Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
DAQ-2024-007777
1 DAQC-354-24 CAERS ID 100441 (B4) MEMORANDUM TO: STACK TEST FILE – JAVELIN ENERGY LLC – Flying Dutchman 1-13C5 MWF – Duchesne County, UT THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Kyle Greenberg, Environmental Scientist DATE: April 19, 2024 SUBJECT: Sources: One (1) Cummins KTA19GC Engine; SN: 37254961 Contact: Brian Shpakoff: 682-209-2074 Location: Remote location in Duchesne County, UT Test Contractor: Oasis Emissions Consultants Permit/AO#: 40 CFR 60, Subpart JJJJ: UAC R307-510 Action Code: TR Subject: Review of Stack Test Report dated February 12, 2024 On February 22, 2024, DAQ received a test report for the above listed unit. Testing was performed February 5, 2024, to demonstrate compliance with the emission limits found in UAC R307-510 and 40 CFR Part 60, Subpart JJJJ. The calculated test results are: Source Test Date Test Method Pollutant Tester Results DAQ Results Limits Cummins KTA19GC SN: 37254961 Feb. 5, 2024 320 NOx 0.01 g/hp-hr 0.008 g/hp-hr 1.729 ppmvd at 15% O2 1.00 g/hp-hr 160 ppmvd at 15% O2 320 CO 0.06 g/hp-hr 0.060 g/hp-hr 22.276 ppmvd at 15% O2 2.0 g/hp-hr 270 ppmvd at 15% O2 320 VOC 0.01 g/hp-hr 0.011 g/hp-hr 2.572 ppmvd at 15% O2 0.7 g/hp-hr 60 ppmvd at 15% O2 DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from the one (1) Cummins KTA19GC engine should be considered to have been in compliance with the emission limits of UAC R307-510 and 40 CFR Part 60 Subpart JJJJ, during the time of testing. ATTACHMENTS: DAQ stack test review Excel Spreadsheets; Javelin Energy Test Report. Emissions Javelin Energy LLC Flying Dutchman 1-13C5 MWF; Site ID: 100441 Duchesne County, Utah Cummins KTA19GC; SN: 37254961 Test Date: 2/5/2024 Run #1 2 3 Average Start Time 14:07 15:08 16:09 Stop Time 15:07 16:08 17:09 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 380 380 380 380 DS Stack Diameter (inches)5.0 5.0 5.0 5.0 PAVG Average (Delta P)½ (" H2O)½0.7450 0.7460 0.7500 0.7470 CP Pitot Tube Constant (unitless)0.84 0.84 0.84 0.84 TS Stack Temperature (°F)1150 1150 1150 1150 Pbar Barometric Pressure (" Hg)24.17 24.17 24.17 24.17 Ps Stack Pressure ('' H2O)0.12 0.13 0.13 0.13 O2%vd O2 (%vd)0.0 0.0 0.0 0.0 CO2%vd CO2 (%vd)11.8 11.8 11.8 11.8 N2%vd N2 (%vd)88.2 88.2 88.2 88.2 dry NOX (ppmvd)6.2 5.9 6.4 6.1 dry CO (ppmvd) 72.5 82.7 81.6 78.9 wet NMNEOC (ppmvw as C3H8)7.4 7.4 7.5 7.4 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.189 0.189 0.187 0.188 Bws Saturated Moisture Content (%/100)1636.376 1636.326 1636.326 1636.343 Bws Actual Moisture Content (%/100)0.189 0.189 0.187 0.188 MD Molecular Weight Dry (lb/lb-mole)29.89 29.89 29.89 29.89 MA Molecular Weight Wet (lb/lb-mole)27.64 27.65 27.67 27.65 VS Gas Velocity (ft/sec)83.0 83.1 83.5 83.2 FACFM Gas Flow (acfm)679 680 683 681 FDSCFM Gas Flow (dscfm)146 146 147 146 FWSCFM Gas Flow (wscfm)180 180 181 180 FKWSCFH Gas Flow (kwscfh)11 11 11 11 FKWSCFM Gas Flow (kwscfm)0 0 0 0 lb/hr Gas Flow (lb/hr) 775 776 781 777 Fo Fo (unitless)1.771 1.771 1.771 1.771 wet O2 (%vw)0.000 0.000 0.000 0.000 wet CO2 (%vw)9.567 9.575 9.599 9.580 wet NOX (ppmvw)4.986 4.763 5.166 4.972 15 NOX (ppmvd @ 15% O2)1.736 1.657 1.793 1.729 160.0 lb/hr NOX (lb/hr)0.006 0.006 0.007 0.006 g/bhp-hr NOX (g/bhp-hr)0.008 0.007 0.008 0.008 1.0 wet CO (ppmvw) 58.751 67.095 66.365 64.070 15 CO (ppmvd @ 15% O2)20.455 23.343 23.030 22.276 270.0 lb/hr CO (lb/hr) 0.046 0.053 0.052 0.050 g/bhp-hr CO (g/bhp-hr) 0.055 0.063 0.063 0.060 2.0 dry NMEOC (ppmvd as C3H8)9.110 9.060 9.160 9.110 15 NMEOC (ppmvd as C3H8 @ 15% O2)2.572 2.558 2.586 2.572 60 lb/hr NMEOC (lb/hr as C3H8)0.009 0.009 0.009 0.009 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.011 0.011 0.011 0.011 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 Source Test Report For Javelin Energy Partners Flying Dutchman 18-17-C4 Utah Test Date: February 5, 2024 Report Date: February 12, 2024 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Cummins KTA19GC SN: 37254961 Unit ID: 6318 (100441) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 February 12, 2024 Mr. Brian Shpakoff Javelin Energy Partners Dear Mr. Shpakoff: Re: Engine Emission Testing For Javelin Energy Partners, Flying Dutchman 18-17- C4, Unit 6318 (100441), Federal Regulation: EPA 40 CFR 60, Subpart JJJJ. An air emissions test program was conducted on a Cummins KTA19GC engine, operated by Javelin Energy Partners and designated as Unit 6318 (100441), located at the Flying Dutchman 18-17-C4 in Utah. The purpose of the testing was to demonstrate initial compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on February 5, 2024. Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.01 1.0 0.06 2.0 0.01 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 1133 8.0 Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 380 380.0 100.0 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: Javelin Energy Partners Owner/Operator Contact: Brian Shpakoff Facility Name: Flying Dutchman 18-17-C4 Latitude: 40.217278 Longitude: -110.393122 Utah Emission Source: Cummins KTA19GC Unit 6318 (100441) Date of Test: February 5, 2024 Date of Report: February 12, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters............................................................................................................... 7 5.1 Quality Assurance ................................................................................................................ 8 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................ 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Example Calculations and Summary APPENDIX D: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Cummins KTA19GC engine, operated by Javelin Energy Partners and designated as Unit 6318 (100441), located at the Flying Dutchman 18-17-C4 in Utah. The purpose of the testing was to demonstrate initial compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non-methane, non-ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is currently located in Utah. Three one hour test runs were performed on February 5, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Each one hour test run consisted of 60 readings taken at one minute intervals. The engine load was approximated at the site rated load as there was insufficient information available from the manufacturer to determine an engine load. The following key personnel were present during testing: David Martinez, OEC 2 2.1 Stack Sampling Location The facility is currently located in Utah. Testing was conducted on the Cummins KTA19GC engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 1.8 pipe diameters (9”) downstream from the nearest flow disturbance (Distance B) and 7.4 pipe diameters (37”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 12 traverse insertion depths (6 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location 5" A B 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on February 5, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate initial compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Cummins KTA19GC, NOx, CO and VOC The first test was performed from 14:07 to 15:06 for NOx, CO and VOC. Based on the site rated load of 380.0 bhp, and the average NOx and CO levels were found to be 0.01 g/bhp-hr and 0.06 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp-hr, which tested in compliance. 