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HomeMy WebLinkAboutDAQ-2024-0077751 DAQC-358-24 CAERS ID 4683 (B4) MEMORANDUM TO: STACK TEST FILE – JAVELIN ENERGY LLC – 8-24-23-C5-2H MWF – Duchesne County, UT THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Kyle Greenberg, Environmental Scientist DATE: April 19, 2024 SUBJECT: Sources: One (1) Caterpillar G3516; SN: N6E00129 Contact: Brian Shpakoff: 682-209-2074 Location: Remote location in Duchesne County, UT Test Contractor: Oasis Emissions Consultants Permit/AO#: 40 CFR 60, Subpart JJJJ: UAC R307-510 Action Code: TR Subject: Review of Stack Test Report dated February 12, 2024 On February 22, 2024, DAQ received a test report for the above listed unit. Testing was performed February 5, 2024, to demonstrate compliance with the emission limits found in UAC R307-510 and 40 CFR Part 60, Subpart JJJJ. The calculated test results are: Source Test Date Test Method Pollutant Tester Results DAQ Results Limits Caterpillar G3516; SN: N6E00129 Feb. 5, 2024 320 NOx 0.44 g/hp-hr 0.439 g/hp-hr 34.044 ppmvd at 15% O2 1.00 g/hp-hr 160 ppmvd at 15% O2 320 CO 0.02 g/hp-hr 0.022 g/hp-hr 2.796 ppmvd at 15% O2 2.0 g/hp-hr 270 ppmvd at 15% O2 320 VOC 0.15 g/hp-hr 0.151 g/hp-hr 12.242 ppmvd at 15% O2 0.7 g/hp-hr 60 ppmvd at 15% O2 DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from the one (1) Caterpillar G3516 engine should be considered to have been in compliance with the emission limits of UAC R307-510 and 40 CFR Part 60 Subpart JJJJ, during the time of testing. ATTACHMENTS: DAQ stack test review Excel Spreadsheets; Javelin Energy Test Report. Emissions Javelin Energy LLC 8-24-23-C5-2H MWF ; Site ID: 4683 Duchesne County, Utah Caterpillar G3516 ULB; SN: N6E00129 Test Date: 2/5/2024 Run #1 2 3 Average Start Time 8:45 9:46 10:47 Stop Time 9:45 10:46 11:47 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 938.4 938.4 952.2 943.0 DS Stack Diameter (inches)15.0 15.0 15.0 15.0 PAVG Average (Delta P)½ (" H2O)½0.796 0.834 0.842 0.824 CP Pitot Tube Constant (unitless)0.84 0.84 0.84 0.84 TS Stack Temperature (°F)715 718 718 717 Pbar Barometric Pressure (" Hg)24.25 24.27 23.27 23.93 Ps Stack Pressure ('' H2O)0.22 0.23 0.23 0.23 O2%vd O2 (%vd)8.8 8.8 8.8 8.8 CO2%vd CO2 (%vd)6.5 6.7 6.8 6.7 N2%vd N2 (%vd)84.7 84.5 84.4 84.5 dry NOX (ppmvd)68.7 69.9 70.9 69.8 dry CO (ppmvd) 5.8 5.7 5.7 5.7 wet NMNEOC (ppmvw as C3H8)22.0 21.7 22.8 22.2 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.115 0.116 0.119 0.117 Bws Saturated Moisture Content (%/100)269.585 274.056 285.825 276.489 Bws Actual Moisture Content (%/100)0.115 0.116 0.119 0.117 MD Molecular Weight Dry (lb/lb-mole)29.40 29.42 29.44 29.42 MA Molecular Weight Wet (lb/lb-mole)28.09 28.10 28.08 28.09 VS Gas Velocity (ft/sec)75.1 78.7 81.1 78.3 FACFM Gas Flow (acfm)5526 5794 5975 5765 FDSCFM Gas Flow (dscfm)1781 1862 1836 1826 FWSCFM Gas Flow (wscfm)2014 2108 2084 2069 FKWSCFH Gas Flow (kwscfh)121 126 125 124 FKWSCFM Gas Flow (kwscfm)2 2 2 2 lb/hr Gas Flow (lb/hr) 8809 9224 9116 9050 Fo Fo (unitless)1.850 1.806 1.779 1.812 wet O2 (%vw)7.787 7.780 7.756 7.775 wet CO2 (%vw)5.787 5.923 5.994 5.901 wet NOX (ppmvw)60.748 61.799 62.500 61.682 15 NOX (ppmvd @ 15% O2)33.474 34.083 34.576 34.044 160.0 lb/hr NOX (lb/hr)0.875 0.932 0.932 0.913 g/bhp-hr NOX (g/bhp-hr)0.423 0.450 0.444 0.439 1.0 wet CO (ppmvw) 5.132 5.039 5.024 5.065 15 CO (ppmvd @ 15% O2)2.828 2.779 2.779 2.796 270.0 lb/hr CO (lb/hr) 0.045 0.046 0.046 0.046 g/bhp-hr CO (g/bhp-hr) 0.022 0.022 0.022 0.022 2.0 dry NMEOC (ppmvd as C3H8)24.910 24.500 25.910 25.107 15 NMEOC (ppmvd as C3H8 @ 15% O2)12.146 11.946 12.634 12.242 60 lb/hr NMEOC (lb/hr as C3H8)0.304 0.313 0.326 0.315 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.147 0.151 0.155 0.151 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 Source Test Report For Javelin Energy Partners Moose Hollow 24-23-C5 Utah Test Date: February 5, 2024 Report Date: February 12, 2024 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Caterpillar G3516 ULB SN: N6E00129 Unit ID: 4683 (6995) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 February 12, 2024 Mr. Brian Shpakoff Javelin Energy Partners Dear Mr. Shpakoff: Re: Engine Emission Testing For Javelin Energy Partners, Moose Hollow 24-23-C5, Unit 4683 (6995), Federal Regulation: EPA 40 CFR 60, Subpart JJJJ. An air emissions test program was conducted on a Caterpillar G3516 ULB engine, operated by Javelin Energy Partners and designated as Unit 4683 (6995), located at the Moose Hollow 24-23-C5 in Utah. The purpose of the testing was to demonstrate initial compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on February 5, 2024. Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.44 1.0 0.02 2.0 0.15 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 714 3.5 Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 1380 943.0 68.3 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: Javelin Energy Partners Owner/Operator Contact: Brian Shpakoff Facility Name: Moose Hollow 24-23-C5 Latitude: 40.205614 Longitude: -110.387667 Utah Emission Source: Caterpillar G3516 ULB Unit 4683 (6995) Date of Test: February 5, 2024 Date of Report: February 12, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters............................................................................................................... 7 5.1 Quality Assurance ................................................................................................................ 8 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................ 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Load Approximation APPENDIX D: Example Calculations and Summary APPENDIX E: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Caterpillar G3516 ULB engine, operated by Javelin Energy Partners and designated as Unit 4683 (6995), located at the Moose Hollow 24-23-C5 in Utah. The purpose of the testing was to demonstrate initial compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non-methane, non- ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is currently located in Utah. Three one hour test runs were performed on February 5, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percentage. The following key personnel were present during testing: David Martinez, OEC 2 2.1 Stack Sampling Location The facility is currently located in Utah. Testing was conducted on the Caterpillar G3516 ULB engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 2.3 pipe diameters (34”) downstream from the nearest flow disturbance (Distance B) and 2.4 pipe diameters (34”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 16 traverse insertion depths (8 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location 15" A B Oxidation Catalyst 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on February 5, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate initial compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Caterpillar G3516 ULB, NOx, CO and VOC The first test was performed from 8:45 to 9:44 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 938.4 bhp, and the average NOx and CO levels were found to be 0.42 g/bhp-hr and 0.02 g/bhp-hr respectively, below limitations. The VOC level tested at 0.15 g/bhp- hr, which tested in compliance. 