Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
DRC-2021-005522 - 0901a06880e6d3f1
Radioactive Material License Application / Federal Cell Facility Page D-1 Appendix D April 9, 2021 Revision 0 APPENDIX D PHASE 1 BASAL-DEPTH STUDY REPORT AND 2021 INTERROGATORY RESPONSES Radioactive Material License Application / Federal Cell Facility Page D-2 Appendix D April 9, 2021 Revision 0 Phase 1 - Final Basal-Depth Aquifer Study Report and Responses to Round 2 Interrogatories In response to a letter dated July 29, 2019 (Verbica, 2019), Phase 1 of the Basal Depth Aquifer Study Plan (EnergySolutions, 2019 and Stantec, 2019) was developed to enhance understand the hydrogeologic and geologic characteristics of the basal-depth aquifer at the proposed location for the Federal Cell Facility (Facility). The hydrogeologic conditions of the first 100 feet below the Facility have already been well characterized since the U.S. Department of Energy VITRO Chemical Company project and original Envirocare of Utah licensing actions (Bingham Environmental, 1991 and Department of Energy [DOE] 1984a, 1984b). In addition, EnergySolutions’ subsequent licensing and permitting activities have further characterized the subsurface beneath the Facility. These previous activities, coupled with long-term monitoring of the shallow, unconfined aquifer, have extensively captured the hydrogeologic conditions in the first 100 feet below ground surface (bgs). Based on the understanding of the hydrogeologic conditions in the first 100 feet, DOE and EnergySolutions expect the conceptual model of the Facility to include similar stratigraphy below that first 100 feet. EnergySolutions was tasked by the Director of the Utah Division of Waste Management and Radiation Control (Director) to validate this hydrogeologic conceptual model down to basal depths (i.e., log the subsurface geology/stratigraphy and characterize the deep aquifer) through the installation and sampling of a basal depth well. Data collected from Phase 1 of the Study are used to understand the characteristics of the subsurface hydrogeology at depths exceeding 100 feet bgs (as reported in Stantec (2020); which was separately submitted to the Director via Rogers (2020) and hereto attached as Exhibit 2 to Appendix D). EnergySolutions hereby responds to interrogatories received on January 15, 2021 from the Director of the Division of Waste Management and Radiation Control (Willoughby, 2021). Supplemental interrogatory responses prepared by Stantec Consulting Services (Stantec, 2021) are hereto attached as Exhibit 1 to Appendix D. • Interrogatory #1 The Division requested information from EnergySolutions about basal aquifers at the Facility and other hydrogeological information at depth not previously provided. The Division acknowledges the careful field and laboratory work and the useful information that EnergySolutions has provided to the Division through this study. However, the Division has comments and questions regarding some of the information and interpretations of the data. These questions should be considered in the context of the following list of rules: UAC R313-25-8(1), UAC R313-35-9(4)(a), UAC R313-25-15(1)(a), UAC R313-25-3(6), UAC R313- 25-24(2) and (7), and UAC R313-25-27(1). Regarding the quoted paragraph above, please indicate which of the Division Director’s requirements, as outlined in the listed rules and as specifically requested by the Director and referenced in the study Plan, have already been met, and which requirements still need to be met, and explain why. Response Summary: In the letter dated July 29, 2019 (Verbica, 2019), the Director provided a “… description of the data objectives the Division expects to be met through EnergySolutions’ assessment and characterization of the basal aquifer at the Clive facility.” The Director emphasized the importance of the study by noting that “… a study of the unconsolidated basal Radioactive Material License Application / Federal Cell Facility Page D-3 Appendix D April 9, 2021 Revision 0 aquifer system is required as part of the DUPA. In addition, a basal aquifer assessment and characterization is required by Condition 11.4 of the 11e(2) license [which has been licensed and in operation for more than 20 years]. It is also a necessary component for evaluation of the pending LLRW license renewal [which also has been licensed and in operation for more than 20 years].” Rather than to address the Utah Administrative Code rules cited in the Division’s Request for Information, Phase 1 of EnergySolutions Basal Study Plan (submitted via CD19- 0185, CD19-0224, CD19-0227 and CD20-0004 and approved by the Director on December 10, 2019) was specifically prepared in response to the data quality objectives required in the Director’s July 29, 2019 letter. “The Director’s letters include a list of basal-depth groundwater characteristics of interest to the Division (see Table 1). Even with the uncertainty associated with a Proof of Process, Phase 1 has been designed to be understand these characteristics of the basal-depth aquifer.” (Rogers, 2020). In preparing a Study Plan that addressed the Director’s 2019 requirements and following that Plan in preparation of the Study Report, EnergySolutions has supplied the information requested. The latest Request’s new reference to Utah regulatory rules were not identified in the Director’s data quality objectives nor are they commonly required by other holders of Utah’s Groundwater Quality Discharge Permits (Eyzaguirre, 2021). • Interrogatory #2 The Division does not see in the Report the following information requested from EnergySolutions and found in the Plan (item numbering retained for ease of reference to the above list): (1) Depth of bedrock geophysical survey (3) Top and bottom depth of each aquifer and aquitard (one or more aquifers not described) (6) Horizontal gradient(s) (not possible in this phase since all wells had similar x-y coordinates) (7) Vertical gradient(s) (the Division has concerns with some calculations made in the Report) (8) Horizontal hydraulic conductivity (the Division has concerns about calculations in the Report) (11) Groundwater age dating (12) Distribution coefficients/retardation factors Please (i) provide an update on plans to obtain this missing information and subsequently report it to the Division, or (ii) justify the absence of the missing information despite having indicated previously in the Plan that EnergySolutions would obtain and report this information. Response Summary: Stantec’s Report specifically identifies the purpose of the Phase 1 Study as “Data collected from Phase 1 of the Study are used to understand the characteristics of the subsurface hydrogeology at depths exceeding 100 feet bgs and inform Radioactive Material License Application / Federal Cell Facility Page D-4 Appendix D April 9, 2021 Revision 0 EnergySolutions and DWMRC if development of subsequent Study phases are warranted.” (Stantec, 2020; pg 1.1) In their Report, Stantec concludes contaminant transport downward into basal depths of the aquifer underlying the Clive Facility is highly unlikely. “These results indicate limited connectivity between the shallow zones and the deeper basal aquifer at the Facility. Given the upward component of groundwater flow, vertical heterogeneity with aquifer zones separated by an aquitard and a semi-confined aquifer underlain by a thick aquitard, low vertical hydraulic conductivity and observed dryness of the aquitard zones, and the lack of response in the 30 and 50 foot deep observation wells during the aquifer test, hydraulic communication from the shallow zones to the deeper basal aquifer under natural conditions is unlikely.” (Stantec, 2020; pg 4.1) Even with Stantec’s finding of negligible downward transport communication between upper and basal-depth aquifers, EnergySolutions restates it’s offer included with Report, “EnergySolutions welcomes the opportunity to consider through collaboration with the Director, benefits from further field studies and analysis.” (Rogers, 2020). • Interrogatory #3 The Division asks the following questions: 3.1 Neptune’s conceptual model (Neptune, 2015b) describes two aquifers existing in the depth range below 25 ft and above 275 ft bgs: (i) an unconfined aquifer that extends from the water table down to a total depth of only about 40 to 45 ft bgs, and (ii) a deeper confined aquifer extending downwards from about 45 ft bgs. The presence of the confined aquifer also implies a thin aquitard existing directly above it. Neptune’s conceptual model is also provided in Bingham Environmental (1991). Stantec (2020b), on the other hand, describes a single, undifferentiated unconfined aquifer extending from the water table down to a depth of about 275 feet. For depths down to 275 ft bgs, which conceptual model, if either, appears to be correct? Please provide justification for your answer. 3.2 Neptune’s conceptual model (Neptune, 2015b) describes a single deep aquifer at depths beyond 275 ft bgs. Stantec (2020b) describes two aquitards, as well as a leaky aquifer, in this depth range. Which description is correct? 3.3 Please represent the correct types and locations of all aquifers and aquitards in a revised Figure 3 for the Report. Response Summary: Stantec was commissioned to conduct the Phase 1 Study (Rogers, 2019) that specifically focuses on a selection of the data quality objectives from the Director’s July 29, 2019 letter (Verbica, 2019). EnergySolutions required Stantec’s efforts to focus on observations, analysis and conclusions related to the new basal-depth well I-1-700 that was constructed in 2019. As such, Stantec was not commissioned to evaluate any analysis conducted by Neptune Radioactive Material License Application / Federal Cell Facility Page D-5 Appendix D April 9, 2021 Revision 0 nor have they access to any source material on which Neptune based their analysis. In Figure 3 of Report (based on data and analysis from Well I-1-700), Stantec affirms that it accurately “:…illustrates the aquifer stratification based on the screened intervals and lithology boring.” The analyses presented by Stantec are from physical observations of the boring, not conceptual modeling. No further correction or revision is warranted. • Interrogatory #4 The Division has the following questions: 4.1 Stantec (2020b) indicates that it calculated “mid-points of saturated zone elevations”, as are found in the last column of Table 3-3, but it is uncertain as to what that implies relative to the calculations. All the calculations for hydraulic gradient in Table 3-4 appear to have been done differently, using instead the freshwater mid-screen interval, corrected for buoyancy. Please clarify what was done for what purpose and justify why. 4.2 The text refers to mid-points of the saturated zone elevations, whereas Table 3-3 gives the mid-points of the filter pack elevations as well as the mid-points of the saturated zone elevations, and the calculations in Table 3-4 are based on the mid- screen elevations. Why? The elevations of the mid-points of the saturated zone, mid- points of the filter packs, and mid-points of the screen for each well are all different. So are derivatives of each these quantities. 4.3 Based on the results of calculations shown in Table 3-4, it appears that some part of each range of what are called the buoyancy-corrected vertical gradients associated with the shallow aquifer well (I-1-30) indicate downward flow to any of the wells in what Neptune (2015) has called the deep aquifer (i.e., I-1-50, I-1-100, and I-1-700). This is because some part of each range has negative values, which, according to the Stantec (2020b) sign convention, represents downward flow. Is this also how EnergySolutions interprets this? Please justify your response. 4.4 Looking at Table 3-4, for the well pair I-1-30 and I-1-700, how does the sum of 0.041, the freshwater mid-screen gradient, and 0.040, the buoyancy correction, supposedly equal 0.002? The latter value is said in Stantec (2020b) to be the buoyancy-corrected mid-screen gradient. Calculations done by the Division indicate that this value, based on the mid-screen assumption for estimating the gradient, should be 0.001, not 0.002 (using the Stantec sign convention for the result). 4.5 What is the overall range of vertical gradients calculated for the well pair I-1-30 and I-1-700, when accounting for well geometry and water level elevations, as indicated in the last column of Table 3-4? Do the negative values given for some of these data combinations indicate (according to the Stantec convention) the possibility of downward flow? Please justify your response. 4.6 What is the overall calculated range of corrected vertical gradients for the well pair consisting of I-1-50 and I-1-100? Do the negative values given for each of these data combinations indicate (according to the Stantec convention) downward flow? Please justify your response. Radioactive Material License Application / Federal Cell Facility Page D-6 Appendix D April 9, 2021 Revision 0 4.7 The specific gravity for groundwater in the shallow aquifer is said in Table 3-3 to be 1.032. This value, based on a single measurement for groundwater in the shallow aquifer at a single point may not be representative of the entire aquifer. Neptune (2015), having examined data from many dozens of wells scattered across the Clive Facility, indicates that, for this facility, The geochemistry of the shallow, unconfined aquifer consists of very high levels of dissolved solutes as outlined above. . . . with TDS values ranging from 20 to 70 parts per thousand and specific gravity from 1.02 to 1.06 g/mL (Envirocare 2004, and recent site specific groundwater data acquired by EnergySolutions). This range of specific gravity for the shallow-aquifer groundwater, from 1.02 to 1.06, can be compared with the single value for shallow-aquifer groundwater specific gravity of 1.032 measured in the field recently and used in the Report, which would be more toward the bottom of the reported Neptune (2015) range. If a value of 1.060, at the upper end of the reported range, is instead used for illustrative purposes for groundwater in some areas of the shallow aquifer, then the groundwater density averaged between the basal aquifer and the shallow aquifer is equal to 1.054 g/cm3, the value of (ρa-ρf)/ρf is equal to 0.054, and a table using this higher specific gravity for the shallow-aquifer groundwater, when presented using the Division’s sign convention of this Interrogatory. All calculated flow directions here are downward. This is because the sign associated with qv, or vertical component of flow per unit area, is negative. If flow had been upward, the sign of qv would have been positive. But, in this case, all the values of qv are seen to have negative values. For shallow-aquifer groundwater in this reported specific-gravity range with values of specific gravity as low as a little more than 1.042, which is a little more than midway across the range given by Neptune (2015), the value of (ρa-ρf)/ρf is greater than 0.045. When this is the case, all calculated groundwater flow directions between these two wells are still downward, regardless of the value of |dhf/dz| chosen from the range given by Stantec (2020a) in the original Report. Despite uncertainty about density values and gradients, it is easy to see for the example above that the term (ρa-ρf)/ρf has a value that is nearly the same absolute magnitude as dhf/dz, but that it has an opposite sign. Accordingly, to determine flow direction, even for simple flow examined using an analytical model, it seems vital to understand both (i) the signs of these two terms and (ii) their values. Please look at density and specific gravity values found in Neptune (2015) and indicate based on this much-larger sample what fraction of the calculated flow-direction values would indicate upward flow, and what fraction would indicate downward flow for each specific-gravity value in the range for each aquifer. 4.8 There’s illustrative value in using the mathematical or analytical model as Stantec (2020b) has done, for it shows that, for a hypothetical hydrogeologically homogeneous system, calculations indicate that flow under certain conditions would Radioactive Material License Application / Federal Cell Facility Page D-7 Appendix D April 9, 2021 Revision 0 be downward at the site, based on considerations of relative density as well as freshwater head. It must be kept in mind, however, that all analytical models like the Post et al. (2007) model employed in the Basal Aquifer Study assume hydrogeological homogeneity (e.g., no aquitards between aquifers). Typically, a numerical model, as opposed to an analytical model, must be run for sites at which much heterogeneity exists to obtain viable results. Examples are SEAWAT and SUTRA by the USGS. Please justify, if possible, why it would be valid to do what Stantec (2020b) has done, i.e., apply an analytical model designed for homogeneous conditions to the heterogeneous site at Clive, where aquitards are known to exist between aquifers. 4.9 Although Stantec (2020b) says, “vertical hydraulic gradient estimates between I-1- 700 and the rest of the wells were all upward with buoyancy considered,” it is noted that, for the specific gravity for shallow-aquifer groundwater of 1.032, Table 3-4 shows that that situation was not the case. Table 3-4 shows that for the I-1-30 and I- 1-700 pair, the buoyancy corrected vertical gradient range varies from -0.002 to 0.005. The lower part of this range, i.e., from -0.002 to slightly below zero, represents downward flow, based on the Stantec (2020b) sign convention. Why is Stantec not using the values in the negative range? Please justify your answer. Response Summary: Stantec’s responses to Interrogatory 4 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #5 It appears that a direct hydraulic response had not propagated to Well I-1-50 (screened at a depth of about 50 ft bgs) by the time that the reverse water-level fluctuation in that well was noted. Based on the reference to Kim and Parizek (1997) that Stantec offers, it appears that only an apparent mechanical deformation response in the aquitard and the non-pumped aquifer at a depth of 50 ft bgs had occurred, yielding the observed reverse water-level fluctuation. Is this EnergySolutions’ interpretation, or does it offer an alternative possible interpretation? The reference made by Stantec (2020) to Kim and Parizek (1997) appears to the Division to be reasonable. If the direct hydraulic propagation had not reached up to 50 ft bgs by that time, then that would explain why, by that time, no direct hydraulic response had propagated to the even more-distant shallow aquifer screened by Well I-1-30 (screened at a depth of about 30 ft bgs). Well I-1-30 appears to be separated from Well I-1-50 by an aquitard or semi-confining layer. It seems logical to assume that an aquitard exists at a depth of about 45 ft bgs between those two wells, since Neptune (2015) says that, above that depth, there is an unconfined aquifer, and below that depth, there is a confined aquifer. For the latter to be confined, there must be an aquitard above it. Radioactive Material License Application / Federal Cell Facility Page D-8 Appendix D April 9, 2021 Revision 0 Does a lack of discernible drawdown response in Well I-1-30 throughout the pumping test show limited hydraulic connection between Well I-1-700 and Well I-1-30 over the duration of the pumping test or for all time? Please justify your response. Response Summary: Stantec’s responses to Interrogatory 5 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #6 What is the justification for assuming both in the implementation of the Cooper-Jacob (1946) method and in the implementation of the Theis (1935) method that the tested aquifer is 325 feet thick? Substantial evidence in the Report indicates that, instead of a single 325- foot-thick aquifer, the sediments screened in Well I-1-700 and Well I-1-100 respectively represent at least two distinct aquifers, each of much smaller saturated thickness, which are separated by a significantly thick aquitard. Field and laboratory observations and measurements support this conclusion. One line of evidence that a substantial aquitard lies between the two aquifers is based on field data. This apparent aquitard is shown in the Stantec Form to consist of 44.5 feet of sediments extending from 274.5-319.0 ft bgs. Based on this Soil Boring/Lithology Form, this apparent aquitard contains many dry zones. The descriptions in the Form note these dry zones occur specifically at 274.5-277 ft, 286.5-287 ft, 287-297 ft, 297-299 ft, 310-314.5 ft, and 314.5-319 ft bgs. Some of these zones are hard, dense or both. Soil from 289-297 ft bgs, for example, is said to be "very hard, dense, dry." From 314.5-319 ft bgs, soil is said in the Form to be "dense and dry." These data suggest that much of this interval (from 274.5-319 ft bgs) is relatively hard and/or dry, indicating that it would tend, on the whole, to act as an aquitard. Laboratory hydraulic-conductivity testing confirms this assessment. An “undisturbed sample. . . representative of aquitard material”, is how a sample sampled from 297.5-298.0 ft bgs is described in the Report. The Report describes this sample as being “reddish-brown clayey sand.” Table 3-2 of the Report indicates that the vertical component of hydraulic conductivity (Kv) measured in the lab for this sample is only 2.60 x 10-5 cm/s. That is a relatively small value, consistent with that of an aquitard. Experts in the field of well hydraulics indicate that the saturated thickness of a semi- confined aquifer like the aquifer screened by I-1-700 is simply the thickness of the aquifer material (located between a confined layer and an aquitard) that is saturated. For example, Boonstra and Soppe (2017) say, The saturated thickness is equal to the physical thickness of the aquifer between the aquicludes above and below it . . . The same is true for the confined parts of a leaky aquifer bounded by an aquitard and an aquiclude. . . the saturated thickness is a constant. In other words, the saturated thickness does not include any aquitard or aquiclude material. The saturated thickness thus does not include material in two separate aquifers, just in one. Neither does the saturated thickness depend on the height of the potentiometric surface. The saturated thickness for a semi-confined aquifer is thus a constant. Radioactive Material License Application / Federal Cell Facility Page D-9 Appendix D April 9, 2021 Revision 0 It appears to the Division that, for this site, employing for calculation purposes a saturated thickness of 36 feet, rather than 325 feet, is the only approach that makes sense. Using a saturated thickness of 325 feet instead of 36 feet would seemingly render the results of the analysis conducted by Stantec (2020b) inaccurate by a significant amount. The Division has previously addressed this. Is there a reason why EnergySolutions would continue to choose to conduct the analysis using a value of 325 feet? Please justify your answer. Response Summary: Stantec’s responses to Interrogatory 6 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #7 The Hantush (1960) method specifically requires data from an observation well, rather than from a pumping well, or a control well, to be employed. ASTM D6028, which describes how to analyze data using the modified Hantush (1960) method, directs users who would use it to “construct one or more observation wells or piezometers screened only in the pumped aquifer at a distance from the control well”. So, data for drawdown must come from one or more observation wells or piezometers located in the pumped aquifer some distance from the pumping or control well. While data obtained from groundwater levels measured in a pumping or control well may be of interest qualitatively, such data has limited or no quantitative significance in the Hantush (1960) method. There are several reasons, among which are those described in ASTM (2017). In a footnote in ASTM (2017), which references Moench (1985), it says, “data from the pumped well are affected by variations in the pumping rate, effects of well-bore storage, and the ‘skin’ (a zone around the well hydraulically different from the native materials because of disturbance and alteration caused by well drilling and construction).” These factors mean that drawdown data taken from the pumping well cannot be utilized directly in the Hantush (1960) method to arrive at accurate parameter-estimation results. Data from external observation wells must be employed. Such data are not employed in the Stantec (2020b) study. Additionally, Moench (1985) explains how it is possible during well testing to make an adaptation in the testing method to reduce the error from well-bore storage effects by up to five orders of magnitude. Usually, this adaptation involves packing off the screened interval, injecting water, and monitoring the rise of water levels in the observation wells or piezometers. Such an adaptation was not used during aquifer testing at Clive. Other researchers and practitioners likewise discourage attempts to analyze pumping tests in semi-confined or leaky aquifers using only data from a pumping well. Typically, either piezometers or observation wells distinct and separate from the pumping well are required. In addition, such points of measurement are required from not just a single layer, but from multiple layers. For instance, Kruseman and de Ridder (1992) say, For a proper analysis of a pumping test in a leaky aquifer, piezometers are required in the leaky confined aquifer, in the aquitard, and in the upper unconfined aquifer. Please justify use of the Hantush (1960) method in the Report without utilizing data from an observation well or a piezometer as is required by the method. Radioactive Material License Application / Federal Cell Facility Page D-10 Appendix D April 9, 2021 Revision 0 Response Summary: Stantec’s responses to Interrogatory 7 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #8 Please justify implementation of the Hantush (1960) method of analysis for analyzing drawdown test data in Well I-1-700 when (i) that method is based on an assumption of constant head in the non-pumped aquifer, shown through field data to have been violated in the overlying aquifer during the test, and (ii) the method was employed despite Neuman and Witherspoon (1969a) warning that Hantush (1960) analysis of aquifer test data assuming constant head in an unpumped aquifer can “lead to significant errors at large values of time.” Response Summary: Stantec’s responses to Interrogatory 8 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #9 Please justify the lack of use of drawdown data from the aquitard when implementing the Neuman and Witherspoon (1969b) method. Response Summary: Stantec’s responses to Interrogatory 9 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #10 Considering the previous discussions about the limitations of the several aquifer-test analysis methods applied, please justify, in a rigorous way, why the values of any of the parameters in Table 3-5 should be considered accurate, or even approximate. Response Summary: Stantec’s responses to Interrogatory 10 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #11 This value for storativity (2.354x10-10) is very far outside the range of values for storativity (S) reported by others for aquifer materials found in the subsurface. Storativity values for confined aquifers are said to generally range from 5×10-5 to 5×10-3 (Todd, 1980). Since Well I-1-100 is said to have been screened across an aquifer, and Bingham Environmental (1981) and Neptune (2015) identify this aquifer as being confined, its storativity would normally be assumed to be within the range given by Todd. Moreover, storativity is generally recognized as not being able to be determined accurately without using data from an observation well located some distance from the pumping well. Can Stantec justify this low storativity? Storativity values for various subsurface materials can be calculated from reported specific- storage values. Specific storage, Ss, is equal to S/b, where b is aquifer thickness. On rearrangement, S = Ssb. The following is a table for ranges of Ss and S values for types and thicknesses of aquitard and aquifer materials (with Ss ranges reported by Domenico and Mifflin, 1965). Radioactive Material License Application / Federal Cell Facility Page D-11 Appendix D April 9, 2021 Revision 0 The specific-storage values can also be found at http://www.aqtesolv.com/aquifer- tests/aquifer_properties.htm#Storativity. For thicker aquifers, a value listed in one of the two columns on the right can simply be multiplied by an appropriate factor to determine the storativity. For example, for an aquifer 50 feet thick, the value in the right-hand column would be multiplied by five to calculate the storativity range. Or the value in third column could be multiplied by 50. The lowest Ss value shown for sedimentary material in Domenico and Mifflin (1965) is 1.5 x 10-5. For layers 1, 10 and 100 feet thick, this lowest Ss value would result in estimated S values of 1.5 x 10-5, 1.5 x 10-4, and 1.5 x 10-3, respectively. Even the lowest value for S is about five orders of magnitude greater than the 2.354x10-10 value for S reported in Table 3- 5 of Stantec (2020b). Since the reported S value of 2.354x10-10 in Stantec (2020b) is five orders of magnitude lower in value than published values for S for the subsurface materials given above, or less, the reported Stantec (2020b) storativity value of 2.354x10-10 does not appear reliable. Besides, it is orders of magnitude smaller than other calculated values listed in the Report for the same layer. As previously discussed, the assumption in the Report of a saturated thickness of 325 feet used in developing the analysis is not correct. Moreover, the drawdown data shown are drawdown data for the upper aquifer, which was separated by a substantial aquitard from the basal aquifer being pumped. Those conditions are definitely outside of the assumptions inherent in the Cooper-Jacob model. Please justify presenting such a remarkably low storativity value, one that was also calculated using the Cooper-Jacob model for drawdown for a single, pumped aquifer even though two aquifers were involved, and the measurements were not taken in the pumped aquifer, but in a non-pumped aquifer. Response Summary: Stantec’s responses to Interrogatory 11 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #12 None of these estimated hydraulic conductivity values appear to be accurate if the previously identified issues are indicative of actual problems in testing or analysis. Assuming a saturated thickness of 325 feet if the saturated thickness is only 36 feet, for example, by itself means that the estimated value of hydraulic conductivity as reported by Stantec (2020) for the two confined aquifer cases would be too small by about an order of magnitude since hydraulic conductivity is equal to transmissivity divided by the saturated thickness. The assumptions required by the analysis for the confined aquifer (e.g., Cooper- Jacob method assumptions) were not even marginally met during testing. Is this not the case? Please justify the response. Response Summary: Stantec’s responses to Interrogatory 12 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #13 Please provide justification for the statement that “groundwater chemistry of I-1-700 is typical of deep groundwater isolated from recharge.” What set of data is identified in the Report that indicates that the groundwater in the aquifer screened by I-1-700 is isolated Radioactive Material License Application / Federal Cell Facility Page D-12 Appendix D April 9, 2021 Revision 0 from, or is typical of groundwater isolated from, recharge? A few sentences that follow the claim made there depict the aquifer as having a relatively reducing environment. However, while reducing environments are generally more common at depth, reducing environments can also be found in many shallow water-bearing zones. Response Summary: Stantec’s responses to Interrogatory 13 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #14 This statement, which refers to “the observed most permeable zone from 325 to 355 ft bgs,” seems to contradict the information in Table 3-5 indicating that the most permeable zone is the one covering a depth range of 90-100 ft bgs. Please provide justification for this statement. Response Summary: Stantec’s responses to Interrogatory 14 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #15 Please provide justification for the assessment given above that results of lab tests indicate