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HomeMy WebLinkAboutDRC-2024-004047 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144880 • Salt Lake City, UT 84114-4880 Telephone (801) 536-0200 • Fax (801)-536-0222 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF WASTE MANAGEMENT AND RADIATION CONTROL Douglas J. Hansen Director MEMORANDUM TO: File THROUGH: Phil Goble, Manager FROM: Christopher Leahy, P.G. DATE: January 16, 2024 SUBJECT: Review of the Energy Fuels Resources (USA) Inc. 3rd Quarter 2023 Groundwater Monitoring Report for the White Mesa Uranium Mill Review Summary: The Utah Division of Waste Management and Radiation Control (“Division”) has reviewed the following documents submitted by Energy Fuels Resources (USA) Inc. (“EFR”): 1. EFR, November 7, 2023, Transmittal of 3rd Quarter 2023 Groundwater Monitoring Report Groundwater Quality Discharge Permit UGW370004 White Mesa Uranium Mill. (Received by the Division on November 13, 2023) 2. EFR, October 25, 2023, State of Utah Ground Water Discharge Permit No. UGW370004 White Mesa Uranium Mill – Notice Pursuant to Part I.G.1(a) (Received by the Division on November 1, 2023) The review was conducted to ensure compliance with all applicable parts of Utah Groundwater Discharge Permit No. UGW370004 (“Permit”) issued for the White Mesa Uranium Mill located in Blanding, Utah (Mill). Significant Findings of the 3rd Quarter 2023 Report and Related Actions at the White Mesa Uranium Mill: When a monitoring well has a pollutant that exceeds a Ground Water Compliance Limit (GWCL) set forth in Table 2 of the Permit, it is in Probable Out-of-Compliance (POOC) status. According to the Permit, EFR is then required to immediately initiate accelerated sampling of that pollutant EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 2 (see the Permit, Part I.G.1). No new compliance parameters went into accelerated monitoring frequency POOC based on sampling during the 3rd Quarter 2023. When monitoring wells have parameters that have exceeded the GWCL two or more consecutive times they are in Out-of-Compliance (OOC) status (see the Permit, Part I.G.2). No new compliance parameters went into OOC status based on their first consecutive non-exceedances occurring during the quarter and/or previous quarter: In the event a constituent is in OOC status, EFR is required to prepare and submit within 30 calendar days to the Director a plan and time schedule for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain groundwater quality to ensure that Permit limits will not be exceeded at the compliance monitoring point and that DMT or BAT will be re-established, in accordance with Part I.G.4(c) of the Permit. Table 1 and Table 2 below list monitoring wells with parameters currently in OOC or POOC status as of the 3rd Quarter of 2023. The following wells therefore are required to be sampled under the accelerated monitoring requirements. EFR is required to notify the DWMRC on a quarterly basis regarding wells and parameters which went into accelerated monitoring during the period [Part I.G.1(a), Accelerated Monitoring Status Reports (AMSR)]. Table 1 - Wells Monitored Quarterly Accelerated to Monthly Monitoring Well Class *Position Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-11 Class II water D-3 Chloride Sulfate Total Dissolved Solids Manganese Nitrate + Nitrite (as N) Selenium 3rd Quarter 2019 3rd Quarter 2019 3rd Quarter 2020 3rd Quarter 2021 1st Quarter 2022 4th Quarter 2022 November 2019 November 2019 November 2020 November 2021 June 2022 March 2023 MW-25 Class III water D3 Chloride 4th Quarter 2022 March 2023 MW-26(a) Class III water C-2 Nitrate + Nitrite (as N) Chloroform Chloride February 2010 February 2010 February 2010 May 2010 May 2010 May 2010 MW-30 Class II water D-2 Nitrate + Nitrite (as N) Chloride Uranium Selenium Field pH February 2010 1st Quarter 2011 1st Quarter 2021 1st Quarter 2019 4th Quarter 2022 May 2010 May 2011 2nd Quarter 2021 May 2019 March 2023 MW-31 Class III water D-2 Nitrate + Nitrite (as N) Chloride Total Dissolved Solids Sulfate Uranium 1st Quarter 2010 1st Quarter 2011 3rd Quarter 2019 3rd Quarter 2019 2nd Quarter 2020 May 2010 May 2011 November 2019 November 2019 August 2020 EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 3 D = Down-gradient; U = Up-gradient; C = Cross-gradient; 1,2,3,4A, 4B = Cell # a = Monitoring well MW-26 is a pumping well for the Chloroform investigation Table 2 - Wells Monitored Semi-annually Accelerated to Quarterly Monitoring