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HomeMy WebLinkAboutDRC-2020-011934 - 0901a06880cc83a6Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 w ww.energyfuels.com ENERGY FUELS June 24, 2020 DRC-2012O-ol.93 Div of Waste Management and Radiation Control Sent VIA E-MAIL AND OVERNIGHT DELIVERY Mr. Ty L. Howard Director Division of Waste Management and Radiation Control Utah Department of Environmental Quality 195 North 1950 West P.O. Box 144880 Salt Lake City, UT 84114-4880 JUN 2 6 2020 Re: Transmittal of Source Assessment Report for MW-31 White Mesa Mill Groundwater Discharge Permit UGW370004 Dear Mr. Howard: Enclosed are two copies of Energy Fuels Resource (USA) Inc.'s ("EFRI's") Source Assessment Report ("SAR") for MW-31 at the White Mesa Mill. This SAR addresses the constituents that were identified as exceeding the GWCL in the 4th Quarter 2019 as described in the Division of Waste Management and Radiation Control ("DWMRC")-approved Q4 2019 Plan and Time Schedule. EFRI submitted the Plan and Time Schedule for MW-31 on February 27, 2020. DWMRC approval of the Plan and Time Schedule was received by EFRI on March 26, 2020. Pursuant to the Plan and Time Schedule EFRI has prepared this SAR. This transmittal also includes two CDs each containing a word searchable electronic copy of the report. If you should have any questions regarding this report please contact me. Yours very truly, 9104itike-Liti, ENERGY FUELS RESOURCES (USA) INC. Kathy Weinel Quality Assurance Manager CC: David C. Frydenlund Paul Goranson Terry Slade Logan Shurnway Scott Bakken Stewart Smith (HGC) June 24, 2020 Sent VIA E-MAIL AND OVERNIGHT DELIVERY Mr. Ty L. Howard Director Division of Waste Management and Radiation Control Utah Department of Environmental Quality 195 North 1950 West P.O. Box 144880 Salt Lake City, UT 84114-4880 Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 www.enern:yfuel..com Re: Transmittal of Source Assessment Report for MW-31 White Mesa Mill Groundwater Discharge Permit UGW370004 Dear Mr. Howard: Enclosed are two copies of Energy Fuels Resource (USA) Inc.'s ("EFRI's") Source Assessment Report ("SAR") for MW-31 at the White Mesa Mill. This SAR addresses the constituents that were identified as exceeding the GWCL in the 4th Quarter 2019 as described in the Division of Waste Management and Radiation Control ("DWMRC")-approved Q4 2019 Plan and Time Schedule. EFRI submitted the Plan and Time Schedule for MW-31 on February 27, 2020. DWMRC approval of the Plan and Time Schedule was received by EFRI on March 26, 2020. Pursuant to the Plan and Time Schedule EFRI has prepared this SAR. This transmittal also includes two CDs each containing a word searchable electronic copy of the report. If you should have any questions regarding this report please contact me. Yours very truly, c/(M;iv~ ENERGY FUELS RESOURCES (USA) INC. Kathy Weinel Quality Assurance Manager CC: David C. Frydenlund Paul Goranson Terry Slade Logan Shumway Scott Bakken Stewart Smith (HGC) SOURCE ASSESSMENT REPORT FOR MW-31 WHITE MESA URANIUM MILL Blanding, Utah Prepared for: Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, Colorado 80228 Prepared by: 6000 Uptown Boulevard NE, Suite 220 Albuquerque, New Mexico 87110 June 24, 2020 Source Assessment Report for MW-31 White Mesa Uranium Mill, Blanding, Utah SOURCE ASSESSMENT REPORT FOR MW-31 WHITE MESA URANIUM MILL Blanding, Utah Prepared for: Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, Colorado 80228 Prepared Under the Supervision of: ___________________________________ Bryn E. Kimball, PG Utah Registration Number 10823695-2250 Expires 03/31/2021 Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah ES-i June 24, 2020 EXECUTIVE SUMMARY This Source Assessment Report (“SAR”) is an assessment of the sources, extent, and potential dispersion of sulfate and total dissolved solids (“TDS”) in MW-31 at the White Mesa Mill (“the Mill”) as required under State of Utah Groundwater Discharge Permit UGW370004 (the “GWDP”) Part I.G.4, relating to violations of Part I.G.2 of the GWDP. Each of these constituents occur naturally at the Mill (INTERA, 2008) and have exhibited exceedances of the applicable Groundwater Compliance Limits (“GWCLs”). MW-31 has been included in multiple recent investigations and reports including the New Wells Background Report (INTERA, 2008), an isotopic investigation (Hurst and Solomon, 2008), and four SAR reports (INTERA, 2012a, 2013, 2015, 2017). Sulfate and TDS in MW-31 were most recently assessed and included in the 2017 SAR. The 2017 SAR concluded that increasing concentrations of sulfate and TDS could be attributed to natural background and site-wide influences (oxidation of pyrite and decreasing pH) or to impacts at the Mill site that are already being addressed with an existing corrective action (nitrate/chloride plume capture). In a letter dated March 20, 2018, the State of Utah Division of Waste Management and Radiation Control (“DWMRC”) stated, “it appears that Mill activities are not influencing SAR studied concentrations at monitoring well MW-31.” The 2017 SAR and the associated modified GWCLs, as presented in the March 20, 2018 letter from DWMRC, were approved. Increasing trends in concentrations have continued in MW-31, prompting additional exceedances and out-of-compliance (“OOC”) status and resulting in the need for this SAR. Analytical results for constituents included in this SAR exhibit increases in concentrations over time, which are likely due to the location of this well within the nitrate/chloride plume and the result of oxidation of pyrite in the formation around and upgradient of this well. To a lesser extent, increased frequency of sampling and well redevelopment have also likely affected the behavior of constituents in MW-31. In addition, changes in analytical methods and/or changing the analytical laboratory may affect the concentrations of constituents reported for MW-31. As the results of this analysis will demonstrate, concentrations of sulfate and TDS in MW-31 are within the range of site-wide background and are likely influenced by oxidation of pyrite. Mass balance calculations (Appendix E) demonstrate that concentrations in MW-31 are not consistent with impacts from potential tailings system seepage. Once again, this SAR concludes that the exceedances of sulfate and TDS in MW-31 can be attributed to natural background and site-wide influences (oxidation of pyrite and decreasing pH) or to impacts at the Mill site that are already being addressed with an existing corrective action (nitrate/chloride plume capture). The conclusions of this analysis are consistent with conclusions presented in the Background Reports (INTERA 2007a, 2007b, 2008) and other recent analyses. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah ES-ii June 24, 2020 In accordance with the DWMRC-approved Flowsheet (from INTERA [2007a], included as Appendix H), increasing trends necessitate a modified approach for calculation of GWCLs. The modification in this approach uses a more recent dataset (collected after May 2014) and the greater of (1) mean concentration plus two standard deviations (“mean + 2σ”), (2) highest historical value, (3) background x 1.5, (4) the fractional approach, or (5) the upper tolerance limit to determine representative and appropriate GWCLs for trending constituents. Regular revisions to GWCLs for constituents in wells with significantly increasing trends over time due to background is consistent with the United States Environmental Protection Agency’s Unified Guidance (USEPA, 2009). Such revisions account for the trends and minimize unwarranted OOC status in such wells. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah i June 24, 2020 TABLE OF CONTENTS EXECUTIVE SUMMARY ..................................................................................................... ES-i LIST OF TABLES ........................................................................................................................ ii LIST OF FIGURES ...................................................................................................................... ii LIST OF APPENDICES .............................................................................................................. ii ABBREVIATIONS AND ACRONYMS .................................................................................... iv 1.0 INTRODUCTION............................................................................................................. 1 1.1 Source Assessment Report Organization ................................................................ 3 1.2 Limitations Statement ............................................................................................. 4 2.0 CATEGORIES AND APPROACH FOR ANALYSIS .................................................. 5 2.1 Approach for Analysis ............................................................................................ 5 2.2 Approach for Setting Revised GWCLs ................................................................... 7 2.3 University of Utah Study ........................................................................................ 7 3.0 RESULTS OF ANALYSIS............................................................................................... 9 3.1 Site-Wide Decreasing pH ....................................................................................... 9 3.2 Changes in Groundwater in MW-31 ..................................................................... 10 3.3 Indicator Parameter Analysis ................................................................................ 10 3.4 pH Analysis ........................................................................................................... 12 3.5 Mass Balance Analyses......................................................................................... 12 3.6 Summary of Results .............................................................................................. 15 3.6.1 Sulfate ...................................................................................................... 15 3.6.2 Total Dissolved Solids ............................................................................. 15 4.0 CALCULATION OF GROUNDWATER COMPLIANCE LIMITS ........................ 16 4.1 Evaluation of Modified Approaches to Calculation of GWCLs for Trending Constituents........................................................................................................... 16 4.2 Proposed Revised GWCLs ................................................................................... 18 5.0 CONCLUSIONS AND RECOMMENDATIONS ........................................................ 19 6.0 REFERENCES ................................................................................................................ 21 Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah ii June 24, 2020 LIST OF TABLES Table 1. White Mesa Uranium Mill SARs ...................................................................................... 2 Table 2. Proposed GWCLs ........................................................................................................... 18 Table 3. MW-31 Summary of Findings ........................................................................................ 20 LIST OF FIGURES Figure 1 Location of White Mesa Mill Site Figure 2 Exceedances and Proximity of MW-31 to Chloride Plume Figure 3 Exceedances and Proximity of MW-31 to Nitrate Plume Figure 4 Groundwater Elevation over Time in MW-31 Figure 5 Groundwater Elevation Contours Figure 6 Ratio of Chloride to Fluoride Concentrations in MW-31 Figure 7 Ratio of Chloride to Sulfate Concentrations in MW-31 Figure 8 Ratio of Chloride to Uranium Concentrations in MW-31 LIST OF APPENDICES Appendix A GWCL Exceedances for Fourth Quarter 2019 under the March 19, 2019 GWDP Appendix B Statistical Analysis for MW-31 SAR Constituents B-1 Statistical Analysis Summary Table B-2 Comparison of Calculated and Measured TDS for Samples with Complete Major Ions B-3 Charge Balance Calculations B-4 Descriptive Statistics B-5 Data Used for Statistical Analysis B-6 Box Plots for MW-31 SAR Constituents B-7 Box Plots for SAR Constituents in MW-31 and in Upgradient and Downgradient Wells B-8 Box Plots for SAR Constituents in All Groundwater Monitoring Wells B-9 Histograms B-10 Linear Regressions B-11 Time Series with Events Appendix C Statistical Analysis for Indicator Parameters in MW-31 C-1 Indicator Parameter Analysis Summary Table C-2 Descriptive Statistics of Indicator Parameters in MW-31 C-3 Data Used for Statistical Analysis C-4 Data Omitted from Statistical Analysis C-5 Box Plots for Indicator Parameters in MW-31 Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah iii June 24, 2020 C-6 Box Plots for Indicator Parameters in MW-31 and Upgradient and Downgradient Wells C-7 Piper Diagram for Cell 1, MW-31, and Upgradient and Downgradient Wells C-8 Histograms for Indicator Parameters in MW-31 C-9 Time Series Plots for Lognormally or Normally Distributed Constituents C-10 Time Series with Events Appendix D pH Analysis D-1 pH Analysis Summary Table D-2 Data Used for Analysis D-3 Box Plots for pH D-4 Histograms for pH D-5 Linear Regressions for pH Appendix E Mass Balance Calculations Appendix F Flowsheet (Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site [INTERA, 2007a]) Appendix G Flowsheet Analysis for Post-Inflection Data (Modified Approach) for Purposes of Calculating GWCLs G-1 Descriptive Statistics for Modified GWCL Data Set and All Data G-2 Data Used for Modified Approach G-3 Box Plots for Modified Data Set G-4 Histograms for Modified Data Set G-5 Linear Regressions for Modified Data Set Appendix H Input and Output Files (Electronic Only) Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah iv June 24, 2020 ABBREVIATIONS AND ACRONYMS μg/L micrograms per liter 95-UTL 95% upper tolerance limit Background Reports collectively refers to relevant background reports for this well and site: the Existing Wells Background Report (INTERA, 2007a), the Regional Background Report (INTERA, 2007b), and the New Wells Background Report (INTERA, 2008) CAP Corrective Action Plan CFCs chlorofluorocarbons CIR Contaminant Investigation Report DF dilution factor Director Director of the Division of Waste Management and Radiation Control DWMRC State of Utah Division of Waste Management and Radiation Control EFRI Energy Fuels Resources (USA) Inc. Existing Wells Background Report INTERA (2007a) Flowsheet Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site, San Juan County, Utah GWCL Groundwater Compliance Limit GWDP State of Utah Ground Water Discharge Permit UGW370004 GWQS Groundwater Quality Standard INTERA INTERA Incorporated mg/L milligrams per liter Mill White Mesa Uranium Mill New Wells Background Report INTERA (2008) OOC out of compliance pH Report INTERA (2012b) Pyrite Report HGC (2012a) Q4 2019 Plan and Time Schedule plan and time schedule for MW-31 for the fourth quarter of 2019 Q4 2019 Exceedance Notice exceedance notice submitted by EFRI January 31, 2020 Regional Background Report INTERA (2007b) SAR Source Assessment Report Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah v June 24, 2020 ACRONYMS AND ABBREVIATIONS (Continued) TDS Total Dissolved Solids THF Tetrahydrofuran UAC Utah Administrative Code University of Utah Study Hurst and Solomon, (2008) USEPA United States Environmental Protection Agency Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 1 June 24, 2020 1.0 INTRODUCTION Energy Fuels Resources (USA) Inc. (“EFRI”) operates the White Mesa Uranium Mill (the “Mill”), located near Blanding, Utah (Figure 1). Groundwater is regulated under the State of Utah Groundwater Discharge Permit UGW370004 (the “GWDP”). This is the Source Assessment Report (“SAR”) required under Part I.G.4 of the GWDP, relating to Part I.G.2 of the GWDP with respect to sulfate and total dissolved solids (“TDS”) in groundwater compliance monitoring well MW-31. The sulfate and TDS exceedances were addressed in previous SARs, but have exceeded the recalculated groundwater compliance limits (“GWCLs”) specified in those SARs due to statistically significant trends noted in those previous studies. Part I.G.2 of the GWDP provides that an out-of-compliance (“OOC”) status exists when the concentration of a constituent in two consecutive samples from a compliance monitoring point exceeds a GWCL in Table 2 of the GWDP. The GWDP was originally issued in March 2005, at which time GWCLs were set on an interim basis, based on fractions of State of Utah Ground Water Quality Standards (“GWQSs”) or the equivalent, without reference to natural background at the Mill. The GWDP also required that EFRI prepare a background groundwater quality report to evaluate all historical data for the purposes of establishing background groundwater quality at the Mill site and developing GWCLs under the GWDP. As required by then Part I.H.3 of the GWDP, EFRI submitted the following three “Background Reports” to the Director (the “Director”) of the State of Utah Division of Waste Management and Radiation Control (“DWMRC”)1 (the Director was formerly the Executive Secretary of the Utah Radiation Control Board and the Co-Executive Secretary of the Utah Water Quality Board): • A revised background groundwater quality report: Existing Wells for Denison Mines (USA) Corp.’s Mill Site, San Juan County, Utah, October 2007, prepared by INTERA Incorporated (INTERA) (the “Existing Wells Background Report”). • A revised addendum: Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.’s Mill Site, San Juan County, Utah, November 16, 2007, prepared by INTERA (the “Regional Background Report”). • A revised addendum: Background Groundwater Quality Report: New Wells for Denison Mines (USA) Corp.’s Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA (the “New Wells Background Report”). Based on a review of the Background Reports and other information and analyses, the Director re- opened the GWDP and modified the GWCLs to be equal to the mean concentration plus two standard 1 Formerly referred to as the State of Utah Division of Radiation Control. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 2 June 24, 2020 deviations (“mean + 2σ ”) or the equivalent. The modified GWCLs became effective on January 20, 2010. On January 19, 2018, and March 19, 2019, revised GWDPs were issued, which set the revised GWCLs as approved by the Director through SARs. The plans and time schedules and the associated SARs for White Mesa Uranium Mill are summarized in Table 1: Table 1. White Mesa Uranium Mill SARs Plan and Time Schedule Date Monitoring Periods Covered DWMRC Plan and Time Schedule Approval Date SAR Date SAR Approval Date Constituents 6/13/2011 Q1, Q2, Q3, Q4 of 2010, Q1 of 2011 7/12/2012 10/10/2012 4/25/2013 Multiple 9/7/2011 Q2 2011 7/12/2012 10/10/2012 4/25/2013 Multiple 4/13/2012 Multiple 7/12/2012 pH report - 11/9/12 Pyrite Report - 12/7/12 4/25/2013 pH - multiple wells 12/13/2012 Q3 2012 2/4/2013 5/8/2013 7/23/2013 TDS - MW-29 3/15/2013 Q4 2012 5/30/2013 8/30/2013 9/17/2013 Se - MW-31 8/28/2013 Q1 2013 9/17/2013 12/17/2013 1/7/2014 THF - MW-01 9/20/2013 Q2 2013 10/16/2013 1/13/2014 3/10/2014 Gross Alpha - MW-32 12/5/2013 Q3 2013 12/18/2013 3/19/2014 6/5/2014 SO4 - MW-01; TDS - MW-03A 12/4/2014 Q3 2014 1/8/2015 No SAR - OOC due to well damage No SAR - OOC due to well damage U - MW-28 5/19/2015 Q1 2015 8/11/2015 Due 12/9/15* 2/19/2016 Se, SO4, TDS, pH - MW-31 9/10/2015 Q2 2015 11/10/2015 No SAR - install packer No SAR - install packer Cd, Zn, Be, Ni - MW-03 12/3/2015 Q3 2015 2/25/2016 No SAR - install packer NO SAR SO4- MW-3 3/3/2016 Q4 2015 4/4/2016 6/24/2016 12/20/2016 SO4- MW-18 F, Cd, Tl, and pH- MW-24 3/10/2017 Q4 2016 5/23/2017 8/20/2017 3/20/2018 Se, SO4, TDS, and U in MW-31 3/2/2018 Q4 2017 3/30/2018 6/25/2018 7/25/2018 F- MW-14 8/28/2018 Q2 2018 10/18/2018 1/16/2019 7/9/2019 U, Se, pH - MW-30 12/5/2018 Q3 2018 3/5/2019 6/27/2019 9/5/2019** Tl, Cd, pH - MW-24 2/21/2019 Q4 2018 3/5/2019 6/27/2019 9/5/2019 Mn - MW-11 5/13/2019 Q1 2019 6/26/2019 9/23/2019 11/26/2019 Cd - MW-25 2/27/2020 Q4 2019 3/26/2020 TDS, SO4 - MW-31 5/21/2020 Q1 2020 Se, U - MW-28 Notes: *30-day extension for SAR; ** Installed MW-24A Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 3 June 24, 2020 On January 31, 2020, EFRI submitted a notice (the “Q4 2019 Exceedance Notice”) to the Director under Part I.G.1(a) of the GWDP; providing notice that the concentrations of specific constituents in the monitoring wells at the Mill exceeded their respective GWCLs for the fourth quarter of 2019, and indicating which of those constituents had two consecutive exceedances as of that quarter. A plan and time schedule for the fourth quarter of 2019 (“Q4 2019 Plan and Time Schedule”) covered new dual exceedances of sulfate and TDS at MW-31. The MW-31 Q4 2019 Plan and Time Schedule was submitted on February 27, 2020, and was approved by the DWMRC in correspondence dated March 26, 2020. This SAR addresses the constituents that were identified as new dual exceedances or as exceeding the previously revised GWCLs in the Q4 2019 Exceedance Notice as described in the DWMRC- approved Q4 2019 Plan and Time Schedule. 1.1 Source Assessment Report Organization A description of the approach used for analysis is provided in Section 2, the results of the analysis are presented in Section 3, the calculation of GWCLs is provided in Section 4, and conclusions and recommendations are presented in Section 5. Section 6 lists references cited in the SAR. The appendices comprise the analyses performed for this Report and are organized in the following manner: Appendix A contains a table showing exceedances for Fourth Quarter 2019 under the March 19, 2019 GWDP. Appendix B contains the geochemical analysis performed on sulfate and TDS in MW-31. Appendix C contains the indicator parameter analysis performed on MW-31. Appendix D contains the pH analysis performed on MW-31. Appendix E contains mass balance calculations. Appendix F contains the Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site, San Juan County, Utah (“Flowsheet”) that was developed based on the United States Environmental Protection Agency’s (“USEPA”) Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance (USEPA, 1989, 1992, 2009). This Flowsheet was approved by DWMRC prior to completion of the Background Reports. Appendix G contains analyses of two modified data sets (post October 2012 and post May 2014) to address revising GWCLs for constituents with increasing trends. Appendix H is included on the compact disc that accompanies this SAR and contains the electronic input and output files used for statistical analysis. Statistical analysis was performed using the software package “R.” R is a free statistical package that allows the analyst to perform statistical analysis and format and output graphs more effectively than the Statistica software package used in the past. Input and output files included in Appendix H can be imported into either R or Statistica to replicate the results presented in this SAR. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 4 June 24, 2020 1.2 Limitations Statement This SAR presents the findings and interpretations of INTERA based on, and limited to, the conditions existing at the time of this SAR and the scope of services agreed upon between INTERA and EFRI. The calculations presented herein were completed using industry standard practices and were performed on data received from others. INTERA relies in good faith on information provided for this SAR, including analytical data, measurements, and previous investigations performed at the Mill site, but does not make any warranty, expressed or implied, that the information is accurate and complete. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 5 June 24, 2020 2.0 CATEGORIES AND APPROACH FOR ANALYSIS Generally, OOC constituents and wells can be grouped into five categories: Constituents in wells with previously identified rising trends. Constituents in pumping wells. Constituents potentially impacted by decreasing trends in pH across the Mill site. Newly installed wells with interim GWCLs. Other constituents and wells. This SAR addresses two constituents in one well (sulfate and TDS in MW-31). These constituents fall into category five: other constituents and wells. It is important to note that sulfate and TDS also fall within the first and third categories: constituents in wells with previously identified rising trends and constituents potentially impacted by decreasing trends in pH across the Mill site. The pH is decreasing site-wide, likely due to oxidation of pyrite in the aquifer (HGC, 2012a). Sulfate and increased TDS are also products of pyrite oxidation. Increased sulfate and TDS concentrations may also be due to the location of MW-31 within the downgradient toe of the nitrate/chloride plume (Figure 2 and Figure 3). Additional factors that may have contributed to a potential change in behavior of groundwater conditions and reported constituent concentrations in MW-31 include the following: (1) the 2011 well redevelopment project, which took place in April and May of 2011 (HGC, 2011); (2) the change in analytical laboratory in 2012; (3) groundwater elevations that increased until 2013 (Figure 4) as a result of former wildlife pond seepage (HGC, 2014); (4) groundwater elevations that have decreased since 2013 (Figure 4) as a result of cessation of water delivery to the wildlife ponds in 2012 (HGC, 2014); and (5) the addition of several pumping wells under the nitrate/chloride and chloroform Corrective Action Plans (“CAP”) subsequent to the fourth quarter of 2012. A more detailed discussion of these variables is presented in Section 3.1 of the 2015 SAR (INTERA, 2015). 2.1 Approach for Analysis The first step in the analysis is to perform an assessment of the potential sources for the exceedances to determine whether they are due to background influences or Mill activities. If the exceedances are determined to be caused by background influences, then it is not necessary to perform any further evaluations on the extent and potential dispersion of the contamination or to perform an evaluation of potential remedial actions. Monitoring will continue; and, where Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 6 June 24, 2020 appropriate, a revised GWCL is proposed to reflect changes in background conditions at the Mill site. Assessments for potential sources of increasing concentrations of sulfate and TDS in MW-31 have been performed in SARs produced in 2012, 2013, 2015, and 2017 (INTERA, 2012a, 2013, 2015, 2017). Assessment of the site-wide pH trend has been performed in PH Report White Mesa Uranium Mill, Blanding, Utah (the “pH Report”) and Investigation of Pyrite in the Perched Zone, White Mesa Uranium Mill Site (the “Pyrite Report,” HGC, 2012a). The analysis performed in this SAR considers all available data to date to help determine if there have been any changes in potential tailings system seepage indicator parameters (e.g., chloride, sulfate, fluoride, and uranium) since the date of the New Wells Background Report and the approved SARs that may suggest a change in the behavior of the groundwater in the well. As discussed in the Background Reports (INTERA, 2007a, 2007b, 2008), indicator parameters of potential tailings system seepage include chloride, sulfate, fluoride, and uranium. Chloride is the best indicator of potential tailings system seepage; however, chloride is problematic as an indicator parameter for those groundwater monitoring wells at the Mill impacted by the chloride plume (EFRI, 2020). Sulfate and fluoride are useful indicator parameters under geochemical conditions allowing conservative (i.e., non-reactive) behavior. Uranium behavior may range from conservative to non-conservative depending on the geochemical conditions. Groundwater impacted by any potential seepage from the tailings system would be expected to exhibit increasing concentrations of chloride, sulfate, fluoride, and uranium, among other constituents. While uranium can be the most mobile of trace metals under certain conditions, it is typically retarded behind chloride, fluoride, and sulfate due to possible sorption and precipitation and would likely not show increasing concentrations in groundwater until sometime after chloride, fluoride, and sulfate concentrations had begun to increase (INTERA, 2007a). It is important to note, however, that while the absence of a rising trend in constituent concentrations would indicate that there has been no impact from the tailings system, a rising trend in concentrations could also be due to natural influences (see Section 12.0 of INTERA, 2007a). The evaluation of SAR parameters and indicator parameters in MW-31 was supported by a statistical analysis that followed the process outlined in the Flowsheet (INTERA, 2007a) attached as Appendix F. As discussed in Section 1.1, the Flowsheet was designed based on USEPA’s Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance (USEPA, 1989, 1992, 2009), and was approved by DWMRC prior to completion of the Background Reports (INTERA, 2007a, 2007b, 2008). Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 7 June 24, 2020 2.2 Approach for Setting Revised GWCLs If the preceding approach resulted in the conclusion that the previous analysis in the Background Reports or most recently approved SARs has not changed, or that the OOC status of sulfate or TDS in MW-31 is due to natural or other site-wide influences that are already being addressed by corrective action, then new GWCLs may be proposed for the constituents. In proposing revised GWCLs, INTERA has adopted the approach in the DWMRC-approved Flowsheet, including the last decision of the process that directs the analyst to consider a modified approach to determining a GWCL if an increasing trend is present. 2.3 University of Utah Study At the request of the DWMRC, T. Grant Hurst and D. Kip Solomon of the Department of Geology and Geophysics of the University of Utah performed a groundwater study (the “University of Utah Study”) at the Mill site in July 2007 (Hurst and Solomon, 2008). The purpose of this study was to characterize groundwater flow, chemical composition, noble gas composition, and age to evaluate whether the increasing and elevated trace metal concentrations in monitoring wells at the Mill, all of which were identified in the Background Reports, may indicate that potential seepage from the tailings system is occurring. To evaluate sources of solute concentrations at the Mill, low-flow groundwater sampling was used as a method for collecting groundwater quality samples from 15 monitoring wells. In addition, tailings solution and surface water samples were collected from cells 1, 3, and 4A, and two wildlife ponds. Passive diffusion samplers were also deployed and collected to characterize the dissolved gas composition of groundwater at different depths within the wells. Samples were collected and analyzed for the following constituents: tritium, nitrate, sulfate, deuterium and oxygen-18 of water, sulfur-34 and oxygen-18 of sulfate, trace metals (uranium, manganese, and selenium), and chlorofluorocarbons (“CFCs”). The 15 wells sampled included MW-31. Hurst and Solomon (2008, page iii) concluded generally that, [t]he data show that groundwater at the Mill is largely older than 50 years, based on apparent recharge dates from chlorofluorocarbons and tritium concentrations. Wells exhibiting groundwater that has recharged within the last 50 years appears to be a result of recharge from wildlife ponds near the site. Stable isotope fingerprints do not suggest contamination of groundwater by tailings cell leakage, evidence that is corroborated by trace metal concentrations similar to historically- observed observations. With respect to CFC age dating, MW-31 was found to exhibit CFC recharge dates of the 1960s and 1970s, indicating that the water in that well predated construction of the Mill in 1980. Tritium was not detected in MW-31, indicating that impacts from wide-scale atmospheric injection of Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 8 June 24, 2020 tritium during aboveground thermonuclear weapons testing in the 1950s and 1960s, expected to be found in surface waters such as solutions in the Mill’s tailings system, were not observed in that well. Hurst and Solomon (2008) also concluded that, [i]n general, the data collected in this study do not provide evidence that tailings cell leakage is leading to contamination of groundwater in the area around the White Mesa Mill. Evidence of old water in the majority of wells, and significantly different isotopic fingerprints between wells with the highest concentrations of trace metals and surface water sites, supports this conclusion. The only evidence linking surface waters to recharging groundwater is seen in MW-27 and MW-19. Measurable tritium and CFC concentrations indicate relatively young water, with low concentrations of selenium, manganese, and uranium. Furthermore, stable isotope fingerprints of ðD and ð18O suggest mixing between wildlife pond recharge and older groundwater in MW-19 and MW-27. D34S-SO4 and ð18O-SO4 fingerprints closely relate MW-27 to wildlife pond water, while the exceptionally low concentration of sulfate in MW-27, the only groundwater site to exhibit sulfate levels below 100 mg/L, suggest no leachate from the tailings cells has reached the well. It should be further noted that, subsequent to the University of Utah Study, EFRI submitted a Nitrate Groundwater Contamination Investigation Report, White Mesa Uranium Mill Site, Blanding, Utah, dated December 30, 2009 (INTERA, 2009) (“CIR”), relating to the nitrate/chloride plume at the Mill site. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 9 June 24, 2020 3.0 RESULTS OF ANALYSIS This section describes the potential geochemical influences on groundwater in MW-31 and results of the analysis, summaries of which are provided in Appendix B-1, Appendix C-1, and Appendix D- 1. Supporting analyses are presented in Appendix E and Appendix G. 3.1 Site-Wide Decreasing pH A general discussion of the site-wide pH trend is necessary because decreasing pH is one of the most important contributors to increasing concentrations of the SAR parameters. A decreasing trend in pH has been observed in almost every groundwater monitoring well across the Mill site, including upgradient and far downgradient monitoring wells (INTERA, 2012b). The Pyrite Report (HGC, 2012a) attributed the decline in pH across the Mill site to the site-wide existence and oxidation of pyrite in the perched aquifer monitored at the site. This report showed that pyrite was observed in cuttings of at least 14 monitoring wells, including MW-26 (HGC, 2012a), which is upgradient of MW-31 (Figure 5). Pyrite may oxidize according to the following reaction (Williamson and Rimstidt, 1994): FeS2(s) + 7/2O2(g) + H2O  Fe2+(aq) + 2SO42-(aq) + 2H+ (reaction 1) Reaction 1 will increase hydrogen ion concentrations, which results in decreasing pH. Increasing concentrations of sulfate and TDS may also be a direct result of pyrite oxidation. Sulfate is a product of reaction 1, so increasing sulfate concentrations may be due to increased site-wide pyrite oxidation. The acidity produced during reaction 1 may also lead to increased mineral dissolution overall (Brantley, 2008), which usually leads to increased TDS concentrations. The likely causes for site-wide oxidation of pyrite include the following: (1) infiltration of oxidized water from the wildlife ponds upgradient of the Mill site; (2) changing water levels and incorporation of oxygen in air-filled pore spaces into groundwater; (3) the introduction of oxygen during pumping related to treatment of the chloride and nitrate plumes; and (4) the introduction of oxygen during increased sampling of monitoring wells (INTERA, 2012b). Oxidation of pyrite and the resulting decrease in pH tends to cause subsequent pH-dependent reactions, some of which are described below. Pyrite may also oxidize in the presence of bacteria and nitrate according to the following reaction (Hayakawa et al., 2013): 5FeS2 + 15NO3- + 10H2O  15/2N2 + 10SO42- + 5Fe(OH)3 + 5H+ (reaction 2) Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 10 June 24, 2020 Reaction 2 could be occurring in the parts of the aquifer impacted by the nitrate plume (Figure 3), potentially causing further oxidation and dissolution of pyrite and subsequent decreasing pH and increasing sulfate and TDS concentrations. As discussed in HGC (2017), the stability of nitrate concentrations in MW-30 and MW-31, which are located at the downgradient toe of the nitrate plume, could be due to nitrate degradation through oxidation of pyrite. Pyrite oxidation by nitrate may occur by another pathway that consumes acid and produces sulfate (Spiteri et al., 2008), as discussed in HGC (2017): 5FeS2 + 14NO3- + 4H+  7N2 + 10SO42- + 5Fe2+ + 2H2O (reaction 3) The relative dominance of pyrite oxidation by dissolved oxygen (producing acid and sulfate by reaction 1) and/or by nitrate (producing acid and sulfate by reaction 2; or producing sulfate but consuming acid by reaction 3) may result in sulfate production with or without a decrease in pH. 3.2 Changes in Groundwater in MW-31 The behavior of groundwater has changed since the time of the Background Reports, but to a lesser extent since recent SAR evaluations. Section 3.1 of the 2015 SAR describes in detail the changes, events, and other factors that may be influencing the behavior of constituents in this well, including: • Sampling frequency (monthly monitoring commenced in 2010). • Well redevelopment in 2011. • Hydraulic influences (Figure 4). • Geochemical influences. • Analytical changes. 3.3 Indicator Parameter Analysis Concentrations of parameters monitored in well MW-31 vary from concentrations observed at the time of the Background Reports. The changes in concentrations are most likely attributable to a combination of the influences discussed in Section 3.1 of the 2015 SAR: the proximity to the chloride/nitrate plume and changing hydrologic and geochemical conditions due to pumping wells, increased sample frequency, removal of recharge from the wildlife ponds, well rehabilitation, and the oxidation of pyrite leading to decreasing pH and increasing concentrations. For these reasons, the typical suite of indicator parameters of potential tailings system seepage may be impacted by other processes. A summary of geochemical analysis of indicator parameters is included in Appendix C-1. Appendix C-2 presents a descriptive statistics comparison for indicator Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 11 June 24, 2020 parameters from the New Wells Background Report and the 2012, 2013, 2015, and 2017 SARs. Data used in the analysis and data removed prior to analysis are presented in Appendices C-3 and C-4, respectively. The distribution and identification of outliers and extreme outliers in indicator parameter concentration data sets are demonstrated in the box plots included in Appendix C-5. Data from additional monitoring wells were plotted alongside indicator parameters for MW-31 (Appendix C-6). The additional wells and the areas they represent are the following: (1) MW-1, MW-18, and MW-19 as upgradient wells; (2) MW-20 and MW-3A as downgradient wells; and (3) MW-22 as a downgradient and far cross-gradient well (grouped with the other downgradient wells). This comparison illustrates that fluoride, sulfate, and uranium concentrations in MW-31 are well within the range of site-wide background concentrations. Chloride concentrations are above the range for site-wide background, consistent with the location of MW-31 within the nitrate/chloride plume. As the mass balance evaluation demonstrates (Section 3.5), the concentrations of constituents that are increasing and/or exceeding GWCLs in MW-31 are not the result of potential tailings system seepage. A Piper diagram, which can be used to distinguish between different waters, is presented in Appendix C-7. The diagram illustrates that the geochemical signature of major ions in solution differs between MW-31 and Cell 1. Chloride concentrations in MW-31 exhibit a statistically significant increasing trend (see Appendix C-9 for a time series). Fluoride concentrations are decreasing significantly in MW-31. Sulfate and uranium concentrations in MW-31 are relatively low for the Mill site (Appendix B-8 and Appendix C-6), but show significant increasing trends at the time of this SAR. Time series plots with vertical lines to indicate events that may have contributed to observed changes in indicator parameters are included in Appendix C-10. Current sulfate concentrations in MW-31 are among the lowest at the Mill site. A box plot showing sulfate concentrations in all monitoring wells at the Mill site is included in Appendix B-8. Other monitoring wells show sulfate concentrations that are three to seven times higher than those in MW-31 (see Table 7 of the 2012 SAR). Sulfate is also significantly increasing in a number of wells at the Mill site, including upgradient and far downgradient wells. See, for example, the indicator parameter analyses for MW-18 included in the 2012 SAR, which show a significantly increasing trend in sulfate and suggest that there are natural influences at the site that can influence sulfate concentrations. Specifically, as noted by DWMRC in their approval letter of the MW-18 SAR, based on review of water level elevations included in the Mill site Quarterly Groundwater Reports, upgradient wells are not likely to be impacted by current Mill activities. The elevations at monitoring wells MW-l, MW-18 and MW-19 are higher than water elevations in the Burro Canyon Aquifer beneath all of the Mill tailings cells. Those monitoring wells are located north and northeast of the tailings cells, and local groundwater flow is to the south-southwest Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 12 June 24, 2020 (DWMRC, 2013). The widespread occurrence of pyrite in the Burro Canyon Formation and the Dakota Sandstone (which host the perched groundwater monitored at the Mill site) can contribute to decreasing pH and increasing sulfate in wells at the Mill site (HGC, 2012a; reaction 1). Increased concentrations of sulfate, as well as chloride and TDS, are expected due to site-wide pyrite oxidation and the location of MW-31 within the nitrate/chloride plume. Uranium concentration trends are highly variable site-wide. An evaluation of uranium concentrations over time was included for all groundwater monitoring wells at the Mill site in Appendix F of the 2017 SAR (INTERA, 2017). Uranium concentrations in MW-31 are relatively low for the site and exhibit a statistically significant upward trend first identified during the 2015 SAR (INTERA, 2015). Box plots showing uranium in all of the groundwater monitoring wells at the Site are plotted in Appendix C-6. These box plots illustrate that uranium concentrations in MW-31 are within the range of background concentrations. With the exception of chloride, and despite any increasing trends, indicator parameters in MW-31 remain amongst the lowest at the Mill site (Appendix C-6) and are not present in concentrations that would be expected if they were due to potential tailings system seepage (Section 3.5). 3.4 pH Analysis A pH analysis was also performed for MW-31 (Appendix D). The pH analysis included creating box plots to identify and omit extreme outliers, performing the Shapiro-Wilk test of normality (Shapiro and Wilk, 1965), and testing for trends using either the least squares regression or the Mann-Kendall trend method (see Appendices D-1 through D-5). The results of the pH analysis in MW-31 show a significant decreasing trend in pH. The data appear to show more variance beginning in 2010 (Appendix D-5), which corresponds to the increase in monthly sampling frequency implemented that year. 3.5 Mass Balance Analyses The 2017 SAR for MW-31 included a mass balance analysis where fluoride concentrations in MW-31 were predicted by assuming a hypothetical situation under which potential tailings system seepage has entered the groundwater and has become diluted during transport before reaching MW‐31. Predicted fluoride concentrations were based on the dilution factors calculated for other indicator parameters (uranium, chloride, and sulfate) using average Cell 1 concentrations and current MW-31 concentrations. Because the conditions in MW-31 have not changed substantially since 2017, the mass balance analysis in the 2017 SAR remains valid. This mass balance analysis has been updated with more recent concentration values in this SAR. The mass balance model is based on current concentrations of fluoride, uranium, chloride, and sulfate in MW-31 and mean concentrations of the same constituents in Cell 1 water. The mean Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 13 June 24, 2020 concentrations in Cell 1 were based on data collected between 2003 and 2019 (EFRI 2019). Samples of tailings system water have produced variable results between 2003 and 2019, so average concentrations were used to describe the tailings system water. The model calculates estimated fluoride contributions to MW‐31 groundwater from hypothetical tailings system seepage based on measured concentrations of chloride, sulfate, and uranium. The model assumes potential tailings system seepage has entered the groundwater and has become diluted during transport before reaching MW‐31 and that this occurred far enough in the past to potentially reach MW‐31 at the present time. Therefore, the most recent analyses of MW‐31 groundwater were selected to represent modern MW‐31 water. For this mass balance calculation, indicator parameters are assumed to be conservative tracers (INTERA, 2007a) and not subject to attenuation during transport. Therefore, if the tailings are a source of contamination at MW‐31, the concentration of fluoride in MW‐31 is expected to be proportional to the concentration of uranium, chloride, and sulfate in the tailings system water. Although this model assumes only hypothetical tailings seepage and dilution of natural groundwater at MW‐31, recent analyses show that more likely sources of increasing constituent concentrations in this well include the chloride/nitrate plume (discussed below) and oxidization of naturally occurring pyrite associated with decreasing pH. Model calculations are presented in Appendix E. The mass balance calculations are based on dilution factors (DF) computed as the ratio of a particular constituent’s current (Q2 2020) concentration in MW-31 to its average concentration in the Cell 1 tailings solution since 2003. The DFs calculated for all indicator parameters based on the ratio of Cell 1 and MW-31 constituent concentrations vary by four orders of magnitude. Based on the computed DFs for uranium, chloride, and sulfate, the predicted MW-31 fluoride concentrations are 0.087, 35, and 15 milligrams per liter (mg/L), respectively. The most recent observed concentration of fluoride in MW-31 is 0.632 mg/L. The dissimilarity between predicted and observed fluoride concentrations and the large range in calculated dilution factors for the four indicator parameters indicate that potential tailings system seepage is an unlikely contributor to the groundwater chemistry of MW-31. Instead, fluoride concentrations in MW-31 are similar to most natural waters (< 1 mg/L; Hem 1985) and are more consistent with natural processes. In addition, if the same mass balance methodology is applied to uranium, the predicted MW-31 uranium concentrations range from 112 micrograms per liter (μg/L) (based on the fluoride DF) to 6,179 μg/L (based on the chloride DF). All of the predicted concentrations of uranium substantially exceed the most recent observed uranium concentration of approximately 16 μg/L. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 14 June 24, 2020 Fluoride concentrations at MW-31 are stable to decreasing (Appendix C-9), which is inconsistent with potential tailings system seepage. Because concentrations of chloride are increasing and fluoride is stable to decreasing, the ratio of chloride to fluoride concentrations is increasing (Figure 6). If the chloride in MW-31 resulted from a potential tailings solution impact, the MW-31 chloride to fluoride ratio would be decreasing (rather than increasing) because the chloride to fluoride ratio in Cell 1 (approximately 11 based on average concentrations) is much lower than the ratio at MW-31 (595 as of Q2 2020, Figure 6). In other words, if chloride to fluoride ratios represent geochemical signatures, then it appears that MW-31 is not inheriting the signature of tailings solution. The increase in the chloride to fluoride ratio at MW-31 is, however, consistent with the position of MW-31 in the downgradient toe of the nitrate/chloride plume and the ongoing downgradient migration of the plume. As discussed in Nitrate Contamination Investigation Report White Mesa Uranium Mill Site, Blanding, Utah (INTERA, 2009), the nitrate/chloride plume originated primarily from a pre-Mill source. This source (the historical pond) was located approximately 500 feet upgradient (northeast) of Cell 1 (INTERA, 2009). Finally, the ratios of other indicator parameters in MW-31 also differ substantially from ratios of the same constituents in Cell 1 solutions. Like the ratio of chloride to fluoride described above (Figure 6), the ratios of chloride to sulfate and chloride to uranium are shown for MW-31 and average Cell 1 tailings solution in Figures 7 and 8, respectively. The average chloride to average sulfate ratio in Cell 1 is approximately 0.14 while the Q2 2020 ratio in MW-31 is approximately 0.33; the ratio of average chloride to average uranium in Cell 1 is approximately 61 while the Q2 2020 ratio in MW-31 is approximately 24,260. The ratios of both chloride to sulfate and chloride to uranium at MW-31 are increasing (Figures 7 and 8). The increasing chloride to sulfate ratio is inconsistent with a Cell 1 impact because the ratio of chloride to sulfate is lower in Cell 1 (0.14) than in MW-31 (0.33). Therefore, if Cell 1 were potentially contributing chloride and sulfate to MW-31, the trend in the chloride to sulfate ratio would be expected to decrease rather than increase. Likewise, the increasing ratio of chloride to uranium concentrations at MW-31 could not result from a potential Cell 1 impact because the ratio at MW-31 (24,260) is substantially larger than in Cell 1 (61). Overall, the mass balance analysis indicates that potential tailings system seepage is an unlikely contributor to the groundwater chemistry at MW-31. The nitrate/chloride plume and oxidation of pyrite are the most likely cause of the increase in chloride, sulfate, and TDS measured in MW-31, which is located in the downgradient toe of the plume where such increases would be expected (as indicated above). This conclusion is consistent with previous mass balance analyses that were based on nitrate concentrations within the nitrate/chloride plume as described below. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 15 June 24, 2020 The nitrate mass balance calculation presented in the December 2009 CIR (INTERA, 2009) suggested that groundwater mounding would occur underneath the tailings system if the nitrate/chloride plume was caused by hypothetical tailings system seepage. The results of this calculation predicted that a 5-foot groundwater mound would be expected if the nitrate/chloride plume was caused by tailings system seepage. This nitrate mass balance calculation was updated in the 2015 SAR (INTERA, 2015, Appendix F-2). Although a substantial groundwater mound was predicted, such a mound has not been identified beneath the tailings cells (Figure 5). 3.6 Summary of Results As the results of the analysis of SAR parameters in MW-31 demonstrate, increasing trends in MW-31 are not consistent with potential tailings system seepage. A summary of conclusions for each SAR parameter is included below. 3.6.1 Sulfate Sulfate is naturally occurring in groundwater and is released into solution during the oxidation of pyrite (reactions 1 through 3) and dissolution of common sulfate-bearing minerals such as gypsum and anhydrite, both of which have been detected in the perched zone at the Mill (HGC, 2012a). Sulfate concentrations in MW-31 are significantly increasing, although the concentrations remain amongst the lowest at the Mill (Appendix B-8). These increasing concentrations are most likely the result of pyrite oxidation. 3.6.2 Total Dissolved Solids Appendix B-3 presents molar concentrations of the major cations and anions in MW-31 over time. All of the major ions show increasing concentrations over time, and these ions make up the bulk of measured TDS. This increase in TDS is consistent with decreasing pH because mineral dissolution tends to increase with decreasing pH (Brantley, 2008). Appendix B-3 shows that the most abundant cation is calcium, and the most abundant anions are chloride and sulfate. The source of calcium is likely increased dissolution of calcite, the source of chloride is the chloride/nitrate plume, and the source of sulfate is likely the oxidation of pyrite. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 16 June 24, 2020 4.0 CALCULATION OF GROUNDWATER COMPLIANCE LIMITS The findings of analyses discussed above support the conclusions that (1) MW-31 is not being impacted by potential tailings system seepage, and (2) increasing concentrations of constituents in MW-31 are the result of background and/or site-wide influences, such as the nitrate/chloride plume and a site-wide decline in pH. Therefore, revision of GWCLs for SAR parameters in MW-31 is proposed. 