3.1.2 Source Test 2: Caterpillar G3516 ULB, NOx, CO and VOC The second test was performed from 9:46 to 10:45 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 938.4 bhp, and the average NOx and CO levels were found to be 0.45 g/bhp-hr and 0.02 g/bhp-hr respectively, below limitations. The VOC level tested at 0.15 g/bhp- hr, which tested in compliance. 3.1.3 Source Test 3: Caterpillar G3516 ULB, NOx, CO and VOC The third test was performed from 10:47 to 11:46 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 952.2 bhp, and the average NOx and CO levels were found to be 0.44 g/bhp-hr and 0.02 g/bhp-hr respectively, below limitations. The VOC level tested at 0.16 g/bhp- hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 1 68.65 0.42 5.80 0.02 24.91 0.15 8.8 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 2 69.90 0.45 5.70 0.02 24.50 0.15 8.8 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 3 70.91 0.44 5.70 0.02 25.91 0.16 8.8 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 8 February 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percentage. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 99.0%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 61.248541 7.310255 68.558796 6.111737 24.998101 12.169165 8:45:20 02/05/2024 2 61.487942 7.479284 68.967226 6.114929 25.130545 11.860389 8:46:20 02/05/2024 3 61.352452 7.518323 68.870775 6.093429 25.079094 13.615776 8:47:20 02/05/2024 4 61.427851 7.595505 69.023356 5.950508 25.308757 12.168999 8:48:21 02/05/2024 5 61.131015 7.493301 68.624316 5.919408 26.126334 14.532655 8:49:21 02/05/2024 6 60.513238 7.633324 68.146562 5.954064 24.497432 10.74507 8:50:21 02/05/2024 7 60.928117 7.681186 68.609303 5.966045 24.662448 11.057797 8:51:21 02/05/2024 8 60.906705 7.76827 68.674975 5.891046 24.355467 11.085174 8:52:21 02/05/2024 9 61.225554 7.851493 69.077047 5.93691 24.574491 11.165038 8:53:21 02/05/2024 10 61.108703 7.805151 68.913854 5.859793 24.25066 11.149188 8:54:21 02/05/2024 11 60.70991 7.709435 68.419345 5.846756 25.94719 12.311401 8:55:21 02/05/2024 12 60.700783 7.804573 68.505356 5.926649 24.902918 11.916166 8:56:21 02/05/2024 13 60.969145 7.941364 68.910509 5.974984 24.595396 11.037375 8:57:22 02/05/2024 14 60.533253 7.947374 68.480627 5.951989 24.14949 10.966865 8:58:22 02/05/2024 15 60.886116 8.029924 68.91604 5.878205 24.622037 10.859784 8:59:22 02/05/2024 16 59.948584 7.857371 67.805955 5.898846 24.978909 11.188081 9:00:22 02/05/2024 17 60.686152 8.052389 68.738541 5.821796 24.179774 10.761781 9:01:22 02/05/2024 18 60.589765 8.038382 68.628147 5.872539 24.690626 11.666835 9:02:22 02/05/2024 19 59.328643 7.843518 67.172161 5.770112 24.924605 10.887471 9:03:22 02/05/2024 20 60.262711 7.943641 68.206352 5.796268 26.112726 15.453771 9:04:22 02/05/2024 21 59.997827 8.16019 68.158017 5.79365 24.341912 10.875132 9:05:23 02/05/2024 22 60.49425 8.29303 68.78728 5.697726 24.749877 10.6523 9:06:22 02/05/2024 23 60.138349 8.201044 68.339393 5.780416 24.735222 10.842321 9:07:22 02/05/2024 24 60.153289 8.213186 68.366475 5.854121 24.33687 10.668792 9:08:22 02/05/2024 25 60.07425 8.217388 68.291638 5.780758 24.654159 10.811633 9:09:23 02/05/2024 26 60.774107 8.420318 69.194425 5.782129 24.54105 10.82978 9:10:23 02/05/2024 27 59.704342 8.241729 67.946071 5.705399 24.874895 10.899493 9:11:23 02/05/2024 28 60.477308 8.393596 68.870904 5.776908 24.780158 10.780125 9:12:23 02/05/2024 29 60.234391 8.243075 68.477466 5.76882 25.321728 13.569194 9:13:23 02/05/2024 30 60.571639 8.373679 68.945318 5.827769 24.286599 11.903404 9:14:23 02/05/2024 31 59.046167 8.103521 67.149688 5.80484 24.325993 10.904085 9:15:23 02/05/2024 32 59.277349 8.022934 67.300283 5.786126 24.854319 10.888335 9:16:23 02/05/2024 33 59.677616 8.07115 67.748766 5.80023 24.922814 10.914786 9:17:24 02/05/2024 34 59.938493 8.184344 68.122837 5.737342 24.534334 10.660307 9:18:24 02/05/2024 35 59.924827 8.109865 68.034692 5.749925 25.646302 10.952733 9:19:23 02/05/2024 36 60.786816 8.285451 69.072267 5.838263 25.581962 12.464001 9:20:24 02/05/2024 37 61.085007 8.402982 69.487989 5.815684 24.884439 11.970231 9:21:24 02/05/2024 38 60.465671 8.350227 68.815898 5.701689 24.885092 10.868237 9:22:24 02/05/2024 39 60.611794 8.403164 69.014958 5.688896 25.630902 10.883794 9:23:24 02/05/2024 40 60.943357 8.567703 69.51106 5.660096 26.148667 12.90656 9:24:24 02/05/2024 41 60.323818 8.564142 68.88796 5.569632 25.034729 10.743589 9:25:24 02/05/2024 42 60.908018 8.791805 69.699823 5.701037 24.936282 10.890958 9:26:25 02/05/2024 43 59.941649 9.000983 68.942632 5.565385 24.888144 10.963483 9:27:24 02/05/2024 44 60.267029 8.472527 68.739556 5.693246 25.689521 11.050891 9:28:24 02/05/2024 45 60.174182 8.588975 68.763157 5.747851 24.517724 11.023593 9:29:24 02/05/2024 46 60.60348 8.690614 69.294094 5.778367 24.525704 10.821552 9:30:25 02/05/2024 47 59.403829 8.224496 67.628325 5.651369 25.843642 13.110278 9:31:25 02/05/2024 48 59.751999 8.602425 68.354424 5.793311 24.607139 11.387218 9:32:25 02/05/2024 49 59.818703 8.587419 68.406122 5.793598 24.406398 10.952423 9:33:25 02/05/2024 50 60.526505 8.639956 69.166461 5.769507 25.181528 11.012459 9:34:25 02/05/2024 51 59.715025 8.602623 68.317648 5.757906 25.191085 10.891037 9:35:25 02/05/2024 52 60.618871 8.665477 69.284348 5.657655 25.953212 15.248038 9:36:25 02/05/2024 53 59.910768 8.625482 68.53625 5.6419 25.388065 11.574674 9:37:25 02/05/2024 54 60.210254 8.667004 68.877258 5.682263 25.274715 10.745481 9:38:25 02/05/2024 55 60.157045 8.785289 68.942334 5.684711 24.628097 10.917607 9:39:26 02/05/2024 56 60.717496 8.973487 69.690983 5.664172 24.284468 11.129536 9:40:25 02/05/2024 57 60.188638 8.736743 68.925381 5.676223 24.63229 10.982921 9:41:26 02/05/2024 58 60.176337 8.801966 68.978303 5.686792 24.884912 11.103544 9:42:26 02/05/2024 59 60.72142 8.755017 69.476437 5.660226 24.466059 12.861025 9:43:26 02/05/2024 60 60.525003 8.881877 69.40688 5.731006 24.343541 11.30583 9:44:26 02/05/2024 AVG 60.42 8.24 68.65 5.80 24.91 11.51 ppm@15% O2 33.48 2.83 12.15 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.42 0.87 0.02 0.04 0.15 0.30 4683 (6995) FTIR Measurements Calculated Emission Levels Javelin Energy Partners Moose Hollow 24-23-C5 Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 15 