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Home My WebLink AboutDAQ-2024-004514 DAQE-IN101520030-23 December 14, 2023 Jeff Schmidt Northrop Grumman Systems Corporation 2211 West North Temple Salt Lake City, UT 84116 j.schmidt@ngc.com Dear Mr. Schmidt: Re: Intent to Approve: Modification to Approval Order DAQE-AN101520028-22 to Add Equipment and Change Ownership Project Number: N101520030 The attached document is the Intent to Approve (ITA) for the above-referenced project. The ITA is subject to public review. Any comments received shall be considered before an Approval Order (AO) is issued. The Division of Air Quality is authorized to charge a fee for reimbursement of the actual costs incurred in the issuance of an AO. An invoice will follow upon issuance of the final AO. Future correspondence on this ITA should include the engineer's name, Christine Bodell, as well as the DAQE number as shown on the upper right-hand corner of this letter. Christine Bodell, can be reached at (385) 290-2690 or cbodell@utah.gov, if you have any questions. Sincerely, {{$s }} Alan D. Humpherys, Manager New Source Review Section AFH:CB:jg cc: Davis County Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director STATE OF UTAH Department of Environmental Quality Division of Air Quality INTENT TO APPROVE DAQE-IN101520030-23 Modification to Approval Order DAQE-AN101520028-22 to Add Equipment and Change Ownership Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Northrop Grumman Systems Corporation - Clearfield Issued On December 14, 2023 {{$s }} New Source Review Section Manager Alan D. Humpherys {{#s=Sig_es_:signer1:signature}} TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 PUBLIC NOTICE STATEMENT............................................................................................... 5 SECTION I: GENERAL PROVISIONS .................................................................................... 5 SECTION II: PERMITTED EQUIPMENT .............................................................................. 6 SECTION II: SPECIAL PROVISIONS ..................................................................................... 9 PERMIT HISTORY ................................................................................................................... 14 ACRONYMS ............................................................................................................................... 15 DAQE-IN101520030-23 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Northrop Grumman Systems Corporation Northrop Grumman Systems Corporation - Clearfield Mailing Address Physical Address 2211 West North Temple Freeport Center 13th Street Salt Lake City, UT 84116 Clearfield, UT 84016 Source Contact UTM Coordinates Name Jeff Schmidt 414,000 m Easting Phone (801) 774-4171 4,550,000 m Northing Email j.schmidt@ngc.com Datum NAD83 UTM Zone 12 SIC code 3728 (Aircraft Parts & Auxiliary Equipment, NEC) SOURCE INFORMATION General Description Northrop Grumman Systems Corporation (Northrop) manufactures aerospace composite structures at their Freeport Center plant located in Clearfield, Davis County. Northrop manufactures composite components for the aerospace industry, specifically for commercial and defense contractors. General steps in the manufacturing process include the following: raw material receipt and storage, material and tool preparation, fabrication, curing, finishing, testing, and packaging and shipping. As part of these steps, Northrop uses natural gas-fired equipment including curing ovens, boilers, burners, hot rooms, autoclaves, and heated paint booths; operates dust collectors for control of various machining processes; has painting and welding operations; has various natural gas-fired and diesel-fired emergency generators; and has various laboratory and chemical mixing operations. NSR Classification Minor Modification at Minor Source Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA Davis County Airs Source Size: B Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines NSPS (Part 60), JJJJ: Standards of Performance for Stationary Spark Ignition Internal Combustion Engines DAQE-IN101520030-23 Page 4 MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines MACT (Part 63), WWWWWW: National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Plating and Polishing Operations Project Description Northrop has requested a modification to AO DAQE-AN101520028-22 to add one (1) electric oven and one (1) mandrel preparation room. Northrop has also requested a name change from "ATK Space Systems, LLC" (subsidiary of Northrop) to "Northrop Grumman Systems Corporation". The VOC and HAPs emission limitations outlined in the current AO will not be increasing as part of this modification. The new equipment will operate under existing emissions limitations. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 24245.00 Carbon Monoxide 0 16.38 Nitrogen Oxides 0 19.49 Particulate Matter - PM10 0 13.42 Particulate Matter - PM2.5 0 13.21 Sulfur Dioxide 0 0.15 Volatile Organic Compounds 0 69.00 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) 1,1,2-Trichloroethane (CAS #79005) 0 4000 2-(2-Butoxyethoxy)-Ethanol (CAS #112345) 0 4000 Chromium Compounds (CAS #CMJ500) 0 27 Cumene (CAS #98828) 0 4000 Ethyl Acrylate (CAS #140885) 0 4000 Ethyl Benzene (CAS #100414) 0 4000 Ethylene Glycol (CAS #107211) 0 4000 Formaldehyde (CAS #50000) 0 1000 Generic HAPs (CAS #GHAPS) 0 2000 Glycol Ethers (CAS #EDF109) 0 4000 Hexamethylene-1,6-Diisocyanate (CAS #822060) 0 14 Hexane (CAS #110543) 0 4000 Hydrogen Fluoride (Hydrofluoric Acid) (CAS #7664393) 0 20 Methanol (CAS #67561) 0 4000 Methyl Chloroform (1,1,1-Trichloroethane) (CAS #71556) 0 19000 Methyl Isobutyl Ketone (Hexone) (CAS #108101) 0 4000 Methyl Isocyanate (CAS #624839) 0 20 Methyl Methacrylate (CAS #80626) 0 200 Methylene Chloride (Dichloromethane) (CAS #75092) 0 4000 DAQE-IN101520030-23 Page 5 Methylene Diphenyl Diisocyanate (MDI) (CAS #101688) 0 20 Naphthalene (CAS #91203) 0 4000 Nickel Compounds (CAS #NDB000) 0 40 Phenol (CAS #108952) 0 4000 Styrene (CAS #100425) 0 200 Tetrachloroethylene (Perchloroethylene) (CAS #127184) 0 4000 Toluene (CAS #108883) 0 4000 Trichloroethylene (CAS #79016) 0 4000 Xylenes (Isomers And Mixture) (CAS #1330207) 0 4000 Change (TPY) Total (TPY) Total HAPs 0 45.27 PUBLIC NOTICE STATEMENT The NOI for the above-referenced project has been evaluated and has been found to be consistent with the requirements of UAC R307. Air pollution producing sources and/or their air control facilities may not be constructed, installed, established, or modified prior to the issuance of an AO by the Director. A 30-day public comment period will be held in accordance with UAC R307-401-7. A notification of the intent to approve will be published in the Ogden Standard Examiner on December 16, 2023. During the public comment period the proposal and the evaluation of its impact on air quality will be available for the public to review and provide comment. If anyone so requests a public hearing within 15 days of publication, it will be held in accordance with UAC R307-401-7. The hearing will be held as close as practicable to the location of the source. Any comments received during the public comment period and the hearing will be evaluated. The proposed conditions of the AO may be changed as a result of the comments received. SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] DAQE-IN101520030-23 Page 6 I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.A THE APPROVED EQUIPMENT II.A.1 Northrop Grumman Systems Corp Aerospace composite components manufacturing facility II.A.2 Five (5) Electric Curing Ovens Ovens: O-21; O-36; O-48 (New); O-159; O-160 Venting (all): Atmospheric II.A.3 Eleven (11) Natural Gas-Fired Ovens Oven: Rating: O-26 1.2 MMBtu/hr O-27 4.0 MMBtu/hr COV1 2.8 MMBtu/hr COV2 4.0 MMBtu/hr O-30 3.5 MMBtu/hr O-22 2.0 MMBtu/hr O-24 0.6 MMBtu/hr O-37 3.0 MMBtu/hr O-39 6.4 MMBtu/hr O-41 1.0 MMBtu/hr O-47 3.0 MMBtu/hr DAQE-IN101520030-23 Page 7 II.A.4 Seven (7) Hot Rooms Rooms: ACU253, AHU1, AHU2, AHU3, AHU4, HR1, HR3 Fuel (all): Natural Gas Maximum Rating: < 5.0 MMBtu/hr (each) II.A.5 One (1) Boiler- BO1 Fuel: Natural Gas Rating: 8.37 MMBtu/hr II.A.6 Three (3) Autoclaves Autoclave: Rating: AC1 12.0 MMBtu/hr AC6 24.3 MMBtu/hr AC12 15.0 MMBtu/hr Fuel (all): Natural Gas II.A.7 Five (5) Autoclaves Autoclaves: CAC1, CAC2, CAC3, CAC4, CAC5 Fuel (all): Natural Gas Rating: 15.8 MMBtu/hr (each) II.A.8 Twelve (12) Ventilation Rooms Ten Mandrel Prep Rooms (1 NEW); FX-141; Paint Touchup Room II.A.9 Eleven (11) Laboratory Hoods FUH-3; FUH-7; AT-401073; FUH-5; FUH-2; AT-401706; FE-200; FE-222; FUH-1; SB-2; 2228 II.A.10 Thirteen (13) Exhaust Hoods 1,2. Two Welding fume exhausters 3. RMS-6 4. Battery Charging area exhaust hood 5. MX-85 6. M-5 7. 83310J00475 8. E-145 Tacking Table 9. FX-105 10. FX-106 11. FE-655 12, 13. Two Paint mixing fume hoods II.A.11 Four (4) Heated Paint Booths Paint Booth: Heater Rating: SB10 750 KBtu/hr SB11 950 KBtu/hr SB12 950 KBtu/hr SB13 950 KBtu/hr Fuel (all): Natural Gas Control: Vacuum System (each) II.A.12 Six (6) Spray Booths SB7, SB9, SB5, SB14, IFE SB, Topcoat SB Control: Fabric Filters (each) DAQE-IN101520030-23 Page 8 II.A.13 One (1) Ceramics Spray Booth Control: High efficiency 3-stage fabric filters II.A.14 One (1) Thermal Spray Booth Control: Pulse jet baghouse (DC-58) Baghouse Maximum Flow Rate: 25,300 acfm MACT Applicability: Subpart WWWWWW II.A.15 Eight (8) Natural Gas-Fired Emergency Generators Engine: Rating: GE 3 7 kW GE 4 35 kW GE 5 100 kW GE 8 80 kW GE 9 240 kW GE 10 45 kW GE 11 45 kW GE 12 85 kW NSPS Applicability: Subpart JJJJ MACT Applicability: Subpart ZZZZ II.A.16 Two (2) Diesel-Fired Emergency Generators Engine: GE 7 Rating: 225 kW Engine: GE 13 Rating: 268 hp NSPS Applicability: Subpart IIII MACT Applicability: Subpart ZZZZ II.A.17 Eight (8) Dust Collectors DC-16, DC-27, DC-28, DC-29, DC-30, DC-36, DC-37, DC-38 II.A.18 Miscellaneous Equipment Miscellaneous vacuum pumps Miscellaneous Air compressors II.A.19 Miscellaneous Combustion Equipment Various Boilers and Heaters Maximum Rating: <5.0 MMBtu/hr Fuel: Natural Gas II.A.20 Eighteen (18) Wet Cooling Towers CT-6, CT-7, CT-9, CT-13, CT-14, CT-15, CT-16, CT-17, CT-18, CT-19, CT-20, CT-21, CT-22, CT-23, CT-24, CT-25, CT-26, CT-27 Controls: High Efficiency Drift Eliminators (each) DAQE-IN101520030-23 Page 9 II.A.21 Informational-Only Equipment* Nineteen (19) electrical sample curing ovens One (1) electrical Hot room Eight (8) electrical autoclaves One (1) Buffer room Miscellaneous Dust Collectors, including portable and orifice scrubbers Miscellaneous Machining Centers / Lathes / Cork Cutting Equipment One (1) Spray Gun Cleaning Station Miscellaneous Grit Blast and Abrading Equipment 3D Printers *This equipment does not vent to atmosphere and is listed for informational purposes only II.A.22 Informational-Only Equipment* (Continued) Three (3) Hot Drape Forming Machines One (1) Ductless Fume Hood Two (2) Reticulators Two (2) Dry Cooling Towers *This equipment does not vent to atmosphere and is listed for informational purposes only II.A.23 Grandfathered Equipment* Pit exhaust system Indirect gas fired curing oven - #20 Rating: 6 MMBtu/hr *This equipment was installed before 1969 and is listed for informational purposes only SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following emission points to exceed the following values: A. Diesel-fired emergency engines - 20% opacity B. All other emission points - 10% opacity. [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8] II.B.1.b The owner/operator shall not exceed a plant-wide natural gas consumption limit of 406,624 Decatherms per rolling 12-month period. [R307-401-8] DAQE-IN101520030-23 Page 10 II.B.1.b.1 The owner/operator shall: A. Determine consumption by gas billing records B. Record consumption on a monthly basis C. Use the consumption records to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep consumption records for all periods the plant is in operation. [R307-401-8] II.B.1.c The owner/operator shall comply with all applicable requirements of UAC R307-325 (Ozone Nonattainment and Maintenance Areas: General Requirements) and UAC R307-355 (Control of Emissions from Aerospace Manufacture and Rework Facilities). [R307-355] DAQE-IN101520030-23 Page 11 II.B.2 VOC & HAP Requirements II.B.2.a The owner/operator shall not emit more than the following from all sources on site: A. 69.00 tons per rolling 12-month period of VOCs B. 19.00 tons per rolling 12-month period of all HAPs combined C. 2.00 tons per rolling 12-month period of 2-Butoxyethanol D. 0.014 tons per rolling 12-month period of Chromium Compounds E. 2.00 tons per rolling 12-month period of Cumene F. 2.00 tons per rolling 12-month period of Ethyl Acrylate G. 2.00 tons per rolling 12-month period of Ethylbenzene H. 2.00 tons per rolling 12-month period of Ethylene Glycol I. 0.50 tons per rolling 12-month period of Formaldehyde J. 1.20 tons per rolling 12-month period of Generic HAPs K. 2.00 tons per rolling 12-month period of Glycol Ethers L. 0.007 tons per rolling 12-month period of Hexamethylene-1,6-Diisocyanate M. 2.00 tons per rolling 12-month period of Hexane N. 0.010 tons per rolling 12-month period of Hydrogen Fluoride O. 2.00 tons per rolling 12-month period of Methyl Alcohol P. 0.010 tons per rolling 12-month period of Methyl Isocyanate Q. 2.00 tons per rolling 12-month period of Methylene Chloride R. 0.10 tons per rolling 12-month period of Methylenedianiline S. 0.010 tons per rolling 12-month period of Methylene Diphenyl Diisocyanate T. 2.00 tons per rolling 12-month period of Methyl Isobutyl Ketone (MIBK) U. 2.00 tons per rolling 12-month period of Naphthalene DAQE-IN101520030-23 Page 12 V. 0.02 tons per rolling 12-month period of Nickel Compounds W. 2.00 tons per rolling 12-month period of Phenol X. 2.00 tons per rolling 12-month period of Tetrachloroethylene Y. 2.00 tons per rolling 12-month period of Toluene Z. 9.50 tons per rolling 12-month period of 1,1,1-Trichloroethane AA. 2.00 tons per rolling 12-month period of 1,1,2-Trichloroethane BB. 2.00 tons per rolling 12-month period of Trichloroethylene CC. 2.00 tons per rolling 12-month period of Xylene. [R307-401-8] II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed] [R307-401-8] II.B.2.a.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] II.B.2.a.3 The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and each HAP in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs and the amount of each HAP emitted from each material F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons). [R307-401-8] DAQE-IN101520030-23 Page 13 II.B.3 Paint Booth Requirements II.B.3.a The owner/operator shall equip each paint booth with paint arrestor particulate filters to control particulate emissions. All exhaust air from the paint booths shall be routed through the filters before venting to the atmosphere. [R307-401-8] II.B.3.b The paint booths shall be equipped with HVLP spray guns, or an equivalent method, to control VOC emissions. [R307-355-6] II.B.3.c The owner/operator shall control the thermal spray booth with a baghouse. [R307-401-8] II.B.3.d The owner/operator shall install a manometer or magnehelic pressure gauge to measure the differential pressure across the baghouse. The baghouse shall operate within the static pressure range recommended by the manufacturer for normal operations. [R307-401-8] II.B.3.d.1 Pressure drop readings shall be recorded at least once during each day of operation while the baghouse is operating. Records documenting the pressure drop shall be kept in a log and shall include the following: A. Unit identification B. Manufacturer-recommended pressure drop for the unit C. Daily pressure drop readings D. Date of reading. [R307-401-8] II.B.3.d.2 Each pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.d.3 The instrument shall be calibrated in accordance with the manufacturer's instructions or recommendations or replaced at least once every 12 months. Documentation of calibrations and replacements shall be maintained. [R307-401-8] II.B.4 Emergency Engine Requirements II.B.4.a The owner/operator shall not operate each emergency engine on site for more than 100 hours per calendar year during non-emergency situations. There is no time limit on the use of the engines during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.4.a.1 To determine compliance with a calendar year total, the owner/operator shall calculate a new yearly total by January 31st using data from the previous calendar year. Records documenting the operation of each emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used B. The duration of operation in hours C. The reason for the emergency engine usage. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.4.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour meter for each emergency engine. [40 CFR 63 Subpart ZZZZ, R307-401-8] DAQE-IN101520030-23 Page 14 II.B.5 Fuel Requirements II.B.5.a The owner/operator shall use only natural gas as a fuel in all fuel-burning furnaces, ovens, boilers, heaters, and natural gas-fired emergency engines. [R307-401-8] II.B.5.b The owner/operator shall only use diesel fuel (fuel oil #1, #2 or diesel fuel oil additives) in the diesel-fired emergency engines. All diesel burned shall meet the definition of ultra-low sulfur diesel (ULSD) and contain no more than 15 ppm sulfur. [R307-401-8] II.B.5.b.1 To demonstrate compliance with the diesel fuel requirements for any diesel fuel purchased, the owner/operator shall keep and maintain fuel purchase invoices. The fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements, or the owner/operator shall obtain certification of sulfur content from the fuel supplier. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN101520028-22 dated September 26, 2022 Is Derived From NOI dated December 21, 2022 Incorporates Additional Information dated October 26, 2023 DAQE-IN101520030-23 Page 15 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds Northrup Grumman Systems 10152 0030 - Page 1 of 2 FILER Jeree Greenwood jereeg@utah.gov (801) 536-4000 FILING FOR Standard-Examiner Columns Wide:1 Ad Class:Legals OFFICIAL AD PROOF T h i s is t he p r oo f o f yo ur ad sc he du l e d to r u n in S t an d a rd -E xa m i n e r o n t he d a te s in dic ate d be l ow. If c h a n ge s a r e ne ed ed , p l ea se co nt a ct us pr i o r to d ea dlin e a t (8 01 ) 6 25 -4 30 2. Notice ID: T7Jh7HUYGSwj5HMVqms4 | Proof Updated: Dec. 13, 2023 at 03:19pm MST Notice Name: Northrup Grumman Systems 10152 0030 | Publisher ID: UC0085 This is not an invoice. Below is an estimated price, and it is subject to change. You will receive an invoice with the final price upon invoice creation by the publisher. 12/16/2023: Custom Notice 390.22 Base Affidavit Fee 12.00 Subtotal $402.22 Tax $0.00 Processing Fee $40.22 Total $442.44 See Proof on Next Page Northrup Grumman Systems 10152 0030 - Page 2 of 2 DAQE-NN101520030-23 December 14, 2023 Ogden Standard Examiner Legal Advertising Department 332 Standard Way P.O. Box 12790 Ogden, Ut 84412 Acct # 100331 RE: Legal Notice of Intent to Approve This letter will confirm the authorization to publish the attached NOTICE in the Ogden Standard Examiner (Account Number: 100331) on December 16, 2023. Please mail the invoice and affidavit of publication to the Utah State Department of Environmental Quality, Division of Air Quality, P.O. Box 144820, Salt Lake City, Utah 84114-4820. If you have any questions, contact Jeree Greenwood, who may be reached at (385) 306-6514. Sincerely, {{$s }} Jeree Greenwood Office Technician Enclosure cc: Davis County cc: Wasatch Front Regional Council 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director DAQE-NN101520030-23 Page 2 NOTICE A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been received for consideration by the Director: Company Name: Northrop Grumman Systems Corporation Location: Northrop Grumman Systems Corporation - Clearfield – Freeport Center 13th Street, Clearfield, UT Project Description: Northrop Grumman Systems Corporation (Northrop) manufactures aerospace composite structures at their Freeport Center plant located in Clearfield, Davis County. Northrop manufactures composite components for the aerospace industry, specifically for commercial and defense contractors. General steps in the manufacturing process include the following: raw material receipt and storage, material and tool preparation, fabrication, curing, finishing, testing, and packaging and shipping. As part of these steps, Northrop uses natural gas-fired equipment including curing ovens, boilers, burners, hot rooms, autoclaves, and heated paint booths; operates dust collectors for control of various machining processes; has painting and welding operations; has various natural gas-fired and diesel-fired emergency generators; and has various laboratory and chemical mixing operations. Northrop has requested a modification to Approval Order DAQE-AN101520028- 22 to add one (1) electric oven and one (1) mandrel preparation room. Northrop has also requested a name change from "ATK Space Systems, LLC" (subsidiary of Northrop) to "Northrop Grumman Systems Corp". The Volatile organic compounds and Hazardous air pollutant(s) emission limitations outlined in the current Approval Order will not be increasing as part of this modification. The new equipment will operate under existing emissions limitations. The completed engineering evaluation and air quality impact analysis showed the proposed project meets the requirements of federal air quality regulations and the State air quality rules. The Director intends to issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the effect on local air quality and draft Approval Order are available for public inspection and comment at the Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments received by the Division at this same address on or before January 15, 2024 will be considered in making the final decision on the approval/disapproval of the proposed project. Email comments will also be accepted at cbodell@utah.gov. If anyone so requests to the Director in writing within 15 days of publication of this notice, a hearing will be held in accordance with R307-401-7, UAC. Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or argument during an adjudicatory proceeding that was raised during the public comment period and was supported with sufficient information or documentation to enable the Director to fully consider the substance and significance of the issue. Date of Notice: December 16, 2023 {{#s=Sig_es_:signer1:signature}} \___._, ', State of Utah SPENCER J. COX (iivemor DEIDRE HENDERSON I lt'IltCI1,IIO (h,scrnn,r December 6, 2023 Jeff Schmidt Northrop Grumman Systems Corporation 2211 West North Temple Salt Lake City, UT 84116 j.schmidt@ngc.com Dear Jeff Schmidt, Re: Engineer Review: RN 101520030 Modification to Approval Order DAQE-AN101520028-22 to Add Equipment and Change Ownership Project Number: N 101520030 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review permitting program. Northrop Grumman Systems Corporation should complete this review within 10 business days of receipt. Northrop Grumman Systems Corporation should contact Christine Bodell at (385) 290-2690 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Christine Bodell at cbodell@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an hA for a 30-day public comment period. At the completion of the comment period, the DAQ will address any comments and will prepare an Approval Order (AO) for signature by the DAQ Director. If Northrop Grumman Systems Corporation does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Northrop Grumman Systems Corporation has concerns that cannot be resolved and the project becomes stagnant, the DAO,.Director may issue an Order prohibiting construction. ii Approval Signature ff / (Signature & Date) Department of Environmental Quality Kimberly I). Shelley Executive Director DIVISION OF AIR QUALITY BtyceC Bird 195 North 19511 Went. Salt Lake City. UT Mourn0 Addrenn, P.O. Boa 1441120 Sell Lake City. UT 84114.4820 Telephone (1101) 556.41)00 Fan ($01) 536.4099 .T.D.D. (1101)903.3978 tlnW. dtq. utah. got Printed on 000 recycled paper Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N101520030 Owner Name Northrop Grumman Systems Corporation Mailing Address 2211 West North Temple Salt Lake City, UT, 84116 Source Name Northrop Grumman Systems Corp. - Clearfield Source Location Freeport Center 13th Street Clearfield, UT 84016 UTM Projection 414,000 m Easting, 4,550,000 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 3728 (Aircraft Parts & Auxiliary Equipment, NEC) Source Contact Jeff Schmidt Phone Number (801) 774-4171 Email j.schmidt@ngc.com Billing Contact Jeff Schmidt Phone Number 801-774-4171 Email j.schmidt@ngc.com Project Engineer Christine Bodell, Engineer Phone Number (385) 290-2690 Email cbodell@utah.gov Notice of Intent (NOI) Submitted October 31, 2023 Date of Accepted Application November 9, 2023 Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 2 SOURCE DESCRIPTION General Description Northrop Grumman Systems Corp. (Northrop) manufactures aerospace composite structures at their Freeport Center plant located in Clearfield, Davis County. Northrop manufactures composite components for the aerospace industry, specifically for commercial and defense contractors. General steps in the manufacturing process include the following: raw material receipt and storage, material and tool preparation, fabrication, curing, finishing, testing, and packaging and shipping. As part of these steps, Northrop uses natural gas-fired equipment including curing ovens, boilers, burners, hot rooms, autoclaves, and heated paint booths; operates dust collectors for control of various machining processes; has painting and welding operations; has various natural gas-fired and diesel-fired emergency generators; and has various laboratory and chemical mixing operations. NSR Classification: Minor Modification at Minor Source Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA Davis County Airs Source Size: B Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines NSPS (Part 60), JJJJ: Standards of Performance for Stationary Spark Ignition Internal Combustion Engines MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines MACT (Part 63), WWWWWW: National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Plating and Polishing Operations Project Proposal Modification to Approval Order DAQE-AN101520028-22 to Add Equipment and Change Ownership Project Description Northrop Grumman Systems Corp. (Northrop) has requested a modification to AO DAQE- AN101520028-22 to add one (1) electric oven and one (1) mandrel preparation room. Northrop has also requested a name change from "ATK Space Systems, LLC" (subsidiary of Northrop) to "Northrop Grumman Systems Corp". The VOC and HAPs emission limitations outlined in the current AO will not be increasing as part of this modification. The new equipment will operate under existing emissions limitations. EMISSION IMPACT ANALYSIS The new equipment will operate under existing emissions limitations. There are no emission increases. Therefore, modeling is not required for this modification. [Last updated November 9, 2023] Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 3 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 24245.00 Carbon Monoxide 0 16.38 Nitrogen Oxides 0 19.49 Particulate Matter - PM10 0 13.42 Particulate Matter - PM2.5 0 13.21 Sulfur Dioxide 0 0.15 Volatile Organic Compounds 0 69.00 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) 1,1,2-Trichloroethane (CAS #79005) 0 4000 2-(2-Butoxyethoxy)-Ethanol (CAS #112345) 0 4000 Chromium Compounds (CAS #CMJ500) 0 27 Cumene (CAS #98828) 0 4000 Ethyl Acrylate (CAS #140885) 0 4000 Ethyl Benzene (CAS #100414) 0 4000 Ethylene Glycol (CAS #107211) 0 4000 Formaldehyde (CAS #50000) 0 1000 Generic HAPs (CAS #GHAPS) 0 2000 Glycol Ethers (CAS #EDF109) 0 4000 Hexamethylene-1,6-Diisocyanate (CAS #822060) 0 14 Hexane (CAS #110543) 0 4000 Hydrogen Fluoride (Hydrofluoric Acid) (CAS #7664393) 0 20 Methanol (CAS #67561) 0 4000 Methyl Chloroform (1,1,1-Trichloroethane) (CAS #71556) 0 19000 Methyl Isobutyl Ketone (Hexone) (CAS #108101) 0 4000 Methyl Isocyanate (CAS #624839) 0 20 Methyl Methacrylate (CAS #80626) 0 200 Methylene Chloride (Dichloromethane) (CAS #75092) 0 4000 Methylene Diphenyl Diisocyanate (MDI) (CAS #101688) 0 20 Naphthalene (CAS #91203) 0 4000 Nickel Compounds (CAS #NDB000) 0 40 Phenol (CAS #108952) 0 4000 Styrene (CAS #100425) 0 200 Tetrachloroethylene (Perchloroethylene) (CAS #127184) 0 4000 Toluene (CAS #108883) 0 4000 Trichloroethylene (CAS #79016) 0 4000 Xylenes (Isomers And Mixture) (CAS #1330207) 0 4000 Change (TPY) Total (TPY) Total HAPs 0 45.27 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 4 Review of BACT for New/Modified Emission Units 1. BACT review regarding New Mandrel Prep Room and Electric Oven Northrop's Clearfield facility is located in Clearfield, Davis County. The location is a nonattainment area for ozone and PM2.5. The new electric oven and mandrel prep room are under a BACT review, but the emissions associated with each piece of equipment will remain under an existing permit limit. Therefore, there is no emissions increase in the site-wide PTE. The source is subject to UAC R307-325 (Ozone Nonattainment and Maintenance Areas: General Requirements). These are general provisions that require sources in an ozone nonattainment area not to spill, discard, or store any VOC containing materials in any other manner that could results in greater VOC emissions. The source is subject to UAC R307-355 (Control of Emissions from Aerospace Manufacture and Rework Facilities) as the facility is an aerospace manufacture and rework facility that has the potential to emit 10 tons or more per year of VOCs. The rule includes provisions for VOC content limits, application methods, work practices, and solvent cleaning. The new equipment will operate under existing emissions limitations. There are no emission increases. Therefore, additional controls to reduce emissions from the mandrel prep room and electric oven are not cost effective. The minor NSR Section considers the above as BACT. [Last updated December 12, 2023] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 5 I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307- 150] I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 Northrop Grumman Systems Corp Aerospace composite components manufacturing facility II.A.2 Five Electric Curing Ovens Ovens: O-21; O-36; O-48 (New); O-159; O-160 Venting (all): Atmospheric Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 6 II.A.3 Eleven Natural Gas-Fired Ovens Oven: Rating: O-26 1.2 MMBtu/hr O-27 4.0 MMBtu/hr COV1 2.8 MMBtu/hr COV2 4.0 MMBtu/hr O-30 3.5 MMBtu/hr O-22 2.0 MMBtu/hr O-24 0.6 MMBtu/hr O-37 3.0 MMBtu/hr O-39 6.4 MMBtu/hr O-41 1.0 MMBtu/hr O-47 3.0 MMBtu/hr II.A.4 Seven Hot Rooms Rooms: ACU253, AHU1, AHU2, AHU3, AHU4, HR1, HR3 Fuel (all): Natural Gas Maximum Rating: < 5.0 MMBtu/hr (each) II.A.5 One Boiler- BO1 Fuel: Natural Gas Rating: 8.37 MMBtu/hr II.A.6 Three Autoclaves Autoclave: Rating: AC1 12.0 MMBtu/hr AC6 24.3 MMBtu/hr AC12 15.0 MMBtu/hr Fuel (all): Natural Gas II.A.7 Five Autoclaves Autoclaves: CAC1, CAC2, CAC3, CAC4, CAC5 Fuel (all): Natural Gas Rating: 15.8 MMBtu/hr (each) II.A.8 Twelve Ventilation Rooms Ten Mandrel Prep Rooms (1 NEW); FX-141; Paint Touchup Room II.A.9 Eleven Laboratory Hoods FUH-3; FUH-7; AT-401073; FUH-5; FUH-2; AT-401706; FE-200; FE-222; FUH-1; SB-2; 2228 Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 7 II.A.10 Thirteen Exhaust Hoods 1,2. Two Welding fume exhausters 3. RMS-6 4. Battery Charging area exhaust hood 5. MX-85 6. M-5 7. 83310J00475 8. E-145 Tacking Table 9. FX-105 10. FX-106 11. FE-655 12, 13. Two Paint mixing fume hoods II.A.11 Four Heated Paint Booths Paint Booth: Heater Rating: SB10 750 KBtu/hr SB11 950 KBtu/hr SB12 950 KBtu/hr SB13 950 KBtu/hr Fuel (all): Natural Gas Control: Vacuum System (each) II.A.12 Six Spray Booths SB7, SB9, SB5, SB14, IFE SB, Topcoat SB Control: Fabric Filters (each) II.A.13 One Ceramics Spray Booth Control: High efficiency 3-stage fabric filters II.A.14 One Thermal Spray Booth Control: Pulse jet baghouse (DC-58) Baghouse Maximum Flow Rate: 25,300 acfm MACT Applicability: Subpart WWWWWW II.A.15 Eight Natural Gas-Fired Emergency Generators Engine: Rating: GE 3 7 kW GE 4 35 kW GE 5 100 kW GE 8 80 kW GE 9 240 kW GE 10 45 kW GE 11 45 kW GE 12 85 kW NSPS Applicability: Subpart JJJJ MACT Applicability: Subpart ZZZZ Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 8 II.A.16 Two Diesel-Fired Emergency Generators Engine: GE 7 Rating: 225 kW Engine: GE 13 Rating: 268 hp NSPS Applicability: Subpart IIII MACT Applicability: Subpart ZZZZ II.A.17 Eight Dust Collectors DC-16, DC-27, DC-28, DC-29, DC-30, DC-36, DC-37, DC-38 II.A.18 Miscellaneous Equipment Miscellaneous vacuum pumps Miscellaneous Air compressors II.A.19 Miscellaneous Combustion Equipment Various Boilers and Heaters Maximum Rating: <5.0 MMBtu/hr Fuel: Natural Gas II.A.20 Eighteen Wet Cooling Towers CT-6, CT-7, CT-9, CT-13, CT-14, CT-15, CT-16, CT-17, CT-18, CT-19, CT-20, CT-21, CT- 22, CT-23, CT-24, CT-25, CT-26, CT-27 Controls: High Efficiency Drift Eliminators (each) II.A.21 Informational-Only Equipment* Nineteen electrical sample curing ovens One electrical Hot room eight electrical autoclaves One Buffer room Miscellaneous Dust Collectors, including portable and orifice scrubbers Miscellaneous Machining Centers / Lathes / Cork Cutting Equipment One Spray Gun Cleaning Station Miscellaneous Grit Blast and Abrading Equipment 3D Printers *This equipment does not vent to atmosphere and is listed for informational purposes only II.A.22 Informational-Only Equipment* (Continued) Three Hot Drape Forming Machines One Ductless Fume Hood Two Reticulators Two Dry Cooling Towers *This equipment does not vent to atmosphere and is listed for informational purposes only Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 9 II.A.23 Grandfathered Equipment* Pit exhaust system Indirect gas fired curing oven - #20 Rating: 6 MMBtu/hr *This equipment was installed before 1969 and is listed for informational purposes only SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following emission points to exceed the following values: A. Diesel-fired emergency engines - 20% opacity B. All other emission points - 10% opacity [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8] II.B.1.b The owner/operator shall not exceed a plant-wide natural gas consumption limit of 406,624 Decatherms per rolling 12-month period. [R307-401-8] II.B.1.b.1 NEW The owner/operator shall: A. Determine consumption by gas billing records B. Record consumption on a monthly basis C. Use the consumption records to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep consumption records for all periods the plant is in operation. [R307-401-8] II.B.1.c NEW The owner/operator shall comply with all applicable requirements of UAC R307-325 (Ozone Nonattainment and Maintenance Areas: General Requirements) and UAC R307-355 (Control of Emissions from Aerospace Manufacture and Rework Facilities), [R307-355] Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 10 II.B.2 VOC & HAP Requirements II.B.2.a NEW The owner/operator shall not emit more than the following from all sources on site: A. 69.00 tons per rolling 12-month period of VOCs B. 19.00 tons per rolling 12-month period of all HAPs combined C. 2.00 tons per rolling 12-month period of 2-Butoxyethanol D. 0.014 tons per rolling 12-month period of Chromium Compounds E. 2.00 tons per rolling 12-month period of Cumene F. 2.00 tons per rolling 12-month period of Ethyl Acrylate G. 2.00 tons per rolling 12-month period of Ethylbenzene H. 2.00 tons per rolling 12-month period of Ethylene Glycol I. 0.50 tons per rolling 12-month period of Formaldehyde J. 1.20 tons per rolling 12-month period of Generic HAPs K. 2.00 tons per rolling 12-month period of Glycol Ethers L. 0.007 tons per rolling 12-month period of Hexamethylene-1,6-Diisocyanate M. 2.00 tons per rolling 12-month period of Hexane N. 0.010 tons per rolling 12-month period of Hydrogen Fluoride O. 2.00 tons per rolling 12-month period of Methyl Alcohol P. 0.010 tons per rolling 12-month period of Methyl Isocyanate Q. 2.00 tons per rolling 12-month period of Methylene Chloride R. 0.10 tons per rolling 12-month period of Methylenedianiline S. 0.010 tons per rolling 12-month period of Methylene Diphenyl Diisocyanate T. 2.00 tons per rolling 12-month period of Methyl Isobutyl Ketone (MIBK) U. 2.00 tons per rolling 12-month period of Naphthalene Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 11 V. 0.02 tons per rolling 12-month period of Nickel Compounds W. 2.00 tons per rolling 12-month period of Phenol X. 2.00 tons per rolling 12-month period of Tetrachloroethylene Y. 2.00 tons per rolling 12-month period of Toluene Z. 9.50 tons per rolling 12-month period of 1,1,1-Trichloroethane AA. 2.00 tons per rolling 12-month period of 1,1,2-Trichloroethane BB. 2.00 tons per rolling 12-month period of Trichloroethylene CC. 2.00 tons per rolling 12-month period of Xylene [R307-401-8] II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed] [R307-401-8] II.B.2.a.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 12 II.B.2.a.3 NEW The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and each HAP in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs and the amount of each HAP emitted from each material F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons) [R307-401-8] II.B.3 Paint Booth Requirements II.B.3.a NEW The owner/operator shall equip each paint booth with paint arrestor particulate filters to control particulate emissions. All exhaust air from the paint booths shall be routed through the filters before venting to the atmosphere. [R307-401-8] II.B.3.b The paint booths shall be equipped with HVLP spray guns, or an equivalent method, to control VOC emissions. [R307-355-6] II.B.3.c The owner/operator shall control the thermal spray booth with a baghouse. [R307-401-8] II.B.3.d The owner/operator shall install a manometer or magnehelic pressure gauge to measure the differential pressure across the baghouse. The baghouse shall operate within the static pressure range recommended by the manufacturer for normal operations. [R307-401-8] II.B.3.d.1 Pressure drop readings shall be recorded at least once during each day of operation while the baghouse is operating. Records documenting the pressure drop shall be kept in a log and shall include the following: A. Unit identification B. Manufacturer-recommended pressure drop for the unit C. Daily pressure drop readings D. Date of reading [R307-401-8] II.B.3.d.2 Each pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 13 II.B.3.d.3 The instrument shall be calibrated in accordance with the manufacturer's instructions or recommendations or replaced at least once every 12 months. Documentation of calibrations and replacements shall be maintained. [R307-401-8] II.B.4 Emergency Engine Requirements II.B.4.a The owner/operator shall not operate each emergency engine on site for more than 100 hours per calendar year during non-emergency situations. There is no time limit on the use of the engines during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.4.a.1 To determine compliance with a calendar year total, the owner/operator shall calculate a new yearly total by January 31st using data from the previous calendar year. Records documenting the operation of each emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used B. The duration of operation in hours C. The reason for the emergency engine usage [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.4.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour meter for each emergency engine. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.5 Fuel Requirements II.B.5.a The owner/operator shall use only natural gas as a fuel in all fuel-burning furnaces, ovens, boilers, heaters, and natural gas-fired emergency engines. [R307-401-8] II.B.5.b The owner/operator shall only use diesel fuel (fuel oil #1, #2 or diesel fuel oil additives) in the diesel-fired emergency engines. All diesel burned shall meet the definition of ultra-low sulfur diesel (ULSD) and contain no more than 15 ppm sulfur. [R307-401-8] II.B.5.b.1 To demonstrate compliance with the diesel fuel requirements for any diesel fuel purchased, the owner/operator shall keep and maintain fuel purchase invoices. The fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements, or the owner/operator shall obtain certification of sulfur content from the fuel supplier. [R307-401-8] Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 14 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN101520028-22 dated September 26, 2022 Is Derived From NOI dated December 21, 2022 Incorporates Additional Information dated October 26, 2023 REVIEWER COMMENTS 1. Comment regarding HAP Emissions: Condition II.B.2.a contains a 19.00 TPY rolling 12-month limit for all HAPs combined. Additionally, Condition II.B.2.a also includes individual HAP limits. If added up, these individual limits exceed the total HAP limit. Northrop has been given individual limits to add greater flexibility in their operations, with an established combined HAP limit which prevents Northrop from becoming a major source of HAP emissions. The generic HAP limit was established to provide Northrop flexibility in their operations for when minor processes use HAPs other than those listed. [Last updated November 28, 2023] 2. Comment regarding Modification: Northrop has requested to add one (1) mandrel prep room. The mandrel prep room will be constructed to support research and development. Solvents are used to clean the tool and release agents are used to prevent parts from adhering to the tooling. The addition of this mandrel prep room will result in 0.01 tpy of HAPs (toluene, methanol, methyl isobutyl ketone) and 0.19 tpy of VOCs. However, Northrop is not requesting to increase the emission limits for VOCs and each HAP outlined in Condition II.B.2.a of Approval Order DAQE-AN101520028-22. The PTE estimates for this permit modification are not changing. The mandrel prep room is a new piece of equipment that increases hourly emissions. Northrop has also requested to add one (1) electric oven. Sealants applied to aerospace parts will cure in the oven and the off-gassing products from this process will be exhausted to the atmosphere. The addition of this electric oven will result in 0.01 tpy of HAPs (xylene, methylbenzene) and 0.01 tpy of VOCs. As stated above, Northrop is not requesting to increase the emission limits for VOCs and each HAP outlined in Condition II.B.2.a of the current AO. The PTE estimates are not changing. The electric oven is a new piece of equipment that increases hourly emissions. This project is classified as a modification. VOC and HAPs emissions were estimated by material balance using VOC/HAP contents obtained from SDS sheets. [Last updated December 12, 2023] 3. Comment regarding NSPS and MACT Applicability: 40 CFR 60 NSPS Subpart IIII - Standards of Performance or Stationary Compression Ignition Internal Combustion Engines The provisions of this subpart apply to owners and operators of stationary CI ICE that commence construction after July 11, 2005, where the stationary CI ICE are manufactured after April 1, 2006. The two (2) diesel-fired emergency stationary engines at this facility were constructed after this date and are therefore subject to NSPS Subpart IIII. 40 CFR 60 NSPS Subpart JJJJ - Standards of Performance for Stationary Spark Ignition Internal Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 15 Combustion Engines The provisions of this subpart apply to owners and operators of stationary SI ICE that commence construction after June 12, 2006, where the stationary SI ICE are manufactured on or after July 1, 2008, for engines with a maximum engine power less than 500 HP. The eight (8) natural gas-fired emergency stationary engines on site were constructed after this data and are therefore subject to NSPS Subpart JJJJ. 40 CFR 63 Subpart ZZZZ - Standards of Performance for Stationary Spark Ignition Internal Combustion Engines The provisions of this subpart are applicable to owners/operators of stationary RICE at a major or area sources of HAP emissions. The facility includes (2) diesel-fired emergency stationary engines and eight (8) natural gas-fired emergency stationary engines. The provisions of MACT Subpart ZZZZ apply as the stationary reciprocating internal combustion engine (RICE) is at an area source of HAP emissions. The engines are not designated as nonroad and are not exempt are affected sources under this regulation. Therefore, MACT Subpart ZZZZ applies to this facility. 