Well Class *Position Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-03A Class III water D-4B Selenium 2nd Quarter 2023 3rd Quarter 2023 MW-05 Class II water D-3 Uranium 2nd Quarter 2023 3rd Quarter 2023 MW-17 Class III water D-4A Chloride 4th Quarter 2022 2nd Quarter 2023 MW-24 Class III water D-1 Beryllium Cadmium Thallium Field pH Fluoride Nickel Manganese Sulfate Gross Alpha Total Dissolved Solids 1st Quarter 2017 2nd Quarter 2018 2nd Quarter 2018 2nd Quarter 2018 1st Quarter 2018 1st Quarter 2018 1st Quarter 2019 1st Quarter 2020 1st Quarter 2020 2nd Quarter 2021 1st Quarter 2018 3rd Quarter 2018 3rd Quarter 2018 3rd Quarter 2018 3rd Quarter 2019 3rd Quarter 2019 1st Quarter 2020 3rd Quarter 2020 3rd Quarter 2021 3rd Quarter 2021 MW-27 Class III water U-1 Nitrate + Nitrite (as N) Fluoride 2nd Quarter 2010 2nd Quarter 2022 3rd Quarter 2010 3rd Quarter 2022 MW-28 Class III water D-1 Chloride Uranium Selenium Nitrate + Nitrite (as N) Total Dissolved Solids 2nd Quarter 2010 2nd Quarter 2014 2nd Quarter 2019 1st Quarter 2019 2nd Quarter 2023 3rd Quarter 2010 2nd Quarter 2014 3rd Quarter 2019 3rd Quarter 2020 3rd Quarter 2023 MW-29 Class III water D-2 Uranium 1st Quarter 2020 3rd Quarter 2021 MW-32 Class III water C-2 Chloride 2nd Quarter 2014 4th Quarter 2014 MW-37 Class III water D-4B Field pH 4th Quarter 2022 2nd Quarter 2023 * D = Down-gradient; U = Up-gradient; C = Cross-gradient; 1, 2, 3, 4A, 4B = Cell # Each well with a parameter in accelerated status is described in detail below: EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 4 Wells Monitored Quarterly - Accelerated to Monthly Monitoring Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-11 Class II Downgradient of Cell 3 Chloride Sulfate Total Dissolved Solids Manganese Nitrate + Nitrite (as N) Selenium 3rd Quarter 2019 3rd Quarter 2019 3rd Quarter 2020 3rd Quarter 2021 1st Quarter 2022 4th Quarter 2022 November 2019 November 2019 November 2020 November 2021 June 2022 March 2023 Chloride and Nitrate + Nitrite (as N) - MW-11 is downgradient of the Nitrate plume and actions currently being implemented from an approved CAP for Nitrate + nitrite are expected to address chloride also. A 30-day plan and time schedule (P&TS) for assessment to address consecutive exceedances is not necessary. Additional actions are not required at this time and concentrations of these constituents in groundwater will be monitored closely. Sulfate - Under the current GWDP, the first consecutive exceedances of the 1,309 mg/L GWCL occurred during the accelerated monthly July and August 2021 sample events. A Source Assessment Report (SAR) was approved by DWMRC on July 27, 2022, which proposed the GWCL be modified to 1,493.6 mg/L. The new GWCL will become effective on the next revision of the GWDP. In the 3rd Quarter 2023, Sulfate exceeded the current 1,309 mg/L GWCL during the July and September monthly sample events (1,370 mg/L and 1,330 mg/L respectively). Total Dissolved Solids (TDS) – TDS exceeded the GWCL of 2,528 mg/L during the 3rd Quarter 2020 sampling event and on three occasions during monthly sampling after, however, never on consecutive occasions. At the conclusion of the 2nd quarter 2023, TDS had not exceeded the GWCL for the last 8 monthly sample events. A request for removal of TDS from accelerated sampling was approved by the Division in a letter dated August 22, 2023. TDS did not exceed the GWCL during the two monthly sampling events performed in the 3rd Quarter 2023 (July and August) and was returned to quarterly baseline sampling thereafter. Manganese – Under the current GWDP, consecutive exceedances of the conservative 237 ug/L GWCL for Manganese first occurred during the 3rd and 4th Quarter 2021 sampling events. A SAR was approved by DWMRC on July 27, 2022 which proposed the GWCL be modified to 376 ug/L. The new GWCL will become effective on the next revision of the GWDP. Including the 3rd Quarter 2023, 9 of the last 14 accelerated monthly sample results have been below the current GWCL. Selenium – Consecutive exceedances of the current 12.5 ug/L GWCL for Selenium first occurred during the 3rd Quarter and 4th Quarter 2022 sampling events. Accelerated monthly sampling began in February 2023. A SAR was approved by DWMRC on November 6, 2023 which proposed the GWCL be modified to 20.49 ug/L. The new GWCL will become effective on the next revision of the GWDP. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 5 Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-25 Class III water Downgradient of Cell 3 Chloride 4th Quarter 2022 March 2023 Chloride – Since the onset for sampling Chloride in groundwater at MW-25 in 2005, the concentration has remained from approximately 30-35 mg/L. Single exceedances of the 35 mg/L GWCL occurred during the 3rd Quarter 2015 sampling event then did not occur until the 4th Quarter 2022 sampling event when the concentration was 35.8 mg/L. Accelerated monthly sampling began in the 1st Quarter 2023. Since then, Chloride exceeded the GWCL in 3 of the 9 monthly sampling events and on consecutive occasions in the June and July 2023 sample events at concentrations just over the GWCL. An approved CAP addressing nitrate + nitrite contamination in groundwater is expected to address chloride concentrations at nearby wells also. The actions specified in the CAP are currently being implemented, therefore a P&TS for assessment to address consecutive exceedances is not necessary. Well Water Class *Position Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-26 Class III water Cross Gradient of Cell 2 Nitrate + Nitrite (as N) Chloroform Chloride February 2010 February 2010 February 2010 May 2010 May 2010 May 2010 Note: MW-26 is used as a pumping well for the ongoing chloroform capture program and is expected to yield increased concentrations of chloroform in groundwater. MW-26 is also located within the nitrate plume which also contains elevated concentrations of chloride in groundwater. CAPs have been approved by DWMRC addressing chloroform in 2011 and Nitrate + Nitrite/Chloride in 2012. Activities associated with the CAPs are on-going and consecutive exceedances of the GWCLs for these constituents is expected to occur. A P&TS for assessment of consecutive exceedances is not necessary. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 6 Well Water Class *Position Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-30 Class II water Downgradient of Cell 2 Nitrate + Nitrite (as N) Chloride Uranium Selenium Field pH February 2010 1st Quarter 2011 1st Quarter 2021 1st Quarter 2019 4th Quarter 2022 May 2010 May 2011 2nd Quarter 2021 May 2019 March 2023 Nitrate + Nitrite (as N) and Chloride – MW-30 is downgradient from and within the Nitrate plume and actions currently being implemented from an approved CAP for Nitrate + nitrite are expected to address chloride also. A P&TS for assessment to address consecutive exceedances is not necessary, concentrations of these constituents in groundwater will be monitored closely. Uranium and Selenium - Concentrations of both of these constituents in groundwater has increased gradually at similar rates since the inception of MW-30 in 2005. Under the current GWDP, consecutive exceedances of the 9.82 ug/L GWCL for Uranium occurred in 2021 and the 47.2 ug/L GWCL for selenium, established during the 2018 GWDP revision, was exceeded on consecutive occasions in 2019. A SAR was approved by DWMRC on April 5, 2022, which proposed modifications of the GWCLs for Uranium to 13.11 ug/L and for Selenium to 72.52 ug/L. The new GWCL will become effective in the next revision of the GWDP. Uranium exceeded the GWCL in 2 of the 3 accelerated monthly sampling events in the 3rd Quarter 2023 (10.3 ug/L, 11.4 ug/L). Selenium exceeded the GWCL in all of the accelerated monthly sampling events in the 3rd Quarter 2023 (70.7 ug/L, 70.8 ug/L, 73.0 ug/L). Field pH – MW-30 was sampled for Field pH since 2005 and monthly since 2007. The first exceedance of the GWCL range occurred in June 2011. Exceedances, including consecutive occurred during monthly sampling from 2011-2018 and the GWCL range was modified to 6.47- 8.5 in the 2018 GWDP revision. Since the 2018 permit revision, only a few single exceedances of the GWCL range have occurred. Field pH was within the GWCL range during all three of the 3rd Quarter 2023 accelerated monthly sampling events and has been within the GWCL range during the last 10 sample events. A request to return to quarterly baseline monitoring frequency was approved by DWMRC on November 6, 2023. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 7 Well Water Class *Position Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-31 Class III water Downgradient of Cell 2 Nitrate + Nitrite (as N) Chloride Total Dissolved Solids Sulfate Uranium 1st Quarter 2010 1st Quarter 2011 3rd Quarter 2019 3rd Quarter 2019 2nd Quarter 2020 May 2010 May 2011 November 2019 November 2019 August 2020 Nitrate + Nitrite (as N) and Chloride – MW-31 is downgradient from and within the Nitrate/Chloride plume and actions currently being implemented from an approved CAP for Nitrate + nitrite are expected to address chloride also. A P&TS for assessment to address consecutive exceedances is not necessary, concentrations of these constituents in groundwater will continue to be monitored closely. Total Dissolved Solids (TDS) and Sulfate – Consecutive exceedances under the current GWCLs for TDS (2,132 mg/L) and Sulfate (993 mg/L), established during the 2019 GWDP revision, occurred in the 3rd and 4th Quarter 2019 sampling events for both constituents. A SAR was approved by DWMRC on August 6, 2020, which proposed modifications of the GWCL for TDS to 2,664 mg/L and Sulfate to 1,170.5 mg/L. The new GWCLs will become effective in the next revision of the GWDP. Both constituents have experienced increases in concentrations in MW-31 since 2005, however, per DWMRC review, from 2021 until the 3rd Quarter 2023, a linear trend analysis shows a flattening trend for TDS and Sulfate. TDS and Sulfate exceeded their current GWCLs during all three of the 3rd Quarter 2023 monthly accelerated sampling events. Uranium - The current GWCL for Uranium of 15 ug/L was established during the 2019 GWDP revision. Consecutive exceedances of the current GWCL occurred in the 2nd and 3rd Quarter 2020 sampling events and accelerated monthly sampling began in August 2020. A SAR was approved by DWMRC on July 7, 2021, which proposed modifications of the of the GWCL to 29.03 ug/L. The new GWCL will become effective in the next revision of the GWDP. Uranium exceeded the GWCL during all three of the 3rd Quarter 2023 monthly accelerated sampling events at concentrations of 23.4, 25.8, and 27.1 ug/L. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 8 Wells Monitored Semi-annually Accelerated to Quarterly Monitoring Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-03A Class III Downgradient of Cell 4B Selenium 2nd Quarter 2023 4th Quarter 2023 Selenium – Selenium exceeded the current GWCL of 109.58 ug/L in the 1st Semi-annual sampling event of 2023 in April, testing at 112 ug/L. Accelerated quarterly sampling was initiated in the 3rd Quarter 2023 sampling event and a second consecutive exceedance was recorded. A P&TS for assessment was submitted and approved by DWMRC on December 5, 2023. A SAR is now required to be submitted 90 days from December 5th. Per DWMRC review, a linear trend analysis of Selenium concentration in groundwater since 2005 appears to show a slight upward trend, however the concentration has been variable over that time, fluctuating between 70 ug/L and 110 ug/L during the majority of sample events. Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-05 Class II Downgradient of Cell 3 Uranium 2nd Quarter 2023 4th Quarter 2023 Uranium – Under the current GWDP, Uranium first exceeded the GWCL of 7.5 ug/L in the 1st Semi-annual sampling event of 2023 in April. Accelerated quarterly sampling was initiated for the 3rd Quarter 2023 sampling event and results were below the GWCL. Per DWMRC review, since 2005, the Uranium concentration in groundwater at MW-05 has been below the GWCL the majority of the sample events (47 out of 56). Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-17 Class III water Downgradient of 4A Chloride 4th Quarter 2022 2nd Quarter 2023 Chloride – Chloride exceeded the 46.8 mg/L GWCL during the 2nd Semi-Annual sampling event of 2022 in October, testing at 54.0 mg/L. This is the first and only exceedance since sampling was initiated in 2005. Accelerated quarterly sampling was initiated during the 1st Quarter 2023 and results did not exceed the GWCL. Chloride did not exceed the GWCL during the subsequent 2nd and 3rd Quarter 2023 sampling events. Per DWMRC review, since 2007, the Chloride concentration in groundwater at MW-17 has been consistently between 30 mg/L and 40 mg/L with the only exceedance being during the 4th Quarter 2022 sample event. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 9 Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-24 Class III water Downgradient of Cell 1 Beryllium Cadmium Thallium Field pH Fluoride Nickel Manganese Sulfate Gross Alpha Total Dissolved Solids 4th Quarter 2017 2nd Quarter 2018 2nd Quarter 2018 2nd Quarter 2018 3rd Quarter 2018 3rd Quarter 2018 3rd Quarter 2019 1st Quarter 2020 1st Quarter 2020 2nd Quarter 2021 1st Quarter 2018 3rd Quarter 2018 3rd Quarter 2018 3rd Quarter 2018 3rd Quarter 2019 3rd Quarter 2019 1st Quarter 2020 3rd Quarter 2020 3rd Quarter 2021 3rd Quarter 2021 Note: After multiple constituents reached OOC status, a SAR was approved by DWMRC in 2019 to study groundwater trends near MW-24. The source assessment is nearing completion as Phase 2 included installation of a downgradient/co-located well (MW-41B) in April 2023. An additional P&TS for consecutive exceedances is not required. Exceedances will continue to be tracked until conclusion of the source investigation. Groundwater sampling at co-located well MW-41B was initiated for the 3rd Quarter 2023 sampling event. Gross Alpha – Gross Alpha first exceeded the 7.5 pCi/L GWCL during the 2nd Semi-Annual sampling event of 2020 in October. Accelerated quarterly sampling was initiated during the 1st Quarter 2021 and no exceedances have occurred in the 13 sample events since. Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-27 Class III water Upgradient of Cell 1 Nitrate + Nitrite (as N) Fluoride 2nd Quarter 2010 2nd Quarter 2022 3rd Quarter 2010 3rd Quarter 2022 Nitrate + Nitrite (as N) - MW-27 is downgradient/cross-gradient from the Nitrate plume and a CAP addressing Nitrate + Nitrite in groundwater was approved in 2012. Activities associated with the CAP are on-going and a P&TS for assessment of consecutive exceedances is not required for Nitrate + Nitrite and Chloride. In the previous 5 quarterly sampling events including the 3rd Quarter 2023, Nitrate + Nitrite (as N) has been below the GWCL of 5.6 mg/L. Fluoride –Since 2010, Fluoride only exceeded the 0.85 mg/L GWCL one time during the 1st Semi-Annual sampling event of 2022. Accelerated quarterly sampling was initiated during the 3rd Quarter 2022. No exceedances have occurred since and concentrations have been decreasing since the 4th Quarter 2022. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 10 Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-28 Class III water Downgradient of Cell 1 Chloride Uranium Selenium Nitrate + Nitrite (as N) 2nd Quarter 2010 2nd Quarter 2014 2nd Quarter 2019 1st Quarter 2019 3rd Quarter 2010 2nd Quarter 2014 3rd Quarter 2019 3rd Quarter 2020 Chloride and Nitrate + Nitrite (as N) – It appears that MW-28 is impacted by the western margin of the Nitrate and Chloride plume and a CAP addressing Nitrate + Nitrite and Chloride in groundwater was approved in 2012. Activities associated with the CAP are on-going and a P&TS for assessment of consecutive exceedances is not required for Nitrate + Nitrite and Chloride. Per DWMRC review, after increases in concentrations of both constituents since sampling of MW-28 began in 2005, Nitrate + Nitrite concentration from 2022-2023 has remained near the GWCL of 5 mg/L and Chloride concentration has remained near 150 mg/L. Uranium and Selenium - Consecutive exceedances of the GWCLs for Uranium (4.9 ug/L) and Selenium (11.1 ug/L) have occurred and a SAR was approved by DWMRC on January 21, 2021. The SAR proposed modifications of the GWCLs for Uranium to 12.29 ug/L and for Selenium to 17.9 ug/L. The new GWCL will become effective in the next revision of the GWDP. Per DWMRC review, concentrations of Uranium and Selenium in groundwater at MW-28 have increased since 2017 but appear to show a flattening trend recently. Uranium exceeded the GWCL during the 3rd Quarter 2023 sample event (11.2 ug/L). Selenium exceeded the GWCL during the 3rd Quarter 2023 sample event (23.5 ug/L). Concentrations of Uranium and Selenium in groundwater at MW-28 will continue to be monitored closely. Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-29 Class III water Downgradient of Cell 2 Uranium 4th Quarter 2020 2nd Quarter 2021 Uranium – The first exceedance of the current 15 ug/L GWCL was during the 2nd semi-annual sampling event of 2020. Accelerated quarterly sampling and a consecutive exceedance occurred in the 1st Quarter of 2021. A P&TS was submitted and a SAR was approved by DWMRC on January 18, 2022. A modified GWCL of 20.2 ug/L will become effective in the next revision of the GWDP. Per DWMRC review, Uranium concentrations in MW-29 from 2021-2023 have remained steady and near the GWCL of 15 ug/L. Uranium did not exceed the GWCL in the 3rd Quarter 2023 sampling event (14.1 ug/L). EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 11 Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-32 Class III water Cross- Gradient of Cell 2 Chloride 2nd Quarter 2014 4th Quarter 2014 Chloride – MW-32 (also known as TW4-17) has been sampled for Chloride since 2005. The GWCL has been established as 35.39 mg/L. Per DWMRC review, a linear trend analysis of Chloride in MW-32 since 2005 appears to show a slight increasing trend, however, the concentration in groundwater has generally remained from 30-40 mg/L with a handful of exceptions over that same time. MW-32 is nearby the Nitrate plume and a CAP addressing Nitrate + Nitrite and Chloride in groundwater was approved in 2012. Activities associated with the CAP are on-going and a P&TS for assessment of consecutive exceedances is not required for Chloride. Chloride exceeded the GWCL in the 3rd Quarter 2023 sampling event (38.4 mg/L). Well Water Class Location Parameter Date of First Exceedance of GWCL Date Accelerated Monitoring First Required MW-37 Class III water Downgradient of Cell 4B Field pH 4th Quarter 2022 2nd Quarter 2023 Field pH – During quarterly sampling from 2011 – 2017, Field pH exceeded the current GWCL limits of 6.61 - 8.5 in 8 of the 26 sampling events including consecutive exceedances in 2016- 2017. Under the current GWDP, semi-annual sampling was performed from 2018 until an exceedance occurred during the 2nd Semi-Annual sampling event of 2022 in November (pH = 6.60). A second consecutive exceedance of the GWCL limits occurred during accelerated quarterly sampling initiated during the 1st Quarter 2023 (pH = 6.55) and Field pH at MW-37 went into OOC status. A P&TS was submitted, and a SAR was approved by DWMRC on November 6, 2023. Per the SAR, the Field pH GWCL limits were modified to 6.05-8.5, based on the lowest historical value, and will become effective in the next revision of the GWDP. Per DWMRC review, a linear trend analysis since 2016 appears to show Field pH with an increasing trend towards neutral. Field pH tested at 7.02 during the 3rd Quarter 2023 sample event. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 12 DWMRC Review Checklist: 1. Monitoring Wells Purged for Two Casing Volumes Before Sample Collection: As stated in Section 6.2.7 of the EFR Quality Assurance Plan (QAP), Rev. 7.7, EFR has a choice regarding purge volumes as follows: “1. Purging three well casing volumes with a single measurement of field parameters 2. Purging two casing volumes with stable field parameters (within 10% RPD) 3. Purging a well to dryness and stability of a limited list of field parameters after recovery” Per DWMRC review of the Report, the following purge methods were used during the 3rd Quarter 2023 (including accelerated samples). Purge methods and volumes are summarized in Tab G, on Table G-1A and G-1B of the Report: Quarter # Purged 2 Casing Volumes # Purged to Dryness # Purged 3 Casing Volumes 3rd Qtr. 2023 25 3 3 (continuous pumping) When purging two casing volumes, the QAP directs EFR to first calculate the amount of time to evacuate two casing volumes and then to pump for that length of time. Per DWMRC cross-check of the field data sheets for each of the reports reviewed, it appears EFR correctly calculated the well casing volumes and evacuated the required two volumes (when 2 casing volume method selected) in monitoring wells prior to sample collection during the 3rd Quarter 2023 monitoring period. Volumes are calculated according to measured pump rates and can be verified by calibration marks on the collection containers. During the 3rd Quarter 2023 monitoring period, three monitoring wells were pumped or bailed to dryness (MW-37, MW-38, and MW-41B). In cases where wells are evacuated to dryness the QAP Rev. 7.7 (Attachment 2-3) requires that: “(vii) If the well is purged to dryness: Record the number of gallons purged on the Field Data Worksheet. The well should be sampled as soon as a sufficient volume of groundwater is available to fill sample containers. Upon arrival at the well after recovery or when sufficient water is available for sampling measure depth to water and record on the Field Data Worksheet. Take one set of measurements of field parameters for pH, specific conductance, and temperature only. Collect the samples into the appropriate sample containers. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 13 Take an additional set of measurements of field parameters for pH, specific conductance and temperature after the samples have been collected. If the field parameters of pH, specific conductance and temperature are within 10% RPD the samples can be shipped for analysis. If the field parameters of pH, specific conductance and temperature are not within 10% RPD, dispose of the sample aliquots, and purge the well again as described above. Repeat this process, if necessary, for three complete purging events. If after the third purging the event, the parameters of pH, specific conductance and temperature do not stabilize to within 10% RPD, the well is considered sufficiently purged and collected samples can be submitted for analysis.” DWMRC staff verified that in cases where the monitoring well was evacuated to dryness and samples were collected, the number of gallons evacuated was recorded in compliance with the QAP. Additionally, depth to water before sample collection was recorded on all applicable field data worksheets which resolved past DWMRC comments. 2. Analytical Laboratories Used by EFR Certified by State of Utah to Perform Analysis for all Analytes: The analytical laboratories (GEL Laboratories LLC, Charleston, SC; Chemtech Ford Laboratory, Sandy, UT) were contracted by EFR to perform analysis on the samples collected during the 3rd Quarter 2023. Per DWMRC review of the National Environmental Laboratory Accreditation Management System Website, both laboratories have an active certification within the State of Utah. Screen prints from the website showing certification status are included in Appendix A. Upon further cross checking of laboratory certification for specific parameters, it appears that the EFR contract laboratories were certified to perform analysis for the specified parameters. 3. Laboratory Report Turn Around Times: Per DWMRC review of Laboratory reports contained in Tab E and Tab F, it was noted that laboratory report turnaround times for both quarterly and accelerated monitoring was approximately 27 days for radiological analysis performed by GEL and 14-17 days for all other analyses performed by Chemtech Ford (not including re-submission/corrected reports). The turn- around times and EFR data review timelines appear to be reasonable/appropriate. 4. Sample Holding Times: Per review of the 3rd Quarter 2023 Report (Section 3.4.2, Tab E, Tab F, and Tables G-2A and G- 2B in Tab G of the Report, all method holding times were met for each analyte submitted for laboratory analysis (for quarterly and accelerated samples). DWMRC staff cross checked all EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 14 holding time requirements and verified that all samples/analytes appeared to be analyzed within holding times during the 3rd Quarter 2023 reporting period. 5. Sample Preservation: Per review of the 3rd Quarter 2023 Report (Section 3.4.3, Tab E, Tab F, Tab G), it appears that all samples required to be chilled (≤6° C) met the temperature preservation requirements. Per review of the laboratory check in sheets and laboratory QA/QC, no issues related to sample preservation were noted. Per EFR information and method requirements, samples for gross alpha analysis do not have a sample temperature requirement. 6. Analytical Reporting Limits: Per DWMRC review of the quarterly and accelerated electronic laboratory analytical reports as well as Tables G-5A and G-5B in the 3rd Quarter 2023 Report, it appears that laboratory reporting limits met the required reporting limits set forth in Table 1 of the QAP. 7. Sample Trip Blank Evaluation: Per review of the 3rd Quarter 2023 Report, it appears that all trip blank samples met the following criteria: - Per Section 3.4.6, Tabs E and F, Table G-6A, and Table G-6B of the 3rd Quarter 2023 Report, all trip blank results associated with the quarterly and accelerated samples were non detect for volatile organic compounds. - Per Table G-2A and Table G-2B in Tab G of the Report, all trip blank samples associated with the quarterly and accelerated samples were analyzed within the allowed holding time. - Per Table G-3A and Table G-3B in Tab G of the Report, all trip blank samples associated with the quarterly and accelerated samples were received by the Laboratory within an acceptable temperature range. - Per Table G-5A and Table G-5B in Tab G of the Report, the laboratory reporting limit for all trip blank samples associated with the quarterly and accelerated samples met the required reporting limits. 8. Review of Time-Concentration Plots The Permit Part I.F.1.g requires EFR to submit Time-Concentration Plots for each monitoring well for primary indicators of cell leakage; chloride, fluoride, sulfate, and uranium. DWMRC notes that per the discussions with EFR, it was agreed that EFR need not plot trend lines on the Time Concentration Plots and that all data is included on the plots (no data culled from the set). Per DWMRC review of the 3rd Quarter 2023 Report, the reviewed plots appear to be in conformance with the agreed upon changes. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 15 9. Review of Depth to Groundwater Measurements and Water Table Contour Maps Per DWMRC cross checks of groundwater elevation measurement calculations used for the 3rd Quarter 2023, approximately 5% of wells cross checked, comparing surface casing measured elevations minus measured static levels with plotted elevations, no errors were noted. The upper wildlife ponds at the White Mesa Mill were taken offline (pond recharge from Recapture Reservoir discontinued) during the 2nd Quarter 2011 to re-establish groundwater contours. Hydrographs of the upper wildlife pond ground water piezometers (Water Level Elevation vs. Time) are included in Appendix B (Northern piezometers and southern piezometers). It was also noted that the static water levels in several monitoring wells close to the upper wildlife ponds showed significant decrease in water levels since the ponds were taken offline. These declines can be attributed to natural dissipation of the area ground water mound and/or ground water pumping activities related to corrective action of nitrate and chloroform contamination plumes (development of cone of depressions around pumping wells). Nitrate and Chloroform Corrective Action Plan Pumping Wells: Ground water elevations are being impacted by effects from ground water pumping for the nitrate and chloroform contamination plume remediation. The following monitoring wells have been converted to active pumping wells: Nitrate Pumping Wells – TW4-22, TW4-24, TW4-25, TWN-2 (The nitrate pumping project was initiated during January 2013). Chloroform Pumping Wells – MW-4, MW-26, TW4-1, TW4-2, TW4-4, TW4-11, TW4-19, TW4- 21, TW4-22, TW4-24, TW4-25, TW4-37, TW4-39. The pumping wells for both the nitrate and chloroform projects are set up with a delay device wherein the wells purge for a set amount of time then shut off to let the well recharge. All pumping wells include a flow meter which records the volume of water pumped from the well in gallons. Quarterly nitrate and chloroform reports are prepared by EFR and include pump volumes and delineation of pump capture zones based on kriged water contours. DWMRC expects that ground water elevation contours will continue to adjust in response to the pumping activities and discontinuance of recharge to the upper wildlife ponds. 12. Conclusions and Recommendations Per the Division review it appears that the Report complies with Permit and QAP. Therefore, a letter will be drafted notifying EFR of the review and closing out of the November 7, 2023, 3rd Quarter, 2023 Groundwater Report. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 16 13. References 1 Energy Fuels Resources (USA) Inc., November 7, 2023, 3rd Quarter 2023 Groundwater Monitoring Report, Groundwater Discharge Permit UGW370004, White Mesa Uranium Mill. 2 Energy Fuels Resources (USA) Inc., October 25, 2023, State of Utah Ground Water Discharge Permit No. UGW370004 White Mesa Uranium Mill – Notice Pursuant to Part I.G.1(a). 3 Energy Fuels Resources (USA) Inc., February 15, 2022, White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP), Revision 7.7. 4 INTERA Incorporated, 2007, Revised Background Groundwater Quality Report: Existing Wells for Dension Mines (USA) Corp.’s White Mesa Uranium Mill Site, San Juan County, Utah. 5 INTERA Incorporated, 2007, Background Groundwater Quality Report: New Wells for Denison Mines (USA) Corp.’s White Mesa Uranium Mill Site, San Juan County, Utah. 6 Hurst, T.G., and Solomon, D.K., 2008. Summary of Work Completed, Data Results, Interpretations and Recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill located near Blanding Utah. Prepared by University of Utah Department of Geology and Geophysics. 7 Utah Department of Environmental Quality, March 8, 2021, Modified Utah Ground Water Discharge Permit No. UGW370004 issued for the Energy Fuels Resources (USA) Inc. White Mesa Uranium Mill. EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 17 Appendix A – State of Utah Laboratory Certifications EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 18 EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 19 EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 20 Appendix B – Hydrographs of the Upper Wildlife Pond Groundwater Piezometers EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 21 EFR 3rd Quarter 2023 Groundwater Monitoring Report DWMRC Review Memo Page 22 Signature: Email:pgoble@utah.gov