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.62 1210 0.22 0.787 Average O2 8.8 (% dry)A 2 1.58 0.67 0.819 Average CO2 6.54 (% dry)A 3 2.91 0.66 0.812 Average N2 + CO 84.7 (% dry)A 4 4.85 0.63 0.794 Dry Molecular Weight 29.40 lb/lbmol A 5 10.16 0.60 0.775 Wet Molecular Weight 28.09 lb/lbmol A 6 12.09 0.59 0.768 EPA REFERENCE METHOD 320 A 7 13.43 0.56 0.748 Barometric Pressure 24.25 in Hg A 8 14.50 0.55 0.742 Moisture Content 11.51 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 68.65 ppm A 11 Calculated NOx Mass Output 0.87 lbs/hr A 12 Calculated NOx Output 0.42 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 5.80 ppm A 15 Calculated CO Mass Output 0.04 lbs/hr A 16 Calculated CO Output 0.02 g/bhp-hr B 1 0.50 0.63 1175 0.22 0.794 EPA REFERENCE METHOD 320 B 2 1.58 0.66 0.812 Average Analyzer NMNEHC Level 24.91 ppm B 3 2.91 0.71 0.843 Calculated NMNEHC Mass Output 0.30 lbs/hr B 4 4.85 0.69 0.831 Calculated NMNEHC Output 0.15 g/bhp-hr B 5 10.16 0.66 0.812 LOAD APPROXIMATION B 6 12.09 0.67 0.819 Estimated Engine Load 938.4 BHP B 7 13.43 0.62 0.787 B 8 14.50 0.64 0.800 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.6 1193 0.2 0.796 Average Stack Gas Velocity 75.65 ft/sec Average Dry Flowrate 1770.03 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 59.829724 8.817339 68.647063 5.746624 24.296264 11.036961 9:46:26 02/05/2024 2 59.900895 8.805935 68.70683 5.794034 24.33024 11.167751 9:47:26 02/05/2024 3 59.805202 8.770959 68.576161 5.712759 24.537796 10.84347 9:48:27 02/05/2024 4 60.449562 8.80944 69.259002 5.677007 24.716296 11.630236 9:49:26 02/05/2024 5 59.978726 8.63362 68.612346 5.700366 25.290459 12.377832 9:50:26 02/05/2024 6 60.293355 8.962861 69.256216 5.62378 24.552175 10.72571 9:51:27 02/05/2024 7 60.315027 8.956765 69.271792 5.661797 24.482651 11.825108 9:52:27 02/05/2024 8 60.998352 9.009634 70.007986 5.607336 25.431635 13.279446 9:53:27 02/05/2024 9 60.072263 9.001372 69.073635 5.605427 24.744616 11.172849 9:54:27 02/05/2024 10 60.555519 9.255907 69.811426 5.73147 24.001752 11.022767 9:55:27 02/05/2024 11 60.440009 9.253668 69.693677 5.7421 24.089989 11.045514 9:56:27 02/05/2024 12 60.348482 9.2601 69.608582 5.771257 23.953685 10.971812 9:57:27 02/05/2024 13 61.067253 9.377759 70.445012 5.690197 23.845671 11.000821 9:58:27 02/05/2024 14 60.616399 9.306323 69.922722 5.683732 24.865078 11.15262 9:59:27 02/05/2024 15 60.617226 9.130637 69.747863 5.668128 24.765433 11.946413 10:00:27 02/05/2024 16 61.231658 9.056096 70.287754 5.548813 25.028966 12.900709 10:01:28 02/05/2024 17 60.904437 9.299088 70.203525 5.6899 24.95361 11.037945 10:02:28 02/05/2024 18 60.133567 9.281319 69.414886 5.612959 24.277065 10.727883 10:03:28 02/05/2024 19 60.382374 9.227779 69.610153 5.68037 24.771442 12.46563 10:04:28 02/05/2024 20 60.439083 9.259637 69.69872 5.646934 24.169974 11.222485 10:05:28 02/05/2024 21 61.383908 9.476078 70.859986 5.58756 25.095519 12.906748 10:06:28 02/05/2024 22 60.074765 9.213287 69.288052 5.717528 23.896029 10.72158 10:07:28 02/05/2024 23 60.31963 9.265463 69.585093 5.627043 24.024403 10.982593 10:08:28 02/05/2024 24 60.609929 9.373202 69.983131 5.631331 24.585462 11.089865 10:09:28 02/05/2024 25 60.931028 9.221096 70.152124 5.523929 24.53906 13.114323 10:10:28 02/05/2024 26 60.520093 9.169884 69.689977 5.635555 24.296377 12.117614 10:11:29 02/05/2024 27 59.54659 9.126964 68.673554 5.729768 24.36566 10.87824 10:12:29 02/05/2024 28 60.245324 9.289225 69.534549 5.670294 25.294643 11.024839 10:13:29 02/05/2024 29 60.993153 9.463155 70.456308 5.671762 24.493166 10.872105 10:14:29 02/05/2024 30 59.933703 9.261796 69.195499 5.740463 24.268439 11.082159 10:15:29 02/05/2024 31 60.371158 9.282855 69.654013 5.637814 23.458395 11.360278 10:16:29 02/05/2024 32 60.794886 9.407358 70.202244 5.681005 23.488229 11.10907 10:17:29 02/05/2024 33 60.819774 9.095945 69.915719 5.738664 24.742199 12.924713 10:18:29 02/05/2024 34 60.423932 9.06692 69.490852 5.651077 24.990301 11.681269 10:19:29 02/05/2024 35 60.402462 9.180797 69.583259 5.790126 24.159603 11.115121 10:20:29 02/05/2024 36 61.311698 9.496653 70.808351 5.769644 23.766328 11.08392 10:21:29 02/05/2024 37 60.408885 9.180784 69.589669 5.743466 24.864684 12.02927 10:22:29 02/05/2024 38 60.345639 9.102204 69.447843 5.677005 24.900364 12.570228 10:23:30 02/05/2024 39 60.533412 9.154514 69.687926 5.800011 24.635655 10.87241 10:24:30 02/05/2024 40 60.842904 9.344272 70.187176 5.733895 24.549205 11.00655 10:25:30 02/05/2024 41 60.751119 9.313815 70.064934 5.720093 23.785988 11.263381 10:26:30 02/05/2024 42 60.428983 9.283044 69.712027 5.7493 24.095354 10.978606 10:27:30 02/05/2024 43 61.043434 9.241392 70.284826 5.737263 24.018982 12.768786 10:28:31 02/05/2024 44 61.250018 9.415778 70.665796 5.71742 24.256398 11.933421 10:29:30 02/05/2024 45 60.587979 9.276072 69.864051 5.723785 26.849052 11.800331 10:30:30 02/05/2024 46 60.462354 9.365183 69.827537 5.81367 24.64398 11.179329 10:31:30 02/05/2024 47 60.705969 9.455015 70.160984 5.665596 23.797737 11.329411 10:32:30 02/05/2024 48 61.615558 9.479271 71.094829 5.725941 25.562154 11.846315 10:33:31 02/05/2024 49 60.701395 9.201883 69.903278 5.654886 24.927084 12.821784 10:34:31 02/05/2024 50 61.383615 9.343954 70.727569 5.649073 24.695934 11.308325 10:35:31 02/05/2024 51 61.276891 9.262561 70.539452 5.823491 24.751897 11.336236 10:36:31 02/05/2024 52 61.972184 9.384196 71.35638 5.703311 24.770842 11.280741 10:37:31 02/05/2024 53 60.832402 9.302886 70.135288 5.779962 24.257607 11.29938 10:38:31 02/05/2024 54 60.865402 9.134603 70.000005 5.765937 24.5763 11.917922 10:39:31 02/05/2024 55 60.953056 9.20859 70.161646 5.826916 24.454272 12.529131 10:40:32 02/05/2024 56 61.827001 9.50697 71.333971 5.687575 25.150767 11.301298 10:41:32 02/05/2024 57 61.602683 9.09968 70.702363 5.543652 25.178546 13.40959 10:42:31 02/05/2024 58 61.601555 9.173366 70.774921 5.668347 24.794862 12.656173 10:43:32 02/05/2024 59 60.833655 9.373088 70.206743 5.717434 23.368335 11.209982 10:44:32 02/05/2024 60 61.04873 9.433584 70.482314 5.789778 22.639719 10.968419 10:45:32 02/05/2024 AVG 60.68 9.22 69.90 5.70 24.50 11.59 ppm@15% O2 34.08 2.78 11.95 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.45 0.93 0.02 0.05 0.15 0.31 Calculated Emission Levels Record Date Javelin Energy Partners Moose Hollow 24-23-C5 Run 2 4683 (6995) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 15 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.65 1178 0.23 0.806 Average O2 8.8 (% dry)A 2 1.58 0.69 0.831 Average CO2 6.7 (% dry)A 3 2.91 0.73 0.854 Average N2 + CO 84.5 (% dry)A 4 4.85 0.72 0.849 Dry Molecular Weight 29.42 lb/lbmol A 5 10.16 0.70 0.837 Wet Molecular Weight 28.10 lb/lbmol A 6 12.09 0.68 0.825 EPA REFERENCE METHOD 320 A 7 13.43 0.65 0.806 Barometric Pressure 24.27 in Hg A 8 14.50 0.61 0.781 Moisture Content 11.59 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 69.90 ppm A 11 Calculated NOx Mass Output 0.93 lbs/hr A 12 Calculated NOx Output 0.45 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 5.70 ppm A 15 Calculated CO Mass Output 0.05 lbs/hr A 16 Calculated CO Output 0.02 g/bhp-hr B 1 0.50 0.68 1178 0.23 0.825 EPA REFERENCE METHOD 320 B 2 1.58 0.70 0.837 Average Analyzer NMNEHC Level 24.50 ppm B 3 2.91 0.72 0.849 Calculated NMNEHC Mass Output 0.31 lbs/hr B 4 4.85 0.75 0.866 Calculated NMNEHC Output 0.15 g/bhp-hr B 5 10.16 0.74 0.860 LOAD APPROXIMATION B 6 12.09 0.72 0.849 Estimated Engine Load 938.4 BHP B 7 13.43 0.71 0.843 B 8 14.50 0.69 0.831 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.7 1178 0.2 0.834 Average Stack Gas Velocity 78.70 ft/sec Average Dry Flowrate 1863.97 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 60.459287 9.618242 70.077529 5.705674 24.626952 11.000099 10:47:32 02/05/2024 2 61.613543 9.646259 71.259802 5.852551 25.435302 10.822729 10:48:32 02/05/2024 3 60.400458 9.539715 69.940173 5.762249 24.407333 10.906951 10:49:32 02/05/2024 4 61.142597 9.624843 70.76744 5.63664 26.605373 11.163358 10:50:33 02/05/2024 5 60.993739 9.509304 70.503043 5.748288 25.786731 12.920483 10:51:32 02/05/2024 6 61.670129 9.697238 71.367367 5.794562 26.31785 12.023893 10:52:32 02/05/2024 7 61.584034 9.71306 71.297094 5.6199 27.671094 11.806625 10:53:33 02/05/2024 8 61.537809 9.664993 71.202802 5.67256 26.318794 11.495515 10:54:33 02/05/2024 9 61.403436 9.546635 70.950071 5.542646 24.325954 12.895912 10:55:33 02/05/2024 10 61.20042 9.527206 70.727626 5.727192 27.929823 12.693231 10:56:33 02/05/2024 11 61.651773 9.714273 71.366046 5.792636 27.024093 12.505962 10:57:33 02/05/2024 12 61.72275 9.65927 71.38202 5.646064 28.401669 11.901105 10:58:33 02/05/2024 13 62.082684 9.734813 71.817497 5.631957 27.252603 11.816594 10:59:33 02/05/2024 14 60.768878 9.474621 70.243499 5.788431 25.880874 11.729742 11:00:33 02/05/2024 15 61.668471 9.736512 71.404983 5.716187 24.799828 11.60992 11:01:33 02/05/2024 16 61.731314 9.832122 71.563436 5.868195 26.720761 11.625846 11:02:34 02/05/2024 17 61.018037 9.553236 70.571273 5.778991 23.642413 12.778888 11:03:33 02/05/2024 18 61.616501 9.786069 71.40257 5.675211 27.457936 11.751342 11:04:34 02/05/2024 19 61.411804 9.550787 70.962591 5.614613 26.610329 11.658549 11:05:34 02/05/2024 20 61.746292 9.782949 71.529241 5.706142 27.216175 11.65904 11:06:34 02/05/2024 21 60.780041 9.635254 70.415295 5.604496 26.66919 11.658944 11:07:34 02/05/2024 22 60.349375 9.711787 70.061162 5.786771 26.683452 11.637854 11:08:34 02/05/2024 23 61.260011 9.661709 70.92172 5.788478 24.957749 11.628859 11:09:34 02/05/2024 24 61.934238 9.764257 71.698495 5.644904 26.448132 11.623349 11:10:34 02/05/2024 25 61.598661 9.736314 71.334975 5.608029 23.960228 11.611266 11:11:34 02/05/2024 26 61.179239 9.51362 70.692859 5.710244 25.214556 15.187006 11:12:34 02/05/2024 27 61.123583 9.823381 70.946964 5.626646 28.498338 11.994518 11:13:34 02/05/2024 28 61.061404 9.743747 70.805151 5.614628 25.709551 11.65015 11:14:34 02/05/2024 29 60.778192 9.641064 70.419256 5.628493 27.03265 11.65921 11:15:35 02/05/2024 30 61.948581 9.867861 71.816442 5.680386 23.600646 11.601569 11:16:35 02/05/2024 31 61.000534 9.67151 70.672044 5.803828 23.908173 11.988547 11:17:35 02/05/2024 32 61.053325 9.80369 70.857015 5.7049 25.920388 11.670322 11:18:35 02/05/2024 33 62.141205 9.940575 72.08178 5.612583 24.842113 11.544188 11:19:35 02/05/2024 34 60.917526 9.677642 70.595168 5.60731 26.131832 11.551618 11:20:35 02/05/2024 35 61.060384 9.567054 70.627438 5.726831 26.13494 11.581719 11:21:35 02/05/2024 36 61.080164 9.621441 70.701605 5.692484 25.559572 13.053531 11:22:35 02/05/2024 37 61.25169 9.886643 71.138333 5.760958 28.674406 11.53972 11:23:35 02/05/2024 38 61.426236 9.872299 71.298535 5.733259 24.50965 11.600891 11:24:35 02/05/2024 39 61.880497 9.937065 71.817562 5.683254 25.644131 11.580509 11:25:35 02/05/2024 40 61.149962 9.676699 70.826661 5.733571 24.195911 11.581381 11:26:35 02/05/2024 41 61.283861 9.896856 71.180717 5.656128 23.548943 11.570812 11:27:36 02/05/2024 42 61.088344 9.826213 70.914557 5.684242 24.44974 11.566514 11:28:36 02/05/2024 43 61.402491 9.832939 71.23543 5.612551 27.02882 11.600679 11:29:36 02/05/2024 44 61.207787 9.712801 70.920588 5.661402 25.35465 11.593822 11:30:36 02/05/2024 45 60.634186 9.726272 70.360458 5.59417 26.293296 11.589865 11:31:36 02/05/2024 46 60.508986 9.661641 70.170627 5.64543 25.817882 11.579863 11:32:36 02/05/2024 47 60.634729 9.821915 70.456644 5.639504 25.838851 11.591798 11:33:36 02/05/2024 48 60.985777 9.582977 70.568754 5.671221 25.201157 13.394623 11:34:37 02/05/2024 49 60.245097 9.561497 69.806594 5.712982 24.641729 11.84905 11:35:36 02/05/2024 50 61.488581 9.567802 71.056383 5.609173 24.868696 13.330512 11:36:36 02/05/2024 51 60.760079 9.566402 70.326481 5.634099 25.781336 11.550553 11:37:37 02/05/2024 52 61.317613 9.760681 71.078294 5.752354 26.338673 11.582698 11:38:37 02/05/2024 53 61.710289 9.779502 71.489791 5.788376 23.567026 11.555569 11:39:37 02/05/2024 54 61.791263 9.647506 71.438769 5.81954 27.880423 11.560924 11:40:37 02/05/2024 55 60.780939 9.415323 70.196262 5.676439 24.74285 11.580919 11:41:37 02/05/2024 56 61.07242 9.428551 70.500971 5.68875 25.122746 11.575865 11:42:37 02/05/2024 57 61.06195 9.476371 70.538321 5.688642 25.530824 11.533192 11:43:37 02/05/2024 58 61.130727 9.577927 70.708654 5.689735 30.310467 11.502893 11:44:37 02/05/2024 59 61.079324 9.395905 70.475229 5.787255 24.838252 12.846696 11:45:38 02/05/2024 60 61.60422 9.439426 71.043646 5.687764 28.950743 11.697424 11:46:37 02/05/2024 AVG 61.24 9.67 70.91 5.70 25.91 11.86 ppm@15% O2 34.58 2.78 12.64 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.44 0.93 0.02 0.05 0.16 0.33 FTIR Measurements 4683 (6995) Calculated Emission Levels Javelin Energy Partners Moose Hollow 24-23-C5 Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 15 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.67 1178 0.23 0.819 Average O2 8.8 (% dry)A 2 1.58 0.68 0.825 Average CO2 6.8 (% dry)A 3 2.91 0.70 0.837 Average N2 + CO 84.4 (% dry)A 4 4.85 0.73 0.854 Dry Molecular Weight 29.44 lb/lbmol A 5 10.16 0.74 0.860 Wet Molecular Weight 28.08 lb/lbmol A 6 12.09 0.72 0.849 EPA REFERENCE METHOD 320 A 7 13.43 0.71 0.843 Barometric Pressure 23.27 in Hg A 8 14.50 0.68 0.825 Moisture Content 11.86 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 70.91 ppm A 11 Calculated NOx Mass Output 0.93 lbs/hr A 12 Calculated NOx Output 0.44 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 5.70 ppm A 15 Calculated CO Mass Output 0.05 lbs/hr A 16 Calculated CO Output 0.02 g/bhp-hr B 1 0.50 0.68 1178 0.23 0.825 EPA REFERENCE