40 CFR 63 Subpart WWWWWW - National Emissions Standards for Hazardous Air Pollutants: Area Source Standards for Plating and Polishing Operations This subpart applies to owners and operators of affected sources at plating and polishing facilities that are area sources of HAPs. This subpart specifically applies to plating and polishing facilities that use one or more plating and polishing metal HAPs, including compounds of nickel, in affected sources, including thermal spraying. This source is considered an area source of HAPs and has a thermal spraying operation using nickel compounds; therefore, MACT Subpart WWWWWW applies to this source. MACT Subpart WWWWWW contains capture system requirements for thermal spraying operations. Northrop has chosen to comply with the capture system requirements with a pulse jet baghouse to control the thermal spraying operations. In addition to this requirement, MACT Subpart WWWWWW contains other management practices, equipment and operating standards, and notification, reporting, and recordkeeping requirements for thermal spraying operations. [Last updated December 5, 2023] 4. Comment regarding Title V Applicability: Title V of the 1990 CAA (Title V) applies to the following: A. Any major source B. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources C. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants D. Any Title IV-affected source This facility is not a major source and is not a Title IV source, but is subject to 40 CFR 60 NSPS Subparts A, IIII, and JJJJ, and 40 CFR 63 MACT Subparts A, ZZZZ, and WWWWWW regulations. However, Title V does not apply because NSPS Subparts IIII and JJJJ and MACT Subparts ZZZZ and WWWWWW exempt sources from the obligation to obtain a permit under 40 CFR part 70 (Title V permit) if the source is not otherwise required by law to obtain a permit. There are no other reasons why this source would be required to obtain a part 70 permit; therefore, Title V does not apply to this facility. [Last updated November 28, 2023] Engineer Review N101520030: Northrop Grumman Systems Corp. - Clearfield December 12, 2023 Page 16 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds Utah Division of Air Quality New source Review Section Ownership Change/Company Name Change Notification The following information is necessary before the Division will be able to make the name change you have requested. Please return this document within 30 days of receipt. Please be aware that all records associated with this company will change to the new name unless you specifically indicate otherwise. The fee assessed for making these changes is authorized by the legislature for the actual time spent by the reviewer. Note: If this name change is the result of a sale or acquisition, both the buyer & the seller must sign this document as proof of the closure of the agreement. Reason for Ownership Change/Company Name Change ___Reorganization________________________________ Company Name Current Previous Parent Company: Parent Company: Company Address Current Previous Approval Orders Affected and Sites For Each Approval Order Approval Order # (DAQE-ANxxxxxxxxxx-xx) Site Name & Address (for each Approval Order) The undersigned, as an authorized representative of the company, acknowledges that the above information is correct, and requests that the company name change be made in all Air Quality records. Present Owner _______________________ Previous Owner ______________________ ____________________________________ ____________________________________ Signature Signature ________________________ ____________________________________ Name (please print) ____________________________________ Title Title ____________ _____________________________ Return this form to: Contact Name (Please print) State of Utah (_ ) - Division of Air Quality Phone Number Attn: NSR – Ownership/Name Change Notification 195 North 1950 West _____________________________ PO Box 144820 E-mail Salt Lake City, Utah 84114-4820 SECTION\Forms\Name Change.doc Revised 5/16/11 Northrop Grumman Systems Corp.ATK Space Systems, LLC Northrop Grumman Corp.Northrop Grumman Corp. Freeport Center, 13th Street Clearfield, UT 84016 Freeport Center, 14th Street Clearfield, UT DAQE-AN101520028-22 ATK Space Systems, LLC - Clearfield Freeport Center, 14th Street, Clearfield, UT 84016 Jeff Schmidt 801 774 4171 j.schmidt@ngc.com Nicholas Tucker Name (please print) ___Director, Program Integration and Stragic Business Operations Northrop Grumman Form 2 Company lnformation/Notice of lntent (NOl) Utah Division of Air Quality New Source Review Section Date 12t8t22 UTAH DEPARTMENT OF ENVIRONMENTAL OUAUTY AIR OUALITY Application for: I tntl"l Approval order f approvat ord8f &iod iti#En General Owner and Source lnformation 2. Company** contact for environmental matters: Jeff Schmidt Phone no.: ((801) 774-417 1 Emait: i.schmidt@nqc.com '. Company contact only; consultant or independent contractor contact information can be orovided in a cover letter l.Company name and mailing address: Northrop Grumman Systeml P.O. Box 160433 Clearfield, UT 84016 Phone No.: (801) 775-1262 Fax No.: (801)) 775-1559 3. Source name and physical address (if different from ubou")' Northrop Grumman system, Freeport Center, Bldg. A-15 Clearfield, UT 84016 4. Source Property Universal Transverse Mercator coordinates (UTM), including System and Datum: UTM: 12 X: 4550000 y: 414000 5. The Source is tocated 1n. Davis 6. Standard lndustrial Classification Code (SlC) 7. lf request for modification, Ao# to be modified: DAQE #DAQE-AN101520028-22 DATED: Y-t26 -t4- 8. Brief (50 words or less) description of process. To support growth and new programs, Northrop Grumman Systems Corp. seeks a revision of the existing AO to add one mold prep room and one electric oven, Electronic NOI 9. A complete and accurate electronic NOI submitted to DAQ Permitting Mangers Jon Black (jlblack@utah.gov) or Alan Humpherys (ahumpherys@utah.gov) can expedite review process. Please mark application type. Authorization/Si g natu re I hereby certify that the information and data submitted in and with this application is completely true, accurate and complete, based on reasonable inquiry made by me and to the best of my knowledge and belief. * ,,t", EH&S Engineer Telephone Number: (80)1) 774-4171 Email: j.schmidt@ngc.com Date: 1218122 Jeff Schmidt Name (Type or print) 1of1 .3',"Form 1 '| Notice of lntent (NOl) Application Checklist Utah Division of Air Quality New Source Review Section Date Company 12t8t22 Northrop Grumman Systems Corp. !^\ to AIR OUALITY Source Identification Information [R307 -401 -5) l. Company name, mailing address, physical address and telephone number 2. Company contact (Name, mailing address, and telephone number) 3. Name and contact of person submitting NOI application (if different than 2) 4. Source Universal Transverse Mercator (UTM) coordinates 5. Source Standard Industrial Classification (SIC) code 6. Area designation (attainment, maintenance, or nonattainment) 7. Federal/Stare requirement applicability (NAAQS, NSPS, MACT, SIP, etc.) 8. Source size determination (Major, Minor, PSD) 9. Current Approval Order(s) and/or Title V Permit numbers NOI Application Informatioru fn:OZ-+Of tl. Detailed description of the project and source process 2. Discussion of fuels, raw materials, and products consumed/produced 3. Description of equipment used in the process and operating schedule 4. Description of changes to the process, production rates, etc. 5. Site plan of source with building dimensions, stack parameters, etc. Best Available Control Technology (BACT) Analysis [R307-401-8] A. BACT analysis for all new and modified equipment Emissions Related Information: [R307-401-2(b)] A. Emission calculations for each new/modified unit and site-wide (Include PMro, PMz.s, NO*, SO2, CO, VOCs, HAPs, and GHGs) B. References/assumptions, SDS, for each calculation and pollutant C. All speciated HAP emissions (list in lbsihr) Emissions lmpact Analysis - Approved Modeling Protocol [R307-410] A. Composition and physical characteristics of effluent (emission rates, temperature, volume, pollutant types and concentrations) Nonattainment/Maintenance Areas - Major NSR/Minor (offsetting only) [R307-403] A. NAAQS demonstration, Lowest Achievable Emission Rate, Offset requirements B. Alternative site analysis, Major source ownership compliance certification Major Sources in Attainment or Unclassified Areas (PSD) [R307-405, R307-406] A. Air quality analysis (air model, met data, background data, source impact analysis) B. Visibility impact analysis, Class I area impact Signature on Application Note: The Division of Air Quality will not accept documents containing confidential information or data. Documents containing confidential information will be returned to the Source submitting the application. E E @V @ Vg @ Zg g aaaaa a aa Z a tr tr tr tr tr 6. 7. 8. 9. 10. 11. N/A E N/A E N/A N/A Department of Environmental Quality Amanda Smith Executive Director DryISION OF AIR QUALITY Bryce Bird Acting Director Aprrl26,20ll State of Utah GARY R. HERBERT Govemor GREG BELL Lieutenant Governor Minor Source Offset Requirements Is tlre source located in or impact* Davis or Salt Lake County? Are total VOC emissions less than 50 tpy? Will the source have an increase in NOx of less than 40 tpy? Will the source have an increase in VOC's of less than 25 tpy? Source is required to obtain NOx offsets on at least a L15 to I basis. (R307-420-3) Source is required to obtain VOC offsets on a 1.2 to I basis. (R307-420-3) *Impact means having an increase greater than the increments listed in R307-403-3. This document is intended for guidance and educational purposes only. It is not intended to include all possible scenarios. The DAQ NSR Section should be contacted for site specific requirements. 195 North 1950 West. Salt Lake City, UT Mailing Address: P.O. Box lM82O . Salt Lake City, UT 84114-4820 Telephone (801 ) 536-4000 . Fax (80 I ) 5364@9 . T.D.D. (80 I ) 536-441 4 www,deq.utalLgov Printed m 1007o recycted paper mlffiIremre Are the increases of NOx, SO2, and PMl0 less than 25 tpy combined? Are the increases of NOx, SO2, and PMl0 less than 50 tpy combined? Source is required to obtain offsets on a I to I basis. (tnter-pollutant trading is allowed) (R307403-5) Source is required to obtain offsets on a 1.2 to I basis. (Inter-pollutant trading is allowed) (R307403-5) *Impact means having an increase greater than the increments listed in R307403-3. This document is intended for guidance and educational purposes only. It is not intended to include all possible scerurios. The DAQ NSR Section should be contacted for site specific requirements. Page2 Location Determination *Impact means having an increase greater than the increments listed in R307403-3. This document is intended for guidance and educational purposes only. It is not intended to include all possible scenarios. The DAQ NSR Section should be contacted for site specific requirements. Is thc source locaced in or impactr: Duchesne Comty or Uintah Countf Source is located in an unclassifiable area for ozone and an attainment area for all other pollutants. Is the source locahd in or imprt.: Box Elder Courty, Crhc County, or Toocle County? Source may be located in or impact* a PM2 5 nonattainment area- Contact a DAQ NSR permit engineer for area boundaries, rules, and requirements. Is the sourcc Iocatcd in or impoct* Wcber Comty? Is the source located in or impactr Ogden City? Source is located in a nonattainment area for PM1e. Source is located in a maintenance area for CO. Page 3 *Impact means having an increase greater than the increments listed in R307-403-3. This document is intended for guidance and educational purposes only. It is not intended to include all possible scenarios. The DAQ NSR Section should be contacted for site specific requirements. Is the source locatcd in or impactr Salt Lake County? Is the source located in or impactr Salt Lake City? Source is located in a nonattainment area for PMro, PM2s, and SO2. Source is located in a maintenance area for ozone. Is thc sourcc lmdcd in or impact Utah County? Is the source located in or impact' Provo City? Source is located in a nonattainment area for PM16 and PM2 5. Is the sourc€ locared in or impactt Davis County? Source is located in a nonattainment arca for PM2 5. Source is located in a maintenance area for ozone. NOTE: Since 201 S,source is located in a nonattainmenl area for ozone Source is located in an attainment area for all pollutants. ^€e EEEF3P €€Ee4; coos;'tso .E'= .E TE,P-l!>GL E oE L-6e5s H 8E :.= EE .Ea- =oU Io,EsEs =c.=c-lEglodE E2 EsEA'6 o- 6 o€ .E E.g.E 5.E E'Elo9Et€8Se eg +jrEz o LC o oC'f! 5t E:YoS 6E PE a0 .ccrl' -g(J 6 6' E A. {6 gE g:E =bEot, oco or.ttl' 4.oo-(! =tooEE\_6d>o5zUI Ec,= oo Q EOtra-L =iPI turh -Jtro =U}o+,a-taoc Eo(.J I E tEL a0 .Eo 3o -l! tA 1Ao(JoL4 ( ( -'\ -o9eE ;iortuo X cLo, ',.!2 ;= (! r, 'E F s ='T"88$f; SE6. l- o)Ftr -l-- -o)r)\/o +,beo-E OCUoG)t-tLO l=tscrz= GA = CL (E - =ot,TIa f m @ tr (E tr -E =Lo CLoLF -*.Loz 5 tods foreach criteria pollrradg 500 pounds for any singfe HAP, ard 2000 pouhds for all HAPs Source is a Small Source (AO is not rcquired. Source may register for a Small Source Exemption ( SSE), but registration is not required). fugitives,less than 70 tons for PM25 or any fugitives less than 100 tons for CO source a listedsource a listed non-fugitive PTE less thanl00 tons for CO or PTE less than 70 tons for PM25 or any of its precursor pollutanb? fugitives, less firan l0 tons for any single HAP, or 25 tons PTE including fugitives, less ftan l0 tons for any single HAP, or 25 tons for all HAPs Source is a Title V Major Source, PSD may apply; contact a DAQ NSR Engineer for details. Flowchart I Sources Inside PMz.s Serious Non-attainment Area (Pte = PotentialTo Emit) NO YES Source is a Minor Source - AO is Form 5 Emissions lnformation Criteria/GHGs/ HAP's Company Northrop Grumman Systems Corp. Site ASBU Clearfield Utah Division of Air Quality AtR ouALtry New Source Review Section Potentialto Emit*Criteria Pollutants & GHGs Criteria Pollutants Permrtted tsmrssrons (tons/vr) Emissions lncreases (tons/vr) Proposed Emissions (tons/vr) PM,"Total 13.42 0.00 13.42 PM16 Fugitive PMz.s 13.21 0.00 13.21 NO*19.49 0.00 19.49 Soz 0.15 0.00 0.15 co 16.38 0.00 16.38 voc 69.00 0.00 69.00 VOC Fuqitive NHg 0.00 0.00 0.00 Greenhouse Gases co*CO"e CO,e Coz CH. N,O HFCs PFCs SFo TotalCO2e 24,245.00 0.00 24,245.00 .Potential to emit to include tollution control eauiDment as defined t -401-2 HaZafdOUS Aif POllUtants** 1"o"ri, ed in section 1 t 2(b) or the ctean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission !ncrease (lbs/hr) 2-Butoxvethanol 2.00 0.00 2.OO 0.00 Chromium Compounds 0.01 0.00 0.01 0.00 Cumene 2.00 0.00 2.O0 0.00 Ethyl Acrylate 2.00 0.00 2.00 0.00 Ethylbenzene 2.00 0.00 2.00 0.00 Ethylene Glycol 2.00 0.00 2.00 0.00 Formaldehvde 0.50 0.00 0.50 0.00 Generic HAPs 1.20 0.00 1.20 0.00 Glvcol Ethers 2.OO 0.00 2.00 0.00 HDI 0.01 0.00 0.01 0.00 Hexane 2.00 0.00 2.00 0.00 Hvdroqen Fluoride 0.01 0.00 0.01 0.00 MethvlAlcohol 2.00 0.00 2.OO 0.00 Methyl lsocyanate 0.01 0.00 0.01 0.00 Methylene Chloride 2.OO 0.00 2.00 0.00 Methylenedianiline 0.10 0.00 0.10 0.00 MDI 0.01 0.00 0.10 0.00 Methvl lsobutvl Ketone 2.00 0.00 2.OO 0.00 Total HAP *** I l(c adtiilional Rhcels neededpollutants Page I of I Form 5 - Emissions lnformation (cont.) Hazardous Air Pollutant Permitted Emissions (tons/yr) Emission lncrease (tons/yr) Proposed Emissions (tons/yr) Emission lncrease (lblhr) Naohthalene 2.00 0.00 2.00 0.00 NickelCompounds 0.02 0.00 0.02 0.00 Phenol 2.00 0.00 2.00 0.00 Tetrachloroethvlene 2.00 0.00 2.OO 0.00 Toluene 2.00 0.00 2.OO 0.00 L,L,1.- Trichloroethane 9.50 0.00 9.50 0.00 L,L,2- Trichloroethane 2.00 0.00 2.00 0.00 Trichloroethvlene 2.OO 0.00 2.00 0.00 Xylene 2.OO 0.00 2.00 0.00 All HAPs combined 19.00 0.00 19.00 0.00 VOCs 59.00 0.00 69.00 0.00 Federal/State Requirement Applicability The following rules and regulations apply to the equipment identified on this NOl. o Mold Prep Room o Utah R307-355, Aerospoce Manufocture and Rework Focilities I\XOUD ROOI\/I Form 4 Project Information Utah Division of Air Quality New Source Review Section cornp"nyxortht9p.!"'T*ffiSite ASBU AIR QUALITY iic 2 1 ?cli- ). o,r,r'o* oF AIR oulltTY Process Data - For Modification/Amendment ONLY lf submitting a new permit, then use Form 3 ReqrNested Changes 2. Name of process to be modified/added: Mold Prep Room End product of this process: Clean aerospace tooling 3. Permit Change Type: Equipment Process Does new emission unit affect existing permitted process limits? 5. Condition(s)Changing: Add an additional mold prep room as permitted equipment 6. Description of PermiVProcess Change** A mold prep room will be constructed to support research and development. Solvents are used to clean the tool followed by a release agents to prevent parts from adhering to the tooling. The room is used for ventillation to move organic vapors away from worker's breathing zone. 7. New or modified materials and quantities used in process. ** 8. New or modified process emitting units ** the permit being modified does not include CO2e or PMz.s, the emissions need to be calculated and submitted to DAQ, which may emissions increase and a public comment peiod. -.lf additional space is required, please generate a document to accommodate and attach to form. Page 1 of 1 Utah Division of Air Quality New Source Review Section Form 2 Process lnformation Company Northrop Grumman Systems Corp Site/Source ASBU Clearfield Date Process Data 1. Name of process: Mold prep Room 2. End product of this process: Tool Cleaning 3.Primary process equipment: Make or model: Fan Manufacturer: Capacity of equipment (lbs/hr): ldentification #: Year installed: Rated 3725 SCFM Max. (Add additional sheets as needed) 4.Method of exhaust ventilation: E Stack tr Window fan tr Roof vent Are there multiple exhausts: tr Yes tr Other, describe ENO Operating Data 5. Maximum operating schedule: 12 hrs/day 5 daYs/week 50 weeks/year 6. Percent annual production by quarter: Winter 25 Spring 25 Summer 25 Fall 25 7. Hourly production rates (lbs.): Average Maximum 8. Maximum annual production (indicate units): 70.2 gallons p-rojecteo percent annual increase in production: o% 9. Type of operation: o Continuouso Batch E lntermittent 10. lf batch, indicate minutes per cycle Minutes between cycles 11. Materials used in process Raw Materials Principal Use Amounts (Soecitu Units) Acetone Solvent 12 gallons lsopropyl Alcohol Solvent 36 qallons Methyl Propyl Ketone Solvent 1.2 gallons Chemlease MP 117 Tool Sealant 3 gallons Frekote 700-NC Release Agent 12 gallons Frekote B-15 Release Agent 6 gallons Page 1 of 3 Process Form 2 (Continued) 12. Control eouioment (attach additional oaoes if necessary) Item Primary Collector Secondary Collector a. Tvoe b. Manufacturer c- Model d. Year installed e. Serialor lD# f. Pollutantcontrolled g. Controlled pollutant emission rate (if known) h. Pressure drop across control device i. Desion efficiencv j. Operatingefficiency Stack Data (attach additional pages if necessary) 13. Stack identification:14. Height:Above roof ft Aboveground 11 ft 15. Are other sources vented to this stack: trYes E No lf yes, identify sources: 16. I Round, top inside diameter dimension 16" o n".*gr.rl"r, top inside dimensions length _ x width 17. Exit gas: Temperature 72 oF Volume 3,725 ssln't Velocity 2,670 fumin 18. Continuous monitoring equipment: D yes E no lf yes, indicate: Type Manufacturer Make or Model Pollutant(s) monitored Emissions Calculations (PTE) 19. Calculated emissions for this device PMlo 0 Lbs/hr-Q- Tons/yr PM2 s 0 Lbs/hr 0 Tons/yr NO.__9_ Lbs/hr Q_ Tons/yr SO, 0 Lbs/hr Q_ Tons/yr co 0 Lbs/hr_Q_ Tons/yr ygg 0.125 Lbs/hr 0.'!87 Tons/yr CO2 0 Tons/yr CH4 0 Tons/yr N2O 0 Tons/yr HAPs 0.006 Lb s/hr (speciatel 0.008 Tons/yr (speciate) Submit calculations as an appendix. lf other pollutants are emitted, include the emissions in the appendix. Page 2 of 3 Form 2-P s lnformation (cont.) Calculations (PTE) *See DAQ VOC Calcs Spreadsheet, "Summary" g EJ. Eg ! xc€uiF =oEE:o o o it EFi i;.H EEE im oil0o 00; E > >d E -: oO bE E f f do €l :l 3t ;l 3 -c; A E ?5 > >o rd0 i r It9 s9r O=tii>Fc6!999t6,:,= :600 TiEF zo.= EFEdzo .}tr r gg6d _g; ,5e-EEi 5T E*EHE } > >o::E >do P- 9s r 85 5 6Stii>F,!i9p99 :6 0 0 EgEF z '.i .E E5Eozo .! E co o J o: l 9s r 95 ! xt r ii>F.!fr!9!9 5600 EM EI EFz a;s EEg oirqo E > >dt EEE 5 ld(o ,EI -t -t 3 c co t t I n:! B I I ! !- I g; f o=t ii>Fct:e9 =eii;6 0 0 > >d = E! ldo 2 o f 3sEFi;.H EEEazo ?- 9u r 3i 5 6St f,>F.E;!9!9 :6 0 0 ,}t t'.t== AEcPe eou^;> o s vuo I ao Roo A <> ;> > o ! ;l >{lc.lo:l < -ol n5I t: l=lagffi stsr E5U::> EUE N;: UETEE$ t>;>>6 r q! > >o fdg .! > ?- l Ii;3sEF zc.E EEEdz9 MOLD PREP ROOM SAFETY DATA SHEETS Safety Data Sheet date:0412512019Revision Number: 007.1 1. PRODUCT AND PANY IDENTIFICATION Product name:LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterface IDH number: Item number: Region: 548993 38428 United States Product type/use: Mold Release Restriction of Use: None identified Company address: Henkel Corporalion One Henkel Way Rocky Hill, Connecticut 06067 Contact information: Telephone: +1 (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1 -877-671 -4608 (toll free) or 1 -303-592-1 71 1 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 lntemet: www.henkelna.com Contains one or more components for which a Toxic Substances Control Act (TSCA) Low Volume Exemption (LVE) applies. See Section 15. 2.IDENTIFICATION DANGER: EMERGENCY OVERVIEW CONTENTS UNDER PRESSURE. EXTREMELY FLAMMABLE AEROSOL. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE AEROSOL.1 SKIN IRRITATION 2 EYE IRRITATION 2A l.iPF(;il-t(; tAH(iFt (rH(,AN t(rxt(;ttY -:.itN(it F 1-xP()titrHF 3 Precautionary Statements Prevention: Response: Keep away from heal, sparks, open flames, hot surfaces - no smoking. Do not spray on an open flame or other ignition source. Do not pierce or bum, even after use. Avoid breathing mist or spray. Wash aflected area thoroughly after handling. Use only outdoors or in a well- ventilated area. Wear protective gloves, eye protection, and face protection. lF ON SKIN: Wash with plenty of water. lF INHALED: Remove victim to lresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. lF lN EYES: Rinse cautiously with water lor several minutes. Remove contact lenses, il present and easy to do. Continue rinsing. lt skin irritation occurs: Get medical attention. ll eye irritation persists: Get medical attention. Take off contaminated clothing. Product name: LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterlace Page 1 of 7 IDH number: 548993 Storage: Disposal: Store in a well-ventilated place" Keep container tightly closed. Store locked up. Protect lrom sunlight. Do not expose to temperatures exceeding 5O"C1122'F. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classilication complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling ol Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s)CAS Number Percentage* Hydrocarbons, C9-C10, n-alkanes, isoalkanes. cvclics. <2olo aromatics 64742-48-9 60-80 Dibutvl ether 142-96-1 10 - 30 Propane 74-98-6 10 - 30 Hvdrocarbons. C7-C9. isoalkanes 1174921-67-5 1-5 Reaction product of tris(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane lPDMS) 1432471-92-5 1-5 . Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES lnhalation: Skin contact: Eye contact: lngestion: Symptoms: Notes to physician: Move to fresh air. ll breathing is difficult, give orygen. lf not breathing, give artilicial respiration. Get medical attention. Remove contaminated clothing and footwear. lmmediately flush skin with plenty of water (using soap, if available). lf symptoms develop and persist, get medical attention. Wash clothing belore reuse. Rinse immediaiely with plenty ol water, also under the eyelids, for at least 15 minutes. Get medical attention. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. lf vomiting occurs, prevent aspiration by keeping the patient's head below the knees. Get medical attention. See Section 11. This material is an aspiration hazard. Potential danger from aspiration must be weighed against possible oral toxicity when deciding whether to induce vomiting. 5. FIRE FIGHTING MEASURES Extinguishing media: Special f irefi ghting procedures: Water spray (fog), foam, dry chemical or carbon dioxide. Do not use high volume water jet. Wear self-contained breathing apparatus and lull protective clothing, such as lum-out gear. Water may be unsuitable as an extinguishing media, but may be helpful in keeping adiacent containers cool. Keep personnel upwind of fire. Product name: LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterlace Page 2 ol 7 IDH number: 548993 Unusual fre or explosion hazards:Contents under pressure. Do not puncture or incinerate pressurized containers. Containers exposed to fire should be cooled with water to prevent vapor pressure buildup which could result in container rupture. lf a leak or spill has not ignited, use water spray to disperse vapors. The liquid is volatile and gives ofl invisible vapors. Vapors may lorm explosive mi)dures with air. Do not handle or store near an open flame, heat or other sources of ignition. Hydrocarbon solvents are basically non-conductors of electricity and can become electrostatically charged during mixing, Iiltering or pumping at high Ilow rates. lf this charge reaches a significantly high level, sparks can form that may ignite vapors ol flammable liquids. Oxides of carbon. Oxides of nitrogen. Acrid smoke and fumes. Collect contaminated fire extinguishing water separately. This musl not be discharged into drains. Hazardous combustion products: 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions:Do not allow product to enter sewer or waterways. Prevent further leakage or spillage if safe lo do so. Advise authorities if product has entered or may enter sewers, water sources or extensive land areas. This product is insoluble in water and will float on sudace. Remove all sources of ignition. Ventilate area. Keep upwind ol the spilled material and isolate exposure. Soak up with inert absorbent material (e.9. sand, silica gel, acid binder, universal binder, sawdust). Store in a closed container until ready for disposal. Vapors are heavier than air and may travel along the ground or be moved by ventilation and subsequently ignited by heat, pilot lights or other ignition sources at locations distant lrom the material handling point. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Clean-up methods: 7. HANDLING AND STORAGE Handling: During use and until all vapors are gone: Keep area ventilated - do not smoke; exlinguish all flames, pilot lights, and heaters; turn ofl stoves, electrical tools and appliances, and any other sources of ignition. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly alter handling. Do not taste or swallow. Do not puncture or incinerate :::i::i;: j :"*:l?li?;5551,,i,'*:![3[3; 5ll ""t #:il:#l?ji":'" " """" Storage: For safe storage, store at or below 48.8 'C (1 1 9.8 "F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready Ior use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. IDH number: 548993 Product name: LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterlace Page 3 ol 7 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s)ACGIH TLV OSHA PEL AIHA WEEL OTHER Hydrocarbons, C9-C1 0, n-alkanes, isoalkanes. cvclics. <2% aromatics None None None None DabuWl ether None None None None Propane u: srmple asphyxiant, EX: Explosion hazard (Simole asphvxiant.) 1,000 ppm (1,800 mg/m3) PEL None None Hvdrocarbons. C7-C9. isoalkanes None None None None Reaction product ol tris(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane (PDMS) None None None None Engineering controls: Respiratory protection: Eyellace protection: Skin protection: Use explosion-proof mechanical ventilation and local exhaust to control contaminants to within their occupational exposure limits during the use of this product. Use a NIOSH approved supplied air respirator with an organic cartridge if the potential to exceed established exposure limits exists. Safety goggles or salety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Salety showers and eye wash stations should be available. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevenl skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling poinUrange: Melting poinU range: Specilic gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Evaporation rate: Solubility in water: Partition coefficient (n-octanolAivater): VOC content: Viscosity: Decomposition temperature: Aerosol Clear colorless Mitd Not available. Not applicable 1551 - 1809 mm hg Not available. Not available. 0.74 Base only 3.85 Approximately E)dremely Flammable.ASTM D 3065 Not available. Not available. Not available. Extremely Ilammable aerosol. 0.43 (Ether = 1) Slight Not available. 99.8oki740 g/l EPA Method 24 Not available. Not available. Product name: LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterlace Page 4 ol 7 IDH number: 548993 10. ST AND REACTIVITY Stability: Risk of ignition.Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Hazardous decomposition Oxides ol carbon. Traces ol Ammonia. Hydrocarbons. products: lncompatible materials: Strong oxidizing agents. Strong acids and strong bases. Humid air. Waler. Reactivity: Conditions to avoid: Not available. Heat, flames, spafts and other sources of ignition. Store away from incompatible materials. Vapours may lorm explosive mixture with air. Exposure to air or moisture over prolonged periods. Fire or intense heat may cause violent rupture of packages. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, lnhalation, Eyes, lngestion Potential Health Effects/Symptoms lnhalation: Vapors and mists will irritate nose and throat and possibly eyes. Central nervous system depression, including dizziness, drowsiness, latigue, nausea, headache, unconsciousness. Skin contact: Causes skin irritation. Solvent action can dry and delat the skin, causing the skin to crack, leading to dermatitis. Eye contact: Causes serious eye irritation. lngestion: May cause gastrointestinal tract irritation if swallowed. Aspiration may occur during swallowing or vomiting, resulting in lung damage. Central nervous system depression, including dizziness, drowsiness, fatigue, nausea, headache, unconsciousness. Hazardous Component(s)LD50s and LC50s lmmediate and Delayed Health Eflects Hydrocarbons, C9-C1 0, n-alkanes, isoalkanes. cvclics. <2% aromatics lnhalation LC50 (Rat, 4 h) = > 5.36 mg/l lnhalation LC50 (Ral, 4 h) = > 8.530 mq/m3 No Data Dibutyl ether None lrritant, Central neryous system, Cardiac, Kidnev, Gastrointestinal, Mutaqen Propane None Cardiac. Central nervous svstem. lrritant Hvdrocarbons. C7-C9. isoalkanes None No Data Reaction product of tris(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane (PDMS) None No Data Hazardous Component(s)NTP Carcinogen IARC Carcinogen usl.lA uarcrnogen (Specifically Regulated) Hydrocarbons, C9-C1 0, n-alkanes, isoalkanes. cvclics. <Zok aromatics No No No Dibutvl ether No No No Prooane No No No Hvdrocarbons. C7-C9, isoalkanes No No No Reaction product ol tris(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane /PFl[rS) No No No 12. ECOLOGICAL INFORMATION Ecological information:Nol available. IDH number: 548993 Product name: LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterface Page 5 of 7 13. DISPOSAL CONSIDERATIONS lnformation provided is for unused product only. Recommended method of disposal: Do not punclure or incinerate pressurized containers. Follow all local, state, federal and provincial regulations tor disposal. Hazardous waste number: D001: lgnitable. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the materiaUformulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Aerosols Hazard class or division: 2.1 ldentification number: UN 1950 Packing group: None lnternational Ar Transportation (ICAO/IATA) Proper shipping name: Aerosols, flammable Hazard class or division: 2.1 ldentification number: UN 1950 Packing group: None Water Transportation (lMO/lM DG) Proper shipping name: AEROSOLS Hazard class or division: 2.1 ldentification number: UN 1950 Packing group: None 15. REGULATORY INFORMATION United States Regulatory lnformation TSCA 8 (b) lnventory Status: All components of this product are listed on the U.S. Toxic Substances Control Act (TSCA) inventory or are exempt f rom listing because a Low Volume Exemption (LVE) has been granted in accordance with 40 CFR 723.50. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis. CERCLA/SARA Section 3'l'11312: Fire, lmmediate Health, Delayed Health, Pressure CERCLA/SARA Section 313: None above reporting de minimis. CERCLA Reportable quantity: Dibutyl ether (CAS# 142-96-'l ) 100 lbs. (a5.a kg) Propane (CAS# 74-98-6) 100 lbs. (as.a kg) California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory lnformation CEPA DSUNDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: 3, '15 Prepared by: Product Salety and Flegulatory Aflairs lssue date: 0412512019 IDH number: 548993 Product name: LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterlace Page 6 of 7 DISCLAMER: The data contained herein are fumished fror inlormation only and are believed to be reliable. However, Henkel Corporation and its affiliates ('Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. lt is the use/s responsibility to determine the suitability ol Henkel's products or any production methods mentioned herein lor a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel's products. ln light of the foregoing, Henkel specilically disclaims all warranties, express or irnplied, including warranties of merchanlability and litness for a particular purpose, arising from sale or use of Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides information in accordance with U.S. lederal law only. No warranty or representation of any kind is given with respect to the substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the substantive export or other law of any other lurisdiction pfior to export. Please contact Henkel Product Salety and Regulatory Affairs lor additional assistance. Product name: LOCTITE FREKOTE 700-NC known as Frekote@ 700-NC Releasing lnterface PageT ol7 IDH number: 548993 SAFETY DATA SHEET Randolph Products Company TT-]-735A ISOPROPYL ALCOHOL, GR.A-GALLON te Printed: 1 /8/2021 Page 3 of 10 IARC: No component of this product present at l-evels greaLer than or equal to 0.1% is identif i-ed as probably, poss j-ble or confirmed human carcinogen by IARC. ACGIH: No component of this product present at feve-l-s greater than or equal to I O.fz is idenLified as a carcinogen or potential carclnogen by ACGIH. OSHA: No component of this product present at l-evels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP: No component of this product present at level-s greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Teratology (Birth Defects) fnformation: ]NFORMATION NOT AVAILABLE. Reproduction f nformation : INFORMATION NOT AVAILABLE. Aggravation of Pre-Existing Conditions: rrmit.iti-s or oLher skin condi-tions. 3. Coqrosition,/Information on Ingredients Component ISOPROPYL ALCOHOL ACGIH: 200 PPM TWA ACGIH: 4OO PPM STEL OSHA: 400 PPM TWA OSHA: 500 PPM CEILING 4- First Aid Measures CAS# 61 -63-0 % by Wt. 100 If in eyes: Rinse cautiously with water for severa.l- minutes. Remove contact lenses, if present and easy to do. Continue rins j-ng . f f eye irritation persists: Get medical- advj-ce,/attention. Skin: If on skin: wash with plent.y of soap & water. If skin irritation occurs: Get Medical- advice/attention. ke off contamj-nated clothing and wash it before reuse. SAFETY DATA SHEET Randolph Products Company TT-I_7354 ISOPROPYL ALCOHOL, GR.A-GALLON Date Printed: 1 /B/202L Page 4 of 10 Ingestion: If swallowed: Immediately calJ- a poison center,/physj-cian. Do NOT induce vomiting. fnhafation: If inhaled: Remove person to fresh air and keep comfortable for breathrng. CaII a poison controf center/get medj-cal- attention if you feel unwefl. Note Lo Physicians: INEORMATION NOT AVA]LABLE. 5. Eire Fighting Measures Elammable Properties: Flash Poi-nt : 53 F Method: Explosive Limits: Lower explosive limitt 2.0 Upper explosive l-imit: 72.0 Autoignition Temperature : INFORMAT]ON NOT AVAILABLE. Hazardous Combustion Products : Smoke, soot and carbon droxide, carbon monoxide. Extinguishing Media: Dry chemical-, CO2, Halon, Foam Elrefighting Procedures : Special Fire-Eighting Procedures: Wear self-contained breathing apparatus and protective clothing. Unusuaf Fire and Explosion Hazards: Hrgh temperatures can cause sealed containers to rupture due to a build up of internal pressure. Cool- with water spray. Vapors are heavier than air and can travel some distance away and flash back. Sensitivity to Statlc Discharge: MateriaJ- may accumul-ate a static charge which could act as an ignition source. Precautions shoul-d be taken when pouring to mi-nimize splash/free faff . 6. Accidental Release Measures Small Spill: See Information for Large Spi11, below: Large SpiII: Use personal protecti-ve equipment. Ensure adequate ventilation. Remove al-I sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumufating to form explosive concentrations. Vapors can accumufate in low areas. Environmental- Precautions : SAFETY DATA SHEET Randolph Products Compony TT-]-735A ISOPROPYL ALCOHOL, GR.A-GALLON te Printed: 1/8/2027 Page 5 of 10 ]NEORMATION NOT AVAILABLE. Methods/Material-s for Containment and Cleaning Up: Conta:-n spi11age, and then cof fect wit.h non-combustlble absorbent material-, (e.9. sand earth, diatomaceous earth, vermiculite) and place in container for disposaJ- accordi-ng to IocaI/state,/federal- regulatrons . 7. Handling and Storage Handling: Keep away from heat, sparksr open flames, hot surfaces. NO SMOKING. Keep container tightly cl-osed. Ground/bond container and receiving equipment. Use explosion-proof electrical,/venti-lating/Iiqht j-nqlprocessing equipment. Use only non-sparking too1s. Take precautionary measures against static discharge. Wear protective gloves/eye protection/face protection. Storage: Prevent unauthorized access. .ore j-n a well- ventrlated pJ-ace. ep container tightly closed. Keep coo1. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: SEE SECTION 3 FOR THIS INFORMATION Engineering Controls: Ventil-ation: Good general ventilation (typicalJ-y 10 air changes per hour) shoul-d be used. Ventilation rates should be matched to conditions. Ventilation should be explosion proof. Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in special circumstances such as poorly ventilated spaces, spray painLing, mechanical generation of dusts, heating, drying, etc. Personal- Protective Equipment Respiratory Protection: If englneering controls do not maintain airborne concentrations to an cceptable l-evel, an approved respirator must be worn. In the Unj-ted States of America, i-f resp:-rators are used, a program shoufd be instituted to assure compliance SAFETY DATA SHEET Randolph Products Company TT-I-735A ISOPROPYL ALCOHOL, GR.A_GALLON Date Printed: 1/B/2027 Page 5 of 10 with OSHA Standard 63 CER 1152, January 8, 1998. Respirator type: Organic Vapor. Skin Protection: Wear impervious gloves to prevent skin contact. Recommended Decontamination Eacilities: eye bath, washing facilities, safety shower. Eye Protection: Chemical- safety goggles or glasses with side shields. 9. Physical and Chemica1 Properties Boiling Point: 180 E MeJ-ting Point: INEORMATION NOT AVAILABLE. Freezing Point: n/a Vapor Pressure: fnformation not avail-able for mixture Vapor Density: HEAVIER THAN AIR Solubi-l-ity in Water: NEGLIG]BLE Evaporation Rate: SLOWER THAN ETHER Specif ic Gravity z .'7 8'l Weight per Gal1on: 6.55 l-b/qL Coati-ng VOC: 6 . 55 1blq1 Material- VOC: 6.55 Lb/ql Odor: MiId sofvent odor. Appearance: Liquid. Partition Coefficient : INEORMATION NOT AVA]LABLE. 10. Stabil.itv and Reactivity Chemical- Stability (Conditions to Avoid): Stabl-e under normal storage/use conditions. Incompatibility: Avoid strong oxidizing agents, acids and afkalies. Hazardous Decomposition Products: SAFETY DATA SHEET Randolph Products Company TT-I-735A ISOPROPYL ALCOHOL, GR.A-GALLON te Printed: 1/B/202L Page 7 of 10 INEORMATION NOT AVAILABLE. Hazardous PoJ-ymerization : WilI not occur under normal conditions. 11. troxico1ogica]- Infor:oation Eye Irritation,/Damage: Component 67-63-0: Serj-ous eye irritation, Category 2 Skin Irritation/Damage : ComponenL 61- 53-0: LD50: 12,800 mq/kq, rat. Not categorized. Mild skin irritation, Not Categorized. Acute Oral- Toxicity: ComponenL 61- 63-0: LD50: 5045 mq/kq, rat. Not categorized ute Inhalation Toxicity: Component 67-63-0: LC50: 16000 ppmv, rat. Category 4 Respiratory/Skin Sensitization : ComponenL 61- 63-0: No evidence of respiratory or skin sensitization. Carci-nogenicity : Component 67-63-0: Not l-isted as a carcinogren by IARC, NTP, OSHA or ACGIH Reproductive Toxicity : Component 61- 63-0: No evidence of human reproductive toxicity. Germ Cel-l- Mutaqenicity: ComponenL 61-63-0: , data SAFETY DATA SHEET Randolph Products Company TT-I-735A ISOPROPYL ALCOHOL, GR.A-GALLON Date Printed: 1 /8/2021, Page 8 of 10 Aspiration Toxicity: Component 67-63-0: Not classified as an Aspirati-on Hazard STOT-single exposure ComponenL 61- 63-0: No data STOT-repeated exposure Component 67-63-0: No Data Routes of Exposure: Inhal-ation of vapors, sk:-n/eye/mucous membrane absorption, ingestion. 12. Eco].oqical Info:nnation Environmental Toxicity : ComponenL 61-63-0: LC50: >1400 mq/I (fish) Persistance & degradability: Component 67-63-0: No Data Bioaccumulative potential : Component 67-63-0: No Data Mobility in soil: Component 67-63-0: No data Other Adverse Ecological Effects: No information 13. Disposal Considerations Waste Disposal Method: Discharge, treatment or dj-sposal is subject Lo national, state, or local laws. When a decision is made to discard this material- as supplied, it meets RCRA's characteristic definition of ignitabj-1ity. The toxicity characteristi-c (TC) has not been evaluated by the Toxicity Characteristic Leaching Procedure (TCLP). SAFETY DATA SHEET Randolph Products Company TT-I-735A ISOPROPYL ALCOHOL, GR.A-GALLON te Printed: 1/B/202L Page 9 of 10 Federal- Regulations may appfy to empty container. State and,/or l-ocal regulations may be different. Of the methods of disposal currently available, it i-s recommended that an alternative be sel-ected according to the following order of preference, based upon environmental acceptability: (1) recycle or rework, if feasibl-e; (2) incinerate at an authorized facili-ty; or (3) treat at an acceptabJ-e wasLe treatment facility Be sure to contact the appropri-ate qovernment environmental agencies if further guidance is requl-red. L4. Transport Information Domestic (Land, DOT), Internationaf (Water, IMO/IMDG), International (Air, ICAO) Road and Raj-I (ADR/RID) , Air (ICAo/IATA) , Vessel (IMo/IMDG) : DOT (USA) Shipping Name: Isopropyl Alcohol UN/NA ID No: UN1219 Hazard CIass: Class 3 (IATA/49CFR) Packing Group: II Lvironmental Hazards: INFORMATION NOT AVAILABLE. Marine Pof l-utant: Components of this product do not appear on the l-i-st of Marine Pollutants (49CER 712.1,07) Special Precautions for User: INFORMATION NOT AVAILABLE. 