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HomeMy WebLinkAboutDRC-2018-002770 - 0901a068807d2758State of Utah GARYR. HERBERT Governor SPENCERJ. COX Lieutenant Goyernor TO: THROUGH: FROM: DATE: Department of Environmental Quality Alan Matheson Execative Direclor DTVISION OF WASTE MANAGEMENT AND RADIATION CONTROL Scott T. Anderson Director MEMORANDUM File PhirGobre,Manager PfZ C '/'/f romRushins,P.c. Xd 3' h - ts March 14,2018 SUBJECT: Review of the Energy Fuels Resources (USA) Inc. (EFR), White Mesa Uranium Mill, Blanding, Utah August2l,2017 Source Assessment Report for Selenium, Sulfate, Total Dissolved Solids (TDS) and Uranium in Monitoring Well MW-31, Ground Water Discharge Permit UGW3 70004 Summarv An August 21,2017 Source Assessment Report ('SAR') for Selenium, Sulfate, TDS and Uranium in Monitoring Well MW-31 at the White Mesa Uranium Mill (MilD was submitted to the Director by Energy Fuels Resources (USA) Inc. ("EFR"), and received on August23,2017 for review and approval of proposed revised Ground Water Compliance Limits (GWCLs). Monitoring well MW-31 is located on the southeast berm of the Mill tailings cell 2 and is hydraulically downgradient from eastern portions of cell 2 and from the Mill processing areas. MW-31 is within the defined nitrate/chloride plume, and non-compliance for nitrate and chloride are regulated through a separate consent order (UGW|2-04) issued by the Director. The SAR is broken up into four primary sections, 1. The approach for analysis of potential sources of the contamination, 2. Results of the analysis (e.g. changes in groundwater in MW-31, indicator parameter analysis, pH analysis, sorption analysis and mass balance analysis), 3. Statistical evaluation and calculation of revised GWCL's for trending parameters, and,4. Conclusions and recommendations. The SAR notes that though uranium is the only parameter required for assessment (in out-of-compliance status) by Part I.G.2 of the White Mesa Mill Groundwater Discharge Permit (Permit), the EFR SAR is additionally addressing exceedances of the recalculated GWCL's, noting that increasing trends are also observed for these parameters (Se, SO4, TDS). Figures below depict the rising concentration trends in monitoring well MW-31 for Se, SO4, TDS and U using all available historical data. An additional Figure depicts the pH plot for all historical data available for monitoring well MW-31 which shows a slight decreasing trend. EFR August21,20l7 MW-31 Source Assessment Report DWMRC Review Memo Page2 Figure - Selenium Data Plot of Historical Data at MW-31 - lncreasing Trend 100 J80 h0Eoo E ='E 40g ot^ 20 0 Jan-04 Oct-06 Jul{9 Apr-12 Dec-14 Sep-17 Jun-20 Date - Sulfate Data Plot of Historical Data at MW-31 - lncreasing Trend MW-31SO4 u0 Eo t! =Jlrl 1000 800 600 400 200 0 Jan-04 Oct-06 Jul{9 Apr-12 Dec-14 Sep-17 Jun-20 Figuqe,'''JD_IS Data Plot of Historical Data at MW-31 - lncreasing Trend MW-31TDS b rsooE E roooo(JI soo Oct-06 Jul-09 Apr-12 Dec-14 Sep-17 Jun-20 Sample Date EFR August2l,Z}l7 MW-31 Source Assessment Report DWMRC Review Memo Page 3 10 9 ing Trend Data Plot of Historical Data at MW-3l-Sli Decreasing Trend 8- =d- s- =-zf-t-fo.2- t- 0- Jan -04 Oct-06 Jul-09 Apr-72 Dec-14 Sep-17 Jun-20 Date Based on the increasing trends, EFR is proposing that the use of higher GWCL's allowed by the Utah Administrative Code R-317-6 should be considered and are in conformance with the Director approved statistical flow chart for GWCL's. Conclusions of the SAR find that the GWCL exceedances and increasing trends are not caused by releases from the Mill as discussed below. EFR Investieations of Potential Sources of Report Increasine Trends at Monitorins Well IVIW-31 1. Changes in Mill Groundwater Operations Section 3.1 and time series plots included as Appendix C-10 of the SAR discuss several Mill operational and environmental changes that appear to be consistent with data inflections seen on the time series plots. Specifically these changes are; 1. The initiation of monthly groundwater sampling in 2010; 2. A