4.1 Evaluation of Modified Approaches to Calculation of GWCLs for Trending Constituents According to the DWMRC-approved Flowsheet (Appendix F), if an increasing trend is present, a modified approach should be considered for determining GWCLs. Constituents included in this SAR are exhibiting significantly increasing trends that can be attributed to one or more of the following: (1) natural background conditions; (2) pyrite oxidation in the aquifer, which can decrease pH, increase mobility of metals, and increase sulfate and TDS concentrations; (3) the location of this well within the nitrate/chloride plume, which is actively being remediated according to the CAP (HGC, 2012b); and/or (4) effects of recent events on groundwater in MW-31; such as well redevelopment, increased sampling frequency, change in water levels, and analytical method/laboratory change, as described in Section 3.1 of the 2015 SAR (INTERA, 2015). Therefore, the following alternative approaches to calculating GWCLs have been considered for constituents in MW-31: 95% Upper Tolerance Limit (95-UTL). The 95-UTL is one of several options for representing the upper bounds of a given dataset (USEPA, 2009). The 95-UTL gives a 95% confidence that the UTL will contain at least 95% of the distribution of observations in background. UTLs were calculated in USEPA’s free software ProUCL. The ProUCL Version 5.0 Technical Guidance (USEPA, 2015) Chapter 3 describes how the UTL is calculated based on distribution of the data. 1.5 times background concentration as defined in Utah Administrative Code (“UAC”) R317-6-4.3. The UAC R317-6-4.3 recognizes that “contaminants” may be present as part of naturally occurring background conditions: When a contaminant is present in a detectable amount as a background concentration, the concentration of the pollutant may not exceed the greater of 1.5 Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 17 June 24, 2020 times the background concentration or 0.5 times the ground water quality standard or background plus two standard deviations… In this rule, background concentration is defined as the “concentration of a pollutant in ground water upgradient or lateral hydraulically equivalent point from a facility, practice or activity which has not been affected by that facility, practice or activity.” Background at the Mill has been determined on an intrawell basis, as defined in the Background Reports. Therefore, to be conservative, the mean concentration could be used as background for the purposes of this calculation. The mean concentration would assume all data to date (or a data subset as described below), after following the data quality steps of the Flowsheet. Multiplying the mean concentration by 1.5 produces a GWCL that is greater than a GWCL determined using mean + 2σ or the highest historical value. A greater GWCL decreases the likelihood of false positives (exceedances) associated with increasing trends related to natural background conditions or site-wide oxidation of pyrite. Using recent data to calculate GWCLs. This approach follows the DWMRC-approved Flowsheet (Appendix F) by taking into account increasing trends and processing the data consistently with previously determined GWCLs. In this approach, the complete data set, which exhibits an increasing trend over the history of the well record, is divided into subsets of data based on identification of a point of inflection where the results have shifted, or have been approved as background by the Director. This approach is appropriate in wells that have been thoroughly investigated and where the causes of increasing trends are not due to potential tailings system seepage or other Mill-related impacts that are not already being addressed. For the purposes of this modified approach and to be consistent with previous SARs, subsets of data from post October 2012 and post May 2014 were used to calculate GWCLs (Appendix G). These modified approaches have been considered for an achievable GWCL for parameters that are increasing in concentration for reasons other than potential tailings system impact. MW-31 has been thoroughly evaluated multiple times in recent years due to unachievable GWCLs. The most appropriate GWCL that is achievable considering increasing trends is the highest of the following: (1) mean + 2σ; (2) highest historical value; (3) fractional approach; (4) 1.5 times background; or (5) the 95-UTL. This approach of choosing the highest value combines elements from the Flowsheet and from previously approved GWCLs (DWMRC, 2016). Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 18 June 24, 2020 4.2 Proposed Revised GWCLs In accordance with the Flowsheet, the increasing trends identified for sulfate and TDS warrant a modified approach to the calculation of GWCLs. As discussed in detail in Section 3.0 and demonstrated in Appendices B-11 and C-10, the changes observed in groundwater at MW-31 may be attributable to many factors and events, several of which occurred between 2010 and 2014 and correspond to changes in the chloroform CAP in 2014. Increasing trends in MW-31 over time are not related to potential tailings system seepage. Sulfate and TDS trends present in MW-31 likely result from the nitrate/chloride plume, which is being addressed under a separate CAP, and oxidation of pyrite, which can contribute to increasing sulfate and TDS concentrations while decreasing the pH. Since the laboratory change in the fourth quarter of 2012, analytical methods and procedures have been performed according to the Quality Assurance Plan. All parameters included in this SAR have been monitored quarterly or monthly, resulting in a robust data set (over 40 N per data set since June 2014). Subsets of data collected since October 2012 and June 2014 were analyzed for trends (Appendix G). For all SAR parameters, concentrations are significantly increasing. For this reason, the approach to calculation of GWCLs has been modified by using only data collected after May 2014, and by choosing the greater of (1) mean + 2σ, (2) highest historical value, (3) fractional approach, or (4) 1.5 times background. Flowsheet analysis has been performed for these data subsets and the complete datasets and is summarized in Appendix B-1. GWCLs determined according to the Flowsheet using all data to date, data after October 2012, and data collected after May 2014 are presented in Appendix B-1. Based on this analysis, the proposed GWCLs for sulfate and TDS are presented in the column titled “Modified Approach GWCL” in Table 2. Table 2. Proposed GWCLs Parameter GWCLa Flowsheet Revised GWCLb Rationale Modified Approach GWCLc Modified Approach Rationale Sulfate (mg/L) 993 1150 HHV 1170.5 Background x 1.5 TDS (mg/L) 2132 2650 HHV 2664 Background x 1.5 Notes: HHV = highest historical value. a = 2019 GWDP No.UGW370004. b = GWCL calculated using complete historical data set. c = Modified Approach calculated in accordance with the Flowsheet using more recent data (6/2014 to 1/2020) and choosing the highest of either the HHV, mean + 2σ, fractional approach, 95-UTL, or 1.5 x background. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 19 June 24, 2020 5.0 CONCLUSIONS AND RECOMMENDATIONS Background at the Mill site was thoroughly studied as described in the Background Reports (INTERA, 2007a, 2007b, 2008) and in the University of Utah Study (Hurst and Solomon, 2008). Conditions in MW-31 have been studied more recently as described in the 2012, 2013, 2015, and 2017 SARs (INTERA, 2012a, 2013, 2015, 2017). The Background Reports and the University of Utah Study concluded that groundwater at the Mill site has not been impacted by Mill operations. Those studies also acknowledged that there are natural influences operating at the Mill site that have caused increasing trends and general variability of background groundwater quality at the Mill site. The conclusion of the 2012, 2013, 2015, and 2017 SARs is that groundwater in MW-31 is not impacted by potential tailings system seepage. This conclusion is consistent with the conclusions of the Background Reports and the University of Utah Study. MW-31 is located within the nitrate/chloride plume that was identified in 2009, and is currently being addressed under a separate corrective action (HGC, 2012b). Mass balance calculations have demonstrated that concentrations of SAR parameters, indicator parameters (with the exception of chloride), and pH in MW-31 are consistent with background groundwater concentrations across the Mill site, and not the result of potential tailings system seepage. Chloride is being addressed under a separate corrective action (HGC, 2012b), and is not attributed to potential tailings system seepage. The focus of this SAR was to identify any changes in the circumstances identified in previous studies. A change in concentrations of parameters in MW-31 can be observed after monthly monitoring started in 2010, after the well redevelopment effort in 2011, after analytical changes in 2012, after the groundwater elevation peak in 2013, and after changes to the chloroform CAP in 2014. Constituents included in this SAR exhibit significant increasing trends that can be attributed to one or more of the following: (1) natural background conditions; (2) pyrite oxidation in the aquifer, which can decrease pH, increase mobility of metals, and increase sulfate and TDS concentrations; (3) the location of this well within the nitrate/chloride plume, which is actively being remediated according to the CAP (HGC, 2012b); and/or (4) effects of recent events on groundwater in MW-31 such as well redevelopment, increased sampling frequency, changes in water levels, and analytical method/laboratory change, as described in Section 3.1 of the 2015 SAR (INTERA, 2015). A site-wide comparison of concentrations in MW-31 shows that even with significant increasing long-term trends, many of the constituents are present in concentrations less than or within the range of site-wide background concentrations. Thus, increasing sulfate and TDS concentrations in MW-31 over time are likely due to background influences, including the decreasing trend in pH across the Mill site and the location of this well within the existing nitrate/chloride plume, and not to potential tailings system seepage. Findings are summarized on Table 3. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 20 June 24, 2020 Table 3. MW-31 Summary of Findings Out-of-Compliance Constituent Summary Path Forward Sulfate Sulfate concentrations are likely due to a combination of the oxidation of pyrite, which releases sulfate, and the location of MW-31 within the nitrate/chloride plume. Sulfate concentrations in MW-31 remain among the lowest at the Mill site. Modified approach GWCL; continue remedial action on the nitrate/chloride plume. TDS TDS concentrations are impacted by the nitrate/chloride plume and increasing dissolved constituents from pyrite oxidation. TDS concentrations in MW-31 are among the lowest at the Mill site. Modified approach GWCL; continue remedial action on the nitrate/chloride plume. INTERA recommends adopting the revised GWCLs for MW-31 based on the modified approach to address constituents with increasing trends in accordance with the Flowsheet. Regular revisions to GWCLs for constituents in wells with significantly increasing trends due to background is consistent with the USEPA’s Unified Guidance (USEPA, 2009). Such revisions account for the trends and minimize unwarranted OOC status in such wells. Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 21 June 24, 2020 6.0 REFERENCES Brantley, S. L., 2008. Kinetics of Mineral Dissolution. In Kinetics of Water-Rock Interaction. Ed. S. L. 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Nitrate Reduction Coupled with Pyrite Oxidation in the Surface Sediments of a Sulfide-rich Ecosystem. Journal of Geophysical Research: Biogeosciences, 118, 639-649. Hem, J. D., 1985. Study and Interpretation of the Chemical Characteristics of Natural Water. United States Geological Survey Water-Supply Paper, 2254. Hurst, T.G., and Solomon, D.K., 2008. Summary of Work Completed, Data Results, Interpretations and Recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah. Prepared by Department of Geology and Geophysics, University of Utah. Hydro Geo Chem (HGC), 2007. Site Hydrogeology and Estimation of Groundwater Travel Times in the Perched Zone, White Mesa Uranium Mill Site near Blanding, Utah. ––––––, 2011. Redevelopment of Existing Perched Monitoring Wells White Mesa Uranium Mill Near Blanding, Utah ––––––, 2012a. Investigation of Pyrite in the Perched Zone, White Mesa Uranium Mill Site, Blanding, Utah. ––––––, 2012b. 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Nitrate Groundwater Contamination Investigation Report White Mesa Uranium Mill Site, Blanding, Utah. ––––––, 2012a. Source Assessment Report White Mesa Uranium Mill Blanding, Utah. ––––––, 2012b. PH Report White Mesa Uranium Mill, Blanding, Utah. ––––––, 2013. Source Assessment Report for Selenium in MW-31 White Mesa Uranium Mill, Blanding, Utah. ––––––, 2015. Source Assessment Report for MW-31 White Mesa Uranium Mill, Blanding, Utah. ______, 2016. Source Assessment Report for MW-18 and MW-24, White Mesa Uranium Mill, Blanding, Utah. ––––––, 2017. Source Assessment Report for MW-31 White Mesa Uranium Mill, Blanding, Utah. Shapiro, S.S., and Wilk, M.B., 1965. An Analysis of Variance Test for Normality (Complete Samples). Biometrika 52:591-611. Spiteri, C., C.P. Slomp, C.P.,K. Tuncay, K., and C. Meile, C.,. 2008. Modeling Biogeochemical Processes in Subterranean Estuaries: Effect of Flow Dynamics and Redox Conditions on Submarine Groundwater Discharge of Nutrients. Water Resources Research, 2008, 44, W02430. United States Environmental Protection Agency (USEPA), 1989. Statistical Analysis of Ground-water Monitoring Data at RCRA Facilities: Interim Final Guidance, 530-SW-89-026, Office of Solid Waste, Permits and State Programs Division, U.S. Environmental Protection Agency, 401 M Street, S.W. Washington, D.C. 20460. _____, 1992. Statistical Analysis of Ground-Water Monitoring Data at RCRA Facilities: Addendum to Interim Final Guidance, Office of Solid Waste, Permits and State Programs Source Assessment Report for MW-31 White Mesa Uranium Mill Blanding, Utah 23 June 24, 2020 Division, U.S. Environmental Protection Agency, 401 M Street, S.W. Washington, D.C. 20460. _____, 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, EPA 530/R-09-007. _____, 2015. Computing Upper Limits to Estimate Background Threshold Values Based Upon Uncensored Data Sets without Nondetect Observations, in The ProUCL Version 5.0 Technical Guidance, EPA/600/R-07/041. Williamson, M. A., Rimstidt, J. D., 1994. The Kinetics and Electrochemical Rate-Determining Step of Aqueous Pyrite Oxidation. Geochimica et Cosmochimica Acta, 58, 5443-5454. FIGURES Cell No. 1 Cell No. 2 Cell No. 3 Cell No. 4A Wild lifePond Wild lifePond Mill Site Cell No. 4B MW-40 MW-38 MW-39 MW-37 MW-36 MW-34 MW-33 MW-32 MW-31 MW-29 MW-28 MW-27 MW-26 MW-25 MW-24 MW-23 MW-22 MW-21 MW-20 MW-19 MW-18 MW-17MW-15 MW-12 MW-11MW-05 MW-04 MW-02 MW-01 MW-03A MW-14 MW-30 MW-35 S:\ABQ\IUC-001-01-001 De nison Mine s\GIS\mapd oc s\2020_SAR s\MW-31\01_SAR MW31_Loc ationMap.mxd Date : 6/2/2020 Figu re 1Loc ation of White Me sa Mill Siteand Grou nd wate r Monitoring We llsWhite Me sa Uraniu m Mill 900 0 900 Fe e t Sou rc e (s): Ae rial – ESR I Arc GIS online ;We lls – HGC, Inc ., May 2008 re port. Grou nd wate r Monitoring We ll IDAHOIDAHO NEV A D A NEV A D A AR IZ ONAAR IZ ONA WYOMINGWYOMING UTAHUTAH CO L O R A D O CO L O R A D O NEWNEWMEXICOMEXICO White Me saUraniu m Mill Cell No. 1 Cell No. 2 Cell No. 3 Cell No. 4A Wild lifePond Wild lifePond Mill Site Cell No. 4B 100 100 100 300 500 MW-01 MW-02 MW-03A MW-04 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-21 MW-22 MW-23 MW-24 MW-25 MW-26 MW-27 MW-28 MW-29 MW-30 MW-32 MW-33 MW-34 MW-35 MW-36 MW-37 MW-38 MW-39 MW-40 MW-31 S :\ABQ\IUC-001-01-001 Denison Mines\GIS \m apd ocs\2020_S ARs\MW-31\02_S ARMW31_Ch lorid e.m x d Date: 6/3/2020 Fig ure 2Ex ceed ances and Prox im ity ofMW-31 to Ch lorid e Plum eWh ite Mesa Uranium Mill 1,000 0 1,000500 Feet S ource(s): Aerial – ES RI ArcGIS online;Wells – HGC, Inc., May 2008 report;Nitrate and ch lorid e d ata collected Q1, 2020. Leg end Ground water Monitoring Well Monitoring Well Ex ceed s: Ch lorid e,Nitrate, S ulfate, and TDS Ch lorid e Contam ination Area Above100 m g /L 100 m g /L Ch lorid e Contour Cell No. 1 Cell No. 2 Cell No. 3 Cell No. 4A Wild lifePond Wild lifePond Mill Site Cell No. 4B 10 10 10 5 20 30 5 30 5 MW-01 MW-02 MW-03A MW-04 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-21 MW-22 MW-23 MW-24 MW-25 MW-26 MW-27 MW-28 MW-29 MW-30 MW-32 MW-33 MW-34 MW-35 MW-36 MW-37 MW-38 MW-39 MW-40 MW-31 S :\ABQ\IUC-001-01-001 Denison Mines\GIS \m apd ocs\2020_S ARs\MW-31\03_S ARMW31_Nitrate.m x d Date: 6/3/2020 Fig ure 3Ex ceed ances and Prox im ity ofMW-31 to Nitrate Plum eWh ite Mesa Uranium Mill 1,000 0 1,000500 Feet S ource(s): Aerial – ES RI ArcGIS online;Wells – HGC, Inc., May 2008 report;Nitrate and ch lorid e d ata collected Q1, 2020. Leg end Ground water Monitoring Well Monitoring Well Ex ceed s: Ch lorid e,Nitrate, S ulfate, and TDS Nitrate Contam ination Area Above10 m g /L (d ash ed wh ere inferred ) 10 m g /L Nitrate Contour Figure 4 Groundwater Elevations over Time at MW-31 White Mesa Uranium Mill Service Layer Credits: Source: Esri,DigitalGlobe, GeoEye, Earthstar Geographics,CNES/Airbus DS, USDA, USGS, AeroGRID,IGN, and the GIS User Community Figure 5 Groundwater Elevation Contours MW-31 SAR MW-01 MW-02 MW-03A MW-04 MW-05 MW-11MW-12 MW-14MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-26 MW-27 MW-28 MW-29 MW-30 MW-31 MW-32 MW-34 MW-35 MW-36 MW-37 MW-38 MW-39 MW-40 5600 5500 5480 5460 5 5 6 0 5 5 4 0 5580 5 5 2 0 FILE: S:\ABQ\IUC-001-01-001 Denison Mines\GIS\mapdocs\2020_SARs\MW-31\04_SARMW31_GWelev.mxd Date: 6/2/2020 Source(s): Imagery from ArcGIS Online 2,000 0 2,000 Feet Legend Well Type MW PIEZ TW4 TWN Groundwater ElevationContour, ft amsl Figure 6 Ratio of Chloride to Fluoride Concentrations in MW-31 White Mesa Uranium Mill 0 100 200 300 400 500 600 700 800 900 1000 1/1/2005 1/1/2007 1/1/2009 1/1/2011 1/1/2013 1/1/2015 1/1/2017 1/1/20191/1/2021 ra t i o date MW‐31 Cl/F cell 1 average Cl/F Linear (MW‐31 Cl/F) Figure 7 Ratio of Chloride to Sulfate Concentrations in MW-31 White Mesa Uranium Mill 0.00 0.10 0.20 0.30 0.40 0.50 1/1/2005 1/1/2007 1/1/2009 1/1/2011 1/1/2013 1/1/2015 1/1/2017 1/1/20191/1/2021 ra t i o date MW‐31 Cl/SO4 average cell1 Cl/SO4 Linear (MW‐31 Cl/SO4) Figure 8 Ratio of Chloride to Uranium Concentrations in MW-31 White Mesa Uranium Mill 0 5000 10000 15000 20000 25000 30000 35000 1/1/2005 1/1/2007 1/1/2009 1/1/2011 1/1/2013 1/1/2015 1/1/2017 1/1/20191/1/2021 ra t i o date MW‐31 Cl/U average cell 1 Cl/U Linear (MW‐31 Cl/U) APPENDIX A GWCL Exceedances for Fourth Quarter 2019 under the March 19, 2019 GWDP APPENDIX A GWCL Exceedances for Fourth Quarter 2019 under the March 19, 2019 GWDP Monitoring Well (Water Class)Constituent Exceeding GWCL GWCL in March 19, 2019 GWDP Q2 2019 Sample Date Q2 2019 Result May 2019 Monthly Sample Date May 2019 Monthly Result June 2019 Monthly Sample Date June 2019 Monthly Result Q3 2019 Sample Date Q3 2019 Result August 2019 Monthly Sample Date August 2019 Monthly Result Sept. 2019 Monthly Sample Date Sept. 2019 Monthly Result Q4 2019 Sample Date Q4 2019 Result November 2019 Monthly Sample Date November 2019 Monthly Result December 2019 Monthly Sample Date December 2019 Monthly Result Chloride (mg/L)39.16 34 NA NA 48.4 NA NA 30.8 39.1 35.4 Sulfate (mg/L)1309 1160 NA NA 1410 NA NA 1290 1140 1100 Manganese (ug/L)164.67 181 210 210 199 202 174 185 206 167Fluoride (mg/L)0.22 <0.100 NA NA 0.248 NA NA <0.100 0.127 0.120 Sulfate (mg/L)2330 1780 NA NA 2450 NA NA 2180 2110 2120 MW-25 (Class III) Cadmium (ug/L)1.5 4/10/2019 1.30 5/8/2019 1.41 6/4/2019 1.47 7/15/2019 1.23 8/6/2019 1.37 9/23/2019 1.38 10/9/2019 1.45 11/13/2019 1.36 12/4/2019 1.45Nitrate + Nitrite (as N) (mg/L)0.62 3.00 0.986 3.16 2.06 3.10 1.59 2.35 2.90 2.32Chloroform (ug/L)70 4140 1140 778 3110 1090 1540 1710 1280 1110Chloride (mg/L)58.31 82.0 73.0 72.6 75.2 83.5 62.1 73.8 62.3 57.7 Methylene Chloride (ug/L)5 4.16 1.69 <1.00 10.7 1.12 3.35 2.95 1.73 2.64 Nitrogen, Ammonia as N 0.92 0.104 0.479 0.0919 0.357 0.164 0.496 0.273 0.178 0.207 Nitrate + Nitrite (as N) (mg/L)2.5 18.5 17.9 15.8 19.3 15.8 17.9 18.2 17.2 17.8 Chloride (mg/L)128 138 175 165 181 190 176 170 180 185Selenium (ug/L)47.2 53.6 47.1 49.9 48.4 50.9 49.1 56.8 47.8 56.4Uranium (ug/L)8.32 8.62 8.15 8.88 9.03 9.39 8.12 8.69 9.29 8.99Field pH (S.U.)6.47 - 8.5 7.06 7.00 7.12 6.86 7.42 7.00 7.16 7.21 7.22Nitrate + Nitrite (as N) (mg/L)5 19.7 18.9 19.7 19.8 17.0 19.5 19.8 18.8 18.3Sulfate (mg/L)993 917 NA NA 1150 NA NA 1010 990 1020TDS (mg/L)2132 2080 NA NA 2580 NA NA 2280 2650 2030 Chloride (mg/L)143 294 346 325 374 372 365 318 338 343 Sulfate (mg/L)3146.21 2470 NA NA 3170 NA NA 2850 2590 2710 Field pH (S.U.)6.49 - 8.5 7.05 6.73 7.01 6.60 7.33 6.92 7.05 7.09 7.24 MW-12 (Class III)Uranium (ug/L)23.5 4/25/2019 23.2 NS NA NS NA 7/11/2019 23.1 NS NA NS NA 10/23/2019 21.6 NS NA NS NA Beryllium (ug/L)2 2.83 NA NA 2.94 NA NA 3.25 NA NA Cadmium (ug/L)6.43 8.24 NA NA 8.37 NA NA 9.31 NA NA Fluoride (mg/L)0.47 0.839 NA NA 0.996 NA NA 0.667 NA NANickel (mg/L)50 63.9 NA NA 70.6 NA NA 75.4 NA NAManganese (ug/L)7507 7020 NA NA NA NA NA 7700 NA NA Thallium (ug/L)2.01 2.73 NA NA 2.61 NA NA 2.88 NA NA Field pH (S.U.)5.03 - 8.5 4.53 NA NA 5.03 NA NA 5.19 NA NA MW-27 (Class III) Nitrate + Nitrite (as N) (mg/L) 5.6 4/23/2019 6.33 NS NA NS NA 7/12/2019 8/15/2019 6.50 NS NA NS NA 10/22/2019 6.27 NS NA NS NA Chloride (mg/L)105 165 NA NA 133 NA NA 149 NA NA Selenium (ug/L)11.1 12.4 NA NA 10.6 NA NA 16.5 NA NAGross Alpha (pCi/L)2.42 1.94 NA NA 1.20 NA NA <1.00 NA NAUranium (ug/L)4.9 9.60 NA NA 7.83 NA NA 12.4 NA NA MW-32 (Class III)Chloride (mg/L)35.39 4/9/2019 34.5 NS NA NS NA 8/15/2019 35.7 NS NA NS NA 10/8/2019 35.3 NS NA NS NA MW-35 (Class ll) Nitrogen, Ammonia as N 0.14 4/18/2019 0.0634 NS NA NS NA 7/11/2019 0.0935 NS NA NS NA 10/8/2019 <0.0500 NS NA NS NA Notes: NS= Not Required and Not SampledNA= Not Applicable Exceedances are shown in yellow 10/22/2019 NS NS Required Quarterly Sampling Wells Required Semi-Annual Sampling Wells 11/6/2019 NS NS 10/9/2019 11/12/2019 12/3/2019 10/8/2019 11/13/2019 12/3/2019 10/9/2019 11/13/2019 12/4/2019 10/8/2019 11/13/2019 12/4/2019 Q4 2019 Results 10/15/2019 11/12/2019 12/3/2019 10/9/2019 11/13/2019 12/3/2019 MW-24 (Class III) Q3 2019 Results 5/2/2019 NS NS 4/24/2019 NS NS 4/9/2019 5/7/2019 Q2 2019 Results 4/24/2019 5/7/2019 NS 7/18/2019 NS NS 9/24/2019 7/16/2019 8/6/2019 9/24/2019 7/15/2019 8/5/2019 9/23/2019 8/6/2019 9/23/2019 7/16/2019 8/6/2019 MW-11 (Class II)7/16/2019 8/5/2019 9/24/2019 MW-14 (Class III) 4/24/2019 5/7/2019 6/3/2019 4/23/2019 NS NS 7/15/2019 NS NS MW-28 (Class III) MW-26 (Class III) MW-30 (Class II) 7/12/2019 8/16/2019 NS 7/16/2019MW-36 (Class III) 4/18/2019 5/21/2019 6/3/2019 MW-31 (Class III) 6/4/2019 5/7/2019 6/3/2019 6/3/2019 4/10/2019 Source Assessment Report for MW-31 White Mesa Uranium Mill Page 1 of 1 APPENDIX B Geochemical Analysis for SAR Parameters in MW-31 Appendix B-1: Summary of Geochemical Analysis for Out of Compliance Constituents in MW-31 Wp Sp MW-31 Sulfate Complete 126 0 668.9 160.9 0.9468 0.0001 No 6354 0 Increasing Yes 991 1003.3 1080 1150 993 1150 HHV MW-31 Sulfate Post Sep 2012 85 0 741.2 148.2 0.9660 0.0243 No 2679 0 Increasing Yes 1038 1111.8 1120 1150 993 1150 HHVMW-31 Sulfate Post May 2014 65 0 780.3 145.8 0.9674 0.0843 Lognormal 1723 0 Increasing Yes 1071.9 1170.5 1099 1150 993 1071.9 Mean + 2σ 1170.5 Mean x 1.5 MW-31 Total Dissolved Solids Complete 127 0 1555.3 314 0.9420 0.0000 No 6481 0 Increasing Yes 2183 2333 2280 2650 2132 2650 HHV MW-31 Total Dissolved Solids Post Sep 2012 85 0 1689.3 300 0.9567 0.0062 No 2870 0 Increasing Yes 2289 2534 2380 2650 2132 2650 HHV MW-31 Total Dissolved Solids Post May 2014 65 0 1775.7 288 0.9460 0.0068 No 1684 0 Increasing Yes 2352 2664 2580 2650 2132 2650 HHV 2664 Mean x 1.5 Notes: σ = sigma N = number of valid data points S = Mann-Kendall statistic %ND = percent of non-detected values p = probability FA= Fraction of GWQS as defined in UAC R317-6 µg/L = micrograms per liter W = Shapiro Wilk test value NA= Not Applicable mg/L = milligrams per liter r2 = The measure of how well the trendline fits the data where r2=1 represents a perfect fit. Distribution = Distribution as determined by the Shapiro-Wilk distribution test for constituents with % Detect > 50% and N>8 Mean = The arithmatic mean as determined for normally or log-normally distributed constituents with % Detect > 50% Standard Deviation = The standard deviation as determined for normally or log-normally distributed constituents with % Detect > 85% Highest Historical Value = The highest observed value for constituents with % Detect < 50% Flowsheet GWCL does not take into account increasing trends § = GWCL is based on the GWDP or most recent SARs, where applicable. Constituent N % Non- Detected Values MeanWellData Set Modified Approach GWCL Rationale Significant Trend Previously Identified Increasing Trend? Modified Approach GWCL* Standard Deviation Highest Historical Value (HHV) Mean + 2σ Current GWCL § Mann Kendall Trend Analysis Shapiro-Wilk Test for Normality Normally or Lognormally distributed? Upper Tolerance Limit (UTL) Mean x 1.5 Flowsheet GWCL Rationale Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 1 of 17 Appendix B-2: Comparison of Calculated and Measured TDS in MW-31 Date Sampled Alkalinity (mg/L) Calcium (mg/L) Chloride (mg/L) Potassium (mg/L) Magnesium (mg/L) Sodium (mg/L) Sulfate (mg/L) Measured TDS (mg/L) Calculated TDS (mg/L)Ratio 8/24/2009 215 169 122 6.0 79.4 92.7 460 1230 1144 93% 10/14/2009 214 170 138 6.1 78.5 93.6 497 1160 1197 103% 2/9/2010 224 170 128 6.2 80.2 92.2 507 1150 1208 105% 4/20/2010 220 162 128 5.8 79.4 91.3 522 1220 1209 99% 9/13/2010 226 164 139 5.7 78.1 91 527 1330 1231 93% 11/9/2010 216 166 138 5.9 77.8 85.4 539 1320 1228 93% 2/1/2011 211 168 145 5.8 79.6 91.6 538 1220 1239 102% 4/1/2011 213 172 143 6.1 80.1 95 503 1370 1212 88% 8/2/2011 199 172 148 5.7 81.2 95.3 537 1300 1238 95% 10/3/2011 202 177 145 5.9 83.3 85.5 539 1320 1238 94% 2/13/2012 203 190 150 6.0 87.9 97.2 538 1240 1272 103% 5/2/2012 208 187 151 7.0 88 87.9 532 1410 1261 89% 7/9/2012 202 189 161 6.0 90.1 98 529 1400 1275 91% 11/6/2012 209.84 182 189 5.7 86.5 92.6 557 1230 1323 108% 2/19/2013 217.16 200 174 6.4 91.6 98.6 644 1390 1432 103% 5/13/2013 212.28 191 169 5.5 90.9 99.2 630 1540 1398 91% 7/9/2013 212.28 199 182 6.1 94.7 105 659 1510 1458 97% 11/18/2013 213.5 194 174 6.0 89.4 94.2 609 1320 1380 105% 3/10/2014 202.52 195 230 5.8 93.9 94.1 681 1490 1502 101% 6/2/2014 209.84 202 173 6.2 101 93.1 555 1520 1340 88% 9/3/2014 223.26 189 210 6.0 95.8 96.5 560 1460 1381 95% 11/4/2014 201.3 201 204 6.2 95.8 93.1 639 1520 1440 95% 2/2/2015 214.72 194 211 6.4 95.4 95 623 1520 1439 95% 4/7/2015 204.96 207 211 6.1 97.6 103 642 1680 1472 88% 8/10/2015 236.68 221 264 6.5 102 99.5 640 1530 1570 103% 11/09/2015 206 224 215 5.8 99.4 96.3 646 1460 1493 102% 2/15/2016 209 238 246 6.0 106 98.5 631 1490 1534 103% 5/3/2016 201 248 243 6.6 115 108 699 1550 1621 105% 8/16/2016 190 246 272 6.8 109 108 766 1710 1698 99% 11/1/2016 190 244 267 7.1 108 104 752 1690 1672 99% 2/7/2017 193 245 266 7.2 117 113 751 1680 1692 101% 5/1/2017 185 254 263 6.7 119 105 741 1820 1674 92% 8/14/2017 211 257 310 6.3 115 102 916 1780 1917 108% 11/1/2017 209 278 292 6.6 135 109 847 1770 1876 106% 2/20/2018 193.98 283 292 6.92 136 108 835 1930 1855 96% 4/17/2018 207.4 299 308 7.33 138 108 857 1980 1925 97% 9/10/2018 206.18 346 333 7.49 159 126 893 2100 2071 99% 10/24/2018 209.84 341 286 7.6 156 124 950 2000 2074 104% 1/15/2019 231.8 321 283 7.42 151 118 851 2030 1963 97% 4/10/2019 214.72 327 294 7.01 146 107 917 2080 2013 97% 7/15/2019 231.8 400 374 7.76 188 130 1150 2580 2482 96% 10/9/2019 225.7 346 318 6.63 167 124 1010 2280 2197 96% 1/14/2020 234.24 367 381 8.31 170 123 1120 2220 2404 108% Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 2 of 17 Appendix B-3: Charge Balance Calculations for Major Cations and Anions in MW-31 Well Date Calcium (meq/L) Sodium (meq/L) Magnesium (meq/L) Potassium (meq/L) Total Cation Charge (meq/L) HCO3 (meq/L) Chloride (meq/L) SO4 (meq/L) Total Anion Charge (meq/L) Charge Balance Error MW-31 6/22/2005 7.78 3.93 6.47 0.14 18.32 -2.77 -3.92 -10.49 17.18 3.20% MW-31 3/19/2008 8.03 3.96 6.43 0.16 18.58 -3.47 -3.50 -10.85 17.82 2.10% MW-31 6/3/2008 8.13 4.08 6.65 0.15 19.01 -3.23 -3.61 -10.70 17.54 4.02% MW-31 8/4/2008 8.98 4.11 7.26 0.16 20.51 -3.44 -3.50 -10.39 17.33 8.40% MW-31 11/11/2008 8.98 4.22 6.98 0.16 20.34 -3.36 -3.36 -11.26 17.98 6.17% MW-31 2/3/2009 8.43 3.60 6.59 0.14 18.76 -3.36 -3.24 -10.16 16.76 5.63% MW-31 5/13/2009 7.29 3.65 5.98 0.13 17.05 -3.43 -3.50 -10.26 17.19 -0.40% MW-31 8/24/2009 8.43 4.03 6.53 0.15 19.15 -3.52 -3.44 -9.58 16.54 7.31% MW-31 10/14/2009 8.48 4.07 6.46 0.16 19.17 -3.51 -3.89 -10.35 17.75 3.85% MW-31 2/9/2010 8.48 4.01 6.60 0.16 19.25 -3.67 -3.61 -10.55 17.84 3.81% MW-31 4/20/2010 8.08 3.97 6.53 0.15 18.74 -3.61 -3.61 -10.87 18.08 1.77% MW-31 9/13/2010 8.18 3.96 6.43 0.15 18.71 -3.70 -3.92 -10.97 18.60 0.32% MW-31 11/9/2010 8.28 3.71 6.40 0.15 18.55 -3.54 -3.89 -11.22 18.65 -0.28% MW-31 2/1/2011 8.38 3.98 6.55 0.15 19.06 -3.46 -4.09 -11.20 18.75 0.83% MW-31 4/1/2011 8.58 4.13 6.59 0.16 19.46 -3.49 -4.03 -10.47 18.00 3.91% MW-31 8/2/2011 8.58 4.15 6.68 0.15 19.55 -3.26 -4.17 -11.18 18.62 2.46% MW-31 10/3/2011 8.83 3.72 6.85 0.15 19.56 -3.31 -4.09 -11.22 18.62 2.45% MW-31 2/13/2012 9.48 4.23 7.23 0.15 21.09 -3.33 -4.23 -11.20 18.76 5.86% MW-31 5/2/2012 9.33 3.82 7.24 0.18 20.57 -3.41 -4.26 -11.08 18.74 4.65% MW-31 7/9/2012 9.43 4.26 7.41 0.15 21.26 -3.31 -4.54 -11.01 18.86 5.97% MW-31 11/6/2012 9.08 4.03 7.12 0.14 20.37 -2.82 -5.33 -11.60 19.75 1.56% MW-31 2/19/2013 9.98 4.29 7.54 0.16 21.97 -2.92 -4.91 -13.41 21.23 1.70% MW-31 5/13/2013 9.53 4.31 7.48 0.14 21.47 -2.85 -4.77 -13.12 20.73 1.73% MW-31 7/9/2013 9.93 4.57 7.79 0.15 22.44 -2.85 -5.13 -13.72 21.70 1.67% MW-31 11/18/2013 9.68 4.10 7.35 0.15 21.29 -2.87 -4.91 -12.68 20.45 1.99% MW-31 3/10/2014 9.73 4.09 7.73 0.15 21.70 -2.72 -6.49 -14.18 23.39 -3.74% MW-31 6/2/2014 10.08 4.05 8.31 0.16 22.60 -2.82 -4.88 -11.55 19.25 7.99% MW-31 9/3/2014 9.43 4.20 7.88 0.15 21.66 -3.00 -5.92 -11.66 20.58 2.56% MW-31 11/4/2014 10.03 4.05 7.88 0.16 22.12 -2.70 -5.75 -13.30 21.76 0.82% MW-31 2/2/2015 9.68 4.13 7.85 0.16 21.82 -2.88 -5.95 -12.97 21.81 0.04% MW-31 4/7/2015 10.33 4.48 8.03 0.16 22.99 -2.75 -5.95 -13.37 22.07 2.05% MW-31 8/10/2015 11.03 4.33 8.39 0.17 23.91 -3.18 -7.45 -13.32 23.95 -0.07% MW-31 11/09/2015 11.18 4.19 8.18 0.15 23.69 -2.77 -6.06 -13.45 22.28 3.07% MW-31 2/15/2016 11.88 4.28 8.72 0.15 25.04 -2.80 -6.94 -13.14 22.88 4.50% MW-31 5/3/2016 12.38 4.70 9.46 0.17 26.70 -2.70 -6.85 -14.55 24.11 5.10% MW-31 8/16/2016 12.28 4.70 8.97 0.17 26.11 -2.56 -7.67 -15.95 26.18 -0.12% MW-31 11/1/2016 12.18 4.52 8.89 0.18 25.77 -2.56 -7.53 -15.66 25.74 0.05% MW-31 2/7/2017 12.23 4.92 9.63 0.18 26.95 -2.59 -7.50 -15.63 25.73 2.32% MW-31 5/1/2017 12.67 4.57 9.79 0.17 27.20 -2.49 -7.42 -15.43 25.34 3.55% MW-31 8/14/2017 12.82 4.44 9.46 0.16 26.88 -3.46 -8.74 -19.07 31.27 -7.55% MW-31 11/1/2017 13.87 4.74 11.11 0.17 29.89 -3.42 -8.24 -17.63 29.29 1.01% MW-31 2/20/2018 14.12 4.70 11.19 0.18 30.19 -3.18 -8.24 -17.38 28.80 2.35% MW-31 4/17/2018 14.92 4.70 11.35 0.19 31.16 -3.40 -8.69 -17.84 29.93 2.01% MW-31 9/10/2018 17.27 5.48 13.08 0.19 36.02 -3.38 -9.39 -18.59 31.36 6.91% MW-31 10/24/2018 17.02 5.39 12.83 0.19 35.44 -3.44 -8.07 -19.78 31.29 6.22% MW-31 1/15/2019 16.02 5.13 12.42 0.19 33.76 -3.80 -7.98 -17.72 29.50 6.74% MW-31 4/10/2019 16.32 4.65 12.01 0.18 33.16 -3.52 -8.29 -19.09 30.90 3.52% MW-31 7/15/2019 19.96 5.65 15.47 0.20 41.28 -3.80 -10.55 -23.94 38.29 3.75% MW-31 10/9/2019 17.27 5.39 13.74 0.17 36.57 -3.70 -8.97 -21.03 33.70 4.08% MW-31 1/14/2020 18.31 5.35 13.99 0.21 37.86 -3.84 -10.75 -23.32 37.91 -0.06% Notes: meq/L= milliequivalent per liter HCO3 = Bicarbonate SO4 = Sulfate Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 3 of 17 Appendix B-4: Descriptive Statistics for Out of Compliance Constituents in MW-31 Data Set 2020 SAR 2017 SAR 2015 SAR 2012 SAR 2008 Background Report 2020 SAR 2017 SAR 2015 SAR 2012 SAR 2008 Background Report Analyte Sulfate Sulfate Sulfate Sulfate Sulfate Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Units mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L % Non-Detects 0 0 0 0 0 0 0 0 0 0 N 126 100 77 39 10 127 100 78 51 10 Distribution Not normal or lognormal Not normal or lognormal Not normal or lognormal Not normal or lognormal Not normal or lognormal Not normal or lognormal Not normal or lognormal normal or lognormal normal or lognormal Not normal or lognormal Mean 669 1421 567 517 504 1555 1421 1364 1258 1265 Min. Conc.436 1150 436 436 436 1150 1150 1150 1110 1150 Max. Conc.1150 1820 691 552 532 2650 1820 1700 1460 1320 Std. Dev.161 161 65.1 24.2 27.8 314 161 125 76.5 50 Range 714 670 255 116 96.0 1500 670 550 350 170 Geometric Mean 652 1412 564 517 504 1527 1412 1358 1255 1264 Skewness 1.04 0.35 0.40 -1.3 -1.9 1.18 0.35 0.46 0.34 -1.60 Q25 537 1288 521 503 497 1310 1288 1270 1210 1240 Median 640 1410 541 522 513 1480 1410 1330 1240 1280 Q75 750 1530 630 538 522 1705 1530 1460 1300 1290 Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 4 of 17 Appendix B-5: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units Qualifier MW-31 6/22/2005 Sulfate 504 mg/l MW-31 9/22/2005 Sulfate 436 mg/l D MW-31 12/14/2005 Sulfate 509 mg/l D MW-31 3/22/2006 Sulfate 485 mg/l D MW-31 6/21/2006 Sulfate 522 mg/l D MW-31 9/13/2006 Sulfate 516 mg/l D MW-31 10/25/2006 Sulfate 526 mg/l D MW-31 3/15/2007 Sulfate 516 mg/l D MW-31 8/27/2007 Sulfate 532 mg/l D MW-31 10/24/2007 Sulfate 497 mg/l D MW-31 3/19/2008 Sulfate 521 mg/l D MW-31 6/3/2008 Sulfate 514 mg/l D MW-31 8/4/2008 Sulfate 499 mg/l D MW-31 11/11/2008 Sulfate 541 mg/l D MW-31 2/3/2009 Sulfate 488 mg/l D MW-31 5/13/2009 Sulfate 493 mg/l D MW-31 8/24/2009 Sulfate 460 mg/l D MW-31 10/14/2009 Sulfate 497 mg/l D MW-31 2/9/2010 Sulfate 507 mg/l D MW-31 4/20/2010 Sulfate 522 mg/l D MW-31 9/13/2010 Sulfate 527 mg/l D MW-31 11/9/2010 Sulfate 539 mg/l D MW-31 2/1/2011 Sulfate 538 mg/l D MW-31 3/14/2011 Sulfate 531 mg/l D MW-31 4/1/2011 Sulfate 503 mg/l D MW-31 5/10/2011 Sulfate 512 mg/l D MW-31 6/20/2011 Sulfate 540 mg/l D MW-31 7/5/2011 Sulfate 532 mg/l D MW-31 8/2/2011 Sulfate 537 mg/l D MW-31 9/6/2011 Sulfate 541 mg/l D MW-31 10/3/2011 Sulfate 539 mg/l D MW-31 11/8/2011 Sulfate 552 mg/l D MW-31 12/12/2011 Sulfate 530 mg/l D MW-31 1/24/2012 Sulfate 539 mg/l D MW-31 2/13/2012 Sulfate 538 mg/l D MW-31 3/13/2012 Sulfate 517 mg/l D MW-31 4/9/2012 Sulfate 547 mg/l D MW-31 5/2/2012 Sulfate 532 mg/l D MW-31 6/18/2012 Sulfate 497 mg/l D MW-31 7/9/2012 Sulfate 529 mg/l D MW-31 8/6/2012 Sulfate 571 mg/l D MW-31 9/18/2012 Sulfate 561 mg/l D MW-31 10/22/2012 Sulfate 545 mg/l MW-31 11/6/2012 Sulfate 557 mg/l MW-31 12/18/2012 Sulfate 664 mg/l Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 5 of 17 Appendix B-5: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units Qualifier MW-31 1/22/2013 Sulfate 611 mg/l MW-31 2/19/2013 Sulfate 644 mg/l MW-31 3/19/2013 Sulfate 611 mg/l MW-31 4/16/2013 Sulfate 668 mg/l MW-31 5/13/2013 Sulfate 630 mg/l MW-31 6/24/2013 Sulfate 659 mg/l MW-31 7/9/2013 Sulfate 659 mg/l MW-31 8/19/2013 Sulfate 656 mg/l MW-31 9/17/2013 Sulfate 666 mg/l MW-31 10/23/2013 Sulfate 637 mg/l MW-31 11/18/2013 Sulfate 609 mg/l MW-31 12/17/2013 Sulfate 656 mg/l MW-31 1/7/2014 Sulfate 558 mg/l MW-31 2/17/2014 