15. Requ1atory Information U. S. Federal Regulations: TSCA: A11 components of this material- are on the US TSCA 8(b) Inventory or are exempt from listing. OSHA: Thi-s product is hazardous under OSHA's Hazard Communication Std. Not regarded as a heal-th hazard under current legislation. CERCLA: SARA Hazard Category: INFORMATTON NOT AVAILABLE. Section 313:rr*rr Indicates toxic chemj-ca1 (s) subject to the reportj-ng requirements of ecti-on 313 of Title III and of 40 CER 372. rternational Regulations : Canadian WHMIS: INFORMAT]ON NOT AVAILABLE. SAFETY DATA SHEET Randolph Products Company TT-I-735A ISOPROPYL ALCOHOL, GR.A-GALLON Date Printed: 1 /B/2027 Paqe 10 of 10 Canadian Envj-ronmental Protection Act (CEPA) : INFORMATION NOT AVAILABLE. EINECS: INFORMATION NOT AVAILABLE. State Regulati-ons: INEORMATION NOT AVAILABLE. Vofatile Organic Compounds: COATING VOC content is being expressed as mass of VOC per unit volume of coating Less water and exempt solvenLs, where appJ-icab1e. MATERIAL VOC content is the actual weight of VOC per unit volume. L6- Other Information Date Revi-sed: 03/26/\9 Prepared By: Regulat.ory Compll-ance Information Contact: Regulatory Compliance 473-592-479L ext 106 Manufacturer Di-sclaimer : USERS RESPONSIBfLITY: A bul-l-etj-n such as this cannot be expected to cover afl possible indivrdual situations. As the user has the responsibiJ-ity to provide a safe workplace, all aspects of an individual operation shoul-d be examined to determi-ne if, or where, precautions - in addition to those described herej-n - are required. Any health hazard and safety informati-on herein shoufd be passed on to your customers or employees, as the case may be. DISCLAIMER OE LIABILITY: The information contained herein is, to the best of our knowledge and belief. accurate. However, since the condj-tions of handling and use are beyond our control, we make no guarantee of resuJ-ts, and assume no J-iability for damages incurred by use of this material-. All chemicals may present unknown health hazards and shoul-d be used with caution. Afthough certain hazards are described herein, we cannot guarantee that these are the only hazards whj-ch exist. Final determination of suitabil-ity of the chemi-cal is the sole responsibility of the user. No representations or warranties, either expressed or l-mplied, of merchantability, fitness for a parLicular purpose or any other nature are made hereunder wi-th respect to the information contained herein or the chemical to which the information refers. These data rel-ate only to the speci-fic material designated herein and do not relate to use in combination with any other material. It is the responsibility of the user to comply with all appli-cabIe federal-, state and local laws and reguJ-atl-ons. End of Material Safety Data Sheet www. srgmaaldflch,com Version 6.3 Revision Date OB / 02 / 2O2l Print Date 09/L6/2O21 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Productidentifiers Product name Product Number Brand Index-No. CAS-No. L.2 Relevant identified Identified uses against Details of the supplier of Acetone 00585 Fluka 606-001-00-8 67-64-L uses of the substance or mixture and uses advised : Laboratory chemicals, Synthesis of substances 1.3 Company Telephone Fax 1.4 Emergencytelephone Emergency Phone # the safety data sheet Sigma-Aldrich Inc. 3O5O SPRUCE ST ST. LOUIS MO 63103 UNITED STATES +1 314 771-5765 +1 800 325-5052 800-424-9300 CHEMTREC (USA) + 1-703- 527 -3887 CHEMTREC (Internation al) 24 Hours/day; 7 Days/week SECTION 2: Hazards identification 2.L Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Flammable liquids (Category 2), H225 Eye irritation (Category 2A), H319 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 GHS Label elements, including precautionary statementsPictosram a$ai)\7V Signal word Fluka - 00585 Danger Page 1 of 12 The life science business of Merck operates as MilliporeSigma in the KGaA, Darmstadt, Germany US and Canada ?vlittiPOResiG?\,la Hazard statement(s) H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Precautionary statement(s) P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P24O Ground/bond container and receiving equipment. P24t Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P26L Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P277 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant. 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none SECTION 3: Composition/information on ingredients 3.1 Substances Formula Molecular weight CAS-No. EC-No. Index-No. C3H6o 58.08 g/mol 67-64-7 200-662-2 606-001-00-8 Comoonent Classification Concentration acetone Flam. Liq. 2; Eye Irrit. 2A; STOT SE 3; H225, H319, H336 Concentration limits: >= 20 o/o: STOT SE 3, H336; <= 100 o/o Fluka - 00585 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada Page 2 of L2 ?vtittiPOResiG}vla For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: First aid measures 4.L Description of first-aid measures General advice Consult a physician. Show this material safety data sheet to the doctor in attendance.Move out of dangerous area. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures 5.1 Extinguishingmedia Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Furtherinformation Use water spray to cool unopened containers. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. Fluka - 00585 page 3 of 12 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada lYtittipoResiGlvta 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet- brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Advice on protection against fire and explosion Use explosion-proof equipment.Advice on protection against fire and explosion Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): 3: Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1,2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection 8.1 Control parameters control Component CAS-No.Value Control Darameters Basis acetone 57-54-7 TWA 250 ppm USA. ACGIH Threshold Limit Values (TLV) Remarks Not classifiable as a human carcinoqen STEL 500 ppm USA. ACGIH Threshold Limit Values (TLV) Not classifiable as a human carcinoqen Fluka - 00585 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada Page 4 of L2 MiuipoResiGlYta TWA 250 ppm 590 mq/m3 USA. NIOSH Recommended Exoosure Limits TWA 1,000 ppm 2,400 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants STEL 1,000 ppm 2,40O mglm3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 19 10.1000 TWA 750 ppm 1,800 mg/m3 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 C 3,000 ppm California permissible exposure limits for chemical contaminants (Title 8, Article 107) PEL 500 ppm 1,200 mglm3 California permissible exposu re limits for chemical contaminants (Title 8, Article 107) STEL 750 ppm 1,780 mglm3 California permissible exposure limits for chemical contaminants (Title 8, Article 107) Bio !imits Component CAS-No.Parameters Value Biological snpcimpn Basis acetone 67-64-r Acetone 25 mgll Urine ACGIH - Biological Exposure Indices (BEI) Remarks End of shift (As soon as possible after exDosure ceases) Predicted No Effect Concentration PNEC 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eyelface protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Fluka - 00585 Page 5 of 12 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada lvtittipoRe Soil 33.3 Sea water 1.05 mo/l Fresh water 10.6 mq/l Sea sediment 3.04 mo/ko Fresh water sediment 30.4 mo/ko Onsite sewaqe treatment plant 100 mq/l siGh/la Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material : butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 480 min Material tested:Butoject@ (KCL 897 / Aldrich 2677647, Size M) Splash contact Material : butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 480 min Material tested:Butoject@ (KCL 897 / Aldrich 2677647 , Size M) data source: KCL GmbH, D-36L24 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Impervious clothing, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full- face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Contro! of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid, clear Color: colorless b) Odor No data available c) Odor Threshold No data available d) pH No data available e) Melting Melting point/range: -94 oC (-137 oF) - lit. point/freezing point f) Initial boiling point 56 oC 133 oF at 1,013 hPa - lit. and boiling range Fluka - 00585 page G of 12 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada tvtittipoResiGhaa S) Flash point -17.0 oC (1,4 oF) - closed cup h) Evaporation rate No data available i) Flammability (solid, No data available gas) j) Upper/lower Upper explosion limit: 13 o/o(V) flammability or Lower explosion limit: 2 %(V) explosive limits k) Vapor pressure 533.3 hPa at 39.5 oC (103.1 oF) 245.3 hPa at 20.0 oC(68.0 oF) l) Vapor density No data available m) Density 0.79 g/cm3 at 20 oC (68 oF) Relative density No data available n) Water solubility completely miscible o) Partition coefficient: log Pow: -0.24 n-octanol/water p) Autoignition 465.0 oC (869.0 oF) temperature q) Decomposition No data available temperature r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Surface tension 23.2 mN/m at 20.0 oC (68.0 oF) SECTION 1O: Stability and reactivity 1O.1 Reactivity No data available 1O.2 Chemacal stability Stable under recommended storage conditions. 1O.3 Possibility of hazardous reactions Vapors may form explosive mixture with air. 1O.4 Conditions to avoid Heat, flames and sparks. 1O.5 Incompatible materials Bases, Oxidizing agents, Reducing agents, Acetone reacts violently with phosphorous oxychloride. 1O.6 Hazardous decomposition products In the event of fire: see section 5 Fluka - 00585 The life science business of Merck KGaA, Darmstadt, Gernrany operates as MilliporeSigma in the US and Canada Page 7 of t2 tvtittiPOResiGI\/Ia SECTION 11: Toxicological information 11.1 Information on toxicologica! effects Acute toxicity LD50 Oral - Rat - female - 5,800 mglkg Remarks: (ECHA) LC50 Inhalation - Rat - 4 h - 76 mg/l Rema rks : Unconsciousness Drowsiness Dizziness (External MSDS) LD50 Dermal - Rabbit - 20,000 mglkg Remarks: (IUCLID) No data available Skin corrosion/irritation Skin - Rabbit Result: Mild skin irritation - 24 h (Draize Test) Remarks: (RTECS) Serious eye damageleye irritation Eyes - Rabbit Result: Eye irritation - 24 h (Draize Test) Remarks: (RTECS) Respiratory or skin sensitization Maximization Test - Guinea pig Result: Not a skin sensitizer. Remarks: (ECHA) Chronic exposure may cause dermatitis. Germ cell mutagenicity Test Type: Mutagenicity (mammal cell test): chromosome aberration. Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative Test Type: Ames test Test system : Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 477 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Mouse lymphoma test Metabolic activation : without metabolic activation Method: OECD Test Guideline 476 Result: negative Carcinogenicity IARC: No ingredient of this product present at levels greaterthan or equal to 0.1olo is identified as probable, possible or confirmed human carcinogen by IARC. NTP: No ingredient of this product present at levels greater than or equal to 0.1olo is Fluka - 00585 Page 8 of 12 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada ?YtittiPOResiG}Vla identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1olo is on OSHA's list of regulated carcinogens. Reproductive toxicity No data available Specific target organ toxicity - single exposure Inhalation - May cause drowsiness or dizziness. - Narcotic effects Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available 11.2 Additional Information RTECS: A13150000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. After absorption: Headache Salivation Nausea Vomiting Dizziness narcosis Coma Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. Kidney - Irregularities - Based on Human Evidence Skin - Dermatitis - Based on Human Evidence Kidney - Irregularities - Based on Human Evidence Skin - Dermatitis - Based on Human Evidence SECTION 12: Ecologica! information 12.1 Toxicity Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 6,270 mg/l - 96 h (OECD Test Guideline 203) Toxicity to daphnia static test LC50 - Daphnia pulex (Water flea) - 8,800 mg/l - 48 h and other aquatic Remarks: (ECHA) i nvertebrates Fluka - 00585 Page 9 of 12 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada fvlittiPORQsiG}Vla Toxicity to algae static test NOEC - M.aeruginosa - 530 mgll - 8 d (DrN 38412) Remarks: (maximum permissible toxic concentration) (rucLrD) Toxicity to bacteria static test EC5O - activated sludge - 61.15 mgll - 30 min (OECD Test Guideline 209) 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 97 o/o - Readily biodegradable. (OECD Test Guideline 301B) Biochemical Oxygen 1,850 mglg Demand (BOD) Remarks: (IUCLID) Chemical Oxygen 2,070 mg/g Demand (COD) Remarks: (IUCLID) Theoretical oxygen 2,200 mg/g demand Remarks: (Lit.) 12.3 Bioaccumulative potential Does not bioaccumulate. 12.4 Mobility in soi! No data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects SECTION 13: Disposal considerations 13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information DOT (US) UN number: 1090 Class: 3 Proper shipping name: Acetone Reportable Quantity (RQ): 5000 lbs Poison Inhalation Hazard: No IMDG Fluka - 00585 Packing group: II The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada Page 10 of 12 MittipoResiG?Yla UN number: 1090 Class: 3 Proper shipping name: ACETONE IATA UN number: 1090 Class: 3 Proper shipping name: Acetone Packing group: II EMS-No: F-E, S-D Packing group: II SECTION 15: Regulatory information SARA 3O2 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 3 13. SARA 31,Ll3LZ Hazards Fire Hazard, Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components acetone Pennsylvania Right To Know Components acetone New Jersey Right To Know Components acetone CAS-No. 67-64-1 CAS-No. 67-64-t CAS-No. 67-64-t Revision Date 1993-02-16 Revision Date 1993-02- 15 Revision Date 1993-02-15 California Prop. 65 Components This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. SECTION 16: Other information Further information Copyright 2020 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. Fluka - 00585 page 11 of 12 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada ?YlittiPOResiGh/la The branding on the header and/or footer of this document may temporarily not visually match the product purchased as we transition our branding. However, all of the information in the document regarding the product remains unchanged and matches the product ordered. For further information please contact mlsbranding@sial.com. Version: 6.3 Revision Date: 08/02/202L Print Date: O9/76/202L Fluka - 00585 The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada Page !2 of tz MittipoRe!i:Gt\rla Safety Data Sheet lssue date: 02/02/2018Revision Number: 005.0 1. PRODUCT AND COMPANY IDENTIFICATION Product name:LOCTITE FREKOTE B-15 known as FREKOTE B-15 PT CN IDH number: Item number: Region: 420430 83493 United States Product type: Mold Release Restriction of Use: None identilied Company address: Henkel Corporation Henkel Way One Rocky Hill, Connecticut 06067 Contact information: Telephone: +1 (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) oill-303-592-171 1 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 I nternet: www. henkelna.com Contains one or more components for which a Toxic Substances Control Act (TSCA) Low Volume Exemption (LVE) applies. See Section'15. 2. HAZARDS IDENTIFICATION WARNING: EMERGENCY OVERVIEW FLAMMABLE LIQUID AND VAPOR. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE RESPIRATORY IRRITATION. HAZARD CLASS HAZARD CATEGOBY FLAMMABLE LIOUID J SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSUHE e Precautionary Statements Prevention: Response: Storage: Disposal: IDH number: 420430 Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container tightly closed. No release into water. Use explosion-proof equipment. Use non-sparking tools. Take aclion to prevenl static discharges. Avoid breathing vapors, misl, or spray. Wash affected area thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye prolection, and lace proteclion. lf on skin (or hair): Take ofl immediately all contaminated clothing. lF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. lF lN EYES: Rinse cautiously with water lor several minules. Remove contact lenses, if present and easy to do. Continue rinsing. lf skin irritation occurs: Get medical attention. lf eye irritation persists: Get medical attention. Take otf contaminated clothing. ln case of fire: Use foam, dry chemical or carbon dioxide to exlinguish. Store in a well-ventilaled place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local govemmental regulations. Producl name: LOCTITE FREKOTE B-15 known as FREKOTE B-15 PT CN Page 1 of 6 Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s)CAS Number Percentage* Dibutvl ether 142-96-1 90 - 100 Reaction product of tris(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane (PDMS) 1432471-92-5 1-5 ' Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections 4. FIRST AID MEASURES lnhalation: Move to lresh air. lf breathing is difficult, give oxygen. lf not breathing, give artificial respiration. Gel medical attention. Skin contact: lmmediately wash skin thoroughly with soap and water. Remove contaminated clothing and lootwear. ll symptoms develop and persist, get medical attention. Wash clothing belore reuse. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. lngestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray (log), Ioam, dry chemical or carbon dioxide. Do not use high volume water jet. Special firefighting procedures: Wear self-contained breathing apparatus and lull protective clothing, such as turn-out gear. Water may be unsuitable as an extinguishing media, but may be helplul in keeping adiacent containers cool. Keep personnel upwind of fire. Unusual fire or explosion hazards: Vapors may form explosive mixtures with air. Do not handle or store near an open llame, heat or other sources of ignition. This product may form explosive peroxides. Hydrocarbon solvents are basically non-conductors ol electricity and can become electrostatically charged during mixing, filtering or pumping at high flow rates. ll this charge reaches a signilicantly high level, sparks can lorm that may ignite vapors of llammable liquids. IDH number: 420430 Product name: LOCTITE FREKOTE B-15 known as FREKOTE B-15 PT CN Page 2 ol 6 Hazardous combustion products:Oxides of carbon. lrritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Advise authorities il product has entered or may enter sewers, water sources or extensive land areas. Prevent lurther leakage or spillage il safe to do so. This product is insoluble in water and will float on surface. Clean-up methods: Remove all sources of ignition. Ventilate area. Keep upwind of the spilled material and isolate exposure. Soak up with inert absorbent material (e.9. sand, silica gel, acid binder, universal binder, sawdust). Store in a closed metal container until ready for disposal. Reler to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling:During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all flames, pilot lights, and heaters; tum off stoves, electrical tools and appliances, and any olher sources ol ignition. Make sure containers are properly grounded before use or transler ol material. Avoid contact with eyes, skin and clothing. Do not breathe gas/fumes/vapor/spray. Do not taste or swallow. Wash thoroughly alter handling. For operations where eye or face contact could occur, provide safety shower and eyewash fountain. For safe storage, store at or below 48.8 "C (1 1 9.8 "F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Storage: 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s)ACGIH TLV OSHA PEL AIHA WEEL OTHER Dibutvl ether None None None None Reaction product of tras(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane (PDMS) None None None None Engineering controls: Use explosion-proof mechanical ventilation and local exhausl to control contaminants to within their occupational exposure limits during the use ol this product. Bespiratory protection: Use a NIOSH approved supplied air respirator if the potential to exceed established exposure limits exists. Eyey'face protection: Salety goggles or salely glasses with side shields. Full face protection should be used it the potential for splashing or spraying ol product exists. Safety showers and eye wash stations should be available. Skin protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. IDH number: 420430 Product name: LOCTITE FREKOTE B-15 known as FREKOTE B-15 PT CN Page 3 of 6 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Colorless Odor: Mild, Solvent Odor threshold: Not available.pH: Not applicable Vapor pressure: 4.8 mm hg Boiling poinUrange: > 142'C (> 287.6 "F) Melting poinU range: Not available. Specific gravity: 0.769 Vapor density: Heavier than air Flash point: 25'C (77'F) Tagliabue closed cup Flammable/Explosive limits - lower: 1.5 % (value for solvent) Flammable/Explosive limits - upper: 7 .6 "/" (value f or solvent) Autoignition temperature: 194 "C (381.2 "F)Flammability: Not applicable Evaporation rate: Slower than ether. Solubility in water: lnsoluble Partition coefficient (n-octanolArater): Not available. VOC content: 99.5 %;746 gll Viscosity: Not available. Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions ol storage and use.May form explosive peroxides with prolonged exposure to air or oxygen, especially under anhydrous conditions. Hazardous reactions: Will nol occur. Hazardous decomposition Oxides of carbon. Hydrocarbons. lrritating organic vapours. products: lncompatible materials: Strong oxidizing agents. Strong acids and strong bases. Reactivity: Not available. Conditions to avoid: Exposure to air or moisture over prolonged periods. Heat, flames, sparks and other sources ol ignition. Store away lrom incompatible materials. 1 1. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, lnhalation, Eyes, lngestion IDH number: 420430 Product name: LOCTITE FREKOTE B-15 known as FREKOTE B-15 PT CN Page 4 of 6 Potential Health Effectsr/Symptoms lnhalation: May cause respiratory tract irritation. Skin contact: Causes skin irritation. Eye contact: Causes serious eye irritalion. lngestion: May cause gastrointestinal tract irriiation il swallowed. Hazardous Component(s)LD50s and LC50s lmmediate and Delayed Health Effects Dibutyl ether None lrritant, Central nervous system, Cardiac, Kidnev. Gastrointestinal. Mutaoen Reaction product of tris(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane (PDMS) None No Data Hazardous Component(s)NTP Carcinogen IARC Carcinogen usilA uarcrnogen (Specifically Regulated) Dibutvl ethel No No No Reaction product of tris(n- methylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane (PDMS\ No No No 12.INFORMATION Ecological information:Not available. 13. DISPOSAL CONSIDERATIONS lnformation provided is for unused product only. Recommended method of disposal: Follow all local, state, Iederal and provincial regulations lor disposal. Hazardous waste number: D001: lgnitable. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/conf iguration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Resin solution Hazard class or division: 3 ldentification number: UN 1866 Packing group: lll lnternational Air Transportation (lCAOfl ATA) Proper shipping name: Resin solution Hazard class or division: 3 ldentification number: UN 1866 Packing group: lll Water Transportation (lMO/lM DG) Proper shipping name: RESIN SOLUTION Hazard class or division: 3 ldentification number: UN 1866 Packing group: lll IDH number: 420430 Product name: LOCTITE FREKOTE B-15 known as FREKOTE B-15 PT CN Page 5 of 6 15. REGULATORY INFORMATION United States Regulatory lnformation TSCA 8 (b) lnventory Status: All components ol this product are listed on the U.S. Toxic Substances Control Act (TSCA) inventory or are exempt from listing because a Low Volume Exemption (LVE) has been granted in accordance with 40 CFR 723.50. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis. CERCLA/SARA Section 31'11312: lmmediate Health, Delayed Health, Fire CERCLA/SARA Section 3'13: None above reporting de minimis. CERCLA Reportable quantity: Dibutyl ether (CAS# 142-96-1) 100 lbs. (a5.4 kg) California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory lnformation CEPA DSUNOSL Status: One or more components are not listed on, and are not exempt lrom listing on either the Domestic Substances List or the Non-Domeslic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: 2, 3 Prepared by: Product Satety and Regulatory Affairs lssue date: 02/0212018 DISCLAMER: The data contained herein are tumished for inlormation only and are believed to be reliable. However, Henkel Corporation and its affiliates ("Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. lt is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein lor a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use ol any Henkel's products. ln light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties ol merchantability and fitness for a particular purpose, arising lrom sale or use ol Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 42O43O Product name: LOCTITE FREKOTE B-1 5 known as FREKOTE B-1 5 PT CN Page 6 of 6 SAFETY DATA SHEET Chemlease@ MPP 117 (7Sher? I rend Section 1. ldentification Product name : Chemlease@ MPP 117 Relevant identified uses of the substance or mixture and uses advised against Mold Primer Supplier's details : Chem-Trend LP 1445 W McPherson Park Dr PO Box 860, Howell M148844-0860 517-5464520 = +1 517 546 4520Emergency telephone number and Telephone number Section 2. Hazards identification OSHA/HCS status Glassification of the substance or mixture GHS labelelements Hazard pictograms Signalword Hazard statements This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (oral) - Category 3 ACUTE TOXICITY (dermal) - Category 3 ACUTE TOXICITY (inhalation) - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 24 SKIN SENSITIZATION - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 1B TOXIC TO REPRODUCTION (Unborn child) - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (central nervous system (CNS), optic nerve) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (eyes, hearing organs) - Category 2 ASPIRATION HAZARD - Category 1 9@@O Danger Highly flammable liquid and vapor. Toxic if swallowed, in contact with skin or if inhaled. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. May damage fertility or the unbom child. May be fatal if swallowed and enters ainuays. Causes damage to organs. (central nervous system (CNS), optic nerve) May cause drowsiness or dizziness. Date of issue/Date of revision :1f242020 Date of previous r.ssue : 112ffi,019 Version :2.01 1/13 Chemlease@ MPP 117 Section 2. Hazards identification May cause damage to organs through prolonged or repeated exposure. (eyes, hearing organs) Precautionary statements Prevention Obtain special instructions before use. Do not handle untilallsafety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Get medical attention if you feel unwell. lF exposed: Call a POISON CENTER or physician. lF INHALED: Remove person to fresh air and keep comfortable for breathing. Calla POISON CENTER or physician. lF SWALLOWED: lmmediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. lF ON SKIN (or hair): Take off immediately allcontaminated clothing. Rinse skin with water or shower. lF ON SKIN: Take off immediately allcontaminated clothing and wash it before reuse. Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Wash contaminated clothing before reuse. !f skin irritation or rash occurs: Get medical attention. lF lN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents and container in accordance with all local, regional, national and international regulations. None known. Response Storage Disposal Hazards not otherwise classified Section 3. Gomposition/information on ingredients Substance/mixture : Mixture lngredient name otto CAS number [rfethanol toluene Light aliphatic naphtha nonane 3-butorypropan-Z-ol dibutyltin dilaurate >25 - <50 >10 - <25 >10 - <25 <5 <3 <0.3 67-s6-1 1 08-88-3 111-84-2 5131€6-8 77-58-7 Section 4. First aid measures Descriotion of necessarv first aid measures Eye contact lnhalation : lmmediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. !f necessary, call a poison center or physician. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. lf it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. lf not breathing, if breathing is irregular or if respiratory anest occurs, provide artificial respiration or oxygen by trained personnel. lt may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. lf necessary, call a poison center or physician. lf unconscious, place in recovery position and get medical attention immediately. Maintain an open Date of issue/Date of revision :1t24f2020 Date of previous issue : 11f2M019 Version :2.01 2/13 Chemlease@MPP 117 Section 4. First aid measures Skin contact airway. Loosen tight clothing such as a collar, tie, belt or waistband. : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. lf necessary, call a poison center or physician. ln the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. : Get medicalattention immediately. Calla poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. lf material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and €use damage. Do not induce vomiting. lf vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. lf unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. lngestion Most important symotoms/effects. acute and delayed Potential acute health effects Eye contact lnhalation Skin contact lngestion Over-exoosu re si g ns/symptoms Eye contact !nhalation Skin contact Causes serious eye initation. Toxic if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Toxic in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Toxic if swallowed. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Adverse symptoms may include the following: pain or irritation watering redness Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetalweight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetalweight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetalweight increase in fetal deaths skeletal malformations lngestion ndication of immediate medica! attention and special treatment needed. if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Dateofissue/Dateofrevision :1f24f2020 Dateofpreviousr.ssue :11f2612019 Version :2.01 3/13 Chemlease@ MPP 117 Section 4. First aid measures Specific treatments Protection of first-aiders See toxicologica! information (Section 11) : No specific treatment. : No action shall be taken involving any personal risk or without suitable training. lf it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. lt may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Section 5. Fire-fighting measures Extinguishing media Su itable extinguishing media U nsuitable exting uishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective actions for fire-fighters Special protective equipment for fire-fighters Use dry chemical, COz, water spray (fog) or foam. Do not use water jet. Frghly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. ln a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Decomposition products may include the following materials: carbon dioxide carbon monoxide Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a fullface-piece operated in positive pressure mode. Section 6. Accidental release measures Personal orecautions. protective equipment and emergencv procedures For non-emergency : personnel For emergency responderc : Environmentalprecautions : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. lf specialized clothing is required to deal with the spillage, take note of any information in Section I on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Koid dispersal of spilled material and runoff and contact with soil, watenrays, drains and sewers. lnform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleanino uo Date of issue/Date of revision : 1f24t2020 Date of previous rssue :11t26f2019 Version :2.01 /t/13 Chembase@ MPP 117 Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. tpproach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages rnto an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Fut on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle untilall safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area. 'ncluding any Store in originalcontainer protected from direct sunlight in a dry, cool and well-ventilated ncompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Gontrol parameters Occuoational exoosure limits toluene nonane dibutyltin dihurate ACGIH TLV (United States, 312019). Absorbed through skin. TWA:200 ppm 8 hours. TWA:262 mg/m" I hours. STEL:250 ppm 15 minutes. STEL: 328 mg/mr 15 minutes. OSHA PEL (United States,512018). TWA:200 ppm I hours. TWA: 260 mg/m3 8 hours. ACGIH TLV (United States, 3/2019). TWA:20 ppm I hours. ACGIH TLV (United States, 3120191. TWA: 200 ppm I hours. TWA: 1050 mg/m3 8 hours. ACGIH TLV (United States,3/2019). Absorbed through skin. TWA:0.1 mg/m", (as Sn) 8 hours. Exposure limits Dateofissue/Dateofrevision :1f24t2020 Dateofpreviousissue :11f26f2019 Version:2.01 5/13 Chemlease@MPP 117 Section 8. Exposure controls/personal protection Appropriate eng ineering controls Environmental exposure controls lnd ividual orotection measures Eye/face protection Hand protection Body protection Other skin protection Respiratory protection STEL: 0.2 mg/ms, (as Sn) 15 minutes. OSHA PEL (United States, 512018l,. TWA: 0.1 mg/mS, (as Sn) I hours. Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. !n some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. lf contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufiacturer, check during use that the gloves are still retaining their protective properties. lt should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. ln the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certiflcation. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Section 9. Physical and chemical properties Physicalstate Liquid.Color Yellow. Odor Solvents Odor threshold Not available. pH Not available.Melting point Not available. Boiling point 66'C (150.8"F)Flash point Closed cup: 4'C (39.2'F) [ Tagliabue Closed Cupl Burning time Not applicable.Burning rate Not applicable. Evaporation rate Not available.Flammability (solid, gas) Not available. Date of issue/Date of revision : 124f2020 Date of previous r.ssue : 1 1f26f2019 Version : 2.01 il13 Chembase@MPP 117 Section 9. Physical and chemical properties Lower and upper explosive (flammable) limits Not available.Vapor pressure Not available. Vapor density >1 [Air = 1]Relative density 0.84 Solubility lnsoluble in the following materials: cold water. Solubility in water Not available. Partition coefficient: n- octanol/water Not available.Auto-ignition temperature Not available. Decomposition temperature Not available.SADT Not available. Viscosity Kinematic (40'C (104"F)): <0.2 cm2/s (<20 cSt) Volatility 91.06 Lower and upper explosive (flammable) limits ffinane Naphtha (petroleum), hydroheated light toluene methanol Lower: 0.8% Upper'. 2.9o/o Lower: 1.05Yo Upper: 7.60/o Lower: 1.1 % Upper: 7.1o/o Lower: 60/o Upper: 44o/o Section 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid lncompatible materials Hazardous decomposition products No specific test data related to reactivi$ available for this product or its ingredients. The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Reactive or incompatible with the following materials: oxidizing materials Formaldehyde and silicon dioxide may be evolved at elevated temperatures. Section 1 1. Toxicological information lnformation on toxicological effects Acute toxicitv Date of issue/Date of revision :1f24t2020 Date of previous rlssue :112il2019 Version :2.01 7/13 Chemlease@MPP 117 Section 1 1. Toxicological information ProducUingredient name Result Species Dose Exposure ffiethanol toluene nonane 3-butorypropan-2-ol dibutyltin dilaurate LC50 lnhalation Gas. LC50 lnhalation Gas. LD50 Dermal LD50 Oral LC50 lnhalation Vapor LC50 !nhalation Gas. LC50 !nhalation Vapor LD50 Dermal LD50 Oral Rat Rat Rabbit Rat Rat Rat Rat Rabbit Rat 145000 ppm 64000 ppm 15800 mg/kg 5600 mg/kg 49 g/ms 3200 ppm 17000 mg/m" 3100 mg/kg 175 mg/kg t hours 4 hours 4 hours 4 hours 4 hours lrritation/Corrosion Sensitization Mutagenicity Carcinogenicity Reproductive toxicity Teratogenicity lnformation on the likely routes of exposure Potential acute health effects Eye contact lnhalation Skin contact lngestion Causes serious eye irritation. Causes skin initation. May cause an allergic skin reaction. No known significant effects or critical hazards. No known significant effects or critical hazards. May damage fertility or the unborn child. No known significant effects or critical hazards. Target organs eyes and hearing organs Not determined Not available. Causes serious eye irritation. Toxic if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Toxic in contact with skin. Causes skin initation. May cause an allergic skin reaction. Toxic if swallowed. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Specific target organ toxicity (single exposure) Name Target organs methanol toluene Light aliphatic naphtha dibutyltin dilaurate central nervous system (CNS) and optic nerve Narcotic effects Narcotic effects Not determined Soecific target organ toxicity (repeated exoosure) toluene dibutyltin dilaurate Asoiration hazard Name Result toluene Light aliphatic naphtha nonane ASPIRATION HAZARD - Category 1 ASPIRATION HAZARD - Category 1 ASPIRATION HAZARD - Category 1 Svmptoms related to the phvsical. chemical and toxicological characteristics Dateofissue/Dateofrevision :1t24f2020 Dateofpreviousissue :11f2il2019 Version :2.01 413 Chemlease@ MPP 117 Section 1 1. Toxicological information Skin contact Adverse symptoms may include the following: irritation redness reduced fetalweight increase in fetal deaths skeletal malformations lngestion Adverse symptoms may include the following: nausea or vomiting reduced fetalweight increase in fetal deaths skeletal malformations Eye contact Adverse symptoms may include the following: pain or irritation watering redness lnhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetalweight increase in fetal deaths skeletal malformations Delaved and immediate effects and also chronic effects from short and lono term exposure Short term exposure Potential immediate effects Potential delayed effects Long term exposure Potential immediate effects Potential delayed effects Numerical measures of toxicity Acute toxicitv estimates Not available. Not available. Not available. Not available. Route ATE value Wal Dermal lnhalation (gases) lnhalation (vapors) 153.7 mg/kg 623.4 mg/kg 97284 ppm 6.177 mgll Section 12. Ecological information No known significant effects or critical hazards. Section 13. Disposal considerations Date of issue/Date of revision ;1f24f2020 Date of previous issue :1126f2019 Version :2.01 9/13 Chemlease@ MPP 117 Section 1 3. Disposal considerations Disposalmethods RCRA classification The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. lncineration or landfillshould only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the contiainer. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. D001 Because of its ignitability if the product is disposed of in its original form. Section 14. Transport information DOT Classification Bulk TDG Classification IATA !MDG UN number uN1992 uN1992 uN1992 uN1992 uN1992 UN proper shipping name Flammable liquids, toxic, n.o.s. (toluene, methanol) FLAMMABLE LIQUID, TOXIC, N.O.S.(toluene, methanol) FLAMMABLE LIQUID, TOXIC, N.O.S. (toluene, methanol) Flammable liquid, toxic, n.o.s. (toluene, methanol) FLAMMABLE LIQUID, TOXIC, N. O.S. (toluene, methanol) Transport hazard class(es) 3 (6.1)3 (6.1)3 (6.1)3 (6.1)3 (6.1) Packing group lt il I lt il Environmental hazards No.Fo.No.fo.Ko. Emergency Response Guidebook (ERG): 131 Additional information DOT Classification Reportable ouantitv 4018.7 lbs / 1824.5 kg [573.79 gal12172 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation req u irements. Limited quantitv Yes. Packagino instruction Exceptions: None. Non-bulk:202. Bulk: 243. Quantity limitation Passenger aircrafUrail: 1 L. Cargo aircraft: 60 L. Soecial orovisions lB2, T7, TP2, TP13 Product classified as per the following sections of the Transportation of Dangerous Goods Regulations 2.18-2.19 (Class 3),2.26-2.36 (Class 6). Explosive Limit and Limited Quantitv lndex 1 Passenoer Carrving Road or Rail lndex 1 Soecial orovisions 16 Tmergency schedules F-E, S-D Special orovisions 274 TDG Classification IMDG Date of issue/Date of revision :1f242,020 Date of previous issue : 11f2tr2019 Version :2.01 1A13 Chemlease@MPP 117 Section 14. Transport information Passenger and Cargo Aircraft: 1 L.Packaging instructions: 352. Limited Quantities - PassengerCargo Aircraft Only: 60 L. Packaging instructions: 364. Aircraft: 1 L. Packaging instructions: Y341. Special orovisions A3 Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Section 15. Regulatory information lnventory list Australia Canada China Europe Japan New Zealand Philippines Republic of Korea Taiwan United States Clean Air Act Section 'llzlbl Hazardous Air Pollutants (HAPs) lngredient name SARA 302/304 Gomposition/information on ingredients No products were found. SARA 304 RQ SARA 311/312 Classification Allcomponents are listed or exempted. Allcomponents are listed or exempted. Allcomponents are listed or exempted. Contact local supplier or distributor. Japan inventory (ENCS): Allcomponents are listed or exempted. Japan inventory (ISHL): Allcomponents are listed or exempted. All components are listed or exempted. All components are listed or exempted. Allcomponents are listed or exempted. Allcomponents are listed or exempted. All components are listed or exempted. : Not applicable. : FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (oral) - Category 3 ACUTE TOXICITY (dermal)- Category 3 ACUTE TOXICITY (inhalation) - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 1B TOXIC TO REPRODUCTION (Unborn child) - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (central nervous system (CNS), optic nerve) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (eyes, hearing organs) - Category 2 ASPIRATION HAZARD - Category 1 methanol toluene SARA 313 Dateofissue/Dateofrevision :1f24t2020 Dateofpreviousrl*sue :11f26t2019 Version :2.01 11/13 Chemlease@MPP 117 Section 15. Regulatory information Product name CAS number Yo Form R - Reporting requirements methanol toluene i7-56-1 I 08-88-3 5-<50 0-s25 Supplier notification methanol toluene i7-56-1 I 08-88-3 :25 - <50 :10 - s25 SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. State reoulations Massachusetts New York New Jersey Pennsylvania The following components are listed: METHANOL; METHYL ALCOHOL; TOLUENE; METHYLBENZENE; NONANE The following components are listed: Methanol; Toluene The following components are listed: METHYL ALCOHOL; METHANOL; TOLUENE; BENZENE, METHYL-; NONANE The following components are listed: METHANOL; BENZENE, METHYL-; NONANE California Proo.65 A mn}.ll]llG: This product €n expose you to Benzene, which is known to the State of California to cause cancer and birth defects or other reproductive harm. This product can expose you to chemicals including Ethylbenzene, Cumene, Naphthalene, which are known to the State of California to cause cancer, and Toluene, Methanol, which are known to the State of California to cause birth defects or other reproductive harm. For more information go to www. P65Warni n gs. ca. gov. U.S. Federal regulations : TSCA 12(b) one-time export: nonane Section 16. Other information Hazardous Materia! lnformation Svstem (U.S.A.) Health: 4 * Flammability: 3 Physicalhazards: 0 PerconalprotectionCode: H Nationa! Fire Protection Association (U.S.A.) Health: 2 Flammability: 3 lnstability/Reactivity: 0 Special : - Historv Date of issue/Date of revision Date of previous issue Vercion Prepared by Key to abbreviations 1t24t2020 11t26t2019 2.01 Chem-Trend Regulatory Affairs Department. ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = I nternational Ai r Transport Association IBC = lntermediate Bulk Container IMDG = !ntemational Maritime Dangerous Goods LogPow = logarithm of the octanolArvater partition coefficient MARPOL = lnternational Convention for the Prevention of Pollution From Ships, 1973 Dateofissue/Dateofrevision :1f24t2020 Dateofpreviousissue :1126t2019 Version :2.01 12/13 Chembase@ MPP 117 Section 16.Other information as modified by the Protocolof 1978. ("Marpol" = marine pollution) UN = United Nations Z lndicates information that has changed from previously issued vercion. Notice to reader lnformation presented herein has been compiled from information provided to us by our supplierc and other sounces considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or the use of any product in violation of any patent or in violation of any law or regulation. !t is the users' responsibility to determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warrantyl as to the results to be obtained in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us. @ APPBWEII Date of issue/Date of revision :1f242,020 Date of previous iss.re :11f2tr2019 Version :2.01 1Y13 E'ISTTUT'IIT SDSUS /EN /TUSO1 Version: 2.1 Revision D alet 1 21 17 1201 4 lnitiator: 0001 / PRD 150000001116 SAFETY DATA SHEET SEGTION 1: ldentification of the substance/mixture and of the Product identifier Product name: Eastman(TM) MPK Product No.: EAN 901928. P0654804 Synonyms, Trade Names: 06548-00 Additional identif ication Chemicalname: methyl propyl ketone CAS-No.: 107-87-9 Relevant identified uses of the substance or mixture and uses advised against ldentified uses: Solvent Uses advised against: None known. Details of the supplier of the safety data sheet Manufacturer / Supplier Eastman Chemical Company 200 South Wilcox Drive Kingsport, TN 37660-5280 US +14232292000 Visit our website at www.EASTMAN.com or email emnmsds@eastman.com Emergency telephone number: For emergency health, safety, and environmental information, call 1-423-229-4511 or 1-423-229-2OOO. For emergency transportation information, in the United States: call CHEMTREC at 800-424-9300 or call 423-229-2000. ION 2: Hazards identification Hazard Classif ication : Physical Hazards Flammable liquids Category 2 Health Hazards Acute toxicity (Oral) Category 4 Serious Eye Damage/Eye lrritation Category 2A OSHA Specified Hazards: not applicable Warning label items including precautionary statement: Pictogram: 1112 E'TSTTUI'TIT SDSUS /EN /TUSO1 Version: 2.1 Revision D ale'. 1 2J 17 l2o1 4 lnitiator: 0001 / PRD 15000000t116 90 SignalWords: DANGER! Hazard Statement(s): H225: Highly flammable liquid and vapor. H302: Harmful if swallowed. H319: Causes serious eye irritation. Precautionary Statement: Prevention: P210: Keep away from heaVsparkVopen flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P24 1 : Use explosion-proof el ectrical/venti lati ngili ghti ng/equi pm ent. P242: Use only non-sparking tools. P 243: T ake precauti onary m easu res agai nst stati c discharge. P280: Wear protective gloves/protective clothing/eye protection/f ace protection. P264: Wash hands thoroughly after handling. P27O: Do not eat, drink or smoke when using this product. P26 1 : Avoid breathi ng dusVf ume/gadm i sUvapors/spray. P271: Use only outdoors or in a well-ventilated area. Response: P370 + 378: ln case of fire: Use water spray, carbon dioxide, dry chemical or foam for extinction. P303+P361+P353: lF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P301+P312: lF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330: Rinse mouth. P305+P351+P338: lF lN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: lf eye irritation persists: Get medical advice/attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. Storage: P4O3+P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. Disposal: P501: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Hazard(s) not otheruvise Potential peroxide former. classified (HNOC): ECTION 3:nonr Substances / Mixtures @OPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 2t12 ErtSTIUInil SDSUS /EN/TUSO1 Version:2.1 Revision D ale:. 1 21 17 l2O1 4 Initiator: 0001 / PRD 't 50000001 1 16 Ghemlca! name 'oncentration Additional identif ication Notes methvl DroDVl ketone >90%CAS-No.: 1O7-87-g * methvl isobutvl ketone <100/"CAS-No.: 108-10-1 * General information: . All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. # This substance has workplace exposure limit(s). SECTION 4: First aid measures Description of first aid measures lnhalation: Move to fresh air. Treat symptomatically. Get medical attention if symptoms persist. Eye contact: lmmediately flush with plenty of water for at least 15 minutes. lf easy to do, remove contact lenses. Get medical attention. ln case of irritation from airborne exposure, move to fresh air. Get medical attention if symptoms persist. Skin Contact: Wash with soap and water. Get medical attention if symptoms occur. lngestion: Seek medical advice. Most important symptoms and May irritate and cause redness and pain. effects, both acute and delayed: lndication of any immediate medical attention and special treatment needed Hazards: None known. Treatment: Treat symptomatically. SECTION 5:measures General Fire Hazards: Flammable liquid and vapor. USE WATER WITH CAUTION. Material will float and may ignite on surface of water. Extinguishing media Suitable extinguishing Water spray. Dry chemical. Carbon Dioxide. Foam. media: Unsuitable extinguishing None known. media: Special hazards arising from Vapors may cause a flash fire or ignite explosively. Vapors may travel the substance or mixture: considerable distance to a source of ignition and flash back. Prevent buildup of vapors or gases to explosive concentrations. May form peroxides of unknown stability. Advice for f iref ighters Special fire fighting Water may be ineffective in fighting the fire. Use water spray to keep fire-procedures: exposed containers cool. @OPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 3112 EnsTtn,til SDSUS /EN /TUSO1 Version:2.1 Revision D ale: 1 21 17 l2O1 4 lnitiator: 0001 / PRD 't 50000001 1 16 Special protective Self-contained breathing apparatus and full protective clothing must be equipment for fire-fighters: worn in case of fire. ECTION 6: Accidental release measures Personal precautions, Wear appropriate personal protective equipment. protective equipment and emergency procedures: Environmental Precautions: Avoid release to the environment. Methods and material for Eliminate sources of ignition. Absorb spill with vermiculite or other inert containment and cleaning material, then place in a container for chemical wasle. Large Spillages: Use up: water spray to disperse vapors and dilute spill to a nonflammable mixture. Prevent runoff f rom entering drains, sewers, or streams. Dike for later disposal. Notification Procedures: ln the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. 7: Hand and Precautions for safe handling: Avoid contact with eyes. Wash thoroughly after handling. Minimize exposure to air. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Do not allow to evaporate to near dryness. Do not distill to near dryness. Addition of water or appropriate reducing materials will lessen peroxide formation. Conditions for safe storage, Keep container tightly closed and in a well-ventilated place. Store away including any from heat and light. incompatibilities: Specific end use(s): Solvent ECTION 8: E ure Control Parameters Occupational Exposure Limits Country specific exposure limits have not been established or are not applicable unless listed below. Chemical name Type Exposure Limit Values Source methvl oroovl ketone STEL '150 ppm US. ACGIH Threshold Limit Values (01 2010) PEL 200 ppm 700 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) methvl isobutvl ketone TWA 20 ppm US. ACGIH Threshold Limit Values (01 2010) STEL 75 ppm US. ACGIH Threshold Limit Values (01 2010) PEL 100 ppm 410 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) @OPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 4112 EnsTrnnil SDSUS /EN/TUSO1 Version: 2.1 Revision D ale:. 1 2l'17 l2O1 4 lnitiator: 0001 / PRD 1500000011 t6 cal Limit Values Chemical name Exposure Limit Values Source methyl isobutyl ketone (methyl isobutyl ketone: Samolino time: End of shift.) 1 mg/l (Urine)ACG|H BEL (01 2010) Exposure controls Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used.controls: Ventilation rates should be matched to conditions. lf applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. lf exposure limits have not been established, maintain airborne levels to an acceptable level. lndividual protection measures, such as personal protective equipment General information: Eye bath. Washing facilities. Eye/face Protection: Wear safety glasses with side shields (or goggles). Wear a full-face respirator, if needed. Skin protection Hand Protection: lt is a good industrial hygiene practice to minimize skin contact. Other: No data available. Respiratory Protection: lf engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. ln the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR '1152, January 8, 1998. Respirator type: Air- purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cafiridge or canister. Contact health and safety professional or manufacturer for specific information. Hygiene measures: Observe good industrial hygiene practices. Environmental Controls: No data available. 9:!and chemical lnformation on basic physical and chemical properties Appearance PhysicalState: Liquid Form: Liquid Color: Colorless Odor: Odor Threshold: pH: Melting Point @OPYRIGHT 2014BY EASTMAN CHEMICAL COMPANY ketone 11 ppm No data available. -78'C 5112 Ertsrmnil SDSUS /EN /TUSO1 Version: 2.1 Revision D ale: 1 2/ 17 /201 4 lnitiator: 0001 / PRD 'l5000000tI16 Boiling Point: 101 'C Flash Point= 7.8 "C (Tag closed cup) Evaporation Rate: 2.3 Flammability (solid, gas): No data available. Flammability Limit - Upper (o/o)-: 8.7 "/"(V) Flammability Limit - Lower (o/o)-: 1.56 %(V) Vapor pressure: 37 mbar (20'C) Vapor density (air=1): 2.9 Specific Gravity: 0.81 (20 "C) Solubility(ies) Solubility in Water: Moderate Solubility (other): No data available. Partition coetficient (n-octanoUwater): log Pow: 0.857 Autoignition Temperature: 450'C Decomposition Temperature: (DTA) No exotherm to boiling Dynamic Viscosity: 0.607 mPa.s (20 "C) Kinematic viscosity: Not determined. Explosive properties: No data available. Oxidizing properties: No data available. Other information Minimum ignition temperature: 449'C (ASTM D2155) SECTION 10: Stabi and Reactivity: None known. ChemicalStability: Stable Possibility of Hazardous May form peroxides of unknown stability. Reactions: Conditions to Avoid: Heat, sparks, flames. lncompatible Materials: Strong oxidizing agents. HazardousDecomposition CarbonDioxide.CarbonMonoxide. Products: SECTION 11: T information lnformation on likely routes of exposure lnhalation: lngestion: Skin Contact: Eye contact: None known. Harmful if swallowed. None known. Causes serious eye irritation. @COPYRIGHT 2014BY EASTMAN CHEMICAL COMPANY 6112 E,IST]UT,ril SDSUS /EN/TUSO1 Version:2.1 Revision D ale: 1 21 17 1201 4 lnitiator: 0001 / PRD 'r 50000001 1 16 !nformation on toxicological effects Acute Toxicity Oral Product: No data available. Specified substance(s) methyl propyl ketone Oral LD-50: (Rat): 1,600 mg/kg methyl isobutyl ketone Oral LD-50: (Rat): 2,080 mg/kg Dermal Product: No data available. Specified substance(s) methyl propyl ketone Dermal LD-50: (Guinea Pig): > 20 ml/kg methyl isobutyl ketone Dermal LD-50: (Rabbit): >10 ml/kg lnhalation Product: No data available. Specified substance(s) methyl propyl ketone LC50 (Rat' 4 h): 25'5 mg/l methyl isobutyl ketone LC50 (Rat, 4 h):2000 - 4000 ppm Repeated Dose Toxicity Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Skin Corrosion/lrritation : Product: No data available. Specified substance(s) methyl propylketone (Guinea Pig,24h): slight methyl isobutylketone (Rabbit' 72 h): none Serious Eye Damage/Eye lrritation: Product: No data available. Specified substance(s) methyl propyl ketone (Rabbit' 24 h): moderate methyl isobutyl ketone (Rabbit): slight to moderate Respiratory or Skin Sensitization: Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' @OPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 7112 E,tSTtUt,tTT SDSUS /EN/TUSO1 Version: 2. 1 Revision D ale: 1 21 17 l2O1 4 lnitiator: 0001 / PRD 150000001116 Mutagenicity ln vitro Product: No data available. Specified substance(s) methyt propyt ketone ::ffff',:lrjxi[1,r;fl assay (Ames test), Bacterial Reverse Mutation Assay : Mutagenicity - Mammalian, ln vitro Mammalian Cell Gene Mutation Test : negative +/- activation Chromosomal aberration, ln vitro Mammalian Chromosome Aberration Test : negative +/- activation methyl isobutyl ketone No data available' ln vivo Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Carcinogenicity Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone IARC 28: possibly carcinogenic to humans. Reproductive Toxicity Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Specific Target Organ Toxicity - Single Exposure Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Specific Target Organ Toxicity - Repeated Exposure Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Aspiration Hazard Product: No data available. Specified substance(s) methyl propyl ketone May be harmful if swallowed and enters airways. methyl isobutyl ketone May be harmful if swallowed and enters airways. @OPYRIGHT 2014BY EASTMAN CHEMICAL COMPANY 8112 E,ISTIUI,til SDSUS /EN /TUSO1 Version: 2.1 Revision D ale: 1 21 17 1201 4 lnitiator: 0001 / PRD 15000000.t 1 16 Other Adverse Effects: Contains an IARC (lnternational Agency for Flesearch on Cancer) 28 material. IARC 28 is a classification for possible human carcinogen based on sufficient evidence on carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans, 12:information Toxicity Acute toxicity Fish Product: No data available. Specified substance(s) methyl propyl ketone LC-50 (Fathead Minnow, 96 h): 1,240 mg/l methyl isobutyl ketone L!-!0 (goldfish' 24 h):460 mg/l LC-50 (golden orfe, 48 h): 675 - 750 mg/ Aquatic Invertebrates Product: No data available. Specified substance(s) methyl propyl ketone EC-50 (Water Flea, 48 h): > 1 10 mg/l methylisobutylketone LC'50 (Water Flea,24 h):4,300 mg/l chronic Toxicity Lc-50 (Brown shrimp' 24 h): 1'250 mg/l Fish Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Aquatic lnvertebrates Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Toxicity to Aquatic Plants Product: No data available. Specified substance(s) methylpropylketone NOEC:.(Alga'72h):74m$l EC-50 (Alga, 72 h): 150 mg/ methyl isobutyl ketone No data available' Persistence and Degradability Biodegradation Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' @OPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 9112 E,ISTITT,tIT SDSUS /EN /TUSO1 Version:2.1 Revision D ale: 1 21 17 l2O1 4 lnitiator: 0001 / PRD 150000001116 Biological Oxygen Demand: Product No data available. Specified substance(s) methyl propyl ketone P9P-!: 1,380 mg/g BOD-20: 1,800 mg/g methyl isobutyl ketone BOD-S: 1'940 - 2'060 mg/g Chemical Oxygen Demand: Product No data available. Specified substance(s) methyl propyl ketone 1'800 mg/g methyl isobutylketone 2'160 - 2'460 mg/g BOD/COD Ratio Product No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Bioaccumulative Potential Product: No data available. Specified substance(s) methyl propyl ketone No data available' methyl isobutyl ketone No data available' Mobility in Soil: No data available. Known or predicted distribution to environmental compartments methyl propyl ketone No data available' methyl isobutyl ketone No data available' Results of PBT and vPvB No data available. assessment: methyl propyl ketone No data available' methyl isobutyl ketone No data available' Other Adverse Effects: No data available. SECTION 13:considerations Waste treatment methods General information: No data available. Disposal methods: Dispose of waste and residues in accordance with local authority requirements. Mix with compatible chemicalwhich is less flammable and incinerate. Since emplied containers retain product residue, follow label warnings even after container is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near this container. @COPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 10112 E,LSTTUT'TTU SDSUS /EN /TUSO1 Version:2.1 Revision D ale: 1 21 17 1201 4 lnitiator:0001 / PRD 150000001116 ECTION 14=T information lmportant Note: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Consult your company's Hazardous Materials/Dangerous Goods expert for information specific to your situation. DOT Reportable Quantity: 22,700 kg (methyl isobutyl ketone) Possible Shi ppi ng Description(s) : UN 1224 Ketones, liquid, n.o.s. (methyl propyl ketone,methyl isobutyl ketone) 3 ll IMDG - International Maritime Dangerous Goods Code Possible Shipping Description(s): UN 1224 KETONES, LlQUlD, N.O.S. (methyl propyl ketone,methylisobutyl ketone) 3 il IATA Possibl e Shipping Descri ption(s) : UN 1224 Ketones, liquid, n.o.s. (methyl propyl ketone,methyl isobutyl ketone) 3 ll ECTION 15:information Safety, health and environmental regulations/legislation specific for the substance or mixture: This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS (Canada) Status: controlled WHMIS (Canada) Hazard Classification: Bl2, Dl2lA, Dl2lB SARA 31 1-31 2 Hazard Classification(s): immediate (acute) health hazard delayed (chronic) health hazard fire hazard US EPCRA (SARA Title lll) Section 313 - Toxic Chemical List METHYL ISOBUTYL KETONE OSHA: hazardous @OPYRIGHT 2014 BY EASTMAN CHEMICAL COMPANY 11t12 ErtSTI$nil SDSUS /EN /TUSO1 Version: 2. 1 Revision D ale: 1 21 17 l2O1 4 lnitiator:0001 / PRD 1500000011 t6 TSCA (US Toxic Substances Control Act): All components of this product are listed on the TSCA inventory. Any impurities present in this product are exempt from listing. DSL (Canadian Domestic Substances List) and CEPA (Canadian Environmental Protection Act): All components of this product are listed on the DSL. Any impurities present in this product are exempt from listing. AICS / NICNAS (Australian lnventory of Chemical Substances and National lndustrial Chemicals Notification and Assessment Scheme): All components of this product are listed on AICS or otherwise comply with NICNAS. MtTl (Japanese Handbook of Existing and New Ghemical Substances): All components of this product are listed in the Handbook or have been approved in Japan by new substance notification. ECL (Korean Toxic Substances ControlAct): All components of this product are listed on the Korean inventory or otherwise comply with the Korean Toxic Substances Control Act. Philippines lnventory (PICCS) : All components of this product are listed on the Philippine inventory or otherwise comply with PICCS. lnventory of Existing Chemical Substances in China: All components ol this product are listed on the lnventory of Existing Chemical Substances in China (IECSC). SECTION 16: Other information HMIS@ Hazard Ratings: Health - 2, Flammability - 3, Chemical Reactivity - 1 HMIS@ rating involves data interpretations that may vary from company to company. They are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the information contained in this MSDS must be considered. Revision Information: Not relevant. Key literature references and No data available. sources for data: Training information: No data available. Issue Date: 1211712014 SDS No.: Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. @OPYRIGHT 20.I4 BY EASTMAN CHEMICAL COMPANY 12112 MOLD PREP ROOM BACTANALYSIS Best Available Contro! Technology Analysis Northrop Grumman Systems Corp. Clearfield, Utah Process: Mandrel Prep Room Emission Unit: 3,725 SCM Fan Pollutant: VOC / HAP Potentialto Emit Summarv (Criteria pollutants and HAP) Pollutant voc HAP PTE (tons/vr) 0.187 0.008 A copy of the entire PTE calculations for this source is attached (see DAQ VOC Calcs spreadsheet). A traditional top-down Best Available Control Technology (BACT) analysis consists of 5 steps as detailed below. . Step 1 - ldentify all control technologies . Step 2 - Eliminate technically infeasible options . Step 3 - Rank remaining control technologies by control effectiveness . Step 4 - Perform impacts analysis . Step 5 - Select BACT Control Technoloqies Control technologies for VOC include variations of carbon adsorbers; refrigerated condensers; flares; and incinerators and oxidizers. Eliminate Technicallv lnfeasible Options Refrigerated condensers are used for treating emission streams with high VOC concentration (>5,000 ppm) (EPA Air Pollution Control Cost Manual, section 3, chapter 2.1). Control Effectiveness Rankinq 1. lncinerators and Oxidizers 99% Removal Efficiency 2. Carbon Adsorbers g8% Removal Efficiency lmpacts Analvsis Multiple types of equipment were evaluated for VOC removal for each control technology.'The impact analysis is attached (see various H5 Mandrel Prep spreadsheets). Cost Effectiveness voc $280,974 Carbon Adsorber 176.712 $1 ,980,719,967 lncinerators and Oxidizers 1 .980.719.967 Multiple types of equipment were evaluated for HAP removal for each control technology. The impact analysis is attached (see various HS Mandrel Prep spreadsheets). Cost Effectiveness Carbon Adsorber $3,715,410 $31,425 ,698 lncinerators and Oxidizers $31,425 $32 884 1,347,784 BACT Selection Northrop Grumman Systems Corp. proposes the installation of an air pollution control device for this process is not cost effective. The processes and VOC and HAP emissions which occur during this process are regulated under Utah Administrative Code Rule R307-355, Aerospace Manufacture and Rework Facilities. Northrop Grumman Systems Corp. has documented procedures in place which require all containers to remain closed except during use and define responses to any spills which may occur. Solvents applied on the manufacturing floor are dispensed in 500 ml squeeze bottles or pre-saturated wipes which limit the volume of any spills. Northrop Grumman Systems Corp. proposes compliance Utah Administrative Code Rule 307- 355, including VOC and HAP controls and work practices, as BACT. $47 MOLD PREP ROOM BACT CALCULATIONS-VOC Volume 2: Chapter 8: Preferred and Alternative Methods for Estimating Air Emissions from Paint, lnk and Other Coating Manufacturing Facilitie! httos://www.eoa.Rov/sites/default/files/2015-08/documents/iiO8 feb20O5.od' Emission Model for Surface Evaporation IPA 50.1011b/lb.mol iurf. Area 1I ;q. ft. Prrdall vaDo, Pltnsurr 0.6381 rtlr latch time 0.2!lrs , Batches / year 4t ilind Speed 1(x 'ps 58.181t nDh vtass Transfer Coeffi cient o.078922621 t/sec Jniversal Gas Constant 10.73lPsia-ft/" Rlb.mol l.emperature s3i R /OC Emissions 2.14742466 b/hr Max hourly 0.1889733;on/year OensiW 0.764 b/ft" \ir Flow 372!iCFM 67050000(1'lyr 5as Stream Volume 6.28863128r b.mol/yr 169.713960!t3/vr ias StEam Conc.0.25ilU5527lpprnv Panial Vapor Pressure (Raoult's Law) IPA /apor Pressure 0.63811 csra .toutd mass ractlon b/rb vlw 60.lb/lb.mol 0.01663! .iouid mole fraction )artial Vapor Pressure 0.538112 GAs SteeA[4 coNc' ?lRrrAu t 3oR PRes. CALCut A7o,\ls - Vo< t'- ) ..}llo) MA=)rrfiA e/{i) pslgq -*o?Af tAf.f,frf I Iro\ t al^orr&tuJj,fl) I ,) s.l.d s. Vr d catun.6orbr syn.m: h, tu# tu d.dB, pEdd. th. lolos[ ln6nih: S# th. ryF d oF.tlon; Sdd tu tyF of mat d.lud to L&iet th.6rbn.ditrhrv6i.lrl S.t.d th. od.nt.tloh 16r th. ds6.r v8dr: f fl E Nuhb€r d@.r.u{ hou6 rrysr(eJ w.sr!Gas Flw R.t. (O) v@ Emi$lon R.t. (m*) Rquird voc rumov.l.trid.nry (E) Estjm.td.quipm.nl llf. of .uxiliary Equipm..t (n) Numbn ol OFr.tlry H@rs8€lor. OrbnC.nH.rRepl.em.nt (€J 1.725 acfm' O.lE lbs/hour lm 1&..rh6n.er.:n*r m hou6 93 per.entira delau[rontioletfi.en.y ut€,rhou]denteradu.lvllue il tnown '10veru itrdefau[ euimeni lile Urershouldenre,actual!alu?,dknown P.nl.l Pr.siu..of 2-Protsnol inw.{.a.r rrc.m P.r.m.t.r "l" ld 2-P.oFnol P.r.m.l.. "m" lor 2-Prop.nol qEllrx TddYfud'l! d16rldsm6mlnd O-1S ve .ro hsn h r.e CEPCI'tor2022 Annurl lnt.r.5t R.t€ (i) useolotherwell known c6r indexB (e.g., M&S) B.c(eptable. lf known,.ntcrrny.ddltlon.lc6Btor3it.pr.Fniron.nd buildiq Slt. Pr.tsrdion (SP) = EulldinF (8Eg) = Equlph.nt Co*s lor.urill.ry.quipment (..t., dutuork, d.mFB,.nd 3t!ck) (EC.J -- contlns.nq F.dor (cr) Note:TyPic.l@'t3'orcarbonc.nisteuar.5howninT.bleB ' IOE(enr ts a ddaoll value Thecontinren.v,a.lor 5hould be kween 5 and 15 oercent fr.followtnad.dan N.!m.t ritdth.qrbd.dsrhr*.rcokdddbdonrh. v.lue5.nt.Ed onih.OotdrrryB t.b.t.r. v.lu.s w.rc us.d lo pr.p.r. th..o* rhown on theCositniddt bb. fE ol ctrion rd$tu: mdEffiLd: ffiolfuffiffi6nlorbd.olM 2frFd Qudryd2-lqdhl!l.d: Qu.ntlty ol z-Propanol R.mond (wrcc) = Ertlnabd Catroh Con3ump$on (M") for.n i.t.mhentt op.Et.d rysm. N!mber of tim.s c.nisteds) repla.ed peryear: ffirMEtuOtuOdoE: Ilm. brAdsntlon(eJ = Equilibdum ep.clv dth. lnl.t (Wnd). wo*ha ap.city (w.) = E*ih.td Tobl erbn Requ[.d (M.] = tumhrof c.6on onisE R4ulrod. Tod Quntry of qdon R.qulrud for 1 C.ni3EB: CdblMryM C.pbl Rcorry Fdorfor.uxlll.ry.qulDm.nt (CFtuux) : C.piblR@rcry rdor lor c.tun {cRF..d-d,) = W*=n*te,xE. Nunhr ot o8dnc houE bhE .tu d@r ftpldwfr . M"/c.6on c.nl*r c.p.chy Numblr ofC.tron qal*B'C.M Gp.dty p.rAnk.r = trx (1+ i)il / I(1+ i)i -lt: Wh.ro n = €qulphlnt Lil. .nd i: hEd Rd. tri (1+ i)"1 / I(1 + il^ -11 = Whcrc n= Arbon CrnklrLil!.nd i = lnbrei Rd€ 0.14 b6ry..r a lbs. 1 a,3@ houE 0.8 lb. voc/lb- o6on O3S lb. VOC/lb. Orbon 6B lbs- 3,& lbs. 0.1121 o.7s7a EnhdadEloarr. c.rtqr C.nb..Aio.t rutiC..th..t rLffi dnrfi.lfu.radrn@ VOC C.trh[.d/R.csnd i 2-PE?.B| Addb.. Vfr$l Othrb$on . ilor Applobh Or.ntlilSdr.duL . hbmhldtODi.tlor Tal C.Clnl lffi OO) (h 1022 ildbBl lbEffi Ecurbd cd $43,166 S2,o@ 54s,866 s4,st, s1J76 s2,293 Tot.l Pufthrsd Eqclprenl Cffi (B) = $49.535 Total Cost forAll Carbon Adsorber CanisteE (ECe*J = Aurili.ry €quipment (Ec.,,l = Tdd A/.6..d Equhmm C* fd C.rbotr Adryts (A) r sales taxes = Fr€ight = ,bEffi lnst.ll.tion = Sit€ Pr.p.ralion (SP) = Sulldints (gld3) = Co.tint nqc6t{C): Canister CGt x Nomber ot Cani*r6 R.quired = (&sd on d..i8n corts or.stim.ted u.ing m.thods provided in Section 2) . ECe6 + Eq*. O.10rA= O.03rA= O.05rA= Eqatbo O.20xg= TotC Oid ad lndind hrfrl.tlon Cd - cF(Purch.s. EquiDm.nt coit + lnstall.tlon c6ts)= h ts,eo, So So S9,94, stea4 Dk^,trlCd P.ffi Maintenance cosls: Cerbq Qni$er ReDlacement Costal Eqctlon 0.6 x TCI lnstallation Cort= 0.2r ilumb.rof Canist€rsx&stperCanisterx CRF = Canist.rc = numb.r ofc.niite6 x Coii FrGniiterx 1.08rCRF = Cd 53,923 li&r.t Al,ul Cc.b hEffi Administrative Charges Prop€fry Tares caphal Recov€ry CqElhn = 2% of TCI = 1% of TCI = 1% ot TCI = CRFAuxili.ry €qoipm.nr r (TCl - 1.o8lcanirt.r Costs)) = cd S1,38 $6s.t S65{ s2,s64 Cd Efi..ltuM Panmtat lTot.l Annu.l esr = lAnnu.l ouentity ofvtr R.moved = Cost Effedivencss = Egdo.l We =m6. x e,xE= Total Annual Gst (TAC) /Annual quantity ofVOC Rcnovcd/Rccovcred = cd SSL629 pgy.$h2o22d6{.F Olt tffiF..ycr 32toJr4 Ftdoa9ol6nEromddtn dolh6 Sdd tu typ! d orbn.&orh. iyn m: ktu# &n ddF, F#. tuilo6a ffimdhl 5ebd th€ ryts ol oF,ataon: S€ld th€ typ! ol h.t.il.l ud tof.briete h. arbn.&or&r vc$dt: S.ld th od.nt.tlon for th. rdrorb.r wr*ls: f fI f Numb ol qs.tiry houB F y..r (e,) w.*. G.s Flfl n.t. (Q) vC Emli3loh R.t. {k} R{uk.dVOC r.moval cffidcnd {E} E*lm.td.qulpm.ntlileof .dsorbav.r*h.nd.uxlli.ryEquipmsl(nl Estlm.td c.6on lif.ln) Estlmdd c.60n R.pl.c.m.nt R.t. (cRR) m lb ca.bon Er(an6re, 9Sper.enturdelaoh.onilolefi(@ncy Usershouldenrera.lualv.lue,irknown Itvea6 n a def.uX equrpment lile User should enl€r a.lual v.l!e, il lnown 179 lB./[o!. n.defauh value l@ r& ol . a rbon pe. ..n6Ier is a def.uh value Ure, 3hould enler prefered can6teil tre, r lnowr P.ni.lPr.$urcof 2-Protsnol i.w.3t.!.rnr..m P.r.m.ter'k" tor 2'ProFnol P.r.m.t.r "m" fo. 2-Prop.nol Phholsddd;.1@hol Tyrld v4G d"r' .nd'm'ttr'm 6mlM O.1S3 vcelhoflhl&^ CEPCI'for2022 Annu.l lht...n R.t.li) Uleotothe.welllnown cott index6 (e g, M&5) ts..cepi.br€ M.int n.nc!bbrR.t. orbn c6l{ccl llknown,.ntu.ny:dltonilc6cfddt.pr.Fnilon.nd st. ProFr.tlon (sP) = sslldlqilEldt) = pd enister {in 2022 dolla6)Typical cottr.or c.rbon c.hrrl..t.re rhown in T.bl. E Equipm.ntC6ttld.uili.ry.quirlnt(!.t-,dotuoil, d.mtsB,.nd+.d) lEc,-l = Contlna.nqF.do. (cF) D€fauhvalu€. Ueer shouldent€, a.tual vrlue. dknown Ddauhlalu€ U!e. shouldenler adual value, itknown Ddauhvalue.lser 5houldenter.dualvalue,f known 530.2]lhoor B a derau[ valoe Uen rhourd enteradual!.lo€, ii known l,the rate r nor know., us€ I 10 x 54.20/lbbadel.lltvaluebatedon20lSmarketprice ussshould.nrs..ru.lv.lue,ilknown l0 Frcent 6 a defalt va rue The ( ontingen.y fa.to' lhould & H ween 5 and 15 per.enr sffitumivrb omtuF*Ebsrbrtuftso C 51.90 rnuary 2O1a ma.k* p.t.ror vrgan..@n Oo.rator Labor Rat. lSlhoud s71.48 ureauof Labo.5talirtica, May20lTNalior.lo.cupalion.ltmploym$land UaBe E!ilmater-Unt€dStil6, May 2017 rfr F://ww.bh.gov/o4/.u..envo6_n.t.hlml. Houdy rat6 ror operatoc b6s n d.rator Dlantand svstm OftratoR - other l9l 3G91. !ainrenance Labor Rat. (5/hou4 530.23 ft.bllodht&iF Fnm.b6torth.orbn.d$rbrw.n c.lcul.t.db!3.donlh v.lu...nl.nd mth.&turrpa hb. ft.sEl@smn dto prctsn th.@ns.hwn onth.aorlE(hor. trb. rFdhladbrn Gltoiffirifrdfio4rermn hdEc6had: Au.hdty of 2-Prcpanol R6nov.d {wvoc) = v.elol.md.r(o): s{i.e &.. of Aeorber V.s.l (s) - Numb.r oftim.s c.nist.r(s) replaced pe. year = ffirhEmduhffiM: IlmcturAdsrytlon (e^l = :qulllbdumop.cty.tthc lnl.t(W.rE)) : woruna op.clty (w.) = E3lh.l.d Tobl Orbon R.qu[.d lM.] = tumb.rof C.6on OnlsR Sqdd = TohlO!.nthy ototun R.qulred for 1onlftG: Orhlbryf6i c.plbl Rcorry F.dor for.detur v.$li.nd.urili.ry qoipmnt (cffiSetur)= c.plul REorry F.dor lor c.6o^ lGFcrbJ : ws=nvre,rE= 6g fr. as fr. 133 q.fr I a,3O houri o.7s lb. voc/lb. c.rbn 039 lb. Vo(./lb. c.rbon 573 lbs. 3,m lb.. 0.1@ 05931 ! Erth.d o?atl qb ,o. . c..tdr c.dm Ad.o.t r uhh C.Ao l.Fbold 'll|t fh. ,cll(ha drnffi VOC Cortrolhd/Rcc4r.d. 2-P.ogel Mrqbdv6rd (Haihdd. Vddol Op.ndntsdr.drh . hEmlit ntoD.,.lion Tot l Ctanl lffi ffql th 2022 do{.n} 'bEffiTot.l C6t forAll Cerbon AdsorberCanisteE {€Ce-J = Auxiliary Equipment (EC.,,) = Totl Purch.$d Equlpm.m Co.E io, C.rhor Adsdbcr (Al = FreiSht = lmlhiloo C* lln 2022 dold Pa[nrat, okd.rd lndir.d lnstallation = Site Preparataoo (SP) = BualdinSs (8ldd = Continr.nryC6t (C) = E$.rln Canistar Cost x Numb€r ofCanisters nequired = (h*d on dlsi8n costs ore$im.t.d u.ing m.thods provid€d in Section 2) cd $43,E66 91m s45,866. ECsd+tqu. 0.O3xA= 0.6xA= EqEtLn 0.20x8= s4,s87 $1,3x $2,2ca Tot.l Purch.sd Equlph.nr Co.tr (8) - 55,,722 Cd s,$30 5o 5o Td.l Dkcd sd t.dlEd tnthlldlon C6. 54,330 ct(Purcha* Equipme.t C6t + ln*.lhtion c6B)= S5,t4S DHM6 P.ffi Operating bbd Co.tsi Maintenance costs: C.rbil Replacement CosB: lquion Oper.tor= 0.5 houE/shift x [abor Rat. x (Op€rating hour/8 hours/:hift) SupervLor = 15% otOpe.ator Labor = 0.5 hours/rhift x bbor R.te x {Op.rating kurs/8 houE/shift) M.t.ri.ls = 1OO% ot m.int.nan.! labor t.bor = cFR...hlbbor Rrt. x TdlcRR] = C.rbon = cRF..blccx T. x 1.081 = cd S9,rs3tnt S5,568 $s,66r $120 57,325 InC.6AmlCd P.nffi ov.rhead Administrative charSes PrcpcdyT.xes Capat.l R€covery EqEtbn : m96 of sum orop.ratoi, sup.flisor, maintenaoc€ labor Plus maint€nanc€ mateilals = 2% ofTCl : 1% oflcl = 1% ofTCl = cRFl,.*, x ITcl - [(1.08'cc 'Tc) + (LR*TclcRRl] = cd s1q3S7 51,286 9543 9643 ss,s:t!t CdalHY..rd lbnffi Totel Annual 6st = Annual Qu.hlityofVG Removcd = corl tffediven.ss = EqEtldt Wi.=mw.xg:xE. Total Annual Cost (TAC) / Annual QuantitvoIVOC Removed/Recovered: Cd Sar,376 psy.$in2o22dolhB o.lt m^,rs t2l6,lE, !q td ot polbt ntr rcmwd lh 20ZI d.llft Nor.: Ih! Idererpl6io. limn (LEL), h.n d comhEtion.nd mol..ul.r weitht fo, rome (ohmnlt usd vd/mP.re piovid€d in rh.r.blc hln. ln.ddnbn, rfi. h..r ol combustion ro be.nr.rd in column D b a ltuer &.ra.av.lue ltHV), nd. hider h..lnBv.lu. (HHvl. f2-il to Number ol op.rftng hours/ve.r lnldvolumevrcflow rd€lqJ.r 77!F..d 1 nm Motor/F:n tfltienq (El rnld w-r. c5 l.mpErature tr-J oFrdr.a T.mp.r{ur€ (TtJ O6nudb...d n.m@.| Efficienq (DRE) €nim.t.d Iqulpment Ltre P*@n EnqBRed.ry(HR). ; ] Nfur.lc.eFu.lcGr (caqEJ M.inten.n.. t.br r.le codin.€nq F.dor I CF) id.il (..a. Mal ! &rr.hh //ww.r..p/.hdkr!hnnuJAdhts_or_*hh[. M6nqhbdffiF.'s rErhI..@. at//fw.btr.p/-r.wmra._Mlhihl edy rb ro' op.d4u B3//ft.bLE/ilroa^vr1-nlhrh, bdyrErtu ddrr.r 4dF.fr r4r'r l.$?B) spropyl Alcohol N/ N/ N/ N/ N/ N/ NI N/ N,/ NI Constants usd in @lculations: Temperature of auxiliary fuel (Tr) = Density of auxiliary Fuel at 77 'F (p"r) = Heat lnput of auxiliary fuel (-Ah..r) = Density of waste gas at 77 "F (pr,,) = Mean Heat Cipacity of Air (Cr-.r) Reference Temperaturc (Td) = (For thermal oxidizers) 77.O't o.o4o8 tblft3 21,502 Btu/b 0.0739 tblft3 0.255 Btu/b'F Sum of volume f.action of combustible components = = (!x,) = Lower Explosive Limit of waste gas (LELmr) % LEt-, Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air = [:((xr)/((:x,) x LEL))l't . Where xi is the volume fraction and LEL the lower explosive limit for each combustible componen[ in the waste gas. = (Total Combustible Conc. ln Mixture/LEl*n) x 100 - = (LEL-tr x 0.249)/(:xi) E = (Total Adjusted Conc. With Dilution AirlLEl{!} x 100 = O ppmv 20,0@ ppmv O.0O pc@nt Not.pplic.ble Not Appli6blc lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. (From Data Entry Tab) = 3,725 scfm Oxygencontentofgasstream = 100-(:xjxXo0/105)a 2o.9op!rsnt Fan Power Consumption {FP) = (1.17 x 10'1 x O{ix API/€ 13.8 kW 4.. = Q-i= 3,725 ssfm Operating temperature of oxidizer (TrJ (From Data Entry lab) 1,900 'F Temperature of waste gas at outlet to preheater (T*.) = Heat Recovery x (Tri - T*J + T*i= 1,360 'F Temperature of flue gas exiting the regenerative oxidize. (Tro) = Tri - 0.95(Tri - Twr) = 190 'F Heat lnput of waste gas (-Allo.) = : (-ahci) xi Where (-Ah.J is the heat of combustion and x1 the fraction of component "i" at 77 'F. 0.0O Btu/sf Estimated Auxiliary Fuel Flow (Qs) at 77 'F and 1 atm. (Calculated using Equation 2.45 in Appendix B) 7.29 lcfm Auxiliary fuel Energy lnput = 5,394 Btu/min Minimum Energy requiredforcombustionstabilization = = 5% xTotal Energylnput= 0,05 xpr, x O., x Crd.x (Tn-T.d). 5,235 Btu/min ls the calculated auxiliary fuel sufficient to stabilize combustion? (Note: lf the auxiliary fuel energy input > 5% oflotal Energy lnput, then the auxilary fuel is sufficient.) Yes Auxiliaryfuelflow(Qafl at77'Fandlatm.= Tscfm Total VolumetricThroughput (Qr.r) at 77'F and 1 atm. = q{i = O*o+ CL + A€r = Q*r + qr= 3,732 sdm C.*dfcorqlraor: I ' ,,'. Capital Recovery Factor (CRF) = i (1+ i)"/(1+ i)" - 1 = Where n = Equipment Life and i= lnterest Rate lncinerator + auxiliary equipment'(A) = Equipment Co.ts (EC) for Re8€nerative Oxidizer lnstrumentationb = Sales taxes: Freight = Foundations and Supports = HandlinS and Erection = Electrical = PipihB -- lnsulation for Ductwork = Painting = Site Preparation (SP) = Buildings (Bldg) = Tot ltIEctCosts(DC)= Entineering = Construction and field expenses = Cont6ctor fees = start-up = Performance test = =(2.204 x 100,000 + 1157 Qtot) x (2022 CEPU1999 cEPcl) = 0.10 x A= 0.03xA= 0.05xA= 0.08xB= 0.14 x B= O.04xB= 0.02xB= 0.01x B= 0.01x B = B+C+SP+BHl= tffil Oktct lnrt.lLton costs = ss6,154 s2,.,on ssr,15,1 9u,63r ss,815 IotllndhcrCostr0C1= 5162,832 992,833 ln 2022dolhr3 s/rs,283 3r4,7ts 924,s2 9581,543 in 2022 dolLrtTof.l Purch.$d.quiprcd @.t5 (B) = F@tnota3 a - AulllLry .qulpmnt lndudcs Gquhmot (c1., duct rcrt) lm{y rct lncld.d wnh untt furnist d by iEhrrntor wndor. b - lrclld.s th. lBtrumnt tbn .id @ntrob fumlshad by thc lrclmntor Endtr. DeGr rdr*q|Coctr&r 2022 doLrrl 546,523 9t!015 32?,262 511,631 ss,rls $5,815 90 9o 5174163 $756,005 tn 2022 dolLrs roiJ lndct ln ilirdon ccir(h21122 dotrl 0.10i8= 0.05x8= 0.10r9= 0.02x8= O.01r B = Annual Electricity Cost Annual Fuel Coats for Natural Gas Operatin8 tabor Maintenance Co5ts = Annual Electricity Usate: OperatinS Hours/year x Eledricity Price = = costtud x Fuel usate Ste x 50 min/hr x operating hours/year Operator = O.5hours/shlft ' Ubor nate ' (Operating hours/8 hours/shift) Superui5or = 15% ofOplrator Labor = 0.5 hours/shift t tabor Rate r (OpeEting Hourr/8 houR/shift) Materials = 100% of malntenan@ labor s3,4s3 537,125 s9,37s S1,/O6 S9,375 S9,375 overhead Administrative CharSes Property Taxes lnsurance Capital Re@very = 50% of sum of operatlnS, superuisor, maintenance labor and meintenance materials = 2oA ol lct = 1% of TCI = l% ofTcl = CRFlTCl1.08(cat. Cost)l s17,7ts sm,2t1 910,107 s10,107 Sgs.4os Cost EfiGctlEms = (Tot l Annual Costlfl]Annul qu.mtty ot VOC/H P Pollut nts Destrcyld) Annual Cost (TAC) =Prr yaar ih Pollutants Destroyed =0.0 tmslyc.r Eff.diveness =ton of Emdln doll.E to&:The lil.rdplGion limn {tEL}, h.d d.ombuttion.nd mole(ul.rw.i8hr,or3om.(ommnt usdvoc/HAP.r.provid.dinrhetablebelil. Inaddtlo.,th.h..tolcombBtionro&entq..d in.olumn D ira lde. heatingvalue (tHV), nd.hEner he.nn,v.lue lHHv). t@ P.r...l 8..ry R.cw.ry{HR} =llnl.tvolum€tkllow r.r.(q) il r7'F.nd I nm Moto./Fan Efi i.i.n.v (.) lnl.t w:rte G5 Temper:rure (i") op€rn int Ieftperar u,e (IJ D6rudDn.nd R€n@J E('.'.nq (oRE) Esrinded Equrphent tre Enih.r.d c.i.tFr l[. ly) sp.ce velo.ny f or c.r:trr lO) CtEl'1o.2022 Ndu.elcsFu.l c6r (c6teJ Ma..ren.ncet.br rale continqenq Fador {CFl tuffiEc'db*&lrs rr.. .nir .r..vrc ry .6r ,or rnd* 16.6dr.dby h.! s .^.,r ^r.h lsr //*w.ir.p/.i.drLi!/rniu.rhrhr/.p. 0z e.hrl. 6hhtqark.6,.6p.effi q//ff*a/.l@/d8.ffi. io rffi .t.p/dov/ir'h4n3o$u.^.hb hxhhfQao&hdrsdp.'he rb?Mdo/dil@ol5lgh. rs'//wwwbB@/-*umivd'_n.Ltufrr edyrnrtury.B: .dildd.tuPi.m.nd trEm6(B e. l9r3Bl ,@!/fw b ! F/a*urc^r'-r_othr6). env aE. k sopropyl Alcohol N/ N/ N,/ N/ NI N/ NI N/ N,/ Constants used in calculations: Temperature of auxiliary fuel (T",) = Density of auxiliary Fuel at 77'F (p,r) = Heat lnput of auxiliary fuel (-Ah."r) = Density of waste gas at 77 'F (p*,) = Mean Heat Capacity of Air (Cr.",,) = Reference Temperature (T,"r) = (For catalytic oxidizers) 77.0 .F 0.0408 tb/ft3 21,502 Btu/lb 0.0739 tblft3 0.248 Btu/lb'f Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas {LEL.|,) = (:x) = = tt((xr)/({:x) x LE!))1 I = Where xr is the volume fraction and LElr the lower explosive limit for each combustible compohent in the waste gas. = (Total Combustible Conc. ln Mixture/LEl-i,) x 100 = = (LEL.; x 0.2as)/([x) = = (Total Adjusted Conc. With Dilution AirltEk,,) x 100 = (From Data Entry Tab) = = 1oo - (:xr x 1oo/101 = = [{1.17 x 10 4) x o*,x AP]/E = a*,= (From Data Entry Tab) = Heat Recovery x (Tri - T",) + T", = =T.-T +T = = : (_ah.,) x, Where (-Ah.J is the heat of combustion and { the fraction of component "i" at 77 't (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5%xTotal Energy Input =0.05 xpr x Q, x Cr-r, x (Tr, -T,*) = (Note; lf the = A{o, x (s1e)/(77 'F + 460) = Where Oft is the volumetric flow rate of the waste gas (Q) corrected to 60 'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) 0 ppmv 20,000 ppmv % LEL^i, Oilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77"F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) a*. Operating temperature of oxidizer (Tr,) Temperature of waste gas at outlet to preheater (T*") Temperature of flue gas exiting the oxidizer (Tr") Heat lnput of waste gas (-Ah.*,) Estimated Auxiliary Fuel Flow (O"r) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% ofTotal Energy lnput, then the auxilary fuel is 5ufficient.) Auxiliary fuel flow (Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (qd) at 77 'F and 1 atm.=q,=O{o+q+qr=O{r+qr= Cakulatlon o, CatalFt Volume and E3tlmated TempeEturc of W6te Gas Enterlnt th€ Catabst Bed Volumetric Flow Rate at 60'F and 1 atm (Oi) Catalyst Volume (Vol.r) Estimated inlet temperature to the catalyst bed (T, ) = Capltal ReoEry Factor: 0.00 percent Not applicable Not Applicable 3,725 scfm 20,90 percent 16,7 kW 3,725 scfm 900 .F 660 .F 340 .F 0.00 Btu/scf 25.33 scfm 22,223 Btulmin 2,908 Btu/min Yes 25 scfm 3,750 scfm 3,625 scfm 7.25 ft3 900'F Capital Recovery Factor (CRF) =i (1+ i)"/(1+ i)" - 1 = Where n = Equipment Life and i= lnterest Rate Futurc lilrorth Facior Future Worth Factor (FWF) = i [1/(1+ i)v - 1l = Where y = Catalyst Life and i= lnte.est Rate lncinerator + auxiliary equipment' (A) = Equipment costs {EC) for a Fixed Bed Catalytic Oxidizer tnstrumentationb = Sales taxes = Frei8ht = tggbcE! = (1,1143 x Qtot^(o.ss27)) x (2022 CEPU1999 CEPCI) = 0.10rA= 0.03xA= 0.O5xA= by hEhcnlor wndq DlrGthnrll|tbn c6ta 0tr 2022 doLcl 0.08xB= 0.14x8= 0.04x8= 0.02x8= 0-01x B = 0.01x8= 8+C+SP+Bldg= S2t9,665 ln 2022 doll.B s28,966 9r,G9o S14,413 S341,t05 ln 2022 dollars . - Aulhry tqulpmnt lndtdG qqulpGnt (..s., duct rcrt) rcmlly rct lndufu wfth unlt furnir b - lmhd.r th. lnstrumnt tlon .nd @ntro& fumlshed by tfiG lrclmntq wndor. Foundations ahd Supports = Handling and Eredion = Eledrical = Piping = lnsulation for D!ctwork = PaintinS = Site Preparation (SP) = Euildin8s (Bld8) = Tot l DiEct Costs (DCi) = EnBineerins = Construction and field expenses = Contractor fees = Start-up = Performance test = Continehry Cost (C ) = TotC lndlrct lmtdilrtbn CoEtt (h mA:l &llr{ 0.10x8= 0.05x8= 0.10x8= 0.02x8= 0.01x8= TelDid lffilbbn Co*= 527,344 547,853 s13,5-r2 S5,t36 s3,418 s3r18 so so S102,s41 5444,346 in 2022 dollars s34,180 s17,090 s34,180 56,136 s3I18 s9s,7o5Total lndlEct Costs (lC) = CF(lC+DC)= Catalyst Replacement Coit Annual Eledricity Cost Annual Fuel Costs fo. Natural Gas Operating Labor Maintenance Costs = 1.08 x CC x Vol..' x FWF Where CC is the S/ft' c6t for the replacement catalysc Vol.r is the volume of catalyst required based on the waste gas flow rate (o{r} and the catalyst space 51'146 velocity (O); and FWF is the future worth fador. = Annual Electricity Usage x OpeEtinS Hours/year r Electricity Price = 54,f80 = Costtu.r x Fuel UsaSe Rate x 60 min/hr x OpeEting hours/year 5129,W Operator = o.shours^hift x Labor Rate x (Operating hours/8 hours^hift) 59,375 Superuisor = 15% of Oporator 5,,406 Labor = 0.5 hours/shift r Labor Rate x (Operatins Hours/8 hours/shift) 99,375 Materials = 100% of maintenance labor 99,375 overhead Administrative Charges Property Taxes lnsulance capital Recovery = 60% ofsum ofoperating, supeNisor, maintenance labor and maintenance mat.rials = 2'l ol"lcl = 1% ofTCl = 1% ofTCl = cRFtTcl-1.08(cat. cost)l s77,719 S11,881 Ss,941 ss,941 Sss,95r CGt EfrGctlv.nrs' (Totll Annu.l Colt)/(iAnnul qurntlty ofVOC/HAP Pollstrntr D6trcyld) Annual Cost (TAC) =5261,336 pcr yc.r ln 2022 doll$s 0.0 tons/yorPollutants Destroyrd = Xde: fte ld., dplGion limn (LtL), h.r dcomburnon a.d mol.cul.rweiShl lor rom cohmnly usdvtr/Mp.r.prdidedinrh.i.bl.hld. rn:ddtion,th.h.no,.omb6tionrohenred in column D a. liler he{ina v.lu. {LHv), nd. nid.r hEdi.avalu. (HHv). lumber ol oF..lina houc/te., rnh volumdrk f,il de{A"J.t 77ot.nd 1 dm Moto./F.n Effi.l.n.vk) lnla wde Ga I.mp.r.trr. FJ OFrring I€mp.r{ur. fri) D6tdid and R.M.l Eri.ienqlfft) tnimr.dEqllpru.r ltre Enlm.r.d.ar.h6t llf. ly) sr. vebov to. cd.hEr {o} CErcl'fo,2022 Nnur.lG6Fuel c6t (C6nr) M.lnt.na... L.br rar. Per€.tt..rdRE@.ry(Hi). "; l :.dr&, kfrEroiuE u*r $oid. rbacH4tuur h,rr^b 'sr./*w.L.p/.L.nd!/.^^qifr nurF_o2,(h6o ffilqhbddE.ffi Qrh-d.@e @r/ff.* p/ddffiU.sl9d^ hh tuleblo^){rbdGp-'M t6rh*a&/|@, ,E//wr.b[ F/erdrcnvs_M.hhl eudy 'rbr 6r Constants used in calculations: Temperature of auxiliary fuel (T,, = Density of auxiliary Fuel at 77'F (p") = Heat lnput of auxiliary fuel (-Ah."r) = Density of waste gas at 77'F (pw,) = Mean Heat Capacity of Air (ca.",,) = Reference Temperature (T.d) = (For catalytic oxidizers) 77.0'F 0.0408 tb/ft3 21,502 Btu/lb 0.0739 lbft3 0.248 Btu/lb "F sopropyl Alcohol NA NA NA NA NA NA NA NA NA 0 sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEL-,,) = (:x,) = = [:((xr)/((:x,) x LEt))l 1 = Where xr is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. = (TotalCombustible Conc. ln Mixture/LEl*,,) x 100 = = (LEL.,, x 0.249)/(:xJ = = (TotalAdjusted Conc. With Dilution AirlLEl-,,) x 100 = (From Data Entry Tab) = = 1oo - (:xr x 1oo/101 = = [(1.17 x 10 4) x O*,x AP]/€ (From Data Entry Tab) = Heat Recovery x (Tr - T*J + T*,= =Tr,-T*o+T*,= = : (-Ah.r) x, Where (-Ah.) is the heat of combustion and x, the fraction of component "i" at 77 'F (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy lnput = 0.05 x pr, x Q, x C0.,, x (T6, - T.a) = (Note: lf the 0 ppmv 20,000 ppmv % LEL." Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilutioh air tnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) a*. Operating temperature of oxidizer {Tr,) Temperature of waste gas at outlet to preheater (Tw.) Temperature of flue gas exiting the oxidizer (Tf.) Heat lnput of waste gas (-Ahc*J Estimated Auxiliary Fuel Flow (Q"r) at 77 "F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% ofTotal Energy lnput, then the auxilary fuel is sufficient.) Auxiliaryfuelflow(Qaf) at77'Fand 1atm. = Total Volumetric Throughput (q"i) at 77 'F and 1 atm.= Qr, : Q*6 + q + qr = Q*, + qr= 0.00 percent Not applicable Not Applicable 3,725 sclm 20.90 percent 16.7 kW 3,725 scfm 900 .F 650 "F 340 .F 0.00 Btu/scf 25.33 scfm 22,223 Bru/min 2,908 Btu/min Yes 25 scfm 3,750 scfm 3,525 scfm 7.25 ft3 900 "F Cahulatlon of CatalystVolume and f,stlmated Tempeaturc of Waste 6as Enterlng the CatafFt 8ed Volumetric Flow Rate at 60'F and 1 atm (Oi) Catalyst Volume (Vol."r) Estimated inlet temperature to the catalyst bed (T.J = Capltal R€covery f actor: = qo, x (s19)/(77 'F + 460) = Where On is the volumetric flow rate of the waste gas (O.J corrected to 60'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) Capital Recovery Factor (CRF) =i (1+ i)"/(1+ i)" - 1 = Where n = Eouioment Life and i= lnterest Rate Iuture Worth Factor Future Worth Factor (FWF) = Where v: Catalvst Life and i= lnterest Rate lncinerator + auxiliary equipmentr {A) = Equipment Costs (EC) fora Monlith CatalytacOxidizer lnstrumentationb = Sales taxe5 = Freight = Foundations and Supports = Handling and Erection = Eledrical= Piping = lnsulation for Ductwork = Paihting -- Site Preparation (SP) = Euildinss (Bldg) = Total DlGct Cost! (DC) = Engineering = construction and field expenses = Contractor fees = Start-uP = Performance test = Continenry Cost (C ) = = (1,i143 x Qtot^(0.ss27ll \ 12022 CEP!lL999 CErctl . 0.10xA= 0.03xA= OO5xA= 0.08r8= 0.14x8= 0.04r8= 0.02xB= 0.01i8= 0.01x B= Total DlEct lnstallaton Costs = 8+C+SP+8ldg= Tot l lndlct lEtJlrdon Catu (h 2@ll &lhrl 0.10 x B= 0.05xB= 0.10x8= 0.02x8= 0.01x B = Total lndircst Cost! (lC) = cF(rc+Dcl= 5289,665 in 2022 dollars S28,e66 58,690 S144&] S341,to5 in 2022 dollarsTotal Purchaed .quipmnt @ds (B) = F@trcta3 . - Auxill.ry equlprent iodud$Gquipmnt (.I., duct mrl) rclmlly not includ.d wlth unh turnlsd€d by incineratorv.ndo.. b - lrcludcs th! lnetrurcntrtion .nd @ntrok fumlshcd by tie lrclnentor Eidor. Dll*t lntt.lLdon C6b I n 2OZr dolllBl 527,344 s47,Es3 5t3,672 S6,t36 s3,418 s3,41r s0 so S102,541 5/t44,345 ln 2022 dollars s34,rE0 Sl7,o9o s:x.1ro s6,836 s3,418 s9s,70s Ss4,oo5 Catalyst Replacement Cost Annual Eledracity cost Annual Fuel Costs for Natural Gas Operating tabor Mainlenahce Costs = 1.08 x CC x Vol..r x FWF where cC is the S/ftr c6t for the replacement catalyst; Vol..r is the volume of catalyst required based on the waste 8as flow rate (Q&) and the catalyst rpace velocity (O); and FWF is the future worth factor. = Annual Eledricity Usage t Operating Hours/year x Eledricity Price = = costrtu.r x Fuel UsaSe Rate x 50 min/hr x OperatinS hours/year Operator = 0.5hours/shift x Labor Rate x (Operatin8 hours/8 hours^hift) Superyisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operatins Hours/8 hours/shift) Materials = 100% of maintenance labor s1,146 s4,180 s129,040 S9,37s S1,406 s9,37s s9,37s overhead Administrative charSes Property Taxes lhsurance Capital Recovery = 6096 of sum of orErating, superyisor, maintenance labor and maintenance materials = 2',t ol 7Cl = 1% ofTCl = 1% ofTCl = CRFITCI-1.08(cat. cost)l St7,7t9 su,t8r ss,941 55,941 s55.958 @st EfiGctiEm$ = (Tonl Annull Cost)/(Annual Qu.ntity ofVOC/HAP Pollutants Dcsuoy.d) Annual Cost (TAC) =pcr wtr In Pollutants Destroyed =O.O tons/ylar ton of rcmorcd in 2022 doll.rs Nore: The ltuer erplGion limh {tEt), h.a d combErion.nd mol..ula.w.iah fo. tm€.oBmnly 6.d voc/HAP are provid.d i.lhe labl. b€|il- ln dhioo ihe heil of.ombuiton lo h enr.rd Pekenr En€rei6@ery(Hn)= ;F.-, ;l l.kvolumetd(flwrre{q-J.t77qF.nd!nm Moio/r.n Etrcienql.) hh Wer. G6 I.mperature lT-J oFraangTemp.rilu.. (IJ D6rrudao...d n.md.l tff i.i€.q IDR[) Esrm{ed Equipm.d l{e Eiimn.d c.r.brliL (Y) sp.c. v.lo.ty tor dr.rFl lol Clmlr fo.2022 N.iu,.l G.t Flelc6l (c6!-J M.inl.n.n.. L.borr.r. Co.ilna.ncy rador(cF) !rdcrrc,,lsBen4edind , s.didr lru. ur d 06, snriil^ .on id.r8 (... , Msl B ..apubh @ pdpmMftd+1.-tuft *-ddhtu5E.. .#hMbdSft 16 .aik by tu u 5. En.rd hbh rdd q b- Era&1.d s rt ior/lw..i.s/.hdti!/.inu.rhrh/.4 02 o1.hh0 hM@&&lBds.rl& a/h{@,k a?/trv!h e/dfr MBvnrorsBr^.hh hMM&&d,gde.'Ld &/hd@. ,s. //trih p/dr.46vdi_dthn) xoudy (.! b, Qi.rd! rd6d.. kohddsFnr krM dhrltl.@) E //*l hB.p/rv.u,nnv$ orhh). &udy .G br durd, {iF.^r r.tsr., 1.e18). sopropyl Alcohol NI NI NI NI NI NI NI NI NI NI Constants used in Glculationsi Temperature of auxiliary fuel (T,i) = Density of auxiliary Fuel at 77 'F (p") = Heat lnput of auxiliary fuel (-Ah."r) = Density ofwaste gas at 77'F (p*,) = Mean Heat Capacity of Air (C.-.r,) = Reference Temperature (Trei) = (For catalytic oxidizers) -17.o "F o.Mo8 tblft3 2L,5O2 Btu/lb 0.0739 Ib/ft3 0.248 Btu/lb "F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEl-i) = (rx,) = = tl((x,)/((Ix,) x IELJ)l '= Where xr is the volume fraction and LELj the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl-i,) x 100 = = (LEt*," x 0.2ae)/(:x,) = = (Total Adjusted Conc. With Dilution AirlLEl*t,) x 100 = (From Data Entry Tab) = = 1oo - (:xj x 100/106) = = [(1.17 x 10 4) x Q*,x AP]/€ (From Data Entry Tab) = Heat Recovery x (Tfl - T*J + T*r= =Tii-T.o+T*,= = : (-Ah.i) xr Where (-Ah.,) is the heat of combustion and \ the fraction of component "i" at 77 'F (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy lnput = 0.05 x pr x qi x Ce.r x (Trr - T,e, = {Note: tf the 0 ppmv 20,000 ppmv % LEL-i Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) a OperatinE temperature of oxidizer (Tr,) Temperatu.e of waste gas at outlet to preheater {T*.) Temperature of flue gas exitang the oxidizer (Tr.) Heat lnput of waste gas (-Ah.*,) Estimated Auxiliary Fuel Flow (Q", at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy I nput, then the auxilary fuel is sufficient.) Auxiliaryfuel flow (Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (q.t) at 77 "F and 1 atm.= Qr, = Q*" + CL + qr = Q_, + qr= 0.00 percent Not applicable Not Applicable 3,725 sdm 20.90 percent 16.7 kW 3,725 sdm 900 .F 660 .F 340 .F 0.00 Btu,/scf 25.33 scfm 22,223 Btu/min 2,908 Btu/min yes 25 scfm 3,750 scfm 3,625 scfm .t.2s fe 900 .F Cak{l.dm of CatahEt Volume and Estlmated Tempe6turc of W8te Gas Entedng the Catalyst B€d Volumetric Flow Rate at 60'F and 1 atm {qr) Catalyst Volume (Vol."r) Estimated inlet temperature to the catalyst bed (T,,) = Capital R€mry tactor; = qo, x (s19)/(77'F + 450) = Where Q( is the volumetric flow rate of the waste gas (q) corrected to 60 'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) capital Recovery Factor (CRF) =i (1+ i)"/(1+ i)" - 1 = Future Worth Factor Life and i= lnterest Rate €quipment Costs (EC) for Fluid Bed Catalytic Oxidi2er = ((8.39 x 10,000) + (192 x qtot)) r (2022 CEPI/1999 cErcD = 5331,211 ln 2022 dolhB tnstrumentationb= O.1OXA= 533,121 S.lestares= O.03xA= 59,936 Freight= O.OSXA= Sf6,561 Tot l Purch.sed Gquiprent @st5 (B) . S390,t29 in zl22 dolhr3 F@tmt i . - Alrnbry lgulpmnt Inctrdcs.quhmnt (G{., dwt rcrt) lrm{y not lrchdGd wlth unlt fumb{od by lrclncntor rcrdor. b - lrcludr. th. lnstrurunt tbn .nd @ntro& fum&hcd by tltc lmlmBtd wndor. Dkcd lntr.Irdil cor.3 Sn 2oz dob.rl Foundations and Supports = HandlinS and Eredion = Eledrical= PipihS = lnsulation for Ductwork = Paintihg = Site Preparation {SP) = Buildings (Bldg) = fot lDlcctCo6ts(DC)= EnEineerins = construction and field expenses = Contractor fees = start-up = Performance test = 0.08xB= 0.14x8= 0.04x8= 0.02x8= 0.01x B = 0.01x B = B+C+sP+8ldl= s31,256 554,715 91s,633 s7,tt7 s3,908 93,9o9 so 9o 3117,249 5508,078 In 2022 dolhE 939,0t3 519,s41 s39,083 57,tr7 s3,908 s1c,r32 s61.751 Tot l Dlcct lrst lLto!Costs. Tot l lrdlEct Co3ts (lc) = Ioa.a h&*r h.t{mon Catt(h m[:l &[nl 0.l0xB= 0.0Sr8= 0.10x8= 0.02x8= 0.01rS= Catalyst Replacement cost Annual Electricity Cost Annual Fuel Costs for NatuEl Gas Operating Labor Maintenance Costs = 1.08 x cC r Volc.r x FWF where cc is the S/ft3 cdst for the replacement 6taiys! Votr is the volume ol catalyst required based bn the waste gas flow rate (qfr) and the catalyst space velocity {O); ahd FWF is the future worth factor. = Ahnual Eledricity UsaSe x OpeEtinS Hours/year x Electricity Price = = costtod r Fuel usaSe Rate x 60 min/hr i Operatihg hours^ear Operator = 0.5hours/shift x tabor Rate x (Operating hours/8 hours/shift) Supervi$r = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operating Hours/8 hours/shift) Materials = 100% of malntenance labor 51,146 s4,lto s129,(xO 9e,37s s1,406 5e,375 ss,375 overhead Administrative Charges Property Taxes lnsurance capital Recovery = 60% of sum of operating, superyisor, maintenance labor and maintenance materials = 2",6 ol fcl = 1% of TCI = 1% of TCI = CRFITCl-1.08(cat. cost)] 5,7,7r9 $r3,srs s6,793 56,793 s64,001 Cost EfflctiEms - (Tot l Annurl Costl/(i\nnual Quantlty of VOC/HAP Polld.nts D6trcyrd) otal Annual Cost {TAC) =787 p.r y..r ln 0.0 tonsrarVOC/HAP Pollutants Destroyed = Effectiveness =ton ol cmwd ln Zr22 dolhtr serhtrFdde F;;; l Nore:Th.lil.r6pl6ionlimh{lEt), h.rdcombutrio..ndmol..!l..wethilorrom..ommnlv utd vtr/MP.re p.ovid.d r th. r.hl€ &|il. l..ddilion, the he.t of.ombction ro h.nrer€d i. collm 0 R. lild h..lhae.l!e (tHV), nd. h8he, h..tinaval!. (lHV), toa lm Number doF iling hours/yerr rnla volum.rkffow rde{qJ zr77!t.nd r rm Moto,/fzi Efrcbncyl€) rnl* w.ne cd T.hp.r.rure (TrJ oFrrin! Temperilur. Oi) 06rdid.d 8em@.1 Efl icEnq {DiE) tnimiled tquPm.nr L{. P.r.enr Endqnecovery(Hi) =l N3ru..l caFuei c6r (c6!d) M.inren.... L.brr{. conriqs.yF.dor lcr) . csPottuo.nior EniEil...dc6reoL6ip..knilbnr& r dIro fc.d*.r E6 ut. d om!.{{*nan.6r id.!r h 4. M6l a reil.bb P.r.na.6 lo. Cohno6 Cohpoudt FdFdni!4*dqtbtuft&dd6tudI. bqlldhreetud* ,r!a. .^isr .r.drry 6r b hd6r ,E.mpr.d byh u.s. hryr.to'm s.//ltt .i: p/.Bdq/riiurhri/.p.-01 @ h6[. ffi@E-ausl4ffi ffilqek@tedB.rr& s/h*9@/btu. a/f}r !h F/du/n4[ri301e61^h6. dt&6@&nbmltds.'M!& '@Jh.ll@h, s!/fr bt p/dcurc.rG n.(hrh,. Houdy ilB tda&3 s3 //Nw bk.p/drcom.v,3 nrlhim). Hoqny rbr b Fprcpyl Alcohol ( ( N/ N/ N/ N/ NI NI NI NI N/ N/ Constants used in calculations: Temperature of auxiliary fuel (T., = Density of auxiliary Fuel at 77 "F (p.r) = Heat lnput of auxiliary fuel (-Ah.a, = Density of waste gas at 77'F (p*,) = Mean Heat Capacity of Ai. (CD..i,) Reference TemperaturF (T.d) = {For thermal oxidiu ers} 77.O'F o.(xo8 tb/ft3 2!,502 Stulb 0.0739 tbft3 0.55 Btu/lb'F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas {LEI*L) = (:x,) = = [((x:)/((Ix,) x r-Er))] 1 = Where xi i5 the volume fraction and LEli the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl."i,) x 100 = = (LEt." x 0.24s)/(!x) = = (Total Adjusted Conc. With Dilution Air/LEl-") x 100 = (From Data Entry Tab) = = 1ss - 15x,,1s97191 = = [(1.17 x 1O4) x cLix AP]/e = e*i= (From Data Entry Tab) = Heat Recovery x (Tf; . T,,) + T*,= =Tri-T*o+T,i= = : (-Ah(i) xi Where (-Ah.i) is the heat of combustion and \ the fraction ofcomponent "i" at 77 "F (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy lnput = 0.05 x p,, x Q, x Co.1 x (Tq - T,a) = (Note: lf the O ppmv 20,000 ppmv % LE|-L Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm, Oxygen Content of 8ar stream Fan Power Consumption (FP) a*" Operating temperature of oxidizer (TrJ Temperature of waste gas at outlet to p.eheater (T..) Temperature of flue gas exiting the oxidizer (Tro) Heat lnput of waste gas (-AIL.J Estimated Auxiliary Fuel Flow (O*r) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) Auxiliary fuel flow (qafl at 77'F and 1 atm. = Total Volumetric Throughput (q"J at 77 'F and 1 atm, Crpftd flcoulry Facton = Q.r = 0*6 + Q" + Q.r = O{i+ qr: 0.0O percent Not appli€blc Not Applicable !,725 sc,m 20.90 perccnt 13.8 kW 3,725 sqfm 1,600'F 1,150'F 550 'F 0.00 Btu/scf 49.16 scfm 43,124 Btu/min 5,267 Btu/min Y!s 49 scfm 3,774 sclm i (1+ i)"/(1+ i)" - 1 =Capital Recovery Fador (CRF) = Whele n =Life and i= lnte.est Rate c6t3lh 2022 lncinerator + auxiliary equipment' (A) = Equipment Costs {EC) for Recup€rative Thermal Oxidizer lnstrumentationb = Sales taxes = Freight = Foundatiohs and Supports = HandlinS and Erection = Electrical = Piping = lnsulation for Outuork = Painting = Site Preparation (SP) = Euildings (Bldg) = Tot l DlEct Costs (OC) = Engineering = Construction and field expehses: ContEdor fees = Staft-up = Performance test = = (21,342 x Qtot{o.2s)) x (2022 CEPI/1999 CEPCI) = 0.10rA= 0.03xA= 0.05x4= Dlrcr ttrrrdl./tril cdtr 0n 2ozr dolrn) 0.08x8= O.14xB= 0.04x8= 0.02x8= 0.01x I = 0.01x B = Tot l DiEcl lnst lhton c6ls = 8+C+5P+BHg= Toi.l lndrEt lnrtlllatbo C6tr (h 202:l dollill 0.10x8= 0.05x8= 0.10x8= 0.02x8= 0.01x B = Total lndlEd Cost5 (lC) = 5355.370 in 2022 doll.B s35,s37 S10,6E1 s77,7@ 919.337 in 2022 dolL6Total Purci.icd lquiprcnt @sts (B) r &chets! . - Auxilhry Gqulpmnt lacludc3 .qulprcnt (e"g., duct wrt, @mlh not lndudcd wfi unlt fumbfrrd by lrcln.ntor wndor. b - lncludrg thc lndrurcntrtlcn .rd @ntrols furnish.d by thc ircimnto. Endo.. S33,sq ss8,707 $16,773 st 3t7 s4,1e3 s4,193 so so s12s,ro1 5545,138 ln 2022 doll.rs 541,934 s20,967 s41,s34 s8,387 s4,1s3 s117,414 S66.2s5Continenry Cost (C I = Annual Electricity Cost Annual Fuel ests for Natural Gas Operating Labor Maintenance Costs = Annual Electricity Usage x Operating Hours/year x Electricity Price = = Costtod x Fuel Usage Rate i 60 min/hr i Openting hours/year Operator = 0.5hours/shift x Labor Rate x (Operatin8 hours/8 hours/shift) Supervisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operating Hours/8 hours/shift) Materials = 100% of maintenance labor s3,4s3 s2sorol s9,37s S1,/()6 s9,37s s9,37s overhead Adminirtrative CharSes Property Taxes ln5urance capital Recovery = 50% of sum of operatlng. superyisor, maintenance labor and maantenance materials = 2% ol TCI = 1% of Tcl = L% ol rgl = CRF x Tcl St7,7t9 s14s76 S7,288 sz28E S58,794 *.t ,O"o1-65 - (fotal Annurl Costl/(Annul Aulntity of VOC/HAP Pollut nts Drstrowd) otal Annual Cost (TAC) =Plr y!.r ln Pollutants Destroyed =0.0 tons/ymr Effectiveness =ton of rcmndln MOLD PREP ROOM BACT CALCULATIONS-HAP Volume 2: Ch.gter 8r Prefered and Afternative Methods for t5tim.ting ah tmissions from Paint, lnk 4nd OtherCo.tinS Menufaduring F.cilities Emkrbn Md.lturSudfr.EEEdbn Mdh.nol lat<d ft O.O524a2S2lbsia 0.2 2 Vind Soeed Sa.latatmoh ,ass Tri nsfer coefficient 0.097333631fr/se€ nilersl Gas Constant 10.73lpsi.-fr /' Rlb.mol R 0.00510934 rir knsitv o.763lrb/ff 67os(mlft'/vr 0.31893563711b.moU! 8.6072513581ft3/vr Padial VaDor Pr€ssur€ lRaoult's hwl o.375ltb/lb 32.O 0.01170 iouid mole fr.dion 0.76s99 ,dirl Vrh6r PrRor.1 o.42221 iquid ma33 ftadion 0.1751tb/tb 0 'adi.l V.oor P16sur€0.o5248 iattAlirblk EDmh 0.34573 ,sia o17 124_ttO 0.m136 0.835 'anial Vapor Prssur€ 0.02silb/tb 124.0.m19 iouid mole fradion 0.o1276 'atial Vapor Prssure o_olsltb/tb 132.:o.m11 iquid mole fraclion rdirl Vr.6r Pr.rsur. 0.001:b/tb Glts stf3,€Art4 coNc, ?tiPiilhL nFDp fRes. C\ L er,t t-,\77 DAI s - l-{ Atrs 92.1411b/lb.mol 1r q.i P.ri.l1 V.66. Pre..xr. 2, Vind speed lOltos 58.18181mph lnrversal Gas constant tg.r. 531 R n 1Str6r777Illh/hr Mit h6ud! o.ffi4o3622[on/vaar 0.7531tb/fr' 3725l5CFM o 1475m1ilb.mOl/vr t-985SO5S3 i.t St6m Com,0,m5relrDw eqAl.{ .)ha.) MAg e4td) .e9gS -Eo?r+l Jlltr#t$ . eu\orr?tJr.t3J/i) , UdtutyFdo&n.&drryn m: b&.Htr ffi, Fid.tu*sthffibn: Sdd th. ryF ol W.tb. i S.ld thc typ. d m.t{l.lud to f.M6reth. orbn.*drv6td3: S.ld th. oilnl.tlon tor S. .d$6.r wsd.: L lI f Numb.r ol ry.tiq houB F ys. {4.) w.n.G8 Flfl8.t. (Ol vCEmlrslon R.t. (e) Rqulrd voc..morl fid.q (E) Eit{m.t d qulph.ntlhof .urlll.ryEqulpm.nt (n) c.rbn Onkt!rsE. Nunb.rdotsttlnrHoursBdoroOrbnC.ni.t!rR.pl.@m6t €^) ,.2S adm' 0,m lbs/hour 10 Yea6 S lb..rbn oer.anirter m houB 98 rrcent 6 . d.oh .onror di.ie.ry user thould enler ad ua I vrlue, if lnown B adual.ubt ter/min rta ddauh &uimenrlile *e. shouldenlera.lual v.tue, il known lm lB ol.ar&n oe...nEler ir adelau[value. user should.nrer erdered canBter !ize, ifknown P.dl.lPrcsurc ol MS.ml/Tdrm ln w8t.t.! nr..m P.r.md.r "k'tu Mdh.mi /Td*m P.r.md.r'm' for M.th.nd /Tolu6. IrldYfbd'r'd'm-bmffi o.lto v@rltu hr&A CEPq'fo.2022 Annu.l lnt...n R.t. (l) Us.ofother*ell lnown.6t i.de!6 le.g., M&5) B.cceil.bl€ C.rhn C.nlrl.rCo* llkrcwn,.nt r.ny.ddltlo6.l c6Btor3lt. petsr.tlon SIt. Pr.Frdlo. (sP) - Eulldlqr (Bb!)= Equlm.dC6bls.urlll.ry4uir.nt(!.r.,dutuork, d.mFR,.ndnad) 6.tl.t.6q l.dor(cF) Note:Typicalc6Blolc.rbonc!nist.Rar.show.inTableB' ' Ddau[value.Uterthould€nie.adualvalue,if known &laohvalue.Ut€rthouldenre.a.ru.lvalu€,if k6own Ddaonvalue. uts rhourd enle. adual value, iflnown Io rrcent ts a delrult valoe. The . ontinsency factor 5hould b€ kween 5 and 15 Fr.ent r the values entered on the Doto ,nputs tab, These values were used to prepare the costs shown on the Cost Estimote lab. carbon Canlster Adsorhr with CanbEr Replacement Methanol / Toluene W*"=m*,xesxE= (m,",/w.) x Oo = e"/ oa= Number of operoting hours fufore corbon conistet repldcement = kxP^= 0.5 x w.1.-1 = (m".o/w") x Oo = Mo/Carbon Canister Capacity Number of Carbon Canisters ' Carbon Capacity per Canister = li x (1 + i)nl / [(1+ i)n - 1] = Where n = Equipment Life and i = lnterest Rate li x (1 + i)il / l(1+ i)" - 1l = Where n = Carbon Canister Life and i = lnterest Rate 0.012 tons/year 0 lbs. 1 4,300 hours 0.421 lb. VOC/Ib. Carbon 0.211 lb. VOC/Ib. Carbon 81 lbs. 1 canisters 3,000 lbs. o.L424 o.7574 tfudodtddtor.Cit .rc.r*n A*..t rrft c.ih.f.dmIlfi VOC Coitro[.d/Rftffi.d - lr.theol / ToludG Ad.dbdv...l O.lmt dn. ild ABlloU. Op.rdrr5dr.d{h = hrrifitmtODd.tbn fal C.tar.l |ilffiil (to,lh 1012 dollnl Total cost for All carbon Adsorber Ca^isters (Ec!d) = Auxiliary Equipment (Ec.,.) = Tot l turcir*d Equbmil C* ,or Cstoo Adldt t (A) . I E$.dc.r ] Gnist.r Coit x Numb.r otC.nisterchequircd = (&*d on d.si8n coils or esim.ted lising methods provlded ln section 2) ' Ec*ilEq-. O.10xA= O.03xA= 0.05xA= Cd til3,s6 32,@ s.s166 Freight: lffi[.tlon CG (ln IO22 doLd ,.ffi Site Preparation (SP) . Buildinss (slds) = Contlna.nqC6t{C) = TdC tu.dr...d Equhmnt Cd (B) = 94,3E7 $1,376 $2,2s3 s49,535 Cot 99,Nl $o So 39,$, ss,gaa Eqcdon 0.20r8= lfrl olnd rd lndrd lBhlhlon cd. CF(Purch.s. Equipm.nt C6t + lnS.ll.tlonc6b): Dt d^trulCd ,aEffi Maintenanca Costsl carbon Canirt€r ReDlacemenl C6tr: EqEdci O.Gr TCI lnst.ll.tlon Co5t = 0.2 x Number ofCdnirt.rs x Cost per Canister x CRF . Canist.6 = number ofcanist€rs x cost per canister x 1.08r cRF = cd s3,923 krCrrtA!,t.1Cd Administr6tiv. Char8es Prop€rtyTaxes Capfral Recov€ry Eqcd.n = 2% of lcl = 1% ofTcl . 1% ofTcl = CRfAuxiliary Equipmcnt x (TCl - l.o8{CanisterCosts)) = cd str3c s65,. S6s4 s2l,a CdEli.dm hffi lrotal lnnual ost = lAnnual QuantityofVOC Remov.d = Cost tftdiveness = Ecadon We=msxe,xE= Total Annual tust (TAC) /Annual Quahtity oIVOC Remwed/Recovered = cd 551,629 pdysh2o:l2dolhF O.01 ffip.ry€t $aA22n2 pstdoapofifirEremov.dh dols s.ld thc typc d c.rbn.eorEr.y*!m: tornrffi aM d.dq pffi ft Ho*thbffi : 5dd the W of ots.atlon: s.ld h.lyp. ol m.t.d.l u3d to f.briot. th. c.rbn a*dbr v63.k: S.ld thc od.nt.tlon tor tk .d$d.r Es*|.: l-*^":::rt'rr:rty" f L^-*"r'*:' f ,,.^..,;..; f l Numbd@datjq houE tsrys.{e,l w.st. c.. fril Rar. (cr) vGEml$ad Rit€ (e) BquirdvG rcmil.| trd.nq (E) E*im.td equipmGnt IIL ol.dsrbtrv6ds.6d.urlll.ry Equlpm.nt (n) E*im.td qdon lif. (n) Edm.td qtun R.pl.em$t R.t. {ciR) 3,25 .dm (.t O.G lbs/hour 3D lbs/hour' m lb..rh p€r..n6ler 98 percenl 6 a def.oh contol dicren(y Urerthould enl€r adual value, if known 179 lh /how 6 a d.uh v.rue U5q rhould enre. .ctual val ue, il tnown. rm lB o, . a, bn Er r anBrer ts a ddaoh value User should enter prderd can itter 3te, if kno*n Prdi.lPro$uEotMdh.ml/Tolu.n.lnw.il.3.rsr..m P.r.md.r'k" for Mdh.^ol /Tols^. P.r.md.r "n" lor M.th.nol /Tolud. CEPCI. tor2022 Annu.l lnt.r.rtRrt (l Useof otherw.llknowncostindex5(..r.,MS)is.c.€pt.ble. M.lnt.n.m.Ubr R.t. c.rbn c6t(cc) l, tnown, st r.ny.&frlon.l c6s for slt. pr.p.r.tlon Sh Pr.Frdion {SP} = Buildl$ (8Ur) = taiLEE ps €nBt.. (ih 2022 doll.rs)Typical @sts for.a.bon c..isters are 3hown in T.bl. B 530.2 3/hou. it a defaut value. &s should entil frual ealue, i t.o*n lt the rate ir nor kno*n, 6e 1. l0 x S4.20/lb is a defaukvalue b.!don 20l8 m.rlel ilice. Uld thouldenrer acrualvalle, il kno*n l0 percena6 a ddauhvalu. ThecontinSen.ytactor5hould h bt{een 5 and 15 percenl Equipm..t C6B fd.uili.ry.qulpmcnt (..!., dutuo*, d.mF6,.nd.t.d) (EqJ. contlns.qF.dor (cr) ' Odautvalu. Usershould enier..tual value, itknown Nautv.lu€. User should entEr.dual value, it known odautv.lue. uier ehould enter adual value, it known omdb{F&nf*rb.rtu h sl$ Oe.r.tor bhr8.t. lS/hour)s27.48 ur€audLaborStatiltics, MaV20lTN.lion.lOccupalionalEmploym6t.nd V.ge Estimat6- Unftdst.t6. May 2017 O*ritoB -otherl51-3691 {aint.n.nc. L.bor F.t. (5/hour)530 23 n.followlnad.rianF.n.r.Btorth...rbn.ds.brw.Eol.ul.t.dbedonth.v.lu.5.nrerodo.theOoad,,FBf.b.fr.$v.lu.3w.dus.dtop..FEth..o3lsshownontbCorafsa/-rt t.b. rFdffir3d.r qtu.otrh'&turdto*frr*mrm Mh. d vq hH: tfrnol/ Tolu.m Qlanilw ofM.th.nol/Iorus. Rlmond (Wwc) = sod.@ A,e. olA6o,b.r V.$.1 IS) = Nomb.rof tim.s..nistedd@placed p.rv.a.: &turhnm.6tuqtuOdfd: Ilm.forAdeDlion (eJ = Equllibduh Op.cny.t th! lnl.t (Wn-,i : worklntop.chy (w.) = Estlm.t.d Tobl c.rbon R.quh.d (M.) : Nunb.r ol c.6on cani.bB Rquld : Toul qu.ntrty of c.tron R.quir.d fo. I cari#rt = aDftlbrryren C.pGl REoEry Fft r for.ds6.r v.$ls and auxiliary.quipm.nt (cFnabbded: C.pibl R@rcry Fdor for ca6oo (GF6,8J = trtox(tlD/2)= Nunhr ol op.rdns holB b4orc cdb.n ciltd.r Epbcm.nt . (rJw.) r €. = Mdlc.6on C.nl$.r C.p.city ilumb.rofC.ton c.nlstuE r c.rbol C.paclv p.rC.nH.r" llx 11+ l)"1/l{1+ ili-11 = Wherc n: Equipment Lift.nd I =h+r6t Rat. tl x 11+ i)"1 / t(1+ l)^- 11: Where r = c..bon Lif..nd i: lntcrc*Rile 6.q fr. a.m ft. 133 tq.ft 1 4,3@ houB 0.421 lb. voc./lb. orbon 0.211 lb. vo(./lb. c.rbon 61 lb. 3,m lb5. 0.1M o_ssl Enlmhdoprblcdrd.CrrbffanlfiAd.o.t rrrfthcartqti.rLffiwltittrrblldlfch.nda.lttl6: VOC Cdroll.d/n cdd.d = Mcthilol / Tolucn. Ad.dbtr V6*l mnt.don = V.rtbl OFEtiu kh.dul. : lnt.min.nt Op...tion T6l C.Pabl lMtuil oo) (ln 2022 dolbEl hnmtff Total Cost for All Carbon Adsorber canisters (tcAd,-6) = Auxiliary Equipment (EC.,,) . Tot.l Purcha$d Equlpmnt Corb for C.rbor Adsdbd (A) = ldlLtba Cd (in IOz dolLrl h6M Direct and lndirect lnstall.tion = Sit€ Pr€paration {SP) = Buildinss (Bld8) = ContintenqCosl (C) -_ CqBtl.o Canist€r Cost x Numb€r ofCanisters Required = {8ased on desiSn costs or estim.ted usinB m€thods provid€d in S€.tion 2) = Ecd + Eq",. 0.03xA= 6 Sa3,ffi S2,oo $4s,6 s4s87 S1,375 32.293 Equtlff 0.20 r B= Tot.l Purch.s.d Equipmenl CosB (B) = S54,U2 cat $4,330 So so Tot.l Ok ct.nd lndircd lnsEllillm C6B = CF(P!rch.se Equipme.t cott + l^3tallation costs)= tl,330 ss,s Dld ArnulC66 PaEmtt Op€rating Labor Co*s: Maintenance costs: Carbon R€Dlacem€nt Costs: Eqqtlon Op€rator = 0.5 hours/shifr t L.bor R.te r (Oper.tinS hourr/8 hour5/rhift) SupeNasor: 15% of Operator labor = 0.S hours/shifr x bbor Rate x (Operatine Hours/8 hours/shift) Mat€rials: 1ffi ofmaintenan.€ labor Labor = ctR.,,hIbbor Rate r UcRRI = carbon = cRF..,s^lcc i T. x 1.081 = C6t ss,153 s773 S5,688 S5,ffi 912o 57,526 lndld^molCd hEffi Adminirtrative CharSes Capital Recovery Ecuthn = 5G ot sum of oper.tor, tuperuisor, maintenanc€ labor Plus maint€nance = 2% ofTcl = 1% ofTcl = 1% ofTcl = cRF^d-i, x ITcl - I(1.08 'cc 'Tc) + (tR'T€/cRR)l = tut 910,3s7 S1,2s $e3 s643 9s,s39 CdEMv.n6 Panmdr lTotal Annual cosi = lannual Quantityofvoc Removed = Cost Effe.tiv€ness = dt 9a1,276 p.ryerin2o22dolLB 0.01 tons/F.. 53,715,4r.0 p.r i6 of pollut.ntt rcmord in 2022 doll.E Eqotlon w"". =m"". x e,xE= Total Annual Cost {TAC) /Annual Quanlifl ofVOC R€moved/Recovered. seftrFd& F;;;-ln Not.:Th. lilerdplcion limn{lEL), h.n ol.ombusrion.nd mol.cul.rweEhl loriom.comm.ly !.ed Vtr/uPar. provid.d in rh. t.ble hlil. l. addirion, th. h..r d.ombuerion ro h..ierd in.olumn D b. low.r h€.ting v.he (LHv), not. hiaher h.ninav.l!. (HHv). Numb.r ol oFr.tins houR/yea, lnldvolum.tkflow r.te(a-J.r 77'F.nd 1 rm Moior/F.n E6den.y(E) rnld W.<. 6a T.frp.r.rur. (T-J oFrdhaT.mP.r.lor. O,J 06lrudlon a.d i.mov.l Efl idena (oiEl Eerim.r.d Equipm.nr tr. Perc.nt Ei.ro Reov€ry (8R). rcF.-,E rrddruMiiror!fl rr.rt lrrlto l.s Niur.l crFudc6r (C6ru) M.inr€n.n.. !.br rar. Co.!.4€nq F.dorlct) P.,rmd.B lor Common Co6@udr: & ffihrek@ft ffilcurourr@rm1ll{e s'/ffi.bk p/drcur.^v-'_mlhtm). tuny nB k @.dr triddd.t b DLil..dsFEhturd! oturGlml sr//ltv.br.p/dto6ivdr_{.h6) enyns d Constants usd in Glculatioos: Temperature of auxiliary fuel (T.r) = Density of auxiliary Fuel at 77 "F (p", = Heat lnput of auxiliary fuel (-Ah.r) = Density of waste gas at 77'F (fut) = Mean Heat Capacity of Air (Cp..t) Reference Temperature (T.a) = (For thermal oxidizers) 77.O'F o.o4o8 lblft3 21,502 Btu/lb 0.0739 tblft' 0.255 Btu/lb'F Sum of volume fraction ofcombustible components = Lower Explosive Limit ofwaste gas (LEL-ix) = (:xr) = = II(x;)/(Ix,) x LE!))l{ = Where xj is the volume fraction and LEl, the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl-!) x 100 = = (LEL." x 0.2as)/(:xJ = = (Total Adjusted Conc. With Dilution AirltEl*n) x 100 = (From Data Entry Tab) = = 100 - (:x, x 100/106) F = [(1.17 x 104) x Q*rx AP]/E - Q*i= (From Data Entry Tab) = Heat Recovery x (Tfl - T-J + T-r= = T', - 0.95(Trt - T-,) = = : (-Ah.J xr Where {-Ah.J is the heat of combustion and )q the fraction of component "i" at 77 'F (Calculated using Equation 2.45 in Appendix B) = 5% x Total Energy InpFt = 0.05 x ft, x Q.i x Cemri x (Tr, - Trd) = (Note: lf the % tEr-" Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) o*" Operating temperature of oxidizer (T1) Temperature of waste gas at outlet to preheater (T*o) Temperature of flue gas exiting the regenerative oxidizer (Tf,) Heat lnput of waste gas (-Atr.*) Estimated Auxiliary Fuel Flow (Q., at 77 'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the .alculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufflcient.) Auxiliary fuel flow (qaf) at 77'F and 1 atm. = Total Volumetric Throughput (qoJ at 77 'F and 1 atm C.Dtdn coUGyf..br: = Q.i = Q*d+ q + qf = Q_r + Q"r= 0 ppmv 24898 ppmv 0.00 pcrccnt Not appli€ble Not Appli6bl€ 3,725 scfm 20.90 percent 13.8 kW 3,725 tclm 1,900'F 1,360'F 190 .F 0.0O Btu/scf 7.30 scfm 5,/rc5 Btu/min 5,235 8tu/min Ycs 7 sc'fm 3,732 scfm i (1+ i)"/(1+ i)^. 1 = Where n = Equipment Life and i= lnterest Rate Capital Recovery Factor (CRF) = lncinerator + auxiliary equipment'(A) = Equipment Costs (EC) for Regenerative Oxidirer lnstrumenbtionb = Sales taxes = FreiSht = FootEtar =(2.204 x 100,000 + 11.57 qtot) x (2022 CEPI/1999 CEPCI) = 0.10xA= 0.03xA= o-osxA= S492,6$ ln m22 dolhc 54q2t3 s1478s 524,s2 Tot l PuEh.$d Gquipmnt @str (B) = 5581,543 ln 2022 doll.B . - Aul[.ry tqulprunt lnchdcs cqulpm]lt (G.g,, duct srl) lmty ru loddcd ulth unit fun{+.d ty lndlmtor w.dq. b - lrcludcr th. lnstrumoi.tbn .rd @ntrclr furnbhcd by thc trlmntor cndq. Dlr.cilmtdkhhil co.tr(h 20at dorml 0.08r8= 0.14x8= 0.04x8= 0.02x8= 0.01x8= 0.01x B = Foundations and Supports = HandlinS and Erection = Electrical = Piping = lnsulation for Ouctwork = Paintint = Site Preparation (SP) = Buildings (Bld8) = Iotrl Dircct CosB (t C) = Engineering = construction and field expenses = Contractor fees = start-up = Performance test = s66523 s81^16 523,262 5u,631 s5,8ls $s,tls 9o so 9r74,463 5756,006 ln 2022 doll.6 ss8,154 S29,on ssr,1s4 su,63l ss,81s s152,832 s91,884 Total DlEct lnst lhton costs = B+c+sP+Blir= Tot l hfu knlrlldoi Cats fln me2 dolhr.l 0.10xB= 0.05x8= 0.10x8= 0.02x8= 0.01x B = Tot l lndlnct Costs (lC), Annual Electricity Cost Annual fuel Co*sfor N.tural Gas OperatinS Labor Maintenance Costs = Annual Electricity Uldge x OperatinS Hours/year x Electricity Price = = costto.r x Fuel Usage Rate x 60 min/hr x OpeEting hours/year Operator = 0.5hours/shift x Labor Rate x (Operating hours/8 hours/shift) Superviior = 15% ofOpprator Labor = 0.5 hours/shift f Labor Rate x (Operating Hours/8 hours/shift) Materials = 100% of maint€nance labor s3,4s3 $37,r94 S9,375 $r,406 s9,37S S9,375 overhead Administrative Charges Property Taxes lnsuhnce Capital Recovery = 60pl of sum of operating, superuisor, maintenance labor and maintenance materials = 2% ol rcl = 1% of TCI = 1",4 ol fcl = CRFITCI-1.08(cat. Cost)l $t7,7t9 S2o,2t1 s10,107 310,107 $95,405 6!t Efi.ctlrms = ffotrl Annu.l Cort)/(lAnnol qrmity ot VOCi/HAP Pollubms D6trcyrd) Ahhual Cost {TACI =p.r ylrr in 2022 dolhrr Pollutants Oestroyed = 0,0 tffi/yctr Effectiveness = I 326,8!16,:169,615 D.r tm of Dolluttnts mmnd ln 2022 dolhB Nore:fte l*er.rpl6id lidn {tEt), hen d.ombustton.nd holecul.rweiahl forrome commnt usd Vtr/uP -. Eovd.d inrhar.U. hlil. ln:ddnion, rhe he.r ofcombrtrion ro h enrered in.ol!mn D b. ld.r hedinr{.1!€ (LHv), nd. hider he.ilq v.lu. lxHv). hlet @lumnkno*,.ie(q,J n 77or..d I am Motor/F.. tftcie..y (.1 lnlet Waile G6 T.mper.ture tr-,) op.rninsTemp.riturc (IJ DBrudlon .nd REmoval Efficienq {Oit ) tnihaed Equiph.il tile Eiim.r.d (.r.lEr lia. (y) spac. vdochyfo. ca.br lO) Pe...nl En.rd i6dery(sA, = dB.-, ! ctxl'tor2022 N,lural G.t roelC6l (c6!d) M.int.n.nc. t.bor r.le conlins.nry F.dorlcr) I .b.frrkbyh! s EMrdrntu rDddd Fdm s^*1.il$E 'qr//lrril,pt.fu',t/.^rBrhii/.r.-0.-s hhr) &lhb@hbdltrF.* P/hr@* @//ft .h.p/d.&/n4hvnr0:5urA h6. ffi@arkdl{dp,!Mrryr&d@h. '$7/III br F/d.udiv6-Dri6l. My r.B br.b '@r//ffi hh.F/arcurunv4'-dihrn) sud rrr k I ild dr!iltr 6ftndi .td du.d! {nF.n r.Ft R i.e2B,. !l.thanol foluena NI NI NI NI NI N/ NI N/ N/ N/ Constants used in 6lculations: Temperature of auxiliary fuel (Ta) = Density of auxiliary Fuel at 77'F (pa, = Heat lnput of auxiliary fuel (-Ah.d) = Density of waste gas at 77'F (p*J = Mean Heat Capacity of Air (Cem"r,) = Reference Temperature (T,d) = (For catalWic oxidizers) 77.O'F o.o4o8 tb/ft3 21,502 Biu/lb 0.0739 tb/fir 0.248 Btu/lb'F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEl-i*) Volumetric Flow Rate at 60 "F and 1 atm (Qft) catalyst Volume (Vol."J Estimated inlet temperature to the catalyst bed (T,i) = C.plt lR&ory.ryt clor: = (!x,) = = tI((x//((IxJ x LELi))] r = Where xi is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl*i,) x 100 = = {LEL.,, x 0.249)/(lx) = = (Total Adjusted Conc. With Dilution AirlLEhr.) x 100 = (From Data Entry Tab) = = 100 - (:xj x 100/106) = = [(1.17 x 10 4) x CLi x AP]/E (From Data Entry Tab) = Heat Recovery x (T.i - T.J + T.i= =Tri-T*o+T*r= = I (-Ah.r) xi Where (-Ah"i) is the heat of combustion and 4 the fraction of component "i" at 77 'F (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy lnput = 0.05 x pri x O{, x Cr6r x (Tri - T,+) = (Note: lf the : qo, x (s19)/(77'F + 450) = = On/O (calculated usinE Equation 2.28 in Chapter 2 of the cost Manual) 0 ppmv 24,898 ppmv % LEL,L Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power consumption (FP) a*. operating temperature of oxidizer (TrJ Temperature of waste gas at outlet to preheater (Two) Temperature of flue gas exiting the oxidizer (Tro) Heat lnput of waste gas (-Ah*J Estimated Auxiliary Fuel Flow (qd) at 77'F and 1 atm, Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy I nput, then the auxilary fuel is sufficient.) Auxiliary fuel flow (Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (qd) at 77 "F and 1 atm = Q.r = Q*o + CL + qr = Q{i+ qi= c.lcuLdon dc.t Fvot nr. ild !rt*t:'ld fGmr.itEr of w.rr. G6 Ert rtU&. GrdDn B.d 0.00 pcrccnt Not applicablc Not Applic6ble 3,725 sc{m 20.90 prrcent 16.7 kW 3,725 sclm 900 'F 5@'F 340.F 0.00 Btu/*f 25.35 scfm 22,235 Btulmin 2,908 Btu/min Yc5 25 scfm 3,750 scfm 3,625 scfm 7.25 ft! 900 'F i (1+ i)Y(1+ i)" - 1 = Where n = EouiDment Life and i= lnterest Rate Capital Recovery Factor (CRF) = Futur. Wortli Flctor (FWF) =I p,/(1+ r)' -'q = Whcrc y = Cstrlvct Life rnd i= lntrrrit RatG lncinerator + .uxiliary equipment' (A) = Equipment Costs (EC) for a Fired 8ed Catalytic Oxidizer lnstrumentation6 = Sales taxes = FreiSht = = (1,443 x qtot^(o.ss27)) x (2022 cEPl/1.999 cEPcl) = 0.10xA= O.03xA= 0.05xA= $2E9,555 ln 2022 dollars 52E,96? SE 690 s14,4E3 $341,to5 in m22 dolhETot l Purch.sd equipmnt osts (B) = F@tmt t . - Auxlli.ry lqulpmnt lrrcludcr equFreot (ctr., duci m*) rcmlly not lncludcd wlth unlt furnlslld by lrclrcntor vcido., b - lncludss thc lonrumnt tbn .nd @nt o& furnlsh.d by the inclneBtq Endor. Foundations and Supports = Handling and Erection = Eledricl = Piping = lnsulatioh for Ductwork = PaintinS = Site Preparation (SP) = Buildinss (8lds) = Tot l Dlcst Co* (DC) = EngineerinS = Construction and field expenses = Contractor fees = Start-up = Performance test = Continenry Cost (C ) = Dlrtd lBtJht*n co{il3 0n 2022 doLBl 0.08x8= 0.14x8= 0.04x8= 0.02x8= 0.01x B = 0.01x B = Total Dlnct lNtalhton costs = 8+C+SP+Blda= TotC lndrct ln i.Ltbn c6it (h 2llzt &llfrl OIOxB= 0.05xB= 0.10x8= 0.02x8= 0.01x B = Total lndlnct Co*s (lC) = 527,344 547,8s3 $13,672 56,836 53r18 s3r18 so so 5to2,s2 $444,347 tn2ozzdol|Fs S34,rt1 51Zo9o s3,r,181 s6,835 s3,41r s9s,70s s54,oo5 Catalyst Replacement cost Annual Eledricity Cost Annual Fuel Costs for Natural Gas OperatinS Labor Maintenance Costs = 1.08 x CC x Vol..r x FWF Where CC is the S/ft1 colt for th€ replacement catalys! Votr is the volume of catalyst required based on the waste tas flow Ete (Qft) and the catalyst rpace 51'146 velocity (O); and FWF is the future worth factor. = Annual Electricity Usage x Operating Hours/year x Electricity Price = = Costtod x Fuel Usate Rate x 50 min/hr x OperatinS hours/year operator = 0.5hours/shift x Labor Rate x (operating hours/8 hours/shift) Superuisor = 15% ofOperator Labor = 0.5 hourr/shift x Labor Rate x (Operating Hours/8 hours/shift) Materials = 100% of mailtenance labor 34,1to s129,110 se,37s S1/406 99,37s s9,37s Overhead Admihistrative Charges Property Taxes lnsurance Capital Recovery = 50% of sum of oFrating, superuisor, maintenance labor and maintenance materials = 2% of fcl = 1% of TCI = 1% ofTcl = CRFlTCl1.08(cat. Cost)l Sl7,719 S11,t81 55,94r ste41 sss,9s6 Quentlty of VOC/HAP Polldrnts D$troy.d) pcr y!.r ln 2022 dollsrs ton of pollut.nts rrmoEd in 2022 doll.tr 11d Noie: Se lry.r spbton limn (tEI), hea d.omb6non.nd 6ole.ul.r wdghr for3ome commonlv u.ed Voc/HAP .r. p.ovid.d jn the rable bld rn ddron, $e 6..r ol combciion to h ..rered h colunn 0 k. l*er hedi.gv.lu.(LHV), nd.hrd.rh..iingv.l!e(BHV) l:l !rnldlolumetkflow.fe(qJ al 77'Frnd I am. Moro./f.n Efiicienry(€) lnld w6teGaLmpernure (T-J oFrrinB T.mperdure trn) D6vodion and iem@.| tfii.idry (DRt) ttiihil.dtquipm€m Lde Etrimd.d.araltFr lde ly) sp... v€lody lor cd.lFt ( O) s Ndur.l Ga r!.1 c6l {c6iu) Mainten.n.. L.br rn. CoiliB.nq r.dor (crl P.r.md.B lor common conpoudt 6 .6qx.aurryrlffi ffi.b@irbld'dE.* a/h.@e rE//ffi .h.p/dnrv/ir'hidn30!su3^.hh ffinimaDkM'r6p.rAe '&JhsduM@. rBr/lw bi.p/€*!min ! n.ihhr eiv i.t! ,or oDsld! Constants used in clculations: Temperature of auxiliary fuel (Tar) = Density of auxiliary Fuel at 77 'F (pil) = Heat lnput of auxiliary fuel (-Ah..r) = Density of waste gas at77 'F lpwtl = Mean Heat Capacity of Air (Ce-.n) = Reference Temperature (T,a) = (For catalytic oxidizers) 77.0 "l 0.0408 tblft3 21,502 Btu/lb 0.0739 tbriJ 0.248 Btu/lb'F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas {LEl-") = (Ixt) = = t:((xj)/((:xJ x LELj))l 1 = Where xi is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl-,) x 100 = = (LEL.1 x 0.249)/(lx,) = = (Total Adjusted Conc. With Dilution Air/LEl*;) x 100 = (From Data Entry Tab) = = 1oo - (Ixj x 100/106) = = (1.17 x 1O!) x Q*rx API/€ = Q*r= (From Data Entry Tab) = Heat Recovery x (Tri - Twi) + T.i= =T1,-T*o+T*,= = : (-ahc,) xi Where (-Ah.J is the heat of combustion and 4 the fraction of component "i" at 77 "F. (Calculated using Equatlon 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy Input = 0.05 x F\i x Qri x Ce.ri x (Tri - T-, = (Note: lf the = O.or x (519)/(77'F + 460) = Where Or is the volum€tric flow rate of the waste gas (qJ corrected to 60 'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) 0 ppmv 24898 ppmv %LEL^" Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air Inlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power consumption (FP) a_" Operating temperature of oxidizer (TrJ Temperature of waste gas at outlet to preheater (Two) Temperature of flue gas exiting the oxidizer (Tr.) Heat lnput of waste gas (-AtLwi) Estimated Auxiliary Fuel Flow (Qd) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufflcient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) Auxiliary fuel flow {Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (Q"J at 77 'F and 1 atm = Q{r = Q*o + Q€ + 46, = Q*t+ CL= Cakuhdon of G.t lFt Vohrme lld Etdtnrt d Tsmp.r.tuE of W.sb C.s Eot dr8 tlE CtGhrn Bed Volumetric Flow Rate at 60 "F and 1 atm (Oft) Gtalyst Volume {Volc.r) Estimated inlet temperature to the catalyst bed (T,r) = Crph.l Ra@rrary Frctor: 0.00 pcrccnt Not applieble Not Applicable 3,725 scfm 20.90 perccnt 15.7 kW 3,725 scfm 900 .F 6@'F 340 'F 0.00 Btu/scf 25.35 sqfm 22,235 Btulmin 2,908 Btu/min YGs 25 scfm 3,750 scfm 3,525 scfm 7.25 ft3 900 .F Capital Recovery Factor (CRF) =i (1+ i)"/(1+ i)" - 1 = fstm Worth leb. Where n =Life and i= lnterest Rate Where y = Cetalyst Life and i= lntcrcst Rate lncinerator + auxiliary equipment' (A) = EquipmentCosts (EC) fora Monlith CablyticOxldi2er lnstrumentatiohb = Freight = Foundations and Supports = HandlinS and Eredion = Electrical = Piping = lnsulation for Ductwork = Painting = Siie Preparation (SP) = Buildings (Bldg) = Tot lDlcctCo5ts(DC)= Engineering = construdion and field expenses = Contnctor fees = Start-up = Performance test = fotal Pu.ch.s.d Gquiprcnt @rts (B) = Tot l DiEct lNtalhton Costs = B+C+SP+8ldg. Iot l ln lft.t lnrtlldon c6tr (ln 2022 &lhrl 0.10x8= 0.05x8= 0.10x8= 0.02x8= 0-O1x B = Tot l lndlrcct Costs (lC) - 0.10xA= 5289,655 ln 2022 dolLE 52t,967 sr,590 s14r&' S34Uo5 ln 2022 dolLr3 0.O3xA= 0.05xA= F@inotcs . - Audlhry .qulpmnt lnclud!! .qulpmnt (..i., duct rc*) mlly rct h.hdtd wtti unft fumblrGd by imlnGntor wndor. b - lrcludcs th. lrstrumnt tlor .nd @ntrols furnkh.d by th. ircircEtof Endd. DlGr hn{4bn Co.tt 0n 2022 &LBl 0.08x8= 0.14r8= 0.04x8= 0.02x8= 0.01x I = 0-O1x B = 927,3a4 s47,as3 S11572 S5,r36 s3118 93,4lE 90 so sto2,s2 5444,347 ln2o22dolhrs $4,r81 s1Z09O s34,rEl $5,r38 53,418 ses,Tos Catalyst Replacement Cost Annual Electricity Cost Annual Fuel Costs for Natural Gas Operating Labor Maintenance Costs = 1.08 r Cc r Volar x FWF Where CC is the 5/ft3 cost for the replacement catalyst; VoL"t is the volume of catalyst required based on the waste 8as flow rate (Qn) and the catalyst space velocity (O); and FWF iCthe future worth fador. = Annual Electricity UsaSe x OpeEting Hours/year x Electricity Price = = Costtud x Fuel UsaSe Rate x 60 min/hr x Operating hours^ear Operator = O.Shours/shlft x Labor Rate r (Operating hours/8 hours/shift) Supervisor = 15% ofOparator l-abor = 0.5 hours/shift x Labor Rate x (Operating Hours/8 hourrshift) Materials = 10O% of meinlenance labor Sl,146 s4.180 s129,110 99,37s 91,405 99,375 S9,37s overhead Administrative Charges Property Taxes lnsurahce Capital Recovery = 5096 of sum of operatihg, superyisor, maintenance labo. and maintenance materials = 2% ol rCl = L% ol 7Cl = 1% of rCl = CRFlTcl-l.08(cat. costll s17,7t9 $11,t81 ss,941 ss,s41 s5s,958 @st EffcctlEm$ = flotrlAnnual Cost)/(Annul qulmty ot VOqHAP Pollut nts D€trcrEd) Annual Cost [tAC) = 5251,406 prr y.!r ln 2022 dolLrs Pollutants Destroyed = 0.0 tm/y.fi Effcctiveness = S31r25.601,e8 lcr ton of Dollut nts Em[d ln 2022 doll.R Noter Tn. l*e,dol66 lmnl!Et), hen d.omb6lio..nd mol.c!la.eei.hitortomecommonly ui.d VG/MP ,e prdr&d m rne r.bl. bl@. h addinon, rhe hen of combGtion to b. e.te..d 'n.olumn D 6. ld.r h..i4v.lue{tffvl, nd. hiaher healrngv.lue {HHV). Number ol oErrinE houE/y€.r rnldvolumerkflo* [.E(A-J.l 77!F and I am. Moto./F.n Efi i.i.n.y (E) rn ld w*€ ca lemp.r.rur. lT-J oFrrinslemperdure (iJ Derrudion and nemd.l tfli.bnry (oiE) Errim{.d Equtpmed Lile E{imil.d caEhFt lile Iy) sp..e velocty ro. c.iahEl I o) Natur.l G.i rlel c6r (c6!d) M:I.t...n.e L.bor rd. Continxe.q r.dor lcr) E pdEdnt{**+rk.*tu Meffibfrfk ,u.6dkbvtu u.s.Erud i6.h ollfr d p/dd/dhnvnr0r5u!1a.hh Ecu'Frru:ry@ ffiHdrEIsrdns.'M re/h-.&/,@. @,/ww.bk.p/ar.un.re! i!r.hh) tudy,rb!boFe! 1s/s*.bB.p/n+u'r.v43_n.r hhl eiy r.bi b, Constants used in cl€ulations: Temperature of auxiliary fuel {T.) = Density of auxiliary Fuel at 77'F (par) = Heat lnput of auxiliary fuel (-Ah."r) = Density of waste gas al77 'F lp*,1 = Mean Heat Capacity of Air (Cr."|,) = Reference Temperature (Td) = (For catalytic oxidizers) 77.O "F 0.0408 tbff 21,502 Btu/lb 0.0739 lbft3 0,248 Btu/lb "F NI NI NI NI NI NI NI NI N/ Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEL-,") = (:xr) = = [((x,)/((Ix) x re!))] 1 = Where xr is the volume fraction and LElr the lower explosive limit for each combustible component in the waste gas. = {Total Combustible Conc. ln Mixture/LEl*i,) x 100 = = (LEL.,, x 0.249)/(!x,) = = (Total Adjusted Conc. With Dilution AirlLEl-i,) x 100 = (From Data Entry Tab) = = 100 - (:x,, 1oo/101 = = {{1.17 x 104) x Q*ix API/€ (From Data Entry Tab) = Heat Recovery x (Tri - T* ) + T.i= =T,-T +T = = : {-ah.,) xi Where (-Ah.i) is the heat of combustion and \ the fraction of component "i" at 77 't (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) =5%xTotal Energylnput=0,05 xp,,x q,xCo.,,x (Tq-T,") = (Note: lf the = O{., x (s1s)/(77 'F + 450) = Where Ofi is the volumetric flow rate of the waste gas (q) corrected to 60'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) % LEL^i Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) o*. Operating temperature of oxidize. (Ti,) Temperature of waste gas at outlet to preheater (T*.) Temperature of flue gas exiting the oxidizer (Tr.) Heat lnput of waste gas (-Att*,) Estimated Auxiliary Fuel Flow (Q., at 77 'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) Auxiliaryfuelflow(Qaf) at77"Fand 1 atm. = Total Volumetric Throughput (q"t) at 77 'F and 1 atm.= O{ = O*o+ Os + Q.r = Q*i+ qr= Cakul.don of Catatyst Volume and Esdmated Tempenturc of W6t Ga3 Entarlng the Crtalyst Bed Volumetric Flow Rate at 60'F and 1 atm (Ofr) catalyst Volume (Vol."r) Estimated inlet temperature to the catalyst bed (T,r) = Captal nccat €ry Factor: 0 ppmv 24.898 Domv 0,00 percent Not applicable Not Applicable 3,725 scfm 20.90 percent 16.7 kW 3,725 scfm 900 'F 560 'F 340'F 0.00 Btu/scf 25.35 scfm 22,235 Btu/min 2,908 Btu/min yes 25 scfm 3,750 scfm 3,625 scfm 7.25 ft. 900 'F Capital Recovery Faclor (CRF) =i (1+ i)^/(1+ i)" - 1 = Where n = Equipment Life and i= lnterest Rate futur€ Worth Factol lh2@2do0ml lncinerator + auriliary equipment' (A) = Equipment costs (Ec) for Fluid 8ed catalytic Oxidizer lnstrumentationb = Sale! taxes = Freight = Foundations and Supports = Handlihg and Erection = Electrical = PipinS = lnsulation for 0utuork = Paintihg = Site Preparation (SP) = BuildinBs (BldB) = Totel Dlul Costs (Dc) = EngineerinB = Construction and field expenses = ContEdor fees = Start-up = Pefformance test = = ((8.39 x 10,000) + (19.2 x Qtot)) x {2022 cEPl/1999 CEPCI) =5331,212 tn 2022 dolh6 $3,r21 s9,936 S15,s61 S390,&r0 in 2022 doll.6 0.10 x A= 0.03 x A= 0.05 x A. Tot l Purcha*d equiprent 6sts (B) = F@tmtr5 . - Aullhry rqulpmnt irchd$ aguipm.tt (e{., dwt s*} lEmlly not lnd}dcd utth unh furnlstrlGd by lnclnrntor vGndor. b - lncludcs th. lnst.umnt tlicn and @ntob fumlsh€d by thc hdmEtor Endor. Dlrcct lnrtd.qon Coilr (h m22 doLB) 0.08x8= 0.14x8= O.04xB= 0.02x8= 0.01x B = 0.01x B = Tot l OlEct lmt ll.ton C6ts = B+C+SP+Bldg= Tord tndlrcilntil.lbrhn c6it (ln 20ol dolh.d 0.10x8= 0.05x8= 0.10x8= 0.02x8= 0.01 xB= Tot l lndiEct Costs (lC) = 531,266 Ss4,71G s11633 57,817 53,9oE s3,908 50 so Su7,249 5508,079 ln 2022 dollars s39,083 S19,541 s39,083 $7,817 s3,908 S109,432 s61.7s1 Catalyst Replacement Cost Annual Eledricity Cost Annual Fuel Costs for Natural Gas Operating Labor Maintenahce Cosh = 1.08 x CC x Vol.d i FWF where cc is the S/ftt c6t for the replacement catalyst; Vol..t is the volume of catalyst requlred based on the w.ste gas flow rate (Ofr) ahd the catalyst space 51'146 velocity (O); and FWF is the future worth factor. = Annual Eleciricity Usage x Operating Hours/year x Electricity Price = = Costtod x Fuel Usage Rgte x 60 min/hr x Operating hours^ear Operator = 0.5hours/shift x Labor Rate x (Operating hours/E hours/shift) Superuisor = 15% ofOpqrator Labor = 0.5 hours/shift r Labor Rate x (OpeEtinS Hours/8 hours/shift) Materials = 10o% of malntenance labor s4,18O 9129,rr0 ss,37s s1/{06 s9,37s 59,37s Overhead Admihist.ative charSes Property Tares lnsurance CaDital Recovery = 50% ofsum ofoperating, supervisoL maintenance labor and maintenance materials = 2% ol rcl = 1% ofTCl = L% of Tcl = CRFITCI-1.08(cat. Cost)l s17,779 S13,srg s5,793 s6,7e3 s64,0ol Cost EfflctiEms . (Tot l Annu.l Co5t)/(i\nn[l qu.ntlty of VOC/HAP Pollutants DGstroy.d) otal Annual Cost (TAC) = 5272,857 pctycrrln2ozz 'OC/HAP Pollutants Destroyed = 0.0 tom/yar Effectiveness = 33:1.802.2)4.884 Er ton of Ellutlnts EmoEd in 2022 doll.B krktFddb l,@;;--l Nol.: Th. lN.. dpr6io. limn (LtL), h.a d comb6ton.nd molecularw.ixnr lorrom. commnlv lrd VG/UP.,e p,ovided in th. t.bl. blry. rn.ddllon, rh. he.r ofcombGtion to b..nt.r.d ln collmn Ok. lBe. h..ting v.lue (LHv), nd. hisher h.atingv.lue {HHV). l,@ 'F. 9er<..t En.re RE@erylHR) =3lnld volum.td.nos r.relorJ.r 77or.nd 1 dm Motor/f.n Eftci.ncy {.) hld wste c- Iemp.ra!.e (iNJ oF rin8 Iemper.ture lT,J Defudion and nrhd.l Efficr.nq lDia) Eriimil.d Equipment Lfe N.lu,.l G6 Fu6l c6r (c6qd) M.inl.n.ncetabr r.t. Contna.nq F.dor(cF) .r64bhtuus EErrhrr r@4 kfr !^{1d 61s, ls. //lw .r. p/.tddv/.nMl^nf.rr_o2_M h60 fn.er'ousErykffi ffiE4ertd6(r.t& @/&d@ffi. //fr.bh p/don.V*_M.hhr 1@ r.6 tu ry.6 d d.i b rrd .d tF.n +'.M d, (sis, 's//ft bB p/n/.uuv-!-rlh6l kny rE! b, \rethanol [oluene ( ( ( ( ( ( ( ( N' N' N' N' N' N' N' NI N' N' ( Constants used in calculations: Temperature of auxiliary fuel (T"r) = Density of auxiliary Fuel at 77'F {p"r) = Heat lnput of auxiliary fuel (-Ah."r) = Density of waste gas at 77 'F (p*,) = Mean Heat Capacity of Air {C,-",.) Reference Temperature (Tfd) = (For thermal oxidizers) 77.O'F o.o4o8 tblft3 21,502 Btu/lb 0.0739 lb,/ft3 0.255 Btu/lb'F sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEl-,,) Auxiliaryfuelflow(Qaf) at77'Fand 1atm. = Total Volumetric Throughput (q"r) at 77 'F and 1 atm C.pltel Recot €ry Faclor % LEL.,, Oilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(qwi) at 77'F and 1 atm. Oxygen Cohtent of gas stream Fan Power Consumption (FP) o*. OperatinS temperature of oxidizer (T1 ) Temperature of waste gas at outlet to preheater (T*.) Temperature of flue gas exiting the oxidizer (Tr") Heat lnput of waste gas (-Alt*,) Estimated Auxiliary Fuel Flow (Q"r) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total EnerSy lnput, then the auxilary fuel is sufficient.) = (:xL) : = t:((xr)/((:x,) x LEL,))l 1 = Where xj is the volume fraction and LEq the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl-,,) x 100 = = (LEL.,, x 0.249)/(lx) = = (TotalAdjusted Conc. With Dilution AirllEl-*) x 100 = (From Data Entry Tab) = = 1oo - (:xt x 100/106) = = (1.17 x 104) x O+,x API/€ " Q*i= (From Data Entry Tab) = Heat Recovery x (Tri - T"J + T* -- =Tri-Two+Tw,= = : (_ah.,) x Where (-Ah.J is the heat of combustion and x, the fraction of component "i" at 77'F (Calculated using Equation 2.21 in Chapter 2 of the cost Manual) =5%xTotal Energylnput=0.05 xp,,x Q,x Co.,,x (T1,-T,") = (Note: lf the 0 ppmv 24,898 Domv 0.00 percent Not applicable Not Applicable 3,725 sclm 20.90 percent 13.8 kW 3,725 scfm 1,500 'F 1,150'F 550 'F 0.00 Btu/scf 49.17 scfm 43,136 Btu/min 5,257 Btu/min Yes 49 scfm 3,774 scln= O{, = Oryo + q + qr = Q{i + qr= i (1+ i)"/{1+ i)" - 1 = Where n = Equipment Life and i= lnterest Rate Capital Recovery Fador (CRF) = lncinerator + auxiliary equipment' (A) = Equipment cosb (EC) for Recuperative Thermal oxidizer lnstrumentationb = Sales taxes = Freight = Foundations and Supports = Handling and Eredion = Eledrical= Piping = lnsulation for ouctwork = Paihting = Site Preparation (sP) = Buildihgs (Bldg) = Totel Dlrcct Oosts (DC) = Engineedng = Construction and field exp€nses = ContEdor fees = start-up = Performance test = DlGr tarc.rldil codr tln 2022 dolm, 0.08x8= 0.14xB= 0.04x8= 0.02x8= 0.01x B = 0.01r B = Tot l DiEst lnst lhton CEts. B+C+SPfBHt= Totd lndrrt ht[Ldoo Cctt(ln 2022 dollml 0.10x8= 0.05x8= 0.10x8= 0.02x8= 0.01x B = fot llndlEctco6t (lC)= x (2022 cEPl/1999 cEPcl) =5355,371 in 2022 dolhtr s3ts37 s10,651 st7,769 S4r9,337 rn 2022 dhE 0.10!A= 0.03xA= 0.0SxA= Tot l Pu.ch.ed Gquipmnt @rt! (B) = F@tEtas . - Au$.ry cqulpmnt Indud6 rqulpGnt (c\t., dsct rcrl) umlly rot lncMed ulth unh fumliH by kEkEator Erdor. b - lrcludca th. hnrumnt tjon end @ntob furnlsh.d by thc hElmntor Edd. s33,s{7 ss8,707 S16,773 s8,387 s4,193 S4,193 so 5o s12s,E{'1 S545,139 tn 2022 dolhrs 94r,934 5m,96t s41,934 St 3t7 54,193 su7,414 s66,2ssCF(lC+DC)= Annual Eledricity Cost Annual Fuel Costs for Natural Gas Operatin8 Labor Maintenance CosB = Annual Eledricity usl8e x operatinS Hours/yearu Eledricity Price = = Costtod x Fuel Usa8e Rate x 60 min/hr x opehtinS hours/year Operator = O.Shours/silift x Labor Rate x (Operatin8 hours/8 hours^hift) Supervisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (operating Hour5/8 hours/shift) Materials = 100% of maihtenance l.bor s3,4s3 s2fiA7t s9,37s 31,106 s9,37S 39.375 Overhead Administrative Charges Property Taxei lnsurance CapitalRecowry = 60% of sum of operating, supeilisor, maintenance labor and maintenance meterials = 2',4 ol fcl = 1% ofTCl = 1% ofTCl = CRF x TCI $17,779 514,s76 97,2rr 97,288 966,794 Coit EfrGcthcms . (Totrl Annul Co3t)/Annul Qurntlty of VOC./HAP Pollut.mr Dctrcycd) Total Annual Cost (TAC) =par ylar ln Pollutants Oestroyed =0.0 tms^Frr Effectiveness.ton of Emrd ln 2022 dolhE Form 4 Company Northrop Grumman Systems Corp. Project lnformation Site ASBU Clearfield Utah Division of Air Quality New Source Review Section AIR OUALITY 'lf the permit being modified gloes no!include COee or PMz.s, the emissions need to be calculated and submitted to DAQ, which may result in an emissions increase and a public comment period. ""lf additional space is required, please generate a document to accommodate and attach to form. Process Data - For Modification/Amendment ONLY 1.Pef m it N U m bef DAoE-AN1o 152oo2a-22 lf submitting a new permit, then use Form 3 Reqqested Changes 2. Name of process to be modified/added: Oven End product of this process: Cured aerospace part components 3. Permit Change Type: New lncrease* Equipment Z trProcess tr X Condition Change Add Oven Other Other Other 4. Does new emission unit affect existing permitted process limits? vesn ro E 5. Condition(s) Changing: Add an additional oven with external exhaust as permitted equipment 6. Description of PermiVProcess Change** An oven will be constructed to support operations. Sealants applied to aerospace parts will cure and the off-gassing products from this process will be exhausted to the atmosphere. 7. New or modified materials and quantities used in process. " Material Quantity Annually BR 57-2 7.00 8. New or modified process emitting units * Emiftino Unit(s)Capacitv(s)Manufacture Date(s) Oven 100.00 Page 1 of 1 Utah Division of Air Quality New Source Review Section Form 2 Process lnformation Company Northrop Grumman Systems Corp. Site/Source ASBU Clearfield Date 11129122 Process Data 1. Name of process: Oven Exhaust 2. End oroduct of this orocess:' Cured aerospace component 3. Primary process equipment: Oven Exhaust Make or model: Capacity of equipment (lbs/hr): Manufacturer: ldentification #: Year installed: Rated Max. (Add additionalsheets as needed) 4. Method of exhaust ventilation: tr Stack tr Window fan n Roof vent E Other, describe WallVent Are there multiple exhausts: tr Yes E No Operating Data 5. Maximum operating schedule: hrs/day 7 days/week 50 weeks/year 6. Percent annual production by quarter: Winter 25o/o Spring 25o/o Summer 25% Fall 25o/o 7. Hourly production rates (lbs.): Average Maximum 8. Maximum annual production (indicate units): 7 gallons Projected percent annual increase in production: Oo/o 9. Type of operation: o Continuousn Batch x lntermittent 10. lf batch, indicate minutes per cycle Minutes between cycles 11. Materials used in process Raw Materials Principal Use Amounts (Soecitu Units) B57-2 Adhesive 7 gallons Page 1 of 3 Process Form 2 (Continued) 12. Control eouipment (attach additional paqes if necessary) Item Primarv Collector Secondary Collector a. Tvoe b. Manufacturer c. Model d. Year installed e. Serialor lD# f. Pollutantcontrolled g. Controlled pollutant emission rate (if known) h. Pressure drop across control device i. Desiqn efficiencv j. Operatingefficiency Stack Data (attach additional pages if necessary) 13. Stack identification:14. Height:Above roof Above ground ft ft 15. Are other sources vented to this stack: trYes ts No lf yes, identify sources: 16. tr Round, top inside diameter dimension tr Rectangular, top inside dimensions length _ x width 17. Exit gas: Temperature 435 oF Volume 100 s61p Velocity - fUmin 18. Continuous monitoring equipment: tr yes tr no lf yes, indicate: Type Manufacturer Make or Model Pollutant(s) monitored Emissions Calculations (PTE) 19. Calculated emissions for this device PMlo o Lbs/hr 0 Tons/yr Tons/yr PMz.s Lbs/hr Lbs/hr Tons/yr Tons/yr Tons/yr No. o Lbs/hr-9 SO, CO Lbs/hr 0 1 voc CH+ 0.414 Lbs/hr 0.01Tons/yr Co, 0 Tons/yr Tons/yr Tons/yr NzO Xylene 0.145 lb/hr 0.145 tons/yr HAPs 0.189 Lb s/hr (speciate) 0.005 Tons/yr (speciate)Methylbenzene 0.0214 lb/hr 0.044 tons/yr Submit calculations as an appendix. lf other pollutants are emitted, include the emissions in the appendix. Page 2 of 3 r/oc 19.voc 19.88 0.010 0.414 (ylene 5.8 Xylene 5.98 0.003 0.14C Methylbenzene 2.I Methylbenzene 2.09 0.00r 0.044 AIIHAP 9.AIIHAP 9.O7 0.00s 0.189 OrgE= E > >d O o:: f f d0 E!EE:. E9 €.98,8t99.:oE=:ooo 3sEF z ii.E EEEdzo >tr rr uo;i 5-::> es€--:oe'Euu f do Xoo E <>;>>o E o I e sl-t BI -t 6t 3l E z. a I OVEN SAFEry DATA SHEETS $ ro..ro, 12258 26s3 CYTsT2PADH SAFETY DATA SHEET SDS: 0007175 Date Prepared: 11 12312017 1. IDENTIFICATION Product Name: Product Description: Synonyms: ChemicalFamily: Molecular Formula: Molecular Weight: I ntended/Recommended Use: BR@ 57-2 Paste Adhesive Mixture of polyamide resin and filler None Polymide Mixture Mixture Engineered material adhesive CYTEC INDUSTRIES INC., 504 CARNEGIE CENTER, PRINCETON, NEW JERSEY 08540, USA For Product and all Non-Emergency lnformation call 1-800/652-6013. Outside the USA and Canada call 1-973/357- 3193. EMERGENCY PHONE (24 hours/day) - For emergency only involving spill, leak, fire, exposure or accident call: Asia Pacific: Australia - +61 2 8014 4558 (Carechem24) China (PRC) - +gO 0532 83889090 (NRCC) +86 512 8090 3042 (Carechem24) New Guinea - +61 2 8014 4558 (Carechem24) New Zealand - +64 9 929 1483 (Carechem24) lndia, Japan, Korea, Malaysia, Thailand - +65 3158 1074 (Carechem24 Singapore) lndia (Hindi Speaking Only) - +65 3158 1 198 or 000800 1OO 7479 (Carechem24 Singapore) Canada: 800 424 9300 (Within US,Canada) +1 (703) 527-3887 (lnternational) (CHEMTREC) Europe/Africa/Middle East (Carechem24 UK) : Europe, Middle East, Africa, lsrael- +441235 239 670 (Arabic speaking countries) - +44 1235 239 671 Latin America: Brazil - +55 11 3197 5891 (Carechem24) Chile - +5622582 9336 (Carechem24) All Others - +44 1235 239 670 (Carechem24 UK) USA: 800 424 9300 (Within US,Canada) +1 (703) 527-3887 (lnternational) (CHEMTREC) The @ indicates a Registered Trademark in the United States and the rM indicates a trademark in the United States. The mark may also be registered, subject of an application for registration, or a trademark in other countries. 2. HAARDS IDENTIFICATION GHS Classification Flammable Liquid Hazard Category 3 Germ Cell Mutagenicity Hazard Category 2 Reproductive Toxicant Category 1A Acute Toxicity (Oral) Hazard Category 4 Specific Target Organ Toxicity - Repeated Exposure Hazard Category 2 Specific Target Organ Toxicity - Single Exposure Hazad Category 3 Skin Corrosion / lrritation Hazard Category 2 Serious Eye Damage / Eye lrritation Hazard Category 1 Skin Sensitizer Hazard Category 1B Aspiration Hazard Category 1 Aquatic Environment Acute Hazard Category 2 Aquatic Environment Chronic Hazard Category 2 LABEL ELEMENTS DIVISION OF AIR OIJALITY BR@ 57-2 Paste Adhesive SDS: 0007175 Date Prepared: 11 12312017 Page 2 of 13 SignalWord Danger Hazard Statements Flammable liquid and vapor Suspected of causing genetic defects May damage fertility or the unborn child Harmful if swallowed May cause damage to organs through prolonged or repeated exposure May cause respiratory irritation Causes skin irritation Causes serious eye damage May cause an allergic skin reaction May be fatal if swallowed and enters airways Toxic to aquatic life with long lasting effects Precautionary Statements Keep away from heaUsparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Obtain special instructions before use. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Do not breathe d usUfu me/gas/misUvapou rs/spray. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. lF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. ln case of fire: Use CO2, dry chemical, or foam for extinction. lF exposed or concerned: Get medical advice/attention. Rinse mouth. lF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see supplemental first aid instructions on this label). Take off all contaminated clothing and wash it before reuse. lF lN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. lf skin irritation or rash occurs: Get medical advice/attention. lF SWALLOWED: lmmediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Store in a well-ventilated place. Keep cool. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local and national regulations. Hazards Not Otherwise Classified (HNOC), Other Hazards Polymerization may occur from excessive heat, contamination or exposure to direct sunlight. BR@ 57-2 Paste Adhesive SDS: 0007175 Date Prepared: 1112312017 Page 3 of 13 3. GOMPOSITION/INFORMATION ON INGREDIENTS Substance, Mixture or Article? Mixture .HAZARDOUS INGREDIENTS The specific chemical identity and/or exact percentage of composition for one or more ingredients has been withheld as a trade secret. Additional GHS classification or other information may be included in this section but has not been adopted by OSHA. See Section 16 for full text of H phrases. 4. FIRST AID MEASURES DESCRIPTION OF FIRST AID MEASURES Eye Contact: Rinse immediately with plenty of water for at least 15 minutes. Obtain medical advice if there are persistent symptoms. ]omoonent/ CAS No.oa GHS Classification Carclnooen )olyimide resin 30 40 Eye Dam. 1 (H318) tl-Methylpyrrolidone )72-504 10-15 Repr. 1B (H360D) sToT sE 3 (H335) Skin lrrit. 2 (H315) Eye lrrit. 2A (H319) n-Phenylenediamine 10845-2 1-10 Muta.2 (H341) Acute Tox. 3 (H301) Acute Tox. 3 (H31 1) Acute Tox. 3 (H331) Eye lrrit. 2A (H319) Skin Sens. 1B (H317) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) (ylene 1330-20-7 1-10 Flam. Liq. 3 (H226) Acute Tox. 4 (H312) Acute Tox. 4 (H332) sToT RE 2 (H373) STOT Sinsle 3 (H335) Skin lrrit.2 (H315) Eye lrrit. 2A (H319) Asp. Tox.1 (H304) ;lass, oxide, chemicals 15997-17-3 1-10 Not Classified =thylbenzene10041-4 1-3 Flam. Liq. 2 (H225) Acute Tox. 4 (H332) sToT RE 2 (H373) Skin lrrit. 3 (H316) Eye lrrit. 28 (H320) Asp. Tox. 1 (H304) Aquatic Acute 2 (H401) BR@ 57-2 Paste Adhesive SDS: 0007175 Date Prepared: 11123120'17 Page 4 of 13 Skin Contact: Remove contaminated clothing and shoes without delay. Wash immediately with plenty of water. Do not reuse contaminated clothing without laundering. Get medical attention if pain or irritation persists after washing or if signs and symptoms of overexposure appear. lngestion: lf swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. lnhalation: Remove to fresh air. lf breathing is difficult, give oxygen. Apply artificial respiration if patient is not breathing. Obtain medical attention immediately. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED None known INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDS Not applicable 5. FIRE.FIGHTING MEASURES Suitable Extinguishing Media: Use water spray, alcohol foam, carbon dioxide or dry chemical to extinguish fires. Water stream may be ineffective. Extinguishing Media to Avoid: fullwater jet Protective Equipment: Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing. See MSDS Section 8 (Exposure Controls/Personal Protection). SpecialHazards: Keep containers cool by spraying with water if exposed to fire. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Where exposure level is not known, wear approved, positive pressure, self-contained respirator. Where exposure level is known, wear approved respirator suitable for level of exposure. ln addition to the protective clothing/equipment in Section 8 (Exposure Controls/Personal Protection), wear impermeable boots. Methods For Cleaning Up: Remove sources of ignition. Cover spills with some inert absorbent material; sweep up and place in a waste disposal container. Flush spill area with water. References to other sections: See Sections 8 and 13 for additional information. 7. HANDLING AND STORAGE HANDLING BR@ 57-2 Paste Adhesive SDS: 0007'175 DatePrepared: 1112312017 Page 5 of 13 7. HANDLING AND STORAGE Precautions: Avoid release to the environment. Keep away from heat, sparks and open flame. - No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting and other equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/clothing and eye/face protection. Do not breathe vapors or spray mist. Special Handling Statements: Containers must be bonded and grounded when pouring or transferring material. STORAGE Areas containing this material should have fire safe practices and electrical equipment in accordance with applicable regulations and/or guidelines. Standards are primarily based on the material's flashpoint, but may also take into account properties such as miscibility with water or toxicity. All local and national regulations should be followed. ln the Americas, National Fire Protection Association (NFPA) 30: Flammable and Combustible Liquids Code, is a widely used standard. NFPA 30 establishes storage conditions for the following classes of materials: Class I Flammable Liquids, Flashpoint <37.8 "C. Class ll Combustible Liquids, 37.8'C < Flashpoint <60'C. Class llla Combustible Liquids, 60'C < Flashpoint < 93'C. Class lllb Combustible Liquids, Flashpoint > 93'C. Storage Temperature: Store at -18 "C 0 "F Reason: Quality. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure. Respiratory Protection : Where exposures are below the established exposure limit, no respiratory protection is required. Where exposures exceed the established exposure limit, use respiratory protection recommended for the material and level of exposure. A full facepiece respirator also provides eye and face protection. Cutting, grinding or sanding of parts fabricated after curing may create respirable dust particles. Respiratory protection appropriate for this dust may be required. Refer to components listed above for potential hazardous components in the dust. Eye Protection: Wear eye/face protection such as chemical splash proof goggles or face shield. Eyewash equipment and safety shower should be provided in areas of potential exposure. Skin Protection: Avoid skin contact. Wear impermeable gloves and suitable protective clothing. Barrier creams may be used in conjunction with the gloves to provide additional skin protection. Hand Protection: Wear impermeable gloves. Consider the porosity and elasticity data of the glove manufacturer and the specific conditions in the work place. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Additional Advice: Food, beverages, and tobacco products should not be carried, stored, or consumed where thrs material is in use. Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water. lt is recommended that a shower be taken after completion of workshift especially if significant contact has occurred. Work clothing should then be laundered prior to reuse. Street clothing should be stored separately from work clothing and protective equipment. Work clothing and shoes should not be taken home. Exposure Limit(s) BR@ 57-2 Paste Adhesive SDS:0007175 Date Prepared: 11123120'17 Page 6 of 13 The below constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 100414 Ethylbenzene osHA (PEL): ACGIH (TLV): Other Value: 10845-2 m-Phenylenediamine osHA (PEL): ACG|H (TLV): Other Value: 1330-20-7 Xylene osHA (PEL): ACG|H (TLV): Other Value: 100 ppm (TWA) 435 mg/m3 (TWA) 20 ppm (TWA) Not established Not established 0.1 mg/m3 (TWA) Not established 100 ppm (TWA) 435 mg/m3 (TWA) 150 ppm (STEL) 100 ppm (TWA) Not established Not established 1 f/cc respirable fibers (TWA) 5 mg/m3 inhalable fraction (TWA) Not established 65997-17-3 glass,oxide,chemicals osHA (PEL): ACG|H (TLV): Other Value: 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Appearance: Odor: Boiling Point: Melting Point: Vapor Pressure: Specific Gravity/Density: Vapor Density: Percent Volatile (% by wt.): pH: Saturation ln Air (% By Vol.): Evaporation Rate: Solubility ln Water: Volatile Organ ic Gontent: Flash Point: Flammability (solid, gas): Flammable Limits (% By Vo!): Autoig nition (Self) Tem peratu re: Decomposition Temperatu re: Partition coefficient (n- octanol/water): Odor Threshold: Viscosity (Kinematic): DUST HAZARD I NFORMATION Particle Size (microns): Kst (bar-m/sec): Maximum Explosion Pressure (Pmax): Dust Class: Minimum lgnition Energy (MlE) (mJ): Tan paste solvent Not applicable Not applicable Not available 1.2 Not applicable 28- 32 Not applicable Not applicable Not applicable negligible 2.85 lbs/gal 46 "C 115'F Not available Not available Not available Not available Not available Not available Not applicable Closed Cup Not applicable Not applicable Not applicable Not applicable Not applicable BRO 57-2 Paste Adhesive SDS: 0007175 DatePrepared: 1112312017 Page 7 of 13 Minimum lgnition Temperature (MlT) ("C): Not applicable Minimum Explosive Concentration (MEC) (g/m3): Not applicable Limiting Oxygen Concentration (LOC) (%): Not applicable 10. STABILITY AND REACTIVITY Reactivity: No information available Stability: Stable Conditions To Avoid: Keep away from heat, spark and flame. Polymerization: May occur Conditions To Avoid: Avoid contact with acids, oxidizing agents, free radical initiators, bases or amines. Do not heat above 93.3 C (200 F). Materials To Avoid: Strong oxidizing agents and alkalies. Hazardous Decomposition oxides of carbon Products: Oxides of nitrogen ammonra 1 1. TOXIGOLOGIGAL INFORMATION PRODUCT TOXICITY INFORMATION Likely Routes of Exposure: Oral, Eyes, Skin. ACUTE TOXICITY DATA oral (gavage; rat Acute LD50 -1000 mg/kg dermal rabbit Acute LD50 >2000 mg/kg inhalation rat Acute LC50 4 hr -5 mg/l (DusVMist) LOCAL EFFECTS ON SKIN AND EYE Acute lrritation skin lrritating Acute lrritation eye Causes serious damage ALLERGIC SENSITIZATIONSensitization skin Sensitizing Sensitization respiratory No data GENOTOXICITY Assays for Gene Mutations Ames Salmonella Assay No data OTHER INFORMATION The product toxicity information above has been estimated. HAZARDOUS INGREDIENT TOXICITY DATA Polyimide resin has an oral rat LD50 of >4,000 mg/kg and a dermal rabbit LD50 > 5000 mg/kg. Direct contact may cause mild skin irritation. Polyimide resin caused severe eye irritation in animaltests. However, exposures to polyimide resin have not been reported to cause adverse health outcomes in occupational settings. BR@ 57-2 Paste Adhesive SDS: 0007175 Date Prepared: 1112312017 Page 8 of 13 N-Methylpyrrolidone has acute oral (rat) and dermal (rabbit) LD50 values of 3914 mg/kg and 8000 mg/kg, respectively. ln a subchronic inhalation study, rats were exposed to concentrations of 0, 0.1, 0.5, and 1.0 mg/L for 6hr/day for 5 days/week for 4 weeks. At 0.1 and 0.5 mg/kg exposure levels, no clinical signs or pathological lesions were observed. However, at the 1.0 mg/kg exposure level, lethargy, respiratory difficulty, and excessive mortality were found. Examinations determined that the rats had focal pneumonia, bone marrow hypoplasia, and atrophy of the lymphoid tissue in the spleen and thymus. ln a chronic inhalation study, rats were exposed to concentrations of 0, 0.04 and 0.4 mg/L for 6hr/day for 5 days/weeks for two years. Male rats at 0.4 mg/L showed slightly reduced body weight. No other adverse toxicological or carcinogenic effects were observed. ln a teratology study conducted in rats, N-methylpyrrolidone caused a significant decrease in viable offspring, a decrease in mean fetal body weight and an increased incidence of skeletal abnormalities following dermal application of 750 mg/kg during gestation. At this dose level, bright colored urine and decreased body weight gain were considered to be evidence of maternaltoxicity. ln an inhalation teratology study, N- Methylpyrrolidone was not fetotoxic or teratogenic in rats exposed to vapors up to 0.36 mg/L during gestation. Direct contact with this material caused redness, cracking and blistering of the skin in humans with prolonged or repeated exposure. Direct contact with the eye can produce moderate to severe irritation. lnhalation of vapors can cause irritation of the nose and throat. m-Phenylenediamine has reported acute oral (rat) and acute dermal (rabbit) LD50 values of 650 mg/kg and 1500 mg/kg, respectively. The acute inhalation (rat) LC50 reported for a 4-hour exposure to m-phenylenediamine is 3.2 mg/L. This material is a slight skin irritant, a moderate eye irritant, and a skin sensitizer in tests with laboratory animals. Repeated exposures to low oral doses caused allergic reaction in animals. Repeated ingestion of higher doses caused slight kidney damage and liver degeneration. Long term exposure to m-phenylenediamine has been reported to cause chronic conjunctivitis and inflammation of the respiratory tract. m-Phenylenediamine was not carcinogenic in rats or mice when administered via oral and dermal routes of exposure for periods of 90 days and 2 years, respectively. Teratogenic studies conducted in mice and rats have shown this material to be weakly teratogenic at maternally toxic doses only. m- Phenylenediamine was reported to be mutagenic in the Ames test and active in chromosomal aberration and cell transformation tests. lt does not produce genetic damage in animals. o-Xylene has estimated acute oral LD50 (rat) of 3523 - >5000 mg/kg, estimated acute dermal LD50 (rabbit) value of >1000 - 2000 mg/kg, and an estimate acute 4-hour LC50 (rat-vapor) of >10-20 mg/l lnhalation of vapors may be irritating to the nose, throat and respiratory tract. lnhalation of high concentrations may result in nausea, vomiting, headache, ringing in the ears, and severe breathing difficulties, which may be delayed in onset. This substance is considered an aspiration hazard and may be fatal if swallowed and then enters airways. Direct contact with this material may produce moderate skin and eye irritation. Exposure to vapors will cause eye irritation. This material is not expected to be a dermal sensitizer. This substance is not expected to cause damage to health via repeated oral or inhalation exposure. This substance was not mutagenic in the Ames Assay. O-Xylene is not expected to be carcinogenic, based on animal testing with structurally similar materials. Glass oxide is considered a nuisance particulate which will not cause adverse health effects other than respiratory congestion or irritation. Ethylbenzene has acute oral (rat)and acute dermal (rabbit) LD50 values of 3500 mg/kg and 15.4 g/kg, respectively. The acute 4-hr inhalation (vapor) LC50 is 17.8 mg/L. This substance is considered an aspiration hazard and may be fatal if swallowed and then enters airways. Direct contact with this material is expected to be mildly irritating to skin and eyes. A Repeated lnsult Patch Test with human volunteers did not demonstrate dermal sensitization properties. Ethylbenzene was not mutagenic, genotoxic or clastogenic in a battery of in vitro and in vivo assays. Repeated or prolonged inhalation exposure to ethylbenzene has led to increase inner ear damage. Slight developmental toxicity was observed in animals in the presence of maternal toxicity following inhalation exposure. Carcinogenicity studies in both rats and mice did not provided adequate evidence/relevance of cancer in humans. California Proposition 65 Warning (applicable in California only) - This product contains (a) chemical(s) known to the State of California to cause cancer and birth defects or other reproductive harm. 12. ECOLOGICAL INFORMATION BR@ 57-2 Paste Adhesive SDS: 0007175 Date Prepared: 1'1123120'17 Page I of 13 1 2. EGOLOGICAL INFORMATION TOXICITY, PERSISTENCE AND DEGRADABILITY, BIOACCUMULATIVE POTENTIAL, MOBILITY IN SOIL, OTHER ADVERSE EFFECTS Overall Environmenta! Toxicity: Toxic to aquatic life. Toxic to aquatic life with long lasting effects. The ecological assessment for this material is based on an evaluation of its components. RESULTS OF PBT AND vPvB ASSESSMENT Not determined HAZARDOUS INGRED!ENT TOXICITY DATA ]omoonent / GAS No.Toxicitv to Aloae Toxicitv to Fish Toxicitv to Water Flea )olyimide resin Not available Not available Not available {-Methylpyrrolidone )72-50-4 EC50 > 500 mg/L - )esmodesmus subspicatus (72h CSQ = 1072 mg/L - Pimephales promelas (96h) static LC50 = 1400 mg/L - Poecilia reticulata (96h) static LC50 = 832 mgil - Lepomis macrochirus (96h) static EC50 = 4897 mg/L - Daphnia magna (48h) n-Phenylenediamine t08-45-2 EC50 = 2.4 mglL - Pseudokirchneriella subcapitata (96h) LC50 = 1600 mg/L - Pimephales promelas (96h) EC50 = 5.9 mg/L - Daphnia magna (48h) (ylene r 330-20-7 EC50 = 11 mg/L - Pseudokirchneriella subcapitata (72h) LC50 '13.1 - 16.5 mg/L - Lepomis macrochirus (96h) flow- through LC50 13.5 - 17 3 mg/L - Oncorhynchus mykiss (96h) LC50 2.661 - 4.093 mg/L - Oncorhynchus mykiss (96h) static LC50 23.53 -29.97 mglL- Pimephales promelas (96h) static LC50 30.26 - 40.75 mgil - Poecilia reticulata (96h) static LCSO 7.711 - 9.591 mg/L - Lepomis macrochirus (96h) static LC50 = 13.4 mglL- Pimephales promelas (96h) fl ow{hrough LC50 = '19 mg/L - Lepomis macrochirus (96h) LC50 = 780 mg/L - Cyprinus carpio (96h) semi-static LC50 > 780 mg/L - Cyprinus caroio (96h) LC50=06mg/L-Gammarus lacustris (48h) EC50 = 3.82 mg/L - water flea (48h) )omoonent / CAS l{o.Toxicltv to Aloae Toxlcltv to Flsh Toricity to Water Flea ;lass, oxide, chemicals t5997-1 7-3 Not available Not available Not available =thylbenzene100-41-4 ErC50 = 3.6 mg/L (measured) - Green Algae (96h) NOEC = 3.4 mg/L (measured) - Green Algae (96h) LC50 = 4.2mglL (measured) - Rainbow Trout (96h) semi-static EC50 = 1.8 mg/L (measured) - Daphnia magna (48h) lC50 (reproductionl = 3.3 mg/L measured) - Ceriodaphnia dubie (21 dav], semi-static BR@ 57-2 Paste Adhesive SDS: 0007't75 Date Prepared: 1112312017 Page 10 of 13 1 3. DISPOSAL CONSIDERATIONS The information on RCRA waste classification and disposal methodology provided below applies only to the product, as supplied. lf the material has been altered or contaminated, or it has exceeded its recommended shelf life, the guidance may be inapplicable. Hazardous waste classification under federal regulations (40 CFR Part 261 et seq) is dependent upon whether a material is a RCRA "listed hazardous waste" or has any of the four RCRA "hazardous waste characteristics." Refer to 40 CFR Part261.33 to determine if a given material to be disposed of is a RCRA "listed hazardous waste"; information contained in Section 15 of this MSDS is not intended to indicate if the product is a "listed hazardous waste." RCRA Hazardous Waste Characteristics: There are four characteristics defined in 40 CFR Section 261.21-61.24: lgnitability, Corrosivity, Reactivity, and Toxicity. To determine lgnitability, see Section 9of this MSDS (flash point). For Corrosivity, see Sections 9 and 14 (pH and DOT corrosivity). For Reactivity, see Section 10 (incompatible materials). For Toxicity, see Section 3 (composition). Federal regulations are subject to change. State and local requirements, which may differ from or be more stringent than the federal regulations, may also apply to the classification of the material if it is to be disposed. The Company encourages the recycle, recovery and reuse of materials, where permitted, as an alternate to disposal as a waste. The Company recommends that organic materials classified as RCRA hazardous wastes be disposed of by thermal treatment or incineration at EPA approved facilities. The Company has provided the foregoing for information only; the person generating the waste is responsible for determining the waste classification and disposal method. 14. TRANSPORT INFORMATION This section provides basic shipping classification information. Refer to appropriate transportation regulations for specific requirements. US DOT Dangerous Goods? X Proper Shipping Name: Adhesives Hazard Class: 3 Packing Group: lll UN/ID Number: UN1133 Transport Label Required: Flammable Liquid Marine Pollutant Marine Pollutant TechnicalName(N.O.S.): phenylenediamine Component / CAS No. Hazardous Substances / Reportable Quantity of Product (lbs) Xylene 1123.129 BR(D 57-2 Paste Adhesive SDS: 0007't75 Date Prepared: 1112312017 Page 11 of13 Comments: Flammable liquids with a flash point at or above 38" C (100" F) and not meeting the definition of any other hazard class may be reclassed as a Combustible liquid except for transport by vessel or aircraft. lf reclassed, these Combustible liquids are not regulated in non-bulk packagings. Marine Pollutants - DOT requirements specific to Marine Pollutants do not apply to non-bulk packagings transported by motor vehicles, rail cars or aircraft. Hazardous Substances/Reportable Quantities - DOT requirements specific to Hazardous Substances only apply if the quantity in one package equals or exceeds the product reportable quantity. TRANSPORT CANADA Dangerous Goods? X Proper Shipping Name: Adhesives Hazard Class:3 Packing Group: lll UN Number: UN1133 Transport Label Required: Flammable Liquid Marine Pollutant Marine Pollutant TechnicalName(N.O.S.): phenylenediamine ICAO / IATA Dangerous Goods? X Proper Shipping Name: Adhesives Hazard Class:3 Packing Group: lll UN Number: UN1133 Transport Label Required: Flammable Liquid Marine Pollutant TechnicalName(N.O.S.): phenylenediamine Comments: Marine Pollutants-IATA Special Provision A197 when transported in single or combination packagings containing a net quantity per single or inner packaging of 5L or less for liquids or 5 kg for solids, are not subject to any provisions of these regulations. Note if the material also meets the criteria under additional hazard classes then all requirements continue to apply for those hazards. tMo Dangerous Goods? X Proper Shipping Name: Adhesives Hazard Class:3 UN Number: UN1133 Packing Group: lll Transport Label Required: Flammable Liquid Marine Pollutant Marine Pollutant TechnicalName(N.O.S.): phenylenediamine Comments: Marine Pollutants -IMDG 2.10.2.7 when packaged in single or combination packagings, containing a net quantity per single or inner packaging of 5L or less for liquids or 5 kg for solids are not subject to any other provisions of this code. Note if the material also meets the criteria under additional hazard classes then all requirements continue to apply for those hazards. 1 5. REGULATORY INFORMATION BR@ 57-2 Paste Adhesive SDS: 0007175 Date Prepared: 1112312017 Page 12 of 13 1 5. REGULATORY INFORMATION lnventory lnformation United States (USA): All components of this product are included on the TSCA Chemical lnventory or are not required to be listed on the TSCA Chemical lnventory. Canada: All components of this product are included on the Domestic Substances List (DSL) or are not required to be listed on the DSL. Australia: One or more components of this product have NOT yet been included in the Australian lnventory of Chemical Substances (AICS) or assessed by NICNAS. China: One or more components of this product are NOT included on the Chinese (IECSC) inventory. Japan: One or more components of this product are NOT included on the Japanese (ENCS) inventory. Korea: One or more components of this product are NOT included on the Korean (ECL) inventory. Philippines: One or more components of this product are NOT included on the Philippine (PICCS) inventory. Taiwan: One or more components of this product are NOT included on the Taiwan Chemical Substance lnventory (rcsr). OTHER ENVIRONMENTAL INFORMATION The following components of this product may be subject to reporting requirements pursuant to Section 313 of CERCLA (40 CFR 372), Section 12(b) of TSCA, or may be subject to release reporting requirements (40 CFR 307, 40 CFR 311, etc.) See Section 13 for information on waste classification and waste disposal of this product. Component / CAS No. % TPQ (lbs) RQ(lbs) 5313 TSCA l2B Ethylbenzene 1 - 3 None 1000 Yes No 10041-4 m-Phenylenediamine 1 - 10 None Yes No 108-45-2 Xylene 1330-20-7 N-Methylpyrrolidone 872-50-4 PRODUCT HAZARD CLASSIFICATION UNDER SECTION 311 OF SARA. Acute. Chronic. Fire 16. OTHER INFORMATION NFPA Hazard Rating (National Fire Protection Association) Health: 3 - Materials that, under emergency conditions, can cause serious or permanent injury. Fire:2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. lnstability: 0 - Materials that in themselves are normally stable, even under fire exposure conditions. 1 -10 None 100 Yes No 10 - 15 None Yes No BR@ 57-2 Paste Adhesive SDS: 0007175 Date Prepared: 1'1123120'17 Reasons For lssue: Revised Section 2 Revised Section 3 Revised Section 16 Revised Section 15 Date Prepared: 1112312017 Date of last significant revision: 1112312017 Component Hazard Phrases Polyimide resin H318 - Causes serious eye damage. N-Methylpyrrolidone H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H360D - May damage the unborn child. m-Phenylenediamine H301 - Toxic if swallowed. H31'1 - Toxic in contact with skin. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H331 - Toxic if inhaled. H341 - Suspected of causing genetic defects. H400 - Very toxic to aquatic life. H410 - Very toxic to aquatic life with long lasting effects. Xylene H226 - Flammable liquid and vapor. H304 - May be fatal if swallowed and enters airways. H312 - Harmful in contact with skin. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H335 - May cause respiratory irritation. H373 - May cause damage to organs through prolonged or repeated exposure. Ethylbenzene H225 - Highly flammable liquid and vapor. H304 - May be fatal if swallowed and enters airways. H316 - Causes mild skin irritation. H320 - Causes eye irritation. H332 - Harmful if inhaled. H373 - May cause damage to organs through prolonged or repeated exposure. H401 - Toxic to aquatic life. Page 13 of '13 Prepared By: Legal & Compliance Services; E-mail: custinfo@solvay.com This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. lt is offered solely for your consideration, investigation, and verification. Before using any product, read its label. OVEN BACTANALYSIS Best Available Control Technology Analysis Northrop Grumman Systems Corp. Clearfield, Utah Process: Oven Emission Unit: 100 SCM Fan Pollutant: VOC / HAP Potentialto Emit Summarv (Criteria pollutants and HAP) Pollutant voc HAP PTE (tons/vr) 0.010 0.00s A copy of the entire PTE calculations for this source is attached (see DAQ VOC Calcs spreadsheet). A traditionaltop-down Best Available ControlTechnology (BACT) analysis consists of 5 steps as detailed below. . Step 1 - ldentify all control technologies . Step 2 - Eliminate technically infeasible options . Step 3 - Rank remaining control technologies by control effectiveness . Step 4 - Perform impacts analysis . Step 5 - Select BACT Control Technoloqies Control technologies for VOC include variations of carbon adsorbers; refrigerated condensers; flares; and incinerators and oxidizers. Eliminate Technicallv lnfeasible Options Refrigerated condensers are used for treating emission streams with high VOC concentration (>5,000 ppm) (EPA Air Pollution Control Cost Manual, section 3, chapter 2.1). Control Effectiveness Rankinq 1. lncinerators and Oxidizers 99% Removal Efficiency 2. Carbon Adsorbers 98% Removal Efficiency lmpacts Analvsis Multiple types of equipment were evaluated for VOC removal for each control technology. The impact analysis is attached (see various Oven spreadsheets). Gost Effectivenese voc Carbon Adsorber $167,532 130.787 $10.841 .342.212 $6,761 ,745,911 lncinerators and Oxidizers Fluid Bed Oxidizer $8,436,637,160 ThermalOxidizer $8,386,439,856 Multiple types of equipment were evaluated for HAP removal for each control technology. The impact analysis is attached (see various Oven spreadsheets). Cost Effectiveness $360.920Carbon Adsorber $281,758 $27.615.007 $17,223.534 17.223.534 $21.489.787 $21,361,927 BACT Selection Northrop Grumman Systems Corp. proposes the installation of an air pollution control device for this process is not cost effective. The processes and VOC and HAP emissions which occur during this process are regulated under Utah Administratlve Code Rule R307-355, Aerospace Manufacture and Rework Facilities. Northrop Grumman Systems Corp. has documented procedures in place which require all containers to remain closed except during use and define responses to any spills which may occur. Northrop Grumman Systems Corp. proposes compliance Utah Administrative Code Rule 307- 355, including VOC and HAP controls and work practices, as BACT. 761,745,911 RTO Fixed Bed Carbon RTO Fixed Bed Catalytic Oxidizer Monolith Catalvtic Oxidizer Fluid Bed Catalvtic Oxidizer OVEN BACT CALCULATIONS-VOC * { IdI .vf *[dFa&u\fii #F oco aot a Eo f, o ooo o I E a E I c 6o o ! E ! Eoo @ c, , , I j q \{! fj Gtrc eo cccccq Io @@o qo F € o 6 o qo B o d e =,Et o E D .9 .9 E @ o @I : q 3o 2 E 6 E o EoI E6o 6 o o5x o f o doo E E 9 2 E o E e o o o E ) o E 0 Eoo Io ooo@o u_l oq ,{ ffj @N ci ff cccc€q xt t ooo Nts.i ! E !, l i o oo E o o @ 2 E o o; : o , tr o E 6 E o EoJ E Ge 65 @ ci f f j ocg ooco c o Eoot 6 oooo E t a E D E !9 o E o E t E E !E E c t E o o E t: 6N o o d oo ci .9 E noo i q z @o @N @No 6 a@ o6 : - a ao Et N oo F ui N ui 6 6 di o T E ! o do 3 n ?- oo F€o d: .9 o6 E r af{Ia o j N @ o o oo o o) @@N o o-r o ci q;o q c @6 oo c; o @o o 4 @ 1 a?-o o@ 6o d 6 q F c or 6 6 ci .9 oE E o o t oo E E 6 Ep 3 t o C .9 Ep o = o d o 6 E d oo @ I E I o 3 coo ,s 3 c E =: ,E a Et 6ll slioto Eli ;113t! o E I o o o E o Eoa eia T;x o oo ci (F a c c E cq x Eo @ FooNc c En 'l, 3 oc oe .9 ts d .E o ot o .E E .q Ed E o : cc 3 E E 6 E o coU Eoo o I sIE slEeto 8lE EIE El+'alz o E o o c t =t t E E , E6o !{i a I noo e 6 N N @ oo c, ( F c cc Qooo o6 d @o €ooo d o I 3 d oo = c E t o o 6 og o o E z o oc ': 'o @ E E o C C Ena! nu E E c, o o =oooo ci o E t E o Eoo G ! Ei n F @Fo ts 8Ia iato I 6 ci qq 6 oE aaE o 3: @ d oo G c E n 6 c,! E E c : oo 3 -9 2 E 6 E dcog ECo o o o I oai 3E ttr\Z g$ h(, $E :$ *il Cure Recipe 1 erature ('F)Ramp Rate (ymin)Ramp Time (min)Dwell'Iime (min) rnt - 10O 3(1! 100 135 0.!7t 1! 135 160 0.83.3:1: 150 260 0.:2U 1! 160 350 3(9( Cure Recipe 2 etr rerature ('F)Ramp Rate (7minl Ramp Iime (min))wellTime (minl ent- 350 4.6',5(9( ts0 450 tlA zt 12( Li ! fmfolanttodclhronn I S.ld tu typc d orbn .er syn.m: ktudH afi6 ffia pl!&tu*6t hffih: *bd $€ tyF of oFatbn: kld thtyp. d m.tdl.lud tof.kbt.th. orbn.6dbrv6$bl S.ld th odlnt.tlon for th:dstu sssB: c.Mcosb kler qs onilfi rs6tFr f D;*'*" l i1*"':1i f f*tl E Numb d@d.tiq hdR Fydrl€J w.3r.6.sn0 R.r. (o) vtr Ehissld Rd! (&) Rqurd VOC rcmov.l dld.@ (E) Eiih.td.quired ltr ofaunl.ry Eqdpn.nt (n) NumkolOFctlry Hours Bdo.. Orbn C.nkterR.pl.em.nt F^) &,.O hourr/Y..' 0.lrl lbs/hour lO Ye.r3 6 houB 98 percenr i . def.un .ontrol di. en ry user ehould ent€r adual val ue, il roow. roy€rE B addauh quiFeni life. Urer3hould enteradual v.lue, ifknown 3@ lB or..rhn F..an6rer E ad€,.ut valu€. Urer should enter prde,ed canttei tDe, il krown P.dirl Pr.$uro of Xyl.n./NMP... In w.st. tri *rom P.nmdrr'1" fd XyhrcAMP-. P!r.m.t.r "m" for xvln./NMP... GPCI'for 2022 Annu.l lnErc*R.t.lll Ureofolherwellknown cort index6 1e.8,, M&5) ts acceptable. Noi.|TYpic.lco*sfolcalbo...nhteB.r.showninTable8 lf knowh,st...ny.ddltlon.lcostkrit.pr.Frtion.ndbuildiq Sil. PnFr.tlon (sP) = EulldlnF Fbd = Eqolpm.ntC6Bfor.urlll.rylqulr.d{..g.,dutuil,OmtsB,.dsd) (EqJ = co.tlnr.nryF.dor (cF) DdautValue.U.e.enolUenler.dualvaroe,ilroown Ddaun value. U5e, shouldenler adoal varue, ifknown r0F(ent 6 a de,.uhvalue The.onlingencvf.cto.should &Hwen s and 15 F.cenl ft. followtna d.nan p.nm.t.B for th. arbn .d$rEr *.n okuh.d hd on th v.lDs.hteEd on th.&6 rrrya t.b. ft.s v.lu.s were usd to pr.Fn th..o43.hom o. ih coti Enimo& rb tyr.dffik *iffi.lAo6.r6od+D*ailil xfmdwM tl,.dilP.- q0m& Qu.ndw of xvl!i./ilMP... R.hoEd lwvoc) : a lbr. 2 4,3@ hour. Os lb. vocJlb. o6on Oe b. voc/lb. otun 15 lbi. 3,O@ lbi 0ra4 Idh: M R qld 2.@re3255t imrF.r w*=n*xe,xE- E*lm.tdqtunConsumptbn(M.)tor.nlnEmrcnityoFr.t.drystlm= {eJwJrOr = Numb.roftim.scaniste(r..placcdp.rFir: e,/ e^= ffir?ffikokatu Tim ftrM$rydon (eJ : tumbt olop.td@hou! b,o? cil*n eat*t rcpla.Nnt = Equlllbdum c.p.ciw d th. l.let {w nN, : t t P^ = wor[q qtsciy l*.) : 0.S r wx-r = Edmtulodetur R.qutod(M.): (DJw.) xo^ = Numb.r of C.rbon caniitlE R4uld = M./qtun Csl*d OP.cty IelAu.nttry of Q6on Rcquid ror I C.nlsUrs: Numb.r d C.tun onloE ' C.6on Gp.clty p.r C.nh!r: G.drlbW@ Ir, (1 + rl^l / I(1 + 0".11 = c.pblR&wry F.dorforaurlll.ry.qulpm.nt (cFR.ur): whlE n = Equlpmflt Ltr..6d I = lnEhn Rd! c.phlR*oEryFdorforca6on(cRr.rde)= tlx{1+i)"!/t(1+if'tl=.- ..wh.F ^ = orbon C.nh.r Lft lnd I llnErd R& Ettlmt.d otibl d lor . C.rbqt C.nlfd ld.o.t r witfi C.nitu R.pbamd wtdr tta tolldha clEnda.l.tac* VOc Conroll.d/hcd...d = xyl.n./ilMP... AddbcrVsd Ori.nbtion = trotApplic.bl. Op.Etina Schcdul. : lnt.rhin.nt Op€r.tion Tdl C.pi6l lncftht Fql (h 202 dolLr) Panffi6 Total cost forAll Carbon Adsorber Canist€rs (Ecad-b) = Auxiliary Equipment (8c.,.) = Tot.l turdEs€d Equipmenl osts for C.ftoo Adsodrr (A) = treight = lmlhtilm (d (ln m22 do[.tr| Paaffi lnstallation = site Preparation {SP}. Buildinss lBlds) = Continaency co{ {c) : Equtlon Canister Cost x Number of Canistere Required = (Based on desigo costs or estimated using methods provided in Section 2) C6t S43,s5 92,m S4s,s6 0.05xA= EqEtion 0.20x8" s4,587 S1,376 $7'293 Tot.l turch.s.d Equlrmcnt CosB (B) = S49,535 cct S9,907 So So Tot.l O..d.nd lndired lnst.ll.tion CGts = 59,S7 cF(Purchase €qlipment Cort + lnrtallation co!B): S5,9e Dl6hnElG! hnmtG Maintenance Costs: Carbon Canist€r Replacement csts EqEtbn O06rTCl lnstallation Cost = 0.2 x Number of Canisters x Cost per €anister x Number of tihes reotaced/vear = 5i,a73 Canisterr " number of c.nisters r cosl per canister x 1.08 x Number of times Cd s3,923 Ss,513 lndl6 Amu.l Cd. hEffi Adminidrative Charget EqBt106 . 2% of lcl = 1% of ICl = 1% ofTcl = CRFAuxiliary Equipment x {Tcl-1.o8(canistercosts)} = C6t S1,34 s5s 55s4 s2.5il C6t ElLdlYffG hnmtd lTotal Annual cort = lAnnuar Ouairiry of voc Removed = cosi Efiactiv€n€ss = C6t $123,s9 pe. y..rin 2022 dolhE o.74 tons paryaaa 5157,532 p.rtmotpollubnt.r.movedin dollars Equtlon TAC = w-,'n"",xo"xE= Total Annual Cost (TAC) / Annual Quantitv ofVOc Removed/Recovered = Sdd thG typ. d arbn.d.#r ryn.6 I sdd theqF otoFation: sddth.typ.dil.tdi.ludtot.&i6i.th.c.rbn.diorhrv.$.lsi S.ldth.od.hEtionlorS..d3oft€.rsdr: Ii f lumbd d ry.tlryhouR ts.y€.r{e,l wast.Gar frd R.t. (cI vtr €massion R.t. (k) Rquid voc rcmov.l etri.i.nq (E) Enam.id.quipm.ntlif.of .derb.rvB3.h.nd.uxiliaryEqulpm.ntln) €*im.td otun Uf. (n) €stim.td C.rton R.el.@ment R.t. {CRR) t zS hourr^.rr 10 ecfm {at rtmo3oh.ric oressure and 7/t 0.172 lbr/hour ,9 lbr/hou.' m Ib ca.bon percanister 93per.enr tsad€fauhcontoletriciency ute,thouldenteractualvalue, ilknown 15 yea,s B adeldult equipmenl life. *er thould enter acilal v.lue, d known 179 rh/hoo, is. ddauh valle U3er rhould enrer.dua varue, ilknowf lm 16ol(ar&n Fr.antster 6 a d.raull v,lo€ User should enter prelered canister 5re, il known Pr^ial Pr8su.. ofxy!.ne/NMP... ln w.n.6.s *re.m P.r.md.r "k" lor Xylene/NMP... P.r.m.t!r "m" f or Xylen./NMP... Phcnolrddd j .l@hol d't, d.h, forrffi.6hmd CE?CI' lot 2022 Annull lnt.r.n R.t.li) Useotothe. well known.ort index* le.g., M&S) i5 ac.eptable. M.int.h.nc.t.bor R.t. lf k.own,.hls.ny.ddltion.lcostsforsit.p..p.r.tron.nd sit. Pr.Fr.tion {SP) = Buildlns (8Erl: Equipm.nr C6Bfor.urili.ry.quir..t (.!., dutuo*, d.mtsE,.nd n.d) {EqJ = contingenry F.dor(cF) Def:LI vr[p txn shoulde.rer..ru.] valup il known Delaun varue use.should ent€r a.rual vatue, il known D€lauh v.lu. Us€.should enter..tu.l value. il known 52748/hou.rsad€launvalue u5d3houldenrq ad!alvaiue, ilknown S{ 23/hour ls. der.lrt v.rue Usd 5hould€nte..duarv.lue, ilknown Itlhe,ale is not kno*n, use I 10r, 54zo/lbrsadefau[valu€basedon20lShirkeror'(e usershooldenier.dualvalue,ilknown l0Frcenr Ba deiauhvalue The.onrrng.n(yrr.torrhouldbe*rween 5and l5Brcenl Typical cods lor c.rbon cantsteG ar. thown in Table B. nbrLDtrrEftse sl9 ,nu.ry20lSmarkdpiicelo.vksincarbon oD.rator L.br Rat. lS/houd 527a8 ureauof L.brStatirti.s,MaV2OlTNationalO.cuFlion.ltmplovmeni.nd vige Estimar6 unh€d srars. M.y 20L7 ttps://ww.bb.gov/o6/curenVo6,nat.htm) Ho!dy rat6 ior oFrato^ b.ser l.i.t.^anc. bbor R.te (5/hou4 t?.o1ffiffi iftdWCilffi: c&bonffitAotu#*J -ra.r- Ir.r/xtP,- Qu.ntlty of xyl.n!AMP... R.6oEd (wrcc): v.slDlamd.r(D)= s!d@ &eadA&dsved {s}. Numb.r of tims...bt.(s) replaced pery..r= Mrhdlr.frlorOrhotu: TlmbrAderytlon (e^)" Equilibiom C.p.c[ry .t th! rnl€t (wd*r) : Workni c.p.clty (w.) : Edmd Tol c.rbon Rlqulrd (M.) = Numhr of c.tun qnkhE RqulEd: Tot.lQuiltliy d C.tron R.quid tor 1 Onl#6 = Ctblbsrymr capbl Rfrorcry f.tur fored$turv.s.l..nd.uflbry.quipmnt (tr8.btud= C.pibl R(ov.ry F.dorforca6on (CRF..&) = e,/er= tun&t ol opdinc houts b.tu.. cilf,on contiq Ede!,Mt = ktP^= M"/Ofron C.nH.r Cap.cty Numb.r ofC.don C.nieB'C.don C.p.di Fr canH.r: Ilx l1+ l)"1/t{r+0". 1l= Wh.rc n = Eqoipnst Llte.nd l=lnhlBt tut. tl x (1+ r)"1/l(1 +0^- 11 = Wh.E n = @bn Litu.^d i = lnt r.*8.e o.* ft. 4.18 ft. 15 q.fr z 4,3O hours O.9D lb.voc/lb.Otuo. O.@ lb.voqb.O6on E lbi. 3,m lbs. 0.lffi ossl E5dm.d aplEl d le a Carto.i clnLE Ad.ortat glth Carbqr R.pLffi whfi th. lbllGrtl clEneiLd6: VOC Cont.olhd/R6d.r.d = Xylen./IMP... Msorb.rV6rcl Ori.nt.ilon = vdlcC Op.r.lina Schcdul. = lnLhifi.ntog.r.tion Tdl6Dlhl |ffiil (TOl (in 2OZl dolbE) Panffid Total Cost for All Carbon Adsorber Canisters {ECAd-,b} = Auriliary Equipment (Ec.,,) = Tot.l Purch.srd Equiphcni 6rB fo. C..bon Adsdbc. (A) = F.eitht = lmlhtl,on Cd (lh ,O22 dolrul hnmtr Oirect and lndired lnrtallation = Site Preparation (sP) = Buildinss (BId8) = Contintency Co* (C) - Cqudoi Canister Cost x Number of canisters Rquired. (8ar€d on desirn costs or €stimated using methods provided in section 2) Cdt S43,s6 S2,m Sir5,856 0.03rA= s4s87 51,376 s2,293 Tot.l Purch.r.d Equipm.nt CorB (B) = 551,122 :$n Total Olr.d.nd tndi..d tnsblldio GB = 54,330 CF(Purchare Equipment Cost+ lnstall.tion.osts)= 55,S cd s4330 so So DlmdAmElAB h6lrr& Operrting bbor Cos$: Maantenence Costs: Carbon Replacement Costs: Equtlon Operator = 0.5 hours/shifr r Labor Rate x (Op€raling hours/8 hoors/shift) Supervisor = 15% ofoperator tabor = 0.5 hours/shift r Labor Rate x (Operating Hours/8 hours/shift) Mat€ri.ls = 10e/ of maintenance labor tabor . CrR..,&^ IL.bor Rate x TCICRRI : Carbon = CRF..,$^[CC x T. x 1.08] . c6t s1s,o45 52,257 s16,ss1 S16,ss1 Sr2o 57,526 Indd Arnu.l Cd tanmtd ov€rhead Administrative Charges Eqmron = 50% ofsum of operator, supervisor, maintenance labor Plus mainten.nce = 2% ofTcl = 1% ofTCl = 1% ofTcl = cRr&-,e, x lrcl-(1.08'cc'Tc) + (tR'Tc/cRR)l = C{t $30,242 S1,2s S643 s643 Ss,s3s €6t Elta.tlvm hnmEr lTotal Annual cost = lAnnual Quantity of voc R€moved . Coit Effediveness = cd SS,@ pcry!.rln2022dolhE O.ltr tons/F.r 580,787 pcr t6 of pollubnts rem@d in 2022 doll.rt EqEtbn W$..n$.xetxE= Total Annual Cost (TAc) /Annual Quantity ofVOC R€moved/R€covered = Note: The ld.r qplGion limn {LEL), h.n of.ombclion.nd molecularwelghl fo.rome commnly Gdv*/upr.prov'&drth.i.ble&ld ln.ddilion,theh..lof.ombutliontobeenlerad in.ol!mn 0 6 a ld.r h..liq v.lue ltHV), od. hide. h..rinav.l!. (HHv). 6.19 !.0 5.14 P.r.enr En.r& i€.d.rylHR). rnla volom.tir f,d.n.(qJ d 77!f .nd I dm Moto./tan Efl ici.ncy l.) lnl.r w.tr.Gn I.mp€.ature tr-J op..dins Temp.r.lur. (IrJ D6tudron :nd Femoval tficie.q (oRE) tirim.t.d tquiph.nr tile aaPct'lot 2022 Narur.l6.i Fu"lC6r (c6qd) M.int.n.nc.L.br rar. continr.n.v r.dorlcFl 6 lFdWdnfrtd!*! r.....*&&d.dfr'fuffi.-- ffibffikfr+* s//rw.L.p/d.N/s6vn3o35!.ahh Emmryr-u:!4rm-s ffiGqhbddF.'Affi &rh-@6. ndkqrd Ehrqril.( 1q' //ltl ! r F/a+uh^re!-Dth) eiy ..or b @.6 ]s3r/lw bR.p/ar.umnv*_^rthrml. snry rh b, tBdn (urF.d d*r.El.ezB) N-Methylpyrrolidone m-Phenylenediamine Xylene Ethylbenzene N/ N/ N/ N/ N/ N/ N/ N/ N/ N/ Constants used in (alculations: Temperature of auxiliary fuel (T,, = Density of auxiliary Fuel at 77'F (p., = Heat Input of auxiliary fuel (-Ah.,, : Density of waste gas at 77 'F (p*,) = Mean Heat Capacity of Air (Ce.,,,) Reference Temperature (T,d) = (For thermal oxidizers) 77.0 ',F 0.0408 lbft3 21,502 Btu/lb 0.0739 tblft1 0.255 Btu/lb'F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEL.i,) Auxiliaryfuel flow (Qaf) at 77"Fand 1 atm. = Total Volumetric Throughput (q.J at 77 'F and 1 atm Capltal Racowry Facton % LEt-i Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumptaon (FP) o*" Operating temperature of oxidizer (Ti,) Temperature of waste gas at outlet to preheater (T.") Temperature of flue gas exiting the regenerative oxidizer (Tr") Heat lnput of waste gas (-Ah.*,) Estimated Auxiliary Fuel Flow (Q"i) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) : (:x,) = = tl((x,)/({Ix,) x LEL,))I 1= Where xr is the volume fraction and LE! the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEt-i,) x 100 = = {LEL., x 0.2ae)/(:x,) = = (Total Adjusted Conc. With Dilution AirlLEl-") x 100 = (From Data Entry Tab) = = 1oo - (:xr x 100/106) = = [(1.17 x 10 4) x O*,x AP]/€ (From Data Entry Tab) = Heat Recovery r (Tr, - T*,) + T- = = Tr' - 0.9s(Tr - T*J = = : (-Ah.i) x Where (-Ah.J is the heat of combustion and x, the fraction of componeht "i" at 77 'F (Calculated using Equation 2.45 in Appendix B) = 5% x Total Energy lnput = 0.05 x pr, x Qri x Cpmri x {Tn - T,e, = (Note: lf the 0 ppmv 12,892 ppmv 0.00 percent Not applicable Not Applicable = q, = Q*. + Q. + Q"i = CL, + qf : 100 scfm 20.90 percent 0.4 kw 100 scfm 1,900 'F 1,350 "F 190 'F 0.00 Btu/scf 0.20 scfm L72 gt!/nin 167 8tu/min Ycs 0 scfm 100 scfm i (1+ i)"/(1+ i)" - 1 =Capital Recovery Factor (CRF) = Life and i= lnterest Rate c6rtlh lO2doturl lnclnerator + auxiliary equipment'(A) = EquipmentCosb (€C)forRegenerativeOxidizer =(2.204x1OO,OO0+11.$ZOtot;x1UOUZCfet71999CEPCI)= S4l4,2g2ln2022doll.tr tnstrumentationb= o.1oxA= S4tA2t Salestaxes= O.O3XA= 512,428 Freight= O.O5XA= $2O,7L4 Tot l Purch.$d lqulprut osts (B) = S488r53 ln 2022 dolhrs F@tmt r . - Aqllbry Gqulpmnt lnddca rquhmnt (Gf., duct rc*) lmlh not irchrd.d wltfi unlt fumldild by lndmEto. w.rdd. b - lrcMGs ttE lnrtrumnt rbn .nd @ntrob fumhh.d by thc lrclnlntor wndor. I Fo!ndations and Supports = Handling and Eredion = Electrical = Piping = lnsulation for Dutuort = PaintinS = Site Preparation (SP) = BuildinSs (Bldg) = Tot l DlGt C$ts (DC) = Engineering = construction and field erpenses = Contractor fee5 = Staft_up = Performance test = Dr.Gr hndlrdm cott3 0n 2Of2 dofB, 0,08x8= O.14xB= 0.04x8= O.02xB= O.O1x B = O.01x B = B+C+SP+BHg= fot l OiEct lnstalhton Crstr = 539,108 s58,439 s19,s54 59,777 54,t69 s4,88e so 5o 5146,656 S635,5@ in 2022 dollars s48,88s s24,443 s48,88s 59,n7 S,1,889 Tot.l tndlrct tGrt lhhn co*. (|tr 2c2 &llml 0.10 x B= 0.05x8= 0.10 x B= 0.02xB= 0.01t B = Total lndlEct Co3t3 (lc) =s135,879 977 Annual Electricity Cost Annual Fuel Costs for Natural Gas Operatin8 Labor Maintenance Costs = Annual Electricity Usage x Operating HoursAear i Electricity Price = = Costtod x Fuel Usage Rate x 60 min/hr x Operating hours/year Operator = 0.5hours/shlft r Labor Rate x {Operating hours/8 hours/shift) Supervisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (operating Hours/8 hours/shift) Materials = 100% of malntenance labor s271 sae13 527,a75 $4,roG i27375 527,37s overhead Ad ministrative Charges Property Taxes lnsurance Capital Recovery = 60% of sum of operating, supervisor, maintenance labor and maintenance materials = 2oA ol rcl = 1% ofTCl = 1% ofTcl = CRFITCI-I.08(cat. cost)l ssr,739 s16,9s3 s8,496 9t 49G s8O,199 coit Effcctircm$ s (Totll Annull Cost)/Annul Qu.ntity of VOC/HAP Pollutlnt3 Dcstroyld) Total Annual Cost (TAC) =p.r yG.r ln 2022 doll.rs Pollutants Oest.oyed = 0.0 tons/y4r = SIOI{I.:y|Z,ZIZ mr tl)n Nore: Th. rd.. dpl6'on lhn (tEL), h.n d.omburtron and mole.ul.r *eighl forrome commnly uid Vtr/HAP.re p,ovided 'n the table b.Iil, rn additio., rh. h..r dcomblnion to be enr.rd in collmn 0 hz &er helingvalu.{tHv), nd ahiahd h..t.iv.lu. IHBV). 5lt m s_15 Number ol oFrnrm hou6/y.ar rnld volumeticio* r.i.lqJ at 77"F and I nm Moto/Fan Etrd.nq (El lnlet wart. G- remp..du.e (T.J Operding Temp.r.l!.o (Tr) 06tudion.nd R.mdal Effi.ienq {oRE) tnimd.d Equrphem Lre l{im.r.d..t.h6r lr. Iy) sE.e v.lodv tor ..t.Bt I Ol Cqcat'lot 2022 N.ru,.l 6.3ruelC6t (c6!-J M.lnlen.n.. tabrrare Conllna...y F.dorlCr) r ctrc nd.ckmiar 4nrqf,.^'cdr tohll@.!r.i6'd .er.6n, bdrs.Em.rtE!@ *ranil.dtiil.$(.., Mrs,r.deEbr. P.r.md.6 lo. condon Co6ooudt @ :b(nrk!ytuus tEdroh :tuonrdr arAsl.nd 615. \sr//rwii. F/.tekiq/.nuratmr.F,o2-e hh4. .d.Gtrau5llaffi h,ffi@4inbdndp.* brh.tffiffi s r/lw .L p/di,/MRvn3olsBra.hh t@//ffi bh F/crtu.Enr'c_drha) bdr '.$ rd @rdr .rhre!46.r Empl,@nir 's//tlt bh.B/etorivn! i.i hrir. Noudy ru5 br r ed il*d4 ohmdr .t3 !-Methylpyrrolidone n-Phenylenediamine (ylcnc :thylben.ene NI N/ NI N/ NI NI N/ N/ N/ N/ Constants used in calculations: Temperature of auxiliary fuel (T,r) = Density of auxiliary Fuel at 77 'F (p.i) = Heat lnput of auxiliarv fuel (-Ah.,r) = Oensaty of waste gas at 77 'F (p* ) = Mean Heat Capacity of Air (C"-",,) = Reference Temperature {T,d) = ( For catalytic oxidizers) 77.O ',F 0.0408 tb/ft3 21,502 Btu/lb 0,0739 tb/ft3 0.248 Btu/lb'F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEL-,,) = (:x,) = = I:((x,)/((:x,) ' t-EL,))l ' = Where x, is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Cohc. ln Mixture/LEl-,,) x 100 = = (LEL*, x 0.249)/(:x,) = = (Total Adjusted Conc. With Dilution AirlrE[,) x 100 = (From Data Entry Tab) = = 1oo - (:xr x 1oo/105) = = t(1.17 x 10 4) x q* x API/E = o*,: (From Data Entry Tab) = Heat Recovery x (T1, - T*,) + T" = =Tr,-T*"+T*,= : : (-ah.,) xr where (-dh.,) is the heat of combustion and x, the fraction of component "i" at 77 'F (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% xTotal Energy lnput =0.05 x pr x Qr x Cp.r x (Tr -T,er) = (Notei lf the = qo, x (519)/(77 "F + 460) = where Qh is the volumetric flow rate of the waste gas {q,) corrected to 60 'F and 1 (calculated using Equation 2.28 in chapter 2 of the Cost Manual) % LEL.,, Dilution Factor Lower Explosive Limit (LEL) of waste gas aiter addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) o*" Operating temperature of oxidizer (Tr,) Temperature of waste gas at outlet to preheater (T*") Temperature of flue gas exiting the oxidizer (Tr") Heat lnput of waste gas (-Ah.*,) Estimated Auxiliary Fuel Flow (Q", at 77 'F and 1 atm. Auxiliarv fuel Energv lnput = Minimum Energv required for combustion stabili2ation = ls the calculated auxiliarv fuel sufficient to stabili2e combustion? auxiliarv fuel energy anput > 5% ofTotal Energy lnput, then the auxilary fuel is sufficient.) Auxiliary fuel flow (Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (q.r) at 77 "F and 1 atm = q, = Q*o+ Q€ + Qs, = Q*,+ qr= Cakulatlon of C.taF Voluna and Estlmat.d T.mpenturo of Waste Gas Entednt th€ CattlYst l€d Volumetric Flow Rate at 50'F and 1 atm (Qft) catalyst Volume (Vol."r) Estimated inlet temperature to the catalyst bed (T,,) = Crpltal Rfficry tactor: 0 ppmv 12,892 ppmv 0.00 percent Not applicable Not Applicable 100 scfm 20.90 perc.nt 0.4 kw 100 scfm 900 'F 560 'F 340 'F 0.00 8tu/scf 0.58 scfm 597 Btu/min 78 8tu/min Yes 1 scfm 101 scfm 97 scfm 0.19 ft3 900 "F Capital Recovery Factor (CRF) =i {1+ i)^/(1+ i)" - 1 = Where n = Equipment Life and i= lnterest Rate Future Worti Factor Future Worth Factor (FWF) = i [1/(1+ ilY - 1] = O.X232 Wherc v = Catalvst Life and i= lnterest Rate dold lncinerator + auxiliary equipment'(A) = Equipmentcosts (Ec)foraFixedBedCatalyticOxidizer =(1,443xQtot^(0.5527))x(2022CEPll1999CErc|) = lnstrumentationb = 0.10 r A = S.lestaxes= 0.03xA= Frei8ht= 0.05xA= Tot l PurdE$d equipment @5tr (8) = Fo&Eta3 a - Auxilary rqulgmnt lrch&r lqulcmnt (.&, duct Fr$ llomlly rct hdrdcd whlr untt turnE4d bry lmlnmtor wndor. b - lrcfud.s tht lnstromnt tbn .nd @ntrob fumish.d by ti! hcircntq Endor. 539,222 rn 2022 dolhrs s3,922 s1.,77t S1,96r 96283 ln 2022 ddlm Foundations and Suppods = Handling and Erection = Electrical = Piping = lnsulation for Dutuork = Painting = Site Preparation (SP) = Buildings (Bldg) = Total Dlrtrt Costs (DC) = Engineering = Construction and field expenses = contractor fees = Start-up = Performance test = Continenry Cost (C ) = 0.O8xB= 0.14x8= 0.04x8= 0.02x8= 0.01 x 8= 0.01x I = DlrGt lrEtdmoo Cocti (ln 20Eil dolm) g+C+SP+Bldi: Tot l Dicct lct lhton Costs ' Tot l lndiEct Cort5 (lq = s3,703 55,480 Sl,8s1 5926 5'163 s463 so so $r3 68s S6o,t5., tn 2022 dollars $4,628 52,314 s4,62r 5926 $468 Sl2,9s9 s7.313 rfrl h(trrct tBt lhild cot8 0n 2ol2 dollm) 0.10x8- 0.05x8= 0.10!8= 0.02x8= 0.01 xB= Catalyst Replacement Cost Annual Electricity Cost Annual Fuel costs for Natural Gaa Operatin8 Labor Maintenance Costs = 1.08 x CC x Vol.., x FWt where cc is the s/ftt coEt for the replacement catalysc Vol.{ is the volume of catalyrt required based on the waste 8as flow Gte (Qft) and the cat.lyst space S31 velocity (O); and FWF is the future wodh factor. = Annual Eledricity Usage r OpeEting Hours/year x Eledricity Price = = costto.r x Fuel usage Rate x 50 mis/hr x opehtinS hours/year operator = 0.5hours/shift x Labor Rate x (Operating hours/8 hours/shift) Surervisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operating Hours/8 hours/shift) Materials = 10O% of maintenance labor 9328 s10,118 $27,a75 s4,106 $27,37s $27,375 overhead Administrative Charges Propeaty Taxes lniulance Capital Recovery = 60% of sum of operatihg, supeilisor, maintehance labor and maintenance material5 = 2% ol rcl = 1% of TCI = L% of fcl = CRFITCl-1.08(cat. Cost)] t51,739 Sl,609 s804 Sro4 97,S90 cost Efflctiwrcs . (Tot l Amul cortl^Annul Qusntity ot VOC/HAP Polld.rtr DBtroyad) Annual Cost (TAC) =Itl lEr y..r ln 2022 0.0 tom/yc.rPollutants Destroyed = ton ol ln 2022 doll.R Noie:Ih. lowe.explo5io. limfr(LtL), h.n d.omb6tion.nd mole.ul.,w.aahlrorrom.commn! $.d voc/HAP:re provided in th. table b.ld. rn.ddton, rhe he.l ol.omb6lion to &ente.ed in column D E. lower h.aring valu. luvl, nd. higfi.r he.tinge.lue {HHv). 5_E afi s1 Perceitansoiecd.rylHR)= ;Fc,I hld volumerictu.ne(a-J al 77oF.nd 1 ns Moto./F.n E6cbnq(.1 rnla w-r. G3 Lmpe..ru.. lT.J OF.iins le6p.r.ru.. IIJ 06t0did .nd nem@al tfli(r..q {ORt) Ertimd.dtqupm€nr Lr. Enimrred..r.lFr |il. (yl sp.c. velodyfor.r.lrr (o) CErcl'ror 2022 N.tu..l 6.i f u.l c6r (c6!-J M.int.n.n.o L.bor ..le co.rina.ncv F.dor(CF) . em B*tu'iar tME..4tuilc6r kbrb&<qtrrbre luhrb, b( i hrc mr.n rd re wdl rlwn .or rnd.r3 l. !, Masl k.@FnbE d rpdpilft{r*dErkfrft .db'Ektuffi. .4ik 8e!s Erc(a nbrmil 6&TOdU5Eryffi ffid&blE'dp.td 6rht@ffi .ffiBl..&ddE:ffire/&@. r@//ttt u p/rtd,Env-r_n.L[n). tuudy nb k q..btr '@3 //ff a.E/ar.u@^va! {.161 tudy nrt e rrd.kd6.6il drrd Constants used in 6lculations: Temperature of auxiliary fuel (Tar) = Density of auxiliary Fuel at 77'F (p., = Heat lnput of auxiliary fuel (-Ah.d) = Density of waste gas at 77'F (p*) = Meah Heat Capacity of Air (Cr."r) = Reference Temperatur+ (Td) = (For catalytic oxidizers) 77.O .F 0.@08 tblft3 21,502 Btu/lb 0.0739 tblft! 0.248 Btu/lb't Sum ofvolume fradion of combustible components = Lower Explosive Limit of waste gas (LEI-L) % LEL-" Dilution Factor Lower Explosive Limit (LEL) of waste 8as after addition of dilution air lnlet volumetric flow rate(Qwi) at 77"F and 1 atm. Oxygen Content ofgas stream Fan Power consumption (FP) a*" Operating temperature of oxidizer (Tfl Temperature of waste gas at outlet to preheater (T*.) Temperature of flue gas exiting the oxidizer (Tr.) Heat lnput of waste gas (-AtreJ Estimated Auxiliary Fuel Flow (Q€r) at 77 'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliarv fuel sufficient to stabilize combustion? Volumetric Flow Rate at 50'F and 1 atm {Off) catalyst Volume (Vol.il) Estimated inlet temperature to the catalyst bed (T,r) = Crplr.l nacorr.ry f .cbr: = (:xi) = = [:((xi)/((Ixr) x LE\))]'!= Where xl is the volume fraction and LElt the lower explosive limit for each combustible component in the waste gas. = {Total Combustible Conc. ln Mixture/LEl-") x 100 = = (LEL.k x 0.249)/(:xi) = = (Total Adjusted Conc. With Dilution Air/LEl*i,) x 100 = (From Data Entry Tab) = = 100 - (:x, x 100/106) = = [(1.17 x 10.4) x Q*rx API/E (From Data Entry Tab) = Heat Recovery x (Tn i T,) + T*,= =Tri-T*.+T*r= =: (-Ahci) xi Where (-Ah.,) is the heat of combustion and { the fraction of component "i" at 77 'F (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy Input = 0.05 x pri x O{,, Co-ri, Fri - T,a) = (Note: lf the O ppmv 12,892 ppmv 0.0O pcrccnt Not epplic.bL Not Applic.bl. l0O scfm 20.90 pcmnt 0.4 kw 100 sfm 900 'F 560 'F 340 'F 0.00 Btu/scf 0.58 scfm 597 Btu/min 78 Bfirmin Ycs 1 scfm 101 scfm 97 scrm o.r9 ft3 900 .F auxiliary fuel energy input > 5% ofTotal Energy lnput, then the auxilary fuel is sufficient.) Auxiliary fuel flow (Qaf) at 77"F and 1 atm. = Total Volumetric Throughput (qoJ at 77'F and 1 atm = O.i = q*o+ CL + CLr = Owi + qf = G.loddoo of C{.a}!tlrdrr'}..rd Er&fli.d l.Gpdrun olWIi.6sBi.llr|fi. C*t !t lcd = qd x (s1e)/(77 "F + 460) = Where Or is the volumetric flow rate of the waste gas (qJ corrected to 60 'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) Crpital Recovery Factor (CRF) =i (1+ i)"/{1+ i}" - 1 = hBrWordrfff where n =Life and i= lnterest Rate Future Worth Factor (FWF) =i [1/(1+ i)Y - 1] = Where v = Catalvst Life and i= lnterest Rate ffiEb. i r - Adffrry rqupm* Ldu&r rqutrmnt (r& duct rc*l 'mlly trol lrdudcd wl$ unh fumbfd by Mmntor wndc b - |rcfu&r ft. nrstrucit tloo .nd @rd furnlrh.d by thc loclncnbr wndtr. lhcinerator + auxiliary equipment'(A) = Equipment Costs (EC) for a Monlith Catalytic Oxidizer lnstrumentationb = Sales taxes = Freitht = Foundatlons and Supports = Handling and Erection = Electrical = Piping = lnsul.tion for Ductwork = PaintinS = Site Preparation (sP) = Buildings (Blde) = Total Dlcct Cort! (DC) = Engineering = constructioh and field erpenses = ContEctor fees = Sbd-uP = Performance test = Iod n dr.c.d.qirioEr carr 0n 2m2dob.tt = (1,443 x Qtot^(O.ss27)) * {ZOZZ Crer/rSSS CrrCrl = 0.10 x A= 0.03xA= 0.05xA= 539,222 in 2022 dollaE 53,922 57,777 S1,961 S46,2t3 tr 2022 dbrsTot l PurdE*d Gquhmcnt co6ts (B) r Tot l DIECT lnst lhtonCostr= Dbr.t hndb{d Co.tr 0n 2022 dolill O.08xB= 0.14x8= 0.04x8= 0.02r8= 0.01x I = 0.01t I = B+CISP+Bldg' s1703 s6,480 s1,8s1 9e26 s453 S453 so so S13,Etg Sa),l67 ln m22 dollaB 91,62t 52,314y,62t 5925 S463 s12,sse roiJ lrldnct lm4bdql c6rr (h 2@jl &llxd 0.10 x B= 0.05t8= 0.10x8= 0.02x8= 0.01x8= Totel lodlrect Oosts (lQ . Catalyst Replacement Cost Annual Eledricity Cost Annual Fuel Costs for Natural Gas Operating Labor Maintenance Costs = 1.08 t CC r Volor x FWF Where CC is the S/ft3 cost forthe replacement ctalyst; Vold is the volume of catalyst required based on the waste gas flow Ete (Q&) and the catalyst space S31 veloclw (O); and FWF it the future worth factor. = Annual Eledricity UsiSe x Operating Hours/year r Eledricity Price = S32t = Costtod x Fuel Usage Rate x 60 min/hr x Operating hours/year 910,113 Operato. = 0.5hours/shift x Labor Rate x (Operatihg hours/8 hours^hift) Superuisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operating HouR/8 hours/shift) Materials = 10O% of mainlenance labor 527375 $4,106 527,175 s27,375 Overhead Administrative Charget Property Taxes lnsu6nce CapitalRecowry = 60% ofsum ofoperating, superuisor, maihtenance labor and maintenance materials = 2% ol fcl = 1% of TCI = 1% of TCI = cRF[TCl-l.08(cat. Cost)] ss1,739 s1,6os s8o4 9ro4 s7,590 Cort €tuh,.ms . (tot l &!ru1 C6tliAnnol qrmfv of VOC/}iAP Po$lJt.mr D.rtroy.d) Annuaf Cost (TAC) = S159,254 p.ry!.rln aoz2dolh?s Pollutants Destroyed = 0.0 ton{Yar Effectiveness = t rote: ft. le.. dplGion linn {tEl), hen ol comblilio. and molecu l.r werght for sohe commonlt uid Vfr/NAP,. provi&d inrn. rabl. bls, l..ddilion, ih. h..l d(ohbusnon to b.nl.r.d h.olumn D a a lil.r h..ting v.l!e (LHV), nd a h8her h..ii4v.lu. IHHV). l_1t t( t.o Number ol otsr.t.8 ho!B/ye.r rnlAvoluh.ni.tuw,.r.(qJ*77qF.ndlnm Motor/Fil tfiicr.nq(r) hld Wde 6a Temp.r.tur. {I!J Op.rrinB I.mp.r.l ui. (IJ Errim.r.d (n.lFr life (y) sp..€ velo.hy lor ..r.lFl I O) Per.e^l E.ry Red.ry(HR)f CEX!'td Zo22 N.rur.r c.t a!.1ccr (c6q-J M.l.rEn...e Labor .ale Co.tlnrencv Fador{cF) .. (6dtd .Y tu u r €86 r.['fu rs! //rw ir F/d..nti!/rnMrfrmr.r._or_q nhD. orh*#@ffi 3 t rdulrrr,.dild.! . r16rin sr/ls..t p/dn0ln4Bv.303sud^.hrn. ffi14&knd.sdE.'k&i6r'k..@ r@ //tlt.bB p/,r.qmiv43_Br i6l edy n6 k @&i lsr//lffibh F/*+ui,.nret-^.(tr6l Houay.bi 6r {-Methylpyrrolidone n-Phenylenediamine (ylene :thylbenzene NI NI NI NI NI NI NI NI NI r.&t t Constants used in calculations: Temperature of auxiliary fuel (T.1) = Density of auxiliary Fuel at 77 'F (p", = Heat lnput of auxiliary fuel (-Ah.",) = Density of waste gas at 77 'F (p",) = Mean Heat Capacity of Air (Ce.",,) = Reference Temperature (T,d) = (For catalytic oxidizers) 77.O'.F 0.0408 tblft3 21,502 Btu/lb 0.0739 tblft3 0.248 Btu/lb'F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEL.,,) = (:xr) = = t!((x,)/((Ix,) x LEL;))I 1 = Where xr is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. = (Total combustible Conc. ln Mixture/LEl-,,) x 100 = = (LEL.,, x 0.249)/(!x1) = = (Total Adjusted Conc. With Dilution AirlLEl-r) x 100 = (From Data Entry Tab) = = 1oo - (:xj x 1001106) = = [(1.17 x 104) x O*,x AP]/€ = Q_r= (From Data Entry Tab) = Heat Recovery x (Tri - Twi) + T,i= = Tri - Two + Tw,: = : (-ah.,) x, Where (-Ah.,) is the heat of combustion and \ the fraction of component "i" at 77 "F {Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) =5%xTotal Energylnput=0.05 xpr,x q,x Cp.r,x (Tr,-T,"r) = (Note: lf the = O{o, x (s19)/(77'F + a60) = Where Qft is the volumetric flow rate of the waste gas (O.J corrected to 60'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) % tEL^* Dilution Factor Lower Explosive Limit (LEL) of waste gas alter addition of dilution air lnlet volumetric flow rate(Qwi) at 77"F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) Operating temperature of oxidizer (T1,) Temperature of waste gas at outlet to preheater {T*.) Temperature of flue gas exiting the oxidizer (Tr") Heat lnput of waste gas (-Ahc*,) Estimated Auxiliary Fuel Flow (Q"r) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energv input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) Auxiliaryfuelflow(Qaf) at77'Fand 1 atm. = Total Volumetric Throughput (q"r) at 77 'F and 1 atm,= Q, = Q*. + CL + CIr = O-, + Q..= Gkalatton of Cetalyst Volume ard E tlmatsd Tempe6turc ot waste Gas Enterlng the Catah led Volumetric Flow Rate at 60'F and 1 atm (Qh) Catalyst Volume (Vol."r) Estimated inlet temperature to the catalyst bed {T,r) = Capftal Rocowry Fadon 0 ppmv 12,892 ppmv 0.0O percent Not applicable Not Applicable 100 sqfm 20.90 percent 0.4 kw 100 sclm 900 'F 550 .F 340 .F 0.00 Btu/scf 0.58 scfm 597 Btu/min 78 Btu/min Yes 1 scfm 101 scrm 97 scfm 0.19 ft! 900'F Capital Recovery Factor {CRF) =i (1+ i)"/(1+ i)^ - 1 = Where n = Equipment Life and i= lnterest Rate tuture wortft F ctot Future Worth Factor (FWF) =i [1/(1+ ilY - 1l = Where v = Catalvst Life and i= lntcrest Rate Tord Prdla.d a[bnai ccrt lncinerator + auxiliary equipment' (A) = Equipment costs (Ec) for Fluid Bed catalytic oxidizer lnstrumentationb = Sales taxes = Freight = Foundations and Supports = Handling and Eredion = Eledrical= Piping = lnsulation for Dutuork = PaintinS = Site Preparation (SP) = Euildings (Bld8) = Tot lDlEctcost5(DC)= EnSineering = Construction and field expenses = Contractor fees = Start-up = Performance test = Continency Cost (C ) = Dl?rctln!*$on Co.l3 0n 20Al do|lrl 0.08x8= 0.14 x B= 0.04x8= 0.02x8= 0.01x B = 0.01x B = Tel OlEd lNt lhton c6B = B+C+sP+8Ha= Iotd ridnd htiilbdo cai3 (h 2022 dolh.l 0.10x8= 0.05x8= 0.10 x B= 0.02 x B= 0.01x B= Tot l lndl.Ect Costs (lC) = = ((8.39 x 10.000) + (19.2 x qtot)) x (2022 CEPI/1999 cEPcl) = 0.10xA= 0.03iA= 0.O5iA= cF(lc+DC)= 5182,345 In 2022 dollari s1&23s ss,,t70 59,117 S215,16t ir 2022 doll.rsTotrl Purcfu*d Gquipmnt @st5 (8) = F@tmtr3 . - Auflhry Gqulprcd lnchrdg .qulprBnt (G&, duct rc*) ffiSy nd Frchfu whh unlt furnlttcd by lndncntor wndq. b - lrclu&3 th. ln*rumnt tbn .nd @ntrck furnlshcd by tha lrclDr.tol Endor. st7,2r, s3q124 s8,607 s4,303 S2,ls2 541s2 so so $64,sso S279,71E tn 2022 dothrs 521,s17 S1o 7s8 S2r.,s17 s4,303 s4ts2 s@,247 s33,997 Catalyst Replacement Cost Annual ElectricityCost Annual Fuel Costs for Natural Gas Operating Labor Maintenance Costs = 1.08 x CC x Vol.., x FWF Where CC is the S/ft3 cost for the replacement catalysq VoLd is the volume of catalyst required based on the waste Bas flow Ete (qe) and the catalyst space $f velocity (O); and FWF is the future worth factor. = Annual Eledricity Usage x OpeEting llours/year x Electricity Price = = Costnd x Fuel UsaSe Rate x @ min/hr x Operating hours/year Operator = 0.5hours/shift x Labor Rate x (Operating hours/8 hours/shift) Supervisor = 15% ofOp€rator Labor = 0.5 hours/shift x Labor Rate x {Operating Hours/8 hours/shift) Materials = 100% of malntenance labor s328 s1q1r8 s27,379 S4,106 s27,375 527,375 overhead Administrative Charges Property Faxes lnsurance Capital Recovery = 60% ofsum ofoperatin8, supervisor. maintenance labor and maintenance materials = 2% of fcl = 1% of TCI = 1% of TCI = CRF(TC!1.08(cat. Costll ss1,73e s7A79 S3.740 s3,7ro 53s,296 qu!ntlty of VOC/HAP Pollutlnts Dstroycdl Annual Cost (TAC) = 519&702 pcr yr.r in 2022 Pollutants Destroyed = 0.0 tone/yc.r ton of @llut nts rorcEd ln 2022 dolhrs ktuwd&|;;;;--E ilor.: fre |tu.. dolGion limn ILEL), h€d d combuttion.nd mol.cula.weiEh to. tom. commn[ 6dvc/MP:reffoead.dinrhetablehlil. ln.ddilion,iheh.ilol.omburtionlob.entered ir.ol!mn D 6. l*.r hefiing v.lu. {lHV),.d.n8her h.atinavalu. (HHVI. XumbE. ot oprr{ing hourr/yer rnldvolometicf,owr.l.(q-Jn77oF.nd1nm Motor/F.n Efiicienq(.) lnld Wni. Ga Temp.rztu.. (T*) oFr, int T€mpe..l ur. On) D6tdion and n.h@J tfficrenry {oiEl tstim.r.d€qupm.nt tfe P...enttneryne@.ry(HR). @,d E aa{l' lot 2022 N.tur.l 6.s Fu.l c6r (C6!-r) M.i.t...nc. L.bor r{e Co^rinae.ry F.do,(CF) . catoctuch.niolEndenn.ErnrcdrE or.rb&.sr.rhhe .eh6,!dt6(tu([roj6 .r*n*.w^(6ti*ril.. Mesls.@p.b. & rrlildBsrtuut hror.km c//Irl d. Fl@qA^MrA!h/.p.-or-il hhl. tM@lb&'6lErs.ffi D/h-@ @/,s.r. p/dB/n4Lr.rr5dAhh rllr*ffi@ebnBEiF,'ffi ryh*s/6@h. LqtT/rk btr p/&r.ur.nvdi-n.rhrhl kudy nb' b 4f,.b' ldelFidrEaphnd.d Ls.//ww bk.p/cr.umnr6 i.r.irml. Nouny nnr k ,l-Methylpyrrolidone n.Phenylenediamine (ylene :thylbenzene NI NI NI NI NI NI NI NI NI N' ( Constants used in calculations: Temperature of auxiliary fuel (T"r) = Density of auxiliary Fuel at 77 'F (p"r) = Heat lnput of auxiliary fuel (-Ah."r) = Density of waste gas at 77 'F (p*,) = Mean Heat Capacity of Air (C0.",.) Reference Temperature (T,"r) = (For thermal oxidizers) 17.O.F o.o4o8 tblft3 27,502 Btu/lb 0.0739 tb/ft3 0.255 Btu/lb'F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEL-*) : (:x,) = = [I((x,)/((Ix,) x LEL,))] 1 = Where xr is the volume fraction and LEq the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEk,,) x 100 = = (LEL.,, x 0.249)/(:xi) = = (Total Adjusted Conc. With Dilution Air/LEl*,,) x 100 = (From Data Entry Tab) = = 1oo - (:xr x 100/106) = = I(1.17 x 104) x o*,x aPl/E (From Data Entry Tab) = Heat Recovery x (Tr, - T* ) + T.,= =Ti,-T*.+T* = ::(_Ah.)r, Where (-4h.,) is the heat of combustion and \ the fraction of component "i" at 77 'F (Calculated using Equation 2.21 in Chapter 2 of the cost Manual) = 5%xTotal Energy lnput =0.05 xpri x q, x Ceil x (Tr, - T,d) = {Note: lf the 0 ppmv 12,892 ppmv % tEt-,, Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution aar lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. OxyEen Content of gas stream Fan Power Consumption (FP) o*. Operating temperature of oxidizer (Tr,) Temperature of waste gas at outlet to preheater (T*") Temperature of flue gas exiting the oxidizer (Tr") Heat lnput of waste gas (-Ah.*,) Estimated Auxiliary Fuel Flow (Q", at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) Auxiliaryfuel flow (Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (q"r) at 77 'F and 1 atm Capltal Recowry Factoe = Q., = Q*.+ Q" + Q.r = O*, + qr= 0.OO percent Not applicable Not Applicable 100 scfm 20.90 percent 0.4 kw 100 sclm 1,500 'F 1,150 'F 550 .F 0.OO Btu/scf 1.32 scfm 1,158 Btu/min 141 Btu/min Yes 1 scfm 101 scfm i (1+ i)"/(1+ i)' - 1 = Where n = Equipment Life and i= lnterest Rate Capital Recovery Factor (CRF) = lncinerator + auxiliary equipment' (A) = Equipmeht costs (Ec) for Recuperative Thermal Oxidizer lnstrumentationb = Sales tax€s = Freight = co.t3 lh 2o2 = (21,342 x Qtotlo.2s)) F {2022 cEPl/1999 cEPcl) =S143,t47 in 2022 dolhrt Footmta3 . - Adlhry cqulpmnt krddcs cqu{rErt (ta., dud rct) ffimly not lndud wlth unlt tumb b - lmfud.r tha lnttnrmnt tbf, .id @ntrolr fum&had bt tho lEln@to, rcndor. s14385 S4,3rs 57,1s2 lot l Purch.ed .qohmnt @!ts (B) - 9169,739 in 2022 dolh.s by hdnar.br wndor. 0.10xA= 0.03tA= 0.0SxA= Foundations and Supports = Handlint and E.ection = Electrial= Piping = lnsulation for Ductwork = Painting = Site Preparation (SP) = Suildings (Bldg) = Tot l Dlcct co58 (trc) = Engineering = Construction and field expenses = Contractor fees = Start-up = Performance test = Contineory Coit (C ) = B+C+SP+8ldi= Tot l DlEst lnstallatoncoJt = Total lrdlE€t Cort! (lO ' Dkcr lnttrlr{m cod! ft 2or2doa.B, 0.08x8= 0.14x8= 0.()4x8= O.02xB= 0.01x B = 0.01x I = s13,57e $23,753 S6,790 s3,39S Sr,@7 s1,4r7 so So sso,s22 5220,651 ln 2022 dollaF s16,974 s8A87 S16,974 s3,395 S1,607 y7,527 S26,819 Iotrl lrdrtct lndd6 coda (h 2o2 ddlrsl O.1O x B= 0.05xB= 0.10 x B= 0.02x8= 0.01x B= cF(lc+0c)= Annual Electriclty Cost Annual Fuel Costs for Natural Gas Operating [.bor Maintenance Costs = Annual Electricity Usale x Operating Hours/year x Eledricity Price = = Costtod x Fuel Usa8e Rate x 60 min/hr x Operating hours/year Operator = 0.5hours/shift x tabor Rate x (Operaiing hours/8 hours/rhift) Supervisor = 15% of Operator Labor = 0.S hours/shift r tabor Rate r (Operating Hours/8 hours/shift) Materia15 = 100% of malntenance labor s277 919,632 527,375 S/r,106 527,37s 927,37s overhead Administrative CharSes Property Taxes lnsurance C.pital Recovery = 60% ofsum of operatifrg, supervisor, maintenance labor and maintenance materials = 2% ol rcl = 1% of TCI = 1% of TCI = CRF x TCI ss1,739 s5,900 S2,eso s2,9s0 327,u7 Cort Etulrm$ " (Tot l AnnulGo6t)/hnnul qr.ntty of VOC/H,AP Pollut nt! Dctrcy.d) Annual Cost (TAC) =par vart in Pollutants Destroyed =0.0 ton/yc.r Effcctivcness =ton of romnd ln 2022 dolhE OVEN BACT CALCULATIONS-HAP S.ldthqrderbn.&frri6.m: tufu*t ddiqi*trqFffihtffi,ffi: f 5&ti.qtso.oF.tbn: I''^'"'"'"""'"' f $ld th. tyF ol6.tdl.lud to f.bri6i. th. orbn.d$rhrvcas.ls: f lldthodcnt.donfdth..dso6.r€s*ls: ;^,,--. f Numbd d opd.ilnS houR rry..r (q) W.& G.r Flil R.r. (Q) vG Ehl.rl6 R.t. (&) Rqlird vOC cmowl dld.nq (E) €nim.td qulr.d lif. of .urfl.ry Equapn€nt (n) NumbdotOtsr.tq Hours 8dorc Orbn C.nlnerReplaom.nr (gJ ar& hous/v.ar 0.m lbs/ho!r * o.rcnt lO Y..B 130 hours adm is adu.l.ubt fel/min 98r(€ntisaddau(contoldi.iencr U5er5hooldenteradualvalue.iltnown ars n a defaufr (uiment lite. $er 5hould ent€r adualvalue, if laown l@lBol (atun rrcrnkle. is addauh valoe. User3hooldenter pref€red.ani3rer rn€, d known P.dl.l Pns.uc ol Xylcn. / Etlrylbnr... In w.sE tas fom P.r.mGer "k- fd Xyl.E / ESylbrs. P.r.md.r "m' ror xyl6. / Ethrbr6. CEPCI' tor ZO22 Anftu.l lnt.r.sttut. (l) U5eolother*ell tnown cost in&r6 {e8., M&51 6 acc€pi.ble I C.rbn C.^irt.rC6r Note:TyP.c.l@3tsforc.rbo.c.nBt.6.re'howninTablcB ll t.osn, 6t.r .^y.ditlon.l cdts fd dt pmFndon .nd bulldlnt.onsrdiq/modlffatlonl value. U!e.thouldeoter actual v.lue, ifknoans. PcPrdlon (sP) = Suildi{3l8Et): Equapm.ntC6Blorrurlll.ry.qulpm.nt(..!., dutuo*, d.hFa,.dild) continS.nry F.dor {CFl Odauhvalue.U5e.5houldenterddualvalue,if known Ddauhvalue.U5e.5houldentera(tual!alue,if known l0 Frce.t 6 a defa uh value Ih€ .onrngen.y f&tor rhould & ktween 5 a nd I 5 pe..ent qu:nflty of xyl.n. / Ethylknr.n. 8.mEd (wrc.) = Estldd.d cr6on Coniumptlon (M") 6r.n lnEfr H.ntlyop.nt.d ry$m : Numb.. of tim.s c..lste(s) replaced per ye.r = ffirhlffiln66dffiu: Tim tur &erDrb^ (eJ : Equlllbdum 6p.clty il th. lnld (Wdsr) : Woruna c.Fclty lwJ = Edm&d ToblO6on R.qod (M.) = Numb.rolc.6on qnisR Reuld : Tot.lQu.ntlv of ca6on Rquircdtor l onl*B= C+blbqf..d C.plbl 8eorry F.dorfor.uxllhry.qolpmnl (cFkox) : C.plbl iEonry r.dorfor..rton (CRF(.,haio,) = W*.n*xe,xE. Nunbu ol opdhg hopB b4oft ctu ffii*t rcplectuia . M"/c.6on crnl*.r c.p.ciw tumhrdc.6on Gnish6'c.rbonC.p.cltypdcrnBt r: ll, (1+ l)^l / I{1a I)'-11 = Wh.n n= Equlpmdt S..nd i=lnEct n.t. tlrll+ l)'l / tUa ll" - 11: Wh.ro n = O6oa C.rtu.U..nd i: lnbr.si ht 2 lb.. 2 a3@ hom o.m lb.vo(/lb.G6on 03S lb.voc./lb.c.6on rc lbi 3,m lbs. o.L121 lfl bh: ffi E e qled 2$re38 dm{F Edrilrd aplll cs lo . C..bq clnitu Ad.o.t r wth Cadtu l.p|:affi whh th. tolbwllt. .h.ndltl.ti.rl VOC Cdtroll.d/R.cwsad = xy'lenc / EthYlb.rt.n. Adsb.. V6rcl d..ibdd = Iot Applk bl. OF.lintsch.dul. = lntrmindt opd.tion Tdl c.plbl lmnmfr (1Ol (ln 2oz doaLEl P.dmE Eq[tloo Total Cost for All Carbon Adsorb€r Canist€tr ltCad,.,b) . Auxiliary [quipment (tC.,,) . TotC hrrdEtcd Equipmcnt co$ tor C.fbon Adsbcr (A) = freight = lMlhtloo Cd (h zoza do{.n} P.offi Sit€ Pr€par.tion (SP) . Euildingr (Bldg) = CoFtiatencyCo* (C) = canisler Cost x Number of Canisters R€quired = (8ased on design costs or €stimat€d using methods provided in Section 2) O.OlrA= 0.05xA= C*t s43,866 S2,m trs,866 s4s87 91,376 s2,293 Total Pu.ch.s.d [quipment OsB (8) = 549,535 kt se,s7 $o 9o Egdha 0.20x8= Total O.d.nd lndired ln.bllnld C6ts - S9,9O7 CF(Pur.h.s€ Equiphenrco* + ln*all6tion codr= 55,9,14 OlffiAmhlCdB PaEmtr M.intenan.e Costrl Carbon Canister ReDlacemenl Costs: Eq[tbn 0.05 x TCI lnstallation Cost = 0.2 x Number otCanislers x Con per canaster x Numb€r oftimes replaced/vear = 917,873 Canisters = number ofcanirt€rs x Cost per canister x 1.08 x Number of time, replacemed/year = S96,513 ad 93,923 lndlEdAnnulCd P.ndd Administrative CharSet Equdon = 2% ol lcl = 1% ofTCl = 1% ofTCl = cRtAuxiliary tquipm€nt: (ICl, 1.08(CanEter CosB)) . cd S1,3s S6s4 S6s4 s2,561 Cdt E r..tlvod ttnffi llotal Annual coil = lA^nu.l Quantty ofVoc Removed = cost Effediveness = cd SU3,489 p.r y..r ih 2022 dolL6 0.34 toni pcr yaar S350B20 pcrtnotpollut.ntrr.howdin dolls Eqrtb6 W,". =n"..x O,xE= Iotal Annual Cost {TAC) / Annual Quantity ofvOC Remov€d/Recovered = Sddttu tyts d orbn.&&r ryn.m: kffi tu d.qb',pfrtuffiatuffi: *k th€ NE ol oFatlon: kld ih tyr d m.tdj.l ud to t Mot. h. orb^ .dter v6.ls: s.ld th od.il.tion 1o.fr. dstd [td.: otuo .r^6r.r ^Jll*r {ilh .rd id.tunr I Numbd d op.r.tiry houE ts.y..r(€J w.rt.G.rrld f,.ta (O) vG Eml$ld R.t. (k) RqulrdvC rcmoEl.trd.ry(E) Enlm.td.qulpm.nt llf. ol.de.&r v6-lr.nd.urlll.ry Equipm.nt (n) Ertlm.td otun llf. (.) E{im.td Otun Rcd.@matR.t. (CRR) l,760 hoors/verr 0.m Ibr/hou, ! Y..6' !m l* ca.bon Ercanist€r' 98 per(enri5adel.ut(ontol.fiiciency Userrhouldent.r r.rualvalue,ilknown lsye.6 6 a de,aultquipment lfe. user shouldente. actual valoe, ifknown m b o,.rrhn F cantster ir zd€fautvalle. Be. should entei Drefered cankter s[€, ilknown P.di.l P..sur. of Xybr / Eihylhnz€rc in w.st€ gas *sm P.r.mlter "k' fn Xyl.m / Ethylbnra. P.r.m.t.r'm" for Xyld./ E$ylhlcn. Phnolrddd;.|@hol CEPCI'tor 2022 Annu.l lntcr.nR.E {i) Ure oforherwell lnown c6t index6 (e8., M&S) B.cceilable M.hts.^c. bbr R.t. c.rbnco{ (cc) lrlnown, 6td.ny.dltionrlc6ctorin.pcPr.tlon.MbulldlB sii. Pr.Frxion (SP): Bulldlns (Bld!) = o.r dnbtd lin 202? doll.6)Typic.l c6B lor c.rbon c.nkt.6.r. shown rn T.bl. B Equlpm.ilCdld.urlil.rycqulncnt(€.!.,dutuoil,6mtsE,.nd tud) (!c.B) = Coilln!.nqfado. (CF) '5121/hou,Baddauhvalle.Uierthould€nteradualv.lue,itknown lftheratelsnorkDown,usellOx 'S! 2ollb B. deraun valuebded on 2018 m..ket pri.e Ut{ should enrer.ctual value, il known ' 10Er.ent B a ddauhvalu€.TheronnnEencyla(o, thoutd be &tween 5 and 15 p€,.enr dp.nG?d*Elqra.tu ft 51.90 .nuarv 20[ ma.ket p.icerorvrgin c.r&n y rurl Na(onar uccuparonar tmproymst a.d taee Esnmat6- Unhed srat6, Mav 2017 hnF://ww.bts gov/o6/currenvo6_nat.htB). Boudy i.t6 f or oFrdo.r baser 'n d:t.for.lanf ihd\6im O*r:td6 - 6ih.rl5l A@S! c. L.er Rat. {S/hour)sto 2f *imatde 1lO percentot oF,ato. labo. rate tr.dkffi xlmdEffi: ffiffiliort rfrhortfrbrhil.n I|tr/EffiDD Au.ntlw ol xy'.n! / Ethylhnz.n. R.mov.d (wrcc) = v.s*l Dl.m.t.r(Dl" sud& Ar.. olA606.rvsd (s) - Number ol times canBte(, replaced per year = bft.. hnhoEld qh q.ffi: Tlh. tor Ad.o.ptlon (eJ = EqulllbdumC.p.dty.tth. lnl.t(w.rr)) = Worklnt C.p.clty (w.) = Eslm.t d Toulc.rbon R.qulrcd(M.) = NumblrofC!6on C.alsE6 R4uirod = Totd Au.nthv ofC.6on R.quk.d for 1 OnisB. Ceblhrymr Crpbl Rrcwry Fdor for.de6.r v.sli 6nd .uxllry.qulpmnt (cR.betur)= C.phl ReEry fdo. lor 060. (CRf.J = W*:n*xe,tE: Nunbr ol opffis htuE blorc .albil cilifiu rcpt@nr . Md/O6on C.nh..C.p..hy NumbrotC.6on onli.E'crbodcrp.cltyp..c.nlf.r- ll r {1 + l)'l / lU + I}"- 1l: wh.ro. = Equlpm.ntft.ndi = lnt.f.st n.t. Ii, (1 + i,^l / I(1 + 0". rl = Wh.n n = arrbd. l lL rnd i = lnt.rod n.t. o,s fr. 4.11 fr. 14 {.fr 2 4,30 ho!ts O.Z1 lb- voc/lb.c.rbon 0.385 lb. voc./lb. c.rbon {S lbs. !P@ lbs. o.1B 05531 €.thd opibl cd td r Arbd! Onhnar Ad&rtar whft Cart6 R.Da.offi rtdi d. lollorha dr.Edariade VOC Controll.d/Ihcd.r.d = Xylen. / Ethrbcnrcne Adidbar V.sl @.nEtld = VdlcC Opc6tinS S.lradula = lnErmitrnt O9mdon Tdl c.9ltl lffi (TOl (in 2022 dolhnl fhdffi Total cost forAll Carbon Adsorber Canisters (ECAd-.J = Auxiliary Equipment (Ec.,,) = Tot.l Purcfi.sed Equipm.nt Gsts for Grbon Adsdb.. (A) = Frelght = lelbdon Cd (ln D22 dolLu) Panmfr Dfect and lndirect lnstallation = Site Preparation {SP) = Euildinss (Blds) = Contint..ryCosl (C) = Eq[tlon Canirter Cott x Number of Caniiters Required = (8ared on design costs or estim.ted u3ing methods provided in Section 2) cd 943,856 s2,m S,|s,866 0.03 x A= 0.05 r A= Equtbn 0.20x B= s4s87 S1,376 52,293 Tot.l Plrch.rcd Equlpmeni &rB (B) = 5*,D2 6 Sd330 So So Tdd CXr€d.nd lndlrcd lniblliid C6B = $43S cr(Purcha.e Equipment Co*+ lnstallation co*s): S5,8,15 OL.dtul6 hnffia Operating Labor Costr: Maintenance costs: Carbon ReDlacementCostr: EqEtbn operator = 0.5 hours/shift r Labor Rate r (operatinB hourt/8 hours/shift) 5upervisor = 15% ofOp€rator tabo. = 0.5 hourr/ihift x Labor Rate r (Operating Hour5/8 hourj/shift) Materials = 100% of maintenanc€ labor Labor = CtR..,bltabor Rate x To|CRRI = carbon = CRF,.,bICC x T, x 1.081 = cd 91s,04s 52,257 s16,ss1 s16,s51 s120 S7,s26 lndaEd Aonul Cd P.nd, Overhead Administrative Ch.rges Capital Recov€ry Eqbtlo6 = 50% ofsum ofoper.tor, superuiror, maintenance labor Plus maintenahce mal€rial5 . 2% ofTCl . 1% ofTCl . 1% ofTCl . cRt&-.h, x [Tcl - [{1.08 'cc 'rc) + (LR'Tc/cRR)] " cd 330,242 91,285 S543 S543 Ss.539 hE ftcdvod ttnffi lTotal Annual aost = lAnnual quannty of voc R€moved = Cort Effectiveoe$ = cd S96,104 p.r y..r in 2022 dolL6 0.:ll to3/F.r 928r"758 p.r tff ofpollubntsrcmowd ln 2022 doll.rs Eq[tion w,,,=frb.xOsxE= Total Annual Cost (TAc) / Annual Qu.ntity ofVOC R€moved/Re(overed = s&ftWd&F,-F ilol.: Th. laer dpl6ion lint (tlL), &n d.ombclion a^d mol.cularw.iShr forroD. cohmonly u.d VOa/AAP..e grovid.d in th. table h&. ln.dd[io., lhe he.l ol.omhBtior io 6e.il...d rn column D B a l*er h4.tiq v.lue {tHV), nol . h€he, he.lingv.lu. (HHv) to N uBh.r ol oFrarinB houR/Vear lhld vollmertf,ow ril.(c\L).t TTorand 1 rm Moro,/F.n EtrtEn.y(€) rnld W.rre G6 I.mpe.atur. (TvJ OErnDrlemeeralor. (IJ 06r rldio. .nd iemdal Efii.i€.ry ( DRt) aim.red Equipmm Lr. P..c.ri Enerry R.cov.ry{HRl.l CEPCI'for 2022 il.rur.l c.s Fu€l C6r (C6!,J M.intenrn.e Labrr.r. coding.nq aador{Cf) . cE c ntuctuDiqrs^dr.il^aF.nr.6r€er.@retrrhrd .a.io[ bd L s.n il,.t roj* r *n*iff 6i d.r.r l.., M$) B.@p.bh. P.Emd.6 lor Common Compoud! & I I rstT/,s.h @/d.ctr.E/.inurhhr.e. or ilhhD lsr //lI' 5B a/d.Um^Vds_nr.hhr &dr '.ei k op.il@r .dod:r.6pLd.d sEn+..B ft I lsr#) 1@ //*ffi bL.p/crar.nvs r rd .krd., (sil(nr .d 'd!r n.cuh.ntrcEr.B l4e.2B). (ylene :thylbenzene N/ N/ N/ N/ N/ N/ N/ N/ N/ N/ Constants used in calculations: Temperature of auxiliary fuel (T,) = Density of auxiliary Fuel at 77't (p", = Heat lnput of auriliary fuel (-Ah.,r) = Density of waste gas at 77 'F (p*,) = Mean Heat Capacity of Air (ce.,,,) Reference Temperature (T,"r) = (For thermal oxidizers) 77.0 'F 0.0408 lbft3 21,502 Btu/lb 0.0739 tb/ft3 0.255 Btu/lb "F Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEl*,,) = (:x,) = = {I((x,)/((Ix,) x re!))l 1= Where xr is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl-u) x 100 = = {LEL.,, x 0.249)/{:x,) = = (TotalAdjusted Conc. With Dilution Air/LEl*,,) x 1OO = (From Data Entry Tab) = = 1oo - {:x, r 100/106) = = [{1.17 x 10 4) x Cl*r x AP]/e . Q*i= {From Data Entry Tab) = Heat Recovery x (Tfi - T*,) + T*i= = Tr - 0.95(Tr - T*J = =: (-4h.,) x, Where (-Ah.,) is the heat of combustion and \ the fraction of component "i" at 77 "F (calculated using Equation 2.45 in Appendix B) = 5% x Total Energy Input = 0.05 xpr, x Qr x Cp.r, x (Tr, -Tr., = (Note: lf the % LEL^, Dilution Factor Lower Explosive Limit {LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygeh Content of gas stream Fan Power consumption (FP) a*" Operating temperature of oxidizer (T1 ) Temperature of waste gas at outlet to preheater (T*") Temperature of flue gas exiting the regenerative oxidizer (Tr") Heat lnput of waste gas (-6h.*i) Estimated Auxiliary Fuel Flow (Q"r) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum EnerEy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) Auxiliary fuel flow (Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (q"r) at 77 "F and 1 atm Capltal Re@rery Fador: 0 ppmv 8,748 pemv 0.00 percent Not applicable Not Applicable 100 scfm 20.90 percent 0.4 kw 100 scfm 1,900 'F 1,350 'F 190'F 0.00 Btu/scf 0.20 scfm 172 Btu/min 167 Btu/min Y!s 0 scfm 100 scfm=q,=O{o+q+qr=Q{,+qr= i (1+ i)^/(1+ i)n - 1 = Where n = Equipment Life and i= lnterest Rate capital Recovery Factor (CRF) = lncinerator + auxiliary equipment' (A) = Equipment Costs (EC) for Regenerative Oxidizer lnstrumentationh = Sales taxes = Freighr = Foundations and Suppons = HandlinS and Erection = Electrical = Piping = lnsulation for 0uctwork = Painting = Site Preparation (SP) = Buildings (Bldg) = Total Dlcct cost5 (DC) = Engineering = Construction and field expenses = contEctor fees = Stad'uP = Performan.e test = =(2.204 x 100,000 + 11.57 qtot) x (2022 CEPU1999 CEPCI) = 0.10xA= 0.03rA= 0.05xA= Yl4,2A2 i^ 2022 dol|r. s41,42t 512,428 S2o,7t4 S4a8,$3 in 2022 ddLETot l Purch.sed .quipmnt osts (B) = F@tmtas r - Auxllhry .qulpmnt lrcludca.quhmnt (.a9,, duct rcrt) Mlh rct incld.d wfi unlt fumh\.d by lndnentor v.ndor. b - lrcludcs the lnrtrumnt tlon .nd @ntds furnbh€d by thG lnckf,Etor Erdor. Dlixr lnrrdl46 cosrt (ln 2022 dol.Bl 0.08x8= 0.14x8= 0.04x8= 0.02x8= 0.01x B = 0.01x8= s39,108 s58r3e s19,ss4 5e,7n s4,889 54,tr9 so so s146,6s6 5635,509 ln 2022 dollar5 948,8rs s24,A43 548,r8s 59,777 s4,889 sr35,179 577,23s 8+C+SP+Blda= Tot.l lflIrEt llr.ll.thn con3 0n at22 &llml 0.10 x B= 0.05x8= 0.10x8= 0.02x8= 0.01 tB= Total DlEct lNt ll.ton C6t3 = Tot l lndlEct Costs 0C) = Annual Electricity Cost Annual Fuel costs for Natural Gas OperatinB Labor Maintanancp Costs = Annual Eledricity UsaSe x OperatinS Hours/year x Eledricity Price = = Costtud x Fuel Usage Rate x 50 min/hr x Operating hours/year Operator = 0.5hours/shift x tabor Rate x (Operating hours/8 hours/shift) Supervisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operating Hours/8 hours/shift) Materials = 100% of maintenance labor s277 S2,9rs 927,37s s4,106 527,37s $27,175 overhead Administrative CharSes Property Taxes ln5urance Capital Recovery = 60% of sum of operating, superuisor, maintenance labor and maintenance materials = 2% ofTCl = 1% ofTCl = 1% ofTCl = CRFITCI-1.08(cat. Co.t)l ss1,73e s15,e93 Sr,496 s8196 S80,r.99 Cost Eff.ctiwrc$ . (Tot l Annul Cost)/(Annu.l Qulntity of VOC/HAP Pollutsnts Dcstrolcd) Annual Cost (TAC) =pcr yaar ln Pollutants Destroyed =O.O tons/y6r Effediveness =s27,ton of rcmnd ln 2022 doll.tr s&eqFd& F;*-ln Nol.. The l@.r !rpl6io. llmt (ltl), he, d.omb6ton.^d mol..llat *dahl lor!om. ommonlY u.d V@/HAp a.. p.ovid.d inih.i.ble bl*. ln ddaon,6. h..r ol comh6tion ro 6..ilerd incolumn D6i lil.r h€*insv:lu.(LHV), nd.hiaie, h..lin8value (HHv). Number ol ope..nng hooB/year lhldvdum.rkflow.ile(C\).r77qFandlnm Moio./F.n Efiici.nq(E) inld Wd. G- I.mee.ilur€ tr-J OFrarnrI.moernu.. (IJ O6rldion.nd R€md.l tfir.ie.q (oRE) E{imn.dEqo'rm..t 1il. tnimd.dc.r.\dltr IY) Perceni Ene.s Recovery(HR) =l N.rur.l G- Fu.l c6r {C6i-J M.inlen.n.. t.br ..le pdFfrrabrrdftd&ta.rtuft &dd6tuGE--- ffi&.mtulrq& .b 6qH rytuu s tu,r ntu rBr//ttt.hel.kb!/.ndarE{.F_0?,e6hl ffi@tr&d.6p-* o/h-@.* sr//ff.bh.p/4r.!rcnv4r_Mr.hh) e4 ,ru' b rytu is//rw brrF/c/.!'nnv-r-mr.hrn) Houi, ,.Er br *t. {uiF.d'.Ftr.6(.41H) Constints used in calculations: Temperature of auxiliary fuel (T"1) = Density of auxiliary Fuel at 77 'F {pr) = Heat lnput of auxiliary fuel (-Ah."r) = Density of waste gas at 77 'F (p.,) = Mean Heat Capacity of Air (ce."i,) = Reference Temperature (T.€r) = (For catalytic oxidizers) 77.0 'F 0.0408 tbrt3 21,502 Btu/lb 0.0739 lb/ft3 0.248 Btu/lb "F (ylene :thylbenzene N' N' N' N' N' N' N' NI NI NI ( Sum of volume fraction of combustible components = Lower Explosive Limit of waste gas (LEL-,) Volumetric Flow Rate at 50'F and 1 atm (Qft) Catalyst Volume (vol."t) Estimated inlet temperature to the catalyst bed (T.,) = Capital Racovery Fecttrl : (:x,) = = I:((xr)/({:xJ x LELj))l 1 = Where xr is the volume fraction and LEq the lower explosive limit for each combustible component in the waste gas. = (Total Combustible conc. ln Mixture/LEl-,,) x 100 = = (LEL-,, x 0.2ae)/(Ix,) = = (Total Adjusted Conc. With Dilution AirlLEl-,,) x 1OO = (From Data Entry Tab) = = 1oo - (:xr x 1oo/105) = = [(1.17 x 10 4) x O* x AP]/€ (From Data Entry Tab) = Heat Recovery x {Tr, - T.i) + T* = =Tr,-Two+Tw = = : (-Ah.r) x, where (-4h.,) is the heat of combustion and \ the fraction of component "i" at 77 'F. (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy lnput = 0.05 x pr x qi x Cehr,x {Tri -T/ei) = (Note: lf the = Q", x (s1s)/(77 'F + 460) = Where Qn is the volumetric flow rate of the waste gas (q,) corrected to 60'F and I (calculated using Equation 2.28 in chapter 2 of the Cost Manual) Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77"F and 1 atm. Oxygen Content of Bas stream Fan Power Consumption {FP) o*. Operating temperature of oxidizer (Tr,) Temperature of waste gas at outlet to preheater (T*") Temperature of flue gas exiting the oxidizer (Tr") Heat tnput of waste gas (-AlL.,) Estimated Auxiliary Fuel Flow (Q"r) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel enerSy input > 5% of Total Energy I nput, then the auxilary fuel is sufficient.) Auxiliaryfuelflow(Qaf) at77'Fand 1 atm. = Total Volumetric Throughput (q"J at 77 'F and 1 atm.= Q, : qqo+ q + CLr = Q*i+ Q"r= Cakulation of Catllyst Volume and Ertlmated TempeEturc ot Waste Gas Entednt the Ctl.lyst Bed 0 ppmv 8,748 ppmv 0.00 percent Not applicable Not Applicable 100 scfm 20.90 percent 0.4 kw 100 scfm 900'F 660 'F 340'F 0.00 Btu/scf 0.58 scfm 597 Btu/min 78 Btu/min Yes 1 scfm 101 sqfm 97 sctm 0.19 ft3 900 'F Capital Recovery Factor (CRF) =i (1+ i)"/{1+ i)" - 1 = Where n = Equipment Life and i= lnterest Rate Future Wordr Factol Future Worth Factor (FWF) =i[U(1+ i)'- 11= Where v = Catalvst Life and i= lnterest Rate t lncinerator + auxiliary equipment'(A) = Equipment Costs (EC) for a Fixed Bed Catalytic Oxidirer = (1,443 x qtot^(0.55271) x ( 2022 CEPI/1999 CErc0 = lnstrumentation6= 0.10xA= Sales taxes: 0.03 x A = Freight= 0.05xA= Tot l Purchrsd.qulpmnr @st (B) . F@tnota3 . - Aurllhry rqulpmnt lnchdci Gquhmnt (..t. duct rcrl) mmily not lncludcd whh unlt fumFl.d by trdMtor Ends. b - lnchde! thc lnrtrumnt tbn .nd @fltpb fumlrhad by th! lElmntor wndd. $39,222 |nm22 dollars 53,922 5r,t77 S1,961 S46,2&i in 2022 doll.rs Dlrct hndbr46 Codr &t zOzt Ofzrl 0.08x8=Foundations and Suppods = HandlinS and Eredion = Eledrical= Piping = lnsulation for Ductwork = PaintinS = Site Preparation {SP) = Buildin8s (Bld8) = fod Dirct Costs (DC) = EngineerinS = construction and field expenses: Contractor fees = Staft_up = Performance test = 0.14x8= 0.04xB= 0.02x8= 0.01 xB= 0.01x B = B+C+SP+Bldt= s3,703 s6,480 9Lrs1 S926 $/t63 5463 so So 9116rs 9@,1t tn 2022 dollars y,628 s2,314 51,628 S926 s463 s12,9s9 57,313 Tot l DlEct lrotalhton csb = Tot l lndtrct oons (rc) = Totd hdrEr hrniLtbo cBtr(h21t22 doErl 0.10t8= 0.05x8= 0.10x8= 0.02x8= 0.01x B = Catalyst Replacement Cost Annual Eledricity Cost Ann!al Fuel Costs for Natural Gas Operatang Labor Maintenance Cosis = 1.08 x CC x Vol..r x FWF Where CC is the S/ft3 cost for the replacement catalyst; Vo[.r is the volume of catalyst required based on the waste gas flow Ete (Qfi) and the catalyst space 931 velocity {O); and FWF is the future wofrh fador. = Annual Eledricity Usate x Operatin8 Hours/year x Electracity Price = 5328 = Costtod x Fuel L,sage P€te x 60 min/hr x Operatihg hours/year S10,120 Operator = 0.5hours/shlft x Labor Rate x (Operatins hourV8 hourr^hift) Superuisor = 15% ofOpcrator Labor = 0.5 hours/shift x Labor Rate x (Operating Hours/8 hours/shift) Materials = 100% of maintenance labor 527,375 s4,106 5n37s $27,37s overhead Administratiye CharSes Property Taxes lnsurance Capital Recovery = 60% of sum of operatinS, supervisor, maintenance labor and maintenance materials = 2% ol lcl = 1% ofTcl = 1% of TCI = CRFITCI-1.081cat. Cost)l 5s1,739 s1,609 Sto4 Sto4 9zseo Cost Elfr€tlEms r (Iot l Annu.l Co5tl/(Annul qr.ntty of VOCi/HAP Pollubm3 Dcstroyld) Annual Cost fIAC) =155 pcr y..r in 2022 doll.rs 0.0 tonsrGlrPollutants Oesroycd = ton of bllutrnts EmEd ln dollrrr Nol.:ThelderexplGionlimnltEt), h.ad.ombuttion:nd mol.ol.rweighllorsme.ohtunly usedvoc/HAP.reprovidedi.riet.bl.hlil. lnaddnio.,rh.henof.omb6r.ontob.nt.rd in colum. D is. lder heatingvallelLHV), nd.hisn.r h..n4v.lu.{HHv). Pd..nrE.erpRftd.ry{HR)= .!n^ Ihldlolumeticflo, rn.lo.J at77!F.rd I nm Moror/ran EtrEi..(y l.) hld WeeG6hp.rnr.e(T.J Op,ai.aT.moe.rur. IIJ Dgrldion..d l.m&.| E(i.ie.q (ofit) Esram.ted c.r.lF |il. (yJ sp..e v.b.ny ld c.blFr lO) CEPClr lor2022 N.tur.lG* Fu.lCc!{cc!!J M.lnl.n.ncet.bo, rat. conrha.ncy a.dor(cFl ' cftr Ltu.kftiar t4Nn{tunicdhot@..or.th dr .5r.tb. b{ B tu,. ru'.ry6 dh r' }rirbl( d. fn&ff @i tu w.n*iw^.6r hd.r.t (!., Mtr9)n..apubL & ffihffituJbaft *r+ oior .kddq dr rd rnd6 !q.d oIfr s^sld$lt 's/*.i..p/.h.E.iq/..ru.ratn/.p. o2 ff.hh). .fr65a4urqrffi M@&b'6lq.F,Mh a/h@e ffi@h6ddFld* @M@. rbn ft.uFnar thrqr.^t.nd '@ltu btdtdsn.nla'_o:hhl &iy..hrbs.,.btr rd6de krLilrdsFbn @.rur-fr, (91.B1 1idF.d,.Fn.u{.ers) Constants !sed in calculationS: Temperature of auxiliary fuel (T^r) = Density of auxiliary Fuel at 77'F (pr) = Heat lnput of auxiliary fuel (-Ah.", = Density of waste gas at 77 'F (p*,) = Mean Heat Capacity of Air (Cp."i,) = Reference Temperature (T..r) = (For catalytic oxidizers) 77.0',F 0.0408 tb/ft3 21,502 Btu/lb 0.0739 lbft3 0.248 Btu/lb'F (ylcne :thylbenzene NI N' NI N' N' N' N' N' N' N' ( Sum of volume fraction of combustible components : Lower Explosive Limit of waste gas (LEl-,,) = (:x,) = = tt((x)/((tx,) x Lrr,))l 1. Where xr is the volume fraction and LEI the lower explosive limit for each combustible component in the waste 8as. = (Total Combustible Conc. ln Maxture/LEl-,,) x 100 = = (tEL.i, x 0.249)/(:x,) = = (Total Adjusted Conc. With Dilution Air/LEt*,,) x 100 = (From Data Entry Tab) = = 1oo - (:xj x 1oo/105) = = [(1.17 x 10 4) x Q*i x AP]/€ " o*,= (From Data Entry Tab) = Heat Recovery x (Tf; - T",) + T",= - rf,- rwoT rw - = : (-Ah.,) xl Where (-4h.,) is the heat of combustion and \ the fraction of component "i" at 77 'F (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy lnput = 0.05 x pri r q x Cefrr, x (Tr,-T,ed = (Note: lf the = qo, x (s19)/(77'F + 450) = Where Qn is the volumetric flow rate of the waste gas (q,) corrected to 60'F and 1 (Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) 0 ppmv 8,748 ppmv 0.00 percent Not applicable Not Applicable %LEL^,, Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) a*" Operating temperature of oxidizer (Tr ) Temperature of waste gas at outlet to preheater (T*.) Temperature of flue gas exiting the oxidizer (Tr.) Heat lnput of waste gas (-AlL*,) Estimated Auxiliary Fuel Flow (Q"r) at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufflcient to stabilize combustion? auxiliary fuel energy input > 5% of Total Energy lnput, then the auxilary fuel is sufficient.) Auxiliaryfuelflow(Qaf) at77'Fand 1 atm. = Total Volumetric Throughput (q",) at 77 'F and 1 atm = q, : Q{. + q + Qar = O{, + Qr= Calolatlon ot Crtah/st Volums and Bdmatrd Tempo6ture of Waste Gas Enterlng the Crtalyst Bed Volumetric Flow Rate at 60'F and 1 atm (Ah) Catalyst Volume {Vol.r) Estimated inlet temperature to the catalyst bed (T,,) = Cspat l R.mry factot: 100 scfm 20.90 percent 0.4 kw 100 scfm 900 'F 660 'F 340 'F 0.00 Btu/scf 0.58 scfm 597 Btu/min 78 8tu/min Yes 1 scfm 101 scfm 97 scfm 0.19 ft3 900'F Capital Recovery Factor (CRF) =i {1+ i)^/(1+ i)" - 1 = Where n = Equipment Life and i= lnterest Rate Future Worth Factor Future Worth Factor (FWF) =i [1/(1+ i)v - 1] = Where v = Catalvst Life ahd i= lnt€rest Rate P.2252 lncinerator + auxiliary equipment' (A) = Equipmenl Costs (EC) for a Monlith Catalytic Oxidizer lnstrumentationb = Sales taxes = Freight = = (1,443 x Qtot^(o.S527)) x (2022 cEPl/1999 CEPcI) = 0.10xA= 0.O3xA= 0.05xA= Dlrrct ltrrtdblarCoct30n 2OZf dohnl 0.08x8= O.14xB= 0.o4xB= 0.02x8= 0.01x B= 0.01x B = Tot l Dlct lnst lLton Costs = g+C+SP+BHg= Iot l lrdrEt lnrLlhilon Co.ft 0n zof:l dofnl 0.10x8= 0.05i8= 0.10x8= 0.02x8= 0.01x B = s39,222 tn 2022 dolhE 53,922 St,tt7 s1,s51 $4q243 in 2022 doll.rsTot l Purchasd equiprcm osts (B) = Foo(mtcr r - Aurilhry rqulpmit |rdidGe Gqulpmat (c{., dirct rcIt} mlty nd inctrfu whfi unh fumtfnd bv rrrrntor nrdor. b - lrchdct tlE h3numnt tbn .rd @ntol! fumlshad by th. lrclmntor wndor. Foundations and Supports = Handling and Erection = Electrical = Piping = lnsulation for Ouctwork = Painting = Site Preparation (SP) = Buildings (Bldg) = Tot l DiEct Costs (Irc) = EnSineering = Construction and field expenses = Contractor fees = Stad_uP = Performahce test = Continenry Cost (C | = Tot l lndlEt Coits (lC) . s3,703 56,480 s1,8s1 S92G 5463 s453 so so S13,tts S6O,t57 ln 2022 dollers 94,628 S2,314 54,628 9926 s463 912,95e Catalyst Replacement Cost Annual Electricity Cost Annual Fuel costs for Natural Gas Operatin8 Labor Maintenance Costs = 1.08 x CC x Vol..r x FWF Where CC is the 5ft3 cost for the replacement catalyru Volor is the volume of catalyst required based on the waste gas flow rate (Qfr) and the catalyst space S31 velocity (O); and tWF is the future wodh factor. = Annlal Electricity UsaSe x OpeBting Hours/year x Electricity Price = 5328 = Costtu.r x Fuel UsaSe Rate x c'0 min/hr x operating hours/year 510,120 operator = 0.5hours/shift x Labor Rate x (Operating hours/8 hours/shift) Supeilisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operating Hours/8 hours/shift) Materials = 100% of malnt€nance labor sn37s s4,106 527,37s $27,375 Overhead Administrative charges Property Taxes lnsurance Capital Recovery = 60% of sum of operating, superyiror, maintenance labor and maihtehance materials = 2% of rcl = 1% of TCI = 1% ofTCl = CRFITCI-1.08(cat. cost)l ss1,739 S1,6c, s&,4 s8O4 szseo Con Effqctircrcs 3 (Iot l Annull Cort)/(Annul Qu.ntlty ot VOC/HAP Pollut rlt3 D.stroy.d) Annual Cost ITACI =255 pcr y.rr ln 2022 doll.rs O.0 tom^/urPollutants Oestroved = Effectiveness : Noter The ld.r.!pl6Dn limn {LEl), h.n d.omburrion.nd molecub. w.rght lorrome commnly G.d VG/MP.r. proei&d in rh. r.bl. blil. rn.ddnion, t6e hen olcombueilon ro be emered in colum. D 6. l@.r heni.rv.l!. ltHVl, nd, hder ne.timv.lu. (HHV). P.r..nr En..& R€dery(nh). J rnhvolud.M.no,r.re(O-J.t77"F.nd tam Moto./F.n tffi.rc.0 (.1 ln let W$t. G- I.mp.r.r!r. (TNJ OF.ding Lmo.,ilure lTrJ Das(dion.nd R.m@.1 Effi.ienq {0Rt) €srimar.dtquDmed Lile Enim.r.dc.r.hr |il. (v) Sra.e velo(ly lo. 6l.tir (Ol N.tur.l G.r r!.1 CGI (cc!-J M.inten.nce Labo. ,ate 'c€Po r6.chmrdr.^amnqtunrcdr.s6.@.or.rE'd .krilron butBhrcrrtEre *I*^*n.6rid.rsl.3 u&slRr.epEbl.. f,rrddfrturc.., .6ldhMkdw .b.mnk4frut hrdr^k hs!/ffi dlp/.r.6kiv/.nur^ilr.r-02-r hhu ffiH&bddF.r Brhdffitu ffi&-b&tu!lgns.'^& Erhtffiffi. is,/*w.bh F/-rur.nvE'-il,.h,il) sounvaB b ndnLr..uimd rE r.u 1.418) (ylene :thylbenzene NI NI N/ N/ N/ NI N/ N/ N/ N/ Constants used in 6lculations: Temperature of auxiliary fuel (T") = Density of auxiliary Fuel at 77'F (p", = Heat lnput of auxiliary fuel (-Ah.ar) = Density ofwaste Bas at 77'F (p*,) = Mean Heat capacity of Air (C.-.r,) = Reference Temperature (T,d) = (For catalytic oxidizers) 77.O "F O.O4O8 lbft3 21,502 Btu/lb 0.0739 tb/ft3 0.248 Btu/lb'F % LEL^,, Dilution Factor Lower Explosive Limit (LEL) of waste gas after addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of gas stream Fan Power Consumption (FP) a*" Operating temperature of oxidizer (TrJ Temperature of waste gas at outlet to preheater (T*.) Temperature of flue gas exiting the oxidizer (Tr") Heat lnput of waste gas (-Ah.*J Estimated Auxiliary Fuel Flow (Q", at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% ofTotal Energy lnput, then the auxilary fuel is sufficient.) Sum of volume fraction of combustible components = Lower Explosive Limat of waste gas (LEL*,) Auxiliaryfuelflow{Qaf) at77'Fand 1atm. = Total Volumetric Throughput (qor) at 77 'F and 1 atm. Volumetric Flow Rate at 50'F and 1 atm (Oft) Catalyst Volume (Vol."r) Estimated inlet temperature to the catalyst bed (T,,) = C.pltal Rscmry Factor: = (:x,) = = [((x,)/((Ix,) x rr!))] 1= Where x, is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. = (Total Combustible Conc. ln Mixture/LEl-i,) x 100 = = (LEL." x 0.249)/(:x,) = = (Total Adjusted Conc. With Dilution Air/LEl-,,) x 1OO = (From Data Entry Tab) = = 1oo - (:xr x 100/106) = = [(1.17 x 10 4) x Q*, x AP]/€ (From Data Entry Tab) = Heat Recovery x (Tri - T*J + T*i= =Tr,-T*"+T*,= = : (-4h.,) x, Where (-Ah.,) is the heat of combustion and \ the fraction of component "i" at 77 'F {Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) =5yoxlotal Ene.gy lnput = 0.05 x pr x Qr x Cp.r x (Tr - T,"r) = (Note: lf the = qr = O*.+ q" + Q"r= O{,+ qr= 0 ppmv 8,748 ppmv 0.00 percent Not applicable Not Applicable 100 scfm 20.90 percent 0.4 kw 100 sctm 900 "F 650 'F 340 "F 0.00 Btu/scf 0.58 scfm 597 Btu/min 78 Btu/min Yes 1 sqfm 101 scfm 97 scfm 0.19 ft3 900'F Cakulation of CrtalFt Volumc and Estlmated Tempaature of W6t Gas Entedq the Cfrlyst Bd = qo, x (s19)/(77 'F + 460) = Where Ofl is the volumetric flow rate of the waste gas (qJ corrected to 60 'F and 1 {Calculated using Equation 2.28 in Chapter 2 of the Cost Manual) Capital Recovery Factor (CRF) =i (1+ i)"/{1+ i)" - 1 = Future Worth Factor Life and i= lnterest Rate Future Worth Fastor (FWF) = I [r(1+ i]v - 1l =l'ffiWharc v = Catalvst Ufc and i= lntecst Rat. lncinerator + auxiliary equipment'(A) = Equipment Costs (EC) for Fluid Bed catalytic Oxidizer lnstrumentationb = Salet taxes = FreiSht = Foundations and Supports = Handling and Eredion = Eledri@l = Piping = lnsulation for Ductwork = Painting = Site Preparation (SP) = Buildings (Bldg) = fobl Dlcd CorB (trc)= €nSineering = Construction and field exp€nses = Contractor fees = Sta rt-u p = Performance test = = ({8.39 x 10,000) + (19.2 x Qtot)) x (2022 cEPl/1999 CEPCI) 0.10tA= 0.03xA= 0.05xA= Dhxr htt.ll.dil co.t3 0n 2022 doLc) 0.08x8= 0.14 x B= 0.04x8= 0.02xB= 0.01x8= 0.01x8= S182,346 in 2022 dolhrs $rE 23s s5,470 ss,u7 3215,16r in 2022 dolhETot l Purch.ed Gquhmcnt @ste (B). Fo.dlobr i . - Ardh.y .qsipmnt lndud.s aqrlprent (..i,, duct mll) mmlly no{ lnctrdld ulti unft fumls}iod by Inanmtr rcndq. b - lrchd.e th€ in tnrmnt tlon ard @ntrclr fumlsh.d by lh! lmlmntor Endor. B+C+SP+BH3= Totd tndlrct tnn+lnbn cod! (ln 2022 &lh.l 0.10x8= 0.05x8= O.10xB= 0.02x8= 0.01x B = fotal DlEt lntt.lLtoo Cost = ToLl lndircct Oosts (lcl = 5t7,213 530,124 58,607 s4,303 s2,rs2 52,152 so so S64,sso S279,71t tn 2022 dollars s27,Sr7 slq7s8 s21,s17 s4,303 s2,rs2 $@,247 s33,997Continency Cost (C Catalyst Replacement Cost Annual Electricity Cost Annual Fuel Costs for Natural Ga! Operating Lebor Maintenance Costs = 1.08 x CC x Voloi x FWF where cc is the S/ftr cost for the replacement 6talyst; Vol..r is the volume of catalyst required based on the waste gas flow rate (O{) and the catalYst space velocity (O); and FWF is the future worth fador. = Ahnual Electricity Usage x OpeEting Hours/year x Electricity Price = = costtod x Fuel Usage Rate x 60 min/hr x operating hours/year Operator = 0.5hourtshift x Labor Rate x (Operating hours/8 hours/shift) Superuisor = 15% ofOperator Labor = 0.5 hours/shift x Labor Rate x (Operating Houtr/8 hours/shift) Materials = 10O% of maihtenance labor 93r s328 slq120 527,37s S4,106 527,?75 s27,37s overhead Administr.tive Charges Property Taxes Capital Recovery = 60% of sum of operatlng, supervisor, maintenance labor and maintenance materials = 2% of rcl = 1% ofTCl = 1% ofTCl = CRFITCI-1.08(cat. Cost)l ss1,739 57Ale 53,710 s3,740 s35,296 @ctEfi.ctlnm$=(fot lAnnu.lCdt)/(AnnrlQurntityofVOC/HAPPollui.ntsDcstroyad) Annual Cost (TAC) .pcr y!!r ln Pollutants Destroyed =0.0 tons/yclt ton of ErcEd in 2022 1t Nore: Tne ltu.,.rpl6io. lhil (tEL), he, or combGlion and mol..ula.wel8ht ro. rome commonly usd vx/uP.r. provid.d in rhe t.bl. &le. rn.ddilio., rhe he.r ofcombustion to be entered in (ol!m. D ir. ld.r he.tina v.lo€ (LHv),.d a hBh.r h..ri4v.l!. (ffHV). t_@ Number ot oFr{rna hour/y..r lnld volumettno*r.r.lqJ il77oFa.d I {m Motoy'r.n t6.i.n.y (rl I nld warl. Ga l.mp.r.lue trrJ oFrdi.S Iemper.iure (T,J D6rrudron.nd Remry.l Etricienry (ofi E) Enimar.d aquipment Lr. P.ic6! tn.r& ieov€ry(Hn) =l CEPCI'fo.2022 tr.rw.l6.i Fuelc6l (46!{l} M.$ren:ncet.&r r.re Co.tinS.nq F.dorlcr) . cttcr h tu c&hior €nrm.ni. thnr con tior.il@.{or.don rd &bn6.bdBh4Dcnbidrdd.ir.bnnd.w.r{iowi.6rh rfnr^*.crid.p,1..,Ms)n..erEbr E .!.mnEbYtuus ldryhkru ts!//ffi .n.p/.kdkrn/tndrhmr.s 0, q hhD I t id6ri.r r.dnet n u6 rm q/lw.6 p/dsv/ndL/ns35usah6. ffi@)-.&d€np.!h& tqr'h-@. 's//ffi u p/o*(nnv43_Dthh). tudy rnr b 6.sr .rd kuFdo.rEapBil.r:' ,s!/lwbB.F/4r.ur.nva! ilr.hh) Hdiy,.$ rs (ylene :thylbenzene N/ N/ N/ N/ N/ N/ N/ N/ Ni Constants used in @lculations: Temperature of auxiliary fuel (T"i) = Density of auxiliary Fuel at 77 'F (pa,) = Heat lnput of auxiliary fuel (-Ah."r) = Density of waste gas at 77 "F (p*J = Mean Heat Capacity of Air (C.-.,,) Reference Temperature (T.e, = {For thermal oxidizers) 77.0 "F 0.0408 lbft3 21,502 Btu/lb 0.0739 tblft3 0.255 Btu/lb'F Sum of volume fraction of combustible components : Lower Explosive Limit of waste gas (LEL-,,) =(:x)= = t:{(x])/((:x,) x LELj))l I = Where x) is the volume fraction and LEI the lower explosive limit for each combustible component in the waste gas. : (Total Combustible Conc. ln Mixture/LEl-i,) x 100 = = (tEL.r, x 0.2a9)/(:xt) = : (Total Adjusted Conc. With Dilution Air/LEl-r) x 100 = (From Data Entry Tab) = = 1oo - (:xr x 100/106) = = [(1.17 x 10.4) x Q*,x AP]/€ " Q*i= (From Data Entry Tab) = Heat Recovery x (Ty] - T*) + T*,= =Tii-Two+Tw = = : (-ah.,) x, Where (-Ah.J is the heat of combustion and x, the fraction of component "i" at 77 't (Calculated using Equation 2.21 in Chapter 2 of the Cost Manual) = 5% x Total Energy lnput = 0.05 x pri x Qri x Cemri x {Tri - T,d) = {Note: lf the % LEL.,, Dilution Factor Lower Explosive Limit (LEL) of waste gas atter addition of dilution air lnlet volumetric flow rate(Qwi) at 77'F and 1 atm. Oxygen Content of 8as stream Fan Power Consumption (FP) a*" Operating temperature of oxidizer (Tr,) Temperature of waste gas at outlet to preheater (T*.) Temperature of flue gas exiting the oxidizer (Tt.) Heat lnput of waste gas (-Att*,) Estimated Auxiliary Fuel Flow (Q", at 77'F and 1 atm. Auxiliary fuel Energy lnput = Minimum Energy required for combustion stabilization = ls the calculated auxiliary fuel sufficient to stabilize combustion? auxiliary fuel energy input > 5% ofTotal Energy lnput, then the auxilary fuel is sufficient.) Auxiliary fuel flow (Qaf) at 77'F and 1 atm. = Total Volumetric Throughput (q.r) at 77 'F and 1 atm Capltal Recovery F.ctoI 0 ppmv 8,748 ppmv 0.00 percent Not applicable Not Applicable 100 scfm 20.90 percent 0.4 kw 100 sc'fm 1,500'F 1,150 'F 550 'F 0.00 Btu/scf 1.32 scfm 1,158 Btu/min 141 Btu/min Yes 1 scfm 101 scfm= Q{, = Q*"+ Q. + Q* = Q*i+ Q"r= i (1+ i)"/(1+ i)" - 1 =capital Recovery Fador (CRF) = Life end i= lnterest Rate fod nrdlu.d 2012aolLrl lncinemtor + auxiliary equipment'(A) = Equipmentcosts (Ec)forRecuperativeThermalOxidiler =(21,342xQtot(0.25))x(2022CEPll1999CEPCI) = 5143,847ln2022dolh6 tnstrumentationb= O.IOXA= S143S5 Salestaxes= 0.03xA= 54,315 FreiSht= O.O5XA= 57,192 Totrl Purchrsd cqqlpmnt 6cts (B) = S159,739 lr 2022 dolh6 f.@r . - ADdlLry.qulpmnt ldrd.5 Cqubrunt (ca., duct rcr$ mfi not lncfudld wifi unlt fi[nbh.d by lrElMtor wndor. b . lnclld.r th. lnrtrumnt tlor .rd @ntrols fumhhcd by lh. loctncnta Endq. ] Foundations and Supports = Handling and Eredion = Eledrical= Piping = lnsulation for Ductwork = Paintin8 = Site Prepar.tion (SP) = Buildings (Bldg) = Tot lDicctCotB(DC)= Engineering = construction and field expenses = Contcctor fees = Start-uP = Performane test = Dk Giln rdllbiconr(ln2o2i! doLBl 0.08x8= 0.14x8= 0.04x8= 0.02x8= 0.01x B = 0.01x B = B+CtSP+Bldg= s13,579 s2,.,761 s5,79O $3,395 sl,6e7 $1,6e7 so so 55,,922 5220,651 tn 2022 dollaB s1Oe74 s8,487 57G,974 s3,39s 91,5e7 547,527 s26,819 Tffil DlEd lBi.lhton Costi. rot.l lndlEct C$t! (lC) = Iotrl IrrllGr lnd*nabn co.tr lh 2@2 doL.rl 0.10x8= 0.05x8= 0.10x8= 0.02x8= 0.01x8= Ct(lC+DC)= Annual Eledricity Cost Annual Fuel Costs for Natural Gas OperatinS Labor Mainienance Costs = Annual Electricity Usage x Operatint Hours/year x Eledricity Price = = Costftd r Fuel Usage Rate x 60 min/hr x Operating hours/year Operator = O.5hourrshift x Labor Rate i (Operating hours/8 hours/shift) Superuisor = 15% of OpErator Labor = 0.5 houri/shift x Labor Rate x (Operatin8 Hours/8 hours/shift) Materials = 100% of maintenance labor 5271 s19,533 irt,375 Sa,106 s2?,375 527,37s Overhead Adminlstrative charSes Property Taxes Capital Recovery = 50% of sum of operetlng, superuisor, maintenance lebor and fraintenance materials = 2% ol rgl = 1% ofTCl = 1% of TCI = CRF x TCI ssl,73s stsoo 92,9s0 9aeso 927,U7 Co9t Efisctlwms I Oot l Annu.l Costl (Arnel Clu.Dtity of VOC/MP Pollutrnts Dcstrcy.d) Annual cost OAc) = 5192521 prr y..r ln 2022 dollTr Pollutants Destroyed = 0.0 toni/y4r Effectiveness = 321.351-927.524 mrbn of mllut nts nmEd ln 2022 doll.R t,TA}I DEPAHTMENT OF E}WIRO{MENTAL OIJAUTY DEC 21 2022 DIVTSION OF AIR QUAUTY DAQE-AN101520030-24 {{$d1 }} Jeff Schmidt Northrop Grumman Systems Corporation 2211 West North Temple Salt Lake City, UT 84116 j.schmidt@ngc.com Dear Mr. Schmidt: Re: Approval Order: Modification to Approval Order DAQE-AN101520028-22 to Add Equipment and Change Ownership Project Number: N101520030 The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on October 31, 2023. Northrop Grumman Systems Corporation must comply with the requirements of this AO, all applicable state requirements (R307), and Federal Standards. The project engineer for this action is Christine Bodell, who can be contacted at (385) 290-2690 or cbodell@utah.gov. Future correspondence on this AO should include the engineer's name as well as the DAQE number shown on the upper right-hand corner of this letter. No public comments were received on this action. Sincerely, {{$s }} Bryce C. Bird Director BCB:CB:jg cc: Davis County Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director January 18, 2024 STATE OF UTAH Department of Environmental Quality Division of Air Quality {{#s=Sig_es_:signer1:signature}} {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}} APPROVAL ORDER DAQE-AN101520030-24 Modification to Approval Order DAQE-AN101520028-22 to Add Equipment and Change Ownership Prepared By Christine Bodell, Engineer (385) 290-2690 cbodell@utah.gov Issued to Northrop Grumman Systems Corporation - Clearfield Freeport Center Issued On {{$d2 }} Issued By {{$s }} Bryce C. Bird Director Division of Air Quality January 18, 2024 TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 5 SECTION II: PERMITTED EQUIPMENT .............................................................................. 6 SECTION II: SPECIAL PROVISIONS ..................................................................................... 9 PERMIT HISTORY ................................................................................................................... 13 ACRONYMS ............................................................................................................................... 14 DAQE-AN101520030-24 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Northrop Grumman Systems Corporation Northrop Grumman Systems Corporation - Clearfield Freeport Center Mailing Address Physical Address 2211 West North Temple Freeport Center 13th Street Salt Lake City, UT 84116 Clearfield, UT 84016 Source Contact UTM Coordinates Name: Jeff Schmidt 414,000 m Easting Phone: (801) 774-4171 4,550,000 m Northing Email: j.schmidt@ngc.com Datum NAD83 UTM Zone 12 SIC code 3728 (Aircraft Parts & Auxiliary Equipment, NEC) SOURCE INFORMATION General Description Northrop Grumman Systems Corporation (Northrop) manufactures aerospace composite structures at their Freeport Center plant located in Clearfield, Davis County. Northrop manufactures composite components for the aerospace industry, specifically for commercial and defense contractors. General steps in the manufacturing process include the following: raw material receipt and storage, material and tool preparation, fabrication, curing, finishing, testing, and packaging and shipping. As part of these steps, Northrop uses natural gas-fired equipment including curing ovens, boilers, burners, hot rooms, autoclaves, and heated paint booths; operates dust collectors for control of various machining processes; has painting and welding operations; has various natural gas-fired and diesel-fired emergency generators; and has various laboratory and chemical mixing operations. NSR Classification Minor Modification at Minor Source Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA Davis County Airs Source Size: B Applicable Federal Standards NSPS (Part 60), A: General Provisions NSPS (Part 60), IIII: Standards of Performance for Stationary Compression Ignition Internal Combustion Engines DAQE-AN101520030-24 Page 4 NSPS (Part 60), JJJJ: Standards of Performance for Stationary Spark Ignition Internal Combustion Engines MACT (Part 63), A: General Provisions MACT (Part 63), ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines MACT (Part 63), WWWWWW: National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Plating and Polishing Operations Project Description Northrop has requested a modification to AO DAQE-AN101520028-22 to add one (1) electric oven and one (1) mandrel preparation room. Northrop has also requested a name change from "ATK Space Systems, LLC" (subsidiary of Northrop) to "Northrop Grumman Systems Corporation." The VOC and HAPs emission limitations outlined in the current AO will not be increasing as part of this modification. The new equipment will operate under existing emissions limitations. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 24245.00 Carbon Monoxide 0 16.38 Nitrogen Oxides 0 19.49 Particulate Matter - PM10 0 13.42 Particulate Matter - PM2.5 0 13.21 Sulfur Dioxide 0 0.15 Volatile Organic Compounds 0 69.00 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) 1,1,2-Trichloroethane (CAS #79005) 0 4000 2-(2-Butoxyethoxy)-Ethanol (CAS #112345) 0 4000 Chromium Compounds (CAS #CMJ500) 0 27 Cumene (CAS #98828) 0 4000 Ethyl Acrylate (CAS #140885) 0 4000 Ethyl Benzene (CAS #100414) 0 4000 Ethylene Glycol (CAS #107211) 0 4000 Formaldehyde (CAS #50000) 0 1000 Generic HAPs (CAS #GHAPS) 0 2000 Glycol Ethers (CAS #EDF109) 0 4000 Hexamethylene-1,6-Diisocyanate (CAS #822060) 0 14 Hexane (CAS #110543) 0 4000 Hydrogen Fluoride (Hydrofluoric Acid) (CAS #7664393) 0 20 Methanol (CAS #67561) 0 4000 Methyl Chloroform (1,1,1-Trichloroethane) (CAS #71556) 0 19000 DAQE-AN101520030-24 Page 5 Methyl Isobutyl Ketone (Hexone) (CAS #108101) 0 4000 Methyl Isocyanate (CAS #624839) 0 20 Methyl Methacrylate (CAS #80626) 0 200 Methylene Chloride (Dichloromethane) (CAS #75092) 0 4000 Methylene Diphenyl Diisocyanate (MDI) (CAS #101688) 0 20 Naphthalene (CAS #91203) 0 4000 Nickel Compounds (CAS #NDB000) 0 40 Phenol (CAS #108952) 0 4000 Styrene (CAS #100425) 0 200 Tetrachloroethylene (Perchloroethylene) (CAS #127184) 0 4000 Toluene (CAS #108883) 0 4000 Trichloroethylene (CAS #79016) 0 4000 Xylenes (Isomers And Mixture) (CAS #1330207) 0 4000 Change (TPY) Total (TPY) Total HAPs 0 45.27 SECTION I: GENERAL PROVISIONS I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] DAQE-AN101520030-24 Page 6 I.8 The owner/operator shall submit documentation of the status of construction or modification to the Director within 18 months from the date of this AO. This AO may become invalid if construction is not commenced within 18 months from the date of this AO or if construction is discontinued for 18 months or more. To ensure proper credit when notifying the Director, send the documentation to the Director, attn.: NSR Section. [R307-401-18] SECTION II: PERMITTED EQUIPMENT II.A THE APPROVED EQUIPMENT II.A.1 Northrop Grumman Systems Corporation Aerospace composite components manufacturing facility II.A.2 Five (5) Electric Curing Ovens Ovens: O-21; O-36; O-48 (New); O-159; O-160 Venting (all): Atmospheric II.A.3 Eleven (11) Natural Gas-Fired Ovens Oven: Rating: O-26 1.2 MMBtu/hr O-27 4.0 MMBtu/hr COV1 2.8 MMBtu/hr COV2 4.0 MMBtu/hr O-30 3.5 MMBtu/hr O-22 2.0 MMBtu/hr O-24 0.6 MMBtu/hr O-37 3.0 MMBtu/hr O-39 6.4 MMBtu/hr O-41 1.0 MMBtu/hr O-47 3.0 MMBtu/hr II.A.4 Seven (7) Hot Rooms Rooms: ACU253, AHU1, AHU2, AHU3, AHU4, HR1, HR3 Fuel (all): Natural Gas Maximum Rating: < 5.0 MMBtu/hr (each) II.A.5 One (1) Boiler- BO1 Fuel: Natural Gas Rating: 8.37 MMBtu/hr II.A.6 Three (3) Autoclaves Autoclave: Rating: AC1 12.0 MMBtu/hr AC6 24.3 MMBtu/hr AC12 15.0 MMBtu/hr Fuel (all): Natural Gas DAQE-AN101520030-24 Page 7 II.A.7 Five (5) Autoclaves Autoclaves: CAC1, CAC2, CAC3, CAC4, CAC5 Fuel (all): Natural Gas Rating: 15.8 MMBtu/hr (each) II.A.8 Twelve (12) Ventilation Rooms Ten (10) Mandrel Prep Rooms (1 NEW); FX-141; Paint Touchup Room II.A.9 Eleven (11) Laboratory Hoods FUH-3; FUH-7; AT-401073; FUH-5; FUH-2; AT-401706; FE-200; FE-222; FUH-1; SB-2; 2228 II.A.10 Thirteen (13) Exhaust Hoods 1,2. Two (2) Welding fume exhausters 3. RMS-6 4. Battery Charging area exhaust hood 5. MX-85 6. M-5 7. 83310J00475 8. E-145 Tacking Table 9. FX-105 10. FX-106 11. FE-655 12, 13. Two (2) Paint mixing fume hoods II.A.11 Four (4) Heated Paint Booths Paint Booth: Heater Rating: SB10 750 KBtu/hr SB11 950 KBtu/hr SB12 950 KBtu/hr SB13 950 KBtu/hr Fuel (all): Natural Gas Control: Vacuum System (each) II.A.12 Six (6) Spray Booths SB7, SB9, SB5, SB14, IFE SB, Topcoat SB Control: Fabric Filters (each) II.A.13 One (1) Ceramics Spray Booth Control: High efficiency 3-stage fabric filters II.A.14 One (1) Thermal Spray Booth Control: Pulse jet baghouse (DC-58) Baghouse Maximum Flow Rate: 25,300 acfm MACT Applicability: Subpart WWWWWW DAQE-AN101520030-24 Page 8 II.A.15 Eight (8) Natural Gas-Fired Emergency Generators Engine: Rating: GE 3 7 kW GE 4 35 kW GE 5 100 kW GE 8 80 kW GE 9 240 kW GE 10 45 kW GE 11 45 kW GE 12 85 kW NSPS Applicability: Subpart JJJJ MACT Applicability: Subpart ZZZZ II.A.16 Two (2) Diesel-Fired Emergency Generators Engine: GE 7 Rating: 225 kW Engine: GE 13 Rating: 268 hp NSPS Applicability: Subpart IIII MACT Applicability: Subpart ZZZZ II.A.17 Eight (8) Dust Collectors DC-16, DC-27, DC-28, DC-29, DC-30, DC-36, DC-37, DC-38 II.A.18 Miscellaneous Equipment Miscellaneous vacuum pumps Miscellaneous Air compressors II.A.19 Miscellaneous Combustion Equipment Various Boilers and Heaters Maximum Rating: <5.0 MMBtu/hr Fuel: Natural Gas II.A.20 Eighteen (18) Wet Cooling Towers CT-6, CT-7, CT-9, CT-13, CT-14, CT-15, CT-16, CT-17, CT-18, CT-19, CT-20, CT-21, CT-22, CT-23, CT-24, CT-25, CT-26, CT-27 Controls: High Efficiency Drift Eliminators (each) II.A.21 Informational-Only Equipment* Nineteen (19) electrical sample curing ovens One (1) electrical Hot room Eight (8) electrical autoclaves One (1) Buffer room Miscellaneous Dust Collectors, including portable and orifice scrubbers Miscellaneous Machining Centers / Lathes / Cork Cutting Equipment One (1) Spray Gun Cleaning Station Miscellaneous Grit Blast and Abrading Equipment 3D Printers *This equipment does not vent to atmosphere and is listed for informational purposes only DAQE-AN101520030-24 Page 9 II.A.22 Informational-Only Equipment* (Continued) Three (3) Hot Drape Forming Machines One (1) Ductless Fume Hood Two (2) Reticulators Two (2) Dry Cooling Towers *This equipment does not vent to atmosphere and is listed for informational purposes only II.A.23 Grandfathered Equipment* Pit exhaust system Indirect gas fired curing oven - #20 Rating: 6 MMBtu/hr *This equipment was installed before 1969 and is listed for informational purposes only SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS II.B.1 Site-Wide Requirements II.B.1.a The owner/operator shall not allow visible emissions from the following emission points to exceed the following values: A. Diesel-fired emergency engines - 20% opacity B. All other emission points - 10% opacity. [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40 CFR 60, Appendix A, Method 9. [R307-401-8] II.B.1.b The owner/operator shall not exceed a plant-wide natural gas consumption limit of 406,624 Decatherms per rolling 12-month period. [R307-401-8] II.B.1.b.1 The owner/operator shall: A. Determine consumption by gas billing records B. Record consumption on a monthly basis C. Use the consumption records to calculate a new rolling 12-month total by the 20th day of each month using data from the previous 12 months D. Keep consumption records for all periods the plant is in operation. [R307-401-8] II.B.1.c The owner/operator shall comply with all applicable requirements of UAC R307-325 (Ozone Nonattainment and Maintenance Areas: General Requirements) and UAC R307-355 (Control of Emissions from Aerospace Manufacture and Rework Facilities), [R307-355] DAQE-AN101520030-24 Page 10 II.B.2 VOC & HAP Requirements II.B.2.a The owner/operator shall not emit more than the following from all sources on site: A. 69.00 tons per rolling 12-month period of VOCs B. 19.00 tons per rolling 12-month period of all HAPs combined C. 2.00 tons per rolling 12-month period of 2-Butoxyethanol D. 0.014 tons per rolling 12-month period of Chromium Compounds E. 2.00 tons per rolling 12-month period of Cumene F. 2.00 tons per rolling 12-month period of Ethyl Acrylate G. 2.00 tons per rolling 12-month period of Ethylbenzene H. 2.00 tons per rolling 12-month period of Ethylene Glycol I. 0.50 tons per rolling 12-month period of Formaldehyde J. 1.20 tons per rolling 12-month period of Generic HAPs K. 2.00 tons per rolling 12-month period of Glycol Ethers L. 0.007 tons per rolling 12-month period of Hexamethylene-1,6-Diisocyanate M. 2.00 tons per rolling 12-month period of Hexane N. 0.010 tons per rolling 12-month period of Hydrogen Fluoride O. 2.00 tons per rolling 12-month period of Methyl Alcohol P. 0.010 tons per rolling 12-month period of Methyl Isocyanate Q. 2.00 tons per rolling 12-month period of Methylene Chloride R. 0.10 tons per rolling 12-month period of Methylenedianiline S. 0.010 tons per rolling 12-month period of Methylene Diphenyl Diisocyanate T. 2.00 tons per rolling 12-month period of Methyl Isobutyl Ketone (MIBK) U. 2.00 tons per rolling 12-month period of Naphthalene. DAQE-AN101520030-24 Page 11 II.B.2.a The owner/operator shall not emit more than the following from all sources on site continued: V. 0.02 tons per rolling 12-month period of Nickel Compounds W. 2.00 tons per rolling 12-month period of Phenol X. 2.00 tons per rolling 12-month period of Tetrachloroethylene Y. 2.00 tons per rolling 12-month period of Toluene Z. 9.50 tons per rolling 12-month period of 1,1,1-Trichloroethane AA. 2.00 tons per rolling 12-month period of 1,1,2-Trichloroethane BB. 2.00 tons per rolling 12-month period of Trichloroethylene CC. 2.00 tons per rolling 12-month period of Xylene. [R307-401-8] II.B.2.a.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAP = [% HAP by Weight/100] x [Density] x [Volume Consumed] [R307-401-8] II.B.2.a.2 The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] II.B.2.a.3 The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and each HAP in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs and the amount of each HAP emitted from each material F. The amount of VOCs and the amount of each HAP reclaimed and/or controlled from each material G. The total amount of VOCs, the total amount of each HAP, and the total amount of all HAPs combined emitted from all materials (in tons). [R307-401-8] DAQE-AN101520030-24 Page 12 II.B.3 Paint Booth Requirements II.B.3.a The owner/operator shall equip each paint booth with paint arrestor particulate filters to control particulate emissions. All exhaust air from the paint booths shall be routed through the filters before venting to the atmosphere. [R307-401-8] II.B.3.b The paint booths shall be equipped with HVLP spray guns, or an equivalent method, to control VOC emissions. [R307-355-6] II.B.3.c The owner/operator shall control the thermal spray booth with a baghouse. [R307-401-8] II.B.3.d The owner/operator shall install a manometer or magnehelic pressure gauge to measure the differential pressure across the baghouse. The baghouse shall operate within the static pressure range recommended by the manufacturer for normal operations. [R307-401-8] II.B.3.d.1 Pressure drop readings shall be recorded at least once during each day of operation while the baghouse is operating. Records documenting the pressure drop shall be kept in a log and shall include the following: A. Unit identification B. Manufacturer-recommended pressure drop for the unit C. Daily pressure drop readings D. Date of reading. [R307-401-8] II.B.3.d.2 Each pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.d.3 The instrument shall be calibrated in accordance with the manufacturer's instructions or recommendations or replaced at least once every 12 months. Documentation of calibrations and replacements shall be maintained. [R307-401-8] II.B.4 Emergency Engine Requirements II.B.4.a The owner/operator shall not operate each emergency engine on site for more than 100 hours per calendar year during non-emergency situations. There is no time limit on the use of the engines during emergencies. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.4.a.1 To determine compliance with a calendar year total, the owner/operator shall calculate a new yearly total by January 31st using data from the previous calendar year. Records documenting the operation of each emergency engine shall be kept in a log and shall include the following: A. The date the emergency engine was used B. The duration of operation in hours C. The reason for the emergency engine usage. [40 CFR 63 Subpart ZZZZ, R307-401-8] II.B.4.a.2 To determine the duration of operation, the owner/operator shall install a non-resettable hour meter for each emergency engine. [40 CFR 63 Subpart ZZZZ, R307-401-8] DAQE-AN101520030-24 Page 13 II.B.5 Fuel Requirements II.B.5.a The owner/operator shall use only natural gas as a fuel in all fuel-burning furnaces, ovens, boilers, heaters, and natural gas-fired emergency engines. [R307-401-8] II.B.5.b The owner/operator shall only use diesel fuel (fuel oil #1, #2 or diesel fuel oil additives) in the diesel-fired emergency engines. All diesel burned shall meet the definition of ultra-low sulfur diesel (ULSD) and contain no more than 15 ppm sulfur. [R307-401-8] II.B.5.b.1 To demonstrate compliance with the diesel fuel requirements for any diesel fuel purchased, the owner/operator shall keep and maintain fuel purchase invoices. The fuel purchase invoices shall indicate that the diesel fuel meets the ULSD requirements, or the owner/operator shall obtain certification of sulfur content from the fuel supplier. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN101520028-22 dated September 26, 2022 Is Derived From NOI dated December 21, 2022 Incorporates Additional Information dated October 26, 2023 DAQE-AN101520030-24 Page 14 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds