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HomeMy WebLinkAboutDRC-2022-018844 - 0901a068810b8a83TNENoYFUEIS Dir, 611'4uut* Management nrrd ltadiation Control JUL f 9 ?il2? Energy Fuels Resources (USA) Inc. 225Union Blvd. Suite 600 Lakewood, CO, US,80228 303 974 2t40 www.energ)'fuels.com Re: July 15,2022 Sent VIA EXPEDITED DELMRY Mr. Doug Hansen Director Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116 Transmittal of Groundwater Discharge Permit Renewal Application for the White Mesa Uranium Mill, Blanding Utah Pursuant to Part tV.D of the March 8,2021Utah Groundwater Discharse Permit No. ucw370004 Dear Mr. Hansen: Enclosed are two copies of the Energy Fuels Resources (USA) Inc. ("EFRI") White Mesa Uranium Mill Groundwater Discharge Permit ("GWDP") application for the White Mesa Mill in accordance with R317-6- 6.7 and the current GWDP revision dated March 8,202I, Part IV.D. This is. an updated application (the "Application") to the Director for renewal of the Permit for another S-years under R313-6-6.7. If you should have any questions regarding this submittal, please contact me at 303-3 89-4134. Yours very truly, Kathy Weinel Director, Regulatory Compliance CC: Scott Bakken David Frydenlund Logan Shumway Garrin Palmer tM ENnnc{ FUELS RnsouncBs (USA) INC. DRC-2022-018844 July 15, 2022 Sent VIA EXPEDITED DELIVERY Mr. Doug Hansen Director Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116 Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 www.energyfuels.com Re: Transmittal of Groundwater Discharge Permit Renewal Application for the White Mesa Uranium Mill, Blanding Utah Pursuant to Part IV.D of the March 8, 2021 Utah Groundwater Discharge Permit No. UGW370004 Dear Mr. Hansen: Enclosed are two copies of the Energy Fuels Resources (USA) Inc. ("EFRI") White Mesa Uranium Mill Groundwater Discharge Permit ("GWDP") application for the White Mesa Mill in accordance with R317-6- 6. 7 and the current GWDP revision dated March 8, 2021, Part IV.D. This is an updated application (the "Application") to the Director for renewal of the Permit for another 5-years under R313-6-6. 7. If you should have any questions regarding this submittal, please contact me at 303-389-4134. Yours very truly, ~ ENERGj FUELS RESOURCES (USA) INC. Kathy W einel Director, Regulatory Compliance CC: Scott Bakken David Frydenlund Logan Shumway Garrin Palmer White Mesa Mill Renewal Application State of Utah Groundwater Discharge Permit No. UGW370004 Energy Fuels Resources (USA) Inc. July 2022 1.0 INTRODUCTION 1.1 Background 1.2 Applicable Standards for Review and Approval of this Application 1.3 Background Groundwater Reports 2.0 INFORMATION PROVIDED IN SUPPORT OF THE APPLICATION 2.1 Name and Address of Applicant and Owner (R317-6-6.3.A) 2.2 Legal Location of the Facility (R317-6-6.3B) 2.3 Name and Type of Facility (R317-6-6.3.C) 1 1 1 5 18 18 19 19 2.4 A Plat Map Showing All Water Wells, Including The Status And Use Of Each Well, Drinking Water Source Protection Zones, Topography, Springs, Water Bodies, Drainages, And Man-Made Structures Within A One-Mile Radius Of The Discharge. (R317-6-6.3.D) 20 2.5 Geologic, Hydrologic, and Agricultural Description of the Geographic Area (R317-6-6.3.E) 2.5.1 Groundwater Characteristics 2.5.1.1 Geologic Setting 2.5.1.2 Hydrogeologic Setting 2.5.1.3 Perched Zone Hydrogeology 2.5.1.4 Perched Groundwater Flow 2.5.1.5 Perched Zone Hydrogeology Beneath And Downgradient Of The TMS 2.5.2 Groundwater Quality 2.5.2.1 Entrada/Navajo Aquifer 2.5.2.2 Perched Groundwater Zone 2.5.3 Springs and Seeps 2.5.4 Topography 2.5.5 Soils 2.5.6 Bedrock 2.5.7 Agricultural and Land Use Description of the Area 2.5.8 Well Logs 20 20 20 21 21 25 26 27 27 28 28 29 29 30 30 31 2.6 The Type, Source, and Chemical, Physical, Radiological, and Toxic Characteristics of the Effluent or Leachate to be Discharged (R317-6-6.3.F) 31 2.7 Information Which Shows that the Discharge can be Controlled and Will Not Migrate Into or Adversely Affect the Quality of any Other Waters of the State (R317-6-6.3.G) 32 2.7.1 General 32 2.7.2 Cells 1, 2 and 3 33 2.7.2.1 Design and Construction of Cells 1, 2 and 3 2.7.2.2 Improved Groundwater Monitoring 2.7.2.3 Operational Changes and Improved Operations Monitoring 2.7.2.4 Evaluation ofTailings Cell Cover System Design 2.7.3 Cell 4A 2.7.4 Cell 4B 33 34 35 35 36 39 2.7.5 Future Additional TMS Cells 2.7.6 Other Facilities and Protections 2. 7 .6.1 Feedstock Storage 2.7.6.2 Mill Site Reagent Storage 2.7.6.3 New Construction 2.7.6.4 Other 2.7.7 Surface Waters 2. 7 .8 Alternate Concentration Limits 2.8 For Areas Where the Groundwater Has Not Been Classified by the Board, Information of the Quality of the 41 42 42 42 42 43 43 43 Receiving Ground Water (R317-6-6.3.H) 43 2.8.1 Existing Wells at the Time of Original Permit Issuance 44 2.8.2 New Wells Installed After the Date of Original Issuance of the Permit 44 2.9 Sampling and Analysis Monitoring Plan (R317-6-6.3.I) 45 2.9.1 Groundwater Monitoring to Determine Groundwater Flow Direction and Gradient, Background Quality at the Site, and the Quality of Groundwater at the Compliance Monitoring Point 45 2.9.1.1 Groundwater Monitoring at the Mill Prior to Issuance of the Permit 45 2.9.1.2 Issuance of the Permit 45 2.9.1.3 Current Ground Water Monitoring Program at the Mill Under the Permit 2.9.1.4 Groundwater Flow Direction and Gradient 2.9.1.5 Background Quality at the Site 2.9.1.6 Quality of Ground Water at the Compliance Monitoring Point 46 47 48 so 2.9.2 Installation, Use and Maintenance of Monitoring Devices 50 2.9.2.1 Compliance Well Monitoring 50 2.9.2.2 Leak Detection System in Cell 4A and Cell 48 50 2.9.2.3 Other DMT Monitoring Requirements 51 2.9.3 Description of the Compliance Monitoring Area Defined by the Compliance Monitoring Points 51 2.9.4 Monitoring of the Vadose Zone 52 2.9.5 Measures to Prevent Ground Water Contamination After the Cessation of Operation, Including Post- Operational Monitoring 52 2.9.5.1 Measures to Prevent Ground Water Contamination After the Cessation of Operation 52 2.9.5.2 Post-Operational Monitoring 52 2.9.6 Monitoring Well Construction and Ground Water Sampling Which Conform Where Applicable to Specified Guidance 52 2.9.6.1 Monitoring Well Construction 52 2.9.6.2 Ground Water Sampling 57 2.9. 7 Description and Justification of Parameters to be Monitored 57 2.9.8 Quality Assurance and Control Provisions for Monitoring Data 58 2.10 Plans and Specifications Relating to Construction, Modification, and Operation of Discharge Systems (R317- 6-6.3.J) 59 2.11 Description of the Ground Water Most Likely to be Affected by the Discharge (R317-6-6.3.K) 2.11.1 General 2.11.2 Background Ground Water Quality in the Perched Aquifer 2.11.3 GWCL Determination for Field pH 2.11.4 Quality of Ground Water at the Compliance Monitoring Point 2.12 Compliance Sampling Plan (R317-6-6.3.L) 2.12.1 Tailings Cell Wastewater Quality Sampling Plan 2.12.2 White Mesa Seeps and Springs Sampling Plan 2.12.3 Monitoring of Deep Wells 11 59 59 60 66 69 69 69 70 71 2.13 Description of the Flooding Potential of the Discharge Site (R317-6-6.3.M) 2.13.1 Surface Water Characteristics 2.13.2 Flood Protection Measures 2.14 Contingency Plan (R317-6-6.3.N) 71 71 72 72 2.15 Methods and Procedures for Inspections of the Facility Operations and for Detecting Failure of the System (R317-6-6.3.0) 72 2.15.1 Existing Tailings Cell Operation 73 2.15.2 Existing Facility DMT Performance Standards 73 2.15.2.1 DMT Monitoring Wells at Cells 1, 2 and 3 73 2.15.2.2 Slimes Drain Monitoring 73 2.15.2.3 Maximum Tailings Waste Solids Elevation 76 2.15.2.4 Inspection of Feedstock Storage Area 76 2.15.2.5 Monitor and Maintain Inventory of Chemicals 77 2.15.3 BAT Performance Standards for Cell 4A 78 2.15.3.1 BAT Operations and Maintenance Plan 78 2.15.3.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan 78 2.15.4 BAT Performance Standards for Cell 4B 79 2.15.4.1 BAT Operations and Maintenance Plan 79 2.15.4.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan 79 2.15.5 Stormwater Management and Spill Control Requirements 80 2.15.6 Tailings and Slimes Drain Sampling 80 2.15.7 Additional Monitoring and Inspections Required Under the Mill License 81 2.15.7.1 Daily Inspections 81 2.15.7.2 Weekly Inspections 82 2.15.7.3 Monthly Reports 82 2.15.7.4 Quarterly Tailings Inspections 83 2.15.7.5 Annual Evaluations 83 2.16 Corrective Action Plan or Identification of Other Response Measures to be Taken to Remedy any Violation of Applicable Ground Water Quality Standards (R317-6-6.3.P) 84 2.16.1 Chloroform Investigation 84 2.16.2 Nitrate Investigation 87 2.17 Other Information Required by the Director (R317-6-6.3.Q) 91 2.17.1 Chemical Inventory Report 91 2.17.2 Southwest Hydrogeologic Investigation 92 2.18 This Application Performed Under the Direction of a Professional Engineer (R317-6-6.3.R) 92 2.19 Closure and Post Closure Management Plan Demonstrating Measures to Prevent Ground Water Contamination During the Closure and Post Closure Phases of Operation (R17-6-6.3.S) 93 2.19.1 Regulatory Requirements for Uranium Mills 93 2.19.1.1 Long Term Custodian 93 2.19.1.2 Responsibility For And Manner Of Clean Up 93 2.19.1.3 Surface 93 2.19.1.4 Groundwater 94 2.19.1.5 License Termination 94 2.19.2 Current Reclamation Plan 95 2.19.3 Provisions Included in the Permit Relating to the Mill's Reclamation Plan 96 2.19.4 Post-Operational Monitoring 97 lll 3.0 CONCLUSIONS 4.0 SIGNATURE AND CERTIFICATIONS 5.0 REFERENCES IV 97 98 99 Figure No. 1 ....................... . 2 ....................... . 3 ....................... . 4 ....................... . 5 ....................... . 6 ....................... . 7 ....................... . 8 ....................... . 9 ....................... . 10 ....................... . 11 ....................... . INDEX OF FIGURES Description White Mesa Mill Location Map White Mesa Mill Land Map Generalized Stratigraphy of White Mesa Mill Kriged Top of Brushy Basin White Mesa Site Kriged 4th Quarter, 2021 Water Levels Showing Inferred Perched Water Flow Paths Southwest of Tailings Management System Seeps and Springs on USGS Topographic Base White Mesa 4th Quarter, 2021 Depths to Perched Water in Feet, White Mesa Site 4th Quarter, 2021 Perched Zone Saturated Thickness in Feet White Mesa Site Groundwater (Well and Spring) Sampling Stations in the White Mesa Vicinity White Mesa Mill Site Plan Showing Locations of Perched Wells and Piezometers Mill Site Layout 12......... ... .... .. . ..... Drainage Map of the Vicinity of the White Mesa Mill 13 ......... .. . .. . . . . . . .... Streamflow Summary Blanding, UT Vicinity V Table No. 1.2-1 ............. . 1.2-2 ............. . 2.4-1 .............. . 2.5.2.1-1 ......... . 2.5.3-1 ........... . 2.5.3-2 ........... . 2.5.3-3 ........... . 2.5.3-4 ........... . 2.5.3-5 ........... . 2.9.1.3-1 ........ .. 2.11.2-1.. ........ . 2.13.1-1 ........... . INDEX OF TABLES Description Chloroform Monitoring Wells (Depth and Purpose) Nitrate Monitoring Wells (Depth and Purpose) Groundwater Monitoring Wells (Depth and Purpose) Water Quality of Entrana/Navajo Aquifer in the Mill Vicinity Results of Quarterly Sampling Ruin Spring (2003-2004) Results of Annual Sampling Ruin Spring (2009-2022) Results of Annual Sampling Cottonwood Spring (2009-2022) Results of Annual Sampling Westwater Seep (2009-2022) Results of Annual Sampling Entrance Spring (2009-2022) Groundwater Monitoring Constituents Listed in Table 2 of the Permit Plan & Time Schedule and Source Assessment Report Status Drainage Areas of Mill Vicinity and Region Vl Appendix A .................... . B .................... . INDEX OF APPENDICES Description Radioactive Materials License Amendment No. 4: March 31, 2007 White Mesa Mill Site Maps with Well Locations C..................... Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill, Revision: 3, November 11, 2019 D......... .. . . . . .. . . . . Results of Soil Analysis at Mill Site E..................... Tables: Chemical and Radiological Characteristics of Tailings Solutions, Leak Detection Systems and Slimes Drains F. ........ ... ......... Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan 07/11 Revision: Denison 2.3 G. ...... .. ...... ... .. . Stormwater Best Management Practices Plan, Revision 2.1: April 2022 H... .. . . . .. . . . . . . . . . .. White Mesa Mill Discharge Minimization Technology (DMT) Monitoring Plan, 1/2022, Revision: EFRI 13.0 I....................... White Mesa Mill Tailings Management System, 3/2017, Revision: EFR 2.5 J. .. . . . . .. . . . . .. . . .. . .. . Cell 2 Slimes Drain Calculations and Figure 2009-2022 K............. .. ... .... White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) Date 2/15/2022 Revision 7.7 L..................... .. Tailings and Slimes Drain Sampling Program, Revision 3.0, July 8, 2016 M.................... .... Contingency Plan, 12/11 Revision: DUSA-4 N ..................... .. White Mesa Mill Containerized Alternate Feedstock Material Storage Procedure, PBL- 19, Revision: 3.0, March 1, 2017 0... . . . . . . . . . . . . . . . . . . . . . White Mesa Mill Chemical Inventory vii 1.0 INTRODUCTION 1.1 Background Energy Fuels Re ources (USA) Inc. ("EFRI") operate the White Mesa Uranium Mill (the "Mill"), located approximately six miles south of Blanding, Utah, under State of Utah Ground Water Discharge Permit No. UGW 370004 (the "Permit" or "GWDP"). The Permit was originally issued by the Co-Executive Secretary of the Utah Water Quality Board on March 8, 2005, for 5 years, expiring on March 8, 2010, and was up for timely renewal in accordance with Utah Administrative Code ("UAC") R317-6-6.7. A renewal application was submitted September l 2009. At the reqL1e: t of the Director of the Utah Division of Radiation Control ("DRC ), EPRI ubmitted an updated ver ion of the September I, 2009 renewal application on July 13 2012. EFRI ubrnitted an updated ver ion of the July 2012 renewal application on June 5, 2014 to address the Division of Waste Management and Radiation Control's ("DWMRC' ') Request for Additional Information ("RAJ"). The Permit wa i ued January 19 2018. In accordance with R317-6-6.7 and the current GWDP revision dated March 8, 2021, Part IV.D, this is an updated application (the "Application") to the Director for renewal of the Permit for another 5-years under R313-6-6.7. The Mill is also subject to State of Utah Radioactive Materials License No. UT 1900479 (the "Mill License"), which was issued by DWMRC on January 18, 2018 for 10-years. The current amendment to the License (Amendment 10) was issued July 27 2021. The Mill is al o ubject to State of Utah Air Quality Approval Order DAQE-ANOl 12050024-21 (the 'Air Approval Order') which wa re-is ued on December 23 2021 and is not up for renewal at thi time. While the Mill License is referred to in this Application from time to time in order to allow the Director to better understand Mill operations and compliance with applicable regulatory requirements, this is not an application for renewal of the Mill License or Air Approval Order. Prior to July 1, 2012, the Director of the Utah Division of Radiation Control ("Director") was referred to as the Executive Secretary of the Utah Radiation Control and Board Co-Executive Secretary of the Utah Water Quality Board. Prior to 2015, the DWMRC was referred to as the Utah DRC. Document referenced in this Application, published prior to these dates, may refer to the previous titles and division names. 1.2 Applicable Standards for Review and Approval of this Application In accordance with R317-6-6.4C, the Director may issue ( or renew) a ground water discharge permit for an existing facility, such as the Mill, provided: a) The applicant demonstrates that the applicable class total dissolved solids ("TDS") limits, groundwater quality standards and protection levels will be met; b) The monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; c) The applicant utilizes treatment and discharge minimization technology commensurate with plant process design capability and similar or equivalent to that utilized by 1 facilities that produce similar products or services with similar production process technology; and d) There is no current or anticipated impairment of present and future beneficial uses of the ground water. Thi Permit Application demonsn·ates how ex1 trng facilities continue to meet applicable regulatory criteria and the monitoring u·ategie employed to prevent impairment of pre ent and future beneficial u e. of the groundwater. EFRI conducts variou kinds of environmental monitoring at the White Mesa Mill including but not limited to groundwater, surface water, soil, sediment, tailings waste water, air, and vegetation. Specific groundwater monitoring activities employed are summarized below. EFRI's groundwater monitoring program is comprehensive in that it includes all of the 82 monitoring wells and three piezometers at the facility, as described below, although not every location is sampled every quarter or for the complete list of GWDP con tituents. Samples are taken and analyzed for a large number of groundwater contaminants including heavy metals, nutrients, general chemistry analytes, radiologies, and volatile organic compounds ("VOCs"). Exceedences of standards found during this monitoring program have been addressed as described throughout this GWDP Application. Under the License, the Permit, and the Corrective Action Plans, EFRI has completed and is monitoring the 85 groundwater monitoring locations (82 wells and three piezometers) described below. • 31 grollndwater wells monitored to detect any potential leaks from the Tailings Management System ("TMS") and/or provide information regarding local geochemical conditions at the Mill. Because the leak detection systems for Cells 1, 2, and 3 utilized older, less sophisticated technology, DWMRC required nine new wells be installed adjacent to the TMS in 2005. These wells are used as a first line of defense to detect any potential TMS impacts. These supplemented the existing thirteen wells that were installed prior to the 2005 issuance of the original permit (existing well MW-3 has since been abandoned). Two additional general monitoring wells were included in the program (MW-20 and MW-22). An additional three wells have been installed in association with the construction of Cells 4A and 4B. Three wells have been added by EFRI in response to requests from the Ute Mountain Ute Tribe ("UMUT") far cross-gradient to the TMS to provide water level data and to provide additional information on site geology and naturally occurring geochemical behaviors. One weJJ ha been in talled adjacent to MW- 24 for additional studies of regional geochemi try. Chloroform weJI TW4-24 ha been added as a general monitoring well under the groundwater sampling program. • 43 monitoring wells associated with characterizing the chloroform groundwater plume. • Eight monitoring wells and three piezometers are a ociated with characterizing the nitrate groundwater plume. The monitoring results for each of the 31 groundwater wells that are sampled, are evaluated against standards for 38 different constituents. Monitoring results for each of the 43 chloroform wells and 11 nitrate sampling locations are evaluated for six different constituents and two 2 different constituents respectively. For all 85 monitoring locations, regardless of whether the standards are met, the results are evaluated for trends in the data that may show a need for further action. Four indicator parameters ( chloride, uranium, fluoride, and sulfate) are used at the site to determine if there has been any potential cell leakage. These constituents were chosen because they are the most mobile and are expected to be seen first with any upward trend in consistent concentrations. If a cell were leaking, it is expected that all four parameters would show increasing trends within two years, based on Kd values and other transport characteristics for the contaminants and site. In instances where the indicator parameters are affected by the co-located nitrate and chloride plume or other location specific geochemical influences, alternative mass balance assessments and studies are completed to assure protection levels are met. During a DWMRC split sampling event in May, 1999, excess chloroform concentrations were discovered in monitoring well MW-4, which is located along the eastern margin of the site. Because these concentrations were above the Utah Ground Water Quality Standard of 70 µg/L, the DWMRC initiated enforcement action against EFRI on August 23, 1999 by issuing a Ground Water Corrective Action Order. The Order required completion of: 1) a contaminant investigation report to define and delineate boundaries for the contaminant plume, and 2) a groundwater corrective action plan to clean it up. Twenty new monitoring wells (since increased to 34 wells) were installed at the site as part of the investigation. Table 1.2-1 lists the 43 chloroform monitoring wells. The Director and EFRI determined that the laboratory wastewater sent to sewage leach fields, and not potential impacts from the TMS, was the most likely source of the chloroform plume. As with every groundwater corrective action, the corrective action plan is developed based on assumptions about the source, and those assumptions are tested continuously with groundwater monitoring as corrective action proceeds. With DWMRC concurrence, EFRI began to pump chloroform contaminated groundwater in April, 2003. Groundwater monitoring results show this initial remediation effort has been effective based on reduction of contaminant concentrations. Reductions of the contaminant concentrations indicates both that the pumping program is working and that there is no continuous source for the contaminants, as would be the case if the TMS were leaking. During a review of the EFRI April 30, 2008 New Wells Background Report and other EFRI reports, Nitrate + Nitrite (as N) (hereafter Nitrate) concentrations were observed above the Utah Ground Water Quality Standard (10 milligrams per liter ["mg/L"]) in five monitoring wells in the mill site area. After the Nitrate Plume was identified, the Executive Secretary and EFRI entered into a January 28, 2009 Stipulated Consent Agreement that required EFRI to complete a Contaminant Investigation Report to determine the potential sources of the Nitrate contamination. Nineteen additional wells were installed to determine the extent of the contamination; nine of these wells have since been abandoned. An additional two wells were installed in 2021 to address nitrate 3 plume migration occurring upgradient of the TMS. Table 1.2-2 lists the current and former nitrate wells installed as part of the nitrate corrective actions. EFRI submitted two reports to DWMRC regarding the elevated Nitrate concentrations. The reports identified the extent of the Nitrate plume but EFRI and DWMRC disagreed about what the rep01ts indicated about the likely source of the plume. EFRI does not believe that the results adequately demonstrated an on-site source, especially since a significant p01tion of the plume originates upgradient from the Mill facilities, specifically upgradient of the TMS. EFRI agreed to implement a corrective action plan to clean up the plume. EFRI completed and submitted the Nitrate Corrective Action Plan to the DRC on May 7, 2012 (HGC 2012b). The Corrective Action Plan was approved following a public comment period, and was incorporated into a December 12, 2012 Stipulation and Consent Order, Docket Number UGW12-04. The approval is subject to conditions, stipulated penalties and timelines outlined in the Stipulation and Consent Order. The remediation plan requires EFRI to pump the groundwater and treat it by evaporation and/or use as process water. Pumping under the remediation plan began in January 2013. Groundwater monitoring results show this initial remediation effort has been effective based on reduction of the plume mass to date. When the DWMRC began oversight of the Mill, it noted that groundwater monitoring had showed elevated concentrations of metals, primarily uranium, in wells MW-3, MW-3A, MW-14, MW-15, MW-22 on the Mill site. The DWMRC was concerned about whether the observations meant that the TMS was potentialJy impacting groundwater. To address its concerns, the DWMRC commissioned the Uoiver ity of Utah to investigate the elevated concentrations in July 2007. The University completed its study and published a report in May 2008 (the "2008 University Report"). After review of the 2008 University Report, the DWMRC determined that downgradient wells with elevated total uranium concentrations (including well MW-22) were not being impacted by potential TMS leakage. This conclusion was based on at least three lines of isotopic evidence: 1. Tritium Signature. Wells MW-3 (now abandoned), MW-3A, MW-14, MW-15, MW-22 had tritium signatures in groundwater at or below the limit of detection of 0.3 Tritium Units (2008 University Report p. 26). These values are more than an order of magnitude below the corresponding surface water results found in either the TMS or the wildlife ponds. This means that the groundwater in these five downgradient wells is older than water in the TMS, and is of a different origin than the TMS fluids. 2. Stable Isotopes of Deuterium and Oxygen-18 in Water. The Deuterium and Oxygen-18 content of the groundwater matrix and TMS fluids were tested in all of the water sources studied. The 2008 University Report results showed that wells MW-3 (now abandoned), MW-3A, MW-14, MW-15, and MW-22, all downgradient wells with elevated uranium concentrations, had Deuterium and Oxygen-18 signatures that were almost twice as negative as any of the surface water results (2008 University Report, p. 42.). This shows that 4 groundwater in these downgradient wells had a different geochemical origin than the TMS fluids. 3. Stable Isotopes on Dissolved Sulfate. The University Study evaluated two stable isotopes found in sulfate minerals dissolved in the water samples, Oxygen-18 and Sulfur-34. The evaluation showed that the sulfate solutes in groundwater from downgradient wells MW-3 (now abandoned), MW-3A, MW-14, MW-15, and MW-22 had a different isotopic signature than the sulfate minerals dissolved in the TMS fluids. In the case of Oxygen-18 in sulfate, the downgradient wells showed more negative values than the TMS fluids. For Sulfur-34, the results were inversed, with groundwater showing more positive values than the negative values seen in the TMS fluids (2008 University Report p. 46.). This shows that the sulfate dissolved in the downgradient wells, with elevated uranium concentrations, has a different origin than the TMS fluids. In summary, the University Study concluded that wells with high concentrations of metals (MW- 3 [now abandoned], MW-14, MW-15, MW-18, and MW-22) bear very different isotopic fingerprints than those of the surface water sites (e.g. wildlife ponds, and TMS) (2008 Univer ity Report p. 58). Regarding uranium concentrations in well MW-22, the University Study stated that " .. .it does not appear that the elevated uranium values are the result of leakage from tailings cells .... " (2008 University Report p. 45). The 2008 University Report further theorized that the cause of the increasing contaminant concentrations on the site wa artificial recharge from wildlife pond constructed in 1995 de ·cribed in Part 1.5.1 of the 2008 Univer ity Report. Tiu recharge likely leached and mobilized natural uranium and other con tituent as a re ult of new aturation of zones beneath the site that had previously been unsaturated. The Mill ceased delivery of water to the wildlife ponds in March 2012. As indicated by these previous studies, the Mill meets the requirements set out in R317-6-6.4( c ). This Application has been prepared under the direction, and bears the seal, of a professional engineer qualified to practice engineering before the public in the state of Utah and professionally registered as required under the Professional Engineers and Professional Land Surveyors Licensing Act rules (UAC 156-22). 1.3 Background Groundwater Reports In the December 1, 2004 Statement of Basis (the "2004 Statement of Basis") prepared by DWMRC in connection with the original issuance of the Permit, three monitoring wells (MW- 14, MW-15, and MW-17) located downgradient of the Mill's TMS were found to have long-term increasing concentration trends for uranium. These three wells had uranium concentrations above the Utah Ground Water Quality Standard ("GWQS"), found in UAC R317-6-2 (see the 2004 Statement of Basis, pp. 6-7). These findings were of concern to the DWMRC becau e they appeared to indicate that the TMS had possibly discharged fluids into the underlying hallow aquifer. To resolve this concern, the Director required EFRI to evaluate groundwater quality data from 5 the thirteen existing wells on site, and submit a Background Ground Water Quality Report for Director approval. The exi ting well are tho, e wells which were installed prior to the issuance of the original GWDP on March 8, 2005 and include: MW-! MW-2, MW-3 (now abandoned) MW-5, MW-11, MW-12, MW-14, MW-15, MW-17 MW-18 MW-19 MW-26 (formerly called TW4-15 and installed as part of the chloroform corrective action order), and MW-32 (formerly called TW4-17 and installed as part of the chloroform corrective action order). It is important to note that MW-4 was in talled prior to the issuance of the original permit; however, MW-4 is monitored under the chloroform program and was not included in the Existing Background Report. Groundwater Compliance Limits ( GWCLs') have not been establi. hed for thi · well, and MW-4 i not a Point of Compliance ("POC') well Llnder the GWDP. One of the purposes of the background report was to provide a critical evaluation of historic groundwater quality data from the facility, and determine representative background quality conditions and reliable GWCLs for the Permit. As required, EFRI submitted the following reports: • Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, October 2007 (INTERA 2007a) prepared by INTERA, Inc. (the 'Existing Well Background Report"); and • Revised Addendum: --Evaluation of Available Pre-Operational and Regional Background Data, Ba ·kground Groundwater Quality Report: Existing Wells For Denison Mines (USA) Co,p. 's White Mesa Mill Site, an Juan County, Utah November 16, 2007 (INTERA 2007b), prepared by INTERA, Inc. (the "Regional Background Report"). The Exi ting WelJ Background Report and the Regional Background Reporl included a detailed quality assurance evaluaLion of all existing groundwater quaJity data collected pr.ior to the date of is. uaoce for the thirteen existing wells, jn accordance with criteria e. tabli hed by DWMRC and United States Environmental Protection Agency ("EPA') guidance. Thi resulted .in a database suitable for statistical and other analyses. Ba ed on an analy i of this updated database the Existing Well Background Report and Regional BackgrOLmd Report concluded that there had been no impacts to groundwater from Mill activitie , ba ed on a number of factor including the following: • There were a number of exceedances of GWQSs in upgradient and far downgradient wells at the site, which cannot be considered to have been impacted by Mill operation . Exceedances of GWQSs in monitoring wells nearer to the site itself are therefore consistent with natural background in the area. • There were numerou case of both increasing and decreasing trends in constituents in upgradient far downgradient and MiJJ ite wells, which provide evidence that there are natural force at work that are impacting groundwater quality across the entire site. • In almost all cases where there were increasing trends in constituents in wells at the site, there were increasing trends in those constituents in upgradient wells. 6 See Section 2.11.2 below for a more detailed discussion of the Existing Well Background Report and Regional Background Report and their conclusions. The Permit also required nine new monitoring wells to be installed around TMS Cells 1 and 2, followed by groundwater sampling and analysis, and later submittal of another Background Ground Water Quality Report to determine reliable background conditions and groundwater compliance limits for the new wells. The new wells are those wells, which were installed after the issuance of the original GWDP on March 8, 2005 and include: MW-3A, MW-23, MW-24, MW-25, MW-27, MW-28, MW-29, MW-30, and MW-31. In response to this requirement, EFRI installed the nine new wells, and submitted to the Director a Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA, Inc. (the "New Well Background Report"), and together with the Existing Well Background Repmt and the Regional Background Report, are referred to as the "Background Reports"). The New Well Background Report concluded that the sampling results for the new wells confirm that the groundwater at the Mill site and in the region is highly variable naturally and has not been impacted by Mill operations and that varying concentrations of constituents at the site are consistent with natural background variation in the area. See Section 2.11.2 below for a more detailed discussion of the New Well Background Report and its conclusions. During the course of discussions with EFRI staff, and further DWMRC review, DWMRC decided to supplement the analysis provided in the Background Reports by commissioning the University of Utah to perform a geochemical and isotopic groundwater study at White Mesa. This resulted in the University of Utah completing a study entitled Summary of work completed, data results, interpretations and recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, May 2008, prepared by T. Grant Hurst and D. Kip Solomon, Department of Geophysics, University of Utah (the "University of Utah Study"). The purpose of the University of Utah Study was to determine if the increasing and elevated trace metal concentrations (such as uranium) found in the monitoring wells at the Mill were due to potential leakage from the TMS. To investigate this potential problem, the study examined groundwater flow, chemical composition, noble gas and isotopic composition, and age of the on-site groundwater. Similar evaluations were also made on samples of the TMS fluids and nearby surface water stored in the northern wildlife ponds at the facility. Fieldwork for the University of Utah Study was conducted from July 17 -26 of 2007. The conclusions in the University of Utah Study supported EFRI's conclusions in the Background Reports. As stated above, EFRI prepared Background Reports that evaluated all historic data for the thirteen existing wells and nine new wells for the purposes of establishing background groundwater quality at the site and developing GWCLs under the GWDP. Prior to review and acceptance of the conclusions in these Background Reports, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water based on TDS in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality 7 for the thirteen existing wells and the nine new wells based primarily on the conclusions and analysis in the Background Reports. It should be noted however, that, becau e the GWCLs have been set at the mean pJu second standard deviation, or the equivalent un-impacted groundwater would normally be expected to exceed the GWCL. appioximately 2.5% of tbe time. Therefore, exceedances are expected in approximately 2.5% of all sample re ults, and do not necessarily represent impacts to groundwater from Mill operations. In addition to the thirteen existing wells (12 remaining after the abandonment of MW-3) and the nine new wells there are an additional 10 monitoring wells at the site which are included in the routine groundwater monitoring program and sampled when ufficient water i present. Tho e nine wells are: MW-20, MW-22, MW-35, MW-36, MW-37, MW-38 MW-39, MW-40 MW- 24A, and TW4-24. The GWDP dated January 20, 2010 required the completion of eight consecutive quarters of groundwater sampling and analysis of MW-20 and MW-22 and later submittal of anothes Background Report to determine if wells MW-20 and MW-22 should be added a POC monitoring wells. Data from MW-20 and MW-22 were analyzed in the pre-operational and regional background addendum (JNTERA 2007a); however there was not a complete data set at the time. Although wells MW-20 and MW-22 were installed in 1994, they were not sampled regularly until the econd quarter of 2008. The eighth full round of sampling was completed during the fir t quarter of 2010, and EFRI submitted to the Director the Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, June 1, 2010, prepared by INTERA, Inc. (the "MW-20 and MW-22 Background Report"). DWMRC classified MW-20 and MW-22 as general monitoring wells, and GWCLs have not been established for these wells. MW-20 and MW-22 are sampled semi-annually. Part I.H.6 of the GWDP dated June 21, 2010 required the in tallation of three hydraulically downgradient wells adjacent to Tailings Cell 4B (MW-33, MW-34, and MW-35) prior to placement of solids or fluids in Cell 4B. The purpo e of the, e monitoring wells was to provide early detection of potential impacts to the shallow groundwater from Tailings Cell 4B. EFRI installed MW-33, MW-34, and MW-35 as required. Of the, e three well. installed near tailing Cell 4B, only MW-35 was hydraulically acceptable, with five feet or more of saturated thickness. MW-35 was sampled quarterly since fourth quarter 2010 to collect eight statistically valid data points for the completion of the Background Report and calculation of GWCLs. MW-33 and MW-34 had insufficient water for sampling, with saturated thicknesses less than five feet. MW- 33 is completely dry, and no samples or depth to water measurements are collected from this well. Quarterly depth to water is measured in MW-34, but no sampling or analysis is required. Part I.H.4 of the February 15, 2011 GWDP required the installation of two wells hydraulically downgradient of Tailings Cell 4B as replacements for MW-33 and MW-34. EFRI installed MW-36 and MW-37 as required. MW-36 and MW-37 were sampled quarterly beginning in the third quarter 2011 to collect eight statistically valid data points for the completion of the Background Report and calculation of GWCLs. The Background Report for wells MW-35, MW-36, and MW-37 was submitted to the Director on May 1, 2014. The findings of the Background Analysis for wells MW-35, MW-36, and MW- 8 37 support previous conclusions that the groundwater at the Mill is not being affected by any potential TMS seepage. The Director incorporated MW-35, MW-36 and MW-37 in a subsequent revision of the GWDP and these wells are sampled as required. Three wells have been added by EFRI in response to requests from the UMUT far cross-gradient to the TMS to provide water level data and to provide additional information on site geology and naturally occurring geochemical behaviors. DWMRC stated in the Public Participation Summary ("PPS") for the January 18, 2018 GWDP renewal that "There is no regulatory or technical basis to require additional monitoring wells between Cell 4A and MW-22. Monitoring wells currently exist directly downgradient and cross gradient from Cell 4A which would identify potential TMS impacts before anything would appear in MW-22 and at this time no tailings cell leakage has been observed. In regards to the requested three new monitoring wells made by the UMUT in other comments, although the Division e s no technical or regulatory basis to include monitoring wells in the location between Tailing, Cell 4A and MW-22, EFRI has agreed to address the UMUT concern and voluntarily install three monitoring wells in the area between monitoring wells MW-17 and MW -22." The three wells, MW-38, MW-39 and MW-40, were installed in February 2018. The Background Report for wells MW-38, MW-39, and MW-40 was submitted to the Director on June 7, 2021 after sufficient data had been collected to complete the statistical evaluation. The findings of the Background Analysis for wells MW-38, MW-39, and MW-40 support previous conclusions that the groundwater at the Mill is not being impacted by any potential TMS seepage. The Director approved the background report for MW-38, MW-39, and MW-40 by letter dated June 16, 2021. MW-38, MW-39, and MW-40 will be incorporated into a subsequent revision of the GWDP. Until such time as these wells are incorporated into the GWDP, they are sampled on a quarterly basis. Part I.G.2 of the Permit provide that out-of-compliance ·tatu exi t when the concentration of a constituent in two con ecutive sample from a compliance monitoring po.int exceeds a GWCL in Table 2 of the Permit. A part of the a se ment of exceedance. of previ.ou GWCLs, increasing trends in several constituents in MW-24 and other wells were observed as noted in the reports listed below. In response to the previously identified exceedances and increasing trends, in 2020 EFRI voluntarily completed a study of MW-24A (collocated with MW-24) to determine what geochemical and hydrogeological influence. are pre ent which may be impacting monitoring data collected at these two wells and potentially other wells aero. the Mill ite. The MW-24A study and report (EFRI, 2021c) included several additional field data collection and analytical .activities based on the conclusions of other Mill reports including but not limited to: • 2008. Background Groundwater Quality Report: New Wells for Denison Mines (USA) Corp. 's Mill Site. April 30, 2008. Prepared by INTERA. • 2012. Source Assessment Report White Mesa Uranium Mill. October 10, 2012. Prepared by INTERA ("2012 SAR"). • 2012. pH Report White Mesa Uranium Mill. November 9, 2012. Prepared by Intera ("pH Report"). 9 • 2012. Investigation of Pyrite in the Perched Zone White Mesa Uranium Mill. Prepared by HGC ("Pyrite Report ). • 2016. Source Assessment Report for MW-18 and MW-24 White Mesa Uranium Mill. June 24, 2016. Prepared by INTERA ("2016 SAR"). • 2019. Source Assessment Report for MW-11 and MW-24 White Mesa Uranium Mill. June 27, 2019. Prepared by INTERA ("2019 SAR") The result of the analytical and test data collected during tbe MW-24A tudy demonstrated that natural proce e unrelated to dispo al of materials in the TMS can account for the behavior of all trace metaJ · of concern, as weU as fluoride in groundwater at MW-24 and MW-24A. Bottle- roll test results indicated that naturally-occurring trace metal can be mobilized at concentrations imilar to or greater than in groundwater even without a large pH decrea e, uggesting that agitation alone, 'uch as would occur during routine purging and ·ampling of low penneability well uch a MW-24A, could re ult in metal mobilization. The perched groundwater y tern ho ted by the Burro Canyon Formation and Dakota Sandstone does not approach teady tate over mu b of the monitored area. A large part of the site perched water y tern i · in a transient state and affected by long-term chru1ge in water level due to past and current activitie unrelated to the di 'PO al of materials to the TMS. Ba ed on the result of the MW-24A tudy EFRI ha voluntarily agreed to implement a Phase 2 study to determine what geochemical and hydrogeological influences are present that may be affecting monitoring data collected at other wells acros the Mill site. Thi voluntary tudy will commence in mid to late 2022. As a result of the planned additional . tudies EFRI received a deferment of the Background Groundwater Quality Report for MW-24A required by the March 8, 2021 GWDP because the Background Report for MW-24A i · premature at thi time. The deferment until will last until after the completion of the additional tudie · discussed above. Monitoring well MW-41 will be installed during the planned additional studies associated with MW-24/MW-24A. 1.4 Documents Referenced in This Application The following documents are referenced in this Application. a) The following Permits, Licenses, Statement of Basis, Plans and Related Reports: (i) State of Utah GWDP No. UGW370004 dated March 8, 2021 and previoll ver ions of the Permit dated January 10, 2010, March 8, 2010, June 21, 2010, February 15, 2011, July 14, 2011, August 24, 2012 January 19, 2018, and Mrud1 19, 2019. (ii) State of Utah License No. UT 1900479, Amendment 10 dated July 27, 2021; (iii) Statement of Basis For a Uranium Milling Facility at White Mesa, South of Blanding, Utah, Owned and Operated by International Uranium (USA) 10 Corporation, December 1, 2004, prepared by the State of Utah Division of Radiation Control; (iv) Statement of Basis Radioactive Materials License No. UT 1900479 and Groundwater Discharge Permit No. UGW 370004, January 2018 (v) Final Statement of Basis and Groundwater Permit, UGW370004, January 2019 (vi) Modification of Groundwater Permit No UGW370004 Statement of Basis, March 2020 (vii) Reclamation Plan White Mesa Mill Blanding, Utah, Revision 5.1, February 8, 2018 (the "Reclamation Plan"); and (i) UMETCO Minerals Corporation: White Mesa Mill Drainage Report for Submittal to NRC, January 1990; b) The following Background Groundwater Quality Reports and Related Studies: (i) Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, October 2007 (INTERA 2007a), prepared by INTERA, Inc.; (ii) Revised Addendum: --Evaluation of Available Pre-Operational and Regional Background Data, Ba kground Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, November 16, 2007 (INTERA 2007b), prepared by INTERA, Inc.; (iii) Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA, Inc.; and (iv) Summary of work completed, data results, interpretations and recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, May 2008, prepared by T. Grant Hurst and D. Kip Solomon, Department of Geophysics, University of Utah; (v) Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, June 1, 2010, prepared by INTERA, Inc. (the "MW-20 and MW-22 Background Report"); (vi) Background Groundwater Quality Report for Monitoring Wells MW-35, MW-36 and MW-37 White Me a Mill Blanding, Utah, May 1, 2014 (INTERA 2014c) prepru:ed by INTERA, Inc. (the 'MW-35, MW-36, and MW-37 Background Report". 11 (vii) Background Groundwater Quality Report for Monitoring Wells MW-38, MW-39 and MW-40 White Mesa Mill Blanding, Utah June 7, 2021, prepared by INTERA, Inc. (the "MW-38, MW-39, and MW-40 Background Report". c) The following environmental reports and analyses: (i) Environmental Report, White Mesa Uranium Project San Juan County, Utah, January 30, 1978, prepared by Dames & Moore (the "1978 ER"); and (ii) Final Environmental Statement related to operation of White Mesa Uranium Project Energy Fuels Nuclear, Inc., May 1979, Docket No. 40-8681, prepared by the United States Nuclear Regulatory Commission (the "FES"); d) The following engineering, geological and hydrogeological reports: (i) Umetco Groundwater Study, White Mesa Facilitie , Blanding, Utah, 1993, prepared by Umetco Minerals Corporation (the operator of the Mill at the time) and Peel Environmental Services; (ii) Hydrogeological Evaluation of White Mesa Uranium Mill, July 1994, prepared by Titan Environmental Corporation (the "1994 Titan Report"); (iii) Evaluation of Potential for Tailings Cell Discharge -White Mesa Mill, November 23, 1998, prepared by Knight-Pie ·old LLC; (iv) Investigation of Elevated chloroform concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah, 2001, prepared by Hydro Geo Chem, Inc.; (v) Letter Report dated August 29, 2002, prepared by Hydro Geo Chem, Inc.; (vi) Hydrogeology White Mesa Uranium Mill Site Near Blanding, Utah, June 6, 2012, prepared by Hydro Geo Chem, Inc.; e) The following plans and specifications relating to construction and operation of the Mill's TMS: (i) Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah, June 1979, prepared by D' Appolonia Consulting Engineers, Inc.; (ii) Engineer's Report: Second Phase Design -Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah, May 1981, prepared by D' Appolonia Consulting Engineers, Inc.; 12 (iii) Construction Report: Initial Phase -Tailings Management System, White Mesa Uranium Project Blanding, Utah, February 1982, prepared by D' Appolonia Consulting Engineers, Inc.; (iv) Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project, March 1983, prepared by Energy Fuels Nuclear, Inc. (the operator of the Mill at the time); (v) Cell 4 Design, White Mesa Project Blanding, Utah, April 10, 1989, prepared by Umetco Minerals Corporation (the operator of the Mill at the time); (vi) Construction Report: Tailings Cell 4A, White Mesa Uranium Mill -Tailings Management System, August 2000, prepared by International Uranium (USA) Corporation (the operator of the Mill at the time); (vii) Cell 4A Lining System Design Report For The White Mesa Mill Blanding, Utah, January 2006, prepared by GeoSyntec Consultants; (viii) Cell 4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah, July 2008, prepared by Geosyntec consultants; (ix) Cell 4B Design Report, White Mesa Mill, Blanding, Utah, December 8, 2007, prepared by Geosyntec Consultants; and (x) Cell 4B Construction Quality Assurance Report, Volumes 1-3, November 2010, prepared by Geosyntec Consultants. f) The following documents relating to the chloroform investigation at the site: (i) Stipulation and Consent Order Docket Number UGW20-01-SCO September 14, 2015; (ii) Groundwater Corre ·tive Action Plan ("GCAP") for the Energy Fuels Resources (USA) Inc. Chloroform Plume at the White Mesa Uranium Recovery Facility Near Blanding, Utah, September 14, 2015. (iii) Corrective Action Comprehensive Monitoring Evaluation ("CACME") report for chloroform in perched groundwater at the White Mesa Uranium Mill (the 'Mill") located near Blanding, Utah, March 16, 2016, prepared by Hydro Geo Chem, Inc.; (iv) Corrective Action Comprehensive Monitoring Evaluation ("CACME") report for chloroform in perched groundwater at the White Mesa Uranium Mill (the "Mill") located near Blanding, Utah, March 31, 2018, prepared by Hydro Geo Chem, Inc.; 13 (v) Corrective Action Comprehensive Monitoring Evaluation ("CACME") report for chloroform in perched groundwater at the White Mesa Uranium Mill (the "Mill") located near Blanding, Utah, March 31, 2020, prepared by Hydro Geo Chem, Inc.; (vi) Corrective Action Comprehensive Monitoring Evaluation ("CACME") report for chloroform in perched groundwater at the White Mesa Uranium Mill (the "Mill") located near Blanding, Utah, March 31, 2022, prepared by Hydro Geo Chem, Inc.; g) The following documents relating to the pH and other Out of Compliance investigations at the site: (i) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the First, Second, Third and Fourth Quarters of 2010 and First Quarter 2011, June 13, 2011; (ii) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Second Quarter of 2011, September 7, 2011; (iii) Plan and Time Schedule for Assessment of pH Under Groundwater Discharge Permit UGW370004, April 13, 2012 (2012a) prepared by Hydro Geo Chem, Inc.; (iv) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of 2012, December 13, 2012; (v) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Fourth Quarter of 2012, March 15, 2013; (vi) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for Constituents in the First Quarter of 2013, August 28, 2013; (vii) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for Constituents in the Second Quarter of 2013, September 20, 2013; (viii) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of 2013, December 5, 2013; (ix) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of 2014, December 4, 2014; 14 (x) (xi) (xii) (xiii) (xiv) (xv) (xvi) (xvii) (xviii) (xix) (xx) (xxi) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the First Quarter of 2015, May 19, 2015; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Second Quarter of 2015, September 10, 2015; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of 2015, December 3, 2015; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for Constituents in the Fourth Quarter of 2015, March 3, 2016; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for Constituents in the Fourth Quarter of 2016, March 10, 2017; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Fourth Quarter of 2017, March 2, 2018; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Second Quarter of 2018, August 28, 2018; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of 2018, December 5, 2018; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Fourth Quarter of 2018, February 21, 2019; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for Constituents in the First Quarter of 2019, May 13, 2019; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part l.G.2 for Constituents in the Fourth Quarter of 2019, February 27, 2020; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan 15 (xxii) (xxiii) (xxiv) (xxv) (xxvi) (xxvii) (xxviii) (xxix) (xxx) (xxxi) (xxxii) (xxxiii) (xxxiv) and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for Constituents in the First Quarter of 2020, May 21, 2020; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of 2020, November 18, 2020; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Fourth Quarter of 2020, January 25, 2021; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the First Quarter of 2021, May 11, 2021; White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part l.G.2 for Constituents in the Second Quarter of 2021, August 25, 2021; Source Assessment Report, White Mesa Uranium Mill, Blanding Utah, October 10, 2012 prepared by INTERA, Inc; pH Report White Mesa Uranium Mill, Blanding Utah, November 9, 2012 prepared by INTERA, Inc; Investigation of Pyrite in the Perched Zone, White Mesa Uranium Mill, Blanding Utah, December 7, 2012 (HGC 2012c) prepared by Hydro Geo Chem, Inc.; Source Assessment Report for TDS in MW-29, White Mesa Uranium Mill, Blanding Utah, May 7, 2013 (INTERA 2013a) prepared by INTERA, Inc; Source Assessment Report for Selenium in MW-31, White Mesa Uranium Mill, Blanding Utah, August 30, 2013 (INTERA 2013b) prepared by INTERA, Inc; Source Assessment Report for Tetrahydrofuran in MW-OJ, White Mesa Uranium Mill, Blanding Utah, December 17, 2013 (INTERA 2013c); prepared by INTERA, Inc. Source Assessment Report for Gross Alpha in MW-32, White Mesa Uranium Mill, Blanding Utah, January 13, 2014 (INTERA 2014a) prepared by INTERA, Inc; Source Assessment Report for Sulfate in MW-OJ and TDS in MW-03A, White Mesa Uranium Mill, Blanding Utah, March 19, 2014 (INTERA 2014b) prepared by INTERA, Inc; Source Assessment Report for Selenium, Sulfate, TDS and pH in MW-31, White 16 Mesa Uranium Mill, Blanding Utah, December 9, 2015 prepared by INTERA, Inc; (xxxv) Source Assessment Report for Sulfate in MW-18 and Fluoride, Cadmium Thallium and pH in MW-24, White Mesa Uranium Mill, Blanding Utah, June 24, 2016 prepared by INTERA, Inc; (xxxvi) Source Assessment Report for Selenium, Sulfate, and Uranium in MW-31, White Mesa Uranium Mill, Blanding Utah, August 20, 2017 prepared by INTERA, Inc; (xxxvii) Source Assessment Report for Fluoride in MW-14, White Mesa Uranium Mill, Blanding Utah, June 25 , 2018 prepared by INTERA, Inc; (xxxviii) Source Assessment Report for Uranium, Selenium and pH in MW-30, White Mesa Uranium Mill, Blanding Utah, January 16, 2019 (INTERA 2019a) prepared by INTERA, Inc; (xxxix) Source Assessment Report for Manganese in MW-11, andfluoride, pH, cadmium, beryllium, nickel, and thallium in MW-24 White Mesa Uranium Mill, Blanding Utah,, June 27, 2019 (INTERA 2019b) prepared by INTERA, Inc; (xl) Source Assessment Report for Cadmium in MW-25, White Mesa Uranium Mill, Blanding Utah, September 23, 2019 (INTERA 2019c) prepared by INTERA, Inc; (xii) Source Assessment Report for TDS and Sulfate, in MW-31, White Mesa Uranium Mill, Blanding Utah, June 24, 2020 prepared by INTERA, Inc; (xiii) Source Assessment Report for Selenium and Uranium in MW-28, White Mesa Uranium Mill, Blanding Utah, October 19, 2020 prepared by EFRI; (xliii) Source Assessment Report for Uranium in MW-31, White Mesa Uranium Mill, Blanding Utah, April 29, 2021 (EFRI 2021a) prepared by EFRI; (xliv) Source Assessment Report for Uranium in MW-29, White Mesa Uranium Mill, Blanding Utah, September 7, 2021 (EFRI 2021b) prepared by EFRI; (xlv) Source Assessment Report for Uranium and Selenium in MW-30, White Mesa Uranium Mill, Blanding Utah, January 28, 2022 prepared by EFRI; h) The following documents relating to the nitrate investigations at the site: (i) Stipulated Consent Agreement Docket No. UGW12-03 between Denison Mines (USA) Corp. and the Director of the Division of Radiation Control, July 12, 2012. (ii) Revised Tolling Agreement, Revision 3, between DUSA and the Director, Revision 2, dated August 21, 2011. 17 (iii) Revised Phase 1 (A through C) Work Plan and Schedule for Phase 1 A -C Investigation, May 11, 2011, prepared by INTERA, Inc; (iv) Revised Phase 2 through 5 Work Plan and Schedule, June 3, 2011, prepared by INTERA, Inc; (v) Revised Phase 2 QAP and Work Plan, Revision 2.0, July 12, 2011; (vi) Nitrate Corrective Action Plan, May 7, 2012 (HGC 2012b), prepared by Hydro Geo Chem, Inc.; (vii) Nitrate Contamination investigation Report, December 30, 2009, prepared by INTERA, Inc.; (viii) Stipulation and Consent Order Docket No. UGW12-04 between DUSA and the Director, December 12, 2012; (ix) Nitrate CACME UDEQ Docket UGW12-04, December 11, 2017 prepared by Hydro Geo Chem, Inc., Inc.; and (x) Phase Ill Nitrate Corrective Action Planning Document and Recommended Phase Ill Corrective Action Docket UGW12-04, White Mesa Mill, December 13, 2018 prepared by Hydro Geo Chem, Inc. 2.0 INFORMATION PROVIDED IN SUPPORT OF THE APPLICATION 2.1 Name and Address of Applicant and Owner (R317-6-6.3.A) The Applicant and Mill Operator is Energy Fuels Resources (USA) Inc. EFRI is the current holder of the Permit. The Mill is owned by EFRI' s affiliate, EFR White Mesa LLC ("EFRWM"). The address for both EFRI and EFRWM is: 225 Union Boulevard, Suite 600 Lakewood, CO 80228 Telephone: 303-974-2140 Fax: 303-389-4125 Contacts at EFRI, all located at the aforementioned office: David C. Frydenlund Chief Financial Officer, General Counsel and Corporate Secretary Direct telephone: 303-389-4130 dfrydenlund@energyfuels.com 18 Scott Bakken Vice President, Regulatory Affairs Direct telephone: 303-389-4132 sbakken@energyfuels.com Kathy Weinel Director, Regulatory Compliance Direct telephone: 303-389-4134 kweinel@energyfuels.com 2.2 Legal Location of the Facility (R317-6-6.3B) The Mill is regionally located in central San Juan County, Utah, approximately 6 miles (9.5 km) south of the city of Blanding. The Mill can be reached by taking a private road for approximately 0.5 miles west of Utah State Highway 191. See Figure 1. Within San Juan County, the Mill is located on fee land and mill site claims, covering approximately 5,415 acres, encompassing all or part of Sections 21, 22, 27, 28, 29, 32, and 33 of T37S, R22E, and Sections 4, 5, 6, 8, 9, and 16 of T38S, R22E, Salt Lake Base and Meridian ("SLBM"). See Figure 2. All operations authorized by the Mill License are conducted within the existing site boundary. The milling facility currently occupies approximately 50 acres, and the TMS encompass another 250 acres. See Figure 2. 2.3 Name and Type of Facility (R317-6-6.3.C) The name of the facility is the White Mesa Uranium Mill. The facility is a uranium milling and TMS facility, which operates under a Radioactive Materials License issued by the Director of the DWMRC under UAC R313-24. The Mill produces uranium in the form of U30s from conventional ores and alternate feed materials. Alternate feed materials are uranium bearing materials other than conventionally mined ores. The Mill also produces vanadium, in the form of vanadium pentoxide ("V20s"), ammonia metavanadate ("AMY") and vanadium pregnant liquor ("VPL"), from certain conventional ores. The Mill has produced other metals from certain alternate feed materials (specifically tantalum and niobium as authorized under NRC License amendment 4, included as Attachment A). In addition, the Mill also processes uranium-bearing natural ores for the production of uranium and a Rare Earth Element ("REE") carbonate. Construction of the Mill was completed and first operations commenced in May 1980. The Mill does not have a set operating life, and can operate indefinitely, subject to available TMS capacity and license and permit renewals. EFRI has submitted a GWDP and RML amendment application to construct, operate and (when operations are complete) reclaim proposed Cells 5A and 5B. The amendment request is currently in progress by DWMRC. Upon completion of the DWMRC review, the RML will be subject to a Public Comment period. The construction of Cells 5A and 5B is an essential element of future operations at the Mill as their construction is necessary in order to continue providing sufficient impoundment surface area for the evaporation of Mill process water, and to provide additional tailings capacity which is necessary to 19 accommodate the tailings volume associated with routine processing operations. At this time, EFRI does not anticipate the construction of Cells 5A and SB immediately upon the Director's approval of the License and GWDP amendments; however, authorization is being sought in advance to allow the Mill to respond to future needs. The conceptual and permitted total capacity is for the quantity of Mill tailings produced from a 15-year operating period at a rate of 2,000 tons per day, operating 340 days per year. Since it commenced operations in 1980, the Mill has operated on a campaign basis, processing conventional ores and alternate feed materials as they become available and as economic conditions warrant. 2.4 A Plat Map Showing All Water Wells, Including The Status And Use Of Each Well, Drinking Water Source Protection Zones, Topography, Springs, Water Bodies, Drainages, And Man-Made Structures Within A One-Mile Radius Of The Discharge. (R317-6-6.3.D) There are five deep wells within a one mile radius of the Mill, two of which supply the Mill facility. There are no Drinking Water Source Protection Zones or ordinances within this radius. Routine groundwater monitoring wells have been established for monitoring under the Permit. These monitoring wells are depicted on Figure 10 and in Appendix B to this Application. The depth and purpose of each of these wells is as shown in Tables 1.2-1, 1.2-2, and 2.4-1. See Section 2. 9 .1.3 below for a detailed description of the Mill's groundwater monitoring program. The surface topography and man-made structures are shown on Figures presented in Appendix B. See Sections 2.5.4 and 2.5.7 below for a more detailed discussion on local topography and land use. In addition, see the biennial land use reports from 2018, 2020 and 2022 for details regarding land use (EFRI 2018, 2020, 2022). The Mill area has several dry drainages, and the only nearby natural water bodies within one mile are Westwater Creek, Corral Creek and Cottonwood Creek. In addition to these are Ruin Spring and several other springs and seeps located within a 1.5 mile radius of the Mill. See Sections 2.5.3 and 2.13 below for discussions relating to seeps and springs in the vicinity of the site and to surface water and drainages, respectively. 2.5 Geologic, Hydrologic, and Agricultural Description of the Geographic Area (R317-6-6.3.E) 2.5.1 Groundwater Characteristics This Section is based primarily on the Report entitled: Hydrogeology of the White Mesa Uranium Mill, Blanding Utah July 13, 2022, prepared by Hydro Geo Chem, Inc. ("HGC") (the "2022 HGC Report" referred to as HGC, 2022). Other reports are referenced as needed. 2.5.1.1 Geologic Setting The Mill is located within the Blanding Basin of the Colorado Plateau physiographic province. Typical of large portions of the Colorado Plateau province, the rocks underlying the site are relatively undeformed. The average elevation of the site is approximately 5,600 ft (1,707 m) above mean sea level ("amsl"). The site is underlain by unconsolidated alluvium and indurated sedimentary rocks consisting primarily of sandstone and shale. The indurated rocks are relatively flat lying with dips generally 20 less than 3°. The alluvial materials consist mostly of aeolian silts and fine-grained aeolian sands with a thickness varying from negligible to as much as 25 to 30 feet across the site. In some portions of the site the alluvium is underlain by a few feet to as much as 30 feet of Mancos Shale. In other areas, the Mancos Shale is absent. The alluvium and Mancos (where present) are underlain by the Dakota Sandstone and Burro Canyon Formation, which are sandstones having a combined total thickness ranging from approximately 55 to 140 feet (17 to 43 m). Beneath the Burro Canyon Formation lies the Morrison Formation, consisting, in descending order, of the Brushy Basin Member, the Westwater Canyon Member, the Recapture Member, and the Salt Wash Member. The Brushy Basin and Recapture Members of the Morrison Formation, classified as shales, are very fine-grained and have a very low permeability. The Brushy Basin Member is primarily composed of bentonitic mudstone, siltstone, and claystone. The Westwater Canyon and Salt Wash Members are primarily sandstones but are expected to have a low average vertical permeability due to the presence of interbedded shales. See Figure 3 for a generalized stratigraphic column for the region. Beneath the Morrison Formation lies the Summerville Formation, an argillaceous sandstone with interbedded shales, and the Entrada Sandstone. Beneath the Entrada lies the Navajo Sandstone. The Navajo and Entrada Sandstones constitute the primary aquifer in the area of the site. The Entrada and Navajo Sandstones are separated from the Burro Canyon Formation by approximately 1,000 to 1,100 feet (305 to 335 m) of materials having a low average vertical permeability. Groundwater within this system is under artesian pressure in the vicinity of the site, is of generally good quality, and is used as a secondary source of water at the site. 2.5.1.2 Hydrogeologic Setting The site is located within a region that has a dry to arid continental climate, with average annual precipitation of approximately 13.3 inches, and an average annual lake evaporation rate of approximately 47.6 inches. Recharge to the principal aquifers (such as the Navajo/Entrada) occurs primarily along the mountain fronts (for example, the Henry, Abaja, and La Sal Mountains), and along the flanks of folds such as Comb Ridge Monocline. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth of the aquifer (approximately 1,200 feet below land surface [ft bls]) makes access difficult. The Navajo/Entrada aquifer is capable of yielding significant quantities of water to wells (hundreds of gallons per minute [gpm]). Water in on-site wells completed within the Navajo/Entrada rises approximately 800 feet above the base of the overlying Summerville Formation. The shallowest groundwater beneath the site consists of perched water hosted primarily by the Burro Canyon Formation. Perched water is used on a limited basis to the north (upgradient) of the site because it is much shallower and more easily accessible than the deep Navajo/Entrada aquifer. 2.5.1.3 Perched Zone Hydrogeology Perched groundwater originates mainly from precipitation and local recharge sources such as unlined reservoirs (Kirby, 2008) and is supported within the Burro Canyon Formation by the underlying, fine-grained Brushy Basin Member. Perched groundwater at the site is generally of 21 poor quality due to high TDS in the range of approximately 1,100 to 7,900 mg/L. Its relatively poor quality is one reason that perched water is used primarily for stock watering and irrigation in areas upgradient (north) of the site. Figure 4 is a contour map showing the approximate elevation of the contact of the Burro Canyon Formation with the Brushy Basin Member, which essentially forms the base of the perched water zone at the site. Based on Figure 4, the Burro Canyon Formation/Brushy Basin Member contact generally dips to the south/southwest beneath the site. Figure 5 is a perched groundwater elevation contour map for the fourth quarter, 2021. Based on the contoured water levels, groundwater within the perched zone flows generally south to southwest beneath the site. Beneath the TMS, perched groundwater flow is generally to the southwest. Perched groundwater discharges from outcrops of the Burro Canyon Formation in seeps and springs along Westwater Creek Canyon and Cottonwood Canyon (to the west-southwest of the mill site and TMS) and along Corral Canyon (to the east and northeast of the mill site and TMS). Known discharge points include the seeps and springs shown in Figure 5 except Cottonwood Seep. As discussed in (HGC, 2014; 2018a; and 2022), Cottonwood Seep is located more than 1,500 feet west of White Mesa in an area where the Dakota Sandstone and Burro Canyon Formation (which hosts the perched water system) are absent due to erosion, and at an elevation approximately 230 feet below the base of the perched zone defined by the contact between the Burro Canyon Formation and the underlying Brushy Basin Member. Cottonwood Seep occurs near the contact between the slope-forming Brushy Basin Member and the underlying Westwater Canyon (sandstone) Member. Contact elevations shown in Figure 4 are based on perched monitoring well drilling and geophysical logs and surveyed land surface elevations, and the surveyed elevations of Westwater Seep and Ruin Spring. The elevations of Westwater Seep and Ruin Spring are included in the kriged contours because they occur at the contact between the Burro Canyon Formation and the underlying Brushy Basin Member. Groundwater elevations shown in Figure 5 include the surveyed elevations of all seeps and springs except Cottonwood Seep. As discussed above, no evidence exists to connect Cottonwood Seep to the perched water system. Although Cottonwood Seep may potentially receive some contribution from perched water, its occurrence near the contact between the Brushy Basin Member and the underlying Westwater Canyon Member indicates that its elevation is not representative of the perched water system. The permeabilities of the Dakota Sandstone and Burro Canyon Formation at the site are generally low. No significant joints or fractures within the Dakota Sandstone or Burro Canyon Formation have been documented in any wells or borings installed across the site (Knight Piesold, 1998). Any fractures observed in cores collected from site borings are typically cemented, showing no open space. Porosities and water contents of the Dakota Sandstone have been measured in samples collected during installation of former well MW-16 and well MW-17 (Figure 5). MW-16 was located immediately downgradient of TMS Cell 3 (beneath Cell 4B); and MW-17 is located south of 22 TMS Cell 4A at a location primarily cross-gradient with respect to perched water flow. Porosities of the Dakota Sandstone range from 13.4% to 26%, averaging 20%, and water saturations range from 3.7% to 27.2%, averaging 13.5%. The average volumetric water content is approximately 3%. The hydraulic conductivity of the Dakota Sandstone based on packer tests in borings installed at the site prior to 1994 ranges from 2. 71 x 1 o-6 centimeters per second ("crn/s") to 9.12 x 10-4 crn/s, with a geometric average of 3.89 x 10-5 emfs (TIT AN, 1994). The average porosity of the Burro Canyon Formation is similar to that of the Dakota Sandstone. Based on samples collected from the Burro Canyon Formation at former well MW-16 porosity ranges from 2% to 29.1 %, averaging 18.3%, and water saturations of unsaturated materials range from 0.6% to 77.2%, averaging 23.4% (TITAN, 1994). These porosities are similar to those reported by MWH (MWH, 2010) for archived samples from borings MW-23 and MW-30. Extensive hydrogeologic characterization of the saturated Burro Canyon Formation has occurred through hydraulic testing of perched monitoring wells and borings at the site. Hydraulic testing of MW-series wells located upgradient, cross-gradient, downgradient, and within the millsite and TMS, TW4-series wells located cross-gradient to upgradient of the millsite and TMS, TWN- series wells located primarily upgradient of the millsite and TMS, and DR-series piezometers, located downgradient of the TMS, indicate that the hydraulic conductivity of the perched zone ranges from approximately 2 x 10-8 to 0.01 crn/s. TIT AN (1994 ), reported that the hydraulic conductivity of the Burro Canyon Formation ranges from 1.9 x 10-7 to 1.6 x 10 -3 emfs, with a geometric mean of 1.01 x 10-5 emfs, based on the results of 12 pumping/recovery tests performed in monitoring wells and 30 packer tests performed in borings prior to 1994. The range reported by TITAN (1994) is within the hydraulic conductivity range of approximately 2 x 10-8 to 0.01 emfs reported by HGC (HGC, 2014; 2018a; and 2022). In general the highest permeabilities and well yields are in the area of the site immediately northeast and east (upgradient to cross gradient) of the TMS. A relatively continuous, higher permeability zone (associated with poorly indurated coarser-grained materials in the general area of the chloroform plume) has been inferred to exist in this portion of the site. Analysis of drawdown data collected from this zone during long-term pumping of MW-4, MW-26 (TW 4-15), and TW 4-19 (Figure 5) yielded estimates of hydraulic conductivity ranging from approximately 4 x 10-5 to 1 x 10-3 emfs (HGC, 2014; 2018a; and 2022). The decrease in perched zone permeability south to southwest of this area (south of TW4-4), based on tests at TW4-6, TW4-26, TW4-27, TW4-29 through TW4-31, and TW4-33 and TW4-34, indicates that this higher permeability zone "pinches out". Relatively high conductivities measured at MW-11, located on the southeastern margin of the downgradient edge of TMS Cell 3, and at MW-14, located on the downgradient edge of TMS Cell 4A, of 1.4 x 10-3 crn/s and 7.5 x 10-4 crn/s, respectively, may indicate that this higher permeability zone extends beneath the southeastern portion of the TMS. However, based on hydraulic tests south and southwest of these wells, this zone of higher permeability does not appear to exist within the saturated zone downgradient (south-southwest) of the TMS. Furthermore, as discussed in HGC (2018b), although the hydraulic conductivity is relatively high 23 at both MW-11 and MW-14, the higher permeability materials penetrated by these wells do not appear to connect. Slug tests performed at groups of wells and piezometers located northeast (upgradient) of, in the immediate vicinity of, and southwest (downgradient) of the TMS indicate generally lower permeabilities compared with the area of the chloroform plume. The following results are based on analysis of automatically logged slug test data using the KGS solution available in AQTESOL V (HydroSOL VE, 2000). Te ting of TWN-edes wells instaUed in the northeast portio11 of the site a part of nitrate inve tigation activitie yielded a hydraulic conductivity range of approximately 3.6 x 10-7 to 0.01 cm/ with a geometric average f approximately 6 x I 0-5 cm/s. lnclL1ding more recently in talled well TWN-20 and TWN-21 (HGC, 2021) yields a geometric average hydraulic conductivity of approximately 5 x 10-5 cm/s. The value of 0.01 cm/s estimated for TWN-16 is the highest mea, med at the site, and the value of 3.6 x 10-7 cm/s estimated for TWN-7 is one of the lowest measured at the site. Testing of MW-series wells MW-23 through MW-32 installed between and at the margins of the TMS in 2005 (and using the higher estimate for MW-23) yielded a hydraulic conductivity range of approximately 2 x 10-7 to 1 x 10-4 cm/ with a geometric average of approximately 2 x 10- cm/s. The geometric average hydraulic conductivity of all te ted MW-erie well · (including far up-gradient; far cross-gradient; and far downgradient well ; and u ing the higher e timate for MW-23) is less than 3 x 10-5 cm/s. Hydraulic test conducted at DR-erie piezometers installed as part of the southwest area investigation dowogradient of the TMS yielded hydraurc conductivitie ranging from approximately 2 x 10·8 to 4 x 104 cm/ with a geometric average of 9.6 x 10-6 cm/·. The low permeabilitie and shallow hydralllic gradi nts downgradjent of the TMS result in average perched groundwater pore velocity e timate that are among the lowest on site (approximately 0.26 feet per year (ft/yr) to 0.91 ft/yr). The extensive hydraulic testing of perched zone wells at the site indicates that perched zone permeabilitie are generally Jow with the exception of the apparently relatively isolated zone of higher permeability a s ciated with the chloroform plume ea t to norlhea t (cro -gradient to upgradie1 t) of the TMS (Figure 5). The geometric average hydraulic conductivity (approximately 1 x 10-5 cm/ ) of the DR-eries piezometer · which cover an area nearly half the size of the total monitored area at White Mesa (excluding MW-22), is nearly identical to the geometric average hydraulic conductivity of 1.01 x 10-cm/ reported by TITAN (1994), and is within the range of 5 to 10 feet per year (ft/yr) [approximately 5 x 10-6 emfs to 1 x 10-5 cm/ ] reported by Dames and Moore (1978) [the 1978 ER] for tbe ( aturated) perched zone during the initial site investigation. Becau e of the generally low permeability of the perched zone beneath the site, well yield me typically low (les than 0.5 gpm), although su tainable yields of as much as 4 gpm (for example, at TW4-19 hown in Figure 5) have been (at least temporarily) possible in wells intercepting the relatively large saturated thicknesses within the higher pe1111eability zone located east to northeast (cross-gradient to upgradient) of the TMS at the ite. However, even site wells that 24 yielded as much as 4 gpm during the first few months of pumping eventually saw yields drop to about 1 gpm or less. As of the fourth quarter of 2021, total sustainable pumping from the 16 wells comprising the chloroform and nitrate pumping systems was just under 6 gpm. Sufficient productivity from the perched zone can generally be obtained only in areas where the saturated thickness is greater, which is one reason that 1) some perched zone wells completed near the northern wildlife ponds are relatively productive and 2) the perched zone has been used on a limited basis as a water supply to the north (upgradient) of the site. Due to the continuing decay of the perched groundwater mounds associated with former wildlife pond usage, and consequent reductions in saturated thicknesses, productivities of on-site wells are expected to continue to decline. 2.5.1.4 Perched Groundwater Flow Perched groundwater flow at the site has historically been to the south/southwest. Figure 5 groundwater elevations indicate that beneath and south of the TMS, in the west central portion of the site, perched water flow is south-southwest to southwest. Flow on the western margin of White Mesa is generally south, approximately parallel to the mesa rim (where the Burro Canyon Formation [and perched zone] is terminated by erosion). On the eastern side of the site, perched water flow is also generally southerly. Near the formerly used northern wildlife ponds, flow direction ranges locally from southwesterly (west of the ponds) to southeasterly (east of the ponds). A residual groundwater mound associated with well TWN-3 (located west of the northern wildlife pond) likely results from low permeability and possibly enhanced recharge in the vicinity due to graded areas of the Mill site having relatively flat topography and relatively slow runoff. Although the water level at TWN-3 remains relatively elevated, the formerly elevated water level at TWN-2 has declined due to pumping. Cones of depression result from pumping of chloroform wells MW-4, MW-26, TW4-1, TW4-2, TW4-4, TW4-ll, TW4-19, TW4-21, TW4-37, TW4-39, TW4-40 and TW4-41; and nitrate wells TWN-02, TW4-22, TW4-24, and TW4-25 (Figure 10). These wells are pumped to reduce chloroform and nitrate mass in the perched zone east and northeast of the TMS. The cones of depression resulting from pumping of these wells are evident in the water level contours shown on Figure 5. In general, perched groundwater elevations have not changed significantly at most of the site monitoring wells since installation, except in the vicinity of the wildlife ponds and the pumping wells. For example, relatively large increases in water levels occurred between 1994 and 2002 at MW-4 and MW-19, located in the east and northeast portions of the site, respectively. These water level increases in the northeastern and eastern portions of the site were the result of seepage from formerly used wildlife ponds located near piezometers PIEZ-1 through PIEZ-5 shown in Figure 5, which were installed in 2001 for the purpose of investigating these changes. The mounding associated with the formerly used wildlife ponds and the resulting general increase in water levels in the northeastern portion of the site caused local steepening of groundwater gradients over portions of the site. Conversely, pumping of chloroform wells MW- 4, MW-26, TW4-1, TW4-2, TW4-4, TW4-ll, TW4-19, TW4-21, TW4-37, TW4-39, TW4-40 and TW4-41; and nitrate wells TWN-02, TW4-22, TW4-24, and TW4-25; has depressed the perched water table locally and reduced average hydraulic gradients to the south and southwest 25 of these wells. In addition, at the request of DWMRC, water has not been delivered to the northern wildlife ponds since March, 2012. The perched water mound associated with recharge from the formerly used ponds is diminishing and is expected to continue to diminish, thereby reducing saturated thicknesses, as well as hydraulic gradients downgradient of the ponds, in particular to the south and southwest. As discussed above, perched water discharges in springs and seeps along Westwater Creek Canyon and Cottonwood Canyon to the west-southwest of the site, and along Corral Canyon to the east of the site. The known discharge points located directly downgradient of the TMS are Westwater Seep and Ruin Spring. These features are located more than 2,000 feet west- southwest and more than 9,000 feet south-southwest of the TMS as shown in Figure 5. DR-8, located approximately 4,000 feet southwest of the TMS, is located near the mesa rim above Cottonwood Seep along a line between the TMS and Cottonwood Seep. There is no evidence to connect Cottonwood Seep to the perched water system as it is separated from the perched water by approximately 230 feet of low permeability shale and mud tone . However under hypothetical condition ' that Cottonwood Seep receives ome contribution from perched water perched water passing beneath the TMS would pre umably pac;s by DR-8 before continuing on an unidentified potential pathway toward Cottonwood Seep ('potential path' shown in Figure 5). Figure 5 shows perched water pathlines southwest of the TMS based on fourth quarter, 2021 perched water level data. Paths 1 and 3 repre ent the shortest pathlines to di ·charge point. Westwater Seep and Ruin Spring, respectively. Path 2 i the shorte 't pathline to DR-8, located near the edge of the mesa above Cottonwood Seep. A · noted above, a potential pathJjne i drawn from DR-8 to Cottonwood Seep. Although there is no evidence to connect Cottonwood Seep to the perched water system, this potential pathline is represented to allow for the possibility of an as yet unidentified connection. Westwater Seep is downgradient of TMS Cell 1 and the western po1tions of Cells 2, 3, and 4B. DR-8 is downgradient of TMS Cells 2, 3 and 4B. Ruin Spring is downgradient of Cell 4A, and the eastern portions of Cells 2, 3, and 4B. 2.5.1.5 Perched Zone Hydrogeology Beneath And Downgradient Of The TMS The perched zone hydrogeology southwest ( downgradient) of the TMS is imilar to other areas of the site except that the saturated thicknesse:s are generally smaller, portions of the perched zone are dry, and hydraulic gradients and hydraulic conductivities are relatively low. The combination of shallow hydraulic gradients, relatively low permeabilities, and small saturated thicknesses, results in rates of perched water movement that are among the lowest on-site. In the immediate vicinity of the TMS, perched water was encountered at depths of approximately 58 to 114 ft below the top of casing ("btoc") as of the fourth quarter of 2021 (Figure 7). Beneath TMS Cell 3, depth, to water ranged from approximately 69 feet btoc near the northea t (upgradient) corner of the ceJI to approximately L 14 feet btoc at the southwest (down gradient) corner of the cell. Assuming an average depth of the ba e of TMS Cell 3 of 25 feet below grade this corresponds to perched water depths of approximately 44 to 89 feet below the base of the cell; the average depth to water is approximately 67 feet beneath the base of the cell. 26 Beneath TMS Cells 4A and 4B, depths to water ranged from approximately 81 feet btoc near the northeast (upgradient) corner of Cell 4A to approximately 114 feet btoc along the western margin of Cell 4B. Assuming an average depth of the base of TMS Cells 4A and 4B of 25 feet below grade, this corresponds to perched water depths of approximately 56 to 89 feet below the base of the cells; the average depth to water is approximately 79 feet beneath the base of the cells. The saturated thickness of the perched zone in the immediate vicinity of the TMS as of the fourth quarter of 2021 ranges from approximately 74 feet to negligible (Figure 8). Beneath TMS Cell 3, the saturated thickness varies from approximately 58 feet in the eastern portion of the cell to approximately 8 feet in the western portion of the cell. Beneath TMS Cells 4A and 4B, the saturated thickness varies from approximately 47 feet along the north dike of Cell 4A to negligible in the southwestern portion of Cell 4B, where a dry zone, defined by MW-33 and former (historically dry) well MW-16, is present. Saturated thicknesses in the southwest area of the site are affected by the ridge-like high in the Burro Canyon Formation/Brushy Basin Member contact (see Figure 4). As shown in Figures 5 and 8, dry to low saturated thickness conditions are associated with this paleoridge. South-southwest of the TMS, the saturated thickness ranges from negligible at MW-21 (historically dry) to approximately 25 feet at DR-9. Small saturated thicknesses (less than or about equal to 3 feet) near DR-6, DR-7, and DR-10 (west and southwest of Cell 4B) result from the paleoridge. The average saturated thickness based on measurements at MW-37, DR-13, MW- 3, MW-20, and DR-21, which lay close to a line between the southeast portion of TMS Cell 4B and Ruin Spring, is approximately 11 feet. The average saturated thickness based on measurements at MW-35, DR-7, and DR-6, which are the points closest to a line between the southeast portion of TMS Cell 3 and Westwater Seep, is approximately 6 feet. Perched zone hydraulic gradients currently range from a maximum of approximately 0.098 feet per foot (ft/ft) east of Cell 2 (within and in the vicinity of the chloroform plume, between TW4-2 and TW4-3) to approximately 0.0021 ft/ft in the northeast corner of the site (between TWN-19 and TWN-16). Hydraulic gradients in the southwest portion of the site are typically close to 0.01 ft/ft, but the gradient is less than 0.005 ft/ft west/southwest of TMS Cell 4B, between Cell 4B and DR-8. The overall average site hydraulic gradient, between TWN-19 in the extreme northeast to Ruin Spring in the extreme southwest, is approximately 0.011 ft/ft. The hydraulic gradient between the west dike of TMS Cell 3 and Westwater Seep is approximately 0.0136 ft/ft, and between the south dike of TMS Cell 4B and Ruin Spring, approximately 0.0116 ft/ft 2.5.2 Groundwater Quality 2.5.2.1 Entrada/Navajo Aquifer The Entrada and Navajo Sandstones are prolific aquifers beneath and in the vicinity of the site. Water supply wells at the site are screened in both of these units, and therefore, for the purposes of this discussion, they will be treated as a single aquifer. Water in the Entrada/Navajo Aquifer is under artesian pressure, rising 800 to 900 ft above the top of the Entrada's contact with the overlying Summervillle Formation; static water levels are 390 to 500 ft below ground surface. 27 Within the region, this aquifer is capable of yielding domestic quality water at rat of 150 to 225 gpm, and for that reason, it serves as a secondary source of water for the Mill. Additionally, two domestic water supply wells drawing from the Entrada/Navajo Aquifer are located 4.5 miles southeast of the Mill site on the Ute Mountain Ute Reservation. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth of the aquifer (>1,000 ft bls) makes access difficult. Table 2.5.2.1-1 i a tabulation of groundwater quality of the Navajo Sand tone aqu ifer a reported in the FES and sub equeat ampling. TDS range from 244 to 1, J 10 mg/liter in three ample taken over a period from January 27, 1977, to May 4 1977. High iron (0.057 mg/liter) concenn·atjons are found in the Navajo Sandstone. Because the Navajo Sandstone aquifer is isolated from the perched groundwater zone by approximately 1,000 to 1,100 ft of materials having a Jow average vertical permeability, . ampling of the Navajo Sandstone is not required un der the Mill's previou NRC Po.int of Compliance monitoring program or under the Permit. However, samples were taken at two other deep aquifer wells (#2 and #5) on site (See Figure 9 for the locations of these wells), on June 1, 1999 and June 8, 1999, respectively, and the results are included in Table 2.5.2.1-1. 2.5.2.2 Perched Groundwater Zone Perched groundwater in the Dakota/Burro Canyon Formation is u ed on a limited basis to the north (upgradient) of the ite becau e it is more easily acces ible. The quality of the Burro Canyon perched water beneath and downgrad.ient from the ite i poor and extremely variable. The concentrations of TDS measured in water sampled from upgradient and downgradjent well range between approximately 1. l 00 to 7 900 mg/L. Sulfate concentrations measured in three upgradient well. varied between 670 and 1,740 mg/1 (Titan, 1994). The perched groundwater therefore i u ed primarily for stock watering and irrigation. The aturated thiclcne of the perched water zone generally increase to the north of the site. See Section 2.11.2 below for a more detailed discussion of background ground water quality in the perched zone. 2.5.3 Springs and Seeps As discussed in Section 2.5.1.4, perched groundwater at the Mill site discharges in springs and seeps along Westwater Creek Canyon and C ttonwood Canyon to the west-southwest of Lhe ite, and along Corral Canyon to the east of the site where the Burro Canyon Formation outcrop ·. Water samples have been collected and analyzed from ~-prings and seep in the Mill. vicinjty a part of the baseline field investigations reported in the 1978 ER (See Table 2.6-6 in the I 978 ER). During the period 2003-2004, EFRI implemented a sampling program for seeps and springs in the vicinity of the Mill which had been sampled in 1978, prior to the Mill's construction. Four locations were designated for sampling, as shown on Figure 9. These are Ruin Spring (G3R), Cottonwood Seep (G4R), west of Westwater Creek (G5R) and Corral Canyon (GlR). During the 2-year study period only two of the four locations could be sampled, Ruin Spring and Cottonwood Canyon. The other two locations, Corral Creek and the location west of Westwater Creek were not flowing (seeping), and samples could not be collected. With regard to the 28 Cottonwood seep, while water was present, the volume was not sufficient to complete all determinations, and only organic analyses were conducted. Analysis of the Cottonwood Seep water samples did not detect any organics. Samples at Ruin Spring were analyzed for major ions, physical properties, metals, radionuclides, volatile and semi-volatile organic compounds, herbicides and pesticides, and synthetic organic compounds. With the exception of one chloromethane detection, all organic determinations were at less than detectable concentrations. The detection of chloromethane is not uncommon in groundwater and can be due to natural sources. The results of sampling for the other parameters tested are shown in Table 2.5.3-1. The results of the 2003/2004 sampling did not indicate the presence of mill derived groundwater constituents and are representative of background conditions. As required by Part I.E.6 of the Permit, the Mill has implemented a Sampling Plan for Seeps and Springs. Per Part I.E.6 of the Permit, sampling of seeps and springs in required annually. A copy of the currently approved Sampling Plan for Seeps and Springs Revision 3, dated November 11, 2019, is included as Appendix C to this Application. A summary of sampling results from the 2009 through 2022 sampling events, performed under the approved Sampling Plans for Seeps and Springs, is provided in Table 2.5.3-2 through Table 2.5.3-5. 2.5.4 Topography The Mill site is located on a gently sloping mesa that, from the air, appears similar to a peninsula, as it is surrounded by steep canyons and washes and is connected to the Abajo Mountains to the north by a narrow neck of land. On the mesa, the topography is relatively flat, sloping at less than one (1) percent to the south and nearly horizontal from east to west. See also Figure 6. 2.5.5 Soils The majority (99%) of the soil at the Mill site consists of the Blanding soil series (1978 ER, Section 2.10.1.1 ). The remaining 1 % of the site is in the Mellenthin soil series. Because the Mellenthin soil occurs only on the eastern-central edge of the site (1978 ER, Plate 2.10-1), the FES (Section 2.8) concluded that it should not be affected by Mill construction and operation. The Mill and TMS are located on Blanding silt loam, a deep soil formed from wind-blown deposits of fine sands and silts. Although soil textures are predominantly silt loam, silty-clay- loam textures are found at some point in most profiles (See Appendix D to this Application - Results of Soil Analysis at Mill Site). This soil generally has a 4 to 5 inch reddish-brown, silt- loam A horizon and a reddish-brown, silt-loam to silty-clay-loam B horizon. The B horizon extends downward about 12 to 16 inches where the soil then becomes calcareous silt-loam or silty-clay-loam, signifying the C horizon. The C horizon and the underlying parent material are also reddish-brown in color. The A and B horizon both are non-calcareous with an average pH of about 8.0, whereas the C horizon is calcareous with an average pH of about 8.5. Subsoil sodium levels range up to 12% in some areas, which is close to the upper limit of acceptability for use in reclamation work (1978 29 ER, Sect. 2.10.1.1). Other elements, such as boron and selenium, are well below potentially hazardous levels. Potassium and phosphorus values are high in this soil (1978 ER, Table 2.10-2) and are generally adequate for plant growth. Nitrogen, however, is low (1978 ER, Sect. 2.10.1.1) and may have to be provided for successful revegetation during final reclamation. With well-drained soils, relatively flat topography (see Section 2.5.4), and limited annual precipitation (see Section 2.5.1.2), the site generally has a low potential for water erosion. However, the flows resulting from thunderstorm activity are nearly instantaneous and, without the Mill's design controls, could result in substantial erosion. When these soils are barren, they are considered to have a high potential for wind erosion. Although the soil is suitable for crops, the low percentage of available moisture (6 to 9%) is a limiting factor for plant growth; therefore, light irrigation may be required to establish native vegetation during reclamation. 2.5.6 Bedrock Subsurface conditions at the Mill site area were investigated as part of the 1978 ER by drilling, sampling, and logging a total of 28 borings which ranged in depth from 6.5 to 132.4 ft. Of these borings, 23 were augured to bedrock to enable soil sampling and estimation of the thickness of the soil cover. The remaining 5 borings were drilled through bedrock to below the perched water table, with continuous in situ permeability testing where possible and selective coring in bedrock. The soils encountered in the borings were classified, and a complete log for each boring was maintained. See Appendix A of Appendix H of the 1978 ER. Borings in the footprint of the existing TMS reported calcareous, red-brown sands and silts from the surface to a depth of 15 ft, averaging over 7 ft. Borings in the general area of the Mill site and the TMS reported calcareous, red-brown sands and silts from the surface to a depth of 14 ft, averaging over 9 ft. Downgradient of the TMS, calcareous sands and silts extend to a depth of 17 ft of the surface. The calcareous silts and sands of the near-surface soils grade to weathered claystones or weathered sandstones, inter-layered with weathered claystone and iron staining. At depth, the weathered claystone or weathered clayey sandstone grade into sandstone with inter- layered bands of claystone, gravel, and conglomerate. Some conglomerates are cemented with a calcareous matrix. 2.5.7 Agricultural and Land Use Description of the Area Approximately 60% of San Juan County is federally owned land administered by the U.S. Bureau of Land Management (41%), the National Park Service (10%), and the U.S. Forest Service (9% ). Primary land uses include livestock grazing, wildlife range, recreation, and exploration for minerals, oil, and gas. Approximately 23% of the county is Native American land owned either by the Navajo Nation or the Ute Mountain Ute Tribe. Approximately 8% of the county is state-owned land, 8% privately-owned land and 1 % Indian Trust land. The area within 5 miles of the Mill site is predominantly range land owned by residents of Blanding. The Mill site itself, including TMS, encompasses approximately 300 acres. A more detailed discussion of land use at the Mill site, in surrounding areas, and in southeastern Utah, is presented in the FES (Section 2.5). Results of archeological studies conducted at the site and in the surrounding areas as part of the 1978 ER are also documented in the FES (Section 2.5.2.3). 30 2.5.8 Well Logs Well/boring logs for wells MW-1 (general monitoring well), MW-2, MW-3, MW-4 (not a compliance well under the Permit), MW-5 MVv-11, MW-12, MW-14, MW-15, MW-16 (not a compliance well under the Pe1mit and abandoned during the con truction of Tailing Ce!J 4B), MW-17, MW-18 (general. monitoring well) and MW-19 (general monitoring welJ), are included as Appendix A to the 1994 Titan Report. A copy of the 1994 Titan Report was previou ly submitted under separate cover. Lithologic and core logs for wells MW-3A, MW-23, MW-24, MW-25, MW-27, MW-28, MW- 29, MW-30 and MW-31 are included as Appendix A to the Report: Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill April Through June 2005, August 3, 2005, prepared by Hydro Geo Chem, Inc. A copy of that Report was previously submitted under separate cover. Lithologic and core logs for well MW-26 (previously named TW4-15) and well MW-32 (previously named TW4-17) are included a Appendix A to the Letter Report dated August 29, 2002, prepared by Hydro Geo Chern, Inc. and addressed to Harold Roberts. Lithologic and core logs for well MW-33, MW-34 and well MW-35 are included a Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-33, MW-34 and MW-35 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chem, Inc. October 11, 2010. A copy of that Rep01t was previously submitted under separate cover. Lithologic and core logs for well MW-36 and weU MW-37 are included a Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-36 and MW-37 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chem, In c. June 28, 2011. A copy of that Report was previously submitted under separate cover. Lithologic and core logs for well MW-38 MW-39 and well MW-40 are included as Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-38, MW-39 and MW- 40 at the White Mesa Uranium Mill Near Blandin Utah, prepared by Hydro Geo Chem, Inc. June 12, 2018. A copy of that Report was previously submitted under separate cover. The Lithologic and core log for well MW-24A are included as Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-36 and MW-37 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chem, Inc. January 29, 2020. A copy of that Report was previously submitted under separate cover. 2.6 The Type, Source, and Cl1emical Physical, Radiological, and Toxic Characteristics of the Effluent or Leachate to be Discharged (R317-6-6.3.F) The Mill is designed not to discharge to groundwater or surface waters. Instead, the Mill utilizes the TMS for disposal or evaporation of Mill effluents as indicated below: • Cell 1: dedicated to evaporation of Mill solutions; • Cell 2: contains Mill tailings, has an interim cover and is closed to future tailings disposal; 31 • Cell 3: contains Mill tailings and is in the final stages of filling; • Cell 4A: receives Mill tailings and is used for evaporation of Mill solutions; and • Cell 48: authorized to receive Mill tailings but currently is used only for evaporation of Mill solutions. See Sections 2. 7 .2 through 2. 7.4 below for a more detailed discussion of the Mill's TMS. The projected chemical and radiological characteristics of tailings solutions were assessed by Energy Fuels Nuclear, Inc., a predecessor operator of the Mill, and NRC in 1979 and 1980, respectively. In addition, early samples were assessed by D' Appolonia Engineering as the Mill started operations to further evaluate and project the character of the solutions. Samples of tailings after the Mill was fully operational were collected by NRC (1987), EFRI/UDEQ (2003), and EFRI (2007 -2013). Samples collected in 2003 were obtained under the oversight of DWMRC personnel. The Samples collected in 2007 and 2008 were obtained by EFRI on a voluntary basis as the then proposed Tailings and Slimes Drain Sampling Plan (the "Tailings Sampling Plan") had not been approved by the Director at that time. The 2009 samples were collected on August 6, 2009 under the Tailings Sampling Plan that was approved at that time. Subsequent annual sampling has been performed annually under an approved Tailings Sampling Plan. A copy of the currently approved Tailings Sampling Plan is included as Appendix L. The chemical and radiological characteristics of the solutions held in the TMS, based on the sample results described above, are provided in the tables included in Appendix E, which list the concentration of parameters measured in accordance with the Permit. There is no active discharge from the TMS; therefore, an estimation of the flow rate ("gpd") is not applicable in this instance. However, when operating at full capacity, the Mill discharges approximately 2000 tons per day of dry tailings and approximately 600 gpm of solutions to the Mill's TMS. 2.7 Information Which Shows that the Discharge can be Controlled and Will Not Migrate Into or Adversely Affect the Quality of any Other Waters of the State (R317-6-6.3.G) 2.7.1 General The Mill has been designed as a facility that does not discharge to groundwater or surface water. All tailings and other Mill wastes are disposed of permanently into the Mill's TMS. Excess waters are disposed of in the tailings or evaporation cells, where they are subject to evaporation, or re-processed through the Mill circuit. See Section 2.6. The Mill was also designed and constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the TMS; and b) diverting mnoff from surrounding areas away from the Mill site. The Permit therefore does not authorize any discharges to groundwater or surface water, but is intended to protect against potential inadvertent or unintentional discharges, such as through potential failure of the Mill's TMS. 32 The Mill's TMS is currently comprised of five cells (Cells 1, 2, 3 4A, and 4B). Currently, Cells 3 and 4A are active tailings cells. Cells 1 and 4B are nonconventional impoundments used for evaporation only. Cell 4B is authorized to receive Mill tailings but currently is used only for evaporation of Mill olutions. Diagram. hawing the Mill facility layout, including the existing TMS structures are included as Figures 10 and 11 to this Application. The following sections de cribe the primary Discharge Minimization Technology ("DMT") and Best Available Technology(' BAT ) features of the Mill, which demonstrate that the wastes and tailings at the Mill can be controlled so that they do not migrate into or adversely affect the quality of any waters of the State including groundwater and surface water. 2.7.2 Cells 1, 2 and 3 2. 7.2.1 Design and Construction of Cells 1, 2 and 3 Construction of Cell 2 was completed on May 3, 1980, construction of Cell 1 was completed on June 29, 1981, and construction of Cell 3 was completed on September 15, 1982. Each of Cells 1, 2 and 3 are constructed below grade. Each has a single 30 mil PVC flexible membrane liner ("FML") constructed of olvent welded seams on a prepared sub base. A protective soil cover layer was constructed immediately over the FML with a Lhickne of 12- inches on the cell floor and 18-inches on the interior . ide lope. The criterion for placement of the FML in Cells 1, 2 and 3 was a smooth ub base with no rock prolrudjng that could potentially damage the FML. The cells were excavated by ripping the in-place Dakota Sandstone with a large dozer. Where the rock could not be efficiently ripped, explosives were used to loosen the rock. The cell bottom was then graded to the final design contours and rolled with a smooth drum vibrating roller. The smooth drum roller effectively crushed the loose sandstone, filling in small holes, and allowed for a smooth surface suitable for liner placement. Due to the excavation method (ripping and blasting) there were some areas that required little or no fill to meet final grade , while other area required pl acement of additional crushed sand tone to meet the final grade. Tbe cell bottom wa ·ometime. re-worked everaJ time to accomplish the desired result. The majority of the cell bottom is covered with a layer (1 to 6 inches) of cru hed sandstone wl1ile the liner in ome area is placed directly on a smooth ro.lled surface of Dakota Sandstone with onJy a thin veneer of re-compa ted and tone. In places where the urface wa rough or contained maU hole , washed concrete and was used to fill or mootb the imperfections, and the area was then rolled one last time before FML placement. Areas of crushed sandstone filled sub base versus areas with little or no crushed sandstone base were not documented during construction. Areas filled or smoothed with washed concrete sand is likely less than 0.1 % of the cell bottoms. Beneath thi · underlay, native , andstone and other foundation materials were graded to drain to a single low point .near the up, tream toe of the ot1th cro · - valley dike. Inside this layer, is an east-west oriented pipe to gather fluid at the up t:ream toe of the cross-valley dike. The crushed sandstone Layer draining to the pipe at the up t.ream toe of the dike of the cell was intended to be a leak detection sy tern for each cell. However becau e the de ·ign of these leak detection systems does rnot meet current BAT tandards, they are not recognized as leak detection systems in the Permit. 33 Each of Cells 2 and 3 also has a slimes drain collection system immediately above the FML, comprised of a nominal 12-inch thick protective blanket layer of soil or comparable material, on top of which is a network of PVC perforated pipe laterals on a grid spacing interval of about 50- feet. These pipe laterals gravity drain to a perforated PVC collector pipe which also drains toward the south dike and is accessed from the ground surface via a non-perforated access pipe. At cell closure, leachate head inside the pipe network will be removed via a submersible pump installed inside the access pipe See Part I.D. l of the Permit for a more detailed description of the design of Cells 1, 2 and 3. After review of the existing design and construction and consultation with the State of Utah Division of Water Quality, the Director determined, in connection with the issuance of the Permit in 2005, that the DMT required under the groundwater quality protection rules (UAC R317-6-6.4(c)(3)) for Cells 1, 2 and 3 that pre-dated those rules will be defined by the current or existing cell construction, with modifications that were included in the Permit (see page 25 of the 2004 Statement of Basis). These modifications focus on changes in monitoring requirements, and on improvements to facility closure. The goal of these improvements is to ensure that potential wastewater losses are minimized and local groundwater quality is protected. The modifications are described in Sections 2.7.2.2, 2.7.2.3 and 2.7.2.4 below. 2. 7.2.2 Improved Groundwater Monitoring Improvements were made to the Mill's groundwater monitoring network at the time of issuance of the original Permit, to meet the following goals: a) Early Detection As previously stated, 31 groundwater wells are monitored to detect any potential leaks from the TMS. Because the leak detection systems for Cells 1, 2, and 3 utilized older, less sophisticated technology, DWMRC required nine new wells be installed adjacent to the TMS in 2005. These wells are used as a first line of defense to detect any potential TMS impacts. These supplemented the existing thirteen wells that were installed prior to the 2005 issuance of the original permit. Of the thirteen wells (MW-01, MW-02, MW-03 [subsequently abandoned], MW-05, MW-11, MW-12, MW-14, MW-15, MW-17, MW-18, MW-19, MW-26, and MW-32) installed prior to 2005, seven of the wells are on the dikes of the cells or immediately adjacent to the cells, three are upgradient, one has been abandoned and replaced and one is downgradient and one is cross gradient. Of the nine wells installed as a result of the 2005 Permit, seven monitoring wells (MW-23, MW-24, MW-25, MW-28, MW-29, MW-30 and MW-31) were added immediately adjacent to or on the dikes of the existing cells. MW-03A and MW-27 are downgradient and upgradient of the TMS respectively. DWMRC also required three new monitoring wells (MW- 35, MW-36 and MW-37) on the dikes of Cell 4B prior to that its use. The three wells on the dikes of Cell 4B supplement the existing wells (MW-14 and MW-15) on the southern dike of Cell 4A. As can be seen from the well network, the site groundwater is extensively monitored and the program is adequate to provide early detection of any potential TMS impacts. 34 b) Discrete Monitoring In order to individually monitor each cell in the TMS and to be able to pinpoint the source of any potential groundwater contamination that may be detected, there are 14 wells on the dikes or immediately adjacent to the cells. The monitoring program implemented at the site provides a comprehensive monitoring network to determine any potential leakage from Cells 1, 2 and 3. See Figure 4 and Figure 10 for a map showing the locations of the compliance monitoring wells for the site. 2.7.2.3 Operational Changes and Improved Operations Monitoring The Permit required changes to disposal cell operation in order to increase efforts to minimize potential seepage losses, and thereby improve protection of local groundwater quality. Examples of these changes are: c) Maximum Waste and Wastewater Pool Elevation Part I.D.3 of the Permit requires that EFRI continue to ensure that impounded wastes and wastewaters for all of the Mill's TMS are held within an FML. d) Slimes Drain Maximum Allowable Head Part I.D.3(b) of the Permit require that the Mill provide constant pumping efforts to minimize the accumulation of leachate over the FML in Cell 2, and upon commencement of dewatering activities, in Cell 3, and thereby minimize potential FML leakage to the foundation and groundwater. See the discussion in Section 2.15 .2.2 below. 2. 7.2.4 Evaluation of Tailings Cell Cover System Design EFRI submitted an Infiltration and Contaminant Transport Modeling Report ("ICTM Report"), White Mesa Mill Site Blanding, Utah, N vember 2007, prepared by MWH Americas, Inc. EFRI submitted a revised Infiltration and Contaminant Transport Modeling Report, White Mesa Mill Site, Blanding, Utah, March 2010 ("revised ICTM Report") in response to DWMRC comments. The March 2010 report is currently being reviewed in conjunction with the Reclamation Plan, Revision 5.0. DWMRC provided interrogatories for the revised ICTM Report in March 2012. EFRI provided responses to these interrogatories in May and September 2012. DRC provided review comments on EFRI's May and September 2012 responses in February 2013. The 2010 modeling was updated to address the Director's March 2012 and February 2013 comments on the ICTM Report and to incorporate supplemental field investigations conducted in 2010 and 2012 for cover borrow material and in 2013 for in situ tailings. The updated infiltration modeling results were presented in EFRI's submitted responses to the Director's March 2012 and February 2013 review comments in August 2012 and August 2015. On November 11, 2015, the Director held a conference call with EFRI and recommended submittal of an agreement outlining a plan to complete reclamation of Cell 2. This plan would 35 consist of completing placement of the cover design presented in Revision 5.0 of the Reclamation Plan on Cell 2 and demonstrating acceptable cover performance via a performance monitoring program. On August 11, 2016, EFRI submitted Reclamation Plan, Revision 5 .1, with an Updated Tailings Cover Design Report and incorporated comments received from the Director. On December 5, 2016, EFRI submitted the final version of Reclamation Plan, Revision 5.1, which incorporated additional comments received from the Director. EFRI and the Director executed a Stipulation and Consent Agreement ("SCA") on February 23, 2017 (DWMRC, 2017) defining the commitments and timeframes for completing placement of reclamation cover on Cell 2 and performance assessment of the cover system, in accordance with the Reclamation Plan Revision 5.1. EFRI updated the Reclamation Plan on February 8, 2018 to Revision 5. lB and submitted to the Director, but the guidelines, monitoring, and reporting requirements for the test sections did not change. Per the 2017 SCA, the Director will approve Reclamation Plan 5.1 upon completion of a public notice and comment period, and in conjunction with and conditional upon the execution and delivery of the SCA by EFRI and the Director. See Section 2.19 below for a more detailed discussion of post-closure requirements for the Mill. 2.7.3 Cell 4A Construction of Cell 4A was completed on or about November 1989. Cell 4A was used for a short period of time after its construction for the disposal of raffinates from the Mill's vanadium circuit. No tailings waste or wastewater had been disposed of in Cell 4A since the early 1990s. This lack of waste disposal, and exposure of the FML to the elements, caused Cell 4A to fall into disrepair over the years. Although the original design of Cell 4A was an improvement over the design of Cells 1, 2 and 3 (it had a one-foot thick clay liner under a 40 ml high density polyethylene ("HDPE") FML, with a more elaborate leak detection system), it was constructed in 1989 and did not meet today's BAT standards. Cell 4A was re-lined in 2007-2008 and was re-authorized for use in November 2008. With the reconstruction of Cell 4A, BAT was required, as mandated by Part I.D.4 of the Permit and as stipulated by the Utah Ground Water Quality Regulations at UAC R317-6-6.4(A). With BAT for Cell 4A, there are also new performance standards that require daily leak detection system monitoring, weekly wastewater level monitoring, and slimes drain recovery head monitoring. The BAT monitoring results are required to be reported and summarized in the Routine DMT and BAT Performance Standard Monitoring Reports. See Section 2.15.3 below for a more detailed discussion relating to the BAT performance standards and monitoring requirements for Cell 4A. Tailings Cell 4A Design and Construction was approved by the Director as meeting BAT requirements. The major design elements are set out in Part I.D.5 of the Permit and consist of 36 the following: a) Dikes -consisting of existing earthen embankment. of compacted . oil, con tructed by a previous Mill operator between J 989-1990, and composed of four dikes each including a 15-foot wide road at the top (minimum). On the north ea t, and soL1th margin the e dike have lopes of 3H to JV. The west dike has a slope f 2H to L V. Width of the e dike varies. Each has a minimum crest width of at least 15 feet to upport an acce s road. Base width also varie. from 89-feet on the east dike (with no exterior embankment), to 211-feet at the we t dike. b) Foundation -including existing subgrade oils over bedrock materials. Foundation preparation inclL1ded excavation and removal of contaminated soils, compaction of imported oils to a maximum dry den ity of 90%. The floor of Cell 4A has an average Jope of J ~ that grade from the northeast to the southwest corners. c) Tailings Capacity -the floor and in ide lopes of Cell 4A encompa s about 40 acres and hav a maximum capacity of about 1.6 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: (i) Primary FML -consisting of an impermeable 60 mil HDPE membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML is in direct physical contact with the tailings material over most of the Cell 4A floor area. In other location ·, the primary FML is in contact with the slimes drain collection ystern (di cu ed below). (ii) Leak Detection Sy tern -includes a permeable HDPE geonet fabric that extends acros the entire area under the primary FML in Cell 4A, and. drains to a leak detection sump in the southwest corner. Access to the leak detection ump is via an 18-inch inside diameter (ID) HDPE pipe placed down the inside slope, located between the primary and secondary FML. At its base this pipe is surrounded with a gravel filter set in the leak detection sump, having dirnen ions of 10 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer is enclo ed in an envelope of geotextile fabric. The purpo. e of both the gravel and geotextile fabric is to serve as a filter. (iii) Secondary FML -consisting of an impermeable 60-mil HDPE membrane found immediately below the leak detection geonet. This FML also extend aero s the entire Cell 4A floor, up the inside side-Jope and i also anchored in a trench at the top of all fow-dikes. (iv) Geo ynthetic C]ay Liner -consisting of a manufactured geosynthetic clay liner (' GCL") compo ed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. e) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: (i) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4A that drains to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated, two-part gee-composite drain material 37 (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southwesterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. (ii) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection ("SDC") pipe found at the downgradient end of the strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, sun-ounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast corner downhill to the far southwest corner of Cell 4A where it joins the slimes drain access pipe. (iii) Slimes Drain Access Pipe -consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4A at the southwest corner, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and woven geotextile that serves as a cushion to protect the primary FML. A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. t) North Dike Splash Pads -three 20-foot wide splash pads have been constructed on the north dike to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HOPE membrane that has been installed in the anchor trench and placed down the inside slope of Cell 4A, from the top of the dike, under the inlet pipe, and down the inside slope to a point 5-feet beyond the toe of the slope. g) Emergency Spillway -a concrete lined spillway has been constructed near the southwestern corner of the west dike to allow emergency runoff from Cell 4A to Cell 4B. At this time, all stormwater runoff and tailings wastewaters not retained in Cells 2, 3, and 4A will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. h) BAT Performance Standards for Tailings Cell 4A -EFRI shall operate and maintain Tailings Cell 4A so as to prevent release of wastewater to groundwater and the environment in accordance with an Operations and Maintenance Plan, as cun-ently approved by the Director, pursuant to Part I.H.19. At a minimum these performance standards shall include: (i) Maximum Allowable Daily Head-on the secondary FML, (ii) Maximum Allowable Daily Leak Detection System Flow Rate (iii) Slimes Drain Monthly and Annual Average Recovery Head Criteria -to be applied after the Mill initiates pumping conditions in the slimes drain layer. 38 See Part I.D.5 of the Permit for a more detailed discussion of the design of Cell 4A. A copy of the Mill's Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan is attached as Appendix F to this Application. 2. 7 .4 Cell 4B Construction of Cell 4B was completed in November 2010. Tailings Cell 4B Design and Construction was approved by the Director as meeting BAT requirements. The major design elements are set out in Part I.D.12 of the Permit and consist of the following: a) Dikes -consisting of newly constructed dikes on the south and west side of the cell, each including a 20-foot wide road at the top (minimum). The exterior slopes of the southern and western dikes have slopes of 3H to 1 V. The interior dikes have slopes of 2H to 1 V. Limited portions of the Cell 4B interior sidelopes in the northwest corner and southeast corner of the cell (where the slimes drain and leak detection sump are located) have a slope of 3H to 1 V. Width of these dikes varies. The base width of the southern dike varies from approximately 92 feet at the western end to approximately 190 feet at the eastern end of the dike, with no exterior embankment present on any other side of the cell. b) Foundation -including existing sub grade soils over bedrock materials. Foundation preparation included excavation and removal of contaminated soils, compaction of imported soils to a maximum dry density of 90%. The floor of Cell 4B has an average slope of 1 % that grades from the northwest to the southeast corner. c) Tailings Capacity -the floor and inside slopes of Cell 4B encompass about 40 acres and the cell has a maximum capacity 1.9 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: (i) Primary FML -consisting of an impermeable 60 mil HDPE membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML is in direct physical contact with the tailings material over most of the Cell 4B floor area. In other locations, the primary FML is in contact with the slimes drain collection system (discussed below). (ii) Leak Detection System -includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4B, and drains to a leak detection sump in the southeast corner. Access to the leak detection sump is via an 18-inch inside diameter ("ID") HDPE pipe placed down the inside slope, located between the primary and secondary FML. At its base this pipe is surrounded with a gravel filter set in the leak detection sump, having dimensions of 15 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer is enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. 39 (iii) Secondary FML -consisting of an impermeable 60-rnil HDPE membrane found immediately below the leak detection geonet. This FML also extends across the entire Cell 4B floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. (iv) Geosynthetic Clay Liner -consisting of a manufactured geosynthetic clay liner ("GCL") composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. e) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: (i) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4B that drains to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated two-part geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southeasterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. (ii) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection (SDC) pipe found at the downgradient end of the strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast corner downhill to the far southeast corner of Cell 4A where it joins the slimes drain access pipe. (iii) Slimes Drain Access Pipe -consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4B at the southeast corner, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and woven geotextile that serves as a cushion to protect the primary FML. A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. f) North and East Dike Splash Pads -nine 20-foot wide splash pads have been constructed on the north and east dikes to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HDPE membrane that has been installed in the anchor trench and placed down the inside slope of Cell 4B, from the top of the dike, under the inlet pipe, and down the inside slope to a point 5-feet beyond the toe of the slope. 40 g) Emergency Spillway -a concrete lined spillway has been constructed near the southeastern corner of the east dike to allow emergency runoff from Cell 4A into Cell 4B. This spillway is limited to a 6-inch reinforced concrete slab, with a welded wire fabric installed within its midsection, set directly atop a cushion geotextile placed directly over the primary FML in a 4-foot deep trapezoidal channel. A 100-foot wide, 60-mil HDPE membrane splash pad is installed beneath the emergency spillway. No other spillway or overflow structure will be constructed at Cell 4B unless and until the construction of Cells 5A and 5B. At this time, all stormwater runoff and tailings wastewaters not retained in Cells 2, 3, and 4A will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. h) BAT Performance Standards for Tailings Cell 4B -EFRI shall operate and maintain Tailings Cell 4B so as to prevent release of wastewater to groundwater and the environment in accordance with the currently-approved Cell 4B BAT, Monitoring, Operations and Maintenance Plan. At a minimum these performance standards shall include: (i) Maximum Allowable Daily Head-on the secondary FML, (ii) Maximum Allowable Daily Leak Detection System Flow Rate (iii) Slimes Drain Monthly and Annual Average Recovery Head Criteria -to be applied after the Mill initiates pumping conditions in the slimes drain layer, (iv) Maximum Daily Wastewater Level -to ensure compliance with the minimum freeboard requirements for Cell 4B, and prevent discharge of wastewaters via overtopping. See Part I.D.12 of the Permit for a more detailed discussion of the design of Cell 4B. A copy of the Mill's Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan is attached as Appendix F to this Application. 2.7.5 Future Additional TMS Cells Future additional TMS cells at the Mill will require Director approval prior to construction and operation. Future TMS cells at the Mill will be required to satisfy BAT standards at the time of construction. EFRI has submitted a GWDP and RML amendment application to construct, operate and (when operations are complete) reclaim proposed new tailings impoundment Cells 5A and 5B at the Mill. The License amendment request was previously submitted under separate cover. Review of the application is currently in progress by DWMRC. Upon completion of the DWMRC review, the RML will be subject to a Public Comment period. The construction of Cells 5A and SB is an essential element of future operations at the Mill as their construction is necessary in order to continue providing sufficient impoundment surface area for the evaporation of Mill process water, and to provide additional tailings capacity which is necessary to accommodate the tailings volume associated with routine processing operations. At this time, Energy Fuels does not anticipate the construction of Cells 5A and 5B immediately upon the Director's approval of the License and GWDP amendments; however, authorization is being sought in advance to allow the Mill to respond to future needs. 41 2.7.6 Other Facilities and Protections 2.7.6.J Feedstock Storage In order to constrain and minimize potential generation of contaminated stormwater or leachates, Part I.D. J L of the Permit require the MilJ to continue it. existing practice of limiting open air to.rage of feed tock material to the hi torical torage area found along the eastern margin of the M.ill ite (as defined by the urvey coordinates found in Permit Table 4). The intent of Section I. D. L 1, (based on the SOB for the 2009 GWDP), is to require that feedstock storage outside of the area pecified in Tab.le 4 shall meet the following requirements: a) Feedstock materials shall be stored at all times in water-tight containers or water-tight container overpacks, and aisle ways will be provided at all times to allow visual inspection of each and every feedstock container and container overpack, or b) Feed tock container hall be stored on a hardened su1face to prevent p.il.lage onto ub LIIface soil and that conform · with the foJiowing minimum pby ical requirement : 1) A torage area composed of a hardened engineered mface of a phaJt or concrete and 2)A torage area de igned con tructed, and operated in accordance with engineering plan and pecification approved in advance by the Director. AJJ ucb engineering plan or pecifications ubmitted shall demon trate compliance with Part I.D.4, 3)A torage area that provide containment berms to control stormwater run-on and run- off, and 4)Stormwater drainage works approved in advance by the Director, or 5)0ther storage facilities and means approved in advance by the Director. 2. 7.6.2 Mill Site Reagent Storage Part I.D.3(±) of the Permit requires the Mill to demonstrate that it has adequate provisions for spill response, cleanup, and reporting for reagent storage facilities. The ·e provisions are detailed in the Stormwater Best Management Practice Plan which is designed to prevent potential reagent tank pill or leak. that could release contaminant to site soi]s or groundwater and to provide proper spill prevention and control. Content of this plan are stipulated in Part I .D. JO of the Permil, and . ub.mitta1 and approval of the plan is required. For exi t.ing facilities at the Mill secondary containment is required, although such containment may be earthen ]ined. For new facilities con tructed at the Mill, or reconstruction of exi ·ting facilities, Part I.D.3(±) requires a higher standard of secondary containment that would prevent contact of any potential spill with the ground surface. A copy of the Mill's Stormwater Best Management Practices Plan, Revision 2.1: April 2022 is attached a· Appendix G to this Application. 2. 7.6.3 New Construction Part I.D.4 of the Permit requires any construction, modification, or operation of new waste or wastewater disposal, treatment, or storage facilities shall require submittal of engineering design plans and specifications, and prior Director review and approval. All engineering plans or specifications submitted shall demonstrate compliance with all BAT requirements stipulated by 42 the Utah Ground Water Quality Protection Regulations (U AC R317-6). Upon Director approval the Permit may be re-opened and modified to include any necessary requirements. 2.7.6.4 Other The White Mesa Mill Discharge Minimization Technology Monitoring Plan, 01/22 Revision: EFRI 13.0 (the "DMT Plan"), and the White Mesa Mill Tailings Management System, 03/17 Revision: EFR 2.5 (the "Tailings Management Plan"), are attached as Appendix H and Appendix I to this Application, respectively. These plans provide a systematic program for constant surveillance and documentation of the integrity of the TMS, including monitoring the leak detection systems. The DMT Plan requires daily, weekly, quarterly, monthly and annual inspections and evaluations and monthly reporting to Mill management. See Section 2.15.2 below for a more detailed discussion of the requirements of the DMT Plan. 2.7.7 Surface Waters The Mill has been designed as a facility that does not discharge to surface waters. Tailings and other Mill wastes are disposed of permanently into the Mill's TMS. Further, as mentioned above, the Mill was designed and constructed to prevent run on or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the TMS; and b) diverting runoff from surrounding areas away from the Mill site. As a result, there is no pathway for liquid effluents from Mill operations to impact surface waters. Under the Mill License, the Mill is required to periodically sample local surface waters to determine if Mill activities may have impacted those waters. The primary pathway would be from air particulates generated during Mill operations that may have landed on or near surface waters, or that may have accumulated in drainage areas that could feed into surface waters. Sampling results show no trends or other impacts of Mill operations on local surface waters. See the Mill's Semi-Annual Effluent Reports, copies of which have previously been provided to the Director. 2. 7 .8 Alternate Concentration Limits Therefore, no alternate concentration limits are currently applicable to the site. 2.8 For Areas Where the Groundwater Has Not Been Classified by the Board, Information of the Quality of the Receiving Ground Water (R317-6-6.3.H) Groundwater classification was assigned by the Director in the Permit on a well-by-well basis after review of groundwater quality characteristics for the perched aquifer at the Mill site. A well-by-well approach was selected by the Director in order to acknowledge the spatial variability of groundwater quality at the Mill, and afford the most protection to those portions of the perched aquifer that exhibited the highest quality groundwater. These groundwater classifications are set out in Part I.A and Table 1 of the Permit. The primary element used by the Director in determining the groundwater classification of each monitoring well at the site, is the TDS content of the groundwater, as outlined in UAC 317-6-3. Groundwater quality data collected by the Mill show the shallow aquifer at the Mill has a highly 43 variable TDS content, wilh TDS average ranging from about 1100 to about 7700 mg/L. Another key element in determination of groundwater class is the presence of naturally occurring contaminants in concentration lbat exceed their respective GWQS. In such cases, the Director has cause to downgrade aquifer classification from Class II to Class III (see UAC R317-6-3.6). Using all available TDS data and background data, for the POC and general monitoring wells the Director determined that four of those wells exhibit Class II drinking water quality groundwater. The remaining wells at the site exhibited Class III or limited use groundwater. Well MW-24A has not been classified at this time. 2.8.1 Existing Wells at the Time of Original Permit Issuance The Director required EFRI to evaluate groundwater quality data front the thirteen existing wells (MW-03 has since been abandoned) on site, and submit a Background Ground Water Quality Report for Director approval. One of the purpo e of that report was to provide a critical evaluation of historic groundwater quality data from the facility, and determine representalive background quality conditions and reliable GWCLs for the Permit. EFRI (then Denison) prepared the Existing Well Background Report that evaluated all historic data for the tllirteen exi ting wells for Lhe purposes of establishing background groundwater quality at the ite and developing GWCL under the GWDP. Prior to review and acceptance of the conclusion ·in the Exi ting Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were e tablished as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflected background groundwater quality for the thirteen existing wells, based primarily on the analysis performed in the Existing Wells Background Report. It should be noted, however, that, because the GWCLs have been set at the mean plus two tandard deviations, or Lhe equivalent, un-impacted groundwater would normally be expected to exceed the GWCL approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all ample results, and do not nece sarily represent impacts to groundwater from Mill operations. 2.8.2 New Wells Installed After the Date of Original Issuance of the Permit Because the Permit called for installation of nine new monitoring wells around the TMS, background groundwater quality had to be determi11ed for those monitoring point . To this end, the Permit requjred the Mill to collect at least eight quarter of groundwater quality data and submit the New Well Background Report for Director approval to e. tablisb background groundwater quality for those wells. EFRI (then Deni on) prepared the New WelJ Background Report that evaluated all hj toric data for the nine new welJ for the purpose of e tablishing background groundwater quality at the ·ite and developing GWCL under the GWDP. Prior to review and acceptance of Lhe conclu. ion in the New Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. 44 The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the aine new well ba ed primaril y on the analysis performed in the New Well Background Report. It should be noted, however, Lhat, becau e th e GWCLs have been set at the mean plus second tandard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Theref: re, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. 2.9 Sampling and Analysis Monitoring Plan (R317-6-6.3.I) The groundwater monitoring plan is set out in the Permit. All groundwater monitoring at the site is in the perched aquifer. The following sections summarize the key components of the Mill's sampling and analysis plan. 2.9.1 Groundwater Monitoring to Determine Groundwater Flow Direction and Gradient, Background Quality at the Site, and the Quality of Groundwater at the Compliance Monitoring Point 2.9.1.1 Groundwater Monitoring at the Mill Prior to Issuance of the Permit At the time of renewal of the Mill license by NRC in March, 1997 and up until issuance of the Permit in March 2005, the Mill implemented a ground.water detection monit cing program, in accordance with 10 CFR Part 40, Appendix A and the pro vi. ions of the NRC Mill Licen ·e condition 11.3A. The detection monitoring program wa implemented in accordance with the report entitled, Points of Compliance, White Mesa Uranium Mill, prepared by Titan Environmental Corporation, submitted by letter to the NRC dated October 5, 1994. Under that program, the Mill sampled monitoring wells MW-5, MW-11, MW-12, MW-14, MW-15 and MW-17, on a quarterly basis. Samples were analyzed for chloride, potassium, nickel and uranium, and the results of such sampling were included in the Mill's Semi -Annual Effluent Monitoring Reports that were filed with the NRC up until August 2004 and with the DWMRC subsequent thereto. Between 1979 and 1997, the Mill monitored up to 20 constituents in up to 13 wells. That program was changed to the Points of Compliance Program in 1997 because NRC had concluded that: • The Mill and TMS had produced no impacts to the perched zone or deep aquifer; and • The most dependable indicators of water quality and potential cell failure were considered to be chloride, nickel, potassium and natural uranium. 2.9.1.2 Issuance of the Permit On March 8, 2005, the Director issued the Permit, which includes a groundwater monitoring program that superseded and replaced the groundwater monitoring requirements set out in the NRC Mill License Condition 11.3A. Condition 11.3A has since been removed from the Mill License. Groundwater monitoring under the Permit commenced in March 2005, the results of which are included in the Mill's Quarterly Groundwater Monitoring Reports that are filed with 45 the Director. On September 1, 2009, EFRI fiJed a Groundwater Di charge Permit Renewal Application. At the reque t of the Director of the Utah Divi ion of Radiation Control, EFRI submitted an updated ver. ion of the September 1, 2009 renewal application on July 13, 2012. At the request of the Director of the Utah Division of Radiation Control, EFRI submitted an updated version of the July 2012 renewal application on June 5, 2014. In accordance with R317-6-6.7 and the current GWDP dated March 8, 2021, Part IV.D, this is an updated application to the Director for renewal of the Permit for another 5-years under R313-6-6. 7. 2.9.1.3 Current Ground Water Monitoring Program at the Mill Under the Permit The current groundwater monitoring program at the Mill is used to determine groundwater flow direction, gradient, and quality at the compliance monitoring points. This program consists of monitoring at point of compliance monitoring wells: MW-2, MW-3A, MW-5, MW-11, MW-12, MW-14,MW-15,MW-17,MW-23,MW-24,MW-25,MW-26,MW-27,MW-28,MW-29,MW- 30, MW-31, MW-32, MW-35, MW-36, and MW-37. Groundwater flow, direction and quality are monitored at six general monitoring wells: MW-1, MW-18, MW-19, MW-20, MW-22 and TW4-24 and at three well added by EFRI in respon e to reque t from the UMUT far cros - graclient to the TMS to provide water level data and to provide adclitional information on ite geology and naturally occmring geochemical behavior . One well ha been installed adjacenl to MW-24 (MW-24A) for additional studie · of regional geochemistry. The l cati011 of these welJ ' are indicated on Figure 10. Depth to water is measured quarterly in all of the well listed above as well as MW-34. Due to limited water in MW-34, it is not ampJed for POC compliance. MW-33 is completely dry and is not sampled for POC compliance. Part I.E. l.( d) of the Permit requires that each point of compliance well as well as general monitoring wells must be sampled for the constituents listed in Table 2.9.1.3-1. Further, Part I.E.l.(d)l) of the Permit, requires that, in addition to pH, the following field parameters must also be monitored: • Depth to groundwater • Temperature • Specific conductance • Redox potential ("Eh") • Dissolved Oxygen ("DO") and that, in addition to chloride and sulfate, the following general inorganics must also be monitored: • Carbonate, bicarbonate, sodium, potassium, magnesium, calcium, and total anions and cations. 46 Sample frequency depends on the speed of groundwater flow in the vicinity of each well. Parts I.E.1 (b) and ( c) provide that quarterly monitoring is required for all wells where local groundwater average linear velocity has been found by the Director to be equal to or greater than 10 feet/year, and semi-annual monitoring is required where the local groundwater average linear velocity has been found by the Director to be less than 10 feet/year. Based on these criteria, quarterly monitoring is required at MW-11, MW-14, MW-25, MW-26 and MW-30, MW-31, and MW-36. Quarterly monitoring is required for MW-38, MW-39 and MW-40 until such time as they are added to the GWDP and the frequency is modified based on the flow velocity discussed above as necessary. Semi-annual monitoring is required at MW-1, MW-2, MW-3A, MW-5, MW-12, MW-15, MW-17, MW-18, MW-19, MW-20, MW-22, MW- 23, MW-27, MW-28, MW-29, MW-32, MW-35 and MW-37. MW-24 and MW-24A, which would normally be monitored on a semi-annual frequency, are monitored quarterly due to their inclusion in additional geochemical studies. An additional well (MW-41) is planned for the area downgradient of MW-24/MW-24A and upgradient of MW-2 as part of the additional studies associated with MW-24A. Geochemical and indicator parameter analysis during the initial SAR in October of 2012 concluded that upgradient monitoring wells MW-1, MW-18, and MW-19 have not been impacted by Mill activities. These upgradient monitoring wells are sampled semi-annually but are not subject to GWCLs. In addition, MW-20 MW-22, and TW4-24 are monitored on a semi- annual basis as "General Monitoring Wells," but they are not subject to GWCLs. 2.9.1.4 Groundwater Flow Direction and Gradient Part I.E.3 of the Permit requires that, on a quarterly basis and at the same frequency as groundwater monitoring required by Part I.E.1 and described in Section 2.9.1.3 above, the Mill shall measure depth to groundwater in the following wells and/or piezometers: a) The point of compliance wells identified in Table 2 and l .E.1 of the Permit, as described in Section 2.9.1.3 above. b) Piezometers P-1, P-2, P-3A, P-4 and P-5. c) Head Monitoring Well-MW-34. d) General monitoring wells -Upgradient MW-1, MW-18, and MW-19; Lateral well TW4-24; and Downgradient wells MW-20, MW-22. e) Contaminant investigation wells -any well required by the Director as a part of a contaminant investigation or groundwater corrective action (at this time this includes the chloroform and nitrate investigation wells). f) Any other wells or piezometers required by the Director. While it is not a requirement of the GWDP, EFRI also measures depth to water in the DR piezometers which were installed during the Southwest Hydrogeologic Investigation. The Mill uses these measurements to prepare groundwater isocontour maps each quarter that show the groundwater flow direction and gradient. The isocontour map for the fourth quarter of 2021 is attached as Figure 5. 47 2.9.1.5 Background Quality at the Site A significant amount of hi toric groundwater quality data had been colle ted by EFRI and previou operators of the Mill for ome well at the faciUty. In some case the e data extend back more than 42 years to September 1979. A brief ummary of the variou tudies that had been performed prior to the original issuance of the Permit i · . et Olll in Section 2.0 of the Regional Background Report. However, at the time of original is ·uance of the Permit, the Director had not yet completed an evaluation of the historic data, particularly with regard to data qtiality, and quality as urance issues. Such an examination needed to include such things as ju tification of any zero concentration values reported, adequacy of minimum detection limits provided (particularly with re pect to the c rre. ponding GWQS) adequacy of laboratory and analytical method u ed con ·i tency of laboratory unit or reporting, internal con istency between :pecific and composite types of analysi (e.g., major ion. and TDS) identification and ju tification of concentration outlier and .implications of concentration trends (both temporal and spatial). As discussed in Section 2.9 .6.1 below, the Director also noted several groundwater quality issues that needed to be re olved prior to a determination of background groundwater quality at the . ite. These were: 1) a number of con tituent exceeded their re pective GWQS (including nitrate in one well and mangane e, elenium and uranium in several well ); 2) long term trend in uranium in downgradient wells MW-14, MW-15 and MW-17; and 3) a spatial high of uranium in those three downgradient well . See pages 5-8 of the 2004 Statement of Basis for a more detailed discussion of these points. As a result of the foregoing, the Director required that the Background Reports be prepared to address and resolve these issues. Further becau e background groundwater quality at the Mill site had not yet been approved at the time of original Permit i uance, the Di1·ector was not able to determine if any contaminant is naturally occurring and therefore detectable or undetectable for purpo e of electing GWCL · in each well. Con equently the Director initia!Jy assigned GWCLs a · if they were 'undetectable' (i.e. a sum.ing that all natural background concentrations were le s than a fraction of the respective GWQS). As di cussed in Section L.3 above and 2.1 J.2 below, EFRI submitted the Background Reports to the DiJector. Both the Exi ting Well Background Report and the New Well Background Report provided GWCLs for all of the con tituents in the exi ting weJI · and new weJls respectively, based on a tatistical intra-well approach. The Director has approved the Background Reports. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells (MW-3 has since been abandoned) and the nine new wells based primarily on the analy i performed in the Background Report . It should be noted however, that becau e the GWCLs had been et at the mean plu econd standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCL approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all ample re uJts and do not neces arily repre ent impacts to groundwater from Mill operations. 48 The GWDP dated January 20, 2010 required the completion of eight con, ecutive quarter of groundwater sampling and analy i, of MW-20 and MW-22 and later ubmittal of another Background Report to determine if well MW-20 and MW-22 should be added as POC monitoring wells. Data from MW-20 and MW-22 were analyzed in the pre-operational and regional background addendum (INTERA 2007a)· however there wa not a complete data set at the time. Although well MW-20 and MW-22 were in taHed in 1994 they were not . ampled regularly until the second quarter of 2008. The eighth fuU round of sampling was completed during the fir t quarter of 2010, and EFRT ubmitted to the Director the Background Groundwmer Quality Report for Wells MW-20 and MW-22 for Denison Mines ( USA) Co1p. 's White Mesa Mill Site San Juan County, Utah, June l 2010, prepared by INTERA Inc. (the "MW-20 and MW-22 Background Report"). DWMRC classified MW-20 and MW-22 as general monitoring wells, and GWCLs have not been established for these wells. MW-20 and MW-22 are sampled semi-annually. Part I.H.6 of the GWDP dated June 21, 2010 required the installation of three hydraulically downgradient well adjacent to Taijjog Cell 4B (MW-33 MW-34, and MW-35) prior to placement of olid or fluids in Cell 4B. The purpose of the e monitoring weU . was to provide early detection of potential impacts to the hallow groundwater from Tailing · Cel.I 4B. EFRl in talled MW-33, MW-34. and MW-35 a required. Of the e three wells installed near tailing Cell 4B only MW-35 wa hydraulically acceptable, with five feet or more of saturated thickness. MW-35 was ·ampJed quarterly ince fourth quarter 2010 to collect eight statistically valid data points for the completion of the Background Report and calculation of GWCLs. MW-33 and MW-34 had in ufficient water for sampling, with saturated thicknesses less than five feet. MW- 33 is completely dry, and no samples or depth to water measurements are collected from this well. Quarterly depth to water is measured in MW-34, but no sampling or analysis is required. Part I.H.4 of the February J 5, 2011 GWDP required the installation of two wells hydraulically downgradient of Tailing Cell 4B as replacements for MW-33 and MW-34. EFRI installed MW-36 and MW-37 as required. MW-36 and MW-37 were sampled quarterly beginning in the third quarter 2011 to collect eight statistically valid data points for the completion of the Background Report and calculation of GWCLs. The Background Report for well MW-35, MW-36, and MW-37 was submitted to the Director on May 1, 2014. The findings of the Background Analysis for well MW-35, MW-36, and MW- 37 upport previous conclusions that the groundwater at the Mill i not being affected by any potential TMS seepage. The Director incorporated MW-35, MW-36 and MW-37 in a subsequent revision of the GWDP and these weUs are ampled as required. Three wells have been added by EFRI in response to reque ts from tbe UMUT far cross-gradient to the TMS to provide water level data and to provide additional information on site geology and naturally occurring geochemical behavior . DWMRC stated in the Public Participation Summary ("PPS ) for the January 18 2018 GWDP renewal that "There i no regulatory or technical. ba i to require additional monitoring well between CeJJ 4A and MW-22. Monitoring weJI currently exi t directly downgradient and cross gradient from CelJ 4A which would identify potential TMS impacts before anything would appear in MW-22 and at thi. time no tailing cell leakage ha been observed. In regard · to the requested three new monitoring well made by the UMUT in other comments although the Division ee no technical or r gulatory 49 basis to include monitoring wells in the location between Tailings Cell 4A and MW-22, EFRI has agreed to address the UMUT concern and voluntarily install three monitoring wells in the area between monitoring wells MW-17 and MW-22." The three wells, MW-38, MW-39 and MW-40, were installed in February 2018. The Background Report for wells MW-38, MW-39, and MW-40 was submitted to the Director on June 7, 2021 after sufficient data had been collected to complete the statistical evaluation. The findings of the Background Analysis for wells MW-38, MW-39, and MW-40 support previous conclusions that the groundwater at the Mill is not being impacted by any potential TMS seepage. The Director approved the background report for MW-38, MW-39, and MW-40 by letter dated June 16, 2021. MW-38, MW-39, and MW-40 will be incorporated into a subsequent revision of the GWDP. Until such time as these wells are incorporated into the GWDP, they are sampled on a quarterly basis. 2.9.1.6 Quality of Ground Water at the Compliance Monitoring Point There are over 42 years of data for some constituents in some wells at the site, but not for all constituents. However, with the exception of tin, which was added as a monitoring constituent in 2007, all currently required monitoring constituents have been sampled in the wells that were in existence on the date of the original issuance of the Permit commencing with the first quarter of 2005 . Further, all constituents in any new compliance monitoring wells have been sampled upon installation of those wells, commencing either in the second or third quarters of 2005 for the wells installed as a result of the 2005 Permit and in any wells installed subsequent to the 2005 Permit. The analytical results from this sampling are reported quarterly in Groundwater Monitoring Reports, which are filed with the Director pursuant to Part I.F.1 of the Permit. 2.9.2 Installation, Use and Maintenance of Monitoring Devices Compliance monitoring at the Mill site is accomplished in three ways: the compliance well monitoring program; the leak detection monitoring system in Cells 4A and 4B; and various DMT monitoring requirements. Each of these are discussed below. 2.9.2.1 Compliance Well Monitoring Compliance for TMS Cells 1, 2 and 3 and the remainder of the Mill site, other than Cells 4A and 4B, is accomplished by quarterly or semi-annual sampling of the network of compliance monitoring wells at the site. See Figure 10 for a map that shows the compliance monitoring well locations, and Section 2.9 .1.3 for a description of the monitoring program. 2.9.2.2 Leak Detection System in Cell 4A and Cell 4B BAT was required, as mandated in Part I.D.4 of the Permit and as stipulated by UAC R317-6- 6.4(a) for the reconstruction of Cell 4A and the construction of Cell 4B. Because TMS Cells 1, 2 and 3 were constructed prior to the GWDP BAT requirements, and after review of the existing design and construction, the Director determined that DMT rather than BAT is required for Cells 1, 2 and 3 (see the discussion in Section 2.7.2 above). 50 BAT for Cell 4A and Cell 4B included the construction of a modern leak detection system. See Sections 2.7.3 and 2.7.4 above for a description of the key design elements of Cell 4A and Cell 4B respectively, including their leak detection systems. With BAT for Cell 4A and Cell 4B, there are new performance standards in the Permit that require daily leak detection system monitoring, weekly wastewate1· level monitoring, and Limes drain recovery head monitoring. The BAT monitoring results are required to be reported and summarized in the Routine DMT and BAT Performance Standard Monitoring Reports. See Sections 2.15.3 and 2.15.4 below for a more detailed discussion of the BAT monitoring requirements for Cell 4A and Cell 4B respectively. Because Cell 4A and Cell 4B have modern leak detection systems, that meet BAT standards and are monitored daily, the leak detection systems in Cell 4A and Cell 4B can be considered to be a point of compliance monitoring devices. 2.9.2.3 Other DMT Monitoring Requirements In addition to the foregoing, the additional DMT performance standard monitoring discussed in detail in Section 2.15 below is required to be performed under the Permit 2.9.3 Description of the Compliance Monitoring Area Defined by the Compliance Monitoring Points The compliance monitoring area at the site is the area covered by the groundwater compliance monitoring wells. Figure 10 shows the current locations of the compliance groundwater monitoring wells at the site. At the time of original Permit issuance, the Director reviewed the then recent water table contour maps of the perched aquifer. Those maps identified a significant western component to groundwater flow at the Mill site, which the Director concluded appeared to be the result of wildlife pond seepage and groundwater mounding ( ee page 23 of the 2004 Statement of Ba i ). As a consequence, new groundwater monitoring well were required, particularly along the western margin of the TMS, in addition to the monitoring well already in existence at that time. The Director also concluded that new wells were also needed for DMT purposes and to provide discrete monitoring of each tailings cell. This resulted in the addition of the following compliance monitoring wells to the then existing monitoring well network: MW-23, MW-24, MW-25, MW-26 (which was then existing chloroform investigation well TW4-15), MW-27, MW-28, MW-29, MW-30, MW-31 MW-32 (which was then existing chloroform investigation well TW4-17), MW-35, MW-36, and MW-37. As previously stated MW-33 and MW-34 were installed but are not currently sampled due to limited water and saturated thickness. MW-1, MW- 18, MW-19, MW-20, MW-22, and TW4-24 are not POC wells but are general monitoring wells and are sampled semi-annually for information purposes only. MW-38, MW-39 and MW-40 have been added by EFRI in response to requests from the UMUT far cross-gradient to the TMS to provide water level data and to provide additional information on site geol gy and naturally occurring geochemical behaviors. One well ha been installed adjacent to MW-24 (MW-24A) for additional studies of regional geochemistry. Monitoring well MW-41 will be in tailed during the additional studies associated with MW-24/MW-24A. 51 Based on groundwater flow direction and velocity, the compliance monitoring network, with the fo regoing addjLional new wells, was considered to be adequate for compliance monitoring in the perched aquifer at the site. Further, as mentioned in Section 2.9.2.2 above, the leak detection systems in Cell 4A and 4B can also be considered to be compliance monitoring areas for these cells. 2.9.4 Monitoring of the Vadose Zone Monitoring is not performed in the vadose zone at the site. 2.9.5 Measures to Prevent Ground Water Contamination After the Cessation of Operation, Including Post-Operational Monitoring 2.9.5.1 Measures to Prevent Ground Water Contamination After the Cessation of Operation Please see Section 2.19 below for a detailed discussion of the measures to prevent groundwater contamination after the cessation of operations. 2.9.5.2 Post-Operational Monitoring Groundwater monitoring will continue during the post-operational phase through final closure until the Permit i terminated. EFRI understands that the final closure will take place and the Permit will be terminated upon termination of the Mill License and transfer of the reclaimed TMS to the United States Department of Energy pursuant to U.S.C. 2113. See Section 2.19.1.1 below. 2.9.6 Monitoring Well Construction and Ground Water Sampling Which Conform Where Applicable to Specified Guidance 2.9.6.1 Monitoring Well Construction a) New Wells All new compliance monitoring wells installed after the original issuance of the Permit were installed in accordance with the requirements of Part I.E.4 of the Permit. Part I.E.4 requires that new groundwater monitoring wells installed at the facility comply with the following design and construction criteria: a) Located as close as practical to the contamination source, tailings cell, or other potential origin of groundwater pollution; b) Screened and completed in the shallow aquifer; c) Designed and constructed in compliance with UAC R317-6-6.3(I)(6), including the EPA RCRA Ground Water Monitoring Technical Enforcement Guidance Document, 1986, OSWER-9950.1 (the "EPA RCRA TEGD"); and d) Aquifer tested to determine local hydraulic properties, including but not limited to hydraulic conductivity. 52 As-built reports for all new groundwater monitoring wells were submitted to the Director for his approval, in accordance with Part I.F.6 of the Permit. Part I.F.6 requires those reports to include the following information: a) Geologic logs that detail all soil and rock lithologies and physical properties of all subsurface materials encountered during drilling. Said logs were prepared by a Professional Geologist licensed by the State of Utah or otherwise approved beforehand by the Director ; b) A well completion diagram that details all physical attributes of the well construction, including: 1) Total depth and diameters of boring; 2) Depth, type, diameter, and physical properties of well casing and screen, including well screen slot size; 3) Depth intervals, type and physical properties of annular filterpack and seal materials used; 4) Design, type, diameter, and construction of protective surface casing; and 5) Survey coordinates prepared by a State of Utah licensed engineer or land surveyor, including horizontal coordinates and elevation of water level measuring point, as measured to the nearest 0.01 foot; and c) Aquifer permeability data, including field data, data analysis, and interpretation of slug test, aquifer pump test or other hydraulic analysis to determine local aquifer hydraulic conductivity in each well. Between April and June 2005, EFRI installed wells MW-23, MW-24, MW-25, MW-27, MW-28, MW-29, MW-30, and MW-31. On August 23, 2005, EFRI submitted a Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill April through June 2005 Report, prepared by Hydro Geo Chem, Inc., that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. Between August 30 and September 2, 2010, EFRI installed wells MW-33, MW-34, and MW-35. On October 11, 2010, EFRI submitted Installation and Hydraulic Testing of Perched Monitoring Wells MW-33, MW-34, and MW-35 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chem, Inc. that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. During the week of April 25, 2011, EFRI installed wells MW-36, and MW-37. On June 28, 2011, EFRI submitted Installation and Hydraulic Testing of Perched Monitoring Wells MW-36, and MW-37 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chem, Inc. that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. Between February 12 and February 21, 2018, EFRI installed wells MW- 38, MW-39, and MW-40. On June 18, 2018, EFRI submitted Installation and Hydraulic Testing of Perched Monitoring Wells MW-38, MW-39, and MW-40 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chem, Inc. that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. During the week of December 2, 2019, EFRI installed Well MW-24A. On January 29, 2020 EFRI submitted Installation and Hydraulic 53 Testing of Perched Well MW-MW~24A White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chem, Inc. that documented how this well had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. b) Existing Wells The Existing Well , MW-1 MW-2, MW-3 (now abandoned) MW-5, MW-11, MW-12, MW-14, MW-15, MW-.17, MW-18 MW-19 MW-26 and MW-32 as well as wells MW-20 and MW-22, which are not compliance monitoring well , and piezometer P-1, P-2, P-3 (replaced with P-3A), P-4 and P-5 were all con trncted and jnstaJled prior to original issuance of the Permit. Some of those wells date back to 1979. During everal ite vi its and four split groundwater sampling events between May 1999 and the date of original is ·uance of the Permit, and a review of available as built information, DWMRC taff noted the need for remedial construction, maintenance, or repair at several of these wells, including: (i) (ii) (iii) A. B. C. D. 16 of the ex1stmg monitoring well failed to produce cJear groundwater in conformance with the EPA RCRA TEGD, apparently due to incomplete well development. Consequently, the Permit required that MW-5 MW-11, MW-18 MW-19, MW-26, TW4-16, and MW-32 be developed to en ure that groundwater clarity conforms to the EPA RCRA TEGD to the extent reasonably achievable· The Permit required the Mill to in tall protective steel surface casings to protect the exposed PVC well and piezometer casings for piezometer P-1, P-2, P-3 (now replaced w.ith P-3A), P-4 and P-5 and wells MW-26 and MW-32; and Several problem were observed with the construction of MW-3, including: A review of the MW-3 well as-built djagram howed that no geologic Jog wa provided at the time of well in. tallation. Con equently, the Director was not able to ascertain if the screened interval wa adequately located across the ba e of the shallow aquifer; MW-3 was constructed without any filter media or sand pack across the screened interval; An excessively long casing sump (a 9 or 10 foot long non-perforated section of well casing), was constructed at the bottom of the well; and The well screen appeared to be poorly positioned, based on the low productivity of the well, (there is no geologic log to verify proper positioning). The Mill developed the wells as required and installed the protective casings required. The Director concluded that EFRI had fulfilled the requirements and sent EFRI a Closeout Letter on August 5, 2008. With respect to the concerns raised about MW-3 the MilJ in talled MW-3A approximately 10 feet southeast of MW-3, in order to verify the depth to the upper contact of the Brushy Ba in Member of the Morrison Formation (the "UCBM"). After in tallation, the Director reviewed the geologic log for MW-3 and the as-built reports for both MW-3 and MW-3A and concluded that 54 the well screen for MW-3A was 2.5 feet below the UCBM and the well screen for MW-3 was 4.5 feet above the UCBM. Therefore MW-3 was a partially penetrating well; whereas MW-3A is fully penetrating. The Director concluded that semiannual sampling was to continue in both wells until sufficient data is available and the DWMRC could make a conclusion regarding the effects of partial well penetration and screen length. As a result, the GWDP was modified to require that MW-3A be completed with a permanent surface well completion according to EPA RCRA TEGD. EFRI completed MW-3A as required, and on August 5, 2008 the DWMRC sent EFRI a Closeout Letter. Both MW-3 and MW-3A were sampled emi-arurnally through the fourth quarter of 2016. A review of the MW-3 and MW-3A data in 2016 indicated that MW-3A lacked the construction issues seen in MW-3. With the concurrence of the DWMRC, EFRI abandoned MW-3 in November 2016 in accordance with State of Utah regulations R655-4-14.8 by a Utah licensed water well driller. An abandonment report was submitted to DWMRC under separate cover. Subsequent to original Permit issuance, on January 6, 2006, DWMRC staff performed an inspection of the compliance groundwater monitoring wells at the Mill. During the inspection, well MW-5 was found to have a broken PVC surface casing. The repair of MW-5 was added to the Permit compliance schedule to require the Mill to repair the broken PVC casing to meet the requirements of the Permit. The Permit required EFRI.to submit an As-Built report for the repairs of monitoring well MW-5 on or before May 1, 2008. EFRI submitted the required report, and on Augu t 5, 2008 the DWMRC sent EFRI a Closeout Letter. In the 2012 SAR, it was noted that uranium values in MW-5 were erratic and extremely variable which appeared to be affected by temporal or seasonal conditions as evidenced by concentrations which rise in either the fourth quarter or first quarter followed by substantial decrea es beginning in the second quarter. Stati tical analysis of the data showed no need for an increa ed GWCL due to the presence of tatisticaJ outlier . EFRI proposed that the GWCL for manium in MW-5 of 7 .5 µg/L be retained and additional ·tndie be undertaken lo try and determine the rea on for the ea onal variation observed in the data. In an effort to addre potential phy. ical cau ·e on the uranium variability EFRI made changes to the ca ing and urrounding area in May 2017. The top of the ca ing (' TOC ') for MW-5 was lightly below the ground urface and may have inadvertently aUowed dust and dirt to enter the well during ampLing activities. To addres thi i ue EFRI extended the TOC several feet and regraded the area urrounding the well. After the TOC was extended, the well was overpumped to remove any dirt which may have been introduced during these field activities. All uranium data collected in MW-5 after the extension of the casing are below the GWCL and no further actions were required for this well. MW-12 is west of MW-5 on the dike between Cell 3 and Cell 4B. When wells MW-5 and MW- 12 were installed the TOC for both wells was above the ground surface by several feet. During the construction of the dike of Cell 4B several feet of fill dirt was placed around MW-5 and MW-12. MW-5 and MW-12 were not extended and the TOC of both MW-5 and MW-12 was slightly below the ground surface. As previously noted, MW-5 was extended in May 2017 in response to variable uranium concentrations likely caused by dust and dirt entering the well during sampling activities. 55 Since MW-12 has reported exceedances of uranium similar to MW-5 and due to the proximity of MW-12 to MW-5, prior to completing a SAR, EFRI believed it was appropriate to first address potential physical causes. In an effort to address potential physical causes of the exceedances, EFRI made changes to the casing and urrounding area of MW-12 in October 2020. The TOC for MW-12 was slightly below the ground surface and may have inadvertently allowed dust and dirt to enter the well during ampJjng activitie . To addre this is ue EFRI extended the TOC several feet and regraded the area ·urrounding the well. After the TOC was extended, the well was overpumped to remove any dirt which may have been introduced during these field activities. These activities were completed after the third quarter 2020 sampling event was conducted. EFRI submitted a Plan and Time Schedule as required by the GWDP for MW-12 to address consecutive exceedances of uranium and selenium in MW-12. The Plan and Time Schedule stated that EFRI would continue accelerated monitoring of selenium and uranium in MW-12 for four quarters beginning with the fourth qua1ter 2020 through the third quarter 2021. Progress and results will be discussed in the routine quarterly groundwater reports. The fourth quarter MW-12 results for selenium and uranium were below their respective GWCLs. No further actions for MW-12 were required. The groundwater monitoring program at the Mill has historically had oumerou well wilh elevated turbidjty, tmbidity levels which could not tabilize to within 10% Relative Percent Difference (10% RPO) or both. Identification of equipmen problem and jmprovements to field sampling practices did not result in improvements to measured turbiditie . Ongoing turbidity issues were the result of monitoring requirements which were most likely ill-suited to the site geology. It is uspected that many well at the Mill might not be capable of attaining a turbidity of 5 nephJometric turbidity unit ( NTU ') due to the natural conditions in the formation hosting tb perched monitoring well (the Burro Canyon Formation and Dakota Sand tone). Clay interbed occur in both the Burro Canyon Formation and Dakota Sandstone, and friable materials occur within the Burro Canyon Formation. Saturated clays aad friable materials will likely continue to be mobilized using standard purging technique current1y in u e for the ampli.ng program at the Mill. Mobilized kaolinite (a cementing material within lhe formation) is expected to be an additional continuing source of turbidity in perched well . EFRI ruscu ed the turbidity issues with DWMRC and agreed to complete a redevelopment program for the elected we.II at the Mill in a "good-faith" effort to reduce the turbidity level. Surging, bailing, and overpumping were determined to be the preferred well devel pment technique ·. The rationale for u ·ing surging and bailing followed by overpumping i con ·istent with EPA guidance and guidance provided in other technical papers and publications. Select, nonpumping, chloroform, nitrate and groundwater POC, wells were redeveloped during the period from fall 2010 to pring 2011 by surging and bailing followed by overpumping. The results of the redevelopment are provided in the Report entitled: Redevelopment of Existing Perched Monitoring Wells White Mesa Uranium Mill, Near Blanding Utah, prepared by Hydro Geo Chem, Inc. September 30, 2011 (the 'Redevelopment Report"). The Redevelopment Report provides a qualitative description of turbidity behavior before and after redeveJopment and 56 provides a number of conclusions and recommendations. A copy of the Redevelopment Report wa previously submitted under eparate cover. The Redevelopment Report was closed out by the Director in a letter dated November 15, 2012. As described above, the existing wells have been reviewed by the Director, and repairs, modifications, retrofits, etc. have been made as required to conform those wells to the requirements of Part I.E.4 of the Permit, to the extent reasonably practicable. 2.9.6.2 Ground Water Sampling Groundwater sampling is performed in accordance with the requirements of Part I.E.5 of the Permit, which requires that all monitoring shall be conducted in conformance with the following procedures: a. Sampling -grab samples shall be taken of the groundwater, only after adequate removal or purging of standing water withi11 the well casing has been performed. b. Sampling Plan -all sampling hall be conducted to ensure collection of representative ample , and J·eliability and validity of groundwater monitoring data. c. Laboratory Approval -all analy es . hall be performed by a laboratory certified by the State of Utah to perform the tests required. d. Damage to Monitoring Wells -if any monitor well is damaged or is otherwise rendered inadequate for its intended purpose, the Permittee shall notify the Director in writing within five calendar days of discovery. e. Field Monitoring Equipment Calibration and Records -immediately prior to each monitoring event, the Permittee shall calibrate all field monitoring equipment in accordance with the respective manufacturer's procedures and gujdeJine . The Permittee shall make and preserve on-site written records of such equipment calibration in accordance with Part II.G and H of this Permit. Said records shall identify the manufacturer's and model number of each piece of field equipment used and calibration. In accordance with the requirements of Part I.E. I (a) of the Permit, groundwater ampling at the MiJJ i performed in accordance with the White Mes-a Uranium. Mill Ground Water Monitoring Quality Assurance Plan (QA.P) (the "QAP') which bas been approved by the Director. The QAP complie with UAC R3 l7-6-6.3(I) and (L) and by reference incorporates the relevant requirements of the Hcmdbook of Suggested Practices for Design and bistallation of Ground- Water Monitoring Wells (EPN600/4-89/034 March 1991), ASTM Standards on Grou,zd Water and Vadose Investigations (1996), Practical Guide for Ground Water Sampling EPA/600/2- 85/104, (November 1985) and RCRA Ground Water Monitoring Technical Enforcement Guidance Document (1986), unless otberwi e pecified or approved by the Director. A copy of the current version of the QAP, Date: 02-05-2022 Revision 7.7, is included as Appendix K. 2.9.7 Description and Justification of Parameters to be Monitored The groundwater parameter to be monitored are described in Table 2.9.1.3-1. The proce · of electing the groundwater quality monitoring parameters for the original Permit included examination of several technical factor . The e factors are Li ted below and discussed in detail in Section 4 on pages 9-19 of the 2004 Statement of Basis. : 57 a) The number and types of contaminants that might occur in feedstock materials processed at the Mill; b) Mill process reagents as a source of contaminants; c) Source term abundance in the Mill's tailings cell solutions, based on historic wastewater quality sampling and analysis that had been done at the Mill's TMS; and d) A consideration of contaminant mobility in a groundwater environment, based on site specific Ki information where available and lowest Kct values in the literature where site specific Ki information is not available. One additional parameter, tin, was added to the list of groundwater monitoring constituents in 2007. Tin was not originally a required groundwater monitoring parameter in the Permit, and was omitted from the original Permit due to non-detectable concentrations reported by EFRI in three tailings leachate samples (2004 Statement of Basis, Table 5). With the addition of the alternate feed material from Fansteel Inc., tin was estimated to increase from 9 to 248 tons in the tailings inventory. The Director concluded that, with an estimated Ki of 2.5 to 5, tin is not as mobile in the groundwater environment as other metals; however, with the acidic conditions in the tailings wastewater, tin could stay in solution and not partition on aquifer materials. As a result, tin was added as a monitoring constituent to Table 2 of the Permit. 2.9.8 Quality Assurance and Control Provisions for Monitoring Data Part I.E.1 ( e) of the Permit sets out some special conditions for groundwater monitoring. Under those conditions, the Mill must ensure that all groundwater monitoring conducted and reported complies with the following: 1) Depth to groundwater measurements -shall always be made to the nearest 0.01 foot; 2) Minimum Detection Limits -all groundwater quality analyses reported shall have a minimum detection limit or reporting limit that is less than its respective GWCL concentration defined in Table 2 of the Permit; and 3) Gross Alpha Counting Variance -all gross alpha anaJy ·is shall be reported with an error term. All gross alpha analysis reported wjth an activity equal to or greater than the GWCL, shall have a counting variance that is equal to or less than 20% of the reported activity concentration. An error term may be greater than 20% of the reported activity concentration when the sum of the activity concentration and error term is less than or equal to the GWCL. 4) All equipment used for purging and sampling of groundwater shall be made of inert materials. As mentioned in Section 2.9.6.2 above, Part I.E.l(a) of the Permit requires that all groundwater sampling shall be conducted in accordance with the currently approved QAP. The detailed quality assurance and control provisions for monitoring data are set out in the QAP, a copy of which is attached as Appendix K to this Application. 58 2.10 Plans and Specifications Relating to Construction, Modification, and Operation of Discharge Systems (R317-6-6.3.J) A di cus ed in Section 2.7. l above, the Mill bas been designed as a faciHty that does not discharge to groundwater or urface water. Tailing and other wastes a . ociated with Mill operation are de igned to be permanently dispo ed of in the MiU s TMS. The Mill' TMS can therefore be con idered the Mill' di. charge sy tern in that they permanently contain discharges from the Mill's process circuits and all other Mill tailings and wastes. The following plans and specifications and as built reports relating to TMS Cells 1, 2, 3, 4A and 4B are referenced in this ApplicaLion and were previously submitted on the dates noted below under separate cover: a. Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah, June 1979, prepared by D' Appolonia Con ulting Engineers, Inc.; b. Engineer's Report: Second Phase Design -Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah, May 198], prepared by D' Appolonia Consulting Engineers, Inc.; c. Construction Report: Initial Phase -Tailings Management System, White Mesa Uranium Project Blanding, Utah, February l982, prepared by D' Appolonia Consulting Engineers, Inc.; d. Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project, March 1983 prepared by Energy Fuels Nuclear, Inc.; e. Cell 4 Design, White Mesa Projecl Blanding, Utah, April 10, 1989, prepared by Umetco Minerals Corporation; f. Construction Report: Tailings Cell 4A, White Mesa Uranium Mill -Tailings Management System, August 2000, prepared by EFRI (then named International Uranium (USA) Corporation); g. Cell 4A Lining System Design Report For The White Mesa Mill Blanding, Utah, January 2006, prepared by GeoSyntec Consultants; and h. Cell 4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah, July 2008 prepared by Geosyntec consultants. 1. Cell 4B Design Report, White Mesa Mill, Blanding, Utah, December 8, 2007, prepared by Geo yntec Con uJtants J. Cell 4B Construction Quality Assurance Report, Volumes 1-3, November 2010, prepared by Geo yntec Consultants 2.11 Description of the Ground Water Most Likely to be Affected by the Discharge (R317-6-6.3.K) 2.11.1 General The groundwater most likely to be affected by a potential discharge from Mill activities is the perched aquifer. The deep confined aquifer under White Me a is found in the Entrada and underlying Navajo Sandstones, is hydraulically i olated from the perched aquifer, and i therefOJe extremely unlikely to be affected by any uch potential discharge . The top of the Entrada Sand tone at the 59 site is found at a depth of approximately 1,200 feet below land surface (see the discussion in Section 2.5 above). This deep aquifer is hydraulically i o.lated from the shallow perched aquifer by at least two shale members of the Morrison Formation, including the Brushy Basin (approximately 295 feet thick) and the Recapture (approximately 120 feet thick) Members. Other geologic units are also found between the perched and deep confined aquifers that include many layers of thin shale interbeds that contribute to hydraulic isolation of these two groundwater systems, including: the Morrison Formation We ·twater Canyon (approximately 60 feet thick), and Salt Wash (approximately 105 feet thick) Member , and the Summerville Formation (approximately 100 feet thick). Arte ion groundwater co11ditions found in the deep Entrada/Navajo Sandstone aquifer also reinforce this concept of hydraulic isolation from the shallow perched system. See the discussion on page 2 of the 2004 Statement of Basis. 2.11.2 Background Ground Water Quality in the Perched Aquifer This Section describes the groundwater quality in the perched aquifer. See Sections 2.5.1.3, 2.5.1.4 and 2.5.1.5 above for a more detailed de cription of the perched aquifer itself, the depth to ground water the aturated thick.ne , flow dil'ection, porosity, hydraulic conductivity and flow system characteristics of the perched aquifer. As mentioned in Section 2.9 .1.5 above, a significant amount of historic groundwater quality data had been collected by EFRI and previous operators of the Mill for many wells at the facility. However, at the time of original issuance of the Permit, the Director had not yet completed an evaluation of the historic data, particularly with regard to data quality, and quality a urance issues. The Director also noted several groundwater quaLity issues that needed to be resolved prior to a determination of background groundwater quality at the site ucb a · a number of constituents that exceeded their respective GWQS and long term trend in uranium in downgradient wells MW-14, MW-15 and MW-17, and a spatial high of uranium in those three downgradient wells. As a result of the foregoing, the Director required that the Existing Well Background Report be prepared to address and re olve these issues. EFRI (formerly DUSA) prepared the Exi ting WeH Background Report that evaluated all historic data for the thirteen exi ting wells (MW-3 ha been abandoned as discussed in Section 2.9.6.1) for the purpo e of establishing background groundwater quality at the site and developing groundwater compliance limits GWCLs under the GWDP. Prior to review and acceptance of the cooclu ion. in the Existing Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells based primarily on the analysis performed in the Existing Well background Report. It should be noted, however, that, because the GWCLs had been set at the mean plu second standard deviation or tbe equivalent, un-impacted groundwater would normally be expected to exceed the GWCL approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of aJl sample results, and do not oeces, arily represent impacts to groundwater from Mill operations. 60 As required by the Permit, the Existing Well Background Report addre ·sed all available historic data, which includes pre-operational and operational data, for the compliance monitoring wells under the Permit that were in existence at the date of issuance of the Permit. The Regional Background Report focuse on the pre-operational site data and the available regional data to develop the be t available et of background data that could not have been influenced by Mill operation . The New Well Background Report, which was required by the Perm.it, analyzed the data collected from tbe new weUs, which were installed in 2005, to determine background concentrations for constituents listed in the Permit for each new well. The Exjsting Well Background Report and the New Well Background Report were prepared to atisfy everal objectives. Fir t in the case of the Existing Well Background Report, to perform a quality a surance evaluation and data validation of the existing and historical on-site groundwater qualHy data in accordance with the requirements of the Permit, and to develop a databa. e consisting of hi t.orjcal groundwater monitoring data for "existing" wells and constituents. Second in the case of the New Well Background Report, to compile a database consisting of monitoring results for new wells, whlch were colJected subsequent to issuance of the Permit, in accordance with the MiJJ's QAP data quality objectives. Third, to perform a statistical, temporal and spatial evaluation of the exi ting well and new well data bases to determine if there have been any impact to groundwater from Mill activities. Since the Mill is an existing facility that has been in operation ince 1980, such an analy i of historic groundwater monitoring data wa required in order to verify that the monitoring re ults to be used to determine background groundwater quality at the site and GWCLs have not been impacted by Mill activities. Finally, since the analysis demonstrated that groundwater has not been impacted by Mill activities, to develop a GWCL for each constituent in each well. The Regional Background Report was prepared as a supplement to the Existing Well Background Report to provide further support to the conclusion that Mill activities have not impacted groundwater. In evaluating the historic data for the existing wells, lNTERA used the following approach: • If historic data for a constituent in a well do not demonstrate a statistically significant upward trend then the propo ed GWCL for that con tituent i accepted a repre entative of background, regardless of whether or not the propo ed GWCL exceed the GWQS for that con tituent. This is becau e the monitoring re ults for the con tituent can be considered to have been consistently representative since commencement of Mill activities or installation of the well; and • If historic data for a con tituent in a monitoring well represent a tati ·ticalJy significant upward trend or downward trend in the case of pH, then the data is further evaluated to 61 determine whether the trend is the result of natural causes or Mill activities. If it is concluded that the trend results from natural causes, then the GWCL propo ed in the Existing Well Background Rep01t will be appropriate. After applying the foregoing approach INTERA concluded that, other than some detected chloroform and related organic contamination at the Mill site which is the ubject of a . eparate inve tigation and remedial action, and that is the re ult of pre-Mill activitie ·, and some elevated nitrate concentration · in certain wells which were considered to be a ooiated with the chloroform plume, there have been no impacts to groundwater from MiJJ activities (See Section 2.16.1 below relating to the chloroform contamination and Section 2.16.2 [elating to the nitrate contamination). In reaching this conclusion, INTERA noted that, even though there are a number of increasing trends in various constituents at the site, none of the trends are caused by Mill activities, for the following reasons: • There are no noteworthy correlations between chloride and uranium iu wells with increa ing trends in uranium, other than in upgradient well MW-19 and MW-J 8, which INTERA concluded are not related to any potential tailings eepage. INTERA noted that it is inconceivable to have an increasing tret1d in any ther parameter cau ed by seepage from the Mill tailings without a corresponding increa e in chloride; • There are ignificant increasing trends upgradient in MW-J , MW-18 or MW-19 in uranium, ulfate, TDS iron, elenium thallium, ammonia and fluoride ,md far downgradient in MW-3 in uranium and elenium sulfate, TDS and pH (decrea ing trend). INTERA concluded that thi provi.des very strong evjdence that natural force at the site are causing increasing trend in these con tituent (decrea ing in pH) in other wells and supports the conclusion that natural force are also cau ing increa ing trends in other constituents as well; and • On a review of the spatial distribution of constituents, it is quite apparent that the constituents of concern are dispersed across the site and not located in any systematic manner that would suggest a tailings plume. JNTERA concluded that, after extensive analysi. of the data and given the conclu ion that there have been no impacts to groundwater from Mill activities, the GWCL. ·et out in TabJe J 6 of the Existing Well Background Report are appropriate and are indicative of background ground water quality. INTERA did advj e, however, that propo ed GWCL for all the trending con tituents should be re-evaluated upon Permit renewal to determine if they are till appropriate at the time of renewal. See Table 16 of the Existing Well Background Report for INTERA calculation of background ground water quality as repre ented by the proposed GWCLs. See Section 6.0 of the Existing Well Background Report for a discus ion of lhe tati tical manner used to calculate each proposed GWCL. Upon approval of the Exi ting Wells Background Report, the Director required that the New Well Background Report be prepared to addre and resolve similar issues in the newer wells. EFRI prepared the New Well Background Report that evaluated all historic data for the nine new wells for the purpo e. of establi hing background grmmdwater quality at the site and developing 62 GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the New Well Background Report, the GWCLs for the new wells were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. In evaluating the new well data, INTERA used the same approach in the New Well Background Report that was used in the Existing Well Background Report for existing well data. In addition, INTERA compared the groundwater monitoring results for the new wells to the results for the existing wells analyzed in the Existing Well Background Report and to the pre-operational and regional results analyzed in the Regional Background Report. This was particularly important for the new wells because there is no historic data for any constituents in those wells dating back to commencement of Mill operations. A long-term trend in a constituent may not be evident from the available data for the new wells. By comparing the mean concentrations of the constituents in the new wells to the results for the existing wells and regional background data, INTERA was able to determine if the constituent concentrations in the new wells were consistent with background at the site. INTERA concluded that after applying the foregoing approach, there have been no impacts to groundwater in the new monitoring wells from Mill activities. INTERA concluded that the groundwater monitoring results for the new wells are consistent with the results for the existing wells analyzed in the Existing Well Background Report and for the pre-operational and regional wells, seeps and springs analyzed in the Regional Background Report. INTERA noted that there were some detections of chloroform and related organic contamination and degradation products and nitrate and nitrite in the new wells, which are now the subject of two separate investigations (see Sections 2.16.1 and 2.16.2), but that such contamination was the result of pre-Mill activities. As a result, given the conclusion that there have been no impacts to groundwater from Mill activities, INTERA concluded that the calculated GWCLs for new wells set out in Table 10 of the New Well Background Report are appropriate, and are indicative of background ground water quality. Again, INTERA noted that GWCLs for trending constituents should be re- evaluated upon Permit renewal to determine if they are still appropriate at the time of renewal. Additionally, the Flow Sheet states to "Consider an Alternate Approach" for determination of GWCLs in trending constituents. In its report, INTERA recommended, as an alternative, that GWCLs be set at the highest of a) the Flow Sheet approach, b) the highest historical value or c) the fractional approach; provided that in no event would the GWCL be less than mean plus 20% . This approach was rejected by the DRC in favor of the mean plus two standard deviation or equivalent. See Table 10 of the New Well Background Report for INTERA's calculation of background ground water quality as represented by the proposed GWCLs. See Section 2.2 of the New Well Background Report for a discussion of the statistical manner used to calculate each proposed GWCL. The University of Utah Study confirmed INTERA's conclusions in the Background Reports that groundwater at the site has not been impacted by Mill operations (see the discussion in Section 1.3 above). The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the nine new wells based primarily on the analysis performed during the New Well 63 Background Report. IL houJd be noted bowever, that, because the GWCLs were set at the mean plus two tandard deviation , or the equivalent un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedance. are expected in approximately 2.5% of al.I ample re ults, and do not necessarily represent impacts to groundwater from Mill operations. The GWDP dated January 20 20 IO required the completion of eight con ·ecutive quarters of groundwater ampling and anaJy is of MW-20 and MW-22, and later ubmjttal of another Background Report to determine if weUs MW-20 and MW-22 hould be added a POC monitoring weJls. Data from MW-20 and MW-22 were analyzed in the pre-operational and regional background addendum (INTERA 2007a)· however there wa not a complete data et at the time. Although well MW-20 and MW-22 were in ·cal.led in 1994, they were not ampled regularly until the second quarter of 2008. The~ ejghth full round of ampling wa, completed dming the fir t quarter of 2010, and EFRI submitted to the Director the Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, June 1, 2010, prepared by INTERA, Inc. (the "MW-20 and MW-22 Background Report"). DWMRC classified MW-20 and MW-22 as general monitoring wells, and GWCLs have not been e tabli. hed for the e well . MW-20 and MW-22 are sampled semiannually. The background report for MW-20 and MW-22 upport the conclusions of the previous background assessments that groundwater at the site ha n t been impacted by Mill operations. Part I.H.6 of the GWDP dated June 21, 2010 requjred the in tallation of three hydraulically downgradient wells adjacent to Tailings Cell 4B (MW-33, MW-34, and MW-35) prior to placement of olids or fluid in Cell 4B. The purpo e of the e monitoring well wa to provjde earl y detecti n of potential impact: to the hallow groundwater from Tailings Cell 4B. EFRI installed MW-33 MW-34 and MW-35 as required. Of thee three weJls installed near tailing Cell 4B, only MW-35 was hydraulically acceptable, with five feet or more of saturated thickness. MW-35 was sampled quarterly since fourth quarter 2010 to collect eight statistically valid data points for the comp.letion of the Background Report and calculation of GWCLs. MW-33 and MW-34 had insufficient water for sampling, with aturated thicknesses less than five feet. MW- 33 is completely dry, and no samples or depth to water measurements are collected from this well. Quarterly depth to water is measured in MW-34, but no sampling or analysis is required. Part l.H.4 of the February 15 2011 GWDP required the installation of two wells hydraulically downgradient of Tailing CeU 4B as replacement for MW-33 and MW-34. EFRI installed MW-36 and MW-37 as required. MW-36 and MW-37 were sampled quarterly beginning in the third quarter 2011 to collect eight statistically valid data points for the completion of the Background Report and calculation of GWCLs. The Background Report for wells MW-35, MW-36, and MW-37 was submitted to the Director on May 1, 2014. The findings of the Background Analysis for wells MW-35, MW-36, and MW- 37 support previous conclu ·ions that the groundwater at the Mill is not being affected by any potential TMS seepage. The Director incorporated MW-35, MW-36 and MW-37 in a , ub equent revision of the GWDP and these wells are , ampled as required. The background reporl for MW- 35, MW-36 and MW-37 support the conclusions of the previou background as e sments that groundwater at the site has not been impacted by Mill operations. 64 Three wells have been added by EFRI in response to request from the UMUT far cro -gradient to the TMS to provide water level data and to provide additional information on ite geology and naturally occurring geochemical behavior ·. The three well MW-38, MW-39 and MW-40, were in tailed in February 2018. The Background Report for well MW-38, MW-39 and MW--40 was ubmitted to the Director on June 7, 2021 after sufficient data had been collected to complete the stati ticaJ evaluation. The finding· of the Background Analy i for well · MW-38, MW-39, and MW-40 support previou conclu ion that the groundwater at the Milli not being impacted by any potential TMS seepage. The Director approved the background report for MW-38 MW-39, and MW-40 by Jetter dated June I 6 2021. MW-38, MW-39, and MW-40 will be incorporated into a ub equenl revi. ion of the GWDP. Until uch time a the e well are incorporated into the GWDP, they are sampled on a quarterly ba is. Part I.G.2 of the Permit provides that out-of-compliance . tatu exi t when the concentration of a p llutant in two consecutive sample from a compliance monitoring point exceeds a GWCL in Table 2 of the Permit. Per the requirement of Part I.G.4(c) of the Permit, EFRJ is required to prepare and ubmit written pJaus and time chedule., for Director approval, to fully comply with the requirements of Part I.G.4(c) of the Permit reJati11g to any uch out-of-compliance situation, including, but not limited to: (i) submittal of a written assessment of the source(s); (ii) submittal of a written evaluation of the extent and potential dispersion of said groundwater contamination; and (iii) ubmittal of a written evaluation of any and all potential remedial actions to restore and. maintain ground water quality at the facility for the po.int of compliance well · and contaminants in que tion to en ure that: l) halJow groundwater quality at the facility will be restored and 2) the contaminant concentration. in ·aid point of compliance well will be returned to and maintained in compliance with their respective GWCLs. Twenty-five Plan and Time Schedules and twenty-two SAR have been ubmitted to address consecutive exceedances which have been noted in wells ince thee tablishmenl of the GWCLs in the January 20, 2010 GWDP. The Plans and Time Schedule and the SARs are inclllded in Table 2.11.2-l. These Plans and Time ScheduJe and SAR were previou Jy submitted under separate cover. Plan and Time Schedules submitted to the Director have been approved by the Director in letters to EFRI. The submission dates and the associated DWMRC approval dates of the Plans and Time Schedules and the associated SARs are listed on Table 2.11.2-1. Given the varied background groundwater quality at the site, previously identified rising trends in some wells and other factors, it cannot be assumed that consecutive exceedances of a constituent in a monitoring well means that contamination has been introduced to groundwater in that well. The exceedances may very well be the result of background influences. The approach in these Plans therefore is to first determine if the recent exceedances are the result of 65 background influences. If they are determined to be the result of background influences, then no remedial actions are required. If, however, they are determined to not be the result of natural background influences, then further analyses will be required. Based on the information available in the SARs, EFRI believes that the GWCL exceedances observed are the result of natural influences and reflect the need to adjust some of the GWCLs for the site. In addition to the SARs listed in Table 2.11.2-1, EFRI completed a supplementary investigation of rising trends present in MW-24/MW-24A. Tbe results of the analytical and te t data collected during the MW-24A study demon traced that natural proce-ses unrelated to dispo al of material in the TMS can account for the behavior of all trace metal of concern, as well as fluoride, in groundwater at MW-24 and MW-24A. Bottle- roll test results indicated that naturally-occurring trace metals can be mobi.lized at concentrations similar to or greater than in groundwater even without a large pH decrea e, suggesting that agitation alone, such as would occur during routine purging and sampling of low permeability wells such as MW-24A, could result in metals mobilization. The perched g.rollndwater y. tern ho ted by the Burro Canyon Formation and Dakota Sandstone does not approach teady tate over much of the monitored area. A large part of the site perched water ystem is in a transient state and affected by long-term changes in water levels due to past and current activities unrelated to U1e di posal of material. to the TMS. Based on the results of the MW-24A tudy EFRI has voluntarily agreed to implement a Pha e 2 . tudy to determine what geochemical and hydrogeological influence are pre ent that may be affecting monitoring data collected at other well aero 'S the Mill , ite. Thi voluntary study will commence in mid to late 2022. 2.11.3 GWCL Determination for Field pH During the completion of the 4th Quarter 2010 Quarterly Groundwater Monitoring Report EFRl noted eleven perched groundwater monitoring well with pH measurements below the GWCL.. These wells are located upgrad.ient, cro s-grad.ient, and downgradient of the Mill and TMS. Investigation into the eleven pH GWCLs in que tion fodicated that the GWCL for groundwater pH in all wells established in the January 20, 20 IO GWDP were erroneou ly ba ed on historic laboratory results instead of field measurement as contemplated by Table 2 of the GWDP. EFRI noLified DWMRC that the existing GWCLs for groundwater pH were incorrectly based on laboratory results rather than field measurements and propo ed to ubmit revised descriptive statistics for field pH to be used as revised pH GWC by the end of the econd quarter 2011. EFRI received approval from DWMRC to proceed with the revision of the pH GWCLs based on field measurements. The data processing and statistical assessments necessary to revise the GWCLs based on historic field pH data were completed. The data proce sing and tati ticaJ assessments completed were based on the DWMRC-approved method · in the logic flow diagram included as Figure 17 of the New Well Background Report. Following the stati tical evaluation of pH data, EFRI compared the Mill groundwater pH data from the 2nd Quarter of 2011 including accelerated ampling results through June 2011 , and noted that all of the June 2011 groundwater result ·, and many of the other results from the 2nd Quarter, were already outside the revi ed GWCLs to be propo ed based on the logic flow diagram. 66 It was noted that the hi. torical trend of decrea ing pH, which wa addre ed in the Background Study Report , appeared to be present in nearly all well · throughout the Mill ite area, including upgradient downgradient and cro. -gradient wells in the groundwater monitorjng program. A of June 2011, all groundwater monitoring well demon trated a downward trend in the fieJd pH data over time. EFR[ notified DWMRC that the 2nd Quarter 20 I l data exceeded the recalculated GWCLs. EFRl advi ed DWMRC that, as a re ult of these finding , EFRI did not believe it wa appropriate to contfoue with it · effort: to re et the GWCL for pH ba ed on field pH data a originally planned, but in tead it appeared that it would be more appropriate to undertake a tudy to determine whether the decreasing trend in pH are due to natural influence and, if . o to determine a more appropriate way to determine GWCLs. EFRI and DWMRC agreed on further inve. ligation to be completed, as well a the ·teps and mile tone date to be incorporated into a pH Report. The procedures for inve ·tigating the decrea ing ite-wide pH trend i documented in the Plan to Investigate pH Exceedances in Perched Groundwater Monitoring Wells White Mesa Uranium Mill Blanding, Utah, Prepared by HydJO Geo Chem, Inc, April J3 2012 (HGC 2012a) (the pH Plan and Time Schedule'). The pH Plan and Time Schedule de cribed the pH awe. tigation which wa incorporated into the July 12, 20 J 2 Stipulated Con ent Agreement referred to above. The pH Plan and Time Schedule wa. previously submitted under separate cover. The Stipulated Consent Agreement of July J 2, 20 L2 specified that a pH Report be completed as well a a eparate inve tigation into the natural phenomenon that wa causing the ite-wide trend. As a result two report investigating and describing the causes of the pH trend were completed. The e report are the pH Report dated November 9 2012 (INTERA 2012b) and the Investigation of P)rite in the Perched Zone, White Mesa Uranium Mill ("Pyrite Report'), dated December 7 2012 (HGC, 2012c). The pH Report con i t. of a tati ·tical and geochemical evaluation of the decline in pH in groundwater wells at the Mill. The primary conclusion from the pH Report was that the hi toricaJ trend of decrea:ing pH, which was addre ed in the Background Study Reports, appear. to be present in nearly all wells tlu·oughout lbe Mill site area, including upgradient downgradient and cro sgradient wells in the groundwater monitoring program and there seems to be no abatement of the trend. The wide-pread nature of the decrease in pH in upgradient, downgradient and cro · ·gradient well sugge ts that the pH decrea e result from a natural phenomenon unrelated to Mill operation , which i al o confirmed by the indicator parameter analysi conducted as patt of the pH Report. A discus ·ed in The Pyrite Report, the mo ·t likely cau e of declining pH across the site appear · at this time to be the oxidation of pyrite, po ibly due to increasing water level. at the ite attributed primarily to recharge of wildlife pond. and/or the introduction of oxygen into the perched water zone a a re ult of increased groundwater ampling frequency. Ba ed on the concJa. ion that the pH trend wa. caused by natural phenomenon, the pH Report recalculated the Groundwater Compliance Limit ("GWCL ") for all compliance monitoring well at the ite. The Pyrite Report evaluated and quantified the presence of pyrite throughout the Mill site, and identified and quantified the mechanism by which it contributes to the sitewide decline in pH. 67 The results of the inve tigation support pyrite oxidation as the most likely mechanism to explain decreases in pH and increases in sulfate concentrations in site wells and indicates that pyrite must be considered in assessing perched water cbemi try in the future. The complex interaction of the various naturally occurring factor · identified at the ite, including the presence of pyrite at varyi11g concentrations, variable oxygen tran port, and variable carbonate species concentrations, i expected to re ult in relatively large background variation in pH, sulfate (and therefore TDS) concentration , a well as variation in background concentrations of pH sensitive analyte. such as metals. The expected impact of the e various factors on pH and analyte concentration , all of which are unrelated to Mill operations, is generally consi tent with site analytical results, suggesting that pyrite oxidation plays a significant role in perched water chemistry at the site. The primary conclusion from the activities conducted to date and described above is that the pH trends are not due to potential TMS cell leakage or Mill activities, but to a natural phenomenon unrelated to Mill operations. In an effort to diminish any trends that may have resulted in whole or in part, from increasing water levels attributed to the Wildlife ponds at the Mill, EFRI discontinued recharging the two most northern of these ponds, commencing in March 2012. Although decreasing pH trends occurred in nearly all MW-series wells until about 2016, pH began to tabilize and then increase. The mechani m(.) for thi. apparently ite-wide change from generally decrea ing to increa ing pH, affecting well that, with i:e, pect to perched groundwater flow, a.re located far upgradient far cros -gradient and far downgradient of the TMS in addition to wells located near and within the TMS, are not known at this time. Such cban_ge could re ·ult from several potential mechanisms. First, the pH increases may result from reduced acid generation caused by a general reduction in pyrite reactivity near site wells. Reduced pyrite reactivity could result from passivation of pyrite surfaces caused by increases in dissolved oxygen via the mechanisms discussed above. The passivation process could potentially have been accelerated by the site-wide well redevelopment effort that occurred during late 2010 and early 2011. Second, the pH increases may result from reduced acid generation caused by degradation and reduction in concentration of the more reactive fractions of pyrite present near the wells. The more reactive fractions would include the generally more fine-grained fractions (which have a larger ratio of surface area to volume); or perhaps the fraction composed of the less stable polymorph of iron sulfide (marcasite). Third, the change in pH trends could be related, at least in part, to the non-steady state conditions that exist over much of the site due to long-term changes in water levels related to former seepage from formerly used wildlife ponds and due to changes induced by chloroform and nitrate pumping. Finally although the . pecific mechanj ms can only be speculated upon, pH changes could potentially re. ult from long-term change in groundwater chemistry related to climatic variation. For example, groundwater cbemi try change could result from changes in recharge rates 68 resulting from changes in precipitation amounts; and changes in groundwater chemistry could result from changes in precipitation pH. Regardless of the specific potential mechanism(s) however, the po t-20 L6 ite-wide pH increase measured in site wells cannot result from a TMS impact because TMS olutions have very Jow pH. The post-2016 increasing pH trends indicate that TMS operation has not impacted groundwater. 2.11.4 Quality of Ground Water at the Compliance Monitoring Point The analytical results from groundwater sampling are reported quarterly in Groundwater Monitoring Reports, which are filed with the Director pursuant to Part I.F.1 of the Permit. 2.12 Compliance Sampling Plan (R317-6-6.3.L) The Mill's plan for sampling groundwater compliance monitoring points is discu ed in detail in Section 2.9.1.3 above, and the plan for sampling the leak detection systems in CeU 4A and 4B is discussed in Sections 2.15.3 and 2.15.4 below. This section addresses other sampling required under the Permit. As the Mill is designed not to discharge to groundwater, there are no flow monitoring requirements in the Permit. 2.12.1 Tailings Cell Wastewater Quality Sampling Plan Part I.E.10 of the Permit requires that, on an annual basis, EFRI collect wastewater quality amples from each wastewater ource at each tailings ceH at the facility, includfog wa tewater in urface impoundment , and limes drain . The sampling i conducted in August of each calendar year in compliance with an approved plan. The Tailings SAP (dated July 8 2016) was approved by the Director on Augu t 8 2016. A copy of the approved Tailings and Slim.es Drain Sampling Program Revision 3.0, July 8, 2016 is attached a Appendix L to this Applkation. The purpose of the Tailings SAP is to characterize the source term quality of all tailings cell wastewaters, including impounded wastewaters or process waters in the TMS, and wastewater or leachates collected by internal limes drains. The Revision 3.0, Tailings SAP requires: • Collection of samples from the pond area of each active cell and the slimes drain of each cell that has commenced de-watering activities; • Sample · of tailings and slimes drain material will be analyzed at an off ite contract laboratory and subjected to the analytical parameters included in Table 2 of the Permit and general inorganics listed in Part I.E.l(d)(2)(ii) of the Permit, as well a-semi-volatile organic compounds; • A detailed description of all sampling methods to be employed; • The procedures utilized to conduct these analyses will be standard analytical methods utilized for groundwater sampling and a.· shown in Section 8.2 of the QAP; • The contracted laboratory will be certified by the State of Utah in accordance with UAC R317-6-6. l 2A; and • 30-day advance notice of each annual sampling event must be given, to allow the Director to collect split samples of all tailings cell wastewater sources. 69 The tailing and lime drain ampJing events are subject to the currently approved QAP, unless otherwi e specifically modified by the Tailing SAP to meet the specific needs of this type of ampling. Tbe QAP has been approved by the Director and satisfies the most applicable requirements of the following reference , unless otherwise specified by the Director through his approval of the Tailings SAP: • Standard Methods for the Examination of Water and Wastewater, twentieth edition, 1998; Library of Congress catalogue number: ISBN: 0-87553-235-7; • E.P.A. Methods for Chemical Analysis of Water and Wastes, 1983; Stock Number EPA- 600/4-79-020; • Techniques of Water Resource Investigations of the U.S. Geological Survey, (1998); Book 9; • Monitoring requirement in 40 CFR part 14 l and 142, 2000 ed. Primary Drinking Water Regulations and 40 CFR parts 264 and 270, 2000 ed.; and • National Handbook of Recommended Methods for Wat er-Data Acquisition GSA-GS edition; Book 85 AD-2777, U.S. Government Printing Office Stock Number 024-001 - 03489-1. 