Sulfate 480 mg/l MW-31 3/10/2014 Sulfate 681 mg/l MW-31 4/28/2014 Sulfate 527 mg/l MW-31 5/13/2014 Sulfate 639 mg/l MW-31 6/2/2014 Sulfate 555 mg/l MW-31 7/28/2014 Sulfate 600 mg/l MW-31 8/18/2014 Sulfate 620 mg/l MW-31 9/3/2014 Sulfate 560 mg/l MW-31 10/6/2014 Sulfate 606 mg/l MW-31 11/4/2014 Sulfate 639 mg/l MW-31 12/9/2014 Sulfate 687 mg/l MW-31 1/20/2015 Sulfate 669 mg/l MW-31 2/2/2015 Sulfate 623 mg/l MW-31 3/3/2015 Sulfate 616 mg/l MW-31 4/7/2015 Sulfate 642 mg/l MW-31 5/11/2015 Sulfate 668 mg/l MW-31 6/23/2015 Sulfate 691 mg/l MW-31 7/6/2015 Sulfate 684 mg/l MW-31 8/10/2015 Sulfate 640 mg/l MW-31 9/15/2015 Sulfate 638 mg/l MW-31 10/6/2015 Sulfate 655 mg/l MW-31 11/9/2015 Sulfate 646 mg/l MW-31 12/8/2015 Sulfate 690 mg/l MW-31 1/19/2016 Sulfate 675 mg/l MW-31 2/15/2016 Sulfate 631 mg/l MW-31 3/2/2016 Sulfate 654 mg/l MW-31 4/12/2016 Sulfate 715 mg/l MW-31 5/3/2016 Sulfate 699 mg/l MW-31 6/15/2016 Sulfate 748 mg/l MW-31 7/12/2016 Sulfate 712 mg/l MW-31 8/16/2016 Sulfate 766 mg/l MW-31 9/13/2016 Sulfate 703 mg/l Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 6 of 17 Appendix B-5: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units Qualifier MW-31 10/4/2016 Sulfate 720 mg/l MW-31 11/1/2016 Sulfate 752 mg/l MW-31 12/5/2016 Sulfate 748 mg/l MW-31 1/17/2017 Sulfate 809 mg/l MW-31 2/7/2017 Sulfate 751 mg/l MW-31 3/6/2017 Sulfate 741 mg/l MW-31 4/4/2017 Sulfate 758 mg/l MW-31 5/1/2017 Sulfate 741 mg/l MW-31 6/5/2017 Sulfate 808 mg/l MW-31 7/11/2017 Sulfate 747 mg/l MW-31 8/14/2017 Sulfate 916 mg/l MW-31 9/11/2017 Sulfate 762 mg/l MW-31 10/2/2017 Sulfate 823 mg/l MW-31 11/1/2017 Sulfate 847 mg/l MW-31 12/4/2017 Sulfate 825 mg/l MW-31 1/24/2018 Sulfate 813 mg/l MW-31 2/20/2018 Sulfate 835 mg/l MW-31 4/17/2018 Sulfate 857 mg/l MW-31 6/18/2018 Sulfate 976 mg/l MW-31 7/23/2018 Sulfate 857 mg/l MW-31 8/10/2018 Sulfate 841 mg/l MW-31 9/10/2018 Sulfate 893 mg/l MW-31 10/24/2018 Sulfate 950 mg/l MW-31 11/13/2018 Sulfate 841 mg/l MW-31 12/10/2018 Sulfate 905 mg/l MW-31 1/15/2019 Sulfate 851 mg/l MW-31 2/12/2019 Sulfate 893 mg/l MW-31 3/5/2019 Sulfate 953 mg/l MW-31 4/10/2019 Sulfate 917 mg/l MW-31 7/15/2019 Sulfate 1150 mg/l MW-31 10/9/2019 Sulfate 1010 mg/l MW-31 11/12/2019 Sulfate 990 mg/l MW-31 12/3/2019 Sulfate 1020 mg/l MW-31 1/14/2020 Sulfate 1120 mg/l MW-31 2/4/2020 Sulfate 1150 mg/l MW-31 3/10/2020 Sulfate 1080 mg/l MW-31 6/22/2005 Total Dissolved Solids 1290 mg/l MW-31 9/22/2005 Total Dissolved Solids 1280 mg/l MW-31 12/14/2005 Total Dissolved Solids 1290 mg/l MW-31 3/22/2006 Total Dissolved Solids 1280 mg/l H MW-31 6/21/2006 Total Dissolved Solids 1300 mg/l MW-31 9/13/2006 Total Dissolved Solids 1320 mg/l MW-31 10/25/2006 Total Dissolved Solids 1220 mg/l MW-31 3/15/2007 Total Dissolved Solids 1280 mg/l MW-31 8/27/2007 Total Dissolved Solids 1240 mg/l Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 8 of 17 Appendix B-5: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units Qualifier MW-31 10/24/2007 Total Dissolved Solids 1150 mg/l MW-31 3/19/2008 Total Dissolved Solids 1220 mg/l MW-31 6/3/2008 Total Dissolved Solids 1180 mg/l MW-31 8/4/2008 Total Dissolved Solids 1240 mg/l MW-31 11/11/2008 Total Dissolved Solids 1220 mg/l MW-31 2/3/2009 Total Dissolved Solids 1210 mg/l MW-31 5/13/2009 Total Dissolved Solids 1230 mg/l MW-31 8/24/2009 Total Dissolved Solids 1230 mg/l MW-31 12/2/2009 Total Dissolved Solids 1160 mg/l MW-31 2/9/2010 Total Dissolved Solids 1150 mg/l MW-31 4/20/2010 Total Dissolved Solids 1220 mg/l MW-31 9/13/2010 Total Dissolved Solids 1330 mg/l MW-31 11/9/2010 Total Dissolved Solids 1320 mg/l MW-31 1/10/2011 Total Dissolved Solids 1240 mg/l MW-31 2/1/2011 Total Dissolved Solids 1220 mg/l MW-31 3/14/2011 Total Dissolved Solids 1250 mg/l MW-31 4/1/2011 Total Dissolved Solids 1370 mg/l MW-31 5/10/2011 Total Dissolved Solids 1290 mg/l MW-31 6/20/2011 Total Dissolved Solids 1330 mg/l MW-31 7/5/2011 Total Dissolved Solids 1280 mg/l MW-31 8/2/2011 Total Dissolved Solids 1300 mg/l MW-31 9/6/2011 Total Dissolved Solids 1300 mg/l MW-31 10/3/2011 Total Dissolved Solids 1320 mg/l MW-31 11/8/2011 Total Dissolved Solids 1290 mg/l MW-31 12/12/2011 Total Dissolved Solids 1330 mg/l MW-31 1/24/2012 Total Dissolved Solids 1360 mg/l MW-31 2/13/2012 Total Dissolved Solids 1240 mg/l MW-31 3/13/2012 Total Dissolved Solids 1400 mg/l MW-31 4/9/2012 Total Dissolved Solids 1380 mg/l MW-31 5/2/2012 Total Dissolved Solids 1410 mg/l MW-31 6/29/2012 Total Dissolved Solids 1460 mg/l MW-31 7/9/2012 Total Dissolved Solids 1400 mg/l MW-31 8/6/2012 Total Dissolved Solids 1400 mg/l MW-31 9/18/2012 Total Dissolved Solids 1460 mg/l MW-31 10/22/2012 Total Dissolved Solids 1320 mg/l MW-31 11/6/2012 Total Dissolved Solids 1230 mg/l MW-31 12/18/2012 Total Dissolved Solids 1270 mg/l MW-31 1/22/2013 Total Dissolved Solids 1270 mg/l MW-31 2/19/2013 Total Dissolved Solids 1390 mg/l MW-31 3/19/2013 Total Dissolved Solids 1420 mg/l MW-31 4/16/2013 Total Dissolved Solids 1260 mg/l MW-31 5/13/2013 Total Dissolved Solids 1540 mg/l MW-31 6/24/2013 Total Dissolved Solids 1380 mg/l MW-31 7/9/2013 Total Dissolved Solids 1510 mg/l MW-31 8/19/2013 Total Dissolved Solids 1440 mg/l Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 9 of 17 Appendix B-5: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units Qualifier MW-31 9/17/2013 Total Dissolved Solids 1500 mg/l MW-31 10/23/2013 Total Dissolved Solids 1460 mg/l MW-31 11/18/2013 Total Dissolved Solids 1320 mg/l MW-31 12/17/2013 Total Dissolved Solids 1500 mg/l MW-31 1/7/2014 Total Dissolved Solids 1510 mg/l MW-31 2/17/2014 Total Dissolved Solids 1460 mg/l MW-31 3/10/2014 Total Dissolved Solids 1490 mg/l MW-31 4/28/2014 Total Dissolved Solids 1440 mg/l MW-31 5/13/2014 Total Dissolved Solids 1510 mg/l MW-31 6/2/2014 Total Dissolved Solids 1520 mg/l MW-31 7/28/2014 Total Dissolved Solids 1400 mg/l MW-31 8/18/2014 Total Dissolved Solids 1410 mg/l MW-31 9/3/2014 Total Dissolved Solids 1460 mg/l MW-31 10/6/2014 Total Dissolved Solids 1420 mg/l MW-31 11/4/2014 Total Dissolved Solids 1520 mg/l MW-31 12/9/2014 Total Dissolved Solids 1450 mg/l MW-31 1/20/2015 Total Dissolved Solids 1540 mg/l MW-31 2/2/2015 Total Dissolved Solids 1520 mg/l MW-31 3/3/2015 Total Dissolved Solids 1530 mg/l MW-31 4/7/2015 Total Dissolved Solids 1680 mg/l MW-31 5/11/2015 Total Dissolved Solids 1700 mg/l MW-31 6/23/2015 Total Dissolved Solids 1630 mg/l MW-31 7/6/2015 Total Dissolved Solids 1440 mg/l MW-31 8/10/2015 Total Dissolved Solids 1530 mg/l MW-31 9/15/2015 Total Dissolved Solids 1480 mg/l MW-31 10/6/2015 Total Dissolved Solids 1540 mg/l MW-31 11/9/2015 Total Dissolved Solids 1460 mg/l MW-31 12/8/2015 Total Dissolved Solids 1580 mg/l MW-31 1/19/2016 Total Dissolved Solids 1560 mg/l MW-31 2/15/2016 Total Dissolved Solids 1490 mg/l MW-31 3/2/2016 Total Dissolved Solids 1580 mg/l MW-31 4/12/2016 Total Dissolved Solids 1710 mg/l MW-31 5/3/2016 Total Dissolved Solids 1550 mg/l MW-31 6/15/2016 Total Dissolved Solids 1580 mg/l MW-31 7/12/2016 Total Dissolved Solids 1610 mg/l MW-31 8/16/2016 Total Dissolved Solids 1710 mg/l MW-31 9/13/2016 Total Dissolved Solids 1570 mg/l MW-31 10/4/2016 Total Dissolved Solids 1670 mg/l MW-31 11/1/2016 Total Dissolved Solids 1690 mg/l MW-31 12/5/2016 Total Dissolved Solids 1670 mg/l MW-31 1/17/2017 Total Dissolved Solids 1730 mg/l MW-31 2/7/2017 Total Dissolved Solids 1680 mg/l MW-31 3/6/2017 Total Dissolved Solids 1690 mg/l MW-31 4/4/2017 Total Dissolved Solids 1660 mg/l MW-31 5/1/2017 Total Dissolved Solids 1820 mg/l Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 10 of 17 Appendix B-5: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units Qualifier MW-31 6/5/2017 Total Dissolved Solids 1710 mg/l MW-31 7/11/2017 Total Dissolved Solids 1830 mg/l MW-31 8/14/2017 Total Dissolved Solids 1780 mg/l MW-31 9/11/2017 Total Dissolved Solids 1780 mg/l MW-31 10/2/2017 Total Dissolved Solids 1760 mg/l MW-31 11/1/2017 Total Dissolved Solids 1770 mg/l MW-31 12/4/2017 Total Dissolved Solids 1910 mg/l MW-31 1/24/2018 Total Dissolved Solids 1800 mg/l MW-31 2/20/2018 Total Dissolved Solids 1930 mg/l MW-31 4/17/2018 Total Dissolved Solids 1980 mg/l MW-31 6/18/2018 Total Dissolved Solids 2010 mg/l MW-31 7/23/2018 Total Dissolved Solids 2000 mg/l MW-31 8/10/2018 Total Dissolved Solids 1980 mg/l MW-31 9/10/2018 Total Dissolved Solids 2100 mg/l MW-31 10/24/2018 Total Dissolved Solids 2000 mg/l MW-31 11/13/2018 Total Dissolved Solids 1960 mg/l MW-31 12/10/2018 Total Dissolved Solids 2090 mg/l MW-31 1/15/2019 Total Dissolved Solids 2030 mg/l MW-31 2/12/2019 Total Dissolved Solids 2090 mg/l MW-31 3/5/2019 Total Dissolved Solids 2160 mg/l MW-31 4/10/2019 Total Dissolved Solids 2080 mg/l MW-31 7/15/2019 Total Dissolved Solids 2580 mg/l MW-31 10/9/2019 Total Dissolved Solids 2280 mg/l MW-31 11/12/2019 Total Dissolved Solids 2650 mg/l MW-31 12/3/2019 Total Dissolved Solids 2030 mg/l MW-31 1/14/2020 Total Dissolved Solids 2220 mg/l MW-31 2/4/2020 Total Dissolved Solids 2240 mg/l MW-31 3/10/2020 Total Dissolved Solids 2380 mg/l Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 11 of 17 Appendix B-6: Box Plots Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 12 of 17 :::::::::: C> E Q) -~ ::i (f) :::::::::: 1100 1000 900 800 700 600 500 E' 2500 .._.... (/) "'O 0 (f) "'O Q) > 0 (/) (/) 0 ro -0 I- 2000 1500 Sulfate in MW-31 8 0 Percent nondetect: 0% Min: 436, Mean: 668.86, Max: 1150, Std Dev: 160.92 Upper extreme threshold (Q75 + 3xH): 1389.25 Lower extreme threshold (Q25 -3xH): -101.75 Total Dissolved Solids in MW-31 0 0 0 Percent nondetect: 0% Min: 1150, Mean: 1555.28, Max: 2650, Std Dev: 313.7 Upper extreme threshold (075 + 3xH): 2890 Lower extreme threshold (Q25 -3xH): 125 P'!-$INTERA Appendix B-7: Box Plots for MW-31 and Upgradient and Downgradient Wells Downgradient wells: MW-3A, MW-20, and MW-22. Upgradient wells: MW-1, MW-18, and MW-19 Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 13 of 17 Appendix B-8: Box Plots for SAR Parameters in Groundwater Monitoring Wells Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 14 of 17 Appendix B-11: Timeseries Plots with Events Appendix B Source Assessment Report for MW-31 White Mesa Uranium Mill Page 17 of 17 APPENDIX C Geochemical Analysis for Indicator Parameters in MW-31 Appendix C-1: Summary of Geochemical Analysis for Indicator Parameters in MW-31 W p r2 p S p MW-31 Chloride (mg/L)131 0 220 73.9 0.9532 0.0002 No NA NA 7448 0 Increasing Increasing No IncreasingMW-31 Fluoride (mg/L)59 0 0.809 0.103 0.9689 0.1355 Normal 0.540 3.4E-11 -1046 4.04E-12 Decreasing Decreasing No Decreasing MW-31 Sulfate (mg/L)126 0 669 160.9 0.9468 0.0001 No NA NA 6354 0 Increasing Increasing No Increasing MW-31 Uranium (µg/L)79 0 9.24 2.24 0.9548 0.0070 No NA NA 2307 0 Increasing Increasing No Increasing Notes: σ = sigma N = number of valid data points S = Mann-Kendall statistic %ND = percent of non-detected values p = probability µg/L = micrograms per liter W = Shapiro-Wilk test value mg/L = milligrams per liter r2 = The measure of how well the trendline fits the data where r2=1 represents a perfect fit. a = A regression test was performed on data that was determined to have normal or log-normal distribution b = The Mann-Kendall test was performed on data that are not normally or lognormally distributed 2020 Significant TrendStandard DeviationWellConstituentN % Non- Detected Values Mean Least Squares Regression Trend Analysisa Mann-Kendall Trend Analysisb 2017 Significant Trend? Background Report Significant Trend? Shapiro-Wilk Test for Normality Normally or Lognormally distributed? 2015 Significant Trend? Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Appendix C-2: Descriptive Statistics of Indicator Parameters in MW-31 Data Set Analyte Chloride Fluoride Sulfate Uranium Chloride Fluoride Sulfate Uranium Chloride Fluoride Sulfate Uranium Chloride Fluoride Sulfate Uranium Chloride Fluoride Sulfate Uranium Units mg/L mg/L mg/L ug/L mg/L mg/L mg/L ug/L mg/L mg/L mg/L ug/L mg/L mg/L mg/L ug/L mg/L mg/L mg/L ug/L % Non-Detects 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N 131 59 126 79 98 47 99 54 76 41 77 42 50 31 47 32 10 10 10 10 Normally or Lognormallly Distributed?No Yes No No No Yes No Yes No No No Yes Yes No No Yes Yes No No Yes Mean 219.63 0.81 668.86 9.24 186 0.818 601 7.96 167 0.84 567 7.5 146 0.86 527 7.3 133 0.91 504 7.6 Min. Conc.115 0.53 436 5.77 115 0.605 436 5.77 115 0.61 436 5.8 115 0.73 436 5.8 122 0.80 436 6.6 Max. Conc.381 1.18 1150 14.80 287 0.99 809 10.3 264 1.2 691 9.3 189 1.0 630 9.3 139 1.2 532 9.3 Std. Dev.73.92 0.10 160.92 2.24 47.7 0.080 87.9 1.08 35 0.09 65 0.8 18.1 0.06 34.5 0.74 5 0.12 28 0.75 Range 266.0 0.66 714 9.03 172 0.385 373 4.53 149 0.60 255 3.6 74.0 0.26 194 3.6 17 0.40 96 2.8 Geometric Mean 207.60 0.80 651.61 8.99 180 0.814 594 7.89 163 0.84 564 7.5 145 0.86 526 7.3 133 0.90 504 7.6 Skewness 0.45 0.40 1.04 0.76 0.37 -0.27 0.41 0.43 0.56 0.96 0.40 0.31 0.50 -0.17 0.56 0.73 -1.1 1.9 -1.9 1.2 Q25 149 0.74 537.25 7.34 144 0.763 528 7.14 138 0.78 521 7.0 132 0.83 507 6.9 131 0.85 497 7.2 Median 210 0.81 639.50 8.73 176 0.830 600 7.72 159 0.84 541 7.5 144 0.86 529 7.2 134 0.90 513 7.4 Q75 276 0.87 750.25 10.70 225.75 0.89 665.00 8.75 195 0.90 630 8.0 157 0.90 540 7.7 136 0.90 522 8.0 2017 SAR 2015 SAR 2013 SAR 2008 Background Report2020 SAR Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 06/22/2005 Chloride 139 mg/l MW-31 09/22/2005 Chloride 136 mg/l MW-31 12/14/2005 Chloride 135 mg/l MW-31 03/22/2006 Chloride 133 mg/l MW-31 06/21/2006 Chloride 138 mg/l MW-31 09/13/2006 Chloride 131 mg/l MW-31 10/25/2006 Chloride 127 mg/l MW-31 03/15/2007 Chloride 132 mg/l MW-31 08/27/2007 Chloride 136 mg/l MW-31 10/24/2007 Chloride 122 mg/l MW-31 03/19/2008 Chloride 124 mg/l MW-31 06/03/2008 Chloride 128 mg/l MW-31 08/04/2008 Chloride 124 mg/l MW-31 11/11/2008 Chloride 119 mg/l MW-31 02/03/2009 Chloride 115 mg/l MW-31 05/13/2009 Chloride 124 mg/l MW-31 08/24/2009 Chloride 122 mg/l MW-31 10/14/2009 Chloride 138 mg/l MW-31 02/09/2010 Chloride 128 mg/l MW-31 04/20/2010 Chloride 128 mg/l MW-31 09/13/2010 Chloride 139 mg/l MW-31 11/09/2010 Chloride 138 mg/l MW-31 02/01/2011 Chloride 145 mg/l MW-31 04/01/2011 Chloride 143 mg/l MW-31 05/10/2011 Chloride 143 mg/l MW-31 06/20/2011 Chloride 145 mg/l MW-31 07/05/2011 Chloride 148 mg/l MW-31 08/02/2011 Chloride 148 mg/l MW-31 09/06/2011 Chloride 148 mg/l MW-31 10/03/2011 Chloride 145 mg/l MW-31 11/08/2011 Chloride 145 mg/l MW-31 12/12/2011 Chloride 148 mg/l MW-31 01/24/2012 Chloride 155 mg/l MW-31 02/13/2012 Chloride 150 mg/l MW-31 03/13/2012 Chloride 152 mg/l MW-31 04/09/2012 Chloride 160 mg/l MW-31 05/02/2012 Chloride 151 mg/l MW-31 06/18/2012 Chloride 138 mg/l MW-31 07/09/2012 Chloride 161 mg/l MW-31 08/06/2012 Chloride 175 mg/l MW-31 09/18/2012 Chloride 172 mg/l MW-31 10/22/2012 Chloride 157 mg/l MW-31 11/06/2012 Chloride 189 mg/l MW-31 12/18/2012 Chloride 170 mg/l MW-31 01/22/2013 Chloride 176 mg/l Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 3 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 02/19/2013 Chloride 174 mg/l MW-31 03/19/2013 Chloride 168 mg/l MW-31 04/16/2013 Chloride 171 mg/l MW-31 05/13/2013 Chloride 169 mg/l MW-31 06/24/2013 Chloride 179 mg/l MW-31 07/09/2013 Chloride 182 mg/l MW-31 08/19/2013 Chloride 183 mg/l MW-31 09/17/2013 Chloride 193 mg/l MW-31 10/23/2013 Chloride 188 mg/l MW-31 11/18/2013 Chloride 174 mg/l MW-31 12/17/2013 Chloride 203 mg/l MW-31 01/07/2014 Chloride 194 mg/l MW-31 02/17/2014 Chloride 197 mg/l MW-31 03/10/2014 Chloride 230 mg/l MW-31 04/28/2014 Chloride 230 mg/l MW-31 05/13/2014 Chloride 200 mg/l MW-31 06/02/2014 Chloride 173 mg/l MW-31 07/28/2014 Chloride 200 mg/l MW-31 08/18/2014 Chloride 210 mg/l MW-31 09/03/2014 Chloride 210 mg/l MW-31 10/06/2014 Chloride 205 mg/l MW-31 11/04/2014 Chloride 204 mg/l MW-31 12/09/2014 Chloride 215 mg/l MW-31 01/20/2015 Chloride 226 mg/l MW-31 02/02/2015 Chloride 211 mg/l MW-31 03/03/2015 Chloride 209 mg/l MW-31 04/07/2015 Chloride 211 mg/l MW-31 05/11/2015 Chloride 225 mg/l MW-31 06/23/2015 Chloride 228 mg/l MW-31 07/06/2015 Chloride 222 mg/l MW-31 08/10/2015 Chloride 264 mg/l MW-31 09/15/2015 Chloride 231 mg/l MW-31 10/06/2015 Chloride 222 mg/l MW-31 11/09/2015 Chloride 215 mg/l MW-31 12/08/2015 Chloride 231 mg/l MW-31 01/19/2016 Chloride 228 mg/l MW-31 02/15/2016 Chloride 246 mg/l MW-31 03/02/2016 Chloride 228 mg/l MW-31 04/12/2016 Chloride 254 mg/l MW-31 05/03/2016 Chloride 243 mg/l MW-31 06/15/2016 Chloride 252 mg/l MW-31 07/12/2016 Chloride 241 mg/l MW-31 08/16/2016 Chloride 272 mg/l MW-31 09/13/2016 Chloride 254 mg/l MW-31 10/04/2016 Chloride 260 mg/l Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 4 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 11/01/2016 Chloride 267 mg/l MW-31 12/05/2016 Chloride 274 mg/l MW-31 01/17/2017 Chloride 287 mg/l MW-31 02/07/2017 Chloride 266 mg/l MW-31 03/06/2017 Chloride 250 mg/l MW-31 04/04/2017 Chloride 263 mg/l MW-31 05/01/2017 Chloride 263 mg/l MW-31 06/05/2017 Chloride 278 mg/l MW-31 07/11/2017 Chloride 254 mg/l MW-31 08/14/2017 Chloride 310 mg/l MW-31 09/11/2017 Chloride 248 mg/l MW-31 10/02/2017 Chloride 287 mg/l MW-31 11/01/2017 Chloride 292 mg/l MW-31 12/04/2017 Chloride 285 mg/l MW-31 01/24/2018 Chloride 323 mg/l MW-31 02/20/2018 Chloride 292 mg/l MW-31 03/05/2018 Chloride 311 mg/l MW-31 04/17/2018 Chloride 308 mg/l MW-31 05/14/2018 Chloride 326 mg/l MW-31 06/18/2018 Chloride 359 mg/l MW-31 07/23/2018 Chloride 351 mg/l MW-31 08/10/2018 Chloride 336 mg/l MW-31 09/10/2018 Chloride 333 mg/l MW-31 10/24/2018 Chloride 286 mg/l MW-31 11/13/2018 Chloride 281 mg/l MW-31 12/10/2018 Chloride 302 mg/l MW-31 01/15/2019 Chloride 283 mg/l MW-31 02/12/2019 Chloride 296 mg/l MW-31 03/05/2019 Chloride 322 mg/l MW-31 04/10/2019 Chloride 294 mg/l MW-31 05/07/2019 Chloride 346 mg/l MW-31 06/03/2019 Chloride 325 mg/l MW-31 07/15/2019 Chloride 374 mg/l MW-31 08/05/2019 Chloride 372 mg/l MW-31 09/23/2019 Chloride 365 mg/l MW-31 10/09/2019 Chloride 318 mg/l MW-31 11/12/2019 Chloride 338 mg/l MW-31 12/03/2019 Chloride 