3.1.2 Source Test 2: Cummins KTA19GC, NOx, CO and VOC The second test was performed from 15:08 to 16:07 for NOx, CO and VOC. Based on the site rated load of 380.0 bhp, and the average NOx and CO levels were found to be 0.01 g/bhp-hr and 0.06 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp-hr, which tested in compliance. 3.1.3 Source Test 3: Cummins KTA19GC, NOx, CO and VOC The third test was performed from 16:09 to 17:08 for NOx, CO and VOC. Based on the site rated load of 380.0 bhp, and the average NOx and CO levels were found to be 0.01 g/bhp-hr and 0.06 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp-hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 1 6.15 0.01 72.46 0.06 9.11 0.01 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 2 5.87 0.01 82.69 0.06 9.06 0.01 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 3 6.35 0.01 81.58 0.06 9.16 0.01 0.0 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 8 February 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters The engine load was approximated at the site rated load as there was insufficient information available from the manufacturer to determine an engine load. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 70.2%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 6.648648 -0.04536 6.603288 41.335795 8.341165 19.386362 14:07:20 02/05/2024 2 8.332376 0.290887 8.623263 42.262515 8.339521 20.75271 14:08:20 02/05/2024 3 4.876028 0.255271 5.131299 65.810824 9.079533 19.033237 14:09:20 02/05/2024 4 5.252724 0.208909 5.461633 35.231163 8.539804 19.442662 14:10:20 02/05/2024 5 4.888838 0.222012 5.11085 37.795032 8.521605 19.086023 14:11:20 02/05/2024 6 5.799387 0.212653 6.01204 39.287965 9.989824 21.747921 14:12:20 02/05/2024 7 4.581965 0.199542 4.781507 75.163186 9.002774 18.839206 14:13:20 02/05/2024 8 5.141687 0.239448 5.381135 57.558937 10.192479 19.334221 14:14:20 02/05/2024 9 6.228189 0.181701 6.40989 67.260686 9.130942 20.005862 14:15:21 02/05/2024 10 9.053526 0.05643 9.109956 85.632905 8.99097 18.831288 14:16:20 02/05/2024 11 4.633434 0.217564 4.850998 107.542418 9.365898 18.452776 14:17:20 02/05/2024 12 7.449518 -0.006474 7.443044 96.798408 10.380744 18.386773 14:18:21 02/05/2024 13 9.195252 0.086858 9.28211 109.050372 9.141203 18.543663 14:19:21 02/05/2024 14 6.777937 0.039381 6.817318 92.865604 9.366209 18.654675 14:20:21 02/05/2024 15 6.762241 0.207049 6.96929 108.711799 10.460369 18.990595 14:21:21 02/05/2024 16 7.698475 0.215289 7.913764 82.65349 8.02275 19.013002 14:22:21 02/05/2024 17 5.966018 0.137202 6.10322 97.573898 8.497813 18.78312 14:23:21 02/05/2024 18 6.895454 0.267583 7.163037 88.55891 7.479916 18.991257 14:24:21 02/05/2024 19 5.392764 0.065955 5.458719 70.085697 10.263177 18.670874 14:25:21 02/05/2024 20 4.610728 0.267092 4.87782 63.173033 8.594215 20.12548 14:26:22 02/05/2024 21 5.028303 0.093434 5.121737 60.617795 9.374361 18.716266 14:27:21 02/05/2024 22 4.720929 0.101116 4.822045 82.065416 9.86395 18.513649 14:28:22 02/05/2024 23 5.471944 0.097206 5.56915 74.697578 8.511716 18.459501 14:29:22 02/05/2024 24 5.679616 0.097573 5.777189 72.975148 8.198453 18.599519 14:30:22 02/05/2024 25 5.793401 0.25257 6.045971 67.389664 8.993402 18.912035 14:31:22 02/05/2024 26 6.684288 0.169667 6.853955 80.565773 8.271996 18.539713 14:32:22 02/05/2024 27 5.27329 0.227424 5.500714 64.098083 9.74436 18.8238 14:33:22 02/05/2024 28 6.110777 0.315792 6.426569 56.405749 8.268334 18.940024 14:34:22 02/05/2024 29 5.21377 0.220605 5.434375 81.696109 9.381166 18.955129 14:35:22 02/05/2024 30 7.227579 0.25417 7.481749 83.298007 9.523296 18.930839 14:36:22 02/05/2024 31 5.717073 0.106879 5.823952 86.511244 8.274048 18.543784 14:37:22 02/05/2024 32 5.914351 0.180731 6.095082 76.067692 9.525098 18.765479 14:38:22 02/05/2024 33 5.693024 0.119813 5.812837 51.491158 9.912413 18.590481 14:39:22 02/05/2024 34 5.977081 0.127708 6.104789 52.257246 9.465701 18.615598 14:40:23 02/05/2024 35 5.271494 0.163737 5.435231 65.908227 9.077101 18.632445 14:41:23 02/05/2024 36 5.380441 0.184596 5.565037 75.976186 10.235926 18.302998 14:42:23 02/05/2024 37 6.592669 0.08437 6.677039 67.658567 9.44149 18.432361 14:43:23 02/05/2024 38 5.216416 0.096919 5.313335 78.987258 9.684554 18.314377 14:44:23 02/05/2024 39 6.2954 0.016537 6.311937 73.004674 10.395152 17.98953 14:45:23 02/05/2024 40 5.213602 0.073828 5.28743 65.083259 9.114751 18.514565 14:46:23 02/05/2024 41 4.925935 0.079757 5.005692 65.510862 10.612326 17.915899 14:47:23 02/05/2024 42 6.134985 0.152491 6.287476 106.976292 10.031019 18.827099 14:48:23 02/05/2024 43 5.256886 0.136458 5.393344 101.051583 9.799418 18.426735 14:49:23 02/05/2024 44 5.289917 0.166861 5.456778 78.817823 10.715542 18.245737 14:50:24 02/05/2024 45 7.299701 0.175726 7.475427 95.532843 8.227207 19.271847 14:51:24 02/05/2024 46 8.221723 0.206086 8.427809 81.517544 8.622059 18.526541 14:52:24 02/05/2024 47 6.00437 0.170663 6.175033 55.384611 8.697849 18.821809 14:53:24 02/05/2024 48 5.1951 0.33746 5.53256 61.999258 8.719464 18.678027 14:54:24 02/05/2024 49 6.304194 0.104539 6.408733 84.261113 8.855153 18.666563 14:55:24 02/05/2024 50 5.221748 0.097271 5.319019 53.562314 7.778003 18.92438 14:56:24 02/05/2024 51 6.220856 0.229839 6.450695 55.283597 8.329649 19.291968 14:57:24 02/05/2024 52 5.872998 0.092207 5.965205 80.870877 9.412285 19.303751 14:58:25 02/05/2024 53 5.404388 0.033909 5.438297 62.89754 7.707882 19.079223 14:59:25 02/05/2024 54 7.370161 0.099684 7.469845 71.528623 9.372959 18.997998 15:00:25 02/05/2024 55 5.677568 0.088026 5.765594 60.73248 8.909368 19.312603 15:01:25 02/05/2024 56 4.996031 0.192145 5.188176 56.943522 9.69806 19.562613 15:02:25 02/05/2024 57 5.330557 0.26295 5.593507 45.223102 8.641061 19.365386 15:03:25 02/05/2024 58 5.421171 0.200503 5.621674 73.377431 8.123529 19.133077 15:04:25 02/05/2024 59 5.90657 0.210824 6.117394 82.30277 8.135357 19.03861 15:05:25 02/05/2024 60 6.635559 0.052894 6.688453 92.941946 9.385709 18.924944 15:06:25 02/05/2024 AVG 5.99 0.16 6.15 72.46 9.11 18.92 ppm@15% O2 1.73 20.46 2.57 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.01 0.01 0.06 0.05 0.01 0.01 6318 (100441) FTIR