2.12.2 White Mesa Seeps and Springs Sampling Plan The in.itial Permit required EFRl to ubmil a plan for groundwater ampJing and analysi of all eeps and spring found downgradient or cro s gradient from the TMS for DiJector review and approval. Tbe Djrector approved the plan on March 17, 2009. Pur uant to a reque. t from the DWMRC, the plan wa rev.i ed in 2016. A copy of the Sampling Plan.for Seeps and prings in the Vicinity of the White Mesa Uranium Mill, Revi ion: 3 November 11 2019 is attached a Appendix C to this Application. The Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill wa approved by DWMRC on November 22, 2019. Under the Seep. and Spring. SAP sampling i conducted on an annual basis between May 1 and July 15 of each year, to the extent ufficient water is available for sampling, at six identified eep. and . pr.ing near the Mill. The ampling locations were selected to correspond with those . eeps and prings sampled for the ini tial Mill site characterization performed in the 1978 ER, plus additional ites located by EFRI, the United States Bureau of Land Management and Ute Mountain Ute Indian Tribe representatives. Sample are analyzed for all groundwater monjtoring parameters found .in Table 2 of the Permit. The laboratory procedures utilized to conduct the analyse · of parameter listed in Table 2 are the , ame a utilized for groundwater arnpling and a hown in Section 8.2 of the QAP. In addition to these laboratory parameter , the pH, temperature, redox potential, DO and conductivity of each ample will be mea ured and recorded in the field. Laboratories selected by EFRI to perform analyse· of eeps and springs sampl are required to be certified by the State of Utah in accordance with UAC R317-6-6.12.A. The seeps and pring sampling events are subject to the currently approved QAP unless otherwise specifically modified by the Seeps and Spring SAP to meet the specific needs of this type of sampling. The QAP has been approved by the Director and ati fie the applicable 70 requirement of the references listed in Section 2.12.1 above, unless otherwise specified by the Director thrnugh his approval of the Seeps and Springs SAP. 2.12.3 Monitoring of Deep Wells Due to the fact that the deep confined aquifer at the site is hydraulically isolated from the shallow perched aquifer ( see the discussion in Section 2.11.1 above) monitoring of the deep aquifer is not required under the Permit. 2.13 Description of the Flooding Potential of the Discharge Site (R317-6-6.3.M) 2.13.1 Surface Water Characteristics The Mill site is located on White Mesa, a gently loping (l % SSW) plateau that i · phy ically defined by the adjacent drainages which have cut deeply into regional sand tone formations. There is a small drainage area of approximately 62 acres (25 ha) above the . ite that could yield surface runoff to the site. Runoff from the mesa i conveyed by the general urface topography to either Westwater Creek, Corral Creek, or to the outb into an unnamed branch of Cottonwood Wa h. LocaJ porou oil condition topography and low average annual rainfall of 13.3 inches (reported as 11.8 by Dames and Moore in bj tori reports) cau e these streams to be intermittently active re ponding to pring nowmelt and local rainstorms (particularly thunderstorms). Surface mnoff from approximately 624 acres of the Mill drains westward and is collected by We twater Creek, and runoff from another 384 acres drains east into Corral Creek. The remaining 4,500 acres of the outhern and outhwe tern portions of the site drain indirectly in to Cottonwood Wa h (1978 ER, p. 2-143). The ite and vicinity drainages carry water only on an intermittent basis. The major drainages in the vicinity of the Mill are depicted in Figure 12 and their drainage areas are tabulated in Table 2.1.3.1-1. Total runoff from the mesa (total yield per watershed area) is estimated to be less than 0.5 inch annually (1978 ER, p. 2-143). There are no perenniaJ urface waters on or in the vicinity of the Mill site. This is due to the gentle slope of the me a on which the . ite is located, the low average annual rainfall of 13.3 inches per year at Blanding, .local oil characteristics and the porous nature of local stream channels. Prior to MilJ con Lruction three small ephemeral catch basins were present to the northwest and northeast of the Mill site. Corral Creek is an intermittent tributary to Recapture Creek. The drainage area of that portion of Corral Creek above and including drainage from the eastern portion of the site is about 5 square miles. Westwater Creek is also an intermittent tributary of Cottonwood Wash. The Westwater Creek drainage basin covers nearly 27 square miles at its confluence with Cottonwood Wash 1.5 miles west of the Mill site. Both Recapture Creek and Cottonwood Wash are similarly intermittently active, although they carry water more often and fo.r longer period of time due to their larger water bed area . They both drain to the ·outh and are tributarie. of the San Juan River. The confluence of Recapture Creek and Cottonwood Wa b with the San Juan River are approximately 18 mile outh of the Mill site. The Sao Juan River a major tributary for the upper CoJorado River has a drainage of 23,000 square miles measured at the USGS gauge to the we t of Bluff Utah () 978 ER, p. 2-130). 71 Storm runoff in these streams is characterized by a rapid rise in flow rates, followed by rapid recession primarily due to the small storage capacity of the surface soils in the area. For example, on August 1, 1968, a flow of 20,500 cubic feet per second was recorded in Cottonwood Wash near Blanding. The average flow for that day, however, was only 4,340 cubic feet per second ("cfs"). By August 4, the flow had returned to 16 cfs (1978 ER, p. 2-135). Monthly streamflow summaries as updated from Figure 2.4 of the FES are presented in Figure 13 for Cottonwood Wash, Recapture Creek and Spring Creek. Flow data are not available for the two smaller water courses closest to the Mill site, Corral Creek and Westwater Creek, because these streams carry water infrequently and only in respon ·e to local heavy rainfall and snowmelt, which occurs primarily in the months of April, Augu t and October. Flow typically ceases in Corral Creek and Westwater Creek within 6 to 48 hours after precipitation or snowmelt ends. 2.13.2 Flood Protection Measures The Mill was designed and constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the TMS; and b) diverting runoff from surrounding areas away from the Mill site via three drainage ditches that have been constructed north (upslope) of the Mill facility. A detailed description of the flooding potential of the site, including the 6-hour probable maximum precipitation (which is more conservative than the 100-year flood plain), and applicable flood protection measures is provided in the UMETCO Minerals Corporation: White Mesa Mill Drainage Report for Submittal to NRC, January 1990. In addition to the foregoing designed control features, the facility has developed a Stormwater Best Management Practices Control Plan which includes a description of the site drainage features and the best management practices employed to ensure appropriate control and routing of stormwater. A copy of the Mill's Stormwater Best Management Practices Plan is included as Appendix G to this Application. 2.14 Contingency Plan (R317-6-6.3.N) As required by Part I.H.15 of the Permit, the Mill has a Contingency Plan for regaining and maintaining compliance with the Permit limits and for re-establishing best available technology as defined in the Permit. A copy of the most current approved version of the Mill's Contingency Plan is included as Appendix M to this Application. 2.15 Methods and Procedures for Inspections of the Facility Operations and for Detecting Failure of the System (R317-6-6.3.0) Part I.D. of the Permit sets out a number of DMT and BAT standards that must be followed. Part I.E. of the Permit sets out the Ground Water Compliance and Technology Performance Monitoring requirements, to ensure that the DMT and BAT standards are met. These provisions of the Permit, along with the DMT Plan, Cell 4A and Cell 4B BAT Monitoring Operations and Maintenance Plan and other plans and programs developed pursuant to these Parts, set out the methods and procedures for inspections of the facility operations and for detecting failure of the system. 72 In addition to the programs discussed above, the following additional DMT and BAT performance standards and associated monitoring are required under Parts I.D and I.E. of the Permit 2.15.1 Existing Tailings Cell Operation Part I.D.2 of the Permit provides that authorized operation and maximum disposal capacity in each of the existing TMS CeJJs 1, 2 and 3 hall not exceed the levels authorized by the Mill License and that under no circumstance · shall the freeboard be less than three feet, as measured from the top of the FML. Part I.E.7(a) of th Permit require · that the wa tewater pool elevation in Cells 1 and 3 must be monitored weekly to en ure compliance with the maximum wastewater elevation criteria mandated by Condition 10.3 of the Mill Licea e. However, a letter from the Director dated January 27, 2011, which approved the use of Cell 4B, and a subsequent letter dated March 14, 2011, stated that authorization of the use of Cell 4B and approval of the DMT and Cell 4A Operations and Maintenance ("O&M") Plans effectively eliminated the former freeboard elevation requirements for tailings Celli 3 and 4A. Part I.D.2 further provide that any modification by EFRI to any approved engineering design parameter at these exi ting TMS cell require prior Director appr val, modification of the Permit and i. uance of a con t:ruction permit. 2.15.2 Existing Facility DMT Performance Standards Part I.D.3 of the Permit requires EFRI to operate and maintain certain Mill site facilities and the exi ting TMS to minimize the potential for wastewater release to groundwater and the environment, including, but not limited to the following additional DMT compliance measures described in Sections 2.15 .2.1 through 2.15 .2.5 below. 2.15.2.1 DMT Monitoring Wells at Cells 1, 2 and 3 Parts I.D.3 (a) and (d) require that at all time EFRl operate and maintain Cell l 2 and 3 to prevent groundwater quality conditions in any nearby monitoring well · from exceeding the GWCLs in Table 2 of the Permit. The groundwater compliance monjtoring program de cribed in detail in Section 2.9.1.3, is designed to provide early detection of a y tem failure in the TMS. 2.15.2.2 Slimes Drain Monitoring The Permit revi ions is. ued prior to the January 20 I 8 renewal included a provi ion at Pait l.D.3(b)(l) (now I.D.3(b)(3)) to calculate the phreatic surface above the ·limes drain evacuation pump and with that data to calculate the three-year running average of that elevation. The three-year mnning average would then be plotted along with previou. years calcu.lations. The mea. urement. that facilitate that calculation were taken quarterly o the p.lot would pre ent the tlu·ee-year running averages in temporal sequence. EFRI wa required to maintain a downward trajectory with no more than two consecutive calculations failing to show a downward trend. That formula erved to encourage EFRI to do the maximum possible to dewater. Prior to the 2018 i uance of the renewal Permit, EFRI ha been required to calculate accorcLing to that formula DWMRC staff ha noticed that the pace of dewatering bas decrea ed and approached a 73 horizontal asymptote. Factors beyond EFRI s control have intervened. However, EFRI has installed piezometer · and bas collected sample of the tailings to analyze what is happening in the tailing mass. There wa Lhe potential that EFRI could be in violation of this provision of the Permit through no fault of it. own bllt becau e the natural system would not cooperate with the regulatory authority. EFRJ ha since placed several feet of soil on Cell 2 to complete the primary radon barrier. That material ba surcharged lhe tailing ma , creating exce pore pre ure as the fluid i compressed along with the tailings. A a result of the increased pore pres ure, the phreatic urface ha risen, and the amount of fluid available for pumping has al o increa. ed. DWMRC has exercised discretion in not citing EFRI for missing wba amounted to an arbitrary date 'et by the Division, before it could be known how long the proce. would actuaHy take ba ed on the conditions of the system. The circumstances were beyond the rea onable control of EFRI. Moreover, the GWDP has been modified to remove the arbitrary date. Currently, Part I.D.3(b)(l) of the Permit requires that EFRI at all time maintain the average wastewater head in the slimes drain access pipe to be s low as rea onably achievable (' ALARA") in each tailings disposal cell in accordance with the approved DMT Plan. Compliance is documented in the average annual wastewater recovery report, which verifies that the maximum fluid volume which could practicably be extracted from the slimes drain in accordance with the systems in place was removed. Part I.E.7(b) of the Permit requires that EFRI monitor and record quarterly the depth to wastewater in the slimes drain access pipes a de ·cribed in the currently approved DMT Plan at Cell 2, and upon commencement of de-watering activities, at Ce!J 3, in order to en ure compliance with Part I.D.3 of the Permit. Specifically Part I.E.7(b) requires: 1. Perform at least 1 separate slimes drain recovery test at each disposal cell in each quarterJ y period of each calendar year that meets the requirement of Part I.D.3 2. De ignate operate maintain, and preserve one water level measuring point at the centerline of the .lime drain acce s pipe that has been surveyed and certified by a Utah licensed engineer or land surveyor, 3. Make all slimes drain recovery head test (depth to fluid) measurements from the same designated water level measuring point, and 4. Record and report all fluid depth measurements to the nearest 0.01 foot. 5. For Cell 3 these requirements shall apply upon initiation of tailings de-watering operations. At this time, de-watering of Cell 3 has not commenced. Quarterly mea urements of the wastewater bead in CeU 2 are reported in the quarterly DMT report. submitted to DWMRC pursuant to the requirement of Part I.F.l, Table 7 of the GWDP. The historic measurement · for 2009 thrnugh 2022 are included graphicaUy in Appendix J. Annual compliance assessments pursuant to Part I.D.3.b of the GWDP are submitted to DWMRC on or before March 1 of the following year. Part l .D.3.b specifically requires: TMS Cells 2 and 3 -including the following performance criteria: 74 1. Slimes Drain Maximum Allowable Head -the Permittee shall at all times maintain the average wastewater recovery head in the slimes drain access pipe to be as low as reasonably achievable (ALARA) in each tailings disposal cell, in accordance with the currently approved DMT Monitoring Plan. 2. Quarterly Slimes Drain Recovery Test -effective July 11, 2011, the Permittee shall conduct a quarterly slimes drain recovery test at each tailings cell slimes drain that meets the following minimum requirements: i. Includes a duration of at least 90-hours, as measured from the time that pumping ceases, and ii. Achieves a stable water level at the end of the test, as measured by three consecutive hourly water level depth measurements, with no change in water level, as measured to the nearest 0.01 foot. 3. Annual Slimes Drain CompUance -The Perm.ittee hall submit an annual report on or before March 1 following the reporting year which includes but is not limited to; 1) Monthly volumes of fluid pumped from the slime draim for each applicable tailings disposal cell; 2) The results of all quarterly slime drain recovery tests; 3) A calculation of average annual wastewater recovery elevation in the slimes drain access pipe, and; 4) The annual report shall include an assessment and verification that the maximum fluid volume which could practicably be extracted from the slimes drain in accordance with the systems in place was removed. Appendjx J includes the Cel1 2 slimes drain annual information submitted in the routine DMT report ince 2018. A noted above, the regulatory regime regarding Cell 2 slimes drain pumping and compliance point. ha been changed to address the addition of 4.5 feet of cover material and natural phenomenon inherent in the system. EFRI has met the current requirements and has pumped the maximum possible volume of fluids annually as described below. The amount of fluid pumped from the Cell 2 slimes is maximized. The slimes drain pump was lowered to the lowest point practicable to maximize the length of time the pump operates. In addition, the slimes drain pump in Cell 2 is activated and deactivated by a float mechanism and water level probe system. When the water level reaches the level of the float mechanism the pump is activated. Pumping then occurs until the solution level reaches the lower probe which turns the pump off. This system, rather than a timed system, assures that the pump operate the maximum time practicable thus maximizing the amount of fluid pumped. Unscheduled downtimes of the pump in the Cell 2 slimes are minimized, and the maximum fluid volume which could practicably be extracted from the slimes drain in accordance with the systems in place was removed. No additional optimization of the system is possible and EFRI has maximized the system components. EFRI has evaluated all data collected to date, data collection methods, and all related calculations required by the Permit, and has verified the accuracy and reliability of both the data and calculations reported. The Cell 2 slimes drain data are usable for the intended purpose of 75 determining compliance with the GWDP requirements. Cell 2 slimes drain pumping and monitoring are completed in accordance with Part I.D.3(b) and I.E.7(b) of the Permit for the reasons stated above. Additional detail regarding the Cell 2 slimes drain pumping system are included in the Slimes Drain Compliance Plan, which was submitted to DWMRC under separate cover on January 16, 2020. 2.15.2.3 Maximum Tailings Waste Solids Elevation Part I.D.3(c) of the Permit requires that upon closure of any tailings cell, EFRI must ensure that the maximum elevation of the tailings waste solids does not exceed the top of the FML liner. 2.15.2.4 Inspection of Feedstock Storage Area Part I.D.3(e) of the Permit requires that open-air or bulk storage of all feedstock materials at the Mill facility awaiting Mill processing must be limited to the eastern portion of the Mill site (the "ore pad") described by the coordinates set out in that Part of the Permit, and that storage of feedstock materials at the facility outside of this defined area, must meet the requirements of Part I.D.11 of the Permit. Part I.D.11 requires EFRI to store and manage feedstock materials outside the defined ore storage pad in accordance with the following minimum performance requirements: a) Feedstock materials shall be stored at all times in water-tight containers or water-tight container overpacks, and aisle ways will be provided at all times to allow visual inspection of each and every feedstock container and container overpack, or b) Feedstock containers shall be stored on a hardened surface to prevent spillage onto subsurface soils, and that conforms with the following minimum physical requirements: l)A storage area composed of a hardened engineered surface of asphalt or concrete, and 2)A storage area designed, constructed, and operated in accordance with engineering plans and specifications approved in advance by the Director. All such engineering plans or specifications submitted shall demonstrate compliance with Part I.D.4, 3)A storage area that provides containment berms to control stormwater run-on and run- off, 4)Stormwater drainage works approved in advance by the Director, or 5)0ther storage facilities and means approved in advance by the Director. Part I.E.7(c) of the Permit requires that EFRI inspect the feedstock storage areas weekly to: a) Confirm that the bulk feedstock materials are maintained within approved feedstock storage defined by Table 4 of the Permit; and b) Verify that all alternate feedstock materials located out ide the feedstock storage area defined in Table 4 are stored in accordance with the requirements found in Part I.D.11. 76 Part I.E.7(d) further provides that EFRI inspections of feed material stored outside the feedstock storage area include the following: a) Feed tock MateriaJ Stored Outside the Feed lock Storage Area Inspections a) Weekly Inspection -the Permjttee will conduct weekly in pections to verify that each feed material container complies with the requirements of Part I.D.11. b) Hardened Surface Storage Area -in the event the Permittee constructs a hardened surface storage area for feed material pursuant to Part I.D.11. prior Director approval will be secured for the following: Part I.E. Permit No. UGW370004 1. Engineering Design and Specifications -in accordance with the requirements of Part I.D.4, and 11. Operation and Maintenance Plan. The Mill's procedure for inspection of the Mill's ore pad is contained in Section 3.2 of the DMT Plan, a copy of which is attached as Appendix H to this Application. 2.15.2.5 Monitor and Maintain Inventory of Chemicals Part I.D.3(f) of the Permit requires, EFRI to provide secondary containment to capture and contain all volumes of reagent(s) that might be released at any individual storage area. This requirement applies to all chemical reagents stored at existing storage facilities and held for use in the milling process. Response to spills, cleanup thereof, and required reporting must comply with the provisions of an approved Emergency Response Plan and an approved Stormwater Best Management Practices Plan. Part I.D.3(f) also stipulates that for any new construction of reagent storage facilities, such secondary containment and control must prevent any contact of the spilled or otherwise released reagent or product with the ground surface. Part I.E.9 of the Permit requires that EFRI monitor and maintain a current inventory of all chemicals used at the facility at rates equal to or greater than 100 kg/yr. This inventory is to be maintained on-site, and must include: (i) Identification of chemicals used in the milling process and the on-site laboratory; and (ii) Determination of volume and mass of each raw chemical currently held in storage at the facility. A copy of the Mill's chemical Inventory is attached as Appendix Oto this Application. A copy of the Mill's Stormwater Best Management Practices Plan, Revision 2.0; January 10, 2022 is attached as Appendix G to this Application. It is important to note that the chemical inventory included with this application has been modified from the previous submittal to exclude any chemicals not used at the rate specified in I.E.9 of 100 kg/yr. 77 2.15.3 BAT Performance Standards for Cell 4A 2.15.3.1 BAT Operations and Maintenance Plan Part I.D.6 of the GWDP requires EFRI to operate and maintain Cell 4A so as to prevent release of wastewater to groundwater and the environment in accordance with a BAT Operations and Maintenance Plan. Performance standards for Cell 4A include the following: a) The fluid head in the leak detection system shall not exceed 1 foot above the lowest point in the lower membrane liner; b) The leak detection y tern maximum allowable daily leak rate shall not exceed 24,160 gallon. /day; c) After EFRI initiates pumping conditions in the slimes drain layer in Cell 4A, EFRI will provide conlinuous declining fluid head in the slimes drain layer in a manner equivalent to the requirement found in Part I.D.3(b) for Celt 2 and 3 and a maximum bead of 1.0 feet in tbe tailing (as mea ured from the lowest point of the upper FML) in 6.4 years or less; and d) Under no circumstances shall the freeboard be less than 3-feet in Cell 4A, as measured from the top of the FML. The BAT Operations and Maintenance Plan required under Part I.D.6 was approved by the Director on December 21, 2011. A copy of the most currently-approved BAT Operations and Maintenance Plan is included as Appendix F to this Application. 2.15.3.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan Part I.E.8 of the Permit provides tbal, in accordance with the currently approved Tailing Cell 4A BAT Operations and Maintenance Plan EFRI mu t immediately implement all monitoring and recordkeeping requirement contained in the plan . At a minimum, such BAT monitoring hall include: a) Weekly Leak Detection System (LDS) Monitoring -including: 1) continuous operation of the leak detection y tern pllmping and monitoring equipment, including but not limited to the ubmer ihle pump, pump controller head monitoring, and flow meter equipment approved by the Director. Failure of any pumping or monitoring equipment not repaired and made fully operational within 24-hours of discovery shall con titute failure of BAT and a violation of the Permit; 2) measurement of the fluid head above the lowe t point on the econdary FML by the use of procedures and equipment approved by the Director. Under no circumstance shall fluid head in the leak detection ystem sump exceed a 1-fool level above the lowest point in the lower FML on the cell fJoor. For purpo es of compliance monitoring this I-foot distance shall equate to 2.28 feet above the leak detection system transducer; 78 3) measurement of the volume of all fluids pumped from the leak detection system. Under no circumstances shall the average daily leak detection system flow volume exceed 24,160 gallons/day; and 4) operation and maintenance of wastewater levels to provide a 3-foot Minimum of vertical freeboard in tailings Cell 4A. Such measurements must be made to the nearest 0.1 foot. b) Slimes Drain Recovery Head Monitoring will commence immediately after the Mill initiates pumping conditions in the Cell 4A slimes drain system, quarterly recovery head tests and fluid level measurements are to be made in accordance with the requirements of Parts I.D.3 and I.E.7(b) of the Permit and the currently approved Cell 4A BAT Operations and Maintenance Plan. 2.15.4 BAT Performance Standards for Cell 4B 2.15.4.1 BAT Operations and Maintenance Plan Part I.D.13 requires EFRI to operate and maintain Cell 4B so as to prevent release of wastewater to groundwater and the environment in accordance with a BAT Operations and Maintenance Plan, and that at a minimum such plan must include the following performance standards: a) The fluid head in the leak detection system shall not exceed 1 foot above the lowest point in the lower membrane liner and operate the LOS pump and transducer in a horizontal position at the lowest point of the LOS sump floor; b) The leak detection system maximum allowable daily leak rate shall not exceed 26,145 gallons/day; c) After EFRI initiates pumping conditions in the slimes drain layer in Cell 4B, EFRI will provide continuous declining fluid heads in the slimes drain layer, in a manner equivalent to the requirements found in Part I.D.3(b) for Cells 2, 3 and 4A and a maximum head of 1.0 feet in the tailings (as measured from the lowest point of the upper FML) in 5.5 years or less; and d) Under no circumstances shall the freeboard be less than 3-feet in Cell 4B, as measured from the top of the FML. As mentioned above, the BAT Operations and Maintenance Plan was approved by the Director on December 21, 2011. A copy of the most currently-approved BAT Operations and Maintenance Plan, is included as Appendix F to this Application. 2.15.4.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan Part I.E.12 of the Permit provides that EFRI must implement all monitoring and recordkeeping requirements contained in the Tailings Cell 4B BAT Operations and Maintenance Plan. At a minimum, such BAT monitoring includes weekly LOS Monitoring including: 79 1) continuous operation of the leak detection ·ystem pumping and monitoring equipment, including, but not limited to, Lbe ubmer ibJe pump, pump controller, head monitoring, and flow meter equipment approved by the Dfrector. Failure of any pumping or monitoring equipment not repaired and made fully operational within 24-hours of discovery shall con titute fa ilure of BAT and a violation of the Permit; 2) measurement of the fluid head above the lowest point on the secondary FML by the use of procedures and equipment approved by the Director. Under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower FML on the cell floor. For purposes of compliance monitoring this 1-foot distance shall equate to 2.25 feet above the leak detection system transducer; 3) measurement of the volume of all fluids pumped from the leak detection system. Under no circumstances shall the average daily leak detection system flow volume exceed 26,145 gallons/day; and 4) operation and maintenance of wastewater levels to provide a 3-foot Minimum of vertical freeboard in tailings CelJ 4B. Such measurements must be made to the nearest 0.1 foot. Slimes Drain Recovery Head Monitoring immediately after the Mill initiates pumping conditions in the Cell 4B slimes drain system, monthly recovery head tests and fluid level measurement are to be made in accordance with the reqnirements of Parts I.D.3 and I.E.7(b) of the Permit and any plan approved by the Director. 2.15.5 Stormwater Management and SpiJI Control Requirements Part I.D.10 of the Permit requires EFRI to manage all contact and non-contact stormwater and control contaminant spills at the facility in accordance with an approved stormwater best management practices plan. Such plan must include the following minimum provisions: a) Protect groundwater quality or other water · of the state by design, construction, and/or active operational mea ure that meet the requirements of the Ground Water Quality Prnte tion Regulation found in UAC R3 17-6-6.3(G) and R317 -6-6.4(C); b) Prevent control and contain pill of stored reagents or other chemical at the Mill site; c) Cleanup spills of stored reagents or other chemicals at the Mill site immediately upon discovery; and d) Report reagent spills or other releases at the Mill site to the Director in accordance with UAC 19-5-114. The Mill's Stormwater Best Management Practices Plan, Revision 2.1, dated April 12, 2022, is included as Appendix G to this Application. 2.15.6 Tailings and Slimes Drain Sampling 80 Part I.E.10 of Lhe Permit requires EFRI to annuaJJy collect wa tewater quaLity ·ample from each wa 'tewater ource at each tailings cell at the facility incJuding surface impounded wa tewater., the leak detection ystems (if pre. ent) and limes drain wa tewaters. AJI uch sampling must be conducted in August of each calendar year in compliance with the approved Tailings Sampling Plan. See Section 2.12.1 above for a more detailed description of this program. The Mill's Sampling and Analysis Plan for the Tailings Management System, Leak Detection System and Slimes Drains, Revision 3.0, dated July 8, 2016 is included as Appendix L to this Application. 2.15.7 Additional Monitoring and Inspections Required Under the Mill License Under the Mill License daily, weekly, and monthly inspection reporting and monitoring are required in accordance with NRC Regulatory Guide 8.31, biormation Relevant to Ensuring that Occupational Radiation Exposures at Uranium Recovery Facilities will be As Low As i Reasonable A hievable, Revision 1 May 2002 (' Reg Guide 8.3 J ') by Section 2.3 f the Mill ' ALARA Program and by the Mill's Environmental Protection Manual ("EPM"). The e requirements are over and above the in pections described above that are required under the Permit. Additional daily, weekly, monthly, quarterly, and annual inspection and reporti11g requirements are specified in the Tailing Management System Procedure and the EFRI DMT Plan (Sections 3.1 and 3.2 of the EPM re pectively). The DMT Plan and Tailings Management System are included as Appendix Hand Appendix I to this Application, respectively. 2.15.7.1 Daily Inspections Three types of daily inspections are performed at the Mill under the Mill License: a) Radiation Staff Inspections Paragraph 2.3.1 of Reg. Guide 8.3 L provide. that the MilJ Rad iation Safety Officer ("RSO') or designated health phy ic technidan should conduct a daily walk-through (vi ual) in pection of all work and torage area of the Mill to en ure proper implementation of good radiation safety procedures, including good housekeeping that would minimjze unneces ary contamination. Thee inspecti n are required by Section 2.3.1 of the Mill's ALARA Program, and are documented and on file in the MiJJ s Radiation Protection Office. b) Operating Foreman Inspections 30 CFR Section 56.18002 of the Mine Safety and Health Administration regulations requires that a competent person designated by the operator mu t examine each working place at least once each shift for conditions which may adver ely affect safety or health. These daily inspections are documented and on file in the Mill's Radiation Protection Office. 81 c) Daily Tailings Inspection Section 3.1 of the MiJI' EPM require that during Mill operation, the Shift Foreman or other per on with the U'aining pecified in paragraph 2.4 of the Tailings Management Procedure, designated by the RSO, will perform an in pection of the tailings Jine and tailings area at Jea t once per shift, paying do e attention for potential leak and to the di charge from the pipelines. Ob ervations by the In pector are recorded on the appropriate line on the Mill s Daily Inspection Data form. 2.15.7.2 Weekly Inspections Three types of weekly inspections are performed at the Mill under the Mill License: a) Weekly Inspection of the Mill Forms Paragraph 2.3.1 of Reg. Guide 8.31 provides that the RSO and the Mill foreman should, and Section 2.3.2 of the Mill's ALARA Program provides that the RSO and Mill foreman or their respective de ignee shall, conduct a weekly in pection of all Mill areas to ob ·erve general radiation control practices and review required changes in procedure and equipment. Particular attention is to be focused on areas where potential exposure: to per onnel might exist and in areas of operation or locations where contamination is evident. b) Weekly Ore Storage Pad Inspection Forms Paragraph 3.2 of the DMT Plan and Part I.E.7.d of the Permit require · that weekly feedstock torage area inspection be performed by the Radiation Safety Department to confirm that the bulk feedstock materials are . tored and maintained within the defined area of the ore pad and that all alternate feed materials located outside the defined ore pad area are maintained in accordance with the requirements of the Permit. The result. of these inspection are recorded on the Mill' Ore Storage/Sample Plant Weekly Inspection Report. c) Weekly Tailings and DMT Inspection Sections 3.1 and 3.2 of the EPM requires that weekly inspections of the tailings area and DMT requirements be performed by the radiation safety department. 2.15.7.3 Monthly Reports Two types of monthly reports are prepared by Mill staff: a) Monthly Radiation Safety Reports The RSO review the result. of daily and weekly in pections, including a review of all monitoring and exposure data for the month, and provide to the Mill Manager a monthly report containing a written summary of the month s ignificant worker protection activitie (Section 2.3.4 of the ALARA Program). 82 b) Monthly Tailings Inspection Reports Sections 3.1 and 3.2 of the EPM, requires that a Monthly Inspection Data form be completed for the monthly tailings inspection. This inspection is typically performed in the fourth week of each month and is in lieu of the weekly tailings inspection for that week. Mill staff also prepares a monthly summary of all daily, weekly, monthly and quarterly tailings inspections. 2.15.7.4 Quarterly Tailings Inspections Sections 3.1 and 3.2 of the EPM requires that the RSO or his designee perform a quarterly tailings inspection. 2.15. 7.5 Annual Evaluations The following annual evaluations are performed under the Mill License, as set out in Sections 3.1 and 3.2 of the EPM. a) Annual Technical Evaluation An annual technical evaluation of the tailings management system must be performed by a registered profe ional engineer ("PE"), who has experience and training in the area of geotechnical aspects of retention structures. The technical evaluation includes an on-site inspection of the tailings management system and a thorough review of all tailings records for the past year. The Technical Evaluation also includes a review and summary of the annual movement monitor survey (see Section (b) below). All TMS cells and corresponding dikes are inspected for signs of erosion, subsidence, shrinkage, and seepage. The drainage ditches are inspected to evaluate surface water control structures. In the event tailings capacity evaJuations were performed for the receipt of alternate feed material during the year, the capacity evaluation forms and associated calculation sheets will be reviewed to ensure that the maximum tailings capacity estimate is accurate. The amount of tailings added to the system since the last evaluation will also be calculated to determine the estimated capacity at the time of the evaluation. As discussed above, tailings inspection records consist of daily, weekly, monthly, and quarterly tailings inspections. These inspection records are evaluated to determine if any freeboard limits are being approached and to identify any areas of potential concern. The evaluation also involves discussion with the Environmental and/or Radiation Technician and the RSO regarding activities around the tailings area for the past year. During the annual inspection, photographs of the tailings area are taken. The training of individuals is also reviewed as a part of the Annual Technical Evaluation. 83 The regi tered engineer obtain copies of elected tailings inspections, along with the monthly and quarterly ummarie of ob ervations of concern and the corrective actions taken. These copies are then included in the Annual Technical Evaluation Report. The Annual Technical Evaluation Report must be submitted to DWMRC and the Directing Dam Safety Engineer, State of Utah, Natural Resources by March 1st of the following year. b) Annual Movement Monitor Survey A movement monitor survey is conducted by a licensed surveyor annually during the second quarter of each year. The movement monitor survey consists of surveying monitors along dikes 3-S, 4A-W, and 4A-S to detect any po. ible . enlement or movement of the dike . The data generated from thi survey i · reviewed and incorporated into the Annual Technical Evaluation Report of the TMS. c) Annual Leak Detection Fluid Samples Annually, the leak detection system fluids in Cells 1, 2, 3, 4A and 4B are sampled when present as described in the Tailings Sampling Plan in Section 2.12.1. 2.16 Corrective Action Plan or Identification of Other Response Measures to be Taken to Remedy any Violation of Applicable Ground Water Quality Standards (R317-6-6.3.P) There are two circumstances where applicable groundwater standards have been exceeded at the site that are not associated with natural background: chloroform contamination, and nitrate contamination. As discussed below, none of these circumstances appear to be related to di ·charges from milling activities. See Section 2.11.2 for a discussion of the current inve tigati.on into exceedances of GWCLs for certain constituents at the site, which EFRI believe · are a sociated with natural background. 2.16.1 Chloroform Investigation In May, 1999, excess chloroform concentration were di ·covered in monitoring well MW-4 which is screened in the shallow perched aquifer along the eastern margin of the MilJ site. Repeated groundwater sampling by both the Mill and DWMRC confirmed the presence of chloroform in concentrations that exceed the GWQS along the eastern margin of the site in wells that are upgradient or cross gradient from the TMS. Other VOC contaminants and nitrate and nitrite were also been detected in these samples. Based on the location of the plume and characterization studie completed to date the contamination appears to have resulted from the operation of temporary laboratory facilitie. that were located at the site prior to and during construction of the Mill facility, and septic drainfields that were used for laboratory and sanitary wastes prior to construction of the Mill's TMS. In the 2004 GWDP Statement of Basis, DWMRC noted on page 3 that, whjJe the contaminant inve tigation and groundwater remediation plan were not complete at that time, the DWMRC beljeved that additional time was available to re olve the e requirement based on the following factors: 1) hydraulic isolation found between the hallow perched aquifer in which the contamination has been detected and the deep confined aquifers which are a source of drinking 84 water in the area, 2) the large horizontal distance and the long groundwater travel times between the existing groundwater contamination on site and the seeps and springs where the shallow aquifer discharges at the edge of White Mesa, and 3) lack of human exposure for these shallow aquifer contaminants along this travel path. The discovery resulted in the issuance of State of Utah Notice of Violation ("NOV") and Groundwater Corrective Action Order ("CAO") DWMRC Docket No. UGW-20-01, which required that EFRI submit a Contamination Investigation Plan and Report pursuant to the provisions of UAC R317-6-6.15(D). In response to the NOV, EFRI submitted a series of documents outlining plans for investigation of the chloroform contamination. This plan of action and preliminary schedule was set out in EFRI submittals dated: September 20, 1999; June 30, 2000; April 14, 2005; and November 29, 2006. EFRI submitted a draft Groundwater Corrective Action Plan ("GCAP") dated August 22, 2007. The draft GCAP was reviewed by the Director, who advised EFRI in 2013 that modifications were required. In an effort to expedite and formalize active and continued remediation of the chloroform plume, both parties have agreed to the GCAP found in Attachment 1, of the final Stipulation and Consent Order ("SCO") dated September 14, 2015. Between the time of discovery and the fourth quarter of 2021, the plume has been delineated by installation of 43 TW4-series wells and placed under remediation by pumping. Physical factors that have influenced the transport of chloroform (and the size and shape of, and concentration distribution within, the chloroform plume) include the following: 1) the nature of the source(s); 2) perched groundwater flow in the vicinity of the plume; 3) the permeability distribution; 4) natural attenuation; 5) initiation of long term pumping within the plume at wells MW-4, MW-26, and TW4-19 in 2003; 6) the addition of TW4-20 to the pumping system in 2005 (which has since been abandoned); 7) the addition of TW4-4 to the pumping system in 2010; 8) reduced wildlife pond recharge (since the first quarter of 2012); 9) nitrate pumping in TW4-22, TW4-24, TW4-25, and TWN-2 (since the first quarter of 2013); 10) the addition of TW4-1, TW4-2, TW4-11, TW4-21, and TW4-37 to the pumping system during the first half of 2015; and 11) the addition of TW4-39, TW4-40 and TW4-41 to the pumping system since 2015. Although pumping well TW4-20 failed and was abandoned during 2020, little or no impact to chloroform mass removal rates and capture effectiveness has occurred. Increased pumping at TW4-19 subsequent to TW4-20 failure more than compensated for the loss in pumping at TW4-20. The number of chloroform pumping wells doubled (from five to ten) during the first half of 2015. Doubling the number of chloroform pumping wells more than tripled the short-term rate of chloroform mass removal from approximately 10.2 pounds ("lbs")/quarter in the third quarter of 2014 to 32.3 lbs/quarter by the fourth quarter of 2015. Since 2015, the chloroform pumping system has continued to expand through the addition of TW4-39, TW4-40 and TW4-41. Chloroform pumping since 2015 has exceeded the conservatively large calculated 'background flow' through the plume (3.4 gpm) by between approximately 0.9 gpm and 2.5 gpm (26% to 74%), or on average 1.8 gpm (53%), indicating that pumping is adequate. Since implementation of the GCAP in the third quarter of 2015, chloroform plume residual mass estimates have trended downward. The decrease in residual mass estimates is a consequence of decreases in average concentrations and reduced saturated thicknesses within the plume. In 85 addition, since implementation of the GCAP, pumped mass removal rates have trended downward. Decreasing mass removal rates are attributable primarily to the reduced concentrations within the plume. As concentrations decrease in pumping wells within the plume, the pumped mass removal rates also decrease, even if pumping rates remain relatively stable. Doubling the number of chloroform pumping wells during 2015 also expanded the area of the plume under hydraulic capture by approximately 30%. As of the fourth quarter of 2015, approximately 74% of the plume area and approximately 89% of the re idual plume mas were under hydrnulic capture. Although the area under capture increased by approximately 30% (from approximately 27 acre. to approximately 35 acres) between the fourth quarter of 20 I 4 and 20J 5 the increa e in the proportion of total plume mass under hydraulic capture did not change significantly and remained at approximately 90%. Additional expansion of capture since 2015 has re ulted from adding TW4-39 TW4-40 and TW4-4J to the pumping system. As of the fourth quarter of 2021 , approx_imately 85% of the plume area and approximately 97% of the plume ma are under captur . Since the end of 2012 total pumping from the chloroform plume (incJucling pumping from nitrate wells TW4-22 and TW4-24 located within and ju t in ide the margin of the chloroform plume, respectively) has increased from approximately 2.8 gpm to approximately 5.1 gpm. The chloroform plume is completely bounded by twenty compliance wells having concentrations that are below the GCAL of 70 µg/L: seventeen of these wells are ·pecified in Table IA of the GCAP and TW4-38, TW4-42 and TW4-43 are new compliance wells installed since implementation of the GCAP. Fourteen of these twenty bounding wells are non-detect for chloroform as of the fourth quarter of 2021. The fourteen non-detect wells are MW-32, TW4-3, TW4-12, TW4-13, TW4-14, TW4-23, TW4-25, TW4-28, TW4-34, TW4-35, TW4-36, TW4-38, TW4-42 and TW4-43. The plume is also nearly 1 200 feet from the closest (eastern) property boundary (as of the fourth quarter of 2021), and becau. e perched water flow is approximately parallel to that boundary, any chloroform encroaching on that boundary is unlikely to cros the boundary. The southern portion of the p.lume i bounded immediately to the south by TW4-42, and far to the south by MW-22 and MW-40 (all non-detect for chloroform). TW4-40 was installed once concentrations at TW 4-26 exceeded 70 µg/L for two consecutive quarters; likewise, TW4-42 was installed once concentrations at TW4-40 exceeded 70 µg/L for two consecutive quarters. TW4-40 has been converted to a pumping well. Likewi e generally decrea ing chloroform concentrations at downgradient well TW4-6 since the first quarter of 2015 and i ncrea ·ing to table concentrations at TW 4-26 since the first quarter of 2016 suggest that chloroform migration ha been arrested at TW4-6 by TW4-4 (and TW4-41) pumping and that increa ·ing to stable chloroform at TW4-26 results from a remnant of the plume that migrated downgraclient to the outh. Based on the above factors, the chloroform plume is under control and the GCAP has been effective in protecting public health and the envirnnment. In particular current pumping y ·tern effectiveness is demonstrated by 1) the slowing to near halting of plume boundary ex pan 'ion attributable to reduced dilution from reduced wildlife pond recharge and redistribution of chloroform resulting from nitrate pumping; and 2) maintaining a large proportion of the plume 86 mass under hydraulic capture (approximately 97% as of the fourth quarter of 2021). High rates of capture have been maintained even considering reduced productivities at some of the pumping wells and the failure and subsequent abandonment of TW4-20. Furthermore, natural attenuation calculations provided in HGC (2007) suggest that all chloroform concentrations will be below the GCAL within less than 200 years, not taking into account the effects of any pumping. Specifically, using the average calculated chloroform degradation rate h wn in Appendix C of the 2022 Chloroform CACME, reducing the highest 2021 chloroform concentration of 14,800 µg/L to the GCAL of 70 µg/L would take approximately 61,353 days or 168 years, even in the absence of pumping. If the degradation rate is based onJy on MW-26 data, the time to reduce the highest 2021 concentration of 14,800 µg/L to the GCAL of 70 µg/L would take approximately 16,890 days or only 46 years. 2.16.2 Nitrate Investigation During review of the New Well Background Report and other reports a Nitrate contaminant plume was identified by DWMRC ·taff in five monitoring wells in the Mill ite area, including wells: MW-30, MW-3 L TW4-22, TW4-24 and TW4-25. TW4-25 is located upgradient of the Mill's TMS. Elevated concentrations of chloride also appear to be associated with the nitrate plume. On September 30, 2008, the Director issued a request for a voluntary plan and schedule for EFRI to investigate and remediate this Nitrate contamination. On November 19, 2008 EFRI submitted a plan and schedule prepared by INTERA, Inc., which identified a number of potential sources for the contamination, including several potential historic and off site sources. On January 27, 2009, the Director and EFRI signed a Stipulated Consent Agreement ("SCA") by which EFRI agreed to conduct an investigation of the Nitrate contamination, determine the sources of pollution, and submit a report by January 4, 2010. EFRI submitted a Contaminant Investigation Report ("CIR") on December 30, 2009. On October 5, 2010 the Director issued a Notice of Additional Required Action ("NARA") letter that notified EFRI of the Director's determination that the 2009 CIR was incomplete. On December 20, 2010 EFRI and the Director entered into Revision O of a Tolling Agreement, allowing a tolling period until April 30, 2011 in order to provide time for EFRI to prepare a Plan and Schedule for Director review addressing additional investigations to resolve open issues identified in the October 5, 2010 NARA, and to execute a revised SCA. EFRI submitted a Plan and Schedule on February 14, 2011 and a revi ed Plan and Schedule on February 18, 2011. The Director provided comment on the revi ed Plan and Schedule on March 21, 2011. In an April 20, 2011 meeting, EFRI and the Director agreed that the Plan and Schedule to conduct additional nitrate investigations would be composed of four to five phases of study, including geoprobe drilling and soil sampling/analysis to investigate natural nitrate salt reservoir sources in the vadose zone beyond the Mill site, potential Mill sources, and other potential source ; groundwater sampling and analy is of existing monitoring wells for non- isotopic analyte · deep bedrock core sampling/analy i of possible natural nitrate reservoir and 87 potentiaJ nitrate source locations; stable i otopic sampling/analysis of groundwater in existing monitoring wells; and stable isotopic sampling/analysi. of oil/core samples, if needed. On April 28, 2011, EFRI and the Director entered into Revi ion 1 of the Tolling Agreement to extend the Tolling Period through June 30, 2011 and adopt the agreements made on April 20, 2011. Under the Tolling Agreement Revision 1, EFRI agreed to ubmit a Revi. ed Pha e 1 (A through C) Work Plan on or before May 6, 2011 and a Revi ed Pha. e 2 through 5 Work Plan and Schedule on or before June 3, 2011. EFRI submitted a May 6, 2011 Revised Phase 1 Work Plan and Schedule for the Phase 1 A -C investigation for Director review. EFRI conducted field and laboratory work for the Phase 1 A-C study in May and June, 2011. EFRI submitted a Revised Phase 2 through 5 Work Plan and Schedule for Director review on June 3, 2011. The Director provided comments on this document on June 23, 2011 and advised EFRI that in order to revise the 2009 SCA to incorporate needed deliverable and timelines, the Phase 2 through 5 Work Plan would need to be expanded to the same level of detail as was provided for Phase 1 in Attachment 1 of the Revision 1 Tolling Agreement. On June 30, 2011, EFRI and the Director entered into Revision 2 of the Tolling Agreement extending the Tolling Period to August 31, 2011, to facilitate the revision of the Phase 2 through 5 Work Plan to provide the required level of detail to construct a replacement SCA. EFRI submitted a separate July 1, 2011 detailed Revision O of the Work Plan and Quality Assurance Plan ("QAP") for the Phase 2 investigation. The Director provided comments on this document on July 7, 2011. EFRI provided a July 12, 2011 Revision 1.0 to the Phase 2 QAP and Work Plan, which DWMRC conditionally approved in a letter dated July 18, 2011. On August 1 and 2, 2011 EFRI submitted by email preliminary laboratory results for the Phase 1 A-C study to the Director. On August 4, 2011, EFRI provided a Revision 1.0 to the Phase 2 -5 Work Plan for Director review. The Director provided comments on the Phase 2-5 Work Plan, Revision 1.0 and the August 1, 2011 preliminary laboratory results on August 11, 2011. EFRI submitted Revision 2.0 of the Phase 2-5 Work Plan for Dfrector review on August 11, 2011. On August 25, 2011, the Director determined that based on review of the Revision 2.0 Phase 2-5 Work Plan, a finalized Plan and Schedule that meets the satisfaction of the Director, and which would allow the preparation of a replacement SCA, was not possible at that time; and that the development of a replacement SCA for continued contaminant investigation activities was not supported. At a meeting on August 29, 2011, EFRI and DWMRC agreed that: 1. After more than two years of investigation it has been determined that there are site conditions that make it difficult to determine the source(s) of the contamination at the White Mesa site; 2. As a result, resources will be better spent in developing a CAP in accordance with UAC R317-6-6.15(D), rather than continuing with further investigations as to the source(s) of the contamination. 88 In discussions during October 2011, EFRI and the Director acknowledged that it has not been possible to date to determine the source(s), cause(s), attribution, magnitudes of contribution, and proportion(s) of the local nitrate and chloride in groundwater, and thereby cannot eliminate Mill activities as a potential cause, either in full or in part, of the contamination. As a result, EFRI and the Director agreed that resources will be better spent in developing a Corrective Action Plan in accordance with UAC R317-6-6.15(D), rather than continuing with further investigations. On October 3, 2011 EFRI and the Director entered into a revised Stipulated Consent Agreement which required EFRI to submit a Corrective Action Plan for Director review that included plans to: Phase I -determine the physical extent of soil contamination observed at the Ammonium Sulfate Crystal Tanks, and provide a control measure consisting of either removal of the areal extent of contamination down to bedrock, or a Plan and Schedule for covering the areal extent of contamination with at least 6 inches of concrete, followed by removal action during or before site closure. Phase II -implement near term active remediation of the nitrate contamination by pumping contaminated water into the Mill's TMS for disposal. This phase is to include development, implementation, operation, and monitoring of a pumping well network to contain and hydraulically control the nitrate plume; monitoring of chloride concentrations; and any required increases to the Mill's surety for activities in this Phase. Phase III -develop, if necessary, a comprehensive long-term solution for the nitrate contamination at the Mill Site. This Phase is to be determined after public participation and Director approval, and may include continuation of Phase I and II activities alone or in combination with any of the following: monitored natural attenuation, additional remediation and monitoring, determination of additional hydrogeologic characterization, contaminant travel times, points of exposure to public or wildlife, risk analysis, cost/benefit analysis, and possible development and petition of the Board for alternate corrective action concentration limits. EFRI submitted a Draft Corrective Action Plan on November 30, 2011. The Director provided comments on the Draft Corrective Action Plan on January 19, 2012. EFRI provided Revision 1.0 of the Corrective Action Plan on February 27, 2012, and received comments from the Director on March 19, 2012. Pursuant to the revised SCA, EFRI provided Revision 2.0 to the Director on May 7, 2012 (HGC 2012b). On December 12, 2012, DRC signed the SCO, Docket Number UGW12-04, which approved the EFRI CAP, dated May 7, 2012 (HGC 2012b). The SCO ordered EFRI to fully implement all elements of the May 7, 2012 CAP (HGC 2012b). Based on the schedule included in the CAP and as delineated and approved by the SCO, the activities associated with the implementation of the CAP began in January 2013. The nitrate plume has been under remediation by (Phase II) pumping since the first quarter of 2013 . The plume, defined by groundwater concentrations exceeding 10 mg/L nitrate as nitrogen, 89 originates upgradient (northeast) of the TMS at the site (HGC, 2017). Likewise, the commingled chloride plume, defined by groundwater concentrations exceeding 100 mg/L chloride, also originates upgradient of the TMS. The 2017 CA CME report for the nitrate plume (HGC, 2017) represents a 5-year review of the Phase II Corrective Action as specified in the final SCO Docket No. UGW12-04. As discussed in the nitrate CACME, between the second quarter of 2010 and the third quarter of 2017, the mass of nitrate contained within the plume has been reduced by approximately 11 % to 25%. Based on data presented in EFRI (2022c), the residual mass of the nitrate plume has continued to decline. Furthermore, there is enough pyrite in the perched zone within the path of the nitrate plume to completely attenuate the plume through natural reduction of nitrate alone. As discussed in HGC (2017), estimated natural nitrate degradation rates range from approximately 172 lb/ year ("yr") to 200 lb/yr, indicating that less than 200 years would be required to remediate the nitrate plume, even in the absence of any direct mass removal by pumping. However, considering both pumping and estimated natural attenuation rates presented in HGC (2017), the mass of the plume is expected to be reduced by approximately 573 to 601 lb/yr, and nitrate concentrations within the plume are expected to be reduced to negligible values (less than 10 mg/L) within approximately 54 to 57 years. As the estimated time for impacted water to reach the nearest discharge point (Westwater Seep or Ruin Spring) is greater than 3,000 years, there is no concern at this time that the continuation of current corrective actions will not result in remediation of the plume well before it can reach any exposure to the public or wildlife. In response to a DWMRC request, additional attenuation modeling of the nitrate plume was conducted to further study and refine the conclusions presented in the 2017 nitrate CACME. Accordingly, a Phase III Planning Document was prepared (HGC 2018e). The Phase III planning document included conceptual-level numerical groundwater flow and solute transport assessments to evaluate the maximum distance that the nitrate plume could travel, assuming hypothetical 'worst-case' conditions, before all concentrations are reduced below 10 mg/L, indicating that full attenuation has occurred. These 'worst-case' transport assessments: 1. Disregard the natural degradation of nitrate within the plume via pyrite oxidation which will cause overestimation of simulated plume migration; 2. Disregard the (relative) stability of the southern (downgradient) margin of the nitrate plume which suggests that pumping and natural attenuation processes are minimizing or preventing plume expansion to the south; 3. Disregard nitrate mass removal by pumping and natural dilution of nitrate concentrations via recharge by precipitation, which will cause overestimation of simulated plume migration; 4. Substantially overestimate hydraulic conductivities (by as much as two orders of magnitude) and hydraulic gradients (by nearly a factor of two) down gradient of the TMS, which will cause substantial overestimation of simulated plume migration rates; and 90 5. Underestimate dispersivities which will cause underestimation of hydrodynamic dispersion and overestimation of simulated plume migration. The conceptual-level transport assessments indicate that the nitrate plume will not migrate beyond the site property boundary or to a discharge point before fully attenuating, even under hypothetical 'worst-case' assumptions. Therefore, under any currently conceivable conditions, including hypothetical 'worst-case' conditions that greatly overestimate plume migration rates, underestimate mechanical dispersion, and disregard mass removal by pumping and natural degradation, there will be no expected hazard to public health, safety or the environment; no expected exposure to the public, wildlife or the environment; and, as a result, no additional hazard or exposure assessments are needed at this time. In summary, the assessments provided in the 2017 nitrate CACME indicate that the plume would fully degrade via natural pyrite oxidation alone before reaching a discharge point. This degradation would occur within 200 years assuming no pumping, dilution by natural recharge, or hydrodynamic dispersion. The conceptual-level transport assessments performed in 2019 indicate that, even without mass removal via pyrite oxidation or pumping, and assuming hypothetical 'worst case' conditions regarding future nitrate transport, the plume will fully attenuate before reaching the site property boundary or a discharge point. 2.17 Other Information Required by the Director (R317-6-6.3.Q) As discussed below, a chemical inventory report and a Hydrogeologic investigation report for the southwest portion of the Mill site have been completed at the request of the Director. No other information has been specifically required by the Director to be included in this Application at this time. EFRI will provide additional information as requested by the Director. 2.17.1 Chemical Inventory Report Part I.E.9 requires that an On-site Chemicals Inventory be maintained. Specifically, I.E.9 states: On-site Chemicals Inventory -the Permittee shall monitor and maintain a current inventory of all chemicals used at the facility at rates equal to or greater than 100 kg/yr. Said inventory shall be maintained on-site, and shall include, but is not limited to: a. Identification of chemicals used in the milling process and the on-site laboratory, and b. Determination of volume and mass of each raw chemical currently held in storage at the facility. Part I.F.8 states: Chemicals Inventory Report -at the time of submittal of an application for Permit renewal the Permittee shall submit a report to update the facilities chemical inventory report. Said report shall include: a. Identification of all chemicals used in the milling and milling related processes at the White Mesa Mill, and 91 b. Provide all inventory information gathered pursuant to Part I.E.9, c. Determination of the total volumes currently in use and historically used, as data is available. The updated chemical inventory is included Appendix 0. It is important to note that the chemical inventory included with this application has been modified from the previous submittal to exclude any chemicals not used at the rate specified in 1.E.9 of 100 kilograms per year ("kg/yr"). 2.17.2 Southwest Hydrogeologic Investigation In response to previous Permit requirements, EFRI performed a detailed Southwest Hydrogeologic Investigation to define, demonstrate and characterize: 1) the hydraulic connection and local groundwater flow directions between the area near Tailings Cell 4B, and the western margin of White Mesa, and 2) the full physical extent of the unsaturated area between former well MW-16, MW-33 and the western margin of White Mesa. During 2011, EFRI installed 18 piezometers to define the geologic and physical extent of the apparent unsaturated structural high between Tailings Cell 4B and the western margin of White Mesa and the location and direction of groundwater flow paths between Tailings Cell 4B and Westwater and Cottonwood Seeps and Ruin Spring. Consistent with Part I.H.6.c) of the Permit, EFRI submitted an investigation report, the Hydro geology of the Perched Groundwater Zone in the Area Southwest of the Tailings Cells, White Mesa Uranium Mill Site (the "Southwest Hydrogeology Report"), prepared by Hydro Geo Chem, on January 12, 2012. The Director provided comments in a conference call during May 2012, and in a letter dated May 30, 2012. EFRI submitted a revised version of the Report on August 3, 2012 and agreed to repeat slug testing of piezometer DR-08. DRC's September 20, 2012 review Summary and RFI, specifically requested that EFRI: • repeat slug testing of piezometer DR-08, • recalculate hydraulic properties, and • recalculate travel times if necessary based on new data. The Second Revision to the Report, addressing the data and re-calculations resulting from retesting of piezometer DR-08, was submitted on November 7, 2012. 2.18 This Application Performed Under the Direction of a Professional Engineer (R317-6-6.3.R) This Application has been performed under the direction, and bears the seal, of Timo Groves, EFRI Chief Metallurgist. Mr. Groves is a Registered Professional Engineer in the State of Utah, No. 11793034. 92 2.19 Closure and Post Closure Management Plan Demonstrating Measures to Prevent Ground Water Contamination During the Closure and Post Closure Phases of Operation (R17-6-6.3.S) 2.19.1 Regulatory Requirements for Uranium Mills 2.19.1.1 Long Term Custodian One unique feature of the regulatory scheme for uranium mill tailings is that Section 83 of the Atomic Energy Act of 1954, as amended by the Uranium Mill Tailings Radiation Control Act of 1978 ("UMTRCA") (the Atomic Energy Act of 1954 as so amended is referred to herein as the "AEA")1 requires that, prior to license termination, title to uranium mill tailings (1 le.(2) byproduct material) must be tran ferred to the United States Department of Energy ("DOE") or the State in which the activity occurred if the State so elects, for custody and long term care. 10 CFR 40.28 provides a general license to DOE or the State for that purpose. 2.19.1.2 Responsibility For And Manner Of Clean Up UMTRCA amended the AEA to require that all Title II facilities (i.e., active mills) comply with the decontamination, decommissioning, and reclamation standards prescribed by the Commission2 and to require that such facilities post reclamation bonds or surety3. Re ponsibility for reclamation of Title II facili ties rest with th e Jicen ee. 10 CFR Part 40 Appenrux A Criterion 6A requires the adoption of a Director-approved red amation plan for the site, Criterion 9 requires that financial surety mu t be e tabli bed to fund the co. t of reclamation in accordance with such plan, and Criterion 10 requires that each licensee include in its financial surety an amount equivalent to $250,000 (1978 dollars) to cover the costs of long-term surveillance by the long-term government custodian (DOE). Criteria 6, 9 and 10 have been incorporated by reference into the Utah rules by UAC R313-24-4. 2.19.1.3 Surface The reclamation plan adopted by the Mill at the outset, as required by 10 CFR Part 40, Appendix A, Criterion 9, addresses the decontamination and decommissioning of the Mill and Mill ite and reclamation of tailings and other waste disposal areas. As is the case for most uranium mills, the Mill's reclamation plan requires that, upon closure, all mill buildings, unsalvageable equipment, contaminated soils (impacted by Mill operations within the Mill site itself as well as surrounding areas that may be impacted by windblown radioactive dusts from milling operations) etc. be deposited in the TMS and the TMS capped in place. Appendix A, Criterion 6(6) sets the standard for determining when all impacted areas other than the TMS have been adequately cleaned up. Criterion 6(6) provides that byproduct material containing concentrations of radionuclides other than radium in soil, and surface activity on remaining structures, must not result in a total effective dose equivalent ("TEDE") exceeding the dose from cleanup of radium contaminated soil to the benchmark standard of 5pCi/g t See 42 U.S.C. 2113. 2 See 42 U.S.C. 2113. 3 See 42 U.S.C. 2201. 93 concentration of radium in the upper 15 cm (6 in) of surface soils and 15 pCi/g concentration of radium in the subsurface soils, and must be at levels which are ALARA. If more than one residual radionuclide is present, the sum of the ratios for each radionuclide present will not exceed "1" (unity). Further details on the NRC's approach to evaluating reclamation plans and release criteria for uranium mill sites, including the manner of modeling the relea e 'tandard set out in Criterion 6(6), are contained in NUREG-1620, Rev 1, Standard Review Plan for the Review of a Reclamation Plan for Mill Tailings Sites Under Title II of the Uranium Mill Tailings Radiation Control Act of 1978, Final Report, June 2003 ("NUREG-1620"). 2.19.1.4 Groundwater Each uranium mill is required to have a groundwater monitoring program. In the case of the Mill, the Permit implements the applicable requirements of UAC R317-6. If there is groundwater contamination after cessation of operations, the requirements of UAC R317-6.15 must be satisfied. 2.19.1.5 License Termination Section 83. 7 of the AEA 4 provides that material and land transferred to the long term custodian must be transferred without cost to the long-term custodian other than administrative and legal costs incurred in carrying out such transfer. In order to cover the costs of long-term surveillance, Criterion 10 requires that a minimum charge of $250,000 (1978 dollars) must be paid by each mill operator to the general treasury of the United States or to an appropriate State agency prior to the termination of a uranium mill license. In most case! if there i a groundwater ontamination problem, the problem must be remediated prior to Jicen e termination or an alternate corrective action concentration limit under R317-6- 6.15.G must be achieved that i. protective of public health and the environment. In some circumstances DOE may agree to take some additional actions after it takes title to the site, such as additional monitoring, if not onerous and provided adequate funding is provided. Upon the Director and the NRC being satisfied that alJ regulatory requirements have been met and the site is reclaimed in a manner that sati fie aU applicable tandard , the Mill's licen e will be terminated upon transfer of the tailings to DOE. 10 CPR 40.28 provide a general license in favor of the long-term custodian for custody of and long-term care of the tailings impoundments and any surrounding lands transferred to it. 5 The surrounding areas not transferred to DOE would generally be free-released. 4 See 42 U.S.C. 2113. 5 In circumstances where th e facility has a groundwater contamination p.lume, addilional lands may be acquired by the licensee in order to bound the plume. In these circumstances these adcliti nal lands w uld be transfe rTed along with the capped tailings impoundments, to DOE. 94 2.19.2 Current Reclamation Plan The Mill's Reclamation Plan, Revision 3.2B, was approved by DWMRC under the Mill License on January 26, 2011. The Reclamation Plan sets out the requirements to be met by EFRI for the final reclamation and closure of the Mill facility, including the tailings cells and all impacted surrounding areas, in accordance with the requirements of 10 CFR Part 40, Appendix A (which have since been incorporated by reference into UAC R313-24). A copy of the Mill's Reclamation Plan, Revision 4.0 was previously submitted to the Director in November 2009 and is on file at the DWMRC. EFRI submitted Revision 5.0 of the Reclamation Plan in September 2011. DWMRC provided one round of interrogatories for this document in March 2012. EFRI provided responses to these interrogatories in May and August 2012. DWMRC provided review comments on EFRI's May and August 2012 responses in February 2013. . EFRI completed supplemental investigations in 2013 and 2014 in response to the Director's February 2013 review comments. EFRI submitted responses to the Director's February 2013 review comments in August 2015. Infiltration modeling was conducted for the monolithic ET cover presented in Revision 5.0 of the Reclamation Plan and a complete description of the analyses were provided in EFRI's March 2010 Revised Infiltration and Contaminant Transport Modeling (ICTM) Report, White Mesa Mill Site, Blanding, Utah,. The modeling was updated to address the Director's March 2012 and February 2013 comments on the ICTM Report and to incorporate supplemental field investigations conducted in 2010 and 2012 for cover borrow material and in 2013 for in situ tailings. The updated infiltration modeling results were presented in EFRI's submitted responses to the Director's March 2012 and February 2013 review comments in August 2012 and August 2015. On November 11, 2015, the Director held a conference call with EFRI and recommended submittal of an agreement outlining a plan to complete reclamation of tailings Cell 2. This plan would consist of completing placement of the cover design presented in Revision 5.0 of the Reclamation Plan on Cell 2 and demonstrating acceptable cover performance via a performance monitoring program. On August 11, 2016, EFRI submitted Reclamation Plan, Revision 5.1, with an Updated Tailings Cover Design Report and incorporated comment received from the Director. On December 5, 2016, EFRI submitted the final ver ion of Reclamation Plan, Revision 5.1, which incorporated additional comments received from the Director. EFRI and the Director executed a Stipulation and Consent Agreement (SCA) on February 23, 2017 (DWMRC, 2017) defining the commitments and timeframes for completing placement of reclamation cover on Cell 2 and performance assessment of the cover system, in accordance with the Reclamation Plan Revision 5.1. EFRI updated the Reclamation Plan on February 8, 2018 to Revision 5. lB and submitted to the Director, but the guidelines, monitoring, and reporting requirements for the test sections did not change. 95 Per the 2017 SCA, the Director will approve Reclamation Plan 5.1 upon completion of a public notice and comment period, and in conjunction with and conditional upon the execution and delivery of the SCA by EFRI and the Director. 2.19.3 Provisions Included in the Permit Relating to the Mill's Reclamation Plan The Mill GWDP was issued by DWMRC on January 19, 2018 for 5 years. The current revision of the GWDP was issued March 8, 2021. The Permit ensures that the final reclamation design approved by the Director will provide adequate performance criteria to protect local groundwater quality. To this end, Part I.D.8 of the Permit states that: Closed Cell Performance Requirements -before reclamation and closure of any tailings disposal cell, the Permittee shall ensure that the final design, construction, and operation of the cover system at each tailings cell will comply with all requirements of an approved Reclamation Plan, and will for a period of not less than 200 years meet the following minimum performance requirements: a. Minimize infiltration of precipitation or other surface water into the tailings, including, but not limited to the radon barrier, b. Prevent the accumulation of leachate head within the tailings waste layer that could rise above or over-top the maximum FML elevation internal to any disposal cell, i.e. create a "bathtub" effect, and c. Ensure that groundwater quality at the compliance monitoring wells does not exceed the Ground Water Quality Standards or Ground Water Compliance Limits specified in Part I.C. l and Table 2 of this Permit. In addition, Pait I.D.9 was included in the Permit, which provides that upon commencement of decommissioning, EFRI will reclaim the Mill site and all related facilities, stabilize the tailings cells, and construct a cover system over the tailings cells in compliance with all engineering design and specifications of the approved reclamation plan. Part I.D.9 also provides that the Director reserves the right to require modifications to the Mill's Reclamation Plan for purposes of compliance with the Utah Ground Water Quality Protection Regulations, including but not limited to containment and control of contaminants, or discharges, or potential discharges to waters of the State. In response to the GWDP requirements, the EFRI Reclamation Plan delineates the activities that will assure that the uranium and vanadium processing areas of the Mill, including equipment, structures and support facilities, will be decommissioned and disposed of in tailings or buried at the Mill site as appropriate. Equipment (including tankage and piping, agitation, process control instrumentation and switchgears, and contaminated structures) will be cut up, removed, and buried in tailings prior to final cover placement. Concrete structures and foundations will be demolished and removed for disposal in tailings or covered in place with soil as appropriate. 96 The sequence of demolition will proceed so as to allow the maximum use of support areas of the facility, such as the office and shop areas. Uncontaminated or decontaminated equipment to be considered for salvage will be released in accordance with NRC guidance and in compliance with the conditions of the EFRI's License No. UT1900479. As with the equipment for disposal, contaminated soils from the Mill and surrounding areas and ore or feed materials on the Mill site will be disposed of in the tailings cells in accordance with the Reclamation Plan. 2.19.4 Post-Operational Monitoring Monitoring will continue under the Permit after cessation of operations, during reclamation and after reclamation has been completed until such time as the Mill License and Permit are terminated and the reclaimed tailings impoundments are transferred to the Department of Energy for perpetual care and maintenance. 3.0 CONCLUSIONS This Application describes the key monitoring and DMT performance standard requirements and other protections contained in the Permit. EFRI believes that with this Application, the accompanying Background Reports and other documentation, the Director has been provided sufficient information to determine that: a) EFRI has demonstrated that the applicable class TDS limits, ground water quality standards and protection levels will be met; b) The monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; c) EFRI utilizes treatment and discharge minimization technology at the Mill commensurate with plant process design capability and similar or equivalent to that utilized by facilities that produce similar products or services with similar production process technology; and d) There is no current or anticipated impairment of present and future beneficial uses of the ground water. 97 4.0 SIGNATURE AND CERTIFICATIONS This Application is being submitted by Energy Fuels Resources (USA) Inc. Energy Fuels Resources (USA) Inc. By: Scott Bakken Date Vice President, Regulatory Affairs I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the .information submitted. Based on my inquiry of the person or per ons who manage the y tern, or those person · directly re ponsible for gathering the information, the information ubmitted i to the be t of my knowledge and belief true accurate and complete. I am aware that there are significant penaltie for . ubmitting false .information, including the possibility of fine and imprisonment for knowing violations. Scott Bakken Vice President, Regulatory Affairs CERTIFICATION BY REGISTERED PROFESSIONAL ENGINEER I hereby certify that the foregoing Application has been prepared under my direction, that I have reviewed this Application, that I am familiar with the Mill facilities, and attest that this Application has been prepared in accordance with good engineering practices. Timo Groves Registered Professional Engineer State of Utah No. 11793034 (seal) 98 5.0 REFERENCES American Society for Testing and Materials. 1996. Standards on Ground Water and Vadose Investigations. Dames & Moore. January 30, 1978. Environmental Report, White Mesa Uranium Project San Juan County, Utah. D'Appolonia Consulting Engineers, Inc. June 1979. Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah. D' Appolonia Consulting Engineers, Inc. May 1981. Engineer's Report: Second Phase Design- Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah. D' Appolonia Consulting Engineers, Inc. February 1982. Construction Report: Initial Phase - Tailings Management System, White Mesa Uranium Project Blanding, Utah. Division of Radiation Control, Utah. December 1, 2004. Statement of Basis For a Uranium Milling Facility at White Mesa, South of Blanding, Utah, Owned and Operated by International Uranium (USA) Corporation. Energy Fuels Nuclear, Inc. March 1983. Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project. Energy Fuels Resources (USA) Inc. ("EFRI") August 2000. Construction Report: Tailings Cell 4A, White Mesa Uranium Mill -Tailings Management System. Prepared by EFRI (formerly International Uranium (USA) Corporation). EFRI, July 12, 2011. Revised Phase 2 QAP and Work Plan, Revision 2.0. EFRI, August 15, 2012a. Responses to Interrogatories -Round 1 for Reclamation Plan, Revision 5.0, March 2012. EFRI, August 15, 2012b. Responses to Interrogatories -Round 1 for the Revised Infiltration and Contaminant Transport Modeling Report, March 2010. EFRI August 31, 2015. Responses to Review of September 10, 2012 Energy Fuels Resources (USA) Inc. Responses to Round 1 Interrogatories on Revised Infiltration and Contaminant Transport Modeling Report, White Mesa Mill Site, Blanding Utah, Report Dated March 10. EFRI, February 8, 2018. Reclamation Plan White Mesa Mill Blanding, Utah, Revision 5.1. EFRI, October 19, 2020. Source Assessment Report for Selenium and Uranium in MW-28, White Mesa Uranium Mill, Blanding Utah. 99 EFRI, April 29, 2021 (EFRI 2021a). Source Assessment Report for Uranium in MW-31, White Mesa Uranium Mill, Blanding Utah. EFRI, September 7, 2021 (EFRI 2021b). Source Assessment Report for Uranium in MW-29, White Mesa Uranium Mill, Blanding Utah. EFRI, June 14, 2021 (EFRI 2021c). White Mesa Mill MW-24A Report, White Mesa Mill, Blanding Utah. EFRI, January 28, 2022. Source Assessment Report for Uranium and Selenium in MW-30, White Mesa Uranium Mill, Blanding Utah. Environmental Protection Agency. March, 1991. Handbook of Suggested Practices for Design and Installation of Ground-Water Monitoring Wells (EP A/600/4-89/034 ). Environmental Protection Agency. November, 1985. Practical Guide for Ground Water Sampling (EPA/600/2-85/104). GeoSyntec Consultants. January 2006. Cell 4A Lining System Design Repmt For The White Mesa Mill Blanding, Utah. GeoSyntec Consultants. December 8, 2007. Cell 4B Design Report For The White Mesa Mill Blanding, Utah. Geosyntec Consultants. July 2008. Cell 4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah. Geosyntec Consultants. November 2010. Cell 4B Construction Quality Assurance Report, Volumes 1-3. Hydro Geo Chem, Inc. 2001. Update to report: Investigation of Elevated chloroform concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah. Hydro Geo Chem, Inc. August 29, 2002. Letter Report. Hydro Geo Chem, Inc. August 20, 2007. Preliminary Corrective Action Plan, White Mesa Mill Near Blanding, Utah. Hydro Geo Chem, Inc. April 13, 2012. (2012a). Plan and Time Schedule for Assessment of pH Uner Groundwater Discharge Permit UGW370004. Hydro Geo Chem, Inc. May 7, 2012. (2012b). Nitrate Corrective Action Plan. Hydro Geo Chem, Inc. December 7, 2012. (2012c). Investigation of Pyrite in the Perched Zone, White Mesa Uranium Mill, Blanding, Utah. 100 Hydro Geo Chem, Inc. July 13, 2022. Hydrogeology of the White Mesa Uranium Mill Site Near Blanding, Utah. HydroSOLVE, Inc. 2000. AQTESOL VE for Windows. Users Guide. INTERA, Inc. October 2007. (2007a). Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA Inc. November 16, 2007. (2007b). Revised Addendum: --Evaluation of Available Pre- Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA Inc. April 30, 2008. Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA, Inc. December 30, 2009 Nitrate Contamination Investigation Report White Mesa Uranium Mill Site Blanding, Utah. INTERA, Inc. June 1, 2010 Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA, Inc. May 11, 2011. Revised Phase 1 (A through C) Work Plan and Schedule for Phase 1 A -C Investigation. INTERA, Inc. June 3, 2011. Revised Phase 2 through 5 Work Plan and Schedule. INTERA, Inc. October 10, 2012. Source Assessment Report, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. November 9, 2012. pH Report White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. May 7, 2013 (INTERA 2013a) Source Assessment Report for TDS in MW-29, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. August 30, 2013 (INTERA 2013b).Source Assessment Report for Selenium in MW-31, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. December 17, 2013 (INTERA 2013c). Source Assessment Report for Tetrahydrofuran in MW-01, White Mesa Uranium Mill, Blanding, Utah. INTERA, Inc. January 13, 2014 (INTERA 2014a). Source Assessment Report for Gross Alpha in MW-32, White Mesa Uranium Mill, Blanding, Utah. 101 INTERA, Inc. March 19, 2014 (INTERA 2014b). Source Assessment Report for Sulfate in MW- 01 and TDS in MW-03A, White Mesa Uranium Mill, Blanding, Utah. INTERA, Inc. May 1, 2014 (INTERA 2014c). Background Groundwater Quality Report for Wells MW-35, MW-36 and MW-37 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA, Inc. June 7, 2021. Background Groundwater Quality Report for Wells MW-38, MW- 39 and MW-40 White Mesa Mill Site, San Juan County, Utah. INTERA, Inc. December 9, 2015. Source Assessment Report for Selenium, Sulfate, TDS and pH in MW-31, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. June 24, 2016. Source Assessment Report for Sulfate in MW-18 and Fluoride, Cadmium Thallium and pH in MW-24, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. August 20, 2017. Source Assessment Report for Selenium, Sulfate, and Uranium in MW-31, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. June 25, 2018. Source Assessment Report for Fluoride in MW-14, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. January 16, 2019. (INTERA 2019a). Source Assessment Report for Uranium, Selenium and pH in MW-30, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. June 27, 2019. (INTERA 2019b). Source Assessment Report for Manganese in MW-11, and fluoride, pH, cadmium, beryllium, nickel, and thallium in MW-24 White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. September 23, 2019. (INTERA 2019c) Source Assessment Report for Cadmium in MW-25, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. June 24, 2020. Source Assessment Report for TDS and Sulfate, in MW-31, White Mesa Uranium Mill, Blanding Utah. Kirby, 2008. Geologic and Hydrologic Characterization of the Dakota-Burro Canyon Aquifer Near Blanding, San Juan County, Utah. Utah Geological Survey Special Study 123. Knight-Piesold LLC. November 23, 1998. Evaluation of Potential for Tailings Cell Discharge -White Mesa Mill. MWH Americas November 2007. Denison Mines (USA) Corp. Infiltration and Contaminant Transport Modeling Report, White Mesa Mill Site, Blanding, Utah. MWH Americas (Now Stantec). March, 2010. Revised Infiltration and Contamination Transport Modeling Report, White Mesa Mill Site, Blanding Utah, Denison Mines (USA) Corp. 102 Nuclear Regulatory Commission. May 1979. Final Environmental Statement related to operation of White Mesa Uranium Project Energy Fuels Nuclear Inc., Docket No. 40-8681. Resource Conservation Recovery Act. 1986. Ground Water Monitoring Technical Enforcement Guidance Document. Revised Tolling Agreement, Revision 3, between DUSA and the Director, Revision 2. August 21, 2011. Stipulated Consent Agreement Docket No. UGW12-03 between Denison Mines (USA) Corp. and the Director of the Divi ion of Radiation Control. July 12, 2012. T. Grant Hurt and D. Kip Solomon, Department of Geophy ic University of Utah. May 2008. Summary of work completed data re ults, interpretation and recommendations for the July 2007 Sampling Event at the Deni on Mine , USA White Me. a Uranium Mill Near Blanding Utah. United States Geological Survey. 1998. Techniques of Water Resource Investigation of the US Geological Survey, Book 9. TITAN Environmental Corporation. July 1994. Hydrogeological Evaluation of White Mesa Uranium Mill. Umetco Minerals Corporation. April 10, 1989. Cell 4 Design, White Mesa Project Blanding, Utah. Umetco Minerals Corporation. January 1990. White Mesa Mill Drainage Report for Submittal to NRC. Umetco Minerals Corporation and Peel Environmental Services. 1993. Groundwater Study, White Mesa Facilities, Blanding, Utah. United States Department of Agriculture Natural Resource Conservation Service http ://www.nrcs .usda.gov/wp /portaJ/nrcs/detail/ut/technical/dma/nri accessed 6/ 19/22. Utah, State of. January 20, 2010. Ground Water Discharge Permit No. UGW370004. Utah, State of. June 21, 2010. Ground Water Discharge Permit No. UGW370004. Utah, State of. February 15, 2011. Ground Water Discharge Permit No. UGW370004. Utah, State of. June 13, 2011. Ground Water Discharge Permit UGW370004. Utah, State of. July 14, 2011. Ground Water Discharge Permit No. UGW370004 103 Utah, State of. September 7, 2011. Ground Water Discharge Permit UGW370004. Utah, State of. August 24, 2012. Ground Water Discharge Permit No. UGW370004. Utah, State of. July 27, 2021 (Amendment 10) Radioactive Materials License No. UT 1900479 (the "Mill License"). Utah, State of. December 23, 2021. Air Approval Order No. DAQE-ANl 12050024-21 (the "Air Order"). Utah, State of. Department of Environmental Quality, Stipulation and Consent Agreement between Ene.rgy Fuel Re ource (USA) Inc. and the Director of the Utah Division of Wa te Management and Racliation Control ("Division") (Cell 2 Cover SCA). 104 Table No. 1.2-1 ............. . 1.2-2 ............. . 2.4-1 .............. . 2.5.2.1-1 ......... . 2.5.3-1 ........... . 2.5.3-2 ........... . 2.5.3-3 ........... . 2.5.3-4 ........... . 2.5.3-5 ........... . 2.9.1.3-1 ......... . 2. L1 .2-1 .......... . 2.13.1-1 ........... . INDEX OF TABLES Description Chloroform Monitoring Wells (Depth and Purpose) Nitrate Monitoring Wells (Depth and Purpose) Groundwater Monitoring Wells (Depth and Purpose) Water Quality of Entrana/N avajo Aquifer in the Mill Vicinity Results of Quarterly Sampling Ruin Spring (2003-2004) Results of Annual Sampling Ruin Spring (2009-2022) Results of Annual Sampling Cottonwood Spring (2009-2022) Results of Annual Sampling Westwater Seep (2009-2022) Results of Annual Sampling Entrance Spring (2009-2022) Groundwater Monitoring Constituents Listed in Table 2 of the Permit Plan & Time Schedule and Source Assessment Report Status Drainage Areas of Mill Vicinity and Region Table 1.2-1 Chloroform Monitoring Wells (Depth and Purpose) Wd: L0,wjj, D "f01tal Dqlh Jhwvns:e TW4-1 111.04 Chloroform Monitoring Well TW4-2 121.125 Chloroform Monitoring Well TW4-3 141.00 Chloroform Monitoring Well TW4-4 114.50 Chloroform Pumping Well TW4-5 121.75 Chloroform Monitoring Well TW4-6 98.55 Chloroform Monitoring Well TW4-7 119.80 Chloroform Monitoring Well TW4-8 126.00 Chloroform Monitoring Well TW4-9 121.33 Chloroform Monitoring Well TW4-10 111.00 Chloroform Monitoring Well TW4-11 100.00 Chloroform Monitoring Well TW4-12 101.50 Chloroform Monitoring Well TW4-13 102.50 Chloroform Monitoring Well TW4-14 93.00 Chloroform Monitoring Well MW-26 121.33 Chloroform Pumping Well/Groundwater Monitoring Well TW4-16 142.00 Chloroform Monitoring Well MW-32 130.60 Chloroform Pumping Well/Groundwater Moni toring Well TW4-18 137.50 Chloroform Monitoring Well TW4-19 121.33 Chloroform Pumping Well TW4-20 106.00 Collapsed/ Abandoned TW4-21 120.92 Chloroform Monitoring Well TW4-22 113.50 Chloroform Monitoring Well/Nitrate Pumping Well TW4-23 113.50 Chloroform Monitoring Well Well Location Total Depth Purpose I TW4-24 113.50 Chloroform Monitoring Well/Nitrate Pumping Well TW4-25 134.80 Chloroform Monitoring Well/Nitrate Pumping Well TW4-26 86.00 Chloroform Monitoring Well TW4-27 96.00 Chloroform Monitoring Well TW4-28 105.00 Chloroform Monitoring Well TW4-29 91.00 Chloroform Monitoring Well TW4-30 90.00 Chloroform Monitoring Well TW4-31 104.00 Chloroform Monitoring Well TW4-32 113.00 Chloroform Monitoring Well TW4-33 84.70 Chloroform Monitoring Well TW4-34 94.00 Chloroform Monitoring Well TW4-35 86.5 Chloroform Monitoring Well TW4-36 99.41 Chloroform Monitoring Well TW4-37 113.72 Chloroform Pumping Well TW4-38 113.92 Chloroform Monitoring Well TW4-39 120.74 Chloroform Pumping Well TW4-40 86.00 Chloroform Pumping Well TW4-41 97.80 Chloroform Pumping Well TW4-42 86.00 Chloroform Monitoring Well TW4-43 95.50 Chloroform Monitoring Well Table 1.2-2 Nitrate Monitoring Wells (Depth and Purpose) Dum.atbm 1:qtalDe]dh ~p-o e TWN-1 112.50 Nitrate Monitoring Well TWN-2 95.00 Nitrate Pumping Well TWN-3 110.00 Nitrate Monitoring Well TWN-4 136.00 Nitrate Monitoring Well TWN-5 155.00 Abandoned TWN-6 135.00 Water Level Monitoring Well TWN-7 120.00 Nitrate Monitoring Well TWN-8 160.00 Abandoned TWN-9 102.50 Abandoned TWN-10 107.50 Abandoned TWN-11 147.50 Abandoned TWN-12 115.00 Abandoned TWN-13 120.00 Abandoned TWN-14 135.00 Water Level Monitoring Well TWN-15 155.00 Abandoned TWN-16 100.00 Water Level Monitoring Well TWN-17 100.00 Abandoned TWN-18 100.00 Nitrate Monitoring Well TWN-19 110.00 Water Level Monitoring Well TWN-20 95.50 Nitrate Monitoring Well TWN-21 105.70 Nitrate Monitoring Well PIEZ-01 107.50 Nitrate Monitoring Piezometer PIEZ-02 100.00 Nitrate Monitoring Piezometer PIEZ-03A 79.00 Nitrate Monitoring Piezometer Table 2.4-1 Groundwater Monitoring Wells (Depth and Purpose) W:eJI Location Total Depth Purpose MW-1 115.00 General Monitoring Well MW-2 125.00 Semi-Annual Groundwater Compliance MW-3 96.00 Abandoned MW-3A 95.00 Semi-Annual Groundwater Compliance MW-4 122.00 No Longer Included In Groundwater Program MW-5 138.50 Semi-Annual Groundwater Compliance MW-11 135.00 Quarterly Groundwater Compliance MW-12 129.00 Semi-Annual Groundwater Compliance MW-14 127.00 Quarterly Groundwater Compliance MW-15 134.00 Semi-Annual Groundwater Compliance MW-17 110.00 Semi-Annual Groundwater Compliance MW-18 148.50 General Monitoring Well MW-19 149.00 General Monitoring Well MW-20 114.50 General Monitoring Well MW-22 140.00 General Monitoring Well MW-23 129.00 Semi-Annual Groundwater Compliance MW-24 119.90 Semi-Annual Groundwater Compliance MW-24A 120.00 Additional Studies MW-25 115.10 Quarterly Groundwater Compliance MW-26 121.33 Quarterly Groundwater Compliance MW-27 91.00 Semi-Annual Groundwater Compliance MW-28 106.00 Semi-Annual Groundwater Compliance W<41 L<Joatiu T~tal lte,pth Pu.t-,pQse MW-29 125.00 Semi-Annual Groundwater Compliance MW-30 107.00 Quarterly Groundwater Compliance MW-31 129.00 Quarterly Groundwater Compliance MW-32 133.70 Semi-Annual Groundwater Compliance MW-33 103.50 Dry, Not sampled MW-34 109.00 Water Level Monitoring only MW-35 123.60 Semi-Annual Groundwater Compliance MW-36 119.90 Quarterly Groundwater Compliance MW-37 120.20 Semi-Annual Groundwater Compliance MW-381 90.00 Quarterly Groundwater for Background MW-391 102.50 Quarterly Groundwater for Background MW-401 120.00 Quarterly Groundwater for Background TW4-242 113.50 General Monitoring Well Notes: 1 -The Background Report for MW-38, MW-39, and MW-40 was submitted on June 7, 2021. These wells will continued to be sampled quarterly until such a time that these wells are incorporated into the GWDP and the frequency is changed as appropriate. 2 -TW4-24 is a chloroform monitoring well and nitrate pumping well. It is sampled semi-annually under the groundwater program as a general monitoring well. Table 2.5.2.1-1 Water Quality of Entrana/Navajo Aquifer in the Mill Vicinity FES, Test Well Well#2 Well#S Parameter (G2R) 6/01/991 6/08/991 (1/27/77 -3/23/781) Field Specific Conductivity 310 to 400 (umhos/cm) Field pH 6.9 to 7.6 Temperature (0C) 11 to 22 Estimated Flow m/hr (gom) 109(20) pH 7.9to8.16 Determination, mwliter TDS (@ l 80°C) 216 to 1110 Redox Potential 211 to 220 Alkalinity (as CaCOS3) 180 to 224 Hardness, total (as CaC03) 177 to 208 Bicarbonate 226 214 Carbonate (as C03) 0.0 <1.0 <1.0 Aluminum 0.003 0.058 Aluminum, dissolved <0.1 Ammonia (as N) 0.0 to 0.16 <0.05 <0.05 Antimony <0.001 <0.001 Arsenic, total .007 to 0.014 0.018 <0.001 Barium, total 0.0 to 0.15 0. I 19 0.005 Beryllium <0.001 <0.001 Boron, total <0.1 to 0.11 Cadmium, total <0.005 to 0.0 <0.001 0.018 Calcium 50.6 39.8 Calcium, dissolved 51 to 112 Chloride 0.0 to 50 <1.0 2.3 Sodium 7.3 9.8 Sodium, dissolved 5.3 to 23 Silver <0.001 <0.001 Silver, dissolved <0.002 to 0.0 Sulfate 28.8 23.6 Sulfate, dissolved (as SQ4) 17 to 83 Vanadium 0.003 0.003 Vanadium, dissolved <.002 to 0. I 6 Manganese 0.011 0.032 Manganese, dissolved 0.03 to 0.020 Chromium, total 0.02 to 0.0 0.005 0.005 Copper, total 0.005 to 0.0 0.002 0.086 Fluoride 0.18 0.18 Fluoride, dissolved 0.1 to 0.22 Iron, total 0.35 to 2.1 0.43 0.20 Iron, dissolved 0.30 to 2.3 Lead, total 0.02 -0.0 <0.001 O.Dl8 Ma.!!;nesium 20.4 21.3 Magnesium, dissolved I 5 to 21 Mercury, total <.00002 to 0.0 <0.001 <0.001 Molybdenum 0.001 <0.001 1 Zero values (O.O) are below detection limits. FES, Test Well Well#2 Well#5 Parameter (G2R) 6/01/991 6/08/991 (1/27/77 · 3/23/781) Molybdenum, dissolved 0.004 to 0.010 Nickel <0.001 0.004 Nitrate + Nitrate as N <0.10 <0.10 Nitrate (as N) <.05 to 0.12 Phosphorus, total (as P) <0.0 l to 0.03 Potassium 3.1 3.3 Potassium, dissolved 2.4 to 3.2 Selenium <0.001 <0.001 Selenium, dissolved <.005 to 0.0 Silica dissolved (as Si02) 5.8 to 12 Strontium, total 0.5 to 0.67 Thallium <0.001 <0.001 Uranium, total (as U) <.002 to 0.16 0.0007 0.0042 Uranium dissolved (as U) <.002 to 0.031 Zinc 0.010 0.126 Zinc, dissolved 0.007 to 0.39 Total Organic Carbon 1.1 to 16 Chemical Oxvll:en Demand <l to 66 Oil and Grease 1 Total Suspend1::d Solids 6 to 1940 <1.0 10.4 Turbidjty 5.56 19.1 Determination (pCi/liter) Gross Alpha <1.0 Gross Alpha + precision 1.6+1.3 to 10.2+2.6 Gross Beta <2.0 Gross Beta+ precision 8+8 to 73+J9 Radium 226 + precision 0.3+0.2 Radium 228 <1.0 Ra-226 + precision 0.1 +.3 to 0.6+0.4 Th-230 + preci sion 0.1+0.4 to 0.7+2.7 Pb-210 + precision 0.0+4.0 to 1.0+2.0 Po-210 + precision 0.0+0.3 to 0.0+0.8 Source: Adapted from FES Table 2.25 with additional Mill sampling data Parameter Ma.ior Ions (m2'L) Alkalinity Carbon Dioxide Carbonate Bicarbonate Hydroxide Calcium Chloride Fluoride Magnesium Nitrogen, Ammonia As N Nitrogen, Nitrate+Nitrite as N Phosohorous Potassium Sodium Sulfate Physical Properties Conductivity (umhos/cm) pH TDS (m.l!/L) TSS (mg/L) Turbidity (NTU) Metals-Dissolved (me/L) Aluminum Antimony Arsenic Barium Beryllium Cadmium Chromium Coooer Iron Lead Manganese Mercury Molybdenum Nickel Selenium Silver Thallium Uranium Vanadium Zinc Radionuclides (pCi/L) Gross Alpha Minus Rn & U Lead 210 Radium 226 Thorium 230 Thorium 232 Thorium 228 Table 2.5.3-1 Results of Quarterly Sampling Ruin Spring (2003-2004) Ruin Sprine. Ql-03 02-03 QJ-03 Q4-3 Ql-04 --196 198 193 --ND ND ND --ND ND ND --239 241 235 -ND ND ND 153 156 149 158 158 28. l 21.5 27.4 28.0 29.3 --ND 0.5 0.5 34.8 34.2 31.7 34.2 35.8 ND ND ND ND ND 1.6 1.5 1.4 1.4 1.73 0.10 ND -ND ND 2.6 3.3 3.3 3.9 3.4 110 105 103 113 104 503 501 495 506 539 . . 1440 1410 1390 . -7.91 7.98 -. . 1040 1000 1050 -. 13.5 ND ND . . 0.16 0.13 ND ND ND 0.40 ND ND ND ND ND ND ND 0.001 ND ND 0.001 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.082 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.013 0.012 0.012 0.012 0.012 ND ND ND ND ND ND ND ND ND ND 0.009 0.011 0.010 0.010 0.011 ND ND ND ND ND 0.014 ND ND ND ND ----ND 42 ND ND ND ND 0.3 ND 0.3 ND ND 0.3 0.2 0.5 ND ND --ND ND ND . -ND ND ND Q2-04 Q3-04 Q4-04 191 195 183 ND 12 ND ND ND ND 232 238 223 ND ND ND 162 176 186 28.5 26 25 0.6 0.6 0.6 35.l 37. l 38.6 0.06 ND 0.06 1.85 1.34 1.7 ND ND ND 3.6 4.0 3.7 110 113 116 468 544 613 1440 1320 1570 -- 1110 1050 1070 ND ND ND 0.12 -- ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.012 0.012 0.012 ND ND ND ND ND ND 0.011 0.009 0.010 ND ND ND ND ND ND ND 1.4 ND ND ND ND ND 1.3 ND ND 0.4 ND ND ND - ND -- Table 2.5.3-2 Results of Annual Sampling Ruin Spring (2009-2022) Ruin Spring Range of Average Constituent 2009 2010 2011 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Historic Avg2003 May July 2022 Values for 20042 Monitoring Wells 1 * Major Ions (mg/I) Carbonate <I <I <I I <I <I <I <I <l <I <I <I <I <l <l -= - Bicarbonate 233 254 241 239 237 208 204 200 193 208 202 202 186 200 185 -- Calcium 151 136 145 148 147 149 150 162 138 145 158 165 169 154 141 -- Chloride 28 23 25 44 28 26.3 27.1 27.4 24.4 27.4 29.9 23.9 25.8 28.1 28.4 ND-213 27 Fluoride 0.5 0.53 0.45 0.5 0.52 0.538 <I 0.445 0.541 0.5 0.414 0.505 0.473 0.468 0.5 ND-1.3 0.6 Magnesium 32.3 29.7 30.6 31. J 31.9 32.1 35.4 31.8 31.1 30.2 33.9 45.6 36.9 34.8 32.9 -- Nitrogen-Ammonia 0.09 <0.05 ND <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.2 -- Nitrogen-Nitrate 1.4 1.7 1.7 1.6 1.6 1.56 1.54 1.31 1.64 1.55 1.35 1.56 1.39 1.26 1.2 -- Potassium 3.3 3.07 3.2 3.3 3.5 3.46 3.24 3.14 3.18 3.07 3.58 3.31 4.09 3.83 3.2 -- Sodium 104 93.4 110 111 115 118 119 126 105 113 128 128 139 119 117 -- Sulfate 528 447 486 484 464 553 553 528 490 476 547 474 469 557 595 ND-3455 521 TDS 1010 903 942 905 1000 952 984 1000 916 972 1000 900 1240 1080 992 1019 -5548 1053 Metals (ug/1) Arsenic <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <0.5 -- Beryllium <0.5 <0.5 <0.5 < 0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 -- Cadmium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 ND-4.78 0.01 Chromium <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 4.2 -- Cobalt <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <0.5 -- Copper <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <1.0 "'-- Iron <30 <30 <30 <30 <30 <30 <30 <30 <30 <30 <30 <30 <30 <30 <20 ND-7942 25 Lead <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <l.0 <l.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.5 --- Manganese <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <0.5 ND-34,550 5 Mercury <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 -- Molybdenum 17 17 16 17 16 16.1 16.0 18.3 17.8 17.2 18 20.2 18.7 18.7 17.7 -- Nickel <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 0.6 ND-61 0.05 Selenium 12.2 10 11.8 10.2 10.8 10.2 12 10 10 10.5 12.2 10.8 10.5 11.2 11.7 ND-106.5 12.1 Silver <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <0.5 -- Thallium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 -- Tin <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <20 -- Uranium 9.11 8.47 9.35 8.63 8.68 9.12 9.61 9.03 8.38 8.49 9.35 9.02 9.32 9.31 9.1 ND-59.8 10 Vanadium <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 1.3 -- Zinc <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 -- Table 2.5.3-2 Results of Annual Sampling Ruin Spring (2009-2022) -Ruin Spring Range of Average Constituent 2009 2010 2011 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2022 Historic Avg2003 May July 2021 Values for 20042 Monitoring Wells 1* Radiologies (pCill)_ Gross Alpha <0.2 <0.2 <-0.3 <-0.05 <-0.09 <LO <I <1.0 <1.0 <LO <1.57 <1.0 <1.0 <LO <1.0 ND -36 0.28 VOCS(ug/L) Acetone <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <10 -- Benzene <LO <1.0 <LO <1.0 <LO <LO <LO <LO <1.0 <LO <1.0 <LO <1.0 <1.0 <1.0 -- Carbon <LO <1.0 <LO <1.0 <LO <LO <1.0 <LO <LO <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Teirachloride -- Chloroform <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <LO <1.0 <1.0 <LO <1.0 <l.0 <1.0 <l.0 --- Chloromethane <LO <1.0 <1.0 <LO <1.0 <LO <1.0 <1.0 <1.0 <LO <1.0 <1.0 <1.0 <l.0 <1.0 -.,. MEK <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <10 -- Methylene Chloride <LO <1.0 <LO <LO <LO <1.0 <LO <1.0 <LO <LO <1.0 <LO <1.0 <LO <2.0 -- Naphthalene <LO <LO <LO <1.0 <LO <LO <1.0 <LO <1.0 <LO <1.0 <1.0 <1.0 <LO <1.0 -- Tetrahydrofuran <1.0 <1.0 <LO <1.0 <LO <1.0 <LO <LO <1.0 <1.0 <1.0 <LO <1.0 <LO <1.0 -- Toluene <1.0 <1.0 <1.0 <1.0 <LO <1.0 <LO <1.0 <1.0 <LO <1.0 <LO <1.0 <LO <1.0 -- Xylenes <1.0 <LO <1.0 <LO <1.0 <1.0 <1.0 <1.0 <LO <1.0 <LO <1.0 <1.0 <1.0 <1.0 -- 1 From Figure 3, Table IO and Appendix B of the Revised Addcmlum. Background Grom1d .. wer Qua/If)' Re11or1: New \\'ellf ft1r Denison Mines (USA) Corp·.~ \\fhite Mesa Mill Sire. San Juan Cou11f)·. Uwlt . April 30. 2008. prepared by INTERA, Inc. and Table 16 and Appendix D of the Revised Backgr<111nd Gmundwater Quality Re11on: £,risring Wells/or Deni.,m1 Mi11u.~ (USA) Corp. ·s White M,m, Uranium Mill Sire. San Juan Counf)'. Utah. October 2007. prepared by INTERA. Inc. 2 From Figure 9 of the Revised Addendum, Evalua1ion of Available Pre-Operario,u1I and Regional Backrvound Data. Background Groundwater Quality Report: Existing Wells for Deni.wn MineJ (USA) Co,p. 's While Mesa Mill Sire. San Juan Couinf)•, Utah, November 16, 2007, prepared by INTERA, Inc. *Range of average historic values for On-Site Monitoring Wells as reported on April 30, 2008 (MW-l, MW-2. MW-3, MW-3A, MW-4, MW-5. MW-I I, MW-12, MW-14. MW-15, MW-17, MW-18, MW-19, MW-20. MW-22, MW-23, MW-24, MW-25. MW-26, MW-27, MW-28, MW-29, MW-30, MW-31 and MW-32)1 Table 2.5.3-3 Results of Annual Sampling Cottonwood Spring (2009-2022) Cottonwood Spring Range of Average Constituent 2009 2010 2011 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 Historic Avgl~7 May July Values for 1982 1 Monitoring Wells1"' Major Ions (mg/I) Carbonate <I <I <l 6 <I <I <I <I <I <I <I <l <I <l <I -- Bicarbonate 316 340 330 316 326 280 251 271 256 280 283 286 280 298 267 -- Calcium 90.3 92.2 95.4 94.2 JOI 87.9 99.7 Ill 102 99.6 109 122 120 108 99.0 -- Chloride 124 112 113 134 149 118 128 133 138 129 153 138 146 143 143 ND-213 31 Fluoride 0.4 0.38 0.34 0.38 0.38 0.417 <I 0.318 0.466 0.344 0.282 0.249 0.233 0.317 0.3 ND-1.3 0.8 Magnesium 25 24.8 25.2 25.2 27.7 23.6 29.0 27.5 29.5 27.1 30.2 35.3 32.9 31.3 28.5 -- Nitrogen-<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.0512 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.2 Ammonia -- Nitrogen-Nimue 0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.124 0.108 <0.1 <0.1 <0.1 <0.1 -- Potassium 5.7 5.77 6 5.9 6.2 5.53 6.18 5.91 6.11 5.72 6.35 6.78 7.14 7.40 5.9 -- Sodium 205 214 229 227 247 217 227 251 221 213 234 268 273 223 214 -- Sulfate 383 389 394 389 256 403 417 442 443 409 428 423 417 443 528 ND-3455 230 TDS 1010 900 1030 978 1040 996 968 1020 1070 1080 1080 1010 860 1110 1130 10l9 -5548 8.11 Metals (ug/1) Arsenic <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 1.8 -- Beryllium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 -- Cadmium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 ND.-4.78 - Chromium <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 6.6 -- Cobalt <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <0.5 -- Copper <10 <10 <10 <10 <10 <10 <JO <10 <10 <10 <10 <10 <10 <10 <1.0 --" Iron <30 <30 53 <30 <30 <30 <30 <30 <30 <30 <30 <30 <30 <30 <20 ND -7942 150 Lead <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.5 -- Manganese <JO <10 <10 <JO <JO <10 <10 <10 <JO <10 <10 <10 <10 <10 0.9 ND -34.550 580 Mercury <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 - Molybdenum <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <IO <10 <10 1.4 ·--" Nickel <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <0.5 ND-61 ·- Selenium <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5 <5 <5 <5 <5 <5 <5 1.4 ND · 106.5 -· Silver <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <0.5 -- Thallium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <5 <5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 --·- Tin <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <20 .. -- Uranium 8.42 8.24 7.87 8.68 8.17 8.95 9.62 9.12 8.84 9.17 10.3 10.1 10.5 10.6 9.7 ND -59,8 - Vanadium <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 2.4 -- Zinc <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 -- Table 2.5.3·3 Results of Annual Sampling Cottonwood Spring (2009·2022) Cottonwood Spring Range of Average Constituent 2009 2010 2011 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 Historic Avg1977 May July Values for 1982 1 Monitoring Wells1* Radiologies (pCi/1) Gross Alpha <0.2 <0.2 <0.1 <-0.1 <-0.2 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ND ·36 7.2_ VOCS(ug/L) Acetone <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <10 -- Benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- Carbon <1.0 <.1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <l.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 tetrachloride -- Chloroform <1.0 <1.0 <1.0 <1.0 <1.0 <l.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- Chloromethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- MEK <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <10 -- Methylene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 -Chloride - Naphthalene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- Tetruhydrofuran <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- Toluene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- Xylenes <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ---- 1 From Figure 3, Table LO and Appendix B of the Revised Addendum, Backgroulld Grou1Zdwater Quality Repor1: New Wells.for Denison Mines (USA) Corp 's White Mesa Mill Site, San Juan Count.·, Utah, April 30, 2008, prepared by INTERA, Inc. and Table 16 and Appendix D of the Revised Background Groundwater Qua/in• Repor1: Existing Wells for Denison Mines (USA) Corp. 's White Mesa Uranium Mill Sire, San Juan Count.-, Utah, October 2007, prepared by INTERA, Inc. *Range of average historic values for On-Site Monitoring Wells as reponed on April 30, 2008 (MW-L MW-2, MW-3. MW-3A, MW-4, MW-5. MW-11. MW-12. MW-14, MW-15. MW-17. MW-18. MW-19, MW-20. MW-22, MW-23. MW-24. MW-25. MW-26, MW-27. MW-28, MW-29, MW-30. MW-3 l and MW-32) Table 2.5.3-4 R fA IS line. Wi s (2009-2022) Westwater·Seep· Range of Average Constituent 2009 2010 2011 May 2011 July 2012 2013 2014 2015 2016 2017 2018 2019 2020 2020 2021 2022 Historic (March) (June) Values for Monitoring Wells1 * Major Ions (llll! ) Carbonate <I <I <I <1 <1 <1 <l <I <I <1 <I <I - Bicarbonate 465 450 371 359 399 369 444 450 270 450 320 257 - Calcium 191 179 247 150 176 125 204 185 118 204 125 104 - Chloride 41 40 21 32.6 38.0 27.5 36.2 41.6 26.6 40.6 29.2 21.9 ND-213 Fluoride 0.7 0.6 0.54 0.424 0.618 0.574 0.659 0.505 0.555 0.429 0.473 0.5 ND-1.3 Magnesium 45.9 44.7 34.7 Not Not Sampled Not Sampled Not Sampled 34 47.3 31.7 56.6 43.7 30.8 54.6 30.9 26.4 - Nitrogen-Ammonia <0.05 0.5 0.06 Sampled Dry Dry Dry 0.123 <0.05 <0.05 0.0832 <0.05 0.0593 <0.05 <0.05 <0.2 Dry - Ni1rogen-Nitrate 0.8 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - Potassium 1.19 6.57 3.9 1.98 2.32 2.33 2.94 3.99 1.76 5.28 1.78 1.3 - Sodium 196 160 l 12 139 185 133 218 152 117 245 111 98.7 - Sulfate 646 607 354 392 573 318 580 436 307 460 340 278 ND-3455 TDS 1370 1270 853 896 1060 820 1220 1110 1200 1480 876 672 1019-5548 Metals (ue/1) Arsenic <5 <5 12.3 <5.0 <5.0 <.5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1.8 - Beryllium <0.5 <0.5 0.91 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - Cadmium <0.5 <0.5 0.9 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 ND-4.78 Chromium <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 1.4 - Cobalt <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 I - Copper <10 <10 16 <10 <lO <10 <10 <10 <10 <10 <10 <1.0 - Iron 89 56 4540 <30 40.l 181 575 1200 401 <30 948 920 ND-7942 Lead <1.0 <1.0 41.4 <1.0 <1.0 <1.0 <l.0 <1.0 <1.0 <l.0 <1.0 <0.5 - Manganese 37 87 268 Not 171 55.5 144 312 528 369 35.4 432 206 ND-34,550 Mercury <0.5 <0.5 <0.5 Sampled Not Sampled Not Sampled Not Sampled <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 Dry Dry Dry - Molybdenum 29 29 <10 Dry <10 <10 <10 <10 <10 <10 <lO <10 1.4 - Nickel <20 <20 29 <20 <20 <20 <20 <20 <20 <20 <20 1.7 ND-61 Selenium <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5 .0 <5.0 1.4 ND-106.5 Silver <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <lO <0.5 - Thallium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 - Tin <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <20 - Uranium 15.1 46.6 6.64 2.1 19.0 5.17 13.2 4.92 2.34 12.90 2.07 1.40 ND-59.8 Vanadium <15 <15 34 <15 <15 <15 <15 <15 <15 <15 <15 0.6 - Zinc <10 <10 28 <10 <10 <10 <10 <10 <10 <10 <10 <10 - Table 2.5.3-4 Results of Annual SamplinjL Westwater Seep (2009-2022) Westwater Seep Range of Average Constituent 2009 2010 2011May 2011 July 2012 2013 2014 2015 2016 2017 2018 2019 2020 2020 2021 2022 Historic (March) (June) Values for Monitoring Wells1 "' RadioJQJ?ics (pCi/1) Not Not Sampled Not Sampled Not Sampled Gross Alpha <-0.1 <0.3 0.5 Sampled <l.0 <l.0 <1.0 <1.0 <1.0 <l.0 <1.0 <1.0 <l.0 ND-36 Dry Dry Dry Dry voes (u!!IL) Acetone <20 <20 <20 <20 <20 23.l <20 <20 <20 <20 <20 <10 - Benzene <l.0 <l.0 <l.0 <l.0 <1.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 <0.4 - Carbon tetrachloride <1.0 <l.O <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.O <l.0 - Chloroform <1.0 <l.0 <1.0 <l.0 <l.0 <l.0 <1.0 <1.0 <l.0 <1.0 <l.0 <l.0 - Chloromethane <l.0 <l.0 <l.0 Not <l.0 <1.0 <l.0 <l.0 <l.0 <1.0 <1.0 <l.0 <l.0 - MEK <20 <20 <20 Sampled Not Sampled Not Sampled Not Sampled <20 <20 <20 <20 <20 <20 <20 <20 <10 Dry Dry Dry - Mc1hylcne Chloride <1.0 <1.0 <1.0 Dry <1.0 <l.0 <l.0 <l.0 <l.0 <1.0 <l.0 <l.0 <2.0 - Naphthalene <l.0 <l.0 <1.0 <l.0 <1.0 <l.0 <1.0 <l.0 <1.0 <1.0 <l.0 <1.0 ~ - Te1rahydrofumn <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 <1.0 <l.0 <l.0 <l.0 <l.0 <l.0 - Toluene <l.0 <l.0 <l.0 <1.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 - Xylenes <l.0 <l.0 <l.0 <l.0 <l.0 <1.0 <l.0 <l.0 <l.0 <l.0 <l.0 <l.0 -·-~ .. . -.. ·--· -... -.. -.. .. .. -. .. I • o-. • • ·----·-___ ., .. .. .. --·- by INTERA, Inc. and Table 16 and Appendix D of the Revised Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp. 's White Mesa Uranium Mill Site, San Juan County, Utah , October 2007, prepared by INTERA, Inc. - *Range of average historic values for On-Site Monitoring Wells as reported on April 30, 2008 (MW-!, MW-2, MW-3, MW-3A, MW-4, MW-5, MW-! I, MW-1 2, MW-14, MW-15, MW-17, MW-18, MW-19, MW-20, MW-22, MW- 23, MW-24, MW-25, MW-26, MW-27, MW-28, MW-29, MW-30, MW-31 and MW-32) Table 2.5.3-5 Results of Annual Sampling Entrance Spring (2009-2022) -Entrance Sj>ring - Range of A vetage, Constituent 2009 2010 2011 May 2011 July 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 Historic Values for Monitoring Wells1* Major Ions (mwl) Carbonate <I <I <I 7 <I <I <I <I <I <I <I <I <I <I <I - Bicarbonate 292 332 270 299 298 292 247 324 340 402 236 480 242 260 308 -· Calcium 90.8 96.5 88.8 96.6 105 121 103 131 131 129 116 155 144 138 123 - Chloride 60 63 49 64 78 139 76.8 75.6 75 84.6 75.9 104 76.7 90.3 91.8 ND-213 Fluoride 0.7 0.73 0.58 0.58 0.64 0.71 <I 0.606 0.668 0.615 0.454 0.912 0.638 0.625 0.8 ND-1.3 Ma~nesium 26.6 28.9 26.4 28.4 32.7 43 34.9 33.3 38.6 36.4 42.4 48.0 45.1 47.7 44.8 -- Nitrogen-Ammonia 028 <0.05 <0.05 0.32 <0.05 <0.05 <0.05 0.202 0.0962 0.247 0.102 0.168 <0.05 <0.05 <0.2 - Nitrogen-Nitrate 1.4 1 1.4 0.5 2.8 2.06 3.65 <0.1 0.403 <I 2.34 <I 2.46 1.55 0.2 - Potassium 2.4 2.74 2.6 2.9 2 3.83 1.56 1.62 <1.0 3.88 3.64 4.66 4.31 4.04 4.5 - Sodium 61.4 62.7 62.5 68.6 77.4 127 78.9 93.1 90.8 90.3 96 126 108 98.3 100 -- Sulfate 178 179 166 171 171 394 219 210 245 187 243 160 317 362 323 ND-3455 TOS 605 661 571 582 660 828 688 680 828 752 820 892 964 888 904 1019-SS{S Metals ( 112/1) Arsenic <5 <5 <5 <5 <5 <5 <5 5.02 <5 9.16 <5 8.94 <5 <5 3.1 ·- Beryllium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - Cadmium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 ND-4.78 Chromium <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 5.S - Cobalt <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 I - Coooer <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <1.0 - Iron <30 <30 37 55 34 162 37.2 295 94.4 371 <30 453 <30 <30 390 Nll>-7942 Lead <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <l.0 <0.5 - Manganese 54 II 47 84 <10 259 16.1 367 210 9 13 405 587 56.3 27.2 629 !ID • 34 .5SO Mercury <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.2 - Molybdenum <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 14.30 <10 <10 1.8 -- Nickel <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 1.0 ND-61 Selenium 12.1 9 .. 2 13.1 5.5 13.2 1 l.2 15.9 <5 <5 <5 15.3 <5 15 13.6 5.2 NE>'-106.5 Silver <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <0.5 - Thallium <0.5 <0.5 <0.5 <O·.S <0.5 <O.S <0.5 <O.S <0.5 <0.5 <0.5 <O.S <0.5 <0.5 <0.2 - Tin <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <20 - Uranium 15.2 17.8 18.8 15.3 21.1 38.8 23.2 36 22.0 14.6 27.6 70.I 24.7 36.1 17.5 ND-59.8 Vanadium <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 <15 3.4 - Zinc <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 - Table 2.5.3-5 Results of Annual Sampling Entrance Spring (2009-2022) Entrance Spring - Range of Average Constituent 2009 2010 2011 May 2011 JuJ:i: 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 Historic Values for Monitoring Wells1 • Radioloeics (pCi/1)' Gross Aloha 0.9 <0.5 I 1.5 1.6 0.5 2.3 <I 3.05 <I 2.53 <I 2.63 <I <I <I ND-36 voes c mill.) Acetone <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <ID -- Benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Carbon tetrachloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Chloroform <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Chloromethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - MEK <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <10 - Methvlene Chloride <1.0 <l.0 <1.0 <l.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 - Naphthalene <1.0 <1.0 <1.0 <l.0 <l.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Tetrahvdrofuran <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Toluene <1.0 <1.0 <l.0 <1.0 <1.0 <1.0 1.32 <1.0 <1.0 13.1 <1.0 5.59 <1.0 <1.0 <l.0 - Xylenes <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - 1 From Figure 3, Table lO and Appendix B of the Revised Addendum, Background Groundwater Qualiry Report: New Wells.for Denison Mines (USA) Corp 's White Mesa Mill Site, San Juan Counly, Utah , April 30, 2008, prepared by INTERA, Inc. and Table 16 and Appendix D of the Revised Background Groundwater Qua lily Report: Existing Wells.for Denison Mines (USA) Corp. 's White Mesa Uranium Mill Site, San Juan Counry, Utah, October 2007, prepared by INTERA, Inc. *Range of average historic values for On-Site Monitoring Wells as reported on April 30, 2008 (MW-I, MW-2, MW-3, MW-3A, MW-4, MW-5, MW-11. MW-12, MW-14, MW-15, MW-17, MW-18, MW-19, MW-20, MW- 22, MW-23, MW-24, MW-25, MW-26, MW-27, MW-28, MW-29, MW-30, MW-31 and MW-32) Table 2.9.1.3-1 Groundwater Monitoring Constituents Listed in Table 2 of the Permit Nutrients: Ammonia ( as N) Nitrate & Nitrite (as N) Heavy Metals: Arsenic Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Mercury Molybdenum Nickel Selenium Silver Thallium Tin Uranium Vanadium Zinc Radiologies: Gross Alpha Volatile Organic Compounds: Acetone Benzene 2-Butanone (MEK) Carbon Tetrachloride Chloroform Chloromethane Dichloromethane Naphthalene Tetrahydrofuran Toluene Xylenes (total) Others: Field pH (S.U.) Fluoride Chloride Sulfate Plan and Time Schedule (P&TS) Date 6/13/2011 9/7/2011 4/13/2012 12/13/2012 3/15/2013 8/28/2013 9/20/2013 12/5/2013 12/4/2014 5/19/2015 9/10/2015 12/3/2015 3/3/2016 3/10/2017 3/2/2018 8/28/2018 12/5/2018 2/21/2019 5/13/2019 2/27/2020 5/21/2020 11/18/2020 1/25/2021 5/11/2021 8/25/2021 *30 day extension for SAR ** Install MW-24A Monitoring Periods Covered Ql, Q2, Q3, Q4 of 2010, Ql of 2011 Q2 2011 Multiple Q3 2012 Q4 2012 Ql 2013 Q2 2013 Q3 2013 Q3 2014 Ql 2015 Q2 2015 Q3 2015 Q4 2015 Q4 2016 Q4 2017 Q2 2018 Q3 2018 Q4 2018 QI 2019 Q4 2019 Ql 2020 Q3 2020 Q4 2020 QI 2021 Q2 2021 *** No SAR for MW-12 extend casing Table 2.11.2-1 Plan & Time Schedule and Source Assessment Report Status - DWMRCP&TS DWMRCSAR Approval Date SAR Date Approval Date 7/12/2012 10/10/2012 4/25/2013 7/12/2012 10/10/2012 4/25/2013 pH report -11/9/12 Pyrite 7/12/2012 Report -12/7/12 4/25/2013 2/4/2013 5/8/2013 7/23/2013 5/30/2013 8/30/2013 9/17/2013 9/17/2013 12/17/2013 1/7/2014 10/16/2013 1/13/2014 3/10/2014 12/18/2013 3/19/2014 6/5/2014 NO SAR -OOC due to NO SAR -OOC due 1/8/2015 well damage to well damage 8/11/2015 12/9/15* 2/19/2016 11/10/2015 No SAR -install packer NOSAR 2/25/2016 No SAR -install packer NOSAR 4/4/2016 6/24/2016 12/20/2016 5/23/2017 8/20/2017 3/20/2018 3/30/2018 6/25/2018 7/25/2018 10/18/2018 1/16/2019 7/9/2019 3/5/2019 6/27/2019 9/5/2019** 3/5/2019 6/27/2019 9/5/2019 6/26/2019 9/23/2019 11/26/2019 3/26/2020 6/24/2020 8/6/2020 6/22/2020 10/19/20* 1/21/2021 2/1/2021 4/29/2021 7/7/2021 NoSAR NoSAR 6/9/2021 9/7/2021 1/18/2022 9/29/2021 1/28/2022 5/5/2022 Constituents Multiple Multiple pH -multiple wells TDS-MW-29 Se -MW-31 THF-MW-01 Gross Alpha -MW-32 S04 -MW-01, TDS -MW-03A U in MW-28 MW-31 -Se, S04, TDS, pH MW-3-Cd, Zn, Be, Ni MW-3 S04 MW-18 -S04 and MW-24 F, Cd, Tl, and pH MW-31 -Se, S04, U MW-14-F MW-30 -U, Se, pH MW-24 -Tl, Cd, pH MW-11 Manganese MW-25 Cd MW-31 TDS, S04 MW-28 Se, U MW-12-Se, U and MW-31 -U*** MW-26TDS MW-29-U MW-30U,Se Table 2.13.1-1 Drainage Areas of Mill Vicinity and Region Basin Description Draina~e Area sa. miles km2 Corral Creek at confluence with Recapture Creek 5.8 15.0 Westwater Creek at confluence with Cottonwood Wash 26.6 68.8 Cottonwood Wash at USGS Gauge west of project site ::::205 <531 Cottonwood Wash at confluence with San Juan River :::: 332 <860 Recapture Creek at USGS gauge 3.8 9.8 Recapture Creek at confluence with San Juan River ::::200 <518 San Juan River at USGS gauge downstream at Bluff, Utah :::: 23,000 <60,000 Source: Adapted from 1978 ER, Table 2.6-3 Figure No. 1 ....................... . 2 ....................... . 3 ....................... . 4 ....................... . 5 ....................... . 6 ....................... . 7 ....................... . 8 ....................... . 9 ....................... . 10 ....................... . 11 ....................... . INDEX OF FIGURES Description White Mesa Mill Location Map White Mesa Mill Land Map Generalized Stratigraphy of White Mesa Mill Kriged Top of Brushy Basin White Mesa Site Kriged 4th Quarter, 2021 Water Levels Showing Inferred Perched Water Flow Paths Southwest of Tailings Management System Seeps and Springs on USGS Topographic Base White Mesa 4th Quarter, 2021 Depths to Perched Water in Feet, White Mesa Site 4th Quarter, 2021 Perched Zone Saturated Thickness in Feet White Mesa Site Groundwater (Well and Spring) Sampling Stations in the White Mesa Vicinity White Mesa Mill Site Plan Showing Locations of Perched Wells and Piezometers Mill Site Layout 12... .. . . . . . . . . .. .. . . . .... Drainage Map of the Vicinity of the White Mesa Mill 13. . . . . . . . . . . . . . . . . . . . . . .. Streamflow Summary Blanding, UT Vicinity WYOMING UTAH White Mesa Mill Legend * Public Land Ownership White Mesa Mill Private • Town • Village -Highway --Road --··-· -Stream -·-·-·-Intermittent Stream Tribal Land Bureau of Land Management Forest Service State Trust Land 1:300,000 3 1.5 0 MILES N 3 I ~RGYFUELS REVISIONS Project: WHITE MESA MILL Dale: By: county: San Juan State; Utah Location Portions ofT37S R22E S28 Author: a re ither FIGURE 1 WHITE MESA MILL LOCATION MAP Date: 5/20/2014 Drafted By: areither S:\EnvironmentanUliWhlteM_esaMilnGroundwater Discharge Pennlt~enewal Appllcatlon\Ffgures\2022 Renev,al Draft figures\Land0wnershi!l_Map2022 No Lebels,mxd / 6/22/2022 8:04:31 AM by joapp .fD :J' ~ j L < -ff 24 ·-:.... 25 ~ ~ ~ -=>.; C:::. "' r-~ 19 ""'"'"of ... ~ ..... ]= \ 30 ie' .,,,ti ~e" + ,1/, ..... (il:,2~ ++ * • •• ¢ t Lyman \ 21 Lyman • Shumway Flavel I,. ' ·""1~Y.5SS 1-' Meyer (. fNIGtv1, ,..--. 1:.tr.'..c S: + + + ---4 " llf 0 # 9.~ ~g _ Structures Monitoring Locations e Boring • Drinking Water ... MW Chloroform • MW Nitrate • Monitor Well + Piezometer Chloroform • Ute Monitoring Well -Seep or Spring * Air Monitoring Station * Control Point Legend --Canyon Rim Surface Land Ownership -Highway ~ Bureau of Land Management --Road L--1 Private 9:-~~ 81 7/ ,I Coordinate System: NAO 1983 StatePlane Utah South FIPS 4303 Feet 28 .. L- --lb REVISIONS I Project: 15 ~4 Grover Niels·on -------. Grover FROG POND w O! i cf i\ 26 ENTRANCE $PRIii\ 35 I of Land Manag\ment T37S 27 WHITE MESA MILL !I l!Property Boundary~ Mill Site Claim Date: I By: I County: San Juan State: Utah CJ Tailings Cell ISSSI Utah State Lease C=:J Utah Land Trust School Section 1 IN = 3,333 FT CJ Ute Mountain Ute 3,000 1,500 0 • N 3,000 Location: Portions of T37S R22E FIGURE 2 MONITORING LOCATIONS C: 0 "' ai z ~c.;ALE IN FEET ! Author: joapp Date: 6/23/2022 Drafted By: joapp Cl) Cl) w z ~ () I 1- w ~ ~ >< 0 a: a.. a.. <( LO N l 0 lO z . 0 0) 2 . 0 0 n z 0 ({) . 0 U) n z 0 0 2 . 0 0 N z . LO CX) z • -~ t COVERED BY UNCONSOLIDATED ALLUVIUM, COLLUVIUM AND TALUS ~----~--------------- EOLIAN SAND SAND AND SILT, REDDISH BROWN VERY FINE-GRAINED • ~ -o.-. J ~ • ~ •• : == == == == == == = MANCOS SHALE= == = SHALE, LIGHT GRAY, SOFT '"'''"'"'' '' ''' ''' DAKOTA SANDSTONE '" '"" '" '' ,,,,,,,, , , , , , , , · BURRO CANYON FORMATION ,,,,,,, .. ''"'''' ''''"'' -~~~~-------------- BRUSHY BASIN MEMBER ____ ___,_ ------------- WESTWATER CANYON MEMBER RECAPTURE MEMBER ~ SALT WASH MEMBER ~--/~--------------- SUMMERVILLE FORMATION ENTRADA SANDSTONE NAVAJO SANDSTONE z 0 ~ ~ a: 0 LL z 0 Cl) oc a: 0 ~ SANDSTONE, QUAfHZ. LIGHT YELLOW BROWN, POORLY SORTED, IRON CON CREATIONS WELL INDURATED SANDSTONE, QUARTZ. LIGHT GRAY TO LIGHT BROWN, CROSS-BEDDED, CONGLOMERATIC. POORLY SORTED INTERBEDDED WITH GRAY-GREEN SHALE SHALE, GRAY, GRAY-GREEN, AND PURPLE, SILTY IN PART WITH SOME SANDSTONE LENSES SANDSTONE, ARKOSIC, )1:LLOW TO GREENISH GRAY. FINE TO COARSE GRAINED. INTERBEODED WITH GREENISH-GRAY TO REDDlSH-BROWN SHALE SHALE, REDDISH-GRAY SILTY TO SANDY INTERBEDDED IMTH SANDSTONE. ARKOSIC, REDDISH-GRAY, TO YELLOW-BROWN, FINE-TO MEDIUM-GRAINED SANDSTONE, QUARTZ, YELLOWISH-TO REDDISH BROWN, PINE-TO COARSE-GRAINED INTERBEODED WITI·I REDDISH-GRAY SHALE SANDSTONE, RED-BROWN, THIN-BEDDED, WITH RIPPLE MARKS, ARGILLACEOUS WITH SHALE INTERBEDS SANDSTONE, QUARTZ WHITE TO GRAYISH BROWN, MASSIVE, CROSS-BEDDED, FINE-TO MEDIUM-GRAINED SANDSTONE, QUARTZ. LIGHT Yt:LLOWISH-BROWN TO LIGHT-GRAY AND WHITE. MASSIVE, CROSS-BEDDED, FRIABLE, FINE-TO MEDIUM-GRAINED Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO 80228 WHITE MESA MILL Date By County: Son Juan tate: Utah 5-1 4 DLS Location: FIGURE 3 GENERALIZED STRATIGRAPHY OF WHITE MESA MILL ale: N/A Dale: Au • 2009 ralted By' D.Sledd Taken from Stratigraphic Section near Water Well #3 Sira!igraphy.dwg Figure 3 -- ~· , , , , TW443 ~5504 TWN-20 []5546 TW4-42 ¢ 5508 MW-38 "9-5459 MW-5 .5491 TW4-12 kriged top of Brushy Basin elevation contour and label (feet amsl) approximate axis of Brushy Basin paleoridge approximate axis of Brushy Basin paleovalley temporary perched monitoring well installed September, 2021 showing elevation in feet amsl temporary perched nitrate monitoring well installed April, 2021 showing elevation in feet amsl temporary perched monitoring well installed April, 2019 showing elevation in feet amsl perched monitoring well installed February, 2018 showing elevation in feet amsl perched monitoring well showing elevation in feet amsl 0 5521 temporary perched monitoring well showing elevation in feet amsl TWN-7 h d . . . A.5545 temporary perc e nitrate monrtonng -V well showing elevation in feet amsl PIEZ-1 perched piezometer showing Q 5552 elevation in feet amsl (X = abandoned) RUIN SPRING 6 5380 seep or spring showing elevation in feet amsl HYDRO GEO CHEM, INC. APPROVED SJS KRIGED TOP OF BRUSHY BASIN WHITE MESA SITE OATE REFERENCE H :/718000/hydrpt2022/ GWDPrenewal/Ubbel1221_gwdp.srf FIGURE 4 0 0 -- "-.. ssoo -, ·-@ 4th quarter 2021 nitrate plume 4th quarter 2021 chloroform plume potential perched water pathline (assuming hypothetical connection to Cottonwood Seep) 4th quarter 2021 water level contour and label in feet amsl saturated thickness estimated to be less than 5 feet estimated dry area TW4-43 temporary perched monitoring ~5524 well installed September. 2021 showing elevation in feet amsl TWN-20 temporary perched nitrate monitoring []5565 well installed April, 2021showing elevation in feet amsl TW4-42 ¢ 5525 MW-38 ~5463 temporary perched monitoring well installed April, 2019 showing elevation in feet amsl perched monitoring well installed February, 2018 showing elevation in feet amsl M;·:504 perched monitoring well showing elevation in feet amsl TW4-12 d . . II 0 5569 temporary perche monitoring we showing elevation in feet amsl TWN-7 . . . A.5569 temporary perched nitrate monitoring V well showing elevation in feet amsl PIEZ-1 perched piezometer showing ~ 5588 elevation in feet amsl RUIN SPRING b 5380 seep or spring showing elevation in feet amsl NOTES: MW-4, MW-26, TW4-1, TW4-2, TW4-4, TW4-11, TW4-19, TW4-21, TW4-37, TW4-39, TW4-40 and TW4-41 are chloroform pumping wells; TW4-22, lW4-24, TW4-25 and TWN-2 are nitrate pumpin_g wells; TW4-1 , TW4-2 and TW4-11 water levels are below the base of the Burro Canyon Formation HYDRO GEO CHEM, INC. KRIGED 4th QUARTER, 2021 WATER LEVELS SHOWING INFERRED PERCHED WATER FLOW PATHS SOUTHWEST OF TAILINGS MANAGEMENT SYSTEM APPROVED DATE SJS REFERENCE H:/718000/hydrpt2022/ GWDPrenewal/UpathNchl4021_gwdp_r1 .srf FIGURE 5 0 "' S! :> rt (!) N 0 w 0 Cl) Q) 0 E 00 <( "' .... "'m ",;;,... (!) (.) if z-0 -:I:<( a: c.. Cl) .... c.. <( w iD Cl) a: :i: .... !! " cgw ~o z c.. I- <( 0 ~ Cl) I-;;: Cl) c.. Cl) :ti (!) Cl) Cl) => z 0 0 ~ 0 ~ ::c -a: _g C ~ 0 .... ~ .... ~ 0) ~o -g Cl) > "") !? Cl) j u z -"' ~ 0~ ~ ::c <., u ai > .l!! 111 Q) Ill C: 111 Q) E Q) > 0 ..c 111 ti):;:;-c: Q) i~ Cl) C: ... 0 o:;: g-~ Q) .l!! Cl) w a: w ~ ;;: !;; l8 ~;j!j • I V'Jd sg:00: r oroc: 'n ,aqwa1das 'AllP!'=' :pxw·£>c:ooosws1mooos tl\:>t @ estimated dry area ,-, saturated thickness estimated -to be less than 5 feet TW-443 temporary perched monitoring ~73 well installed September, 2021 showing depth to water in feet TWN-20 temporary perched nitrate monitoring []78 well installed April, 2021 showing depth to water in in feet TW4-42 temporary perched monitoring well 9 70 installed April, 2019 showing depth to water in feet MW-38 perched monitoring well -¢-10 installed February, 2018 showing depth to water in feet MW-5 perched monitoring well showing e 108 depth to water in feet TW4-12 0 56 temporary perched monitoring well showing depth to water in feet TWN-7 temporary perched nitrate monitoring ~81 well showing depth to water in feet PIEZ-1 perched piezometer showing g 57 depth to water in feet RUIN SPRING b seep or spring Note: Q4 2021 water levels for TW4-1 , TW4-2 and TW4-11 are below the base of the Burro Canyon Formation HYDRO GEO CHEM,INC. APPROVED 4th QUARTER, 2021 DEPTHS TO PERCHED WATER IN FEET WHITE MESA SITE DATE REFERENCE FIGURE SJS H :/718000/hydrpt202/ GWDPrenewal/Udtw1221_gwdp.srf 7 ® estimated dry area ,-} saturated thickness estimated to be less than 5 feet -, approximate axis of Brushy Basin , paleoridge -, approximate axis of Brushy Basin , -paleovalley TW4-43 temporary perched monitoring ~20 well installed September, 2021 showing thickness in feet TWN-20 temporary perched nitrate monitoring IJ19 well installed April, 2021 showing thickness in feet TW4-42 temporary perched monitoring well ¢ 17 installed April, 2019 showing thickness in feet MW-38 perched monitoring well -<:>-4 installed February, 2018 showing thickness in feet MW-5 perched monitoring well showing e 12 thickness in feet TW4-12 Q 47 temporary perched monitoring well showing thickness in feet TWN-7 temporary perched nitrate monitoring <>24 well showing thickness in feet PIEZ-1 perched piezometer showing ~37 thickness in feet RUIN SPRING c!, seep or spring Note: 04 2021 water levels for TW4-1, TW4-2 and TW4-11 are below the base of the Burro Canyon Formation HYDRO GEO CHEM, INC. APPROVED SJS 4th QUARTER, 2021 PERCHED ZONE SATURATED THICKNESS IN FEET WHITE MESA SITE DATE REFERENCE H:/718000/hydrpt2022/ GWDPrenewal/Usat1221_gwdp.srf FfGURE 8 I ' I >J ,. :' ! " •• ~ -=~-· ---T --------~~ \_ ,~ ! -· ------=--,-~ ~ ... J,'! N I I--l --· 1'----J 1 -r --• _.,._.-._ ' I i ,. -. .t ( l".:. I~( , I . ,:, -I & .... V \ I .,. lfa.ait• , 'I ., j\ !° '-'~ .ri .. ~-··'l# r : ,.. /·· 1 I \ ,.. / •• • , .... L I &.. • t ,· itt , 1 ----~ -i v~/ ;~--- I ~. : , ~ ~,.! I ~\ \ , # \,\ *.-. I • \ =1 -#' i\ , • .,. I ~ I • / .• G1R : ~ ' 1 i ! ,~~l t A ( / I~ : ) : :a••• ••1••1•• •• ••t•• •, '· ..... j.: I ·1' I ; i1 ,, : ( /. / -1 .. r ~: / I y{~£ I I .j. s 1500' 0 1500' I -- 1 -- I I SCALE: 1" = 3,000' 3000,1 I I I --{-----~· tt:t --~-!' .. '~ --------+\-1 : j' ,.,., I (~ I --).·· ta? ;·: ?. ,,, I I ... ... I • ,, I ~ 1 \f!_s 'i •• :. 1 > ~··"'a 1 , 1 ; i lt ~-----, ' \ r ,, I + a !=: l~~, I -1 J <. ., .,,,...... Ir-·· ,J I I! .~ l·, •.. ,,; I ... ._.., \( '/ .. • , ' ., I • -.. ~".. cree,:__/.l , -G2R f " ' ., ,.. • , I -\------ter-:::...---:··· .:..•! ..... \=· :-f \ ! --i I -!ii i_ I " ii ~ ··. sl'l'/ .. ,-,.,..#\ .... ""ti,, -~ '"\ ~..... • "" I /"' ~' : G5R = ! \ .. *'1 I J. , ,.. • ~ • .. I ) • , .... I CJ-. \ i = '-t \;.. 12. : ..... I / •,, % ; \ <"~ 'f> } I ."--4-. • I , ' ! .. ~ , I I .._ A G4R ~ II + II ~ ~ I ~ : I j ? ,. 5 ' • ) ... ,, I yL. I I ... -· I : ~,'\I I -I ---) -:!-·l··J-ri --~----r------.••·-------#~\~ 1 ~ -;----~-1-· ' • -I • I \\\, ~ O .,. I • .. • -#.,._-....-,"" '" ~ "\ ,,# .. , ' \ • t i ~ 1···/i "t .,. ,. , • .... • • \., .:. ., I j • .l-~ ,.,.._,. ) 4-1.-~ \ I\ ~ : I : '-1#1 \,\ i' :\ I '·l ~ • : • ~"#<:e, ·-. ,,. # ( • I • °" ..,,, 'I\__.,, .,., I • • , ) 1 : : ! . \ ··, ( .. ~. .~ , / t --___ J ·,., l. -~:<••1•• ........... ~----. ~ --.. ~ --\ ---,: ~., .. , ! ! ~>-.··1 I ) %. f Ruin Spring • • '-' c ·.. ,.,; l (_/.. ··,··~·-··'; : ; Q 1··, .• ;;,\? ,J ~ I I • I .. • V ., ···~ J ., . -. ..... . , # .. • •••••• I.. ...._:• " \ "'""'-I \ • L_ ... " ' ! .. ! • \ I # "i I ~, \ \ : ; ! i : 1 ,-..,... t .. 1 _ : , i ! : ; ... : \, I ... , -~ ,_.. \ !. l -i ,~ ' • ·~ _.. I. --,--. ------~\ --_, ___ ----! -f -·--.,,v,. • \J ~ • l ~~ ~ I ' ~-_.> : : I \ \! : ~ (···~--= ,.. i ,., . . ' ·--, : ii : I ,.,. ~ i ! ·.. j ~"'tt 0 ~ ... _)_ . -~-+-_; -0 -Jfa ., ••.• . I .. " ~ \ ~ ( l~ J....~ ,,.l ,,, \., # .,,. ,,'I-"'~ ~ .,. .... ~ ' -I -.. ., ~~ ,~. « -r-~ ~ -I #. ; { r··' ~~·· I i \ \ ,.. U TE ~ 0 UN ;fliA IN ., ~·-.... '~ U1 ·-- 'J ~1 ~ ," I L_. .. .. ~I ~ -~r!f!''; __ __.__ *l , ~~ 11 Ii I . ---' ---~--~----·-~ t ,A. G4R GROUNDWATER (WELL OR SPRING) • • •a ,•• • PROPERTY BOUNDARY SAMPLING LOCATION RESERVATION BOUNDARY 5+ WATER SUPPLY WELL -••-••-CANYON RIM Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 500 Lakewood, CO 80228 WHITE MESA MILL Date I By I County: Soo Juon ,ta\e: Utah 5-14 I DLS I Location: Figure 9 Groundwater (Well and Spring) Sampling 1 1 1 Stations in the White Mesa Vicinity S-cale: 1 "=300~Date: Auq, 2009 ] DraftedBy: D.Sledd GW,Sam_011rig W&S dwg Figure 9 TW4-43 temporary perched monitoring well ~ Installed September, 2021 TWN-20 temporary perched nitrate monitoring C well installed April, 2021 MW-24A perched monitoring well installed • December 2019 TW4-42 ¢ temporary perched monitoring well installed April 2019 TW4-40 perched chloroform pumping well EB installed February 2018 TW4-19 perched chloroform or EB nitrate pumping well MW-38 -¢-perched monitoring well installed February 2018 MW-5 • perched monitoring well TW4-12 0 temporary perched monitoring well TWN-7 temporary perched nitrate monitoring <> well PIEZ-1 perched piezometer (,i) RUIN SPRING b seep or spring ~·fll • ~21 HYDRO GEO CHEM,INC. WHITE MESA SITE PLAN SHOWING LOCATIONS OF PERCHED WELLS AND PIEZOMETERS APPROVED DATE REFERENCE H:/718000/hydrpt2022/ GWDPrenewal/Uwelloc0322.srf FIGURE 10 5620 HCL TANKS ~ SUBSTATION Cl D Q wATER TANK cu GRIZZLY 0 OLD DECONTAMINATION ~ PAD MILL o BUILDING o Q PROCESS WATER 0 0 I VPL STORAGE 0 Oa-o· CAUSTIC SODA oo ooQASH ~~ AMMONIA Do c=:!:=L---'--'-'-----=..:; Lldl SALT BOILERS ~ 0 0 0 00 D0°0 D o 0o o ALTERNATE FEED CIRCUIT C DRY REAGENT STORAGE c:=i REAGENT YARD sx BUILDING b Cl Qo KEROSENE 0~ 00 0 • SODIUM CHLORATE X J SHOP 1- 0 o ::> Cl'. 0 <( ~ >- 0.. 0 0 = c L----'-<--1 ---5630- CJ TRUCK SHOP _1[ __ ORE PAD SAMPLE PLANT I D 5646 -6640 ·~~ HOUSE <;>,~ ----_____ __, >-c:: c3 2 ::> 0 co ~ -c:: <( 0 UJ l-o ~ Cf) UJ er \l \ \\f 100 50 ~,gyFue/s REVISIONS Dale By San Juan 10-11 GM 5-14 DLS 4-16 RE 1-22 ss N _,, E , '1 -;- ' s 0 100 200 SCALE IN FEET Energy Fuels Resources (USA) Inc. 225 Union Blvd. Sufte 600 Lakewood, CO 80228 WHITE MESA MILL !ale: Utah Figure 11 MILL SITE LAYOUT ate: May 12, 2000 rafted y: D.Sledd Mill Site Layout 1 5 22 dwg Figure 11 • 1 USGS GAUGE NO. 09376900 e 2 USGS GAUGE NO. 09378630 • 3 USGS GAUGE NO. 09378700 Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO 80228 WHITE MESA MILL Juan ta e: Utah Figure 12 Drainage Map of the Vicinity of the White Mesa Mill 1 :250,000 Dale Au , 2009 Draftea By: D.Sledd Drainage Map.dwg Figure 12 400 I-350 w w u.. w 300 0:: () <( s· 250 0 ...J u.. 200 ~ I I-150 z 0 :!; w 100 c., ii 50 w ~ tu 400 w Ji 350 0:: ~ s 0 ...J u.. ~ ~ z 0 :!; 300 250 200 150 w ~ 100 ~ 50 AVERAGE ANNUAL FLOW=950 AF -(1966-2001) DRAINAGE AREA=3.77 SQ. Ml. AVERAGE ANNUAL YIELD=252.1 AF/SQ. Ml. YIELD-AF/SQ. Ml MIN. AVG. 2,7 252 (1990) JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC MONTH RECAPTURE CREEK NEAR BLANDING USGS GAUGE 09378630 AVERAGE ANNUAL FLOW=7757 AF -(1966-1971) DRAINAGE AREA=4.95 SQ. Ml AVERAGE ANNUAL YIELD=153 AF/SQ. Ml. MAX. 881 (1983) YIELD-AF/SQ. Ml MIN. 46.9 (1971) JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC MONTH SPRING CREEK ABOVE DIVERSIONS, USGS GAUGE 09376900 AVG. 153 1600 tu 1400 w u.. ~ 1200 ~1000 0 ...J u.. 800 ~ I !z 600 0 :!; w 400 ~ w 200 ~ MAX • 262 (1966) AVERAGE ANNUAL FLOW=6547 AF -(1965-1986) DRAINAGE AREA=205 SQ. Ml. AVERAGE ANNUAL YIELD=32 AF/SQ. ML JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC MONTH COTTONWOOD WASH NEAR BLANDING USGS GAUGE 09378700 NOTES 1. FOR THE LOCATION OF WATER COURSES SUMMARIZED, SEE FIGURE 3.7-1 YIELD-AF/SQ. Ml MIN. AVG . 4.9 32 (1976) 2. SOURCE OF DATA. WATER RESOURCES DATA RECORDS. COMPILED AND PUBLISHED BY USGS. MAX • 88 (1983) Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO 80228 WHITE MESA MILL San Juan taie: Utah Figure 13 Streamflow Summary Blanding UT Vicinity N/A Dale: Au • 2009 Dratted By: D.Sledd Streamflow Summary dwg Figure 13 Appendix A .................... . B .................... . C .................... . D .................... . E .................... . F .................... . G .................... . H .................... . I. ..................... . 1 ..................... .. K ..................... . L ...................... . M ....................... . N ..................... .. INDEX OF APPENDICES Description Radioactive Materials License Amendment No. 4: March 31, 2007 White Mesa Mill Site Maps with Well Locations Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill, Revision: 3, November 11, 2019 Results of Soil Analysis at Mill Site Tables: Chemical and Radiological Characteristics of Tailings Solutions, Leak Detection Systems and Slimes Drains Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan 07/11 Revision: Denison 2.3 Stormwater Best Management Practices Plan, Revision 2.1: April 2022 White Mesa Mill Discharge Minimization Technology (DMT) Monitoring Plan, 1/2022, Revision: EFRI 13.0 White Mesa Mill Tailings Management System, 3/2017, Revision: EFR 2.5 Cell 2 Slimes Drain Calculations and Figure 2009-2022 White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) Date 2/15/2022 Revision 7.7 Tailings and Slimes Drain Sampling Program, Revision 3.0, July 8, 2016 Contingency Plan, 12/11 Revision: DUSA-4 White Mesa Mill Containerized Alternate Feedstock Material Storage Procedure, PBL- 19, Revision: 3.0, March 1, 2017 0.. . . . . . . . . . . . . . . . . . . . . . . White Mesa Mill Chemical Inventory Appendix A Radioactive Materials License Amendment No. 4: March 31, 2007 i:t...G.15.1997 1:3::flM l'0.340 P.4 TECHNICAL EVALUATION REPORT REQUEST TO RECEIVE AND PROCESS ALTERNATE FEED MAlERIAL DOCKET NO. 40--8681 LICENSEE: International Uranium (USA) Corporation FACILITY: VVhite Mesa Uranium Mill PROJECT MANAGER: James Park SUMMARY AND CONCLUSIONS: LICENSE NO. SUA-1358 The U.S. Nuclear Regulatory Commission staff has reviewed Energy Fuels Nudear, Inc. 's (EFN's) request dated Apnl s, "i997, ta receive and process uranium-bearing material currently contained at Cabot Perfonnance Materials' (CPM's) facility near Boyertown, Pennsylvania. The material would be processed at the White Mesa mill, of which EFN is the former owner. The current owner of the mill and NRC licensee, International Uranium (USA) Corporation (IUC), previously has agreed to abide by all commitments and representation made _by EFN. Based on its review of the Apnl 3, 1997, submittal and additional information provided by letters dated May 6, May 19, June 20, and August 6, 1997, the NRC staff considers the amendment request acooptable. QESCRIPTION OF LICENSEE'S AMENDMENT REQUEST: By its submittal dated April 3, 1997, EFN requested that NRC Source Material License SUA-1358 be amended to allow receipt and processing of alternate feed material (i.e., material other than natural uranium ore) at its White Mesa uranium mill located near Blanding, Utah. This uranium-bearing material, weighing approximately 16,000 dry tons, is held currently by CPM at its facility near Boyertown, Pennsylvania. The material is a moist solid (up to 40 percent moisture content) which contains uranium at an average concentration of 0.3 percent by weight, and ~r..onomically attractive concentrations of tantalum and niobium. CPM is authorized to possess this material under NRC Source Material License SMB-920. The material will be shipped by train and exclusive-use trucks from CPM's facility to the White Mesa mill in intennodal containers. After being loaded and sealed at CPM's facility, the containers will be transpcrted by truck to a nearby inteimodal rail terminal. The containers will be loaded on flatbed railcani and transported cross--cauntry to the final ran destination (either Grand Junction, Colorado or Green River, Utah), where they will be transferred to trucks far the final leg of the journey to the White Mesa mill. Each ccntainer ha5 a capacity of 25 cubic yards, and it is expected that approximately 15 containers will be loaded and transported each day. At the mill site, the uranium-bearing material will be emptied from the intermodal containers into the ore receiving hopper. From there, the material will be processed through the semi- autogenous grind (SAG) mill, where water will be added to create a sluny, which is then 1 f'.l,.G.15.1997 t:34A'1 l'().340 P.S pumped to~ pulp storage tank and from there into the leach circuit. ln the leach circuit, the slurry will be treated to separate the uranium from the tantalum and niobium, and rue wm utilize the uranium and vanadium solvent extraction circuits, respectively, to recover these metals. IUC plans to add two filter presses and some additional piping to itS mill circuit to aid in the processing of this material. Water spray systems will be utilized to reduce the potential for dust dispersion and airborne contamination in emptying the intermodal containers. Other than the slight circuit changes mentioned previously, IUC anticipates that processing the uranium-bearing material will not differ from processing natural uranium/vanadium ores. rue will provide personal protective equipment (coveralls, gloves, and full-face respirators (to be used if needed)) to indiViduars engaged in process( ng the material. The efficiency of airborne contamination control measures durfng the material handling operations will be assessed in the immediate vicinity of these operations. Airborne particulate samples and breathing zone samples will be collected during initial material processing activities and analyzed for gross alpha. Sampling results will be used to establish health and safety guidelines to be implemented throughout the processing operations. Additional environmental air samples will be collected at nearby locations to the material processing activities and analyzed to ensure that the established contamination control measures are adequate and effective. Trucks used to transport the material to the mill site will be radiometrically scanned upon arriVal to ensure that leakage has not occurred and that radiation levels are_ within appropriate limits. TruckS will again be scanned prior to their release from the site restrlct&d area. In addition, the intermodal containers used to transport the material will be property closed, cleaned (if necessary), surveyed, and documented before leaving the site. TECHNICAL EVALUATION: The NRC staff has revfewad IUC's request In accordance with 10 CFR Part 40, Appendix A. requirement& and NRC staff guidance "Final Position and Guidance on the Use ot·uranium MIii Feed Material Other Toan ~miral Ores" (60 FR 49296; September 22, 1995). This guidance (referred to hereinafter as the alternate feed guidance) requires that: the staff make the following detenninationa in its reviews of ffcensee requests to precess material other than natural uranium ores. 1. Whettler the faed material meets the definition of "ore;" 2. VVhether the feed matelial contains hazardous waste: and ,.... 3. Whether tne ore is being processed primarily for its source-material content. 2 ~.15.1997 1=34A1 -l'fJ. 340 P. 6 netecmioation ar whether the feed material ;s ·ore· FOT the tailings and wastes from the proposed processing ta qualify as 11 e.(2) byproduct material, the feed material must qualify as "are.• In the aJtemate feed guidance, ore IS defined as " ... a natural or native matter that may be n,ined and treated for the extraction of any of its constituents or any other matter from which source material is extracted in a licensed uranium or thorium mill." The proposed allemate feed material contains uranium at an average concentration of 0.3 percent by weight; therefore, it meets the definition of •source materia~" as defined at 1 o CFR 40.4. IUC Is proposing to extract this uranium. Therefore, the material meets the definition of ore, because it is a· "matter from which source materiaJ Is extracted In a llcensed uranium or thorium mill." Determination of whether the feed material contains hazardous,waste Under the alternate feed guidance, proposed feed material whiCh contains a listed hazardous waste will not be approved by the NRC staff for processing at a licensed min. Feeq materials which exhibit only a characteristic of hazardous waste o.e., lgnltabilJty, corrcslvity, reactivity, er toxicity) would not be regulated as hazardous waste and could therefore be approved by the staff for recycling and extraction of source material. However, this does not apply to residues from water treatment. Therefore, NRC staff acceptance of aud1 residue& as feed material would depend on their not containing any hazardous or Characteristic hazardous waste. The NRC staff has reviewed the fallowing sources of information In determining whether the uranium-bearing material is or contains hazardous waste: (1) the average composition data for the material, as submitted by IUC on June 20, 1997, (2) the results of additional testing, as provided by letter dated May 6, 1997, (3) NRC flies far the Boyertown facility, which address, in part, the pracas used to produae the material and the methOds used to store the materfal, and (4) supplementary information concerning the State of Pennsylvania Department of Environmental Protection's hazardous waste regulations. In addition, as an attachment to a letter dated August 6, 1997, IUC provided an anadavit from CPM in which CPM afflnned that the material is ~ot and does not contain hazardous waste. Based on its revtew, U\e NRC staff finds that the uranium-bearing material la not hazardous waste and does not contai'I hazardous waste. The NRC staff has determined alao that the uranium-beartng ma18rial is nat a residue from water natl 1.ent. Thia material is the result of the initial processing of raw ares containing tantalum and niobium. Therefore, the NRC staff considers the uranium-bearing material acceptable for recycling and extraction of source material 3 ~.15.1997 1:35PM l'().340 P.7 - Detennioattea ot whether v,e feed material is being processed primarily toe its soy,:ce--material con1ent To show that potential alternate feec1 material is being processed primarily for its source- material content, a licensee must either (1) demonstrate that U,e material would be approved for disposal In the tailings impcundment under the "Final Revised Guidance on Disposal of Non- Atomic Energy Act of 1954, Section 11e.(2) Byproduct ~aterial In Tailings Impoundments;" or (2) certify, under oath or affirmation, that the material is being processed primarily for the recovery af uranium and for no other primary purpose. Any such certification must be supported by an appropriate justification and accompanying dOaJmentation. The licensee has provided a signed affirmation that the uranium-bearing material is being processed primarily for the recovery of uranium and tor no other primary purpose. IUC states that the uranium content of the material, in canjunction with the reduced uranium processing costs associated with the recovery of the tantalum and niobium, makes processing the CPM material economically attractive to IUC. The NRC staff has discussed with IUC the business arrangements regarding the material and finds that IUC is paying CPM for the acquisition of the material. The NRC staff has reviewed the ana&ytical data provided by IUC and infcrmation contained In the NRC's flies for the CPM facility, and finds that the uraniUm concentration in the material is comparable With that in natural uranium ores whld'I are and were normally processed by uranium mills in the U.S.. These natural ores contained uranium at concentrations of 0.3 percent and below. Therefore, the NRC staff considers IUC'a juatitication to be acceptable. Conclusions concemina alternate feed matenal designation Based on the information provided by the licen&ee, the NRC staff finds that tha CPM's uranium- bearing material is altemate feed material because: (1) It meets the definition of "ore," (2) It does not contain hazardous waste, and (3) it Is being processed primarily for its source-material content Other considerations The NRC staff has also concluded that the processing of this material wtl not result In (1) a significant change or increase in the types or amounts of effluents that may be released offsite; (2) a significant incn!ase In individual or cumulative occupational radiation exposure; (3) a significant construction impact; or (4) a significant increase In the potential for or consequences from radiological accidents. This ccndusion Is based on the following Information: a. YeUowcake produced from the processing of this matertal wlll not cause the currantJy- approved yeOowcake production limit of 4380 tons per year to be exceeded. In addition, and as a result, radiological doeea to members of the public in the vicinity af the mill will not be elevated above levels previously assessed and approved. 4 ~.15.1997 1:35PM -l'0.340 P.8 b. The-physicar changes to the miU circuit that IUC will implement to process this materiaJ are not significant No construction impacts beyond those previously assessed will be involved with these changes. c. Tailings produced by the processing of this material will be disposed of on-site In an existing llned tailings impoundment (Cell 3). The addition af these tailings (a maximum of 16,000 tons) to Cell 3 wm increase the tCJb!l' amount of tailings in the cell by one percent. to a total of approximately 69 percent of cell capacity; therefore, na new impoundments are necessary. The design of the uisting impoundments previously has been approved by the NRC, and IUC is required by ils NRC 6cense to conduct regular monitoring of the impoundment liners and of the groundwater around the Impoundments to detect leakage if it should occur. d. The uranium-bearing material contains metals and other parameters which already are present in the mill taiDngs disposed of in the Cell 3 impoundment. Analysis of samples from the uranium-bearing material and from Cell 3 show that the only.~ 1:11,neters present in signific;antly higher concentrations in the uranium-bearing material are fluorine and carbon. HC7N9V8r, these concentrc•J.-, ... should not have an acfvenla Impact an the overall Cell 3 tafflngs c:ompositian, because the amount of tail!!1gs (a maximum of 16,000 tons) produced by processing u,e material is not significant in comparison to the total amount of tailings currently in the cell (approximately 1.4 mDlion tans). AdditfonaJIJ, as stated previously, IUC is required to conduct regular manitaring cf the impoundment leak detection systems and of the groundwater in the vieinity of the impoundments to detect leakage tr it ahaulc:f occur. e. For the following reasons, it is not expected that transportation impact& associated with the movement of the material by train and buck fn>m Pennsylvania to the White Mesa mill will be significant • The material will be shipped as ·row specific aetivity" material in exclusive-use containers (I.e., no other materials wlll be In the containers with the uranium- bearing material). The containers will be appropriately labeled, placarded, and manifested, and shipments will be tracked by the shipping company from CPM's facility until they reach the White Masa mm. • On average during 1996, 370 trucks per day traveled the sb etch of State Road 191 between Monticello, UT and Blanding, UT (personal communication with the State d Utah Department of Transportation). An additional 15 true.ks per day travelng this room to the mill represents an inaeased traffic load of only four percent. Shipnenta are expected to take place over the course of a limited time penod (three to soc months). • The cantainens end trucks involved in transporting the material to the mm site will be surveyed and decontaminated, as necessary, prior to leaving CPM's facility far Whlta Meaa and again prior to leaving the mm site for the return bip. 5 ~.15.1997 1:36PM f'(),340 P.9 f. MIii-empioyees lnvclved in handling the material wiD be prwided with personal protective equipment. induding respiratory protection. AJrbome particulate and breathing zone sampling result& wm be used to establish health and safety guideHnes to be implemented throughout the precessing operations. RECOMMENDED LICENSE CHANGE: Pursuant to Trtle 1 O of the Code of Fede~I Regulations, Part 40, Source Material Ucense SUA-1358 will be amended by the addition of Ucense Condition No. 10.9 as follows: 10.9 The licensee is authorized to receive and prt1cess source material from Cabot Perfonnance Materials' facility near Boyertown, Pennsylvania, in accordance with the amendment request dated April 3, 1997, as amended by submittals dated May 19, and August 6, 1997. ENVIRONMENTAL :;.n?ACT EVALUATION: Because IUC's receipt and processing of the 'T11lterial will not result in (1) a significant change or increas9 in the types or amounts of effluents that may be released offilite; (2) a significant increase in indiVidual or cumulative occupational radiation exposure; (3) a significant construdion impact; er (4) a significant increase In the patential for or consequences from radiological accidents, an environmental review was not performed since actions meeting theS8 critaria are categorically exduded under 10 CFR 51.22(c)(11). 6 ii ii: WW 'liihihitii jniiili Ww: WW j\'i I U.S. NUCLEAR REGULATORY COIDl1SSION MATERIALS UCENSE f'0.340 P.10 ···--····-·--Sllil PAGE 1 OF • 8 -~es Pw"Suaat to tbe Atomic Eneru Jr.a. ·oe J9S4, as amcuded, the El1eT8Y Reorpuiz&ti01t Aci of 1974 (Public Law 93-438), and Title 10, Code of Federal Rcgvtauom, Chaptu I. P:im :30, 3 J. 32. 33. 34, 35. 36. 39, 40, and 70. and in tcliatiCe on sraterneun md repRKnwions hctetofcfc made by the licc11See. a license i.J hereby iuued wcbonzing the licensee to receive, acquire, possess. and tnns&r byproduct. source, and special nuclear material designated below; to use JUGh mmterial for tbe pw'!)C)Se(I) and at the place(s) desipatad below; to deliver or trllllfer such matmial to pcrsom aulborized to re<:cive il in acconlance with tile regulations of the applicable Part(s). This li=mc shall be deemed to contain the conditions specified in Section 183 of the Atomic Ensgy Act of 1954, u amended, and ii .liDbject to all appliculc rul~. regulations, and orden of the Nuclear Regula.tor, Commiuion now or hereafter in effect and t0 any condiciom specified below. l. 2. Licensee International Uranium (USA) corporation [Applicable Amendments: 2] 6425 S. HighWay 191 P.O. Box809 Blanding, utah 84511 3. License Number s. Docul<* .. ·· Rcfemu:e No. 6. Byproduct, Source, .md/or Special Nuclear Material 7. Chemical and/or P11y,,.....;. . Form . 8. MaxirnnrnAmountthatLicemec May Posscas at.Any One Tune ' Uuda' 'lb.is UCCDSC . . Natural Uranium Any SECTION 9: Administrative Conditions 9.1 The authorized place of use shall be the licensee's VVh1ta Mesa ~ium mil6ng facility, located in San Juan County, Utah. · 9.2 All written notice9 and reports to the NRC required Ul'lder this license, with the exception of incident and event notifications under 10 CFR 20.2202 and 10 CFR 40.60 requiring telephone notfflcation, shall be addressed to the 01ief, Uranium Recovery Brandl, Division of Waste Management, Office of Nuclear Material safety and Safeguards. Incident and event notifications that require telephone notification shaU be made to the NRC Operations Canter at (301) 816-6100. 9.3 The licensee shall conduct operations in accordance with statements, representations, and conditions contained in the license renewal applicatJon submitted by letter dated August 23, 1991, as revised by submittals dated J~nuary 13, and April 7, 1992, November 22, 1994, July 27, 1996, December 13, and December 31, 1998, and Janumy 30, 1997, whieh are hereby Incorporated by reference, and for the standby Trust Agreement, dated April 29, 1997, except whera super&eded by license conditions below. 9.4 VVhenever the wcrd "wilr is used in 1ha above referenced documents, it shall denote a requirement [Applicable Amendments: 2) A. The licensee may, Mthout prior NRC approval, and subject to the conditions specified in Part B of thi$ conaltion: (1) Make changes in the fadfity or process, as presented in the application. l'O. 340 P.11 i::t..)'.;. 15.1937 1: 37A'1 ,. •wwawawww+wwwwww U.S. NUCt.EAR REGULATORY COMIIISSION Jll'Gf OF 8 f'll.GES I':.-,.,....~ ,-n.,""""'N,..,..umtl-=-IG'-----=--------'---- -MATERIALS LICENSE SUPPLEMENTARY SHEET SlJA..1 August 15, 1997 (2) Make changes in the procedures presented in the application. (3) Conduct tests or experiments not presented in the application. 8. Toe ricensee shall file an application fer an amendment to the license, unless the following conditions are satisfied. (1) The change, t~t, or experiment does not conflict 'Nith any requiroment specifically stated in this license, or impair the licensee's ability ta meet au applicable NRC regulations. (2) There ~ r,o degfadatiot1h ~-£~,;~ or environmental corrmlltments in the licen~pplit!ation, or provided by~ ipen:>ved reclamation plan . • , 'l ...,..,v. ~'. • ::> • ·~'/ ), (3) The c.[taage, test, or experiment is consistent wftn\ie conclusions of actions anatymd and selected in the i:A dated Febru1uy @. 11 • .... -,,: • •,1 ' • -... ,, • c. The li~1s 'd~enrunations concerning Part B ,of1ft~l'fditior'I, shall be made by a "Safety and Envi~htal Review Panel (SeRffl'· ·nie seRJ,1ihall co~ist of a minimum of thl'H inanriduals, One .member'of,Vte;..SERP shalU•ve expertise in management and ~ l'!l&ponsibre-for~al and financfal approval changesj one member shall have ~11iS, in operatjo~~or con~n and shall have respqosibility f\lr ffflP,lementing,a...y ~,1Jat;'cbanges; and, Or:J,~ member shall be the ~rate radia,ian ~·.bffic?.ar iCR~) ~-~•lent. with ~ ,:esponsfbifrty of ass~ng chana.,,confoan ~ rad~.IJ ,~ty . .and ~ufrements. . Additional members may be Jnduded 111 .the SERP8$:appropria'.ltt, to address technical aspects.such u .._ ~st~ •. grt,u~ar hy~. su,fa~ water hydrology, spacifi~,,arth ~c:Hi and alb.et techn~J~~nes. T~~rary members or permanent ~bets, other thari 'the three ~~s~J~'IViduats, may be consuharits. · . 4 ,,. ,, •:,,. ·:.I' • , • • • \ ... • ·'.J .o,Q\'('\:., I&,, •. •• :, • ~ I J •• ... ,1 D. The ficensee~ll maintain records of any chang~·:Uiacfa pursuant ta th: ... condition until license terrnl~~n. These records s~~ fI,cluVll!Witten safety and environmental evaluations, made byj\at SERP, that ~e basis for detennining changes are in compliance with the rvquintRM1nlB.(Bf~ to'ln Part B of this concfltion. The licensee shall fumlsh. in an aMual repor( to NRC, a descriptian of such changes, tests, or experiments. Including a summary Of the safety and environmental evaluation of eadl. In addition, the licensee shall annually submit to the NRC changed pages to the Operations Plan and Reclamation Plan of the approved license application to reflect changes made under this condition. Toe licensee's SERP shaH function in accordance with the standard operating procedures submittad by letter dated June 10, 1997. [Applicable Amendments: 3) 9.5 9.6 •stwwvww•.,.,WWWWWWP M•-~-e~1~•••w1 _ .... NUCLEAA REGULATOfn' COMMSSION MATERIALS LICENSE SUPPLEMENTARY SHEET OF Au ust 15 1997 The licensee shall maintain an NRC-approved flnandal surety arrangament. consistent with 10 CFR 40, AppendiX A, Criteria 9 and 1 o, adequate to caver the estimated costs, if accomplished by a thjnj party, fer decommissioning and decontamination of the mm and mm site, fer redamation of any tailings er waste dispesal areas, grcund-wata-restoration as warranted and for the long-term surveilJance fee. Within three months cf NRC approval of a revised redamation/dec:a 1 ,l'ti5sloning plan, the licensee shall submit, fOf' NRC reYiew and approval, a proposed revision tc the financial surety arrangement if estimated costs In the newly approved plan exceed the amount covered in the existing financial surety. The revised surety shall ttlen be In effect within 3 months of 'Mitten NRC approval. Annual updates to the surety~mou~~~O.CFR40, AppencflXA, Criteria 9 and 10, shall be submitted to tne NRC:~sf 3 mo~-in*,r>.Jha anniversary date which is designated as June 4 {If~ year. If the NRC has not'l.ae~ved a proposed revision to the surety eoverage 3Q~~-prior to the expiration date of the lixi~ surety arrangement, the licensee shall ~.oa"1he existing surety arrangement for 1 ~~,Along wi1h each proposed revision or annL1a11pdate1 the licensee shall submit supporting' .d~mentation showing a breakdown o~tl:)e costs-and the basis far the cost estimat~ttrfid)JStments for inflation, maintenan~ ·or-a minttn&Jm;;l5 percent contrngency f~~ iitf!tiglneering plans, activitieS pei1bnned and'.IIJ'1y'· other conditions ~nsf.. , mated costs fOf' site closure. Toe basis for th• a:ist estimate' is~ "NRC ~d.rilcl~nldeccmmi!isioning plan or NRC approved revisions to th~_plan.-rllle preYiow.ly P.ro~idance e~ •Recommended Outline for 'Stta Spedflc ~on ar:1(1 SJablllzaUoll Cost Esti~ .butllnes the minimum considerations used·ay..the ~t t,:.·~e revtew~~~~U~1estimat!,~·. Reclamatio~eco~~ioningp~ ~9-~~r:U~es Should foll~\this outline. • •• ' -I • • I I • .. • 4 • .. :. • The currentty.approvecfsuraty l~nt;: F'arfonnan~:B9ffll·1e-2~:,. issued by National Union Fire lnmh:ance ~11Y Jn t'awor .of the tq~~ ~~~ ~ Standby Trust Agreement. dated Apnl 29, '1997·, 'ittafl .be conttrl~&·mainta!M,d,~ an amount not less than $11,278, 1_34 for the purp~ of con,plyii,g ~-;JD CFR 40{Mf>endbc A, Criteria 9 and 10, until a raplaC&rTW1nt Is authorized by the NRC. '· · , ·~.: • · •••• ... 1 ··1, .• ' J,. ·~:1 [Applicable Amendr,181'1•: 2, 3] l·~ ,, f \ 11 .. ~ • ·.""". Standard operating proceddi'ei shall tt,e·e~ti,~wid followed far an operationai process activities involving radioactive matariabHhat l!ne handled, processed, or stored. SOPs for operatiaMI activities shaD enumerate pertinent radiation safety practices to be followed. AdditionalJy, written procedures Shau be established tor non-operational activities to Include in,,plant and environmental monitoring, bioassay analyses, and instrument calibratians. An up-to-date copy of each 'Mittan procedure shall ba kept in the mill af'!'8 to 'M'lic:h it appfies. AD written procedures for both operational and non-.operatianal activities shall be reviewed and approved in writing by the radiation safety officer (RSO) before implementation and whenever a chang~ in procedure is prgposed to ensure that proper radiation protection principles are being applied. In addition, the RSO shall perfonn a documented review of all existing operating procaduru at least annually. 9. 7 Before engaging in any aetiVity not pruviously assessed by the NRC, the licensee shall adrrinister a cultural resource inventory. All disturbances associated with the proposed development will be completed in compliance with the National Histcric PreseNaticn Ad (as /:l.G.15.1997 1:~ I'(), 340 P.13 NRC FOAM 374A (7-841 U.S. NUQ.~R REGULATOOY COfiNSSIOH 1 -.MATERIALS LICENSE SUPPLEMENTARY SHEET Au ust 15 1997 amended) and its implementing regulations (36 CFR 800), and the An:haeological Resources Proteotion Act (as amended) and Its Implementing regulations (43 CFR n. In order to ensure that no unapproved disturbance of cultural resources occurs, any work resulting in the discovery of preViously unknOYffl cultural artifacts shan cease. Toe artifacts shaD be inventoried and evaluated in accordance with 36 CFR Part 800, and no disturbance shall occur until the licensee has received authorization from Iha NRC to proceed. The licensee shall avoid by project design, where feasible, the archeological sites designated "contributing" in the report submitted by letter dated July 28, 1988. VVhen it is not feasible to avoid a site designated "conttjb~n~fn ttW>1-P<}i:tttf)e licensee shall institute a data recovery program for that site based Q~l>tt)&'nlsean:h ~~-~~by letter from C. E. Baker of Energy Fuels Nuclear ju' M_r;:.Metvin T. Smith, Utah ~ t-!~aric Preservation Officer (SHPO), dated April-::13";,1981. .. \·~ •·. ' ":"\ •' . ~"' ··:-,,.."'~: • V ,,..,., The licensee shG\.t~er through archeological excavation al~,!?')tributing" sites listed in the report whid'I are-located in or within 100 feet of borrow ~ile areas, construction areas, a~~~i:iJ'ne1er of the reclaimed ~l,ings "impo6'~dmenl Data recovery fieldwork at -.c11 site n-.eting·1hese criteria shaU beda,nplltted prfor u, the start of any project rel~ed. disturbance within 100 feet of the sft~ ~-analysis a'.fld.report preparation need not be c:omplete. · : . : :.·.:~ .'. ·::.:.'. I u • I , l I Additionally, the Ileen~ shst\:~~uct·S\Jcta..testing··~-~ required to:eiiable U,e Commission to detennina if those. ~ites desigr:t~ .~.:U!1~~~h~" in ,the repo5$11d located Within 100 feet cf'f)resent D~~.OYffl futl!re·~·8f88S ar.e:of ~ch sfQ,:ilflcance to warrant their redesig~tJon as~l'.itributing,11 In· ~'l'~tlS; ·such 1~ shall ~'completed before any aspect of th._.undertakinQ.'"1fects. ~.~~-: 1 ~ ; • , :;. f ' · ~~" • ' • • •• ... I -~ ,/. • .I t !1-:. ,.._. :••-..__ ••• ,/ ~~ \ ,;:, '•w Art:heolcgfcal~tradoNi sh~ll-be ~~ved.1~ ~~i)t the Cqni"vis1on. Toe commission wm approve an iar,:tteotogical con11'atjorwba. ~~ minl~'jtandan:Ss for a principal investigator set f'oF1n' ln 38 CFR Part.~ Appendix C1'"and ~quaUrications are found acceptable by the Gii~-~~ ~ ' 9.8 The licensee is hereby ~o ~e~~uct material in the form of uranium waste taDings and other uran(um&;prdJRict-. fanandad by the licensee's mflling operations authorized by this license. Mill tailings shall nat be tran.sfem=d fn:Jm the site witho&rt specific pnor approval or ttte NRC in the form Of a license amendment. The licensee shall maintain a pennanent record of aJI transfers made under the provisions of this condition. 9.9 The lfcensee is hell!lby exempted from the requirements of Section 20.1902 (e) of 10 CFR Part 20 for areas within the mill, provided that all entrances to the mill are conspicuously posted in accordance with Section 20.1902 (e) and with the words, "Any area within this mill may contain radioactive material.• 9.1 O Release of equipment or packages from the restricted area shall be in accordance with "Guidelines for Decontamination of Facilities and Equipment Pr1or to Release far Unrestricted Use or Termination of Licenses for Byproduct, Sourte, or Special Nuclear Materiel," dated May 1987, or suitable alternative praceduru apprcvad by the NRC prior to any such release. !'.L(;.15.1997 1:39A1 I'(). 340 P.14 NRCFORM~4A (7-MJ u.S. NUCLEAR REGULATORY CO ... SSION -MATERIALS LICENSE SUPPLEMENTARY SHEET . • •• . •. .• • ••. :.. . : -=~: ··: '•. ... • •. .. OF 1--Utei---.-Nlll'llbcr.....,.. ____ ___...._ _____ _ Au ust 15 199 ---------------------"---~==....!!!,l!:...L....;~:.L__------ SECTION 10: Operational Controls, Limits, and Restrictions 10. 1 The mill production rate shall not exceed ~O tons of yefiowcake per year. 10.2 All Hquid effluents from mill p~ buildings, with the exception of sanitary wastes, shall be retlffled to the mill circuit or discharged to the tailings impoundment. 10.3 Freeboard rrmits for Cells 1-f, 3, and 4A. and tonnage limits for Cell 3, shan be as stated in Section 3.0 ta Appendix E af the approved ncense application. 10.4 Disposal of material and equipmenmen(~~--*e mm sfte shall be conducted as descn~ed in ~e licensee~ ~~ls'.lcfat'ed ~ ~' 1994 and May 23, 1 ~. with the following addition: . ~,,.., , .. ,. · J ;,• 11, ... "C.o ,f I • :-.:., '"\-1 '.) A. The maximurh:,flft thickness for matP.rials placed over'tai\iogs shall be less than 4--feet thick. Su~uent lifts .shell be less than 2-feet thick. ~ Rft shall be compacted by traekins;~ ~Y)f. equipment, such as a cat D-6, at I~~ prior to placement of subsequent lifts.. .. ' ,• ·' (,-. • 1 , (_ •, 1 ~. ~' • ,•~~t•,.,. '~ I :.J~~ 10.5 In acc:on:ta~··with the 11<:ahsee's submittal dated~;20; 1993. the-iicensee is hereby authorized lo:dispase of by~uct ~I genende(f af·licensed irt"Si\U leach facilities, b·ect to ...... ._ foUowi . ~ . J .. \ • • ..... SU ~ uiw ng ~U}J&unt: . . ·, ,· :r~ ; :,,-> ' ••• (I • • ~ • ,.. • I •• ' •, I •• t ... • %: ... t. ... t ,;a..~,. A. Oisp~I of ~is n~~ ~1<=,!-l~I ~~.~~-~ ~ngle «,4rce. • ,. ,• • I t 1 • 0 • '' • ""'-r• B. All CQf1tP.fflinatliMf ~~wpment.s~all ~ dj~ed. ~. or ~oned to rnlnimize void spaces. 8~~-~ntaininQ<~ affler tha:soit or sludges shaU be emptied Into t~e cf~aJ areajlind-the,bari'ets'~:~~-contain.~soil or sludges shall be verified ~.be fiJII prior to dispoRil. ~n:els J1att;Ctnp1etelv,:fijtshall be fiUed with tailings or soil '! ;, . ,,-,}f' -. --... ~1".~ • • f I : f..,•{.i. ~ .. -c .• ,. • 'J J "!L~ ,:. C. All waste shati.~;buried in cen No. 3 unless prior~ approval IS obtained frt.,n tha NRC for attamatB bu~ locations. '-< \ "I, ..J. ,).. ~-"' >., '\ ·~"' o. All disposal ac:tiVitieS shan.f:>e..,do~~. The documentation shall incfude desctiptions of the waste and the disposal locations, as weH as an actions required by this concfdlon. An annual SU1T1T1ary of the amounts of waste disposed of from off..site generators shall be sent to the NRC. 10.6 The licensee is authorized lo receive and process source materials from the Alliad Signal Corporation's MetropoliS, Illinois, facility in accordance with the amendment request dated June 15, 1993. 10. 7 The licensee is authorized to receive and process source material from Allied Signal, Inc. of MetJ:opolis, Illinois, in accordance with the amendment requ,st dated September 20, 1996, and amended by letters dated October 30, and November 11, 199& . . 10.B The licensee is aU1harized to racaive and process source material, in accordance with the amendment request dated March 5, 1997. [Applicable Amendments: 1] .15 .1997 t:39flM ~.340 P.15 · · •••wwwww••••••+• ,· ·•www *****wwww1 MAl'ERIAI.S UCENSE · --SUPPLEIIENTAR't SHEET Au ust 15 1997 10. 9 The licensee is authorized to receive and proce~~ source material from ca bot Perfom,ance Materials' facility near Boyertown, Pennsylvania, in accordance with the amendment request dated April 3, 1997, as amended by submittals dated May 19, and August 6, 1997. [Applicable Amendments: 4] SECTION 1t: Monitoring, Recording, and Bookkeeping Requirements 11.1 The results of sampling, analyses, surveys and monHoring, the results of calibration of equipment, reports on audits ~~.i~;:i=tings and training courses required by this license and any su~~ews.-'lnv .... ~·n!.11..and carrective actions, sMall be documented. Unless Qfl,enivise specified in the NR~~lations all such documentation shall be maintaine~ 1q;'1t1period of at least five (5) years. ~-; \ . . · ':·~ ~~.~ .... ~ 11.2 The llcensae s~~pfement the effluent and environmental mo.ilitoring program specified in Section 5.S of (be ·rel)ewal application as revised with the followinef#lodifications or additions: ; . . . , . . •' ,. .,,, • , .... I '•, "' •' ·.'• '·~ A. stack: sampling shall inau.de a detarmlnation.af'.trow tale. • , • • • • I ',.•"' • .Y\ ' ' ~ " '. 8. SL1rface water samJlles S,,aO al&~ t,e analyzed .leriiannualfy fot,'\t)tal and dissolved U- nat, Ra-226. and Th-2301 with the ex~ptico Qf..jt,e. Westwater~ek, which shall be sampled annually for'W&ter sedimehfs· and .~lilYZed as above. :~sediment sample shaH not be taken In place i:Jf a wat~ s,anyp11!'-'u!11ess. a water s~ple was not available. I t fl .. i, I ~ ~ f • "• I f • .. ' ., C. Groundwater sa~Ung shaJIJ:ie can'ductedin aCCQfJia'r¢e ~1, requirements In License Condition 1,1.3. . '; ,. .: ·' ·:\. '.. ·<·, • • ' N •• ,'l I : ••• •• •• '•;i :" ,,IP ... ,. D. The licensee sha1l·u1111ze 1owe·r: Omits of ctetdftn acco~ with Section 5 of ' Regulatory.~uide 4.14 (Revislaf'.11), for an~ of efflu~nd environmental samples. , .""-'t.1 > • Y,j j . -. ·~ ):._.)I E. The inspections·perfo[!Red semiannually af tti~ ~ orifice assembly committed to in the subrntttaJ dated M~ 'Uiir.1 ~" spll{l ~-~mented. The critfc:al orifice assembly shall be calibratf!Ct~t 1$51 ew,y 2 ·years against a posttiw displacement Roots meter ta obtain the raqUirad calibration curve. 11.3 The licensee shall implement a groundwater detection monitoring program to ensure campHance ta 10 CFR Part 40, Appendix A. The detection monitoring program shall be In accordance with the report entitled, "Points of Compliance, VVhite Mesa Uranium Mill," submitted by letter dated October 5, 1994, as modified by the following: A. The leak detection system for all pond& wm be checked weekly. If liquid is present, it shall be analyzed for chloride, sulfate, selenium. and pH. The samples will be statistically analyzed tc determine if significant linear trends exist, and the results will be submitted to NRC far review. ,. 11.4 11.5 11.6 l'().340 P.16 --,wwwwwswwww-••••-,™"~«~-~-~-~-~-~-~-~-~-~-~-~- u.S. NUCLEAJII REGULATOflY COIMSSION __ MATER.IALS UCENSE ·suPPLEMENTARY SH!ET OF August 15, 1997 B. If a significant linear trend is indica1ed, the licensee will submit a proposed corrective action for review and approvaJ to NRC Toe corrective action shall indude a discussion on delineation of the areal extent and concentration of hazardous constituents. C. The licensee shall sample monitoring wells WMMW-5, -11, -12, -14, -15, and -17, on a quarterly basis. Samples shall be analyzed for chloride. potassium, nickel, and uranium, and the results of such sampling shall be induded with the environmental monitoring reports submitted in accordance with 1 o CFR 40.65. During extended periods of mill standby, eight-hour anm.1al sampling for U-nat, Ra-226, To- 230 and Pb-210 may be eHmi[lated'lifro~A'e.iirt,oe,e sampling show levef5 below 10 percent of the appropriate 1 O CF~ ~~-~tiimits. · ·~ .\.! t ::' _., .. ,f .. > • , ~.-!• • -.·~ •• ~I During periods of s~_Cfb'y, sampling frf'""''~"!cies for area an;bo.q,e uranium sampling withJ,, the mill may be ~ to quarterty, provided measull!d levels remain below 1 o percent of the derived air d>l'.ltentration (DAC). If these levels exceed 10 "n:ent of the DAC, the sampling traquency should follow the recommendations in R,.m,il&U!J;Y Guide· 8.30 . • • :.) •• , • • •• _.,.. J • ; calibration crf ii;,-plant air and radiation monitoring eq(if p~m shall be'periormed as specified In the license renewal ap~ic.ation, unde:rs~on 3:o .cf;-tt;\e "Radlatfon~l?,rotectlon Procedures Manual," with-the exception 1hm i~lantair sampl~llipment sha)I ~ calibrated at least quarterty amt air sampling equipment c;hecks shall ~·-a~mented. (. • • ' ' .l • ' I • : <,\. , t ,, • The licensee-shall perfonn an annual Al.ARA au'diNSf-tha radlation sa~ program in accordance-'\Mth R~latory Guide 8,31,' ·1 ; •• :· 1 • • • ' • '. .. '.. • • • + I • •1,,. ,' ••,I .... .. ....;,, SECTION 12: Reporting Requirements t····· ..• f) ~ '; ~-~·· 12.1 ,t • • • .-• •• ~ ,,. - The licensee shaJl-~ubmft to NRC fQr. review,. l?Y Jut,J . .30, 1997.~atalled reciamation plan for the authorized tflllings disposal area vmf~ includes the ~l'IDwind: A. A post-operati~~ inte('im stabirization plan which J~i;: methods to prevent wind and water erosion and red\ttge 4f_ U,"~ili~~ ., ... ._j ~' ~,.~ 8. A plan to determine the best methodology to dewater and/or consolidate the tailings cells prior to placement of the final reclamation cover. C. Plan and aass-sectianal views af a final l'l!clamation cover which details the location and elevation af tailings. The plan shaU include details en cover thickness, physical charaderistics of cover materials, proposed testing of cover materials (specifications and quality assurance), the estimated volumes of cover materials and their avanability and location. D. Detailed plans for placement of rock or vegetative cover on the final reclaimed tamngs pile and mill site areL E. A proposed implementation schedule for items A through D above which defines the sequence of events and expected time ranges. 12.2 MATERIALS UCENSE -SUPPLEMENTARY SHEET August 15, 1997 F. An analysis to show that the proposed type and thickness of soil cover is adequate to provide attenuation of radon and is adequate to assure long-term stability, as wetl as an analysis and proposal on methodology and time required to res1ore ground water In conf crmance to regulatory requirements. G. The licensee shall include a detailed cost analysis of each phase of the reclamation plan to include c:ontractor costs, projected costs of inflation based upon the schedule proposed in item E, a proposed contingency cost, and the costs of long-term maintenance and monitoring. ~.15.199'7 1:3::FM l'0.340 P.4 TECHNICAL EVALUATION REPORT REQUEST TO RECEIVE AND PROCESS AL TERNA TE FEED MATERIAL DOCKET NO. :4(H681 UCENSEE: International Uranium (USA} Corporation FACILl1Y: White Mesa Uranium Mill PROJECT MANAGER: James Park SUMMARY AND CONCLUSIONS: LICENSE NO. SUA-1358 The U.S. Nuclear Regulatory Commission staff has reviewed Energy Fuels Nuclear, Inc. 's (EFN's) request dated Apnl s, ·i997, to receive and process uranium-bearing material currently contained at Cabot Perfcnnance Materials' (CPM's) facility near Boyertown, Pennsylvania. The material would be processed at the White Mesa mill, of which EFN Is the former owner. Toe current cwner of the mill and NRC licensee, International Uranium (USA) Corporation (IUC), previously has agreed to abide by all commitments and representation made _t;,y EFN. Based on its review of the Apnl 3, 1997, submittal and additional information provided by lett~ dated May 6, May 19, June 20, and August 6, 1997, the NRC staff considers the amendment request acceptable. DESCRIPTION OF LICENSEE'S AMENDMENT REQUEST: By its submittal dated April 3, 1997, EFN requested that NRC Source Material License SUA-1358 be amended to allow receipt and processing of alternate feed material (i.e., material other than natural uranium ore) at Its White Mesa uranium mill located near Blanding, Utah. This uranium-bearing material, weighing approximately 18,000 dry tone, is held currently by CPM at its facility near Boyertown, Pennsylvania. The material is a moist solid (up to 40 percent moisture content) which contains uranium at an average concentration of 0.3 percent by weight, and pr.,onamic:ally attractive cancentraticns cf tantalum and niobium. CPM is authorized to possess this material under NRC Source Material License SMB-920. The material will be shipped by train and exclusive-use trucks fron-1 CPM's facility to the White Mesa mill in intennodal cantainens. After being loaded and sealed at CPM's facility, the containers will be transported by tnJck to a nearby intermodal rail terminal. The containers will be loaded on flatbed railan and transported c:ros&-Q)Untry to the final ran destination (either Grand Junction, Colorado or Green River, Utah), where they will be transferred tc trucks for the final leg of the journey· to the VVhite Mesa mill. Each amtainer has a capacity of 25 cubic yards, and it is exr:,ected U,at approximately 15 containers will be loaded and transported each day. At the mill site, the uranium-bearing material will be emptied from the intermodal containers into the are recefving hopper. From there, the material will be processed through the seml- autagenous grind (SAG) mill, whera water will be added to create a sluny, which is then 1 ~.15.1997 1:34A'1 l'().340 P.5 pumped to.a pulp storage tank and from there into the leach circuit. In the leach circuit, the slurry will be treated to separate the uranium frotn the tantalum and niobium, and IUC will ublize the uranium and vanadium solvent extraction circuits, respectively, to recover these metals. IUC plans to add two filter presses and some additional piping to its mill circuit to aid in the processing cf this material. Water spray systems will be utilized to reduce the potential for dust dispersion and airborne contamination in emptying the intennodal containers. Other than the slight circuit changes mentioned previously, IUC anticipates that processing the uranium-bearing material will not differ from processing natural uranium/vanadium ores. rue wm provide personal protec.1ive equipment (coveraffs, gloves, and full-face respirators (to be used if needed)) to individuals engaged in processing the material. The efficiency of airborne contamination control measures during the material handling operations will be assessed in the immediate vicinity of these operations. Airborne particulate samples and breathing zone samptes will be ccllected during initial material processing activities and analyzed for gross alpha. Samping results will be used to establish health and safety guidelines to be Implemented throughout the processing operations. Additional environmental air sample& will be collected at nearby locations to the material precessing activities and analyzed to ensure that the established contamination control measures arw adequate and effective. Trucks used to transport the material to the mill site will be radiometricaUy scanned upon arrival to ensure that leakage has not occurred and that radiation levels are_ within appropriate limits. Trucks will again be scanned prior to their release from the site restricted area. In addition, the intermadal containers used to transport the material will be proper1y closed, cleaned (if necessary), surveyed, and documented before leaving the site. TECHNICAL EVALUATION: The NRC staff has rev1ewad IUC'a request In accordance With 10 CFR Part 40, Appendix A. requirements and NRC staff guidance "Final Position and Guidance on the Use of Uranium Mill Feed Material Other Than M9tural Ores" (60 FR 49296; September 22, 1995). This guidance (refened to hereinafter as the alternate feed guidance) requires that the staff make the following determinations in its reviews of licensee requests to prac:ess material other than natural uranium ores. 1. Whether the feed material meets the definition of "ore;" 2. VVhether the feed material contains hazardous waste; and ·-3. Whether tne ore is being processed primarily fer its source-material content. 2 . _, A...X;.15.1997 1: 34A1 I'(). 340 P. 6 oetermjnation Qf whether the feed material i!i ·m· For the tailings and wastes from the propased processing to qualify as 11 e.(2) byproduct material. the feed material must qualify as "ore.• In the alternate feed guidance, ere IS defined as " ... a naturat or native matter that may be rr,ined and treated for the extraction of any of its constituents or any other matter from which source material is extracted in a licensed uranium or thorium miR.11 The proposed alternate feed material contains uranium at an average concentration of 0.3 percent by weight therefore, it meets the definition at "source materta~" as defined at 1 o CFR 40.4. IUC is proposing to extract this uranium. Therefore, the material meets the definition of ore, because it is a "matter from whldi source material Is extracted In a llcensed uranium or thorium mm.• Determinaticn of whether the feed material contains b!zaedous.waste Under the alternate feed guidance, proposed feed material which contains a fisted hazardous waste wm not be apprcved by the NRC staff for processing at a licensed min. Feed materials which exhibit only a characteristic of hazardous waste (I.e., lgnitabillty, corroaivlty, reactivity, or toxicity) would not be regulated as hazardous waste and could therefore be approved by the staff for recycling and extradion of source material. However, this does not apply to residues from water treatment. Therefore, NRC staff acceptance of audi residues as feed material would depend on their not containing any hazardous or Characteristie hazardous waste. The NRC staff has reviewed the following sources of information in detennining whether the uranium-bearing material is ar contains hazardous waste: (1) the average composition data for the material, as submitted by IUC on June 20, 1997, (2) the resultB of additional testing, as provided by letter dated May 6, 1997, (3) NRC files fer the Boyertown fadlity, which address, in part. the pracega used to produce the material and the methOds used to store the material, and (4) supplementary information concerning the State of Pennsytvanla Department af Environmental Protection's hazardous waste regulations. In addition, as an attachment to a letter dated August 6, 1997, IL.JC provided an anadavit from CPM in which CPM affirmed that the material Is r:iot and does not contain hazardous waste. Based on its revieW, tne NRC staff finds that the uranium-bearing material is not hazardous waste and does not contain hazardous waste. The NRC staff has determined al&a that the uranium-bearing material is nat a residue from water nab I tent. Thia material is the result of the initial processing of raw ores containing tantalum and niobium. Therefore, the NRC staff considers the uranium-bearing material acceptable for recycling and extraction of source material. 3 Ft.JG.15.1997 1:35R1 l'«J.340 P.7 - DeterroioiU,eo ot whett)er tf)e feed material is being mocesseg primari!y for rts source-material content To show that potential alternate feet1 material is being processed primarily for ilB source- material content, a licensee must either (1) demonstrate that U,e material would be approved for disposal in the tailings impoundment under the 11Final Revised Guidance on Disposal Of Nan- Atomic Energy Act of 1954, Section 11e.(2) Byprodud ~aterial in Tailings Impoundments;" or (2) certify, under oath or affirmation, that the material is being processed primarily for the recovery of uranium and for no other primary purpose. Any such certification must be supported by an appropriate justification and accompanying dOaJmentation. The licensee has provided a signed affirmation that the uranium-bearing material is being pracessed primarily for the recovery of uranium and tor no other primary purpose. IUC states that the uranium content of the material, in canjunction with the reduced uranium processing costs associated with the recovery of the tantalum and niobium, makes processing the CPM material economically attractive to IUC. The NRC staff has discussed with IUC the business arrangements regarding the material and finds that IUC is paying CPM for the acquisition of the materiaJ. The NRC staff has reviewed the analytical data provided by IUC and infcnnation contained in the NRC's flies for the CPM facility, and fincta that the uraniUm concentration in the material is comparable With that in natural uranium ores Whfd'I are and were normally processed by uranium mills in the U.S.. These natural om contained uranium at concentrations of 0.3 percent and below. Therefore, the NRC staff considers IUC'a justiffcation to be acceptable. Conclusjons concerning alternate feed material designation Based on the information provided by Uie licerwee, the NRC staff finds that tha CPM's uranium- bearing material is alternate feed material because: (1) it meets the definition of "are," (2) It does not contain hazardous waste, and (3) it Is being processed primarily for its source-material content Other cposeiderationa The NRC staff has also concluded that the processing of this material wll not result In (1) a significant change or Increase In the types or amounts of effluents that may be released offsite; (2) a significant incntase in individual or cumulative occupational radiation exposure; (3) a significant construction impact; or(~) a significant increase in the potential for or consequerices from radiological accidents. This concfusion fs based on the fallowing infonnation: a. YeUowcake produced from the processing of this matarfaf will not cause the aurantty- approved yeOowcake production limit of 4380 tons per year to be exceeded. In addition, and aa a result. radiological doeu ta members of the public in the vicinity Df the mill will not be elevated above levels previously assessed and approved. 4 r:tJ;.15.1997 1:35PM l'Cl.340 P.8 b. Thei,hysicaf changes to the miU circuit that IUC will implement to process this material are not significant No cons1ruction impacts beyond those previously assessed will be involVed with these changes. c. Tailings produced by the precessing af this material wlU be disposed of on-site In an existing lined tailings impoundment (Cell 3). The addition of these tailings (a maximum of 18,000 tonsj to Cell 3 wm increase the tctP' amount of tailings in the cell by one percent. to a total of approximately 69 percent of cell capacity; therefore, no new impoundments are necessary. The design of the existing impoundments previously has been approved by the NRC, and IUC iS required by its NRC license to conduct regular manitaring of the impoundment liners and of the groundwater around the impoundments to detect leakage if it should occur. d. The uranium-bearing material contains metals and other parameters which already are present in the mill taiHngs disposed of in the Cell 3 impoundment. Analysis of samples from the uranium-bearing material and from Cell 3 show that the only.~ 1:1.neters present in significantly higher concentrations in the uranium-bearing material are fluorine and carbon. However, these concentrG •!,.. .... should not hava an advenla impact on the overall Cell 3 taffings composition, because the amount of tail!!'lgs (a maximum of 16,000 tons) produced by processing the material is not significant in comparison to the total amount of tailings currently in the cell (approximately 1.4 mDlion tons). Additionally:, as stated previously, IUC is required ID canduct regular monitoring of the impaundment leak detection systems and of the grounc:fwater in the vicinity of the impoundments to detect leakage if it should occur. e. For the following reasons, it is not expected that transpartation impacts associated with the movement of the material by train and buck from Pennsylvania to the White Mesa mill will be significant • The material will be shipped as "low specific activity" materiaJ in exclusive-use containers (i.e., no other materials will be In the containers with the uranium- bearing materfal). The containers will be appropriately labeled, placarded, and manifested, and shipment& will be tracked by the shipping a>mpany from CPM's facility until they reach the VVhite Mesa mill. • On average during 1996, 370 b'ucks per day traveled the stretch of State Road 191 between Monticello, UT and Blanding, UT (personal communication with the State rA Utah Department of Transportation). An additional 15 trucks per day traveling this route to the mill represents an inaeased b'afflc load of only four percent Shipmenta are expected to take place over the course of a limited time period (three to soc months). • The containers and trucks involved in transporting the material to the mnl site will be swvayad and decontaminated, as necessary, prior to leaving CPM's facility for 'White Mesa and again prior to leaving the mm site for the retum trip. 5 ~.15.1997 1:36A'! l'l>.340 P.9 f. MH~ployees invafved In handling the material wil be prwfded with personal protective equipment. including respiratory protactfon. Alrbome partictJlate and breathing zone sampling results wm be used to establish health and safety guideHnes 1D be implemented throughout the processing operations. RECOMMENDED LICENSE CHANGE: Pursuant to Trtle 1 O of the Code of Federal Regulations, Part 40, Source Material License SUA-1358 will be amended by the addition of License Condition No. 10.9 as fellows: 10.9 The licensee la authorized to receive and precess source material fn::lm Cabot Perfonnance Materials' facility near Boyertown, Pennsylvania. in accordance with the amendment request dated April 3, 1997, as amended by submittals dated May 19, and August 6, 1997. ENVIRONMENTAL ;;.i?ACT EVALUATION: Because IUC's receipt and processing of the '11flterial will not result in (1) a significant change or increas~ in the typea or amounts of effluents that may be released offi!rite; (2) a Bignificant increase in individual or cumulative occupational radiation exposure; (3) a significant construdion Impact; er (4) a significant increase in the potential for ar consequences from radiological accidents, an environmental review was not performed since actions meeting theS8 criteria are categorically exduded under 10 CFR 51.22(c)(11). 6 Appendix B White Mesa Mill Site Maps with Well Locations . -~ -. . r , MW•23 ESTWATER~ MW-21 DR-14 16 ..., C!'l. T ~ Shumway ~ :E J ~ l\i1EMEB:S-1 CJ) Fla~el z- ' I -.. .. ' ' . ::--.. . -· ~ -. 2,1 Ly,malil MW-18 TWN-06 \ • MW-34 MW-37 MW-14 , 't' MW-15 t MW-25 DR-12 \ \ MW-17 DR-13 t PIEZ-05 PIEZ-04 DR-16 \ BHV-4 \._ MW-03 DR-5--t? • MW-20 \ MW-39--¢ TW4-40 MW-38 c -3 ~ Nle.y,e.r ~ 15 Gr:oter Gr.OMer 14 Nielso.n 22 Grover ---------=---234..--..----~;;........;.i CORRAL CANYON TW4-38 BHV-5 TW4-13 TW4-11 TW4-02 s::: 0 .!!l. .!!! z Legend --Canyon Rim Surface Land Ownership -Highway CJ Bureau of Land Management --Road D Private U l!Property Boundary ~ Mill Site Claim D Tailings Cell ~ Utah State Lease CJ Utah Land Trust School Sectic 3,000 ~ Structures Monitoring Locations • Boring ~ Drinking Water ~ MW Chloroform • MW Nitrate t Monitor Well 0 Piezometer Chloroform Ute Monitoring Well 0v Seep or Spring * Air Monitoring Station * Control Point Coordinate System: NAO 1983 StatePlane Utah South FIPS 4303 Feet 1,500 1 IN = 2,000 FT 0 SCALE IN FEET 3,000 Dale: By: Counly:San Juan Location: Portions of T37S R22E Author:joapp Appendix B-1 White Mesa Mill (North) Date: 6/21/2022 Drafted By: joapp N I DR-17_....._ _ __,'tr' ~B,,,2(:) DR-19 --,,..- MW-38 MW-39 '-....__/--~4 \ MW-22 Bareau of Land Management 17 ... :d _1 {. Ti lJ I ,I .. .. '" .I -· ·, 11 • - Legend Surface Land Ownership __ Canyon Rim ent CJ Bureau of Land Managem -Highway CJ Utah Land Trust School Sectic --Road 11 · Ut L.._J Ute Mountain e II II Property Boundary 3,000 Structures Monitoring Locations • • 0v * * Boring Drinking Water MW Chloroform MW Nitrate Monitor Well Piezometer Chloroform Ute Monitoring Well Seep or Spring Air Monitoring Station Control Point . t · NAO 1983 Coordinate Sys em. th FIPS 4303 Feet StatePlane Utah Sou 1 IN = 2,000 FT 1,500 0 3,000 SCALE IN FEET '(/!£,RGYFUELS REVISIONS Pr ·ect _wttfil ME.C:A_Mll.l OJ 1s1a1a: Utah Date: By: Counly:San Juan Location:Portions of T37S R22E Append ix B-2 White Mesa Mill (South) Aulhor:joapp J Date: 6/21/2022 J Drafted By: joapp Appendix C Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill, Revision: 3, November 11, 2019 White Mesa Uranium Mill SAMPLING AND ANALYSIS PLAN FOR SEEPS AND SPRINGS Revision 2 State of Utah Groundwater Discharge Permit No. UGW370004 Prepared by: Energy Fue)s Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, CO 80228 JuJy 8, 2016 Table of Contents 1.0 Introduction and Objectives ................................................................................................................... 3 2.0 Seeps and Springs Sampling Locations ................................................................................................... 3 2.1 Timing of Sample Collection ............................................................................................................... 3 3.0 Field Sampling Procedures ...................................................................................................................... 4 3.1 Field Data ........................................................................... -................................................................. 5 3.3 Field QC ............................................................................................................................................... 5 3.4 Sample Handling ................................................................................................................................. 6 4.0 QA and Data Evaluation .......................................................................................................................... 6 5.0 Laboratory Analysis ................................................................................................................................. 6 5.1 Analytical Quality Control ............................................................................................................. 7 5.2 Evaluation of Analytical Data .............................................................................................................. 7 6.0 Reporting ........................................................................................................................................... 7 Attachments Tab A Seeps and Springs Location Map Tab B Bureau of Land Management Letter Tab C Field Data Form Tables Table 1 Seeps and Springs Survey Information 1.0 Introduction and Objectives This Sampling and Analysis Plan ("SAP") describes the procedures for sampling seeps and springs in the vicinity of the Energy Fuels Resources (USA) Inc. ("EFRI") White Mesa Uranium Mill ("the Mill") in Blanding, Utah as required by the State of Utah Groundwater Discharge Permit ("GWDP") No. UGW370004. The objective of the seeps and springs sampling program is to collect annual surface water samples from the locations identified below as required by the GWDP. This SAP specifies the sample collection requirements, procedures, analytical methodologies and associated quality control ("QC") checks, sample handling protocols and reporting requirements for the annual seeps and springs sampling program. 2.0 Seeps and Springs Sampling Locations The annual seeps and springs sampling locations correspond with those seeps and springs sampled for the initial site characterization performed for the Environmental Assessment as shown on Plate 2.6-10 of the Environmental Report (Dames & Moore, 1978), and additional sites located by EFRI, the Bureau of Land Management ("BLM") and Ute Mountain Tribal representatives. The locations included in the annual seeps and springs sampling event are: • Cottonwood Seep • Westwater Seep • Ruin Spring • Corral Canyon Seep • Entrance Spring • Corral Springs The Permit Section I.F.7 (g) requires that survey data for the seeps and springs be submitted prior to the collection of samples. The Division of Waste Management and Radiation Control ("DWMRC") previously clarified the requirement to submit survey data only prior to the first sampling and not on an annual basis. The survey data submitted with the first annual seeps and springs report in 2009 was incorrect. In response to the incorrect data, EFRI completed another survey of the seeps and springs in December 2009. Those survey data are included in Table 1 of this SAP and the locations are shown on Figure 1 included in Tab A. The surveyed coordinates and elevations of the seeps and springs were within 1 foot of the highest point of the saturated seepage face on the day of the survey 2.1 Timing of Sample CoJJection EFRI representatives conducted reconnaissance visits to the locations listed in Section 2.0 above in June 2008 in order to determine the status of the listed springs and seeps and to evaluate the feasibility of physical development with hand tools in order to better accommodate sampling at dry locations. It was observed at that time that water flow was available for sampling at Ruin Spring, Cottonwood Seep and Entrance Spring. Alternatively, Westwater Seep, Corral Canyon Seep and Corral Springs were entirely dry or exhibited only barely moist soil. Annual sampling events conducted from 2009 through 2016 noted that dry conditions continued at Westwater Seep, Corral Canyon Seep and Corral Springs with no opportunity for sampling even with limited hand tool development. Based on the data collected to date regarding the conditions at the six locations specified in Section 2.0 above, the following schedule for site visits and possible sampling will be employed: • Once per calendar quarter, the Westwater Seep, Corral Canyon Seep and Corral Springs will be visited. If sufficient water is present, a sample will be collected and no further visits will be completed for the year. If no sample is collected prior to the annual event, these locations will be visited during the annual sampling event. If these locations are dry during the annual sampling event, the calendar quarter checks will continue until either a sample is collected or 4 quarterly checks (one per calendar quarter) have been completed. NOTE: The annual report is due December 1 of each year. The fourth quarter check will be limited to October and November to meet the report deadline. • Annually, between May 1 and July 15 of each year, a sample will be collected from Ruin Spring, Cottonwood Seep and Entrance Spring. Should any of these locations be dry during the annual event, quarterly checks (for the remaining calendar quarter) will be completed starting after the annual event. Should a visit reveal a change in conditions at any of these dry locations which may yield water sampling opportunities, EFRI will proceed with limited hand tool excavation of the sampling location. The hand- dug excavation will be left open for a maximum of 48 hours and allowed to fill with water. If water collects in the excavation, it will be sampled. If the location is excavated with hand tools, it will be filled after sampling has been completed, with the soil that was removed from it per the BLM request included in Tab B. EFRI will provide at least 15 days notice of the annual sampling event conducted between May 1 and July 15 in order to allow DWMRC to collect split water quality samples of the seeps and springs. 3.0 Fie)d Sampling Procedures The field sampling and data collection program will obtain samples to be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP. Analyses will be completed by a State of Utah certified laboratory using the methods specified in the currently approved EFRI Quality Assurance Plan for Groundwater sampling ("QAP"). Minimum detection limits or reporting limits for seeps and springs analyses will be less than or equal to the Groundwater Quality Standards defined in Table 2 of the GWDP. The minimum detection limits for total dissolved solids ("TDS"), sulfate, and chloride will be 10 mg/L, 1 mg/L, and 1 mg/L respectively. Field activities include collecting samples, recording of field data and field parameters, and preparing and shipping samples to the analytical laboratory. Sampling procedures employed at each location will be dependent on the site location and access. Several sampling methodologies may be employed during one annual event based on access limitations and flow rates of the seeps and springs that are sampled. Potential sampling methodologies are briefly described below. Direct Collection Direct collection of the samples involves collecting the sample directly into the sample container from the surface water feature or from spring out-flow. In instances where direct collection is employed the parameters which require filtration will be collected by one of two methods. In the first method, the peristaltic pump will be used to draw the sample from the out-flow and pump it through a 0.45 micron filter directly into the appropriate sample container. The second method is used in situations with limited access for the generator required to run the peristaltic pump. When the generator cannot be used, a large, unused sample jug will be used to collect the sample. The peristaltic pump will then be used to transfer the sample from the large sample jug to the sample bottles through a 0.45 micron filter. This filtration and pumping will be completed at a location where there is access for the generator. Peristaltic Pump Sample collection with a peristaltic pump involves collecting the sample from the source or out-flow using the peristaltic pump. The peristaltic pump is used to deliver the sample from the source or out-flow to the sample bottles. Filtered parameters are pumped through a 0.45 micron filter prior to delivery to the sample bottle. Sample Ladle Sample collection using a ladle involves dipping or filling a ladle made from an inert material into the surface water source or out-flow and filling the ladle. The sample is transferred from the ladle to the sample bottles. This process is repeated until the sample bottles are filled. Filtered parameters are collected into a large, unused sample jug. The peristaltic pump is then used to transfer the sample from the large sample jug to the sample bottles through a 0.45 micron filter. 3.1 Field Data In addition to the analytical parameters noted above, field data will be recorded at the time of sample collection. Field parameters required by the GWDP include pH, specific conductance and temperature. Additional field parameters such as oxidation reduction potential ("REDOX") and turbidity may be measured as available sample volume allows. Field data will be recorded on the Field Data Record included in Tab C of this SAP. The dates of the site visits, the availability of surface water for sampling, and the possibility for development will be recorded on the field data sheets for inclusion in the annual report. 3.2 Decontamination Decontamination of sampling equipment will be completed if non-dedicated and/or non-disposable sampling equipment is used to collect samples. Decontamination procedures will be as described in the approved QAP. Rinsate blanks will be collected daily after decontamination of sampling equipment. If disposable or dedicated sampling equipment is used to collect samples then rinsate blanks will not be collected. 3.3 Field QC The field QC samples generated during the annual seeps and springs sampling event will include sample duplicates, trip blanks, and rinsate blank samples as appropriate. Sample Duplicate Sample duplicates will be collected at a frequency of one duplicate per 20 field samples. Sample duplicates will be collected by filling the sample container for a certain analytical parameter for the duplicate immediately following the collection of the parent sample for that parameter. Trip Blanks Trip blank samples will be included in every shipment of samples that has field samples to be analyzed for Volatile Organic Compounds ("VOCs"). Trip blank samples are VOC sample containers filled by the analytical laboratory with laboratory grade deionized water and shipped to the site. Trip blank samples are taken into the field with the sample containers, never opened, and kept with the field samples from collection through shipment to the analytical laboratory for analysis. Trip blanks are analyzed to determine if the sample concentration of VOCs have been effected by the "trip" from collection through shipment. Rin ale Blru1k Samples Rinsate blank samples are collected at a frequency of one per day when non-disposable, non-dedicated, reusable sampling equipment is used to collect samples. If the sampling equipment has a disposable component that comes in contact with the samples and the component is changed prior to sampling at each location then a rinsate blank sample will not be collected. For example, if a peristaltic pump is used to collect and filter seeps and springs samples and the tubing used in the peristaltic is changed at each location and never reused for more than one sample, no rinsate blank sample would be required. 3.4 Sample Handling Seeps and springs sampling events will be subject to the applicable sample handling requirements noted in the approved QAP. 4.0 QA and Data Evaluation The Permit requires that the annual seeps and springs sampling program be conducted in compliance with the requirements specified in the Mill's approved QAP, the approved SAP and the Permit itself. To meet this requirement, the data validation for the seeps and springs sampling program will utilize the requirements outlined in the QAP, the Permit and the approved SAP as applicable. The Mill QA Manager will perform a QA/QC review to confirm compliance of the monitoring program with requirements of the Permit, QAP and SAP. As required in the QAP, data QA includes preparation and analysis of field QC samples, review of field procedures, an analyte completeness review, and quality control review of laboratory data methods and data. The QAP and the Permit identify the data validation steps and data quality control checks required for the seeps and springs monitoring program. Consistent with these requirements, the Mill QA Manager will performed the following evaluations: a field data QA/QC evaluation, a receipt temperature check, a holding time check, an analytical method check, a reporting limit check, a trip blank check, a QA/QC evaluation of sample duplicates, a gross alpha counting error evaluation and a review of each laboratory's reported QA/QC information. The corrective action procedures described in the approved QAP will be followed as necessary when data validation and QC reviews indicate a non-compliant situation. 5.0 Laboratory Analysis Samples will be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP using the analytical methods and specified reporting limits contained in the approved QAP. Laboratories used for the seeps and springs sampling program will be Utah certified as required by the GWDP Part l.E.6 (c). Laboratory data will be validated as described in the approved QAP and as described in Section 4.0 above. Analytical QC is described below. 5.1 Analytical Quality Control Analytical QC samples and protocols are described in the approved QAP. Laboratory QC procedures will meet, at a minimum, the requirements set forth in the analytical methods that the laboratory is certified for by the State of Utah. The analytical QC samples included at least the following: a method blank, a laboratory control spike ("LCS"), a matrix spike ("MS") and a matrix spike duplicate ("MSD"), or the equivalent, where applicable. It should be noted that: • Laboratory fortified blanks are equivalent to LCSs. • Laboratory reagent blanks are equivalent to method blanks. • Post digestion spikes are equivalent to MSs. • Post digestion spike duplicates are equivalent to MSDs. • For method E900. l, used to determine gross alpha, a sample duplicate was used instead of a MSD. All qualifiers, and the corresponding explanations reported in the QA/QC Summary Reports for any of the analytical QC samples for any of the analytical methods will be reviewed by the Mill QA Manager. The effect on data usability will be discussed in the evaluation section of the annual report. 5.2 Evaluation of Analytical Data An evaluation of the analytical data will be completed in the annual report. A discussion of the results will be included which will summarize the data relative to any detections reported in the samples with comparisons as appropriate to the Mill groundwater quality data. 6.0 Reporting EFRI will collect seeps and springs samples annually as required by the GWDP Part 1.F.7. Each report will: 1) document the sampling event by means of providing the field sheets recorded at the time of sampling; 2) transmit copies of all field measurements and laboratory results; 3) provide a water table contour map that includes water table elevation of all groundwater monitoring wells at the facility and the elevations of the phreatic surfaces observed at each of the seeps and springs sampled; and 4) provide an evaluation and interpretation of the groundwater quality data collected. Specific reporting requirements for the seeps and springs sampling program will include but are not limited to : • The annual seeps and springs monitoring report will be included with the 3rd quarter Routine Groundwater Monitoring Report due on December 1, of each year. • The seeps and springs water table contour map will include all water level data measurements from all monitoring wells at the site from the 3rd quarter groundwater monitoring event for each year. • The seeps and springs water table contour map shall be at the map scale such that all seeps and springs listed in this Plan and monitor wells at the site may be seen on one map. Table 1 s eeps an ,prmgs urvey n orma ion d S S I f f December 2009 Survey Location Latitude (N) Longitude (W) Elevation FROG POND 37°33'03.5358" 109°29'04.9552" 5589.56 CORRAL CANYON 37°33'07.1392" 109°29' l 2.3907" 5623.97 ENTRANCE SPRING 37°32'01.6487" 109°29'33.7005" 5559.71 CORRAL SPRINGS 37°29'37.9192" 109°29'35.8201" 5383.35 RUIN SPRING 37°30'06.0448" 109°3 l '23.4300" 5380.03 COTTONWOOD 37°31 '21. 7002" 109°32'14.7923" 5234.33 WESTWATER 37°3 l '58.5020" 109°31 '25.7345" 5468.23 Verification Survey July 2010 RUIN SPRING 37°30'06.0456" 109°31 '23.4181" 5380.01 COTTONWOOD 37°3 l '21.6987" 109°32' l 4.7927" 5234.27 WESTWATER 37°31 '58.5013" 109°31 '25.7357" 5468.32 Attachment A ~ : 0 :IE Cl ., C ~ u ..9 I C .: ... U) .... C a .. a. .. .. U) .,. Jo .., ~ 3 II\ 0 ~ .. :IE C .. 7i .3 .. .. C a ~ .., C i : ,.. I fil ~{ .. !. ~ ':. '"" 7 ,,-, ' 0 ,, .,;\'- •• ' D • 1' V' ~,: . . . • ... ,, .. _, .• . . . . .,, . ~ ," ,. . -. . ' . • .--. "'~-. -• I • 1· "'~~ . 'r/J,'! .-.- ._'# rfJ ~\ ~- .. a /l;:ai I\ I " • \ : , , 19 '' .\' I · ' · --20 • [l • • ~ I ! ~ _' . l! :: \ .--.. '·" :· I' • , "' I ~I :· • I a {J : ~,' '• ~o t ' •J . .. I 23 24 "' /\ 25 I \.,_i ..... 16 21 15 I t • ' I ____ ,. ---~ ---------/_,,.. I I I if'y I " l l SMo I • :..•• ........... 1 •• , ........... ------' qLv.1""' I I -·----1 - MW-1 + MW-18 28 + A27 14 23 l 6 '··, ........ , •• '"'", '· 3 ~ 30 j ' • cc' .. : \ . - I ' I~ • • • ·~ ..... , ..... --... cie*-__ /._Seep__~ 1: :.\ t' ~ W ... *5-r; '\ .. ; \ 26 .,,., '' ~-:: ~·-I : --t, ;: 35 2 11 14 23 26 . • I ... ., ,36 .. .. :-, ... -' • ' , .. • ... .. ,._. 1 ·, # -.... , ·"' •-I ... ' --., ,.,,2 .. \ .a."~ • --~ .. ~~· ... \ ~--.. -... ,, 'J, ..... -\. ---' .. , ... ... m\ ··\3 •• --,_. ... .t ·,· • ---\ ,.. } ,.,,24 •• \ .. .. ~ 25 .... ... \ --, \fl~ / f9i-~j v/.; / /1 /MW·~~ ~4 ri5 • . . , /1 ~~-S -"'~7 • .. 31\.# ::.: u, """!'-'4-I • ;.. -~ .... . ' ~ c::. ~ -0 .. i .. , - • • ,,. * •.._ it ,....J/ I + .,,, ::C / I MW-17 co=-S-':., /;5_ / /1 BL+4 I o' ··,~.\ -~' ~ . "'·'- -s,. .L I • • ii , / / I MVN:J MW -_,(!: ........ • • / L.A.. .:J ---. l : •••• \'~ ,- • I MW-201 . . . ~ ... .,,. t . .,,.. -i. .A • #' ... # j I ~ ! ---·· I I 4 • 1 5 1 ~ ~·'IW" ....., ...... 2\ ,. • I I I !, .. ~ ~ .... . .. #,~, ··~ a It-5 : 1 \ "\ 11 •.• , ""C ~ # ;s i i*Corre!S!>n"O" Cl ·~,, ' ~ .... . ' , ... \ \ I -----,;."-----#7-n ! ••• • '# ; ... "· r' ._ • I # .. I "-.,... # ··,. '18 17 I.,,. 16 / 15 ':\: I • \ •'A1' 14 ,: 19 • • \ ~ • ~ .. I. : \ 0 , ....... i *\ I ~ • I • ._ ~ (/#" I ~ .. "' .. --------,_ -----------' •••••• ,. J..-.lq ' l ...... · :., .. :, /,'"'? -,._ __ -V ~ ,.-..,: k,; ~--~#p u '~ r.~ ' .. I ._ _.,. .. ~ ~-lq ~ , ..• J..-. a ~,, \ ' ~ , ..... ~.::i:, !~·' , # ..... ·-b, I ... 22 ' + ; -----------1 -r---- ...... ·1 ,. I INDIAN) R 29 ' •• \ • .. , ·, lx ... -J V A ~ .. ~ I ~ - .. .,. .. .., I • ~:" ~:.1,: • -~ • I i 35 ~'!i~\/ " : -,,.-, I I o • ,. 1 I ~ ' --:a ,s\:i , -5. j 32 ... ...... ~ Y? C C\ ~ : ,. i f 'i :::) ~ .. I BLM --1 ---Denison Property Boundary -----Ute Mtn. Ute Reservation Boundary •• Canyon Rim ENERGY FUELS White Mesa Mill N :le, UT 12-11 I GM SEEPS AND SPRINGS LOCATION MAP A<ltncr. HRR Dita: Nov. 3, 2003 I D<al!Od ey. BM Attachment B United States Department of the Interior BUREAU OF LAND MANAGEMENT Monticello Field Office IN REPLY REFER TO: P.O. Box 7 Monticello, Utah 84535 http://www.blm.gov/utah/monticello TAKE PRICE:• INAMERICA MAY O 3 2011 LOAs UTY020 Jo Ann Tischler Denison Mines (USA) Corp. RECFI\/ED fit=======-- Director, Compliance and Permitting 1050 17th Street, Suite 950 Denver, CO, US, 80265 Dear Ms. Tischler: As per your phone conversation with Realty Specialist Maxine Deeter 1ast week, this letter authorizes Denison to do water sampling on public lands administered by the Bureau of Land Management adjacent to the White Mesa Mill south of Blanding, Utah. We understand that the sampling will consist of hand digging two cubic feet square holes at springs which do not contain standing water and leaving the holes to fill with water so that it can be tested in compliance with Department of Environmental Quality (DEQ) requirements. As Maxine stated on the phone, we do not consider this to be "development,, of these springs but rather meets the definition of casual use of public lands. We would request that these test holes be filled again with the soil that was removed from them. If you have questions or concerns, please contact Maxine at 435-587-1522 or via email. Sincerely, Thomas A. Heinlein Field Office Manager Attachment C II Field Data Record-Seeps and Springs Sampling Seep or Spring Location: ---------------------- Date For Initial Sampling Visit: ________ Time: _________ _ Sample Collected: o Yes o No Date For Second Sampling Visit: ________ Time: _________ _ Sample Collected: o Yes o No Date For Third Sampling Visit: ________ Time: _________ _ Sample Collected: o Yes o No Date For Fourth Sampling Visit: ________ Time: _________ _ Sample Collected: o Yes o No Sampling Personnel: Weather Conditions at Time of Sampling: _______________ _ Estimated Seep or Spring Flow Rate: ------------------ Field Parameter Measurements: -pH -Temperature (°C) --------------- -Conductivity µMHOC/cm ------------ -Turbidity (NTU) (if measured) __________ _ -Redox Potential Eh (mV) (if measured) ______ _ Analytical Parameters/Sample Collection Method: Pat-ameter hmpl Taken Filtered S8fttplin2. Method Direct Pe:ri&~tic Ladle 0tker ~ (4~:em 11otes sedien} voes o Yes oNo D Yes D No D D D D Metals o Yes oNo o Yes D No D D D D Nutrients o Yes oNo o Yes D No D D D D Other Non o Yes DNo o Yes DNo D D D D Radiologies Gross Alpha o Yes D No o Yes D No D D D D QC Samples Associated with this Location: o Rinsate Blank o Duplicate Duplicate Sample Name: ___________ _ Notes: ------------------------------- Appendix D Results of Soil Analysis at Mill Site f 'I \..._ -·--·-Results Of Soil Analyses At Mill Site g i~ l ie ); i-~1 t-. ...... 01{ ti~ ... '!I .§ ~ .J. i!•Q ,:.; ... a, ll't 1,1 '-' ..:i .... , •. , ..... ~~ <i ~ ! ! ..., I BIIIDdlng 4 04 SiL 7.6 36.0 7.4 7,9 0.3 .15 1.2 ~Snd) Ustollic 4-12 SiCL 8.7 49.0 7.6 8.0 0,3 0.14 0,8 Ellplugid F'me-silty, 18-40 SiCL 8.0 43.7 8.0 8.5 2.0 0.30 0.7 mixeil 9 0-S SiL 8.9 38.7 7.6 8.1 0.3 0.17 0.9 S-12 SiL 9.3 4S.6 8.0 8.4 0.3 0.18 0.9 18-40 SiL 8.0 38.7 8.S 9.0 3.8 0.18 1.2 40-50 SiCL 9.0 38,9 8.8 9.2 1.6 0.18 1.0 Souroe: Adapted from 1978 ER Table 2.10-2.2 SiCL :a ailty clay loam: SIL m &IU loam ·sii ~ j,... '0G ~~ ii c.i8 ]a t,i:::! ga-C, ~ ! ,Q'-' ci. Do I.I .63 IS 198 12.8 0.2 0.53 3 170 16.6 0.6 0.42 3 165 14.9 1.8 0.53 10 182 13,1 J.4 Q.47 2 138 10.9 11.5 0.37 2 123 11.9 12.5 0.26 1 161 IS.9 ·-:' .~~ Appendix E Tables: Chemical and Radiological Characteristics of Tailings Solutions, Leak Detection Systems and Slimes Drains Cell 1 Chemical and Radiological Characteristics Constituent 1987 2003 2007 2008 2009 2010 2011 2012 2013 2013 2014 2015 2016 2017 2018 2018 2019 2020 2021 Resample Resample Major Ions (mg/L) Carbonate <5 <l ND ND <1 <1 <l <l <1 NS <1 <1 <1 <l <l NS <5 <5 <5 Bicarbonate <5 NA ND ND <1 <l <l <I <l NS <1 <1 <1 <1 <1 NS <5 <5 <5 Calcium 630 307 483.8 604 635 711 577 426 768 NS 404 573 647 581 518 NS 720 618 234 Chloride 8000 6728 37340 9830 20700 7440 33800 78000 9900 NS 11600 25500 19200 19900 39300 NS 19800 40000 74700 Fluoride <100 3005 31.72 0.3 0.4 28.4 69.2 62.9 4130 NS 2380 5880 2980 4290 5020 NS 3480 7460 14900 Magnesium 7900 5988 21220 6550 16200 5410 14300 16000 4470 NS 5530 12400 9210 9380 20800 NS 9200 12300 19800 Nitrogen-Ammonia 7800 3353 10628 5250 15200 8120 12900 9750 3900 NS 5700 5.4 7090 1040 9810 NS 10400 10600 5850 Nitrogen-Nitrate <100 41.8 269.4 64.9 142 58 212 556 128 NS 53 192 124 152 328 NS 118 191 27 Potassium NA 647 5698 1880 4140 1840 4510 9750 6580 NS 3010 7330 1970 2700 4790 NS 2600 4580 4030 Sodium 10000 8638 62600 13200 39000 16700 29500 41700 15900 NS 12200 32100 18900 23900 53500 NS 28000 62900 91900 Sulfate 190000 63667 287600 118000 232000 107000 182000 158000 100000 NS 124000 204000 212000 165000 253000 NS 169000 222000 351000 pH (s.u.) 0.70 1.88 0.80 1.53 l.15 2.73 2.23 1.90 2.74 NS 1.30 1.01 <I.DO <I.DO <l.00 NS 1.14 0.92 0.4 TDS 120000 94700 357400 131000 140000 130000 216000 342000 149000 NS 159000 334000 242000 231000 361000 NS 257000 422000 584000 Conductivity (umhos/cm) NA NA NA NA 365000 110000 112000 136000 94200 NS 113000 131000 123000 57600 110000 NS 119000 81500 76000 Metals (ug/L) Arsenic 440000 121267 849000 271000 436000 74400 299000 25500 9800 NS 249000 377000 407000 391000 641000 NS 270000 599000 1040000 Beryllium 780 475 2262 500 410 338 1270 3180 415 NS 448 1290 1030 749 1510 NS 930 1330 3660 Cadmium 6600 3990 29320 8790 9120 2940 13700 30700 2380 NS 3060 7710 6320 6730 14000 NS 5400 9070 21300 Chromium 13000 6365 29940 6760 18700 5620 22700 12100 8350 NS 13200 19600 14000 15900 21100 NS 15000 25700 29600 Cobalt 120000 NA 88240 23500 97500 16200 56000 53100 25500 NS 56500 82000 77200 91400 113000 NS 66000 51400 59500 Copper 740000 196667 881000 360000 168000 125000 483000 885000 544000 NS 3420000 3560000 4730000 3440000 4550000 NS 1700000 2110000 3760000 Iron 3400000 2820000 13480000 3280000 2390000 3400000 8940000 840000 1420000 NS 2520000 6680000 5650000 2300000 12200000 NS 9100000 15400000 6680000 Lead <20000 3393 27420 11200 10600 9240 23600 17000 2810 NS 13500 16800 22500 23000 41000 NS 22000 42400 91200 Manganese 140000 162500 990200 206000 723000 173000 735000 1560000 188000 NS 162000 515000 713000 510000 936000 NS 540000 833000 1630000 Mercury NA NA ND ND 7.61 7.2 61.4 117 6.16 NS 12.5 24.6 8.59 7.86 16.8 NS 3.7 14 0.035 Molybdenum 240000 50550 415600 106000 142000 35300 235000 434000 16800 NS 68800 127000 97100 128000 239000 NS 120000 247000 418000 Nickel 370000 36950 40860 32000 156000 27500 43700 15000 39100 NS 129000 130000 170000 183000 167000 NS 110000 27100 18400 Selenium <20000 1862 15420 13000 14800 5220 11600 8090 2690 NS 3970 7070 3950 5070 10700 NS 10000 16600 21800 Silver <5000 NA 1559.2 449 558 155 1110 4310 329 NS 336 1390 1240 1240 2320 NS 790 1290 2640 Thallium 45000 NA 407.8 165 387 193 560 13 63.3 NS 876 1130 754 155 442 NS <700 <50 1680 Tin <5000 NA 6512 1240 2290 263 1500 <100 <100 NS <17000 <100 <17000 <17000 <17000 NS 540 1220 1820 Uranium 105000 134517 788600 416000 578000 159000 838000 1450000 140000 NS 137000 363000 131000 102000 248000 NS 81000 200000 655000 Vanadium 280000 348000 2208200 1200000 773000 752000 2500000 1940000 98200 NS 485000 1130000 746000 1520000 2440000 NS 1400000 2090000 4410000 Zinc 1300000 NA 642940 476000 229000 171000 398000 811000 228000 NS 229000 638000 448000 515000 948000 NS 550000 396000 905000 Radiologies (pCi/L) 735000 Gross Alpha NA 1693331 29380 21900 16500 11300 3610 12600 32700 NS 331000 (8/4/2015) 420000 191000 550000 NS 326000 83800 24600 73800 -(5/28/2015) Cell I Chemical and Radiological Characteristics Constituent 1987 2003 2007 2008 2009 2010 2011 2012 2013 2013 2014 2015 2016 2017 2018 2018 2019 2020 2021 Resample Resample voes (ug/L) Acetone 35 NA 66.5 110 710 260 80 310 41.1 NS <700 56 40.6 28 50.4 NS 28 32.6 152 Benzene <5 NA ND ND <1 <1 <1 <1 <1 NS <5.0 <1 <l <1 <l NS <1 <1 <5 Carbon tetrachloride <5 NA ND ND <l <I <l <I <1 NS <5.0 <1 <l <l <l NS <l <l <5 Chloroform 8 NA 6.7 6.6 16 4.9 13 19 7.62 NS <70.0 5.54 <l 3.42 114 NS 7.5 2.84 46.2 Chloromethane NA NA ND 9.4 11 4.4 3.6 4 5 NS <30.0 1.93 <1 1.13 1.16 NS 2.3 1.49 <5 MEK NA NA ND ND 120 65 <1 200 <20 NS <4000 <20 <20 <20 <20 NS 11 J 6.41 <25 Methylene Chloride 11 NA ND ND 2 <l <l 2 <1 NS <5.0 1.83 <l 1.09 2.41 NS <I <5 <25 Naphthalene <10000 NA <10 ND 1.1 5.4 2 3 <l NS <100 <1 <1 <l <l NS <l <l <5 Tetrahydrofuran NA NA 150 <20 <100 <10 <500 2.9 <l NS <46.0 <1 <l <1 4.93 NS <35 <5 <25 Toluene <5 NA ND ND <l <l <I <I <1 NS <1000 <l <l <l <I NS <I <1 <5 Xylenes <5 NA ND ND <l <1 <1 <l <l NS <10000 <1 <1 <l <I NS <1 <3 <15 SVOCS (ug/L) 1,2,4-Trichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 1,2-Dichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8 .04 <10 <30 <37.5 1,3-Dichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 1,4-Dichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 1-Methy !naphthalene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3.0 <3.75 2,4,5-Trichlorophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 2,4,6-Trichlorophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 2,4-Dichlorophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 2,4-Dimethylphenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37 .5 2,4-Dinitrophenol NA NA NA NA <250 <20 <20 <20 <21.6 <20 <20 <20 <10 <10 <148 <8.04 <50 <50 <62.5 2,4-Dinitrotoluene NA NA NA NA <50 <IO <10 <10 <10.8 <10 <10 <IO <IO <IO <148 <8 .04 <10 <30 <37.5 2,6-Dinitrotoluene NA NA NA NA <50 <10 <IO <10 <10.8 <IO <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 2-Ch loronaphthalene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <4.1 <5.13 2-Chlorophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 2-Methylnaphthalene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 2-Methylphenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 2-Nitrophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 3&4-Methylphenol NA NA NA NA <22 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <37 <46.3 3 ,3-Dich lorobenzidi ne NA NA NA NA <100 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <50 <33 <41.3 4,6-Dinitro-2-NA NA NA NA <250 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8 .04 <50 <30 <37.5 methyl phenol 4-Bromophenyl phenyl NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <IO <10 <10 <148 <8.04 <10 <30 <37.5 ether 4-Chloro-3-methylphenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 4-Chlorophenyl phenyl NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 ether 4-Nitrophenol NA NA NA NA <250 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <50 <30 <37.5 Acenaphthene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Acenaphthylene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Anthracene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Azobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <IO <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 Benz(a)anthracene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Cell 1 Chemical and Radiological Characteristics Constituent 1987 2003 2007 2008 2009 2010 2011 2012 2013 2013 2014 2015 2016 2017 2018 2018 2019 2020 2021 Resample Resample Benzidine NA NA NA NA <100 <10 <10 <10 <10.8 <10 41 <10 <10 <10 <148 <8.04 <100 <39 <48.8 Benzo(a)pyrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Benzo(b )fluoranthene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Benzo(g,h,i)perylene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Benzo(k)tluoranthene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Bis(2-chloroethoxy) NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <37.5 methane Bis(2-chloroethyl) ether NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 Bis(2-chloroisopropyl) NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 ether Bis(2-ethylhexyl) NA NA NA NA <50 27 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 phthalate Butyl benzyl phthalate NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Chrysene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Dibenz(a,h)anthracene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Diethyl phthalate NA NA NA NA 170 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Dimethyl phthalate NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Di-n-butyl phthalate NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Di-n-octyl phthalate NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Fluoranthene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Fluorene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Hexachlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 Hexachlorobutadiene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <30 <30 <37.5 Hexachloro -NA NA NA NA <50 <10 <10 <10 <10.8 cyclopentadiene <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 Hexachloroethane NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <30 <30 <37.5 Indeno( 1,2,3-cd)pyrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Isophorone NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <35 <43.8 Naphthalene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Nitrobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 N-Nitrosodimethylamine NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 N-Nitrosodi-n-NA NA NA NA <50 <10 <10 <10 <10.8 propylamine <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 N-Nitrosodiphenylamine NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 Pentachlorophenol NA NA NA NA <250 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <50 <30 <37.5 Phenanthrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Phenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <30 <37.5 Pyrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <10 <3 <3.75 Pyridine NA NA NA NA <50 <10 <10 <10 <10.8 <10 <10 <10 <10 <10 <148 <8.04 <20 <30 146 1 Historic values reported for Gross Alpha from 1987 and 2003 are total gross alpha reported in pCi/L. All other gross alpha data are reported as Gross Alpha minus Rn & U. Cell 2 Slimes Drain Chemical and Radiological Characteristics Constituents 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Major Ions (mg/L) Carbonate ND ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 Bicarbonate ND ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <l <5 <5 <5 Calcium 572 528 508 496 474 462 465 322 524 402 477 538 480 513 463 Chloride 3700 3860 2750 3510 3110 3730 3270 3720 3850 4040 3820 4310 3870 4080 4200 Fluoride 3.3 ND <0.1 2.4 2.1 1.32 161 130 204 48.4 110 116 105 130 130 Magnesium 4100 4030 3750 3790 3640 3760 3320 2780 3810 3570 3630 4470 3700 3800 3950 Nitrogen-Ammonia 4020 3620 3240 3820 2940 3540 1880 3500 367 3800 500 5620 4420 7150 2950 Nitrogen-Nitrate 30.9 20.3 38 126 38 27 47.2 35 1.06 12.7 13.7 12.1 33.0 21.6 48.0 Potassium 636 560 689 620 636 611 622 489 659 512 668 774 710 735 661 Sodium 4050 4600 4410 4770 4590 4380 3980 3130 4800 4690 4810 5290 4600 4620 4520 Sulfate 60600 74000 72200 63700 64200 58300 83700 62200 57800 83900 58300 63300 67000 67000 68500 pH (s.u.) 3.18 3.24 3.11 3.39 3.18 3 3.02 3.1 3.1 2.99 3.08 2.89 3.07 3.06 3.0 TDS 84300 74600 84100 79900 80200 83800 92200 87000 88200 93100 85900 99900 94300 89500 95700 Conductivity (umhos/cm) NA NA 88700 60200 51400 52900 51100 54100 58800 44500 52600 58200 55700 53900 53200 Metals ( ug/L) Arsenic 26900 19300 14200 23500 17800 19400 21000 19800 13300 16900 21100 19600 23000 18000 19300 Beryllium 298 245 271 267 231 251 262 197 275 259 261 241 280 284 217 Cadmium 5500 5840 5510 6370 5580 5290 5780 6480 6260 6610 6790 6380 6500 5220 5890 Chromium 2750 2450 2230 2510 2380 2350 2290 1630 1840 1630 2290 2100 2100 1860 1810 Cobalt 46500 43800 38700 48200 42500 48700 44900 46700 46000 46100 50600 46900 54000 40800 42700 Copper 106000 154000 170000 148000 132000 138000 137000 126000 143000 156000 148000 136000 160000 93900 139000 Iron 2770000 3310000 3230000 2720000 2960000 2850000 2810000 2180000 3000000 3410000 3430000 3030000 3600000 2420000 2840000 Lead 566 528 403 586 501 619 515 638 268 484 593 589 590 400 562 Manganese 117000 130000 160000 144000 123000 141000 122000 98000 136000 149000 151000 137000 170000 133000 138000 Mercury ND ND <0.5 <4 11.1 1.9 <0.5 <0.0020 <0.5 <2.00 <2.00 <2.00 <0.2 0.058 <0.2 Molybdenum 4080 3190 2240 4630 3510 3610 3650 4250 2010 3360 4060 3340 3200 2170 3090 Nickel 123000 122000 108000 126000 111000 125000 108000 127000 120000 134000 133000 121000 140000 104000 119000 Selenium 422 647 726 844 714 711 678 1020 631 615 683 635 1300 585 657 Silver ND ND <10 <10 <10 <10 <10 <100 <20 <100 <100 <100 <50 6 5 Thallium 361 703 368 470 371 338 278 402 233 212 373 374 390 2190 1580 Tin ND ND <100 <100 <100 <100 <100 <17000 <100 <17000 <17000 <17000 <50 <50 <50 Uranium 23000 29200 29900 30600 27100 33400 22800 26400 27200 27300 28600 25200 29000 18600 24300 Vanadium 409000 463000 536000 469000 454000 475000 452000 497000 513000 497000 534000 516000 500000 345000 450000 Zinc 767000 750000 582000 652000 574000 639000 631000 405000 702000 764000 760000 728000 850000 816000 674000 Radiologies (pCi/L) Gross Alpha 1290 1570 1580 1000 1230 1370 2270 6890 7210 5660 4570 7520 3790 1630 1920 (2400)* voes (ug/L) Acetone 550 410 570 460 690 600 384 <700 599 473 551 551 449 501 522 Benzene ND ND <1 <1 <1 <1 <1 <5.0 <l <1 <l <1 <l <5 <5 Carbon tetrachloride ND ND <l <l <1 <1 <1 <5.0 <1 <1 <1 <1 <l <5 <5 Chloroform 20 17 16 15 20 16 21.4 <70.0 18.6 15 17.1 17.1 16 13.7 15.9 Chloromethane 1.8 ND 2.2 2.3 2 3 2.04 <30.0 <l <l 1.46 1.46 2.2 <5 <5 Cell 2 Slimes Drain Chemical and Radiological Characteristics Constituents 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 MEK 65 ND 100 83 130 100 95.5 <4000 102 80.3 58.4 58.4 135 74.0 89.9 Methylene Chloride ND ND <1 <1 <l <l <1 <5.0 <l <l 1.02 1.02 0.49 J <25 <25 Naphthalene 14 7.5 16 17 13 12 16.8 <100 16.2 11.9 10.1 10.1 13 7.65 7.15 Tetrahydrofuran 15 NA <100 <10 <10 3.2 3.98 <46.0 2.16 <1 2.88 2.88 <10 <25 <25 Toluene 1.7 ND 2.6 2.6 3 2 3.23 <1000 3.74 2.94 3.20 3.20 2.4 <5 <5 Xylenes 1.5 ND <l 2.2 <l 2 5.97 <10000 <l <l <l <l 0.51 J <15 <15 SVOCS (ug/L) 1,2,4-Trichlorobenzene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 1,2-Dichlorobenzene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 1,3-Dichlorobenzene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 1,4-Dichlorobenzene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 1-Methylnaphthalene NA NA <11 <10 <10 <10 <10 11 <10 <10 <10 <9.03 12 <3.0 11.6 2,4,5-Trichlorophenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2,4,6-Trichlorophenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2,4-Dichlorophenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2,4-Dimethylphenol NA NA <51 <20 <20 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2,4-Dinitrophenol NA NA <11 <10 <10 <20 <20 <20 <20 <10 <10 <9.03 <50 <50 <50 2,4-Dinitrotoluene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2,6-Dinitrotoluene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2-Chloronaphthalene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <4.1 <4.10 2-Chlorophenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2-Methylnaphthalene NA NA <11 <10 <10 <10 <10 11 <10 11.1 <10 <9.03 11 <3 10.4 2-Methylphenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 2-Nitrophenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 3&4-Methylphenol NA NA <21 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <37 <37 3,3 '-Dichlorobenzidine NA NA <51 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <46 <33 <33 4,6-Dinitro-2-methylphenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <50 <30 <30 4-Bromophenyl phenyl ether NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 4-Chloro-3-methylphenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 4-Chlorophenyl phenyl ether NA NA <51 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 4-Nitrophenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <50 <30 <30 Acenaphthene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Acenaphthylene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Anthracene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Azobenzene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 Benz( a)anthracene NA NA <21 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Benzi dine NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <92 <39 <39 Benzo(a)pyrene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Benzo(b )flu oran thene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Benzo(g,h,i)perylene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Benzo(k)fluoranthene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Bi s(2-chloroethoxy )methane NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <30 Bis(2-chloroethyl) ether NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 Bis(2-chloroisopropy]) ether NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 Cell 2 Slimes Drain Chemical and Radiological Characteristics Constituents 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Bis(2-ethylhexyl) phthalate NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 1.1 <3 <3 Butyl benzyl phthalate NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Chrysene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Dibenz( a,h )anthracene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Diethyl phthalate NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Dimethyl phthalate NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 1.5 <3 <3 Di-n-butyl phthalate NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Di-n-octyl phthalate NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Fluoranthene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Fluorene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Hexachlorobenzene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 Hexachlorobutadiene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <28 <30 <30 Hexachlorocyclopentadiene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 Hexachloroethane NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <28 <30 <30 Indeno( 1,2,3-cd)pyrene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Isophorone NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <35 <35 Naphthalene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 5.3 <3 <3 Nitrobenzene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 N-Nitrosodimethylamine NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 N-Nitrosodi-n-propylamine NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 N-Nitrosodipheny )amine NA NA <51 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 Pentachlorophenol NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <50 <30 <30 Phenanthrene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Phenol NA NA <11 10.7 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <30 <30 Pyrene NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <10 <3 <3 Pyridine NA NA <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.03 <18 <30 <30 * Sample was reanalyzed due to comparability with the duplicate sample. The reanalysis data are in (parenthesis). Cell 2 LDS Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Major Ions (mglL) Carbonate <1 <l Bicarbonate 168 324 Calcium 711 615 Chloride 1750 1360 Fluoride 0.4 0.4 Magnesium 596 454 Nitrogen-Ammonia 32.6 0.7 Not Not Not Not Not Not Not Not Not Not Not Nitrogen-Nitrate 2.8 2.2 Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Potassium 22 13 Sodium 412 318 Sulfate 2700 1780 pH (s.u.) 6.6 7.36 TDS 6750 5310 Conductivity (umhos/cm) 11000 6500 Metals {ug/L) Arsenic <5 <5 Beryllium <0.50 <0.50 Cadmium 33.4 1.1 Chromium <25 <25 Cobalt 314 <10 Copper 59 12 Iron 208 37 Lead <LO <1.0 Manganese 1810 395 Not Not Not Not Not Not Not Not Not Not Not Mercury <0.50 0.52 Molybdenum 21 13 Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Nickel 948 <20 Selenium 7.9 9.4 Silver <10 <10 Thallium 0.92 <0.50 Tin <100 <100 Uranium 83.8 79.6 Vanadium 22 <15 Zinc 4220 78 Cell 2 LDS Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Radiologies (pCi/L) Gross Alpha 13.5 7.3 Not Not Not Not Not Not Not Not Not Not Not Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled voes (ug/L) Acetone <20 <20 Benzene <1 <l Carbon tetrachloride <1 <l Chloroform <1 <l Chloromethane <l <1 Not Not Not Not Not Not Not Not Not Not Not MEK <20 <20 Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Methylene Chloride <1 <l Naphthalene <l <1 Tetrahydrofuran <100 6.13 Toluene <1 <l Xylenes <1 <l SVOCS (ug/L) 1,2,4-Trichlorobenzene NA <10 1,2-Dichlorobenzene NA <10 1,3-Dichlorobenzene NA <10 1,4-Dichlorobenzene NA <10 I -Me thy !naphthalene NA <10 2,4,5-Trichlorophenol NA <10 2,4,6-Trichlorophenol NA <10 2,4-Dichlorophenol NA <10 2,4-Dimethylphenol NA <10 2,4-Dinitrophenol NA <20 Not Not Not Not Not Not Not Not Not Not Not 2,4-Dinitrotoluene NA <10 Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled 2,6-Dinitrotoluene NA <10 2-Chloronaphthalene NA <10 2-Chlorophenol NA <10 2-Methylnaphthalene NA <10 2-Methylphenol NA <10 2-Nitrophenol NA <10 3&4-Methylphenol NA <10 3 ,3 '-Dichlorobenzidine NA <10 4,6-Dinitro-2-methylphenol NA <10 4-Bromophenyl phenyl ether NA <10 Cell 2 LDS Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 201S 2016 2017 2018 2019 2020 2021 4-Chloro-3-methylphenol NA <10 4-Chlorophenyl phenyl ether NA <10 4-Nitrophenol NA <10 Acenaphthene NA <10 Acenaphthylene NA <10 Anthracene NA <10 Azobenzene NA <10 Benz(a)anthracene NA <10 Benzidine NA <10 Benzo(a)pyrene NA <10 Benzo(b )fluoranthene NA <10 Benzo(g,h,i)perylene NA <10 Benzo(k)tluoranthene NA <10 B is(2-chloroethoxy )methane NA <10 Bis(2-chloroethyl) ether NA <10 Bis(2-chloroisopropyl) ether NA <10 Bis(2-ethylhexyl) phthalate NA <10 Butyl benzyl phthalate NA <10 Chrysene NA <10 Dibenz( a,h )anthracene NA <10 Diethyl phthalate NA <10 Not Not Not Not Not Not Not Not Not Not Not Dimethyl phthalate NA <10 Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Sampled Di-n-butyl phthalate NA <10 Di-n-octyl phthalate NA <10 Fluoranthene NA <10 Fluorene NA <10 Hexachlorobenzene NA <10 Hexachlorobutadiene NA <10 Hexachlorocyclopentadiene NA <10 Hexachloroethane NA <10 Indeno( 1,2,3-cd)pyrene NA <10 Isophorone NA <10 Naphthalene NA <10 Nitro benzene NA <10 N-Nitrosodimethylamine NA <10 N-Nitrosodi-n-propylamine NA <10 N-Nitrosodiphenylamine NA <10 Pentachlorophenol NA <10 Phenanthrene NA <10 Phenol NA <10 Pyrene NA <10 Pyridine NA <10 Cell 3 ennca an 8 0 Ol!ICa aractens cs Ch . I d R di 1 . I Ch . ti 2013 2018 Constituent 1987 2003 (Avg) 2007 (Avg) 2008 2009 2010 2011 2012 2013 ReSample 2014 2015 2016 2017 2018 ReSample 2019 2020 2021 Major Ions (mg/L) Carbonate NA <l ND ND <l <l <1 <l <l NS <1 <1 <1.00 <1.00 <1.00 NS <5 236 Bicarbonate <5 NA ND ND <l <I <l <l <l NS <l <I <1.00 <1.00 <1.00 NS <5 175 Calcium 300 418 887 478 628 560 200 591 586 NS 294 713 148 526 498 NS 510 3 Chloride NA 2460 15965 15400 17200 3470 40400 8880 38400 NS 7200 22800 115000 2720 55200 NS 15000 500 Fluoride <100 667 42.8 1.4 0.6 54.8 64.1 2300 12400 NS 1330 5410 46500 189 7400 NS 1340 2.2 Magnesium 5400 3386 15767 13100 17100 2500 22100 5680 15400 NS 1910 12700 31000 84400 22000 NS 10000 11 Nitrogen-Ammonia 13900 1302 13867 9010 21600 2650 6470 6840 100 NS 3030 8.91 6270 88.5 9490 NS 9000 Not 278 Nilrogen-Nitrate <100 20 102 44 142 26 261 64 277 NS 59.5 26.6 582 107 710 NS 925 Sampled-12.2 Potassium NA 254 6657 4760 3820 782 2590 1190 2ll0 NS 386 1620 3120 133 1480 NS 630 Dry 20 Sodium 5900 3198 25583 22900 28600 5620 47900 6660 34400 NS 3630 23800 59800 2120 46900 NS 14000 1210 Sulfate 180000 33400 173667 167000 214000 40400 197000 80000 440000 NS 37000 158000 834000 9970 208000 NS 96000 1630 pH (s.u.) 0.82 2.28 1.6 1.79 1.4 2.18 1.27 2.4 1.05 NS 2.2 1.72 <1.00 3.63 1.32 NS 3.88 LO TDS 189000 51633 228500 193000 243000 56200 296000 120000 410000 NS 70100 238000 887000 17300 327000 NS 143000 3930 Conductivity (umhos/cm) NA NA NA NA 304000 59800 86400 80300 84300 NS 56200 121000 13600 20300 104000 NS 95500 5870 Metals (ug/L) Arsenic 163000 32867 256500 489000 ND 52900 263000 4340 66000 NS 2920 21500 194000 870 20900 NS 380 170 Beryl I iu,n 540 430 913 840 905 206 1570 678 2570 NS 222 1520 12500 590 2950 NS 350 <I Cadmium 2600 1958 9260 15400 ND 1960 12200 3460 24000 NS 2550 14800 41000 1190 52100 NS 7400 2 Chromium 12000 3742 14883 12800 ND 3360 22800 10900 30600 NS 2380 15300 76200 <100 25100 NS 2301 <5 Cobalt 48000 NA 82783 57000 ND 13000 76000 76100 99700 NS 20800 72500 74200 4440 120000 NS 64000 <100 Copper 360000 87333 505000 345000 ND 89000 768000 379000 954000 NS 139000 511000 3000000 9720 515000 NS 35000 454 Iron 2100000 1278333 4874500 4400000 5970000 1460000 10200000 3400000 9700000 NS 688000 4570000 15400000 262000 13300000 NS 2500000 519 Lead <20000 2507 9647 16900 ND 17200 16700 1860 14400 NS 1900 9090 4030 15.8 20500 NS <75 2 Manganese 82000 144000 496833 313000 ND 101000 587000 3110000 2470000 NS 214000 1270000 5690000 102000 4070000 NS 1000000 Not 47 Mercury ND NA ND 16 ND <4 30.9 9.6 21.6 NS 2.4 7.01 873 <2.00 430 NS 0.20 Sampled-<1 Molybdenum 52000 12250 122167 209000 14 21300 96200 790 56100 NS 2930 12500 133000 70.1 3740 NS 550 Dry 759 Nickel 170000 20917 131833 241000 ND 23800 75800 150000 122000 NS 44900 121000 29200 7220 113000 NS 150000 33 Selenium <2000 910 5856 10200 ND 3080 6900 2460 7060 NS 1370 4330 3170 306 3680 NS 2900 135 Silver <2500 NA 305 1010 ND IOI 792 1850 3380 NS 329 1790 6780 <100 3770 NS 110 <I Thallium 4700 NA 446 1200 ND 190 518 1080 694 NS 290 602 2160 21.3 3760 NS 170 1.6 Tin NA NA 1090 1070 ND 155 325 <100 <100 NS <17000 <100 <17000 <17000 <17000 NS <50 <50 Uranium 118000 67833 332333 636000 3690 180000 458000 835000 1200000 NS 134000 530000 5360000 9630 1110000 NS 19000 533 Vanadium 210000 158333 935000 1130000 ND 692000 2370000 836000 3220000 NS 454000 1720000 10300000 5600 2420000 NS 54000 6740 Zinc 590000 NA 748833 515000 ND 134000 726000 652000 1430000 NS 155000 899000 7810000 68100 2100000 NS 950000 114 Radiologies (pCi/L) 94900 Not Gross Alpha NA 1015831 16533 21700 17000 4030 11100 1530 81900 NS 19700 (8/4/2015) 86000 292 19700 NS 3890 Sampled-<18.5 8780 Dry (5/28/2015) Cell 3 ennca an a o oe1ca Ch . I d R di l . J Ch aracter1sttcs 2013 2018 Constituent 1987 2003 (Avg) 2007 (Avg) 2008 2009 2010 2011 2012 2013 ReSample 2014 2015 2016 2017 2018 ReSample 2019 2020 2021 voes (ug/L) Acetone 28 NA 80 100 67 37 330 64 302 159 <700 82.8 <200 48.4 135 NS 135 46.6 Benzene <5 NA ND ND <I <I <1 <I <5 <I <5.0 <l <I <I <I NS <I <5 Carbon tetrachloride <5 NA ND ND <I <l <I <I <5 <I <5.0 <I <I <I <1 NS <I <5 Chloroform 6 NA ND 11 4.2 2.6 31 2 56.3 21 <70.0 1.75 13.2 <I 5.02 NS 18 <5 Chloromethane NA NA ND ND 1.4 1.8 3.5 I <5 2.58 <30.0 1.03 19.8 <l 5.36 NS 2.8 Not <5 MEK NA NA ND ND <I <I 67 <20 <100 24.5 <4000 <20 <20 <20 <20 NS 34 Sampled -<25 Methylene Chloride 10 NA ND ND <I <I 7.4 <I 6.95 <I <5.0 <l <l <I 10.4 NS 0.67 J Dry <25 Naphthalene <10000 NA ND <10 <I 2.1 1.2 <I <5 <I <100 <l <I <I <I NS 0.57 J <5 TeLrahydrofuran NA NA 150 <20 <100 <10 <10 <I <5 <I <46.0 <I <I <l 3.01 NS <35.0 <25 Toluene <5 NA ND ND <I <I <I <I <5 <l <1000 <I <I <I <I NS <I <5 Xylenes <5 NA ND ND <I <I <I <I <5 <l <10000 <l <I <I <I NS <l <15 SVOCS (ug/L) 1,2,4--Trichlorobenzene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 I .2-Dichlorobenzene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 1,3-Dichlorobenzene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <30 1,4-Dichlorobenzene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 I-Methyl naphthalene NA NA NA NA <I I <10 <IO <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 2,4,5-Trichlorophenol NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 2,4.6-Trichlorophenol NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 2,4-Dichlorophenol NA NA NA NA <I I <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1 ,490 <7.78 <10 <30 2,4-Di methylphenol NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 2.4-Dinitrophenol NA NA NA NA <53 <20 <20 <20 <21.1 <20 <20 <20 <10 <10 <1,490 <7.78 <50 <50 2,4-Diniu·otoluene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 2,6-Di ni trotoluene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 Not <30 2-Chloronaphthalene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 Sampled -<4.10 2-Chlorophenol NA NA NA NA <I I <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 Dry <30 2-Melhylnaphthalene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 2-Methylphenol NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <I ,490 <7.78 <10 <30 2-Nirrophenol NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <30 3&4-Methylphenol NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <i,490 <7.78 <10 <37 3,3 '-Dichlorobenzidine NA NA NA NA <21 <10 <10 <10 <10.5 <10 <10 <IO <10 <10 <1,490 <7.78 <45 <33 4,6-Dinitro-2-methylphenol NA NA NA NA <53 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <50 <30 4-Bromophenyl phenyl ether NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 4-Chloro-3-rnethyl phenol NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <30 4-Chlorophenyl phenyl ether NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 4-Nitrophenol NA NA NA NA <53 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <50 <30 Acenaphthene NA NA NA NA <l I <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Cell 3 em1ca an a 10 Ol!lca Ch . I d R d" I . I Ch aracterishcs 2013 2018 Constituent 1, 1987 2003 (Avg) 2007 (Avg) 2008 1: 2009 2010 2011 2012 2013 ReSample 2014 2015 2016 2017 2018 ReSample 2019 2020 2021 Acenaphthylene NA NA NA NA <11 <LO <10 <10 <10.5 <LO <10 <10 <10 <10 <1.490 <7.78 <LO <3 Anthracene NA NA NA NA <11 <10 <10 <10 <L0.5 <LO <10 <10 <10 <LO <1,490 <7.78 <10 <3 Azobenzene NA NA NA NA <11 <LO <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 Benz( a)anthracene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Benzidine NA NA NA NA <21 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <39 Benzo(a)pyrene NA NA NA NA <11 <10 <10 <10 <L0.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Benzo(b )fluoranthene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Benzo(g,h,i)perylene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Benzo(k)tluoranthene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 B is(2-chl oroethoxy )methane NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <LO <10 <1,490 <7.78 <10 <30 Bis(2-chloroethyl) ether NA NA NA NA <11 <LO <10 <10 <10.5 <10 <10 <10 <10 <10 <l.490 <7.78 <10 <30 Bis(2-chloroisopropyl) ether NA NA NA NA <11 <LO <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 Bis(2-ethylhexyl) phthalate NA NA NA NA <II 10.6 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Butyl benzyl phthalate NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Chrysene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <3 Di benz( a, h )anthracene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Diethyl phthalate NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Dimethyl phthalate NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 Not <3 Di-n-butyl phthalate NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <3 Di-n-octyl phthalate NA NA NA NA <11 <LO <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 Sampled -<3 Auoranthene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 Dry <3 Auorene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Hexachlorobenzene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 Hexachlorobutadiene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <27 <30 Hexachlorocyclopentadiene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 Hexachloroethane NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <27 <30 Indeno( 1,2,3-cd)pyrene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <3 Isophorone NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <35 Naphthalene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <3 Nitrobenzene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <10 <30 N-Nitrosodimethylamine NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 N-Nitrosodi-n-propylamine NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 N-Nitrosodiphenylamine NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 Pentachlorophenol NA NA NA NA <53 <10 <10 <10 <10.5 <10 <10 <10 <10 <IO <1,490 <7.78 <50 <30 Phenanthrene NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1.490 <7.78 <IO <3 Phenol NA NA NA NA <11 <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <10 <30 Pyrene NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <IO <1,490 <7.78 <10 <3 Pyridine NA NA NA NA <II <10 <10 <10 <10.5 <10 <10 <10 <10 <10 <1,490 <7.78 <18 <30 1 Historic values reported for Gross Alpha from 1987 and 2003 are total gross alpha reported in pCi/L. All other gross alpha data are reported as Gross Alpha minus Rn & U. Cell 4A Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Major Ions (mg/L) Carbonate <l <1 <1 <1 <1 <l <1 <1 <1 <1 <5 <5 <5 Bicarbonate <1 <1 <1 <1 <1 <1 <1 <1 <l <1 <5 <5 <5 Calcium 627 598 558 591 668 445 604 632 607 707 510 641 637 Chloride 4650 7350 5870 4980 4530 5900 6410 7040 8060 10100 8670 9120 12700 Fluoride 0.3 21.6 30.6 43 1130 1290 1660 2030 1420 2000 1650 1700 3190 Magnesium 3250 4940 4720 2230 3660 2990 3910 3550 4360 7030 4100 4700 5020 Nitrogen-Ammonia 3140 5230 4930 1540 1340 2730 11 4770 924 9060 6700 10000 7250 Nitrogen-Nitrate 28 52 44 27 38.2 39.5 19.9 41.9 53.4 73.4 70.4 84.8 112 Potassium 980 1440 1450 558 773 724 1020 915 1500 2020 1200 1660 1730 Sodium 5980 11300 11400 7130 6860 7190 9760 9580 12000 17600 15000 17700 18800 Sulfate 67600 87100 267000 64900 83300 64900 77200 126000 77800 116000 81300 85700 110000 pH (s.u.) 1.4 1.99 1.73 1.2 1.47 1.7 1.51 1.59 1.53 1.25 2.40 2.36 2.2 TDS 81400 107000 108000 76000 90000 97000 104000 124000 120000 147000 122000 139000 162000 Conductivity (umhos/cm) 131000 101000 82100 78100 66300 73000 89600 81300 89800 115000 81400 84000 91300 Metals (ug/L) Arsenic 626000 109000 86600 60500 73700 70000 82600 94400 104000 125000 63000 71300 68600 Beryllium 296 215 323 167 247 190 281 320 440 538 420 485 448 Cadmium 1920 3670 2190 844 1450 1780 2090 2850 3360 3850 2500 3490 3540 Chromium 3220 7500 5900 5990 5220 4620 5460 7920 8520 9350 7200 9050 8820 Cobalt 9440 26500 22500 22900 22900 27500 26100 32800 37900 41000 28000 32800 30600 Copper 99200 168000 181000 433000 540000 556000 477000 566000 578000 683000 580000 617000 557000 Iron 2360000 2920000 3390000 3190000 2620000 2280000 3090000 3850000 4480000 5320000 3200000 3690000 3810000 Lead 5360 11800 11000 5270 11500 14800 11700 14000 15100 16400 9000 8680 8380 Manganese 178000 209000 131000 112000 143000 120000 181000 225000 261000 307000 210000 211000 214000 Mercury 1.19 <4 15.2 2.4 0.786 2.5 0.99 <2 2.30 2.52 2.1 3.4 3.7 Molybdenum 24300 43800 24200 58200 25500 40600 35400 43900 40800 59100 19000 25700 32600 Nickel 17100 40900 43500 41300 43300 54100 48700 61300 66800 71900 50000 58800 57100 Selenium 4620 5810 4460 1310 2080 2000 2400 2820 4450 5870 3700 3660 3740 Silver 78 193 216 127 144 197 186 305 379 521 310 487 466 Thallium 162 350 410 250 256 376 436 568 169 727 90 524 185 Tin 257 378 319 169 118 <17000 142 <17000 <17000 <17000 77 181 105 Uranium 118000 217000 153000 91000 112000 159000 171000 214000 193000 244000 35000 42600 43300 Vanadium 918000 1090000 730000 237000 461000 535000 577000 715000 972000 1080000 150000 205000 237000 Zinc 142000 224000 286000 200000 183000 169000 237000 318000 344000 406000 280000 350000 307000 Radiologies (pCi/L) 176000 Gross Alpha 8910 3400 8290 16300 15800 240000 (8/4/2015) 292000 133000 516000 261000 52400 122000 37800 (5/28/2015) Cell 4A Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 voes (ug/L) Acetone 60 55 100 25 28.4 <700 42.5 45.1 21.4 42.7 39 J 16.2 <25 Benzene <1 <1 <1 <1 <1 <5.0 <1 <1 <1 <1 <2.5 <1 <5 Carbon tetrachloride <1 <1 <1 <1 <1 <5.0 <1 <1 <1 <1 <2.5 <1 <5 Chloroform 4 8.5 10 <1 <1 <70.0 <1 <1 <1 1.91 1.9 J 1.50 <5 Chloromethane 3.4 5.5 7.9 <1 <1 <30.0 <1 <1 1.35 1.76 1.7 J 1.90 <5 MEK <1 <1 <1 <1 <20 <4000 <20 <20 <20 <20 13 J <5 <25 Methylene Chloride <1 <1 <1 <20 <1 <5.0 <1 <1 <1 <1 <2.5 <5 <25 Naphthalene 1.8 <1 <1 <1 <1 <100 <1 <1 <1 <1 <2.5 <1 <5 Tetrahydrofuran <100 <10 <10 1.36 <1 <46.0 <1 12.6 <1 <1 <35.0 <5 <25 Toluene <1 <1 <1 <1 <1 <1000 <1 <1 <1 <1 <2.5 <1 <5 Xylenes <1 <1 <1 <1 <1 <10000 <1 <1 <1 <1 <2.5 <3 <5 SVOCS (ug/L) 1,2,4-Trichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 1,2-Dichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 1,3-Dichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 1,4-Dichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 1-Methylnaphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3.0 <3 2,4,5-Trichlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2,4,6-Trichlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2,4-Dichlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2,4-Dimethylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2,4-Dinitrophenol <53 <20 <20 <20 <20 <20 <20 <10 <10 <8.57 <50 <50 <50 2,4-Dinitrotoluene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2,6-Dinitrotoluene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2-Chloronaphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <4.1 <4.10 2-Chlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2-Methylnaphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 2-Methylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 2-Nitrophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 3&4-Methylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <37 <37 3,3 '-Dichlorobenzidine <21 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <46 <33 <33 4,6-Dinitro-2-methylphenol <53 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <50 <30 <30 4-Bromophenyl phenyl ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 4-Chloro-3-methylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 4-Chlorophenyl phenyl ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 4-Nitrnphenol <53 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <50 <30 <30 Acenaphthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Acenaphthylene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Anthracene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 1.2 <3 <3 Azobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 Cell 4A Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Benz(a)anthracene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Benzidine <21 <10 <10 <10 <10 <10 <10 <10 <10 <8 .57 <10 <39 <39 Benzo(a)pyrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Benzo(b )fluoranthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Benzo(g,h,i)perylene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Benzo(k)fluoranthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 B is(2-chloroetho xy )methane <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <30 Bis(2-chloroethyl) ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 Bis(2-chloroisopropyl) ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <8 .57 <10 <30 <30 Bis(2-ethylhex_yl) phthalate <11 19.6 <10 <10 <10 <10 <10 <10 <10 <8 .57 <10 <3 <3 Butyl benzyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Chrysene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Dibenz( a,h)anthracene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8 .57 <10 <3 <3 Diethyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Dimethyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Di-n-buty 1 phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <8 .57 <10 <3 <3 Di-n-octyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Fluoranthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Fluorene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 IIexachlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 llexachlorobutadiene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <28 <30 <30 IIexachlorocyclopentadiene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 IIexachloroethane <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <28 <30 <30 Indeno( 1,2,3-cd)pyrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Isophorone <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <35 <35 Naphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Nitro benzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 N-Nitrosodimethylamine <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 N-Nitrosodi-n-propylamine <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 N-Nitrosodiphenylamine <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 Pentachlorophenol <53 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <50 <30 <30 Phenanthrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Phenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <30 <30 Pyrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <8.57 <10 <3 <3 Pyridine <11 <10 <10 <10 <10 <10 <10 <10 <10 34.0 <19 <30 <30 Cell 4A LDS Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Major Ions (mg/L) Carbonate <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 Bicarbonate <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5 Calcium 558 474 470 453 429 336 510 446 542 516 520 496 500 Chloride 7570 4670 6040 2710 1910 4200 2860 5200 8610 4360 7360 3860 6510 Fluoride 0.7 39.4 46 27 1970 1320 282 1150 1370 716 1530 500 2240 Magnesium 6390 3240 5100 2070 1710 2690 2730 3940 4630 3820 3800 3690 3780 Nitrogen-Ammonia 4480 2290 3480 1320 1010 2920 13.4 5050 846 4580 6080 3050 3680 Nitrogen-Nitrate 69 183 94 15 28.9 39 27.4 40.9 63.1 44.0 58.2 60.2 161 Potassium 1960 934 1500 503 305 415 245 675 1710 539 1000 334 635 Sodium 12600 6700 11000 3500 2930 4190 3490 8050 11500 6780 13000 5260 9550 Sulfate 92400 41700 77400 39600 31400 56000 50500 91300 89100 68600 72600 59900 72900 pH (s.u.) 1.98 2.53 2.32 2.1 2.32 2.4 2.29 2.04 1.50 1.88 2.39 2.25 2.4 TDS 117000 56900 93800 55400 49700 81900 65200 95400 142000 75300 112000 83800 105000 Conductivity (umhos/cm) 150000 49000 66600 39600 31300 53600 50200 62200 97900 63400 75600 53200 65900 Metals (ug/L) Arsenic 133000 54000 74700 44100 35700 51200 10400 43500 117000 42400 52000 16600 32300 Beryllium 536 295 367 180 188 185 199 289 479 298 370 317 323 Cadmium 4010 2650 3160 921 1170 4720 4270 4500 4080 3740 1900 4410 4220 Chromium 9140 3890 5940 3930 2630 2780 1760 4250 9410 3930 6500 2820 5200 Cobalt 37300 15200 21700 22300 44300 41200 33700 32100 42700 30600 25000 45800 73400 Copper 222000 116000 150000 481000 754000 439000 160000 331000 650000 376000 500000 273000 322000 Iron 3940000 1420000 2530000 2460000 1370000 1850000 1320000 2330000 5140000 2090000 2500000 1440000 1370000 Lead 5270 3400 4520 2300 165 991 46.8 797 15500 118 4200 254 1120 Manganese 389000 157000 207000 95200 86300 98600 96700 184000 296000 136000 190000 137000 195000 Mercury 2.66 6.2 14.7 0.7 <0.5 <0.0020 <0.5 <2.00 <2.00 <2.00 1.4 0.20 0.30 Molybdenum 49200 23900 29300 10200 1200 3970 278 10700 49900 2350 8400 2190 4090 Nickel 43900 23900 29600 35000 54600 99300 86300 72700 74700 70900 46000 110000 67700 Selenium 5250 2820 3780 1260 1020 2170 649 1590 4940 1550 3100 1230 1960 Silver 204 62 127 44 24.8 <100 25.6 144 312 <100 230 150 212 Thallium 252 194 290 332 171 522 218 439 550 281 55 425 245 Tin 504 180 119 <100 <100 <17000 <100 <17000 <17000 <17000 <70 <500 <50 Uranium 284000 145000 168000 90200 75000 82200 25000 116000 247000 78600 38000 48000 76000 Vanadium 1150000 518000 770000 240000 157000 510000 253000 449000 1090000 475000 130000 374000 458000 Zinc 298000 152000 204000 181000 163000 306000 510000 502000 385000 446000 210000 541000 380000 Radiologies (pCi/L) 17200 Gross Alpha 7020 3230 7440 4730 6930 61800 (8/4/2015) 98700 176000 51000 163000 5450 23700 1670 (5/28/2015) Cell 4A LDS Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 voes (ug/L) Acetone 240 130 120 55 57 <700 84.7 61.5 79.8 108 84 90.3 262 Benzene <1 <1 <1 <1 <1 <5.0 <1 <1 <1 <1 <1 <5 <5 Carbon tetrachloride <1 <1 <1 <1 <1 <5.0 <1 <1 <1 <1 <1 <5 <5 Chloroform 23 52 26 42 110 95 129 84.5 21.6 33.8 31 120 47.2 Chloromethane 7.9 13 3.8 6 9.93 <30.0 5.35 <1.00 3.00 2.41 3.6 6.90 <5 MEK 78 50 82 36 <20 <4000 <20 <20 <20 <20 43 29.5 92.2 Methylene Chloride <1 <1 <1 <1 <1 <5.0 <1 <1 <1 1.05 0.47 J <25 <25 Naphthalene <1 1.5 <1 1 2.35 <100 <1 <1 <1 <1 <1 <5 <5 Tetrahydrofuran 140 158 102 117 39.1 <46.0 18.5 <1 15.7 19.7 16 <25 <25 Toluene <1 <1 <1 <1 <1 <1000 <1 <1 <1 <1 <1 <5 <5 Xylenes <1 <1 <1 <1 <1 <10000 <1 <1 <1 <1 <1 <15 <15 SVOCS (ug/L) 1,2,4-Trichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 1,2-Dichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 1,3-Dichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 1,4-Dichlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 1-Methy lnaphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3.0 <3 2,4,5-Trichlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 2,4,6-Trichlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 2,4-Dichlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 2,4-Dimethylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 11.1 <10 <30 <30 2,4-Dinitrophenol <54 <20 <20 <20 <20 <20 <20 <10 <10 <9.08 <50 <50 <50 2,4-Dinitrotoluene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 2,6-Dinitrotoluene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 2-Chloronaphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <4.1 <4.10 2-Chlorophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 2-Methylnaphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 2-Methylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 2-Nitrophenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 3&4-Methylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <37 <37 3,3 '-Dichlorobenzidine <22 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <46 <33 <33 4,6-Dinitro-2-methylphenol <54 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <50 <30 <30 4-Bromophenyl phenyl ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 4-Chloro-3-methylphenol <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 4-Chloro_phenyl phenyl ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 4-Nitrophenol <54 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <50 <30 <30 Acenaphthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Acenaphthylene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Anthracene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Azobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 -<30 <30 Cell 4A LDS Chemical and Radiological Characteristics Constituent 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Benz( a)anthracene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Benzidine <22 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <39 <39 Benzo( a)pyrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Benzo(b )fluoranthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Benzo(g,h,i)perylene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Benzo(k)fluoranthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 B is(2-chloroethoxy )methane <11 -<10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <30 Bis(2-chloroethyl) ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 Bis(2-chloroisopropyl) ether <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 Bis(2-ethylhexyl) phthalate <11 54.9 54.9 16.6 <10 <10 <10 <10 <10 <9.08 1.1 <3 <3 Butyl benzyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Chrysene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Dibenz( a,h)anthracene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Diethyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Dimethyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Di-n-butyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Di-n-octyl phthalate <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Fluoranthene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Fluorene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Hexachlorobenzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 Hexachlorobutadiene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <28 <30 <30 Hexachlorocyclopentadiene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 Hexachloroethane <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <28 <30 <30 Indeno( 1,2,3-cd)pyrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Isophorone <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <35 <35 Naphthalene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Nitro benzene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 N-Nitrosodimethy !amine <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 N-Nitrosodi-n-propylamine <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 N-Nitrosodiphenylamine <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 Pentachlorophenol <54 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <50 <30 <30 Phenanthrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Phenol 33 23.5 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <30 <30 Pyrene <11 <10 <10 <10 <10 <10 <10 <10 <10 <9.08 <10 <3 <3 Pyridine <11 <10 <10 <10 <10 <10 <10 <10 <10 12.9 <19 <30 <30 Cell 4B Chemical and Radiological Characteristics Constituent 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Major Ions (mg/L) Carbonate <1 <l <l <l <l <l <l <l <5 <5 <5 Bicarbonate <l <l <l <l <l <l <1 <I <5 <5 <5 Calcium 570 580 662 366 655 523 473 664 670 628 534 Chloride 8290 8170 4570 7300 8500 12000 6930 7860 10500 10200 44800 Fluoride 26 .7 23.3 1050 1150 1210 1780 1170 1410 2300 1730 7000 Magnesium 3910 4500 3560 3310 5530 5780 3550 5790 6500 4520 8200 Nitrogen-Ammonia 5220 5580 2060 5380 1.09 8690 724 7590 8150 6580 9100 Nitrogen-Nitrate 39 42 51.4 47 15.2 64.5 31.3 42.2 38.6 70.0 286 Potassium 1370 1650 1110 989 1700 1710 1230 1660 1900 1680 3540 Sodium 9050 11700 3150 7100 12800 14100 10600 15700 18000 17100 54000 Sulfate 134000 119000 98100 91500 108000 285000 708000 98400 124000 97200 259000 pH (s.u.) 1.87 1.5 1.65 1.6 1.35 1.26 1.41 1.24 1.53 2.24 1.2 TDS 98000 128000 108000 131000 149000 172000 103000 117000 180000 150000 423000 Conductivity (umhos/cm) 76900 86900 72800 90100 115000 116000 93800 107000 99600 87300 109000 Metals (ug/L) Arsenic 67400 80000 65400 70400 106000 139000 82700 97800 140000 67900 307000 Beryllium 311 356 334 275 430 557 347 407 640 455 1280 Cadmium 1990 2540 1990 2290 2980 4260 2340 2520 2000 1800 6760 Chromium 6860 8280 6390 6940 7450 11900 7800 8630 12000 9350 16600 Cobalt 17800 29300 21300 24600 33700 46700 30300 32900 44000 30900 39700 Copper 193000 340000 340000 368000 499000 684000 457000 539000 830000 602000 1170000 Iron 2960000 3580000 2830000 2480000 4340000 6340000 3690000 4400000 5800000 3690000 7610000 Lead 9960 11600 9820 10900 13400 17900 12200 12500 16000 8150 26000 Manganese 128000 148000 154000 129000 231000 325000 207000 242000 320000 201000 602000 Mercury 13.7 2.6 1.49 <0.0020 1.72 <2.00 <2.00 <2.00 0.46 0.40 8.6 Molybdenum 21400 27600 26100 29000 39800 55400 22600 27400 29000 8110 95600 Nickel 33900 50500 35100 42000 56400 79600 53000 57800 78000 56400 48900 Selenium 4670 4470 3900 5010 5600 7300 3740 4510 6600 3540 9080 Silver 137 169 137 142 195 307 <100 160 170 76 741 Thallium 237 368 243 258 408 559 17.5 33 .7 <100 165 2160 Tin 196 215 163 <17000 211 <17000 <17000 <17000 340 138 879 Uranium 133000 171000 110000 133000 200000 278000 23100 28100 36000 47400 279000 Vanadium 660000 783000 163000 666000 881000 868000 746000 828000 710000 113000 1060000 Zinc 191000 270000 184000 144000 313000 476000 267000 323000 280000 334000 475000 Radiologies (pCi/L) 267000 Gross Alpha 8590 13600 14600 148000 (8/4/2015) 42500 262000 132000 320000 310000 54500 87400 (5/28/2015) voes (ug/L) Acetone 130 94 43.5 <700 56.2 86.4 38.6 56 .8 39 12.7 97.6 Benzene <1 <1 <l <5.0 <1 <1 <l <l <l <I <5 Carbon tetrachloride <1 <1 <l <5.0 <l <l <1 <1 <1 <1 <5 Chloroform 9.4 4 8.06 <70.0 2.34 3.07 2.39 2.17 3.4 <I <5 Chloromethane 8.5 8 7.12 <30.0 3.62 6.01 1.26 1.72 2.1 1.28 <5 MEK <l <l <20 <4000 <20 <20 <20 27.4 15 J <5 57 Cell 4B Chemical and Radiological Characteristics Constituent 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Methylene Chloride <1 <1 <1 <5.0 <1 <1 <1 <l <1 <5 <25 Naphthalene <1 <l <1 <100 <1 <1 <1 <l <1 <1 <5 Tetrahydrofuran <10 11.1 <1 <46.0 <l <1 <1 1.87 <35.0 <5 164 Toluene <1 <1 <1 <1000 <l <l <1 <l <1 <1 <5 Xvlenes <1 <l <l <10000 <1 <l <l <1 <1 <3 <15 SVOCS (ug/L) 1,2,4-Trichlorobenzene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 1,2-Dichlorobenzene <10 <10 <10 <10 <10 <10 <10 <8 .72 <10 <30 <30 1,3-Dichlorobenzene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 1,4-Dichlorobenzene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 1-Methylnaphthalene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3.0 <3 2,4,5-Trichlorophenol <10 <10 <10 <10 <10 <10 <10 <8 .72 <10 <30 <30 2,4,6-Trichlorophenol <10 <10 <10 <10 <10 <10 <10 <8 .72 <10 <30 <30 2,4-Dichlorophenol <10 <10 <10 <10 <10 <10 <10 <8 .72 <50 <30 <30 2,4-Dimethylphenol <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 2,4-Dinitrophenol <20 <20 <20 <20 <20 <10 <10 <8.72 <10 <50 <50 2,4-Dinitrotoluene <10 <10 <10 <10 <10 <10 <10 <8 .72 <10 <30 <30 2,6-Dinitrotoluene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 2-Chloronaphthalene <10 <10 <10 <10 <10 <10 <10 <8 .72 <10 <4.1 <4.10 2-Chlorophenol <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 2-Methy !naphthalene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 2-Methylphenol <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 2-Nitrophenol <10 <10 <10 <10 <10 <10 <10 <8 .72 <10 <30 <30 3&4-Methylphenol <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <37 <37 3,3 '-Dichlorobenzidine <10 <10 <10 <10 <10 <10 <10 <8 .72 <44 <33 <33 4,6-Dinitro-2-methylphenol <10 <10 <10 <10 <10 <10 <10 <8 .72 <50 <30 <30 4-Bromophenyl phenyl ether <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 4-Chloro-3-methylphenol <10 <10 <10 <10 <10 <10 <10 <8 .72 <10 <30 <30 4-Chlorophenyl phenyl ether <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 4-Nitrophenol <10 <10 <10 <10 <10 <10 <10 <8 .72 <50 <30 <30 Acenaphthene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Acenaphthylene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Anthracene <10 <10 <10 <10 <10 <10 <10 <8.72 1.7 <3 <3 Azobenzene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 Benz(a)anthracene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <30 Benzidine <10 <10 <10 26 <10 <10 <10 <8.72 <10 <39 <39 Benzo(a)pyrene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <30 Benzo(b )fluoranthene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <30 Benzo(g,h,i)perylene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <30 Benzo(k)fluoranthene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <30 B is(2-chloroethoxy )methane <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <30 Bis(2-chloroethyl) ether <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 Cell 4B Chemical and Radiological Characteristics Constituent 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Bis(2-chloroisopropyl) ether <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 Bis(2-ethylhexyl) phthalate 410 19 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Butyl benzyl phthalate <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Chrysene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Dibenz( a,h)anthracene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Diethyl phthalate <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Dimethyl phthalate <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Di-n-butyl phthalate <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Di-n-octyl phthalate <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Fluoranthene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Fluorene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Hexachlorobenzene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 Hexachlorobutadiene <10 <10 <10 <10 <10 <10 <10 <8.72 <26 <30 <30 Hexachlorocyclopentadiene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 Hexachloroethane <10 <10 <10 <10 <10 <10 <10 <8.72 <26 <30 <30 Indeno( 1,2,3-cd)pyrene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Isophorone <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <35 <35 Naphthalene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Nitrobenzene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 N-Nitrosodimethylamine <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 N-Nitrosodi-n-propylamine <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 N-Nitrosodiphenylamine <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 Pentachlorophenol <10 <10 <10 <10 <10 <10 <10 <8.72 <50 <30 <30 Phenanthrene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Phenol <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <30 <30 Pyrene <10 <10 <10 <10 <10 <10 <10 <8.72 <10 <3 <3 Pyridine <10 <10 <10 15 <10 <10 <10 31.7 <18 <30 118 Cell 4B LDS Chemical and Radiological Characteristics Constituent 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Major Ions (mg/L) Carbonate <1 <1 dry <1 <1 <1 <1 <1 <5 <5 <5 Bicarbonate <1 <1 dry <1 <1 <1 <1 <1 <5 <5 <5 Calcium 486 456 dry 308 538 547 516 592 550 555 526 Chloride 3630 6850 dry 6900 7960 8510 10400 8060 8050 7630 9180 Fluoride 28.4 22 dry 970 1150 1290 1050 1480 1680 1550 1870 Magnesium 3230 3360 dry 3400 5190 4780 5370 5580 4800 4830 4850 Nitrogen-Ammonia 4260 4090 dry 5240 2.43 7540 739 7510 7080 5080 4280 Nitrogen-Nitrate 30 31 dry 43 16.6 49.6 63.9 47.4 41.2 39.5 67.5 Potassium 1130 1060 dry 952 1560 1360 2130 1620 1400 1350 1240 Sodium 8240 8080 dry 6920 11900 10800 13200 14500 13000 12600 12200 Sulfate 59900 99100 dry 82300 104000 163000 117000 100000 89500 88700 99000 pH (s.u.) 2.23 2.4 dry 2.2 1.51 1.88 1.44 1.35 1.73 1.89 2.0 TDS 85800 90200 dry 129000 131000 133000 168000 132000 131000 134000 132000 Conductivity (umhos/cm) 63000 62400 dry 76300 106000 68400 105000 104000 80800 77600 78000 Metals ( ug/L) Arsenic 54200 41200 dry 67800 98400 98800 135000 94100 89000 84900 74800 Beryllium 274 271 dry 282 411 430 559 416 470 483 318 Cadmium 1670 1740 dry 2290 2790 3250 4500 2610 2000 2060 2140 Chromium 6250 5930 dry 6160 7320 9470 13700 8980 9100 9620 8980 Cobalt 15600 19000 dry 23300 31100 33600 48900 31700 31000 32200 60300 Copper 176000 181000 dry 308000 458000 475000 681000 497000 550000 500000 423000 Iron 2450000 2120000 dry 2590000 4180000 4680000 5910000 4190000 4400000 4180000 3660000 Lead 6060 4420 dry 4120 10100 5860 14000 8770 7800 5110 1860 Manganese 118000 162000 dry 144000 222000 262000 346000 239000 240000 221000 213000 Mercury 12.3 3 dry 0.002 1.47 <2.00 <2.00 <2.00 0.1 lJ 0.10 <0.2 Molybdenum 16700 15000 dry 24300 36300 35500 52900 25900 27000 19800 14300 Nickel 30700 33700 dry 40100 52600 58100 84400 56100 59000 57900 52000 Selenium 3710 2880 dry 4080 5080 5310 6860 4500 4700 3950 3870 Silver 111 117 dry 119 179 224 266 156 170 173 142 Thallium 179 175 dry 336 354 414 427 245 87 98 123 Tin 332 <100 dry <17000 198 <17000 <17000 <17000 200 258 141 Uranium 111000 132000 dry 143000 185000 192000 269000 54200 31000 34600 29400 Vanadium 518000 428000 dry 671000 817000 847000 1260000 811000 760000 743000 683000 Zinc 172000 182000 dry 144000 296000 315000 443000 303000 280000 286000 244000 Radiologies (pCi/L) 375000 Gross Alpha 6000 7500 dry 181000 (8/4/2015) 185000 165000 305000 226000 54100 105000 52500 (5/28/2015) Cell 4B LDS Chemical and Radiological Characteristics Constituent 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 voes (ug/L) Acetone 390 370 drv <700 218 266 479 147 102 68.5 <25 Benzene <1 <1 dry <5.0 <1 <1 <1 <1 <1 <1 <5 Carbon tetrachloride <1 <1 dry <5.0 <1 <1 <1 <1 <1 <1 <5 Chloroform 20 19 dry <70.0 5.03 9.97 9.13 4.74 3.9 1.22 <5 Chloromethane 11 11 dry <30.0 9.72 10.8 7.16 2.4 2.3 <1 <5 MEK 240 180 dry <4000 71.8 53.6 89.4 34.6 71 42.8 <25 Methylene Chloride <1 <1 dry <5.0 <1 <1 1.01 <1 <1 <5 <25 Naphthalene <1 <1 dry <100 <1 <1 <1 <1 <1 <1 <5 Tetrahydrofuran 198 322 dry 75.6 36.6 75.9 51.2 17.3 53 96.5 <25 Toluene <1 <1 dry <1000 <1 <1 <1 <1 <1 <1 <5 Xylenes <1 <1 dry <10000 <1 <1 <1 <1 <1 <3 <15 SVOCS (ug/L) 1,2,4-Trichlorobenzene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 1,2-Dichlorobenzene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 1,3-Dichlorobenzene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 1,4-Dichlorobenzene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 1-Methylnaphthalene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3.0 <3 2,4,5-Trichlorophenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2,4,6-Trichlorophenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2,4-Dichlorophenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2,4-Dimethylphenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2,4-Dinitrophenol <20 <20 dry <20 <20 <20 <10 <8.79 <50 <50 <50 2,4-Dinitrotoluene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2,6-Dinitrotoluene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2-Chloronaphthalene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <4.1 <4.10 2-Chlorophenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2-Methylnaphthalene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 2-Methylphenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 2-Nitrophenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 3&4-Methylphenol <10 <10 dry <10 <10 <10 <10 <8.79 0.42 <37 <37 3,3 '-Dichlorobenzidine <10 <10 dry <10 <10 <10 <10 <8.79 <45 <33 <33 4,6-Dinitro-2-methylphenol <10 <10 dry <10 <10 <10 <10 <8.79 <50 <30 <30 4-Bromophenyl phenyl ether <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 4-Chloro-3-methylphenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 4-Chlorophenyl phenyl ether <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 4-Nitrophenol <10 <10 dry <10 <10 <10 <10 <8.79 <50 <30 <30 Acenaphthene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Acenaphthylene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Anthracene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Azobenzene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 Cell 4B LDS Chemical and Radiological Characteristics Constituent 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Benz(a)anthracene <10 <10 drv <10 <10 <10 <10 <8.79 <10 <3 <3 Benzidine <10 <10 dry <10 <10 <10 <10 <8.79 <10 <39 <39 Benzo(a)pyrene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Benzo(b )fluoranthene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Benzo(g,h,i)perylene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Benzo(k)fluoranthene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Bis(2-chloroethoxy )methane <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <30 Bis(2-chloroethyl) ether <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 Bis(2-chloroisopropyl) ether <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 Bis(2-ethylhexyl) phthalate 191 191 dry 27 <10 132 145 65.9 16 <3 43.1 Butyl benzyl phthalate <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Chrysene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Dibenz(a,h)anthracene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Diethyl phthalate <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Dimethyl phthalate <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Di-n-butyl phthalate <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Di-n-octyl phthalate <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Fluoranthene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Fluorene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Hexachlorobenzene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 Hexachlorobutadiene <10 <10 dry <10 <10 <10 <10 <8.79 <27 <30 <30 Hexachlorocyclopentadiene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 Hexachloroethane <10 <10 dry <10 <10 <10 <10 <8.79 <27 <30 <30 Indeno( 1,2,3-cd)pyrene <10 <10 drv <10 <10 <10 <10 <8.79 <10 <3 <3 Isophorone <10 <10 dry <10 <10 <10 <10 <8.79 <10 <35 <35 Naphthalene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Nitrobenzene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 N-Nitrosodimethy !amine <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 N-Nitrosodi-n-propylamine <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 N-Nitrosodiphenylamine <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 Pentachlorophenol <10 <10 dry <10 <10 <10 <10 <8.79 <50 <30 <30 Phenanthrene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Phenol <10 <10 dry <10 <10 <10 <10 <8.79 <10 <30 <30 Pyrene <10 <10 dry <10 <10 <10 <10 <8.79 <10 <3 <3 Pyridine <10 <10 dry <10 <10 <10 <10 29.1 <18 <30 146 Cell I Additional RadiologicaJ Analyses Thorium-228 Thorium-230 Thorium-232 Radium-226 Uranium-233/234 Uranium-235/236 Uranium-238 Specific Gravity <nCi/L) (nCi/L) (pCi/L) (pCi/L) <nCi/L) <nCi/L) (pCi/L) 8/4/15 1310 991000 6150 1110 141000 8920 140000 1.21 5/28/15 204 782000 6730 829 96700 5980 100000 1.13 8/30/16 ND 677000 4480 497 2380 45800 1.15 8/29/17 2890 8100000 76000 391 353000 20400 344000 1.17 8/1 /18 ND 856000 8410 443 97300 6970 97200 1.16 8/21/19 1380 747000 4780 348 28400 1650 28700 1.15 8/21/2019 (Cell 65 -1500 663000 5720 434 25500 1960 27700 1.15 Duplicate of Cell I) 8/19/20 1090 1030000 6670 801 68300 4020 64600 1.33 9/1/21 469 174000 1060 424 218000 11800 221000 1.38 9/1/2021 (Cell 65 -500 178000 946 281 212000 10300 223000 1.33 Duplicate of Cell 1) Thorium-228 Thorium-230 (pCi/L) (pCi/L) 8/4/15 ND 6680 8/30/16 ND 5050 8/29/17 ND 38500 8/1/2018 ND 7390 8/1/2018 (cell 65 - Duplicate ND 6860 of Cell 2 Slimes) 8/21/2019 ND 1750 8/19/2020 ND 5180 9/1/21 ND 2780 Cell 2 Slimes Drain Additional Radiological Analyses Thorium-232 Radium-226 Uranium- (pCi/L) (pCi/L) 233/234 (pCi/L) ND 36.6 11300 ND 52.4 11700 ND 51.2 111000 ND 36.2 14900 ND 29.8 10700 ND 62.5 9300 ND 86.0 8680 ND 63.0 9210 Uranium-Uranium-238 Specific Gravity 235/236 (pCi/L) (pCi/L) 858 10500 1.09 599 10700 1.03 ND 75600 1.07 ND 12500 1.07 3440 12600 1.06 484 9150 1.03 917 8760 1.08 582 9040 1.07 Cell 3 Add · itional R . I • acho og1cal Analyses Thorium-228 Thorium-230 Thorium-232 Radium-226 Uranium-Uranium-Uranium-238 Specific Gravity (pCi/L) (pCi/L) (pCi/L) (pCi/L) 233/234 (pCi/L) 235/236 (pCi/L) (pCi/L) 8/4/15 ND 123000 1640 448 184000 10300 191000 1.21 5/28/15 798 131000 1290 202 557000 37900 591000 1.29 8/30/16 983 72500 1670 584 1960000 130000 2060000 1.62 1S/5U/l 0 (cell 65 -ND Duplicate 67000 788 640 2520000 130000 2490000 1.53 of Cell 3) 8/29/17 ND ND ND 101 37600 ND 32800 0.989 8/1/18 ND 28100 2310 79.8 398000 . 24000 468000 1.21 8/21/19 ND 6610 ND 48.0 6640 ND 5780 1.07 8/19/20 Not Sampled -Dry 9/1/21 ND 31.2 ND ND 144 ND 209 0.984 Cell 4A Additional Radiological Analyses Thorium-228 Thorium-230 Thorium-232 Radium-226 Uranium-Uranium-Uranium-238 Specific Gravity (pCi/L) (pCi/L) (pCi/L) (pCi/L) 233/234 (pCi/L) 235/236 (pCi/L) (pCi/L) 8/4/15 ND 374000 3490 663 57500 3720 64400 1.11 5/28/15 327 405000 3440 ND 61200 4030 62700 1.07 5/28/2015 (Cell 65 - Duplicate 265 315000 3790 772 58600 3020 58300 NS of Cell 4A) 8/30/16 ND 466000 2870 1050 61100 3320 70900 1.10 8/29/17 ND 4450000 47700 759 637000 30600 692000 1.09 8/29/17 (Cell 65 - Duplicate ND 4080000 11000 822 602000 44900 616000 1.12 of Cell 4A) 8/1 /I 8 1970 539000 8230 59.2 88700 9900 86300 1.10 8/21/19 941 430000 2870 260 9350 674 10900 1.02 8/19/20 1040 521000 4130 395 17200 991 13700 1.10 8/19/2020 (Cell 65 - Duplicate ND 488000 2200 372 14100 1000 14300 1.11 of Cell 4A) 9/l /21 1000 662000 6240 686 18000 1150 17900 1.11 Thorium-228 Thorium-230 (pCi/L) (pCi/L) 8/4/15 ND 25300 5/28/15 ND 25300 8/30/16 ND 134000 8/29/17 ND 5410000 8/1/18 ND 76000 8/21/19 1060 366000 8/19/20 ND 39500 9/1 /21 462 101000 Cell 4A LDS Additional R:1diologicaJ Analyses Thorium-232 Radium-226 Uranium- (pCi/L) (pCi/L) 233/234 (pCi/L) ND 19.3 9380 ND 19.3 9380 1130 51.1 46200 49200 286 852000 ND 38.2 28800 2230 73.4 13500 ND 18.6 19000 731 33.4 38200 Uranium-Uranium-238 Specific Gravity 235/236 (pCi/L) (pCi/L) 504 10800 1.07 504 10800 NS 1900 40400 1.10 66200 851000 1.17 ND 30500 1.05 738 13000 1.02 711 16600 1.07 1720 37500 1.08 Cell 4B Additional Radiological Amdyses Thorium-228 Thorium-230 Thorium-232 Radium-226 Uranium-233/234 Uranium-235/236 Uranium-238 Specific Gravity (nCi/L) (nCi/L) fnCi/L) (nCi/L) (oCi/L) (nCi/L) fnCi/L) 8/4/15 ND 410000 2210 611 63500 3710 67000 1.12 5/28/15 122 346000 3790 544 65000 3870 66100 1.08 8/30/16 ND 595000 3510 715 90200 4090 90100 1.13 8/29/17 ND 3390000 56000 489 76000 8100 92700 1.07 8/1/18 ND 461000 7360 307 13700 ND 8420 1.08 8/21/19 1080 434000 3490 296 11600 563 10800 1.10 8/19/20 1280 606000 4320 360 17000 1080 17700 1.11 9/1/21 1590 523000 3240 495 58400 3780 60000 1.25 Thorium-228 Thorium-230 (nCi/L) (nCi/L) 8/4/15 ND 452000 8/4/15 (Cell 65 - Duplicate ND 436000 ofCell 4B LOS) 5/28/15 334 487000 8/30/16 ND 368000 8/29/17 4680 5220000 8/1/18 1520 424000 8/21/19 1030 368000 8/19/20 888 541000 9/1/21 803 452000 Cell 4B LDS Additional Radiological AnaJyses Thorium-232 Radium-226 Uranium- (nCi/L) (oCi/L) 233/234 (oCi/L) 3660 161 62600 4000 125 62600 5430 55.2 63500 1010 104 78600 43200 143 846000 5130 88.3 14300 2650 105 8840 4070 153 11700 3110 174 10700 Uranium-235/236 Uranium-238 Specific Gravity <oCi/L) (oCi/L) 3890 60900 1.12 2680 61300 1.12 3900 65500 NS 3820 78900 1.11 64200 894000 1.07 ND 18400 1.09 412 9600 1.05 749 14500 1.11 631 11400 1.10 Appendix F Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan 07 /11 Revision: Denison 2.3 07/2011 Revision Denison 2.3 Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan. TABLE OF CONTENTS 1.0 Introduction .............................................................................................................. 2 2.0. Cell Design ............................................................................................................... 2 2.1 Cell 4A Design ................................................................................................. 2 2.2 Cell 4B Design .................................................................................................. 5 3.0 Cell Operation .......................................................................................................... 8 3.1 Solution Discharge to Cell 4A .......................................................................... 8 3.2 Solution Discharge to Cell 4B .......................................................................... 8 3.3 Initial Solids Discharge into Cell 4A ................................................................ 9 3.4 Initial Solids Discharge into Cell 4B ................................................................ 9 3.5 Equipment Access to Cell 4A and Cell 4B ..................................................... 10 3.6 Reclaim Water System at Cell 4A .................................................................. 10 3.7 Reclaim Water System at Cell 4B .................................................................. 10 3.8 Interim Solids Discharge to Cell 4A. .............................................................. 11 3.9 Interim Solids Discharge to Cell 4B ............................................................... 11 3.10 Liner Maintenance and QA/QC for Cell 4A ............................................... 11 3.11 Liner Maintenance and QA/QC for Cell 4B ............................................... 11 4.0 BAT Performance Standards for Tailings Cell 4A and 4B .................................... 11 5.0 Routine Maintenance and Monitoring ................................................................... 13 5.1 Solution Elevation .......................................................................................... 13 5.2 Leak Detection System ................................................................................... 13 5.3 Slimes Drain System ...................................................................................... 15 6.0 Tailings Emergencies ............................................................................................. 16 7.0 Solution Freeboard Calculations ............................................................................ 16 8.0 List of Attachments ................................................................................................ 18. S:\Environmental\UT\WhiteMesaMill\Cell 4B\Tuly 2011 Bat O&M Plan Revision 2.3\Tuly 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page 1 07/2011 Revision Denison 2.3 1.0 Introduction Construction of Cell 4A was authorized by the Utah Department of Environmental Quality, Division of Radiation Control ("DRC) on June 25, 2007. The construction authorization provided that Cell 4A shall not be in operation until after a BAT Monitoring, Operations and Maintenance Plan is submitted for Executive Secretary review and approval. The Plan shall include requirements in Part I.F.3 of the Groundwater Discharge Permit No. UGW370004 ("GWDP") and fulfill the requirements of Parts I.D.6, I.E.8, and I.F.9 of the GWDP. Construction of Cell 4B was authorized by DRC on June 21, 2010. The construction authorization provided that Cell 4B shall not be in operation until after a BAT Monitoring, Operations and Maintenance Plan is submitted for Executive Secretary review and approval. The Plan shall include requirements in Part I.F.3 of the GWDP and fulfill the requirements of Parts I.D.12, I.E.12, and I.F.9 of the GWDP 2.0 Cell Design 2.1 Cell 4A Design Tailings Cell 4A consists of the following major elements: a) Dikes -consisting of earthen embankments of compacted soil, constructed between 1989-1990, and composed of four dikes, each including a 15-foot wide road at the top (minimum). On the north, east, and south margins these dikes have slopes of 3H to 1 V. The west dike has an interior slope of 2H to 1 V. Width of these dikes varies; each has a minimum crest width of at least 15 feet to support an access road. Base width also varies from 89-feet on the east dike (with no exterior embankment), to 211-feet at the west dike. b) Foundation -including subgrade soils over bedrock materials. Foundation preparation included excavation and removal of contaminated soils, compaction of imported soils to a maximum dry density of 90%. Floor of Cell 4A has an average slope of 1 % that grades from the northeast to the southwest corners. c) Tailings Capacity -the floor and inside slopes of Cell 4A encompass about 40 acres and have a maximum capacity of about 1.6 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: 1) Primary Flexible Membrane Liner (FML) -consisting of impermeable 60 S:\Environmental\U1\WhiteMesaMill\Cell 4B\Tuly 2011 Bat O&M Plan Revision 2.3\Tuly 2011 BAT O and M Revision for permit\Cell 4A and 48 0 M Plan Rev 2.2 July 2011 clean.doc Page 2 07/2011 Revision Denison 2.3 mil high density polyethylene (HOPE) membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML will be in direct physical contact with the tailings material over most of the Cell 4A floor area. In other locations, the primary FML will be in contact with the slimes drain collection system (discussed below). S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page3 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 2) Leak Detection System -includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4A, and drains to a leak detection sump in the southwest corner. Access to the leak detection sump is via an 18-inch inside diameter (ID) PVC pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe will be surrounded with a gravel filter set in the leak detection sump, having dimensions of 10 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer will be enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. 3) Secondary FML -consisting of an impermeable 60-mil HOPE membrane found immediately below the leak detection geonet. Said FML also extends across the entire Cell 4A floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. 4) Geosynthetic Clay Liner -consisting of a manufactured geosynthetic clay liner (GCL) composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. Prior to disposal of any wastewater in Cell 4A, the Permittee shall demonstrate that the GCL has achieved a moisture content of at least 50% by weight. This item is a revised requirement per DRC letter to DUSA dated September 28,2007 e) Slimes Drain Collection System -including a two-part system of strip drains and perlorated collection pipes both installed immediately above the primary FML, as follows: 1) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4A that drain to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated two-part gee-composite drain material (solid polymer drainage strip) _ core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southwesterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. 2) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection (SOC) pipe found at the downgradient end of the strip drain lines. This pipe is in tum overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted laterally by sandbags on each side of the backbone of the berm. S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page4 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast corner downhill to the far southwest corner of Cell 4A where it joins the slimes drain access pipe. 3) Slimes Drain Access Pipe -consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4A at the southwest corner, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and nonwoven geotextile that serves as a cushion to protect the primary FML. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted by sandbags.A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. t) Dike Splash Pads -A minimum of eight (8) 20-foot wide splash pads are installed on the interior dike slopes to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HDPE membrane that is placed down the inside slope of Cell 4A, from the top of the dike and down the inside slope. The pads extend to a point 5-feet beyond the toe of the slope to protect the liner bottom during initial startup of the Cell. The exact location of the splash pads is detailed on the As-Built Plans and Specifications. g) Rub Protection Sheets -In addition to the splash pads described in f) above, rub sheets are installed beneath all piping entering or exiting Cell 4A that is not located directly on the splash pads. h) Emergency Spillway -a concrete lined spillway constructed near the western corner of the north dike to allow emergency runoff from Cell 3 into Cell 4A. This spillway will be limited to a 6-inch reinforced concrete slab set directly over the primary FML in a 4-foot deep trapezoidal channel. A second spillway has been constructed in the southwest corner of Cell 4A to allow emergency runoff from Cell 4A into Cell 4B. All stormwater runoff and tailings wastewaters not retained in Cells 3 and 4A, will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. 2.2 Cell 4B Design Tailings Cell 4B consists of the following major elements: a) Dike -consisting of a newly-constructed dike on the south side of the cell with a 15-foot wide road at the top (minimum) to support an access road. The grading plan for the Cell 4B excavation includes interior slopes of 2H to 1 V. The exterior slope of the southern dike will have the typical slopes of 3H to 1 V. Limited portions of the Cell 4B interior sideslopes in the S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page5 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 northwest corner and southeast corner of the cell (where the slimes drain and leak detection sump will be located) will also have a slope of 3H to 1 V. The base width of the southern dike varies from approximately 100 feet at the western end to approximately 190 feet at the eastern end of the dike, with no exterior embankment present on any other side of the cell. b) Foundation -including sub grade soils over bedrock materials. Foundation preparation included 6-inch over excavation of rock and placement and compaction of imported soils to a maximum dry density of 90% at a moisture content between +3% and -3% of optimum moisture content, as determined by ASTM D-1557. The floor of Cell 4B has an average slope of 1 % that grades from the northwest corner to the southeast corner. c) Tailings Capacity -the floor and inside slopes of Cell 4B encompass about 45 acres and the cell will have a water surface area of 40 acres and a maximum capacity of about 1.9 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: 1) Primary Flexible Membrane Liner (FML) -consisting of 60 mil high density polyethylene (HDPE) membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML will be in direct physical contact with the tailings material over most of the Cell 4B floor area. In other locations, the primary FML will be in contact with the slimes drain collection system (discussed below). 2) Leak Detection System -includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4B, and drains to a leak detection sump in the southeast corner. Access to the leak detection sump is via an 18-inch inside diameter (ID) PVC pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe will be surrounded with a gravel filter set in the leak detection sump, having dimensions of 10 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer will be enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. 3) Secondary FML -consisting of a 60-mil HDPE membrane found immediately below the leak detection geonet. Said FML also extends across the entire Cell 4B floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. 4) Geosynthetic Clay Liner -consisting of a manufactured geosynthetic clay liner (GCL) composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. Prior to disposal of any wastewater in Cell 4B, the Permittee shall demonstrate that the GCL has achieved a moisture content of at least 50% by weight. S:\Environmental\U1\WhiteMesaMill\Cell 4B\Tuly 2011 Bat O&M Plan Revision 2.3\Tuly 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page6 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 e) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: 1) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4B that drain to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated two-part geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southeasterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. 2) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection (SDC) pipe found at the downgradient end of ~he strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted by sandbags. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northwest comer downhill to the far southeast corner of Cell 48 where it joins the slimes drain access pipe. 3) Slimes Drain Access Pipe -consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4B at the southeast corner, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and non-woven geotextile that serves as a cushion to protect the primary FML. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted laterally by sandbags on each side of the backbone of the berm. A reducer connects the horizontal 18- inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. f) Cell 4B North and East Dike Splash Pads -Nine 20-foot-wide splash pads will be constructed on the north and east dikes to protect the primary FML from abrasion and scouring by tailings slurry. These pads will consist of an extra layer of textured, 60 mil HOPE membrane that will be installed in the anchor trench and placed down the inside slope of Cell 4B, from the top of the dike, under the inlet pipe, and down the inside slope to a point at least 5 feet onto the Cell 4B floor beyond the toe of the slope. S:\Environmental\U1\WhiteMesaMill\Cell 48\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 48 0 M Plan Rev 2.2 July 2011 clean.doc Page? Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 g) Rub Protection Sheets -In addition to the splash pads described in f) above, rub sheets are installed beneath all piping entering or exiting Cell 4B that is not located directly on the splash pads. h) Emergency Spillway -a concrete lined spillway constructed near the southern corner of the east dike to allow emergency runoff from Cell 4A into Cell 4B. This spillway will be limited to a 6-inch reinforced concrete slab, with a welded-wire fabric installed within its midsection, set atop a cushion geotextile placed directly over the primary FML in a 4-foot deep trapezoidal channel. A 100 foot wide, 60 mil HDPE geomembrane splash pad will be installed beneath the emergency spillway. No other spillway or overflow structure will be constructed at Cell 4 B. All storm water runoff and tailings wastewaters not retained in Cells 2, 3 and 4A, will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. 3.0 Cell Operation 3.1 Solution Discharge to Cell 4A Cell 4A will initially be used for storage and evaporation of process solutions from the Mill operations. These process solutions will be from the uranium/vanadium solvent extraction circuit, or transferred from Cell 1 evaporation pond or the free water surface from Cell 3, or transferred from Cell 2 tailings dewatering operations. The solution will be pumped to Cell 4A through appropriately sized pipelines. The initial solution discharge will be in the southwest corner of the Cell. The solution will be discharged in the bottom of the Cell, away from any sand bags or other installation on the top of the FML. Building the solution pool from the low end of the Cell will allow the solution pool to gradually rise around the slimes drain strips, eliminating any damage to the strip drains or the sand bag cover due to solution flowing past the drainage strips. The solution will eventually be discharged along the dike between Cell 3 and Cell 4A, utilizing the Splash Pads described above. The subsequent discharge of process solutions will be near the floor of the pond, through a discharge header designed to discharge through multiple points, thereby reducing the potential to damage the Splash Pads or the Slimes Drain system. At no time, subsequent to initial filling, will the solution be discharged into less than 2 feet of solution. As the cell begins to fill with solution the discharge point will be pulled back up the Splash Pad and allowed to continue discharging at or near the solution level. 3.2 Solution Discharge to Cell 4B Cell 4B will initially be used for storage and evaporation of process solutions from the Mill operations. These process solutions will be from the uranium/vanadium solvent extraction circuit, or transferred from Cell 1 evaporation pond or the free water surface from Cell 3 or Cell 4A, or transferred S:\Environmental\U1\WhiteMesaMill\Cell 4B\Tuly 2011 Bat O&M Plan Revision 2.3\Tuly 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page8 CeJJ 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 from Cell 2 dewatering operations. The solution will be pumped to Cell 4B through appropriate sized pipelines pipelines. The initial solution discharge will be in the southeast corner of the Cell. The discharge pipe will be routed down the Splash Pad provided in the southeast corner of the Cell at the spillway to protect the primary FML. The solution will be discharged in the bottom of the Cell, away from any sand bags or other installation on the top of the FML. Building the solution pool from the low end of the Cell will allow the solution pool to gradually rise around the slimes drain strips, eliminating any damage to the strip drains or the sand bag cover due to solution flowing past the drainage strips. The solution will eventually be discharged along the dike between Cell 3 and Cell 4B, utilizing the Splash Pads described above. The subsequent discharge of process solutions will be near the floor of the pond, through a discharge header designed to discharge through multiple points, thereby reducing the potential to damage the Splash Pads or the Slimes Drain system. At no time, subsequent to initial filling, will the solution be discharged into less than 2 feet of solution. As the cell begins to fill with solution the discharge point will be pulled back up the Splash Pad and allowed to continue discharging at or near the solution level. 3.3 Initial Solids Discharge into Cell 4A Once Cell 4A is needed for storage for tailings solids the slurry discharge from No. 8 CCD thickener will be pumped to the cell through appropriately sized pipelines. The pipelines will be routed along the dike between Cell 3 and Cell 4A, with discharge valves and drop pipes extending down the Splash Pads to the solution level. One or all of the discharge points can be used depending on operational considerations. Solids will settle into a cone, or mound, of material under the solution level, with the courser fraction settling out closer to the discharge point. The initial discharge locations are shown on Figure lA. Figure 2A illustrates the general location of the solution and slurry discharge pipelines and control valve locations. The valves are 6" or 8" stainless steel knife-gate valves. The initial discharge of slurry will be at or near the toe of the Cell slope and then gradually moved up the slope, continuing to discharge at or near the water surface. This is illustrated in Section A-A on Figure 2A. Because of the depth of Cell 4A, each of the discharge points will be utilized for an extended period of time before the cone of material is above the maximum level of the solution. The discharge location will then be moved further to the interior of the cell allowing for additional volume of solids to be placed under the solution level. The solution level in the cell will vary depending on the operating schedule of the Mill and the seasonal evaporation rates. The tailings slurry will not be allowed to discharge directly on to the Splash Pads, in order to further protect the FML. The tailings slurry will discharge directly in to the solution contained in the Cell, onto an additional protective sheet, or on to previously deposited tailings sand. 3.4 Initial Solids Discharge into Cell 4B Once Cell 4B is needed for storage for tailings solids the slurry discharge from No. 8 CCD thickener will be pumped to the cell through appropriately sized S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page9 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 pipelines. The pipelines will be routed along the dike between Cell 3 and Cell 4B, with discharge valves and drop pipes extending down the Splash Pads to the solution level. One or all of the discharge points can be used depending on operational considerations. Solids will settle into a cone, or mound, of material under the solution level, with the courser fraction settling out closer to the discharge point. The initial discharge locations are shown on Figure lB. Figure 2B illustrates the general location of the solution and slurry discharge pipelines and control valve locations. The valves are 6" or 8" stainless steel knife-gate valves. The initial discharge of slurry will be at or near the toe of the Cell slope and then gradually moved up the slope, continuing to discharge at or near the water surface. This is illustrated in Section A-A on Figure 2B. Because of the depth of Cell 4B, each of the discharge points will be utilized for an extended period of time before the cone of material is above the maximum level of the solution. The discharge location will then be moved further to the interior of the cell allowing for additional volume of solids to be placed under the solution level. The solution level in the cell will vary depending on the operating schedule of the Mill and the seasonal evaporation rates. The tailings slurry will not be allowed to discharge directly on to the Splash Pads, in order to further protect the FML. The tailings slurry will discharge directly in to the solution contained in the Cell, onto an additional protective sheet, or on to previously deposited tailings sand. 3.5 Equipment Access to Cell 4A and Cell 4B Access will be restricted to the interior portion of the cells due to the potential to damage the flexible membrane liners. Only low pressure rubber tired all terrain vehicles or foot traffic will be allowed on the flexible membrane liners. Personnel are also cautioned on the potential damage to the flexible membrane liners through the use and handling of hand tools and maintenance materials. 3.6 Reclaim Water System at Cell 4A A pump barge and solution recovery system is operating in the southwest corner of the cell to pump solution from the cell for water balance pmposes or for re-use in the Mill process. Figure 3A illustrates the routing of the solution return pipeline and the location of the pump barge. The pump barge will be constructed and maintained to ensure that the flexible membrane liner is not damaged during the initial filling of the cell or subsequent operation and maintenance activities. The condition of the pump barge and access walkway will be noted during the weekly Cell inspections. 3.7 Reclaim Water System at Cell 4B A pump barge and solution recovery system will be installed in the southeast comer of the cell to pump solution from the cell for water balance purposes or for re-use in the Mill process. Figure 3B illustrates the routing of the solution return pipeline and the location of the pump barge. The pump barge will be constructed and maintained to ensure that the flexible membrane liner is not damaged during S:\Environmental\U1\WhiteMesaMill\Cell 4B\Tuly 2011 Bat O&M Plan Revision 2.3\Tuly 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page 10 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 the initial filling of the cell or subsequent operation and maintenance activities. The condition of the pump barge and access walkway will be noted during the weekly Cell inspections. 3.8 Interim Solids Discharge to Cell 4A Figure 4A illustrates the progression of the slurry discharge points around the north and east sides of Cell 4A. Once the tailings solids have been deposited along the north and east sides of the Cell, the discharges points will subsequently be moved to the sand beaches, which will eliminate any potential for damage to the liner system. 3.9 Interim Solids Discharge to Cell 4B Figure 4B illustrates the progression of the slurry discharge points around the north and east sides of Cell 4B. Once the tailings solids have been deposited along the north and east sides of the Cell, the discharges points will subsequently be moved to the sand beaches, which will eliminate any potential for damage to the liner system. 3.10 Liner Maintenance and QA/QC for Cell 4A Any construction defects or operational damage discovered during observation of the flexible membrane liner will be repaired, tested and documented according to the procedures detailed in the approved Revised Construction Quality Assurance Plan for the Construction of the Cell 4A Lining System, May 2007, by GeoSyntec Consultants. 3.11 Liner Maintenance and QA/QC for Cell 4B Any construction defects or operational damage discovered during observation of the flexible membrane liner will be repaired, tested and documented according to the procedures detailed in the approved Construction Quality Assurance Plan for the Construction of the Cell 4B Lining System, October 2009, by Geosyntec Consultants. 4.0 BAT Performance Standards for Tailings Cell 4A and 4B DUSA will operate and maintain Tailings Cell 4A and 4B so as to prevent release of wastewater to groundwater and the environment in accordance with this BAT Monitoring Operations and Maintenance Plan, pursuant to Part I.H.8 of the GWDP. These performance standards shall include: 1) Leak Detection System Pumping and Monitoring Equipment -the leak detection system pumping and monitoring equipment in each cell S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 201 l BAT O and M Revision for perm.it\Cell 4A and 48 0 M Plan Rev 2.2 July 2011 clean.doc Page 11 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 includes a submersible pump, pump controller, water level indicator (head monitoring), and flow meter with volume totalizer. The pump controller is set to maintain the maximum level in the leak detection system in each cell at no more than 1 foot above the lowest level of the secondary flexible membrane, not including the sump. A second leak detection pump with pressure transducer, flow meter, and manufacturer recommended spare parts for the pump controller and water level data collector is maintained in the Mill warehouse to ensure that the pump and controller can be replaced and operational within 24 hours of detection of a failure of the pumping system. The root cause of the equipment failure will be documented in a report to Mill management with recommendations for prevention of a re-occurrence. 2) Maximum Allowable Head -the Permittee shall measure the fluid head above the lowest point on the secondary flexible membrane in each cell by the use of procedures and equipment specified in the White Mesa Mill Tailings Management System and Discharge Minimization Technology (DMT) Monitoring Plan, 10/10 Revision: Denison-10.2, or the currently approved DMT Plan. Under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower flexible membrane liner, not including the sump. 3) Maximum Allowable Daily LDS Flow Rates -the Permittee shall measure the volume of all fluids pumped from each LDS on a weekly basis, and use that information to calculate an average volume pumped per day. Under no circumstances shall the daily LDS flow volume exceed 24,160 gallons/day for Cell 4A or 26,145 gallons/day for Cell 4B. The maximum daily LDS flow volume will be compared against the measured cell solution levels detailed on the attached Table lA or lB for Cells 4A or 4B, respectively, to determine the maximum daily allowable LDS flow volume for varying head conditions in the cell. 4) 3-foot Minimum Vertical Freeboard Criteria-the Permittee shall operate and maintain wastewater levels to provide a 3-foot Minimum of vertical freeboard in Tailings Cell 4A and Cell 4B. Said measurements shall be made to the nearest 0.1 foot. 5) Slimes Drain Recovery Head Monitoring -immediately after the Perrnittee initiates pumping conditions in the Tailings Cell 4A or Cell 4B slimes drain system, quarterly recovery head tests and fluid level measurements will be made in accordance with a plan approved by the DRC Executive Secretary. The slimes drain system pumping and monitoring equipment, includes a submersible pump, pump controller, water level indicator (head monitoring), and flow meter with volume totalizer. S:\Environmental\UT\WhiteMesaMill\Cell 48\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 48 0 M Plan Rev 2.2 July 2011 clean.doc Page 12 Cell 4A BAT Monitoring, Operations and Maintenance Plan 5.0 Routine Maintenance and Monitoring 01/21/2010 Revision Denison 2.2 Trained personnel inspect the White Mesa tailings system on a once per day basis. Any abnormal occurrences or changes in the system will be immediately reported to Mill management and maintenance personnel. The inspectors are trained to look for events involving the routine placement of tailings material as well as events that could affect the integrity of the tailings cell dikes or lining systems. The daily inspection reports are summarized on a monthly basis and reviewed and signed by the Mill Manager and RSO. 5.1 Solution Elevation Measurements of solution elevation in Cell 4A and Cell 4B are to be taken by survey on a weekly basis, and measurements of the beach area in Cell 4A and Cell 4B with the highest elevation are to be taken by survey on a monthly basis, by the use of the procedures and equipment specified in the latest approved edition of the DMTPlan. 5.2 Leak Detection System The Leak Detection System in Cell 4A and Cell 4B is monitored on a continuous basis by use of a pressure transducer that feeds water level information to an electronic data collector. The water levels are measured every hour and the information is stored for later retrieval. The water levels are measured to the nearest 0.10 inch. The data collector is currently programmed to store 7 days of water level information. The number of days of stored data can be increased beyond 7 days if needed. The water level data is downloaded to a laptop computer on a weekly basis and incorporated into the Mill's environmental monitoring data base, and into the files for weekly inspection reports of the tailings cell leak detection systems. Within 24 hours after collection of the weekly water level data, the information will be evaluated to ensure that: 1) the water level in the Cell 4A and Cell 4B leak detection sumps did not exceed the allowable level (5556.14 feet amsl in the Cell 4A LDS sump and 5558.5 feet amsl in the Cell 4B sump), and 2) the average daily flow rate from the LDS did not exceed the maximum daily allowable flow rate at any time during the reporting period. For Cell 4A and Cell 4B, under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower flexible membrane liner, not including the sump. To determine the Maximum Allowable Daily LDS Flow Rates in the Cell 4A and Cell 4B leak detection system, the total volume of all fluids pumped from the LDS of each cell on a weekly basis shall be recovered from the data collector, and that information will be used to calculate an average volume pumped per day for each cell. Under no circumstances shall the daily LDS flow volume exceed 24,160 gallons/day from Cell 4A or 26,145 gallons/day from Cell 4B. The S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 48 0 M Plan Rev 2.2 July 2011 clean.doc Page 13 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 maximum daily LDS flow volume will be compared against the measured cell solution levels detailed on the attached Tables lA and lB, to determine the maximum daily allowable LDS flow volume for varying head conditions in Cell 4A and Cell 4B. Any abnormal or out of compliance water levels must be immediately reported to Mill management. The data collector on each cell is also equipped with an visual strobe light that flashes on the control panel if the water level in the leak detection sump exceeds the allowable level (5556.14 feet amsl in the Cell 4A LDS sump and 5558.5 feet amsl in the Cell 4B sump). The current water level is displayed at all times on each data collector and available for recording on the daily inspection form. Each leak detection system is also equipped with a leak detection pump, EPS Model # 25S05- 3 stainless steel, or equal. Each pump is capable of pumping in excess of 25 gallons per minute at a total dynamic head of 50 feet. Each pump has a 1.5 inch diameter discharge, and operates on 460 volt 3 phase power. Each pump is equipped with a pressure sensing transducer to start the pump once the level of solution in the leak detection sump is approximately 2.25 feet (elevation 5555.89 in the Cell 4A LDS sump and 5557.69 feet amsl in the Cell 4B sump) above the lowest level of the leak detection sump (9 inches [0.75 feet] above the lowest point on the lower flexible membrane liner for Cell 4A and 2 1/4 inches [0.19 feet] for Cell 4B), to ensure the allowable 1.0 foot (5556.14 feet amsl in the Cell 4A LDS sump and 5558.5 feet amsl in the Cell 4B sump) above the lowest point on the lower flexible membrane liner is not exceeded). The attached Figures 6A and 6B (Cell 4A and 4B, respectively), Leak Detection Sump Operating Elevations, illustrates the relationship between the sump elevation, the lowest point on the lower flexible membrane liner and the pump-on solution elevation for the leak detection pump. The pump also has manual start and stop controls. The pump will operate until the solution is drawn down to the lowest level possible, expected to be approximately 4 inches above the lowest level of the sump (approximate elevation 5554.0 and 5555.77 ft amsl for Cells 4A and 48, respectively). The pump discharge is equipped with a 1.5 inch flow meter, EPS Paddle Wheel Flowsensor, or equal, that reads the pump discharge in gallons per minute, and records total gallons pumped. The flow rate and total gallons are recorded by the Inspector on the weekly inspection form. The leak detection pump is installed in the horizontal section of the 18 inch, perforated section of the PVC collection pipe. The distance from the top flange face, at the collection pipe invert, to the centerline of the 22.5 degree elbow is 133.4 feet in Cell 4A and 135.6 feet in Cell 4B, and the vertical height is approximately 45 feet in Cell 4A and approximately 42.5 feet in Cell 4B. The pump is installed at least 2 feet beyond the centerline of the elbow. The bottom of the pump will be installed in the leak detection sump at least 135.4 feet in Cell 4A and 137.6 feet in Cell 4B or more from the top of the flange invert. A pressure transducer installed within the pump continuously measures the solution head and 1s S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page 14 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 programmed to start and stop the pump within the ranges specified above. The attached Figure 5, illustrates the general configuration of the pump installation. A spare leak detection pump with pressure transducer, flow meter, and manufacturer recommended spare parts for the pump controller and water level data collector will be maintained in the Mill warehouse to ensure that the pump and controller on either cell can be replaced and operational within 24 hours of detection of a failure of the pumping system. The root cause of the equipment failure will be documented in a report to Mill management with recommendations for prevention of a re-occurrence. 5.3 Slimes Drain System (i) A pump, Tsurumi Model# KTZ23.7-62 stainless steel, or equal, will be placed inside of the slimes drain access riser pipe of each cell and a near as possible to the bottom of the slimes drain sump. The bottom of the slimes drain sump in Cell 4A and Cell 4B are 38 and 35.9 feet below a water level measuring point, respectively, at the centerline of the slimes drain access pipe, near the ground surface level. Each pump discharge will be equipped with a 2 inch flow meter, E/H Model #33, or equal, that reads the pump discharge in gallons per minute, and records total gallons pumped. The flow rate and total gallons will be recorded by the Inspector on the weekly inspection form. (ii) The slimes drain pumps will be on adjustable probes that allow the pumps to be set to start and stop on intervals determined by Mill management. (iii)The Cell 4A and Cell 4B slimes drain pumps will be checked weekly to observe that they are operating and that the level probes are set properly, which is noted on the Weekly Tailings Inspection Form. If at any time either pump is observed to be not working properly, it will be repaired or replaced within 15 days; (iv)Depth to wastewater in the Cell 4A and Cell 4B slimes drain access riser pipes shall be monitored and recorded weekly to determine maximum and minimum fluid head before and after a pumping cycle, respectively. All head measurements must be made from the same measuring point, to the nearest 0.01 foot. The results will be recorded as depth-in-pipe measurements on the Weekly Tailings Inspection Form; (v) After initiation of pumping conditions in Tailings Cell 4A or 4B, n a quarterly basis, each slimes drain pump will be turned off and the wastewater in the slimes drain access pipe will be allowed to stabilize for at least 90 hours. Once the water level has stabilized (based on no change in water level for three (3) successive readings taken no less than one (1) hour apart) the water level of the wastewater will be measured and recorded as a depth-in-pipe measurement on a Quarterly Data form, by measuring the depth to water below the water level measuring point on the slimes drain access pipe; S:\Environmental\UT\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page 15 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 The slimes drain pumps for each cell will not be operated until Mill management has determined that no additional process solutions will be discharged to that cell, and the cell has been partially covered with the first phase of the reclamation cap. The long term effectiveness and performance of the slimes drain dewatering will be evaluated on the same basis as the currently operating slimes drain system for Cell 2. 6.0 Tailings Emergencies Inspectors will notify the Radiation Safety Officer and/or Mill management immediately if, during their inspection, they discover that an abnormal condition exists or an event has occurred that could cause a tailings emergency. Until relieved by the Environmental or Radiation Technician or Radiation Safety Officer, inspectors will have the authority to direct resources during tailings emergencies. Any major catastrophic events or conditions pertaining to the tailings area should be reported immediately to the Mill Manager or the Radiation Safety Officer, one of whom will notify Corporate Management. If dam failure occurs, notify your supervisor and the Mill Manager immediately. The Mill Manager will then notify Corporate Management, MSHA (303-231-5465), and the State of Utah, Division of Darn Safety (801-538-7200). 7 .0 Solution Free board Calculations The maximum tailings cell pond wastewater levels in Cell 1, Cell 2, Cell 3, Cell 4A, and Cell 4B are regulated by condition 10.3 of the White Mesa Mill 1 le.(2) Materials License. However, freeboard limits are no longer applicable to Cell 2, Cell 3, and Cell 4A, as discussed below. Condition 10.3 states that "Freeboard limits, stormwater and wastewater management for the tailings cells shall be determined as follows: A. The freeboard limit for Cell 1 shall be set annually in accordance with the procedures set out in Section 3.0 to Appendix E of the previously approved NRC license application, including the January 10, 1990 Drainage Report. Discharge of any surface water or wastewater from Cell 1 is expressly prohibited. B. The freeboard limit for Cell 4B shall be recalculated annually in accordance with the procedures established by the Executive Secretary. Said calculations for freeboard limits shall be submitted as part of the Annual Technical Evaluation Report (ATER), as described in Condition 12.3 below [of the license and not included herein]. Based on approved revisions to the DMT Plan dated January 2011, the freeboard limit is no longer applicable to Cells 2, S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page 16 Cell 4A BAT Monitoring, Operations and Maintenance Plan 3 and4A. 01/21/2010 Revision Denison 2.2 C. The discharge of any surface water, stormwater, or wastewater from Cells 3, 4A, and 48 shall only be through an Executive Secretary authorized spillway structure. [Applicable NRC Amendment: 16] [Applicable UDRC Amendment: 3] [Applicable UDRC Amendment:4]" The freeboard limits set out in Section 6.3 of the DMT Plan are intended to capture the Local 6-hour Probable Maximum Precipitation (PMP) event, which was determined in the January 10, 1990 Drainage Report for the White Mesa site to be 10 inches. Based on the PMP storm event, the freeboard requirement for Cell 1 is a maximum operating water level of 5615.4 feet above mean sea level (amsl). The Cell 1 freeboard limit is not affected by operations or conditions in Cells 2, 3, 4A, or 48. Cells 2 and 3 have no freeboard limit because those Cells are full or near full of tailings solids. Cell 4A has no freeboard limit because it is assumed that all precipitation falling on Cell 4A will overflow to Cell 48. All precipitation falling on Cell 2, 3, and 4A and the adjacent drainage areas must be contained in Cell 48. The flood volume from the PMP event over the Cell 2, 3, and Cell 4A pond areas, plus the adjacent drainage areas, which must be contained in Cell 48, is 159.4 acre-feet of water. The flood volume from the PMP event over the Cell 4A area is 36 acre-feet of water (40 acres, plus the adjacent drainage area of 3.25 acres, times the PMP of 10 inches). For the purposes of establishing the freeboard in Cell 48, it is assumed Cell 4A has no freeboard limit and all of the flood volume from the PMP event will be contained in Cell 48. The flood volume from the PMP event over the Cell 48 area is 38.1 acre-feet of water (40 acres, plus the adjacent drainage area of 5.7 acres, times the PMP of 10 inches). This would result in a total flood volume of 197.5 acre-feet, including the 123.4 acre-feet of solution from Cells 2 and 3 and 36 acre-feet of solution from Cells 2, 3, and 4A that must be contained in Cell 48. The procedure for calculating the freeboard limit for Cell 48 is set out in the DMT Plan. The Groundwater Quality Discharge Permit, No. UGW370004, for the White Mesa Mill requires that the minimum freeboard be no less than 3.0 feet for Cells 1, 4A, and 48 but based on License condition 10.3 and the procedure set out in the DMT Plan, the freeboard limits for Cells 1, 4A, and 4B will be at least three feet. Figure 7, Hydraulic Profile Schematic, shows the relationship between the Cells, and the relative elevations of the solution pools and the spillway elevations. The required freeboard for Cell 4B will be recalculated annually. S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT O and M Revision for permit\Cell 4A and 4B O M Plan Rev 2.2 July 2011 clean.doc Page 17 Cell 4A BAT Monitoring, Operations and Maintenance Plan 8.0 List of Attachments 01/21/2010 Revision Denison 2.2 1) Figures IA and lB, Initial Filling Plan, Geosyntec Consultants 2) Figure 2A and 2B, Initial Filling Plan, Details and Sections, Geosyntec Consultants 3) Figure 3A and 3B, Initial Filling Plan, Solution and Slurry Pipeline Routes, Geosyntec Consultants 4) Figure 4A and 4B, Interim Filling Plan, Geosyntec Consultants 5) Figure 5, Leak Detection System Sumps for Cell 4A and 4B, Geosyntec Consultants 6) Figure 6A and 6B, Leak Detection Sump Operating Elevations, Geosyntec Consultants 7) Figure 7, Hydraulic Profile Schematic 8) Cell 4A and Cell 4B Freeboard Calculations 9) Table lA, Calculated Action leakage Rates for Various Head Conditions, Cell 4A, White Mesa Mill, Blanding, Utah, Geosyntec Consultants 10) Table lB, Calculated Action leakage Rates for Various Head Conditions, Cell 4B, White Mesa Mill, Blanding, Utah, Geosyntec Consultants 11) White Mesa Mill Tailings Management System and Discharge Minimization Technology (DMT) Monitoring Plan. S:\Environmental\U1\WhiteMesaMill\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\Tuly 201 l BAT O and M Revision for permit\Cell 4A and 48 0 M Plan Rev 2.2 July 2011 clean.doc Page 18 ,1 :, ~ i .:· --· '· ·, .--'-~\ \ \ '-~ "':' ·-. -: ....... ' -\ i • ~L/ .. i J' -,.. ___ """ --. I -... __ -·--.---.._ --... - ,,l .1 . / \ \ . /" LEGEND \ -.. .~ --"500 --EXISTING GROUHD CONTOUR -MAJOR EXISTING GROUND CONTOUR -MINOR --5590--PROPOSED SURFACE CONTOUR -MAJOR PROPOSED SURFACE CONTOUR -MINOR ~ UMIT OF LINER SP'...ASH F'AO ----HOPE Pl?ELIME SLIJRAY OR SOUL TION SOUJTION RETIJRN SLIMES DRAIN ,· .,.. \. .. \ ' \ • \. . \ ...... D ZIO' 400' ~ i ! [ Geosyntect> I consultan~ SCALf: IN FCET INITIAL FILLING PLAN CELL4A BLANDING, UTAH DATE: OCTOBER 2010 PAOJECTNO. SC0349 T FIGURE 1A I I I I \ ', --- -------------------.. _ ·-------... __ .... _______ _ -------------------- -------------~ -------------------------------------------------------------------------~------- .. ___ ""' 6" OR tr HDPE Pl1'£1H'. SUIIRY QI sa.JJTI<IN /J ·S::U.'7Xlll l£IUffi T LEGEND EXIS11NG GROUND CONTil.lR -MAJOR DGS'TIHG CROUND CONTOUR -MINOR --5590--PROPOSED SUNFA~ CONlOOR -t.lAJOft PROPOSED SllRFACE l;Otl'TOOR -MIHOR ------LIMIT <F UN£R m:mm,. §LASH PAD • --lllPE PF£I..JIE SlllRRY OR SIDULllON S0Ll1tl0N RElURH SlM£S DRAIN 0 200' <400' ~ ! I SCALE IN fEET INITIAL ALLING PLAN cELL,e BLANDING, UTAH llllTE: OCTOBER 2D10 PRCLJB:TNO SC0349 ~lliUIU,. 18 RETl.JRN 8" HOPE PIPEUNE S0W11iA SLURRY OR SOLUTION r , I I I ._ .:..-=---.,,,. ........ ., .. ,/ I I I , . ;:--_ ' ......... --.... ~ :::--_;__ ,--.A ._ ..... ---- MIM.II 2lf WIDE 5TR'iP OF -E ID IIL HDPE IIEIIIIIIM-(SMCllnl) <alNEJ(llll 14,) e~PAD ~·'" ~-;;;;-. ~ .......... ----~ . :::-----.... I Wll.l!IIUlol: ~t--:rn•~ .1,-(lf"=---l ,. LEGEND EXISTING GROUND COIITOUR -MA..'OR EXIS11NG GROUND CONTOUR -t.llNCR --5590--PROPOSED SURF'ACE CON1tlUR -MAJOR PROPOSED S\JRF'AC£ COlffl1JR -l#IOR ------LNTCE"UNER ~ SPI.ASHPAD -• -Hill'£ PIPELINE SL.LIMY OR SOIJLTIOH sownON RETURN SUWE'S DRAIN ::,._ VALJUMITS OF LINER - .............. ---;;---.. =---1 ------..... . -........ ' . I . ! I 0 100' 200' --SCALE IN FEET INITW. Fll.LING Pl.AN, DETAILS AND SECT1DNS CELl.4" Bl.ANDING, UTAH I Geosyntect>I DAlE: acroBER2010 I FtGUftE C01\.~1.1l!ant11 PRDJECT IIO. SC0349 2A -r--.. """~ --~ . --... -------ri·,-:::i.;-;.;;:,,;.";;.-;;.;_--;;_ a-e. _. -I. --7~------,_ ,r t ----------;;:.: --. -~---,.· ---------' j ' . . I I ' : . : ' ' ' . . . , . / 1 ,1, '· • • , , • '/ , 1 1 1 I I I • < • I -:---. • ' . I . . I .: , ; I I I I 1 • 1 0~'/ 1 l j,J / I I I , I I I ,, I I I ·/ ·I J ' . ' ' . . . . . ,' ' . . I I - ,~:::·~ e~PAD 11C4.t, tC.U l.£GEND EXISllNG GROUND CllN'TtlUR -MA.JOR ElCIS11NG GRDUND CQmll.lR -MINOR --5590--PROPOSED SURFACE CCll111llt -IIAJCR PftOP0'5E> SURFMZ CClfTtUt -~ ------UNIT CF UtlER I 2222222d SPLASH PAD • ~ HDFE Plf'aJNE SUJMY <ll SOOLlDI .. SCl1JTitN RrlURt,I • • ------· su.tES DRAN -&- l D 1.00' 200' ---SCALE IN FEET IMTIAL Rl.l.lNG Pl.AN, OETAILS AND SECTIONS CEU.48 Geosyntect> amsulta:ms BLANDING. UTAH DA.TEo OCTOBER zno PROJECT NO SC0349 1'1GURE 28 • ~--------------------------~ SOWTION REl\JRN A ,, I ~-, · . , ' \ a• HOPE PIPELINE , :·.. I I : I ,· I I I I 1' I / / ;' / / SLURRY OR SOLUTION I ' ··. . ' . I : . I i I ' I I \. ,:·, . . I : ,· : { I fl I I I . I : I . I t I I ' .' • / / -J , + f , • ' , ' / ' I ·, sa..uTION 1' I • J : l • . I ; ; / ' / I ' I I • I • I I I \ REO.AIM 1 1 1 I • ,·/ : ' 'I I ' I' \ ~~-l:1 1 ·~ !+1 1 'J _:-':_/ !J~)dd ~1J./{LU1 _ _ _ } \ ,, ~ 1:.' i'':·!1 !'11,!.'::::I ~ , en , . , , I . 1 1 , • • 1 . • ••• \ l -. 1-1 r -=-1 :' -, ~ • "':' -! :-l -r' .,. It I ..!, !--, I -:-i --\ ' I I • • \ I I ' , 1 • 1 I I I I \ \ \ " \ • l , •1 1 ' , 1 • \ I 1 ' , ' \ I , n I ·. \0' • " \, 1 • 1 •, I I t I I 1 , , ,v· \ r -\-~ -\-' --~·..:.. -:...., ... ,1:1._, .:...,J.tll 1 __ .-.I~ \_\U'-_ _ \~ \ I ' ' I I \V-\ I I , n • ' , V' \ \ \ \ •'"' I '\ I . \ , j , n , • (J\, • • ~· \ ' '. ' ,,..,, \ \\ u..-• • \ • 1 v· l , • ... , CP \ u.,, \ \ I '+ \ l '--\~ ~ L \ ~0':A \_ . .l ~\ 1. \-\c.:P -..: \_ \0 \ _ \0' _ _ \ \ I \ \',J \~~\l ~~\ \_\~j \\~\~\~i \\~\:..\~\\\~'~-~-_ \~ \ \ I ~. ,\\())I \ 1,0"\ • ' \~~A\ \ \ ~ \ ~ \ 1 \,\0'\I.'\ \\, \\ \ \ I \ \ . l, \i, \-, ';'° \, \ \ , \ \ , "\ t \ ~ ·\ \-' \_ '\ _ \. I I I \ \ "' \ \ , \ \ • \ ·, \ ._ \ , , \ , 1.." \) / •\ LEGEND EXISllN6 IRlUND CllN10UR -MAJQft D1S11NC GAOU1m CON"TDUR --«lR --SSIIO--.. DPOSED SIJRrACE CQlffllUR -MAJOR PROPOSE) SURP'ACE CDN'ltlUR -IIINCR ---lJIIIT Of" UN~ ~ 0 100' 2®" ------SCALE IN FEET 5l'I.AStl PNJ -• -HDPE l'FEUE SlURRT D1t SOtUlaN SOWllllN R!'1IRI INITIAL FIWNG Pl.AN, SOLUTION AMl SLURRY PIPELINE ROUl=S CB.L<IA ----SUIES llRAl4 Geosyntect> i:uru.-ulwnts ~.UT.Ni CIATE: OCTOBER.2010 PRCJECT NO SC0348 ..- 3A SCW110N ·---·r-·-~· ------, ., ,: \~ . I \~ 6" CR e• -E -~ \ 1 1 SUJll:RY OR S0\,:11',CN ""\. . ,, \• I \1 I \! ', '\ \ \.' -\\\~~yy,-'"', \ "'i. "\.-.-\-~ ---- -..__ -,-...... _,,. -'~~\ i. ~\\ __ .. \ \ i... _\ ~.\_\ \ \_\ \ t~ \ '~- v TS ~LMR \\ \ \ \\ \ \ .. \' \' ,,, \\ ,IP '\.--------A--.. \. '· \ . \ \ \ '. i \ i i \.I") • ----"""-..--.--.-,-··--\l.-.a..\--~-' .· .. -\-0 . \ \ \ ·, ~ \ \ ', ·" \ \ '~·\'\ \ \ \ \ ··\\ ·. '\ ,\ \ r-\-\-,.· ~ -·;-. ~-sru.~ R£cu.al e1,,~ . -., ', \\' .'\ \\'. 1, IP '\\•,•\',\\ ,, -"'\;" "'\-\ • • • -·-\ • • , I I \ ' u\ 1 I I, I I ,' ' t , \ \ , \ \ "\ \o-\ -,-, ..... .l_. • .,-•. \ "\!. • -4. \ \ I • I , I \ , \ \ , J\ • \ \ I • , I ""f'°'""-"'"'" ••-··-· _f \ • \ W' I ~ , t \ 4 \ • -,. I -4 '\ \ \ \tl. ~ \ ' . -: 1, \ • l t ' , • -.. ·o·'\·,-\.\--1,.·;--1--\>.-~-\\~-~--.:\1. , \. \ 1 , • \ \ \ '· • \ ,., ,. \ \ , \ , , \ , • , . 1 1 \ , -,.. ---,--• r _, _ __ _ , . , ...,, \ \ ' • I ' \ I I ' I I I I \ ,.. ' -----.., ·, 'fA ,\.,•.,, I .1 :\,. I ,\1 1 'i /. I I I I I I I I I I I LEGEND ~ GROOICI CQNTDUR -MAJOR EXIS'IING CRCIUND CONTClJR -MINOR --51:590--~ SURFACE CCNTOJR -MAJOR ~~ ---P'Ra'OSED SURFACE cancuR -IINOR 0 100' 200' ------UMJT OF' UNER W 1 ! '2 > > t > 2 > .. , SPLASH PAD SCALE IN FEET -• ~ HOPE PIPELI£ SW1RY OR SOULnc,i ... S0llJ1IOH REtUIIN INITIAL FIWNG Pl.AN, SOWTION AND SLURR'I PIPELINE RO\JTcS CELL4B • -• -• • • • • SUMES llftALN Geosyntect'I f'ODSIJJfants BLANDING, UTAH °"TE: OCTOBER 2010 PROJECT flD SCQ349 3B ) ,/' . '( ;--_, , . ' .. ,,- .11 ; ; ., ., • I ( rl \ ' I I I I I I I I I I I I I I I I I I I . I I t I \ ' ~ R£11JliN I T --SS9o-- ==--- L£GEND EXISilNG (iffOUN D CONTOUR -MAJOR DOSTING GROUND aJllOUR -IQIDR PROPCSEtl SURF-.a: CONTOUR -MAJOR PROPOSED 9JRF J.CE !XlNTOJR -MtlOR UIIIT OF L!NER Sl'I.ASH PAO HOPE PIPEl.lNE SUJRRY OR SOULTION SOWTIOH RETURN SUMES DRAIN 0 200' 400' L;;.-I ! SCALE IN F'EET INTERIM FIWNG Pl.AN CEl.L4B Bl.ANDING, UfAH 48 011.-re: OCT0BER2010 l'lQ.IRE Geosyntece> amsultaDt5 PROJECT NO. SC0349 1s• • SCHEDULE 40 PVC --------~~--~ '\... 60 Ml!.. HOPE: GEOMEMBRANE (TEXlURED} SECTION LEAK DE IECTION SYSTEM SUMP N..T.S. LEAK OETECilON SYS'TEM 4" \'I SCHEDULE 40 PVC / / -4-" ; SCHEDULE 40 P\/C / .-1· LEAK DETECTION sYSTcM SUMP CELI.S4AAN04B BLANDING. UTAH Ceo~~t>I ::~n~.ocroe::: FICiLIRE 5 I I ~ 11 11 i 11 I jl I ii I I I I I I I ' I I I I I I I m !1 i I I. ! z ~I ffil I !I a, I ii I I I I I I I I I I I I am I i 11 I i I ffl M! I ! I i PMPVOW~ 38.1 AC...fT. ·1 PLUS 15!L«J AC-FT FIIDM CEUS • 1 2. 3,AND 4A _J TOTAL !..<17 •. 50 AC•FT _ CELL48 FREEBOARD UMJ'T 5594.64 FT. MSL PMPVOLUMf, 36AC.ff. PLUS 123.4 N;...fT AIOM CB.l2 AND CB.L3 159.40 AC-flovetFLOWS TO all.48 PW va.uME, 12S.4 AC.FT OVERFI..OWS TO CELL4A CEU2SPIU.WAY [aEVS611.0 ~ ~ NOTTO SCALE HVORAUIJC PROFILE SCHBMl1C caL48 BI.AND9,IG, UTAH Geosyn.tec C>I ~ OCTOBER201D aznmlllmls JIRO,IEC!" NQ. St::0349 PICIURE: 7 Geos~ntet: Consuftanr, Table 1A Calcufated Action La•"-1• Rates for Var'°'3 Head Conditions CeH 4A, White Mesa MIii Blandfn1, Utah Head Above Uner C.tcul•'-d Action LHlcap Rate System (feet) (pllam/1CNJ/d1y) 5 222.04 10 314.0 15 384.58 20 444.08 25 496.S 30 543.88 35 587.5 37 604.0 Geasyntec Consultar,ts Table 18 Calculated Action Leakage Rates far Various Head Conditions Cell 48, White Mesa MIii er,ndln1, Utah Head Abave Uner Sptem Cllcul1ted Action Ltakqe Rita {feet) (11Hons/acr1/dayJ 5 211.4 10 317.0 15 369.9 20 422.7 25 475.6 30 528.4 35 570,0 37 581.2 Appendix G Stormwater Best Management Practices Plan, Revision 2.1: April 2022 STORMWATER BEST MANAGEMENT PRACTICES PLAN for White Mesa Uranium Mill 6425 South Highway 191 P.O. Box 809 Blanding, Utah April 14, 2022 Prepared by: Energy Fuels Resources (USA) Inc. 225 Union Blvd., Suite 600 Lakewood, CO 80228 TABLE OF CONTENTS Best Management Practices Plan Revi.~ion 2.1; April 2022 1.0 INTRODUCTION/PURPOSE ................................................................................... , ....... 2 2.0 SCOPE ..... , .. , .............................................................................................................................. ~ 3.0 RESPONSIBJ:I..,ITY .................... i .................... , •••••••• ,. ••••• ; •• , ........................... ; ........ , ................... 4 4.0 BEST MANAGEMENT PRACTICES .............................................................................. 5 4.1 General Management Practices Applicable to All Areas ....................................... 5 4.1.1 Keep Potential Pollutants from Contact with Soil, and Surface Water: ........ 5 4.1.2 Keep Potential Pollutants from Contact with Precipitation ............................ 5 4.1.3 Keep Paved Areas from B~oming Pollutant Sources ..................................... 5 4.1.4 Inspection and Maintenance of Diversion l;>itch~ and Drainage Chan.nets within the Process and Reagent Storage Area ................................. '., ............................ 5 4.1.5 Recycle Fluids Whenever Possible: ................................................................... , S 4.2 Management Practices for Process and Laboratory Areas .................... , .............. 5 4.2~1 Clean Up Spills Properly .................................................................................... 5 4.2.2 Protect Materials Stored Outdoors .......................................... ; ......................... 6 4.2.3 Ma-nagement .............. , ........ , ................ ~~············-···············,····················· .. ············· 6 4.2.4 Materials Management ....................................................................................... 6 4.3 Management Practices for Maintenance Activities ................................................ 6 4.3.1 Keep.a Clean Dry Shop ........................................................................................ 6 4.J·.2 Manage Vehicle Fluids., ..................................................... , ................. , .............. 6 4.3.3 Use Controls During Paint Removal., ......... ;., ................................................... 7 4.3.4 Use Controls During Paint Application and Cleanup ...................................... 7 4.4 Management Practices for Ore Pad, Tailings Area, and Heavy Equipment ........ 7 4.4.1 Wash Down Vehicles and Equipment in Proper Areas ................................... 7 4.4.2 Manage Stockpiles to Prevent Windborne Contamination ..................... ; ....... 7 4.4.3 Keep Earthmoving Activities from Becoming· Pollutant Sources ................... 8 Figures Figure 1: White Mesa Mill Site Layout Figure 2:· White Mesa Mill Site Drainage Basins Figure 3: Energy Fuels Resources (USA) Inc.-White Mesa Mill Management Organization Charl Tables TABLB 1.0: Whit~ Mesa Mill Management Personnel Respcmsible for Impltirnenling This BMPP TABLE 2.0: REAGENT YARD LIST TABLE 3.0: LABORATORY CHEMlCAL INVENTORY LIST TABLE 4.0: REAGENT YARD AND BULK CHEMICALS LIST TABLE 5.0: PETROLEUM PRODUCTS AND SOLVENTS LIST Pagel 1.0 INTRODUCTION/PURPOSE Best Management Practices Plan Revision 2.1: April 2022 Energy Fuels Resources (USA) Inc. ("EFRI") operates the White Mesa Uranium Mill (the "Mill") in Blanding, Utah. The Mill is a net water consumer, and is a zero-discharge facility with respect to water effluents. That is, no water leaves the Mill site because the Mill has: • no outfalls to public stormwater systems, • no surf ace runoff to public stormwater systems, • no discharges to publicly owned treatment works ("POTWs"), and • no discharges to surface water bodies. The State of Utah issued Groundwater Discharge Permit ("GWDP") No. UGW370004 to EFRI on March 8, 2005. As a part of compliance with the Permit, EFRI is required to submit a Stormwater Best Management Practices Plan ("BMPP") to the Director of the Division of Waste Management and Radiation Control ("DWMRC"), Utah Department of Environmental Quality ("UDEQ"). This BMPP presents operational and management practices to minimize or prevent spills of chemicals or hazardous materials, which could result in contaminated surface water effluents potentially impacting surface waters or ground waters through runoff or discharge connections to stormwater or surface water drainage routes. Although the Mill, by design, cannot directly impact stormwater, surface water, or groundwater, the Mill implements these practices in a good faith effort to minimize all sources of pollution at the site. Page 2 2.0 SCOPE Best Management Practices Plan Revision 2.1: April 2022 This BMPP identifies practices to prevent spills of chemicals and hazardous materials used in process operations, laboratory operations, and maintenance activities, and minimize spread of particulates from stockpiles and tailings management areas at the Mill. Storage of ores and alternate feeds on the ore pad, and containment of tailings in the Mill tailings impoundment system are not considered "spills" for the purposes of this BMPP. The Mill site was constructed with an overall grade and diversion ditch system designed to channel all surface runoff, including precipitation equivalent to a Probable Maximum Precipitation/Probable Maximum Flood ("PMP/PMF") storm event, to the tailings management system. In addition, Mill tailings, all other process effluents, all solid waste and debris (except used oil and recyclable materials), and spilled materials that cannot be recovered for reuse are transferred to one or more of the tailings management impoundments in accordance with the Mill's Radioactive Materials License ("RML") #UT1900479 conditions. All of the process and laboratory building sinks, sumps, and floor drains are tied to the transfer lines to the tailings impoundments. A site map of the Mill is provided in Figure 1. A sketch of the site drainage basins is provided in Figure 2. As a result, unlike other industrial facilities, whose spill management programs focus on minimizing the introduction of chemical and solid waste and wastewater into the process sewers and storm drains, the Mill is permitted by RML to manage some spills via draining or wash down to the process sewers, and ultimately the tailings management system. However, as good environmental management practice, the Mill attempts to minimize: 1. the number and size of material spills, and 2. the amount of unrecovered spilled material and wash water that enters the process sewers after a spill cleanup. Section 4.0 itemizes the practices in place at the Mill to meet these objectives. This BMPP addresses the management of stormwater, and the prevention of spills of chemicals and hazardous materials, at the Mill site. Detailed requirements and methods for management, recordkeeping, and documentation of hazardous material spills are addressed separately in the EFRI White Mesa Mill Spill Prevention, Control and Countermeasures ("SPCC") Plan, the Emergency Response Plan ("ERP"), and the housekeeping procedures incorporated in the White Mesa Mill Standard Operating Procedures ("SOPs"). Page 3 3.0 RESPONSIBILITY Best Management Practices Plan Revision 2.1: April 2022 All Mill personnel are responsible for implementation of the practices in this BMPP. EFRI White Mesa Mill management is responsible for providing the facilities or equipment necessary to implemenuhe..practices-in.thisJ3MPP. . The EFRI Corporate Management and Mill Management Organization is presented in Figure 3. An updated spill prevention and control notification list is provided in Table I. Page4 Best Management Practices Plan Revision 2.1: April 2022 4.0 BEST MANAGEMENT PRACTICES A summary list and inventory of all liquid and solid materials managed at the Mill is provided in Tables 2 through 5. 4,1 General Management Practices Applicable to All Areas 4.1.1 Keep Potential Pollutants from Contact with Soil, and Surface Water: • Store hazardous materials and other potential pollutants in appropriate containers. • Label the containers. • Keep the containers coveted when not in use. 4.1.2 Keep Potential Pollutants from Contact with Precipitation • Store bulk materials fo covered tanks or drums. • Store jars, bottle, or similar smalJ containers in buildings or under covered areas. • Replace or repair broken dumpsters and bins. • Keep dumpster lids and latge container covers closed when not in use (to keep precipitation out). 4.1.3 Keep Paved Areas from Becoming Pollutant Sourees • Sweep paved areas regularly, and dispose of debris in the solid waste dumpsters or lai lings area as appropriate. 4.1.4 Inspection and Maintenance of Diversion Ditches and Drainage Channels within the Process and Reagent Storage Ar~a • Diversion ditches, drainage channels and surface water control structures in and around the Mill area will be inspected at least monthly in accordance with the regularly scheduled inspections required by the GWDP, and the RML. Areas requiring maintenance or repair, such as excessive vegetative growth, channel erosion or pooling of surl'ace water runoff, will be reported to site management and maintenance departments for necessary action to repair damage or perform reconstruction in order for the control feature to perform as intended. Status of maintenance or rep&irs will be documented during follow up inspections and additional action taken if necessary. 4.1.5 Recycle Fluids Whenever Possible: • When possible, select tlUtomotive fluids. solvents, and cleaners that can be recycled or reclaimed • When possjble, select consumable materials from suppliers who will reclaim empty containers. • Keep spent fluids in properly labeled, covered containers until they are picked up for recycle or transferred to the tailings management system for disposal. 4.2 Management Practices for Pl."ocess and Laboratory Areas 4.2.1 Clean Up Spills Properly • Clean up spills With dry cleanup methods (absorbents, sweeping, collection drums) instead of water whenever possible. Pages Best Management Practices Plan Revision 2.1: April 2022 • CJean spi I ls of stored reagents or other chemicals immediately after discovery. • (GWDP, Section I.D.10.c.) • Recove.r and re-use spilled material whenever possible. • Keep supplies of rags, sorbent materials (such as cat litter), spill collection drums, and personnel protective equipment ("PPE") near the areas where they may be needed for spill response. • If spills m1,1st be washed down, use the minimum amount of water needed for effective cleatmp. 4.2.2 Protect Materials Stored Outdoors • If drummed feeds or products must be stored outdoors, store them in covered or diked areas when possible. • If drummed chemicals must be stored outdoors, store them in covered or diked areas when possible. • Make sure drums ~nd containers stored outdoors are in good condition and secured against wind or leakage. Place any damaged containers into an overpack drum or second container. 4.2.3 Management • When possible, recycle and reuse water from flushing and pressure testing equipment. When possible, wipe down the out~ides of containers instead of rinsing them off in the sink. • When possible, wipe down counters and work surfaces instead of hosing or rinsing them off to sinks and drain 4.2.4 Materials Managehlent • Purchase and inventory the smallest amount of laboratory reagent necessary. • Do not stock more of a reagent than will be used up before its expiration date. • All new construction of reagent storage facilities wiJI include secondary containment which shall control and prevent any contact of spilled reagents, or otherwise released • reagent or product, with the ground surface. (GWDP, Section J.D.3.g.) • 4.3 Manasement Practices for Maintenance Activities 4.3.1 Keep a Clean Dry Shop • Sweep or vacuum shop floors regularly. • Designate specific areas indoors for parts cleaning, and use cleaners and solvents only in those areas. • Clean up spills promptly. Don't' let minor spilis spread. • Keep supplies of rags, collection containers, and sorbent material near each work area where they are needed. • Store bulk fluids. waste fluids, and baueries in an area with secondary containment (double drum, drip pan) fo capture leakage and contain spills. 4.3.2 M~age Vehicle Fluids • Drain fluids from leaking or wrecked/damaged vehicles and equipment as soon as possible. Use dtip pans or plastic tarps to prevent spillage ·and spread of fluids. Page~ Best Management Practices Plan Revision 2.1: April 2022 • Promptly contain and transfer drained fluids to appropriate storage area for reuse, recycle, or disposal. • Recycle automotive fluids, if possible, when their useful life is finished. 4.3.3 Use Controls During Paint Removal • Use drop cloths and sheeting to prevent windborne contamination from paint chips and sandblasting dust. • Collect, contain, and transfer, as soon as possible, accumulated dusts and paint chips to a disposal location in the tai1ings area authorized to accept waste materials from maintenance or construction activities. 4.3.4 Use Controls During Paint Application and Cleanup • Mix and use the right amount of paint for the job. Use up one container before opening a second one. • Recycle or reuse leftover paint whenever possible. • Never clean brushes or rinse or drain paint containers on the ground (paved or unpaved). • Clean brushes and containers only at sinks and stations that drain to the process sewer to the tailings management system. • Paint out brushes to the extent possible before water washing (water-based paint) or solvent rinsing ( oil-based paint). • Filter and reuse thinners and solvent whenever possible). Contain solids and unusable excess liquids for transfer to the tailings management system. 4.4 Management Practices for Ore Pad, Tailings Area, and Heavy Equipment Detailed instructions for ore unloading, dust suppression, and tailings management are provided in the Mill SOPs. 4.4.1 Wash Down Vehicles and Equipment in Proper Areas • Wash down trucks, trailers, and other heavy equipment only in areas designated for this purpose (such as wash down pad areas and decontamination pads). • At the decontamination pads, make sure the water collection and recycJing system is working before turning on water sprays. 4.4.2 Manage Stockpiles to Prevent Windborne Contamination • Water spray the ore pad and unpaved areas at appropriate frequency in accordance with Mill SOPs. • Water spray stockpiles as required by opacity standards or weather conditions. • Don't over-water. Keep surfaces moist but minimize runoff water. Page 7 4.4.3 Keep Earthmo\'111,g Aetivitle$ ·rrom Becoming Pollutant Sources Best Managem~nt Practices PlaJ\ kevi&lon 2J: Aprll 2022 • Sch¢dule excavation, grading, an~ other ~moving activ1tie!! when extreme dryness and high winds will not be a factor (to prevent the need for-excessive dust suppression}. • Remove existing vegetation only when al;,solurely necessaey. • Se(d or plant temporary vege.tatfon for erosion cQntrol on slQpes, p.age8 TABU£S TABLEt.O RESPONSIBILITIES " · ifljrs-Jffi~tehai:gc·or facUUy:t es· = 1e,to~ention: ·--:-_: Logan Shumway 6425 South Highway 191 Blanding, 1JT84511 (435) 678-4119 (work) (435) 459-9878 (home) -Person in·cfiarge of follow-up spill reporting: - Garrin Palmer 6425 South Highway 191 Blanding, UT 84511 (435) 678-4114 (work) (435) 459-9463 (cell) ,, QU~ 2 2 3 1 I I 1 1 2 I 1 I J I I 1 1 1 J l 2 TABLE2.0 REAGENT TANK LIST RB'.AGE,NT AMMONIUM SULFATE DIESEL KEROSENE USED/WASTE OIL DIESEL UNLEADED PROPANE LNG AMMONIA WEST SALT SALT DCLUTION SODIUM HYDROXIDE SODA ASH SOLUTION SODA ASH SHIFr SODA ASH SILO SODIUM CHLORATE SODIUM CHLORATE SODIUM CHLORATE SULFURIC ACID SULFURIC ACID HYDROCHLORIC ACID CAPACITYtOAL} " 24,366 250 10,152 5,000 6,000 3,000 30,000 30,000 31,409 17,635 9,451 19,904 16,921 8,530 22;841 16,075 21,057 28,788 1,600,000 1 J,000 13,650 TAHL~:.i.U LABORATORY CHEMICAL INVENTORY L1ST1 ' Chemical in. Lah I l(Qz Typical Quantity ln:Stock· 1 I '-JI Acetic Acid, Glacial 5,000 lbs (2,270 kg) (approx. 2,160 Lor 571 gal.) lOL Aluminum nitrate 5,000 lb (2,270 kg) 20kg Ammonium carbonate 5,000 lb (2,270 kg) 2kg Ammonium bifluoride 100 lb (45.4 kg) 10 lbs Ammonium chloride 5,000 (2,270 kg) 6 kg Ammonium hydroxide 1,000 lb (454 kg) (approx. 510 L) 57.5 L Ammonium oxalate 5,000 (2,270 kg) 12 kg Ammonium thiocyanate 5,000 (2,270 kg) 15 kg Antimony potassium tartrate 100 lb (45.4 kg) 0.500 kg Ammonium, hydroxide 1,000 lb (454 kg) (approx. 510 L) 5L n-Butyl acetate 5,000 lb (2,270 kg) (approx. 2594 L) 4L Calcium acetate None l kg Cyclohexane 1,000 lb (454 kg) (approx. 583 L) 5L Ferric chloride 1,000 lb (454 kg) 2kg Ferric nitrate 1,000 lb ( 454 kg) 0.500 kg Ferrous ammonium sulfate 1,000 lb (454 kg) 10 kg Ferrous sulfate heptahydrate 1,000 lb (454 kg) 6kg Hydrofluoric Acid 100 lb (45.4 kg) (approx. 39 L) IL Lead nitrate 10 lb (4.54 kg) 1 kg Potassium chromate 10 lh (4.54 kg) 1 lb Potassium Permanganate 0. IN 100 lb (45.4 kg) (32 gal) 5 kg (11 lbs) Silver Nitrate I lb (0.454 kg) 2.6 kg Sodium hydrosulfidc 5,000 lb (2,270 kg) 2.5 kg Sodium nitrite 100 lb (45.4 kg) 10 kg Sodium phosphate tribasic 5,000 lb (2,270 kg) 3 lbs Zinc acetate 1,000 lb (454 kg) l k~ Cherg.ical in Volatiles and Flammabl~ Lockers (A,8,C} II RQ2,3 Typical Quantity in Stock Acetone 5,000 lb (2,270 kg) (approx. 759 gal) 2L Chloroform 10 lb (4.54 kg) ( approx. 3.1 L) IL For ma ldeh yde JOO lb (45.4 kg) (approx. 41.7 L) IL Nitroben1..ene 1,000 lb (454 kg) (approx. 377 L) 12L Tri ch lo roe thy Jene 100 lb (45.4 kg) (approx. 31.1 L) 2L Toluene 1,000 Jb (454 kg) (approx. 523 L) 12L Chemical' in Outside Acid, - RQ2,,3 Typical Quantity·in Stock Conu --II Hydrochloric acid 5,000 lbs (2,270 kg) (approx. 1,894 Lor 501 gal.) 22L Nitric acid 1,000 lb (454 kg) (approx. 322 L) 25L Phosphoric acid 5,000 lb (2,270 kg) (approx. 1,350 L) 20L Sulfuric acid 1,000 lb (454 kg) (approx. 247 L) 45 L I. This list identifies chemicals :,vhich arc rcgulmcd as hazardous substances under the federal Water Pollution Control Act 40 CFR Pait I 17. The lab also stores small quantities of other materials that arc not hazardous substances per the above regulation. 2. Reportable Quantities arc those identified in 40 CPR Part 117 Table 117.3: "Reportable Quantities of Hazardous Substances Designated Pursuant lo Section 311 of the Clean Water Act." 3. Eslinmtion of Reportable Quantities in L assumes pure compound ( 100%) concentration, unless otherwise specified. TABLE4.0 REAGENT YARD AND BULK Clll!:MlCALS LIST1 -·Ty.P,f~l Quantity In .Reageilt RQ1 -Stock Sulfuric add 93 LO 98% I ,000 lb (454 kg) (approx. 247 L) 4,000,000 lb Ammonia -East Tank l 00 lb (45.4 k.1t) 50,000 lb Ammonia-West Tank JOO lb (45.4 kg) 50,000 lb Kerosene 100 gal* 5,000 ~al Salt (Bags) None 40,000 lh Soda Ash Bulk None 80,000 lb Soda Ash Dense (Bu_g) None 40,000 lb Hydrogen Peroxide None 20,000 lb Diesel JOO gal• 3,000 gal Gasoline 100 gal* 1,500 gal Tcrliary Amine None 30,000 lb Sall (Bulk solids) None 50,000 lb Caustic Soda 1,000 lb (454 kg) 1,000,000 lb Ammonium Sulfate None 120,000 lb Sodium Chlorate None 70,000 lb in 50% solution Alaminc 335 Bulk None O lbs Alamine 310 Bulk None 0 lbs lsodecanol None 0 lbs Vanadium Pentoxide'.\ 1.000 lb (454 kg) 50,000 lb Ycllowcake3 None 200,000 lb Liquid Natural Gas l 0,000 lbs (4,540 kg) 60,000 lb Tri-decyl alcphol Non\! 20,000 lb Flocculant 655 None 40.000 lb Flocculant314 None 4,000 lb Propane None ]6,000 lb Solid-A-Sorb None 44,000 lb Perlite None 25,000 lb Diatomaceous Earth filter Aid None 30,000 lb DEHPA None 2,000 lb Organic Phosphinic/Phosphoric Acid None 5000 gal Barium Chloride None 15,000 lb Hydrochloric Acid 5,000 lbs (2,270 kg) (approx.. 1,894 25,000 gal Lor 501 gal.) Rare Earth Carbonates1 None 200,000 lb. 1. This list identifies the bulk chemicals al rhe Mill and the chemi~Js in the reagent yard whether or not lhey are regulated as hazardous substances under the Federal Water Pollution Control Act 40 CFR Part 117. 2. Reportable Quantities arc those identified in 40 CFR Part l 17 Table l 17.3; "Reportahle Quantitb of Hazardous Substances Designated Pursuant to Section 31 l of the Clean Waler Act." 3. The Mill's product,; are not stored in the Reagent Yard itself, but arc present in containers in lhe Mill Buildings and/or Mill Yard. * These materials do not have an RQ under 40 CFR I I 0, 40 CFR 117, 40 CFR 302 or Utah regulations. These values are used by the Mill for conservatism as Best Management Practices. TABLE S.O PETROLEUM PRODUCTS AND SOLVENTS L1ST1 i Reagent RQz,3,4 Typical Quantity In Stock, 1, i Lubricating Oils in 55 gallon drums JOO gal* J ,000 gallons Transmission Oils JOO gal* 250 gallons Dielectric fluids None 5 gallons Antifreeze (Ethylene glycol) 5,000 lb 100 gallons Greases None 5001bs Water Soluble Oils 100 gal* 30 gallons Xylene (mixed isomers) 100 lbs (45.4 kg) 50 gallons (approx. 13.9 gal) Acetone 5,000 lb (2,270 kg) 55 gallons (362 lbs) (approx. 759 gal) Methyl Ethyl Ketone 5,000 lb (2,270 kg) 55 gaJlons (369 lbs) (approx. 745 gal) Toluene 1000 lbs (454 kg) 0 gallons (approx. 138 gal) Varsol Solvent (2% trimethyl 100 gal* 0 gallons benzene in petroleum distillates) Resin None 25 gallons Epoxy Paints None 50 gallons Epoxy Catalyst None. 20 gallons Oil Base paints None 25 ga11ons Paint thinners None 40 gallons Other paints None 20 gallons l. This list includes all solvents and petroleum-based products in the Mill warehouse 2. Reportable Quantilies are those identified in 40 CFR Part 117 Table 117.3: "Reportable Quantities of Hazardous Substances Designated Pursuant to Section 311 of the Clean Water Act." 3. If a spill occurs of a product that is a mixture of chemicals, Mill personnel will contact EFRI Corporate Environmental Department. 4. Estimation of Reportable Quantities in L assumes pure compound ( 100%) concentration. * These materials do not have an RQ under 40 CFR 110, 40 CFR 117, 40 CFR 302 or Utah FIGlJIUc:S 5620 HCL TANKS ~ BOILERS ~ 00000 oo~o D o0oo ALTERNATE FEED CIRCUIT DRY REAGENT STORAGE c:=> REAGENT YARD 11 O Q wATER TANK Q) SUBSTATION - 4 5630 GRIZZLY MILL o BUILDING D OLD DECONTAMINATION C::::J PAO O Q PROCESS WATER 0 J ' ( VPL STORAGE ORE PAD SODA o" o· SAMPLE PLANT SX BUILDING OO oo ;SH ~~ AMMONIA Qo KEROSENE o ~ oO 0 • SODIUM CHLORATE 0 SHOP = o·------- 5630 I D 5640 n y--x ------lt,t;· CJ TRUCK SHOP J ( * -I· _ __. TOPSOIL SCAt HOUSE ~O <J}oc NEW ONTAMINATION PAO 'i\ 0 >-er: <I'. 0 z => 0 00 J. i --) 0 UJ I--(,J ii I-C/J w er: ' I I I /i , I :I ----- \ .,.. N f: s 100 50 0 100 200 ty: SanJuan SCALE IN FEET Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO 80228 WHITE MESA MILL 818: Utah Figure 1 MILL SITE LAYOUT 1"=200' ie: May 12. 2000 Mill Site u,yout 1 5 22 dwg Rgure 11 ,-I CELL4B DRAINAGE BASIN ·F" 44.67 AC. PMF CONTAINED WITHIN BASIN ~ / ( --'--'- -4- ' 1000 0 1000 2000 .. \J + \\ '~ ~___..., + ·~ ~ . CELL4A DRAINAGE BASI 42.14 AC. .,-·--, ~ Sufrace Water Flow Drainage Basins Diversion Ditches Diversion Berm n eF 6111/08 BM 1219Al8 DI.$ tll/09 BM 11115/11 GM Energy Fuels Resources (USA) Inc. 225 Union Blvd. Ste 600 Lakewood, CO 80228 White Mesa Mill te: UT MILL SITE DRAINAGE BASINS FIGURE 2 5/29119 I SH I Au1hcr. HRR OIIO: 2005 IOtalledlly. ,_ Harold Roberts Consultant AF/AUM Project Management ENERGYFUEl.S Supervisor, Corp Safety& NAZ Standby cs Hancock) - Mgr. Technical Services (D Kapostasy) New position ,_ - Director ISR Operations (B Bonifas) TX Operations Director (P Luthiger) Director, Geology &Land /BfLtNI I Al"!:An\ ..__ - Figure 3 President/CEO (M Chalmers) u,reaor Conventional Operations 11 Sl'lumwav} Asset Mgr. Colorado Plateau - (R Fisher) Mine Geologist Canyon Mine (M Germansen) VPHR & Administration (D Nazarenus) ITMgr. (L Graham) VP Marketing & Corp. Development (C Moore) I VP Regulatory Attain (S Bakken) I ISR Permitting Mgr. .--(0 Kolkman) Quality Assurance ~ Mgr. (KV\leinel) Sr. V.P. General Co111seV Corp. Seaetary/CFO (D Frydenlund) Staff Attorney (J Hoffmeier) I Controner (S Luksch) I Assistant Conlroller ~ NewPosition -Tax Mgr. (KBeck PT) Appendix H White Mesa Mill Discharge Minimization Technology (DMT) Monitoring Plan, 1/2022, Revision: EFRI 13.0 WHITE MESA MILL DISCHARGE MINJMJZATIONTECHNOLOGY (DMT) MONITORING PLAN Revision 13.0 January 2022 Prepared by: Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, CO 80228 White Mesa Mill -Discharge Minimization Technology Monitoring Plan WHITE MESA MILL 01/22 Revision: EFRT 13.0 Page2 of26 DISCHARGE MINIMIZATION TECHNOLOGY (DMT) MONITORING PLAN TABLE OF CONTENTS 1. .IN'TRODUCTION ......... , ....................................... , ............................................................ , .... 3 1.1. Background ..... , ..........•......•. , ....•.... , ..................................................................................... , 3 2~ DAaY TAILINGS IN'SPECTIONS .......................................................... , .............................. 4 2. l. Daily lllspection ...................................................... "' ............................................................. 4 3. WEEKLYTAil.,JNGS AND DMT INSPECTION ................................................................. 5 3.1. Weekly Tailings Inspections ............................................................................................ 5 Northing ................................ , ......................................................... _ ............................................. 9 Easting .. , ...................................... ,..,. ..... , ............. J, ••••••••••••• ., •••••••••••••••••••••••••••••••••••••• •• •••• •• ··········~·· •• 9 3.2. Weekly Feedstock Storage Area fuspections ................................................................. 11 4. ANNUAL EVALUATIONS ...... , ........................................................................................... 12 4.1. Annual Leak Detection Fluid Samples ........................................................................... 12 4.2. Annual Inspection of the Decontamination Pads ........................................................... 12 4.3, Annual Inspection of Waste Oil and Fuel Tanks ., ......................................................... 13 4.4. Annual Inspection of Hydrochloric Acid ("HCI") Secondary Containment Concrete ... 13 5, INSPECTION OF THE AMMONIUM SULFATE COVER AREA ................................... 13 6. OTHER INSPECTIONS ........................................................................................................ 14 7. REPORTING REQUIR.EMENTS ........................................................................................ 14 7.1, DMT Re.ports ..... , ............ " ........................................................................................ , .... ,. ...... 14 Attachment A Attachment B Attachment C ATTACHMENTS Forms Feedstock Storage Area Map Tables White Mesa Mill -Discharge Minimization Technology Monitoring Plan 1. INTRODUCTION 01/22 Revision: EFRI 13.0 Page 3 of26 This DMT Monitoring Plan ("DMT Plan") sets out the procedures to demonstrate compliance with Discharge Minimization Technology ("DMT") as specified throughout Parts I.D, 1.E and I.F of the White Mesa Mill's (the "Mill's") Groundwater Discharge Permit ("GWDP") Number 370004. Additional procedures for monitoring the tailings cell systems as required under State of Utah Radioactive Materials License No. UT 19004 79 ( the "RML") are set out in the Tailings Management System procedure for the Mill, which comprises Chapter 3 .1 of the Mill's Environmental Protection Manual. This DMT Plan and the Tailings Management System procedure when implemented in concert are designed as a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system including dike stability, liner integrity, and transport systems, as well as monitoring of the feedstock storage areas at the Mill. This DMT Plan is issued as a stand-alone document, while the Tailings Management System procedure is published and maintained in the Mill's Environmental Protection Manual. 1.1. Background The Tailings Management System procedure was originally developed as Chapter 3.1 of the Mill's Environmental Protection Manual, under the Mill's NRC Source Material License, and constituted a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system. Upon the State of Utah becoming an Agreement State for uranium mills in 2004, the Mill's Source Material License was replaced by the State of Utah RML and the State of Utah GWDP. The GWDP required that EFRI develop the initial DMT Plan in response to GWDP requirements. In developing the initial DMT Plan, EFRI combined the existing Tailings Management System procedure set out as Chapter 3.1 of the Mill's Environmental Protection Manual with a number of new DMT requirements from the GWDP to form the initial DMT Plan. The initial DMT Plan and subsequent revisions (through revision 11.5) maintained the requirements from the RML (i.e., Chapter 3.1 of the Mill's Environmental Protection Manual) and the DMT requirements of the GWDP in a single document. However, after several years of implementing the DMT Plan, EFRI concluded that it is preferable to separate the RML portions of the DMT Plan from the GWDP portions of the DMT Plan, into two separate documents. This DMT Plan continues to be a stand-alone plan that contains the DMT requirements from the GWDP except for the daily recording of the Cells l, 2, and 3 LDS measurements as noted below. However, the portions of the initial DMT Plan that flowed from the RML and not from the GWDP have been separated from the DMT Plan and have been returned to their original status as the Tailings Management System procedure, which comprises Chapter 3.1 of the Mill's Environmental Protection Manual. This allows the DMT Plan to be managed, inspected and enforced under the requirements of the GWDP and this Tailings Management System procedure to be managed, inspected and enforced under the requirements of the RML. White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 4 of 26 This division of the requirements was discussed with DRC on October 26,201 l. DRC agreed with the division of the 1'equirements into two distinct. documents as. noted in their correspondence dated December 20, 201 l. Pursuant to a written request from DRC, dated May 30, 2012, the RML requirements for the inspections of the Cells l, 2, and 3 Leak Detection Systems (''LDSs") has been included in this DMT Plan. The inclusion of this RML requirement into this DMT Plan is to address the DRC request for uniformity in monitoring and reporting requirements for Cells l, 2, and 3 and to address anticipated GWDP modifications regarding the LOS monitoring in Cells 1, 2, and 3. 2. DAILY TAILINGS INSPECTIONS The following daily tailings inspections shall be performed: 2.1. Daily Inspection On a daily basis, including weekends, the Cells 1, 2, 3, 4A, and 4B leak detection systems must be inspected either under the DMT Plan or the Tailings Management System procedure. The Radiation Safety Officer ("RSO") or his designee is responsible for performing these daily tailings inspections. The RSO may designate other individuals with training, as described in Section 2.4 below, to perform these inspections. Observations made by the inspector will be recorded on Attachment A to this DMT Plan. The inspector will place a check by all inspection items that appear to be operatingproper1y. Those items where conditions of potential concern are observed should be marked with an "X". A note should accompany the "X" specifying what the concern is and what corrective measures will resolve the problem. This observation of concern should be noted on the form until the problem bas been remedied. The date that corrective action was taken should be noted as well. See the Tailings Managernent System procedure for additional daily inspection requirements. a) Daily measurements in the leak detection system sumps of Cells l, 2, 3, (as required by the RML) and CeHs 4A, and 4B (as required by the GWDP) are recorded. For simpJicity, the leak detection system measurements for all cells have been combined on the Daily Inspection Data Form included ai; Attachment A-1 to this DMT Plan regardless of the origin of the requirement. The triggers for further action and the associated actions when evaluating Cells 1, 2, and 3, leak detection systems are discussed in the Tailings Management System procedure, Section 2. lq). The solution level in Cell 4A or 4B leak detection system is not allowed Lo be more than 1.0 foot above the lowest point on the bottom flexible membrane liner (FML) (Cell 4A FML eleva.tion is 5555.14 amsl and with the ~ddition of the 1.0 foot of solution the solution elevation is 5556.14 feet amsl. For Cell 4B the FML elevation is 5557.50 amsl and with the addition of the 1.0 foot of solution the White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 5 of 26 solution elevation is 5558.50 feet amsl). If any of these observations are made, the Mill Manager should be notified immediately and the leak detection system pump started. In addition, the requirement to notify the Executive Secretary in accordance with Parts I.D.6 and I.G.3 of the GWDP must be adhered to when the solution level trigger for Cell 4A or 4B has been exceeded. 3. WEEKLY TAILINGS AND DMT INSPECTION 3.1. Weekly Tailings Inspections Weekly tailings inspections are to be conducted by the RSO or his designee and include the following: a) Leak Detection Systems Each tailings cell's LDS shall be checked weekly (as well as daily) to determine whether it is wet or dry. If marked wet, the liquid levels need to be measured and reported. In Cells 1, 2, and 3 the LDS is measured by use of a dual probe system that senses the presence of solutions in the LDS ( comparable to the systems in Cell 4A and Cell 4B) and indicates the presence of solution with a warning light. The Cell 4A and 4B leak detection systems are monitored on a continuous basis by use of a pressure transducer that feeds water level information to an electronic data collector. The pressure transducer is calibrated for fluid with a specific gravity of 1.0. The water levels are measured every hour and the information is stored for later retrieval. The water levels are measured to the nearest 0.10 inch. The data collector is currently programmed to store 7 days of water level information. The number of days of stored data can be increased beyond 7 days if needed. For Cells 1, 2, and 3, the water level data is recorded on the Daily Tailings Inspection Form included as Attachment A-1 of this DMT Plan . For Cells 4A and 4B, the water level data is downloaded to a laptop computer periodically and incorporated into the Mill's environmental monitoring data storage. The data are reviewed during the weekly inspections of the tailings cell leak detection systems. If an LDS monitoring system becomes inoperable, alternate methods for LDS fluid measurements may be employed with Executive Secretary approval. If sufficient fluid is present in the leak detection system of any cell, the fluid shall be pumped from the LDS, to the extent reasonably possible, and record the volume of fluid recovered. Any fluid pumped from an LDS shall be returned to a disposal cell. For Cells 1, 2, and 3, if fluid is pumped from an LDS, the procedures specified in the Tailings Management System procedure Section 3 .1 a) shall be implemented. White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 6 of26 For Cells 1, 2, and 3, upon the initial pumping of fluid from an LOS, a fluid sample shall be collected and analyzed in accordance with paragraph l l .3C of the RML as described in the Tailings Management System procedure. For Cell 4A and 4B, under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower flexible membrane liner. To determine the Maximum Allowable Daily LDS Flow Rates in the Cell 4A and 4B leak detection systems, the total volume of all fluids pumped from the LDS on a weekly basis shall be recovered from the data collector, and that information will be used to calculate an average volume pumped per day. Under no circumstances shall the daily LOS flow volume exceed 24,160 gallons/day for Cell 4A or 26,145 gallons/day for Cell 4B. The maximum daily LDS flow volume will be compared against the measured cell solution levels detailed on Table lA and lB (for Cells 4A and 4B, respectively) in Attachment C, to determine the maximum daily allowable LOS flow volume for varying head conditions in Cell 4A and 4B. b) Slimes Drain Water Level Monitoring (i) Cell 3 is nearly full and will commence closure when filled. Cell 2 closed and Phase 1 cover activities have commenced. Each cell has a slimes drain system which aids in de watering the slimes and sands placed in the cel1; (ii) EFRI re-graded the interim fill on Cell 2 in 2011 in order to reduce the potential for the accumulation of storm water on the surface of Cell 2. As a result of the 2011 re- grading of the interim cover and the placement of an additional 62,000 cubic yards of fill material on Cell 2, the slimes drain access pipe was extended 6.97 feet. The extension pipe was 6.97 feet in length and the measuring point was 37 .97 feet from the bottom of the slimes drain. This value was used in all calculations from 4th quarter 2011 through the 3rd quarter 2016. In April 2016, Phase 1 cover placement and construction commenced. The Phase 1 cover activities include the placement and compaction of approximately 4.5 feet of soil materials. During the 3rd quarter 2016, the slimes drain access pipe was extended 5.44 feet as a result of the Phase 1 cover activities. The measuring point on the extension pipe was surveyed by a Utah- Certified Land Surveyor. The measuring point elevation is now 5624.17 fmsl. For the quarterly recovery test described in section vi below, this extension has no effect on the data measurement procedures. Cell 2 has a pump placed inside of the slimes drain access pipe at the bottom of the slimes drain. As taken from actual measurements, the bottom of the slimes drain is 43.41 feet below a water level measuring point which is a notch on the side of the Cell 2 slimes drain access pipe .. This means that the bottom of the slimes drain pool and the location of the pump are one foot above the lowest point of the FML in Cell 2, which, based on construction reports, is at a depth of 44.31 feet below the water level measuring point on the slimes drain access pipe for Cell 2; (iii)The slimes drain pump in Cell 2 is activated and deactivated by a float mechanism White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 . Page 7 of26 and water level probe system. When the water level reaches the level of the float mechanism the pump is activated. Pumping then occurs until the water level reaches the lower probe which turns the pump off. The lower probe is located one foot above the bottom of the slimes drain standpipe, and the float valve is located at three feet above the bottom of the slimes drain standpipe. The average wastewater head in the Cell 2 slimes drain is therefore less than 3 feet and is below the phreatic surface of tailings Cell 2, about 27 feet below the water level measuring point on the slimes drain access pipe. As a result, there is a continuous flow of wastewater from Cell 2 into the slimes drain collection system. Mill management considers that the average allowable wastewater head in the Cell 2 slimes drain resulting from pumping in this manner is satisfactory and is as low as reasonably achievable. (iv)All head measurements must be made from the same measuring point (the notch at the north side of the access pipe 5624.17 fmsl), and made to the nearest 0.01 foot. The equation specified in the GWDP will be used to calculate the slimes drain recovery elevation (SDRE). To calculate the SDRE contemplated by the GWDP, the depth to wastewater in the Cell 2 slimes drain access pipe (in feet) will be subtracted from the surveyed elevation of the measuring point. The calculation is as follows: 5624.17 -Depth to wastewater in the Cell 2 slimes drain access pipe = SDRE (v) Effective July 11, 2011, on a quarterly basis, the slimes drain pump will be turned off and the wastewater in the slimes drain access pipe will be allowed to stabilize for at least 90 hours. Once the water level has stabilized (based on no change in water level for three (3) successive readings taken no less than one (1) hour apart) the water level of the wastewater will be measured and recorded as a depth-in-pipe measurement on Quarterly Data form, by measuring the depth to water below the water level measuring point on the slimes drain access pipe; (vi)No process liquids shall be allowed to be discharged into Cell 2; (vii)In accordance with GWDP Part I.F.11 an Annual Slimes Drain Recovery Head Report will be submitted with the annual DMT report for fourth quarter. The Annual Slimes Drain Recovery Head Report will be submitted on or before of March 1 of each year. The report will conform to Part I.D.3, I.E.7 and Il.G of the GWDP; (viii) Because Cell 3, Cell 4A, and 4B are currently active, no pumping from the Cell 3, Cell 4A, or 4B slimes drain is authorized. Prior to initiation of tailings dewatering operations for Cell 3, Cell 4A, or Cell 4B, a similar procedure will be developed for ensuring that average head elevations in the Cell 3, Cell 4A, and 4B slimes drains are kept as low as reasonably achievable, and that the Cell 3, Cell 4A, and Cell 4B slimes drains are inspected and the results reported in accordance with the requirements of the permit. c) Tailings Wastewater Pool Elevation Monitoring Solution elevation measurements in Cells 1, 4A, and 4B are to be taken by survey on a weekly basis. The beach area in Cell 4B with the maximum elevation is to be taken by survey on a monthly basis when beaches are first observed, as follows: White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 8 of26 (i) The survey will be performed by the Mill's Radiation Safety Officer or designee (the "Surveyor") with the assistance of another Mill worker (the "Assistant"); (ii) The survey will be performed using a survey instrument (the "Survey Instrument") accurate to 0.01 feet, such as a Sokkai No. B21, or equivalent, together with a survey rod (the "Survey Rod") having a visible scale in 0.01 foot increments; (iii)The Reference Points for Cells 1, Cell 4A, and 4B, are known points established by professional survey. For Cell 1, the Reference Point is a wooden stake with a metal disk on it located on the southeast corner of Cell 1. The elevation of the metal disk (the "Reference Point Elevation") for Cell 1 is at 5,623.14 feet above mean sea level ("FMSL"). For Cell 4A and 4B, the Reference Point is a piece of stamped metal monument located next to the transformer on the south side of Cell 4A and 4B. The elevation at the top of this piece of rebar (the Reference Point Elevation for Cell 4A and 4B) is 5600.49 fmsl. The Surveyor will set up the Survey Instrument in a location where both the applicable Reference Point and pond surface are visible. (iv)Once in location, the Surveyor will ensure that the Survey Instrument is level by centering the bubble in the level gauge on the Survey Instrument; (v) The Assistant will place the Survey Rod vertically on the Reference Point (on the metal disk on the Cell 1 Reference Point on the top of the rebar on the Cell 4A and 4B Reference Point. The Assistant will ensure that the Survey Rod is vertical by gently rocking the rod back and forth until the Surveyor has established a level reading; (vi) The Surveyor will focus the cross hairs of the Survey Instrument on the scale on the Survey Rod, and record the number (the "Reference Point Reading"), which represents the number of feet the Survey Instrument is reading above the Reference Point; (vii) The Assistant will then move to a designated location where the Survey Rod can be placed on the surface of the main solution pond in the Cell 1, Cell 4A, or Cell 4B, or the area of the beach in Cell 4B with the highest elevation, as the case may be. These designated locations, and the methods to be used by the Assistant to consistently use the same locations are as follows: For a newly-constructed cell, when the cell is first placed into operation, the solution level is typically zero feet above the FML or a minimal elevation above the FML due to natural precipitation. For newly-constructed cells, measurement of solution level will commence within 30 days of authorization for use. Measurements will be conducted as described above in items d) (i) through d) (vii) of this Section consistent with current Mill health and safety procedures. The measurements will be completed using survey equipment and the appropriate length survey rod (either 25' or 45'). A. Pond Surface Measurements I. Cell 4A The Assistant will walk down the slope in the northeast comer of Cell 4A and place the Survey Rod at the liquid level. White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 9 of26 B. II. Cell 4B The Assistant will walk down the slope in the southeast corner of Cell 4B and place the Survey Rod at the liquid level. ill. Cell l A mark has been painted on the north side of the ramp going to the pump platform in Cell 1. The Assistant will place the Survey Rod against that mark and hold the rod vertically, with one end just touching the liquid surface; and Based on the foregoing methods, the approximate coordinate locations for the measuring points for the Cells are: Northinll Eastinll Cell 1 322,196 2,579,277 Cell 4A 320,300 2,579,360 Cell 4B 320,690 2,576,200 These coordinate locations may vary somewhat depending on solution elevations in the Pond and Cells; Cell 4B Beach Elevation Beach elevations in Cell 4B will commence when beaches are first observed. The Assistant will place the Survey Rod at the point on the beach area of Cell 4B that has the highest elevation. If it is not clear which area of the beach has the highest elevation, then multiple points on the beach area will be surveyed until the Surveyor is satisfied that the point on the Cell 4B beach area with the highest elevation has been surveyed. If it is clear that all points on the Cell 4B beach area are below 5,593 FMSL, then the Surveyor may rely on one survey point; (i) The Assistant will hold the Survey Rod vertically with one end of the Survey Rod just touching the pond surface. The Assistant will ensure that the Survey Rod is vertical by gently rocking the rod back and forth until the Surveyor has established a level reading; (ii) The Surveyor will focus the cross hairs of the Survey Instrument on the scale on the Survey Rod, and record the number (the "Pond Surface Reading"), which White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page IO of26 represents the number of feet the Survey Instrument is reading above the pond surface level. The Surveyor will calculate the elevation of the pond surface as FSML by adding the Reference Point Reading for the Cell, as the case may be, to the Reference Point Elevation for the Cell and subtracting the Pond Surface Reading for the Cell, and will record the number accurate to 0.01 feet. d) Decontamination Pads (i) New Decontamination Pad The New Decontamination Pad is located in the southeast corner of the ore pad, near the Mill's scale house. A. In order to ensure that the primary containment of the New Decontamination Pad water collection system has not been compromised, and to provide an inspection capability to detect leakage from the primary containment, vertical inspection portals have been installed between the primary and secondary containments; B. These portals will be visually observed on a weekly basis as a means of detecting any leakage from the primary containment into the void between the primary and secondary containment. The depth to water in each portal will be measured weekly, by physically measuring the depth to water with an electrical sounding tape/device. All measurements must be made from the same measuring point and be made to the nearest 0.01 foot; C. These inspections will be recorded on the Weeldy Tailings Inspection form; D. The water level shall not exceed 0.10 foot above the concrete floor in any standpipe, at any time. This will be determined by subtracting the weekly depth to water measurement from the distance from the measuring point in the standpipe to the dry concrete floor The depth to water from the top (elevation 5589.8 feet amsl) of any of the three (3) observation ports to the standing water shall be no less than 6.2 feet. Depths less than 6.2 feet shall indicate more that 0.1 foot of standing water above the concrete floor (elev. 5583.5 feet amsl), and shall indicate a leak in the primary containment. E. Any observation of fluid between the primary and secondary containments will be reported to the RSO. White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 11 of 26 F. In addition to inspection of the water levels in the standpipes, the New Decontamination Pad, including the concrete integrity of the exposed surfaces of the pad, will be inspected on a weekly basis. Any soil and debris will be removed from the New Decontamination Pad immediately prior to inspection of the concrete wash pad for cracking. Observations will be made of the current condition of the New Decontamination Pad. Any abnormalities relating to the pad and any damage to the concrete wash surface of the pad will be noted on the Weekly Tailings Inspection form. If there are any cracks greater than 1/8 inch separation (width), the RSO must be contacted. The RSO will have the responsibility to cease activities and have the cracks repaired. (ii) Existing Decontamination Pad The Existing Decontamination Pad is located between the northwest comer of the Mill's maintenance shop and the ore feeding grizzly. Weekly inspection requirements for the Existing Decontamination Pad are discussed in the Tailings Management System Procedure. e) Summary In addition, the weekly inspection should summarize all activities concerning the tailings area for that particular week. Results of the weekly tailings inspection are recorded on the Weekly Tailings and DMT Inspection form. An example of the Weekly Tailings and DMT Inspection form is provided in Appendix A to the Tailings Management System and as Attachment A to this DMT Plan. 3.2. Weekly Feedstock Storage Area fnspections Weekly feedstock storage area inspections will be performed by the Radiation Safety Department to confirm that: a) the bulk feedstock materials are stored and maintained within the defined area described in the GWDP, as indicated on the map attached hereto as Attachment B; b) a 4 ft. buffer is maintained at the periphery of the storage area which is absent bulk material in order to assure that the materials do not encroach upon the boundary of the storage area; and c) all alternate feedstock located outside the defined Feedstock Area are maintained within White Mesa Mill -Discharge M,nimizarion Technology Monitoring Plan water tight containers. 01/22 Revision: EFRI 13.0 Page 12 of26 The results of this inspection wi11 be recorded on the Ore Storage/Sample Pla,tt Weekly Inspection Repon, a copy of which is contained in Attachment A. Any variance in stored materials from this requirement or observed leaking alternate feedstock drums or other containers will be brought to the attention of Mill Management and rectified within 15 days. 4. ANNUAL EVALUATIONS The following annual evaluations shall be performed: 4.1. Annual Leak Detection. Fluid Samples Pursuant to Part J.E. JO(c) of the GWDP, a sample will be collected from the Cells 4A and 48 leak detection systems annually as part of the Tailings Ce JI Wastewater Quality Monitoring. Sampling procedures are described in the Tailings Sampling and Analysis PJan. 4.2. Annual In pection of the Decontamination Pads a) New Decontamination Pad During the second quarter of each year, the New Decontamination Pad will be taken out of ~ervicc and inspected to ensure the integrity of the wash pad's exposed concrete surface. If any abnormalities are identified, i.e. cracks in the concrete with greater than 1/8 inch separation (width) or any significant deterioration or damage of the pad surface, repairs will be made prior to resuming the use of the facility. All in$pection findings and any repairs required shalJ be documented on the Annual Decontamination Pad Inspection form. The inspection findings. any repairs required and repaiJ;S completed shall be summarized in the 2nd Quarter DMT Monitoring Rep01:t due Sept~mber 1 of each calendar year. b) Existing Decontamination Pad During the second quarte.r of each year, the EXisting Decontamination Pad will be taken out of service and inspected to ensure the integrity of the steel tank. Once the water and any sediment present is removed from the steel tank containment, the walls aad bottom of the tank will be visually inspected for arty areas of damage, cracks, or bubbling indicating corrosion that. may have occurred since the last inspection. If any abnormalities arc identified, defects or damage wm be reported to Mi11 management and repairs wiJl be made prior to resuming the use of the facility. All inspection findings and any repairs required shall be documented on the Annual Decontamination Pad Inspection fonn. A record of the repairs will be maintained as a part of the Annual Inspection records at the Mill site. The inspection findings, any repairs required and repairs completed shall be summarized in the 2nd Quarter DMT Monitoring Report due September l of each calendar year. White Mesa Mill -Discharge Minimization Technology Monitoring Plan 4.3. Annual Inspection of Waste Oil and Fuel Tanks 01/22 Revision: EFRI 13.0 Page 13 of 26 During the second quarter of each year, the used/waste oil tank and fuel tanks will be inspected to ensure the integrity of the tanks and support structures. The tanks and any associated piping will be visually inspected for signs of corrosion or leaking. Any concrete structures, containments and supports will be inspected to ensure the integrity of the exposed concrete surface. If any abnormalities are identified, i.e. cracks in the concrete with greater than 1/8 inch separation (width) or any significant deterioration or damage of the surface, repairs will be made within 7 days. All inspection findings and any repairs required shall be documented on the Annual Inspection form. The documentation of the inspection findings, any repairs required and repairs completed will be maintained at the Mill. 4.4. Annual Inspection of Hydrochloric Acid ("HCJ ') Secondary Containment Concrete During the second quarter of each year, the HCl secondary containment concrete will be inspected. Any associated piping will be visually inspected for signs of corrosion or leaking. Any concrete structures, containments and supports will be inspected to ensure the integrity of the exposed concrete surface. If any abnormalities are identified, i.e. cracks in the concrete with greater than 1/8 inch separation ( width) or any significant deterioration or damage of the surface, repairs will be made within 7 days. All inspection findings and any repairs required shall be documented on the Annual fuspection form included as Attachment A-7. The documentation of the inspection findings, any repairs required and repairs completed will be maintained at the Mill. S. INSPECTION OF THE AMMONIUM SULFATE COVER AREA After installation and approval of the As-Built plans by DRC, the Ammonium Sulfate Cover Area will be inspected quarterly for eight (8) quarters and annually thereafter. The annual inspections will be conducted during the second quarter of each year. The results of quarterly and annual inspections will be reported in the quarterly DMT Reports. Quarterly and annual inspections will be completed as described below and will be documented on the inspection form included as Attachment A-5. The Ammonium Sulfate Cover Area will be inspected to ensure the integrity of the exposed concrete and asphalt surfaces. If any abnormalities are identified, i.e. cracks in the concrete or asphalt with greater than 1/8 inch separation (width) or any significant deterioration or damage of the concrete pad or asphalt surfaces, repairs will be made within 7 calendar days of the inspection. All inspection findings and any repairs required shall be documented on the Decontamination Pad/Ammonium Sulfate Cover Area Inspection form. The inspection findings, any repairs required and repairs completed shall be summarized in the 2nd Quarter DMT Monitoring Report due September 1 of each calendar year. The first inspection of the Ammonium Sulfate Cover Area will be conducted during the second quarter in the year following installation/completion of the pad. While Mesa Mill -Discharge Minimization Technology Monitoring Plan 6. OTHER INSPECTIONS 01/22 Revision: EFRJ 13.0 Page 14of26 AU daily, weekly. monthly. quarterly and annual inspections and evaluations should be performed as specifi~d in this DMT Plan. See also the Tailings Management System procedure included in Lhe EPM for additional inspection requirements. However, additional inspections should be conducted after any significant storm or significant natural or man-made event occurs. 7. REPORTING REQUIREMENTS In addition to the forms included in this DMT Plan, the following additional reporti, shall also be prepared: 7 .1. DMT Reports Quarterly reports of DMT monitoring activities, which will include the following information, will be provided to the Executive Secretary on the schedule provided in Table 5 of the GWDP: a) On a quarterly basis, all required jnfonnation required by Part I .F.2 of the GWDP relating to the inspections described in Section 3.1 (a) (Leak Detection Systems Monitoring), Section 3. t (b) (Slimes Drain Water Level Monitoring), 3.1 (c) (Tailings Wastewater Pool Blevation Monitoring), 3. l(d) (Tailings Wastewater Pool and Beach Area Elevation Monitoring), 3.2(Weekly Feedstock Storage Area Inspections) 5.0 (Inspection of the Ammonium Sulfate Cover Area [for 8 quarters including any repairs required, and repairs completed]); b) On a quarterly basis, a summary of the weekly water level (depth) inspections for the quarler for the presence of fluid in all three v~rtij:~ inspection port~s for each of the three chambers in the concrete settling tank system for the New Decontamination Pad, which will include a table indicating the water level measurements in each portal during the quarter; c) With respect to the annual ittspection of the New Decontamination Pad descrjbed in Section 4.3(a); the inspection findings, any repairs required, and repairs completed shall be summarized in the 2nd Quarter report, due September I of each calendar year; d) With respect to the annual inspection of the Existing Decontamination Pad described in Section 4.3(b ), the inspection findings, any repairs required. and repair$ completed shall be summarized in the 2nd Quarter report, due September I of each calendar year; White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 15 of 26 e) With respect to the annual inspection (after the completion of 8 quarterly inspections) of the Ammonium Sulfate Cover Area described in Section 5.0, the inspection findings, any repairs required, and repairs completed shall be summarized in the 2nd Quarter report, due September 1 of each calendar year; and f) An annual summary and graph for each calendar year of the depth to wastewater in the Cell 2 slimes drain must be included in the fourth quarter report. White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT A FORMS 01/22 Revision: EFRI 13.0 Page 16 of26 White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 17 of26 ATTACHMENT A-1 DAILY INSPECTION DATA Any Item not "OK" must be documented. A check mark = OK, X = Action Required VII. DAILY LEAK DETECTION CHECK Cell 1 Cell 2 Cell 3 Inspector: ______ _ Date:. ________ _ Accompanied by: ___ _ Time:. ________ _ Cell 4A Cell 4B Leak Checked Checked Checked Checked Checked Detection System Wet Dry Wet Dry Wet Dry Wet Dry Wet Checked Initial level Initial level Initial level Initial level Initial level Final Final Final Final Final level level level level leve·1 Gal. pumrv>.rl Gal. pumnP.rl Gal. pump£>.rl Gal. pumned Gal. pumped Record Observations of Potential Concern and Actions Required on the Daily Inspection Form included in the Tailings Management System (Appendix A-1) Dry White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 Revision: EFRI 13.0 Page 18 of26 1. Pond and Beach elevations (msl, ft) ATTACHMENT A-2 WEEKLY TAILINGS INSPECTION Inspectors:------------- Cell 1: (a) Pond Solution Elevation (b) FML Bottom Elevation 5597 __ _ (c) Depth of Water above FML ((a)-(b)) _____ _ Cell 4A: (a)Pond Solution Elevation (b)FML Bottom Elevation 5555.14_ (c)Depth of Water above FML ((a)-(b)) ------ Cell 4B: (a)Pond Solution Elevation (b)FML Bottom Elevation 5557.50 (c)Depth of Water above FML ((a)-(b)) _____ _ ( d)Elevation of Beach Area with Highest Elevation (monthly) 2. Leak Detection Systems Observation: New Decon Pad, Portal 1 New Decon Pad, Po11al 2 New Decon Pad Portal 3 Is LDS (Portal) wet or __ wet __ dry __ wet __ dry __ wet __ dry dry? If wet, Record liquid Ft to Liquid Ft to Liquid Ft to Liquid level: If wet. Report to RSO * Does Level exceed 12 inches above the lowest point on the bottom flexible membrane liner (solution elevation of 5556.14 ams) for Cell 4A and 5558.50 for Cell 4B)? no __ yes If Cell 4A leak detection system level exceeds 12 inches above the lowest point on the bottom flexible membrane liner (elevation 5556.14 amsl), notify supervisor or Mill manager immediately. 3. New Decontamination Pad (concrete):-------------------- White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT A-3 01/22 Revision: EFRI 13.0 Page 19 of26 ORE STORAGE/SAMPLE PLANT WEEKLY INSPECTION REPORT Week of ____ through ____ Date of Inspection: _______ _ Inspector: ___________ _ Weather conditions for the week: Blowing dust conditions for the week: Corrective actions needed or taken for the week: Are all bulk feedstock materials stored in the area indicated on the attached diagram: yes: ___ no: ___ _ comments: ___________________________________ _ Are there any alternate feed materials stored outside the ore storage pad? yes: ___ no:. __ _ If yes, are the alternate feedstock materials located outside the ore storage pad maintained within water- tight containers: yes: ___ no: __ _ comments (e.g., conditions of containe.rs): ______________________ _ Are an sumps and low lying areas free of standing solutions? Yes: No: __ _ If "No", how was the situation corrected, supervisor contacted and correction date? Is there free standing water or water running off of the feedstock stockpiles? Yes: No: __ _ Comments: __________________________________ _ White Mesa Mill -Discharge Minimization Technology Monitoring Plan Ore Pad Stormwater Transfer Line: Is the transfer line visible? Yes: No: __ _ 01/22 Revision: EFRI 13.0 Page 20 of26 Comments: __________________________________ _ Is there any evidence of breakage, spillage or leakage? Yes: No: __ _ Comments: __________________________________ _ Other comments: Ore Pad Southwest Stormwater Containment {Kiva): Is there sediment or debris in the bottom of the Kiva? Yes: No: __ _ Comments: __________________________________ _ Is the sediment or debris level below the bottom of the outlet line? If the sediment/debris is greater than 3 inches deep, complete a work order to have the Kiva deaned out. If there is significant debris (tumble weeds or trash present, complete a work order to have the Kiva deaned out. Yes: No: __ _ Comments: __________________________________ _ White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT A-4 01/22 Revision: EFRI 13.0 Page 21 of26 ANNUAL DECONTAMINATION PAD INSPECTION Date of Inspection: -------- Inspector:----------- New Decontamination Pad: Are there any cracks on the wash pad surface greater than 1/8 inch of separation? _Yes_No Is there any significant deterioration or damage of the pad surface? __ Yes __ No Findings: Repair Work Required: Existing Decontamination Pad: Were there any observed problems with the steel tank? __ Yes __ No Findings: Repair Work Required: Note: For the annual inspection of the Existing and New Decontamination, the annual inspection findings, any repairs required, and repairs completed, along with a summary of the weekly inspections of the Decontamination Pads, shall be discussed in the 2"d Quarter report, due September 1 of each calendar year. White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT A-5 01/22 Revision: EFRI 13.0 Page 22 of26 AMMONIUM SULFATE COVER AREA INSPECTION Date of Inspection: ____ _ Ammonium Su]fate Concrete Pad: Are there any cracks on the concrete pad surface greater than 1/8 inch of separation? _Yes_No Is there any significant deterioration or damage of the pad surface? __ Yes __ No Findings: Repair Work Required: Ammonium Su]fate Aspha]t Cover: Are there any cracks on asphalt surface greater than 1/8 inch of separation? _Yes_No Is there any significant deterioration or damage of the asphalt surface? __ Yes __ No Findings: Repair Work Required: Note: For the quarterly inspection of the Ammonium Sulfate Cover Area, the quarterly inspection findings, any repairs required, and repairs completed, shall be discussed in the associated quarterly DMT Report. For the annual inspection of the Ammonium Sulfate Cover Area, the annual inspection findings, any repairs required, and repairs completed, along with a summary of the weekly inspections of the Decontamination Pads, shall be discussed in the 2"d Quarter report, due September 1 of each calendar year. White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENTA-6 01/22 Revision: EFRI 13.0 Page 23 of26 ANNUAL USED/WASTE OIL AND FUEL TANK INSPECTION Date of Inspection: ___ _ Are there any anomalies on tanks including dents or rusty areas? _Yes_No Comments: _________________________________ _ Inspect the following as appropriate. Note any leakage, seepage, breakage or unusual conditions. Pipeline Joints: _____________________________ _ Pipeline Supports: _____________________________ + Valves: ________________________________ _ Point(s) of Discharge: ___________________________ _ Are there any cracks on the concrete surfaces (if present) greater than 1/8 inch of separation? _Yes_No Is there any significant deterioration or damage of the concrete surfaces (if present)? __ Yes __ No Findings: Repair Work Required: Date Repair Work Completed (if applicable): ______ _ White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENTA-7 01/22 Revision: EFRI 13.0 Page 24 of26 ANNUAL HCI SECONDARY CONTAINMENT CONCRETE INSPECTION Date of Inspection: ___ _ Are there any anomalies on tanks? _Yes_No Comments: _________________________________ _ Inspect the following as appropriate. Note any leakage, seepage, breakage or unusual conditions. Pipeline Joints: _____________________________ _ Pipeline Supports: _____________________________ + Valves: ________________________________ _ Point(s) of Discharge: ___________________________ _ Are there any cracks on the concrete surfaces (if present) greater than 1/8 inch of separation? _Yes_No Is there any significant deterioration or damage of the concrete surfaces (if present)? __ Yes __ No Findings: Repair Work Required: Date Repair Work Completed (if applicable): ______ _ White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT B 01/22 Revision: EFRI 13.0 Page 25 of26 I UTAH * ENERGY FUELS RESOURCES (USA), INC. WHITE MESA MILL San Juan County, Utah Feedstock Storage Area Map c:::J Feedstock Storage Area Date: January 2022 Source: Energy Fuels, 2022 --·--~··-··· ,,.,u..,,3,11,, N A 0 50 100 200 Feet White Mesa Mill -Discharge Minimization Technology Monitoring Plan 01/22 ~evision: EFRI 13.0 Page 26 of26 FEEDSTOCK STORAGE AREA ATTACHMENT C TABLES Table IA Calculated Action leakage Rates for Various head Conditions Cell 4A White Mesa Mill Blanding. Utah Head above Liner System (feet) Calculated Action leakage Rate 5 10 15 20 25 30 35 37 ( gallons / acre / day ) Table 18 Calculated Action leakage Rates fqr Various head Conditions Cell 4B White Mesa Mill Blanding, Utah 222.04 314.01 384.58 444.08 496.50 543.88 587.46 604.01 Head above Liner System (feet) Calculated Action leak.age Rate ( gallons / acre / day ) 5 211.40 10 317.00 15 369.90 20 422.70 25 475.60 30 528.40 35 570.00 37 581.20 Appendix I White Mesa Mill Tailings Management System, 3/2017, Revision: EFR 2.5 WHITE MESA MILL TAILINGS MANAGEMENT SYSTEM Revision 2.5 March 2017 Prepared by: Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, CO 80228 White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 2 of 37 WHITE MESA MILL TAILINGS MANAGEMENT SYSTEM TABLE OF CONTENTS 1. IN"TRODUCTION ................................................................................................................... 3 1.1. Background ....................................................................................................................... 3 2. DAII..,Y TAIIJNGS IN"SPECTIONS ........................................................................................ 4 2.1. Daily Comprehensive Tailings Inspection ....................................................................... .4 2.2. Daily Operations Inspection .............................................................................................. ? 2.3. Daily Operations Patrol ..................................................................................................... ? 2.4. Training .............................................................................. : .............................................. ? 2.5. Tailings Emergencies ........................................................................................................ 7 3. WEEKLY TAILINGS AND DMT IN"SPECTION .................................................................. 8 3.1. Weekly Tailings Inspections ............................................................................................. 8 4. MONTfil Y TAILINGS INSPECTION ................................................................................ 11 5. QUARTERLYTAILIN"GS INSPECTION ............................................................................ 12 6. ANNUALEVALUATIONS .................................................................................................. 13 6.1. Annual Technical Evaluation .......................................................................................... 13 6.2. Movement Monitors ........................................................................................................ 14 6.3. Freeboard Limits ............................................................................................................. 15 6.3.1. Cell l ........................................................................................................................ 15 6.3.2. Cell 2 ........................................................................................................................ 15 6.3.3. Cell 3 ........................................................................................................................ 16 6.3.4. Cell 4A ..................................................................................................................... 16 6.3.5. Cell 4B ..................................................................................................................... 16 7. OTHER IN"SPECTIONS ........................................................................................................ 19 8. REPORTING REQUIREMENTS ......................................................................................... 19 8.1. Monthly Tailings Reports ............................................................................................... 19 8.2. Weekly Cell 1 and Cell 4B Photographs ......................................................................... 19 Appendix A AppendixB Appendix C AppendixD APPENDICES Forms Tailings Inspector Training Certification Form Example Freeboard Calculations for Cell 4B White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 1. INTRODUCTION 03/17 Revision: EFR 2.5 Page 3 of37 This Tailings Management System procedure for the White Mesa Mill (the "Mill") provides procedures for monitoring the tailings cell systems as required under State of Utah Radioactive Materials License No. UT1900479 (the "RML"). The procedures to demonstrate compliance with Discharge Minimization Technology ("DMT") as specified throughout Parts I.D, I.E and I.F of the Mill's Groundwater Discharge Permit ("GWDP") Number 370004, are presented in the DMT Monitoring Plan ("DMT Plan"), which is a separate Plan .. This Tailings Management System procedure and the DMT Plan when implemented in concert are designed as a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system including dike stability, liner integrity, and transport systems, and inspection of the feedstock storage areas at the Mill. This Tailings Management System is published and maintained in the Mill's Environmental Protection Manual while the DMT Plan is issued as a stand-alone document. 1.1. Background This Tailings Management System procedure was originally developed as Chapter 3.1 of the Mill's Environmental Protection Manual, under the Mill's NRC Source Material License, and constituted a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system. Upon the State of Utah becoming an Agreement State for uranium mills in 2004, the Mill's Source Material License was replaced by the State of Utah RML and the State of Utah GWDP. The GWDP required that Energy Fuels Resources (USA) Inc. ("EFRI") develop the initial DMT Plan in response to GWDP requirements. In developing the initial DMT Plan, EFRI combined the existing Tailings Management System procedure set out as Chapter 3.1 of the Mill's Environmental Protection Manual with a number of new DMT requirements from the GWDP to form the initial DMT Plan. The initial DMT Plan and subsequent revisions (through revision 11.5) maintained the requirements from the RML (i.e., Chapter 3 .1 of the Mill's Environmental Protection Manual) and the DMT requirements of the GWDP in a single document. However, after several years of implementing the DMT Plan, EFRI concluded that it is preferable to separate the RML portions of the DMT Plan from the GWDP portions of the DMT Plan, into two separate documents. The DMT Plan continues to be a stand-alone plan that contains the DMT requirements from the GWDP except for the daily recording of the Cells 1, 2, and 3 LDS measurements as noted below. However, the portions of the DMT Plan that flow from the RML and not from the GWDP have been separated from the DMT Plan and have been returned to their original status as this Tailings Management System procedure, which comprises Chapter 3.1 of the Mill's Environmental Protection Manual. This allows the DMT Plan to be managed, inspected and enforced under the requirements of the GWDP and this Tailings Management System procedure to White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 4 of 37 be managed, inspected and enforced under the requirements of the RML. In addition, EFRI has incorporated in this plan the requirements for operating mill tailings specified by the Environmental Protection Agency ("EPA") in 40 CFR Part 61, Revisions to National Emissions Standards for Radon Emissions From Operating Mill Tailings. This division of the requirements was discussed with DRC on October 26, 2011. DRC agreed with the division of the requirements into two distinct documents as noted in their correspondence dated December 20, 2011. Pursuant to a written request from DRC, dated May 30, 2012, the RML requirements for the inspections of the Cells 1, 2, and 3 Leak Detection Systems ("LDSs") have been included in this DMT Plan. The inclusion of this RML requirement is to address the DRC request for uniformity in monitoring and reporting requirements for Cells 1, 2, and 3 and to address anticipated GWDP modifications regarding the LOS monitoring in Cells 1, 2, and 3. 2. DAILY TAILINGS INSPECTIONS The following daily tailings inspections shall be performed: 2.1. Daily Comprehensive Tailings Inspection On a daily basis, including weekends, all areas connected with the evaporation cells (Cell 1 and Cell 4B) and the tailings cells (Cells 2, 3, 4A,) will be inspected. Observations will be made of the current condition of each cell, noting any corrective action that needs to be taken. The Radiation Safety Officer ("RSO") or his designee is responsible for performing the daily tailings inspections. The RSO may designate other individuals with training, as described in Section 2.4 below, to perform the daily tailings inspection. Observations made as required by this Tailings Management System by the inspector will be recorded on the Daily Inspection Data form (a copy of which is included in Appendix A to this Tailings Management System procedure). The daily leak detection check for Cells 1, 2, and 3 will be recorded on the Daily Inspection Data form included as Attachment A-1 of the DMT Plan. The Daily Inspection Data form included with this Tailings Management System procedure contains an inspection checklist, which includes a tailings cells map, and spaces to record observations, especially those of immediate concern and those requiring corrective action. The inspector will place a check by all inspection items that appear to be operating properly. Those items where conditions of potential concern are observed should be marked with an "X". A note should accompany the "X" specifying what the concern is and what corrective measures will resolve the problem. This observation of concern should be noted on the form until the problem has been remedied. The date that corrective action was taken should be noted as well. Additional inspection items are required under the DMT Plan, which requires that the daily inspection form requirements in Attachment A to the DMT Plan also be completed. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 5 of37 Areas to be inspected include the following: Cell 1, 2, 3, 4A and 4B, the liners of Cells 1, 2, and 3, Dikes 4A-S, 4A-E, and 4B-S, wind movement of tailings, effectiveness of dust minimization methods, spray evaporation, Cell 2 spillway, Cell 3 spillway, Cell 4A spillway, Cell 3, Cell 4A and 4B liquid pools and associated liquid return equipment, and the Cell 1, 2, and 3 leak detection systems. Operational features of the tailings area are checked for conditions of potential concern. The following items require visual inspection during the daily tailings inspection: a) Tailings slurry and SX raffinate transport systems from the Mill to the active disposal cell(s), and pool return pipeline and pumps. Daily inspections of the tailings lines are required to be performed when the Mill is operating. The lines to be inspected include the: tailings slurry lines from CCD to the active tailings cell; SX raffinate lines that can discharge into Cell 1, Cell 4A or Cell 4B; the pond return line from the tailings area to the Mill; and, lines transporting pond solutions from one cell to another. b) Cell 1. c) Cell 2. d) Cell 3. e) Cell 4A. f) Cell 4B. g) Dike structures including dikes 4A-S, 4A-E, and 4B-S. h) The Cell 2 spillway, Cell 3 spillway, Cell 4A spillway, Cell 3, Cell 4A and Cell 4B liquid pools and associated liquid return equipment. i) Presence of wildlife and/or domesticated animals in the tailings area, including waterfowl and burrowing animal habitations. j) Spray evaporation pumps and lines. k) Wind movement of tailings and dust minimization. Wind movement of tailings will be evaluated for conditions which may require White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 6 of 37 initiation of preventative dust minimization measures for cells containing tailings sand. During tailings inspection, general surface conditions will be evaluated for the following: 1) areas of tailings subject to blowing and/or wind movement, 2) liquid pool size, 3) areas not subject to blowing and/or wind movement, expressed as a percentage of the total cell area. The evaluations will be reviewed on a weekly basis, or more frequently if warranted, and will be used to direct dust minimization activities. 1) Observation of flow and operational status of the dust control/spray evaporation system(s). m) Observations of any abnormal variations in tailings pond elevations in Cells I, 3, 4A, and4B. n) Locations of slurry and SX discharge within the active cells. Slurry and SX discharge points need to be indicated on the tailings cells map included in the Daily Inspection Data form. o) An estimate of flow for active tailings slurry and SX line(s). p) An estimate of flow in the solution return line(s). q) Daily measurements in the leak detection system sumps of the tailings Cells I, 2, and 3 will be made when warranted by changes in the solution level of the respective leak detection system. Measurement of fluids in the Cells 4A and 4B leak detection system and recording of the daily measurements cif the Cells 1, 2, and 3 leak detection systems sumps are discussed in the DMT Plan. The trigger for further action when evaluating the measurements in the Cells 1, 2, and 3 leak detection systems is a gain of more than 12 inches in 24 hours. If observations of trigger levels of fluids are made, the Mill Manager should be notified immediately and the leak detection system pump started. Whenever the leak detection system pump is operating and the flow meter and totalizer is recording on Cells 1, 2, and 3, a notation of the date and the time will be recorded on the Daily Inspection Data form. This data will be used in accordance with License Condition 11.3 .B through 11.3 .E of the Mill's Radioactive Materials License, to determine whether or not the flow rate into the leak detection system is in excess of the License Conditions. ff an LDS monitoring system becomes inoperable, alternate methods for LDS fluid measurements may be employed following notification to the Director. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 7 of37 r) Observations regarding visible sediments (Celll and Cell 4B only). Items (a), (m), (n), and (o) are to be done only when the Mill is operating. When the Mill is down, these items cannot be performed. 2.2. Daily Operations Inspection During Mill operation, the Shift Foreman, or other person with the training specified in Section 2.4 below, designated by the Radiation Safety Officer, will perform an inspection of the tailings line and tailings area at least once per shift, paying close attention for potential leaks and to the discharges from the pipelines. Observations by the Inspector will be recorded on the appropriate line on the Operating Foreman's Daily Inspection form. 2.3. Daily Operations Patrol In addition to the inspections described in Sections 2.1 and 2.2 above, a Mill employee will patrol the tailings area at least twice per shift during Mill operations to ensure that there are no obvious safety or operational issues, such as leaking pipes or unusual wildlife activity or incidences. No record of these patrols need be made, but the inspectors will notify the RSO and/or Mill management in the event that during their inspection they discover that an abnormal condition or tailings emergency has occurred. 2.4. Training All individuals performing inspections described in Sections 2.1 and 2.2 above must have Tailings Management System training as set out in the Tailings Inspection Training procedure, which is attached as Appendix B. This training will include a training pack explaining the procedure for performing the inspection and addressing inspection items to be observed. In addition, each individual, after reviewing the training pack, will sign a certification form, indicating that training has been received relative to his/her duties as an inspector. 2.5. Tailings Emergencies Inspectors will notify the RSO and/or Mill management immediately if, during their inspection, they discover that an abnormal condition exists or an event has occurred that could cause a tailings emergency. Until relieved by the Environmental or Technician or RSO, inspectors will have the authority to direct resources during tailings emergencies. Any major catastrophic events or conditions pertaining to the tailings area should be reported immediately to the Mill Manager or the RSO, one of whom will notify Corporate Management. If White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 8 of37 dam failure occurs, notify your supervisor and the Mill Manager immediately. The Mill Manager will then notify Corporate Management, MSHA (303-231-5465), and the State of Utah, Division of Dam Safety (801-538-7200). 3. WEEKLY TAILINGS AND DMT INSPECTION 3 .1. Weekly Tailings Inspections Weekly tailings inspections are to be conducted by the Radiation Safety Department and include the following: a) Leak Detection Systems Each tailings cell's leak detection system shall be checked weekly (as well as daily) to determine whether it is wet or dry. If marked wet, the liquid levels need to be measured and reported. In Cell 1, 2, and Cell 3 the leak detection system is measured by use of a dual-probe system that senses the presence of solutions in the LDS system ( comparable to the systems in Cells 4A and 4B) and indicates the presence of solution with a warning light. The water levels are measured to the nearest 0.10 inch. The water level data in Cells 1, 2, and 3 is recorded on the Daily Tailings Inspection Form included as Attachment A-1 of the DMT Plan. If sufficient fluid is present in the leak detection system of Cells 1, 2, and 3, the fluid shall be pumped from the LDS, to the extent reasonably possible, and the volume of fluid recovered will be recorded. Any fluid pumped from an LDS shall be returned to a disposal cell. For Cells 1, 2, and 3, if fluid is pumped from an LDS, the flow rate shall be calculated by dividing the recorded volume of fluid recovered by the elapsed time since fluid was last pumped or increases in the LDS fluid levels were recorded, whichever is the more recent. This calculation shall be documented as part of the weekly inspection. For Cells 1 and 3, upon the initial pumping of fluid from an LDS, a fluid sample shall be collected and analyzed in accordance with paragraph 11.3 C. of the RML. The LDS requirements for Cells 4A and 4B are discussed in the DMT Plan. b) Slimes Drain Water Level Monitoring (i) Cell 3 is nearly full and will commence closure when filled. Cell 2 is partially reclaimed with the surface covered by platform fill. Each cell has a slimes drain t. ' White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 9 of37 system which aids in dewatering the slimes and sands placed in the cell; (ii) EFRI re-graded the interim fill on Cell 2 in order to reduce the potential for the accumulation of storm water on the surface of Cell 2. As a result of the re-grading of the interim cover and the placement of an additional 62,000 cubic yards of fill material on Cell 2, the slimes drain access pipe was extended 6.97 feet. The extension pipe is 6.97 feet in length, and therefore the new measuring point is 37 .97 feet from the bottom of the slimes drain. The measuring point on the extension pipe was surveyed by a Utah-Certified Land Surveyor. The measuring point elevation is 5618.73 fmsl. For the quarterly recovery test described in section vi below, this extension has no effect on the data measurement procedures. Cell 2 has a pump placed inside of the slimes drain access pipe at the bottom of the slimes drain. As taken from actual measurements, the bottom of the slimes drain is 37 .97 feet below a water level measuring point which is a notch on the side of the Cell 2 slimes drain access pipe. This means that the bottom of the slimes drain pool and the location of the pump are one foot above the lowest point of the FML in Cell 2, which, based on construction reports, is at a depth of 38.97 feet below the water level measuring point on the slimes drain access pipe for Cell 2; (iii)The slimes drain pump in Cell 2 is activated and deactivated by a float mechanism and water level probe system. When the water level reaches the level of the float mechanism the pump is activated. Pumping then occurs until the water level reaches the lower probe which turns the pump off. The lower probe is located one foot above the bottom of the slimes drain standpipe, and the float valve is located at three feet above the bottom of the slimes drain standpipe. The average wastewater head in the Cell 2 slimes drain is therefore less than 3 feet and is below the phreatic surface of tailings Cell 2, about 27 feet below the water level measuring point on the slimes drain access pipe. As a result, there is a continuous flow of wastewater from Cell 2 into the slimes drain collection system. Mill management considers that the average allowable wastewater head in the Cell 2 slimes drain resulting from pumping in this manner is satisfactory and is as low as reasonably achievable. (iv)The Cell 2 slimes drain pump is checked weekly to observe that it is operating and that the water level probe and float mechanism are working properly, which is noted on the Weekly Tailings Inspection Form. If at any time the pump is observed to be not working properly, it will be fixed or replaced within 15 days; (v) Depth to wastewater in the Cell 2 slimes drain access pipe shall be monitored and recorded weekly to determine maximum and minimum fluid head before and after a pumping cycle, respectively. The extension of the Cell 2 slimes drain access pipe did not require any changes to the measurement procedure. The surveyed measuring point on the extended pipe is used as required. The elevation of the measuring point is 5618.73 fmsl. The head measurements are calculated in the same manner, using the same procedures as those used prior to the extension of the Cell 2 slimes drain access pipe; however, the total depth to the bottom of the pipe is now 37.97 feet as noted on the corrected form in Attachment A. All head measurements must be made White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 10 of37 from the same measuring point ( the notch at the north side of the access pipe 5618. 73 fmsl), and made to the nearest 0.01 foot. The results will be recorded as depth-in- pipe measurements on the Weekly Tailings Inspection Form. The quarterly recovery test specified in the GWDP is discussed in the DMT Plan. It is important to note that the extension of the Cell 2 slimes access pipe has not changed the method of calculation of the pre-and post-pump head calculations, only the constant (Cell 2 slimes drain access pipe height) used in the calculation has changed. The head is calculated by subtracting the depth to liquid from 37.97 feet rather than from the previous measurement of 38 feet. The weekly Tailings Inspection form included in Attachment A has been changed to reflect the extension height; (vi)No process liquids shall be allowed to be discharged into Cell 2; (vii) Because Cell 3, Cell 4A, and 4B are currently active, no pumping from the Cell 3, Cell 4A, or 4B slimes drain is authorized. Prior to initiation of tailings dewatering operations for Cell 3, Cell 4A, or Cell 4B, a similar procedure will be developed for ensuring that average head elevations in the Cell 3, Cell 4A, and 4B slimes drains are kept as low as reasonably achievable, and that the Cell 3, Cell 4A, and Cell 4B slimes drains are inspected and the results reported in accordance with the requirements of the permit. c) Wind Movement of Tailings An evaluation of wind movement of tailings or dusting and control measures shall be taken if needed. d) Decontamination Pads (i) New Decontamination Pad The New Decontamination Pad is located in the southeast corner of the ore pad, near the Mill's scale house. Weekly and annual inspection requirements for the New Decontamination Pad are discussed in the DMT Plan. (ii) Existing Decontaminaiion Pad The Existing Decontamination Pad is located between the northwest corner of the Mill's maintenance shop and the ore feeding grizzly. A The Existing Decontamination Pad will be inspected on a weekly basis. Any soil and debris will be removed from the Existing Decontamination Pad immediately prior to inspection of the concrete wash pad for cracking Observations will be made of the current condition of the Existing Decontamination Pad, including the concrete integrity of the White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 11 of37 exposed surfaces of the pad. Any abnormalities relating to the pad and any damage or cracks on the concrete wash surface of the pad will be noted on the Weekly Tailings Inspection form. If there are any cracks greater than 1/8 inch separation (width), the RSO must be contacted. The RSO will have the responsibility to cease activities and have the cracks repaired. e) Weekly Photographs for EPA Subpart W Weekly photographs of Cells 1 and Cell 4B documenting observations regarding sediments present and proof of saturation as necessary. Digital photographs will be taken and will have at a minimum date and time electronically embedded. Notations regarding the completion of the photographic documentation will be made on the Weekly Tailings and DMT Inspection form in Attachment A. f) Summary In addition, the weekly inspection should summarize all activities concerning the tailings area for that particular week. Results of the weekly tailings inspection are recorded on the Weekly Tailings and DMT Inspection form. An example of the Weekly Tailings Inspection form is provided in Appendix A of this Tailings Management System procedure. A similar form containing DMT inspection requirements is provided as Attachment A of the DMT Plan. 4. MONTHLY TAILINGS INSPECTION Monthly tailings inspections will be performed by the RSO or his designee from the Radiation Safety Department and recorded on the Monthly Inspection Data form, an example of which is contained in Appendix A. Monthly inspections are to be performed no sooner than 14 days since the last monthly tailings inspection and can be conducted concurrently with the quarterly tailings inspection when applicable. The following items are to be inspected: a) Tailings Slurry Pipeline When the Mill is operating, the slurry pipeline will be visually inspected at key locations to determine pipe wear. The critical points of the pipe include bends, slope changes, valves, and junctions, which are critical to dike stability. These locations to be monitored will be determined by the Radiation Safety Officer or his designee from the Radiation Safety Department during the Mill run. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 b) Diversion Ditches 03/17 Revision: EFR 2.5 Page 12 of 37 Diversion ditches 1, 2 and 3 shall be monitored monthly for sloughing, erosion, undesirable vegetation, and obstruction of flow. Diversion berm 2 should be checked for stability and signs of distress. c) Sedimentation Pond Activities around the Mill and facilities area sedimentation pond shall be summarized for the month. d) Overspray Dust Minimization The inspection shall include an evaluation of overspray minimization, if applicable. This entails ensuring that the overspray system is functioning properly. In the event that overspray is carried more than 50 feet from the cell, the overspray system should be immediately shut-off. e) Remarks A section is included on the Monthly Inspection Data form for remarks in which recommendations can be made or observations of concern can be documented. f) Summary of Daily, Weekly and Quarterly Inspections The monthly inspection will also summarize the daily, weekly and, if applicable, quarterly tailings inspections for the specific month. In addition, settlement monitors are typically surveyed monthly and the results attached to the Monthly Inspection Data form. 5. QUARTERLY TAILINGS INSPECTION The quarterly tailings inspection is performed by the RSO or his designee from the Radiation Safety Department, having the training specified in Section 2.4 above, once per calendar quarter. A quarterly inspection should be performed no sooner than 45 days since the previous quarterly inspection was performed. Each quarterly inspection shall include an Embankment Inspection, an Operations/Maintenance Review, a Construction Review and a Summary, as follows: ( White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 a) Embankment Inspection 03/17 Revision: EFR 2.5 Page 13 of37 The Embankment inspection involves a visual inspection of the crest, slope and toe of each dike for movement, seepage, severe erosion, subsidence, shrinkage cracks, and exposed liner. b) Operations/Maintenance Review The Operations/Maintenance Review consists of reviewing Operations and Maintenance activities pertaining to the tailings area on a quarterly basis. c) Construction Review The Construction Review consists of reviewing any construction changes or modifications made to the tailings area on a quarterly basis. An estimate of the percentage of the tailings beach surface area and solution pool area is made, including estimates of solutions, cover areas, and tailings sands for Cells 3, 4A and 4B. d) Summary The summary will include all major activities or observations noted around the tailings area on a quarterly basis. If any of these conditions are noted, the conditions and corrective measures taken should be documented in the Quarterly Inspection Data form. An example of the Quarterly Inspection Data form is provided in Appendix A. 6. ANNUAL EVALUATIONS The following annual evaluations shall be performed: 6.1. Annual Technical Evaluation An annual technical evaluation of the tailings management system is performed by a registered professional engineer (PE), who has experience and training in the area of geotechnical aspects of retention structures. The technical evaluation includes an on-site inspection of the tailings management system and a thorough review of all tailings records for the past year. The Technical Evaluation also includes a review and summary of the annual movement monitor survey (see Section 5.2 below). White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3 .1 03/17 Revision: EFR 2.5 Page 14 of37 All tailings cells and corresponding dikes will be inspected for signs of erosion, subsidence, shrinkage, and seepage. The drainage ditches will be inspected to evaluate surface water control structures. fu the event tailings capacity evaluations (as per SOP PBL-3) were performed for the receipt of alternate feed material during the year, the capacity evaluation forms and associated calculation sheets will be reviewed to ensure that the maximum tailings capacity estimate is accurate. The amount of tailings added to the system since the last evaluation will also be calculated to determine the estimated capacity at the time of the evaluation. Tailings inspection records will consist of daily, weekly, monthly, and quarterly tailings inspections. These inspection records will be evaluated to detennine if any freeboard limits are being approached. Records will also be reviewed to summarize observations of potential concern. The evaluation also involves discussion with the Environmental and/or Radiation Technician and the RSO regarding activities around the tailings area for the past year. During the annual inspection, photographs of the tailings area will be taken. The training of individuals will be reviewed as a part of the Annual Technical Evaluation. The registered engineer will obtain copies of selected tailings inspections, along with the monthly and quarterly summaries of observations of concern and the corrective actions taken. These copies will then be included in the Annual Technical Evaluation Report. The Annual Technical Evaluation Report must be submitted by November 15th of every year to the Director and to the Assistant State Engineer, Utah Division of Water Rights at the address specified below. Assistant State Engineer Utah Division of Water Rights 1594 West North Temple, Suite 220 P.O. Box 146300 Salt Lake City, Utah 84114-6300 6.2. Movement Monitors A movement monitor survey is to be conducted by a licensed surveyor annually during the second quarter of each year. The movement monitor survey consists of surveying monitors along dikes 4A- E, 4A-S, and 4B-S to detect any possible settlement or movement of the dikes. The data generated from this survey is reviewed and incorporated into the Annual Technical Evaluation Report of the tailings management system. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 6.3. Freeboard Limits 03/17 Revision: EFR 2.5 Page 15 of37 The freeboard limits set out in this Section are intended to capture the Local 6-hour Probable Maximum Precipitation (PMP) event, which was determined in the January 10, 1990 Drainage Report (the "Drainage Report") for the White Mesa site to be 10 inches. The flood volume from the PMP event over the Cell 1 pond area plus the adjacent drainage areas, was calculated in the Drainage Report to be 103 acre feet of water, with a wave run up factor of 0.90 feet. The flood volume from the PMP event over the Cell 2 and Cell 3 pond areas, plus the adjacent drainage areas was calculated in the Drainage Report to be 123.4 acre-feet of water. The flood volume from the PMP event over the Cell 4A area was calculated in the Drainage Report to be 36 acre-feet of water (40 acres, plus the adjacent drainage area of 3.25 acres), times the PMP of 10 inches), with a wave run up factor of 0.77 feet. The flood volume from the PMP event over the Cell 4B area has been calculated to be 38.1 acre- feet of water ( 40 acres, plus the adjacent drainage area of 5. 72 acres), times the PMP of 10 inches, with a wave run up factor of 0.77 feet. The total pool surface area in Cell 1 is 52.9 acres, in Cell 4A is 40 acres, and in Cell 4B is 40 acres. The top of the flexible membrane liner ("FML") for Cell 1 is 5,618.2 FMSL, for Cell 4A is 5,598.5 FMSL and for Cell 4B is 5600.4 FMSL. Based on the foregoing, the free board limits for the Mill's tailings cells will be set as follows: 6.3.1. Cell 1 The freeboard limit for Cell 1 will be set at 5,615.4 FMSL. This will allow Cell 1 to capture all of the PMP volume associated with Cell 1. The total volume requirement for Cell 1 is 103 acre feet divided by 52.9 acres equals 1.95 feet, plus the wave run up factor of 0.90 feet equals 2.85 feet. The freeboard limit is then 5,618.2 FMSL minus 2.85 feet equals 5,6.15.4 FMSL. Under Radioactive Materials License condition 10.3, this freeboard limit is set and is not recalculated annually. 6.3.2. The freeboard limit for Cell 2 is inapplicable, since Cell 2 is filled with solids. All of the PMP volume associated with Cell 2 will be attributed to Cell 4A (and/or any future tailings cells). White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 6.3.3. Cell 3 03/17 Revision: EFR 2.5 Page 16 of 37 The freeboard limit for Cell 3 is inapplicable, since Cell 3 is close to being filled with solids, and all of the PMP flood volume associated with Cell 3 will be attributed to Cell 4B (and/or any future tailings cells). 6.3.4. Cell 4A The freeboard limit for Cell 4A is inapplicable since all of the PMP flood volume associated with Cell 4A will be attributed to Ce114B. A spillway has been added to Cell 4A to allow overflow into Cell 4B. 6.3.5. Cell 4B The. freeboard limit for Cell 4B will be set assuming that the total PMP volume for Cells 2, 3, 4A, and 4B of 159.4 acre feet will be accommodated in Cell 4B. The procedure for calculating the freeboard limit for Cell 4B is as follows: ( a) When the Pool Surface Area is 40 Acres When the pool surface area in Cell 4B is 40 acres (i.e., when there are no beaches), the freeboard limit for Cell 4B will be 5,594.6FMSL, which is 5.7 feet below the FML. This freeboard value was developed as follows: PMP Flood Volume Overflow from Cell 4A assuming no storage in Cell 3 or 4A Sum of PMP volume and overflow volume Depth to store PMP an overflow volume = 197.5 acre-feet/40 acres Wave run up factor Total required freeboard 38.1 acre-feet 159.4 acre-feet 197 .5 acre-feet 4.9 feet 0.77 feet 5.7 feet (all values in the above calculation have been rounded to the nearest one-tenth of afoot); (b) When the Maximum Elevation of the Beach Area is 5,594 FMSL or Less When the maximum elevation of the beach area in Cell 4B is 5594 FMSL or less, then the freeboard limit will be 5,594.6 FMSL, which is the same as in (a) above. This allows for the situation where there may be beaches, but these beaches are at a lower elevation than the freeboard limit established in (a) above, and there is therefore ample freeboard above the beaches to hold the maximum PMP volume. The maximum elevation of the beach area will be determined by monthly surveys performed by Mill personnel in accordance with the Mill's DMT Plan. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 17 of37 (c) When the Maximum Elevation of the Beach Area First Exceeds 5,594 FMSL When the maximum elevation of the beach area in Cell 4B first exceeds 5,594 FMSL, then the freeboard limit for the remainder of the ensuing year (period t=O) ( until the next November 1) will be calculated when that elevation is first exceeded (the "Initial Calculation Date"), as follows: i) The total number of dry tons of tailings that have historically been deposited into Cell 4B prior to the Initial Calculation Date ("To") will be determined; ii) The expected number of dry tons to be deposited into Cell 4B for the remainder of the ensuing year (up to the next November 1), based on production estimates for that period ("80*"), will be determined; iii) 80* will be grossed up by a safety factor of 150% to allow for a potential underestimation of the number of tons that will be deposited in the cell during the remainder of the ensuing year. This grossed up number can be referred to as the "modeled tonnage" for the period; iv) The total design tailings solid storage capacity of Cell 4B will be accepted as 2,094,000 dry tons of tailings; v) The available remaining space in Cell 4B for solids as at the Initial Calculation Date will be calculated as 2,094,000 dry tons minus To; vi) The reduction in the pool surface area for the remainder of the ensuing year will be assumed to be directly proportional to the reduction in the available space in Cell 4B for solids. That is, the reduced pool surface area for period t=O ("RP Ao"), after the reduction, will be calculated to be: (1 -(80* x 1.5) / (2,094,000 -To)) x 40 acres= RPAo vii) The required freeboard for Cell 4B for the remainder of the period t=O can be calculated in feet to be the wave run up factor for Cell 4B of 0.77 feet plus the quotient of 197.5 acre feet divided by the RP Ao. The freeboard limit for Cell 4B for the remainder of period t=O would then be the elevation of the FML for Cell 4B of 5594.0 FMSL less this required freeboard amount, rounded to the nearest one-tenth of a foot; and viii) The foregoing calculations will be performed at the Initial Calculation Date and the resulting free board limit will persist until the next November 1. An example of this calculation is set out in Appendix F. ( d) Annual Freeboard Calculation When the Maximum Elevation of the Beach Area Exceeds 5,594FMSL On November 1 of each year (the "Annual Calculation Date"), the reduction in pool area for the ensuing year (referred to as period t) will be calculated by: i) First, calculating the Adjusted Reduced Pool Area for the previous period (ARP At-I) to reflect actual tonnages deposited in Cell 4B for the previous period (period t-1). The RP At-I used for the previous period was based on expected tonnages for period t- 1, grossed up by a safety factor. The ARPAt-I is merely the RPA that would have White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 18 of37 been used for period t-1 had the actual tonnages for year t-1 been known at the outset of period t-1 and had the RP A been calculated based on the actual tonnages for period t-1. This allows the freeboard calculations to be corrected each year to take into account actual tonnages deposited in the cell as of the date of the calculation. The ARP At-t can be calculated using the following formula: (1 -~t-1 I (2,094,000 -Tt-t)) x ARPAt-2 = ARPAt-t Where: • ~t-1 is the actual number of dry tons of tailings solids deposited in Cell 4B during period t-1; • Tt-1 is the actual number of dry tons of tailings solids historically deposited in Cell 4B prior to the beginning of period t-1; and • ARPAt-2 is the Adjusted Reduced Pool Area for period t-2. If period t-2 started at the Initial Calculation Date, then ARP At-2 is 40 acres; ii) Once the ARP At-I for the previous period (period t-1) has been calculated, the RP A for the subject period (period t) can be calculated as follows: (1 -(~t* x 1.5) / (2,094,000 -Tt)) x ARPAt-t = RPAt Where: • ~t* is the expected number of dry tons of tailings to be deposited into Cell 4B for the ensuing year (period t), based on production estimates for the year (as can be seen from the foregoing formula, this expected number is grossed up by a safety factor of 1.5); • Ti is the actual number of dry tons of tailings solids historically deposited in Cell 4B prior to the beginning of period t; and • ARPA1-1 is the Adjusted Reduced Pool Area for period t-1, which is the pool surface area for the previous period (period t-1) that should have applied during that period, had modeled tonnages (i.e., expected tonnages grossed up by the 150% safety factor) equaled actual tonnages for the period; iii) The required freeboard for period t can be calculated in feet to be the wave run up factor for Cell 4B of 0. 77 feet plus the quotient of 197.5 acre feet divided by the RP At. The freeboard limit for Cell 4B for period t would then be the elevation of the FML for Cell 4B of 5594.0 FMSL less this required freeboard amount, rounded to the nearest one-tenth of a foot; and iv) The foregoing calculations will be performed at the Annual Calculation Date for period t and the resulting free board limit will persist until the next Annual Calculation Date for period t+ 1. An example of this calculation is set out in Appendix D. (e) When a Spillway is Added to Cell 4B that Allows Overflow Into a New Tailings Cell When a spillway is added between Cell 4B and a new tailings cell then, if an approved freeboard White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 19 of 37 limit calculation method for the new cell is set to cover the entire PMP event for Cells 2, 3, 4A, 4B and the new tailings cell, the freeboard limit for Cell 4B will be inapplicable, except for approved provisions to prevent storm water runoff from overtopping dikes. 7. OTHER INSPECTIONS All daily, weekly, monthly, quarterly and annual inspections and evaluations should be performed as specified in Sections 2, 3, 4, 5 and 6 above. However, additional inspections should be conducted after any significant storm or significant natural or man-made event occurs. 8. REPORTING REQUIREMENTS In addition to the Daily inspection forms included as Appendix A to this Tailings Management System procedure, the inspection forms included as Attachment A of the DMT Plan and the Operating Foreman's Daily Inspection form the following additional reports shall also be prepared: 8.1. Monthly Tailings Reports Monthly tailings reports are prepared every month and summarize the previous month's activities around the tailings area. If not prepared by the RSO, the report shall be submitted to the RSO for review. The Mill Manager will review the report as well before the report is filed in the Mill Central File. The report will contain a summary of observations of concern noted on the daily and weekly tailings inspections. Corrective measures taken during the month will be documented along with the observations where appropriate. All daily and weekly tailings inspection forms will be attached to the report. A monthly inspection form will also be attached. Quarterly inspection forms will accompany the report when applicable. The report will be signed and dated by the preparer in addition to the Radiation Safety Officer and the Mill Manager. 8.2. Weekly Cell 1 and Cell 4B Photographs Weekly photographs taken in response to EPA 40 CFR Part 61 will be stored on the Mill network and reported in the EPA Central Data Exchange at least monthly (as available). If the EPA Central Data Exchange is unavailable, the photographs will be maintained at the Mill in an electronic format. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 APPENDIX A FORMS 03/17 Revision: EFR 2.5 Page 20 of37 White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3 .1 03/17 Revision: EFR 2.5 Page 21 of 37 APPENDIXA-1 DAILY INSPECTION DATA Inspector: ______ _ Date~-------- Accompanied by: ___ _ Time: _______ _ Any Item not "OK" must be documented. A check mark= OK, X = Action Required I. TAILINGS SLURRY TRANSPORT SYSTEM I lnsoection Items Conditions of Potential Concern Cell 1 Cell 2 Cell 3 Slurry Pioeline Leaks, Damage, Blockage, Sharo Bends Pipeline Joints Leaks, Loose Connections Pipeline Supports Damage, Loss of Support Valves Leaks, Blocked, Closed Point(s) of Discharge Improper Location or Orientation n. OPERATIONAL SYSTEMS and INTERIOR of CELLS Insnection Items Conditions of Potential Concern Cell 1 Cell 2 Cell 3 N s E w Interior Cell Walls Liner Observable Liner Damage Water Level Greater Than Operating Level, Large Change Since Previous Inspection Beach Cracks, Severe Erosion, Subsidence Liner and Cover Erosion of cover, Exposure of Liner Cell4A Cell4B Ce114A Cell 4B N s EW N S E w I Presence of Sediments Sediments should be saturated YorN NIA NIA NIA YorN Notes:~~~~:::===~==========-=------------------------------- -- White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 Ill. DIKES AND EMBANKMENTS Insgection Items Conditions of Potential Concern Slopes Sloughs or Sliding Cracks, Bulges, Subsidence, Severe Erosion, Moist Areas, Areas of Seepage Outbreak Crest Cracks, Subsidence, Severe Erosion IV. FLOWRATES Dike 1-I No visible exterior slope or dike to inspect No visible exterior slope or dike to inspect I Dike 1- lA No visible exterior slope or dike to inspect No visible exterior slope or dike to inspect 03/17 Revision: EFR 2.5 Page 22 of37 Dike2 Dike3 No No visible visible exterior exterior slope or slope or dike to dike to inspect inspect No No visible visible exterior exterior slope or slope or dike to dike to inspect inspect Dike 4A-S Slurrv Line(s) Pond Return S-X Tails GPM V. PHYSICAL INSPECTION OF SLURRY LINES(S) Walked to Discharge Point Observed Entire Discharge Line VI. DUST CONTROL Dusting Wind Movement of Tailings Precipitation: inches liquid Slimes Cell2 _____ "Y'es _____ 'Y"es Ce113 Dike Dike 4A-E 4B-S Sorav Svstem -----~No ______ No Cell4A Ce114B White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 General Meteorological conditions: VII. DAILY LEAK DETECTION CHECK 03/17 Revision: EFR 2.5 Page 23 of 37 Daily Leak Detection Checks are recorded on the Daily Inspection Data form included as Attachment A-1 of the DMT Plan VIll OBSERVATIONS OF POTENTIAL CONCERN - Action Required Tailings Daily Inspection Repmt Tailings Sluny Discharge Locatiou I j ,I I I I •-------• ' I I I I I MILL SITE ; I i ( I I I ; ; : , . CELL N0.1 I' l, I 1-"\ !-L (/ ' ---------j __.._ ...... Dilte 1-l I t I , ·--.___ ·---.. _ CELL NO. 2 ; I , "· ... _ "'·· Fill~ I ! ./! Ctf.LNo Dik.~-----, .... ,,____ / / ( ·-----.:-----.. _ ,'' ' I :· ·-----. / ·--D~J··-~----j I CELL NO. 48 /. 1, \. :· ·~~ II.:' CELL NO. 4A 1/ • .. -"il."c-q9 . . fg s----! l!;' Date: N:: / L~ /H 'µ,14~~1.\S .. Inspect or: . ~ .. N ~--~. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 25 of37 APPENDIX A-2 WHITE MESA MILL WEEKLY TAILINGS INSPECTION Date: _______ _ 1. Slimes Drain Liquid Levels Cell 2 Inspectors:-------------- Pump functioning properly ___ _ _______ Depth to Liquid pre-pump _______ Depth to Liquid Post-pump (all measurements are depth-in-pipe) Pre-pump head is 43.41 '-Depth to Liquid Pre- pump = __ _ Post-pump head is _43.41' -Depth to Liquid Post- pump = __ _ 2. Existing Decontamination Pad (concrete): ___________________ _ 3. Tailings Area Inspection (Note dispersal of blowing tailings): 4. Sediments visible in: Cell 1: Y Or N Cell 4B: Y Or N If yes, are they saturated? Y Or N 5. If no, note corrective actions:. ______________________ _ 6. Control Methods Implemented: _____________________ _ 7. Remarks: ________________________________ _ 8. Designated Disposal Area for Non-Tailings Mill Waste (awaiting DRC approval) White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 26 of37 APPENDIX A-3 MONTHLY INSPECTION DATA Inspector:------------- Date: --------------- 1. Slurry Pipeline: ------------------------------ 2. Diversion Ditches and Diversion Berm: Observation: Diversion Ditches: Sloughing Erosion Undesirable Vegetation Obstruction of Flow Diversion Berm: Stability Issues Signs of Distress Diversion Ditch 1 __ yes __ no yes __ no yes __ no yes __ no __ yes __ no __ yes __ no Diversion Ditch 2 __ yes __ no yes __ no __ yes __ no yes __ no Diversion Ditch 3 Diversion Berm 2 __ yes __ no __ yes __ no __ yes __ no yes __ no Comments:, _________________________________ _ 3. Summary of Activities Around Sedimentation Pond: ---------------- ( White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 4. Overspray Dust Minimization: Overspray system functioning properly: ___ __,yes. __ ~no Overspray carried more than 50 feet from the cell: yes no If "yes", was system immediately shut off? __ yes __ no 03/17 Revision: EFR 2.5 Page 27 of37 Comments: __________________________________ _ 5. Remarks:-------------------------------- 6. Settlement Monitors: Attach the Settlement monitor monthly survey data (spreadsheet). Note any unusual observations below. 7. Movement Monitors: (Is there visible damage to any movement monitor or to adjacent surfaces)? 8. Summary of Daily, Weekly and Quarterly Inspections: --------------- 9. Monthly LDS Pump Checks in Cells 4A and 4B: White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 28 of37 APPENDIX A-4 WIDTE MESA MILL TAILINGS MANAGEMENT SYSTEM QUARTERLY INSPECTION DATA Inspector:------------- Date: --------------- 1. Embankment Inspection: --------------------- 2. Operations/Maintenance Review: 3. Construction Activities:-------------------- 4. Estimated Areas: Cell 3 Cell 4A Cell 4B Estimated percent of beach surface area Estimated percent of solution pool area Estimated percent of cover area Comments: ------------ White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 APPENDIXB TAILINGS INSPECTOR TRAINING 03/17 Revision: EFR 2.5 Page 29 of37 This document provides the training necessary for qualifying management-designated individuals for conducting daily tailings inspections. Training information is presented by the Radiation Safety Officer or designee from the Environmental Department. Daily tailings inspections are conducted in accordance with the White Mesa Mill Tailings Management System and Discharge Minimization Technology (DMT) Monitoring Plan. The Radiation Safety Officer or designee from the Radiation Safety Department is responsible for performing monthly and quarterly tailings inspections. Tailings inspection forms will be included in the monthly tailings inspection reports, which summarize the conditions, activities, and areas of concern regarding the tailings areas. Notifications: The inspector is required to record whether all inspection items are normal (satisfactory, requiring no action) or that conditions of potential concern exist (requiring action). A "check" mark indicates no action required. If conditions of potential concern exist the inspector should mark an "X" in the area the condition pertains to, note the condition, and specify the corrective action to be taken. If an observable concern is made, it should be noted on the tailings report until the corrective action is taken and the concern is remedied. The dates of all corrective actions should be noted on the reports as well. Any major catastrophic events or conditions pertaining to the tailings area should be reported immediate} y to the Mill Manager or the Radiation Safety Officer, one of whom will notify Corporate Management. If dam failure occurs, notify your supervisor and the Mill Manager immediately. The Mill Manager will then notify Corporate Management, MSHA (303-231-5465), and the State of Utah, Division of Dam Safety (801-538-7200). Inspections: All areas of the tailings disposal system are routinely patrolled and visible observations are to be noted on a daily tailings inspection form. Refer to Appendix A of this Tailings Management System procedure. A similar form containing DMT inspection requirements is provided as Attachment A of the DMT Plan. The inspection form contained in this Tailings Management System procedure is summarized as follows: 1. Tailings Slurry Transport System: The slurry pipeline is to be inspected for leaks, damage, and sharp bends. The pipeline joints .. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 30 of 37 are to be monitored for leaks, and loose connections. The pipeline supports are to be inspected for damage and loss of support. Valves are also to be inspected particularly for leaks, blocked valves, and closed valves. Points of discharge need to be inspected for improper location and orientation. 2. Operational Systems: Operating systems including water levels, beach liners, and covered areas are items to be inspected and noted on the daily inspection forms. Sudden changes in water levels previously observed or water levels exceeding the operating level of a pond are potential areas of concern and should be noted. Beach areas that are observed as having cracks, severe erosion or cavities are also items that require investigation and notation on daily forms. Exposed liner or absence of cover from erosion are potential items of concern for ponds and covered areas. These should also be noted on the daily inspection form. Cells 1, 3, 4A and 4B solution levels are to be monitored closely for conditions nearing maximum operating level and for large changes in the water level since the last inspection. All pumping activities affecting the water level will be documented. In Cells 1 and 3, the PVC liner needs to be monitored closely for exposed liner, especially after storm events. It is important to cover exposed liner immediately as exposure to sunlight will cause degradation of the PVC liner. Small areas of exposed liner should be covered by hand. Large sections of exposed liner will require the use of heavy equipment These conditions are considered serious and require immediate action. After these conditions have been noted to the Radiation Safety Officer, a work order will be written by the Radiation Safety Officer and turned into the Maintenance Department. All such repairs should be noted in the report and should contain the start and finish date of the repairs. 3. Dikes and Embankments: Inspection items include the slopes and the crests of each dike. For slopes, areas of concern are sloughs or sliding cracks, bulges, subsidence, severe erosion, moist areas, and areas of seepage outbreak. For crests, areas of concern are cracks, subsidence, and severe erosion. When any of these conditions are noted, an "X" mark should be placed in the section marked for that dike. In addition, the dikes, in particular dikes 4A-S, 4A-E, and 4B-S,, should be inspected closely for mice holes and more importantly for prairie dog holes, as the prairie dogs are likely to burrow in deep, possibly to the liner. If any of these conditions exist, the inspection report should be marked accordingly. \ White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3. l 4. Flow Rates: 03/17 Revision: EFR 2.5 Page31 of37 Presence of all flows in and out of the cells should be noted. Flow rates are to be estimated in gallons per minute (GPM). Rates need to be determined for slurry lines, pond return, SX- tails, and the spray system. During non-operational modes, the flow rate column should be marked as "O". The same holds true when the spray system is not utilized. 5. Physical Inspection of Slurry Line(s): A physical inspection of all slurry lines has to be made every 4 hours during operation of the mill. If possible, the inspection should include observation of the entire discharge line and discharge spill point into the cell. If "fill to elevation" flags are in place, the tailings and build-up is to be monitored and controlled so as to not cover the flags. 6. Dust Control: Dusting and wind movement of tailings should be noted for Cells 2, 3, 4A, and 4B. Other observations to be noted include a brief description of present weather conditions, and a record of any precipitation received. Any dusting or wind movement of tailings should be documented. In addition, an estimate should be made for wind speed at the time of the observed dusting or wind movement of tailings. The Radiation Safety Department measures precipitation on a daily basis. Daily measurements should be made as near to 8:00 a.m. as possible every day. Weekend measurements will be taken by Environmental, Health and Safety personnel as close to 8:00 a.m. as possible. All snow or ice should be melted before a reading is taken. 7. Observations of Potential Concern: All observations of concern during the inspection should be noted in this section. Corrective action should follow each. area of concern noted. All work orders issued, contacts, or notifications made should be noted in this section as well. It is important to document all these items in order to assure that the tailings management system records are complete and accurate. 8. Map of Tailings Cells: The last section of the inspection involves drawing, as accurately as possible, the following items where applicable. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 1. Cover area 2. Beach/tailing sands area 3. Solution as it exists 4. Pump lines 03/17 Revision: EFR 2.5 Page 32 of37 5. Activities around tailings cell (i.e. hauling trash to the dump, liner repairs, etc.) 6. Slurry discharge when operating 7. Over spray system when operating 9. Safety Rules: All safety rules applicable to the mill are applicable when in the tailings area. These rules meet the required MSHA regulations for the tailings area. Please pay particular notice to the following rules: 1. The posted speed limit on Cell 4A and 4B dike is 5 mph, and the posted speed limit for the tailings area ( other than the Cell 4A and 4B dike) is 15 mph. These limits should not be exceeded. 2. No food or drink is permitted in the area. 3. All personnel entering the tailings area must have access to a two-way radio. 4. Horseplay is not permitted at any time. 5. Only those specifically authorized may operate motor vehicles in the restricted area. 6. When road conditions are muddy or slick, a four-wheel drive vehicle is required in the area. 7. Any work performed in which there is a danger of falling or slipping in the cell will require the use of a safety belt or harness with attended life line and an approved life jacket. A portable eyewash must be present on site as well. 8. Anytime the boat is used to perform any work; an approved life jacket and goggles must be worn at all times. There must also be an approved safety watch with a two-way hand- held radio on shore. A portable eyewash must be present on site as well. 10. Preservation of Wildlife: Every effort should be made to prevent wildlife and domesticated animals from entering the tailings area. All wildlife observed should be reported on the Wildlife Report W orkshee! during each shift. Waterfowl seen near the tailings cells should be discouraged from landing by the use of noisemakers. 11. Certification: Following the review of this document and on-site instruction on the tailings system inspection program, designated individuals will be certified to perform daily tailings inspections. The Rl;1diation Safety Officer authorizes certification. Refer to the Certification ( White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 33 of37 Form, Appendix C. This form should be signed and dated only after a thorough review of the tailings information previously presented. The form will then be signed by the RSO and filed. White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 APPENDIXC CERTIFICATION FORM Date:------------ Name: ------------ 03/17 Revision: EFR 2.5 Page 34 of37 I have read the document titled "Tailings Management System, White Mesa Mill Tailings Inspector Training" and have received on-site instruction at the tailings system. This instruction included documentation of daily tailings inspections, analysis of potential problems (dike failures, unusual flows), notification procedures and safety. Signature I certify that the above-named person is qualified to perform the daily inspection of the tailings system at the White Mesa Mill. Radiation Safety Personnel/ Tailings System Supervisor White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3 .1 Assumptions and Factors: APPENDIXD Example of Freeboard Calculations For Cell 4B o Total PMP volume to be stored in Cell 4B -159.4 acre feet o Wave runup factor for Cell 4B -0.77 feet o Total capacity of Cell 4B -2,094,000 dry tons o Elevation of FML of Cell 4B -5,600.35 FMSL o Maximum pool surface area of Cell 4B -40 acres 03/17 Revision: EFR 2.5 Page 35 of37 o Total tailings solids deposited into Cell 4B at time beach area first exceeds 5,594 FMSL-1,000,000 dry tons* o Date beach area first exceeds 5,594, FMSL-March 1, 2012* o Expected and actual production is as set forth in the following table: Time Period Expected Expected Tailings Actual Tailings Solids Tailings Solids Solids Disposition into Disposition into Cell 4B Disposition into Cell 4B at the determined at end of Cell4B beginning of the the period (dry tons)* Determined at period, multiplied by the beginning of 150 % Safety Factor the period ( dry (dry tons) tons)* March 1, 2012 to 150,000 225,000 225,000 November 1, 2012 November 1, 2012 to 300,000 450,000 275,000 November 1, 2013 November 1, 2013 to 200,000 300,000 250,000 November 1, 2014 *These expected and actual tailings and production numbers and dates are fictional and have been assumed for illustrative purposes only. Based on these assumptions and factors, the freeboard limits for Cell 4B would be calculated as follows: 1. Prior to March 1. 2012 Prior to March 1, 2012, the maximum elevation of the beach area in Cell 4B is less than or White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 36 of37 equal to 5,594 FMSL, therefore the freeboard limit is set at 5,594.6 FMSL. 2. March l, 2012 to November 1. 2012 The pool surf ace area would be reduced to the following amount (1 -225,000/ (2,094,000 -1,000,000)) x 40 acres= 31.77 acres Based on this reduced pool area, the amount of free board would be 197. 5 acre feet divided by 31. 77 acres equals 6.22 feet. When the wave run up factor for Cell 4B of 0. 77 feet is added to this, the total freeboard required is 6.99 feet. This means that the freeboard limit for Cell 4B would be reduced from 5594.6 FMSL to 5592.2 FMSL (5594.6 FMSL minus 6.22 feet, rounded to the nearest one- tenth of a foot). This calculation would be performed at March 1, 2012, and this freeboard limit would persist until November 1, 2012. 3. November 1. 2012 to November l, 2013 The pool surface area would be reduced to the following amount: First, recalculate the pool surface area that should have applied during the previous period, had modeled tonnages (i.e., expected tonnages grossed up by the 150% safety factor) equaled actual tonnages for the period. Since the actual tonnage of 225,000 dry tons was the same as the modeled tonnage of 225,000 dry tons, the recalculated pool surface area is the same as the modeled pool surface area for the previous period, which is 31.77 acres. Then, calculate the modeled pool surface area to be used for the period: (1-450,000/ (2,094,000-1,000,000-225,000)) x 31.77 acres= 15.32 acres Based on this reduced pool area, the amount of freeboard would be 197 .5 acre feet divided by 15.32 acres equals 12.89 feet. When the wave run up factorforCell 4B of0.77 feet is added to this, the total free board required is 13 .66 feet. This means that the free board limit for Cell 4B would be reduced from 5592.2 FMSL to 5586.7 FMSL (5600.35 FMSL minus 13.66 feet, rounded to the nearest one-tenth of a foot). This calculation would be performed at November 1, 2012, and this freeboard limit would persist until November 1, 2013. 4. November 1. 2013 to November 1. 2014. The pool surface area would be reduced to the following amount: First, recalculate the pool surface area that should have applied during the previous period, had modeled tonnages (i.e., expected tonnages grossed up by the 150% safety factor) equaled actual tonnages for the period. Since modeled tonnages exceeded actual tonnages, the pool area was reduced too much during the previous period, and must be adjusted. The recalculated pool area for the previous period is: ( ' l White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 03/17 Revision: EFR 2.5 Page 37 of 37 (1 -275,000/ (2,094,000-1,000,000 -225,000) x 31.77 acres= 21.72 acres. This recalculated pool surface area will be used as the starting point for the freeboard calculation to be performed at November 1, 2013. Then, calculate the modeled pool surface area to be used for the period: (1 -300,000 I (2,094,000 -1,000,000 -225,000 -275,000)) x 21.72 acres= 10.75 acres Based on this reduced pool area, the amount offreeboard would be 197.5 acre feet divided by 10.75 acres equals 18.37 feet. When the wave run up factor for Cell 4B of 0.77 feet is added to this, the total freeboard required is 19 .14 feet. This means that the freeboard limit for Cell 4B would be reduced from 5586.7 FMSL to 5581.2 FMSL (5600.4 FMSL minus 18.4 feet, rounded to the nearest one-tenth of a foot). This calculation would be performed at November 1, 2013, and this freeboard limit would persist until November 1, 2014. Appendix J Cell 2 Slimes Drain Calculations and Figure 2009-2022 n tD --N V, --· 3 tD "' C @ -::::, I N 0 0 \D I N 0 N N Vl fl) :::::!. fl) V> N C: ::, fl) Q) .... vi" fl) -, it," V> N lJJ 0 i:::::, 0 N ID i:::::, 0 N 00 i:::::, 0 Feet Below Top of Standpipe N -..J i:::::, 0 N a, i:::::, 0 N V, i:::::, 0 N :, i:::::, 0 N lJJ i:::::, 0 N N i:::::, 0 N N I-' 0 i:::::, i:::::, 0 0 1/30/2009 6/30/2009 11/30/2009 4/30/2010 9/30/2010 2/28/2011 7/31/2011 12/31/2011 5/31/2012 10/31/2012 3/31/2013 8/31/2013 1/31/2014 6/30/2014 11/30/2014 4/30/2015 9/30/2015 2/29/2016 7/31/2016 12/31/2016 5/31/2017 10/31/2017 3/31/2018 8/31/2018 1/31/2019 6/30/2019 11/30/2019 4/30/2020 9/30/2020 2/28/2021 7/31/2021 12/31/2021 Cell 2 Slimes Drain Monthly Volumes of Fluids Pumped Total Pum;pea, by Month ' Date (gal) January-18 103660 February-18 92178 March-18* 86924 April-18 99087 May-18 100122 June-18* 76523 July-18 109049 August-18 100122 September-18* 85596 "October-18* 95366 November-18 96712 December-18 100183 2018Total U455Z2 *Pursuant to Part I.D.3(b) of the January 19, 2018 GWDP, slimes darin recovery tests were performed quarterly. The recovery tests (and GWDP) require the pump to be turned off for 90 hours. No pumping of slimes drain fluid occurs during the recovery test. Less volumes are reported during the months in which the recovery tests are conducted. Cell 2 Slimes Drain Recovery Head and SORE Values for 2018 2018 Test Elevation of Reported Level SORE Values Closing Date Measurement (feet) (Reported as fmsl) Point (fmsl) 3/28/2018 5ti24.17 27.88 5596.29 6/28/2018 562..,4.17. 28.48 5:595.69 9/19/2018 5fi24.11 28.17 5.o9a.oo I 10/8/2018 .se24J'7 27.45 5596.:n . lE2011 22584.:Z,(i) I N20n 4 2018 Average 55,96.1'8 - ' Recovery • Cell 2 S1imes Drain Monthly Volumes of Fluids Pumped 1'etal Pmnpiet by Month Date (gal) January-19 94713 February-19* 80084 March-19* 97921 April-19 92178 May-19* 84677 June-19 87619 July-19 90063 August-19 90647 September-19* 79259 October-20 92165 November-19* 80057 December-19 100221 28ff'Te.faf ~4 *Pursuant to Part I.D.3(b) of the January 19, 2018 GWDP, slimes darin recovery tests were performed quarterly. The recovery tests (and GWDP) require the pump to be turned off for 90 hours. No pumping of slimes drain fluid occurs during the recovery test. Less volumes are reported during the months in which the recovery tests are conducted. Cell 2 Slimes Drain Recovery Head and SORE Values for 2019 2019 Test Elevation of Reported Level SDRE Values Closing Date Measurement (feet) (Reported as fmsl) Point (fmsl) 3/4/2019 i~24.17' 28.30 55~.S.'87, 5/13/2019 ,$624.1 7 28.57 $595.&0 9/16/2019 5<£24.n 28.40 §S95 .. n 11/25/2019 se:124.11 28.00 559.~.1'7 .. I.E2019 2238l.4t - N2019 4 2019 Average 55,g5_g'5 I Recovery -- Cell 2 Slimes Drain Monthly Volumes of Fluids Pumped Total .Pumped by .Month ".Date fgpl;) January-20 85791 February-20* 72593 March-20 91513 April-20 81454 May-20 85725 June-20* 75640 July-20 84720 August-20 84236 September-20* 72815 October-20 87111 November-20* 73744 December-20 87767 .. ~ .. t8;3l&9 *Pursuant to Part I.D.3(b) of the January 19, 2018 GWDP, slimes darin recovery tests were performed quarterly. The recovery tests (and GWDP) require the pump to be turned off for 90 hours. No pumping of slimes drain fluid occurs during the recovery test. Less volumes are reported during the months in which the recovery tests are conducted. Cell 2 Slimes Drain Recovery Head and SORE Values for 2020 2020 Test Elevation of Reported Level SORE Values Closing Date Measurement (feet) (Reported as fmsl) Point (fmsl) 2/25/2020 56M.17 I 28.53 II 5.595.M! 6/8/2020 II 562~.17 l 28.61 II 5595.56 9/8/2020 562~.17 28.38 II $595.79 11/23/2020 II 5624.17 28.35 5595.8'2 ' II IE2020 22382.81 N2020 4 II 2020 Average SS9~.70 Ii II Recovery II Elevation II Cell 2 Slimes Drain Monthly Volumes of Fluids Pumped TotarPumped by Month Date (gal) January-21 82019 February-21 * 62164 March-21 89359 April-21 80045 May-21 80704 June-21 * 72298 July-21 76870 August-21 79833 September-21 * 71715 October-21 82796 November-21 75809 December-21 * 79601 2021 Total 933!l.13 *Pursuant to Part I.D.3(b) of the January 19, 2018 GWDP, slimes drain recovery tests were performed quarterly. The recovery tests (and GWDP) require the pump to be turned off for 90 hours. No pumping of slimes drain fluid occurs during the recovery test. Less volumes are reported during the months in which the recovery tests are conducted. Cell 2 Slimes Drain Recovery Head and SDRE Values for 2021 2021 Test Elevation of Reported Level SDRE Values Closing Date Measurement (feet) (Reported as fmsl) Point (fmsl) 3/2/2021 5,(9~.17 28.88 $595.29 6/8/2021 $624.17 29.10 5595.07 9/20/2021 $,624.~7 29.54 5594.t53 12/7/2021 5624.17 28.78 5595.39 I.E2021 223·8@.~'8 ' N2021 4 2021 Average 5595.J.C!) Recovery Elevation Appendix K White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) Date 2/15/2022 Revision 7.7 Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 02-15-2022 Revision 7.7 Pagel of61 Quality Assurance Plan (QAP) WHITE MESA URANIUM MILL GROUNDWATER MONITORING QUALITY ASSURANCE PLAN (QAP) State of Utah Groundwater Discharge permit No. UGW370004 Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, CO 80228 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) TABLE OF CONTENTS Date: 02-15-2022 Revision 7.7 Page 2 of61 1.0 INTRODUCTION 6 2.0 ORGANIZATION AND RESPONSIBILITIES 6 2.1 Functional Groups 6 2..2 OveraU Responsibility For the QA/QC Program 6 2,3 »~ta aequestors/Users 6 2.4 Data Generaton 7 2.4.1 Sampling and QC Monitors 7 2.4.2 Analysis Monitor 8 2.4.3 Data Reviewers/Approvers 8 l.S Res.,onsibilities Of Analytical Laboratory 8 3.0 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT OF DATA 9 3, 1 Pffl:isi«m 9 3.2 Ateuracy 10 3.3 Represent.tiveness l O 3.4 Completeness 10 J,5 Coffll)arability t1 4.0 FIELD SAMPLING QUALITY ASSURANCE METHODOLOGY 11 4.1 Controlling Well Contamination 11 4.2 Controlling Depth to Groundwater Measurements 11 4.3 Water Quality QC Samples 11 4.3.1 voe Trip Blanks 11 4.3.2 Equipment Rinsa~e Samples 11 4:3,3 Field DupJi~tcs J 2 4.3.4 Definition of "Batch" 12 S.O CALffiRATION 12 5.1 Depth to Groundwater Measutemeqts 12 5.2 W~ter Qu•lity 12 Mill -Groundwater Discharge Perm.it Orol.lndwatcr Mc,nitoring Quality Assurance Plan (QAP) Date: 02-15-2022 R,evision 7.7 Page 3 of61 6.0 GROUNDWATER SAMPLING AND MEASUREMENT OF FIELD PARAMETERS 12 6.1 Groundwater Head Monitoring 12 6.1.1 Location and Frequency of Groundwater Head Monitoring 13 6.1.2 Groundwater Head Monitoring r"fequency l 3 6.2 Grouhd Water Compliance Monitoring 13 6.2.1 Location and Frequency of Groundwater CompJiance Monitoring 13 6.2.2 Quarterly and Semi~Annual Sampling Required Under Parts l.E. I .b) or I.E.1.c) of the GWDP 14 6.2.3 Quarterly or Monthly Sampling Required Under Paragraphs LG. I or I.G.2 of the GWDP 14 6.2.4 Sampling Equipment for Gr9undwater Compliance Monitoring 14 6.2.5 Decontamination Procedure 15 6.2.6 Pre-Purging/ Sampling Activities 15 6.2.7 Well Purging/Measurement bfFieJd Parameters 15 6.2.8 Samples to be taken and order of taking samples 15 7.0 SAMPLE DOCUMENTATION TRACKING AND RECORD KEEPING 16 7.1 Field Data Worksheets 16 7.2 Chain-Of-Custody and Analytical Request Record 17 7.3 Rerorcl Keeping 18 8.0 ANALYTICAL PROCEDURES AND QA/QC 18 8,1 Analytical Quality Control 18 8.1.2 Spikes, Blan.ks and Duplicates l 9 8.2 Analytical Laboratory Procedu~ 20 9.0 INTERNAL QUALITY CONTROL CHECKS 25 9.1 Field QC Ctu~ck Procedures 25 9. I, I Review of Compliance With the Procedures Contained in this QAP 25 9. J .2 Analyte Completeness Review 25 9.1.3 Blank Comparisons 25 9.1.4 Duplicate Sample Comparisons 26 .9.i Analytical Laboratory QA Reviews 27 9.3 QA Man11ger Review of Analytical Laboratory Results and Pr:ocedures 27 9.4 Analytical Dffta 28 10.0 CORRECTIVE ACTION 29 10.1 When Corrective Action is Required 29 10.:2 Procedure for Corredin Action 29 Mill-Groundwater Oischarge Permit Date: 02-15-2022 Revision 7.7 Groundwater Monit<,>ring Quality Assurance. Plan (QAP) Page 4 of 61 11.0 REPORTING ·30 12.0 SYSTEM AND PERFORMANCE AUDITS 31 12.1 QA M•Qqer to Pedorm System Audits a.-.d Performance Audits JI l2.1SystemAudiis 31 12.3 Performance Audits 32 12.4 Follow-Up A.ctions 32 12.S Audit Records 32 13.0 PREVENTIVE MAINTENANCE 32 14.0 QUALITY ASSURAN~ REPORTS TO MANAGEMENT 14.l Ongoing QA/QC Reporting 14.l Periodic Reporting to Management 15.0 AMENDMENT 16.0 REFERENCES 33 33 33 33 34 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) ATTACHMENTS Date: 02-15-2022 Revision 7.7 Page 5 of61 Attachment 1 Field and Data Forms Attachment 1-1 Quarterly Depth to Water Data Sheet Attachment 1-2 White Mesa Uranium Mill Field Data Work Sheet for Groundwater Attachment 1-3 Example Field Data Report Attachment 2 Field Procedures Attachment 2-1 Groundwater Head (Depth to Water) Measurement Procedures Attachment 2-2 Decontamination Procedures Attachment 2-3 Purging Procedures Attachment 2-4 Sample Collection Procedures Attachment 2-5 Field QC Samples APPENDICES Appendix A Chloroform Investigation Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Appendix B Nitrate Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Mill -Groundwater Discharge Permil GruundwaLer Mortitoting Quality Assurance Plan (QAP) 1.0 INTRODUCTION Date: 02-15-2022 Revision 7.7 Page 6 of 61 This Groundwater Monitoring Quality Assurance Plan (the "QAP") details and describes all sampling equipment. field methods, laboratory methods. qualifications of environmental anaJytical laboratories, data validation, and sampling and other corrective actions necessary to comply with UAC R317-6-6,3(1) and (L) at the White Mesa Uranium Mill (the "Mill''), as required by the State of Utah Groundwater Discharge Permit No. UGW370004 (the "GWDP") for the Mill. This Procedure incorporates the applicable provisions of the United States Environmental Protection Agency ("EPA'') RCRA Groundwater Monitoring Technical Enforcement Guidance Document (OSWER-9950.l, September, 1986), as updated byEPA's RCRA Ground-Water Monitoring: Draft Technical Guidance (November 1992). Activities in an integrated program to generate quality data can be classified as management (i.e., quality assurance or "QA'') and as functional (i.e .• quality control or "QC''). The objective of this QAP is to ensure that monitoring data are generated at the Mill that meet the requirements for precision, accuracy, completeness, representativeness and comparability required for management purposes and to comply with the reporting requirements established by applicable permits and regulations. 2.0 ORGANIZATION AND RESPONSIBILmES 2.1 Func'tional Groups This QAP specifies roles for a QA Manager as weH as representatives of three different functional groups: the data users; the data generators, and the data reviewers/approvers. The roles and responsibilities of these representatives are described below. 2,2 Overall Responsibility For the QA/QC Program The overall responsibility for ensuring that the QNQC measures are properly employed is the responsibility of the QA Manager. The QA Manager is typically not directly involved in the. data generation (i.e., sampling or analysis) activities. The QA Manager is designated by Energy Fuels Resources (USA) Inc. ("EFRI") corporate management. 2.3 Data Requestors/Users The generation of data that meets the objectives· of this QAP is necessary for management to make informed decisions relating to the operation of the Mill facility, and to comply with the reporting requirements set out in the GWDP and other permits a'nd applicab1e regulations. Accordingly, the data requesters/users (the "Data Users") are therefore EFRI;s corporate m.anagement and regulatory authorities through the implementation of s1,1ch pe1miti,; and regulations. The data quaJity objectives (0 DQ0s;,) required for any groundwater sampling eventf such as acceptable minimum detection limits, are specified in this QAP. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 2.4 Data Generators Date: 02-15-2022 Revision 7.7 Page 7 of 61 The individuals who carry out the sampling and analysis activities at the request of the Data Users are the data generators. For Mill activities, this involves sample collection, record keeping and QA/QC activities conducted by one or more sampling and quality control/data monitors (each a "Sampling and QC Monitor"). The Sampling and QC Monitors are qualified Mill personnel as designated by the QA Manager. The Sampling and QC Monitors perform all field sampling activities, collect all field QC samples and perform all data recording and chain of custody activities in accordance with this QAP. Data generation at the contract analytical laboratory (the "Analytical Laboratory") utilized by the Mill to analyze the environmental samples is performed by or under an employee or agent (the "Analysis Monitor") of the Analytical Laboratory, in accordance with specific requirements of the Analytical Laboratory's own QA/QC program. The responsibilities of the data generators are as follows: 2.4.1 Sampling and OC Monitors The Sampling and QC Monitors are responsible for field activities. These include: a) Ensuring that samples are collected, preserved, and transported as specified in this QAP; b) Checking that all sample documentation (labels, field data worksheets, chain-of- custody records,) is correct and transmitting that information, along with the samples, to the Analytical Laboratory in accordance with this QAP; c) Maintaining records of all samples, tracking those samples through subsequent processing and analysis, and, ultimately, where applicable, appropriately disposing of those samples at the conclusion of the program; d) Preparing quality control samples for field sample collection during the sampling event; e) Preparing QC and sample data for review by the QA Manager; and f) Preparing QC and sample data for reporting and entry into a computerized database, where appropriate. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 2.4.2 Analysis Monitor Date: 02-15-2022 Revision 7.7 Page 8 of61 The Analysis Monitor is responsible for QA/QC activities at the Analytical Laboratory. These include: a) Training and qualifying personnel in specified Analytical Laboratory QC and analytical procedures, prior to receiving samples; b) Receiving samples from the field and verifying that incoming samples correspond to the packing list or chain-of-custody sheet; and c) Verifying that Analytical Laboratory QC and analytical procedures are being followed as specified in this QAP, by the Analytical Laboratory's QA/QC program, and in accordance with the requirements for maintaining National Environmental Laboratory Accreditation Program ("NELAP") certification. 2.4.3 Data Reviewers/Approvers The QA Manager has broad authority to approve or disapprove project plans, specific analyses and final reports. In general, the QA Manager is responsible for reviewing and advising on all aspects of QA/QC, including: a) Ensuring that the data produced by the data generators meet the specifications set out in this QAP; b) Making on-site evaluations and submitting audit samples to assist in reviewing QA/QC procedures; c) Determining (with the Sampling and QC Monitor and Analysis Monitor) appropriate sampling equipment and sample containers, in accordance with this QAP, to minimize contamination; and d) Supervising all QA/QC measures to assure proper adherence to this QAP and determining corrective measures to be taken when deviations from this QAP occur. The QA Manager may delegate certain of these responsibilities to one or more Sampling and QC Monitors or to other qualified Mill personnel. 2.5 Responsibilities Of Analytical Laboratory Unless otherwise specified by EFRI corporate management, all environmental analysis of groundwater sampling required by the GWDP or by other applicable permits, will be performed by a contract Analytical Laboratory. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 9 of61 The Analytical Laboratory is responsible for providing sample analyses for groundwater monitoring and for reviewing all analytical data to assure that data are valid and of sufficient quality. The Analytical Laboratory is also responsible for data validation in accordance with the requirements for maintaining National Environmental Laboratory Accreditation Program ("NELAP") ce1tification, which is a national accreditation program developed by the NELAC institute ("TNI"). In addition, to the extent not otherwise required to maintain NELAP certification, the Analytical Laboratory must adhere to U.S. EPA Guideline SW-846 and, to the extent consistent with NELAP and EPA practices, the applicable portions of NRC Regulatory Guide 4.14. The Analytical Laboratory will be chosen by EFRI and must satisfy the following criteria: (1) experience in analyzing environmental samples with detail for precision and accuracy, (2) experience with similar matrix analyses, (3) operation of a stringent internal quality assurance program meeting NELAP certification requirements and that satisfies the criteria set out in Section 8 below, (4) ability to satisfy radionuclide requirements as stipulated in the applicable portions of NRC Regulatory Guide 4.14, and (5) certified by the State of Utah for and capable of performing the analytical methods set out in Table 1. The analytical procedures used by the Analytical Laboratory will be in accordance with Utah Administrative Code R317-6-6.3L. 3.0 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT OF DATA The objective of this QAP is to ensure that monitoring data are generated at the Mill that meet the requirements for precision, accuracy, representativeness, completeness, and comparability required for management purposes and to comply with the reporting requirements established by applicable permits and regulations (the Field and Analytical QC samples described in Sections 4.3 and 8.1 below are designed to ensure that these criteria are satisfied). Data subject to QNQC measures are deemed more reliable than data without any QA/QC measures. 3.1 Precision Precision is defined as the measure of variability that exists between individual sample measurements of the same property under identical conditions. Precision is measured through the analysis of samples containing identical concentrations of the parameters of concern. For duplicate measurements, precision is expressed as the relative percent difference ("RPD") of a data pair and will be calculated by the following equation: RPD = [(A-B)/{(A+B) /2}] x 100 Where A ( original) and B (duplicate) are the reported concentration for field duplicate samples analyses (or, in the case of analyses performed by the Analytical Laboratory, the Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 10 of61 percent recoveries for matrix spike and matrix spike duplicate samples) (EPA SW -846, Chapter 1, Section 5.0, page 27 -28). 3.2 Accuracy Accuracy is defined as a measure of bias in a system or as the degree of agreement between a measured value and a known value. The accuracy of laboratory analyses is evaluated based on analyzing standards of known concentration both before and during analysis. Accuracy will be evaluated by the following equation: % Recovery= (IA-BI /C) x 100 Where: A = the concentration of analyte in a sample B = the concentration of analyte in an unspiked sample C = the concentration of spike added 3.3 Representativeness Representativeness is defined as the degree to which a set of data accurately represents the characteristics of a population, parameter, conditions at a sampling point, or an environmental condition. Representativeness is controlled by performing all sampling in compliance with this QAP. 3.4 Completeness Completeness refers to the amount of valid data obtained from a measurement system in reference to the amount that could be obtained under ideal conditions. Laboratory completeness is a measure of the number of samples submitted for analysis compared to the number of analyses found acceptable after review of the analytical data. Completeness will be calculated by the following equation: Completeness= (Number of valid data points/total number of measurements) x 100 Where the number of valid data points is the total number of valid analytical measurements based on the precision, accuracy, and holding time evaluation. Completeness is determined at the conclusion of the data validation. The Director ("Director") of the Utah Division of Waste Management and Radiation Control) ("DWMRC") approval will be required for any completeness less than 100 percent. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 3.5 Comparability Date: 02-15-2022 Revision 7.7 Page 11 of 61 Comparability refers to the confidence with which one set of data can be compared to another measuring the same property. Data are comparable if sampling conditions, collection techniques, measurement procedures, methods, and reporting units are consistent for all samples within a sample set. 4.0 FIELD SAMPLING QUALITY ASSURANCE METHODOLOGY 4.1 Controlling Well Contamination Well contamination from external surface factors, is controlled by installation of a cap over the surface casing and cementing the surface section of the drill hole. Wells have surface covers of mild steel with a lockable cap cover. Radiation Safety staff has access to the keys locking the wells. 4.2 Controlling Depth to Groundwater Measurements Monitoring of depth to groundwater is controlled by comparing historical field data to actual measurement depth. This serves as a check of the field measurements. 4.3 Water Quality QC Samples Quality assurance for groundwater monitoring consists of the following QC samples: 4.3.l VOC Trip Blanks Trip blanks will be used to assess contamination introduced into the sample containers by volatile organic compounds ("VOCs") through diffusion during sample transport and storage. At a minimum (at least) one trip blank will be in each shipping container containing samples to be analyzed for VOCs. Trip blanks will be prepared by the Analytical Laboratory, transported to the sampling site, and then returned to the Analytical Laboratory for analysis along with the samples collected during the sampling event. The trip blank will be unopened throughout the transportation and storage processes and will accompany the technician while sampling in the field. 4.3.2 Equipment Rinsate Samples Where portable (non-dedicated) sampling equipment is used, a rinsate sample will be collected at a frequency of one rinsate sample per 20 field samples collected from non- pumping wells. Pumping wells have dedicated pumps and will not be included in the total sample count for the purposes of calculating the number of required rinsate samples. Rinsate blanks will be collected after decontamination and prior to subsequent use. Rinsate blank samples for a non-dedicated pump are prepared by pumping de-ionized water into the sample containers. Rinsate blank samples for a non-disposable or non-dedicated bailer are prepared Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 12 of61 by pouring de-ionized water over and through the bailer and into the sample containers. Equipment rinsate blanks will be analyzed only for the contaminants required during the monitoring event in which they are collected. Equipment rinsate blank sampling procedures are described in Attachments 2-2 and 2-5. 4.3.3 Field Duplicates Field duplicate samples are collected at a frequency of one duplicate per 20 field samples. Field duplicates will be submitted to the Analytical Laboratory and analyzed for the same constituents as the parent sample. Field duplicate sampling procedures are described in Attachment 2-5. 4.3.4 Definition of "Batch" For the purposes of this QAP, a Batch is defined as 20 or fewer samples. 5.0 CALIBRATION A fundamental requirement for collection of valid data is the proper calibration of all sample collection and analytical instruments. Sampling equipment shall be calibrated in accordance with manufacturers' recommendations, and Analytical Laboratory equipment shall be calibrated in accordance with Analytical Laboratory procedures. 5.1 Depth to Groundwater Measurements Equipment used in depth to groundwater measurements will be checked prior to use as noted in Attachment 2 to ensure that the Water Sounding Device is functional. 5.2 Water Quality The Field Parameter Meter will be calibrated prior to each sampling event and at the beginning of each day of the sampling event according to manufacturer's specifications (for example, by using two known pH solutions and one specific conductance standard.) Per the manufacturer, temperature cannot be calibrated but will be periodically checked comparatively by using a thermometer. Conductivity and pH calibration results will be recorded as described in Section 7 .1. 6.0 GROUNDWATER SAMPLING AND MEASUREMENT OF FIELD PARAMETERS 6.1 Groundwater Head Monitoring Groundwater head measurements ("depth to water") will be completed as described in Attachment 2 using the equipment specified in Attachment 2. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 6.1.1 Location ond I~requency of Groundwat~r Head Monitoring Date: 02~15-2022 Revision 7.7 Page 13 of61 Depth to groundwater shall be measured quarterly in the following wells and piezometers: a) All Point of Compliance wells listed in the GWDP; b) Monitoring wen MW-34~ c) All piezometers (P-1, P-2, P-3A, P-4, P-5 and the Dry Ridge piezometers); d) All contaminant investigation wells required by the Director as part of a contaminant investigation or groundwater corrective action (chloroform and nitrate wells). 6.1.2 Groundwater Bead Monitoring Frequency Depth to groundwater is measured and recorded in any well that is being sampled for groundwater quality prior to sampling. In addition, a depth to groundwater measurement campaign will be completed each quarter. The data from the quarterly campaign will be used for modeling purposes and will be completed within a 5--day period. The data from the quarterly campaign will be recorded on a data sheet. An example of a Quarterly Depth to Water data sheet is included Attachment 1. Data from the quarterly depth to water campaign will be recorded by hand on hardcopy forms in the field, but may be entered into an eJectronic data management system (spreadsheet and/or database). The data from the quarterly depth to water measurements will be included in the quarterly reports. In addition, weekly and monthly depth to groundwater measurements are takeo in the chloroform pumping wells MW-4, MW-26, TW4-l, TW4-'.i, TW4-l l, TW4-l9, TW4-20, TW4-4, TW4-21, TW4-37, TW4-39 TW4-40 (starting in May 2019) and TW4-41, and the nitrate pumping wells TW4- 22, TW4-24, TW4-25, and TWN-t The depth to groundwater measured immediately prior to purging/sampling will be recorded for each w,ell as described in Section 7. 1. 6.2 Ground Water Compliance Monitoring 6.2,1 Location and Frequency of Groundwater Compliance Monitoring Groundwater quality shall be measured in the wells specified in the GWDP at the frequencies specified in the GWDP. In addition, the Chloroform Investigation and Nitrate Corrective Action wells will be sampled quarterly as described in Appendix A and Appendix B of this QAP. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 14 of61 Accelerated quarterly or monthly sampling may be required for certain parameters in certain wells based on the requirements specified in the GWDP. Sampling personnel should coordinate with the QA Manager prior to conducting any monitoring well sampling to determine if any parameters in any wells are subject to accelerated monitoring. 6.2.2 Quarterly and Semi-Annual Sampling Required In Accordance With the GWDP All quarterly and semi-annual samples collected in accordance with the GWDP shall be analyzed for the following parameters: a) Field parameters -depth to groundwater, pH, temperature, specific conductance, redox potential (Eh) turbidity and dissolved oxygen ("DO"); and b) Laboratory Parameters: (i) All parameters specified in Table 2 of the GWDP; and (ii) General inorganics -chloride, sulfate, carbonate, bicarbonate, sodium potassium, magnesium, calcium, and total anions and cations. 6.2.3 Accelerated Quarterly or Monthly Sampling Required .By the GWDP Any quarterly or monthly accelerated sampling required by the GWDP shall be analyzed for the specific parameters as required by previous sampling results as determined by the QA Manager. 6.2.4 Sampling Equipment for Groundwater Compliance Monitoring All equipment used for purging and sampling of groundwater which enters the well or may otherwise contact sampled groundwater, shall be made of inert materials. Purging and sampling equipment is described in Attachment 2-3 of this QAP. Field parameters are measured by using a flow cell system that enables the measurements to be taken on a real-time basis without exposing the water stream to the atmosphere; Mill -Groundwater Discharge Permit Gmundwater Monitoring Quality Assurance Plan (QAP) 6.2.5 Decontamination Procedure Date: 02-15-2022 Revii,ion 7.7 Page 15 of61 Portable (non-dedicated) sampling equipment will be decontaminated prior to each sampling event, at the beginning of each day during the sampling event, and between each sampling location (well). Non-dedicated sampling equipment will be decontaminated using Lhe procedure described in Attachment 2-2. 6.2.6 Pre-Purging/ Sampling Activities Pre-purging and sampling activities are described in Attachment 2-3. The purging and sampling techniques used at each well will be a function of the we)]' s historic recovery rates, the equipment used for purging. and the analytical suite Lo be completed. 6.2.7 Well Pureinl!{Measurement of Field Parameters The purging techniques described in Attachment 2-3 wiU be used for all groundwater sampling conducted at the Mill unless otherwise stated in the program.-specific QAPs for the chloroform and nitrate investigations. The program~specific QAPs for the chloroform and nitrate investigations are included as Appendix A and Appendix B respectively. Purging wells prior to sampling removes the stagnant water column present in the well casing and assures that representative samples of the formation water are collected. Purging will be completed as described in Attachment 2-3. There are three purging strategies that will be used to remove stagnant water from the well casing during groundwater sampling at the Mill. The three strategies are as follows: l. Purging three well casing volumes with a single measurement of field parameters 2. Purging two casing volumes with stable field parameters (within 10% RPD) 3. Purging a well to dryness and stability of a limited list of field parameters after recovery 6.2:.8 Samples to be taken and order of taking samples For each quarterly or semi-annual sampling event, samp]es will be collected for the anaJyte specified in Table 2 of the GWDP. The following is a list of the sample containers that will be collected to provide sample aliquots to the Analytical Laboratory for the completion of the analyses specified in Table 2 of the GWDP. The Analytical Laboratory will provide the sampling containers and may request that certain analytes be combined into a single container due to like sampling requirements (filtering) and/or like preservation. The container requirements will be detennined by the Analytical Laboratory and specified with the bottles supplied to the Field Personnel. Bottle requirements may change if the Analytical Laboratory is changed or if advances in analytical techniques allow for reduced samples volumes. The following list is a general guideline. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) a) VOCs, 3 sample containers, 40 ml each; Date: 02-15-2022 Revision 7.7 Page 16 of61 b) Nutrients (ammonia, nitrate/nitrite as N), 1 sample container, 250 ml; c) All other non-radiologies (anions, general inorganics, TDS, total cations and total anions), 2 sample containers, 500 and 250 ml,; d) Gross alpha, 1 sample container, 500 ml, filtered; and e) Metals, 1 sample container, 250 ml, filtered. The sample collection containers and sample volumes for chloroform and nitrate program sampling are specified in Appendices A and B to this document. Accelerated samples will be analyzed for a limited list of analytes as determined by previous sampling results. Only the containers for the specific list of analytes will be collected for accelerated monitoring samples. 7.0 SAMPLE DOCUMENTATION TRACKING AND RECORD KEEPING 7 .1 Field Data Collection Documentation of observations and data from sampling provide important information about the sampling process and provide a permanent record for sampling activities. All observations and field sampling data will be recorded. Field data collection will be completed using either an electronic device (such as a tablet) or a hardcopy form. Hardcopy forms will be completed in waterproof ink. If field data collection is completed using an electronic device, a data report for each well sampled will be printed after the completion of the sampling event and signed by one member of the sampling crew. The signed sheets will be maintained on file and the Mill and will be included in the quarterly reports. The electronic data collection will be accomplished using a standardized collection module. An example of a hardcopy field collection form as well as an example data report are included as Attachment lA and lB respectively. The hardcopy data sheets and data reports included herein are examples and may be changed to accommodate additional data collection. If a change is made to a data sheet to accommodate additional information, a copy will be provided to the Director. Changes to hardcopy field forms and data reports will not eliminate any data collection activity without written approval of the Director. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 02-15-2022 Revision 7.7 Quality Assurance Plan (QAP) Page 17 of61 Regardless of the field data collection method, the following information will be collected: • Name of the site/facility • description of sampling event • location of sample ( well name) • sampler's name(s) and/or initials(s) • date(s) and time(s) of well purging and sample collection • type of well purging equipment used (pump or bailer) • previous well sampled during the sampling event • well depth • depth to groundwater before purging and sampling • field measurements (pH, specific conductance, water temperature, redox potential, turbidity, DO) • calculated well casing volume • volume of water purged before sampling • volume of water purged when field parameters are measured • type of well pump • description of samples taken • sample handling, including filtration and preservation • volume of water collected for analysis • types of sample containers and preservatives • weather conditions and external air temperature • name of certified Analytical Laboratory. Field data collection will also include detailed notes describing any other significant factors noted during the sampling event as necessary, including, as applicable: condition of the well cap and lock; water appearance, color, odor, clarity; presence of debris or solids; any variances from this procedure; and any other relevant features or conditions. 7.2 Chain-Of-Custody and Analytical Request Record A Chain-of-Custody (the "COC Form") will accompany the samples being shipped to the Analytical Laboratory. Standard Chain-of-Custody protocol is initiated for each sample set. A COC Form is to be completed for each set of samples collected and is to include the following: • sampler's name • company name • date and time of collection • sample matrix (e.g., water) • sample location • number of sample containers in the shipping container • analyses requested Mill · Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) • signatures of persons involved in the chain of p<,sscssion Date: 02-15.2022 Revision 7.7 Page 18 of61 • internal temperatures of the shipping container when opened at the laboratory • remarks section to identify potential hazards or to relay other information to the Analytical Laboratory. · Chain·of-Custody reports will be placed inside a re-sealable bag and taped to the inside lid. Custody seals will be placed on the outside of each cooler. The person shipping the samples to the Analytical Laboratol'y will sign the COC Form, document shipment method, and send the original COC Form with the samples. Upon receipt of the samples, the person receiving the samples will sign the COC Form and return an electronic copy to the Mill and the QA Manager. Copies of the COC Forms and other relevant documentation will be retained at the Mill. 7.3 Record Keeping The data coJlection records arc retained in an electronic database and hardcopies are retained at tl)e Mill. Data from the Analytical Laboratory, showing the laboratory analytical results for the water samples, are maintained at the Mill. EFRI wiU ensure that the Analytical Laboratory or Laboratories used, have certifications for each parameter and method required by Section 8.2! Table I of the QAP. The QA Manager will check th.e Utah certifications at least annually. Once all the data for the quarter (all wells sampled during the quarter) is completed, key data from the field and from the data packages are managed using electronic data management software. The data management software will be managed and administered by the QA Manager or designec. 8.0 ANALYTICAL PROCEDURES AND QA/QC Analytical Laboratory QA provides a means for establishing consistency in the performance of analytical procedures and assuring adherence to analytical methods utilized. Analytical Laboratory QC programs include traceability of measurements to independent reference materials and internal controls. 8.1 Analytical Quality Control Analytical QA/QC will be governed by the QA/QC program of the Analytical Laboratory. In choosing and retaining the Analytical Laboratory, EFRI shall ensure that the Analytical Laboratory is certified by the State of Utah and by NELAP, is capable of performing the Mill -Oroundwatcr Discharge Permit Groundwater Monitoring Quality Asimrancc Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 19 of61 analytical procedures specified in Section 8.2, and that the QA/QC program of the Analytical Laboratory includes the spikes, blanks and duplicates described in Section 8.1.2. 8.1.2 Spikes, Blanks and Duplicates Analytical Laboratory QC samples will assess the accuracy and precision of the analyses. Tb~ following describes the type of QC samples that will be used by the Analytical Laboratory to assess the quality of the data. The following procedures shall be performed at least once with each analytical Batch of samples: a) Matrix Spike/Matrix Spike Duplicate A spiked field sample analyzed in duplicate may be analyzed with every analytical batch (depending on the analytical method requirements and or method limitations). Analytes stipulated by the analytical method, by applicable regulations, or by other specific requirements may be spiked into the samples. Selection of the sample to be spiked depends on the information required and the variety of conditions within a typical matrix. The matrix spike sample serves as a check evaluating the effect of the sample matrix. on the accuracy of analysis. The matrix spike duplicate serves as a check of the analytical precision. b) Method Blanks Each analytical batch shall be accompanied by a method blank. The method blank shall be carried through the entire analytical procedure. Contamination detected in analysis of method blanks wiJl be used to evaluate any Analytical Laboratory contamination of environmental samples which may have occurred. c) Surrogate Compounds Every blank, standard, and environmental sample (including matrix spike/matrix duplicate samples) for analysis of VOCs (or other organics only) shall be spiked with surrogate compounds prior to purging or extraction. Surrogates are organic compounds which are similar to analytes of interest in chemical composition, extraction, and chromatography, but which are not normaJly found in environmental samples. Surrogates shall be spiked into samples according to the appropriate organic analytical methods. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) d) Check Sample Date: 02-15-2022 Revision 7.7 Page 20 of61 Each analytical batch shall contain a number of check samples. For each method, the Analytical Laboratory will normally analyze the following check samples or their equivalents: a method blank, a laboratory control spike, a matrix spike, and a matrix spike duplicate, or the equivalent, with relative percent difference reported. 8.2 Analytical Laboratory Procedures The analytical procedures to be used by the Analytical Laboratory will be as specified in Table 1, or as otherwise authorized by the Director. With respect to Chloroform Investigation and Nitrate Corrective Action sampling, the analytical procedures for parameters monitored under those programs are specified in Appendix A and B respectively. Mill -Groundwater Discharge Permit Groundwater Monitoring Qu~lity Assurance Plan (QAP) Contaminant Analytical Methods to be Used Nutrients Ammonia (as N) A4500- NH3 Gor E350.l Nitrate & Nitrite E353. l or (as N) E353.2 or A4500- N03F Heavy Metals Arsenic B200.7 or E200.8 Beryllium E200.7 or E200.8 Cadmium E200.7 or E200.8 Chromium E200.7 or E200.8 Cobalt B200.7 or E200,8 Copper E200.7 or E200.8 Iron E200.7 or E200.8 Lead E200.7 or E200.8 Manganese E200.7 or E200.S Mercury E 245.l or E200.7 or E200.8 Molybdenum E200.7 or E200.8 Nickel E200.7 or E200.8 Selenium E200.7 or E200.8 Silver E200.7 or E200.8 Table 1 Reporting Maximum Limit1 Holding Times 0.05 mg/L 28 days O;I mg/L 28 days 5 µg/L 6 months 0.50 µg/L 6 months 0.50 µg/L 6 months 25 i-tg/L 6 months 10 µg/L 6 months 10 µg/L 6 months 30 µg/L 6 months 1.0 µg/L 6 months 10 µg/L 6 months 0,50 µg/L 28 days 10 µg/L 6 months 20 µg/L 6 months 5 µg/L 6 months lO µg/L 6 months Date: 02-15-2022 Revision 7.7 Page 21 of61 Sample Sample Preservation Temperature Requirements Requirements H2S04 to S 6°C pH<2 H2S04 to S6°C pH<2 HN03topH<2 None HN03 to pH<2 None HN03topH<2 None HN03topH<2 None HN03to pH<2 None HN03to pH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Contaminant Analytical Methods to be Used Thallium E200.7 or E200.8 Tin E200.7 or E200.8 Uranium E200.7 or E200.8 Vanadium E200.7 or E200.8 Zinc E200.7 or E200.8 Radiolo~ics Gross Alpha E 900.0 or E900.1 or 903.0 Volatile Organic Compounds Acetone SW8260B, SW8260C or SW8260D Benzene SW8260B, SW8260C or SW8260D 2-Butanone SW8260B, (MEK) SW8260C or SW8260D Carbon SW8260B, Tetrachloride SW8260C or SW8260D Chloroform SW8260B, SW8260C or SW8260D Chloromethane SW8260B, SW8260C Reporting Maximum Limit1 Holding Times 0.50 µg/L 6 months 100 µg/L 6 months 0.30 µg/L 6 months 15 µg/L 6 months 10 µg/L 6 months 1.0 pCi/L 6 months 20 µg/L 14 days 1.0 µg/L 14 days 20 µg/L 14 days 1.0 µg/L 14 days 1.0 µg/L 14 days 1.0 µg/L 14 days Date: 02-15-2022 Revision 7.7 Page 22 of61 Sample Sample Preservation Temperature Requirements Requirements HN03topH<2 None HN03topH<2 None HN03to pH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None HCJ topH<2 S 6°C HCI to pH<2 S 6°C HCl topH<2 S 6°C HCI topH<2 S6°C HCl topH<2 S6°C HCl topH<2 S6°C Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance P]an (QAP) Contaminant Analytical Methods to be Used or SW8260D Dichloromethane SW8260B, (Methylene SW8260C Chloride) or SW8260D Naphthalene SW8260B, SW8260C or SW8260D Tetrahydrofuran SW8260B, SW8260C or SW8260D Toluene SW8260B, SW8260C or SW8260D Xylenes (total) SW8260B, SW8260C or SW8260D Others Field pH (S.U.) A4500-H B Fluoride A4500-FC orE300.0 TDS A2540C General lnoru;anics Chloride A4500-Cl B or A4500-Cl E orE300.0 Sulfate A4500- S04 Eor E300.0 Carbonate as A2320B Reporting Maximum Limit1 Holding Times 1.0 µg/L 14 days 1.0 µg/L 14 days 1.0 µg/L 14 days 1.0 µg/L 14 days 1.0 µg/L 14 days 0.01 s.u. Immediate 0.1 mg/L 28 days lOmwL 7 days 1 mg/L 28 days 1 mg/L 28 days 1 mg/L 14 days Date: 02-15-2022 Revision 7.7 Page 23 of61 Sample Sample Preservation Temperature Requirements Requirements HCI to pH<2 S6°C HCl to pH<2 S6°C HCI topH<2 :5 6°C HCI topH<2 S6°C HCl to pH<2 :5 6°C None None None None None S6°C None None None S6°C None S6°C Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Contaminant Analytical Methods to be Used C03 Bicarbonate as A2320B HC03 Sodium E200.7 Potassium E200.7 Magnesium E200.7 Calcium E200.7 Reporting Limit1 1 mg/L 0.5 mg/L 0.5 mg/L 0.5 mg/L 0.5 mg/L Maximum Holding Times 14 days 6 months 6 months 6 months 6 months Date: 02-15-2022 Revision 7.7 Page 24 of61 Sample Sample Preservation Temperature Requirements Requirements None ~6°C HN03topH<2 None HN03topH<2 None HN03topH<2 None HN03topH<2 None 1. The Analytical Laboratory will be required to meet the reporting limits ("RLs") in the foregoing Table, unless the RL must be increased due to sample matrix interference (i.e., due to dilution gain), in which case the increased RL will be used, or unless otherwise approved by the Director. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 9.0 INTERNAL QUALITY CONTROL CHECKS Date: 02-15-2022 Revision 7.7 Page 25 of 61 Internal quality control checks are inherent in this QAP. The QA Manager will monitor the performance of the Sample and QC Monitors, and, to the extent practicable, the Analysis Monitor to ensure that they are following this QAP. In addition, either the QA Manager or a Sampling and QC Monitor will review and validate the analytical data generated by the Analytical Laboratory to ensure that it meets the DQOs established by this QAP. Finally, periodic system and performance audits will be performed, as detailed in Section 12 below. 9.1 Field QC Check Procedures The QA Manager will perform the following QNQC analysis of field procedures: 9.1.1 Review of Compliance With the Procedures Contained in this OAP Observation of technician performance is monitored by the QA Manager on a periodic basis to ensure compliance with this QAP. 9.1.2 Analyte Completeness Review The QA Manager will review all Analytical Results to confirm that the analytical results are complete (i.e., there is an analytical result for each required constituent in each well). The QA Manager shall also identify and report all instances of non-compliance and non- conformance as required by the Permit. Director approval will be required for any completeness (prior to QNQC analysis) less than 100 percent. Non-conformance will be defined as a failure to provide field parameter results and analytical results for each parameter and for each well required in Sections 6.2.2 and 6.2.3, for the sampling event, without prior written Director approval. 9.1.3 Blank Comparisons Trip blanks, method blanks, and equipment rinsate samples will be compared with original sample results. Non-conformance conditions will exist when contaminant levels in the samples(s) are not an order of magnitude greater than the blank result. (TEGD, Field QNQC Program, page 119). Corrective actions for blank comparison non-conformance shall first determine if the non- conformance is a systematic issue which requires the procedures described in Section 10. If the non-conformance is limited in scope and nature, the QA Manager will: 1. Review the data and determine the overall effect to the data quality, 2. Notify the laboratory of the discrepancy (if it is a laboratory generated blank), and 3. Request the laboratory review all analytical results for transcription and calculation errors, and (for laboratory generated blanks) Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 26 of61 4. If the samples are still within holding time, the QA Manager may request the laboratory re-analyze the affected samples. If re-analysis is not possible, qualifiers may be applied to the samples associated with a non-conforming blank. Recommendations regarding the usability of the data may be included in the quarterly report. 9.1.4 Duplicate Sample Comparisons The following analyses will be performed on duplicate field samples: a) Relative Percent Difference. RPDs will be calculated in comparisons of duplicate and original field sample results. Non-conformance will exist when the RPD ~20%, unless the measured concentrations are less than 5 times the required detection limit (Standard Methods, 1998) (EPA Contract Laboratory Program National Functional Guidelines for Inorganic Data Review, February 1994, 9240.1-05-01, p. 25). b) Radiologies Counting Error Term All gross alpha analyses shall be reported with an error term. All gross alpha analysis reported with an activity equal to or greater than the GWCL, shall have a counting variance that is equal to or less that 20% of the reported activity concentration. An error term may be greater than 20% of the reported activity concentration when the sum of the activity concentration and error term is less than or equal to the GWCL. c) Rad.iologics, Duplicate Samples Comparability of results between the original and duplicate radiologic samples will be evaluated by determining compliance with the following formula: Where: A = the first duplicate measurement B = the second duplicate measurement Sa 2 = the uncertainty of the first measurement squared Sb 2 = the uncertainty of the second measurement squared Non-conformance exists when the foregoing equation is > 2. (EPA Manual for the Certification of Laboratories Analyzing Drinking Water, Criteria and Procedures Quality Assurance, January 2005, EPA 815-R-05-004, p. VI-9). Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 27 of61 Corrective actions for duplicate deviations shall first determine if the deviation is indicative of a systematic issue which requires the procedures described in Section IO. If the non- conformance is limited in scope and nature, the QA Manager will: 1. Notify the laboratory, 2. Request the laboratory review all analytical results for transcription and calculation errors, and 3. If the samples are still within holding time, the QA Manager may request the laboratory re-analyze the affected samples. 9.2 Analytical Laboratory QA Reviews Full validation will include recalculation of raw data for a minimum of one or more analytes for ten percent of the samples analyzed. The remaining 90% of all data will undergo a QC review which will include validating holding times and QC samples. Overall data assessment will be a part of the validation process as well. The Analysis Monitor or data validation specialist will evaluate the quality of the data based on SW-846, the applicable portions of NRC guide 4.14 and on analytical methods used. The reviewer will check the following: (1) sample preparation information is correct and complete, (2) analysis information is correct and complete, (3) appropriate Analytical Laboratory procedures are followed, (4) analytical results are correct and complete, (5) QC samples are within established control limits, (6) blanks are within QC limits, (7) special sample preparation and analytical requirements have been met, and (8) documentation is complete. The Analytical Laboratory will prepare and retain full QC and analytical documentation. The Analytical Laboratory will report the data as a group of one batch or less, along with the QNQC data. The Analytical Laboratory will provide the following information: (1) cover sheet listing samples included in report with a narrative, (2) results of compounds identified and quantified, (3) reporting limits for all analytes, and (4) QNQC analytical results. 9.3 QA Manager Review of Analytical Laboratory Results and Procedures The QA Manager shall perform the following QA reviews relating to Analytical Laboratory procedures: Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) a) Reporting Limit (RL) Comparisons Date: 02-15-2022 Revision 7.7 Page 28 of61 The QA Manager shall confirm that all reporting limits used by the Analytical Laboratory are in conformance with the reporting limits set out on Table 1. Non-conformance shall be defined as: 1) a reporting limit that violates these provisions, unless the reporting limit must be increased due to sample matrix interference (i.e., due to dilution); or 2) a reporting limit that exceeds the respective GWQS listed in Table 2 of the GWDP unless the reported concentration is greater than the raised reporting limit. b) Laboratory Methods Review The QA Manager shall confirm that the analytical methods used by the Analytical Laboratory are those specified in Table 1, unless otherwise approved by the Director. Non-conformance shall be defined when the Analytical Laboratory uses analytical methods not listed in Table 1 and not otherwise approved by the Director. c) Holding Time Examination The QA Manager will review the analytical reports to verify that the holding time for each contaminant was not exceeded. Non-conformance shall be defined when the holding time is exceeded. d) Sample Temperature Examination The QA Manager shall review the analytical reports to verify that the samples were received by the Analytical Laboratory at a temperature no greater than the approved temperature listed in Table 1. Non-conformance shall be defined when the sample temperature is exceeded. 9.4 Analytical Data All QA/QC data and records required by the Analytical Laboratory's QA/QC program shall be retained by the Analytical Laboratory and shall be made available to EFRI as requested. Analytical data submitted by the Analytical Laboratory should contain the date/time the sample was collected, the date/time the sample was received by the Analytical Laboratory, the date/time the sample was extracted (if applicable), and the date/time the sample was analyzed. All out-of-compliance results will be logged by the Analysis Monitor with corrective actions described as well as the results of the corrective actions taken. All raw and reduced data will be stored according to the Analytical Laboratory's record keeping procedures and QA program. All Analytical Laboratory procedures and records will be available for on-site inspection at any time during the course of investigation. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 02-15-2022 Revision 7.7 Quality Assurance Plan (QAP) . Page 29 of61 If re-runs occur with increasing frequency, the Analysis Monitor and the QA Manager will be consulted to establish more appropriate analytical approaches for problem samples. 10.0 CORRECTIVE ACTION 10.1 When Corrective Action is Required The Sampling and QC Monitors and Analytical Laboratory are responsible for following procedures in accordance with this QAP. Corrective action should be taken for any procedural or systematic deficiencies or deviations noted in this QAP. All deviations from field sampling procedures will be noted during field data collection. Any QA/QC problems that arise will be brought to the immediate attention of the QA Manager. Analytical Laboratory deviations will be recorded by the Analysis Monitor in a logbook as well. When a procedural or systematic non-conformance is identified, EFRI shall: a) When non-conformance occurs as specified in Sections 9.1.3 or 9.1.4 the data shall be qualified to denote the problem and the QC sample-specific corrective actions in Sections 9.1.3, 9.1.4 or 9.3 will be followed. If the non-conformance is deemed to be systematic or procedural, EFRI shall determine the root cause, and provide specific steps to resolve problems(s) in accordance with the procedure set forth in Section 10.2. Any non-conformance with QAP requirements in a given quarterly groundwater monitoring period will be corrected and reported to the Director on or before submittal of the next quarterly ground water monitoring report. b) When a sample is lost, sample container broken, or the sample or analyte was omitted, resample within 10 days of discovery and analyze again in compliance with all requirements of this QAP. The results for this sample(s) should be included in the same quarterly monitoring report with other samples collected for the same sampling event; and c) For any other material deviation from this QAP, the procedure set forth in Section 10.2 shall be followed. 10.2 Procedure for Corrective Action The need for corrective action for non-conformance with the requirements of this QAP, may be identified by system or performance audits or by standard QA/QC procedures. The procedures to be followed if the need for a corrective action is identified, are as follows: a) Identification and definition of the problem; b) Assignment of responsibility for investigating the problem; c) Investigation and determination of the cause of the problem; Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 30 of61 d) Determination of a corrective action to eliminate the problem; e) Assigning and accepting responsibility for implementing the corrective action; t) Implementing the corrective action and evaluating its effectiveness; and g) Verifying that the corrective action has eliminated the problem. The QA Manager shall ensure that these steps are taken and that the problem which led to the corrective action has been resolved. The corrective actions will be documented either in a memorandum explaining the steps outlined above, which will be placed in the applicable monitoring files and the Mill Central Files, or the corrective action will be documented in the quarterly reports prepared in accordance with Section 11. 11.0 REPORTING As required by the GWDP, the Mill will send a groundwater monitoring report to the Director on a quarterly basis. Both the Routine Groundwater Monitoring Reports and Chloroform Investigation and Nitrate Corrective Action Reports shall be submitted according to the following schedule: Quarter Period Due Date First January -March June 1 Second April-June September 1 Third July -September December 1 Fourth October -December March 1 The Routine Groundwater Monitoring Reports (required by the GWDP) will include the following information: • Description of monitor wells sampled • Description of sampling methodology, equipment and decontamination procedures to the extent they differ from those described in this QAP • A summary data table of groundwater levels for each monitor well and piezometer • A summary data table showing the results of the sampling event, listing all wells and the analytical results for all constituents and identifying any constituents that are subject to accelerated monitoring in any particular wells pursuant to the GWDP or are out of compliance in any particular wells pursuant to the GWDP • Field data recorded during sample collection • Copies of Analytical Laboratory results • Copies of Chain of Custody Forms (included in the data packages) Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 31 of 61 • A Water Table Contour Map showing groundwater elevation data for the quarter will be contemporaneous for all wells on site, not to exceed a maximum time difference of five calendar days. • Evaluation of groundwater levels, gradients and flow directions • Quality assurance evaluation and data validation description (see Section 9 for further details) • All non-conformance with this QAP and all corrective actions taken With respect to the Chloroform Investigation and Nitrate Corrective Action reporting requirements, these are specified in Appendix A and B to this document. In addition, an electronic copy of all analytical results will be transmitted to the DWMRC in comma separated values ("CSV") format, or as otherwise advised by the DWMRC. Further reporting may be required as a result of accelerated monitoring under the GWDP. The frequency and content of these reports will be defined by EFRI corporate management working with the Director. 12.0 SYSTEM AND PERFORMANCE AUDITS 12.1 QA Manager to Perform System Audits and Performance Audits EFRI shall perform such system audits and performance audits as it considers necessary in order to ensure that data of known and defensible quality are produced during a sampling program. The frequency and timing of system and performance audits shall be as determined byEFRI. 12.2 System Audits System audits are qualitative evaluations of all components of field and Analytical Laboratory QC measurement systems. They determine if the measurement systems are being used appropriately. System audits will review field and Analytical Laboratory operations, including sampling equipment, laboratory equipment, sampling procedures, and equipment calibrations, to evaluate the effectiveness of the QA program and to identify any weakness that may exist. The audits may be carried out before all systems are operational, during the program, or after the completion of the program. Such audits typically involve a comparison of the activities required under this QAP with those actually scheduled or performed. A special type of systems audit is the data management audit. This audit addresses only data collection and management activities. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 12.3 Performance Audits Date: 02-15-2022 Revision 7 .7 Page 32 of61 The performance audit is a quantitative evaluation of the measurement systems of a program. It requires testing the measurement systems with samples of known composition or behavior to evaluate precision and accuracy. With respect to performance audits of the analytical process, either blind performance evaluation samples will be submitted to the Analytical Laboratory for analysis, or the auditor will request that it provide results of the blind studies that the Analytical Laboratory must provide to its NELAP accreditation agency on an annual basis. The performance audit is carried out without the knowledge of the analysts, to the extent practicable. 12.4 Follow-Up Actions Response to the system audits and performance audits is required when deviations are found and corrective action is required. Where a corrective action is required, the steps set out in Section 10.2 will be followed. 12.5 Audit Records Audit records for all audits conducted will be retained in Mill Central Files. These records will contain audit reports, written records of completion for corrective actions, and any other documents associated with the audits supporting audit findings or corrective actions. 13.0 PREVENTIVE MAINTENANCE Preventive maintenance concerns the proper maintenance and care of field and laboratory instruments. Preventive maintenance helps ensure that monitoring data generated will be of sufficient quality to meet QA objectives. Both field and laboratory instruments have a set maintenance schedule to ensure proper functioning of the instruments. Field instruments will be maintained as per the manufacturer's specifications and established sampling practice. Field instruments will be checked and calibrated prior to use, in accordance with Section 5. Batteries will be charged and checked daily when these instruments are in use. All equipment out of service will be immediately replaced. Field instruments will be protected from adverse weather conditions during sampling activities. Instruments will be stored properly at the end of each working day. Calibration and maintenance problems encountered will be recorded and addressed as soon as practical. The Analytical Laboratory is responsible for the maintenance and calibration of its instruments in accordance with Analytical Laboratory procedures and as required in order to maintain its NELAP certifications. Preventive maintenance will be performed on a scheduled basis to minimize downtime and the potential interruption of analytical work. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 33 of61 14.0 QUALITY ASSURANCE REPORTS TO MANAGEMENT 14.1 Ongoing QA/QC Reporting The following reporting activities shall be undertaken on a regular basis: a) The Sample and QC Monitors shall report to the QA Manager regularly regarding progress of the applicable sampling program. The Sample and QC Monitors will also brief the QA Manager on any QNQC issues associated with such sampling activities. b) The Analytical Laboratory shall maintain detailed procedures for laboratory record keeping. Each data set report submitted to the Mill's QA Manager or his staff will identify the analytical methods performed and all QNQC measures not within the established control limits. Any QNQC problems will be brought to the QA Manager's attention as soon as possible; and c) After sampling has been completed and final analyses are completed and reviewed, a brief data evaluation summary report (case narrative) will be prepared by the Analytical Laboratory for review by the QA Manager, by a Sampling and QC Monitor or by such other qualified person as may be designated by the QA Manager. The report will be prepared in accordance with NELAP requirements and will summarize the data validation efforts and provide an evaluation of the data quality. 14.2 Periodic Reporting to Management The QA Manager shall present a report to EFRI' s ALARA Committee at least once per calendar year on the performance of the measurement system and the data quality. These reports shall include: a) Periodic assessment of measurement quality indicators, i.e., data accuracy, precision and completeness; b) Results of any performance audits, including any corrective actions; c) Results of any system audits, including any corrective actions; and d) Significant QA problems and recommended solutions. 15.0 AMENDMENT This QAP may be amended from time to time by EFRI only with the approval of the Director. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 16.0 REFERENCES Date: 02-15-2022 Revision 7.7 Page 34 of61 United States Environmental Protection Agency, November 2004, Test Methods for Evaluating Solid Waste, EPA SW-846. United States Environmental Protection Agency, September, 1986, RCRA Ground-Water Monitoring Technical Enforcement Guidance Document (TEGD), Office of Solid Waste and Emergency Response, OSWER-9950.1. United States Environmental Protection Agency, November 1992, RCRA Ground-water Monitoring Draft Technical Guidance (DTG), Office of Solid Waste. Standard Methods for the Examination of Water and Wastewater, 201h Edition, 1998. American Public Health Association, American Water Works Association, Water Environment Federation. Washington, D.C. p. 1-7. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) ATTACHMENT 1 Field and Data Forms Date: 02-15-2022 Revision 7.7 Page 35 of61 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Attachment 1-1 Quarterly Depth to Water Data Sheet NAME: DATE: Depth to Depth to D11te Time Well Water (n.) Date Time Well Water (f'C.) Date: 02-15-2022 Revision 7.7 Date T1me Page 36 of61 Well Depth to Water (f'l.) Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 37 of61 ATTACHMENT 1-2 WHITE MESA URANIUM MILL FIELD DATA WORKSHEET J'OR GROUNDWATER A'ITACHMF:NT 1-2 WHfffi MESA URANIUM MILL FIELD DATA WORI<SHEETJ!'OR GROUNDWA'JER Description or Sampling Evenl: Location (well name): ~-------------0 Field Sample ID Sampler Name and initials: Date and Time for Purging..._ _______ __, and Sampling (if different) Well Purging Equip Used: [filpump or [fil bailer Well Pump (if other lhan Bennet) Purging Method Used: 1 ) Sec lns11uclion [filz casings [fil3 casings Prev. Well Sampled in Sampling Event I..__ _______ __, Sampling Event ~---------__, pll Buffer 7.0 !..__ ____ _, Specific Conduclance! .... ____ __..,jµMHOS/ cm Depth lo Water Before Purging._! ___ __. Weather Cond. Time I I Gal. Purged I I Conductance I I pH I I Temp. °C I I Redox Potential Eh (mV) I Turbidity (NTU) I Time I I Gal. Purged I Conductance I I pH I Temp. °C I I Rcdox Potential Eh (mV) I I Turbidily (NTU) I I pH Ruffer 4.0 Well Dcpth(O.Olft): Casing Volume (Y) 4" Wcll:I l(.653h) 3" Wcll:1-----1. (.367h) Ext'I Amb. Temp. •c (prior sampling event) ._I ___ _, Time I I Gal. Purged I I Conductance I I pH! I Temp. °C I I Rcdox Potential Eh (mV) I I Turbidity (NTU) I I Time I I Gal. Purged I I Conduclnncc I I pHI I Temp, ~c I I Redox Potenlial Eh (mY) I I Turbidity (NTU) I I Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Volume of Water Purged Pumping Rah: C11lc11ln1ion gallon(s) Date: 02-15-2022 Revision 7 .7 Page 38 of61 Flow Rate (Q). in w,11. S/60 = I.__ ___ __, Time to evacuate two ,using volumes (2Y) T =2V/Q=I l Number of casing volumes evacuated (if other than two) If well evacuated lo dryne.~s. number of gallons evacuated Name of Certified Analytical Laboratory if Other Than Energy Labs Sample Taken Sample Vol (indicatc if Filtered Preservative Preservative Added Type or Sample other than as specified Type y N below) y N y N voes D D 3x40 ml D D HCL D D Nutrients D D 100ml D D H2S04 D D Heavy Metals D D 250ml D D HN03 D D All Other Non Radiolo2ics D D 250ml D D No Preserv. D D Gross Alpha D D 1,000 ml D D HN03 D D Other (specify) D D Sample volume D D D D If preservative is used, specify Type and Quantity of Preservative: Final Depth ~' -----~ Sample Time Comment I -, See instruction .._ _______ __,Do not touch this cell (SheetName) Mill -GroundwaLcr Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Dace: 02-15-2022 Revision 7.7 Page39 of61 ATTACHMENT 1-3 EXAMPLE FIELD DATA REPORT White Mesa MIii Ftald o ... Wort<&IIMI For OICIUl\dMmr L-nlD MW-11 FIHIBamlllalD MW-U D3062019 l'ur11• o.te & Tlma 3/6/2019 6:55 lamole Da1e & Tllne 3/S/20U U,25 l'ur111na EciutomeM. Pumo l'umpTIIINI 0£0 PUTlllna Molhod 2casin11S Pr'filo111 Well 811 C•olna Volume 111111 Z!l.12 c11cu10111d Cuing VolUmff Pu.a• Oun,uon (mlnJ 26U2 'oH lutr.r r.o 7.0 'oH luffar •.o 4.0 lloaclflc Conduemnce imleroffllH>I) 1000 Da1a1T1ma Oollons Purald Conductlvltv Jiff TMllllllleaC} l/6/201911:22 S7.93 2917 HS 14.02 3/6/2019 U :23 58.15 2927 7.46 14.Dl 3/6/201.9 II :24 58.37 2925 7.48 14.DD 3/6/2019 U:25 58.59 29.30 7.48 14.01 !Volumo or w.i.r pmqoc1 (p-"I &HO Anll tc;.al " lnt01mat1on S.mple Col,ic;J.ed? Matrl• Numllel V WATER 1 aO',W\4*-tilM Ot\oft41,1 g,11 Pan:tl O!'...-wMmllonoo_/lsl_ .. Flan Mardi 2019 TH/OL !!loud D MW-30 130.00 85.40 1 ..... 0 .. _ Rado• TUrbldlll/ O•wan llefMa/Allal 266 0 262 0 259 0 256 0 .217 270.00 UK) 0 Preservative Added? y Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) ATTACHMENT 2 Field Procedures Date: 02-15-2022 Revision 7.7 Page 40 of61 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Attachment 2-1 Date: 02-15-2022 Revision 7.7 Page 41 of61 Groundwater Head (Depth to Water) Measurement Procedures Measure and record all depth to water data to the nearest 0.01 feet. Equipment Used For Groundwater Head Monitoring Measurement of depth to groundwater is accomplished by using a Solinist -IT 300 or equivalent device (the "Water Level Indicator"). Equipment Checks Equipment used in depth to groundwater measurements will be checked prior to each day's use to ensure that the Water Sounding Device is functional. Check the Water Sounding Device as follows: • Turn the Water Level Indicator on. • Test the Water Level Indicator using the test button located on the instrument. • If the Water Level Indicator alarms using the test button it is considered operational and can be used for depth to water measurements. Measurement of Depth to Water All depth to water measurements (quarterly and immediately prior to sample collection) will be completed using the following procedure: • For monitoring wells -Measure depth to water from the top of the inner well casing at the designated measurement point. • For the piezometers -Measure depth to water from the top of the casing at the designated measurement point. • Measurements are taken by lowering the Water Level Indicator into the casing until the device alarms, indicating that the water surface has been reached. • Record the depth to groundwater on the appropriate form in Attachment 1 as the distance from the measuring point to the liquid surface as indicated by the alarm. The distance is determined using the tape measure on the Water Level Indicator. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Attachment 2-2 Date: 02-15-2022 Revision 7.7 Page 42 of61 Decontamination Procedures Non-dedicated sampling equipment will be decontaminated using the following procedures: Water level meter Decontaminate the water level meter probe with deionized ("Dr') water. Field Parameter Instrument (Hydrolab or equivalent) Rinse the field parameter instrument probe unit with DI water prior to each calibration. Wash the cup of the flow through cell with a detergent/DI water mixture and rinse with fresh DI water prior to each calibration. Non-Dedicated Purging/Sampling Pump Non-dedicated sampling/purging equipment will be decontaminated after each use and prior to use at subsequent sampling locations using the following procedures: a) submerge the pump into a 55-gallon drum of nonphosphate detergent/DI water mixture; b) pump the detergent/DI water solution through the pump and pump outlet lines; c) pump as much of the detergent/DI water mixture from the drum through the pump and outlet lines as possible; d) submerge the pump into a 55-gallon drum of DI water; e) pump the DI water solution through the pump and pump outlet lines into the drain line connected to Cell 1; t) pump as much of the detergent/DI water mixture from the drum through the pump and outlet lines as possible; g) if an equipment rinsate blank is required, submerge the pump into a fresh 55- gallon drum of DI water and pump 50% or more of the DI water through the pump and pump outlet lines; Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page43 of61 h) if required, collect the equipment rinsate blank directly from the pump outlet lines into the appropriate sample containers (filtering the appropriate aliquots as needed). All water produced during decontamination of a non-dedicated pump will pumped to an appropriate drain line which outlets into Cell 1. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Attachment 2-3 Purging Procedures Date: 02-15-2022 Revision 7.7 Page 44 of61 The following equipment will be used for groundwater purging and sampling: • Disgosable Bailer: A bailer that is used at one specific well for one event for purging and/or sampling. These hailers are single use and are disposed of as trash after sampling in accordance with Mill disposal requirements for Mill-generated solid waste. • Dedicated Pump: A pump that is dedicated to one specific well for the use of purging or sampling. A dedicated pump remains inside the well casing suspended and secured. • Non -Dedicated Pump: A pump that is used for purging and sampling at one or more wells. • Field Parameter Meter: A meter used to measure groundwater quality parameters as listed below. Field parameters shall be measured using a Hydrolab M-5 with Flow Cell Multi-Parameter Meter system or equivalent that allows a continuous stream of water from the pump to the meter that enables measurements to be taken on a real-time basis without exposing the water stream to the atmosphere. The Field Parameter Meter measures the following parameters: ~ Water temperature; ~ Specific conductivity; ~ Turbidity; ~ pH; ~ Redox potential (Eh); ~ Dissolved Oxygen ("DO") • Water Level Indicator: A tape measure with a water level probe on the end that alarms when contact is made with water. • Generator: Mobile power supply to provide power for submersible pump. • 150 psi air compressor and ancillary equipment, or equivalent to operate dedicated "bladder" pumps. Additional supplies for purging and sampling are as follows: • IPad, tablet, Cell phone or Field Data Sheets • 45 micron in-line filters (when metals and gross alpha analyses are required) • Calculator • Clock, stopwatch or other timing device • Buckets • Sampling containers (as provided by the Analytical Laboratory) • Field preservation chemicals (as provided by the Analytical Laboratory) • Disposable gloves • Appropriate health and safety equipment • Sample labels (as provided by the Analytical Laboratory) Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Pre-Purging/ Sampling Activities Date: 02-15-2022 Revision 7.7 Page 45 of61 If a portable (non-dedicated) pump is to be used, prior to commencing the event's sampling activities, 1. check the pumping equipment to ensure that no air is leaking into the discharge line, in order to prevent aeration of the sample; 2. decontaminate the sampling pump using the procedure described in Attachment 2-2 and collect a equipment rinsate blank as required; and 3. Prior to leaving the Mill office, place the Trip Blank(s) and ice into a cooler that will transport the VOC samples. The Trip Blank(s) will accompany the groundwater (VOC) samples throughout the monitoring event. Well Purging The purging techniques described below will be used for all groundwater sampling conducted at the Mill unless otherwise stated in the program-specific QAPs for the chloroform and nitrate investigations. The program-specific QAPs for the chloroform and nitrate investigations are included as Appendix A and Appendix B respectively. Purging is completed using the equipment described above. Purging is completed to remove stagnant water from the casing and to assure that representative samples of formation water are collected for analysis. There are three purging strategies that will be used to remove stagnant water from the casing during groundwater sampling at the Mill. The three strategies are as follows: 1. Purging three well casing volumes with a single measurement of field parameters 2. Purging two casing volumes with stable field parameters (within 10% RPD) 3. Purging a well to dryness and stability of a limited list of field parameters after recovery The groundwater in the well should recover to within at least 90% of the measured groundwater static surface before sampling. If after 2 hours, the well has not recovered to 90% the well will be sampled as soon as sufficient water for the full analytical suite is available. Turbidity measurement in the water should be 5 5 NTU prior to sampling unless the well is characterized by water that has a higher turbidity. A flow-cell needs to be used for field parameters. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 02-15-2022 Revision 7.7 Page 46 of 61 Quality Assurance Plan (QAP) Procedure a) Determine the appropriate purging strategy based on historic performance of the well (3 casing volumes, 2 casing volumes and stable parameters, or purging the well to dryness) b) Remove the well casing cap and measure and record depth to groundwater as described in Attachment 2-1 above; c) Determine the casing volume (V) in gallons. When using the electronic data collection module, input the depth to water in the appropriate location. The module will calculate the casing volume. Proceed to purging. When the field data are collected manually, calculate the casing volume where h is column height of the water in the well (calculated by subtracting the depth to groundwater in the well from the total depth of the well), V = 0.653*h, for a 4" casing volume and V = .367*h for a 3" casing volume. Record the casing volume on the Field Data Worksheet; If a portable (non-dedicated) pump is used: • Ensure that it has been decontaminated in accordance with Attachment 2-2 since its last use. • Lower the pump into the well. Keep the pump at least five feet from the bottom of the well. If a non-dedicated pump or dedicated pump is used: (i) Commence pumping; (ii) For a non-dedicated pump only, determine pump flow rate by using a stopwatch or other timing device and a calibrated bucket by measuring the number of seconds required to fill to the one-gallon mark. Record this in the "pumping rate" section on the Field Data Worksheet or in the "flow rate" section in the electronic field collection module; (iii) Calculate the amount of time to evacuate two or three casing volumes; (iv) Evacuate two or three casing volumes by pumping for the length of time determined in paragraph (iii); (v) If two casing volumes will be purged: Take measurements of field parameters (pH, specific conductance, temperature, redox potential, turbidity, and DO) during well purging, using the Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 47 of61 Field Parameter Meter. These measurements will be recorded either electronically or on the Field Data Worksheet. Purging is completed after two casing volumes have been removed and the field parameters pH, temperature, specific conductance, redox potential (Eh), turbidity, and DO have stabilized to within 10% RPD over at least two consecutive measurements. (vi)lf three casing volumes will be purged: Take one set of measurements of field parameters (pH, specific conductance, temperature, redox potential, turbidity, and DO) after three casing volumes have been purged immediately prior to sample collection using the Field Parameter Meter. Record these measurements either electronically or on the Field Data Worksheet. (vii) If the well is purged to dryness: Record the number of gallons purged either electronically or on the Field Data Worksheet. The well should be sampled as soon as a sufficient volume of groundwater is available to fill sample containers. Upon arrival at the well after recovery or when sufficient water is available for sampling measure depth to water and record either electronica1ly or on the Field Data Worksheet. Take one set of measurements of field parameters for pH, specific conductance and temperature only. Collect the samples into the appropriate sample containers. Take an additional set of measurements of field parameters for pH, specific conductance and temperature after the samples have been collected. If the field parameters of pH, specific conductance and temperature are within 10% RPD the samples can be shipped for analysis. If the field parameters of pH, specific conductance and temperature are not within 10% RPD, dispose of the sample aliquots, and purge the well again as described above. Repeat this process if necessary for three complete purging events. If after the third purging the event, the parameters of pH, specific conductance and temperature do not stabilize to within 10% RPD, the well is considered sufficiently purged and collected samples can be submitted for analysis. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Purging using a disposable bailer Date: 02-15-2022 Revision 7 .7 Page 48 of61 For wells where a pump is not effective due to shallow water columns, a disposable bailer, made of inert materials, will be used. When a bailer is used, the following procedure will be followed: (i) Use the water level meter to determine the water column and figure the amount of water that must be evacuated. (ii) Attach a disposable bailer to a rope and reel. (iii)Lower the bailer into the well and listen for contact with the solution. Once contact is made, allow the bailer to gradually sink in the well, being careful not to allow the bailer to come in contact with the bottom sediment. (iv)After the bailer is full, retrieve the bailer and pour the water from the bailer into 5 gallon buckets. By doing this, one can record the number of gallons purged. (v) Repeat this process until either two casing volumes have been collected or until no more water can be bailed. When the process is finished for the well, the bailer will be disposed of. (vi)Take field measurements from the water in the buckets. All water produced during well purging will be containerized. Containerized water will be disposed of into an active Tailings Cell. After the collection of all samples, and prior to leaving the sampling site, replace the well cap and lock the casing. Mill -Groundwater Discharg~ Pennit Ground water Monitoring Quality Assurance Plan (QAP) Attachment 2-4 Sample Collection Procedures Sample Collection Order Dale; 02-1.5-2022 Revision 7,7 Page 49 of 61 Regardless of the purging method employed samples will be collected in the order specified below. All containers and preservatives will be provided by the Analytical Laboratory. ColJect the samples in accordance with the volume, container and preservation requirements specified by the Analytical Laboratory which should be provided with the supplied containers. VOCs; Nutrients (ammonia, nitrate and nitrite); All other non-radiologies (general inorganics, TDS, anions. total cations and total anions); and Gross alpha and he~vy metals (filtered). Sample Filt~ri~g When sampling for heavy metals and for gross alpha, the following procedure shall be followed: a) Obtain the specifically identified sample container for the type of samp]e to be taken, as provided by the Analytical Laboratory; b) Add the quantity of specified preservative provjded by the Analytical Laboratory to each sample container; c) When using a pump to sample: (i) Place a new 0.45 micron filter on the sample tubing; (ii) Pump the sample through the filter, and into the sample container containing the preservative; (iii) The pump should be operated so that it does not produce samples that are aerated in the return tube or upon discharge; d) When using a bailer to sample (wells with shallow water columns, i.e., where the water column is less than five feet above the bottom of the well casing), then the following procedure will be used to filter samples: (i) Collect samples ftom the bailer into a large, unused samp]e jug that does not contain any preservatives. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 50 of61 (ii) Add the appropriate preservatives to the appropriate sample container provided by the Analytical Laboratory. (iii) Place dean unused tubing in the peristaltic pump. (iv) Use the peristaltic pump to transfer the unpreserved sample from the large sample jug to the sample containers through a 0.45 micron filter. Procedures to Follow After Sampling a) In each case, once a sample is taken, identify and label the sample container using the labels provided by the Analytical Laboratory. The labels may include the following information depending on the type of analysis requested: • Sample location ~ Date and time of sample • Any preservation method utilized • Filtered or unfiltered b) Immediately after sample collection, place each sample in an ice-packed cooler; and c) Before leaving the sampling location, thoroughly document the sampling event either electronically or on the Field Data Worksheet, by recording all pertinent data. Upon returning to the office, the samples must be stored in a refrigerator at less than or equal to 6° C. These samples shall be received by the Analytical Laboratory at less than or equal to 6° C. Samples will then be re-packed in the plastic ice-packed cooler and transported via these sealed plastic containers by overnight delivery services to the Analytical Laboratory. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Field Duplicates Attachment 2-5 Field QC Samples Date: 02-15-2022 Revision 7.7 Page 51 of61 Field duplicates are required to be collected at a frequency of one duplicate per every 20 field samples. Field duplicate samples are analyzed for the same analytes as the parent sample. Field duplicate samples should be as near to split samples as reasonably practicable. Collection of field duplicates is completed as follows: Fill a single VOC vial for the parent sample. Collect a second VOC vial for the duplicate sample. Collect the second set of VOC vials for the parent immediately followed by the duplicate sample. Fill the third set of VOC vials in the same manner. Repeat this parent/duplicate process for the remaining analytes in the order specified in Attachment 2-4 blind to the Analytical Laboratory. Field duplicate samples are labeled using a "false" well number such as MW-65 and MW-70. Equipment Rinsate Samples Where portable (non-dedicated) sampling equipment is used, a rinsate sample will be collected at a frequency of one rinsate sample per 20 field samples collected from non- pumping wells. Pumping wells have dedicated pumps and will not be included in the total sample count for the purposes of calculating the number of required rinsate samples. Equipment rinsate samples are collected after the decontamination procedure in Attachment 2-2 is completed as follows: Submerge the pump into a fresh 55-gallon drum of DI water and pump 50% or more of the DI water through the pump and pump outlet lines; Collect the equipment rinsate blank directly from the pump outlet lines into the appropriate sample containers (filtering the appropriate aliquots as needed). Equipment rinsate blanks are labeled with the name of the subsequently purged well with a terminal letter "R" added ( e.g. MW-1 lR). Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Appendix A Date: 02-15-2022 Revision 7.7 Page 52 of 61 Chloroform Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 53 of61 Chloroform Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah This document sets out the quality assurance plan to be used by EFRI for Chlorofonn monitoring conducted pursuant to the Groundwa.ter Corrective Action Plan ("GCAP") found in Attachment 1, of the final Stipulation and Consent Order ( .. SCO") dated September 14, 2015. (UDEQ Docket No. UGW-20-01). Specifically, the Mill will use the same sampling regimen for the Chlorofonn Investigation that is utilized for groundwater sampling under its groundwater discharge permit, as set forth in the attached groundwater discharge permit Quality Assurance Plan (QAP), except as set fortn below: I) Dedicated Purge Pump/Sampling Chloroform samples are collected by means of disposabie bailer(s) the day following the purging. The disposable bailer is used only for the collection of a sample from an individual well and disposed subsequent to the sampling. The wells are purged prior to sampling by means of a portable pump. Each quarterly purging event begins at the location least affected by chloroform (b~sed on the previous quarters sampling event) and proceeds by affected concentration to the most affected location. Although purging will generally follows this order, the sampling order may deviate slightly from the generated list. This practice does not affect the samples for these reasons: any wells sampled in slightly different order have either dedicated pumps or are sampled via a disposable bailer. This ptactice docs not affect the quality or usability of the data as there will be no cross~contamination resulting from sampling order. Decontamination of all sampling equipment will follow the decontamination procedure outlined in Attachment 2-2 of the QAP. 2) Chloroform lnve tigation,Sampling Frequency, Order and Locations The chloroform investigation wel1s listed below are required to be monitored on a quarterly basis under SCA and GCAP. Chloroform wells shall be purged from the least contaminated to the most contaminated as based on the most recent quarterly results. • MW-4 • TW4-22 • TW4-l • TW4-23 • TW4-2 • TW4-24 • TW4-3 • TW4-25 • TW4-4 • TW4-26 • TW4-5 • TW4~27 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) • TW4-6 • TW4-7 • TW4-8 • TW4-9 • TW4-10 • TW4-11 • TW4-12 • TW4-13 • TW4-14 • MW-26 • TW4-16 • MW-32 • TW4-18 • TW4-19 • TW4-20 • TW4-21 • TW4-28 • TW4-29 • TW4-30 • TW4-31 • TW4-32 • TW4-33 • TW4-34 • TW4-35 • TW4-36 • TW4-37 • TW4-38 • TW4-39 • TW4-40 • TW4-41 • TW4-42 • TW4-43 Date: 02-15-2022 Revision 7.7 Page 54 of61 Note: Wells MW-26 and MW-32 may be monitored under either the Chloroform Program or the Groundwater Discharge Permit Monitoring Program. 3) Chloroform Sample Containers and Collection Volume The chloroform sampling program requires a specific number of sampling containers and the collection of specific volumes of sample. Accordingly, the following sample volumes are collected by bailer from each sampling location: • For Volatile Organic Compounds (VOC), collect three samples into three separate 40 ml containers. • For Nitrate/Nitrite determinations, collect one sample into a 250 ml container. • For Inorganic Chloride, collect one sample into a 500 ml container. The Analytical Laboratory will provide the sampling containers and may request that certain analytes be combined into a single container due to like sampling requirements and/or like preservation. The container requirements will be determined by the Analytical Laboratory and specified with the bottles supplied to the Field Personnel. Bottle requirements may change if the Analytical Laboratory is changed or if advances in analytical techniques allow for reduced samples volumes. The above list is a general guideline. 4) Laborato1y Requirements Collected samples which are gathered for chloroform investigation purposes are shipped to an analytical laboratory where the requisite analyses are performed. At the laboratory the following analytical specifications must be adhered to: Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Analytical Analytical Parameter Method Nitrate & Nitrite E353.1 or (asN) E353.2 or A4500- N03F Carbon SW8260B, Tetrachloride SW8260C or SW8260D Chloroform SW8260B, SW8260C or SW8260D Dichloromethane SW8260B, (Methylene SW8260C Chloride) or SW8260D Chloromethane SW8260B, SW8260C or SW8260D Inorganic A4500-CIB Chloride or A4500-Cl E or E300.0 5) Field Parameters Date: 02-15-2022 Revision 7.7 Page 55 of 61 Reporting Maximum Sample Sample Limit Holding Preservation Temperature Times Requirement Requirement 0.1 mg/L 28 days H2S04 to :5 6°C pH<2 1.0 µg/L 14 days HCI topH<2 :5 6°C 1.0 µg/L 14 days HCl to pH<2 :5 6°C 1.0 µg/L 14 days HCl to pH<2 :5 6°C 1.0 µg/L 14 days HCl topH<2 :5 6°C 1 mg/L 28 days None :5 6°C Only one set of field parameters are required to be measured prior to sampling in chloroform pumping wells. However, if a pumping well has been out of service for 48 hours or more, EFRI shall follow the purging requirements outlined in Attachment 2-3 of the QAP before sample collection. Field parameters will be measured in chloroform wells which are not continuously pumped as described in Attachment 2-3 of the groundwater QAP. 6) Chl oroform Quarterly Reports The Chloroform Quarterly Reports will include the information required by Part ID of the GCAP. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 56 of 61 Except as otherwise specified above, the Mill will follow the procedure set out in the Mill's QAP. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Appendix B Date: 02-15-2022 Revision 7.7 Page 57 of61 Nitrate Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 02-15-2022 Revision 7.7 Quality Assurance Plan (QAP) Nitrate Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Page 58 of61 This document sets out the quality assurance plan to be used by Denison Mines (USA) Corp. for Nitrate Corrective Action Monitoring ("Nitrate Program") conducted pursuant to the Stipulation and Consent Order ("SCO"), Docket Number UGW12-04, which approved the EFRI CAP, dated May 7, 2012. Specifically, the Mill will use the same sampling regimen for the Nitrate program that is utilized for groundwater sampling under its groundwater discharge permit, as set forth in the attached groundwater discharge permit Quality Assurance Plan ("QAP"), except as set forth below: 1) Purge Pump/Sampling The Nitrate program wells are purged and sampled by means of a portable pump. If the well is purged to dryness the samples are collected the following day by means of disposable bailer(s). The disposable bailer is used only for the collection of a sample from an individual well and disposed subsequent to the sampling. Each quarterly purging event begins at the location least affected by nitrate (based on the previous quarters sampling event) and proceeds by affected concentration to the most affected location. Purging and sampling follows this order if the wells are not purged to dryness and the samples are collected immediately after purging using the portable pump. If the well is purged to dryness and sampled with a disposable bailer, the sampling order may deviate slightly from the generated list. This practice does not affect the samples collected with a bailer for this reason: there is no cross- contamination resulting from sampling order when the samples are collected with a disposable bailer. Decontamination of all non-disposable sampling equipment will follow the decontamination procedure outlined in Attachment 2-2 of the QAP. 2) Nitrate Program Sampling Frequency, Order and Locations The Nitrate Program wells listed below are required to be monitored on a quarterly basis as required by the SCO, Docket Number UGW12-04, which approved the EFRI CAP, dated May 7, 2012. Nitrate Program wells shall be purged from the least contaminated to the most contaminated as based on the most recent quarterly results. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) • TWN-1 • TWN-2 • TWN-3 • TWN-4 • TWN-6** • TWN-7 **De12th to water measurements only. • • • • • • • Date: 02-15-2022 Revision 7.7 Page 59 of61 TWN-14** TWN-16** TWN-18 TWN-19** Piezometer-01 Piezometer-02 Piezometer-03A 7) Nitrate Program Sample Containers and Collection Volume The Nitrate Program sampling requires a specific number of sampling containers and the collection of specific volumes of sample. Accordingly, the following sample volumes are collected by bailer from each sampling location: • For Nitrate/Nitrite determinations, collect one sample into a 250 ml container. • For Inorganic Chloride, collect one sample into a 500 ml container. The Analytical Laboratory will provide the sampling containers and may request that certain analytes be combined into a single container due to like sampling requirements and/or like preservation. The container requirements will be determined by the Analytical Laboratory and specified with the bottles supplied to the Field Personnel. Bottle requirements may change if the Analytical Laboratory is changed or if advances in analytical techniques allow for reduced samples volumes. The above list is a general guideline. 8) Laboratory Requirements Collected samples which are gathered for Nitrate Program purposes are shipped to an analytical laboratory where the requisite analyses are performed. At the laboratory the following analytical specifications must be adhered to: Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 02-15-2022 RevisiQn 7.7 Page 60 of 61 Quality Assurance Plan (QAP) Analytical Analytical Reporting Maximum Sample Sample Parameter Method Limit Holding Preservation Temperature Times Requirement Requirement Nitrate & Nitrite E353. l or 0.1 mg/L 28 days HiS04 to ~6°C (asN) E353.2 or pH<2 A4500- N03F Inorganic A4500-CJ B 1 mg/L 28 days None ~6°C Chloride or A4500-CI E or E300.0 9) fjeJd Parameters Field parameters will be measured in Nitrate Program wells as de.scribed in Attachment 2-3 of the groundwater QAP. 10) Nitrate Program Investigation Reports The Nitrate Program Reports will include the following information: a) Introduction b) Sampling and Monitoring Plan • Description of monitor wells • Description of sampling methodology, equipment and decontamination procedures • Identify all quality assurance samples, e.g. trip bJanks, equipment bJanks, duplicate samples c) Data Interpretation • Interpretation of groundwater levels, gradients, and flow directions. Interpretations will include a discussion on: l) A current site groundwater contour map, 2) hydrographs to show groundwater el~vation in each monitor well over time, 3) depth to groundwater measured and groundwater elevation from each monitor well summarized in a data tabJe, that includes historic groundwater level data for each well, and 4) an evaluation of the effectiveness of hydraulic capture of all contaminants of concern. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 02-15-2022 Revision 7.7 Page 61 of61 • Interpretation of all analytical results for each well, analytical results for each well summarized in a data table, that includes historic analytical results for each well. • Calculate nitrate mass removed by pumping wens (as the pumps are installed and operational). Calculations would include: 1) total nitrate mass removed, 2) total historic nitrate mass removed for each pumping well, 3) total nitrate mass removed for the quarter and, 4) total nitrate mass removed from each pumping well for the quarter. d) Conclusions and Recommendations e) Electronic copy of all laboratory results for Nitrate Program monitoring conducted during the quarter. f) Copies of EFRI field records, laboratory reports and chain of custody forms. Except as otherwise specified above, the Mill will follow the procedure set out in the Mill's QAP. Appendix L Tailings and Slimes Drain Sampling Program, Revision 3.0, July 8, 2016 White Mesa Uranium Mill SAMPLING AND ANALYSIS PLAN FOR THE TAILINGS MANAGEMENT SYSTEM, LEAK DETECTION SYSTEMS AND SLIMES DRAINS State of Utah Groundwater Discharge Permit No. UGW370004 Prepared by: Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, CO 80228 July 8, 2016 Tailings Management System, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 3.0 July 8, 2016 Contents 1.0 Introduction ............................................................................................................................... 3 2.0 Sampling Frequency and Monitoring Requirements ................................................................ 3 3.0 Field Sampling Procedures ....................................................................................................... 3 3.1 Cell Solution Sampling ......................................................................................................... 4 3.1.1 Sampling with a Peristaltic Pump .................................................................................. 4 3.1.2 Sampling with a Ladle ................................................................................................... 5 3.1.3 Sampling with a Bailer ................................................................................................... 5 3.2 LDS Sampling ....................................................................................................................... 5 3.2.1 Cells 1, 2 and 3 LDS ...................................................................................................... 5 3.2.2 Cells 4A and 4B LDS .................................................................................................... 5 3.3 Slimes Drain Sampling ......................................................................................................... 5 3.4 Decontamination ................................................................................................................... 6 3.5 Field QC ................................................................................................................................ 6 3.5.1 Sample Duplicates ......................................................................................................... 6 3.5.2 Trip Blanks ..................................................................................................................... 6 3.5.3 Rinsate Blank Samples .................................................................................................. 6 4.0 QA and Data Evaluation ........................................................................................................... 7 5.0 Laboratory Analysis .................................................................................................................. 7 5.1 Analytical Quality Control ............................................................................................... 7 6.0 Reporting ................................................................................................................................... 8 7 .0 Agency Notification ................................................................................................................. 8 2 Tailings Management System, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 3.0 July 8, 2016 1.0 Introduction This Sampling and Analysis Plan ("SAP") describes the procedures for sampling solutions in the tailings management system, Leak Detection Systems ("LDS") and slimes drains at the White Mesa Mill in Blanding, Utah as required under Part I.E.10 of the Groundwater Discharge Permit ("GWDP") No. UGW370004. The objective of the sampling is to collect annual samples from the locations identified below as required by the GWDP. This SAP specifies the sample collection requirements, procedures, analytical methodologies, and associated Quality Control ("QC") checks, sample handling protocols and reporting requirements for the annual cell solution, LDS and slimes drain sampling program. 2.0 Sampling Frequency and Monitoring Requirements The sampling frequency and sample monitoring requirements for the cell solutions, LDS and slimes drains are as specified in the GWDP. Sampling is required to be conducted on an annual basis in August of each year for the solutions in Cells 1, 3, 4A, and 4B, the solutions in the slimes drains in Cells 2, 3, 4A, and 4B (for Cells 3, 4A, and 4B after the commencement of dewatering), the solutions in the LDS in Cells 4A and 4B and any detected solutions in the LDS in Cells 1, 2, and 3 at the time of the August sampling event. Sampling locations are shown in Attachment 1. 3.0 Field Sampling Procedures The field sampling and data collection program will obtain samples to be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP. Analyses will be completed by a State of Utah certified laboratory using methods specified in the currently approved Energy Fuels Resources (USA) Inc. ("EFRI") Quality Assurance Plan ("QAP") for Groundwater. Additionally per the GWDP requirements, cell solutions, LDS and slimes drain samples will be collected and analyzed for Semivolatile Organic Compounds ("SVOCs"). Per the GWDP, the SVOCs will be analyzed by Environmental Protection Agency ("EPA") Method 8270D. Minimum detection limits or reporting limits for cell solutions, LDS and slimes drain samples for those analytes which have Groundwater Quality Standards (GWQSs") defined in Table 2 of the GWDP, will be less than or equal to the GWQS. The minimum detection or reporting limits for total dissolved solids ("TDS") sulfate, chloride and SVOCs are specified in the GWDP and are: • TDS will be less than or equal to 1,000 mg/L, • Sulfate will be less than or equal to 1,000 mg/L, • Chloride will be less than or equal to 1 mg/L, and • SVOCs will have reporting limits less than or equal to the lower limit of quantitation for groundwater listed in Table 2 of EPA Method 8270D Revision 4, dated February 2007. Field activities include collecting samples, recording field data and field parameters, and preparing and shipping samples to the analytical laboratory. Sampling information will be recorded on the Tailings Management System and Slimes Drain Field Sheet, (or its equivalent), included in Attachment 2. 3 Tailings Management System, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 3.0 July 8, 2016 Sample handling and preservation requirements for cell solutions, LDS and slimes drain samples are as specified in the QAP, except for SVOCs which are not routinely collected for any other Mill sampling program. SVOCs do not require any chemical preservation per EPA Method 8270D; however, SVOCs are required to be chilled. Receipt temperatures, for all analytes except SVOCs, are as specified in the QAP. The receipt temperature requirement for SVOCs is less than or equal to 6°C. Sample collection procedures for cell solutions, LDS and slimes drain samples are as described below. Where more than one sampling method is described, field personnel will choose a sampling method based on field conditions and safety considerations at the time of sampling. The gross alpha and metals sample aliquots of the cell solutions, LDSs and slimes drains will not be field filtered or field preserved due to safety concerns associated with the filtering apparatus and the backpressure created by the increased viscosity of these samples. The gross alpha and metals aliquots will be filtered and preserved by the analytical laboratory within 24 hours of receipt. Field preservation of the gross alpha and metals sample aliquots may interfere with the laboratory's ability to filter the samples upon receipt. It is important to note that field preservation of the samples is to preclude biological growth and prevent the inorganic analytes from precipitating. Based on the previous field data, the cell solutions, LDS and slimes drain samples were at a pH of 3.0 or less at the time of collection without additional preservative. The addition of preservatives in the field would add minimal if any protection from biological growth or precipitation. The VOC sample aliquots will be preserved in the field. Clean sample containers utilized for this sampling effort will be provided by the analytical laboratory. 3.1 Cell Solution Sampling As noted in Section 2.0, sampling is required to be conducted on an annual basis in August of each year for the solutions in Cells 1, 3, 4A, and 4B. Cell solution samples may be collected using a ladle, a peristaltic pump or a bailer. The procedures for each sampling method are described below. In all instances the sampling equipment will be either disposable or dedicated and decontamination procedures and rinsate blanks will not be required. Sampling equipment will be inert and non-reactive. 3 .1.1 Sampling with a Peristaltic Pump Cell solution samples may be collected using a peristaltic pump. Samples collected with the peristaltic pump will be collected by extending collection tubing approximately 6 ft. from the edge of the sampling station. The tubing will be attached to a horizontal rod with sufficient tubing attached to lower the suction end of the tubing to approximately 2 feet below the surface. The collection tubing will be attached to a peristaltic pump. The tubing will be replaced prior to each use to preclude cross contamination and to eliminate the need for decontamination of sampling equipment. Due to the nature of the peristaltic pump, sample fluids do not come in contact with any surface other than the interior of the tubing, and decontamination of the pump or rinsate blanks is therefore not required. The sample containers will be filled directly from the peristaltic pump outflow. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required, as noted in Section 3.0. 4 Tailings Management System, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 3.0 July 8, 2016 3.1.2 Sampling with a Ladle Cell solution samples may be collected using a ladle. Samples collected with the ladle will be collected by dipping the ladle directly into the solution. Sample bottles will be filled directly from the ladle. Ladles used for sampling will be dedicated to each location or will be disposed after each use to preclude cross contamination and to eliminate the need for decontamination of sampling equipment. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be completed as noted in Section 3.0. 3.1.3 Sampling with a Bailer Cell solution samples may be collected using a disposable bailer. Samples collected with the bailer will be collected by submerging the bailer into the solution and allowing it to fill, taking care not to allow the bailer to contact the bottom of the cell. The bailer will withdrawn from the solution and the sample bottles will be filled directly from the bailer. Bailers used for sampling will be disposed after each use to preclude cross contamination and to eliminate the need for decontamination of sampling equipment. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required as noted in Section 3.0. 3.2 LDS Sampling The LOS systems will be sampled as noted below. 3.2.1 Cells I, 2 and 3 LOS The Cells 1, 2 and 3 LOSs will only be sampled if there is fluid present during the August sampling event. If fluids are present during the annual August sampling event, samples will be collected using the dedicated pumps installed in the riser pipe. Fluid level will be measured using the electronic pressure transducers currently installed in the LOS systems in the cells. Samples will be collected directly from the pump outflow lines into the sample containers. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required as noted in Section 3.0. 3.2.2 Cells 4A and 4B LDS Solution from the Cell 4A and 4B LOS will be collected into a dedicated stainless steel bucket. Sample bottles will be filled from the stainless steel bucket using either the peristaltic pump or a ladle. If the peristaltic pump is used to transfer the solution to the sample bottles, the tubing in the pump will be disposed of and not reused, thereby eliminating the need for decontamination of equipment or rinsate blanks. If a ladle is used to transfer the solution to the sample bottles, the ladle will be either disposed of or will be dedicated to that location thereby eliminating the need for decontamination or rinsate blanks. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required as noted in Section 3.0. 3.3 Slimes Drain Sampling Once a tailings cell has started de-watering procedures, a sample should be collected from the slimes drain system. At this time Cell 2 is the only slimes drain that should be sampled. The location of the slime drain for Cell 2 is depicted on Attachment 1. While Cell 3, Cell 4A and 4B are each equipped with 5 Tailings Management System, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 3.0 July 8, 2016 a slimes drain sample access location, these Cells have not started dewatering and the slimes drain will not be sampled until dewatering operations are underway. Because de watering in Cell 2 is ongoing, this cell will be included in the annual sampling effort. The Cell 2 slimes drain will be sampled using a disposable bailer. A disposable bailer will be used to collect Cell 2 slimes drain samples and will be used to fill clean sample containers. The bailer will be disposed of and not reused, thereby eliminating the need for decontamination of equipment or rinsate blanks. 3.4 Decontamination Decontamination of sampling equipment will be completed if non-dedicated and/or non-disposable sampling equipment is used to collect samples. Decontamination procedures will be as described in the approved QAP. Rinsate blanks will be collected daily after decontamination of sampling equipment. If disposable or dedicated sampling equipment is used to collect samples, then rinsate blanks will not be collected. 3.5 Field QC The field QC samples generated during the annual cell solution, LDS and slimes drain sampling event will include sample duplicates, trip blanks, and rinsate blank samples as appropriate. 3.5.1 Sample Duplicates Sample duplicates will be collected at a frequency of one duplicate per 20 field samples. Sample duplicates will be collected by filling the sample container for a certain analytical parameter for the duplicate immediately following the collection of the parent sample for that parameter. 3.5.2 Trip Blanks Trip blank samples will be included in every shipment of samples that has field samples to be analyzed for Volatile Organic Compounds ("VOCs"). Trip blank samples are VOC sample containers filled by the analytical laboratory with laboratory grade deionized water and shipped to the site. Trip blank samples are taken into the field with the sample containers, never opened, and kept with the field samples from collection through shipment to the analytical laboratory for analysis. Trip blanks are analyzed to determine if the sample concentration of VOCs have been effected by the "trip" from collection through shipment. 3.5.3 Rinsate Blank Samples Rinsate blank samples are collected at a frequency of one per day when non-disposable, non-dedicated, reusable sampling equipment is used to collect samples. If the sampling equipment has a disposable component that comes in contact with the samples and the component is changed prior to sampling at each location then a rinsate blank sample will not be collected. For example, if a peristaltic pump is used to collect and filter tailings, LDS and slimes drain samples and the tubing used in the peristaltic pump is changed at each location and never reused for more than one sample, no rinsate blank sample would be required. 6 Tailings Management System, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 3.0 July 8, 2016 4.0 QA and Data Evaluation The Permit requires that the annual sampling program be conducted in compliance with the requirements specified in the Mill's approved QAP, the approved SAP and the Permit itself. To meet this requirement, the data validation for the sampling program will utilize the requirements outlined in the QAP, the Permit and the approved SAP as applicable. The Mill QA Manager will perform a QA/QC review to confirm compliance of the monitoring program with requirements of the Permit, QAP and SAP. As required in the QAP, data QA includes preparation and analysis of field QC samples, review of field procedures, an analyte completeness review, and quality control review of laboratory data methods and data. The QAP and the Permit identify the data validation steps and data quality control checks required for the tailings cell LDS and slimes drain monitoring program. Consistent with these requirements, the Mill QA Manager will performed the following evaluations: a field data QA/QC evaluation, a receipt temperature check, a holding time check, an analytical method check, a reporting limit check, a trip blank check, a QA/QC evaluation of sample duplicates, a gross alpha counting error evaluation and a review of each laboratory's reported QA/QC information. The corrective action procedures described in the approved QAP will be followed as necessary when data validation and QC reviews indicate a non-compliant situation. 5.0 Laboratory Analysis As previously stated, samples will be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP and SVOCs using the analytical methods specified in the approved QAP and EPA Method 8270D for SVOCs. The Laboratories used for the sampling program will be Utah certified as required by the GWDP Part l.E.6 (c). Laboratory data will be validated as described in the approved QAP and as described in Section 4.0 above. Analytical QC is described below. 5.1 Analytical Quality Control Analytical QC samples and protocols are described in the approved QAP. Laboratory QC procedures will meet, at a minimum, the requirements set forth in the analytical methods that the laboratory is certified for by the State of Utah. The analytical QC samples included at least the following: a method blank, a laboratory control spike ("LCS"), a matrix spike ("MS") and a matrix spike duplicate ("MSD"), or the equivalent, where applicable. It should be noted that: • Laboratory fortified blanks are equivalent to LCSs. • Laboratory reagent blanks are equivalent to method blanks. • Post digestion spikes are equivalent to MSs. • Post digestion spike duplicates are equivalent to MSDs. • For method E900.1, used to determine gross alpha, a sample duplicate was used instead of a MSD. 7 Tailings Management System, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 3.0 July 8, 2016 All qualifiers, and the corresponding explanations reported in the QNQC Summary Reports for any of the analytical QC samples for any of the analytical methods will be reviewed by the Mill QA Manager. The effect on data usability will be discussed in the evaluation section of the annual report. 6.0 Reporting An annual Tailings System Wastewater Sampling Report will be included with the 3rd Quarter Groundwater Monitoring Report, due each year on December 1st. Each Tailings System Wastewater Sampling Report will include the following information: • Introduction, • A description of sampling methodology, equipment and decontamination procedures identify all quality assurance samples, e.g. trip blanks, equipment blanks, duplicate samples, • Analytical data interpretation for each tailing cell, slimes drain, and leak detection system sample, • A written summary and conclusions of analytical results, • A table summarizing historic analytical results, • A QA evaluation, • All field data sheets accompanying the sampling event, • Copies of the laboratory reports, and • A "Tailings and Slime Drains System Sample Locations Map". 7 .0 Agency Notification At least 30 days advanced notice will be given to Division of Waste Management and Radiation Control ("DWMRC") prior to sampling activities described in this Tailings Management System, Leak Detections System and Slimes Drain SAP in order to allow DWMRC to collect split samples of all samples. 8 Attachment 1 9 ~ [i] a:: I'-., a, 0 a.. a, 3: -0 ~ ::, a, i.;: t:: 0 a. ., a:: .!!l ~ c ::, C C c C Q) E Q) a, 0 C 0 ::I: (/) a, ~ 'ci !;;-(/) a. 0 ::::;; .,;; 'i 0 (/) ., ::I! ., ~ .<: 3: \'.'.'.'.' ~ / ., !:: ::, 0 Ul / cii 32 MW-G3 • 600' I 0 I II II fl ~ 600' I SCALE: 1" • 1,000' 1,000' I CELL 1 MW-17 • MW-27 • CELL 2 33 PIEZ-2 PIEZ-3 • • 0TW4-1fcTW4-11 OTW4-13 TW4-7*.e OTW4•1 PIEZ-4 • PIEZ-5 • • Energy Fuels Resources (USA) Inc. 11/24/1~ RE Aulhor: White Mesa Mill e: Utah Annual Tailings System, Cell Solution Sample Locations lo: 11/24/15 ~ G:i a:: <Xl 32 " en C a.. en 3: "'C ,; ~ ::, en Ll: -e 0 a. " a:: !a '6 I- a ::, C } C " E ., en C C C ::. ., C> :§ ·o / ., a. C ::. ~ ~ C "' ., ::. ~ .r;; ~ ~ ::, / Q) I: ::, 0 U1 ~ U1 CELL 1 LEAK DETECTION SAMPLE LOCATION 4-21 PIEZ-2 PIEZ-3 • • .,..!:======~=============:........:tti.~:i~ T\'lf4-lD OTW4-0 CELL 48 SLIME O<-& LF.AJ( cTf:CTi()N SI\MP1 E LOct1r10N MW-03 • 500' 0 600' SCALE: 1" • 1,000' 1,000' MW-17 • M ·28 tw4.1cf1'W4-9 o OTW4""3 CTW4-12 CELL 2 33 OTW4•1foTW4-11 O'TW4-13 • TW4•.,m-8 OTW4-1 OTW4-4mw4-14 OTW4-6 PIEZ-5 • l!:IJF Energy Fuels Resources (USA) Inc . REVISIONS Date By roJect: White Mesa Mill San Juan late: Utah oca ion: T37S, R22E Author. Annual Tailings System Slimes and Leak Detection Sample Locations ale: 11/24/15 Attachment 2 10 Field Data Record-Tailings Solutions, LDS and Slimes Drain Sampling Location: _________ Sampling Personnel: ________ _ Is this a Slimes Drain? D Yes D No If this is a Slimes Drain, measure depth to wastewater immediately before sampling. DTW immediately before sampling (slimes only): ___________ _ Weather Conditions at Time of Sampling: ________________ _ Analytical Parameters/Sample Collection Method: Parametter Sample Takien Pike-Teel ialmub l\fretlto:cl L.al Per.idttl.1ic: Pump Dai'lv Lmlffe, ~me voes D Yes D No D Yes DNo D D D Metals D Yes DNo D Yes DNo D D D Nutrients D Yes D No o Yes D No D D D Other Non D Yes D No D Yes D No D D D Radiologies Gross Alpha D Yes D No o Yes D No D D D SVOCs o Yes oNo o Yes DNo D D D pH/Conductivity o Yes oNo o Yes D No D D D QC Samples Associated with this Location: o Rinsate Blank o Duplicate Duplicate Sample Name: ___________ _ Notes: --------------------------------- Appendix M Contingency Plan, 12/11 Revision: DUSA-4 White Mesa Mill -Standard Operating Procedures Book# 19---Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 1 of 15 WHITE MESA URANIUM MILL CONTINGENCY PLAN As Contemplated by Part I.G.4(d) of State of Utah Groundwater Discharge Permit No.UGW370004 Prepared by: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver CO 80265 December 2, 2010 White Mesa Mill-Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures TABLE OF CONTENTS Date: 12/11 Revision: DUSA-4 Page 2 of 15 1.0 INTRODUCTION ................................................................................................... 3 2.0 PURPOSE ................................................................................................................ 3 3.0 GROUNDWATER CONTAMINATION ............................................................... 3 3.1 Notification ........................................................................................................... 4 3.2 Continuation of Accelerated Monitoring ............................................................. 4 3.3 Submission of Plan and Timetable ....................................................................... 4 3.4 Groundwater Remediation Plan ........................................................................... 5 4.0 Mil,L DISCHARGE VIOLATIONS -INCLUDING UNAUTHORIZED DISCHARGE OR RELEASE OF PROHIBITED CONT AMIN ANTS TO THE T AIT.,IN G CELLS ................................................... -............................................................ 6 4.1 Notifications ......................................................................................................... 6 4.2 Field Activities ..................................................................................................... 6 4.3 Request for Approvals and/or Waivers ................................................................ 7 5.0 DMT VIOLATIONS ............................................................................................... 7 5.1 Tailings Cell Wastewater Pool Elevation Above the Maximum Elevations ....... 7 5.2 Excess Head in Tailings Cells 2, 3, 4A, and 4B Slimes Drain Systems .............. 8 5.3 Excess Cell 4A Leak Detection System Fluid Head or Daily Leak Rate ............ 9 5.4 Excess Cell 4B Leak Detection System Fluid Head or Daily Leak Rate ........... 10 5.5 Excess New Decontamination Pad Leak Detection System Fluid Head ........... 11 5.6 Cracks or Physical Discrepancies on New Decontamination Pad Wash Pad .... 11 5.7 Excess Elevation For Tailings Solids ................................................................. 12 5.8 Roberts Pond Wastewater Elevation .................................................................. 13 5.9 Feedstock Storage Area ...................................................................................... 13 5.10 Mill Site Chemical Reagent Storage .............................................................. 14 5.11 Failure to Construct as per Approval.. ............................................................ 15 5.12 Failure to Comply with Stormwater Management and Spill Control Requirements ............................................................................ _ ..................................... 15 White Mesa Mill -Standard Operating Procedures Book# 19-Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 3 of 15 WHITE MESA URANIUM MILL CONTINGENCY PLAN State of Utah Groundwater Discharge Permit No. UGW370004 1.0 INTRODUCTION The State of Utah has granted Ground Water Discharge Permit No. UGW370004 (the "GWDP") for Denison Mines (USA) Corp.'s ("Denison's") White Mesa Uranium Mill (the "Mill"). The GWDP specifies the construction, operation, and monitoring requirements for all facilities at the Mill that have a potential to discharge pollutants directly or indirectly into the underlying aquifer. 2.0 PURPOSE This Contingency Plan (the "Plan") provides a detailed list of actions Denison will take to regain compliance with GWDP limits and Discharge Minimization Technology Plan ("DMT") and the Best Available Technology Plan ("BAT") requirements defined in Parts I.C, I.D, and I.H.4 of the GWDP. The timely execution of contingency and corrective actions outlined in this Plan will provide Denison with the basis to exercise the Affirmative Action Defense provision in Part I.G.3.c) of the GWDP and thereby avoid noncompliance status and potential enforcement action 1• The contingency actions required to regain compliance with GWDP limits and DMT and BAT requirements defined in Parts I.C, I.D, and I.H.4 of the GWDP are described below. 3.0 GROUNDWATER CONTAMINATION Since there are many different possible scenarios that could potentially give rise to groundwater contamination, and since the development and implementation of a remediation program will normally be specific to each particular scenario, this Plan does not outline a definitive remediation program. Rather, this Plan describes the steps that 1 Part I.G.3.c) of the GWDP provides that, in the event a compliance action is initiated against Denison for violation of permit conditions relating to best available technology or DMT, Denison may affirmatively defend against that action by demonstrating that it has made appropriate notifications, that the failure was not intentional or caused by Denison' s negligence, that Denison has taken adequate measures to meet permit conditions in a timely manner or has submitted an adequate plan and schedule for meeting permit conditions, and that the provisions ofUCA 19-5-107 have not been violated. White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 4 of 15 will be followed by Denison in the event Denison is found to be out of compliance with respect to any constituent in any monitoring well, pursuant to Part I.G.2 of the GWDP. When the concentration of any parameter in a compliance monitoring well is out of compliance, Denison will, subject to specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: 3.1 Notification Denison will notify the Executive Secretary of the out of compliance status within 24 hours after detection of that status followed by a written notice within 5 days after detection, as required under Part I.G.4.a) of the GWDP. 3.2 Continuation of Accelerated Monitoring Denison will continue accelerated sampling for the parameter in that compliance monitoring well pursuant to Part I.G.1 of the GWDP, unless the Executive Secretary determines that other periodic sampling is appropriate, until the facility is brought into compliance, as required under Part I.G.4.b) of the GWDP. If the accelerated monitoring demonstrates that the monitoring well has returned to compliance with respect to a parameter in a wen, then, with written approval from the Executive Secretary, Denison will cease accelerated monitoring for that parameter, and will continue routine monitoring for that parameter. 3.3 Submission of Plan and Timetable If the accelerated monitoring confirms that the Mill is out of compliance with respect to a parameter in a well, then, within 30 days of such confirmation, Denison will prepare and submit to the Executive Secretary a plan and a time schedule for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain ground water quality to ensure that permit limits will not be exceeded at the compliance monitoring point and that DMT or BAT will be reestablished, as required under part I.G .4.c) of the GWDP. This plan will normally include, but is not limited to: a) The requirement for Denison to prepare a detailed and comprehensive operational history of the facility and surrounding areas which explores all activities that may have contributed to the contamination; White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 5 of 15 b) A requirement for Denison to complete an evaluation, which may include geochemical and hydrogeological analyses, to determine whether or not the contamination was caused by Mill activities or was caused by natural forces or offsite activities; c) If it is concluded that the contamination is the result of current or past activities at the Mill, Denison will prepare a Characterization Report, which characterizes the physical, chemical, and radiological extent of the ground water contamination. This will normally include a description of any additional wells to be used or installed to characterize the plume and the hydrogeologic characteristics of the affected zone, the analytical parameters to be obtained, the samples of ground water to be taken, and any other means to measure and characterize the affected ground water and contamination zone; and d) If it is concluded that the contamination is the result of current or past activities at the Mill, Denison will evaluate potential remedial actions, including actions to restore and maintain groundwater quality to ensure that permit limits will not be exceeded at the compliance monitoring point and that DMT and BAT will be reestablished, as well as actions that merely allow natural attenuation to operate and actions that involve applying for Alternate Concentration Limits ("ACLs"). ACLs require approval of the Water Quality Board prior to becoming effective. If groundwater remediation is required, Denison will prepare and submit for Executive Secretary approval a Ground Water Remediation Plan, as described in Section 3 .4 below. 3.4 Groundwater Remediation Plan If the Executive Secretary determines that ground water remediation is needed, Denison will submit a Ground Water Remediation Plan to the Executive Secretary within the time frame requested by the Executive Secretary. The Ground Water Remediation Plan will normally include, but is not limited to: a) A description and schedule of how Denison will implement a corrective action program that prevents contaminants from exceeding the ground water protection levels or ACLs at the compliance monitoring point(s) or other locations approved by the Executive Secretary, by removing the contaminants, treating them in place, or by other means as approved by the Executive Secretary; b) A description of the remediation monitoring program to demonstrate the effectiveness of the plan; and c) Descriptions of how corrective action will apply to each source of the pollution. White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 6 of 15 Denison will implement the Ground Water Remediation Plan in accordance with a schedule to be submitted by Denison and approved by the Executive Secretary. 4.0 MILL DISCHARGE VIOLATIONS -INCLUDING UNAUTHORIZED DISCHARGE OR RELEASE OF PROHIBITED CONTAMINANTS TO THE TAILING CELLS Part I.C.2. of the GWDP provides that only 1 le.(2) by-product material authorized by the Mill's State of Utah Radioactive Materials License No. UT-2300478 (the "Radioactive Materials License") shall be discharged to or disposed of in the Mill's tailings cells. Part I.C.3 of the GWDP provides that discharge of other compounds into the Mill's tailings cells, such as paints, used oil, antifreeze, pesticides, or any other contaminant not defined as 1 le.(2) material is prohibited. In the event of any unauthorized disposal of contaminants or wastes (the "Unauthorized Materials'') to the Mill's tailings cells, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: 4.1 Notifications a) Upon discovery, the Mill Manager or RSO will be notified immediately; and b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery. 4.2 Field Activities a) Upon discovery, Mill personnel will immediately cease placement of Unauthorized Materials into the Mill's tailings cells; b) To the extent reasonably practicable and in a manner that can be accomplished safely, Mill personnel will attempt to segregate the Unauthorized Materials from other tailings materials and mark or record the location of the Unauthorized Materials in the tailings cells. If it is not reasonably practicable to safely segregate the Unauthorized Material from other tailings materials, Mill personnel will nevertheless mark or record the location of the Unauthorized Materials in the tailings cells; White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 7 of 15 c) To the extent reasonably practicable and in a manner that can be accomplished safely, Mill personnel will attempt to remove the Unauthorized Material from the tailings cells; and d) Denison will dispose of the removed Unauthorized Material under applicable State and Federal regulations with the approval of the Executive Secretary. 4.3 Request for Approvals and/or Waivers If it is not reasonably practicable to safely remove the Unauthorized Materials from the tailings cells, then Denison will, in accordance with a schedule to be approved by the Executive Secretary: a) Submit a written report to the Executive Secretary analyzing the health, safety and environmental impacts, if any, associated with the permanent disposal of the Unauthorized Material in the Mill's tailings cells; b) Apply to the Executive Secretary for any amendments that may be required to the GWDP and the Radioactive Materials License to properly accommodate the permanent disposal of the Unauthorized Material in the Mill's tailings cells in a manner that is protective of health, safety and the environment; and c) Make all applications required under the United States Nuclear Regulatory Commission's ("NRC's") Non-lle.(2) Disposal Policy (NRC Regulatory Issue Summary 2000-23 (November 2000), Interim Guidance on Disposal of Non- Atomic Energy Act of 1954, Section 11 e. (2) Byproduct Material in Tailings Impoundments), including obtaining approval of the Department of Energy as the long term custodian of the Mill's tailings, in order to obtain approval to permanent! y dispose of the Unauthorized Material in the Mill's tailings cells. 5.0 DMT VIOLATIONS 5.1 Tailings Cell Wastewater Pool Elevation Above the Maximum Elevations Part I.D.2 and Part I.D.6.d) of the GWDP provide that authorized operation and maximum disposal capacity in each of the existing tailings cells shall not exceed the levels authorized by the Radioactive Materials License and that under no circumstances shall the freeboard be less than three feet, as measured from the top of the flexible membrane liner ("FML"). White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 8 of 15 In the event that tailings cell wastewater pool elevation in any tailings cell exceeds the maximum elevations mandated by Part I.D.2 and Part I.D.6.d) of the GWDP, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; c) Upon discovery, Mill personnel will cease to discharge any further tailings to the subject tailings cell, until such time as adequate freeboard capacity exists in the subject tailings cell for the disposal of the tailings; d) To the extent reasonably practicable, without causing a violation of the freeboard limit in any other tailings cell, Mill personnel will promptly pump fluids from the subject tailings cell to another tailings cell until such time as the freeboard limit for the subject tailings cell is in compliance. If there is no room available in another tailings cell, without violating the freeboard limit of such other cell, then, as soon as reasonably practicable, Mill personnel will cease to discharge any further tailings to any tailings cell until such time as adequate freeboard capacity exists in all tailings cells; e) If it is not reasonably practicable to pump sufficient solutions from the subject tailings cell to another tailings cell, then the solution levels in the subject tailings cell will be reduced through natural evaporation; and f) Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to minimize the chance of a recurrence. 5.2 Excess Head in Tailings Cells 2, 3, 4A, and 4B Slimes Drain Systems Part I.D.3.b)l) of the GWDP provides that Denison shall at all times maintain the average wastewater head in the slimes drain access pipe in Cell 2 to be as low as reasonably achievable, in accordance with the Mill's currently approved DMT Monitoring Plan, and that for Cell 3, this requirement shall apply only after initiation of de-watering operations. Similarly, Part I.D.6.c) of the GWDP provides that after Denison initiates pumping conditions in the slimes drain layer in Cell 4A, Denison will provide: 1) continuous declining fluid heads in the slimes drain layer, in a manner equivalent to the requirements found in Part I.D.3.b); and 2) a maximum head of 1.0 feet in the tailings (as measured from the lowest point of the upper FML) in 6.4 years or less. White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 9 of 15 In the event that the average wastewater head in the slimes drain access pipe for Cell 2 or, after initiation of de-watering activities, Cell 3 or initiation of pumping conditions in the slimes drain layer in Cell 4A exceeds the levels specified in the DMT Monitoring Plan, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Mill personnel will promptly pump the excess fluid into an active tailings cell, or other appropriate containment or evaporation facility approved by the Executive Secretary; c) If the exceedance is the result of equipment failure, Mill personnel will attempt to repair or replace the equipment; d) If the cause of the exceedance is not rectified within 24 hours, Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; and e) If not due to an identified equipment failure, Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to minimize the chance of a recurrence. 5.3 Excess Cell 4A Leak Detection System Fluid Head or Daily Leak Rate Part I.D.6.a) provides that the fluid head in the Leak Detection System ("LDS") for Cell 4A shall not exceed 1 foot above the lowest point in the lower membrane liner, and Part I.D.6.b) of the GWDP provides that the maximum allowable daily leak rate measured in the LDS for Cell 4A shall not exceed 24,160 gallons/day. In the event that the fluid head in the LOS for Cell 4A exceeds 1 foot above the lowest point in the lower membrane layer or the daily leak rate measured in the Cell 4A LDS exceeds 24,160 gallons/day, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Mill personnel will promptly pump the excess fluid into an active tailings cell, or other appropriate containment or evaporation facility approved by the Executive Secretary, until such time as the cause of exceedance is rectified or until such time as otherwise directed by the Executive Secretary; White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/1 l Revision: DUSA-4 Page IO of 15 c) If the exceedance is the result of equipment failure, Mill personnel will attempt to repair or replace the equipment; d) If the cause of the exceedance is not rectified within 24 hours, Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; and e) If not due to an identified equipment failure, Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to remediate the exceedance and to minimize the chance of a recurrence. 5.4 Excess Cell 4B Leak Detection System Fluid Head or Daily Leak Rate Part I.D.13.a) provides that the fluid head in the Leak Detection System ("LDS") for Cell 4B shall not exceed 1 foot above the lowest point in the lower membrane liner, and Part I.D.13.b) of the GWDP provides that the maximum allowable daily leak rate measured in the LDS for Cell 4B shall not exceed 26,145 gallons/day. In the event that the fluid head in the LDS for Cell 4B exceeds 1 foot above the lowest point in the lower membrane layer or the daily leak rate measured in the Cell 4B LDS exceeds 26,145 gallons/day, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Mill personnel will promptly pump the excess fluid into an active tailings cell, or other appropriate containment or evaporation facility approved by the Executive Secretary, until such time as the cause of exceedance is rectified or until such time as otherwise directed by the Executive Secretary; c) If the exceedance is the result of equipment failure, Mill personnel will attempt to repair or replace the equipment; d) If the cause of the exceedance is not rectified within 24 hours, Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; and If not due to an identified equipment failure, Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to remediate the exceedance and to minimize the chance of a recurrence. White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 11 of 15 5.5 Excess New Decontamination Pad Leak Detection System Fluid Head In order to ensure that the primary containment of the New Decontamination Pad water collection system has not been compromised, and to provide an inspection capability to detect leakage from the primary containment in each of the three settling tanks, a vertical inspection portal has been installed between the primary and secondary containment of each settling tank. Section 3.l(e) of the Mill's DMT Monitoring Plan provides that the fluid head in the LDS for the New Decontamination Pad shall not exceed 0.10 feet above the concrete floor in any of the three standpipes. Compliance is defined in Part I.D.14 a) of the GWDP as a depth to standing water present in any of the LDS access pipes of more than or equal to 6.2 feet as measured from the water measuring point (top of access pipe). In the event that the fluid head in the standpipe for a settling tank exceeds 0.10 feet above the concrete floor in the standpipe, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; c) Mill personnel will promptly pump the fluid from the settling tank's LDS as well as the fluids in the settling tank into another settling tank or into an active tailings ce11, or other appropriate containment or evaporation facility approved by the Executive Secretary, until such time as the cause of the exceedance is rectified or until such time as otherwise directed by the Executive Secretary; and d) Denison will perform a root cause analysis of the exceedance and, if appropriate, will implement new procedures or change existing procedures to remediate the exceedance and to minimize the chance of a recurrence. 5.6 Cracks or Physical Discrepancies on New Decontamination Pad Wash Pad. Soil and debris will be removed form the wash pad of the NDP in accordance with the currently approved DMT Monitoring Plan. In the event that cracks of greater than 1/8 inch (width) are observed on the concrete wash pad, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 12 of 15 a) Upon discovery, the Mill Manager or RSO will be notified immediately; · b) The NDP shall be taken out of service and the cracks will be repaired utilizing industry standard materials and procedures appropriate for the defect within five working days of discovery. Following recommended cure times, the cracks or deficiencies will be re-inspected and, if acceptable, the NDP will be placed back into service. c) A record of the repairs will be maintained as a part of the inspection records at the White Mesa Mill. 5.7 Excess Elevation For Tailings Solids Part I.D.3.c) of the GWDP provides that upon closure of any tailings cell, Denison shall ensure that the maximum elevation of the tailings waste solids does not exceed the top of the FML. In the event that, upon closure of any tailings cell, the maximum elevation of the tailings waste solids exceeds the top of the FML, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; c) To the extent reasonably practicable, without causing a violation of the freeboard limit in any other tailings cell, Mill personnel will promptly remove tailings solids from the subject tailings cell to another tailings cell, or other location approved by the Executive Secretary, until such time as the maximum elevation of the tailings waste solids in the subject tailings cell does not exceed the top of the FML; and d) Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to minimize the chance of a recurrence. White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures 5.8 Roberts Pond Wastewater Elevation Date: 12/11 Revision: DUSA-4 Page 13 of 15 Part I.D.3.e) of the GWDP provides that the Permittee shall operate Roberts Pond so as to provide a minimum 2-foot freeboard at all times and that under no circumstances shall the water level in Roberts Pond exceed an elevation of 5,624 feet above mean sea level. In the event that the wastewater elevation exceeds this maximum level, Denison shall remove the excess wastewater and place it into containment in Tailings Cell 1 within 72 hours of discovery, as specified in Part I.D.3.e) of the GWDP. In the event that, Denison fails to remove the excess wastewater within 72 hours of discovery, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; and b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification and proposed corrective actions within five days of discovery. 5.9 Feedstock Storage Area Part I.D.3.f) and Part I.D.11 of the GWDP provide that open-air or bulk storage of all feedstock materials at the Mill facility awaiting Mill processing shall be limited to the eastern portion of the Mill site area described in Table 4 of the GWDP, and that storage of feedstock materials at the facility outside that area shall be performed in accordance with the provisions of Part I.D.11 of the GWDP. In the event that, storage of any feedstock at the Mill is not in compliance with the requirements specified in Part I.D.3.f) and Part I.D.11 of the GWDP, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; c) Mill personnel will: White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 14 of 15 (i) move any open-air or bulk stored feedstock materials to the portion of the Mill site area described in Table 4 of the GWDP; (ii) ensure that any feedstock materials that are stored outside of the area described in Table 4 of the GWDP are stored and maintained in accordance with the provisions of Part I.D.11 of the GWDP; and (iii) to the extent that any such containers are observed to be leaking, such leaking containers will be placed into watertight over-pack containers or otherwise dealt with in accordance with the provisions of Part I.D.11 of the GWDP, and any impacted soils will be removed and will be deposited into the Mill's active tailings cell; and d) Denison will perform a root cause analysis of the non-compliant activity and will implement new procedures or change existing procedures to minimize the chance of a recurrence. 5.10 Mill Site Chemical Reagent Storage Part I.D.3.g) of the GWDP provides that for all chemical reagents stored at existing storage facilities, Denison shall provide secondary containment to capture and contain all volumes of reagent(s) that might be released at any individual storage area, and that for any new construction of reagent storage facilities, the secondary containment and control shall prevent any contact of the spilled reagent with the ground surface. In the event that Denison fails to provide the required secondary containment required under Part I.D.3.g) of the GWDP, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; and c) Denison will promptly remediate any spilled re-agent resulting from the failure to provide the required secondary containment under Part I.D.3.g) of the GWDP, by removal of the contaminated soil and disposal in the active tailings cell. White Mesa Mill -Standard Operating Procedures Book# 19 -Groundwater Discharge Permit Plans and Procedures 5.11 Failure to Construct as per Approval Date: 12/11 Revision: DUSA-4 Page 15 of 15 Part I.D.4 of the GWDP provides that any construction, modification, or operation of new waste or wastewater disposal, treatment, or storage facilities shall require submittal of engineering design plans and specifications, and prior Executive Secretary review and approval, and that a Construction Permit may be issued. In the event that, any new waste or wastewater disposal, treatment, or storage facilities are constructed at the Mill facility without obtaining prior Executive Secretary review and approval, or any such facilities are not constructed in accordance with the provisions of any applicable Construction Permit, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; and b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification and proposed corrective actions within five days of discovery. 5.12 Failure to Comply with Stormwater Management and Spill Control Requirements Part I.D.10 of the GWDP provides that Denison will manage all contact and non-contact stormwater and control contaminant spills at the Mill facility in accordance with the currently approved Stormwater Best Management Practices Plan. In the event that any contact or non-contact stormwater or contaminant spills are not managed in accordance with the Mill's approved Stormwater Best Management Practices Plan, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification and proposed corrective actions within five days of discovery; and c) To the extent still practicable at the time of discovery, Denison will manage any such contaminant spill in accordance with the Mill's approved Stormwater Best Management Practices Plan. To the extent it is no longer practicable to so manage any such spill, Denison will agree with the Executive Secretary on appropriate clean up and other measures. Appendix N White Mesa Mill Containerized Alternate Feedstock Material Storage Procedure, PBL-19, Revision: 3.0, March 1, 2017 • No.: PBL-19 ENERGY FUELS RESOURCES (USA) INC. Rev. No.: 3 STANDARD OPERATING PROCEDURES Page 1 of 3 Date: March 1, Title: Feed Material Receipt/Storage Procedure 2017 1.0 Purpose The purpose of this procedure is to assure that the receipt and storage of feed materials is conducted in a manner so as to preclude the release of Mill feed material to the environment. 2.0 Scope Feed materials delivered to the White Mesa Mill must be stored in a manner which precludes the release of the materials to the environment. In the case of bulk materials, such as unrefined natural ores and alternate feeds delivered in inter-modal containers, these materials are offloaded from the truck or shipping container directly onto the approved ore pad where migration of material is precluded by the pad's design and operating procedures (i.e. low permeability pad material, dust control procedures and limited stockpile height). However, certain feeds are received in drums or other containers which serve to effectively contain the material during storage and, as such, are amenable for storage either on the ore pad or at locations other than the ore pad. It is the intent of this procedure to describe the environmental safety precautions utilized for contained feed storage. 3.0 Procedure 3.1 Feed Material Inspections All feed materials received at the White Mesa Mill are inspected upon arrival, prior to entering the Restricted Area, to determine that the containers and/or conveyances are not leaking and to assure container integrity prior to placing the material into storage. Each container and/or conveyance will be observed on all sides for damage or leakage of contents. If any container and/or conveyance has signs of leakage, the inspector must notify the RSO, or their designee, immediately. The RSO, or their designee, will make the determination through visual observation and radiological assessment if a leak has occurred. If a leak has occurred, the RSO, or their designee, will make the proper notifications to Corporate Management and regulatory agencies and complete page 2 of the Feed Material Receipt form. All containers exhibiting signs of leakage will be re- packed or placed in over-pack containers prior to placing the materials into storage. Dented drums are acceptable if the dent is not located near a seam or when the dent is not accompanied by a damage crease on the drum surface. Drums damaged by dents near the seam, crease damaged drums or containers that have been otherwise compromised during shipment are re-packed or placed in over-pack containers prior to storage. Containers which are not damaged at the time of receipt are transferred directly for placement at the storage location. No.: PBL-19 Rev. No.: 3 Date: March 1, 2017 3.2 ENERGY FUELS RESOURCES (USA) INC. STANDARD OPERATING PROCEDURES Page 2 of 3 Title: Feed Material Receipt/Storage Procedure Storage Localions 3.2.1 Defined Feedstock Storage Feedstock materials stored at the defined storage location indicated on the map attached hereto as Attachment A) the "Defined Feedstock Area" can be stored in containers or in bulk form and are subject to the routine inspections described by the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan of the Mill's Environmental Protection Manual. 3.2.2 Storage of Contained Feeds in Location Other Than the Defined Feedstock Area a) Over-pack Container Materials received or transferred into over-pack containers can be stored at locations other than the Defined Feedstock Area absent a hardened ground surface or containment berms due to the fact that the over-pack container provides a secondary containment for the packaged material. Over-pack materials are subject to the routine inspections described by the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan. b) Hardened Surface Storage Locations Contained feed materials, including materials in containers which have not been provided with over-pack protection, can be stored at locations other than the Defined Feedstock Area when a hardened ground surface storage location is used and has been provided with containment berms. These materials are subject to the routine inspections described by the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan. c) Single Lined Containers Stored Outside the Defined Feedstock Area Where Hardened Surfaces and Containment Berms Are Not Utilized Contained feeds can also be stored in locations, other than the Defined Feedstock Area, that have been selected to avoid impact by site drainage and/or pooling. Prior to storage at these locations, planks or pallets are placed beneath the drum storage locations in order to raise the container from the ground surface and avoid corrosion from water which may accumulate during precipitation events ( despite site selection) and from rusting due to soil moisture when drums are stored directly on the ground. These contained materials are subject to the more particular storage protocols and inspections outlined below. No.: PBL-19 ENERGY FUELS RESOURCES (USA) INC. Rev. No.: 3 STANDARD OPERATING PROCEDURES Page 3 of 3 Date: March 1, Title: Feed Material Receipt/Storage Procedure 2017 3.3 Storage ProtocoJ Sfogle Lined Containers 3.4 3.5 In accordance with MSHA requirements, container storage must be implemented in such a manner as to limit the potential for a container to tip or fall onto a worker. For drummed materials, the agency limits such stacks to three drums in height due to stability considerations. In keeping with these concerns, EFR will configure single lined storage drums (stored off the Designated Feedstock Area) in rows no more than two containers wide at the base and may place a one- container row either on top of a single row or in the middle of a lower two- container row, in each case so as to straddle the tops of drums in the lower container row(s). This stacking configuration distributes the single upper row across bottom row(s) of containers in such a manner as to hold the bottom row(s) from leaning and allowing for limited stacking on top of these lower row(s). accordingly, when stacking is necessary, this configuration minimizes the risk of falling drums, limits stacking height for safety reasons and allows for a thorough inspection of each of the individual containers from the outside of the container row(s). Single Lined Container Storage Area Inspections The single lined container storage area(s) that are off of the Designated Feedstock Area will be inspected on a weekly basis (and after significant precipitation events) on both sides of any row in order to assure that the stored materials remain intact, that standing water has not accumulated and that materials are not leaking or migrating from the storage area. Single Lined Container Storage Inspection Records EFR will record all instances where single lined containers are received damaged ( or leaking) and require re-packing or the provision of an over-pack container. This information will be recorded on a container receipt form (see Attachment B) which documents the receipt of drummed materials to be stored in locations other than the Defined Feedstock Area. Similarly, each weekly inspection shall be recorded on the inspection form referred to in the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan at Attachment A-3 and attached as Attachment C to this procedure. Such inspections require the documentation of container condition, the drainage conditions in the storage location, the presence of leakage, if any, and any corrective actions taken due to leakage of containers or standing water at the storage location. Attachment A ( .. )rftJi:I -, --- ) :. ) • le: l/T Attachment B ( • j ! " ··~) Feed Material Receipt Inspection Date: ------------------- j Inspector: ---------- Is the shipment leaking? Yes or No If Yes, complete the other side of this document. Number of containers/drums in shipment: ________ _ Radiation Activity Levels: ---------- Location of Storage: ------------- Corrective Action Taken for Damaged Drums: Observations (note dented or damaged drums) Inspector:---------- (Print Name) (Signature) Feed Material Receipt Inspection Name of generator of shipment: ----------- Bill of Lading#:--------------- Activity in Curies:---------------- Radionuclides: ----------------- The amount of material that leak out of the package (if known): The amount of material that leak out of the conveyance (if known): Can it be determined when the leak occurred? Corrective Actions: RSO: -------- (Print Name) (Signature) Attachment C • / •, \ ' ·, _;,,' White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT A-3 12/16 Revision: EFRI 12.4 Page 19 of25 ORE STORAGE/SAMPLE PLANT WEEKLY INSPECTION REPORT Week of ____ through ____ Date of Inspection: _______ _ Inspector: ___________ _ Weather conditions for the week: Blowing dust conditions for the week: Corrective actions needed or taken for the week: Are all bulk feedstock materials stored in the area indicated on the attached diagram: yes: no: ___ _ comments: ___________________________________ _ Are all alternate feedstock materials located outside the area indicated on the attached diagram maintained within water-tight containers: yes: no: __ _ comments (e.g., conditions of containers): _________________ _ Are all sumps and low lying areas free of standing solutions? Yes: No: __ _ If "No", how was the situation corrected, supervisor contacted and correction date? Is there free standing water or water running off of the feedstock stockpiles? Yes: No: __ _ Comments: __________________________________ _ • White Mesa Mill -Discharge Minimization Technology Monitoring Plan Ore Pad Stonnwater Transfer Line: Is the transfer line visible? Yes: No: __ _ 12/16 Revision: EFRI 12.4 Page 20 of25 Comments: __________________________________ _ Is there any evidence of breakage, spillage or leakage? Yes: No: __ _ Comments: __________________________________ _ Other comments: Ore Pad Southwest Stormwater Containment (Kiva): Is there sediment or debris in the bottom of the Kiva? Yes: No: __ _ CommeJ1ts: __________________________________ _ Is the sediment or debris level below the bottom of the outlet line? If the sediment/debris is greater than 3 inches deep, complete a work order to have the Kiva cleaned out. If there is significant debris (tumble weeds or trash present, complete a work order to have the Kiva cleaned out. Yes: No: __ _ Comments: __________________________________ _ Appendix 0 White Mesa Mill Chemical Inventory Location Key Chem Lab CL Maintenance Shop/Warehouse MSW Bulk Around the Mill Mill Location CL CL CL CL CL CL CL CL CL CL CL CL Chemical Name Alcohol, Reagent Aluminum Nitrate Solution Compressed Gas (Argon) Compressed Gas (Nitrogen) Hydrochloric acid Hydroflouric Acid Isa-Octane Mercuric Nitrate ( .1410 N) Nitric Acid Perchloric Acid Phosphoric Acid Sulfuric Acid Appendix 0-1 Laboratory Chemical Inventory1 Historic volume or mass used Current Volume and Mass at the Mill (1978 -2013) Density 1cm 3 -1 Quantity Unit g/cm3 Volume mL Quantity Unit 32 kg 0.79 40 L 4,156 L 291,685 g 1.401 55 gal 1457 L 74,400 cf * * * 497,364 cf 26,190 cf * * * 152,775 cf 23,000 g 1.15 20,000 mL 4,826 L 2,500 g 1.25 2,000 mL 231 L 17 kg 0.692 24 L 1,304 L 20,400 g 1.02 20,000 mL 274 L 35,500 g 1.42 25,000 mL 3,109 L 8,368 g 1.6736 5,000 mL 1,487 L 4,700 g 1.88 2,500 mL 1,665 L 18,300 g 1.83 10,000 mL 2,245 L Total historic Historic volume volume or mass or mass used used (1978 - (2014 -2022) 2022) Quantity Unit Quantity Unit 1,712 L 5,868 L 240 L 1697 L 595,187 cf 1,092,551 cf 342,652 cf 495,427 cf 97 L 4,923 L 104 L 335 L 816 L 2,120 L 232 L 506 L 732 L 3,841 L 266 L 1,753 L 296 L 1,961 L 183 L 2,428 L 1 Part 1.E.9 states that "The Permittee shall monitor and maintain a current inventory of all chemicals used at the facility at rates equal to or greater than 100 kg/yr." Previous chemical inventories inadvertantly included all chemical in the laboratory regardless of usage rate. This inventory has been modified to include only those chemicals that meet the Part 1.E.9 usage rate. Inclusion in this inventory is based on the highest annual usage from 2014 through May 2022 exceeding 100 kg/yr and/or more than 100 kg total usage for the period of 2014 -May 2022. * Pursuant to Section I.E.9b) of the GWDP dated August 24, 2012, the Permittee shall provide "Determination of volume and mass of each raw chemical currently held in storage at the facility." Both mass and volume are provided when specific gravity data are available. Laboratory chemicals are stored in the laboratory or in the laboratory storage areas adjacent to the laboratory. Abbreviations: gal = gallons cf= cubic feet ml = milliliters g = grams kg = kilograms L = liters Appendix 0-2 Current Mill Chemical Inventory Historic volume or Historic volume or Total historic volume mass used (1978 -mass used (2014 -or mass used (1978 - Current Volume and Mass at the Mill 4 2013) 2022) 2022) Quantity Specific Gravity Approximate Location Chemical Name (lbs) or Bulk Density Volume (gals) Quantity Unit Quantity Unit Quantity Unit Alamine 336 Drums and Mill Totes2 0 0.80 sp.g 0 1,538,782 lbs 134,109 lbs 1,672,891 lbs Mill Ammonia (East and West) 183,662 5.68 lb/gal 32,335 34,861 ,910 lbs 6,258,243 lbs 41 ,120,153 lbs Ammonium sulfate (North Mill and South) 92,124 1.76 sp.g 6,284 44,266,008 lbs 6,305,875 lbs 50,571,883 lbs Ammonium Sulfate Super Mill Sacks 0 1.76 sp.g 0 :j: lbs 13,200 lbs :j: lbs Mill Barium Chloride 27,000 3.86 sp.g 840 0 lbs 78,364 lbs 78,364 lbs Boiler Salt (Sure Soft NaCl Mill or equivalent) 45,790 63 lbs/cu ft 727 cu ft 0 lbs 136,910 lbs 136,910 lbs Mill Cyanex 801 397 0.96 sp.g 50 0 lbs 13,889 lbs 13,889 lbs Sodium Hydroxide 50% Mill (Caustic) 84,496 1.50 sp.g 6,762 42,332,116 lbs 9,154,782 lbs 51,486,898 lbs Sodium Hydroxide (Solid Mill caustic) 898,415 2.13 sp.g 50,635 0 lbs 942,771 lbs 942,771 lbs De-Scaler (ChemTreat BL Mill 122 or equivalent) 232 1.16 sp.g 200 3,960 lbs 0 lbs 3,960 lbs Mill Armeen 380 Totes 0 0.82 sp.g 0 0 lbs 83,531 lbs 83,531 lbs Diatomaceous Earth Filter Mill Aid 12,480 2.30 sp.g 651 1,000,000 lbs 6,240 lbs 1,006,240 lbs Mill DEHPA 0 0.98 sp.g 0 0 lbs 31,676 lbs 31,676 lbs Mill Flocculant 6551 23,100 0.80 sp.g 3,466 1,149,225 lbs 44,550 lbs 1,193,775 lbs Mill Flocculant 314 8,150 0.80 sp.g 1,223 0 lbs 0 lbs 0 lbs Hydrochloric Acid (Tanks Mill and Totes) 1,143 9.83 lb/gal 116 98,300 lbs 2,201 ,060 lbs 2,299,360 lbs Mill Hydrogen Peroxide 50% 1,000 1.20 sp.g 100 537,973 lbs 135,432 lbs 673,405 lbs Mill Hyper Floe 757 Coagulant 0 0.80 sp.g 0 1,395 lbs 0 lbs 1,395 lbs Mill Hyperfloc 624 2,300 0.80 sp.g 345 0 lbs 4,600 lbs 4,600 lbs Mill Kerosene 123,392 6.80 lb/gal 18,146 15,067,139 lbs 5,243,276 lbs 20,310,415 lbs Appendix 0-2 Current Mill Chemical Inventory Historic volume or Historic volume or Total historic volume mass used (1978-mass used (2014 -or mass used (1978 - Current Volume and Mass at the Mill4 2013) 2022) 2022) Quantity Specific Gravity Approximate Location Chemical Name (lbs) or Bulk Density Volume (gals) Quantity Unit Quantity Unit Quantity Unit Mill Liquified Natural Gas 65,739 0.55 sp.g 14,245 23,371,465 lbs 16,241,163 lbs 39,612,628 lbs Mill Perlite Filter Aid 3,888 2.30 sp.g 203 604,158 lbs 156,669 lbs 760,827 lbs Mill Propane 75,182 0.50 sp.g 17,908 7,309,158 lbs 1,286,955 lbs 8,596,113 lbs Mill Salt 149,634 2.16 sp.g 8,316 63,111,955 lbs 13,230,595 lbs 76,342,549 lbs Mill Soda ash silo 131,544 0.99 sp.g 15,951 76,472,417 lbs 20,210,604 lbs 96,683,021 lbs Mill Soda ash Super Sacks 2,000 0.99 sp.g 243 :j: lbs 188,000 lbs 188,000 lbs Sodium chlorate Tanks 1-3 Mill (50% Solution) 95,649 1.45 sp.g 7,919 30,978,629 lbs 3,572,595 lbs 34,551,224 lbs Sodium Chlorate Super Mill Sacks 0 1.32 sp.g 0 :j: lbs 0 lbs :j: lbs Mill Sulfuric Acid 94% 5,734,000 1.84 sp.g 374,106 757,297,581 lbs 96,146,376 lbs 853,443,956 lbs Mill Tertiary amine 2 8,818 0.80 1,323 0 lbs 61,729 lbs 61,729 lbs sp.g Mill Tri-decyl alcohol 3 26,484 0.83 sp.g 3,831 967,383 lbs 222,535 lbs 1,189,918 lbs 1The Mill uses a number of comparable polymer flocculants depending on the specific feed. 2 The Mill has and may continue to use other tertiary amines with comparable chemical properties. 3Current alcohol used as modifier. Alternatively, the Mill has and may continue to use other secondary and tertiary alcohols, including isodecanol, among others, to improve tertiary amine/U/kerosene solubility. 4 Pursuant to Section I.E.9b) of the GWDP dated August 24, 2012, the Permittee shall provide "Determination of volume and mass of each raw chemical currently held in storage at the facility." Both mass and volume are provided when specific gravity data are available. :j: -Historic values reported are the total quantity used at all locations. The historic quantities are reported as a single total for the first location listed. Abbreviations: lbs= pounds lb/gal -pounds per gallon sp.g = specific gravity Appendix 0-3 Cleaners and Maintenance/Miscellaneous Chemicals1 Total historic volume Historic volume or mass Historic volume or mass or mass used (1978- Current used (1978 -2013) used (2014 -2022) 2022) Location Cleaners Quantity Units Quantity Unit Quantity Unit Quantity Unit MSW #2 EP Grease Shell Retinax LXZ 0 lbs 3300 lbs 796 lbs 4,096 lbs MSW #5182 Pyroshield Grease / oil 240 lbs 21660 lbs 840 lbs 22,500 lbs MSW 150 Gear Oil 110 gal 4312 gal 220 gal 4,532 gal MSW 15-40w Motor Oil 165 gal 8435 gal 1265 gal 9,700 gal MSW 220 Gear Oil 91 gal 26000 gal 1943 gal 27,943 gal MSW 30w motor oil Rotella T 55 gal 2805 gal 385 gal 3,190 gal MSW 460 Gear Oil 267 gal 6718 gal 613 gal 7,331 gal MSW 5w-30 synthetic blend oil 55 gal 421 gal 275 gal 696 gal MSW 680 gear oil 165 gal 17514 gal 770 gal 18,284 gal MSW Acetylene bottle 1,173 cf 141008 cf 6701 cf 147,709 cf MSW Anti-Freeze 165 gal 4,377 gal 495 gal 4,872 gal MSW Argon mixed gas 660 cf 63,114 cf 6,930 cf 70,044 cf MSW Argon T-large 331 cf 27,074 cf 3,972 cf 31,046 cf MSW Bredel hose lubricant 98 gal 2,857 gal 522 gal 3,379 gal MSW Fantastik 2.5 gal 1,777 gal 229 gal 2,006 gal MSW Ferric Chloride 0 gal 660 gal 304 gal 964 gal MSW Go-Jo hand cleaner 0 lbs 4,004 lbs 243 lbs 4,247 lbs MSW Grease tubes 0.65625 lbs 6,874 lbs 1,480 lbs 8,354 lbs MSW Hydraulic oil #68 165 gal 18,467 gal 1,650 gal 20,117 gal MSW Laundry Soap 330 lbs 72,996 lbs 8,760 lbs 81,756 lbs MSW Lysol 1.875 gal 1,543 gal 258 gal 1,801 gal MSW Methyl Ethyl Ketone #366 0 gal 3,286 gal 165 gal 3,451 gal MSW Oil absorbent floor dry 100 lbs 31,800 lbs 5,925 lbs 37,725 lbs MSW Oxygen Cylinder TOX 2,310 cf 303,600 cf 21,450 cf 325,050 cf MSW Sullair Coolent 40 gal 2,259 gal 345 gal 2,604 gal MSW Sweeping compound oil base 25 lbs 29,066 lbs 975 lbs 30,041 lbs MSW T-Chlor liquid chlorine 12% 40 gal 96 gal 765 gal 861 gal MSW Windshield washer fluid 6 gal 1,053 gal 252 gal 1,305 gal Appendix 0-3 1 Part 1.E.9 states that "The Permittee shall monitor and maintain a current inventory of all chemicals used at the facility at rates equal to or greater than 100 kg/yr." Previous chemical inventories inadvertantly included all chemical in the laboratory regardless of usage rate. This inventory has been modified to include only those chemicals that meet the Part 1.E.9 usage rate. Inclusion in this inventory is based on the highest annual usage from 2014 through May 2022 exceeding 100 kg/yr and/or more than 100 kg total usage for the period of 2014 -May 2022. Abbreviations: lbs= pounds gal = gallons cf = cubic feet Location of Storage or Use Leach circuit UraniumSX UraniumSX Appendix 0-4 Historic/Formerly Used Chemicals Chemicals Formerly Used at Mill/No Longer Used or Present on Site 1 Time Period of Total Quantity Chemical Form Use Used 2 Several months Dry solid in during 1997 or No more than several Ammonium Bi-fluoride SuperSaks 1998 thousand lbs. Several months during 1997 or No more than 2,000 J-Mt primary amine Drummed Liquid 1998 gallons Several months Tri octyl phosphine during 1997 or No more than 2,000 oxide ("TOPO") Drummed liquid 1998 gallons Current Status None on site since 1998 None on site since 1998 . None on site since 1998 1. These reagents were used during processing of one alternate feed for 6 months in 1997 /1998, and have not been used before or since. 2. Total quantities used are also the total quantities purchased over life of the alternate feed project, that is, total on site was this quantitiy or less. 3. Unused residual consumed from 1997 to 1999 for cleaning purposes.