hydraulic conductivities for samples being two to three orders of magnitude lower than aquifer-test calculated values. Data in Tables 3-2 and 3-5 do not seem to support that assessment. Order-of-magnitude comparisons provided by data in the table values and the assessment above seem to be off by about an order of magnitude. Response Summary: Stantec’s responses to Interrogatory 15 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #16 Please provide justification for this conclusion. As indicated in Interrogatory #4, uncorrected apparent hydraulic gradients for groundwater that varies in density with depth, even in the case of hydrogeologically homogeneous systems, do not necessarily indicate vertical flow direction. Corrections must be applied to heads in these wells to account for groundwater-density change. For this site, if one were to assume aquifer homogeneity, once corrections are made in the flow equations to account for the effects of buoyancy, no evidence is given in the Report that, in general, groundwater at the Facility does not have a downward component of flow. Comparisons between buoyancy-corrected values in the basal aquifer and in the shallow aquifer, for example, show that some combinations of plausible densities and hydraulic gradients indicate an estimated downward flow component. Moreover, the analytical equations used for making comparisons in the Report are intended for, and would only provide reasonably accurate results for, homogeneous systems. The analytical equations cannot and do not apply to analysis of more complex systems, e.g., ones in which aquifer components are separated by aquitard components. Radioactive Material License Application / Federal Cell Facility Page D-13 Appendix D April 9, 2021 Revision 0 Response Summary: Stantec’s responses to Interrogatory 16 are hereto attached in Exhibit 1 of Appendix D. • Interrogatory #17 The phase “poor water quality” is subjective. It is the Division’s position that this groundwater still needs to be protected. Response Summary: Stantec’s reference to the “poor” quality of groundwater is based on the measured level of total Dissolved Solids (TDS) that classify the basal-depth groundwater beneath EnergySolutions’ Clive facility as “Saline Ground Water,” (e.g., non-potable) in accordance with Utah Administrative Code R317-6-4. The Director has used a similar reference to describe the groundwater beneath EnergySolutions’ Clive, Utah Facility, “The expected dose from the groundwater pathway is zero because of the poor groundwater quality.” (Utah Division of Radiation Control, 2012; pg 93). Neither EnergySolutions’ nor the Director’s own reference to “poor groundwater quality” imply anything regarding the importance of groundwater resource protection. • Interrogatory #18 An apparent hydraulic connection exists between the I-1-700 well, screened at a depth of 325-355 ft bgs, and the overlying aquitard and the aquifer above it. The latter is screened by Well I-1-100 from 90-100 ft bgs. Hydraulic connection is demonstrated because drawdown in the basal aquifer causes water- level drawdown in the upper aquifer (screened from 90-100 ft bgs). A subdued impact is expected in the upper aquifer due to groundwater head losses as the hydraulic response to pumping propagates through an intervening aquitard. This drawdown in an unpumped aquifer indicates that one of the primary assumptions underlying the Hantush (1960) method is not being met. There also appears to be a connection between groundwater in the basal aquifer and groundwater in the aquifer material screened at about 50 feet. This is because groundwater in Well I-1-50 has been identified as having responded to changes in head occasioned by the pumping test in the basal aquifer with a transient reverse drawdown effect. That effect may be due to early deformation of the aquitard and an accompanying temporary increase in fluid pressure in the upper part of the aquitard, transmitted up to the overlying aquifer, as described in Kim and Parizek (1997). A more direct hydraulic response (e.g., drawdown) was not observed in Well I-1-50 during 12 hours of testing. The reason for no response during that time cannot be fully ascertained based on the data currently provided. It has not been demonstrated yet that the length of the pumping test was sufficient for an unconfined aquifer separated from the pumped aquifer by two aquitards and another aquifer. It takes time for direct hydraulic responses to propagate. This is illustrated for two different wells, each one screened in a different aquifer, in the graph shown below, copied from Appendix D of the Report. Radioactive Material License Application / Federal Cell Facility Page D-14 Appendix D April 9, 2021 Revision 0 The displacement (i.e., drawdown) experienced by groundwater in the basal aquifer (screened from 325-355 ft bgs) is shown in blue. This displacement is seen (i) to rapidly increase in value over the interval between 69 and 90 seconds, and then (ii) to asymptotically transition to a plateau displacement range of about 24-25 feet. By contrast, the displacement experienced by groundwater in the more-elevated aquifer screened at 90-100 ft bgs, which displacement is shown in red, does not begin to plateau until about 10,000 seconds. The time taken to begin to approximate the plateau value is, for this upper aquifer, about 100 times as great as the time needed for groundwater levels in the basal aquifer to reach a plateau-level range. Instead of taking about 1 ½ minutes, as it does for the basal aquifer, it takes about 2 ¾ hours for the upper aquifer. While no direct hydraulic response was noted in the very shallow aquifer material above these two aquifers during the testing period, that lack of a direct hydraulic response may have simply been due to insufficient time allowed for a direct hydraulic response to propagate that far upward through additional aquitard material. Considering that it took about 100 times as great a time for the confined aquifer at 90-100 ft bgs to respond than it took for the basal aquifer to do so, it might take considerably more time than that for an overlying unconfined aquifer screened from 25-45 ft bgs and separated from the other aquifers by an aquitard to respond. What is the evidence or justification for assuming that there is “limited connectivity between the shallow zones and the deeper basal aquifer at the Facility?” And what is the precise meaning of the term “limited” in the statement quoted above? What is the significance of the hydraulic connection that is shown to exist in the upper aquifer, owing to the measured drawdown in the groundwater observed in it during the aquifer test? Response Summary: Stantec’s responses to Interrogatory 18 are hereto attached in Exhibit 1 of Appendix D. Radioactive Material License Application / Federal Cell Facility Page D-15 Appendix D April 9, 2021 Revision 0 REFERENCES Bingham Environmental, “Hydrogeologic Report Envirocare Waste Disposal Facility South Clive, Utah.” Prepared for Envirocare of Utah, Prepared by Bingham Environmental. October, 1991. DOE. “Final Environmental Impact Statement of Remedial Actions at the Former Vitro Chemical Site, South Salt Lake, Salt Lake County, Utah.” (DOE/EIS-0099-F) U.S. Department of Energy, UMTRA Project Office, Albuquerque Operations Office, Albuquerque, New Mexico, July, 1984. DOE. “Remedial Action Plan and Site Conceptual Design for Stabilization of the Inactive Uranium Mill Tailings Site at Salt Lake City, Utah.” (UMTRA-DOE-/EA-0141.0000) U.S. Department of Energy, UMTRA Project Office, Albuquerque Operations Office, Albuquerque, New Mexico. 1984. DOE. “Final Environmental Impact Statement - Remedial Actions at the Former Vitro Chemical Company Site South Salt Lake, Salt Lake County Utah.” (DOE/EIS-0099-F). U.S. Department of Energy. July 1984. Vol2. Pg. D-92. EnergySolutions, 2019. “Basal-Depth Aquifer Study Plan” letter to Mr. Ty Howard, Director Utah Division of Waste Management and Radiation Control. October 3, 2019. Personal Communication. Susan Eyzaguirre, Stantec. January 22, 2021. Rogers, V.C. “Radioactive Material License UT2300249: Revised Phase 1 Basal-Depth Aquifer Study Report” Letter CD-2020-149 from EnergySolutions to Ty Howard, Utah Division of Waste Management and Radiation Control. October, 2, 2020. Rogers, V.C. “Radioactive Material Licenses UT2300249 and UT2300478: Phase 1 of the Basal-Depth Aquifer Study Plan (Revised)” Letter CD19-0227 from EnergySolutions to Ty Howard, Utah Division of Waste Management and Radiation Control. November 12, 2019. Stantec Consulting Services Inc, 2021. Responses to the Division’s January 15, 2021 Interrogatory. March 10, 2021. Stantec, 2020. Phase 1 Basal-Depth Aquifer Study Report – Final, Revised, v2, September 30, 2020, Prepared for and Submitted to EnergySolutions, EnergySolutions, LLC by Stantec Consulting Services, Inc., Salt Lake City, Utah. Stantec Consulting Services Inc, 2019. Clive Facility Basal (Deep) Aquifer Characterization Work Plan. October 1, 2019. Utah Division of Radiation Control. “Utah Division of Radiation Control: EnergySolutions LLRW Disposal Facility Class A West Amendment Request – Safety Evaluation Report.” Report by URS, Corporation. Salt Lake City. June 2012. Radioactive Material License Application / Federal Cell Facility Page D-16 Appendix D April 9, 2021 Revision 0 Verbica, D.G. “Basal Aquifer Study” Letter to Vern Rogers of EnergySolutions from the Utah Division of Waste Management and Radiation Control. July 29, 2019. Willoughby, O.H. “Interrogatories for Basal-Depth Aquifer System Study Submitted October 3, 2020.” Letter from the Utah Division of Waste Management and Radiation Control to Vern Rogers of EnergySolutions. January 15, 2021. Radioactive Material License Application / Federal Cell Facility Page D-17 Appendix D April 9, 2021 Revision 0 EXHIBIT 1 TO APPENDIX D STANTEC RESPONSES TO THE DIVISION’S JANUARY 15, 2021 INTERROGATORY Responses to Interrogatory To: Vern C. Rogers, EnergySolutions From: Susan Eyzaguirre, PE, PG, PMP and Walter Weinig, PG, PMP January 15, 2021 Interrogatory Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final (as revised, submitted to the Division October 3, 2020) INTRODUCTION On March 13, 2020, EnergySolutions submitted to the Utah Division of Waste Management and Radiation Control (the Division) the Phase I Basal-Depth Aquifer Study Report (the Report), prepared by Stantec Consulting Services, Inc. (Stantec, 2020a). Based on interrogatories provided by the Division on August 11, 2020 EnergySolutions submitted a revised version (Stantec, 2020b) to the Division on October 3, 2020. Subsequently the Division provided an Interrogatory of the October 3, 2020 revised report on January 15, 2021. Responses to the January 15, 2021 Interrogatory are provided in this memorandum. The interrogatories are shown in italics, each followed by a written response. INTERROGATORY #1 Interrogatory. The Division requested information from EnergySolutions about basal aquifers at the Facility and other hydrogeological information at depth not previously provided. The Division acknowledges the careful field and laboratory work and the useful information that EnergySolutions has provided to the Division through this study. However, the Division has comments and questions regarding some of the information and interpretations of the data. These questions should be considered in the context of the following list of rules: UAC R313-25-8(1), UAC R313-35-9(4)(a), UAC R313-25-15(1)(a), UAC R313-25-3(6), UAC R313-25-24(2) and (7), and UAC R313-25-27(1). Regarding the quoted paragraph above, please indicate which of the Division Director’s requirements, as outlined in the listed rules and as specifically requested by the Director and referenced in the study Plan, have already been met, and which requirements still need to be met, and explain why. Response: Response provided by EnergySolutions. INTERROGATORY #2 Interrogatory. The Division does not see in the Report the following information requested from EnergySolutions and found in the Plan (item numbering retained for ease of reference to the above list): 1. Depth of bedrock geophysical survey 2. Geology (sample description, logs, grain-size, porosity, void ratio, bulk density) 3. Top and bottom depth of each aquifer and aquitard (one or more aquifers not described) 4. Screened depths for the aquifer(s) 5. Hydraulic head for the aquifer(s) 6. Horizontal gradient(s) (not possible in this phase since all wells had similar x-y coordinates) 7. Vertical gradient(s) (the Division has concerns with some calculations made in the Report) 8. Horizontal hydraulic conductivity (the Division has concerns about calculations in the Report) ( 9. Vertical hydraulic conductivity 10. Background groundwater quality of the basal-depth aquifer March 10, 2021 Page 2 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final 11. Groundwater age dating 12. Distribution coefficients/retardation factors Please (i) provide an update on plans to obtain this missing information and subsequently report it to the Division, or (ii) justify the absence of the missing information despite having indicated previously in the Plan that EnergySolutions would obtain and report this information. Response: Response provided by EnergySolutions. INTERROGATORY #3 Interrogatory. The Division asks the following questions: 3.1 Neptune’s conceptual model (Neptune, 2015b) describes two aquifers existing in the depth range below 25 ft and above 275 ft bgs: (i) an unconfined aquifer that extends from the water table down to a total depth of only about 40 to 45 ft bgs, and (ii) a deeper confined aquifer extending downwards from about 45 ft bgs. The presence of the confined aquifer also implies a thin aquitard existing directly above it. Neptune’s conceptual model is also provided in Bingham Environmental (1991). Stantec (2020b), on the other hand, describes a single, undifferentiated unconfined aquifer extending from the water table down to a depth of about 275 feet. For depths down to 275 ft bgs, which conceptual model, if either, appears to be correct? Please provide justification for your answer. 3.2 Neptune’s conceptual model (Neptune, 2015b) describes a single deep aquifer at depths beyond 275 ft bgs. Stantec (2020b) describes two aquitards, as well as a leaky aquifer, in this depth range. Which description is correct? 3.3 Please represent the correct types and locations of all aquifers and aquitards in a revised Figure 3 for the Report. Response: Response provided by EnergySolutions. INTERROGATORY #4 Interrogatory. The Division has the following questions: 4.1 Stantec (2020b) indicates that it calculated “mid-points of saturated zone elevations”, as are found in the last column of Table 3-3, but it is uncertain as to what that implies relative to the calculations. All the calculations for hydraulic gradient in Table 3-4 appear to have been done differently, using instead the freshwater mid-screen interval, corrected for buoyancy. Please clarify what was done for what purpose, and justify why. Response: The mid-points of saturated zones for each unit are provided for completeness and consistency with the language of Post et al (2007). Elevations of the middle of the filter pack are generally very close to mid-screen elevations. Groundwater inflow to a well can occur over the filter-packed zone. The mid-point of March 10, 2021 Page 3 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final filter pack elevation was used to calculate the vertical hydraulic gradients shown in Table 3-4. The reference to “midscreen” in the Table 3-4 header was a carryover from the previous version of the table. 4.2 The text refers to mid-points of the saturated zone elevations, whereas Table 3-3 gives the mid-points of the filter pack elevations as well as the mid-points of the saturated zone elevations, and the calculations in Table 3-4 are based on the mid-screen elevations. Why? The elevations of the mid-points of the saturated zone, mid-points of the filter packs, and mid- points of the screen for each well are all different. So are derivatives of each these quantities. Response: See response to Interrogatory 4.1 above regarding the different elevations. Calculations in Table 3-4 are based on the mid-point of the filter pack as being most representative of the point associated with the measured groundwater level in the well. 4.3 Based on the results of calculations shown in Table 3-4, it appears that some part of each range of what are called the buoyancy-corrected vertical gradients associated with the shallow aquifer well (I-1-30) indicate downward flow to any of the wells in what Neptune (2015) has called the deep aquifer (i.e., I-1-50, I-1-100, and I-1-700). This is because some part of each range has negative values, which, according to the Stantec (2020b) sign convention, represents downward flow. Is this also how EnergySolutions interprets this? Please justify your response. Response: We have discussed sign conventions and directionality in previous meetings and responses to interrogatories. The purpose of the Stantec revised report is to describe and interpret the results of the Phase 1 program, which is focused on well I-1-700 and the basal aquifer. It is incorrect to state that the buoyancy- corrected calculations “indicate downward flow to any of the wells…” For example, buoyancy-corrected vertical gradients between I-1-50 and I-1-700, and between I-1-100 and I-1-700 indicate an upward vertical component of gradient for calculations using both mid-point of filter pack and mid-point of saturated zone elevations. 4.4 Looking at Table 3-4, for the well pair I-1-30 and I-1-700, how does the sum of 0.041, the freshwater mid-screen gradient, and 0.040, the buoyancy correction, supposedly equal 0.002? The latter value is said in Stantec (2020b) to be the buoyancy-corrected mid-screen gradient. Calculations done by the Division indicate that this value, based on the mid-screen assumption for estimating the gradient, should be 0.001, not 0.002 (using the Stantec sign convention for the result). Response: The reported result is the result of rounding and the number of significant digits reported in each calculation. Carried to three significant figures, the result is 0.00152 which rounds to 0.002 with one significant digit of precision. The conclusion of an upward vertical gradient is not altered whether a rounded value of 0.001 or 0.002 is evaluated. 4.5 What is the overall range of vertical gradients calculated for the well pair I-1-30 and I-1-700, when accounting for well geometry and water level elevations, as indicated in the last column of Table 3-4? Do the negative values given for some of these data combinations indicate (according to the Stantec convention) the possibility of downward flow? Please justify your response. Response: The overall range of calculated, buoyancy-corrected vertical gradients for the well pair I-1-30 and I-1-700 is -0.002 (downward) to +0.005 (upward) as shown in the last column of Table 3-4. The range is based on assuming either mid-filter pack elevation or mid-aquifer elevation for the gradient calculation with the same well pair. Gradient calculations are between two points in an aquifer and are independent of the March 10, 2021 Page 4 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final nature of the aquifer material itself. The Stantec (2020b) report describes the results of the Phase 1 program. Evaluations of groundwater flow would require additional assessments that are outside the scope of this study. 4.6 What is the overall calculated range of corrected vertical gradients for the well pair consisting of I-1-50 and I-1-100? Do the negative values given for each of these data combinations indicate (according to the Stantec convention) downward flow? Please justify your response. Response: The overall range of calculated, buoyancy-corrected vertical gradients for the well pair I-1-50 and I-1-100 is -0.009 to -0.001 as shown in the last column of Table 3-4. The direction of the calculated gradients is downward between those two wells at a single point in time. Evaluations of groundwater flow are outside the scope of this study. 4.7 The specific gravity for groundwater in the shallow aquifer is said in Table 3-3 to be 1.032. This value, based on a single measurement for groundwater in the shallow aquifer at a single point, may not be representative of the entire aquifer. Neptune (2015), having examined data from many dozens of wells scattered across the Clive Facility, indicates that, for this facility, the geochemistry of the shallow, unconfined aquifer consists of very high levels of dissolved solutes as outlined above with TDS values ranging from 20 to 70 parts per thousand and specific gravity from 1.02 to 1.06 g/mL (Envirocare 2004, and recent site specific groundwater data acquired by EnergySolutions). This range of specific gravity for the shallow-aquifer groundwater, from 1.02 to 1.06, can be compared with the single value for shallow-aquifer groundwater specific gravity of 1.032 measured in the field recently and used in the Report, which would be more toward the bottom of the reported Neptune (2015) range. If a value of 1.060, at the upper end of the reported range, is instead used for illustrative purposes for groundwater in some areas of the shallow aquifer, then the groundwater density averaged between the basal aquifer and the shallow aquifer is equal to 1.054 g/cm3, the value of (ρa-ρf)/ρf is equal to 0.054, and a table using this higher specific gravity for the shallow- aquifer groundwater, when presented using the Division’s sign convention of this Interrogatory, is as follows: dhf/dz (ρa-ρf)/ρf [dhf/dz + ((ρa-ρ f)/ρf)]qv Flow Direction -0.038 0.016K 0.039 0.015K 0.040 0.014K 0.041 0.013K 0.042 0.012K 0.043 0.011K March 10, 2021 Page 5 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final -0.044 0.010K 0.045 0.009K All calculated flow directions here are downward. This is because the sign associated with qv, or vertical component of flow per unit area, is negative. If flow had been upward, the sign of qv would have been positive. But, in this case, all the values of qv are seen to have negative values. For shallow-aquifer groundwater in this reported specific-gravity range with values of specific gravity as low as a little more than 1.042, which is a little more than midway across the range given by Neptune (2015), the value of (ρa-ρf)/ρf is greater than 0.045. When this is the case, all calculated groundwater flow directions between these two wells are still downward, regardless of the value of |dhf/dz | chosen from the range given by Stantec (2020a) in the original Report. dhf/dz (ρa-ρf)/ρf [dhf/dz + ((ρa-ρ f)/ρf)]qv Flow Direction -0.038 -0.007K 0.039 -0.006K 0.040 -0.005K 0.041 -0.004K 0.042 -0.003K 0.043 -0.002K 0.044 -0.001K 0.045 Despite uncertainty about density values and gradients, it is easy to see for the example above that the term (ρa-ρf)/ρf has a value that is nearly the same absolute magnitude as dhf/dz, but that it has an opposite sign. Accordingly, to determine flow direction, even for simple flow examined using an analytical model, it seems vital to understand both (i) the signs of these two terms and (ii) their values. Please look at density and specific gravity values found in Neptune (2015) and indicate based on this much-larger sample what fraction of the calculated flow-direction values would indicate upward flow, and what fraction would indicate downward flow for each specific-gravity value in the range for each aquifer. Response: As described in the response to Interrogatory 4.3 above, the purpose of the Report is to describe and interpret the results of the Phase 1 program with a focus on well I-1-700 and the basal aquifer. Using the measured, location-specific density values is more appropriate for interpreting this test than using regional values that are not supported by site-specific measurements. March 10, 2021 Page 6 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final 4.8 There’s illustrative value in using the mathematical or analytical model as Stantec (2020b) has done, for it shows that, for a hypothetical hydrogeologically homogeneous system, calculations indicate that flow under certain conditions would be downward at the site, based on considerations of relative density as well as freshwater head. It must be kept in mind, however, that all analytical models like the Post et al. (2007) model employed in the Basal Aquifer Study assume hydrogeological homogeneity (e.g., no aquitards between aquifers). Typically, a numerical model, as opposed to an analytical model, must be run for sites at which much heterogeneity exists to obtain viable results. Examples are SEAWAT and SUTRA by the USGS. Please justify, if possible, why it would be valid to do what Stantec (2020b) has done, i.e., apply an analytical model designed for homogeneous conditions to the heterogeneous site at Clive, where aquitards are known to exist between aquifers. Although Stantec (2020b) says, “vertical hydraulic gradient estimates between I-1-700 and the rest of the wells were all upward with buoyancy considered,” it is noted that, for the specific gravity for shallow- aquifer groundwater of 1.032, Table 3-4 shows that that situation was not the case. Table 3-4 shows that for the I-1-30 and I-1-700 pair, the buoyancy corrected vertical gradient range varies from -0.002 to 0.005. The lower part of this range, i.e., from -0.002 to slightly below zero, represents downward flow, based on the Stantec (2020b) sign convention. Why is Stantec not using the values in the negative range? Please justify your answer. Response: Gradient calculations are between two points in an aquifer and are independent of the nature of the aquifer material itself. Contrary to the reviewer’s assertion, Post et al (2007) does not make an assumption of hydrogeological homogeneity with respect to calculating hydraulic gradient. No assumptions of aquifer homogeneity or heterogeneity are necessary for the results reported in Table 3-4. The primary purpose of the Report is to describe and interpret the results of the Phase 1 program with a focus on well I-1-700 and the basal aquifer. Thus, the gradient relationships between conditions measured at I-1-700 and deepest of the three shallower wells are most relevant to the interpretation. The screened intervals of wells I-1-100 and I-1-50 lie between I-1-700 and I-1-30 as shown in Figure 3 of the Report. An upward gradient is indicated between I-1-700 and I-1-100, and between I-1-700 and I-1-50. The downward gradient (negative values) calculated between I-1-30 and I-1-700 was not weighted as heavily because the consistent upward gradients are calculated for wells paired with I-1-700 that lie between I-1-30 and I-1-700. INTERROGATORY #5 Interrogatory. It appears that a direct hydraulic response had not propagated to Well I-1-50 (screened at a depth of about 50 ft bgs) by the time that the reverse water-level fluctuation in that well was noted. Based on the reference to Kim and Parizek (1997) that Stantec offers, it appears that only an apparent mechanical deformation response in the aquitard and the non-pumped aquifer at a depth of 50 ft bgs had occurred, yielding the observed reverse water-level fluctuation. Is this EnergySolutions’ interpretation, or does it offer an alternative possible interpretation? The reference made by Stantec (2020) to Kim and Parizek (1997) appears to the Division to be reasonable. If the direct hydraulic propagation had not reached up to 50 ft bgs by that time, then that would explain why, by that time, no direct hydraulic response had propagated to the even more-distant shallow aquifer screened by Well I-1-30 (screened at a depth of about 30 ft bgs). Well I-1-30 appears to be separated from Well I-1-50 by an aquitard or semi-confining layer. It seems logical to assume that an aquitard exists at a depth of about 45 ft bgs between those two wells, since Neptune March 10, 2021 Page 7 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final (2015) says that, above that depth, there is an unconfined aquifer, and below that depth, there is a confined aquifer. For the latter to be confined, there must be an aquitard above it. Does a lack of discernible drawdown response in Well I-1-30 throughout the pumping test show limited hydraulic connection between Well I-1-700 and Well I-1-30 over the duration of the pumping test or for all time? Please justify your response. Response: The purpose of the Report is to describe and interpret the results of the Phase 1 program with a focus on well I-1-700 and the basal aquifer, not to re-evaluate the regional work done by others with a focus on the shallower zones. Limited hydraulic connectivity is demonstrated by the lag in response, likely due to the factors cited by the reviewer. These factors may cause the time-related responses observed in the data but are not themselves time dependent. Thus, the interpretation of limited hydraulic connectivity is independent of time although the manifestations of that limited connectivity may vary with time. INTERROGATORY #6 Background. In Stantec (2020b), Section 3.3.1, Analysis Methods, it says For the Cooper-Jacob (1946) and Theis (1935) solutions, the aquifer is conceptualized as confined with infinite areal extent, homogeneous, isotropic and of uniform thickness of 325 feet. Interrogatory. What is the justification for assuming both in the implementation of the Cooper-Jacob (1946) method and in the implementation of the Theis (1935) method that the tested aquifer is 325 feet thick? Substantial evidence in the Report indicates that, instead of a single 325-foot-thick aquifer, the sediments screened in Well I-1-700 and Well I-1-100 respectively represent at least two distinct aquifers, each of much smaller saturated thickness, which are separated by a significantly thick aquitard. Field and laboratory observations and measurements support this conclusion. One line of evidence that a substantial aquitard lies between the two aquifers is based on field data. This apparent aquitard is shown in the Stantec Form to consist of 44.5 feet of sediments extending from 274.5-319.0 ft bgs. Based on this Soil Boring/Lithology Form, this apparent aquitard contains many dry zones. The descriptions in the Form note these dry zones occur specifically at 274.5-277 ft, 286.5-287 ft, 287-297 ft, 297-299 ft, 310-314.5 ft, and 314.5-319 ft bgs. Some of these zones are hard, dense or both. Soil from 289-297 ft bgs, for example, is said to be "very hard, dense, dry." From 314.5-319 ft bgs, soil is said in the Form to be "dense and dry." These data suggest that much of this interval (from 274.5-319 ft bgs) is relatively hard and/or dry, indicating that it would tend, on the whole, to act as an aquitard. Laboratory hydraulic-conductivity testing confirms this assessment. An “undisturbed sample. . . representative of aquitard material”, is how a sample sampled from 297.5-298.0 ft bgs is described in the Report. The Report describes this sample as being “reddish-brown clayey sand.” Table 3-2 of the Report indicates that the vertical component of hydraulic conductivity (Kv) measured in the lab for this sample is only 2.60 x 10-5 cm/s. That is a relatively small value, consistent with that of an aquitard. Experts in the field of well hydraulics indicate that the saturated thickness of a semi-confined aquifer like the aquifer screened by I-1-700 is simply the thickness of the aquifer material (located between a confined layer and an aquitard) that is saturated. For example, Boonstra and Soppe (2017) say, March 10, 2021 Page 8 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final The saturated thickness is equal to the physical thickness of the aquifer between the aquicludes above and below it . . . The same is true for the confined parts of a leaky aquifer bounded by an aquitard and an aquiclude. . . the saturated thickness is a constant. In other words, the saturated thickness does not include any aquitard or aquiclude material. The saturated thickness thus does not include material in two separate aquifers, just in one. Neither does the saturated thickness depend on the height of the potentiometric surface. The saturated thickness for a semi-confined aquifer is thus a constant. It appears to the Division that, for this site, employing for calculation purposes a saturated thickness of 36 feet, rather than 325 feet, is the only approach that makes sense. Using a saturated thickness of 325 feet instead of 36 feet would seemingly render the results of the analysis conducted by Stantec (2020b) inaccurate by a significant amount. The Division has previously addressed this. Is there a reason why EnergySolutions