343 mg/l MW-31 01/14/2020 Chloride 381 mg/l MW-31 02/04/2020 Chloride 370 mg/l MW-31 03/10/2020 Chloride 368 mg/l MW-31 06/22/2005 Fluoride 0.83 mg/l MW-31 09/22/2005 Fluoride 0.91 mg/l MW-31 12/14/2005 Fluoride 0.85 mg/l MW-31 03/22/2006 Fluoride 0.90 mg/l Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 5 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 06/21/2006 Fluoride 0.86 mg/l MW-31 09/13/2006 Fluoride 0.94 mg/l MW-31 10/25/2006 Fluoride 1.18 mg/l MW-31 03/15/2007 Fluoride 0.94 mg/l MW-31 08/27/2007 Fluoride 0.99 mg/l MW-31 10/24/2007 Fluoride 0.85 mg/l MW-31 03/19/2008 Fluoride 0.92 mg/l MW-31 06/03/2008 Fluoride 0.94 mg/l MW-31 08/04/2008 Fluoride 0.85 mg/l MW-31 02/03/2009 Fluoride 0.91 mg/l MW-31 05/13/2009 Fluoride 0.90 mg/l MW-31 08/24/2009 Fluoride 0.89 mg/l MW-31 10/14/2009 Fluoride 0.90 mg/l MW-31 02/09/2010 Fluoride 0.88 mg/l MW-31 04/20/2010 Fluoride 0.84 mg/l MW-31 09/13/2010 Fluoride 0.89 mg/l MW-31 11/09/2010 Fluoride 0.84 mg/l MW-31 02/01/2011 Fluoride 0.83 mg/l MW-31 04/01/2011 Fluoride 0.83 mg/l MW-31 08/02/2011 Fluoride 0.80 mg/l MW-31 10/03/2011 Fluoride 0.84 mg/l MW-31 02/13/2012 Fluoride 0.86 mg/l MW-31 05/02/2012 Fluoride 0.78 mg/l MW-31 07/09/2012 Fluoride 0.78 mg/l MW-31 11/06/2012 Fluoride 0.76 mg/l MW-31 02/19/2013 Fluoride 0.73 mg/l MW-31 05/13/2013 Fluoride 0.76 mg/l MW-31 07/09/2013 Fluoride 0.84 mg/l MW-31 11/18/2013 Fluoride 0.76 mg/l MW-31 02/17/2014 Fluoride 0.81 mg/l MW-31 03/10/2014 Fluoride 0.82 mg/l MW-31 06/02/2014 Fluoride 0.74 mg/l MW-31 09/03/2014 Fluoride 0.80 mg/l MW-31 11/04/2014 Fluoride 0.61 mg/l MW-31 02/02/2015 Fluoride 0.76 mg/l MW-31 04/07/2015 Fluoride 0.75 mg/l MW-31 08/10/2015 Fluoride 0.72 mg/l MW-31 11/09/2015 Fluoride 0.68 mg/l MW-31 02/15/2016 Fluoride 0.72 mg/l MW-31 05/03/2016 Fluoride 0.76 mg/l MW-31 08/16/2016 Fluoride 0.77 mg/l MW-31 11/01/2016 Fluoride 0.74 mg/l MW-31 02/07/2017 Fluoride 0.71 mg/l MW-31 05/01/2017 Fluoride 0.69 mg/l MW-31 08/14/2017 Fluoride 0.73 mg/l Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 6 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 11/01/2017 Fluoride 0.79 mg/l MW-31 02/20/2018 Fluoride 0.81 mg/l MW-31 04/17/2018 Fluoride 0.81 mg/l MW-31 09/10/2018 Fluoride 0.66 mg/l MW-31 10/24/2018 Fluoride 0.69 mg/l MW-31 01/15/2019 Fluoride 0.70 mg/l MW-31 04/10/2019 Fluoride 0.67 mg/l MW-31 07/15/2019 Fluoride 0.89 mg/l MW-31 10/09/2019 Fluoride 0.53 mg/l MW-31 01/14/2020 Fluoride 0.78 mg/l MW-31 06/22/2005 Sulfate 504 mg/l MW-31 09/22/2005 Sulfate 436 mg/l D MW-31 12/14/2005 Sulfate 509 mg/l D MW-31 03/22/2006 Sulfate 485 mg/l D MW-31 06/21/2006 Sulfate 522 mg/l D MW-31 09/13/2006 Sulfate 516 mg/l D MW-31 10/25/2006 Sulfate 526 mg/l D MW-31 03/15/2007 Sulfate 516 mg/l D MW-31 08/27/2007 Sulfate 532 mg/l D MW-31 10/24/2007 Sulfate 497 mg/l D MW-31 03/19/2008 Sulfate 521 mg/l D MW-31 06/03/2008 Sulfate 514 mg/l D MW-31 08/04/2008 Sulfate 499 mg/l D MW-31 11/11/2008 Sulfate 541 mg/l D MW-31 02/03/2009 Sulfate 488 mg/l D MW-31 05/13/2009 Sulfate 493 mg/l D MW-31 08/24/2009 Sulfate 460 mg/l D MW-31 10/14/2009 Sulfate 497 mg/l D MW-31 02/09/2010 Sulfate 507 mg/l D MW-31 04/20/2010 Sulfate 522 mg/l D MW-31 09/13/2010 Sulfate 527 mg/l D MW-31 11/09/2010 Sulfate 539 mg/l D MW-31 02/01/2011 Sulfate 538 mg/l D MW-31 03/14/2011 Sulfate 531 mg/l D MW-31 04/01/2011 Sulfate 503 mg/l D MW-31 05/10/2011 Sulfate 512 mg/l D MW-31 06/20/2011 Sulfate 540 mg/l D MW-31 07/05/2011 Sulfate 532 mg/l D MW-31 08/02/2011 Sulfate 537 mg/l D MW-31 09/06/2011 Sulfate 541 mg/l D MW-31 10/03/2011 Sulfate 539 mg/l D MW-31 11/08/2011 Sulfate 552 mg/l D MW-31 12/12/2011 Sulfate 530 mg/l D MW-31 01/24/2012 Sulfate 539 mg/l D MW-31 02/13/2012 Sulfate 538 mg/l D Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 7 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 03/13/2012 Sulfate 517 mg/l D MW-31 04/09/2012 Sulfate 547 mg/l D MW-31 05/02/2012 Sulfate 532 mg/l D MW-31 06/18/2012 Sulfate 497 mg/l D MW-31 07/09/2012 Sulfate 529 mg/l D MW-31 08/06/2012 Sulfate 571 mg/l D MW-31 09/18/2012 Sulfate 561 mg/l D MW-31 10/22/2012 Sulfate 545 mg/l MW-31 11/06/2012 Sulfate 557 mg/l MW-31 12/18/2012 Sulfate 664 mg/l MW-31 01/22/2013 Sulfate 611 mg/l MW-31 02/19/2013 Sulfate 644 mg/l MW-31 03/19/2013 Sulfate 611 mg/l MW-31 04/16/2013 Sulfate 668 mg/l MW-31 05/13/2013 Sulfate 630 mg/l MW-31 06/24/2013 Sulfate 659 mg/l MW-31 07/09/2013 Sulfate 659 mg/l MW-31 08/19/2013 Sulfate 656 mg/l MW-31 09/17/2013 Sulfate 666 mg/l MW-31 10/23/2013 Sulfate 637 mg/l MW-31 11/18/2013 Sulfate 609 mg/l MW-31 12/17/2013 Sulfate 656 mg/l MW-31 01/07/2014 Sulfate 558 mg/l MW-31 02/17/2014 Sulfate 480 mg/l MW-31 03/10/2014 Sulfate 681 mg/l MW-31 04/28/2014 Sulfate 527 mg/l MW-31 05/13/2014 Sulfate 639 mg/l MW-31 06/02/2014 Sulfate 555 mg/l MW-31 07/28/2014 Sulfate 600 mg/l MW-31 08/18/2014 Sulfate 620 mg/l MW-31 09/03/2014 Sulfate 560 mg/l MW-31 10/06/2014 Sulfate 606 mg/l MW-31 11/04/2014 Sulfate 639 mg/l MW-31 12/09/2014 Sulfate 687 mg/l MW-31 01/20/2015 Sulfate 669 mg/l MW-31 02/02/2015 Sulfate 623 mg/l MW-31 03/03/2015 Sulfate 616 mg/l MW-31 04/07/2015 Sulfate 642 mg/l MW-31 05/11/2015 Sulfate 668 mg/l MW-31 06/23/2015 Sulfate 691 mg/l MW-31 07/06/2015 Sulfate 684 mg/l MW-31 08/10/2015 Sulfate 640 mg/l MW-31 09/15/2015 Sulfate 638 mg/l MW-31 10/06/2015 Sulfate 655 mg/l MW-31 11/09/2015 Sulfate 646 mg/l Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 8 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 12/08/2015 Sulfate 690 mg/l MW-31 01/19/2016 Sulfate 675 mg/l MW-31 02/15/2016 Sulfate 631 mg/l MW-31 03/02/2016 Sulfate 654 mg/l MW-31 04/12/2016 Sulfate 715 mg/l MW-31 05/03/2016 Sulfate 699 mg/l MW-31 06/15/2016 Sulfate 748 mg/l MW-31 07/12/2016 Sulfate 712 mg/l MW-31 08/16/2016 Sulfate 766 mg/l MW-31 09/13/2016 Sulfate 703 mg/l MW-31 10/04/2016 Sulfate 720 mg/l MW-31 11/01/2016 Sulfate 752 mg/l MW-31 12/05/2016 Sulfate 748 mg/l MW-31 01/17/2017 Sulfate 809 mg/l MW-31 02/07/2017 Sulfate 751 mg/l MW-31 03/06/2017 Sulfate 741 mg/l MW-31 04/04/2017 Sulfate 758 mg/l MW-31 05/01/2017 Sulfate 741 mg/l MW-31 06/05/2017 Sulfate 808 mg/l MW-31 07/11/2017 Sulfate 747 mg/l MW-31 08/14/2017 Sulfate 916 mg/l MW-31 09/11/2017 Sulfate 762 mg/l MW-31 10/02/2017 Sulfate 823 mg/l MW-31 11/01/2017 Sulfate 847 mg/l MW-31 12/04/2017 Sulfate 825 mg/l MW-31 01/24/2018 Sulfate 813 mg/l MW-31 02/20/2018 Sulfate 835 mg/l MW-31 04/17/2018 Sulfate 857 mg/l MW-31 06/18/2018 Sulfate 976 mg/l MW-31 07/23/2018 Sulfate 857 mg/l MW-31 08/10/2018 Sulfate 841 mg/l MW-31 09/10/2018 Sulfate 893 mg/l MW-31 10/24/2018 Sulfate 950 mg/l MW-31 11/13/2018 Sulfate 841 mg/l MW-31 12/10/2018 Sulfate 905 mg/l MW-31 01/15/2019 Sulfate 851 mg/l MW-31 02/12/2019 Sulfate 893 mg/l MW-31 03/05/2019 Sulfate 953 mg/l MW-31 04/10/2019 Sulfate 917 mg/l MW-31 07/15/2019 Sulfate 1150 mg/l MW-31 10/09/2019 Sulfate 1010 mg/l MW-31 11/12/2019 Sulfate 990 mg/l MW-31 12/03/2019 Sulfate 1020 mg/l MW-31 01/14/2020 Sulfate 1120 mg/l MW-31 02/04/2020 Sulfate 1150 mg/l Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 9 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 03/10/2020 Sulfate 1080 mg/l MW-31 06/22/2005 Uranium 6.56 µg/l MW-31 09/22/2005 Uranium 7.25 µg/l MW-31 12/14/2005 Uranium 7.27 µg/l MW-31 03/22/2006 Uranium 8.04 µg/l MW-31 06/21/2006 Uranium 9.32 µg/l MW-31 09/13/2006 Uranium 8.03 µg/l MW-31 10/25/2006 Uranium 7.71 µg/l MW-31 03/15/2007 Uranium 7.60 µg/l MW-31 08/27/2007 Uranium 7.18 µg/l MW-31 10/24/2007 Uranium 7.20 µg/l MW-31 03/19/2008 Uranium 7.02 µg/l MW-31 06/03/2008 Uranium 6.95 µg/l MW-31 08/04/2008 Uranium 6.77 µg/l MW-31 11/11/2008 Uranium 6.35 µg/l MW-31 02/03/2009 Uranium 7.08 µg/l MW-31 05/13/2009 Uranium 6.76 µg/l MW-31 08/24/2009 Uranium 6.97 µg/l MW-31 10/14/2009 Uranium 6.97 µg/l MW-31 02/09/2010 Uranium 7.12 µg/l MW-31 04/20/2010 Uranium 6.74 µg/l MW-31 09/13/2010 Uranium 7.23 µg/l MW-31 11/09/2010 Uranium 6.72 µg/l MW-31 02/01/2011 Uranium 5.77 µg/l MW-31 04/01/2011 Uranium 6.81 µg/l MW-31 08/02/2011 Uranium 7.68 µg/l MW-31 10/03/2011 Uranium 8.87 µg/l MW-31 02/13/2012 Uranium 7.96 µg/l MW-31 05/02/2012 Uranium 7.34 µg/l MW-31 07/09/2012 Uranium 8.17 µg/l MW-31 11/06/2012 Uranium 8.73 µg/l MW-31 02/19/2013 Uranium 7.33 µg/l MW-31 05/13/2013 Uranium 7.63 µg/l MW-31 07/09/2013 Uranium 7.90 µg/l MW-31 11/18/2013 Uranium 9.03 µg/l MW-31 02/17/2014 Uranium 7.65 µg/l MW-31 03/10/2014 Uranium 7.96 µg/l MW-31 06/02/2014 Uranium 7.72 µg/l MW-31 09/03/2014 Uranium 8.40 µg/l MW-31 11/04/2014 Uranium 7.71 µg/l MW-31 02/02/2015 Uranium 8.00 µg/l MW-31 04/07/2015 Uranium 8.07 µg/l MW-31 08/10/2015 Uranium 8.76 µg/l MW-31 11/09/2015 Uranium 8.72 µg/l MW-31 02/15/2016 Uranium 8.41 µg/l Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 10 of 23 Appendix C-3: Data Used for Statistical Analysis Well Sample Date Parameter Result Units Qualifier MW-31 05/03/2016 Uranium 9.05 µg/l MW-31 08/16/2016 Uranium 9.41 µg/l MW-31 11/01/2016 Uranium 9.56 µg/l MW-31 12/05/2016 Uranium 10.30 µg/l MW-31 01/17/2017 Uranium 9.03 µg/l MW-31 02/07/2017 Uranium 9.92 µg/l MW-31 03/06/2017 Uranium 9.62 µg/l MW-31 04/04/2017 Uranium 10.10 µg/l MW-31 05/01/2017 Uranium 9.62 µg/l MW-31 06/05/2017 Uranium 9.89 µg/l MW-31 07/11/2017 Uranium 10.50 µg/l MW-31 08/14/2017 Uranium 10.10 µg/l MW-31 09/11/2017 Uranium 9.74 µg/l MW-31 10/02/2017 Uranium 10.90 µg/l MW-31 11/01/2017 Uranium 9.31 µg/l MW-31 12/04/2017 Uranium 10.40 µg/l MW-31 01/24/2018 Uranium 11.40 µg/l MW-31 02/20/2018 Uranium 11.20 µg/l MW-31 03/05/2018 Uranium 11.40 µg/l MW-31 04/17/2018 Uranium 11.50 µg/l MW-31 05/14/2018 Uranium 11.50 µg/l MW-31 06/18/2018 Uranium 12.90 µg/l MW-31 07/23/2018 Uranium 12.30 µg/l MW-31 08/10/2018 Uranium 11.70 µg/l MW-31 09/10/2018 Uranium 11.00 µg/l MW-31 10/24/2018 Uranium 11.60 µg/l MW-31 11/13/2018 Uranium 13.20 µg/l MW-31 12/10/2018 Uranium 12.70 µg/l MW-31 01/15/2019 Uranium 13.20 µg/l MW-31 02/12/2019 Uranium 13.60 µg/l MW-31 03/05/2019 Uranium 12.50 µg/l MW-31 04/10/2019 Uranium 13.60 µg/l MW-31 07/15/2019 Uranium 14.30 µg/l MW-31 10/09/2019 Uranium 14.40 µg/l MW-31 01/14/2020 Uranium 14.80 µg/l Notes: D = field duplicate Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 11 of 23 Appendix C-4: Indicator Parameter Data Removed from Analysis Reason Location ID Date Sampled Parameter Name Report Result Report Units Extreme (Low)MW-31 11/11/2008 Fluoride 0.32 mg/L Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Appendix C-5: Box Plots for Indicator Parameters in MW-31 Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 13 of 23 350 ..-.. ::::: O> 300 .s Q) 250 "'O ·;:: 0 ..c (.) 200 150 1.2 1.1 ...-.. 1.0 ::::: O> .s 0 .9 Q) "'O ·;:: 0 .8 0 ::i LL 0.7 0.6 0 .5 Chloride in MW-31 Percent nondetect: 0% o Outlier • Extreme Min: 115, Mean: 219.63, Max: 381 , Std Dev: 73.92 Upper extreme threshold (Q75 + 3xH): 657 Lower extreme threshold (Q25 -3xH): -232 Fluoride in MW-31 0 0 Percent nondetect: 0% o Outlier • Extreme Min: 0.526, Mean: 0.81 , Max: 1.183244, Std Dev: 0.1 Upper extreme threshold (Q75 + 3xH): 1.2525 Lower extreme threshold (Q25 -3xH): 0.36 ---=2#e lNTERA Appendix C-5: Box Plots for Indicator Parameters in MW-31 Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 14 of 23 1100 1000 :::::::: 900 O> E .__. 800 Q) -~ 700 ::::J Cf) 600 500 14 ..--... :::::::: 12 O> ::::J .__. E 10 ::::J c:: ro ,__ :::) 8 6 Sulfate in MW-31 8 0 Percent nondetect: 0% o Outlier • Extreme Min: 436, Mean: 668.86, Max: 1150, Std Dev: 160.92 Upper extrema threshold (075 + 3xH): 1389.25 Lower extrema threshold (025 -3xH): -1 01.75 Uranium in MW-31 Percent nondetect: 0% o Outlier • Extreme Min: 5.77, Mean: 9.24, Max: 14.8, Std Dev: 2.24 Upper extreme threshold (075 + 3xH): 20.795 Lower extreme threshold (025 -3xH): -2.76 ---=2#e lNTERA Appendix C-6: Box Plots for Indicator Parameters in MW-31 and Upgradient and Downgradient Wells Downgradient wells: MW-3A, MW-20, and MW-22. Upgradient wells: MW-1, MW-18, and MW-19 Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 15 of 23 Appendix C-6: Box Plots for Indicator Parameters in MW-31 and Upgradient and Downgradient Wells Downgradient wells: MW-3A, MW-20, and MW-22. Upgradient wells: MW-1, MW-18, and MW-19 Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 16 of 23 Appendix C-9: Time Series Plots and Linear Regressions for Indicator Parameters in MW-31 Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 21 of 23 -14 ::::::: O> :::s 12 E 10 :::s c ro 8 ..... => 6 Uranium in MW-31 -d:>v ~eft; -~ 0 0 0 o 00 oa:>o o ooo cJS> BoocfP o -o <oo 0 00 CD 0:0 Oo<D'b <t> 0 0 0 I 2005 I 2010 I 2015 Sample Date I 2020 ---=2#e lNTERA Appendix C-10: Time Series with Events Appendix C Source Assesment Report for MW-31 White Mesa Uranium Mill Page 23 of 23 Sulfate in MW-31 • • 11 00 • -• 1000 -• , • •• -:::::::: 900 O> -• .... E ._... 800 Q) -~ ::i 700 (/) 600 ... , .. -...... ..... -.. ._,., ....... • t• t ··~· •• ::~ . --• 500 • • _. -41. •4 •• . . . ,. ... • .... 4 -.-• -• • ••• • • • • I I I 2005 2010 2015 2020 Sample Date Uranium in MW-31 • •• 14 ---• • • • ........... 12 :::::: O> ::I .__, -., .. • • E ::I 10 ·c ro ..._ => 8 ••• -•••• ·-· • • • • ~ • • • •• • • -•• •• • • -•• • • .4 •• .. -.. . -·· • • • • • • • •• • -• 6 I I I I 2005 2010 2015 2020 2010-02-01 Monthly sampling 2011-05-03 Well redevelopment 2012-10-01 Lab change Sample Date 2013-09-27 Peak groundwater elevation 2014-06-01 Five new ch loroform pumping wells brought online ---=2#e lNTERA APPENDIX D Geochemical Analysis for pH in MW-31 Appendix D-1: pH Analysis Summary Table W p Normally or Lognormally distributed? S p Trend MW-31 pH 142 0 7.02 6.16 8.50 0.37 0.9616 0.0005 No -1605 0.0023 Decreasing Yes Notes: N = number of valid data points p = probability W = Shapiro Wilk test value S = Mann-Kendall statistic Shapiro-Wilk Test for Normality Significant Trend Mann Kendall Trend Analysis Standard DeviationWellConstituentN % Non- Detected Values Mean Minimum Maximum Appendix D Source Assessment Report for MW-31White Mesa Uranium Mill Appendix D-2: Field pH Measurements Used for pH Analysis Location ID Field Parameter Date Measured Field Measurement MW-31 pH 6/22/2005 7.27 MW-31 pH 9/22/2005 7.19 MW-31 pH 12/14/2005 7.30 MW-31 pH 3/22/2006 7.33 MW-31 pH 6/21/2006 7.15 MW-31 pH 9/13/2006 7.31 MW-31 pH 10/25/2006 7.26 MW-31 pH 3/15/2007 7.41 MW-31 pH 8/27/2007 7.08 MW-31 pH 10/24/2007 6.97 MW-31 pH 3/19/2008 6.95 MW-31 pH 6/3/2008 7.20 MW-31 pH 8/4/2008 7.20 MW-31 pH 11/10/2008 7.42 MW-31 pH 2/3/2009 7.30 MW-31 pH 5/13/2009 7.12 MW-31 pH 8/10/2009 7.34 MW-31 pH 8/24/2009 7.18 MW-31 pH 10/14/2009 7.05 MW-31 pH 12/2/2009 7.17 MW-31 pH 2/9/2010 6.96 MW-31 pH 4/20/2010 7.38 MW-31 pH 5/21/2010 6.95 MW-31 pH 6/15/2010 7.01 MW-31 pH 7/21/2010 7.80 MW-31 pH 8/24/2010 7.10 MW-31 pH 9/13/2010 7.66 MW-31 pH 9/21/2010 7.13 MW-31 pH 10/19/2010 6.92 MW-31 pH 11/9/2010 6.98 MW-31 pH 12/14/2010 6.95 MW-31 pH 1/10/2011 6.65 MW-31 pH 2/1/2011 7.21 MW-31 pH 3/14/2011 7.43 MW-31 pH 4/1/2011 7.01 MW-31 pH 5/10/2011 6.73 MW-31 pH 6/20/2011 6.16 MW-31 pH 7/5/2011 6.64 MW-31 pH 8/2/2011 6.67 MW-31 pH 9/6/2011 7.03 MW-31 pH 10/3/2011 7.28 MW-31 pH 11/8/2011 7.01 MW-31 pH 11/29/2011 7.34 MW-31 pH 12/12/2011 7.46 Appendix D Source Assessment Report for MW-31 White Mesa Uranium Mill Page 2 of 8 Appendix D-2: Field pH Measurements Used for pH Analysis Location ID Field Parameter Date Measured Field Measurement MW-31 pH 1/24/2012 6.78 MW-31 pH 2/13/2012 7.37 MW-31 pH 4/9/2012 7.14 MW-31 pH 5/2/2012 7.19 MW-31 pH 7/9/2012 7.53 MW-31 pH 8/6/2012 6.96 MW-31 pH 9/18/2012 7.10 MW-31 pH 10/22/2012 7.05 MW-31 pH 11/6/2012 7.04 MW-31 pH 12/18/2012 7.10 MW-31 pH 1/22/2013 6.90 MW-31 pH 2/19/2013 7.31 MW-31 pH 3/19/2013 7.22 MW-31 pH 4/16/2013 6.37 MW-31 pH 5/13/2013 7.92 MW-31 pH 6/24/2013 7.12 MW-31 pH 7/9/2013 6.98 MW-31 pH 8/19/2013 7.47 MW-31 pH 9/17/2013 7.09 MW-31 pH 10/23/2013 7.39 MW-31 pH 11/18/2013 6.99 MW-31 pH 12/17/2013 7.23 MW-31 pH 1/7/2014 7.11 MW-31 pH 2/17/2014 6.45 MW-31 pH 3/10/2014 6.53 MW-31 pH 4/28/2014 7.45 MW-31 pH 5/13/2014 6.83 MW-31 pH 6/2/2014 8.50 MW-31 pH 7/28/2014 6.92 MW-31 pH 8/18/2014 7.82 MW-31 pH 9/3/2014 7.11 MW-31 pH 10/6/2014 7.01 MW-31 pH 11/4/2014 6.69 MW-31 pH 12/9/2014 6.75 MW-31 pH 1/20/2015 6.47 MW-31 pH 2/2/2015 6.42 MW-31 pH 3/3/2015 6.35 MW-31 pH 4/7/2015 6.67 MW-31 pH 5/11/2015 6.74 MW-31 pH 6/1/2015 7.23 MW-31 pH 6/23/2015 7.15 MW-31 pH 7/6/2015 7.28 MW-31 pH 8/10/2015 6.80 MW-31 pH 9/15/2015 6.73 Appendix D Source Assessment Report for MW-31 White Mesa Uranium Mill Page 3 of 8 Appendix D-2: Field pH Measurements Used for pH Analysis Location ID Field Parameter Date Measured Field Measurement MW-31 pH 10/6/2015 6.47 MW-31 pH 11/9/2015 6.36 MW-31 pH 12/8/2015 6.70 MW-31 pH 1/19/2016 7.04 MW-31 pH 2/15/2016 7.27 MW-31 pH 3/2/2016 6.85 MW-31 pH 4/12/2016 6.93 MW-31 pH 5/3/2016 6.48 MW-31 pH 6/15/2016 7.09 MW-31 pH 7/12/2016 6.49 MW-31 pH 8/16/2016 6.92 MW-31 pH 9/13/2016 6.35 MW-31 pH 10/4/2016 7.05 MW-31 pH 11/1/2016 6.97 MW-31 pH 12/5/2016 6.80 MW-31 pH 1/17/2017 6.75 MW-31 pH 2/7/2017 6.20 MW-31 pH 3/6/2017 6.39 MW-31 pH 4/4/2017 6.16 MW-31 pH 5/1/2017 6.94 MW-31 pH 6/5/2017 6.96 MW-31 pH 7/11/2017 6.97 MW-31 pH 8/14/2017 6.29 MW-31 pH 9/11/2017 6.34 MW-31 pH 10/2/2017 7.01 MW-31 pH 11/1/2017 7.07 MW-31 pH 12/4/2017 7.54 MW-31 pH 1/24/2018 6.32 MW-31 pH 2/20/2018 7.35 MW-31 pH 3/5/2018 6.92 MW-31 pH 4/17/2018 6.75 MW-31 pH 5/14/2018 7.08 MW-31 pH 6/18/2018 7.21 MW-31 pH 7/23/2018 7.17 MW-31 pH 8/10/2018 7.02 MW-31 pH 9/10/2018 7.18 MW-31 pH 10/24/2018 6.59 MW-31 pH 11/13/2018 7.10 MW-31 pH 12/10/2018 7.03 MW-31 pH 1/15/2019 6.86 MW-31 pH 2/12/2019 6.24 MW-31 pH 3/5/2019 7.20 MW-31 pH 4/10/2019 7.30 MW-31 pH 5/7/2019 7.04 Appendix D Source Assessment Report for MW-31 White Mesa Uranium Mill Page 4 of 8 Appendix D-2: Field pH Measurements Used for pH Analysis Location ID Field Parameter Date Measured Field Measurement MW-31 pH 6/3/2019 7.04 MW-31 pH 7/15/2019 6.82 MW-31 pH 8/5/2019 7.44 MW-31 pH 9/23/2019 7.24 MW-31 pH 10/9/2019 7.23 MW-31 pH 11/12/2019 7.33 MW-31 pH 12/3/2019 7.30 MW-31 pH 1/14/2020 6.80 MW-31 pH 2/4/2020 7.24 MW-31 pH 3/10/2020 7.15 Appendix D Source Assessment Report for MW-31 White Mesa Uranium Mill Page 5 of 8 Appendix D-3: Box Plot for pH Appendix D Source Assessment Report for MW-31 White Mesa Uranium Mill Page 6 of 8 8.5 8.0 .