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HomeMy WebLinkAboutDRC-2022-018843 - 0901a068810b89f6D1,",, .-,:.,-.,,.,., r.rl ;-,:;: : *:""fl nfituil.;,-ir'i., :,,,-,-t ;.,,r,!ii-if lf r,Jr-iL 1 B Zi;;iI r -@F.'*YFUEL. Energy Fuels Resources (USA) Inc' 225 Union Blvd. Suite 600 Lakewood, CO,US' 80228 3Mn42140 gusl*gnetgyfucl$"com Jnly 13,2022 Sent VIA EXPEDITED DELMRY Mr. Doug Hansen Director Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116 Re: Transmittal of Hydrogeology Report for the White Mesa Uranium Mill, Blanding Utah Pursuant to Part [V.D of the Utah Groundwater Discharge Permit. Dear Mr. Hansen: Enclosed are two copies of the Energy Fuels Resources (USA) Inc. ("EFRI") White Mesa Uranium Mill Hydrogeology Report for the facility and surrounding area, pursuant to Part IV.D of the Utah Groundwater Discharge Permit ("GWDP"). The revised Hydrogeology Report incorporates the relevant information from studies conducted at the White Mesa Mill since the submission of the previous Hydrogeology Report. If you should have any questions regarding this report, please contact me at 303-389-4t34. Yours very truly, t*tlq-;-t''{ ENnncv Furr,s RBsouncrs (USA) INC. Kathy Weinel Director, Regulatory Compliance CC: Scott Bakken David Frydenlund Logan Shumway Garrin Palmer Teny Slade Stewart Smith (HGC) i liiinlhiri iiJltiUriiT#'r DRC-2022-018843 HYDRO GEO CHEM, INC. Environmental Science & Technology HYDROGEOLOGY OF THE WHITE MESA URANIUM MILL BLANDING, UTAH July 13, 2022 Prepared for: ENERGY FUELS RESOURCES (USA) INC. 225 Union Boulevard, Suite 600 Lakewood, Colorado 80228 (303) 628-7798 Prepared by: HYDRO GEO CHEM, INC. 51 W. Wetmore, Suite 101 Tucson, Arizona 85705-1678 (520) 293-1500 Project Number 7180000.00-02.0 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 i TABLE OF CONTENTS 1. INTRODUCTION .............................................................................................................. 1 2. BACKGROUND AND OVERVIEW ................................................................................ 3 2.1 Overview of Site Hydrogeology ............................................................................. 5 2.1.1 Geology/Stratigraphy .................................................................................. 5 2.1.2 Hydrogeologic Setting ................................................................................ 6 2.1.3 Perched Water Zone .................................................................................... 7 2.1.4 Seeps and Springs in Relation to Perched Zone Hydrogeology ............... 11 2.1.5 Tailings Management System ................................................................... 13 3. DETAILED SITE HYDROGEOLOGY ........................................................................... 15 3.1 Stratigraphy and Formation Characteristics .......................................................... 15 3.1.1 Brushy Basin Member .............................................................................. 15 3.1.2 Burro Canyon Formation/Dakota Sandstone ............................................ 15 3.1.2.1 Dakota Sandstone....................................................................... 16 3.1.2.2 Burro Canyon Formation ........................................................... 17 3.1.3 Mancos Shale ............................................................................................ 19 3.1.4 Pyrite Occurrence in the Dakota Sandstone and Burro Canyon Formation .................................................................................... 21 3.2 Contact Descriptions ............................................................................................. 22 3.2.1 Brushy Basin Member/Burro Canyon Formation Contact Elevations ..... 22 3.2.2 Mancos Shale/Dakota Contact Elevations ................................................ 23 3.2.3 Soils Above the Dakota and /or Mancos................................................... 24 3.3 Perched Water Elevations, Saturated Thicknesses, and Depths to Water ............ 25 3.4 Interpretation of Cross-Sections ........................................................................... 26 3.4.1 Central and Northeast Areas ..................................................................... 26 3.4.2 Southwest Area ......................................................................................... 27 3.5 Perched Water Occurrence and Flow ................................................................... 28 3.5.1 Overview ................................................................................................... 28 3.5.1.1 General Site Flow Pattern .......................................................... 29 3.5.1.2 Influence of Pumping and Wildlife Pond Seepage on Flow and Dissolved Constituent Concentrations ...................... 30 3.5.2 Nitrate Investigation Area ......................................................................... 34 3.5.3 Vicinity of Chloroform Plume .................................................................. 36 3.5.4 Beneath and Downgradient of the Tailings Management System ............ 43 3.5.4.1 Overview .................................................................................... 43 3.5.4.2 Water Balance Near DR-2 and DR-5......................................... 44 3.5.4.3 Water Balance Near Ruin Spring and Westwater Seep ............. 46 3.6 Perched Water Migration Rates and Travel Times ............................................... 48 3.6.1 Nitrate Investigation Area ......................................................................... 48 3.6.2 Vicinity of Chloroform Plume .................................................................. 49 3.6.3 Beneath and Downgradient of Tailings Management System .................. 50 3.6.3.1 Vadose Zone .............................................................................. 51 3.6.3.2 Perched Water Zone Downgradient of Tailings Management System ................................................................. 52 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 ii TABLE OF CONTENTS (Continued) 3.7 Implications for Seeps and Springs....................................................................... 54 3.7.1 Westwater Seep and Ruin Spring ............................................................. 54 3.7.2 Cottonwood Seep ...................................................................................... 55 3.7.3 Potential Dilution of Perched Water Resulting from Local Recharge of the Dakota and Burro Canyon Near Seeps and Springs ....... 56 3.8 Implications for Transport of Chloroform and Nitrate ......................................... 57 4. COMPOSITION OF DAKOTA SANDSTONE AND BURRO CANYON FORMATION ................................................................................................. 59 4.1 Mineralogy ............................................................................................................ 59 4.2 Pyrite Occurrence.................................................................................................. 59 4.3 Expected Influence of Transient Conditions, Oxygen Introduction, and the Mancos and Brushy Basin Shales on Dakota/Burro Canyon Chemistry .............. 61 4.4 Implications for Perched Water Chemistry and Natural Attenuation of Nitrate and Chloroform ......................................................................................... 65 4.4.1 Pyrite Degradation by Oxygen .................................................................. 65 4.4.2 Nitrate Degradation by Pyrite ................................................................... 66 4.4.2.1 Other Relevant Studies Regarding Nitrate Reduction by Pyrite .................................................................................... 69 4.4.2.2 Comparison to Oostrum Site ...................................................... 70 4.4.3 Chloroform Reduction .............................................................................. 71 5. SUMMARY OF PERCHED GROUNDWATER MONITORING AND STUDIES ...... 73 5.1 Chloroform Plume ................................................................................................ 74 5.2 Nitrate Plume ........................................................................................................ 75 5.3 MW-24A Study ..................................................................................................... 77 5.4 Proposed Phase 2 Study ........................................................................................ 79 6. SUMMARY AND CONCLUSIONS REGARDING MILL HYDROGEOLOGY ......... 81 6.1 Perched Water Pore Velocities in the Nitrate Plume Area ................................... 89 6.2 Perched Water Pore Velocities in the Vicinity of the Chloroform Plume ............ 89 6.3 Hydrogeology and Perched Water Pore Velocities in the Southwest Area .......... 90 6.4 Fate of Chloroform and Nitrate............................................................................. 91 7. PROPOSED CELLS 5A AND 5B .................................................................................... 93 8. REFERENCES ................................................................................................................. 95 9. LIMITATIONS STATEMENT ...................................................................................... 105 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 iii TABLE OF CONTENTS (Continued) TABLES 1 Results of Slug test Analyses Using KGS and Bouwer-Rice Solutions 2 Results of Recovery and Slug Test Analyses Using Moench Solution 3 Estimated Perched Zone Hydraulic Properties Based on Analysis of Observation Wells Near MW-4 and TW4-19 During Long Term Pumping of MW-4 and TW4-19 4 Summary of Hydraulic Properties White Mesa Uranium Mill from TITAN (1994) 5 Properties of the Dakota/Burro Canyon Formation White Mesa Uranium Mill from TITAN (1994) 6 Hydraulic Conductivity Estimates for Spring Flow Calculations 7 Hydraulic Conductivity Estimates for Travel Time Calculations Paths 1, 2A, and 2B 8 Hydraulic Conductivity Estimates for Travel Time Calculations Paths 3-6 9 Estimated Perched Zone Pore Velocities Along Path Lines 10 Results of XRD and Sulfur Analysis in Weight Percent 11 Tabulation of Presence of Pyrite, Iron Oxide, and Carbonaceous Fragments in Drill Logs 12 Sulfide Analysis by Optical Microscopy 13 Summary of Pyrite in Drill Cuttings and Core 14 Summary of Nitrate Degradation Rates 15 Pyrite Contents in samples From White Mesa Mill and Oostrum, Netherlands Site FIGURES 1A White Mesa Site Plan Showing Location of Perched Wells, Piezometers, Lithologic Cross-Sections (as of Q4, 2021) And Proposed New Cells 5A and 5B. 1B White Mesa Site Plan Showing Location of Perched Wells, Piezometers, and Nitrate and Chloroform Plume Boundaries 2 Lithologic Column 3 White Mesa Stratigraphic Section Based on Lithology of WW-3 from TITAN (1994) 4 Photograph of the Contact Between the Burro Canyon formation and the Brushy Basin Member 5 Kriged 4th Quarter, 2021 Water Levels, White Mesa Site 6 Annotated Photograph Showing East Side of Cottonwood Canyon (looking east toward White Mesa from west side of Cottonwood Canyon) 7 Extent of the Western Interior Sea (Cretaceous) 8 Kriged Top of Brushy Basin, White Mesa Site 9A Kriged Top of Bedrock, White Mesa Site 9B Kriged Top of Bedrock Using Revised Depth to Mancos Data, White Mesa Site 10 Kriged Top of Dakota Sandstone, White Mesa Site 11A Kriged Top of Bedrock Showing Approximate Mancos Thickness, White Mesa Site 11B Kriged Top of Bedrock Showing Approximate Revised Mancos Thickness, White Mesa Site Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 iv TABLE OF CONTENTS (Continued) FIGURES (Continued) 12 Approximate Geoprobe Boring and Cross-Section Locations, White Mesa Site 13 Soil Cross Sections East of Ammonium Sulfate Crystal Tanks, White Mesa Site 14 4th Quarter, 2021 Perched Zone Saturated Thicknesses and Brushy Basin Paleoridges and Paleovalleys, White Mesa Site 15 4th Quarter, 2021 Depths to Perched Water, White Mesa Site 16A Interpretive Northeast-Southeast Cross Section (NE-SW), White Mesa Site 16B Interpretive Northeast-Southwest Cross Section (NE2-SW2), White Mesa Site 17 Interpretive Northwest-Southeast Cross Section (NW-SE), White Mesa Site 18A Interpretive East-West Cross Sections (W-E and W2-E2) Southwest Investigation Area 18B Interpretive East-West Cross Section (WNW-ESE) Southwest Investigation Area 19 Interpretive North-South Cross Sections (S-N) Southwest Investigation Area 20 DR Series Piezometer Depths to Water 2Q 2011 to 4Q 2021 21 Kriged 4thQuarter, 2021 Water Levels Showing Inferred Perched Water Pathlines and Kriged Nitrate and Chloroform Plumes 22 Kriged 4th Quarter, 2021 Water Levels and Estimated Capture Zones, White Mesa Site (detail map) 23 Kriged 4th Quarter, 2011 Water Levels, White Mesa Site 24 TW4-4 and TW4-6 Water Levels 25 Kriged 4th Quarter, 2021 Water Levels Showing Inferred Perched Water Pathlines Downgradient of the Tailings Management System, White Mesa Site 26 Kriged 4th Quarter, 2021 Water Levels Showing Inferred Perched Water Flow Pathlines Near Ruin Spring and Westwater Seep 27 Kriged 4th Quarter, 2021 Water Levels Showing Inferred Perched Water Flow used for Travel Time Estimates and Kriged Nitrate and Chloroform Plumes 28 Photograph of the Westwater Seep Sampling Location July 2010 29 Photograph of the Contact Between the Burro Canyon Formation and the Brushy Basin Member at Westwater Seep 30 Kriged 4th Quarter, 2021 Water Levels showing Kriged Nitrate and Chloroform Plumes and Inferred Perched Water Pathlines, White Mesa Site 31 Water Level in Wells Near TW4-27 32 White Mesa Site Plan Showing Pyrite Occurrence in Perched Borings 33 Proposed New Cell 5A and 5B Monitoring Wells and Piezometer, White Mesa Site Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 v TABLE OF CONTENTS (Continued) APPENDICES A Lithologic Logs B Well Construction Schematics C INTERA Soil Boring Logs D Historic Water Level Maps (Seep and Spring Elevations Not Considered in Contouring) E Topographic and Geologic Maps F Hydrogeology Beneath Proposed Cells 5A and 5B and Proposed New Monitoring Installations Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 vi Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 1 1. INTRODUCTION This report provides an update to the July 11, 2018 report Hydrogeology of the White Mesa Uranium Mill, Blanding Utah, and Recommended Locations of New Perched Wells to Monitor Proposed Cells 5A and 5B (the 2018 Hydrogeologic Report; HGC [2018d]). The present report incorporates all the elements of the 2018 Hydrogeologic Report with appropriate updates. Section 7 includes updates provided in HGC (2018e) and HGC (2019a) regarding additional monitoring installations for proposed new cells 5A and 5B. The proposed new installations are subject to change as approval of the final design is pending. The present report considers the additional hydrogeologic data collected at the site from the first quarter of 2018 through the fourth quarter of 2021. Calculations provided in the 2018 Hydrogeologic Report are updated based on the more recent data. Some of the additional data and updated calculations include: 1. Quarterly perched water level and analytical (chloroform and nitrate concentration) data; 2. Lithologic data collected from wells MW-24A, MW-38 through MW-40, TW4-40 through TW4-43, and TWN-20 and TWN-21; 3. Hydraulic test data collected from wells MW-24A, MW-38 through MW-40, TW4-40 through TW4-43, and TWN-20 and TWN-21; 4. Rates of perched groundwater movement and conservative solute travel times, in particular within the southwest portion of the site (downgradient of the tailings management system [TMS]); 5. Perched water balance calculations in the southwest portion of the site; 6. Pyrite occurrence; 7. Changes in chloroform and nitrate plumes; and 8. Chloroform and nitrate degradation rates. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 2 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 3 2. BACKGROUND AND OVERVIEW Figure 1A is a site map showing general site features and the locations of perched groundwater wells and piezometers (as of the fourth quarter of 2021), springs, and lithologic cross-sections. Figure 1B shows fourth quarter, 2021 kriged perched groundwater elevation contours and the kriged fourth quarter 2021 boundaries of the chloroform and nitrate plumes at the site. Since the time period covered by the previous (2018) Hydrogeologic Report, monitoring wells MW-38, MW-39, and MW-40 were installed in the southeastern portion of the site (between MW-17 and MW-22) during the first quarter of 2018 (HGC, 2018c). These wells are located far cross-gradient of the tailings management system (TMS). Also during the first quarter of 2018, two new chloroform wells (TW4-40 and TW4-41) were installed as discussed in HGC (2018b). Chloroform well TW4-40 was installed approximately 200 feet south of TW4-26 and chloroform pumping well TW4-41 was installed immediately north-northeast of TW4-4 to augment pumping in the vicinity of TW4-4. In addition, chloroform monitoring well TW4-42 was installed approximately 200 feet south of TW4-40 during April, 2019 (HGC, 2019b); nitrate monitoring wells TWN-20 and TWN-21 were installed west of TWN-7 during April, 2021 (HGC, 2021a); and chloroform monitoring well TW4-43 was installed approximately 200 feet east-southeast of TW4-30 during September, 2021 (HGC, 2021b). Hydrogeologic investigation of the site has been ongoing since the initial investigation in 1977- 1978 (Dames and Moore, 1978). Major hydrogeologic and groundwater investigations include Dames and Moore (1978); UMETCO (1993); UMETCO (1994); TITAN (1994); International Uranium (USA) Corporation (IUSA) and Hydro Geo Chem, Inc. (HGC) [2000]; IUSA and HGC (2001); HGC (2004); HGC (2007b); INTERA (2007a); INTERA (2007b); INTERA (2008); Hurst and Solomon (2008); INTERA (2009); HGC (2010g); INTERA (2012a); INTERA (2012b); HGC (2012b); HGC (2012c); HGC (2014a); HGC (2014b); and HGC (2018d). Investigations to date and more than 41 years of perched groundwater monitoring indicate that operation of the TMS (cells 1 through 4B in Figures 1A and 1B) has not impacted perched groundwater. The lack of impact is detailed in Hurst and Solomon (2008) and various INTERA documents (INTERA, 2007a; INTERA 2007b; INTERA, 2008; INTERA, 2010; INTERA, 2012a; INTERA 2012b; INTERA, 2013a; INTERA, 2013b; INTERA, 2014a; INTERA, 2014b; INTERA, 2014c; INTERA, 2015; INTERA, 2016; INTERA, 2017; INTERA, 2018; INTERA,2019a; INTERA, 2019b; INTERA, 2019c; and INTERA, 2020). Additional documents demonstrating the lack of impact include EFRI, 2020; EFRI, 2021a; EFRI 2021c; EFRI, 2022a; and EFRI, 2022d. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 4 Perched groundwater was impacted by operation of a temporary laboratory facility that was located at the site prior to and during the construction of the Mill, and from septic drain fields that were used for laboratory and sanitary wastes prior to operation of the Mill’s TMS circa 1980 (HGC, 2007b; HGC, 2022). Laboratory wastes prior to 1980 were first disposed to the abandoned scale house leach field, and later to the former office leach field. Disposal of laboratory wastes to the abandoned scale house and former office leach fields is considered the source of the chloroform plume (defined by concentrations greater than 70 micrograms per liter [µg/L]) located upgradient to cross-gradient (northeast to east) of the TMS (Figure 1B). The eastern portion of the chloroform plume likely originated from the abandoned scale house leach field (located immediately north-northwest of TW4-18 [Figure 1B]), and the western portion from the former office leach field (located in the immediate vicinity of TW4-19 [Figure 1B]). Perched groundwater has also been impacted by nitrate (INTERA, 2009). The nitrate plume (Figure 1B), defined by concentrations greater than 10 milligrams per liter (mg/L), contains elevated chloride (exceeding 100 mg/L) and extends from upgradient (northeast) of the TMS to a portion of the area beneath the TMS as described in the Nitrate Corrective Action Plan (nitrate CAP)[HGC, 2012a]. The precise source(s) of the nitrate plume are not well defined. However, the footprint of a former agricultural/stock watering pond referred to as the ‘historical pond’ is located beneath the upgradient portion of the nitrate plume and extends to the north of the plume (Figure 1B). This pond was active from the early part of the 20th century until the area was re- graded as part of Mill construction circa 1980 (HGC, 2012a). This pond is considered one of the likely historical sources of nitrate and chloride to the nitrate plume. Ammonium sulfate handling in the vicinity of the ammonium sulfate crystal tanks (southeast of TWN-2 [Figures 1A and 1B]) is considered the only potential Mill contribution of nitrate to the nitrate plume and has been addressed through implementation of Phase 1 of the nitrate CAP [HGC (2012a) and EFRI (2013)]. The chloroform and nitrate plumes have been under remediation by pumping since 2003 and 2013, respectively. Actions taken by the Mill are consistent with the preliminary chloroform CAP (HGC, 2012a) and final GCAP (Utah Department of Environmental Quality Division of Solid Waste and Radiation Control [DWMRC], 2015; and with the nitrate CAP (HGC, 2012a). Because the northwestern portion of the chloroform plume commingles with the central portion of the nitrate plume, the effects of the pumping systems overlap, and the initiation of nitrate pumping in 2013 caused redistribution of chloroform as discussed in HGC (2022). Both plumes are discussed in more detail in Sections 3, 4, and 5. Appendix A contains copies of lithologic logs from site perched monitoring wells and piezometers. Appendix B contains copies of perched well construction schematics. Appendix C Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 5 contains logs of borings installed by INTERA as part of the nitrate investigation that supported the nitrate CAP. Logs of soil borings installed per Phase I of the nitrate CAP are provided in EFRI (2013). 2.1 Overview of Site Hydrogeology TITAN (1994) provides a detailed description of site hydrogeology based on information available at that time. A brief summary of site hydrogeology that is based in part on TITAN (1994) and updated with information from the literature and more recent site investigations is provided below. 2.1.1 Geology/Stratigraphy The White Mesa Uranium Mill is located within the Blanding Basin (the Basin) of the Colorado Plateau physiographic province. Bedrock units exposed in the Basin include Upper Jurassic through Cretaceous sedimentary rocks (Figure 2, from Doelling, 2004). The general succession, in ascending order, is the Upper Jurassic Morrison Formation, the Lower Cretaceous Burro Canyon Formation, and the Upper Cretaceous Dakota Sandstone and Mancos Shale. Most exposures of the Morrison Formation consist of the Brushy Basin Member. Typical of large portions of the Colorado Plateau province, the rocks within the Basin are relatively undeformed. The Mill has an average elevation of approximately 5,600 feet above mean sea level (ft amsl) and is underlain by unconsolidated alluvium and indurated sedimentary rocks. Indurated rocks include those exposed within the Basin (described above), and consist primarily of sandstone and shale. The indurated rocks are relatively flat lying with dips generally less than 3º. The alluvial materials consist primarily of aeolian silts and fine-grained aeolian sands with a thickness varying from a few feet to as much as 25 to 30 feet across the site. The alluvium is underlain by the Dakota Sandstone and Burro Canyon Formation, and where present, the Mancos Shale. The Dakota and Burro Canyon are sandstones having a total thickness ranging from approximately 55 to 140 feet, and, because of their similarity, are typically not distinguished in lithologic logs at the site. Beneath the Burro Canyon Formation lies the Morrison Formation, consisting, in descending order, of the Brushy Basin Member, the Westwater Canyon Member, the Recapture Member, and the Salt Wash Member. The Brushy Basin and Recapture Members of the Morrison Formation, classified as shales, are very fine-grained, have a very low permeability, and are considered aquicludes. The Brushy Basin Member is primarily composed of bentonitic mudstones, siltstones, and claystones. The Westwater Canyon and Salt Wash Members also have a low average vertical permeability due to the presence of interbedded shales. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 6 Beneath the Morrison Formation lie the Summerville Formation, an argillaceous sandstone with interbedded shales, and the Entrada Sandstone. Beneath the Entrada lies the Navajo Sandstone. The Navajo and Entrada Sandstones constitute the primary aquifer in the vicinity of the site. The Entrada and Navajo Sandstones are separated from the Burro Canyon Formation by approximately 1,000 to 1,100 feet of materials having a low average vertical permeability. Groundwater within this system is under artesian pressure in the vicinity of the site, is of generally good quality, and is used as a secondary source of water at the site. Stratigraphic relationships beneath the site are summarized in Figure 3 (adapted from TITAN, 1994 and based on the lithology of water supply well WW-3, located just northwest of TWN-2 [Figure 1A]). The Upper Jurassic Morrison Formation is the youngest Jurassic unit in the Basin. In many places an unconformity separates the Morrison Formation from underlying Middle Jurassic strata. The Morrison was deposited in a variety of depositional environments, ranging from aeolian to fluvial and lacustrine. Much of the Morrison is composed of fluvial sandstone and mudstone that have sources to the west and southwest of the Basin (Peterson and Turner- Peterson, 1987). The upper Brushy Basin Member (a bentonitic shale), was deposited in a combination of lacustrine and marginal lacustrine environments (Turner and Fishman, 1991). The contact between the Morrison Formation and overlying strata has been subject to discussion. In the southeastern part of the Basin, the Lower Cretaceous Burro Canyon Formation overlies the Morrison Formation. The contact between the Burro Canyon Formation and the Morrison Formation has been interpreted as a disconformity (Young, 1960); however, Tschudy et al., (1984) indicated that the Burro Canyon Formation may be a continuation of deposition of the Morrison Formation. More recent studies by Aubrey (1992) also suggest interfingering between the Morrison Formation and overlying units. Kirby (2008) indicates that the contact between the Morrison Formation and the Burro Canyon Formation (between the Brushy Basin Member of the Morrison and the Burro Canyon Formation) near Blanding, Utah is disconformable with “local erosional relief of several feet”. Data collected from perched borings at the site that penetrate the Brushy Basin Member are consistent with a disconformable, erosional contact in agreement with Kirby (2008). 2.1.2 Hydrogeologic Setting The site and vicinity has a dry to arid continental climate, with an average annual precipitation of approximately 13.3 inches, and an average annual lake evaporation rate of approximately 47.6 inches. Recharge to major aquifers (such as the Entrada/Navajo) occurs primarily along the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 7 mountain fronts (for example, the Henry, Abajo, and La Sal Mountains), and along the flanks of folds such as Comb Ridge Monocline. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth (approximately 1,200 feet below land surface [ft bls]) makes access difficult. The Navajo/Entrada aquifer is capable of yielding significant quantities of water to wells (hundreds of gallons per minute [gpm]). Water in WW-series supply wells completed across these units at the site rises approximately 800 feet above the base of the overlying Summerville Formation (TITAN, 1994). 2.1.3 Perched Water Zone Perched groundwater occurs within the Dakota Sandstone and Burro Canyon Formation beneath the site and is used on a limited basis to the north (upgradient) of the site because it is more easily accessible than the Navajo/Entrada aquifer. Perched groundwater originates mainly from precipitation and local recharge sources such as unlined reservoirs (Kirby, 2008) and is supported within the Burro Canyon Formation by the underlying aquiclude (Brushy Basin Member of the Morrison Formation). Water quality of the Dakota Sandstone and Burro Canyon Formation is generally poor due to high total dissolved solids (TDS) in the range of approximately 1,100 to 7,900 milligrams per liter (mg/L), and is used primarily for stock watering and irrigation. The saturated thickness of the perched water zone generally increases to the north of the site, increasing the yield of the perched zone to wells installed north of the site. The generally low permeability of the perched zone limits well yields. Although sustainable yields of as much as 4 gallons per minute (gpm) have been achieved in site wells penetrating higher transmissivity zones near unlined wildlife ponds, yields are typically low (<1/2 gpm) due to the generally low permeability of the perched zone. Even site wells that yielded as much as 4 gpm during the first few months of pumping eventually saw yields drop to about 1 gpm or less. As of the fourth quarter of 2021, total sustainable pumping from the 16 wells comprising the chloroform and nitrate pumping systems was just under 6 gpm. In addition, many of the perched monitoring wells purge dry and take several hours to more than a day to recover sufficiently for groundwater samples to be collected. During redevelopment (HGC, 2011b) many of the perched wells went dry during surging and bailing and required several sessions on subsequent days to remove the proper volumes of water. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 8 Although perched groundwater extends into the overlying Dakota Sandstone within areas having greater saturated thicknesses, perched groundwater at the site is hosted primarily by the Burro Canyon Formation, which consists of a relatively hard to hard, fine- to medium-grained sandstone containing siltstone, shale and conglomeratic materials. As discussed above, the Burro Canyon Formation is separated from the underlying regional Navajo/Entrada aquifer by approximately 1,000 to 1,100 feet of Morrison Formation and Summerville Formation materials having a low average vertical permeability. As discussed above, the Brushy Basin Member of the Morrison Formation (a bentonitic shale), lying immediately beneath the Burro Canyon Formation, forms the base of the perched water zone at the site. Figure 4 is a photograph of the contact between the Burro Canyon Formation and the underlying Brushy Basin Member taken from a location along Highway 95 north of the Mill. This photograph illustrates the transition from the cliff-forming sandstone of the Burro Canyon Formation to the slope-forming Brushy Basin Member. Figure 5 is a perched groundwater elevation contour map generated from fourth quarter, 2021 data. Historic water level maps based on data from 1990, 1994 and 2002 are provided in Appendix D. Note that maps shown in Appendix D are based only on water levels from perched zone wells and do not include seep and spring elevations. As shown in Figure 5 and Appendix D, perched water flow across the site is generally from northeast to southwest. This general flow pattern has been consistent based on perched water level data collected beginning with the initial site investigation described in Dames and Moore (1978). Perched water discharges in seeps and springs located to the west, southwest, east, and southeast of the site. Beneath and south of the TMS, in the west central portion of the site, perched water flow is south-southwest to west-southwest. Flow on the western margin of the mesa south of the TMS is generally southerly, approximately parallel to the mesa rim (where the Burro Canyon Formation is terminated by erosion). On the eastern side of the site perched water flow is also generally southerly to southwesterly. Perched water flow beneath and downgradient of the Mill site and TMS is influenced by perched water discharge points Westwater Seep, located west to west-southwest of the TMS, and Ruin Spring, located southwest of the TMS. The overall southwesterly flow pattern is locally influenced by former seepage from the unlined wildlife ponds. Because of relict mounding near the northern wildlife ponds, flow direction ranges from locally westerly (west of the ponds) to locally easterly (east of the ponds). Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 9 In general, perched groundwater elevations have not changed significantly at most of the site monitoring wells since installation, except in the vicinity of the three unlined wildlife ponds and sixteen pumping wells (shown in Figures 1A and 1B). For example, relatively large increases in water levels occurred between 1994 and 2002 at MW-4 and MW-19, located in the east and northeast portions of the site, as discussed in HGC (2007b). These water level increases in the northeastern and eastern portions of the site were the result of seepage from the northern wildlife ponds. Piezometers PIEZ-1 through PIEZ-5, shown in Figure 5, were installed in 2001 to investigate these changes. The mounding associated with the wildlife ponds and the general increase in water levels in the northeastern portion of the site resulted in a local steepening of groundwater gradients near the ponds. Since the first quarter of 2012, after water delivery to the two northern wildlife ponds ceased, the perched groundwater mound associated with these ponds (the northern mound) began to diminish. In addition, reduced water delivery to the southern wildlife pond caused the associated perched groundwater mound (the southern mound) to diminish. Since the first quarter of 2012, water levels have declined within the northern mound by as much as 25 feet (at PIEZ-2), and within the southern mound by more than 23 feet (at PIEZ-5). The decay of the groundwater mounds associated with the wildlife ponds has caused reductions in hydraulic gradients over those portions of the site that experienced prior increases resulting from former water delivery to the ponds. Although use of these ponds specifically as wildlife ponds began in the early 1990s, the northernmost pond contained water as least as early as 1984 (based on aerial photography). The 1985 editions of United States Geological Survey (USGS) topographic maps covering the western (Black Mesa Butte map) and eastern (Blanding South map) portions of the Mill property show the Mill buildings but none of the cells within the future TMS. The northern wildlife pond is shown as water-bearing, but the historical pond, which shows up on pre-1978 aerial photography, is not shown. The absence of the historical pond is consistent with the elimination of that pond during regrading as part of Mill construction circa 1979. The features shown on these maps suggest that they are representative of the time period between approximately 1979 and the year the maps were published, 1985. Therefore, based on the features shown on these USGS topographic maps, the northern wildlife pond could have been water bearing as early as about 1979. In addition a perched groundwater mound extending beneath the future Mill site was likely present at the time of the initial site investigation. Dames and Moore (1978) indicated that the depth to water beneath the future Mill site was a relatively shallow 56 ft bls, while depths to water beneath the future TMS were generally greater than 90 ft bls. Dames and Moore (1978) Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 10 also indicated that the hydraulic gradient beneath the future Mill site was a relatively large 0.03 feet per foot (ft/ft), while the hydraulic gradient beneath the future TMS was a more typical 0.01 ft/ft. The relatively shallow depth to water and relatively steep hydraulic gradient beneath the future Mill site are consistent with a perched groundwater mound originating from a source upgradient to the north (historical pond) or northeast (northernmost wildlife pond). In addition to the impacts of wildlife and historical pond seepage on site water levels, pumping of chloroform wells MW-4, MW-26, TW4-1, TW4-2, TW4-4, TW4-11, TW4-19, TW4-20 (now abandoned), TW4-21, TW4-37, TW4-39, TW4-40 and TW4-41; and nitrate wells TW4-22, TW4-24, TW4-25, and TWN-2; has depressed the perched water table locally and contributed to reduced average hydraulic gradients to the south and southwest of these wells. Pumping is designed to remove chloroform and nitrate associated with the chloroform and nitrate plumes shown on Figure 1B. Hydraulic testing of perched zone wells yields a hydraulic conductivity range of approximately 2 x 10-8 to 0.01 centimeters per second (cm/s) as discussed in HGC (2012b). Hydraulic conductivity estimates obtained from perched wells installed and tested subsequent to HGC (2012b) also fall within this range (HGC, 2013a; HGC, 2013b; HGC, 2014c; HGC, 2015; HGC, 2016; HGC, 2018b; HGC, 2018c; HGC, 2019b; HGC, 2020; HGC, 2021a; and HGC, 2021b). Hydraulic conductivity estimates are summarized in Tables 1 through 4. Table 1 provides estimates of hydraulic conductivity from slug test data analyzed using the KGS and Bouwer-Rice solutions available in AQTESOLV (HydroSOLVE, 2000). Table 2 summarizes recovery and slug test data analyzed using the Moench solutions in WHIP (HGC, 1988) and AQTESOLV. The estimates provided in Tables 1 and 2 are based on HGC (2002); HGC (2005); HGC (2010c); HGC (2010d); HGC (2010e); HGC (2010f); HGC (2011a); HGC (2011c); HGC (2013a); HGC (2013b); HGC (2014c); HGC (2015); HGC (2016); HGC (2018b); HGC (2018c); HGC (2019b); HGC (2021a); and HGC (2021b). Table 3 summarizes analyses of test data collected during long-term pumping within the chloroform plume area using the Theis solutions available in AQTESOLV (HGC, 2004). Table 4 (from TITAN, 1994) summarizes hydraulic conductivity estimates based on testing prior to 1994. In general, the highest perched zone permeabilities and well yields are in the area of the site immediately northeast and east (upgradient to cross gradient) of the TMS. A relatively continuous, higher permeability zone associated with the chloroform plume and consisting of poorly indurated (poorly cemented) coarser-grained materials has been inferred to exist in this portion of the site (HGC, 2007b; HGC, 2018a). Because their existence requires both coarse grain size and poor cementation, such relatively continuous, higher permeability zones are expected to be relatively rare at the site. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 11 Perched zone permeabilities downgradient (southwest) of the TMS are generally low. The low permeabilities and relatively shallow hydraulic gradients downgradient of the TMS result in average perched groundwater pore velocity estimates that are among the lowest on site. 2.1.4 Seeps and Springs in Relation to Perched Zone Hydrogeology Hydro Geo Chem (2010g) discusses the relationships between the perched water zone and seeps and springs at the margins of White Mesa. The relationships between seeps and springs and site geology/stratigraphy are provided in Figure E.1 and Figure E.2 of Appendix E. Key findings of HGC (2010g) include the following: 1. Incorporating the seep and spring elevations in perched water elevation contour maps produces little change with regard to perched water flow directions except in the area west of the TMS and near Entrance Spring. West of the TMS, incorporation of Westwater Seep creates a more westerly hydraulic gradient. Westwater Seep appears to be downgradient of the western portion of the TMS (Figure 5); and Ruin Spring is downgradient of the eastern portion of the TMS (Figure 5). Westwater Seep is the closest apparent discharge point west of the TMS and Ruin Spring is the closest discharge point south-southwest of the TMS. Including the Entrance Spring elevation on the east side of the site creates a more easterly gradient in the perched water contours, and places Entrance Spring more directly downgradient of the northern wildlife ponds. Seeps and springs on the east side of the mesa are either cross-gradient of the TMS or are separated from the TMS by a groundwater divide. 2. Ruin Spring and Westwater Seep are interpreted to occur at the contact between the Burro Canyon Formation and the Brushy Basin Member. Corral Canyon Seep, Entrance Spring, and Corral Springs are interpreted to occur at elevations within the Burro Canyon Formation at their respective locations but above the contact with the Brushy Basin Member. All seeps and springs (except Cottonwood Seep which is located within the Morrison Formation near the Brushy Basin Member/Westwater Canyon Member contact) are associated with conglomeratic portions of the Burro Canyon Formation. Provided they are poorly indurated (poorly cemented) the more conglomeratic portions of the Burro Canyon Formation are likely to have higher permeabilities and the ability to transmit water more readily than finer-grained portions. This behavior is consistent with on-site drilling and hydraulic test data that associates higher permeability with the poorly indurated coarser-grained horizons detected east and northeast of the TMS that are associated with the chloroform plume). 3. Cottonwood Seep is located more than 1,500 feet west of the mesa rim in an area where the Dakota Sandstone and Burro Canyon Formation (which hosts the perched water system) are absent due to erosion. Cottonwood Seep occurs near a transition from slope- forming to bench-forming morphology (indicating a change in lithology). Cottonwood Seep (and 2nd Seep located immediately to the north [annotated photograph provided in Figure 6]) are interpreted to originate from coarser-grained materials within the lower portion of the Brushy Basin Member (or upper portion of the Westwater Canyon Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 12 Member) and are therefore not (directly) connected to the perched water system at the site. 4. Only Ruin Spring appears to receive a predominant and relatively consistent proportion of its flow from perched groundwater. Ruin Spring originates from conglomeratic Burro Canyon Formation sandstone where it contacts the underlying Brushy Basin Member, at an elevation above the alluvium in the associated drainage. Westwater Seep, which also originates at the contact between the Burro Canyon Formation and the Brushy Basin Member, likely receives a significant contribution from perched water. All seeps and springs other than Ruin Spring (and 2nd Seep just north of Cottonwood Seep) are located within alluvium occupying the basal portions of small drainages and canyons. The relative contribution of flow to these features from bedrock and from alluvium is indeterminate. 5. All seeps and springs are reported to have enhanced flow during wet periods. For seeps and springs associated with alluvium, this behavior is consistent with an alluvial contribution to flow. Enhanced flow during wet periods at Ruin Spring, which originates from bedrock above the level of the alluvium, likely results from direct recharge of Burro Canyon Formation and Dakota Sandstone outcropping near the mesa margin in the vicinity of Ruin Spring. This recharge would be expected to temporarily increase the flow at Ruin Spring (as well as other seeps and springs where associated bedrock is directly recharged) after precipitation events. 6. The assumption that the seep or spring elevation is representative of the perched water elevation is likely to be correct only in cases where the feature receives most or all of its flow from perched water and where the supply is relatively continuous (for example at Ruin Spring). The perched water elevation at the location of a seep or spring that receives a significant proportion of water from a source other than perched water may be different from the elevation of the seep or spring. The elevations of seeps that are dry for at least part of the year will not be representative of the perched water elevation when dry. Some uncertainty therefore results from including these seeps and springs in the contouring of perched water levels. However, even if such springs are sometimes dry, the presence of cottonwoods suggests that perched groundwater is close to the surface at these locations. Although there are uncertainties associated with incorporation of seep and spring elevations into maps depicting perched water elevations or maps depicting the Burro Canyon Formation/Brushy Basin Member contact elevations, post-2010 perched water elevation maps incorporate seep and spring elevations other than Cottonwood Seep, and post-2010 contact elevation maps incorporate Westwater Seep and Ruin Spring elevations. As discussed above, Cottonwood Seep was interpreted in HGC (2010g) to be associated with coarser-grained materials within the lower portion of the Brushy Basin Member. The justification for this interpretation is based primarily on 1) the rate of flow at Cottonwood Seep, which is typically estimated to range between approximately 1 and 10 gpm (consistent with Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 13 Dames and Moore, 1978), 2) the need for relatively permeable materials to transmit this rate of flow, and 3) the change in morphology near Cottonwood Seep indicating a change in lithology. The change in morphology from slope-former to bench-former just east of Cottonwood Seep can be seen in the topographic map included in Appendix E (Figure E.1) and the annotated photograph provided in Figure 6. The upper portion of the Brushy Basin Member, which hydraulically isolates the perched zone from underlying materials, is composed primarily of bentonitic mudstone, claystone, and shale. The rate of flow at Cottonwood Seep is inconsistent with the materials found within the upper portion of the Brushy Basin Member but is consistent with coarser-grained materials expected either within the lower portion of the Brushy Basin Member or within the upper portion of the underlying Westwater Canyon (sandstone) Member. The relationship between Cottonwood Seep and lithology is shown on the geologic map provided in Appendix E (Figure E.2) and Figure 6. As shown in Figures 6 and E.1, Cottonwood Seep is located approximately 230 feet below the base of the perched zone defined by the contact between the cliff-forming Burro Canyon Formation and the underlying slope-forming Brushy Basin Member. The change in morphology from slope-former to bench-former occurs within the lower portion of the Brushy Basin Member (or the upper portion of the Westwater Canyon Member), between the termination of the perched zone at the mesa rim and Cottonwood Seep. The bench-like area hosting Cottonwood Seep begins at the change in morphology east of Cottonwood Seep and terminates west of Cottonwood Seep where a cliff-forming sandstone, interpreted to be within the Westwater Canyon Member, is exposed. The contact between the Westwater Canyon Member and the Brushy Basin Member is interpreted to be located between this sandstone outcrop and the change in morphology from slope-former to bench-former. This places Cottonwood Seep at the transition between the Brushy Basin Member and the underlying Westwater Canyon Member. This is consistent with the stratigraphy provided in Figure 3 which places the contact between the Brushy Basin Member and the Westwater Canyon Member at elevations between approximately 5,220 and 5,230 ft amsl in this portion of the site, within 5 to 15 feet of the elevation of Cottonwood Seep (5,234 ft amsl). Details of the coarse-grained nature of the lower portion of the Brushy Basin Member are consistent with Shawe (2005) as will be discussed in Section 3.1.1. 2.1.5 Tailings Management System The existing TMS includes cells 1 through 4B (Figure 1A). Details of the construction of cells 2 though 4A are provided in UMETCO (1993). Mill tailings are disposed in lined cells excavated Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 14 below grade into the upper Dakota Sandstone. Cells 2 and 3 are underlain by a synthetic liner placed over compacted bedding material. The bedding material serves as a drain layer. The drain layer and a sand drain on the downstream embankment are connected to a leak detection lateral. Slime drains were installed above the liner in each cell within the area having the lowest topographic elevation. Cell 4A and cell 4B have a geoclay liner overlain by geotextile and a double synthetic liner. The leak detection systems lie between the two synthetic liners. Although the cells are equipped with leak detection systems, and monitoring activities have not detected impacts to the perched aquifer from tailings disposal (as discussed in Section 2), the Mill installed additional perched monitoring wells between existing wells on the downgradient margin of the TMS and between existing cells to function as an ‘early warning system’ for any potential impacts to perched water. These additional wells, MW-23 through MW-25, and MW- 27 through MW-31, were installed and tested in 2005 (HGC 2005). At this time, temporary wells TW4-15 and TW4-17, located at the eastern edge of the cell complex and installed in 2002 (HGC, 2002), were converted to permanent status and renamed MW-26 and MW-32, respectively. Subsequently, upon installation of cell 4B, MW-33 through MW-37 were added to the west and south (downgradient) edges of the cell. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 15 3. DETAILED SITE HYDROGEOLOGY A detailed description of site hydrogeology is provided in the following Sections. 3.1 Stratigraphy and Formation Characteristics The site stratigraphy is summarized in Figure 3. Details of formations underlying the site that are stratigraphically above the Westwater Canyon Member of the Morrison Formation are provided in the following Sections. 3.1.1 Brushy Basin Member As discussed in Sections 2.1.1 and 2.1.3, the upper portion of the Brushy Basin Member is composed of bentonitic mudstone, claystone, and shale, which hydraulically support the perched groundwater zone and isolate it from underlying materials. The upper portion of the Brushy Basin Member is described by Shawe (2005) as “principally mudstone; it contains only minor amounts of sandstone, conglomeratic sandstone, and conglomerate as discontinuous lenses”. Shawe (2005) describes the lower portion of the Brushy Basin as coarser-grained, having “mudstone layers which contain, near their base, lenses lithologically similar to sandstone of the Salt Wash Member, and near their top, conglomeratic sandstone lenses”. With regard to the vicinity of Cottonwood Seep (discussed in Section 2.1.4), the expectation of coarser-grained materials is consistent with its location near the transition from the lower coarser-grained portion of the Brushy Basin Member into the underlying Westwater Canyon Member. As discussed in Craig et al. (1955), and Flesch (1974), the Westwater Canyon Member intertongues with the Brushy Basin Member. Craig et al. (1955) state “The Westwater Canyon Member forms the lower portion of the upper part of the Morrison in northeastern Arizona, northwestern New Mexico, and places in southeastern Utah and southwestern Colorado near the Four Corners, and it intertongues and intergrades northward into the Brushy Basin Member”. 