would continue to choose to conduct the analysis using a value of 325 feet? Please justify your answer. Response: The assumptions inherent in the Cooper-Jacob and Theis methods are included in the Report for completeness and context. The assumption of an aquifer thickness of 325 feet represents the saturated zone between the bottom of the basal aquifer and the water table measured in the shallow wells. Assuming the full 325-foot saturated thickness for the purposes of the Cooper-Jacob and Theis calculations allowed the observed drawdown in well I-1-100 to be incorporated into the analysis. Consistent with good professional practice, the Report includes a range of analytical methods and results to evaluate the effects of different assumptions, some of which may be more applicable than others for future tasks. INTERROGATORY #7 Background. Section 3.3.1, Analysis Methods, presents results from aquifer-test analysis, with some of the data shown in Appendix D, AQTESOLV Analytical Results (Stantec, 2020b). The first graph in this appendix shows the results of an analysis based on the Hantush (1960) method, but it is noted from this graph that, in this analysis, Stantec (2020b) employs drawdown data from a pumping well instead of from an observation well. Interrogatory. The Hantush (1960) method specifically requires data from an observation well, rather than from a pumping well, or a control well, to be employed. ASTM D6028, which describes how to analyze data using the modified Hantush (1960) method, directs users who would use it to “construct one or more observation wells or piezometers screened only in the pumped aquifer at a distance from the control well”. So, data for drawdown must come from one or more observation wells or piezometers located in the pumped aquifer some distance from the pumping or control well. While data obtained from groundwater levels measured in a pumping or control well may be of interest qualitatively, such data has limited or no quantitative significance in the Hantush (1960) method. There are several reasons, among which are those described in ASTM (2017). In a footnote in ASTM (2017), which references Moench (1985), it says, “data from the pumped well are affected by variations in the pumping rate, effects of well-bore storage, and the ‘skin’ (a zone around the well hydraulically different from the native materials because of disturbance and alteration caused by well drilling and construction).” These factors mean that drawdown data taken from the pumping well cannot be utilized directly in the Hantush (1960) method to arrive at accurate parameter-estimation results. Data from external observation wells must be employed. Such data are not employed in the Stantec (2020b) study. March 10, 2021 Page 9 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final Additionally, Moench (1985) explains how it is possible during well testing to make an adaptation in the testing method to reduce the error from well-bore storage effects by up to five orders of magnitude. Usually, this adaptation involves packing off the screened interval, injecting water, and monitoring the rise of water levels in the observation wells or piezometers. Such an adaptation was not used during aquifer testing at Clive. Other researchers and practitioners likewise discourage attempts to analyze pumping tests in semi- confined or leaky aquifers using only data from a pumping well. Typically, either piezometers or observation wells distinct and separate from the pumping well are required. In addition, such points of measurement are required from not just a single layer, but from multiple layers. For instance, Kruseman and de Ridder (1992) say, For a proper analysis of a pumping test in a leaky aquifer, piezometers are required in the leaky confined aquifer, in the aquitard, and in the upper unconfined aquifer. Please justify use of the Hantush (1960) method in the Report without utilizing data from an observation well or a piezometer as is required by the method. Response: The 2017 version of ASTM Standard Practice D6028 has been superseded by the 2020 update. Referencing the current (2020) version, we disagree that ASTM Standard Practice D6028/D6028M (ASTM D6028) specifically requires the use of data from an observation well or piezometer. As stated clearly in the Standard (paragraph 1.6), “This document cannot replace education or experience and should be used in conjunction with professional judgment. Not all aspects of the practice may be applicable in all circumstances.” It is common practice to use the drawdown in the pumping well as an observation well. The footnote referenced by the reviewer (Note 5, section 8.1.3 of ASTM D6028/6028M) lists factors that can affect drawdown data from the pumped well, which are well understood by practitioners in the field. The note does not state that the data cannot be used directly in the Hantush (1960) analysis. All aquifer tests involve approximations to and variations from the idealized conditions described in textbooks and the assumptions of analytical solutions. A comparison of the quote cited by the reviewer from Kruseman and de Ridder (1992, page 74) with ASTM D6028 illustrates this well. ASTM D6028 (section 6.3) describes the construction of observation wells “screened only in the pumped aquifer at a distance from the control well.” It does not mention the use of observation wells completed in the aquitard above the leaky aquifer. In fact, the Hantush (1960) method assumes that groundwater levels in the overlying aquifer remain constant. If the standard of the quote taken from Kruseman and de Ridder (1992) is strictly applied, no test performed and analyzed using the Hantush (1960) method in conformance with ASTM D6028 would be valid. This is clearly not the case. Furthermore, the example of the Dalem pumping test used by Kruseman and de Ridder (1992) as an example of a leaky-aquifer test itself violates the strict reading of the quote provided by the reviewer. As Kruseman and de Ridder (1992, page 75) themselves state, “The reader will note that there is no aquifer overlying the aquitard in Figure 4.1” which illustrates the Dalem test conditions. Thus, there are no piezometers in the overlying, unconfined aquifer and yet the authors use this example to demonstrate how a leaky-aquifer pumping test can be conducted and interpreted. Field tests in practical applications typically vary from textbook examples. Standards of practice allow professional judgment to be applied to real-world implementation. Use of the Hantush (1960) method to March 10, 2021 Page 10 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final analyze the I-1-700 aquifer test data was appropriate for the purpose of this study. We believe that the work described in the Stantec the Report is consistent with the standard of professional practice for work of this nature, at the location the work was performed, at the time the work was performed. INTERROGATORY #8 Background. Stantec (2020b) utilizes the Hantush (1960) method, which assumes as one of its primary assumptions that the head in the overlying, non-pumped aquifer remains constant. See AQTESOLVE (1998-2020) and ASTM (2017). In other words, drawdown in the non-pumped aquifer must be zero. Yet, data from the Basal Aquifer Study show that, to the contrary, significant drawdown was observed in groundwater within the overlying, non-pumped aquifer during the testing period. This is depicted in the second graph found in Appendix D, AQTESOLV Analytical Results. Consider also that Neuman and Witherspoon (1969a) show that, when using the Hantush (1960) method, “the . . . assumption of zero drawdown in the unpumped aquifer can . . . lead to significant errors at large values of time.” Interrogatory. Please justify implementation of the Hantush (1960) method of analysis for analyzing drawdown test data in Well I-1-700 when (i) that method is based on an assumption of constant head in the non-pumped aquifer, shown through field data to have been violated in the overlying aquifer during the test, and (ii) the method was employed despite Neuman and Witherspoon (1969a) warning that Hantush (1960) analysis of aquifer test data assuming constant head in an unpumped aquifer can “lead to significant errors at large values of time.” Response: The drawdown in the non-pumped aquifer is a very small fraction of the saturated thickness, indicating the resulting uncertainty in the analysis is correspondingly small due to this variation between the idealized solution assumptions and the real-world test results. The tests did not run for a long time, so the issue of “significant errors at large values of time” is not relevant. INTERROGATORY #9 Interrogatory. Please justify the lack of use of drawdown data from the aquitard when implementing the Neuman and Witherspoon (1969b) method. Response: No data were available from the aquitard in this test configuration. The lack of aquitard data does not invalidate the test results, but may introduce more uncertainty in the analysis than would occur with the additional data. INTERROGATORY #10 Background. Section 3.2.2 of Stantec (2020b) says that AQTESOLV analytical results for the aquifer test are presented in Appendix D. Estimated hydraulic parameters from the pumping test analysis (including transmissivity, hydraulic conductivity, storativity, and specific yield) are presented in Table 3-5. A copy of Table 3-5 is presented below: March 10, 2021 Page 11 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final Interrogatory. Considering the previous discussions about the limitations of the several aquifer-test analysis methods applied, please justify, in a rigorous way, why the values of any of the parameters in Table 3-5 should be considered accurate, or even approximate. Response: All aquifer test analyses result in approximations due to limitations of test configuration, data quality, and assumptions inherent to the solutions. Consistent with standard practice, Stantec evaluated the data with four different analytical methods that are well accepted and widely used in the industry. The Report includes all the results along with the assumptions and conceptualizations of the physical system. The Report presents the following conclusion regarding the results of the aquifer test analyses (Section 3.3.2): “The leaky-confined conceptual model better represents the field observations than the assumptions of a single, homogenous aquifer inherent in the Cooper-Jacob (1946) and Theis (1935) solutions. Therefore, predicted parameters using the leaky-confined solutions (Hantush, 1960, and Neuman- Witherspoon, 1969) are likely more representative than the other two solutions (Cooper-Jacob, 1946 and Theis, 1935).” The purpose of the Report is to describe and interpret the results of the Phase 1 program with a focus on well I-1-700 and the basal aquifer. The methods and results used are appropriate for the purpose of this study and March 10, 2021 Page 12 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final provide reasonable results consistent with the standard of professional practice for work of this nature, at the location the work was performed, at the time the work was performed. INTERROGATORY #11 Background. Table 3-5, referenced in Section 3.2.2 of Stantec (2020b), is presented in Interrogatory #10. It is noted from this table that the Stantec calculated storativity for the aquifer screened by Well I-1-100 (screened from 90-100 ft bgs) is, based on the Cooper-Jacob analysis for the pumping phase of the test, 2.354x10-10. Interrogatory. This value for storativity (2.354x10-10) is very far outside the range of values for storativity (S) reported by others for aquifer materials found in the subsurface. Storativity values for confined aquifers are said to generally range from 5×10-5 to 5×10-3 (Todd, 1980). Since Well I-1-100 is said to have been screened across an aquifer, and Bingham Environmental (1981) and Neptune (2015) identify this aquifer as being confined, its storativity would normally be assumed to be within the range given by Todd. Moreover, storativity is generally recognized as not being able to be determined accurately without using data from an observation well located some distance from the pumping well. Can Stantec justify this low storativity? Storativity values for various subsurface materials can be calculated from reported specific-storage values. Specific storage, Ss, is equal to S/b, where b is aquifer thickness. On rearrangement, S = Ssb. The following is a table for ranges of Ss and S values for types and thicknesses of aquitard and aquifer materials (with Ss ranges reported by Domenico and Mifflin, 1965): Material Ss (ft-1)S, Aquitard 1.0 ft Thick S, Aquitard 10 ft Thick Plastic clay -4-6.2×10-3 -4-6.2×10-3 -3-6.2×10-2 clay -4-7.8×10-4 -4-7.8×10-4 -3-7.8×10-3 hard clay -4-3.9×10-4 -4-3.9×10-4 -3-3.9×10-3 sand -4-3.1×10-4 -4-3.1×10-4 -3-3.1×10-3 sand -5-6.2×10-5 -5-6.2×10-5 -4-6.2×10-4 sandy gravel -5-3.1×10-5 -5-3.1×10-5 -4-3.1×10-4 The specific-storage values can also be found at http://www.aqtesolv.com/aquifer- tests/aquifer_properties.htm#Storativity. For thicker aquifers, a value listed in one of the two columns on the right can simply be multiplied by an appropriate factor to determine the storativity. For example, for an aquifer 50 feet thick, the value in the right-hand column would be multiplied by five to calculate the storativity range. Or the value in third column could be multiplied by 50. The lowest Ss value shown for sedimentary material in Domenico and Mifflin (1965) is 1.5 x 10-5. For layers 1, 10 and 100 feet thick, this lowest Ss value would result in estimated S values of 1.5 x 10-5, 1.5 x 10-4, and 1.5 x 10-3, respectively. Even the lowest value for S is about five orders of magnitude greater than the 2.354x10-10 value for S reported in Table 3-5 of Stantec (2020b). March 10, 2021 Page 13 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final Since the reported S value of 2.354x10-10 in Stantec (2020b) is five orders of magnitude lower in value than published values for S for the subsurface materials given above, or less, the reported Stantec (2020b) storativity value of 2.354x10-10 does not appear reliable. Besides, it is orders of magnitude smaller than other calculated values listed in the Report for the same layer. As previously discussed, the assumption in the Report of a saturated thickness of 325 feet used in developing the analysis is not correct. Moreover, the drawdown data shown are drawdown data for the upper aquifer, which was separated by a substantial aquitard from the basal aquifer being pumped. Those conditions are definitely outside of the assumptions inherent in the Cooper-Jacob model. Please justify presenting such a remarkably low storativity value, one that was also calculated using the Cooper-Jacob model for drawdown for a single, pumped aquifer even though two aquifers were involved, and the measurements were not taken in the pumped aquifer, but in a non-pumped aquifer. Response: The Report describes the assumptions and limitations of the aquifer-test analyses that were performed. Table 3-5 includes all results for completeness and transparency. We agree that the storativity (S) value calculated using the Cooper-Jacob method lies outside the generally accepted range for the types of materials described in the Report. The following paragraph in Section 3.2.2 provides Stantec’s conclusion regarding the applicability of the various analyses that were included: “The leaky-confined conceptual model better represents the field observations than the assumptions of a single, homogenous aquifer inherent in the Cooper-Jacob (1946) and Theis (1935) solutions. Therefore, predicted parameters using the leaky-confined solutions (Hantush, 1960, and Neuman-Witherspoon, 1969) are likely more representative than the other two solutions (Cooper-Jacob, 1946 and Theis, 1935).” INTERROGATORY #12 Interrogatory. None of these estimated hydraulic conductivity values appear to be accurate if the previously identified issues are indicative of actual problems in testing or analysis. Assuming a saturated thickness of 325 feet if the saturated thickness is only 36 feet, for example, by itself means that the estimated value of hydraulic conductivity as reported by Stantec (2020) for the two confined aquifer cases would be too small by about an order of magnitude since hydraulic conductivity is equal to transmissivity divided by the saturated thickness. The assumptions required by the analysis for the confined aquifer (e.g., Cooper-Jacob method assumptions) were not even marginally met during testing. Is this not the case? Please justify the response. Response: The following paragraph in Section 3.2.2 provides Stantec’s conclusion regarding the applicability of the various analyses that were presented: “The leaky-confined conceptual model better represents the field observations than the assumptions of a single, homogenous aquifer inherent in the Cooper-Jacob (1946) and Theis (1935) solutions. Therefore, predicted parameters using the leaky-confined solutions (Hantush, 1960, and Neuman-Witherspoon, 1969) are likely more representative than the other two solutions (Cooper-Jacob, 1946 and Theis, 1935).” INTERROGATORY #13 Interrogatory. Please provide justification for the statement that “groundwater chemistry of I-1-700 is typical of deep groundwater isolated from recharge.” What set of data is identified in the Report that indicates that the groundwater in the aquifer screened by I-1-700 is isolated from, or is typical of groundwater isolated from, recharge? A few sentences that follow the claim made there depict the aquifer as having a relatively reducing environment. However, while reducing environments are generally more common at depth, reducing environments can also be found in many shallow water- bearing zones. March 10, 2021 Page 14 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final Response: Reducing environments may be found in some shallow water-bearing zones but are uncommon in recharge zones where water by definition has recently been in contact with the atmosphere. In addition to the reducing conditions, high total dissolved solids (TDS) concentrations indicate an extended time for groundwater to dissolve constituents from the aquifer material and a lack of mixing with recently recharged water that would be naturally low in TDS. INTERROGATORY #14 Interrogatory. This statement, which refers to “the observed most permeable zone from 325 to 355 ft bgs,” seems to contradict the information in Table 3-5 indicating that the most permeable zone is the one covering a depth range of 90-100 ft bgs. Please provide justification for this statement. Response: The statement in the Summary and Conclusions section accurately summarizes the observations made in the field during drilling and well construction. The purpose of the Phase 1 program was to investigate conditions in the basal aquifer. Well I-1-100 is already screened in the approximate 90-100 ft below ground surface (bgs) depth interval; completing well I-1-700 in the same interval would not achieve the purpose of the investigation. The screened interval for well I-1-700 was selected in the field as the most permeable zone below the deepest existing well based on visual inspection and logging of the extracted core material. The selected screened interval was agreed to by the Division during a meeting on December 9, 2019 after the boring was completed. The estimated hydraulic conductivity reported in Table 3-5 for the depth interval of 90-100 ft below ground surface (bgs) was calculated using the Cooper-Jacob (1946) method analyzing the drawdown response from well I-1-100. The reviewer has previously noted the assumptions and limitations of the Cooper-Jacob (1946) method. The following paragraph in Section 3.2.2 provides Stantec’s conclusion regarding the applicability of the various analyses that were presented: “The leaky-confined conceptual model better represents the field observations than the assumptions of a single, homogenous aquifer inherent in the Cooper-Jacob (1946) and Theis (1935) solutions. Therefore, predicted parameters using the leaky-confined solutions (Hantush, 1960, and Neuman-Witherspoon, 1969) are likely more representative than the other two solutions (Cooper-Jacob, 1946 and Theis, 1935).” INTERROGATORY #15 Background. Section 4, Summary and Conclusions, states Low vertical hydraulic conductivities were measured in undisturbed samples collected from the identified aquitard zones above and below the I-1-700 screened interval, on the order of 10-5 cm/s in the upper and 10-6 cm/s in the lower aquitard zones (Table 3-2). These results are two to three orders of magnitude lower than horizontal hydraulic conductivity estimates of the aquifer test data analysis. Interrogatory. Please provide justification for the assessment given above that results of lab tests indicate hydraulic conductivities for samples being two to three orders of magnitude lower than aquifer-test calculated values. Data in Tables 3-2 and 3-5 do not seem to support that assessment. Order-of-magnitude comparisons provided by data in the table values and the assessment above seem to be off by about an order of magnitude. March 10, 2021 Page 15 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final Response: The ratios range from over an order of magnitude to over two orders of magnitude when comparing the laboratory vertical hydraulic conductivity results (Table 3-4) with the estimated horizontal hydraulic conductivity results from I-1-700 (Table 3-5) and three orders of magnitude if the results from well I-1-100 are included in the evaluation. INTERROGATORY #16 Background. Section 4, Summary and Conclusions, states The vertical hydraulic gradient, calculated using fresh water equivalent heads for I-1-700 and three nested wells, indicates an upward direction of vertical groundwater flow between I-1-700 and the shallower monitoring wells at this location. Interrogatory. Please provide justification for this conclusion. As indicated in Interrogatory #4, uncorrected apparent hydraulic gradients for groundwater that varies in density with depth, even in the case of hydrogeologically homogeneous systems, do not necessarily indicate vertical flow direction. Corrections must be applied to heads in these wells to account for groundwater-density change. For this site, if one were to assume aquifer homogeneity, once corrections are made in the flow equations to account for the effects of buoyancy, no evidence is given in the Report that, in general, groundwater at the Facility does not have a downward component of flow. Comparisons between buoyancy-corrected values in the basal aquifer and in the shallow aquifer, for example, show that some combinations of plausible densities and hydraulic gradients indicate an estimated downward flow component. Moreover, the analytical equations used for making comparisons in the Report are intended for, and would only provide reasonably accurate results for, homogeneous systems. The analytical equations cannot and do not apply to analysis of more complex systems, e.g., ones in which aquifer components are separated by aquitard components. Response: The statement regarding vertical gradients calculated using fresh-water equivalent heads is correct. Buoyancy corrections are discussed elsewhere in the Report. The calculated, buoyancy-corrected vertical gradients between well I-1-700 and wells I-1-100 and I-1-50 are upward for the range of assumptions regarding the relative depths of measurement. The direction of the calculated, buoyancy-corrected vertical gradient between well I-1-700 and well I-1-30 using the mid-filter pack elevations is upward. While the calculated, buoyancy-corrected vertical gradient between I-1-700 and I-1-30 could be either upward or downward depending on the assumptions made regarding the relative depth of measurement for hydraulic head between the two wells, an upward gradient is more likely. Taken as a whole, the data and calculations with buoyancy corrections support the conclusion of an upward gradient between I-1-700 and the shallower monitoring wells at that location. Gradient calculations are made between two points in an aquifer and are independent of the nature of the aquifer material itself. The purpose of the Report is to describe and interpret the results of the Phase 1 program with a focus on well I-1-700 and the basal aquifer. Evaluations of groundwater flow are outside the scope of this study. March 10, 2021 Page 16 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final INTERROGATORY #17 Interrogatory. The phase “poor water quality” is subjective. It is the Division’s position that this groundwater still needs to be protected. Response: Response provided by EnergySolutions. INTERROGATORY #18 Background. Section 4, Summary and Conclusions, states These results indicate limited connectivity between the shallow zones and the deeper basal aquifer at the Facility. Given the upward component of groundwater flow, vertical heterogeneity with aquifer zones separated by an aquitard and a semi-confined aquifer underlain by a thick aquitard, low vertical hydraulic conductivity and observed dryness of the aquitard zones, and the lack of response in the 30 and 50 foot deep observation wells during the aquifer test, hydraulic communication from the shallow zones to the deeper basal aquifer under natural conditions is unlikely. Interrogatory. An apparent hydraulic connection exists between the I-1-700 well, screened at a depth of 325-355 ft bgs, and the overlying aquitard and the aquifer above it. The latter is screened by Well I- 1-100 from 90-100 ft bgs. Hydraulic connection is demonstrated because drawdown in the basal aquifer causes water-level drawdown in the upper aquifer (screened from 90-100 ft bgs). A subdued impact is expected in the upper aquifer due to groundwater head losses as the hydraulic response to pumping propagates through an intervening aquitard. This drawdown in an unpumped aquifer indicates that one of the primary assumptions underlying the Hantush (1960) method is not being met. There also appears to be a connection between groundwater in the basal aquifer and groundwater in the aquifer material screened at about 50 feet. This is because groundwater in Well I-1-50 has been identified as having responded to changes in head occasioned by the pumping test in the basal aquifer with a transient reverse drawdown effect. That effect may be due to early deformation of the aquitard and an accompanying temporary increase in fluid pressure in the upper part of the aquitard, transmitted up to the overlying aquifer, as described in Kim and Parizek (1997). A more direct hydraulic response (e.g., drawdown) was not observed in Well I-1-50 during 12 hours of testing. The reason for no response during that time cannot be fully ascertained based on the data currently provided. It has not been demonstrated yet that the length of the pumping test was sufficient for an unconfined aquifer separated from the pumped aquifer by two aquitards and another aquifer. It takes time for direct hydraulic responses to propagate. This is illustrated for two different wells, each one screened in a different aquifer, in the graph shown below, copied from Appendix D of the Report. March 10, 2021 Page 17 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final The displacement (i.e., drawdown) experienced by groundwater in the basal aquifer (screened from 325-355 ft bgs) is shown in blue. This displacement is seen (i) to rapidly increase in value over the interval between 69 and 90 seconds, and then (ii) to asymptotically transition to a plateau displacement range of about 24-25 feet. By contrast, the displacement experienced by groundwater in the more-elevated aquifer screened at 90-100 ft bgs, which displacement is shown in red, does not begin to plateau until about 10,000 seconds. The time taken to begin to approximate the plateau value is, for this upper aquifer, about 100 times as great as the time needed for groundwater levels in the basal aquifer to reach a plateau- level range. Instead of taking about 1 ½ minutes, as it does for the basal aquifer, it takes about 2 ¾ hours for the upper aquifer. While no direct hydraulic response was noted in the very shallow aquifer material above these two aquifers during the testing period, that lack of a direct hydraulic response may have simply been due to insufficient time allowed for a direct hydraulic response to propagate that far upward through additional aquitard material. Considering that it took about 100 times as great a time for the confined aquifer at 90-100 ft bgs to respond than it took for the basal aquifer to do so, it might take considerably more time than that for an overlying unconfined aquifer screened from 25-45 ft bgs and separated from the other aquifers by an aquitard to respond. What is the evidence or justification for assuming that there is “limited connectivity between the shallow zones and the deeper basal aquifer at the Facility?” And what is the precise meaning of the term “limited” in the statement quoted above? What is the significance of the hydraulic connection that is shown to exist in the upper aquifer, owing to the measured drawdown in the groundwater observed in it during the aquifer test? Response: As described in the response to Interrogatory # 5 above, limited hydraulic connectivity is demonstrated by the lag in response of drawdown in the shallow wells due to pumping in the deep well, likely due to the factors cited by the reviewer in that interrogatory. “Limited” means less responsive than would be expected under idealized conditions, for all the factors cited by the reviewer. The Division’s conceptual model of dry zones and a heterogeneous aquifer sequence of aquifers and aquitards supports the conclusion of limited connectivity between the shallow and deep zones at the location of I-1-700. March 10, 2021 Page 18 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final REFERENCES ASTM, 2017. D6028 − 17 Standard Test Method (Analytical Procedure) for Determining Hydraulic Properties of a Confined Aquifer Taking into Consideration Storage of Water in Leaky Confining Beds by Modified Hantush Method, ASTM, 9 pp. ASTM, 2020. D6028/D6028M, Standard Practice for (Analytical Procedure) Determining Hydraulic Properties of a Confined Aquifer Taking into Consideration Storage of Water in Leaky Confining Beds by Modified Hantush Method, ASTM International. Bingham Environmental (1981) Hydrogeologic Report Envirocare Waste Disposal Facility South Clive, Utah, prepared for Envirocare of Utah. Salt Lake City, UT, October 9. Boonstra, H. and Soppe, R. (2017) Well Hydraulics and Aquifer Tests, in, Cushman, J.H. and Tartakovsy, D.M., eds., The Handbook of Groundwater Engineering, Third Edition, CRC Press, Boca Raton, Florida. Domenico, P.A. and Mifflin, M.D. (1965) Water from low-permeability sediments and land subsidence, Water Resources Research, v. 1, no. 4, p. 563-576. Hantush, M.S., 1960. Modification of the theory of leaky aquifers, Journal of Geophysical Research, v. 65, no. 11, p. 3713-3725. Kim, J. and Parizek, R.R., 1997. Numerical simulation of the Noordbergum effect resulting from groundwater pumping in a layered aquifer system, Journal of Hydrology, v. 202, p. 231–243. Kruseman, G. P., and N. A. de Ridder, 1992. Analysis and Evaluation of Pumping Test Data, 2nd ed., Publication 47, International Institute for Land Reclamation and Improvement, Wageningen, Netherlands. Moench, A. F., 1985. Transient flow to a large-diameter well in an aquifer with storative semiconfining layers, Water Resources Research, v. 21, no. 8, p. 1121–1131. Neptune, 2015. Final Report for the Clive DU PA Model, Clive DU PA, Model v1.4, Prepared for EnergySolutions, LLC by Neptune and Company, Inc., Los Alamos, New Mexico. See also various appendices therein. Neuman, S.P. and Witherspoon, P.A., 1969a. Applicability of Current Theories of Flow in Leaky Aquifers, Water Resources Research, v. 5, no. 4, p. 817-829. Neuman, S.P. and P.A. Witherspoon.1969b. Theory of flow in a confined two aquifer system, Water Resources Research, v. 5, no. 4, p. 803-816. Post, V., Kooi, H. and Simmons, C., 2007. Using hydraulic head measurements in variable-density ground water flow analyses, Groundwater, v. 45, no. 6 p. 664-671. Stantec, 2020a. Phase 1 Basal-Depth Aquifer Study Report, dated March 13, 2020, Prepared for and Submitted to EnergySolutions, LLC by Stantec Consulting Services, Inc., Salt Lake City, Utah. March 10, 2021 Page 19 of 19 Reference: Responses to Interrogatory for EnergySolutions’ Phase 1 Basal-Depth Aquifer Study Report – Final Stantec, 2020b. Phase 1 Basal-Depth Aquifer Study Report – Final, Revised, v2, September 30, 2020, Prepared for and Submitted to EnergySolutions, EnergySolutions, LLC by Stantec Consulting Services, Inc., Salt Lake City, Utah. Radioactive Material License Application / Federal Cell Facility Page D-19 Appendix D April 9, 2021 Revision 0 EXHIBIT 2 TO APPENDIX D STANTEC’S PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT CLIVE DISPOSAL FACILITY Phase 1 Basal-Depth Aquifer Study Report Utah 84111 PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT This document entitled Phase 1 Basal-Depth Aquifer Study Report was prepared by Stantec Consulting Services Inc. (“Stantec”) for the account of EnergySolutions, LLC (EnergySolutions). Any reliance on this document by any third party is strictly prohibited. The material in it reflects Stantec’s professional judgment in light of the scope, schedule and other limitations stated in the document and in the contract between Stantec and EnergySolutions. The opinions in the document are based on conditions and information existing at the time the document was published and do not take into account any subsequent changes. In preparing the document, Stantec did not verify information supplied to it by others. Any use which a third party makes of this document is the responsibility of such third party. Such third party agrees that Stantec shall not be responsible for costs or damages of any kind, if any, suffered by it or any other third party as a result of decisions made or actions taken based on this document. Prepared by (signature) Emil Yeager, PG Reviewed by (signature) Walter Weinig, PG, PMP, QP Approved by (signature) Susan Eyzaguirre, PE, PG, PMP PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT Table of Contents ABBREVIATIONS .....................................................................................................................iii 1.0 INTRODUCTION .......................................................................................................... 