METHOD 320 B 2 1.58 0.70 0.837 Average Analyzer NMNEHC Level 25.91 ppm B 3 2.91 0.72 0.849 Calculated NMNEHC Mass Output 0.33 lbs/hr B 4 4.85 0.76 0.872 Calculated NMNEHC Output 0.16 g/bhp-hr B 5 10.16 0.74 0.860 LOAD APPROXIMATION B 6 12.09 0.73 0.854 Estimated Engine Load 952.2 BHP B 7 13.43 0.71 0.843 B 8 14.50 0.69 0.831 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.7 1178 0.2 0.842 Average Stack Gas Velocity 81.20 ft/sec Average Dry Flowrate 1838.39 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) span CO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm) 2/5/2024 7:54:52 -0.885641 -0.135904 0.004246 0.050186 0.182863 0.104504 -0.755269 0.13549 0.135495 0.004671 -1.021545 -1.021588 1.387701 154.483246 1.04717 2/5/2024 7:54:59 -0.944071 -0.208079 -0.006618 -0.037033 0.46937 1.311518 -0.822495 -0.017938 -0.017937 0.012659 -1.15215 -1.152074 2.695334 154.994415 1.046757 2/5/2024 7:55:06 -0.935036 -0.230389 0.001557 -0.165995 0.242831 1.3705 -1.022999 0.144997 0.144999 -0.005111 -1.165426 -1.165444 3.002682 155.328735 1.046894 2/5/2024 7:55:14 -1.121586 -0.166002 -0.007783 -0.192977 0.454535 0.802394 -0.255435 0.242062 0.242043 0.017724 -1.287588 -1.287488 1.402078 155.692139 1.047445 2/5/2024 7:55:52 0 0 0 0 0 0 0 0 0 0 0 0 0 156.908295 1.047569 2/5/2024 7:56:05 -0.144915 0.015803 0.002287 -0.109999 -0.119671 -0.537348 0.320601 0.159194 0.159198 -0.009153 -0.129112 -0.129115 0.061575 158.417587 1.047223 2/5/2024 7:56:13 -0.110578 -0.001588 -0.004387 0.017835 0.42584 0.187603 -0.073098 -0.075981 -0.075978 -0.008902 -0.112165 -0.112161 0.017157 158.904526 1.047124 2/5/2024 7:56:20 -0.215551 0.003491 -0.001037 0.025634 0.632499 0.110381 -0.086766 -0.150051 -0.150049 -0.009972 -0.21206 -0.212058 0.011926 159.195236 1.03932 2/5/2024 7:56:28 -0.073033 0.030009 0.003614 -0.008598 1.597899 0.13626 1.046828 -0.050249 -0.050251 0.008823 -0.043024 -0.043025 0.121837 159.427811 1.022704 2/5/2024 7:56:35 0.008052 0.014267 0.000859 0.071636 0.702601 1.660601 0.175864 0.361828 0.361831 -0.000386 0.022319 0.02232 1.599743 159.762131 1.022658 2/5/2024 7:56:43 -0.265641 0.005555 -0.003072 0.029345 0.374499 0.321747 -1.10515 0.005505 0.005505 -0.007067 -0.260086 -0.260078 0.007756 160.109177 1.021625 2/5/2024 7:56:50 0.093547 0.081379 0.002021 -0.039479 0.280472 1.307646 -0.714273 -0.033011 -0.033012 -0.005798 0.174926 0.174929 1.085537 160.452591 1.020982 2/5/2024 7:56:58 0.086472 0.044283 0.005585 0.339576 -0.105064 0.65695 0.257771 0.07446 0.074464 -0.000596 0.130755 0.130763 0.107587 160.732391 1.021304 2/5/2024 7:57:05 -0.118757 0.021412 0.00666 -0.213839 -0.444653 0.661948 0.394667 -0.104778 -0.104785 -0.004568 -0.097345 -0.097352 0.094663 161.128494 1.021189 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 8:06:06 485.429254 489.883452 498.174957 184.803238 1.006947 2/5/2024 8:12:55 91.984022 191.020004 1.006068 2/5/2024 8:06:14 504.299212 506.947836 518.594451 185.216019 1.006242 2/5/2024 8:13:03 97.06158 191.028488 1.005215 2/5/2024 8:06:21 504.64874 507.720143 512.761107 185.519455 1.005995 2/5/2024 8:13:10 97.96171 191.086639 1.005031 2/5/2024 8:06:29 505.902473 507.758941 518.55968 185.897369 1.006546 2/5/2024 8:13:18 96.522783 191.144775 1.004618 2/5/2024 8:06:36 503.49226 506.14329 513.367433 186.159027 1.006317 2/5/2024 8:13:25 96.231891 191.231995 1.004435 2/5/2024 8:06:44 500.573685 506.813583 515.738619 186.487885 1.006443 2/5/2024 8:13:33 97.807487 191.348282 1.004526 2/5/2024 8:06:51 501.559656 506.60123 515.627038 186.784058 1.006133 2/5/2024 8:13:40 97.920801 191.508163 1.004251 2/5/2024 8:06:59 501.628896 505.833716 504.580168 187.08931 1.006362 2/5/2024 8:13:48 97.899997 191.566315 1.004343 2/5/2024 8:07:06 501.294947 506.085964 511.386901 187.365479 1.005949 2/5/2024 8:13:55 97.262734 191.638992 1.004664 2/5/2024 8:07:14 502.076217 506.313861 507.312998 187.728882 1.005628 2/5/2024 8:14:03 97.645128 191.726212 1.004848 Date Time NO2 191C span Temp ( C )Pressure (atm) 2/5/2024 8:09:23 94.63613 191.613556 1.010941 2/5/2024 8:09:31 137.861959 191.71167 1.009622 2/5/2024 8:09:39 141.10957 191.726212 1.009208 2/5/2024 8:09:46 142.223286 191.784348 1.009897 2/5/2024 8:09:53 143.0042 191.75528 1.009071 2/5/2024 8:10:01 143.541289 191.740738 1.008566 2/5/2024 8:10:09 143.11235 191.715302 1.009616 2/5/2024 8:10:16 143.478382 191.697128 1.008887 2/5/2024 8:10:23 146.538941 191.682602 1.009025 2/5/2024 8:10:31 146.982257 191.66806 1.008795 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 8:14:32 12.750099 32.372685 15.809582 191.749222 0.982665 2/5/2024 8:24:07 93.927039 191.93576 1.006711 2/5/2024 8:14:39 267.914238 295.849371 263.605845 191.71167 0.996264 2/5/2024 8:24:14 96.926975 191.886093 1.006225 2/5/2024 8:14:47 481.2111 493.570987 485.64969 191.624451 1.000212 2/5/2024 8:24:22 96.447997 191.827957 1.006776 2/5/2024 8:14:54 491.025737 499.960984 495.132653 191.551773 1.000349 2/5/2024 8:24:29 97.395076 191.857025 1.006684 2/5/2024 8:15:02 489.945089 500.891427 497.11266 191.522705 0.99989 2/5/2024 8:24:37 96.719714 191.813416 1.007235 2/5/2024 8:15:09 490.797213 501.367472 497.565348 191.493637 1.00012 2/5/2024 8:24:44 97.49519 191.827957 1.007235 2/5/2024 8:15:17 492.146938 502.689813 497.426952 191.486359 0.999695 2/5/2024 8:24:52 97.428021 191.817047 1.006122 2/5/2024 8:15:25 498.076862 501.462855 495.256105 191.37735 0.999615 2/5/2024 8:24:59 97.577312 191.798889 1.006271 2/5/2024 8:15:32 496.319139 500.917521 498.811929 191.450027 0.999477 2/5/2024 8:25:07 97.177885 191.857025 1.006638 2/5/2024 8:15:39 497.061918 502.77615 496.948808 191.37735 0.998972 2/5/2024 8:25:15 97.367547 191.827957 1.006684 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 8:25:37 0.134767 0.730079 -0.363265 0.984756 191.827957 1.006317 2/5/2024 8:25:45 -0.059216 0.677225 -0.671087 1.852407 191.813416 1.006867 2/5/2024 8:25:52 0.051089 0.589246 0.140634 1.433021 191.798889 1.007372 2/5/2024 8:26:00 -0.089525 0.78293 -0.811611 1.227698 191.827957 1.006225 2/5/2024 8:26:07 -0.034858 0.638397 -0.824444 0.790951 191.842484 1.006454 2/5/2024 8:26:15 -0.213188 0.537858 0.193132 0.37933 191.842484 1.007005 2/5/2024 8:26:22 -0.231241 0.551438 0.080985 1.266185 191.791611 1.007567 2/5/2024 8:26:30 -0.024873 0.687423 0.235415 0.294466 191.857025 1.005903 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm) 2/5/2024 8:39:38 5.883125 13.388039 191.630508 0.998812 2/5/2024 8:39:45 5.898602 12.640194 191.624451 0.998972 2/5/2024 8:39:53 5.891672 11.395851 191.595383 0.99888 2/5/2024 8:40:00 5.935746 11.790811 191.624451 0.999661 2/5/2024 8:40:08 6.002939 12.641256 191.697128 1.00269 2/5/2024 8:41:01 5.961146 13.260738 191.8293 1.000781 2/5/2024 8:41:08 5.938547 12.682028 191.918808 1.001221 2/5/2024 8:41:16 4.981754 69.764553 191.813416 1.006684 2/5/2024 8:41:23 4.604782 104.250153 191.75528 1.004297 2/5/2024 8:41:31 5.538618 47.867506 191.726212 1.003012 2/5/2024 8:41:38 5.554479 43.650412 191.664429 1.003149 2/5/2024 8:41:46 5.619373 37.658614 191.638992 1.002507 2/5/2024 8:41:53 5.592698 42.14023 191.566315 1.003976 2/5/2024 8:42:01 5.52463 48.459172 191.537247 1.005559 2/5/2024 8:42:08 5.319861 60.682025 191.609924 1.004572 2/5/2024 8:42:16 5.316688 63.316081 191.609924 1.005582 2/5/2024 8:42:23 5.412653 59.591076 191.580841 1.005399 2/5/2024 8:43:08 5.324403 59.979942 191.691986 1.004896 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 11:54:40 488.040371 485.421359 463.851972 191.648239 0.994766 2/5/2024 11:52:45 94.535526 191.990494 1.04013 2/5/2024 11:54:48 510.22325 508.760853 488.795893 191.613556 0.994152 2/5/2024 11:52:53 96.277458 192.04599 1.039579 2/5/2024 11:54:55 510.175714 509.700219 498.919901 191.653519 0.994107 2/5/2024 11:53:00 95.48317 192.075058 1.040009 2/5/2024 11:55:03 510.895189 510.772164 487.62043 191.638992 0.994107 2/5/2024 11:53:08 96.489641 192.060532 1.039412 2/5/2024 11:55:11 509.933959 509.716368 489.832214 191.697128 0.994382 2/5/2024 11:53:16 97.599141 192.04599 1.039917 2/5/2024 11:55:18 510.69492 509.885318 489.34429 191.740738 0.994112 2/5/2024 11:53:23 95.425783 191.973312 1.040606 2/5/2024 11:55:26 511.288035 510.031026 491.261704 191.857025 0.993739 2/5/2024 11:53:31 95.72808 191.886093 1.038724 2/5/2024 11:55:33 509.311881 509.367899 489.292109 192.016922 0.993602 2/5/2024 11:53:38 97.392917 191.880646 1.038976 2/5/2024 11:55:41 509.679235 508.686599 494.665808 192.00238 0.994061 2/5/2024 11:53:46 96.339072 191.842484 1.039779 2/5/2024 11:55:48 509.527609 510.249743 494.519854 192.016922 0.993785 2/5/2024 11:54:06 96.360029 191.757706 1.03105 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 2/5/2024 11:53:00 0.066152 1.220142 -0.888007 192.075058 1.040009 2/5/2024 11:56:38 -1.115579 191.886093 0.998467 2/5/2024 11:53:08 -0.078763 1.05207 -1.78924 192.060532 1.039412 2/5/2024 11:56:45 -1.598279 191.769806 0.999431 2/5/2024 11:53:16 0.067171 1.12843 -1.770495 192.04599 1.039917 2/5/2024 11:56:52 -2.129146 191.769806 0.997962 2/5/2024 11:53:23 -0.327245 1.315136 -1.842327 191.973312 1.040606 2/5/2024 11:57:00 -1.847694 191.769806 0.999018 2/5/2024 11:53:31 -0.322508 1.265634 -1.437426 191.886093 1.038724 2/5/2024 11:57:07 0.782294 191.702591 0.99837 2/5/2024 11:53:38 -0.046092 1.291139 -0.349531 191.880646 1.038976 2/5/2024 11:57:15 -0.323638 191.653519 0.997871 2/5/2024 11:53:46 -0.116296 1.187162 -0.969134 191.842484 1.039779 2/5/2024 11:57:22 -0.660411 191.66806 0.998238 2/5/2024 11:54:06 -0.076054 1.587529 -2.158822 191.757706 1.03105 2/5/2024 11:57:30 -0.861609 191.697128 0.99833 SAMPLE SPIKE RECOVERY POST SYSTEM CAL POST SYSTEM ZERO PRE TEST 1 495.1 6.0 12.6 5.4 59.6 0.098 99.0% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 506.3 502.6 -0.1 0.74 -0.01 CO 502.1 503.7 0.0 -0.32 0.01 Propane 507.3 495.1 0.5 2.47 0.10 Ethylene 97.6 99.84 0.5 -2.20 0.47 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 502.8 502.6 0.6 0.04 0.13 CO 497.1 503.7 -0.1 -1.32 -0.01 Propane 496.9 495.1 -0.3 0.37 -0.07 Ethylene*97.4 99.84 1.1 -2.48 1.14 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 510.2 502.6 1.2 1.52 0.24 1.49 0.11 CO 509.5 503.7 -0.1 1.16 -0.02 2.47 0.01 Propane 494.5 495.1 -1.3 -0.12 -0.26 0.49 0.20 Ethylene*97.4 99.84 -1.2 -2.45 -1.18 0.03 2.32 *CTS Scans are conducted with Ethylene through the sample line. % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL Instrument/Make/Model Nicolet iS50 AUP2110269 CO MCO Nicolet iS50 AUP2110269 CI-14 M2CH4 Nicolet iS50 AUP2110269 NO MNO Nicolet iS50 AUP2110269 N02 impurity MKS FTIR C3H8 018143349 Triad Data Available Upon Request Airgas an Air Liquide company Part Number: Cylinder Number: Laboratory. PGVP Number: Gas Code: Jul 26,2023 Jul 06,2023 Jul "12,2023 Jul 12,2023 Jul 11,2023 Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele,UT 84074 Airgas.com CERTIFICATE OF ANALYSIS Grade of Product:EPA PROTOCOL STANDARD E05N199E15AOOOO CC734179 124 -Tooele (SAP)-UT B72023 Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date. 153-402805097-1 144.0 CF 2015 PSIG 660 Aug 08,2023 Expiration Date:Au 08 2031 Certification performed in accordance with "EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)"document EPA600/R-12/531 ,using the assay procedures listed.Analytical Methodology does not require correction for analytical interference,This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%.There are no significant impurities which affect the use of this calibration mixture.All concentrations are on amole/mole basis unless otherwise noted.The results relate only to the items tested.The report shall not be reproduced except in full without approval of the laboratory.Do Not Use This Cylinder below 100 psig,i.e.0.7 megapascals. ANALYTICAL RESULTS Component NOX CARBON MONOXIDE METHANE NITRIC OXIDE PROPANE Requested Concentration 500.0 PPM 500.0 PPM 500.0 PPM 500.0 PPM 500.0 PPM Balance Actual Concentration 502.6 PPM 503.7 PPM 508.2 PPM 502.6 PPM 495.1 Protocol Method Gl Gl Total Relative Uncertainty +1-0.6%NIST Traceable +1-0.7%NIST Traceable +/-0.7%NIST Traceable +1-0.6%NIST Traceable +/-0.9%NIST Traceable NITROGEN Type NTRM NTRM NTRM GMIS NTRM Lot ID 15060543 12409 0801 1609 15010116 1534012021 103 12010921 Cylinder No CC453965 D913660 K020818 KAL003474 ND73012 ND46380 CALIBRATION STANDARDS Concentration 491.9 PPM CARBON MONOXIDE/NITROGEN 15.01 PPM NITROGEN DIOXIDE/AIR 496.5 PPM METHANE/NITROGEN 494.6 PPM NITRIC OXIDE/NITROGEN 4.956 PPM NITROGEN DIOXIDE/NITROGEN 487 PPM PROPANE/AIR Uncertainty 0.6 0.6% 0.5% 1.6% 0.6% Assay Dates 08/01/2023,08/08/2023 08/01/2023 08/0112023 08/01/2023,08/08/2023 08/02/2023 Expiration Date Mar 05,2027 Feb 17,2023 Aug 08,2024 Aug 16,2027 Jun 15,2025 Apr 24,2024TheSRM,NTRM,PRM,or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Analytical Principle FTIR FTIR FTIR FTIR N02 impurity FTIR Last Multipoint Calibration pro ed for Release Page I of I Airgas an Air Liquide company Part Number: Cylinder Number: Laboratory: Analysis Date: Lot Number: Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele,UT 84074 Airgas.com CERT FICATE OF ANALYSIS Grade ofP oduct:PRIMARY STANDARD X02N199P15AD52 SG9166916BAL 124 -Tooele (SAP -UT Aug 01,2023 153-402805171-1 Expiratio Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: 153-402805171-1 140.0 CF 2015 PSIG 350 Primary Standard Gas Mixtures are tracea Date:Aug 01,2026 le to N.I.S.T.weights and/or N.I.S.T.Gas Mixture reference materials. Component ETHYLENE NITROGEN Req Conc 100.0 PPM Balance Approve for Re ALYTICAL RESULTS Actual Concentration (Mole 99.84 ase Analytical Uncertainty Page 1 of •1 Javelin – Moose Hollow 2-5-2024 Javelin – Moose Hollow 2-5-2024 Javelin – Moose Hollow 2-5-2024 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report Sample Filename: C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000154.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000077.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000078.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000079.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000080.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000081.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000082.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000083.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000084.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000085.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 50.62 6.72 -0.24 0.33 9.16 9.16 -5.09 --0-2795 1.04 Good NO2 191C 7.46 0.62 -0.03 0.03 0.66 0.66 -0.41 --0-488 0.99 Good N2O 191C -0.07 0.38 0.21 0.03 0.03 0.43 0.43 0.21 0.35 0 0.07 0-200 -Close to DL NH3 TE 191C 5.87 52.03 12.14 4.14 7.06 88.79 88.79 12.2 47.93 0.06 4.05 0-2995 -Close to DL H2O% (HIGH) 191C15.25 0.32 -0.02 0.03 0.51 0.51 -0.3 --0-40 -Good FORMALDEHYDE 191C9.18 1.31 7.71 0.24 0.27 1.5 1.5 8.56 8.56 0.85 2.57 0-69 -Close to DL FORMIC ACID 191C TE0.63 10.77 3.07 1.56 1.83 12.6 12.6 3.82 9.25 0.75 1.02 0-466 -Close to DL CH4 2900 CM-1 191C934.88 30.63 -1.69 2.46 56.74 56.74 -18.72 --0-3143 1 Good PROPANE 191C 12.07 1.28 -0.22 0.27 1.54 1.54 -0.75 --0-4976 0.94 Good PROPYLENE 191C TE-5.81 11.38 2.19 1.57 1.86 13.46 13.46 7.73 9.66 5.55 0.73 0-194 -Close to DL ETHANE 191C 73.44 2.92 -0.55 0.85 4.55 4.55 -1.48 --0-1004 -Good ETHYLENE 191C TE15.2 23.42 14.35 2.07 2.55 28.2 28.2 16.96 20.96 2.61 4.78 0-900 -Close to DL CO PPM 191C (1OF2)4.85 1.23 5.72 0.26 0.57 2.67 2.67 6.29 6.29 0.58 1.91 0-5010 1.05 Close to DL CO2% 191C 5.74 0.17 -0.01 0.02 0.24 0.24 -0.11 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.52 3.2 1.88 0.61 0.78 4.1 4.1 2.54 2.59 0.67 0.63 0-186 0.96 Close to DL ACETYLENE 191C 1.01 5.96 0.62 0.79 1.05 7.87 7.87 0.7 5.18 0.07 0.21 0-1016 -Close to DL SO2 191C 3.9 3.51 3.24 0.26 0.32 4.27 4.27 3.46 3.46 0.22 1.08 0-964 1.02 Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000213.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000077.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000078.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000079.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000080.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000081.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000082.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000083.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000084.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000085.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 53.86 5.4 -0.24 0.33 7.34 7.34 -3.73 --0-2795 1.04 Good NO2 191C 8.42 0.51 -0.03 0.03 0.54 0.54 -0.29 --0-488 0.99 Good N2O 191C 0.03 0.45 0.21 0.03 0.03 0.51 0.51 0.21 0.42 0 0.07 0-200 -Close to DL NH3 TE 191C 10.06 57.38 12.14 4.14 7.06 97.92 97.92 12.2 53.16 0.06 4.05 0-2995 -Close to DL H2O% (HIGH) 191C11.32 0.33 -0.02 0.03 0.53 0.53 -0.23 --0-40 -Good FORMALDEHYDE 191C7.41 1.25 7.71 0.24 0.27 1.41 1.41 8.56 8.56 0.85 2.57 0-69 -Close to DL FORMIC ACID 191C TE-0.55 12.06 3.07 1.56 1.83 14.12 14.12 3.82 10.54 0.75 1.02 0-466 -Close to DL CH4 2900 CM-1 191C999.99 26.85 -1.69 2.46 49.75 49.75 -20 --0-3143 1 Good PROPANE 191C 13.02 1.38 -0.22 0.27 1.66 1.66 -0.82 --0-4976 0.94 Good PROPYLENE 191C TE-0.72 13.65 2.19 1.57 1.86 16.15 16.15 7.73 12.09 5.55 0.73 0-194 -Close to DL ETHANE 191C 76.84 3.47 -0.55 0.85 5.4 5.4 -1.66 --0-1004 -Good ETHYLENE 191C TE13.47 51.04 14.35 2.07 2.55 62.99 62.99 16.96 48.63 2.61 4.78 0-900 -Close to DL CO PPM 191C (1OF2)5.07 2.58 5.72 0.26 0.57 5.57 5.57 6.29 6.29 0.58 1.91 0-5010 1.05 Close to DL CO2% 191C 6.13 0.21 -0.01 0.02 0.3 0.3 -0.12 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.11 3 1.88 0.61 0.78 3.85 3.85 2.54 2.54 0.67 0.63 0-186 0.96 Close to DL ACETYLENE 191C 0.16 6.67 0.62 0.79 1.05 8.8 8.8 0.7 5.91 0.07 0.21 0-1016 -Close to DL SO2 191C 1.67 2.1 3.24 0.26 0.32 2.56 2.56 3.46 3.46 0.22 1.08 0-964 1.02 Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000275.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000077.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000078.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000079.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000080.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000081.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000082.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000083.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000084.LAB C:\OLT\Data\Javelin\JAVELIN MH C5 2-5-24_000085.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 53.24 5.59 -0.24 0.33 7.61 7.61 -3.93 --0-2795 1.04 Good NO2 191C 8.59 0.51 -0.03 0.03 0.54 0.54 -0.29 --0-488 0.99 Good N2O 191C 0.06 0.45 0.21 0.03 0.03 0.52 0.52 0.21 0.43 0 0.07 0-200 -Close to DL NH3 TE 191C 11.17 58.29 12.14 4.14 7.06 99.49 99.49 12.2 54.05 0.06 4.05 0-2995 -Close to DL H2O% (HIGH) 191C11.59 0.33 -0.02 0.03 0.54 0.54 -0.23 --0-40 -Good FORMALDEHYDE 191C7.46 1.31 7.71 0.24 0.27 1.48 1.48 8.56 8.56 0.85 2.57 0-69 -Close to DL FORMIC ACID 191C TE-2.84 13.08 3.07 1.56 1.83 15.31 15.31 3.82 11.49 0.75 1.02 0-466 -Close to DL CH4 2900 CM-1 191C999.94 26.49 -1.69 2.46 49.07 49.07 -20 --0-3143 1 Good PROPANE 191C 12.34 1.44 -0.22 0.27 1.73 1.73 -0.9 --0-4976 0.94 Good PROPYLENE 191C TE2.25 14.67 2.19 1.57 1.86 17.35 17.35 7.73 13.06 5.55 0.73 0-194 -Close to DL ETHANE 191C 76.25 3.77 -0.55 0.85 5.87 5.87 -1.8 --0-1004 -Good ETHYLENE 191C TE12.86 27.14 14.35 2.07 2.55 33.5 33.5 16.96 24.75 2.61 4.78 0-900 -Close to DL CO PPM 191C (1OF2)5.04 2.81 5.72 0.26 0.57 6.07 6.07 6.29 6.29 0.58 1.91 0-5010 1.05 Close to DL CO2% 191C 6.16 0.22 -0.01 0.02 0.31 0.31 -0.13 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C0.22 3.11 1.88 0.61 0.78 3.99 3.99 2.54 2.54 0.67 0.63 0-186 0.96 Close to DL ACETYLENE 191C 0.19 7.44 0.62 0.79 1.05 9.83 9.83 0.7 6.69 0.07 0.21 0-1016 -Close to DL SO2 191C 1.4 1.94 3.24 0.26 0.32 2.36 2.36 3.46 3.46 0.22 1.08 0-964 1.02 Close to DL APPENDIX C Test Run Load %Site Rated Load, bhp Load Approx., bhp 1 68 1380 938.4 2 68 1380 938.4 3 69 1380 952.2 Engine Load Approximation based on Panel Levels APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 1770.03 938.4 8.8 68.65 0.42 0.87 5.80 0.02 0.04 24.91 0.15 0.30 11.51 2 1863.97 938.4 8.8 69.90 0.45 0.93 5.70 0.02 0.05 24.50 0.15 0.31 11.59 3 1838.39 952.2 8.8 70.91 0.44 0.93 5.70 0.02 0.05 25.91 0.16 0.33 11.86 943.0 8.8 69.82 0.44 0.91 5.73 0.02 0.05 25.11 0.15 0.31 11.65 Summary Average Levels