Measurements Calculated Emission Levels Javelin Energy Partners Flying Dutchman 18-17-C4 Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 5 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 12 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.52 1610 0.12 0.721 Average O2 0.0 (% dry)A 2 0.73 0.53 0.728 Average CO2 11.8 (% dry)A 3 1.48 0.55 0.742 Average N2 + CO 88.2 (% dry)A 4 3.52 0.59 0.768 Dry Molecular Weight 29.89 lb/lbmol A 5 4.27 0.56 0.748 Wet Molecular Weight 27.64 lb/lbmol A 6 4.50 0.55 0.742 EPA REFERENCE METHOD 320 A 7 Barometric Pressure 24.17 in Hg A 8 Moisture Content 18.92 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 6.15 ppm A 11 Calculated NOx Mass Output 0.01 lbs/hr A 12 Calculated NOx Output 0.01 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 72.46 ppm A 15 Calculated CO Mass Output 0.05 lbs/hr A 16 Calculated CO Output 0.06 g/bhp-hr B 1 0.50 0.52 1610 0.12 0.721 EPA REFERENCE METHOD 320 B 2 0.73 0.53 0.728 Average Analyzer NMNEHC Level 9.11 ppm B 3 1.48 0.56 0.748 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 3.52 0.60 0.775 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 4.27 0.59 0.768 LOAD APPROXIMATION B 6 4.50 0.57 0.755 Estimated Engine Load 380.0 BHP B 7 B 8 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.6 1610 0.1 0.745 Average Stack Gas Velocity 83.08 ft/sec Average Dry Flowrate 146.04 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 6.977132 0.115667 7.092799 114.999097 9.096088 18.826025 15:08:25 02/05/2024 2 7.25032 0.052483 7.302803 83.193715 9.555946 18.56201 15:09:25 02/05/2024 3 5.777896 0.006623 5.784519 77.20285 9.631231 18.003174 15:10:25 02/05/2024 4 5.053153 -0.034069 5.019084 104.814009 9.847717 18.045825 15:11:26 02/05/2024 5 5.646606 -0.050982 5.595624 68.185307 9.206735 17.221816 15:12:25 02/05/2024 6 4.877775 -0.064817 4.812958 68.372769 9.664973 16.978671 15:13:26 02/05/2024 7 5.227034 -0.076287 5.150747 76.214569 8.853495 16.72597 15:14:26 02/05/2024 8 5.28795 -0.051998 5.235952 85.860366 8.655888 16.440295 15:15:26 02/05/2024 9 7.160684 -0.098681 7.062003 77.84252 8.467809 16.052957 15:16:26 02/05/2024 10 8.221874 -0.146727 8.075147 109.526816 8.237744 16.138566 15:17:26 02/05/2024 11 5.82923 -0.008732 5.820498 118.525962 8.73203 17.548134 15:18:26 02/05/2024 12 5.790422 0.039753 5.830175 50.977967 8.591458 17.485637 15:19:27 02/05/2024 13 5.182802 0.146725 5.329527 61.998039 9.123727 17.751029 15:20:26 02/05/2024 14 6.894439 0.114062 7.008501 68.671489 8.741857 17.27671 15:21:26 02/05/2024 15 4.666147 -0.040592 4.625555 69.600299 9.194782 16.941961 15:22:26 02/05/2024 16 5.811293 0.194583 6.005876 53.843605 8.81574 18.139341 15:23:27 02/05/2024 17 4.899565 0.156295 5.05586 110.678058 10.396692 18.070015 15:24:27 02/05/2024 18 7.034739 0.074794 7.109533 76.575765 9.581845 18.218173 15:25:27 02/05/2024 19 6.756962 0.13502 6.891982 122.441033 8.779314 18.914855 15:26:27 02/05/2024 20 5.824128 0.231746 6.055874 68.20373 8.149788 19.390406 15:27:27 02/05/2024 21 5.726931 0.081085 5.808016 91.654449 9.638844 19.088111 15:28:27 02/05/2024 22 5.060491 0.169592 5.230083 145.960585 9.229436 19.487489 15:29:27 02/05/2024 23 4.030034 0.271244 4.301278 94.307721 9.003853 22.043667 15:30:27 02/05/2024 24 4.072258 0.221906 4.294164 115.989345 9.931945 22.1518 15:31:27 02/05/2024 25 5.55975 -0.023341 5.536409 114.992339 8.85183 20.619798 15:32:27 02/05/2024 26 6.934329 0.128208 7.062537 92.244908 8.923976 20.948881 15:33:28 02/05/2024 27 4.021344 0.355036 4.37638 96.006276 9.396647 20.929263 15:34:28 02/05/2024 28 6.502941 0.327166 6.830107 92.461004 7.962063 20.981684 15:35:28 02/05/2024 29 4.967963 0.338856 5.306819 59.360043 9.084197 20.323753 15:36:28 02/05/2024 30 5.525294 0.213711 5.739005 49.950393 10.149427 19.991741 15:37:28 02/05/2024 31 4.495806 0.438091 4.933897 35.785153 8.46747 20.348826 15:38:28 02/05/2024 32 4.330941 0.368181 4.699122 44.701032 8.494122 20.14782 15:39:28 02/05/2024 33 6.153759 0.234291 6.38805 89.683896 9.179873 19.702886 15:40:28 02/05/2024 34 9.013076 0.035945 9.049021 68.926742 8.619566 19.552089 15:41:28 02/05/2024 35 5.359718 0.119546 5.479264 78.162072 8.955179 18.952596 15:42:28 02/05/2024 36 4.720252 0.163633 4.883885 54.013255 8.533814 20.604979 15:43:29 02/05/2024 37 4.667527 0.044824 4.712351 61.606434 10.065445 18.369491 15:44:28 02/05/2024 38 5.299634 0.149672 5.449306 47.734976 9.511871 18.412535 15:45:29 02/05/2024 39 4.871819 0.207888 5.079707 53.648742 9.223195 19.106375 15:46:29 02/05/2024 40 6.238299 0.309871 6.54817 68.70627 7.612092 18.958601 15:47:29 02/05/2024 41 4.873553 0.293036 5.166589 91.065201 9.541529 18.698731 15:48:29 02/05/2024 42 6.258893 0.072422 6.331315 98.014047 8.772198 17.988846 15:49:29 02/05/2024 43 5.35901 0.141426 5.500436 79.409339 8.717837 19.289974 15:50:29 02/05/2024 44 5.364637 0.227427 5.592064 65.967511 9.048698 19.088146 15:51:29 02/05/2024 45 5.400658 0.123107 5.523765 73.037271 8.990133 19.034645 15:52:29 02/05/2024 46 7.119711 0.252376 7.372087 97.422139 8.971756 18.440118 15:53:30 02/05/2024 47 5.889058 0.138966 6.028024 70.971888 9.500302 19.01292 15:54:29 02/05/2024 48 5.152998 0.151352 5.30435 90.029789 9.187845 19.282137 15:55:30 02/05/2024 49 6.005782 0.201608 6.20739 95.472216 9.524829 20.159557 15:56:29 02/05/2024 50 5.911213 0.35704 6.268253 94.420183 9.658883 18.516423 15:57:30 02/05/2024 51 5.705083 0.062561 5.767644 71.415026 8.809261 18.262014 15:58:30 02/05/2024 52 5.263751 0.155838 5.419589 82.897879 9.681462 18.571743 15:59:30 02/05/2024 53 6.220007 0.105731 6.325738 100.849941 8.662204 17.545207 16:00:30 02/05/2024 54 6.922212 -0.018501 6.903711 111.661698 8.809535 19.85734 16:01:30 02/05/2024 55 5.301746 0.209621 5.511367 94.400681 9.179408 18.95856 16:02:30 02/05/2024 56 5.37791 0.211041 5.588951 92.997087 9.530382 17.876743 16:03:30 02/05/2024 57 6.828274 -0.064315 6.763959 86.792196 8.881792 18.5214 16:04:30 02/05/2024 58 4.74638 0.278053 5.024433 80.394034 8.006325 20.72878 16:05:30 02/05/2024 59 6.028397 0.127986 6.156383 69.512608 9.413197 18.627338 16:06:30 02/05/2024 60 6.616765 0.15717 6.773935 91.29096 8.590502 19.469084 16:07:31 02/05/2024 AVG 5.73 0.13 5.87 82.69 9.06 18.86 ppm@15% O2 1.66 23.34 2.56 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.01 0.01 0.06 0.05 0.01 0.01 Calculated Emission Levels Record Date Javelin Energy Partners Flying Dutchman 18-17-C4 Run 2 6318 (100441) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 5 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 12 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.51 1610 0.13 0.714 Average O2 0.0 (% dry)A 2 0.73 0.54 0.735 Average CO2 11.8 (% dry)A 3 1.48 0.59 0.768 Average N2 + CO 88.2 (% dry)A 4 3.52 0.62 0.787 Dry Molecular Weight 29.89 lb/lbmol A 5 4.27 0.59 0.768 Wet Molecular Weight 27.65 lb/lbmol A 6 4.50 0.57 0.755 EPA REFERENCE METHOD 320 A 7 Barometric Pressure 24.17 in Hg A 8 Moisture Content 18.86 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 5.87 ppm A 11 Calculated NOx Mass Output 0.01 lbs/hr A 12 Calculated NOx Output 0.01 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 82.69 ppm A 15 Calculated CO Mass Output 0.05 lbs/hr A 16 Calculated CO Output 0.06 g/bhp-hr B 1 0.50 0.51 1610 0.13 0.714 EPA REFERENCE METHOD 320 B 2 0.73 0.53 0.728 Average Analyzer NMNEHC Level 9.06 ppm B 3 1.48 0.57 0.755 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 3.52 0.59 0.768 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 4.27 0.55 0.742 LOAD APPROXIMATION B 6 4.50 0.51 0.714 Estimated Engine Load 380.0 BHP B 7 B 8 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.6 1610 0.1 0.746 Average Stack Gas Velocity 83.11 ft/sec Average Dry Flowrate 146.22 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 6.349054 0.112288 6.461342 74.585591 9.123869 17.635829 16:09:31 02/05/2024 2 5.243669 0.011049 5.254718 90.423588 9.216034 17.718978 16:10:31 02/05/2024 3 7.371336 0.12461 7.495946 82.930443 9.243783 19.016515 16:11:31 02/05/2024 4 5.817129 -0.053556 5.763573 84.631305 8.972162 17.741304 16:12:31 02/05/2024 5 5.427514 0.059063 5.486577 56.721836 9.741787 18.887005 16:13:31 02/05/2024 6 4.74903 -0.055769 4.693261 66.706446 9.482008 18.848689 16:14:31 02/05/2024 7 5.432053 0.022486 5.454539 56.645678 9.173055 18.165318 16:15:32 02/05/2024 8 5.03889 0.14207 5.18096 33.340945 9.26283 18.605694 16:16:32 02/05/2024 9 4.218926 0.110126 4.329052 68.734464 10.559333 17.802784 16:17:32 02/05/2024 10 5.111847 0.084769 5.196616 62.642485 10.585358 18.405315 16:18:31 02/05/2024 11 4.14167 0.110925 4.252595 44.965453 8.753233 20.194375 16:19:32 02/05/2024 12 4.490594 0.087145 4.577739 58.931695 9.334991 17.741756 16:20:32 02/05/2024 13 4.959447 0.055125 5.014572 53.419035 8.814148 18.159929 16:21:32 02/05/2024 14 5.165183 0.089562 5.254745 68.905146 10.142911 19.019788 16:22:32 02/05/2024 15 4.950939 0.071845 5.022784 83.958157 8.99125 17.894591 16:23:32 02/05/2024 16 7.680234 0.033418 7.713652 75.075065 9.154283 18.460363 16:24:32 02/05/2024 17 4.920066 0.07972 4.999786 64.490739 9.164518 17.788092 16:25:32 02/05/2024 18 5.75592 -0.045284 5.710636 80.266828 8.489206 18.945629 16:26:32 02/05/2024 19 4.658755 -0.090317 4.568438 67.623325 9.835078 18.250191 16:27:32 02/05/2024 20 5.984717 -0.192957 5.79176 81.117048 8.972733 18.580083 16:28:32 02/05/2024 21 4.671056 0.012466 4.683522 53.935646 9.664012 19.788548 16:29:32 02/05/2024 22 4.605272 -0.17345 4.431822 42.052222 9.605398 17.722311 16:30:33 02/05/2024 23 7.198479 -0.200055 6.998424 90.383558 8.879375 19.97758 16:31:33 02/05/2024 24 4.008674 -0.067784 3.94089 109.962109 9.854301 18.825344 16:32:33 02/05/2024 25 4.77745 -0.168136 4.609314 44.273611 10.165818 18.303058 16:33:33 02/05/2024 26 4.931291 0.052527 4.983818 28.769304 8.825174 19.238057 16:34:33 02/05/2024 27 4.836727 0.145925 4.982652 49.245362 9.21224 19.56296 16:35:33 02/05/2024 28 5.604598 0.16762 5.772218 45.487969 9.633247 18.702817 16:36:33 02/05/2024 29 4.823227 0.111777 4.935004 62.668921 9.014913 18.10829 16:37:33 02/05/2024 30 6.085837 0.237452 6.323289 43.430881 9.424931 19.491665 16:38:34 02/05/2024 31 8.442674 0.192683 8.635357 127.446761 8.264585 18.486222 16:39:33 02/05/2024 32 5.965871 0.242322 6.208193 82.445219 8.722943 18.305742 16:40:34 02/05/2024 33 4.195993 0.084146 4.280139 67.220737 8.021769 19.933681 16:41:34 02/05/2024 34 6.149281 0.075243 6.224524 105.601376 10.417898 18.734508 16:42:34 02/05/2024 35 6.846315 0.213523 7.059838 158.022314 10.011732 19.088552 16:43:34 02/05/2024 36 58.981497 0.233029 59.214526 124.445866 8.091575 20.064024 16:44:34 02/05/2024 37 4.325329 0.256089 4.581418 232.319245 7.383788 19.424571 16:45:34 02/05/2024 38 5.887331 0.293301 6.180632 180.430189 7.597559 21.11671 16:46:34 02/05/2024 39 6.199482 0.148158 6.34764 168.17147 7.697958 18.499471 16:47:34 02/05/2024 40 4.770459 0.158545 4.929004 151.670342 8.739184 17.841821 16:48:34 02/05/2024 41 5.528768 0.169912 5.69868 135.084414 9.020878 17.048672 16:49:34 02/05/2024 42 5.694293 0.075143 5.769436 78.566331 9.407822 17.198839 16:50:34 02/05/2024 43 5.478056 0.138916 5.616972 85.133141 8.85303 16.871317 16:51:35 02/05/2024 44 4.69693 -0.070663 4.626267 82.665106 10.095867 17.7773 16:52:35 02/05/2024 45 5.523437 0.287962 5.811399 53.847738 9.84572 18.833612 16:53:35 02/05/2024 46 5.884511 0.133748 6.018259 72.602439 7.963874 17.718616 16:54:35 02/05/2024 47 5.028599 0.265417 5.294016 89.549418 8.622375 19.48208 16:55:35 02/05/2024 48 5.79116 0.236372 6.027532 77.559552 9.426574 18.649774 16:56:35 02/05/2024 49 4.762624 0.236272 4.998896 51.045101 8.560189 20.248188 16:57:36 02/05/2024 50 5.696484 0.238257 5.934741 57.234515 9.444931 18.751279 16:58:35 02/05/2024 51 4.881074 0.110165 4.991239 53.964147 9.70032 18.44565 16:59:35 02/05/2024 52 4.710892 0.033798 4.74469 55.65722 9.3068 18.103839 17:00:35 02/05/2024 53 5.326909 0.078112 5.405021 64.374477 9.03456 18.136384 17:01:36 02/05/2024 54 4.041203 -0.023335 4.017868 98.43501 8.927273 20.402281 17:02:36 02/05/2024 55 4.544994 0.040224 4.585218 73.749277 10.312526 18.304287 17:03:36 02/05/2024 56 4.53477 -0.08559 4.44918 64.785473 9.63446 18.851389 17:04:36 02/05/2024 57 6.294834 -0.042063 6.252771 80.539699 8.392184 18.85825 17:05:36 02/05/2024 58 4.636605 0.049302 4.685907 109.543353 9.322775 19.555189 17:06:36 02/05/2024 59 6.50109 0.018909 6.519999 81.619363 8.489787 18.744284 17:07:36 02/05/2024 60 5.773493 0.061417 5.83491 104.884706 9.101016 18.221744 17:08:36 02/05/2024 AVG 6.27 0.08 6.35 81.58 9.16 18.65 ppm@15% O2 1.79 23.03 2.59 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.01 0.01 0.06 0.05 0.01 0.01 FTIR Measurements 6318 (100441) Calculated Emission Levels Javelin Energy Partners Flying Dutchman 18-17-C4 Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 5 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 12 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.52 1610 0.13 0.721 Average O2 0.0 (% dry)A 2 0.73 0.53 0.728 Average CO2 11.8 (% dry)A 3 1.48 0.56 0.748 Average N2 + CO 88.2 (% dry)A 4 3.52 0.58 0.762 Dry Molecular Weight 29.89 lb/lbmol A 5 4.27 0.57 0.755 Wet Molecular Weight 27.67 lb/lbmol A 6 4.50 0.56 0.748 EPA REFERENCE METHOD 320 A 7 Barometric Pressure 24.17 in Hg A 8 Moisture Content 18.65 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 6.35 ppm A 11 Calculated NOx Mass Output 0.01 lbs/hr A 12 Calculated NOx Output 0.01 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 81.58 ppm A 15 Calculated CO Mass Output 0.05 lbs/hr A 16 Calculated CO Output 0.06 g/bhp-hr B 1 0.50 0.51 1610 0.13 0.714 EPA REFERENCE METHOD 320 B 2 0.73 0.54 0.735 Average Analyzer NMNEHC Level 9.16 ppm B 3 1.48 0.59 0.768 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 3.52 0.62 0.787 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 4.27 0.60 0.775 LOAD APPROXIMATION B 6 4.50 0.57 0.755 Estimated Engine Load 380.0 BHP B 7 B 8 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.6 1610 0.1 0.750 Average Stack Gas Velocity 83.52 ft/sec Average Dry Flowrate 147.30 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) span CO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm) 2/5/2024 12:22:34 1.003869 0.138364 0.005745 0.160265 0.955939 -2.876385 0.1456 0.073959 0.073963 0.006511 1.142234 1.1423 5.64957 191.44397 0.992037 2/5/2024 12:22:42 1.297127 0.170645 -0.000916 0.156533 0.316642 0.57414 1.857722 -0.019925 -0.019925 -0.023888 1.467772 1.467759 0.062572 191.464554 0.992316 2/5/2024 12:22:49 0.640022 0.069822 -0.004123 -0.228889 1.954185 -1.075715 0.474477 -0.051583 -0.051581 0.004487 0.709844 0.709815 4.70136 191.464554 0.992408 2/5/2024 12:22:56 0.928253 0.184336 0.020962 0.182792 -0.06696 -3.587692 0.272671 -0.055696 -0.055708 -0.010543 1.112589 1.112822 6.671178 191.537247 0.992362 2/5/2024 12:23:35 0 0 0 0 0 0 0 0 0 0 0 0 0 191.543411 0.992166 2/5/2024 12:23:49 -0.238515 -0.081661 0.013598 -0.117572 0.787847 -0.628334 -1.358925 -0.19187 -0.191896 -0.003676 -0.320176 -0.32022 -0.005993 191.808578 0.992037 2/5/2024 12:23:57 -0.391668 0.064299 -0.006907 -0.098842 1.129968 0.554274 0.231136 -0.223147 -0.223131 -0.003728 -0.327369 -0.327346 0.291893 192.118668 0.99227 2/5/2024 12:24:04 -0.139045 0.003631 -0.013584 0.012449 -2.255266 1.398504 -0.360133 -0.205242 -0.205214 -0.010135 -0.135414 -0.135396 1.287417 192.365784 0.992316 2/5/2024 12:24:12 -0.253026 0.005882 0.002034 0.090781 -3.251019 0.190046 -0.831272 -0.014942 -0.014943 0.002446 -0.247144 -0.247149 -0.006319 192.598343 0.992408 2/5/2024 12:24:19 -0.268531 -0.103169 0.013347 0.097795 -2.303361 -1.111611 1.263676 -0.030866 -0.03087 -0.007329 -0.3717 -0.37175 0.017265 192.743698 0.991811 2/5/2024 12:24:27 -0.105167 0.063948 -0.00577 0.111908 -0.818924 -0.393732 1.294654 0.11507 0.115064 0.00588 -0.041219 -0.041217 0.578628 192.772781 0.992133 2/5/2024 12:24:34 0.05992 -0.028745 -0.014017 0.146909 -1.398484 0.150308 0.800748 0.00064 0.00064 -0.007328 0.031176 0.031171 -0.009605 192.745529 0.991662 2/5/2024 12:24:42 -0.306064 0.003996 0.001304 0.027832 -2.434703 -0.593914 0.622567 0.070457 0.070458 -0.000765 -0.302068 -0.302072 -0.011917 192.656494 0.99227 2/5/2024 12:24:49 -0.16494 0.001341 -0.007988 0.047235 -1.482082 1.435218 -0.425347 -0.183424 -0.183409 0.020709 -0.163599 -0.163586 1.319424 192.569275 0.991536 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 12:25:22 494.99132 492.972893 470.38735 192.105347 0.987806 2/5/2024 12:30:16 94.496797 191.58812 0.991368 2/5/2024 12:25:29 508.706986 506.021518 491.808801 192.016922 0.988644 2/5/2024 12:30:24 95.057033 191.624451 0.991628 2/5/2024 12:25:37 511.930661 508.514339 490.99642 191.857025 0.987956 2/5/2024 12:30:31 96.758155 191.609924 0.991765 2/5/2024 12:25:45 511.175944 507.742513 490.685875 191.842484 0.988231 2/5/2024 12:30:39 96.465122 191.609924 0.991077 2/5/2024 12:25:52 511.056242 507.725023 498.627797 191.842484 0.988552 2/5/2024 12:30:46 95.927804 191.626266 0.992265 2/5/2024 12:26:00 509.65514 507.245884 497.401246 191.7789 0.98861 2/5/2024 12:30:53 96.055404 191.580841 0.991949 2/5/2024 12:26:07 509.332171 506.78966 497.424969 191.75528 0.988002 2/5/2024 12:31:01 95.589867 191.566315 0.991628 2/5/2024 12:26:15 507.81486 506.664984 491.427775 191.653519 0.988093 2/5/2024 12:31:08 97.202061 191.522705 0.992362 2/5/2024 12:26:22 506.634168 506.662535 498.645472 191.682602 0.988093 2/5/2024 12:31:16 95.266711 191.551773 0.992408 2/5/2024 12:26:30 510.297176 506.275924 496.094413 191.638992 0.988506 2/5/2024 12:31:23 94.939808 191.537247 0.992316 2/5/2024 12:31:31 98.638548 191.562683 0.990979 Date Time NO2 191C span Temp ( C )Pressure (atm) 2/5/2024 12:27:05 138.794761 191.472488 0.99386 2/5/2024 12:27:12 147.005777 191.460922 0.994112 2/5/2024 12:27:19 147.884395 191.566315 0.994107 2/5/2024 12:27:27 148.320882 191.493637 0.993464 2/5/2024 12:27:35 148.175606 191.464554 0.993785 2/5/2024 12:27:42 148.327646 191.493637 0.993831 2/5/2024 12:27:50 148.497364 191.473648 0.993952 2/5/2024 12:27:57 148.184349 191.537247 0.993923 2/5/2024 12:28:04 148.471139 191.479095 0.993877 2/5/2024 12:28:12 148.182287 191.479095 0.994428 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 12:32:06 114.069812 147.085069 96.668734 191.554199 0.977471 2/5/2024 13:50:48 83.845617 191.605072 0.992332 2/5/2024 12:32:13 342.921345 369.717018 322.058949 191.522705 0.984146 2/5/2024 13:50:56 52.147101 191.609924 0.990893 2/5/2024 12:32:21 501.548549 502.317422 485.457426 191.551773 0.988782 2/5/2024 13:51:03 93.509672 191.624451 1.00191 2/5/2024 12:32:28 508.619357 507.545051 499.079974 191.580841 0.988736 2/5/2024 13:51:11 93.960529 191.580841 1.001176 2/5/2024 12:32:36 508.966291 507.359678 497.217067 191.566315 0.98869 2/5/2024 13:51:18 94.797596 191.551773 1.000487 2/5/2024 12:32:43 508.123925 505.777089 499.435808 191.549957 0.987927 2/5/2024 13:51:26 93.831951 191.486359 1.00098 2/5/2024 12:32:50 506.690328 506.556684 489.045786 191.537247 0.988422 2/5/2024 13:51:33 97.327816 191.464554 1.000762 2/5/2024 12:32:58 509.190783 506.34835 496.300272 191.562683 0.987847 2/5/2024 13:51:41 96.663898 191.551773 1.001864 2/5/2024 12:33:05 510.181076 506.999627 489.015866 191.580841 0.988874 2/5/2024 13:51:49 97.63316 191.580841 1.001956 2/5/2024 12:33:13 510.347611 508.353325 494.969195 191.537247 0.988185 2/5/2024 13:51:56 96.095443 191.609924 1.00113 2/5/2024 13:52:03 96.267056 191.58812 1.001141 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 13:52:26 -0.033427 -0.332248 0.212257 -0.617705 191.609924 0.998834 2/5/2024 13:52:33 0.099188 -0.256851 0.091638 -1.837916 191.697128 0.997687 2/5/2024 13:52:41 -0.139936 -0.340532 0.093667 0.288923 191.915161 0.997595 2/5/2024 13:52:48 -0.214362 -0.258125 0.041136 -1.995835 191.987854 0.997779 2/5/2024 13:52:56 0.162965 0.098183 0.005644 -1.861836 192.160461 0.996964 2/5/2024 13:53:04 -0.130402 -0.255855 0.872797 -0.708419 192.278564 0.997549 2/5/2024 13:53:11 0.008436 -0.370719 1.483023 1.753306 192.38031 0.996815 2/5/2024 13:53:18 0.223879 -0.012882 1.244055 0.727902 192.409378 0.995989 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm) 2/5/2024 14:02:13 9.888048 5.003948 191.571152 0.99367 2/5/2024 14:02:21 9.844497 4.047334 191.566315 0.993602 2/5/2024 14:02:28 9.842296 6.001404 191.580841 0.992867 2/5/2024 14:02:36 9.874888 4.467522 191.595383 0.992638 2/5/2024 14:03:51 9.591024 3.871437 191.54245 0.989876 2/5/2024 14:03:59 9.691147 2.714218 191.638992 0.989333 2/5/2024 14:04:06 8.381325 50.183036 191.624451 0.996402 2/5/2024 14:04:13 8.548828 47.473131 191.580841 0.994152 2/5/2024 14:04:21 9.182881 24.803556 191.595383 0.993602 2/5/2024 14:04:28 9.175547 21.578131 191.624451 0.991306 2/5/2024 14:04:36 9.117308 27.942747 191.60083 0.993751 2/5/2024 14:04:44 8.974125 35.752958 191.580841 0.994657 2/5/2024 14:05:36 9.03027 35.272915 191.635284 0.996571 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 17:14:46 504.844256 500.996838 494.283776 192.198608 0.992787 2/5/2024 17:13:04 93.148664 192.419067 1.007246 2/5/2024 17:14:54 510.724331 505.85471 496.783406 192.147736 0.993693 2/5/2024 17:13:11 98.074079 192.482056 0.995713 2/5/2024 17:15:01 511.088054 506.140594 494.366085 192.075058 0.992638 2/5/2024 17:13:19 96.251323 192.540207 0.996356 2/5/2024 17:15:08 510.513889 506.928837 500.648028 192.04599 0.993005 2/5/2024 17:13:26 97.960757 192.554733 0.996677 2/5/2024 17:15:16 507.984187 505.862017 489.869369 192.04599 0.993693 2/5/2024 17:13:34 97.249854 192.627426 0.995667 2/5/2024 17:15:23 508.511589 505.214627 493.797707 192.04599 0.992408 2/5/2024 17:13:41 97.859777 192.598343 0.998559 2/5/2024 17:15:31 508.206869 505.441743 492.097417 192.0896 0.992729 2/5/2024 17:13:49 97.974556 192.567459 0.997727 2/5/2024 17:15:39 511.64614 505.90913 492.673699 192.109589 0.992425 2/5/2024 17:13:56 96.205169 192.496597 0.997457 2/5/2024 17:15:46 510.616569 507.606831 498.381942 192.0896 0.992684 2/5/2024 17:14:04 95.437246 192.467529 0.998421 2/5/2024 17:15:53 511.562461 507.868843 491.455057 192.176819 0.992041 2/5/2024 17:14:12 96.255561 192.365784 0.997595 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 17:13:19 -0.34946 -0.386399 0.851646 192.540207 0.996356 2/5/2024 17:16:47 -1.448766 192.278564 0.998972 2/5/2024 17:13:26 -0.26491 -0.385037 -0.537346 192.554733 0.996677 2/5/2024 17:16:54 -2.520565 192.322174 0.998605 2/5/2024 17:13:34 -0.035831 -0.207463 0.343743 192.627426 0.995667 2/5/2024 17:17:01 -3.267977 192.42392 0.999661 2/5/2024 17:13:41 -0.087026 -0.652788 1.142786 192.598343 0.998559 2/5/2024 17:17:09 -1.618619 192.438461 0.999339 2/5/2024 17:13:49 -0.064344 0.060148 0.569241 192.567459 0.997727 2/5/2024 17:17:16 -1.34752 192.482056 0.998743 2/5/2024 17:13:56 -0.343716 -0.323807 -0.444505 192.496597 0.997457 2/5/2024 17:17:24 -2.475603 192.496597 0.999431 2/5/2024 17:14:04 -0.200988 -0.111241 0.948259 192.467529 0.998421 2/5/2024 17:17:32 -0.985513 192.496597 0.999477 2/5/2024 17:14:12 0.0197 -0.233815 -0.750795 192.365784 0.997595 2/5/2024 17:17:39 -1.370848 192.580185 0.998611 SAMPLE SPIKE RECOVERY POST SYSTEM CAL POST SYSTEM ZERO PRE TEST 1 495.1 9.9 4.5 9.0 35.8 0.091 70.2% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 506.3 502.6 -0.2 0.73 -0.04 CO 510.3 503.7 -0.1 1.31 -0.01 Propane 496.1 495.1 -0.1 0.20 -0.01 Ethylene 98.6 99.84 -1.3 -1.20 -1.32 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 508.4 502.6 -0.2 1.14 -0.05 CO 510.3 503.7 0.0 1.32 -0.01 Propane 495.0 495.1 0.4 -0.03 0.08 Ethylene*97.6 99.84 -0.7 -2.21 -0.71 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 507.9 502.6 -0.3 1.05 -0.06 0.10 0.01 CO 511.6 503.7 -0.2 1.56 -0.04 0.24 0.03 Propane 491.5 495.1 0.4 -0.74 0.08 0.71 0.00 Ethylene*98.0 99.84 -2.0 -1.87 -2.04 0.34 1.33 *CTS Scans are conducted with Ethylene through the sample line. Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration Instrument/Make/Model Nicolet iS50 AUP2110269 CO MCO Nicolet iS50 AUP2110269 CI-14 M2CH4 Nicolet iS50 AUP2110269 NO MNO Nicolet iS50 AUP2110269 N02 impurity MKS FTIR C3H8 018143349 Triad Data Available Upon Request Airgas an Air Liquide company Part Number: Cylinder Number: Laboratory. PGVP Number: Gas Code: Jul 26,2023 Jul 06,2023 Jul "12,2023 Jul 12,2023 Jul 11,2023 Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele,UT 84074 Airgas.com CERTIFICATE OF ANALYSIS Grade of Product:EPA PROTOCOL STANDARD E05N199E15AOOOO CC734179 124 -Tooele (SAP)-UT B72023 Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date. 153-402805097-1 144.0 CF 2015 PSIG 660 Aug 08,2023 Expiration Date:Au 08 2031 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)"document EPA600/R-12/531 ,using the assay procedures listed.Analytical Methodology does not require correction for analytical interference,This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%.There are no significant impurities which affect the use of this calibration mixture.All concentrations are on amole/mole basis unless otherwise noted.The results relate only to the items tested.The report shall not be reproduced except in full without approval of the laboratory.Do Not Use This Cylinder below 100 psig,i.e.0.7 megapascals. ANALYTICAL RESULTS Component NOX CARBON MONOXIDE METHANE NITRIC OXIDE PROPANE Requested Concentration 500.0 PPM 500.0 PPM 500.0 PPM 500.0 PPM 500.0 PPM Balance Actual Concentration 502.6 PPM 503.7 PPM 508.2 PPM 502.6 PPM 495.1 Protocol Method Gl Gl Total Relative Uncertainty +1-0.6%NIST Traceable +1-0.7%NIST Traceable +/-0.7%NIST Traceable +1-0.6%NIST Traceable +/-0.9%NIST Traceable NITROGEN Type NTRM NTRM NTRM GMIS NTRM Lot ID 15060543 12409 0801 1609 15010116 1534012021 103 12010921 Cylinder No CC453965 D913660 K020818 KAL003474 ND73012 ND46380 CALIBRATION STANDARDS Concentration 491.9 PPM CARBON MONOXIDE/NITROGEN 15.01 PPM NITROGEN DIOXIDE/AIR 496.5 PPM METHANE/NITROGEN 494.6 PPM NITRIC OXIDE/NITROGEN 4.956 PPM NITROGEN DIOXIDE/NITROGEN 487 PPM PROPANE/AIR Uncertainty 0.6 0.6% 0.5% 1.6% 0.6% Assay Dates 08/01/2023,08/08/2023 08/01/2023 08/0112023 08/01/2023,08/08/2023 08/02/2023 Expiration Date Mar 05,2027 Feb 17,2023 Aug 08,2024 Aug 16,2027 Jun 15,2025 Apr 24,2024TheSRM,NTRM,PRM,or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Analytical Principle FTIR FTIR FTIR FTIR N02 impurity FTIR Last Multipoint Calibration pro ed for Release Page I of I Airgas an Air Liquide company Part Number: Cylinder Number: Laboratory: Analysis Date: Lot Number: Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele,UT 84074 Airgas.com CERT FICATE OF ANALYSIS Grade ofP oduct:PRIMARY STANDARD X02N199P15AD52 SG9166916BAL 124 -Tooele (SAP -UT Aug 01,2023 153-402805171-1 Expiratio Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: 153-402805171-1 140.0 CF 2015 PSIG 350 Primary Standard Gas Mixtures are tracea Date:Aug 01,2026 le to N.I.S.T.weights and/or N.I.S.T.Gas Mixture reference materials. Component ETHYLENE NITROGEN Req Conc 100.0 PPM Balance Approve for Re ALYTICAL RESULTS Actual Concentration (Mole 99.84 ase Analytical Uncertainty Page 1 of •1 Javelin – Flying Dutchman 2-5-2024 Javelin – Flying Dutchman 2-5-2024 Javelin – Flying Dutchman 2-5-2024 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report Sample Filename: C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000141.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000069.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000070.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000071.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000072.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000073.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000074.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000075.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000076.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000077.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 4.42 5.13 4.34 0.24 0.33 7 7 4.64 4.79 0.3 1.45 0-2795 1.04 Close to DL NO2 191C 0.08 0.42 0.2 0.03 0.03 0.45 0.45 0.23 0.4 0.04 0.07 0-488 0.99 Close to DL N2O 191C 1.08 0.55 0.2 0.03 0.03 0.63 0.63 0.23 0.5 0.03 0.07 0-200 -Close to DL NH3 TE 191C 38.02 72.62 33.22 4.14 7.06 123.94 123.94 36.39 67.57 3.17 11.07 0-2995 -Close to DL H2O% (HIGH) 191C19.3 0.46 -0.02 0.03 0.71 0.71 -0.39 --0-40 -Good FORMALDEHYDE 191C-0.04 0.91 0.53 0.24 0.27 1.03 1.03 0.6 0.67 0.07 0.18 0-69 -Close to DL FORMIC ACID 191C TE1.89 9.92 3.57 1.56 1.83 11.62 11.62 4.96 8.36 1.38 1.19 0-466 -Close to DL CH4 2900 CM-1 191C229.89 9.84 -1.69 2.46 18.57 18.57 -4.79 --0-3143 1 Good PROPANE 191C 3.7 1.19 4.8 0.22 0.27 1.43 1.43 5.81 5.81 1.01 1.6 0-4976 0.94 Close to DL PROPYLENE 191C TE-7.92 10.06 9.62 1.57 1.86 11.9 11.9 11.17 11.17 1.55 3.21 0-194 -Close to DL ETHANE 191C 5.82 2.6 6.12 0.55 0.85 4.04 4.04 6.63 6.63 0.51 2.04 0-1004 -Close to DL ETHYLENE 191C TE6.17 26.77 6.91 2.07 2.55 33.05 33.05 7.01 24.58 0.11 2.3 0-900 -Close to DL CO PPM 191C (1OF2)65.58 2.99 -0.26 0.57 6.21 6.21 -1.52 --0-5010 1.05 Good CO2% 191C 9.54 0.28 -0.01 0.02 0.39 0.39 -0.19 --0-23 -Good CO% 191C (2OF2)0.01 0 0.01 0 0 0 0 0.01 0.01 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.67 2.2 3.22 0.61 0.78 2.83 2.83 3.49 3.49 0.27 1.07 0-186 0.96 Close to DL ACETYLENE 191C 0.06 9.27 2.11 0.79 1.05 12.24 12.24 2.12 8.52 0 0.7 0-1016 -Close to DL SO2 191C 3.74 3.39 1.84 0.26 0.32 4.13 4.13 2.81 3.06 0.98 0.61 0-964 1.02 Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000202.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000069.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000070.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000071.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000072.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000073.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000074.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000075.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000076.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000077.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 3.9 4.27 4.34 0.24 0.33 5.83 5.83 4.64 4.64 0.3 1.45 0-2795 1.04 Close to DL NO2 191C 0.04 0.36 0.2 0.03 0.03 0.38 0.38 0.23 0.35 0.04 0.07 0-488 0.99 Close to DL N2O 191C 1.04 0.53 0.2 0.03 0.03 0.61 0.61 0.23 0.48 0.03 0.07 0-200 -Close to DL NH3 TE 191C 30.2 64.7 33.22 4.14 7.06 110.42 110.42 36.39 59.88 3.17 11.07 0-2995 -Close to DL H2O% (HIGH) 191C18.52 0.42 -0.02 0.03 0.66 0.66 -0.37 --0-40 -Good FORMALDEHYDE 191C-0.03 0.93 0.53 0.24 0.27 1.05 1.05 0.6 0.69 0.07 0.18 0-69 -Close to DL FORMIC ACID 191C TE2.17 8.87 3.57 1.56 1.83 10.39 10.39 4.96 7.31 1.38 1.19 0-466 -Close to DL CH4 2900 CM-1 191C250.48 10.3 -1.69 2.46 19.42 19.42 -5.14 --0-3143 1 Good PROPANE 191C 3.01 1.12 4.8 0.22 0.27 1.35 1.35 5.81 5.81 1.01 1.6 0-4976 0.94 Close to DL PROPYLENE 191C TE-6.43 9.01 9.62 1.57 1.86 10.66 10.66 11.17 11.17 1.55 3.21 0-194 -Close to DL ETHANE 191C 6.13 2.39 6.12 0.55 0.85 3.72 3.72 6.63 6.63 0.51 2.04 0-1004 -Close to DL ETHYLENE 191C TE8.05 23.27 6.91 2.07 2.55 28.73 28.73 7.01 21.02 0.11 2.3 0-900 -Close to DL CO PPM 191C (1OF2)67.79 2.92 -0.26 0.57 6.06 6.06 -1.5 --0-5010 1.05 Good CO2% 191C 9.64 0.27 -0.01 0.02 0.37 0.37 -0.19 --0-23 -Good CO% 191C (2OF2)0.01 0 0.01 0 0 0 0 0.01 0.01 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.7 2.12 3.22 0.61 0.78 2.73 2.73 3.49 3.49 0.27 1.07 0-186 0.96 Close to DL ACETYLENE 191C 1.15 8.38 2.11 0.79 1.05 11.06 11.06 2.12 7.59 0 0.7 0-1016 -Close to DL SO2 191C 4.98 3.45 1.84 0.26 0.32 4.2 4.2 2.81 3.08 0.98 0.61 0-964 1.02 Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000261.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000069.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000070.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000071.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000072.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000073.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000074.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000075.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000076.LAB C:\OLT\Data\Javelin\Javelin Flying Dutchman C4 2-5-24\JAVELIN FD C4 2-5-24_000077.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 4.23 4.34 4.34 0.24 0.33 5.92 5.92 4.64 4.64 0.3 1.45 0-2795 1.04 Close to DL NO2 191C 0.1 0.42 0.2 0.03 0.03 0.45 0.45 0.23 0.4 0.04 0.07 0-488 0.99 Close to DL N2O 191C 1.13 0.54 0.2 0.03 0.03 0.62 0.62 0.23 0.48 0.03 0.07 0-200 -Close to DL NH3 TE 191C 25.88 63.55 33.22 4.14 7.06 108.46 108.46 36.39 58.86 3.17 11.07 0-2995 -Close to DL H2O% (HIGH) 191C18.7 0.43 -0.02 0.03 0.67 0.67 -0.37 --0-40 -Good FORMALDEHYDE 191C-0.05 0.89 0.53 0.24 0.27 1 1 0.6 0.65 0.07 0.18 0-69 -Close to DL FORMIC ACID 191C TE2.41 8.69 3.57 1.56 1.83 10.17 10.17 4.96 7.12 1.38 1.19 0-466 -Close to DL CH4 2900 CM-1 191C227.73 9.48 -1.69 2.46 17.88 17.88 -4.67 --0-3143 1 Good PROPANE 191C 3.59 1.05 4.8 0.22 0.27 1.26 1.26 5.81 5.81 1.01 1.6 0-4976 0.94 Close to DL PROPYLENE 191C TE-8.64 8.84 9.62 1.57 1.86 10.45 10.45 11.17 11.17 1.55 3.21 0-194 -Close to DL ETHANE 191C 5.31 2.39 6.12 0.55 0.85 3.72 3.72 6.63 6.63 0.51 2.04 0-1004 -Close to DL ETHYLENE 191C TE6.86 23.33 6.91 2.07 2.55 28.79 28.79 7.01 21.11 0.11 2.3 0-900 -Close to DL CO PPM 191C (1OF2)46.35 2.12 -0.26 0.57 4.39 4.39 -1.04 --0-5010 1.05 Good CO2% 191C 9.61 0.27 -0.01 0.02 0.37 0.37 -0.19 --0-23 -Good CO% 191C (2OF2)0 0 0.01 0 0 0 0 0.01 0.01 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.7 2.12 3.22 0.61 0.78 2.72 2.72 3.49 3.49 0.27 1.07 0-186 0.96 Close to DL ACETYLENE 191C 1.07 8.27 2.11 0.79 1.05 10.92 10.92 2.12 7.48 0 0.7 0-1016 -Close to DL SO2 191C 3.74 3.48 1.84 0.26 0.32 4.24 4.24 2.81 3.15 0.98 0.61 0-964 1.02 Close to DL APPENDIX C Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 146.04 380.0 0.0 6.15 0.01 0.01 72.46 0.06 0.05 9.11 0.01 0.01 18.92 2 146.22 380.0 0.0 5.87 0.01 0.01 82.69 0.06 0.05 9.06 0.01 0.01 18.86 3 147.30 380.0 0.0 6.35 0.01 0.01 81.58 0.06 0.05 9.16 0.01 0.01 18.65 380.0 0.0 6.12 0.01 0.01 78.91 0.06 0.05 9.11 0.01 0.01 18.81 Summary Average Levels Example Calculations: Javelin Energy Partners, Flying Dutchman 18-17-C4, 6318 (100441) The following is a step-by-step calculation for the first test run conducted on the Flying Dutchman 18-17-C4 6318 (100441). Test Parameters • Stack Diameter = 5 inches • Traverse Points = 16 • Ports = 2 • Barometric Pressure = 24.17 in Hg • Average O2 = 0.0% • Average CO2 = 11.8% • Load Approximation = 380.0 bhp • Moisture Content = 18.92% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 11.8% %O2 – Oxygen Content Of The Gas = 0.0% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 0.0 – 11.8) = 88.2% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 11.8) + (0.32 * 0.0) + (0.28 * 88.2) = 29.89 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.89 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 18.92% = MD * (1-BWS) + (18) * BWS = 29.89 * (1 – (18.92/ 100)) + (18 * (18.92/ 100)) = 27.64 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 0.745 in H2O TS – Average stack temperature (R) = 1610 R PB – Barometric pressure (in Hg) = 24.17 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.1 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 27.64 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 0.745 * ( 1610 / (((0.1/ 13.6) + 24.17) * 27.64)) = 83.08 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 5 inches BWS – Moisture content of the gas (%) = 18.92% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1610 R PB – Barometric pressure (in Hg) = 24.17 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.1 in H2O VS– Average Stack gas velocity (ft/sec) = 83.08 ft/sec = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (18.92/ 100)) * 83.08 * * (((5 / 2) / 12))2) * 528 / 1610 * (24.17 + (0.1 / 13.6)) / 29.92 = 146.04 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 146.04 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 146.04 *60 * 2.83168*10 -2 = 248.123 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 6.15 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 248.123 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 380.0 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (6.15 * 1.912*10 -3 * 248.123 * 1) / 380.0 = 0.01 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.01 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 380.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.01 / 454 * 380.0 = 0.01 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 72.46 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 248.123 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 380.0 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (72.46 * 1.164*10 -3 * 248.123 * 1) / 380.0 = 0.06 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.06 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 380.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.06 / 454 * 380.0 = 0.05 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 9.11 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 248.123 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 380.0 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (9.11 * 1.833*10 -3 * 248.123 * 1) / 380.0 = 0.01 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.01 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 380.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.01 / 454 * 380.0 = 0.01 lbs/hr APPENDIX D FTIR Engine Test Sheet Company Name ~wl;,(l Location / Unit 1.0. flv;"'J\ !\,.+rhJlYYl(l {.~ ~ial.""; David Martinez ". d.-S-~~' Type of Test Completed Field Technician (5) Client Rep and/or State Rep Date Non-Resettable Run Time Hours Sq~ to Stack Diagram Engine Make LI ~(I'l m;'('\ < Engine Model Engine SIN Port Distance A \;(TAIl.i &..L 1>I~~\ tIhl., """'~'''' __"'''_N'''"''''''~' ".".~""." T Port Distance B q A Exhaust Diameter (inches) Calibration Gas NO (ppm) CO (ppm) Propane (ppm) N02 (ppm) Ethylene (ppm) Methane (ppm) Acetaldehyde (ppm) S Cylinder # CC734179 CC734179 CC734179 CC51 0760 SG9166916BAL CC734179 CC358296 Concentration 502.6 503.7 495.1 .... -147 99.84 J508.2 ~30.18 C ., ",~ *. TJ.; I t• t B 1 Test 1 Test 2 Test 3 Time of Reading ~'{)(,. o'":!,; ()I £f/Of Atm Pressure (in Hg) l..ll.~O -..;r{n ~L.f. \ 7 Atm Temp CF) ~(j,q t:.tl 3:3." Engine RPM /1 \I ';\ B. \7l(7 I'7CiO *Manifold PrelY.'Vae('1 or Boost(psi) or Boost (psia) .~ .s S' Manifold Tem~ , .7~ l~ ""J.(/ Psuction (psi) Stage 1 ('.7i 6l> 60 Tsuction CF) Stage 1 .....---. - Pdischarae (psi) Staae 1 1,(3~ ""i(,(t> 5%0 Psuction (psi) Stage 2 rnV ,1Llo , Tsuction CF) Stage 2 \.<."" Pdischarae (psi) Staae 2 Psuction (psi) Stage 3 Tsuction CF) Stage 3 Pdischarae (psi) Staae 3 Psuction (psi) Stage 4 Tsuction CF) Stage 4 Pdischarge (psi) Stage 4 Gas Throuuhout (mmctrd) or ( ~Lr-l'\. )\fV\;' \\fn ,. \.? 1,~ Pre Cat Temp CF) \\~ ~ \\"\3\l)os Post Cat Temp CF) I\SO \\~o \\$ (.I Cat Differential Pres. (" of H2O) ~ x g Humidity % ..--02% t» 0 0 C02 % Dry ----H,~ 1\. ~ \I. <i LOAD % (Panel) or ( t~ I (), C£ 4fl,(C /. f6 Ignition Timing CF) -j~ 3'.).. 3~ AFR Setting mV (Left Bank) --...--" AFR Settinq mV (Riqht Bank) "..----.--. RevS • Some units show boost in inches of Hg. In this situation please indicate if it is -t '\ ~ positive (+) or negative(-). Eg: (+12") or (- 5") 9/17/2019 COMPANY NAME:Javelin COMPANY LOCATION:Flying Dutchman C4 DATE:2/5/2024 STACK DIAMETER (inches):5 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:0 AVERAGE O2:0 AVERAGE O2:0 AVERAGE CO2:11.8 AVERAGE CO2:11.8 AVERAGE CO2:11.8 BARO PRESSURE:24.17 BARO PRESSURE:24.17 BARO PRESSURE:24.17 Point Insertion DepthDP (H2O)Ts (deg F)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg F)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg F)Stat P (H2O) 1 0.5 0.52 1150 0.12 1 0.5 0.51 1150 0.13 1 0.5 0.52 1150 0.13 2 0.73 0.53 2 0.73 0.54 2 0.73 0.53 3 1.48 0.55 3 1.48 0.59 3 1.48 0.56 4 3.52 0.59 4 3.52 0.62 4 3.52 0.58 5 4.27 0.56 5 4.27 0.59 5 4.27 0.57 6 4.5 0.55 6 4.5 0.57 6 4.5 0.56 7 7 7 8 8 8 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 0.52 1150 0.12 1 0.5 0.51 1150 0.13 1 0.5 0.51 1150 0.13 2 0.73 0.53 2 0.73 0.53 2 0.73 0.54 3 1.48 0.56 3 1.48 0.57 3 1.48 0.59 4 3.52 0.6 4 3.52 0.59 4 3.52 0.62 5 4.27 0.59 5 4.27 0.55 5 4.27 0.6 6 4.5 0.57 6 4.5 0.51 6 4.5 0.57 7 7 7 8 8 8 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 Worksheet: O2 Stratification Client:Javelin Location:Flying Dutchman C4 Date:2/5/2024 PD:5 DD:10 YES Method 1 Criteria Met UD:37 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 0.83 0.00 A 2 2.50 0.00 A 3 4.17 0.00 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 0.00 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification)