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HomeMy WebLinkAboutDAQ-2024-0042771 DAQC-045-24 Site ID 10335 (B4) MEMORANDUM TO: STACK TEST FILE – TESORO REFINING AND MARKETING COMPANY – Salt Lake City Refinery THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Paul Morris, Environmental Scientist DATE: January 12, 2024 SUBJECT: Source: FCCU WGS Contact: Crystal Beffa – 606-369-4370 Location: 474 West 900 North, SLC, Salt Lake County, Utah Test Contractor: Alliance Technical Group, LLC Permit/AO#: AO DAQE-AN103350075-18, dated January 11, 2018 FRS ID# UT000000493500004 Action Code: TR Subject: Review of revised stack test report received January 12, 2024 On January 12, 2024, Utah Division of Air Quality (DAQ) received a revised report for the FCCU wet gas scrubber. A three-run test was performed on October 24, 2023, to demonstrate compliance with emission limits as defined in condition II.B.8.a. The test results are as follow: Source Test Date Pollutant DAQ Result Test Result Limit FCCU 10/24/2023 PM 10 0.65 lbs/hr 0.65 lbs/hr Na DEVIATIONS: No deviations reported. CONCLUSION: The FCCU PM10 emission factor appears to be acceptable. RECOMMENDATION: None HPV: No ATTACHMENTS: Revised stack test report received January 12, 2024, and DAQ generated spreadsheets. 6 , 3 Source Test Report Tesoro Refining and Marketing Company Salt Lake City Refinery 474 West 900 North Salt Lake City, UT 84103 Source Tested: Wet Gas Scrubber Test Date: October 24, 2023 Project No. AST-2023-2130-003R1 Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Source Test Report Test Program Summary AST-2023-2130-003R1 MPC – Salt Lake City, UT Page i Regulatory Information Permit No. DAQE-AN103350075-18 Source Information Source Name Source ID Target Parameters FCCU WGS PS#4 PM, PM2.5, PM10 Contact Information Test Location Test Company Analytical Laboratories Tesoro Refining and Marketing Company Salt Lake City Refinery 474 West 900 North Salt Lake City, UT 84103 Crystal Beffa crbeffa@marathonpetroleum.com (606) 369-4370 Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Project Manager/Field Team Leader Charles Horton charles.horton@alliancetg.com (352) 663-7568 QA/QC Manager Kathleen Shonk katie.shonk@alliancetg.com (812) 452-4785 Report Coordinator Sarah Perry sarah.perry@alliancetg.com Alliance Technical Group, LLC 5530 Marshall Street Arvada, CO 80002 Eric Grosjean eric.grosjean@alliancetg.com (303) 420-5949 Particle Technology Labs 555 Rogers St. #4 Downers Grove, IL 60515 Aubrey Montana amontana@particlelabs.com (630) 969-2703 2 of 84 Source Test Report Certification Statement AST-2023-2130-003R1 MPC – Salt Lake City, UT Page ii Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the relevant sections in the test report. This report is only considered valid once an authorized representative of Alliance has signed in the space provided below; any other version is considered draft. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. Charles Horton, QSTI Alliance Technical Group, LLC Date 3 of 84 Source Test Report Table of Contents AST-2023-2130-003R1 MPC – Salt Lake City, UT Page iii TABLE OF CONTENTS 1.0 Introduction .................................................................................................................................................. 1-1 1.1 Process/Control System Descriptions ...................................................................................................... 1-1 1.2 Project Team ............................................................................................................................................ 1-1 1.3 Site-Specific Test Plan & Notification ..................................................................................................... 1-1 1.4 Report Revision Notes ............................................................................................................................. 1-1 2.0 Summary of Results ..................................................................................................................................... 2-1 3.0 Testing Methodology .................................................................................................................................... 3-1 3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate ..... 3-1 3.2 U.S. EPA Reference Test Method 3/3A – Oxygen/Carbon Dioxide ........................................................ 3-1 3.3 U.S. EPA Reference Test Method 4 – Moisture Content ......................................................................... 3-1 3.4 U.S. EPA Reference Test Methods 5 and 202 – Total Particulate Matter ................................................ 3-1 3.5 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3/3A ....................................... 3-2 LIST OF TABLES Table 1-1: Project Team ........................................................................................................................................... 1-1 Table 2-1: Summary of Results ................................................................................................................................ 2-1 Table 3-1: Source Testing Methodology .................................................................................................................. 3-1 APPENDICES Appendix A Sample Calculations Appendix B Field Data Appendix C Laboratory Data Appendix D Quality Assurance/Quality Control Data Appendix E Process Operating/Control System Data 4 of 84 Introduction 5 of 84 Source Test Report Introduction AST-2023-2130-003R1 MPC – Salt Lake City, UT Page 1-1 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by Marathon Petroleum Corporation (MPC) to conduct compliance testing at the Tesoro Refining and Marketing Company (Tesoro) Salt Lake City, Utah refinery. Portions of the facility are subject to provisions of the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-AN103350075-18. Testing was conducted to determine the emission rates of particulate matter (PM), particulate matter less than 10 microns (PM10) and particulate matter less than 2.5 microns (PM2.5) from the exhaust of the Fluidized Catalytic Cracking Unit (FCCU) Belco Wet Gas Scrubber (WGS) Electrostatic Precipitator (ESP) for the PM10 Cap calculation per the annual requirement detailed in the UDAQ permit. Following the gravimetric analysis, the Method 5 front half PM samples were analyzed for particle size distribution (PSD) by Particle Technology Labs (PTL) in Downers Grove, Illinois. PM mass emission rates are reported as filterable PM2.5, filterable PM10 and total PM (filterable plus condensable PM). 1.1 Process/Control System Descriptions The FCCU Regenerator / Carbon Monoxide Boiler (Heat Recovery Unit) is equipped with CONOx oxygen injection, ammonia injection, and an ESP/LoTOx (WGS) system for emission controls. Emissions are exhausted through one (1) stack designated as PS#4. 