well redevelopment project in 201l; 3. A change in environmental laboratory used in2012;4. A peak groundwater elevation at MW-31 in20l3; and, 5. Five new chloroform wells brought online on the east side of Cell 2in20l4- Per DWMRC review of the time series plot it is observable that the trends in MW- 31 and at other sitewide monitoring wells appear to begin in late 2010 and 2011, during the time of initiation of increased frequency (monthly monitoring) and the well redevelopment project, which included Fisure - U Data Plot of Historical Data at MW-31 - Slieht Increas MW-3l Uranium uo E E Et!Lf 12.o0 10.00 8.00 6.00 4.00 2.00 0.00 Jan-04 Oct-06 Jul-09 Apr-12 Dec-14 Sep-17 Jun-20 EFR August2l,2}l7 MW-31 Source Assessment Report DWMRC Review Memo Page 4 overpumping all monitoring wells at the Mill. These actions may have introduced/allowed oxygen to enter pores within the sandstone and shales of formations in the well screened intervals and caused geochemical reactions within the minerals of those zones. Also, an inflection in certain monitoring analytes and wider scattering of data is clearly seen in 2012 whenthe analytical laboratory was changed. Per DWMRC findings regarding time series plots of data, the data inflection seen late 2012,for certain parameters indicates a shift in background concentrations due to the laboratory change. For parameters where this is observed in MW-31, and consistent with the EPA 2009 Unified Statistical Guidance, it is appropriate to use the data after this inflection to evaluate the background data. 2. Discussion of Tailings Solution Groundwater Indicator Parameters at Monitoring WeA MIV-31 The SAR Section 3.2 discusses four primary indicator parameters (Chloride, Fluoride, Sulfate and Uranium) which would be detected in ground water in the event of discharge from the Mill tailings cells. Mass balance evaluation comparisons at MW-31 included Fluoride and Sodium, as representative mobile contaminants for comparison with the study parameters (CL, Sulfate and Uranium). Piper diagrams evaluating chemical relationships of Cell I wastewater and observed groundwater concentrations are included in the SAR. Additionally, the SAR includes an evaluation of upgradient well data and downgradient well data in comparison with current data from MW-31. Based on this review, fluoride, sulfate and uranium concentrations in MW-31 are within the same background range of monitoring wells upgradient and far downgradient from the Mill. The evaluation confirms that chloride concentrations in MW-31 are well above background range, as expected, based on the MW-31 location within the nitrate/chloride plume. Chloride Per the SAR, the use of chloride as an indicator parameter in the case of monitoring well MW-3lis complicated by the fact that MW-31 is screened within a nitrate/chloride plume, and chloride is therefore above background and is not a reliable primary indicator of cell leakage for MW-31. Chloride at monitoring well MW-31 is showing a significant increasing trend. Findings related to comparisons of MW-31 chloride and background wells outside of the nitrate/chloride plume show chloride well outside of background range. The chloride plume has been delineated based on concentrations and plots clearly show that the plume leading edge is hydraulically upgradient from the mill tailings cells and is not attributed to tailings cell leakage based on groundwater flow data and mass balance calculations. Fluoride Fluoride is highly concentrated in tailings wastewater and per literature and mill groundwater transport modeling has been shown to be highly mobile in the vadose zofle and groundwater beneath the tailings cells. Per the figure below, fluoride is showing a decreasing concentration trend in MW-31. EFR August2l,2}l7 MW-31 Source Assessment Report DWMRC Review Memo Page 5 Fizure - Fluoride Plot of Historical Data at MW-31 - Decreasins Trend MW-3l Fluoride L.4 L.2 t (. o.sho Eu 0.6 o.4 o.2 0 Jan-04 Oct-06 Jul-09 Apr-t2 Dec-14 Sep-17 Jun-20 Mass balance calculations for fluoride are included in the SAR. Per presented findings the concentration of fluoride in groundwater when compared with less mobile constituents in tailings wastewater are much lower that less mobile constituents and additionally as per the figure above are declining. The SAR uses a comparison of selenium and fluoride in Cell 1 tailings wastewater and MW-31 groundwater and notes that selenium is found at much higher percentages in groundwater than fluoride. Fluoride concentrations should be over 20 times higher to indicate a relationship with tailings wastewater. SuAatu Sulfate concentrations in MW-31 are very low in comparison with other wells at the site. The highest historic value of sulfate is 916 mglL (2"d Quarter 2Ol7). This concentration is compared with highest historical values of other site monitoring wells (nearby MW-31) on the table below: The SAR additionally includes box plots comparing groundwater chemistry and concentration in all wells with MW-31. Per DWMRC review, the sulfate concentrations in MW-31 are low by comparison site wide. Sulfate concenfrations are rising at several of the monitoring wells at the mill including upgradient and far downgradient monitoring wells. EFR notes that the increasing sulfate in many wells and corresponds to Monitoring Well No.Location Relative to Tailings Cells Highest Historic Measured Sulfate Value (ms/L) Average Sulfate Concentration (Complete Data Set) (msll) Iv[$r€1 Bofimffidi&n*ti&ll'z 1;,;go.1f ;,;;$r*,t MW-l Uosradient 1.990 837 MW-l8 Upsradient 2.020 r.828 MW-19 Uperadient 1.320 669 MW-20 Far Downsradient 4,090 3,526 MW-03A Far Downmadient 5,940 3,568 MW-29 Downsradient Cells I and2 2.980 2704 MW-ll Downpradient Cells 2 and3 1.360 1.105 EFR August2l,2Al7 MW-31 Source Assessment Report DWMRC Review Memo Page 6 decreases in pH. Additionally, EFR offers this as a possible explanation for increases in some metals in solution at those corresponding wells, including uranium. In the case of MW-3 1, the relatively low concentration of sulfate indicates a source other than tailings solution. Additionally, a clear data shift is observed to have started in2012 in association with the change of laboratory. Uranium Uranium concentrations in monitoring well MW-31 are similar to sulfate concentrations in that site-wide they are low, as demonstrated by box plot evaluation comparing uranium concentration in MW-31 to all monitoring wells site wide. Box plot evaluation finds that the uranium concentrations in MW-31 are within background concentration range and are low for the mill site. The SAR discusses that rising uranium concentrations are likely associated with lower pH in the groundwater. Indicator parameters, other than chloride, are seen to have low site wide concentrations regardless of trends. Per SAR evaluations of ratios of the mobile contaminants in groundwater with the tailings wastewater concentrations, it appears that the source of the mobile contaminants is due to causes other than tailings wastewater. 3. pH Analysis Section 3.3 and Appendix D of the SAR include an evaluation of pH in MW-31. The analysis includes statistical evaluation (identification of outliers and trend analysis) which confirmed a significantly decreasing trend in pH in MW-31. EFR then conducted a site wide analysis for selenium trends (included as Appendix F of the SAR) and noted that 13 mill monitoring wells appear to have significantly increasing selenium trends. Of the 13 monitoring wells with increasing selenium trends, 10 have significantly decreasing pH trends. The SAR argues that the site wide distribution of pH declines and selenium increases links the reaction as related but not associated with mill activities or tailings wastewater. DWMRC review of upgradient wells (MW-l, MW-18 and MW-19) does confirm decreasing pH trends in all three monitoring wells, however, an increasing selenium trend is only observed in monitoring well MW-l9 and is probably due to the formation of a groundwater mound from infiltration from the wildlife ponds. Per review, it is agreed that in general, decreasing pH trends appear in select monitoring wells site wide, including far upgradient and far downgradient wells. The rising selenium and uranium concentrations in MW-31 may be related to decreases in pH. However, based on review of the SA& there does not appear to be a consistent site-wide correlation sufficient to generalize the sorption reactions for a group of monitoring wells. The Dakota/Buro canyon aquifer material is heterogeneous, as evidenced by drill logs and area geological investigation. Geochemical reactions will be dependent on minerology of discreet geological zones; this is recognized and is the basis of intrawell background and statistics at the White Mesa Mill. 4. Sorption Analysis Section 3.4 of the SAR provides a simple model, using Geochemist's Workbench (v. 11), of potential mineral sorption for MW-31. The SAR notes that iron oxides have been identified in most of the boring EFR Augustzl,2}l7 MW-31 Source Assessment Report DWMRC Review Memo Page 7 logs at White Mesa, and that per confirmation through X-Ray diffraction analysis of drill cuttings, "more iron is available than can be accountedfor by common crystalline iron phases such as goethite." The SAR questions some assumptions made in past geochemical modeling. Based on field readings of redox at MW-31, the groundwater is oxidized and pH has historically been in a neutral range. Based on these conditions it has been assumed that uranium and selenium are complexed with carbonate or oxygen and that uranium and selenium concentrations should decrease with decreasing pH. However, the SAR states"these early models, however, sufferedfrom convergence issues such as charge inbalance." The SAR discusses that calcite is present in the bedrockat l%oto l4%o by weight and that the addition of calcium in modeling would allow for charge balance by calcium ions. The SAR geochemical model included calcium as an input. Uranium and selenium sorption curves (SAR Figure 3) generated by the Geochemist's Workbench model (Appendix I), indicates decreasing uranium and selenium sorption with decreasing pH, supporting the EFR view that increasing concentrations of Se and U in solution are associated with the decreasing pH in MW- 31. Per summary of the SAR findings, the decreased sorption of selenium and uranium is due to other prevalent anions (HCOj and SOa2-) occupying sorption sites blocking sorption of selenium and uranium. The SAR discusses that several assumptions were made when using input values into *re model and that the Geochemist's Workbench is a simplistic model. Per review, the modeling demonstrates that calcite has a potential effect of inhibiting selenium and uranium sorption. However, additional analysis would need to be conducted to confirm that this is the case at specific locations including batch testing to determine the impact of specific variables for more representative geochemical modeling (e.g. pH, time, presence and absence of oxygen, presence of additional minerals, etc.). 5. Mass Balance The SAR includes a mass balance evaluation of current concentrations (5/2017) of fluoride, uranium, chloride, sulfate, selenium and sodium in MW-31, and average concentrations of the same paftrmeters in cell I wastewater (based on averages of data collected between 2003 and 2016). The SAR clarifies that the mass balance calculations evaluate the data only for comparisons due to dilution and do not consider relative mobility of contaminants. Based on large inconsistencies between the tailings wastewater concentrations and the expected diluted concentrations, the SAR concludes that "modeled parameter concentrations in MW-31 differ greatlyfrom observed concentrations ofJluoride in MW-31." Per review, the analysis indicates that the groundwater concentrations of these parameters in MW-31 are not consistent with a tailings source. DWMRC review conducted an additional dilution based evaluation using slimes drain concentrations of Cell2. DWMRC calculations regarding the same method to calculate mean Cell 2 concentrations (data from the Cell2 slimes drpin) from20A7 1.o2016 are included on the table below: EFR AugustZl,2Al7 MW-31 Source Assessment Report DWMRC Review Memo Page 8 Units Fluoride Uranium Chloride Sulfate Selenium Sodium MW-31 Concentration 5DA17 pg/L 690 9.62 2.658+05 7.418+05 85.2 1.05E+05 Cell2 Concentration Slimes Drain Average (2007- 2016) pelL 74"000 27,773 3.5E+06 6.78+07 699 4.38+06 Dilution Factor ILs./L 0.00932432 .0003463795 .0757142857 .0110s9701s .1218884t2 .0239726027 Predicted Diluted Fluoride $slL 2s6 5,603 8r8 9,020 3.088+06 It was noted that a similar result of the SAR analysis using Cell I was obtained. Chloride, sulfate and selenium were underestimated and uranium was overestimated. Per evaluation it was noted that sulfate concentrations are in line with fluoride based on Cell2 slimes drain concentrations and concentrations seen in MW-31, however, the fact that fluoride concentrations are decreasing while sulfate is increasing negates this relationship as due to a tailings source. If tailings wastewater were the source, uranium concentrations would be expected to be considerably higher and selenium concentrations considerably higher. The table below summarizes the evaluation and includes lines indicating current May 2017 concenfations of fluoride, uranium, chloride, sulfate and selenium, and expected concentrations of uranium, chloride, sulfate, and selenium compared to fluoride if there was a release using the fluoride dilution factor for each parameter: The mass balance (dilution) evaluation results indicate that the source of the increasing trends is not the result of tailings wastewater release. 6. University of Utah Study Monitoring well MW-31 was included in a University of Utah study conducted at the White Mesa Uranium Mill during 2007 (Final Report of Study Findings Dated May, 2008). Based on groundwater age dating at monitoring well MW-31 [chlorofluorocarbon ("CFC') analysis], the groundwater was found to exhibit CFC recharge dates which predate the construction of the Mill in 1980. Additionally, tritium concentrations in monitoring well MW-31 were found to be non-detect. If ground water in monitoring well MW-31 had a surface infiltration source post 1950's (time period of atrnospheric injection of tritium during above-ground thermonuclear weapons testing) then tritium concentrations would be expected in ground water samples in monitoring well MW-31. Figure 5 below is taken from the Units Fluoride Uranium Chloride Sulfate Selenium Sodium MW-31 Mav 2017 Concentrations uslL 690 9.62 2.65F+05 7.41E+05 85.2 1.05E+05 Mass balance concentrations expected in the event ofa release from Cell 1 pe/L 690 191 9.65E+3 6.668+04 3.2 42.9 Mass balance concentrations expected in the event ofa release from the Cell2 Slimes Drain ttdL 690 258 3.2E+4 6.248+05 6.5 979 EFR August2l,2}l7 MW-31 Source Assessment Report DWMRC Review Memo Page 9 University of Utah ("U of U") Report (Hurst and Solomon 2008) and depicts atmospheric concentrations of tritium in the southwest by year. Based on review of the U of U Report and specific data results for monitoring well MW-31 age dating of groundwater at the well indicates that the MW-31 groundwater predates Mill construction. 7. Source Assessment Conclusions Section 3.6 of the SAR discusses the summary of results for evaluation of each of the SAR parameters at MW-31 (Se, SO4, TDS andU). Based on EFR evaluations and studies performed and discussed in the SA& and DWMRC review as discussed above, it appears that the Out of Compliance status (U) and rising trends (Se, SO4, TDS and U) are not due to wastewater release from the mill. EFRPronosed Modified GWCL Statistical Evaluation of Data: Based on DWMRC review of the SAR statistical analysis it was noted that analysis was conducted for the complete historic data set for MW-31 and for a post October 2012 data set. The complete data set showed normal or log normal distribution for uranium but not for selenium, sulfate or TDS. The modified data set did show normality for selenium, sulfate, TDS and uranium. Statistical methods used included; 1. Descriptive statistics for the complete and modified data sets; 2. Mean and Standard Deviation Calculation; 3. Shapiro-Wilk Test for normality; and,4. Mann-Kendall Trend Analysis (non-normally distributed data sets). Proposed GWCL'S were calculated based on Mean * 2 Standard Deviation, Highest Historical Value, Fraction of Groundwater Standard, and Background Mean Concentration times 1.5. The calculations and findings are summarized on a table in the SAR (Appendix B-1 of the SAR). Per the DWMRC approved statistical flow chart for the White Mesa Mill groundwater monitoring wells, it was noted that if an upward trend is apparent for an analyte then a modified approach should be considered. The modified approach should allow for a GWCL which considers the increasing concentrations. Based on this, EFR calculated GWCL's according to the Utah Groundwater Rules (Utah Figure 5 - Concentrations of Atmospheric Tritium in the Southwestern United States glr, tlll l^h* lrcrtq+F.oddt,tlan . . i'"8rfr ti.)ctl(y {i8rbd, " *..&rroilq$(atud)**-"FilSn{ar*r{eq EFR August2l,2017 MW-31 Source Assessment Report DWMRC Review Memo Page 10 Administrative Code R317-6) which allow maximums to be set according to Mean + 2 Standard Deviations, 0.5 times the GWQS (Class III Water), or 1.5 times the background concentration. DWMRC findings note that setting the GWCL at a maximum value for these parameters is reasonable, given that the wells will likely exceed a more conservative GWCL in a short period of time when considering the increasing trends. This is particularly the case for selenium and sulfate in MW-3lwhich have relatively stronger trends are present at higher concenhations. Selenium and sulfate additionally show a defined change in background data pre October 2012. Per the EPA 2009 Unified Statistical Guidance Section 5.3, and based on verification that the increases are due to background influences, it is appropriate to use the data collected after the point of inflection and therefore, GWCL's for selenium and sulfate will use the post 2012 data set. It should be noted that the difference between the post 2012 data set mean and the complete data set mean are not significantly different. The TDS time series plot does not show a clear point of inflection and the complete data set will be used. Since uranium GWCL is being reset based on the fraction of the GWQS, the specific data sets are not used except for comparisons. Therefore, when comparing the various calculated GWCL's it is found appropriate to set GWCL's for selenium and sulfate and TDS according to 1.5 times background for post 2012 data sets (Se and SO4) or the complete data set (TDS). Uranium will be set according to 0.5 times the GWQS. These values are in conformance with the approved statistical flow chart, the Utah Groundwater Rules, EPA Statistical Guidance and consider the increasing data trends. A cross review of EFR calculated mean concentrations for parameters using 1.5 X background was conducted as shown on the table below. Per evaluation, the EFR mean calculations are correct and are representative ofthe data set used for evaluation. Table - Comparison of EFR Background Data Set Mean Values in SAR with DWMRC Calculated Mean fbr Se. SO4 and'l'DS in MW Parameter EFR Calculated Mean DWMRC Calculated Mean MW-3l Selenium (Post Oct. 2012\ 79.6 pglL 80.0 pgll, MW-31 Sulfate (Post Oct.2012) 662mglL 665.1mgtL MW-3I TDS (Comolete Data Set) l42l mglL 1434 mglL The table below summarizes the EFR calculations and background rationale for the proposed modified GWCL's. EFR August2l,2Al7 MW-31 Source Assessment Report DWMRC Review Memo Page I 1 ,-3'able of EFR Proposed Revised GWCL for Selenium at Monitorins lTell MW-31: Well Number Parameter Current GV/CL EFR Proposed GWCL Revision Method to Determine GWCL DWMRC Finding-Is Proposed GWCL in Conformance with the Statistical Flow Chart? DWMRC Recommended Modified GWCL Based on SAR Review MW-31 Selenium 86.81 pgll,119.4 pglL 1.5 x Background of Post Oct. 2012Data Set Increasing Trend allows for modified approach on Flow Chart. Per UAC 317-6, Class III water is allowed to be calculated by 1.5 X Background. Per DWMRC Review of the Selenium Data the modified approach appears appropriate since an increasing trend is apparent. Use of the post Oct. 2012 data set is appropriate and in conformance with EPA guidance since a data shift is noted corresponding to laboratorv chanse. l19.a pgL MW-31 Sulfate 697.6mgtL 993 mgtL 1.5 X Background of Post Oct. 2072Data Set lncreasing Trend allows for modified approach on Flow Chart. Per UAC 317-6, Class III water is allowed to be calculated by 1.5 X Background. Per DWMRC Review of the Sulfate Data the modifi ed approach appeaxs appropriate. Use of the post Oct.2012 data set is appropriate and in conformance with EPA guidance since a data shift is noted corresponding to laboratorv chanse. 993 mglL MW-31 TDS 1700 mglL 2228mgtL 1.5 X Background of Complete Data Set lncreasing Trend allows for modified approach on Flow Chart. Per UAC 317-6, Class III water is allowed to be calculated by 1.5 X Background. Per DWMRC Review of the TDS Data the modified apDroach appears 2132mgll- EFR August2l,2}l7 MW-31 Source Assessment Report DWMRC Review Memo Page 12 Conclusions: Based on DWMRC review of the background statistics and confirmation that the proposed parameters for GWCL modifications are showing increasing trends not associated with contamination from the mill, it is appropriate to set GWCL's for these parameters at the maximum concenfrations per Utah Administrative Code (UAC) R317-6 for Class III groundwater. This review is consistent with the Director approved statistical flowchart which appreciates that a modified approach is appropriate for parameters showing statistically significant increasing trends. Based on review a letter will be sent to EFR of initial approval of the modified GWCL's on the table above. The letter will include notification that the modifications are subject to public notice and public participation requirements, and that the modifications will not be effective until formal issuance of a modified Permit. References ' Energy Fuels Resources (USA) Inc., August 20,2017, Transmittal of Source Assessment Report for Sulfate, Selenium, Total Dissolved Solids, and Uranium in MW-31 ll'hite Mesa Mill Groundwater D is char ge P ermit UGW3 7 0 0 0 4 'Energy Fuels Resources (USA) lnc., August 15,2017, White Mesa (Jrqnium Mill Ground Water Monitoring Quality Assurance Plan (QAP), Revision 7.3 3 Er"rgy Fuels Resources (USA) Inc., October 12,2012, Source Assessment Reporr, Prepared by Intera o Energy Fuels Resources (USA) Inc., November 9,2012, pH Report, Prepared by Intera Well Number Parameter Current GWCL EFR Proposed GWCL Revision Method to Determine GWCL DWMRC Finding- Is Proposed GWCL in Conformance with the Statistical Flow Chart? DWMRC Recommended Modified GWCL Based on SAR Review appropriate; however, there does not appear to be a well- defined data shift in Oct. 2012. Recalculated GWCL uses background of complete data set. MW-31 Uranium 9.1pelL 15 pe/L 0.5 x GWQS Increasing Trend allows for modified approach on Flow Chart. PeTUAC 317-6, Class III water is allowed to be calculated by 0.5 X the GWOS. ts pdL 0.5 x GWQS EFR August2l,2Al7 MW-31 Source Assessment Report DWMRC Review Memo Page l3 5 Hurst, T.G., and Solomon, D.K. University of Utah,2OO8, Summary of Work Completed, data Results, Interpretations and Recommendationsfor the July 2007 Sampling Event at the Denison Mines, USA White Mesa Uranium Mill Near Blanding, Utah, Prepared by Department of Geology and Geophysics uHydro Geo Chem, December 7,2012, Pyrite Investigation Report ' Inter4 2007, Groundwater Data Prepardtion and Statistical Process Flowfor Calculating Groundwater Protection Standards, White Mesa Mill Sile, San Juan County, Uah 'Utah Departrnent of Environmental Quality, August 24,2012, Utah Division of Radiation Control, Ground Water Dischorge Permit, Permit No. UGW37A004, Energt Fuels Resources (USA) Inc.