-.. (j) ::: c:: 7.5 ::> I Q. -7.0 I Q. 6.5 pH in MW-31 0 0 Percent nondetect: 0% Min: 6.16, Mean: 7.02, Max: 8.5, Std Dev: 0.37 Upper extreme threshold (075 + 3xH): 8.505 Lower extreme threshold (025 -3xH): 5.53 ---=2#e lNTERA APPENDIX E Mass Balance in MW-31 Dilution Factors and Predicted Fluoride and Uranium Concentrations Fluoride Uranium Chloride Sulfate (mg/L) (ug/L)  (mg/L) (mg/L) MW‐31 concentration (04/06/2020) 0.632 15.5 376 1130 Cell 1 concentration (2003 ‐ 2019 average) 2240 398000 24217 169662 Dilution factor (DF) = Cmw31/Ccell1 2.82E‐04 3.89E‐05 1.55E‐02 6.66E‐03 Fluoride Based  on Uranium  Dilution Fluoride Based  on Chloride  Dilution Fluoride Based  on Sulfate  Dilution (mg/L) (mg/L) (mg/L) Predicted diluted fluoride (Ccell1 F x DF)_0.087 35 15 Fluoride Uranium Chloride Sulfate (mg/L) (ug/L)  (mg/L) (mg/L) MW‐31 concentration (04/06/2020) 0.632 15.5 376 1130 Cell 1 concentration (2003 ‐ 2019 average) 2240 398000 24217 169662 Dilution factor (DF) = Cmw31/Ccell1 2.82E‐04 3.89E‐05 1.55E‐02 6.66E‐03 Uranium  Based on  Fluoride  Dilution Uranium  Based on  Chloride  Dilution Uranium  Based on  Sulfate  Dilution (ug/L) (ug/L) (ug/L) Predicted diluted fluoride (Ccell1 U x DF)112 6,179 2,651 NOTES: C mw31  = latest concentration at MW‐31 C cell1  = average concentration in Cell 1 ug/L = micrograms per liter mg/L = milligrams per liter Appendix E  Source Assessment Report for MW‐31 White Mesa Uranium Mill APPENDIX F Flowsheet (Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site [INTERA, 2007a]) Negative Value? Zero Value? Truncated Value? Duplicate Value? Units Consistant? Non-detects Exceeding Criteria Specified by URS Memo* Analysis Internally Consistent?(TDS and Charge Balance Check) YesNo No Yes No No No Yes Yes No Yes Yes Yes Radionuclide? Yes Remove from DatasetDetection Limit and U-Flag Data Qualifier NoNo Review for Units Remove from Dataset If chloride, sulfate, or TDS, Remove from Dataset Correct Value Confirmed? Remove from Dataset Remove from Dataset Determine Percentage Non-Detects in Remaining Data Plot Data Sets as Box Plots to Identify Extreme Values As Specified in Background Report. Extreme Value? No Remove from Dataset Yes At Least 8 Data Points Remaining? Defer Analysis Until Eight Data Points Avalible 0-15 Percent Non-Detects >15-50 Percent Non-Detects >90 Percent Non-Detects No Yes No Substitute One Half of Detection Limit Log Transform Data Use Probability Plots to Determine if Cohen’s or Aitchison’s Method Calculate Descriptive Statistics (Redo Tables In Background Report) Screen for Trends Using Least Squares Regression. Calculate GWCL (Mean +2Sigma) Calculate Descriptive Statistics (Redo Tables In Background Report) Yes No Calculate GWCL (Mean +2Sigma) Calculate GWCL Using Greater of Fraction Approach under UAC R317-6-4-4.5(B)(2) or 4.6(B)(2) or Poisson Prediction Limit Yes No >50-90 Percent Non-Detects Calculate Upper Prediction Limit (Highest Historical Value) Calculate GWCL Using Greater of Fraction Approach under UAC R317-6-4-4.5(B)(2) or 4.6(B)(2) or the Highest Historic Value Estimate Mean and Standard Deviation Screen for Trends Using Mann-Kendall Screen for Trends Using Mann-Kendall Yes Use Non-Parametric StatisticsNo Screen for Trends Using Least Squares Regression Appendix F. Flowsheet Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site, San Juan County, Utah Upward Trend?Upward Trend? No No Yes Consider Modified Approch to GWCL Upward Trend?Upward Trend? No No Yes Consider Modified Approch to GWCL Log Transform Data Log-Normal or Normal?Shapiro WilkProbability PlotsHistograms Log-Normal or Normal?Shapiro WilkProbability PlotsHistograms *A non-detect considered “insensitive” will be the maximum reporting limit in a dataset and will exceed other non-detects by, for example, an order of magnitude (e.g., <10 versus <1.0 µg/L). In some cases, insensitive non-detects may also exceed detectable values in a dataset (e.g., <10 versus 3.5 µg/L). Database of Wells and Analytes Listed in the Statement of Basis APPENDIX G Flowsheet Analysis for Post-Inflection Data Appendix G-1: Descriptive Statistics for Modified GWCL Data Set and All Data Data Set GWCL Subset Post May 2014 GWCL Subset Post Sep. 2012 ALL 2020 SAR Data GWCL Subset Post May 2014 GWCL Subset Post Sep. 2012 ALL 2020 SAR Data Analyte Sulfate Sulfate Sulfate Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Units mg/L mg/L mg/L mg/L mg/L mg/L % Non-Detects 0 0 0 0 0 0 N 65 85 126 65 85 127 Distribution normal or lognormal Not normal or lognormal Not normal or lognormal Not normal or lognormal Not normal or lognormal Not normal or lognormal Mean 780 741 669 1776 1689 1555 Min. Conc.555 480 436 1400 1230 1150 Max. Conc.1150 1150 1150 2650 2650 2650 Std. Dev.145.8 148.2 160.9 288 300 314 Range 595 670 714 1250 1420 1500 Geometric Mean 768 728 652 1754 1665 1527 Skewness 0.80 0.93 1.04 1.00 1.04 1.18 Q25 668 639 537 1540 1480 1310 Median 748 691 640 1700 1580 1480 Q75 857 835 750 1980 1830 1705 ALL 2020 SAR Data = All data with extremes removed GWCL Subset Post 2012 = All data post September 2012 GWCL Subset Post 2014 = All data post May 2014 Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 1 of 13 Appendix G-2: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units MW-31 6/22/2005 Sulfate 504 mg/l MW-31 9/22/2005 Sulfate 436 mg/l MW-31 12/14/2005 Sulfate 509 mg/l MW-31 3/22/2006 Sulfate 485 mg/l MW-31 6/21/2006 Sulfate 522 mg/l MW-31 9/13/2006 Sulfate 516 mg/l MW-31 10/25/2006 Sulfate 526 mg/l MW-31 3/15/2007 Sulfate 516 mg/l MW-31 8/27/2007 Sulfate 532 mg/l MW-31 10/24/2007 Sulfate 497 mg/l MW-31 3/19/2008 Sulfate 521 mg/l MW-31 6/3/2008 Sulfate 514 mg/l MW-31 8/4/2008 Sulfate 499 mg/l MW-31 11/11/2008 Sulfate 541 mg/l MW-31 2/3/2009 Sulfate 488 mg/l MW-31 5/13/2009 Sulfate 493 mg/l MW-31 8/24/2009 Sulfate 460 mg/l MW-31 10/14/2009 Sulfate 497 mg/l MW-31 2/9/2010 Sulfate 507 mg/l MW-31 4/20/2010 Sulfate 522 mg/l MW-31 9/13/2010 Sulfate 527 mg/l MW-31 11/9/2010 Sulfate 539 mg/l MW-31 2/1/2011 Sulfate 538 mg/l MW-31 3/14/2011 Sulfate 531 mg/l MW-31 4/1/2011 Sulfate 503 mg/l MW-31 5/10/2011 Sulfate 512 mg/l MW-31 6/20/2011 Sulfate 540 mg/l MW-31 7/5/2011 Sulfate 532 mg/l MW-31 8/2/2011 Sulfate 537 mg/l MW-31 9/6/2011 Sulfate 541 mg/l MW-31 10/3/2011 Sulfate 539 mg/l MW-31 11/8/2011 Sulfate 552 mg/l MW-31 12/12/2011 Sulfate 530 mg/l MW-31 1/24/2012 Sulfate 539 mg/l MW-31 2/13/2012 Sulfate 538 mg/l MW-31 3/13/2012 Sulfate 517 mg/l MW-31 4/9/2012 Sulfate 547 mg/l MW-31 5/2/2012 Sulfate 532 mg/l MW-31 6/18/2012 Sulfate 497 mg/l MW-31 7/9/2012 Sulfate 529 mg/l MW-31 8/6/2012 Sulfate 571 mg/l MW-31 9/18/2012 Sulfate 561 mg/l MW-31 10/22/2012 Sulfate 545 mg/l MW-31 11/6/2012 Sulfate 557 mg/l MW-31 12/18/2012 Sulfate 664 mg/l Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 2 of 13 Appendix G-2: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units MW-31 1/22/2013 Sulfate 611 mg/l MW-31 2/19/2013 Sulfate 644 mg/l MW-31 3/19/2013 Sulfate 611 mg/l MW-31 4/16/2013 Sulfate 668 mg/l MW-31 5/13/2013 Sulfate 630 mg/l MW-31 6/24/2013 Sulfate 659 mg/l MW-31 7/9/2013 Sulfate 659 mg/l MW-31 8/19/2013 Sulfate 656 mg/l MW-31 9/17/2013 Sulfate 666 mg/l MW-31 10/23/2013 Sulfate 637 mg/l MW-31 11/18/2013 Sulfate 609 mg/l MW-31 12/17/2013 Sulfate 656 mg/l MW-31 1/7/2014 Sulfate 558 mg/l MW-31 2/17/2014 Sulfate 480 mg/l MW-31 3/10/2014 Sulfate 681 mg/l MW-31 4/28/2014 Sulfate 527 mg/l MW-31 5/13/2014 Sulfate 639 mg/l MW-31 6/2/2014 Sulfate 555 mg/l MW-31 7/28/2014 Sulfate 600 mg/l MW-31 8/18/2014 Sulfate 620 mg/l MW-31 9/3/2014 Sulfate 560 mg/l MW-31 10/6/2014 Sulfate 606 mg/l MW-31 11/4/2014 Sulfate 639 mg/l MW-31 12/9/2014 Sulfate 687 mg/l MW-31 1/20/2015 Sulfate 669 mg/l MW-31 2/2/2015 Sulfate 623 mg/l MW-31 3/3/2015 Sulfate 616 mg/l MW-31 4/7/2015 Sulfate 642 mg/l MW-31 5/11/2015 Sulfate 668 mg/l MW-31 6/23/2015 Sulfate 691 mg/l MW-31 7/6/2015 Sulfate 684 mg/l MW-31 8/10/2015 Sulfate 640 mg/l MW-31 9/15/2015 Sulfate 638 mg/l MW-31 10/6/2015 Sulfate 655 mg/l MW-31 11/9/2015 Sulfate 646 mg/l MW-31 12/8/2015 Sulfate 690 mg/l MW-31 1/19/2016 Sulfate 675 mg/l MW-31 2/15/2016 Sulfate 631 mg/l MW-31 3/2/2016 Sulfate 654 mg/l MW-31 4/12/2016 Sulfate 715 mg/l MW-31 5/3/2016 Sulfate 699 mg/l MW-31 6/15/2016 Sulfate 748 mg/l MW-31 7/12/2016 Sulfate 712 mg/l MW-31 8/16/2016 Sulfate 766 mg/l MW-31 9/13/2016 Sulfate 703 mg/l MW-31 10/4/2016 Sulfate 720 mg/l Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 3 of 13 Appendix G-2: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units MW-31 11/1/2016 Sulfate 752 mg/l MW-31 12/5/2016 Sulfate 748 mg/l MW-31 1/17/2017 Sulfate 809 mg/l MW-31 2/7/2017 Sulfate 751 mg/l MW-31 3/6/2017 Sulfate 741 mg/l MW-31 4/4/2017 Sulfate 758 mg/l MW-31 5/1/2017 Sulfate 741 mg/l MW-31 6/5/2017 Sulfate 808 mg/l MW-31 7/11/2017 Sulfate 747 mg/l MW-31 8/14/2017 Sulfate 916 mg/l MW-31 9/11/2017 Sulfate 762 mg/l MW-31 10/2/2017 Sulfate 823 mg/l MW-31 11/1/2017 Sulfate 847 mg/l MW-31 12/4/2017 Sulfate 825 mg/l MW-31 1/24/2018 Sulfate 813 mg/l MW-31 2/20/2018 Sulfate 835 mg/l MW-31 4/17/2018 Sulfate 857 mg/l MW-31 6/18/2018 Sulfate 976 mg/l MW-31 7/23/2018 Sulfate 857 mg/l MW-31 8/10/2018 Sulfate 841 mg/l MW-31 9/10/2018 Sulfate 893 mg/l MW-31 10/24/2018 Sulfate 950 mg/l MW-31 11/13/2018 Sulfate 841 mg/l MW-31 12/10/2018 Sulfate 905 mg/l MW-31 1/15/2019 Sulfate 851 mg/l MW-31 2/12/2019 Sulfate 893 mg/l MW-31 3/5/2019 Sulfate 953 mg/l MW-31 4/10/2019 Sulfate 917 mg/l MW-31 7/15/2019 Sulfate 1150 mg/l MW-31 10/9/2019 Sulfate 1010 mg/l MW-31 11/12/2019 Sulfate 990 mg/l MW-31 12/3/2019 Sulfate 1020 mg/l MW-31 1/14/2020 Sulfate 1120 mg/l MW-31 2/4/2020 Sulfate 1150 mg/l MW-31 3/10/2020 Sulfate 1080 mg/l MW-31 6/22/2005 Total Dissolved Solids 1290 mg/l MW-31 9/22/2005 Total Dissolved Solids 1280 mg/l MW-31 12/14/2005 Total Dissolved Solids 1290 mg/l MW-31 3/22/2006 Total Dissolved Solids 1280 mg/l MW-31 6/21/2006 Total Dissolved Solids 1300 mg/l MW-31 9/13/2006 Total Dissolved Solids 1320 mg/l MW-31 10/25/2006 Total Dissolved Solids 1220 mg/l MW-31 3/15/2007 Total Dissolved Solids 1280 mg/l MW-31 8/27/2007 Total Dissolved Solids 1240 mg/l MW-31 10/24/2007 Total Dissolved Solids 1150 mg/l MW-31 3/19/2008 Total Dissolved Solids 1220 mg/l Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 4 of 13 Appendix G-2: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units MW-31 6/3/2008 Total Dissolved Solids 1180 mg/l MW-31 8/4/2008 Total Dissolved Solids 1240 mg/l MW-31 11/11/2008 Total Dissolved Solids 1220 mg/l MW-31 2/3/2009 Total Dissolved Solids 1210 mg/l MW-31 5/13/2009 Total Dissolved Solids 1230 mg/l MW-31 8/24/2009 Total Dissolved Solids 1230 mg/l MW-31 12/2/2009 Total Dissolved Solids 1160 mg/l MW-31 2/9/2010 Total Dissolved Solids 1150 mg/l MW-31 4/20/2010 Total Dissolved Solids 1220 mg/l MW-31 9/13/2010 Total Dissolved Solids 1330 mg/l MW-31 11/9/2010 Total Dissolved Solids 1320 mg/l MW-31 1/10/2011 Total Dissolved Solids 1240 mg/l MW-31 2/1/2011 Total Dissolved Solids 1220 mg/l MW-31 3/14/2011 Total Dissolved Solids 1250 mg/l MW-31 4/1/2011 Total Dissolved Solids 1370 mg/l MW-31 5/10/2011 Total Dissolved Solids 1290 mg/l MW-31 6/20/2011 Total Dissolved Solids 1330 mg/l MW-31 7/5/2011 Total Dissolved Solids 1280 mg/l MW-31 8/2/2011 Total Dissolved Solids 1300 mg/l MW-31 9/6/2011 Total Dissolved Solids 1300 mg/l MW-31 10/3/2011 Total Dissolved Solids 1320 mg/l MW-31 11/8/2011 Total Dissolved Solids 1290 mg/l MW-31 12/12/2011 Total Dissolved Solids 1330 mg/l MW-31 1/24/2012 Total Dissolved Solids 1360 mg/l MW-31 2/13/2012 Total Dissolved Solids 1240 mg/l MW-31 3/13/2012 Total Dissolved Solids 1400 mg/l MW-31 4/9/2012 Total Dissolved Solids 1380 mg/l MW-31 5/2/2012 Total Dissolved Solids 1410 mg/l MW-31 6/29/2012 Total Dissolved Solids 1460 mg/l MW-31 7/9/2012 Total Dissolved Solids 1400 mg/l MW-31 8/6/2012 Total Dissolved Solids 1400 mg/l MW-31 9/18/2012 Total Dissolved Solids 1460 mg/l MW-31 10/22/2012 Total Dissolved Solids 1320 mg/l MW-31 11/6/2012 Total Dissolved Solids 1230 mg/l MW-31 12/18/2012 Total Dissolved Solids 1270 mg/l MW-31 1/22/2013 Total Dissolved Solids 1270 mg/l MW-31 2/19/2013 Total Dissolved Solids 1390 mg/l MW-31 3/19/2013 Total Dissolved Solids 1420 mg/l MW-31 4/16/2013 Total Dissolved Solids 1260 mg/l MW-31 5/13/2013 Total Dissolved Solids 1540 mg/l MW-31 6/24/2013 Total Dissolved Solids 1380 mg/l MW-31 7/9/2013 Total Dissolved Solids 1510 mg/l MW-31 8/19/2013 Total Dissolved Solids 1440 mg/l MW-31 9/17/2013 Total Dissolved Solids 1500 mg/l MW-31 10/23/2013 Total Dissolved Solids 1460 mg/l MW-31 11/18/2013 Total Dissolved Solids 1320 mg/l Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 5 of 13 Appendix G-2: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units MW-31 12/17/2013 Total Dissolved Solids 1500 mg/l MW-31 1/7/2014 Total Dissolved Solids 1510 mg/l MW-31 2/17/2014 Total Dissolved Solids 1460 mg/l MW-31 3/10/2014 Total Dissolved Solids 1490 mg/l MW-31 4/28/2014 Total Dissolved Solids 1440 mg/l MW-31 5/13/2014 Total Dissolved Solids 1510 mg/l MW-31 6/2/2014 Total Dissolved Solids 1520 mg/l MW-31 7/28/2014 Total Dissolved Solids 1400 mg/l MW-31 8/18/2014 Total Dissolved Solids 1410 mg/l MW-31 9/3/2014 Total Dissolved Solids 1460 mg/l MW-31 10/6/2014 Total Dissolved Solids 1420 mg/l MW-31 11/4/2014 Total Dissolved Solids 1520 mg/l MW-31 12/9/2014 Total Dissolved Solids 1450 mg/l MW-31 1/20/2015 Total Dissolved Solids 1540 mg/l MW-31 2/2/2015 Total Dissolved Solids 1520 mg/l MW-31 3/3/2015 Total Dissolved Solids 1530 mg/l MW-31 4/7/2015 Total Dissolved Solids 1680 mg/l MW-31 5/11/2015 Total Dissolved Solids 1700 mg/l MW-31 6/23/2015 Total Dissolved Solids 1630 mg/l MW-31 7/6/2015 Total Dissolved Solids 1440 mg/l MW-31 8/10/2015 Total Dissolved Solids 1530 mg/l MW-31 9/15/2015 Total Dissolved Solids 1480 mg/l MW-31 10/6/2015 Total Dissolved Solids 1540 mg/l MW-31 11/9/2015 Total Dissolved Solids 1460 mg/l MW-31 12/8/2015 Total Dissolved Solids 1580 mg/l MW-31 1/19/2016 Total Dissolved Solids 1560 mg/l MW-31 2/15/2016 Total Dissolved Solids 1490 mg/l MW-31 3/2/2016 Total Dissolved Solids 1580 mg/l MW-31 4/12/2016 Total Dissolved Solids 1710 mg/l MW-31 5/3/2016 Total Dissolved Solids 1550 mg/l MW-31 6/15/2016 Total Dissolved Solids 1580 mg/l MW-31 7/12/2016 Total Dissolved Solids 1610 mg/l MW-31 8/16/2016 Total Dissolved Solids 1710 mg/l MW-31 9/13/2016 Total Dissolved Solids 1570 mg/l MW-31 10/4/2016 Total Dissolved Solids 1670 mg/l MW-31 11/1/2016 Total Dissolved Solids 1690 mg/l MW-31 12/5/2016 Total Dissolved Solids 1670 mg/l MW-31 1/17/2017 Total Dissolved Solids 1730 mg/l MW-31 2/7/2017 Total Dissolved Solids 1680 mg/l MW-31 3/6/2017 Total Dissolved Solids 1690 mg/l MW-31 4/4/2017 Total Dissolved Solids 1660 mg/l MW-31 5/1/2017 Total Dissolved Solids 1820 mg/l MW-31 6/5/2017 Total Dissolved Solids 1710 mg/l MW-31 7/11/2017 Total Dissolved Solids 1830 mg/l MW-31 8/14/2017 Total Dissolved Solids 1780 mg/l MW-31 9/11/2017 Total Dissolved Solids 1780 mg/l Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 6 of 13 Appendix G-2: MW-31 Data Used for Analysis Well Date Sampled Parameter Name Report Result Report Units MW-31 10/2/2017 Total Dissolved Solids 1760 mg/l MW-31 11/1/2017 Total Dissolved Solids 1770 mg/l MW-31 12/4/2017 Total Dissolved Solids 1910 mg/l MW-31 1/24/2018 Total Dissolved Solids 1800 mg/l MW-31 2/20/2018 Total Dissolved Solids 1930 mg/l MW-31 4/17/2018 Total Dissolved Solids 1980 mg/l MW-31 6/18/2018 Total Dissolved Solids 2010 mg/l MW-31 7/23/2018 Total Dissolved Solids 2000 mg/l MW-31 8/10/2018 Total Dissolved Solids 1980 mg/l MW-31 9/10/2018 Total Dissolved Solids 2100 mg/l MW-31 10/24/2018 Total Dissolved Solids 2000 mg/l MW-31 11/13/2018 Total Dissolved Solids 1960 mg/l MW-31 12/10/2018 Total Dissolved Solids 2090 mg/l MW-31 1/15/2019 Total Dissolved Solids 2030 mg/l MW-31 2/12/2019 Total Dissolved Solids 2090 mg/l MW-31 3/5/2019 Total Dissolved Solids 2160 mg/l MW-31 4/10/2019 Total Dissolved Solids 2080 mg/l MW-31 7/15/2019 Total Dissolved Solids 2580 mg/l MW-31 10/9/2019 Total Dissolved Solids 2280 mg/l MW-31 11/12/2019 Total Dissolved Solids 2650 mg/l MW-31 12/3/2019 Total Dissolved Solids 2030 mg/l MW-31 1/14/2020 Total Dissolved Solids 2220 mg/l MW-31 2/4/2020 Total Dissolved Solids 2240 mg/l MW-31 3/10/2020 Total Dissolved Solids 2380 mg/l Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 7 of 13 Appendix G‐3: Box Plots Sulfate in MW-31 for All data Sulfate in MW-31 Post September 2012 Sulfate in MW-31 Post May 2014 Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 8 of 13 Appendix G‐3: Box Plots Total Dissolved Solids in MW-31 Post May 2014 Total Dissolved Solids in MW-31 for All data Total Dissolved Solids in MW-31 Post September 2012 Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 9 of 13 Appendix G‐4: Histograms Sulfate in MW-31 for All data Sulfate in MW-31 Post September 2012 Sulfate in MW-31 Post May 2014 Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 10 of 13 Appendix G‐4: Histograms Total Dissolved Solids in MW-31 for All data Total Dissolved Solids in MW-31 Post September 2012 Total Dissolved Solids in MW-31 Post May 2014 Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 11 of 13 Appendix G‐5: Linear Regression Analysis Sulfate in MW-31 for All data Sulfate in MW-31 Post September 2012 Sulfate in MW-31 Post May 2014 Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 12 of 13 Appendix G‐5: Linear Regression Analysis Total Dissolved Solids in MW-31 for All data Total Dissolved Solids in MW-31 Post September 2012 Total Dissolved Solids in MW-31 Post May 2014 Appendix G Source Assessment Report for MW-31 White Mesa Uranium Mill Page 13 of 13 APPENDIX H Input and Output Files (Electronic Only)