1.2 Project Team Personnel involved in this project are identified in the following table. Table 1-1: Project Team MPC Personnel Crystal Beffa Alliance Personnel Charles Horton Xander Krahn Supilani Mailei 1.3 Site-Specific Test Plan & Notification Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by MPC. 1.4 Report Revision Notes This report was revised on January 12, 2024 (R1). On January 8, 2024, UDEQ contacted Alliance regarding a discrepancy in the filterable PM10 percentage calculations. Alliance investigated and discovered a miscalculation in the determination of the filterable PM10 emission results. This report revision corrects those calculations and updates results shown in Table 2-1 and included in Appendix B. No other changes were made. 6 of 84 Summary of Results 7 of 84 Source Test Report Summary of Results AST-2023-2130-003R1 MPC – Salt Lake City, UT Page 2-1 2.0 Summary of Results Alliance conducted compliance testing at the Tesoro Salt Lake City, Utah refinery on October 24, 2023. Testing consisted of determining the emission rates of PM, PM10 and PM2.5 from the exhaust of the FCCU Belco WGS ESP. Table 2-1 provides a summary of the emission testing results. Any difference between the summary results listed in the following table and the detailed results contained in appendices is due to rounding for presentation. Table 2-1: Summary of Results Run Number Run 1 Run 2 Run 3 Average Date 10/24/23 10/24/23 10/24/23 -- Filterable Particulate Matter 2.5 Data Concentration, grain/dscf 0.00030 0.00010 0.00016 0.00019 Emission Rate, lb/hr 0.21 0.073 0.11 0.13 Filterable Particulate Matter 10 Data Concentration, grain/dscf 0.0016 0.00061 0.00061 0.00093 Emission Rate, lb/hr 1.07 0.44 0.43 0.65 Total Particulate Matter 2.5 Data Concentration, grain/dscf 0.0028 0.0025 0.0013 0.0022 Emission Rate, lb/hr 2.1 2.0 1.0 1.7 Total Particulate Matter 10 Data Concentration, grain/dscf 0.0041 0.0030 0.0017 0.0029 Emission Rate, lb/hr 2.8 2.2 1.2 2.1 8 of 84 Testing Methodology 9 of 84 Source Test Report Testing Methodology AST-2023-2130-003R1 MPC – Salt Lake City, UT Page 3-1 3.0 Testing Methodology The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method descriptions are provided below while quality assurance/quality control data is provided in Appendix D. Table 3-1: Source Testing Methodology Parameter U.S. EPA Reference Test Methods Notes/Remarks Volumetric Flow Rate 1 & 2 Full Velocity Traverses Oxygen / Carbon Dioxide 3 / 3A Integrated Bag / Instrumental Analysis Moisture Content 4 Gravimetric Analysis Total Particulate Matter 5 / 202 Isokinetic Sampling 3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA Reference Test Method 1. To determine the minimum number of traverse points, the upstream and downstream distances were equated into equivalent diameters and compared to Figure 1-1 in U.S. EPA Reference Test Method 1. Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type thermocouple and pyrometer. Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2. 3.2 U.S. EPA Reference Test Method 3/3A – Oxygen/Carbon Dioxide The oxygen (O2) and carbon dioxide (CO2) testing was conducted in accordance with U.S. EPA Reference Test Method 3/3A. One (1) integrated Tedlar bag sample was collected during each test run. The bag samples were analyzed on site with a gas analyzer. The remaining stack gas constituent was assumed to be nitrogen for the stack gas molecular weight determination. The quality control measures are described in Section 3.5. 3.3 U.S. EPA Reference Test Method 4 – Moisture Content The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on the same balance to determine the amount of moisture condensed. 3.4 U.S. EPA Reference Test Methods 5 and 202 – Total Particulate Matter The total particulate matter (filterable and condensable PM) testing was conducted in accordance with U.S. EPA Reference Test Methods 5 and 202. The complete sampling system consisted of a stainless steel nozzle, glass-lined probe, pre-weighed quartz filter, coil condenser, un-weighed Teflon filter, gas conditioning train, pump and calibrated dry gas meter. The gas conditioning train consisted of a coiled condenser and four (4) chilled impingers. The first, and second impingers were initially empty, the third contained 100 mL of de-ionized water and the last 10 of 84 Source Test Report Testing Methodology AST-2023-2130-003R1 MPC – Salt Lake City, UT Page 3-2 impinger contained 200-300 grams of silica gel. The un-weighed 90 mm Teflon filter was placed between the second and third impingers. The probe liner heating system was maintained at a temperature of 248 ±25°F, and the impinger temperature was maintained at 68°F or less throughout testing. The temperature of the Teflon filter was maintained greater than 65°F but less than or equal to 85°F. Following the completion of each test run, the sampling train was leak checked at a vacuum pressure greater than or equal to the highest vacuum pressure observed during the run. Condensate was collected in the first dry impinger, therefore the front-half of the sample train (the nozzle, probe, and heated pre-weighed filter) was removed in order to purge the back-half of the sample train (coil condenser, first and second impingers and CPM filter). A glass bubbler was inserted into the first impinger. If needed, de-ionized ultra-filtered (DIUF) water was added to the first impinger to raise the water level above the bubbler, then the coil condenser was replaced. Zero nitrogen was connected to the condenser, and a 60-minute purge at 14 liters per minute was conducted. After the completion of the nitrogen purge the impinger contents were measured for moisture gain. The pre-weighed quartz filter was carefully removed and placed in container 1. The probe, nozzle and front half of the filter holder were rinsed six (6) and three (3) times with acetone to remove any adhering particulate matter and these rinses were recovered in container 2. All containers were sealed, labeled and liquid levels marked for transport to the identified laboratory for filterable particulate matter analysis. The contents of impingers 1 and 2 were recovered in container CPM Cont. #1. The back half of the filterable PM filter holder, the coil condenser, impingers 1 and 2 and all connecting glassware were rinsed with DIUF water and then rinsed with acetone, followed by hexane. The water rinses were added to container CPM Cont. #1 while the solvent rinses were recovered in container CPM Cont. #2. The Teflon filter was removed from the filter holder and placed in container CPM Cont. #3. The front half of the condensable PM filter holder was rinsed with DIUF water and then with acetone, followed by hexane. The water rinse was added to container CPM Cont. #1 while the solvent rinses were added to container CPM Cont. #2. All containers were sealed, labeled and liquid levels marked for transport to the identified laboratory for condensable particulate matter analysis. 3.5 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3/3A Cylinder calibration gases used met EPA Protocol 1 (+/- 2%) standards. Copies of all calibration gas certificates can be found in the Quality Assurance/Quality Control Appendix. Low-Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High-Level calibration gases were sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5% absolute difference. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance’s office, all written and electronic data was relinquished to the report coordinator and then a final review was performed by the Project Manager. 11 of 84 Appendix A 12 of 84 Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: Meter Pressure (Pm), in. Hg where, Pb 25.57 = barometric pressure, in. Hg ΔH 2.388 = pressure differential of orifice, in H2O Pm 25.75 = in. Hg Absolute Stack Gas Pressure (Ps), in. Hg where, Pb 25.57 = barometric pressure, in. Hg Pg -0.01 = static pressure, in. H2O Ps 25.57 = in. Hg Standard Meter Volume (Vmstd), dscf where, Y 1 = meter correction factor Vm 52.267 = meter volume, cf Pm 25.75 = absolute meter pressure, in. Hg Tm 517.1 = absolute meter temperature, oR Vmstd 45.891 = dscf Standard Wet Volume (Vwstd), scf where, Vlc 402.9 = weight of H2O collected, g Vwstd 19.001 = scf Moisture Fraction (BWSsat), dimensionless (theoretical at saturated conditions) where, Ts 145.0 = stack temperature, °F Ps 25.57 = absolute stack gas pressure, in. Hg BWSsat 0.259 = dimensionless Moisture Fraction (BWS), dimensionless (measured) where, Vwstd 19.001 = standard wet volume, scf Vmstd 45.891 = standard meter volume, dscf BWS 0.293 = dimensionless MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 1 PM Pm ൌ Pb ൅ Δ H 13.6 Ps ൌ Pb ൅ Pg 13.6 𝑉𝑚𝑠𝑡𝑑 ൌ 17.636 ൈ Y ൈ Vm ൈ Pm 𝑇𝑚 Vwstd ൌ 0.04716 ൈ Vlc BWSsat ൌ 10଺.ଷ଻ି ଶ,଼ଶ଻ ୘ୱାଷ଺ହ Ps BWS ൌ Vwstd ሺVwstd ൅ Vmstdሻ 13 of 84 Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 1 PM Moisture Fraction (BWS), dimensionless where, BWSsat 0.259 = moisture fraction (theoretical at saturated conditions) BWSmsd 0.293 = moisture fraction (measured) BWS 0.259 Molecular Weight (DRY) (Md), lb/lb-mole where, CO2 14.8 = carbon dioxide concentration, % O2 5.1 = oxygen concentration, % Md 30.57 = lb/lb mol Molecular Weight (WET) (Ms), lb/lb-mole where, Md 30.57 = molecular weight (DRY), lb/lb mol BWS 0.259 = moisture fraction, dimensionless Ms 27.32 = lb/lb mol Average Velocity (Vs), ft/sec where, Cp 0.840 = pitot tube coefficient Δ P1/2 0.722 = velocity head of stack gas, (in. H2O)1/2 Ts 604.7 = absolute stack temperature, °R Ps 25.57 = absolute stack gas pressure, in. Hg Ms 27.32 = molecular weight of stack gas, lb/lb mol Vs 48.3 = ft/sec Average Stack Gas Flow at Stack Conditions (Qa), acfm where, Vs 48.3 = stack gas velocity, ft/sec As 50.27 = cross-sectional area of stack, ft2 Qa 145,582 = acfm Average Stack Gas Flow at Standard Conditions (Qs), dscfm where, Qa 145,582 = average stack gas flow at stack conditions, acfm BWS 0.259 = moisture fraction, dimensionless Ps 25.57 = absolute stack gas pressure, in. Hg Ts 604.7 = absolute stack temperature, °R Qs 80,445 = dscfm Md ൌ ሺ0.44 ൈ % COଶ ሻ ൅ ሺ0.32 ൈ % O2ሻ ൅ ሺ0.28 ሺ100 െ % COଶ െ % O2ሻሻ Ms ൌ Md ሺ1 െ BWSሻ ൅ 18.015 ሺBWSሻ Qa ൌ 60 ൈ Vs ൈ As Qs ൌ 17.636 ൈ Qa ൈ ሺ1 െ BWSሻ ൈ Ps Ts Vs ൌ 85.49 ൈ Cp ൈ ሺΔ P ଵ/ଶ ሻ avg ൈ Ts Ps x Ms BWS ൌ BWSmsd unless BWSsat ൏ BWSmsd 14 of 84 Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 1 PM Dry Gas Meter Calibration Check (Yqa), dimensionless where, Y 1 = meter correction factor, dimensionless Θ 60 = run time, min. Vm 52.267 = total meter volume, dcf Tm 517.1 = absolute meter temperature, °R ΔH@ 1.922 = orifice meter calibration coefficient, in. H2O Pb 25.57 = barometric pressure, in. Hg ΔH avg 2.388 = average pressure differential of orifice, in H2O Md 30.57 = molecular weight (DRY), lb/lb mol (Δ H)1/2 1.534 = average squareroot pressure differential of orifice, (in. H2O)1/2 Yqa 0.9 = percent Volume of Nozzle (Vn), ft3 where, Ts 604.7 = absolute stack temperature, °R Ps 25.57 = absolute stack gas pressure, in. Hg Vlc 402.9 = volume of H2O collected, ml Vm 52.267 = meter volume, cf Pm 25.75 = absolute meter pressure, in. Hg Y 1.000 = meter correction factor, unitless Tm 517.1 = absolute meter temperature, oR Vn 86.966 = volume of nozzle, ft3 Isokinetic Sampling Rate (I), % where,* Vn 86.966 = nozzle volume, ft3 θ 60.0 = run time, minutes An 0.00044 = area of nozzle, ft2 Vs 48.3 = average velocity, ft/sec I 107.9 = % Filterable PM Concentration (Cs), grain/dscf where, Mn 20.2 = filterable PM mass, mg Vmstd 45.891 = standard meter volume, dscf Cs 0.0068 = grain/dscf C௦ ൌ M୬ ൈ 0.0154 Vmstd Yqa ൌ Y െ Θ Vm 0.0319 ൈ Tm ൈ 29 Δ𝐻@ ൈ Pb ൅ Δ Havg. 13.6 ൈ𝑀𝑑 ΔH avg. 𝑌 ൈ 100 Vn ൌ 𝑇𝑠 𝑃𝑠 0.002669 ൈ𝑉𝑙𝑐൅Vm ൈ𝑃𝑚ൈ𝑌 𝑇𝑚 15 of 84 Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 1 PM Filterable PM Emission Rate (PMR), lb/hr where, Cs 0.0068 = filterable PM concentration, grain/dscf Qs 80,445 = average stack gas flow at standard conditions, dscfm PMR 4.7 = lb/hr Filterable PM Emission Rate (ERPMTPY), ton/yr where, PMR 4.7 = filterable PM emission rate, lb/hr ERPMTPY 20.5 = ton/yr Condensable PM Concentration (CCPM), grain/dscf where, MCPM 7.5 = condensable PM mass, mg Vmstd 45.891 = standard meter volume, dscf CCPM 0.0025 = grain/dscf Condensable PM Emission Rate (ERCPM), lb/hr where, CCPM 0.0025 = condensable PM concentration, grain/dscf Qs 80,445 = average stack gas flow at standard conditions, dscfm ERCPM 1.7 = lb/hr Condensable PM Emission Rate (ERCPMTPY), ton/yr where, ERCPM 1.7 = condensable PM emission rate, lb/hr ERCPMTPY 7.6 = ton/yr Total PM Concentration (CTPM), grain/dscf where, Cs 0.0068 = filterable PM concentration, grain/dscf CCPM 0.0025 = condensable PM concentration, grain/dscf CTPM 0.0093 = grain/dscf PMR ൌ Cୱ ൈ Qs ൈ 60 7.0E ൅ 03 Cେ୔୑ ൌ Mେ୔୑ ൈ 0.0154 Vmstd ERେ୔୑  ൌ Cେ୔୑ ൈ Qs ൈ 60 𝑚𝑖𝑛 ℎ𝑟 7.0E ൅ 03 𝐸𝑅஼௉ெ்௉௒ ൌ 𝐸𝑅஼௉ெ ൈ 8,760 ℎ𝑟 𝑦𝑟 2.0𝐸൅03 𝐶்௉ெ ൌ𝐶ௌ ൅𝐶஼௉ெ ER ୔୑୘୔ଢ଼ ൌ PMR ൈ 8,760 2.0E ൅ 03 16 of 84 Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 1 PM Total PM Emission Rate (ERTPM), lb/hr where, PMR 4.7 = filterable PM emission rate, lb/hr ERCPM 1.7 = condensable PM emission rate, lb/hr ERTPM 6.4 = lb/hr Total PM Emission Rate (ERTPMTPY), ton/yr where, ERPMTPY 20.5 = filterable PM emission rate, ton/yr ERCPMTPY 7.6 = condensable PM emission rate, ton/yr ERTPMTPY 28.1 = ton/yr 𝐸𝑅்௉ெ ൌ𝑃𝑀𝑅൅𝐸𝑅஼௉ெ 𝐸𝑅்௉ெ்௉௒ ൌ𝐸𝑅௉ெ்௉௒ ൅𝐸𝑅஼௉ெ்௉௒ 17 of 84 Appendix B 18 of 84 Emission Calculations Location Source Project No. Parameter Run Number Run 1 Run 2 Run 3 Average Date 10/24/23 10/24/23 10/24/23 -- Start Time 9:45 12:00 14:12 -- Stop Time 10:55 13:20 15:26 -- Run Time, min (θ)60.0 60.0 60.0 60.0 Coke Burn Rate, lb/hr (FR)29,101 29,097 29,103 29,100 Barometric Pressure, in. Hg (Pb)25.57 25.62 25.62 25.60 Meter Correction Factor (Y)1 1 1 1 Orifice Calibration Value (ΔH @)1.922 1.922 1.922 1.922 Meter Volume, ft3 (Vm)52.267 53.688 47.295 51.083 Meter Temperature, °F (Tm)57.5 67.5 67.8 64.3 Meter Temperature, °R (Tm)517.1 527.1 527.5 523.9 Meter Orifice Pressure, in. WC (ΔH)2.388 2.492 1.888 2.256 Volume H2O Collected, mL (Vlc)402.9 282.0 172.2 285.7 Nozzle Diameter, in (Dn)0.285 0.285 0.285 0.285 Area of Nozzle, ft2 (An)0.0004 0.0004 0.0004 0.0004 Filterable PM Mass, mg (Mn)20.2 11.7 6.9 12.9 Condensable PM Mass, mg (MCPM)7.5 7.2 3.0 5.9 PM2.5 PSD Results, % of Total Filterable PM (PSDPM2.5)4.4 2.6 6.0 4.3 PM10 PSD Results, % of Total Filterable PM (PSDPM10)22.9 15.7 23.3 20.6 Filterable PM2.5 Mass, mg (MPM2.5)0.9 0.3 0.4 0.5 Filterable PM10 Mass, mg (MPM10)4.6 1.8 1.6 2.7 Standard Meter Volume, ft3 (Vmstd)45.891 46.348 40.730 44.323 Standard Water Volume, ft3 (Vwstd)19.001 13.299 8.121 13.474 Moisture Fraction Measured (BWSmsd)0.293 0.223 0.166 0.227 Moisture Fraction @ Saturation (BWSsat)0.259 0.277 0.351 0.296 Moisture Fraction (BWS)0.259 0.223 0.166 0.216 Meter Pressure, in Hg (Pm)25.75 25.80 25.76 25.77 Volume at Nozzle, ft3 (Vn)86.966 80.166 66.712 77.95 Isokinetic Sampling Rate, (%)(I)107.9 104.1 93.2 101.7 DGM Calibration Check Value, (+/- 5%)(Yqa)0.9 0.6 1.2 0.9 Filterable PM Concentration, grain/dscf (Cs)0.0068 0.0039 0.0026 0.0044 Filterable PM Emission Rate, lb/hr (PMR)4.7 2.8 1.9 3.1 Filterable PM Emission Rate, ton/yr (ERFPM)20.5 12.3 8.1 13.6 Condensable PM Concentration, grain/dscf (CCPM)0.0025 0.0024 0.0011 0.0020 Condensable PM Emission Rate, lb/hr (ERCPM)1.7 1.7 0.8 1.4 Condensable PM Emission Rate, ton/yr (ERCPM)7.6 7.6 3.5 6.2 Total PM Concentration, grain/dscf (CTPM)0.0093 0.0063 0.0038 0.0065 Total PM Emission Rate, lb/hr (ERTPM)6.4 4.5 2.7 4.5 Total PM Emission Rate, ton/yr (ERTPM)28.1 19.9 11.6 19.9 Filterable PM2.5 Concentration, grain/dscf (CPM2.5)0.00030 0.00010 0.00016 0.00019 Filterable PM2.5 Emission Rate, lb/hr (ERPM2.5)0.21 0.073 0.11 0.13 Filterable PM2.5 Emission Rate, ton/yr (ERPM2.5)0.90 0.32 0.49 0.57 Filterable PM10 Concentration, grain/dscf (CPM10)0.00156 0.00061 0.00061 0.00093 Filterable PM10 Emission Rate, lb/hr (ERPM10)1.07 0.44 0.43 0.65 Filterable PM10 Emission Rate, ton/yr (ERPM10)4.7 1.9 1.89 2.8 Total PM2.5 Concentration, grain/dscf (CTPM2.5)0.0028 0.0025 0.0013 0.0022 Total PM2.5 Emission Rate, lb/hr (ERTPM2.5)2.8 2.2 1.2 2.1 Total PM2.5 Emission Rate, ton/yr (ERTPM2.5)8.5 7.9 4.0 6.8 Total PM10 Concentration, grain/dscf (CTPM10)0.0041 0.0030 0.0017 0.0029 Total PM10 Emission Rate, lb/hr (ERTPM10)2.8 2.2 1.2 2.1 Total PM10 Emission Rate, ton/yr (ERTPM10)12.3 9.5 5.4 9.1 MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 EMISSION CALCULATIONS ISOKINETIC DATA INPUT DATA PM 19 of 84 Emission Calculations Location Source Project No. Parameter Run Number Run 1 Run 2 Run 3 Average Date 10/24/23 10/24/23 10/24/23 -- Start Time 9:45 12:00 14:12 -- Stop Time 10:55 13:20 15:26 -- Run Time, min 60.0 60.0 60.0 60.0 Point 1 0.70 0.77 0.42 0.63 Point 2 0.55 0.81 0.40 0.59 Point 3 0.50 0.71 0.46 0.56 Point 4 0.51 0.48 0.41 0.47 Point 5 0.49 0.45 0.48 0.47 Point 6 0.46 0.68 0.51 0.55 Point 7 0.41 0.65 0.54 0.53 Point 8 0.44 0.58 0.59 0.54 Point 9 0.37 0.56 0.56 0.50 Point 10 0.38 0.61 0.49 0.49 Point 11 0.39 0.60 0.43 0.47 Point 12 0.40 0.62 0.46 0.49 Point 13 0.65 0.48 0.45 0.53 Point 14 0.57 0.40 0.50 0.49 Point 15 0.55 0.43 0.49 0.49 Point 16 0.67 0.44 0.40 0.50 Point 17 0.90 0.45 0.51 0.62 Point 18 0.81 0.41 0.49 0.57 Point 19 0.55 0.39 0.45 0.46 Point 20 0.57 0.36 0.41 0.45 Point 21 0.49 0.40 0.45 0.45 Point 22 0.50 0.54 0.40 0.48 Point 23 0.46 0.55 0.42 0.48 Point 24 0.39 0.50 0.40 0.43 Square Root of ΔP, (in. WC)1/2 (ΔP) 0.722 0.728 0.680 0.710 Pitot Tube Coefficient (Cp) 0.840 0.840 0.840 0.840 Barometric Pressure, in. Hg (Pb) 25.57 25.62 25.62 25.60 Static Pressure, in. WC (Pg) -0.01 -0.01 -0.01 -0.01 Stack Pressure, in. Hg (Ps) 25.57 25.62 25.62 25.60 Stack Cross-sectional Area, ft2 (As) 50.27 50.27 50.27 50.27 Temperature, °F (Ts) 145.0 147.8 157.5 150.1 Temperature, °R (Ts) 604.7 607.5 617.2 609.8 Moisture Fraction Measured (BWSmsd) 0.293 0.223 0.166 0.227 Moisture Fraction @ Saturation (BWSsat) 0.259 0.277 0.351 0.296 Moisture Fraction (BWS) 0.259 0.223 0.166 0.216 O2 Concentration, %(O2) 5.1 5.3 4.9 5.10 CO2 Concentration, %(CO2) 14.8 14.7 14.9 14.80 Molecular Weight, lb/lb-mole (dry) (Md) 30.57 30.56 30.58 30.57 Molecular Weight, lb/lb-mole (wet) (Ms) 27.32 27.77 28.49 27.86 Velocity, ft/sec (Vs) 48.3 48.3 44.9 47.1 At Stack Conditions, acfm (Qa) 145,582 145,637 135,350 142,190 At Standard Conditions, scfm (Qsw) 108,570 108,315 99,081 105,322 At Standard Conditions, dscfm (Qs) 80,445 84,165 82,610 82,407 MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 VOLUMETRIC FLOW RATE CALCULATED DATA VELOCITY HEAD, in. WC PM 20 of 84 Method 1 Data Location Source Project No. Date: Vertical Circular 105.00 in 9.00 in 96.00 in 50.27 ft2 2 35.0 ft 4.4 (must be ≥ 0.5) 20.0 ft 2.5 (must be ≥ 2) 24 24 1 Measurer (Initial and Date):XGK 10/24 Reviewer (Initial and Date):SPR 10/24 23456789101112 1 14.6 -- 6.7 -- 4.4 -- 3.2 -- 2.6 -- 2.1 1 2.1 2.02 11 2 85.4 -- 25.0 -- 14.6 -- 10.5 -- 8.2 -- 6.7 2 6.7 6.43 15 7/16 3 -- -- 75.0 -- 29.6 -- 19.4 -- 14.6 -- 11.8 3 11.8 11.33 20 5/16 4 -- -- 93.3 -- 70.4 -- 32.3 -- 22.6 -- 17.7 4 17.7 16.99 26 5 -- -- -- -- 85.4 -- 67.7 -- 34.2 -- 25.0 5 25.0 24.00 33 6 -- -- -- -- 95.6 -- 80.6 -- 65.8 -- 35.6 6 35.6 34.18 43 3/16 7 -- -- -- -- -- -- 89.5 -- 77.4 -- 64.4 7 64.4 61.82 70 13/16 8 -- -- -- -- -- -- 96.8 -- 85.4 -- 75.0 8 75.0 72.00 81 9 -- -- -- -- -- -- -- -- 91.8 -- 82.3 9 82.3 79.01 88 10 -- -- -- -- -- -- -- -- 97.4 -- 88.2 10 88.2 84.67 93 11/16 11 -- -- -- -- -- -- -- -- -- -- 93.3 11 93.3 89.57 98 9/16 12 -- -- -- -- -- -- -- -- -- -- 97.9 12 97.9 93.98 103 *Percent of stack diameter from inside wall to traverse point. A = 35 ft. B = 20 ft. Depth of Duct = 96 in. Duct Orientation: MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 10/24/23 Stack Parameters Duct Design: Nipple Length: Depth of Duct: Cross Sectional Area of Duct: Distance from Far Wall to Outside of Port: No. of Test Ports: Number of Readings per Point: Distance A: Distance A Duct Diameters: Distance B: Distance B Duct Diameters: Minimum Number of Traverse Points: Actual Number of Traverse Points: CIRCULAR DUCT Number of traverse points on a diameter Stack Diagram Cross Sectional Area LOCATION OF TRAVERSE POINTS Traverse Point % of Diameter Distance from inside wall Distance from outside of port Upstream Disturbance Downstream Disturbance B A 21 of 84 Cyclonic Flow Check Location MPC-Tesoro - Salt Lake City Refinery Source FCCU Wet Gas Scrubber Project No. AST-2023-2130 Date 10/24/23 Sample Point Angle (ΔP=0) 1 6 2 2 3 1 4 1 5 1 6 0 7 0 8 1 9 2 10 3 11 3 12 4 13 7 14 5 15 8 16 2 17 1 18 1 19 0 20 1 21 0 22 2 23 5 24 5 Average 3 22 of 84 Method 4 Data Location Source Project No. Parameter Analysis Run 1 Date:10/24/23 Impinger No.1234Total Contents Empty Empty H2O Silica -- Initial Mass, g 497.0 631.4 699.5 936.7 2764.6 Final Mass, g 883.0 634.5 700.8 949.2 3167.5 Gain 386.0 3.1 1.3 12.5 402.9 Run 2 Date:10/24/23 Impinger No.1234Total Contents Empty Empty H2O Silica -- Initial Mass, g 762.1 640.1 640.0 961.7 3003.9 Final Mass, g 1019.5 648.1 642.1 976.2 3285.9 Gain 257.4 8.0 2.1 14.5 282.0 Run 3 Date:10/24/23 Impinger No.1234Total Contents Empty Empty H2O Silica -- Initial Mass, g 753.3 631.4 700.8 938.5 3024.0 Final Mass, g 909.5 631.7 703.0 952.0 3196.2 Gain 156.2 0.3 2.2 13.5 172.2 MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 PM Gravimetric 23 of 84 Isokinetic Field Data Location: Start Time:Source: Date: VALID End Time:Project No.:AST-2023-2130 PM Moisture: 20.0 % est.Est. Tm: 141 °F Pb: 25.57 in. Hg Barometric: 25.62 in. Hg Est. Ts: 142 °F Pg: -0.01 in. WC Static Press: -0.10 in. WC Est. ΔP: 0.58 in. WC O2:5.1 % Stack Press: 25.61 in. Hg Est. Dn: 0.240 in.CO2:14.8 % CO2:14.0 %Target Rate: 0.75 scfm Check Pt. Initial Final Corr. O2:5.0 %LEAK CHECKS Pre Mid 1 Mid 2 Mid 3 Post Mid 1 (cf)-- N2/CO:81.0 %0.840 S-type Leak Rate (cfm):0.002 -- -- -- 0.001 Mid 2 (cf)-- Md: 30.44 lb/lb-mole SS282 SS Vacuum (in Hg):15 -- -- -- 13 Mid 3 (cf)-- Ms: 27.95 lb/lb-mole Pitot Tube:Pass -- -- -- Pass -- Stack Probe Filter Imp Exit Aux Amb.Amb. Amb. Amb. Amb. Begin End 61 Ideal Actual 62 61 61 61 1 0.00 2.50 0.70 141 3.11 3.10 7 253 244 49 63 102.2 55.03 2 2.50 5.00 0.55 144 2.43 2.40 8 263 258 63 73 100.5 48.90 3 5.00 7.50 0.50 146 2.22 2.20 7 268 266 63 74 101.3 46.71 4 7.50 10.00 0.51 145 2.27 2.30 7 268 267 59 74 101.7 47.13 5 10.00 12.50 0.49 145 2.18 2.20 7 268 271 57 76 101.8 46.20 6 12.50 15.00 0.46 146 2.05 2.10 5 267 269 55 77 101.4 44.80 7 15.00 17.50 0.41 146 1.83 1.80 5 269 267 53 76 100.4 42.29 8 17.50 20.00 0.44 146 1.96 2.00 5 269 269 55 77 101.3 43.81 9 20.00 22.50 0.37 146 1.65 1.70 5 266 263 55 78 101.1 40.18 10 22.50 25.00 0.38 145 1.71 1.70 5 262 269 51 79 100.9 40.68 11 25.00 27.50 0.39 144 1.76 1.80 5 265 271 54 78 100.7 41.18 12 27.50 30.00 0.40 143 1.80 1.80 5 265 264 54 74 100.1 41.67 13 30.00 32.50 0.65 145 2.92 2.90 8 258 255 64 81 100.4 53.21 14 32.50 35.00 0.57 145 2.56 2.60 8 254 250 64 80 102.2 49.83 15 35.00 37.50 0.55 145 2.47 2.50 8 247 255 67 81 101.8 48.94 16 37.50 40.00 0.67 146 3.00 3.00 10 248 256 67 81 101.2 54.07 17 40.00 42.50 0.90 146 4.03 4.00 12 267 272 59 79 99.1 62.66 18 42.50 45.00 0.81 144 3.65 3.70 11 268 268 58 75 102.7 59.35 19 45.00 47.50 0.55 145 2.48 2.50 7 267 269 59 73 102.1 48.94 20 47.50 50.00 0.57 146 2.57 2.60 7 270 270 59 78 101.3 49.87 21 50.00 52.50 0.49 145 2.22 2.20 7 271 268 59 77 101.2 46.20 22 52.50 55.00 0.50 146 2.26 2.30 7 271 262 61 80 101.0 46.71 23 55.00 57.50 0.46 145 2.08 2.10 6 269 262 61 81 100.5 44.76 24 57.50 60.00 0.39 145 1.77 1.80 5 271 267 62 81 101.2 41.21 Final DGM: Max Vac %ISO BWS 60.0 min 52.267 ft3 0.53 in. WC 57.5 °F 145.0 °F 12 2.388 in. WC 107.9 0.259 Gas Temperatures (°F) 61 62 62 62 5.243 54 56 61 54 60 59 61 59 59 Vs (fps) Pump Vac (in. Hg) Orifice Press. ΔH (in. WC) Sa m p l e Pt . Gas Temperatures (°F) DGM Average Amb. Sample Time (minutes) Dry Gas Meter Reading (ft3) 59 57 58 58 881.645 50 50 53 865.320 862.806 875.920 FCCU Wet Gas Scrubber STACK DATA (EST) MB706 Run 1 9:45 10:55 MPC-Tesoro - Salt Lake City Refinery STACK DATA (EST) EQUIPMENT MOIST. DATA Vlc (ml) 402.9 K-FACTOR STACK DATA (FINAL)FILTER NO. Parameter: 16729-C 10/24/23 1 1.922 Meter Box ID: Y: 0.9 YqaΔHTsΔPTm RE S U L T S 915.073 VmRun Time ΔH @ (in.WC): Probe ID: Nozzle ID: Nozzle Dn (in.): 902.285 Liner Material: 873.885 Pitot Tube ΔP (in WC) 891.995 899.520 877.825 867.510 887.274 869.625 896.720 879.815 Pitot ID: 894.250 889.690 885.380 glass Pr702-9 908.975 911.120 Mid-Point Leak Check Vol (cf):0.285 54 883.500 906.845 61 % ISO 913.170 62 904.555 Pr702-9 Pitot Cp/Type: 871.775 54 54 24 of 84 Isokinetic Field Data Location: Start Time:Source: Date: VALID End Time:Project No.:AST-2023-2130 PM Moisture: 20.0 % est.Est. Tm: 57 °F Pb: 25.62 in. Hg Barometric: 25.62 in. Hg Est. Ts: 145 °F Pg: -0.01 in. WC Static Press: -0.10 in. WC Est. ΔP: 0.53 in. WC O2:5.3 % Stack Press: 25.61 in. Hg Est. Dn: 0.265 in.CO2:14.7 % CO2:14.0 %Target Rate: 0.75 scfm Check Pt. Initial Final Corr. O2:5.0 %LEAK CHECKS Pre Mid 1 Mid 2 Mid 3 Post Mid 1 (cf)-- N2/CO:81.0 %0.840 S-type Leak Rate (cfm):0.010 -- -- -- 0.010 Mid 2 (cf)-- Md: 30.44 lb/lb-mole SS282 SS Vacuum (in Hg):17 -- -- -- 15 Mid 3 (cf)-- Ms: 27.95 lb/lb-mole Pitot Tube:Pass -- -- -- Pass -- Stack Probe Filter Imp Exit Aux Amb.Amb. Amb. Amb. Amb. Begin End -- Ideal Actual -- -- -- -- 1 0.00 2.50 0.77 145 3.49 3.50 10 258 261 61 65 100.8 57.91 2 2.50 5.00 0.81 145 3.66 3.70 11 259 258 60 65 101.3 59.40 3 5.00 7.50 0.71 146 3.21 3.20 10 261 264 58 66 101.0 55.66 4 7.50 10.00 0.48 145 2.17 3.10 10 261 265 59 66 102.8 45.72 5 10.00 12.50 0.45 145 2.05 2.10 7 261 264 59 66 101.5 44.27 6 12.50 15.00 0.68 145 3.09 3.10 9 266 262 60 68 102.7 54.42 7 15.00 17.50 0.65 145 2.96 3.00 10 265 271 62 68 103.0 53.21 8 17.50 20.00 0.58 145 2.64 2.60 8 266 270 62 68 102.4 50.26 9 20.00 22.50 0.56 144 2.57 2.60 8 266 272 63 69 100.5 49.35 10 22.50 25.00 0.61 144 2.79 2.80 8 266 271 63 70 100.7 51.50 11 25.00 27.50 0.60 145 2.75 2.80 8 267 272 65 71 101.0 51.12 12 27.50 30.00 0.62 145 2.84 2.80 8 267 268 65 72 101.4 51.97 13 30.00 32.50 0.48 144 2.20 2.20 6 270 269 66 70 100.8 45.69 14 32.50 35.00 0.40 151 1.82 1.80 5 265 268 66 74 101.0 41.95 15 35.00 37.50 0.43 151 1.95 2.00 6 268 270 64 74 101.7 43.49 16 37.50 40.00 0.44 151 2.00 2.00 6 265 268 64 75 100.1 43.99 17 40.00 42.50 0.45 150 2.04 2.00 6 267 265 63 77 101.6 44.45 18 42.50 45.00 0.41 152 1.86 1.90 6 267 267 66 77 100.9 42.50 19 45.00 47.50 0.39 152 1.77 1.80 6 260 266 66 77 102.7 41.45 20 47.50 50.00 0.36 152 1.63 1.60 5 261 267 61 72 101.0 39.83 21 50.00 52.50 0.40 152 1.82 1.90 6 262 269 60 72 100.9 41.98 22 52.50 55.00 0.54 151 2.45 2.50 7 263 271 61 72 103.5 48.74 23 55.00 57.50 0.55 151 2.50 2.50 7 268 269 62 73 102.6 49.19 24 57.50 60.00 0.50 152 2.27 2.30 7 269 270 63 75 100.3 46.94 Final DGM: Max Vac %ISO BWS 60.0 min 53.688 ft3 0.54 in. WC 67.5 °F 147.8 °F 11 2.492 in. WC 104.1 0.223 940.865 945.635 948.065 950.190 943.255 956.155 952.125 954.145 958.220 960.175 962.120 69 64 69 70 69 68 68 68 68 68 69 69 69 918.975 933.700 929.080 931.140 921.635 926.935 924.375 963.960 968.200 965.895 ΔP 972.663 970.510 65 64 64 938.570 936.210 70 70 12:00 K-FACTOR 16937-c STACK DATA (EST) Dry Gas Meter Reading (ft3) EQUIPMENT FCCU Wet Gas Scrubber Vs (fps) MPC-Tesoro - Salt Lake City Refinery 10/24/23 STACK DATA (EST) MB706 Sample Time (minutes) Nozzle Dn (in.): % ISO Nozzle ID: 13:20 STACK DATA (FINAL) Mid-Point Leak Check Vol (cf): Run 2 Parameter: Meter Box ID: Sa m p l e Pt . RE S U L T S Run Time 0.6 Vm ΔH Yqa Pump Vac (in. Hg) Gas Temperatures (°F) 66 66 64 66 TsTm 68 68 Liner Material: Gas Temperatures (°F) 4.49 Pitot ID: Pitot Cp/Type: 0.285 Pr702-9 Pitot Tube ΔP (in WC) Pr702-9 glass Orifice Press. ΔH (in. WC) DGM Average Amb. -- MOIST. DATA Vlc (ml) 282.0 FILTER NO. Y: ΔH @ (in.WC): Probe ID: 1 1.922 25 of 84 Isokinetic Field Data Location: Start Time:Source: Date: VALID End Time:Project No.:AST-2023-2130 PM Moisture: 25.0 % est.Est. Tm: 67 °F Pb: 25.62 in. Hg Barometric: 25.62 in. Hg Est. Ts: 148 °F Pg: -0.01 in. WC Static Press: -0.10 in. WC Est. ΔP: 0.54 in. WC O2:4.9 % Stack Press: 25.61 in. Hg Est. Dn: 0.269 in.CO2:14.9 % CO2:14.0 %Target Rate: 0.75 scfm Check Pt. Initial Final Corr. O2:5.0 %LEAK CHECKS Pre Mid 1 Mid 2 Mid 3 Post Mid 1 (cf)-- N2/CO:81.0 %0.840 S-type Leak Rate (cfm):0.001 -- -- -- 0.001 Mid 2 (cf)-- Md: 30.44 lb/lb-mole SS282 SS Vacuum (in Hg):20 -- -- -- 10 Mid 3 (cf)-- Ms: 27.33 lb/lb-mole Pitot Tube:Pass -- -- -- Pass -- Stack Probe Filter Imp Exit Aux Amb.Amb. Amb. Amb. Amb. Begin End -- Ideal Actual -- -- -- -- 1 0.00 2.50 0.42 162 1.68 1.90 5 270 250 58 66 102.1 43.86 2 2.50 5.00 0.40 165 1.59 1.60 5 267 271 59 66 101.5 42.90 3 5.00 7.50 0.46 163 1.83 1.80 5 267 270 59 67 105.3 45.94 4 7.50 10.00 0.41 159 1.64 1.70 5 269 271 60 68 101.0 43.23 5 10.00 12.50 0.48 159 1.92 1.90 5 269 272 60 67 101.8 46.77 6 12.50 15.00 0.51 156 2.06 2.10 6 271 261 61 68 100.4 48.10 7 15.00 17.50 0.54 157 2.17 2.20 6 269 262 61 68 100.7 49.53 8 17.50 20.00 0.59 156 2.38 2.40 7 269 253 62 69 100.9 51.73 9 20.00 22.50 0.56 155 2.25 2.30 6 269 271 62 66 101.0 50.36 10 22.50 25.00 0.49 156 1.97 2.00 5 269 270 62 67 101.5 47.14 11 25.00 27.50 0.43 156 1.73 1.70 5 269 272 62 67 100.7 44.16 12 27.50 30.00 0.46 152 1.87 1.90 5 269 264 63 68 101.5 45.53 13 30.00 32.50 0.45 151 1.84 1.80 5 268 265 65 68 99.6 44.99 14 32.50 35.00 0.50 159 2.02 2.00 5 270 261 55 67 101.9 47.74 15 35.00 37.50 0.49 158 1.97 2.00 5 264 266 56 67 103.8 47.22 16 37.50 40.00 0.40 158 1.61 1.60 3 269 264 58 68 102.6 42.66 17 40.00 42.50 0.51 159 2.05 2.10 5 267 266 58 68 100.9 48.21 18 42.50 45.00 0.49 157 1.98 2.00 5 264 264 59 68 101.1 47.18 19 45.00 47.50 0.45 157 1.82 1.80 4 262 268 59 67 101.0 45.21 20 47.50 50.00 0.41 157 1.67 1.70 4 264 262 61 67 103.7 43.16 21 50.00 52.50 0.45 157 1.83 1.80 4 264 262 61 68 100.8 45.21 22 52.50 55.00 0.40 157 1.63 1.70 4 266 264 61 68 101.4 42.63 23 55.00 57.50 0.42 158 1.70 1.70 4 267 269 62 69 101.1 43.72 24 57.50 60.00 0.40 157 1.63 1.60 4 268 269 62 71 100.3 42.63 Final DGM: Max Vac %ISO BWS 60.0 min 47.295 ft3 0.46 in. WC 67.8 °F 157.5 °F 7 1.888 in. WC 93.2 0.166 68 65 1004.965 1007.020 1001.035 1009.045 991.180 998.975 1003.110 997.055 995.080 993.200 65 1010.990 1012.900 974.980 67 66 67 1018.570 1016.690 Pump Vac (in. Hg) STACK DATA (FINAL) 4.095 FILTER NO. Mid-Point Leak Check Vol (cf): 69 % ISO 68 Vs (fps) Orifice Press. ΔH (in. WC) Gas Temperatures (°F) 65 Gas Temperatures (°F) Pr702-9 1.922 glass Pr702-9 65 67 67 66 66 MPC-Tesoro - Salt Lake City Refinery 10/24/23 Run 3 STACK DATA (EST) MB706 Nozzle ID: Nozzle Dn (in.): Sa m p l e Pt . Sample Time (minutes) Dry Gas Meter Reading (ft3)-- 0.285 EQUIPMENT Meter Box ID: Y: ΔH @ (in.WC): Probe ID: Liner Material: Pitot ID: Pitot Cp/Type: 1 DGM Average Amb. Pitot Tube ΔP (in WC) 15:26 K-FACTOR MOIST. DATA Vlc (ml) 172.2 FCCU Wet Gas Scrubber 16735-C STACK DATA (EST) Parameter: 14:12 973.100 986.820 984.710 980.660 982.665 978.820 989.030 976.795 1014.845 1.2 ΔHVm YqaΔPTmTs 68 68 71 70 71 71 71 RE S U L T S Run Time 70 68 69 1020.395 26 of 84 Appendix C 27 of 84 Version No. LT 2020-00_20.0 Project No. AST-2023-2130 Alliance Technical Group, LLC Analytical Services 5530 Marshall St. Arvada, CO 80002 (720) 457-9504 www.alliancetg.com Analytical Laboratory Report 474 West 900 North Salt Lake City, UT 84103 Marathon Petroleum (Salt Lake City Refinery) - Tesoro 1 of 21 28 of 84 Quality Associate Date Certification Statement Alliance Source Testing, LLC (AST) has completed the analysis as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and AST is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Any deviations or problems are detailed in the relevant sections on the test report. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. Validation Signature The analytical data and all QC contained within this report was reviewed and validated by the following individual. James Davidson 2 of 21 Digitally signed by James Davidson DN: C=US, CN=James Davidson, E=james.davidson@stacktest.com Reason: I attest to the accuracy and integrity of this document Location: your signing location here Date: 2023.11.22 17:00:40-06'00' Foxit PDF Editor Version: 11.2.7 James Davidson 29 of 84 Project Narrative Analytical Method(s):Method 5 - Determination of Particulate Matter Emissions From Stationary Sources Method 202 - Dry Impinger Method for Determining Condensable Particulate Matter Emissions From Stationary Sources Filterable The filter(s) were either oven dried and/or desiccated per the method until a final weight was obtained. The liquid fractions were extracted if required, evaporated and cooled until a final weight was obtained. These fractions were summed together to provide the total Particulate Matter collected. Condensable The filter(s) were extracted per the method. The organic extract was added to the organic rinse, and the inorganic extract was added to the inorganic rinse. The inorganic fraction was extracted with solvent per the method. Extracts were combined with the organic rinse. The organic and inorganic fractions were evaporated and desiccated until a final weight was obtained. MDL The Minimum Detection Level (MDL) is 0.5 mg per fraction. If the measured result for a fraction is less than the MDL, the MDL was used in ensuing calculations. Blank Correction If blank correction is performed, only blank values returned higher than the MDL are used. If a blank returns a value less than the MDL, no correction is included. Custody:The samples were received by Cory Manshack on 11/8/2023 in Arvada, CO. The samples were received in good condition with proper Chain-of-Custody documentation. No apparent container problems were noted upon receipt. Prior to analysis, the samples were kept secure with access limited to authorized personnel of AST. Number of Samples:23 (2 on Hold) Labeling: Acceptable Analyst:Eric Grosjean - Laboratory Manager Cory Manshack-Laboratory Analyst II Ryan Gillett-Laboratory Analyst II Carson Williamson-Laboratory Analyst I Equipment:Mettler Toledo Balance ML-104, SN B217893065. This scale was used for analytical determinations of filters and rinse vessels. Denver Instruments Balance TB-6201, SN 17904189. This scale was used to measure the total mass of rinse collected for blank correction. Analysis was performed on the same balance as the associated tare. Quincy Lab Inc oven, 30CG, SN G3-012673. Lab Reagents:Acetone Lot Number: 216612 Hexane Lot Number: 224521 QC Notes:The samples met the minimum criteria established by the relevant method. A blank correction was applied per the method. Reporting Notes:none 3 of 21 30 of 84 Client City, State Project No. Method Lab ID Field ID Filter ID 16729 - C 16937 - C 16735 - C Filter Tare Weight, g Date - Desiccator Time - Desiccator Date of Weighing 11/7/23 11/8/23 11/7/23 11/8/23 11/7/23 11/8/23 Time of Weighing 14:37 8:46 14:37 8:46 14:37 8:46 Filter Weight, g 0.4883 0.4887 0.5171 0.5174 0.4871 0.4871 Filter PM Mass, mg* Lab ID Field ID Beaker ID Beaker tare, g Beaker with Acetone, g Acetone Mass, g Date - Desiccator Time - Desiccator Date of Weighing 11/10/23 11/13/23 11/10/23 11/13/23 11/10/23 11/13/23 Time of Weighing 12:50 8:17 12:50 8:17 12:50 8:17 Weight, g 3.9826 3.9826 4.0044 4.0047 3.9379 3.9379 Measured Rinse Mass, mg Blank Corrected Total PM Mass, mg *All fractions were analyzed and returned values greater than the MDL of 0.5 mg. D38238 M5/202-WGS-Run 1 Cont. 1 M5/202-WGS-Run 2 Cont. 1 M5/202-WGS-Run 3 Cont. 1 D38228 D38233 Marathon Petroleum (Salt Lake City Refinery) - Tesoro Salt Lake City, UT 84103 AST-2023-2130 EPA Method 5 Front Half Filter 13:45 13:45 13:45 11/6/23 11/6/23 11/6/23 5.2 3.7 4.5 Front Half Rinse M5/202-WGS-Run 1 Cont. 2 M5/202-WGS-Run 2 Cont. 2 M5/202-WGS-Run 3 Cont. 2 32382 32391 32402 D38229 D38234 D38239 3.9676 3.9967 3.9355 109.7 78.3 70.4 105.7 74.3 66.5 11/9/23 11/9/23 11/9/23 12:30 15.0 7.9 2.4 20.2 11.7 6.9 0.4834 0.5135 0.4826 No 12:30 12:30 4 of 21 31 of 84 Client City, State Project No. Method Lab ID Field ID Beaker ID Beaker tare, g Beaker with Acetone, g Acetone Mass, g Date - Desiccator Time - Desiccator Date of Weighing 11/13/23 11/14/23 Time of Weighing 14:32 4:43 Weight, g 3.9401 3.9400 Blank Mass, mg* Salt Lake City, UT 84103 Marathon Petroleum (Salt Lake City Refinery) - Tesoro 157.74 M5 Acetone Blank 32405 3.9397 D38248 Acetone Blank EPA Method 5 AST-2023-2130 0.0 12:30 153.80 11/9/23 5 of 21 32 of 84 Client City, State Project No. Method Lab ID Field ID Lab ID Field ID Beaker ID Beaker tare, g Beaker Solvent, g Solvent Mass, g Date - Desiccator Time - Desiccator Date of Weighing 11/10/23 11/13/23 11/10/23 11/13/23 11/10/23 11/13/23 Time of Weighing 14:26 8:10 14:26 8:10 14:26 8:10 Weight, g 4.0036 4.0038 4.0492 4.0492 3.8616 3.8619 Measured Organic Mass, mg Lab ID Field ID Beaker ID Beaker tare, g Beaker Water, g Water Mass, g Date - Desiccator Time - Desiccator Date of Weighing 11/10/23 11/13/23 11/10/23 11/13/23 11/10/23 11/13/23 Time of Weighing 13:31 8:00 13:31 8:00 13:31 8:00 Weight, g 49.8781 49.8784 49.9986 49.9984 50.8284 50.8285 Inorganic Mass, mg* Blank Corrected Total PM Mass, mg *All fractions were analyzed and returned values greater than the MDL of 0.5 mg. 328.3 376.8 328.6 D38241 M5/202-WGS-Run 1 Cont. 4 M5/202-WGS-Run 2 Cont. 4 M5/202-WGS-Run 3 Cont. 4 31596 31598 49.8744 49.9935 50.8254 426.8378.2 379.4 D38231 D38236 11/9/23 11/9/23 11/9/23 12:30 12:30 12:30 5.0 3.1 Yes 195.1 166.1 75.9 31595 5.7 4.2 1.9 191.1 162.1 72.0 Teflon Filter Organic Fraction Marathon Petroleum (Salt Lake City Refinery) - Tesoro 11/9/23 11/9/23 11/9/23 13:29 13:29 13:29 3.9 D38230 D38235 D38240 M5/202-WGS-Run 1 Cont. 3 M5/202-WGS-Run 2 Cont. 3 M5/202-WGS-Run 3 Cont. 3 Salt Lake City, UT 84103 AST-2023-2130 EPA Method 202 Inorganic Fraction 3.9981 4.0450 3.8599 M5/202-WGS-Run 1 Cont. 5 M5/202-WGS-Run 2 Cont. 5 M5/202-WGS-Run 3 Cont. 5 32394 32482 32480 D38242D38237D38232 7.5 7.2 3.0 6 of 21 33 of 84 Client City, State Project No. Method Lab ID Field ID Lab ID Field ID Beaker ID Beaker tare, g Beaker Solvent, g Solvent Mass, g Date - Desiccator Time - Desiccator Date of Weighing 11/10/23 11/13/23 11/10/23 11/13/23 Time of Weighing 14:26 8:10 12:50 8:17 Weight, g 3.9407 3.9408 3.9446 3.9446 Organic Mass, mg* Lab ID Field ID Beaker ID Beaker tare, g Beaker Water g Water Mass, g Date - Desiccator Time - Desiccator Date of Weighing 11/10/23 11/13/23 11/10/23 11/13/23 Time of Weighing 14:26 8:00 14:26 8:00 Weight, g 50.8643 50.8641 51.2866 51.2862 Inorganic Mass, mg* Marathon Petroleum (Salt Lake City Refinery) - Tesoro Salt Lake City, UT 84103 AST-2023-2130 EPA Method 202 116.8 100.1 3.9387 M202-FT Proof Recovery Blank Cont. 3 N/A Field Train Blank Field Train Blank Proof Blank D38245 N/A Teflon Filter Blanks D38244 32400 32401 M202-FT Proof Recovery Blank Cont. 5 M202-FT Proof Blank-Cont. 5 D38247 Field Train Blank Proof Blank 3.9426 11/9/23 11/9/23 2.02.0 120.7 Organic Fraction Blanks M202-FT Proof Recovery Blank Cont. 4 M202-FT Proof Blank-Cont. 4 D38246 Inorganic Fraction Blanks 11/9/23 283.5 164.0 Proof Blank 14:23 12:30 104.0 D38243 31599 50.8620 51.2851 31594 334.4 215.3 14:23 14:23 11/9/23 2.0 1.4 7 of 21 34 of 84 8 of 21 35 o f 8 4 9 of 21 36 of 84 10 of 21 37 of 84 11 of 21 38 of 84 12 of 21 39 of 84 13 of 21 40 of 84 14 of 21 41 of 84 15 of 21 42 of 84 16 of 21 43 of 84 17 of 21 44 of 84 18 of 21 45 of 84 19 of 21 46 of 84 20 of 21 47 of 84 21 of 21 48 of 84 49 of 84 50 of 84 51 of 84 52 of 84 53 of 84 54 of 84 55 of 84 56 of 84 57 of 84 58 of 84 59 of 84 60 of 84 61 of 84 62 of 84 63 of 84 64 of 84 65 of 84 66 of 84 67 of 84 68 of 84 69 of 84 70 of 84 71 of 84 72 of 84 73 of 84 74 of 84 75 of 84 Appendix D 76 of 84 Method 3/3A Data Location Source Project No. Date/Time 10/24/23 13:45 Date/Time 10/24/23 13:45 Make/Model/SN Servomex 1440D 14150/3279 Servomex 1440D 14200/3279 Parameter Cylinder ID Cylinder Concentration, % Analyzer Concentration, %Cylinder ID Cylinder Concentration, % Analyzer Concentration, % Zero Gas 0.00 0.00 0.00 0.00 High Range Gas EB0078994 24.00 23.80 EB0078994 23.90 23.90 Mid Range Gas RR04251 10.99 11.10 RR04251 11.10 11.10 Concentration Span, % Required Accuracy, % Run No. Analysis Date/Time 10/24/2023 16:45 10/24/2023 17:15 10/24/2023 17:45 Parameter O2 %CO2 %O2 %CO2 %O2 %CO2 % Analysis #1 5.10 14.80 5.30 14.80 4.90 14.90 Analysis #2 5.10 14.80 5.30 14.70 4.90 14.90 Analysis #3 5.10 14.80 5.30 14.70 4.90 14.90 Average 5.1 14.8 5.3 14.7 4.9 14.9 The remaining consistuent is assumed to be nitrogen. Run 1 Run 2 Run 3 MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 0.48 0.48 24.0 O2 Data CO2 Data 23.9 77 of 84 Balance Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551-8150 Accreditation #62754 PGVP Vendor ID # G12021 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number:EB0078994 Certification Date:04/29/2021 Product ID Number:127907 Expiration Date:04/27/2029 Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA COA #EB0078994.20210414-0 Lot Number:EB0078994.20210414 Customer PO. NO.:Tracking Number:084269913 Customer:Previous Certification Dates: This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531, using procedure G2. Do Not Use This Cylinder Below 100 psig (0.7 Megapascal). Certified Concentration(s) Component Concentration Uncertainty Analytical Principle Assayed On Carbon Dioxide 23.9 %±0.16 %NDIR 04/29/2021 Oxygen 24.0 %±0.13 %MPA 04/27/2021 Nitrogen Analytical Measurement Data Available Online. Reference Standard(s) Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference CC729793 CC729793.20201022 04/06/2029 GMIS N2 O2 20.01 %0.115 SRM 2659a EB0007615 EB0007615.20190610 11/24/2027 GMIS N2 CO2 24.71 %0.274 C1579010.02 EB0041474 EB0041474.20180504 07/21/2026 GMIS N2 O2 24 %0.497 071001 EB0097757 EB0097757.20190610 11/24/2027 GMIS N2 CO2 19.58 %0.306 C1579010.02 Analytical Instrumentation SMART-CERT Component Principle Make MPC Date O2 MPA Thermo 04/20/2021 CO2 NDIR Thermo 04/09/2021 Serial 1162980025 1162980025 This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. Anthony Cyr Assistant Operations Manager Assay Laboratory: Red Ball TGS Version 02-J, Revised on 2018-09-17 Model 410i 410i 78 of 84 Balance Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551-8150 Accreditation #62754 PGVP Vendor ID # G12023 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number:RR04251 Certification Date:09/21/2023 Product ID Number:125371 Expiration Date:09/19/2031 Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA COA #RR04251.20230831-0 Lot Number:RR04251.20230831 Customer PO. NO.:Tracking Number:107549718 Customer:Previous Certification Dates: This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531, using procedure G1. Do Not Use This Cylinder Below 100 psig (0.7 Megapascal). Certified Concentration(s) Component Concentration Uncertainty Analytical Principle Assayed On Carbon Dioxide 11.1 %±0.11 %FTIR 09/21/2023 Oxygen 10.99 %±0.03 %MPA 09/18/2023 Nitrogen Analytical Measurement Data Available Online. Reference Standard(s) Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference CC737012 CC737012.20230228 07/09/2031 GMIS N2 O2 20 %0.112 SRM 2659a EB0022021 EB0022021.20180323 07/15/2026 GMIS N2 CO2 14.9 %0.777 101001 Analytical Instrumentation SMART-CERT Component Principle Make MPC Date O2 MPA Thermo 09/18/2023 CO2 FTIR MKS 09/21/2023 Serial 1162980025 017146467 This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. Jasmine Godfrey Analytical Chemist Assay Laboratory: Red Ball TGS Version 02-J, Revised on 2018-09-17 Model 410i MKS 2031DJG2EKVS13T 79 of 84 QA/QC Data Location Source Project No. Parameter #1 #2 #3 Dn (Average)Difference 10/24/23 SS282 0.285 0.284 0.285 0.285 0.001 SS 10/24/23 Pr710-9 no no no Date Probe or Thermocouple ID Reference Temp. (°F) Indicated Temp. (°F)Difference Criteria Probe Length 10/24/23 Pr710-9 68.4 68.2 0.0%10 ' Date 10/24/23 Balance ID:B304743079 Certified Weight ID:SLC-1KG-2 Certified Weight (g):1000.0 Measured Weight (g):1000.0 Weight Difference (g):0.0 ---------- 10/24/23 Weather Station No Yes No 10/24/23 MB706 Acetone 216543 No NA NA NA Hexane 218359 No NA NA NA DI H2O 230440 No NA NA NA Flow Rate (lpm):14 Flow Rate (lpm):14 Flow Rate (lpm):14 Clock Time Temperature Clock Time Temperature Clock Time Temperature 11:30 75.0 13:45 75.0 15:45 76.0 11:40 75.0 13:55 75.0 15:55 76.0 11:50 75.0 14:05 75.0 16:05 76.0 12:00 75.0 14:15 75.0 16:15 76.0 12:10 75.0 14:25 75.0 16:25 76.0 ± 1.5 % (absolute) Reagent ByDateField LotField Prep performedLot# Date Barometric Pressure Evidence of damage?Reading Verified Calibration or Repair required? Posttest Purge Run 1 Run 2 Run 3 Material Date Meter Box ID Positive Pressure Leak Check Pass ≤ 0.004 in. Date Pitot ID Evidence of damage? Weather Station Location Salt Lake City UT Evidence of mis-alignment? Calibration or Repair required? Field Balance Check MPC-Tesoro - Salt Lake City Refinery FCCU Wet Gas Scrubber AST-2023-2130 Nozzle Diameter (in.) Date Nozzle ID Criteria PM 80 of 84 Document ID 620.004 Revision 22.3 Effective Date 12/16/22 Issuing Department Page 1 of 1 Console ID: Meter S/N: Critical Orifice S/N: (PbI) (PbF) (Pb) (Y)1330-31 1330-31 1330-25 1330-25 1330-19 1330-19 (K')0.8429 0.8429 0.6728 0.673 0.5186 0.519 (VP)15.0 15.0 15.0 15.0 17.0 17.0 Initial DGM Volume, ft3 (VmI)423.941 434.737 449.922 458.683 474.495 481.430 Final DGM Volume, ft3 (VmF)434.837 445.698 458.683 467.443 481.430 488.317 Total DGM Volume, ft3 (Vm)10.896 10.961 8.761 8.760 6.935 6.887 Ambient Temperature, °F (Ta)83 84 84 84 85 86 Initial DGM Temperature, °F (TmI)81 81 82 83 84 85 Final DGM Temperature, °F (TmF)81 82 83 84 85 85 Average DGM Temperature, °F ( Tm)81 82 83 84 85 85 Elapsed Time (Θ)10.00 10.00 10.00 10.00 10.00 10.00 Meter Orifice Pressure, in. WC (ΔH)3.30 3.30 2.20 2.20 1.40 1.40 Standard Meter volume, ft3 (Vmstd)9.1653 9.2114 7.3259 7.3116 5.7645 5.7194 Standard Critical Orifice Volume, ft3 (Vcr)9.2410 9.2325 7.3694 7.3694 5.6752 5.670 Meter Correction Factor (Y)1.008 1.002 1.006 1.008 0.985 0.991 Tolerance --0.008 0.002 0.006 0.008 0.016 0.009 Orifice Calibration Value (ΔH @)1.828 1.830 1.905 1.902 2.032 2.034 Tolerance --0.094 0.092 0.017 0.020 0.110 0.112 Orifice Cal Check -- Meter Correction Factor (Y) Orifice Calibration Value (ΔH @) Accuracy Difference oF oR oF oR %oF 0 460 0 460 0.0 0 68 528 66 526 0.4 2 100 560 98 558 0.4 2 223 683 223 683 0.0 0 248 708 248 708 0.0 0 273 733 273 733 0.0 0 300 760 300 760 0.0 0 400 860 398 858 0.2 2 500 960 498 958 0.2 2 600 1,060 599 1,059 0.1 1 700 1,160 701 1,161 -0.1 1 800 1,260 801 1,261 -0.1 1 900 1,360 901 1,361 -0.1 1 1,000 1,460 1,002 1,462 -0.1 2 1,100 1,560 1,102 1,562 -0.1 2 1,200 1,660 1,202 1,662 -0.1 2 Calibration Date: Amos OmerCalibration By: 9/7/2023 Equipment Detail - Thermocouple Sensor Reference Temp.Display Temp. OMEGA T-197207 Personnel Reference Calibrator Make: Reference Calibrator Model: Reference Calibrator S/N: Calibration Detail K' Factor, ft3·R1/2 / in. WC·min CL23A Vacuum Pressure, in. Hg Initial Barometric Pressure, in. Hg Final Barometric Pressure, in. Hg Average Barometric Pressure, in. Hg Critifcal Orifice ID Calibration Detail MB-706 283355 1330 Positive Pressure Leak Check Equipment Detail - Dry Gas Meter 1.000 1.922 Yes 1.76 1.92 1.89 DGM Calibration-Orifices Tech Services 25.54 25.54 25.54 81 of 84 Appendix E 82 of 84 Start Time Finish Time FCU FRESH FEED TO RX F100202.pv BPD Run #1 10/24/23 9:45 AM 10/24/23 10:55 AM 29101 Run #2 10/24/23 12:00 PM 10/24/23 1:20 PM 29,097 Run #3 10/24/23 2:12 PM 10/24/23 3:26 PM 29,103 AVERAGE:29,100 FCU FRESH FEED TO RX 83 of 84 Last Page of Report 84 of 84 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Tesouro - FCCU WGS Company Contact:Morgan Sites Contact Phone No.385-306-4615 Source Designation:FCCU WGS Test & Review Dates Test Date: 10/24/2023 Review Date: 1/12/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits ton/yr lbs/hr gr/dscf - - - Emission Rates - "Front Half" ton/yr lbs/hr gr/dscf 0.6528 0.0009 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 96.00 50.27 1.0000 1.922 0.84 25.6 -0.01 0.285 Contractor Information Contracting Company: Alliance Technical Group, LLC Contact: Shamit Nakra Phone No.: 385-252-7553 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Tesouro - FCCU WGS Testing Results Lab Data - grams collected Test Date 10/24/2023 10/24/2023 10/24/2023 10/24/2023 Lab Data Probe Filter Back Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.015 0.0052 0.0075 22.9% As ft^2 50.27 50.27 50.27 Run 2 0.0079 0.0037 0.0072 15.7% Pbar 25.60 25.60 25.60 Run 3 0.0024 0.0045 0.003 23.3% Pq (static)-0.01 -0.01 -0.01 Run 4 Ps 25.60 25.60 25.60 Avg. Ts F 145.00 147.83 157.54 Front Half Emissions Summary CO2 - FCO2 14.80 14.70 14.90 Run 1 Run 2 Run 3 Run 4 Avg. O2 5.10 5.30 4.90 gr./dscf 0.0016 0.0006 0.0006 0.00093 N2+C 80.10 80.00 80.20 lbs/hr 1.0917 0.4376 0.4292 0.65 Md 30.57 30.56 30.58 ton/yr 4.78 1.92 1.88 2.86 Ms 27.29 27.77 28.50 Y 1.00 1.00 1.00 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 52.27 53.69 47.30 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 402.90 282.00 172.20 gr./dscf 0.0042 0.0030 0.0017 0.0030 AVG. Tm F 67.79 66.69 63.94 lbs/hr 2.8617 2.1676 1.2301 2.0865 Vm std 45.03 46.36 40.98 ton/yr 12.53 9.49 5.39 9.14 Vw std 18.96 13.27 8.11 Bws 0.30 0.22 0.17 S Bws 0.26 0.28 0.36 Avg. Sqrt Dlp 0.72 0.73 0.68 Vs 48.28 48.32 44.90 F factor used scfm wet 108737.25 108308.66 99057.79 acfm 145623.97 145729.30 135411.03 Qsd dscfh 4819211.07 5052071.26 4962120.93 # Sample Points 24.00 24.00 24.00 Dn 0.285 0.285 0.285 An 4.43E-04 4.43E-04 4.43E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 60.00 60.00 60.00 Time @ point 2.50 2.50 2.50 Fraction PM 10 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Tesouro - FCCU WGS Flow & Moisture Test Date 10/24/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 50.27 25.60 -0.01 25.60 145 14.80 5.10 80.10 30.57 27.29 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.2613 1.0000 0.84 52.267 402.90 67.79 45.027 18.965 0.2964 0.2613 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.722 48.28 108,737 145,624 4.82E+06 24 0.285 60 2.50 2.387500 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 862.806 0.70 3.10 141 49 63 Wt. (Final) Wt. (Initial) lc 2 865.320 0.55 2.40 144 63 73 883.00 497.00 386.0 3 867.510 0.50 2.20 146 63 74 634.50 631.40 3.1 4 869.625 0.51 2.30 145 59 74 700.80 699.50 1.3 5 871.775 0.49 2.20 145 57 76 949.20 936.70 12.5 6 873.885 0.46 2.10 146 55 77 0.0 7 875.920 0.41 1.80 146 53 76 8 877.825 0.44 2.00 146 55 77 Isokinetics 111.3 9 879.815 0.37 1.70 146 55 78 Test Date 10/24/2023 10 881.645 0.38 1.70 145 51 79 Start Time enter 11 883.500 0.39 1.80 144 54 78 End Time 12 885.380 0.40 1.80 143 54 74 Run 1 13 887.274 0.65 2.90 145 64 81 14 889.690 0.57 2.60 145 64 80 15 891.995 0.55 2.50 145 67 81 16 894.250 0.67 3.00 146 67 81 17 896.720 0.90 4.00 146 59 79 18 899.520 0.81 3.70 144 58 75 19 902.285 0.55 2.50 145 59 73 20 904.555 0.57 2.60 146 59 78 21 906.845 0.49 2.20 145 59 77 22 908.975 0.50 2.30 146 61 80 23 911.120 0.46 2.10 145 61 81 24 913.170 0.39 1.80 145 62 81 25 915.073 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Tesouro - FCCU WGS Flow & Moisture Test Date 10/24/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 50.27 25.60 -0.01 25.60 148 14.70 5.30 80.00 30.56 27.77 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.2806 1.0000 0.84 53.688 282.00 67 46.362 13.274 0.2226 0.2806 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.728 48.32 108,309 145,729 5.05E+06 24 0.285 60 2.50 2.49 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 918.975 0.77 3.50 145.0 61.0 65.0 Wt. (Final) Wt. (Initial) lc 2 921.635 0.81 3.70 145.0 60.0 65.0 1019.50 762.10 257.4 3 924.375 0.71 3.20 146.0 58.0 66.0 648.10 640.10 8.0 4 926.935 0.48 3.10 145.0 59.0 66.0 642.10 640.00 2.1 5 929.080 0.45 2.10 145.0 59.0 66.0 976.20 961.70 14.5 6 931.140 0.68 3.10 145.0 60.0 68.0 0.0 7 933.700 0.65 3.00 145.0 62.0 68.0 8 936.210 0.58 2.60 145.0 62.0 68.0 Isokinetics 104.2 9 938.570 0.56 2.60 144.0 63.0 69.0 Test Date 10/24/2023 10 940.865 0.61 2.80 144.0 63.0 70.0 Start Time 11 943.255 0.60 2.80 145.0 65.0 71.0 End Time 12 945.635 0.62 2.80 145.0 65.0 72.0 Run 2 13 948.065 0.48 2.20 144.0 66.0 70.0 14 950.190 0.40 1.80 151.0 66.0 74.0 15 952.125 0.43 2.00 151.0 64.0 74.0 16 954.145 0.44 2.00 151.0 64.0 75.0 17 956.155 0.45 2.00 150.0 63.0 77.0 18 958.220 0.41 1.90 152.0 66.0 77.0 19 960.175 0.39 1.80 152.0 66.0 77.0 20 962.120 0.36 1.60 152.0 61.0 72.0 21 963.960 0.40 1.90 152.0 60.0 72.0 22 965.895 0.54 2.50 151.0 61.0 72.0 23 968.200 0.55 2.50 151.0 62.0 73.0 24 970.510 0.50 2.30 152.0 63.0 75.0 25 972.663 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Tesouro - FCCU WGS Flow & Moisture Test Date 10/24/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 50.27 25.60 -0.01 25.60 158 14.90 4.90 80.20 30.58 28.50 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.3559 1.0000 0.84 47.295 172.20 64 40.985 8.105 0.1651 0.3559 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.680 44.90 99,058 135,411 4.96E+06 24 0.285 60 2.50 1.89 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 973.100 0.42 1.90 162.0 58.0 66 Wt. (Final) Wt. (Initial) lc 2 974.980 0.40 1.60 165.0 59.0 66 909.5 753.3 156.2 3 976.795 0.46 1.80 163.0 59.0 67 631.7 631.4 0.3 4 978.820 0.41 1.70 159.0 60.0 68 703.0 700.8 2.2 5 980.660 0.48 1.90 159.0 60.0 67 952.0 938.5 13.5 6 982.665 0.51 2.10 156.0 61.0 68 0.0 7 984.710 0.54 2.20 157.0 61.0 68 8 986.820 0.59 2.40 156.0 62.0 69 Isokinetics 93.8 9 989.030 0.56 2.30 155.0 62.0 66 Test Date 10/24/2023 10 991.180 0.49 2.00 156.0 62.0 67 Start Time 11 993.200 0.43 1.70 156.0 62.0 67 End Time 12 995.080 0.46 1.90 152.0 63.0 68 Run 3 13 997.055 0.45 1.80 151.0 65.0 68 14 998.975 0.50 2.00 159.0 55.0 67 15 1001.035 0.49 2.00 158.0 56.0 67 16 1003.110 0.40 1.60 158.0 58.0 68 17 1004.965 0.51 2.10 159.0 58.0 68 18 1007.020 0.49 2.00 157.0 59.0 68 19 1009.045 0.45 1.80 157.0 59.0 67 20 1010.990 0.41 1.70 157.0 61.0 67 21 1012.900 0.45 1.80 157.0 61.0 68 22 1014.845 0.40 1.70 157.0 61.0 68 23 1016.690 0.42 1.70 158.0 62.0 69 24 1018.570 0.40 1.60 157.0 62.0 71 25 1020.395 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1