3.1.2 Burro Canyon Formation/Dakota Sandstone Although the Dakota Sandstone and Burro Canyon Formations are often described as a single unit due to their similarity, previous investigators at the site have distinguished between them. The Dakota Sandstone is a relatively hard to hard, generally fine-to-medium grained sandstone cemented by kaolinite clays. The Dakota Sandstone locally contains discontinuous interbeds of siltstone, shale, and conglomeratic materials. Porosity is primarily intergranular. The underlying Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 16 Burro Canyon Formation is the primary host of the perched groundwater at the site. The Burro Canyon Formation is similar to the Dakota Sandstone but is generally more poorly sorted, contains more conglomeratic materials, and becomes argillaceous near its contact with the underlying Brushy Basin Member (TITAN, 1994). The permeabilities of the Dakota Sandstone and Burro Canyon Formations at the site are generally low. Porosities and water contents measured in samples of Dakota Sandstone and Burro Canyon Formation collected from borings MW-16 and MW-17 are described in Sections 3.1.2.1 and 3.1.2.2 below. Porosity estimates from these borings agree with measurements reported by MWH (MWH, 2010) for archived samples collected from borings MW-23 and MW-30. No significant joints or fractures within the Dakota Sandstone or Burro Canyon Formation have been documented in any wells or borings installed across the site (Knight-Piésold, 1998). Any fractures observed in cores collected from site borings are typically cemented, showing no open space. The Knight-Piésold findings are consistent with the evaluation of a 1994 drilling program provided in HGC (2001a) and with examination of drill core samples collected during installation of MW-3A, MW-23, MW-24, MW-28, MW-30, and TW4-22 in 2005 (HGC, 2005). 3.1.2.1 Dakota Sandstone The Dakota Sandstone, named by Meek and Hayden (1862) for exposures in northeastern Nebraska, rests disconformably upon the Burro Canyon Formation where present. A three-fold lithologic sequence occurs in many localities, and consists of a basal conglomeratic sandstone with an underlying disconformity, a middle unit of carbonaceous shale and coal, and an upper unit of evenly-bedded sandstone which intertongues with the overlying Mancos Shale. These strata have been described as deposits of transitional environments which accompanied the westward transgressing Mancos Sea (Young, 1973). The basal conglomerate represents floodplain braided channel deposits which extend into the adjacent paludal environment. The carbonaceous shales are partly marshy but most formed in lagoon ponds, tidal flats and tidal channels of the lagoonal environment just seaward of the marsh belt. The evenly-bedded sandstone was formed at the shoreline as a mainland or barrier beach deposit of the littoral marine environment. Faunal evidence summarized by O'Sullivan et al., (1972) indicates that the lower part of the Dakota Sandstone is of Early Cretaceous age and the upper part is of Late Cretaceous age. Based on samples collected during installation of wells MW-16 (abandoned) and MW-17, located beneath and immediately downgradient of the TMS at the site (Figures 1A and 1B), porosities of the Dakota Sandstone range from 13.4% to 26%, and average 20% (Table 5) which Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 17 is nearly the same as the average porosity of 19% reported by MWH (MWH, 2010) for archived sandstone samples collected from MW-23 and MW-30. Water saturations from MW-16 and MW-17 range from 3.7% to 27.2%, averaging 13.5%, and the average volumetric water content is approximately 3% (Table 5). The permeability of the Dakota Sandstone based on packer tests in borings installed at the site ranges from 2.71 x 10-6 cm/s to 9.12 x 10-4 cm/s, with a geometric average of 3.89 x 10-5 cm/s (TITAN, 1994). 3.1.2.2 Burro Canyon Formation The Burro Canyon Formation, as defined by Stokes and Phoenix (1948) at its type locality near Slick Rock, Colorado, consists of alternating conglomerate, sandstone, shale, limestone and chert ranging in thickness from 150 to 260 feet. In the Blanding Basin, the Burro Canyon Formation consists of deposits of alluvial and floodplain materials up to about 100 feet thick, consisting of medium to coarse grained sandstone, conglomerate, pebbly sandstone, and claystone. Persistent, widely traceable, conglomeratic sandstones, interpreted as deposits of a braided channel sub- environment, occur within the formation. Sandwiched between these sandstones are variegated mudstone units containing sandstone and siltstone lenses, the products of interchannel and meandering channel subenvironments. Fossils collected from the Burro Canyon Formation at various localities include freshwater invertebrates, dinosaur bones and plants. Although not truly diagnostic, they suggest an Early Cretaceous (Aptian) age. The average porosity of the Burro Canyon Formation is similar to that of the Dakota Sandstone. Based on samples collected from the Burro Canyon Formation at MW-16 (abandoned, located beneath cell 4B as shown in Figure 1A), porosity ranges from 2% to 29.1%, averaging 18.3%, similar to the average porosity of 19% reported by MWH (MWH, 2010) for archived sandstone samples collected from MW-23 and MW-30. Water saturations of unsaturated materials collected from MW-16 range from 0.6% to 77.2%, and average 23.4% (Table 5). TITAN (1994), reported that the hydraulic conductivity of the Burro Canyon Formation ranges from 1.9 x 10-7 to 1.6 x 10-3 cm/s, with a geometric mean of 1.01 x 10-5 cm/s, based on the results of 12 pumping/recovery tests performed in monitoring wells and 30 packer tests performed in borings prior to 1994 (Table 4). As discussed in Section 2, subsequent testing of wells by HGC yields a hydraulic conductivity range of approximately 2 x 10-8 to 0.01 cm/s (HGC, 2012b). Hydraulic conductivity estimates obtained from perched wells installed and tested subsequent to HGC (2012b) also fall within this range (HGC, 2013a; HGC, 2013b; HGC, 2014c; HGC, 2015; HGC, 2016; HGC, 2018b; HGC, 2018c; HGC, 2019b; HGC, 2021a; and HGC, 2021b. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 18 In general (as discussed in Section 2.1.3), the highest permeabilities and well yields are in the portion of the site immediately northeast and east (upgradient to cross gradient) of the TMS. A relatively continuous, higher permeability zone (associated with poorly indurated coarser-grained materials in the general area of the chloroform plume) has been inferred to exist in this portion of the site (HGC, 2007b). As discussed in HGC (2004), analysis of drawdown data collected from this zone during long-term pumping of MW-4, MW-26 (TW4-15), and TW4-19 (Figures 1A and 1B) yielded estimates of hydraulic conductivity ranging from approximately 4 x 10-5 to 1 x 10-3 cm/s (Table 3). A slug test performed at TW4-4 yielded a hydraulic conductivity of approximately 1.7 x 10-3 cm/s (Table 1). The decrease in perched zone permeability south to southwest of this area (south of TW4-4), based on tests at TW4-6, TW4-26, TW4-27, TW4-29 through TW4-31, and TW4-33 and TW4-34 (Table 1), indicates that this higher permeability zone “pinches out”, consistent with the interpretation provided in HGC (2007b). Relatively high conductivities measured at MW-11, located on the southeastern margin of the downgradient edge of cell 3, and at MW-14, located on the downgradient edge of cell 4A, of 1.4 x 10-3 cm/s and 7.5 x 10-4 cm/s, respectively (UMETCO, 1993 and Table 4), may indicate that this higher permeability zone extends beneath the southeastern portion of the TMS. However, based on hydraulic tests conducted south and southwest of these wells, this zone of higher permeability does not appear to exist within the saturated zone downgradient (south-southwest) of the TMS. Furthermore, as discussed in HGC (2018e), although the hydraulic conductivity is relatively high at both MW-11 and MW-14, the higher permeability materials penetrated by these wells do not appear to connect. Slug tests performed at groups of wells and piezometers located northeast (upgradient) of, in the immediate vicinity of, and southwest (downgradient) of the TMS indicate generally lower permeabilities compared with the area of the chloroform plume. The following results are based on analysis of automatically logged slug test data using the KGS solution available in AQTESOLV (HydroSOLVE, 2000). Testing of TWN-series wells installed in the northeast portion of the site as part of nitrate investigation activities (HGC, 2009) yielded a hydraulic conductivity range of approximately 3.6 x 10-7 to 0.01 cm/s with a geometric average of approximately 6 x 10-5 cm/s; including more recently installed wells TWN-20 and TWN-21 yields a geometric average hydraulic conductivity of approximately 5 x 10-5 cm/s. The value of 0.014 cm/s estimated for TWN-16 is the highest measured at the site, and the value of 3.6 x 10-7 cm/s estimated for TWN-7 is one of the lowest measured at the site. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 19 Testing of MW-series wells MW-23 through MW-32 (HGC, 2005) installed within and at the margins of the TMS in 2005 (and using the higher estimate for MW-23) yielded a hydraulic conductivity range of approximately 2 x 10-7 to 1 x 10-4 cm/s with a geometric average of approximately 2 x 10-5 cm/s. The geometric average hydraulic conductivity of all tested MW- series wells (including far up-gradient; far cross-gradient; and far downgradient wells; and using the higher estimate for MW-23) is less than 3 x 10-5 cm/s. Hydraulic tests conducted at DR-series piezometers installed as part of the southwest area investigation (HGC 2012b) downgradient of the TMS yielded hydraulic conductivities ranging from approximately 2 x 10-8 to 4 x 10-4 cm/s with a geometric average of 9.6 x 10-6 cm/s. The relatively low permeabilities and shallow hydraulic gradients downgradient of the TMS result in average perched groundwater pore velocity estimates that are among the lowest on site (approximately 0.26 feet per year (ft/yr) to 0.91 ft/yr based on calculations presented in HGC, 2012b). The extensive hydraulic testing of perched zone wells at the site indicates that perched zone permeabilities are generally low with the exception of the apparently isolated zone of higher permeability associated with the chloroform plume east to northeast (cross-gradient to upgradient) of the TMS. The geometric average hydraulic conductivity (less than 1 x 10-5 cm/s) of the DR-series piezometers which cover an area nearly half the size of the total monitored area at White Mesa (excluding MW-22), is nearly identical to the geometric average hydraulic conductivity of 1.01 x 10-5 cm/s reported by TITAN (1994), and is within the range of 5 to 10 feet per year (ft/yr) [approximately 5 x 10-6 cm/s to 1 x 10-5 cm/s] reported by Dames and Moore (1978) for the (saturated) perched zone during the initial site investigation. 3.1.3 Mancos Shale Conformably overlying the Dakota Sandstone is the Upper Cretaceous Mancos Shale. The Mancos Shale was deposited in the Western Interior Cretaceous seaway (Figure 7) and is primarily composed of uniform, dark-gray mudstone, shale, and siltstone. It was deposited in nearshore and offshore neritic subenvironments of the Late Cretaceous Sea during its overall southwestern transgression and subsequent northeastward regression. The Mancos Shale was named by Cross and Purington (1899) from exposures near Mancos, Colorado. Outcrops of the Upper Cretaceous Mancos Shale occur as hills and slopes generally near or directly beneath overlying Quaternary pediment remnants across portions of the Blanding Basin. Mancos Shale is absent in most of the Blanding Basin (due to erosion) where rocks of the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 20 Dakota Sandstone and Burro Canyon Formation are either exposed or mantled by thin unconsolidated deposits. The Mancos Shale in the Blanding Basin consists of marine shale and interbeds of thin (less than 2 feet thick) sandstone and siltstone beds. Various pelecypod fossils are common in Mancos Shale outcrop areas (Huff and Lesure, 1965; Haynes et al., 1972). Total thickness is estimated at 30 to 40 feet, but is generally negligible to 20 feet, a small erosional remnant of its original thickness of approximately 2,000 feet. The Mancos Shale was deposited during transgression and highstand of the Cretaceous Interior Seaway during the Late Cretaceous (Elder and Kirkland, 1994). Where present, the Mancos Shale may act as an important impermeable layer reducing the amount of potential infiltration and recharge to the underlying Dakota-Burro Canyon perched aquifer (Avery, 1986; Goodknight and Smith, 1996). The Mancos Shale belongs to the group of thick marine organic muds (or black shales) generally considered to be deposited in geosynclinal areas. Bentonitic volcanic ash layers are abundant in the Mancos Shale (Shawe, 1968). An abundance of pyrite in the layers may indicate that iron was an important constituent of the ash, possibly being liberated by devitrification of glass and redeposited with the diagenetic development of pyrite. Hydrogen sulfide was abundant in the organic rich sediments accumulating at the bottom of the Mancos Sea, if it was a typical sapropelic marine environment, as seems likely, and may have been especially abundant in the volcanic ash (Fenner, 1933). Trapped sea water that is buried in the mud of the Mancos Shale likely had a high content of organic material consistent with the abundance of diagenetic pyrite. Chemical reduction resulting from hydrogen sulfide generated in carbon-rich sediments is characteristic of stagnant sea bottoms. In the Early Tertiary, the original clay and silt deposited in the Mancos Shale became compacted to about a third to a tenth of its original water saturated volume by the time it was buried to a depth of about 10,000 feet (Shawe, 1976). Pore water throughout the Colorado Plateau, driven from compacting mud, moved largely upward into younger sediments (Yoder, 1955), but much water must have moved into the lower more porous strata because of local conditions of rock structure (Hedberg, 1936), because of the relatively high water density, and because of abnormally high fluid pressures. Expulsion of water likely occurred throughout the deposition of the Mancos Shale in the Late Cretaceous and during deposition of younger sediments in the Early Tertiary. Therefore expulsion occurred during a period of many millions of years and at depths ranging from near- surface to nearly maximum depths of burial. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 21 Faulting occurred in many places on the Colorado Plateau, including the Blanding Basin during the Late Cretaceous and Early Tertiary when the Mancos was undergoing deep burial by younger strata. Faulting provided numerous avenues allowing water movement into underlying porous strata. It seems likely therefore that the Dakota Sandstone at the base of the Mancos Shale, and the dominantly sandy underlying Burro Canyon Formation, contained pore water which was expelled from the Mancos and was under abnormally high fluid pressures (Shawe, 1976). Compaction of bedding around pyrite crystals shows the early development of part of the diagenetic pyrite, and indicates that pore fluids were being squeezed out of the Mancos Shale during the period of diagenesis. As pore fluids became trapped in the Mancos Shale following deposition of sediment in the Late Cretaceous, they immediately began to react with black opaque minerals, with magnetite deposited with the abundant ash fall material and possibly with volcanic glass and other iron-bearing material to form pyrite. Faulting that occurred on the Colorado Plateau in the Late Cretaceous and Early Tertiary facilitated movement of the Mancos pore water into underlying beds, causing removal of hematite coating on sand grains, destruction of detrital black opaque minerals, and growth of iron sulfide minerals (Shawe, 1976). 3.1.4 Pyrite Occurrence in the Dakota Sandstone and Burro Canyon Formation As discussed above, downward movement of the Mancos Shale pore water into underlying beds of the Dakota Sandstone and Burro Canyon Formations caused removal of hematite coatings on sand grains, destruction of detrital black opaque minerals, and the growth of iron sulfide minerals. Shawe (1976) classifies the Dakota Sandstone and Burro Canyon Formations as “altered-facies” rocks primarily as a result of the invasion of pore waters expelled from the overlying Mancos Shale during compaction. Shawe states that “altered facies rocks that developed by solution attack are notable for their almost complete loss of black opaque minerals and gain of significant pyrite.” Shawe further states that “altered-facies rocks contain only sparse black opaque minerals but appreciable pyrite” and that “alteration caused destruction of most detrital back opaque minerals, precipitation of substantial pyrite, and recrystallization of carbonate minerals that took up much of the iron liberated from the solution of black opaque minerals.” According to Shawe (1976), “altered-facies sandstone is light gray or, where weathered, also light buff to light brown. It contains only a small amount of black opaque heavy minerals and may or may not contain carbonaceous material. The light buff to light brown colors are imparted by limonite formed from oxidation of pyrite in weathered rock.” Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 22 Furthermore Shawe (1976) states “In weathered rocks as observed in thin sections pyrite has been replaced by ‘limonite’, but preservation of original pyrite crystal forms and lack of abundant limonite ‘wash’ or dustlike limonite suggest that the forms of most limonite are indicative of the original forms of pyrite before oxidation. Pyrite (or limonite) in sandstone occurs as isolated interstitial patches as much as 2 millimeters (mm) in diameter enclosing many detrital grains, or as cubes 1 mm across and smaller that are mainly interstitial but that also partially replace detrital grains.” Also “limonite pseudomorphs after marcasite have been recognized in vugs in altered-facies sandstone of the Burro Canyon Formation.” Shawe (1976) also notes that pyrite is more common below the water table and iron oxides (likely formed by oxidation of pyrite) are more common in the vadose zone. These observations are consistent with the occurrence of and oxidation of pyrite in the formations hosting the perched water at the site as will be discussed in Section 4. 3.2 Contact Descriptions Lithologic contacts between the Brushy Basin Member of the Morrison Formation, and between the Dakota Sandstone and the overlying soils and/or the Mancos Shale, are described in Sections 3.2.1 and 3.2.2. Cross-sections through soils based on soil borings installed per Phase I of the nitrate CAP are presented and discussed in Section 3.2.3. 3.2.1 Brushy Basin Member/Burro Canyon Formation Contact Elevations Figure 8 is a contour map of the Burro Canyon Formation/Brushy Basin Member contact generated from perched well, piezometer, DR-series boring data and the locations and elevations of Westwater Seep and Ruin Spring. Figure 8 was generated based on data indicating that only Westwater Seep and Ruin Spring are located at the contact between the Burro Canyon Formation and the Brushy Basin Member (HGC, 2012b). Other seeps and springs (except Cottonwood Seep) shown on Figure 8 occur within generally conglomeratic horizons of the Burro Canyon Formation but at elevations above the contact with the underlying Brushy basin Member. As discussed in HGC (2012b) examination of the area near Cottonwood Seep in July 2010 and re-examination in October 2011 revealed no evidence for a hydraulic connection with the perched zone. The absence of any visible seeps or anomalous vegetation in the Brushy Basin Member east and northeast of Cottonwood Seep is consistent with dry conditions in the upper portion of the Brushy Basin Member. Figure 8 shows that the erosional Brushy Basin/Burro Canyon contact surface dips generally to the south-southwest and is very irregular in the northeast portion of the site. A paleoridge in the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 23 Brushy Basin erosional paleosurface extends from beneath cell 4B to the southwest near abandoned boring DR-18. To the east of this paleoridge, a paleovalley extends from south of cell 4A to the northeast, extending into the vicinity of the northern wildlife ponds. A paleovalley subparallel to the cell 4B paleoridge is also present on the west side of the paleoridge, between the paleoridge and the western mesa margin. The approximate axes of these and other paleoridges and paleovalleys in the southwest portion of the site are indicated on Figure 8. These features are especially important in this portion of the site due to the generally small saturated thicknesses and the consequently relatively large impacts these features are expected to have on perched water flow in this area. Other notable features include a paleoridge surrounded by paleovalleys that trend northwest – southeast (rather than northeast – southwest) in the area northeast of the Mill site; a paleovalley extending from the area of cell 4B to Westwater Seep; paleovalleys converging on Ruin Spring; and a paleoridge that appears to extend from the eastern margin of cell 4A through the vicinity of MW-38. 3.2.2 Mancos Shale/Dakota Contact Elevations Figures 9A through 11B are elevation contour maps of the top of bedrock (top of the Dakota Sandstone or Mancos Shale [where present]), the top of the Dakota Sandstone, and the top of bedrock showing Mancos thickness. Figures 9A and 9B show alternate interpretations of bedrock elevations based on a re-interpretation of lithologic logs for the site. Specifically, Figure 9B is based on a re-interpretation of lithologic logs (provided in Appendix A.6 and summarized in Figure A.6) that did not specifically call out ‘Mancos Shale’ but described materials overlying the Dakota Sandstone as having characteristics that were similar to or nearly identical to those logged as ‘Mancos Shale’ in other borings. Two of the primary factors considered in the re- interpretation include 1) a description of materials overlying the Dakota Sandstone as ‘shale’ or ‘silty’ or ‘sandy shale’; and 2) materials overlying the Dakota Sandstone having a strong reactivity with dilute hydrochloric acid (HCL). As discussed in U. S. Department of Energy (USDOE), 2011, and Shawe (1968), the carbonate content of the Mancos is high, reaching as much as 40% and averaging 20%. This suggests that materials overlying the Dakota at the site that react strongly with dilute HCL, even when not specifically logged as ‘Mancos Shale’, or just ‘shale’, may at least in part be composed of weathered Mancos due to their reactivity. In contrast to the Mancos, surficial alluvial materials and aeolian sands are less likely to have carbonate contents as significant as the Mancos or to react strongly with dilute HCL. In addition, logs for many borings within and at the margins of Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 24 the TMS (in particular MW-5, MW-11, MW-12, MW-14 and MW-15) show only ‘dike material’ above the Dakota; yet Mancos Shale was likely present prior to excavating for TMS cell construction. The interpreted thickness of the Mancos Shale is shown in Figures 11A and 11B. Figure 11B is based on the re-interpreted presence and thickness of the Mancos as described above and as summarized in Figure A.6 (Appendix A.6). The thickness of the Mancos Shale shown in Figures 11A and 11B is based on the difference between the top of bedrock and top of Dakota Sandstone surfaces, and is clipped in areas where erosion is expected to have removed the Mancos. Based on these maps, the top of Dakota and top of bedrock surfaces dip generally to the south-southwest consistent with the general dip of the top of Brushy Basin surface. In the northeast portion of the site these surfaces are generally less irregular than the top of the Brushy Basin surface. Notable features include a structural high in the top of Dakota and top of bedrock surfaces near cell 4B, and a north-south trending structural high in the top of bedrock surface east to northeast of the TMS. The latter feature is primarily the result of a ridge-like remnant of the Mancos Shale that reaches thicknesses greater than 30 feet along the axis of the feature. Structural highs near cell 4B are present in the top of Brushy Basin surface (Figure 8), the top of bedrock (Figures 9A and 9B), and the top of Dakota (Figure 10) surface. These features are ridge-like in all three surfaces but the paleoridge in the top of Brushy Basin is not coincident with the paleoridge in the top of bedrock and top of Dakota surfaces except in the vicinity of cell 4B. The primary axis of the paleoridge in the Brushy Basin surface extends from MW-33 at the southwest corner of cell 4B through DR-10, MW-21 and DR-18. The axis of the paleoridge in the top of bedrock surface extends from MW-35 through DR-11, DR-15, and DR-21. The axis of the paleoridge in the top of Dakota surface appears to extend from the vicinity of MW-24 (at the southwest corner of cell 1) through MW-33, DR-11, and possibly DR-15 (but is less well-defined near DR-15). 3.2.3 Soils Above the Dakota and /or Mancos Figure 12 depicts the locations of soil borings installed near the ammonium sulfate crystal tanks as per Phase I of the nitrate CAP (HGC, 2012a). Borings were installed to depths of refusal using a drive-point rig as described in EFRI (2013). The depth of refusal is assumed to represent competent bedrock. Figure 13 depicts soils cross-sections developed from these borings. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 25 Unconsolidated soils consist primarily of silts with interbedded sands and clays. Weathered Mancos Shale was encountered in many of the borings. Detailed logs of all soil borings are provided in EFRI (2013). Soils present above the Mancos Shale in this portion of the site are dominated by the same fine- grained materials typical of other portions of the site. Soil types encountered in borings installed by INTERA (Appendix C) are generally consistent with those found in the vicinity of the ammonium sulfate crystal tanks and other portions of the site. 3.3 Perched Water Elevations, Saturated Thicknesses, and Depths to Water As discussed in Section 2.1.3, Figure 5 is a contour map of perched water elevations generated from fourth quarter, 2021 water level data. Figure 5 contains perched well and piezometer water level data, and the elevations of all seeps and springs except Cottonwood Seep (for which there is no evidence to establish a connection to the perched water system and which is located near the Brushy Basin Member/Westwater Canyon Member contact, indicating that its elevation is not representative of the perched potentiometric surface). Fill-in contours between the 10-foot elevation contours are provided over portions of the site, including the area immediately west- southwest of the TMS to allow detail in an area having relatively flat hydraulic gradients. Figure 5 was generated assuming that each seep or spring (except Cottonwood Seep) is a known discharge point for perched groundwater and that the elevation of the seep or spring is representative of the perched water elevation at that location (HGC, 2010g). As discussed in Section 2.1.4, because of the presence of cottonwoods, perched groundwater elevations near seeps/springs that are dry for portions of the year are likely to be near the surface. Figure 14 shows the saturated thicknesses of the perched zone based on fourth quarter, 2021 water level data. Saturated thicknesses range from approximately 81 feet at TWN-18, located just north of the Mill site (and adjacent to the historic pond), to less than 5 feet in the southwest portion of the site, downgradient of the TMS. A saturated thickness of approximately 2 feet occurs in well MW-34 along the south dike of cell 4B, and the perched zone has been consistently dry at MW-33 located at the southwest corner of cell 4B, and at MW-21 located south-southwest of cell 4B. Abandoned well MW-16 (formerly located beneath cell 4B as shown in Figure 1A) was also consistently dry. MW-21, MW-33 and abandoned well MW-16 are all located on a structural high in the top of Brushy Basin Member surface (Figure 8). Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 26 Figure 15 shows depths to perched water as of the fourth quarter of 2021. Depths to perched water range from approximately 42 feet below top of casing (btoc) northeast of the TMS (at TWN-3, adjacent to the historical pond) to approximately 114 feet btoc at the southwestern margin of cell 3. Prior to cessation of water delivery to the northern wildlife ponds the shallowest depths to water were encountered in piezometers and wells near these ponds. 3.4 Interpretation of Cross-Sections Lithologic and soils cross-sections prepared for various portions of the site are discussed in the following Sections. In general, the lithologies encountered in the borings used to construct the cross-sections are consistent with the literature and with past investigations at the site (prior to TITAN, 1994). Figures 16A, 16B, 17, 18A, 18B, and 19 are lithologic and perched groundwater elevation cross-sections covering various areas of the site. 3.4.1 Central and Northeast Areas Figures 16A, 16B and 17 are lithologic cross-sections in the central to northeast portions of the site, as shown on Figure 1A. Figure 16A is a northeast-southwest oriented cross-section (NE- SW) extending from abandoned well MW-3 to TWN-12. Figure 16B is a parallel cross section (NE2-SW2) extending from TWN-18 to TWN-19. Figure 17 is a northwest-southeast cross- section (NW-SE) extending from TWN-7 to abandoned piezometer Piez-3. Figures 16A, 16B, and 17 indicate site features located near the cross-sections. These cross-sections indicate that the top of Brushy Basin surface is irregular in the northeast portion of the site and that, as discussed in Sections 3.1.2.1 and 3.1.2.2, the Burro Canyon Formation and Dakota Sandstone contain shale/claystone and conglomerate interbeds of varying thickness and continuity. Where poorly indurated (poorly cemented), coarser sand and conglomeratic horizons are expected to be relatively permeable; shale/claystone horizons are expected to be at least partial barriers to perched groundwater flow, and where present in the vadose zone, to represent at least partial barriers to downward percolation of recharge. That local saturated conditions have not been encountered above shale/claystone horizons during drilling within the Dakota Sandstone and Burro Canyon Formations suggests that recharge rates over most of the site are generally low, except near unlined ponds or surface depressions, or other areas having enhanced recharge due to their locations within drainages or due to relatively flat, slowly drainable topography. Figure 16A, 16B and 17 show that the perched water table surface remains relatively elevated in the vicinities of the northern wildlife ponds and the historical pond. TWN-2 and TWN-3 (Figure Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 27 1B) are located within and adjacent to the footprint of the historical pond, respectively. TWN-2 is a nitrate pumping well and TWN-3 a non-pumping nitrate monitoring well. As will be discussed in Section 3.5.2, the water level at TWN-2 remained persistently high for many years after installation, likely as a result of low permeability and possibly enhanced recharge in the vicinity due to graded areas of the Mill site having relatively flat topography and relatively slow runoff. Although the water level at TWN-3 remains relatively elevated, the water level at TWN-2 has declined due to pumping. 3.4.2 Southwest Area Figures 18A, 18B and 19 are cross-sections showing the hydrogeology of the perched zone in the area southwest of the TMS located as shown in Figure 1A. Figure 18A provides west-east cross- sections (W-E and W2-E2) across the area immediately west and southwest of cell 4B. Figure 18B is a west-northwest to east-southeast (WNW to ESE) cross section (from DR-7 to MW-17) that extends along the south dikes of TMS cells 4A and 4B. Figure 19 is a south-north cross- section (S-N) from the south dike of cell 4B to Ruin Spring. Cross-sections W-E and S-N are oriented generally parallel to perched water flow; and W2-E2 and WNW-ESE are oriented generally perpendicular to perched water flow. Figure 18B (WNW-ESE) shows that MW-33 is dry and the saturated thickness at MW-34 is small due to the structural high in the top of the Brushy Basin surface that trends through MW-21 and MW-33. Except for abandoned DR-series borings, water levels in the cross sections are based on fourth quarter, 2021 data. Water levels for abandoned DR-series borings are from the second quarter, 2011. Water levels for DR-series piezometers have not changed significantly between the third quarter of 2011 and the fourth quarter of 2021 (as shown in Figure 20) suggesting that second quarter, 2011 water levels for abandoned DR-series borings are likely still representative of current conditions. As shown in Figure 14, cross-sections W-E and W2-E2 in Figure 18A, and cross section S-N in figure 19, the saturated thickness of the perched zone in the southwest area of the site varies from negligible to more than 20 feet. The variable saturated thickness has implications regarding the flow of perched water to known discharge points Westwater Seep and Ruin Spring. Perched water moving downgradient from the vicinity of the TMS westward toward abandoned boring DR-2 must pass through a region of small saturated thickness occupied by DR-6 and DR-7 (Figures 5, 14 and 18A). By Darcy’s Law, downgradient areas affected by groundwater discharge points such as Westwater Seep and Ruin Spring that have larger saturated thicknesses must receive local recharge from precipitation because the water supplied by lateral perched flow is inadequate to maintain the large saturated thicknesses in these areas. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 28 Two areas of relatively large saturated thickness that are downgradient of areas of small saturated thickness are of particular interest: the area near DR-2 (abandoned) and DR-5 located west of the area near DR-6 and DR-7 as shown in Figure 18A (cross-section W-E), and the area near DR-25 located south of the area near MW-20 as shown in Figure 19 (cross-section S-N). Each of the above areas of larger saturated thickness is downgradient of the corresponding area of small saturated thickness, and each downgradient area of larger saturated thickness is affected by a perched water sink or discharge point. The primary known perched groundwater discharge point or sink downgradient of DR-2 (abandoned) and DR-5 are Westwater Seep to the northeast and the paleovalley leading south to Ruin Spring (Figures 8 and 14). The primary discharge point near abandoned boring DR-25 is Ruin Spring. Lateral flow from areas of larger saturated thickness that may exist to the east of cross-section S-N may supply the water needed to maintain the relatively large saturated thickness near DR-25. However, the reported temporary increases in flow from Ruin Spring (and Westwater Seep) after precipitation events (HGC, 2010g) are problematic unless flow is temporarily enhanced by local recharge. As discussed in HGC (2010g), enhanced local recharge is likely near the mesa margins where weathered Dakota Sandstone and Burro Canyon Formation are exposed by erosion (Figure E.2, Appendix E). Lithologic Logs at DR-2 and DR-5 (Appendix A) show only a few feet of unconsolidated material above the Dakota Sandstone and visual inspection of the mesa near DR- 2 (abandoned) and DR-5 shows that weathered Dakota is often exposed (consistent with the geology presented in Dames and Moore (1978). Due to the thin veneer of unconsolidated material overlying the Dakota Sandstone, and thin, weathered or absent Mancos Shale, recharge near DR-2 and DR-5 (cross-section W-E, Figure 18A) will be facilitated. Similarly, in the area near abandoned boring DR-25 and Ruin Spring, recharge will be facilitated by the topography, the thinness or absence of the Mancos Shale, and the surface exposure of the Dakota Sandstone and Burro Canyon Formation between DR-25 and Ruin Spring (cross-section S-N, Figure 19). 3.5 Perched Water Occurrence and Flow Description of the occurrence and flow of perched water at the site focuses on three general areas: 1) the nitrate investigation area, 2) the vicinity of the chloroform plume, and 3) areas beneath and downgradient of the TMS, as per Sections 3.5.2, 3.5.3, and 3.5.4 respectively. 3.5.1 Overview As discussed in Section 2.1.3, perched groundwater at the site occurs primarily within the Burro Canyon Formation as well as the overlying Dakota sandstone where saturated thicknesses are greater. Perched water flow is generally from northeast to southwest across the site. Flow onto Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 29 the site occurs as underflow from areas northeast of the Mill site where perched zone saturated thicknesses are generally greater. Flow exits the Mill property in seeps and springs to the east, west, southwest and southeast. Any flow that does not discharge in seeps or springs presumably exits as underflow to the southeast of Ruin Spring, along the southwest extending lobe of White Mesa located between Ruin Spring and Corral Springs (Figure 1B). 3.5.1.1 General Site Flow Pattern Fourth quarter 2021 perched water elevations (Figure 5) show the typical west-southwesterly to south-southwesterly flow pattern at the site. The historic water level contour maps in Appendix D demonstrate the persistence of the generally southwesterly perched flow pattern. As noted previously, the Appendix D maps do not incorporate seep and spring elevations. As discussed in Section 2.1.3, beneath and downgradient of the TMS, on the west side of the site, perched water flow is south-southwest to west-southwest. On the eastern side of the site perched water flow is generally southerly to south-southwesterly. Perched zone hydraulic gradients currently range from a maximum of nearly 0.098 feet per foot (ft/ft) east of cell 2 (in the vicinity of the chloroform plume, between TW4-2 and TW4-3) to approximately 0.0021 ft/ft in the northeast corner of the site (between TWN-19 and TWN-16). Hydraulic gradients in the southwest portion of the site are typically close to 0.01 ft/ft, but the gradient is less than 0.005 ft/ft to the west-southwest of cell 4B, between cell 4B and DR-8. The overall average site hydraulic gradient, between TWN-19 in the extreme northeast to Ruin Spring in the extreme southwest, is approximately 0.011 ft/ft. Perched groundwater discharges in springs and seeps along the mesa margins. These features are located along Westwater Creek Canyon and Cottonwood Canyon to the west and southwest of the site, and along Corral Canyon to the east of the site, where the Burro Canyon Formation is exposed. Based on the data presented in Figure 5, the discharge points located most directly downgradient of the TMS are Westwater Seep and Ruin Spring. Westwater Seep is located approximately 2,200 feet west, and Ruin Spring is located approximately 9,400 feet south- southwest, of the existing TMS (Figure 1B). Dry areas beneath cell 4B and southwest of cell 4B (south of MW-21) affect perched water flow and are defined in Figure 5 by areas where the kriged contact between the Burro Canyon Formation and the Brushy Basin Member is higher in elevation than the kriged perched groundwater elevation. The dry areas shown in Figure 5 encompass abandoned dry well MW-16, dry well MW-21, dry well MW-33, and abandoned dry boring DR-18. The areas defined by the heavy yellow dashed contour lines have saturated thicknesses estimated to be less than 5 feet. As Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 30 shown in Figure 5 and southwest area cross-sections (Figures 18A, 18B and 19), a large portion of the perched zone west and southwest (downgradient) of the TMS has a saturated thickness less than 5 feet. This zone has been persistent based on measurements since the third quarter of 2011. An apparent perched groundwater divide exists in the vicinity of DR-2 (abandoned, Figure 1A) and DR-5 (Figure 5). Perched water north of this apparent divide is expected to flow primarily northeast toward Westwater Seep and perched water south of this apparent divide is expected to flow primarily south toward Ruin Spring (as will be discussed in Section 3.5.4). Figure 14 shows the axes of paleoridges and paleovalleys in the Brushy Basin Member erosional paleosurface and posted fourth quarter, 2021 saturated thicknesses. As indicated, paleoridges in the southwest area of the site are associated with dry areas and with areas of low saturated thicknesses; paleovalleys are associated with areas of higher saturated thicknesses. Westwater Seep and Ruin Spring are located in paleovalleys. The average saturated thickness based on measurements at MW-35, DR-7, and DR-6, which are the points closest to a line between the southwest portion of cell 3 and Westwater Seep, is less than 6 feet. The average saturated thickness based on measurements at MW-37, DR-13, MW-3A, MW-20, and DR-21, which lay close to a line between the southeast portion of cell 4B and Ruin Spring, is approximately 11 feet. Perched groundwater mounding associated with the wildlife ponds locally changes the generally southwesterly perched water flow patterns. For example, northeast of the Mill site, relict mounding associated with the northern wildlife ponds results in locally northwesterly flow near PIEZ-1. Mounding also causes the hydraulic gradient to be more westerly west of the ponds and more easterly east of the ponds. The impact of the mounding associated with the northern ponds, to which water has not been delivered since March 2012, continues to diminish as the mound decays due to reduced recharge. Similarly, the impact of mounding associated with the southern wildlife pond is diminishing due to reduced recharge. As discussed in Section 2.1.3, since the first quarter of 2012, water levels have declined within the northern mound by as much as 25 feet (at PIEZ-2), and within the southern mound by as much as 23 feet (at PIEZ-5). 3.5.1.2 Influence of Pumping and Wildlife Pond Seepage on Flow and Dissolved Constituent Concentrations Figures 1A and 1B show the locations of chloroform and nitrate pumping wells at the site. MW- 4, MW-26, TW4-1, TW4-2, TW4-4, TW4-11, TW4-19, TW4-21, TW4-37, TW4-39, TW4-40 and TW4-41 are chloroform pumping wells; and TWN-2, TW4-22, TW4-24, and TW4-25 are nitrate pumping wells. TW4-20 was formerly a chloroform pumping well, but due to collapse during August, 2020, was abandoned in October, 2020. As discussed in HGC (2022), the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 31 abandonment of TW4-20 had little or no impact on the effectiveness of the chloroform pumping system in this area. Figure 21 is a map showing kriged fourth quarter 2021 perched water levels, the extents of the nitrate and chloroform plumes at the site, and inferred perched water flow paths. Figure 22 is a detail map showing the locations of perched wells, fourth quarter, 2021 kriged water levels, and inferred capture zones associated with pumping wells. As discussed in Section 2, four additional chloroform wells, TW4-40 through TW4-43, were installed during February, 2018 (HGC, 2018b); April, 2019 (HGC, 2019b); and September, 2021 (HGC, 2021b). TW4-40 was installed approximately 200 feet south of TW4-26; TW4-41 was installed immediately north-northeast of TW4-4; TW4-42 was installed approximately 200 feet south of TW4-40; and TW4-43 was installed approximately 200 feet east-southeast of TW4-30. TW4-41 was designed as a pumping well to augment chloroform mass removal in the southern portion of the plume; and TW4-40 was converted into a pumping well to control chloroform migration in the southern extremity of the plume. TW4-40 primarily controls elevated chloroform detected at both TW4-40 and TW4-26 (located immediately up-gradient of TW4-40). As described in HGC (2012a) the nitrate pumping system, which became operational in the first quarter of 2013, is designed to (eventually) establish hydraulic capture of the nitrate plume upgradient (north of) TW4-22 and TW4-24. MW-30 and MW-31, located at the downgradient edge of the plume, are not pumped in order to minimize the potential for downgradient chloroform migration. As described in HGC (2007b) and HGC (2022), the chloroform pumping system, which became operational in 2003 with the pumping of MW-4, TW4-19, and MW-26 (TW4-15), and later enhanced by the addition of TW4-20 in 2005; TW4-4 in 2010; TW4-1, TW4-2, TW4-11, TW4-21, and TW4-37 in 2015; TW4-39 in 2016; and TW4-41 in 2018, is designed primarily to reduce mass in upgradient portions of the plume where saturated thicknesses, concentrations, and well productivities are higher. Mass reduction is thereby maximized, the source of chloroform to downgradient areas cut off, and natural attenuation facilitated. As discussed above, the addition to the pumping system in 2019 of well TW4-40, which is located in the southern extremity of the plume, helps to control elevated chloroform detected at both TW4-40 and TW4-26. TW4-40 is valuable in that it is located within the downgradient (southern) toe of the plume and is relatively productive. Pumping of TW4-40 is likely to more effectively reduce or prevent further downgradient plume migration than can be expected by pumping at the more upgradient locations. Local depression of the perched water table occurs near chloroform pumping wells MW-4, MW- 26, TW4-1, TW4-2, TW4-11, TW4-19, TW4-21, TW4-37, TW4-39, TW4-40 and TW4-41 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 32 (Figure 22). Pumping of chloroform wells MW-4 and TW4-19 began in 2003 (HGC, 2004). Well-defined cones of depression are evident near all chloroform pumping wells except TW4-37, which began pumping during 2015. The lack of a well-defined cone of depression near TW4-37 is likely due to its close proximity to chloroform and nitrate pumping wells TW4-19 and TW4- 22. Although operation of chloroform pumping well TW4-4 depressed the water table in the vicinity of TW4-4, a well-defined cone of depression was not clearly evident until adjacent well TW4-41 began pumping in 2018. The former lack of a well-defined cone of depression near TW4-4 likely resulted from 1) variable permeability conditions in the vicinity of TW4-4, and 2) persistent relatively low water levels at adjacent well TW4-14, as will be discussed in Section 3.5.3. Local depression of the perched water table also occurs near nitrate pumping wells TWN-2, TW4-22, TW4-24, and TW4-25 (Figure 22), which are operated to reduce nitrate mass in the perched groundwater as per the nitrate CAP (HGC, 2012a). Although TWN-2 has been pumping as long as the other nitrate pumping wells, the cone of depression now associated with this well was formerly masked by its location on the edge of a perched groundwater mound. Cones of depression are likely to still be in the process of development in the vicinities of the four nitrate pumping wells which were brought on-line in the first quarter of 2013. Relatively slow development of capture zones has been expected due to generally low permeability within the nitrate plume. The hydraulic effects of the chloroform and nitrate pumping systems overlap. Figure 22 shows the inferred capture of both chloroform and nitrate pumping systems as of the fourth quarter of 2021. Capture zones are calculated by hand based on the kriged water level contours following the rules for flow nets. From each pumping well, stream tubes that bound the capture zone are reverse-tracked, and perpendicularity is maintained between each stream tube and the intersected kriged water level contours. Recharge from the wildlife ponds has impacted perched water elevations and flow directions at the site by creating perched groundwater mounds as discussed in Section 3.5.1. Furthermore, the March 2012 cessation of water delivery to the northern ponds, which are generally upgradient of the nitrate and chloroform plumes at the site, has resulted in changing conditions that were expected to impact constituent concentrations and migration rates within the plumes. Specifically, past recharge from the ponds has helped limit many constituent concentrations within the plumes by dilution while the associated groundwater mounding has increased hydraulic gradients and contributed to plume migration. Since use of the northern ponds was discontinued in March 2012, increases in constituent concentrations in many wells, and Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 33 decreases in hydraulic gradients within the plumes, are attributable to reduced recharge and the decay of the associated groundwater mound. The impacts associated with cessation of water delivery to the northern wildlife ponds were expected to propagate downgradient (south and southwest) over time. Wells close to the ponds were generally expected to be impacted sooner than wells farther downgradient of the ponds. Therefore, constituent concentrations were generally expected to increase in downgradient wells close to the ponds before increases were detected in wells farther downgradient of the ponds. Although such increases were anticipated to result from reduced dilution, the magnitude and timing of the increases have been difficult to predict due to the complex permeability distribution at the site and factors such as pumping and the rate of decay of the perched groundwater mound. The potential exists for some wells completed in higher permeability materials to be impacted sooner than some wells completed in lower permeability materials even though the latter may be closer to the ponds. Localized increases in concentrations of constituents such as chloroform and nitrate within and near the chloroform plume, and of nitrate and chloride within and near the nitrate plume, may occur even when these plumes are under control. Ongoing mechanisms that can be expected to increase constituent concentrations locally as a result of reduced wildlife pond recharge include but are not limited to: 1. Reduced dilution - the mixing of low constituent concentration pond recharge into existing perched groundwater will be reduced over time. 2. Reduced saturated thicknesses – dewatering of any higher permeability layers receiving primarily low constituent concentration pond water will result in wells intercepting these layers receiving a smaller proportion of the low constituent concentration water. The combined impact of the above two mechanisms was considered to be especially likely at chloroform and nitrate pumping wells and non-pumped wells adjacent to the pumped wells. The expected overall impact was generally higher constituent concentrations in chloroform and nitrate wells over time until mass reduction resulting from pumping and natural attenuation eventually reduced concentrations. Short-term changes in concentrations at pumping wells and wells adjacent to pumping wells are also expected to result from changes in pumping conditions. In general, due to its closer proximity to the wildlife ponds, reduced dilution has impacted wells within and adjacent to the chloroform plume to a greater extent than wells located within and adjacent to the nitrate plume. However, between the third quarter of 2018 and first quarter of 2021, continued pumping, natural attenuation, and the diminishing effects of reduced recharge from the wildlife ponds, have caused chloroform concentrations at several of the chloroform wells, in particular TW4-6, TW4-8, TW4-9 and TW4-33, to drop below 70 µg/L. Prior to dropping below Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 34 70 µg/L, these four wells were either already within the chloroform plume; or had been re- incorporated into the plume after cessation of water delivery to the wildlife ponds. 3.5.2 Nitrate Investigation Area The extent of the nitrate plume addressed by the nitrate CAP (HGC, 2012a) and referred to as the ‘nitrate plume’ (defined by nitrate as nitrogen concentrations exceeding 10 mg/L) is shown in Figure 21. Figure 21 also displays kriged fourth quarter, 2021 perched water level contours and inferred flow paths and shows the extent of the chloroform plume which overlaps the nitrate plume in the vicinity of TW4-22. Nitrate exceeding 10 mg/L also occurs to the southeast of the plume in relatively isolated pockets (for example, near TW4-27). As discussed in HGC (2014a), this southeastern nitrate is attributed to sanitary leach field discharge associated with the chloroform plume and potentially with former cattle ranching operations at the site. Nitrate exceeding 10 mg/L far to the south and southwest at MW-20 and MW-38 is also potentially associated with former cattle ranching operations. The potential for cattle to contribute nitrate to soil is discussed in McFarland et al (2006). Elevated nitrate in soil can then act as a source to groundwater. Perched groundwater flow within the area of the nitrate plume varies from south-southwest to west-southwest. The generally southwesterly hydraulic gradient typical of the majority of the site is influenced by past recharge from the northern wildlife ponds; elevated water levels in the vicinity of well TWN-3; and formerly elevated water levels at pumping well TWN-2. TWN-2 is within the footprint of the historical pond and TWN-3 is immediately east of the footprint of the pond, as shown in Figure 1B. Recharge from the northern wildlife ponds, located immediately northeast of the nitrate plume, caused a shift in gradient in the northern portion of the plume from southwesterly to west-southwesterly (compare Appendix D 1990 and 1994 water level maps with Figure 21). The persistently elevated water level that formerly existed at TWN-2, which has functioned as a nitrate pumping well since the first quarter of 2013, likely resulted from low permeability and possibly enhanced recharge in the vicinity of TWN-2 due to graded areas of the Mill site having relatively flat topography and relatively slow runoff. Cones of depression associated with nitrate pumping wells TW4-22, TW4-24, TW4-25, and TWN-2, have been developing since initiation of pumping during the first quarter of 2013. Hydraulic capture associated with these wells has developed slowly due to low permeability conditions. That sufficient capture will eventually develop is indicated by calculations presented in HGC (2017) showing that nitrate pumping exceeds pre-pumping flow through the nitrate plume by a factor of approximately 2.1; and calculations presented in EFRI (2022c) showing that as of the fourth quarter of 2021, pumping at nitrate wells, and at chloroform wells within the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 35 nitrate plume (TW4-19, TW4-21 and TW4-37), exceeds pre-pumping flow through the plume by a factor of 2.3. Water level patterns near nitrate pumping wells have been influenced by the presence of, and the decay of, the groundwater mound associated with the northern wildlife ponds, and by the persistent relatively low water level elevation that formerly existed at TWN-7. In addition, water level patterns near nitrate pumping wells are influenced by interaction with nearby chloroform pumping wells. The long term interaction between nitrate and chloroform pumping systems continues to evolve. Criteria regarding control and potential migration of the nitrate plume are detailed in the nitrate CAP (HGC, 2012a). As stated in the CAP, MW-5, MW-11, MW-30, and MW-31 are located downgradient of TW4-22 and TW4-24; MW-30 and MW-31 are within the nitrate plume near its downgradient edge; and MW-5 and MW-11 are outside of and downgradient of the plume. Per the CAP, hydraulic control based on concentration data is considered successful if the concentrations of nitrate in MW-30 and MW-31 remain stable or decline, and concentrations of nitrate in downgradient wells MW-5 and MW-11 do not exceed the 10 mg/L standard. Based on these criteria, the nitrate plume is under control. The plume has not migrated downgradient to MW-5 or MW-11 because nitrate exceeding 10 mg/L has not been detected at MW-11 and has been detected at concentrations less than 1 mg/L at MW-5. Nitrate concentrations in both MW-30 and MW-31 at the downgradient edge of the plume have been relatively stable, demonstrating that plume migration is minimal (HGC, 2017; EFRI, 2022c). Recent increases in nitrate at downgradient well MW-11 suggest that downgradient migration continues to occur but at a low rate. As discussed in Section 2, elevated chloride (exceeding 100 mg/L) commingles with the nitrate plume. Chloride has been increasing at MW-31; and is also increasing at MW-30 (but at a lower rate). Increasing chloride at both MW-30 and MW-31 is consistent with ongoing downgradient migration of the nitrate/chloride plume (EFRI, 2022c). The increases in chloride and stable nitrate at MW-30 and MW-31 suggest a natural attenuation process that is affecting nitrate but not chloride. A likely process that would degrade nitrate but leave chloride unaffected is reduction of nitrate by pyrite. The likelihood of this process in the perched zone is discussed in HGC (2012c) and HGC (2017). Estimated natural nitrate degradation rates range from approximately 172 pounds per year (lb/yr) to 200 lb/yr as discussed in HGC (2017). Based on these rates, less than 200 years would be required to remediate the nitrate plume, even in the absence of any direct mass removal by pumping. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 36 Understanding of perched water level behavior in the area northeast (upgradient) of the Mill site was enhanced by the installation of TWN-series wells TWN-1 through TWN-19 within and northeast of the nitrate plume in 2009; and by the installation of TWN-20 and TWN-21 to the west of the nitrate plume during the second quarter of 2021. Prior to the installation of TWN- series wells, upgradient information was limited to that provided by MW-1, MW-18, MW-19, PIEZ-1, and PIEZ-2. As shown in Figure 1B, nitrate wells TWN-5, TWN-8, TWN-9, TWN-10, TWN-11, TWN-12, TWN-13, TWN-15, and TWN-17 have been abandoned as per the nitrate CAP. TWN-20 and TWN-21 were installed in response to nitrate exceeding 10 mg/L at TWN-7 (Figure 1B), which was historically located downgradient of the northern extremity of the nitrate plume defined by wells TWN-2 and TWN-3. Although measurements at TWN-20 and TWN-21 provide additional detail on water level distributions in this area, no significant changes to water level contours north of cell 1 resulted from water level measurements at these wells. In general, water level data provided by the TWN-series wells and existing wells and piezometers in the northeast portion of the Mill property indicate that perched water flow is to the southwest. Data from many of these wells helped to better define the extent of the perched groundwater mound resulting from former recharge at the northern wildlife ponds. Figure 23 is a water level contour map from the fourth quarter, 2011 constructed prior to both TWN well abandonment and cessation of water delivery to the wildlife ponds. Comparing Figure 23 with Figure 5 demonstrates the substantial reductions in the perched groundwater mounds associated with the wildlife ponds between the fourth quarters of 2011 and 2021. 3.5.3 Vicinity of Chloroform Plume As noted in Section 3.5.1.2, the footprint of the chloroform plume is shown in Figure 21. The plume boundary is defined by the Groundwater Corrective Action Limit (GCAL) of 70 µg/L. Water level and concentration data presented in this Section are from EFRI (2022b) or HGC (2022) unless otherwise indicated. Perched groundwater flow within the area of the chloroform plume has been generally southerly to southwesterly. The chloroform plume resulted from disposal of laboratory wastes to the abandoned scale house and former office sanitary leach fields. The abandoned scale house leach field is the likely source of the southeastern portion of the plume and the former office leach field is the likely source of the northwestern portion of the plume (HGC, 2007b). Both of these sources received laboratory wastes prior to operation of the TMS (circa 1980), and in the case of the abandoned scale house leach field, prior to construction of the Mill. Laboratory wastes prior Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 37 to 1980 were first disposed to the abandoned scale house leach field and later to the former office leach field. Laboratory wastes have been disposed to the TMS since it became operational circa 1980. The abandoned scale house leach field was located immediately north-northwest of well TW4-18 (Figure 1B). Historic perched water flow in this area was generally to the south (Appendix D). Chloroform disposed in the abandoned scale house leach field migrated primarily southerly to the vicinity of well MW-4 where it was detected in 1999. Hydraulic gradients and flow directions in this area were impacted by pre-2012 recharge from the northern wildlife ponds located north of MW-4. The former office leach field is located in the immediate vicinity of chloroform pumping well TW4-19 and immediately northeast of cell 2 (and former chloroform pumping well TW4-20, now abandoned) [Figure 1B]. Perched water flow in this area was historically southwest (Appendix D), and hydraulic gradients were enhanced by pre-2012 recharge from the northern wildlife ponds (located to the northeast). Once chloroform pumping began in 2003 the flow regime, formerly dominated by wildlife pond recharge in the vicinity of the chloroform plume, began to change locally under the influence of the pumping. Reduced wildlife pond recharge since the first quarter of 2012 and the initiation of nitrate pumping in the first quarter of 2013 have also impacted the flow regime. Well defined cones of depression are evident in the vicinity of all chloroform pumping wells except TW4-37, which began pumping during 2015. The lack of a well-defined cone of depression near TW4-37 is likely due to its close proximity to chloroform pumping well TW4-19 and nitrate pumping well TW4-22. Prior to pumping at adjacent well TW4-41, a well-defined cone of depression was not evident at TW4-4. The former lack of a well-defined cone of depression near TW4-4 had causes other than proximity of other pumping wells, although once it began pumping in 2010, TW4-4 has depressed the water table in the vicinity of TW4-4. As discussed in Section 3.5.1.2 variable permeability conditions likely contributed to the former lack of a well-defined cone of depression near chloroform pumping well TW4-4. Changes in water levels at wells immediately south of TW4-4 resulting from TW4-4 pumping were expected to be muted because TW4-4 is located at a transition from relatively high to relatively low permeability conditions south (downgradient) of TW4-4. The permeability of the perched zone at TW4-6, TW4-26, and TW4-29 is approximately two orders of magnitude lower than at TW4-4 (Table 1). In addition, drawdown of water levels at wells immediately south of TW4-4 resulting Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 38 from TW4-4 pumping was difficult to determine because of the general increase in water levels that formerly occurred in this area due to past recharge from the wildlife ponds. Water levels at TW4-4 and TW4-6 increased by nearly 2.7 and 2.9 feet, respectively, between the fourth quarter of 2007 and the fourth quarter of 2009 (just prior to the start of TW4-4 pumping) at rates of approximately 1.2 feet/year and 1.3 feet/year, respectively. However, the increase in water level at TW4-6 was reduced after the start of pumping at TW4-4 (first quarter of 2010) to approximately 0.5 feet/year suggesting that TW4-6 is within the hydraulic influence of TW4-4 (Figure 24). Except for TW4-30, which was incorporated into the chloroform plume in the fourth quarter of 2020, water levels in wells currently within the chloroform plume south of TW4-4 (TW4-26, TW4-29, and TW4-40) have been trending generally downward since the fourth quarter of 2013. This downward trend is attributable to both the cessation of water delivery to the wildlife ponds and pumping. Prior to 2018, generally increasing water levels were confined to some of the wells marginal to the chloroform plume such as TW4-14, TW4-27, TW4-30, and TW4-31. Water levels in these marginal wells, and TW4-30, have since stabilized. These spatially variable water level trends likely result from pumping conditions, the permeability distribution, and distance from the wildlife ponds. Wells that are relatively hydraulically isolated (due to completion in lower permeability materials or due to intervening lower permeability materials) and that are more distant from pumping wells and the wildlife ponds, are expected to respond more slowly to pumping and reduced recharge than wells that are less hydraulically isolated and are closer to pumping wells and the wildlife ponds. Wells that are more hydraulically isolated will also respond more slowly to changes in pumping. The former lack of a well-defined cone of depression at TW4-4 was also influenced by the former, relatively low water level at non-pumping well TW4-14, located east of TW4-4 and TW4-6. Since pumping began at TW4-41, however, water levels at TW4-14 have generally been higher than water levels at TW4-4. For the fourth quarter of 2021, the water level at TW4-14 (approximately 5535.7 ft amsl) is nearly 6 feet higher than the water level at TW4-6 (approximately 5529.8 ft amsl) and more than 5 feet higher than the water level at TW4-4 (approximately 5530.3 ft amsl), consistent with a substantial cone of depression. The water levels at wells TW4-14 and downgradient well TW4-27 (installed south of TW4-14 in the fourth quarter of 2011) were similar (within 1 to 2 feet) until the third quarter of 2014; both appeared anomalously low. TW4-27 was positioned at a location considered likely to detect any chloroform present and/or to bound the chloroform plume to the southeast and east (respectively) Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 39 of TW4-4 and TW4-6. Groundwater data collected since installation indicates that TW4-27 does indeed bound the chloroform plume to the southeast and east of TW4-4 and TW4-6 (respectively); however chloroform exceeding 70 µg/L was detected at more recently installed temporary perched wells TW4-29 (located south of TW4-27) and TW4-33 (located between TW4-4 and TW4-29). Note that, although chloroform at TW4-33 exceeded 70 µg/L through 2020, concentrations dropped below 70 µg/L after the fourth quarter of 2020. Prior to the installation of TW4-27, the former (pre-TW4-41 pumping), persistently low water level at TW4-14 was considered anomalous because it appeared to be downgradient of all three wells TW4-4, TW4-6, and TW4-26, yet chloroform had not been detected at TW4-14. Chloroform had apparently migrated from TW4-4 to TW4-6 and from TW4-6 to TW4-26. This suggested that TW4-26 was actually downgradient of TW4-6, and TW4-6 was actually downgradient of TW4-4, regardless of the flow direction implied by the low water level at TW4- 14. The water level at TW4-26 (5527.8 feet amsl) is, however, lower than water levels at adjacent wells TW4-6 (5529.8 feet amsl), and TW4-23 (5531.8 feet amsl). Hydraulic tests indicate that the permeability at TW4-27 is an order of magnitude lower than at TW4-6 and three orders of magnitude lower than at TW4-4 (Table 1). Past similarity of water levels at TW4-14 and TW4-27, and the low permeability estimate at TW4-27, suggested that both wells were completed in materials having lower permeability than nearby wells. The low permeability condition likely reduced the rate of long-term water level increase at TW4-14 and TW4-27 compared to nearby wells, yielding water levels that appeared anomalously low. This behavior is consistent with hydraulic test data collected from more recently installed wells TW4- 29, TW4-30, TW4-31, TW4-33, TW4-34 and TW4-35, which indicate that the permeability of these wells is one to two orders of magnitude higher than the permeability of TW4-27 (Table 1). Hydraulic tests also indicate that the permeability at TW4-36 is slightly higher than but comparable to the low permeability at TW4-27, suggesting that TW4-36, TW4-14 and TW4-27 are completed in a continuous low permeability zone. The fourth quarter, 2021 water level at TW4-27 (approximately 5529.1 ft. amsl) is more than 6 1/2 feet lower than the water level at TW4-14 (5535.7 ft. amsl). Increases in water level differences between TW4-14 and TW4-27 since 2013 are attributable to more rapid increases in water levels at TW4-14 compared to TW4-27. This behavior likely results primarily from: the relative positions of the wells; past water delivery to the northern wildlife ponds; and the permeability distribution. Past seepage from the ponds caused propagation of water level increases in all directions including downgradient to the south. The relative hydraulic isolation of TW4-14 and TW4-27 delayed responses at these locations to such an extent that they responded to past seepage more slowly than many nearby wells. Water levels at these wells remained lower Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 40 than in surrounding higher permeability materials even though water levels in surrounding materials were generally decreasing due to reduced wildlife pond seepage and pumping. Before stabilizing in 2018, water levels at TW4-14 and TW4-27 increased. Compared to TW4-27, the rate of increase was higher at TW4-14 due to factors that include: closer proximity to the northern pond seepage source; a smaller thickness of low permeability materials separating TW4-14 from surrounding higher permeability materials; and hydraulic gradients between TW4- 14 and surrounding higher permeability materials that on average were larger. Slowing of the rates of water level increase at TW4-14 (between 2015 and 2018) and TW4-27 (between early 2014 and 2018) is attributable to reduced hydraulic gradients as TW4-14 and TW4-27 water levels ‘caught up’ with water levels in surrounding higher permeability materials. In addition, water levels in this area have been affected by reduced recharge at the southern wildlife pond and the consequent decay of the associated groundwater mound. The decay of the southern mound likely contributed to the reduction in hydraulic gradients between the low permeability materials penetrated by TW4-14 and TW4-27 and the surrounding higher permeability materials. TW4-27 is closer to the southern wildlife pond than TW4-14. Any reduction in hydraulic gradients attributable to the southern pond was expected to impact TW4- 27 sooner and to a greater extent than TW4-14, consistent with the lower rate of increase in water levels at TW4-27, and the earlier reduction in the rate of increase (since early 2014) as discussed above. The low permeability at TW4-14 and TW4-27 has retarded the transport of chloroform to these wells (compared to nearby wells). TW4-14 and TW4-27 remain outside the plume; and concentrations at these wells have remained below 10 µg/L. During the fourth quarter of 2021, chloroform was not detected at TW4-14 and was detected at TW4-27 at approximately 4 µg/L. Chloroform exceeding 70 µg/L at TW4-29 and formerly at TW4-33 indicated that, in addition to migrating south from TW4-4 to TW4-6 and TW4-26, chloroform also migrated along a relatively narrow path to the southeast from the vicinity of TW4-4 to TW4-33 then TW4-29 and eventually to TW4-30. Such migration was in a direction nearly cross-gradient with respect to the direction of groundwater flow implied by the historic groundwater elevations in this area, which, until relatively recently, placed TW4-14 almost directly downgradient of TW4-4. Such migration was historically possible because the water levels at TW4-29 have been lower than the water levels at TW4-4 (and TW4-6); and, prior to the second quarter of 2021, the water levels at TW4-30 were lower than the water levels at TW4-29. The permeability and historic water level distributions are generally consistent with the apparent nearly cross-gradient migration of chloroform from TW4-4 around the low permeability zone defined by TW4-36, TW4-14, and TW4-27. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 41 During the fourth quarter of 2021 chloroform at TW4-30 (located east and cross-gradient of TW4-29) was detected at approximately 81 µg/L. TW4-30 bounded the chloroform plume to the east until concentrations first exceeded 70 µg/L during the fourth quarter of 2020 (as discussed above). Chloroform has not been detected at wells TW4-31 (located east of TW4-27), TW4-34 (located south and cross- to downgradient of TW4-29 and TW4-30), TW4-35 (located southeast and generally downgradient of TW4-29 and TW4-30), nor at TW4-43 (located cross-to downgradient of TW4-29 and TW4-30). Data from wells within and adjacent to the southern portion of the chloroform plume indicate that: 1. Chloroform exceeding 70 µg/L at TW4-29 is bounded by concentrations below 70 µg/L at wells TW4-6, TW4-23, TW4-27, TW4-33, TW4-34, TW4-35 and TW4-42; however, as discussed above, TW4-30 no longer bounds the plume immediately to the east. Although previously downgradient of TW4-29, due to long-term changes in water levels, TW4-30 is now generally cross-gradient of TW4-29. TW4-6, TW4-23, TW4-27 and TW4-33 are generally cross- to upgradient of TW4-29; TW4-34 and TW4-35 are generally downgradient of TW4-29; TW4-42 is generally cross- to downgradient of TW4-29; and TW4-43 (which bounds the plume to the east) is generally cross- to downgradient of TW4-30. 2. Chloroform concentrations at TW4-33 that are lower than concentrations at TW4-29, and the likelihood that a pathway exists from TW4-4 to TW4-33 to TW4-29, suggest that concentrations in the vicinity of TW4-33 were likely higher prior to initiation of TW4-4 pumping, and that lower concentrations currently detected at TW4-33 are due to its closer proximity to TW4-4. 3. Chloroform concentrations at TW4-26 exceeded 70 µg/L for the first time during the second quarter of 2017. Chloroform at TW4-26 is bounded by concentrations below 70 µg/L at TW4-6 and TW4-23 (located up- to cross-gradient of TW4-26); and at TW4-34 (located generally cross- gradient of TW4-26). Chloroform has not been detected at either TW4-23 or TW4-34. Although chloroform exceeding 70 µg/L was detected at well TW4- 40, installed approximately 200 feet south of TW4-26 in February, 2018, chloroform has not been detected at TW4-42, installed approximately 200 feet south of TW4-40 in April, 2019. TW4-42 is generally downgradient of both TW4-26 and TW4-40 and bounds the chloroform plume to the south. Eventually, TW4-4 pumping, enhanced by operation of adjacent pumping well TW4-41, was expected to reduce chloroform at both TW4-29 and TW4-33 by cutting off the source. The decrease at TW4-33 was expected to be faster than at TW4-29 because TW4-33 is in closer proximity to TW4-4 pumping. Such behavior was expected by analogy with the temporary decreases in chloroform concentrations that occurred at TW4-6 and TW4-26 once TW4-4 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 42 pumping began (discussed in Section 4.2.3). Since installation in 2013, however, concentrations at TW4-33 appear to be relatively stable to decreasing (and have generally been decreasing since 2018). From the third quarter of 2014 until the second quarter of 2020, concentrations at TW4-29 generally increased; however since the second quarter of 2020 concentrations appear to be relatively stable. Chloroform trends at TW4-29 and TW4-33 suggest that chloroform migration has been arrested at TW4-33 by TW4-4 (and TW4-41) pumping and that increased chloroform at TW4-29 resulted from a remnant of the plume that migrated past TW4-33 and generally toward TW4-30 (which was previously downgradient of TW4-29, and until the fourth quarter of 2020, bounded the plume to the east). The influence of TW4-4 pumping at the distal end of the plume is consistent with generally decreasing water levels at both TW4-29 and TW4-33. Pumping at TW4-41 since the second quarter of 2018 is expected to help maintain or enhance this decline. Decreasing water level trends at TW4-29 and TW4-33 are also consistent with reduced wildlife pond seepage. The decay of the groundwater mound associated with the southern wildlife pond, which is 3 to 4 times closer to the southern extremity of the chloroform plume than the northern ponds, is expected to impact water levels within and adjacent to this portion of the plume. Reduced wildlife pond seepage, in particular, reduced seepage from the southern wildlife pond, likely contributes to decreasing water level trends at both wells (since about the fourth quarter of 2013); temporarily increased concentrations at TW4-6 subsequent to the first quarter of 2014; and increased concentrations at TW4-26 since the third quarter of 2016. As the groundwater mound associated with the southern pond decays, groundwater flow directions in the southern extremity of the plume have become more southerly (rather than southeasterly), and plume migration has turned more to the south. An increasingly southerly direction of plume migration is consistent with increasing concentrations at TW4-26. Continued decay of the southern mound is expected to result in eventual restoration of the typical site southwesterly flow pattern within this portion of the plume. Detectable chloroform concentrations at TW4-14 (between the fourth quarter of 2014 and the first quarter of 2021) and TW4-27 (since the third quarter of 2015) suggest ongoing, but slow, downgradient migration of chloroform from the distal end of the plume into the low permeability materials penetrated by TW4-14 and TW4-27. Although chloroform at the southeastern extremity of the plume may temporarily continue to migrate to the southeast, the southeastern extremity of the plume is approximately 1,200 feet from the closest (eastern) property boundary (Figure 1B). Site water level data suggest that the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 43 plume is unlikely to reach the eastern property boundary as perched water flow along the boundary to the east of the southeastern extremity of the plume appears to be generally south- southwesterly and sub-parallel to the boundary (Figure 1B; Figure 21; HGC, 2018d). The southern property boundary on the east side of the site is more than three miles to the south of the plume and the nearest downgradient discharge point (Ruin Spring) is nearly two miles to the south-southwest of the plume. Because of the large distance to the southern property boundary, chloroform mass removal by pumping, and natural attenuation of chloroform, it is unlikely that chloroform within the southern or southeastern extremities of the plume will ever reach the southern property boundary at concentrations exceeding the GCAL. As discussed in HGC (2022), reduced dilution from reduced wildlife pond recharge caused average chloroform concentrations and calculated residual masses within the plume to increase after 2012; however both average concentrations and calculated residual masses have been trending downward since 2015. In addition, the more than doubling of the number of chloroform pumping wells since 2014 has increased mass removal rates and has helped to maintain a relatively large proportion of the plume mass under hydraulic capture (between 89% and 99%). Furthermore, as will be discussed in Section 4.4.3, first-order chloroform biodegradation rate calculations presented in HGC (2007b) and HGC (2022) indicate that less than 200 years would be required to remediate the plume, even in the absence of any direct mass removal by pumping. 3.5.4 Beneath and Downgradient of the Tailings Management System As discussed in Section 2, more than 41 years of groundwater monitoring beneath and downgradient of the TMS indicates that the system has not impacted groundwater. In the event that potential seepage from the TMS should impact groundwater at a future date, the likely pathways to known discharge points Westwater Seep and Ruin Spring are calculated in Section 3.5.4.1. Perched zone water balances within the areas near DR-2 (abandoned) and DR-5, and flow within the vicinities of Westwater Seep and Ruin Spring are calculated in Sections 3.5.4.2 and 3.5.4.3. 3.5.4.1 Overview Figure 25 is a perched water level contour map showing inferred pathlines from various locations on the west or south (downgradient) dikes of TMS cells toward known discharge points Westwater Seep and Ruin Spring. These pathlines show the primary expected directions of perched water flow. As indicated, perched water passing beneath the west dike of cell 4B has the potential to travel to either of known discharge points Westwater Seep or to Ruin Spring because of an apparent groundwater divide in the vicinity of DR-2 (abandoned; Figure 1A) and DR-5. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 44 Perched water north of this apparent divide is expected to flow primarily northeast to Westwater Seep and perched water south of this apparent divide is expected to flow primarily south toward Ruin Spring. The presence of this apparent divide is consistent with enhanced recharge over this portion of the mesa. The path to Ruin Spring from the area south of the apparent groundwater divide is sub-parallel to the western rim of the mesa. The path is generally along a paleovalley between the mesa rim and the dry portion of the Brushy Basin Member paleoridge defined by MW-21 and abandoned boring DR-18. Perched water passing beneath the south dike of cell 4B (and cell 4A) is expected to travel south-southwest to Ruin Spring, to the east of the dry paleoridge defined by MW-21 and abandoned boring DR-18. As discussed previously, the data suggest that perched water flow in the southwest portion of the site is influenced by paleotopography to a greater extent than in other areas of the site due to the prevalence of relatively small saturated thicknesses. As discussed in Section 2.1.4, there is no evidence to hydraulically connect Cottonwood Seep to the perched water system; therefore no inferred flow pathway depicted in Figure 25 leads to Cottonwood Seep. Section 3.6.3 posits a potential pathway that may hypothetically exist between the perched zone near DR-8 and Cottonwood Seep for purposes of travel time calculations, and to allow for the possibility that an as yet unidentified pathway may exist. 3.5.4.2 Water Balance Near DR-2 and DR-5 Enhanced recharge south/southwest of Westwater Seep near DR-2 (abandoned; Figure 1A) and DR-5 is likely needed to maintain the relatively large saturated thicknesses there, considering the slow rate of perched water flow into this area via the zone of small saturated thickness and the presence of known discharge point Westwater Seep to the northeast and the paleovalley leading south to Ruin Spring (acting as a sink). Because the water columns in most piezometers penetrating the area of low saturated thicknesses were inadequate for hydraulic testing, only one estimate of hydraulic conductivity was obtained, at DR-10. As shown in Table 1, the KGS method hydraulic conductivity estimates at DR-10 (located within the area of low saturated thickness) were one to two orders of magnitude lower than at DR-5 and DR-9, located west of the area of low saturated thickness. Assuming the estimate at DR-10 is representative of the area of low saturated thickness, the transmissivity (the product of hydraulic conductivity and saturated thickness) of the area of low saturated thickness is two to three orders of magnitude lower than for the area of larger saturated thickness to the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 45 west (near DR-2 [abandoned], DR-5, and DR-9). Figures 5 and 25 show that the hydraulic gradient in this area is relatively flat; the gradient does not change significantly across the area of low saturated thickness, but flattens to the west (downgradient) of the area. Water flows westward from the area of the TMS through the area of low saturated thickness between DR-6 and DR-10 (Figure 25). The fourth quarter, 2021 saturated thicknesses at DR-6 and DR-10 are approximately 2 feet and 2.8 feet, respectively, averaging approximately 2.4 feet. Using Darcy’s Law, and assuming a hydraulic conductivity of 3 x 10-6 cm/s (0.0084 feet per day [ft/day], based on the KGS estimate provided for DR-10 in Table 1), an average hydraulic gradient of approximately 0.0058 ft/ft, an average saturated thickness of approximately 2.4 ft, and a width of approximately 1,600 feet (the approximate distance between DR-6 and DR-10), the rate of perched water flow westward through the area of low saturated thickness is approximately 0.187 cubic feet per day (ft3/day) or 0.00097 gpm. Water flows out of the area of larger saturated thickness (near DR-2 [abandoned] and DR-5) to the northeast toward known discharge point Westwater Seep and to the south through the paleovalley leading towards known discharge point Ruin Spring. The rate of flow out of this area northeast to Westwater Seep is expected to be smaller than the discharge rate at Westwater Seep which also receives water from the east and northeast. The discharge rate at Westwater Seep is too small for a reliable estimate. However, the rate of flow south through the paleovalley leading towards Ruin Spring can be calculated using the geometric average hydraulic conductivity of 0.0089 ft/day (based on KGS estimates for DR-8 [October, 2012 estimate], DR-9, and DR-10 in Table 1), an approximate hydraulic gradient of 0.0080 ft/ft (between DR-9 and DR-14), an average saturated thickness of approximately 12 ft, and a width of approximately 2,250 ft (between DR-8 and DR-10), as 1.9 ft3/day, or approximately 0.01 gpm, an order of magnitude larger than the calculated flow into the area. The difference between calculated inflow and outflow is approximately 0.009 gpm. These calculations indicate that an additional water source is needed to maintain the relatively large saturated thicknesses west of the area of low saturated thickness between DR-6 and DR-10; otherwise Westwater Seep and the paleovalley to the south would drain the area of larger saturated thickness more quickly than water was supplied. The most likely source of additional water is infiltration of precipitation enhanced by the direct exposure of weathered Dakota Sandstone and Burro Canyon Formation, and the thinness or absence of any overlying low permeability materials such as the Mancos Shale. Assuming uniform recharge over the portion of the mesa west of Westwater Seep and north of DR-8 and DR-9 (an area of approximately 175 acres, or 7.6 x 106 square feet [ft2]), the calculated difference of 0.009 gpm implies a conservatively low recharge rate of approximately 0.001 inches per year (in/yr). Most of the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 46 recharge likely occurs near the mesa rim where the Dakota Sandstone and Burro Canyon Formation are exposed (Figure E.1 and Figure E.2, Appendix E). Such recharge is expected to be enhanced within drainages where they cross weathered Dakota Sandstone and Burro Canyon Formation. Furthermore, these calculations indicate that perched water flow in the portion of the site south of Westwater Seep is inadequate as a primary supply to Cottonwood Seep. Perched water flow from the area of the TMS through the area of low saturated thickness towards Cottonwood Seep would have to be more than three orders of magnitude higher than calculated above to provide a supply of between approximately 1 and 10 gpm. The required flow would have to be even larger considering that some of the incoming flow is diverted to known discharge point Westwater Seep and to the paleovalley that leads south to known discharge point Ruin Spring. Even if this calculation were performed using the geometric average of the KGS hydraulic conductivity estimates for all tested DR-series piezometers (approximately 1 x 10-5 cm/s or 0.028 ft/day) rather than the estimate for DR-10 (3 x 10-6 cm/s or 0.0084 ft/day), the calculated rate of flow through the area of low saturated thickness would be approximately 0.0032 gpm, which is still approximately three orders of magnitude lower than the estimated discharge rate of Cottonwood Seep. The inadequacy of the perched zone as the primary supply to Cottonwood Seep indicates that the primary source or sources of Cottonwood Seep lie elsewhere. 3.5.4.3 Water Balance Near Ruin Spring and Westwater Seep Figure 26 is a map showing inferred perched groundwater pathlines in the immediate vicinities of Ruin Spring and Westwater Seep. These pathlines were used to estimate expected flow rates to these features based on Darcy’s Law using local hydraulic gradients, saturated thicknesses, and hydraulic conductivity estimates. Saturated thicknesses posted on Figure 26 were calculated as the difference between kriged fourth quarter, 2021 water level and top of Brushy Basin Member surfaces. The water level contours plotted on Figure 26 do not demonstrate the increase in hydraulic gradient that would generally be expected when groundwater approaches a discharge point such as Ruin spring (or an extraction well). However, the increase in hydraulic gradient is evident if an additional data point, DR-25 (Figure 1A), is considered. Boring DR-25 was abandoned during 2011; however, as shown in Figure 20, water levels at DR-series piezometers have been stable. Therefore, the water level at abandoned boring DR-25 at the present time would likely be about the same as the second quarter, 2011 water level that was included in Figure 19. As shown in Figure 19 the water table (and hydraulic gradient) show the expected steepening approaching Ruin Spring. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 47 The area of the perched zone providing flow to Ruin Spring was estimated by assuming the flow is approximately divided between Ruin Spring to the west and Corral Springs to the east. This division coincides approximately with a groundwater divide that extends southwest from the southern wildlife pond toward Ruin Spring, approximately parallel to the southeasternmost flow path depicted on Figure 21. Using the geometric average hydraulic conductivity based on estimates at DR-21, DR-23, and DR-24 (2.2 x 10-5 cm/s or 0.062 ft/day based on KGS analysis of automatically logged slug test data [Table 6]), which are closest to Ruin Spring, an average hydraulic gradient of approximately 0.011 ft/ft, and an average saturated thickness of approximately 15.5 feet over a width of approximately 8,400 feet (along the 5420 foot elevation contour), yields a rate of perched flow of approximately 80 ft3/day or 0.42 gpm. The calculated value of 0.42 gpm is slightly less than the estimated average flow for Ruin Spring of approximately 0.5 gpm. Assuming that the difference between the calculated perched water flow and the estimated flow at Ruin Spring (0.08 gpm or approximately 15 ft3/day) is due to local recharge over the area of Figure 26 covered by the inferred flow paths (approximately 420 acres or 18.3 x 106 ft2), then the local recharge rate needed to make up the difference is approximately 8.2 x 10-7 ft/day or 0.0036 in/yr. If the average flow for Ruin Spring were as high as 1 gpm, then approximately 0.58 gpm, or 0.027 in/yr of local recharge would be needed to make up the difference. Both estimates of local recharge are relatively small and within a range that is reasonable considering the topography and surface lithology of this portion of the site. Perched groundwater flow to Westwater Seep was similarly estimated. Hydraulic conductivities used in the calculations are summarized in Table 6. Hydraulic conductivity estimates at DR-5, DR-8, DR-9, DR-10, and DR-11 are based on automatically logged slug test data analyzed using the KGS solution method; estimates at MW-12, MW-14, and MW-15 are based on pumping test analyses reported in TITAN (1994) [Table 4]. Estimates from DR-2, DR-16, and DR-17 are not available as hydraulic tests could not be performed because these borings were abandoned after surveying and water level collection based on the criteria presented in HGC (2012b). Tests also could not be performed at DR-6 nor DR-7 due to an insufficient water column. Using a geometric average hydraulic conductivity of 9.8 x 10-6 cm/s (0.027 ft/day), an average hydraulic gradient of 0.013 ft/ft, and an average saturated thickness of 5 feet over a width of approximately 3,300 feet, yields a rate of perched flow of approximately 5.8 ft3/day or 0.03 gpm. If the geometric average of the hydraulic conductivities estimated at the four closest wells (MW- 23, MW-24, MW-35, and DR-5) is substituted (1.8 x 10-5 cm/s [0.05 ft/day]), the calculated rate of perched flow is 10.7 ft3/day or 0.056 gpm. In calculating the latter average, the highest estimate from the MW-24 test was used. Because the flow to Westwater Seep is too small to be reliably measured (as discussed in Section 3.7), either result is considered reasonable. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 48 3.6 Perched Water Migration Rates and Travel Times Perched groundwater pore velocities and travel times along selected pathlines shown in Figure 27 were calculated using Darcy’s Law. The calculated pore velocities and travel times are representative of the movement of a conservative solute assuming no hydrodynamic dispersion. Hydraulic conductivity estimates used for pathlines 1, 2A, and 2B are summarized in Table 7, and for pathlines 3 through 6 in Table 8. Pore velocity estimates are summarized in Table 9. 3.6.1 Nitrate Investigation Area Perched groundwater pore velocities and travel times were calculated along Path 1 (Figure 27) located within the nitrate plume. Path 1 is approximately 1,940 feet long. Under current conditions, a particle migrating along Path 1 would be captured by nitrate pumping well TW4-24 (near the center of the plume). The average hydraulic conductivity along Path 1 is assumed to be the geometric average of the conductivities of wells located within and immediately upgradient and downgradient of the nitrate plume (wells TWN-2, TWN-3, TWN-18, TW4-21, TW4-22, TW4-24, TW4-25, TW4-37, MW-11, MW-27, MW-30, and MW-31) as estimated by analyzing automatically logged slug test data using the KGS solution (Table 7). Using a geometric average conductivity of 1.19 x 10-4 cm/s (0.33 ft/day), a hydraulic gradient of 0.0165 ft/ft, and a porosity of 0.18, the estimated average pore velocity along Path 1 is approximately 11 ft/yr. This implies that, under current conditions, approximately 176 years would be required to traverse Path 1. Historic hydraulic gradients within the area of the nitrate plume were likely substantially larger than 0.0165 ft/ft during the time prior to Mill construction when the historical pond was active (Figure 1B). The depth to water at TWN-2, located within the former footprint of the historical pond (Figure 1B), was approximately 16 feet bls prior to its conversion to a nitrate pumping well. The relatively small depth to water is interpreted to result from the relatively low perched zone permeability at TWN-2 (approximately 1.5 x 10-5 cm/s) and slightly elevated recharge by precipitation resulting from the relatively flat topography in that portion of the site. When the historical pond was active and ponded water was present in the vicinity of TWN-2, depths to water were likely negligible as the associated groundwater mound likely reached an elevation just beneath the pond bottom. Historic water level maps (Appendix D) show that water levels in the vicinities of MW-30 and MW-31, located along the downgradient margin of cell 2, and at the downgradient margin of the nitrate plume, were approximately 5,520 feet amsl. Assuming that the perched water level beneath the historical pond was close to the pond bottom (approximately 5,625 feet amsl), the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 49 perched water level at the downgradient edge of cell 2 was approximately 5,520 feet amsl, and the distance between the southern edge of the historical pond and the downgradient edge of cell 2 was approximately 2,200 feet, the historic hydraulic gradient is calculated as approximately 0.048 ft/ft. This estimate is more than four times the overall average site hydraulic gradient of approximately 0.011 ft/ft (calculated between TWN-19 and Ruin Spring). Using the geometric average hydraulic conductivity of 0.33 ft/day (as discussed above), the estimated historic hydraulic gradient of 0.048 ft/ft, and a porosity of 0.18, the estimated historic pore velocity downgradient of the historical pond is approximately 32 ft/yr, implying that nitrate originating from the historical pond could have migrated to the downgradient edge of cell 2 within 69 years. Assuming the historical pond was active circa 1920, that nitrate was conservative, and ignoring hydrodynamic dispersion, nitrate originating from the historical pond could have reached the vicinities of MW-30 and MW-31 by 1989. 3.6.2 Vicinity of Chloroform Plume Perched groundwater pore velocities and travel times along Paths 2A and 2B (Figure 27), located within the vicinity of the chloroform plume, were calculated. Path 2A is approximately 1,045 feet long and path 2B is approximately 1,080 feet long. Under current conditions, a particle migrating along Path 2A would be captured by chloroform pumping well MW-26, and. a particle migrating along Path 2B would be captured by chloroform pumping well TW4-2. In evaluating average hydraulic conductivities along these paths, estimates assuming both confined and unconfined conditions were used. This methodology is considered appropriate for this area of the site because of the potential for semi-confined conditions to exist at least locally (HGC, 2004). The average hydraulic conductivity along Path 2A is assumed to be the geometric average of the conductivities of nearby wells MW-26, TW4-5, TW4-9, TW4-10, TW4-18 and TW4-39 (Table 7). Using a geometric average conductivity of 3.23 x 10-4 cm/s (0.9 ft/day), a hydraulic gradient of 0.0344 ft/ft, and a porosity of 0.18, the estimated average pore velocity along Path 2A is approximately 63 ft/yr. This pore velocity implies that, under current conditions, approximately 17 years would be required to traverse Path 2A. The average hydraulic conductivity along Path 2B is assumed to be the geometric average of the conductivities of nearby wells MW-4A, TW4-2, TW4-8, TW4-9, TW4-28, TW4-32 and TW4-38 (Table 7). Estimates based on the early time data for MW-4A (formerly located approximately 10 feet south of MW-4) were used in calculating the averages because these data are considered more representative of conditions in the immediate vicinity of MW-4. Using a geometric average conductivity of 1.18 x 10-4 cm/s (0.33 ft/day), a hydraulic gradient of 0.057 ft/ft, and a porosity Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 50 of 0.18, the estimated average pore velocity along Path 2B is approximately 38 ft/yr. This pore velocity implies that, under current conditions, approximately 28 years would be required to traverse Path 2B. Historic hydraulic gradients within the northern (upgradient) areas of the eastern portion of the chloroform plume (prior to about 1990) were likely larger and contributed to relatively rapid movement of chloroform from the abandoned scale house leach field (located immediately north of TW4-18) to MW-4 where chloroform was detected in 1999. The assumptions are made that 1) water levels near the abandoned scale house leach field were affected relatively early by wildlife and/or historical pond seepage (owing to the close proximity of the northern wildlife ponds and historical pond); and 2) that the water level at TW4-18, which was relatively stable and averaged approximately 5,586 ft amsl between installation in 2002 and cessation of water delivery to the northern wildlife ponds in 2012, is representative of the water level at the leach field circa 1980. Based on these assumptions and the historic water level maps provided in Appendix D, the hydraulic gradient over the approximate 1,200 foot distance between the abandoned scale house leach field and MW-4 was approximately 0.048 ft/ft in 1990 and approximately 0.029 ft/ft in 1999, averaging 0.038 ft/ft. This is more than three times the overall average site hydraulic gradient of approximately 0.011 ft/ft (calculated between TWN-19 and Ruin Spring) but is within the range of hydraulic gradients occurring at present within and adjacent to the chloroform plume, and is similar to the current hydraulic gradient of approximately 0.041 ft/ft just east the plume, between non-pumping wells TW4-36 and TW4-27. Using a geometric average hydraulic conductivity of 1.1 ft/day based on Table 3 estimates from wells MW-4A, TW4-5, TW4-9, TW4-10, and TW4-18 (located near a line connecting MW-4 with the abandoned scale house leach field), an estimated historic hydraulic gradient of 0.038 ft/ft, and a porosity of 0.18, the calculated average pore velocity prior to 1999 was approximately 84 ft/yr. This is sufficient for chloroform to have migrated from the abandoned scale house leach field to MW-4 between 1978 and 1999. This calculation implies that chloroform could have migrated nearly to TW4-4 by 1999. 3.6.3 Beneath and Downgradient of Tailings Management System Estimated times for a hypothetical conservative solute originating from the TMS to migrate downgradient to known discharge points Westwater Seep and Ruin Spring assuming no dispersion are calculated in the following Sections. Because the hypothetical conservative solute is assumed to originate from individual cells within the system, the time for the solute to migrate downward from the base of a cell to the perched water must be taken into account. Vadose zone travel times are estimated in Section 3.6.3.1. Total travel times are estimated in Section 3.6.3.2. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 51 3.6.3.1 Vadose Zone Depths to perched groundwater near cell 2 vary from approximately 66 feet btoc near the northeast (upgradient) corner of the cell to approximately 110 feet btoc at the northwest corner of the cell. Depths to water near cell 3 vary from approximately 69 feet btoc near the northeast (upgradient) corner of the cell to approximately 114 feet btoc at the southwest (downgradient) corner of the cell. Depths to water near cells 4A and 4B vary from approximately 81 feet btoc near the northeast (upgradient) corner of cell 4A to approximately 114 feet btoc along the western margin of cell 4B. The average depth to water near cell 2 is approximately 80 feet btoc; near cell 3 approximately 92 feet btoc; and near cells 4A and 4B approximately 104 feet btoc. Because the cells are installed a maximum of approximately 25 feet below grade, the average depth to perched water from the base of cell 2 is approximately 55 feet; beneath cell 3 approximately 67 feet; and beneath cells 4A and 4B approximately 79 feet. Any seepage through the cell liners would have to travel downward through approximately 55 feet of vadose materials to impact perched water beneath cell 2; through approximately 67 feet to impact perched water beneath cell 3; and through approximately 79 feet to impact perched water beneath cells 4A and 4B. Knight-Piésold (1998) estimated a maximum volumetric seepage rate for cell 3 based on cell construction and liner characteristics, of approximately 80 cubic feet per day (ft/day) or 0.42 gpm over the entire cell. Most of this seepage was estimated to be via diffusion through the liner. This rate was estimated to decrease over time as the cell desaturates once the final cover is emplaced. Assuming a cell footprint of 3.38 x 106 ft2, this maximum rate is equivalent to 2.37 x 10-5 ft/day or 0.0086 ft/yr. The average saturation expected in vadose bedrock beneath the TMS is approximately 20% based on saturations measured in bedrock samples presented in Table 5 (from TITAN, 1994). Assuming that the Knight-Piésold estimates from cell 3 are also representative of cell 2 and cells 4A and 4B, and assuming that this rate of seepage would not significantly raise the average saturation of the underlying vadose zone materials, the average rate of downward movement of a conservative solute dissolved in the seepage, assuming 1) no hydrodynamic dispersion, 2) an average water saturation of 0.20, and 3) an average porosity of 0.18, can be approximated as: yrftyrft/24.0)18(.)20(. /0086.0 = Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 52 The average times to travel from cell liners to the perched water zone would then be approximately 229 years beneath cell 2; 279 years beneath cell 3; and 329 years beneath cells 4A and 4B. These are conservative estimates because the maximum estimated seepage rate is used, and the average vadose zone water saturations would be likely to increase (because some of the seepage would go into storage), thereby reducing the downward rates of travel, and increasing the travel times. Numerical modeling of potential TMS seepage and rates of downward migration of solutes are provided in MWH (2010). Based on Figure A-3 from MWH (2010), the simulated seepage rates beneath cells 2 and 3 would reach a maximum of approximately 7.7 millimeters per year (mm/yr) [0.025 ft/yr] by year 25, then drop to approximately 0.7 mm/yr (0.0023 ft/yr) by year 70. The average seepage rate over the 240 year simulation period is approximately 0.0043 ft/yr, half the estimate used in the above calculations. Using this rate with the above assumptions would double the travel times estimated for seepage to reach perched water beneath cells 2, 3, and 4A and 4B. However, the MWH analyses used smaller initial water saturations for the vadose zone which correspondingly reduced travel time estimates. Based on personal communication with MWH personnel, a 200+ year vadose zone travel time estimate for cells 2 and 3 is considered reasonable. The estimates calculated above for cell 2 (229 years), cell 3 (279 years) and cells 4A and 4B (329 years) will be used in subsequent calculations. Because cells 2 and 3 are at least 38 years old, the travel times starting from the present time will be 191 years for cell 2, and 241 years for cell 3. Cell 4B was installed in 2010 and cell 4A refurbished and put into use shortly thereafter so the effective travel time will be assumed to be 317 years for these cells. Furthermore, the estimates for cells 4A and 4B are considered even more conservative because of improvements in cell design and liner quality that were incorporated in these cells but were not available during construction of cells 2 and 3. 3.6.3.2 Perched Water Zone Downgradient of Tailings Management System Perched groundwater pore velocities and travel times along selected paths between the existing TMS and perched water discharge points were calculated for pathlines 3 through 6 shown in Figure 27. The Figure 27 pathlines were selected as the shortest Figure 25 paths from the TMS to a) Westwater Seep (Path 3), b) Ruin Spring via the west side of the Brushy Basin paleoridge (Path 5), and c) Ruin Spring via the east side of the Brushy Basin paleoridge (Path 6). A pathline from the TMS to the vicinity of DR-8 (Path 4) is also shown on Figure 27. From the vicinity of DR-8 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 53 perched water is expected to flow primarily south (within a paleovalley) toward Ruin Spring. However, a potential pathline from the vicinity of DR-8 is also shown in Figure 27 that posits a hypothetical connection between the perched zone and Cottonwood Seep. Path 4 provides the shortest pathline between the TMS and the western edge of the perched zone near DR-8, and the potential path provides the shortest hypothetical connection between the western edge of Path 4 and Cottonwood Seep. Hydraulic conductivities used in the calculations are summarized in Table 8. Hydraulic conductivity estimates are based on automatically logged slug test data analyzed using the KGS solution method, except for MW-12, MW-14, and MW-15. Hydraulic conductivity estimates at MW-12, MW-14, and MW-15 are based on pumping test analyses reported in Table 4 (from TITAN, 1994). Hydraulic tests could not be performed at DR-2, DR-16, DR-18, nor DR-25. These borings were abandoned after surveying and water level collection based on the criteria presented in HGC (2012b). Tests also could not be performed at DR-6 nor DR-7 due to insufficient water column height. Pore velocity calculations for pathlines 3 through 6 are summarized in Table 9. Path 3 is approximately 2,200 feet long with an average hydraulic gradient of 0.0136 feet per foot (ft/ft) based on the fourth quarter, 2021 water level at MW-23 (5,498 ft amsl) and the elevation of Westwater Seep (5,468 ft amsl). The geometric average hydraulic conductivity of the perched zone in the vicinity of Path 3 (based on data from DR-5, DR-8, DR-9, DR-10, DR- 11, MW-12, MW-23, MW-24, and MW-36) is 9.8 x 10-6 cm/s (0.027 ft/day or 10 ft/yr). Assuming an effective porosity of 0.18, the average perched water pore velocity along Path 3 is 0.76 feet per year (ft/yr), yielding a travel time of approximately 2,895 years. Including a vadose zone travel time of approximately 279 years for cell 3, the total travel time is approximately 3,175 years. Path 4 is approximately 4,125 feet long with an average hydraulic gradient of 0.0046 ft/ft based on the fourth quarter, 2021 water level at MW-36 (5,493 ft amsl) and the water level at DR-8 (5,474 ft amsl). The geometric average hydraulic conductivity of the perched zone in the vicinity of Path 4 (based on data from DR-5, DR-8, DR-9, DR-10, DR-11, MW-12, MW-23, MW-24, and MW-36) is 9.8 x 10-6 cm/s (0.027 ft/day or 10 ft/yr). Assuming an effective porosity of 0.18, the average perched water pore velocity along Path 4 is 0.26 feet per year (ft/yr), yielding a travel time of approximately 15,865 years. Including a vadose zone travel time of approximately 329 years for cell 4A, the total travel time is approximately 16,195 years. The additional time to travel along the hypothetical pathway to Cottonwood Seep is not calculated because of the hypothetical nature of the pathway and because the hypothetical pathway is through the Brushy Basin Member which is considered an aquiclude. If such a pathway exists, the combined travel Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 54 time along Path 4 and the hypothetical pathway (which adds approximately 2,150 horizontal feet to the total path length), would be significantly greater than 16,195 years. Path 5 is approximately 11,800 feet long with an average hydraulic gradient of 0.0096 ft/ft based on the fourth quarter, 2021 water level at MW-36 (5,493 ft amsl) and the elevation of Ruin Spring (5,380 ft amsl). The geometric average hydraulic conductivity of the perched zone in the vicinity of Path 5 (based on test data from DR-5, DR-8, DR-9, DR-10, DR-11, DR-14, DR-17, DR-19, DR-20, DR-21, DR-23, DR-24, MW-23, MW-24, and MW-36) is 1.1 x 10-5 cm/s (0.031 ft/day or 11.3 ft/yr). Assuming an effective porosity of 0.18, the average perched water pore velocity along Path 5 is 0.60 ft/yr, yielding a travel time of approximately 19,665 years. Including a vadose zone travel time of approximately 329 years for cell 4A, the total travel time is approximately 19,995 years. Path 6 is approximately 9,700 feet long with an average hydraulic gradient of 0.0116 ft/ft based on the fourth quarter, 2021 water level at MW-37 of 5,493 ft amsl and the elevation of Ruin Spring (5,380 ft amsl). The geometric average hydraulic conductivity of the perched zone in the vicinity of Path 6 (based on test data from DR-11, DR-13, DR-21, DR-23, MW-3, MW-14, MW- 15, MW-20 and MW-37) is 1.38 x 10-5 cm/s (0.039 ft/day or 14.1 ft/yr). Assuming an effective porosity of 0.18, the average perched water pore velocity along Path 6 is 0.91 ft/yr, yielding a travel time of approximately 10,660 years. Including a vadose zone travel time of approximately 329 years for cell 4B, the total travel time is approximately 10,990 years. 3.7 Implications for Seeps and Springs The lithologic and hydraulic data collected from the southwest area investigation (HGC 2012b) allow a more comprehensive assessment of the hydrogeology of the site and have implications with regard to seeps and springs southwest of the site. The data indicate that dilution of perched water by local recharge is expected to occur in the vicinities of Westwater Seep and Ruin Spring, and that perched zone permeabilities and flow rates in the southwestern portion of the site are too low (by several orders of magnitude) for the perched zone to serve as the primary source of water for Cottonwood Seep. 3.7.1 Westwater Seep and Ruin Spring As discussed in HGC (2010g) the water source for both Westwater Seep and Ruin Spring is lateral flow from upgradient portions of the perched zone enhanced by local recharge near the edge of the mesa. Most of this recharge likely occurs near the mesa rim where weathered Dakota Sandstone and Burro Canyon Formation are largely exposed. Such recharge is likely to be Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 55 enhanced within drainages where they cross weathered Dakota Sandstone and Burro Canyon Formation. The results of the southwest area investigation (HGC, 2012b) indicate that the permeability of the perched zone in the southwest area of the site is on average lower than was estimated prior to 2010 (as in HGC, 2009) and that the contribution to flow at Westwater Seep and Ruin Spring by local recharge may be more significant than previously thought. 3.7.2 Cottonwood Seep The low perched zone permeabilities and small saturated thicknesses in the southwest area of the site are consistent with low rates of perched water flow, as shown by the calculated flow through the area of small saturated thickness southwest of the TMS (between DR-6 and DR-10) provided in Section 3.5.4.2. This low rate of perched water flow (approximately 0.00097 gpm) is inadequate (by more than three orders of magnitude) to function as the primary supply to Cottonwood Seep which has historic flows estimated to lie between 1 and 10 gpm. As discussed in Section 3.5.4.2, the estimated flow of between 1 and 10 gpm at Cottonwood Seep is consistent with Dames and Moore (1978). In summary, the perched zone cannot be the primary source of water to Cottonwood Seep for the following reasons: 1. Cottonwood Seep occurs in the lower third of Brushy Basin Member, approximately 230 feet below the contact between the Burro Canyon Formation and the Brushy Basin Member, more than 1,500 ft west of the termination of the perched zone, and just west of a change in morphology from slope-former to bench-former. The change in morphology is indicative of a change in lithology. As discussed in HGC (2010g) Cottonwood Seep likely originates from coarser-grained materials within the lower portion of the Brushy Basin Member. Alternatively, Cottonwood Seep may originate from coarser-grained materials of the Westwater Canyon (sandstone) Member intertongueing with the overlying Brushy Basin Member at the transition between the two Members. The presence of coarser-grained materials similar to the Salt Wash (sandstone) Member within the lower portion of the Brushy Basin member is discussed in Shawe (2005). The intertongueing of the Westwater Canyon and Brushy Basin Members is discussed in Craig et al. (1955) and Flesch (1974). Based on lithologic cross sections provided in TITAN (1994), the elevation of Cottonwood Seep (5,234 ft amsl) is within 5 to 15 feet of the elevation of the contact between the Brushy Basin Member and the underlying Westwater Canyon Member (5,220 to 5,230 ft amsl). This is also shown in Figure 3. 2. The historic flow at Cottonwood Seep exceeds the flow in the perched zone in the area southwest of the TMS by several orders of magnitude. Historic flows at Cottonwood Seep are relatively large compared to seeps and springs known to originate from the perched zone, consistent with a primary source other than perched water. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 56 3. There is no evidence to establish a direct hydraulic connection between the perched zone and Cottonwood Seep, located more than 1,500 ft west of the termination of the Burro Canyon Formation which hosts the perched water zone. Examination of the area between Cottonwood Seep and mesa rim (the edge of the perched zone) reveals that the upper portion of the Brushy Basin Member appears dry and no previously undiscovered seeps originating from the Burro Canyon Formation near Cottonwood Seep were identified. Because the results of the southwest area investigation do not provide evidence that Cottonwood Seep is hydraulically connected to the perched water system at the site, and because the perched zone near Cottonwood Seep is inadequate as a primary supply, the primary source (or sources) of water to Cottonwood Seep must lie elsewhere. The primary source(s) must be significant to supply consistent historic flows at rates between 1 and 10 gpm. By contrast, flows at Ruin Spring (estimated at approximately 1/2 gpm, consistent with Dames and Moore, 1978) are lower than at Cottonwood Seep (historically between 1 and 10 gpm), and flows at Westwater Seep are too small to measure reliably. Westwater Seep generally consists of damp soil that can be sampled only by excavating and waiting for enough water to seep in for sample collection (see Figures 28 and 29 taken from HGC, 2010g). Although no evidence of a direct hydraulic connection between the perched zone and Cottonwood Seep was provided by the southwest area investigation, the possibility of a hypothetical, as yet unknown, connection was postulated for the purpose of calculating a travel time from the TMS to the western edge of the perched zone (near DR-8), and thence along a potential pathway to Cottonwood Seep. The total travel time from the TMS to DR-8 was calculated as approximately 16,195 years. Should a potential pathline such as that shown in Figure 27 exist, the total time needed to travel from the TMS to Cottonwood Seep would be significantly larger than 16,195 years. 3.7.3 Potential Dilution of Perched Water Resulting from Local Recharge of the Dakota and Burro Canyon Near Seeps and Springs As discussed in Section 3.5.4.2, the rate of flow in the perched water zone in the southwest area of the site is small and a contribution from local recharge is needed to explain many areas of relatively high saturated thickness near discharge points such as Westwater Seep and Ruin Spring that are downgradient of areas of relatively low saturated thickness. The presence of local recharge is expected to affect the water quality of seeps and springs and has the potential to dilute any dissolved constituents that may migrate from upgradient areas. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 57 3.8 Implications for Transport of Chloroform and Nitrate Chloroform and nitrate plumes are under remediation by pumping. Pumping systems are designed to remove chloroform and nitrate mass from the perched zone as quickly as is practical to allow natural attenuation in the far downgradient portions of the plumes to be more effective. Furthermore, nitrate pumping is designed to capture approximately the northern 2/3 of the nitrate plume. Pumping at the downgradient margin of the chloroform plume has generally been impractical primarily due to low permeability and low productivity conditions. Only one chloroform pumping well, TW4-40, is both positioned at the downgradient edge of the plume and within materials having permeabilities large enough to support meaningful pumping and mass removal rates. Pumping at the downgradient margin of the nitrate plume (at MW-30 and MW-31) has also been impractical primarily because of the potential to draw chloroform downgradient. In the absence of remedial pumping, the western portion of the nitrate plume would eventually migrate towards Westwater Seep and the eastern portion toward Ruin Spring (Figure 21 and Figure 30). However, as discussed in HGC (2018e), numerical flow and transport modeling using conservatively large hydraulic conductivities and hydraulic gradients, and conservatively small dispersivities, demonstrates that natural attenuation, even in the absence of nitrate reduction by pyrite and mass removal by pumping, would reduce all concentrations within the nitrate plume to less than the 10 mg/L GCAL before reaching a property boundary. In the absence of remedial pumping, the western portion of the chloroform plume would eventually migrate towards Ruin Spring and the eastern portion toward the perched groundwater low defined by TW4-35 and recently installed well TW4-43 (Figures 22 and 30). Should this low eventually disappear, chloroform within the eastern extremity of the plume would be expected to migrate towards the lobe of the White Mesa between Ruin and Corral Springs. In addition, the continuing decay of the perched groundwater mound associated with the southern wildlife pond and the resulting more southerly to southwesterly flow within the southern portion of the plume, is expected to place Ruin Spring downgradient of the entire plume. As indicated by calculations in Section 3.6, thousands of years would be required for either the chloroform or nitrate plume to reach a discharge point. That is sufficient time for both chloroform and nitrate to degrade naturally prior to reaching a discharge point as will be discussed in Section 4.4. Furthermore, as discussed above, numerical flow and transport modeling using conservative assumptions demonstrates that all concentrations within the nitrate plume would be reduced to less than the 10 mg/L GCAL before reaching a property boundary, even in the absence of mass removal by pumping and pyrite degradation. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 58 Groundwater lows at TW4-35 and relatively recently installed well TW4-43 are interpreted to result from partial hydraulic isolation from upgradient and cross-gradient areas that were more strongly affected by wildlife pond seepage. Prior to 2012, wildlife pond seepage resulted in increases in water levels at wells in the vicinity of TW4-27 as shown in Figure 31. Prior to 2012, water levels in wells TW4-6, TW4-26, and TW4-13 rose relatively rapidly compared with water levels at TW4-14. The permeabilities of TW4-6 and TW4-26 are similar (Table 1) and both exhibit similar water level behavior. The permeability at TW4-27 is relatively low (Table 1), and the similar water level behavior at TW4-14 and TW4-27 between 2012 and 2014 suggests that TW4-14 is also installed in low permeability materials. After 2012, water levels at TW4-27 began to stabilize; however water levels at TW4-14 continued to increase until about 2018 before reaching relative stability. These differences in water level behavior are likely due to the relative distances of these wells from the northern and southern wildlife ponds. That both wells are having a delayed response to reduced wildlife pond recharge is also consistent with low permeability at both locations. The low permeability at TW4-27, the inferred low permeability at TW4-14, and the low permeability at TW4-36 (Table 1) suggests that a continuous low-permeability zone extends from TW4-27 through TW4-14 to TW4-36. These low permeability materials are the likely cause of the partial hydraulic isolation of TW4-35 and TW4-43. Because the groundwater lows at these wells are interpreted to result from variable permeability and from transient hydraulic conditions brought on by former wildlife pond seepage, water levels in this area are expected to ‘catch up’ eventually with water levels in less hydraulically isolated areas. Water balance calculations near Westwater Seep and Ruin Spring (Section 3.5.4.3) indicate that local recharge is needed to maintain areas having relatively large saturated thicknesses that supply water to known discharge points Westwater Seep and Ruin Spring but that are isolated from other portions of the perched zone by areas of relatively low saturated thickness. The presence of local recharge near these discharge points at least partly explains reported increased flow at these features after precipitation events (HGC, 2010g). In the unlikely event that nitrate or chloroform not removed by pumping did not degrade within the thousands of years needed to reach a discharge point, local recharge would act to reduce concentrations prior to discharge. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 59 4. COMPOSITION OF DAKOTA SANDSTONE AND BURRO CANYON FORMATION As discussed in HGC (2012c), samples of selected archived drill core and drill cuttings were analyzed visually and quantitatively by an analytical laboratory. Table 10 summarizes the mineralogy of samples submitted to the contract laboratory for quantitative analysis. Table 11 summarizes the occurrence of pyrite, iron oxides, and carbonaceous material in site drilling logs having sufficient detail. Table 12 summarizes the results of laboratory visual (microscopic) analyses for sulfides. Table 13 and Figure 32 summarize the occurrence of pyrite in site borings based on both lithologic logs and laboratory analyses. 4.1 Mineralogy As discussed in Section 3.1.2, the Dakota Sandstone is a relatively hard to hard, generally fine- to-medium grained sandstone cemented by kaolinite clays. The underlying Burro Canyon Formation is similar to the Dakota Sandstone but is generally more poorly sorted, contains more conglomeratic materials, and becomes argillaceous near its contact with the underlying Brushy Basin Member of the Morrison Formation. Because of the similarity of the Burro Canyon Formation and Dakota Sandstone they are typically not distinguished in lithologic logs at the site. Based on quantitative analysis of samples for major and minor mineralogy (Table 10), the primary mineral occurring in the Burro Canyon Formation is quartz (greater than or equal to 80% in all analyzed samples except SS-26 which consisted of ‘play sand’). Other detected minerals (not necessarily present in all the samples) include potassium feldspar, plagioclase, mica, kaolinite, calcite, dolomite, anhydrite, gypsum, pyrite, hematite, and magnetite. Because of their relatively high reactivity, pyrite, calcite and dolomite are expected to have the most potential to impact perched water chemistry. The presence of carbonaceous matter (Table 11) is also expected to impact perched water chemistry. 4.2 Pyrite Occurrence As discussed in Section 3.1.4 pyrite occurs within the Dakota Sandstone and Burro Canyon Formations which host the perched groundwater at the site. Table 11 summarizes the occurrence of pyrite, iron oxides, and carbonaceous material in site lithologic logs. These logs were based on field logging of drill cuttings and/or core samples at the time of drilling. Pyrite has been noted in approximately 2/3 of site borings having detailed lithologic logs. These borings are located upgradient, cross-gradient and downgradient of the Mill site and TMS. In addition, carbonaceous Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 60 material has been noted at many locations which is consistent with at least locally reducing conditions and the existence of pyrite (Table 11). As discussed in HGC (2012c), samples of selected archived drill core and drill cuttings were analyzed visually and quantitatively by a contract analytical laboratory. Table 13 and Figure 32 summarize the occurrence of pyrite in site borings based on lithologic logs and laboratory analyses. The results of the visual and quantitative analyses verify the site-wide, apparently ubiquitous existence of pyrite in the perched zone at the site. The existence of pyrite is confirmed at locations upgradient, cross-gradient, and downgradient of the Mill site and TMS. The results are consistent with Shawe’s (1976) description of the Dakota Sandstone and Burro Canyon Formations as “altered-facies” rocks within which pyrite formed as a result of invasion by pore waters originating from compaction of the overlying Mancos Shale. Pyrite and/or marcasite were detected in all samples submitted for visual (microscopic) analysis (Table 12) having pyrite noted in their respective lithologic logs. Pyrite occurs primarily as individual grains and as a cementing material, and more rarely as inclusions in quartz grains. Pyrite and/or marcasite were detected in the samples at volume percents ranging from approximately 0.05 to 25. Grain sizes ranged from approximately one micrometer to nearly 2,000 micrometers. Small grain sizes suggest that much of the pyrite present in the formation may not be detectable during field lithologic logging of boreholes and that the actual abundance of pyrite is larger than indicated by the lithologic logs. The detection of marcasite (orthorhombic crystalline FeS2), which is more reactive than pyrite (cubic crystalline FeS2), is an important result of the investigation because its reaction rate with either oxygen or nitrate will likely be higher. The laboratory visual (microscopic) analyses confirm the visual observations made during field lithologic logging. Pyrite was detected by quantitative x-ray diffraction (XRD) analysis in samples from MW-3A, MW-24, MW-26, MW-27, MW-28, and MW-32 at concentrations ranging from 0.1% to 0.8% by weight (Table 10). Based on the iron content via XRD analysis and the total sulfur analysis, pyrite may also be present in samples from MW-23, MW-25, and MW-29 at concentrations ranging from 0.1% to 0.3%. The presence of pyrite is not indicated in MW-30 or MW-31 by either method of analysis, although it was noted in the lithologic logs. This suggests that the samples submitted for analysis from these borings may not have been representative, or that pyrite degraded over time during storage. Except for MW-30 and MW-31, the quantitative analyses confirm the visual observations made during field lithologic logging. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 61 Although pyrite was not directly detected by XRD in samples from MW-23, MW-25, or MW-29, the detected iron and sulfur in these samples is consistent with the presence of pyrite. While at least a portion of the detected sulfur may result from the gypsum or anhydrite detected in some of these samples (Table 10), iron not in the form of pyrite would be expected to exist primarily in the form of iron oxides or perhaps iron carbonates. The absence of detected iron oxides or carbonates in samples from these borings suggests iron in the form of pyrite. Furthermore, pyrite was either directly detected or possibly detected based on the presence of iron and sulfur in samples from MW-3A, MW-23, MW-24, MW-28, and MW-29, which did not have pyrite noted in the associated lithologic logs. These results are consistent with the small grain sizes noted via the laboratory visual (microscopic) analysis indicating the absence of pyrite in a lithologic log does not necessarily mean pyrite is not present in the associated boring, and that pyrite occurrence at the site has likely been underestimated based on the lithologic logs. In addition, pyrite was reported in the lithologic log for MW-24A (Appendix A), installed in 2019, and co-located with MW-24. 4.3 Expected Influence of Transient Conditions, Oxygen Introduction, and the Mancos and Brushy Basin Shales on Dakota/Burro Canyon Chemistry Current conditions within the perched groundwater system hosted by the Burro Canyon Formation and Dakota Sandstone do not approach steady state over much of the monitored area. A large part of the site perched water system is transient and affected by long-term changes in water levels due to past and current activities unrelated to the disposal of materials to the TMS. Changes in water levels have historically been related to seepage from the wildlife ponds; however past impacts related to the historical pond, and to a lesser extent the sanitary leach fields, are also expected. Water levels have decreased at many locations due to chloroform and nitrate pumping and reduced recharge from the wildlife ponds. The transient nature of a large portion of the perched water system, manifested in long-term changes in saturated thicknesses and rates of groundwater flow, is expected to result in trends in pH and in the concentrations of many dissolved constituents that are unrelated to site operations. Changes in saturated thicknesses and rates of groundwater flow can result in changes in concentrations of dissolved constituents (or pH) for many reasons. For example, as discussed in HGC (2012c), groundwater rising into a vadose zone having a different chemistry than the saturated zone can result in changes in pH and groundwater constituent concentrations. If the rise Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 62 in groundwater represents a long-term trend, long-term changes in groundwater constituent concentrations (or pH) may result. Under conditions where vadose zone chemistry is not markedly different from saturated zone chemistry, changing groundwater flow rates may result in changing constituent concentrations due to changes in dilution. For example, relatively constant flux of a particular solute into the groundwater zone, resulting in a relatively constant groundwater concentration under conditions of steady groundwater flow, will likely result in changing concentrations should groundwater flow become unsteady. If the change in flow rate is in one direction over a long period of time, a long-term trend in the solute concentration is expected to result. Examples include oxygen dissolved in recharge or a constituent present in vadose zone materials overlying perched groundwater that dissolves in recharge and leaches into perched water at a steady rate. An increase in perched flow may cause an increase in dilution and a reduction in constituent concentration and vice-versa. For example, the decrease in dilution related to reduced wildlife pond recharge has caused increases in dissolved constituent concentrations within the chloroform plume and, to a lesser extent, the nitrate plume as discussed in Section 3.4.1.2. Furthermore, the lined cells within the TMS are expected to act as barriers to natural recharge and exchange of gas with the atmosphere; their mere presence may thus result in changes in perched water chemistry. Any such changes are likely to be relatively slow and in one direction, potentially yielding long term trends in parameter values. The perched groundwater chemistry at the Mill is also expected to be impacted by the following factors: 1. The relatively low permeability of the perched zone. This condition increases groundwater residence times and the time available for groundwater to react with the formation. 2. The location of the perched system between two shales, the underlying Brushy Basin Member of the Morrison Formation and the overlying Mancos Shale. Both are potential sources of numerous dissolved constituents. Potential interaction between the Brushy Basin Member and perched water are discussed in TITAN (1994). The potential for natural contamination from the Mancos Shale is discussed in USDOE (2011). 3. The rate of interaction between the Mancos and Brushy basin Member shales and the perched water. Interaction with the Mancos Shale at any particular location will depend on the presence, thickness, and composition of the Mancos, the rate of recharge through the Mancos into the perched zone, and the saturated thickness and rate of groundwater flow in the perched zone. Interaction with the Brushy Basin Member at any particular location will depend on the composition of the Brushy Basin, and the saturated thickness and rate of flow in the perched zone. Oxygen introduced into site monitoring wells may Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 63 also react with the Brushy Basin Member and affect the chemistry of perched groundwater in contact with the Brushy Basin. 4. The rate of oxygen introduction into the perched zone via recharge or via site groundwater monitoring wells. Introduced oxygen is available to oxidize constituents such as pyrite, which impacts the local groundwater chemistry near each recharge source and near each well by releasing acid and sulfate. The resulting increased acidity can also destabilize various mineral phases in the aquifer matrix. The degree of impact on perched groundwater chemistry will depend on the amount of pyrite, the rate of oxygen transfer, the neutralization capacity and saturated thickness of the perched zone, and the rate of groundwater flow. 5. Elements other than iron and sulfur as contaminants in pyrite. Pyrite reacting with oxygen introduced into the formation will release these elements, potentially altering both the vadose zone and the groundwater chemistry. The likelihood of pyrite having significant contaminants (such as selenium) is enhanced considering its origin from fluids expelled from the Mancos Shale. As discussed in EFRI (2021b), bottle-roll tests using pyrite- bearing core from the formation hosting perched groundwater at the site yielded bottle- roll solutions initially consisting of laboratory-grade DI water generating as much as 74 µg/L beryllium; 118 µg/L cadmium; 79 µg/L cobalt; 959 µg/L copper; 4,120 µg/L manganese; 278 µg/L nickel; 303 µg/L selenium; 2.3 µg/L thallium; 6,700 µg/L uranium; and 1,680 µg/L zinc; as well as elevated concentrations other constituents. Changes in perched zone constituent concentrations and pH are therefore expected to result from the introduction of oxygen into the subsurface, the oxidation of pyrite and other constituents, changes in recharge rates, and past and current recharge passing through the Mancos Shale. Selenium is an example of a constituent that: is naturally occurring in the Burro Canyon Formation; is elevated in the Mancos Shale; and is a common contaminant in pyrite. That the Mancos Shale is a significant source of selenium is discussed in Baker, (2007); Colorado Department of Health and Environment (2011); (Tuttle, 2005); and USDOE (2011). Because the Mancos overlies the perched zone over much of the site (Figures 11A and 11B) it could represent a past and ongoing source of selenium (as wells as other constituents). Selenium originating from the Mancos Shale could potentially increase concentrations in the perched zone by three mechanisms: 1) ongoing leaching from the Mancos Shale via recharge; 2) oxidation of Mancos-derived selenium in the Burro Canyon Formation and Dakota Sandstone by dissolved nitrate in the perched water and/or oxygen introduced into the perched zone via perched well casings; and 3) oxidation of pyrite containing Mancos-derived selenium by dissolved perched zone nitrate and/or oxygen introduced into the perched zone via perched well casings. Selenium already present in the Dakota Sandstone and Burro Canyon Formation (including as a constituent Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 64 in pyrite) could have originated from the Mancos Shale in the past, and could affect the entire formation rather than just the areas beneath the current erosional remnants of the Mancos. Precipitation percolating downward from the land surface is expected to leach selenium from the Mancos Shale and carry it downward into the perched zone. Beneath the TMS, any such leaching is expected to have occurred for the most part prior to the installation of the individual cells which represent barriers to infiltration of precipitation. Vadose pore waters in the Dakota Sandstone and Burro Canyon Formation beneath the TMS may thus be expected to contain selenium leached from the Mancos in the past. Perched water rising into vadose pore waters containing selenium may enhance mass transfer and result in increased selenium concentrations in the perched water. Potentially increasing selenium concentrations may also result from the oxidation of selenium already present in the Dakota Sandstone and Burro Canyon Formation. Oxidation of selenium by nitrate present in perched water and/or by oxygen introduced into the formation via the well casings may result in increasing dissolved selenium concentrations. The possibility of nitrate oxidation of selenium is presented in Potoroff (2005). A third potential source for increasing dissolved selenium concentrations in perched water is oxidation of pyrite by nitrate and/or oxygen introduced into the formation via well casings. Pyrite typically contains trace elements including selenium. Selenium has been measured at concentrations as high as 0.2% by weight in pyrite (Deditius, 2011). As discussed in HGC (2012c), pyrite oxidation is expected to result in other changes that include an increase in dissolved sulfate (unless a sink for sulfate is present). Oxidation of pyrite by dissolved oxygen is expected to result in a decrease in pH as acid is released in the reaction: FeS2 + 33/4O2 + 31/2H2O = Fe(OH)3 + 2SO42- + 4H+ Oxidation of pyrite by nitrate may also occur as discussed in HGC (2012c). This process may result in either an increase or decrease in pH depending on the reaction pathway: 5 FeS2 + 14NO3- + 4H+ = 7N2 + 10SO42- + 5Fe2+ + 2H2O; or 2 FeS2 + 6NO3- + 2H2O = 3N2 + 4SO42- + 2FeOOH + 2H+ The interaction between nitrate and pyrite will be discussed in more detail in the following Section. Furthermore, constituents other than selenium that are elevated in the Burro Canyon Formation due to past invasion of pore waters from the Mancos Shale, or that exist as contaminants in Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 65 pyrite, can be released as a result of geochemical changes unrelated to disposal of materials to the TMS (such as increases in oxygen and nitrate), causing trends in concentrations of these constituents in site monitoring wells. As discussed above, other potential constituents include (but are not limited to) beryllium, cadmium, cobalt, copper, manganese, nickel, thallium, uranium, and zinc. 4.4 Implications for Perched Water Chemistry and Natural Attenuation of Nitrate and Chloroform As discussed above, past, current, and future interaction of the perched groundwater zone with the overlying Mancos Shale and underlying Brushy Basin Member can be expected to affect perched water chemistry at the site. Changes in perched water chemistry related to oxidation of pyrite by oxygen introduced into the subsurface dissolved in recharge and via well casings is also expected to occur. Concentrations of chloroform and nitrate already present in the perched zone will be affected over time by various processes, including direct mass removal by pumping. Natural attenuation of both constituents is expected to result from physical processes that include dilution by recharge and hydrodynamic dispersion. Volatilization into the vadose zone is another physical process that is expected to lower chloroform concentrations in perched water. Mass reduction processes expected to lower both nitrate and chloroform concentrations include chemical and biologically-mediated processes. The impacts of pyrite degradation by oxygen, degradation of nitrate by pyrite, and reductive dechlorination of chloroform are discussed in Sections 4.4.1 through 4.4.3. 4.4.1 Pyrite Degradation by Oxygen As discussed in HGC (2012c), the pH values measured in many site groundwater monitoring wells located upgradient, within the vicinity of, and downgradient of the Mill site and TMS displayed decreasing trends. pH decreases in many of these wells were accompanied by increases in sulfate concentrations. Ten of the MW-series groundwater monitoring wells were previously out of compliance (OOC) with respect to pH due to a decreasing trend. As discussed in INTERA (2012a and 2102b) and Section 5 below, changes in pH were determined to result from natural causes unrelated to the operation of the TMS. Based on work described in HGC (2012c), the decreases in pH and increases in sulfate in OOC wells were explainable by oxidation of pyrite, which releases acid and sulfate as described above. Screening-level calculations and geochemical modeling using PHREEQC (Parkhurst and Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 66 Appelo, 1999) indicated that pyrite measured in samples from the perched zone existed in more than sufficient quantity to have resulted in the measured changes in pH and sulfate at three representative wells located immediately upgradient (MW-27), immediately downgradient (MW- 24), and far downgradient (MW-3A) of the TMS. The calculations also indicated that pyrite existed in sufficient quantity to maintain these trends provided sufficient oxygen was available. Furthermore, site dissolved oxygen measurements since the third quarter of 2019 confirm that there is sufficient oxygen available to oxidize pyrite and produce acid and sulfate. Continued release of any contaminants within site pyrite was expected as was the release of pH sensitive constituents present in the Burro Canyon Formation and Dakota Sandstone. Although decreasing pH trends occurred in nearly all MW-series wells until about 2016, pH began to stabilize and then increase. The pH increase cannot result from a TMS impact because TMS solutions have very low pH. The post-2016 increasing pH trends indicate that TMS operation has not impacted groundwater. 4.4.2 Nitrate Degradation by Pyrite As discussed in HGC (2012c), nitrate will degrade in the presence of pyrite. Nitrate will also degrade, and more readily, in the presence of organic matter. Both pyrite and organic material in the form of carbonaceous matter have been logged in drill cuttings from the perched groundwater zone. As discussed in (Korom, 1992), the thermodynamically favored electron donor for reduction of nitrate in groundwater is typically organic matter. This process under neutral conditions is represented via the following generalized reaction (e.g. van Beek, 1999; Rivett et al., 2008; Tesoriero and Puckett, 2011; Zhang, 2012): 2 3 2 3 2 3 2 5 4 2 4 2CH O NO N HCO H CO H O - -+ = + + +(Reaction 1); In acidic (pH < 6.4) aquifer conditions, reduction of nitrate by organic matter can be generalized by the following pathway: 2 3 2 2 3 2 5 4 4 2 5 2CH O NO H N H CO H O - ++ + = + +(Reaction 2). In both cases, five moles of organic matter are required to reduce four moles of nitrate. Under acidic conditions the alkalinity generated by denitrification by organic matter consumes acid. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 67 In the absence of dissolved oxygen, pyrite can also be oxidized by nitrate. Denitrification by pyrite may occur via two primary reaction pathways. The pathway most commonly applied in geochemical studies (Kolle et al., 1983, 1985; Postma et al., 1991; Korom, 1992; Robertson et al., 1996; Pauwels et al., 1998; Hartog et al., 2001, 2004; Spiteri et al., 2008) is a bacteria- mediated reaction that yields ferrous iron, sulfate, water, and nitrogen gas as follows: 2 2 2 3 2 4 2 5 14 4 7 10 5 2FeS NO H N SO Fe H O - + - ++ + = + + + (Reaction 3). By Reaction 3, five moles of pyrite reduce 14 moles of nitrate, consuming four moles of acid. Reaction 3 is considered applicable when pyrite concentrations exceed nitrate concentrations (van Beek, 1999). Where nitrate concentrations exceed pyrite concentrations, Reaction 4 is a more likely mechanism (Kolle et al., 1987; van Beek, 1999; Schlippers and Jorgensen, 2002): 2 2 3 2 2 4 3 2 6 4 3 4 2 ( ) 2FeS NO H O N SO Fe OH H -- ++ + = + + +(Reaction 4). By Reaction 4, two moles of pyrite reduce six moles of nitrate, yielding iron hydroxide, sulfate, acid, and nitrogen gas. Therefore, when nitrate concentrations exceed pyrite concentrations (Reaction 4), denitrification by pyrite is more efficient than when pyrite is in excess (Reaction 3). Additionally, Reaction 4 produces acid, while Reaction 3 consumes acid, indicating that the impact of denitrification by pyrite on aquifer geochemistry is controlled by the relative abundance of pyrite and nitrate; and that pH may decrease or increase depending on the reaction pathway. Reaction 4 is an overall reaction that combines Reaction 3 and a second step whereby ferrous iron is oxidized by nitrate. This second step is more likely to occur when excess nitrate is present and available to oxidize ferrous iron (Kolle et al., 1987; Rivett et al., 2008; Zhang 2012). Stoichiometric calculations were used to determine the weight percent of perched zone pyrite that would be required to reduce the ‘baseline’ estimate of 43,700 lbs of nitrate (HGC, 2012a) via reaction mechanisms 3 and 4 (assuming each was the only denitrification reaction occurring). 43,700 lbs of nitrate corresponds to 19,822 kg and 319,684 moles. Although organic matter is noted in lithologic logs, the organic matter content of the perched zone has not been quantified so calculations regarding nitrate degradation by reactions 1 and 2 are not presented, even though significant nitrate reduction via these mechanisms is likely to occur. Nitrate can either migrate towards Ruin Spring to the south-southwest or to Westwater Seep to the west. Assuming the entire nitrate plume migrated south towards Ruin Spring, the volume of the perched zone through which the nitrate plume would migrate was assumed to be on average Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 68 20 feet thick, 1,200 feet wide, and 10,000 feet long, representing a total saturated formation volume of 2.4 x 108 ft3 or 6.8 x 109 liters. Assuming the entire nitrate plume migrated west toward Westwater Seep, the volume of the perched zone through which the nitrate plume would migrate was assumed to be on average 18 feet thick, 2,800 feet wide, and 4,950 feet long, representing a total saturated formation volume of 2.5 x 108 ft3 or 7 x 109 liters. To be conservative, the following calculations are based on the smaller volume of 6.8 x 109 liters. Using these estimates, reaction 3 would require 114,173 moles of pyrite to consume 43,700 lbs of nitrate, and would consume 91,338 moles of acid (1.34 x 10-5 moles H+ per liter of formation). Reaction 4 would require 106,561 moles of pyrite to degrade the nitrate, producing 106,561 moles of acid or 1.57 x 10-5 moles H+ per liter of formation. Assuming a conservatively large porosity of 0.2 for the perched zone (HGC, 2012c), the total volume of water is 1.36 x 109 liters; and assuming a solids density of 2.6 kg L-1, yields a total solid mass of 1.4 x 1010 kg. Using this solid mass, both Reactions 3 and 4 would require pyrite formation weight percents of 0.000098% (9.8 x 10-5 %) and 0.000091% (9.1 x 10-5 %), respectively, to degrade 43,700 lbs of nitrate. These calculated pyrite weight percents are orders of magnitude less than conservative estimates of pyrite content based on samples analyzed during the pyrite investigation (HGC, 2012c), which ranged from 0.0056% to 0.08% (5.6 x 10-3 % to 8 x 10-2 %). These results suggest that the available pyrite content in the path of the nitrate plume is two to three orders of magnitude greater than needed to degrade the total mass (43,700 lbs) of nitrate. These calculations are conservative in that they assume the degradation of the entire mass of nitrate and not just the mass needed to reduce concentrations below 10 mg/L. Whether or not pyrite oxidation by nitrate at the site is generating or consuming acid depends largely on whether oxidation of ferrous iron by nitrate is occurring (i.e. whether pyrite denitrification is occurring by Reaction 3 or Reaction 4; whether nitrate exists in excess). The preferred mechanism for denitrification by pyrite is likely to vary spatially. If pyrite is assumed to be relatively evenly distributed throughout the formation, while nitrate occurs in a discrete plume, Reaction 3 may dominate on the plume edges while Reaction 4 may dominate the core of the plume. As discussed in HGC (2017), estimated average natural nitrate degradation rates range from approximately 172 lb/yr to 200 lb/yr (or approximately 5.4 x 10-6 pounds per cubic feet per year [lb/ft3 yr] to 6.4 x 10-6 lb/ft3 yr). These estimates conservatively ignore the much higher rates Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 69 calculated in HGC (2017) using ‘Method 2’, which yielded nitrate degradation rates as large as 9 x 10-5 lb/ft3 yr. Based on the third quarter, 2021 residual nitrate plume mass estimate of approximately 28,290 lb, and assuming natural nitrate degradation rates of 172 lb/yr to 200 lb/yr, less than 200 years would be required to remediate the nitrate plume, even in the absence of any direct mass removal by pumping. 4.4.2.1 Other Relevant Studies Regarding Nitrate Reduction by Pyrite Nitrate degradation by pyrite is a well-known mechanism discussed extensively in the literature. USEPA (2007) recognizes the importance of pyrite-bearing aquifers in reducing or eliminating nitrate contamination, stating that “pyrite-bearing aquifers represent important hydrological compartments due to their capacity to eliminate nitrate.” Other relevant excerpts from available literature are provided below: • Jioyang (2014) indicates that pyrite is suitable for nitrate remediation with a nitrate removal rate constant of 0.95/day. • Krieger (2014) indicates that “the major electron donors for denitrification are organic carbon (OC), pyrite (FeS2) and ferrous iron silicate minerals. In the […] tracer tests, increases in sulfate indicated that the oxidation of pyrite explained a significant [proportion] of the denitrification.” • Zhang (2012) indicates that “Pyrite oxidation leads to sulfate production and trace metal release to groundwater. This process can have a major impact on local and regional water quality.” • Zhang (2012) also indicates that “denitrification with pyrite can be the dominant pathway of nitrate removal from groundwater, even when organic matter is present.” • Zhang (2009) concludes that “nitrate removal from the groundwater below cultivated fields correlates with sulfate production, and the release of dissolved Fe2+ and pyrite- associated trace metals (e.g. As, Ni, Co and Zn). These results, and the presence of pyrite in the sediment matrix within the nitrate removal zone, indicate that denitrification coupled to pyrite oxidation is a major process in the aquifer.” • Tesoriero (2011) indicates that “A review of published rates suggests that denitrification tends to occur more quickly when linked with sulfide oxidation than with carbon oxidation.” • Bosch (2011) states “Here, we provide evidence for the capability of Thiobacillus denitrificans to anaerobically oxidize a putatively nanosized pyrite particle fraction with nitrate as electron acceptor. Nanosized pyrite was readily oxidized to ferric iron and sulfate with a rate of 10.1 μM h-1. The mass balance of pyrite oxidation and nitrate reduction revealed a closed recovery of the electrons. This substantiates a further ‘missing lithotrophy’ in the global cycles of sulfur and iron and emphasizes the high reactivity of nanominerals in the environment.” Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 70 • Aguerri (2010) identified areas within the Osona region of Spain where, based on hydrogeological and multi-isotopic methods, nitrate degradation via pyrite oxidation was occurring. • Torrento (2010) indicates that “Nitrate reduction was satisfactorily accomplished in experiments with pyrite as the sole electron donor, in presence of the autotrophic denitrifying bacterium Thiobacillus denitrificans and at nitrate concentrations comparable to those observed in contaminated groundwater. The experimental results corroborated field studies in which the reaction occurred in aquifers.” • Jorgensen (2009) concludes that microbes can control groundwater nitrate concentrations by denitrification “using primarily pyrite as electron donor at the oxic-anoxic boundary in sandy aquifers.” Note the potentially important impacts on water quality resulting from the trace metal and sulfate release from pyrite oxidation as discussed in Zhang (2009; 2012). In addition, as discussed above, depending on the particular reaction pathway, acid may also be released causing a decrease in pH resulting in mobilization of additional metals. 4.4.2.2 Comparison to Oostrum Site Bosch and Meckenstock (2012) discuss degradation of nitrate via pyrite oxidation in field and laboratory studies and provide calculated rates. These rates are summarized in Table 14. Of particular interest are the rates calculated for the Oostrum, Netherlands site, an agricultural area which overlies a pyritic sandy aquifer. The Oostrum site is discussed in detail in Zhang (2009) and Zhang (2012). Similarities between the Oostrum and Mill sites include: • Sandy materials containing pyrite host groundwater; • Locally anaerobic conditions are present (inferred at Mill from detectable chloroform daughter product concentrations and persistence of pyrite); • Similar pyrite concentrations (from <0.1 to approximately 0.8 wt% at both sites; and similar average concentrations as shown in Tables 14 and 15); • Calculated nitrate (as nitrogen) degradation rates at the Mill that are similar to, but lower than the rate calculated for the Oostrum site (approximately 5.4 x 10-4 lb/ft3-yr at Oostrum; and approximately 5.4 x 10-6 to 6.35 x 10-6 lb/ft3 yr at the Mill as shown in Table 15). The rate reported for the Oostrum site, which has pyrite concentrations that are similar to those measured at the Mill, is one to two orders of magnitude higher than the rates calculated for the Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 71 Mill, suggesting that the rates calculated for the Mill are conservatively low and may underestimate actual rates. Regardless, as discussed in Section 3.8, even in the absence of any nitrate reduction by pyrite or mass removal via pumping, numerical flow and transport modeling using conservative assumptions indicates that natural attenuation will reduce all nitrate concentrations within the plume to less than the 10 mg/L GCAL before reaching a property boundary. 4.4.3 Chloroform Reduction As discussed in HGC (2007b) and HGC (2022), the presence of chloroform daughter products indicates that chloroform is degrading naturally via reductive dechlorination. Calculations presented in HGC (2022) based on daughter product concentrations indicated that the entire chloroform plume would be reduced to concentrations below the GCAL of 70 ug/L within approximately 168 years or less, even in the absence of any direct mass removal by pumping. Reductive dechlorination takes place under anaerobic conditions which were inferred to exist only locally within the perched zone. The low rates of degradation and the persistence of nitrate associated with the chloroform plume are consistent with primarily aerobic conditions. However, the widespread occurrence of pyrite in the perched zone is consistent with at least locally anaerobic conditions, and with the relatively low calculated rates of chloroform degradation presented in HGC (2007b) and HGC (2022). Continued reductive dechlorination is expected within locally anaerobic portions of the perched zone. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 72 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 73 5. SUMMARY OF PERCHED GROUNDWATER MONITORING AND STUDIES As noted in Section 2.0, investigations to date and more than 41 years of perched groundwater monitoring indicate that operation of the Mill has not impacted perched groundwater. A detailed list of studies and the associated reports is included in Section 2.0 and in Section 1.0 of the 2022 Groundwater Discharge Permit Renewal Application. Specifically, background groundwater quality evaluations have been performed for each MW- series groundwater monitoring well. These wells are located within the Mill site and cells comprising the TMS as well as up-gradient, downgradient and cross-gradient of these facilities. Groundwater compliance limits (GWCLs) have been established for each Groundwater Discharge Permit (GWDP) constituent on an intra-well basis. Compliance limits are calculated on an intra-well basis because of the large variation in background water quality within the perched groundwater zone. The Background Quality Reports completed prior to 2010 (INTERA, 2007a and 2007b; collectively the Background Reports), evaluated groundwater analytical data collected since the initiation of groundwater sampling and in the wells installed as specified in the DWMRC GWDP respectively. The Background Reports identified naturally occurring elevated, increasing, and decreasing concentrations of various constituents in monitoring wells located far upgradient, far downgradient, far cross-gradient and in the vicinity of the Mill site and TMS. Increasing concentration trends identified by INTERA were present at the time that an isotopic investigation by the University of Utah (Hurst and Solomon, 2008) concluded that there were no impacts to groundwater from the TMS. The isotopic study provided additional confirmation that the identified constituent trends were the result of natural background influences unrelated to disposal of materials to the TMS. Additional Background Reports have been completed for wells installed after the completion of the 2007 and 2008 studies. These Background analyses for wells MW-20, MW-22, MW-35, MW-36, MW-37, MW-38, MW-39 and MW-40 support previous conclusions that the groundwater at the Mill is not being affected by disposal of materials to the TMS. Per the GWDP, constituents with two consecutive GWCL exceedances are subject to a Source Assessment Report (SAR) as defined in the GWDP. The initial SAR was submitted in October of 2012 (INTERA 2012a) and covered all of the constituents in wells with consecutive exceedances since the approval of the GWDP in 2010. The October 2012 SAR (INTERA 2012a) presented a geochemical analysis of parameters that exhibited exceedances as well as an analysis of indicator Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 74 parameters (chloride, fluoride, sulfate and uranium) to determine if the exceedance could be related to potential TMS seepage or Mill-related activities. Since then, twelve additional SARs prepared by INTERA (INTERA 2013a; 2013b; 2014a; 2014b; 2015; 2016; 2017; 2018; 2019a; 2019b; 2019c; and 2020); and five SARs prepared by EFRI (EFRI, 2020; 2021a; 2021c; 2022a; and 2022d) cover additional consecutive exceedances. In all cases the exceedances for which the SARs were performed were determined to result from naturally occurring conditions in the groundwater at the site or from other factors that are affecting groundwater but are unrelated to TMS operation. These other factors include the nitrate/chloride plume that extends approximately 1,000 feet upgradient (north-northeast) of the TMS (and is addressed by the nitrate CAP); a sitewide decline in pH that was identified at the time of the Background Report; as well as other natural background factors unrelated to disposal of materials to the TMS. Further study of the natural background factors affecting the groundwater at the site have been undertaken by EFRI and are discussed below. At the time of the Background Report, an overall decline in pH across the site was observed. Background analysis and determination of GWCLs for pH were performed using laboratory pH measurements rather than using measurements that are collected in the field at the time of sampling by using a pH probe. Since the latter of these two methods of measuring pH is more reliable, an additional pH analysis was performed in 2012 using only field data. GWCLs for pH were recalculated at this time using the field measurements. As discussed in Section 4.4.1, HGC (2012c) determined that pH decreases resulted from oxidation of naturally-occurring pyrite enhanced by oxygen delivery to the perched zone. Oxygen delivery mechanisms included advective transport to the perched zone dissolved in wildlife pond seepage, and diffusive and dispersive transport to perched groundwater in the vicinities of perched wells via perched well casings. In addition, pH decreases at wells impacted by the nitrate plume could result from nitrate degradation of pyrite by the reaction mechanism that produces, rather than consume, acid as discussed in Section 4.4.2. pH decreases have therefore been determined to be unrelated to TMS operation. Furthermore, although the pH decrease was an apparently site-wide phenomenon, since about 2016, pH in nearly all MW-series wells has stabilized and has begun to increase. As discussed in EFRI (2022a) and EFRI (2022d), because TMS solutions have very low pH, the post-2016 increases indicate that TMS solutions cannot be impacting groundwater. 5.1 Chloroform Plume As discussed in Section 2, a chloroform plume occurring within shallow perched groundwater at the Mill has been under remediation by pumping since 2003 (HGC, 2007a). The chloroform Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 75 plume is located generally cross- to up-gradient of the TMS (HGC, 2007b and Figure 1B). The 2022 Corrective Action Comprehensive Monitoring Evaluation (CACME) report for the chloroform plume (HGC, 2022) represents a 2-year review of the Corrective Action as required by Part III.H of the Groundwater Corrective Action Plan (GCAP) found in Attachment 1, of the final Stipulation and Consent Order (“SCO”) Docket No. UGW20-01 (Utah Department of Environmental Quality Division of Solid Waste and Radiation Control, 2015). As discussed in the chloroform CACME the chloroform plume is under control. Current pumping system effectiveness is demonstrated by 1) the slowing to near halting of plume boundary expansion attributable to reduced dilution from reduced wildlife pond recharge and redistribution of chloroform resulting from nitrate pumping; and 2) the maintenance of a large proportion of the plume mass under hydraulic capture (approximately 97% as of the fourth quarter of 2021). High rates of capture have been maintained even considering reduced productivities at some of the pumping wells and the failure and subsequent abandonment of pumping well TW4-20 during 2020. The abandonment of TW4-20 had little to no measurable impact on pumping, mass removal rates, and capture in the vicinity of TW4-20, as increases in pumping at TW4-19 subsequent to TW4-20 failure more than compensated for the loss of pumping at TW4-20. As discussed in Section 4.4.3 and Appendix C of the CACME, natural attenuation calculations suggest that all chloroform concentrations will be below the GCAL of 70 ug/L within less than 200 years, not taking into account the effects of any direct mass removal by pumping. Using the average calculated chloroform degradation rate (Appendix C of the CACME), the highest 2021 chloroform concentration of 14,800 µg/L would be reduced to the GCAL of 70 µg/L within approximately 61,353 days or 168 years, even in the absence of pumping. If the degradation rate is based only on data collected from pumping well MW-26, which has chloroform concentrations close to the average chloroform concentration for the plume, the time to reduce the highest 2021 concentration of 14,800 µg/L to the GCAL of 70 µg/L would take approximately 16,890 days or only 46 years. 5.2 Nitrate Plume As discussed in Section 2, the nitrate plume has been under remediation by (Phase II) pumping since the first quarter of 2013. The plume, defined by groundwater concentrations exceeding 10 mg/L nitrate as nitrogen, originates upgradient (northeast) of the TMS at the site (HGC, 2017 and Figure 1B). Likewise, the commingled chloride plume, defined by groundwater concentrations exceeding 100 mg/L chloride, also originates upgradient of the TMS. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 76 The 2017 Corrective Action Comprehensive Monitoring Evaluation (CACME) report for the nitrate plume (HGC, 2017) represents a 5-year review of the Phase II Corrective Action as specified in the final Stipulation and Consent Order (SCO) Docket No. UGW12-04 (Utah Department of Environmental Quality Division of Solid Waste and Radiation Control, 2012). As discussed in the nitrate CACME, between the second quarter of 2010 and the third quarter of 2017, the mass of nitrate contained within the plume has been reduced by approximately 11% to 25%. Based on data presented in EFRI (2022c), the residual mass of the nitrate plume has continued to decline. Furthermore, as discussed in Section 4.4.2, there is enough pyrite in the perched zone within the path of the nitrate plume to completely attenuate the plume through natural reduction of nitrate alone. As discussed in HGC (2017) and Section 4.4.2, estimated natural nitrate degradation rates range from approximately 172 lb/yr to 200 lb/yr, indicating that less than 200 years would be required to remediate the nitrate plume, even in the absence of any direct mass removal by pumping. However, considering both pumping and estimated natural attenuation rates presented in HGC (2017), the mass of the plume is expected to be reduced by approximately 573 to 601 lb/yr, and nitrate concentrations within the plume are expected to be reduced to negligible values (less than 10 mg/L) within approximately 54 to 57 years. As the estimated time for impacted water to reach the nearest discharge point (Westwater Seep or Ruin Spring) is greater than 3,000 years, there is no concern at this time that the continuation of current corrective actions will not result in remediation of the plume well before it can reach any exposure to the public or wildlife. In response to a DWMRC request, additional attenuation modeling of the nitrate plume was conducted to further study and refine the conclusions presented in the 2017 nitrate CACME. Accordingly, a Phase III Planning Document was prepared (HGC 2018e). The Phase III planning document included conceptual-level numerical groundwater flow and solute transport assessments to evaluate the maximum distance that the nitrate plume could travel, assuming hypothetical ‘worst-case’ conditions, before all concentrations are reduced below 10 mg/L, indicating that full attenuation has occurred. These ‘worst-case’ transport assessments: 1. Disregard the natural degradation of nitrate within the plume via pyrite oxidation which will cause overestimation of simulated plume migration; 2. Disregard the (relative) stability of the southern (downgradient) margin of the nitrate plume which suggests that pumping and natural attenuation processes are minimizing or preventing plume expansion to the south; Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 77 3. Disregard nitrate mass removal by pumping and natural dilution of nitrate concentrations via recharge by precipitation, which will cause overestimation of simulated plume migration; 4. Substantially overestimate hydraulic conductivities (by as much as two orders of magnitude) and hydraulic gradients (by nearly a factor of two) downgradient of the TMS, which will cause substantial overestimation of simulated plume migration rates; and 5. Underestimate dispersivities which will cause underestimation of hydrodynamic dispersion and overestimation of simulated plume migration. The conceptual-level transport assessments indicate that the nitrate plume will not migrate beyond the site property boundary or to a discharge point before fully attenuating, even under hypothetical ‘worst-case’ assumptions. Therefore, under any currently conceivable conditions, including hypothetical ‘worst-case’ conditions that greatly overestimate plume migration rates, underestimate mechanical dispersion, and disregard mass removal by pumping and natural degradation, there will be no expected hazard to public health, safety or the environment; no expected exposure to the public, wildlife or the environment; and, as a result, no additional hazard or exposure assessments are needed at this time. In summary, the assessments provided in Section 4.4.2 and the 2017 nitrate CACME indicate that the plume would fully degrade via natural pyrite oxidation alone before reaching a discharge point. This degradation would occur within 200 years assuming no pumping, dilution by natural recharge, or hydrodynamic dispersion. The conceptual-level transport assessments performed in 2019 indicate that, even without mass removal via pyrite oxidation or pumping, and assuming hypothetical ‘worst case’ conditions regarding future nitrate transport, the plume will fully attenuate before reaching the site property boundary or a discharge point. 5.3 MW-24A Study As noted above, Part I.G.2 of the GWDP provides that out-of-compliance status exists when the concentration of a constituent in two consecutive samples from a compliance monitoring point exceeds a GWCL in Table 2 of the GWDP. As part of the assessment of exceedances of previous GWCLs, increasing trends in several constituents in MW-24 and other MW-series wells were observed as noted in the Background Repots and SARs listed above and in Section 2. In response to the previously identified exceedances and increasing trends, in 2020 EFRI voluntarily completed a study of MW-24A (collocated with MW-24 as shown in Figure 1A) to determine what geochemical and hydrogeological influences may be impacting monitoring data collected at these two wells and potentially other wells across the Mill site. The MW-24A study Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 78 and report (EFRI, 2021b) included several additional field data collection and analytical activities based on the conclusions of other Mill reports. Tests included whole-rock and synthetic precipitation leaching procedure (SPLP) analysis of drill core; bottle-roll tests on drill core noted to have pyrite; and bottle roll tests on ‘pure’ pyrite obtained from a rock shop. The results of the analytical and other test data collected during the MW-24A study demonstrated that natural processes unrelated to disposal of materials in the TMS can account for the behavior of all trace metals of concern, as well as fluoride, in groundwater at MW-24 and MW-24A. Bottle-roll test results indicated that naturally-occurring trace metals can be mobilized at concentrations similar to or greater than in groundwater even without a large pH decrease, suggesting that agitation alone, such as would occur during routine purging and sampling of low permeability wells such as MW-24A, could result in metals mobilization. Test results are consistent with average crustal abundances of trace metals detected in some site groundwater monitoring wells; and with the formations hosting the perched groundwater (Dakota Sandstone and Burro Canyon Formation) having been impacted by past invasion of pore waters from the overlying Mancos Shale as discussed in Shawe (1976). For example, Fleisher (1953) reports the following estimated average crustal abundances of various metals converted to parts per billion (ppb) by weight: cadmium (100 to 5,000 ppb); beryllium (5,000 to 30,000 ppb); thallium (0.8 to 600 ppb); cobalt (10,000 to 40,000 ppb); nickel 80,000 to 200,000 ppb); selenium (30 to 800 ppb); and uranium (200 to 9,000 ppb). There is no compelling reason to suppose that these elements would not naturally be present in the perched water-bearing Burro Canyon Formation and Dakota Sandstone beneath the Mill. Some or all of these metals have been detected in far upgradient and far cross-gradient wells that could not have been impacted by the TMS. In addition, as discussed in Sections 3.1.3, 3.1.4 and 4.3, the Mancos Shale directly overlying these formations is anomalous in many metals including selenium and uranium ( USDOE, 2011). Furthermore, as discussed in Shawe (1976), the Dakota and Burro Canyon are considered ‘altered facies’ rocks primarily as a result of the invasion of pore waters expelled from the overlying Mancos Shale during compaction that caused removal of hematite coatings on sand grains, destruction of detrital black opaque minerals, and the growth of iron sulfide minerals such as pyrite. Not only were the metals contents of the Dakota and Burro Canyon increased by the invasion of Mancos Shale pore waters, the pyrite created as a result of invasion of these solutions is expected to contain significant trace metals including selenium. As discussed in Deditius et al (2011) pyrite commonly contains arsenic (As), lead (Pb), antimony (Sb), bismuth (Bi), copper (Cu), cobalt (Co), nickel (Ni), zinc (Zn), gold (Au), silver (Ag), selenium (Se) and tellurium (Te). Oxidation of pyrite by oxygen introduced into the formation via wells or wildlife pond Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 79 seepage, or by nitrate within the nitrate/chloride plume (which originates upgradient of the Mill and TMS) is expected to directly release these metals to groundwater. Furthermore, the Dakota Sandstone and Burro Canyon Formation host naturally-occurring uranium mineralization (Pierson and Greene, 1980; Craig, 1982) that is expected to be mobilized in the presence of oxygen and/or nitrate. Rose and Wright (1980) indicate that elements associated with sandstone-type uranium deposits include sulfur (S), vanadium (V), molybdenum (Mo), Se, As, Cu, Ag, chromium (Cr), Pb, Zn, Ni, Co, rhenium (Re), beryllium (Be), phosphorous (P), manganese (Mn) and rare earths. Overall, considering that the Dakota Sandstone and Burro Canyon Formation have been impacted by the Mancos Shale, and that uranium mineralization with associated elements occurs naturally within these formations, it is likely that the concentrations of many or all of these metals exceed average crustal abundances, which appears consistent with the results of the MW- 24A study. As discussed in Section 4.3, bottle-roll tests using pyrite-bearing core from MW-24A yielded bottle-roll solutions initially consisting of laboratory-grade deionized (DI) water generating as much as 74 µg/L Be; 118 µg/L cadmium (Cd); 79 µg/L Co; 959 µg/L Cu; 4,120 µg/L Mn; 278 µg/L Ni; 303 µg/L Se; 2.3 µg/L thallium (Tl); 6,700 µg/L U; and 1,680 µg/L Zn; as well as elevated concentrations other constituents 5.4 Proposed Phase 2 Study As noted in Section 4.3, the perched groundwater system hosted by the Burro Canyon Formation and Dakota Sandstone does not approach steady state over much of the monitored area. A large part of the site perched water system is in a transient state and affected by long-term changes in water levels due to past and current activities unrelated to the disposal of materials to the TMS. The MW-24A study indicates that naturally-occurring trace metals can be mobilized at concentrations similar to or greater than in groundwater even without a large pH decrease, suggesting that agitation alone, such as would occur during routine purging and sampling of low permeability wells such as MW-24A, could result in metals mobilization. However, the lack of steady-state conditions, in particular groundwater level changes resulting from changing background conditions, and local increases in oxygen and/or nitrate concentrations in groundwater, can also be expected to result in mobilization of naturally-occurring metals and other constituents. Based on the results of the MW-24A study EFRI has voluntarily agreed to implement a Phase 2 study to determine what geochemical and hydrogeological influences are present that may be Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 80 affecting monitoring data collected at other wells across the Mill site. This voluntary study is in the planning phases and will be implemented upon approval of DWMRC. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 81 6. SUMMARY AND CONCLUSIONS REGARDING MILL HYDROGEOLOGY The Mill, situated on White Mesa within the Blanding Basin physiographic province, has an average elevation of approximately 5,600 feet above mean sea level (ft amsl), and is underlain by unconsolidated alluvium and indurated sedimentary rocks. Indurated rocks include those exposed within the Blanding Basin which consist primarily of sandstone and shale. The indurated rocks are relatively flat lying with dips generally less than 3º. The alluvial materials overlying the indurated rocks consist primarily of aeolian silts and fine-grained aeolian sands with a thickness varying from a few feet to as much as 25 to 30 feet across the site. The alluvium is underlain by the Dakota Sandstone and Burro Canyon Formation, and where present, the Mancos Shale. The Dakota Sandstone and Burro Canyon Formation are sandstones having a total thickness ranging from approximately 55 to 140 feet. Beneath the Burro Canyon Formation lies the Morrison Formation, consisting, in descending order, of the Brushy Basin Member, the Westwater Canyon Member, the Recapture Member, and the Salt Wash Member. The Brushy Basin and Recapture Members of the Morrison Formation, classified as shales, are very fine-grained and have a very low permeability. The Brushy Basin Member is primarily composed of bentonitic mudstones, siltstones, and claystones. The Westwater Canyon and Salt Wash Members also have a low average vertical permeability due to the presence of interbedded shales. Beneath the Morrison Formation lie the Summerville Formation, an argillaceous sandstone with interbedded shales, and the Entrada Sandstone. Beneath the Entrada lies the Navajo Sandstone. The Navajo and Entrada Sandstones constitute the primary aquifer in the vicinity of the site. The Entrada and Navajo Sandstones are separated from the Burro Canyon Formation (and the perched water system monitored at the site) by approximately 1,000 to 1,100 feet of materials having a low average vertical permeability. Groundwater within the Entrada/Navajo system is under artesian pressure in the vicinity of the site, is of generally good quality, and is used as a secondary source of water at the site. Stratigraphic relationships beneath the site are summarized in Figure 3. The site and vicinity has a dry to arid continental climate, with an average annual precipitation of approximately 13.3 inches, and an average annual lake evaporation rate of approximately 47.6 inches. Recharge to major aquifers (such as the Entrada/Navajo) occurs primarily along the mountain fronts (for example, the Henry, Abajo, and La Sal Mountains), and along the flanks of folds such as Comb Ridge Monocline. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 82 Perched groundwater beneath the site occurs in the Dakota Sandstone and Burro Canyon Formation and is used on a limited basis to the north (upgradient) of the site because it is more easily accessible than the Navajo/Entrada aquifer. Perched groundwater originates mainly from precipitation and local recharge sources such as unlined reservoirs (Kirby, 2008) and is supported within the Burro Canyon Formation by the underlying, fine-grained, and bentonitic Brushy Basin Member, considered an aquiclude. Water quality of the Dakota Sandstone and Burro Canyon Formation is generally poor due to high total dissolved solids (TDS) in the range of approximately 1,100 to 7,900 milligrams per liter (mg/L) and is used primarily for stock watering and irrigation. Nitrate and chloroform plumes occur in site perched groundwater as shown in Figure 1B. The nitrate plume extends from approximately 1,000 feet upgradient (north-northeast) of the TMS to beneath the TMS. The chloroform plume is located primarily upgradient to cross-gradient (northeast to east) of the TMS. Sources of the nitrate plume are not well-defined but the historical pond shown on Figures 1A and 1B is considered a source of nitrate and chloride to the plume. The only potentially active source of nitrate to the plume is related to ammonium sulfate crystal handling near the ammonium sulfate crystal tanks located southeast of TWN-2 (Figures 1A and 1B) and has been addressed through implementation of Phase I of the nitrate CAP. Past sources of the chloroform plume are two abandoned sanitary leach fields (located near TW4-18 and TW4-19 [Figures 1A and 1B]) that received laboratory wastes prior to any cells within the TMS becoming operational circa 1980. Both plumes are under remediation by pumping. The saturated thickness of the perched groundwater zone generally increases to the north of the site, increasing the yield of the perched zone to wells installed north of the site. The generally low permeability of the perched zone limits well yields. Although sustainable yields of as much as 4 gallons per minute (gpm) have been achieved in site wells penetrating higher transmissivity zones near the unlined wildlife ponds (Figures 1A and 1B), yields are typically low (<1/2 gpm) due to the generally low permeability of the perched zone. Even site wells that yielded as much as 4 gpm during the first few months of pumping eventually saw yields drop to about 1 gpm or less. As of the fourth quarter of 2021, total sustainable pumping from the 16 wells comprising the chloroform and nitrate pumping systems was just under 6 gpm. In addition, many of the perched monitoring wells purge dry and take several hours to more than a day to recover sufficiently for groundwater samples to be collected. During redevelopment (HGC, 2011b) many of the wells went dry during surging and bailing and required several sessions on subsequent days to remove the proper volumes of water. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 83 As shown in Figure 5 and Appendix D, perched water flow across the site is generally (and historically) from northeast to southwest. Perched water discharges in seeps and springs located to the west, southwest, east, and southeast of the site (Figure 1B). Beneath and south of the TMS, in the west central portion of the site, perched water flow is south-southwest to west-southwest. Flow on the western margin of the mesa south of the TMS is generally southerly, approximately parallel to the mesa rim (where the Burro Canyon Formation is terminated by erosion). On the eastern side of the site perched water flow is also generally southerly to southwesterly. Perched water flow beneath and downgradient of the Mill site and TMS is influenced by perched water discharge points Westwater Seep, located west to west-southwest of the TMS, and Ruin Spring, located southwest of the TMS. Hydraulic gradients at the site currently range from approximately 0.0021 ft/ft in the northeastern corner of the site (between TWN-19 and TWN-16) to 0.098 feet per foot (ft/ft) east of cell 2 (in the vicinity of the chloroform plume, between TW4- 2 and TW4-3). Because of relict mounding near the northern wildlife ponds, flow direction ranges from locally westerly (west of the ponds) to locally easterly (east of the ponds). The March 2012 cessation of water delivery to the northern ponds, which are generally upgradient of the nitrate and chloroform plumes at the site, resulted in changing conditions that were expected to impact constituent concentrations and migration rates within these plumes. Specifically, past recharge from the ponds helped limit many constituent concentrations within these plumes by dilution while the associated groundwater mounding increased hydraulic gradients and contributed to plume migration. Since use of the northern wildlife ponds ceased in March 2012, the reduction in recharge and decay of the associated groundwater mound have increased many constituent concentrations within the plumes while reducing hydraulic gradients and acting to reduce rates of plume migration. The impacts associated with cessation of water delivery to the northern ponds were expected to (and have) propagate downgradient (south and southwest) over time. Reduced recharge from the southern wildlife pond resulting from reduced water delivery, and the decay of the associated (southern) perched groundwater mound, is causing changes in hydraulic gradients in the vicinity. In particular the decay of the southern mound has resulted in more southerly (rather than southeasterly) flow within the southernmost portion of the chloroform plume. Continued decay of the southern mound is expected to result in eventual restoration of the typical site southwesterly flow pattern within this portion of the plume. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 84 Flow onto the site occurs as underflow from areas northeast of the Mill site where perched zone saturated thicknesses are generally greater. Any flow that does not discharge in seeps or springs presumably exits as underflow to the southeast of Ruin Spring, along the southwest extending lobe of White Mesa located between Ruin Spring and Corral Springs. Darcy’s Law calculations of perched water flow to Ruin Spring and Westwater Seep yield reasonable results and suggest that local recharge contributes to seep/spring flow. Hydraulic testing of perched zone wells yields a hydraulic conductivity range of approximately 2 x 10-8 to 0.01 cm/s (Tables 1- 4). In general, the highest permeabilities and well yields are in the area of the site immediately northeast and east (upgradient to cross gradient) of the TMS. A relatively continuous, higher permeability zone associated with the chloroform plume and consisting of poorly indurated coarser-grained materials has been inferred to exist in this portion of the site (HGC, 2007b). Because their existence requires both coarse grain size and poor cementation, such relatively continuous, higher permeability zones are expected to be relatively rare at the site. Permeabilities downgradient (southwest) of the TMS are generally low. The low permeabilities and shallow hydraulic gradients downgradient of the TMS result in average perched groundwater pore velocity estimates that are among the lowest on site. Furthermore, more than 41 years of groundwater monitoring indicate no impacts to perched groundwater from TMS operation. As discussed above, perched groundwater discharges in seeps and springs located along the mesa margins. The relationships between seeps and springs and site geology/stratigraphy are provided in Figure E.1 and Figure E.2. Seep and spring investigation (HGC, 2010g) and investigation of the southwest portion of the site (HGC, 2012b) indicate the following: 1. Incorporating the seep and spring elevations in perched water elevation contour maps produces little change with regard to perched water flow directions except in the area west of the TMS and near Entrance Spring. West of the TMS, incorporation of Westwater Seep creates a more westerly hydraulic gradient. Westwater Seep appears to be downgradient of the western portion of the TMS (Figure 25); and Ruin Spring is downgradient of the eastern portion of the TMS (Figure 25). Westwater Seep is the closest apparent discharge point west of the TMS and Ruin Spring is the closest discharge point south-southwest of the TMS. Including the Entrance Spring elevation on the east side of the site creates a more easterly gradient in the perched water contours, and places Entrance Spring more directly downgradient of the northern wildlife ponds. Seeps and springs on the east side of the mesa are either cross-gradient of the TMS or are separated from the TMS by a groundwater divide. 2. Ruin Spring and Westwater Seep are interpreted to occur at the contact between the Burro Canyon Formation and the Brushy Basin Member of the Morrison Formation. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 85 Corral Canyon Seep, Entrance Spring, and Corral Springs are interpreted to occur at elevations within the Burro Canyon Formation at their respective locations but above the contact with the Brushy Basin Member. All seeps and springs (except Cottonwood Seep which is located within the Morrison Formation near the Brushy Basin Member/Westwater Canyon Member contact) are associated with conglomeratic portions of the Burro Canyon Formation. Provided they are poorly indurated the more conglomeratic portions of the Burro Canyon Formation are likely to have higher permeabilities and the ability to transmit water more readily than finer-grained portions. This behavior is consistent with on-site drilling and hydraulic test data that associates higher permeability with the poorly indurated coarser-grained horizons detected east and northeast of the TMS that are associated with the chloroform plume. 3. Cottonwood Seep is located more than 1,500 feet west of the mesa rim in an area where the Dakota Sandstone and Burro Canyon Formation (which hosts the perched water system) are absent due to erosion (Figures E.1 and E.2). Cottonwood Seep occurs near a transition from slope-forming to bench-forming morphology (indicating a change in lithology). Cottonwood Seep (and 2nd Seep located immediately to the north [Figure 6]) is interpreted to originate from coarser-grained materials within the lower portion of the Brushy Basin Member (or upper portion of the Westwater Canyon Member) of the Morrison Formation. Alternatively, Cottonwood Seep may originate from coarser-grained materials of the Westwater Canyon (sandstone) Member intertongueing with the overlying Brushy Basin Member at the transition between the two Members. The presence of coarser-grained materials similar to the Salt Wash (sandstone) Member within the lower portion of the Brushy Basin member is discussed in Shawe (2005). The intertongueing of the Westwater Canyon and Brushy Basin Members is discussed in Craig et al. (1955) and Flesch (1974). Based on lithologic cross sections provided in TITAN (1994), the elevation of Cottonwood Seep (5,234 ft amsl) is within 5 to 15 feet of the elevation of the contact between the Brushy Basin Member and the underlying Westwater Canyon Member (5,220 to 5,230 ft amsl). This is also shown in Figure 3. Cottonwood Seep is therefore not (directly) connected to the perched water system at the site. 4. Only Ruin Spring appears to receive a predominant and relatively consistent proportion of its flow from perched groundwater. Ruin Spring originates from conglomeratic Burro Canyon Formation sandstone where it contacts the underlying Brushy Basin Member, at an elevation above the alluvium in the associated drainage. Westwater Seep, which also originates at the contact between the Burro Canyon Formation and the Brushy Basin Member, likely receives a significant contribution from perched water. All seeps and springs other than Ruin Spring (and 2nd Seep just north of Cottonwood Seep) are located within alluvium occupying the basal portions of small drainages and canyons. The relative contribution of flow to these features from bedrock and from alluvium is indeterminate. 5. All seeps and springs are reported to have enhanced flow during wet periods. For seeps and springs associated with alluvium, this behavior is consistent with an alluvial contribution to flow. Enhanced flow during wet periods at Ruin Spring, which originates from bedrock above the level of the alluvium, likely results from direct recharge of Burro Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 86 Canyon Formation and Dakota Sandstone exposed near the mesa margin in the vicinity of Ruin Spring. This recharge would be expected to temporarily increase the flow at Ruin Spring (as well as other seeps and springs where associated bedrock is directly recharged) after precipitation events. As discussed previously, local recharge is consistent with Darcy’s law calculations of perched water flow to Ruin Spring and Westwater Seep. 6. The assumption that the seep or spring elevation is representative of the perched water elevation is likely to be correct only where the feature receives most or all of its flow from perched water and where the supply is relatively continuous (for example at Ruin Spring). The perched water elevation at the location of a seep or spring that receives a significant proportion of water from a source other than perched water may be different from the elevation of the seep or spring. The elevations of seeps that are dry for at least part of the year will not be representative of the perched water elevation when dry. Some uncertainty therefore results from including these seeps and springs in the contouring of perched water levels. However, even if such springs are sometimes dry, the presence of cottonwoods suggests that perched groundwater is close to the surface at these locations. The rate of perched water flow in the southwest area of the site (downgradient of the TMS) is small and contributions from local recharge are needed to explain many areas of higher saturated thickness affected by discharge points such as Westwater Seep and Ruin Spring that are downgradient of areas of low saturated thickness (HGC, 2012b). The presence of local recharge is expected to affect the water quality of seeps and springs and has the potential to dilute any dissolved constituents that may migrate from upgradient areas. As discussed in HGC (2012c), samples of selected archived drill core and drill cuttings were analyzed visually and quantitatively by a contract analytical laboratory. Table 13 and Figure 32 summarize the occurrence of pyrite in site borings based on lithologic logs and laboratory analyses. The results verify the site-wide, apparently ubiquitous existence of pyrite in the perched zone at the site. The existence of pyrite is confirmed at locations upgradient, cross- gradient, and downgradient of the Mill site and TMS. The results are consistent with Shawe’s (1976) description of the Dakota Sandstone and Burro Canyon Formations as “altered-facies” rocks within which pyrite formed as a result of invasion by pore waters originating from compaction of the overlying Mancos Shale. A large portion of the perched water system at the site is in a transient state, manifested in long- term changes in saturated thicknesses and rates of groundwater flow. This condition is expected to result in trends in pH and concentrations of many dissolved constituents that are unrelated to site operations. Changes in saturated thicknesses and rates of groundwater flow can result in changes in concentrations of dissolved constituents (or pH) for many reasons. For example, as discussed in HGC (2012c), groundwater rising into a vadose zone having a different chemistry Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 87 than the saturated zone can result in changes in pH and groundwater constituent concentrations. If the rise in groundwater represents a long-term trend, long-term changes in groundwater constituent concentrations (or pH) may result. Under conditions where vadose zone chemistry is not markedly different from saturated zone chemistry, changing groundwater flow rates may result in changing constituent concentrations due to changes in dilution. For example, relatively constant flux of a particular solute into the groundwater zone, resulting in a relatively constant groundwater concentration under conditions of steady groundwater flow, will likely result in changing concentrations should groundwater flow become unsteady. If the change in flow rate is in one direction over a long period of time, a long-term trend in the solute concentration is expected to result. Examples include oxygen dissolved in recharge or a constituent present in vadose zone materials overlying perched groundwater that dissolves in recharge and leaches into perched water at a steady rate. An increase in perched flow may cause an increase in dilution and a reduction in constituent concentration and vice-versa. For example, the decrease in dilution related to cessation of water delivery to the northern wildlife ponds has caused increases in dissolved constituent concentrations within the chloroform plume and, to a lesser extent, the nitrate plume. Furthermore the lined cells within the TMS are expected to act as barriers to natural recharge and exchange of gas with the atmosphere; their mere presence may thus result in changes in perched water chemistry. Any such changes are likely to be relatively slow and in one direction, potentially yielding long term trends in parameter values. The perched groundwater chemistry at the Mill is also expected to be impacted by the following factors: 1. The relatively low permeability of the perched zone. This condition increases groundwater residence times and the time available for groundwater to react with the formation. 2. The location of the perched system between two shales, the underlying Brushy Basin Member of the Morrison Formation and the overlying Mancos Shale. Both are potential sources of numerous dissolved constituents. The potential for natural contamination from the Mancos Shale is discussed in USDOE (2011). 3. The rate of interaction between the Mancos and Brushy Basin Member shales and the perched water. Interaction with the Mancos Shale at any particular location will depend on the presence, thickness, and composition of the Mancos, the rate of recharge through the Mancos into the perched zone, and the saturated thickness and rate of groundwater flow in the perched zone. Interaction with the Brushy Basin Member at any particular location will depend on the composition of the Brushy Basin, and the saturated thickness and rate of flow in the perched zone. Oxygen introduced into site monitoring wells may Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 88 also react with the Brushy Basin and affect the chemistry of perched groundwater in contact with the Brushy Basin. 4. The rate of oxygen introduction into the perched zone via recharge or via site groundwater monitoring wells. Introduced oxygen is available to oxidize constituents such as pyrite, which impacts the local groundwater chemistry near each recharge source and near each well by releasing acid and sulfate. The resulting increased acidity can also destabilize various mineral phases in the aquifer matrix. The degree of impact on groundwater chemistry will depend on the amount of pyrite, the rate of oxygen transfer, the neutralization capacity and saturated thickness of the perched zone, and the rate of groundwater flow. 5. Elements other than iron and sulfur as contaminants in pyrite. Pyrite reacting with oxygen introduced into the formation will release these elements, potentially altering both the vadose zone and the groundwater chemistry. The likelihood of pyrite having significant contaminants (such as selenium) is enhanced considering its origin from fluids expelled from the Mancos. As discussed in EFRI (2021b), bottle-roll tests using pyrite-bearing core from the formation hosting perched groundwater at the site yielded bottle-roll solutions initially consisting of laboratory-grade DI water generating as much as 74 µg/L beryllium; 118 µg/L cadmium; 79 µg/L cobalt; 959 µg/L copper; 4,120 µg/L manganese; 278 µg/L nickel; 303 µg/L selenium; 2.3 µg/L thallium; 6,700 µg/L uranium; and 1,680 µg/L zinc; as well as elevated concentrations other constituents. Changes in perched zone constituent concentrations and pH are therefore expected to result from the introduction of oxygen into the subsurface, the oxidation of pyrite and other constituents, changes in recharge rates, and past and current recharge passing through the Mancos Shale. Pyrite may also be oxidized by nitrate, impacting wells affected by the nitrate plume (which originates approximately 1,000 feet upgradient of the TMS). Decreasing trends in pH accompanied by increasing sulfate concentrations in MW-series wells that were previously OOC for pH were determined to result from oxidation of pyrite based on screening-level calculations and geochemical modeling presented in HGC (2012c). The calculations also indicated that pyrite existed in sufficient quantity to maintain these trends provided sufficient oxygen was available. In addition, pH decreases at wells impacted by the nitrate plume could result from nitrate degradation of pyrite by the reaction mechanism that produces, rather than consume, acid as discussed in Section 4.4.2. Furthermore, although the pH decrease was an apparently site-wide phenomenon, since about 2016, pH in nearly all MW-series wells has stabilized and has begun to increase. As discussed in EFRI (2022a) and EFRI (2022d), because TMS solutions have very low pH, the post-2016 increases indicate that TMS solutions cannot be impacting groundwater. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 89 6.1 Perched Water Pore Velocities in the Nitrate Plume Area Perched groundwater pore velocities and travel times calculated within the nitrate plume along Path 1 (Figure 27) yield an estimated average pore velocity of approximately 11 ft/yr and a travel time of approximately 176 years, based on a fourth quarter, 2021 hydraulic gradient of 0.0165 ft/ft. Historic hydraulic gradients within the area of the nitrate plume were likely much larger than the current hydraulic gradient of 0.0165 ft/ft during the time prior to Mill construction when the historical pond was active (Figure 1B). Based on historic water levels in the vicinities of MW-30 and MW-31, located along the downgradient margin of cell 2 (Appendix D), and at the downgradient margin of the nitrate plume, an historic hydraulic gradient is estimated as approximately 0.048 ft/ft. This is more than four times the overall average site hydraulic gradient of approximately 0.011 ft/ft (calculated between TWN-19 and Ruin Spring). Using the estimated historic hydraulic gradient of 0.048 ft/ft, the estimated historic pore velocity downgradient of the historical pond is approximately 32 ft/yr, implying that nitrate originating from the historical pond could have migrated to the downgradient edge of cell 2 within 69 years. Assuming the historical pond was active by 1920, that nitrate was conservative, and ignoring hydrodynamic dispersion, nitrate originating from the historical pond could have reached the vicinities of MW-30 and MW-31 by 1989. 6.2 Perched Water Pore Velocities in the Vicinity of the Chloroform Plume Perched groundwater pore velocities and travel times in the vicinity of the chloroform plume along Paths 2A and 2B (Figure 27) were calculated based on fourth quarter, 2021 hydraulic gradients of 0.034 ft/ft and 0.057 ft/ft, respectively. The estimated average pore velocity along Path 2A is approximately 63 ft/yr, implying that approximately 17 years would be required to traverse Path 2A. The estimated average pore velocity along Path 2B is approximately 38 ft/yr, implying that approximately 28 years would be required to traverse Path 2B. Historic hydraulic gradients within the northern (upgradient) areas of the eastern portion of the chloroform plume (prior to about 1990) were likely larger than current hydraulic gradients and contributed to relatively rapid movement of chloroform from the abandoned scale house leach field (located immediately north of TW4-18) to MW-4 where chloroform was detected in 1999. Based on historic water levels (Appendix D) the hydraulic gradient between the abandoned scale house leach field and MW-4 is estimated as approximately 0.048 ft/ft in 1990 and approximately 0.029 ft/ft in 1999, averaging 0.038 ft/ft. This is more than three times the overall average site Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 90 hydraulic gradient of approximately 0.011 ft/ft (calculated between TWN-19 and Ruin Spring), but is within the range of hydraulic gradients occurring at present within and adjacent to the chloroform plume, and is similar to the current hydraulic gradient of approximately 0.041 ft/ft just east the plume, between non-pumping wells TW4-36 and TW4-27. The estimated historic hydraulic gradient implies an average pore velocity prior to 1999 of approximately 84 ft/yr, sufficient for chloroform to have migrated from the abandoned scale house leach field to MW-4 between 1978 and 1999. This calculation implies that chloroform could have migrated nearly to TW4-4 by 1999. 6.3 Hydrogeology and Perched Water Pore Velocities in the Southwest Area Investigation of the southwest area of the site, including seeps and springs (HGC, 2012b), indicates that permeabilities in the southwest portion of the site are on average lower than estimated prior to 2010 (as for example in HGC, 2009), and that perched water discharges to Westwater Seep and Ruin Spring, but there is no evidence for a direct hydraulic connection between the perched water zone and Cottonwood Seep. The hydraulic test and water level data also demonstrate that the perched zone southwest of cell 4B is inadequate as a primary supply to Cottonwood Seep by several orders of magnitude and that that the primary source of Cottonwood Seep lies elsewhere. However, a hypothetical connection between the perched zone near piezometer DR-8 and Cottonwood Seep is postulated for the purposes of calculating perched water travel times and to allow for the possibility that an as yet unidentified connection may exist. Important results of the southwest area investigation are: 1. The Brushy Basin Member erosional paleosurface in the southwest area of the Mill site is dominated by a paleoridge extending from beneath cell 4B to abandoned boring DR-18 (Figure 8). The paleoridge is flanked to the west by a north-south trending paleovalley oriented roughly parallel to the western mesa rim (Figure 8). 2. The southwest area of the Mill site is characterized by generally low saturated thicknesses, low permeabilities, and relatively shallow hydraulic gradients. This is illustrated in Table 1 and Figure 14. Hydraulic gradients in the southwest portion of the site are typically close to 0.1 ft/ft, but are less than approximately 0.005 ft/ft west/southwest of cell 4B, between cell 4B and DR-8. 3. The paleotopography of the Brushy Basin Member erosional surface has a greater influence on perched water flow in the southwest portion of the site than other areas because of the low saturated thicknesses and dry areas associated with the paleoridge extending south-southwest from the TMS (Figures 8, 14, 18, and 19). Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 91 4. The low transmissivities implied by the low permeabilities and low saturated thicknesses combined with the shallow hydraulic gradients imply low rates of perched water flow in the southwest portion of the site. Calculated average pore velocities along Pathlines 3, 5, and 6 (Figure 27) from the TMS to known discharge points Westwater Seep and Ruin Spring range from 0.60 ft/yr to 0.91 ft/yr, and travel times from approximately 2,895 to 19,665 years based on fourth quarter, 2021 water level data. If vadose zone travel times from the base of the individual cells to the perched water are included, the range of calculated travel times is approximately 3,175 to 19,995 years. 5. The estimated travel time from the TMS to the vicinity of DR-8 (Path 4) is approximately 15,865 years based on fourth quarter, 2021 water level data and a calculated pore velocity of 0.26 ft/yr. Including the vadose travel time of approximately 329 years yields a total travel time of approximately 16,195 years. Assuming a hypothetical pathway to Cottonwood Seep, the time to travel along Path 4 and thence along the potential pathway from the edge of Path 4 to Cottonwood Seep (which adds approximately 2,150 horizontal feet) is expected to be significantly greater than 16,195 years. 6. Brushy Basin Member paleotopography influences the locations of Westwater Seep and Ruin Spring; both are located in paleovalleys within the Brushy Basin Member paleosurface (Figure 8). 7. Local recharge is needed to explain areas of relatively large saturated thickness that supply Westwater Seep and Ruin Spring, because lateral flow into these areas from upgradient low saturated thickness portions of the perched zone is inadequate. The calculated perched zone recharge rate in the approximate 175 acre area southwest of Westwater Seep (near DR-2 [abandoned] and DR-5) is approximately 0.001 in/yr. 8. The perched water system in the southwestern portion of the site is inadequate as the primary supply to Cottonwood Seep by several orders of magnitude. Therefore the primary source(s) of Cottonwood Seep must lie elsewhere. 6.4 Fate of Chloroform and Nitrate Natural attenuation of nitrate and chloroform in the perched water is expected to result from physical processes that include dilution by recharge and hydrodynamic dispersion. Volatilization is another physical process that is expected to lower chloroform concentrations in perched water. Mass reduction processes expected to lower both nitrate and chloroform concentrations include chemical and biologically-mediated processes. These processes include reduction of nitrate by pyrite, and anaerobic reductive dechlorination of chloroform. Both nitrate and chloroform plumes are under remediation by pumping. Pumping acts to reduce nitrate and chloroform mass as rapidly as is practical, allowing natural attenuation to be more effective. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 92 The nearest potential discharge points for nitrate originating from the nitrate plume are Westwater Seep and Ruin Spring, both located downgradient of the TMS at the site. The nearest potential discharge point for chloroform is Ruin Spring. Corral Springs, located cross-gradient of the TMS, appears to be positioned too far east for any potential future impacts by chloroform. Calculations of perched groundwater flow rates indicate that thousands of years will be required for perched groundwater at the downgradient margins of the TMS to reach a discharge point. Because both chloroform and nitrate plumes are more distant from discharge points than the TMS, even more time would be required for chloroform or nitrate to reach a discharge point. Since both plumes are expected to naturally attenuate within less than 200 years (through physical, chemical, and/or biological processes), even in the absence of direct mass removal by pumping, there is more than sufficient time for any residual chloroform or nitrate within the respective plumes to degrade before reaching a discharge point. In addition, as discussed in HGC (2018e), numerical flow and transport modeling using conservatively large hydraulic conductivities and hydraulic gradients, and conservatively small dispersivities, demonstrates that natural attenuation, even in the absence of nitrate reduction by pyrite and mass removal by pumping, would reduce all concentrations within the nitrate plume to less than the 10 mg/L GCAL before reaching a property boundary. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 93 7. PROPOSED CELLS 5A AND 5B Cells 5A and 5B are proposed to be located as shown on Figure 33. Based on analyses presented in HGC (2018d); HGC (2018e); and HGC (2019a), seven new perched groundwater monitoring wells MW-42 though MW-48; and one new perched groundwater piezometer (DR-26); are proposed to be located as shown on Figure 33. As final approval of the proposed design is pending, the locations of these proposed installations are subject to change. Details of the hydrogeology of the perched groundwater zone beneath proposed cells 5A and 5B, and the rationale for selection of the number and locations of monitoring installations, are provided in Appendix F. In addition to HGC (2018d), HGC (2018e) and HGC (2019a), conclusions presented in Appendix F are based on HGC (2001a); HGC (2001b); HGC (2005); and Knight-Piésold (1998). Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 94 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 95 8. REFERENCES Aubrey, W. M. 1992. Stratigraphy and Sedimentology of Latest Jurassic to Mid-Cretaceous Rocks, Four Corners Area, in Semken, S. C., ed., Field Guide to a Geologic Excursion in the Northeastern Navajo Nation: Shiprock, New Mexico, Navajo Community College, p. 33-40. Avery, C. 1986. Bedrock Aquifers of Eastern San Juan County, Utah: Utah Department of Natural Resources Technical Publication no. 86, 114 p. Baker. 2007. Passive Treatment of Selenium-Contaminated Groundwater. Colorado NPS Connection, Summer, 2007. Aguerri, 2010. Denitrification With Pyrite for Bioremediation of Contaminated Groundwater. PHD Thesis. University of Barcelona. Bosch, Julian; Keun-Young Lee; Guntram Jordan; Kyoun-Woong Kim; and Rainer U. 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Description of the Telluride Quadrangle (Colorado): U.S. Geological Survey Geological Atlas, Folio 57, 19 p. Deditius, Artur P., Satoshi Utsunomiya, Martin Reich, Stephen E. Kesler, Rodney C. Ewing, Robert Hough, and John Walsh. 2011. Trace Metal Nonoparticles in Pyrite. Ore Geology reviews 42 (2011) p. 32-46. Doelling, H. H. 2004. Geologic Map of the La Sal 30′ x 60’ Quadrangle, San Juan, Wayne, and Garfield Counties, Utah, and Montrose and San Miguel Counties, Colorado: Utah Geological Survey Map 205, scale 1:100,000. Dames and Moore. 1978. White Mesa Uranium Project, San Juan County, Utah. For Energy Fuels Nuclear, Inc. January 30, 1978. Energy Fuels Resources, Inc. (EFRI). 2013. Proposal for Remediation of Nitrate Contaminated Soils. Phase I of Final Nitrate Corrective Action Plan, May 7, 2012 and Stipulation and Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 96 Consent Order of December 12, 2012 Docket UGW-12-04. Submitted to R. Lundberg, Utah Division of Radiation Control, December 12, 2013. EFRI. 2018a. White Mesa Uranium Mill. Nitrate Monitoring Report, State of Utah Stipulated Consent Agreement, January 2009, Docket No. UGW09-03, 4th Quarter (October through December) 2017. EFRI. 2018b. White Mesa Uranium Mill. Chloroform Monitoring Report, State of Utah Stipulation and Consent Order Docket No. UGW-20-01, 4th Quarter (October through December) 2017. EFRI, 2020. White Mesa Uranium Mill, State of Utah Groundwater Discharge Permit No. UGW370004. Source Assessment Report Under Part I.G.4 For Exceedances in MW-28 in the First Quarter of 2020. October 20, 2020. EFRI, 2021a. 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Pneumatolytic Processes in the Formation of Minerals and Ores, in Ore Deposits of the Western States (Lindgren Volume): American Institute Mining & Metallurgical Engineers, p. 58-106 Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 97 Fleisher, 1953. Recent Estimates of the Abundance of the Elements in the Earth’s Crust. United States Geological Survey Circular 285. Flesch. 1974. Stratigraphy and Sedimentology of the Morrison Formation (Jurassic), Ojito Spring Quadrangle, Sandoval County, New Mexico: A Preliminary Discussion. New Mexico Geological Society Guidebook, 25th Field Conference, Ghost Ranch (Central- Northern New Mexico), 1974. Goodknight, C. S., and Smith, G. M. 1996. Influences of Geologic and Hydrogeologic Conditions on the Uranium Mill Tailings Repository Design, Monticello, Utah, in Huffman, A. 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Gravitational Compaction of Clays and Shales: American Association of Petroleum Geologists Bulletin v. 10, no. 11, p. 241-287. Huff, L.C., and Lesure, F. G. 1965. Geology and Uranium Deposits of Montezuma Canyon area, San Juan County, Utah: U.S. Geological Survey Bulletin 1190, 102 p. Hurst and Solomon. 2008. Utah Division of Radiation Control. Summary of Work Completed, Data Results, Interpretations and Recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding, Utah. Prepared by T. Grant Hurst and D. Kip Solomon, Department of Geology and Geophysics, University of Utah. Submitted May 2008. Hydro Geo Chem, Inc. (HGC). 1988. WHIP. Well Hydraulics Interpretation Program, Version 3.22, User’s Manual. July 1988. HGC. 2001a. Letter to Mr. Harold Roberts, International Uranium Corporation (Regarding the Review of the 1994 Drilling Program). June 21, 2001. HGC. 2001b. Assessment of the Effectiveness of Using Existing Monitoring Wells For GWDP Detection Monitoring at the White Mesa Uranium Mill, Blanding, Utah. September 25, 2001. HGC. 2002. Hydraulic Testing at the White Mesa Uranium Mill Near Blanding, Utah During July, 2002. August 22, 2002. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 98 HGC. 2004. Final Report. Long Term Pumping at MW-4, TW4-10, and TW4-15. White Mesa Uranium Mill Near Blanding, Utah. May 26, 2004. HGC. 2005. Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill, April through June 2005. August 3, 2005. HGC. 2007a. Preliminary Corrective Action Plan. White Mesa Uranium Mill Site Near Blanding, Utah. August 20, 2007. HGC. 2007b. Preliminary Contamination Investigation Report. White Mesa Uranium Mill Site Near Blanding, Utah. November 20, 2007. HGC. 2009. Site Hydrogeology and Estimation of Groundwater Travel Times in the Perched Zone. White Mesa Uranium Mill Near Blanding, Utah. August 27, 2009. HGC. 2010a. Letter Report to David Frydenlund, Esq. February 10, 2010. HGC. 2010b. Letter Report to David Frydenlund, Esq. February 12, 2010. HGC. 2010c. Perched Monitoring Well Installation and Hydraulic Testing. White Mesa Uranium Mill, October 2009. March 10, 2010. HGC. 2010d. Letter Report to David Frydenlund, Esq. March 10, 2010. HGC. 2010e. Hydraulic Testing of TW4-4, TW4-6, and TW4-26. White Mesa Uranium Mill. July 2010. September 20, 2010. HGC. 2010f. Installation and Hydraulic Testing of Perched Monitoring Wells MW-33, MW-34, and MW-35 at the White Mesa Uranium Mill Near Blanding Utah. October 11, 2010. HGC. 2010g. Hydrogeology of the Perched Groundwater Zone and Associated Seeps and Springs Near the White Mesa Uranium Mill Site, Blanding, Utah. November 12, 2010. HGC. 2011a. Installation and Hydraulic Testing of Perched Monitoring Wells MW-36 and MW- 37 at the White Mesa Uranium Mill Near Blanding Utah. June 28, 2011. HGC. 2011b. Redevelopment of Existing Perched Monitoring Wells. White Mesa Uranium Mill Near Blanding, Utah. September 30, 2011. HGC. 2011c. Installation, Hydraulic Testing, and Perched Zone Hydrogeology of Perched Monitoring Well TW4-27. White Mesa Uranium Mill Near Blanding Utah. November 28, 2011. HGC. 2012a. Corrective Action Plan for Nitrate. White Mesa Uranium Mill Near Blanding, Utah. May 7, 2012. HGC. 2012b. Revised Report on the Hydrogeology of the Perched Groundwater Zone in the Area Southwest of the Tailings Cells. White Mesa Uranium Mill Site. Blanding, Utah. August 3, 2012. HGC. 2012c, Investigation of Pyrite in the Perched Zone. White Mesa Uranium Mill Site. Blanding, Utah. December 7, 2012. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 99 HGC. 2013a. Installation and Hydraulic Testing of Perched Monitoring Wells TW4-28 through TW4-31. White Mesa Uranium Mill Near Blanding Utah. April 30, 2013. HGC. 2013b. Installation and Hydraulic Testing of Perched Monitoring Wells TW4-32 through TW4-34. White Mesa Uranium Mill Near Blanding Utah.As Built Report. October 30, 2013. HGC. 2014a. Contamination Investigation Report. TW4-12 and TW4-27 Areas. White Mesa Uranium Mill Near Blanding, Utah. January 23, 2014. HGC. 2014b. Hydrogeology of the White Mesa Uranium Mill, Blanding Utah. June 6, 2014. HGC. 2014c. Installation and Hydraulic Testing of Perched Monitoring Wells TW4-35 and TW4-36. White Mesa Uranium Mill Near Blanding Utah. As Built Report. July 1, 2014. HGC. 2015. Installation and Hydraulic Testing of Perched Monitoring Well TW4-37. White Mesa Uranium Mill Near Blanding Utah. As Built Report. 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Passier; and Philippe Van Cappellen 2009. Denitrification coupled to pyrite oxidation and changes in groundwater quality in a shallow sandy aquifer. Geochimica et Cosmochimica Acta, vol. 73, pp 6716- 6726. Zhang, Y. 2012. Coupled biogeochemical dynamics of nitrogen and sulfur in a sandy aquifer and implications for groundwater quality. Thesis presented at Utrecht University, Netherlands, November 19, 2012. Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 105 9. LIMITATIONS STATEMENT The opinions and recommendations presented in this report are based upon the scope of services and information obtained through the performance of the services, as agreed upon by HGC and the party for whom this report was originally prepared. 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Hydrogeology of the White Mesa Uranium Mill Blanding, Utah H:\718000\Hydrpt2022\Report\EFRI_Hydrpt22_Final.Docx July 13, 2022 106 TABLES TABLE 1 Results of Slug test Analyses Using KGS and Bouwer-Rice Solutions Bouwer-Rice Bouwer-Rice Test Saturated Thickness K (cm/s) Ss (1/ft) K (cm/s) K (cm/s) Ss (1/ft) K (cm/s) TWN-1 54 1.70E-04 2.22E-03 NI 1.97E-04 1.25E-03 1.36E-04 TWN-2 74 1.49E-05 3.20E-04 2.25E-05 2.04E-05 1.16E-04 2.73E-05 TWN-3 60 8.56E-06 8.73E-06 8.97E-06 7.75E-06 1.53E-05 8.89E-06 TWN-4 85 1.76E-03 3.43E-04 2.79E-05 1.25E-03 1.84E-06 NI TWN-5 77 4.88E-04 3.88E-07 4.06E-04 4.88E-04 3.88E-07 3.70E-04 TWN-6 79 1.74E-04 2.22E-03 NI 3.50E-04 2.22E-12 3.36E-04 TWN-7 11 3.57E-07 2.22E-03 4.59E-07 3.57E-07 2.21E-03 NI TWN-8 80 1.51E-04 3.66E-04 7.55E-05 4.73E-04 1.41E-06 2.48E-04 TWN-9 29 2.99E-05 6.92E-03 2.86E-05 6.02E-05 5.59E-03 7.93E-05 TWN-10 20 3.83E-05 0.1 2.31E-05 8.71E-05 8.12E-03 1.10E-04 TWN-11 68 1.18E-04 1.08E-05 9.83E-05 9.34E-05 7.18E-05 9.78E-05 TWN-12 67 8.05E-05 4.65E-05 7.69E-05 1.28E-04 1.27E-07 7.39E-05 TWN-13 68 2.62E-06 0.1 4.77E-06 2.09E-06 0.1 6.93E-06 TWN-14 57 3.61E-06 6.39E-03 2.74E-06 3.98E-06 3.17E-03 7.93E-06 TWN-15 58 4.75E-05 1.04E-03 2.61E-05 5.86E-05 3.49E-04 6.42E-05 TWN-16 41 0.0142 8.02E-04 6.47E-03 NI NI NI TWN-17 69 3.73E-06 0.033 6.18E-06 1.41E-06 0.061 1.96E-06 TWN-18 83 2.27E-03 2.44E-06 1.14E-03 2.67E-03 2.22E-12 NI TWN-19 50 2.69E-05 2.49E-03 1.81E-05 3.83E-05 3.34E-03 NI TWN-20 19 1.06E-05 5.74E-04 1.07E-05 1.65E-05 2.10E-04 2.22E-05 TWN-21 28 2.80E-05 9.82E-04 3.00E-05 2.97E-05 1.39E-03 4.59E-05 MW-03 (mlt) 5.2 4.00E-07 1.92E-02 1.50E-05 -- -- -- MW-05 (lt)3.90E-06 4.30E-06 MW-05 (et)2.40E-05 1.80E-05 MW-17 18 2.60E-05 1.71E-04 2.70E-05 2.20E-05 -- 3.00E-05 MW-18 58 2.90E-04 4.60E-07 2.40E-04 3.20E-04 -- 2.50E-04 MW-19 80 1.70E-05 1.44E-06 1.30E-05 1.20E-05 -- 1.50E-05 MW-19, confined 47 1.60E-05 3.24E-06 1.20E-05 -- -- -- MW-20 (mlt)9.30E-06 -- MW-20 (mlt)5.90E-06 2.50E-06 MW-22 7.90E-06 -- MW-22 4.40E-06 3.40E-06 MW-23 12 3.20E-08 0.1 1.60E-06 NI NI NI MW-23b 12 2.30E-07 2.30E-03 2.50E-07 NI NI 2.00E-07 MW-24 3.4 4.16E-05 5.20E-03 3.15E-05 3.03E-05 0.0152 3.03E-05 MW-24A 9 1.41E-05 1.10E-02 1.85E-05 1.97E-05 4.88E-03 1.88E-05 MW-25 33 1.10E-04 3.00E-04 7.40E-05 1.70E-04 2.00E-04 1.00E-04 MW-27 36 8.20E-05 5.30E-04 3.60E-05 1.40E-04 8.70E-05 3.10E-05 MW-28 23 1.70E-06 0.02 1.70E-06 1.70E-06 0.02 2.00E-06 MW-29 18 1.10E-04 1.90E-04 9.30E-05 1.30E-04 2.10E-04 1.00E-04 MW-30 24 1.00E-04 2.90E-04 6.40E-05 1.10E-04 1.40E-04 5.10E-05 MW-31 53 7.10E-05 2.50E-05 6.90E-05 7.40E-05 7.20E-06 6.90E-05 MW-32 46 3.00E-05 8.80E-05 2.60E-05 2.80E-05 2.50E-04 3.00E-05 MW-35 12 3.48E-04 1.95E-05 2.18E-04 2.59E-04 1.78E-05 1.65E-04 MW-36 6.2 4.51E-04 4.29E-04 NA 7.73E-04 2.66E-04 6.52E-04 MW-36 (lt)6.2 NA NA 1.84E-04 NA NA NA MW-36 (et)6.2 NA NA 5.07E-04 NA NA NA MW-37 2.9 1.28E-05 2.22E-12 1.21E-05 NA NA NA MW-38 3.0 6.84E-05 0.022 5.90E-05 5.13E-05 0.015 6.86E-05 MW-39 33 1.76E-05 8.07E-04 2.43E-05 1.43E-05 3.80E-03 2.48E-05 MW-40 38 1.26E-04 3.36E-04 1.23E-04 1.26E-04 3.36E-04 2.08E-04 MW-40 (lt)38 NA NA 4.18E-05 NA NA NA TW4-4 (et) 22 NA NA 1.26E-03 NA NA NA TW4-4 (lt) 22 1.66E-03 6.21E-05 2.89E-04 1.63E-03 3.01E-04 7.91E-04 TW4-6 24 1.15E-05 3.67E-05 1.00E-05 1.19E-05 1.49E-04 1.32E-05 TW4-20 43 5.90E-05 1.60E-05 4.20E-05 7.00E-05 1.20E-05 5.30E-05 TW4-21 63 1.90E-04 1.10E-04 3.20E-05 1.90E-04 3.20E-05 9.40E-06 TW4-22 55 1.30E-04 6.80E-06 1.10E-04 1.30E-04 4.50E-06 1.10E-04 TW4-23 43 3.80E-05 7.40E-03 2.90E-05 3.40E-01 6.40E-04 7.90E-05 TW4-24 53 1.60E-04 1.10E-03 1.00E-04 1.20E-04 1.70E-03 5.20E-05 TW4-25 89 5.80E-05 0.001 3.70E-05 7.40E-05 1.10E-03 5.00E-05 TW4-26 18 2.40E-05 3.23E-04 2.16E-05 2.28E-05 3.13E-04 2.55E-05 TW4-27 (uncorrected) NA NA NA 2.13E-06 1.51E-03 1.59E-06 TW4-27 (100% correction) 7.01E-07 2.22E-03 1.99E-06 NA NA NA TW4-27(60% correction) 1.35E-06 1.27E-03 1.15E-06 NA NA NA TW4-28 67.9 3.52E-04 1.22E-06 3.92E-04 3.29E-04 7.49E-06 4.07E-04 TW4-29 17.7 4.24E-05 1.19E-03 5.24E-05 4.52E-05 9.62E-04 5.66E-05 TW4-29 (lt) 17.7 NA NA 2.00E-05 NA NA 3.80E-05 TW4-30 9.6 1.44E-04 1.00E-02 6.22E-05 1.34E-04 1.00E-02 1.38E-04 TW4-30 (et) 9.6 NA NA 1.63E-04 NA NA 2.91E-04 TW4-30 (lt)9.6 NA NA 1.12E-05 NA NA 1.41E-05 TW4-31 18.1 4.18E-05 2.54E-05 3.87E-05 3.24E-05 9.65E-05 4.01E-05 TW4-32 64.8 9.53E-05 1.15E-04 NA 5.34E-05 7.97E-04 5.86E-05 TW4-32(et) 64.8 NA NA 1.09E-04 NA NA 1.34E-04 TW4-32(lt) 64.8 NA NA 2.51E-05 NA NA 1.17E-05 TW4-33 13.1 5.51E-05 3.73E-04 5.78E-05 5.25E-05 5.32E-04 5.76E-05 TW4-34 25.2 9.98E-05 1.13E-03 1.54E-04 9.39E-05 1.54E-03 1.25E-04 TW4-34 (lt) 25.2 NA NA 1.17E-04 NA NA NA TW4-35 8.8 6.27E-05 1.49E-03 5.72E-05 5.72E-05 1.69E-03 6.42E-05 TW4-36 36.7 3.23E-06 1.07E-03 6.39E-06 1.82E-06 2.83E-03 4.79E-06 TW4-37 51.6 1.43E-04 2.14E-04 2.17E-04 1.93E-04 8.60E-05 2.33E-04 TW4-38 6.37E-05 1.15E-04 NA 4.76E-05 2.81E-05 NA TW4-38 (mlt)NA NA 7.16E-05 NA NA 5.54E-05 TW4-38 (lt)NA NA 5.68E-05 NA NA 3.76E-05 TW4-39 5.27E-05 2.03E-04 NA 6.15E-05 1.70E-04 NA TW4-39 (mlt)NA NA 7.21E-05 NA NA 8.41E-05 TW4-39 (lt)NA NA 2.85E-05 NA NA 3.17E-05 TW4-40 19.3 9.81E-03 3.96E-04 8.54E-03 9.81E-03 3.96E-04 6.48E-03 TW4-41 17.9 2.69E-03 2.22E-03 3.03E-03 2.69E-03 2.22E-03 5.40E-03 TW4-42 20.5 2.43E-05 2.22E-03 2.92E-05 3.25E-05 1.55E-03 4.92E-05 TW4-43 19.4 4.37E-05 5.44E-04 5.76E-05 5.84E-05 2.43E-04 6.40E-05 DR-5 12.3 2.95E-05 4.21E-05 3.80E-05 2.86E-05 2.65E-03 3.76E-05 DR-8, Oct 2012 7.8 2.46E-08 1.00E-02 3.56E-07 4.46E-08 1.00E-02 4.45E-07 DR-8, Oct 2011 7.7 3.40E-08 0.01 NA 1.07E-07 0.0011 NA DR-9 24.5 4.49E-04 4.30E-06 3.41E-04 4.73E-04 1.21E-05 4.73E-04 DR-10 3 2.92E-06 6.54E-03 5.56E-06 9.71E-06 8.41E-04 9.71E-06 DR-11 8.9 8.88E-06 8.88E-04 1.54E-05 5.83E-06 2.22E-03 1.11E-05 DR-13 11.2 5.90E-06 7.33E-05 5.38E-06 4.93E-06 1.57E-04 1.49E-06 DR-13(et) 11.2 NA NA NA NA NA 6.81E-06 DR-14 18.8 1.26E-05 7.34E-05 1.66E-05 7.78E-06 4.84E-04 6.18E-06 DR-14(et) 18.8 NA NA NA NA NA 1.23E-05 DR-17 6.5 1.24E-05 1.53E-04 1.43E-05 3.17E-06 5.00E-03 2.19E-06 DR-17(et) 6.5 NA NA NA NA NA 8.35E-06 DR-19 3.5 3.29E-05 2.54E-03 3.78E-05 3.39E-05 1.86E-03 4.08E-05 DR-20 17.9 2.14E-06 1.91E-05 2.69E-06 1.43E-06 1.90E-05 1.89E-06 DR-21 13.5 3.29E-05 7.17E-06 3.60E-05 2.21E-05 1.87E-04 3.49E-05 DR-23 7.5 1.96E-05 3.85E-04 2.35E-05 7.49E-06 5.00E-03 4.51E-06 DR-23(et) 7.5 NA NA NA NA NA 2.16E-05 DR-24 17.4 1.64E-05 7.49E-05 1.43E-05 1.64E-05 7.49E-05 8.23E-06 DR-24(et) 17.4 NA NA NA NA NA 1.97E-05 Notes: Bouwer-Rice = Unconfined Bouwer-Rice solution method in Aqtesolv™ unless otherwise noted cm/s = centimeters per second ft = feet K = hydraulic conductivity KGS = Unconfined KGS solution method in Aqtesolv™ unless otherwise noted Ss= specific storage NI= Not Interpretable . et= early time data mlt=middle to late time data lt=late time data NA=not applicable Automatically Logged Data 12 -- -- 51 1.00E-06 2.00E-03 Hand Collected Data KGS KGS 10 3.50E-06 4.40E-03 57.97 56.3 9.00E-07 -- 3.20E-06 -- -- -- 9 H:\718000\hydrpt2022\tables\T1_2_3_6_Hydraulic_props_4Q21_rev.xls: T1-KGS and B-R slug test K data TABLE 2 Results of Recovery and Slug Test Analyses Using Moench Solution Hand Data Well ID Interpretation Method Type Hydraulic Conductivity (cm/sec) Storativity Saturated Thickness (feet) Skin Hydraulic Conductivity (cm/sec) WHIP pump/recovery 7.70E-07 0.0082 20 none 7.70E-07 AQTESOLV (Moench, Leaky)pump/recovery 7.70E-07 0.0082 20 none 7.70E-07 AQTESOLV (Moench, Unconfined)pump/recovery 8.90E-07 0.01 40 none -- MW-03 WHIP slug 4.30E-05 0.01 5.2 none -- MW-05 WHIP slug 1.10E-05 0.1 10 none -- MW-17 WHIP slug 2.90E-05 0.01 18 none -- WHIP slug 4.40E-04 2.20E-05 45 none -- WHIP slug 5.30E-04 0.02 45 6.54 -- WHIP slug 7.10E-06 0.032 47 none -- WHIP slug 1.70E-05 0.027 47 2.24 -- AQTESOLV (Moench, Leaky)slug 1.70E-05 0.027 47 2.24 -- MW-20 WHIP slug 8.20E-06 0.02 12 none -- MW-22 WHIP slug 4.20E-06 0.014 51 none -- Notes: cm/sec = Centimeters per second WHIP analyses via modfied Moench Leaky Solution MW-01 MW-19 Automatically-Logged Data MW-18 H:\718000\hydrpt2022\tables\T1_2_3_6_Hydraulic_props_4Q21.xls: T2-Moench and WHIP data 4/7/2022 TABLE 3 Estimated Perched Zone Hydraulic Properties Based on Analysis of Observation Wells Near MW-4 and TW4-19 During Long Term Pumping of MW-4 and TW4-19 Observation Well Theis Solution (Confined or Unconfined) Transmissivity (ft2/day) Storage Coefficient Water Bearing Zone Thickness (feet) Average Hydraulic Conductivity (ft/day) Average Hydraulic Conductivity (cm/sec) Unconfined 8.9 0.023 39 0.23 8.20E-05 Confined 8.4 0.023 24 0.35 1.30E-04 Unconfined 4.6 0.0065 39 0.12 4.30E-05 Confined 3.8 0.0063 24 0.16 5.70E-05 Unconfined 4.7 0.011 39 0.12 4.30E-05 Confined 3.3 0.011 24 0.14 5.00E-05 Unconfined 4.5 0.010 39 0.12 4.30E-05 Confined 3.9 0.010 24 0.16 5.70E-05 Unconfined 5.8 0.019 39 0.15 5.40E-05 Confined 3.5 0.019 24 0.15 5.40E-05 Unconfined 12.4 0.0029 39 0.32 1.10E-04 Confined 9.1 0.0031 24 0.38 1.40E-04 Unconfined 89 0.0043 67 1.3 4.60E-04 Confined 87 0.0043 31 2.8 1.00E-03 Unconfined 72 0.0043 67 1.1 3.90E-04 Confined 71 0.0043 31 2.3 8.20E-04 Unconfined 48 0.0077 67 0.72 2.60E-04 Confined 46 0.0076 31 1.5 5.40E-04 Unconfined 15 0.0037 67 0.22 7.90E-05 Confined 12 0.0037 31 0.39 1.40E-04 Unconfined 19 0.0036 67 0.28 1.00E-04 Confined 18 0.0035 31 0.58 2.10E-04 Unconfined 76 0.0046 67 1.1 3.90E-04 Confined 74 0.0046 31 2.4 8.60E-04 Unconfined 44 0.12 67 0.66 2.40E-04 Confined 39 0.12 31 1.3 4.60E-04 Notes: cm/sec = Centimeters per second ft/day = Feet per day ft2/day = Feet squared per day TW4-16 TW4-18 TW4-19 TW4-5 TW4-9 TW4-10 TW4-15 (MW-26) MW-4A (early time) TW4-1 TW4-2 TW4-7 TW4-8 MW-4A H:\718000\hydrpt2022\tables\T1_2_3_6_Hydraulic_props_4Q21.xls: T3-Pump Test Obs Wells Page 1 of 1 4/7/2022 TABLE 4 Summary of Hydraulic Properties White Mesa Uranium Mill from TITAN (1994) Soils 6 Laboratory Test 9 D&M 1.20E+01 1.20E-05 7 Laboratory Test 4.5 D&M 1.00E+01 1.00E-05 10 Laboratory Test 4 D&M 1.20E+01 1.20E-05 12 Laboratory Test 9 D&M 1.40E+02 1.40E-04 16 Laboratory Test 4.5 D&M 2.20E+01 2.10E-05 17 Laboratory Test 4.5 D&M 9.30E+01 9.00E-05 19 Laboratory Test 4 D&M 7.00E+01 6.80E-05 22 Laboratory Test 4 D&M 3.90E+00 3.80E-06 Geometric Mean 2.45E+01 2.37E-05 Dakota Sandstone No. 3 Injection Test 28-33 D&M (1) 5.68E+02 5.49E-04 No. 3 Injection Test 33-42.5 D&M 2.80E+00 2.71E-06 No. 12 Injection Test 16-22.5 D&M 5.10E+00 4.93E-06 No. 12 Injection Test 22.5-37.5 D&M 7.92E+01 7.66E-05 No. 19 Injection Test 26-37.5 D&M 7.00E+00 6.77E-06 No. 19 Injection Test 37.5-52.5 D&M 9.44E+02 9.12E-04 Geometric Mean 4.03E+01 3.89E-05 Burro Canyon Formation No. 3 Injection Test 42.5-52.5 D&M 5.80E+00 5.61E-06 No. 3 Injection Test 52.5-63 D&M 1.62E+01 1.57E-05 No. 3 Injection Test 63-72.5 D&M 5.30E+00 5.13E-06 No. 3 Injection Test 72.5-92.5 D&M 3.20E+00 3.09E-06 No. 3 Injection Test 92.5-107.5 D&M 4.90E+00 4.74E-06 No. 3 Injection Test 122.5-142 D&M 6.00E-01 5.80E-07 No. 9 Injection Test 27.5-42.5 D&M 2.70E+00 2.61E-06 No. 9 Injection Test 42.5-59 D&M 2.00E+00 1.93E-06 No. 9 Injection Test 59-82.5 D&M 7.00E-01 6.77E-07 No. 9 Injection Test 82.5-107.5 D&M 1.10E+00 1.06E-06 No. 9 Injection Test 107.5-132 D&M 3.00E-01 2.90E-07 No. 12 Injection Test 37.5-57.5 D&M 9.01E-01 8.70E-07 No. 12 Injection Test 57.5-82.5 D&M 1.40E+00 1.35E-06 No. 12 Injection Test 82.5-102.5 D&M 1.07E+01 1.03E-05 No. 28 Injection Test 76-87.5 D&M 4.30E+00 4.16E-06 No. 28 Injection Test 87.5-107.5 D&M 3.00E-01 2.90E-06 No. 28 Injection Test 107.5-132.5 D&M 2.00E-01 1.93E-07 WMMW1 (7) Recovery 92-112 Peel (2) 3.00E+00 2.90E-06 WMMW3 (7) Recovery 67-87 Peel 2.97E+00 2.87E-06 WMMW5 (7) Recovery 95.5-133.5 H-E 1.31E+01 1.27E-05 WMMW5 (7) Recovery 95.5-133.5 Peel 2.10E+01 2.03E-05 WMMW11 (7) Recovery 90.7-130.4 H-E (3)1.23E+03 1.19E-03 WMMW11 (7) Single Well Drawdown 90.7-130.4 Peel 1.63E+03 1.58E-03 WMMW12 (7) Recovery 84-124 H-E 6.84E+01 6.61E-05 WMMW12 (7) Recovery 84-124 Peel 6.84E+01 6.61E-05 WMMW14 Single Well Drawdown 90-120 (5) H-E 1.21E+03 1.16E-03 WMMW14 Single Well Drawdown 90-120 (6) H-E 4.02E+02 3.88E-04 WMMW15 Single Well Drawdown 99-129 H-E 3.65E+01 3.53E-05 WMMW15 (7) Recovery 99-129 Peel 2.58E+01 2.49E-05 WMMW16 Injection Test 28.5-31.5 Peel 9.42E+02 9.10E-04 WMMW16 Injection Test 45.5-51.5 Peel 5.28E+01 5.10E-05 WMMW16 Injection Test 65.5-71.5 Peel 8.07E+01 7.80E-05 WMMW16 Injection Test 85.5-91.5 Peel 3.00E+01 2.90E-05 WMMW17 Injection Test 45-50 Peel 3.10E+00 3.00E-06 WMMW17 Injection Test 90-95 Peel 3.62E+00 3.50E-06 WMMW17 Injection Test 100-105 Peel 5.69E+00 5.50E-06 WMMW18 Injection Test 27-32 Peel 1.14E+02 1.10E-04 WMMW18 Injection Test 85-90 Peel 2.59E+01 2.50E-05 WMMW18 Injection Test 85-90 Peel 2.69E+01 2.60E-05 WMMW18 Injection Test 120-125 Peel 4.66E+00 4.50E-06 WMMW19 Injection Test 55-60 Peel 8.69E+00 8.40E-06 WMMW19 Injection Test 95-100 Peel 1.45E+00 1.40E-06 Geometric Mean 1.05E+01 1.01E-05 Entrada/Navajo Sandstones WW-1 Recovery D'Appolonia (4) 3.80E+02 3.67E-04 WW-1 Multi-well drawdown D'Appolonia 4.66E+02 4.50E-04 WW-1,2,3 Multi-well drawdown D'Appolonia 4.24E+02 4.10E-04 Geometric Mean 4.22E+02 4.08E-04 Notes (1) D&M = Dames & Moore, Environmental Report, White Mesa Uranium Project, January 1978. (2) Peel = Peel Environmental Services, UMETCO Minerals Corp., Ground Water Study, White Mesa Facility, June 1994. (3) H-E = Hydro-Engineering, Ground-Water Hydrology at the White Mesa Tailings Facility, July 1991. (4) D'Appolonia, Assessment of the Water Supply System, White Mesa Project, Feb. 1981. (5) Early test data. (6) Late test data. (7) Test data reanalyzed by TEC. Hydraulic Conductivity (ft/yr) Hydraulic Conductivity (cm/sec) Boring/ Well Location Test Type Interval (ft-ft) Document Referenced H:\718000\hydrpt14\Titan_material_props.xls TABLE 5 Properties of the Dakota/Burro Canyon Formation White Mesa Uranium Mill from TITAN (1994) Dakota WMMW-16 26.4' - 38.4' 1.50 3.30 135.20 17.90 2.64 18.20 5.10 -- -- -- Sandstone WMMW-16 37.8' - 38.4' 0.40 0.80 127.40 22.40 2.63 3.70 6.30 -- -- -- Sandstone WMMW-17 27.0' - 27.5' 0.30 0.60 138.80 13.40 2.57 4.80 5.10 -- -- -- Sandstone WMMW-17 49.0' - 49.5' 3.60 7.10 121.90 26.00 2.64 27.20 9.60 -- -- -- Sandstone Burro Canyon WMMW-16 45.0' - 45.5' 5.60 12.60 140.90 16.40 2.70 77.20 --29.60 15.40 14.20 Sandy Mudstone WMMW-16 47.5' - 48.0' 2.60 5.90 142.80 12.00 2.60 48.90 4.40 -- -- -- Sandstone WMMW-16 53.5' - 54.1' 0.70 1.40 129.00 19.90 2.58 7.10 6.40 -- -- -- Sandstone WMMW-16 60.5' - 61.0' 0.10 0.20 117.90 27.30 2.61 0.80 9.90 -- -- -- Sandstone WMMW-16 65.5' - 66.0' 2.60 5.50 131.50 19.30 2.62 28.20 7.10 -- -- -- Sandstone WMMW-16 73.0' - 73.5' 0.10 0.30 130.30 20.60 2.63 1.30 5.50 -- -- -- Sandstone WMMW-16 82.0' - 82.4' 0.10 0.10 134.30 18.50 2.64 0.60 4.80 -- -- -- Sandstone WMMW-16 90.0' - 90.7' 0.10 0.30 161.50 2.00 2.64 12.80 0.90 -- -- -- Sandstone WMMW-16 91.1' - 91.4' 5.20 9.80 118.10 29.10 2.67 33.80 -- 33.70 16.20 17.50 Claystone WMMW-17 104.0' - 104.5' *0.20 0.40 161.40 1.70 2.67 26.60 0.80 -- -- -- Sandstone* Note: *Data from this interval is actually from the Brushy Basin and is not included in the averages. 18.34 2.63 23.41 5.57Formation Average: 1.90 4.01 134.03 19.93 2.62 13.48 6.53Formation Average: 1.45 % Plasticity Index Rock TypeWell No. and Sample Interval % Moisture Content 2.95 130.83 % Saturation % Retained Moisture % Liquid Limit % Plastic Limit Moisture Content, Volumetric Dry Unit Weight (lbs/cu ft) % Porosity Particle Specific Gravity Formation H:\718000\hydrpt14\Titan_material_props.xls: T5-TITAN Formation Properties 5/15/2014 TABLE 6 Hydraulic Conductivity Estimates For Spring Flow Calculations location k (cm/s) location k (cm/s) location k (cm/s) DR-21 3.29E-05 DR-5 2.95E-05 DR-5 2.95E-05 DR-23 1.96E-05 DR-8 2.46E-08 MW-23 2.30E-07 DR-24 1.64E-05 DR-9 4.49E-04 MW-24 4.16E-05 DR-10 2.92E-06 MW-35 3.48E-04 DR-11 8.88E-06 MW-12 2.20E-05 MW-23 2.30E-07 MW-24 4.16E-05 MW-36 4.51E-04 geomean:2.19E-05 geomean:9.76E-06 geomean:1.77E-05 Notes: k = hydraulic conductivity cm/s = centimeters per second Ruin Spring Westwater Seep Westwater Seep (2) H:\718000\hydrpt2022\tables\T1_2_3_6_Hydraulic_props_4Q21.xls: T6-Springs 4/7/2022 TABLE 7 Hydraulic Conductivity Estimates For Travel Time Calculations Paths 1, 2A, and 2B location k (cm/s) location k (cm/s) location k (cm/s) TWN-2 1.49E-05 TW4-5 u 4.60E-04 MW-4A u 1.10E-04 TWN-3 8.56E-06 TW4-5 c 1.00E-03 MW-4A c 1.40E-04 TWN-18 2.27E-03 TW4-9 u 3.90E-04 TW4-2 u 4.30E-05 TW4-21 1.90E-04 TW4-9 c 8.20E-04 TW4-2 c 5.70E-05 TW4-22 1.30E-04 TW4-10 u 2.60E-04 TW4-8 u 4.30E-05 TW4-24 1.60E-04 TW4-10 c 5.40E-04 TW4-8 c 5.70E-05 TW4-25 5.80E-05 TW4-18 u 3.90E-04 TW4-9 u 3.90E-04 TW4-37 1.43E-04 TW4-18 c 8.60E-04 TW4-9 c 8.20E-04 MW-11 1.40E-03 MW-26 u 7.90E-05 TW4-28 3.52E-04 MW-27 8.20E-05 MW-26 c 1.40E-04 TW4-32 9.53E-05 MW-30 1.00E-04 TW4-39 5.27E-05 TW4-38 6.40E-05 MW-31 7.10E-05 geomean:1.19E-04 geomean:3.23E-04 geomean:1.18E-04 Notes: k = hydraulic conductivity cm/s = centimeters per second c = confined solution u = unconfined solution PATH 1 PATH 2A PATH 2B near historical pond (near wildlife ponds) (near wildlife ponds) (nitrate plume area (chloroform plume area (chloroform plume area H:\718000\hydrpt2022\tables\T7_8_9_PATHCALCS21.xls: T7-paths 1, 2a, 2b 4/7/2022 TABLE 8 Hydraulic Conductivity Estimates for Travel Time Calculations Paths 3-6 location k (cm/s) location k (cm/s) location k (cm/s) DR-5 2.95E-05 DR-5 2.95E-05 DR-11 8.88E-06 DR-8 2.46E-08 DR-8 2.46E-08 DR-13 5.89E-06 DR-9 4.49E-04 DR-9 4.49E-04 DR-21 3.29E-05 DR-10 2.92E-06 DR-10 2.92E-06 DR-23 1.54E-05 DR-11 8.88E-06 DR-11 8.88E-06 MW-3 4.00E-07 MW-12 2.20E-05 DR-14 1.26E-05 MW-14 7.50E-04 MW-23 2.30E-07 DR-17 1.24E-05 MW-15 1.90E-05 MW-24 4.16E-05 DR-19 3.29E-05 MW-20 9.30E-06 MW-36 4.51E-04 DR-20 2.14E-06 MW-37 1.28E-05 DR-21 3.29E-05 DR-23 1.96E-05 DR-24 1.64E-05 MW-23 2.30E-07 MW-24 4.16E-05 MW-36 4.51E-04 geomean:9.76E-06 geomean:1.10E-05 geomean:1.38E-05 Notes: k = hydraulic conductivity cm/s = centimeters per second tailings management tailings management PATHS 3 and 4 PATH 5 PATH 6 (downgradient of system) (downgradient of system) (downgradient of system) tailings management H:\718000\hydrpt2022\tables\T7_8_9_PATHCALCS21.xls: T8-paths 3-6 4/7/2022 TABLE 9 Estimated Perched Zone Pore Velocities Along Path Lines Path Length Head Change Hydraulic Gradient Pore Velocity General Path Location (cm/s) (ft/yr) (ft) (ft) (ft/ft) (ft/yr) (area of site) 1 1.19E-04 122 1,940 32 0.0165 11 nitrate plume area near historical pond 2A 3.23E-04 330 1,045 36 0.0344 63 chloroform plume area near wildlife ponds 2B 1.18E-04 121 1,080 61 0.0565 38 chloroform plume area near wildlife ponds 3 9.76E-06 10.0 2,200 30 0.0136 0.76 downgradient of tailings mgmt system 4 9.76E-06 10.0 4,125 19 0.0046 0.26 downgradient of tailings mgmt system 5 1.10E-05 11.3 11,800 113 0.0096 0.60 downgradient of tailings mgmt system 6 1.38E-05 14.1 9,700 113 0.0116 0.91 downgradient of tailings mgmt system Notes: a Geometric average (from Tables 7 and 8) Assumes effective porosity of 0.18 cm/s = centimeters per second ft/ft = feet per foot ft/yr = feet per year mgmt = management Path Hydraulic Conductivitya H:\718000\hydrpt2022\tables\T7_8_9_PATHCALCS21.xls: T9-pore velocities 4/7/2022 TABLE 10 Results of XRD and Sulfur Analysis in Weight Percent Mineral Formula MW-3A MW-23 MW-24 MW-25 MW-26 MW-27 MW-28 MW-29 MW-30 MW-31 MW-32 (TW4-17)SS-26* 89.5 108 118.5 65 - 67.5 90 - 92.5 80 - 82.5 88.5 102 65 - 67.5 95 - 97.5 105-107.5 NA quartz SiO2 79.7 96.2 88.4 90 86.9 95.4 90.1 95.8 87 91.7 94.1 39.2 K-feldspar KAlSi3O8 ND 0.2 0.6 2.4 2.4 0.7 1.5 0.5 1.4 2 0.8 21.6 plagioclase (Na,Ca)(Si,Al)4O8 ND ND ND 1.4 1.6 1.5 1.8 1.5 1.5 0.5 0.2 29 mica KAl2(Si3Al)O10(OH)2 0.3 1.2 4.5 2.2 2 0.2 3 0.2 5.9 3.1 1.2 5.2 kaolinite Al2Si2O5(OH)4 1.1 1 4.3 3.2 2.5 1.4 2.9 1.7 3.6 2.4 1.6 0.8 calcite CaCO3 14 ND ND ND 3.9 ND ND ND ND ND 1.2 0.6 dolomite CaMg(CO3)2 4.1 ND ND ND ND ND ND ND ND ND ND ND anhydrite CaSO4 0.4 0.8 0.4 0.4 ND ND ND ND ND ND ND ND gypsum CaSO4·2H2O ND 0.2 0.8 ND ND ND 0.3 ND 0.3 ND ND ND iron Fe 0.3 0.4 0.2 0.4 0.4 0.4 0.2 0.3 0.3 0.3 0.4 0.2 pyrite FeS2 0.1 ND 0.8 ND 0.3 0.4 0.2 ND ND ND 0.5 ND hematite Fe2O3 ND ND ND ND ND ND ND ND ND ND ND 1.4 magnetite Fe3O4 ND ND ND ND ND ND ND ND ND ND ND 2 Total S S 0.14 0.14 0.63 0.05 0.13 0.15 0.04 0.03 0.02 0.02 0.26 0.02 equivalent FeS2 FeS2 0.3 0.3 1.2 0.1 0.2 0.3 0.1 0.1 <0.1 <0.1 0.5 <0.1 Notes: NA = Not applicable: quality control sample ND = Not Detected * = 'play sand' Sulfur Determination Depth (feet) H:\718000\hydrpt2022\ Pyrite_results_tables_4Q21.xls: Table 10 4/8/2022 TABLE 11 Tabulation of Presence of Pyrite, Iron Oxide, and Carbonaceous Fragments in Drill Logs Well Pyrite C Fragments Iron Oxide MW-3A X aMW-16 X aMW-17 X aMW-18 X aMW-19 X aMW-20 X aMW-21 X X aMW-22 X MW-23 X MW-24 X MW-25 X X MW-26 X X MW-27 X X MW-28 X MW-29 X MW-30 X X MW-31 X X MW-32 X X MW-33 X MW-34 X X X MW-35 X X X MW-36 X X MW-37 X X MW-38 X MW-39 X X MW-40 X X Piez-2 X Piez-4 X X Piez-5 X X DR-2 X X DR-5 X X DR-6 X X DR-7 X DR-8 X DR-9 X X DR-10 X DR-11 X X DR-12 X X DR-13 X DR-14 X X DR-15 X X DR-16 X X DR-17 DR-18 X X DR-19 X DR-20 X X DR-21 X DR-22 DR-23 X X DR-24 X X DR-25 X X TW4-1 X TW4-2 X X TW4-3 X X X TW4-4 TW4-5 X X TW4-6 X X X TW4-7 X X X TW4-8 X TW4-9 X X X TW4-10 X X H:\718000\hydrpt2022\ Pyrite_results_tables_4Q21.xls: Table 11 Page 1 of 2 4/8/2022 TABLE 11 Tabulation of Presence of Pyrite, Iron Oxide, and Carbonaceous Fragments in Drill Logs Well Pyrite C Fragments Iron Oxide TW4-11 X TW4-12 X X X TW4-13 X X X TW4-14 X TW4-15 X X TW4-16 X X TW4-17 X X TW4-18 X X TW4-19 X TW4-20 X TW4-21 X X TW4-22 X TW4-23 X X X TW4-24 X TW4-25 X X TW4-26 X TW4-27 X X TW4-28 X X TW4-29 X X X TW4-30 X X X TW4-31 X X X TW4-32 X X X TW4-33 X X TW4-34 X X TW4-35 X X X TW4-36 X X X TW4-37 X TW4-38 X TW4-39 X X TW4-40 X TW4-41 X X TW4-42 X X TW4-43 X TWN-1 X TWN-2 X X TWN-3 X X TWN-4 X TWN-5 X X TWN-6 X X TWN-7 X TWN-8 X X TWN-9 X TWN-10 X TWN-11 X X TWN-12 X X TWN-13 X X TWN-14 X X TWN-15 X X TWN-16 X X TWN-17 X TWN-18 X X TWN-19 X X TWN-20 X X TWN-21 X X Notes: C Fragments = particles of carbonaceous material (plant remains, etc) a = only moderately detailed log available H:\718000\hydrpt2022\ Pyrite_results_tables_4Q21.xls: Table 11 Page 2 of 2 4/8/2022 TABLE 12 Sulfide Analysis by Optical Microscopy Grain size (micrometers) Sample Depth (feet) Mineral Volume% Minimum Maximum Mean MW-26 (TW4-15)1 92.5’ - 97.5' pyrite 4.30 5.6 44.4 128.9 MW-34 67.5’ - 70' pyrite 0.30 1.1 177.8 71.1 MW-36 87.5’ - 90' pyrite 5.20 5.6 88.9 52.2 MW-36 87.5’ - 90' marcasite 0.50 22.2 488.8 121.2 MW-36 112.5’ - 115' pyrite 2.20 16.7 577.7 188.9 MW-36 112.5’ - 115' marcasite 0.20 22.2 333.3 177.8 MW-37 110’ - 112.5' pyrite 9.80 11.1 1666.5 131.1 TW4-162 92.5’ - 95' pyrite 0.10 11.1 105.5 47.8 TW4-22 90’ - 92.5' pyrite 0.30 5.6 66.7 26.7 TWN-5 110’ - 112.5' pyrite 15.80 5.6 1377.6 208.9 TWN-5 112.5’ - 115' pyrite 0.50 5.6 266.6 70 TWN-5 112.5’ - 115' marcasite 0.50 22.2 55.6 36.7 TWN-5 112.5’ - 115' chalcopyrite 0.02 ND ND 6 TWN-8 117.5’ - 120' pyrite 12.00 5.6 455.1 137.8 TWN-8 117.5’ - 120' marcasite 0.60 66.6 288.9 155.5 AWN-X23 87.5’ - 90' pyrite 2.40 5.6 33.3 17.8 AWN-X23 87.5’ - 90' marcasite 0.60 66.6 288.9 155.5 TWN-164 82.5’ - 85' pyrite 0.10 1.1 11.1 6.1 TWN-164 87.5' - 90' pyrite 0.16 7 168 35.5 TWN-164 87.5' - 90' marcasite 0.05 ND 129.5 ND TWN-195 82.5 ' - 85' pyrite 1.18 3.5 434 42.1 TWN-195 82.5 ' - 85' marcasite 0.06 21 42 36.4 DR-9 105’ - 107.5' pyrite 17.00 2.2 677.7 136.7 DR-12 87.5’ - 90' pyrite 0.30 11.1 111.1 52.2 DR-12 87.5’ - 90' marcasite 0.10 22.2 111.1 72.2 DR-16 97.5’ - 100' pyrite 2.40 5.6 33.3 17.8 DR-16 97.5’ - 100' marcasite 0.60 66.6 288.9 155.5 DR-25 75’ - 77.5' pyrite 25.00 1.1 1955 22 DR-25 75’ - 77.5' marcasite 2.50 55.6 621.6 265.5 SS-31*NA chalcopyrite 0.01 ND ND 10 SS-37*NA pyrite 0.02 7 14 11.7 Notes: 1 Samples from 92.5' - 95' and 95' - 97.5' combined due to small sample volume 2 Sample from 92.5' - 95' submitted instead of sample from 95' - 97.5' because no sample material available 3 Originally TWN-16 4 Originally TWN-19 5 Originally TWN-22 NA = Not applicable: quality control sample ND = Not determined * = 'play sand' H:\718000\hydrpt2022\ Pyrite_results_tables_4Q21.xls: Table 12 4/8/2022 TABLE 13 Summary of Pyrite in Drill Cuttings and Core Well Pyrite Noted in Drill Logs Pyrite Detected by Laboratory MW-3A X (Q) aMW-16 NA aMW-17 NA aMW-18 NA aMW-19 NA aMW-20 NA aMW-21 X NA aMW-22 NA MW-23 possibleb (Q) MW-24 X (Q) MW-25 X possibleb (Q) MW-26 X X (Q) MW-27 X X (Q) MW-28 X (Q) MW-29 possibleb (Q) MW-30 X ND (Q) MW-31 X ND (Q) MW-32 X X (Q) MW-33 NA MW-34 X X (V) MW-35 X NA MW-36 X X (V) MW-37 X X (V) MW-38 NA MW-39 X NA MW-40 X NA Piez-2 NA Piez-4 X NA Piez-5 X NA DR-2 X NA DR-5 X NA DR-6 X NA DR-7 NA DR-8 NA DR-9 X X (V) DR-10 NA DR-11 X NA DR-12 X X (V) DR-13 NA DR-14 X NA DR-15 X NA DR-16 X X (V) DR-17 NA DR-18 X NA DR-19 NA DR-20 X NA DR-21 NA DR-22 NA DR-23 X NA DR-24 X NA DR-25 X X (V) TW4-1 NA TW4-2 X NA TW4-3 X NA TW4-4 NA TW4-5 X NA TW4-6 X NA TW4-7 X NA TW4-8 NA TW4-9 X NA TW4-10 X NA TW4-11 NA TW4-12 X NA TW4-13 X NA H:\718000\hydrpt2022\ Pyrite_results_tables_4Q21.xls: Table 13 Page 1 of 2 4/8/2022 TABLE 13 Summary of Pyrite in Drill Cuttings and Core Well Pyrite Noted in Drill Logs Pyrite Detected by Laboratory TW4-14 NA TW4-15 X NA TW4-16 X X (V) TW4-17 X NA TW4-18 NA TW4-19 NA TW4-20 NA TW4-21 X NA TW4-22 X X (V) TW4-23 X NA TW4-24 NA TW4-25 X NA TW4-26 NA TW4-27 NA TW4-28 X NA TW4-29 X NA TW4-30 X NA TW4-31 X NA TW4-32 X NA TW4-33 X NA TW4-34 NA TW4-35 X NA TW4-36 X NA TW4-37 NA TW4-38 NA TW4-39 X NA TW4-40 NA TW4-41 X NA TW4-42 X NA TW4-43 NA TWN-1 NA TWN-2 X NA TWN-3 X NA TWN-4 NA TWN-5 X X (V) TWN-6 X NA TWN-7 NA TWN-8 X X (V) TWN-9 NA TWN-10 NA TWN-11 X NA TWN-12 X NA TWN-13 X NA TWN-14 X NA TWN-15 X NA TWN-16 X X (V) TWN-17 NA TWN-18 X NA TWN-19 X X (V) TWN-20 X NA TWN-21 X NA AWN-X1 NA AWN-X2 X X (V) AWN-X3 NA Notes: a = only moderately detailed log available b = detected iron and sulfur may indicate the presence of pyrite Q = quantiative analysis by XRD V = visual (microscopic) analysis ND = not detected by laboratory NA = not analyzed by laboratory H:\718000\hydrpt2022\ Pyrite_results_tables_4Q21.xls: Table 13 Page 2 of 2 4/8/2022 TABLE 14 Summary of Nitrate Degradation Rates Source Type Pyrite Species Pyrite Weight % Pyrite oxidation rate (μM/h NO3-) Pyrite oxidation rate (NO3-N lbs/ft3/yr) Torrento et al. (2010)Incubation Crystals of 25-100 μm 99.5 2.04 1.56E-02 Bosch et al. (2012)Incubation Nanoparticles of ~1 μm 100 38.56 2.95E-01 Jorgensen et al. (2009)Columns Crystals of 45-200 μm amended in sediment 1.0 0.05 3.83E-04 Torrento et al. (2010)Columns Crystals of 25-100 μm amended in sediment 99.5 4.67 3.58E-02 Zhang et al. (2009)Field study pyritic sands < 0.1 to 0.85 0.07 5.36E-04 White Mesa XRD Analysis Field study pyritic sands < 0.1 to 0.8 a5.4e-6 to 6.4e-6 Notes: μM/h NO3- = micromoles per liter nitrate per hour NO3-N lbs/ft3/yr = pounds per cubic foot per year nitarte as nitrogen a =average based on HGC (2017) H:\718000\hydrpt2022\Tables r1\T14_15_rate_summary_rev.xlsx: Table 14 - rates TABLE 15 Pyrite Contents in Samples From White Mesa Mill and Oostrum, Netherlands Site White Mesa Uranium Mill site Oostrum, Netherlands site well depth (ft) Mill wt% pyrite (XRD) 1Mill 'equiv' wt% pyrite depth (m) depth (ft) 2Oostrum wt% pyrite MW-3A 89.5 0.1 0.3 5.1 16.73 0 MW-23 108 0 0.3 5.2 17.06 0.01 MW-24 118.5 0.8 1.2 5.4 17.72 0.01 MW-25 66.25 0 0.1 7 22.97 0.01 MW-26 91.25 0.3 0.2 9.1 29.86 0 MW-27 81.25 0.4 0.3 9.3 30.51 0.01 MW-28 88.5 0.2 0.1 15.2 49.87 0.09 MW-29 102 0 0.1 19 62.34 0.85 MW-30 66.25 0 0 21.7 71.19 0.25 MW-31 96.25 0 0 23.3 76.44 0.49 MW-32 106.25 0.5 0.5 23.3 76.44 NA 25.8 84.65 0.37 27.5 90.22 0.29 29.2 95.80 0.09 31.2 102.36 0.08 33.2 108.92 0.19 35.3 115.81 0.09 36.9 121.06 0.38 37.2 122.05 NA 39.1 128.28 0.17 average 0.21 0.28 0.28 (pyritic depths only) Notes: XRD = X-ray diffraction 1 = Based on total iron and sulfur contents 2 = Based on total sulfur content 0 = not detected (< 0.1%) m = meters ft = feet H:\718000\hydrpt2022\Tables r1\T14_15_rate_summary_rev.xlsx: Table 15 - pyrite content FIGURES HYDRO GEO CHEM, INC. 1 mile WHITE MESA Mill Site WW-3 CORRAL CANYON CORRAL SPRINGS COTTONWOOD ENTRANCE SPRING RUIN SPRING WESTWATER Cell 1 Cell 2 Cell 3 Cell 4A Cell 4B MW-01 MW-02 MW-3A MW-11 MW-14MW-15 MW-17 MW-18 MW-19 MW-20 MW-21 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-32 MW-33 MW-34MW-37 MW-38 MW-39 MW-40 TW4-01 TW4-03 TWN-01 TWN-02 TWN-03 TWN-04 TWN-05 TWN-06 TWN-07 TWN-08 TWN-09 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 TWN-20 TWN-21 PIEZ-01 PIEZ-02 PIEZ-3A PIEZ-04 PIEZ-05 TW4-05 TW4-12 TW4-13 TW4-31 TW4-32 MW-12 TW4-11TW4-16 TW4-18 TW4-27 MW-26 MW-35 MW-36 TW4-04 TW4-07 TW4-09 TW4-19 TW4-21 TW4-24 TW4-25 TW4-26 TW4-40 TW4-06 TW4-42 TW4-02 TW4-08 MW-04 MW-05 TW4-22 TW4-23 TW4-20 TW4-28 TW4-29 TW4-30 TW4-10 TW4-33 TW4-34 TW4-36 TW4-41TW4-14 TW4-43TW4-35 TW4-37 TW4-38 TW4-39 DR-05 DR-06 DR-07 DR-08 DR-09 DR-10 DR-11 DR-12 DR-13 DR-14 DR-15 DR-17 DR-19 DR-20 DR-21 DR-22 DR-23 DR-24 abandoned abandoned abandoned abandoned abandoned abandoned abandoned abandoned abandoned DR-02 DR-16 DR-18 DR-25 abandoned abandoned abandoned abandoned MW-24A MW-16abandoned MW-3abandoned W E S N SW NE SW2 NE2 NW SE W2 E2 WNW ESE wildlife pond wildlife pond wildlife pond abnd EXPLANATION perched monitoring well perched piezometer seep or spring WHITE MESA SITE PLAN SHOWING LOCATIONS OF PERCHED WELLS, PIEZOMETERS AND LITHOLOGIC CROSS-SECTIONS (as of 4th quarter, 2021) H:/718000/ hydrpt2022/figures/Uwellocxs2022_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well temporary perched nitrate monitoring well TW4-12 TWN-7 TW4-19 perched chloroform or nitrate pumping well approximate footprint of historical pond 1A perched monitoring well installed February, 2018 MW-38 TW4-42 MW-24A TWN-20 TW4-43 temporary perched monitoring well installed April 2019 perched monitoring well installed December 2019 temporary perched nitrate monitoring well installed April, 2021 temporary perched monitoring well installed September, 2021 HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 historic pond footprint Q4, 2021 nitrate plume boundary Q4, 2021 chloroform plume boundary H:/718000/ hydrpt2022/figures/UwlChlNt4Q21.srf 1BSJS WHITE MESA SITE PLAN SHOWING 4th QUARTER 2021 PERCHED WELL AND PIEZOMETER LOCATIONS, KRIGED PERCHED WATER LEVELS AND CHLOROFORM AND NITRATE PLUMES H:\718000\hydrpt2018\Figure2_7.xls: F2 litho clmn LITHOLOGIC COLUMNHYDRO GEO CHEM, INC.Approved FigureDateAuthorDate File Name SJS 11/9/12 2F2 litho clmn11/9/12SJS B ur ro Canyon Fo rma t ion Brushy Basin Member Highway 95 Reference Outcrop Just North of White Mesa Uranium Mill HYDRO GEO CHEM, INC. 4 PHOTOGRAPH OF THE CONTACT BETWEEN THE BURRO CANYON FORMATION AND THE BRUSHY BASIN MEMBER H:/718000/hydrpt2022/ Figures/contact2.srf HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl KRIGED 4th QUARTER, 2021 WATER LEVELS WHITE MESA SITE H:/718000/hyrpt2022/figures/Uwl1221det.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 5 saturated thickness estimated to be less than 5 feet 5500 4th quarter 2021 water level contour and label in feet amsl SJS HYDRO GEO CHEM, INC. "Dry Seep""2nd Seep" (5240 ft amsl)Cottonwood Seep (5234 ft amsl) Kdbc Kdbc Jmbb ss (within Jmw) sh (Jmr) (contact approx. 5465 ft amsl) Approximate Location of DR-8 EXPLANATION Dakota Sandstone/ Burro Canyon Formation Brushy Basin (Shale) Member Approximate Location of Geologic Contact Kdbc Jmbb sandstone (within Westwater Canyon Member) ss (within Jmw) shale (Recapture Member)sh (Jmr) H:/718000/hydrpt2022/ Figures/cottonwood2.srf ANNOTATED PHOTOGRAPH SHOWING EAST SIDE OF COTTONWOOD CANYON (looking east toward White Mesa from west side of Cottonwood Canyon) NOTES: adapted from HGC (2010); "2nd Seep" and "Dry Seep" are described in HGC (2010) Approximate Change From Slope-Former to Bench-Former Jmbb Jmbb WHITE MESA (slope-former) (cliff-former) (cliff-former)(cliff-former) (slope-former)(slope-former) COTTONWOOD CANYON lower Jmbb/upper Jmw (bench former) lower Jmbb/upper Jmw (bench former) (slope-former) 6 H:\718000\hydrpt2018\Figure2_7.xls: F7 west int sea EXTENT OF THE WESTERN INTERIOR SEA (CRETACEOUS) HYDRO GEO CHEM, INC.Approved FigureDateAuthorDate File Name SJS 11/9/12 7F7 west int sea11/9/12SJS HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl (X = abandoned) KRIGED TOP OF BRUSHY BASIN WHITE MESA SITE H:/718000/hydrpt2022/figures/Ubbel1221_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5491 5521 5545 5552 MW-38 5459 TW4-42 5508 TWN-20 5546 8seep or spring showing elevation in feet amsl5380 5 3 8 0 kriged top of Brushy Basin elevation contour and label (feet amsl) approximate axis of Brushy Basin paleoridge approximate axis of Brushy Basin paleovalley TW4-43 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl5504 temporary perched nitrate monitoring well installed April, 2021 showing elevation in feet amsl HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl (X = abandoned) KRIGED TOP OF BEDROCK WHITE MESA SITE H:/718000/hydrpt2022/ figures/Ubdrkel1221_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5579 5602 5637 5640 MW-38 5525 TW4-42 5587 TWN-20 5626 9Aseep or spring 5 4 6 0 kriged top of bedrock elevation contour and label (feet amsl) TW4-43 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl5590 temporary perched nitrate monitoring well installed April, 2021 showing elevation in feet amsl HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl (X = abandoned) MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5579 5602 5637 5649 MW-38 5531 TW4-42 5587 TWN-20 5626 9Bseep or spring 5 4 6 0 kriged top of bedrock elevation contour and label (feet amsl) TW4-43 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl5590 KRIGED TOP OF BEDROCK USING REVISED DEPTH TO MANCOS DATA WHITE MESA SITE H:/718000/hydrpt2022 figures/Ubdrkel1221_rev2.srf temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl (X = abandoned) KRIGED TOP OF DAKOTA WHITE MESA SITE H:/718000/hydrpt2022/ figures/Udakotael1221_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5579 5591 5625 5640 MW-38 5525 TW4-42 5572 TWN-20 5623 10seep or spring 5 4 6 0 kriged top of Dakota elevation contour and label (feet amsl) TW4-43 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl5563 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl (X = abandoned) KRIGED TOP OF BEDROCK SHOWING APPROXIMATE MANCOS THICKNESS WHITE MESA SITE H:/718000/hydrpt2022/ figures/Ubdrkmanc_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5579 5602 5637 5640 MW-38 5525 TW4-42 5587 TWN-20 5626 11Aseep or spring 5 3 8 0 kriged top of bedrock elevation contour and label (feet amsl) TW4-43 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl5590 2.5 5 10 20 30 approximate Mancos thickness (feet) temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl (X = abandoned) MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5579 5602 5637 5649 MW-38 5531 TW4-42 5587 TWN-20 5626 11Bseep or spring 5 3 8 0 kriged top of bedrock elevation contour and label (feet amsl) TW4-43 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl5590 KRIGED TOP OF BEDROCK SHOWING APPROXIMATE REVISED MANCOS THICKNESS WHITE MESA SITE H:/718000/hydrpt2022 figures/Ubdrkmanc_rev2.srf 2.5 5 10 20 30 approximate Mancos thickness (feet) temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl HYDRO GEO CHEM, INC. P7 C-01 P7C-02 P7 C-03 P8 C-01 P8C-02P8 C-03 P8C-04 P 9C-01 P9 C-02 P9 C-03 P9C-04 P9 C-05 P10 C-01 P10 C-02 P10 C-03 P 11C-01 P11 C-02 P11 C-03 P11C-04 P11 C-05 P12C-01 P12C-02 P12C-03 P 13C-01 P 13C-02 P 13C-03 P14C-01 P14C-02 P 14C-03 P15C-01 P16 C-01P16C-02 P16C-03 P16 C-04 P16 C-05 P 17C-01 P17 C-02 P 17C-03 P17 C-04 P 18C-01 P18 C-02 P18C-03 P1A-01 P2A-01 P3A-N01 P4A-01 P5A-01 P1A-08 P2A-08 P3A-08 P4A-10 P5A-10 P6A-01 P6A-04 100 feet EXPLANATION APPROXIMATE GEOPROBE BORING AND CROSS-SECTION LOCATIONS WHITE MESA SITE H:/718000/hydrpt2022/ xsections/soilxs/soilxsloc_rev.srf approximate 1st sampling event geoprobe boring location approximate 2nd sampling event geoprobe boring location approximate 3rd sampling event geoprobe boring location ammonium sulfate crystal tank north-south (N-S) cross-section northeast - southwest (NE-SW) cross-section HYDRO GEO CHEM, INC. SOIL CROSS SECTIONS EAST OF AMMONIUM SULFATE CRYSTAL TANKS WHITE MESA SITE S N EXPLANATION weathered mancos shale competent bedrock asphalt primarily sand primarily clay primarily silt vertical exaggeration = 2:1 Note: NH3 xtal tanks 60 feet west of section 0 50 100 150 200 250 300 distance (feet) 5610 5615 5620 5625 5630 5635 5640 5645 ap p r o x i m a t e e l e v a t i o n ( f t a m s l ) NH 3 x t a l t a n k s P1 7 C - 0 1 P1 6 C - 0 1 P1 4 C - 0 1 P1 3 C - 0 1 P1 2 C - 0 1 P1 A - 0 8 P1 A - 0 7 P1 A - 0 6 P1 A - 0 5 P1 A - 0 4 P1 A - 0 3 P1 A - 0 2 P2 A - 0 1 P3 A - N 0 1 P4 A - 0 1 P5 A - 0 1 P1 1 C - 0 4 P1 1 C - 0 3 P1 1 C - 0 2 silt/clay 0 50 100 distance (feet) 5605 5610 5615 5620 5625 5630 5635 5640 5645 ep p r o x i m a t e e l e v a t i o n ( f t a m s l ) P1 A - 0 3 P2 A - 0 3 P3 A - 0 3 P4 A - 0 5 P5 A - 0 5 P6 A - 0 2 P8 C - 0 1 P9 C - 0 1 P1 0 C - 0 1 SW NE H:/718000/hydrpt2022/ Figures/soilxs.srf 13 HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing thickness in feet perched piezometer showing thickness in feet 4th QUARTER, 2021 SATURATED THICKNESS IN FEET WHITE MESA SITE H:/718000/hydrpt2022/figures/Usat1221_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing thickness in feet temporary perched nitrate monitoring well showing thickness in feet TW4-12 TWN-7 12 47 24 37 MW-38 4 TW4-42 17 TWN-20 19 14seep or spring approximate axis of Brushy Basin paleoridge approximate axis of Brushy Basin paleovalley TW4-43 temporary perched monitoring well installed September, 2021 showing thickness in feet20 estimated dry area saturated thickness estimated to be less than 5 feet Note: Q4 2021 water levels for TW4-1, TW4-2 and TW4-11 are below the base of the Burro Canyon Formation temporary perched nitrate monitoring well installed April, 2021 showing thickness in feet HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing depth to water in feet perched piezometer showing depth to water in feet 4th QUARTER, 2021 DEPTH TO WATER IN FEET WHITE MESA SITE H:/718000/hydrpt2022/figures/Udtw1221_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing depth to water in feet temporary perched nitrate monitoring well showing depth to water in feet TW4-12 TWN-7 108 56 81 67 MW-38 70 TW4-42 70 TWN-20 78 15seep or spring TW4-43 temporary perched monitoring well installed September, 2021 showing depth to water in feet73 estimated dry area saturated thickness estimated to be less than 5 feet Note: Q4 2021 water levels for TW4-1, TW4-2 and TW4-11 are below the base of the Burro Canyon Formation temporary perched nitrate monitoring well installed April, 2021 showing depth to water in in feet EXPLANATION Qaf Km Kdbc Jmbb Alluvium/Fill/ Weathered Mancos Mancos Shale Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Shale/claystone in Dakota / Burro Canyon Formation Conglomerate in Dakota / Burro Canyon Formation SW NE Piezometric Surface vertical exaggeration = 20 : 1 0 2000 4000 6000 8000 10000 12000 distance (feet) 5420 5440 5460 5480 5500 5520 5540 5560 5580 5600 5620 5640 5660 5680 5700 5720 el e v a t i o n ( f e e t a m s l ) MW - 0 3 * MW - 1 4 MW - 1 1 MW - 3 1 TW 4 - 2 4 MW - 2 7 TW N - 2 TW N - 3 TW N - 1 8 TW N - 8 * TW N - 6 TW N - 1 0 * TW N - 1 5 * TW N - 1 6 TW N - 1 2 * Cell # 4A Cell # 3 Cell # 2 Cell # 1 Fl y A s h P o n d Ce l l 1 L e a c h F i e l d CC D / S X L e a c h F i e l d Hi s t o r i c a l P o n d La w z y L a k e Kdbc Kdbc Kdbc Km Km Km Jmbb Jmbb Jmbb Qaf Qaf Notes: 1) water levels from TWN-8, TWN-10, TWN-12, and TWN-15 are estimated by kriging; 2) lithology for MW-3 from log of MW-3A * denotes abandoned boring 16AH:/718000/ hydrpt2022/xsections/nsxsne/nsxsne18b.srf HYDRO GEO CHEM, INC. SW2 NE2 INTERPRETIVE NORTHEAST-SOUTHWEST CROSS SECTION (NE2-SW2) WHITE MESA SITE EXPLANATION Qaf Kdbc Jmbb Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Shale/claystone in Dakota / Burro Canyon Formation Conglomerate or Conglomeratic Sandstone in Dakota / Burro Canyon Formation Piezometric Surface TW N - 1 8 MW - 1 9 PI E Z - 1 TW N - 9 * TW N - 1 4 TW N - 1 7 * TW N - 1 9 Law zy L a k e ( 1 ) Wi l d l i f e P ond ( 2 ) 5450 5470 5490 5510 5530 5550 5570 5590 5610 5630 5650 5670 5690 5710 5730 5750 el e v a t i o n ( f e e t a m s l ) 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 distance (feet) Notes: (1) approximately 200 feet north of cross section (2) approximately 200 feet south of cross section vertical exaggeration = 8 : 1 SJS Note: water levels from TWN-9 and TWN-17 are estimated by kriging * denotes abandoned boring H:/718000/hydrpt2022/ xsections/nsxs2ne/nsxs2ne18b.srf 16B Alluvium/Fill/ Weathered Mancos HYDRO GEO CHEM, INC. 0 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 distance (feet) 5460 5480 5500 5520 5540 5560 5580 5600 5620 5640 5660 5680 5700 5720 5740 5760 el e v a t i o n ( f e e t a m s l ) TW N - 7 TW N - 2 TW 4 - 2 5 TW 4 - 2 1 TW N - 1 PI E Z - 3 * Hi s t o r i c a l P o n d La w z y S u m p SA G L e a c h F i e l d Am m o n i u m S u l f a t e T a n k s ( 1 ) Am m o n i a T a n k s ( 2 ) Fo r m e r O f f i c e L e a c h F i e l d ( 3 ) Ma i n L e a c h F i e l d ( 4 ) QafKm Km Km Kdbc Kdbc Kdbc Jmbb Jmbb Notes: (1) approximately 115 feet southwest of cross-section (2) approximately 150 feet southwest of cross-section (3) approximately 300 feet south of cross-section (4) immediately south of cross-section EXPLANATION Qaf Km Kdbc Jmbb Mancos Shale Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Shale/claystone in Dakota / Burro Canyon Formation Conglomerate or Conglomeratic Sandstone in Dakota / Burro Canyon Formation Piezometric Surface INTERPRETIVE NORTHWEST-SOUTHEAST CROSS SECTION (NW-SE) WHITE MESA SITE NW SE vertical exaggeration = 3 : 1 SJS H:/718000/hydrpt2022/ xsections/ewxsne/ewxsne18b.srf 17 Note: water level shown for Piez-3 is from replacement piezometer Piez-3A Alluvium/Fill/ Weathered Mancos APPROVED DATE REFERENCE FIGURE HYDRO GEO CHEM, INC. EXPLANATION Qal Km Kdbc Jmbb Mancos Shale Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Piezometric surface vertical exaggeration = 5:1 Shale/claystone within Dakota/Burro Canyon Conglomerate within Dakota/Burro Canyon INTERPRETIVE EAST-WEST CROSS SECTIONS (W-E and W2-E2) SOUTHWEST INVESTIGATION AREA 0 500 1000 1500 2000 2500 3000 3500 distance (feet) 5450 5475 5500 5525 5550 5575 5600 5625 5650 el e v a t i o n ( f e e t a m s l ) DR - 2 ( a b n d ) DR - 5 DR - 6 DR - 7 MW - 3 5 W E Qal Km Kdbc Kdbc Jmbb Jmbb 18A H:/718000/hydrpt2022/ xsections/ewxssw/ewxssw2b_rev3.srf Note: water level for abandoned piezometer DR-2 is from the second quarter of 2011 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 distance (feet) 5450 5475 5500 5525 5550 5575 5600 5625 el e v a t i o n ( f e e t a m s l ) DR - 8 DR - 9 DR - 1 0 DR - 1 1 DR - 1 2 DR - 1 3 MW - 1 7 Qal Km Km Kdbc Kdbc Jmbb Jmbb W2 E2 vertical exaggeration = 10:1 Conglomeratic Dakota Sandstone/ Burro Canyon Formation SJS Alluvium/Fill/ Weathered Mancos APPROVED DATE REFERENCE FIGURE HYDRO GEO CHEM, INC. EXPLANATION Qal/Fill Km Kdbc Jmbb Mancos Shale Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Piezometric surface vertical exaggeration = 5:1 Shale/Shaly Sandstone within Dakota/Burro Canyon Conglomerate within Dakota/Burro Canyon INTERPRETIVE EAST-WEST CROSS SECTION (WNW - ESE) SOUTHWEST INVESTIGATION AREA H:/718000/hydrpt2022/ xsections/ewxssw3/ew3xsectb_rev2.srf * = detailed log unavailable Conglomeratic Dakota Sandstone/ Burro Canyon Formation SJS 0 500 1000 1500 2000 2500 3000 3500 distance (feet) 5450 5475 5500 5525 5550 5575 5600 5625 5650 5675 el e v a t i o n ( f e e t a m s l ) DR - 7 MW - 3 6 MW - 3 3 MW - 3 4 MW - 3 7 MW - 1 5 * MW - 1 4 * MW - 1 7 Qal/Fill Qal/FillKm Kdbc Kdbc Jmbb WNW ESE south dike Cell 4B south dike Cell 4A 18B Alluvium/Fill/ Weathered Mancos HYDRO GEO CHEM, INC. EXPLANATION Qal Km Kdbc Jmbb Mancos Shale Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Piezometric surface INTERPRETIVE NORTH-SOUTH CROSS SECTION (S-N) SOUTHWEST INVESTIGATION AREA vertical exaggeration = 20:1 0 1000 2000 3000 4000 5000 6000 7000 8000 9000 distance (feet) 5375 5400 5425 5450 5475 5500 5525 5550 5575 5600 5625 el e v a t i o n ( f e e t ) Ru i n S p r i n g DR - 2 5 ( a b n d ) DR - 2 1 MW - 2 0 DR - 1 6 ( a b n d ) MW - 3 DR - 1 3 MW - 3 7 Qal Km Km Km Kdbc Kdbc Jmbb Jmbb S N Shale/claystone within Dakota/Burro Canyon Conglomerate within Dakota/Burro Canyon H:/718000/hydrpt2022/ xsections/nsxssw/nsxssw18b.srf 19 Notes: water levels for abandoned piezometers DR-16 and DR-25 are from the second quarter of 2011; MW-3 lithology from MW-3A SJS Alluvium/Fill/ Weathered Mancos H:\718000\hydrpt2022\DR_ Hydrographs_4Q21.xls: DR Piez Hydrographs 40 50 60 70 80 90 100 110 Q2 11 Q3 11 Q4 11 Q1 12 Q2 12 Q3 12 Q4 12 Q2 13 Q3 13 Q4 13 Q1 14 Q2 14 Q3 14 Q4 14 Q1 15 Q2 15 Q3 15 Q4 15 Q1 16 Q2 16 Q3 16 Q4 16 Q1 17 Q2 17 Q3 17 Q4 17 Q1 18 Q2 18 Q3 18 Q4 18 Q1 19 Q2 19 Q3 19 Q4 19 Q1 20 Q2 20 Q3 20 Q4 20 Q1 21 Q2 21 Q3 21 Q4 21 De p t h t o W a t e r ( f e e t b t o c ) Quarter DR-5 DR-6 DR-7 DR-8 DR-9 DR-10 DR-11 DR-12 DR-13 DR-14 DR-15 DR-17 DR-19 DR-20 DR-21 DR-23 DR-24 DR-SERIES PIEZOMETER DEPTHS TO WATER 2Q 2011 TO 4Q 2021 HYDRO GEO CHEM, INC.Approved FigureDateAuthorDate File Name SJS 20DR Piez HydrographSJS HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl H:/718000/hyrpt2022/ figures/Uflow1221Nchl_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 21 saturated thickness estimated to be less than 5 feet KRIGED 4th QUARTER, 2021 WATER LEVELS SHOWING INFERRED PERCHED WATER PATHLINES AND KRIGED NITRATE AND CHLOROFORM PLUMES kriged chloroform > 70 ug/L kriged nitrate > 10 mg/L within area addressed by nitrate CAP estimated total pumping capture estimated perched water flow path SJS HYDRO GEO CHEM, INC. 5520 5525 5526.25 5527.5 5530 5 5 4 5 5 5 5 05552.5 5 5 6 0 5 5 6 5 5 5 7 0 5 5 7 5 5 5 8 0 5 5 8 2 .5 5 5 8 5 EXPLANATION perched monitoring well showing elevation in feet amsl temporary perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl MW-25 TW4-7 PIEZ-2 KRIGED 4th QUARTER, 2021 WATER LEVELS AND ESTIMATED CAPTURE ZONES WHITE MESA SITE (detail map) 5532 5539 5583 5525 TW4-43 5524 TW4-42 temporary perched monitoring well installed April, 2019 showing elevation in feet amsl temporary perched monitoring well installed September, 2021 showing elevation in feet amsl 22SJS HYDRO GEO CHEM, INC. 1 mile WHITE MESA 5390 5390 5410 5 4 1 0 5430 5 4 3 0 5450 5 4 5 0 5470 5470 5490 5 4 9 0 5 5 1 0 5 5 1 0 5530 5 5 3 0 5 5 5 0 5 5 7 0 5 5 7 0 55 9 0 5590 5600 5600 5610 CORRAL CANYON CORRAL SPRINGS COTTONWOOD ENTRANCE SPRING RUIN SPRING WESTWATER Cell 1 Cell 2 Cell 3 Cell 4A Cell 4B MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14MW-15 MW-17 MW-18 MW-19 MW-20 MW-21 MW-22 MW-23 MW-24 MW-25 MW-26 MW-27 MW-28 MW-29 MW-30 MW-31 MW-32 MW-33 MW-34 MW-35 MW-36 MW-37 TW4-01 TW4-10 TW4-20TW4-22 TW4-23 TWN-01 TWN-02 TWN-03 TWN-04 TWN-05 TWN-06 TWN-07 TWN-08 TWN-09 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 PIEZ-01 PIEZ-02 PIEZ-03 PIEZ-04 PIEZ-05 TW4-02 TW4-05 TW4-06 TW4-09 TW4-11 TW4-12 TW4-13 TW4-14 TW4-16 TW4-18 TW4-27 TW4-19 TW4-26 TW4-04 TW4-07 TW4-21 TW4-24 TW4-25 TW4-03 TW4-08 MW-04 DR-05 DR-06 DR-07 DR-08 DR-09 DR-10 DR-11 DR-12 DR-13 DR-14 DR-15 DR-17 DR-19 DR-20 DR-21 DR-22 DR-23 DR-24 5581 5503 5471 5503 5523 5501 54945494 5500 5588 5603 5453 dry 5451 5495 5507 5539 5577 5544 5513 5538 5548 dry 5494 5493 5484 55795549 5550 55765571 5598 5594 5610 5598 5544 5542 5597 5610 5602 5603 5586 5591 5561 5590 5587 5586 5615 5639 5588 5587 5584 5605 5608 5588 5609 5583 5544 5539 5555 5584 5574 5526 5559 5586 5538 5518 5555 5558 5585 5584 55675563 55855571 5543 5493548354845492 5474 5480 5482 5487 5492 5487 5466 5465 5454 5455 5443 5420 dry 5425 5418 5624 5383 5234 5560 5380 5468 (not included) EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl KRIGED 4th QUARTER, 2011 WATER LEVELS WHITE MESA SITE H:/718000/hydrpt2022/figures/Uwl1211b.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well installed October, 2011 showing elevation in feet amsl TW4-27 temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-10 5503 5584 5586 5594 5518 5380 Estimated dry area NOTE: MW-4, MW-26, TW4-4, TW4-19, and TW4-20 are pumping wells H:\718000\hydrpt2022\TW6wltrend_4Q21.xls: TW4_6 plot 5520 5525 5530 5535 5540 5545 5550 5555 Q4 0 7 Q1 0 8 Q2 0 8 Q3 0 8 Q4 0 8 Q1 0 9 Q2 0 9 Q3 0 9 Q4 0 9 Q1 1 0 Q2 1 0 Q3 1 0 Q4 1 0 Q1 1 1 Q2 1 1 Q3 1 1 Q4 1 1 Q1 1 2 Q2 1 2 Q3 1 2 Q4 1 2 Q1 1 3 Q2 1 3 Q3 1 3 Q4 1 3 Q1 1 4 Q2 1 4 Q3 1 4 Q4 1 4 Q1 1 5 Q2 1 5 Q3 1 5 Q4 1 5 Q1 1 6 Q2 1 6 Q3 1 6 Q4 1 6 Q1 1 7 Q2 1 7 Q3 1 7 Q4 1 7 Q1 1 8 Q2 1 8 Q3 1 8 Q4 1 8 Q1 1 9 Q2 1 9 Q3 1 9 Q4 1 9 Q1 2 0 Q2 2 0 Q3 2 0 Q4 2 0 Q1 2 1 Q2 2 1 Q3 2 1 Q4 2 1 Wa t e r L e v e l ( f t a m s l ) Quarter TW4-4 TW4-6 TW4-4 AND TW4-6 WATER LEVELSHYDRO GEO CHEM, INC.Approved FigureDateAuthorDateFile Name SJS 24TW6 wltrend plotSJS HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl H:/718000/hyrpt2022/ figures/Uflowsw1221_rev.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 25 estimated area having saturated thickness less than 5 feet estimated perched water flow path KRIGED 4th QUARTER, 2021 WATER LEVELS SHOWING INFERRED PERCHED WATER PATHLINES DOWNGRADIENT OF THE TAILINGS MANAGEMENT SYSTEM WHITE MESA SITE SJS HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl H:/718000/hyrpt2022/figures/Uspgflow1221.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 26 saturated thickness estimated to be less than 5 feet KRIGED 4th QUARTER, 2021 WATER LEVELS SHOWING INFERRED PERCHED WATER FLOW PATHLINES NEAR RUIN SPRING AND WESTWATER SEEP inferred perched flow path estimated saturated thickness in feet15 SJS temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-42 TWN-20 TW4-43 5524 HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well perched piezometer seep or spring showing elevation in feet amsl MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well temporary perched nitrate monitoring well TW4-12 TWN-7 5380 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021 temporary perched monitoring well installed September, 2021 TW4-43 TWN-20 saturated thickness estimated to be less than 5 feet 5500 4th quarter 2021 water level contour and label in feet amsl KRIGED 4th QUARTER, 2021 WATER LEVELS SHOWING INFERRED PERCHED WATER FLOW PATHS USED FOR TRAVEL TIME ESTIMATES AND KRIGED NITRATE AND CHLOROFORM PLUMES H:/718000/hydrpt2022/ figures/UpathNchl4Q21_rev.srf 27 4th quarter 2021 chloroform plume 4th quarter 2021nitrate plume potential perched water pathline (assuming hypothetical connection to Cottonwood Seep) inferred perched water pathline SJS B ur ro Canyon Fo rma t ion Brushy Basin Member HYDRO GEO CHEM, INC. 28 PHOTOGRAPH OF THE WESTWATER SEEP SAMPLING LOCATION JULY, 2010 Westwater Seep (sampling location) B ur ro Canyon Fo rma t ion Brushy Basin Member HYDRO GEO CHEM, INC. 29 PHOTOGRAPH OF THE CONTACT BETWEEN THE BURRO CANYON FORMATION AND THE BRUSHY BASIN MEMBER AT WESTWATER SEEP H:/718000/hydrpt2022/ Figures/westcontact2.srf Westwater Seep (immediately downgradient from sampling location) Burro Canyon Formation Brushy Basin Member HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl H:/718000/hyrpt2022/figures/UflvectNchlQ21.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 30 saturated thickness estimated to be less than 5 feet KRIGED 4th QUARTER, 2021 WATER LEVELS SHOWING KRIGED NITRATE AND CHLOROFORM PLUMES AND GENERAL FLOW DIRECTIONS WHITE MESA SITE 4th quarter, 2021 chloroform plume 4th quarter, 2021 nitrate plume estimated perched water flow direction SJS H:\718000\hydrpt2022\TW27area_wl_4Q21.xls: plot F31 5510 5520 5530 5540 5550 5560 5570 5580 12/31/1999 12/30/2001 12/31/2003 12/30/2005 12/31/2007 12/30/2009 12/31/2011 12/30/2013 12/31/2015 12/30/2017 12/31/2019 12/30/2021 el e v a t i o n ( f t a m s l ) date TW4-6 TW4-13 TW4-14 TW4-26 TW4-27 WATER LEVELS IN WELLS NEAR TW4-27HYDRO GEO CHEM, INC.Approved FigureDateAuthorDateFile Name SJS 31plot F31SJS HYDRO GEO CHEM, INC. 1 mile WHITE MESA Mill Site CORRAL CANYON CORRAL SPRINGS COTTONWOOD ENTRANCE SPRING RUIN SPRING WESTWATER Cell 1 Cell 2 Cell 3 Cell 4A Cell 4B MW-01 MW-02 MW-3A MW-11 MW-14MW-15 MW-17 MW-18 MW-19 MW-20 MW-21 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-32 MW-33 MW-34MW-37 MW-38 MW-39 MW-40 TW4-01 TW4-03 TW4-34 TWN-01 TWN-02 TWN-03 TWN-04 TWN-05 TWN-06 TWN-07 TWN-08 TWN-09 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 TWN-20 TWN-21 PIEZ-01 PIEZ-02 PIEZ-3A PIEZ-04 PIEZ-05 TW4-05 TW4-12 TW4-13 TW4-31 TW4-32 MW-12 TW4-11TW4-16 TW4-18 TW4-27 MW-26 MW-35 MW-36 TW4-04 TW4-07 TW4-09 TW4-19 TW4-21 TW4-24 TW4-25 TW4-26 TW4-40 TW4-06 TW4-42 TW4-02 TW4-08 MW-04 MW-05 TW4-22 TW4-23 TW4-20 TW4-28 TW4-29 TW4-30 TW4-10 TW4-33 TW4-35 TW4-36 TW4-41TW4-14 DR-05 DR-06 DR-07 DR-08 DR-09 DR-10 DR-11 DR-12 DR-13 DR-14 DR-15 DR-17 DR-19 DR-20 DR-21 DR-22 DR-23 DR-24 TW4-37 TW4-38 TW4-39 MW-24A abandoned abandoned abandoned abandoned abandoned abandoned abandoned abandoned abandoned abnd AWN-X1 AWN-X2 AWN-X3 abnd abnd abnd wildlife pond wildlife pond wildlife pond TW4-43 DR-02 DR-16 DR-18 DR-25 abandoned abandoned abandoned abandoned EXPLANATION seep or spring RUIN SPRING MW-30 perched boring showing pyrite in log and having no laboratory detection MW-29 perched boring having a possible pyrite detection via laboratory analysis (but not shown in log) MW-24 perched boring having pyrite detected via laboratory analysis only (not shown in log) MW-25 perched boring showing pyrite in log and having a laboratory detection (if analyzed) MW-33 perched boring having detailed log showing no pyrite perched boring (pyrite status unknown)MW-5 WHITE MESA SITE PLAN SHOWING PYRITE OCCURRENCE IN PERCHED BORINGS 32H:/718000/hydrpt2022/ figures/pyrite_ocuurence21.srfSJS (note: 'abnd' = abandoned) HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well perched piezometer seep or spring MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well temporary perched nitrate monitoring well TW4-12 TWN-7 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021 temporary perched monitoring well installed September, 2021 TW4-43 TWN-20 saturated thickness estimated to be less than 5 feet 5500 4th quarter 2021 water level contour and label in feet amsl PROPOSED NEW CELL 5A AND 5B MONITORING WELLS AND PIEZOMETER WHITE MESA SITE H:/718000/hydrpt2022/ figures/UwlPropWellC5_r1.srf 33SJS MW-42 DR-26 APPENDIX A LITHOLOGIC LOGS APPENDIX A.1 DR - SERIES APPENDIX A.2 MW - SERIES APPENDIX A.3 PIEZ - SERIES APPENDIX A.4 TW4 - SERIES APPENDIX A.5 TWN - SERIES APPENDIX A.6 REVISED MANCOS PRESENCE AND THICKNESS HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 1 mile CORRAL CANYON CORRAL SPRINGS COTTONWOOD ENTRANCE SPRING RUIN SPRING WESTWATER Cell 1 Cell 2 Cell 3 Cell 4A Cell 4B 7.5 11 13 17 6 9.5 6 17.5 5 2 3 12 MW-3A MW-23 MW-24 MW-28 MW-38 PIEZ-01 PIEZ-02 PIEZ-05 TWN-09 DR-02 DR-05 DR-09 MW-05 MW-11 MW-12 MW-14MW-15 abandoned abandoned EXPLANATION seep or spring RUIN SPRING perched boring re-interpreted to have Mancos Shale showing estimated thickness in feet MW-24 13 H:/718000/hydrpt2022/ report/AppA.6/newmancos_4Q21.srf WHITE MESA SITE PLAN SHOWING BORINGS RE-INTERPRETED TO HAVE MANCOS SHALE Mancos likely to have been present prior to cell excavation/construction MW-12 A.6SJS3/28/2022 APPENDIX B WELL CONSTRUCTION SCHEMATICS APPENDIX B.1 DR - SERIES APPENDIX B.2 MW - SERIES APPENDIX B.3 TW4 - SERIES 2 TW4-27 AS-BUILT WELL CONSTRUCTION SCHEMATIC SJS 10/25/11 K:\7180272A Well Construction DiagramCHEM, INC. GEO HYDRO Approved Date FigureReference 2 CHEM, INC. GEO HYDRO Approved DateDate File Name FigureAuthor TW4-43 AS-BUILT WELL CONSTRUCTION SCHEMATIC SJS 9/28/21 7180291A 2JAA9/28/21 APPENDIX B.4 TWN - SERIES CHEM, INC. GEO HYDRO Approved DateDate File Name FigureAuthor TWN-20 AS-BUILT WELL CONSTRUCTION SCHEMATIC SJS 04/29/21 7180290A 2JAA04/29/21 CHEM, INC. GEO HYDRO Approved DateDate File Name FigureAuthor TWN-21 AS-BUILT WELL CONSTRUCTION SCHEMATIC SJS 04/29/21 7180290A 3JAA04/29/21 APPENDIX C INTERA SOIL BORING LOGS H:\718000\hydrpt14\AppC_INTERA_logs\INTERA soil boring logs summary.doc C-1 APPENDIX C INTERA SOIL BORING LOGS SUMMARY In May and June 2011, INTERA, Inc. installed 75 soil borings in the vicinity of the mill site. Borings GP-01A1 through GP-02A1 and GP-01C through GP-07C were installed to the north and south of the mill site and tailings cells; GP-01B through GP-48B were completed within and immediately outside the area of the mill site. Borings were drilled by Earth Worx using the Geoprobe push probe method. Soil samples for lithologic logging were collected using the continuous dual tube method. Locations of soil borings are provided on Figures C.1 and C.2; copies of the boring logs are provided in Appendix C.1. Soil samples from the GP-A1 and GP-B series borings showed a consistent lithology. Depths of refusal ranged from 2.7 ft bgs to 9.7 ft bgs. Yellowish-red, silty, fine sand predominated from the ground surface to about four to six ft bgs, generally transitioning to pink, silty, fine sand or pink sandstone to the depth of refusal. Roots were occasionally present in the top several feet of the borings. Soil samples from the GP-C series borings within or near the mill site showed more variable lithology. Depths to refusal were deeper overall than in the GP-A1 and GP-B series borings, and ranged from 1.7 to 24.5 ft bgs. Yellowish-red silty sand predominated in the upper portion of the GP-C borings, from approximately four to 10 ft bgs, and was typically underlain by interbedded reddish clay or clayey silt, and pinkish silt or silty sand to the depth of refusal. Gypsum precipitate was commonly seen in the lower portions of the GP-C series borings, and fine gravel was present in low proportions in multiple borings. FIGURES HYDRO GEO CHEM, INC. APPROVED DATE REFERENCE FIGURE 1 mile Mill Site CORRAL CANYON CORRAL SPRINGS COTTONWOOD ENTRANCE SPRING RUIN SPRING WESTWATER Cell 1 Cell 2 Cell 3 Cell 4A Cell 4B GP-01A GP-02A GP-03A GP-04A GP-05A GP-06A GP-07A GP-08A GP-09A GP-10A GP-11A GP-12A GP-13A GP-14A GP-15A GP-16A GP-17A GP-18A GP-19A GP-20A GP-01C GP-02C GP-03C GP-04C GP-05C GP-06C GP-07C EXPLANATION off-site Intera soil borings GP-01A through GP-20A seep or spring GP-01A RUIN SPRING off-site Intera soil borings GP-01C through GP-07C GP-01C GP-01B on-site Intera soil borings GP-01B through GP-48B INTERA SOIL BORING LOCATIONS WHITE MESA SITE See Inset Map Detail Figure C.2 H:/718000/hydrpt14/Intera_logs/interaloc.srf C.1 Cell 1 Cell 2 Cell 3 Cell 4A GP-07B GP-35B GP-25B GP-39B GP-08B GP-36B GP-44B GP-26B GP-40B GP-11BGP-12B GP-31B GP-32B GP-33B GP-46B GP-47B GP-42B GP-43B GP-21BGP-22B GP-23B GP-24B GP-16B GP-37B GP-03B GP-05B GP-10B GP-34B GP-45B GP-48B GP-41B GP-15B GP-38B GP-04B GP-01B GP-02B GP-09B HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE EXPLANATION GP-01B INTERA BORING LOCATIONS GP-1B THROUGH GP-48B (DETAIL MAP) WHITE MESA SITEon-site Intera soil borings GP-01B through GP-48B GP-06B GP-13B GP-14B GP-30BGP-28BGP-27B GP-29B GP-20B GP-19B GP-17B GP-18B H:/718000/hydrpt14/ Intera_logs/intera_loc_det_rev.srf C.2 APPENDIX C.1 INTERA SOIL BORING LOGS 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 1 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-01A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.95 0.5/0.65 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.7' Silty SAND, reddish brown (5YR 4/4), very fine-grained sand, silt, poorly graded, very loose, dry, little white mottling, HCl strong 3.7-4.5' Silty SAND, pink (5YR 6/4), very fine-grained sand, silt, poorly graded, medium dense, dry, HCl strong Total depth of boring 4.5' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 2 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-02A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 3.1/3.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.7' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl weak to moderate, little white mottling w/ HCl strong 4.7-7.1' Silty SAND, pink (5YR 7/3), very fine-grained sand, silt, poorly graded, dense, dry, HCl strong, trace fine sand Total depth of boring 7.1' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 3 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate additional sample volume required by the analytical laboratory. Log of Soil Boring GP-03A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 2.8/3.1 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis (1) 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose, dry, root at top, HCl strong 4.0-6.8' Silty SAND, reddish yellow (6/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl strong, trace fine sand Total depth of boring 6.8' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 4 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-04A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.7' Silty SAND, reddish brown (5YR 4/4), very fine-grained sand, silt, poorly graded, very loose, dry, little white mottling, HCl strong 3.7-4.0' Silty SAND, pink (5YR 6/4), very fine-grained sand, silt, poorly graded, medium dense, dry, HCl strong Total depth of boring 4.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 5 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-05A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Duel Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.7 3.6/3.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-6.4' Silty SAND, yellow red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose, roots at top, HCl moderate 6.4-7.6' Silty SAND, light brown gray (10YR 6/2), very fine-grained sand, silt, poorly graded, dense, dry, HCl strong, trace fine sand Total depth of boring 7.6' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 6 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-06A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.1 4.0/3.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis (1) 0-5.9' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl moderate, trace roots at top, little white mottling w/ HCl strong 5.9-8.0' Silty SAND, very pale brown (10YR 8/4), very fine-grained sand, silt, poorly graded, dense, dry, HCl strong, trace fine sand Total depth of boring 8.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 7 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-07A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 4.0/3.3 1.7/1.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.9' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl strong, little white mottling, HCl strong 4 to 4.9' bgs 4.9-7.5' Silty SAND, pink (7.5YR 7/4), very fine-grained sand, silt, poorly graded, medium dense to dense, dry, HCl strong, trace loose fine sand 7 to 7.5' 7.5-9.7' Silty SAND, pink (7.5YR 7/3), very fine-grained sand, silt, poorly graded, loose to dense, dry, HCl strong, trace fine sand Total depth of boring 9.7' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 8 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-08A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.5' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose, dry, trace gravel, roots at top, HCl none 3.5-4.0' Silty SAND, pink (7.5YR 8/4), very fine-grained sand, silt, poorly graded, dense, dry, HCl strong Total depth of boring 4.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 0 9 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Duplicate sample collected. Sample interval was increased to 2 feet to accommodate additional sample volume required by the analytical laboratory. Log of Soil Boring GP-09A1 (Page 1 of 1) Date/Time Started : 05/17/11 Date/Time Completed : 05/17/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.95 4.0/3.75 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose, dry, HCl none, trace roots 4.0-8.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand trace fine-grained sand, silt, poorly graded, loose, HCl none, trace mica, trace white mottled w/ HCl strong Total depth of boring 8.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 0 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-10A1 (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 2.66/1.25 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none to weak 2.0-2.7' Sand/Silty Sand, very pale brown (10YR 8/3), very fine-grained sand, trace silt, poorly graded, loose, dry, subangular to subrounded, HCl none, little very fine sand Total depth of boring 2.7' bgs (refusal) US C S SM SP/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 1 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Duplicate sample collected. Sample interval was increased to 2 feet to accommodate additional sample volume required by the analytical laboratory. Log of Soil Boring GP-11A1 (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 1.0/1.2 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none 3.0-5.0' Silty SAND, yellowish red (5YR 5/8 & very pale brown 10YR 8/2), fine-grained sand, silt, poorly graded, loose to medium dense, dry, some white mottling w/ HCl strong, mottled but little red or very pale brown, HCl weak to medium, trace fine sand Total depth of boring 5.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 2 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-12A1 (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none 2.0-4.0' Silty SAND, pink (5YR 7/4), very fine-grained sand, silt, poorly graded, medium dense loose to medium dense, trace fine sand, dry, some white mottling w/ HCl strong Total depth of boring 4.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 3 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-13A1 (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.1 0.7/0.7 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, trace white mottling w/ HCl strong 4.0-4.7' Silty SAND, pink (5YR 7/4), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl strong, trace fine sand Total depth of boring 4.7' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 4 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-14A1 (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.9 2.9/1.9 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-5.8' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, trace white mottling w/ HCl strong, HCl none to weak 5.8-6.9' Silty SAND, pink (5YR 7/4 & yellowish red 5YR 5/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, some what mottling w/ HCl strong, trace fine sand Total depth of boring 6.9' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 5 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-15A1 (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 3.6/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-5.1' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, trace white mottling w/ HCl strong, HCl none to weak 5.1-7.6' Silty SAND, pink (5YR 7/4), very fine-grained sand, silt, poorly graded, medium dense, dry, trace fine sand, HCl strong, some white mottling w/ HCl strong Total depth of boring 7.6' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 6 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Duplicate sample collected. Sample interval was increased to 2 feet to accommodate additional sample volume required by the analytical laboratory. Log of Soil Boring GP-16A1 (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.7 3.1/3.3 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.1' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none 3.1-7.1' Silty SAND, pink (5YR 7/4), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl strong, trace fine sand Total depth of boring 7.1' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 7 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Notes: Log of Soil Boring GP-17A1 (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 3.2/2.9 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2.5' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl weak 2.5-3.2' Silty SAND, pink (5YR 7/4), very fine-grainded sand, silt, loose to medium dense, dry, HCl strong, trace fine sand, little white mottling w/ HCl strong Total depth of boring 3.2' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 8 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Notes: Log of Soil Boring GP-18A1 (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 3.3/3.1 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-6.9' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl strong, trace white mottling w/ HCl strong, trace roots at top 6.9-7.3' Silty SAND, pink (5YR 7/4), very fine-grainded sand, silt, poorly graded, loose to medium dense, dry, HCl strong, trace fine sand Total depth of boring 7.3' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 1 9 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Duplicate sample collected. Sample interval was increased to 2 feet to accommodate additional sample volume required by the analytical laboratory. Log of Soil Boring GP-19A1 (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v l Pe n . / R e c . ( f e e t ) 4.0/3.9 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-6.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none to weak, little white mottling w/ HCl strong 6.0-8.0' Silty SAND, pink (5YR 7/4), very fine-grainded sand, silt, poorly graded, loose to medium dense, dry, HCl strong, trace fine sand, sand & fine gravel 7.9-8.0' bgs Total depth of boring 8.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o re L o g s \ D e n i s o n \ G P - 2 0 A 1 . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Notes: Log of Soil Boring GP-20A1 (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 1.1/1.3 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.1' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none 3.1-5.1' Silty SAND, pink (5YR 7/4), very fine-grainded sand, silt, loose to medium dense, dry, HCl weak to strong, little white mottling w/ HCl strong, trace fine sand Total depth of boring 5.1' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 1 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-01B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.15 0.4/0.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.1' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, loose to dense, dry, HCl strong, mottling common 3.1-4.4' Silty Gravelly SAND, pinkish gray (5YR 7/2), very fine- to coarse-grained sand (~60%), gravel to 0.1" diameter (~30%), well graded, angular to subrounded, very loose, non-plastic, dry, no HCl Total depth of boring 4.4' bgs (refusal) US C S SM SW/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 2 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-02B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/1.5 4.0/3.8 3.8/3.5 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~65%), poorly graded, subangular to subrounded, loose, dry, HCl strong, roots abundant top 0.5' 3.0-7.0' Lean CLAY, light reddish brown (5YR 6/3), very fine-grained sand (~25%), subangular to subrounded, soft, medium plastic, moist, HCl moderate 7.0-11.8' Clayey SAND, light reddish brown (5YR 6/3), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose to dense, medium plastic, moist, HCl strong Total depth of boring 11.8' bgs (refusal) US C S SM CL SC GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 3 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-03B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 4.0/4.0 1.6/2.2 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, loose, dry, HCl strong, mottling common 4.0-8.6' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, moist, HCl strong, mottling common 8.6-9.6' Lean CLAY, pink (5YR 7/4), very fine-grained sand (~25%), subangular to subrounded, soft, moderately plastic, moist, HCl strong Total depth of boring 9.6' bgs (refusal) US C S SM CL GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 4 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-04B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 0.8/1.1 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, dry, HCl weak, mottling common, roots in top 0.3' 4.0-4.6' SILT, red (2.5YR 5/6), very fine-grained sand (~25%), loose, non-plastic, non-cohesive, dry, HCl strong Total depth of boring 4.8' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 5 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-05B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 4.0/3.4 4.0/3.9 1.3/1.3 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-6.5' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common, roots in top 1.3' 6.5-13.3' Clayey SILT, yellowish brown (10YR 5/4), loose to dense, non- to slightly plastic, dry to moist, HCl slight, gypsum stringers and precipitate common Total depth of boring 13.3' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 6 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-06B (Page 1 of 1) Date/Time Started : 06/07/11 Date/Time Completed : 06/07/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 4.0/4.0 4.0/4.0 1.8/1.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~80%), poorly graded, angular to subrounded, very loose, dry, no HCl 1-4' HCl strong and 5YR 4/4 4.0-8.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~80%), poorly graded, angular to subrounded, very loose, dry, HCl 8.0-12' Clayey SILT, yellowish brown (10YR 5/4), poorly graded, loose, non-plastic, dry to moist, HCl slight 12-13.8' Clayey SILT, yellowish brown (10YR 5/4), poorly graded, loose, non-plastic, dry, HCl slight, laminated Total depth of boring 13.8' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 7 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-07B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.5 4.0/3.5 2.8/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common 4.0-8.0' Silty SAND, reddish brown (5YR 5/4), very fine-grainded sand (~80%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common 8.0-10.2' Silty SAND, reddish brown (5YR 5/4), very fine-grainded sand (~60%), poorly graded, subangular to subrounded, slightly dense, dry, HCl strong, white mottling common 10.2-10.8' SILT, pink (5YR 7/4), very dense to hard, non-plastic, dry, HCl strong Total depth of boring 10.8' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 8 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-08B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 4.0/3.9 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis Road base 0.8-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, dense, dry, HCl strong, white mottling throughout 4.0-8.0' SILT, pink (5YR 7/4), trace very fine-grained sand, loose, non-plastic, dry, HCl strong 8.0-11.3' Silty SAND, pink (5YR 7/4), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose to dense, dry, HCl strong 11.3-12' SILT, pink (5YR 7/4), very dense, hard, non-plastic, dry, HCl strong Total depth of boring 12' bgs (refusal) US C S SM ML SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 9 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-09B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.2 4.0/3.75 3.4/3.4 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, reddish brown (5YR 5/4), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common 4.0-8.0' Silty SAND, reddish brown (5YR 5/4), very fine-grained sand (~80%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common 8.0-10.8' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, slightly dense, dry to moist, HCl strong, white mottling common 10.8-11.4' SILT, pink (5YR 7/4), very dense, hard, non-plastic, dry, HCl strong Total depth of boring 11.4' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 0 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-10B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 4.0/4.0 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common 4.0-8.0' Silty SAND, reddish brown (5YR 5/4), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common 8.0-11.5' Silty SAND, reddish brown (5YR 5/4), very fine-grained sand (~60%), poorly graded, loose to dense, dry, HCl strong, white mottling common 11.5- 12' SILT, pink (5YR 7/4), very dense, hard, dry, HCl strong Total depth of boring 12' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 1 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-11B (Page 1 of 1) Date/Time Started : 06/07/11 Date/Time Completed : 06/07/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 4.0/3.2 4.0/3.2 0.1/0.1 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2.0' Silty SAND, reddish brown (5YR 4/4), very fine-grained sand (~60%), poorly graded, subangular to subrounded, very loose, dry, HCl slight, roots 2.0-4.0' Silty SAND, light reddish brown (5YR 6/3), very fine-grained sand (~60%), poorly graded, subangular to subrounded, very loose, dry, HCl strong 4.0-7.0' Silty SAND, light reddish brown (5YR 6/3), very fine-grained sand (~60%), poorly graded, subangular to subrounded, very loose, dry, HCl strong 7.0-12.1' Clayey SILT, pinkish gray (7.5YR 6/2), loose to dense, non-plastic, dry, HCl strong, white mottling common, laminated Total depth of boring 12.1' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 2 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-12B (Page 1 of 1) Date/Time Started : 06/07/11 Date/Time Completed : 06/07/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.5 4.0/3.1 4.0/3.4 0.4/0.4 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.5' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, poorly graded, subangular to subrounded, very loose, dry, no HCl 0-1.5' bgs, HCl slight 1.5-8.0' Silty SAND, reddish brown (5YR 5/4), very fine-grained sand, poorly graded, subangular to subrounded, very loose, dry, HCl slight, laminated 8.0-12.4' Clayey SILT, light olive brown (2.5YR 4/3), poorly graded, loose, non-plastic, dry, HCl, laminated, gypsum precipitate throughout 10.5-12' 5-10mm gypsum stringers Total depth of boring 12.4' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 3 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-13B (Page 1 of 1) Date/Time Started : 06/07/11 Date/Time Completed : 06/07/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 4.0/4.0 4.0/4.0 1.8/1.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.5' Silty SAND, yellowish red brown (5YR 4/6), very fine-grained sand, poorly graded, subangular to subrounded, very loose, dry, HCl slight 1.5-6.2' Silty SAND, light reddish brown (5YR 6/3), very fine-grained sand, poorly graded, subangular to subrounded, very loose, dry, HCl slight 6.2-8.0' Clayey SILT, reddish brown (5YR 5/4), trace very fine-grained sand, loose to dense, non-plastic, dry to moist, HCl strong, white mottling throughout 8.0-12' Clayey SILT, dark grayish brown (10YR 4/2), dense, slightly plastic, dry, HCl weak, thin bedding 12-13.8' Clayey SILT, light yellowish brown (10YR 6/4), loose, non-plastic, dry, HCl slight, thin bedding Total depth of boring 13.8' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 4 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-14B (Page 1 of 1) Date/Time Started : 06/07/11 Date/Time Completed : 06/07/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 4.0/3.0 4.0/3.5 2.0/2.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand, poorly graded, subangular to subrounded, very loose, dry, no HCl quartz fragments 4.0-4.7' bgs 4.7-8.0' Silty SAND, reddish yellow (2.5YR 6/6), very fine-grained sand, poorly graded, loose to dense, dry, HCl moderate, white mottling throughout 8.0-12' Clayey SILT, brown (7.5YR 5/2), poorly graded, loose to dense, non-plastic, dry, HCl slight 12-14' Clayey SILT, yellowish brown (10YR 5/6), poorly graded, loose to dense, non-plastic, dry, HCl slight Total depth of boring 14' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 5 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-15B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.4 4.0/3.4 4.0/2.8 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.5' Silty SAND, yellowish red (5YR 4/6), very fine- to medium-grained sand (~80%), well graded, angular to subrounded, loose, dry to moist, HCl moderate, minor white mottling 3.5-4.0' Clayey SILT, light reddish brown (5YR 6/4), poorly graded, dense, slightly plastic, moist, HCl moderate 4.0-10' Silty SAND, yellowish red (5YR 4/6), very fine-grainded sand (~75%), poorly graded, subangular to subrounded, loose, dry to moist, HCl strong, white mottling throughout 10-12' CLAY, yellowish red (5YR 4/6), dense, low to medium plastic, cohesive, moist, HCl slight 12-16' CLAY, pale brown (10YR 6/3), very dense, low plastic, slightly cohesive, dry, HCL moderate, minor FeO staining Total depth of boring 16' bgs (refusal) US C S SM ML/CL SM CL GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 6 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-16B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 4.0/3.2 4.0/3.1 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-5.5' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~75%), poorly graded, subangular to subrounded, loose, dry to moist, no HCl 5.5-8.0' Silty SAND, reddish yellow (5YR 6/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling throughout 8.0-11.3' CLAY, reddish yellow (5YR 6/6), hard, medium plastic, cohesive, dry to moist w/ increasing moisture towards base of interval, HCl strong 11.3-16' CLAY, pale brown (10YR 6/3), very hard, slightly plastic, slightly cohesive, moist, HCl strong Total depth of boring 16' bgs (refusal) US C S SM CL ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 7 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-17B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 4.0/3.85 4.0/3.65 4.0/3.4 2.6/2.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.4' FILL 1.4-12' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~75%), poorly graded, subangular to subrounded, loose, dry, HCl moderate, white mottling common 12-15.6' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, moist, HCl strong, white mottling common 15.6-16' SILT, very pale brown (10YR 7/4), hard, non-plastic, non-cohesive, dry, HCl moderate 16-18' Lean CLAY, yellowish red (5YR 5/6), very fine-grained sand (~30%), subrounded, soft, slightly plastic, slightly cohesive, moist, HCl slight 18-18.6' SILT, very pale brown (10YR 7/4), hard, non-plastic, non-cohesive, dry, HCl moderate Total Depth of Boring 18.6' bgs (refusal) US C S SM ML ML/CL ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 8 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-18B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/4.0 4.0/3.8 4.0/3.8 4.0/3.25 2.5/2.85 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.5' FILL 1.5-12' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~75%), poorly graded, subangular to subrounded, loose, dry, HCl strong, white mottling common, caliche rich 10-10.5' bgs 12-16' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~75%), poorly graded, subangular to subrounded, loose, slightly moist with moisture increasing w/ depth, HCl strong, occasional white mottling 16-17.9' Sandy Silty CLAY, yellowish red (5YR 5/6), very fine-grained sand (~30%), soft, slightly plastic, slightly cohesive, moist, HCl slight 17.9-18.5' SILT, very pale brown (10YR 7/4), hard, non-plastic, non-cohesive, dry, HCl strong, shale Total depth of boring 18.5' bgs (refusal) US C S SM ML/CL ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 1 9 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-19B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.85 4.0/3.85 4.0/3.95 4.0/3.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2.5' FILL 2.5-12' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~75%), poorly graded, subangular to subrounded, loose, dry, HCl moderate, occasional white mottling 12-17.1' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose to dense, slightly moist to moist increasing w/ depth, HCl strong, occasional white mottling 17.1-17.9' SILT, very pale brown (10YR 7/4), very dense, hard, non-plastic, dry, HCl strong, weathered shale Total depth of boring 17.9' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 0 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-20B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/4.0 4.0/3.9 4.0/3.5 4.0/3.2 1.4/1.4 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.0' FILL 1.0-12' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, dry, HCl moderate, occasional white mottling 12-16' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, moist, HCl moderate, occasional white mottling 16-16.7' Sandy Lean CLAY, very fine-grained sand (~15%), yellowish red (5YR 5/6), soft, medium plastic, medium cohesive, very moist, HCl slight 16.7-17.4' SILT, very pale brown (10YR 7/4), hard, non-plastic, dry, HCl strong, shale Total depth of boring 17.4' bgs (refusal) US C S SM CL ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 1 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-21B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.3 2.7/2.9 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.5' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, moist, HCl weak, gravel from 3.8-4.0' 4.5-5.5' Silty SAND, pink (5YR 7/3), very fine-grained sand (~60%), poorly graded, subrounded, loose, slightly cohesive, wet, HCl moderate 5.5-6.7' Sandy SILT, light yellowish brown (10YR 6/4), very fine-grained sand (~15%), poorly graded, subrounded, loose, dry, thin bedding, HCl strong Total depth of boring 6.7' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 2 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-22B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 4.0/2.9 0.9/1.9 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~75%), poorly graded, subrounded, loose, dry to slightly moist, HCl no to weak 4.0-7.6' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, moist to very moist, HCl weak 7.6-8.0' SILT, pink (5YR 8/3), very fine-grained sand (~25%), poorly graded, subrounded, dense, slightly cohesive, moist, HCl strong8.0-8.9' SILT, brownish yellow (10YR 6/6), very fine-grained sand (~25%), poorly graded, subrounded, loose, slightly moist, HCl weak, thin bedding Total depth of boring 8.9' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 3 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-23B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 4.0/2.5 4.0/2.0 3.3/2.3 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2.0' Silty SAND, reddish gray (5YR 5/2), very fine- to coarse-grained sand, well graded, angular to subrounded, loose, non-plastic, dry, HCl moderate 2.0-4.0' Lean CLAY w/ Sand, brownish yellow (10YR 6/6), fine- to coarse-grained sand (~20%), well graded, angular to subrounded, hard, slightly plastic, moist, HCl slight, burned (ash?) layer from 2.0-2.2' bgs 4.0-15.3' Sandy Lean CLAY, reddish brown (5YR 5/4), fine- to coarse-grained sand (~30%), up to 0.05' diameter gravel (<10%), well graded, angular to subrounded, soft, low to moderate plastic, moist, HCl weak Total depth of boring 15.3' bgs (refusal) US C S SW/SM CL GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 4 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-24B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.7 4.0/2.7 4.0/2.5 0.8/0.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-8.0' Clayey Gravelly SAND, dark yellowish brown, (10YR 4/4), very fine- to coarse-grained sand (~75%), up to 0.04' diameter gravel (~15%), soft, slightly plastic, moist, HCl weak 8.0-11.3' Sandy Gravelly SILT, brown (10YR 5/3), fine- to coarse-grained sand (~30%), up to 0.02' diameter gravel (~10%), soft, slightly plastic, moist, HCl weak 11.3-12.5' Silty SAND, brownish yellow (10YR 6/6), very fine- to fine-grained sand (~70%), well graded, subangular to subrounded, dense, dry, no HCl, gypsum precipitate throughout 12.5-12.8' Silty SAND, yellowish red (5YR 4/6), very fine- to fine-grained sand (~80%), poorly graded, subangular to subrounded, loose, wet, HCl weak Total depth of boring 12.8' bgs (refusal) US C S SW/SC ML SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 5 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-25B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.1 4.0/3.6 4.0/3.8 4.0/4.0 3.4/3.4 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-0.75' Road base gravel 0.75-11.7' Silty SAND, reddish yellow (5YR 6/6), very fine-grained sand (~65%), poorly graded, subangular to subrounded, loose to dense, dry to 10.9' bgs, moist to 11.7' bgs, HCl strong, occasional white mottling 11.7-13.3' CLAY, reddish yellow (5YR 6/6), dense, plastic to very plastic, cohesive, slightly moist, HCl strong 13.3-19.4' CLAY, pale brown (10YR 6/3), dense, slightly plastic, slightly cohesive, dry, HCl slight, weathered shale, platy shale fragments increasing w/ depth, weathered shale w/ shale fragments Total depth of boring 19.4' bgs (refusal) US C S SM CL/CH ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 6 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-26B (Page 1 of 1) Date/Time Started : 06/09/11 Date/Time Completed : 06/09/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 4.0/3.3 4.0/3.6 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-0.3' Road base gravel 0.3-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, dense, moist, HCl strong, white mottling common 4.0-10.1' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, dense, dry to moist, HCl moderate, white mottling common 10.1-13' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, dense, moist, HCl moderate 13-16' SILT, yellowish brown (10YR 5/4), very dense, hard, dry, HCl strong Total depth of boring 16' bgs (refusal) US C S SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 7 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-27B (Page 1 of 1) Date/Time Started : 06/10/11 Date/Time Completed : 06/10/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 4.0/3.3 4.0/3.6 2.6/2.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, loose, dry, HCl moderate, mottling common 4.0-11.8' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, moist, HCl weak, mottling rare 11.8-13' Clayey SAND, yellowish red (5YR 4/6), very fine-grained sand, subrounded, loose, slightly plastic, moist, HCl strong, mottling throughout 13-14.6' Sandy SILT, yellowish brown (10YR 5/6), very fine-grained sand (~25%), subrounded, loose, non-plastic, non-cohesive, dry, HCl strong Total depth of boring 14.6' bgs (refusal) US C S SM SC ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 8 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-28B (Page 1 of 1) Date/Time Started : 06/10/11 Date/Time Completed : 06/10/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 4.0/3.0 4.3/3.4 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-7.4' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, moist, HCl weak to strong 7.4-7.7' Lean CLAY w/ Sand, very dark gray (5YR 3/1), very fine-grained sand (~15%), soft, plastic, moist, HCl weak 7.7-12' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, loose, moist, HCl weak, occasional mottling 12-12.3' Clayey SAND, very pale brown (10YR 7/3), very fine-grained sand w/ plastic fines, poorly graded, subangular to subrounded, loose, slightly plastic, moist, HCl strong Total depth of boring 12.3' bgs (refusal) US C S SM CL SM SC GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 2 9 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-29B (Page 1 of 1) Date/Time Started : 06/10/11 Date/Time Completed : 06/10/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.95 4.0/3.0 4.0/3.25 2.4/2.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.3' Road base 1.3-3.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, loose, dry, HCl moderate, white mottling throughout 3.0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, loose, moist, gravel and wood fragments common, HCl moderate, 4.0-12' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, dry to moist, HCl weak, occasional mottling 12-13.2' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, moist, HCl moderate 13.2-14.4' Silty SAND, yellowish brown (10YR 5/4), very fine-grained sand (~60%), poorly graded, subangular to subrounded, dense, moist, HCl moderate Total depth of boring 14.4' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 0 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-30B (Page 1 of 1) Date/Time Started : 06/10/11 Date/Time Completed : 06/10/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 4.0/3.15 4.0/3.3 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-7.1' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, loose, dry to moist, HCl weak, occasional mottling 7.1-7.2' Clayey SAND w/ low plastic fines, dark reddish brown (5YR 3/4), very fine-grained sand, poorly graded, subrounded, soft, slightly plastic, moist, HCl moderate 7.2-12' Silty SAND, Yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, moist, HCl none to weak 12-13.1' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, wet, HCl moderate Total depth of boring 13.1' bgs (refusal) US C S SM SC SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 1 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-31B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.1 1.6/1.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.7' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~65%), poorly graded, subangular to subrounded, very loose, dry, HCl moderate, white mottling throughout 4.7-5.6' SAND w/ minor Silt, pinkish gray (7.5YR 6/2), very fine- to fine-grained sand, poorly to well graded, subangular to subrounded, very loose, moist, HCl strong Total depth of boring 5.6' bgs (refusal) US C S SM SP/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 2 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-32B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.9 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subangular to subrounded, very loose, dry to moist increasing w/ depth, HCl moderate Total depth of boring 4.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 3 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-33B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 1 2 3 4 5 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 1.7/1.7 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.2' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~75%), poorly graded, subangular to subrounded, very loose, dry, HCl moderate, minor white mottling 1.2-1.7' SAND w/ minor Silt, pinkish gray (5YR 6/2), very fine- to fine-grained sand, poorly to well graded, subangular to subrounded, very loose, dry, HCl strong Total depth of boring 1.7' bgs (refusal) US C S SM SP/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 4 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-34B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 3.8/2.7 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~65%), poorly graded, subangular to subrounded, loose, dry to moist, HCl slight, minor roots 0-0.8' bgs 3.0-3.8' SAND w/ minor silt, pinkish gray (5YR 6/2), very fine- to fine-grained sand, poorly to well graded, subangular to subrounded, very loose, moist, HCl strong Total depth of boring 3.8' bgs (refusal) US C S SM SP/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 5 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-35B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.5 4.0/1.8 4.0/2.7 4.0/3.7 2.9/2.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' SAND w/ gravel FILL, dark reddish brown (5YR 3/3), fine- to coarse-grained sand, gravel to 0.06' diameter, well graded, angular to subrounded, loose, dry, HCl moderate 4.0-11' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~75%), poorly graded, subrounded, loose, moist, HCl moderate, mottling common 11-12' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~75%), poorly graded, subrounded, dense, moist, HCl weak 12-17.4' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~75%), poorly graded, subrounded, loose, moist to wet near bottom of interval. HCl weak 17.4-18.9' Clayey SILT, yellowish brown (10YR 5/4), dense, slightly plastic, moist, HCl strong Total depth of boring 18.9' bgs (refusal) US C S SW SM ML/CL GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 6 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-36B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.5 4.0/2.6 4.0/2.8 4.0/3.4 9.3/3.1 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2.5' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, loose, dry, HCl moderate, mottling common 2.5-11' Clayey Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, soft, slightly plastic, moist, HCl moderate 11- 13' Clayey Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, dense, slightly plastic, moist, no HCl 13-18.3' Silty SAND, reddish yellow ( 5YR 6/8), very fine-grained sand (~70%), poorly graded, subrounded, loose, dry to moist increasing with depth, HCl strong, mottling common 18.3-19.3' SILT, light gray (10YR 7/2), very fine-grained sand (~30%), subrounded, dense, non-plastic, dry, HCl strong, FeO staining Total depth of boring 19.3' bgs (refusal) US C S SM SM/SC SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 7 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-37B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 4.0/3.2 4.0/4.0 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, dry, HCl strong, mottling throughout 4.0-9.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subrounded, loose, moist, HCl slight, occasional mottling 9.0'-13.2' Clayey SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subrounded, soft, slightly plastic, moist, HCl strong, ~30% motttling 13.2-16' Clayey SILT, yellowish brown (10YR 5/6), soft to hard, slightly plastic, moist, HCl strong, ~5% mottling Total depth of boring 16' bgs (refusal) US C S SM SC ML/CL GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 8 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-38B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 4.0/3.3 4.0/3.1 4.0/4.0 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-5.0' Silty SAND, yellowish red (5YR 5/8), very fine-grained sand (~70%), poorly graded, subrounded, loose, dry, HCL strong, mottling common 5.0-11.9' Silty SAND, yellowish red (5YR 5/8), very fine-grained sand (~60%), poorly graded, subrounded, dense, moist, HCl weak 11.9-16' Clayey SILT, yellowish brown (10YR 5/6), soft to hard, slightly plastic, moist, massive-transitions to platy structure near bottom of interval, HCl slight Total depth of boring 16' bgs (refusal) US C S SM ML/CL GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 3 9 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-39B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 4.0/4.0 4.0/4.0 2.2/3.4 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-6.6' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~70%), poorly graded, subrounded, loose, dry to moist, HCL none 0-4' bgs & strong 4-6.6' bgs, mottling common 4-6.6' bgs 6.6-11' Lean CLAY, reddish brown (5YR 5/3), very fine-grained sand (~15%), poorly graded, subrounded soft, slightly plastic to plastic, moist, HCl strong 11-12.8' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, moist w/ moisture increasing with depth, HCl weak 12.8-14.2' Sandy SILT, gray (10YR 5/1), very fine-grained sand (~30%), poorly graded, subrounded, dense, dry, HCl weak, thin bedding to platy, FeO common 12.8-13.6' bgs Total depth of boring 14.2' bgs (refusal) US C S SM CL SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 0 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-40B (Page 1 of 1) Date/Time Started : 06/12/11 Date/Time Completed : 06/12/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 4.0/4.0 4.0/3.9 1.6/1.8 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subrounded, loose, dry to moist, HCL moderate 4.0-8.0' Sandy Silty Lean CLAY, yellowish red (5YR 5/6), very fine-grained sand (~20%), poorly graded, subrounded, soft, slightly plastic, moist, HCl moderate, occasional mottling 8.0-13' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, moist, HCl moderate, occasional mottling 13-13.6' Sandy SILT, yellowish brown (10YR 5/4), very fine-grained sand (~30%), poorly graded, subrounded, soft, slightly plastic, moist, HCl moderate Total depth of boring 13.6' bgs (refusal) US C S SM ML/CL SM ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 1 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-41B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 25 30 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.4 4.0/2.8 4.0/3.0 4.0/2.8 4.0/2.7 4.0/3.8 0.5/0.9 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-6.5' SAND, pale yellow (5Y 8/2), very fine- to fine-grained sand (~85%), poorly graded, subangular to subrounded, dense, dry, HCl none 6.5-19' Silty SAND, light brown (7.5YR 6/3) to pinkish gray (7.5YR 7/2), very fine-grained sand (~60%), poorly graded, subangular to subrounded, loose, dry, HCl none, thin bedded, occasional sandstone fragments, occasional FeO stains 19-24.5' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, loose, dry, HCl strong, mottling common Total depth of boring 24.5' bgs (refusal) US C S SP SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 2 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-42B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.4 4.0/3.8 0.5/1.1 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-5.5' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~65%), poorly graded, subangular to subrounded, loose, dry to moist, HCl strong, mottling common 5.5-8.0' Clayey Silty SAND, reddish brown (5YR 5/4), very fine-grained sand, poorly graded, subrounded, dense, slightly plastic, moist, HCl strong, mottling common 8.0-8.5' Silty CLAY, dark reddish brown (5YR 3/2), soft, slightly plastic to plastic, non-cohesive, dry, HCl strong, weathered shale, thin bedding Total depth of boring 8.5' bgs (refusal) US C S SM SM/SC ML/CL GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 3 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-43B (Page 1 of 1) Date/Time Started : 06/11/11 Date/Time Completed : 06/11/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.5 4.0/4.0 1.7/1.9 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-1.8' Fill 1.8-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~65%), poorly graded, subrounded, loose, dry, HCl moderate 4.0-5.8' Well Graded GRAVEL, very pale brown (10YR 2/3), fine- to medium-grained sand (~10%), gravel (~40%), well graded, subangular to subrounded, very loose, non-plastic, dry, HCl moderate 5.8-8.4' Clayey SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, dense, plastic, moist, HCl strong 8.4-9.7' SILT, light yellowish brown (10YR 6/4), soft, non-plastic, non-cohesive, moist, HCl strong Total depth of boring 9.7' bgs (refusal) US C S SM GW/GM SC ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 4 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-44B (Page 1 of 1) Date/Time Started : 06/10/11 Date/Time Completed : 06/10/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 15 20 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.3 4.0/2.8 4.0/3.7 4.0/3.5 2.4/3.1 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, pale brown (10YR 6/3), very fine- to medium-grained sand (~80%), well graded, subrounded, loose, dry, HCl moderate, fine crystals precipitate throughout 4.0-6.0' Clayey Sitly SAND, very pale brown (10YR 7/4), very fine-grained sand (~60%), poorly graded, subrounded, loose, slightly plastic, dry, HCL none, small rocks, wood scattered throughout 6.0-8.0' Clayey Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~60%), poorly graded, subrounded, slightly plastic, moist, HCl weak 8.0-12' Lean CLAY, dark reddish brown (5YR 3/2), silt, soft, slightly plastic, moist, HCl weak 12-14.3' Sandy Lean CLAY, dark reddish brown (5YR 3/2), very fine-grained sand (~20%), poorly graded, subrounded, very soft, plastic to very plastic, very cohesive, moist, HCl weak 14.3-16' Lean CLAY, gray to blueish gray (2 6/1), hard, plastic, non-cohesive, moist, HCl none, laminate bedding, weathered shale 16-18' Lean CLAY, blueish gray to gray (2 6/1), loose, plastic, moist, HCl none, thin bedding, FeO staining throughout, weathered shale 18-18.4' SILT, blueish gray to gray (2 5/1), hard, laminate bedding, shale fragments Total depth of boring 18.4' bgs (refusal) US C S SW/SM SM/SC CL CL/CH CL ML GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 5 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Duplicate sample collected. Sample interval was increased to 2 feet to accommodate for additional sample volume required by the analytical laboratory. Log of Soil Boring GP-45B (Page 1 of 1) Date/Time Started : 06/07/11 Date/Time Completed : 06/07/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.0 0.6/0.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, dark reddish brown (5YR 3/4), fine- to very fine-grained sand, poorly graded, subangular to subrounded, very loose, moist to wet, HCl none, roots 0-2' bgs 4.0-4.6' SAND w/ minor silt, pinkish gray (5YR 6/2), very fine- to fine-grained sand, poorly graded, subangular to subrounded, very loose, moist, HCl none Total depth of boring 4.6' bgs (refusal) US C S SM SP/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 6 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-46B (Page 1 of 1) Date/Time Started : 06/07/11 Date/Time Completed : 06/07/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.8 0.3/0.6 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-3.7' Silty SAND, dark reddish brown (5YR 3/4), very fine-grained sand (~70%), poorly graded, subangular to subrounded, very loose, moist to wet, HCl slight 3.7-4.3' SAND w/ minor silt, yellowish red (5YR 5/6), very fine- to fine-grained sand, poorly graded, subangular to subrounded, very loose, moist, HCl none Total depth of boring 4.3' bgs (refusal) US C S SM SP/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 7 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-47B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.6 0.7/0.7 DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.7' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand (~80%), poorly graded, subangular to subrounded, very loose to loose, moist to wet, HCl none, roots 0-2.5' bgs Total depth of boring 4.7' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 4 8 B . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): Log of Soil Boring GP-48B (Page 1 of 1) Date/Time Started : 06/08/11 Date/Time Completed : 06/08/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : E. Muller Depth in Feet 0 1 2 3 4 5 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 2.3/ DESCRIPTION Sample Interval Description Soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-2.0' Silty SAND, yellowish red (5YR 5/6), very fine-grained sand (~70%), poorly graded, subangular to subrounded, very loose, dry, HCl none, roots 0-1.4' bgs 2.0-2.3' SAND w/ minor Silt, light gray (10YR 7/2), very fine- to fine-grained sand, poorly graded, subangular to subrounded, very loose, dry, HCl strong Total depth of boring 2.3' bgs (refusal) US C S SM SP/SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 1 C . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Field test soil sample not submitted to laboratory due to no detectable results during test kit analysis. Log of Soil Boring GP-01C (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 3.5/2.8 DESCRIPTION Sample Field test sample collected; not submitted to lab (1) Field test sample submitted for laboratory analysis Duplicate soil sample not submitted for laboratory analysis 0-3.1' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none, trace white mottled HCl strong 3.1-3.5' Sandstone, pink (5YR 7/3), very fine- to fine-grained sand, dense, dry, HCl medium to strong Total depth of boring 3.5' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 2 C . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Field test soil sample not submitted to laboratory due to no detectable results during test kit analysis. Log of Soil Boring GP-02C (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 2.7/2.7 DESCRIPTION Sample Interval Description Field test soil sample collected; not submitted to lab (1) Field test soil sample submitted for laboratory analysis Duplicate soil sample not submitted for laboratory analysis 0-2.3' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl strong 2.3-2.7' Sandstone, brownish yellow (10YR 6/6), very fine- to fine-grained sand, poorly graded, loose to dense, dry, subangular to subrounded, HCl none Total depth of boring 2.7' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 3 C . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Field test soil sample not submitted to laboratory due to no detectable results during test kit analysis. Log of Soil Boring GP-03C (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/2.8 2.6/2.7 DESCRIPTION Sample Interval Description Field test soil sample collected; not submitted to lab (1) Field test soil sample submitted for laboratory analysis Duplicate soil sample submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none 4.0-5.4' Silty SAND, pink (5YR 7/4), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, trace fine sand, HCl medium to strong, white mottling w/ HCl strong 5.4-6.6' Sandstone, light brown gray (10YR 6/2), very fine- to fine-grained sand, loose to dense, dry, HCl none to weak, subangular to subrounded Total depth of boring 6.6' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 4 C . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Field test soil sample not submitted to laboratory due to no detectable results during test kit analysis. Log of Soil Boring GP-04C (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.3 1.5/1.7 DESCRIPTION Sample Interval Description Field test soil sample collected; not submitted to lab (1) Field test soil sample submitted for laboratory analysis Duplicate soil sample not submitted for laboratory analysis 0-5.1' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none, trace white mottling w/ HCl strong, roots at top Total depth of boring 5.1' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 5 C . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Field test soil sample not submitted to laboratory due to no detectable results during test kit analysis. Log of Soil Boring GP-05C (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.6 DESCRIPTION Sample Interval Description Field test soil sample collected; not submitted to lab (1) Field test soil sample submitted for laboratory analysis Duplicate soil sample not submitted for laboratory analysis 0-4.0' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose, dry, HCl none, trace white mottling w/ HCl strong Total depth of boring 4.0' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 6 C . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Field test soil sample not submitted to laboratory due to no detectable results during test kit analysis. Log of Soil Boring GP-06C (Page 1 of 1) Date/Time Started : 05/19/11 Date/Time Completed : 05/19/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.4 1.6/1.7 DESCRIPTION Sample Interval Description Field test soil sample collected; not submitted to lab (1) Field test soil sample submitted for laboratory analysis Duplicate soil sample not submitted for laboratory analysis 0-4.4' Silty SAND, yellowish red (5YR 4/6), very fine-grained sand, silt, poorly graded, loose to medium dense, dry, HCl none to strong, some white mottling w/ HCl strong 3.2-4.4' bgs 4.4-4.9' Silty SAND, pink (5YR 7/4), very fine-grained sand, silt, poorly graded, loose to medium dense, HCl strong, trace fine sand 4.9-5.6' Rock fragments, white, HCl none, very fine grained Total depth of boring 5.6' bgs (refusal) US C S SM GR A P H I C 07 - 2 8 - 2 0 1 1 S : \ P r o j e c t s \ B o r e L o g s \ D e n i s o n \ G P - 0 7 C . b o r White Mesa Mill, Blanding, Utah Denison Nitrate Investigation Project Name: Project #: DENMC.C002.000 Note(s): 1. Field test soil sample not submitted to laboratory due to no detectable results during test kit analysis. Log of Soil Boring GP-07C (Page 1 of 1) Date/Time Started : 05/18/11 Date/Time Completed : 05/18/11 Drilling Method : Geoprobe Sampling Method : Continuous Dual Tube Drilling Co./Driller : Earth Worx Driller : L. Trujillo Depth to Water : NA Logged by : J. Reed Depth in Feet 0 5 10 Sa m p l e I n t e r v a l Pe n . / R e c . ( f e e t ) 4.0/3.2 2.1/2.1 DESCRIPTION Sample Interval Description Field test soil sample collected; not submitted to lab (1) Field test soil sample submitted for laboratory analysis Duplicate soil sample not submitted for laboratory analysis 0-1.5' Sandy Clayey SILT, reddish brown (5YR 4/4), very fine-grained sand, medium stiff, dry to moist, cohesive, HCl none 1.5-1.7' CLAY, dark red brown (5YR 3/4), stiff, moist, medium plastic 1.7-4.9' Sandy SILT/Silty SAND, reddish brown (5YR 4/4), very fine-grained sand, silt, medium stiff/medium dense, slightly moist to moist, trace clay (cohesive), trace fine sand, HCl none to weak, trace white mottling at 2.5' bgs, little more sand or more silt 4.9-6.1' Silty SAND/SAND, brownish yellow (10YR 6/4), very fine- to fine-grained sand, silt (varying amounts), medium dense, slightly moist, trace medium sand, slightly cohesive, HCl none, little iron stained Total depth of boring 6.1' bgs (refusal) US C S ML CL ML/SM SM/SP GR A P H I C APPENDIX D HISTORIC WATER LEVEL MAPS (SEEP AND SPRING ELEVATIONS NOT CONSIDERED IN CONTOURING) D.1 D.2 D.3 APPENDIX E TOPOGRAPHIC AND GEOLOGIC MAPS ! ! ! ! ! ! ! CORRAL CANYON 5624 CORRAL SPRINGS 5383 COTTONWOOD 5234 ENTRANCE SPRING 5560 FROG POND 5590 RUIN SPRING 5380 WESTWATER 5468 Approved Date Author Date File Name Figure HYDRO GEO CHEM, INC. SEEPS AND SPRINGS ON USGS TOPOGRAPHIC BASE WHITE MESA 7180002G09/17/10SJS 707/16/10DRS 0.5 0 0.5 10.25 Mile Cell No. 1 Cell No. 3 Cell No. 2 Cell No. 4A NK:\718000\GIS\7180002G.mxd: Friday, September 17, 2010 1:02:59 PM Cell No. 4B WESTWATER 5468 Seep or Spring Elevation (feet) above mean sea level 0.5 10 Mile E E E E E E E Cell No. 1 Cell No. 2 Cell No. 3 Cell No. 4A Qh Qlbb Qlbb Qlbb Kdb Kdb Kdb Kdb Kdb Kdb Jmb Jmb Jmb Jmb Jmb Jmb Qea Qea Qea Qea Qa Qa Qa Qa Qa Kdb Kdb Jmb Qa Cell No. 4B Jmw Jmr Qh Qea Jmr Jmw Kdb Jmb Kdb Kdb CORRAL CANYON CORRAL SPRINGS COTTONWOOD ENTRANCE SPRING FROG POND RUIN SPRING WESTWATER GEOLOGIC MAP WHITE MESA, UTAH SJSÒApproved Date File Figure HYDRO GEO CHEM, INC.12/28/11 Geological Map of the Blanding Area, San Juan County, Utah (modified from Haynes et al., 1962; Dames & Moore, 1978 and Kirby, 2008) Base Map Prepared from Portions of the Blanding South, Black Mesa Butte, Big Bench and No Mans Land U.S.G.S. 7.5' Quadrangles. K:\718000\GIS\Geology E.2 Contact - dashed where uncertain E Seep or Spring EXPLANATION Tailing Cell Artificial cut and fill Stream alluvium Slumps and landslides, Brushy Basin Mixed eolian and alluvial deposits Dakota and Burro Canyon Formations (undivided) Brushy Basin Member of the Morrison Formation Westwater Canyon Member of the Morrison Formation Recapture Member of the Morrison Formation QhQhQhQh QaQaQaQa QlbbQlbbQlbbQlbb QeaQeaQeaQea KdbKdbKdbKdb JmbJmbJmbJmb JmwJmwJmwJmw JmrJmrJmrJmr APPENDIX F HYDROGEOLOGY BENEATH PROPOSED CELLS 5A AND 5B AND PROPOSED NEW MONITORING INSTALLATIONS F.1 Appendix F: H:\718000\Hydrpt2022\Report\Appf\Cellsa5b_Final.Docx HYDROGEOLOGY OF THE AREA NEAR PROPOSED CELLS 5A AND 5B AND RECOMMENDED LOCATIONS OF NEW PERCHED MONITORING WELLS The hydrogeology of the portion of the site beneath proposed cells 5A and 5B, the recommended placement of new perched groundwater monitoring wells, and the rationale for the recommended placement and spacing of wells is discussed in the following Sections. Hydrogeology Figure F.1 is a fourth quarter, 2022 perched groundwater level contour map showing the locations of hydrogeologic cross-sections in the vicinity of proposed new cells 5A and 5B. Cross section WNW-ESE (Figure F.2) extends from piezometer DR-7 (to the west of proposed cell 5A), along the upgradient (northern) dikes of proposed cells 5A and 5B, to MW-17, located on the east dike of proposed cell 5B. Cross section W2-E2 (Figure F.3) extends from piezometer DR-8 (to the west of proposed cell 5A), beneath the southwest corner of proposed cell 5A, to MW-17 on the east dike of proposed cell 5B. The hydrogeology depicted on cross-sections in Figures F.2 and F.3 is similar to the hydrogeology beneath the existing tailings management system (TMS) at the site. Alluvium is underlain locally by Mancos Shale. The alluvium (and Mancos where present) is (are) underlain by Dakota Sandstone and Burro Canyon Formation. Both are sandstones that are often not readily distinguishable in the field and are not separately defined on the cross sections. The Burro Canyon Formation is underlain by the Brushy Basin Member of the Morrison Formation. The Brushy Basin Member, a bentonitic shale, functions as an aquiclude supporting the perched groundwater system. The Dakota Sandstone and Burro Canyon Formations locally contain relatively thin, sub- horizontal, interbedded shale and conglomerate horizons that are often discontinuous between boreholes. Although the lithology shown for MW-17 is more general (due to the less-detailed nature of the log for the boring), shale and ‘conglomeratic’ horizons within the Burro Canyon and Dakota are described in the log (Appendix A [main report]). Detailed logs showing variations in the lithology of the Dakota and Burro Canyon for MW-14 and MW-15 are unavailable. Figures F.2 and F.3 show that perched groundwater saturated thicknesses vary from negligible at MW-33 (a consistently dry well located at the northwest corner of proposed cell 5A) to approximately 33 feet at MW-17 (located on the east dike of proposed cell 5B). Figure F.1 shows that a dry area extends from beneath cell 4B under the northwest portion of proposed cell 5A. F.2 Appendix F: H:\718000\Hydrpt2022\Report\Appf\Cellsa5b_Final.Docx Figure F.1 also shows that perched groundwater flow beneath the proposed cells is generally to the south-southwest, towards perched groundwater discharge point Ruin Spring. As discussed in Section 3.1.2 of the main text, porosity within the Dakota Sandstone and Burro Canyon Formation is primarily intergranular, and no significant joints or fractures have been documented in any wells or borings installed across the site (Knight-Piésold, 1998). Any fractures observed in cores collected from site borings are typically cemented, showing no open space. The Knight-Piésold findings are consistent with the evaluation of a 1994 drilling program provided in HGC (2001a) and with examination of drill core samples collected during installation of MW-3A, MW-23, MW-24, MW-28, MW-30, and TW4-22 in 2005 (HGC, 2005). The installation of proposed cells 5A and 5B will extend the TMS farther downgradient; the southern (downgradient) boundary will be closer to perched water discharge point Ruin Spring. However, as noted in Section 2.1.3 of the main text, hydraulic conductivities and perched water migration rates to the southwest of the TMS (between the TMS and Ruin Spring) are among the lowest at the site. Figure F.4 depicts inferred perched groundwater flow pathlines downgradient of the existing TMS, and beneath and downgradient of proposed cells 5A and 5B. Figure F.5 depicts the shortest pathline from the downgradient (southern) dikes of proposed cells 5A and 5B to the nearest discharge point, Ruin Spring. The length of this pathline is approximately 8,550 feet. Using an average hydraulic conductivity of 14.1 ft/yr (as calculated for Path 6 in Figure 27 of the main text), the Figure F.5 path length of 8,550 feet, an average hydraulic gradient of 0.0125 ft/ft (between DR-13 and Ruin Spring), and a porosity of 0.18, the estimated average groundwater pore velocity is approximately 0.98 ft/yr. The estimated time for perched groundwater to travel from the downgradient edge of proposed cells 5A and 5B to Ruin Spring is therefore approximately 8,720 years. Recommended Well Locations Seven new perched groundwater monitoring wells (MW-42 through MW-48; and one new piezometer, DR-26; as shown in Figure F.6) are proposed to monitor proposed cells 5A and 5B. Cell 5A and associated groundwater monitoring wells are to be installed first. Therefore, proposed groundwater monitoring wells MW-42 through MW-45; and piezometer DR-26; would be installed as part of the construction of cell 5A. MW-46 through MW-48 would be installed later as part of the construction of cell 5B. Proposed wells MW-42 through MW-45; and piezometer DR-26; are considered adequate to monitor proposed cell 5A even if the construction of cell 5B is delayed indefinitely. F.3 Appendix F: H:\718000\Hydrpt2022\Report\Appf\Cellsa5b_Final.Docx As discussed in HGC (2018) these proposed wells will be located far down- to cross-gradient of the nitrate plume (shown on Figure F.6 and discussed in the main text) and will provide additional information regarding groundwater conditions (saturated thicknesses and flow directions) in the downgradient area. MW-42 through MW-48 will provide an additional ‘line of defense’ of wells to augment the two east-west lines of wells that are currently located down- to cross-gradient of the nitrate plume. The current lines of wells include: MW-5, MW-11, MW12, MW-23 and MW-25, along the downgradient margin of cell 3; and MW-14, MW-15, MW-34, MW-35, MW-36 and MW-37, along the downgradient margin(s) of cells 4A and 4B In addition, existing wells MW-17 and MW-38 are located cross-gradient and far cross-gradient of the nitrate plume; and MW-3A and MW-20 are located far downgradient of the nitrate plume. Due to the location of proposed cell 5A above and near the structural high in the Brushy Basin Member surface, three of the proposed wells (MW-42, MW-43 and MW-44) are (unavoidably) expected to have relatively small saturated thicknesses, although MW-43 and MW-44 are likely to have saturated thicknesses of at least 5 feet or greater. As its proposed position is likely near the crest of the structural high, piezometer DR-26 is expected to be dry. Narrow-diameter pilot borings are proposed to be installed to ensure adequate saturated thicknesses within the proposed monitoring wells (with the exception of piezometer DR-26). Should the saturated thickness within a pilot boring be inadequate (less than 5 feet), the boring (with the concurrence of DWMRC) will either be converted to a piezometer or abandoned. A new pilot boring will be installed within approximately 100 feet in a direction along the cell margin likely to have adequate saturated thickness. Pilot borings having saturated thicknesses of 5 feet or greater will be reamed and completed as monitoring wells. The spacing of the five wells (MW-43 through MW-47) along the southern (downgradient) dikes of the proposed cells is similar to the spacing of existing wells along the southern (downgradient) dikes of cells 4A and 4B. Proposed well MW-42 and piezometer DR-26 along the west dike of proposed cell 5A are generally cross-gradient with respect to groundwater flow; and existing well MW-17 and proposed well MW-48 along the east dike of proposed cell 5B are generally up- to cross-gradient with respect to groundwater flow. F.4 Appendix F: H:\718000\Hydrpt2022\Report\Appf\Cellsa5b_Final.Docx The spacing of the proposed wells (approximately 750 ft or closer) is conservative with regard to reliable detection of potential future impacts to groundwater that may arise from any future seepage from the proposed cells. As discussed in HGC (2001b), numerical simulations of hypothetical ‘point’ source ‘leaks’ from the existing TMS indicate that such leaks could be reliably detected using well spacings of between 850 and 900 ft. However, the advanced design and leak detection systems that are to be incorporated in the construction of the proposed cells makes it highly unlikely that any potential future seepage could bypass the leak detection systems to an extent that could impact groundwater. The proposed well spacing is likely overly conservative considering that the cell design includes multiple liners with a leak detection system installed between the liners. Simulations of hypothetical ‘leaks’ presented in HGC (2001b) assumed a relatively conservative 10:1 ratio of horizontal to vertical permeability within vadose materials (unsaturated Dakota Sandstone and Burro Canyon Formation) underlying the TMS at the site. In reality, the effective ratio of horizontal to vertical permeability is likely to be larger than 10:1, making the resulting potential for lateral spreading, and the reliability of the monitoring well network, greater than was simulated. A large ratio of horizontal to vertical permeability is likely to exist due to the sub- horizontal layering that is present in both the Dakota Sandstone and Burro Canyon Formation. The conclusions based on the HGC (2001b) simulations were confirmed by more recent numerical modeling of the adequacy of well spacing provided in HGC (2019). These simulations assumed ‘worst-case’ conditions and were based on conservative assumptions that included the same 10:1 ratio of horizontal to vertical permeability. Simulations assumed hypothetical ‘point’ source ‘leaks’ of 0.1 and 1 gallons per minute (gpm) at locations halfway between proposed wells MW-45 and MW-46; and halfway between proposed wells MW-46 and MW-47. Any such ‘leaks’ would be the most difficult to detect because they would occur at the downgradient edge of the proposed cells at the maximum distance from the two nearest wells. Because of the nearest wells’ position along the downgradient edge of the TMS, these wells would be mainly cross- gradient of the hypothetical ‘leak’. In all simulated cases, assuming worst-case conditions, potential impacts are predicted to spread sufficiently cross-gradient to allow timely detection using the proposed well spacing. The proposed well spacing was concluded to be more than adequate to detect both changes in concentration and saturated thicknesses resulting from these hypothetical ‘leaks’. Specifically, simulation results indicated that impacts to groundwater would be detected by wells proposed along the southern margins of cells 5A and 5B more than 100 years before they would be detected at the next closest downgradient well MW-3A. Under conditions assuming a F.5 Appendix F: H:\718000\Hydrpt2022\Report\Appf\Cellsa5b_Final.Docx hypothetical 1 gpm ‘leak’, impacts would be detected along the cell margin in less than 50 years; and under conditions assuming a hypothetical 0.1 gpm ‘leak’, within 100 to 200 years. In addition, interbedded sub-horizontal shale and/or coarse-grained (conglomeratic) horizons that exist beneath proposed cells 5A and 5B (Figures F.2 and F.3) are both likely to enhance lateral spreading of any future seepage that may potentially originate from the proposed cells. Such lateral spreading would increase the area of perched groundwater impacted by any potential future seepage and thus reduce the number of wells needed for reliable detection. Sub-horizontal shale horizons are expected to have low vertical permeability (and therefore low vertical hydraulic conductivity). Any seepage percolating vertically downward that encountered a shale horizon would be likely to perch, then spread laterally. Lateral spreading would continue until the perched area was large enough that seepage through the low-permeability shale became equal to the incoming seepage rate. The footprint of seepage through the base of the shale horizon would thus be larger than the footprint of incoming seepage above the shale horizon. Sub-horizontal coarse-grained (conglomeratic) horizons at the site may have either relatively high or relatively low permeability depending on the degree of cementation. HGC (2010a and 2010b) summarize the lithology and hydraulic testing of angle borings GH-94-1 and GH-94-2A (angled beneath cell 3, as described in HGC, 2001a). The majority of the hydraulic tests within these angle borings were conducted within the vadose zone and are considered generally representative of vadose conditions beneath the TMS. The test results discussed in HGC (2010a and 2010b) indicate the following: Horizontal hydraulic conductivities of the Dakota Sandstone ranged from 5.9 x 10-6 centimeters per second (cm/s) to 8.8 x 10-5 cm/s; horizontal hydraulic conductivities of the underlying Burro Canyon Formation ranged from 4 x 10-5 cm/s to 6.3 x 10-4 cm/s. Less than half of the higher conductivities occurred in conglomeratic materials, with three of the tests conducted in conglomeratic material yielding conductivity estimates less than 10- 5 cm/s. Only one test yielded a conductivity estimate greater than 10-5 cm/s. The available (pre-2010) borehole data near cell 4B indicate poor correlation between conglomeratic intervals and enhanced permeability. Only one (possibly two) reported zone(s) of higher permeability within conglomeratic materials exist(s) near the saturated portion of the Burro Canyon Formation. Cross-gradient to up-gradient (east to northeast) of the TMS, in the vicinity of the chloroform plume, conglomeratic materials within the deep saturated Burro Canyon Formation appear to be associated with higher permeability, at least in the vicinity of MW-4 (within the chloroform plume). However, available data from the vicinity of cell 4B do not indicate a consistent association between conglomeratic materials and higher permeability in the vadose zone. Overall, vadose conglomeratic intervals do not consistently have higher hydraulic conductivities (or permeabilities) than the surrounding sandstones. However, F.6 Appendix F: H:\718000\Hydrpt2022\Report\Appf\Cellsa5b_Final.Docx conglomeratic intervals having higher conductivities than surrounding materials would likely spread any seepage laterally so that the seepage would contact a larger area of perched groundwater. With regard to lateral spreading, potential seepage encountering a relatively high permeability, sub-horizontal conglomeratic horizon is expected to spread laterally as a result of two factors: 1) the conglomeratic material would likely behave as a capillary barrier; and 2) the relatively high lateral permeability of the conglomeratic material would facilitate lateral spreading of any seepage percolating into the material. First, as a capillary barrier, a relatively high permeability conglomeratic material would prevent infiltration of seepage from finer-grained, lower-permeability, overlying materials until near- saturated conditions were reached in the overlying material above the contact. As saturations build up within the overlying materials, the potential for lateral spreading increases. Second, any seepage percolating into a relatively high permeability conglomeratic horizon would tend to perch on the underlying lower permeability materials, causing lateral spreading within the conglomeratic horizon, and increasing the area of the underlying materials impacted by the continuing downward percolation of the seepage. Overall, the vertical heterogeneity encountered beneath proposed cells 5A and 5B is expected to enhance the likelihood for timely detection of any groundwater impacts from any potential future seepage originating from the cells. Furthermore, as discussed above, improvements in cell design since installation of cells 1 through 3 at the site make it highly unlikely that any potential future seepage could bypass the leak detection systems incorporated in proposed cells 5A and 5B to an extent that could impact groundwater. F.7 Appendix F: H:\718000\Hydrpt2022\Report\Appf\Cellsa5b_Final.Docx References HGC. 2001a. Letter to Mr. Harold Roberts, International Uranium Corporation (Regarding the Review of the 1994 Drilling Program). June 21, 2001. HGC. 2001b. Assessment of the Effectiveness of Using Existing Monitoring Wells for GWDP Detection Monitoring at the White Mesa Uranium Mill, Blanding, Utah. September 25, 2001. HGC. 2005. Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill, April through June 2005. August 3, 2005. HGC, 2018. Revised Phase III Nitrate Corrective Action Planning Document and Recommended Phase III Corrective Action. White Mesa Uranium Mill Near Blanding, Utah. December 13, 2018. HGC, 2019. Letter to Ms. Kathy Weinel Re: Numerical Transport Simulations to Support Proposed Cell 5A and 5B Well Spacing. March 7, 2019. Knight-Piésold. 1998. Evaluation of Potential for Tailings Cell Discharge – White Mesa Mill. Attachment 5, Groundwater Information Report, White Mesa Uranium Mill, Blanding, Utah. Submitted to UDEQ. APPENDIX F FIGURES HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl H:/718000/hyrpt2022/ report/AppF/Uwl1221c5a5b.srf MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 saturated thickness estimated to be less than 5 feet 5500 4th quarter 2021 water level contour and label in feet amsl SJS PROPOSED CELLS 5A AND 5B (showing kriged Q4 2021 perched water levels and cross sections in proposed cell area) WHITE MESA SITE F.1 APPROVED DATE REFERENCE FIGURE HYDRO GEO CHEM, INC. EXPLANATION Qal/Fill Km Kdbc Jmbb Mancos Shale Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Piezometric surface vertical exaggeration = 5:1 Shale/Shaly Sandstone within Dakota/Burro Canyon Conglomerate within Dakota/Burro Canyon INTERPRETIVE EAST-WEST CROSS SECTION (WNW - ESE) SOUTHWEST INVESTIGATION AREA H:/718000/hydrpt2022/ report/AppF/wnwesexssw.srf * = detailed log unavailable Conglomeratic Dakota Sandstone/ Burro Canyon Formation SJS 5450 5475 5500 5525 5550 5575 5600 5625 5650 5675 el e v a t i o n ( f e e t a m s l ) DR - 7 MW - 3 6 MW - 3 3 MW - 3 4 MW - 3 7 MW - 1 5 * MW - 1 4 * MW - 1 7 Qal/Fill Qal/FillKm Kdbc Kdbc Jmbb WNW ESE proposed cell 5A proposed cell 5B F.2 Alluvium/Fill/ Weathered Mancos APPROVED DATE REFERENCE FIGURE HYDRO GEO CHEM, INC. EXPLANATION Qal/Fill Km Kdbc Jmbb Alluvium/Fill Mancos Shale Dakota Sandstone/ Burro Canyon Formation Brushy Basin Member of Morrison Formation Piezometric surface vertical exaggeration = 15:1 Shale/Shaly Sandstone within Dakota/Burro Canyon Conglomerate within Dakota/Burro Canyon INTERPRETIVE EAST-WEST CROSS SECTION (W2 - E2) PROPOSED CELL 5A/5B AREA Conglomeratic Dakota Sandstone/ Burro Canyon Formation SJS 0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 distance (feet) 5450 5475 5500 5525 5550 5575 5600 5625 el e v a t i o n ( f e e t a m s l ) DR - 8 DR - 9 DR - 1 0 DR - 1 1 DR - 1 2 DR - 1 3 MW - 1 7 Qal Km Km Kdbc Kdbc Jmbb Jmbb W2 E2 proposed Cell 5A proposed Cell 5B F.3 H:/718000/hydrpt2022/ report/AppF/e2w2xssw.srf HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 F.4 estimated area having saturated thickness less than 5 feet estimated perched water flow path SJS H:/718000/hydrpt2022/ report/AppF/Uwl1221c5a5b_path.srf PROPOSED LOCATIONS OF CELLS 5A AND 5B (showing kriged Q4 2021 perched water levels and inferred perched water flow paths downgradient of the tailings management system) HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl seep or spring showing elevation in feet amsl MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl TW4-12 TWN-7 5504 5569 5569 5588 5380 5463 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021showing elevation in feet amsl 5524 temporary perched monitoring well installed September, 2021 showing elevation in feet amsl TW4-43 TWN-20 F.5 estimated area having saturated thickness less than 5 feet SJS H:/718000/hydrpt2022/ report/AppF/Uwl1221c5a5b_path6B.srf PROPOSED LOCATIONS OF CELLS 5A AND 5B (showing kriged Q4 2021 perched water levels and inferred perched water flow paths downgradient of the tailings management system) estimated shortest perched water flow path to nearest discharge point HYDRO GEO CHEM, INC. EXPLANATION perched monitoring well perched piezometer seep or spring MW-5 PIEZ-1 RUIN SPRING temporary perched monitoring well temporary perched nitrate monitoring well TW4-12 TWN-7 MW-38 TW4-42 temporary perched nitrate monitoring well installed April, 2021 temporary perched monitoring well installed September, 2021 TW4-43 TWN-20 saturated thickness estimated to be less than 5 feet 5500 4th quarter 2021 water level contour and label in feet amsl PROPOSED NEW CELL 5A AND 5B MONITORING WELLS AND PIEZOMETER WHITE MESA SITE H:/718000/hydrpt2022/ report/AppF/UwlPropWellC5_r1.srf F.6SJS MW-42 DR-26