1.1 1.1 SITE DESCRIPTION .................................................................................................... 1.1 1.2 GEOLOGY AND HYDROSTRATIGRAPHY .................................................................. 1.1 2.0 SUMMARY OF FIELD WORK CONDUCTED .............................................................. 2.1 2.1 BOREHOLE DRILLING AND GEOTECHNICAL SOIL SAMPLING ............................... 2.1 2.2 WELL INSTALLATION ................................................................................................. 2.2 2.3 MONITORING WELL DEVELOPMENT ........................................................................ 2.3 2.4 AQUIFER TEST AND GROUNDWATER SAMPLING .................................................. 2.3 3.0 RESULTS .................................................................................................................... 3.1 3.1 GEOTECHNICAL ANALYTICAL RESULTS ................................................................. 3.1 3.2 GROUNDWATER LEVELS AND VERTICAL HYDRAULIC GRADIENTS ..................... 3.1 3.2.1 Density Corrections ..................................................................................... 3.1 3.2.2 Vertical Hydraulic Gradients ........................................................................ 3.2 3.3 AQUIFER TEST RESULTS .......................................................................................... 3.2 3.3.1 Analysis Methods ........................................................................................ 3.2 3.3.2 Analysis Results .......................................................................................... 3.3 3.4 GROUNDWATER SAMPLE RESULTS ........................................................................ 3.4 4.0 SUMMARY AND CONCLUSIONS ............................................................................... 4.1 5.0 REFERENCES ............................................................................................................. 5.1 LIST OF TABLES Table 2-1 Summary of Stratigraphically Representative Zones Table 3-1 Geotechnical Test Results for Disturbed Samples Table 3-2 Geotechnical Test Results for Undisturbed Samples Table 3-3 Static Water Level Measurements and Elevations Table 3-4 Vertical Hydraulic Gradients Using Fresh Water Equivalent Heads Table 3-5 January 2020 I-1-700 Estimated Hydraulic Parameters Table 3-6 January 2020 I-1-700 Groundwater Sampling Results PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT LIST OF FIGURES Figure 1 Site Location Figure 2 Location of I-1-700 LIST OF APPENDICES Appendix A Borehole Log, Well Build Diagram, and Field Forms Appendix B Photographs Appendix C Geotechnical Report Appendix D AQTESOLV Analytical Results Appendix E Groundwater Analytical Laboratory Reports PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT iii Abbreviations % percent AWAL American West Analytical Laboratories bgs below ground surface cm/s centimeters per second CRT constant rate test DOE Department of Energy DWMRC Division of Waste Management and Radiation Control Facility EnergySolutions Clive Facility GEL GEL Laboratories LLC IGES IGES geotechnical lab K hydraulic conductivity mg/l milligrams per liter OD outer diameter ORP oxidation reduction potential pCi/l picoCuries per liter Study Basal-Depth Aquifer Study TDS total dissolved solids UAC Utah Administrative Code USCS Unified Soil Classification System U.S. EPA United States Environmental Protection Agency PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT INTRODUCTION 1.1 1.0 INTRODUCTION This summary report presents findings for Phase 1 of the Basal-Depth Aquifer Study (Study) conducted at the EnergySolutions Clive Facility (Facility). Phase 1 of the Study was performed in accordance with the Basal-Depth Aquifer Study Plan (EnergySolutions, 2019 and Stantec, 2019), which was designed to understand the hydrogeologic and geologic characteristics of the basal-depth aquifer at the Facility where aquifer properties at basal-depths have not been extensively studied. The hydrogeologic conditions of the first 100 feet below the Facility have already been well characterized since the State of Utah/Department of Energy VITRO Chemical Company project and original Envirocare of Utah licensing actions (Bingham Environmental, 1991 and Department of Energy [DOE] 1984a, 1984b). In addition, EnergySolutions’ subsequent licensing and permitting activities have further characterized the subsurface beneath the Facility. These previous activities, coupled with long-term monitoring of the shallow, unconfined aquifer, have extensively captured the hydrogeologic conditions in the first 100 feet below ground surface (bgs). Based on the understanding of the hydrogeologic conditions in the first 100 feet, DOE and EnergySolutions assumed the conceptual model of the Facility includes similar stratigraphy below that first 100 feet. EnergySolutions has been tasked by the Utah Division of Waste Management and Radiation Control (DWMRC) to validate this hydrogeologic conceptual model down to basal depths (i.e., log the subsurface geology/stratigraphy and characterize the deep aquifer) through the installation and sampling of a basal depth well. Data collected from Phase 1 of the Study are used to understand the characteristics of the subsurface hydrogeology at depths exceeding 100 feet bgs and inform EnergySolutions and DWMRC if development of subsequent Study phases are warranted. In addition to collection of basal-depth aquifer characteristic information, Phase 1 of the Study complies with the DWMRC Director’s regulatory requirements. 1.1 SITE DESCRIPTION The Facility is located near the eastern margin of the Great Salt Lake Desert, approximately 50 miles east of Wendover, Nevada and 80 miles west of Salt Lake City, Utah (Figure 1). EnergySolutions operates a low-level radioactive waste and mixed waste disposal facility and has been in operation since 1989. Work was performed at an uncontaminated background area of the Facility and media (soil and groundwater) encountered were not contaminated with hazardous or radiological substances. 1.2 GEOLOGY AND HYDROSTRATIGRAPHY The surficial geology beneath the Facility consists of Quaternary Lacustrine (lakebed) deposits of ancient Lake Bonneville (Stephens, 1974). The upper 40 feet of lacustrine deposits consist of four hydrostratigraphic units including an upper silty clay/clayey silt (Unit 4), an upper silty sand (Unit 3), a middle silty clay (Unit 2), and a lower sand/silty sand (Unit 1). PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT INTRODUCTION 1.2 The unsaturated zone beneath the facility includes Unit 4 and portions of Units 3 and 2. The shallow, unconfined groundwater system includes the saturated portions of Units 3 and 2. The confined aquifer occurs in Unit 1. Depths to groundwater typically range from 25 to 40 feet bgs beneath the Facility. Cross sections showing the four hydrostratigraphic units are presented in Figures 6, 9, and 10 of Bingham (1991). A new monitoring well was installed beneath the well-characterized 100-foot-deep near-surface material where similar unconsolidated lake-bed sediments and alluvial valley fill were encountered (refer to Section 2.1). PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT SUMMARY OF FIELD WORK CONDUCTED 2.1 2.0 SUMMARY OF FIELD WORK CONDUCTED The objective of Phase 1 of the Study was to characterize the basal-depth aquifer. To collect Phase 1 data, a borehole was drilled; a basal-depth monitoring well was installed, developed, and sampled; and an aquifer test was conducted. DWMRC personnel observed the field data collection activities for the Study. Details regarding the data collection are discussed below. 2.1 BOREHOLE DRILLING AND GEOTECHNICAL SOIL SAMPLING Between November 15 and December 5, 2019, one borehole was drilled by Cascade Drilling using the sonic drilling method. The borehole is located south of the Mixed Waste Cell (Figure 2) and upgradient of any historical or current disposal activities based on the shallow aquifer flow direction. Because creation of a detailed stratigraphic log is critical to characterizing the geology and hydrogeology at basal depths, particularly the stratigraphy below the first 100 feet, the sonic drilling method was selected as this method extracts a continuous core to the total depth of the boring. A telescoping or step-down technique was used to advance the boring because the desired borehole depth scoped in the Basal-Depth Aquifer Study Plan was relatively deep (i.e., between 700 and 800 feet bgs). Telescoping of the boring reduces friction, allowing the boring to be drilled deeper than if drilled without telescoping. The boring began with a 9-inch outer diameter (OD) casing drilled from ground surface to 157 feet bgs, telescoped down to a 8-inch OD casing from 157 feet to 337 feet bgs, and ended with a 7-inch OD casing from 337 feet to 615 feet bgs (the borehole total depth). The borehole was terminated at a depth shallower than the intended depth of 800 feet, because the sonic drill bit met refusal upon encountering a hard breccia layer at 607 to 615 feet bgs, which significantly reduced the drilling efficiency and risked damage of the drilling equipment. Because the borehole termination depth was shallower than the scoped depth a meeting was held on December 9, 2019 with EnergySolutions, DWMRC, Stantec Consulting Services Inc. (Stantec)1, and Cascade Drilling to evaluate adjustments to the planned borehole depth and effects on the planned monitoring well installation (refer to Section 2.2). During the meeting, all parties agreed to: (1) terminate the borehole at the depth achieved; and (2) screen the well at the deepest water-bearing bearing-zone encountered (approximately 330 to 350 feet bgs within the fine grained, wet, silty sand stratigraphy). This meeting was held in accordance with the Basal-Depth Aquifer Study Plan. The collected continuous drill core was visually logged by a Stantec professional geologist licensed in the state of Utah using the Unified Soil Classification System (USCS) soil classification procedures and field descriptions including soil type, color, texture, bedding structures, and moisture content. The geologist also provided drilling and well installation oversight for the duration of the project. A copy of the borehole log is provided in Appendix A and photographs of the sonic core are provided in Appendix B-1. 1 Stantec Consulting Services Inc. was retained by EnergySolutions to assist in the preparation and execution of Phase 1 of the Study. PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT SUMMARY OF FIELD WORK CONDUCTED 2.2 The geologist identified 12 stratigraphically representative zones along the length of the drill core and collected one grab soil sample from each zone to measure grain-size distribution analysis (in accordance with ASTM D6913a). A summary of the representative zones is provided in Table 2-1. The samples were remitted by the geologist to EnergySolutions personnel for submission to IGES geotechnical lab (IGES). This analysis is used to determine particle size distribution and provide an indicator of material properties across the borehole area. Additionally, the geologist identified depths where four undisturbed soil samples were collected in brass sleeves using a direct-push method to evaluate subsurface soil characteristics in an off-site laboratory. Specifically, two undisturbed samples were collected that could be representative of potential aquifer material (coarse-grained) and two undisturbed samples were collected that could be representative of potential aquitard (fine-grained) material. The sample depths were selected based on the geologist’s professional judgement while logging the core utilizing the USCS. The samples were classified in the field as potential aquifers or potential aquitards. These samples were submitted to a local geotechnical laboratory (IGES) to measure porosity and bulk density. Additionally, the two undisturbed samples collected in the potential aquitard material also were submitted to IGES to measure vertical hydraulic conductivity. Geotechnical analytical results are presented in Section 3.1. 2.2 WELL INSTALLATION Between December 10 and December 14, 2019, a deep well, designated I-1-700, was installed in the boring by Cascade Drilling with oversight provided by the Stantec geologist. Stantec recommended well construction details (i.e., installation depth, screen interval, and construction materials) to EnergySolutions based on discussions from the December 9, 2019 meeting with DWMRC and in accordance with the Basal-Depth Aquifer Study Plan. EnergySolutions submitted the recommendations in an email to DWMRC for approval, and DWMRC agreed with the recommended well construction in an email on December 10, 2019. The agreed upon well construction details were: • Backfill the 617 feet deep boring with bentonite chips to a depth to accommodate a total well depth of approximately 350 feet bgs • Install 0.020 stainless steel screen from 320 to 350 feet bgs, across what appears to be the most transmissive zone encountered during drilling (refer to borehole log in Appendix A) • Install 10/20 sand pack around the well screen • Install 3-inch diameter stainless steel casing • Install an above-grade surface completion as outlined in the Basal-Depth Aquifer Study Plan The well was installed to a total depth of 355 feet bgs with a 30-foot screen placed from 325-355 feet bgs. During well construction the well casing was suspended from the drill rig to 350 feet bgs, as specified in the bullet list above. However, after well construction was complete and the well casing was un-hooked from the drill rig the well settled an additional 5 feet, resulting in a total depth of 355 feet bgs. The well settlement was due to the weight of the stainless-steel casing used to construct the well. The interval from 350 to 355 feet consisted of the same fine grained, wet, silty sand stratigraphy as the proposed screened interval (320 to 350 feet) and was back-filled with filter pack sand prior to the well build, so the settlement did not affect the aquifer material screen interval. Once well construction was complete the inside of the PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT SUMMARY OF FIELD WORK CONDUCTED 2.3 well casing was tagged with a weighted tape measure to verify a total depth at 355 feet bgs. The bottom of the well felt solid when tagged, indicating minor or no sediment inside the well after construction. The as-built well construction details include: • 3-inch diameter stainless steel screen from 355 feet bgs to 325 feet bgs • 3-inch diameter stainless steel casing from 325 feet bgs to 2.0 feet above ground surface • 10/20 sand filter pack from 355 feet bgs to 319 feet bgs • Fine-grained sand from 319 feet bgs to 314 feet bgs • 3/8-inch bentonite chips from 314 feet bgs to 300 feet bgs • Annular seal of bentonite grout from 300 feet bgs to 2 feet bgs • Surface seal of concrete from 2 feet bgs to surface A well construction diagram for I-1-700 is provided in Appendix A and photographs of well construction materials and well surface completion are provided in Appendix B-2. 2.3 MONITORING WELL DEVELOPMENT Between January 14 and 15, 2020, I-1-700 was developed in accordance with the Basal-Depth Aquifer Study Plan by Cascade Drilling with oversight provided by a Stantec field technician. On January 14, 2020, the well was bailed, surged, bailed, and then pumped for 30 minutes at an average flow rate of 12.5 gallons per minute (gpm) using an electrical submersible pump installed to approximately mid- screen depth. The purge water was pumped directly to a 20,000-gallon capacity frac tank for storage (refer to photograph 11 in Appendix B-2). Purge water was monitored for water quality parameters pH, specific conductivity, turbidity, temperature and general appearance. Development resumed January 15, 2020, with continued pumping of the well for an additional 1.8 hours at an average flow rate of 15 gpm. Water level measurements were collected during the pumping period and showed a 21.76-foot drop during the 1.8 hours of pumping. Development was stopped once the water parameters were stable and the final turbidity reading readings hovered in the low teens (refer to monitoring well development field forms provided in Appendix A). The purge water toward the end of the pumping period looked clear with no visible suspended solids. Approximately 2,058 gallons of water were purged during the two days of well development. 2.4 AQUIFER TEST AND GROUNDWATER SAMPLING Between January 15 and 16, 2020, a 12-hour constant rate pumping test (i.e., aquifer test) was conducted for I-1-700 in accordance with the Basal-Depth Aquifer Study Plan, by the Stantec field technician and professional geologist, with pumping support provided by Cascade Drilling. On January 15, well development was completed, and the field technician installed pressure transducers in I-1-700 and in nearby observation wells I-1-100, I-1-50, and I-1-30 (refer to Figure 2). To accommodate the transducer the dedicated bladder pump in well I-1-30 was removed and placed in a plastic bag to keep the pump clean and contained. The pump was then delivered to the EnergySolutions security personnel to be placed in a warehouse storage area until it could be reinstalled after completion of the aquifer test. PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT SUMMARY OF FIELD WORK CONDUCTED 2.4 On January 16, 2020 the aquifer test was conducted. The pump in I-1-700 was turned on at 0750, pumped for 12 hours at an average flow rate of 15.4 gpm, and was shut off at 1950. During the aquifer test, water levels were recorded in the pumping well and the three nearby observation wells by the transducers and manually measured by the technician and geologist using electronic water-level sounders. The transducer in monitoring well I-1-100 stopped working during the aquifer test, therefore; manually recorded groundwater levels for this well were used in the aquifer test analysis (refer to Section 3.3). During the 12 hours of pumping approximately 11,088 gallons of water were purged from the well and pumped directly to a 20,000-gallon capacity frac tank for storage. Aquifer test results are presented in Section 3.3. During the aquifer test, EnergySolutions personnel collected groundwater samples and measured field parameters (i.e. pH, temperature, specific conductivity, oxidation reduction potential [ORP], and dissolved oxygen) in the discharge from I-1-700 in accordance with the Basal-Depth Aquifer Study Plan. The samples were collected using a valve installed in the pump discharge line (refer to photograph 11 in Appendix B-2). EnergySolutions submitted the non-radiological parameter analyses samples to American West Analytical Laboratories (AWAL) and the radiological parameters analyses samples to GEL Laboratories LLC (GEL). At the time of groundwater collection, DWMRC personnel also collected splits of the groundwater samples for their own use. The groundwater sample field form is provided in Appendix A and sample results are presented in Section 3.4. PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT RESULTS 3.1 3.0 RESULTS 3.1 GEOTECHNICAL ANALYTICAL RESULTS Soil descriptions and laboratory grain-distribution analysis results (in accordance with ASTM D6913a) of the disturbed grab samples collected from the stratigraphically representative zones are presented in Table 3-1. Depth intervals where the samples were collected are also presented in Table 3-1. Laboratory analyses indicate that the discrete samples collected from between 87 and 287 feet generally consist of sands with smaller fractions of gravels, silts, and/or clays. Samples collected from 337 to 592 feet include a higher percentage of fines (silt and clay) than those observed between 87 and 287 feet bgs. Porosity and bulk density analyses were conducted for two undisturbed samples selected to be representative of aquifer material and the two undisturbed samples representative of aquitard material. Results are presented in Table 3-2. Porosity results for the aquifer samples are 33.5 percent (%) (I-1-700 247-248.5) and 47.2% (I-1-700 337-338.5). The higher porosity of the lower aquifer sample is likely due to the higher prevalence of fines (refer Table 3-1). Porosity values for the aquitard samples are 44.3% (I-1-700 297-298.5) and 49.1% (I-1-700). Results of the vertical hydraulic conductivity (K) tests conducted on the two undisturbed samples representative of potential aquitard material were 0.074 and 0.011 feet per day (feet/day) (2.6×10−5 and 3.9×10−6 centimeters per second [cm/s]). The samples were collected from 297.5-298.0 feet bgs and 377.5-378.0 feet bgs, respectively (refer to Table 3-2). The geotechnical laboratory description for both samples is reddish-brown clayey sand. A copy of the geotechnical laboratory report is provided in Appendix C. 3.2 GROUNDWATER LEVELS AND VERTICAL HYDRAULIC GRADIENTS Static groundwater levels were collected prior to the aquifer test on January 16, 2020, 32 days after I-1-700 was installed. In accordance with EnergySolutions’ Groundwater Quality Discharge permit UGW450005, groundwater levels were corrected to freshwater equivalents prior to further interpretation and modeling. Corrected groundwater levels were used to calculate vertical hydraulic gradients (refer to Section 3.2.2) and model the hydraulic response to the aquifer pumping test (refer to Section 3.3.2). 3.2.1 Density Corrections Due to the variable salinity of groundwater found beneath the Facility, density corrections were utilized to calculate fresh water equivalent heads (Post et al., 2007). Fresh water equivalent heads facilitate the PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT RESULTS 3.2 assessment of hydraulic gradients. The corrected densities were calculated utilizing the following equation: ℎ𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐=𝑧𝑧+(𝑝𝑝𝑢𝑢𝑢𝑢𝑐𝑐𝑐𝑐𝑐𝑐𝑐𝑐× 𝑆𝑆𝑆𝑆𝑤𝑤𝑤𝑤𝑤𝑤𝑤𝑤) Where: hcorr is the fresh water equivalent hydraulic head (feet amsl), z is the elevation head of the mid-filter pack or mid-point of the saturated zone, whichever is lower (feet amsl), puncorr is the uncorrected pressure head above point z (feet), and SGwell is the specific gravity of the water in the well (unitless). Measured static water levels and corrected and uncorrected heads are presented in Table 3-3. The magnitude of the density correction was greatest for I-1-700 because of the high groundwater specific gravity and long water column inside the well. 3.2.2 Vertical Hydraulic Gradients Vertical hydraulic gradients between the collocated wells I-1-30, I-1-50, I-1-100, I-1-700 were calculated after converting saline water levels into fresh water equivalent heads (see Section 3.2). Vertical gradients were calculated using the United States Environmental Protection Agency (U.S. EPA) Vertical Gradient Calculator (U.S. EPA, 2020). The calculator provides the mid-filter pack vertical gradient as well as the range of gradients, which account for well geometry and water level elevations, as applicable. A summary of gradient magnitudes and directions are provided in Table 3-4. All vertical gradients were upward immediately prior to the January 16, 2020 pumping test. The I-1-700 well has a hydraulic head that is higher than all collocated wells. 3.3 AQUIFER TEST RESULTS 3.3.1 Analysis Methods Aquifer test data were analyzed using the software package AQTESOLV, version 4.0 Professional (Duffield, 2007). Groundwater level measurements were collected from the transducers as well as recorded manually by Stantec field personnel at I-1-700 (screened from 325-355 feet bgs), I-1-100 (screened from 90-100 feet bgs), I-1-50 (screened from 40-50 feet bgs), and I-1-30 (screened from 20-30 feet bgs) during the aquifer test. Well I-1-30 showed no discernable response to the aquifer test, suggesting a limited hydraulic connection with the pumped aquifer. Well I-1-50 showed a slight reverse water-level fluctuation, which has been observed in aquifers and aquitards overlying pumped aquifers (Kim and Parizek, 1997). Typical pumping responses were measured in wells I-1-700 and I-1-100. These two wells were selected to evaluate best fit hydraulic parameters using four different mathematical solutions including Hantush (1960), Neuman-Witherspoon (1969), and Cooper-Jacob (1946) for the constant rate test (CRT) pumping PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT RESULTS 3.3 period, and Theis (1935) for the recovery data. The following assumptions were applied for these methods of analysis (Duffield, 2007): • The aquifer is confined or leaky confined, infinite areal extent, homogeneous, isotropic and of uniform thickness of 325 feet. • For leaky aquifers, aquitards have infinite areal extent; uniform vertical hydraulic conductivity, storage coefficient, and uniform thickness; and flow in aquitards is vertical. • For the Hantush method, the pumping and observation wells are partially penetrating, and diameter of pumping well is very small so that storage in the well can be neglected. • For the Hantush method, the ratio of vertical to horizontal hydraulic conductivity (Kv/Kh) was assumed to be 0.1. • Flow to the pumping well is unsteady; flow is horizontal and uniform in a vertical section through the axis of the well. • Water is released from storage in an aquitard instantaneously with a decline of hydraulic head. • Displacement is small relative to the saturated thickness of the aquifer. • For the Neuman-Witherspoon method, aquitards are overlain or underlain by an infinite constant- head plane source. During the aquifer test, the transducer in monitoring well I-1-100 stopped working during the pumping test; therefore, manually recorded groundwater levels were used in the analysis. 3.3.2 Analysis Results Freshwater density corrections were applied to the measured groundwater levels due to the high and variable salinity observed locally. At I-1-700, freshwater equivalent drawdown is approximately 0.3 feet greater than the response in saline water. At I-1-100, the density correction was negligible. The AQTESOLV analytical results for the aquifer test are presented in Appendix D. Estimated hydraulic parameters from the pumping test analysis (including transmissivity, hydraulic conductivity, storativity, and specific yield) are presented in Table 3-5. The maximum measured drawdown from the pumping test was 24.99 feet at I-1-700. The geometric mean for the estimated horizontal hydraulic conductivity in the basal aquifer is estimated to be 6.01 feet/day based on the results from I-1-100 and I-1-700. The average of the horizontal hydraulic conductivity estimates using different methods of analysis is 1.26 feet/day for I-1-700, and 28.72 feet/day for I-1-100 while the average value of storativity was estimated at 1.57×10−3 for I-1-700 and 6.81×10−3 for I-1-100. Two of the four analysis methods applied at I-1-700 assumed the basal-depth aquifer is leaky confined (Hantush, 1960, and Neuman-Witherspoon, 1969). The relatively flat response near the end of pumping suggests a constant source of water is available, consistent with recharge (leakage) occurring during the test. Three analyses were conducted to evaluate the pumping test response at I-1-100. Estimated hydraulic conductivity for I-1-100 is higher than I-1-700, suggesting the hydraulic conductivity at shallower depths is greater than the hydraulic conductivity near 325 feet bgs. PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT RESULTS 3.4 3.4 GROUNDWATER SAMPLE RESULTS The groundwater sample from I-1-700 was analyzed for metals, radionuclides, and major ions at an off- site laboratory, and water quality parameters were measured in the field as provided in Table 3-6. The major cation is sodium and the major anion is chloride. Total dissolved solids (TDS) at basal depths are 65,400 milligrams per liter (mg/l), as compared to an average of 40,297 mg/l for shallow groundwater samples collected in 2018. As is the case for the Facility’s shallow groundwater, the basal-depth groundwater is classified as Class IV – Saline Groundwater, due to the TDS concentration exceeding 10,000 mg/l (Utah Administrative Code R317-6-3, Ground Water Classes). Total uranium (U) is 17.4 micrograms per liter (µg/l); isotopes U-233/234 and U-238 were detected and U-235-236 was not detected. Thorium isotopes were not detected. Gross alpha was not detected, though the analysis did not meet detection limit requirements due to low sample volume; sample volume was limited due to the analytical procedures (refer to the GEL analytical laboratory report provided in Appendix E). Gross beta is 495 picoCuries per liter (pCi/l). A copy of the AWAL and GEL groundwater analytical laboratory reports are provided in Appendix E. The groundwater chemistry of I-1-700 is typical of deep groundwater isolated from recharge. Redox conditions are relatively reducing, based on the field ORP (i.e., Eh) measurement (refer to the groundwater sample field form provided in Appendix A) and the presence of dissolved iron and ammonia. Detected radiological and non-radiological constituents are naturally occurring. PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT SUMMARY AND CONCLUSIONS 4.1 4.0 SUMMARY AND CONCLUSIONS In November and December 2019, a deep boring was drilled at the Facility to 617 feet bgs. The core extracted from the boring was logged and geotechnical soil samples were collected and analyzed. The boring was backfilled to 355 feet bgs and a 3-inch diameter well (I-1-700, screened across the observed most permeable zone from 325 to 355 feet bgs) was successfully constructed. Groundwater samples were collected and analyzed, and an aquifer test was conducted in January 2020. From data collected during this Study, characteristics of the unconsolidated basal aquifer to 617 feet beneath the Facility were evaluated and several basal aquifer study data objectives outlined by DWMRC in their July 29, 2019 letter to EnergySolutions have been met. Visual inspection of the extracted core, geotechnical analysis results, aquifer test evaluation, and groundwater sampling results indicate the following: • The zone of highest permeability (sandy silt) across the 617-foot-deep boring is located at 320 to 355 feet bgs. Horizontal hydraulic conductivity estimates from January 2020 aquifer tests are indicative of silt and silty sand material (Table 3-5), which correlate well with the stratigraphic boring log (Appendix A). • Aquitard material is located both above and below the highest permeability interval, with the largest percentage of fine-grained material (up to 76.2%) located at deeper depths (Table 3-1). Much of the aquitard material was observed to be dense and dry (Appendix A). • Low vertical hydraulic conductivities were measured in undisturbed samples collected from the identified aquitard zones above and below the I-1-700 screened interval, on the order of 10-5 cm/s in the upper and 10-6 cm/s in the lower aquitard zones (Table 3-2). These results are two to three orders of magnitude lower than horizontal hydraulic conductivity estimates of the aquifer test data analysis. • The vertical hydraulic gradient, calculated using fresh water equivalent heads for I-1-700 and three nested wells, indicates an upward direction of vertical groundwater flow at the Facility. • Poor water quality was measured in the groundwater samples collected from I-1-700 (screened from 325 to 355 feet bgs), notably a TDS concentration of 65,400 mg/l which is above the Utah Administrative Code 10,000 mg/l threshold for Class IV groundwater (UAC R317-6-3). These results indicate limited connectivity between the shallow zones and the deeper basal aquifer at the Facility. Given the upward component of groundwater flow, low vertical hydraulic conductivity and observed dryness of the aquitard zones, and the lack of response in the 30 and 50 foot deep observation wells during the aquifer test, hydraulic communication from the shallow zones to the deeper basal aquifer under natural conditions is unlikely. PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT REFERENCES 5.1 5.0 REFERENCES Bingham Environmental, 1991. Hydrogeologic Report Envirocare Waste Disposal Facility South Clive, Utah. Prepared for Envirocare of Utah, Prepared by Bingham Environmental. October 1991. Cooper, H.H. and C.E. Jacob, 1946. A generalized graphical method for evaluating formation constants and summarizing well field history, Am. Geophys. Union Trans., vol. 27, pp. 526-534. Department of Energy (DOE), 1984a. "Final Environmental Impact Statement of Remedial Actions at the Former Vitro Chemical Site, South Salt Lake, Salt Lake County, Utah." (DOE/EIS-0099-F) U.S. Department of Energy, UMTRA Project Office, Albuquerque Operations Office, Albuquerque, New Mexico, July 1984. DOE, 1984b. "Remedial Action Plan and Site Conceptual Design for Stabilization of the Inactive Uranium Mill Tailings Site at Salt Lake City, Utah” (UMTRA-DOE-/EA-0141.0000) U.S. Department of Energy, UMTRA Project Office, Albuquerque Operations Office, Albuquerque, New Mexico. 1984. Duffield, G.M., 2007. AQTESOLV for Windows Version 4.0, HydroSOLVE, Inc., Reton, VA. EnergySolutions, 2019. “Basal-Depth Aquifer Study Plan” letter to Mr. Ty Howard, Director Utah Division of Waste Management and Radiation Control. October 3, 2019. Hantush, M.S, 1960. Modification of the theory of leaky aquifers, Jour. of Geophys. Res., vol. 65, no. 11, pp. 3713-3725. Kim J. and R.R. Parizek, 1997. Numerical simulation of the Noordbergum effect resulting from groundwater pumping in a layered aquifer system. Jour. of Hydrology vol. 202, pp. 231–243. Neuman, S.P. and P.A. Witherspoon, 1969. Theory of flow in a confined two aquifer system, Water Resources Research, vol. 5, no. 4, pp. 803-816. Post, V. H. Kooi, and C. Simmons, 2007. Using Hydraulic Head Measurements in Variable‐Density Ground Water Flow Analyses. Groundwater, vol. 45, no. 6 pp. 664-671. Stantec Consulting Services Inc, 2019. Clive Facility Basal (Deep) Aquifer Characterization Work Plan. October 1, 2019. Stephens, 1974. Hydrologic Reconnaissance of the Northern Great Salt Lake Desert and summary hydrologic Reconnaissance of Northwestern Utah. Utah Department of Natural Resources Technical Publication No. 42, 1974. Theis, C.V., 1935. The relation between the lowering of the piezometric surface and the rate and duration of discharge of a well using groundwater storage, Am. Geophys. Union Trans., vol. 16, pp. 519- 524. PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT REFERENCES 5.2 United States Environmental Protection Agency, 2020. EPA On-line Tools for Site Assessment Calculation, Vertical Gradient Calculator, https://www3.epa.gov/ceampubl/learn2model/part- two/onsite/vgradient02.html, Accessed February 21, 2020. FIGURES U:\233001389\studies_wkplans_reports\Deeper Aquifer Characterization WP\2- Figures\MXD\Fig 1_EnergySol_SiteLoc.mxd DRAWN BY J. Kester Date: 9/4/2019 Salt Lake City Clive FacilityLocation §¨¦15 §¨¦15 §¨¦80 §¨¦70 EnergySolutions Figure 1 SITE LOCATION / Legend 0 30 Miles Interstate CountyBound Site Boundary CLIVE FACILITY 0 1 Miles / §¨¦80 Reference: ESRI/ArcGIS online basemaps U:\233001389\studies_wkplans_reports\Deeper Aquifer Characterization WP\2- Figures\MXD\Fig 2_Drilling_Locs_MW_02212020.mxd DRAWN BY J. Kester Date: 2/21/2020 (A(A Mixed WasteFacility I-1-30I-1-50I-1-100 I-1-700 Legend 0 170 Feet (A I-1-700 (A Existing Wells Mixed Waste Facility Site Boundary / Reference: ESRI/ArcGIS online world imagery EnergySolutions Figure 2 LOCATION OF I -1-700 TABLES TABLE 2-1 SUMMARY OF STRATIGRAPHICALLY REPRESENTATIVE ZONES PHASE 1 BASAL DEPTH AQUIFER STUDY ENERGYSOLUTIONS , CLIVE, UTAH PAGE 1 of 1 Zone Generalized Soil Description Corresponding Geotechnical Sample ID 1 0 98.0 light brown silty sand I-1-700 87-89 87.0 89.0 2 98.0 214.5 brown clayey/silty sand with gravel I-1-700 107-109 107.0 109.0 3 214.5 239.0 brown poorly graded sand I-1-700 227-229 227.0 229.0 4 239.0 267.0 brown silty sand with gravel I-1-700 245-255 245.0 255.0 5 267.0 314.5 brown clayey/silty sand I-1-700 282-287 282.0 287 6 314.5 355.0 grey silty sand / sandy silt I-1-700 337-342 337.0 342.0 7 355.0 359.0 brown clayey/silt with gravel I-1-700 356-359 356.0 359.0 8 359.0 515.5 brown silt/clay with sand(a)I-1-700 367-369 (b)367.0 369.0 8 359.0 515.5 brown clay with silt I-1-700 430-432 (c)430.0 432.0 8 359.0 515.5 brown clay with silt I-1-700 505-507 (d)505.0 507.0 9 515.5 534.0 brown silty sand I-1-700 523-525 523.0 525.0 10 534.0 550.0 brown silty clay I-1-700 542-544 542.0 544.0 11 550.0 577.0 light brown clayey/silty sand I-1-700 570-572 570.0 572.0 12 577.0 607.0 dark brown clayey/silty sand I-1-700 590-592 590.0 592.0 Notes bgs below ground surface Corresponding Sample Depth Interval (feet bgs) Zone Depth Interval (feet bgs) TABLE 3-1GEOTECHNICAL LABORATORY TEST RESULTS FOR DISTURBED SAMPLESPHASE 1 BASAL DEPTH AQUIFER STUDY ENERGYSOLUTIONS, CLIVE, UTAH PAGE 1 of 1 Sample ID Geotechnical Laboratory Soil Description Water Content (%) (1) Coarse Fraction Water Content (%) (2) Split Fraction Water Content (%) (3)Gravel (%)Sand (%)Fines (%)Comments I-1-700 87-89 87.0 89.0 light brown silty sand 16.1 ----0.4%69.9%29.7% I-1-700 107-109 107.0 109.0 brown clayey sand with gravel --8.9 15.7 17.7%70.2%12.1% I-1-700 227-229 227.0 229.0 brown silty sand --7.9 39.1 0.4%63.5%36.1% I-1-700 245-255 245.0 255.0 brown silty sand with gravel --10.9 21.1 15.0%68.5%16.5%Results are in nonconformance with Method D6913 because the minimum dry mass was not met. I-1-700 282-287 282.0 287 brown clayey sand --15.3 28.1 12.8%53.1%34.1%Results are in nonconformance with Method D6913 because the minimum dry mass was not met. I-1-700 337-342 337.0 342.0 grey sandy silt --5.5 36.2 0.6%44.1%55.4% I-1-700 356-359 356.0 359.0 brownish grey clayey gravel with sand --6.3 17.4 27.8%24.3%47.9%Results are in nonconformance with Method D6913 because the minimum dry mass was not met. I-1-700 367-369 367.0 369.0 light brown clayey sand 30.1 ----5.4%47.7%46.9% I-1-700 430-432 430.0 432.0 brown clayey sand 28.3 ----7.4%43.5%49.1% I-1-700 505-507 505.0 507.0 brown clay with sand --4.0 22.9 2.4%21.3%76.2% I-1-700 523-525 523.0 525.0 brown silty sand 27.6 ----0.3%55.1%44.6% I-1-700 542-544 542.0 544.0 reddish brown sandy clay 25.0 ----0.1%46.1%53.8% I-1-700 570-572 570.0 572.0 light brown clayey sand --8.7 21.2 10.0%40.7%49.2%Results are in nonconformance with Method D6913 because the minimum dry mass was not met. I-1-700 590-592 590.0 592.0 dark brown silty sand 31.6 ----0.0%57.5%42.5% Notes ft bgs feet below ground surfaceIDidentification%percent--not applicable Laboratory method used: Depth Interval (ft bgs) TABLE 3-2 GEOTECHNICAL LABORATORY TEST RESULTS FOR UNDISTURBED SAMPLES PHASE 1 BASAL DEPTH AQUIFER STUDY ENERGYSOLUTIONS, CLIVE, UTAH PAGE 1 of 1 Sample ID Sample Representative Material Geotechnical Description Water Content (%) Dry Unit Weight (pcf) Specific Gravity of (G20°C) Total Soil Porosity (%) Conductivity (cm/s) (1) Vertical Hydraulic Conductivity (feet/day) (1) I-1-700 247-247.5 247.0 247.5 24.7 98.6 I-1-700 247.5-248 247.5 248.0 15.7 115.7 I-1-700 248-248.5 248.0 248.5 20 105.3 I-1-700 297-297.5 297.0 297.5 31.4 89.4 I-1-700 297.5-298 297.5 298.0 33.9 82.8 I-1-700 298-298.5 298.0 298.5 29 86.9 I-1-700 337-337.5 337.0 337.5 25.3 90.1 I-1-700 337.5-338 337.5 338.0 46.9 72.7 I-1-700 338-338.5 338.0 338.5 43.8 73.1 I-1-700 377-377.5 377.0 377.5 33 86.3 I-1-700 377.5-378 377.5 378.0 34.3 85.7 I-1-700 378-378.5 378.0 378.5 39.2 80.8 Notes %percent --not analyzed bgs below ground surface cm/s centimeters per second ID identification pcf pounds per cubic foot Laboratory methods used: Water Content and Unit Weight of Soil Specific Gravity of Soil Solids by Water Pycnometer Hydraulic Conductivity of Saturated Porous Materials using a Flexible Wall Permeameter -- 7.40E-02 -- 1.10E-02aquitard3.90E-06 2.60E-05 -- -- -- -- reddish brown clayey sand reddish brown clayey sand 49.12.631 (2) 33.5 44.3 47.2 Depth Interval (feet bgs) 2.579 2.499 (2) 2.390 aquifer aquitard aquifer TABLE 3-3 JANUARY 2020 STATIC WATER LEVEL MEASUREMENTS AND ELEVATIONS PHASE 1 BASAL DEPTH AQUIFER STUDY ENERGYSOLUTIONS, CLIVE, UTAH PAGE 1 of 1 Well ID Easting (feet) (1) Northing (feet) (1) Top of Protective Casing w/o Lid (feet amsl) Water Level Date & Time Depth to Water (feet) Saline Water Elevation (feet amsl) Gravity Fresh Water Groundwater Elevation (feet amsl) Mid-Point of Filter Pack Elevation (feet amsl) Sat Zone Elevation (feet amsl) I-1-30 1,194,196 7,420,901 4279.45 1/16/2020 07:51 28.85 4250.60 1.032 4250.73 4247.79 4253.67 I-1-50 1,194,193 7,420,900 4279.15 1/16/2020 07:53 28.65 4250.50 1.017 4250.78 4233.92 4243.05 I-1-100 1,194,194 7,420,897 4279.33 1/16/2020 07:54 29.17 4250.16 1.018 4251.35 4184.04 4217.2 I-1-700 1,194,218 7,420,924 4280.06 1/16/2020 07:50 31.40 4248.66 1.048 4263.33 3943.16 4087.44 Notes amsl – above mean sea level ID - identification Sat - saturated TABLE 3-4 VERTICAL HYDRAULIC GRADIENTS USING FRESH WATER EQUIVALENT HEADS PHASE 1 BASAL DEPTH AQUIFER STUDY ENERGYSOLUTIONS , CLIVE, UTAH PAGE 1 of 1 Upper Well Lower Well Midscreen Vertical Gradient Vertical Gradient Ranges I-1-50 +0.004 +0.002 to +0.023 I-1-100 +0.010 +0.008 to +0.012 I-1-700 +0.041 +0.038 to +0.045 I-1-100 +0.011 +0.009 to +0.016 I-1-700 +0.043 +0.040 to +0.048 I-1-100 I-1-700 +0.050 +0.044 to +0.056 Note positive (+) = upward gradient, negative (−) = downward gradient I-1-30 I-1-50 TABLE 3-5 JANUARY 2020 AQUIFER TEST ESTIMATED HYDRAULIC PARAMETERS PHASE 1 BASAL DEPTH AQUIFER STUDY ENERGYSOLUTIONS, CLIVE, UTAHPAGE 1 of 1 Well ID Tests Analysis Method (1)Aquifer Type Transmissivity (ft2/day) Horizontal Hydraulic Conductivity (ft/day) Storativity (-) Average Horizontal Hydraulic Conductivity (ft/day) Geometric Mean Horizontal Hydraulic Conductivity (ft/day) Calculated Average for Storativity (-) Hantush Leaky Confined 1.91x10 Witherspon Confined 1.29x10 Recovery Confined Witherspon Confined 2.354x10 Notes: from 325-355 feet bgs) from 90-100 feet bgs) 6.01 Pumping Pumping TABLE 3-6 JANUARY 2020 I-1-700 GROUNDWATER SAMPLING RESULTS PHASE 1 BASAL DEPTH AQUIFER STUDY ENERGYSOLUTIONS, CLIVE, UTAHPAGE 1 of 1 Calcium 773Iron, Dissolved 0.685Magnesium794Potassium507Sodium23,200 Metals (µg/l)Uranium 17.4 Radionuclides (pCi/L)Result Uncertainty MDA Water Parameters (mg/l) Ammonia (as N)0.189 Bicarbonate (as CaCO3)180 Bromide 10.5Carbonate (as CaCO3)<10.0Chloride42,100Nitrate/Nitrite (as N)0.134Sulfate 2,890Total Dissolved Solids 65,400 Additional Water Parameters Conductivity (µmhos/cm)111,000 Ion Balance percent (%)-5.30 pH@ 25°C 7.04 Field-measured Parameters pH 6.92Specific Conductivity (µmhos/cm)95,800 Oxygen Reduction Potential (millivolts)-275Dissolved Oxygen (mg/l)0.30Specific Gravity (unitless)1.048 Notes:bgs below ground surface°C degrees Celsius µg/l micrograms per liter µmhos/cm micromhos per centimeter mg/l milligrams per liter pCi/l picocuries per literMDAminimum detectable activityUAnalyte was analyzed for but not detected above the MDAK-40 Potassium 40Th-228 Thorium 228Th-230 Thorium 230 Th-232 Thorium 232 U-233/234 Uranium 233/234 U-235/236 Uranium 235/236 U-238 Uranium 238Ra-226 Radium 226 APPENDICES PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT Appendix A BOREHOLE LOG, WELL BUILD DIAGRAM, AND FIELD FORMS Appendix A BOREHOLE LOG, WELL BUILD DIAGRAM, AND FIELD FORMS WELL DEVELOPMENT RECORD Well Number: 1-1-·100Job No. A)'l,00\ �4 ProjectNrune: �v...,.,-17 So\ •. ,.:l,;,o,,,.r W-t.'-\ ()..>.v.Date(s): 1/IY/ ;z.o�o (_ //tr;/�o'l,o Comments: No�:. r(1)\..u...(Developed by: C. O...S�IX. \) of'·,\\ , � t "5\-o..-.. �'--Measuring Point (MP) of Well: TDC ),JScreened Interval (ft bgs): 2> 2. S - 3 5 5 Starting H 20 Level (BMP):Filter Pack Interval (ft bgs): 3 I C\ ·- 3 5 5 Casing Stickup TOC (ft):Development Method: �o-\\ Sv-�&, 1 f ..... M.g Casing Diameter On ID):Casirur Volume faal):QUALITY ASSURANCE Methods (describe) Clcanin2 Equipment: N�Page:_J._of '/.. b1 f>i.,,,v., P..--rt4..'J' .3 /,9'S i\<t:7Devdopment: I, '5' " ')( l D' 'oc-·�, · 3 ,. ')).-.c:.. r,. llo - A-.>L s, • ....-"-<-3" e �J.'-. �-u!o, p """"',p-Disoosal of Pur1re Water: Co""\-o:,"' tr·, -z::-<-!).. c:::>""-S'itc. Instruments (indicate make, model, id.) Water Level:Thermometer: 5C.."M.t' ll.A �....,_,(._oH Meter: I\ q,�.. Tr>\\ (t;c:ro / :;/.,, 'I (Q q Cf\ q Field Calibration: l /H /2-0Conductivity l'vleter: Se..� o..i. A. loo\.>-{ Field Calibration: 1/1flzoTurbidity Meter: So..-. "'-� ti.louVJ.... Field Calibration:Other: Iv A..Field Calibration:DEVELOPMENT MEASUREMENTS Date/Time\ l"f zo D%5f\\4 "20 \\1..0\IL.f Z.D 1'7.'?:.U111-I 'ti) 1�\0I ill./ ·". m�I 14 J.D li.\1<liJ 11/ 11.v lb\'5I 11-111.0 lli,15 \ 11'-lhD jl,1,1..i IJd/i., .�30, t'i(zo /k�Zi/!'1/1.0 11.?j-5.1 1'-1'/?.o llJ'-lilI 1'1 hD H,'\< I 11.dio 1�50I Nizo 1�55/ '1'1/-i.:, 1 /tii 5i Cumul.Vol.(gal) 2 10---20 ---- It>:> I (.Q5 -2R5-3 '11 ]-i-7 Temp.(C)11.lo'-i13,�'-\---12,11..------11.--':lt\1 .. ,1.DD-12, 9-l\� .t'l -Total Discharge (gal): 51'1-Field EC Color Turbidity( �5/c�) 7 "7'il<t.YD -i�J\. 1010.� �01t;·1.-�C?. °Kfbl,)V"\ 53J/,2.-------41 '1<'l�. le �i�121. ·3>---------------T�l't>'\,�� iro\.vl\.3(9.<if,13, 79S1�,'l'-i Bro"'"·.5'"�1.1---1'14S'f,o't �\,\. ·.;u� .-��0�3't.�13 �/0� I (i,7. 5---Casing Volumes Purged:Observations/ Comments: ?.,__r-.� \.,.J-r,..-t.v--bctD,....�t., Lut +-,.61�. .;, Abbreviations:ID = inside diameterBMP = below measuring point C = CelsiusBGS = below ground surface gal = gallonsCumul. Vol. = cumulative volume removed ft= feetin= inchesFolcnamc: Well dn-d.dwoe Otherr it '7,"i 5-, • zcP ---1.1..0-----7,o·i.,7.011,oq l.()'8°'- 3,1 (.01.,_-l(,"'--'--'-' Remarks �C>(Z.r - � <» .11/- I to:.�{)i,,r 11.n fi,,:'tk_ ll;tt-u..1 ,.sto.�� S'-'r_.'.y(--,�'"'" $WJ"'j .$'t?f,�t,t.,.,.(_a.,. \', ... u.-t-J... (}11,·,v;-1--1 Drwc; �;.2,-5 1-c.Si .:,:....� A.. .. ,1 ,... j'IA°"f ---�· .... \\-� A� '3'i s I £'-\ �.--L..J.. lv......_p11. 7� 'lPtY\ / D1l.>:: i/-?.�i, '-I.;;;,..._ I JJ rw:.. '-f2.l-f1,,,,i:.ru-.r /lo1.,;' �Q... .\ D TL,>:: /../1, ", L F'L;y.,, l'Z, I t:)TIJ;-'-fl,5'./OT�::. '11,�S 0 rw � 'i&.olorw -'1'o.1s ;:-1,.,,,,, rz-u- F4'1.v /Z,�1 "({-Oi,,,, /'2,5 S\.....,_ 1,. e,�'.t..- � LAw\.o/JP..c....,,/) D<...v'1 °" 1/1-r(u t7 i-.-I )f ;,., �f �I () Stantec 1.41 1.41 Groundwater Well No. or Sampling Point Sampling Team Members: Date Team Leader Groundwater Sampling Sheet EnergySoludons CL-EV-PR-004-F3 (Rev 2) Arrival Time 5',0 !lJ'uCt� � Assistant Description of Well Condition. (Note the condition of the well at the time of arrival, whether the well is secure (locked), general condition, note presence of cracks or any evidence oftampenng) r:C} N In good cond111on? '(J N ls the well fully operanonal? Y N Was the lock secure on arrival?_.,.. #Jk Y N e sandy or silty materials in the well? Weather Conditions Wind Direction Speed (est.) Cloud Cover Temperature Q-S::�6 �ve�,L __ 3=--=''----degrees F Yj;idence of tampering or vandalism? Y landing water in or around the well? Precip: Present Recent Rain Snow Other _.:_,M_c:..�.L.--Y racks or breaks in the concrete or casings? , 9 N Has the annual TD been detennined? Y N Has the annual pump/tubing inspection been performed?-Iv fC v {5)1s tl1e well in need of repairs? Y N ls there a marked change in pumping rate?...-rJ k Pre--Sampling Groundwater Field Analysis Results. Temperature: F C Specific Conductivity: µmbos/cm # Pre-pH Pre-Temp Pre-SC Pre-Eh Pre-Diss 0 Appearance of Groundwater Cb/( ( t4-.fu3 2 �.qJ_ (4-,<o� 3 6Ad-I �L�t Well Infonnation: for 2-inch well Purge Volwne Fonnula: Depth to well bottom Com): Survey factor for DTW probe: Calculated purge volwne: qs�� -.1.,� 0,3� �s-,=r -i�(®i � { is-a -�s--t0 .30 v, (gal)= 0.5 gaVft x (Deptbm -Depthm0) Depth to groundwater (Dm0): Adjusted Dm0: Time pump on: /J'+> Time pump off: c.1-ea"- Total purge volwne: !" flow rate of purge: --�('---------gallons/minute 2nd flow rate of purge: __ _.[L-________ gallons/minute Analytical laboratories and delivery infonnation: Rad Lab Chem Lab Collection Order Minimwn VoV Container --�A}k�'--a. Volatile Organics 3x40mVglass 2 ,J A:, b. Semi-VOCs --�---__ _,)<.._,,.__c. Metals/Inorgs 4 -�>( __ d.@-ss 2x500mVamber glass 500 ml plastic 500 ml plastic Sampling Team Leader's Initials: -----'&tJA'--'--"-''--=----- Delivery Time/Date: Delivery Time/Date: Collection Order Minimum VoV Container X e. Cations 5 00 ml plastic 6 X f Anions 500 ml plastic x �-0 g. Radiologies pgallons plastic 8 /JR h. Others ( descnbe) a ,_a.-Otbers: ____ ,,,_�tf:::.... ___________ _ Page_±J_ PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT Appendix B PHOTOGRAPHS Appendix B PHOTOGRAPHS Photographic Log Page 1 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:1 Drilling Date: 11/15/2019 Comments: 0 - 2 ft bgs Photograph ID:2 Drilling Date: 11/15/2019 Comments: 2 - 4.5 ft bgs Photographic Log Page 2 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:3 Drilling Date: 11/15/2019 Comments: 4.5 - 7 ft bgs Photograph ID:4 Drilling Date: 11/15/2019 Comments: 7 - 9.5 ft bgs Photographic Log Page 3 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:5 Drilling Date: 11/15/2019 Comments: 9.5 - 12 ft bgs Photograph ID:6 Drilling Date: 11/15/2019 Comments: 12 - 14.5 ft bgs Photographic Log Page 4 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:7 Drilling Date: 11/15/2019 Comments: 14.5 - 17 ft bgs Photograph ID:8 Drilling Date: 11/15/2019 Comments: 17 - 19.5 ft bgs Photographic Log Page 5 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:9 Drilling Date: 11/15/2019 Comments: 19.5 - 22 ft bgs Photograph ID:10 Drilling Date: 11/15/2019 Comments: 22 - 24.5 ft bgs Photographic Log Page 6 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:11 Drilling Date: 11/15/2019 Comments: 24.5 - 27 ft bgs Photograph ID:12 Drilling Date: 11/15/2019 Comments: 27 - 29.5 ft bgs Photographic Log Page 7 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:13 Drilling Date: 11/15/2019 Comments: 29.5 - 32 ft bgs Photograph ID:14 Drilling Date: 11/15/2019 Comments: 32 - 34.5 ft bgs Photographic Log Page 8 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:15 Drilling Date: 11/15/2019 Comments: 34.5 - 37 ft bgs Photograph ID:16 Drilling Date: 11/15/2019 Comments: 37 - 39.5 ft bgs Photographic Log Page 9 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:17 Drilling Date: 11/15/2019 Comments: 39.5 - 42 ft bgs Photograph ID:18 Drilling Date: 11/15/2019 Comments: 42 - 44.5 ft bgs Photographic Log Page 10 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:19 Drilling Date: 11/15/2019 Comments: 44.5 - 47 ft bgs Photograph ID:20 Drilling Date: 11/15/2019 Comments: 47 - 49.5 ft bgs Photographic Log Page 11 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:21 Drilling Date: 11/15/2019 Comments: 49.5 - 52 ft bgs Photograph ID:22 Drilling Date: 11/15/2019 Comments: 52 - 57 ft bgs Photographic Log Page 12 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:23 Drilling Date: 11/15/2019 Comments: 57 - 59.5 ft bgs Photograph ID:24 Drilling Date: 11/15/2019 Comments: 59.5 - 62 ft bgs Photographic Log Page 13 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:25 Drilling Date: 11/15/2019 Comments: 62 - 64.5 ft bgs Photograph ID:26 Drilling Date: 11/15/2019 Comments: 64.5 - 67 ft bgs Photographic Log Page 14 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:27 Drilling Date: 11/15/2019 Comments: 67 - 69.5 ft bgs Photograph ID:28 Drilling Date: 11/15/2019 Comments: 69.5 - 71 ft bgs Photographic Log Page 15 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:29 Drilling Date: 11/15/2019 Comments: 71 - 77 ft bgs Photograph ID:30 Drilling Date: 11/15/2019 Comments: 77 - 79.5 ft bgs Photographic Log Page 16 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:31 Drilling Date: 11/15/2019 Comments: 79.5 - 82 ft bgs Photograph ID:32 Drilling Date: 11/15/2019 Comments: 82 - 84.5 ft bgs Photographic Log Page 17 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:33 Drilling Date: 11/15/2019 Comments: 84.5 - 87 ft bgs Photograph ID:34 Drilling Date: 11/15/2019 Comments: 87 - 89.5 ft bgs Photographic Log Page 18 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:35 Drilling Date: 11/15/2019 Comments: 89.5 - 92 ft bgs Photograph ID:36 Drilling Date: 11/15/2019 Comments: 92 - 94.5 ft bgs Photographic Log Page 19 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:37 Drilling Date: 11/15/2019 Comments: 94.5 - 97 ft bgs Photograph ID:38 Drilling Date: 11/15/2019 Comments: 97 - 99.5 ft bgs Photographic Log Page 20 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:39 Drilling Date: 11/15/2019 Comments: 99.5 - 102 ft bgs Photograph ID:40 Drilling Date: 11/15/2019 Comments: 102 - 104.5 ft bgs Photographic Log Page 21 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:41 Drilling Date: 11/15/2019 Comments: 104.5 - 107 ft bgs Photograph ID:42 Drilling Date: 11/15/2019 Comments: 107 - 109.5 ft bgs Photographic Log Page 22 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:43 Drilling Date: 11/15/2019 Comments: 109 - 112.5 ft bgs Photograph ID:44 Drilling Date: 11/15/2019 Comments: 112 - 114.5 ft bgs Photographic Log Page 23 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:45 Drilling Date: 11/15/2019 Comments: 114.5 - 117 ft bgs Photograph ID:46 Drilling Date: 11/15/2019 Comments: 117 - 119.5 ft bgs Photographic Log Page 24 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:47 Drilling Date: 11/15/2019 Comments: 119.5 - 122 ft bgs Photograph ID:48 Drilling Date: 11/15/2019 Comments: 122 - 124.5 ft bgs Photographic Log Page 25 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:49 Drilling Date: 11/18/2019 Comments: 124.5 - 127 ft bgs Photograph ID:50 Drilling Date: 11/18/2019 Comments: 127 - 129.5 ft bgs Photographic Log Page 26 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:51 Drilling Date: 11/18/2019 Comments: 129.5 - 132 ft bgs Photograph ID:52 Drilling Date: 11/18/2019 Comments: 132 - 134.5 ft bgs Photographic Log Page 27 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:53 Drilling Date: 11/18/2019 Comments: 134.5 - 137 ft bgs Photograph ID:54 Drilling Date: 11/18/2019 Comments: 137 - 139.5 ft bgs Photographic Log Page 28 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:55 Drilling Date: 11/18/2019 Comments: 139.5 - 142 ft bgs Photograph ID:56 Drilling Date: 11/18/2019 Comments: 142 - 144.5 ft bgs Photographic Log Page 29 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:57 Drilling Date: 11/18/2019 Comments: 144.5 - 147 ft bgs Photograph ID:58 Drilling Date: 11/18/2019 Comments: 147 - 149.5 ft bgs Photographic Log Page 30 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:59 Drilling Date: 11/18/2019 Comments: 149.5 - 152 ft bgs Photograph ID:60 Drilling Date: 11/18/2019 Comments: 152 - 154.5 ft bgs Photographic Log Page 31 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:61 Drilling Date: 11/18/2019 Comments: 154.5 - 157 ft bgs Photograph ID:62 Drilling Date: 11/18/2019 Comments: 157 - 159.5 ft bgs Photographic Log Page 32 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:63 Drilling Date: 11/18/2019 Comments: 159.5 - 162 ft bgs Photograph ID:64 Drilling Date: 11/18/2019 Comments: 162 - 164.5 ft bgs Photographic Log Page 33 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:65 Drilling Date: 11/18/2019 Comments: 164.5 - 167 ft bgs Photograph ID:66 Drilling Date: 11/18/2019 Comments: 167 - 169.5 ft bgs Photographic Log Page 34 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:67 Drilling Date: 11/18/2019 Comments: 169.5 - 172 ft bgs Photograph ID:68 Drilling Date: 11/18/2019 Comments: 172 - 174.5 ft bgs Photographic Log Page 35 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:69 Drilling Date: 11/18/2019 Comments: 174.5 - 177 ft bgs Photograph ID:70 Drilling Date: 11/18/2019 Comments: 177 - 179.5 ft bgs Photographic Log Page 36 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:71 Drilling Date: 11/18/2019 Comments: 179.5 - 182 ft bgs; bag broke, sample fell out Photograph ID:72 Drilling Date: 11/18/2019 Comments: 182 - 184.5 ft bgs Photographic Log Page 37 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:73 Drilling Date: 11/18/2019 Comments: 184.5 - 187 ft bgs Photograph ID:74 Drilling Date: 11/18/2019 Comments: 187 - 189.5 ft bgs Photographic Log Page 38 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:75 Drilling Date: 11/18/2019 Comments: 189.5 - 192 ft bgs Photograph ID:76 Drilling Date: 11/18/2019 Comments: 192 - 194.5 ft bgs Photographic Log Page 39 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:77 Drilling Date: 11/18/2019 Comments: 194.5 - 197 ft bgs Photograph ID:78 Drilling Date: 11/18/2019 Comments: 197 - 199.5 ft bgs Photographic Log Page 40 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:79 Drilling Date: 11/18/2019 Comments: 199.5 - 202 ft bgs Photograph ID:80 Drilling Date: 11/18/2019 Comments: 202 - 204.5 ft bgs Photographic Log Page 41 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:81 Drilling Date: 11/18/2019 Comments: 204.5 - 207 ft bgs Photograph ID:82 Drilling Date: 11/18/2019 Comments: 207 - 209.5 ft bgs Photographic Log Page 42 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:83 Drilling Date: 11/18/2019 Comments: 209.5 - 212 ft bgs Photograph ID:84 Drilling Date: 11/18/2019 Comments: 212 - 214.5 ft bgs Photographic Log Page 43 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:85 Drilling Date: 11/18/2019 Comments: 214.5 - 217 ft bgs Photograph ID:86 Drilling Date: 11/18/2019 Comments: 217 - 219.5 ft bgs Photographic Log Page 44 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:87 Drilling Date: 11/18/2019 Comments: 219.5 - 222 ft bgs Photograph ID:88 Drilling Date: 11/18/2019 Comments: 222 - 224.5 ft bgs Photographic Log Page 45 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:89 Drilling Date: 11/18/2019 Comments: 224.5 - 227 ft bgs Photograph ID:90 Drilling Date: 11/19/2019 Comments: 227 - 229.5 ft bgs Photographic Log Page 46 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:91 Drilling Date: 11/19/2019 Comments: 229.5 - 232 ft bgs Photograph ID:92 Drilling Date: 11/19/2019 Comments: 232 - 234.5 ft bgs Photographic Log Page 47 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:93 Drilling Date: 11/19/2019 Comments: 234.5 - 237 ft bgs Photograph ID:94 Drilling Date: 11/19/2019 Comments: 237 - 239.5 ft bgs Photographic Log Page 48 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:95 Drilling Date: 11/19/2019 Comments: 239.5 - 242 ft bgs Photograph ID:96 Drilling Date: 11/19/2019 Comments: 242 - 244.5 ft bgs Photographic Log Page 49 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:97 Drilling Date: 11/19/2019 Comments: 244.5 - 247 ft bgs Photograph ID:98 Drilling Date: 11/19/2019 Comments: 247 - 249.5 ft bgs - No Recovery Photographic Log Page 50 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:99 Drilling Date: 11/19/2019 Comments: 249.5 - 252 ft bgs Photograph ID:100 Drilling Date: 11/19/2019 Comments: 252 - 254.5 ft bgs Photographic Log Page 51 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:101 Drilling Date: 11/19/2019 Comments: 254.5 - 257 ft bgs Photograph ID:102 Drilling Date: 11/19/2019 Comments: 257 - 259.5 ft bgs Photographic Log Page 52 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:103 Drilling Date: 11/19/2019 Comments: 259.5 - 262 ft bgs Photograph ID:104 Drilling Date: 11/19/2019 Comments: 262 - 264.5 ft bgs Photographic Log Page 53 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:105 Drilling Date: 11/19/2019 Comments: 264.5 - 267 ft bgs Photograph ID:106 Drilling Date: 11/19/2019 Comments: 267 - 269.5 ft bgs Photographic Log Page 54 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:107 Drilling Date: 11/19/2019 Comments: 269.5 - 272 ft bgs Photograph ID:108 Drilling Date: 11/19/2019 Comments: 272 - 274.5 ft bgs Photographic Log Page 55 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:109 Drilling Date: 11/19/2019 Comments: 274.5 - 277 ft bgs Photograph ID:110 Drilling Date: 11/19/2019 Comments: 277 - 279.5 ft bgs Photographic Log Page 56 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:111 Drilling Date: 11/19/2019 Comments: 279.5 - 282 ft bgs Photograph ID:112 Drilling Date: 11/19/2019 Comments: 282 - 284.5 ft bgs Photographic Log Page 57 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:113 Drilling Date: 11/19/2019 Comments: 284.5 - 287 ft bgs Photograph ID:114 Drilling Date: 11/19/2019 Comments: 287 - 289.5 ft bgs Photographic Log Page 58 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:115 Drilling Date: 11/19/2019 Comments: 289.5 - 292 ft bgs Photograph ID:116 Drilling Date: 11/19/2019 Comments: 292 - 294.5 ft bgs Photographic Log Page 59 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:117 Drilling Date: 11/19/2019 Comments: 294.5 - 297 ft bgs Photograph ID:118 Drilling Date: 11/20/2019 Comments: 297 - 299.5 ft bgs Photographic Log Page 60 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:119 Drilling Date: 11/20/2019 Comments: 299.5 - 302 ft bgs Photograph ID:120 Drilling Date: 11/20/2019 Comments: 302 - 304.5 ft bgs Photographic Log Page 61 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:121 Drilling Date: 11/20/2019 Comments: 304.5 - 307 ft bgs Photograph ID:122 Drilling Date: 11/20/2019 Comments: 307 - 309.5 ft bgs Photographic Log Page 62 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:123 Drilling Date: 11/20/2019 Comments: 309.5 - 312 ft bgs Photograph ID:124 Drilling Date: 11/20/2019 Comments: 312 - 314.5 ft bgs Photographic Log Page 63 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:125 Drilling Date: 11/20/2019 Comments: 314.5 - 317 ft bgs Photograph ID:126 Drilling Date: 11/20/2019 Comments: 317 - 319.5 ft bgs Photographic Log Page 64 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:127 Drilling Date: 11/20/2019 Comments: 319.5 - 322 ft bgs Photograph ID:128 Drilling Date: 11/20/2019 Comments: 322 - 324.5 ft bgs Photographic Log Page 65 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:129 Drilling Date: 11/20/2019 Comments: 324.5 - 327 ft bgs Photograph ID:130 Drilling Date: 11/20/2019 Comments: 327 - 329.5 ft bgs Photographic Log Page 66 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:131 Drilling Date: 11/20/2019 Comments: 329.5 - 332 ft bgs Photograph ID:132 Drilling Date: 11/20/2019 Comments: 332 - 334.5 ft bgs Photographic Log Page 67 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:133 Drilling Date: 11/20/2019 Comments: 334.5 - 337 ft bgs Photograph ID:134 Drilling Date: 11/21/2019 Comments: 337 - 339.5 ft bgs Photographic Log Page 68 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:135 Drilling Date: 11/21/2019 Comments: 339.5 - 342 ft bgs Photograph ID:136 Drilling Date: 11/21/2019 Comments: 342 - 344.5 ft bgs Photographic Log Page 69 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:137 Drilling Date: 11/21/2019 Comments: 344.5 - 347 ft bgs Photograph ID:138 Drilling Date: 11/21/2019 Comments: 347 - 349.5 ft bgs Photographic Log Page 70 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:139 Drilling Date: 11/21/2019 Comments: 349.5 - 352 ft bgs Photograph ID:140 Drilling Date: 11/21/2019 Comments: 352 - 354.5 ft bgs Photographic Log Page 71 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:141 Drilling Date: 11/21/2019 Comments: 354.5 - 357 ft bgs Photograph ID:142 Drilling Date: 11/21/2019 Comments: 357 - 359.5 ft bgs Photographic Log Page 72 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:143 Drilling Date: 11/21/2019 Comments: 359.5 - 362 ft bgs Photograph ID:144 Drilling Date: 11/21/2019 Comments: 362 - 364.5 ft bgs Photographic Log Page 73 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:145 Drilling Date: 11/21/2019 Comments: 364.5 - 367 ft bgs Photograph ID:146 Drilling Date: 11/21/2019 Comments: 367 - 369.5 ft bgs Photographic Log Page 74 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:147 Drilling Date: 11/21/2019 Comments: 369.5 - 372 ft bgs Photograph ID:148 Drilling Date: 11/21/2019 Comments: 372 - 374.5 ft bgs Photographic Log Page 75 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:149 Drilling Date: 11/21/2019 Comments: 374.5 - 377 ft bgs Photograph ID:150 Drilling Date: 11/21/2019 Comments: 377 - 379.5 ft bgs Photographic Log Page 76 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:151 Drilling Date: 11/21/2019 Comments: 379.5 - 382 ft bgs Photograph ID:152 Drilling Date: 11/21/2019 Comments: 382 - 384.5 ft bgs Photographic Log Page 77 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:153 Drilling Date: 11/21/2019 Comments: 384.5 - 387 ft bgs Photograph ID:154 Drilling Date: 11/21/2019 Comments: 387 - 389.5 ft bgs Photographic Log Page 78 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:155 Drilling Date: 11/21/2019 Comments: 389.5 - 392 ft bgs Photograph ID:156 Drilling Date: 11/21/2019 Comments: 392 - 394.5 ft bgs Photographic Log Page 79 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:157 Drilling Date: 11/22/2019 Comments: 394.5 - 397 ft bgs Photograph ID:158 Drilling Date: 11/22/2019 Comments: 397 - 399.5 ft bgs Photographic Log Page 80 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:159 Drilling Date: 11/22/2019 Comments: 399.5 - 402 ft bgs Photograph ID:160 Drilling Date: 11/22/2019 Comments: 402 - 404.5 ft bgs Photographic Log Page 81 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:161 Drilling Date: 11/22/2019 Comments: 404.5 - 407 ft bgs Photograph ID:162 Drilling Date: 11/22/2019 Comments: 407 - 409.5 ft bgs Photographic Log Page 82 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:163 Drilling Date: 11/22/2019 Comments: 409.5 - 212 ft bgs Photograph ID:164 Drilling Date: 11/22/2019 Comments: 412- 414.5 ft bgs Photographic Log Page 83 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:165 Drilling Date: 11/22/2019 Comments: 414.5 - 417 ft bgs Photograph ID:166 Drilling Date: 11/22/2019 Comments: 417 - 419.5 ft bgs Photographic Log Page 84 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:167 Drilling Date: 11/22/2019 Comments: 419.5 - 422 ft bgs Photograph ID:168 Drilling Date: 11/22/2019 Comments: 422 - 424.5 ft bgs Photographic Log Page 85 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:169 Drilling Date: 11/22/2019 Comments: 424.5 - 427 ft bgs Photograph ID:170 Drilling Date: 11/22/2019 Comments: 427 - 429.5 ft bgs Photographic Log Page 86 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:171 Drilling Date: 11/22/2019 Comments: 429.5 - 432 ft bgs Photograph ID:172 Drilling Date: 11/22/2019 Comments: 432 - 434.5 ft bgs Photographic Log Page 87 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:173 Drilling Date: 11/22/2019 Comments: 434.5 - 437 ft bgs Photograph ID:174 Drilling Date: 11/25/2019 Comments: 437 - 440 ft bgs Photographic Log Page 88 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:175 Drilling Date: 11/25/2019 Comments: 440 - 442.5 ft bgs Photograph ID:176 Drilling Date: 11/25/2019 Comments: 442.5 - 445 ft bs Photographic Log Page 89 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:177 Drilling Date: 11/25/2019 Comments: 445 - 447.5 ft bgs Photograph ID:178 Drilling Date: 11/25/2019 Comments: 447.5 - 450 ft bgs Photographic Log Page 90 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:179 Drilling Date: 11/25/2019 Comments: 450 - 452 ft bgs Photograph ID:180 Drilling Date: 11/25/2019 Comments: 452 - 454.5 ft bgs Photographic Log Page 91 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:181 Drilling Date: 11/25/2019 Comments: 454.5 - 457 ft bgs Photograph ID:182 Drilling Date: 11/25/2019 Comments: 457 - 460 ft bgs Photographic Log Page 92 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:183 Drilling Date: 11/25/2019 Comments: 460 - 462.5 ft bgs Photograph ID:184 Drilling Date: 11/25/2019 Comments: 462.5 - 465 ft bgs Photographic Log Page 93 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:185 Drilling Date: 11/25/2019 Comments: 465 - 467.5 ft bgs Photograph ID:186 Drilling Date: 11/25/2019 Comments: 467.5 - 470 ft bgs Photographic Log Page 94 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:187 Drilling Date: 11/26/2019 Comments: 470 - 472 ft bgs Photograph ID:188 Drilling Date: 11/26/2019 Comments: 472 - 474.5 ft bgs Photographic Log Page 95 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:189 Drilling Date: 11/26/2019 Comments: 474.5 - 477 ft bgs Photograph ID:190 Drilling Date: 11/26/2019 Comments: 477 - 479 ft bgs Photographic Log Page 96 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:191 Drilling Date: 11/26/2019 Comments: 479 - 481.5 ft bgs Photograph ID:192 Drilling Date: 11/26/2019 Comments: 481.5 - 484 ft bgs Photographic Log Page 97 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:193 Drilling Date: 11/26/2019 Comments: 484 - 486.5 ft bgs Photograph ID:194 Drilling Date: 11/26/2019 Comments: 486.5 - 489 ft bgs Photographic Log Page 98 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:195 Drilling Date: 11/26/2019 Comments: 489 - 491.5 ft bgs Photograph ID:196 Drilling Date: 11/26/2019 Comments: 491.5 - 494 ft bgs Photographic Log Page 99 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:197 Drilling Date: 11/26/2019 Comments: 494 - 497 ft bgs Photograph ID:198 Drilling Date: 11/26/2019 Comments: 497 - 499.5 ft bgs Photographic Log Page 100 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:199 Drilling Date: 11/26/2019 Comments: 499.5 - 502 ft bgs Photograph ID:200 Drilling Date: 11/26/2019 Comments: 502 - 504.5 ft bgs Photographic Log Page 101 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:201 Drilling Date: 11/26/2019 Comments: 504.5 - 507 ft bgs Photograph ID:202 Drilling Date: 11/26/2019 Comments: 507 - 510 ft bgs Photographic Log Page 102 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:203 Drilling Date: 11/26/2019 Comments: 510 - 512.5 ft bgs Photograph ID:204 Drilling Date: 11/26/2019 Comments: 512.5 - 515 ft bgs Photographic Log Page 103 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:205 Drilling Date: 11/26/2019 Comments: 515 - 517.5 ft bgs Photograph ID:206 Drilling Date: 11/26/2019 Comments: 517.5 - 520 ft bgs Photographic Log Page 104 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:207 Drilling Date: 11/26/2019 Comments: 520 - 522.5 ft bgs Photograph ID:208 Drilling Date: 11/26/2019 Comments: 522.5 - 525 ft bgs Photographic Log Page 105 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:209 Drilling Date: 11/26/2019 Comments: 525 - 527 ft bgs Photograph ID:210 Drilling Date: 11/26/2019 Comments: 527 - 529.5 ft bgs Photographic Log Page 106 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:211 Drilling Date: 11/26/2019 Comments: 529.5 - 532 ft bgs Photograph ID:212 Drilling Date: 11/26/2019 Comments: 532 - 534.5 ft bgs Photographic Log Page 107 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:213 Drilling Date: 11/26/2019 Comments: 534.5 - 537 ft bgs Photograph ID:214 Drilling Date: 12/2/2019 Comments: 537 - 539.5 ft bgs Photographic Log Page 108 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:215 Drilling Date: 12/2/2019 Comments: 539.5 - 542 ft bgs Photograph ID:216 Drilling Date: 12/2/2019 Comments: 542 - 544.5 ft bgs Photographic Log Page 109 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:217 Drilling Date: 12/2/2019 Comments: 544.5 - 547 ft bgs Photograph ID:218 Drilling Date: 12/2/2019 Comments: 547 - 549.5 ft bgs Photographic Log Page 110 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:219 Drilling Date: 12/2/2019 Comments: 549.5 - 552 ft bgs Photograph ID:220 Drilling Date: 12/2/2019 Comments: 552 - 554.5 ft bgs Photographic Log Page 111 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:221 Drilling Date: 12/2/2019 Comments: 554.5 - 557 ft bgs Photograph ID:222 Drilling Date: 12/3/2019 Comments: 557 - 559.5 ft bgs Photographic Log Page 112 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:223 Drilling Date: 12/3/2019 Comments: 559.5 - 562 ft bgs Photograph ID:224 Drilling Date: 12/3/2019 Comments: 562 - 564.5 ft bgs Photographic Log Page 113 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:225 Drilling Date: 12/3/2019 Comments: 564.5 - 567 ft bgs Photograph ID:226 Drilling Date: 12/3/2019 Comments: 567 - 569.5 ft bgs Photographic Log Page 114 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:227 Drilling Date: 12/3/2019 Comments: 569.5 - 572 ft bgs Photograph ID:228 Drilling Date: 12/3/2019 Comments: 572 - 574.5 ft bgs Photographic Log Page 115 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:229 Drilling Date: 12/3/2019 Comments: 574.5 - 577 ft bgs Photograph ID:230 Drilling Date: 12/3/2019 Comments: 577 - 579.5 ft bgs Photographic Log Page 116 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:231 Drilling Date: 12/3/2019 Comments: 579.5 - 582 ft bgs Photograph ID:232 Drilling Date: 12/3/2019 Comments: 582 - 584.5 ft bgs Photographic Log Page 117 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:233 Drilling Date: 12/3/2019 Comments: 584.5 - 587 ft bgs Photograph ID:234 Drilling Date: 12/3/2019 Comments: 587 - 589.5 ft bgs Photographic Log Page 118 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:235 Drilling Date: 12/3/2019 Comments: 589.5 - 592 ft bgs Photograph ID:236 Drilling Date: 12/3/2019 Comments: 592 - 594.5 ft bgs Photographic Log Page 119 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:237 Drilling Date: 12/3/2019 Comments: 594.5 - 597 ft bgs Photograph ID:238 Drilling Date: 12/4/2019 Comments: 597 - 599.5 ft bgs Photographic Log Page 120 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:239 Drilling Date: 12/4/2019 Comments: 599.5 - 602 ft bgs Photograph ID:240 Drilling Date: 12/4/2019 Comments: 602 - 604.5 ft bgs Photographic Log Page 121 of 121 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:241 Drilling Date: 12/4/2019 Comments: 604.5 - 607 ft bgs Photograph ID:242 Drilling Date: 12/5/2019 Comments: 607 - 615 ft bgs; Breccia/Rock flour Photographic Log Page 1 of 6 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:1 Drilling Date: 11/26/2019 Comments: Sonic drill rig and support truck set up on I-1-700. Core laid down under tarps covered by snow. Photograph ID:2 Drilling Date: 1/31/2020 Comments: End cap placed at bottom of well screen prior to lowering down borehole. Photographic Log Page 2 of 6 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:3 Drilling Date: 12/12/2019 Comments: Stainless steel well screen specifics. Photograph ID:4 Drilling Date: 12/12/2019 Comments: Stainless steel well blank casing specifics. Photographic Log Page 3 of 6 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:5 Drilling Date: 12/12/2019 Comments: Stainless steel well blank casing laid out for well build installation. Photograph ID:6 Drilling Date: 12/12/2019 Comments: Sand used for filter pack around screen. Photographic Log Page 4 of 6 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:7 Drilling Date: 12/12/2019 Comments: Sand used for filter pack around screen. Photograph ID:8 Drilling Date: 12/12/2019 Comments: Bentonite chips used for bentonite seal. Photographic Log Page 5 of 6 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:9 Drilling Date: 12/13/2019 Comments: Grout used for annular seal. Photograph ID:10 Drilling Date: 12/13/2019 Comments: Concrete used for surface seal. Photographic Log Page 6 of 6 Client:EnergySolutions, LLC Project:Basal Aquifer Characterization Drilling Site Name:Clive Facility Site Location:I-1-700 Photograph ID:11 Drilling Date: 1/16/2020 Comments: Surface completion of I-1-700 (photo taken during well development set up) PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT Appendix C GEOTECHNICAL LABORATORY REPORT Appendix C GEOTECHNICAL LABORATORY REPORT Water Content and Unit Weight of Soil (In General Accordance with ASTM D7263 Method B and D2216)© IGES 2004, 2020 Project: No: Location: Date: By: Boring No.I-1-700 I-1-700 I-1-700 I-1-700 I-1-700 I-1-700 I-1-700 I-1-700 Sample: Depth (ft.):247.0-247.5 247.5-248.0 248.0-248.5 297.0-297.5 297.5-298.0 298.0-298.5 337.0-337.5 337.5-338.0 Sample height, H (in)5.402 5.838 5.433 5.939 3.018 5.948 5.124 5.031 Sample diameter, D (in)2.424 2.417 2.398 2.441 2.432 2.432 2.383 2.378 Sample volume, V (ft3) 0.0144 0.0155 0.0142 0.0161 0.0081 0.0160 0.0132 0.0129 Mass rings + wet soil (g)1010.32 1145.56 1021.85 1061.63 1165.19 1015.51 955.73 904.34 Mass rings/tare (g)205.18 204.31 207.97 204.47 757.31 202.42 279.00 278.36 Moist soil, Ws (g) 805.14 941.25 813.88 857.16 407.88 813.09 676.73 625.98 Moist unit wt., m (pcf)123.03 133.87 126.36 117.49 110.83 112.11 112.81 106.73 Wet soil + tare (g)356.47 470.32 385.11 402.79 329.56 362.35 391.51 345.68 Dry soil + tare (g)309.94 423.99 341.49 336.78 278.54 309.66 336.89 274.06 Tare (g)121.93 128.51 123.63 126.68 127.94 127.97 120.75 121.26 24.7 15.7 20.0 31.4 33.9 29.0 25.3 46.9 98.6 115.7 105.3 89.4 82.8 86.9 90.1 72.7 Entered by:___________ Reviewed:___________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[MDv1.xlsx]1 EnergySolutions M03271-001 Basal Aquifer Investigation 1/10/2020 Dry Unit Wt., d (pcf) Sa m p l e In f o . Un i t W e i g h t I n f o . Wa t e r Co n t e n t Water Content, w (%) Wa t e r o b s e r v e d l e a k i n g f r o m t h e t u b e s a m p l e . BF/EH/KK Wa t e r o b s e r v e d l e a k i n g f r o m t h e t u b e s a m p l e . Co m m e n t s : Water Content and Unit Weight of Soil (In General Accordance with ASTM D7263 Method B and D2216)© IGES 2004, 2020 Project: No: Location: Date: By: Boring No.I-1-700 I-1-700 I-1-700 I-1-700 Sample: Depth (ft.):338.0-338.5 377.0-377.5 377.5-378.0 378.0-378.5 Sample height, H (in)5.491 2.726 2.929 5.890 Sample diameter, D (in)2.388 2.400 2.404 2.398 Sample volume, V (ft3) 0.0142 0.0071 0.0077 0.0154 Mass rings + wet soil (g)957.82 371.42 1158.90 785.75 Mass rings/tare (g)278.93 0.00 757.31 0.00 Moist soil, Ws (g) 678.89 371.42 401.59 785.75 Moist unit wt., m (pcf)105.16 114.74 115.08 112.53 Wet soil + tare (g)382.09 362.31 314.75 356.51 Dry soil + tare (g)308.47 327.00 262.99 291.27 Tare (g)140.36 219.88 112.21 125.04 43.8 33.0 34.3 39.2 73.1 86.3 85.7 80.8 Entered by:___________ Reviewed:___________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[MDv1.xlsx]2 Sa m p l e In f o . EnergySolutions M03271-001 Basal Aquifer Investigation 1/10/2020 BF/EH/KK Un i t W e i g h t I n f o . Wa t e r Co n t e n t Water Content, w (%) Dry Unit Wt., d (pcf) Specific Gravity of Soil Solids by Water Pycnometer (ASTM D854)© IGES 2005, 2020 Project: No: Location: Date: By: I-1-700 I-1-700 I-1-700 I-1-700 I-1-700 I-1-700 247.0-248.5 297.5-298.0 297.0-298.5 337.0-338.5 377.5-378.0 377.0-378.5 Not req. Not req. Not req. Not req. Not req. Not req. A A A A A A 100 100 100 100 100 100 7 3 8 3 5 5 169.53 170.54 166.67 170.57 168.65 168.65 725.43 714.08 712.18 695.21 710.2 695.25 21.1 20.6 21.1 20.8 20.6 20.8 668.14 669.31 665.36 669.29 667.31 667.29 419.96 484.86 410.46 377.72 400.16 369.23 326.41 410.39 332.29 333.15 330.85 324.16 93.55 74.47 78.17 44.57 69.31 45.07 2.580 2.508 2.493 2.390 2.623 2.634 0.99977 0.99987 0.99977 0.99983 0.99987 0.99983 2.579 2.508 2.493 2.390 2.623 2.633 Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[Gsv1.0.xlsx]1 Mass of tare + dry soil (g) Mass of tare (g) Mass of pycnometer (g) Mass of pycnometer, soil, and water, Mws,t (g) Temperature, T t (°C) Mass of pycnometer and water at test temperature, Mpw,t (g) Reviewed by:___________ Drill hole / Sample: Sample: Depth (ft) Temperature coefficient, K Specific gravity of soil solids at 20°C, G20°C Method Material passing No. 4 sieve, P (%) Pycnometer No. Mass of soil, M s (g) Specific gravity of soil solids at test temperature, G t Co m m e n t s : Entered by:___________ Apparent specific gravity of solids retained on No. 4, G1@20°C Average specific gravity at 20°C, Gavg @20°C EnergySolutions M03271-001 Basal Aquifer Investigation 1/13/2020 Engineering Classification BF In i t i a l s p e c i f i c g r a v i t y t e s t p e r f o r m e d o n l y o n t h e m i d d l e d e p t h in t e r v a l s a m p l e . A v e r a g e s p e c i f i c g r a v i t y v a l u e i s 2 . 6 3 1 In i t i a l s p e c i f i c g r a v i t y t e s t p e r f o r m e d o n l y o n t h e m i d d l e d e p t h in t e r v a l s a m p l e . A v e r a g e s p e c i f i c g r a v i t y v a l u e i s 2 . 4 9 9 Porosity of Soil © IGES 2007, 2020 Project: No: Location: Date: By: Boring No.I-1-700 I-1-700 I-1-700 I-1-700 Sample: Depth (ft.):247.0-248.5 297.0-298.5 337.0-338.5 377.0-378.5 Sample height, H (in)16.673 14.905 15.646 11.545 Sample diameter, D (in)2.413 2.435 2.383 2.401 Mass rings + wet soil (g)3177.73 3242.33 2817.89 2316.07 Mass rings/tare (g)617.46 1164.20 836.29 757.31 Moist soil, Ws (g) 2560.27 2078.13 1981.60 1558.76 Moist unit wt., m (pcf)127.9 114.1 108.2 113.6 Wet soil + tare (g)1211.90 1094.70 1119.28 1033.57 Dry soil + tare (g)1075.42 924.98 919.42 881.26 Tare (g)374.07 382.59 382.37 457.13 Water content (%) 19.5 31.3 37.2 35.9 Specific gravity of solids, Gs 2.579 2.499 2.390 2.631 Void ratio, e 0.504 0.796 0.892 0.964 Porosity, n 0.335 0.443 0.472 0.491 33.5 44.3 47.2 49.1 33.4 43.5 47.0 48.1 0.1 0.8 0.2 1.0 Entered by:___________ Reviewed:___________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[PORv1.xlsx]1 EnergySolutions M03271-001 Basal Aquifer Investigation 1/13/2020 Sa m p l e In f o . EH/KK/BF Un i t W e i g h t D a t a Wa t e r Co n t e n t Total Soil Porosity, n (%) Water Porosity, w (%) Air Porosity, a (%) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data Split:o Moist soil + tare (g):- 350.61 Dry soil + tare (g):- 319.84 Moist Dr Tare (g):- 128.53 Total sample wt. (g):222.08 191.31 Water content (%): 0.0 16.1 0.00 0.00 -0.00 Split fraction: 1.000 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 - 3/8" -9.5 100.0 o.4 0.82 4.75 99.6 o.10 1.68 2 99.1 o.20 2.64 0.85 98.6 o.40 3.70 0.425 98.1 o.60 5.48 0.25 97.1 o.100 21.35 0.15 88.8 o.140 78.00 0.106 59.2 o.200 134.50 0.075 29.7 Gravel %:0.4 Sand %:69.9 Fines %:29.7 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]1 I-1-700 87-89' Light brown silty sand BF EnergySolutions M03271-001 Basal Aquifer Investigation 12/26/2019 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):331.15 414.97 Split sieve:3/8"Dry soil + tare (g):314.51 375.50 Moist Dr Tare (g):128.58 124.48 Total sample wt. (g):2562.54 2222.37 Water content (%): 8.9 15.7 +3/8" Coarse fraction (g):149.21 136.95 -3/8" Split fraction (g):290.49 251.02 Split fraction: 0.938 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 100.0 3/4" 20.08 19 99.1 3/8" 136.95 9.5 93.8 ←Split o.4 30.88 4.75 82.3 o.10 85.09 2 62.0 o.20 134.68 0.85 43.5 o.40 166.66 0.425 31.5 o.60 186.16 0.25 24.2 o.100 203.91 0.15 17.6 o.140 211.43 0.106 14.8 o.200 218.62 0.075 12.1 Gravel %:17.7 Sand %:70.2 Fines %:12.1 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]2 M03271-001 Basal Aquifer Investigation 107-109' 12/26/2019 Brown clayey sand with gravelBF EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):136.68 436.92 Split sieve:3/8"Dry soil + tare (g):136.08 349.82 Moist Dr Tare (g):128.50 126.86 Total sample wt. (g):2183.34 1571.47 Water content (%): 7.9 39.1 +3/8" Coarse fraction (g):7.01 6.50 -3/8" Split fraction (g):310.06 222.96 Split fraction: 0.996 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 100.0 3/8" 6.50 9.5 99.6 ←Split o.4 -4.75 99.6 o.10 0.54 2 99.3 o.20 1.26 0.85 99.0 o.40 2.18 0.425 98.6 o.60 6.72 0.25 96.6 o.100 46.27 0.15 78.9 o.140 83.41 0.106 62.3 o.200 142.11 0.075 36.1 Gravel %:0.4 Sand %:63.5 Fines %:36.1 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]3 M03271-001 Basal Aquifer Investigation 227-229' 12/24/2019 Brown silty sand BF EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):380.30 571.90 Split sieve:3/8"Dry soil + tare (g):364.95 494.60 Moist Dr Tare (g):224.10 128.68 Total sample wt. (g):1961.20 1628.46 Water content (%): 10.9 21.1 +3/8" Coarse fraction (g):122.19 110.18 -3/8" Split fraction (g):443.22 365.92 Split fraction: 0.932 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 100.0 3/4" 35.88 19 97.8 3/8" 110.18 9.5 93.2 ←Split o.4 32.42 4.75 85.0 o.10 77.93 2 73.4 o.20 118.12 0.85 63.1 o.40 150.71 0.425 54.8 o.60 183.78 0.25 46.4 o.100 236.50 0.15 33.0 o.140 268.67 0.106 24.8 o.200 301.12 0.075 16.5 Gravel %:15.0 Sand %:68.5 Fines %:16.5 Comments: Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]4 These results are in nonconformance with Method D6913 because the minimum dry mass was not met. M03271-001 Basal Aquifer Investigation 245-255' 12/24/2019 Brown silty sand with gravel BSS EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):304.94 627.29 Split sieve:3/8"Dry soil + tare (g):280.84 516.38 Moist Dr Tare (g):123.56 121.66 Total sample wt. (g):2120.08 1668.44 Water content (%): 15.3 28.1 +3/8" Coarse fraction (g):155.00 134.41 -3/8" Split fraction (g):505.63 394.72 Split fraction: 0.919 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 100.0 1" 90.93 25 94.6 3/4" 100.72 19 94.0 3/8" 134.41 9.5 91.9 ←Split o.4 20.27 4.75 87.2 o.10 46.43 2 81.1 o.20 84.76 0.85 72.2 o.40 112.72 0.425 65.7 o.60 134.66 0.25 60.6 o.100 169.71 0.15 52.4 o.140 205.65 0.106 44.0 o.200 248.25 0.075 34.1 Gravel %:12.8 Sand %:53.1 Fines %:34.1 Comments: Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]5 These results are in nonconformance with Method D6913 because the minimum dry mass was not met. M03271-001 Basal Aquifer Investigation 282-287' 12/24/2019 Brown clayey sand BSS EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):129.52 559.45 Split sieve:3/8"Dry soil + tare (g):129.44 442.95 Moist Dr Tare (g):127.99 121.13 Total sample wt. (g):1669.7 1226.26 Water content (%): 5.5 36.2 +3/8" Coarse fraction (g):1.53 1.45 -3/8" Split fraction (g):438.32 321.82 Split fraction: 0.999 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 100.0 3/8" 1.45 9.5 99.9 ←Split o.4 1.44 4.75 99.4 o.10 4.95 2 98.3 o.20 7.25 0.85 97.6 o.40 11.47 0.425 96.3 o.60 28.85 0.25 90.9 o.100 65.36 0.15 79.6 o.140 99.19 0.106 69.1 o.200 143.39 0.075 55.4 Gravel %:0.6 Sand %:44.1 Fines %:55.4 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]6 M03271-001 Basal Aquifer Investigation 337-342' 12/24/2019 Grey sandy silt BSS EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):556.94 471.52 Split sieve:3/8"Dry soil + tare (g):531.45 420.55 Moist Dr Tare (g):127.36 127.23 Total sample wt. (g):1812.4 1578.55 Water content (%): 6.3 17.4 +3/8" Coarse fraction (g):388.41 365.36 -3/8" Split fraction (g):344.29 293.32 Split fraction: 0.769 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 100.0 1.5" 255.62 37.5 83.8 1" 290.99 25 81.6 3/4" 316.64 19 79.9 3/8" 365.36 9.5 76.9 ←Split o.4 17.72 4.75 72.2 o.10 39.59 2 66.5 o.20 61.00 0.85 60.9 o.40 75.73 0.425 57.0 o.60 86.62 0.25 54.2 o.100 97.89 0.15 51.2 o.140 104.54 0.106 49.5 o.200 110.43 0.075 47.9 Gravel %:27.8 Sand %:24.3 Fines %:47.9 Comments: Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]7 These results are in nonconformance with Method D6913 because the minimum dry mass was not met. M03271-001 Basal Aquifer Investigation 356-359' 12/27/2019 Brownish grey clayey gravel with sandBSS EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data Split:o Moist soil + tare (g):- 363.07 Dry soil + tare (g):- 308.46 Moist Dr Tare (g):- 126.91 Total sample wt. (g):236.16 181.55 Water content (%): 0.0 30.1 0.00 0.00 -0.00 Split fraction: 1.000 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 - 3/8" -9.5 100.0 o.4 9.86 4.75 94.6 o.10 26.19 2 85.6 o.20 39.97 0.85 78.0 o.40 51.38 0.425 71.7 o.60 61.30 0.25 66.2 o.100 75.20 0.15 58.6 o.140 84.44 0.106 53.5 o.200 96.38 0.075 46.9 Gravel %:5.4 Sand %:47.7 Fines %:46.9 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]8 M03271-001 Basal Aquifer Investigation 367-369' 12/26/2019 Light brown clayey sand BF EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data Split:o Moist soil + tare (g):- 367.31 Dry soil + tare (g):- 313.35 Moist Dr Tare (g):- 122.99 Total sample wt. (g):244.32 190.36 Water content (%): 0.0 28.3 0.00 0.00 -0.00 Split fraction: 1.000 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 - 3/8" -9.5 100.0 o.4 14.04 4.75 92.6 o.10 26.54 2 86.1 o.20 38.63 0.85 79.7 o.40 49.41 0.425 74.0 o.60 59.79 0.25 68.6 o.100 73.38 0.15 61.5 o.140 84.09 0.106 55.8 o.200 96.90 0.075 49.1 Gravel %:7.4 Sand %:43.5 Fines %:49.1 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]9 M03271-001 Basal Aquifer Investigation 430-432' 12/26/2019 Brown clayey sand BF EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):127.31 316.49 Split sieve:3/8"Dry soil + tare (g):127.20 281.20 Moist Dr Tare (g):124.46 126.87 Total sample wt. (g):1181.22 961.79 Water content (%): 4.0 22.9 +3/8" Coarse fraction (g):2.77 2.66 -3/8" Split fraction (g):189.62 154.33 Split fraction: 0.997 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 100.0 3/8" 2.66 9.5 99.7 ←Split o.4 3.32 4.75 97.6 o.10 8.91 2 94.0 o.20 15.48 0.85 89.7 o.40 19.62 0.425 87.0 o.60 22.53 0.25 85.2 o.100 26.91 0.15 82.3 o.140 31.07 0.106 79.6 o.200 36.35 0.075 76.2 Gravel %:2.4 Sand %:21.3 Fines %:76.2 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]10 M03271-001 Basal Aquifer Investigation 505-507' 12/27/2019 Brown clay with sand JAB EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data Split:o Moist soil + tare (g):- 345.04 Dry soil + tare (g):- 296.00 Moist Dr Tare (g):- 118.61 Total sample wt. (g):226.43 177.39 Water content (%): 0.0 27.6 0.00 0.00 -0.00 Split fraction: 1.000 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 - 3/8" -9.5 100.0 o.4 0.61 4.75 99.7 o.10 3.58 2 98.0 o.20 10.75 0.85 93.9 o.40 18.31 0.425 89.7 o.60 27.36 0.25 84.6 o.100 49.19 0.15 72.3 o.140 73.35 0.106 58.7 o.200 98.28 0.075 44.6 Gravel %:0.3 Sand %:55.1 Fines %:44.6 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]11 M03271-001 Basal Aquifer Investigation 523-525' 12/27/2019 Brown silty sand JAB EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data Split:o Moist soil + tare (g):- 338.74 Dry soil + tare (g):- 299.29 Moist Dr Tare (g):- 141.48 Total sample wt. (g):197.26 157.81 Water content (%): 0.0 25.0 0.00 0.00 -0.00 Split fraction: 1.000 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 - 3/8" -9.5 100.0 o.4 0.21 4.75 99.9 o.10 3.42 2 97.8 o.20 13.38 0.85 91.5 o.40 22.35 0.425 85.8 o.60 29.88 0.25 81.1 o.100 43.48 0.15 72.4 o.140 57.62 0.106 63.5 o.200 72.89 0.075 53.8 Gravel %:0.1 Sand %:46.1 Fines %:53.8 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]12 M03271-001 Basal Aquifer Investigation 542-544' 12/27/2019 Reddish brown sandy clay JAB EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data C.F.(+3/8")S.F.(-3/8") Split:Yes Moist soil + tare (g):163.59 298.26 Split sieve:3/8"Dry soil + tare (g):160.71 268.46 Moist Dr Tare (g):127.74 128.08 Total sample wt. (g):1060.98 878.51 Water content (%): 8.7 21.2 +3/8" Coarse fraction (g):35.05 32.23 -3/8" Split fraction (g):170.18 140.38 Split fraction: 0.963 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 100.0 1" 29.54 25 96.6 3/4" 29.54 19 96.6 3/8" 32.23 9.5 96.3 ←Split o.4 9.29 4.75 90.0 o.10 18.87 2 83.4 o.20 27.32 0.85 77.6 o.40 33.38 0.425 73.4 o.60 38.62 0.25 69.8 o.100 48.50 0.15 63.0 o.140 58.70 0.106 56.1 o.200 68.61 0.075 49.2 Gravel %:10.0 Sand %:40.7 Fines %:49.2 Comments: Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]13 These results are in nonconformance with Method D6913 because the minimum dry mass was not met. M03271-001 Basal Aquifer Investigation 570-572' 12/27/2019 Light brown clayey sand JAB EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Particle-Size Distribution (Gradation) of Soils Using Sieve Analysis (ASTM D6913)© IGES 2004, 2020 Project: Boring No.: No: Sample: Location:Depth: Date: Description: By: Water content data Split:o Moist soil + tare (g):- 375.69 Dry soil + tare (g):- 315.09 Moist Dr Tare (g):- 123.54 Total sample wt. (g):252.15 191.55 Water content (%): 0.0 31.6 0.00 0.00 -0.00 Split fraction: 1.000 Accum. Grain Size Percent Sieve Wt. Ret. (g) (mm) Finer 6" -150 - 4" -100 - 3" -75 - 1.5" -37.5 - 1" -25 - 3/4" -19 - 3/8" -9.5 - o.4 -4.75 100.0 o.10 1.22 2 99.4 o.20 3.24 0.85 98.3 o.40 5.21 0.425 97.3 o.60 11.53 0.25 94.0 o.100 40.15 0.15 79.0 o.140 75.82 0.106 60.4 o.200 110.22 0.075 42.5 Gravel %:0.0 Sand %:57.5 Fines %:42.5 Entered by:__________ Reviewed:__________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[GSDv2.xlsm]14 M03271-001 Basal Aquifer Investigation 590-592' 12/30/2019 Dark brown silty sand BF EnergySolutions I-1-700 3 in No.4 No.2003/4 in No.10 No.40 0 10 20 30 40 50 60 70 80 90 100 0.010.1110100 Pe r c e n t f i n e r b y w e i g h t Grain size (mm) Hydraulic Conductivity of Saturated Porous Materials Using a Flexible Wall Permeameter, Method C (ASTM D5084)© IGES 2005, 2020 Project: Boring No.: No: Sample: Location:Depth: Date:Sample Description: By:Sample Type: Initial (o) Final (f) Sample Height, H (in)3.018 2.988 Sample Diameter, D (in)2.432 2.370 Gs 2.508 Determined Sample Length, L (cm) 7.666 7.590 Cell No.2 Sample Area, A (cm^2) 29.970 28.462 Station No.3 Sample Volume, V (cm^3) 229.74 216.02 Permeant liquid used Wt. Rings + Wet Soil (g)1165.19 422.20 Total backpressure (psi)30 Wt. Rings (g)757.31 0 Effective horiz. consolidation stress (psi)60 Wet Unit Wt.,m (pcf) 110.8 122.0 Effective vert. consolidation stress (psi)60 Wet Soil + Tare (g)329.56 539.89 Initial (o) Final (f) Dry Soil + Tare (g)278.54 428.50 B value 0.76 0.94 Tare (g)127.94 139.76 External Burette (cm )6.30 34.20 Weight of solids, Ws (g) 304.67 304.67 Cell Pressure (psi)0.0 90.0 Water Content, w (%) 33.88 38.58 Backpressure bottom (psi)30.0 Dry Unit Wt, d (pcf) 82.8 88.0 Backpressure top (psi)30.0 Void ratio, e 0.89 0.97 System volume coefficient (cm /psi)0.158 Saturation (%) 95.3 100 a System volume change (cm )14.18 ` Net sample volume change (cm )-13.72 Bottom burette ground length, l (cm) 82.25 a Saturation set to 100% for hase calculations Top burette ground length, l (cm) 81.95 b K corrected to 20ºC Burette area, a (cm )0.197 Conversion, reading to cm head (cm/rd) 5.076 Start Date and Time:1/8/20 10:11 Elapsed h1 h2 K Temp isc. Rati Kb time (sec) (cm) (cm) (cm/sec) (ºC) RT (cm/sec) 23.5 23.5 23.5 23.5 23.5 23.5 23.5 23.5 23.5 23.5 23.5 23.5 Comments: Entered by:___________ Reviewed:___________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[KBPFRHv1.xlsx]1 60.0 60.0 29.03 2.7E-05 2.7E-05 2.9E-05 8.40 8.2060.0 1.77 2.15 2.33 2.33 2.50 60.0 2.5E-05 27.15 60.0 29.038.00 60.0 7.81 8.40 35.07 0.92 2.5E-05 0.92 Middle depth interval tube sample of three used for test specimen. The maximum Skempton's B-value of 0.94 was determined on subsequent B-checks with no increase. It is assumed that the test specimen was saturated. 1/9/2020 EH Top Burette (cm3) Bottom Burette (cm3) 2.6E-05 Reddish brown clayey sand Undisturbed Average Kb (cm/sec) De-aired tap water 1.96 1.32 1.55 1.77 1.55 8.64 37.46 8.20 1.96 8.00 2.15 Energy Solutions M03271-001 Basal Aquifer Investigation I-1-700 297.5-298.0' 30.96 35.07 32.94 32.94 7.81 7.62 7.62 7.46 2.7E-05 27.15 25.48 0.92 0.92 0.92 2.6E-05 2.9E-05 2.8E-05 2.8E-05 30.96 0.92 2.7E-05 2.6E-05 Hydraulic Conductivity of Saturated Porous Materials Using a Flexible Wall Permeameter, Method C (ASTM D5084)© IGES 2005, 2020 Project: Boring No.: No: Sample: Location:Depth: Date:Sample Description: By:Sample Type: Initial (o) Final (f) Sample Height, H (in)2.929 2.877 Sample Diameter, D (in)2.404 2.296 Gs 2.493 Determined Sample Length, L (cm) 7.440 7.308 Cell No.1 Sample Area, A (cm^2) 29.284 26.716 Station No.6 Sample Volume, V (cm^3) 217.86 195.24 Permeant liquid used Wt. Rings + Wet Soil (g)1158.9 404.58 Total backpressure (psi)30 Wt. Rings (g)757.31 0 Effective horiz. consolidation stress (psi)60 Wet Unit Wt.,m (pcf) 115.1 129.4 Effective vert. consolidation stress (psi)60 Wet Soil + Tare (g)314.75 524.72 Initial (o) Final (f) Dry Soil + Tare (g)262.99 419.81 B value 0.76 0.96 Tare (g)112.21 122.86 External Burette (cm )13.30 49.40 Weight of solids, Ws (g) 298.96 298.96 Cell Pressure (psi)0.0 90.0 Water Content, w (%) 34.33 35.33 Backpressure bottom (psi)30.0 Dry Unit Wt, d (pcf) 85.7 95.6 Backpressure top (psi)30.0 Void ratio, e 0.82 0.88 System volume coefficient (cm /psi)0.150 Saturation (%) 100.0 100 a System volume change (cm )13.48 Net sample volume change (cm )-22.62 Bottom burette ground length, l (cm) 82.05 a Saturation set to 100% for hase calculations Top burette ground length, l (cm) 82 b K corrected to 20ºC Burette area, a (cm )0.197 Conversion, reading to cm head (cm/rd) 5.076 Start Date and Time:1/8/20 10:11 Elapsed h1 h2 K Temp isc. Rati Kb time (sec) (cm) (cm) (cm/sec) (ºC) RT (cm/sec) 23.6 23.6 23.6 23.6 23.6 23.6 23.6 23.6 23.6 23.6 23.6 23.6 Comments: Entered by:___________ Reviewed:___________Z:\PROJECTS\M03271_Energy_Solutions\001_Basal_Aquifer\[KBPFRHv1.xlsx]2 Middle depth interval tube sample of three used for test specimen. 0.92 0.92 0.92 3.9E-06 377.5-378.0' Reddish brown clayey sand Undisturbed 3.9E-06 4.0E-060.92 Average Kb (cm/sec) De-aired tap water 47.82 46.50 9.37 9.26 49.19 9.60 Bottom Burette (cm3) 0.59 4.0E-06 180.0 43.91 3.9E-06 4.2E-06 4.2E-06 9.72 9.60180.0 0.45 Energy Solutions M03271-001 Basal Aquifer Investigation I-1-700 3.9E-06 9.48 0.59 0.16 0.31 0.45 0.31 Top Burette (cm3) 9.84 1/9/2020 EH 9.72 47.82 0.92 3.8E-06 0.92180.0 180.0 0.73 0.86 0.86 0.99 180.0 9.26 42.69 180.0 43.919.48 9.370.73 4.2E-06 4.3E-06 4.3E-06 42.69 41.47 45.18 4.3E-06 46.50 45.18 9.15 PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT Appendix D AQTESOLV ANALYTICAL RESULTS Appendix D AQTESOLV ANALYTICAL RESULTS 10. 100. 1000. 1.0E+4 1.0E+5 0.01 0.1 1. 10. 100. Time (sec) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: C:\...\I-1-700_Hantush_leakyconfined_pump.aqt Date: 02/28/20 Time: 13:14:26 PROJECT INFORMATION Client: EnergySolns Project: 233001389 Test Date: 1-16-2020 AQUIFER DATA Saturated Thickness: 325. ft Anisotropy Ratio (Kz/Kr): 0.1 Aquitard Thickness (b'): 1. ft Aquitard Thickness (b"): 1. ft WELL DATA Pumping Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 Observation Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 SOLUTION Aquifer Model: Leaky Solution Method: Hantush T = 45.51 ft2/day S = 1.91E-5 r/B' = 0.1 ß' = 0.1 r/B" = 0.ß" = 1.85 10. 100. 1000. 1.0E+4 1.0E+5 0.01 0.1 1. 10. 100. Time (sec) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: C:\...\I-1-700_Neuman_leakyconfined_pump.aqt Date: 02/28/20 Time: 13:24:29 PROJECT INFORMATION Client: EnergySolns Project: 233001389 Test Date: 1-16-2020 AQUIFER DATA Saturated Thickness: 325. ft Anisotropy Ratio (Kz/Kr): 0.1 Aquitard Thickness (b'): 1. ft Aquitard Thickness (b"): 1. ft WELL DATA Pumping Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 Observation Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 SOLUTION Aquifer Model: Leaky Solution Method: Neuman-Witherspoon T = 48.08 ft2/day S = 0.004676 r/B = 0.1 ß = 0.1148 T2 = 3065.6 ft2/day S2 = 1.259E-5 10. 100. 1000. 1.0E+4 1.0E+5 -0.03 5.98 12. 18. 24. 30. Adjusted Time (sec) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: \...\I-1-700_CooperJacob_confined_pump.aqt Date: 02/28/20 Time: 12:02:10 PROJECT INFORMATION Client: EnergySolns Project: 233001389 Test Date: 1-16-2020 AQUIFER DATA Saturated Thickness: 325. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA Pumping Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 Observation Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 SOLUTION Aquifer Model: Confined Solution Method: Cooper-Jacob T = 241.7 ft2/day S = 1.292E-7 1. 10. 100. 1000. -0.03 2.98 5.98 8.99 12. 15. Time, t/t' Re s i d u a l D r a w d o w n ( f t ) WELL TEST ANALYSIS Data Set: \...\I-1-700_Theis_confined_recovery.aqt Date: 02/28/20 Time: 11:59:37 PROJECT INFORMATION Client: EnergySolns Project: 233001389 Test Date: 1-16-2020 AQUIFER DATA Saturated Thickness: 325. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA Pumping Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 Observation Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 SOLUTION Aquifer Model: Confined Solution Method: Theis (Recovery) T = 1298.8 ft2/day S/S' = 4.621 100. 1000. 1.0E+4 1.0E+5 1.0E+6 0.01 0.1 1. Time (sec) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: C:\...\I-1-700_Hantush_leakyconfined_obs.aqt Date: 02/28/20 Time: 13:10:33 PROJECT INFORMATION Client: EnergySolns Project: 233001389 Test Date: 1-16-2020 AQUIFER DATA Saturated Thickness: 325. ft Anisotropy Ratio (Kz/Kr): 0.1 Aquitard Thickness (b'): 1. ft Aquitard Thickness (b"): 1. ft WELL DATA Pumping Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 Observation Wells Well Name X (ft)Y (ft) I-1-100 1194186.5 7420897.9 SOLUTION Aquifer Model: Leaky Solution Method: Hantush T = 1213.5 ft2/day S = 0.001335 r/B' = 0.1 ß' = 0.1 r/B" = 0.ß" = 1.85 100. 1000. 1.0E+4 1.0E+5 1.0E+6 0. 0.06 0.12 0.18 0.24 0.3 Time (sec) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: C:\...\I-1-700_Neuman_leakyconfined_obs.aqt Date: 02/28/20 Time: 13:21:35 PROJECT INFORMATION Client: EnergySolns Project: 233001389 Test Date: 1-16-2020 AQUIFER DATA Saturated Thickness: 325. ft Anisotropy Ratio (Kz/Kr): 0.1 Aquitard Thickness (b'): 1. ft Aquitard Thickness (b"): 1. ft WELL DATA Pumping Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 Observation Wells Well Name X (ft)Y (ft) I-1-100 1194186.5 7420897.9 SOLUTION Aquifer Model: Leaky Solution Method: Neuman-Witherspoon T = 2492.9 ft2/day S = 0.0191 r/B = 0.1 ß = 0.1148 T2 = 8.64E+9 ft2/day S2 = 1.0E-10 100. 1000. 1.0E+4 1.0E+5 1.0E+6 0. 0.06 0.12 0.18 0.24 0.3 Adjusted Time (sec) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: \...\I-1-700_CooperJacob_confined_obs.aqt Date: 02/28/20 Time: 12:01:38 PROJECT INFORMATION Client: EnergySolns Project: 233001389 Test Date: 1-16-2020 AQUIFER DATA Saturated Thickness: 325. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA Pumping Wells Well Name X (ft)Y (ft) I-1-700 1194214.7 7420935.3 Observation Wells Well Name X (ft)Y (ft) I-1-100 1194186.5 7420897.9 SOLUTION Aquifer Model: Confined Solution Method: Cooper-Jacob T = 2.43E+4 ft2/day S = 2.354E-10 PHASE 1 BASAL-DEPTH AQUIFER STUDY REPORT Appendix E GROUNDWATER ANALYTICAL LABORATORY REPORTS Appendix E GROUNDWATER ANALYTICAL LABORATORY REPORTS February 12, 2020 Mr. Jared Stark EnergySolutions, LLC. 299 South Main Street, Suite 1700 Salt Lake City, Utah 84111 Re: EUI-11 Environmental Monitoring-Rad Purchase Order:20-EUI-11 Work Order: 502174 Chain of Custody:65534 SDG: EUI-11350 Dear Mr. Stark: GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received on January 24, 2020. Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time. Test results for NELAP or ISO 17025 accredited tests are verified to meet the requirements of those standards, with any exceptions noted. The results reported relate only to the items tested and to the sample as received by the laboratory. These results may not be reproduced except as full reports without approval by the laboratory. Copies of GEL's accreditations and certifications can be found on our website at www.gel.com. This original data report has been prepared and reviewed in accordance with GEL's standard operating procedures. We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at (843)556-8171 extension 4453. Sincerely, PM_SIGN_HERE Edith Kent Project Manager Enclosures Table of Contents Case Narrative....................................................................................3 Chain of Custody and Supporting Documentation.........................6 Laboratory Certifications................................................................10 Metals Analysis.................................................................................12 Case Narrative..........................................................................13 Sample Data Summary............................................................17 Quality Control Summary.......................................................19 Standards...................................................................................31 Raw Data...................................................................................34 Miscellaneous............................................................................56 Radiological Analysis.......................................................................70 Case Narrative..........................................................................71 Sample Data Summary............................................................78 Quality Control Summary.......................................................81 Case Narrative Page 1 of 84 SDG: EUI-11350 Case Narrative for EnergySolutions LLC (693694) SDG: EUI-11350 Work Order: 502174 February 11, 2020 Laboratory Identification: GEL Laboratories LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171 PO 20-EUI-11 Summary Sample Receipt The sample arrived at GEL Laboratories LLC, Charleston, South Carolina on January 24, 2020 for analysis. The samples associated with Chain of Custody 65534 were received at a temperature of 2 degrees C. The samples were analyzed for Metals and Radiochemistry parameters. Sample Identification The laboratory received the following sample: Laboratory Identification Sample Description 502174001 I-1-700 011720-01 Items of Note There are no items to note. Page 2 of 84 SDG: EUI-11350 Case Narrative Sample analyses were conducted using methodology as outlined in GEL Laboratories, LLC (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package. PM_SIGN_HERE Edith Kent Project Manager Page 3 of 84 SDG: EUI-11350 Chain of Custody and Supporting Documentation Page 4 of 84 SDG: EUI-11350 Page 5 of 84 SDG: EUI-11350 Page 6 of 84 SDG: EUI-11350 Page 7 of 84 SDG: EUI-11350 Laboratory Certifications Page 8 of 84 SDG: EUI-11350 State Certification Alaska Alaska Drinking Water Arkansas CLIA California Colorado Connecticut DoD ELAP/ ISO17025 A2LA Florida NELAP Foreign Soils Permit Georgia Georgia SDWA Hawaii Idaho Illinois NELAP Indiana Kansas NELAP Kentucky SDWA Kentucky Wastewater Louisiana Drinking Water Louisiana NELAP Maine Maryland Massachusetts Massachusetts PFAS Approv Michigan Mississippi Nebraska Nevada New Hampshire NELAP New Jersey NELAP New Mexico New York NELAP North Carolina North Carolina SDWA North Dakota Oklahoma Pennsylvania NELAP Puerto Rico S. Carolina Radiochem Sanitation Districts of L South Carolina Chemistry Tennessee Texas NELAP Utah NELAP Vermont Virginia NELAP Washington 17−018 SC00012 88−0651 42D0904046 2940 SC00012 PH−0169 2567.01 E87156 P330−15−00283, P330−15−00253 SC00012 967 SC00012 SC00012 200029 C−SC−01 E−10332 90129 90129 LA024 03046 (AI33904) 2019020 270 M−SC012 Letter 9976 SC00012 NE−OS−26−13 SC000122020−1 2054 SC002 SC00012 11501 233 45709 R−158 2019−165 68−00485 SC00012 10120002 9255651 10120001 TN 02934 T104704235−19−15 SC000122019−30 VT87156 460202 C780 List of current GEL Certifications as of 11 February 2020 Page 9 of 84 SDG: EUI-11350 Metals Analysis Page 10 of 84 SDG: EUI-11350 Case Narrative Page 11 of 84 SDG: EUI-11350 Metals Technical Case Narrative EnergySolutions LLC SDG #: EUI-11350 Work Order #: 502174 Product: Determination of Metals by ICP-MS Analytical Method: EPA 200.8 Analytical Procedure: GL-MA-E-014 REV# 33 Analytical Batch: 1962589 Preparation Method: EPA 200.2 Preparation Procedure: GL-MA-E-016 REV# 18 Preparation Batch: 1962588 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 502174001 I-1-700 011720-01 1204483525 Method Blank (MB)ICP-MS 1204483526 Laboratory Control Sample (LCS) 1204483529 502174001(I-1-700 011720-01L) Serial Dilution (SD) 1204483527 502174001(I-1-700 011720-01D) Sample Duplicate (DUP) 1204483528 502174001(I-1-700 011720-01S) Matrix Spike (MS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Calibration Information ICSA/ICSAB Statement For the ICP-MS analysis, the ICSA solution contains analyte concentrations which are verified trace impurities indigenous to the purchased standard. Technical Information Sample Dilutions Dilutions may be required for many reasons, including to minimize matrix interferences or to bring over range target analyte concentrations into the linear calibration range. Per the SOP, sample 502174001 (I-1-700 011720-01) was diluted due to internal standard recoveries outside the acceptable control limits. Analyte 502174 001 Uranium 5X Page 12 of 84 SDG: EUI-11350 Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Page 13 of 84 SDG: EUI-11350 GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com CARE009 EnergySolutions LLC (693694) Client SDG: EUI-11350 GEL Work Order: 502174 GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverables receive a third level review of the fractional data package. The following data validator verified the information presented in this data report: The Qualifiers in this report are defined as follows: * A quality control analyte recovery is outside of specified acceptance criteria U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD. for Qualifier Definition Report Signature:Name: Date:Title:04 FEB 2020 Edmund Frampton Team Leader Review/Validation Page 14 of 84 SDG: EUI-11350 Sample Data Summary Page 15 of 84 SDG: EUI-11350 METALS −1− INORGANICS ANALYSIS DATA PACKAGE GEL Laboratories LLC EPA SDG No:METHOD TYPE: SAMPLE ID:CLIENT ID: CONTRACT: MATRIX:DATE RECEIVED LEVEL: CAS No Analyte Result Units C Qual M* Inst ID Analytical Run Low EUI−11350 502174001 I−1−700 011720−01 CARE EUI−11 Water 24−JAN−20 7440−61−1 Uranium 17.4 ug/L 0.335 ICPMS12MS 200131−1 EPA MDL DF 5 MS EPA 200.8 *Analytical Methods: Page 16 of 84 SDG: EUI-11350 Quality Control Summary Page 17 of 84 SDG: EUI-11350 METALS −2a− Initial and Continuing Calibration Verification GEL Laboratories LLC EPA SDG No: Contract:Lab Code: GEL EUI−11350 Instrument ID: Sample ID Analyte Result Units True Value Units % Recovery Acceptance Window (%R)M*Analysis Date/Time Run Number ICV01 CCV01 CCV02 Uranium Uranium Uranium 47.3 47.8 47.3 50 50 50 94.6 95.5 94.6 31−JAN−20 14:03 31−JAN−20 14:11 31−JAN−20 14:24 200131−1 200131−1 200131−1 MS MS MS ICPMS12 CARE EUI−11 ug/L ug/L ug/L ug/L ug/L ug/L 90.0 − 110.0 90.0 − 110.0 90.0 − 110.0 *Analytical Methods: MS EPA 200.8 Page 18 of 84 SDG: EUI-11350 METALS −2b− CRDL Standard for ICP & ICPMS GEL Laboratories LLC EPA SDG No: Contract:Lab Code: GEL EUI−11350 Instrument ID: Sample ID Analyte Result Units True Value Units % Recovery Advisory Limits (%R)M*Analysis Date/Time Run Number CRDL01 Uranium .2 .2 100 31−JAN−20 14:06 200131−1MS ICPMS12 CARE EUI−11 ug/L ug/L 70.0 − 130.0 *Analytical Methods: MS EPA 200.8 Page 19 of 84 SDG: EUI-11350 Metals −3a− Initial and Continuing Calibration Blank Summary GEL Laboratories LLC EPA SDG No.: Contract:Lab Code: GELCARE EUI−11 EUI−11350 ICB01 CCB01 CCB02 Uranium Uranium Uranium 0.067 0.067 0.067 +/−.2 +/−.2 +/−.2 U U U 0.067 0.067 0.067 0.2 0.2 0.2 MS MS MS 31−JAN−20 14:04 31−JAN−20 14:13 31−JAN−20 14:25 200131−1 200131−1 200131−1 Sample ID Analyte Result ug/L Acceptance Conc Qual RDL M*Analysis Date/Time RunMDLMatrix LIQ LIQ LIQ *Analytical Methods: MS EPA 200.8 Page 20 of 84 SDG: EUI-11350 METALS −3b− PREPARATION BLANK SUMMARY GEL Laboratories LLC EPA Sample ID Analyte Result Acceptance Window Conc Qual M*RDL 1204483525 Uranium 0.0670 0.0670 0.200 SDG NO. Contract: Matrix: EUI−11350 CARE EUI−11 U MS+/−0.2 Units ug/L MDL Water *Analytical Methods: MS EPA 200.8 Page 21 of 84 SDG: EUI-11350 METALS −4− Interference Check Sample GEL Laboratories LLC EPA SDG No: Contract:Lab Code: GEL EUI−11350 Sample ID Analyte Result Units True Value Units % Recovery Acceptance Window (%R) Analysis Date/Time Run Number ICSA01 ICSAB01 Uranium Uranium 0.014 19.5 20 97.4 31−JAN−20 14:08 31−JAN−20 14:09 200131−1 200131−1 CARE EUI−11 ug/L ug/L ug/L 80.0 − 120.0 ICPMS12Instrument: Page 22 of 84 SDG: EUI-11350 METALS −5a− Matrix Spike Summary GEL Laboratories LLC EPA Analyte Units Acceptance Limit Spiked Result C Sample Result C Spike Added SDG NO. Contract: Matrix: EUI−11350 CARE EUI−11 WATER % Recovery Qual M* Sample ID:502174001 Level: Spike ID: Client ID: % Solids: Uranium ug/L 68.3 50.0 102 MS I−1−700 011720−01S 75−125 1204483528 Low 17.4 *Analytical Methods: MS EPA 200.8 Page 23 of 84 SDG: EUI-11350 Metals −6− Duplicate Sample Summary GEL Laboratories LLC EPA SDG No.:EUI−11350 Contract: CARE EUI−11 Lab Code: GEL Matrix:WATER Level:Low Client ID:I−1−700 011720−01D Sample ID:502174001 Duplicate ID:1204483527 Percent Solids for Dup:N/A Analyte Units Acceptance Limit Sample Result C Duplicate Result C RPD Qual M* Uranium ug/L +/−20%17.4 18.4 5.74 MS *Analytical Methods: MS EPA 200.8 Page 24 of 84 SDG: EUI-11350 METALS −7− Laboratory Control Sample Summary GEL Laboratories LLC EPA Analyte Units Acceptance LimitSample ID Result C True Value SDG NO. Contract: EUI−11350 CARE EUI−11 % Recovery M* Aqueous LCS Source:Inorganic Ventures Solid LCS Source: Uranium ug/L 1204483526 49.450.0 98.9 MS85−115 *Analytical Methods: MS EPA 200.8 Page 25 of 84 SDG: EUI-11350 METALS −9− Serial Dilution Sample Summary GEL Laboratories LLC EPA SDG NO. Contract: Matrix: EUI−11350 CARE EUI−11 LIQUID % Difference Qual M* Sample ID:502174001 Level: Serial Dilution ID: Client ID:I−1−700 011720−01L 1204483529 Low Initial Value ug/L Acceptance LimitAnalyteCSerial Value ug/L C Uranium 3.47 3.45 .576 MS *Analytical Methods: MS EPA 200.8 Page 26 of 84 SDG: EUI-11350 METALS −13− SAMPLE PREPARATION SUMMARY GEL Laboratories LLC EPA SDG No:Method Type: Contract: Sample ID Client ID Sample Type Matrix Prep Date Initial Sample Size Percent Solids EUI−11350 Lab Code: GEL Final Sample Volume Batch Number 1962588 1204483525 1204483526 1204483528 1204483527 502174001 MB LCS MS DUP SAMPLE W W W W W 30−JAN−20 30−JAN−20 30−JAN−20 30−JAN−20 30−JAN−20 50 50 50 50 50 mL mL mL mL mL 50 50 50 50 50 mL mL mL mL mL MB for batch 1962588 LCS for batch 1962588 I−1−700 011720−01S I−1−700 011720−01D I−1−700 011720−01 MS CARE EUI−11 Page 27 of 84 SDG: EUI-11350 GEL Laboratories LLC Metals -14- Analysis Run Log EPAPage 1 200131-1 13:58:32 14:00:09 14:01:46 14:03:21 14:04:58 14:06:34 14:08:11 14:09:47 14:11:25 14:13:02 14:14:40 14:16:17 14:17:54 14:19:30 14:21:06 14:22:42 14:24:21 14:25:57 U X X X X X X X X X X X X X X X X X X S0.0 S10 S100 ICV01 ICB01 CRDL01 ICSA01 ICSAB01 CCV01 CCB01 1204483525 1204483526 502174001 1204483527 1204483528 1204483529 CCV02 CCB02 1 1 1 1 1 1 1 1 1 1 1 1 5 5 5 25 1 1 D/F Contract: CARE EUI-11 Run Time Lab Code : GEL Client Sdg: Inst Name: Start Date:End Date:Data File: Instrument Type:ICPMS12 31-JAN-20 31-JAN-20 MS EUI-11350 Samp ID Page 28 of 84 SDG: EUI-11350 Standards Page 29 of 84 SDG: EUI-11350 METALS −10− Instrument Detection Limits GEL Laboratories LLC EPA SDG NO.EUI−11350 Uranium 0.067 0.2 Contract:CARE EUI−11 Effective Date:16−APR−17Lab Code: GEL MDL MDL ICP/MS Analyte Wavelength (nm) RDL ug/L ug/L LIQUID Verified on:Instrument(s): ICPMS12 31−JAN−2020LIQU Page 30 of 84 SDG: EUI-11350 METALS −12− Linear Ranges GEL Laboratories LLC EPA SDG NO.EUI−11350 Units Integration TimeAnalyte LDR Uranium 1000 5000 ug/L Contract:CARE EUI−11 Lab Code: GEL Instrument IDICPMS12 Effective Date 01−AUG−17 (msec) Page 31 of 84 SDG: EUI-11350 Raw Data Page 32 of 84 SDG: EUI-11350 Sample ID: Sample Report Date/Time: Friday, January 31, 2020 10:20:30 Page 1 ICPMS #12 Daily Performance Sample ID: Sample Sample Date/Time: Friday, January 31, 2020 10:16:26 Sample Description: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\Daily 2.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\default4\Sample.580 Mass Calibration File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\MassCal\default2.tun Dual Detector Mode: Pulse Acquisition Date/Time&Time Zone: Friday, January 31, 2020 10:16:26 Eastern Standard Time Number of Replicates: 5 Summary Analyte Mass Meas. Intens. Mean Net Intens. Mean Net Intens. SD Net Intens. RSD Be 9.0 51713.1 51713.060 1054.533 2.0 Mg 24.0 103587.1 103587.112 2390.861 2.3 Co 58.9 68934.9 68934.880 2393.442 3.5 Rh 102.9 38755.3 38755.303 448.958 1.2 In 114.9 249189.4 249189.398 4499.056 1.8 Pb 208.0 108077.4 108077.418 2570.774 2.4 >Ba 137.9 236465.6 236465.620 4185.334 1.8 Ba++69.0 2831.0 0.012 0.000 0.6 >Ce 139.9 256536.2 256536.162 6581.448 2.6 CeO 155.9 4375.8 0.017 0.001 5.9 Bkgd 220.0 0.2 0.200 0.112 55.9 Current Conditions C Val Description 0.96 Nebulizer Gas Flow STD/KED [NEB] 1.20 Auxiliary Gas Flow 18.00 Plasma Gas Flow -12.00 Deflector Voltage 1600.00 ICP RF Power -1525.00 Analog Stage Voltage 800.00 Pulse Stage Voltage 0.00 Quadrupole Rod Offset STD [QRO] -16.00 Cell Rod Offset STD [CRO] 8.00 Discriminator Threshold -12.00 Cell Entrance/Exit Voltage STD 0.00 RPa 0.45 RPq 0.96 DRC Mode NEB -9.00 DRC Mode QRO -2.00 DRC Mode CRO -7.00 DRC Mode Cell Entrance/Exit Voltage 0.60 Cell Gas A 200.00 Axial Field Voltage -16.00 KED Mode CRO -12.50 KED Mode QRO -9.00 KED Mode Cell Entrance Voltage -31.00 KED Mode Cell Exit Voltage 3.00 KED Cell Gas A 0.00 KED RPa 0.25 KED RPq 475.00 KED Mode Axial Field Voltage Current Autolens Data Page 33 of 84 SDG: EUI-11350 Sample ID: Sample Report Date/Time: Friday, January 31, 2020 10:20:30 Page 2 Analyte Mass Num of Pts DAC Value Maximum Intensity Be 9.012 41 -13.5 34020.5 Mg 23.985 41 -14.5 169728.3 In 114.904 41 -11.5 135178.6 Ce 139.905 41 -10.0 87078.6 Pb 207.977 41 -6.5 54993.6 U 238.050 41 -7.0 91767.8 Page 34 of 84 SDG: EUI-11350 Report Date/Time: Friday, January 31, 2020 10:06:38 Page 1 ICPMS #12 Instrument Tuning Report Analyte Exact Mass Meas. Mass Mass DAC Res DAC Meas. Pk. Width Be 9.0 9.0 1640 2060 0.714 Mg 24.0 24.0 4629 2068 0.665 Mg 25.0 25.0 4813 2065 0.675 Mg 26.0 26.0 5026 2065 0.686 Co 58.9 58.9 11597 2062 0.710 Rh 102.9 102.9 20382 2065 0.724 In 114.9 114.9 22774 2064 0.726 Ce 139.9 139.9 27775 2065 0.739 Pb 206.0 206.0 40982 2069 0.698 Pb 207.0 207.0 41195 2070 0.705 Pb 208.0 208.0 41385 2065 0.729 U 238.1 238.0 47395 2065 0.748 Page 35 of 84 SDG: EUI-11350 Sample ID: Cal Blank Report Date/Time: Friday, January 31, 2020 13:58:42 Page 1 ICPMS #12 - Summary Report Sample ID: Cal Blank Sample Date/Time: Friday, January 31, 2020 13:58:32 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\Cal Blank.731 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 952701.526 U 238 ug/L 29.000 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 36 of 84 SDG: EUI-11350 Sample ID: Standard 1 Report Date/Time: Friday, January 31, 2020 14:00:19 Page 1 ICPMS #12 - Summary Report Sample ID: Standard 1 Sample Date/Time: Friday, January 31, 2020 14:00:09 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\Standard 1.732 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 896076.707 896076.707 U 238 10.000 ug/L 0.567 209214.886 0.233 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 37 of 84 SDG: EUI-11350 Sample ID: Standard 2 Report Date/Time: Friday, January 31, 2020 14:01:55 Page 1 ICPMS #12 - Summary Report Sample ID: Standard 2 Sample Date/Time: Friday, January 31, 2020 14:01:46 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\Standard 2.733 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 925992.276 925992.276 U 238 100.039 ug/L 1.457 2250794.791 2.431 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 38 of 84 SDG: EUI-11350 Sample ID: QC Std 1 Report Date/Time: Friday, January 31, 2020 14:03:31 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 1 Sample Date/Time: Friday, January 31, 2020 14:03:21 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 1.734 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 871435.623 871435.623 U 238 47.291 ug/L 2.312 1001542.868 1.149 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 91.47 U 238 94.583 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 39 of 84 SDG: EUI-11350 Sample ID: QC Std 2 Report Date/Time: Friday, January 31, 2020 14:05:08 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 2 Sample Date/Time: Friday, January 31, 2020 14:04:58 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 2.735 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 947985.272 947985.272 U 238 0.010 ug/L 9.173 248.669 0.000 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 99.50 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 40 of 84 SDG: EUI-11350 Sample ID: QC Std 3 Report Date/Time: Friday, January 31, 2020 14:06:44 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 3 Sample Date/Time: Friday, January 31, 2020 14:06:34 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 3.736 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 835333.195 835333.195 U 238 0.200 ug/L 1.473 4078.916 0.005 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 87.68 U 238 99.847 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 41 of 84 SDG: EUI-11350 Sample ID: QC Std 4 Report Date/Time: Friday, January 31, 2020 14:08:21 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 4 Sample Date/Time: Friday, January 31, 2020 14:08:11 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 4.737 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 724920.967 724920.967 U 238 0.014 ug/L 9.427 268.003 0.000 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 76.09 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 42 of 84 SDG: EUI-11350 Sample ID: QC Std 5 Report Date/Time: Friday, January 31, 2020 14:09:57 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 5 Sample Date/Time: Friday, January 31, 2020 14:09:47 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 5.738 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 725859.312 725859.312 U 238 19.481 ug/L 2.217 343591.874 0.473 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 76.19 U 238 97.406 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 43 of 84 SDG: EUI-11350 Sample ID: QC Std 6 Report Date/Time: Friday, January 31, 2020 14:11:34 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 6 Sample Date/Time: Friday, January 31, 2020 14:11:25 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 6.739 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 797012.107 797012.107 U 238 47.751 ug/L 0.415 925001.909 1.161 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 83.66 U 238 95.502 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 44 of 84 SDG: EUI-11350 Sample ID: QC Std 7 Report Date/Time: Friday, January 31, 2020 14:13:12 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 7 Sample Date/Time: Friday, January 31, 2020 14:13:02 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 7.740 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 834209.795 834209.795 U 238 0.006 ug/L 4.338 139.001 0.000 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 87.56 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 45 of 84 SDG: EUI-11350 Sample ID: 1204483525 Report Date/Time: Friday, January 31, 2020 14:14:50 Page 1 ICPMS #12 - Summary Report Sample ID: 1204483525 Sample Date/Time: Friday, January 31, 2020 14:14:40 Sample Type: Sample Sample Description: CARE 200.8 MB Number of Replicates: 3 Batch ID: 1962589|1|baj Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\1204483525.741 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 857726.557 857726.557 U 238 0.004 ug/L 1.266 101.334 0.000 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 90.03 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 46 of 84 SDG: EUI-11350 Sample ID: 1204483526 Report Date/Time: Friday, January 31, 2020 14:16:27 Page 1 ICPMS #12 - Summary Report Sample ID: 1204483526 Sample Date/Time: Friday, January 31, 2020 14:16:17 Sample Type: Sample Sample Description: CARE 200.8 LCS Number of Replicates: 3 Batch ID: 1962589|1|baj Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\1204483526.742 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 886084.003 886084.003 U 238 49.439 ug/L 2.530 1064894.867 1.202 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 93.01 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 47 of 84 SDG: EUI-11350 Sample ID: 502174001 Report Date/Time: Friday, January 31, 2020 14:18:04 Page 1 ICPMS #12 - Summary Report Sample ID: 502174001 Sample Date/Time: Friday, January 31, 2020 14:17:54 Sample Type: Sample Sample Description: CARE 200.8 Number of Replicates: 3 Batch ID: 1962589|5|baj Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\502174001.743 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 576087.730 576087.730 U 238 3.470 ug/L 1.520 48590.852 0.084 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 60.47 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 48 of 84 SDG: EUI-11350 Sample ID: 1204483527 Report Date/Time: Friday, January 31, 2020 14:19:40 Page 1 ICPMS #12 - Summary Report Sample ID: 1204483527 Sample Date/Time: Friday, January 31, 2020 14:19:30 Sample Type: Sample Sample Description: CARE 200.8 DUP Number of Replicates: 3 Batch ID: 1962589|5|baj Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\1204483527.744 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 587095.442 587095.442 U 238 3.675 ug/L 2.225 52438.072 0.089 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 61.62 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 49 of 84 SDG: EUI-11350 Sample ID: 1204483528 Report Date/Time: Friday, January 31, 2020 14:21:15 Page 1 ICPMS #12 - Summary Report Sample ID: 1204483528 Sample Date/Time: Friday, January 31, 2020 14:21:06 Sample Type: Sample Sample Description: CARE 200.8 MS Number of Replicates: 3 Batch ID: 1962589|5|baj Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\1204483528.745 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 587636.851 587636.851 U 238 13.655 ug/L 0.474 195041.584 0.332 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 61.68 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 50 of 84 SDG: EUI-11350 Sample ID: 1204483529 Report Date/Time: Friday, January 31, 2020 14:22:52 Page 1 ICPMS #12 - Summary Report Sample ID: 1204483529 Sample Date/Time: Friday, January 31, 2020 14:22:42 Sample Type: Sample Sample Description: CARE 200.8 SDILT Number of Replicates: 3 Batch ID: 1962589|25|baj Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\1204483529.746 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 880726.867 880726.867 U 238 0.690 ug/L 1.382 14798.330 0.017 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 92.45 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 51 of 84 SDG: EUI-11350 Sample ID: QC Std 6 Report Date/Time: Friday, January 31, 2020 14:24:31 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 6 Sample Date/Time: Friday, January 31, 2020 14:24:21 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 6.747 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 1014388.816 1014388.816 U 238 47.309 ug/L 2.227 1166250.605 1.150 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 106.47 U 238 94.618 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 52 of 84 SDG: EUI-11350 Sample ID: QC Std 7 Report Date/Time: Friday, January 31, 2020 14:26:07 Page 1 ICPMS #12 - Summary Report Sample ID: QC Std 7 Sample Date/Time: Friday, January 31, 2020 14:25:57 Sample Type: Sample Sample Description: Number of Replicates: 3 Batch ID: Method File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\Method\200.8 u.mth Dataset File: C:\Users\Public\Documents\PerkinElmer Syngistix\ICPMS\DataSet\200128\QC Std 7.748 Concentration Results Summary Analyte Mass Conc. Mean Report Unit Conc. RSD Meas. Intens. Mean Net Intens. Mean >Lu 175 ug/L 967064.818 967064.818 U 238 0.006 ug/L 6.177 175.334 0.000 Calibration Analyte MassCurve Type Correlation Coefficient Lu 175Linear Thru Zero U 238Linear Thru Zero 1.0000 QC Calculated Values Internal Standard SymbolAnalyteMassQC Std % Recovery Int Std % RecoverySpike % RecoveryDilution % DifferenceDuplicate Rel. % Difference >Lu 175 101.51 U 238 QC Out of Limits Measurement TypeAnalyte MassOut of Limits Message QC Action QC Action Line: No QC action taken Page 53 of 84 SDG: EUI-11350 Miscellaneous Page 54 of 84 SDG: EUI-11350 Prep Logbook Analytical Logbook version 1 11-04-2002 GEL Laboratories LLC 50 01/30/20 13:50 50 1 <2 50 01/30/20 13:50 50 1 <2 50 01/30/20 13:50 50 1 <2 50 01/30/20 13:50 50 1 <2 50 01/30/20 13:50 50 1 <2 50 01/30/20 13:50 50 1 <2 1962588 Initial Volume (mL) Hot Block Stop Date (date) Final Volume (mL) Prep Factor (mL/mL) pH CheckSample ID Batch ID: 1204483525 MB 1204483526 LCS 502174001 1204483529 SDILT (502174001) 1204483527 DUP (502174001) 1204483528 MS (502174001) 30-JAN-2020 09:50:58 30-JAN-2020 09:50:58 30-JAN-2020 09:50:58 30-JAN-2020 09:50:58 30-JAN-2020 09:50:58 30-JAN-2020 09:50:58 Sample IdType Serial Number Spike UnitsSpike Amount ICP-MS spiking soluiton A ICP-MS spiking solution B ICP-MS spiking soluiton A ICP-MS spiking solution B mL mL mL mL UI191025-A UI191025-B UI191025-A UI191025-B 1204483526 1204483526 1204483528 1204483528 LCS LCS MS MS Description .25 .25 .25 .25 Analyst: Ridge Gleaton Method: Lab SOP:GL-MA-E-016 REV# 18 Instrument: Metals Manual Instrument Comments: Block Temperature (90-95C): 94 C Temperature within limits (Y/N)?: y Thermometer ID: 118840 Hot Block ID: 14 Digestion tube lot #: 1906257 EPA 200.2 Sample Preparation for Total Recoverable Elements by EPA Method 200.2 Reagent/Solvent Lot ID Amount HYDROCHLORIC ACID Concentrated Nitric Acid 200120 3011870 Description .5 mL 1 mL Water Water Water Water Water Water Matrix Prep Date Page 55 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS CRDL Master Soln #1 ICPMS CRDL Soln #2 ICP-MS spiking soluiton A Description: Description: Description: Aluminum Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Nickel Phosphorous Potassium Selenium Sodium Strontium Thallium Thorium Uranium Vanadium Zinc Antimony Molybdenum Silver Tin Titanium Tungsten Zirconium Analyte Analyte Analyte 50 mg/L 5 mg/L 4 mg/L .5 mg/L 15 mg/L 1 mg/L 200 mg/L 30 mg/L 1 mg/L 2 mg/L 100 mg/L 2 mg/L 10 mg/L 30 mg/L 5 mg/L 2 mg/L 50 mg/L 300 mg/L 5 mg/L 250 mg/L 10 mg/L 2 mg/L 2 mg/L .2 mg/L 20 mg/L 20 mg/L 3 mg/L 1 mg/L 1 mg/L 5 mg/L 10 mg/L 5 mg/L 2 mg/L Concentration Concentration Concentration Amount : Catalog Number : Lot Number : Solvent : Amount : Catalog Number : Lot Number : Solvent : Catalog Number : Lot Number : 250 mL 090014-MC-02 10091735-1 +/- 0.5% IN 2% HNO3 250 mL 160044-11-02 10091735-2 +/- 0.5% IN 2% HNO3 GEL-12A N2-MEB673694 Comments: Comments: Comments: None None None ICP-MS CRDL Master #1 ICP-MS CRDL Master #2 ICP-MS SPIKE A Name: Name: Name: Source Material Source Material Source Material Type: Type: Type: 15-APR-19 15-APR-19 25-OCT-19 Received: Received: Received: 15-APR-20 15-APR-20 25-OCT-20 Expires: Expires: Expires: 02SI 02SI Inorganic Ventures Supplier: Supplier: Supplier: Paul Boyd Paul Boyd Edmund Frampton Employee: Employee: Employee: Serial ID: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: Open/Reference Date: 15-APR-19 15-APR-19 13-NOV-19 UI190415-09 UI190415-10 UI191025-A Analyte Analyte Analyte Concentration Concentration Concentration Page 56 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICP-MS spiking solution B ICPMS ICV/CCV Soln B - 20ppm Description: Description: Antimony Hafnium Molybdenum Tantalum Tin Titanium Tungsten Zirconium Aluminum Arsenic Barium Beryllium Bismuth Boron Cadmium Calcium Cesium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Nickel Phosphorous Potassium Rhenium Rhodium Selenium Silver Sodium Strontium Thallium Thorium Uranium Uranium-235 Uranium-238 Vanadium Zinc Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Analyte Analyte Analyte 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 400 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 20 mg/L 10 mg/L 400 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 400 mg/L 10 mg/L 10 mg/L 400 mg/L 10 mg/L 10 mg/L 400 mg/L 400 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 400 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L .072 mg/L 9.928 mg/L 10 mg/L 10 mg/L 20 mg/L 20 mg/L 20 mg/L 40 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L Concentration Concentration Concentration Catalog Number : Lot Number : Amount : Catalog Number : Lot Number : Solvent : GEL-12B N2-MEB673693 250 mL 160054-02-03 10066767-11 2% HNO3 100 cm2 Comments: Comments: None None ICP-MS SPIKE B ICP-MS ICV/CCV Master B Name: Name: Source Material Source Material Type: Type: 25-OCT-19 02-NOV-19 Received: Received: 25-OCT-20 02-NOV-20 Expires: Expires: Inorganic Ventures 02SI Supplier: Supplier: Edmund Frampton Paul Boyd Employee: Employee: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: 13-NOV-19 02-NOV-19 UI191025-B UI191102-07 Analyte Analyte Analyte Concentration Concentration Concentration Page 57 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS ICV/CCV SOLN A - 2000ppm ICPMS Tungsten standard SPIKE - 10mg/L ICPMS ICV/CCV Soln C - 20ppm Description: Description: Description: Lead Lithium Manganese Nickel Selenium Strontium Thallium Thorium Uranium Vanadium Zinc Aluminum Calcium Iron Magnesium Phosphorous Potassium Sodium Tungsten Antimony Molybdenum Silver Tin Titanium Tungsten Analyte Analyte Analyte Analyte 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 2020 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 10 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L Concentration Concentration Concentration Concentration Amount : Catalog Number : Lot Number : Solvent : Catalog Number : Lot Number : Solvent : Amount : Catalog Number : Lot Number : Solvent : 250 mL 160055-01-03 10066767-12 2% HNO3 100 cm2 060074-05-01 10070573-10 2% HNO3 + Tr HF 250 mL ZGEL-107-500 52-274CR 2% HNO3/Tr. Tart Acid/ Tr. HF 100 c Comments: Comments: Comments: None None None ICP-MS ICV/CCV Master A ICPMS Tungsten - 10mg/L S ICP-MS ICV/CCV Master C Name: Name: Name: Source Material Source Material Source Material Type: Type: Type: 02-NOV-19 12-NOV-19 04-DEC-19 Received: Received: Received: 02-NOV-20 12-NOV-20 30-OCT-20 Expires: Expires: Expires: 02SI O2SI Spex Supplier: Supplier: Supplier: Paul Boyd Paul Boyd Paul Boyd Employee: Employee: Employee: Serial ID: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: Open/Reference Date: 02-NOV-19 12-NOV-19 04-DEC-19 UI191102-09 UI191112-03 UI191204-08 Analyte Analyte Analyte Analyte Concentration Concentration Concentration Concentration Page 58 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS ICSAB Master B ICPMS ICSAB Master C ICP-MS ICSA Master A NEXION Description: Description: Description: Zirconium Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Lead Lithium Manganese Nickel Selenium Strontium Thallium Thorium Uranium Vanadium Zinc Antimony Silver Tin Tungsten Zirconium Analyte Analyte Analyte Analyte 20 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L Concentration Concentration Concentration Concentration Amount : Catalog Number : Lot Number : Solvent : Amount : Catalog Number : Lot Number : Solvent : Amount : Catalog Number : Lot Number : Solvent : 250 mL 160033-02-02 10069799-9 +/- 2.0% in 2% HNO3 250 mL 160033-03-02 10069799-10 +/- 2.0% in 2% HNO3 + tr HF 1000 mL 60013-01-01LNexion 10065549-13 5% HNO3 + Tr HF Comments: Comments: Comments: None None None ICP-MS ICSAB Master B ICP-MS ICSAB Master C ICP-MS ICSA Master A Nex Name: Name: Name: Source Material Source Material Source Material Type: Type: Type: 18-DEC-19 18-DEC-19 02-NOV-19 Received: Received: Received: 18-DEC-20 18-DEC-20 02-NOV-20 Expires: Expires: Expires: 02SI 02SI 02SI Supplier: Supplier: Supplier: Paul Boyd Paul Boyd Paul Boyd Employee: Employee: Employee: Serial ID: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: Open/Reference Date: 18-DEC-19 18-DEC-19 02-NOV-19 UI191218-12 UI191218-13 UI3001438-11 Analyte Analyte Analyte Analyte Concentration Concentration Concentration Concentration Page 59 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS Calibration Standard Solution B ICPMS Calibration Standard Solution A Description: Description: Aluminum Calcium Carbon Chloride Iron Magnesium Molybdenum Phosphorous Potassium Sodium Sulfur Titanium Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Lead Lithium Manganese Nickel Selenium Silver Strontium Thallium Thorium Uranium Vanadium Zinc Aluminum Calcium Iron Magnesium Phosphorous Potassium Sodium Analyte Analyte Analyte 1000 mg/L 1000 mg/L 2000 mg/L 10000 mg/L 1000 mg/L 1000 mg/L 20 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 20 mg/L 10 mg/L 10 mg/L 10 mg/L 20 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L Concentration Concentration Concentration Amount : Catalog Number : Lot Number : Catalog Number : Lot Number : 250 mL ZGEL-100-250 8-124AB ZGEL-102-250 8-126AB Comments: Comments: None None ICPMSCalSPIKEB ICPMSCalSPIKEA Name: Name: Source Material Source Material Type: Type: 03-DEC-19 03-DEC-19 Received: Received: 30-NOV-20 30-NOV-20 Expires: Expires: SPEX SPEX Supplier: Supplier: Paul Boyd Paul Boyd Employee: Employee: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: 03-DEC-19 03-DEC-19 UMS191203-01 UMS191203-02 Analyte Analyte Analyte Concentration Concentration Concentration Page 60 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS Calibration Standard Solution C ICPMS Calibration Standard (100 ppb) Description: Description: Antimony Molybdenum Tin Titanium Zirconium Analyte 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L Concentration Parent Material UI191112-03 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-01 UMS191203-02 UMS191203-02 UMS191203-02 UMS191203-02 Amount : Catalog Number : Lot Number : Amount : Balance Id : Pipet Id : Solvent : 250 ml ZGEL-101-250 8-125AB 50 mL 4025216 3541598 2%HNO3/1%HCl -3032237 Comments: Comments: None None Analyte Final Conc.Parent Conc.Aliquot Final Vol. 10 mg/L 10 mg/L 10 mg/L 10 mg/L 20 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 100 ug/l 100 ug/l 100 ug/l 100 ug/l 200 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 10000 ug/l 10000 ug/l 10000 ug/l 10000 ug/l Tungsten Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Lead Lithium Manganese Nickel Selenium Silver Strontium Thallium Thorium Uranium Vanadium Zinc Aluminum Calcium Iron Magnesium ICPMSCalSPIKEC ICPMS Cal Standard 100 Name: Name: Source Material Working Type: Type: 03-DEC-19 31-JAN-20 Received: Received: 30-NOV-20 01-FEB-20 Expires: Expires: SPEX GEL Supplier: Supplier: Paul Boyd Paul Boyd Employee: Employee: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: 03-DEC-19 31-JAN-20 UMS191203-03 WMS200131-04 Analyte Concentration Page 61 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS Calibration Standard (10 ppb)Description: Parent Material Parent Material UMS191203-02 UMS191203-02 UMS191203-02 UMS191203-03 UMS191203-03 UMS191203-03 UMS191203-03 UMS191203-03 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 Balance Id : Pipet Id : Solvent : 4025216 3541598 2%HNO3/1%HCl -3032237 Comments:None Analyte Analyte Final Conc. Final Conc. Parent Conc. Parent Conc. Aliquot Aliquot Final Vol. Final Vol. 1000 mg/L 1000 mg/L 1000 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10 mg/L 10000 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 200 ug/l 100 ug/l 10000 ug/l 100 ug/l 100 ug/l 100 ug/l 10000 ug/l 100 ug/l 100 ug/l 10000 ug/l 100 ug/l 100 ug/l 100 ug/l 10000 ug/l 10000 ug/l 100 ug/l 100 ug/l 10000 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 5 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 10000 ug/l 10000 ug/l 10000 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 1000 ug/l 10 ug/l 10 ug/l 10 ug/l 10 ug/l 20 ug/l 10 ug/l 1000 ug/l 10 ug/l 10 ug/l 10 ug/l 1000 ug/l 10 ug/l 10 ug/l 1000 ug/l 10 ug/l 10 ug/l 10 ug/l 1000 ug/l 1000 ug/l 10 ug/l 10 ug/l 1000 ug/l 10 ug/l 10 ug/l 10 ug/l 10 ug/l Phosphorous Potassium Sodium Antimony Molybdenum Tin Titanium Zirconium Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Phosphorous Potassium Selenium Silver Sodium Strontium Thallium Thorium Tin ICPMS Cal Standard 10Name: WorkingType: 31-JAN-20Received: 01-FEB-20Expires: GELSupplier: Paul BoydEmployee: Serial ID:Open/Reference Date:31-JAN-20WMS200131-04A Page 62 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS ICVDescription: Parent Material Parent Material WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 WMS200131-04 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-07 UI191102-09 UI191102-09 UI191102-09 UI191102-09 UI191102-09 UI191102-09 UI191102-09 UI191204-08 UI191204-08 UI191204-08 Balance Id : Pipet Id : Solvent : BAL216 3541598 2%HNO3/1%HCl -3032237 Comments:None Analyte Analyte Final Conc. Final Conc. Parent Conc. Parent Conc. Aliquot Aliquot Final Vol. Final Vol. 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 100 ug/l 20 mg/L 20 mg/L 20 mg/L 40 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 20 mg/L 2020 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 2000 mg/L 20 mg/L 20 mg/L 20 mg/L 50 mL 50 mL 50 mL 50 mL 50 mL 50 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 1000 mL 10 ug/l 10 ug/l 10 ug/l 10 ug/l 10 ug/l 10 ug/l 50 ug/L 50 ug/L 50 ug/L 100 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 5050 ug/L 5000 ug/L 5000 ug/L 5000 ug/L 5000 ug/L 5000 ug/L 5000 ug/L 50 ug/L 50 ug/L 50 ug/L Titanium Tungsten Uranium Vanadium Zinc Zirconium Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Lead Lithium Manganese Nickel Selenium Strontium Thallium Thorium Uranium Vanadium Zinc Aluminum Calcium Iron Magnesium Phosphorous Potassium Sodium Antimony Molybdenum Silver ICPMS ICVName: WorkingType: 31-JAN-20Received: 01-FEB-20Expires: GELSupplier: Paul BoydEmployee: Serial ID:Open/Reference Date:31-JAN-20WMS200131-05 Page 63 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS CRDLDescription: Parent Material Parent Material UI191204-08 UI191204-08 UI191204-08 UI191204-08 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-09 UI190415-10 UI190415-10 UI190415-10 UI190415-10 UI190415-10 Balance Id : Pipet Id : Solvent : BAL216 3820544 2%HNO3/1%HCl - 3032237 Comments:None Analyte Analyte Final Conc. Final Conc. Parent Conc. Parent Conc. Aliquot Aliquot Final Vol. Final Vol. 20 mg/L 20 mg/L 20 mg/L 20 mg/L 50 mg/L 5 mg/L 4 mg/L .5 mg/L 15 mg/L 1 mg/L 200 mg/L 30 mg/L 1 mg/L 2 mg/L 100 mg/L 2 mg/L 10 mg/L 30 mg/L 5 mg/L 2 mg/L 50 mg/L 300 mg/L 5 mg/L 250 mg/L 10 mg/L 2 mg/L 2 mg/L .2 mg/L 20 mg/L 20 mg/L 3 mg/L 1 mg/L 1 mg/L 5 mg/L 10 mg/L 2.5 mL 2.5 mL 2.5 mL 2.5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL .5 mL 1000 mL 1000 mL 1000 mL 1000 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 500 mL 50 ug/L 50 ug/L 50 ug/L 50 ug/L 50 ug/L 5 ug/L 4 ug/L .5 ug/L 15 ug/L 1 ug/L 200 ug/L 10 ug/L 1 ug/L 2 ug/L 100 ug/L 2 ug/L 10 ug/L 30 ug/L 5 ug/L 2 ug/L 50 ug/L 300 ug/L 5 ug/L 250 ug/L 10 ug/L 2 ug/L 2 ug/L .2 ug/L 20 ug/L 20 ug/L 3 ug/L 1 ug/L 1 ug/L 5 ug/L 10 ug/L Tin Titanium Tungsten Zirconium Aluminum Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Nickel Phosphorous Potassium Selenium Sodium Strontium Thallium Thorium Uranium Vanadium Zinc Antimony Molybdenum Silver Tin Titanium ICPMS CRDLName: WorkingType: 31-JAN-20Received: 01-FEB-20Expires: GELSupplier: Paul BoydEmployee: Serial ID:Open/Reference Date:31-JAN-20WMS200131-06 Page 64 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC ICPMS ICSA NexION ICPMS ICSAB NexION Description: Description: Parent Material Parent Material Parent Material UI190415-10 UI190415-10 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 Balance Id : Lot Number : Pipet Id : Solvent : Balance Id : Pipet Id : Solvent : BAL216 1064482 3541598 2%HNO3/1%HCl -3032237 BAL216 1758088 2%HNO3/1%HCl -3032237 Comments: Comments: None None Analyte Analyte Analyte Final Conc. Final Conc. Final Conc. Parent Conc. Parent Conc. Parent Conc. Aliquot Aliquot Aliquot Final Vol. Final Vol. Final Vol. 5 mg/L 2 mg/L 1000 mg/L 1000 mg/L 2000 mg/L 10000 mg/L 1000 mg/L 1000 mg/L 20 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 20 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L .5 mL .5 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 500 mL 500 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 5 ug/L 10 ug/L 100000 ug/L 100000 ug/L 200000 ug/L 1000000 ug/L 100000 ug/L 100000 ug/L 2000 ug/L 100000 ug/L 100000 ug/L 100000 ug/L 100000 ug/L 2000 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20.804 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 26.141 ug/L Tungsten Zirconium Aluminum Calcium Carbon Chloride Iron Magnesium Molybdenum Phosphorous Potassium Sodium Sulfur Titanium Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Lead Lithium Manganese ICPMS ICSA ICPMS ICSAB Name: Name: Working Working Type: Type: 31-JAN-20 31-JAN-20 Received: Received: 01-FEB-20 01-FEB-20 Expires: Expires: GEL GEL Supplier: Supplier: Paul Boyd Paul Boyd Employee: Employee: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: 31-JAN-20 31-JAN-20 WMS200131-20 WMS200131-21 Page 65 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC HYDROCHLORIC ACID HYDROCHLORIC ACID Description: Description: Parent Material UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-12 UI191218-13 UI191218-13 UI191218-13 UI191218-13 UI191218-13 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 UI3001438-11 Lot Number : Lot Number : 2019092697 2019111458 Comments: Comments: None None Analyte Final Conc.Parent Conc.Aliquot Final Vol. 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 2 mg/L 1000 mg/L 1000 mg/L 2000 mg/L 10000 mg/L 1000 mg/L 1000 mg/L 20 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 1000 mg/L 20 mg/L 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 2.5 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 25 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 250 mL 20 ug/L 20 ug/L 23.162 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 20 ug/L 100000 ug/L 100000 ug/L 200000 ug/L 1000000 ug/L 100000 ug/L 100000 ug/L 2000 ug/L 100000 ug/L 100000 ug/L 100000 ug/L 100000 ug/L 2000 ug/L Nickel Selenium Strontium Thallium Thorium Uranium Vanadium Zinc Antimony Silver Tin Tungsten Zirconium Aluminum Calcium Carbon Chloride Iron Magnesium Molybdenum Phosphorous Potassium Sodium Sulfur Titanium I-HCL I-HCL Name: Name: Reagent/Solvent Reagent/Solvent Type: Type: 17-DEC-19 20-JAN-20 Received: Received: 17-DEC-21 20-JAN-22 Expires: Expires: VWR VWR Supplier: Supplier: Edmund Frampton Edmund Frampton Employee: Employee: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: 30-DEC-19 20-JAN-20 191217 200120 Page 66 of 84 SDG: EUI-11350 Standard Logbook Report run on: 04-FEB-20 Page:GEL Laboratories LLC Concentrated Nitric Acid Concentrated Nitric Acid 2%HNO3/1%HCl Solution (Type I Water) Description: Description: Description: Parent Material 191217 3000723 Lot Number : Lot Number : Solvent : 0000226537 2019100718 Type I Water Comments: Comments: Comments: None None None Analyte Final Conc.Parent Conc.Aliquot Final Vol. 36.5-38.0 68.0-70.0% 80 mL 160 mL 8 l 8 l N/A N/A I-HCL I-HNO3 I-HNO3 I-HNO3 B-2%HNO3/1%HCl-ICPMS Name: Name: Name: Reagent/Solvent Reagent/Solvent Reagent/Solvent Type: Type: Type: 31-OCT-19 26-NOV-19 20-JAN-20 Received: Received: Received: 31-OCT-21 26-NOV-21 03-FEB-20 Expires: Expires: Expires: VWR - BDH Chemicals VWR - BDH Chemicals GEL Supplier: Supplier: Supplier: Edmund Frampton Hannah Hatherly Paul Boyd Employee: Employee: Employee: Serial ID: Serial ID: Serial ID: Open/Reference Date: Open/Reference Date: Open/Reference Date: 10-DEC-19 20-JAN-20 3000723 3011870 3032237 Page 67 of 84 SDG: EUI-11350 Radiological Analysis Page 68 of 84 SDG: EUI-11350 Case Narrative Page 69 of 84 SDG: EUI-11350 Radiochemistry Technical Case Narrative EnergySolutions LLC SDG #: EUI-11350 Work Order #: 502174 Product: Alphaspec Th-228, 230, 232, Liquid Analytical Method: DOE EML HASL-300, Th-01-RC Modified Analytical Procedure: GL-RAD-A-038 REV# 18 Analytical Batch: 1962978 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 502174001 I-1-700 011720-01 1204484437 Method Blank (MB) 1204484438 502174001(I-1-700 011720-01) Sample Duplicate (DUP) 1204484439 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Technical Information Recounts Samples 1204484438 (I-1-700 011720-01DUP) and 502174001 (I-1-700 011720-01) were given additional clean-up steps and recounted in order to remove suspected interferences. The recounts are reported. Product: Alphaspec U-233/234, 235/236, 238, Liquid Analytical Method: DOE EML HASL-300, U-02-RC Modified Analytical Procedure: GL-RAD-A-011 REV# 27 Analytical Batch: 1962983 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 502174001 I-1-700 011720-01 1204484441 Method Blank (MB) 1204484442 502174001(I-1-700 011720-01) Sample Duplicate (DUP) 1204484443 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Page 70 of 84 SDG: EUI-11350 Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Quality Control (QC) Information Duplication Criteria between QC Sample and Duplicate Sample The Sample and the Duplicate, (See Below), did not meet the relative percent difference requirement; however, they do meet the relative error ratio requirement with the value listed below. Sample Analyte Value 1204484442 (I-1-700 011720-01DUP)Uranium-233/234 RPD 27.6* (0.00%-20.00%) RER 1.63 (0-3) Product: Gammaspec, Gamma, K-40 Analytical Method: DOE EML HASL-300 Analytical Procedure: GL-RAD-A-013 REV# 27 Analytical Batch: 1962483 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 502174001 I-1-700 011720-01 1204483327 Method Blank (MB) 1204483328 502174001(I-1-700 011720-01) Sample Duplicate (DUP) 1204483329 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable. Product: GFPC Ra228, Liquid Analytical Method: EPA 904.0/SW846 9320 Modified Analytical Procedure: GL-RAD-A-009 REV# 17 Analytical Batch: 1962818 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 502174001 I-1-700 011720-01 Page 71 of 84 SDG: EUI-11350 1204484083 Method Blank (MB) 1204484084 502174001(I-1-700 011720-01) Sample Duplicate (DUP) 1204484085 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable. Product: GFPC Gross A/B, Liquid Analytical Method: EPA 900.0/SW846 9310 Analytical Procedure: GL-RAD-A-001 REV# 20 Analytical Batch: 1962821 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 502174001 I-1-700 011720-01 1204484086 Method Blank (MB) 1204484087 502174001(I-1-700 011720-01) Sample Duplicate (DUP) 1204484088 502174001(I-1-700 011720-01) Matrix Spike (MS) 1204484089 502174001(I-1-700 011720-01) Matrix Spike Duplicate (MSD) 1204484090 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Preparation Information Aliquot Reduced aliquot volumes were reduced due to the sample matrix. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with the other sample aliquots. Sample Analyte Value 1204484086 (MB)ALPHA Result -45.6 < MDA 86.3 > RDL 5 pCi/L BETA Result -8.1 < MDA 151 > RDL 5 pCi/L Page 72 of 84 SDG: EUI-11350 Samples (See Below) did not meet the required detection limits due to low sample volume. No more volume could be used due to not exceeding the maximum net weight limit of the calibration curve. The samples counted for 500 minutes. Sample Analyte Value 1204484087 (I-1-700 011720-01DUP)ALPHA Result 142 < MDA 249 > RDL 5 pCi/L 502174001 (I-1-700 011720-01)ALPHA Result 91.5 < MDA 189 > RDL 5 pCi/L Technical Information Gross Alpha/Beta Preparation Information High hygroscopic salt content in evaporated samples can cause the sample mass to fluctuate due to moisture absorption. To minimize this interference, the salts are converted to oxides by heating the sample under a flame until a dull red color is obtained. The conversion to oxides stabilizes the sample weight and ensures that proper alpha/beta efficiencies are assigned for each sample. Volatile radioisotopes of carbon, hydrogen, technetium, polonium and cesium may be lost during sample heating. Product: Lucas Cell, Ra226, Liquid Analytical Method: EPA 903.1 Modified Analytical Procedure: GL-RAD-A-008 REV# 15 Analytical Batch: 1962720 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 502174001 I-1-700 011720-01 1204483826 Method Blank (MB) 1204483827 502174001(I-1-700 011720-01) Sample Duplicate (DUP) 1204483828 502174001(I-1-700 011720-01) Matrix Spike (MS) 1204483829 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Quality Control (QC) Information Duplication Criteria between QC Sample and Duplicate Sample The Sample and the Duplicate, (See Below), did not meet the relative percent difference requirement; however, they do meet the relative error ratio requirement with the value listed below. Sample Analyte Value 1204483827 (I-1-700 011720-01DUP)Radium-226 RPD 41.8* (0.00%-20.00%) RER 2.38 (0-3) Page 73 of 84 SDG: EUI-11350 Technical Information Recounts Sample 1204483826 (MB) was recounted due to a suspected blank false positive. The recount is reported. Miscellaneous Information Additional Comments The matrix spike, 1204483828 (I-1-700 011720-01MS), aliquot was reduced to conserve sample volume. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Page 74 of 84 SDG: EUI-11350 GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com CARE009 EnergySolutions LLC (693694) Client SDG: EUI-11350 GEL Work Order: 502174 GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverables receive a third level review of the fractional data package. The following data validator verified the information presented in this data report: The Qualifiers in this report are defined as follows: * A quality control analyte recovery is outside of specified acceptance criteria ** Analyte is a Tracer compound U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD. for Qualifier Definition Report Signature:Name: Date:Title:12 FEB 2020 Heather McCarty Analyst II Review/Validation Page 75 of 84 SDG: EUI-11350 Sample Data Summary Page 76 of 84 SDG: EUI-11350 Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: February 11, 2020 Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLMDCPF Rad Alpha Spec Analysis Rad Gamma Spec Analysis Rad Gas Flow Proportional Counting Rad Radium-226 1962978 1962983 1962483 1962821 1962818 1962720 0803 1208 1716 1906 0940 1212 pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L 02/03/20 01/28/20 01/25/20 02/05/20 02/05/20 02/10/20 HAKB HAKB RYH1 JXC9 JXK3 MXH8 1.00 1.00 1.00 1.00 1.00 1.00 5.00 5.00 3.00 1.00 Mr. Jared StarkContact: EnergySolutions, LLC.Company : 299 South Main Street, Suite 1700 Salt Lake City, Utah 84111 Address : EUI-11 Environmental Monitoring-RadProject: 502174001 Water 16-JAN-20 15:14 24-JAN-20 I-1-700 011720-01 CARE EUI-11Project: CARE009Client ID: Client +/-0.366 +/-0.430 +/-0.252 +/-2.09 +/-0.351 +/-1.43 +/-96.3 +/-112 +/-157 +/-1.80 +/-0.559 Sample ID: Receive Date: Client Sample ID: Surrogate/Tracer Recovery Matrix: Collect Date: Collector: Recovery%Test Acceptable Limits 0.662 0.730 0.501 0.746 0.557 0.451 61.2 189 248 1.78 0.312 1 2 3 4 5 6 U U U U U Thorium-228 Thorium-230 Thorium-232 Uranium-233/234 Uranium-235/236 Uranium-238 Potassium-40 Alpha Beta Radium-228 Radium-226 Alphaspec Th-228, 230, 232, Liquid "As Received" Alphaspec U-233/234, 235/236, 238, Liquid "As Received" Gammaspec, Gamma, K-40 "As Received" GFPC Gross A/B, Liquid "As Received" GFPC Ra228, Liquid "As Received" Lucas Cell, Ra226, Liquid "As Received" 0.136 0.228 0.0370 13.6 0.153 6.39 478 91.5 495 8.14 2.71 Thorium-229 Tracer Uranium-232 Tracer Barium-133 Tracer Alphaspec Th-228, 230, 232, Liquid "As Received" Alphaspec U-233/234, 235/236, 238, Liquid "As Received" GFPC Ra228, Liquid "As Received" 59.9 86.9 69.6 (15%-125%) (15%-125%) (15%-125%) The following Analytical Methods were performed: 1 2 3 4 5 6 Method Description DOE EML HASL-300, Th-01-RC Modified DOE EML HASL-300, U-02-RC Modified DOE EML HASL-300 EPA 900.0/SW846 9310 EPA 904.0/SW846 9320 Modified EPA 903.1 Modified Analyst Comments Uncertainty NominalResult Page 77 of 84 SDG: EUI-11350 Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: February 11, 2020 Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLMDCPF Mr. Jared StarkContact: EnergySolutions, LLC.Company : 299 South Main Street, Suite 1700 Salt Lake City, Utah 84111 Address : EUI-11 Environmental Monitoring-RadProject: 502174001 I-1-700 011720-01 CARE EUI-11Project: CARE009Client ID:Sample ID: Client Sample ID: Uncertainty Notes: Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma). Lc/LC: Critical Level PF: Prep Factor RL: Reporting Limit SQL: Sample Quantitation Limit Column headers are defined as follows: DF: Dilution Factor DL: Detection Limit MDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration Page 78 of 84 SDG: EUI-11350 Quality Control Summary Page 79 of 84 SDG: EUI-11350 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Alpha Spec 1962978 1962983 Batch Batch Thorium-228 Thorium-230 Thorium-232 Thorium-228 Thorium-230 Thorium-232 Thorium-228 Thorium-230 Thorium-232 Uranium-233/234 Uranium-235/236 Uranium-238 Parmname Mr. Jared StarkContact: EnergySolutions, LLC. 299 South Main Street, Suite 1700 Salt Lake City, Utah February 11, 2020Report Date: Units pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L Anlst Date Time HAKB HAKB 02/03/20 08:03 01/29/20 12:49 01/29/20 12:49 01/28/20 12:08 QC 0.153 0.535 0.0561 21.5 2.44 20.5 0.137 0.313 0.0827 10.3 0.317 5.67 NOM Sample 0.136 0.228 0.0370 13.6 0.153 6.39 Range N/A N/A N/A (75%-125%) (75%-125%) (0%-20%) N/A (0%-20%) Qual U U U U U U U QC1204484438 502174001 QC1204484439 QC1204484437 QC1204484442 502174001 N/A N/A N/A 27.6 N/A 11.9 REC% 10319.9 DUP LCS MB DUP 502174Workorder: U U U U +/-0.366 +/-0.430 +/-0.252 +/-2.09 +/-0.351 +/-1.43 +/-0.354 +/-0.504 +/-0.242 +/-2.30 +/-0.822 +/-2.24 +/-0.409 +/-0.424 +/-0.311 +/-2.14 +/-0.560 +/-1.59 * RPD% Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 1 of 5 Page 80 of 84 SDG: EUI-11350 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Alpha Spec Rad Gamma Spec 1962983 1962483 Batch Batch Uranium-233/234 Uranium-235/236 Uranium-238 Uranium-233/234 Uranium-235/236 Uranium-238 Potassium-40 Americium-241 Cesium-137 Cobalt-60 Potassium-40 Potassium-40 Parmname Units pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L Anlst Date Time HAKB RYH1 01/28/20 12:08 01/28/20 12:08 01/26/20 06:20 01/26/20 07:18 01/25/20 17:17 QC 26.2 2.09 28.3 0.163 -0.0206 -0.0833 561 1.20E+05 40300 28200 300 4.30 NOM Sample 478 Range (75%-125%) (0%-20%) (75%-125%) (75%-125%) (75%-125%) Qual U U U U U QC1204484443 QC1204484441 QC1204483328 502174001 QC1204483329 QC1204483327 16 REC% 104 110 102 104 27.3 1.09E+05 39600 27000 LCS MB DUP LCS MB 502174Workorder: +/-96.3 +/-4.36 +/-1.52 +/-4.55 +/-0.346 +/-0.178 +/-0.158 +/-89.9 +/-4010 +/-858 +/-855 +/-478 +/-47.9 RPD% Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 2 of 5 Page 81 of 84 SDG: EUI-11350 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Gas Flow 1962818 1962821 Batch Batch Radium-228 Radium-228 Radium-228 Alpha Beta Alpha Beta Alpha Beta Alpha Beta Alpha Beta Parmname Units pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L Anlst Date Time JXK3 JXC9 02/05/20 09:40 02/05/20 09:40 02/05/20 09:40 02/05/20 19:07 02/05/20 17:10 02/05/20 19:07 02/05/20 17:10 02/05/20 17:10 QC 9.97 57.8 0.186 142 472 11700 48500 -45.6 -8.10 9470 47400 9980 46300 NOM Sample 8.14 91.5 495 91.5 495 91.5 495 Range (0% - 100%) (75%-125%) N/A (0% - 100%) (75%-125%) (75%-125%) (75%-125%) (75%-125%) (0%-20%) (0%-20%) Qual U U U U QC1204484084 502174001 QC1204484085 QC1204484083 QC1204484087 502174001 QC1204484090 QC1204484086 QC1204484088 502174001 QC1204484089 502174001 20.2 N/A 4.94 5.21 2.19 REC% 98.1 93.5 108 75.6 104 79.6 102 58.9 12500 45000 12500 45000 12500 45000 DUP LCS MB DUP LCS MB MS MSD 502174Workorder: U U U +/-1.80 +/-112 +/-157 +/-112 +/-157 +/-112 +/-157 +/-2.23 +/-3.86 +/-0.658 +/-150 +/-128 +/-1160 +/-1700 +/-37.8 +/-86.6 +/-1820 +/-1760 +/-1880 +/-1730 RPD% Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 3 of 5 Page 82 of 84 SDG: EUI-11350 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Rad Ra-226 1962720Batch Radium-226 Radium-226 Radium-226 Radium-226 Parmname Units pCi/L pCi/L pCi/L pCi/L Anlst Date Time MXH8 02/10/20 12:12 02/10/20 12:43 02/10/20 13:44 02/10/20 12:12 QC 4.14 27.9 0.180 130 NOM Sample 2.71 2.71 Range (0%-20%) (75%-125%) (75%-125%) Qual U QC1204483827 502174001 QC1204483829 QC1204483826 QC1204483828 502174001 The Qualifiers in this report are defined as follows: 41.8 REC% 103 94.1 27.1 135 DUP LCS MB MS 502174Workorder: ** < > BD FA H J J K L M M N/A N1 ND NJ Q R U UI Analyte is a Tracer compound Result is less than value reported Result is greater than value reported Results are either below the MDC or tracer recovery is low Failed analysis. Analytical holding time was exceeded See case narrative for an explanation Value is estimated Analyte present. Reported value may be biased high. Actual value is expected to be lower. Analyte present. Reported value may be biased low. Actual value is expected to be higher. M if above MDC and less than LLD REMP Result > MDC/CL and < RDL RPD or %Recovery limits do not apply. See case narrative Analyte concentration is not detected above the detection limit Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier One or more quality control criteria have not been met. Refer to the applicable narrative or DER. Sample results are rejected Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD. Gamma Spectroscopy--Uncertain identification +/-0.559 +/-0.559 +/-0.689 +/-1.72 +/-0.167 +/-9.77 * RPD% Uncertainty Uncertainty Uncertainty Uncertainty Notes: Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma). Page 4 of 5 Page 83 of 84 SDG: EUI-11350 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Parmname Page 5 of 5 Units Anlst Date TimeQCNOMSampleRangeQualREC% 502174Workorder: UJ UL X Y ^ h Gamma Spectroscopy--Uncertain identification Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias. Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Other specific qualifiers were required to properly define the results. Consult case narrative. RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry. Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable. ^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. * Indicates that a Quality Control parameter was not within specifications. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. RPD% Page 84 of 84 SDG: EUI-11350