Example Calculations: Javelin Energy Partners, Moose Hollow 24-23-C5, 4683 (6995) The following is a step-by-step calculation for the first test run conducted on the Moose Hollow 24-23-C5 4683 (6995). Test Parameters • Stack Diameter = 15 inches • Traverse Points = 16 • Ports = 2 • Barometric Pressure = 24.25 in Hg • Average O2 = 8.8% • Average CO2 = 6.54% • Load Approximation = 938.4 bhp • Moisture Content = 11.51% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 6.54% %O2 – Oxygen Content Of The Gas = 8.8% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 8.8 – 6.54) = 84.7% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 6.54) + (0.32 * 8.8) + (0.28 * 84.7) = 29.40 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.40 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 11.51% = MD * (1-BWS) + (18) * BWS = 29.40 * (1 – (11.51/ 100)) + (18 * (11.51/ 100)) = 28.09 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 0.796 in H2O TS – Average stack temperature (R) = 1193 R PB – Barometric pressure (in Hg) = 24.25 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.2 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 28.09 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 0.796 * ( 1193 / (((0.2/ 13.6) + 24.25) * 28.09)) = 75.65 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 15 inches BWS – Moisture content of the gas (%) = 11.51% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1193 R PB – Barometric pressure (in Hg) = 24.25 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.2 in H2O VS– Average Stack gas velocity (ft/sec) = 75.65 ft/sec = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (11.51/ 100)) * 75.65 *  * (((15 / 2) / 12))2) * 528 / 1193 * (24.25 + (0.2 / 13.6)) / 29.92 = 1770.03 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 1770.03 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 1770.03 *60 * 2.83168*10 -2 = 3007.3 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 68.65 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 3007.3 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 938.4 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (68.65 * 1.912*10 -3 * 3007.3 * 1) / 938.4 = 0.42 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.42 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 938.4 Bhp = g/Bhp-hr / 454 * Bhp = 0.42 / 454 * 938.4 = 0.87 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 5.80 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 3007.3 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 938.4 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (5.80 * 1.164*10 -3 * 3007.3 * 1) / 938.4 = 0.02 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.02 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 938.4 Bhp = g/Bhp-hr / 454 * Bhp = 0.02 / 454 * 938.4 = 0.04 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 24.91 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 3007.3 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 938.4 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (24.91 * 1.833*10 -3 * 3007.3 * 1) / 938.4 = 0.15 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.15 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 938.4 Bhp = g/Bhp-hr / 454 * Bhp = 0.15 / 454 * 938.4 = 0.30 lbs/hr APPENDIX E -- FTIR Engine Test Sheet Company Name ~"'eh,. Location / Unit I.D. Type of Test Completed Field Technician (5) Yn()OSc­H-1lI11o...." ~v\lr David Martinez ~Y~l$-C~ Client Rep and/or State Rep Date ~ -_~ -cl'l Engine Make Engine Model Enaine SIN Port Distance A Port Distance B exhaust Diameter (inches) Calibration Gas NO (ppm) Non-Resettable Run Time Hours Stack Diagram ~>1 CO (ppm) CC734179 503.7 /Propane (ppm) CC734179 495.1 / BN02 (ppm) CC510760 ,., f147 Ethylene (ppm) SG9166916BAL ,99.84 I "Methane (ppm) ...CC734179 508.2 1.....Acetaldehvde (ppm) CC358296 30.18 lA1 ~"~,".~._-,,,..,.,.~,6~h1C-111 R w..,··.....~~--,·<>·Nl.f:.nr? '"d~ '7>/..\1 '"'''', 'T t A~ .,\-" "\,.5 " ~, Cylinder # Concentration .. t.~_CC734179 502.6 ". Test 1 Test 2 Test 3 Time of Reading Atm Pressure (in Hg) Atm Temp CF) Engine RPM *Manifold Pres. Vac(") or ,litoost(gsi) or Boost (psia) Manifold Temn CF) {(,'4 "I fcl-. ~\.). ~ '1\. ~ \ ~d-{. '~l,\ \\'1.'\ • - q:/fS d. '1.1 1 .3 ~, L-l \~~6 'J..(,. " \ \I--j., .. _ . 10 ;'16 "'J4dl 377. '7 fa ~i. '~6,'1 II~, I Psuction psi) Stage 1 Tsuction ('F) Stage 1 ,. ~L-I -----_. \ 3l\ -" 3'1 ...--'-'" Pdischarae (osi) Staae 1 \ OCr\ 10 'jCj 100'7 Psuction (psi) Stage 2 Tsuction CF) Stage 2 Pdischaroe (psi) Staae 2 Psuction psi) Stage 3 Tsuction OF) Stage 3 -- Pdischarae (osi) Staoe 3 / Psuction (psi) Stage 4 Tsuction 'F) Stage 4 , Pdischarge (psi) Stage 4 Gas Throuohout (mmcf/d) or ( Pre CatTemp CF) Post Cat Temp rF) Cat Differential Pres. (" of H2O) Humidity % , mi== t= l-B"A,..) £\1"Po., I'd,. b\.\ ·15"' 'bj;ij 5.S - \ J.t,~,\ 7la b~Y '31 ~, - 0 J63.7 7/6 hR''1 3,(-­02% C02 % Dry ~ LOAD % W'aneU'or (Estimated) kmition TiminaTF) AFR Setting mV (Left Bank) AFR Settina mV (Rioht Bank) '11'.\( £.."7 t~ ~.\ d...C\. ~I ~.r t.l 6f(. 'dod-.\ }/v-\- 5-'.'6 t:.y 61 ~~.I -~'f.} Rev I • Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-). Eg: (+12") or (- 5") -i\6d~' »_.>~ 9/17/2019 COMPANY NAME:Javlin COMPANY LOCATION:Moose Hollow C5 DATE:2/5/2024 STACK DIAMETER (inches):15 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:8.8 AVERAGE O2:8.8 AVERAGE O2:8.8 AVERAGE CO2:6.54 AVERAGE CO2:6.7 AVERAGE CO2:6.8 BARO PRESSURE:24.25 BARO PRESSURE:24.27 BARO PRESSURE:23.27 Point Insertion DepthDP (H2O)Ts (deg F)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg F)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg F)Stat P (H2O) 1 0.5 0.62 715 0.22 1 0.5 0.65 718 0.23 1 0.5 0.67 718 0.23 2 1.575 0.67 2 1.575 0.69 2 1.575 0.68 3 2.91 0.66 3 2.91 0.73 3 2.91 0.7 4 4.845 0.63 4 4.845 0.72 4 4.845 0.73 5 10.155 0.6 5 10.155 0.7 5 10.155 0.74 6 12.09 0.59 6 12.09 0.68 6 12.09 0.72 7 13.425 0.56 7 13.425 0.65 7 13.425 0.71 8 14.5 0.55 8 14.5 0.61 8 14.5 0.68 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 0.63 715 0.22 1 0.5 0.68 718 0.23 1 0.5 0.68 718 0.23 2 1.575 0.66 2 1.575 0.7 2 1.575 0.7 3 2.91 0.71 3 2.91 0.72 3 2.91 0.72 4 4.845 0.69 4 4.845 0.75 4 4.845 0.76 5 10.155 0.66 5 10.155 0.74 5 10.155 0.74 6 12.09 0.67 6 12.09 0.72 6 12.09 0.73 7 13.425 0.62 7 13.425 0.71 7 13.425 0.71 8 14.5 0.64 8 14.5 0.69 8 14.5 0.69 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 Worksheet: O2 Stratification Client:Javlin Location:Moose Hollow C5 Date:2/5/2024 PD:15 DD:34 YES Method 1 Criteria Met UD:36 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 2.49 8.80 A 2 7.50 8.80 A 3 12.50 8.80 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 8.80 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification)