DSHW-2024-006040

ANALYTICAL REPORT
PREPARED FOR
Attn: Dave Lunt
Clean Harbors Environmental Services Inc
11600 North Aptus Road
Exit 56
Aragonite UT 84083
Generated 3/25/2024 9:50 AM
JOB DESCRIPTION
Carbon Beds Test
JOB NUMBER
140-35862-1
See page two for job notes and contact information.
Knoxville TN 37921
5815 Middlebrook Pike
Eurofins Knoxville
Page 1 of 864
Eurofins Knoxville
Eurofins Knoxville is a laboratory within TestAmerica Laboratories, Inc., a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager.
Authorization
Generated
3/25/2024 9:50 AM
Authorized for release by
Jamie A McKinney, Senior Project Manager
[e-mail]
865 291-3000
3/25/2024
9:50:51 AM
Page 2 of 864
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .33
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .40
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .41
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .43
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .45
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .46
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .47
Air - GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .47
Method TO15 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .47
Method TO15 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .48
Method TO15 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .66
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .379
Method TO15 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .379
Method TO15 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .740
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .775
Method TO15 Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .775
Method TO15 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .797
Method TO15 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .817
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Table of Contents
Method TO15 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .836
Method TO15 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .853
Air Canister Dilution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .860
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . .861
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .862
Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .864
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Definitions/Glossary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Qualifiers
Air - GC/MS VOA
Qualifier Description
CI The peak identified by the data system exhibited chromatographic interference that could not be resolved. There is reason to suspect
there may be a high bias.
Qualifier
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Air - GC/MS VOA TICs
Qualifier Description
J Indicates an Estimated Value for TICs
Qualifier
N Presumptive evidence of material.
T Result is a tentatively identified compound (TIC) and an estimated value.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Knoxville
3/25/2024
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Job Narrative
140-35862-1
Receipt
The samples were received on 3/12/2024 10:00 AM.Unless otherwise noted below,the samples arrived in good
condition,and where required,properly preserved and on ice.
Air -GC/MS VOA
Methods TO 15 LL,TO-14A,TO-15:EPA methods TO-14A and TO-15 specify the use of humidified "zero air"as the
blank reagent for canister cleaning,instrument calibration and sample analysis.Ultra-high purity humidified nitrogen
from a cryogenic reservoir is used in place of "zero air"by Eurofins TestAmerica Knoxville.
Methods TO 15 LL,TO-15:Although the BFB tune is flagged as outside control limits for TO-14A on batch 140-84641,
the results are within limits for TO-15,which is required for this project.
Method TO-15:The continuing calibration verification (CCV)associated with batch 140-84584 exhibited %difference
of >30%for the following analyte(s)Methylcyclohexane and Ethanol;however,the results were within the LCS
acceptance limits.The EPA method requires that all target analytes in the continuing calibration verification standard
be within 30%difference from the initial calibration.According to the laboratory standard operating procedure,the
continuing calibration is acceptable if it meets the laboratory control sample acceptance criteria.
No additional analytical or quality issues were noted,other than those described above or in the Definitions/Glossary
page.
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Detection Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-1 Lab Sample ID: 140-35862-1
1,1,1-Trichloroethane
RL
4.0 ppb v/v
MDL
1.4
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.01J3.6 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 4.0 ppb v/v0.48 Total/NA4.011.0 J TO-15
1,1-Dichloroethane 4.0 ppb v/v0.54 Total/NA4.0120 TO-15
1,2,3-Trimethylbenzene 4.0 ppb v/v1.8 Total/NA4.014.6 TO-15
1,2,4-Trimethylbenzene 4.0 ppb v/v1.0 Total/NA4.0118 TO-15
1,3,5-Trimethylbenzene 8.0 ppb v/v3.2 Total/NA4.016.6 J TO-15
2-Butanone (MEK)20 ppb v/v3.6 Total/NA4.01160 TO-15
4-Ethyltoluene 8.0 ppb v/v1.1 Total/NA4.015.2 J TO-15
4-Methyl-2-pentanone (MIBK)20 ppb v/v2.8 Total/NA4.0143 TO-15
Acetone 600 ppb v/v110 Total/NA4.01140J TO-15
Benzene 4.0 ppb v/v0.66 Total/NA4.01150 TO-15
Chloroform 4.0 ppb v/v0.72 Total/NA4.011.4 J TO-15
cis-1,2-Dichloroethene 4.0 ppb v/v0.50 Total/NA4.0149 TO-15
Cyclohexane 8.0 ppb v/v1.9 Total/NA4.0199 TO-15
Ethanol 100 ppb v/v44 Total/NA4.01160 TO-15
Ethyl acetate 40 ppb v/v3.0 Total/NA4.0142 TO-15
Ethylbenzene 4.0 ppb v/v0.66 Total/NA4.0127 TO-15
Isopropyl alcohol 160 ppb v/v19 Total/NA4.013500 TO-15
Methylcyclohexane 4.0 ppb v/v1.0 Total/NA4.01150CI TO-15
Methylene Chloride 20 ppb v/v6.8 Total/NA4.0119J TO-15
m-Xylene & p-Xylene 4.0 ppb v/v1.5 Total/NA4.01100 TO-15
n-Heptane 8.0 ppb v/v0.70 Total/NA4.01190 TO-15
n-Hexane 8.0 ppb v/v1.3 Total/NA4.01240 TO-15
Nonane 8.0 ppb v/v2.2 Total/NA4.0144 TO-15
o-Xylene 4.0 ppb v/v0.76 Total/NA4.0131 TO-15
Styrene 4.0 ppb v/v1.2 Total/NA4.014.1 TO-15
Tetrachloroethene 4.0 ppb v/v0.58 Total/NA4.0129 TO-15
Toluene 20 ppb v/v1.1 Total/NA4.01200 TO-15
Trichloroethene 4.0 ppb v/v0.66 Total/NA4.01560 TO-15
1,1,1-Trichloroethane
RL
22 ug/m3
MDL
7.9
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.01J20 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 31 ug/m33.7 Total/NA4.018.0 J TO-15
1,1-Dichloroethane 16 ug/m32.2 Total/NA4.0180 TO-15
1,2,3-Trimethylbenzene 20 ug/m38.9 Total/NA4.0123 TO-15
1,2,4-Trimethylbenzene 20 ug/m34.9 Total/NA4.0189 TO-15
1,3,5-Trimethylbenzene 39 ug/m316 Total/NA4.0132J TO-15
2-Butanone (MEK)59 ug/m311 Total/NA4.01470 TO-15
4-Ethyltoluene 39 ug/m35.2 Total/NA4.0125J TO-15
4-Methyl-2-pentanone (MIBK)82 ug/m311 Total/NA4.01180 TO-15
Acetone 1400 ug/m3270 Total/NA4.01340J TO-15
Benzene 13 ug/m32.1 Total/NA4.01480 TO-15
Chloroform 20 ug/m33.5 Total/NA4.016.8 J TO-15
cis-1,2-Dichloroethene 16 ug/m32.0 Total/NA4.01190 TO-15
Cyclohexane 28 ug/m36.4 Total/NA4.01340 TO-15
Ethanol 190 ug/m383 Total/NA4.01300 TO-15
Ethyl acetate 140 ug/m311 Total/NA4.01150 TO-15
Ethylbenzene 17 ug/m32.9 Total/NA4.01120 TO-15
Isopropyl alcohol 390 ug/m347 Total/NA4.018500 TO-15
Methylcyclohexane 16 ug/m34.0 Total/NA4.01590CI TO-15
Methylene Chloride 70 ug/m324 Total/NA4.0168J TO-15
m-Xylene & p-Xylene 17 ug/m36.4 Total/NA4.01440 TO-15
Eurofins Knoxville
This Detection Summary does not include radiochemical test results.
3/25/2024
9:50:51 AM
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Detection Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-1 (Continued)Lab Sample ID: 140-35862-1
n-Heptane
RL
33 ug/m3
MDL
2.9
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.01760 TO-15
n-Hexane 28 ug/m34.5 Total/NA4.01830 TO-15
Nonane 42 ug/m312 Total/NA4.01230 TO-15
o-Xylene 17 ug/m33.3 Total/NA4.01140 TO-15
Styrene 17 ug/m35.1 Total/NA4.0117 TO-15
Tetrachloroethene 27 ug/m33.9 Total/NA4.01190 TO-15
Toluene 76 ug/m34.3 Total/NA4.01750 TO-15
Trichloroethene 22 ug/m33.6 Total/NA4.013000 TO-15
Client Sample ID: 03072024-2 Lab Sample ID: 140-35862-2
1,1,1-Trichloroethane
RL
4.0 ppb v/v
MDL
1.4
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA3.954.1 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 4.0 ppb v/v0.47 Total/NA3.950.95 J TO-15
1,1-Dichloroethane 4.0 ppb v/v0.53 Total/NA3.9523 TO-15
1,2,3-Trimethylbenzene 4.0 ppb v/v1.8 Total/NA3.958.3 TO-15
1,2,4-Trimethylbenzene 4.0 ppb v/v0.99 Total/NA3.9530 TO-15
1,3,5-Trimethylbenzene 7.9 ppb v/v3.2 Total/NA3.9511 TO-15
2-Butanone (MEK)20 ppb v/v3.6 Total/NA3.95210 TO-15
4-Ethyltoluene 7.9 ppb v/v1.0 Total/NA3.958.5 TO-15
4-Methyl-2-pentanone (MIBK)20 ppb v/v2.8 Total/NA3.9555 TO-15
Acetone 590 ppb v/v110 Total/NA3.95180J TO-15
Benzene 4.0 ppb v/v0.65 Total/NA3.95110 TO-15
Chloroform 4.0 ppb v/v0.71 Total/NA3.950.84 J TO-15
cis-1,2-Dichloroethene 4.0 ppb v/v0.49 Total/NA3.9557 TO-15
Cyclohexane 7.9 ppb v/v1.8 Total/NA3.9576 TO-15
Ethanol 99 ppb v/v43 Total/NA3.95160 TO-15
Ethyl acetate 40 ppb v/v3.0 Total/NA3.9518J TO-15
Ethylbenzene 4.0 ppb v/v0.65 Total/NA3.9526 TO-15
Isopropyl alcohol 160 ppb v/v19 Total/NA3.953300 TO-15
Methylcyclohexane 4.0 ppb v/v0.99 Total/NA3.95140CI TO-15
Methylene Chloride 20 ppb v/v6.7 Total/NA3.959.3 J TO-15
m-Xylene & p-Xylene 4.0 ppb v/v1.4 Total/NA3.9592 TO-15
n-Heptane 7.9 ppb v/v0.69 Total/NA3.95150 TO-15
n-Hexane 7.9 ppb v/v1.2 Total/NA3.95170 TO-15
Nonane 7.9 ppb v/v2.2 Total/NA3.9565 TO-15
o-Xylene 4.0 ppb v/v0.75 Total/NA3.9530 TO-15
Styrene 4.0 ppb v/v1.2 Total/NA3.951.8 J TO-15
Tetrachloroethene 4.0 ppb v/v0.57 Total/NA3.9539 TO-15
Tetrahydrofuran 20 ppb v/v3.6 Total/NA3.9589 TO-15
Toluene 20 ppb v/v1.1 Total/NA3.95220 TO-15
Trichloroethene 4.0 ppb v/v0.65 Total/NA3.95690 TO-15
1,1,1-Trichloroethane
RL
22 ug/m3
MDL
7.8
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA3.9522 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 30 ug/m33.6 Total/NA3.957.3 J TO-15
1,1-Dichloroethane 16 ug/m32.2 Total/NA3.9591 TO-15
1,2,3-Trimethylbenzene 19 ug/m38.7 Total/NA3.9541 TO-15
1,2,4-Trimethylbenzene 19 ug/m34.9 Total/NA3.95150 TO-15
1,3,5-Trimethylbenzene 39 ug/m316 Total/NA3.9553 TO-15
2-Butanone (MEK)58 ug/m310 Total/NA3.95630 TO-15
4-Ethyltoluene 39 ug/m35.1 Total/NA3.9542 TO-15
Eurofins Knoxville
This Detection Summary does not include radiochemical test results.
3/25/2024
9:50:51 AM
Page 8 of 864
Detection Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-2 (Continued)Lab Sample ID: 140-35862-2
4-Methyl-2-pentanone (MIBK)
RL
81 ug/m3
MDL
11
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA3.95220 TO-15
Acetone 1400 ug/m3260 Total/NA3.95420J TO-15
Benzene 13 ug/m32.1 Total/NA3.95350 TO-15
Chloroform 19 ug/m33.5 Total/NA3.954.1 J TO-15
cis-1,2-Dichloroethene 16 ug/m32.0 Total/NA3.95220 TO-15
Cyclohexane 27 ug/m36.3 Total/NA3.95260 TO-15
Ethanol 190 ug/m382 Total/NA3.95310 TO-15
Ethyl acetate 140 ug/m311 Total/NA3.9563J TO-15
Ethylbenzene 17 ug/m32.8 Total/NA3.95110 TO-15
Isopropyl alcohol 390 ug/m347 Total/NA3.958000 TO-15
Methylcyclohexane 16 ug/m34.0 Total/NA3.95570CI TO-15
Methylene Chloride 69 ug/m323 Total/NA3.9532J TO-15
m-Xylene & p-Xylene 17 ug/m36.3 Total/NA3.95400 TO-15
n-Heptane 32 ug/m32.8 Total/NA3.95620 TO-15
n-Hexane 28 ug/m34.4 Total/NA3.95600 TO-15
Nonane 41 ug/m311 Total/NA3.95340 TO-15
o-Xylene 17 ug/m33.3 Total/NA3.95130 TO-15
Styrene 17 ug/m35.0 Total/NA3.957.7 J TO-15
Tetrachloroethene 27 ug/m33.9 Total/NA3.95260 TO-15
Tetrahydrofuran 58 ug/m310 Total/NA3.95260 TO-15
Toluene 74 ug/m34.2 Total/NA3.95830 TO-15
Trichloroethene 21 ug/m33.5 Total/NA3.953700 TO-15
Client Sample ID: 03072024-3 Lab Sample ID: 140-35862-3
1,1,1-Trichloroethane
RL
4.2 ppb v/v
MDL
1.5
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.16J3.3 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 4.2 ppb v/v0.50 Total/NA4.160.70 J TO-15
1,1-Dichloroethane 4.2 ppb v/v0.56 Total/NA4.1618 TO-15
1,2,3-Trimethylbenzene 4.2 ppb v/v1.9 Total/NA4.169.8 TO-15
1,2,4-Trimethylbenzene 4.2 ppb v/v1.0 Total/NA4.1635 TO-15
1,3,5-Trimethylbenzene 8.3 ppb v/v3.3 Total/NA4.1613 TO-15
2-Butanone (MEK)21 ppb v/v3.7 Total/NA4.16200 TO-15
4-Ethyltoluene 8.3 ppb v/v1.1 Total/NA4.169.8 TO-15
4-Methyl-2-pentanone (MIBK)21 ppb v/v2.9 Total/NA4.1642 TO-15
Acetone 310 ppb v/v58 Total/NA4.16260J TO-15
Benzene 4.2 ppb v/v0.69 Total/NA4.1699 TO-15
Chloroform 4.2 ppb v/v0.75 Total/NA4.160.80 J TO-15
cis-1,2-Dichloroethene 4.2 ppb v/v0.52 Total/NA4.1644 TO-15
Cyclohexane 8.3 ppb v/v1.9 Total/NA4.1662 TO-15
Ethanol 100 ppb v/v46 Total/NA4.16170 TO-15
Ethyl acetate 42 ppb v/v3.1 Total/NA4.1613J TO-15
Ethylbenzene 4.2 ppb v/v0.69 Total/NA4.1625 TO-15
Isopropyl alcohol 83 ppb v/v10 Total/NA4.162300 TO-15
Methylcyclohexane 4.2 ppb v/v1.0 Total/NA4.16110CI TO-15
Methylene Chloride 21 ppb v/v7.1 Total/NA4.169.0 J TO-15
m-Xylene & p-Xylene 4.2 ppb v/v1.5 Total/NA4.1691 TO-15
n-Heptane 8.3 ppb v/v0.73 Total/NA4.16130 TO-15
n-Hexane 8.3 ppb v/v1.3 Total/NA4.16140 TO-15
Nonane 8.3 ppb v/v2.3 Total/NA4.1663 TO-15
o-Xylene 4.2 ppb v/v0.79 Total/NA4.1631 TO-15
Eurofins Knoxville
This Detection Summary does not include radiochemical test results.
3/25/2024
9:50:51 AM
Page 9 of 864
Detection Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-3 (Continued)Lab Sample ID: 140-35862-3
Styrene
RL
4.2 ppb v/v
MDL
1.2
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.16J1.6 TO-15
Tetrachloroethene 4.2 ppb v/v0.60 Total/NA4.1637 TO-15
Tetrahydrofuran 21 ppb v/v3.7 Total/NA4.16130 TO-15
Toluene 21 ppb v/v1.2 Total/NA4.16190 TO-15
Trichloroethene 4.2 ppb v/v0.69 Total/NA4.16600 TO-15
1,1,1-Trichloroethane
RL
23 ug/m3
MDL
8.2
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.16J18 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 32 ug/m33.8 Total/NA4.165.3 J TO-15
1,1-Dichloroethane 17 ug/m32.3 Total/NA4.1672 TO-15
1,2,3-Trimethylbenzene 20 ug/m39.2 Total/NA4.1648 TO-15
1,2,4-Trimethylbenzene 20 ug/m35.1 Total/NA4.16170 TO-15
1,3,5-Trimethylbenzene 41 ug/m316 Total/NA4.1663 TO-15
2-Butanone (MEK)61 ug/m311 Total/NA4.16590 TO-15
4-Ethyltoluene 41 ug/m35.4 Total/NA4.1648 TO-15
4-Methyl-2-pentanone (MIBK)85 ug/m312 Total/NA4.16170 TO-15
Acetone 740 ug/m3140 Total/NA4.16610J TO-15
Benzene 13 ug/m32.2 Total/NA4.16320 TO-15
Chloroform 20 ug/m33.7 Total/NA4.163.9 J TO-15
cis-1,2-Dichloroethene 16 ug/m32.1 Total/NA4.16170 TO-15
Cyclohexane 29 ug/m36.7 Total/NA4.16210 TO-15
Ethanol 200 ug/m386 Total/NA4.16320 TO-15
Ethyl acetate 150 ug/m311 Total/NA4.1647J TO-15
Ethylbenzene 18 ug/m33.0 Total/NA4.16110 TO-15
Isopropyl alcohol 200 ug/m325 Total/NA4.165700 TO-15
Methylcyclohexane 17 ug/m34.2 Total/NA4.16460CI TO-15
Methylene Chloride 72 ug/m325 Total/NA4.1631J TO-15
m-Xylene & p-Xylene 18 ug/m36.6 Total/NA4.16390 TO-15
n-Heptane 34 ug/m33.0 Total/NA4.16520 TO-15
n-Hexane 29 ug/m34.6 Total/NA4.16480 TO-15
Nonane 44 ug/m312 Total/NA4.16330 TO-15
o-Xylene 18 ug/m33.4 Total/NA4.16130 TO-15
Styrene 18 ug/m35.3 Total/NA4.166.8 J TO-15
Tetrachloroethene 28 ug/m34.1 Total/NA4.16250 TO-15
Tetrahydrofuran 61 ug/m311 Total/NA4.16390 TO-15
Toluene 78 ug/m34.5 Total/NA4.16720 TO-15
Trichloroethene 22 ug/m33.7 Total/NA4.163200 TO-15
Client Sample ID: 03072024-4 Lab Sample ID: 140-35862-4
1,1,1-Trichloroethane
RL
4.0 ppb v/v
MDL
1.4
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.01J2.2 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 4.0 ppb v/v0.48 Total/NA4.010.50 J TO-15
1,1-Dichloroethane 4.0 ppb v/v0.54 Total/NA4.0111 TO-15
1,2,3-Trimethylbenzene 4.0 ppb v/v1.8 Total/NA4.019.5 TO-15
1,2,4-Trimethylbenzene 4.0 ppb v/v1.0 Total/NA4.0134 TO-15
1,3,5-Trimethylbenzene 8.0 ppb v/v3.2 Total/NA4.0111 TO-15
2-Butanone (MEK)20 ppb v/v3.6 Total/NA4.01150 TO-15
4-Ethyltoluene 8.0 ppb v/v1.1 Total/NA4.019.9 TO-15
4-Methyl-2-pentanone (MIBK)20 ppb v/v2.8 Total/NA4.0130 TO-15
Acetone 150 ppb v/v28 Total/NA4.01230 TO-15
Benzene 4.0 ppb v/v0.66 Total/NA4.0181 TO-15
Eurofins Knoxville
This Detection Summary does not include radiochemical test results.
3/25/2024
9:50:51 AM
Page 10 of 864
Detection Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-4 (Continued)Lab Sample ID: 140-35862-4
Chloroform
RL
4.0 ppb v/v
MDL
0.72
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.01J0.79 TO-15
cis-1,2-Dichloroethene 4.0 ppb v/v0.50 Total/NA4.0127 TO-15
Cyclohexane 8.0 ppb v/v1.9 Total/NA4.0147 TO-15
Ethanol 100 ppb v/v44 Total/NA4.01130 TO-15
Ethyl acetate 40 ppb v/v3.0 Total/NA4.0110J TO-15
Ethylbenzene 4.0 ppb v/v0.66 Total/NA4.0119 TO-15
Isopropyl alcohol 40 ppb v/v4.8 Total/NA4.011700 TO-15
Methylcyclohexane 4.0 ppb v/v1.0 Total/NA4.0186CI TO-15
Methylene Chloride 20 ppb v/v6.8 Total/NA4.019.1 J TO-15
m-Xylene & p-Xylene 4.0 ppb v/v1.5 Total/NA4.0171 TO-15
n-Heptane 8.0 ppb v/v0.70 Total/NA4.0192 TO-15
n-Hexane 8.0 ppb v/v1.3 Total/NA4.01100 TO-15
Nonane 8.0 ppb v/v2.2 Total/NA4.0149 TO-15
o-Xylene 4.0 ppb v/v0.76 Total/NA4.0124 TO-15
Styrene 4.0 ppb v/v1.2 Total/NA4.011.3 J TO-15
Tetrachloroethene 4.0 ppb v/v0.58 Total/NA4.0125 TO-15
Tetrahydrofuran 20 ppb v/v3.6 Total/NA4.0172 TO-15
Toluene 20 ppb v/v1.1 Total/NA4.01140 TO-15
Trichloroethene 4.0 ppb v/v0.66 Total/NA4.01400 TO-15
1,1,1-Trichloroethane
RL
22 ug/m3
MDL
7.9
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.01J12 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 31 ug/m33.7 Total/NA4.013.8 J TO-15
1,1-Dichloroethane 16 ug/m32.2 Total/NA4.0145 TO-15
1,2,3-Trimethylbenzene 20 ug/m38.9 Total/NA4.0147 TO-15
1,2,4-Trimethylbenzene 20 ug/m34.9 Total/NA4.01170 TO-15
1,3,5-Trimethylbenzene 39 ug/m316 Total/NA4.0153 TO-15
2-Butanone (MEK)59 ug/m311 Total/NA4.01450 TO-15
4-Ethyltoluene 39 ug/m35.2 Total/NA4.0149 TO-15
4-Methyl-2-pentanone (MIBK)82 ug/m311 Total/NA4.01120 TO-15
Acetone 360 ug/m367 Total/NA4.01550 TO-15
Benzene 13 ug/m32.1 Total/NA4.01260 TO-15
Chloroform 20 ug/m33.5 Total/NA4.013.8 J TO-15
cis-1,2-Dichloroethene 16 ug/m32.0 Total/NA4.01110 TO-15
Cyclohexane 28 ug/m36.4 Total/NA4.01160 TO-15
Ethanol 190 ug/m383 Total/NA4.01240 TO-15
Ethyl acetate 140 ug/m311 Total/NA4.0138J TO-15
Ethylbenzene 17 ug/m32.9 Total/NA4.0183 TO-15
Isopropyl alcohol 99 ug/m312 Total/NA4.014200 TO-15
Methylcyclohexane 16 ug/m34.0 Total/NA4.01340CI TO-15
Methylene Chloride 70 ug/m324 Total/NA4.0132J TO-15
m-Xylene & p-Xylene 17 ug/m36.4 Total/NA4.01310 TO-15
n-Heptane 33 ug/m32.9 Total/NA4.01380 TO-15
n-Hexane 28 ug/m34.5 Total/NA4.01360 TO-15
Nonane 42 ug/m312 Total/NA4.01260 TO-15
o-Xylene 17 ug/m33.3 Total/NA4.01100 TO-15
Styrene 17 ug/m35.1 Total/NA4.015.4 J TO-15
Tetrachloroethene 27 ug/m33.9 Total/NA4.01170 TO-15
Tetrahydrofuran 59 ug/m311 Total/NA4.01210 TO-15
Toluene 76 ug/m34.3 Total/NA4.01540 TO-15
Trichloroethene 22 ug/m33.6 Total/NA4.012200 TO-15
Eurofins Knoxville
This Detection Summary does not include radiochemical test results.
3/25/2024
9:50:51 AM
Page 11 of 864
Detection Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-5 Lab Sample ID: 140-35862-5
1,1,1-Trichloroethane
RL
3.6 ppb v/v
MDL
1.3
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.45J2.0 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 3.6 ppb v/v0.43 Total/NA4.450.43 J TO-15
1,1-Dichloroethane 3.6 ppb v/v0.48 Total/NA4.459.7 TO-15
1,2,3-Trimethylbenzene 3.6 ppb v/v1.6 Total/NA4.457.9 TO-15
1,2,4-Trimethylbenzene 3.6 ppb v/v0.89 Total/NA4.4527 TO-15
1,3,5-Trimethylbenzene 7.1 ppb v/v2.8 Total/NA4.4510 TO-15
2-Butanone (MEK)18 ppb v/v3.2 Total/NA4.45150 TO-15
4-Ethyltoluene 7.1 ppb v/v0.94 Total/NA4.459.0 TO-15
4-Methyl-2-pentanone (MIBK)18 ppb v/v2.5 Total/NA4.4537 TO-15
Acetone 130 ppb v/v25 Total/NA4.45230 TO-15
Benzene 3.6 ppb v/v0.59 Total/NA4.4586 TO-15
Chlorobenzene 3.6 ppb v/v1.0 Total/NA4.451.1 J TO-15
Chloroform 3.6 ppb v/v0.64 Total/NA4.450.85 J TO-15
cis-1,2-Dichloroethene 3.6 ppb v/v0.45 Total/NA4.4524 TO-15
Cyclohexane 7.1 ppb v/v1.7 Total/NA4.4547 TO-15
Ethanol 89 ppb v/v39 Total/NA4.45150 TO-15
Ethyl acetate 36 ppb v/v2.7 Total/NA4.4511J TO-15
Ethylbenzene 3.6 ppb v/v0.59 Total/NA4.4518 TO-15
Isopropyl alcohol 36 ppb v/v4.3 Total/NA4.452000 TO-15
Methylcyclohexane 3.6 ppb v/v0.89 Total/NA4.4583CI TO-15
Methylene Chloride 18 ppb v/v6.1 Total/NA4.459.9 J TO-15
m-Xylene & p-Xylene 3.6 ppb v/v1.3 Total/NA4.4570 TO-15
n-Heptane 7.1 ppb v/v0.62 Total/NA4.4591 TO-15
n-Hexane 7.1 ppb v/v1.1 Total/NA4.45100 TO-15
Nonane 7.1 ppb v/v2.0 Total/NA4.4551 TO-15
o-Xylene 3.6 ppb v/v0.68 Total/NA4.4524 TO-15
Styrene 3.6 ppb v/v1.1 Total/NA4.451.3 J TO-15
Tetrachloroethene 3.6 ppb v/v0.52 Total/NA4.4525 TO-15
Tetrahydrofuran 18 ppb v/v3.2 Total/NA4.45100 TO-15
Toluene 18 ppb v/v1.0 Total/NA4.45140 TO-15
Trichloroethene 3.6 ppb v/v0.59 Total/NA4.45370 TO-15
1,1,1-Trichloroethane
RL
19 ug/m3
MDL
7.0
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.45J11 TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 27 ug/m33.3 Total/NA4.453.3 J TO-15
1,1-Dichloroethane 14 ug/m31.9 Total/NA4.4539 TO-15
1,2,3-Trimethylbenzene 18 ug/m37.9 Total/NA4.4539 TO-15
1,2,4-Trimethylbenzene 18 ug/m34.4 Total/NA4.45130 TO-15
1,3,5-Trimethylbenzene 35 ug/m314 Total/NA4.4549 TO-15
2-Butanone (MEK)52 ug/m39.4 Total/NA4.45450 TO-15
4-Ethyltoluene 35 ug/m34.6 Total/NA4.4544 TO-15
4-Methyl-2-pentanone (MIBK)73 ug/m310 Total/NA4.45150 TO-15
Acetone 320 ug/m359 Total/NA4.45540 TO-15
Benzene 11 ug/m31.9 Total/NA4.45270 TO-15
Chlorobenzene 16 ug/m34.6 Total/NA4.454.9 J TO-15
Chloroform 17 ug/m33.1 Total/NA4.454.2 J TO-15
cis-1,2-Dichloroethene 14 ug/m31.8 Total/NA4.4595 TO-15
Cyclohexane 25 ug/m35.7 Total/NA4.45160 TO-15
Ethanol 170 ug/m374 Total/NA4.45290 TO-15
Ethyl acetate 130 ug/m39.6 Total/NA4.4540J TO-15
Ethylbenzene 15 ug/m32.6 Total/NA4.4580 TO-15
Isopropyl alcohol 88 ug/m311 Total/NA4.454800 TO-15
Eurofins Knoxville
This Detection Summary does not include radiochemical test results.
3/25/2024
9:50:51 AM
Page 12 of 864
Detection Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-5 (Continued)Lab Sample ID: 140-35862-5
Methylcyclohexane
RL
14 ug/m3
MDL
3.6
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA4.45CI330 TO-15
Methylene Chloride 62 ug/m321 Total/NA4.4535J TO-15
m-Xylene & p-Xylene 15 ug/m35.6 Total/NA4.45300 TO-15
n-Heptane 29 ug/m32.6 Total/NA4.45370 TO-15
n-Hexane 25 ug/m34.0 Total/NA4.45360 TO-15
Nonane 37 ug/m310 Total/NA4.45270 TO-15
o-Xylene 15 ug/m32.9 Total/NA4.45100 TO-15
Styrene 15 ug/m34.5 Total/NA4.455.4 J TO-15
Tetrachloroethene 24 ug/m33.5 Total/NA4.45170 TO-15
Tetrahydrofuran 52 ug/m39.4 Total/NA4.45290 TO-15
Toluene 67 ug/m33.8 Total/NA4.45540 TO-15
Trichloroethene 19 ug/m33.2 Total/NA4.452000 TO-15
Eurofins Knoxville
This Detection Summary does not include radiochemical test results.
3/25/2024
9:50:51 AM
Page 13 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-1Client Sample ID: 03072024-1
Matrix: AirDate Collected: 03/07/24 11:20
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air
RL MDL
3.6 J 4.0 1.4 ppb v/v 03/19/24 20:19 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
4.0 0.70 ppb v/v 03/19/24 20:19 4.01ND1,1,2,2-Tetrachloroethane
4.0 0.48 ppb v/v 03/19/24 20:19 4.011.0 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
4.0 0.76 ppb v/v 03/19/24 20:19 4.01ND1,1,2-Trichloroethane
4.0 0.54 ppb v/v 03/19/24 20:19 4.01201,1-Dichloroethane
4.0 0.64 ppb v/v 03/19/24 20:19 4.01ND1,1-Dichloroethene
4.0 1.8 ppb v/v 03/19/24 20:19 4.014.61,2,3-Trimethylbenzene
20 1.8 ppb v/v 03/19/24 20:19 4.01ND1,2,4-Trichlorobenzene
4.0 1.0 ppb v/v 03/19/24 20:19 4.01181,2,4-Trimethylbenzene
4.0 0.62 ppb v/v 03/19/24 20:19 4.01ND1,2-Dibromoethane (EDB)
4.0 0.60 ppb v/v 03/19/24 20:19 4.01ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
8.0 1.6 ppb v/v 03/19/24 20:19 4.01ND1,2-Dichlorobenzene
4.0 0.50 ppb v/v 03/19/24 20:19 4.01ND1,2-Dichloroethane
4.0 0.50 ppb v/v 03/19/24 20:19 4.01ND1,2-Dichloropropane
8.0 3.2 ppb v/v 03/19/24 20:19 4.016.6 J1,3,5-Trimethylbenzene
8.0 0.96 ppb v/v 03/19/24 20:19 4.01ND1,3-Butadiene
4.0 0.80 ppb v/v 03/19/24 20:19 4.01ND1,3-Dichlorobenzene
4.0 0.80 ppb v/v 03/19/24 20:19 4.01ND1,4-Dichlorobenzene
20 3.6 ppb v/v 03/19/24 20:19 4.011602-Butanone (MEK)
10 2.8 ppb v/v 03/19/24 20:19 4.01ND2-Hexanone
8.0 1.1 ppb v/v 03/19/24 20:19 4.015.2 J4-Ethyltoluene
20 2.8 ppb v/v 03/19/24 20:19 4.01434-Methyl-2-pentanone (MIBK)
600 110 ppb v/v 03/20/24 16:56 4.01140JAcetone
4.0 0.66 ppb v/v 03/19/24 20:19 4.01150Benzene
8.0 1.9 ppb v/v 03/19/24 20:19 4.01NDBenzyl chloride
4.0 0.88 ppb v/v 03/19/24 20:19 4.01NDBromodichloromethane
4.0 1.3 ppb v/v 03/19/24 20:19 4.01NDBromoform
4.0 1.1 ppb v/v 03/19/24 20:19 4.01NDBromomethane
8.0 1.7 ppb v/v 03/19/24 20:19 4.01NDCarbon disulfide
4.0 0.64 ppb v/v 03/19/24 20:19 4.01NDCarbon tetrachloride
4.0 1.1 ppb v/v 03/19/24 20:19 4.01NDChlorobenzene
4.0 1.6 ppb v/v 03/19/24 20:19 4.01NDChloroethane
4.0 0.72 ppb v/v 03/19/24 20:19 4.011.4 JChloroform
20 3.2 ppb v/v 03/19/24 20:19 4.01NDChloromethane
4.0 0.50 ppb v/v 03/19/24 20:19 4.0149cis-1,2-Dichloroethene
8.0 0.96 ppb v/v 03/19/24 20:19 4.01NDcis-1,3-Dichloropropene
8.0 1.9 ppb v/v 03/19/24 20:19 4.0199Cyclohexane
4.0 0.68 ppb v/v 03/19/24 20:19 4.01NDDibromochloromethane
4.0 0.70 ppb v/v 03/19/24 20:19 4.01NDDichlorodifluoromethane
100 44 ppb v/v 03/19/24 20:19 4.01160Ethanol
40 3.0 ppb v/v 03/19/24 20:19 4.0142Ethyl acetate
4.0 0.66 ppb v/v 03/19/24 20:19 4.0127Ethylbenzene
20 1.6 ppb v/v 03/19/24 20:19 4.01NDHexachlorobutadiene
160 19 ppb v/v 03/20/24 16:56 4.013500Isopropyl alcohol
20 2.6 ppb v/v 03/19/24 20:19 4.01NDMethyl tert-butyl ether
4.0 1.0 ppb v/v 03/19/24 20:19 4.01150CIMethylcyclohexane
20 6.8 ppb v/v 03/19/24 20:19 4.0119JMethylene Chloride
4.0 1.5 ppb v/v 03/19/24 20:19 4.01100m-Xylene & p-Xylene
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 14 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-1Client Sample ID: 03072024-1
Matrix: AirDate Collected: 03/07/24 11:20
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
190 8.0 0.70 ppb v/v 03/19/24 20:19 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Heptane
8.0 1.3 ppb v/v 03/19/24 20:19 4.01240n-Hexane
8.0 2.2 ppb v/v 03/19/24 20:19 4.0144Nonane
4.0 0.76 ppb v/v 03/19/24 20:19 4.0131o-Xylene
4.0 1.2 ppb v/v 03/19/24 20:19 4.014.1Styrene
4.0 0.58 ppb v/v 03/19/24 20:19 4.0129Tetrachloroethene
20 3.6 ppb v/v 03/19/24 20:19 4.01NDTetrahydrofuran
20 1.1 ppb v/v 03/19/24 20:19 4.01200Toluene
4.0 0.66 ppb v/v 03/19/24 20:19 4.01NDtrans-1,2-Dichloroethene
4.0 0.98 ppb v/v 03/19/24 20:19 4.01NDtrans-1,3-Dichloropropene
4.0 0.66 ppb v/v 03/19/24 20:19 4.01560Trichloroethene
4.0 0.56 ppb v/v 03/19/24 20:19 4.01NDTrichlorofluoromethane
20 1.4 ppb v/v 03/19/24 20:19 4.01NDVinyl acetate
8.0 1.3 ppb v/v 03/19/24 20:19 4.01NDVinyl chloride
RL MDL
20 J 22 7.9 ug/m3 03/19/24 20:19 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
28 4.8 ug/m3 03/19/24 20:19 4.01ND1,1,2,2-Tetrachloroethane
31 3.7 ug/m3 03/19/24 20:19 4.018.0 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
22 4.2 ug/m3 03/19/24 20:19 4.01ND1,1,2-Trichloroethane
16 2.2 ug/m3 03/19/24 20:19 4.01801,1-Dichloroethane
16 2.5 ug/m3 03/19/24 20:19 4.01ND1,1-Dichloroethene
20 8.9 ug/m3 03/19/24 20:19 4.01231,2,3-Trimethylbenzene
150 13 ug/m3 03/19/24 20:19 4.01ND1,2,4-Trichlorobenzene
20 4.9 ug/m3 03/19/24 20:19 4.01891,2,4-Trimethylbenzene
31 4.8 ug/m3 03/19/24 20:19 4.01ND1,2-Dibromoethane (EDB)
28 4.2 ug/m3 03/19/24 20:19 4.01ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
48 9.4 ug/m3 03/19/24 20:19 4.01ND1,2-Dichlorobenzene
16 2.0 ug/m3 03/19/24 20:19 4.01ND1,2-Dichloroethane
19 2.3 ug/m3 03/19/24 20:19 4.01ND1,2-Dichloropropane
39 16 ug/m3 03/19/24 20:19 4.0132J1,3,5-Trimethylbenzene
18 2.1 ug/m3 03/19/24 20:19 4.01ND1,3-Butadiene
24 4.8 ug/m3 03/19/24 20:19 4.01ND1,3-Dichlorobenzene
24 4.8 ug/m3 03/19/24 20:19 4.01ND1,4-Dichlorobenzene
59 11 ug/m3 03/19/24 20:19 4.014702-Butanone (MEK)
41 12 ug/m3 03/19/24 20:19 4.01ND2-Hexanone
39 5.2 ug/m3 03/19/24 20:19 4.0125J4-Ethyltoluene
82 11 ug/m3 03/19/24 20:19 4.011804-Methyl-2-pentanone (MIBK)
1400 270 ug/m3 03/20/24 16:56 4.01340JAcetone
13 2.1 ug/m3 03/19/24 20:19 4.01480Benzene
42 9.9 ug/m3 03/19/24 20:19 4.01NDBenzyl chloride
27 5.9 ug/m3 03/19/24 20:19 4.01NDBromodichloromethane
41 14 ug/m3 03/19/24 20:19 4.01NDBromoform
16 4.3 ug/m3 03/19/24 20:19 4.01NDBromomethane
25 5.4 ug/m3 03/19/24 20:19 4.01NDCarbon disulfide
25 4.0 ug/m3 03/19/24 20:19 4.01NDCarbon tetrachloride
18 5.2 ug/m3 03/19/24 20:19 4.01NDChlorobenzene
11 4.2 ug/m3 03/19/24 20:19 4.01NDChloroethane
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 15 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-1Client Sample ID: 03072024-1
Matrix: AirDate Collected: 03/07/24 11:20
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
6.8 J 20 3.5 ug/m3 03/19/24 20:19 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Chloroform
41 6.6 ug/m3 03/19/24 20:19 4.01NDChloromethane
16 2.0 ug/m3 03/19/24 20:19 4.01190cis-1,2-Dichloroethene
36 4.4 ug/m3 03/19/24 20:19 4.01NDcis-1,3-Dichloropropene
28 6.4 ug/m3 03/19/24 20:19 4.01340Cyclohexane
34 5.8 ug/m3 03/19/24 20:19 4.01NDDibromochloromethane
20 3.5 ug/m3 03/19/24 20:19 4.01NDDichlorodifluoromethane
190 83 ug/m3 03/19/24 20:19 4.01300Ethanol
140 11 ug/m3 03/19/24 20:19 4.01150Ethyl acetate
17 2.9 ug/m3 03/19/24 20:19 4.01120Ethylbenzene
210 17 ug/m3 03/19/24 20:19 4.01NDHexachlorobutadiene
390 47 ug/m3 03/20/24 16:56 4.018500Isopropyl alcohol
72 9.4 ug/m3 03/19/24 20:19 4.01NDMethyl tert-butyl ether
16 4.0 ug/m3 03/19/24 20:19 4.01590CIMethylcyclohexane
70 24 ug/m3 03/19/24 20:19 4.0168JMethylene Chloride
17 6.4 ug/m3 03/19/24 20:19 4.01440m-Xylene & p-Xylene
33 2.9 ug/m3 03/19/24 20:19 4.01760n-Heptane
28 4.5 ug/m3 03/19/24 20:19 4.01830n-Hexane
42 12 ug/m3 03/19/24 20:19 4.01230Nonane
17 3.3 ug/m3 03/19/24 20:19 4.01140o-Xylene
17 5.1 ug/m3 03/19/24 20:19 4.0117Styrene
27 3.9 ug/m3 03/19/24 20:19 4.01190Tetrachloroethene
59 11 ug/m3 03/19/24 20:19 4.01NDTetrahydrofuran
76 4.3 ug/m3 03/19/24 20:19 4.01750Toluene
16 2.6 ug/m3 03/19/24 20:19 4.01NDtrans-1,2-Dichloroethene
18 4.5 ug/m3 03/19/24 20:19 4.01NDtrans-1,3-Dichloropropene
22 3.6 ug/m3 03/19/24 20:19 4.013000Trichloroethene
23 3.2 ug/m3 03/19/24 20:19 4.01NDTrichlorofluoromethane
71 4.9 ug/m3 03/19/24 20:19 4.01NDVinyl acetate
21 3.3 ug/m3 03/19/24 20:19 4.01NDVinyl chloride
Butane, 2-methyl-100 T J N ppb v/v 5.28 78-78-4 03/19/24 20:19 4.01
Tentatively Identified Compound Dil FacAnalyzedPreparedUnitDQualifierEst. Result CAS No.RT
4.0103/19/24 20:19T JUnknown N/A50ppb v/v 6.58
4.0103/19/24 20:19T J NPentane, 2-methyl-107-83-5140ppb v/v 7.55
4.0103/19/24 20:19T J NPentane, 3-methyl-96-14-0100ppb v/v 8.03
4.0103/19/24 20:19T JUnknown N/A57ppb v/v 8.84
4.0103/19/24 20:19T J NCyclopentane, methyl-96-37-7180ppb v/v 9.74
4.0103/19/24 20:19T J NHexane, 3-methyl-589-34-472ppb v/v 11.33
4.0103/19/24 20:19T J NCyclopentane, 1,3-dimethyl-, cis-2532-58-349ppb v/v 11.70
4.0103/19/24 20:19T JUnknown N/A100ppb v/v 11.80
4.0103/19/24 20:19T J NIsopropylcyclobutane 872-56-077ppb v/v 11.89
4.0103/19/24 20:19T J NOctane 111-65-975ppb v/v 15.07
4.0103/19/24 20:19T J NDecane 124-18-569ppb v/v 19.01
4-Bromofluorobenzene (Surr)94 60 -140 03/19/24 20:19 4.01
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)102 03/20/24 16:56 4.0160-140
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 16 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-2Client Sample ID: 03072024-2
Matrix: AirDate Collected: 03/07/24 12:40
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air
RL MDL
4.1 4.0 1.4 ppb v/v 03/19/24 21:05 3.95
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
4.0 0.69 ppb v/v 03/19/24 21:05 3.95ND1,1,2,2-Tetrachloroethane
4.0 0.47 ppb v/v 03/19/24 21:05 3.950.95 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
4.0 0.75 ppb v/v 03/19/24 21:05 3.95ND1,1,2-Trichloroethane
4.0 0.53 ppb v/v 03/19/24 21:05 3.95231,1-Dichloroethane
4.0 0.63 ppb v/v 03/19/24 21:05 3.95ND1,1-Dichloroethene
4.0 1.8 ppb v/v 03/19/24 21:05 3.958.31,2,3-Trimethylbenzene
20 1.8 ppb v/v 03/19/24 21:05 3.95ND1,2,4-Trichlorobenzene
4.0 0.99 ppb v/v 03/19/24 21:05 3.95301,2,4-Trimethylbenzene
4.0 0.61 ppb v/v 03/19/24 21:05 3.95ND1,2-Dibromoethane (EDB)
4.0 0.59 ppb v/v 03/19/24 21:05 3.95ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
7.9 1.5 ppb v/v 03/19/24 21:05 3.95ND1,2-Dichlorobenzene
4.0 0.49 ppb v/v 03/19/24 21:05 3.95ND1,2-Dichloroethane
4.0 0.49 ppb v/v 03/19/24 21:05 3.95ND1,2-Dichloropropane
7.9 3.2 ppb v/v 03/19/24 21:05 3.95111,3,5-Trimethylbenzene
7.9 0.95 ppb v/v 03/19/24 21:05 3.95ND1,3-Butadiene
4.0 0.79 ppb v/v 03/19/24 21:05 3.95ND1,3-Dichlorobenzene
4.0 0.79 ppb v/v 03/19/24 21:05 3.95ND1,4-Dichlorobenzene
20 3.6 ppb v/v 03/19/24 21:05 3.952102-Butanone (MEK)
9.9 2.8 ppb v/v 03/19/24 21:05 3.95ND2-Hexanone
7.9 1.0 ppb v/v 03/19/24 21:05 3.958.54-Ethyltoluene
20 2.8 ppb v/v 03/19/24 21:05 3.95554-Methyl-2-pentanone (MIBK)
590 110 ppb v/v 03/20/24 17:43 3.95180JAcetone
4.0 0.65 ppb v/v 03/19/24 21:05 3.95110Benzene
7.9 1.9 ppb v/v 03/19/24 21:05 3.95NDBenzyl chloride
4.0 0.87 ppb v/v 03/19/24 21:05 3.95NDBromodichloromethane
4.0 1.3 ppb v/v 03/19/24 21:05 3.95NDBromoform
4.0 1.1 ppb v/v 03/19/24 21:05 3.95NDBromomethane
7.9 1.7 ppb v/v 03/19/24 21:05 3.95NDCarbon disulfide
4.0 0.63 ppb v/v 03/19/24 21:05 3.95NDCarbon tetrachloride
4.0 1.1 ppb v/v 03/19/24 21:05 3.95NDChlorobenzene
4.0 1.6 ppb v/v 03/19/24 21:05 3.95NDChloroethane
4.0 0.71 ppb v/v 03/19/24 21:05 3.950.84 JChloroform
20 3.2 ppb v/v 03/19/24 21:05 3.95NDChloromethane
4.0 0.49 ppb v/v 03/19/24 21:05 3.9557cis-1,2-Dichloroethene
7.9 0.95 ppb v/v 03/19/24 21:05 3.95NDcis-1,3-Dichloropropene
7.9 1.8 ppb v/v 03/19/24 21:05 3.9576Cyclohexane
4.0 0.67 ppb v/v 03/19/24 21:05 3.95NDDibromochloromethane
4.0 0.69 ppb v/v 03/19/24 21:05 3.95NDDichlorodifluoromethane
99 43 ppb v/v 03/19/24 21:05 3.95160Ethanol
40 3.0 ppb v/v 03/19/24 21:05 3.9518JEthyl acetate
4.0 0.65 ppb v/v 03/19/24 21:05 3.9526Ethylbenzene
20 1.6 ppb v/v 03/19/24 21:05 3.95NDHexachlorobutadiene
160 19 ppb v/v 03/20/24 17:43 3.953300Isopropyl alcohol
20 2.6 ppb v/v 03/19/24 21:05 3.95NDMethyl tert-butyl ether
4.0 0.99 ppb v/v 03/19/24 21:05 3.95140CIMethylcyclohexane
20 6.7 ppb v/v 03/19/24 21:05 3.959.3 JMethylene Chloride
4.0 1.4 ppb v/v 03/19/24 21:05 3.9592m-Xylene & p-Xylene
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 17 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-2Client Sample ID: 03072024-2
Matrix: AirDate Collected: 03/07/24 12:40
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
150 7.9 0.69 ppb v/v 03/19/24 21:05 3.95
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Heptane
7.9 1.2 ppb v/v 03/19/24 21:05 3.95170n-Hexane
7.9 2.2 ppb v/v 03/19/24 21:05 3.9565Nonane
4.0 0.75 ppb v/v 03/19/24 21:05 3.9530o-Xylene
4.0 1.2 ppb v/v 03/19/24 21:05 3.951.8 JStyrene
4.0 0.57 ppb v/v 03/19/24 21:05 3.9539Tetrachloroethene
20 3.6 ppb v/v 03/19/24 21:05 3.9589Tetrahydrofuran
20 1.1 ppb v/v 03/19/24 21:05 3.95220Toluene
4.0 0.65 ppb v/v 03/19/24 21:05 3.95NDtrans-1,2-Dichloroethene
4.0 0.97 ppb v/v 03/19/24 21:05 3.95NDtrans-1,3-Dichloropropene
4.0 0.65 ppb v/v 03/19/24 21:05 3.95690Trichloroethene
4.0 0.55 ppb v/v 03/19/24 21:05 3.95NDTrichlorofluoromethane
20 1.4 ppb v/v 03/19/24 21:05 3.95NDVinyl acetate
7.9 1.3 ppb v/v 03/19/24 21:05 3.95NDVinyl chloride
RL MDL
22 22 7.8 ug/m3 03/19/24 21:05 3.95
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
27 4.7 ug/m3 03/19/24 21:05 3.95ND1,1,2,2-Tetrachloroethane
30 3.6 ug/m3 03/19/24 21:05 3.957.3 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
22 4.1 ug/m3 03/19/24 21:05 3.95ND1,1,2-Trichloroethane
16 2.2 ug/m3 03/19/24 21:05 3.95911,1-Dichloroethane
16 2.5 ug/m3 03/19/24 21:05 3.95ND1,1-Dichloroethene
19 8.7 ug/m3 03/19/24 21:05 3.95411,2,3-Trimethylbenzene
150 13 ug/m3 03/19/24 21:05 3.95ND1,2,4-Trichlorobenzene
19 4.9 ug/m3 03/19/24 21:05 3.951501,2,4-Trimethylbenzene
30 4.7 ug/m3 03/19/24 21:05 3.95ND1,2-Dibromoethane (EDB)
28 4.1 ug/m3 03/19/24 21:05 3.95ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
47 9.3 ug/m3 03/19/24 21:05 3.95ND1,2-Dichlorobenzene
16 2.0 ug/m3 03/19/24 21:05 3.95ND1,2-Dichloroethane
18 2.3 ug/m3 03/19/24 21:05 3.95ND1,2-Dichloropropane
39 16 ug/m3 03/19/24 21:05 3.95531,3,5-Trimethylbenzene
17 2.1 ug/m3 03/19/24 21:05 3.95ND1,3-Butadiene
24 4.7 ug/m3 03/19/24 21:05 3.95ND1,3-Dichlorobenzene
24 4.7 ug/m3 03/19/24 21:05 3.95ND1,4-Dichlorobenzene
58 10 ug/m3 03/19/24 21:05 3.956302-Butanone (MEK)
40 11 ug/m3 03/19/24 21:05 3.95ND2-Hexanone
39 5.1 ug/m3 03/19/24 21:05 3.95424-Ethyltoluene
81 11 ug/m3 03/19/24 21:05 3.952204-Methyl-2-pentanone (MIBK)
1400 260 ug/m3 03/20/24 17:43 3.95420JAcetone
13 2.1 ug/m3 03/19/24 21:05 3.95350Benzene
41 9.7 ug/m3 03/19/24 21:05 3.95NDBenzyl chloride
26 5.8 ug/m3 03/19/24 21:05 3.95NDBromodichloromethane
41 13 ug/m3 03/19/24 21:05 3.95NDBromoform
15 4.2 ug/m3 03/19/24 21:05 3.95NDBromomethane
25 5.4 ug/m3 03/19/24 21:05 3.95NDCarbon disulfide
25 4.0 ug/m3 03/19/24 21:05 3.95NDCarbon tetrachloride
18 5.1 ug/m3 03/19/24 21:05 3.95NDChlorobenzene
10 4.1 ug/m3 03/19/24 21:05 3.95NDChloroethane
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 18 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-2Client Sample ID: 03072024-2
Matrix: AirDate Collected: 03/07/24 12:40
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
4.1 J 19 3.5 ug/m3 03/19/24 21:05 3.95
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Chloroform
41 6.5 ug/m3 03/19/24 21:05 3.95NDChloromethane
16 2.0 ug/m3 03/19/24 21:05 3.95220cis-1,2-Dichloroethene
36 4.3 ug/m3 03/19/24 21:05 3.95NDcis-1,3-Dichloropropene
27 6.3 ug/m3 03/19/24 21:05 3.95260Cyclohexane
34 5.7 ug/m3 03/19/24 21:05 3.95NDDibromochloromethane
20 3.4 ug/m3 03/19/24 21:05 3.95NDDichlorodifluoromethane
190 82 ug/m3 03/19/24 21:05 3.95310Ethanol
140 11 ug/m3 03/19/24 21:05 3.9563JEthyl acetate
17 2.8 ug/m3 03/19/24 21:05 3.95110Ethylbenzene
210 17 ug/m3 03/19/24 21:05 3.95NDHexachlorobutadiene
390 47 ug/m3 03/20/24 17:43 3.958000Isopropyl alcohol
71 9.3 ug/m3 03/19/24 21:05 3.95NDMethyl tert-butyl ether
16 4.0 ug/m3 03/19/24 21:05 3.95570CIMethylcyclohexane
69 23 ug/m3 03/19/24 21:05 3.9532JMethylene Chloride
17 6.3 ug/m3 03/19/24 21:05 3.95400m-Xylene & p-Xylene
32 2.8 ug/m3 03/19/24 21:05 3.95620n-Heptane
28 4.4 ug/m3 03/19/24 21:05 3.95600n-Hexane
41 11 ug/m3 03/19/24 21:05 3.95340Nonane
17 3.3 ug/m3 03/19/24 21:05 3.95130o-Xylene
17 5.0 ug/m3 03/19/24 21:05 3.957.7 JStyrene
27 3.9 ug/m3 03/19/24 21:05 3.95260Tetrachloroethene
58 10 ug/m3 03/19/24 21:05 3.95260Tetrahydrofuran
74 4.2 ug/m3 03/19/24 21:05 3.95830Toluene
16 2.6 ug/m3 03/19/24 21:05 3.95NDtrans-1,2-Dichloroethene
18 4.4 ug/m3 03/19/24 21:05 3.95NDtrans-1,3-Dichloropropene
21 3.5 ug/m3 03/19/24 21:05 3.953700Trichloroethene
22 3.1 ug/m3 03/19/24 21:05 3.95NDTrichlorofluoromethane
70 4.9 ug/m3 03/19/24 21:05 3.95NDVinyl acetate
20 3.3 ug/m3 03/19/24 21:05 3.95NDVinyl chloride
Butane, 2-methyl-72 T J N ppb v/v 5.27 78-78-4 03/19/24 21:05 3.95
Tentatively Identified Compound Dil FacAnalyzedPreparedUnitDQualifierEst. Result CAS No.RT
3.9503/19/24 21:05T J NPentane, 2-methyl-107-83-5110ppb v/v 7.55
3.9503/19/24 21:05T J NPentane, 3-methyl-96-14-077ppb v/v 8.02
3.9503/19/24 21:05T JUnknown N/A85ppb v/v 8.81
3.9503/19/24 21:05T J NCyclopentane, methyl-96-37-7130ppb v/v 9.74
3.9503/19/24 21:05T J NHexane, 3-methyl-589-34-459ppb v/v 11.33
3.9503/19/24 21:05T JUnknown N/A120ppb v/v 11.79
3.9503/19/24 21:05T J NIsopropylcyclobutane 872-56-055ppb v/v 11.89
3.9503/19/24 21:05T J NHeptane, 2-methyl-592-27-852ppb v/v 14.15
3.9503/19/24 21:05T J NOctane 111-65-985ppb v/v 15.07
3.9503/19/24 21:05T J NDecane 124-18-5110ppb v/v 19.01
3.9503/19/24 21:05T J NUndecane 1120-21-469ppb v/v 20.28
4-Bromofluorobenzene (Surr)91 60 -140 03/19/24 21:05 3.95
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)103 03/20/24 17:43 3.9560-140
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 19 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-3Client Sample ID: 03072024-3
Matrix: AirDate Collected: 03/07/24 13:55
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air
RL MDL
3.3 J 4.2 1.5 ppb v/v 03/19/24 21:50 4.16
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
4.2 0.73 ppb v/v 03/19/24 21:50 4.16ND1,1,2,2-Tetrachloroethane
4.2 0.50 ppb v/v 03/19/24 21:50 4.160.70 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
4.2 0.79 ppb v/v 03/19/24 21:50 4.16ND1,1,2-Trichloroethane
4.2 0.56 ppb v/v 03/19/24 21:50 4.16181,1-Dichloroethane
4.2 0.67 ppb v/v 03/19/24 21:50 4.16ND1,1-Dichloroethene
4.2 1.9 ppb v/v 03/19/24 21:50 4.169.81,2,3-Trimethylbenzene
21 1.9 ppb v/v 03/19/24 21:50 4.16ND1,2,4-Trichlorobenzene
4.2 1.0 ppb v/v 03/19/24 21:50 4.16351,2,4-Trimethylbenzene
4.2 0.64 ppb v/v 03/19/24 21:50 4.16ND1,2-Dibromoethane (EDB)
4.2 0.62 ppb v/v 03/19/24 21:50 4.16ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
8.3 1.6 ppb v/v 03/19/24 21:50 4.16ND1,2-Dichlorobenzene
4.2 0.52 ppb v/v 03/19/24 21:50 4.16ND1,2-Dichloroethane
4.2 0.52 ppb v/v 03/19/24 21:50 4.16ND1,2-Dichloropropane
8.3 3.3 ppb v/v 03/19/24 21:50 4.16131,3,5-Trimethylbenzene
8.3 1.0 ppb v/v 03/19/24 21:50 4.16ND1,3-Butadiene
4.2 0.83 ppb v/v 03/19/24 21:50 4.16ND1,3-Dichlorobenzene
4.2 0.83 ppb v/v 03/19/24 21:50 4.16ND1,4-Dichlorobenzene
21 3.7 ppb v/v 03/19/24 21:50 4.162002-Butanone (MEK)
10 2.9 ppb v/v 03/19/24 21:50 4.16ND2-Hexanone
8.3 1.1 ppb v/v 03/19/24 21:50 4.169.84-Ethyltoluene
21 2.9 ppb v/v 03/19/24 21:50 4.16424-Methyl-2-pentanone (MIBK)
310 58 ppb v/v 03/20/24 18:30 4.16260JAcetone
4.2 0.69 ppb v/v 03/19/24 21:50 4.1699Benzene
8.3 2.0 ppb v/v 03/19/24 21:50 4.16NDBenzyl chloride
4.2 0.92 ppb v/v 03/19/24 21:50 4.16NDBromodichloromethane
4.2 1.4 ppb v/v 03/19/24 21:50 4.16NDBromoform
4.2 1.1 ppb v/v 03/19/24 21:50 4.16NDBromomethane
8.3 1.8 ppb v/v 03/19/24 21:50 4.16NDCarbon disulfide
4.2 0.67 ppb v/v 03/19/24 21:50 4.16NDCarbon tetrachloride
4.2 1.2 ppb v/v 03/19/24 21:50 4.16NDChlorobenzene
4.2 1.6 ppb v/v 03/19/24 21:50 4.16NDChloroethane
4.2 0.75 ppb v/v 03/19/24 21:50 4.160.80 JChloroform
21 3.3 ppb v/v 03/19/24 21:50 4.16NDChloromethane
4.2 0.52 ppb v/v 03/19/24 21:50 4.1644cis-1,2-Dichloroethene
8.3 1.0 ppb v/v 03/19/24 21:50 4.16NDcis-1,3-Dichloropropene
8.3 1.9 ppb v/v 03/19/24 21:50 4.1662Cyclohexane
4.2 0.71 ppb v/v 03/19/24 21:50 4.16NDDibromochloromethane
4.2 0.73 ppb v/v 03/19/24 21:50 4.16NDDichlorodifluoromethane
100 46 ppb v/v 03/19/24 21:50 4.16170Ethanol
42 3.1 ppb v/v 03/19/24 21:50 4.1613JEthyl acetate
4.2 0.69 ppb v/v 03/19/24 21:50 4.1625Ethylbenzene
21 1.7 ppb v/v 03/19/24 21:50 4.16NDHexachlorobutadiene
83 10 ppb v/v 03/20/24 18:30 4.162300Isopropyl alcohol
21 2.7 ppb v/v 03/19/24 21:50 4.16NDMethyl tert-butyl ether
4.2 1.0 ppb v/v 03/19/24 21:50 4.16110CIMethylcyclohexane
21 7.1 ppb v/v 03/19/24 21:50 4.169.0 JMethylene Chloride
4.2 1.5 ppb v/v 03/19/24 21:50 4.1691m-Xylene & p-Xylene
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 20 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-3Client Sample ID: 03072024-3
Matrix: AirDate Collected: 03/07/24 13:55
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
130 8.3 0.73 ppb v/v 03/19/24 21:50 4.16
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Heptane
8.3 1.3 ppb v/v 03/19/24 21:50 4.16140n-Hexane
8.3 2.3 ppb v/v 03/19/24 21:50 4.1663Nonane
4.2 0.79 ppb v/v 03/19/24 21:50 4.1631o-Xylene
4.2 1.2 ppb v/v 03/19/24 21:50 4.161.6 JStyrene
4.2 0.60 ppb v/v 03/19/24 21:50 4.1637Tetrachloroethene
21 3.7 ppb v/v 03/19/24 21:50 4.16130Tetrahydrofuran
21 1.2 ppb v/v 03/19/24 21:50 4.16190Toluene
4.2 0.69 ppb v/v 03/19/24 21:50 4.16NDtrans-1,2-Dichloroethene
4.2 1.0 ppb v/v 03/19/24 21:50 4.16NDtrans-1,3-Dichloropropene
4.2 0.69 ppb v/v 03/19/24 21:50 4.16600Trichloroethene
4.2 0.58 ppb v/v 03/19/24 21:50 4.16NDTrichlorofluoromethane
21 1.5 ppb v/v 03/19/24 21:50 4.16NDVinyl acetate
8.3 1.4 ppb v/v 03/19/24 21:50 4.16NDVinyl chloride
RL MDL
18 J 23 8.2 ug/m3 03/19/24 21:50 4.16
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
29 5.0 ug/m3 03/19/24 21:50 4.16ND1,1,2,2-Tetrachloroethane
32 3.8 ug/m3 03/19/24 21:50 4.165.3 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
23 4.3 ug/m3 03/19/24 21:50 4.16ND1,1,2-Trichloroethane
17 2.3 ug/m3 03/19/24 21:50 4.16721,1-Dichloroethane
16 2.6 ug/m3 03/19/24 21:50 4.16ND1,1-Dichloroethene
20 9.2 ug/m3 03/19/24 21:50 4.16481,2,3-Trimethylbenzene
150 14 ug/m3 03/19/24 21:50 4.16ND1,2,4-Trichlorobenzene
20 5.1 ug/m3 03/19/24 21:50 4.161701,2,4-Trimethylbenzene
32 5.0 ug/m3 03/19/24 21:50 4.16ND1,2-Dibromoethane (EDB)
29 4.4 ug/m3 03/19/24 21:50 4.16ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
50 9.8 ug/m3 03/19/24 21:50 4.16ND1,2-Dichlorobenzene
17 2.1 ug/m3 03/19/24 21:50 4.16ND1,2-Dichloroethane
19 2.4 ug/m3 03/19/24 21:50 4.16ND1,2-Dichloropropane
41 16 ug/m3 03/19/24 21:50 4.16631,3,5-Trimethylbenzene
18 2.2 ug/m3 03/19/24 21:50 4.16ND1,3-Butadiene
25 5.0 ug/m3 03/19/24 21:50 4.16ND1,3-Dichlorobenzene
25 5.0 ug/m3 03/19/24 21:50 4.16ND1,4-Dichlorobenzene
61 11 ug/m3 03/19/24 21:50 4.165902-Butanone (MEK)
43 12 ug/m3 03/19/24 21:50 4.16ND2-Hexanone
41 5.4 ug/m3 03/19/24 21:50 4.16484-Ethyltoluene
85 12 ug/m3 03/19/24 21:50 4.161704-Methyl-2-pentanone (MIBK)
740 140 ug/m3 03/20/24 18:30 4.16610JAcetone
13 2.2 ug/m3 03/19/24 21:50 4.16320Benzene
43 10 ug/m3 03/19/24 21:50 4.16NDBenzyl chloride
28 6.1 ug/m3 03/19/24 21:50 4.16NDBromodichloromethane
43 14 ug/m3 03/19/24 21:50 4.16NDBromoform
16 4.4 ug/m3 03/19/24 21:50 4.16NDBromomethane
26 5.6 ug/m3 03/19/24 21:50 4.16NDCarbon disulfide
26 4.2 ug/m3 03/19/24 21:50 4.16NDCarbon tetrachloride
19 5.4 ug/m3 03/19/24 21:50 4.16NDChlorobenzene
11 4.3 ug/m3 03/19/24 21:50 4.16NDChloroethane
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 21 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-3Client Sample ID: 03072024-3
Matrix: AirDate Collected: 03/07/24 13:55
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
3.9 J 20 3.7 ug/m3 03/19/24 21:50 4.16
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Chloroform
43 6.9 ug/m3 03/19/24 21:50 4.16NDChloromethane
16 2.1 ug/m3 03/19/24 21:50 4.16170cis-1,2-Dichloroethene
38 4.5 ug/m3 03/19/24 21:50 4.16NDcis-1,3-Dichloropropene
29 6.7 ug/m3 03/19/24 21:50 4.16210Cyclohexane
35 6.0 ug/m3 03/19/24 21:50 4.16NDDibromochloromethane
21 3.6 ug/m3 03/19/24 21:50 4.16NDDichlorodifluoromethane
200 86 ug/m3 03/19/24 21:50 4.16320Ethanol
150 11 ug/m3 03/19/24 21:50 4.1647JEthyl acetate
18 3.0 ug/m3 03/19/24 21:50 4.16110Ethylbenzene
220 18 ug/m3 03/19/24 21:50 4.16NDHexachlorobutadiene
200 25 ug/m3 03/20/24 18:30 4.165700Isopropyl alcohol
75 9.7 ug/m3 03/19/24 21:50 4.16NDMethyl tert-butyl ether
17 4.2 ug/m3 03/19/24 21:50 4.16460CIMethylcyclohexane
72 25 ug/m3 03/19/24 21:50 4.1631JMethylene Chloride
18 6.6 ug/m3 03/19/24 21:50 4.16390m-Xylene & p-Xylene
34 3.0 ug/m3 03/19/24 21:50 4.16520n-Heptane
29 4.6 ug/m3 03/19/24 21:50 4.16480n-Hexane
44 12 ug/m3 03/19/24 21:50 4.16330Nonane
18 3.4 ug/m3 03/19/24 21:50 4.16130o-Xylene
18 5.3 ug/m3 03/19/24 21:50 4.166.8 JStyrene
28 4.1 ug/m3 03/19/24 21:50 4.16250Tetrachloroethene
61 11 ug/m3 03/19/24 21:50 4.16390Tetrahydrofuran
78 4.5 ug/m3 03/19/24 21:50 4.16720Toluene
16 2.7 ug/m3 03/19/24 21:50 4.16NDtrans-1,2-Dichloroethene
19 4.6 ug/m3 03/19/24 21:50 4.16NDtrans-1,3-Dichloropropene
22 3.7 ug/m3 03/19/24 21:50 4.163200Trichloroethene
23 3.3 ug/m3 03/19/24 21:50 4.16NDTrichlorofluoromethane
73 5.1 ug/m3 03/19/24 21:50 4.16NDVinyl acetate
21 3.5 ug/m3 03/19/24 21:50 4.16NDVinyl chloride
Butane, 2-methyl-61 T J N ppb v/v 5.27 78-78-4 03/19/24 21:50 4.16
Tentatively Identified Compound Dil FacAnalyzedPreparedUnitDQualifierEst. Result CAS No.RT
4.1603/19/24 21:50T J NPentane, 2-methyl-107-83-593ppb v/v 7.55
4.1603/19/24 21:50T J NPentane, 3-methyl-96-14-069ppb v/v 8.02
4.1603/19/24 21:50T JUnknown N/A200ppb v/v 8.59
4.1603/19/24 21:50T JUnknown N/A84ppb v/v 8.81
4.1603/19/24 21:50T J NCyclopentane, methyl-96-37-7120ppb v/v 9.74
4.1603/19/24 21:50T JUnknown N/A80ppb v/v 11.79
4.1603/19/24 21:50T J NOctane 111-65-977ppb v/v 15.07
4.1603/19/24 21:50T J NDecane 124-18-5120ppb v/v 19.01
4.1603/19/24 21:50T J NUndecane 1120-21-483ppb v/v 20.28
4-Bromofluorobenzene (Surr)99 60 -140 03/19/24 21:50 4.16
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)103 03/20/24 18:30 4.1660-140
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 22 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-4Client Sample ID: 03072024-4
Matrix: AirDate Collected: 03/07/24 15:25
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air
RL MDL
2.2 J 4.0 1.4 ppb v/v 03/19/24 22:36 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
4.0 0.70 ppb v/v 03/19/24 22:36 4.01ND1,1,2,2-Tetrachloroethane
4.0 0.48 ppb v/v 03/19/24 22:36 4.010.50 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
4.0 0.76 ppb v/v 03/19/24 22:36 4.01ND1,1,2-Trichloroethane
4.0 0.54 ppb v/v 03/19/24 22:36 4.01111,1-Dichloroethane
4.0 0.64 ppb v/v 03/19/24 22:36 4.01ND1,1-Dichloroethene
4.0 1.8 ppb v/v 03/19/24 22:36 4.019.51,2,3-Trimethylbenzene
20 1.8 ppb v/v 03/19/24 22:36 4.01ND1,2,4-Trichlorobenzene
4.0 1.0 ppb v/v 03/19/24 22:36 4.01341,2,4-Trimethylbenzene
4.0 0.62 ppb v/v 03/19/24 22:36 4.01ND1,2-Dibromoethane (EDB)
4.0 0.60 ppb v/v 03/19/24 22:36 4.01ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
8.0 1.6 ppb v/v 03/19/24 22:36 4.01ND1,2-Dichlorobenzene
4.0 0.50 ppb v/v 03/19/24 22:36 4.01ND1,2-Dichloroethane
4.0 0.50 ppb v/v 03/19/24 22:36 4.01ND1,2-Dichloropropane
8.0 3.2 ppb v/v 03/19/24 22:36 4.01111,3,5-Trimethylbenzene
8.0 0.96 ppb v/v 03/19/24 22:36 4.01ND1,3-Butadiene
4.0 0.80 ppb v/v 03/19/24 22:36 4.01ND1,3-Dichlorobenzene
4.0 0.80 ppb v/v 03/19/24 22:36 4.01ND1,4-Dichlorobenzene
20 3.6 ppb v/v 03/19/24 22:36 4.011502-Butanone (MEK)
10 2.8 ppb v/v 03/19/24 22:36 4.01ND2-Hexanone
8.0 1.1 ppb v/v 03/19/24 22:36 4.019.94-Ethyltoluene
20 2.8 ppb v/v 03/19/24 22:36 4.01304-Methyl-2-pentanone (MIBK)
150 28 ppb v/v 03/21/24 18:00 4.01230Acetone
4.0 0.66 ppb v/v 03/19/24 22:36 4.0181Benzene
8.0 1.9 ppb v/v 03/19/24 22:36 4.01NDBenzyl chloride
4.0 0.88 ppb v/v 03/19/24 22:36 4.01NDBromodichloromethane
4.0 1.3 ppb v/v 03/19/24 22:36 4.01NDBromoform
4.0 1.1 ppb v/v 03/19/24 22:36 4.01NDBromomethane
8.0 1.7 ppb v/v 03/19/24 22:36 4.01NDCarbon disulfide
4.0 0.64 ppb v/v 03/19/24 22:36 4.01NDCarbon tetrachloride
4.0 1.1 ppb v/v 03/19/24 22:36 4.01NDChlorobenzene
4.0 1.6 ppb v/v 03/19/24 22:36 4.01NDChloroethane
4.0 0.72 ppb v/v 03/19/24 22:36 4.010.79 JChloroform
20 3.2 ppb v/v 03/19/24 22:36 4.01NDChloromethane
4.0 0.50 ppb v/v 03/19/24 22:36 4.0127cis-1,2-Dichloroethene
8.0 0.96 ppb v/v 03/19/24 22:36 4.01NDcis-1,3-Dichloropropene
8.0 1.9 ppb v/v 03/19/24 22:36 4.0147Cyclohexane
4.0 0.68 ppb v/v 03/19/24 22:36 4.01NDDibromochloromethane
4.0 0.70 ppb v/v 03/19/24 22:36 4.01NDDichlorodifluoromethane
100 44 ppb v/v 03/19/24 22:36 4.01130Ethanol
40 3.0 ppb v/v 03/19/24 22:36 4.0110JEthyl acetate
4.0 0.66 ppb v/v 03/19/24 22:36 4.0119Ethylbenzene
20 1.6 ppb v/v 03/19/24 22:36 4.01NDHexachlorobutadiene
40 4.8 ppb v/v 03/21/24 18:00 4.011700Isopropyl alcohol
20 2.6 ppb v/v 03/19/24 22:36 4.01NDMethyl tert-butyl ether
4.0 1.0 ppb v/v 03/19/24 22:36 4.0186CIMethylcyclohexane
20 6.8 ppb v/v 03/19/24 22:36 4.019.1 JMethylene Chloride
4.0 1.5 ppb v/v 03/19/24 22:36 4.0171m-Xylene & p-Xylene
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 23 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-4Client Sample ID: 03072024-4
Matrix: AirDate Collected: 03/07/24 15:25
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
92 8.0 0.70 ppb v/v 03/19/24 22:36 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Heptane
8.0 1.3 ppb v/v 03/19/24 22:36 4.01100n-Hexane
8.0 2.2 ppb v/v 03/19/24 22:36 4.0149Nonane
4.0 0.76 ppb v/v 03/19/24 22:36 4.0124o-Xylene
4.0 1.2 ppb v/v 03/19/24 22:36 4.011.3 JStyrene
4.0 0.58 ppb v/v 03/19/24 22:36 4.0125Tetrachloroethene
20 3.6 ppb v/v 03/19/24 22:36 4.0172Tetrahydrofuran
20 1.1 ppb v/v 03/19/24 22:36 4.01140Toluene
4.0 0.66 ppb v/v 03/19/24 22:36 4.01NDtrans-1,2-Dichloroethene
4.0 0.98 ppb v/v 03/19/24 22:36 4.01NDtrans-1,3-Dichloropropene
4.0 0.66 ppb v/v 03/19/24 22:36 4.01400Trichloroethene
4.0 0.56 ppb v/v 03/19/24 22:36 4.01NDTrichlorofluoromethane
20 1.4 ppb v/v 03/19/24 22:36 4.01NDVinyl acetate
8.0 1.3 ppb v/v 03/19/24 22:36 4.01NDVinyl chloride
RL MDL
12 J 22 7.9 ug/m3 03/19/24 22:36 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
28 4.8 ug/m3 03/19/24 22:36 4.01ND1,1,2,2-Tetrachloroethane
31 3.7 ug/m3 03/19/24 22:36 4.013.8 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
22 4.2 ug/m3 03/19/24 22:36 4.01ND1,1,2-Trichloroethane
16 2.2 ug/m3 03/19/24 22:36 4.01451,1-Dichloroethane
16 2.5 ug/m3 03/19/24 22:36 4.01ND1,1-Dichloroethene
20 8.9 ug/m3 03/19/24 22:36 4.01471,2,3-Trimethylbenzene
150 13 ug/m3 03/19/24 22:36 4.01ND1,2,4-Trichlorobenzene
20 4.9 ug/m3 03/19/24 22:36 4.011701,2,4-Trimethylbenzene
31 4.8 ug/m3 03/19/24 22:36 4.01ND1,2-Dibromoethane (EDB)
28 4.2 ug/m3 03/19/24 22:36 4.01ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
48 9.4 ug/m3 03/19/24 22:36 4.01ND1,2-Dichlorobenzene
16 2.0 ug/m3 03/19/24 22:36 4.01ND1,2-Dichloroethane
19 2.3 ug/m3 03/19/24 22:36 4.01ND1,2-Dichloropropane
39 16 ug/m3 03/19/24 22:36 4.01531,3,5-Trimethylbenzene
18 2.1 ug/m3 03/19/24 22:36 4.01ND1,3-Butadiene
24 4.8 ug/m3 03/19/24 22:36 4.01ND1,3-Dichlorobenzene
24 4.8 ug/m3 03/19/24 22:36 4.01ND1,4-Dichlorobenzene
59 11 ug/m3 03/19/24 22:36 4.014502-Butanone (MEK)
41 12 ug/m3 03/19/24 22:36 4.01ND2-Hexanone
39 5.2 ug/m3 03/19/24 22:36 4.01494-Ethyltoluene
82 11 ug/m3 03/19/24 22:36 4.011204-Methyl-2-pentanone (MIBK)
360 67 ug/m3 03/21/24 18:00 4.01550Acetone
13 2.1 ug/m3 03/19/24 22:36 4.01260Benzene
42 9.9 ug/m3 03/19/24 22:36 4.01NDBenzyl chloride
27 5.9 ug/m3 03/19/24 22:36 4.01NDBromodichloromethane
41 14 ug/m3 03/19/24 22:36 4.01NDBromoform
16 4.3 ug/m3 03/19/24 22:36 4.01NDBromomethane
25 5.4 ug/m3 03/19/24 22:36 4.01NDCarbon disulfide
25 4.0 ug/m3 03/19/24 22:36 4.01NDCarbon tetrachloride
18 5.2 ug/m3 03/19/24 22:36 4.01NDChlorobenzene
11 4.2 ug/m3 03/19/24 22:36 4.01NDChloroethane
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 24 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-4Client Sample ID: 03072024-4
Matrix: AirDate Collected: 03/07/24 15:25
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
3.8 J 20 3.5 ug/m3 03/19/24 22:36 4.01
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Chloroform
41 6.6 ug/m3 03/19/24 22:36 4.01NDChloromethane
16 2.0 ug/m3 03/19/24 22:36 4.01110cis-1,2-Dichloroethene
36 4.4 ug/m3 03/19/24 22:36 4.01NDcis-1,3-Dichloropropene
28 6.4 ug/m3 03/19/24 22:36 4.01160Cyclohexane
34 5.8 ug/m3 03/19/24 22:36 4.01NDDibromochloromethane
20 3.5 ug/m3 03/19/24 22:36 4.01NDDichlorodifluoromethane
190 83 ug/m3 03/19/24 22:36 4.01240Ethanol
140 11 ug/m3 03/19/24 22:36 4.0138JEthyl acetate
17 2.9 ug/m3 03/19/24 22:36 4.0183Ethylbenzene
210 17 ug/m3 03/19/24 22:36 4.01NDHexachlorobutadiene
99 12 ug/m3 03/21/24 18:00 4.014200Isopropyl alcohol
72 9.4 ug/m3 03/19/24 22:36 4.01NDMethyl tert-butyl ether
16 4.0 ug/m3 03/19/24 22:36 4.01340CIMethylcyclohexane
70 24 ug/m3 03/19/24 22:36 4.0132JMethylene Chloride
17 6.4 ug/m3 03/19/24 22:36 4.01310m-Xylene & p-Xylene
33 2.9 ug/m3 03/19/24 22:36 4.01380n-Heptane
28 4.5 ug/m3 03/19/24 22:36 4.01360n-Hexane
42 12 ug/m3 03/19/24 22:36 4.01260Nonane
17 3.3 ug/m3 03/19/24 22:36 4.01100o-Xylene
17 5.1 ug/m3 03/19/24 22:36 4.015.4 JStyrene
27 3.9 ug/m3 03/19/24 22:36 4.01170Tetrachloroethene
59 11 ug/m3 03/19/24 22:36 4.01210Tetrahydrofuran
76 4.3 ug/m3 03/19/24 22:36 4.01540Toluene
16 2.6 ug/m3 03/19/24 22:36 4.01NDtrans-1,2-Dichloroethene
18 4.5 ug/m3 03/19/24 22:36 4.01NDtrans-1,3-Dichloropropene
22 3.6 ug/m3 03/19/24 22:36 4.012200Trichloroethene
23 3.2 ug/m3 03/19/24 22:36 4.01NDTrichlorofluoromethane
71 4.9 ug/m3 03/19/24 22:36 4.01NDVinyl acetate
21 3.3 ug/m3 03/19/24 22:36 4.01NDVinyl chloride
Butane, 2-methyl-52 T J N ppb v/v 5.27 78-78-4 03/19/24 22:36 4.01
Tentatively Identified Compound Dil FacAnalyzedPreparedUnitDQualifierEst. Result CAS No.RT
4.0103/19/24 22:36T J NPentane, 2-methyl-107-83-568ppb v/v 7.55
4.0103/19/24 22:36T J NPentane, 3-methyl-96-14-050ppb v/v 8.02
4.0103/19/24 22:36T JUnknown N/A68ppb v/v 8.80
4.0103/19/24 22:36T J NCyclopentane, methyl-96-37-788ppb v/v 9.74
4.0103/19/24 22:36T JUnknown N/A64ppb v/v 11.80
4.0103/19/24 22:36T J NOctane 111-65-951ppb v/v 15.07
4.0103/19/24 22:36T J NDecane 124-18-5120ppb v/v 19.01
4.0103/19/24 22:36T J NUndecane 1120-21-483ppb v/v 20.28
4-Bromofluorobenzene (Surr)100 60 -140 03/19/24 22:36 4.01
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)120 03/21/24 18:00 4.0160-140
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 25 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-5Client Sample ID: 03072024-5
Matrix: AirDate Collected: 03/07/24 16:30
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air
RL MDL
2.0 J 3.6 1.3 ppb v/v 03/19/24 23:21 4.45
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
3.6 0.62 ppb v/v 03/19/24 23:21 4.45ND1,1,2,2-Tetrachloroethane
3.6 0.43 ppb v/v 03/19/24 23:21 4.450.43 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
3.6 0.68 ppb v/v 03/19/24 23:21 4.45ND1,1,2-Trichloroethane
3.6 0.48 ppb v/v 03/19/24 23:21 4.459.71,1-Dichloroethane
3.6 0.57 ppb v/v 03/19/24 23:21 4.45ND1,1-Dichloroethene
3.6 1.6 ppb v/v 03/19/24 23:21 4.457.91,2,3-Trimethylbenzene
18 1.6 ppb v/v 03/19/24 23:21 4.45ND1,2,4-Trichlorobenzene
3.6 0.89 ppb v/v 03/19/24 23:21 4.45271,2,4-Trimethylbenzene
3.6 0.55 ppb v/v 03/19/24 23:21 4.45ND1,2-Dibromoethane (EDB)
3.6 0.53 ppb v/v 03/19/24 23:21 4.45ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
7.1 1.4 ppb v/v 03/19/24 23:21 4.45ND1,2-Dichlorobenzene
3.6 0.45 ppb v/v 03/19/24 23:21 4.45ND1,2-Dichloroethane
3.6 0.45 ppb v/v 03/19/24 23:21 4.45ND1,2-Dichloropropane
7.1 2.8 ppb v/v 03/19/24 23:21 4.45101,3,5-Trimethylbenzene
7.1 0.85 ppb v/v 03/19/24 23:21 4.45ND1,3-Butadiene
3.6 0.71 ppb v/v 03/19/24 23:21 4.45ND1,3-Dichlorobenzene
3.6 0.71 ppb v/v 03/19/24 23:21 4.45ND1,4-Dichlorobenzene
18 3.2 ppb v/v 03/19/24 23:21 4.451502-Butanone (MEK)
8.9 2.5 ppb v/v 03/19/24 23:21 4.45ND2-Hexanone
7.1 0.94 ppb v/v 03/19/24 23:21 4.459.04-Ethyltoluene
18 2.5 ppb v/v 03/19/24 23:21 4.45374-Methyl-2-pentanone (MIBK)
130 25 ppb v/v 03/21/24 18:50 4.45230Acetone
3.6 0.59 ppb v/v 03/19/24 23:21 4.4586Benzene
7.1 1.7 ppb v/v 03/19/24 23:21 4.45NDBenzyl chloride
3.6 0.78 ppb v/v 03/19/24 23:21 4.45NDBromodichloromethane
3.6 1.2 ppb v/v 03/19/24 23:21 4.45NDBromoform
3.6 0.98 ppb v/v 03/19/24 23:21 4.45NDBromomethane
7.1 1.5 ppb v/v 03/19/24 23:21 4.45NDCarbon disulfide
3.6 0.57 ppb v/v 03/19/24 23:21 4.45NDCarbon tetrachloride
3.6 1.0 ppb v/v 03/19/24 23:21 4.451.1 JChlorobenzene
3.6 1.4 ppb v/v 03/19/24 23:21 4.45NDChloroethane
3.6 0.64 ppb v/v 03/19/24 23:21 4.450.85 JChloroform
18 2.8 ppb v/v 03/19/24 23:21 4.45NDChloromethane
3.6 0.45 ppb v/v 03/19/24 23:21 4.4524cis-1,2-Dichloroethene
7.1 0.85 ppb v/v 03/19/24 23:21 4.45NDcis-1,3-Dichloropropene
7.1 1.7 ppb v/v 03/19/24 23:21 4.4547Cyclohexane
3.6 0.61 ppb v/v 03/19/24 23:21 4.45NDDibromochloromethane
3.6 0.62 ppb v/v 03/19/24 23:21 4.45NDDichlorodifluoromethane
89 39 ppb v/v 03/19/24 23:21 4.45150Ethanol
36 2.7 ppb v/v 03/19/24 23:21 4.4511JEthyl acetate
3.6 0.59 ppb v/v 03/19/24 23:21 4.4518Ethylbenzene
18 1.4 ppb v/v 03/19/24 23:21 4.45NDHexachlorobutadiene
36 4.3 ppb v/v 03/21/24 18:50 4.452000Isopropyl alcohol
18 2.3 ppb v/v 03/19/24 23:21 4.45NDMethyl tert-butyl ether
3.6 0.89 ppb v/v 03/19/24 23:21 4.4583CIMethylcyclohexane
18 6.1 ppb v/v 03/19/24 23:21 4.459.9 JMethylene Chloride
3.6 1.3 ppb v/v 03/19/24 23:21 4.4570m-Xylene & p-Xylene
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Page 26 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-5Client Sample ID: 03072024-5
Matrix: AirDate Collected: 03/07/24 16:30
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
91 7.1 0.62 ppb v/v 03/19/24 23:21 4.45
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Heptane
7.1 1.1 ppb v/v 03/19/24 23:21 4.45100n-Hexane
7.1 2.0 ppb v/v 03/19/24 23:21 4.4551Nonane
3.6 0.68 ppb v/v 03/19/24 23:21 4.4524o-Xylene
3.6 1.1 ppb v/v 03/19/24 23:21 4.451.3 JStyrene
3.6 0.52 ppb v/v 03/19/24 23:21 4.4525Tetrachloroethene
18 3.2 ppb v/v 03/19/24 23:21 4.45100Tetrahydrofuran
18 1.0 ppb v/v 03/19/24 23:21 4.45140Toluene
3.6 0.59 ppb v/v 03/19/24 23:21 4.45NDtrans-1,2-Dichloroethene
3.6 0.87 ppb v/v 03/19/24 23:21 4.45NDtrans-1,3-Dichloropropene
3.6 0.59 ppb v/v 03/19/24 23:21 4.45370Trichloroethene
3.6 0.50 ppb v/v 03/19/24 23:21 4.45NDTrichlorofluoromethane
18 1.2 ppb v/v 03/19/24 23:21 4.45NDVinyl acetate
7.1 1.2 ppb v/v 03/19/24 23:21 4.45NDVinyl chloride
RL MDL
11 J 19 7.0 ug/m3 03/19/24 23:21 4.45
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
24 4.3 ug/m3 03/19/24 23:21 4.45ND1,1,2,2-Tetrachloroethane
27 3.3 ug/m3 03/19/24 23:21 4.453.3 J1,1,2-Trichloro-1,2,2-trifluoroetha
ne
19 3.7 ug/m3 03/19/24 23:21 4.45ND1,1,2-Trichloroethane
14 1.9 ug/m3 03/19/24 23:21 4.45391,1-Dichloroethane
14 2.3 ug/m3 03/19/24 23:21 4.45ND1,1-Dichloroethene
18 7.9 ug/m3 03/19/24 23:21 4.45391,2,3-Trimethylbenzene
130 12 ug/m3 03/19/24 23:21 4.45ND1,2,4-Trichlorobenzene
18 4.4 ug/m3 03/19/24 23:21 4.451301,2,4-Trimethylbenzene
27 4.2 ug/m3 03/19/24 23:21 4.45ND1,2-Dibromoethane (EDB)
25 3.7 ug/m3 03/19/24 23:21 4.45ND1,2-Dichloro-1,1,2,2-tetrafluoroethane
43 8.3 ug/m3 03/19/24 23:21 4.45ND1,2-Dichlorobenzene
14 1.8 ug/m3 03/19/24 23:21 4.45ND1,2-Dichloroethane
16 2.1 ug/m3 03/19/24 23:21 4.45ND1,2-Dichloropropane
35 14 ug/m3 03/19/24 23:21 4.45491,3,5-Trimethylbenzene
16 1.9 ug/m3 03/19/24 23:21 4.45ND1,3-Butadiene
21 4.3 ug/m3 03/19/24 23:21 4.45ND1,3-Dichlorobenzene
21 4.3 ug/m3 03/19/24 23:21 4.45ND1,4-Dichlorobenzene
52 9.4 ug/m3 03/19/24 23:21 4.454502-Butanone (MEK)
36 10 ug/m3 03/19/24 23:21 4.45ND2-Hexanone
35 4.6 ug/m3 03/19/24 23:21 4.45444-Ethyltoluene
73 10 ug/m3 03/19/24 23:21 4.451504-Methyl-2-pentanone (MIBK)
320 59 ug/m3 03/21/24 18:50 4.45540Acetone
11 1.9 ug/m3 03/19/24 23:21 4.45270Benzene
37 8.8 ug/m3 03/19/24 23:21 4.45NDBenzyl chloride
24 5.2 ug/m3 03/19/24 23:21 4.45NDBromodichloromethane
37 12 ug/m3 03/19/24 23:21 4.45NDBromoform
14 3.8 ug/m3 03/19/24 23:21 4.45NDBromomethane
22 4.8 ug/m3 03/19/24 23:21 4.45NDCarbon disulfide
22 3.6 ug/m3 03/19/24 23:21 4.45NDCarbon tetrachloride
16 4.6 ug/m3 03/19/24 23:21 4.454.9 JChlorobenzene
9.4 3.7 ug/m3 03/19/24 23:21 4.45NDChloroethane
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Page 27 of 864
Client Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Lab Sample ID: 140-35862-5Client Sample ID: 03072024-5
Matrix: AirDate Collected: 03/07/24 16:30
Date Received: 03/12/24 10:00
Sample Container: Summa Canister 6L
Method: EPA TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
RL MDL
4.2 J 17 3.1 ug/m3 03/19/24 23:21 4.45
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Chloroform
37 5.9 ug/m3 03/19/24 23:21 4.45NDChloromethane
14 1.8 ug/m3 03/19/24 23:21 4.4595cis-1,2-Dichloroethene
32 3.9 ug/m3 03/19/24 23:21 4.45NDcis-1,3-Dichloropropene
25 5.7 ug/m3 03/19/24 23:21 4.45160Cyclohexane
30 5.2 ug/m3 03/19/24 23:21 4.45NDDibromochloromethane
18 3.1 ug/m3 03/19/24 23:21 4.45NDDichlorodifluoromethane
170 74 ug/m3 03/19/24 23:21 4.45290Ethanol
130 9.6 ug/m3 03/19/24 23:21 4.4540JEthyl acetate
15 2.6 ug/m3 03/19/24 23:21 4.4580Ethylbenzene
190 15 ug/m3 03/19/24 23:21 4.45NDHexachlorobutadiene
88 11 ug/m3 03/21/24 18:50 4.454800Isopropyl alcohol
64 8.3 ug/m3 03/19/24 23:21 4.45NDMethyl tert-butyl ether
14 3.6 ug/m3 03/19/24 23:21 4.45330CIMethylcyclohexane
62 21 ug/m3 03/19/24 23:21 4.4535JMethylene Chloride
15 5.6 ug/m3 03/19/24 23:21 4.45300m-Xylene & p-Xylene
29 2.6 ug/m3 03/19/24 23:21 4.45370n-Heptane
25 4.0 ug/m3 03/19/24 23:21 4.45360n-Hexane
37 10 ug/m3 03/19/24 23:21 4.45270Nonane
15 2.9 ug/m3 03/19/24 23:21 4.45100o-Xylene
15 4.5 ug/m3 03/19/24 23:21 4.455.4 JStyrene
24 3.5 ug/m3 03/19/24 23:21 4.45170Tetrachloroethene
52 9.4 ug/m3 03/19/24 23:21 4.45290Tetrahydrofuran
67 3.8 ug/m3 03/19/24 23:21 4.45540Toluene
14 2.3 ug/m3 03/19/24 23:21 4.45NDtrans-1,2-Dichloroethene
16 4.0 ug/m3 03/19/24 23:21 4.45NDtrans-1,3-Dichloropropene
19 3.2 ug/m3 03/19/24 23:21 4.452000Trichloroethene
20 2.8 ug/m3 03/19/24 23:21 4.45NDTrichlorofluoromethane
63 4.4 ug/m3 03/19/24 23:21 4.45NDVinyl acetate
18 3.0 ug/m3 03/19/24 23:21 4.45NDVinyl chloride
Butane, 2-methyl-43 T J N ppb v/v 5.28 78-78-4 03/19/24 23:21 4.45
Tentatively Identified Compound Dil FacAnalyzedPreparedUnitDQualifierEst. Result CAS No.RT
4.4503/19/24 23:21T J NPentane, 2-methyl-107-83-568ppb v/v 7.55
4.4503/19/24 23:21T J NPentane, 3-methyl-96-14-049ppb v/v 8.03
4.4503/19/24 23:21T JUnknown N/A150ppb v/v 8.59
4.4503/19/24 23:21T JUnknown N/A81ppb v/v 8.81
4.4503/19/24 23:21T J NCyclopentane, methyl-96-37-788ppb v/v 9.74
4.4503/19/24 23:21T JUnknown N/A64ppb v/v 11.80
4.4503/19/24 23:21T J NOctane 111-65-952ppb v/v 15.07
4.4503/19/24 23:21T J NDecane 124-18-596ppb v/v 19.01
4.4503/19/24 23:21T J NUndecane 1120-21-470ppb v/v 20.28
4-Bromofluorobenzene (Surr)101 60 -140 03/19/24 23:21 4.45
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
4-Bromofluorobenzene (Surr)117 03/21/24 18:50 4.4560-140
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Page 28 of 864
Default Detection Limits
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air
0.201,1,1-Trichloroethane ppb v/v
Analyte UnitsMDLRL
0.072
1.11,1,1-Trichloroethane ug/m30.39
0.201,1,2,2-Tetrachloroethane ppb v/v0.035
1.41,1,2,2-Tetrachloroethane ug/m30.24
0.201,1,2-Trichloro-1,2,2-trifluoroethane ppb v/v0.024
1.51,1,2-Trichloro-1,2,2-trifluoroethane ug/m30.18
0.201,1,2-Trichloroethane ppb v/v0.038
1.11,1,2-Trichloroethane ug/m30.21
0.201,1-Dichloroethane ppb v/v0.027
0.811,1-Dichloroethane ug/m30.11
0.201,1-Dichloroethene ppb v/v0.032
0.791,1-Dichloroethene ug/m30.13
0.201,2,3-Trimethylbenzene ppb v/v0.090
0.981,2,3-Trimethylbenzene ug/m30.44
1.01,2,4-Trichlorobenzene ppb v/v0.089
7.41,2,4-Trichlorobenzene ug/m30.66
0.201,2,4-Trimethylbenzene ppb v/v0.050
0.981,2,4-Trimethylbenzene ug/m30.25
0.201,2-Dibromoethane (EDB)ppb v/v0.031
1.51,2-Dibromoethane (EDB)ug/m30.24
0.201,2-Dichloro-1,1,2,2-tetrafluoroethane ppb v/v0.030
1.41,2-Dichloro-1,1,2,2-tetrafluoroethane ug/m30.21
0.401,2-Dichlorobenzene ppb v/v0.078
2.41,2-Dichlorobenzene ug/m30.47
0.201,2-Dichloroethane ppb v/v0.025
0.811,2-Dichloroethane ug/m30.10
0.201,2-Dichloropropane ppb v/v0.025
0.921,2-Dichloropropane ug/m30.12
0.401,3,5-Trimethylbenzene ppb v/v0.16
2.01,3,5-Trimethylbenzene ug/m30.79
0.401,3-Butadiene ppb v/v0.048
0.881,3-Butadiene ug/m30.11
0.201,3-Dichlorobenzene ppb v/v0.040
1.21,3-Dichlorobenzene ug/m30.24
0.201,4-Dichlorobenzene ppb v/v0.040
1.21,4-Dichlorobenzene ug/m30.24
1.02-Butanone (MEK)ppb v/v0.18
2.92-Butanone (MEK)ug/m30.53
0.502-Hexanone ppb v/v0.14
2.02-Hexanone ug/m30.57
0.404-Ethyltoluene ppb v/v0.053
2.04-Ethyltoluene ug/m30.26
1.04-Methyl-2-pentanone (MIBK)ppb v/v0.14
4.14-Methyl-2-pentanone (MIBK)ug/m30.57
7.5Acetone ppb v/v1.4
18Acetone ug/m33.3
0.20Benzene ppb v/v0.033
0.64Benzene ug/m30.11
0.40Benzyl chloride ppb v/v0.095
2.1Benzyl chloride ug/m30.49
0.20Bromodichloromethane ppb v/v0.044
1.3Bromodichloromethane ug/m30.29
0.20Bromoform ppb v/v0.066
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Page 29 of 864
Default Detection Limits
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
2.1Bromoform ug/m3
Analyte UnitsMDLRL
0.68
0.20Bromomethane ppb v/v0.055
0.78Bromomethane ug/m30.21
0.40Carbon disulfide ppb v/v0.087
1.2Carbon disulfide ug/m30.27
0.20Carbon tetrachloride ppb v/v0.032
1.3Carbon tetrachloride ug/m30.20
0.20Chlorobenzene ppb v/v0.056
0.92Chlorobenzene ug/m30.26
0.20Chloroethane ppb v/v0.079
0.53Chloroethane ug/m30.21
0.20Chloroform ppb v/v0.036
0.98Chloroform ug/m30.18
1.0Chloromethane ppb v/v0.16
2.1Chloromethane ug/m30.33
0.20cis-1,2-Dichloroethene ppb v/v0.025
0.79cis-1,2-Dichloroethene ug/m30.099
0.40cis-1,3-Dichloropropene ppb v/v0.048
1.8cis-1,3-Dichloropropene ug/m30.22
0.40Cyclohexane ppb v/v0.093
1.4Cyclohexane ug/m30.32
0.20Dibromochloromethane ppb v/v0.034
1.7Dibromochloromethane ug/m30.29
0.20Dichlorodifluoromethane ppb v/v0.035
0.99Dichlorodifluoromethane ug/m30.17
5.0Ethanol ppb v/v2.2
9.4Ethanol ug/m34.1
2.0Ethyl acetate ppb v/v0.15
7.2Ethyl acetate ug/m30.54
0.20Ethylbenzene ppb v/v0.033
0.87Ethylbenzene ug/m30.14
1.0Hexachlorobutadiene ppb v/v0.080
11Hexachlorobutadiene ug/m30.85
2.0Isopropyl alcohol ppb v/v0.24
4.9Isopropyl alcohol ug/m30.59
1.0Methyl tert-butyl ether ppb v/v0.13
3.6Methyl tert-butyl ether ug/m30.47
0.20Methylcyclohexane ppb v/v0.050
0.80Methylcyclohexane ug/m30.20
1.0Methylene Chloride ppb v/v0.34
3.5Methylene Chloride ug/m31.2
0.20m-Xylene & p-Xylene ppb v/v0.073
0.87m-Xylene & p-Xylene ug/m30.32
0.40n-Heptane ppb v/v0.035
1.6n-Heptane ug/m30.14
0.40n-Hexane ppb v/v0.063
1.4n-Hexane ug/m30.22
0.40Nonane ppb v/v0.11
2.1Nonane ug/m30.58
0.20o-Xylene ppb v/v0.038
0.87o-Xylene ug/m30.17
0.20Styrene ppb v/v0.060
0.85Styrene ug/m30.26
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Page 30 of 864
Default Detection Limits
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
0.20Tetrachloroethene ppb v/v
Analyte UnitsMDLRL
0.029
1.4Tetrachloroethene ug/m30.20
1.0Tetrahydrofuran ppb v/v0.18
2.9Tetrahydrofuran ug/m30.53
1.0Toluene ppb v/v0.057
3.8Toluene ug/m30.21
0.20trans-1,2-Dichloroethene ppb v/v0.033
0.79trans-1,2-Dichloroethene ug/m30.13
0.20trans-1,3-Dichloropropene ppb v/v0.049
0.91trans-1,3-Dichloropropene ug/m30.22
0.20Trichloroethene ppb v/v0.033
1.1Trichloroethene ug/m30.18
0.20Trichlorofluoromethane ppb v/v0.028
1.1Trichlorofluoromethane ug/m30.16
1.0Vinyl acetate ppb v/v0.070
3.5Vinyl acetate ug/m30.25
0.40Vinyl chloride ppb v/v0.065
1.0Vinyl chloride ug/m30.17
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Page 31 of 864
Surrogate Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air
Prep Type: Total/NAMatrix: Air
Lab Sample ID Client Sample ID (60-140)
BFB
94140-35862-1
Percent Surrogate Recovery (Acceptance Limits)
03072024-1
102140-35862-1 03072024-1
91140-35862-2 03072024-2
103140-35862-2 03072024-2
99140-35862-3 03072024-3
103140-35862-3 03072024-3
100140-35862-4 03072024-4
120140-35862-4 03072024-4
101140-35862-5 03072024-5
117140-35862-5 03072024-5
109LCS 140-84584/1002 Lab Control Sample
103LCS 140-84603/1002 Lab Control Sample
120LCS 140-84641/1002 Lab Control Sample
99MB 140-84584/5 Method Blank
95MB 140-84603/6 Method Blank
114MB 140-84641/5 Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene (Surr)
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Page 32 of 864
QC Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air
Client Sample ID: Method BlankLab Sample ID: MB 140-84584/5
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84584
RL MDL
1,1,1-Trichloroethane ND 0.20 0.072 ppb v/v 03/19/24 09:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.0350.20 ppb v/v 03/19/24 09:44 11,1,2,2-Tetrachloroethane
ND 0.0240.20 ppb v/v 03/19/24 09:44 11,1,2-Trichloro-1,2,2-trifluoroethane
ND 0.0380.20 ppb v/v 03/19/24 09:44 11,1,2-Trichloroethane
ND 0.0270.20 ppb v/v 03/19/24 09:44 11,1-Dichloroethane
ND 0.0320.20 ppb v/v 03/19/24 09:44 11,1-Dichloroethene
ND 0.0900.20 ppb v/v 03/19/24 09:44 11,2,3-Trimethylbenzene
ND 0.0891.0 ppb v/v 03/19/24 09:44 11,2,4-Trichlorobenzene
ND 0.0500.20 ppb v/v 03/19/24 09:44 11,2,4-Trimethylbenzene
ND 0.0310.20 ppb v/v 03/19/24 09:44 11,2-Dibromoethane (EDB)
ND 0.0300.20 ppb v/v 03/19/24 09:44 11,2-Dichloro-1,1,2,2-tetrafluoroethane
ND 0.0780.40 ppb v/v 03/19/24 09:44 11,2-Dichlorobenzene
ND 0.0250.20 ppb v/v 03/19/24 09:44 11,2-Dichloroethane
ND 0.0250.20 ppb v/v 03/19/24 09:44 11,2-Dichloropropane
ND 0.160.40 ppb v/v 03/19/24 09:44 11,3,5-Trimethylbenzene
ND 0.0480.40 ppb v/v 03/19/24 09:44 11,3-Butadiene
ND 0.0400.20 ppb v/v 03/19/24 09:44 11,3-Dichlorobenzene
ND 0.0400.20 ppb v/v 03/19/24 09:44 11,4-Dichlorobenzene
ND 0.181.0 ppb v/v 03/19/24 09:44 12-Butanone (MEK)
ND 0.140.50 ppb v/v 03/19/24 09:44 12-Hexanone
ND 0.0530.40 ppb v/v 03/19/24 09:44 14-Ethyltoluene
ND 0.141.0 ppb v/v 03/19/24 09:44 14-Methyl-2-pentanone (MIBK)
ND 0.0330.20 ppb v/v 03/19/24 09:44 1Benzene
ND 0.0950.40 ppb v/v 03/19/24 09:44 1Benzyl chloride
ND 0.0440.20 ppb v/v 03/19/24 09:44 1Bromodichloromethane
ND 0.0660.20 ppb v/v 03/19/24 09:44 1Bromoform
ND 0.0550.20 ppb v/v 03/19/24 09:44 1Bromomethane
ND 0.0870.40 ppb v/v 03/19/24 09:44 1Carbon disulfide
ND 0.0320.20 ppb v/v 03/19/24 09:44 1Carbon tetrachloride
ND 0.0560.20 ppb v/v 03/19/24 09:44 1Chlorobenzene
ND 0.0790.20 ppb v/v 03/19/24 09:44 1Chloroethane
ND 0.0360.20 ppb v/v 03/19/24 09:44 1Chloroform
ND 0.161.0 ppb v/v 03/19/24 09:44 1Chloromethane
ND 0.0250.20 ppb v/v 03/19/24 09:44 1cis-1,2-Dichloroethene
ND 0.0480.40 ppb v/v 03/19/24 09:44 1cis-1,3-Dichloropropene
ND 0.0930.40 ppb v/v 03/19/24 09:44 1Cyclohexane
ND 0.0340.20 ppb v/v 03/19/24 09:44 1Dibromochloromethane
ND 0.0350.20 ppb v/v 03/19/24 09:44 1Dichlorodifluoromethane
ND 2.25.0 ppb v/v 03/19/24 09:44 1Ethanol
ND 0.152.0 ppb v/v 03/19/24 09:44 1Ethyl acetate
ND 0.0330.20 ppb v/v 03/19/24 09:44 1Ethylbenzene
ND 0.0801.0 ppb v/v 03/19/24 09:44 1Hexachlorobutadiene
ND 0.131.0 ppb v/v 03/19/24 09:44 1Methyl tert-butyl ether
ND 0.0500.20 ppb v/v 03/19/24 09:44 1Methylcyclohexane
ND 0.341.0 ppb v/v 03/19/24 09:44 1Methylene Chloride
ND 0.0730.20 ppb v/v 03/19/24 09:44 1m-Xylene & p-Xylene
ND 0.0350.40 ppb v/v 03/19/24 09:44 1n-Heptane
ND 0.0630.40 ppb v/v 03/19/24 09:44 1n-Hexane
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 33 of 864
QC Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 140-84584/5
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84584
RL MDL
Nonane ND 0.40 0.11 ppb v/v 03/19/24 09:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.0380.20 ppb v/v 03/19/24 09:44 1o-Xylene
ND 0.0600.20 ppb v/v 03/19/24 09:44 1Styrene
ND 0.0290.20 ppb v/v 03/19/24 09:44 1Tetrachloroethene
ND 0.181.0 ppb v/v 03/19/24 09:44 1Tetrahydrofuran
ND 0.0571.0 ppb v/v 03/19/24 09:44 1Toluene
ND 0.0330.20 ppb v/v 03/19/24 09:44 1trans-1,2-Dichloroethene
ND 0.0490.20 ppb v/v 03/19/24 09:44 1trans-1,3-Dichloropropene
ND 0.0330.20 ppb v/v 03/19/24 09:44 1Trichloroethene
ND 0.0280.20 ppb v/v 03/19/24 09:44 1Trichlorofluoromethane
ND 0.0701.0 ppb v/v 03/19/24 09:44 1Vinyl acetate
ND 0.0650.40 ppb v/v 03/19/24 09:44 1Vinyl chloride
RL MDL
1,1,1-Trichloroethane ND 1.1 0.39 ug/m3 03/19/24 09:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.241.4 ug/m3 03/19/24 09:44 11,1,2,2-Tetrachloroethane
ND 0.181.5 ug/m3 03/19/24 09:44 11,1,2-Trichloro-1,2,2-trifluoroethane
ND 0.211.1 ug/m3 03/19/24 09:44 11,1,2-Trichloroethane
ND 0.110.81 ug/m3 03/19/24 09:44 11,1-Dichloroethane
ND 0.130.79 ug/m3 03/19/24 09:44 11,1-Dichloroethene
ND 0.440.98 ug/m3 03/19/24 09:44 11,2,3-Trimethylbenzene
ND 0.667.4 ug/m3 03/19/24 09:44 11,2,4-Trichlorobenzene
ND 0.250.98 ug/m3 03/19/24 09:44 11,2,4-Trimethylbenzene
ND 0.241.5 ug/m3 03/19/24 09:44 11,2-Dibromoethane (EDB)
ND 0.211.4 ug/m3 03/19/24 09:44 11,2-Dichloro-1,1,2,2-tetrafluoroethane
ND 0.472.4 ug/m3 03/19/24 09:44 11,2-Dichlorobenzene
ND 0.100.81 ug/m3 03/19/24 09:44 11,2-Dichloroethane
ND 0.120.92 ug/m3 03/19/24 09:44 11,2-Dichloropropane
ND 0.792.0 ug/m3 03/19/24 09:44 11,3,5-Trimethylbenzene
ND 0.110.88 ug/m3 03/19/24 09:44 11,3-Butadiene
ND 0.241.2 ug/m3 03/19/24 09:44 11,3-Dichlorobenzene
ND 0.241.2 ug/m3 03/19/24 09:44 11,4-Dichlorobenzene
ND 0.532.9 ug/m3 03/19/24 09:44 12-Butanone (MEK)
ND 0.572.0 ug/m3 03/19/24 09:44 12-Hexanone
ND 0.262.0 ug/m3 03/19/24 09:44 14-Ethyltoluene
ND 0.574.1 ug/m3 03/19/24 09:44 14-Methyl-2-pentanone (MIBK)
ND 0.110.64 ug/m3 03/19/24 09:44 1Benzene
ND 0.492.1 ug/m3 03/19/24 09:44 1Benzyl chloride
ND 0.291.3 ug/m3 03/19/24 09:44 1Bromodichloromethane
ND 0.682.1 ug/m3 03/19/24 09:44 1Bromoform
ND 0.210.78 ug/m3 03/19/24 09:44 1Bromomethane
ND 0.271.2 ug/m3 03/19/24 09:44 1Carbon disulfide
ND 0.201.3 ug/m3 03/19/24 09:44 1Carbon tetrachloride
ND 0.260.92 ug/m3 03/19/24 09:44 1Chlorobenzene
ND 0.210.53 ug/m3 03/19/24 09:44 1Chloroethane
ND 0.180.98 ug/m3 03/19/24 09:44 1Chloroform
ND 0.332.1 ug/m3 03/19/24 09:44 1Chloromethane
ND 0.0990.79 ug/m3 03/19/24 09:44 1cis-1,2-Dichloroethene
ND 0.221.8 ug/m3 03/19/24 09:44 1cis-1,3-Dichloropropene
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 34 of 864
QC Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 140-84584/5
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84584
RL MDL
Cyclohexane ND 1.4 0.32 ug/m3 03/19/24 09:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.291.7 ug/m3 03/19/24 09:44 1Dibromochloromethane
ND 0.170.99 ug/m3 03/19/24 09:44 1Dichlorodifluoromethane
ND 4.19.4 ug/m3 03/19/24 09:44 1Ethanol
ND 0.547.2 ug/m3 03/19/24 09:44 1Ethyl acetate
ND 0.140.87 ug/m3 03/19/24 09:44 1Ethylbenzene
ND 0.8511 ug/m3 03/19/24 09:44 1Hexachlorobutadiene
ND 0.473.6 ug/m3 03/19/24 09:44 1Methyl tert-butyl ether
ND 0.200.80 ug/m3 03/19/24 09:44 1Methylcyclohexane
ND 1.23.5 ug/m3 03/19/24 09:44 1Methylene Chloride
ND 0.320.87 ug/m3 03/19/24 09:44 1m-Xylene & p-Xylene
ND 0.141.6 ug/m3 03/19/24 09:44 1n-Heptane
ND 0.221.4 ug/m3 03/19/24 09:44 1n-Hexane
ND 0.582.1 ug/m3 03/19/24 09:44 1Nonane
ND 0.170.87 ug/m3 03/19/24 09:44 1o-Xylene
ND 0.260.85 ug/m3 03/19/24 09:44 1Styrene
ND 0.201.4 ug/m3 03/19/24 09:44 1Tetrachloroethene
ND 0.532.9 ug/m3 03/19/24 09:44 1Tetrahydrofuran
ND 0.213.8 ug/m3 03/19/24 09:44 1Toluene
ND 0.130.79 ug/m3 03/19/24 09:44 1trans-1,2-Dichloroethene
ND 0.220.91 ug/m3 03/19/24 09:44 1trans-1,3-Dichloropropene
ND 0.181.1 ug/m3 03/19/24 09:44 1Trichloroethene
ND 0.161.1 ug/m3 03/19/24 09:44 1Trichlorofluoromethane
ND 0.253.5 ug/m3 03/19/24 09:44 1Vinyl acetate
ND 0.171.0 ug/m3 03/19/24 09:44 1Vinyl chloride
Tentatively Identified Compound None ppb v/v N/A 03/19/24 09:44 1
MB MB
Tentatively Identified Compound Dil FacPreparedAnalyzedDUnitQualifierEst. Result RT CAS No.
4-Bromofluorobenzene (Surr)99 60 -140 03/19/24 09:44 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-84584/1002
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84584
1,1,1-Trichloroethane 1.60 1.52 ppb v/v 95 70 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 1.60 1.62 ppb v/v 101 70 -130
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
1.60 1.66 ppb v/v 104 70 -130
1,1,2-Trichloroethane 1.60 1.65 ppb v/v 103 70 -130
1,1-Dichloroethane 1.60 1.59 ppb v/v 99 70 -130
1,1-Dichloroethene 1.60 1.66 ppb v/v 104 70 -130
1,2,3-Trimethylbenzene 1.60 1.18 ppb v/v 74 70 -130
1,2,4-Trichlorobenzene 1.60 1.33 ppb v/v 83 60 -140
1,2,4-Trimethylbenzene 1.60 1.60 ppb v/v 100 70 -130
1,2-Dibromoethane (EDB)1.60 1.64 ppb v/v 102 70 -130
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 35 of 864
QC Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-84584/1002
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84584
1,2-Dichloro-1,1,2,2-tetrafluoroet
hane
1.60 1.48 ppb v/v 92 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,2-Dichlorobenzene 1.60 1.54 ppb v/v 96 70 -130
1,2-Dichloroethane 1.60 1.72 ppb v/v 107 70 -130
1,2-Dichloropropane 1.60 1.64 ppb v/v 102 70 -130
1,3,5-Trimethylbenzene 1.60 1.74 ppb v/v 109 70 -130
1,3-Butadiene 1.60 1.57 ppb v/v 98 60 -140
1,3-Dichlorobenzene 1.60 1.52 ppb v/v 95 70 -130
1,4-Dichlorobenzene 1.60 1.51 ppb v/v 95 70 -130
2-Butanone (MEK)1.60 1.66 ppb v/v 104 60 -140
2-Hexanone 1.60 1.71 ppb v/v 107 60 -140
4-Ethyltoluene 1.60 1.52 ppb v/v 95 70 -130
4-Methyl-2-pentanone (MIBK)1.60 1.80 ppb v/v 113 60 -140
Benzene 1.60 1.65 ppb v/v 103 70 -130
Benzyl chloride 1.60 1.55 ppb v/v 97 70 -130
Bromodichloromethane 1.60 1.79 ppb v/v 112 70 -130
Bromoform 1.60 1.83 ppb v/v 114 60 -140
Bromomethane 1.60 1.41 ppb v/v 88 70 -130
Carbon disulfide 1.60 1.52 ppb v/v 95 70 -130
Carbon tetrachloride 1.60 1.49 ppb v/v 93 70 -130
Chlorobenzene 1.60 1.66 ppb v/v 104 70 -130
Chloroethane 1.60 1.45 ppb v/v 90 70 -130
Chloroform 1.60 1.64 ppb v/v 102 70 -130
Chloromethane 1.60 1.54 ppb v/v 96 60 -140
cis-1,2-Dichloroethene 1.60 1.64 ppb v/v 102 70 -130
cis-1,3-Dichloropropene 1.60 1.84 ppb v/v 115 70 -130
Cyclohexane 1.60 1.66 ppb v/v 104 70 -130
Dibromochloromethane 1.60 1.70 ppb v/v 106 70 -130
Dichlorodifluoromethane 1.60 1.41 ppb v/v 88 60 -140
Ethanol 8.00 5.48 ppb v/v 68 60 -140
Ethyl acetate 1.60 1.60 ppb v/v 100 60 -140
Ethylbenzene 1.60 1.67 ppb v/v 104 70 -130
Hexachlorobutadiene 1.60 1.27 ppb v/v 80 60 -140
Methyl tert-butyl ether 1.60 1.59 ppb v/v 99 60 -140
Methylcyclohexane 1.60 2.13 ppb v/v 133 60 -140
Methylene Chloride 1.60 1.52 ppb v/v 95 70 -130
m-Xylene & p-Xylene 3.20 3.47 ppb v/v 108 70 -130
n-Heptane 1.60 1.65 ppb v/v 103 70 -130
n-Hexane 1.60 1.73 ppb v/v 108 70 -130
Nonane 1.60 1.81 ppb v/v 113 60 -140
o-Xylene 1.60 1.72 ppb v/v 108 70 -130
Styrene 1.60 1.74 ppb v/v 109 70 -130
Tetrachloroethene 1.60 1.61 ppb v/v 101 70 -130
Tetrahydrofuran 1.60 1.61 ppb v/v 101 60 -140
Toluene 1.60 1.65 ppb v/v 103 70 -130
trans-1,2-Dichloroethene 1.60 1.51 ppb v/v 94 70 -130
trans-1,3-Dichloropropene 1.60 1.73 ppb v/v 108 70 -130
Trichloroethene 1.60 1.70 ppb v/v 106 70 -130
Trichlorofluoromethane 1.60 1.82 ppb v/v 114 60 -140
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 36 of 864
QC Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-84584/1002
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84584
Vinyl acetate 1.60 1.53 ppb v/v 95 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Vinyl chloride 1.60 1.64 ppb v/v 103 70 -130
1,1,1-Trichloroethane 8.7 8.27 ug/m3 95 70 -130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 11 11.1 ug/m3 101 70 -130
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
12 12.7 ug/m3 104 70 -130
1,1,2-Trichloroethane 8.7 9.01 ug/m3 103 70 -130
1,1-Dichloroethane 6.5 6.44 ug/m3 99 70 -130
1,1-Dichloroethene 6.3 6.57 ug/m3 104 70 -130
1,2,3-Trimethylbenzene 7.9 5.80 ug/m3 74 70 -130
1,2,4-Trichlorobenzene 12 9.84 ug/m3 83 60 -140
1,2,4-Trimethylbenzene 7.9 7.86 ug/m3 100 70 -130
1,2-Dibromoethane (EDB)12 12.6 ug/m3 102 70 -130
1,2-Dichloro-1,1,2,2-tetrafluoroet
hane
11 10.3 ug/m3 92 60 -140
1,2-Dichlorobenzene 9.6 9.23 ug/m3 96 70 -130
1,2-Dichloroethane 6.5 6.94 ug/m3 107 70 -130
1,2-Dichloropropane 7.4 7.57 ug/m3 102 70 -130
1,3,5-Trimethylbenzene 7.9 8.56 ug/m3 109 70 -130
1,3-Butadiene 3.5 3.47 ug/m3 98 60 -140
1,3-Dichlorobenzene 9.6 9.14 ug/m3 95 70 -130
1,4-Dichlorobenzene 9.6 9.11 ug/m3 95 70 -130
2-Butanone (MEK)4.7 4.90 ug/m3 104 60 -140
2-Hexanone 6.6 6.99 ug/m3 107 60 -140
4-Ethyltoluene 7.9 7.47 ug/m3 95 70 -130
4-Methyl-2-pentanone (MIBK)6.6 7.38 ug/m3 113 60 -140
Benzene 5.1 5.27 ug/m3 103 70 -130
Benzyl chloride 8.3 8.04 ug/m3 97 70 -130
Bromodichloromethane 11 12.0 ug/m3 112 70 -130
Bromoform 17 18.9 ug/m3 114 60 -140
Bromomethane 6.2 5.48 ug/m3 88 70 -130
Carbon disulfide 5.0 4.75 ug/m3 95 70 -130
Carbon tetrachloride 10 9.37 ug/m3 93 70 -130
Chlorobenzene 7.4 7.63 ug/m3 104 70 -130
Chloroethane 4.2 3.82 ug/m3 90 70 -130
Chloroform 7.8 7.99 ug/m3 102 70 -130
Chloromethane 3.3 3.18 ug/m3 96 60 -140
cis-1,2-Dichloroethene 6.3 6.50 ug/m3 102 70 -130
cis-1,3-Dichloropropene 7.3 8.35 ug/m3 115 70 -130
Cyclohexane 5.5 5.71 ug/m3 104 70 -130
Dibromochloromethane 14 14.5 ug/m3 106 70 -130
Dichlorodifluoromethane 7.9 6.99 ug/m3 88 60 -140
Ethanol 15 10.3 ug/m3 68 60 -140
Ethyl acetate 5.8 5.77 ug/m3 100 60 -140
Ethylbenzene 6.9 7.25 ug/m3 104 70 -130
Hexachlorobutadiene 17 13.6 ug/m3 80 60 -140
Methyl tert-butyl ether 5.8 5.73 ug/m3 99 60 -140
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 37 of 864
QC Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-84584/1002
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84584
Methylcyclohexane 6.4 8.54 ug/m3 133 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Methylene Chloride 5.6 5.28 ug/m3 95 70 -130
m-Xylene & p-Xylene 14 15.1 ug/m3 108 70 -130
n-Heptane 6.6 6.78 ug/m3 103 70 -130
n-Hexane 5.6 6.08 ug/m3 108 70 -130
Nonane 8.4 9.47 ug/m3 113 60 -140
o-Xylene 6.9 7.49 ug/m3 108 70 -130
Styrene 6.8 7.40 ug/m3 109 70 -130
Tetrachloroethene 11 10.9 ug/m3 101 70 -130
Tetrahydrofuran 4.7 4.75 ug/m3 101 60 -140
Toluene 6.0 6.23 ug/m3 103 70 -130
trans-1,2-Dichloroethene 6.3 5.98 ug/m3 94 70 -130
trans-1,3-Dichloropropene 7.3 7.84 ug/m3 108 70 -130
Trichloroethene 8.6 9.15 ug/m3 106 70 -130
Trichlorofluoromethane 9.0 10.2 ug/m3 114 60 -140
Vinyl acetate 5.6 5.37 ug/m3 95 60 -140
Vinyl chloride 4.1 4.20 ug/m3 103 70 -130
4-Bromofluorobenzene (Surr)60 -140
Surrogate
109
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-84603/6
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84603
RL MDL
Acetone ND 7.5 1.4 ppb v/v 03/20/24 08:52 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.242.0 ppb v/v 03/20/24 08:52 1Isopropyl alcohol
RL MDL
Acetone ND 18 3.3 ug/m3 03/20/24 08:52 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.594.9 ug/m3 03/20/24 08:52 1Isopropyl alcohol
Tentatively Identified Compound None ppb v/v N/A 03/20/24 08:52 1
MB MB
Tentatively Identified Compound Dil FacPreparedAnalyzedDUnitQualifierEst. Result RT CAS No.
4-Bromofluorobenzene (Surr)95 60 -140 03/20/24 08:52 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-84603/1002
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84603
Acetone 1.60 2.22 J ppb v/v 139 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Isopropyl alcohol 1.60 1.90 ppb v/v 119 60 -140
Eurofins Knoxville
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9:50:51 AM
Page 38 of 864
QC Sample Results
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method: TO-15 - Volatile Organic Compounds in Ambient Air (Continued)
Acetone 3.8 5.27 J ug/m3 139 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Isopropyl alcohol 3.9 4.67 ug/m3 119 60 -140
4-Bromofluorobenzene (Surr)60 -140
Surrogate
103
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-84641/5
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84641
RL MDL
Acetone ND 7.5 1.4 ppb v/v 03/21/24 08:06 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.242.0 ppb v/v 03/21/24 08:06 1Isopropyl alcohol
RL MDL
Acetone ND 18 3.3 ug/m3 03/21/24 08:06 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.594.9 ug/m3 03/21/24 08:06 1Isopropyl alcohol
Tentatively Identified Compound None ppb v/v N/A 03/21/24 08:06 1
MB MB
Tentatively Identified Compound Dil FacPreparedAnalyzedDUnitQualifierEst. Result RT CAS No.
4-Bromofluorobenzene (Surr)114 60 -140 03/21/24 08:06 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-84641/1002
Matrix: Air Prep Type: Total/NA
Analysis Batch: 84641
Acetone 1.60 1.53 J ppb v/v 96 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Isopropyl alcohol 1.60 1.53 ppb v/v 96 60 -140
Acetone 3.8 3.64 J ug/m3 96 60 -140
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Isopropyl alcohol 3.9 3.76 ug/m3 96 60 -140
4-Bromofluorobenzene (Surr)60 -140
Surrogate
120
LCS LCS
Qualifier Limits%Recovery
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 39 of 864
QC Association Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Air - GC/MS VOA
Analysis Batch: 84584
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air TO-15140-35862-1 03072024-1 Total/NA
Air TO-15140-35862-2 03072024-2 Total/NA
Air TO-15140-35862-3 03072024-3 Total/NA
Air TO-15140-35862-4 03072024-4 Total/NA
Air TO-15140-35862-5 03072024-5 Total/NA
Air TO-15MB 140-84584/5 Method Blank Total/NA
Air TO-15LCS 140-84584/1002 Lab Control Sample Total/NA
Analysis Batch: 84603
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air TO-15140-35862-1 03072024-1 Total/NA
Air TO-15140-35862-2 03072024-2 Total/NA
Air TO-15140-35862-3 03072024-3 Total/NA
Air TO-15MB 140-84603/6 Method Blank Total/NA
Air TO-15LCS 140-84603/1002 Lab Control Sample Total/NA
Analysis Batch: 84641
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air TO-15140-35862-4 03072024-4 Total/NA
Air TO-15140-35862-5 03072024-5 Total/NA
Air TO-15MB 140-84641/5 Method Blank Total/NA
Air TO-15LCS 140-84641/1002 Lab Control Sample Total/NA
Eurofins Knoxville
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9:50:51 AM
Page 40 of 864
Lab Chronicle
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Client Sample ID: 03072024-1 Lab Sample ID: 140-35862-1
Matrix: AirDate Collected: 03/07/24 11:20
Date Received: 03/12/24 10:00
Analysis TO-15 S1K03/19/24 20:194.01 EET KNX84584
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 40 mL 500 mL
Instrument ID:MR
Analysis TO-15 4.01 84603 03/20/24 16:56 S1K EET KNXTotal/NA 10 mL 500 mL
MRInstrument ID:
Client Sample ID: 03072024-2 Lab Sample ID: 140-35862-2
Matrix: AirDate Collected: 03/07/24 12:40
Date Received: 03/12/24 10:00
Analysis TO-15 S1K03/19/24 21:053.95 EET KNX84584
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 40 mL 500 mL
Instrument ID:MR
Analysis TO-15 3.95 84603 03/20/24 17:43 S1K EET KNXTotal/NA 10 mL 500 mL
MRInstrument ID:
Client Sample ID: 03072024-3 Lab Sample ID: 140-35862-3
Matrix: AirDate Collected: 03/07/24 13:55
Date Received: 03/12/24 10:00
Analysis TO-15 S1K03/19/24 21:504.16 EET KNX84584
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 40 mL 500 mL
Instrument ID:MR
Analysis TO-15 4.16 84603 03/20/24 18:30 S1K EET KNXTotal/NA 20 mL 500 mL
MRInstrument ID:
Client Sample ID: 03072024-4 Lab Sample ID: 140-35862-4
Matrix: AirDate Collected: 03/07/24 15:25
Date Received: 03/12/24 10:00
Analysis TO-15 S1K03/19/24 22:364.01 EET KNX84584
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 40 mL 500 mL
Instrument ID:MR
Analysis TO-15 4.01 84641 03/21/24 18:00 S1K EET KNXTotal/NA 40 mL 500 mL
MSInstrument ID:
Client Sample ID: 03072024-5 Lab Sample ID: 140-35862-5
Matrix: AirDate Collected: 03/07/24 16:30
Date Received: 03/12/24 10:00
Analysis TO-15 S1K03/19/24 23:214.45 EET KNX84584
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 500 mL
Instrument ID:MR
Analysis TO-15 4.45 84641 03/21/24 18:50 S1K EET KNXTotal/NA 50 mL 500 mL
MSInstrument ID:
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 41 of 864
Lab Chronicle
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Client Sample ID: Method Blank Lab Sample ID: MB 140-84584/5
Matrix: AirDate Collected: N/A
Date Received: N/A
Analysis TO-15 S1K03/19/24 09:441 EET KNX84584
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 200 mL 500 mL
Instrument ID:MR
Client Sample ID: Method Blank Lab Sample ID: MB 140-84603/6
Matrix: AirDate Collected: N/A
Date Received: N/A
Analysis TO-15 S1K03/20/24 08:521 EET KNX84603
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 200 mL 500 mL
Instrument ID:MR
Client Sample ID: Method Blank Lab Sample ID: MB 140-84641/5
Matrix: AirDate Collected: N/A
Date Received: N/A
Analysis TO-15 S1K03/21/24 08:061 EET KNX84641
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 200 mL 500 mL
Instrument ID:MS
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-84584/1002
Matrix: AirDate Collected: N/A
Date Received: N/A
Analysis TO-15 S1K03/19/24 07:401 EET KNX84584
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 500 mL 500 mL
Instrument ID:MR
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-84603/1002
Matrix: AirDate Collected: N/A
Date Received: N/A
Analysis TO-15 S1K03/20/24 07:061 EET KNX84603
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 500 mL 500 mL
Instrument ID:MR
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-84641/1002
Matrix: AirDate Collected: N/A
Date Received: N/A
Analysis TO-15 S1K03/21/24 06:461 EET KNX84641
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 500 mL 500 mL
Instrument ID:MS
Laboratory References:
EET KNX = Eurofins Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 42 of 864
Accreditation/Certification Summary
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Laboratory: Eurofins Knoxville
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
Utah NELAP TN00009 07-31-24
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
TO-15 Air 1,1,1-Trichloroethane
TO-15 Air 1,1,2,2-Tetrachloroethane
TO-15 Air 1,1,2-Trichloro-1,2,2-trifluoroethane
TO-15 Air 1,1,2-Trichloroethane
TO-15 Air 1,1-Dichloroethane
TO-15 Air 1,1-Dichloroethene
TO-15 Air 1,2,3-Trimethylbenzene
TO-15 Air 1,2,4-Trichlorobenzene
TO-15 Air 1,2,4-Trimethylbenzene
TO-15 Air 1,2-Dibromoethane (EDB)
TO-15 Air 1,2-Dichloro-1,1,2,2-tetrafluoroethane
TO-15 Air 1,2-Dichlorobenzene
TO-15 Air 1,2-Dichloroethane
TO-15 Air 1,2-Dichloropropane
TO-15 Air 1,3,5-Trimethylbenzene
TO-15 Air 1,3-Butadiene
TO-15 Air 1,3-Dichlorobenzene
TO-15 Air 1,4-Dichlorobenzene
TO-15 Air 2-Butanone (MEK)
TO-15 Air 2-Hexanone
TO-15 Air 4-Ethyltoluene
TO-15 Air 4-Methyl-2-pentanone (MIBK)
TO-15 Air Acetone
TO-15 Air Benzene
TO-15 Air Benzyl chloride
TO-15 Air Bromodichloromethane
TO-15 Air Bromoform
TO-15 Air Bromomethane
TO-15 Air Carbon disulfide
TO-15 Air Carbon tetrachloride
TO-15 Air Chlorobenzene
TO-15 Air Chloroethane
TO-15 Air Chloroform
TO-15 Air Chloromethane
TO-15 Air cis-1,2-Dichloroethene
TO-15 Air cis-1,3-Dichloropropene
TO-15 Air Cyclohexane
TO-15 Air Dibromochloromethane
TO-15 Air Dichlorodifluoromethane
TO-15 Air Ethanol
TO-15 Air Ethyl acetate
TO-15 Air Ethylbenzene
TO-15 Air Hexachlorobutadiene
TO-15 Air Isopropyl alcohol
TO-15 Air Methyl tert-butyl ether
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 43 of 864
Accreditation/Certification Summary
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Laboratory: Eurofins Knoxville (Continued)
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes
for which the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
TO-15 Air Methylcyclohexane
TO-15 Air Methylene Chloride
TO-15 Air m-Xylene & p-Xylene
TO-15 Air n-Heptane
TO-15 Air n-Hexane
TO-15 Air Nonane
TO-15 Air o-Xylene
TO-15 Air Styrene
TO-15 Air Tetrachloroethene
TO-15 Air Tetrahydrofuran
TO-15 Air Toluene
TO-15 Air trans-1,2-Dichloroethene
TO-15 Air trans-1,3-Dichloropropene
TO-15 Air Trichloroethene
TO-15 Air Trichlorofluoromethane
TO-15 Air Vinyl acetate
TO-15 Air Vinyl chloride
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 44 of 864
Method Summary
Job ID: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Method Method Description LaboratoryProtocol
EPATO-15 Volatile Organic Compounds in Ambient Air EET KNX
Protocol References:
EPA = US Environmental Protection Agency
Laboratory References:
EET KNX = Eurofins Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 45 of 864
Sample Summary
Client: Clean Harbors Environmental Services Inc Job ID: 140-35862-1
Project/Site: Carbon Beds Test
Lab Sample ID Client Sample ID Matrix Collected Received Asset ID
140-35862-1 03072024-1 Air 03/07/24 11:20 03/12/24 10:00 Air Canister (6-Liter) #11605
140-35862-2 03072024-2 Air 03/07/24 12:40 03/12/24 10:00 Air Canister (6-Liter) #10809
140-35862-3 03072024-3 Air 03/07/24 13:55 03/12/24 10:00 Air Canister (6-Liter) #34002161
140-35862-4 03072024-4 Air 03/07/24 15:25 03/12/24 10:00 Air Canister (6-Liter) #11995
140-35862-5 03072024-5 Air 03/07/24 16:30 03/12/24 10:00 Air Canister (6-Liter) #11198
Eurofins Knoxville3/25/2024
9:50:51 AM
Page 46 of 864
Method TO15
Volatile Organic Compounds (GC/MS)
by Method TO15
3/25/2024
9:50:51 AM
Page 47 of 864
FORM II
AIR - GC/MS VOA SURROGATE RECOVERY
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Matrix:Air Level:Low
GC Column (1):RTX-5 ID:0.32(mm)
Lab Sample IDClient Sample ID #BFB
140-35862-103072024-1 94
140-35862-103072024-1 102
140-35862-203072024-2 91
140-35862-203072024-2 103
140-35862-303072024-3 99
140-35862-303072024-3 103
140-35862-403072024-4 100
140-35862-403072024-4 120
140-35862-503072024-5 101
140-35862-503072024-5 117
MB 140-84584/5 99
MB 140-84603/6 95
MB 140-84641/5 114
LCS
140-84584/1002 109
LCS
140-84603/1002 103
LCS
140-84641/1002 120
QC LIMITS
BFB = 4-Bromofluorobenzene (Surr)60-140
FORM II TO-15
# Column to be used to flag recovery values
3/25/2024
9:50:51 AM
Page 48 of 864
AIR - GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:140-35862-1Eurofins Knoxville
SDG No.:
Level:Matrix:Low Lab File ID:-RCCVZC19-LCS.dAir
Lab ID:LCS 140-84584/1002 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ppb v/v)
SPIKE
ADDED
(ppb v/v)
#
LCS LCS
COMPOUND
1,1,1-Trichloroethane 1.60 1.52 70-13095
1,1,2,2-Tetrachloroethane 1.60 1.62 70-130101
1,1,2-Trichloro-1,2,2-trifluor
oethane
1.60 1.66 70-130104
1,1,2-Trichloroethane 1.60 1.65 70-130103
1,1-Dichloroethane 1.60 1.59 70-13099
1,1-Dichloroethene 1.60 1.66 70-130104
1,2,3-Trimethylbenzene 1.60 1.18 70-13074
1,2,4-Trichlorobenzene 1.60 1.33 60-14083
1,2,4-Trimethylbenzene 1.60 1.60 70-130100
1,2-Dibromoethane (EDB)1.60 1.64 70-130102
1,2-Dichloro-1,1,2,2-tetrafluo
roethane
1.60 1.48 60-14092
1,2-Dichlorobenzene 1.60 1.54 70-13096
1,2-Dichloroethane 1.60 1.72 70-130107
1,2-Dichloropropane 1.60 1.64 70-130102
1,3,5-Trimethylbenzene 1.60 1.74 70-130109
1,3-Butadiene 1.60 1.57 60-14098
1,3-Dichlorobenzene 1.60 1.52 70-13095
1,4-Dichlorobenzene 1.60 1.51 70-13095
2-Butanone (MEK)1.60 1.66 60-140104
2-Hexanone 1.60 1.71 60-140107
4-Ethyltoluene 1.60 1.52 70-13095
4-Methyl-2-pentanone (MIBK)1.60 1.80 60-140113
Benzene 1.60 1.65 70-130103
Benzyl chloride 1.60 1.55 70-13097
Bromodichloromethane 1.60 1.79 70-130112
Bromoform 1.60 1.83 60-140114
Bromomethane 1.60 1.41 70-13088
Carbon disulfide 1.60 1.52 70-13095
Carbon tetrachloride 1.60 1.49 70-13093
Chlorobenzene 1.60 1.66 70-130104
Chloroethane 1.60 1.45 70-13090
Chloroform 1.60 1.64 70-130102
Chloromethane 1.60 1.54 60-14096
cis-1,2-Dichloroethene 1.60 1.64 70-130102
cis-1,3-Dichloropropene 1.60 1.84 70-130115
Cyclohexane 1.60 1.66 70-130104
Dibromochloromethane 1.60 1.70 70-130106
Dichlorodifluoromethane 1.60 1.41 60-14088
Ethanol 8.00 5.48 60-14068
Ethyl acetate 1.60 1.60 60-140100
FORM III TO-15
# Column to be used to flag recovery and RPD values
3/25/2024
9:50:51 AM
Page 49 of 864
AIR - GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:140-35862-1Eurofins Knoxville
SDG No.:
Level:Matrix:Low Lab File ID:-RCCVZC19-LCS.dAir
Lab ID:LCS 140-84584/1002 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ppb v/v)
SPIKE
ADDED
(ppb v/v)
#
LCS LCS
COMPOUND
Ethylbenzene 1.60 1.67 70-130104
Hexachlorobutadiene 1.60 1.27 60-14080
Methyl tert-butyl ether 1.60 1.59 60-14099
Methylcyclohexane 1.60 2.13 60-140133
Methylene Chloride 1.60 1.52 70-13095
m-Xylene & p-Xylene 3.20 3.47 70-130108
n-Heptane 1.60 1.65 70-130103
n-Hexane 1.60 1.73 70-130108
Nonane 1.60 1.81 60-140113
o-Xylene 1.60 1.72 70-130108
Styrene 1.60 1.74 70-130109
Tetrachloroethene 1.60 1.61 70-130101
Tetrahydrofuran 1.60 1.61 60-140101
Toluene 1.60 1.65 70-130103
trans-1,2-Dichloroethene 1.60 1.51 70-13094
trans-1,3-Dichloropropene 1.60 1.73 70-130108
Trichloroethene 1.60 1.70 70-130106
Trichlorofluoromethane 1.60 1.82 60-140114
Vinyl acetate 1.60 1.53 60-14095
Vinyl chloride 1.60 1.64 70-130103
FORM III TO-15
# Column to be used to flag recovery and RPD values
3/25/2024
9:50:51 AM
Page 50 of 864
AIR - GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:140-35862-1Eurofins Knoxville
SDG No.:
Level:Matrix:Low Lab File ID:-RCCVZC20-LCS.dAir
Lab ID:LCS 140-84603/1002 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ppb v/v)
SPIKE
ADDED
(ppb v/v)
#
LCS LCS
COMPOUND
Acetone 1.60 2.22 60-140139J
Isopropyl alcohol 1.60 1.90 60-140119
FORM III TO-15
# Column to be used to flag recovery and RPD values
3/25/2024
9:50:51 AM
Page 51 of 864
AIR - GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:140-35862-1Eurofins Knoxville
SDG No.:
Level:Matrix:Low Lab File ID:-SCCVZC21-LCS.dAir
Lab ID:LCS 140-84641/1002 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ppb v/v)
SPIKE
ADDED
(ppb v/v)
#
LCS LCS
COMPOUND
Acetone 1.60 1.53 60-14096J
Isopropyl alcohol 1.60 1.53 60-14096
FORM III TO-15
# Column to be used to flag recovery and RPD values
3/25/2024
9:50:51 AM
Page 52 of 864
FORM IV
AIR - GC/MS VOA METHOD BLANK SUMMARY
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Date Analyzed:
GC Column:ID:
Instrument ID:03/19/2024 09:44
RTX-5
NHeated Purge:(Y/N)
MR
RZC19MBA.DLab File ID:Lab Sample ID:MB 140-84584/5
AirMatrix:
0.32(mm)
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:
LAB SAMPLE ID
LAB
FILE ID DATE ANALYZEDCLIENT SAMPLE ID
03/19/2024 20:19RZC19P110.D140-35862-103072024-1
03/19/2024 21:05RZC19P111.D140-35862-203072024-2
03/19/2024 21:50RZC19P112.D140-35862-303072024-3
03/19/2024 22:36RZC19P113.D140-35862-403072024-4
03/19/2024 23:21RZC19P114.D140-35862-503072024-5
FORM IV TO-15
3/25/2024
9:50:51 AM
Page 53 of 864
FORM IV
AIR - GC/MS VOA METHOD BLANK SUMMARY
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Date Analyzed:
GC Column:ID:
Instrument ID:03/20/2024 08:52
RTX-5
NHeated Purge:(Y/N)
MR
RZC20BLK35930A2B.DLab File ID:Lab Sample ID:MB 140-84603/6
AirMatrix:
0.32(mm)
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:
LAB SAMPLE ID
LAB
FILE ID DATE ANALYZEDCLIENT SAMPLE ID
03/20/2024 16:56RZC20P107.D140-35862-103072024-1
03/20/2024 17:43RZC20P108.D140-35862-203072024-2
03/20/2024 18:30RZC20P109.D140-35862-303072024-3
FORM IV TO-15
3/25/2024
9:50:51 AM
Page 54 of 864
FORM IV
AIR - GC/MS VOA METHOD BLANK SUMMARY
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Date Analyzed:
GC Column:ID:
Instrument ID:03/21/2024 08:06
RTX-5
NHeated Purge:(Y/N)
MS
SZC21CAN11296MBA.DLab File ID:Lab Sample ID:MB 140-84641/5
AirMatrix:
0.32(mm)
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:
LAB SAMPLE ID
LAB
FILE ID DATE ANALYZEDCLIENT SAMPLE ID
03/21/2024 18:00SZC21P109.D140-35862-403072024-4
03/21/2024 18:50SZC21P110.D140-35862-503072024-5
FORM IV TO-15
3/25/2024
9:50:51 AM
Page 55 of 864
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Knoxville 140-35862-1
Lab File ID:
Instrument ID:
RZC05BFB.D
MR
03/05/2024
13:59
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:84237
50 15.0 - 40.0 % of mass 95 20.3
75 30.0 - 60.0 % of mass 95 51.3
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 7.0
173 Less than 2.0 % of mass 174 0.8 (1.1)1
174 Greater than 50% of mass 95 79.7
175 5.0 - 9.0 % of mass 174 6.1 (7.6)1
176 95.0 - 101.0 % of mass 174 77.2 (96.8)1
177 5.0 - 9.0 % of mass 176 5.0 (6.5)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
IC 140-84237/3 RZC05L10.D 03/05/2024 15:18
IC 140-84237/5 RZC05L9.D 03/05/2024 16:55
IC 140-84237/7 RZC05L8.D 03/05/2024 18:30
IC 140-84237/9 RZC05L1.D 03/05/2024 20:04
IC 140-84237/10 RZC05L2.D 03/05/2024 20:51
IC 140-84237/11 RZC05L3.D 03/05/2024 21:39
IC 140-84237/12 RZC05L4.D 03/05/2024 22:24
IC 140-84237/13 RZC05L5.D 03/05/2024 23:11
IC 140-84237/14 RZC05L6.D 03/05/2024 23:59
ICIS 140-84237/15 RZC05ICIS7.D 03/06/2024 0:47
ICV 140-84237/17 RZC05LCS.D 03/06/2024 2:20
FORM V TO-15 3/25/2024
9:50:51 AM
Page 56 of 864
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Knoxville 140-35862-1
Lab File ID:
Instrument ID:
RBFBZC19.D
MR
03/19/2024
07:09
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:84584
50 15.0 - 40.0 % of mass 95 19.9
75 30.0 - 60.0 % of mass 95 51.4
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.6
173 Less than 2.0 % of mass 174 0.8 (1.1)1
174 Greater than 50% of mass 95 74.4
175 5.0 - 9.0 % of mass 174 5.6 (7.5)1
176 95.0 - 101.0 % of mass 174 72.4 (97.3)1
177 5.0 - 9.0 % of mass 176 4.6 (6.3)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCVIS 140-84584/2 RCCVZC19.D 03/19/2024 7:40
LCS 140-84584/1002 -RCCVZC19-LCS.d03/19/2024 7:40
MB 140-84584/5 RZC19MBA.D 03/19/2024 9:44
03072024-1 140-35862-1 RZC19P110.D 03/19/2024 20:19
03072024-2 140-35862-2 RZC19P111.D 03/19/2024 21:05
03072024-3 140-35862-3 RZC19P112.D 03/19/2024 21:50
03072024-4 140-35862-4 RZC19P113.D 03/19/2024 22:36
03072024-5 140-35862-5 RZC19P114.D 03/19/2024 23:21
FORM V TO-15 3/25/2024
9:50:51 AM
Page 57 of 864
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Knoxville 140-35862-1
Lab File ID:
Instrument ID:
RBFBZC20.D
MR
03/20/2024
06:37
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:84603
50 15.0 - 40.0 % of mass 95 20.3
75 30.0 - 60.0 % of mass 95 50.4
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.6
173 Less than 2.0 % of mass 174 0.7 (0.9)1
174 Greater than 50% of mass 95 78.4
175 5.0 - 9.0 % of mass 174 5.6 (7.2)1
176 95.0 - 101.0 % of mass 174 75.1 (95.8)1
177 5.0 - 9.0 % of mass 176 5.0 (6.6)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCVIS 140-84603/2 RCCVZC20.D 03/20/2024 7:06
LCS 140-84603/1002 -RCCVZC20-LCS.d03/20/2024 7:06
MB 140-84603/6 RZC20BLK35930A2B.D03/20/2024 8:52
03072024-1 140-35862-1 RZC20P107.D 03/20/2024 16:56
03072024-2 140-35862-2 RZC20P108.D 03/20/2024 17:43
03072024-3 140-35862-3 RZC20P109.D 03/20/2024 18:30
FORM V TO-15 3/25/2024
9:50:51 AM
Page 58 of 864
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Knoxville 140-35862-1
Lab File ID:
Instrument ID:
SZBFBB07.D
MS
02/07/2024
14:06
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:83168
50 15.0 - 40.0 % of mass 95 16.7
75 30.0 - 60.0 % of mass 95 45.8
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.7
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 108.2
175 5.0 - 9.0 % of mass 174 7.7 (7.2)1
176 95.0 - 101.0 % of mass 174 106.1 (98.1)1
177 5.0 - 9.0 % of mass 176 7.0 (6.6)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
IC 140-83168/3 SZB07IC10.D 02/07/2024 15:26
IC 140-83168/5 SZB07IC09.D 02/07/2024 17:08
IC 140-83168/7 SZB07IC08.D 02/07/2024 18:49
IC 140-83168/9 SZB07IC01.D 02/07/2024 20:28
IC 140-83168/10 SZB07IC02.D 02/07/2024 21:19
IC 140-83168/11 SZB07IC03.D 02/07/2024 22:11
IC 140-83168/12 SZB07IC04.D 02/07/2024 23:02
IC 140-83168/13 SZB07IC05.D 02/07/2024 23:54
IC 140-83168/14 SZB07IC06.D 02/08/2024 0:44
ICIS 140-83168/15 SZB07ICIS07.D 02/08/2024 1:36
ICV 140-83168/18 SZB07LCS.D 02/08/2024 4:07
FORM V TO-15 3/25/2024
9:50:51 AM
Page 59 of 864
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Knoxville 140-35862-1
Lab File ID:
Instrument ID:
SBFBZC21.D
MS
03/21/2024
06:18
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:84641
50 15.0 - 40.0 % of mass 95 21.1
75 30.0 - 60.0 % of mass 95 60.4
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.6
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 99.1
175 5.0 - 9.0 % of mass 174 7.2 (7.3)1
176 95.0 - 101.0 % of mass 174 97.2 (98.0)1
177 5.0 - 9.0 % of mass 176 6.4 (6.6)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCVIS 140-84641/2 SCCVZC21.D 03/21/2024 6:46
LCS 140-84641/1002 -SCCVZC21-LCS.d03/21/2024 6:46
MB 140-84641/5 SZC21CAN11296MBA.D03/21/2024 8:06
03072024-4 140-35862-4 SZC21P109.D 03/21/2024 18:00
03072024-5 140-35862-5 SZC21P110.D 03/21/2024 18:50
FORM V TO-15 3/25/2024
9:50:51 AM
Page 60 of 864
AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Knoxville 140-35862-1
SDG No.:
Sample No.:ICIS 140-84237/15 Date Analyzed:03/06/2024 00:47
Lab File ID (Standard):RZC05ICIS7.D
Instrument ID:MR GC Column:RTX-5 ID:0.32(mm)
Heated Purge: (Y/N)N
Calibration ID:4937
#RT #RT ##RT ##
CBM DFBZ CBZd5
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
298651
127993 597591
1394379
537236
1253552
9.37 11.56 16.43INITIAL CALIBRATION MID-POINT
9.70
9.04
11.89
11.23
16.76
16.10
213322 995985 895394
LAB SAMPLE ID CLIENT SAMPLE ID
ICV 140-84237/17 211954 983393 888941 9.37 11.56 16.43
CBM = Chlorobromomethane (IS)
DFBZ = 1,4-Difluorobenzene
CBZd5 = Chlorobenzene-d5 (IS)
FORM VIII TO-15
# Column used to flag values outside QC limits
Area Limit = 60%-140% of internal standard area
RT Limit = ± 0.33 minutes of internal standard RT
3/25/2024
9:50:51 AM
Page 61 of 864
AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Knoxville 140-35862-1
SDG No.:
Sample No.:CCVIS 140-84584/2 Date Analyzed:03/19/2024 07:40
Lab File ID (Standard):RCCVZC19.D
Instrument ID:MR GC Column:RTX-5 ID:0.32(mm)
Heated Purge: (Y/N)N
Calibration ID:4937
#RT #RT ##RT ##
CBM DFBZ CBZd5
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
313166
134214 594484
1387128
576297
1344693
9.36 11.55 16.4312/24 HOUR STD
9.69
9.03
11.88
11.22
16.76
16.10
223690 990806 960495
LAB SAMPLE ID CLIENT SAMPLE ID
LCS 140-84584/1002 223690 990806 960495 9.36 11.55 16.43
MB 140-84584/5 242777 1080236 1081984 9.37 11.56 16.44
140-35862-1 03072024-1 186797 864412 828937 9.38 11.56 16.42
140-35862-2 03072024-2 189419 880302 893162 9.37 11.56 16.43
140-35862-3 03072024-3 197722 917397 838314 9.37 11.56 16.42
140-35862-4 03072024-4 205913 956244 862176 9.37 11.56 16.42
140-35862-5 03072024-5 204411 950462 1038244 9.37 11.56 16.42
CBM = Chlorobromomethane (IS)
DFBZ = 1,4-Difluorobenzene
CBZd5 = Chlorobenzene-d5 (IS)
FORM VIII TO-15
# Column used to flag values outside QC limits
Area Limit = 60%-140% of internal standard area
RT Limit = ± 0.33 minutes of internal standard RT
3/25/2024
9:50:51 AM
Page 62 of 864
AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Knoxville 140-35862-1
SDG No.:
Sample No.:CCVIS 140-84603/2 Date Analyzed:03/20/2024 07:06
Lab File ID (Standard):RCCVZC20.D
Instrument ID:MR GC Column:RTX-5 ID:0.32(mm)
Heated Purge: (Y/N)N
Calibration ID:4937
#RT #RT ##RT ##
CBM DFBZ CBZd5
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
290345
124433 582643
1359499
525323
1225755
9.37 11.56 16.4412/24 HOUR STD
9.70
9.04
11.89
11.23
16.77
16.11
207389 971071 875539
LAB SAMPLE ID CLIENT SAMPLE ID
LCS 140-84603/1002 207389 971071 875539 9.37 11.56 16.44
MB 140-84603/6 225746 1054746 986359 9.37 11.56 16.44
140-35862-1 03072024-1 241579 1114980 1000447 9.37 11.56 16.42
140-35862-2 03072024-2 243314 1140850 1042390 9.37 11.56 16.43
140-35862-3 03072024-3 247739 1154233 1055138 9.36 11.55 16.42
CBM = Chlorobromomethane (IS)
DFBZ = 1,4-Difluorobenzene
CBZd5 = Chlorobenzene-d5 (IS)
FORM VIII TO-15
# Column used to flag values outside QC limits
Area Limit = 60%-140% of internal standard area
RT Limit = ± 0.33 minutes of internal standard RT
3/25/2024
9:50:51 AM
Page 63 of 864
AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Knoxville 140-35862-1
SDG No.:
Sample No.:ICIS 140-83168/15 Date Analyzed:02/08/2024 01:36
Lab File ID (Standard):SZB07ICIS07.D
Instrument ID:MS GC Column:RTX-5 ID:0.32(mm)
Heated Purge: (Y/N)N
Calibration ID:4892
#RT #RT ##RT ##
CBM DFBZ CBZd5
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
452610
193976 909937
2123187
817151
1906687
9.93 12.05 16.65INITIAL CALIBRATION MID-POINT
10.26
9.60
12.38
11.72
16.98
16.32
323293 1516562 1361919
LAB SAMPLE ID CLIENT SAMPLE ID
ICV 140-83168/18 326069 1514898 1358477 9.93 12.04 16.65
CBM = Chlorobromomethane (IS)
DFBZ = 1,4-Difluorobenzene
CBZd5 = Chlorobenzene-d5 (IS)
FORM VIII TO-15
# Column used to flag values outside QC limits
Area Limit = 60%-140% of internal standard area
RT Limit = ± 0.33 minutes of internal standard RT
3/25/2024
9:50:51 AM
Page 64 of 864
AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Knoxville 140-35862-1
SDG No.:
Sample No.:CCVIS 140-84641/2 Date Analyzed:03/21/2024 06:46
Lab File ID (Standard):SCCVZC21.D
Instrument ID:MS GC Column:RTX-5 ID:0.32(mm)
Heated Purge: (Y/N)N
Calibration ID:4892
#RT #RT ##RT ##
CBM DFBZ CBZd5
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
317334
136000 649248
1514912
581921
1357815
9.92 12.04 16.6412/24 HOUR STD
10.25
9.59
12.37
11.71
16.97
16.31
226667 1082080 969868
LAB SAMPLE ID CLIENT SAMPLE ID
LCS 140-84641/1002 226667 1082080 969868 9.92 12.04 16.64
MB 140-84641/5 217427 1020063 907363 9.92 12.03 16.64
140-35862-4 03072024-4 183219 842373 792456 9.92 12.03 16.64
140-35862-5 03072024-5 179875 832650 799623 9.92 12.04 16.64
CBM = Chlorobromomethane (IS)
DFBZ = 1,4-Difluorobenzene
CBZd5 = Chlorobenzene-d5 (IS)
FORM VIII TO-15
# Column used to flag values outside QC limits
Area Limit = 60%-140% of internal standard area
RT Limit = ± 0.33 minutes of internal standard RT
3/25/2024
9:50:51 AM
Page 65 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-1 Lab Sample ID:140-35862-1
Matrix:RZC19P110.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 11:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 20:19
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 3.6 J 4.0 1.4
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 4.0 0.70
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
1.0 J 4.0 0.48
133.4179-00-5 1,1,2-Trichloroethane ND 4.0 0.76
98.9675-34-3 1,1-Dichloroethane 20 4.0 0.54
96.9475-35-4 1,1-Dichloroethene ND 4.0 0.64
120.19526-73-8 1,2,3-Trimethylbenzene 4.6 4.0 1.8
181.45120-82-1 1,2,4-Trichlorobenzene ND 20 1.8
120.2095-63-6 1,2,4-Trimethylbenzene 18 4.0 1.0
187.87106-93-4 1,2-Dibromoethane (EDB)ND 4.0 0.62
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 4.0 0.60
147.0095-50-1 1,2-Dichlorobenzene ND 8.0 1.6
98.96107-06-2 1,2-Dichloroethane ND 4.0 0.50
112.9978-87-5 1,2-Dichloropropane ND 4.0 0.50
120.20108-67-8 1,3,5-Trimethylbenzene 6.6 J 8.0 3.2
54.09106-99-0 1,3-Butadiene ND 8.0 0.96
147.00541-73-1 1,3-Dichlorobenzene ND 4.0 0.80
147.00106-46-7 1,4-Dichlorobenzene ND 4.0 0.80
72.1178-93-3 2-Butanone (MEK)160 20 3.6
100.20591-78-6 2-Hexanone ND 10 2.8
120.20622-96-8 4-Ethyltoluene 5.2 J 8.0 1.1
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
43 20 2.8
78.1171-43-2 Benzene 150 4.0 0.66
126.58100-44-7 Benzyl chloride ND 8.0 1.9
163.8375-27-4 Bromodichloromethane ND 4.0 0.88
252.7575-25-2 Bromoform ND 4.0 1.3
94.9474-83-9 Bromomethane ND 4.0 1.1
76.1475-15-0 Carbon disulfide ND 8.0 1.7
153.8156-23-5 Carbon tetrachloride ND 4.0 0.64
112.56108-90-7 Chlorobenzene ND 4.0 1.1
64.5275-00-3 Chloroethane ND 4.0 1.6
119.3867-66-3 Chloroform 1.4 J 4.0 0.72
FORM I TO-15
3/25/2024
9:50:51 AM
Page 66 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-1 Lab Sample ID:140-35862-1
Matrix:RZC19P110.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 11:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 20:19
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 20 3.2
96.94156-59-2 cis-1,2-Dichloroethene 49 4.0 0.50
110.9710061-01-5 cis-1,3-Dichloropropene ND 8.0 0.96
84.16110-82-7 Cyclohexane 99 8.0 1.9
208.28124-48-1 Dibromochloromethane ND 4.0 0.68
120.9175-71-8 Dichlorodifluoromethane ND 4.0 0.70
46.0764-17-5 Ethanol 160 100 44
88.11141-78-6 Ethyl acetate 42 40 3.0
106.17100-41-4 Ethylbenzene 27 4.0 0.66
260.7687-68-3 Hexachlorobutadiene ND 20 1.6
88.151634-04-4 Methyl tert-butyl ether ND 20 2.6
98.19108-87-2 Methylcyclohexane 150 CI 4.0 1.0
84.9375-09-2 Methylene Chloride 19 J 20 6.8
106.17179601-23-1 m-Xylene & p-Xylene 100 4.0 1.5
100.21142-82-5 n-Heptane 190 8.0 0.70
86.17110-54-3 n-Hexane 240 8.0 1.3
128.26111-84-2 Nonane 44 8.0 2.2
106.1795-47-6 o-Xylene 31 4.0 0.76
104.15100-42-5 Styrene 4.1 4.0 1.2
165.83127-18-4 Tetrachloroethene 29 4.0 0.58
72.11109-99-9 Tetrahydrofuran ND 20 3.6
92.14108-88-3 Toluene 200 20 1.1
96.94156-60-5 trans-1,2-Dichloroethene ND 4.0 0.66
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 4.0 0.98
131.3979-01-6 Trichloroethene 560 4.0 0.66
137.3775-69-4 Trichlorofluoromethane ND 4.0 0.56
86.09108-05-4 Vinyl acetate ND 20 1.4
62.5075-01-4 Vinyl chloride ND 8.0 1.3
%RECCAS NO.LIMITSQSURROGATE
94 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 67 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-1 Lab Sample ID:140-35862-1
Matrix:RZC19P110.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 11:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 20:19
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 20 J 22 7.9
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 28 4.8
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
8.0 J 31 3.7
133.4179-00-5 1,1,2-Trichloroethane ND 22 4.2
98.9675-34-3 1,1-Dichloroethane 80 16 2.2
96.9475-35-4 1,1-Dichloroethene ND 16 2.5
120.19526-73-8 1,2,3-Trimethylbenzene 23 20 8.9
181.45120-82-1 1,2,4-Trichlorobenzene ND 150 13
120.2095-63-6 1,2,4-Trimethylbenzene 89 20 4.9
187.87106-93-4 1,2-Dibromoethane (EDB)ND 31 4.8
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 28 4.2
147.0095-50-1 1,2-Dichlorobenzene ND 48 9.4
98.96107-06-2 1,2-Dichloroethane ND 16 2.0
112.9978-87-5 1,2-Dichloropropane ND 19 2.3
120.20108-67-8 1,3,5-Trimethylbenzene 32 J 39 16
54.09106-99-0 1,3-Butadiene ND 18 2.1
147.00541-73-1 1,3-Dichlorobenzene ND 24 4.8
147.00106-46-7 1,4-Dichlorobenzene ND 24 4.8
72.1178-93-3 2-Butanone (MEK)470 59 11
100.20591-78-6 2-Hexanone ND 41 12
120.20622-96-8 4-Ethyltoluene 25 J 39 5.2
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
180 82 11
78.1171-43-2 Benzene 480 13 2.1
126.58100-44-7 Benzyl chloride ND 42 9.9
163.8375-27-4 Bromodichloromethane ND 27 5.9
252.7575-25-2 Bromoform ND 41 14
94.9474-83-9 Bromomethane ND 16 4.3
76.1475-15-0 Carbon disulfide ND 25 5.4
153.8156-23-5 Carbon tetrachloride ND 25 4.0
112.56108-90-7 Chlorobenzene ND 18 5.2
64.5275-00-3 Chloroethane ND 11 4.2
119.3867-66-3 Chloroform 6.8 J 20 3.5
FORM I TO-15
3/25/2024
9:50:51 AM
Page 68 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-1 Lab Sample ID:140-35862-1
Matrix:RZC19P110.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 11:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 20:19
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 41 6.6
96.94156-59-2 cis-1,2-Dichloroethene 190 16 2.0
110.9710061-01-5 cis-1,3-Dichloropropene ND 36 4.4
84.16110-82-7 Cyclohexane 340 28 6.4
208.28124-48-1 Dibromochloromethane ND 34 5.8
120.9175-71-8 Dichlorodifluoromethane ND 20 3.5
46.0764-17-5 Ethanol 300 190 83
88.11141-78-6 Ethyl acetate 150 140 11
106.17100-41-4 Ethylbenzene 120 17 2.9
260.7687-68-3 Hexachlorobutadiene ND 210 17
88.151634-04-4 Methyl tert-butyl ether ND 72 9.4
98.19108-87-2 Methylcyclohexane 590 CI 16 4.0
84.9375-09-2 Methylene Chloride 68 J 70 24
106.17179601-23-1 m-Xylene & p-Xylene 440 17 6.4
100.21142-82-5 n-Heptane 760 33 2.9
86.17110-54-3 n-Hexane 830 28 4.5
128.26111-84-2 Nonane 230 42 12
106.1795-47-6 o-Xylene 140 17 3.3
104.15100-42-5 Styrene 17 17 5.1
165.83127-18-4 Tetrachloroethene 190 27 3.9
72.11109-99-9 Tetrahydrofuran ND 59 11
92.14108-88-3 Toluene 750 76 4.3
96.94156-60-5 trans-1,2-Dichloroethene ND 16 2.6
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 18 4.5
131.3979-01-6 Trichloroethene 3000 22 3.6
137.3775-69-4 Trichlorofluoromethane ND 23 3.2
86.09108-05-4 Vinyl acetate ND 71 4.9
62.5075-01-4 Vinyl chloride ND 21 3.3
%RECCAS NO.LIMITSQSURROGATE
94 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 69 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-1 Lab Sample ID:140-35862-1
Matrix:RZC19P110.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 11:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 20:19
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
Number TICs Found:TIC Result Total:106912
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
5.28 T J N78-78-4 Butane, 2-methyl-100 94%
6.58 T JUnknown50
7.55 T J N107-83-5 Pentane, 2-methyl-140 91%
8.03 T J N96-14-0 Pentane, 3-methyl-100 86%
8.84 T JUnknown57
9.74 T J N96-37-7 Cyclopentane, methyl-180 94%
11.33 T J N589-34-4 Hexane, 3-methyl-72 91%
11.70 T J N2532-58-3 Cyclopentane, 1,3-dimethyl-, cis-49 97%
11.80 T JUnknown100
11.89 T J N872-56-0 Isopropylcyclobutane 77 94%
15.07 T J N111-65-9 Octane 75 91%
19.01 T J N124-18-5 Decane 69 91%
FORM I-TIC TO-15
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Lims ID:140-35862-A-1
Client ID:03072024-1
Sample Type:Client
Inject. Date:19-Mar-2024 20:19:30 ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031988-015
Misc. Info.:140-35862-a-1@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:14:39 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:14:39
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.380 9.364 0.016 90 186797 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.553 0.005 95 864412 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.422 16.433 -0.011 87 828937 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.078 0.000 91 582019 3.84
17 Ethanol 31 5.060 5.031 0.037 88 71354 3.13
23 Acetone 58 5.702 5.690 0.021 97 122044 4.78
24 Isopropyl alcohol 45 5.805 5.820 -0.005 98 7241996 116.8 E
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.484 6.479 0.016 86 2495 0.0209
31 Methylene Chloride 84 6.678 6.679 0.011 92 22864 0.3885
37 1,1-Dichloroethane 63 7.994 7.997 0.011 100 38739 0.3967
40 Hexane 56 8.587 8.586 0.016 93 188928 4.70
39 2-Butanone (MEK) 72 8.603 8.596 0.021 97 82721 3.20
42 cis-1,2-Dichloroethene 96 9.029 9.034 0.011 93 58716 0.9806
43 Ethyl acetate 43 9.245 9.234 0.027 99 91781 0.8351
44 Chloroform 83 9.390 9.391 0.016 44 3515 0.0280
46 Tetrahydrofuran 42 9.887 9.833 0.071 70 3756 0.0703
47 1,1,1-Trichloroethane 97 10.442 10.449 0.011 98 8785 0.0714
50 Cyclohexane 69 11.024 11.029 0.005 83 51177 1.98
51 Benzene 78 11.030 11.035 0.006 96 514703 3.00
56 n-Heptane 71 12.124 12.152 -0.017 89 211928 3.71
58 Trichloroethene 130 12.265 12.303 -0.027 98 908280 11.2
63 Methylcyclohexane 83 13.052 13.097 -0.032 94 300311 2.94
64 4-Methyl-2-pentanone (MIBK) 43 13.516 13.539 -0.010 94 101494 0.8556
67 Toluene 91 14.395 14.421 -0.021 93 901943 3.97
73 Tetrachloroethene 129 15.576 15.591 -0.010 97 46529 0.5699
76 Ethylbenzene 91 16.756 16.773 -0.011 99 155707 0.5317
77 m-Xylene & p-Xylene 91 16.913 16.935 -0.016 98 458479 2.00
78 n-Nonane 57 17.312 17.323 -0.005 87 109483 0.8681
80 Styrene 104 17.398 17.409 -0.006 97 13029 0.0817
81 o-Xylene 91 17.457 17.469 -0.006 99 148720 0.6231
88 4-Ethyltoluene 105 18.687 18.687 0.000 98 33933 0.1031 M
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
87 1,3,5-Trimethylbenzene 120 18.757 18.763 0.000 93 17928 0.1310
92 1,2,4-Trimethylbenzene 105 19.183 19.189 0.000 98 102017 0.3605
98 1,2,3-Trimethylbenzene 105 19.641 19.648 0.000 98 26244 0.0914
QC Flag Legend
Processing Flags
E - Exceeded Maximum Amount
Review Flags
M - Manually Integrated
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Tentatively Identified Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Lims ID:140-35862-A-1
Client ID:03072024-1
Sample Type:Client
Inject. Date:19-Mar-2024 20:19:30 ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031988-015
Misc. Info.:140-35862-a-1@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:14:39 Calib Date:06-Mar-2024 00:47:30
Tic RT Window:0.000 -0.000 Response:height
Quant By:Nearest ISTD Quant LOD:25.00000
MS Library:\\chromfs\Knoxville\Database\NIST14.L
Min. Match:85
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:14:39
Tentative Identified Compound Results
RT Height
Amount
ppb v/v
Quant
Cpnd Qual
Lib
Entry
Molecular
Formula
Mol.
Weight Flags
78-78-4 Butane, 2-methyl-
5.276 305846 2.05 1 94 722 C5H12 72
Unknown
6.581 148599 1.00 1
107-83-5 Pentane, 2-methyl-
7.552 411553 2.76 1 91 1844 C6H14 86
96-14-0 Pentane, 3-methyl-
8.026 301214 2.02 1 86 1847 C6H14 86
Unknown
8.840 168922 1.13 1
96-37-7 Cyclopentane, methyl-
9.741 538172 3.61 1 94 1512 C6H12 84
589-34-4 Hexane, 3-methyl-
11.332 333596 1.43 2 91 4040 C7H16 100
2532-58-3 Cyclopentane, 1,3-dimethyl-, cis-
11.698 228450 0.9797 2 97 3454 C7H14 98
Unknown
11.795 470561 2.02 2
872-56-0 Isopropylcyclobutane
11.893 356710 1.53 2 94 3385 C7H14 98
111-65-9 Octane
15.074 477540 1.49 3 91 7758 C8H18 114
124-18-5 Decane
19.005 440799 1.38 3 91 19650 C10H22 142
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Quantitation Compounds
Compound RT Height
Amount
ppb v/v
* 1 Chlorobromomethane (IS) 9.380 573108 3.84
* 2 1,4-Difluorobenzene 11.558 895442 3.84
* 3 Chlorobenzene-d5 (IS)16.422 1280028 4.00
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1 Worklist Smp#:15
Client ID:03072024-1
Purge Vol:500.000 mL Dil. Factor:4.0100 ALS Bottle#:10
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
Y ( X10
0
0
0
0
)
RZC19P110[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
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n
e

(IS
)(

9
.
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* 1
,4-
D
i
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o
b
e
n
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e
( 1
1
.
5
5
8
)+
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6
.
4
2
2
)+
$ 4
-
Bro
m
o
f
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(Su
r
r
)(
1
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.
0
7
2
)+
3/25/2024
9:50:51 AM
Page 75 of 864
Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Lims ID:140-35862-A-1
Client ID:03072024-1
Sample Type:Client
Inject. Date:19-Mar-2024 20:19:30 ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031988-015
Misc. Info.:140-35862-a-1@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:14:39 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:14:39
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 3.84 94.15
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
47 1,1,1-Trichloroethane, CAS: 71-55-6
30 40 50 60 70 80 90 100 110 120 130
m/z
0
4
8
12
16
20
24
28
32
Y ( X10
0
)
Raw Spec:Scan 1364(10.44)
97
99
61
63 117 11910140604496
30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1364(10.44), Qvalue=98 Sig Qvalue=98
97
99
61
63 117 11910160
30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 47 1,1,1-Trichloroethane (NIST14.L)
97
99
61
117 1196310160
30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 10.440 min.(Qvalue: 98)
9.9 10.2 10.5 10.8
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 97.0
1
0
.
4
4
2
9.9 10.2 10.5 10.8
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 99.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 61.0
1
0
.
4
4
7
9.9 10.2 10.5 10.8
Min
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 97.0
m/z 99.0
m/z 61.0
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
30 1,1,2-Trichloro-1,2,2-trifluoroethane, CAS: 76-13-1
20 40 60 80 100 120 140 160 180
m/z
0
2
4
6
8
10
Y ( X10
0
)
Raw Spec:Scan 630(6.48)
101
32 151
103
153
8559
31
68
20 40 60 80 100 120 140 160 180
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 630(6.48), Qvalue=86 Sig Qvalue=98
101
151
85 153
103
66
68
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 30 1,1,2-Trichloro-1,2,2-trifluoroethane (NIST14.L)
101
151
103
153
85
87 10531 15566
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.480 min.(Qvalue: 86)
5.9 6.2 6.5 6.8
Min
RT
0
2
4
6
8
10
Y ( X10
0
)
m/z 101.0

6
.
4
8
4
5.9 6.2 6.5 6.8
Min
RT
0
12
24
36
48
60
72
Y ( X10
)
m/z 103.0

6
.
4
9
5
5.9 6.2 6.5 6.8
Min
RT
0
13
26
39
52
65
78
Y ( X10
)
m/z 151.0

6
.
4
8
4
5.9 6.2 6.5 6.8
Min
0
2
4
6
8
10
Y ( X10
0
)
m/z 101.0
m/z 103.0
m/z 151.0
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
37 1,1-Dichloroethane, CAS: 75-34-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
)
Raw Spec:Scan 910(7.99)
57 6356
41
6543
83 85
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 910(7.99), Qvalue=100 Sig Qvalue=100
63
65
83
856135 98
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 37 1,1-Dichloroethane (NIST14.L)
63
65
8361 85 98
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.000 min.(Qvalue:100)
7.4 7.7 8.0 8.3
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 63.0

7
.
9
9
4
7.4 7.7 8.0 8.3
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 65.0

7
.
9
9
4
7.4 7.7 8.0 8.3 8.6
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 83.0

7
.
9
9
9
7.4 7.7 8.0 8.3 8.6
Min
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 63.0
m/z 65.0
m/z 83.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
98 1,2,3-Trimethylbenzene, CAS: 526-73-8
20 40 60 80 100 120 140 160
m/z
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
)
Raw Spec:Scan 3070(19.64)
105
120
41 55 7757 1199110329 121
20 40 60 80 100 120 140 160
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 3070(19.64), Qvalue=98 Sig Qvalue=98
105
120
77 91 11910351 1213965
20 40 60 80 100 120 140 160
0
2
4
6
8
10
( X10
0
)
Ref Spec: 98 1,2,3-Trimethylbenzene (NIST14.L)
105
120
77 11991391035165
20 40 60 80 100 120 140 160
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.640 min.(Qvalue: 98)
120
19.1 19.4 19.7 20.0
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 105.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 120.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
m/z 77.0
1
9
.
6
4
7
19.1 19.4 19.7 20.0
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 105.0
m/z 120.0
m/z 77.0
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Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
92 1,2,4-Trimethylbenzene, CAS: 95-63-6
20 40 60 80 100 120 140
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
0
)
Raw Spec:Scan 2985(19.18)
105
120
77 119911033951
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2985(19.18), Qvalue=98 Sig Qvalue=100
105
120
77 119911033951
20 40 60 80 100 120 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 92 1,2,4-Trimethylbenzene (NIST14.L)
105
120
77 11991395110365
20 40 60 80 100 120 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.180 min.(Qvalue: 98)
18.6 18.9 19.2 19.5
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 105.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 120.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
m/z 119.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
87 1,3,5-Trimethylbenzene, CAS: 108-67-8
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
)
Raw Spec:Scan 2906(18.76)
105
120
77 11991395710341
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2906(18.76), Qvalue=93 Sig Qvalue=91
105
120
11977913910351
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 87 1,3,5-Trimethylbenzene (NIST14.L)
105
120
119779139 12110351
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.760 min.(Qvalue: 93)
18.2 18.5 18.8 19.1
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 120.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 105.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
m/z 119.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 120.0
m/z 105.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
39 2-Butanone (MEK), CAS: 78-93-3
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)
Raw Spec:Scan 1023(8.60)
43
57
41
56 72
86
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1023(8.60), Qvalue=97 Sig Qvalue=93
43
72
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 39 2-Butanone (MEK) (NIST14.L)
43
72
57
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.600 min.(Qvalue: 97)
8.1 8.4 8.7 9.0
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 72.0

8
.
6
0
3
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 43.0

8
.
5
9
8
8.0 8.3 8.6 8.9
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 29.0

8
.
5
8
7
8.0 8.3 8.6 8.9 9.2
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 72.0
m/z 43.0
m/z 29.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
)
Raw Spec:Scan 2893(18.69)
105
120
6941 77 125
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
3
6
9
12
15
18
Y ( X10
0
)
Amdis Enhanced Spec: Scan 2893(18.69), Qvalue=98 Sig Qvalue=99
105
67
96
120
124 19366 249207
20 40 60 80 100 120 140 160 180 200 220 240 260
0
2
4
6
8
10
( X10
0
)
Ref Spec: 88 4-Ethyltoluene (NIST14.L)
105
120
91
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.700 min.(Qvalue: 98)
67
18.1 18.4 18.7 19.0
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 105.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 120.0
1
8
.
6
5
5
18.1 18.4 18.7 19.0
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 119.0
1
8
.
6
4
9
18.1 18.4 18.7 19.0
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
64 4-Methyl-2-pentanone (MIBK), CAS: 108-10-1
20 30 40 50 60 70 80 90 100 110 120
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 1934(13.52)
43
70
55
41
58
39
69 8529 100
53 71
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1934(13.52), Qvalue=94 Sig Qvalue=98
43
58
41
85 10029
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 64 4-Methyl-2-pentanone (MIBK) (NIST14.L)
43
58
41
8529 100
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.520 min.(Qvalue: 94)
58
13.0 13.3 13.6 13.9
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 43.0
1
3
.
5
1
6
13.0 13.3 13.6 13.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 58.0
1
3
.
5
2
1
13.0 13.3 13.6 13.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 57.0
1
3
.
5
1
6
13.0 13.3 13.6 13.9
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 43.0
m/z 58.0
m/z 57.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
51 Benzene, CAS: 71-43-2
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
0
)
Raw Spec:Scan 1473(11.03)
78
56 77 8441
8569
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
21
24
Y ( X10
0
)
Amdis Enhanced Spec: Scan 1473(11.03), Qvalue=96 Sig Qvalue=98
78
56
41 84
77 85
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 51 Benzene (NIST14.L)
78
77
51 52
7938
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.020 min.(Qvalue: 96)
56
10.5 10.8 11.1 11.4
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 78.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 77.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 51.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 78.0
m/z 77.0
m/z 51.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
44 Chloroform, CAS: 67-66-3
20 40 60 80 100 120 140 160 180 200
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 1169(9.39)
49 130
128
45 51 93
132957931
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1169(9.39), Qvalue=44 Sig Qvalue=12
57
41
43
85
56
6939
95
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 44 Chloroform (NIST14.L)
83
85
47
48 873582
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.420 min.(Qvalue: 44)
57
41
43
8.8 9.1 9.4 9.7
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 83.0

9
.
3
9
0
8.9 9.2 9.5 9.8
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 85.0

9
.
4
1
7
8.8 9.1 9.4 9.7
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 47.0

9
.
3
7
4
8.8 9.1 9.4 9.7 10.0
Min
0
3
6
9
12
Y ( X10
0
0
)
m/z 83.0
m/z 85.0
m/z 47.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
42 cis-1,2-Dichloroethene, CAS: 156-59-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Raw Spec:Scan 1102(9.03)
61
96
98
63
60
35 10048
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1102(9.03), Qvalue=93 Sig Qvalue=91
61
96
98
63
60
35 10048
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 cis-1,2-Dichloroethene (NIST14.L)
61
96
98
6360
1004748
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.030 min.(Qvalue: 93)
96
8.5 8.8 9.1 9.4
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 96.0

9
.
0
2
9
8.5 8.8 9.1 9.4
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 61.0

9
.
0
2
9
8.5 8.8 9.1 9.4
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 98.0

9
.
0
2
9
8.5 8.8 9.1 9.4
Min
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 96.0
m/z 61.0
m/z 98.0
3/25/2024
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
50 Cyclohexane, CAS: 110-82-7
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
Raw Spec:Scan 1472(11.02)
78
56
844177
8569
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1472(11.02), Qvalue=83 Sig Qvalue=68
56
41
84
43
39
69 85
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 50 Cyclohexane (NIST14.L)
56
84
41
55
69
39 42
8583
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.020 min.(Qvalue: 83)
43
10.5 10.8 11.1 11.4
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 69.0
1
1
.
0
2
4
10.5 10.8 11.1 11.4
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 55.0
1
1
.
0
2
4
10.5 10.8 11.1 11.4
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 41.0
1
1
.
0
1
9
10.5 10.8 11.1 11.4
Min
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 69.0
m/z 55.0
m/z 41.0
3/25/2024
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
17 Ethanol, CAS: 64-17-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
5
10
15
20
25
30
Y ( X10
0
0
)
Raw Spec:Scan 366(5.06)
31
45
46
29
43
32
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 366(5.06), Qvalue=88 Sig Qvalue=89
31
45
46
29
43
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 17 Ethanol (NIST14.L)
31
45
29
46
43
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.060 min.(Qvalue: 88)
45
4.5 4.8 5.1 5.4
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 31.0

5
.
0
6
0
4.5 4.8 5.1 5.4
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 45.0

5
.
0
6
0
4.5 4.8 5.1 5.4
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 31.0
m/z 45.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
43 Ethyl acetate, CAS: 141-78-6
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 1142(9.24)
43
29 45 61 7042 73
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1142(9.24), Qvalue=99 Sig Qvalue=100
43
29 6145 7042
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 43 Ethyl acetate (NIST14.L)
43
614529 70 88
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.240 min.(Qvalue: 99)
29
8.7 9.0 9.3 9.6
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 43.0

9
.
2
4
5
8.7 9.0 9.3 9.6
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
)
m/z 61.0

9
.
2
3
9
8.7 9.0 9.3 9.6
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 43.0
m/z 61.0
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
76 Ethylbenzene, CAS: 100-41-4
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
10
20
30
40
50
60
70
80
Y ( X10
0
0
)
Raw Spec:Scan 2535(16.76)
91
57
106
41 43 7765 78 9229
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
10
20
30
40
50
60
70
80
Y ( X10
0
0
)
Enhanced Spec:Scan 2535(16.76) Bgrd 2525(16.70), Qvalue=99 Sig Qvalue=99
91
57
106
41 43 7765 78 9229
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 76 Ethylbenzene (NIST14.L)
91
106
51 65 77 78 9239
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 2535 @ 16.756 min.(Qvalue: 99)
57
16.2 16.5 16.8 17.1
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
7
5
6
16.2 16.5 16.8 17.1
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 106.0
1
6
.
7
5
6
16.2 16.5 16.8 17.1
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 77.0
1
6
.
7
5
6
16.2 16.5 16.8 17.1
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
63 Methylcyclohexane, CAS: 108-87-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 1848(13.05)
83
55
98
41
39 42 56 69 70 82
29 6753 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1848(13.05), Qvalue=94 Sig Qvalue=97
83
55
98
41
39 42 56 69 8270
29 8453
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 63 Methylcyclohexane (NIST14.L)
83
55
41 98
42 56
69 70
39 822968 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.050 min.(Qvalue: 94)
12.5 12.8 13.1 13.4
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 83.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
0
)
m/z 55.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 98.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 83.0
m/z 55.0
m/z 98.0
3/25/2024
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
31 Methylene Chloride, CAS: 75-09-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Raw Spec:Scan 666(6.68)
49
84
86
51
4735
37
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 666(6.68), Qvalue=92 Sig Qvalue=91
49
84
86
51
4735
37
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 31 Methylene Chloride (NIST14.L)
49
84
86
51
47
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.680 min.(Qvalue: 92)
84 86
6.1 6.4 6.7 7.0
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
)
m/z 84.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 49.0

6
.
6
8
3
6.1 6.4 6.7 7.0
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 86.0

6
.
6
8
3
6.1 6.4 6.7 7.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 84.0
m/z 49.0
m/z 86.0
3/25/2024
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
77 m-Xylene & p-Xylene, CAS: 179601-23-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
0
)
Raw Spec:Scan 2564(16.91)
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2564(16.91), Qvalue=98 Sig Qvalue=98
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 77 m-Xylene & p-Xylene (DATA)
91
106
105
77 785139 9265
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.920 min.(Qvalue: 98)
106
16.4 16.7 17.0 17.3
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
9
1
3
16.4 16.7 17.0 17.3
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 106.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 77.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
3/25/2024
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
56 n-Heptane, CAS: 142-82-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)
Raw Spec:Scan 1676(12.12)
43
41 71
57
5629 70
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1676(12.12), Qvalue=89 Sig Qvalue=91
43
41 71
57
5629 70
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 56 n-Heptane (NIST14.L)
43
41
29 57 71
5639 70 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.120 min.(Qvalue: 89)
715741
11.6 11.9 12.2 12.5
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 71.0
1
2
.
1
2
4
11.6 11.9 12.2 12.5
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 43.0
1
2
.
1
2
4
11.6 11.9 12.2 12.5
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 57.0
1
2
.
1
2
4
11.6 11.9 12.2 12.5
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 71.0
m/z 43.0
m/z 57.0
3/25/2024
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
40 Hexane, CAS: 110-54-3
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 1020(8.59)
5743
41
56
29
39
86
55 72
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Enhanced Spec:Scan 1020(8.59) Bgrd 1006( 8.51), Qvalue=93 Sig Qvalue=99
57
43
56
29
39
86
55 71 72
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 40 Hexane (NIST14.L)
57
43
29
56
39 86
55
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1020 @ 8.587 min.(Qvalue: 93)
5643
8.0 8.3 8.6 8.9
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 56.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 57.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 86.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 56.0
m/z 57.0
m/z 86.0
3/25/2024
9:50:51 AM
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
78 n-Nonane, CAS: 111-84-2
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
0
)
Raw Spec:Scan 2638(17.31)
43
57
41
85
29 7156
39
84 97 9969 128
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2638(17.31), Qvalue=87 Sig Qvalue=91
43
57
41
85
29 7156
39 8455 99 128
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 78 n-Nonane (NIST14.L)
43
57
41 85712956
39 84 99
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.320 min.(Qvalue: 87)
41
57
16.8 17.1 17.4 17.7
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 57.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 43.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 85.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 57.0
m/z 43.0
m/z 85.0
3/25/2024
9:50:51 AM
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Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
81 o-Xylene, CAS: 95-47-6
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 2665(17.46)
91
106
105775139927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2665(17.46), Qvalue=99 Sig Qvalue=99
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 81 o-Xylene (NIST14.L)
91
106
105
7751 92653979
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.460 min.(Qvalue: 99)
16.9 17.2 17.5 17.8
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 91.0
1
7
.
4
5
7
16.9 17.2 17.5 17.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 106.0
1
7
.
4
5
7
16.9 17.2 17.5 17.8
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
)
m/z 77.0
1
7
.
4
5
7
16.9 17.2 17.5 17.8
Min
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
80 Styrene, CAS: 100-42-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
9
18
27
36
45
54
63
Y ( X10
0
)
Raw Spec:Scan 2654(17.40)
104
10378
51 77
39 5232 63 74 10240
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2654(17.40), Qvalue=97 Sig Qvalue=99
104
103
78
51 77
50 1025263
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 80 Styrene (NIST14.L)
104
10378
51 77
50 52 102633974
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.400 min.(Qvalue: 97)
103
16.8 17.1 17.4 17.7
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
)
m/z 104.0
1
7
.
3
9
8
16.9 17.2 17.5 17.8
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 78.0
1
7
.
4
0
4
16.9 17.2 17.5 17.8
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 103.0
1
7
.
4
0
4
16.8 17.1 17.4 17.7 18.0
Min
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 104.0
m/z 78.0
m/z 103.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
73 Tetrachloroethene, CAS: 127-18-4
20 40 60 80 100 120 140 160 180
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Raw Spec:Scan 2316(15.58)
166
164
129 131
168
94
47 96 133
5935 82
98
20 40 60 80 100 120 140 160 180
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Enhanced Spec:Scan 2316(15.58) Bgrd 2306(15.52), Qvalue=97 Sig Qvalue=99
166
164
129 131
168
94
47 96 133
5935 82
98
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 73 Tetrachloroethene (NIST14.L)
166
164
129 131
168
94
96 13347598235
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 2316 @ 15.576 min.(Qvalue: 97)
129
15.0 15.3 15.6 15.9
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 129.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 166.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 168.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 129.0
m/z 166.0
m/z 168.0
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
67 Toluene, CAS: 108-88-3
20 30 40 50 60 70 80 90 100 110 120
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 2097(14.39)
91
92
653951 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
)
Amdis Enhanced Spec: Scan 2097(14.39), Qvalue=93 Sig Qvalue=90
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 67 Toluene (NIST14.L)
91
92
653951 93
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 14.390 min.(Qvalue: 93)
13.8 14.1 14.4 14.7
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 91.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
0
)
m/z 92.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
m/z 91.0
m/z 92.0
3/25/2024
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Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
58 Trichloroethene, CAS: 79-01-6
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
6
12
18
24
30
36
Y ( X10
0
0
0
)
Raw Spec:Scan 1702(12.26)
95 130
97
60
35 6247 999459
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1702(12.26), Qvalue=98 Sig Qvalue=98
13095
97
60
35 6247 999459
20 30 40 50 60 70 80 90 100 110 120 130 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 58 Trichloroethene (NIST14.L)
130
95
97
60
6247 99943559
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.270 min.(Qvalue: 98)
95 97
11.7 12.0 12.3 12.6
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
0
)
m/z 130.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
0
)
m/z 95.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
0
)
m/z 132.0
1
2
.
2
7
0
11.7 12.0 12.3 12.6
Min
0
7
14
21
28
35
Y ( X10
0
0
0
)
m/z 130.0
m/z 95.0
m/z 132.0
3/25/2024
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Page 103 of 864
Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
68 1,1,2-Trichloroethane, CAS: 79-00-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
0
)
Raw Spec:Scan 2149(14.67)
97
55
41
11270563942
29 98836784
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2149(14.67), Qvalue=51
9755
7041 112
5642
982984
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 68 1,1,2-Trichloroethane (NIST14.L)
97
83
61 99
85
96
63
6049 101
14.2 14.5 14.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 83.0
1
4
.
6
7
5
14.2 14.5 14.8
Min
RT
0
9
18
27
36
45
Y ( X10
0
0
)
m/z 97.0
1
4
.
6
7
5
14.2 14.5 14.8
Min
RT
0
9
18
27
36
45
54
Y ( X10
)
m/z 85.0
1
4
.
6
7
0
RT Mass Response Amount
14.67 83.00 8191 0.122352
14.67 97.00 120817
14.67 85.00 441
Reviewer: CJS9, 20-Mar-2024 15:13:05 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 104 of 864
Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
57 1,2-Dichloropropane, CAS: 78-87-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
6
12
18
24
30
36
Y ( X10
0
0
0
)
Raw Spec:Scan 1702(12.26)
95 130
97
60
35 6247 999459
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1702(12.26), Qvalue=45
81
69
7941
5339
20 40 60 80 100 120 140
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 57 1,2-Dichloropropane (NIST14.L)
63
62
41
65
39 76
61 7838
11.9 12.2 12.5
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 63.0
1
2
.
2
6
5
11.9 12.2 12.5
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 62.0
1
2
.
2
6
5
11.9 12.2 12.5
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
)
m/z 65.0
1
2
.
2
6
5
RT Mass Response Amount
12.26 63.00 3174 0.050539
12.26 62.00 137590
12.26 65.00 15199
Reviewer: CJS9, 20-Mar-2024 15:12:36 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 105 of 864
Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
69 2-Hexanone, CAS: 591-78-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
0
0
)
Raw Spec:Scan 2222(15.07)
43
41 85
57
7129567039
84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2222(15.07), Qvalue=64
43
8541
57
71
29 56
7039
84 114
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 69 2-Hexanone (NIST14.L)
43
58
5741 100852971
14.6 14.9
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 58.0
1
5
.
0
6
9
14.6 14.9
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 43.0
1
5
.
0
7
4
14.6 14.9
Min
RT
0
8
16
24
32
40
Y ( X10
0
0
)
m/z 57.0
1
5
.
0
7
4
RT Mass Response Amount
15.07 58.00 4094 0.063106
15.07 43.00 197906
15.07 57.00 85994
Reviewer: CJS9, 20-Mar-2024 15:13:15 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 106 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Manual Integration/User Assign Peak Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
Signal: 1
Processing Integration Results
RT: 18.65
Area: 79176
Amount: 0.240674
Amount Units: ppb v/v
18.3 18.5 18.7 18.9
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
0
)
m/z 105.0
1
8
.
6
5
5
Manual Integration Results
RT: 18.69
Area: 33933
Amount: 0.103147
Amount Units: ppb v/v
18.3 18.5 18.7 18.9
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
0
)
m/z 105.0
1
8
.
6
8
7
Reviewer: CJS9, 20-Mar-2024 15:13:55 07:00:00 (UTC)
Audit Action: Split an Integrated Peak Audit Reason: Wrong peak
3/25/2024
9:50:51 AM
Page 107 of 864
Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
66 trans-1,3-Dichloropropene, CAS: 10061-02-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
6
12
18
24
30
36
Y ( X10
0
0
0
)
Raw Spec:Scan 2096(14.39)
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2096(14.39), Qvalue=50
43
57
5639
85
92
5529 62
6937 93
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 66 trans-1,3-Dichloropropene (NIST14.L)
75
39
77
11049
112385173
14.0 14.3 14.6
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 75.0
1
4
.
3
8
9
14.0 14.3 14.6
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 39.0
1
4
.
3
9
5
14.0 14.3 14.6
Min
RT
0
8
16
24
32
40
Y ( X10
0
)
m/z 77.0
1
4
.
3
8
9
RT Mass Response Amount
14.39 75.00 5562 0.060858
14.39 39.00 104669
14.39 77.00 10138
Reviewer: CJS9, 20-Mar-2024 15:13:01 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 108 of 864
Report Date: 20-Mar-2024 15:14:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
38 Vinyl acetate, CAS: 108-05-4
Processing Results
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 916(8.03)
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 916(8.03), Qvalue=34
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 38 Vinyl acetate (NIST14.L)
43
8642
7.6 7.9 8.2 8.5
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 43.0

8
.
0
2
6
7.6 7.9 8.2 8.5
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 42.0

8
.
0
2
6
7.6 7.9 8.2 8.5
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 86.0

8
.
0
2
6
RT Mass Response Amount
8.03 43.00 49332 0.477361
8.03 42.00 15683
8.03 86.00 7763
Reviewer: CJS9, 20-Mar-2024 15:12:17 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 109 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Butane,2-methyl-78-78-4 NIST14.L 722 C5H12 72 94
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
12
24
36
48
60
Y ( X10
0
0
)
Raw Spec: Scan 406(5.28)
43
57
29 39 56
72
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
12
24
36
48
60
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 406(5.28) Bgrd 356( 5.01)
43
57
29 39 56
72
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #722, Butane, 2-methyl- (from NIST14.L)
43
57
39 5629
72
3/25/2024
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Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
Raw Spec: Scan 648(6.58)
43
74
594229
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 648(6.58) Bgrd 616( 6.41)
43
74
594229
3/25/2024
9:50:51 AM
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Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,2-methyl-107-83-5 NIST14.L 1844 C6H14 86 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 828(7.55)
43
42
71
39 5729 70
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P110[MS SCAN Spec]:Scan 828(7.55) Bgrd 798( 7.39)
43
42
71
39 5729 70
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1844, Pentane, 2-methyl- (from NIST14.L)
43
42
41 71
29 57 70
3/25/2024
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Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,3-methyl-96-14-0 NIST14.L 1847 C6H14 86 86
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
14
28
42
56
70
Y ( X10
0
0
)
Raw Spec: Scan 916(8.03)
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
14
28
42
56
70
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 916(8.03) Bgrd 900( 7.94)
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1847, Pentane, 3-methyl- (from NIST14.L)
57
56
4129
43
39
55 71
3/25/2024
9:50:51 AM
Page 113 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
13
26
39
52
65
Y ( X10
0
0
)
Raw Spec: Scan 1067(8.84)
45
592943
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
13
26
39
52
65
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 1067(8.84) Bgrd 986( 8.40)
45
592943
3/25/2024
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Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Cyclopentane,methyl-96-37-7 NIST14.L 1512 C6H12 84 94
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)Raw Spec: Scan 1234(9.74)
56
41 69
5539
84296753
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)RZC19P110[MS SCAN Spec]:Scan 1234(9.74) Bgrd 1200( 9.56)
56
41 69
5539
84296753
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1512, Cyclopentane, methyl- (from NIST14.L)
56
41
69
39 55
842968
3/25/2024
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Page 115 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Hexane,3-methyl-589-34-4 NIST14.L 4040 C7H16 100 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
11
22
33
44
55
Y ( X10
0
0
)
Raw Spec: Scan 1529(11.33)
43
714157
29 39 55
85 10069
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
11
22
33
44
55
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 1529(11.33) Bgrd 1456(10.94)
43
714157
29 39 55
85 10069
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #4040, Hexane, 3-methyl- (from NIST14.L)
43
41
70 7157
29
39 55
3/25/2024
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Page 116 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Cyclopentane,1,3-dimethyl-,cis-2532-58-3 NIST14.L 3454 C7H14 98 97
Cyclopentane,1,3-dimethyl-2453-00-1 NIST14.L 3443 C7H14 98 95
20 30 40 50 60 70 80 90 100 110 120
m/z
0
8
16
24
32
40
Y ( X10
0
0
)
Raw Spec: Scan 1597(11.70)
70
56
41
39 6943 83712957 9853
20 30 40 50 60 70 80 90 100 110 120
m/z
0
8
16
24
32
40
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 1597(11.70) Bgrd 1456(10.94)
70
56
41
39 6943 83712957 9853
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3454, Cyclopentane, 1,3-dimethyl-, cis- (from NIST14.L)
7056
41
39
6942 8329 98575367
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3443, Cyclopentane, 1,3-dimethyl- (from NIST14.L)
7056
41 55
693942 832957 985371
3/25/2024
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Page 117 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)Raw Spec: Scan 1615(11.80)
43
41 56 8670
71
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)RZC19P110[MS SCAN Spec]:Scan 1615(11.80) Bgrd 1456(10.94)
43
41 56 8670
71
3/25/2024
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Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Isopropylcyclobutane 872-56-0 NIST14.L 3385 C7H14 98 94
Cyclopentane,1,2-dimethyl-,cis-1192-18-3 NIST14.L 3457 C7H14 98 91
Cyclopentane,1,2-dimethyl-,trans-822-50-4 NIST14.L 3465 C7H14 98 91
20 30 40 50 60 70 80 90 100 110 120
m/z
0
12
24
36
48
60
Y ( X10
0
0
)
Raw Spec: Scan 1633(11.89)
56
55 70
41
693942 988357295367
20 30 40 50 60 70 80 90 100 110 120
m/z
0
12
24
36
48
60
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 1633(11.89) Bgrd 1456(10.94)
56
55 70
41
693942 988357295367
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3385, Isopropylcyclobutane (from NIST14.L)
56
41 55
70
39 42 6929 98
5743 8353
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3457, Cyclopentane, 1,2-dimethyl-, cis- (from NIST14.L)
56 704155
4239 6929 9883574353
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3465, Cyclopentane, 1,2-dimethyl-, trans- (from NIST14.L)
56
41 55 70
694239 9829578354
3/25/2024
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Page 119 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Octane 111-65-9 NIST14.L 7758 C8H18 114 91
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)Raw Spec: Scan 2223(15.07)
43
854157
7129
39 55 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)RZC19P110[MS SCAN Spec]:Scan 2223(15.07) Bgrd 2182(14.85)
43
854157
7129
39 55 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #7758, Octane (from NIST14.L)
43
41
5729 8571395584 114
3/25/2024
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Page 120 of 864
Report Date: 20-Mar-2024 15:14:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P110.D
Injection Date:19-Mar-2024 20:19:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Decane 124-18-5 NIST14.L 19650 C10H22 142 91
Hydroxylamine,O-decyl-29812-79-1 NIST14.L 42310 C10H23NO 173 86
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
Raw Spec: Scan 2952(19.01)
5743
41
71
8529557039
105 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
RZC19P110[MS SCAN Spec]:Scan 2952(19.01) Bgrd 2752(17.93)
57
43
41
71
852956703984 105 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #19650, Decane (from NIST14.L)
43 57
41 71
29 85567039
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
m/z
0
18
36
54
72
90
Y ( X10
0
)
Entry #42310, Hydroxylamine, O-decyl- (from NIST14.L)
43
57
41 71
8555
703844 82 97
3/25/2024
9:50:51 AM
Page 121 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-1 Lab Sample ID:140-35862-1
Matrix:RZC20P107.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 11:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
10(mL)
0.32(mm)
Date Analyzed:03/20/2024 16:56
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 140 J 600 110
60.1067-63-0 Isopropyl alcohol 3500 160 19
%RECCAS NO.LIMITSQSURROGATE
102 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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Page 122 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-1 Lab Sample ID:140-35862-1
Matrix:RZC20P107.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 11:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
10(mL)
0.32(mm)
Date Analyzed:03/20/2024 16:56
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 340 J 1400 270
60.1067-63-0 Isopropyl alcohol 8500 390 47
%RECCAS NO.LIMITSQSURROGATE
102 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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9:50:51 AM
Page 123 of 864
Report Date: 21-Mar-2024 10:47:43 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P107.D
Lims ID:140-35862-A-1
Client ID:03072024-1
Sample Type:Client
Inject. Date:20-Mar-2024 16:56:30 ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031995-013
Misc. Info.:140-35862-a-1@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 10:47:42 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1675
First Level Reviewer: U3SA Date:21-Mar-2024 10:47:42
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.374 -0.005 89 241579 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.558 0.000 94 1114980 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.422 16.438 -0.016 87 1000447 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.060 -0.006 88 763519 4.18
23 Acetone 58 5.707 5.701 -0.001 95 23569 0.7132
24 Isopropyl alcohol 45 5.788 5.852 -0.071 97 1389381 17.3
37 1,1-Dichloroethane 63 7.983 7.979 -0.006 99 8523 0.0675
40 Hexane 56 8.576 8.572 -0.006 84 42026 0.8081
39 2-Butanone (MEK) 72 8.614 8.593 0.011 96 15890 0.4750
42 cis-1,2-Dichloroethene 96 9.018 9.019 -0.011 94 12657 0.1634
43 Ethyl acetate 43 9.256 9.224 0.022 100 19332 0.1360
50 Cyclohexane 69 11.024 11.019 0.000 92 10901 0.3270
51 Benzene 78 11.030 11.025 0.000 96 111680 0.5041
56 n-Heptane 71 12.124 12.140 -0.022 87 41547 0.5646
58 Trichloroethene 130 12.265 12.286 -0.027 98 192587 1.83
63 Methylcyclohexane 83 13.052 13.084 -0.038 94 63151 0.4790
67 Toluene 91 14.395 14.408 -0.027 93 180743 0.6591
73 Tetrachloroethene 129 15.576 15.577 -0.016 96 9212 0.0935
76 Ethylbenzene 91 16.762 16.751 -0.005 99 32022 0.0906
77 m-Xylene & p-Xylene 91 16.918 16.913 -0.011 98 94617 0.3423
78 n-Nonane 57 17.312 17.306 -0.011 91 22799 0.1498
81 o-Xylene 91 17.463 17.446 0.000 99 30688 0.1065
88 4-Ethyltoluene 105 18.655 18.674 -0.037 98 15494 0.0390
92 1,2,4-Trimethylbenzene 105 19.183 19.164 0.000 98 19295 0.0565
QC Flag Legend
Processing Flags
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Page 124 of 864
Report Date: 21-Mar-2024 10:47:43 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 125 of 864
Report Date: 21-Mar-2024 10:47:43 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P107.D
Injection Date:20-Mar-2024 16:56:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1 Worklist Smp#:13
Client ID:03072024-1
Purge Vol:500.000 mL Dil. Factor:4.0100 ALS Bottle#:7
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Y ( X10
0
0
0
0
)
RZC20P107[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
3
6
9
)+
* 1
,4-
D
i
f
l
u
o
r
o
b
e
n
zen
e
( 1
1
.
5
5
8
)+
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6
.
4
2
2
)+
$ 4
-
Bro
m
o
f
l
u
o
r
o
b
e
n
zen
e

(Su
r
r
)(
1
8
.
0
7
2
)+
3/25/2024
9:50:51 AM
Page 126 of 864
Report Date: 21-Mar-2024 10:47:43 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P107.D
Lims ID:140-35862-A-1
Client ID:03072024-1
Sample Type:Client
Inject. Date:20-Mar-2024 16:56:30 ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031995-013
Misc. Info.:140-35862-a-1@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 10:47:42 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1675
First Level Reviewer: U3SA Date:21-Mar-2024 10:47:42
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.18 102.34
3/25/2024
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Page 127 of 864
Report Date: 21-Mar-2024 10:47:43 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P107.D
Injection Date:20-Mar-2024 16:56:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
23 Acetone, CAS: 67-64-1
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Raw Spec:Scan 486(5.71)
43
58
42
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 486(5.71), Qvalue=95 Sig Qvalue=95
43
58
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 23 Acetone (NIST14.L)
43
58
42
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.710 min.(Qvalue: 95)
58
5.2 5.5 5.8 6.1
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 58.0

5
.
7
0
7
5.2 5.5 5.8 6.1
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 43.0

5
.
7
0
7
5.2 5.5 5.8 6.1
Min
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 58.0
m/z 43.0
3/25/2024
9:50:51 AM
Page 128 of 864
Report Date: 21-Mar-2024 10:47:43 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P107.D
Injection Date:20-Mar-2024 16:56:30 Instrument ID:MR
Lims ID:140-35862-A-1 Lab Sample ID:140-35862-1
Client ID:03072024-1
Operator ID:ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
24 Isopropyl alcohol, CAS: 67-63-0
20 40 60 80 100 120 140 160 180 200
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 501(5.79)
45
43
39
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 501(5.79), Qvalue=97 Sig Qvalue=100
45
43
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 24 Isopropyl alcohol (NIST14.L)
45
43
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.790 min.(Qvalue: 97)
5.2 5.5 5.8 6.1
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 45.0

5
.
7
8
8
5.2 5.5 5.8 6.1
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 43.0

5
.
7
8
8
5.2 5.5 5.8 6.1
Min
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
m/z 45.0
m/z 43.0
3/25/2024
9:50:51 AM
Page 129 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-2 Lab Sample ID:140-35862-2
Matrix:RZC19P111.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 12:40
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:3.95
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:05
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 4.1 4.0 1.4
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 4.0 0.69
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
0.95 J 4.0 0.47
133.4179-00-5 1,1,2-Trichloroethane ND 4.0 0.75
98.9675-34-3 1,1-Dichloroethane 23 4.0 0.53
96.9475-35-4 1,1-Dichloroethene ND 4.0 0.63
120.19526-73-8 1,2,3-Trimethylbenzene 8.3 4.0 1.8
181.45120-82-1 1,2,4-Trichlorobenzene ND 20 1.8
120.2095-63-6 1,2,4-Trimethylbenzene 30 4.0 0.99
187.87106-93-4 1,2-Dibromoethane (EDB)ND 4.0 0.61
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 4.0 0.59
147.0095-50-1 1,2-Dichlorobenzene ND 7.9 1.5
98.96107-06-2 1,2-Dichloroethane ND 4.0 0.49
112.9978-87-5 1,2-Dichloropropane ND 4.0 0.49
120.20108-67-8 1,3,5-Trimethylbenzene 11 7.9 3.2
54.09106-99-0 1,3-Butadiene ND 7.9 0.95
147.00541-73-1 1,3-Dichlorobenzene ND 4.0 0.79
147.00106-46-7 1,4-Dichlorobenzene ND 4.0 0.79
72.1178-93-3 2-Butanone (MEK)210 20 3.6
100.20591-78-6 2-Hexanone ND 9.9 2.8
120.20622-96-8 4-Ethyltoluene 8.5 7.9 1.0
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
55 20 2.8
78.1171-43-2 Benzene 110 4.0 0.65
126.58100-44-7 Benzyl chloride ND 7.9 1.9
163.8375-27-4 Bromodichloromethane ND 4.0 0.87
252.7575-25-2 Bromoform ND 4.0 1.3
94.9474-83-9 Bromomethane ND 4.0 1.1
76.1475-15-0 Carbon disulfide ND 7.9 1.7
153.8156-23-5 Carbon tetrachloride ND 4.0 0.63
112.56108-90-7 Chlorobenzene ND 4.0 1.1
64.5275-00-3 Chloroethane ND 4.0 1.6
119.3867-66-3 Chloroform 0.84 J 4.0 0.71
FORM I TO-15
3/25/2024
9:50:51 AM
Page 130 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-2 Lab Sample ID:140-35862-2
Matrix:RZC19P111.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 12:40
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:3.95
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:05
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 20 3.2
96.94156-59-2 cis-1,2-Dichloroethene 57 4.0 0.49
110.9710061-01-5 cis-1,3-Dichloropropene ND 7.9 0.95
84.16110-82-7 Cyclohexane 76 7.9 1.8
208.28124-48-1 Dibromochloromethane ND 4.0 0.67
120.9175-71-8 Dichlorodifluoromethane ND 4.0 0.69
46.0764-17-5 Ethanol 160 99 43
88.11141-78-6 Ethyl acetate 18 J 40 3.0
106.17100-41-4 Ethylbenzene 26 4.0 0.65
260.7687-68-3 Hexachlorobutadiene ND 20 1.6
88.151634-04-4 Methyl tert-butyl ether ND 20 2.6
98.19108-87-2 Methylcyclohexane 140 CI 4.0 0.99
84.9375-09-2 Methylene Chloride 9.3 J 20 6.7
106.17179601-23-1 m-Xylene & p-Xylene 92 4.0 1.4
100.21142-82-5 n-Heptane 150 7.9 0.69
86.17110-54-3 n-Hexane 170 7.9 1.2
128.26111-84-2 Nonane 65 7.9 2.2
106.1795-47-6 o-Xylene 30 4.0 0.75
104.15100-42-5 Styrene 1.8 J 4.0 1.2
165.83127-18-4 Tetrachloroethene 39 4.0 0.57
72.11109-99-9 Tetrahydrofuran 89 20 3.6
92.14108-88-3 Toluene 220 20 1.1
96.94156-60-5 trans-1,2-Dichloroethene ND 4.0 0.65
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 4.0 0.97
131.3979-01-6 Trichloroethene 690 4.0 0.65
137.3775-69-4 Trichlorofluoromethane ND 4.0 0.55
86.09108-05-4 Vinyl acetate ND 20 1.4
62.5075-01-4 Vinyl chloride ND 7.9 1.3
%RECCAS NO.LIMITSQSURROGATE
91 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 131 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-2 Lab Sample ID:140-35862-2
Matrix:RZC19P111.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 12:40
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:3.95
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:05
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 22 22 7.8
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 27 4.7
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
7.3 J 30 3.6
133.4179-00-5 1,1,2-Trichloroethane ND 22 4.1
98.9675-34-3 1,1-Dichloroethane 91 16 2.2
96.9475-35-4 1,1-Dichloroethene ND 16 2.5
120.19526-73-8 1,2,3-Trimethylbenzene 41 19 8.7
181.45120-82-1 1,2,4-Trichlorobenzene ND 150 13
120.2095-63-6 1,2,4-Trimethylbenzene 150 19 4.9
187.87106-93-4 1,2-Dibromoethane (EDB)ND 30 4.7
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 28 4.1
147.0095-50-1 1,2-Dichlorobenzene ND 47 9.3
98.96107-06-2 1,2-Dichloroethane ND 16 2.0
112.9978-87-5 1,2-Dichloropropane ND 18 2.3
120.20108-67-8 1,3,5-Trimethylbenzene 53 39 16
54.09106-99-0 1,3-Butadiene ND 17 2.1
147.00541-73-1 1,3-Dichlorobenzene ND 24 4.7
147.00106-46-7 1,4-Dichlorobenzene ND 24 4.7
72.1178-93-3 2-Butanone (MEK)630 58 10
100.20591-78-6 2-Hexanone ND 40 11
120.20622-96-8 4-Ethyltoluene 42 39 5.1
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
220 81 11
78.1171-43-2 Benzene 350 13 2.1
126.58100-44-7 Benzyl chloride ND 41 9.7
163.8375-27-4 Bromodichloromethane ND 26 5.8
252.7575-25-2 Bromoform ND 41 13
94.9474-83-9 Bromomethane ND 15 4.2
76.1475-15-0 Carbon disulfide ND 25 5.4
153.8156-23-5 Carbon tetrachloride ND 25 4.0
112.56108-90-7 Chlorobenzene ND 18 5.1
64.5275-00-3 Chloroethane ND 10 4.1
119.3867-66-3 Chloroform 4.1 J 19 3.5
FORM I TO-15
3/25/2024
9:50:51 AM
Page 132 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-2 Lab Sample ID:140-35862-2
Matrix:RZC19P111.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 12:40
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:3.95
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:05
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 41 6.5
96.94156-59-2 cis-1,2-Dichloroethene 220 16 2.0
110.9710061-01-5 cis-1,3-Dichloropropene ND 36 4.3
84.16110-82-7 Cyclohexane 260 27 6.3
208.28124-48-1 Dibromochloromethane ND 34 5.7
120.9175-71-8 Dichlorodifluoromethane ND 20 3.4
46.0764-17-5 Ethanol 310 190 82
88.11141-78-6 Ethyl acetate 63 J 140 11
106.17100-41-4 Ethylbenzene 110 17 2.8
260.7687-68-3 Hexachlorobutadiene ND 210 17
88.151634-04-4 Methyl tert-butyl ether ND 71 9.3
98.19108-87-2 Methylcyclohexane 570 CI 16 4.0
84.9375-09-2 Methylene Chloride 32 J 69 23
106.17179601-23-1 m-Xylene & p-Xylene 400 17 6.3
100.21142-82-5 n-Heptane 620 32 2.8
86.17110-54-3 n-Hexane 600 28 4.4
128.26111-84-2 Nonane 340 41 11
106.1795-47-6 o-Xylene 130 17 3.3
104.15100-42-5 Styrene 7.7 J 17 5.0
165.83127-18-4 Tetrachloroethene 260 27 3.9
72.11109-99-9 Tetrahydrofuran 260 58 10
92.14108-88-3 Toluene 830 74 4.2
96.94156-60-5 trans-1,2-Dichloroethene ND 16 2.6
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 18 4.4
131.3979-01-6 Trichloroethene 3700 21 3.5
137.3775-69-4 Trichlorofluoromethane ND 22 3.1
86.09108-05-4 Vinyl acetate ND 70 4.9
62.5075-01-4 Vinyl chloride ND 20 3.3
%RECCAS NO.LIMITSQSURROGATE
91 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 133 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-2 Lab Sample ID:140-35862-2
Matrix:RZC19P111.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 12:40
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:3.95
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:05
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
Number TICs Found:TIC Result Total:102412
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
5.27 T J N78-78-4 Butane, 2-methyl-72 91%
7.55 T J N107-83-5 Pentane, 2-methyl-110 91%
8.02 T J N96-14-0 Pentane, 3-methyl-77 87%
8.81 T JUnknown85
9.74 T J N96-37-7 Cyclopentane, methyl-130 94%
11.33 T J N589-34-4 Hexane, 3-methyl-59 91%
11.79 T JUnknown120
11.89 T J N872-56-0 Isopropylcyclobutane 55 93%
14.15 T J N592-27-8 Heptane, 2-methyl-52 97%
15.07 T J N111-65-9 Octane 85 91%
19.01 T J N124-18-5 Decane 110 90%
20.28 T J N1120-21-4 Undecane 69 96%
FORM I-TIC TO-15
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Report Date: 20-Mar-2024 15:17:30 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Lims ID:140-35862-A-2
Client ID:03072024-2
Sample Type:Client
Inject. Date:19-Mar-2024 21:05:30 ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Sample Info:140-0031988-016
Misc. Info.:140-35862-a-2@3.95
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:17:30 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:17:30
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.364 0.010 91 189419 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.553 0.005 95 880302 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.433 -0.005 88 893162 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.078 0.000 90 609168 3.73
17 Ethanol 31 5.050 5.031 0.027 90 76518 3.31
23 Acetone 58 5.691 5.690 0.010 97 131479 5.07
24 Isopropyl alcohol 45 5.799 5.820 -0.011 99 6275729 99.8 E
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.473 6.479 0.005 93 2327 0.0192
31 Methylene Chloride 84 6.678 6.679 0.011 91 11296 0.1893
37 1,1-Dichloroethane 63 7.989 7.997 0.006 100 45317 0.4576
40 Hexane 56 8.582 8.586 0.011 81 140390 3.44
39 2-Butanone (MEK) 72 8.598 8.596 0.016 99 113067 4.31
42 cis-1,2-Dichloroethene 96 9.024 9.034 0.006 93 69676 1.15
43 Ethyl acetate 43 9.250 9.234 0.032 99 39569 0.3551
44 Chloroform 83 9.385 9.391 0.011 46 2162 0.0170
46 Tetrahydrofuran 42 9.833 9.833 0.017 89 98001 1.81
47 1,1,1-Trichloroethane 97 10.437 10.449 0.006 95 10355 0.0830
50 Cyclohexane 69 11.025 11.029 0.005 76 40444 1.54
51 Benzene 78 11.030 11.035 0.006 97 391632 2.24
56 n-Heptane 71 12.125 12.152 -0.016 89 177875 3.06
58 Trichloroethene 130 12.265 12.303 -0.027 97 1166511 14.1
63 Methylcyclohexane 83 13.052 13.097 -0.032 95 299976 2.88
64 4-Methyl-2-pentanone (MIBK) 43 13.510 13.539 -0.016 97 133890 1.11
67 Toluene 91 14.395 14.421 -0.021 93 1087989 4.44
73 Tetrachloroethene 129 15.576 15.591 -0.010 97 68876 0.7829
76 Ethylbenzene 91 16.757 16.773 -0.010 98 168424 0.5338
77 m-Xylene & p-Xylene 91 16.918 16.935 -0.011 98 459329 1.86
78 n-Nonane 57 17.312 17.323 -0.005 88 177947 1.31
80 Styrene 104 17.409 17.409 0.005 95 6277 0.0365
81 o-Xylene 91 17.458 17.469 -0.005 98 157963 0.6143
88 4-Ethyltoluene 105 18.687 18.687 0.000 99 60949 0.1719 M
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
87 1,3,5-Trimethylbenzene 120 18.757 18.763 0.000 93 32414 0.2198
92 1,2,4-Trimethylbenzene 105 19.183 19.189 0.000 98 187713 0.6156
98 1,2,3-Trimethylbenzene 105 19.642 19.648 0.001 99 51938 0.1678
QC Flag Legend
Processing Flags
E - Exceeded Maximum Amount
Review Flags
M - Manually Integrated
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 20-Mar-2024 15:17:30 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Tentatively Identified Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Lims ID:140-35862-A-2
Client ID:03072024-2
Sample Type:Client
Inject. Date:19-Mar-2024 21:05:30 ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Sample Info:140-0031988-016
Misc. Info.:140-35862-a-2@3.95
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:17:30 Calib Date:06-Mar-2024 00:47:30
Tic RT Window:0.000 -0.000 Response:height
Quant By:Nearest ISTD Quant LOD:25.00000
MS Library:\\chromfs\Knoxville\Database\NIST14.L
Min. Match:85
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:17:30
Tentative Identified Compound Results
RT Height
Amount
ppb v/v
Quant
Cpnd Qual
Lib
Entry
Molecular
Formula
Mol.
Weight Flags
78-78-4 Butane, 2-methyl-
5.271 206347 1.45 1 91 722 C5H12 72
107-83-5 Pentane, 2-methyl-
7.546 309288 2.17 1 91 1844 C6H14 86
96-14-0 Pentane, 3-methyl-
8.021 222820 1.56 1 87 1847 C6H14 86
Unknown
8.808 244853 1.72 1
96-37-7 Cyclopentane, methyl-
9.741 383000 2.69 1 94 1512 C6H12 84
589-34-4 Hexane, 3-methyl-
11.332 282510 1.20 2 91 4037 C7H16 100
Unknown
11.790 551497 2.35 2
872-56-0 Isopropylcyclobutane
11.893 260349 1.11 2 93 3385 C7H14 98
592-27-8 Heptane, 2-methyl-
14.152 359447 1.06 3 97 7772 C8H18 114
111-65-9 Octane
15.074 586702 1.73 3 91 7758 C8H18 114
124-18-5 Decane
19.005 735076 2.17 3 90 19648 C10H22 142
1120-21-4 Undecane
20.283 470887 1.39 3 96 29357 C11H24 156
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Report Date: 20-Mar-2024 15:17:30 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Quantitation Compounds
Compound RT Height
Amount
ppb v/v
* 1 Chlorobromomethane (IS) 9.374 546996 3.84
* 2 1,4-Difluorobenzene 11.558 901560 3.84
* 3 Chlorobenzene-d5 (IS)16.422 1357629 4.00
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 20-Mar-2024 15:17:30 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2 Worklist Smp#:16
Client ID:03072024-2
Purge Vol:500.000 mL Dil. Factor:3.9500 ALS Bottle#:11
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
Y ( X10
0
0
0
0
)
RZC19P111[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
3
7
4
)+
* 1
,4-
D
i
f
l
u
o
r
o
b
e
n
zen
e
( 1
1
.
5
5
8
)+
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6
.
4
2
2
)+
$ 4
-
Bro
m
o
f
l
u
o
r
o
b
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n
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e

(Su
r
r
)(
1
8
.
0
7
2
)+
3/25/2024
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Page 139 of 864
Report Date: 20-Mar-2024 15:17:30 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Lims ID:140-35862-A-2
Client ID:03072024-2
Sample Type:Client
Inject. Date:19-Mar-2024 21:05:30 ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Sample Info:140-0031988-016
Misc. Info.:140-35862-a-2@3.95
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:17:30 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:17:30
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 3.73 91.46
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
47 1,1,1-Trichloroethane, CAS: 71-55-6
30 40 50 60 70 80 90 100 110 120 130
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
)
Raw Spec:Scan 1363(10.44)
97
99
61
63 119101356044
30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1363(10.44), Qvalue=95 Sig Qvalue=97
97
99
61
63 11910160
30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 47 1,1,1-Trichloroethane (NIST14.L)
97
99
61
117 1196310160
30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 10.440 min.(Qvalue: 95)
9.9 10.2 10.5 10.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 97.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
)
m/z 99.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 61.0
1
0
.
4
4
8
9.9 10.2 10.5 10.8
Min
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 97.0
m/z 99.0
m/z 61.0
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
30 1,1,2-Trichloro-1,2,2-trifluoroethane, CAS: 76-13-1
30 50 70 90 110 130 150 170
m/z
0
2
4
6
8
10
Y ( X10
0
)
Raw Spec:Scan 628(6.47)
101
151
10359
45 85
153
6647 116
30 50 70 90 110 130 150 170
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 628(6.47), Qvalue=93 Sig Qvalue=97
101
151
103
15385
66
87
30 50 70 90 110 130 150 170
0
2
4
6
8
10
( X10
0
)
Ref Spec: 30 1,1,2-Trichloro-1,2,2-trifluoroethane (NIST14.L)
101
151
103
153
85
87 105 15566
30 50 70 90 110 130 150 170
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.490 min.(Qvalue: 93)
5.9 6.2 6.5 6.8
Min
RT
0
15
30
45
60
75
90
Y ( X10
)
m/z 101.0

6
.
4
7
3
5.9 6.2 6.5 6.8
Min
RT
0
10
20
30
40
50
60
Y ( X10
)
m/z 103.0

6
.
4
8
4
5.9 6.2 6.5 6.8
Min
RT
0
13
26
39
52
65
78
Y ( X10
)
m/z 151.0

6
.
4
7
9
5.9 6.2 6.5 6.8
Min
0
15
30
45
60
75
90
Y ( X10
)
m/z 101.0
m/z 103.0
m/z 151.0
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
37 1,1-Dichloroethane, CAS: 75-34-3
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
)
Raw Spec:Scan 909(7.99)
63
57
41
65
29
834339 8555 98
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 909(7.99), Qvalue=100 Sig Qvalue=100
63
65
83 8561 9835
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 37 1,1-Dichloroethane (NIST14.L)
63
65
8361 85 98
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 7.990 min.(Qvalue:100)
7.4 7.7 8.0 8.3
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 63.0

7
.
9
8
9
7.4 7.7 8.0 8.3
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 65.0

7
.
9
9
4
7.4 7.7 8.0 8.3
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
)
m/z 83.0

7
.
9
8
9
7.4 7.7 8.0 8.3
Min
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 63.0
m/z 65.0
m/z 83.0
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
98 1,2,3-Trimethylbenzene, CAS: 526-73-8
20 40 60 80 100 120 140 160
m/z
0
5
10
15
20
25
30
Y ( X10
0
0
)
Raw Spec:Scan 3070(19.64)
105
120
41 57 77 91 11967103 121
20 40 60 80 100 120 140 160
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 3070(19.64), Qvalue=99 Sig Qvalue=98
105
120
57 77 1199110339
20 40 60 80 100 120 140 160
0
2
4
6
8
10
( X10
0
)
Ref Spec: 98 1,2,3-Trimethylbenzene (NIST14.L)
105
120
77 11991391035165
20 40 60 80 100 120 140 160
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.640 min.(Qvalue: 99)
120
19.1 19.4 19.7 20.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
6
4
2
19.1 19.4 19.7 20.0
Min
RT
0
9
18
27
36
45
Y ( X10
0
0
)
m/z 120.0
1
9
.
6
4
2
19.1 19.4 19.7 20.0
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 77.0
1
9
.
6
4
2
19.1 19.4 19.7 20.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 77.0
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
92 1,2,4-Trimethylbenzene, CAS: 95-63-6
20 40 60 80 100 120 140
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 2985(19.18)
105
120
77 119913910351
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2985(19.18), Qvalue=98 Sig Qvalue=100
105
120
77 119911033951
20 40 60 80 100 120 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 92 1,2,4-Trimethylbenzene (NIST14.L)
105
120
77 11991395110365
20 40 60 80 100 120 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.180 min.(Qvalue: 98)
18.6 18.9 19.2 19.5
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
9
18
27
36
45
Y ( X10
0
0
)
m/z 120.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 119.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
87 1,3,5-Trimethylbenzene, CAS: 108-67-8
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
5
10
15
20
25
30
35
40
Y ( X10
0
0
)
Raw Spec:Scan 2906(18.76)
105
120
77 1199139574110365
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2906(18.76), Qvalue=93 Sig Qvalue=90
105
120
77 119913910351
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 87 1,3,5-Trimethylbenzene (NIST14.L)
105
120
119779139 12110351
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.760 min.(Qvalue: 93)
18.2 18.5 18.8 19.1
Min
RT
0
9
18
27
36
45
Y ( X10
0
0
)
m/z 120.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 119.0
1
8
.
7
5
2
18.2 18.5 18.8 19.1
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 120.0
m/z 105.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
39 2-Butanone (MEK), CAS: 78-93-3
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
Raw Spec:Scan 1022(8.60)
43
57
41 7256
86
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1022(8.60), Qvalue=99 Sig Qvalue=96
43
72
5742
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 39 2-Butanone (MEK) (NIST14.L)
43
72
57
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.590 min.(Qvalue: 99)
8.0 8.3 8.6 8.9
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 72.0

8
.
5
9
8
8.0 8.3 8.6 8.9
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 43.0

8
.
5
9
3
8.0 8.3 8.6 8.9
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 29.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 72.0
m/z 43.0
m/z 29.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 2893(18.69)
105
120
6941 77 125
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2893(18.69), Qvalue=99 Sig Qvalue=98
105
120
67 77
20 40 60 80 100 120 140 160 180 200 220 240 260
0
2
4
6
8
10
( X10
0
)
Ref Spec: 88 4-Ethyltoluene (NIST14.L)
105
120
91
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.690 min.(Qvalue: 99)
120
18.1 18.4 18.7 19.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 120.0
1
8
.
6
5
5
18.1 18.4 18.7 19.0
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 119.0
1
8
.
6
5
5
18.1 18.4 18.7 19.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
64 4-Methyl-2-pentanone (MIBK), CAS: 108-10-1
20 30 40 50 60 70 80 90 100 110 120
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
0
)
Raw Spec:Scan 1933(13.51)
43
70
55 5841
39 85 1006929
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1933(13.51), Qvalue=97 Sig Qvalue=98
43
58
5741
85
10029
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 64 4-Methyl-2-pentanone (MIBK) (NIST14.L)
43
58
41
8529 100
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.510 min.(Qvalue: 97)
58
13.0 13.3 13.6 13.9
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 43.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 58.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 57.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 43.0
m/z 58.0
m/z 57.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
51 Benzene, CAS: 71-43-2
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
0
)
Raw Spec:Scan 1473(11.03)
78
56 77 8441
8569
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1473(11.03), Qvalue=97 Sig Qvalue=98
78
7756 84
39
69
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 51 Benzene (NIST14.L)
78
77
51 52
7938
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.030 min.(Qvalue: 97)
10.5 10.8 11.1 11.4
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 78.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 77.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 51.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 78.0
m/z 77.0
m/z 51.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
44 Chloroform, CAS: 67-66-3
20 40 60 80 100 120 140 160 180 200
m/z
0
12
24
36
48
60
72
84
Y ( X10
0
0
)
Raw Spec:Scan 1168(9.39)
49 130
128
51 93
95 1324579
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1168(9.39), Qvalue=46 Sig Qvalue=9
57
41
43 85
69
93
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 44 Chloroform (NIST14.L)
83
85
47
48 873582
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.420 min.(Qvalue: 46)
5741
43
8.8 9.1 9.4 9.7
Min
RT
0
2
4
6
8
10
Y ( X10
0
)
m/z 83.0

9
.
3
8
5
8.9 9.2 9.5 9.8
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
)
m/z 85.0

9
.
4
2
3
8.8 9.1 9.4 9.7
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 47.0

9
.
3
7
4
8.8 9.1 9.4 9.7 10.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 83.0
m/z 85.0
m/z 47.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
42 cis-1,2-Dichloroethene, CAS: 156-59-2
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
Y ( X10
0
0
)
Raw Spec:Scan 1101(9.02)
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1101(9.02), Qvalue=93 Sig Qvalue=91
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 cis-1,2-Dichloroethene (NIST14.L)
61
96
98
6360
10047
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.030 min.(Qvalue: 93)
96 98
8.5 8.8 9.1 9.4
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 96.0

9
.
0
2
4
8.5 8.8 9.1 9.4
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 61.0

9
.
0
2
4
8.5 8.8 9.1 9.4
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 98.0

9
.
0
2
4
8.5 8.8 9.1 9.4
Min
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 96.0
m/z 61.0
m/z 98.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
50 Cyclohexane, CAS: 110-82-7
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 1472(11.02)
78
56
41 8477
69
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1472(11.02), Qvalue=76 Sig Qvalue=70
56
43
84
39 85
57
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 50 Cyclohexane (NIST14.L)
56
84
41
55
69
39 42
8583
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.020 min.(Qvalue: 76)
43
85
41
10.5 10.8 11.1 11.4
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 69.0
1
1
.
0
2
5
10.5 10.8 11.1 11.4
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 55.0
1
1
.
0
1
9
10.5 10.8 11.1 11.4
Min
RT
0
8
16
24
32
40
Y ( X10
0
0
)
m/z 41.0
1
1
.
0
1
4
10.5 10.8 11.1 11.4
Min
0
8
16
24
32
40
Y ( X10
0
0
)
m/z 69.0
m/z 55.0
m/z 41.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
17 Ethanol, CAS: 64-17-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 364(5.05)
31
45
4629
43
32
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 364(5.05), Qvalue=90 Sig Qvalue=91
31
45
4629
43
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 17 Ethanol (NIST14.L)
31
45
29
46
43
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.050 min.(Qvalue: 90)
45
4.5 4.8 5.1 5.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 31.0

5
.
0
5
0
4.5 4.8 5.1 5.4
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 45.0

5
.
0
5
0
4.5 4.8 5.1 5.4
Min
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
m/z 31.0
m/z 45.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
43 Ethyl acetate, CAS: 141-78-6
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
)
Raw Spec:Scan 1143(9.25)
43
61 7042
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1143(9.25), Qvalue=99 Sig Qvalue=100
43
61 7042
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 43 Ethyl acetate (NIST14.L)
43
61 70 88
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.250 min.(Qvalue: 99)
8.7 9.0 9.3 9.6
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 43.0

9
.
2
5
0
8.7 9.0 9.3 9.6
Min
RT
0
8
16
24
32
40
Y ( X10
0
)
m/z 61.0

9
.
2
5
0
8.7 9.0 9.3 9.6
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 43.0
m/z 61.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
76 Ethylbenzene, CAS: 100-41-4
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
11
22
33
44
55
66
77
88
Y ( X10
0
0
)
Raw Spec:Scan 2535(16.76)
91
57
106
41 43
29 65 77 78
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2535(16.76), Qvalue=98 Sig Qvalue=100
91
57
106
41 43
29 65 77 78
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 76 Ethylbenzene (NIST14.L)
91
106
51 65 77 78 9239
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.760 min.(Qvalue: 98)
57
16.2 16.5 16.8 17.1
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
7
5
7
16.2 16.5 16.8 17.1
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 106.0
1
6
.
7
5
7
16.2 16.5 16.8 17.1
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 77.0
1
6
.
7
5
7
16.2 16.5 16.8 17.1
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
63 Methylcyclohexane, CAS: 108-87-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 1848(13.05)
83
55
9841
564239 69 70 82
29 67 8453
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1848(13.05), Qvalue=95 Sig Qvalue=97
83
55
98
41
42 5639 69 8270
29 53 84
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 63 Methylcyclohexane (NIST14.L)
83
55
41 98
42 56
69 70
39 822968 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.050 min.(Qvalue: 95)
55
12.5 12.8 13.1 13.4
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 83.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 55.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 98.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 83.0
m/z 55.0
m/z 98.0
3/25/2024
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
31 Methylene Chloride, CAS: 75-09-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
7
14
21
28
35
42
49
56
Y ( X10
0
)
Raw Spec:Scan 666(6.68)
49
84
86
51
47
32 35
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 666(6.68), Qvalue=91 Sig Qvalue=89
49
84
86
51
47
35
37
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 31 Methylene Chloride (NIST14.L)
49
84
86
51
47
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.680 min.(Qvalue: 91)
84 86
6.1 6.4 6.7 7.0
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
m/z 84.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 49.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 86.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 84.0
m/z 49.0
m/z 86.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
77 m-Xylene & p-Xylene, CAS: 179601-23-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
0
)
Raw Spec:Scan 2565(16.92)
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2565(16.92), Qvalue=98 Sig Qvalue=98
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 77 m-Xylene & p-Xylene (DATA)
91
106
105
77 785139 9265
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.920 min.(Qvalue: 98)
106
16.4 16.7 17.0 17.3
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 106.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 77.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
56 n-Heptane, CAS: 142-82-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 1676(12.12)
43
41 71
57
5629 70
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1676(12.12), Qvalue=89 Sig Qvalue=90
43
41 71
57
5629 70
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 56 n-Heptane (NIST14.L)
43
41
29 57 71
5639 70 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.130 min.(Qvalue: 89)
715741
11.6 11.9 12.2 12.5
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
0
)
m/z 71.0
1
2
.
1
2
5
11.6 11.9 12.2 12.5
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 43.0
1
2
.
1
2
5
11.6 11.9 12.2 12.5
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 57.0
1
2
.
1
2
5
11.6 11.9 12.2 12.5
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 71.0
m/z 43.0
m/z 57.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
40 Hexane, CAS: 110-54-3
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)
Raw Spec:Scan 1019(8.58)
43
57
41
56
72 86
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
Y ( X10
0
)
Amdis Enhanced Spec: Scan 1019(8.58), Qvalue=81 Sig Qvalue=100
43
57
41
56
86
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 40 Hexane (NIST14.L)
57
43
56
86
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.590 min.(Qvalue: 81)
43
8.0 8.3 8.6 8.9
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 56.0

8
.
5
8
2
8.0 8.3 8.6 8.9
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 57.0

8
.
5
8
2
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 86.0

8
.
5
7
6
8.0 8.3 8.6 8.9
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 56.0
m/z 57.0
m/z 86.0
3/25/2024
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
78 n-Nonane, CAS: 111-84-2
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)
Raw Spec:Scan 2638(17.31)
43
57
41
85
29 7156
39
84 97 9969 128
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2638(17.31), Qvalue=88 Sig Qvalue=91
43
57
41
85
29 7156
39 8455 99 128
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 78 n-Nonane (NIST14.L)
43
57
41 85712956
39 84 99
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.320 min.(Qvalue: 88)
41
57
16.8 17.1 17.4 17.7
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
0
)
m/z 57.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 43.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
)
m/z 85.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 57.0
m/z 43.0
m/z 85.0
3/25/2024
9:50:51 AM
Page 162 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
81 o-Xylene, CAS: 95-47-6
20 30 40 50 60 70 80 90 100 110 120
m/z
0
11
22
33
44
55
66
77
Y ( X10
0
0
)
Raw Spec:Scan 2665(17.46)
91
106
105
77513965 78
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2665(17.46), Qvalue=98 Sig Qvalue=99
91
106
105
77513965 78
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 81 o-Xylene (NIST14.L)
91
106
105
77516539 79 103
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.460 min.(Qvalue: 98)
16.9 17.2 17.5 17.8
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 91.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 106.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
)
m/z 77.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
80 Styrene, CAS: 100-42-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
)
Raw Spec:Scan 2656(17.41)
104
10378
773251
41 55 8367 1022969
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2656(17.41), Qvalue=95 Sig Qvalue=99
104
10378
51
77 10263
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 80 Styrene (NIST14.L)
104
10378
51 77
50 52 102633974
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.410 min.(Qvalue: 95)
16.9 17.2 17.5 17.8
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 104.0
1
7
.
4
0
9
16.8 17.1 17.4 17.7
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 78.0
1
7
.
3
9
8
16.9 17.2 17.5 17.8
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 103.0
1
7
.
4
0
4
16.8 17.1 17.4 17.7 18.0
Min
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 104.0
m/z 78.0
m/z 103.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
73 Tetrachloroethene, CAS: 127-18-4
20 40 60 80 100 120 140 160 180
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 2316(15.58)
166
164129131
16894
9647 133
5935 82
61
20 40 60 80 100 120 140 160 180
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2316(15.58), Qvalue=97 Sig Qvalue=99
166
164129131
16894
9647 13359
8235
61
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 73 Tetrachloroethene (NIST14.L)
166
164
129 131
168
94
96 13347598235
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 15.580 min.(Qvalue: 97)
129
15.0 15.3 15.6 15.9
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 129.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 166.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 168.0
1
5
.
5
7
0
15.0 15.3 15.6 15.9
Min
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 129.0
m/z 166.0
m/z 168.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
46 Tetrahydrofuran, CAS: 109-99-9
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
Y ( X10
0
0
)
Raw Spec:Scan 1251(9.83)
42
41
72
39 43
44
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1251(9.83), Qvalue=89 Sig Qvalue=95
42
41
72
39 43
44
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 46 Tetrahydrofuran (NIST14.L)
42
41 72
4339
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.830 min.(Qvalue: 89)
41
9.3 9.6 9.9 10.2
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 42.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 72.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 71.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 42.0
m/z 72.0
m/z 71.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
67 Toluene, CAS: 108-88-3
20 30 40 50 60 70 80 90 100 110 120
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
0
0
)
Raw Spec:Scan 2097(14.39)
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
)
Amdis Enhanced Spec: Scan 2097(14.39), Qvalue=93 Sig Qvalue=90
91
92
65394357 85
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 67 Toluene (NIST14.L)
91
92
653951 93
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 14.390 min.(Qvalue: 93)
13.8 14.1 14.4 14.7
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
0
)
m/z 91.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 92.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
0
8
16
24
32
40
48
Y ( X10
0
0
0
)
m/z 91.0
m/z 92.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
58 Trichloroethene, CAS: 79-01-6
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
0
0
)
Raw Spec:Scan 1702(12.26)
13095
97
60
35 6247 999459
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1702(12.26), Qvalue=97 Sig Qvalue=98
95 130
97
60
35 6247 999459
20 30 40 50 60 70 80 90 100 110 120 130 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 58 Trichloroethene (NIST14.L)
130
95
97
60
6247 99943559
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.270 min.(Qvalue: 97)
95 97 132
11.7 12.0 12.3 12.6
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
0
)
m/z 130.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
0
)
m/z 95.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
0
)
m/z 132.0
1
2
.
2
7
0
11.7 12.0 12.3 12.6
Min
0
8
16
24
32
40
48
Y ( X10
0
0
0
)
m/z 130.0
m/z 95.0
m/z 132.0
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
82 1,1,2,2-Tetrachloroethane, CAS: 79-34-5
Processing Results
20 40 60 80 100 120 140
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Raw Spec:Scan 2705(17.67)
57
43
41
69
8556
125
713929
98 995367
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2705(17.67), Qvalue=59
57
43
41
69 8556 125
713929
9953
20 40 60 80 100 120 140
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 82 1,1,2,2-Tetrachloroethane (NIST14.L)
83
85
956061 13196 133
17.5 17.8 18.1
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
)
m/z 83.0
1
7
.
6
7
3
17.5 17.8 18.1
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
m/z 85.0
1
7
.
6
7
3
17.5 17.8 18.1
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
)
m/z 96.0
RT Mass Response Amount
17.67 83.00 4355 0.022700
17.67 85.00 7387
17.79 96.00 0
Reviewer: CJS9, 20-Mar-2024 15:16:50 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 169 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
68 1,1,2-Trichloroethane, CAS: 79-00-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
0
)
Raw Spec:Scan 2149(14.68)
9755
41 1127056
39 42
29 98678384
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2149(14.68), Qvalue=51
97
55
70 11241
42
986784
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 68 1,1,2-Trichloroethane (NIST14.L)
97
83
61 99
85
96
63
6049 101
14.2 14.5 14.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 83.0
1
4
.
6
7
5
14.2 14.5 14.8
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 97.0
1
4
.
6
7
5
14.2 14.5 14.8
Min
RT
0
9
18
27
36
45
54
Y ( X10
)
m/z 85.0
1
4
.
6
7
0
RT Mass Response Amount
14.68 83.00 8388 0.116285
14.68 97.00 125915
14.67 85.00 454
Reviewer: CJS9, 20-Mar-2024 15:16:18 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 170 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
57 1,2-Dichloropropane, CAS: 78-87-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 1701(12.26)
95 130
97
60
35 6247 999459
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Amdis Enhanced Spec: Scan 1701(12.26), Qvalue=42
623547
99
59
4837 82
13684
50 66
20 40 60 80 100 120 140
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 57 1,2-Dichloropropane (NIST14.L)
63
62
41
65
39 76
61 7838
11.9 12.2 12.5
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
)
m/z 63.0
1
2
.
2
5
9
11.9 12.2 12.5
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 62.0
1
2
.
2
6
5
11.9 12.2 12.5
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 65.0
1
2
.
2
6
5
RT Mass Response Amount
12.26 63.00 4132 0.064605
12.26 62.00 179260
12.26 65.00 19170
Reviewer: CJS9, 20-Mar-2024 15:16:06 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 171 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
69 2-Hexanone, CAS: 591-78-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 2223(15.07)
43
854157
71
5629
39 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2223(15.07), Qvalue=66
43
854157
71
5629
39 84 114
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 69 2-Hexanone (NIST14.L)
43
58
5741 100852971
14.6 14.9
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 58.0
1
5
.
0
7
4
14.6 14.9
Min
RT
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 43.0
1
5
.
0
7
4
14.6 14.9
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 57.0
1
5
.
0
7
4
RT Mass Response Amount
15.07 58.00 5196 0.074333
15.07 43.00 257122
15.07 57.00 111925
Reviewer: CJS9, 20-Mar-2024 15:16:20 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 172 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Manual Integration/User Assign Peak Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
Signal: 1
Processing Integration Results
RT: 18.65
Area: 190060
Amount: 0.536188
Amount Units: ppb v/v
18.3 18.5 18.7 18.9
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
Y ( X10
0
0
)
m/z 105.0
1
8
.
6
5
5
Manual Integration Results
RT: 18.69
Area: 60949
Amount: 0.171946
Amount Units: ppb v/v
18.3 18.5 18.7 18.9
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X10
0
0
)
m/z 105.0
1
8
.
6
8
7
Reviewer: CJS9, 20-Mar-2024 15:17:17 07:00:00 (UTC)
Audit Action: Split an Integrated Peak Audit Reason: Split Peak
3/25/2024
9:50:51 AM
Page 173 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
66 trans-1,3-Dichloropropene, CAS: 10061-02-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
0
0
)
Raw Spec:Scan 2097(14.39)
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2097(14.39), Qvalue=45
43
57
85
41
56 84
29 39 55
69 9370
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 66 trans-1,3-Dichloropropene (NIST14.L)
75
39
77
11049
112385173
14.0 14.3 14.6
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 75.0
1
4
.
3
9
5
14.0 14.3 14.6
Min
RT
0
9
18
27
36
45
Y ( X10
0
0
)
m/z 39.0
1
4
.
3
8
9
14.0 14.3 14.6
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 77.0
1
4
.
3
9
5
RT Mass Response Amount
14.39 75.00 7017 0.071257
14.39 39.00 115644
14.39 77.00 12350
Reviewer: CJS9, 20-Mar-2024 15:16:15 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 174 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Butane,2-methyl-78-78-4 NIST14.L 722 C5H12 72 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
8
16
24
32
40
Y ( X10
0
0
)
Raw Spec: Scan 405(5.27)
43
57
3929 56
7244
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
8
16
24
32
40
Y ( X10
0
0
)
RZC19P111[MS SCAN Spec]:Scan 405(5.27) Bgrd 334( 4.89)
43
57
3929 56
72
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #722, Butane, 2-methyl- (from NIST14.L)
43
57
39 5629
72
3/25/2024
9:50:51 AM
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Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,2-methyl-107-83-5 NIST14.L 1844 C6H14 86 91
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
16
32
48
64
80
Y ( X10
0
0
)
Raw Spec: Scan 827(7.55)
43
42
71
39 5729 70
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
16
32
48
64
80
Y ( X10
0
0
)
RZC19P111[MS SCAN Spec]:Scan 827(7.55) Bgrd 756( 7.16)
43
42
71
39 5729 70
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1844, Pentane, 2-methyl- (from NIST14.L)
43
42
41 71
29 57 70
3/25/2024
9:50:51 AM
Page 176 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,3-methyl-96-14-0 NIST14.L 1847 C6H14 86 87
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
10
20
30
40
50
Y ( X10
0
0
)
Raw Spec: Scan 915(8.02)
57
41
29
4339
63 71
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
10
20
30
40
50
Y ( X10
0
0
)
RZC19P111[MS SCAN Spec]:Scan 915(8.02) Bgrd 756( 7.16)
57
41
29
4339
63 71
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1847, Pentane, 3-methyl- (from NIST14.L)
57
56
4129
43
39
55 71
3/25/2024
9:50:51 AM
Page 177 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)Raw Spec: Scan 1061(8.81)
45
592943
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)RZC19P111[MS SCAN Spec]:Scan 1061(8.81) Bgrd 954( 8.23)
45
592943
3/25/2024
9:50:51 AM
Page 178 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Cyclopentane,methyl-96-37-7 NIST14.L 1512 C6H12 84 94
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 1234(9.74)
56
41 69
5539
84672953
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P111[MS SCAN Spec]:Scan 1234(9.74) Bgrd 1126( 9.16)
56
41 69
5539
84672953
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1512, Cyclopentane, methyl- (from NIST14.L)
56
41
69
39 55
842968
3/25/2024
9:50:51 AM
Page 179 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Hexane,3-methyl-589-34-4 NIST14.L 4037 C7H16 100 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
10
20
30
40
50
Y ( X10
0
0
)
Raw Spec: Scan 1529(11.33)
43
714157
29
5539
85 100
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
10
20
30
40
50
Y ( X10
0
0
)
RZC19P111[MS SCAN Spec]:Scan 1529(11.33) Bgrd 1388(10.57)
43
714157
29
5539
85 100
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #4037, Hexane, 3-methyl- (from NIST14.L)
43
7157
41
29
5539 85
3/25/2024
9:50:51 AM
Page 180 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
4
8
12
16
20
Y ( X10
0
0
0
)Raw Spec: Scan 1614(11.79)
43
41 865771
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
4
8
12
16
20
Y ( X10
0
0
0
)RZC19P111[MS SCAN Spec]:Scan 1614(11.79) Bgrd 1388(10.57)
43
41 865771
3/25/2024
9:50:51 AM
Page 181 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Isopropylcyclobutane 872-56-0 NIST14.L 3385 C7H14 98 93
Cyclopentane,1,2-dimethyl-,cis-1192-18-3 NIST14.L 3457 C7H14 98 91
Cyclopentane,1,2-dimethyl-2452-99-5 NIST14.L 3440 C7H14 98 91
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
9
18
27
36
45
Y ( X10
0
0
)
Raw Spec: Scan 1633(11.89)
56
55 70
41
693942 988357295367
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
9
18
27
36
45
Y ( X10
0
0
)
RZC19P111[MS SCAN Spec]:Scan 1633(11.89) Bgrd 1388(10.57)
56
55 70
41
693942 988357295367
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3385, Isopropylcyclobutane (from NIST14.L)
56
41 55
70
39 42 6929 98
5743 8353
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3457, Cyclopentane, 1,2-dimethyl-, cis- (from NIST14.L)
56 704155
4239 6929 9883574353
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #3440, Cyclopentane, 1,2-dimethyl- (from NIST14.L)
56
55 7041
6942
39 57 98298354
3/25/2024
9:50:51 AM
Page 182 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Heptane,2-methyl-592-27-8 NIST14.L 7772 C8H18 114 97
20 30 40 50 60 70 80 90 100 110 120
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
Raw Spec: Scan 2052(14.15)
5743
41
70 9929395571
114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
RZC19P111[MS SCAN Spec]:Scan 2052(14.15) Bgrd 1748(12.51)
5743
41
70 9939297155
114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #7772, Heptane, 2-methyl- (from NIST14.L)
5743
42
29 70 99713955 114
3/25/2024
9:50:51 AM
Page 183 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Octane 111-65-9 NIST14.L 7758 C8H18 114 91
20 30 40 50 60 70 80 90 100 110 120
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 2223(15.07)
43
854157
71
29 5539 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P111[MS SCAN Spec]:Scan 2223(15.07) Bgrd 1748(12.51)
43
854157
71
29 5539 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #7758, Octane (from NIST14.L)
43
41
5729 8571395584 114
3/25/2024
9:50:51 AM
Page 184 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Decane 124-18-5 NIST14.L 19648 C10H22 142 90
Hydroxylamine,O-decyl-29812-79-1 NIST14.L 42310 C10H23NO 173 86
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 2952(19.01)
57
43
41
71
8529567084 99 142105
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P111[MS SCAN Spec]:Scan 2952(19.01) Bgrd 2752(17.93)
57
43
41
71
8529567084 99 142105
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #19648, Decane (from NIST14.L)
57
43
71
85562970
99 142
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
18
36
54
72
90
Y ( X10
0
)
Entry #42310, Hydroxylamine, O-decyl- (from NIST14.L)
43
57
41 71
8555
703844 82 97
3/25/2024
9:50:51 AM
Page 185 of 864
Report Date: 20-Mar-2024 15:17:31 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P111.D
Injection Date:19-Mar-2024 21:05:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:11 Worklist Smp#:16
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Undecane 1120-21-4 NIST14.L 29357 C11H24 156 96
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
16
32
48
64
80
Y ( X10
0
0
)
Raw Spec: Scan 3189(20.28)
5743
41 71
85295570 1198498
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
16
32
48
64
80
Y ( X10
0
0
)
RZC19P111[MS SCAN Spec]:Scan 3189(20.28) Bgrd 3118(19.90)
5743
41 71
85295570 1198498 156
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #29357, Undecane (from NIST14.L)
57
43
71
8556297084 98 15699
3/25/2024
9:50:51 AM
Page 186 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-2 Lab Sample ID:140-35862-2
Matrix:RZC20P108.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 12:40
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:3.95
Level: (low/med)Low
10(mL)
0.32(mm)
Date Analyzed:03/20/2024 17:43
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 180 J 590 110
60.1067-63-0 Isopropyl alcohol 3300 160 19
%RECCAS NO.LIMITSQSURROGATE
103 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 187 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-2 Lab Sample ID:140-35862-2
Matrix:RZC20P108.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 12:40
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:3.95
Level: (low/med)Low
10(mL)
0.32(mm)
Date Analyzed:03/20/2024 17:43
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 420 J 1400 260
60.1067-63-0 Isopropyl alcohol 8000 390 47
%RECCAS NO.LIMITSQSURROGATE
103 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 188 of 864
Report Date: 21-Mar-2024 10:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P108.D
Lims ID:140-35862-A-2
Client ID:03072024-2
Sample Type:Client
Inject. Date:20-Mar-2024 17:43:30 ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:3.9500
Sample Info:140-0031995-014
Misc. Info.:140-35862-a-2@3.95
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 10:49:20 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1675
First Level Reviewer: U3SA Date:21-Mar-2024 10:49:20
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.374 0.000 87 243314 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.558 0.000 94 1140850 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.427 16.438 -0.011 87 1042390 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.060 -0.006 88 804376 4.22
23 Acetone 58 5.707 5.701 -0.001 95 29813 0.8957
24 Isopropyl alcohol 45 5.794 5.852 -0.065 98 1335302 16.5
37 1,1-Dichloroethane 63 7.999 7.979 0.010 98 10010 0.0787
40 Hexane 56 8.582 8.572 0.000 84 31612 0.6035
39 2-Butanone (MEK) 72 8.614 8.593 0.011 98 22811 0.6771
42 cis-1,2-Dichloroethene 96 9.024 9.019 -0.005 94 15238 0.1954
43 Ethyl acetate 43 9.272 9.224 0.038 99 8686 0.0607
46 Tetrahydrofuran 42 9.865 9.827 0.027 89 19583 0.2813
50 Cyclohexane 69 11.024 11.019 0.000 93 8786 0.2575
51 Benzene 78 11.035 11.025 0.005 97 86489 0.3816
56 n-Heptane 71 12.124 12.140 -0.022 88 37086 0.4926
58 Trichloroethene 130 12.270 12.286 -0.022 98 255797 2.38
63 Methylcyclohexane 83 13.052 13.084 -0.038 94 56810 0.4212
67 Toluene 91 14.395 14.408 -0.027 93 198757 0.6956
73 Tetrachloroethene 129 15.581 15.577 -0.011 96 13432 0.1308
76 Ethylbenzene 91 16.762 16.751 -0.005 98 32354 0.0879
77 m-Xylene & p-Xylene 91 16.918 16.913 -0.011 98 91606 0.3181
78 n-Nonane 57 17.317 17.306 -0.006 88 35197 0.2219
81 o-Xylene 91 17.463 17.446 0.000 98 31255 0.1041
92 1,2,4-Trimethylbenzene 105 19.183 19.164 0.000 98 36934 0.1038
QC Flag Legend
Processing Flags
3/25/2024
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Page 189 of 864
Report Date: 21-Mar-2024 10:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 190 of 864
Report Date: 21-Mar-2024 10:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P108.D
Injection Date:20-Mar-2024 17:43:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2 Worklist Smp#:14
Client ID:03072024-2
Purge Vol:500.000 mL Dil. Factor:3.9500 ALS Bottle#:8
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Y ( X10
0
0
0
0
)
RZC20P108[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
3
7
4
)+
* 1
,4-
D
i
f
l
u
o
r
o
b
e
n
zen
e
( 1
1
.
5
5
8
)+
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6
.
4
2
7
)+
$ 4
-
Bro
m
o
f
l
u
o
r
o
b
e
n
zen
e

(Su
r
r
)(
1
8
.
0
7
2
)+
3/25/2024
9:50:51 AM
Page 191 of 864
Report Date: 21-Mar-2024 10:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P108.D
Lims ID:140-35862-A-2
Client ID:03072024-2
Sample Type:Client
Inject. Date:20-Mar-2024 17:43:30 ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:3.9500
Sample Info:140-0031995-014
Misc. Info.:140-35862-a-2@3.95
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 10:49:20 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1675
First Level Reviewer: U3SA Date:21-Mar-2024 10:49:20
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.22 103.48
3/25/2024
9:50:51 AM
Page 192 of 864
Report Date: 21-Mar-2024 10:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P108.D
Injection Date:20-Mar-2024 17:43:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
23 Acetone, CAS: 67-64-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 486(5.71)
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 486(5.71), Qvalue=95 Sig Qvalue=96
43
58
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
0
2
4
6
8
10
( X10
0
)
Ref Spec: 23 Acetone (NIST14.L)
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.710 min.(Qvalue: 95)
58
5.2 5.5 5.8 6.1
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 58.0

5
.
7
0
7
5.2 5.5 5.8 6.1
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 43.0

5
.
7
0
7
5.2 5.5 5.8 6.1
Min
0
11
22
33
44
55
66
77
Y ( X10
0
0
)
m/z 58.0
m/z 43.0
3/25/2024
9:50:51 AM
Page 193 of 864
Report Date: 21-Mar-2024 10:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P108.D
Injection Date:20-Mar-2024 17:43:30 Instrument ID:MR
Lims ID:140-35862-A-2 Lab Sample ID:140-35862-2
Client ID:03072024-2
Operator ID:ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:3.9500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
24 Isopropyl alcohol, CAS: 67-63-0
20 40 60 80 100 120 140 160 180 200
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 502(5.79)
45
43
39
20 40 60 80 100 120 140 160 180 200
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Enhanced Spec:Scan 502(5.79) Bgrd 492( 5.74), Qvalue=98 Sig Qvalue=100
45
43
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 24 Isopropyl alcohol (NIST14.L)
45
43
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 502 @ 5.794 min.(Qvalue: 98)
5.2 5.5 5.8 6.1
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 45.0

5
.
7
9
4
5.2 5.5 5.8 6.1
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 43.0

5
.
7
9
4
5.2 5.5 5.8 6.1
Min
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
m/z 45.0
m/z 43.0
3/25/2024
9:50:51 AM
Page 194 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-3 Lab Sample ID:140-35862-3
Matrix:RZC19P112.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 13:55
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.16
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:50
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 3.3 J 4.2 1.5
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 4.2 0.73
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
0.70 J 4.2 0.50
133.4179-00-5 1,1,2-Trichloroethane ND 4.2 0.79
98.9675-34-3 1,1-Dichloroethane 18 4.2 0.56
96.9475-35-4 1,1-Dichloroethene ND 4.2 0.67
120.19526-73-8 1,2,3-Trimethylbenzene 9.8 4.2 1.9
181.45120-82-1 1,2,4-Trichlorobenzene ND 21 1.9
120.2095-63-6 1,2,4-Trimethylbenzene 35 4.2 1.0
187.87106-93-4 1,2-Dibromoethane (EDB)ND 4.2 0.64
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 4.2 0.62
147.0095-50-1 1,2-Dichlorobenzene ND 8.3 1.6
98.96107-06-2 1,2-Dichloroethane ND 4.2 0.52
112.9978-87-5 1,2-Dichloropropane ND 4.2 0.52
120.20108-67-8 1,3,5-Trimethylbenzene 13 8.3 3.3
54.09106-99-0 1,3-Butadiene ND 8.3 1.0
147.00541-73-1 1,3-Dichlorobenzene ND 4.2 0.83
147.00106-46-7 1,4-Dichlorobenzene ND 4.2 0.83
72.1178-93-3 2-Butanone (MEK)200 21 3.7
100.20591-78-6 2-Hexanone ND 10 2.9
120.20622-96-8 4-Ethyltoluene 9.8 8.3 1.1
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
42 21 2.9
78.1171-43-2 Benzene 99 4.2 0.69
126.58100-44-7 Benzyl chloride ND 8.3 2.0
163.8375-27-4 Bromodichloromethane ND 4.2 0.92
252.7575-25-2 Bromoform ND 4.2 1.4
94.9474-83-9 Bromomethane ND 4.2 1.1
76.1475-15-0 Carbon disulfide ND 8.3 1.8
153.8156-23-5 Carbon tetrachloride ND 4.2 0.67
112.56108-90-7 Chlorobenzene ND 4.2 1.2
64.5275-00-3 Chloroethane ND 4.2 1.6
119.3867-66-3 Chloroform 0.80 J 4.2 0.75
FORM I TO-15
3/25/2024
9:50:51 AM
Page 195 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-3 Lab Sample ID:140-35862-3
Matrix:RZC19P112.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 13:55
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.16
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:50
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 21 3.3
96.94156-59-2 cis-1,2-Dichloroethene 44 4.2 0.52
110.9710061-01-5 cis-1,3-Dichloropropene ND 8.3 1.0
84.16110-82-7 Cyclohexane 62 8.3 1.9
208.28124-48-1 Dibromochloromethane ND 4.2 0.71
120.9175-71-8 Dichlorodifluoromethane ND 4.2 0.73
46.0764-17-5 Ethanol 170 100 46
88.11141-78-6 Ethyl acetate 13 J 42 3.1
106.17100-41-4 Ethylbenzene 25 4.2 0.69
260.7687-68-3 Hexachlorobutadiene ND 21 1.7
88.151634-04-4 Methyl tert-butyl ether ND 21 2.7
98.19108-87-2 Methylcyclohexane 110 CI 4.2 1.0
84.9375-09-2 Methylene Chloride 9.0 J 21 7.1
106.17179601-23-1 m-Xylene & p-Xylene 91 4.2 1.5
100.21142-82-5 n-Heptane 130 8.3 0.73
86.17110-54-3 n-Hexane 140 8.3 1.3
128.26111-84-2 Nonane 63 8.3 2.3
106.1795-47-6 o-Xylene 31 4.2 0.79
104.15100-42-5 Styrene 1.6 J 4.2 1.2
165.83127-18-4 Tetrachloroethene 37 4.2 0.60
72.11109-99-9 Tetrahydrofuran 130 21 3.7
92.14108-88-3 Toluene 190 21 1.2
96.94156-60-5 trans-1,2-Dichloroethene ND 4.2 0.69
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 4.2 1.0
131.3979-01-6 Trichloroethene 600 4.2 0.69
137.3775-69-4 Trichlorofluoromethane ND 4.2 0.58
86.09108-05-4 Vinyl acetate ND 21 1.5
62.5075-01-4 Vinyl chloride ND 8.3 1.4
%RECCAS NO.LIMITSQSURROGATE
99 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 196 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-3 Lab Sample ID:140-35862-3
Matrix:RZC19P112.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 13:55
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.16
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:50
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 18 J 23 8.2
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 29 5.0
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
5.3 J 32 3.8
133.4179-00-5 1,1,2-Trichloroethane ND 23 4.3
98.9675-34-3 1,1-Dichloroethane 72 17 2.3
96.9475-35-4 1,1-Dichloroethene ND 16 2.6
120.19526-73-8 1,2,3-Trimethylbenzene 48 20 9.2
181.45120-82-1 1,2,4-Trichlorobenzene ND 150 14
120.2095-63-6 1,2,4-Trimethylbenzene 170 20 5.1
187.87106-93-4 1,2-Dibromoethane (EDB)ND 32 5.0
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 29 4.4
147.0095-50-1 1,2-Dichlorobenzene ND 50 9.8
98.96107-06-2 1,2-Dichloroethane ND 17 2.1
112.9978-87-5 1,2-Dichloropropane ND 19 2.4
120.20108-67-8 1,3,5-Trimethylbenzene 63 41 16
54.09106-99-0 1,3-Butadiene ND 18 2.2
147.00541-73-1 1,3-Dichlorobenzene ND 25 5.0
147.00106-46-7 1,4-Dichlorobenzene ND 25 5.0
72.1178-93-3 2-Butanone (MEK)590 61 11
100.20591-78-6 2-Hexanone ND 43 12
120.20622-96-8 4-Ethyltoluene 48 41 5.4
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
170 85 12
78.1171-43-2 Benzene 320 13 2.2
126.58100-44-7 Benzyl chloride ND 43 10
163.8375-27-4 Bromodichloromethane ND 28 6.1
252.7575-25-2 Bromoform ND 43 14
94.9474-83-9 Bromomethane ND 16 4.4
76.1475-15-0 Carbon disulfide ND 26 5.6
153.8156-23-5 Carbon tetrachloride ND 26 4.2
112.56108-90-7 Chlorobenzene ND 19 5.4
64.5275-00-3 Chloroethane ND 11 4.3
119.3867-66-3 Chloroform 3.9 J 20 3.7
FORM I TO-15
3/25/2024
9:50:51 AM
Page 197 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-3 Lab Sample ID:140-35862-3
Matrix:RZC19P112.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 13:55
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.16
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:50
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 43 6.9
96.94156-59-2 cis-1,2-Dichloroethene 170 16 2.1
110.9710061-01-5 cis-1,3-Dichloropropene ND 38 4.5
84.16110-82-7 Cyclohexane 210 29 6.7
208.28124-48-1 Dibromochloromethane ND 35 6.0
120.9175-71-8 Dichlorodifluoromethane ND 21 3.6
46.0764-17-5 Ethanol 320 200 86
88.11141-78-6 Ethyl acetate 47 J 150 11
106.17100-41-4 Ethylbenzene 110 18 3.0
260.7687-68-3 Hexachlorobutadiene ND 220 18
88.151634-04-4 Methyl tert-butyl ether ND 75 9.7
98.19108-87-2 Methylcyclohexane 460 CI 17 4.2
84.9375-09-2 Methylene Chloride 31 J 72 25
106.17179601-23-1 m-Xylene & p-Xylene 390 18 6.6
100.21142-82-5 n-Heptane 520 34 3.0
86.17110-54-3 n-Hexane 480 29 4.6
128.26111-84-2 Nonane 330 44 12
106.1795-47-6 o-Xylene 130 18 3.4
104.15100-42-5 Styrene 6.8 J 18 5.3
165.83127-18-4 Tetrachloroethene 250 28 4.1
72.11109-99-9 Tetrahydrofuran 390 61 11
92.14108-88-3 Toluene 720 78 4.5
96.94156-60-5 trans-1,2-Dichloroethene ND 16 2.7
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 19 4.6
131.3979-01-6 Trichloroethene 3200 22 3.7
137.3775-69-4 Trichlorofluoromethane ND 23 3.3
86.09108-05-4 Vinyl acetate ND 73 5.1
62.5075-01-4 Vinyl chloride ND 21 3.5
%RECCAS NO.LIMITSQSURROGATE
99 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-3 Lab Sample ID:140-35862-3
Matrix:RZC19P112.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 13:55
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.16
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 21:50
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
Number TICs Found:TIC Result Total:98710
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
5.27 T J N78-78-4 Butane, 2-methyl-61 91%
7.55 T J N107-83-5 Pentane, 2-methyl-93 91%
8.02 T J N96-14-0 Pentane, 3-methyl-69 87%
8.59 T JUnknown200
8.81 T JUnknown84
9.74 T J N96-37-7 Cyclopentane, methyl-120 94%
11.79 T JUnknown80
15.07 T J N111-65-9 Octane 77 91%
19.01 T J N124-18-5 Decane 120 91%
20.28 T J N1120-21-4 Undecane 83 94%
FORM I-TIC TO-15
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Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Lims ID:140-35862-A-3
Client ID:03072024-3
Sample Type:Client
Inject. Date:19-Mar-2024 21:50:30 ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Sample Info:140-0031988-017
Misc. Info.:140-35862-a-3@4.16
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:24:55 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:24:55
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.364 0.010 88 197722 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.553 0.005 95 917397 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.422 16.433 -0.011 87 838314 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.078 0.000 90 620848 4.05
17 Ethanol 31 5.050 5.031 0.027 92 79549 3.30
23 Acetone 58 5.691 5.690 0.010 97 151823 5.61
24 Isopropyl alcohol 45 5.799 5.820 -0.011 98 3607534 55.0 E
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.473 6.479 0.005 92 1696 0.0134
31 Methylene Chloride 84 6.678 6.679 0.011 90 10738 0.1724
37 1,1-Dichloroethane 63 7.989 7.997 0.006 100 35327 0.3418
40 Hexane 56 8.576 8.586 0.005 88 111385 2.62
39 2-Butanone (MEK) 72 8.598 8.596 0.016 99 104554 3.82
42 cis-1,2-Dichloroethene 96 9.024 9.034 0.006 93 53725 0.8477
43 Ethyl acetate 43 9.250 9.234 0.032 99 29328 0.2521
44 Chloroform 83 9.380 9.391 0.006 35 2058 0.0155
46 Tetrahydrofuran 42 9.827 9.833 0.011 91 143161 2.53
47 1,1,1-Trichloroethane 97 10.437 10.449 0.006 97 8164 0.0627
50 Cyclohexane 69 11.019 11.029 0.000 91 32646 1.19
51 Benzene 78 11.030 11.035 0.006 96 346665 1.90
56 n-Heptane 71 12.119 12.152 -0.022 89 147411 2.43
58 Trichloroethene 130 12.265 12.303 -0.027 97 991348 11.5
63 Methylcyclohexane 83 13.052 13.097 -0.032 94 239192 2.21
64 4-Methyl-2-pentanone (MIBK) 43 13.510 13.539 -0.016 92 102288 0.8125
67 Toluene 91 14.389 14.421 -0.027 93 845127 3.68
73 Tetrachloroethene 129 15.570 15.591 -0.016 96 59053 0.7152
76 Ethylbenzene 91 16.757 16.773 -0.010 98 142630 0.4816
77 m-Xylene & p-Xylene 91 16.918 16.935 -0.011 98 404943 1.75
78 n-Nonane 57 17.312 17.323 -0.005 87 154982 1.22
80 Styrene 104 17.404 17.409 0.000 94 4986 0.0309
81 o-Xylene 91 17.458 17.469 -0.005 99 141859 0.5877
88 4-Ethyltoluene 105 18.687 18.687 0.000 99 62874 0.1890 M
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Report Date: 20-Mar-2024 15:24:55 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
87 1,3,5-Trimethylbenzene 120 18.757 18.763 0.000 93 34281 0.2477
92 1,2,4-Trimethylbenzene 105 19.183 19.189 0.000 98 194503 0.6797
98 1,2,3-Trimethylbenzene 105 19.641 19.648 0.000 99 54762 0.1885
QC Flag Legend
Processing Flags
E - Exceeded Maximum Amount
Review Flags
M - Manually Integrated
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 20-Mar-2024 15:24:55 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Tentatively Identified Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Lims ID:140-35862-A-3
Client ID:03072024-3
Sample Type:Client
Inject. Date:19-Mar-2024 21:50:30 ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Sample Info:140-0031988-017
Misc. Info.:140-35862-a-3@4.16
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:24:55 Calib Date:06-Mar-2024 00:47:30
Tic RT Window:0.000 -0.000 Response:height
Quant By:Nearest ISTD Quant LOD:25.00000
MS Library:\\chromfs\Knoxville\Database\NIST14.L
Min. Match:85
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:24:55
Tentative Identified Compound Results
RT Height
Amount
ppb v/v
Quant
Cpnd Qual
Lib
Entry
Molecular
Formula
Mol.
Weight Flags
78-78-4 Butane, 2-methyl-
5.271 162596 1.17 1 91 722 C5H12 72
107-83-5 Pentane, 2-methyl-
7.546 248636 1.79 1 91 1844 C6H14 86
96-14-0 Pentane, 3-methyl-
8.021 183348 1.32 1 87 1847 C6H14 86
Unknown
8.587 536529 3.86 1
Unknown
8.814 224554 1.61 1
96-37-7 Cyclopentane, methyl-
9.736 312083 2.24 1 94 1512 C6H12 84
Unknown
11.790 382747 1.54 2
111-65-9 Octane
15.074 480273 1.49 3 91 7758 C8H18 114
124-18-5 Decane
19.005 739734 2.29 3 91 19650 C10H22 142
1120-21-4 Undecane
20.283 514899 1.59 3 94 29357 C11H24 156
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Quantitation Compounds
Compound RT Height
Amount
ppb v/v
* 1 Chlorobromomethane (IS) 9.374 534343 3.84
* 2 1,4-Difluorobenzene 11.558 952647 3.84
* 3 Chlorobenzene-d5 (IS)16.422 1292398 4.00
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 20-Mar-2024 15:24:55 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3 Worklist Smp#:17
Client ID:03072024-3
Purge Vol:500.000 mL Dil. Factor:4.1600 ALS Bottle#:12
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
Y ( X10
0
0
0
0
)
RZC19P112[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
3
7
4
)+
* 1
,4-
D
i
f
l
u
o
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o
b
e
n
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e
( 1
1
.
5
5
8
)+
* C
h
l
o
r
o
b
e
n
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e
-
d5
(IS
)(
1
6
.
4
2
2
)+
$ 4
-
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m
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(Su
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r
)(
1
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.
0
7
2
)+
3/25/2024
9:50:51 AM
Page 204 of 864
Report Date: 20-Mar-2024 15:24:55 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Lims ID:140-35862-A-3
Client ID:03072024-3
Sample Type:Client
Inject. Date:19-Mar-2024 21:50:30 ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Sample Info:140-0031988-017
Misc. Info.:140-35862-a-3@4.16
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:24:55 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:24:55
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.05 99.31
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Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
47 1,1,1-Trichloroethane, CAS: 71-55-6
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
)
Raw Spec:Scan 1363(10.44)
97
99
61
32
40 63 101 119 207
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1363(10.44), Qvalue=97 Sig Qvalue=97
97
99
61
63 117 1193560
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 47 1,1,1-Trichloroethane (NIST14.L)
97
99
61
117 11963
6035
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 10.440 min.(Qvalue: 97)
9.9 10.2 10.5 10.8
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 97.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
)
m/z 99.0
1
0
.
4
4
7
9.9 10.2 10.5 10.8
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 61.0
1
0
.
4
4
2
9.9 10.2 10.5 10.8
Min
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 97.0
m/z 99.0
m/z 61.0
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Report Date: 20-Mar-2024 15:24:55 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
30 1,1,2-Trichloro-1,2,2-trifluoroethane, CAS: 76-13-1
30 50 70 90 110 130 150 170
m/z
0
2
4
6
8
10
Y ( X10
0
)
Raw Spec:Scan 628(6.47)
101
151
40
103 153
8566
30 50 70 90 110 130 150 170
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 628(6.47), Qvalue=92 Sig Qvalue=98
101
151
103 153
85
78
66
30 50 70 90 110 130 150 170
0
2
4
6
8
10
( X10
0
)
Ref Spec: 30 1,1,2-Trichloro-1,2,2-trifluoroethane (NIST14.L)
101
151
103
153
85
87 105 15566
30 50 70 90 110 130 150 170
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.480 min.(Qvalue: 92)
85 153
5.9 6.2 6.5 6.8
Min
RT
0
12
24
36
48
60
72
Y ( X10
)
m/z 101.0

6
.
4
7
3
5.9 6.2 6.5 6.8
Min
RT
0
8
16
24
32
40
48
Y ( X10
)
m/z 103.0

6
.
4
8
9
5.9 6.2 6.5 6.8
Min
RT
0
10
20
30
40
50
60
Y ( X10
)
m/z 151.0

6
.
4
7
3
5.9 6.2 6.5 6.8
Min
0
12
24
36
48
60
72
Y ( X10
)
m/z 101.0
m/z 103.0
m/z 151.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
37 1,1-Dichloroethane, CAS: 75-34-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
)
Raw Spec:Scan 909(7.99)
63
57
41
65
43 83 85 98
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 909(7.99), Qvalue=100 Sig Qvalue=100
63
65
8361 85 9835
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 37 1,1-Dichloroethane (NIST14.L)
63
65
8361 85 98
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 7.990 min.(Qvalue:100)
7.4 7.7 8.0 8.3
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 63.0

7
.
9
8
9
7.4 7.7 8.0 8.3
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
m/z 65.0

7
.
9
9
4
7.4 7.7 8.0 8.3
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 83.0

7
.
9
8
9
7.4 7.7 8.0 8.3
Min
0
3
6
9
12
Y ( X10
0
0
)
m/z 63.0
m/z 65.0
m/z 83.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
98 1,2,3-Trimethylbenzene, CAS: 526-73-8
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
5
10
15
20
25
30
Y ( X10
0
0
)
Raw Spec:Scan 3070(19.64)
105
120
41 55 77
121
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 3070(19.64), Qvalue=99 Sig Qvalue=98
105
120
77
51 121
20 40 60 80 100 120 140 160 180 200 220 240 260
0
2
4
6
8
10
( X10
0
)
Ref Spec: 98 1,2,3-Trimethylbenzene (NIST14.L)
105
120
7739
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.640 min.(Qvalue: 99)
120
19.1 19.4 19.7 20.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 120.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 77.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 77.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
92 1,2,4-Trimethylbenzene, CAS: 95-63-6
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 2985(19.18)
105
120
77 119911033951
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2985(19.18), Qvalue=98 Sig Qvalue=100
105
120
77 119911033951
20 30 40 50 60 70 80 90 100 110 120 130 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 92 1,2,4-Trimethylbenzene (NIST14.L)
105
120
77 11991395110365
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.180 min.(Qvalue: 98)
18.6 18.9 19.2 19.5
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 120.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 119.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
87 1,3,5-Trimethylbenzene, CAS: 108-67-8
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 2906(18.76)
105
120
77 1199139571034165
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2906(18.76), Qvalue=93 Sig Qvalue=90
105
120
77 119911033951
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 87 1,3,5-Trimethylbenzene (NIST14.L)
105
120
119779139 12110351
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.760 min.(Qvalue: 93)
18.2 18.5 18.8 19.1
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 120.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 119.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 120.0
m/z 105.0
m/z 119.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
39 2-Butanone (MEK), CAS: 78-93-3
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
Raw Spec:Scan 1022(8.60)
43
57
72294156
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1022(8.60), Qvalue=99 Sig Qvalue=97
43
72
29
5742
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 39 2-Butanone (MEK) (NIST14.L)
43
72
29
57
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.590 min.(Qvalue: 99)
8.0 8.3 8.6 8.9
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
)
m/z 72.0

8
.
5
9
8
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
m/z 43.0

8
.
5
9
2
8.0 8.3 8.6 8.9
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 29.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
m/z 72.0
m/z 43.0
m/z 29.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 2893(18.69)
105
120
6941 91 125
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2893(18.69), Qvalue=99 Sig Qvalue=99
105
120
77
51
20 40 60 80 100 120 140 160 180 200 220 240
0
2
4
6
8
10
( X10
0
)
Ref Spec: 88 4-Ethyltoluene (NIST14.L)
105
120
91
20 40 60 80 100 120 140 160 180 200 220 240
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.690 min.(Qvalue: 99)
120
18.1 18.4 18.7 19.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 120.0
1
8
.
6
5
5
18.1 18.4 18.7 19.0
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 119.0
1
8
.
6
6
0
18.1 18.4 18.7 19.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
64 4-Methyl-2-pentanone (MIBK), CAS: 108-10-1
20 30 40 50 60 70 80 90 100 110 120
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 1933(13.51)
43
70
55
41 58
39 8569 10029
53
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1933(13.51), Qvalue=92 Sig Qvalue=98
43
70
55
41 58
39
8569 10029
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 64 4-Methyl-2-pentanone (MIBK) (NIST14.L)
43
58
41
8529 100
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.510 min.(Qvalue: 92)
70
13.0 13.3 13.6 13.9
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 43.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 58.0
1
3
.
5
1
6
13.0 13.3 13.6 13.9
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 57.0
1
3
.
5
1
6
13.0 13.3 13.6 13.9
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 43.0
m/z 58.0
m/z 57.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
51 Benzene, CAS: 71-43-2
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 1473(11.03)
78
56 77 8441
69
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
)
Amdis Enhanced Spec: Scan 1473(11.03), Qvalue=96 Sig Qvalue=98
78
56
43 84
39 77
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 51 Benzene (NIST14.L)
78
77
51 52
7938
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.020 min.(Qvalue: 96)
56
10.5 10.8 11.1 11.4
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 78.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 77.0
1
1
.
0
2
4
10.5 10.8 11.1 11.4
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 51.0
1
1
.
0
2
4
10.5 10.8 11.1 11.4
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 78.0
m/z 77.0
m/z 51.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
44 Chloroform, CAS: 67-66-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)
Raw Spec:Scan 1167(9.38)
49 130
128
51 93
1329579
47
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1167(9.38), Qvalue=35 Sig Qvalue=7
45
59
31
6044 90
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 44 Chloroform (NIST14.L)
83
85
47
48 873582
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.390 min.(Qvalue: 35)
45
59
8.8 9.1 9.4 9.7
Min
RT
0
14
28
42
56
70
84
Y ( X10
)
m/z 83.0

9
.
3
8
0
8.9 9.2 9.5 9.8
Min
RT
0
8
16
24
32
40
Y ( X10
0
)
m/z 85.0

9
.
4
1
8
8.8 9.1 9.4 9.7
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 47.0

9
.
3
6
9
8.8 9.1 9.4 9.7 10.0
Min
0
3
6
9
12
Y ( X10
0
0
)
m/z 83.0
m/z 85.0
m/z 47.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
42 cis-1,2-Dichloroethene, CAS: 156-59-2
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
Y ( X10
0
0
)
Raw Spec:Scan 1101(9.02)
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1101(9.02), Qvalue=93 Sig Qvalue=91
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 cis-1,2-Dichloroethene (NIST14.L)
61
96
98
6360
10047
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.020 min.(Qvalue: 93)
96 98
8.5 8.8 9.1 9.4
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 96.0

9
.
0
2
4
8.5 8.8 9.1 9.4
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 61.0

9
.
0
2
4
8.5 8.8 9.1 9.4
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 98.0

9
.
0
2
9
8.5 8.8 9.1 9.4
Min
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 96.0
m/z 61.0
m/z 98.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
50 Cyclohexane, CAS: 110-82-7
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 1471(11.02)
78
56
41 8477
57
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1471(11.02), Qvalue=91 Sig Qvalue=70
56
84
41
55
69
39 42 85
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 50 Cyclohexane (NIST14.L)
56
84
41
55
69
39 42
8583
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.020 min.(Qvalue: 91)
10.5 10.8 11.1 11.4
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 69.0
1
1
.
0
1
9
10.5 10.8 11.1 11.4
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 55.0
1
1
.
0
1
9
10.5 10.8 11.1 11.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 41.0
1
1
.
0
1
4
10.5 10.8 11.1 11.4
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 69.0
m/z 55.0
m/z 41.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
17 Ethanol, CAS: 64-17-5
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 364(5.05)
31
45
46
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 364(5.05), Qvalue=92 Sig Qvalue=91
31
45
46
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 17 Ethanol (NIST14.L)
31
45
46
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.050 min.(Qvalue: 92)
45
4.5 4.8 5.1 5.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 31.0

5
.
0
5
0
4.5 4.8 5.1 5.4
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 45.0

5
.
0
5
0
4.5 4.8 5.1 5.4
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 31.0
m/z 45.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
43 Ethyl acetate, CAS: 141-78-6
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Raw Spec:Scan 1143(9.25)
43
61 70
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1143(9.25), Qvalue=99 Sig Qvalue=100
43
61 70
42
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 43 Ethyl acetate (NIST14.L)
43
61 70 88
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.250 min.(Qvalue: 99)
61
8.7 9.0 9.3 9.6
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 43.0

9
.
2
5
0
8.7 9.0 9.3 9.6
Min
RT
0
6
12
18
24
30
Y ( X10
0
)
m/z 61.0

9
.
2
4
5
8.7 9.0 9.3 9.6
Min
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 43.0
m/z 61.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
76 Ethylbenzene, CAS: 100-41-4
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 2535(16.76)
91
57
106
41 4329 7765 78
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2535(16.76), Qvalue=98 Sig Qvalue=99
91
57
106
41 4329 7765 78
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 76 Ethylbenzene (NIST14.L)
91
106
51 65 77 78 9239
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.760 min.(Qvalue: 98)
57
16.2 16.5 16.8 17.1
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
7
5
7
16.2 16.5 16.8 17.1
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
0
)
m/z 106.0
1
6
.
7
6
2
16.2 16.5 16.8 17.1
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 77.0
1
6
.
7
5
7
16.2 16.5 16.8 17.1
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
63 Methylcyclohexane, CAS: 108-87-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
12
24
36
48
60
72
84
Y ( X10
0
0
)
Raw Spec:Scan 1848(13.05)
83
55
9841
39 5642 69 70 82
29 6753 84
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1848(13.05), Qvalue=94 Sig Qvalue=97
83
55
98
41
39 42 56 69 8270
29 53 84
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 63 Methylcyclohexane (NIST14.L)
83
55
41 98
42 56
69 70
39 822968 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.050 min.(Qvalue: 94)
12.5 12.8 13.1 13.4
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
0
)
m/z 83.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 55.0
1
3
.
0
4
7
12.5 12.8 13.1 13.4
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 98.0
1
3
.
0
4
7
12.5 12.8 13.1 13.4
Min
0
15
30
45
60
75
90
Y ( X10
0
0
)
m/z 83.0
m/z 55.0
m/z 98.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
31 Methylene Chloride, CAS: 75-09-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
)
Raw Spec:Scan 666(6.68)
49 84
86
51
473235
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 666(6.68), Qvalue=90 Sig Qvalue=91
49
84
86
51
4735
37
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 31 Methylene Chloride (NIST14.L)
49
84
86
51
47
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.680 min.(Qvalue: 90)
84 86
6.1 6.4 6.7 7.0
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
m/z 84.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 49.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 86.0

6
.
6
7
3
6.1 6.4 6.7 7.0
Min
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 84.0
m/z 49.0
m/z 86.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
77 m-Xylene & p-Xylene, CAS: 179601-23-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
Raw Spec:Scan 2565(16.92)
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2565(16.92), Qvalue=98 Sig Qvalue=98
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 77 m-Xylene & p-Xylene (DATA)
91
106
105
77 785139 9265
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.920 min.(Qvalue: 98)
106
16.4 16.7 17.0 17.3
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
0
)
m/z 106.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 77.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
56 n-Heptane, CAS: 142-82-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)
Raw Spec:Scan 1675(12.12)
43
41 71
57
5629 70
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1675(12.12), Qvalue=89 Sig Qvalue=91
43
41 71
57
56 7029
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 56 n-Heptane (NIST14.L)
43
41
29 57 71
5639 70 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.120 min.(Qvalue: 89)
715741
11.6 11.9 12.2 12.5
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
0
)
m/z 71.0
1
2
.
1
1
9
11.6 11.9 12.2 12.5
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 43.0
1
2
.
1
1
9
11.6 11.9 12.2 12.5
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 57.0
1
2
.
1
1
9
11.6 11.9 12.2 12.5
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 71.0
m/z 43.0
m/z 57.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
40 Hexane, CAS: 110-54-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)
Raw Spec:Scan 1018(8.58)
43 57
41
56
8672
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
0
0
)
Enhanced Spec:Scan 1018(8.58) Bgrd 1005( 8.51), Qvalue=88 Sig Qvalue=100
43 57
41
56
8672
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 40 Hexane (NIST14.L)
57
43
56
86
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1018 @ 8.576 min.(Qvalue: 88)
43
8.0 8.3 8.6 8.9
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 56.0

8
.
5
7
6
8.0 8.3 8.6 8.9
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
0
)
m/z 57.0

8
.
5
8
2
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 86.0

8
.
5
7
6
8.0 8.3 8.6 8.9
Min
0
14
28
42
56
70
84
Y ( X10
0
0
)
m/z 56.0
m/z 57.0
m/z 86.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
78 n-Nonane, CAS: 111-84-2
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
12
24
36
48
60
72
84
Y ( X10
0
0
)
Raw Spec:Scan 2638(17.31)
43
57
41
85
29 7156
39
84 9969 128
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2638(17.31), Qvalue=87 Sig Qvalue=89
43 57
41
85
29 7156
39 8455 99 128
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 78 n-Nonane (NIST14.L)
43
57
41 85712956
39 84 99
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.320 min.(Qvalue: 87)
41
57
16.8 17.1 17.4 17.7
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 57.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
0
)
m/z 43.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 85.0
1
7
.
3
1
7
16.8 17.1 17.4 17.7
Min
0
14
28
42
56
70
84
Y ( X10
0
0
)
m/z 57.0
m/z 43.0
m/z 85.0
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Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
81 o-Xylene, CAS: 95-47-6
20 30 40 50 60 70 80 90 100 110 120
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 2665(17.46)
91
106
1057751397865
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2665(17.46), Qvalue=99 Sig Qvalue=99
91
106
105
775139 7865
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 81 o-Xylene (NIST14.L)
91
106
105
77516539 79 103
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.460 min.(Qvalue: 99)
16.9 17.2 17.5 17.8
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 91.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 106.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
)
m/z 77.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
80 Styrene, CAS: 100-42-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
4
8
12
16
20
24
Y ( X10
0
)
Raw Spec:Scan 2655(17.40)
104
10378
32 77515539
8363 976929
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2655(17.40), Qvalue=94 Sig Qvalue=98
104
10378
51 77
6332 102
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 80 Styrene (NIST14.L)
104
10378
51 77
50 52 102633974
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.410 min.(Qvalue: 94)
78
103
16.9 17.2 17.5 17.8
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
m/z 104.0
1
7
.
4
0
4
16.8 17.1 17.4 17.7
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 78.0
1
7
.
3
9
8
16.9 17.2 17.5 17.8
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 103.0
1
7
.
4
0
4
16.8 17.1 17.4 17.7 18.0
Min
0
3
6
9
12
Y ( X10
0
0
)
m/z 104.0
m/z 78.0
m/z 103.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
73 Tetrachloroethene, CAS: 127-18-4
20 40 60 80 100 120 140 160 180
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 2315(15.57)
166
164129131
16894
9647 133593582
20 40 60 80 100 120 140 160 180
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2315(15.57), Qvalue=96 Sig Qvalue=99
166
164129131
16894
9647 133593582
61
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 73 Tetrachloroethene (NIST14.L)
166
164
129 131
168
94
96 13347598235
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 15.570 min.(Qvalue: 96)
129
15.0 15.3 15.6 15.9
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 129.0
1
5
.
5
7
0
15.0 15.3 15.6 15.9
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 166.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 168.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 129.0
m/z 166.0
m/z 168.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
46 Tetrahydrofuran, CAS: 109-99-9
20 40 60 80 100 120 140 160 180 200
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
0
)
Raw Spec:Scan 1250(9.83)
42
41
72
39 43
44
20 40 60 80 100 120 140 160 180 200
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
0
)
Enhanced Spec:Scan 1250(9.83) Bgrd 1240( 9.77), Qvalue=91 Sig Qvalue=95
42
41
72
39 43
44
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 46 Tetrahydrofuran (NIST14.L)
42
41 72
4339
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1250 @ 9.827 min.(Qvalue: 91)
41
9.3 9.6 9.9 10.2
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 42.0

9
.
8
2
7
9.3 9.6 9.9 10.2
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 72.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 71.0

9
.
8
2
7
9.3 9.6 9.9 10.2
Min
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 42.0
m/z 72.0
m/z 71.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
67 Toluene, CAS: 108-88-3
20 30 40 50 60 70 80 90 100 110 120
m/z
0
5
10
15
20
25
30
35
40
Y ( X10
0
0
0
)
Raw Spec:Scan 2096(14.39)
91
92
39 654351 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
)
Amdis Enhanced Spec: Scan 2096(14.39), Qvalue=93 Sig Qvalue=90
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 67 Toluene (NIST14.L)
91
92
653951 93
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 14.380 min.(Qvalue: 93)
13.8 14.1 14.4 14.7
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
0
)
m/z 91.0
1
4
.
3
8
9
13.8 14.1 14.4 14.7
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 92.0
1
4
.
3
8
9
13.8 14.1 14.4 14.7
Min
0
6
12
18
24
30
36
Y ( X10
0
0
0
)
m/z 91.0
m/z 92.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
58 Trichloroethene, CAS: 79-01-6
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 1702(12.26)
95 130
97
60
623547 999459
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1702(12.26), Qvalue=97 Sig Qvalue=97
95 130
97
60
623547 999459
20 30 40 50 60 70 80 90 100 110 120 130 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 58 Trichloroethene (NIST14.L)
130
95
97
60
6247 99943559
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.260 min.(Qvalue: 97)
95 97
11.7 12.0 12.3 12.6
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 130.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 95.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 132.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 130.0
m/z 95.0
m/z 132.0
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Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
82 1,1,2,2-Tetrachloroethane, CAS: 79-34-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
)
Raw Spec:Scan 2736(17.84)
55
57 97
41
43
70 71
29 39 83 96
53 67 98 111
79
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2736(17.84), Qvalue=50
57
43
41
99
7156
8539
29 9745
20 30 40 50 60 70 80 90 100 110 120 130
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 82 1,1,2,2-Tetrachloroethane (NIST14.L)
83
85
956061
17.4 17.7 18.0
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 83.0
1
7
.
8
4
0
17.4 17.7 18.0
Min
RT
0
8
16
24
32
40
Y ( X10
0
)
m/z 85.0
1
7
.
8
6
7
17.4 17.7 18.0
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 96.0
1
7
.
8
2
4
RT Mass Response Amount
17.84 83.00 3366 0.018693
17.87 85.00 2931
17.82 96.00 2215
Reviewer: CJS9, 20-Mar-2024 15:22:45 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 234 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
57 1,2-Dichloropropane, CAS: 78-87-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 1701(12.26)
95 130
97
60
623547 999459
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1701(12.26), Qvalue=41
95 130
97
60
623547 999459
20 40 60 80 100 120 140
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 57 1,2-Dichloropropane (NIST14.L)
63
62
41
65
39 76
61 7838
12.0 12.3
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 63.0
1
2
.
2
5
9
12.0 12.3
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
0
)
m/z 62.0
1
2
.
2
5
9
12.0 12.3
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
m/z 65.0
1
2
.
2
6
5
RT Mass Response Amount
12.26 63.00 3518 0.052781
12.26 62.00 155672
12.26 65.00 16560
Reviewer: CJS9, 20-Mar-2024 15:19:13 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 235 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
69 2-Hexanone, CAS: 591-78-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 2223(15.07)
43
854157
71
562939 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2223(15.07), Qvalue=65
43
854157
71
5629 7039 84 114
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 69 2-Hexanone (NIST14.L)
43
58
5741 100852971
14.6 14.9
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 58.0
1
5
.
0
7
4
14.6 14.9
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 43.0
1
5
.
0
6
9
14.6 14.9
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 57.0
1
5
.
0
7
4
RT Mass Response Amount
15.07 58.00 4092 0.062369
15.07 43.00 214729
15.07 57.00 92756
Reviewer: CJS9, 20-Mar-2024 15:20:36 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 236 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Manual Integration/User Assign Peak Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
Signal: 1
Processing Integration Results
RT: 18.65
Area: 153072
Amount: 0.460093
Amount Units: ppb v/v
18.3 18.5 18.7 18.9
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
Y ( X10
0
0
)
m/z 105.0
1
8
.
6
5
5
Manual Integration Results
RT: 18.69
Area: 62874
Amount: 0.188982
Amount Units: ppb v/v
18.3 18.5 18.7 18.9
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X10
0
0
)
m/z 105.0
1
8
.
6
8
7
Reviewer: CJS9, 20-Mar-2024 15:23:14 07:00:00 (UTC)
Audit Action: Split an Integrated Peak Audit Reason: Wrong peak
3/25/2024
9:50:51 AM
Page 237 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
66 trans-1,3-Dichloropropene, CAS: 10061-02-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
5
10
15
20
25
30
35
40
Y ( X10
0
0
0
)
Raw Spec:Scan 2096(14.39)
91
92
39 654351 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2096(14.39), Qvalue=45
43
57
85
41
56 84
29 39
55
69 70 86
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 66 trans-1,3-Dichloropropene (NIST14.L)
75
39
77
11049
112385173
14.0 14.3 14.6
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 75.0
1
4
.
3
8
9
14.0 14.3 14.6
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 39.0
1
4
.
3
8
9
14.0 14.3 14.6
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
m/z 77.0
1
4
.
3
8
9
RT Mass Response Amount
14.39 75.00 5287 0.057202
14.39 39.00 96561
14.39 77.00 9738
Reviewer: CJS9, 20-Mar-2024 15:19:49 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 238 of 864
Report Date: 20-Mar-2024 15:24:55 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
38 Vinyl acetate, CAS: 108-05-4
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 915(8.02)
57
41
43
63
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 915(8.02), Qvalue=35
57
41
43
71
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 38 Vinyl acetate (NIST14.L)
43
8642
7.7 8.0 8.3
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
)
m/z 43.0

8
.
0
2
1
7.7 8.0 8.3
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 42.0

8
.
0
2
1
7.7 8.0 8.3
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 86.0

8
.
0
2
1
RT Mass Response Amount
8.02 43.00 29787 0.272308
8.02 42.00 9258
8.02 86.00 4716
Reviewer: CJS9, 20-Mar-2024 15:18:54 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 239 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Butane,2-methyl-78-78-4 NIST14.L 722 C5H12 72 91
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
6
12
18
24
30
Y ( X10
0
0
)
Raw Spec: Scan 405(5.27)
43
57
3929 56
7244
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
6
12
18
24
30
Y ( X10
0
0
)
RZC19P112[MS SCAN Spec]:Scan 405(5.27) Bgrd 350( 4.97)
43
57
3929 56
72
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #722, Butane, 2-methyl- (from NIST14.L)
43
57
39 5629
72
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,2-methyl-107-83-5 NIST14.L 1844 C6H14 86 91
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
Y ( X10
0
0
)
Raw Spec: Scan 827(7.55)
43
42
71
39 57 7029
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
Y ( X10
0
0
)
RZC19P112[MS SCAN Spec]:Scan 827(7.55) Bgrd 762( 7.20)
43
42
71
39 57 7029
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1844, Pentane, 2-methyl- (from NIST14.L)
43
42
41 71
29 57 70
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Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,3-methyl-96-14-0 NIST14.L 1847 C6H14 86 87
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
9
18
27
36
45
Y ( X10
0
0
)
Raw Spec: Scan 915(8.02)
57
41
29
4339
63 71
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
9
18
27
36
45
Y ( X10
0
0
)
RZC19P112[MS SCAN Spec]:Scan 915(8.02) Bgrd 762( 7.20)
57
41
29
4339
63 71
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1847, Pentane, 3-methyl- (from NIST14.L)
57
56
4129
43
39
55 71
3/25/2024
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Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
4
8
12
16
Y ( X10
0
0
0
)Raw Spec: Scan 1020(8.59)
43
57
4129 56 7239 86
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
4
8
12
16
Y ( X10
0
0
0
)RZC19P112[MS SCAN Spec]:Scan 1020(8.59) Bgrd 990( 8.43)
43
57
4129 56 7239 86
3/25/2024
9:50:51 AM
Page 243 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
17
34
51
68
85
Y ( X10
0
0
)
Raw Spec: Scan 1062(8.81)
45
592943
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
17
34
51
68
85
Y ( X10
0
0
)
RZC19P112[MS SCAN Spec]:Scan 1062(8.81) Bgrd 990( 8.43)
45
592943
3/25/2024
9:50:51 AM
Page 244 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Cyclopentane,methyl-96-37-7 NIST14.L 1512 C6H12 84 94
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
17
34
51
68
85
Y ( X10
0
0
)
Raw Spec: Scan 1233(9.74)
56
41 69
5539
84682953
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
17
34
51
68
85
Y ( X10
0
0
)
RZC19P112[MS SCAN Spec]:Scan 1233(9.74) Bgrd 990( 8.43)
56
41 69
5539
84682953
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1512, Cyclopentane, methyl- (from NIST14.L)
56
41
69
39 55
842968
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Page 245 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)Raw Spec: Scan 1614(11.79)
43
41 86565770
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)RZC19P112[MS SCAN Spec]:Scan 1614(11.79) Bgrd 1608(11.76)
43
8641707155
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Page 246 of 864
Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Octane 111-65-9 NIST14.L 7758 C8H18 114 91
20 30 40 50 60 70 80 90 100 110 120
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 2223(15.07)
43
854157
71
29 5539 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P112[MS SCAN Spec]:Scan 2223(15.07) Bgrd 1824(12.92)
43
854157
71
29 5539 84 114
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #7758, Octane (from NIST14.L)
43
41
5729 8571395584 114
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Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Decane 124-18-5 NIST14.L 19650 C10H22 142 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)Raw Spec: Scan 2952(19.01)
5743
41 71
852956703984 99 105 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P112[MS SCAN Spec]:Scan 2952(19.01) Bgrd 2752(17.93)
57
43
41 71
852956703984 99 105 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #19650, Decane (from NIST14.L)
43 57
41 71
29 85567039
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Report Date: 20-Mar-2024 15:24:56 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P112.D
Injection Date:19-Mar-2024 21:50:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:12 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Undecane 1120-21-4 NIST14.L 29357 C11H24 156 94
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
18
36
54
72
90
Y ( X10
0
0
)
Raw Spec: Scan 3189(20.28)
57
43
7141
85552970 1198498
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
18
36
54
72
90
Y ( X10
0
0
)
RZC19P112[MS SCAN Spec]:Scan 3189(20.28) Bgrd 3118(19.90)
5743
7141
8529557084 11998
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #29357, Undecane (from NIST14.L)
57
43
71
8556297084 98 15699
3/25/2024
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Page 249 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-3 Lab Sample ID:140-35862-3
Matrix:RZC20P109.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 13:55
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.16
Level: (low/med)Low
20(mL)
0.32(mm)
Date Analyzed:03/20/2024 18:30
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 260 J 310 58
60.1067-63-0 Isopropyl alcohol 2300 83 10
%RECCAS NO.LIMITSQSURROGATE
103 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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Page 250 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-3 Lab Sample ID:140-35862-3
Matrix:RZC20P109.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 13:55
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.16
Level: (low/med)Low
20(mL)
0.32(mm)
Date Analyzed:03/20/2024 18:30
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 610 J 740 140
60.1067-63-0 Isopropyl alcohol 5700 200 25
%RECCAS NO.LIMITSQSURROGATE
103 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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Page 251 of 864
Report Date: 21-Mar-2024 09:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P109.D
Lims ID:140-35862-A-3
Client ID:03072024-3
Sample Type:Client
Inject. Date:20-Mar-2024 18:30:30 ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.1600
Sample Info:140-0031995-015
Misc. Info.:140-35862-a-3@4.16
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 09:49:21 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1675
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.364 9.374 -0.010 87 247739 3.84
* 2 1,4-Difluorobenzene 114 11.553 11.558 -0.005 94 1154233 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.422 16.438 -0.016 87 1055138 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.067 18.060 -0.011 87 807982 4.19
23 Acetone 58 5.675 5.701 -0.033 96 83337 2.46
24 Isopropyl alcohol 45 5.778 5.852 -0.081 97 1846737 22.5
37 1,1-Dichloroethane 63 7.978 7.979 -0.011 100 18534 0.1431
38 Vinyl acetate 43 8.010 8.103 -0.103 34 15447 0.1127
40 Hexane 56 8.571 8.572 -0.011 90 60653 1.14
39 2-Butanone (MEK) 72 8.593 8.593 -0.010 99 52701 1.54
42 cis-1,2-Dichloroethene 96 9.019 9.019 -0.010 93 28922 0.3642
43 Ethyl acetate 43 9.245 9.224 0.011 99 14188 0.0973
46 Tetrahydrofuran 42 9.827 9.827 -0.011 90 70871 1.00
50 Cyclohexane 69 11.014 11.019 -0.010 96 17562 0.5088
51 Benzene 78 11.025 11.025 -0.005 96 186199 0.8120
56 n-Heptane 71 12.119 12.140 -0.027 87 73423 0.9639
57 1,2-Dichloropropane 63 12.254 12.259 -0.011 40 1596 0.0190
58 Trichloroethene 130 12.265 12.286 -0.027 98 506200 4.66
63 Methylcyclohexane 83 13.047 13.084 -0.043 94 114571 0.8395
64 4-Methyl-2-pentanone (MIBK) 43 13.516 13.542 -0.032 91 43858 0.2769
66 trans-1,3-Dichloropropene 75 14.395 14.284 0.097 45 2773 0.0238
67 Toluene 91 14.389 14.408 -0.033 93 430403 1.49
73 Tetrachloroethene 129 15.576 15.577 -0.016 97 29180 0.2808
76 Ethylbenzene 91 16.757 16.751 -0.010 98 74944 0.2010
77 m-Xylene & p-Xylene 91 16.918 16.913 -0.011 98 211218 0.7246
78 n-Nonane 57 17.312 17.306 -0.011 89 84191 0.5245
81 o-Xylene 91 17.458 17.446 -0.005 99 75663 0.2491
82 1,1,2,2-Tetrachloroethane 83 17.673 17.774 -0.119 59 3837 0.0169
88 4-Ethyltoluene 105 18.687 18.674 -0.005 99 37913 0.0905
87 1,3,5-Trimethylbenzene 120 18.757 18.739 0.000 93 17389 0.0998
92 1,2,4-Trimethylbenzene 105 19.183 19.164 0.000 98 99675 0.2767
98 1,2,3-Trimethylbenzene 105 19.642 19.622 0.001 99 28050 0.0767
3/25/2024
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Page 252 of 864
Report Date: 21-Mar-2024 09:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 253 of 864
Report Date: 21-Mar-2024 09:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P109.D
Injection Date:20-Mar-2024 18:30:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3 Worklist Smp#:15
Client ID:03072024-3
Purge Vol:500.000 mL Dil. Factor:4.1600 ALS Bottle#:9
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Y ( X10
0
0
0
0
)
RZC20P109[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
3
6
4
)+
* 1
,4-
D
i
f
l
u
o
r
o
b
e
n
zen
e
( 1
1
.
5
5
3
)+
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6
.
4
2
2
)+
$ 4
-
Bro
m
o
f
l
u
o
r
o
b
e
n
zen
e

(Su
r
r
)(
1
8
.
0
6
7
)+
3/25/2024
9:50:51 AM
Page 254 of 864
Report Date: 21-Mar-2024 09:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P109.D
Lims ID:140-35862-A-3
Client ID:03072024-3
Sample Type:Client
Inject. Date:20-Mar-2024 18:30:30 ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.1600
Sample Info:140-0031995-015
Misc. Info.:140-35862-a-3@4.16
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 09:49:21 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1675
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.19 102.68
3/25/2024
9:50:51 AM
Page 255 of 864
Report Date: 21-Mar-2024 09:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P109.D
Injection Date:20-Mar-2024 18:30:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
23 Acetone, CAS: 67-64-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
12
24
36
48
60
72
84
Y ( X10
0
0
)
Raw Spec:Scan 480(5.68)
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 480(5.68), Qvalue=96 Sig Qvalue=96
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
0
2
4
6
8
10
( X10
0
)
Ref Spec: 23 Acetone (NIST14.L)
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.680 min.(Qvalue: 96)
58
5.1 5.4 5.7 6.0
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 58.0

5
.
6
7
5
5.1 5.4 5.7 6.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 43.0

5
.
6
8
1
5.1 5.4 5.7 6.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 58.0
m/z 43.0
3/25/2024
9:50:51 AM
Page 256 of 864
Report Date: 21-Mar-2024 09:49:21 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20P109.D
Injection Date:20-Mar-2024 18:30:30 Instrument ID:MR
Lims ID:140-35862-A-3 Lab Sample ID:140-35862-3
Client ID:03072024-3
Operator ID:ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.1600
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
24 Isopropyl alcohol, CAS: 67-63-0
20 40 60 80 100 120 140 160 180 200
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
0
0
)
Raw Spec:Scan 499(5.78)
45
43
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 499(5.78), Qvalue=97 Sig Qvalue=99
45
43
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 24 Isopropyl alcohol (NIST14.L)
45
43
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.780 min.(Qvalue: 97)
5.2 5.5 5.8 6.1
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
0
)
m/z 45.0

5
.
7
7
8
5.2 5.5 5.8 6.1
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 43.0

5
.
7
7
2
5.2 5.5 5.8 6.1
Min
0
9
18
27
36
45
54
Y ( X10
0
0
0
)
m/z 45.0
m/z 43.0
3/25/2024
9:50:51 AM
Page 257 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-4 Lab Sample ID:140-35862-4
Matrix:RZC19P113.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 15:25
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 22:36
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 2.2 J 4.0 1.4
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 4.0 0.70
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
0.50 J 4.0 0.48
133.4179-00-5 1,1,2-Trichloroethane ND 4.0 0.76
98.9675-34-3 1,1-Dichloroethane 11 4.0 0.54
96.9475-35-4 1,1-Dichloroethene ND 4.0 0.64
120.19526-73-8 1,2,3-Trimethylbenzene 9.5 4.0 1.8
181.45120-82-1 1,2,4-Trichlorobenzene ND 20 1.8
120.2095-63-6 1,2,4-Trimethylbenzene 34 4.0 1.0
187.87106-93-4 1,2-Dibromoethane (EDB)ND 4.0 0.62
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 4.0 0.60
147.0095-50-1 1,2-Dichlorobenzene ND 8.0 1.6
98.96107-06-2 1,2-Dichloroethane ND 4.0 0.50
112.9978-87-5 1,2-Dichloropropane ND 4.0 0.50
120.20108-67-8 1,3,5-Trimethylbenzene 11 8.0 3.2
54.09106-99-0 1,3-Butadiene ND 8.0 0.96
147.00541-73-1 1,3-Dichlorobenzene ND 4.0 0.80
147.00106-46-7 1,4-Dichlorobenzene ND 4.0 0.80
72.1178-93-3 2-Butanone (MEK)150 20 3.6
100.20591-78-6 2-Hexanone ND 10 2.8
120.20622-96-8 4-Ethyltoluene 9.9 8.0 1.1
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
30 20 2.8
78.1171-43-2 Benzene 81 4.0 0.66
126.58100-44-7 Benzyl chloride ND 8.0 1.9
163.8375-27-4 Bromodichloromethane ND 4.0 0.88
252.7575-25-2 Bromoform ND 4.0 1.3
94.9474-83-9 Bromomethane ND 4.0 1.1
76.1475-15-0 Carbon disulfide ND 8.0 1.7
153.8156-23-5 Carbon tetrachloride ND 4.0 0.64
112.56108-90-7 Chlorobenzene ND 4.0 1.1
64.5275-00-3 Chloroethane ND 4.0 1.6
119.3867-66-3 Chloroform 0.79 J 4.0 0.72
FORM I TO-15
3/25/2024
9:50:51 AM
Page 258 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-4 Lab Sample ID:140-35862-4
Matrix:RZC19P113.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 15:25
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 22:36
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 20 3.2
96.94156-59-2 cis-1,2-Dichloroethene 27 4.0 0.50
110.9710061-01-5 cis-1,3-Dichloropropene ND 8.0 0.96
84.16110-82-7 Cyclohexane 47 8.0 1.9
208.28124-48-1 Dibromochloromethane ND 4.0 0.68
120.9175-71-8 Dichlorodifluoromethane ND 4.0 0.70
46.0764-17-5 Ethanol 130 100 44
88.11141-78-6 Ethyl acetate 10 J 40 3.0
106.17100-41-4 Ethylbenzene 19 4.0 0.66
260.7687-68-3 Hexachlorobutadiene ND 20 1.6
88.151634-04-4 Methyl tert-butyl ether ND 20 2.6
98.19108-87-2 Methylcyclohexane 86 CI 4.0 1.0
84.9375-09-2 Methylene Chloride 9.1 J 20 6.8
106.17179601-23-1 m-Xylene & p-Xylene 71 4.0 1.5
100.21142-82-5 n-Heptane 92 8.0 0.70
86.17110-54-3 n-Hexane 100 8.0 1.3
128.26111-84-2 Nonane 49 8.0 2.2
106.1795-47-6 o-Xylene 24 4.0 0.76
104.15100-42-5 Styrene 1.3 J 4.0 1.2
165.83127-18-4 Tetrachloroethene 25 4.0 0.58
72.11109-99-9 Tetrahydrofuran 72 20 3.6
92.14108-88-3 Toluene 140 20 1.1
96.94156-60-5 trans-1,2-Dichloroethene ND 4.0 0.66
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 4.0 0.98
131.3979-01-6 Trichloroethene 400 4.0 0.66
137.3775-69-4 Trichlorofluoromethane ND 4.0 0.56
86.09108-05-4 Vinyl acetate ND 20 1.4
62.5075-01-4 Vinyl chloride ND 8.0 1.3
%RECCAS NO.LIMITSQSURROGATE
100 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 259 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-4 Lab Sample ID:140-35862-4
Matrix:RZC19P113.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 15:25
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 22:36
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 12 J 22 7.9
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 28 4.8
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
3.8 J 31 3.7
133.4179-00-5 1,1,2-Trichloroethane ND 22 4.2
98.9675-34-3 1,1-Dichloroethane 45 16 2.2
96.9475-35-4 1,1-Dichloroethene ND 16 2.5
120.19526-73-8 1,2,3-Trimethylbenzene 47 20 8.9
181.45120-82-1 1,2,4-Trichlorobenzene ND 150 13
120.2095-63-6 1,2,4-Trimethylbenzene 170 20 4.9
187.87106-93-4 1,2-Dibromoethane (EDB)ND 31 4.8
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 28 4.2
147.0095-50-1 1,2-Dichlorobenzene ND 48 9.4
98.96107-06-2 1,2-Dichloroethane ND 16 2.0
112.9978-87-5 1,2-Dichloropropane ND 19 2.3
120.20108-67-8 1,3,5-Trimethylbenzene 53 39 16
54.09106-99-0 1,3-Butadiene ND 18 2.1
147.00541-73-1 1,3-Dichlorobenzene ND 24 4.8
147.00106-46-7 1,4-Dichlorobenzene ND 24 4.8
72.1178-93-3 2-Butanone (MEK)450 59 11
100.20591-78-6 2-Hexanone ND 41 12
120.20622-96-8 4-Ethyltoluene 49 39 5.2
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
120 82 11
78.1171-43-2 Benzene 260 13 2.1
126.58100-44-7 Benzyl chloride ND 42 9.9
163.8375-27-4 Bromodichloromethane ND 27 5.9
252.7575-25-2 Bromoform ND 41 14
94.9474-83-9 Bromomethane ND 16 4.3
76.1475-15-0 Carbon disulfide ND 25 5.4
153.8156-23-5 Carbon tetrachloride ND 25 4.0
112.56108-90-7 Chlorobenzene ND 18 5.2
64.5275-00-3 Chloroethane ND 11 4.2
119.3867-66-3 Chloroform 3.8 J 20 3.5
FORM I TO-15
3/25/2024
9:50:51 AM
Page 260 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-4 Lab Sample ID:140-35862-4
Matrix:RZC19P113.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 15:25
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 22:36
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 41 6.6
96.94156-59-2 cis-1,2-Dichloroethene 110 16 2.0
110.9710061-01-5 cis-1,3-Dichloropropene ND 36 4.4
84.16110-82-7 Cyclohexane 160 28 6.4
208.28124-48-1 Dibromochloromethane ND 34 5.8
120.9175-71-8 Dichlorodifluoromethane ND 20 3.5
46.0764-17-5 Ethanol 240 190 83
88.11141-78-6 Ethyl acetate 38 J 140 11
106.17100-41-4 Ethylbenzene 83 17 2.9
260.7687-68-3 Hexachlorobutadiene ND 210 17
88.151634-04-4 Methyl tert-butyl ether ND 72 9.4
98.19108-87-2 Methylcyclohexane 340 CI 16 4.0
84.9375-09-2 Methylene Chloride 32 J 70 24
106.17179601-23-1 m-Xylene & p-Xylene 310 17 6.4
100.21142-82-5 n-Heptane 380 33 2.9
86.17110-54-3 n-Hexane 360 28 4.5
128.26111-84-2 Nonane 260 42 12
106.1795-47-6 o-Xylene 100 17 3.3
104.15100-42-5 Styrene 5.4 J 17 5.1
165.83127-18-4 Tetrachloroethene 170 27 3.9
72.11109-99-9 Tetrahydrofuran 210 59 11
92.14108-88-3 Toluene 540 76 4.3
96.94156-60-5 trans-1,2-Dichloroethene ND 16 2.6
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 18 4.5
131.3979-01-6 Trichloroethene 2200 22 3.6
137.3775-69-4 Trichlorofluoromethane ND 23 3.2
86.09108-05-4 Vinyl acetate ND 71 4.9
62.5075-01-4 Vinyl chloride ND 21 3.3
%RECCAS NO.LIMITSQSURROGATE
100 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 261 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-4 Lab Sample ID:140-35862-4
Matrix:RZC19P113.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 15:25
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/19/2024 22:36
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
Number TICs Found:TIC Result Total:6449
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
5.27 T J N78-78-4 Butane, 2-methyl-52 91%
7.55 T J N107-83-5 Pentane, 2-methyl-68 91%
8.02 T J N96-14-0 Pentane, 3-methyl-50 87%
8.80 T JUnknown68
9.74 T J N96-37-7 Cyclopentane, methyl-88 94%
11.80 T JUnknown64
15.07 T J N111-65-9 Octane 51 90%
19.01 T J N124-18-5 Decane 120 91%
20.28 T J N1120-21-4 Undecane 83 93%
FORM I-TIC TO-15
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Lims ID:140-35862-A-4
Client ID:03072024-4
Sample Type:Client
Inject. Date:19-Mar-2024 22:36:30 ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031988-018
Misc. Info.:140-35862-a-4@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:28:39 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:28:39
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.364 0.010 88 205913 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.553 0.005 95 956244 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.422 16.433 -0.011 87 862176 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.078 0.000 90 643281 4.08
17 Ethanol 31 5.050 5.031 0.027 89 64676 2.57
23 Acetone 58 5.691 5.690 0.010 98 165369 5.87
24 Isopropyl alcohol 45 5.794 5.820 -0.016 99 2794064 40.9
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.479 6.479 0.011 42 1305 0.0099
31 Methylene Chloride 84 6.678 6.679 0.011 91 11835 0.1824
37 1,1-Dichloroethane 63 7.994 7.997 0.011 100 24051 0.2234
40 Hexane 56 8.582 8.586 0.011 81 91289 2.06
39 2-Butanone (MEK) 72 8.598 8.596 0.016 99 85838 3.01
42 cis-1,2-Dichloroethene 96 9.024 9.034 0.006 93 36045 0.5461
43 Ethyl acetate 43 9.256 9.234 0.038 99 25241 0.2083
44 Chloroform 83 9.380 9.391 0.006 35 2173 0.0157
46 Tetrahydrofuran 42 9.833 9.833 0.017 90 84139 1.43
47 1,1,1-Trichloroethane 97 10.437 10.449 0.006 97 5862 0.0432
50 Cyclohexane 69 11.025 11.029 0.006 81 26566 0.9291
51 Benzene 78 11.030 11.035 0.006 97 307640 1.62
56 n-Heptane 71 12.125 12.152 -0.016 89 115223 1.83
58 Trichloroethene 130 12.265 12.303 -0.027 97 726904 8.07
63 Methylcyclohexane 83 13.052 13.097 -0.032 95 193706 1.71
64 4-Methyl-2-pentanone (MIBK) 43 13.510 13.539 -0.016 94 77839 0.5932
67 Toluene 91 14.395 14.421 -0.021 93 678996 2.87
73 Tetrachloroethene 129 15.570 15.591 -0.016 96 43184 0.5085
76 Ethylbenzene 91 16.757 16.773 -0.010 98 116656 0.3830
77 m-Xylene & p-Xylene 91 16.913 16.935 -0.016 99 335652 1.41
78 n-Nonane 57 17.312 17.323 -0.005 87 128944 0.9830
80 Styrene 104 17.404 17.409 0.000 89 4185 0.0252
81 o-Xylene 91 17.458 17.469 -0.005 99 116576 0.4696
88 4-Ethyltoluene 105 18.687 18.687 0.000 99 67893 0.1984
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
87 1,3,5-Trimethylbenzene 120 18.757 18.763 0.000 94 30678 0.2155
92 1,2,4-Trimethylbenzene 105 19.183 19.189 0.000 98 199328 0.6772
98 1,2,3-Trimethylbenzene 105 19.642 19.648 0.001 99 56533 0.1892
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Tentatively Identified Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Lims ID:140-35862-A-4
Client ID:03072024-4
Sample Type:Client
Inject. Date:19-Mar-2024 22:36:30 ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031988-018
Misc. Info.:140-35862-a-4@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:28:39 Calib Date:06-Mar-2024 00:47:30
Tic RT Window:0.000 -0.000 Response:height
Quant By:Nearest ISTD Quant LOD:25.00000
MS Library:\\chromfs\Knoxville\Database\NIST14.L
Min. Match:85
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:28:39
Tentative Identified Compound Results
RT Height
Amount
ppb v/v
Quant
Cpnd Qual
Lib
Entry
Molecular
Formula
Mol.
Weight Flags
78-78-4 Butane, 2-methyl-
5.271 149405 1.03 1 91 721 C5H12 72
107-83-5 Pentane, 2-methyl-
7.546 196661 1.36 1 91 1844 C6H14 86
96-14-0 Pentane, 3-methyl-
8.016 142788 0.9876 1 87 1847 C6H14 86
Unknown
8.797 195863 1.35 1
96-37-7 Cyclopentane, methyl-
9.741 254625 1.76 1 94 1512 C6H12 84
Unknown
11.796 332380 1.28 2
111-65-9 Octane
15.074 340985 1.02 3 90 7760 C8H18 114
124-18-5 Decane
19.005 776828 2.32 3 91 19650 C10H22 142
1120-21-4 Undecane
20.283 553793 1.65 3 93 29356 C11H24 156
Quantitation Compounds
Compound RT Height
Amount
ppb v/v
* 1 Chlorobromomethane (IS) 9.374 555204 3.84
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Compound RT Height
Amount
ppb v/v
* 2 1,4-Difluorobenzene 11.558 993785 3.84
* 3 Chlorobenzene-d5 (IS)16.422 1338932 4.00
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4 Worklist Smp#:18
Client ID:03072024-4
Purge Vol:500.000 mL Dil. Factor:4.0100 ALS Bottle#:13
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
Y ( X10
0
0
0
0
)
RZC19P113[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
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e

(IS
)(

9
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)+
* 1
,4-
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( 1
1
.
5
5
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o
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-
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(IS
)(
1
6
.
4
2
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$ 4
-
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3/25/2024
9:50:51 AM
Page 267 of 864
Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Lims ID:140-35862-A-4
Client ID:03072024-4
Sample Type:Client
Inject. Date:19-Mar-2024 22:36:30 ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0031988-018
Misc. Info.:140-35862-a-4@4.01
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:28:39 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:28:39
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.08 100.05
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
47 1,1,1-Trichloroethane, CAS: 71-55-6
30 50 70 90 110 130 150 170 190 210
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
)
Raw Spec:Scan 1363(10.44)
97
99
61
40 63 119 207
30 50 70 90 110 130 150 170 190 210
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1363(10.44), Qvalue=97 Sig Qvalue=97
97
99
61
63 117 11960
30 50 70 90 110 130 150 170 190 210
0
2
4
6
8
10
( X10
0
)
Ref Spec: 47 1,1,1-Trichloroethane (NIST14.L)
97
99
61
117 11963
60
30 50 70 90 110 130 150 170 190 210
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 10.450 min.(Qvalue: 97)
9.9 10.2 10.5 10.8
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 97.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 99.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
m/z 61.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
0
4
8
12
16
20
Y ( X10
0
)
m/z 97.0
m/z 99.0
m/z 61.0
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
30 1,1,2-Trichloro-1,2,2-trifluoroethane, CAS: 76-13-1
30 50 70 90 110 130 150 170
m/z
0
12
24
36
48
60
72
84
Y ( X10
)
Raw Spec:Scan 629(6.48)
101
151
40 103
15385
30 50 70 90 110 130 150 170
m/z
0
7
14
21
28
35
42
49
Y ( X10
)
Enhanced Spec:Scan 629(6.48) Bgrd 622( 6.44), Qvalue=42 Sig Qvalue=93
101
151
103
15385
78
30 50 70 90 110 130 150 170
0
2
4
6
8
10
( X10
0
)
Ref Spec: 30 1,1,2-Trichloro-1,2,2-trifluoroethane (NIST14.L)
101
151
103
153
85
87 105 15566
30 50 70 90 110 130 150 170
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 629 @ 6.479 min.(Qvalue: 42)
5.9 6.2 6.5 6.8
Min
RT
0
8
16
24
32
40
48
Y ( X10
)
m/z 101.0

6
.
4
7
9
5.9 6.2 6.5 6.8
Min
RT
0
7
14
21
28
35
Y ( X10
)
m/z 103.0

6
.
4
9
0
5.9 6.2 6.5 6.8
Min
RT
0
7
14
21
28
35
42
Y ( X10
)
m/z 151.0

6
.
4
7
3
5.9 6.2 6.5 6.8
Min
0
8
16
24
32
40
48
Y ( X10
)
m/z 101.0
m/z 103.0
m/z 151.0
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
37 1,1-Dichloroethane, CAS: 75-34-3
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
)
Raw Spec:Scan 910(7.99)
57
56
63
41
29
654339
8355 853271
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 910(7.99), Qvalue=100 Sig Qvalue=100
63
65
83 8562 9835
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 37 1,1-Dichloroethane (NIST14.L)
63
65
8361 85 98
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.000 min.(Qvalue:100)
7.4 7.7 8.0 8.3
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 63.0

7
.
9
9
4
7.4 7.7 8.0 8.3
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 65.0

7
.
9
9
4
7.4 7.7 8.0 8.3
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 83.0

7
.
9
9
4
7.4 7.7 8.0 8.3
Min
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 63.0
m/z 65.0
m/z 83.0
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Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
98 1,2,3-Trimethylbenzene, CAS: 526-73-8
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 3070(19.64)
105
120
41 7757 91
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 3070(19.64), Qvalue=99 Sig Qvalue=99
105
120
77 9151
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 98 1,2,3-Trimethylbenzene (NIST14.L)
105
120
77 913951
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.640 min.(Qvalue: 99)
120
19.1 19.4 19.7 20.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
6
4
2
19.1 19.4 19.7 20.0
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 120.0
1
9
.
6
4
2
19.1 19.4 19.7 20.0
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 77.0
1
9
.
6
4
2
19.1 19.4 19.7 20.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 77.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
92 1,2,4-Trimethylbenzene, CAS: 95-63-6
20 40 60 80 100 120 140
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 2985(19.18)
105
120
77 119911033951
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2985(19.18), Qvalue=98 Sig Qvalue=100
105
120
77 119911035139
20 40 60 80 100 120 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 92 1,2,4-Trimethylbenzene (NIST14.L)
105
120
77 11991395110365
20 40 60 80 100 120 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.180 min.(Qvalue: 98)
18.6 18.9 19.2 19.5
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 120.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
)
m/z 119.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
87 1,3,5-Trimethylbenzene, CAS: 108-67-8
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 2906(18.76)
105
120
77 11991395741103
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
)
Amdis Enhanced Spec: Scan 2906(18.76), Qvalue=94 Sig Qvalue=90
105
120
97 1194385775569
121115
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 87 1,3,5-Trimethylbenzene (NIST14.L)
105
120
119779139 12110351
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.740 min.(Qvalue: 94)
18.2 18.5 18.8 19.1
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 120.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 119.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 120.0
m/z 105.0
m/z 119.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
39 2-Butanone (MEK), CAS: 78-93-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 1022(8.60)
43
57
72
56
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1022(8.60), Qvalue=99 Sig Qvalue=96
43
72
5742
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 39 2-Butanone (MEK) (NIST14.L)
43
72
57
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.600 min.(Qvalue: 99)
8.0 8.3 8.6 8.9
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 72.0

8
.
5
9
8
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 43.0

8
.
5
9
3
8.0 8.3 8.6 8.9
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 29.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 72.0
m/z 43.0
m/z 29.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 2893(18.69)
105
120
6941 77 125
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2893(18.69), Qvalue=99 Sig Qvalue=100
105
120
77
51
20 40 60 80 100 120 140 160 180 200 220 240
0
2
4
6
8
10
( X10
0
)
Ref Spec: 88 4-Ethyltoluene (NIST14.L)
105
120
91
20 40 60 80 100 120 140 160 180 200 220 240
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.690 min.(Qvalue: 99)
120
18.1 18.4 18.7 19.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 120.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 119.0
1
8
.
6
8
2
18.1 18.4 18.7 19.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
64 4-Methyl-2-pentanone (MIBK), CAS: 108-10-1
20 30 40 50 60 70 80 90 100 110 120
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Raw Spec:Scan 1933(13.51)
43
70
5541 58
39
8569 10029
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1933(13.51), Qvalue=94 Sig Qvalue=98
43
58
41 8557 100
29
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 64 4-Methyl-2-pentanone (MIBK) (NIST14.L)
43
58
41
8529 100
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.510 min.(Qvalue: 94)
13.0 13.3 13.6 13.9
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 43.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 58.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 57.0
1
3
.
5
1
6
13.0 13.3 13.6 13.9
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 43.0
m/z 58.0
m/z 57.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
51 Benzene, CAS: 71-43-2
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 1473(11.03)
78
56 77 8441
69
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1473(11.03), Qvalue=97 Sig Qvalue=98
78
77
56 8439
69
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 51 Benzene (NIST14.L)
78
77
51 52
7938
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.030 min.(Qvalue: 97)
10.5 10.8 11.1 11.4
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 78.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 77.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 51.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 78.0
m/z 77.0
m/z 51.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
44 Chloroform, CAS: 67-66-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 1167(9.38)
49
130
128
51 93
95 13279
47
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1167(9.38), Qvalue=35 Sig Qvalue=5
45
59
31
6244 90
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 44 Chloroform (NIST14.L)
83
85
47
48 873582
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.390 min.(Qvalue: 35)
45
59
8.8 9.1 9.4 9.7
Min
RT
0
14
28
42
56
70
84
Y ( X10
)
m/z 83.0

9
.
3
8
0
8.8 9.1 9.4 9.7
Min
RT
0
6
12
18
24
30
Y ( X10
0
)
m/z 85.0

9
.
3
8
5
8.8 9.1 9.4 9.7
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 47.0

9
.
3
7
4
8.8 9.1 9.4 9.7
Min
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 83.0
m/z 85.0
m/z 47.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
42 cis-1,2-Dichloroethene, CAS: 156-59-2
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
)
Raw Spec:Scan 1101(9.02)
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1101(9.02), Qvalue=93 Sig Qvalue=91
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 cis-1,2-Dichloroethene (NIST14.L)
61
96
98
6360
10047
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.030 min.(Qvalue: 93)
96
98
8.5 8.8 9.1 9.4
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 96.0

9
.
0
2
4
8.5 8.8 9.1 9.4
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 61.0

9
.
0
2
9
8.5 8.8 9.1 9.4
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 98.0

9
.
0
2
4
8.5 8.8 9.1 9.4
Min
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 96.0
m/z 61.0
m/z 98.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
50 Cyclohexane, CAS: 110-82-7
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
Raw Spec:Scan 1472(11.02)
78
56 77 8441
69
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1472(11.02), Qvalue=81 Sig Qvalue=70
56
41
55 84
69 85
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 50 Cyclohexane (NIST14.L)
56
84
41
55
69
39 42
8583
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.020 min.(Qvalue: 81)
10.5 10.8 11.1 11.4
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
)
m/z 69.0
1
1
.
0
2
5
10.5 10.8 11.1 11.4
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 55.0
1
1
.
0
1
4
10.5 10.8 11.1 11.4
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 41.0
1
1
.
0
1
4
10.5 10.8 11.1 11.4
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 69.0
m/z 55.0
m/z 41.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
17 Ethanol, CAS: 64-17-5
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Raw Spec:Scan 364(5.05)
31
45
46
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 364(5.05), Qvalue=89 Sig Qvalue=88
31
45
46
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 17 Ethanol (NIST14.L)
31
45
46
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.050 min.(Qvalue: 89)
45
4.5 4.8 5.1 5.4
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 31.0

5
.
0
5
0
4.5 4.8 5.1 5.4
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 45.0

5
.
0
4
4
4.5 4.8 5.1 5.4
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 31.0
m/z 45.0
3/25/2024
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
43 Ethyl acetate, CAS: 141-78-6
20 40 60 80 100 120 140 160 180 200
m/z
0
11
22
33
44
55
66
77
88
Y ( X10
0
)
Raw Spec:Scan 1144(9.26)
43
45 61
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1144(9.26), Qvalue=99 Sig Qvalue=100
43
61 7042
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 43 Ethyl acetate (NIST14.L)
43
61 70 88
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.250 min.(Qvalue: 99)
8.7 9.0 9.3 9.6
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 43.0

9
.
2
5
6
8.7 9.0 9.3 9.6
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 61.0

9
.
2
5
0
8.7 9.0 9.3 9.6
Min
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 43.0
m/z 61.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
76 Ethylbenzene, CAS: 100-41-4
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
0
)
Raw Spec:Scan 2535(16.76)
91
57
106
41 4329 7765 78
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2535(16.76), Qvalue=98 Sig Qvalue=99
91
57
106
41 4329 65 77 78
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 76 Ethylbenzene (NIST14.L)
91
106
51 65 77 78 9239
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.760 min.(Qvalue: 98)
57
16.2 16.5 16.8 17.1
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
7
5
7
16.2 16.5 16.8 17.1
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 106.0
1
6
.
7
6
2
16.2 16.5 16.8 17.1
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 77.0
1
6
.
7
5
7
16.2 16.5 16.8 17.1
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
63 Methylcyclohexane, CAS: 108-87-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 1848(13.05)
83
55
9841
39 42 56 69 70 82
29 53 67 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1848(13.05), Qvalue=95 Sig Qvalue=98
83
55
98
41
4239 56 69 8270
29 53 84
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 63 Methylcyclohexane (NIST14.L)
83
55
41 98
42 56
69 70
39 822968 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.050 min.(Qvalue: 95)
12.5 12.8 13.1 13.4
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 83.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 55.0
1
3
.
0
4
7
12.5 12.8 13.1 13.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 98.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 83.0
m/z 55.0
m/z 98.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
31 Methylene Chloride, CAS: 75-09-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
)
Raw Spec:Scan 666(6.68)
49 84
86
51
473235
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 666(6.68), Qvalue=91 Sig Qvalue=90
49
84
86
51
4735
37
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 31 Methylene Chloride (NIST14.L)
49
84
86
51
47
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.680 min.(Qvalue: 91)
84 86
6.1 6.4 6.7 7.0
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 84.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 49.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 86.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 84.0
m/z 49.0
m/z 86.0
3/25/2024
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
77 m-Xylene & p-Xylene, CAS: 179601-23-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
0
)
Raw Spec:Scan 2564(16.91)
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
0
)
Enhanced Spec:Scan 2564(16.91) Bgrd 2553(16.85), Qvalue=99 Sig Qvalue=98
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 77 m-Xylene & p-Xylene (DATA)
91
106
105
77 785139 9265
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 2564 @ 16.913 min.(Qvalue: 99)
106
16.4 16.7 17.0 17.3
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
9
1
3
16.4 16.7 17.0 17.3
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 106.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 77.0
1
6
.
9
1
3
16.4 16.7 17.0 17.3
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
3/25/2024
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
56 n-Heptane, CAS: 142-82-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
11
22
33
44
55
66
77
Y ( X10
0
0
)
Raw Spec:Scan 1676(12.12)
43
7141
57
5629 70
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1676(12.12), Qvalue=89 Sig Qvalue=90
43
41 71
57
5629 70
39 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 56 n-Heptane (NIST14.L)
43
41
29 57 71
5639 70 10055
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.120 min.(Qvalue: 89)
714157
11.6 11.9 12.2 12.5
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
0
)
m/z 71.0
1
2
.
1
2
5
11.6 11.9 12.2 12.5
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 43.0
1
2
.
1
2
5
11.6 11.9 12.2 12.5
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 57.0
1
2
.
1
2
5
11.6 11.9 12.2 12.5
Min
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
m/z 71.0
m/z 43.0
m/z 57.0
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
40 Hexane, CAS: 110-54-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)
Raw Spec:Scan 1019(8.58)
43
57
41
56
72 86
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1019(8.58), Qvalue=81 Sig Qvalue=100
57
41
56
86
55 71
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 40 Hexane (NIST14.L)
57
43
56
86
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.590 min.(Qvalue: 81)
8.0 8.3 8.6 8.9
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 56.0

8
.
5
8
2
8.0 8.3 8.6 8.9
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 57.0

8
.
5
8
2
8.0 8.3 8.6 8.9
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 86.0

8
.
5
8
2
8.0 8.3 8.6 8.9
Min
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 56.0
m/z 57.0
m/z 86.0
3/25/2024
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
78 n-Nonane, CAS: 111-84-2
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 2638(17.31)
43
57
41
85
29 7156
39
84 9969 128
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2638(17.31), Qvalue=87 Sig Qvalue=90
43
57
41
85
29 7156
39 8455 99 128
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 78 n-Nonane (NIST14.L)
43
57
41 85712956
39 84 99
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.310 min.(Qvalue: 87)
41 57
16.8 17.1 17.4 17.7
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
0
)
m/z 57.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 43.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 85.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
0
12
24
36
48
60
72
Y ( X10
0
0
)
m/z 57.0
m/z 43.0
m/z 85.0
3/25/2024
9:50:51 AM
Page 290 of 864
Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
81 o-Xylene, CAS: 95-47-6
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
0
)
Raw Spec:Scan 2665(17.46)
91
106
105
775139 927865
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2665(17.46), Qvalue=99 Sig Qvalue=99
91
106
105
775139 926579
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 81 o-Xylene (NIST14.L)
91
106
105
7751 92653979
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.460 min.(Qvalue: 99)
16.9 17.2 17.5 17.8
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 91.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 106.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
m/z 77.0
1
7
.
4
5
8
16.9 17.2 17.5 17.8
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
3/25/2024
9:50:51 AM
Page 291 of 864
Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
80 Styrene, CAS: 100-42-5
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
m/z
0
3
6
9
12
15
18
21
24
Y ( X10
0
)
Raw Spec:Scan 2655(17.40)
104
10378
51 55 7740
41 67 97837357
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2655(17.40), Qvalue=89 Sig Qvalue=98
104
10378
51 77
63 102
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
0
2
4
6
8
10
( X10
0
)
Ref Spec: 80 Styrene (NIST14.L)
104
10378
51 77
50 52 102633974
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.400 min.(Qvalue: 89)
16.9 17.2 17.5 17.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 104.0
1
7
.
4
0
4
16.8 17.1 17.4 17.7
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 78.0
1
7
.
3
9
8
16.9 17.2 17.5 17.8
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 103.0
1
7
.
4
0
4
16.8 17.1 17.4 17.7 18.0
Min
0
2
4
6
8
10
12
Y ( X10
0
0
)
m/z 104.0
m/z 78.0
m/z 103.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
73 Tetrachloroethene, CAS: 127-18-4
20 40 60 80 100 120 140 160 180
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Raw Spec:Scan 2315(15.57)
166
164129
131
16894
9647 133593582
61 98
20 40 60 80 100 120 140 160 180
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2315(15.57), Qvalue=96 Sig Qvalue=100
166
164
129 131
16894
9647 133593582
61
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 73 Tetrachloroethene (NIST14.L)
166
164
129 131
168
94
96 13347598235
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 15.570 min.(Qvalue: 96)
15.0 15.3 15.6 15.9
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 129.0
1
5
.
5
7
0
15.0 15.3 15.6 15.9
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 166.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 168.0
1
5
.
5
7
0
15.0 15.3 15.6 15.9
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 129.0
m/z 166.0
m/z 168.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
46 Tetrahydrofuran, CAS: 109-99-9
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Raw Spec:Scan 1251(9.83)
42
41
71 72
39 43
44
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
)
Enhanced Spec:Scan 1251(9.83) Bgrd 1243( 9.79), Qvalue=90 Sig Qvalue=94
42
41
71 72
39 43
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 46 Tetrahydrofuran (NIST14.L)
42
41 72
4339
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1251 @ 9.833 min.(Qvalue: 90)
41
9.3 9.6 9.9 10.2
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 42.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 72.0

9
.
8
3
8
9.3 9.6 9.9 10.2
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 71.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
m/z 42.0
m/z 72.0
m/z 71.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
67 Toluene, CAS: 108-88-3
20 30 40 50 60 70 80 90 100 110 120
m/z
0
4
8
12
16
20
24
28
32
Y ( X10
0
0
0
)
Raw Spec:Scan 2097(14.39)
91
92
653951
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
)
Amdis Enhanced Spec: Scan 2097(14.39), Qvalue=93 Sig Qvalue=90
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 67 Toluene (NIST14.L)
91
92
653951 93
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 14.390 min.(Qvalue: 93)
13.8 14.1 14.4 14.7
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 91.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
m/z 92.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 91.0
m/z 92.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
58 Trichloroethene, CAS: 79-01-6
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
Raw Spec:Scan 1702(12.26)
13095
97
60
35 6247 94 9959
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1702(12.26), Qvalue=97 Sig Qvalue=98
13095
97
60
35 6247 999459
20 30 40 50 60 70 80 90 100 110 120 130 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 58 Trichloroethene (NIST14.L)
130
95
97
60
6247 99943559
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.270 min.(Qvalue: 97)
95 97 132
11.7 12.0 12.3 12.6
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 130.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 95.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 132.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 130.0
m/z 95.0
m/z 132.0
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Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
57 1,2-Dichloropropane, CAS: 78-87-5
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
0
)
Raw Spec:Scan 1701(12.26)
95 130 132
97
60
134
35 6247 9994
20 40 60 80 100 120 140 160 180 200
m/z
0
9
18
27
36
45
54
63
Y ( X10
0
)
Amdis Enhanced Spec: Scan 1701(12.26), Qvalue=41
97
134
132
62 9969944055
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 57 1,2-Dichloropropane (NIST14.L)
63
62
41
65
39
776138
11.9 12.2 12.5
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
m/z 63.0
1
2
.
2
5
9
11.9 12.2 12.5
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 62.0
1
2
.
2
6
5
11.9 12.2 12.5
Min
RT
0
9
18
27
36
45
Y ( X10
0
)
m/z 65.0
1
2
.
2
6
5
RT Mass Response Amount
12.26 63.00 2665 0.038359
12.26 62.00 111098
12.26 65.00 11434
Reviewer: CJS9, 20-Mar-2024 15:27:25 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
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Page 297 of 864
Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
66 trans-1,3-Dichloropropene, CAS: 10061-02-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
4
8
12
16
20
24
28
32
Y ( X10
0
0
0
)
Raw Spec:Scan 2097(14.39)
91
92
653951
20 30 40 50 60 70 80 90 100 110 120
m/z
0
4
8
12
16
20
24
Y ( X10
0
)
Amdis Enhanced Spec: Scan 2097(14.39), Qvalue=50
92
39
6351
93
38 56 66
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 66 trans-1,3-Dichloropropene (NIST14.L)
75
39
77
11049
112385173
14.0 14.3 14.6
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 75.0
1
4
.
3
9
5
14.0 14.3 14.6
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 39.0
1
4
.
3
8
9
14.0 14.3 14.6
Min
RT
0
6
12
18
24
30
Y ( X10
0
)
m/z 77.0
1
4
.
3
8
9
RT Mass Response Amount
14.39 75.00 4255 0.044762
14.39 39.00 74982
14.39 77.00 7667
Reviewer: CJS9, 20-Mar-2024 15:28:03 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 298 of 864
Report Date: 20-Mar-2024 15:28:39 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
38 Vinyl acetate, CAS: 108-05-4
Processing Results
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 914(8.02)
57
41
29
4339
55 63 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 914(8.02), Qvalue=34
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 38 Vinyl acetate (NIST14.L)
43
8642
7.7 8.0 8.3
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 43.0

8
.
0
1
6
7.7 8.0 8.3
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 42.0

8
.
0
1
6
7.7 8.0 8.3
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 86.0

8
.
0
2
1
RT Mass Response Amount
8.02 43.00 23809 0.209000
8.02 42.00 7809
8.02 86.00 3413
Reviewer: CJS9, 20-Mar-2024 15:26:46 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 299 of 864
Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Butane,2-methyl-78-78-4 NIST14.L 721 C5H12 72 91
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
6
12
18
24
30
Y ( X10
0
0
)
Raw Spec: Scan 405(5.27)
43
57
29 39 56
7244
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
6
12
18
24
30
Y ( X10
0
0
)
RZC19P113[MS SCAN Spec]:Scan 405(5.27) Bgrd 386( 5.17)
43
57
29 39 56
72
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #721, Butane, 2-methyl- (from NIST14.L)
43
41
57
29
39 56
72
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Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,2-methyl-107-83-5 NIST14.L 1844 C6H14 86 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
10
20
30
40
50
Y ( X10
0
0
)
Raw Spec: Scan 827(7.55)
43
42
71
39 5729 70
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
10
20
30
40
50
Y ( X10
0
0
)
RZC19P113[MS SCAN Spec]:Scan 827(7.55) Bgrd 762( 7.20)
43
42
71
39 57 7029
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1844, Pentane, 2-methyl- (from NIST14.L)
43
42
41 71
29 57 70
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Page 301 of 864
Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,3-methyl-96-14-0 NIST14.L 1847 C6H14 86 87
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
7
14
21
28
35
Y ( X10
0
0
)
Raw Spec: Scan 914(8.02)
57
41
29 4339
55 63 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
7
14
21
28
35
Y ( X10
0
0
)
RZC19P113[MS SCAN Spec]:Scan 914(8.02) Bgrd 762( 7.20)
57
41
29
4339
55 63 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1847, Pentane, 3-methyl- (from NIST14.L)
57
56
4129
43
39
55 71
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Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
Raw Spec: Scan 1059(8.80)
45
592943
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
RZC19P113[MS SCAN Spec]:Scan 1059(8.80) Bgrd 1050( 8.75)
45
592943
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Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Cyclopentane,methyl-96-37-7 NIST14.L 1512 C6H12 84 94
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
14
28
42
56
70
Y ( X10
0
0
)
Raw Spec: Scan 1234(9.74)
56
41 69
5539
84296753
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
14
28
42
56
70
Y ( X10
0
0
)
RZC19P113[MS SCAN Spec]:Scan 1234(9.74) Bgrd 1050( 8.75)
56
41 69
5539
84296753
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1512, Cyclopentane, methyl- (from NIST14.L)
56
41
69
39 55
842968
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Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 1615(11.80)
43
41 86567071
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P113[MS SCAN Spec]:Scan 1615(11.80) Bgrd 1354(10.39)
43
41 86567071
3/25/2024
9:50:51 AM
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Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Octane 111-65-9 NIST14.L 7760 C8H18 114 90
Heptane,2,4-dimethyl-2213-23-2 NIST14.L 12971 C9H20 128 86
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
14
28
42
56
70
Y ( X10
0
0
)
Raw Spec: Scan 2223(15.07)
43
854157
7129
39 55 84 114
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
14
28
42
56
70
Y ( X10
0
0
)
RZC19P113[MS SCAN Spec]:Scan 2223(15.07) Bgrd 2174(14.81)
43
8541
57 7129
39 55 84 114
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #7760, Octane (from NIST14.L)
43
57 85417129
5539
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #12971, Heptane, 2,4-dimethyl- (from NIST14.L)
43
8541577129
84
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Report Date: 20-Mar-2024 15:28:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Decane 124-18-5 NIST14.L 19650 C10H22 142 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)Raw Spec: Scan 2952(19.01)
5743
41 71
8556297039 99 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)RZC19P113[MS SCAN Spec]:Scan 2952(19.01) Bgrd 2174(14.81)
5743
41 71
8556297039 99 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #19650, Decane (from NIST14.L)
43 57
41 71
29 85567039
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P113.D
Injection Date:19-Mar-2024 22:36:30 Instrument ID:MR
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:13 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Undecane 1120-21-4 NIST14.L 29356 C11H24 156 93
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 3189(20.28)
57
43
7141
85552970 1198498
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)RZC19P113[MS SCAN Spec]:Scan 3189(20.28) Bgrd 3118(19.90)
57
43
7141
8555297084 11998
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #29356, Undecane (from NIST14.L)
5743
41 71 85
29 56 70 84 98 99 156
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Page 308 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-4 Lab Sample ID:140-35862-4
Matrix:SZC21P109.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 15:25
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/21/2024 18:00
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 230 150 28
60.1067-63-0 Isopropyl alcohol 1700 40 4.8
%RECCAS NO.LIMITSQSURROGATE
120 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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Page 309 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-4 Lab Sample ID:140-35862-4
Matrix:SZC21P109.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 15:25
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.01
Level: (low/med)Low
40(mL)
0.32(mm)
Date Analyzed:03/21/2024 18:00
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 550 360 67
60.1067-63-0 Isopropyl alcohol 4200 99 12
%RECCAS NO.LIMITSQSURROGATE
120 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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Report Date: 22-Mar-2024 14:04:57 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P109.D
Lims ID:140-35862-A-4
Client ID:03072024-4
Sample Type:Client
Inject. Date:21-Mar-2024 18:00:30 ALS Bottle#:9 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0032009-014
Misc. Info.:140-35862-a-4@4.01
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 14:04:57 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 14:04:57
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.916 9.915 0.001 76 183219 3.84
* 2 1,4-Difluorobenzene 114 12.030 12.035 -0.005 95 842373 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.640 16.640 0.000 90 792456 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.249 18.248 0.001 93 692579 4.89
8 Dichlorodifluoromethane 85 4.251 4.245 0.006 47 1877 0.0156
17 Ethanol 31 5.440 5.434 0.006 96 60644 5.63
23 Acetone 58 6.145 6.139 0.006 100 86877 4.58
24 Isopropyl alcohol 45 6.225 6.241 -0.016 98 1706014 34.5
31 Methylene Chloride 84 7.188 7.188 0.000 94 7956 0.1733
37 1,1-Dichloroethane 63 8.522 8.528 -0.006 97 15980 0.1850
39 2-Butanone (MEK) 72 9.087 9.092 -0.005 98 45071 2.01
40 Hexane 56 9.119 9.114 0.005 86 55653 1.54
42 cis-1,2-Dichloroethene 96 9.561 9.566 -0.005 97 19905 0.3782
43 Ethyl acetate 43 9.727 9.727 0.000 97 12436 0.1204
46 Tetrahydrofuran 42 10.319 10.319 0.000 87 70177 1.38
47 1,1,1-Trichloroethane 97 10.965 10.965 0.001 95 6141 0.0513
50 Cyclohexane 69 11.535 11.535 0.000 46 16220 0.7456 a
51 Benzene 78 11.530 11.535 -0.005 98 186132 1.32
56 n-Heptane 71 12.584 12.578 0.000 86 60733 1.30
58 Trichloroethene 130 12.724 12.723 -0.005 95 571831 7.16
63 Methylcyclohexane 83 13.472 13.465 0.001 91 102309 1.12
64 4-Methyl-2-pentanone (MIBK) 43 13.843 13.837 0.006 97 36006 0.3348
67 Toluene 91 14.709 14.709 0.000 93 433692 2.25
73 Tetrachloroethene 129 15.828 15.828 0.000 93 38156 0.4755
76 Ethylbenzene 91 16.963 16.957 0.006 99 73304 0.2866
77 m-Xylene & p-Xylene 91 17.113 17.113 0.000 98 233257 1.19
78 n-Nonane 57 17.490 17.490 0.000 80 71459 0.6527
81 o-Xylene 91 17.641 17.641 0.000 96 76153 0.3434
87 4-Ethyltoluene 105 18.878 18.878 0.000 96 35589 0.1046 M
88 1,3,5-Trimethylbenzene 120 18.948 18.948 0.000 91 18742 0.1272
92 1,2,4-Trimethylbenzene 105 19.389 19.384 0.005 98 121976 0.4291
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Report Date: 22-Mar-2024 14:04:57 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P109.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
98 1,2,3-Trimethylbenzene 105 19.857 19.857 0.000 98 33122 0.1139
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Report Date: 22-Mar-2024 14:04:57 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P109.D
Injection Date:21-Mar-2024 18:00:30 Instrument ID:MS Operator ID:
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4 Worklist Smp#:14
Client ID:03072024-4
Purge Vol:500.000 mL Dil. Factor:4.0100 ALS Bottle#:9
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
Y ( X10
0
0
0
0
)
SZC21P109[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
9
2
1
)
* 1
,4-
D
i
f
l
u
o
r
o
b
e
n
zen
e
( 1
2
.
0
3
0
)+
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6
.
6
4
0
)
$ 4
-
Bro
m
o
f
l
u
o
r
o
b
e
n
zen
e

(Su
r
r
)(
1
8
.
2
4
9
)+
3/25/2024
9:50:51 AM
Page 313 of 864
Report Date: 22-Mar-2024 14:04:57 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P109.D
Lims ID:140-35862-A-4
Client ID:03072024-4
Sample Type:Client
Inject. Date:21-Mar-2024 18:00:30 ALS Bottle#:9 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:4.0100
Sample Info:140-0032009-014
Misc. Info.:140-35862-a-4@4.01
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 14:04:57 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 14:04:57
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.89 119.74
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Report Date: 22-Mar-2024 14:04:58 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P109.D
Injection Date:21-Mar-2024 18:00:30 Instrument ID:MS
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:9 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
23 Acetone, CAS: 67-64-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 402(6.14)
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 402(6.14), Qvalue=100 Sig Qvalue=100
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 23 Acetone (NIST14.L)
43
58
42
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.140 min.(Qvalue:100)
5.6 5.9 6.2 6.5
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 58.0

6
.
1
4
5
5.6 5.9 6.2 6.5
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
m/z 43.0

6
.
1
3
9
5.6 5.9 6.2 6.5
Min
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
m/z 58.0
m/z 43.0
3/25/2024
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Page 315 of 864
Report Date: 22-Mar-2024 14:04:58 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P109.D
Injection Date:21-Mar-2024 18:00:30 Instrument ID:MS
Lims ID:140-35862-A-4 Lab Sample ID:140-35862-4
Client ID:03072024-4
Operator ID:ALS Bottle#:9 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:4.0100
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
24 Isopropyl alcohol, CAS: 67-63-0
20 40 60 80 100 120 140 160 180 200 220
m/z
0
9
18
27
36
45
54
63
Y ( X10
0
0
0
)
Raw Spec:Scan 417(6.23)
45
43
20 40 60 80 100 120 140 160 180 200 220
m/z
0
8
16
24
32
40
48
56
64
Y ( X10
0
0
0
)
Enhanced Spec:Scan 417(6.23) Bgrd 405( 6.16), Qvalue=98 Sig Qvalue=96
45
43
20 40 60 80 100 120 140 160 180 200 220
0
2
4
6
8
10
( X10
0
)
Ref Spec: 24 Isopropyl alcohol (NIST14.L)
45
43
20 40 60 80 100 120 140 160 180 200 220
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 417 @ 6.225 min.(Qvalue: 98)
43
5.7 6.0 6.3 6.6
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
0
)
m/z 45.0

6
.
2
2
5
5.7 6.0 6.3 6.6
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
m/z 43.0

6
.
2
2
5
5.7 6.0 6.3 6.6
Min
0
9
18
27
36
45
54
63
Y ( X10
0
0
0
)
m/z 45.0
m/z 43.0
3/25/2024
9:50:51 AM
Page 316 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-5 Lab Sample ID:140-35862-5
Matrix:RZC19P114.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 16:30
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.45
Level: (low/med)Low
50(mL)
0.32(mm)
Date Analyzed:03/19/2024 23:21
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 2.0 J 3.6 1.3
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 3.6 0.62
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
0.43 J 3.6 0.43
133.4179-00-5 1,1,2-Trichloroethane ND 3.6 0.68
98.9675-34-3 1,1-Dichloroethane 9.7 3.6 0.48
96.9475-35-4 1,1-Dichloroethene ND 3.6 0.57
120.19526-73-8 1,2,3-Trimethylbenzene 7.9 3.6 1.6
181.45120-82-1 1,2,4-Trichlorobenzene ND 18 1.6
120.2095-63-6 1,2,4-Trimethylbenzene 27 3.6 0.89
187.87106-93-4 1,2-Dibromoethane (EDB)ND 3.6 0.55
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 3.6 0.53
147.0095-50-1 1,2-Dichlorobenzene ND 7.1 1.4
98.96107-06-2 1,2-Dichloroethane ND 3.6 0.45
112.9978-87-5 1,2-Dichloropropane ND 3.6 0.45
120.20108-67-8 1,3,5-Trimethylbenzene 10 7.1 2.8
54.09106-99-0 1,3-Butadiene ND 7.1 0.85
147.00541-73-1 1,3-Dichlorobenzene ND 3.6 0.71
147.00106-46-7 1,4-Dichlorobenzene ND 3.6 0.71
72.1178-93-3 2-Butanone (MEK)150 18 3.2
100.20591-78-6 2-Hexanone ND 8.9 2.5
120.20622-96-8 4-Ethyltoluene 9.0 7.1 0.94
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
37 18 2.5
78.1171-43-2 Benzene 86 3.6 0.59
126.58100-44-7 Benzyl chloride ND 7.1 1.7
163.8375-27-4 Bromodichloromethane ND 3.6 0.78
252.7575-25-2 Bromoform ND 3.6 1.2
94.9474-83-9 Bromomethane ND 3.6 0.98
76.1475-15-0 Carbon disulfide ND 7.1 1.5
153.8156-23-5 Carbon tetrachloride ND 3.6 0.57
112.56108-90-7 Chlorobenzene 1.1 J 3.6 1.0
64.5275-00-3 Chloroethane ND 3.6 1.4
119.3867-66-3 Chloroform 0.85 J 3.6 0.64
FORM I TO-15
3/25/2024
9:50:51 AM
Page 317 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-5 Lab Sample ID:140-35862-5
Matrix:RZC19P114.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 16:30
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.45
Level: (low/med)Low
50(mL)
0.32(mm)
Date Analyzed:03/19/2024 23:21
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 18 2.8
96.94156-59-2 cis-1,2-Dichloroethene 24 3.6 0.45
110.9710061-01-5 cis-1,3-Dichloropropene ND 7.1 0.85
84.16110-82-7 Cyclohexane 47 7.1 1.7
208.28124-48-1 Dibromochloromethane ND 3.6 0.61
120.9175-71-8 Dichlorodifluoromethane ND 3.6 0.62
46.0764-17-5 Ethanol 150 89 39
88.11141-78-6 Ethyl acetate 11 J 36 2.7
106.17100-41-4 Ethylbenzene 18 3.6 0.59
260.7687-68-3 Hexachlorobutadiene ND 18 1.4
88.151634-04-4 Methyl tert-butyl ether ND 18 2.3
98.19108-87-2 Methylcyclohexane 83 CI 3.6 0.89
84.9375-09-2 Methylene Chloride 9.9 J 18 6.1
106.17179601-23-1 m-Xylene & p-Xylene 70 3.6 1.3
100.21142-82-5 n-Heptane 91 7.1 0.62
86.17110-54-3 n-Hexane 100 7.1 1.1
128.26111-84-2 Nonane 51 7.1 2.0
106.1795-47-6 o-Xylene 24 3.6 0.68
104.15100-42-5 Styrene 1.3 J 3.6 1.1
165.83127-18-4 Tetrachloroethene 25 3.6 0.52
72.11109-99-9 Tetrahydrofuran 100 18 3.2
92.14108-88-3 Toluene 140 18 1.0
96.94156-60-5 trans-1,2-Dichloroethene ND 3.6 0.59
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 3.6 0.87
131.3979-01-6 Trichloroethene 370 3.6 0.59
137.3775-69-4 Trichlorofluoromethane ND 3.6 0.50
86.09108-05-4 Vinyl acetate ND 18 1.2
62.5075-01-4 Vinyl chloride ND 7.1 1.2
%RECCAS NO.LIMITSQSURROGATE
101 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 318 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-5 Lab Sample ID:140-35862-5
Matrix:RZC19P114.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 16:30
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.45
Level: (low/med)Low
50(mL)
0.32(mm)
Date Analyzed:03/19/2024 23:21
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 11 J 19 7.0
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 24 4.3
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
3.3 J 27 3.3
133.4179-00-5 1,1,2-Trichloroethane ND 19 3.7
98.9675-34-3 1,1-Dichloroethane 39 14 1.9
96.9475-35-4 1,1-Dichloroethene ND 14 2.3
120.19526-73-8 1,2,3-Trimethylbenzene 39 18 7.9
181.45120-82-1 1,2,4-Trichlorobenzene ND 130 12
120.2095-63-6 1,2,4-Trimethylbenzene 130 18 4.4
187.87106-93-4 1,2-Dibromoethane (EDB)ND 27 4.2
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 25 3.7
147.0095-50-1 1,2-Dichlorobenzene ND 43 8.3
98.96107-06-2 1,2-Dichloroethane ND 14 1.8
112.9978-87-5 1,2-Dichloropropane ND 16 2.1
120.20108-67-8 1,3,5-Trimethylbenzene 49 35 14
54.09106-99-0 1,3-Butadiene ND 16 1.9
147.00541-73-1 1,3-Dichlorobenzene ND 21 4.3
147.00106-46-7 1,4-Dichlorobenzene ND 21 4.3
72.1178-93-3 2-Butanone (MEK)450 52 9.4
100.20591-78-6 2-Hexanone ND 36 10
120.20622-96-8 4-Ethyltoluene 44 35 4.6
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
150 73 10
78.1171-43-2 Benzene 270 11 1.9
126.58100-44-7 Benzyl chloride ND 37 8.8
163.8375-27-4 Bromodichloromethane ND 24 5.2
252.7575-25-2 Bromoform ND 37 12
94.9474-83-9 Bromomethane ND 14 3.8
76.1475-15-0 Carbon disulfide ND 22 4.8
153.8156-23-5 Carbon tetrachloride ND 22 3.6
112.56108-90-7 Chlorobenzene 4.9 J 16 4.6
64.5275-00-3 Chloroethane ND 9.4 3.7
119.3867-66-3 Chloroform 4.2 J 17 3.1
FORM I TO-15
3/25/2024
9:50:51 AM
Page 319 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-5 Lab Sample ID:140-35862-5
Matrix:RZC19P114.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 16:30
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.45
Level: (low/med)Low
50(mL)
0.32(mm)
Date Analyzed:03/19/2024 23:21
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 37 5.9
96.94156-59-2 cis-1,2-Dichloroethene 95 14 1.8
110.9710061-01-5 cis-1,3-Dichloropropene ND 32 3.9
84.16110-82-7 Cyclohexane 160 25 5.7
208.28124-48-1 Dibromochloromethane ND 30 5.2
120.9175-71-8 Dichlorodifluoromethane ND 18 3.1
46.0764-17-5 Ethanol 290 170 74
88.11141-78-6 Ethyl acetate 40 J 130 9.6
106.17100-41-4 Ethylbenzene 80 15 2.6
260.7687-68-3 Hexachlorobutadiene ND 190 15
88.151634-04-4 Methyl tert-butyl ether ND 64 8.3
98.19108-87-2 Methylcyclohexane 330 CI 14 3.6
84.9375-09-2 Methylene Chloride 35 J 62 21
106.17179601-23-1 m-Xylene & p-Xylene 300 15 5.6
100.21142-82-5 n-Heptane 370 29 2.6
86.17110-54-3 n-Hexane 360 25 4.0
128.26111-84-2 Nonane 270 37 10
106.1795-47-6 o-Xylene 100 15 2.9
104.15100-42-5 Styrene 5.4 J 15 4.5
165.83127-18-4 Tetrachloroethene 170 24 3.5
72.11109-99-9 Tetrahydrofuran 290 52 9.4
92.14108-88-3 Toluene 540 67 3.8
96.94156-60-5 trans-1,2-Dichloroethene ND 14 2.3
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 16 4.0
131.3979-01-6 Trichloroethene 2000 19 3.2
137.3775-69-4 Trichlorofluoromethane ND 20 2.8
86.09108-05-4 Vinyl acetate ND 63 4.4
62.5075-01-4 Vinyl chloride ND 18 3.0
%RECCAS NO.LIMITSQSURROGATE
101 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 320 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-5 Lab Sample ID:140-35862-5
Matrix:RZC19P114.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 16:30
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.45
Level: (low/med)Low
50(mL)
0.32(mm)
Date Analyzed:03/19/2024 23:21
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
Number TICs Found:TIC Result Total:76110
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
5.28 T J N78-78-4 Butane, 2-methyl-43 91%
7.55 T J N107-83-5 Pentane, 2-methyl-68 91%
8.03 T J N96-14-0 Pentane, 3-methyl-49 90%
8.59 T JUnknown150
8.81 T JUnknown81
9.74 T J N96-37-7 Cyclopentane, methyl-88 94%
11.80 T JUnknown64
15.07 T J N111-65-9 Octane 52 87%
19.01 T J N124-18-5 Decane 96 91%
20.28 T J N1120-21-4 Undecane 70 93%
FORM I-TIC TO-15
3/25/2024
9:50:51 AM
Page 321 of 864
Report Date: 20-Mar-2024 15:31:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Lims ID:140-35862-A-5
Client ID:03072024-5
Sample Type:Client
Inject. Date:19-Mar-2024 23:21:30 ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Sample Info:140-0031988-019
Misc. Info.:140-35862-a-5@4.45
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:31:45 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:31:45
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.364 0.010 88 204411 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.553 0.005 95 950462 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.422 16.433 -0.011 87 1038244 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.078 0.000 87 783744 4.13
17 Ethanol 31 5.055 5.031 0.032 91 86736 3.48
23 Acetone 58 5.697 5.690 0.016 98 172706 6.18
24 Isopropyl alcohol 45 5.805 5.820 -0.005 99 3178708 46.8
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.484 6.479 0.016 91 1258 0.009621
31 Methylene Chloride 84 6.684 6.679 0.017 91 14388 0.2234
37 1,1-Dichloroethane 63 7.994 7.997 0.011 99 23413 0.2191
40 Hexane 56 8.582 8.586 0.011 85 102343 2.33
39 2-Butanone (MEK) 72 8.603 8.596 0.021 99 96094 3.40
42 cis-1,2-Dichloroethene 96 9.029 9.034 0.011 93 35266 0.5382
43 Ethyl acetate 43 9.250 9.234 0.032 99 29809 0.2479
44 Chloroform 83 9.390 9.391 0.016 37 2627 0.0191
46 Tetrahydrofuran 42 9.833 9.833 0.017 89 131052 2.24
47 1,1,1-Trichloroethane 97 10.437 10.449 0.006 96 5933 0.0441
50 Cyclohexane 69 11.024 11.029 0.005 94 29741 1.05
51 Benzene 78 11.030 11.035 0.006 97 363218 1.92
56 n-Heptane 71 12.124 12.152 -0.017 89 128633 2.05
58 Trichloroethene 130 12.265 12.303 -0.027 97 749704 8.37
63 Methylcyclohexane 83 13.052 13.097 -0.032 95 209749 1.87
64 4-Methyl-2-pentanone (MIBK) 43 13.510 13.539 -0.016 95 109705 0.8411
67 Toluene 91 14.395 14.421 -0.021 93 917416 3.22
73 Tetrachloroethene 129 15.576 15.591 -0.010 96 56676 0.5542
74 Chlorobenzene 112 16.476 16.492 -0.011 42 5473 0.0239
76 Ethylbenzene 91 16.762 16.773 -0.005 98 152312 0.4152
77 m-Xylene & p-Xylene 91 16.913 16.935 -0.016 99 451667 1.57
78 n-Nonane 57 17.312 17.323 -0.005 89 182137 1.15
80 Styrene 104 17.409 17.409 0.005 95 5676 0.0284
81 o-Xylene 91 17.457 17.469 -0.006 98 158682 0.5308
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Report Date: 20-Mar-2024 15:31:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
88 4-Ethyltoluene 105 18.687 18.687 0.000 98 83495 0.2026
87 1,3,5-Trimethylbenzene 120 18.757 18.763 0.000 93 38457 0.2243
92 1,2,4-Trimethylbenzene 105 19.183 19.189 0.000 98 217390 0.6133
98 1,2,3-Trimethylbenzene 105 19.641 19.648 0.000 99 63524 0.1766
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 323 of 864
Report Date: 20-Mar-2024 15:31:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Tentatively Identified Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Lims ID:140-35862-A-5
Client ID:03072024-5
Sample Type:Client
Inject. Date:19-Mar-2024 23:21:30 ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Sample Info:140-0031988-019
Misc. Info.:140-35862-a-5@4.45
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:31:45 Calib Date:06-Mar-2024 00:47:30
Tic RT Window:0.000 -0.000 Response:height
Quant By:Nearest ISTD Quant LOD:25.00000
MS Library:\\chromfs\Knoxville\Database\NIST14.L
Min. Match:85
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:31:45
Tentative Identified Compound Results
RT Height
Amount
ppb v/v
Quant
Cpnd Qual
Lib
Entry
Molecular
Formula
Mol.
Weight Flags
78-78-4 Butane, 2-methyl-
5.276 138620 0.9645 1 91 722 C5H12 72
107-83-5 Pentane, 2-methyl-
7.552 218559 1.52 1 91 1846 C6H14 86
96-14-0 Pentane, 3-methyl-
8.026 159686 1.11 1 90 1847 C6H14 86
Unknown
8.592 483143 3.36 1
Unknown
8.808 262843 1.83 1
96-37-7 Cyclopentane, methyl-
9.741 284880 1.98 1 94 1512 C6H12 84
Unknown
11.795 369806 1.45 2
111-65-9 Octane
15.074 460203 1.18 3 87 7758 C8H18 114
124-18-5 Decane
19.005 845939 2.17 3 91 19650 C10H22 142
1120-21-4 Undecane
20.283 610024 1.56 3 93 29356 C11H24 156
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Report Date: 20-Mar-2024 15:31:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Quantitation Compounds
Compound RT Height
Amount
ppb v/v
* 1 Chlorobromomethane (IS) 9.374 551880 3.84
* 2 1,4-Difluorobenzene 11.558 980586 3.84
* 3 Chlorobenzene-d5 (IS)16.422 1560955 4.00
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 325 of 864
Report Date: 20-Mar-2024 15:31:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR Operator ID:
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5 Worklist Smp#:19
Client ID:03072024-5
Purge Vol:500.000 mL Dil. Factor:4.4500 ALS Bottle#:14
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Y ( X10
0
0
0
0
)
RZC19P114[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
3
7
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)+
* 1
,4-
D
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f
l
u
o
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o
b
e
n
zen
e
( 1
1
.
5
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)+
* C
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zen
e
-
d5
(IS
)(
1
6
.
4
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$ 4
-
Bro
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e

(Su
r
r
)(
1
8
.
0
7
2
)+
3/25/2024
9:50:51 AM
Page 326 of 864
Report Date: 20-Mar-2024 15:31:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Lims ID:140-35862-A-5
Client ID:03072024-5
Sample Type:Client
Inject. Date:19-Mar-2024 23:21:30 ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Sample Info:140-0031988-019
Misc. Info.:140-35862-a-5@4.45
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:31:45 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:31:45
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.13 101.23
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
47 1,1,1-Trichloroethane, CAS: 71-55-6
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
)
Raw Spec:Scan 1363(10.44)
97
99
61
32
40 63 119
207
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1363(10.44), Qvalue=96 Sig Qvalue=97
97
99
61
63 1193560
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 47 1,1,1-Trichloroethane (NIST14.L)
97
99
61
117 11963
6035
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 10.440 min.(Qvalue: 96)
9.9 10.2 10.5 10.8
Min
RT
0
4
8
12
16
20
Y ( X10
0
)
m/z 97.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 99.0
1
0
.
4
4
2
9.9 10.2 10.5 10.8
Min
RT
0
2
4
6
8
10
Y ( X10
0
)
m/z 61.0
1
0
.
4
3
7
9.9 10.2 10.5 10.8
Min
0
4
8
12
16
20
Y ( X10
0
)
m/z 97.0
m/z 99.0
m/z 61.0
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Report Date: 20-Mar-2024 15:31:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
30 1,1,2-Trichloro-1,2,2-trifluoroethane, CAS: 76-13-1
30 50 70 90 110 130 150 170
m/z
0
2
4
6
8
10
12
Y ( X10
0
)
Raw Spec:Scan 630(6.48)
101
40 151103
85
45 153
30 50 70 90 110 130 150 170
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 630(6.48), Qvalue=91 Sig Qvalue=98
101
151
103
153
85
30 50 70 90 110 130 150 170
0
2
4
6
8
10
( X10
0
)
Ref Spec: 30 1,1,2-Trichloro-1,2,2-trifluoroethane (NIST14.L)
101
151
103
153
85
87 105 15566
30 50 70 90 110 130 150 170
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.480 min.(Qvalue: 91)
103
151 153
5.9 6.2 6.5 6.8
Min
RT
0
9
18
27
36
45
54
Y ( X10
)
m/z 101.0

6
.
4
8
4
5.9 6.2 6.5 6.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
)
m/z 103.0

6
.
4
7
9
5.9 6.2 6.5 6.8
Min
RT
0
7
14
21
28
35
42
Y ( X10
)
m/z 151.0

6
.
4
9
5
5.9 6.2 6.5 6.8
Min
0
9
18
27
36
45
54
Y ( X10
)
m/z 101.0
m/z 103.0
m/z 151.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
37 1,1-Dichloroethane, CAS: 75-34-3
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
11
22
33
44
55
66
77
88
Y ( X10
0
)
Raw Spec:Scan 910(7.99)
63
56
41
29
65
4339
8355 8571 98
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100104108
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 910(7.99), Qvalue=99 Sig Qvalue=100
63
65
83 8561 983541
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 37 1,1-Dichloroethane (NIST14.L)
63
65
8361 85 98
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.000 min.(Qvalue: 99)
65
7.4 7.7 8.0 8.3
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 63.0

7
.
9
9
4
7.4 7.7 8.0 8.3 8.6
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 65.0

7
.
9
9
9
7.4 7.7 8.0 8.3
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
m/z 83.0

7
.
9
9
4
7.4 7.7 8.0 8.3 8.6
Min
0
14
28
42
56
70
84
Y ( X10
0
)
m/z 63.0
m/z 65.0
m/z 83.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
98 1,2,3-Trimethylbenzene, CAS: 526-73-8
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
35
40
Y ( X10
0
0
)
Raw Spec:Scan 3070(19.64)
105
120
774157 91
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 3070(19.64), Qvalue=99 Sig Qvalue=98
105
120
7757 9139
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 98 1,2,3-Trimethylbenzene (NIST14.L)
105
120
77 913951
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.640 min.(Qvalue: 99)
120
19.1 19.4 19.7 20.0
Min
RT
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 120.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 77.0
1
9
.
6
4
1
19.1 19.4 19.7 20.0
Min
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 77.0
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
92 1,2,4-Trimethylbenzene, CAS: 95-63-6
20 40 60 80 100 120 140
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 2985(19.18)
105
120
77 119911033951
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2985(19.18), Qvalue=98 Sig Qvalue=100
105
120
77 119911035139
20 40 60 80 100 120 140
0
2
4
6
8
10
( X10
0
)
Ref Spec: 92 1,2,4-Trimethylbenzene (NIST14.L)
105
120
77 11991395110365
20 40 60 80 100 120 140
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 19.180 min.(Qvalue: 98)
18.6 18.9 19.2 19.5
Min
RT
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 105.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 120.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 119.0
1
9
.
1
8
3
18.6 18.9 19.2 19.5
Min
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
87 1,3,5-Trimethylbenzene, CAS: 108-67-8
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 2906(18.76)
105
120
77 11991573910341
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2906(18.76), Qvalue=93 Sig Qvalue=90
105
120
77 119911035139
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 87 1,3,5-Trimethylbenzene (NIST14.L)
105
120
119779139 12110351
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.760 min.(Qvalue: 93)
18.2 18.5 18.8 19.1
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 120.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
7
5
7
18.2 18.5 18.8 19.1
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 119.0
1
8
.
7
5
2
18.2 18.5 18.8 19.1
Min
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 120.0
m/z 105.0
m/z 119.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
39 2-Butanone (MEK), CAS: 78-93-3
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
0
)
Raw Spec:Scan 1023(8.60)
43
57
72
56
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1023(8.60), Qvalue=99 Sig Qvalue=96
43
72
5742
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 39 2-Butanone (MEK) (NIST14.L)
43
72
57
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.600 min.(Qvalue: 99)
8.1 8.4 8.7 9.0
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 72.0

8
.
6
0
3
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 43.0

8
.
5
9
8
8.0 8.3 8.6 8.9
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
)
m/z 29.0

8
.
5
9
2
8.0 8.3 8.6 8.9 9.2
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 72.0
m/z 43.0
m/z 29.0
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
88 4-Ethyltoluene, CAS: 622-96-8
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 2893(18.69)
105
120
69 7741 125 193 249
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2893(18.69), Qvalue=98 Sig Qvalue=100
105
120
7739 193133 249
20 40 60 80 100 120 140 160 180 200 220 240 260
0
2
4
6
8
10
( X10
0
)
Ref Spec: 88 4-Ethyltoluene (NIST14.L)
105
120
91
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 18.680 min.(Qvalue: 98)
120
18.1 18.4 18.7 19.0
Min
RT
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 105.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 120.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
RT
0
6
12
18
24
30
Y ( X10
0
)
m/z 119.0
1
8
.
6
8
7
18.1 18.4 18.7 19.0
Min
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 105.0
m/z 120.0
m/z 119.0
3/25/2024
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
64 4-Methyl-2-pentanone (MIBK), CAS: 108-10-1
20 30 40 50 60 70 80 90 100 110 120
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 1933(13.51)
43
70
41 55 58
39 85 1002969
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1933(13.51), Qvalue=95 Sig Qvalue=98
43
58
41
57
8529 100
56
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 64 4-Methyl-2-pentanone (MIBK) (NIST14.L)
43
58
41
8529 100
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 13.510 min.(Qvalue: 95)
58
13.0 13.3 13.6 13.9
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 43.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 58.0
1
3
.
5
1
6
13.0 13.3 13.6 13.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 57.0
1
3
.
5
1
0
13.0 13.3 13.6 13.9
Min
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 43.0
m/z 58.0
m/z 57.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
51 Benzene, CAS: 71-43-2
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 1473(11.03)
78
7756 8441
69
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
Y ( X10
0
)
Amdis Enhanced Spec: Scan 1473(11.03), Qvalue=97 Sig Qvalue=98
78
56
7741 84
69
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 51 Benzene (NIST14.L)
78
77
51 52
7938
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.030 min.(Qvalue: 97)
56
10.5 10.8 11.1 11.4
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 78.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 77.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 51.0
1
1
.
0
3
0
10.5 10.8 11.1 11.4
Min
0
3
6
9
12
15
Y ( X10
0
0
0
)
m/z 78.0
m/z 77.0
m/z 51.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
74 Chlorobenzene, CAS: 108-90-7
20 40 60 80 100 120 140 160 180
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
)
Raw Spec:Scan 2483(16.48)
180
145
161
75 130435084 16374117
41
20 40 60 80 100 120 140 160 180
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2483(16.48), Qvalue=42 Sig Qvalue=83
180
145
161
13075
1635012595
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 74 Chlorobenzene (NIST14.L)
112
77
114
51
38
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.480 min.(Qvalue: 42)
180
145
15.9 16.2 16.5 16.8
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
m/z 112.0
1
6
.
4
7
6
15.9 16.2 16.5 16.8
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 77.0
1
6
.
4
7
1
15.9 16.2 16.5 16.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 51.0
1
6
.
4
7
1
15.9 16.2 16.5 16.8
Min
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 112.0
m/z 77.0
m/z 51.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
44 Chloroform, CAS: 67-66-3
20 40 60 80 100 120 140 160 180 200
m/z
0
10
20
30
40
50
60
70
80
Y ( X10
0
0
)
Raw Spec:Scan 1169(9.39)
49
130
128
51 93
1329579
47
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1169(9.39), Qvalue=37 Sig Qvalue=8
45
59
31
6044 83
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 44 Chloroform (NIST14.L)
83
85
47
48 873582
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.390 min.(Qvalue: 37)
45
59
8.8 9.1 9.4 9.7
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
m/z 83.0

9
.
3
9
0
8.9 9.2 9.5 9.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
m/z 85.0

9
.
4
1
2
8.8 9.1 9.4 9.7
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 47.0

9
.
3
7
4
8.8 9.1 9.4 9.7 10.0
Min
0
3
6
9
12
Y ( X10
0
0
)
m/z 83.0
m/z 85.0
m/z 47.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
42 cis-1,2-Dichloroethene, CAS: 156-59-2
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
Y ( X10
0
0
)
Raw Spec:Scan 1102(9.03)
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1102(9.03), Qvalue=93 Sig Qvalue=92
61
96
98
63
60
35 10048
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 cis-1,2-Dichloroethene (NIST14.L)
61
96
98
6360
10047
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.030 min.(Qvalue: 93)
96
8.5 8.8 9.1 9.4
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 96.0

9
.
0
2
9
8.5 8.8 9.1 9.4
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 61.0

9
.
0
2
9
8.5 8.8 9.1 9.4
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
)
m/z 98.0

9
.
0
3
5
8.5 8.8 9.1 9.4
Min
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 96.0
m/z 61.0
m/z 98.0
3/25/2024
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
50 Cyclohexane, CAS: 110-82-7
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
0
)
Raw Spec:Scan 1472(11.02)
78
56 7741 84
69
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1472(11.02), Qvalue=94 Sig Qvalue=69
56
84
41
39 55 69
85
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 50 Cyclohexane (NIST14.L)
56
84
41
55
69
39 42
8583
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 11.030 min.(Qvalue: 94)
41 84
10.5 10.8 11.1 11.4
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
)
m/z 69.0
1
1
.
0
2
4
10.5 10.8 11.1 11.4
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 55.0
1
1
.
0
1
4
10.5 10.8 11.1 11.4
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 41.0
1
1
.
0
1
4
10.5 10.8 11.1 11.4
Min
0
6
12
18
24
30
Y ( X10
0
0
)
m/z 69.0
m/z 55.0
m/z 41.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
17 Ethanol, CAS: 64-17-5
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
5
10
15
20
25
30
35
40
Y ( X10
0
0
)
Raw Spec:Scan 365(5.06)
31
45
4629
43
32
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 365(5.06), Qvalue=91 Sig Qvalue=91
31
45
4629
43
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 17 Ethanol (NIST14.L)
31
45
29
46
43
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.060 min.(Qvalue: 91)
45
4.5 4.8 5.1 5.4
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
)
m/z 31.0

5
.
0
5
5
4.5 4.8 5.1 5.4
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 45.0

5
.
0
5
5
4.5 4.8 5.1 5.4
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 31.0
m/z 45.0
3/25/2024
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
43 Ethyl acetate, CAS: 141-78-6
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Raw Spec:Scan 1143(9.25)
43
45 61
42
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1143(9.25), Qvalue=99 Sig Qvalue=100
43
61 7042
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 43 Ethyl acetate (NIST14.L)
43
61 70 88
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.250 min.(Qvalue: 99)
8.7 9.0 9.3 9.6
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 43.0

9
.
2
5
0
8.7 9.0 9.3 9.6
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 61.0

9
.
2
5
0
8.7 9.0 9.3 9.6
Min
0
3
6
9
12
15
18
Y ( X10
0
0
)
m/z 43.0
m/z 61.0
3/25/2024
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
76 Ethylbenzene, CAS: 100-41-4
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
)
Raw Spec:Scan 2536(16.76)
91
57
106
41 43
65 77 7829
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2536(16.76), Qvalue=98 Sig Qvalue=99
91
57
106
41 43
65 7729 78
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 76 Ethylbenzene (NIST14.L)
91
106
51 65 77 78 9239
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 16.760 min.(Qvalue: 98)
57
16.2 16.5 16.8 17.1
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
7
6
2
16.2 16.5 16.8 17.1
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 106.0
1
6
.
7
5
6
16.2 16.5 16.8 17.1
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 77.0
1
6
.
7
5
6
16.2 16.5 16.8 17.1
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
3/25/2024
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
63 Methylcyclohexane, CAS: 108-87-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
11
22
33
44
55
66
77
Y ( X10
0
0
)
Raw Spec:Scan 1848(13.05)
83
55
9841
563942 69 70 82
29 53 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
11
22
33
44
55
66
77
Y ( X10
0
0
)
Enhanced Spec:Scan 1848(13.05) Bgrd 1828(12.94), Qvalue=95 Sig Qvalue=93
83
55
9841
563942 69 70 82
29 53 84
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
2
4
6
8
10
( X10
0
)
Ref Spec: 63 Methylcyclohexane (NIST14.L)
83
55
41 98
42 56
69 70
39 822968 8443
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1848 @ 13.052 min.(Qvalue: 95)
55
12.5 12.8 13.1 13.4
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 83.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 55.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
)
m/z 98.0
1
3
.
0
5
2
12.5 12.8 13.1 13.4
Min
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 83.0
m/z 55.0
m/z 98.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
31 Methylene Chloride, CAS: 75-09-2
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
9
18
27
36
45
54
63
72
Y ( X10
0
)
Raw Spec:Scan 667(6.68)
49
84
86
51
473235
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 667(6.68), Qvalue=91 Sig Qvalue=91
49
84
86
51
47
35
37
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
0
2
4
6
8
10
( X10
0
)
Ref Spec: 31 Methylene Chloride (NIST14.L)
49
84
86
51
47
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.680 min.(Qvalue: 91)
84 86
6.1 6.4 6.7 7.0
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
)
m/z 84.0

6
.
6
8
4
6.1 6.4 6.7 7.0
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
)
m/z 49.0

6
.
6
8
4
6.1 6.4 6.7 7.0
Min
RT
0
7
14
21
28
35
Y ( X10
0
)
m/z 86.0

6
.
6
7
8
6.1 6.4 6.7 7.0
Min
0
11
22
33
44
55
66
Y ( X10
0
)
m/z 84.0
m/z 49.0
m/z 86.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
77 m-Xylene & p-Xylene, CAS: 179601-23-1
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
0
)
Raw Spec:Scan 2564(16.91)
91
106
105
775139 926579
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
0
)
Enhanced Spec:Scan 2564(16.91) Bgrd 2553(16.85), Qvalue=99 Sig Qvalue=98
91
106
105
775139 926579
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
0
2
4
6
8
10
( X10
0
)
Ref Spec: 77 m-Xylene & p-Xylene (DATA)
91
106
105
77 785139 9265
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 2564 @ 16.913 min.(Qvalue: 99)
106
16.4 16.7 17.0 17.3
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
1
6
.
9
1
3
16.4 16.7 17.0 17.3
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 106.0
1
6
.
9
1
8
16.4 16.7 17.0 17.3
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 77.0
1
6
.
9
1
3
16.4 16.7 17.0 17.3
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
56 n-Heptane, CAS: 142-82-5
20 40 60 80 100 120 140 160 180 200
m/z
0
12
24
36
48
60
72
84
96
Y ( X10
0
0
)
Raw Spec:Scan 1676(12.12)
43
41 71
57
56
70
100
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1676(12.12), Qvalue=89 Sig Qvalue=91
43
41 71
57
56
70
100
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 56 n-Heptane (NIST14.L)
43
41
57 71
56
70 100
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.120 min.(Qvalue: 89)
714157
11.6 11.9 12.2 12.5
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
m/z 71.0
1
2
.
1
2
4
11.6 11.9 12.2 12.5
Min
RT
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 43.0
1
2
.
1
2
4
11.6 11.9 12.2 12.5
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
0
)
m/z 57.0
1
2
.
1
2
4
11.6 11.9 12.2 12.5
Min
0
3
6
9
12
Y ( X10
0
0
0
)
m/z 71.0
m/z 43.0
m/z 57.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
40 Hexane, CAS: 110-54-3
20 40 60 80 100 120 140 160 180 200
m/z
0
12
24
36
48
60
72
84
96
Y ( X10
0
0
)
Raw Spec:Scan 1019(8.58)
43
57
41
56
8672
20 40 60 80 100 120 140 160 180 200
m/z
0
12
24
36
48
60
72
84
Y ( X10
0
0
)
Enhanced Spec:Scan 1019(8.58) Bgrd 1005( 8.51), Qvalue=85 Sig Qvalue=100
43
57
41
56
8672
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 40 Hexane (NIST14.L)
57
43
56
86
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1019 @ 8.582 min.(Qvalue: 85)
43
8.0 8.3 8.6 8.9
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 56.0

8
.
5
8
2
8.0 8.3 8.6 8.9
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 57.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
m/z 86.0

8
.
5
8
7
8.0 8.3 8.6 8.9
Min
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 56.0
m/z 57.0
m/z 86.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
78 n-Nonane, CAS: 111-84-2
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)
Raw Spec:Scan 2638(17.31)
43
57
41
85
71562939 84 9969 128
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2638(17.31), Qvalue=89 Sig Qvalue=90
43 57
41
85
715629
39 84 9955 128
20 30 40 50 60 70 80 90 100 110 120 130
0
2
4
6
8
10
( X10
0
)
Ref Spec: 78 n-Nonane (NIST14.L)
43
57
41 85712956
39 84 99
20 30 40 50 60 70 80 90 100 110 120 130
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.320 min.(Qvalue: 89)
57
16.8 17.1 17.4 17.7
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
0
)
m/z 57.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 43.0
1
7
.
3
1
2
16.8 17.1 17.4 17.7
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
)
m/z 85.0
1
7
.
3
1
7
16.8 17.1 17.4 17.7
Min
0
2
4
6
8
10
Y ( X10
0
0
0
)
m/z 57.0
m/z 43.0
m/z 85.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
81 o-Xylene, CAS: 95-47-6
20 30 40 50 60 70 80 90 100 110 120
m/z
0
10
20
30
40
50
60
70
80
Y ( X10
0
0
)
Raw Spec:Scan 2665(17.46)
91
106
105
775139 7865
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2665(17.46), Qvalue=98 Sig Qvalue=98
91
106
105
77513965 79
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 81 o-Xylene (NIST14.L)
91
106
105
77516539 79 103
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.460 min.(Qvalue: 98)
16.9 17.2 17.5 17.8
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 91.0
1
7
.
4
5
7
16.9 17.2 17.5 17.8
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 106.0
1
7
.
4
5
7
16.9 17.2 17.5 17.8
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
)
m/z 77.0
1
7
.
4
5
7
16.9 17.2 17.5 17.8
Min
0
13
26
39
52
65
78
Y ( X10
0
0
)
m/z 91.0
m/z 106.0
m/z 77.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
80 Styrene, CAS: 100-42-5
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
)
Raw Spec:Scan 2656(17.41)
104
78 103
775155404169 83 9757
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2656(17.41), Qvalue=95 Sig Qvalue=98
104
10378
51 7763 10252
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
0
2
4
6
8
10
( X10
0
)
Ref Spec: 80 Styrene (NIST14.L)
104
10378
51 77
50 52 102633974
30 34 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98 102 106 110
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 17.410 min.(Qvalue: 95)
16.9 17.2 17.5 17.8
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
m/z 104.0
1
7
.
4
0
9
16.9 17.2 17.5 17.8
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 78.0
1
7
.
4
0
4
16.9 17.2 17.5 17.8
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 103.0
1
7
.
4
0
4
16.9 17.2 17.5 17.8
Min
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 104.0
m/z 78.0
m/z 103.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
73 Tetrachloroethene, CAS: 127-18-4
20 40 60 80 100 120 140 160 180
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
0
)
Raw Spec:Scan 2316(15.58)
166
164129131
16894
9647 133
59 823561
20 40 60 80 100 120 140 160 180
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2316(15.58), Qvalue=96 Sig Qvalue=98
166
164129131
16894
96 13347
59 823561
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 73 Tetrachloroethene (NIST14.L)
166
164
129 131
168
94
96 13347598235
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 15.580 min.(Qvalue: 96)
129
131
15.0 15.3 15.6 15.9
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
m/z 129.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 166.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
m/z 168.0
1
5
.
5
7
6
15.0 15.3 15.6 15.9
Min
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 129.0
m/z 166.0
m/z 168.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
46 Tetrahydrofuran, CAS: 109-99-9
20 40 60 80 100 120 140 160 180 200
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 1251(9.83)
42
41
72
39
43
44
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1251(9.83), Qvalue=89 Sig Qvalue=95
42
41
72
39
43
44
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 46 Tetrahydrofuran (NIST14.L)
42
41 72
4339
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 9.830 min.(Qvalue: 89)
41
9.3 9.6 9.9 10.2
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 42.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 72.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
m/z 71.0

9
.
8
3
3
9.3 9.6 9.9 10.2
Min
0
7
14
21
28
35
42
Y ( X10
0
0
)
m/z 42.0
m/z 72.0
m/z 71.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
67 Toluene, CAS: 108-88-3
20 30 40 50 60 70 80 90 100 110 120
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 2097(14.39)
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
0
)
Amdis Enhanced Spec: Scan 2097(14.39), Qvalue=93 Sig Qvalue=91
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
0
2
4
6
8
10
( X10
0
)
Ref Spec: 67 Toluene (NIST14.L)
91
92
653951 93
20 30 40 50 60 70 80 90 100 110 120
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 14.390 min.(Qvalue: 93)
13.8 14.1 14.4 14.7
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
0
)
m/z 91.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
0
)
m/z 92.0
1
4
.
3
9
5
13.8 14.1 14.4 14.7
Min
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
m/z 91.0
m/z 92.0
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Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
58 Trichloroethene, CAS: 79-01-6
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
Raw Spec:Scan 1702(12.26)
13095 132
97
60
134
623547 9994
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1702(12.26), Qvalue=97 Sig Qvalue=98
95 130 132
97
60
134
623547 9994
20 40 60 80 100 120 140 160 180 200
0
2
4
6
8
10
( X10
0
)
Ref Spec: 58 Trichloroethene (NIST14.L)
130 13295
97
60
134
6247 9994
20 40 60 80 100 120 140 160 180 200
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 12.270 min.(Qvalue: 97)
95 97
11.7 12.0 12.3 12.6
Min
RT
0
6
12
18
24
30
Y ( X10
0
0
0
)
m/z 130.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 95.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
m/z 132.0
1
2
.
2
6
5
11.7 12.0 12.3 12.6
Min
0
6
12
18
24
30
Y ( X10
0
0
0
)
m/z 130.0
m/z 95.0
m/z 132.0
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Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
82 1,1,2,2-Tetrachloroethane, CAS: 79-34-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
)
Raw Spec:Scan 2704(17.67)
57
43
41 69 85
56
125
713929
996744
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2704(17.67), Qvalue=58
57
43
8541
6956 125
84
29 39 99
20 30 40 50 60 70 80 90 100 110 120 130
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 82 1,1,2,2-Tetrachloroethane (NIST14.L)
83
85
956061
17.5 17.8
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
)
m/z 83.0
1
7
.
6
6
8
17.5 17.8
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 85.0
1
7
.
6
6
8
17.5 17.8
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
)
m/z 96.0
RT Mass Response Amount
17.67 83.00 4128 0.018510
17.67 85.00 8888
17.79 96.00 0
Reviewer: CJS9, 20-Mar-2024 15:31:18 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 357 of 864
Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
57 1,2-Dichloropropane, CAS: 78-87-5
Processing Results
20 30 40 50 60 70 80 90 100 110 120 130 140
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
0
)
Raw Spec:Scan 1701(12.26)
95 130
97
60
35 6247 94 9959
20 40 60 80 100 120 140
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1701(12.26), Qvalue=40
95 130
97
60
623547 999459
20 40 60 80 100 120 140
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 57 1,2-Dichloropropane (NIST14.L)
63
62
41
65
39 76
61 7838
12.0 12.3
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
m/z 63.0
1
2
.
2
5
9
12.0 12.3
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
m/z 62.0
1
2
.
2
6
5
12.0 12.3
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
m/z 65.0
1
2
.
2
6
5
RT Mass Response Amount
12.26 63.00 2611 0.037810
12.26 62.00 116374
12.26 65.00 11972
Reviewer: CJS9, 20-Mar-2024 15:30:02 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 358 of 864
Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
66 trans-1,3-Dichloropropene, CAS: 10061-02-6
Processing Results
20 30 40 50 60 70 80 90 100 110 120
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
0
)
Raw Spec:Scan 2097(14.39)
91
92
65394351 85
20 30 40 50 60 70 80 90 100 110 120
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2097(14.39), Qvalue=45
43
57
85
41
56 84
29 39 55
936970
20 30 40 50 60 70 80 90 100 110 120
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 66 trans-1,3-Dichloropropene (NIST14.L)
75
39
77
11049
112385173
14.0 14.3 14.6
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
m/z 75.0
1
4
.
3
9
5
14.0 14.3 14.6
Min
RT
0
7
14
21
28
35
Y ( X10
0
0
)
m/z 39.0
1
4
.
3
8
9
14.0 14.3 14.6
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
m/z 77.0
1
4
.
3
9
5
RT Mass Response Amount
14.39 75.00 5555 0.048528
14.39 39.00 91422
14.39 77.00 10147
Reviewer: CJS9, 20-Mar-2024 15:30:55 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 359 of 864
Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
38 Vinyl acetate, CAS: 108-05-4
Processing Results
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
6
12
18
24
30
36
Y ( X10
0
0
)
Raw Spec:Scan 916(8.03)
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 916(8.03), Qvalue=34
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 38 Vinyl acetate (NIST14.L)
43
8642
7.7 8.0 8.3
Min
RT
0
15
30
45
60
75
90
Y ( X10
0
)
m/z 43.0

8
.
0
2
6
7.7 8.0 8.3
Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
m/z 42.0

8
.
0
2
6
7.7 8.0 8.3
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 86.0

8
.
0
2
1
RT Mass Response Amount
8.03 43.00 26076 0.230582
8.03 42.00 8205
8.02 86.00 4062
Reviewer: CJS9, 20-Mar-2024 15:29:39 07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 360 of 864
Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Butane,2-methyl-78-78-4 NIST14.L 722 C5H12 72 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
5
10
15
20
25
Y ( X10
0
0
)
Raw Spec: Scan 406(5.28)
43
57
3929
56
72
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
5
10
15
20
25
Y ( X10
0
0
)
RZC19P114[MS SCAN Spec]:Scan 406(5.28) Bgrd 336( 4.90)
43
57
3929 56
72
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #722, Butane, 2-methyl- (from NIST14.L)
43
57
39 5629
72
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,2-methyl-107-83-5 NIST14.L 1846 C6H14 86 91
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
12
24
36
48
60
Y ( X10
0
0
)
Raw Spec: Scan 828(7.55)
43
42
71
39 5729 70
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
12
24
36
48
60
Y ( X10
0
0
)
RZC19P114[MS SCAN Spec]:Scan 828(7.55) Bgrd 760( 7.19)
43
42
71
39 5729 70
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1846, Pentane, 2-methyl- (from NIST14.L)
43
42
7139295770
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Pentane,3-methyl-96-14-0 NIST14.L 1847 C6H14 86 90
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
8
16
24
32
40
Y ( X10
0
0
)
Raw Spec: Scan 916(8.03)
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
8
16
24
32
40
Y ( X10
0
0
)
RZC19P114[MS SCAN Spec]:Scan 916(8.03) Bgrd 900( 7.94)
57
41
29
4339
55 71
20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1847, Pentane, 3-methyl- (from NIST14.L)
57
56
4129
43
39
55 71
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Page 363 of 864
Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)Raw Spec: Scan 1021(8.59)
43
57
4129 56 7239 86
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)RZC19P114[MS SCAN Spec]:Scan 1021(8.59) Bgrd 984( 8.39)
43
57
4129 56 7239 86
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)Raw Spec: Scan 1061(8.81)
45
592943
20 40 60 80 100 120 140 160 180 200 220 240
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)RZC19P114[MS SCAN Spec]:Scan 1061(8.81) Bgrd 984( 8.39)
45
592943
3/25/2024
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Page 365 of 864
Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Cyclopentane,methyl-96-37-7 NIST14.L 1512 C6H12 84 94
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
Raw Spec: Scan 1234(9.74)
56
41 69
5539
84295368
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
15
30
45
60
75
Y ( X10
0
0
)
RZC19P114[MS SCAN Spec]:Scan 1234(9.74) Bgrd 1200( 9.56)
56
41 69
5539
84295368
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #1512, Cyclopentane, methyl- (from NIST14.L)
56
41
69
39 55
842968
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
No Library Matches Found above the Threshold: 85
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 1615(11.80)
43
41 86567071
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P114[MS SCAN Spec]:Scan 1615(11.80) Bgrd 1442(10.86)
43
41 86567071
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Octane 111-65-9 NIST14.L 7758 C8H18 114 87
Heptane,2,4-dimethyl-2213-23-2 NIST14.L 12971 C9H20 128 86
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)Raw Spec: Scan 2223(15.07)
43
854157
71
29 5539 84 114
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
0
)RZC19P114[MS SCAN Spec]:Scan 2223(15.07) Bgrd 1658(12.03)
43
85
41 57 71
29 5539 84 114
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #7758, Octane (from NIST14.L)
43
41
5729 8571395584 114
20 30 40 50 60 70 80 90 100 110 120 130
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #12971, Heptane, 2,4-dimethyl- (from NIST14.L)
43
8541577129
84
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Decane 124-18-5 NIST14.L 19650 C10H22 142 91
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
4
8
12
16
Y ( X10
0
0
0
)Raw Spec: Scan 2952(19.01)
5743
41 71
852956703984 99 105 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
4
8
12
16
Y ( X10
0
0
0
)RZC19P114[MS SCAN Spec]:Scan 2952(19.01) Bgrd 1658(12.03)
5743
41 71
852956703984 99 142
20 30 40 50 60 70 80 90 100 110 120 130 140 150
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #19650, Decane (from NIST14.L)
43 57
41 71
29 85567039
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Report Date: 20-Mar-2024 15:31:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19P114.D
Injection Date:19-Mar-2024 23:21:30 Instrument ID:MR
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:14 Worklist Smp#:19
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:Detector MS SCAN
Library Search Compound Match CAS#Library Entry Formula Weight Q
Undecane 1120-21-4 NIST14.L 29356 C11H24 156 93
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
3
6
9
12
Y ( X10
0
0
0
)Raw Spec: Scan 3189(20.28)
5743
7141
85295570 1198498
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
3
6
9
12
Y ( X10
0
0
0
)RZC19P114[MS SCAN Spec]:Scan 3189(20.28) Bgrd 3118(19.90)
5743
7141
8529557084 11998 156
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Entry #29356, Undecane (from NIST14.L)
5743
41 71 85
29 56 70 84 98 99 156
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FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-5 Lab Sample ID:140-35862-5
Matrix:SZC21P110.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 16:30
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.45
Level: (low/med)Low
50(mL)
0.32(mm)
Date Analyzed:03/21/2024 18:50
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 230 130 25
60.1067-63-0 Isopropyl alcohol 2000 36 4.3
%RECCAS NO.LIMITSQSURROGATE
117 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:03072024-5 Lab Sample ID:140-35862-5
Matrix:SZC21P110.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
03/07/2024 16:30
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:4.45
Level: (low/med)Low
50(mL)
0.32(mm)
Date Analyzed:03/21/2024 18:50
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 540 320 59
60.1067-63-0 Isopropyl alcohol 4800 88 11
%RECCAS NO.LIMITSQSURROGATE
117 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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Report Date: 22-Mar-2024 14:07:34 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P110.D
Lims ID:140-35862-A-5
Client ID:03072024-5
Sample Type:Client
Inject. Date:21-Mar-2024 18:50:30 ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.4500
Sample Info:140-0032009-015
Misc. Info.:140-35862-a-5@4.45
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 14:07:33 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 14:07:33
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.921 9.915 0.006 74 179875 3.84
* 2 1,4-Difluorobenzene 114 12.035 12.035 0.000 95 832650 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.640 16.640 0.000 90 799623 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.249 18.248 0.001 94 680095 4.75
8 Dichlorodifluoromethane 85 4.240 4.245 -0.005 38 1977 0.0167
17 Ethanol 31 5.440 5.434 0.006 95 75296 7.11
23 Acetone 58 6.139 6.139 0.000 100 95401 5.13
24 Isopropyl alcohol 45 6.225 6.241 -0.016 98 2028495 44.0
31 Methylene Chloride 84 7.188 7.188 0.000 94 9184 0.2038
37 1,1-Dichloroethane 63 8.528 8.528 0.000 97 15322 0.1807
39 2-Butanone (MEK) 72 9.093 9.092 0.001 98 52234 2.38
40 Hexane 56 9.125 9.114 0.011 86 64670 1.82
42 cis-1,2-Dichloroethene 96 9.566 9.566 0.000 95 19968 0.3864
43 Ethyl acetate 43 9.722 9.727 -0.005 98 17408 0.1716
44 Chloroform 83 9.916 9.926 -0.010 32 1975 0.0190
46 Tetrahydrofuran 42 10.319 10.319 0.000 83 100683 2.02
47 1,1,1-Trichloroethane 97 10.959 10.965 -0.005 94 6481 0.0551
51 Benzene 78 11.529 11.535 -0.006 97 220851 1.59
50 Cyclohexane 69 11.535 11.535 0.000 50 19981 0.9292
56 n-Heptane 71 12.584 12.578 0.000 85 68655 1.49
58 Trichloroethene 130 12.729 12.723 0.000 94 596951 7.57
63 Methylcyclohexane 83 13.471 13.465 0.000 92 118224 1.31
64 4-Methyl-2-pentanone (MIBK) 43 13.837 13.837 0.000 97 50381 0.4739
67 Toluene 91 14.709 14.709 0.000 92 510852 2.62
73 Tetrachloroethene 129 15.822 15.828 -0.006 92 42657 0.5269
75 Chlorobenzene 112 16.694 16.688 0.006 83 3742 0.0228
76 Ethylbenzene 91 16.957 16.957 0.000 99 86888 0.3367
77 m-Xylene & p-Xylene 91 17.113 17.113 0.000 98 270324 1.37
78 n-Nonane 57 17.490 17.490 0.000 81 83896 0.7594
81 o-Xylene 91 17.641 17.641 0.000 97 91708 0.4099
87 4-Ethyltoluene 105 18.878 18.878 0.000 91 40300 0.1174
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Report Date: 22-Mar-2024 14:07:34 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P110.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ppb v/v Flags
88 1,3,5-Trimethylbenzene 120 18.948 18.948 0.000 91 24307 0.1635
92 1,2,4-Trimethylbenzene 105 19.389 19.384 0.005 98 154556 0.5389
98 1,2,3-Trimethylbenzene 105 19.857 19.857 0.000 99 42722 0.1455
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
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Report Date: 22-Mar-2024 14:07:34 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P110.D
Injection Date:21-Mar-2024 18:50:30 Instrument ID:MS Operator ID:
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5 Worklist Smp#:15
Client ID:03072024-5
Purge Vol:500.000 mL Dil. Factor:4.4500 ALS Bottle#:10
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
Y ( X10
0
0
0
0
)
SZC21P110[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
9
1
6
)+
* 1
,4-
D
i
f
l
u
o
r
o
b
e
n
zen
e
( 1
2
.
0
3
0
)+
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6
.
6
4
0
)
$ 4
-
Bro
m
o
f
l
u
o
r
o
b
e
n
zen
e

(Su
r
r
)(
1
8
.
2
4
9
)+
3/25/2024
9:50:51 AM
Page 375 of 864
Report Date: 22-Mar-2024 14:07:34 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P110.D
Lims ID:140-35862-A-5
Client ID:03072024-5
Sample Type:Client
Inject. Date:21-Mar-2024 18:50:30 ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.4500
Sample Info:140-0032009-015
Misc. Info.:140-35862-a-5@4.45
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 14:07:33 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 14:07:33
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.75 116.53
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Report Date: 22-Mar-2024 14:07:34 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P110.D
Injection Date:21-Mar-2024 18:50:30 Instrument ID:MS
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
23 Acetone, CAS: 67-64-1
20 40 60 80 100 120 140 160 180
m/z
0
3
6
9
12
15
Y ( X10
0
0
0
)
Raw Spec:Scan 401(6.14)
43
58
42
20 40 60 80 100 120 140 160 180
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 401(6.14), Qvalue=100 Sig Qvalue=100
43
58
42
20 40 60 80 100 120 140 160 180
0
2
4
6
8
10
( X10
0
)
Ref Spec: 23 Acetone (NIST14.L)
43
58
42
20 40 60 80 100 120 140 160 180
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.140 min.(Qvalue:100)
5.6 5.9 6.2 6.5
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
0
)
m/z 58.0

6
.
1
3
9
5.6 5.9 6.2 6.5
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 43.0

6
.
1
3
9
5.6 5.9 6.2 6.5
Min
0
3
6
9
12
15
18
21
Y ( X10
0
0
0
)
m/z 58.0
m/z 43.0
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Report Date: 22-Mar-2024 14:07:34 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21P110.D
Injection Date:21-Mar-2024 18:50:30 Instrument ID:MS
Lims ID:140-35862-A-5 Lab Sample ID:140-35862-5
Client ID:03072024-5
Operator ID:ALS Bottle#:10 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:4.4500
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
24 Isopropyl alcohol, CAS: 67-63-0
20 40 60 80 100 120 140 160 180 200 220
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
0
)
Raw Spec:Scan 417(6.23)
45
43
20 40 60 80 100 120 140 160 180 200 220
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
0
0
)
Enhanced Spec:Scan 417(6.23) Bgrd 405( 6.16), Qvalue=98 Sig Qvalue=96
45
43
20 40 60 80 100 120 140 160 180 200 220
0
2
4
6
8
10
( X10
0
)
Ref Spec: 24 Isopropyl alcohol (NIST14.L)
45
43
20 40 60 80 100 120 140 160 180 200 220
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 417 @ 6.225 min.(Qvalue: 98)
43
5.7 6.0 6.3 6.6
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
0
0
)
m/z 45.0

6
.
2
2
5
5.7 6.0 6.3 6.6
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
m/z 43.0

6
.
2
2
5
5.7 6.0 6.3 6.6
Min
0
11
22
33
44
55
66
77
Y ( X10
0
0
0
)
m/z 45.0
m/z 43.0
3/25/2024
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Page 378 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
Calibration Files
LEVEL:LAB SAMPLE ID:LAB FILE ID:
1Level IC 140-84237/9 RZC05L1.D
2Level IC 140-84237/10 RZC05L2.D
3Level IC 140-84237/11 RZC05L3.D
4Level IC 140-84237/12 RZC05L4.D
5Level IC 140-84237/13 RZC05L5.D
6Level IC 140-84237/14 RZC05L6.D
7Level ICIS 140-84237/15 RZC05ICIS7.D
8Level IC 140-84237/7 RZC05L8.D
9Level IC 140-84237/5 RZC05L9.D
10Level IC 140-84237/3 RZC05L10.D
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Chlorodifluoromethane ++++++++++1.6692 1.7424 1.6557 Ave 4.7
1.6783 1.6553 1.5648 1.6506 1.4922
30.01.638
6
Propene +++++++++++++++0.7392 0.7326 Ave 4.0
0.7692 0.7549 0.7244 0.7508 0.6772
30.00.735
5
Dichlorodifluoromethane ++++++++++2.5531 3.0083 2.5782 Ave 8.0
2.7932 2.7596 2.4660 2.6535 2.3224
30.02.641
8
Chloromethane +++++++++++++++0.3431 0.3126 Ave 9.2
0.3081 0.2989 0.2683 0.2842 0.2648
30.00.297
1
1,2-Dichloro-1,1,2,2-tetrafluoroet
hane
+++++2.1805 2.0752 2.1537 2.0538 Ave 6.0
2.1587 2.0773 1.8969 1.9711 1.8250
30.02.043
6
Vinyl chloride +++++1.1268 1.1137 1.1970 1.0788 Ave 6.1
1.1168 1.0862 0.9897 1.0280 1.0072
30.01.082
7
Butane +++++++++++++++1.7310 1.5677 Ave 7.2
1.6014 1.5581 1.3986 1.4816 1.4432
30.01.540
2
1,3-Butadiene 0.8498 0.7415 0.7688 0.8519 0.7870 Ave 5.5
0.8261 0.8056 0.7283 0.7684 0.7589
30.00.788
6
Bromomethane ++++++++++1.1155 1.1994 1.1442 Ave 7.6
1.1549 1.0737 0.9732 1.0185 0.9919
30.01.083
9
Chloroethane 0.5209 0.5824 0.6046 0.6366 0.6011 Ave 8.0
0.6042 0.5705 0.4936 0.5262 0.5494
30.00.568
9
Ethanol +++++++++++++++0.5122 0.4905 Ave 8.5
0.4887 0.4861 0.3961 0.4351 0.4718
30.00.468
7
Vinyl bromide 1.1648 1.0351 1.1379 1.1669 1.1161 Ave 5.3
1.1148 1.0904 1.0243 1.0833 1.0016
30.01.093
5
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 379 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
2-Methylbutane +++++++++++++++1.1568 1.1015 Ave 4.8
1.1340 1.0773 1.1165 1.1553 1.0054
30.01.106
7
Trichlorofluoromethane +++++2.9132 2.8258 2.9911 2.8965 Ave 3.6
2.9418 2.8463 2.7276 2.8679 2.6684
30.02.853
2
Acrolein ++++++++++++++++++++0.2703 Ave 7.3
0.2801 0.2761 0.3151 0.3135 0.3138
30.00.294
8
Acetonitrile +++++++++++++++0.3557 0.3763 Ave 6.0
0.4162 0.4181 0.3939 0.4154 0.3851
30.00.394
4
Acetone +++++++++++++++0.5789 0.5656 Ave 11.1
0.5412 0.5935 0.4621 0.4837 0.4522
30.00.525
3
Pentane +++++0.1719 0.1742 0.2041 0.1997 Ave 7.6
0.2141 0.2062 0.1908 0.2102 0.1944
30.00.196
2
Isopropyl alcohol +++++++++++++++1.2573 1.2217 Ave 4.3
1.2717 1.3561 1.2592 1.3412 1.2163
30.01.274
8
Ethyl ether 1.0237 0.9924 0.9356 0.9902 0.9746 Ave 3.5
1.0115 1.0198 0.9986 1.0519 0.9524
30.00.995
1
1,1-Dichloroethene 1.1829 1.0722 1.0911 1.1696 1.1447 Ave 3.7
1.1338 1.1197 1.0818 1.1347 1.0611
30.01.119
2
Acrylonitrile +++++++++++++++0.5604 0.6234 Ave 9.6
0.7114 0.7033 0.6900 0.7479 0.7190
30.00.679
4
1,1,2-Trichloro-1,2,2-trifluoroeth
ane
+++++2.5005 2.4454 2.5692 2.4895 Ave 3.9
2.5666 2.4597 2.3419 2.4590 2.2755
30.02.456
4
tert-Butyl alcohol ++++++++++1.8516 1.8492 1.7853 Ave 5.6
1.9350 2.0853 1.9301 2.0858 1.9147
30.01.929
6
Methylene Chloride +++++++++++++++1.7532 1.3611 Ave 22.6
1.2061 1.1103 1.0028 1.0486 0.9858
30.01.209
7
3-Chloropropene ++++++++++1.4789 0.9407 0.9142 Ave 20.5
0.8921 1.0003 1.3409 1.0449 0.9363
30.01.068
5
Carbon disulfide +++++3.5035 3.3508 3.5487 3.3228 Ave 5.1
3.3806 3.2164 3.0420 3.2622 3.1006
30.03.303
1
trans-1,2-Dichloroethene +++++1.1564 1.1601 1.1768 1.1725 Ave 2.6
1.2144 1.1801 1.1205 1.1973 1.1308
30.01.167
6
2-Methylpentane 2.0869 2.0610 2.0788 2.1130 2.0935 Ave 2.4
2.1598 2.1439 2.0930 2.2377 2.1024
30.02.117
0
Methyl tert-butyl ether 3.0778 2.9648 2.9637 3.1293 3.0091 Ave 3.0
3.1814 3.1195 3.0428 3.2386 3.0188
30.03.074
6
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 380 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
1,1-Dichloroethane 2.0705 1.9243 1.9974 2.0609 2.0354 Ave 3.2
2.0820 2.0135 1.9206 2.0489 1.9214
30.02.007
5
Vinyl acetate +++++++++++++++1.8601 1.9651 Ave 10.5
2.0874 2.0478 2.0445 2.4365 2.4295
30.02.124
4
n-Hexane +++++0.8085 0.7901 0.8515 0.8227 Ave 3.3
0.8575 0.8426 0.7947 0.8600 0.8125
30.00.826
7
2-Butanone (MEK)+++++++++++++++0.4728 0.4948 Ave 7.7
0.5487 0.5935 0.5135 0.5591 0.5395
30.00.531
7
cis-1,2-Dichloroethene 1.3174 1.1908 1.1797 1.2704 1.2070 Ave 3.7
1.2675 1.2367 1.1935 1.2578 1.1884
30.01.230
9
Ethyl acetate +++++++++++++++2.1386 2.0654 Ave 5.5
2.3158 2.2764 2.2745 2.4509 2.2929
30.02.259
2
Chloroform 2.7554 2.6099 2.5377 2.6678 2.5762 Ave 3.7
2.6491 2.5433 2.4446 2.5998 2.4503
30.02.583
4
Tetrahydrofuran +++++++++++++++1.0544 1.0516 Ave 3.7
1.1091 1.1228 1.0996 1.1681 1.0860
30.01.098
8
1,1,1-Trichloroethane 2.6094 2.5332 2.4941 2.5387 2.4968 Ave 2.4
2.5743 2.5226 2.4487 2.6168 2.4449
30.02.527
9
1,2-Dichloroethane ++++++++++0.3103 0.3541 0.3390 Ave 5.1
0.3536 0.3494 0.3515 0.3718 0.3452
30.00.346
9
Cyclohexane +++++++++++++++0.1091 0.1089 Ave 4.1
0.1151 0.1165 0.1147 0.1221 0.1174
30.00.114
8
Benzene ++++++++++0.7870 0.7753 0.7466 Ave 2.4
0.7801 0.7652 0.7373 0.7695 0.7425
30.00.762
9
1-Butanol +++++++++++++++0.0357 0.0602 Lin2 0.9950
0.0792 0.0907 0.0920 0.1020 0.0958
0.9900-0.01
0
0.094
9
Carbon tetrachloride 0.5668 0.5280 0.5085 0.5078 0.4854 QuaF 0.9990
0.4045 0.5527 0.5561 0.5852 0.5262
0.99000.601
0
-0.004550
2,3-Dimethylpentane ++++++++++0.1450 0.1707 0.1672 Ave 5.7
0.1731 0.1711 0.1694 0.1764 0.1701
30.00.167
9
Thiophene 0.4398 0.4013 0.4188 0.4254 0.4256 Ave 3.5
0.4463 0.4370 0.4319 0.4549 0.4385
30.00.432
0
2,2,4-Trimethylpentane 1.2426 1.1403 1.0893 1.1539 1.1143 Ave 3.7
1.1455 1.1268 1.1200 1.1819 1.1343
30.01.144
9
n-Heptane 0.2357 0.2406 0.2291 0.2505 0.2495 Ave 5.9
0.2644 0.2639 0.2596 0.2750 0.2660
30.00.253
4
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 381 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
1,2-Dichloropropane 0.2758 0.2717 0.2786 0.2836 0.2784 Ave 1.8
0.2851 0.2773 0.2728 0.2875 0.2792
30.00.279
0
Trichloroethene 0.3748 0.3395 0.3452 0.3795 0.3566 Ave 3.8
0.3751 0.3636 0.3610 0.3724 0.3496
30.00.361
7
Dibromomethane +++++++++++++++0.3397 0.3254 Ave 2.7
0.3297 0.3206 0.3468 0.3320 0.3256
30.00.331
4
Bromodichloromethane ++++++++++0.4780 0.5694 0.5472 Ave 7.1
0.5708 0.5690 0.5675 0.6182 0.5854
30.00.563
2
1,4-Dioxane +++++++++++++++0.0980 0.1020 Ave 7.4
0.1136 0.1194 0.1117 0.1200 0.1104
30.00.110
7
Methyl methacrylate +++++++++++++++0.2391 0.2390 Ave 13.8
0.2921 0.2863 0.3155 0.3433 0.3222
30.00.291
1
Methylcyclohexane ++++++++++0.4075 0.4478 0.4418 Ave 5.0
0.4647 0.4581 0.4609 0.4843 0.4669
30.00.454
0
4-Methyl-2-pentanone (MIBK)+++++++++++++++0.4618 0.4823 Ave 8.5
0.5197 0.5312 0.5383 0.5914 0.5639
30.00.527
0
cis-1,3-Dichloropropene ++++++++++0.3594 0.4156 0.4105 Ave 8.9
0.4409 0.4442 0.4474 0.4820 0.4690
30.00.433
6
trans-1,3-Dichloropropene ++++++++++0.3538 0.4297 0.4098 Ave 10.2
0.4455 0.4645 0.4664 0.5035 0.4549
30.00.441
0
Toluene ++++++++++1.1226 1.1310 1.0716 Ave 3.6
1.1161 1.1113 1.0894 1.1192 1.0102
30.01.096
4
1,1,2-Trichloroethane ++++++++++0.3228 0.3308 0.3202 Ave 3.6
0.3385 0.3263 0.3164 0.3292 0.3001
30.00.323
0
2-Hexanone +++++++++++++++0.2480 0.2723 Ave 12.6
0.3158 0.3320 0.3209 0.3449 0.3575
30.00.313
1
Octane 0.3119 0.3061 0.3151 0.3347 0.3220 Ave 5.0
0.3435 0.3435 0.3402 0.3535 0.3465
30.00.331
7
C8 Range ++++++++++++++++++++2.3734 Ave 6.1
2.5104 2.4704 2.4928 2.6738 2.7989
30.02.553
3
Dibromochloromethane ++++++++++0.4086 0.6314 0.6249 Ave 15.3
0.6749 0.6847 0.6324 0.7276 0.6700
30.00.631
8
1,2-Dibromoethane (EDB)0.5882 0.5312 0.5094 0.5791 0.5734 Ave 6.3
0.6096 0.6058 0.6005 0.6294 0.5961
30.00.582
3
Tetrachloroethene +++++0.4013 0.3711 0.4123 0.4040 Ave 3.9
0.4052 0.3975 0.3909 0.3969 0.3666
30.00.394
0
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 382 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Chlorobenzene 0.9565 0.9006 0.8954 0.8968 0.8766 Ave 4.5
0.8978 0.8729 0.8468 0.8628 0.8040
30.00.881
0
Ethylbenzene 1.4828 1.3760 1.3532 1.3917 1.3518 Ave 3.2
1.4417 1.4280 1.4095 1.4665 1.4305
30.01.413
2
m-Xylene & p-Xylene 1.2009 1.0753 1.0350 1.0727 1.0788 Ave 4.2
1.1265 1.1246 1.1000 1.1481 1.0886
30.01.105
1
Nonane +++++++++++++++0.5514 0.5591 Ave 6.8
0.6118 0.6146 0.6115 0.6599 0.6517
30.00.608
6
Styrene ++++++++++0.6364 0.7165 0.7397 Ave 8.9
0.8040 0.8090 0.8081 0.8510 0.7937
30.00.769
8
Bromoform ++++++++++0.1771 0.6062 0.5987 Ave 30.2
0.6400 0.6678 0.4637 0.6925 0.5837
*30.00.553
7
o-Xylene 1.1960 1.0931 1.0790 1.1728 1.1389 Ave 3.5
1.1886 1.1764 1.1411 1.1897 1.1410
30.01.151
7
1,1,2,2-Tetrachloroethane 0.9010 0.8103 0.8307 0.8532 0.8424 Ave 3.4
0.8945 0.8773 0.8386 0.8786 0.8655
30.00.859
2
1,2,3-Trichloropropane 0.2432 0.2343 0.2386 0.2536 0.2466 Ave 3.2
0.2591 0.2529 0.2442 0.2565 0.2489
30.00.247
8
Isopropylbenzene +++++1.5562 1.4814 1.5324 1.4990 Ave 2.9
1.5975 1.5967 1.5597 1.6071 1.5310
30.01.551
2
Propylbenzene ++++++++++0.4025 0.4108 0.4256 Ave 4.6
0.4506 0.4516 0.4414 0.4583 0.4403
30.00.435
1
2-Chlorotoluene 0.3958 0.3512 0.3621 0.3972 0.3990 Ave 5.0
0.4118 0.4074 0.3932 0.4046 0.3834
30.00.390
6
4-Ethyltoluene 1.5835 1.4818 1.4834 1.5292 1.5595 Ave 4.6
1.6648 1.6587 1.6198 1.6763 1.6176
30.01.587
5
1,3,5-Trimethylbenzene +++++++++++++++0.6471 0.6445 Ave 2.8
0.6839 0.6735 0.6458 0.6822 0.6461
30.00.660
4
Alpha Methyl Styrene +++++++++++++++0.5290 0.5834 Ave 11.4
0.6654 0.6533 0.6733 0.7524 0.7054
30.00.651
7
Decane +++++++++++++++0.7751 0.8007 Ave 4.9
0.8506 0.8341 0.8510 0.9040 0.8339
30.00.835
6
tert-Butylbenzene 1.4998 1.3602 1.3618 1.4171 1.4178 Ave 5.2
1.5067 1.5080 1.4407 1.4889 1.2912
30.01.429
2
1,2,4-Trimethylbenzene 1.3921 1.2614 1.2994 1.3514 1.3725 Ave 5.5
1.4608 1.4343 1.3966 1.4391 1.2476
30.01.365
5
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 383 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
sec-Butylbenzene 1.9634 1.8341 1.8394 1.9116 1.9280 Ave 5.1
2.0908 2.0768 2.0086 2.1023 1.8930
30.01.964
8
1,3-Dichlorobenzene +++++0.9577 0.9682 0.9735 0.9734 Ave 4.3
1.0031 0.9758 0.9117 0.9589 0.8663
30.00.954
3
Benzyl chloride 1.1981 1.0149 0.9920 0.9519 1.0015 Ave 9.9
1.1343 1.1740 1.2009 1.2729 1.1506
30.01.109
1
1,4-Dichlorobenzene +++++1.0150 0.9815 0.9822 0.9522 Ave 5.9
1.0134 0.9756 0.9085 0.9427 0.8349
30.00.956
2
4-Isopropyltoluene 1.6334 1.5455 1.5637 1.6407 1.6958 Ave 5.7
1.8172 1.7598 1.6957 1.7576 1.5583
30.01.666
8
1,2,3-Trimethylbenzene 1.3432 1.2990 1.2608 1.3655 1.3819 Ave 5.4
1.4747 1.4520 1.4345 1.4867 1.3626
30.01.386
1
Indane 1.4075 1.1915 1.2520 1.3154 1.3389 Ave 6.8
1.4285 1.3957 1.3785 1.3507 1.1747
30.01.323
3
1,2-Dichlorobenzene +++++0.9303 0.9375 0.9690 0.9539 Ave 6.9
1.0014 0.9560 0.9200 0.9001 0.7753
30.00.927
1
Butylbenzene 1.7325 1.5660 1.6633 1.6806 1.7169 Ave 5.4
1.8157 1.7595 1.7394 1.7108 1.5078
30.01.689
2
Indene 1.0025 0.9288 0.9348 1.0369 1.0959 Ave 9.7
1.2094 1.1728 1.1810 1.1768 1.0485
30.01.078
8
Undecane 0.9624 0.9106 0.9423 0.9374 0.9855 Ave 5.4
1.0661 0.9978 1.0465 1.0432 0.9544
30.00.984
6
1,2-Dibromo-3-Chloropropane ++++++++++0.2329 0.4619 0.4762 Ave 24.8
0.5212 0.5515 0.3577 0.5808 0.5178
30.00.462
5
1,2,4,5-Tetramethylbenzene 1.7943 1.6054 1.6472 1.6041 1.7026 Ave 4.9
1.8248 1.7029 1.7569 1.7606 1.5950
30.01.699
4
Dodecane +++++++++++++++1.2233 1.3389 Ave 13.9
1.4298 1.0745 1.1168 1.0692 0.9702
30.01.174
7
1,2,4-Trichlorobenzene ++++++++++1.0659 0.9247 0.9227 Ave 13.4
0.9768 0.8249 0.8067 0.7765 0.7058
30.00.875
5
Naphthalene +++++++++++++++2.0962 2.1744 Ave 12.3
2.3054 1.9468 1.8464 1.7407 1.6334
30.01.963
3
Hexachlorobutadiene ++++++++++1.0703 0.8723 0.8466 QuaF 0.9960
0.8405 0.6466 0.5547 ++++++++++
0.99000.819
2
-0.066973
1,2,3-Trichlorobenzene ++++++++++++++++++++0.8680 Ave 24.0
0.8949 0.7110 0.6317 0.5413 0.4955
30.00.690
4
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 384 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
2-Methylnaphthalene +++++++++++++++1.0670 1.2122 Ave 17.8
1.4328 1.1574 1.0580 0.9569 0.8166
50.01.100
1
1-Methylnaphthalene ++++++++++++++++++++1.4363 Ave 25.8
1.5655 1.1893 1.0580 0.9198 0.7869
50.01.159
3
4-Bromofluorobenzene (Surr)0.7182 0.7189 0.7190 0.7239 0.7171 Ave 2.0
0.7317 0.7426 0.7352 0.7440 0.7605
30.00.731
1
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 385 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
GC Column:RTX-5 ID:0.32(mm)
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
Level 1 IC 140-84237/9 RZC05L1.D
Level 2 IC 140-84237/10 RZC05L2.D
Level 3 IC 140-84237/11 RZC05L3.D
Level 4 IC 140-84237/12 RZC05L4.D
Level 5 IC 140-84237/13 RZC05L5.D
Level 6 IC 140-84237/14 RZC05L6.D
Level 7 ICIS 140-84237/15 RZC05ICIS7.D
Level 8 IC 140-84237/7 RZC05L8.D
Level 9 IC 140-84237/5 RZC05L9.D
Level 10 IC 140-84237/3 RZC05L10.D
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Chlorodifluoromethane AveCBM ++++++++++7236 15284 35196 ++++++++++0.0800 0.160 0.400
89988 16.08.004.002.001.001292647763157388911183918
Propene AveCBM +++++++++++++++6484 15573 +++++++++++++++0.160 0.400
41243 16.08.004.002.001.0058666734711118002983868
Dichlorodifluoromethane AveCBM ++++++++++11068 26389 54804 ++++++++++0.0800 0.160 0.400
149762 16.08.004.002.001.0020117461226838612888306604
Chloromethane AveCBM +++++++++++++++3010 6645 +++++++++++++++0.160 0.400
16519 16.08.004.002.001.002293711314206667633206
1,2-Dichloro-1,1,2,2-tetrafluoroeth
ane
AveCBM +++++4946 8996 18892 43658 +++++0.0400 0.0800 0.160 0.400
115742 16.08.004.002.001.001580949911331471448230795
Vinyl chloride AveCBM +++++2556 4828 10500 22932 +++++0.0400 0.0800 0.160 0.400
59878 16.08.004.002.001.00872510475316245969120678
Butane AveCBM +++++++++++++++15184 33324 +++++++++++++++0.160 0.400
85864 16.08.004.002.001.001250210685014347615173118
1,3-Butadiene AveCBM 1036 1682 3333 7473 16729 0.0200 0.0400 0.0800 0.160 0.400
44292 16.08.004.002.001.0065738135526718101889503
Bromomethane AveCBM ++++++++++4836 10521 24323 ++++++++++0.0800 0.160 0.400
61925 16.08.004.002.001.00859263470927241871119297
Chloroethane AveCBM 635 1321 2621 5584 12777 0.0200 0.0400 0.0800 0.160 0.400
32398 16.08.004.002.001.0047593824327512267063380
Ethanol AveCBM +++++++++++++++22466 52136 +++++++++++++++0.800 2.00
131022 80.040.020.010.05.0020433661005910492283270040
Vinyl bromide AveCBM 1420 2348 4933 10236 23725 0.0200 0.0400 0.0800 0.160 0.400
59773 16.08.004.002.001.00867677500886254581121147
2-Methylbutane AveCBM +++++++++++++++10147 23415 +++++++++++++++0.160 0.400
60804 16.08.004.002.001.00870968534166277486119693
Trichlorofluoromethane AveCBM +++++6608 12250 26238 61570 +++++0.0400 0.0800 0.160 0.400
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 386 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
157732 16.08.004.002.001.0023114821326001677902316243
Acrolein AveCBM ++++++++++++++++++++5746 ++++++++++++++++++++0.400
15016 16.08.004.002.001.002718631449427831030677
Acetonitrile AveCBM +++++++++++++++3120 8000 +++++++++++++++0.160 0.400
22316 16.08.004.002.001.003335891920739790946451
Acetone AveCBM +++++++++++++++15234 36067 +++++++++++++++0.480 1.20
87049 48.024.012.06.003.001175060670882344578197820
Pentane AveCBM +++++390 755 1790 4244 +++++0.0400 0.0800 0.160 0.400
11480 16.08.004.002.001.00168361971824742822915
Isopropyl alcohol AveCBM +++++++++++++++33087 77910 +++++++++++++++0.480 1.20
204549 48.024.012.06.003.0031609641860388938886451994
Ethyl ether AveCBM 1248 2251 4056 8686 20718 0.0200 0.0400 0.0800 0.160 0.400
54234 16.08.004.002.001.00825039486346248196113307
1,1-Dichloroethene AveCBM 1442 2432 4730 10260 24332 0.0200 0.0400 0.0800 0.160 0.400
60793 16.08.004.002.001.00919225524615268858124401
Acrylonitrile AveCBM +++++++++++++++4916 13252 +++++++++++++++0.160 0.400
38144 16.08.004.002.001.0062284134578717148878143
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
AveCBM +++++5672 10601 22537 52919 +++++0.0400 0.0800 0.160 0.400
137614 16.08.004.002.001.0019711761136926582049273288
tert-Butyl alcohol AveCBM ++++++++++8027 16221 37950 ++++++++++0.0800 0.160 0.400
103747 16.08.004.002.001.001658598964366479699231690
Methylene Chloride AveCBM +++++++++++++++15379 28932 +++++++++++++++0.160 0.400
64666 16.08.004.002.001.00853965484843249242123355
3-Chloropropene AveCBM ++++++++++6411 8252 19433 ++++++++++0.0800 0.160 0.400
47832 16.08.004.002.001.00811043483117333270111140
Carbon disulfide AveCBM +++++7947 14526 31129 70633 +++++0.0400 0.0800 0.160 0.400
181259 16.08.004.002.001.0026859181508275756047357362
trans-1,2-Dichloroethene AveCBM +++++2623 5029 10323 24924 +++++0.0400 0.0800 0.160 0.400
65113 16.08.004.002.001.00979559553580278476131112
2-Methylpentane AveCBM 2544 4675 9012 18535 44502 0.0200 0.0400 0.0800 0.160 0.400
115804 16.08.004.002.001.0018212011034617520179238200
Methyl tert-butyl ether AveCBM 3752 6725 12848 27450 63963 0.0200 0.0400 0.0800 0.160 0.400
170579 16.08.004.002.001.0026150861497370756240346597
1,1-Dichloroethane AveCBM 2524 4365 8659 18078 43266 0.0200 0.0400 0.0800 0.160 0.400
111633 16.08.004.002.001.001664397947336477330223705
Vinyl acetate AveCBM +++++++++++++++16317 41772 +++++++++++++++0.160 0.400
111923 16.08.004.002.001.0021045821126537508123227526
n-Hexane AveCBM +++++1834 3425 7469 17489 +++++0.0400 0.0800 0.160 0.400
45977 16.08.004.002.001.0070383139761019752393613
2-Butanone (MEK)AveCBM +++++++++++++++4147 10518 +++++++++++++++0.160 0.400
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 387 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
29419 16.08.004.002.001.0046735925848112761765946
cis-1,2-Dichloroethene AveCBM 1606 2701 5114 11144 25658 0.0200 0.0400 0.0800 0.160 0.400
67958 16.08.004.002.001.001029497581553296624137404
Ethyl acetate AveCBM +++++++++++++++18760 43904 +++++++++++++++0.160 0.400
124168 16.08.004.002.001.0019862491133200565296252920
Chloroform AveCBM 3359 5920 11001 23402 54762 0.0200 0.0400 0.0800 0.160 0.400
142037 16.08.004.002.001.0021225711202016607576282571
Tetrahydrofuran AveCBM +++++++++++++++9249 22353 +++++++++++++++0.160 0.400
59469 16.08.004.002.001.00940763540076273282124753
1,1,1-Trichloroethane AveCBM 3181 5746 10812 22269 53075 0.0200 0.0400 0.0800 0.160 0.400
138025 16.08.004.002.001.0021178621209865608597280276
1,2-Dichloroethane AveDFBZ ++++++++++6289 14429 33630 ++++++++++0.0800 0.160 0.400
88474 16.08.004.002.001.001362128786365394308181239
Cyclohexane AveDFBZ +++++++++++++++4448 10800 +++++++++++++++0.160 0.400
28790 16.08.004.002.001.0046343825823512861260432
Benzene AveDFBZ ++++++++++15949 31598 74072 ++++++++++0.0800 0.160 0.400
195158 16.08.004.002.001.0029299151627489826949396945
1-Butanol Lin2DFBZ +++++++++++++++1453 5971 +++++++++++++++0.160 0.400
19818 16.08.004.002.001.0037788721566810314647044
Carbon tetrachloride QuaFDFBZ 3191 5596 10305 20696 48158 0.0200 0.0400 0.0800 0.160 0.400
101197 16.08.004.002.001.0020763391237738623731286721
2,3-Dimethylpentane AveDFBZ ++++++++++2939 6955 16586 ++++++++++0.0800 0.160 0.400
43297 16.08.004.002.001.0067115037319719003888747
Thiophene AveDFBZ 2476 4254 8487 17337 42227 0.0200 0.0400 0.0800 0.160 0.400
111657 16.08.004.002.001.001730388962215484395226682
2,2,4-Trimethylpentane AveDFBZ 6996 12086 22075 47024 110560 0.0200 0.0400 0.0800 0.160 0.400
286572 16.08.004.002.001.00447597524997791256294584496
n-Heptane AveDFBZ 1327 2550 4642 10208 24759 0.0200 0.0400 0.0800 0.160 0.400
66150 16.08.004.002.001.001049532581659291204136908
1,2-Dichloropropane AveDFBZ 1553 2880 5646 11557 27617 0.0200 0.0400 0.0800 0.160 0.400
71323 16.08.004.002.001.001101580608087305970143855
Trichloroethene AveDFBZ 2110 3598 6996 15467 35381 0.0200 0.0400 0.0800 0.160 0.400
93838 16.08.004.002.001.001379425787574404898188637
Dibromomethane AveDFBZ +++++++++++++++13844 32284 +++++++++++++++0.160 0.400
82480 16.08.004.002.001.001284908702216389010166311
Bromodichloromethane AveDFBZ ++++++++++9687 23205 54288 ++++++++++0.0800 0.160 0.400
142808 16.08.004.002.001.0023098001307482636560295147
1,4-Dioxane AveDFBZ +++++++++++++++3994 10122 +++++++++++++++0.160 0.400
28409 16.08.004.002.001.0043571025381312532361917
Methyl methacrylate AveDFBZ +++++++++++++++9745 23715 +++++++++++++++0.160 0.400
73087 16.08.004.002.001.001271585725998353896148511
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 388 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Methylcyclohexane AveDFBZ ++++++++++8258 18250 43835 ++++++++++0.0800 0.160 0.400
116263 16.08.004.002.001.0018424011024351516995237648
4-Methyl-2-pentanone (MIBK)AveDFBZ +++++++++++++++18821 47855 +++++++++++++++0.160 0.400
130021 16.08.004.002.001.0022251121250855603822275569
cis-1,3-Dichloropropene AveDFBZ ++++++++++7283 16937 40730 ++++++++++0.0800 0.160 0.400
110310 16.08.004.002.001.0018505621019356501794230442
trans-1,3-Dichloropropene AveCBZd5 ++++++++++6176 15068 35112 ++++++++++0.0800 0.160 0.400
96409 16.08.004.002.001.001708905955776462650207949
Toluene AveCBZd5 ++++++++++19599 39658 91825 ++++++++++0.0800 0.160 0.400
241531 16.08.004.002.001.00379500121246131080512497509
1,1,2-Trichloroethane AveCBZd5 ++++++++++5635 11599 27442 ++++++++++0.0800 0.160 0.400
73260 16.08.004.002.001.001127330624836313873146088
2-Hexanone AveCBZd5 +++++++++++++++8697 23332 +++++++++++++++0.160 0.400
68334 16.08.004.002.001.001342916654713318297148627
Octane AveCBZd5 1499 2788 5501 11734 27592 0.0200 0.0400 0.0800 0.160 0.400
74324 16.08.004.002.001.001301774671112337465153800
C8 Range AveDFBZ ++++++++++++++++++++235481 ++++++++++++++++++++0.400
628036 16.08.004.002.001.0011044334565515827961031281480
Dibromochloromethane AveCBZd5 ++++++++++7133 22138 53545 ++++++++++0.0800 0.160 0.400
146050 16.08.004.002.001.0025167261381155627250306552
1,2-Dibromoethane (EDB)AveCBZd5 2827 4839 8894 20304 49132 0.0200 0.0400 0.0800 0.160 0.400
131914 16.08.004.002.001.0022391191194759595648271197
Tetrachloroethene AveCBZd5 +++++3656 6478 14458 34617 +++++0.0400 0.0800 0.160 0.400
87686 16.08.004.002.001.001377300753353387691177938
Chlorobenzene AveCBZd5 4597 8204 15633 31444 75115 0.0200 0.0400 0.0800 0.160 0.400
194275 16.08.004.002.001.0030202411637947839896390774
Ethylbenzene AveCBZd5 7126 12534 23625 48799 115833 0.0200 0.0400 0.0800 0.160 0.400
311978 16.08.004.002.001.00537357327839561398052639329
m-Xylene & p-Xylene AveCBZd5 11543 19591 36139 75227 184881 0.0400 0.0800 0.160 0.320 0.800
487559 32.016.08.004.002.008178477435873521821531006981
Nonane AveCBZd5 +++++++++++++++19334 47910 +++++++++++++++0.160 0.400
132388 16.08.004.002.001.0024480001252624606542275133
Styrene AveCBZd5 ++++++++++11110 25124 63386 ++++++++++0.0800 0.160 0.400
173987 16.08.004.002.001.0029814331615397801534362190
Bromoform AveCBZd5 ++++++++++3092 21257 51300 ++++++++++0.0800 0.160 0.400
138487 16.08.004.002.001.0021926881314557459967298962
o-Xylene AveCBZd5 5748 9957 18838 41123 97596 0.0200 0.0400 0.0800 0.160 0.400
257210 16.08.004.002.001.00428630322584861131819526663
1,1,2,2-Tetrachloroethane AveCBZd5 4330 7381 14503 29916 72181 0.0200 0.0400 0.0800 0.160 0.400
193562 16.08.004.002.001.0032513811667875831748392760
1,2,3-Trichloropropane AveCBZd5 1169 2134 4165 8892 21130 0.0200 0.0400 0.0800 0.160 0.400
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 389 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
56074 16.08.004.002.001.00935064486978242208113214
Isopropylbenzene AveCBZd5 +++++14176 25863 53731 128446 +++++0.0400 0.0800 0.160 0.400
345693 16.08.004.002.001.00575119930507781546990714828
Propylbenzene AveCBZd5 ++++++++++7027 14405 36471 ++++++++++0.0800 0.160 0.400
97499 16.08.004.002.001.001654136869954437796202171
2-Chlorotoluene AveCBZd5 1902 3199 6321 13928 34193 0.0200 0.0400 0.0800 0.160 0.400
89112 16.08.004.002.001.001440137768128390016182376
4-Ethyltoluene AveCBZd5 7610 13498 25898 53620 133633 0.0200 0.0400 0.0800 0.160 0.400
360252 16.08.004.002.001.00607636331822181606649742604
1,3,5-Trimethylbenzene AveCBZd5 +++++++++++++++22689 55230 +++++++++++++++0.160 0.400
147986 16.08.004.002.001.0024269961295115640522301523
Alpha Methyl Styrene AveCBZd5 +++++++++++++++18550 49995 +++++++++++++++0.160 0.400
143997 16.08.004.002.001.0026497091428216667838292476
Decane AveCBZd5 +++++++++++++++27178 68612 +++++++++++++++0.160 0.400
184073 16.08.004.002.001.0031325021715990844074373410
tert-Butylbenzene AveCBZd5 7208 12390 23775 49688 121490 0.0200 0.0400 0.0800 0.160 0.400
326056 16.08.004.002.001.00485032428263501428935675129
1,2,4-Trimethylbenzene AveCBZd5 6690 11490 22685 47385 117611 0.0200 0.0400 0.0800 0.160 0.400
316106 16.08.004.002.001.00468662427318761385185642130
sec-Butylbenzene AveCBZd5 9436 16707 32113 67026 165209 0.0200 0.0400 0.0800 0.160 0.400
452452 16.08.004.002.001.00711097239908291992290929757
1,3-Dichlorobenzene AveCBZd5 +++++8724 16903 34135 83409 +++++0.0400 0.0800 0.160 0.400
217064 16.08.004.002.001.0032541321820256904283436880
Benzyl chloride AveCBZd5 5758 9245 17319 33377 85820 0.0200 0.0400 0.0800 0.160 0.400
245455 16.08.004.002.001.00432208124164291191119525603
1,4-Dichlorobenzene AveCBZd5 +++++9246 17136 34438 81596 +++++0.0400 0.0800 0.160 0.400
219305 16.08.004.002.001.0031363181789598901108436795
4-Isopropyltoluene AveCBZd5 7850 14078 27300 57529 145317 0.0200 0.0400 0.0800 0.160 0.400
393232 16.08.004.002.001.00585392933364501681941787879
1,2,3-Trimethylbenzene AveCBZd5 6455 11833 22011 47880 118418 0.0200 0.0400 0.0800 0.160 0.400
319114 16.08.004.002.001.00511854328222531422835650074
Indane AveCBZd5 6764 10854 21858 46124 114728 0.0200 0.0400 0.0800 0.160 0.400
309127 16.08.004.002.001.00441273225639801367300624853
1,2-Dichlorobenzene AveCBZd5 +++++8474 16367 33977 81743 +++++0.0400 0.0800 0.160 0.400
216710 16.08.004.002.001.0029123431708763912517428020
Butylbenzene AveCBZd5 8326 14265 29038 58926 147118 0.0200 0.0400 0.0800 0.160 0.400
392927 16.08.004.002.001.00566392032476911725264787730
Indene AveCBZd5 4818 8461 16320 36359 93904 0.0200 0.0400 0.0800 0.160 0.400
261710 16.08.004.002.001.00393885022339681171418525063
Undecane AveCBZd5 4625 8295 16451 32868 84451 0.0200 0.0400 0.0800 0.160 0.400
230702 16.08.004.002.001.00358518719803611038024446705
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 390 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
1,2-Dibromo-3-Chloropropane AveCBZd5 ++++++++++4066 16196 40808 ++++++++++0.0800 0.160 0.400
112786 16.08.004.002.001.0019452961102624354793246902
1,2,4,5-Tetramethylbenzene AveCBZd5 8623 14624 28758 56244 145893 0.0200 0.0400 0.0800 0.160 0.400
394877 16.08.004.002.001.00599178333422491742628762363
Dodecane AveCBZd5 +++++++++++++++42893 114730 +++++++++++++++0.160 0.400
309404 16.08.004.002.001.00364471920296071107709481067
1,2,4-Trichlorobenzene AveCBZd5 ++++++++++18608 32424 79063 ++++++++++0.0800 0.160 0.400
211384 16.08.004.002.001.0026512051474036800097369308
Naphthalene AveCBZd5 +++++++++++++++73500 186320 +++++++++++++++0.160 0.400
498878 16.08.004.002.001.00613578633044071831340871593
Hexachlorobutadiene QuaFCBZd5 ++++++++++18686 30585 72546 ++++++++++0.0800 0.160 0.400
181894 ++++++++++4.002.001.00++++++++++550136289470
1,2,3-Trichlorobenzene AveCBZd5 ++++++++++++++++++++74381 ++++++++++++++++++++0.400
193654 16.08.004.002.001.0018613761027493626533318309
2-Methylnaphthalene AveCBZd5 +++++++++++++++37416 103875 +++++++++++++++0.160 0.400
310076 16.08.004.002.001.00306768218165251049457518202
1-Methylnaphthalene AveCBZd5 ++++++++++++++++++++123079 ++++++++++++++++++++0.400
338783 16.08.004.002.001.00295631817461251049478532472
4-Bromofluorobenzene (Surr)AveCBZd5 704159 667978 640155 647263 626743 4.08 4.08 4.08 4.08 4.08
646045 4.084.084.084.084.08728484720324743821678199
Curve Type Legend:
Ave = Average ISTD
Lin2 = Linear 1/conc^2 ISTD
QuaF = Quadratic ISTD forced zero
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 391 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
1Level IC 140-84237/9 RZC05L1.D
2Level IC 140-84237/10 RZC05L2.D
3Level IC 140-84237/11 RZC05L3.D
4Level IC 140-84237/12 RZC05L4.D
5Level IC 140-84237/13 RZC05L5.D
6Level IC 140-84237/14 RZC05L6.D
7Level ICIS 140-84237/15 RZC05ICIS7.D
8Level IC 140-84237/7 RZC05L8.D
9Level IC 140-84237/5 RZC05L9.D
10Level IC 140-84237/3 RZC05L10.D
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Chlorodifluoromethane ++++++++++1.9 6.3 1.0 2.4
1.0 -4.5 0.7 -8.9
50 40 40 40
40 40 40 40
Propene +++++++++++++++0.5 -0.4 4.6
2.6 -1.5 2.1 -7.9
50 40 40
40 40 40 40
Dichlorodifluoromethane ++++++++++-3.4 13.9 -2.4 5.7
4.5 -6.7 0.4 -12.1
50 40 40 40
40 40 40 40
Chloromethane +++++++++++++++15.5 5.2 3.7
0.6 -9.7 -4.3 -10.9
50 40 40
40 40 40 40
1,2-Dichloro-1,1,2,2-tetrafluoroethane +++++6.7 1.5 5.4 0.5 5.6
1.6 -7.2 -3.5 -10.7
50 40 40 40 40
40 40 40 40
Vinyl chloride +++++4.1 2.9 10.6 -0.4 3.1
0.3 -8.6 -5.0 -7.0
50 40 40 40 40
40 40 40 40
Butane +++++++++++++++12.4 1.8 4.0
1.2 -9.2 -3.8 -6.3
50 40 40
40 40 40 40
1,3-Butadiene 7.8 -6.0 -2.5 8.0 -0.2 4.7
2.1 -7.6 -2.6 -3.8
50 40 40 40 40 40
40 40 40 40
Bromomethane ++++++++++2.9 10.7 5.6 6.6
-0.9 -10.2 -6.0 -8.5
50 40 40 40
40 40 40 40
Chloroethane -8.4 2.4 6.3 11.9 5.6 6.2
0.3 -13.2 -7.5 -3.4
50 40 40 40 40 40
40 40 40 40
Ethanol +++++++++++++++9.3 4.7 4.3
3.7 -15.5 -7.2 0.7
50 40 40
40 40 40 40
Vinyl bromide 6.5 -5.3 4.1 6.7 2.1 1.9
-0.3 -6.3 -0.9 -8.4
50 40 40 40 40 40
40 40 40 40
2-Methylbutane +++++++++++++++4.5 -0.5 2.5
-2.7 0.9 4.4 -9.1
50 40 40
40 40 40 40
Trichlorofluoromethane +++++2.1 -1.0 4.8 1.5 3.1
-0.2 -4.4 0.5 -6.5
50 40 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 392 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Acrolein ++++++++++++++++++++-8.3 -5.0
-6.3 6.9 6.3 6.5
50 40
40 40 40 40
Acetonitrile +++++++++++++++-9.8 -4.6 5.5
6.0 -0.1 5.3 -2.4
50 40 40
40 40 40 40
Acetone +++++++++++++++10.2 7.7 3.0
13.0 -12.0 -7.9 -13.9
80 50 50
50 50 50 50
Pentane +++++-12.4 -11.2 4.0 1.8 9.1
5.1 -2.7 7.1 -0.9
50 40 40 40 40
40 40 40 40
Isopropyl alcohol +++++++++++++++-1.4 -4.2 -0.2
6.4 -1.2 5.2 -4.6
50 40 40
40 40 40 40
Ethyl ether 2.9 -0.3 -6.0 -0.5 -2.1 1.7
2.5 0.4 5.7 -4.3
50 40 40 40 40 40
40 40 40 40
1,1-Dichloroethene 5.7 -4.2 -2.5 4.5 2.3 1.3
0.0 -3.3 1.4 -5.2
50 40 40 40 40 40
40 40 40 40
Acrylonitrile +++++++++++++++-17.5 -8.2 4.7
3.5 1.6 10.1 5.8
50 40 40
40 40 40 40
1,1,2-Trichloro-1,2,2-trifluoroethane +++++1.8 -0.4 4.6 1.3 4.5
0.1 -4.7 0.1 -7.4
50 40 40 40 40
40 40 40 40
tert-Butyl alcohol ++++++++++-4.0 -4.2 -7.5 0.3
8.1 0.0 8.1 -0.8
50 40 40 40
40 40 40 40
Methylene Chloride +++++++++++++++44.9 12.5 -0.3
-8.2 -17.1 -13.3 -18.5
80 50 50
50 50 50 50
3-Chloropropene ++++++++++38.4 -12.0 -14.4 -16.5
-6.4 25.5 -2.2 -12.4
50 40 40 40
40 40 40 40
Carbon disulfide +++++6.1 1.4 7.4 0.6 2.3
-2.6 -7.9 -1.2 -6.1
50 40 40 40 40
40 40 40 40
trans-1,2-Dichloroethene +++++-1.0 -0.6 0.8 0.4 4.0
1.1 -4.0 2.5 -3.2
50 40 40 40 40
40 40 40 40
2-Methylpentane -1.4 -2.6 -1.8 -0.2 -1.1 2.0
1.3 -1.1 5.7 -0.7
50 40 40 40 40 40
40 40 40 40
Methyl tert-butyl ether 0.1 -3.6 -3.6 1.8 -2.1 3.5
1.5 -1.0 5.3 -1.8
50 40 40 40 40 40
40 40 40 40
1,1-Dichloroethane 3.1 -4.1 -0.5 2.7 1.4 3.7
0.3 -4.3 2.1 -4.3
50 40 40 40 40 40
40 40 40 40
Vinyl acetate +++++++++++++++-12.4 -7.5 -1.7
-3.6 -3.8 14.7 14.4
50 40 40
40 40 40 40
n-Hexane +++++-2.2 -4.4 3.0 -0.5 3.7
1.9 -3.9 4.0 -1.7
50 50 50 50 50
50 50 50 50
2-Butanone (MEK)+++++++++++++++-11.1 -6.9 3.2
11.6 -3.4 5.1 1.5
50 40 40
40 40 40 40
cis-1,2-Dichloroethene 7.0 -3.3 -4.2 3.2 -1.9 3.0
0.5 -3.0 2.2 -3.5
50 40 40 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 393 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Ethyl acetate +++++++++++++++-5.3 -8.6 2.5
0.8 0.7 8.5 1.5
50 40 40
40 40 40 40
Chloroform 6.7 1.0 -1.8 3.3 -0.3 2.5
-1.6 -5.4 0.6 -5.2
50 40 40 40 40 40
40 40 40 40
Tetrahydrofuran +++++++++++++++-4.0 -4.3 0.9
2.2 0.1 6.3 -1.2
50 40 40
40 40 40 40
1,1,1-Trichloroethane 3.2 0.2 -1.3 0.4 -1.2 1.8
-0.2 -3.1 3.5 -3.3
50 40 40 40 40 40
40 40 40 40
1,2-Dichloroethane ++++++++++-10.5 2.1 -2.3 2.0
0.7 1.3 7.2 -0.5
50 40 40 40
40 40 40 40
Cyclohexane +++++++++++++++-4.9 -5.2 0.2
1.5 -0.1 6.3 2.3
50 40 40
40 40 40 40
Benzene ++++++++++3.2 1.6 -2.1 2.2
0.3 -3.4 0.9 -2.7
50 40 40 40
40 40 40 40
1-Butanol +++++++++++++++4.6 -9.8 -5.8
0.9 -0.4 8.8 1.6
50 40 40
40 40 40 40
Carbon tetrachloride -5.7 -12.1 -15.4 -15.4 -19.0 -32.4
-6.7 -4.7 3.9 -0.4
50 40 40 40 40 40
40 40 40 40
2,3-Dimethylpentane ++++++++++-13.6 1.7 -0.4 3.1
1.9 0.9 5.1 1.3
50 40 40 40
40 40 40 40
Thiophene 1.8 -7.1 -3.1 -1.5 -1.5 3.3
1.2 0.0 5.3 1.5
50 40 40 40 40 40
40 40 40 40
2,2,4-Trimethylpentane 8.5 -0.4 -4.9 0.8 -2.7 0.1
-1.6 -2.2 3.2 -0.9
50 40 40 40 40 40
40 40 40 40
n-Heptane -7.0 -5.1 -9.6 -1.2 -1.5 4.3
4.1 2.4 8.5 4.9
50 40 40 40 40 40
40 40 40 40
1,2-Dichloropropane -1.1 -2.6 -0.1 1.6 -0.2 2.2
-0.6 -2.2 3.1 0.1
50 40 40 40 40 40
40 40 40 40
Trichloroethene 3.6 -6.2 -4.6 4.9 -1.4 3.7
0.5 -0.2 2.9 -3.4
50 40 40 40 40 40
40 40 40 40
Dibromomethane +++++++++++++++2.5 -1.8 -0.5
-3.3 4.7 0.2 -1.7
50 40 40
40 40 40 40
Bromodichloromethane ++++++++++-15.1 1.1 -2.8 1.4
1.0 0.8 9.8 3.9
50 40 40 40
40 40 40 40
1,4-Dioxane +++++++++++++++-11.5 -7.9 2.6
7.8 0.9 8.4 -0.3
50 40 40
40 40 40 40
Methyl methacrylate +++++++++++++++-17.9 -17.9 0.4
-1.6 8.4 17.9 10.7
50 40 40
40 40 40 40
Methylcyclohexane ++++++++++-10.2 -1.4 -2.7 2.4
0.9 1.5 6.7 2.8
50 40 40 40
40 40 40 40
4-Methyl-2-pentanone (MIBK)+++++++++++++++-12.4 -8.5 -1.4
0.8 2.2 12.2 7.0
50 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 394 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
cis-1,3-Dichloropropene ++++++++++-17.1 -4.2 -5.3 1.7
2.4 3.2 11.1 8.2
50 40 40 40
40 40 40 40
trans-1,3-Dichloropropene ++++++++++-19.8 -2.6 -7.1 1.0
5.3 5.8 14.2 3.2
50 40 40 40
40 40 40 40
Toluene ++++++++++2.4 3.2 -2.3 1.8
1.4 -0.6 2.1 -7.9
50 50 50 50
50 50 50 50
1,1,2-Trichloroethane ++++++++++-0.1 2.4 -0.9 4.8
1.0 -2.0 1.9 -7.1
50 40 40 40
40 40 40 40
2-Hexanone +++++++++++++++-20.8 -13.0 0.9
6.0 2.5 10.2 14.2
50 40 40
40 40 40 40
Octane -6.0 -7.7 -5.0 0.9 -2.9 3.5
3.6 2.6 6.6 4.5
50 40 40 40 40 40
40 40 40 40
Dibromochloromethane ++++++++++-35.3 -0.1 -1.1 6.8
8.4 0.1 15.2 6.0
50 40 40 40
40 40 40 40
1,2-Dibromoethane (EDB)1.0 -8.8 -12.5 -0.5 -1.5 4.7
4.0 3.1 8.1 2.4
50 40 40 40 40 40
40 40 40 40
Tetrachloroethene +++++1.9 -5.8 4.7 2.5 2.9
0.9 -0.8 0.7 -6.9
50 40 40 40 40
40 40 40 40
Chlorobenzene 8.6 2.2 1.6 1.8 -0.5 1.9
-0.9 -3.9 -2.1 -8.7
50 40 40 40 40 40
40 40 40 40
Ethylbenzene 4.9 -2.6 -4.2 -1.5 -4.3 2.0
1.1 -0.3 3.8 1.2
50 40 40 40 40 40
40 40 40 40
m-Xylene & p-Xylene 8.7 -2.7 -6.3 -2.9 -2.4 1.9
1.8 -0.5 3.9 -1.5
50 40 40 40 40 40
40 40 40 40
Nonane +++++++++++++++-9.4 -8.1 0.5
1.0 0.5 8.4 7.1
50 40 40
40 40 40 40
Styrene ++++++++++-17.3 -6.9 -3.9 4.4
5.1 5.0 10.5 3.1
50 40 40 40
40 40 40 40
Bromoform ++++++++++-68.0 9.5 8.1 15.6
20.6 -16.2 25.1 5.4
*50 40 40 40
40 40 40 40
o-Xylene 3.9 -5.1 -6.3 1.8 -1.1 3.2
2.1 -0.9 3.3 -0.9
50 40 40 40 40 40
40 40 40 40
1,1,2,2-Tetrachloroethane 4.9 -5.7 -3.3 -0.7 -2.0 4.1
2.1 -2.4 2.3 0.7
50 40 40 40 40 40
40 40 40 40
1,2,3-Trichloropropane -1.8 -5.5 -3.7 2.3 -0.5 4.6
2.1 -1.5 3.5 0.5
50 40 40 40 40 40
40 40 40 40
Isopropylbenzene +++++0.3 -4.5 -1.2 -3.4 3.0
2.9 0.5 3.6 -1.3
50 40 40 40 40
40 40 40 40
Propylbenzene ++++++++++-7.5 -5.6 -2.2 3.5
3.8 1.4 5.3 1.2
50 40 40 40
40 40 40 40
2-Chlorotoluene 1.3 -10.1 -7.3 1.7 2.2 5.4
4.3 0.7 3.6 -1.8
50 40 40 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 395 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
4-Ethyltoluene -0.3 -6.7 -6.6 -3.7 -1.8 4.9
4.5 2.0 5.6 1.9
50 40 40 40 40 40
40 40 40 40
1,3,5-Trimethylbenzene +++++++++++++++-2.0 -2.4 3.5
2.0 -2.2 3.3 -2.2
50 40 40
40 40 40 40
Alpha Methyl Styrene +++++++++++++++-18.8 -10.5 2.1
0.2 3.3 15.4 8.2
50 40 40
40 40 40 40
Decane +++++++++++++++-7.2 -4.2 1.8
-0.2 1.8 8.2 -0.2
50 40 40
40 40 40 40
tert-Butylbenzene 4.9 -4.8 -4.7 -0.8 -0.8 5.4
5.5 0.8 4.2 -9.7
50 40 40 40 40 40
40 40 40 40
1,2,4-Trimethylbenzene 1.9 -7.6 -4.8 -1.0 0.5 7.0
5.0 2.3 5.4 -8.6
50 40 40 40 40 40
40 40 40 40
sec-Butylbenzene -0.1 -6.7 -6.4 -2.7 -1.9 6.4
5.7 2.2 7.0 -3.7
50 40 40 40 40 40
40 40 40 40
1,3-Dichlorobenzene +++++0.4 1.5 2.0 2.0 5.1
2.3 -4.5 0.5 -9.2
50 40 40 40 40
40 40 40 40
Benzyl chloride 8.0 -8.5 -10.6 -14.2 -9.7 2.3
5.9 8.3 14.8 3.7
50 40 40 40 40 40
40 40 40 40
1,4-Dichlorobenzene +++++6.1 2.6 2.7 -0.4 6.0
2.0 -5.0 -1.4 -12.7
50 40 40 40 40
40 40 40 40
4-Isopropyltoluene -2.0 -7.3 -6.2 -1.6 1.7 9.0
5.6 1.7 5.4 -6.5
50 40 40 40 40 40
40 40 40 40
1,2,3-Trimethylbenzene -3.1 -6.3 -9.0 -1.5 -0.3 6.4
4.8 3.5 7.3 -1.7
50 40 40 40 40 40
40 40 40 40
Indane 6.4 -10.0 -5.4 -0.6 1.2 7.9
5.5 4.2 2.1 -11.2
50 40 40 40 40 40
40 40 40 40
1,2-Dichlorobenzene +++++0.3 1.1 4.5 2.9 8.0
3.1 -0.8 -2.9 -16.4
50 40 40 40 40
40 40 40 40
Butylbenzene 2.6 -7.3 -1.5 -0.5 1.6 7.5
4.2 3.0 1.3 -10.7
50 40 40 40 40 40
40 40 40 40
Indene -7.1 -13.9 -13.3 -3.9 1.6 12.1
8.7 9.5 9.1 -2.8
50 40 40 40 40 40
40 40 40 40
Undecane -2.3 -7.5 -4.3 -4.8 0.1 8.3
1.3 6.3 6.0 -3.1
50 40 40 40 40 40
40 40 40 40
1,2-Dibromo-3-Chloropropane ++++++++++-49.6 -0.1 3.0 12.7
19.2 -22.7 25.6 12.0
50 40 40 40
40 40 40 40
1,2,4,5-Tetramethylbenzene 5.6 -5.5 -3.1 -5.6 0.2 7.4
0.2 3.4 3.6 -6.1
50 40 40 40 40 40
40 40 40 40
Dodecane +++++++++++++++4.1 14.0 21.7
-8.5 -4.9 -9.0 -17.4
50 40 40
40 40 40 40
1,2,4-Trichlorobenzene ++++++++++21.7 5.6 5.4 11.6
-5.8 -7.9 -11.3 -19.4
50 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 396 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:84237
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MR
4937Calibration Start Date:Calibration End Date:03/05/2024 15:18
N
03/06/2024 00:47
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Naphthalene +++++++++++++++6.8 10.7 17.4
-0.8 -6.0 -11.3 -16.8
80 40 40
40 40 40 40
Hexachlorobutadiene ++++++++++31.8 8.0 7.1 13.1
-6.9 1.2 ++++++++++
50 40 40 40
40 40
1,2,3-Trichlorobenzene ++++++++++++++++++++25.7 29.6
3.0 -8.5 -21.6 -28.2
50 40
40 40 40 40
2-Methylnaphthalene +++++++++++++++-3.0 10.2 30.2
5.2 -3.8 -13.0 -25.8
80 50 50
50 50 50 50
1-Methylnaphthalene ++++++++++++++++++++23.9 35.0
2.6 -8.7 -20.7 -32.1
80 50
50 50 50 50
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 397 of 864
Report Date: 07-Mar-2024 08:53:49 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L10.D
Lims ID:IC L10
Client ID:
Sample Type:IC Calib Level:10
Inject. Date:05-Mar-2024 15:18:30 ALS Bottle#:12 Worklist Smp#:3
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-003
Misc. Info.:663021 200mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:53:49 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:55:14
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.385 9.385 0.000 97 207901 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.569 11.569 0.000 95 947038 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.433 16.433 0.000 87 939128 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.078 18.078 0.000 87 728484 4.08 4.24
6 Chlorodifluoromethane 51 3.777 3.777 0.000 97 1292647 16.0 14.6
7 Propene 41 3.788 3.788 0.000 98 586667 16.0 14.7
8 Dichlorodifluoromethane 85 3.847 3.847 0.000 100 2011746 16.0 14.1
9 Chloromethane 52 4.052 4.052 0.000 98 229371 16.0 14.3
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.063 4.063 0.000 96 1580949 16.0 14.3
11 Acetaldehyde 44 4.241 4.241 0.000 94 1660864 80.0 68.7
12 Vinyl chloride 62 4.246 4.246 0.000 99 872510 16.0 14.9
13 Butane 43 4.343 4.343 0.000 84 1250210 16.0 15.0
14 Butadiene 54 4.343 4.343 0.000 71 657381 16.0 15.4
15 Bromomethane 94 4.710 4.710 0.000 98 859263 16.0 14.6
16 Chloroethane 64 4.872 4.872 0.000 100 475938 16.0 15.5
17 Ethanol 31 5.023 5.023 0.000 96 2043366 80.0 80.5
18 Vinyl bromide 106 5.212 5.212 0.000 98 867677 16.0 14.7
19 2-Methylbutane 43 5.255 5.255 0.000 89 870968 16.0 14.5
20 Trichlorofluoromethane 101 5.508 5.508 0.000 99 2311482 16.0 15.0
21 Acrolein 56 5.535 5.535 0.000 94 271863 16.0 17.0
22 Acetonitrile 40 5.627 5.627 0.000 98 333589 16.0 15.6
23 Acetone 58 5.664 5.664 0.000 98 1175060 48.0 41.3
25 Pentane 72 5.745 5.745 0.000 98 168361 16.0 15.9
24 Isopropyl alcohol 45 5.788 5.788 0.000 94 3160964 48.0 45.8
26 Ethyl ether 31 5.939 5.939 0.000 93 825039 16.0 15.3
27 1,1-Dichloroethene 96 6.285 6.285 0.000 99 919225 16.0 15.2
29 Acrylonitrile 53 6.430 6.430 0.000 93 622841 16.0 16.9
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.473 6.473 0.000 95 1971176 16.0 14.8
28 2-Methyl-2-propanol 59 6.436 6.436 0.000 95 1658598 16.0 15.9
31 Methylene Chloride 84 6.673 6.673 0.000 91 853965 16.0 13.0
3/25/2024
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Page 398 of 864
Report Date: 07-Mar-2024 08:53:49 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L10.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.689 6.689 0.000 97 811043 16.0 14.0
33 Carbon disulfide 76 6.840 6.840 0.000 99 2685918 16.0 15.0
34 trans-1,2-Dichloroethene 96 7.541 7.541 0.000 97 979559 16.0 15.5
35 2-Methylpentane 43 7.541 7.541 0.000 92 1821201 16.0 15.9
36 Methyl tert-butyl ether 73 7.665 7.665 0.000 96 2615086 16.0 15.7
37 1,1-Dichloroethane 63 7.994 7.994 0.000 100 1664397 16.0 15.3
38 Vinyl acetate 43 8.102 8.102 0.000 99 2104582 16.0 18.3
40 Hexane 56 8.582 8.582 0.000 72 703831 16.0 15.7
39 2-Butanone (MEK) 72 8.576 8.576 0.000 85 467359 16.0 16.2
41 Isopropyl ether 45 8.749 8.749 0.000 94 2863815 16.0 16.2
42 cis-1,2-Dichloroethene 96 9.035 9.035 0.000 93 1029497 16.0 15.4
43 Ethyl acetate 43 9.213 9.213 0.000 99 1986249 16.0 16.2
44 Chloroform 83 9.396 9.396 0.000 96 2122571 16.0 15.2
45 Tert-butyl ethyl ether 59 9.455 9.455 0.000 96 2990855 16.0 15.9
46 Tetrahydrofuran 42 9.800 9.800 0.000 88 940763 16.0 15.8
47 1,1,1-Trichloroethane 97 10.447 10.447 0.000 96 2117862 16.0 15.5
48 1,2-Dichloroethane 62 10.566 10.566 0.000 98 1362128 16.0 15.9
50 Cyclohexane 69 11.024 11.024 0.000 94 463438 16.0 16.4
51 Benzene 78 11.041 11.041 0.000 97 2929915 16.0 15.6
52 Carbon tetrachloride 117 11.057 11.057 0.000 97 2076339 16.0 15.9
49 n-Butanol 31 10.998 10.998 0.000 76 377887 16.0 16.3
53 2,3-Dimethylpentane 71 11.132 11.132 0.000 89 671150 16.0 16.2
54 Thiophene 84 11.316 11.316 0.000 95 1730388 16.0 16.2
55 Isooctane 57 11.763 11.763 0.000 98 4475975 16.0 15.9
56 n-Heptane 71 12.130 12.130 0.000 89 1049532 16.0 16.8
57 1,2-Dichloropropane 63 12.249 12.249 0.000 88 1101580 16.0 16.0
58 Trichloroethene 130 12.276 12.276 0.000 97 1379425 16.0 15.5
59 Dibromomethane 93 12.378 12.378 0.000 96 1284908 16.0 15.7
60 Dichlorobromomethane 83 12.518 12.518 0.000 99 2309800 16.0 16.6
61 1,4-Dioxane 88 12.524 12.524 0.000 88 435710 16.0 16.0
62 Methyl methacrylate 41 12.588 12.588 0.000 95 1271585 16.0 17.7
63 Methylcyclohexane 83 13.057 13.057 0.000 96 1842401 16.0 16.5
64 4-Methyl-2-pentanone (MIBK) 43 13.478 13.478 0.000 97 2225112 16.0 17.1
65 cis-1,3-Dichloropropene 75 13.548 13.548 0.000 95 1850562 16.0 17.3
66 trans-1,3-Dichloropropene 75 14.276 14.276 0.000 98 1708905 16.0 16.5
67 Toluene 91 14.400 14.400 0.000 93 3795001 16.0 14.7
68 1,1,2-Trichloroethane 83 14.486 14.486 0.000 98 1127330 16.0 14.9
69 2-Hexanone 58 14.864 14.864 0.000 94 1342916 16.0 18.3
70 n-Octane 85 15.080 15.080 0.000 91 1301774 16.0 16.7
71 Chlorodibromomethane 129 15.220 15.220 0.000 98 2516726 16.0 17.0
72 Ethylene Dibromide 107 15.522 15.522 0.000 98 2239119 16.0 16.4
73 Tetrachloroethene 129 15.581 15.581 0.000 97 1377300 16.0 14.9
75 2,3-Dimethylheptane 43 16.460 16.460 0.000 93 3445859 16.0 16.7
74 Chlorobenzene 112 16.482 16.482 0.000 94 3020241 16.0 14.6
76 Ethylbenzene 91 16.762 16.762 0.000 99 5373573 16.0 16.2
77 m-Xylene & p-Xylene 91 16.929 16.929 0.000 98 8178477 32.0 31.5
78 n-Nonane 57 17.317 17.317 0.000 88 2448000 16.0 17.1
80 Styrene 104 17.404 17.404 0.000 99 2981433 16.0 16.5
79 Bromoform 173 17.404 17.404 0.000 94 2192688 16.0 16.9
81 o-Xylene 91 17.463 17.463 0.000 98 4286303 16.0 15.9
82 1,1,2,2-Tetrachloroethane 83 17.792 17.792 0.000 99 3251381 16.0 16.1
83 1,2,3-Trichloropropane 110 17.948 17.948 0.000 97 935064 16.0 16.1
3/25/2024
9:50:51 AM
Page 399 of 864
Report Date: 07-Mar-2024 08:53:49 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L10.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.035 18.035 0.000 97 5751199 16.0 15.8
85 N-Propylbenzene 120 18.547 18.547 0.000 99 1654136 16.0 16.2
86 2-Chlorotoluene 126 18.606 18.606 0.000 97 1440137 16.0 15.7
88 4-Ethyltoluene 105 18.692 18.692 0.000 98 6076363 16.0 16.3
87 1,3,5-Trimethylbenzene 120 18.763 18.763 0.000 92 2426996 16.0 15.7
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 88 2649709 16.0 17.3
90 n-Decane 57 19.011 19.011 0.000 92 3132502 16.0 16.0
91 tert-Butylbenzene 119 19.172 19.172 0.000 93 4850324 16.0 14.5
92 1,2,4-Trimethylbenzene 105 19.189 19.189 0.000 96 4686624 16.0 14.6
93 sec-Butylbenzene 105 19.431 19.431 0.000 98 7110972 16.0 15.4
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 99 3254132 16.0 14.5
95 Benzyl chloride 91 19.528 19.528 0.000 98 4322081 16.0 16.6
96 1,4-Dichlorobenzene 146 19.544 19.544 0.000 94 3136318 16.0 14.0
97 4-Isopropyltoluene 119 19.588 19.588 0.000 96 5853929 16.0 15.0
98 1,2,3-Trimethylbenzene 105 19.647 19.647 0.000 98 5118543 16.0 15.7
99 Butylcyclohexane 83 19.690 19.690 0.000 94 3834110 16.0 14.9
100 2,3-Dihydroindene 117 19.890 19.890 0.000 94 4412732 16.0 14.2
101 1,2-Dichlorobenzene 146 19.900 19.900 0.000 95 2912343 16.0 13.4
103 n-Butylbenzene 91 20.003 20.003 0.000 99 5663920 16.0 14.3
102 Indene 116 20.024 20.024 0.000 90 3938850 16.0 15.6
104 Undecane 57 20.283 20.283 0.000 94 3585187 16.0 15.5
105 1,2-Dibromo-3-Chloropropane 157 20.493 20.493 0.000 99 1945296 16.0 17.9
106 1,2,4,5-Tetramethylbenzene 119 20.768 20.768 0.000 96 5991783 16.0 15.0
107 Dodecane 57 21.383 21.383 0.000 96 3644719 16.0 13.2
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 2651205 16.0 12.9
109 Naphthalene 128 21.745 21.745 0.000 98 6135786 16.0 13.3
110 Hexachlorobutadiene 225 21.896 21.896 0.000 95 1368640 16.0 NQ
111 1,2,3-Trichlorobenzene 180 21.955 21.955 0.000 94 1861376 16.0 11.5
112 2-Methylnaphthalene 142 22.489 22.489 0.000 98 3067682 16.0 11.9
113 1-Methylnaphthalene 142 22.618 22.618 0.000 98 2956318 16.0 10.9
A 116 C8 Range 1 15.087 (15.031-15.128) 0 11044334 16.0 17.5
S 117 Xylenes, Total 100 0 48.0 47.4
S 118 1,2-Dichloroethene, Total 1 0 32.0 30.9
QC Flag Legend
Processing Flags
NQ - Not Quantifiable
Reagents:
40L10DQP_00052 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 400 of 864
Report Date: 07-Mar-2024 08:53:49 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L10.D
Injection Date:05-Mar-2024 15:18:30 Instrument ID:MR Operator ID:
Lims ID:IC L10 Worklist Smp#:3
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:12
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
0
0
0
0
)
RZC05L10[MS SCAN Chro]:Total
* C
h
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(IS
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3/25/2024
9:50:51 AM
Page 401 of 864
Report Date: 07-Mar-2024 08:53:49 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L10.D
Injection Date:05-Mar-2024 15:18:30 Instrument ID:MR
Lims ID:IC L10
Client ID:
Operator ID:ALS Bottle#:12 Worklist Smp#:3
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
0
0
0
)
RZC05L10[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 402 of 864
Report Date: 07-Mar-2024 08:54:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L9.D
Lims ID:IC L9
Client ID:
Sample Type:IC Calib Level:9
Inject. Date:05-Mar-2024 16:55:30 ALS Bottle#:11 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-005
Misc. Info.:663022 200mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:54:05 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:53:00
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.380 9.382 -0.002 95 221929 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.564 11.566 -0.002 95 1015222 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.430 -0.002 86 949158 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.075 -0.003 88 720324 4.08 4.15
6 Chlorodifluoromethane 51 3.788 3.782 0.006 97 763157 8.00 8.06
7 Propene 41 3.799 3.793 0.006 98 347111 8.00 8.17
8 Dichlorodifluoromethane 85 3.852 3.850 0.002 100 1226838 8.00 8.04
9 Chloromethane 52 4.063 4.057 0.006 100 131420 8.00 7.65
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.074 4.068 0.006 96 911331 8.00 7.72
11 Acetaldehyde 44 4.246 4.244 0.002 92 911001 40.0 35.3
12 Vinyl chloride 62 4.252 4.249 0.003 99 475316 8.00 7.60
13 Butane 43 4.354 4.349 0.005 91 685014 8.00 7.70
14 Butadiene 54 4.354 4.349 0.005 95 355267 8.00 7.79
15 Bromomethane 94 4.715 4.713 0.002 99 470927 8.00 7.52
16 Chloroethane 64 4.877 4.874 0.003 99 243275 8.00 7.40
17 Ethanol 31 5.023 5.023 0.000 95 1005910 40.0 37.1
18 Vinyl bromide 106 5.217 5.214 0.003 98 500886 8.00 7.93
19 2-Methylbutane 43 5.265 5.260 0.005 89 534166 8.00 8.35
20 Trichlorofluoromethane 101 5.513 5.511 0.002 99 1326001 8.00 8.04
21 Acrolein 56 5.540 5.538 0.002 94 144942 8.00 8.51
22 Acetonitrile 40 5.627 5.627 0.000 98 192073 8.00 8.43
23 Acetone 58 5.664 5.664 0.000 98 670882 24.0 22.1
25 Pentane 72 5.751 5.748 0.003 98 97182 8.00 8.57
24 Isopropyl alcohol 45 5.783 5.786 -0.003 98 1860388 24.0 25.3
26 Ethyl ether 31 5.945 5.942 0.003 94 486346 8.00 8.46
27 1,1-Dichloroethene 96 6.290 6.287 0.003 99 524615 8.00 8.11
29 Acrylonitrile 53 6.430 6.430 0.000 94 345787 8.00 8.81
28 2-Methyl-2-propanol 59 6.441 6.438 0.003 95 964366 8.00 8.65
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.473 6.473 0.000 96 1136926 8.00 8.01
31 Methylene Chloride 84 6.673 6.673 0.000 94 484843 8.00 6.93
3/25/2024
9:50:51 AM
Page 403 of 864
Report Date: 07-Mar-2024 08:54:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L9.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.689 6.689 0.000 97 483117 8.00 7.82
33 Carbon disulfide 76 6.845 6.843 0.002 99 1508275 8.00 7.90
34 trans-1,2-Dichloroethene 96 7.535 7.538 -0.003 98 553580 8.00 8.20
35 2-Methylpentane 43 7.541 7.541 0.000 92 1034617 8.00 8.46
36 Methyl tert-butyl ether 73 7.670 7.668 0.002 96 1497370 8.00 8.43
37 1,1-Dichloroethane 63 7.994 7.994 0.000 100 947336 8.00 8.17
38 Vinyl acetate 43 8.102 8.102 0.000 99 1126537 8.00 9.18
39 2-Butanone (MEK) 72 8.582 8.579 0.003 85 258481 8.00 8.41
40 Hexane 56 8.576 8.579 -0.003 72 397610 8.00 8.32
41 Isopropyl ether 45 8.749 8.749 0.000 95 1635898 8.00 8.66
42 cis-1,2-Dichloroethene 96 9.029 9.032 -0.003 93 581553 8.00 8.17
43 Ethyl acetate 43 9.213 9.213 -0.001 99 1133200 8.00 8.68
44 Chloroform 83 9.390 9.393 -0.003 96 1202016 8.00 8.05
45 Tert-butyl ethyl ether 59 9.455 9.455 0.000 95 1704696 8.00 8.50
46 Tetrahydrofuran 42 9.800 9.800 0.000 89 540076 8.00 8.50
47 1,1,1-Trichloroethane 97 10.442 10.445 -0.003 96 1209865 8.00 8.28
48 1,2-Dichloroethane 62 10.561 10.563 -0.002 98 786365 8.00 8.58
49 n-Butanol 31 11.003 11.000 0.003 87 215668 8.00 8.71
50 Cyclohexane 69 11.024 11.024 0.000 92 258235 8.00 8.51
51 Benzene 78 11.035 11.038 -0.003 97 1627489 8.00 8.07
52 Carbon tetrachloride 117 11.051 11.054 -0.003 96 1237738 8.00 8.31
53 2,3-Dimethylpentane 71 11.132 11.132 0.000 90 373197 8.00 8.41
54 Thiophene 84 11.310 11.313 -0.003 95 962215 8.00 8.43
55 Isooctane 57 11.763 11.763 0.000 98 2499779 8.00 8.26
56 n-Heptane 71 12.130 12.130 0.000 90 581659 8.00 8.68
57 1,2-Dichloropropane 63 12.238 12.243 -0.005 88 608087 8.00 8.24
58 Trichloroethene 130 12.270 12.273 -0.003 96 787574 8.00 8.24
59 Dibromomethane 93 12.372 12.375 -0.003 96 702216 8.00 8.01
60 Dichlorobromomethane 83 12.513 12.515 -0.002 99 1307482 8.00 8.78
61 1,4-Dioxane 88 12.523 12.523 0.000 87 253813 8.00 8.67
62 Methyl methacrylate 41 12.583 12.586 -0.003 94 725998 8.00 9.43
63 Methylcyclohexane 83 13.057 13.057 0.000 96 1024351 8.00 8.53
64 4-Methyl-2-pentanone (MIBK) 43 13.478 13.478 0.000 97 1250855 8.00 8.98
65 cis-1,3-Dichloropropene 75 13.543 13.545 -0.002 95 1019356 8.00 8.89
66 trans-1,3-Dichloropropene 75 14.271 14.273 -0.002 98 955776 8.00 9.13
67 Toluene 91 14.395 14.397 -0.002 93 2124613 8.00 8.17
68 1,1,2-Trichloroethane 83 14.481 14.484 -0.003 98 624836 8.00 8.15
69 2-Hexanone 58 14.864 14.864 0.000 94 654713 8.00 8.81
70 n-Octane 85 15.074 15.077 -0.003 90 671112 8.00 8.53
71 Chlorodibromomethane 129 15.214 15.217 -0.003 98 1381155 8.00 9.21
72 Ethylene Dibromide 107 15.516 15.519 -0.003 98 1194759 8.00 8.65
73 Tetrachloroethene 129 15.576 15.578 -0.002 95 753353 8.00 8.06
75 2,3-Dimethylheptane 43 16.460 16.460 0.000 91 1743503 8.00 8.36
74 Chlorobenzene 112 16.476 16.479 -0.003 93 1637947 8.00 7.83
76 Ethylbenzene 91 16.762 16.762 0.000 99 2783956 8.00 8.30
77 m-Xylene & p-Xylene 91 16.924 16.926 -0.002 99 4358735 16.0 16.6
78 n-Nonane 57 17.317 17.317 0.000 87 1252624 8.00 8.67
80 Styrene 104 17.398 17.401 -0.003 99 1615397 8.00 8.84
79 Bromoform 173 17.404 17.404 0.000 95 1314557 8.00 10.0
81 o-Xylene 91 17.457 17.460 -0.003 98 2258486 8.00 8.26
82 1,1,2,2-Tetrachloroethane 83 17.786 17.789 -0.003 99 1667875 8.00 8.18
83 1,2,3-Trichloropropane 110 17.943 17.946 -0.003 97 486978 8.00 8.28
3/25/2024
9:50:51 AM
Page 404 of 864
Report Date: 07-Mar-2024 08:54:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L9.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.034 18.034 0.000 96 3050778 8.00 8.29
85 N-Propylbenzene 120 18.547 18.547 0.000 99 869954 8.00 8.43
86 2-Chlorotoluene 126 18.601 18.603 -0.002 97 768128 8.00 8.29
88 4-Ethyltoluene 105 18.687 18.690 -0.003 98 3182218 8.00 8.45
87 1,3,5-Trimethylbenzene 120 18.757 18.760 -0.003 92 1295115 8.00 8.26
89 Alpha Methyl Styrene 118 18.983 18.984 -0.001 88 1428216 8.00 9.23
90 n-Decane 57 19.010 19.011 -0.001 92 1715990 8.00 8.65
91 tert-Butylbenzene 119 19.167 19.170 -0.003 92 2826350 8.00 8.33
92 1,2,4-Trimethylbenzene 105 19.183 19.186 -0.003 96 2731876 8.00 8.43
93 sec-Butylbenzene 105 19.426 19.428 -0.002 98 3990829 8.00 8.56
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 99 1820256 8.00 8.04
95 Benzyl chloride 91 19.528 19.528 0.000 98 2416429 8.00 9.18
96 1,4-Dichlorobenzene 146 19.544 19.544 0.000 94 1789598 8.00 7.89
97 4-Isopropyltoluene 119 19.582 19.585 -0.003 97 3336450 8.00 8.44
98 1,2,3-Trimethylbenzene 105 19.641 19.644 -0.003 99 2822253 8.00 8.58
99 Butylcyclohexane 83 19.684 19.687 -0.003 95 2127047 8.00 8.18
100 2,3-Dihydroindene 117 19.889 19.889 0.000 94 2563980 8.00 8.17
101 1,2-Dichlorobenzene 146 19.895 19.898 -0.003 95 1708763 8.00 7.77
103 n-Butylbenzene 91 20.003 20.003 0.000 99 3247691 8.00 8.10
102 Indene 116 20.019 20.022 -0.003 89 2233968 8.00 8.73
104 Undecane 57 20.283 20.283 0.000 94 1980361 8.00 8.48
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.491 -0.003 100 1102624 8.00 10.0
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.766 -0.003 97 3342249 8.00 8.29
107 Dodecane 57 21.378 21.380 -0.002 96 2029607 8.00 7.28
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 1474036 8.00 7.10
109 Naphthalene 128 21.744 21.744 0.000 99 3304407 8.00 7.09
110 Hexachlorobutadiene 225 21.890 21.893 -0.003 93 851802 8.00 NQ
111 1,2,3-Trichlorobenzene 180 21.955 21.955 0.000 95 1027493 8.00 6.27
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 1816525 8.00 6.96
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 1746125 8.00 6.35
A 116 C8 Range 1 15.079 (15.025-15.133) 0 5655158 8.00 8.38
S 117 Xylenes, Total 100 0 24.0 24.9
S 118 1,2-Dichloroethene, Total 1 0 16.0 16.4
QC Flag Legend
Processing Flags
NQ - Not Quantifiable
Reagents:
40L9DQP_00051 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 405 of 864
Report Date: 07-Mar-2024 08:54:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L9.D
Injection Date:05-Mar-2024 16:55:30 Instrument ID:MR Operator ID:
Lims ID:IC L9 Worklist Smp#:5
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:11
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
48
51
54
57
60
63
66
69
72
75
78
81
Y ( X10
0
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)
RZC05L9[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 406 of 864
Report Date: 07-Mar-2024 08:54:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L9.D
Injection Date:05-Mar-2024 16:55:30 Instrument ID:MR
Lims ID:IC L9
Client ID:
Operator ID:ALS Bottle#:11 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
Y ( X10
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RZC05L9[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 407 of 864
Report Date: 07-Mar-2024 08:54:22 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L8.D
Lims ID:IC L8
Client ID:
Sample Type:IC Calib Level:8
Inject. Date:05-Mar-2024 18:30:30 ALS Bottle#:10 Worklist Smp#:7
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-007
Misc. Info.:663023 200mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:54:22 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:52:36
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.380 -0.006 95 238596 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.564 -0.006 95 1076786 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.429 -0.001 86 991861 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.074 -0.002 88 743821 4.08 4.10
6 Chlorodifluoromethane 51 3.782 3.782 0.000 97 388911 4.00 3.82
7 Propene 41 3.793 3.793 0.000 97 180029 4.00 3.94
8 Dichlorodifluoromethane 85 3.853 3.851 0.002 100 612888 4.00 3.73
9 Chloromethane 52 4.057 4.057 0.000 100 66676 4.00 3.61
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.068 4.068 0.000 96 471448 4.00 3.71
11 Acetaldehyde 44 4.246 4.244 0.002 91 469218 20.0 16.9
12 Vinyl chloride 62 4.252 4.250 0.002 99 245969 4.00 3.66
13 Butane 43 4.349 4.349 0.000 92 347615 4.00 3.63
14 Butadiene 54 4.349 4.349 0.000 91 181018 4.00 3.69
15 Bromomethane 94 4.710 4.712 -0.002 99 241871 4.00 3.59
16 Chloroethane 64 4.872 4.874 -0.002 97 122670 4.00 3.47
17 Ethanol 31 5.017 5.021 -0.004 94 492283 20.0 16.9
18 Vinyl bromide 106 5.211 5.213 -0.002 98 254581 4.00 3.75
19 2-Methylbutane 43 5.260 5.260 0.000 90 277486 4.00 4.04
20 Trichlorofluoromethane 101 5.508 5.510 -0.002 99 677902 4.00 3.82
21 Acrolein 56 5.535 5.537 -0.002 94 78310 4.00 4.27
22 Acetonitrile 40 5.621 5.625 -0.004 97 97909 4.00 4.00
23 Acetone 58 5.664 5.664 0.000 98 344578 12.0 10.6
25 Pentane 72 5.745 5.747 -0.002 99 47428 4.00 3.89
24 Isopropyl alcohol 45 5.778 5.783 -0.005 94 938886 12.0 11.9
26 Ethyl ether 31 5.939 5.941 -0.002 94 248196 4.00 4.01
27 1,1-Dichloroethene 96 6.285 6.286 -0.001 99 268858 4.00 3.87
29 Acrylonitrile 53 6.419 6.427 -0.008 93 171488 4.00 4.06
28 2-Methyl-2-propanol 59 6.446 6.441 0.005 95 479699 4.00 4.00
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.468 6.471 -0.003 96 582049 4.00 3.81
31 Methylene Chloride 84 6.667 6.671 -0.004 92 249242 4.00 3.32
3/25/2024
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Page 408 of 864
Report Date: 07-Mar-2024 08:54:22 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L8.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.684 6.687 -0.003 98 333270 4.00 5.02
33 Carbon disulfide 76 6.840 6.842 -0.002 99 756047 4.00 3.68
34 trans-1,2-Dichloroethene 96 7.530 7.536 -0.006 99 278476 4.00 3.84
35 2-Methylpentane 43 7.536 7.539 -0.003 92 520179 4.00 3.95
36 Methyl tert-butyl ether 73 7.670 7.669 0.001 96 756240 4.00 3.96
37 1,1-Dichloroethane 63 7.983 7.990 -0.007 100 477330 4.00 3.83
38 Vinyl acetate 43 8.096 8.100 -0.004 99 508123 4.00 3.85
40 Hexane 56 8.571 8.576 -0.005 73 197523 4.00 3.85
39 2-Butanone (MEK) 72 8.576 8.578 -0.002 85 127617 4.00 3.86
41 Isopropyl ether 45 8.743 8.747 -0.004 94 819402 4.00 4.04
42 cis-1,2-Dichloroethene 96 9.024 9.029 -0.005 93 296624 4.00 3.88
43 Ethyl acetate 43 9.213 9.213 0.000 99 565296 4.00 4.03
44 Chloroform 83 9.380 9.389 -0.009 96 607576 4.00 3.79
45 Tert-butyl ethyl ether 59 9.455 9.455 0.000 95 860763 4.00 3.99
46 Tetrahydrofuran 42 9.800 9.800 0.000 89 273282 4.00 4.00
47 1,1,1-Trichloroethane 97 10.431 10.440 -0.009 96 608597 4.00 3.87
48 1,2-Dichloroethane 62 10.555 10.561 -0.006 98 394308 4.00 4.05
49 n-Butanol 31 11.014 11.005 0.009 68 103146 4.00 3.98
50 Cyclohexane 69 11.019 11.023 -0.004 90 128612 4.00 3.99
51 Benzene 78 11.030 11.035 -0.005 97 826949 4.00 3.87
52 Carbon tetrachloride 117 11.046 11.051 -0.005 97 623731 4.00 3.81
53 2,3-Dimethylpentane 71 11.127 11.130 -0.003 89 190038 4.00 4.04
54 Thiophene 84 11.305 11.310 -0.005 95 484395 4.00 4.00
55 Isooctane 57 11.758 11.761 -0.003 98 1256294 4.00 3.91
56 n-Heptane 71 12.119 12.126 -0.007 90 291204 4.00 4.10
57 1,2-Dichloropropane 63 12.238 12.241 -0.003 87 305970 4.00 3.91
58 Trichloroethene 130 12.270 12.272 -0.002 97 404898 4.00 3.99
59 Dibromomethane 93 12.367 12.373 -0.006 97 389010 4.00 4.19
60 Dichlorobromomethane 83 12.507 12.513 -0.006 99 636560 4.00 4.03
61 1,4-Dioxane 88 12.529 12.525 0.004 91 125323 4.00 4.04
62 Methyl methacrylate 41 12.583 12.585 -0.002 95 353896 4.00 4.34
63 Methylcyclohexane 83 13.052 13.056 -0.004 96 516995 4.00 4.06
64 4-Methyl-2-pentanone (MIBK) 43 13.483 13.480 0.003 97 603822 4.00 4.09
65 cis-1,3-Dichloropropene 75 13.543 13.544 -0.001 95 501794 4.00 4.13
66 trans-1,3-Dichloropropene 75 14.265 14.271 -0.006 98 462650 4.00 4.23
67 Toluene 91 14.395 14.396 -0.001 93 1080512 4.00 3.97
68 1,1,2-Trichloroethane 83 14.476 14.481 -0.005 97 313873 4.00 3.92
69 2-Hexanone 58 14.869 14.866 0.003 95 318297 4.00 4.10
70 n-Octane 85 15.074 15.076 -0.002 89 337465 4.00 4.10
71 Chlorodibromomethane 129 15.209 15.214 -0.005 98 627250 4.00 4.00
72 Ethylene Dibromide 107 15.511 15.516 -0.005 98 595648 4.00 4.13
73 Tetrachloroethene 129 15.576 15.577 -0.001 96 387691 4.00 3.97
75 2,3-Dimethylheptane 43 16.460 16.460 0.000 93 854772 4.00 3.92
74 Chlorobenzene 112 16.476 16.478 -0.002 94 839896 4.00 3.84
76 Ethylbenzene 91 16.757 16.760 -0.003 98 1398052 4.00 3.99
77 m-Xylene & p-Xylene 91 16.918 16.924 -0.006 98 2182153 8.00 7.96
78 n-Nonane 57 17.312 17.316 -0.004 87 606542 4.00 4.02
80 Styrene 104 17.398 17.400 -0.002 99 801534 4.00 4.20
79 Bromoform 173 17.404 17.404 0.000 96 459967 4.00 3.35
81 o-Xylene 91 17.458 17.459 -0.001 98 1131819 4.00 3.96
82 1,1,2,2-Tetrachloroethane 83 17.786 17.788 -0.002 99 831748 4.00 3.90
83 1,2,3-Trichloropropane 110 17.943 17.945 -0.002 97 242208 4.00 3.94
3/25/2024
9:50:51 AM
Page 409 of 864
Report Date: 07-Mar-2024 08:54:22 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L8.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.029 18.033 -0.004 97 1546990 4.00 4.02
85 N-Propylbenzene 120 18.547 18.547 0.000 99 437796 4.00 4.06
86 2-Chlorotoluene 126 18.601 18.602 -0.001 98 390016 4.00 4.03
88 4-Ethyltoluene 105 18.687 18.689 -0.002 99 1606649 4.00 4.08
87 1,3,5-Trimethylbenzene 120 18.757 18.759 -0.002 92 640522 4.00 3.91
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 87 667838 4.00 4.13
90 n-Decane 57 19.005 19.009 -0.004 93 844074 4.00 4.07
91 tert-Butylbenzene 119 19.167 19.169 -0.002 91 1428935 4.00 4.03
92 1,2,4-Trimethylbenzene 105 19.183 19.185 -0.002 96 1385185 4.00 4.09
93 sec-Butylbenzene 105 19.426 19.428 -0.002 98 1992290 4.00 4.09
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 99 904283 4.00 3.82
95 Benzyl chloride 91 19.528 19.528 0.000 98 1191119 4.00 4.33
96 1,4-Dichlorobenzene 146 19.539 19.543 -0.004 95 901108 4.00 3.80
97 4-Isopropyltoluene 119 19.582 19.584 -0.002 97 1681941 4.00 4.07
98 1,2,3-Trimethylbenzene 105 19.641 19.643 -0.002 99 1422835 4.00 4.14
99 Butylcyclohexane 83 19.685 19.686 -0.001 95 1121331 4.00 4.12
100 2,3-Dihydroindene 117 19.890 19.889 0.001 94 1367300 4.00 4.17
101 1,2-Dichlorobenzene 146 19.895 19.897 -0.002 96 912517 4.00 3.97
103 n-Butylbenzene 91 20.003 20.003 0.000 99 1725264 4.00 4.12
102 Indene 116 20.019 20.021 -0.002 90 1171418 4.00 4.38
104 Undecane 57 20.283 20.283 0.000 94 1038024 4.00 4.25
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.490 -0.002 99 354793 4.00 3.09
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.765 -0.002 97 1742628 4.00 4.14
107 Dodecane 57 21.378 21.380 -0.002 96 1107709 4.00 3.80
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 800097 4.00 3.69
109 Naphthalene 128 21.744 21.744 0.000 99 1831340 4.00 3.76
110 Hexachlorobutadiene 225 21.890 21.892 -0.002 93 550136 4.00 4.05
111 1,2,3-Trichlorobenzene 180 21.949 21.953 -0.004 94 626533 4.00 3.66
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 1049457 4.00 3.85
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 1049478 4.00 3.65
A 116 C8 Range 1 15.079 (15.026-15.133) 0 2796103 4.00 3.91
S 117 Xylenes, Total 100 0 12.0 11.9
S 118 1,2-Dichloroethene, Total 1 0 8.00 7.72
QC Flag Legend
Processing Flags
Reagents:
40L8DQP_00049 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 410 of 864
Report Date: 07-Mar-2024 08:54:23 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L8.D
Injection Date:05-Mar-2024 18:30:30 Instrument ID:MR Operator ID:
Lims ID:IC L8 Worklist Smp#:7
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:10
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
44
46
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RZC05L8[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 411 of 864
Report Date: 07-Mar-2024 08:54:23 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L8.D
Injection Date:05-Mar-2024 18:30:30 Instrument ID:MR
Lims ID:IC L8
Client ID:
Operator ID:ALS Bottle#:10 Worklist Smp#:7
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
0
1
2
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6
7
8
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10
11
12
13
14
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RZC05L8[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 412 of 864
Report Date: 07-Mar-2024 08:54:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L1.D
Lims ID:IC L1
Client ID:
Sample Type:IC Calib Level:1
Inject. Date:05-Mar-2024 20:04:30 ALS Bottle#:6 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-009
Misc. Info.:663623 50mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:54:40 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:52:09
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.377 -0.008 84 234059 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.562 -0.004 94 1080986 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.429 -0.001 87 961170 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.074 -0.002 90 704159 4.08 4.01
6 Chlorodifluoromethane 51 3.799 3.787 0.012 92 2301 0.0200 0.0230
7 Propene 41 3.799 3.795 0.004 61 1106 0.0200 0.0247
8 Dichlorodifluoromethane 85 3.858 3.853 0.005 97 3936 0.0200 0.0244
9 Chloromethane 52 4.068 4.060 0.008 53 577 0.0200 0.0319
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.074 4.070 0.004 89 2824 0.0200 0.0227
11 Acetaldehyde 44 4.279 4.253 0.026 78 5144 0.1000 0.1889
12 Vinyl chloride 62 4.257 4.252 0.005 93 1481 0.0200 0.0224
13 Butane 43 4.354 4.350 0.004 84 2354 0.0200 0.0251
14 Butadiene 54 4.360 4.351 0.009 64 1036 0.0200 0.0216
15 Bromomethane 94 4.726 4.715 0.011 93 1647 0.0200 0.0249
16 Chloroethane 64 4.877 4.874 0.003 86 635 0.0200 0.0183
17 Ethanol 31 5.077 5.035 0.042 92 5077 0.1000 0.1777
18 Vinyl bromide 106 5.217 5.214 0.003 92 1420 0.0200 0.0213
19 2-Methylbutane 43 5.271 5.263 0.008 91 1848 0.0200 0.0274
20 Trichlorofluoromethane 101 5.514 5.511 0.003 97 3918 0.0200 0.0225
22 Acetonitrile 40 5.665 5.635 0.029 23 767 0.0200 0.0319
23 Acetone 58 5.740 5.683 0.057 96 2748 0.0600 0.0858
24 Isopropyl alcohol 45 5.891 5.810 0.081 96 4889 0.0600 0.0629
26 Ethyl ether 31 6.020 5.961 0.059 88 1248 0.0200 0.0206
27 1,1-Dichloroethene 96 6.295 6.289 0.006 92 1442 0.0200 0.0211
29 Acrylonitrile 53 6.490 6.442 0.048 37 471 0.0200 0.0114
28 2-Methyl-2-propanol 59 6.597 6.480 0.117 35 1430 0.0200 0.0122
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.473 6.472 0.001 94 3230 0.0200 0.0216
31 Methylene Chloride 84 6.673 6.671 0.002 91 5068 0.0200 0.0687
32 3-Chloro-1-propene 39 6.694 6.689 0.005 90 1997 0.0200 0.0307
33 Carbon disulfide 76 6.840 6.841 -0.001 99 5046 0.0200 0.0251
3/25/2024
9:50:51 AM
Page 413 of 864
Report Date: 07-Mar-2024 08:54:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L1.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
34 trans-1,2-Dichloroethene 96 7.541 7.537 0.004 87 1575 0.0200 0.0221
35 2-Methylpentane 43 7.541 7.540 0.001 90 2544 0.0200 0.0197
36 Methyl tert-butyl ether 73 7.784 7.697 0.087 87 3752 0.0200 0.0200
37 1,1-Dichloroethane 63 7.989 7.990 -0.001 95 2524 0.0200 0.0206
38 Vinyl acetate 43 8.194 8.123 0.071 61 894 0.0200 0.006904
40 Hexane 56 8.582 8.578 0.004 88 885 0.0200 0.0176
41 Isopropyl ether 45 8.835 8.769 0.066 92 4040 0.0200 0.0203 a
42 cis-1,2-Dichloroethene 96 9.029 9.029 0.000 86 1606 0.0200 0.0214
43 Ethyl acetate 43 9.358 9.249 0.109 1 296 0.0200 0.002149
44 Chloroform 83 9.374 9.385 -0.011 49 3359 0.0200 0.0213
45 Tert-butyl ethyl ether 59 9.547 9.478 0.069 94 4075 0.0200 0.0193
46 Tetrahydrofuran 42 9.951 9.838 0.113 71 596 0.0200 0.008899
47 1,1,1-Trichloroethane 97 10.437 10.439 -0.002 91 3181 0.0200 0.0206
48 1,2-Dichloroethane 62 10.566 10.562 0.004 80 1764 0.0200 0.0181
50 Cyclohexane 69 11.035 11.026 0.009 83 545 0.0200 0.0169
51 Benzene 78 11.035 11.035 0.000 96 4884 0.0200 0.0227
52 Carbon tetrachloride 117 11.057 11.053 0.004 92 3191 0.0200 0.0189
53 2,3-Dimethylpentane 71 11.132 11.131 0.001 89 698 0.0200 0.0148
54 Thiophene 84 11.310 11.310 0.000 92 2476 0.0200 0.0204
55 Isooctane 57 11.763 11.762 0.001 96 6996 0.0200 0.0217
56 n-Heptane 71 12.130 12.127 0.003 89 1327 0.0200 0.0186
57 1,2-Dichloropropane 63 12.254 12.244 0.010 84 1553 0.0200 0.0198
58 Trichloroethene 130 12.265 12.270 -0.005 93 2110 0.0200 0.0207
59 Dibromomethane 93 12.383 12.375 0.008 92 2317 0.0200 0.0248
60 Dichlorobromomethane 83 12.513 12.513 0.000 92 2790 0.0200 0.0176
61 1,4-Dioxane 88 12.653 12.557 0.096 1 269 0.0200 0.008630
62 Methyl methacrylate 41 12.572 12.581 -0.009 1 229 0.0200 0.002795
63 Methylcyclohexane 83 13.057 13.056 0.001 92 2490 0.0200 0.0195
64 4-Methyl-2-pentanone (MIBK) 43 13.591 13.508 0.083 38 1709 0.0200 0.0115
65 cis-1,3-Dichloropropene 75 13.570 13.551 0.019 80 1820 0.0200 0.0149
66 trans-1,3-Dichloropropene 75 14.298 14.277 0.021 86 1583 0.0200 0.0149
67 Toluene 91 14.406 14.399 0.007 92 6941 0.0200 0.0263
68 1,1,2-Trichloroethane 83 14.503 14.486 0.017 89 1333 0.0200 0.0172
70 n-Octane 85 15.085 15.078 0.007 78 1499 0.0200 0.0188
71 Chlorodibromomethane 129 15.231 15.218 0.013 93 1880 0.0200 0.0124
72 Ethylene Dibromide 107 15.527 15.519 0.008 66 2827 0.0200 0.0202
73 Tetrachloroethene 129 15.581 15.578 0.003 96 1977 0.0200 0.0209
75 2,3-Dimethylheptane 43 16.455 16.459 -0.004 94 5226 0.0200 0.0247
74 Chlorobenzene 112 16.476 16.477 -0.001 94 4597 0.0200 0.0217
76 Ethylbenzene 91 16.773 16.763 0.010 97 7126 0.0200 0.0210
77 m-Xylene & p-Xylene 91 16.924 16.924 0.000 97 11543 0.0400 0.0435
78 n-Nonane 57 17.317 17.316 0.001 81 2776 0.0200 0.0190
80 Styrene 104 17.420 17.405 0.015 95 2974 0.0200 0.0161
79 Bromoform 173 17.414 17.406 0.008 58 716 0.0200 0.005381
81 o-Xylene 91 17.468 17.462 0.006 96 5748 0.0200 0.0208
82 1,1,2,2-Tetrachloroethane 83 17.797 17.791 0.006 96 4330 0.0200 0.0210
83 1,2,3-Trichloropropane 110 17.948 17.946 0.002 96 1169 0.0200 0.0196
84 Isopropylbenzene 105 18.035 18.033 0.002 91 8590 0.0200 0.0230
85 N-Propylbenzene 120 18.547 18.547 0.000 99 2038 0.0200 0.0195
86 2-Chlorotoluene 126 18.606 18.603 0.003 96 1902 0.0200 0.0203
88 4-Ethyltoluene 105 18.692 18.690 0.002 97 7610 0.0200 0.0199
87 1,3,5-Trimethylbenzene 120 18.757 18.758 -0.001 92 3027 0.0200 0.0191
3/25/2024
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Report Date: 07-Mar-2024 08:54:40 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L1.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
89 Alpha Methyl Styrene 118 18.989 18.985 0.004 87 2331 0.0200 0.0149
90 n-Decane 57 19.005 19.008 -0.003 93 3701 0.0200 0.0184
91 tert-Butylbenzene 119 19.172 19.170 0.002 93 7208 0.0200 0.0210
92 1,2,4-Trimethylbenzene 105 19.189 19.186 0.003 94 6690 0.0200 0.0204
93 sec-Butylbenzene 105 19.431 19.428 0.003 98 9436 0.0200 0.0200
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 96 5076 0.0200 0.0221
95 Benzyl chloride 91 19.534 19.530 0.004 91 5758 0.0200 0.0216
96 1,4-Dichlorobenzene 146 19.550 19.544 0.006 93 5333 0.0200 0.0232
97 4-Isopropyltoluene 119 19.582 19.583 -0.001 97 7850 0.0200 0.0196
98 1,2,3-Trimethylbenzene 105 19.647 19.644 0.003 98 6455 0.0200 0.0194
99 Butylcyclohexane 83 19.685 19.686 -0.001 92 5155 0.0200 0.0196
100 2,3-Dihydroindene 117 19.890 19.890 0.000 93 6764 0.0200 0.0213
101 1,2-Dichlorobenzene 146 19.895 19.896 -0.001 94 4984 0.0200 0.0224
103 n-Butylbenzene 91 20.008 20.004 0.004 97 8326 0.0200 0.0205
102 Indene 116 20.019 20.020 -0.001 88 4818 0.0200 0.0186
104 Undecane 57 20.283 20.283 0.000 90 4625 0.0200 0.0195
105 1,2-Dibromo-3-Chloropropane 157 20.494 20.491 0.003 90 1500 0.0200 0.0135
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.764 -0.001 96 8623 0.0200 0.0211
107 Dodecane 57 21.378 21.379 -0.001 88 7538 0.0200 0.0267
108 1,2,4-Trichlorobenzene 180 21.621 21.620 0.001 94 7286 0.0200 0.0346
109 Naphthalene 128 21.745 21.744 0.001 99 16216 0.0200 0.0344
110 Hexachlorobutadiene 225 21.890 21.891 -0.001 92 5400 0.0200 0.0275
111 1,2,3-Trichlorobenzene 180 21.955 21.953 0.002 95 7178 0.0200 0.0433
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 8856 0.0200 0.0335
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 9259 0.0200 0.0332
A 116 C8 Range 1 15.080 (15.047-15.112) 0 14572 0.0200 0.0203
S 117 Xylenes, Total 100 0 0.0600 0.0642
S 118 1,2-Dichloroethene, Total 1 0 0.0400 0.0435
QC Flag Legend
Processing Flags
Review Flags
a - User Assigned ID
Reagents:
40L1-3DQP_00099 Amount Added: 50.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 415 of 864
Report Date: 07-Mar-2024 08:54:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L1.D
Injection Date:05-Mar-2024 20:04:30 Instrument ID:MR Operator ID:
Lims ID:IC L1 Worklist Smp#:9
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:6
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Y ( X10
0
0
0
0
)
RZC05L1[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
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)+
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( 1
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.
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-
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(IS
)(
1
6
.
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$ 4
-
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)(
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)
3/25/2024
9:50:51 AM
Page 416 of 864
Report Date: 07-Mar-2024 08:54:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L1.D
Injection Date:05-Mar-2024 20:04:30 Instrument ID:MR
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:6 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
11
15
19
23
27
31
35
39
43
47
51
55
59
63
67
71
75
79
Y ( X10
0
)
RZC05L1[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 417 of 864
Report Date: 07-Mar-2024 08:54:58 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L2.D
Lims ID:IC L2
Client ID:
Sample Type:IC Calib Level:2
Inject. Date:05-Mar-2024 20:51:30 ALS Bottle#:6 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-010
Misc. Info.:663623 100mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:54:58 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:51:49
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.375 -0.006 84 217758 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.562 -0.004 95 1017540 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.429 -0.001 87 910928 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.073 -0.001 91 667978 4.08 4.01
6 Chlorodifluoromethane 51 3.793 3.788 0.005 96 4038 0.0400 0.0435
7 Propene 41 3.799 3.795 0.004 65 1998 0.0400 0.0479
8 Dichlorodifluoromethane 85 3.853 3.853 0.000 99 6445 0.0400 0.0430
9 Chloromethane 52 4.058 4.060 -0.002 54 1033 0.0400 0.0613
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.074 4.070 0.004 91 4946 0.0400 0.0427
12 Vinyl chloride 62 4.257 4.253 0.004 95 2556 0.0400 0.0416
11 Acetaldehyde 44 4.273 4.257 0.016 81 8153 0.2000 0.3219
13 Butane 43 4.354 4.351 0.003 83 4040 0.0400 0.0463
14 Butadiene 54 4.360 4.353 0.007 67 1682 0.0400 0.0376
15 Bromomethane 94 4.721 4.716 0.005 94 2872 0.0400 0.0467
16 Chloroethane 64 4.883 4.876 0.007 92 1321 0.0400 0.0409
17 Ethanol 31 5.066 5.041 0.025 93 8713 0.2000 0.3278
18 Vinyl bromide 106 5.217 5.215 0.002 94 2348 0.0400 0.0379
19 2-Methylbutane 43 5.265 5.263 0.002 91 2821 0.0400 0.0450
20 Trichlorofluoromethane 101 5.508 5.510 -0.002 99 6608 0.0400 0.0408
21 Acrolein 56 5.584 5.548 0.036 36 329 0.0400 0.0197
22 Acetonitrile 40 5.643 5.636 0.007 89 1394 0.0400 0.0623
23 Acetone 58 5.729 5.692 0.037 97 4728 0.1200 0.1587
25 Pentane 72 5.745 5.747 -0.002 87 390 0.0400 0.0351
24 Isopropyl alcohol 45 5.880 5.824 0.056 97 8648 0.1200 0.1196
26 Ethyl ether 31 6.010 5.971 0.039 92 2251 0.0400 0.0399
27 1,1-Dichloroethene 96 6.285 6.288 -0.003 97 2432 0.0400 0.0383
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.468 6.471 -0.003 95 5672 0.0400 0.0407
29 Acrylonitrile 53 6.484 6.451 0.033 37 970 0.0400 0.0252
28 2-Methyl-2-propanol 59 6.587 6.501 0.086 97 3384 0.0400 0.0309
31 Methylene Chloride 84 6.673 6.672 0.001 87 6878 0.0400 0.1003
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Page 418 of 864
Report Date: 07-Mar-2024 08:54:58 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L2.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.689 6.689 0.000 94 3427 0.0400 0.0566
33 Carbon disulfide 76 6.840 6.841 -0.001 99 7947 0.0400 0.0424
34 trans-1,2-Dichloroethene 96 7.541 7.538 0.003 89 2623 0.0400 0.0396
35 2-Methylpentane 43 7.546 7.541 0.005 88 4675 0.0400 0.0389
36 Methyl tert-butyl ether 73 7.762 7.710 0.052 94 6725 0.0400 0.0386
37 1,1-Dichloroethane 63 7.994 7.991 0.003 96 4365 0.0400 0.0383
38 Vinyl acetate 43 8.177 8.134 0.043 98 1978 0.0400 0.0164
40 Hexane 56 8.576 8.577 -0.001 87 1834 0.0400 0.0391
41 Isopropyl ether 45 8.824 8.780 0.044 94 6679 0.0400 0.0360
42 cis-1,2-Dichloroethene 96 9.029 9.029 0.000 92 2701 0.0400 0.0387
43 Ethyl acetate 43 9.310 9.261 0.049 89 2952 0.0400 0.0230
44 Chloroform 83 9.380 9.384 -0.004 81 5920 0.0400 0.0404
45 Tert-butyl ethyl ether 59 9.536 9.490 0.046 95 6939 0.0400 0.0353
46 Tetrahydrofuran 42 9.919 9.854 0.065 70 2042 0.0400 0.0328
47 1,1,1-Trichloroethane 97 10.437 10.439 -0.002 95 5746 0.0400 0.0401
48 1,2-Dichloroethane 62 10.566 10.563 0.003 93 3137 0.0400 0.0341
51 Benzene 78 11.041 11.036 0.005 96 8717 0.0400 0.0431
50 Cyclohexane 69 11.025 11.026 -0.002 88 988 0.0400 0.0325
52 Carbon tetrachloride 117 11.051 11.052 -0.001 77 5596 0.0400 0.0351
53 2,3-Dimethylpentane 71 11.122 11.129 -0.007 89 1470 0.0400 0.0330
54 Thiophene 84 11.310 11.310 0.000 90 4254 0.0400 0.0372
55 Isooctane 57 11.769 11.763 0.006 97 12086 0.0400 0.0398
56 n-Heptane 71 12.125 12.127 -0.002 84 2550 0.0400 0.0380
57 1,2-Dichloropropane 63 12.254 12.246 0.008 85 2880 0.0400 0.0390
58 Trichloroethene 130 12.270 12.270 0.000 93 3598 0.0400 0.0375
59 Dibromomethane 93 12.378 12.376 0.002 94 4300 0.0400 0.0490
60 Dichlorobromomethane 83 12.518 12.514 0.004 96 4949 0.0400 0.0332
62 Methyl methacrylate 41 12.653 12.596 0.057 79 619 0.0400 0.008025
61 1,4-Dioxane 88 12.637 12.573 0.064 72 983 0.0400 0.0335
63 Methylcyclohexane 83 13.052 13.055 -0.003 92 4489 0.0400 0.0373
65 cis-1,3-Dichloropropene 75 13.559 13.552 0.007 93 3700 0.0400 0.0322
64 4-Methyl-2-pentanone (MIBK) 43 13.570 13.520 0.050 79 3892 0.0400 0.0279
66 trans-1,3-Dichloropropene 75 14.303 14.283 0.020 96 3005 0.0400 0.0299
67 Toluene 91 14.406 14.400 0.006 92 10674 0.0400 0.0427
68 1,1,2-Trichloroethane 83 14.492 14.487 0.005 93 2691 0.0400 0.0366
69 2-Hexanone 58 14.983 14.895 0.087 79 937 0.0400 0.0131
70 n-Octane 85 15.085 15.080 0.005 85 2788 0.0400 0.0369
71 Chlorodibromomethane 129 15.225 15.220 0.005 93 3573 0.0400 0.0248
72 Ethylene Dibromide 107 15.533 15.522 0.011 94 4839 0.0400 0.0365
73 Tetrachloroethene 129 15.581 15.579 0.002 95 3656 0.0400 0.0407
75 2,3-Dimethylheptane 43 16.460 16.459 0.001 85 8503 0.0400 0.0425
74 Chlorobenzene 112 16.476 16.477 -0.001 96 8204 0.0400 0.0409
76 Ethylbenzene 91 16.767 16.764 0.003 98 12534 0.0400 0.0389
77 m-Xylene & p-Xylene 91 16.924 16.924 0.000 98 19591 0.0800 0.0778
78 n-Nonane 57 17.317 17.316 0.001 82 4866 0.0400 0.0351
79 Bromoform 173 17.414 17.408 0.006 54 1607 0.0400 0.0127
80 Styrene 104 17.404 17.405 -0.001 97 5619 0.0400 0.0321
81 o-Xylene 91 17.463 17.462 0.001 99 9957 0.0400 0.0380
82 1,1,2,2-Tetrachloroethane 83 17.792 17.791 0.001 97 7381 0.0400 0.0377
83 1,2,3-Trichloropropane 110 17.954 17.947 0.007 95 2134 0.0400 0.0378
84 Isopropylbenzene 105 18.029 18.032 -0.003 92 14176 0.0400 0.0401
85 N-Propylbenzene 120 18.547 18.547 0.000 98 3443 0.0400 0.0347
3/25/2024
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Report Date: 07-Mar-2024 08:54:58 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L2.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
86 2-Chlorotoluene 126 18.606 18.604 0.002 97 3199 0.0400 0.0360
88 4-Ethyltoluene 105 18.692 18.690 0.002 98 13498 0.0400 0.0373
87 1,3,5-Trimethylbenzene 120 18.763 18.759 0.004 93 5705 0.0400 0.0379
89 Alpha Methyl Styrene 118 18.984 18.985 -0.001 89 4174 0.0400 0.0281
90 n-Decane 57 19.011 19.008 0.003 94 6507 0.0400 0.0342
91 tert-Butylbenzene 119 19.167 19.169 -0.002 93 12390 0.0400 0.0381
92 1,2,4-Trimethylbenzene 105 19.189 19.186 0.003 95 11490 0.0400 0.0369
93 sec-Butylbenzene 105 19.426 19.428 -0.002 98 16707 0.0400 0.0373
94 1,3-Dichlorobenzene 146 19.464 19.459 0.005 97 8724 0.0400 0.0401
95 Benzyl chloride 91 19.534 19.530 0.004 98 9245 0.0400 0.0366
96 1,4-Dichlorobenzene 146 19.544 19.544 0.000 95 9246 0.0400 0.0425
97 4-Isopropyltoluene 119 19.582 19.583 -0.001 97 14078 0.0400 0.0371
98 1,2,3-Trimethylbenzene 105 19.647 19.645 0.002 98 11833 0.0400 0.0375
99 Butylcyclohexane 83 19.685 19.686 -0.001 94 9340 0.0400 0.0374
100 2,3-Dihydroindene 117 19.890 19.890 0.000 93 10854 0.0400 0.0360
101 1,2-Dichlorobenzene 146 19.900 19.897 0.003 92 8474 0.0400 0.0401
103 n-Butylbenzene 91 20.003 20.004 -0.001 99 14265 0.0400 0.0371
102 Indene 116 20.019 20.020 -0.001 92 8461 0.0400 0.0344
104 Undecane 57 20.283 20.283 0.000 90 8295 0.0400 0.0370
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.490 -0.002 92 2208 0.0400 0.0210
106 1,2,4,5-Tetramethylbenzene 119 20.769 20.765 0.004 96 14624 0.0400 0.0378
107 Dodecane 57 21.378 21.379 -0.001 95 17060 0.0400 0.0638
108 1,2,4-Trichlorobenzene 180 21.621 21.620 0.001 95 10727 0.0400 0.0538
109 Naphthalene 128 21.745 21.744 0.001 99 24848 0.0400 0.0556
110 Hexachlorobutadiene 225 21.890 21.891 -0.001 93 10445 0.0400 0.0562
111 1,2,3-Trichlorobenzene 180 21.949 21.953 -0.004 95 11504 0.0400 0.0732
112 2-Methylnaphthalene 142 22.489 22.489 0.000 98 12564 0.0400 0.0501
113 1-Methylnaphthalene 142 22.618 22.618 0.000 98 14514 0.0400 0.0550
A 116 C8 Range 1 15.085 (15.047-15.123) 0 24457 0.0400 0.0361
S 117 Xylenes, Total 100 0 0.1200 0.1158
S 118 1,2-Dichloroethene, Total 1 0 0.0800 0.0783
QC Flag Legend
Processing Flags
Reagents:
40L1-3DQP_00099 Amount Added: 100.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Page 420 of 864
Report Date: 07-Mar-2024 08:54:58 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L2.D
Injection Date:05-Mar-2024 20:51:30 Instrument ID:MR Operator ID:
Lims ID:IC L2 Worklist Smp#:10
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:6
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
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3/25/2024
9:50:51 AM
Page 421 of 864
Report Date: 07-Mar-2024 08:54:58 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L2.D
Injection Date:05-Mar-2024 20:51:30 Instrument ID:MR
Lims ID:IC L2
Client ID:
Operator ID:ALS Bottle#:6 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
1
2
3
4
5
6
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8
9
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RZC05L2[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 422 of 864
Report Date: 07-Mar-2024 08:55:18 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L3.D
Lims ID:IC L3
Client ID:
Sample Type:IC Calib Level:3
Inject. Date:05-Mar-2024 21:39:30 ALS Bottle#:6 Worklist Smp#:11
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-011
Misc. Info.:663623 200mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:55:17 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:51:30
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.374 -0.005 85 208085 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.561 -0.003 95 972773 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.428 0.000 87 872917 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.073 -0.001 90 640155 4.08 4.01
6 Chlorodifluoromethane 51 3.793 3.789 0.004 96 7236 0.0800 0.0815
7 Propene 41 3.799 3.796 0.003 63 3561 0.0800 0.0894
8 Dichlorodifluoromethane 85 3.853 3.853 0.000 100 11068 0.0800 0.0773
9 Chloromethane 52 4.068 4.061 0.007 50 1550 0.0800 0.0963
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.068 4.070 -0.002 92 8996 0.0800 0.0812
12 Vinyl chloride 62 4.252 4.253 -0.001 97 4828 0.0800 0.0823
11 Acetaldehyde 44 4.273 4.260 0.013 85 14569 0.4000 0.6019
13 Butane 43 4.349 4.350 -0.001 95 7737 0.0800 0.0927
14 Butadiene 54 4.354 4.353 0.001 89 3333 0.0800 0.0780
15 Bromomethane 94 4.715 4.716 -0.001 96 4836 0.0800 0.0823
16 Chloroethane 64 4.888 4.878 0.010 95 2621 0.0800 0.0850
17 Ethanol 31 5.060 5.044 0.016 95 15541 0.4000 0.6119
18 Vinyl bromide 106 5.217 5.215 0.002 97 4933 0.0800 0.0832
19 2-Methylbutane 43 5.265 5.264 0.001 88 5406 0.0800 0.0901
20 Trichlorofluoromethane 101 5.503 5.509 -0.006 99 12250 0.0800 0.0792
21 Acrolein 56 5.578 5.554 0.024 61 933 0.0800 0.0584
22 Acetonitrile 40 5.654 5.639 0.015 96 1497 0.0800 0.0700
23 Acetone 58 5.724 5.698 0.026 98 8287 0.2400 0.2911
25 Pentane 72 5.751 5.747 0.004 47 755 0.0800 0.0710
24 Isopropyl alcohol 45 5.864 5.831 0.033 98 15816 0.2400 0.2290
26 Ethyl ether 31 5.993 5.974 0.019 87 4056 0.0800 0.0752
27 1,1-Dichloroethene 96 6.285 6.287 -0.003 98 4730 0.0800 0.0780
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.473 6.471 0.002 95 10601 0.0800 0.0796
29 Acrylonitrile 53 6.452 6.451 0.001 88 2077 0.0800 0.0564
28 2-Methyl-2-propanol 59 6.576 6.514 0.062 95 8027 0.0800 0.0768
31 Methylene Chloride 84 6.667 6.671 -0.004 91 9853 0.0800 0.1503
3/25/2024
9:50:51 AM
Page 423 of 864
Report Date: 07-Mar-2024 08:55:18 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L3.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.684 6.688 -0.004 94 6411 0.0800 0.1107
33 Carbon disulfide 76 6.840 6.841 -0.001 99 14526 0.0800 0.0812
34 trans-1,2-Dichloroethene 96 7.541 7.538 0.003 80 5029 0.0800 0.0795
35 2-Methylpentane 43 7.546 7.542 0.004 90 9012 0.0800 0.0786
36 Methyl tert-butyl ether 73 7.762 7.719 0.043 93 12848 0.0800 0.0771
37 1,1-Dichloroethane 63 7.989 7.990 -0.002 98 8659 0.0800 0.0796
38 Vinyl acetate 43 8.145 8.136 0.009 99 6329 0.0800 0.0550
40 Hexane 56 8.587 8.579 0.008 88 3425 0.0800 0.0765
39 2-Butanone (MEK) 72 8.684 8.605 0.079 99 1540 0.0800 0.0535
41 Isopropyl ether 45 8.814 8.786 0.028 92 13004 0.0800 0.0734
42 cis-1,2-Dichloroethene 96 9.024 9.028 -0.004 91 5114 0.0800 0.0767
43 Ethyl acetate 43 9.288 9.266 0.022 97 6882 0.0800 0.0562
44 Chloroform 83 9.380 9.383 -0.003 29 11001 0.0800 0.0786
45 Tert-butyl ethyl ether 59 9.525 9.496 0.029 95 13982 0.0800 0.0743
46 Tetrahydrofuran 42 9.908 9.863 0.045 83 4067 0.0800 0.0683
47 1,1,1-Trichloroethane 97 10.437 10.438 -0.001 97 10812 0.0800 0.0789
48 1,2-Dichloroethane 62 10.561 10.562 -0.001 96 6289 0.0800 0.0716
49 n-Butanol 31 11.192 11.051 0.141 7 312 0.0800 0.1202
50 Cyclohexane 69 11.024 11.025 -0.001 69 2056 0.0800 0.0707
51 Benzene 78 11.035 11.036 -0.001 96 15949 0.0800 0.0825
52 Carbon tetrachloride 117 11.051 11.052 -0.001 96 10305 0.0800 0.0677
53 2,3-Dimethylpentane 71 11.127 11.129 -0.002 89 2939 0.0800 0.0691
54 Thiophene 84 11.316 11.311 0.005 93 8487 0.0800 0.0776
55 Isooctane 57 11.763 11.763 0.000 98 22075 0.0800 0.0761
56 n-Heptane 71 12.135 12.128 0.007 88 4642 0.0800 0.0723
57 1,2-Dichloropropane 63 12.248 12.247 0.001 86 5646 0.0800 0.0799
58 Trichloroethene 130 12.270 12.270 0.000 95 6996 0.0800 0.0763
59 Dibromomethane 93 12.367 12.374 -0.007 95 7675 0.0800 0.0914
60 Dichlorobromomethane 83 12.518 12.515 0.003 98 9687 0.0800 0.0679
61 1,4-Dioxane 88 12.621 12.581 0.040 63 1783 0.0800 0.0636
62 Methyl methacrylate 41 12.631 12.602 0.029 91 3296 0.0800 0.0447
63 Methylcyclohexane 83 13.057 13.056 0.001 94 8258 0.0800 0.0718
65 cis-1,3-Dichloropropene 75 13.559 13.553 0.006 96 7283 0.0800 0.0663
64 4-Methyl-2-pentanone (MIBK) 43 13.543 13.524 0.019 97 7972 0.0800 0.0597
66 trans-1,3-Dichloropropene 75 14.287 14.283 0.004 97 6176 0.0800 0.0642
67 Toluene 91 14.400 14.400 0.000 92 19599 0.0800 0.0819
68 1,1,2-Trichloroethane 83 14.492 14.488 0.004 96 5635 0.0800 0.0799
69 2-Hexanone 58 14.934 14.903 0.031 92 3198 0.0800 0.0468
70 n-Octane 85 15.079 15.080 -0.001 86 5501 0.0800 0.0760
71 Chlorodibromomethane 129 15.220 15.220 0.000 96 7133 0.0800 0.0517
72 Ethylene Dibromide 107 15.527 15.523 0.004 98 8894 0.0800 0.0700
73 Tetrachloroethene 129 15.581 15.579 0.002 95 6478 0.0800 0.0753
75 2,3-Dimethylheptane 43 16.460 16.459 0.001 90 15202 0.0800 0.0793
74 Chlorobenzene 112 16.481 16.478 0.003 96 15633 0.0800 0.0813
76 Ethylbenzene 91 16.762 16.764 -0.002 99 23625 0.0800 0.0766
77 m-Xylene & p-Xylene 91 16.924 16.924 0.000 98 36139 0.1600 0.1499
78 n-Nonane 57 17.317 17.316 0.001 85 9173 0.0800 0.0691
80 Styrene 104 17.409 17.405 0.004 98 11110 0.0800 0.0661
79 Bromoform 173 17.409 17.408 0.001 56 3092 0.0800 0.0256
81 o-Xylene 91 17.463 17.462 0.001 98 18838 0.0800 0.0750
82 1,1,2,2-Tetrachloroethane 83 17.792 17.791 0.001 98 14503 0.0800 0.0773
83 1,2,3-Trichloropropane 110 17.943 17.946 -0.003 95 4165 0.0800 0.0770
3/25/2024
9:50:51 AM
Page 424 of 864
Report Date: 07-Mar-2024 08:55:18 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L3.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.029 18.032 -0.003 89 25863 0.0800 0.0764
85 N-Propylbenzene 120 18.547 18.547 0.000 100 7027 0.0800 0.0740
86 2-Chlorotoluene 126 18.606 18.604 0.002 97 6321 0.0800 0.0742
88 4-Ethyltoluene 105 18.692 18.691 0.001 98 25898 0.0800 0.0748
87 1,3,5-Trimethylbenzene 120 18.757 18.759 -0.002 92 10317 0.0800 0.0716
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 87 7925 0.0800 0.0557
90 n-Decane 57 19.005 19.008 -0.003 94 12353 0.0800 0.0677
91 tert-Butylbenzene 119 19.167 19.169 -0.002 93 23775 0.0800 0.0762
92 1,2,4-Trimethylbenzene 105 19.183 19.186 -0.003 96 22685 0.0800 0.0761
93 sec-Butylbenzene 105 19.426 19.428 -0.002 98 32113 0.0800 0.0749
94 1,3-Dichlorobenzene 146 19.458 19.459 -0.001 96 16903 0.0800 0.0812
95 Benzyl chloride 91 19.534 19.531 0.003 98 17319 0.0800 0.0716
96 1,4-Dichlorobenzene 146 19.544 19.544 0.000 94 17136 0.0800 0.0821
97 4-Isopropyltoluene 119 19.577 19.582 -0.005 98 27300 0.0800 0.0751
98 1,2,3-Trimethylbenzene 105 19.641 19.644 -0.003 98 22011 0.0800 0.0728
99 Butylcyclohexane 83 19.679 19.685 -0.006 96 18167 0.0800 0.0759
100 2,3-Dihydroindene 117 19.884 19.889 -0.005 93 21858 0.0800 0.0757
101 1,2-Dichlorobenzene 146 19.895 19.897 -0.002 96 16367 0.0800 0.0809
103 n-Butylbenzene 91 20.003 20.004 -0.001 97 29038 0.0800 0.0788
102 Indene 116 20.019 20.020 -0.001 90 16320 0.0800 0.0693
104 Undecane 57 20.283 20.283 0.000 90 16451 0.0800 0.0766
105 1,2-Dibromo-3-Chloropropane 157 20.493 20.491 0.002 94 4066 0.0800 0.0403
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.765 -0.002 96 28758 0.0800 0.0775
107 Dodecane 57 21.378 21.379 -0.001 94 29781 0.0800 0.1162
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 93 18608 0.0800 0.0974
109 Naphthalene 128 21.744 21.744 0.000 99 42950 0.0800 0.1002
110 Hexachlorobutadiene 225 21.890 21.891 -0.001 93 18686 0.0800 0.1054
111 1,2,3-Trichlorobenzene 180 21.955 21.953 0.002 95 18851 0.0800 0.1251
112 2-Methylnaphthalene 142 22.489 22.489 0.000 98 21529 0.0800 0.0897
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 27169 0.0800 0.1074
A 116 C8 Range 1 15.079 (15.031-15.117) 0 46112 0.0800 0.0713
S 117 Xylenes, Total 100 0 0.2400 0.2248
S 118 1,2-Dichloroethene, Total 1 0 0.1600 0.1561
QC Flag Legend
Processing Flags
Reagents:
40L1-3DQP_00099 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 425 of 864
Report Date: 07-Mar-2024 08:55:18 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L3.D
Injection Date:05-Mar-2024 21:39:30 Instrument ID:MR Operator ID:
Lims ID:IC L3 Worklist Smp#:11
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:6
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
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RZC05L3[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 426 of 864
Report Date: 07-Mar-2024 08:55:18 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L3.D
Injection Date:05-Mar-2024 21:39:30 Instrument ID:MR
Lims ID:IC L3
Client ID:
Operator ID:ALS Bottle#:6 Worklist Smp#:11
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
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9
11
13
15
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3/25/2024
9:50:51 AM
Page 427 of 864
Report Date: 07-Mar-2024 08:55:38 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L4.D
Lims ID:IC L4
Client ID:
Sample Type:IC Calib Level:4
Inject. Date:05-Mar-2024 22:24:30 ALS Bottle#:7 Worklist Smp#:12
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-012
Misc. Info.:663621 80mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:55:38 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:51:10
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.374 -0.005 85 210527 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.561 -0.003 95 978091 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.428 0.000 87 876587 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.073 -0.001 91 647263 4.08 4.04
6 Chlorodifluoromethane 51 3.793 3.789 0.004 98 15284 0.1600 0.1701
7 Propene 41 3.799 3.796 0.003 91 6484 0.1600 0.1608
8 Dichlorodifluoromethane 85 3.858 3.853 0.005 100 26389 0.1600 0.1822
9 Chloromethane 52 4.068 4.062 0.006 54 3010 0.1600 0.1848
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.074 4.071 0.003 93 18892 0.1600 0.1686
12 Vinyl chloride 62 4.257 4.253 0.004 98 10500 0.1600 0.1769
11 Acetaldehyde 44 4.268 4.261 0.007 88 22908 0.8000 0.9354
13 Butane 43 4.349 4.350 -0.001 84 15184 0.1600 0.1798
14 Butadiene 54 4.354 4.353 0.001 69 7473 0.1600 0.1728
15 Bromomethane 94 4.715 4.716 -0.001 98 10521 0.1600 0.1770
16 Chloroethane 64 4.883 4.879 0.003 96 5584 0.1600 0.1790
17 Ethanol 31 5.050 5.045 0.005 95 22466 0.8000 0.8744
18 Vinyl bromide 106 5.217 5.215 0.002 98 10236 0.1600 0.1707
19 2-Methylbutane 43 5.265 5.264 0.001 88 10147 0.1600 0.1672
20 Trichlorofluoromethane 101 5.508 5.509 -0.001 99 26238 0.1600 0.1677
21 Acrolein 56 5.573 5.557 0.016 90 2472 0.1600 0.1529
22 Acetonitrile 40 5.643 5.640 0.003 97 3120 0.1600 0.1443
23 Acetone 58 5.713 5.700 0.013 96 15234 0.4800 0.5290
25 Pentane 72 5.751 5.748 0.003 61 1790 0.1600 0.1664
24 Isopropyl alcohol 45 5.842 5.832 0.010 98 33087 0.4800 0.4734
26 Ethyl ether 31 5.988 5.976 0.012 91 8686 0.1600 0.1592
27 1,1-Dichloroethene 96 6.290 6.288 0.002 99 10260 0.1600 0.1672
29 Acrylonitrile 53 6.446 6.450 -0.004 90 4916 0.1600 0.1320
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.468 6.471 -0.003 96 22537 0.1600 0.1673
28 2-Methyl-2-propanol 59 6.543 6.518 0.025 95 16221 0.1600 0.1533
31 Methylene Chloride 84 6.667 6.670 -0.003 90 15379 0.1600 0.2319
3/25/2024
9:50:51 AM
Page 428 of 864
Report Date: 07-Mar-2024 08:55:38 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L4.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.689 6.688 0.001 98 8252 0.1600 0.1409
33 Carbon disulfide 76 6.840 6.841 -0.001 99 31129 0.1600 0.1719
34 trans-1,2-Dichloroethene 96 7.530 7.537 -0.007 96 10323 0.1600 0.1613
35 2-Methylpentane 43 7.541 7.542 -0.001 91 18535 0.1600 0.1597
36 Methyl tert-butyl ether 73 7.735 7.721 0.014 96 27450 0.1600 0.1628
37 1,1-Dichloroethane 63 7.989 7.990 -0.002 99 18078 0.1600 0.1643
38 Vinyl acetate 43 8.129 8.135 -0.006 98 16317 0.1600 0.1401
40 Hexane 56 8.576 8.579 -0.003 87 7469 0.1600 0.1648
39 2-Butanone (MEK) 72 8.646 8.613 0.033 97 4147 0.1600 0.1423
41 Isopropyl ether 45 8.797 8.787 0.010 94 28907 0.1600 0.1613
42 cis-1,2-Dichloroethene 96 9.024 9.028 -0.004 93 11144 0.1600 0.1651
43 Ethyl acetate 43 9.261 9.265 -0.004 98 18760 0.1600 0.1515
44 Chloroform 83 9.380 9.383 -0.003 74 23402 0.1600 0.1652
45 Tert-butyl ethyl ether 59 9.515 9.498 0.017 95 30376 0.1600 0.1596
46 Tetrahydrofuran 42 9.881 9.866 0.015 86 9249 0.1600 0.1535
47 1,1,1-Trichloroethane 97 10.437 10.438 -0.001 97 22269 0.1600 0.1607
48 1,2-Dichloroethane 62 10.561 10.562 -0.001 97 14429 0.1600 0.1633
50 Cyclohexane 69 11.019 11.024 -0.005 92 4448 0.1600 0.1521
51 Benzene 78 11.030 11.035 -0.005 97 31598 0.1600 0.1626
52 Carbon tetrachloride 117 11.051 11.052 -0.001 97 20696 0.1600 0.1353
53 2,3-Dimethylpentane 71 11.127 11.128 -0.001 88 6955 0.1600 0.1627
49 n-Butanol 31 11.127 11.066 0.061 70 1453 0.1600 0.1673
54 Thiophene 84 11.310 11.311 -0.001 95 17337 0.1600 0.1576
55 Isooctane 57 11.758 11.762 -0.004 98 47024 0.1600 0.1613
56 n-Heptane 71 12.124 12.128 -0.004 87 10208 0.1600 0.1581
57 1,2-Dichloropropane 63 12.243 12.246 -0.003 87 11557 0.1600 0.1626
58 Trichloroethene 130 12.270 12.270 0.000 98 15467 0.1600 0.1679
59 Dibromomethane 93 12.373 12.374 -0.002 96 13844 0.1600 0.1640
60 Dichlorobromomethane 83 12.513 12.514 -0.001 98 23205 0.1600 0.1618
61 1,4-Dioxane 88 12.599 12.584 0.015 92 3994 0.1600 0.1416
62 Methyl methacrylate 41 12.621 12.604 0.017 94 9745 0.1600 0.1314
63 Methylcyclohexane 83 13.052 13.055 -0.003 94 18250 0.1600 0.1578
64 4-Methyl-2-pentanone (MIBK) 43 13.537 13.526 0.011 95 18821 0.1600 0.1402
65 cis-1,3-Dichloropropene 75 13.559 13.554 0.005 97 16937 0.1600 0.1533
66 trans-1,3-Dichloropropene 75 14.276 14.282 -0.006 97 15068 0.1600 0.1559
67 Toluene 91 14.400 14.400 0.000 92 39658 0.1600 0.1650
68 1,1,2-Trichloroethane 83 14.486 14.488 -0.002 97 11599 0.1600 0.1638
69 2-Hexanone 58 14.912 14.904 0.008 95 8697 0.1600 0.1268
70 n-Octane 85 15.079 15.079 0.000 87 11734 0.1600 0.1614
71 Chlorodibromomethane 129 15.214 15.219 -0.005 97 22138 0.1600 0.1599
72 Ethylene Dibromide 107 15.516 15.522 -0.006 98 20304 0.1600 0.1591
73 Tetrachloroethene 129 15.576 15.579 -0.003 96 14458 0.1600 0.1675
75 2,3-Dimethylheptane 43 16.460 16.459 0.001 91 30382 0.1600 0.1577
74 Chlorobenzene 112 16.481 16.478 0.003 96 31444 0.1600 0.1629
76 Ethylbenzene 91 16.762 16.763 -0.001 98 48799 0.1600 0.1576
77 m-Xylene & p-Xylene 91 16.924 16.924 0.000 98 75227 0.3200 0.3106
78 n-Nonane 57 17.317 17.317 0.000 86 19334 0.1600 0.1450
80 Styrene 104 17.404 17.405 -0.001 97 25124 0.1600 0.1489
79 Bromoform 173 17.409 17.408 0.001 90 21257 0.1600 0.1752
81 o-Xylene 91 17.458 17.461 -0.003 98 41123 0.1600 0.1629
82 1,1,2,2-Tetrachloroethane 83 17.786 17.790 -0.004 98 29916 0.1600 0.1589
83 1,2,3-Trichloropropane 110 17.948 17.947 0.001 97 8892 0.1600 0.1637
3/25/2024
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Page 429 of 864
Report Date: 07-Mar-2024 08:55:38 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L4.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.029 18.031 -0.002 92 53731 0.1600 0.1581
85 N-Propylbenzene 120 18.552 18.548 0.004 99 14405 0.1600 0.1511
86 2-Chlorotoluene 126 18.601 18.604 -0.003 97 13928 0.1600 0.1627
88 4-Ethyltoluene 105 18.687 18.690 -0.003 99 53620 0.1600 0.1541
87 1,3,5-Trimethylbenzene 120 18.757 18.759 -0.002 92 22689 0.1600 0.1568
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 87 18550 0.1600 0.1299
90 n-Decane 57 19.005 19.007 -0.002 94 27178 0.1600 0.1484
91 tert-Butylbenzene 119 19.167 19.168 -0.001 93 49688 0.1600 0.1586
92 1,2,4-Trimethylbenzene 105 19.183 19.185 -0.002 96 47385 0.1600 0.1583
93 sec-Butylbenzene 105 19.426 19.427 -0.001 99 67026 0.1600 0.1557
94 1,3-Dichlorobenzene 146 19.458 19.459 -0.001 97 34135 0.1600 0.1632
95 Benzyl chloride 91 19.528 19.531 -0.003 98 33377 0.1600 0.1373
96 1,4-Dichlorobenzene 146 19.544 19.544 0.000 95 34438 0.1600 0.1643
97 4-Isopropyltoluene 119 19.582 19.582 0.000 98 57529 0.1600 0.1575
98 1,2,3-Trimethylbenzene 105 19.641 19.644 -0.003 98 47880 0.1600 0.1576
99 Butylcyclohexane 83 19.679 19.684 -0.005 95 38688 0.1600 0.1610
100 2,3-Dihydroindene 117 19.889 19.889 0.000 94 46124 0.1600 0.1590
101 1,2-Dichlorobenzene 146 19.895 19.896 -0.001 97 33977 0.1600 0.1672
103 n-Butylbenzene 91 20.003 20.004 -0.001 98 58926 0.1600 0.1592
102 Indene 116 20.019 20.020 -0.001 89 36359 0.1600 0.1538
104 Undecane 57 20.283 20.283 0.000 92 32868 0.1600 0.1523
105 1,2-Dibromo-3-Chloropropane 157 20.493 20.491 0.002 94 16196 0.1600 0.1598
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.765 -0.002 97 56244 0.1600 0.1510
107 Dodecane 57 21.378 21.379 -0.001 93 42893 0.1600 0.1666
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 92 32424 0.1600 0.1690
109 Naphthalene 128 21.744 21.744 0.000 99 73500 0.1600 0.1708
110 Hexachlorobutadiene 225 21.890 21.891 -0.001 94 30585 0.1600 0.1728
111 1,2,3-Trichlorobenzene 180 21.949 21.952 -0.003 94 30487 0.1600 0.2015
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 37416 0.1600 0.1552
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 44196 0.1600 0.1740
A 116 C8 Range 1 15.079 (15.042-15.117) 0 98859 0.1600 0.1520
S 117 Xylenes, Total 100 0 0.4800 0.4736
S 118 1,2-Dichloroethene, Total 1 0 0.3200 0.3264
QC Flag Legend
Processing Flags
Reagents:
40L5DQP_00053 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 430 of 864
Report Date: 07-Mar-2024 08:55:38 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L4.D
Injection Date:05-Mar-2024 22:24:30 Instrument ID:MR Operator ID:
Lims ID:IC L4 Worklist Smp#:12
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
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3/25/2024
9:50:51 AM
Page 431 of 864
Report Date: 07-Mar-2024 08:55:38 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L4.D
Injection Date:05-Mar-2024 22:24:30 Instrument ID:MR
Lims ID:IC L4
Client ID:
Operator ID:ALS Bottle#:7 Worklist Smp#:12
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
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RZC05L4[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 432 of 864
Report Date: 07-Mar-2024 08:56:00 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L5.D
Lims ID:IC L5
Client ID:
Sample Type:IC Calib Level:5
Inject. Date:05-Mar-2024 23:11:30 ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-013
Misc. Info.:663621 200mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:55:59 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:50:49
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.373 -0.004 85 204066 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.560 -0.002 94 952471 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.428 0.000 87 856899 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.073 -0.001 91 626743 4.08 4.00
6 Chlorodifluoromethane 51 3.793 3.790 0.003 97 35196 0.4000 0.4042
7 Propene 41 3.799 3.797 0.002 96 15573 0.4000 0.3985
8 Dichlorodifluoromethane 85 3.858 3.854 0.004 100 54804 0.4000 0.3904
9 Chloromethane 52 4.063 4.062 0.001 57 6645 0.4000 0.4208
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.074 4.071 0.003 93 43658 0.4000 0.4020
12 Vinyl chloride 62 4.257 4.254 0.003 99 22932 0.4000 0.3986
11 Acetaldehyde 44 4.262 4.261 0.001 91 52488 2.00 2.21
13 Butane 43 4.349 4.350 -0.001 93 33324 0.4000 0.4071
14 Butadiene 54 4.354 4.353 0.001 95 16729 0.4000 0.3992
15 Bromomethane 94 4.715 4.716 -0.001 98 24323 0.4000 0.4223
16 Chloroethane 64 4.872 4.878 -0.006 98 12777 0.4000 0.4226
17 Ethanol 31 5.044 5.045 -0.001 95 52136 2.00 2.09
18 Vinyl bromide 106 5.211 5.215 -0.004 98 23725 0.4000 0.4083
19 2-Methylbutane 43 5.265 5.264 0.001 89 23415 0.4000 0.3981
20 Trichlorofluoromethane 101 5.508 5.509 -0.001 99 61570 0.4000 0.4061
21 Acrolein 56 5.557 5.557 0.000 92 5746 0.4000 0.3668
22 Acetonitrile 40 5.632 5.639 -0.007 98 8000 0.4000 0.3817
23 Acetone 58 5.697 5.699 -0.002 97 36067 1.20 1.29
25 Pentane 72 5.751 5.748 0.003 93 4244 0.4000 0.4071
24 Isopropyl alcohol 45 5.832 5.832 0.000 99 77910 1.20 1.15
26 Ethyl ether 31 5.966 5.975 -0.009 93 20718 0.4000 0.3918
27 1,1-Dichloroethene 96 6.279 6.287 -0.008 99 24332 0.4000 0.4091
29 Acrylonitrile 53 6.436 6.448 -0.012 95 13252 0.4000 0.3671
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.473 6.471 0.002 97 52919 0.4000 0.4054
28 2-Methyl-2-propanol 59 6.516 6.518 -0.002 96 37950 0.4000 0.3701
31 Methylene Chloride 84 6.673 6.671 0.002 91 28932 0.4000 0.4501
3/25/2024
9:50:51 AM
Page 433 of 864
Report Date: 07-Mar-2024 08:56:00 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L5.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.684 6.688 -0.004 97 19433 0.4000 0.3422
33 Carbon disulfide 76 6.840 6.841 -0.001 99 70633 0.4000 0.4024
34 trans-1,2-Dichloroethene 96 7.530 7.536 -0.006 97 24924 0.4000 0.4017
35 2-Methylpentane 43 7.541 7.542 -0.001 92 44502 0.4000 0.3956
36 Methyl tert-butyl ether 73 7.714 7.720 -0.006 96 63963 0.4000 0.3915
37 1,1-Dichloroethane 63 7.989 7.990 -0.001 100 43266 0.4000 0.4056
38 Vinyl acetate 43 8.118 8.133 -0.015 99 41772 0.4000 0.3700
40 Hexane 56 8.571 8.578 -0.007 80 17489 0.4000 0.3981
39 2-Butanone (MEK) 72 8.614 8.613 0.001 96 10518 0.4000 0.3722
41 Isopropyl ether 45 8.781 8.787 -0.006 93 68614 0.4000 0.3951
42 cis-1,2-Dichloroethene 96 9.018 9.027 -0.009 93 25658 0.4000 0.3922
43 Ethyl acetate 43 9.245 9.262 -0.017 98 43904 0.4000 0.3657
44 Chloroform 83 9.374 9.382 -0.008 39 54762 0.4000 0.3989
45 Tert-butyl ethyl ether 59 9.493 9.498 -0.005 95 71425 0.4000 0.3873
46 Tetrahydrofuran 42 9.860 9.865 -0.005 89 22353 0.4000 0.3828
47 1,1,1-Trichloroethane 97 10.437 10.438 -0.001 97 53075 0.4000 0.3951
48 1,2-Dichloroethane 62 10.561 10.562 -0.001 98 33630 0.4000 0.3909
50 Cyclohexane 69 11.024 11.024 0.000 93 10800 0.4000 0.3792
51 Benzene 78 11.030 11.035 -0.005 97 74072 0.4000 0.3914
52 Carbon tetrachloride 117 11.046 11.051 -0.005 96 48158 0.4000 0.3238
49 n-Butanol 31 11.095 11.071 0.024 69 5971 0.4000 0.3609
53 2,3-Dimethylpentane 71 11.121 11.128 -0.007 88 16586 0.4000 0.3983
54 Thiophene 84 11.305 11.310 -0.005 94 42227 0.4000 0.3941
55 Isooctane 57 11.758 11.762 -0.004 98 110560 0.4000 0.3893
56 n-Heptane 71 12.124 12.127 -0.003 87 24759 0.4000 0.3939
57 1,2-Dichloropropane 63 12.238 12.245 -0.007 88 27617 0.4000 0.3991
58 Trichloroethene 130 12.270 12.270 0.000 97 35381 0.4000 0.3943
59 Dibromomethane 93 12.367 12.373 -0.006 96 32284 0.4000 0.3927
60 Dichlorobromomethane 83 12.507 12.513 -0.006 99 54288 0.4000 0.3886
61 1,4-Dioxane 88 12.572 12.582 -0.010 90 10122 0.4000 0.3685
62 Methyl methacrylate 41 12.604 12.604 0.000 94 23715 0.4000 0.3285
63 Methylcyclohexane 83 13.052 13.055 -0.003 95 43835 0.4000 0.3893
64 4-Methyl-2-pentanone (MIBK) 43 13.516 13.524 -0.008 95 47855 0.4000 0.3661
65 cis-1,3-Dichloropropene 75 13.548 13.553 -0.005 97 40730 0.4000 0.3787
66 trans-1,3-Dichloropropene 75 14.276 14.281 -0.005 98 35112 0.4000 0.3717
67 Toluene 91 14.395 14.399 -0.004 93 91825 0.4000 0.3909
68 1,1,2-Trichloroethane 83 14.481 14.487 -0.006 97 27442 0.4000 0.3965
69 2-Hexanone 58 14.896 14.903 -0.007 95 23332 0.4000 0.3479
70 n-Octane 85 15.074 15.079 -0.005 86 27592 0.4000 0.3883
71 Chlorodibromomethane 129 15.214 15.218 -0.004 97 53545 0.4000 0.3956
72 Ethylene Dibromide 107 15.516 15.521 -0.005 98 49132 0.4000 0.3939
73 Tetrachloroethene 129 15.576 15.578 -0.002 96 34617 0.4000 0.4102
75 2,3-Dimethylheptane 43 16.460 16.459 0.001 89 71462 0.4000 0.3796
74 Chlorobenzene 112 16.476 16.478 -0.002 95 75115 0.4000 0.3980
76 Ethylbenzene 91 16.762 16.763 -0.001 98 115833 0.4000 0.3826
77 m-Xylene & p-Xylene 91 16.924 16.924 0.000 99 184881 0.8000 0.7810
78 n-Nonane 57 17.317 17.317 0.000 84 47910 0.4000 0.3675
80 Styrene 104 17.398 17.404 -0.006 98 63386 0.4000 0.3844
79 Bromoform 173 17.404 17.408 -0.004 93 51300 0.4000 0.4325
81 o-Xylene 91 17.458 17.461 -0.003 98 97596 0.4000 0.3956
82 1,1,2,2-Tetrachloroethane 83 17.786 17.790 -0.004 99 72181 0.4000 0.3922
83 1,2,3-Trichloropropane 110 17.943 17.946 -0.003 97 21130 0.4000 0.3981
3/25/2024
9:50:51 AM
Page 434 of 864
Report Date: 07-Mar-2024 08:56:00 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L5.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.029 18.031 -0.002 96 128446 0.4000 0.3865
85 N-Propylbenzene 120 18.547 18.547 0.000 99 36471 0.4000 0.3912
86 2-Chlorotoluene 126 18.601 18.603 -0.002 97 34193 0.4000 0.4087
88 4-Ethyltoluene 105 18.687 18.690 -0.003 99 133633 0.4000 0.3930
87 1,3,5-Trimethylbenzene 120 18.757 18.758 -0.001 93 55230 0.4000 0.3904
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 88 49995 0.4000 0.3581
90 n-Decane 57 19.005 19.007 -0.002 94 68612 0.4000 0.3833
91 tert-Butylbenzene 119 19.167 19.168 -0.001 93 121490 0.4000 0.3968
92 1,2,4-Trimethylbenzene 105 19.183 19.185 -0.002 96 117611 0.4000 0.4021
93 sec-Butylbenzene 105 19.426 19.427 -0.001 99 165209 0.4000 0.3925
94 1,3-Dichlorobenzene 146 19.458 19.459 -0.001 97 83409 0.4000 0.4080
95 Benzyl chloride 91 19.528 19.530 -0.002 98 85820 0.4000 0.3612
96 1,4-Dichlorobenzene 146 19.539 19.544 -0.005 96 81596 0.4000 0.3983
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 145317 0.4000 0.4070
98 1,2,3-Trimethylbenzene 105 19.641 19.643 -0.002 98 118418 0.4000 0.3988
99 Butylcyclohexane 83 19.679 19.683 -0.004 96 96469 0.4000 0.4108
100 2,3-Dihydroindene 117 19.889 19.889 0.000 94 114728 0.4000 0.4047
101 1,2-Dichlorobenzene 146 19.895 19.896 -0.001 96 81743 0.4000 0.4116
103 n-Butylbenzene 91 20.003 20.003 0.000 98 147118 0.4000 0.4065
102 Indene 116 20.019 20.020 -0.001 89 93904 0.4000 0.4063
104 Undecane 57 20.283 20.283 0.000 92 84451 0.4000 0.4004
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.491 -0.003 96 40808 0.4000 0.4119
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.764 -0.001 97 145893 0.4000 0.4008
107 Dodecane 57 21.378 21.378 0.000 93 114730 0.4000 0.4559
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 79063 0.4000 0.4216
109 Naphthalene 128 21.744 21.744 0.000 99 186320 0.4000 0.4430
110 Hexachlorobutadiene 225 21.890 21.891 -0.001 93 72546 0.4000 0.4284
111 1,2,3-Trichlorobenzene 180 21.949 21.952 -0.003 93 74381 0.4000 0.5029
112 2-Methylnaphthalene 142 22.489 22.489 0.000 98 103875 0.4000 0.4408
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 123079 0.4000 0.4956
A 116 C8 Range 1 15.079 (15.031-15.128) 0 235481 0.4000 0.3718
S 117 Xylenes, Total 100 0 1.20 1.18
S 118 1,2-Dichloroethene, Total 1 0 0.8000 0.7939
QC Flag Legend
Processing Flags
Reagents:
40L5DQP_00053 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 435 of 864
Report Date: 07-Mar-2024 08:56:00 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L5.D
Injection Date:05-Mar-2024 23:11:30 Instrument ID:MR Operator ID:
Lims ID:IC L5 Worklist Smp#:13
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
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9:50:51 AM
Page 436 of 864
Report Date: 07-Mar-2024 08:56:00 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L5.D
Injection Date:05-Mar-2024 23:11:30 Instrument ID:MR
Lims ID:IC L5
Client ID:
Operator ID:ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
0
0
)
RZC05L5[MS SCAN Chro]:Total
3/25/2024
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Page 437 of 864
Report Date: 07-Mar-2024 08:56:25 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L6.D
Lims ID:IC L6
Client ID:
Sample Type:IC Calib Level:6
Inject. Date:05-Mar-2024 23:59:30 ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-014
Misc. Info.:663620 200mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:56:24 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:50:29
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.364 9.372 -0.008 89 205890 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.553 11.559 -0.006 94 960677 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.422 16.428 -0.006 87 865598 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.073 -0.001 91 646045 4.08 4.08
6 Chlorodifluoromethane 51 3.782 3.789 -0.007 97 89988 1.00 1.02
7 Propene 41 3.793 3.796 -0.003 98 41243 1.00 1.05
8 Dichlorodifluoromethane 85 3.847 3.853 -0.006 100 149762 1.00 1.06
9 Chloromethane 52 4.052 4.061 -0.009 98 16519 1.00 1.04
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.063 4.070 -0.007 96 115742 1.00 1.06
12 Vinyl chloride 62 4.246 4.253 -0.007 55 59878 1.00 1.03
11 Acetaldehyde 44 4.246 4.259 -0.013 91 126404 5.00 5.28
13 Butane 43 4.343 4.349 -0.006 91 85864 1.00 1.04
14 Butadiene 54 4.343 4.352 -0.009 93 44292 1.00 1.05
15 Bromomethane 94 4.705 4.715 -0.010 99 61925 1.00 1.07
16 Chloroethane 64 4.866 4.877 -0.011 98 32398 1.00 1.06
17 Ethanol 31 5.023 5.042 -0.019 95 131022 5.00 5.21
18 Vinyl bromide 106 5.201 5.213 -0.012 98 59773 1.00 1.02
19 2-Methylbutane 43 5.255 5.263 -0.008 89 60804 1.00 1.02
20 Trichlorofluoromethane 101 5.497 5.507 -0.010 99 157732 1.00 1.03
21 Acrolein 56 5.540 5.555 -0.015 94 15016 1.00 0.9500
22 Acetonitrile 40 5.616 5.636 -0.020 100 22316 1.00 1.06
23 Acetone 58 5.670 5.696 -0.026 98 87049 3.00 3.09
25 Pentane 72 5.734 5.747 -0.013 96 11480 1.00 1.09
24 Isopropyl alcohol 45 5.799 5.829 -0.030 99 204549 3.00 2.99
26 Ethyl ether 31 5.950 5.972 -0.022 91 54234 1.00 1.02
27 1,1-Dichloroethene 96 6.274 6.285 -0.011 99 60793 1.00 1.01
29 Acrylonitrile 53 6.414 6.445 -0.031 92 38144 1.00 1.05
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.462 6.470 -0.008 96 137614 1.00 1.04
28 2-Methyl-2-propanol 59 6.484 6.514 -0.030 95 103747 1.00 1.00
31 Methylene Chloride 84 6.662 6.670 -0.008 91 64666 1.00 1.00
3/25/2024
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Page 438 of 864
Report Date: 07-Mar-2024 08:56:25 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L6.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.673 6.686 -0.013 97 47832 1.00 0.8349
33 Carbon disulfide 76 6.829 6.839 -0.010 99 181259 1.00 1.02
34 trans-1,2-Dichloroethene 96 7.525 7.535 -0.010 99 65113 1.00 1.04
35 2-Methylpentane 43 7.536 7.541 -0.005 92 115804 1.00 1.02
36 Methyl tert-butyl ether 73 7.681 7.716 -0.035 96 170579 1.00 1.03
37 1,1-Dichloroethane 63 7.978 7.989 -0.011 100 111633 1.00 1.04
38 Vinyl acetate 43 8.096 8.129 -0.033 99 111923 1.00 0.9826
40 Hexane 56 8.571 8.577 -0.006 91 45977 1.00 1.04
39 2-Butanone (MEK) 72 8.582 8.609 -0.027 97 29419 1.00 1.03
41 Isopropyl ether 45 8.754 8.783 -0.029 94 181738 1.00 1.04
42 cis-1,2-Dichloroethene 96 9.018 9.026 -0.008 93 67958 1.00 1.03
43 Ethyl acetate 43 9.218 9.258 -0.040 99 124168 1.00 1.03
44 Chloroform 83 9.374 9.381 -0.007 97 142037 1.00 1.03
45 Tert-butyl ethyl ether 59 9.466 9.494 -0.028 95 192219 1.00 1.03
46 Tetrahydrofuran 42 9.822 9.860 -0.038 88 59469 1.00 1.01
47 1,1,1-Trichloroethane 97 10.426 10.437 -0.011 96 138025 1.00 1.02
48 1,2-Dichloroethane 62 10.550 10.561 -0.011 97 88474 1.00 1.02
50 Cyclohexane 69 11.014 11.023 -0.009 97 28790 1.00 1.00
51 Benzene 78 11.024 11.033 -0.009 97 195158 1.00 1.02
52 Carbon tetrachloride 117 11.041 11.050 -0.009 96 101197 1.00 0.6765
49 n-Butanol 31 11.051 11.068 -0.017 71 19818 1.00 0.9421
53 2,3-Dimethylpentane 71 11.116 11.126 -0.010 89 43297 1.00 1.03
54 Thiophene 84 11.299 11.309 -0.010 94 111657 1.00 1.03
55 Isooctane 57 11.752 11.761 -0.009 98 286572 1.00 1.00
56 n-Heptane 71 12.119 12.126 -0.007 89 66150 1.00 1.04
57 1,2-Dichloropropane 63 12.232 12.244 -0.012 88 71323 1.00 1.02
58 Trichloroethene 130 12.265 12.269 -0.004 97 93838 1.00 1.04
59 Dibromomethane 93 12.362 12.372 -0.010 97 82480 1.00 0.99
60 Dichlorobromomethane 83 12.502 12.512 -0.010 99 142808 1.00 1.01
61 1,4-Dioxane 88 12.545 12.578 -0.033 87 28409 1.00 1.03
62 Methyl methacrylate 41 12.588 12.603 -0.015 95 73087 1.00 1.00
63 Methylcyclohexane 83 13.047 13.054 -0.007 95 116263 1.00 1.02
64 4-Methyl-2-pentanone (MIBK) 43 13.494 13.521 -0.027 96 130021 1.00 0.9863
65 cis-1,3-Dichloropropene 75 13.543 13.552 -0.009 93 110310 1.00 1.02
66 trans-1,3-Dichloropropene 75 14.265 14.280 -0.015 98 96409 1.00 1.01
67 Toluene 91 14.389 14.398 -0.009 93 241531 1.00 1.02
68 1,1,2-Trichloroethane 83 14.476 14.486 -0.010 97 73260 1.00 1.05
69 2-Hexanone 58 14.880 14.900 -0.020 95 68334 1.00 1.01
70 n-Octane 85 15.074 15.078 -0.004 87 74324 1.00 1.04
71 Chlorodibromomethane 129 15.209 15.217 -0.008 98 146050 1.00 1.07
72 Ethylene Dibromide 107 15.511 15.520 -0.009 97 131914 1.00 1.05
73 Tetrachloroethene 129 15.570 15.577 -0.007 96 87686 1.00 1.03
75 2,3-Dimethylheptane 43 16.455 16.459 -0.005 90 187783 1.00 0.9874
74 Chlorobenzene 112 16.476 16.478 -0.002 94 194275 1.00 1.02
76 Ethylbenzene 91 16.756 16.763 -0.007 98 311978 1.00 1.02
77 m-Xylene & p-Xylene 91 16.918 16.923 -0.005 98 487559 2.00 2.04
78 n-Nonane 57 17.312 17.316 -0.004 85 132388 1.00 1.01
80 Styrene 104 17.398 17.404 -0.006 99 173987 1.00 1.04
79 Bromoform 173 17.404 17.407 -0.003 96 138487 1.00 1.16
81 o-Xylene 91 17.457 17.461 -0.004 98 257210 1.00 1.03
82 1,1,2,2-Tetrachloroethane 83 17.786 17.789 -0.003 99 193562 1.00 1.04
83 1,2,3-Trichloropropane 110 17.943 17.946 -0.003 97 56074 1.00 1.05
3/25/2024
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Page 439 of 864
Report Date: 07-Mar-2024 08:56:25 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L6.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.029 18.031 -0.002 94 345693 1.00 1.03
85 N-Propylbenzene 120 18.547 18.547 0.000 99 97499 1.00 1.04
86 2-Chlorotoluene 126 18.595 18.603 -0.008 97 89112 1.00 1.05
88 4-Ethyltoluene 105 18.687 18.689 -0.002 99 360252 1.00 1.05
87 1,3,5-Trimethylbenzene 120 18.757 18.758 -0.001 93 147986 1.00 1.04
89 Alpha Methyl Styrene 118 18.978 18.984 -0.006 88 143997 1.00 1.02
90 n-Decane 57 19.005 19.007 -0.002 93 184073 1.00 1.02
91 tert-Butylbenzene 119 19.167 19.168 -0.001 92 326056 1.00 1.05
92 1,2,4-Trimethylbenzene 105 19.178 19.184 -0.006 96 316106 1.00 1.07
93 sec-Butylbenzene 105 19.426 19.427 -0.001 99 452452 1.00 1.06
94 1,3-Dichlorobenzene 146 19.453 19.458 -0.005 97 217064 1.00 1.05
95 Benzyl chloride 91 19.528 19.530 -0.002 98 245455 1.00 1.02
96 1,4-Dichlorobenzene 146 19.539 19.543 -0.004 95 219305 1.00 1.06
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 393232 1.00 1.09
98 1,2,3-Trimethylbenzene 105 19.641 19.643 -0.002 98 319114 1.00 1.06
99 Butylcyclohexane 83 19.679 19.683 -0.004 96 256918 1.00 1.08
100 2,3-Dihydroindene 117 19.884 19.888 -0.004 94 309127 1.00 1.08
101 1,2-Dichlorobenzene 146 19.889 19.895 -0.006 96 216710 1.00 1.08
103 n-Butylbenzene 91 20.003 20.003 0.000 98 392927 1.00 1.07
102 Indene 116 20.013 20.019 -0.006 89 261710 1.00 1.12
104 Undecane 57 20.278 20.283 -0.005 92 230702 1.00 1.08
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.490 -0.002 96 112786 1.00 1.13
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.764 -0.001 97 394877 1.00 1.07
107 Dodecane 57 21.378 21.378 0.000 93 309404 1.00 1.22
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 211384 1.00 1.12
109 Naphthalene 128 21.744 21.744 0.000 99 498878 1.00 1.17
110 Hexachlorobutadiene 225 21.890 21.891 -0.001 93 181894 1.00 1.13
111 1,2,3-Trichlorobenzene 180 21.949 21.952 -0.003 94 193654 1.00 1.30
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 310076 1.00 1.30
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 338783 1.00 1.35
A 116 C8 Range 1 15.079 (15.026-15.133) 0 628036 1.00 0.9832
S 117 Xylenes, Total 100 0 3.00 3.07
S 118 1,2-Dichloroethene, Total 1 0 2.00 2.07
QC Flag Legend
Processing Flags
Reagents:
40L6DQP_00050 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Page 440 of 864
Report Date: 07-Mar-2024 08:56:25 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L6.D
Injection Date:05-Mar-2024 23:59:30 Instrument ID:MR Operator ID:
Lims ID:IC L6 Worklist Smp#:14
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:8
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
Y ( X10
0
0
0
0
)
RZC05L6[MS SCAN Chro]:Total
* C
h
l
o
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3/25/2024
9:50:51 AM
Page 441 of 864
Report Date: 07-Mar-2024 08:56:25 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05L6.D
Injection Date:05-Mar-2024 23:59:30 Instrument ID:MR
Lims ID:IC L6
Client ID:
Operator ID:ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
Y ( X10
0
0
0
)
RZC05L6[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 442 of 864
Report Date: 07-Mar-2024 08:56:50 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Lims ID:ICIS L7
Client ID:
Sample Type:ICIS Calib Level:7
Inject. Date:06-Mar-2024 00:47:30 ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-015
Misc. Info.:663024 200mL
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub16
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:07-Mar-2024 08:56:49 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: RT Order ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1640
First Level Reviewer: U3SA Date:06-Mar-2024 07:47:37
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.372 0.002 96 213322 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.564 11.560 0.004 94 995985 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.428 16.428 0.000 86 895394 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.073 -0.001 90 678199 4.08 4.14
6 Chlorodifluoromethane 51 3.783 3.788 -0.005 97 183918 2.00 2.02
7 Propene 41 3.793 3.796 -0.003 97 83868 2.00 2.05
8 Dichlorodifluoromethane 85 3.847 3.853 -0.006 100 306604 2.00 2.09
9 Chloromethane 52 4.058 4.061 -0.003 98 33206 2.00 2.01
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.068 4.070 -0.002 98 230795 2.00 2.03
11 Acetaldehyde 44 4.246 4.258 -0.012 92 268964 10.0 10.8
12 Vinyl chloride 62 4.246 4.252 -0.006 99 120678 2.00 2.01
13 Butane 43 4.343 4.349 -0.006 94 173118 2.00 2.02
14 Butadiene 54 4.349 4.352 -0.003 96 89503 2.00 2.04
15 Bromomethane 94 4.710 4.714 -0.004 98 119297 2.00 1.98
16 Chloroethane 64 4.872 4.876 -0.004 97 63380 2.00 2.01
17 Ethanol 31 5.017 5.040 -0.023 95 270040 10.0 10.4
18 Vinyl bromide 106 5.206 5.213 -0.007 98 121147 2.00 1.99
19 2-Methylbutane 43 5.260 5.263 -0.003 89 119693 2.00 1.95
20 Trichlorofluoromethane 101 5.503 5.507 -0.004 99 316243 2.00 2.00
21 Acrolein 56 5.541 5.554 -0.014 93 30677 2.00 1.87
22 Acetonitrile 40 5.616 5.634 -0.018 98 46451 2.00 2.12
23 Acetone 58 5.670 5.694 -0.024 98 197820 6.00 6.78
25 Pentane 72 5.745 5.747 -0.002 95 22915 2.00 2.10
24 Isopropyl alcohol 45 5.783 5.824 -0.041 94 451994 6.00 6.38
26 Ethyl ether 31 5.950 5.970 -0.020 94 113307 2.00 2.05
27 1,1-Dichloroethene 96 6.279 6.285 -0.006 99 124401 2.00 2.00
29 Acrylonitrile 53 6.425 6.443 -0.018 95 78143 2.00 2.07
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.468 6.470 -0.002 97 273288 2.00 2.00
28 2-Methyl-2-propanol 59 6.463 6.509 -0.046 96 231690 2.00 2.16
31 Methylene Chloride 84 6.668 6.670 -0.002 91 123355 2.00 1.84
3/25/2024
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Page 443 of 864
Report Date: 07-Mar-2024 08:56:50 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.684 6.686 -0.002 96 111140 2.00 1.87
33 Carbon disulfide 76 6.835 6.839 -0.004 99 357362 2.00 1.95
34 trans-1,2-Dichloroethene 96 7.530 7.535 -0.004 98 131112 2.00 2.02
35 2-Methylpentane 43 7.541 7.541 0.000 92 238200 2.00 2.03
36 Methyl tert-butyl ether 73 7.681 7.712 -0.031 96 346597 2.00 2.03
37 1,1-Dichloroethane 63 7.989 7.989 0.000 100 223705 2.00 2.01
38 Vinyl acetate 43 8.102 8.126 -0.024 99 227526 2.00 1.93
40 Hexane 56 8.576 8.577 -0.001 77 93613 2.00 2.04
39 2-Butanone (MEK) 72 8.582 8.605 -0.023 98 65946 2.00 2.23
41 Isopropyl ether 45 8.754 8.780 -0.026 94 374324 2.00 2.06
42 cis-1,2-Dichloroethene 96 9.024 9.025 -0.001 93 137404 2.00 2.01
43 Ethyl acetate 43 9.218 9.254 -0.036 99 252920 2.00 2.02
44 Chloroform 83 9.385 9.381 0.004 95 282571 2.00 1.97
45 Tert-butyl ethyl ether 59 9.461 9.491 -0.030 95 392055 2.00 2.03
46 Tetrahydrofuran 42 9.817 9.856 -0.039 89 124753 2.00 2.04
47 1,1,1-Trichloroethane 97 10.437 10.437 0.000 96 280276 2.00 2.00
48 1,2-Dichloroethane 62 10.555 10.560 -0.005 98 181239 2.00 2.01
50 Cyclohexane 69 11.025 11.023 0.002 97 60432 2.00 2.03
51 Benzene 78 11.035 11.034 0.001 96 396945 2.00 2.01
52 Carbon tetrachloride 117 11.052 11.050 0.002 97 286721 2.00 1.87
49 n-Butanol 31 11.030 11.064 -0.034 68 47044 2.00 2.02
53 2,3-Dimethylpentane 71 11.127 11.126 0.001 89 88747 2.00 2.04
54 Thiophene 84 11.305 11.309 -0.004 94 226682 2.00 2.02
55 Isooctane 57 11.758 11.760 -0.002 98 584496 2.00 1.97
56 n-Heptane 71 12.125 12.126 -0.001 88 136908 2.00 2.08
57 1,2-Dichloropropane 63 12.238 12.243 -0.005 88 143855 2.00 1.99
58 Trichloroethene 130 12.270 12.270 0.000 97 188637 2.00 2.01
59 Dibromomethane 93 12.367 12.371 -0.004 97 166311 2.00 1.93
60 Dichlorobromomethane 83 12.507 12.512 -0.005 99 295147 2.00 2.02
61 1,4-Dioxane 88 12.540 12.574 -0.034 88 61917 2.00 2.16
62 Methyl methacrylate 41 12.588 12.601 -0.013 96 148511 2.00 1.97
63 Methylcyclohexane 83 13.052 13.054 -0.002 95 237648 2.00 2.02
64 4-Methyl-2-pentanone (MIBK) 43 13.489 13.518 -0.029 97 275569 2.00 2.02
65 cis-1,3-Dichloropropene 75 13.543 13.551 -0.008 94 230442 2.00 2.05
66 trans-1,3-Dichloropropene 75 14.271 14.279 -0.008 98 207949 2.00 2.11
67 Toluene 91 14.395 14.398 -0.003 93 497509 2.00 2.03
68 1,1,2-Trichloroethane 83 14.481 14.485 -0.004 97 146088 2.00 2.02
69 2-Hexanone 58 14.875 14.897 -0.022 95 148627 2.00 2.12
70 n-Octane 85 15.074 15.078 -0.004 88 153800 2.00 2.07
71 Chlorodibromomethane 129 15.214 15.217 -0.003 98 306552 2.00 2.17
72 Ethylene Dibromide 107 15.516 15.520 -0.004 98 271197 2.00 2.08
73 Tetrachloroethene 129 15.576 15.577 -0.001 96 177938 2.00 2.02
75 2,3-Dimethylheptane 43 16.460 16.459 0.001 93 376026 2.00 1.91
74 Chlorobenzene 112 16.476 16.478 -0.002 94 390774 2.00 1.98
76 Ethylbenzene 91 16.762 16.762 0.000 98 639329 2.00 2.02
77 m-Xylene & p-Xylene 91 16.924 16.923 0.001 98 1006981 4.00 4.07
78 n-Nonane 57 17.317 17.316 0.001 85 275133 2.00 2.02
80 Styrene 104 17.398 17.403 -0.005 98 362190 2.00 2.10
79 Bromoform 173 17.404 17.407 -0.003 96 298962 2.00 2.41
81 o-Xylene 91 17.458 17.460 -0.002 98 526663 2.00 2.04
82 1,1,2,2-Tetrachloroethane 83 17.787 17.789 -0.002 99 392760 2.00 2.04
83 1,2,3-Trichloropropane 110 17.943 17.946 -0.003 97 113214 2.00 2.04
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Report Date: 07-Mar-2024 08:56:50 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.035 18.031 0.004 96 714828 2.00 2.06
85 N-Propylbenzene 120 18.547 18.547 0.000 99 202171 2.00 2.08
86 2-Chlorotoluene 126 18.601 18.602 -0.001 98 182376 2.00 2.09
88 4-Ethyltoluene 105 18.687 18.689 -0.002 99 742604 2.00 2.09
87 1,3,5-Trimethylbenzene 120 18.757 18.758 -0.001 92 301523 2.00 2.04
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 88 292476 2.00 2.00
90 n-Decane 57 19.005 19.007 -0.002 94 373410 2.00 2.00
91 tert-Butylbenzene 119 19.167 19.168 -0.001 93 675129 2.00 2.11
92 1,2,4-Trimethylbenzene 105 19.183 19.184 -0.001 96 642130 2.00 2.10
93 sec-Butylbenzene 105 19.426 19.427 -0.001 99 929757 2.00 2.11
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 98 436880 2.00 2.05
95 Benzyl chloride 91 19.528 19.530 -0.002 98 525603 2.00 2.12
96 1,4-Dichlorobenzene 146 19.539 19.543 -0.004 95 436795 2.00 2.04
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 787879 2.00 2.11
98 1,2,3-Trimethylbenzene 105 19.642 19.643 -0.001 98 650074 2.00 2.10
99 Butylcyclohexane 83 19.685 19.683 0.002 95 508786 2.00 2.07
100 2,3-Dihydroindene 117 19.890 19.888 0.002 94 624853 2.00 2.11
101 1,2-Dichlorobenzene 146 19.895 19.895 0.000 95 428020 2.00 2.06
103 n-Butylbenzene 91 20.003 20.003 0.000 98 787730 2.00 2.08
102 Indene 116 20.019 20.019 0.000 90 525063 2.00 2.17
104 Undecane 57 20.283 20.283 0.000 93 446705 2.00 2.03
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.490 -0.002 97 246902 2.00 2.38
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.764 -0.001 97 762363 2.00 2.00
107 Dodecane 57 21.378 21.378 0.000 94 481067 2.00 1.83
108 1,2,4-Trichlorobenzene 180 21.621 21.620 0.001 94 369308 2.00 1.88
109 Naphthalene 128 21.745 21.744 0.001 99 871593 2.00 1.98
110 Hexachlorobutadiene 225 21.890 21.891 -0.001 96 289470 2.00 1.86
111 1,2,3-Trichlorobenzene 180 21.949 21.952 -0.003 95 318309 2.00 2.06
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 518202 2.00 2.10
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 532472 2.00 2.05
A 116 C8 Range 1 15.079 (15.020-15.128) 0 1281480 2.00 1.94
S 117 Xylenes, Total 100 0 6.00 6.11
S 118 1,2-Dichloroethene, Total 1 0 4.00 4.03
QC Flag Legend
Processing Flags
Reagents:
40L7DQP_00050 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Page 445 of 864
Report Date: 07-Mar-2024 08:56:50 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Injection Date:06-Mar-2024 00:47:30 Instrument ID:MR Operator ID:
Lims ID:ICIS L7 Worklist Smp#:15
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:9
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
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Y ( X10
0
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0
0
)
RZC05ICIS7[MS SCAN Chro]:Total
* C
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3/25/2024
9:50:51 AM
Page 446 of 864
Report Date: 07-Mar-2024 08:56:51 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Injection Date:06-Mar-2024 00:47:30 Instrument ID:MR
Lims ID:ICIS L7
Client ID:
Operator ID:ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 116 C8 Range, CAS: STL00834
15.0
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
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Y ( X10
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RZC05ICIS7[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 447 of 864
Calibration / Chlorodifluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.639
Error Coefficients
Relative Standard Deviation:4.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.03775 3.84 234059.0 1.887524 N
2 IC 140-84237/10 0.04 0.071207 3.84 217758.0 1.780178 N
3 IC 140-84237/11 0.08 0.133533 3.84 208085.0 1.669164 Y
4 IC 140-84237/12 0.16 0.278779 3.84 210527.0 1.74237 Y
5 IC 140-84237/13 0.4 0.662299 3.84 204066.0 1.655747 Y
6 IC 140-84237/14 1.0 1.678342 3.84 205890.0 1.678342 Y
7 ICIS 140-84237/15 2.0 3.3107 3.84 213322.0 1.65535 Y
8 IC 140-84237/7 4.0 6.259192 3.84 238596.0 1.564798 Y
9 IC 140-84237/5 8.0 13.204777 3.84 221929.0 1.650597 Y
10 IC 140-84237/3 16.0 23.875616 3.84 207901.0 1.492226 Y
RelResp = [1.639]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 448 of 864
Calibration / Propene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7355
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.018145 3.84 234059.0 0.907258 N
2 IC 140-84237/10 0.04 0.035233 3.84 217758.0 0.880831 N
3 IC 140-84237/11 0.08 0.065715 3.84 208085.0 0.821434 N
4 IC 140-84237/12 0.16 0.118268 3.84 210527.0 0.739174 Y
5 IC 140-84237/13 0.4 0.293044 3.84 204066.0 0.73261 Y
6 IC 140-84237/14 1.0 0.769212 3.84 205890.0 0.769212 Y
7 ICIS 140-84237/15 2.0 1.509704 3.84 213322.0 0.754852 Y
8 IC 140-84237/7 4.0 2.897414 3.84 238596.0 0.724353 Y
9 IC 140-84237/5 8.0 6.006003 3.84 221929.0 0.75075 Y
10 IC 140-84237/3 16.0 10.835933 3.84 207901.0 0.677246 Y
RelResp = [0.7355]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
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Calibration / Dichlorodifluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.642
Error Coefficients
Relative Standard Deviation:8.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.064574 3.84 234059.0 3.228724 N
2 IC 140-84237/10 0.04 0.113653 3.84 217758.0 2.841319 N
3 IC 140-84237/11 0.08 0.204249 3.84 208085.0 2.553111 Y
4 IC 140-84237/12 0.16 0.481334 3.84 210527.0 3.008336 Y
5 IC 140-84237/13 0.4 1.031271 3.84 204066.0 2.578178 Y
6 IC 140-84237/14 1.0 2.793171 3.84 205890.0 2.793171 Y
7 ICIS 140-84237/15 2.0 5.519165 3.84 213322.0 2.759583 Y
8 IC 140-84237/7 4.0 9.863912 3.84 238596.0 2.465978 Y
9 IC 140-84237/5 8.0 21.227771 3.84 221929.0 2.653471 Y
10 IC 140-84237/3 16.0 37.157612 3.84 207901.0 2.322351 Y
RelResp = [2.642]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 450 of 864
Calibration / Chloromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2971
Error Coefficients
Relative Standard Deviation:9.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.009466 3.84 234059.0 0.473317 N
2 IC 140-84237/10 0.04 0.018216 3.84 217758.0 0.455405 N
3 IC 140-84237/11 0.08 0.028604 3.84 208085.0 0.357546 N
4 IC 140-84237/12 0.16 0.054902 3.84 210527.0 0.343139 Y
5 IC 140-84237/13 0.4 0.125042 3.84 204066.0 0.312605 Y
6 IC 140-84237/14 1.0 0.308092 3.84 205890.0 0.308092 Y
7 ICIS 140-84237/15 2.0 0.59774 3.84 213322.0 0.29887 Y
8 IC 140-84237/7 4.0 1.073094 3.84 238596.0 0.268273 Y
9 IC 140-84237/5 8.0 2.273938 3.84 221929.0 0.284242 Y
10 IC 140-84237/3 16.0 4.236558 3.84 207901.0 0.264785 Y
RelResp = [0.2971]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
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Calibration / 1,2-Dichloro-1,1,2,2-tetrafluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.044
Error Coefficients
Relative Standard Deviation:6.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.046331 3.84 234059.0 2.316544 N
2 IC 140-84237/10 0.04 0.087219 3.84 217758.0 2.180476 Y
3 IC 140-84237/11 0.08 0.166012 3.84 208085.0 2.075152 Y
4 IC 140-84237/12 0.16 0.344589 3.84 210527.0 2.153681 Y
5 IC 140-84237/13 0.4 0.821532 3.84 204066.0 2.05383 Y
6 IC 140-84237/14 1.0 2.158673 3.84 205890.0 2.158673 Y
7 ICIS 140-84237/15 2.0 4.154531 3.84 213322.0 2.077265 Y
8 IC 140-84237/7 4.0 7.587555 3.84 238596.0 1.896889 Y
9 IC 140-84237/5 8.0 15.768606 3.84 221929.0 1.971076 Y
10 IC 140-84237/3 16.0 29.200649 3.84 207901.0 1.825041 Y
RelResp = [2.044]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Vinyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.083
Error Coefficients
Relative Standard Deviation:6.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.024297 3.84 234059.0 1.214873 N
2 IC 140-84237/10 0.04 0.045073 3.84 217758.0 1.126829 Y
3 IC 140-84237/11 0.08 0.089096 3.84 208085.0 1.113699 Y
4 IC 140-84237/12 0.16 0.191519 3.84 210527.0 1.196996 Y
5 IC 140-84237/13 0.4 0.431522 3.84 204066.0 1.078804 Y
6 IC 140-84237/14 1.0 1.116769 3.84 205890.0 1.116769 Y
7 ICIS 140-84237/15 2.0 2.172319 3.84 213322.0 1.08616 Y
8 IC 140-84237/7 4.0 3.958662 3.84 238596.0 0.989666 Y
9 IC 140-84237/5 8.0 8.224312 3.84 221929.0 1.028039 Y
10 IC 140-84237/3 16.0 16.115547 3.84 207901.0 1.007222 Y
RelResp = [1.083]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Butadiene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7886
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.016997 3.84 234059.0 0.849837 Y
2 IC 140-84237/10 0.04 0.029661 3.84 217758.0 0.74152 Y
3 IC 140-84237/11 0.08 0.061507 3.84 208085.0 0.76884 Y
4 IC 140-84237/12 0.16 0.136307 3.84 210527.0 0.851919 Y
5 IC 140-84237/13 0.4 0.314797 3.84 204066.0 0.786992 Y
6 IC 140-84237/14 1.0 0.826078 3.84 205890.0 0.826078 Y
7 ICIS 140-84237/15 2.0 1.61114 3.84 213322.0 0.80557 Y
8 IC 140-84237/7 4.0 2.913331 3.84 238596.0 0.728333 Y
9 IC 140-84237/5 8.0 6.147125 3.84 221929.0 0.768391 Y
10 IC 140-84237/3 16.0 12.142044 3.84 207901.0 0.758878 Y
RelResp = [0.7886]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Butane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.54
Error Coefficients
Relative Standard Deviation:7.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.03862 3.84 234059.0 1.931 N
2 IC 140-84237/10 0.04 0.071242 3.84 217758.0 1.78106 N
3 IC 140-84237/11 0.08 0.142779 3.84 208085.0 1.784732 N
4 IC 140-84237/12 0.16 0.276955 3.84 210527.0 1.73097 Y
5 IC 140-84237/13 0.4 0.627072 3.84 204066.0 1.567681 Y
6 IC 140-84237/14 1.0 1.601427 3.84 205890.0 1.601427 Y
7 ICIS 140-84237/15 2.0 3.11629 3.84 213322.0 1.558145 Y
8 IC 140-84237/7 4.0 5.594568 3.84 238596.0 1.398642 Y
9 IC 140-84237/5 8.0 11.852682 3.84 221929.0 1.481585 Y
10 IC 140-84237/3 16.0 23.091791 3.84 207901.0 1.443237 Y
RelResp = [1.54]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 455 of 864
Calibration / Bromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.084
Error Coefficients
Relative Standard Deviation:7.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.027021 3.84 234059.0 1.351044 N
2 IC 140-84237/10 0.04 0.050646 3.84 217758.0 1.266139 N
3 IC 140-84237/11 0.08 0.089244 3.84 208085.0 1.115544 Y
4 IC 140-84237/12 0.16 0.191902 3.84 210527.0 1.19939 Y
5 IC 140-84237/13 0.4 0.457697 3.84 204066.0 1.144242 Y
6 IC 140-84237/14 1.0 1.154947 3.84 205890.0 1.154947 Y
7 ICIS 140-84237/15 2.0 2.14746 3.84 213322.0 1.07373 Y
8 IC 140-84237/7 4.0 3.892708 3.84 238596.0 0.973177 Y
9 IC 140-84237/5 8.0 8.14837 3.84 221929.0 1.018546 Y
10 IC 140-84237/3 16.0 15.870871 3.84 207901.0 0.991929 Y
RelResp = [1.084]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
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Calibration / Chloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5689
Error Coefficients
Relative Standard Deviation:8.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.010418 3.84 234059.0 0.520894 Y
2 IC 140-84237/10 0.04 0.023295 3.84 217758.0 0.582371 Y
3 IC 140-84237/11 0.08 0.048368 3.84 208085.0 0.604599 Y
4 IC 140-84237/12 0.16 0.101852 3.84 210527.0 0.636574 Y
5 IC 140-84237/13 0.4 0.24043 3.84 204066.0 0.601076 Y
6 IC 140-84237/14 1.0 0.604247 3.84 205890.0 0.604247 Y
7 ICIS 140-84237/15 2.0 1.140901 3.84 213322.0 0.57045 Y
8 IC 140-84237/7 4.0 1.974269 3.84 238596.0 0.493567 Y
9 IC 140-84237/5 8.0 4.209346 3.84 221929.0 0.526168 Y
10 IC 140-84237/3 16.0 8.790732 3.84 207901.0 0.549421 Y
RelResp = [0.5689]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 457 of 864
Calibration / Ethanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4687
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.1 0.083294 3.84 234059.0 0.832939 N
2 IC 140-84237/10 0.2 0.153647 3.84 217758.0 0.768236 N
3 IC 140-84237/11 0.4 0.286794 3.84 208085.0 0.716984 N
4 IC 140-84237/12 0.8 0.409779 3.84 210527.0 0.512223 Y
5 IC 140-84237/13 2.0 0.981066 3.84 204066.0 0.490533 Y
6 IC 140-84237/14 5.0 2.443657 3.84 205890.0 0.488731 Y
7 ICIS 140-84237/15 10.0 4.860978 3.84 213322.0 0.486098 Y
8 IC 140-84237/7 20.0 7.922877 3.84 238596.0 0.396144 Y
9 IC 140-84237/5 40.0 17.405091 3.84 221929.0 0.435127 Y
10 IC 140-84237/3 80.0 37.741644 3.84 207901.0 0.471771 Y
RelResp = [0.4687]x
Concentration
0 10 20 30 40 50 60 70 80
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 458 of 864
Calibration / Vinyl bromide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.094
Error Coefficients
Relative Standard Deviation:5.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.023297 3.84 234059.0 1.164835 Y
2 IC 140-84237/10 0.04 0.041405 3.84 217758.0 1.035131 Y
3 IC 140-84237/11 0.08 0.091034 3.84 208085.0 1.13792 Y
4 IC 140-84237/12 0.16 0.186704 3.84 210527.0 1.1669 Y
5 IC 140-84237/13 0.4 0.446444 3.84 204066.0 1.116109 Y
6 IC 140-84237/14 1.0 1.11481 3.84 205890.0 1.11481 Y
7 ICIS 140-84237/15 2.0 2.180762 3.84 213322.0 1.090381 Y
8 IC 140-84237/7 4.0 4.097265 3.84 238596.0 1.024316 Y
9 IC 140-84237/5 8.0 8.666746 3.84 221929.0 1.083343 Y
10 IC 140-84237/3 16.0 16.02628 3.84 207901.0 1.001643 Y
RelResp = [1.094]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 459 of 864
Calibration / 2-Methylbutane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.107
Error Coefficients
Relative Standard Deviation:4.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.030319 3.84 234059.0 1.515925 N
2 IC 140-84237/10 0.04 0.049746 3.84 217758.0 1.243656 N
3 IC 140-84237/11 0.08 0.099762 3.84 208085.0 1.247029 N
4 IC 140-84237/12 0.16 0.185081 3.84 210527.0 1.156754 Y
5 IC 140-84237/13 0.4 0.44061 3.84 204066.0 1.101526 Y
6 IC 140-84237/14 1.0 1.134039 3.84 205890.0 1.134039 Y
7 ICIS 140-84237/15 2.0 2.154588 3.84 213322.0 1.077294 Y
8 IC 140-84237/7 4.0 4.465902 3.84 238596.0 1.116475 Y
9 IC 140-84237/5 8.0 9.242584 3.84 221929.0 1.155323 Y
10 IC 140-84237/3 16.0 16.087066 3.84 207901.0 1.005442 Y
RelResp = [1.107]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 460 of 864
Calibration / Trichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.853
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.064279 3.84 234059.0 3.213959 N
2 IC 140-84237/10 0.04 0.116527 3.84 217758.0 2.913179 Y
3 IC 140-84237/11 0.08 0.226061 3.84 208085.0 2.825768 Y
4 IC 140-84237/12 0.16 0.47858 3.84 210527.0 2.991122 Y
5 IC 140-84237/13 0.4 1.15859 3.84 204066.0 2.896475 Y
6 IC 140-84237/14 1.0 2.941818 3.84 205890.0 2.941818 Y
7 ICIS 140-84237/15 2.0 5.692676 3.84 213322.0 2.846338 Y
8 IC 140-84237/7 4.0 10.910257 3.84 238596.0 2.727564 Y
9 IC 140-84237/5 8.0 22.943571 3.84 221929.0 2.867946 Y
10 IC 140-84237/3 16.0 42.693834 3.84 207901.0 2.668365 Y
RelResp = [2.853]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Acrolein
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2948
Error Coefficients
Relative Standard Deviation:7.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.0 3.84 234059.0 0.0 N
2 IC 140-84237/10 0.04 0.005802 3.84 217758.0 0.145042 N
3 IC 140-84237/11 0.08 0.017218 3.84 208085.0 0.21522 N
4 IC 140-84237/12 0.16 0.045089 3.84 210527.0 0.281807 N
5 IC 140-84237/13 0.4 0.108125 3.84 204066.0 0.270313 Y
6 IC 140-84237/14 1.0 0.280059 3.84 205890.0 0.280059 Y
7 ICIS 140-84237/15 2.0 0.552215 3.84 213322.0 0.276108 Y
8 IC 140-84237/7 4.0 1.260333 3.84 238596.0 0.315083 Y
9 IC 140-84237/5 8.0 2.507907 3.84 221929.0 0.313488 Y
10 IC 140-84237/3 16.0 5.021399 3.84 207901.0 0.313837 Y
RelResp = [0.2948]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7 IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 462 of 864
Calibration / Acetonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3944
Error Coefficients
Relative Standard Deviation:6.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.012583 3.84 234059.0 0.629175 N
2 IC 140-84237/10 0.04 0.024582 3.84 217758.0 0.614554 N
3 IC 140-84237/11 0.08 0.027626 3.84 208085.0 0.34532 N
4 IC 140-84237/12 0.16 0.056909 3.84 210527.0 0.355679 Y
5 IC 140-84237/13 0.4 0.15054 3.84 204066.0 0.376349 Y
6 IC 140-84237/14 1.0 0.41621 3.84 205890.0 0.41621 Y
7 ICIS 140-84237/15 2.0 0.836162 3.84 213322.0 0.418081 Y
8 IC 140-84237/7 4.0 1.575762 3.84 238596.0 0.393941 Y
9 IC 140-84237/5 8.0 3.323407 3.84 221929.0 0.415426 Y
10 IC 140-84237/3 16.0 6.161499 3.84 207901.0 0.385094 Y
RelResp = [0.3944]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Acetone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5253
Error Coefficients
Relative Standard Deviation:11.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.06 0.045084 3.84 234059.0 0.7514 N
2 IC 140-84237/10 0.12 0.083375 3.84 217758.0 0.69479 N
3 IC 140-84237/11 0.24 0.152928 3.84 208085.0 0.637201 N
4 IC 140-84237/12 0.48 0.277867 3.84 210527.0 0.57889 Y
5 IC 140-84237/13 1.2 0.678689 3.84 204066.0 0.565574 Y
6 IC 140-84237/14 3.0 1.623528 3.84 205890.0 0.541176 Y
7 ICIS 140-84237/15 6.0 3.560949 3.84 213322.0 0.593492 Y
8 IC 140-84237/7 12.0 5.54569 3.84 238596.0 0.462141 Y
9 IC 140-84237/5 24.0 11.608158 3.84 221929.0 0.483673 Y
10 IC 140-84237/3 48.0 21.703746 3.84 207901.0 0.452161 Y
RelResp = [0.5253]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Pentane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1962
Error Coefficients
Relative Standard Deviation:7.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.0 3.84 234059.0 0.0 N
2 IC 140-84237/10 0.04 0.006877 3.84 217758.0 0.171934 Y
3 IC 140-84237/11 0.08 0.013933 3.84 208085.0 0.17416 Y
4 IC 140-84237/12 0.16 0.032649 3.84 210527.0 0.204059 Y
5 IC 140-84237/13 0.4 0.079861 3.84 204066.0 0.199653 Y
6 IC 140-84237/14 1.0 0.21411 3.84 205890.0 0.21411 Y
7 ICIS 140-84237/15 2.0 0.412492 3.84 213322.0 0.206246 Y
8 IC 140-84237/7 4.0 0.763313 3.84 238596.0 0.190828 Y
9 IC 140-84237/5 8.0 1.681524 3.84 221929.0 0.21019 Y
10 IC 140-84237/3 16.0 3.109683 3.84 207901.0 0.194355 Y
RelResp = [0.1962]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Isopropyl alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.275
Error Coefficients
Relative Standard Deviation:4.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.06 0.08021 3.84 234059.0 1.336825 N
2 IC 140-84237/10 0.12 0.152501 3.84 217758.0 1.270842 N
3 IC 140-84237/11 0.24 0.291868 3.84 208085.0 1.216118 N
4 IC 140-84237/12 0.48 0.603505 3.84 210527.0 1.257302 Y
5 IC 140-84237/13 1.2 1.466067 3.84 204066.0 1.221722 Y
6 IC 140-84237/14 3.0 3.814989 3.84 205890.0 1.271663 Y
7 ICIS 140-84237/15 6.0 8.136324 3.84 213322.0 1.356054 Y
8 IC 140-84237/7 12.0 15.110573 3.84 238596.0 1.259214 Y
9 IC 140-84237/5 24.0 32.189979 3.84 221929.0 1.341249 Y
10 IC 140-84237/3 48.0 58.384047 3.84 207901.0 1.216334 Y
RelResp = [1.275]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Ethyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9951
Error Coefficients
Relative Standard Deviation:3.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.020475 3.84 234059.0 1.023742 Y
2 IC 140-84237/10 0.04 0.039695 3.84 217758.0 0.992368 Y
3 IC 140-84237/11 0.08 0.074849 3.84 208085.0 0.935618 Y
4 IC 140-84237/12 0.16 0.158432 3.84 210527.0 0.990201 Y
5 IC 140-84237/13 0.4 0.38986 3.84 204066.0 0.974649 Y
6 IC 140-84237/14 1.0 1.011504 3.84 205890.0 1.011504 Y
7 ICIS 140-84237/15 2.0 2.039634 3.84 213322.0 1.019817 Y
8 IC 140-84237/7 4.0 3.994504 3.84 238596.0 0.998626 Y
9 IC 140-84237/5 8.0 8.415163 3.84 221929.0 1.051895 Y
10 IC 140-84237/3 16.0 15.238742 3.84 207901.0 0.952421 Y
RelResp = [0.9951]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / 1,1-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.119
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.023658 3.84 234059.0 1.182881 Y
2 IC 140-84237/10 0.04 0.042887 3.84 217758.0 1.072163 Y
3 IC 140-84237/11 0.08 0.087287 3.84 208085.0 1.091093 Y
4 IC 140-84237/12 0.16 0.187142 3.84 210527.0 1.169636 Y
5 IC 140-84237/13 0.4 0.457866 3.84 204066.0 1.144665 Y
6 IC 140-84237/14 1.0 1.133834 3.84 205890.0 1.133834 Y
7 ICIS 140-84237/15 2.0 2.239337 3.84 213322.0 1.119668 Y
8 IC 140-84237/7 4.0 4.327041 3.84 238596.0 1.08176 Y
9 IC 140-84237/5 8.0 9.077325 3.84 221929.0 1.134666 Y
10 IC 140-84237/3 16.0 16.978389 3.84 207901.0 1.061149 Y
RelResp = [1.119]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / Acrylonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6794
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.007727 3.84 234059.0 0.386364 N
2 IC 140-84237/10 0.04 0.017105 3.84 217758.0 0.427631 N
3 IC 140-84237/11 0.08 0.038329 3.84 208085.0 0.479112 N
4 IC 140-84237/12 0.16 0.089668 3.84 210527.0 0.560422 Y
5 IC 140-84237/13 0.4 0.249369 3.84 204066.0 0.623422 Y
6 IC 140-84237/14 1.0 0.711414 3.84 205890.0 0.711414 Y
7 ICIS 140-84237/15 2.0 1.406649 3.84 213322.0 0.703324 Y
8 IC 140-84237/7 4.0 2.759954 3.84 238596.0 0.689988 Y
9 IC 140-84237/5 8.0 5.983094 3.84 221929.0 0.747887 Y
10 IC 140-84237/3 16.0 11.504079 3.84 207901.0 0.719005 Y
RelResp = [0.6794]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5 IC 140-84237/3
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Page 469 of 864
Calibration / 2-Methyl-2-propanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.93
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.023461 3.84 234059.0 1.173038 N
2 IC 140-84237/10 0.04 0.059674 3.84 217758.0 1.491858 N
3 IC 140-84237/11 0.08 0.14813 3.84 208085.0 1.851628 Y
4 IC 140-84237/12 0.16 0.29587 3.84 210527.0 1.849188 Y
5 IC 140-84237/13 0.4 0.714122 3.84 204066.0 1.785305 Y
6 IC 140-84237/14 1.0 1.934958 3.84 205890.0 1.934958 Y
7 ICIS 140-84237/15 2.0 4.170642 3.84 213322.0 2.085321 Y
8 IC 140-84237/7 4.0 7.720348 3.84 238596.0 1.930087 Y
9 IC 140-84237/5 8.0 16.686262 3.84 221929.0 2.085783 Y
10 IC 140-84237/3 16.0 30.634852 3.84 207901.0 1.914678 Y
RelResp = [1.93]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 470 of 864
Calibration / 1,1,2-Trichloro-1,2,2-trifluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.456
Error Coefficients
Relative Standard Deviation:3.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.052992 3.84 234059.0 2.649588 N
2 IC 140-84237/10 0.04 0.100021 3.84 217758.0 2.500537 Y
3 IC 140-84237/11 0.08 0.195631 3.84 208085.0 2.445385 Y
4 IC 140-84237/12 0.16 0.411074 3.84 210527.0 2.56921 Y
5 IC 140-84237/13 0.4 0.9958 3.84 204066.0 2.4895 Y
6 IC 140-84237/14 1.0 2.566602 3.84 205890.0 2.566602 Y
7 ICIS 140-84237/15 2.0 4.919445 3.84 213322.0 2.459723 Y
8 IC 140-84237/7 4.0 9.367584 3.84 238596.0 2.341896 Y
9 IC 140-84237/5 8.0 19.672039 3.84 221929.0 2.459005 Y
10 IC 140-84237/3 16.0 36.40827 3.84 207901.0 2.275517 Y
RelResp = [2.456]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
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Page 471 of 864
Calibration / Methylene Chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.21
Error Coefficients
Relative Standard Deviation:22.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.083146 3.84 234059.0 4.157311 N
2 IC 140-84237/10 0.04 0.121288 3.84 217758.0 3.03221 N
3 IC 140-84237/11 0.08 0.181827 3.84 208085.0 2.27284 N
4 IC 140-84237/12 0.16 0.280512 3.84 210527.0 1.7532 Y
5 IC 140-84237/13 0.4 0.544426 3.84 204066.0 1.361066 Y
6 IC 140-84237/14 1.0 1.206068 3.84 205890.0 1.206068 Y
7 ICIS 140-84237/15 2.0 2.220508 3.84 213322.0 1.110254 Y
8 IC 140-84237/7 4.0 4.011338 3.84 238596.0 1.002835 Y
9 IC 140-84237/5 8.0 8.389157 3.84 221929.0 1.048645 Y
10 IC 140-84237/3 16.0 15.773015 3.84 207901.0 0.985813 Y
RelResp = [1.21]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 472 of 864
Calibration / 3-Chloro-1-propene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.069
Error Coefficients
Relative Standard Deviation:20.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.032763 3.84 234059.0 1.638151 N
2 IC 140-84237/10 0.04 0.060433 3.84 217758.0 1.510815 N
3 IC 140-84237/11 0.08 0.118309 3.84 208085.0 1.478857 Y
4 IC 140-84237/12 0.16 0.150516 3.84 210527.0 0.940725 Y
5 IC 140-84237/13 0.4 0.365679 3.84 204066.0 0.914198 Y
6 IC 140-84237/14 1.0 0.892102 3.84 205890.0 0.892102 Y
7 ICIS 140-84237/15 2.0 2.000626 3.84 213322.0 1.000313 Y
8 IC 140-84237/7 4.0 5.363698 3.84 238596.0 1.340924 Y
9 IC 140-84237/5 8.0 8.359292 3.84 221929.0 1.044911 Y
10 IC 140-84237/3 16.0 14.980232 3.84 207901.0 0.936264 Y
RelResp = [1.069]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 473 of 864
Calibration / Carbon disulfide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.303
Error Coefficients
Relative Standard Deviation:5.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.082785 3.84 234059.0 4.139264 N
2 IC 140-84237/10 0.04 0.140139 3.84 217758.0 3.503486 Y
3 IC 140-84237/11 0.08 0.268063 3.84 208085.0 3.350785 Y
4 IC 140-84237/12 0.16 0.567791 3.84 210527.0 3.548694 Y
5 IC 140-84237/13 0.4 1.329132 3.84 204066.0 3.322831 Y
6 IC 140-84237/14 1.0 3.380614 3.84 205890.0 3.380614 Y
7 ICIS 140-84237/15 2.0 6.432858 3.84 213322.0 3.216429 Y
8 IC 140-84237/7 4.0 12.167934 3.84 238596.0 3.041984 Y
9 IC 140-84237/5 8.0 26.097428 3.84 221929.0 3.262178 Y
10 IC 140-84237/3 16.0 49.609791 3.84 207901.0 3.100612 Y
RelResp = [3.303]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 474 of 864
Calibration / trans-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.168
Error Coefficients
Relative Standard Deviation:2.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.02584 3.84 234059.0 1.291982 N
2 IC 140-84237/10 0.04 0.046255 3.84 217758.0 1.156366 Y
3 IC 140-84237/11 0.08 0.092805 3.84 208085.0 1.160064 Y
4 IC 140-84237/12 0.16 0.188291 3.84 210527.0 1.176818 Y
5 IC 140-84237/13 0.4 0.469006 3.84 204066.0 1.172515 Y
6 IC 140-84237/14 1.0 1.214405 3.84 205890.0 1.214405 Y
7 ICIS 140-84237/15 2.0 2.360141 3.84 213322.0 1.180071 Y
8 IC 140-84237/7 4.0 4.481835 3.84 238596.0 1.120459 Y
9 IC 140-84237/5 8.0 9.578501 3.84 221929.0 1.197313 Y
10 IC 140-84237/3 16.0 18.092778 3.84 207901.0 1.130799 Y
RelResp = [1.168]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 475 of 864
Calibration / 2-Methylpentane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.117
Error Coefficients
Relative Standard Deviation:2.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.041737 3.84 234059.0 2.086858 Y
2 IC 140-84237/10 0.04 0.08244 3.84 217758.0 2.061003 Y
3 IC 140-84237/11 0.08 0.166307 3.84 208085.0 2.078843 Y
4 IC 140-84237/12 0.16 0.338077 3.84 210527.0 2.112983 Y
5 IC 140-84237/13 0.4 0.837414 3.84 204066.0 2.093534 Y
6 IC 140-84237/14 1.0 2.15983 3.84 205890.0 2.15983 Y
7 ICIS 140-84237/15 2.0 4.287828 3.84 213322.0 2.143914 Y
8 IC 140-84237/7 4.0 8.371839 3.84 238596.0 2.09296 Y
9 IC 140-84237/5 8.0 17.901803 3.84 221929.0 2.237725 Y
10 IC 140-84237/3 16.0 33.638183 3.84 207901.0 2.102386 Y
RelResp = [2.117]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 476 of 864
Calibration / Methyl tert-butyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.075
Error Coefficients
Relative Standard Deviation:3.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.061556 3.84 234059.0 3.077788 Y
2 IC 140-84237/10 0.04 0.11859 3.84 217758.0 2.964759 Y
3 IC 140-84237/11 0.08 0.237097 3.84 208085.0 2.963712 Y
4 IC 140-84237/12 0.16 0.500686 3.84 210527.0 3.12929 Y
5 IC 140-84237/13 0.4 1.20362 3.84 204066.0 3.00905 Y
6 IC 140-84237/14 1.0 3.181424 3.84 205890.0 3.181424 Y
7 ICIS 140-84237/15 2.0 6.239077 3.84 213322.0 3.119539 Y
8 IC 140-84237/7 4.0 12.171041 3.84 238596.0 3.04276 Y
9 IC 140-84237/5 8.0 25.90874 3.84 221929.0 3.238593 Y
10 IC 140-84237/3 16.0 48.3015 3.84 207901.0 3.018844 Y
RelResp = [3.075]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 477 of 864
Calibration / 1,1-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.007
Error Coefficients
Relative Standard Deviation:3.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.041409 3.84 234059.0 2.070452 Y
2 IC 140-84237/10 0.04 0.076974 3.84 217758.0 1.924338 Y
3 IC 140-84237/11 0.08 0.159793 3.84 208085.0 1.997415 Y
4 IC 140-84237/12 0.16 0.329742 3.84 210527.0 2.060885 Y
5 IC 140-84237/13 0.4 0.814155 3.84 204066.0 2.035389 Y
6 IC 140-84237/14 1.0 2.082038 3.84 205890.0 2.082038 Y
7 ICIS 140-84237/15 2.0 4.026904 3.84 213322.0 2.013452 Y
8 IC 140-84237/7 4.0 7.682221 3.84 238596.0 1.920555 Y
9 IC 140-84237/5 8.0 16.391595 3.84 221929.0 2.048949 Y
10 IC 140-84237/3 16.0 30.741961 3.84 207901.0 1.921373 Y
RelResp = [2.007]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 478 of 864
Calibration / Vinyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.124
Error Coefficients
Relative Standard Deviation:10.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.014667 3.84 234059.0 0.733354 N
2 IC 140-84237/10 0.04 0.034881 3.84 217758.0 0.872014 N
3 IC 140-84237/11 0.08 0.116795 3.84 208085.0 1.459942 N
4 IC 140-84237/12 0.16 0.297621 3.84 210527.0 1.860132 Y
5 IC 140-84237/13 0.4 0.786042 3.84 204066.0 1.965105 Y
6 IC 140-84237/14 1.0 2.087446 3.84 205890.0 2.087446 Y
7 ICIS 140-84237/15 2.0 4.095686 3.84 213322.0 2.047843 Y
8 IC 140-84237/7 4.0 8.177808 3.84 238596.0 2.044452 Y
9 IC 140-84237/5 8.0 19.492279 3.84 221929.0 2.436535 Y
10 IC 140-84237/3 16.0 38.872323 3.84 207901.0 2.42952 Y
RelResp = [2.124]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 479 of 864
Calibration / Hexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8267
Error Coefficients
Relative Standard Deviation:3.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.014519 3.84 234059.0 0.725971 N
2 IC 140-84237/10 0.04 0.032341 3.84 217758.0 0.808531 Y
3 IC 140-84237/11 0.08 0.063205 3.84 208085.0 0.790062 Y
4 IC 140-84237/12 0.16 0.136234 3.84 210527.0 0.851463 Y
5 IC 140-84237/13 0.4 0.329098 3.84 204066.0 0.822746 Y
6 IC 140-84237/14 1.0 0.857505 3.84 205890.0 0.857505 Y
7 ICIS 140-84237/15 2.0 1.685124 3.84 213322.0 0.842562 Y
8 IC 140-84237/7 4.0 3.178965 3.84 238596.0 0.794741 Y
9 IC 140-84237/5 8.0 6.879779 3.84 221929.0 0.859972 Y
10 IC 140-84237/3 16.0 12.999991 3.84 207901.0 0.812499 Y
RelResp = [0.8267]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 480 of 864
Calibration / 2-Butanone (MEK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5317
Error Coefficients
Relative Standard Deviation:7.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.0 3.84 234059.0 0.0 N
2 IC 140-84237/10 0.04 0.0 3.84 217758.0 0.0 N
3 IC 140-84237/11 0.08 0.028419 3.84 208085.0 0.355239 N
4 IC 140-84237/12 0.16 0.075641 3.84 210527.0 0.472756 Y
5 IC 140-84237/13 0.4 0.197922 3.84 204066.0 0.494805 Y
6 IC 140-84237/14 1.0 0.548686 3.84 205890.0 0.548686 Y
7 ICIS 140-84237/15 2.0 1.187091 3.84 213322.0 0.593546 Y
8 IC 140-84237/7 4.0 2.053887 3.84 238596.0 0.513472 Y
9 IC 140-84237/5 8.0 4.472453 3.84 221929.0 0.559057 Y
10 IC 140-84237/3 16.0 8.632275 3.84 207901.0 0.539517 Y
RelResp = [0.5317]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 481 of 864
Calibration / cis-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.231
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.026348 3.84 234059.0 1.317411 Y
2 IC 140-84237/10 0.04 0.04763 3.84 217758.0 1.190753 Y
3 IC 140-84237/11 0.08 0.094374 3.84 208085.0 1.179672 Y
4 IC 140-84237/12 0.16 0.203266 3.84 210527.0 1.270412 Y
5 IC 140-84237/13 0.4 0.482818 3.84 204066.0 1.207045 Y
6 IC 140-84237/14 1.0 1.267467 3.84 205890.0 1.267467 Y
7 ICIS 140-84237/15 2.0 2.473403 3.84 213322.0 1.236702 Y
8 IC 140-84237/7 4.0 4.773911 3.84 238596.0 1.193478 Y
9 IC 140-84237/5 8.0 10.062513 3.84 221929.0 1.257814 Y
10 IC 140-84237/3 16.0 19.015149 3.84 207901.0 1.188447 Y
RelResp = [1.231]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 482 of 864
Calibration / Ethyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.259
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.004856 3.84 234059.0 0.242811 N
2 IC 140-84237/10 0.04 0.052056 3.84 217758.0 1.301408 N
3 IC 140-84237/11 0.08 0.127 3.84 208085.0 1.587505 N
4 IC 140-84237/12 0.16 0.342181 3.84 210527.0 2.138633 Y
5 IC 140-84237/13 0.4 0.826161 3.84 204066.0 2.065402 Y
6 IC 140-84237/14 1.0 2.315825 3.84 205890.0 2.315825 Y
7 ICIS 140-84237/15 2.0 4.552802 3.84 213322.0 2.276401 Y
8 IC 140-84237/7 4.0 9.097959 3.84 238596.0 2.27449 Y
9 IC 140-84237/5 8.0 19.607568 3.84 221929.0 2.450946 Y
10 IC 140-84237/3 16.0 36.686674 3.84 207901.0 2.292917 Y
RelResp = [2.259]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 483 of 864
Calibration / Chloroform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.583
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.055108 3.84 234059.0 2.755408 Y
2 IC 140-84237/10 0.04 0.104395 3.84 217758.0 2.60987 Y
3 IC 140-84237/11 0.08 0.203012 3.84 208085.0 2.537655 Y
4 IC 140-84237/12 0.16 0.426851 3.84 210527.0 2.667819 Y
5 IC 140-84237/13 0.4 1.030481 3.84 204066.0 2.576202 Y
6 IC 140-84237/14 1.0 2.649095 3.84 205890.0 2.649095 Y
7 ICIS 140-84237/15 2.0 5.086548 3.84 213322.0 2.543274 Y
8 IC 140-84237/7 4.0 9.77842 3.84 238596.0 2.444605 Y
9 IC 140-84237/5 8.0 20.79828 3.84 221929.0 2.599785 Y
10 IC 140-84237/3 16.0 39.204586 3.84 207901.0 2.450287 Y
RelResp = [2.583]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 484 of 864
Calibration / Tetrahydrofuran
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.099
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.009778 3.84 234059.0 0.488902 N
2 IC 140-84237/10 0.04 0.036009 3.84 217758.0 0.900229 N
3 IC 140-84237/11 0.08 0.075052 3.84 208085.0 0.938155 N
4 IC 140-84237/12 0.16 0.168701 3.84 210527.0 1.054383 Y
5 IC 140-84237/13 0.4 0.420626 3.84 204066.0 1.051566 Y
6 IC 140-84237/14 1.0 1.109141 3.84 205890.0 1.109141 Y
7 ICIS 140-84237/15 2.0 2.245673 3.84 213322.0 1.122837 Y
8 IC 140-84237/7 4.0 4.398242 3.84 238596.0 1.09956 Y
9 IC 140-84237/5 8.0 9.344844 3.84 221929.0 1.168105 Y
10 IC 140-84237/3 16.0 17.376203 3.84 207901.0 1.086013 Y
RelResp = [1.099]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 485 of 864
Calibration / 1,1,1-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.528
Error Coefficients
Relative Standard Deviation:2.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.052188 3.84 234059.0 2.609393 Y
2 IC 140-84237/10 0.04 0.101326 3.84 217758.0 2.533161 Y
3 IC 140-84237/11 0.08 0.199525 3.84 208085.0 2.494058 Y
4 IC 140-84237/12 0.16 0.406185 3.84 210527.0 2.538658 Y
5 IC 140-84237/13 0.4 0.998736 3.84 204066.0 2.496839 Y
6 IC 140-84237/14 1.0 2.574268 3.84 205890.0 2.574268 Y
7 ICIS 140-84237/15 2.0 5.045236 3.84 213322.0 2.522618 Y
8 IC 140-84237/7 4.0 9.794852 3.84 238596.0 2.448713 Y
9 IC 140-84237/5 8.0 20.93409 3.84 221929.0 2.616761 Y
10 IC 140-84237/3 16.0 39.117609 3.84 207901.0 2.444851 Y
RelResp = [2.528]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 486 of 864
Calibration / 1,2-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3469
Error Coefficients
Relative Standard Deviation:5.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.006266 3.84 1080986.0 0.313314 N
2 IC 140-84237/10 0.04 0.011838 3.84 1017540.0 0.295961 N
3 IC 140-84237/11 0.08 0.024826 3.84 972773.0 0.310321 Y
4 IC 140-84237/12 0.16 0.056648 3.84 978091.0 0.354053 Y
5 IC 140-84237/13 0.4 0.135583 3.84 952471.0 0.338958 Y
6 IC 140-84237/14 1.0 0.353647 3.84 960677.0 0.353647 Y
7 ICIS 140-84237/15 2.0 0.698763 3.84 995985.0 0.349382 Y
8 IC 140-84237/7 4.0 1.406169 3.84 1076786.0 0.351542 Y
9 IC 140-84237/5 8.0 2.974366 3.84 1015222.0 0.371796 Y
10 IC 140-84237/3 16.0 5.523085 3.84 947038.0 0.345193 Y
RelResp = [0.3469]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 487 of 864
Calibration / n-Butanol
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.01017
Slope:0.09488
Error Coefficients
Relative Standard Deviation:6.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.0 3.84 1080986.0 0.0 N
2 IC 140-84237/10 0.04 0.0 3.84 1017540.0 0.0 N
3 IC 140-84237/11 0.08 0.001232 3.84 972773.0 0.015395 N
4 IC 140-84237/12 0.16 0.005704 3.84 978091.0 0.035653 Y
5 IC 140-84237/13 0.4 0.024073 3.84 952471.0 0.060182 Y
6 IC 140-84237/14 1.0 0.079216 3.84 960677.0 0.079216 Y
7 ICIS 140-84237/15 2.0 0.181377 3.84 995985.0 0.090689 Y
8 IC 140-84237/7 4.0 0.367836 3.84 1076786.0 0.091959 Y
9 IC 140-84237/5 8.0 0.815748 3.84 1015222.0 0.101968 Y
10 IC 140-84237/3 16.0 1.532236 3.84 947038.0 0.095765 Y
RelResp = [-0.01017] + [0.09488]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5 IC 140-84237/3
Intercept = 0.107
3/25/2024
9:50:51 AM
Page 488 of 864
Calibration / Cyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1148
Error Coefficients
Relative Standard Deviation:4.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.001936 3.84 1080986.0 0.096801 N
2 IC 140-84237/10 0.04 0.003729 3.84 1017540.0 0.093213 N
3 IC 140-84237/11 0.08 0.008116 3.84 972773.0 0.10145 N
4 IC 140-84237/12 0.16 0.017463 3.84 978091.0 0.109143 Y
5 IC 140-84237/13 0.4 0.043541 3.84 952471.0 0.108854 Y
6 IC 140-84237/14 1.0 0.115079 3.84 960677.0 0.115079 Y
7 ICIS 140-84237/15 2.0 0.232994 3.84 995985.0 0.116497 Y
8 IC 140-84237/7 4.0 0.458652 3.84 1076786.0 0.114663 Y
9 IC 140-84237/5 8.0 0.976754 3.84 1015222.0 0.122094 Y
10 IC 140-84237/3 16.0 1.879124 3.84 947038.0 0.117445 Y
RelResp = [0.1148]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 489 of 864
Calibration / Benzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7629
Error Coefficients
Relative Standard Deviation:2.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.017349 3.84 1080986.0 0.867475 N
2 IC 140-84237/10 0.04 0.032896 3.84 1017540.0 0.822407 N
3 IC 140-84237/11 0.08 0.062958 3.84 972773.0 0.786979 Y
4 IC 140-84237/12 0.16 0.124054 3.84 978091.0 0.775339 Y
5 IC 140-84237/13 0.4 0.29863 3.84 952471.0 0.746575 Y
6 IC 140-84237/14 1.0 0.780082 3.84 960677.0 0.780082 Y
7 ICIS 140-84237/15 2.0 1.530413 3.84 995985.0 0.765207 Y
8 IC 140-84237/7 4.0 2.949039 3.84 1076786.0 0.73726 Y
9 IC 140-84237/5 8.0 6.155853 3.84 1015222.0 0.769482 Y
10 IC 140-84237/3 16.0 11.880066 3.84 947038.0 0.742504 Y
RelResp = [0.7629]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 490 of 864
Calibration / Carbon tetrachloride
Curve Type:Quadratic
Weighting:None
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.601
Second Order:-0.00455
Error Coefficients
Relative Standard Deviation:16.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.011335 3.84 1080986.0 0.566771 Y
2 IC 140-84237/10 0.04 0.021118 3.84 1017540.0 0.527956 Y
3 IC 140-84237/11 0.08 0.040679 3.84 972773.0 0.508485 Y
4 IC 140-84237/12 0.16 0.081253 3.84 978091.0 0.50783 Y
5 IC 140-84237/13 0.4 0.194155 3.84 952471.0 0.485387 Y
6 IC 140-84237/14 1.0 0.404503 3.84 960677.0 0.404503 Y
7 ICIS 140-84237/15 2.0 1.105447 3.84 995985.0 0.552724 Y
8 IC 140-84237/7 4.0 2.22433 3.84 1076786.0 0.556082 Y
9 IC 140-84237/5 8.0 4.68165 3.84 1015222.0 0.585206 Y
10 IC 140-84237/3 16.0 8.41903 3.84 947038.0 0.526189 Y
RelResp = [0.601]x + [-0.00455]x^2
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 491 of 864
Calibration / 2,3-Dimethylpentane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1679
Error Coefficients
Relative Standard Deviation:5.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.00248 3.84 1080986.0 0.123976 N
2 IC 140-84237/10 0.04 0.005547 3.84 1017540.0 0.138687 N
3 IC 140-84237/11 0.08 0.011602 3.84 972773.0 0.14502 Y
4 IC 140-84237/12 0.16 0.027305 3.84 978091.0 0.170659 Y
5 IC 140-84237/13 0.4 0.066868 3.84 952471.0 0.167171 Y
6 IC 140-84237/14 1.0 0.173066 3.84 960677.0 0.173066 Y
7 ICIS 140-84237/15 2.0 0.342162 3.84 995985.0 0.171081 Y
8 IC 140-84237/7 4.0 0.677707 3.84 1076786.0 0.169427 Y
9 IC 140-84237/5 8.0 1.411589 3.84 1015222.0 0.176449 Y
10 IC 140-84237/3 16.0 2.721344 3.84 947038.0 0.170084 Y
RelResp = [0.1679]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 492 of 864
Calibration / Thiophene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.432
Error Coefficients
Relative Standard Deviation:3.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.008796 3.84 1080986.0 0.439776 Y
2 IC 140-84237/10 0.04 0.016054 3.84 1017540.0 0.401344 Y
3 IC 140-84237/11 0.08 0.033502 3.84 972773.0 0.418778 Y
4 IC 140-84237/12 0.16 0.068065 3.84 978091.0 0.425408 Y
5 IC 140-84237/13 0.4 0.170243 3.84 952471.0 0.425608 Y
6 IC 140-84237/14 1.0 0.446313 3.84 960677.0 0.446313 Y
7 ICIS 140-84237/15 2.0 0.873968 3.84 995985.0 0.436984 Y
8 IC 140-84237/7 4.0 1.727434 3.84 1076786.0 0.431859 Y
9 IC 140-84237/5 8.0 3.639505 3.84 1015222.0 0.454938 Y
10 IC 140-84237/3 16.0 7.016286 3.84 947038.0 0.438518 Y
RelResp = [0.432]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 493 of 864
Calibration / Isooctane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.145
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.024852 3.84 1080986.0 1.242599 Y
2 IC 140-84237/10 0.04 0.04561 3.84 1017540.0 1.140256 Y
3 IC 140-84237/11 0.08 0.087141 3.84 972773.0 1.089257 Y
4 IC 140-84237/12 0.16 0.184617 3.84 978091.0 1.153856 Y
5 IC 140-84237/13 0.4 0.445736 3.84 952471.0 1.114339 Y
6 IC 140-84237/14 1.0 1.14548 3.84 960677.0 1.14548 Y
7 ICIS 140-84237/15 2.0 2.253512 3.84 995985.0 1.126756 Y
8 IC 140-84237/7 4.0 4.480156 3.84 1076786.0 1.120039 Y
9 IC 140-84237/5 8.0 9.455224 3.84 1015222.0 1.181903 Y
10 IC 140-84237/3 16.0 18.148949 3.84 947038.0 1.134309 Y
RelResp = [1.145]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 494 of 864
Calibration / n-Heptane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2534
Error Coefficients
Relative Standard Deviation:5.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.004714 3.84 1080986.0 0.235696 Y
2 IC 140-84237/10 0.04 0.009623 3.84 1017540.0 0.24058 Y
3 IC 140-84237/11 0.08 0.018324 3.84 972773.0 0.229052 Y
4 IC 140-84237/12 0.16 0.040077 3.84 978091.0 0.25048 Y
5 IC 140-84237/13 0.4 0.099819 3.84 952471.0 0.249547 Y
6 IC 140-84237/14 1.0 0.264414 3.84 960677.0 0.264414 Y
7 ICIS 140-84237/15 2.0 0.527846 3.84 995985.0 0.263923 Y
8 IC 140-84237/7 4.0 1.038482 3.84 1076786.0 0.259621 Y
9 IC 140-84237/5 8.0 2.200081 3.84 1015222.0 0.27501 Y
10 IC 140-84237/3 16.0 4.255587 3.84 947038.0 0.265974 Y
RelResp = [0.2534]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
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Calibration / 1,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.279
Error Coefficients
Relative Standard Deviation:1.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.005517 3.84 1080986.0 0.275837 Y
2 IC 140-84237/10 0.04 0.010869 3.84 1017540.0 0.271714 Y
3 IC 140-84237/11 0.08 0.022287 3.84 972773.0 0.278593 Y
4 IC 140-84237/12 0.16 0.045373 3.84 978091.0 0.283581 Y
5 IC 140-84237/13 0.4 0.111341 3.84 952471.0 0.278353 Y
6 IC 140-84237/14 1.0 0.285091 3.84 960677.0 0.285091 Y
7 ICIS 140-84237/15 2.0 0.55463 3.84 995985.0 0.277315 Y
8 IC 140-84237/7 4.0 1.09114 3.84 1076786.0 0.272785 Y
9 IC 140-84237/5 8.0 2.300043 3.84 1015222.0 0.287505 Y
10 IC 140-84237/3 16.0 4.466629 3.84 947038.0 0.279164 Y
RelResp = [0.279]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 496 of 864
Calibration / Trichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3617
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.007495 3.84 1080986.0 0.374769 Y
2 IC 140-84237/10 0.04 0.013578 3.84 1017540.0 0.339454 Y
3 IC 140-84237/11 0.08 0.027617 3.84 972773.0 0.345207 Y
4 IC 140-84237/12 0.16 0.060724 3.84 978091.0 0.379523 Y
5 IC 140-84237/13 0.4 0.142643 3.84 952471.0 0.356607 Y
6 IC 140-84237/14 1.0 0.375087 3.84 960677.0 0.375087 Y
7 ICIS 140-84237/15 2.0 0.727286 3.84 995985.0 0.363643 Y
8 IC 140-84237/7 4.0 1.443934 3.84 1076786.0 0.360984 Y
9 IC 140-84237/5 8.0 2.978939 3.84 1015222.0 0.372367 Y
10 IC 140-84237/3 16.0 5.59322 3.84 947038.0 0.349576 Y
RelResp = [0.3617]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 497 of 864
Calibration / Dibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3314
Error Coefficients
Relative Standard Deviation:2.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.008231 3.84 1080986.0 0.411535 N
2 IC 140-84237/10 0.04 0.016227 3.84 1017540.0 0.405684 N
3 IC 140-84237/11 0.08 0.030297 3.84 972773.0 0.378711 N
4 IC 140-84237/12 0.16 0.054352 3.84 978091.0 0.339698 Y
5 IC 140-84237/13 0.4 0.130157 3.84 952471.0 0.325392 Y
6 IC 140-84237/14 1.0 0.329688 3.84 960677.0 0.329688 Y
7 ICIS 140-84237/15 2.0 0.641209 3.84 995985.0 0.320604 Y
8 IC 140-84237/7 4.0 1.387275 3.84 1076786.0 0.346819 Y
9 IC 140-84237/5 8.0 2.656079 3.84 1015222.0 0.33201 Y
10 IC 140-84237/3 16.0 5.209978 3.84 947038.0 0.325624 Y
RelResp = [0.3314]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7 IC 140-84237/5
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Calibration / Dichlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5632
Error Coefficients
Relative Standard Deviation:7.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.009911 3.84 1080986.0 0.495548 N
2 IC 140-84237/10 0.04 0.018677 3.84 1017540.0 0.466914 N
3 IC 140-84237/11 0.08 0.038239 3.84 972773.0 0.47799 Y
4 IC 140-84237/12 0.16 0.091103 3.84 978091.0 0.569395 Y
5 IC 140-84237/13 0.4 0.218869 3.84 952471.0 0.547171 Y
6 IC 140-84237/14 1.0 0.570829 3.84 960677.0 0.570829 Y
7 ICIS 140-84237/15 2.0 1.137933 3.84 995985.0 0.568967 Y
8 IC 140-84237/7 4.0 2.27008 3.84 1076786.0 0.56752 Y
9 IC 140-84237/5 8.0 4.945451 3.84 1015222.0 0.618181 Y
10 IC 140-84237/3 16.0 9.365656 3.84 947038.0 0.585353 Y
RelResp = [0.5632]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 499 of 864
Calibration / 1,4-Dioxane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1107
Error Coefficients
Relative Standard Deviation:7.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.000956 3.84 1080986.0 0.047779 N
2 IC 140-84237/10 0.04 0.00371 3.84 1017540.0 0.092741 N
3 IC 140-84237/11 0.08 0.007038 3.84 972773.0 0.087979 N
4 IC 140-84237/12 0.16 0.015681 3.84 978091.0 0.098003 Y
5 IC 140-84237/13 0.4 0.040808 3.84 952471.0 0.10202 Y
6 IC 140-84237/14 1.0 0.113556 3.84 960677.0 0.113556 Y
7 ICIS 140-84237/15 2.0 0.23872 3.84 995985.0 0.11936 Y
8 IC 140-84237/7 4.0 0.446923 3.84 1076786.0 0.111731 Y
9 IC 140-84237/5 8.0 0.960028 3.84 1015222.0 0.120004 Y
10 IC 140-84237/3 16.0 1.766694 3.84 947038.0 0.110418 Y
RelResp = [0.1107]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 500 of 864
Calibration / Methyl methacrylate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2911
Error Coefficients
Relative Standard Deviation:13.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.000813 3.84 1080986.0 0.040674 N
2 IC 140-84237/10 0.04 0.002336 3.84 1017540.0 0.0584 N
3 IC 140-84237/11 0.08 0.013011 3.84 972773.0 0.162636 N
4 IC 140-84237/12 0.16 0.038259 3.84 978091.0 0.239119 Y
5 IC 140-84237/13 0.4 0.09561 3.84 952471.0 0.239025 Y
6 IC 140-84237/14 1.0 0.292142 3.84 960677.0 0.292142 Y
7 ICIS 140-84237/15 2.0 0.572581 3.84 995985.0 0.286291 Y
8 IC 140-84237/7 4.0 1.262053 3.84 1076786.0 0.315513 Y
9 IC 140-84237/5 8.0 2.746032 3.84 1015222.0 0.343254 Y
10 IC 140-84237/3 16.0 5.155956 3.84 947038.0 0.322247 Y
RelResp = [0.2911]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 501 of 864
Calibration / Methylcyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.454
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.008845 3.84 1080986.0 0.442263 N
2 IC 140-84237/10 0.04 0.016941 3.84 1017540.0 0.423516 N
3 IC 140-84237/11 0.08 0.032598 3.84 972773.0 0.407478 Y
4 IC 140-84237/12 0.16 0.07165 3.84 978091.0 0.447811 Y
5 IC 140-84237/13 0.4 0.176726 3.84 952471.0 0.441815 Y
6 IC 140-84237/14 1.0 0.464724 3.84 960677.0 0.464724 Y
7 ICIS 140-84237/15 2.0 0.916247 3.84 995985.0 0.458124 Y
8 IC 140-84237/7 4.0 1.843691 3.84 1076786.0 0.460923 Y
9 IC 140-84237/5 8.0 3.87453 3.84 1015222.0 0.484316 Y
10 IC 140-84237/3 16.0 7.470471 3.84 947038.0 0.466904 Y
RelResp = [0.454]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 502 of 864
Calibration / 4-Methyl-2-pentanone (MIBK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.527
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.006071 3.84 1080986.0 0.303545 N
2 IC 140-84237/10 0.04 0.014688 3.84 1017540.0 0.367191 N
3 IC 140-84237/11 0.08 0.031469 3.84 972773.0 0.393366 N
4 IC 140-84237/12 0.16 0.073892 3.84 978091.0 0.461822 Y
5 IC 140-84237/13 0.4 0.192933 3.84 952471.0 0.482333 Y
6 IC 140-84237/14 1.0 0.519717 3.84 960677.0 0.519717 Y
7 ICIS 140-84237/15 2.0 1.062451 3.84 995985.0 0.531225 Y
8 IC 140-84237/7 4.0 2.153331 3.84 1076786.0 0.538333 Y
9 IC 140-84237/5 8.0 4.731264 3.84 1015222.0 0.591408 Y
10 IC 140-84237/3 16.0 9.022267 3.84 947038.0 0.563892 Y
RelResp = [0.527]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 503 of 864
Calibration / cis-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4336
Error Coefficients
Relative Standard Deviation:8.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.006465 3.84 1080986.0 0.32326 N
2 IC 140-84237/10 0.04 0.013963 3.84 1017540.0 0.349077 N
3 IC 140-84237/11 0.08 0.028749 3.84 972773.0 0.359369 Y
4 IC 140-84237/12 0.16 0.066495 3.84 978091.0 0.415593 Y
5 IC 140-84237/13 0.4 0.164208 3.84 952471.0 0.41052 Y
6 IC 140-84237/14 1.0 0.440929 3.84 960677.0 0.440929 Y
7 ICIS 140-84237/15 2.0 0.888464 3.84 995985.0 0.444232 Y
8 IC 140-84237/7 4.0 1.789482 3.84 1076786.0 0.44737 Y
9 IC 140-84237/5 8.0 3.855637 3.84 1015222.0 0.481955 Y
10 IC 140-84237/3 16.0 7.503562 3.84 947038.0 0.468973 Y
RelResp = [0.4336]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 504 of 864
Calibration / trans-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.441
Error Coefficients
Relative Standard Deviation:10.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.006588 4.0 961170.0 0.32939 N
2 IC 140-84237/10 0.04 0.013195 4.0 910928.0 0.329883 N
3 IC 140-84237/11 0.08 0.028301 4.0 872917.0 0.353756 Y
4 IC 140-84237/12 0.16 0.068758 4.0 876587.0 0.429735 Y
5 IC 140-84237/13 0.4 0.163903 4.0 856899.0 0.409757 Y
6 IC 140-84237/14 1.0 0.445514 4.0 865598.0 0.445514 Y
7 ICIS 140-84237/15 2.0 0.928972 4.0 895394.0 0.464486 Y
8 IC 140-84237/7 4.0 1.865786 4.0 991861.0 0.466446 Y
9 IC 140-84237/5 8.0 4.02789 4.0 949158.0 0.503486 Y
10 IC 140-84237/3 16.0 7.278688 4.0 939128.0 0.454918 Y
RelResp = [0.441]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Calibration / Toluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.096
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.028886 4.0 961170.0 1.444281 N
2 IC 140-84237/10 0.04 0.046871 4.0 910928.0 1.171772 N
3 IC 140-84237/11 0.08 0.089809 4.0 872917.0 1.122615 Y
4 IC 140-84237/12 0.16 0.180965 4.0 876587.0 1.131034 Y
5 IC 140-84237/13 0.4 0.428639 4.0 856899.0 1.071597 Y
6 IC 140-84237/14 1.0 1.116135 4.0 865598.0 1.116135 Y
7 ICIS 140-84237/15 2.0 2.222526 4.0 895394.0 1.111263 Y
8 IC 140-84237/7 4.0 4.357514 4.0 991861.0 1.089378 Y
9 IC 140-84237/5 8.0 8.953675 4.0 949158.0 1.119209 Y
10 IC 140-84237/3 16.0 16.163935 4.0 939128.0 1.010246 Y
RelResp = [1.096]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Calibration / 1,1,2-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.323
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.005547 4.0 961170.0 0.27737 N
2 IC 140-84237/10 0.04 0.011817 4.0 910928.0 0.295413 N
3 IC 140-84237/11 0.08 0.025821 4.0 872917.0 0.322768 Y
4 IC 140-84237/12 0.16 0.052928 4.0 876587.0 0.3308 Y
5 IC 140-84237/13 0.4 0.128099 4.0 856899.0 0.320248 Y
6 IC 140-84237/14 1.0 0.338541 4.0 865598.0 0.338541 Y
7 ICIS 140-84237/15 2.0 0.65262 4.0 895394.0 0.32631 Y
8 IC 140-84237/7 4.0 1.265794 4.0 991861.0 0.316449 Y
9 IC 140-84237/5 8.0 2.633222 4.0 949158.0 0.329153 Y
10 IC 140-84237/3 16.0 4.801603 4.0 939128.0 0.3001 Y
RelResp = [0.323]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
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(

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)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 507 of 864
Calibration / 2-Hexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3131
Error Coefficients
Relative Standard Deviation:12.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.0 4.0 961170.0 0.0 N
2 IC 140-84237/10 0.04 0.004114 4.0 910928.0 0.102862 N
3 IC 140-84237/11 0.08 0.014654 4.0 872917.0 0.183179 N
4 IC 140-84237/12 0.16 0.039686 4.0 876587.0 0.248036 Y
5 IC 140-84237/13 0.4 0.108914 4.0 856899.0 0.272284 Y
6 IC 140-84237/14 1.0 0.315777 4.0 865598.0 0.315777 Y
7 ICIS 140-84237/15 2.0 0.663962 4.0 895394.0 0.331981 Y
8 IC 140-84237/7 4.0 1.283636 4.0 991861.0 0.320909 Y
9 IC 140-84237/5 8.0 2.759132 4.0 949158.0 0.344891 Y
10 IC 140-84237/3 16.0 5.719842 4.0 939128.0 0.35749 Y
RelResp = [0.3131]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 508 of 864
Calibration / n-Octane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3317
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.006238 4.0 961170.0 0.311912 Y
2 IC 140-84237/10 0.04 0.012242 4.0 910928.0 0.306062 Y
3 IC 140-84237/11 0.08 0.025207 4.0 872917.0 0.315093 Y
4 IC 140-84237/12 0.16 0.053544 4.0 876587.0 0.33465 Y
5 IC 140-84237/13 0.4 0.128799 4.0 856899.0 0.321998 Y
6 IC 140-84237/14 1.0 0.343457 4.0 865598.0 0.343457 Y
7 ICIS 140-84237/15 2.0 0.687072 4.0 895394.0 0.343536 Y
8 IC 140-84237/7 4.0 1.360937 4.0 991861.0 0.340234 Y
9 IC 140-84237/5 8.0 2.828241 4.0 949158.0 0.35353 Y
10 IC 140-84237/3 16.0 5.544607 4.0 939128.0 0.346538 Y
RelResp = [0.3317]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 509 of 864
Calibration / C8 Range
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.553
Error Coefficients
Relative Standard Deviation:6.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.051764 3.84 1080986.0 2.588215 N
2 IC 140-84237/10 0.04 0.092296 3.84 1017540.0 2.3074 N
3 IC 140-84237/11 0.08 0.182026 3.84 972773.0 2.275326 N
4 IC 140-84237/12 0.16 0.388122 3.84 978091.0 2.425762 N
5 IC 140-84237/13 0.4 0.94937 3.84 952471.0 2.373424 Y
6 IC 140-84237/14 1.0 2.510374 3.84 960677.0 2.510374 Y
7 ICIS 140-84237/15 2.0 4.94072 3.84 995985.0 2.47036 Y
8 IC 140-84237/7 4.0 9.971374 3.84 1076786.0 2.492843 Y
9 IC 140-84237/5 8.0 21.390205 3.84 1015222.0 2.673776 Y
10 IC 140-84237/3 16.0 44.781986 3.84 947038.0 2.798874 Y
RelResp = [2.553]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 510 of 864
Calibration / Chlorodibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6318
Error Coefficients
Relative Standard Deviation:15.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.007824 4.0 961170.0 0.39119 N
2 IC 140-84237/10 0.04 0.015689 4.0 910928.0 0.392237 N
3 IC 140-84237/11 0.08 0.032686 4.0 872917.0 0.408573 Y
4 IC 140-84237/12 0.16 0.101019 4.0 876587.0 0.631369 Y
5 IC 140-84237/13 0.4 0.249948 4.0 856899.0 0.624869 Y
6 IC 140-84237/14 1.0 0.674909 4.0 865598.0 0.674909 Y
7 ICIS 140-84237/15 2.0 1.369462 4.0 895394.0 0.684731 Y
8 IC 140-84237/7 4.0 2.529588 4.0 991861.0 0.632397 Y
9 IC 140-84237/5 8.0 5.820548 4.0 949158.0 0.727569 Y
10 IC 140-84237/3 16.0 10.719416 4.0 939128.0 0.669964 Y
RelResp = [0.6318]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 511 of 864
Calibration / Ethylene Dibromide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5823
Error Coefficients
Relative Standard Deviation:6.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.011765 4.0 961170.0 0.588241 Y
2 IC 140-84237/10 0.04 0.021249 4.0 910928.0 0.531217 Y
3 IC 140-84237/11 0.08 0.040755 4.0 872917.0 0.509441 Y
4 IC 140-84237/12 0.16 0.09265 4.0 876587.0 0.579064 Y
5 IC 140-84237/13 0.4 0.229348 4.0 856899.0 0.57337 Y
6 IC 140-84237/14 1.0 0.609586 4.0 865598.0 0.609586 Y
7 ICIS 140-84237/15 2.0 1.21152 4.0 895394.0 0.60576 Y
8 IC 140-84237/7 4.0 2.402143 4.0 991861.0 0.600536 Y
9 IC 140-84237/5 8.0 5.035027 4.0 949158.0 0.629378 Y
10 IC 140-84237/3 16.0 9.537013 4.0 939128.0 0.596063 Y
RelResp = [0.5823]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 512 of 864
Calibration / Tetrachloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.394
Error Coefficients
Relative Standard Deviation:3.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.008227 4.0 961170.0 0.411374 N
2 IC 140-84237/10 0.04 0.016054 4.0 910928.0 0.401349 Y
3 IC 140-84237/11 0.08 0.029684 4.0 872917.0 0.371055 Y
4 IC 140-84237/12 0.16 0.065974 4.0 876587.0 0.412338 Y
5 IC 140-84237/13 0.4 0.161592 4.0 856899.0 0.40398 Y
6 IC 140-84237/14 1.0 0.405204 4.0 865598.0 0.405204 Y
7 ICIS 140-84237/15 2.0 0.794904 4.0 895394.0 0.397452 Y
8 IC 140-84237/7 4.0 1.563489 4.0 991861.0 0.390872 Y
9 IC 140-84237/5 8.0 3.174827 4.0 949158.0 0.396853 Y
10 IC 140-84237/3 16.0 5.866293 4.0 939128.0 0.366643 Y
RelResp = [0.394]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 513 of 864
Calibration / Chlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.881
Error Coefficients
Relative Standard Deviation:4.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.019131 4.0 961170.0 0.956543 Y
2 IC 140-84237/10 0.04 0.036025 4.0 910928.0 0.90062 Y
3 IC 140-84237/11 0.08 0.071636 4.0 872917.0 0.895446 Y
4 IC 140-84237/12 0.16 0.143484 4.0 876587.0 0.896774 Y
5 IC 140-84237/13 0.4 0.350636 4.0 856899.0 0.876591 Y
6 IC 140-84237/14 1.0 0.897761 4.0 865598.0 0.897761 Y
7 ICIS 140-84237/15 2.0 1.745707 4.0 895394.0 0.872854 Y
8 IC 140-84237/7 4.0 3.387152 4.0 991861.0 0.846788 Y
9 IC 140-84237/5 8.0 6.902737 4.0 949158.0 0.862842 Y
10 IC 140-84237/3 16.0 12.864023 4.0 939128.0 0.804001 Y
RelResp = [0.881]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 514 of 864
Calibration / Ethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.413
Error Coefficients
Relative Standard Deviation:3.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.029656 4.0 961170.0 1.482776 Y
2 IC 140-84237/10 0.04 0.055038 4.0 910928.0 1.375959 Y
3 IC 140-84237/11 0.08 0.108258 4.0 872917.0 1.353221 Y
4 IC 140-84237/12 0.16 0.222677 4.0 876587.0 1.391733 Y
5 IC 140-84237/13 0.4 0.540708 4.0 856899.0 1.35177 Y
6 IC 140-84237/14 1.0 1.441676 4.0 865598.0 1.441676 Y
7 ICIS 140-84237/15 2.0 2.856079 4.0 895394.0 1.428039 Y
8 IC 140-84237/7 4.0 5.638096 4.0 991861.0 1.409524 Y
9 IC 140-84237/5 8.0 11.732319 4.0 949158.0 1.46654 Y
10 IC 140-84237/3 16.0 22.8875 4.0 939128.0 1.430469 Y
RelResp = [1.413]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 515 of 864
Calibration / m-Xylene & p-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.105
Error Coefficients
Relative Standard Deviation:4.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.04 0.048037 4.0 961170.0 1.200932 Y
2 IC 140-84237/10 0.08 0.086027 4.0 910928.0 1.075332 Y
3 IC 140-84237/11 0.16 0.165601 4.0 872917.0 1.035007 Y
4 IC 140-84237/12 0.32 0.343272 4.0 876587.0 1.072726 Y
5 IC 140-84237/13 0.8 0.863024 4.0 856899.0 1.078779 Y
6 IC 140-84237/14 2.0 2.25305 4.0 865598.0 1.126525 Y
7 ICIS 140-84237/15 4.0 4.498493 4.0 895394.0 1.124623 Y
8 IC 140-84237/7 8.0 8.800237 4.0 991861.0 1.10003 Y
9 IC 140-84237/5 16.0 18.368849 4.0 949158.0 1.148053 Y
10 IC 140-84237/3 32.0 34.834344 4.0 939128.0 1.088573 Y
RelResp = [1.105]x
Concentration
0 10 20 30 40
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 516 of 864
Calibration / n-Nonane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6086
Error Coefficients
Relative Standard Deviation:6.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.011553 4.0 961170.0 0.577629 N
2 IC 140-84237/10 0.04 0.021367 4.0 910928.0 0.534181 N
3 IC 140-84237/11 0.08 0.042034 4.0 872917.0 0.525422 N
4 IC 140-84237/12 0.16 0.088224 4.0 876587.0 0.5514 Y
5 IC 140-84237/13 0.4 0.223644 4.0 856899.0 0.559109 Y
6 IC 140-84237/14 1.0 0.611776 4.0 865598.0 0.611776 Y
7 ICIS 140-84237/15 2.0 1.229104 4.0 895394.0 0.614552 Y
8 IC 140-84237/7 4.0 2.446077 4.0 991861.0 0.611519 Y
9 IC 140-84237/5 8.0 5.278885 4.0 949158.0 0.659861 Y
10 IC 140-84237/3 16.0 10.426694 4.0 939128.0 0.651668 Y
RelResp = [0.6086]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5 IC 140-84237/3
3/25/2024
9:50:51 AM
Page 517 of 864
Calibration / Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7698
Error Coefficients
Relative Standard Deviation:8.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.012377 4.0 961170.0 0.618829 N
2 IC 140-84237/10 0.04 0.024674 4.0 910928.0 0.616843 N
3 IC 140-84237/11 0.08 0.05091 4.0 872917.0 0.636372 Y
4 IC 140-84237/12 0.16 0.114645 4.0 876587.0 0.716529 Y
5 IC 140-84237/13 0.4 0.295886 4.0 856899.0 0.739714 Y
6 IC 140-84237/14 1.0 0.804008 4.0 865598.0 0.804008 Y
7 ICIS 140-84237/15 2.0 1.618014 4.0 895394.0 0.809007 Y
8 IC 140-84237/7 4.0 3.232445 4.0 991861.0 0.808111 Y
9 IC 140-84237/5 8.0 6.807705 4.0 949158.0 0.850963 Y
10 IC 140-84237/3 16.0 12.698729 4.0 939128.0 0.793671 Y
RelResp = [0.7698]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 518 of 864
Calibration / Bromoform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5537
Error Coefficients
Relative Standard Deviation:30.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.00298 4.0 961170.0 0.148985 N
2 IC 140-84237/10 0.04 0.007057 4.0 910928.0 0.176414 N
3 IC 140-84237/11 0.08 0.014169 4.0 872917.0 0.177107 Y
4 IC 140-84237/12 0.16 0.096999 4.0 876587.0 0.606243 Y
5 IC 140-84237/13 0.4 0.239468 4.0 856899.0 0.59867 Y
6 IC 140-84237/14 1.0 0.63996 4.0 865598.0 0.63996 Y
7 ICIS 140-84237/15 2.0 1.335555 4.0 895394.0 0.667778 Y
8 IC 140-84237/7 4.0 1.854966 4.0 991861.0 0.463741 Y
9 IC 140-84237/5 8.0 5.539887 4.0 949158.0 0.692486 Y
10 IC 140-84237/3 16.0 9.339251 4.0 939128.0 0.583703 Y
RelResp = [0.5537]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
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Page 519 of 864
Calibration / o-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.152
Error Coefficients
Relative Standard Deviation:3.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.023921 4.0 961170.0 1.196042 Y
2 IC 140-84237/10 0.04 0.043722 4.0 910928.0 1.093061 Y
3 IC 140-84237/11 0.08 0.086322 4.0 872917.0 1.079026 Y
4 IC 140-84237/12 0.16 0.187651 4.0 876587.0 1.172816 Y
5 IC 140-84237/13 0.4 0.455578 4.0 856899.0 1.138944 Y
6 IC 140-84237/14 1.0 1.188589 4.0 865598.0 1.188589 Y
7 ICIS 140-84237/15 2.0 2.352765 4.0 895394.0 1.176383 Y
8 IC 140-84237/7 4.0 4.564426 4.0 991861.0 1.141106 Y
9 IC 140-84237/5 8.0 9.517851 4.0 949158.0 1.189731 Y
10 IC 140-84237/3 16.0 18.256523 4.0 939128.0 1.141033 Y
RelResp = [1.152]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 520 of 864
Calibration / 1,1,2,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8592
Error Coefficients
Relative Standard Deviation:3.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.01802 4.0 961170.0 0.900985 Y
2 IC 140-84237/10 0.04 0.032411 4.0 910928.0 0.810273 Y
3 IC 140-84237/11 0.08 0.066458 4.0 872917.0 0.83072 Y
4 IC 140-84237/12 0.16 0.136511 4.0 876587.0 0.853195 Y
5 IC 140-84237/13 0.4 0.336941 4.0 856899.0 0.842351 Y
6 IC 140-84237/14 1.0 0.894466 4.0 865598.0 0.894466 Y
7 ICIS 140-84237/15 2.0 1.75458 4.0 895394.0 0.87729 Y
8 IC 140-84237/7 4.0 3.354293 4.0 991861.0 0.838573 Y
9 IC 140-84237/5 8.0 7.028861 4.0 949158.0 0.878608 Y
10 IC 140-84237/3 16.0 13.848511 4.0 939128.0 0.865532 Y
RelResp = [0.8592]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 521 of 864
Calibration / 1,2,3-Trichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2478
Error Coefficients
Relative Standard Deviation:3.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.004865 4.0 961170.0 0.243245 Y
2 IC 140-84237/10 0.04 0.009371 4.0 910928.0 0.234267 Y
3 IC 140-84237/11 0.08 0.019085 4.0 872917.0 0.238568 Y
4 IC 140-84237/12 0.16 0.040576 4.0 876587.0 0.253597 Y
5 IC 140-84237/13 0.4 0.098635 4.0 856899.0 0.246587 Y
6 IC 140-84237/14 1.0 0.259123 4.0 865598.0 0.259123 Y
7 ICIS 140-84237/15 2.0 0.505762 4.0 895394.0 0.252881 Y
8 IC 140-84237/7 4.0 0.976782 4.0 991861.0 0.244196 Y
9 IC 140-84237/5 8.0 2.052253 4.0 949158.0 0.256532 Y
10 IC 140-84237/3 16.0 3.98269 4.0 939128.0 0.248918 Y
RelResp = [0.2478]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 522 of 864
Calibration / Isopropylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.551
Error Coefficients
Relative Standard Deviation:2.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.035748 4.0 961170.0 1.787405 N
2 IC 140-84237/10 0.04 0.062249 4.0 910928.0 1.556215 Y
3 IC 140-84237/11 0.08 0.118513 4.0 872917.0 1.481412 Y
4 IC 140-84237/12 0.16 0.245183 4.0 876587.0 1.532392 Y
5 IC 140-84237/13 0.4 0.599585 4.0 856899.0 1.498963 Y
6 IC 140-84237/14 1.0 1.597476 4.0 865598.0 1.597476 Y
7 ICIS 140-84237/15 2.0 3.193356 4.0 895394.0 1.596678 Y
8 IC 140-84237/7 4.0 6.238737 4.0 991861.0 1.559684 Y
9 IC 140-84237/5 8.0 12.856776 4.0 949158.0 1.607097 Y
10 IC 140-84237/3 16.0 24.495911 4.0 939128.0 1.530994 Y
RelResp = [1.551]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 523 of 864
Calibration / 4-Bromofluorobenzene (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7311
Error Coefficients
Relative Standard Deviation:2.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/3 4.08 3.10281 4.0 939128.0 0.760493 Y
2 IC 140-84237/5 4.08 3.035634 4.0 949158.0 0.744028 Y
3 IC 140-84237/7 4.08 2.999699 4.0 991861.0 0.73522 Y
4 IC 140-84237/9 4.08 2.930424 4.0 961170.0 0.718241 Y
5 IC 140-84237/10 4.08 2.933176 4.0 910928.0 0.718916 Y
6 IC 140-84237/11 4.08 2.933406 4.0 872917.0 0.718972 Y
7 IC 140-84237/12 4.08 2.95356 4.0 876587.0 0.723912 Y
8 IC 140-84237/13 4.08 2.925633 4.0 856899.0 0.717067 Y
9 IC 140-84237/14 4.08 2.985427 4.0 865598.0 0.731722 Y
10 ICIS 140-84237/15 4.08 3.029723 4.0 895394.0 0.742579 Y
RelResp = [0.7311]x
Concentration
0 1 2 3 4 5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/3IC 140-84237/5IC 140-84237/7IC 140-84237/14ICIS 140-84237/15
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Page 524 of 864
Calibration / N-Propylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4351
Error Coefficients
Relative Standard Deviation:4.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.008481 4.0 961170.0 0.424067 N
2 IC 140-84237/10 0.04 0.015119 4.0 910928.0 0.377966 N
3 IC 140-84237/11 0.08 0.0322 4.0 872917.0 0.402501 Y
4 IC 140-84237/12 0.16 0.065732 4.0 876587.0 0.410826 Y
5 IC 140-84237/13 0.4 0.170246 4.0 856899.0 0.425616 Y
6 IC 140-84237/14 1.0 0.450551 4.0 865598.0 0.450551 Y
7 ICIS 140-84237/15 2.0 0.90316 4.0 895394.0 0.45158 Y
8 IC 140-84237/7 4.0 1.765554 4.0 991861.0 0.441388 Y
9 IC 140-84237/5 8.0 3.666214 4.0 949158.0 0.458277 Y
10 IC 140-84237/3 16.0 7.045412 4.0 939128.0 0.440338 Y
RelResp = [0.4351]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 525 of 864
Calibration / 2-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3906
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.007915 4.0 961170.0 0.395768 Y
2 IC 140-84237/10 0.04 0.014047 4.0 910928.0 0.35118 Y
3 IC 140-84237/11 0.08 0.028965 4.0 872917.0 0.362062 Y
4 IC 140-84237/12 0.16 0.063556 4.0 876587.0 0.397222 Y
5 IC 140-84237/13 0.4 0.159613 4.0 856899.0 0.399032 Y
6 IC 140-84237/14 1.0 0.411794 4.0 865598.0 0.411794 Y
7 ICIS 140-84237/15 2.0 0.81473 4.0 895394.0 0.407365 Y
8 IC 140-84237/7 4.0 1.572866 4.0 991861.0 0.393216 Y
9 IC 140-84237/5 8.0 3.237092 4.0 949158.0 0.404637 Y
10 IC 140-84237/3 16.0 6.133933 4.0 939128.0 0.383371 Y
RelResp = [0.3906]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 526 of 864
Calibration / 4-Ethyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.587
Error Coefficients
Relative Standard Deviation:4.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.03167 4.0 961170.0 1.583487 Y
2 IC 140-84237/10 0.04 0.059271 4.0 910928.0 1.481786 Y
3 IC 140-84237/11 0.08 0.118673 4.0 872917.0 1.483417 Y
4 IC 140-84237/12 0.16 0.244676 4.0 876587.0 1.529226 Y
5 IC 140-84237/13 0.4 0.623798 4.0 856899.0 1.559495 Y
6 IC 140-84237/14 1.0 1.664754 4.0 865598.0 1.664754 Y
7 ICIS 140-84237/15 2.0 3.31744 4.0 895394.0 1.65872 Y
8 IC 140-84237/7 4.0 6.479331 4.0 991861.0 1.619833 Y
9 IC 140-84237/5 8.0 13.410699 4.0 949158.0 1.676337 Y
10 IC 140-84237/3 16.0 25.880872 4.0 939128.0 1.617555 Y
RelResp = [1.587]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 527 of 864
Calibration / 1,3,5-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6604
Error Coefficients
Relative Standard Deviation:2.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.012597 4.0 961170.0 0.629857 N
2 IC 140-84237/10 0.04 0.025051 4.0 910928.0 0.626284 N
3 IC 140-84237/11 0.08 0.047276 4.0 872917.0 0.59095 N
4 IC 140-84237/12 0.16 0.103533 4.0 876587.0 0.647084 Y
5 IC 140-84237/13 0.4 0.257813 4.0 856899.0 0.644533 Y
6 IC 140-84237/14 1.0 0.683856 4.0 865598.0 0.683856 Y
7 ICIS 140-84237/15 2.0 1.346996 4.0 895394.0 0.673498 Y
8 IC 140-84237/7 4.0 2.583112 4.0 991861.0 0.645778 Y
9 IC 140-84237/5 8.0 5.457953 4.0 949158.0 0.682244 Y
10 IC 140-84237/3 16.0 10.337232 4.0 939128.0 0.646077 Y
RelResp = [0.6604]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 528 of 864
Calibration / Alpha Methyl Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6517
Error Coefficients
Relative Standard Deviation:11.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.009701 4.0 961170.0 0.485034 N
2 IC 140-84237/10 0.04 0.018329 4.0 910928.0 0.458214 N
3 IC 140-84237/11 0.08 0.036315 4.0 872917.0 0.453938 N
4 IC 140-84237/12 0.16 0.084646 4.0 876587.0 0.52904 Y
5 IC 140-84237/13 0.4 0.233376 4.0 856899.0 0.583441 Y
6 IC 140-84237/14 1.0 0.665422 4.0 865598.0 0.665422 Y
7 ICIS 140-84237/15 2.0 1.30658 4.0 895394.0 0.65329 Y
8 IC 140-84237/7 4.0 2.693273 4.0 991861.0 0.673318 Y
9 IC 140-84237/5 8.0 6.018876 4.0 949158.0 0.752359 Y
10 IC 140-84237/3 16.0 11.285827 4.0 939128.0 0.705364 Y
RelResp = [0.6517]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5 IC 140-84237/3
3/25/2024
9:50:51 AM
Page 529 of 864
Calibration / n-Decane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8356
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.015402 4.0 961170.0 0.770103 N
2 IC 140-84237/10 0.04 0.028573 4.0 910928.0 0.714326 N
3 IC 140-84237/11 0.08 0.056606 4.0 872917.0 0.70757 N
4 IC 140-84237/12 0.16 0.124017 4.0 876587.0 0.775108 Y
5 IC 140-84237/13 0.4 0.32028 4.0 856899.0 0.800701 Y
6 IC 140-84237/14 1.0 0.850617 4.0 865598.0 0.850617 Y
7 ICIS 140-84237/15 2.0 1.668137 4.0 895394.0 0.834069 Y
8 IC 140-84237/7 4.0 3.404001 4.0 991861.0 0.851 Y
9 IC 140-84237/5 8.0 7.231631 4.0 949158.0 0.903954 Y
10 IC 140-84237/3 16.0 13.342173 4.0 939128.0 0.833886 Y
RelResp = [0.8356]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 530 of 864
Calibration / tert-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.429
Error Coefficients
Relative Standard Deviation:5.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.029997 4.0 961170.0 1.499839 Y
2 IC 140-84237/10 0.04 0.054406 4.0 910928.0 1.360151 Y
3 IC 140-84237/11 0.08 0.108945 4.0 872917.0 1.361813 Y
4 IC 140-84237/12 0.16 0.226734 4.0 876587.0 1.417087 Y
5 IC 140-84237/13 0.4 0.567115 4.0 856899.0 1.417787 Y
6 IC 140-84237/14 1.0 1.506732 4.0 865598.0 1.506732 Y
7 ICIS 140-84237/15 2.0 3.016009 4.0 895394.0 1.508004 Y
8 IC 140-84237/7 4.0 5.762642 4.0 991861.0 1.440661 Y
9 IC 140-84237/5 8.0 11.910978 4.0 949158.0 1.488872 Y
10 IC 140-84237/3 16.0 20.658841 4.0 939128.0 1.291178 Y
RelResp = [1.429]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 531 of 864
Calibration / 1,2,4-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.366
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.027841 4.0 961170.0 1.392053 Y
2 IC 140-84237/10 0.04 0.050454 4.0 910928.0 1.261351 Y
3 IC 140-84237/11 0.08 0.10395 4.0 872917.0 1.299379 Y
4 IC 140-84237/12 0.16 0.216225 4.0 876587.0 1.351406 Y
5 IC 140-84237/13 0.4 0.549008 4.0 856899.0 1.372519 Y
6 IC 140-84237/14 1.0 1.460752 4.0 865598.0 1.460752 Y
7 ICIS 140-84237/15 2.0 2.868592 4.0 895394.0 1.434296 Y
8 IC 140-84237/7 4.0 5.586206 4.0 991861.0 1.396552 Y
9 IC 140-84237/5 8.0 11.51284 4.0 949158.0 1.439105 Y
10 IC 140-84237/3 16.0 19.961598 4.0 939128.0 1.2476 Y
RelResp = [1.366]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 532 of 864
Calibration / sec-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.965
Error Coefficients
Relative Standard Deviation:5.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.039269 4.0 961170.0 1.96344 Y
2 IC 140-84237/10 0.04 0.073363 4.0 910928.0 1.834064 Y
3 IC 140-84237/11 0.08 0.147153 4.0 872917.0 1.839407 Y
4 IC 140-84237/12 0.16 0.30585 4.0 876587.0 1.911562 Y
5 IC 140-84237/13 0.4 0.771195 4.0 856899.0 1.927987 Y
6 IC 140-84237/14 1.0 2.090818 4.0 865598.0 2.090818 Y
7 ICIS 140-84237/15 2.0 4.15351 4.0 895394.0 2.076755 Y
8 IC 140-84237/7 4.0 8.034553 4.0 991861.0 2.008638 Y
9 IC 140-84237/5 8.0 16.818397 4.0 949158.0 2.1023 Y
10 IC 140-84237/3 16.0 30.287552 4.0 939128.0 1.892972 Y
RelResp = [1.965]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 533 of 864
Calibration / 1,3-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9543
Error Coefficients
Relative Standard Deviation:4.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.021124 4.0 961170.0 1.056213 N
2 IC 140-84237/10 0.04 0.038308 4.0 910928.0 0.957705 Y
3 IC 140-84237/11 0.08 0.077455 4.0 872917.0 0.968191 Y
4 IC 140-84237/12 0.16 0.155763 4.0 876587.0 0.97352 Y
5 IC 140-84237/13 0.4 0.389353 4.0 856899.0 0.973382 Y
6 IC 140-84237/14 1.0 1.003071 4.0 865598.0 1.003071 Y
7 ICIS 140-84237/15 2.0 1.951677 4.0 895394.0 0.975839 Y
8 IC 140-84237/7 4.0 3.646813 4.0 991861.0 0.911703 Y
9 IC 140-84237/5 8.0 7.671035 4.0 949158.0 0.958879 Y
10 IC 140-84237/3 16.0 13.860228 4.0 939128.0 0.866264 Y
RelResp = [0.9543]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 534 of 864
Calibration / Benzyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.109
Error Coefficients
Relative Standard Deviation:9.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.023962 4.0 961170.0 1.198123 Y
2 IC 140-84237/10 0.04 0.040596 4.0 910928.0 1.014899 Y
3 IC 140-84237/11 0.08 0.079361 4.0 872917.0 0.992019 Y
4 IC 140-84237/12 0.16 0.152304 4.0 876587.0 0.951902 Y
5 IC 140-84237/13 0.4 0.400607 4.0 856899.0 1.001518 Y
6 IC 140-84237/14 1.0 1.134268 4.0 865598.0 1.134268 Y
7 ICIS 140-84237/15 2.0 2.34803 4.0 895394.0 1.174015 Y
8 IC 140-84237/7 4.0 4.803572 4.0 991861.0 1.200893 Y
9 IC 140-84237/5 8.0 10.183464 4.0 949158.0 1.272933 Y
10 IC 140-84237/3 16.0 18.408911 4.0 939128.0 1.150557 Y
RelResp = [1.109]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 535 of 864
Calibration / 1,4-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9562
Error Coefficients
Relative Standard Deviation:5.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.022194 4.0 961170.0 1.109689 N
2 IC 140-84237/10 0.04 0.0406 4.0 910928.0 1.015009 Y
3 IC 140-84237/11 0.08 0.078523 4.0 872917.0 0.981537 Y
4 IC 140-84237/12 0.16 0.157146 4.0 876587.0 0.982161 Y
5 IC 140-84237/13 0.4 0.38089 4.0 856899.0 0.952224 Y
6 IC 140-84237/14 1.0 1.013427 4.0 865598.0 1.013427 Y
7 ICIS 140-84237/15 2.0 1.951297 4.0 895394.0 0.975649 Y
8 IC 140-84237/7 4.0 3.634009 4.0 991861.0 0.908502 Y
9 IC 140-84237/5 8.0 7.541834 4.0 949158.0 0.942729 Y
10 IC 140-84237/3 16.0 13.358426 4.0 939128.0 0.834902 Y
RelResp = [0.9562]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 536 of 864
Calibration / 4-Isopropyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.667
Error Coefficients
Relative Standard Deviation:5.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.032669 4.0 961170.0 1.633426 Y
2 IC 140-84237/10 0.04 0.061818 4.0 910928.0 1.545457 Y
3 IC 140-84237/11 0.08 0.125098 4.0 872917.0 1.563723 Y
4 IC 140-84237/12 0.16 0.262514 4.0 876587.0 1.64071 Y
5 IC 140-84237/13 0.4 0.678339 4.0 856899.0 1.695847 Y
6 IC 140-84237/14 1.0 1.817158 4.0 865598.0 1.817158 Y
7 ICIS 140-84237/15 2.0 3.519697 4.0 895394.0 1.759849 Y
8 IC 140-84237/7 4.0 6.782971 4.0 991861.0 1.695743 Y
9 IC 140-84237/5 8.0 14.060673 4.0 949158.0 1.757584 Y
10 IC 140-84237/3 16.0 24.933466 4.0 939128.0 1.558342 Y
RelResp = [1.667]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 537 of 864
Calibration / 1,2,3-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.386
Error Coefficients
Relative Standard Deviation:5.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.026863 4.0 961170.0 1.343155 Y
2 IC 140-84237/10 0.04 0.05196 4.0 910928.0 1.299005 Y
3 IC 140-84237/11 0.08 0.100862 4.0 872917.0 1.260773 Y
4 IC 140-84237/12 0.16 0.218484 4.0 876587.0 1.365523 Y
5 IC 140-84237/13 0.4 0.552775 4.0 856899.0 1.381936 Y
6 IC 140-84237/14 1.0 1.474652 4.0 865598.0 1.474652 Y
7 ICIS 140-84237/15 2.0 2.90408 4.0 895394.0 1.45204 Y
8 IC 140-84237/7 4.0 5.738042 4.0 991861.0 1.43451 Y
9 IC 140-84237/5 8.0 11.893712 4.0 949158.0 1.486714 Y
10 IC 140-84237/3 16.0 21.801258 4.0 939128.0 1.362579 Y
RelResp = [1.386]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 538 of 864
Calibration / 2,3-Dihydroindene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.323
Error Coefficients
Relative Standard Deviation:6.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.028149 4.0 961170.0 1.407451 Y
2 IC 140-84237/10 0.04 0.047661 4.0 910928.0 1.191532 Y
3 IC 140-84237/11 0.08 0.100161 4.0 872917.0 1.252009 Y
4 IC 140-84237/12 0.16 0.210471 4.0 876587.0 1.315443 Y
5 IC 140-84237/13 0.4 0.53555 4.0 856899.0 1.338874 Y
6 IC 140-84237/14 1.0 1.428501 4.0 865598.0 1.428501 Y
7 ICIS 140-84237/15 2.0 2.79141 4.0 895394.0 1.395705 Y
8 IC 140-84237/7 4.0 5.514079 4.0 991861.0 1.37852 Y
9 IC 140-84237/5 8.0 10.805282 4.0 949158.0 1.35066 Y
10 IC 140-84237/3 16.0 18.795018 4.0 939128.0 1.174689 Y
RelResp = [1.323]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 539 of 864
Calibration / 1,2-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9271
Error Coefficients
Relative Standard Deviation:6.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.020741 4.0 961170.0 1.037069 N
2 IC 140-84237/10 0.04 0.03721 4.0 910928.0 0.93026 Y
3 IC 140-84237/11 0.08 0.074999 4.0 872917.0 0.937489 Y
4 IC 140-84237/12 0.16 0.155042 4.0 876587.0 0.969014 Y
5 IC 140-84237/13 0.4 0.381576 4.0 856899.0 0.95394 Y
6 IC 140-84237/14 1.0 1.001435 4.0 865598.0 1.001435 Y
7 ICIS 140-84237/15 2.0 1.912097 4.0 895394.0 0.956048 Y
8 IC 140-84237/7 4.0 3.68002 4.0 991861.0 0.920005 Y
9 IC 140-84237/5 8.0 7.201174 4.0 949158.0 0.900147 Y
10 IC 140-84237/3 16.0 12.404456 4.0 939128.0 0.775279 Y
RelResp = [0.9271]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 540 of 864
Calibration / n-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.689
Error Coefficients
Relative Standard Deviation:5.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.034649 4.0 961170.0 1.732472 Y
2 IC 140-84237/10 0.04 0.062639 4.0 910928.0 1.565985 Y
3 IC 140-84237/11 0.08 0.133062 4.0 872917.0 1.663274 Y
4 IC 140-84237/12 0.16 0.268888 4.0 876587.0 1.680552 Y
5 IC 140-84237/13 0.4 0.686746 4.0 856899.0 1.716865 Y
6 IC 140-84237/14 1.0 1.815748 4.0 865598.0 1.815748 Y
7 ICIS 140-84237/15 2.0 3.519032 4.0 895394.0 1.759516 Y
8 IC 140-84237/7 4.0 6.957685 4.0 991861.0 1.739421 Y
9 IC 140-84237/5 8.0 13.686619 4.0 949158.0 1.710827 Y
10 IC 140-84237/3 16.0 24.124166 4.0 939128.0 1.50776 Y
RelResp = [1.689]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 541 of 864
Calibration / Indene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.079
Error Coefficients
Relative Standard Deviation:9.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.020051 4.0 961170.0 1.002528 Y
2 IC 140-84237/10 0.04 0.037153 4.0 910928.0 0.928833 Y
3 IC 140-84237/11 0.08 0.074784 4.0 872917.0 0.934797 Y
4 IC 140-84237/12 0.16 0.165912 4.0 876587.0 1.036948 Y
5 IC 140-84237/13 0.4 0.438343 4.0 856899.0 1.095858 Y
6 IC 140-84237/14 1.0 1.209384 4.0 865598.0 1.209384 Y
7 ICIS 140-84237/15 2.0 2.345618 4.0 895394.0 1.172809 Y
8 IC 140-84237/7 4.0 4.724122 4.0 991861.0 1.18103 Y
9 IC 140-84237/5 8.0 9.414525 4.0 949158.0 1.176816 Y
10 IC 140-84237/3 16.0 16.776627 4.0 939128.0 1.048539 Y
RelResp = [1.079]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 542 of 864
Calibration / Undecane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9846
Error Coefficients
Relative Standard Deviation:5.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.019247 4.0 961170.0 0.962369 Y
2 IC 140-84237/10 0.04 0.036424 4.0 910928.0 0.91061 Y
3 IC 140-84237/11 0.08 0.075384 4.0 872917.0 0.9423 Y
4 IC 140-84237/12 0.16 0.149982 4.0 876587.0 0.937386 Y
5 IC 140-84237/13 0.4 0.394217 4.0 856899.0 0.985542 Y
6 IC 140-84237/14 1.0 1.066093 4.0 865598.0 1.066093 Y
7 ICIS 140-84237/15 2.0 1.995568 4.0 895394.0 0.997784 Y
8 IC 140-84237/7 4.0 4.186167 4.0 991861.0 1.046542 Y
9 IC 140-84237/5 8.0 8.345759 4.0 949158.0 1.04322 Y
10 IC 140-84237/3 16.0 15.270281 4.0 939128.0 0.954393 Y
RelResp = [0.9846]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 543 of 864
Calibration / 1,2-Dibromo-3-Chloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4625
Error Coefficients
Relative Standard Deviation:24.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.006242 4.0 961170.0 0.31212 N
2 IC 140-84237/10 0.04 0.009696 4.0 910928.0 0.24239 N
3 IC 140-84237/11 0.08 0.018632 4.0 872917.0 0.232897 Y
4 IC 140-84237/12 0.16 0.073905 4.0 876587.0 0.461905 Y
5 IC 140-84237/13 0.4 0.190492 4.0 856899.0 0.476229 Y
6 IC 140-84237/14 1.0 0.521193 4.0 865598.0 0.521193 Y
7 ICIS 140-84237/15 2.0 1.102987 4.0 895394.0 0.551494 Y
8 IC 140-84237/7 4.0 1.430817 4.0 991861.0 0.357704 Y
9 IC 140-84237/5 8.0 4.646746 4.0 949158.0 0.580843 Y
10 IC 140-84237/3 16.0 8.285541 4.0 939128.0 0.517846 Y
RelResp = [0.4625]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
IC 140-84237/3
3/25/2024
9:50:51 AM
Page 544 of 864
Calibration / 1,2,4,5-Tetramethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.699
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.035885 4.0 961170.0 1.794272 Y
2 IC 140-84237/10 0.04 0.064216 4.0 910928.0 1.605396 Y
3 IC 140-84237/11 0.08 0.131779 4.0 872917.0 1.647236 Y
4 IC 140-84237/12 0.16 0.25665 4.0 876587.0 1.604062 Y
5 IC 140-84237/13 0.4 0.681028 4.0 856899.0 1.702569 Y
6 IC 140-84237/14 1.0 1.824759 4.0 865598.0 1.824759 Y
7 ICIS 140-84237/15 2.0 3.40571 4.0 895394.0 1.702855 Y
8 IC 140-84237/7 4.0 7.027711 4.0 991861.0 1.756928 Y
9 IC 140-84237/5 8.0 14.085111 4.0 949158.0 1.760639 Y
10 IC 140-84237/3 16.0 25.520623 4.0 939128.0 1.595039 Y
RelResp = [1.699]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 545 of 864
Calibration / Dodecane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.175
Error Coefficients
Relative Standard Deviation:13.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.03137 4.0 961170.0 1.568505 N
2 IC 140-84237/10 0.04 0.074913 4.0 910928.0 1.872815 N
3 IC 140-84237/11 0.08 0.136467 4.0 872917.0 1.705832 N
4 IC 140-84237/12 0.16 0.195727 4.0 876587.0 1.223296 Y
5 IC 140-84237/13 0.4 0.535559 4.0 856899.0 1.338898 Y
6 IC 140-84237/14 1.0 1.429781 4.0 865598.0 1.429781 Y
7 ICIS 140-84237/15 2.0 2.149074 4.0 895394.0 1.074537 Y
8 IC 140-84237/7 4.0 4.467194 4.0 991861.0 1.116799 Y
9 IC 140-84237/5 8.0 8.553295 4.0 949158.0 1.069162 Y
10 IC 140-84237/3 16.0 15.523843 4.0 939128.0 0.97024 Y
RelResp = [1.175]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 546 of 864
Calibration / 1,2,4-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8755
Error Coefficients
Relative Standard Deviation:13.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.030321 4.0 961170.0 1.516069 N
2 IC 140-84237/10 0.04 0.047104 4.0 910928.0 1.17759 N
3 IC 140-84237/11 0.08 0.085268 4.0 872917.0 1.065852 Y
4 IC 140-84237/12 0.16 0.147956 4.0 876587.0 0.924723 Y
5 IC 140-84237/13 0.4 0.369066 4.0 856899.0 0.922664 Y
6 IC 140-84237/14 1.0 0.976823 4.0 865598.0 0.976823 Y
7 ICIS 140-84237/15 2.0 1.649812 4.0 895394.0 0.824906 Y
8 IC 140-84237/7 4.0 3.22665 4.0 991861.0 0.806662 Y
9 IC 140-84237/5 8.0 6.211973 4.0 949158.0 0.776497 Y
10 IC 140-84237/3 16.0 11.292199 4.0 939128.0 0.705762 Y
RelResp = [0.8755]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 547 of 864
Calibration / Naphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.963
Error Coefficients
Relative Standard Deviation:12.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.067484 4.0 961170.0 3.374221 N
2 IC 140-84237/10 0.04 0.109111 4.0 910928.0 2.727768 N
3 IC 140-84237/11 0.08 0.196811 4.0 872917.0 2.460142 N
4 IC 140-84237/12 0.16 0.335392 4.0 876587.0 2.096198 Y
5 IC 140-84237/13 0.4 0.869741 4.0 856899.0 2.174352 Y
6 IC 140-84237/14 1.0 2.305357 4.0 865598.0 2.305357 Y
7 ICIS 140-84237/15 2.0 3.893674 4.0 895394.0 1.946837 Y
8 IC 140-84237/7 4.0 7.38547 4.0 991861.0 1.846368 Y
9 IC 140-84237/5 8.0 13.925635 4.0 949158.0 1.740704 Y
10 IC 140-84237/3 16.0 26.133971 4.0 939128.0 1.633373 Y
RelResp = [1.963]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
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Page 548 of 864
Calibration / Hexachlorobutadiene
Curve Type:Quadratic
Weighting:None
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8192
Second Order:-0.06697
Error Coefficients
Relative Standard Deviation:18.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.022473 4.0 961170.0 1.123631 N
2 IC 140-84237/10 0.04 0.045865 4.0 910928.0 1.146633 N
3 IC 140-84237/11 0.08 0.085626 4.0 872917.0 1.070319 Y
4 IC 140-84237/12 0.16 0.139564 4.0 876587.0 0.872275 Y
5 IC 140-84237/13 0.4 0.338644 4.0 856899.0 0.846611 Y
6 IC 140-84237/14 1.0 0.840547 4.0 865598.0 0.840547 Y
7 ICIS 140-84237/15 2.0 1.293151 4.0 895394.0 0.646576 Y
8 IC 140-84237/7 4.0 2.218601 4.0 991861.0 0.55465 Y
9 IC 140-84237/5 8.0 3.589716 4.0 949158.0 0.448715 N
10 IC 140-84237/3 16.0 5.829408 4.0 939128.0 0.364338 N
RelResp = [0.8192]x + [-0.06697]x^2
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 549 of 864
Calibration / 1,2,3-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6904
Error Coefficients
Relative Standard Deviation:24.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.02 0.029872 4.0 961170.0 1.493596 N
2 IC 140-84237/10 0.04 0.050516 4.0 910928.0 1.262888 N
3 IC 140-84237/11 0.08 0.086382 4.0 872917.0 1.07977 N
4 IC 140-84237/12 0.16 0.139117 4.0 876587.0 0.86948 N
5 IC 140-84237/13 0.4 0.34721 4.0 856899.0 0.868025 Y
6 IC 140-84237/14 1.0 0.894891 4.0 865598.0 0.894891 Y
7 ICIS 140-84237/15 2.0 1.421984 4.0 895394.0 0.710992 Y
8 IC 140-84237/7 4.0 2.526697 4.0 991861.0 0.631674 Y
9 IC 140-84237/5 8.0 4.330124 4.0 949158.0 0.541266 Y
10 IC 140-84237/3 16.0 7.928104 4.0 939128.0 0.495506 Y
RelResp = [0.6904]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 550 of 864
Calibration / 2-Methylnaphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.1
Error Coefficients
Relative Standard Deviation:17.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.020001 0.036855 4.0 961170.0 1.842662 N
2 IC 140-84237/10 0.040002 0.05517 4.0 910928.0 1.379184 N
3 IC 140-84237/11 0.080004 0.098653 4.0 872917.0 1.233103 N
4 IC 140-84237/12 0.160008 0.170735 4.0 876587.0 1.06704 Y
5 IC 140-84237/13 0.40002 0.484888 4.0 856899.0 1.212159 Y
6 IC 140-84237/14 1.00005 1.432887 4.0 865598.0 1.432815 Y
7 ICIS 140-84237/15 2.0001 2.314967 4.0 895394.0 1.157426 Y
8 IC 140-84237/7 4.000199 4.232274 4.0 991861.0 1.058016 Y
9 IC 140-84237/5 8.000399 7.655311 4.0 949158.0 0.956866 Y
10 IC 140-84237/3 16.000797 13.066087 4.0 939128.0 0.81659 Y
RelResp = [1.1]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 551 of 864
Calibration / 1-Methylnaphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.159
Error Coefficients
Relative Standard Deviation:25.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-84237/9 0.020001 0.038532 4.0 961170.0 1.926514 N
2 IC 140-84237/10 0.040002 0.063733 4.0 910928.0 1.593241 N
3 IC 140-84237/11 0.080004 0.124498 4.0 872917.0 1.556141 N
4 IC 140-84237/12 0.160008 0.201673 4.0 876587.0 1.260394 N
5 IC 140-84237/13 0.40002 0.574532 4.0 856899.0 1.436259 Y
6 IC 140-84237/14 1.00005 1.565544 4.0 865598.0 1.565466 Y
7 ICIS 140-84237/15 2.0001 2.378716 4.0 895394.0 1.189299 Y
8 IC 140-84237/7 4.000199 4.232359 4.0 991861.0 1.058037 Y
9 IC 140-84237/5 8.000399 7.358627 4.0 949158.0 0.919783 Y
10 IC 140-84237/3 16.000797 12.591757 4.0 939128.0 0.786946 Y
RelResp = [1.159]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-84237/9
IC 140-84237/10
IC 140-84237/11
IC 140-84237/12
IC 140-84237/13
IC 140-84237/14
ICIS 140-84237/15
IC 140-84237/7
IC 140-84237/5
3/25/2024
9:50:51 AM
Page 552 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
Calibration Files
LEVEL:LAB SAMPLE ID:LAB FILE ID:
1Level IC 140-83168/9 SZB07IC01.D
2Level IC 140-83168/10 SZB07IC02.D
3Level IC 140-83168/11 SZB07IC03.D
4Level IC 140-83168/12 SZB07IC04.D
5Level IC 140-83168/13 SZB07IC05.D
6Level IC 140-83168/14 SZB07IC06.D
7Level ICIS 140-83168/15 SZB07ICIS07.D
8Level IC 140-83168/7 SZB07IC08.D
9Level IC 140-83168/5 SZB07IC09.D
10Level IC 140-83168/3 SZB07IC10.D
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Chlorodifluoromethane ++++++++++1.9735 1.8644 1.7917 Ave 8.5
1.7746 1.7439 1.6366 1.6323 1.5013
30.01.739
8
Propene ++++++++++++++++++++0.8649 Ave 6.0
0.8849 0.8785 0.8299 0.8220 0.7500
30.00.838
4
Dichlorodifluoromethane 3.1900 2.7599 2.4564 2.5819 2.4937 Ave 11.9
2.6155 2.4866 2.2859 2.3171 2.0737
30.02.526
1
Chloromethane +++++++++++++++0.1762 0.1916 Ave 15.1
0.1669 0.1573 0.1429 0.1403 0.1221
30.00.156
8
1,2-Dichloro-1,1,2,2-tetrafluoroet
hane
2.1018 1.8977 1.5666 1.6356 1.5553 Ave 16.2
1.6460 1.5529 1.3934 1.3831 1.1956
30.01.592
8
Vinyl chloride +++++0.5712 0.5513 0.5236 0.5314 Ave 9.6
0.5096 0.5164 0.4627 0.4649 0.4181
30.00.505
5
Butane ++++++++++0.7578 0.7448 0.7100 Ave 10.2
0.7107 0.6891 0.6261 0.6216 0.5570
30.00.677
1
1,3-Butadiene ++++++++++0.4359 0.4407 0.3953 Ave 13.4
0.3819 0.3726 0.3398 0.3312 0.2976
30.00.374
4
Bromomethane +++++0.6675 0.6454 0.5881 0.5682 Ave 13.6
0.5258 0.5355 0.4820 0.4857 0.4465
30.00.549
4
Chloroethane ++++++++++0.2706 0.2560 0.2273 Ave 13.6
0.2220 0.2130 0.1962 0.1978 0.1834
30.00.220
8
Ethanol +++++++++++++++0.2683 0.2440 Ave 11.6
0.2210 0.2390 0.2120 0.2051 0.1920
30.00.225
9
Vinyl bromide ++++++++++0.9577 0.9702 0.9560 Ave 3.8
0.9327 0.9533 0.9064 0.9266 0.8618
30.00.933
1
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 553 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
2-Methylbutane ++++++++++1.0453 1.0111 1.0021 Ave 6.6
0.9689 1.0001 0.9167 0.9272 0.8480
30.00.964
9
Trichlorofluoromethane 3.2611 2.9159 2.9155 2.9445 2.9149 Ave 6.7
2.9266 2.9489 2.7179 2.7227 2.5233
30.02.879
1
Acrolein +++++++++++++++0.3747 0.3196 Ave 11.5
0.2966 0.3043 0.2870 0.2851 0.2655
30.00.304
7
Acetonitrile +++++++++++++++0.3715 0.3607 Ave 4.9
0.3454 0.3959 0.3599 0.3615 0.3423
30.00.362
5
Acetone ++++++++++++++++++++0.4313 Ave 9.8
0.4113 0.4454 0.3803 0.3743 0.3415
30.00.397
4
Pentane +++++0.1715 0.1564 0.1716 0.1594 Ave 7.3
0.1596 0.1632 0.1522 0.1516 0.1335
30.00.157
7
Isopropyl alcohol +++++1.2779 1.1965 1.2076 1.1470 QuaF 1.0000
1.1535 1.2273 1.1143 1.1096 0.9618
0.99001.225
5
-0.005467
Ethyl ether +++++1.0088 1.0297 1.0581 1.0492 Ave 4.3
1.0262 1.0447 0.9742 0.9804 0.9261
30.01.010
8
1,1-Dichloroethene +++++1.1063 1.0711 1.0639 1.0074 Ave 5.5
1.0090 1.0183 0.9699 0.9813 0.9241
30.01.016
8
Acrylonitrile ++++++++++0.6520 0.7071 0.6823 Ave 5.6
0.6489 0.6519 0.6160 0.6266 0.5943
30.00.647
4
tert-Butyl alcohol ++++++++++1.7578 1.7860 1.6750 Ave 4.0
1.7098 1.8115 1.6834 1.7097 1.5992
30.01.716
6
1,1,2-Trichloro-1,2,2-trifluoroeth
ane
2.5566 2.2982 2.2706 2.3150 2.2594 Ave 6.7
2.2595 2.2827 2.1383 2.1425 1.9742
30.02.249
7
Methylene Chloride ++++++++++1.3828 1.1340 0.9422 Ave 20.9
0.9075 0.8886 0.8323 0.8325 0.7769
30.00.962
1
3-Chloropropene +++++1.0277 1.2750 0.9524 0.8825 Ave 15.9
0.8479 0.8794 0.9178 0.8300 0.7695
30.00.931
4
Carbon disulfide ++++++++++3.1122 2.9497 2.7701 Ave 7.1
2.7050 2.7116 2.5895 2.6429 2.5178
30.02.749
8
trans-1,2-Dichloroethene +++++1.1739 1.1355 1.0623 1.0395 Ave 7.6
1.0555 1.0438 0.9924 0.9884 0.9081
30.01.044
4
2-Methylpentane ++++++++++2.0729 2.0942 2.0305 Ave 7.1
2.0961 2.0561 1.9145 1.8883 1.6957
30.01.981
0
Methyl tert-butyl ether ++++++++++2.8757 2.8749 2.8291 Ave 2.5
2.8565 2.8482 2.7601 2.7816 2.6740
30.02.812
5
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 554 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
1,1-Dichloroethane 1.8980 1.9441 1.8304 1.9032 1.7948 Ave 5.1
1.8247 1.8050 1.7108 1.7431 1.6480
30.01.810
2
Vinyl acetate +++++2.1718 2.1970 2.3273 2.1029 Ave 3.8
2.1027 2.0677 2.1346 2.2495 2.2065
30.02.173
3
2-Butanone (MEK)+++++0.4585 0.4793 0.4855 0.4649 Ave 3.5
0.4728 0.4935 0.4609 0.4693 0.4376
30.00.469
1
Hexane ++++++++++0.8248 0.7957 0.7612 Ave 6.2
0.7790 0.7610 0.7278 0.7322 0.6702
30.00.756
5
cis-1,2-Dichloroethene +++++1.1229 1.1446 1.1266 1.0911 Ave 2.6
1.1153 1.1068 1.0778 1.0935 1.0492
30.01.103
1
Ethyl acetate ++++++++++2.3155 2.2465 2.1077 Ave 4.0
2.1989 2.1728 2.0922 2.1439 2.0470
30.02.165
5
Chloroform ++++++++++2.2469 2.3102 2.2711 Ave 3.8
2.2752 2.2632 2.1488 2.1698 2.0563
30.02.217
7
Tetrahydrofuran ++++++++++1.0775 1.0912 1.0712 Ave 2.4
1.0762 1.0936 1.0345 1.0611 1.0232
30.01.066
1
1,1,1-Trichloroethane 2.7873 2.5684 2.4857 2.5913 2.4648 Ave 4.8
2.4976 2.5094 2.4094 2.4460 2.3443
30.02.510
4
1,2-Dichloroethane 0.3390 0.3389 0.3063 0.3201 0.3155 Ave 6.2
0.3195 0.3196 0.3005 0.2944 0.2764
30.00.313
0
1-Butanol ++++++++++0.0902 0.0883 0.0774 Ave 5.0
0.0824 0.0884 0.0871 0.0873 0.0824
30.00.085
4
Cyclohexane ++++++++++0.1050 0.1138 0.1021 Ave 10.6
0.1035 0.1015 0.0972 0.0919 0.0784
30.00.099
2
Benzene ++++++++++0.7167 0.6999 0.6639 Ave 10.4
0.6671 0.6540 0.6217 0.5922 0.5086
30.00.640
5
Carbon tetrachloride 0.6233 0.5683 0.5684 0.4763 0.5663 QuaF 1.0000
0.5419 0.5940 0.5719 0.5611 0.5055
0.99000.605
7
-0.006232
2,3-Dimethylpentane ++++++++++0.1537 0.1595 0.1491 Ave 6.7
0.1496 0.1497 0.1435 0.1386 0.1278
30.00.146
4
Thiophene ++++++++++0.3699 0.3857 0.3832 Ave 3.1
0.3911 0.3897 0.3823 0.3794 0.3556
30.00.379
6
2,2,4-Trimethylpentane ++++++++++0.9888 1.0143 0.9993 Ave 5.1
1.0081 1.0010 0.9683 0.9485 0.8620
30.00.973
8
Heptane ++++++++++0.2050 0.2144 0.2159 Ave 4.5
0.2239 0.2225 0.2151 0.2120 0.1939
30.00.212
8
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 555 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
1,2-Dichloropropane +++++0.2500 0.2353 0.2521 0.2417 Ave 6.7
0.2452 0.2395 0.2294 0.2226 0.2012
30.00.235
2
Trichloroethene 0.4133 0.3649 0.3639 0.3786 0.3644 Ave 6.7
0.3726 0.3651 0.3544 0.3446 0.3169
30.00.363
9
Dibromomethane +++++0.3753 0.3454 0.2941 0.2855 Ave 12.7
0.2886 0.2855 0.2889 0.2707 0.2533
30.00.298
6
Bromodichloromethane 0.5129 0.4816 0.4646 0.4993 0.5015 Ave 4.0
0.5137 0.5142 0.4957 0.4939 0.4591
30.00.493
6
1,4-Dioxane +++++++++++++++0.1082 0.0961 Ave 7.2
0.0994 0.1079 0.0991 0.0972 0.0874
30.00.099
3
Methyl methacrylate +++++++++++++++0.3203 0.2890 Ave 5.5
0.2864 0.2888 0.2845 0.2837 0.2676
30.00.288
6
Methylcyclohexane ++++++++++0.3903 0.4116 0.4053 QuaF 1.0000
0.4147 0.4095 0.4039 0.3975 0.3691
0.99000.421
0
-0.003232
4-Methyl-2-pentanone (MIBK)++++++++++0.4997 0.5067 0.4918 Ave 3.6
0.4960 0.5058 0.4879 0.4831 0.4512
30.00.490
3
cis-1,3-Dichloropropene 0.4026 0.3788 0.3457 0.3679 0.3733 Ave 4.2
0.3857 0.3914 0.3869 0.3885 0.3675
30.00.378
8
trans-1,3-Dichloropropene 0.4179 0.3889 0.3840 0.4023 0.3887 Ave 4.1
0.4134 0.4272 0.4211 0.4298 0.4155
30.00.408
9
Toluene ++++++++++1.0462 1.0004 0.9748 Ave 4.4
0.9910 0.9755 0.9618 0.9544 0.8950
30.00.974
9
1,1,2-Trichloroethane 0.3112 0.2922 0.2891 0.2872 0.2789 Ave 5.6
0.2840 0.2808 0.2733 0.2696 0.2511
30.00.281
7
2-Hexanone +++++++++++++++0.2902 0.2822 Ave 2.9
0.2941 0.3014 0.2903 0.2975 0.2769
30.00.290
4
Octane +++++0.3036 0.2802 0.2954 0.2959 Ave 4.7
0.3010 0.3001 0.2914 0.2859 0.2603
30.00.290
4
C8 Range ++++++++++++++++++++2.2386 Ave 7.8
2.2761 2.2471 2.1224 2.0436 1.8418
30.02.128
3
Dibromochloromethane ++++++++++0.5440 0.6380 0.6580 Ave 8.4
0.6921 0.7150 0.6851 0.7193 0.6774
30.00.666
1
1,2-Dibromoethane (EDB)+++++0.5619 0.5376 0.5448 0.5540 Ave 2.3
0.5627 0.5666 0.5594 0.5564 0.5298
30.00.552
6
Tetrachloroethene 0.4515 0.4235 0.4120 0.4065 0.4093 Ave 6.2
0.4135 0.4029 0.3903 0.3842 0.3565
30.00.405
0
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 556 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Chlorobenzene +++++0.8612 0.8422 0.8675 0.8353 Ave 5.4
0.8381 0.8270 0.8109 0.7883 0.7225
30.00.821
4
Ethylbenzene +++++1.3425 1.2934 1.3138 1.2786 Ave 3.2
1.3133 1.3080 1.2936 1.2784 1.1963
30.01.290
9
m-Xylene & p-Xylene +++++1.0446 1.0017 1.0372 1.0041 Ave 6.2
1.0162 1.0064 0.9784 0.9393 0.8456
30.00.985
9
Nonane ++++++++++0.5629 0.5773 0.5694 Ave 6.6
0.5788 0.5792 0.5505 0.5308 0.4723
30.00.552
7
Styrene 0.8321 0.7546 0.7250 0.7695 0.7724 Ave 6.4
0.8075 0.8047 0.8038 0.7481 0.6634
30.00.768
1
Bromoform ++++++++++0.4227 0.6691 0.6986 Lin2 0.9950
0.7619 0.7992 0.6909 0.8039 0.7189
0.9900-0.02
5
0.769
1
o-Xylene 1.3865 1.1906 1.0980 1.1592 1.0780 Ave 9.7
1.0934 1.0794 1.0506 1.0565 1.0003
30.01.119
2
1,1,2,2-Tetrachloroethane 0.8996 0.7836 0.7722 0.7839 0.7725 Ave 6.4
0.7865 0.7906 0.7580 0.7413 0.7026
30.00.779
1
1,2,3-Trichloropropane 0.2961 0.2425 0.2361 0.2525 0.2425 Ave 7.7
0.2487 0.2458 0.2374 0.2343 0.2271
30.00.246
3
Isopropylbenzene 2.0679 1.7509 1.6595 1.6532 1.6434 Ave 9.3
1.6532 1.6345 1.5967 1.5713 1.4879
30.01.671
9
Propylbenzene 0.5587 0.4659 0.4613 0.4851 0.4824 Ave 6.3
0.4912 0.4910 0.4797 0.4686 0.4450
30.00.482
9
2-Chlorotoluene 0.5072 0.4574 0.4674 0.4760 0.4527 Ave 5.7
0.4653 0.4519 0.4384 0.4301 0.4122
30.00.455
9
4-Ethyltoluene 2.0141 1.7056 1.6733 1.7235 1.7075 Ave 6.7
1.7388 1.7240 1.6706 1.6554 1.5655
30.01.717
8
1,3,5-Trimethylbenzene 0.8371 0.7471 0.7386 0.7688 0.7352 Ave 5.6
0.7581 0.7425 0.7230 0.7120 0.6748
30.00.743
7
Alpha Methyl Styrene +++++++++++++++0.7129 0.7108 Ave 3.6
0.7651 0.7551 0.7590 0.7497 0.7032
30.00.736
5
Decane 0.9907 0.8749 0.9127 0.9319 0.9194 Ave 12.5
0.9039 0.8593 0.8025 0.7369 0.6279
30.00.856
0
tert-Butylbenzene 1.8932 1.6920 1.6206 1.6849 1.6162 Ave 9.7
1.6406 1.5993 1.5374 1.4658 1.2979
30.01.604
8
1,2,4-Trimethylbenzene 1.6862 1.4825 1.4427 1.5279 1.4660 Ave 9.6
1.4656 1.4303 1.3761 1.3108 1.1599
30.01.434
8
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 557 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
sec-Butylbenzene 2.4723 2.2261 2.1688 2.2410 2.1568 Ave 8.2
2.1923 2.1334 2.0647 2.0001 1.7887
30.02.144
4
1,3-Dichlorobenzene 1.3817 1.1770 1.0983 1.1580 1.1180 Ave 9.1
1.1266 1.0978 1.0701 1.0610 0.9959
30.01.128
4
Benzyl chloride +++++++++++++++0.8241 0.8692 Ave 10.9
1.0124 1.0816 1.0834 1.0898 1.0369
30.00.999
6
1,4-Dichlorobenzene 1.3206 1.0943 1.1279 1.1598 1.0998 Ave 8.3
1.1134 1.0887 1.0622 1.0467 0.9624
30.01.107
6
4-Isopropyltoluene 2.1618 1.9910 1.9084 2.0229 1.9309 Ave 6.6
1.9498 1.9059 1.8633 1.8181 1.6800
30.01.923
2
1,2,3-Trimethylbenzene ++++++++++1.4948 1.5566 1.5039 Ave 4.4
1.5169 1.4732 1.4350 1.4177 1.3497
30.01.468
5
Indane 1.7456 1.5064 1.4549 1.5273 1.4626 Ave 10.9
1.4883 1.4285 1.3865 1.3108 1.1328
30.01.444
4
1,2-Dichlorobenzene 1.3774 1.2122 1.0909 1.1691 1.1018 Ave 12.2
1.1076 1.0702 1.0389 0.9891 0.8729
30.01.103
0
Butylbenzene 2.2080 1.7860 1.7315 1.8788 1.7262 Ave 13.4
1.7356 1.6638 1.6132 1.5231 1.3265
30.01.719
3
Indene 1.4984 1.2413 1.1775 1.2956 1.2501 Ave 8.5
1.2911 1.2562 1.2434 1.1984 1.0803
30.01.253
2
Undecane ++++++++++1.2816 1.3316 1.1495 Ave 18.5
1.1659 1.0244 0.9709 0.8827 0.7547
30.01.070
2
1,2-Dibromo-3-Chloropropane 0.6074 0.5047 0.4433 0.5637 0.5393 Ave 9.3
0.5825 0.6064 0.5369 0.5978 0.5814
30.00.556
3
1,2,4,5-Tetramethylbenzene ++++++++++2.1439 2.2501 1.9477 Ave 10.8
1.9659 1.8411 1.7958 1.7337 1.6316
30.01.913
7
Dodecane ++++++++++++++++++++1.2066 Ave 29.5
1.2284 0.8907 0.8251 0.6954 0.5758
30.00.903
7
1,2,4-Trichlorobenzene ++++++++++0.7031 0.7280 0.6087 Ave 8.1
0.6576 0.5969 0.6219 0.6144 0.5863
30.00.639
6
Naphthalene +++++1.6066 1.4365 1.4404 1.1462 Ave 19.0
1.2329 1.0649 1.0606 0.9862 0.9544
30.01.214
3
Hexachlorobutadiene ++++++++++1.1744 1.2026 0.8722 Ave 28.9
0.8230 0.6509 0.5954 ++++++++++
30.00.886
4
1,2,3-Trichlorobenzene ++++++++++++++++++++0.5373 Ave 12.5
0.5536 0.4576 0.4567 0.4234 0.4105
30.00.473
2
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 558 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
2-Methylnaphthalene ++++++++++++++++++++0.4317 Ave 8.2
0.5302 0.4603 0.5169 0.4965 0.5318
50.00.494
6
1-Methylnaphthalene ++++++++++++++++++++0.5560 Ave 8.6
0.6346 0.5145 0.5466 0.5042 0.5277
50.00.547
3
4-Bromofluorobenzene (Surr)0.6975 0.7045 0.7080 0.7097 0.7118 Ave 2.1
0.7183 0.7200 0.7114 0.7202 0.7543
30.00.715
6
FORM VI TO-15
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
3/25/2024
9:50:51 AM
Page 559 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
GC Column:RTX-5 ID:0.32(mm)
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
Level 1 IC 140-83168/9 SZB07IC01.D
Level 2 IC 140-83168/10 SZB07IC02.D
Level 3 IC 140-83168/11 SZB07IC03.D
Level 4 IC 140-83168/12 SZB07IC04.D
Level 5 IC 140-83168/13 SZB07IC05.D
Level 6 IC 140-83168/14 SZB07IC06.D
Level 7 ICIS 140-83168/15 SZB07ICIS07.D
Level 8 IC 140-83168/7 SZB07IC08.D
Level 9 IC 140-83168/5 SZB07IC09.D
Level 10 IC 140-83168/3 SZB07IC10.D
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Chlorodifluoromethane AveCBM ++++++++++13542 24831 60826 ++++++++++0.0800 0.160 0.400
151349 16.08.004.002.001.0020494151179990595275293647
Propene AveCBM ++++++++++++++++++++29363 ++++++++++++++++++++0.400
75475 16.08.004.002.001.001023843594254301873147919
Dichlorodifluoromethane AveCBM 5696 9625 16856 34386 84656 0.0200 0.0400 0.0800 0.160 0.400
223071 16.08.004.002.001.0028307721675055831446418690
Chloromethane AveCBM +++++++++++++++2347 6506 +++++++++++++++0.160 0.400
14235 16.08.004.002.001.001667341014285196726484
1,2-Dichloro-1,1,2,2-tetrafluoroeth
ane
AveCBM 3753 6618 10750 21784 52799 0.0200 0.0400 0.0800 0.160 0.400
140382 16.08.004.002.001.001632096999855506815261484
Vinyl chloride AveCBM +++++1992 3783 6974 18039 +++++0.0400 0.0800 0.160 0.400
43466 16.08.004.002.001.0057070933604516830286960
Butane AveCBM ++++++++++5200 9920 24103 ++++++++++0.0800 0.160 0.400
60611 16.08.004.002.001.00760387449361227720116024
1,3-Butadiene AveCBM ++++++++++2991 5869 13420 ++++++++++0.0800 0.160 0.400
32572 16.08.004.002.001.0040624023944612359762741
Bromomethane AveCBM +++++2328 4429 7832 19290 +++++0.0400 0.0800 0.160 0.400
44844 16.08.004.002.001.0060947335110817531190169
Chloroethane AveCBM ++++++++++1857 3409 7715 ++++++++++0.0800 0.160 0.400
18934 16.08.004.002.001.002503041429997136535871
Ethanol AveCBM +++++++++++++++17869 41420 +++++++++++++++0.800 2.00
94248 80.040.020.010.05.001310416741499385470201240
Vinyl bromide AveCBM ++++++++++6572 12922 32456 ++++++++++0.0800 0.160 0.400
79549 16.08.004.002.001.001176477669860329700160523
2-Methylbutane AveCBM ++++++++++7173 13466 34019 ++++++++++0.0800 0.160 0.400
82638 16.08.004.002.001.001157607670269333424168397
Trichlorofluoromethane AveCBM 5823 10169 20006 39216 98958 0.0200 0.0400 0.0800 0.160 0.400
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 560 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
249608 16.08.004.002.001.0034445461968227988585496544
Acrolein AveCBM +++++++++++++++4990 10849 +++++++++++++++0.160 0.400
25294 16.08.004.002.001.0036246820610610439851231
Acetonitrile AveCBM +++++++++++++++4948 12246 +++++++++++++++0.160 0.400
29456 16.08.004.002.001.0046726926134113089466661
Acetone AveCBM ++++++++++++++++++++43930 ++++++++++++++++++++1.20
105236 48.024.012.06.003.001398416811755415025225001
Pentane AveCBM +++++598 1073 2285 5411 +++++0.0400 0.0800 0.160 0.400
13609 16.08.004.002.001.001822251095895536627481
Isopropyl alcohol QuaFCBM +++++13370 24631 48250 116819 +++++0.120 0.240 0.480 1.20
295127 48.024.012.06.003.00393868224062801215864619975
Ethyl ether AveCBM +++++3518 7066 14092 35618 +++++0.0400 0.0800 0.160 0.400
87526 16.08.004.002.001.001264182708742354359175916
1,1-Dichloroethene AveCBM +++++3858 7350 14169 34201 +++++0.0400 0.0800 0.160 0.400
86054 16.08.004.002.001.001261471709385352773171462
Acrylonitrile AveCBM ++++++++++4474 9418 23164 ++++++++++0.0800 0.160 0.400
55343 16.08.004.002.001.00811257453002224041109774
tert-Butyl alcohol AveCBM ++++++++++12062 23787 56864 ++++++++++0.0800 0.160 0.400
145822 16.08.004.002.001.0021829761235957612317305031
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
AveCBM 4565 8015 15581 30832 76702 0.0200 0.0400 0.0800 0.160 0.400
192705 16.08.004.002.001.0026949331548800777778384360
Methylene Chloride AveCBM ++++++++++9489 15103 31986 ++++++++++0.0800 0.160 0.400
77399 16.08.004.002.001.001060527601817302732149625
3-Chloropropene AveCBM +++++3584 8749 12685 29961 +++++0.0400 0.0800 0.160 0.400
72318 16.08.004.002.001.001050373600033333820148068
Carbon disulfide AveCBM ++++++++++21356 39285 94041 ++++++++++0.0800 0.160 0.400
230702 16.08.004.002.001.0034370321910524941866456585
trans-1,2-Dichloroethene AveCBM +++++4094 7792 14148 35290 +++++0.0400 0.0800 0.160 0.400
90019 16.08.004.002.001.001239613714516360978175753
2-Methylpentane AveCBM ++++++++++14224 27891 68934 ++++++++++0.0800 0.160 0.400
178770 16.08.004.002.001.0023147221365036696345346205
Methyl tert-butyl ether AveCBM ++++++++++19733 38289 96044 ++++++++++0.0800 0.160 0.400
243624 16.08.004.002.001.00365025820108371003940479589
1,1-Dichloroethane AveCBM 3389 6780 12560 25347 60930 0.0200 0.0400 0.0800 0.160 0.400
155626 16.08.004.002.001.0022496481260105622265303927
Vinyl acetate AveCBM +++++7574 15076 30996 71389 +++++0.0400 0.0800 0.160 0.400
179333 16.08.004.002.001.0030120061626186776400348171
2-Butanone (MEK)AveCBM +++++1599 3289 6466 15783 +++++0.0400 0.0800 0.160 0.400
40324 16.08.004.002.001.0059739733922116765183098
Hexane AveCBM ++++++++++5660 10598 25843 ++++++++++0.0800 0.160 0.400
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 561 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
66443 16.08.004.002.001.00914848529332264713128146
cis-1,2-Dichloroethene AveCBM +++++3916 7854 15004 37041 +++++0.0400 0.0800 0.160 0.400
95118 16.08.004.002.001.001432192790501392034186370
Ethyl acetate AveCBM ++++++++++15889 29919 71552 ++++++++++0.0800 0.160 0.400
187536 16.08.004.002.001.0027942841549822760999365858
Chloroform AveCBM ++++++++++15418 30768 77102 ++++++++++0.0800 0.160 0.400
194044 16.08.004.002.001.0028070391568552781572381086
Tetrahydrofuran AveCBM ++++++++++7394 14533 36364 ++++++++++0.0800 0.160 0.400
91791 16.08.004.002.001.001396797767079376264184147
1,1,1-Trichloroethane AveCBM 4977 8957 17057 34512 83677 0.0200 0.0400 0.0800 0.160 0.400
213015 16.08.004.002.001.0032001411768181876380422532
1,2-Dichloroethane AveDFBZ 2834 5523 9837 20018 50065 0.0200 0.0400 0.0800 0.160 0.400
126982 16.08.004.002.001.0018398581019330508423252465
1-Butanol AveDFBZ ++++++++++2896 5524 12281 ++++++++++0.0800 0.160 0.400
32764 16.08.004.002.001.0054848930222514731669839
Cyclohexane AveDFBZ ++++++++++3371 7113 16197 ++++++++++0.0800 0.160 0.400
41133 16.08.004.002.001.0052180431818816446580186
Benzene AveDFBZ ++++++++++23020 43763 105344 ++++++++++0.0800 0.160 0.400
265147 16.08.004.002.001.00338532420502411051677516547
Carbon tetrachloride QuaFDFBZ 5210 9263 18255 29779 89861 0.0200 0.0400 0.0800 0.160 0.400
215381 16.08.004.002.001.0033646161942721967415469149
2,3-Dimethylpentane AveDFBZ ++++++++++4935 9972 23656 ++++++++++0.0800 0.160 0.400
59461 16.08.004.002.001.00850504479863242710118272
Thiophene AveDFBZ ++++++++++11881 24114 60808 ++++++++++0.0800 0.160 0.400
155457 16.08.004.002.001.0023665171313658646678307792
2,2,4-Trimethylpentane AveDFBZ ++++++++++31759 63422 158578 ++++++++++0.0800 0.160 0.400
400717 16.08.004.002.001.00573741532840181638057790653
Heptane AveDFBZ ++++++++++6585 13404 34257 ++++++++++0.0800 0.160 0.400
88988 16.08.004.002.001.001290320733825363911175717
1,2-Dichloropropane AveDFBZ +++++4075 7558 15761 38347 +++++0.0400 0.0800 0.160 0.400
97480 16.08.004.002.001.001338926770726388083189149
Trichloroethene AveDFBZ 3455 5947 11687 23673 57824 0.0200 0.0400 0.0800 0.160 0.400
148108 16.08.004.002.001.0021094201193105599447288347
Dibromomethane AveDFBZ +++++6117 11095 18387 45309 +++++0.0400 0.0800 0.160 0.400
114700 16.08.004.002.001.001686233937051488720225525
Bromodichloromethane AveDFBZ 4287 7849 14923 31217 79573 0.0200 0.0400 0.0800 0.160 0.400
204189 16.08.004.002.001.0030556951709852838624406154
1,4-Dioxane AveDFBZ +++++++++++++++6765 15243 +++++++++++++++0.160 0.400
39495 16.08.004.002.001.0058165933651716771585223
Methyl methacrylate AveDFBZ +++++++++++++++20029 45867 +++++++++++++++0.160 0.400
113837 16.08.004.002.001.001780995982139481338228104
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 562 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
Methylcyclohexane QuaFDFBZ ++++++++++12535 25737 64319 ++++++++++0.0800 0.160 0.400
164849 16.08.004.002.001.0024567711376217683251323432
4-Methyl-2-pentanone (MIBK)AveDFBZ ++++++++++16048 31681 78041 ++++++++++0.0800 0.160 0.400
197139 16.08.004.002.001.0030032501672423825305399537
cis-1,3-Dichloropropene AveDFBZ 3365 6174 11102 23002 59237 0.0200 0.0400 0.0800 0.160 0.400
153313 16.08.004.002.001.0024459531345013654418309126
trans-1,3-Dichloropropene AveCBZd5 2968 5392 10486 21512 52947 0.0200 0.0400 0.0800 0.160 0.400
141378 16.08.004.002.001.0023704451274805616883290886
Toluene AveCBZd5 ++++++++++28566 53488 132774 ++++++++++0.0800 0.160 0.400
338928 16.08.004.002.001.00510616428304731409005664285
1,1,2-Trichloroethane AveCBZd5 2210 4051 7894 15356 37990 0.0200 0.0400 0.0800 0.160 0.400
97142 16.08.004.002.001.001432453799711400326191202
2-Hexanone AveCBZd5 +++++++++++++++15516 38442 +++++++++++++++0.160 0.400
100602 16.08.004.002.001.001579531882374425257205236
Octane AveCBZd5 +++++4210 7650 15792 40303 +++++0.0400 0.0800 0.160 0.400
102942 16.08.004.002.001.001484824847844426890204333
C8 Range AveDFBZ ++++++++++++++++++++355229 ++++++++++++++++++++0.400
904700 16.08.004.002.001.0012258383707516635903681774965
Dibromochloromethane AveCBZd5 ++++++++++14855 34112 89627 ++++++++++0.0800 0.160 0.400
236724 16.08.004.002.001.00386493821332701003560486888
1,2-Dibromoethane (EDB)AveCBZd5 +++++7791 14679 29129 75460 +++++0.0400 0.0800 0.160 0.400
192440 16.08.004.002.001.0030229141650196819527385842
Tetrachloroethene AveCBZd5 3207 5872 11250 21736 55743 0.0200 0.0400 0.0800 0.160 0.400
141425 16.08.004.002.001.0020339201139384571733274359
Chlorobenzene AveCBZd5 +++++11941 22997 46381 113779 +++++0.0400 0.0800 0.160 0.400
286664 16.08.004.002.001.00412225523378921187858563148
Ethylbenzene AveCBZd5 +++++18615 35317 70244 174152 +++++0.0400 0.0800 0.160 0.400
449184 16.08.004.002.001.00682521937915891894974890723
m-Xylene & p-Xylene AveCBZd5 +++++28968 54705 110909 273541 +++++0.0800 0.160 0.320 0.800
695147 32.016.08.004.002.009649133557160228665321370588
Nonane AveCBZd5 ++++++++++15369 30869 77560 ++++++++++0.0800 0.160 0.400
197963 16.08.004.002.001.0026947791574384806458394416
Styrene AveCBZd5 5910 10463 19797 41141 105202 0.0200 0.0400 0.0800 0.160 0.400
276171 16.08.004.002.001.00378510622188501177518547979
Bromoform Lin2CBZd5 ++++++++++11541 35773 95153 ++++++++++0.0800 0.160 0.400
260579 16.08.004.002.001.00410171923843151012176544206
o-Xylene AveCBZd5 9847 16509 29980 61978 146826 0.0200 0.0400 0.0800 0.160 0.400
373970 16.08.004.002.001.00570709831333141539124735040
1,1,2,2-Tetrachloroethane AveCBZd5 6389 10866 21084 41912 105224 0.0200 0.0400 0.0800 0.160 0.400
268995 16.08.004.002.001.00400856521985551110444538355
1,2,3-Trichloropropane AveCBZd5 2103 3363 6447 13500 33028 0.0200 0.0400 0.0800 0.160 0.400
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 563 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
85073 16.08.004.002.001.001295915694857347841167350
Isopropylbenzene AveCBZd5 14687 24278 45312 88394 223847 0.0200 0.0400 0.0800 0.160 0.400
565435 16.08.004.002.001.008489181466018423390801112998
Propylbenzene AveCBZd5 3968 6460 12596 25936 65706 0.0200 0.0400 0.0800 0.160 0.400
167990 16.08.004.002.001.0025388871389780702664334381
2-Chlorotoluene AveCBZd5 3602 6342 12762 25449 61664 0.0200 0.0400 0.0800 0.160 0.400
159154 16.08.004.002.001.0023519831275526642261307703
4-Ethyltoluene AveCBZd5 14305 23650 45689 92153 232571 0.0200 0.0400 0.0800 0.160 0.400
594706 16.08.004.002.001.008931749490971224473861173951
1,3,5-Trimethylbenzene AveCBZd5 5945 10359 20168 41106 100144 0.0200 0.0400 0.0800 0.160 0.400
259272 16.08.004.002.001.00384965221115931059187505616
Alpha Methyl Styrene AveCBZd5 +++++++++++++++38119 96820 +++++++++++++++0.160 0.400
261698 16.08.004.002.001.00401190522234571111859514165
Decane AveCBZd5 7036 12132 24921 49828 125234 0.0200 0.0400 0.0800 0.160 0.400
309170 16.08.004.002.001.00358223221856611175634585159
tert-Butylbenzene AveCBZd5 13446 23461 44252 90090 220142 0.0200 0.0400 0.0800 0.160 0.400
561126 16.08.004.002.001.007404870434722822522651089089
1,2,4-Trimethylbenzene AveCBZd5 11976 20556 39392 81694 199678 0.0200 0.0400 0.0800 0.160 0.400
501260 16.08.004.002.001.00661765238877232015930973971
sec-Butylbenzene AveCBZd5 17559 30867 59219 119824 293773 0.0200 0.0400 0.0800 0.160 0.400
749813 16.08.004.002.001.0010205265593188730245981452791
1,3-Dichlorobenzene AveCBZd5 9813 16320 29989 61917 152279 0.0200 0.0400 0.0800 0.160 0.400
385332 16.08.004.002.001.00568194531468071567591747571
Benzyl chloride AveCBZd5 +++++++++++++++44063 118385 +++++++++++++++0.160 0.400
346252 16.08.004.002.001.00591556732322461587120736534
1,4-Dichlorobenzene AveCBZd5 9379 15174 30798 62013 149796 0.0200 0.0400 0.0800 0.160 0.400
380809 16.08.004.002.001.00549095731044851556094741371
4-Isopropyltoluene AveCBZd5 15354 27607 52109 108160 263008 0.0200 0.0400 0.0800 0.160 0.400
666883 16.08.004.002.001.009585092539211927296431297822
1,2,3-Trimethylbenzene AveCBZd5 ++++++++++40815 83229 204843 ++++++++++0.0800 0.160 0.400
518807 16.08.004.002.001.007700393420458721022251003187
Indane AveCBZd5 12398 20888 39725 81664 199213 0.0200 0.0400 0.0800 0.160 0.400
509024 16.08.004.002.001.00646296438876822031188972736
1,2-Dichlorobenzene AveCBZd5 9783 16808 29787 62512 150076 0.0200 0.0400 0.0800 0.160 0.400
378830 16.08.004.002.001.00498014129335381521864728733
Butylbenzene AveCBZd5 15682 24765 47280 100456 235125 0.0200 0.0400 0.0800 0.160 0.400
593607 16.08.004.002.001.007568298451728923632031132990
Indene AveCBZd5 10642 17212 32153 69272 170271 0.0200 0.0400 0.0800 0.160 0.400
441596 16.08.004.002.001.00616349935543621821515855414
Undecane AveCBZd5 ++++++++++34995 71196 156564 ++++++++++0.0800 0.160 0.400
398758 16.08.004.002.001.00430585126179491422246697607
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 564 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
GC Column:RTX-5 ID:0.32(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (PPB V/V)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10
1,2-Dibromo-3-Chloropropane AveCBZd5 4314 6998 12105 30141 73455 0.0200 0.0400 0.0800 0.160 0.400
199223 16.08.004.002.001.0033170831773084786546412945
1,2,4,5-Tetramethylbenzene AveCBZd5 ++++++++++58541 120307 265287 ++++++++++0.0800 0.160 0.400
672397 16.08.004.002.001.009308725514181026307611253725
Dodecane AveCBZd5 ++++++++++++++++++++164343 ++++++++++++++++++++0.400
420137 16.08.004.002.001.00328534920625611208671606497
1,2,4-Trichlorobenzene AveCBZd5 ++++++++++19199 38926 82914 ++++++++++0.0800 0.160 0.400
224931 16.08.004.002.001.0033447981822209911001406494
Naphthalene AveCBZd5 +++++22277 39224 77016 156114 +++++0.0400 0.0800 0.160 0.400
421684 16.08.004.002.001.00544496929248031553693725133
Hexachlorobutadiene AveCBZd5 ++++++++++32067 64302 118804 ++++++++++0.0800 0.160 0.400
281499 ++++++++++4.002.001.00++++++++++872240443226
1,2,3-Trichlorobenzene AveCBZd5 ++++++++++++++++++++73186 ++++++++++++++++++++0.400
189339 16.08.004.002.001.0023423031255803669030311599
2-Methylnaphthalene AveCBZd5 ++++++++++++++++++++58807 ++++++++++++++++++++0.400
181364 16.08.004.002.001.0030343201472694757260313477
1-Methylnaphthalene AveCBZd5 ++++++++++++++++++++75735 ++++++++++++++++++++0.400
217054 16.08.004.002.001.0030109451495523800711350339
4-Bromofluorobenzene (Surr)AveCBZd5 1010654 996445 985904 967645 988893 4.08 4.08 4.08 4.08 4.08
1002314 4.084.084.084.084.081097386108930010630491000211
Curve Type Legend:
Ave = Average ISTD
Lin2 = Linear 1/conc^2 ISTD
QuaF = Quadratic ISTD forced zero
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 565 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
1Level IC 140-83168/9 SZB07IC01.D
2Level IC 140-83168/10 SZB07IC02.D
3Level IC 140-83168/11 SZB07IC03.D
4Level IC 140-83168/12 SZB07IC04.D
5Level IC 140-83168/13 SZB07IC05.D
6Level IC 140-83168/14 SZB07IC06.D
7Level ICIS 140-83168/15 SZB07ICIS07.D
8Level IC 140-83168/7 SZB07IC08.D
9Level IC 140-83168/5 SZB07IC09.D
10Level IC 140-83168/3 SZB07IC10.D
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Chlorodifluoromethane ++++++++++13.4 7.2 3.0 2.0
0.2 -5.9 -6.2 -13.7
50 40 40 40
40 40 40 40
Propene ++++++++++++++++++++3.2 5.6
4.8 -1.0 -1.9 -10.5
50 40
40 40 40 40
Dichlorodifluoromethane 26.3 9.3 -2.8 2.2 -1.3 3.5
-1.6 -9.5 -8.3 -17.9
50 40 40 40 40 40
40 40 40 40
Chloromethane +++++++++++++++12.4 22.2 6.5
0.3 -8.9 -10.5 -22.1
50 40 40
40 40 40 40
1,2-Dichloro-1,1,2,2-tetrafluoroethane 32.0 19.1 -1.6 2.7 -2.4 3.3
-2.5 -12.5 -13.2 -24.9
50 40 40 40 40 40
40 40 40 40
Vinyl chloride +++++13.0 9.1 3.6 5.1 0.8
2.2 -8.5 -8.0 -17.3
50 40 40 40 40
40 40 40 40
Butane ++++++++++11.9 10.0 4.9 5.0
1.8 -7.5 -8.2 -17.7
50 40 40 40
40 40 40 40
1,3-Butadiene ++++++++++16.4 17.7 5.6 2.0
-0.5 -9.2 -11.5 -20.5
50 40 40 40
40 40 40 40
Bromomethane +++++21.5 17.5 7.0 3.4 -4.3
-2.5 -12.3 -11.6 -18.7
50 40 40 40 40
40 40 40 40
Chloroethane ++++++++++22.6 15.9 2.9 0.6
-3.5 -11.1 -10.4 -16.9
50 40 40 40
40 40 40 40
Ethanol +++++++++++++++18.8 8.0 -2.2
5.8 -6.2 -9.2 -15.0
50 40 40
40 40 40 40
Vinyl bromide ++++++++++2.6 4.0 2.5 0.0
2.2 -2.9 -0.7 -7.6
50 40 40 40
40 40 40 40
2-Methylbutane ++++++++++8.3 4.8 3.9 0.4
3.6 -5.0 -3.9 -12.1
50 40 40 40
40 40 40 40
Trichlorofluoromethane 13.3 1.3 1.3 2.3 1.2 1.6
2.4 -5.6 -5.4 -12.4
50 40 40 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 566 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Acrolein +++++++++++++++23.0 4.9 -2.7
-0.1 -5.8 -6.4 -12.8
50 40 40
40 40 40 40
Acetonitrile +++++++++++++++2.5 -0.5 -4.7
9.2 -0.7 -0.3 -5.6
50 40 40
40 40 40 40
Acetone ++++++++++++++++++++8.6 3.5
12.1 -4.3 -5.8 -14.1
80 50
50 50 50 50
Pentane +++++8.8 -0.8 8.8 1.1 1.2
3.5 -3.4 -3.8 -15.3
50 40 40 40 40
40 40 40 40
Isopropyl alcohol +++++4.3 -2.3 -1.2 -5.9 -4.7
3.0 -4.2 1.6 -0.2
50 40 40 40 40
40 40 40 40
Ethyl ether +++++-0.2 1.9 4.7 3.8 1.5
3.4 -3.6 -3.0 -8.4
50 40 40 40 40
40 40 40 40
1,1-Dichloroethene +++++8.8 5.3 4.6 -0.9 -0.8
0.1 -4.6 -3.5 -9.1
50 40 40 40 40
40 40 40 40
Acrylonitrile ++++++++++0.7 9.2 5.4 0.2
0.7 -4.9 -3.2 -8.2
50 40 40 40
40 40 40 40
tert-Butyl alcohol ++++++++++2.4 4.0 -2.4 -0.4
5.5 -1.9 -0.4 -6.8
50 40 40 40
40 40 40 40
1,1,2-Trichloro-1,2,2-trifluoroethane 13.6 2.2 0.9 2.9 0.4 0.4
1.5 -4.9 -4.8 -12.2
50 40 40 40 40 40
40 40 40 40
Methylene Chloride ++++++++++43.7 17.9 -2.1 -5.7
-7.6 -13.5 -13.5 -19.2
80 50 50 50
50 50 50 50
3-Chloropropene +++++10.3 36.9 2.3 -5.2 -9.0
-5.6 -1.5 -10.9 -17.4
50 40 40 40 40
40 40 40 40
Carbon disulfide ++++++++++13.2 7.3 0.7 -1.6
-1.4 -5.8 -3.9 -8.4
50 40 40 40
40 40 40 40
trans-1,2-Dichloroethene +++++12.4 8.7 1.7 -0.5 1.1
-0.1 -5.0 -5.4 -13.0
50 40 40 40 40
40 40 40 40
2-Methylpentane ++++++++++4.6 5.7 2.5 5.8
3.8 -3.4 -4.7 -14.4
50 40 40 40
40 40 40 40
Methyl tert-butyl ether ++++++++++2.2 2.2 0.6 1.6
1.3 -1.9 -1.1 -4.9
50 40 40 40
40 40 40 40
1,1-Dichloroethane 4.8 7.4 1.1 5.1 -0.9 0.8
-0.3 -5.5 -3.7 -9.0
50 40 40 40 40 40
40 40 40 40
Vinyl acetate +++++-0.1 1.1 7.1 -3.2 -3.3
-4.9 -1.8 3.5 1.5
50 40 40 40 40
40 40 40 40
2-Butanone (MEK)+++++-2.3 2.2 3.5 -0.9 0.8
5.2 -1.8 0.0 -6.7
50 40 40 40 40
40 40 40 40
Hexane ++++++++++9.0 5.2 0.6 3.0
0.6 -3.8 -3.2 -11.4
50 50 50 50
50 50 50 50
cis-1,2-Dichloroethene +++++1.8 3.8 2.1 -1.1 1.1
0.3 -2.3 -0.9 -4.9
50 40 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 567 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Ethyl acetate ++++++++++6.9 3.7 -2.7 1.5
0.3 -3.4 -1.0 -5.5
50 40 40 40
40 40 40 40
Chloroform ++++++++++1.3 4.2 2.4 2.6
2.1 -3.1 -2.2 -7.3
50 40 40 40
40 40 40 40
Tetrahydrofuran ++++++++++1.1 2.4 0.5 1.0
2.6 -3.0 -0.5 -4.0
50 40 40 40
40 40 40 40
1,1,1-Trichloroethane 11.0 2.3 -1.0 3.2 -1.8 -0.5
0.0 -4.0 -2.6 -6.6
50 40 40 40 40 40
40 40 40 40
1,2-Dichloroethane 8.3 8.3 -2.2 2.3 0.8 2.1
2.1 -4.0 -5.9 -11.7
50 40 40 40 40 40
40 40 40 40
1-Butanol ++++++++++5.5 3.4 -9.4 -3.5
3.5 1.9 2.2 -3.6
50 40 40 40
40 40 40 40
Cyclohexane ++++++++++5.8 14.7 2.9 4.4
2.4 -2.0 -7.3 -20.9
50 40 40 40
40 40 40 40
Benzene ++++++++++11.9 9.3 3.6 4.1
2.1 -2.9 -7.5 -20.6
50 40 40 40
40 40 40 40
Carbon tetrachloride 2.9 -6.1 -6.1 -21.3 -6.1 -9.7
0.1 -1.6 1.0 -0.1
50 40 40 40 40 40
40 40 40 40
2,3-Dimethylpentane ++++++++++4.9 8.9 1.8 2.2
2.3 -2.0 -5.3 -12.7
50 40 40 40
40 40 40 40
Thiophene ++++++++++-2.6 1.6 0.9 3.0
2.7 0.7 0.0 -6.3
50 40 40 40
40 40 40 40
2,2,4-Trimethylpentane ++++++++++1.5 4.2 2.6 3.5
2.8 -0.6 -2.6 -11.5
50 40 40 40
40 40 40 40
Heptane ++++++++++-3.7 0.7 1.4 5.2
4.5 1.1 -0.4 -8.9
50 40 40 40
40 40 40 40
1,2-Dichloropropane +++++6.3 0.0 7.2 2.7 4.3
1.8 -2.5 -5.4 -14.5
50 40 40 40 40
40 40 40 40
Trichloroethene 13.6 0.3 0.0 4.0 0.1 2.4
0.3 -2.6 -5.3 -12.9
50 40 40 40 40 40
40 40 40 40
Dibromomethane +++++25.7 15.7 -1.5 -4.4 -3.4
-4.4 -3.2 -9.4 -15.2
50 40 40 40 40
40 40 40 40
Bromodichloromethane 3.9 -2.4 -5.9 1.1 1.6 4.1
4.2 0.4 0.0 -7.0
50 40 40 40 40 40
40 40 40 40
1,4-Dioxane +++++++++++++++8.9 -3.3 0.0
8.6 -0.2 -2.1 -12.0
50 40 40
40 40 40 40
Methyl methacrylate +++++++++++++++11.0 0.1 -0.8
0.1 -1.4 -1.7 -7.3
50 40 40
40 40 40 40
Methylcyclohexane ++++++++++-7.3 -2.1 -3.4 -0.7
-1.3 -1.1 0.6 -0.1
50 40 40 40
40 40 40 40
4-Methyl-2-pentanone (MIBK)++++++++++1.9 3.3 0.3 1.2
3.2 -0.5 -1.5 -8.0
50 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 568 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
cis-1,3-Dichloropropene 6.3 0.0 -8.8 -2.9 -1.5 1.8
3.3 2.1 2.6 -3.0
50 40 40 40 40 40
40 40 40 40
trans-1,3-Dichloropropene 2.2 -4.9 -6.1 -1.6 -4.9 1.1
4.5 3.0 5.1 1.6
50 40 40 40 40 40
40 40 40 40
Toluene ++++++++++7.3 2.6 0.0 1.6
0.1 -1.3 -2.1 -8.2
50 50 50 50
50 50 50 50
1,1,2-Trichloroethane 10.4 3.7 2.6 1.9 -1.0 0.8
-0.3 -3.0 -4.3 -10.9
50 40 40 40 40 40
40 40 40 40
2-Hexanone +++++++++++++++-0.1 -2.8 1.3
3.8 0.0 2.5 -4.7
50 40 40
40 40 40 40
Octane +++++4.6 -3.5 1.7 1.9 3.6
3.3 0.3 -1.6 -10.4
50 40 40 40 40
40 40 40 40
Dibromochloromethane ++++++++++-18.3 -4.2 -1.2 3.9
7.3 2.8 8.0 1.7
50 40 40 40
40 40 40 40
1,2-Dibromoethane (EDB)+++++1.7 -2.7 -1.4 0.3 1.8
2.5 1.2 0.7 -4.1
50 40 40 40 40
40 40 40 40
Tetrachloroethene 11.5 4.6 1.7 0.4 1.0 2.1
-0.5 -3.6 -5.1 -12.0
50 40 40 40 40 40
40 40 40 40
Chlorobenzene +++++4.8 2.5 5.6 1.7 2.0
0.7 -1.3 -4.0 -12.0
50 40 40 40 40
40 40 40 40
Ethylbenzene +++++4.0 0.2 1.8 -1.0 1.7
1.3 0.2 -1.0 -7.3
50 40 40 40 40
40 40 40 40
m-Xylene & p-Xylene +++++5.9 1.6 5.2 1.8 3.1
2.1 -0.8 -4.7 -14.2
50 40 40 40 40
40 40 40 40
Nonane ++++++++++1.8 4.5 3.0 4.7
4.8 -0.4 -3.9 -14.5
50 40 40 40
40 40 40 40
Styrene 8.3 -1.8 -5.6 0.2 0.6 5.1
4.8 4.6 -2.6 -13.6
50 40 40 40 40 40
40 40 40 40
Bromoform ++++++++++-3.8 7.6 -0.9 2.4
5.6 -9.3 4.9 -6.3
50 40 40 40
40 40 40 40
o-Xylene 23.9 6.4 -1.9 3.6 -3.7 -2.3
-3.6 -6.1 -5.6 -10.6
50 40 40 40 40 40
40 40 40 40
1,1,2,2-Tetrachloroethane 15.5 0.6 -0.9 0.6 -0.8 1.0
1.5 -2.7 -4.9 -9.8
50 40 40 40 40 40
40 40 40 40
1,2,3-Trichloropropane 20.2 -1.5 -4.1 2.5 -1.6 1.0
-0.2 -3.6 -4.9 -7.8
50 40 40 40 40 40
40 40 40 40
Isopropylbenzene 23.7 4.7 -0.7 -1.1 -1.7 -1.1
-2.2 -4.5 -6.0 -11.0
50 40 40 40 40 40
40 40 40 40
Propylbenzene 15.7 -3.5 -4.5 0.5 -0.1 1.7
1.7 -0.7 -3.0 -7.8
50 40 40 40 40 40
40 40 40 40
2-Chlorotoluene 11.3 0.3 2.5 4.4 -0.7 2.1
-0.9 -3.8 -5.7 -9.6
50 40 40 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 569 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
4-Ethyltoluene 17.2 -0.7 -2.6 0.3 -0.6 1.2
0.4 -2.7 -3.6 -8.9
50 40 40 40 40 40
40 40 40 40
1,3,5-Trimethylbenzene 12.6 0.5 -0.7 3.4 -1.1 1.9
-0.2 -2.8 -4.3 -9.3
50 40 40 40 40 40
40 40 40 40
Alpha Methyl Styrene +++++++++++++++-3.2 -3.5 3.9
2.5 3.0 1.8 -4.5
50 40 40
40 40 40 40
Decane 15.7 2.2 6.6 8.9 7.4 5.6
0.4 -6.3 -13.9 -26.7
50 40 40 40 40 40
40 40 40 40
tert-Butylbenzene 18.0 5.4 1.0 5.0 0.7 2.2
-0.3 -4.2 -8.7 -19.1
50 40 40 40 40 40
40 40 40 40
1,2,4-Trimethylbenzene 17.5 3.3 0.5 6.5 2.2 2.1
-0.3 -4.1 -8.6 -19.2
50 40 40 40 40 40
40 40 40 40
sec-Butylbenzene 15.3 3.8 1.1 4.5 0.6 2.2
-0.5 -3.7 -6.7 -16.6
50 40 40 40 40 40
40 40 40 40
1,3-Dichlorobenzene 22.4 4.3 -2.7 2.6 -0.9 -0.2
-2.7 -5.2 -6.0 -11.7
50 40 40 40 40 40
40 40 40 40
Benzyl chloride +++++++++++++++-17.6 -13.1 1.3
8.2 8.4 9.0 3.7
50 40 40
40 40 40 40
1,4-Dichlorobenzene 19.2 -1.2 1.8 4.7 -0.7 0.5
-1.7 -4.1 -5.5 -13.1
50 40 40 40 40 40
40 40 40 40
4-Isopropyltoluene 12.4 3.5 -0.8 5.2 0.4 1.4
-0.9 -3.1 -5.5 -12.6
50 40 40 40 40 40
40 40 40 40
1,2,3-Trimethylbenzene ++++++++++1.8 6.0 2.4 3.3
0.3 -2.3 -3.5 -8.1
50 40 40 40
40 40 40 40
Indane 20.9 4.3 0.7 5.7 1.3 3.0
-1.1 -4.0 -9.2 -21.6
50 40 40 40 40 40
40 40 40 40
1,2-Dichlorobenzene 24.9 9.9 -1.1 6.0 -0.1 0.4
-3.0 -5.8 -10.3 -20.9
50 40 40 40 40 40
40 40 40 40
Butylbenzene 28.4 3.9 0.7 9.3 0.4 0.9
-3.2 -6.2 -11.4 -22.8
50 40 40 40 40 40
40 40 40 40
Indene 19.6 -1.0 -6.0 3.4 -0.3 3.0
0.2 -0.8 -4.4 -13.8
50 40 40 40 40 40
40 40 40 40
Undecane ++++++++++19.8 24.4 7.4 8.9
-4.3 -9.3 -17.5 -29.5
50 40 40 40
40 40 40 40
1,2-Dibromo-3-Chloropropane 9.2 -9.3 -20.3 1.3 -3.1 4.7
9.0 -3.5 7.5 4.5
50 40 40 40 40 40
40 40 40 40
1,2,4,5-Tetramethylbenzene ++++++++++12.0 17.6 1.8 2.7
-3.8 -6.2 -9.4 -14.7
50 40 40 40
40 40 40 40
Dodecane ++++++++++++++++++++33.5 35.9
-1.4 -8.7 -23.0 -36.3
50 40
40 40 40 40
1,2,4-Trichlorobenzene ++++++++++9.9 13.8 -4.8 2.8
-6.7 -2.8 -3.9 -8.3
50 40 40 40
40 40 40 40
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 570 of 864
FORM VI
Lab Name:Job No.:
AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Knoxville 140-35862-1 Analy Batch No.:83168
READBACK PERCENT ERROR
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)MS
4892Calibration Start Date:Calibration End Date:02/07/2024 15:26
N
02/08/2024 01:36
0.32(mm)RTX-5 ID:
ANALYTE PERCENT ERROR
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 #####LVL 6 #LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6
PERCENT ERROR LIMIT
LVL 7 LVL 8 LVL 9 LVL 10 ####LVL 7 LVL 8 LVL 9 LVL 10
Naphthalene +++++32.3 18.3 18.6 -5.6 1.5
-12.3 -12.7 -18.8 -21.4
80 40 40 40 40
40 40 40 40
Hexachlorobutadiene ++++++++++32.5 35.7 -1.6 -7.2
-26.6 -32.8 ++++++++++
50 40 40 40
40 40
1,2,3-Trichlorobenzene ++++++++++++++++++++13.6 17.0
-3.3 -3.5 -10.5 -13.2
50 40
40 40 40 40
2-Methylnaphthalene ++++++++++++++++++++-12.7 7.2
-6.9 4.5 0.4 7.5
80 50
50 50 50 50
1-Methylnaphthalene ++++++++++++++++++++1.6 16.0
-6.0 -0.1 -7.9 -3.6
80 50
50 50 50 50
FORM VI TO-15 3/25/2024
9:50:51 AM
Page 571 of 864
Report Date: 10-Feb-2024 14:43:02 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC10.D
Lims ID:IC L10
Client ID:
Sample Type:IC Calib Level:10
Inject. Date:07-Feb-2024 15:26:30 ALS Bottle#:12 Worklist Smp#:3
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-003
Misc. Info.:663021
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:43:02 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 07:27:30
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.932 9.932 0.000 93 327617 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.051 12.051 0.000 93 1597380 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.656 16.656 0.000 83 1426322 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.265 18.265 0.000 96 1097386 4.08 4.30
6 Chlorodifluoromethane 51 4.170 4.170 0.000 97 2049415 16.0 13.8
7 Propene 41 4.181 4.181 0.000 99 1023843 16.0 14.3
8 Dichlorodifluoromethane 85 4.246 4.246 0.000 100 2830772 16.0 13.1
9 Chloromethane 52 4.466 4.466 0.000 97 166734 16.0 12.5
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.471 4.471 0.000 85 1632096 16.0 12.0
11 Acetaldehyde 44 4.649 4.649 0.000 92 962405 80.0 63.1
12 Vinyl chloride 62 4.671 4.671 0.000 100 570709 16.0 13.2
14 Butane 43 4.773 4.773 0.000 83 760387 16.0 13.2
13 Butadiene 54 4.778 4.778 0.000 73 406240 16.0 12.7
15 Bromomethane 94 5.171 5.171 0.000 98 609473 16.0 13.0
16 Chloroethane 64 5.338 5.338 0.000 91 250304 16.0 13.3
17 Ethanol 31 5.451 5.451 0.000 99 1310416 80.0 68.0
18 Vinyl bromide 106 5.693 5.693 0.000 99 1176477 16.0 14.8
19 2-Methylbutane 43 5.746 5.746 0.000 90 1157607 16.0 14.1
20 Trichlorofluoromethane 101 5.999 5.999 0.000 99 3444546 16.0 14.0
21 Acrolein 56 6.015 6.015 0.000 96 362468 16.0 13.9
22 Acetonitrile 40 6.096 6.096 0.000 99 467269 16.0 15.1
23 Acetone 58 6.139 6.139 0.000 98 1398416 48.0 41.2
25 Pentane 72 6.252 6.252 0.000 98 182225 16.0 13.5
24 Isopropyl alcohol 45 6.231 6.231 0.000 97 3938682 48.0 47.9
26 Ethyl ether 31 6.430 6.430 0.000 95 1264182 16.0 14.7
27 1,1-Dichloroethene 96 6.806 6.806 0.000 99 1261471 16.0 14.5
28 Acrylonitrile 53 6.930 6.930 0.000 95 811257 16.0 14.7
29 2-Methyl-2-propanol 59 6.903 6.903 0.000 94 2182976 16.0 14.9
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.995 6.995 0.000 93 2694933 16.0 14.0
31 Methylene Chloride 84 7.199 7.199 0.000 94 1060527 16.0 12.9
3/25/2024
9:50:51 AM
Page 572 of 864
Report Date: 10-Feb-2024 14:43:02 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC10.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.210 7.210 0.000 98 1050373 16.0 13.2
33 Carbon disulfide 76 7.382 7.382 0.000 99 3437032 16.0 14.7
34 trans-1,2-Dichloroethene 96 8.076 8.076 0.000 97 1239613 16.0 13.9
35 2-Methylpentane 43 8.087 8.087 0.000 93 2314722 16.0 13.7
36 Methyl tert-butyl ether 73 8.189 8.189 0.000 95 3650258 16.0 15.2
37 1,1-Dichloroethane 63 8.538 8.538 0.000 100 2249648 16.0 14.6
38 Vinyl acetate 43 8.625 8.625 0.000 100 3012006 16.0 16.2
39 2-Butanone (MEK) 72 9.098 9.098 0.000 99 597397 16.0 14.9
40 Hexane 56 9.130 9.130 0.000 91 914848 16.0 14.2
41 Isopropyl ether 45 9.281 9.281 0.000 96 3950676 16.0 14.8
42 cis-1,2-Dichloroethene 96 9.582 9.582 0.000 91 1432192 16.0 15.2
43 Ethyl acetate 43 9.738 9.738 0.000 99 2794284 16.0 15.1
44 Chloroform 83 9.937 9.937 0.000 96 2807039 16.0 14.8
45 Tert-butyl ethyl ether 59 9.991 9.991 0.000 95 3938050 16.0 15.3
46 Tetrahydrofuran 42 10.324 10.324 0.000 91 1396797 16.0 15.4
47 1,1,1-Trichloroethane 97 10.975 10.975 0.000 94 3200141 16.0 14.9
48 1,2-Dichloroethane 62 11.083 11.083 0.000 98 1839858 16.0 14.1
49 n-Butanol 31 11.443 11.443 0.000 86 548489 16.0 15.4
50 Cyclohexane 69 11.546 11.546 0.000 91 521804 16.0 12.6
51 Benzene 78 11.546 11.546 0.000 97 3385324 16.0 12.7
52 Carbon tetrachloride 117 11.573 11.573 0.000 97 3364616 16.0 16.0
53 2,3-Dimethylpentane 71 11.637 11.637 0.000 91 850504 16.0 14.0
54 Thiophene 84 11.815 11.815 0.000 93 2366517 16.0 15.0
55 Isooctane 57 12.250 12.250 0.000 98 5737415 16.0 14.2
56 n-Heptane 71 12.600 12.600 0.000 90 1290320 16.0 14.6
57 1,2-Dichloropropane 63 12.713 12.713 0.000 89 1338926 16.0 13.7
58 Trichloroethene 130 12.745 12.745 0.000 96 2109420 16.0 13.9
59 Dibromomethane 93 12.837 12.837 0.000 88 1686233 16.0 13.6
60 Dichlorobromomethane 83 12.971 12.971 0.000 99 3055695 16.0 14.9
61 1,4-Dioxane 88 12.955 12.955 0.000 86 581659 16.0 14.1
62 Methyl methacrylate 41 13.014 13.014 0.000 95 1780995 16.0 14.8
63 Methylcyclohexane 83 13.488 13.488 0.000 95 2456771 16.0 16.0
64 4-Methyl-2-pentanone (MIBK) 43 13.843 13.843 0.000 97 3003250 16.0 14.7
65 cis-1,3-Dichloropropene 75 13.923 13.923 0.000 93 2445953 16.0 15.5
66 trans-1,3-Dichloropropene 75 14.596 14.596 0.000 98 2370445 16.0 16.3
67 Toluene 91 14.725 14.725 0.000 94 5106164 16.0 14.7
68 1,1,2-Trichloroethane 83 14.795 14.795 0.000 96 1432453 16.0 14.3
69 2-Hexanone 58 15.134 15.134 0.000 94 1579531 16.0 15.3
70 n-Octane 85 15.354 15.354 0.000 91 1484824 16.0 14.3
71 Chlorodibromomethane 129 15.494 15.494 0.000 98 3864938 16.0 16.3
72 Ethylene Dibromide 107 15.785 15.785 0.000 99 3022914 16.0 15.3
73 Tetrachloroethene 129 15.844 15.844 0.000 96 2033920 16.0 14.1
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 91 3470223 16.0 12.4
75 Chlorobenzene 112 16.705 16.705 0.000 97 4122255 16.0 14.1
76 Ethylbenzene 91 16.974 16.974 0.000 98 6825219 16.0 14.8
77 m-Xylene & p-Xylene 91 17.130 17.130 0.000 99 9649133 32.0 27.4
78 n-Nonane 57 17.506 17.506 0.000 88 2694779 16.0 13.7
80 Styrene 104 17.592 17.592 0.000 97 3785106 16.0 13.8
79 Bromoform 173 17.603 17.603 0.000 98 4101719 16.0 15.0
81 o-Xylene 91 17.657 17.657 0.000 99 5707098 16.0 14.3
82 1,1,2,2-Tetrachloroethane 83 17.974 17.974 0.000 100 4008565 16.0 14.4
83 1,2,3-Trichloropropane 110 18.130 18.130 0.000 97 1295915 16.0 14.8
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Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC10.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.227 18.227 0.000 95 8489181 16.0 14.2
85 N-Propylbenzene 120 18.749 18.749 0.000 100 2538887 16.0 14.7
86 2-Chlorotoluene 126 18.808 18.808 0.000 96 2351983 16.0 14.5
87 4-Ethyltoluene 105 18.894 18.894 0.000 99 8931749 16.0 14.6
88 1,3,5-Trimethylbenzene 120 18.964 18.964 0.000 94 3849652 16.0 14.5
89 Alpha Methyl Styrene 118 19.195 19.195 0.000 92 4011905 16.0 15.3
90 n-Decane 57 19.222 19.222 0.000 92 3582232 16.0 11.7
91 tert-Butylbenzene 119 19.389 19.389 0.000 94 7404870 16.0 12.9
92 1,2,4-Trimethylbenzene 105 19.405 19.405 0.000 95 6617652 16.0 12.9
93 sec-Butylbenzene 105 19.658 19.658 0.000 98 10205265 16.0 13.3
94 1,3-Dichlorobenzene 146 19.685 19.685 0.000 95 5681945 16.0 14.1
95 Benzyl chloride 91 19.755 19.755 0.000 99 5915567 16.0 16.6
96 1,4-Dichlorobenzene 146 19.771 19.771 0.000 97 5490957 16.0 13.9
97 4-Isopropyltoluene 119 19.814 19.814 0.000 98 9585092 16.0 14.0
98 1,2,3-Trimethylbenzene 105 19.879 19.879 0.000 97 7700393 16.0 14.7
99 Butylcyclohexane 83 19.922 19.922 0.000 96 5084183 16.0 13.2
100 2,3-Dihydroindene 117 20.126 20.126 0.000 95 6462964 16.0 12.5
101 1,2-Dichlorobenzene 146 20.137 20.137 0.000 99 4980141 16.0 12.7
102 n-Butylbenzene 91 20.244 20.244 0.000 98 7568298 16.0 12.3
103 Indene 116 20.261 20.261 0.000 92 6163499 16.0 13.8
104 Undecane 57 20.530 20.530 0.000 93 4305851 16.0 11.3
105 1,2-Dibromo-3-Chloropropane 157 20.750 20.750 0.000 92 3317083 16.0 16.7
106 1,2,4,5-Tetramethylbenzene 119 21.035 21.035 0.000 97 9308725 16.0 13.6
107 Dodecane 57 21.648 21.648 0.000 94 3285349 16.0 10.2
108 1,2,4-Trichlorobenzene 180 21.864 21.864 0.000 93 3344798 16.0 14.7
109 Naphthalene 128 21.971 21.971 0.000 99 5444969 16.0 12.6
110 Hexachlorobutadiene 225 22.100 22.100 0.000 94 2522267 16.0 7.98
111 1,2,3-Trichlorobenzene 180 22.160 22.160 0.000 95 2342303 16.0 13.9
112 2-Methylnaphthalene 142 22.676 22.676 0.000 99 3034320 16.0 17.2
113 1-Methylnaphthalene 142 22.805 22.805 0.000 99 3010945 16.0 15.4
A 115 C8 Range 1 15.359 (15.306-15.403) 0 12258383 16.0 13.8
S 116 Xylenes, Total 100 0 48.0 41.7
S 117 1,2-Dichloroethene, Total 1 0 32.0 29.1
QC Flag Legend
Processing Flags
Reagents:
40L10DQP_00052 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Report Date: 10-Feb-2024 14:43:02 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC10.D
Injection Date:07-Feb-2024 15:26:30 Instrument ID:MS Operator ID:
Lims ID:IC L10 Worklist Smp#:3
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:12
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
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3/25/2024
9:50:51 AM
Page 575 of 864
Report Date: 10-Feb-2024 14:43:02 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC10.D
Injection Date:07-Feb-2024 15:26:30 Instrument ID:MS
Lims ID:IC L10
Client ID:
Operator ID:ALS Bottle#:12 Worklist Smp#:3
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.2
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3/25/2024
9:50:51 AM
Page 576 of 864
Report Date: 10-Feb-2024 14:43:18 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC09.D
Lims ID:IC L9
Client ID:
Sample Type:IC Calib Level:9
Inject. Date:07-Feb-2024 17:08:30 ALS Bottle#:11 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-005
Misc. Info.:663022
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:43:18 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 13:35:25
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.932 9.932 0.000 86 346991 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.046 12.049 -0.003 93 1661844 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.656 16.656 0.000 83 1482931 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.265 18.265 0.000 97 1089300 4.08 4.11
6 Chlorodifluoromethane 51 4.170 4.170 0.000 97 1179990 8.00 7.51
7 Propene 41 4.186 4.184 0.002 99 594254 8.00 7.84
8 Dichlorodifluoromethane 85 4.246 4.246 0.000 100 1675055 8.00 7.34
9 Chloromethane 52 4.466 4.466 0.000 98 101428 8.00 7.16
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.472 4.472 0.000 95 999855 8.00 6.95
11 Acetaldehyde 44 4.649 4.649 0.000 93 582479 40.0 36.0
12 Vinyl chloride 62 4.671 4.671 0.000 99 336045 8.00 7.36
14 Butane 43 4.778 4.775 0.003 83 449361 8.00 7.34
13 Butadiene 54 4.778 4.778 0.000 72 239446 8.00 7.08
15 Bromomethane 94 5.171 5.171 0.000 98 351108 8.00 7.07
16 Chloroethane 64 5.338 5.338 0.000 91 142999 8.00 7.17
17 Ethanol 31 5.445 5.448 -0.003 99 741499 40.0 36.3
18 Vinyl bromide 106 5.693 5.693 0.000 98 669860 8.00 7.94
19 2-Methylbutane 43 5.746 5.746 0.000 91 670269 8.00 7.69
20 Trichlorofluoromethane 101 5.999 5.999 0.000 99 1968227 8.00 7.57
21 Acrolein 56 6.015 6.015 0.000 94 206106 8.00 7.49
22 Acetonitrile 40 6.091 6.093 -0.002 98 261341 8.00 7.98
23 Acetone 58 6.139 6.139 0.000 98 811755 24.0 22.6
24 Isopropyl alcohol 45 6.231 6.231 0.000 96 2406280 24.0 24.4
25 Pentane 72 6.252 6.252 0.000 98 109589 8.00 7.69
26 Ethyl ether 31 6.435 6.432 0.003 95 708742 8.00 7.76
27 1,1-Dichloroethene 96 6.806 6.806 0.000 99 709385 8.00 7.72
29 2-Methyl-2-propanol 59 6.903 6.903 0.000 95 1235957 8.00 7.97
28 Acrylonitrile 53 6.925 6.927 -0.002 94 453002 8.00 7.74
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.995 6.995 0.000 93 1548800 8.00 7.62
31 Methylene Chloride 84 7.194 7.196 -0.002 93 601817 8.00 6.92
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Report Date: 10-Feb-2024 14:43:18 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC09.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.210 7.210 0.000 98 600033 8.00 7.13
33 Carbon disulfide 76 7.382 7.382 0.000 99 1910524 8.00 7.69
34 trans-1,2-Dichloroethene 96 8.076 8.076 0.000 98 714516 8.00 7.57
35 2-Methylpentane 43 8.081 8.084 -0.003 93 1365036 8.00 7.63
36 Methyl tert-butyl ether 73 8.189 8.189 0.000 95 2010837 8.00 7.91
37 1,1-Dichloroethane 63 8.533 8.536 -0.003 100 1260105 8.00 7.70
38 Vinyl acetate 43 8.625 8.625 0.000 100 1626186 8.00 8.28
39 2-Butanone (MEK) 72 9.098 9.098 0.000 98 339221 8.00 8.00
40 Hexane 56 9.130 9.130 0.000 91 529332 8.00 7.74
41 Isopropyl ether 45 9.281 9.281 0.000 96 2242836 8.00 7.95
42 cis-1,2-Dichloroethene 96 9.577 9.579 -0.002 91 790501 8.00 7.93
43 Ethyl acetate 43 9.733 9.735 -0.002 99 1549822 8.00 7.92
44 Chloroform 83 9.937 9.937 0.000 95 1568552 8.00 7.83
45 Tert-butyl ethyl ether 59 9.991 9.991 0.000 95 2227520 8.00 8.16
46 Tetrahydrofuran 42 10.325 10.324 0.000 91 767079 8.00 7.96
47 1,1,1-Trichloroethane 97 10.970 10.973 -0.003 95 1768181 8.00 7.79
48 1,2-Dichloroethane 62 11.078 11.080 -0.002 98 1019330 8.00 7.52
49 n-Butanol 31 11.449 11.446 0.003 86 302225 8.00 8.17
50 Cyclohexane 69 11.540 11.543 -0.003 89 318188 8.00 7.41
51 Benzene 78 11.546 11.546 0.000 96 2050241 8.00 7.40
52 Carbon tetrachloride 117 11.567 11.570 -0.003 98 1942721 8.00 8.08
53 2,3-Dimethylpentane 71 11.637 11.637 0.000 90 479863 8.00 7.57
54 Thiophene 84 11.815 11.815 0.000 93 1313658 8.00 8.00
55 Isooctane 57 12.250 12.250 0.000 99 3284018 8.00 7.79
56 n-Heptane 71 12.595 12.597 -0.002 91 733825 8.00 7.97
57 1,2-Dichloropropane 63 12.713 12.713 0.000 88 770726 8.00 7.57
58 Trichloroethene 130 12.740 12.743 -0.003 97 1193105 8.00 7.58
59 Dibromomethane 93 12.837 12.837 0.000 89 937051 8.00 7.25
61 1,4-Dioxane 88 12.955 12.955 0.000 87 336517 8.00 7.83
60 Dichlorobromomethane 83 12.966 12.969 -0.003 98 1709852 8.00 8.00
62 Methyl methacrylate 41 13.014 13.014 0.000 95 982139 8.00 7.86
63 Methylcyclohexane 83 13.482 13.485 -0.003 96 1376217 8.00 8.05
64 4-Methyl-2-pentanone (MIBK) 43 13.843 13.843 0.000 97 1672423 8.00 7.88
65 cis-1,3-Dichloropropene 75 13.923 13.923 0.000 93 1345013 8.00 8.20
66 trans-1,3-Dichloropropene 75 14.591 14.593 -0.003 98 1274805 8.00 8.41
67 Toluene 91 14.725 14.725 0.000 94 2830473 8.00 7.83
68 1,1,2-Trichloroethane 83 14.795 14.795 0.000 96 799711 8.00 7.66
69 2-Hexanone 58 15.134 15.134 0.000 94 882374 8.00 8.20
70 n-Octane 85 15.354 15.354 0.000 92 847844 8.00 7.88
71 Chlorodibromomethane 129 15.494 15.494 0.000 98 2133270 8.00 8.64
72 Ethylene Dibromide 107 15.785 15.785 0.000 99 1650196 8.00 8.06
73 Tetrachloroethene 129 15.839 15.841 -0.002 96 1139384 8.00 7.59
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 95 2099333 8.00 7.20
75 Chlorobenzene 112 16.705 16.705 0.000 97 2337892 8.00 7.68
76 Ethylbenzene 91 16.974 16.974 0.000 98 3791589 8.00 7.92
77 m-Xylene & p-Xylene 91 17.130 17.130 0.000 99 5571602 16.0 15.2
78 n-Nonane 57 17.506 17.506 0.000 89 1574384 8.00 7.68
80 Styrene 104 17.592 17.592 0.000 97 2218850 8.00 7.79
79 Bromoform 173 17.603 17.603 0.000 98 2384315 8.00 8.40
81 o-Xylene 91 17.651 17.654 -0.003 99 3133314 8.00 7.55
82 1,1,2,2-Tetrachloroethane 83 17.969 17.972 -0.003 100 2198555 8.00 7.61
83 1,2,3-Trichloropropane 110 18.130 18.130 0.000 97 694857 8.00 7.61
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Report Date: 10-Feb-2024 14:43:18 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC09.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.224 -0.002 95 4660184 8.00 7.52
85 N-Propylbenzene 120 18.749 18.749 0.000 100 1389780 8.00 7.76
86 2-Chlorotoluene 126 18.808 18.808 0.000 96 1275526 8.00 7.55
87 4-Ethyltoluene 105 18.894 18.894 0.000 99 4909712 8.00 7.71
88 1,3,5-Trimethylbenzene 120 18.964 18.964 0.000 94 2111593 8.00 7.66
89 Alpha Methyl Styrene 118 19.195 19.195 0.000 92 2223457 8.00 8.14
90 n-Decane 57 19.222 19.222 0.000 91 2185661 8.00 6.89
91 tert-Butylbenzene 119 19.389 19.389 0.000 94 4347228 8.00 7.31
92 1,2,4-Trimethylbenzene 105 19.405 19.405 0.000 95 3887723 8.00 7.31
93 sec-Butylbenzene 105 19.653 19.655 -0.002 99 5931887 8.00 7.46
94 1,3-Dichlorobenzene 146 19.685 19.685 0.000 95 3146807 8.00 7.52
95 Benzyl chloride 91 19.755 19.755 0.000 99 3232246 8.00 8.72
96 1,4-Dichlorobenzene 146 19.771 19.771 0.000 97 3104485 8.00 7.56
97 4-Isopropyltoluene 119 19.814 19.814 0.000 98 5392119 8.00 7.56
98 1,2,3-Trimethylbenzene 105 19.873 19.876 -0.003 97 4204587 8.00 7.72
99 Butylcyclohexane 83 19.916 19.919 -0.003 96 2967520 8.00 7.39
100 2,3-Dihydroindene 117 20.126 20.126 0.000 95 3887682 8.00 7.26
101 1,2-Dichlorobenzene 146 20.131 20.134 -0.003 99 2933538 8.00 7.17
102 n-Butylbenzene 91 20.239 20.242 -0.003 98 4517289 8.00 7.09
103 Indene 116 20.261 20.261 0.000 92 3554362 8.00 7.65
104 Undecane 57 20.530 20.530 0.000 94 2617949 8.00 6.60
105 1,2-Dibromo-3-Chloropropane 157 20.750 20.750 0.000 92 1773084 8.00 8.60
106 1,2,4,5-Tetramethylbenzene 119 21.035 21.035 0.000 98 5141810 8.00 7.25
107 Dodecane 57 21.649 21.648 0.000 96 2062561 8.00 6.16
108 1,2,4-Trichlorobenzene 180 21.858 21.861 -0.003 93 1822209 8.00 7.68
109 Naphthalene 128 21.966 21.969 -0.003 99 2924803 8.00 6.50
110 Hexachlorobutadiene 225 22.100 22.100 0.000 93 1536762 8.00 4.68
111 1,2,3-Trichlorobenzene 180 22.154 22.157 -0.003 95 1255803 8.00 7.16
112 2-Methylnaphthalene 142 22.676 22.676 0.000 99 1472694 8.00 8.03
113 1-Methylnaphthalene 142 22.805 22.805 0.000 99 1495523 8.00 7.37
A 115 C8 Range 1 15.359 (15.306-15.403) 0 7075166 8.00 7.68
S 116 Xylenes, Total 100 0 24.0 22.8
S 117 1,2-Dichloroethene, Total 1 0 16.0 15.5
QC Flag Legend
Processing Flags
Reagents:
40L9DQP_00051 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 579 of 864
Report Date: 10-Feb-2024 14:43:18 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC09.D
Injection Date:07-Feb-2024 17:08:30 Instrument ID:MS Operator ID:
Lims ID:IC L9 Worklist Smp#:5
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:11
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
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3/25/2024
9:50:51 AM
Page 580 of 864
Report Date: 10-Feb-2024 14:43:18 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC09.D
Injection Date:07-Feb-2024 17:08:30 Instrument ID:MS
Lims ID:IC L9
Client ID:
Operator ID:ALS Bottle#:11 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.2
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3/25/2024
9:50:51 AM
Page 581 of 864
Report Date: 10-Feb-2024 14:43:35 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC08.D
Lims ID:IC L8
Client ID:
Sample Type:IC Calib Level:8
Inject. Date:07-Feb-2024 18:49:30 ALS Bottle#:10 Worklist Smp#:7
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-007
Misc. Info.:663023
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:43:34 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 13:38:34
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.930 -0.004 87 349180 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.046 12.048 -0.002 93 1623979 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.654 -0.003 84 1464940 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.265 18.265 0.000 97 1063049 4.08 4.06
6 Chlorodifluoromethane 51 4.170 4.170 0.000 97 595275 4.00 3.76
7 Propene 41 4.181 4.183 -0.002 98 301873 4.00 3.96
8 Dichlorodifluoromethane 85 4.246 4.246 0.000 100 831446 4.00 3.62
9 Chloromethane 52 4.466 4.466 0.000 97 51967 4.00 3.65
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.472 4.472 0.000 94 506815 4.00 3.50
11 Acetaldehyde 44 4.649 4.649 0.000 93 298758 20.0 18.4
12 Vinyl chloride 62 4.671 4.671 0.000 100 168302 4.00 3.66
13 Butadiene 54 4.778 4.778 0.000 74 123597 4.00 3.63
14 Butane 43 4.773 4.775 -0.002 83 227720 4.00 3.70
15 Bromomethane 94 5.166 5.169 -0.003 98 175311 4.00 3.51
16 Chloroethane 64 5.338 5.338 0.000 92 71365 4.00 3.55
17 Ethanol 31 5.440 5.445 -0.005 99 385470 20.0 18.8
18 Vinyl bromide 106 5.693 5.693 0.000 98 329700 4.00 3.89
19 2-Methylbutane 43 5.747 5.746 0.001 91 333424 4.00 3.80
20 Trichlorofluoromethane 101 5.999 5.999 0.000 99 988585 4.00 3.78
21 Acrolein 56 6.016 6.015 0.001 96 104398 4.00 3.77
22 Acetonitrile 40 6.091 6.093 -0.002 97 130894 4.00 3.97
23 Acetone 58 6.139 6.139 0.000 98 415025 12.0 11.5
24 Isopropyl alcohol 45 6.231 6.231 0.000 95 1215864 12.0 11.5
25 Pentane 72 6.252 6.252 0.000 94 55366 4.00 3.86
26 Ethyl ether 31 6.435 6.433 0.002 95 354359 4.00 3.86
27 1,1-Dichloroethene 96 6.801 6.804 -0.003 99 352773 4.00 3.82
29 2-Methyl-2-propanol 59 6.909 6.905 0.003 96 612317 4.00 3.92
28 Acrylonitrile 53 6.919 6.925 -0.006 95 224041 4.00 3.81
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.995 6.995 0.000 97 777778 4.00 3.80
31 Methylene Chloride 84 7.194 7.195 -0.001 93 302732 4.00 3.46
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Report Date: 10-Feb-2024 14:43:35 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC08.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.210 7.210 0.000 98 333820 4.00 3.94
33 Carbon disulfide 76 7.382 7.382 0.000 99 941866 4.00 3.77
34 trans-1,2-Dichloroethene 96 8.076 8.076 0.000 98 360978 4.00 3.80
35 2-Methylpentane 43 8.081 8.083 -0.002 93 696345 4.00 3.87
36 Methyl tert-butyl ether 73 8.194 8.191 0.003 96 1003940 4.00 3.93
37 1,1-Dichloroethane 63 8.533 8.535 -0.002 100 622265 4.00 3.78
38 Vinyl acetate 43 8.619 8.623 -0.004 100 776400 4.00 3.93
39 2-Butanone (MEK) 72 9.098 9.098 0.000 99 167651 4.00 3.93
40 Hexane 56 9.125 9.128 -0.003 89 264713 4.00 3.85
41 Isopropyl ether 45 9.281 9.281 0.000 96 1113326 4.00 3.92
42 cis-1,2-Dichloroethene 96 9.571 9.577 -0.006 91 392034 4.00 3.91
43 Ethyl acetate 43 9.733 9.735 -0.002 99 760999 4.00 3.86
44 Chloroform 83 9.932 9.935 -0.003 94 781572 4.00 3.88
45 Tert-butyl ethyl ether 59 9.991 9.991 0.000 95 1097109 4.00 3.99
46 Tetrahydrofuran 42 10.330 10.326 0.004 91 376264 4.00 3.88
47 1,1,1-Trichloroethane 97 10.970 10.972 -0.002 94 876380 4.00 3.84
48 1,2-Dichloroethane 62 11.078 11.079 -0.001 98 508423 4.00 3.84
49 n-Butanol 31 11.449 11.447 0.002 87 147316 4.00 4.08
50 Cyclohexane 69 11.540 11.542 -0.002 78 164465 4.00 3.92
51 Benzene 78 11.546 11.546 0.000 96 1051677 4.00 3.88
52 Carbon tetrachloride 117 11.567 11.569 -0.002 98 967415 4.00 3.94
53 2,3-Dimethylpentane 71 11.632 11.635 -0.003 90 242710 4.00 3.92
54 Thiophene 84 11.809 11.813 -0.004 94 646678 4.00 4.03
55 Isooctane 57 12.245 12.249 -0.004 99 1638057 4.00 3.98
56 n-Heptane 71 12.595 12.596 -0.001 91 363911 4.00 4.04
57 1,2-Dichloropropane 63 12.713 12.713 0.000 88 388083 4.00 3.90
58 Trichloroethene 130 12.740 12.742 -0.002 96 599447 4.00 3.90
59 Dibromomethane 93 12.831 12.835 -0.004 89 488720 4.00 3.87
61 1,4-Dioxane 88 12.955 12.955 0.000 90 167715 4.00 3.99
60 Dichlorobromomethane 83 12.961 12.966 -0.005 99 838624 4.00 4.02
62 Methyl methacrylate 41 13.014 13.014 0.000 95 481338 4.00 3.94
63 Methylcyclohexane 83 13.482 13.484 -0.002 96 683251 4.00 3.96
64 4-Methyl-2-pentanone (MIBK) 43 13.843 13.843 0.000 97 825305 4.00 3.98
65 cis-1,3-Dichloropropene 75 13.918 13.922 -0.004 94 654418 4.00 4.08
66 trans-1,3-Dichloropropene 75 14.591 14.592 -0.001 98 616883 4.00 4.12
67 Toluene 91 14.720 14.723 -0.003 94 1409005 4.00 3.95
68 1,1,2-Trichloroethane 83 14.795 14.795 0.000 96 400326 4.00 3.88
69 2-Hexanone 58 15.134 15.134 0.000 94 425257 4.00 4.00
70 n-Octane 85 15.349 15.353 -0.004 92 426890 4.00 4.01
71 Chlorodibromomethane 129 15.489 15.492 -0.003 98 1003560 4.00 4.11
72 Ethylene Dibromide 107 15.779 15.783 -0.004 98 819527 4.00 4.05
73 Tetrachloroethene 129 15.839 15.840 -0.001 96 571733 4.00 3.85
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 94 1114727 4.00 3.87
75 Chlorobenzene 112 16.699 16.703 -0.004 97 1187858 4.00 3.95
76 Ethylbenzene 91 16.974 16.974 0.000 98 1894974 4.00 4.01
77 m-Xylene & p-Xylene 91 17.124 17.128 -0.004 98 2866532 8.00 7.94
78 n-Nonane 57 17.501 17.504 -0.003 90 806458 4.00 3.98
80 Styrene 104 17.592 17.592 0.000 97 1177518 4.00 4.19
79 Bromoform 173 17.598 17.601 -0.003 97 1012176 4.00 3.63
81 o-Xylene 91 17.652 17.653 -0.001 99 1539124 4.00 3.75
82 1,1,2,2-Tetrachloroethane 83 17.969 17.971 -0.002 100 1110444 4.00 3.89
83 1,2,3-Trichloropropane 110 18.130 18.130 0.000 97 347841 4.00 3.86
3/25/2024
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Report Date: 10-Feb-2024 14:43:35 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC08.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.224 -0.002 95 2339080 4.00 3.82
85 N-Propylbenzene 120 18.749 18.749 0.000 100 702664 4.00 3.97
86 2-Chlorotoluene 126 18.803 18.806 -0.003 96 642261 4.00 3.85
87 4-Ethyltoluene 105 18.894 18.894 0.000 99 2447386 4.00 3.89
88 1,3,5-Trimethylbenzene 120 18.964 18.964 0.000 94 1059187 4.00 3.89
89 Alpha Methyl Styrene 118 19.190 19.194 -0.004 91 1111859 4.00 4.12
90 n-Decane 57 19.217 19.221 -0.004 91 1175634 4.00 3.75
91 tert-Butylbenzene 119 19.389 19.389 0.000 94 2252265 4.00 3.83
92 1,2,4-Trimethylbenzene 105 19.400 19.403 -0.003 95 2015930 4.00 3.84
93 sec-Butylbenzene 105 19.653 19.654 -0.001 99 3024598 4.00 3.85
94 1,3-Dichlorobenzene 146 19.680 19.683 -0.003 95 1567591 4.00 3.79
95 Benzyl chloride 91 19.750 19.753 -0.003 99 1587120 4.00 4.34
96 1,4-Dichlorobenzene 146 19.766 19.769 -0.003 97 1556094 4.00 3.84
97 4-Isopropyltoluene 119 19.809 19.812 -0.003 98 2729643 4.00 3.88
98 1,2,3-Trimethylbenzene 105 19.873 19.875 -0.002 97 2102225 4.00 3.91
99 Butylcyclohexane 83 19.916 19.918 -0.002 96 1537253 4.00 3.87
100 2,3-Dihydroindene 117 20.126 20.126 0.000 95 2031188 4.00 3.84
101 1,2-Dichlorobenzene 146 20.126 20.131 -0.005 99 1521864 4.00 3.77
102 n-Butylbenzene 91 20.239 20.241 -0.002 98 2363203 4.00 3.75
103 Indene 116 20.255 20.259 -0.004 91 1821515 4.00 3.97
104 Undecane 57 20.530 20.530 0.000 95 1422246 4.00 3.63
105 1,2-Dibromo-3-Chloropropane 157 20.745 20.748 -0.003 93 786546 4.00 3.86
106 1,2,4,5-Tetramethylbenzene 119 21.035 21.035 0.000 98 2630761 4.00 3.75
107 Dodecane 57 21.649 21.648 0.001 96 1208671 4.00 3.65
108 1,2,4-Trichlorobenzene 180 21.858 21.860 -0.002 94 911001 4.00 3.89
109 Naphthalene 128 21.966 21.968 -0.002 99 1553693 4.00 3.49
110 Hexachlorobutadiene 225 22.100 22.100 0.000 94 872240 4.00 2.69
111 1,2,3-Trichlorobenzene 180 22.154 22.156 -0.002 95 669030 4.00 3.86
112 2-Methylnaphthalene 142 22.676 22.676 0.000 99 757260 4.00 4.18
113 1-Methylnaphthalene 142 22.805 22.805 0.000 100 800711 4.00 4.00
A 115 C8 Range 1 15.349 (15.301-15.397) 0 3590368 4.00 3.99
S 116 Xylenes, Total 100 0 12.0 11.7
S 117 1,2-Dichloroethene, Total 1 0 8.00 7.71
QC Flag Legend
Processing Flags
Reagents:
40L8DQP_00049 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 584 of 864
Report Date: 10-Feb-2024 14:43:35 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC08.D
Injection Date:07-Feb-2024 18:49:30 Instrument ID:MS Operator ID:
Lims ID:IC L8 Worklist Smp#:7
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:10
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
48
51
54
57
60
63
Y ( X10
0
0
0
0
)
SZB07IC08[MS SCAN Chro]:Total
* C
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3/25/2024
9:50:51 AM
Page 585 of 864
Report Date: 10-Feb-2024 14:43:35 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC08.D
Injection Date:07-Feb-2024 18:49:30 Instrument ID:MS
Lims ID:IC L8
Client ID:
Operator ID:ALS Bottle#:10 Worklist Smp#:7
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.2
Min
0
2
4
6
8
10
12
14
16
18
Y ( X10
0
0
0
0
)
SZB07IC08[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 586 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Lims ID:IC L1
Client ID:
Sample Type:IC Calib Level:1
Inject. Date:07-Feb-2024 20:28:30 ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-009
Misc. Info.:663623
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:43:53 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 07:34:16
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.929 -0.003 80 342835 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.041 12.046 -0.005 93 1604900 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.656 16.655 0.001 85 1420462 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.265 18.265 0.000 96 1010654 4.08 3.98
6 Chlorodifluoromethane 51 4.170 4.170 0.000 95 6365 0.0200 0.0410
7 Propene 41 4.186 4.184 0.002 62 1981 0.0200 0.0265
8 Dichlorodifluoromethane 85 4.251 4.247 0.004 99 5696 0.0200 0.0253
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.477 4.473 0.004 86 3753 0.0200 0.0264
12 Vinyl chloride 62 4.671 4.671 0.000 32 1354 0.0200 0.0300
17 Ethanol 31 5.461 5.449 0.012 95 3940 0.1000 0.1953
18 Vinyl bromide 106 5.693 5.693 0.000 95 2166 0.0200 0.0260
20 Trichlorofluoromethane 101 6.005 6.001 0.004 98 5823 0.0200 0.0227
23 Acetone 58 6.182 6.150 0.032 98 3833 0.0600 0.1080
24 Isopropyl alcohol 45 6.284 6.244 0.040 93 8213 0.0600 0.0751
26 Ethyl ether 31 6.462 6.440 0.022 81 2042 0.0200 0.0226
27 1,1-Dichloroethene 96 6.806 6.805 0.001 95 2399 0.0200 0.0264
29 2-Methyl-2-propanol 59 7.005 6.930 0.075 87 3596 0.0200 0.0235
28 Acrylonitrile 53 6.930 6.926 0.004 73 1682 0.0200 0.0291
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.995 6.995 -0.001 88 4565 0.0200 0.0227
31 Methylene Chloride 84 7.188 7.194 -0.006 94 5395 0.0200 0.0628
32 3-Chloro-1-propene 39 7.215 7.211 0.004 78 2612 0.0200 0.0314
33 Carbon disulfide 76 7.387 7.383 0.004 98 9367 0.0200 0.0382
34 trans-1,2-Dichloroethene 96 8.070 8.074 -0.004 92 2421 0.0200 0.0260
35 2-Methylpentane 43 8.092 8.085 0.007 94 4524 0.0200 0.0256
36 Methyl tert-butyl ether 73 8.264 8.209 0.055 95 6441 0.0200 0.0257
37 1,1-Dichloroethane 63 8.533 8.534 -0.001 95 3389 0.0200 0.0210
38 Vinyl acetate 43 8.635 8.626 0.009 99 4316 0.0200 0.0222
39 2-Butanone (MEK) 72 9.141 9.109 0.032 92 982 0.0200 0.0234
40 Hexane 56 9.130 9.129 0.001 79 1986 0.0200 0.0294
41 Isopropyl ether 45 9.340 9.296 0.044 97 6950 0.0200 0.0249
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Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
42 cis-1,2-Dichloroethene 96 9.582 9.578 0.004 85 2229 0.0200 0.0226
43 Ethyl acetate 43 9.776 9.745 0.031 97 4407 0.0200 0.0228
44 Chloroform 83 9.932 9.934 -0.002 38 4782 0.0200 0.0242
45 Tert-butyl ethyl ether 59 10.050 10.006 0.044 94 5818 0.0200 0.0216
46 Tetrahydrofuran 42 10.400 10.345 0.055 89 2659 0.0200 0.0279
47 1,1,1-Trichloroethane 97 10.970 10.971 -0.001 97 4977 0.0200 0.0222
48 1,2-Dichloroethane 62 11.083 11.080 0.003 94 2834 0.0200 0.0217
49 n-Butanol 31 11.508 11.462 0.046 51 952 0.0200 0.0267
50 Cyclohexane 69 11.546 11.543 0.003 64 1268 0.0200 0.0306
51 Benzene 78 11.540 11.544 -0.004 96 7551 0.0200 0.0282
52 Carbon tetrachloride 117 11.567 11.569 -0.002 96 5210 0.0200 0.0206
53 2,3-Dimethylpentane 71 11.632 11.634 -0.002 90 1690 0.0200 0.0276
54 Thiophene 84 11.804 11.811 -0.007 92 3833 0.0200 0.0242
55 Isooctane 57 12.245 12.248 -0.003 96 9996 0.0200 0.0246
56 n-Heptane 71 12.600 12.597 0.003 87 2339 0.0200 0.0263
57 1,2-Dichloropropane 63 12.713 12.713 0.000 73 2159 0.0200 0.0220
58 Trichloroethene 130 12.740 12.741 -0.001 95 3455 0.0200 0.0227
59 Dibromomethane 93 12.826 12.833 -0.007 87 3844 0.0200 0.0308
61 1,4-Dioxane 88 13.009 12.969 0.040 70 1286 0.0200 0.0310
60 Dichlorobromomethane 83 12.960 12.965 -0.005 98 4287 0.0200 0.0208
62 Methyl methacrylate 41 13.036 13.020 0.016 88 3238 0.0200 0.0268
63 Methylcyclohexane 83 13.477 13.482 -0.005 94 3961 0.0200 0.0225
64 4-Methyl-2-pentanone (MIBK) 43 13.875 13.851 0.024 94 6168 0.0200 0.0301
65 cis-1,3-Dichloropropene 75 13.923 13.922 0.001 93 3365 0.0200 0.0213
66 trans-1,3-Dichloropropene 75 14.590 14.592 -0.002 97 2968 0.0200 0.0204
67 Toluene 91 14.720 14.722 -0.002 93 10190 0.0200 0.0294
68 1,1,2-Trichloroethane 83 14.795 14.795 0.000 93 2210 0.0200 0.0221
69 2-Hexanone 58 15.161 15.141 0.020 94 2291 0.0200 0.0222
70 n-Octane 85 15.349 15.352 -0.003 89 2480 0.0200 0.0240
71 Chlorodibromomethane 129 15.489 15.492 -0.003 94 4114 0.0200 0.0174
72 Ethylene Dibromide 107 15.779 15.782 -0.003 96 4669 0.0200 0.0238
73 Tetrachloroethene 129 15.839 15.840 -0.001 90 3207 0.0200 0.0223
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 87 8547 0.0200 0.0306
75 Chlorobenzene 112 16.699 16.702 -0.003 96 7080 0.0200 0.0243
76 Ethylbenzene 91 16.968 16.972 -0.004 97 11460 0.0200 0.0250
77 m-Xylene & p-Xylene 91 17.124 17.127 -0.003 98 16818 0.0400 0.0480
78 n-Nonane 57 17.501 17.504 -0.003 92 4940 0.0200 0.0252
80 Styrene 104 17.592 17.592 0.000 94 5910 0.0200 0.0217
79 Bromoform 173 17.592 17.599 -0.007 72 3517 0.0200 0.0458
81 o-Xylene 91 17.651 17.653 -0.002 99 9847 0.0200 0.0248
82 1,1,2,2-Tetrachloroethane 83 17.969 17.970 -0.001 98 6389 0.0200 0.0231
83 1,2,3-Trichloropropane 110 18.141 18.133 0.008 97 2103 0.0200 0.0240
84 Isopropylbenzene 105 18.222 18.223 -0.001 87 14687 0.0200 0.0247
85 N-Propylbenzene 120 18.743 18.748 -0.005 99 3968 0.0200 0.0231
86 2-Chlorotoluene 126 18.808 18.807 0.001 96 3602 0.0200 0.0223
87 4-Ethyltoluene 105 18.894 18.894 0.000 98 14305 0.0200 0.0234
88 1,3,5-Trimethylbenzene 120 18.959 18.963 -0.004 93 5945 0.0200 0.0225
89 Alpha Methyl Styrene 118 19.195 19.194 0.001 93 5344 0.0200 0.0204
90 n-Decane 57 19.222 19.221 0.001 94 7036 0.0200 0.0231
91 tert-Butylbenzene 119 19.389 19.389 0.000 93 13446 0.0200 0.0236
92 1,2,4-Trimethylbenzene 105 19.400 19.403 -0.003 94 11976 0.0200 0.0235
93 sec-Butylbenzene 105 19.653 19.654 -0.001 98 17559 0.0200 0.0231
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Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
94 1,3-Dichlorobenzene 146 19.680 19.682 -0.002 94 9813 0.0200 0.0245
95 Benzyl chloride 91 19.755 19.754 0.001 97 7905 0.0200 0.0223
96 1,4-Dichlorobenzene 146 19.771 19.770 0.001 95 9379 0.0200 0.0238
97 4-Isopropyltoluene 119 19.809 19.811 -0.002 97 15354 0.0200 0.0225
98 1,2,3-Trimethylbenzene 105 19.873 19.875 -0.002 96 12263 0.0200 0.0235
99 Butylcyclohexane 83 19.911 19.916 -0.005 87 8819 0.0200 0.0229
100 2,3-Dihydroindene 117 20.121 20.125 -0.004 96 12398 0.0200 0.0242
101 1,2-Dichlorobenzene 146 20.131 20.131 0.000 97 9783 0.0200 0.0250
102 n-Butylbenzene 91 20.239 20.240 -0.001 98 15682 0.0200 0.0257
103 Indene 116 20.255 20.258 -0.003 94 10642 0.0200 0.0239
104 Undecane 57 20.530 20.530 0.000 95 10186 0.0200 0.0268
105 1,2-Dibromo-3-Chloropropane 157 20.745 20.747 -0.002 94 4314 0.0200 0.0218
106 1,2,4,5-Tetramethylbenzene 119 21.030 21.034 -0.004 98 18592 0.0200 0.0274
107 Dodecane 57 21.648 21.648 0.000 95 13406 0.0200 0.0418
108 1,2,4-Trichlorobenzene 180 21.858 21.860 -0.002 93 8103 0.0200 0.0357
109 Naphthalene 128 21.966 21.967 -0.001 99 16229 0.0200 0.0376
110 Hexachlorobutadiene 225 22.095 22.099 -0.004 94 10051 0.0200 0.0319
111 1,2,3-Trichlorobenzene 180 22.154 22.156 -0.002 95 8098 0.0200 0.0482
112 2-Methylnaphthalene 142 22.676 22.676 0.000 99 9258 0.0200 0.0527
113 1-Methylnaphthalene 142 22.805 22.805 0.000 99 11845 0.0200 0.0610
A 115 C8 Range 1 15.360 (15.322-15.397) 0 21994 0.0200 0.0247
S 116 Xylenes, Total 100 0 0.0600 0.0728
S 117 1,2-Dichloroethene, Total 1 0 0.0400 0.0486
QC Flag Legend
Processing Flags
Reagents:
40L1-3DQP_00099 Amount Added: 50.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 589 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS Operator ID:
Lims ID:IC L1 Worklist Smp#:9
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:5
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
Y ( X10
0
0
0
0
)
SZB07IC01[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
9
2
6)
+
* 1
,4-
D
i
f
l
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o
r
o
b
e
n
zen
e
( 1
2
.
0
4
1
)
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6.656)
$ 4
-
B
r
o
m
o
f
l
u
o
r
o
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e
n
zen
e

(Su
r
r
)(
1
8
.
2
65)
3/25/2024
9:50:51 AM
Page 590 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.3
Min
8
9
10
11
12
13
14
15
16
17
18
19
20
Y ( X10
0
0
)
SZB07IC01[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 591 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
19 2-Methylbutane, CAS: 78-78-4
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
)
Raw Spec:Scan 327(5.74)
32
44
57
78 207
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 327(5.74), Qvalue=80
42
43
57
56
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 19 2-Methylbutane (NIST14.L)
43
42
57
56
72
5.4 5.7 6.0
Min
RT
2
4
6
8
10
12
14
Y ( X10
0
)
m/z 43.0

5
.
7
4
1
5.4 5.7 6.0
Min
RT
0
14
28
42
56
70
84
Y ( X10
)
m/z 57.0

5
.
7
3
6
5.4 5.7 6.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
m/z 42.0

5
.
7
4
6
RT Mass Response Amount
5.74 43.00 2389 0.027784
5.74 57.00 1752
5.75 42.00 2381
Reviewer: T5MR, 10-Feb-2024 13:40:00 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 592 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
22 Acetonitrile, CAS: 75-05-8
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
)
Raw Spec:Scan 390(6.08)
32
44
55 78 207
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
)
Enhanced Spec:Scan 390(6.08) Bgrd 386( 6.06), Qvalue=24
40
44
56
78
77
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 22 Acetonitrile (NIST14.L)
41
40
39
5.8 6.1 6.4
Min
RT
39
46
53
60
67
74
Y ( X10
)
m/z 40.0

6.0
8
0
5.8 6.1 6.4
Min
RT
27
42
57
72
87
102
117
Y ( X10
)
m/z 41.0

6.0
9
6
5.8 6.1 6.4
Min
RT
21
30
39
48
57
66
75
Y ( X10
)
m/z 39.0

6.1
0
1
RT Mass Response Amount
6.08 40.00 1185 0.036677
6.10 41.00 1445
6.10 39.00 260
Reviewer: T5MR, 10-Feb-2024 13:40:14 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 593 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
21 Acrolein, CAS: 107-02-8
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
)
Raw Spec:Scan 380(6.03)
32
44
101
56 103 20778
20 40 60 80 100 120 140 160 180 200
m/z
0
8
16
24
32
40
48
56
Y ( X10
)
Enhanced Spec:Scan 380(6.03) Bgrd 371( 5.98), Qvalue=32
101
56
103
6752 9138 115 207
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 21 Acrolein (NIST14.L)
56
55
37
5.7 6.0 6.3
Min
RT
0
10
20
30
40
50
60
Y ( X10
)
m/z 56.0

6.0
2
6
5.7 6.0 6.3
Min
RT
18
27
36
45
54
63
Y ( X10
)
m/z 55.0

6.0
1
5
5.7 6.0 6.3
Min
RT
33
39
45
51
57
63
69
Y ( X10
)
m/z 29.0

6.0
1
0
RT Mass Response Amount
6.03 56.00 708 0.027175
6.02 55.00 257
6.01 29.00 286
Reviewer: T5MR, 10-Feb-2024 13:40:12 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 594 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
15 Bromomethane, CAS: 74-83-9
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
Y ( X10
0
)
Raw Spec:Scan 221(5.17)
44
32
78 9155 94
207115154
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 221(5.17), Qvalue=87
96
93 1158034
16562132
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 15 Bromomethane (NIST14.L)
94 96
93
91
4.9 5.2
Min
RT
0
10
20
30
40
50
60
Y ( X10
)
m/z 94.0

5
.
1
7
1
4.9 5.2
Min
RT
0
10
20
30
40
50
60
Y ( X10
)
m/z 96.0

5
.
1
7
1
4.9 5.2
Min
RT
8
17
26
35
44
53
62
Y ( X10
)
m/z 81.0

5
.
1
65
RT Mass Response Amount
5.17 94.00 1216 0.024789
5.17 96.00 1427
5.17 81.00 645
Reviewer: T5MR, 10-Feb-2024 13:39:38 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 595 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
13 Butadiene, CAS: 106-99-0
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
32
Y ( X10
0
)
Raw Spec:Scan 148(4.78)
44
78
50 91
20796117
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 148(4.78), Qvalue=78
43
39
54
13566
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 13 Butadiene (NIST14.L)
39 54
53
38
4.5 4.8
Min
RT
0
9
18
27
36
45
Y ( X10
)
m/z 54.0

4
.
7
7
8
4.5 4.8
Min
RT
50
63
76
89
102
115
128
Y ( X10
)
m/z 39.0

4
.
7
7
8
4.5 4.8
Min
RT
0
8
16
24
32
40
48
Y ( X10
)
m/z 53.0

4
.
7
8
3
RT Mass Response Amount
4.78 54.00 663 0.019835
4.78 39.00 1005
4.78 53.00 521
Reviewer: T5MR, 10-Feb-2024 13:39:36 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 596 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
16 Chloroethane, CAS: 75-00-3
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
Y ( X10
0
)
Raw Spec:Scan 250(5.33)
44
32
78 91
207115135
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
21
24
Y ( X10
)
Enhanced Spec:Scan 250(5.33) Bgrd 246( 5.31), Qvalue=1
37
19357
68 103
43
135
104
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 16 Chloroethane (NIST14.L)
64
6649
51
5.2 5.5
Min
RT
0
5
10
15
20
25
30
Y ( X10
)
m/z 64.0

5
.
3
2
7
5.2 5.5
Min
RT
87
93
99
105
111
117
Y ( X10
)
m/z 29.0
5.2 5.5
Min
RT
0
6
12
18
24
30
Y ( X10
)
m/z 66.0
RT Mass Response Amount
5.33 64.00 239 0.012124
5.34 29.00 0
5.34 66.00 0
Reviewer: T5MR, 10-Feb-2024 13:39:40 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 597 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
9 Chloromethane, CAS: 74-87-3
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
)
Raw Spec:Scan 86(4.44)
32
44
78
7750 91 207135105
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
Y ( X10
)
Enhanced Spec:Scan 86(4.44) Bgrd 82( 4.42), Qvalue=1
78
65
9452
953236
105
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 9 Chloromethane (NIST14.L)
50
52
4935
4.3
Min
RT
0
7
14
21
28
35
42
Y ( X10
)
m/z 52.0

4
.
4
4
5
4.3
Min
RT
17
31
45
59
73
87
101
Y ( X10
)
m/z 50.0

4
.
4
66
RT Mass Response Amount
4.44 52.00 265 0.018932
4.47 50.00 1929
Reviewer: T5MR, 10-Feb-2024 13:38:59 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 598 of 864
Report Date: 10-Feb-2024 14:43:53 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC01.D
Injection Date:07-Feb-2024 20:28:30 Instrument ID:MS
Lims ID:IC L1
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:9
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
25 Pentane, CAS: 109-66-0
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
)
Raw Spec:Scan 421(6.25)
32
44
57
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 421(6.25), Qvalue=96
43
42
57 72
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 25 Pentane (NIST14.L)
43
42
5739
72
6.1 6.4
Min
RT
0
4
8
12
16
20
Y ( X10
)
m/z 72.0

6.2
4
7
6.1 6.4
Min
RT
28
42
56
70
84
98
112
Y ( X10
)
m/z 41.0

6.2
4
7
6.1 6.4
Min
RT
0
8
16
24
32
40
48
Y ( X10
)
m/z 57.0

6.2
4
1
RT Mass Response Amount
6.25 72.00 375 0.026643
6.25 41.00 2782
6.24 57.00 1807
Reviewer: T5MR, 10-Feb-2024 13:40:19 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 599 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Lims ID:IC L2
Client ID:
Sample Type:IC Calib Level:2
Inject. Date:07-Feb-2024 21:19:30 ALS Bottle#:5 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-010
Misc. Info.:663623
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:44:11 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 13:44:01
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.929 -0.003 81 334795 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.041 12.045 -0.004 93 1564659 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.654 -0.003 85 1386594 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.259 18.264 -0.005 96 996445 4.08 4.02
6 Chlorodifluoromethane 51 4.170 4.170 0.000 96 7838 0.0400 0.0517
7 Propene 41 4.186 4.184 0.002 98 4046 0.0400 0.0554
8 Dichlorodifluoromethane 85 4.246 4.247 -0.001 99 9625 0.0400 0.0437
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.471 4.473 -0.002 85 6618 0.0400 0.0477
11 Acetaldehyde 44 4.660 4.652 0.008 91 5340 0.2000 0.3425
12 Vinyl chloride 62 4.671 4.671 0.000 94 1992 0.0400 0.0452
15 Bromomethane 94 5.171 5.170 0.001 95 2328 0.0400 0.0486
17 Ethanol 31 5.467 5.453 0.014 99 6646 0.2000 0.3374
18 Vinyl bromide 106 5.693 5.693 0.000 96 3700 0.0400 0.0455
19 2-Methylbutane 43 5.746 5.746 0.000 89 4051 0.0400 0.0482
20 Trichlorofluoromethane 101 5.999 6.000 -0.001 99 10169 0.0400 0.0405
23 Acetone 58 6.177 6.155 0.022 98 5967 0.1200 0.1722
25 Pentane 72 6.241 6.249 -0.008 94 598 0.0400 0.0435
24 Isopropyl alcohol 45 6.284 6.252 0.032 93 13370 0.1200 0.1252
26 Ethyl ether 31 6.467 6.446 0.021 92 3518 0.0400 0.0399
27 1,1-Dichloroethene 96 6.801 6.804 -0.003 97 3858 0.0400 0.0435
28 Acrylonitrile 53 6.935 6.928 0.007 98 2886 0.0400 0.0511
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 7.000 6.996 0.004 91 8015 0.0400 0.0409
29 2-Methyl-2-propanol 59 6.995 6.943 0.051 86 6393 0.0400 0.0427
31 Methylene Chloride 84 7.194 7.194 0.000 91 6807 0.0400 0.0811
32 3-Chloro-1-propene 39 7.215 7.212 0.003 78 3584 0.0400 0.0441
33 Carbon disulfide 76 7.387 7.384 0.003 98 13018 0.0400 0.0543
34 trans-1,2-Dichloroethene 96 8.081 8.076 0.005 95 4094 0.0400 0.0450
35 2-Methylpentane 43 8.087 8.086 0.001 88 7081 0.0400 0.0410
36 Methyl tert-butyl ether 73 8.259 8.219 0.040 96 10473 0.0400 0.0427
37 1,1-Dichloroethane 63 8.528 8.533 -0.005 97 6780 0.0400 0.0430
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Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
38 Vinyl acetate 43 8.635 8.628 0.007 99 7574 0.0400 0.0400
40 Hexane 56 9.136 9.130 0.006 74 3204 0.0400 0.0486
39 2-Butanone (MEK) 72 9.146 9.116 0.030 85 1599 0.0400 0.0391
41 Isopropyl ether 45 9.329 9.302 0.027 95 11510 0.0400 0.0423
42 cis-1,2-Dichloroethene 96 9.571 9.577 -0.006 92 3916 0.0400 0.0407
43 Ethyl acetate 43 9.765 9.749 0.016 99 7030 0.0400 0.0372
44 Chloroform 83 9.932 9.934 -0.002 28 8270 0.0400 0.0428
45 Tert-butyl ethyl ether 59 10.039 10.012 0.027 94 10319 0.0400 0.0392
46 Tetrahydrofuran 42 10.384 10.352 0.032 93 4467 0.0400 0.0481
47 1,1,1-Trichloroethane 97 10.970 10.971 -0.001 96 8957 0.0400 0.0409
48 1,2-Dichloroethane 62 11.078 11.080 -0.002 97 5523 0.0400 0.0433
49 n-Butanol 31 11.497 11.469 0.028 30 1689 0.0400 0.0485
51 Benzene 78 11.540 11.543 -0.003 97 12112 0.0400 0.0464
50 Cyclohexane 69 11.540 11.542 -0.002 61 2131 0.0400 0.0527
52 Carbon tetrachloride 117 11.567 11.568 -0.001 96 9263 0.0400 0.0375
53 2,3-Dimethylpentane 71 11.632 11.634 -0.002 89 2689 0.0400 0.0451
54 Thiophene 84 11.804 11.809 -0.005 93 6607 0.0400 0.0427
55 Isooctane 57 12.245 12.247 -0.002 98 17012 0.0400 0.0429
56 n-Heptane 71 12.595 12.597 -0.002 93 3719 0.0400 0.0429
57 1,2-Dichloropropane 63 12.713 12.713 0.000 82 4075 0.0400 0.0425
58 Trichloroethene 130 12.740 12.741 -0.001 95 5947 0.0400 0.0401
59 Dibromomethane 93 12.831 12.832 -0.001 89 6117 0.0400 0.0503
60 Dichlorobromomethane 83 12.960 12.964 -0.004 98 7849 0.0400 0.0390
61 1,4-Dioxane 88 13.014 12.978 0.036 73 1859 0.0400 0.0459
62 Methyl methacrylate 41 13.025 13.021 0.004 94 5048 0.0400 0.0429
63 Methylcyclohexane 83 13.482 13.482 0.000 95 6854 0.0400 0.0400
64 4-Methyl-2-pentanone (MIBK) 43 13.875 13.856 0.019 94 8372 0.0400 0.0419
65 cis-1,3-Dichloropropene 75 13.923 13.922 0.001 96 6174 0.0400 0.0400
66 trans-1,3-Dichloropropene 75 14.590 14.592 -0.002 97 5392 0.0400 0.0380
67 Toluene 91 14.720 14.722 -0.002 94 16069 0.0400 0.0476
68 1,1,2-Trichloroethane 83 14.790 14.794 -0.004 95 4051 0.0400 0.0415
69 2-Hexanone 58 15.155 15.144 0.011 94 4049 0.0400 0.0402
70 n-Octane 85 15.349 15.351 -0.002 92 4210 0.0400 0.0418
71 Chlorodibromomethane 129 15.494 15.492 0.002 96 7732 0.0400 0.0335
72 Ethylene Dibromide 107 15.779 15.782 -0.003 96 7791 0.0400 0.0407
73 Tetrachloroethene 129 15.844 15.841 0.003 95 5872 0.0400 0.0418
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 96 12882 0.0400 0.0473
75 Chlorobenzene 112 16.699 16.701 -0.002 94 11941 0.0400 0.0419
76 Ethylbenzene 91 16.968 16.971 -0.003 98 18615 0.0400 0.0416
77 m-Xylene & p-Xylene 91 17.124 17.126 -0.002 98 28968 0.0800 0.0848
78 n-Nonane 57 17.501 17.503 -0.002 86 8478 0.0400 0.0443
80 Styrene 104 17.587 17.591 -0.004 97 10463 0.0400 0.0393
79 Bromoform 173 17.592 17.598 -0.006 74 6505 0.0400 0.0574
81 o-Xylene 91 17.651 17.653 -0.002 99 16509 0.0400 0.0426
82 1,1,2,2-Tetrachloroethane 83 17.969 17.970 -0.001 99 10866 0.0400 0.0402
83 1,2,3-Trichloropropane 110 18.130 18.132 -0.002 95 3363 0.0400 0.0394
84 Isopropylbenzene 105 18.222 18.223 -0.001 89 24278 0.0400 0.0419
85 N-Propylbenzene 120 18.749 18.748 0.001 100 6460 0.0400 0.0386
86 2-Chlorotoluene 126 18.803 18.806 -0.003 96 6342 0.0400 0.0401
87 4-Ethyltoluene 105 18.889 18.893 -0.004 98 23650 0.0400 0.0397
88 1,3,5-Trimethylbenzene 120 18.959 18.962 -0.003 93 10359 0.0400 0.0402
89 Alpha Methyl Styrene 118 19.190 19.193 -0.003 90 8996 0.0400 0.0352
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Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
90 n-Decane 57 19.217 19.220 -0.003 92 12132 0.0400 0.0409
91 tert-Butylbenzene 119 19.384 19.388 -0.004 94 23461 0.0400 0.0422
92 1,2,4-Trimethylbenzene 105 19.400 19.402 -0.002 94 20556 0.0400 0.0413
93 sec-Butylbenzene 105 19.653 19.654 -0.001 98 30867 0.0400 0.0415
94 1,3-Dichlorobenzene 146 19.685 19.683 0.002 96 16320 0.0400 0.0417
95 Benzyl chloride 91 19.749 19.753 -0.004 98 12358 0.0400 0.0357
96 1,4-Dichlorobenzene 146 19.766 19.769 -0.003 96 15174 0.0400 0.0395
97 4-Isopropyltoluene 119 19.809 19.811 -0.002 98 27607 0.0400 0.0414
98 1,2,3-Trimethylbenzene 105 19.868 19.873 -0.005 96 22009 0.0400 0.0432
99 Butylcyclohexane 83 19.911 19.915 -0.004 96 16832 0.0400 0.0448
100 2,3-Dihydroindene 117 20.121 20.124 -0.003 95 20888 0.0400 0.0417
101 1,2-Dichlorobenzene 146 20.126 20.130 -0.004 96 16808 0.0400 0.0440
102 n-Butylbenzene 91 20.239 20.240 -0.001 98 24765 0.0400 0.0416
103 Indene 116 20.255 20.257 -0.002 92 17212 0.0400 0.0396
104 Undecane 57 20.530 20.530 0.000 95 18190 0.0400 0.0490
105 1,2-Dibromo-3-Chloropropane 157 20.745 20.747 -0.002 95 6998 0.0400 0.0363
106 1,2,4,5-Tetramethylbenzene 119 21.035 21.034 0.001 97 31656 0.0400 0.0477
107 Dodecane 57 21.648 21.648 0.000 95 23889 0.0400 0.0763
108 1,2,4-Trichlorobenzene 180 21.858 21.859 -0.001 93 11684 0.0400 0.0527
109 Naphthalene 128 21.966 21.967 -0.001 99 22277 0.0400 0.0529
110 Hexachlorobutadiene 225 22.095 22.098 -0.003 94 16684 0.0400 0.0543
111 1,2,3-Trichlorobenzene 180 22.154 22.155 -0.001 96 11265 0.0400 0.0687
112 2-Methylnaphthalene 142 22.676 22.676 0.000 99 11836 0.0400 0.0690
113 1-Methylnaphthalene 142 22.805 22.805 0.000 99 16392 0.0400 0.0864
A 115 C8 Range 1 15.349 (15.306-15.392) 0 38596 0.0400 0.0445
S 116 Xylenes, Total 100 0 0.1200 0.1273
S 117 1,2-Dichloroethene, Total 1 0 0.0800 0.0857
QC Flag Legend
Processing Flags
Reagents:
40L1-3DQP_00099 Amount Added: 100.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Page 602 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Injection Date:07-Feb-2024 21:19:30 Instrument ID:MS Operator ID:
Lims ID:IC L2 Worklist Smp#:10
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:5
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
Y ( X10
0
0
0
0
)
SZB07IC02[MS SCAN Chro]:Total
* C
h
l
o
r
o
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3/25/2024
9:50:51 AM
Page 603 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Injection Date:07-Feb-2024 21:19:30 Instrument ID:MS
Lims ID:IC L2
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.2
Min
7
9
11
13
15
17
19
21
23
25
27
Y ( X10
0
0
)
SZB07IC02[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 604 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Injection Date:07-Feb-2024 21:19:30 Instrument ID:MS
Lims ID:IC L2
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
22 Acetonitrile, CAS: 75-05-8
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
7
14
21
28
35
42
49
56
Y ( X10
0
)
Raw Spec:Scan 397(6.12)
32
44
78
20 40 60 80 100 120 140 160 180 200
m/z
0
3
6
9
12
15
18
Y ( X10
)
Enhanced Spec:Scan 397(6.12) Bgrd 392( 6.09), Qvalue=75
5641 73
40
91
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 22 Acetonitrile (NIST14.L)
41
40
39
5.9
Min
RT
39
49
59
69
79
89
99
Y ( X10
)
m/z 40.0

6.1
1
8
5.9
Min
RT
2
4
6
8
10
12
14
Y ( X10
0
)
m/z 41.0

6.0
9
6
5.9
Min
RT
22
30
38
46
54
62
70
Y ( X10
)
m/z 39.0

6.1
0
7
RT Mass Response Amount
6.12 40.00 453 0.014358
6.10 41.00 3207
6.11 39.00 603
Reviewer: T5MR, 10-Feb-2024 13:43:04 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 605 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Injection Date:07-Feb-2024 21:19:30 Instrument ID:MS
Lims ID:IC L2
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
21 Acrolein, CAS: 107-02-8
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
)
Raw Spec:Scan 378(6.02)
32
101
10344
56 10578
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 378(6.02), Qvalue=25
101
103
66 1054731
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 21 Acrolein (NIST14.L)
56
55
37
5.7 6.0 6.3
Min
RT
0
10
20
30
40
50
60
Y ( X10
)
m/z 56.0

6.0
1
5
5.7 6.0 6.3
Min
RT
0
9
18
27
36
45
54
Y ( X10
)
m/z 55.0

6.0
3
7
5.7 6.0 6.3
Min
RT
33
46
59
72
85
98
111
Y ( X10
)
m/z 29.0

6.0
1
5
RT Mass Response Amount
6.02 56.00 1828 0.071848
6.04 55.00 748
6.02 29.00 498
Reviewer: T5MR, 10-Feb-2024 13:43:08 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 606 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Injection Date:07-Feb-2024 21:19:30 Instrument ID:MS
Lims ID:IC L2
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
13 Butadiene, CAS: 106-99-0
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
)
Raw Spec:Scan 149(4.78)
44
7854
57 84 207105153135179
20 40 60 80 100 120 140 160 180 200
m/z
0
2
4
6
8
10
Y ( X10
0
)
Amdis Enhanced Spec: Scan 149(4.78), Qvalue=76
43
54
55 77 95
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 13 Butadiene (NIST14.L)
39 54
53
38
4.4 4.7 5.0
Min
RT
0
12
24
36
48
60
72
Y ( X10
)
m/z 54.0

4
.
7
8
4
4.4 4.7 5.0
Min
RT
5
8
11
14
17
20
Y ( X10
0
)
m/z 39.0

4
.
7
7
8
4.4 4.7 5.0
Min
RT
0
11
22
33
44
55
66
Y ( X10
)
m/z 53.0

4
.
7
8
4
RT Mass Response Amount
4.78 54.00 2079 0.063691
4.78 39.00 2272
4.78 53.00 2142
Reviewer: T5MR, 10-Feb-2024 13:43:42 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 607 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Injection Date:07-Feb-2024 21:19:30 Instrument ID:MS
Lims ID:IC L2
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
16 Chloroethane, CAS: 75-00-3
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
)
Raw Spec:Scan 253(5.34)
44
32
78
55 91 207115
20 40 60 80 100 120 140 160 180 200
m/z
0
7
14
21
28
35
42
49
Y ( X10
)
Enhanced Spec:Scan 253(5.34) Bgrd 244( 5.29), Qvalue=49
64
74
11933 207154
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 16 Chloroethane (NIST14.L)
64
6649
51
5.1 5.4
Min
RT
0
8
16
24
32
40
48
Y ( X10
)
m/z 64.0

5
.
3
4
3
5.1 5.4
Min
RT
6
8
10
12
14
16
Y ( X10
0
)
m/z 29.0
5.1 5.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
)
m/z 66.0

5
.
3
4
3
RT Mass Response Amount
5.34 64.00 1048 0.054441
5.34 29.00 0
5.34 66.00 602
Reviewer: T5MR, 10-Feb-2024 13:43:31 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 608 of 864
Report Date: 10-Feb-2024 14:44:11 Chrom Revision: 2.3 02-Feb-2024 10:24:08
User Disabled Compound Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC02.D
Injection Date:07-Feb-2024 21:19:30 Instrument ID:MS
Lims ID:IC L2
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:10
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
9 Chloromethane, CAS: 74-87-3
Processing Results
20 40 60 80 100 120 140 160 180 200
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
)
Raw Spec:Scan 90(4.47)
8532
135
44
87
78 137
52 101 20777103151
20 40 60 80 100 120 140 160 180 200
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 90(4.47), Qvalue=49
85
135
8750 137
101
31 10366 1516935
20 40 60 80 100 120 140 160 180 200
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 9 Chloromethane (NIST14.L)
50
52
4935
4.3 4.6
Min
RT
0
9
18
27
36
45
54
Y ( X10
)
m/z 52.0

4
.
4
66
4.3 4.6
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
m/z 50.0

4
.
4
7
1
RT Mass Response Amount
4.47 52.00 279 0.020411
4.47 50.00 2359
Reviewer: T5MR, 10-Feb-2024 13:43:49 -05:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
3/25/2024
9:50:51 AM
Page 609 of 864
Report Date: 10-Feb-2024 14:44:31 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC03.D
Lims ID:IC L3
Client ID:
Sample Type:IC Calib Level:3
Inject. Date:07-Feb-2024 22:11:30 ALS Bottle#:5 Worklist Smp#:11
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-011
Misc. Info.:663623
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:44:30 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 13:49:11
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.928 -0.002 81 329376 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.041 12.044 -0.003 93 1541660 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.654 -0.003 85 1365261 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.259 18.263 -0.004 96 985904 4.08 4.04
6 Chlorodifluoromethane 51 4.170 4.170 0.000 96 13542 0.0800 0.0907
7 Propene 41 4.192 4.185 0.007 98 6909 0.0800 0.0961
8 Dichlorodifluoromethane 85 4.246 4.246 0.000 100 16856 0.0800 0.0778
9 Chloromethane 52 4.472 4.467 0.005 53 1749 0.0800 0.1301
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.472 4.472 0.000 85 10750 0.0800 0.0787
11 Acetaldehyde 44 4.649 4.651 -0.002 93 9689 0.4000 0.6317
12 Vinyl chloride 62 4.676 4.671 0.005 95 3783 0.0800 0.0873
14 Butane 43 4.778 4.775 0.003 85 5200 0.0800 0.0895
13 Butadiene 54 4.773 4.777 -0.004 74 2991 0.0800 0.0931
15 Bromomethane 94 5.165 5.169 -0.004 94 4429 0.0800 0.0940
16 Chloroethane 64 5.338 5.338 0.000 71 1857 0.0800 0.0981
17 Ethanol 31 5.461 5.454 0.007 98 11592 0.4000 0.5982
18 Vinyl bromide 106 5.698 5.694 0.004 98 6572 0.0800 0.0821
19 2-Methylbutane 43 5.746 5.746 0.000 88 7173 0.0800 0.0867
20 Trichlorofluoromethane 101 6.005 6.001 0.004 99 20006 0.0800 0.0810
21 Acrolein 56 6.026 6.018 0.008 26 2004 0.0800 0.0767
22 Acetonitrile 40 6.096 6.093 0.003 96 3294 0.0800 0.1060
23 Acetone 58 6.177 6.159 0.018 98 10313 0.2400 0.3026
25 Pentane 72 6.247 6.249 -0.002 97 1073 0.0800 0.0793
24 Isopropyl alcohol 45 6.284 6.258 0.026 98 24631 0.2400 0.2346
26 Ethyl ether 31 6.467 6.449 0.018 94 7066 0.0800 0.0815
27 1,1-Dichloroethene 96 6.806 6.804 0.002 98 7350 0.0800 0.0843
28 Acrylonitrile 53 6.930 6.928 0.002 95 4474 0.0800 0.0806
29 2-Methyl-2-propanol 59 6.995 6.951 0.044 81 12062 0.0800 0.0819
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 7.000 6.996 0.004 91 15581 0.0800 0.0807
31 Methylene Chloride 84 7.188 7.193 -0.005 93 9489 0.0800 0.1150
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Report Date: 10-Feb-2024 14:44:31 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC03.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.210 7.212 -0.002 98 8749 0.0800 0.1095
33 Carbon disulfide 76 7.382 7.384 -0.002 99 21356 0.0800 0.0905
34 trans-1,2-Dichloroethene 96 8.070 8.075 -0.005 94 7792 0.0800 0.0870
35 2-Methylpentane 43 8.087 8.086 0.001 93 14224 0.0800 0.0837
36 Methyl tert-butyl ether 73 8.248 8.224 0.024 95 19733 0.0800 0.0818
37 1,1-Dichloroethane 63 8.528 8.532 -0.004 100 12560 0.0800 0.0809
38 Vinyl acetate 43 8.635 8.629 0.006 99 15076 0.0800 0.0809
40 Hexane 56 9.130 9.130 0.000 74 5660 0.0800 0.0872
39 2-Butanone (MEK) 72 9.141 9.120 0.021 90 3289 0.0800 0.0817
41 Isopropyl ether 45 9.324 9.306 0.018 96 21266 0.0800 0.0794
42 cis-1,2-Dichloroethene 96 9.577 9.577 0.000 89 7854 0.0800 0.0830
43 Ethyl acetate 43 9.765 9.752 0.013 98 15889 0.0800 0.0855
44 Chloroform 83 9.932 9.934 -0.002 29 15418 0.0800 0.0811
45 Tert-butyl ethyl ether 59 10.034 10.016 0.018 95 20227 0.0800 0.0780
46 Tetrahydrofuran 42 10.378 10.357 0.021 89 7394 0.0800 0.0809
47 1,1,1-Trichloroethane 97 10.975 10.972 0.003 95 17057 0.0800 0.0792
48 1,2-Dichloroethane 62 11.072 11.079 -0.007 96 9837 0.0800 0.0783
49 n-Butanol 31 11.503 11.475 0.028 66 2896 0.0800 0.0844
51 Benzene 78 11.540 11.543 -0.003 96 23020 0.0800 0.0895
50 Cyclohexane 69 11.535 11.541 -0.006 63 3371 0.0800 0.0847
52 Carbon tetrachloride 117 11.562 11.567 -0.005 95 18255 0.0800 0.0751
53 2,3-Dimethylpentane 71 11.632 11.634 -0.002 90 4935 0.0800 0.0839
54 Thiophene 84 11.809 11.809 0.000 95 11881 0.0800 0.0780
55 Isooctane 57 12.245 12.247 -0.002 98 31759 0.0800 0.0812
56 n-Heptane 71 12.589 12.596 -0.007 92 6585 0.0800 0.0771
57 1,2-Dichloropropane 63 12.713 12.713 0.000 86 7558 0.0800 0.0800
58 Trichloroethene 130 12.740 12.741 -0.001 96 11687 0.0800 0.0800
59 Dibromomethane 93 12.826 12.831 -0.005 90 11095 0.0800 0.0926
60 Dichlorobromomethane 83 12.960 12.963 -0.003 99 14923 0.0800 0.0753
61 1,4-Dioxane 88 12.998 12.981 0.017 84 3490 0.0800 0.0875
62 Methyl methacrylate 41 13.025 13.021 0.004 93 8291 0.0800 0.0716
63 Methylcyclohexane 83 13.482 13.482 0.000 93 12535 0.0800 0.0742
64 4-Methyl-2-pentanone (MIBK) 43 13.870 13.858 0.012 97 16048 0.0800 0.0815
65 cis-1,3-Dichloropropene 75 13.918 13.922 -0.004 93 11102 0.0800 0.0730
66 trans-1,3-Dichloropropene 75 14.591 14.591 -0.001 98 10486 0.0800 0.0751
67 Toluene 91 14.720 14.721 -0.001 94 28566 0.0800 0.0859
68 1,1,2-Trichloroethane 83 14.795 14.794 0.001 97 7894 0.0800 0.0821
69 2-Hexanone 58 15.155 15.145 0.010 93 7091 0.0800 0.0715
70 n-Octane 85 15.349 15.351 -0.002 91 7650 0.0800 0.0772
71 Chlorodibromomethane 129 15.489 15.492 -0.003 98 14855 0.0800 0.0653
72 Ethylene Dibromide 107 15.774 15.780 -0.006 97 14679 0.0800 0.0778
73 Tetrachloroethene 129 15.839 15.840 -0.001 96 11250 0.0800 0.0814
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 95 24756 0.0800 0.0923
75 Chlorobenzene 112 16.699 16.701 -0.002 96 22997 0.0800 0.0820
76 Ethylbenzene 91 16.974 16.972 0.002 98 35317 0.0800 0.0802
77 m-Xylene & p-Xylene 91 17.124 17.126 -0.002 98 54705 0.1600 0.1626
78 n-Nonane 57 17.501 17.503 -0.002 88 15369 0.0800 0.0815
80 Styrene 104 17.587 17.590 -0.003 97 19797 0.0800 0.0755
79 Bromoform 173 17.598 17.598 0.000 93 11541 0.0800 0.0769
81 o-Xylene 91 17.651 17.652 -0.001 99 29980 0.0800 0.0785
82 1,1,2,2-Tetrachloroethane 83 17.969 17.970 -0.001 98 21084 0.0800 0.0793
83 1,2,3-Trichloropropane 110 18.130 18.132 -0.002 97 6447 0.0800 0.0767
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Report Date: 10-Feb-2024 14:44:31 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC03.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.223 -0.001 93 45312 0.0800 0.0794
85 N-Propylbenzene 120 18.749 18.748 0.001 99 12596 0.0800 0.0764
86 2-Chlorotoluene 126 18.803 18.805 -0.002 96 12762 0.0800 0.0820
87 4-Ethyltoluene 105 18.894 18.893 0.001 98 45689 0.0800 0.0779
88 1,3,5-Trimethylbenzene 120 18.964 18.962 0.002 94 20168 0.0800 0.0795
89 Alpha Methyl Styrene 118 19.195 19.194 0.001 90 17332 0.0800 0.0689
90 n-Decane 57 19.217 19.220 -0.003 92 24921 0.0800 0.0853
91 tert-Butylbenzene 119 19.389 19.388 0.001 96 44252 0.0800 0.0808
92 1,2,4-Trimethylbenzene 105 19.400 19.402 -0.002 95 39392 0.0800 0.0804
93 sec-Butylbenzene 105 19.653 19.654 -0.001 99 59219 0.0800 0.0809
94 1,3-Dichlorobenzene 146 19.685 19.683 0.002 96 29989 0.0800 0.0779
95 Benzyl chloride 91 19.750 19.752 -0.002 99 22721 0.0800 0.0666
96 1,4-Dichlorobenzene 146 19.766 19.768 -0.002 97 30798 0.0800 0.0815
97 4-Isopropyltoluene 119 19.809 19.810 -0.001 98 52109 0.0800 0.0794
98 1,2,3-Trimethylbenzene 105 19.868 19.872 -0.004 97 40815 0.0800 0.0814
99 Butylcyclohexane 83 19.916 19.915 0.001 94 31473 0.0800 0.0851
100 2,3-Dihydroindene 117 20.121 20.123 -0.002 95 39725 0.0800 0.0806
101 1,2-Dichlorobenzene 146 20.126 20.130 -0.004 98 29787 0.0800 0.0791
102 n-Butylbenzene 91 20.239 20.240 -0.001 98 47280 0.0800 0.0806
103 Indene 116 20.255 20.257 -0.002 90 32153 0.0800 0.0752
104 Undecane 57 20.530 20.530 0.000 95 34995 0.0800 0.0958
105 1,2-Dibromo-3-Chloropropane 157 20.745 20.747 -0.002 94 12105 0.0800 0.0637
106 1,2,4,5-Tetramethylbenzene 119 21.030 21.033 -0.003 98 58541 0.0800 0.0896
107 Dodecane 57 21.649 21.648 0.000 95 46039 0.0800 0.1493
108 1,2,4-Trichlorobenzene 180 21.858 21.859 -0.001 94 19199 0.0800 0.0879
109 Naphthalene 128 21.966 21.967 -0.001 99 39224 0.0800 0.0946
110 Hexachlorobutadiene 225 22.095 22.098 -0.003 93 32067 0.0800 0.1060
111 1,2,3-Trichlorobenzene 180 22.154 22.155 -0.001 95 19986 0.0800 0.1237
112 2-Methylnaphthalene 142 22.676 22.676 0.000 98 19306 0.0800 0.1144
113 1-Methylnaphthalene 142 22.805 22.805 0.000 100 25450 0.0800 0.1363
A 115 C8 Range 1 15.349 (15.317-15.392) 0 71244 0.0800 0.0834
S 116 Xylenes, Total 100 0 0.2400 0.2410
S 117 1,2-Dichloroethene, Total 1 0 0.1600 0.1700
QC Flag Legend
Processing Flags
Reagents:
40L1-3DQP_00099 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
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Page 612 of 864
Report Date: 10-Feb-2024 14:44:31 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC03.D
Injection Date:07-Feb-2024 22:11:30 Instrument ID:MS Operator ID:
Lims ID:IC L3 Worklist Smp#:11
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:5
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
Y ( X10
0
0
0
0
)
SZB07IC03[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
9
2
6)
+
* 1
,4-
D
i
f
l
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r
o
b
e
n
zen
e
( 1
2
.
0
4
1
)
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6.651
)
$ 4
-
B
r
o
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e

(Su
r
r
)(
1
8
.
2
65)
3/25/2024
9:50:51 AM
Page 613 of 864
Report Date: 10-Feb-2024 14:44:31 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC03.D
Injection Date:07-Feb-2024 22:11:30 Instrument ID:MS
Lims ID:IC L3
Client ID:
Operator ID:ALS Bottle#:5 Worklist Smp#:11
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.3
Min
7
10
13
16
19
22
25
28
31
34
37
40
43
46
Y ( X10
0
0
)
SZB07IC03[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 614 of 864
Report Date: 10-Feb-2024 14:44:52 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC04.D
Lims ID:IC L4
Client ID:
Sample Type:IC Calib Level:4
Inject. Date:07-Feb-2024 23:02:30 ALS Bottle#:6 Worklist Smp#:12
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-012
Misc. Info.:663622
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:44:51 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 13:50:16
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.928 -0.002 82 319640 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.041 12.044 -0.003 93 1500663 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.653 -0.002 85 1336701 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.259 18.262 -0.003 96 967645 4.08 4.05
6 Chlorodifluoromethane 51 4.170 4.170 0.000 97 24831 0.1600 0.1715
7 Propene 41 4.186 4.186 0.000 97 12398 0.1600 0.1777
8 Dichlorodifluoromethane 85 4.246 4.246 0.000 100 34386 0.1600 0.1635
9 Chloromethane 52 4.466 4.467 -0.001 48 2347 0.1600 0.1799
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.472 4.472 0.000 86 21784 0.1600 0.1643
11 Acetaldehyde 44 4.654 4.652 0.002 92 16701 0.8000 1.12
12 Vinyl chloride 62 4.671 4.671 0.000 99 6974 0.1600 0.1658
13 Butadiene 54 4.784 4.778 0.006 72 5869 0.1600 0.1883
14 Butane 43 4.778 4.776 0.002 84 9920 0.1600 0.1760
15 Bromomethane 94 5.171 5.169 0.002 96 7832 0.1600 0.1713
16 Chloroethane 64 5.338 5.338 0.000 86 3409 0.1600 0.1855
17 Ethanol 31 5.461 5.455 0.006 99 17869 0.8000 0.9502
18 Vinyl bromide 106 5.687 5.693 -0.006 95 12922 0.1600 0.1664
19 2-Methylbutane 43 5.747 5.746 0.001 89 13466 0.1600 0.1677
20 Trichlorofluoromethane 101 6.005 6.002 0.003 99 39216 0.1600 0.1636
21 Acrolein 56 6.026 6.020 0.006 90 4990 0.1600 0.1968
22 Acetonitrile 40 6.096 6.094 0.002 98 4948 0.1600 0.1640
23 Acetone 58 6.161 6.159 0.002 99 19523 0.4800 0.5902
25 Pentane 72 6.252 6.249 0.003 96 2285 0.1600 0.1741
24 Isopropyl alcohol 45 6.274 6.260 0.014 96 48250 0.4800 0.4740
26 Ethyl ether 31 6.457 6.450 0.007 94 14092 0.1600 0.1675
27 1,1-Dichloroethene 96 6.801 6.804 -0.003 99 14169 0.1600 0.1674
28 Acrylonitrile 53 6.930 6.928 0.002 94 9418 0.1600 0.1748
29 2-Methyl-2-propanol 59 6.978 6.955 0.023 95 23787 0.1600 0.1665
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.989 6.995 -0.006 94 30832 0.1600 0.1646
31 Methylene Chloride 84 7.194 7.193 0.001 94 15103 0.1600 0.1886
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Page 615 of 864
Report Date: 10-Feb-2024 14:44:52 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC04.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.204 7.210 -0.006 97 12685 0.1600 0.1636
33 Carbon disulfide 76 7.382 7.383 -0.001 99 39285 0.1600 0.1716
34 trans-1,2-Dichloroethene 96 8.076 8.075 0.001 92 14148 0.1600 0.1627
35 2-Methylpentane 43 8.081 8.085 -0.004 93 27891 0.1600 0.1691
36 Methyl tert-butyl ether 73 8.237 8.226 0.011 96 38289 0.1600 0.1635
37 1,1-Dichloroethane 63 8.528 8.532 -0.004 100 25347 0.1600 0.1682
38 Vinyl acetate 43 8.635 8.630 0.005 100 30996 0.1600 0.1713
40 Hexane 56 9.130 9.130 0.000 70 10598 0.1600 0.1683
39 2-Butanone (MEK) 72 9.120 9.120 0.000 85 6466 0.1600 0.1656
41 Isopropyl ether 45 9.313 9.307 0.006 96 43244 0.1600 0.1664
42 cis-1,2-Dichloroethene 96 9.571 9.576 -0.005 91 15004 0.1600 0.1634
43 Ethyl acetate 43 9.765 9.753 0.012 99 29919 0.1600 0.1660
44 Chloroform 83 9.932 9.933 -0.001 31 30768 0.1600 0.1667
45 Tert-butyl ethyl ether 59 10.023 10.017 0.006 95 40348 0.1600 0.1604
46 Tetrahydrofuran 42 10.373 10.359 0.014 93 14533 0.1600 0.1638
47 1,1,1-Trichloroethane 97 10.965 10.971 -0.006 94 34512 0.1600 0.1652
48 1,2-Dichloroethane 62 11.078 11.078 0.000 97 20018 0.1600 0.1636
49 n-Butanol 31 11.492 11.477 0.015 91 5524 0.1600 0.1654
50 Cyclohexane 69 11.546 11.542 0.004 68 7113 0.1600 0.1835
51 Benzene 78 11.546 11.543 0.003 98 43763 0.1600 0.1748
52 Carbon tetrachloride 117 11.562 11.566 -0.004 98 29779 0.1600 0.1260
53 2,3-Dimethylpentane 71 11.637 11.634 0.003 90 9972 0.1600 0.1743
54 Thiophene 84 11.809 11.809 0.000 94 24114 0.1600 0.1626
55 Isooctane 57 12.245 12.247 -0.002 99 63422 0.1600 0.1667
56 n-Heptane 71 12.589 12.595 -0.006 91 13404 0.1600 0.1612
57 1,2-Dichloropropane 63 12.708 12.712 -0.004 87 15761 0.1600 0.1715
58 Trichloroethene 130 12.735 12.740 -0.005 97 23673 0.1600 0.1665
59 Dibromomethane 93 12.826 12.831 -0.005 88 18387 0.1600 0.1576
60 Dichlorobromomethane 83 12.961 12.963 -0.002 99 31217 0.1600 0.1618
61 1,4-Dioxane 88 12.998 12.984 0.014 76 6765 0.1600 0.1743
62 Methyl methacrylate 41 13.025 13.022 0.003 93 20029 0.1600 0.1776
63 Methylcyclohexane 83 13.482 13.482 0.000 95 25737 0.1600 0.1566
64 4-Methyl-2-pentanone (MIBK) 43 13.864 13.859 0.005 96 31681 0.1600 0.1654
65 cis-1,3-Dichloropropene 75 13.918 13.921 -0.003 93 23002 0.1600 0.1554
66 trans-1,3-Dichloropropene 75 14.591 14.591 0.000 98 21512 0.1600 0.1574
67 Toluene 91 14.720 14.721 -0.001 94 53488 0.1600 0.1642
68 1,1,2-Trichloroethane 83 14.795 14.794 0.001 96 15356 0.1600 0.1631
69 2-Hexanone 58 15.150 15.146 0.004 93 15516 0.1600 0.1599
70 n-Octane 85 15.354 15.351 0.003 93 15792 0.1600 0.1627
71 Chlorodibromomethane 129 15.489 15.491 -0.002 97 34112 0.1600 0.1532
72 Ethylene Dibromide 107 15.779 15.780 -0.001 99 29129 0.1600 0.1577
73 Tetrachloroethene 129 15.839 15.840 -0.001 95 21736 0.1600 0.1606
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 93 45387 0.1600 0.1728
75 Chlorobenzene 112 16.699 16.701 -0.002 97 46381 0.1600 0.1690
76 Ethylbenzene 91 16.974 16.972 0.002 98 70244 0.1600 0.1628
77 m-Xylene & p-Xylene 91 17.130 17.127 0.003 99 110909 0.3200 0.3366
78 n-Nonane 57 17.501 17.502 -0.001 90 30869 0.1600 0.1671
80 Styrene 104 17.592 17.591 0.001 98 41141 0.1600 0.1603
79 Bromoform 173 17.598 17.598 0.000 97 35773 0.1600 0.1721
81 o-Xylene 91 17.652 17.652 0.000 99 61978 0.1600 0.1657
82 1,1,2,2-Tetrachloroethane 83 17.969 17.970 -0.001 99 41912 0.1600 0.1610
83 1,2,3-Trichloropropane 110 18.130 18.132 -0.002 97 13500 0.1600 0.1640
3/25/2024
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Page 616 of 864
Report Date: 10-Feb-2024 14:44:52 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC04.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.222 0.000 95 88394 0.1600 0.1582
85 N-Propylbenzene 120 18.744 18.747 -0.003 99 25936 0.1600 0.1607
86 2-Chlorotoluene 126 18.803 18.805 -0.002 97 25449 0.1600 0.1671
87 4-Ethyltoluene 105 18.894 18.893 0.001 98 92153 0.1600 0.1605
88 1,3,5-Trimethylbenzene 120 18.964 18.963 0.001 94 41106 0.1600 0.1654
89 Alpha Methyl Styrene 118 19.190 19.193 -0.003 91 38119 0.1600 0.1549
90 n-Decane 57 19.217 19.219 -0.002 92 49828 0.1600 0.1742
91 tert-Butylbenzene 119 19.389 19.388 0.001 94 90090 0.1600 0.1680
92 1,2,4-Trimethylbenzene 105 19.400 19.401 -0.001 95 81694 0.1600 0.1704
93 sec-Butylbenzene 105 19.653 19.653 0.000 99 119824 0.1600 0.1672
94 1,3-Dichlorobenzene 146 19.680 19.683 -0.003 95 61917 0.1600 0.1642
95 Benzyl chloride 91 19.750 19.752 -0.002 99 44063 0.1600 0.1319
96 1,4-Dichlorobenzene 146 19.766 19.768 -0.002 96 62013 0.1600 0.1675
97 4-Isopropyltoluene 119 19.809 19.810 -0.001 97 108160 0.1600 0.1683
98 1,2,3-Trimethylbenzene 105 19.873 19.872 0.001 97 83229 0.1600 0.1696
99 Butylcyclohexane 83 19.911 19.915 -0.004 94 63566 0.1600 0.1756
100 2,3-Dihydroindene 117 20.121 20.123 -0.002 95 81664 0.1600 0.1692
101 1,2-Dichlorobenzene 146 20.131 20.130 0.001 98 62512 0.1600 0.1696
102 n-Butylbenzene 91 20.239 20.240 -0.001 99 100456 0.1600 0.1748
103 Indene 116 20.255 20.257 -0.002 91 69272 0.1600 0.1654
104 Undecane 57 20.530 20.530 0.000 96 71196 0.1600 0.1991
105 1,2-Dibromo-3-Chloropropane 157 20.750 20.747 0.003 96 30141 0.1600 0.1621
106 1,2,4,5-Tetramethylbenzene 119 21.035 21.034 0.001 98 120307 0.1600 0.1881
107 Dodecane 57 21.649 21.648 0.001 97 94629 0.1600 0.3134
108 1,2,4-Trichlorobenzene 180 21.858 21.859 -0.001 94 38926 0.1600 0.1821
109 Naphthalene 128 21.966 21.967 -0.001 99 77016 0.1600 0.1898
110 Hexachlorobutadiene 225 22.095 22.097 -0.002 94 64302 0.1600 0.2171
111 1,2,3-Trichlorobenzene 180 22.154 22.155 -0.001 95 37954 0.1600 0.2400
112 2-Methylnaphthalene 142 22.676 22.676 0.000 99 22875 0.1600 0.1384
113 1-Methylnaphthalene 142 22.805 22.805 0.000 99 33464 0.1600 0.1830
A 115 C8 Range 1 15.354 (15.311-15.397) 0 140269 0.1600 0.1686
S 116 Xylenes, Total 100 0 0.4800 0.5023
S 117 1,2-Dichloroethene, Total 1 0 0.3200 0.3262
QC Flag Legend
Processing Flags
Reagents:
40L4DQP_00063 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 617 of 864
Report Date: 10-Feb-2024 14:44:52 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC04.D
Injection Date:07-Feb-2024 23:02:30 Instrument ID:MS Operator ID:
Lims ID:IC L4 Worklist Smp#:12
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:6
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
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1
2
3
4
5
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3/25/2024
9:50:51 AM
Page 618 of 864
Report Date: 10-Feb-2024 14:44:52 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC04.D
Injection Date:07-Feb-2024 23:02:30 Instrument ID:MS
Lims ID:IC L4
Client ID:
Operator ID:ALS Bottle#:6 Worklist Smp#:12
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.3
Min
7
11
15
19
23
27
31
35
39
43
47
51
55
59
63
67
71
75
79
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SZB07IC04[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 619 of 864
Report Date: 10-Feb-2024 14:45:14 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC05.D
Lims ID:IC L5
Client ID:
Sample Type:IC Calib Level:5
Inject. Date:07-Feb-2024 23:54:30 ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-013
Misc. Info.:663621
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:45:13 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 13:51:25
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.921 9.927 -0.006 82 325906 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.040 12.043 -0.003 93 1523374 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.653 -0.002 85 1362070 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.265 18.263 0.002 96 988893 4.08 4.06
6 Chlorodifluoromethane 51 4.165 4.170 -0.005 97 60826 0.4000 0.4119
7 Propene 41 4.181 4.185 -0.004 98 29363 0.4000 0.4127
8 Dichlorodifluoromethane 85 4.240 4.246 -0.006 100 84656 0.4000 0.3949
9 Chloromethane 52 4.461 4.466 -0.005 53 6506 0.4000 0.4890
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.471 4.472 -0.001 87 52799 0.4000 0.3906
11 Acetaldehyde 44 4.649 4.651 -0.002 94 36755 2.00 2.42
12 Vinyl chloride 62 4.670 4.671 -0.001 99 18039 0.4000 0.4205
14 Butane 43 4.773 4.775 -0.002 83 24103 0.4000 0.4194
13 Butadiene 54 4.773 4.777 -0.004 73 13420 0.4000 0.4224
15 Bromomethane 94 5.165 5.169 -0.004 97 19290 0.4000 0.4137
16 Chloroethane 64 5.327 5.336 -0.009 88 7715 0.4000 0.4117
17 Ethanol 31 5.450 5.455 -0.005 99 41420 2.00 2.16
18 Vinyl bromide 106 5.687 5.692 -0.005 99 32456 0.4000 0.4098
19 2-Methylbutane 43 5.741 5.746 -0.005 90 34019 0.4000 0.4154
20 Trichlorofluoromethane 101 5.999 6.001 -0.002 100 98958 0.4000 0.4050
21 Acrolein 56 6.015 6.019 -0.004 95 10849 0.4000 0.4196
22 Acetonitrile 40 6.096 6.094 0.002 98 12246 0.4000 0.3981
23 Acetone 58 6.155 6.159 -0.004 99 43930 1.20 1.30
25 Pentane 72 6.252 6.250 0.002 97 5411 0.4000 0.4044
24 Isopropyl alcohol 45 6.257 6.260 -0.003 97 116819 1.20 1.13
26 Ethyl ether 31 6.451 6.451 0.000 95 35618 0.4000 0.4152
27 1,1-Dichloroethene 96 6.801 6.804 -0.003 99 34201 0.4000 0.3963
28 Acrylonitrile 53 6.924 6.928 -0.004 98 23164 0.4000 0.4216
29 2-Methyl-2-propanol 59 6.957 6.956 0.001 96 56864 0.4000 0.3903
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.989 6.995 -0.006 94 76702 0.4000 0.4017
31 Methylene Chloride 84 7.188 7.192 -0.004 93 31986 0.4000 0.3917
3/25/2024
9:50:51 AM
Page 620 of 864
Report Date: 10-Feb-2024 14:45:14 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC05.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.204 7.210 -0.006 98 29961 0.4000 0.3790
33 Carbon disulfide 76 7.382 7.383 -0.001 99 94041 0.4000 0.4029
34 trans-1,2-Dichloroethene 96 8.070 8.074 -0.004 98 35290 0.4000 0.3981
35 2-Methylpentane 43 8.081 8.085 -0.004 93 68934 0.4000 0.4100
36 Methyl tert-butyl ether 73 8.221 8.225 -0.004 96 96044 0.4000 0.4024
37 1,1-Dichloroethane 63 8.533 8.532 0.001 99 60930 0.4000 0.3966
38 Vinyl acetate 43 8.624 8.629 -0.005 100 71389 0.4000 0.3870
39 2-Butanone (MEK) 72 9.114 9.119 -0.005 96 15783 0.4000 0.3964
40 Hexane 56 9.125 9.130 -0.005 75 25843 0.4000 0.4025
41 Isopropyl ether 45 9.297 9.306 -0.009 96 106263 0.4000 0.4011
42 cis-1,2-Dichloroethene 96 9.571 9.575 -0.004 91 37041 0.4000 0.3957
43 Ethyl acetate 43 9.749 9.753 -0.004 99 71552 0.4000 0.3893
44 Chloroform 83 9.926 9.932 -0.006 44 77102 0.4000 0.4096
45 Tert-butyl ethyl ether 59 10.012 10.016 -0.004 95 103011 0.4000 0.4015
46 Tetrahydrofuran 42 10.357 10.359 -0.002 91 36364 0.4000 0.4019
47 1,1,1-Trichloroethane 97 10.970 10.971 -0.001 96 83677 0.4000 0.3927
48 1,2-Dichloroethane 62 11.072 11.078 -0.006 98 50065 0.4000 0.4032
49 n-Butanol 31 11.476 11.477 -0.001 90 12281 0.4000 0.3623
51 Benzene 78 11.540 11.543 -0.003 96 105344 0.4000 0.4146
50 Cyclohexane 69 11.540 11.542 -0.002 65 16197 0.4000 0.4117
52 Carbon tetrachloride 117 11.567 11.566 0.001 99 89861 0.4000 0.3754
53 2,3-Dimethylpentane 71 11.632 11.634 -0.002 92 23656 0.4000 0.4072
54 Thiophene 84 11.809 11.809 0.000 94 60808 0.4000 0.4038
55 Isooctane 57 12.245 12.246 -0.001 98 158578 0.4000 0.4105
56 n-Heptane 71 12.594 12.595 -0.001 91 34257 0.4000 0.4058
57 1,2-Dichloropropane 63 12.707 12.712 -0.005 87 38347 0.4000 0.4109
58 Trichloroethene 130 12.740 12.740 0.000 97 57824 0.4000 0.4006
59 Dibromomethane 93 12.826 12.830 -0.004 90 45309 0.4000 0.3825
60 Dichlorobromomethane 83 12.960 12.962 -0.002 98 79573 0.4000 0.4063
61 1,4-Dioxane 88 12.976 12.983 -0.007 87 15243 0.4000 0.3869
62 Methyl methacrylate 41 13.019 13.022 -0.003 94 45867 0.4000 0.4006
63 Methylcyclohexane 83 13.482 13.482 0.000 96 64319 0.4000 0.3862
64 4-Methyl-2-pentanone (MIBK) 43 13.859 13.859 0.000 97 78041 0.4000 0.4013
65 cis-1,3-Dichloropropene 75 13.918 13.921 -0.003 94 59237 0.4000 0.3942
66 trans-1,3-Dichloropropene 75 14.590 14.591 -0.001 99 52947 0.4000 0.3803
67 Toluene 91 14.719 14.721 -0.002 94 132774 0.4000 0.4000
68 1,1,2-Trichloroethane 83 14.795 14.794 0.001 96 37990 0.4000 0.3960
69 2-Hexanone 58 15.150 15.147 0.003 94 38442 0.4000 0.3888
70 n-Octane 85 15.354 15.352 0.002 94 40303 0.4000 0.4076
71 Chlorodibromomethane 129 15.494 15.492 0.002 98 89627 0.4000 0.3951
72 Ethylene Dibromide 107 15.779 15.780 -0.001 98 75460 0.4000 0.4010
73 Tetrachloroethene 129 15.838 15.840 -0.002 97 55743 0.4000 0.4042
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 94 113034 0.4000 0.4223
75 Chlorobenzene 112 16.699 16.701 -0.002 97 113779 0.4000 0.4068
76 Ethylbenzene 91 16.973 16.972 0.001 98 174152 0.4000 0.3962
77 m-Xylene & p-Xylene 91 17.129 17.127 0.002 98 273541 0.8000 0.8148
78 n-Nonane 57 17.506 17.503 0.003 90 77560 0.4000 0.4121
80 Styrene 104 17.592 17.591 0.001 98 105202 0.4000 0.4022
79 Bromoform 173 17.603 17.598 0.005 96 95153 0.4000 0.3963
81 o-Xylene 91 17.651 17.652 -0.001 99 146826 0.4000 0.3852
82 1,1,2,2-Tetrachloroethane 83 17.969 17.970 -0.001 100 105224 0.4000 0.3966
83 1,2,3-Trichloropropane 110 18.130 18.132 -0.002 97 33028 0.4000 0.3938
3/25/2024
9:50:51 AM
Page 621 of 864
Report Date: 10-Feb-2024 14:45:14 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC05.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.222 0.000 96 223847 0.4000 0.3932
85 N-Propylbenzene 120 18.749 18.748 0.001 100 65706 0.4000 0.3996
86 2-Chlorotoluene 126 18.803 18.805 -0.003 97 61664 0.4000 0.3973
87 4-Ethyltoluene 105 18.894 18.893 0.001 99 232571 0.4000 0.3976
88 1,3,5-Trimethylbenzene 120 18.964 18.963 0.001 93 100144 0.4000 0.3954
89 Alpha Methyl Styrene 118 19.195 19.193 0.002 92 96820 0.4000 0.3860
90 n-Decane 57 19.217 19.219 -0.002 92 125234 0.4000 0.4296
91 tert-Butylbenzene 119 19.389 19.388 0.001 96 220142 0.4000 0.4028
92 1,2,4-Trimethylbenzene 105 19.400 19.401 -0.001 95 199678 0.4000 0.4087
93 sec-Butylbenzene 105 19.652 19.653 -0.001 99 293773 0.4000 0.4023
94 1,3-Dichlorobenzene 146 19.685 19.683 0.002 96 152279 0.4000 0.3963
95 Benzyl chloride 91 19.755 19.752 0.003 99 118385 0.4000 0.3478
96 1,4-Dichlorobenzene 146 19.765 19.768 -0.003 97 149796 0.4000 0.3972
97 4-Isopropyltoluene 119 19.808 19.810 -0.002 98 263008 0.4000 0.4016
98 1,2,3-Trimethylbenzene 105 19.873 19.873 0.000 97 204843 0.4000 0.4097
99 Butylcyclohexane 83 19.916 19.915 0.001 95 157026 0.4000 0.4256
100 2,3-Dihydroindene 117 20.126 20.123 0.003 96 199213 0.4000 0.4050
101 1,2-Dichlorobenzene 146 20.126 20.129 -0.003 99 150076 0.4000 0.3996
102 n-Butylbenzene 91 20.239 20.240 -0.001 98 235125 0.4000 0.4016
103 Indene 116 20.255 20.256 -0.001 91 170271 0.4000 0.3990
104 Undecane 57 20.529 20.530 -0.001 95 156564 0.4000 0.4296
105 1,2-Dibromo-3-Chloropropane 157 20.750 20.747 0.003 96 73455 0.4000 0.3877
106 1,2,4,5-Tetramethylbenzene 119 21.035 21.034 0.001 98 265287 0.4000 0.4071
107 Dodecane 57 21.648 21.648 0.000 95 164343 0.4000 0.5341
108 1,2,4-Trichlorobenzene 180 21.858 21.859 -0.001 93 82914 0.4000 0.3807
109 Naphthalene 128 21.966 21.967 -0.001 99 156114 0.4000 0.3776
110 Hexachlorobutadiene 225 22.095 22.097 -0.002 94 118804 0.4000 0.3936
111 1,2,3-Trichlorobenzene 180 22.154 22.155 -0.001 95 73186 0.4000 0.4542
112 2-Methylnaphthalene 142 22.676 22.676 0.000 100 58807 0.4000 0.3492
113 1-Methylnaphthalene 142 22.805 22.805 0.000 99 75735 0.4000 0.4064
A 115 C8 Range 1 15.359 (15.311-15.397) 0 355229 0.4000 0.4207
S 116 Xylenes, Total 100 0 1.20 1.20
S 117 1,2-Dichloroethene, Total 1 0 0.8000 0.7938
QC Flag Legend
Processing Flags
Reagents:
40L5DQP_00053 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 622 of 864
Report Date: 10-Feb-2024 14:45:14 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC05.D
Injection Date:07-Feb-2024 23:54:30 Instrument ID:MS Operator ID:
Lims ID:IC L5 Worklist Smp#:13
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
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10
11
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18
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20
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SZB07IC05[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 623 of 864
Report Date: 10-Feb-2024 14:45:14 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC05.D
Injection Date:07-Feb-2024 23:54:30 Instrument ID:MS
Lims ID:IC L5
Client ID:
Operator ID:ALS Bottle#:7 Worklist Smp#:13
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.3
Min
0
2
4
6
8
10
12
14
16
18
20
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SZB07IC05[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 624 of 864
Report Date: 10-Feb-2024 14:45:37 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC06.D
Lims ID:IC L6
Client ID:
Sample Type:IC Calib Level:6
Inject. Date:08-Feb-2024 00:44:30 ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-014
Misc. Info.:663620
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:45:36 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 13:56:45
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.927 -0.001 85 327506 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.040 12.043 -0.003 94 1526327 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.653 -0.002 85 1368090 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.259 18.262 -0.003 97 1002314 4.08 4.10
6 Chlorodifluoromethane 51 4.165 4.169 -0.004 97 151349 1.00 1.02
7 Propene 41 4.181 4.185 -0.004 99 75475 1.00 1.06
8 Dichlorodifluoromethane 85 4.245 4.246 -0.001 100 223071 1.00 1.04
9 Chloromethane 52 4.466 4.466 0.000 51 14235 1.00 1.06
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.466 4.471 -0.005 85 140382 1.00 1.03
11 Acetaldehyde 44 4.649 4.651 -0.002 95 82110 5.00 5.38
12 Vinyl chloride 62 4.670 4.671 -0.001 99 43466 1.00 1.01
13 Butadiene 54 4.778 4.777 0.001 77 32572 1.00 1.02
14 Butane 43 4.773 4.775 -0.002 87 60611 1.00 1.05
15 Bromomethane 94 5.165 5.168 -0.003 97 44844 1.00 0.9570
16 Chloroethane 64 5.332 5.335 -0.003 92 18934 1.00 1.01
17 Ethanol 31 5.440 5.453 -0.013 100 94248 5.00 4.89
18 Vinyl bromide 106 5.687 5.691 -0.004 99 79549 1.00 1.00
19 2-Methylbutane 43 5.741 5.745 -0.004 91 82638 1.00 1.00
20 Trichlorofluoromethane 101 5.994 6.000 -0.006 99 249608 1.00 1.02
21 Acrolein 56 6.010 6.018 -0.008 96 25294 1.00 0.9734
22 Acetonitrile 40 6.085 6.093 -0.008 98 29456 1.00 0.9529
23 Acetone 58 6.144 6.157 -0.013 98 105236 3.00 3.11
25 Pentane 72 6.252 6.250 0.002 75 13609 1.00 1.01
24 Isopropyl alcohol 45 6.247 6.258 -0.011 82 295127 3.00 2.86
26 Ethyl ether 31 6.440 6.449 -0.009 95 87526 1.00 1.02
27 1,1-Dichloroethene 96 6.801 6.803 -0.002 99 86054 1.00 0.99
28 Acrylonitrile 53 6.919 6.927 -0.008 95 55343 1.00 1.00
29 2-Methyl-2-propanol 59 6.935 6.953 -0.018 95 145822 1.00 1.00
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.989 6.994 -0.005 95 192705 1.00 1.00
31 Methylene Chloride 84 7.188 7.192 -0.004 93 77399 1.00 0.9432
3/25/2024
9:50:51 AM
Page 625 of 864
Report Date: 10-Feb-2024 14:45:37 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC06.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.210 7.210 0.000 98 72318 1.00 0.9104
33 Carbon disulfide 76 7.382 7.383 -0.001 99 230702 1.00 0.9837
34 trans-1,2-Dichloroethene 96 8.070 8.074 -0.004 98 90019 1.00 1.01
35 2-Methylpentane 43 8.081 8.084 -0.003 94 178770 1.00 1.06
36 Methyl tert-butyl ether 73 8.205 8.223 -0.018 96 243624 1.00 1.02
37 1,1-Dichloroethane 63 8.528 8.531 -0.003 100 155626 1.00 1.01
38 Vinyl acetate 43 8.619 8.628 -0.009 100 179333 1.00 0.9675
39 2-Butanone (MEK) 72 9.103 9.118 -0.015 98 40324 1.00 1.01
40 Hexane 56 9.130 9.130 0.000 90 66443 1.00 1.03
41 Isopropyl ether 45 9.286 9.304 -0.018 96 274501 1.00 1.03
42 cis-1,2-Dichloroethene 96 9.571 9.575 -0.004 91 95118 1.00 1.01
43 Ethyl acetate 43 9.738 9.751 -0.013 99 187536 1.00 1.02
44 Chloroform 83 9.926 9.932 -0.006 93 194044 1.00 1.03
45 Tert-butyl ethyl ether 59 10.002 10.015 -0.013 95 264725 1.00 1.03
46 Tetrahydrofuran 42 10.341 10.357 -0.016 92 91791 1.00 1.01
47 1,1,1-Trichloroethane 97 10.970 10.971 -0.001 96 213015 1.00 0.99
48 1,2-Dichloroethane 62 11.072 11.077 -0.005 98 126982 1.00 1.02
49 n-Butanol 31 11.465 11.476 -0.011 86 32764 1.00 0.9647
51 Benzene 78 11.540 11.543 -0.003 96 265147 1.00 1.04
50 Cyclohexane 69 11.540 11.541 -0.001 67 41133 1.00 1.04
52 Carbon tetrachloride 117 11.562 11.566 -0.004 97 215381 1.00 0.9030
53 2,3-Dimethylpentane 71 11.632 11.633 -0.001 90 59461 1.00 1.02
54 Thiophene 84 11.804 11.809 -0.005 94 155457 1.00 1.03
55 Isooctane 57 12.245 12.246 -0.001 99 400717 1.00 1.04
56 n-Heptane 71 12.589 12.594 -0.005 91 88988 1.00 1.05
57 1,2-Dichloropropane 63 12.708 12.711 -0.003 88 97480 1.00 1.04
58 Trichloroethene 130 12.734 12.739 -0.005 97 148108 1.00 1.02
59 Dibromomethane 93 12.826 12.830 -0.004 90 114700 1.00 0.9664
60 Dichlorobromomethane 83 12.960 12.962 -0.002 99 204189 1.00 1.04
61 1,4-Dioxane 88 12.966 12.981 -0.015 82 39495 1.00 1.00
62 Methyl methacrylate 41 13.020 13.021 -0.001 94 113837 1.00 0.99
63 Methylcyclohexane 83 13.477 13.482 -0.005 95 164849 1.00 0.99
64 4-Methyl-2-pentanone (MIBK) 43 13.853 13.858 -0.005 97 197139 1.00 1.01
65 cis-1,3-Dichloropropene 75 13.918 13.920 -0.002 94 153313 1.00 1.02
66 trans-1,3-Dichloropropene 75 14.590 14.591 -0.001 98 141378 1.00 1.01
67 Toluene 91 14.720 14.721 -0.001 94 338928 1.00 1.02
68 1,1,2-Trichloroethane 83 14.789 14.794 -0.005 97 97142 1.00 1.01
69 2-Hexanone 58 15.144 15.146 -0.002 94 100602 1.00 1.01
70 n-Octane 85 15.349 15.351 -0.002 92 102942 1.00 1.04
71 Chlorodibromomethane 129 15.489 15.491 -0.002 98 236724 1.00 1.04
72 Ethylene Dibromide 107 15.779 15.780 -0.001 99 192440 1.00 1.02
73 Tetrachloroethene 129 15.838 15.840 -0.002 96 141425 1.00 1.02
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 94 280542 1.00 1.04
75 Chlorobenzene 112 16.699 16.700 -0.001 97 286664 1.00 1.02
76 Ethylbenzene 91 16.968 16.972 -0.004 98 449184 1.00 1.02
77 m-Xylene & p-Xylene 91 17.124 17.127 -0.003 98 695147 2.00 2.06
78 n-Nonane 57 17.501 17.503 -0.002 90 197963 1.00 1.05
80 Styrene 104 17.587 17.590 -0.003 98 276171 1.00 1.05
79 Bromoform 173 17.598 17.598 0.000 98 260579 1.00 1.02
81 o-Xylene 91 17.651 17.652 -0.001 99 373970 1.00 0.9769
82 1,1,2,2-Tetrachloroethane 83 17.969 17.969 0.000 100 268995 1.00 1.01
83 1,2,3-Trichloropropane 110 18.125 18.131 -0.006 98 85073 1.00 1.01
3/25/2024
9:50:51 AM
Page 626 of 864
Report Date: 10-Feb-2024 14:45:37 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC06.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.222 0.000 96 565435 1.00 0.9888
85 N-Propylbenzene 120 18.749 18.748 0.001 100 167990 1.00 1.02
86 2-Chlorotoluene 126 18.803 18.804 -0.001 97 159154 1.00 1.02
87 4-Ethyltoluene 105 18.894 18.894 0.000 99 594706 1.00 1.01
88 1,3,5-Trimethylbenzene 120 18.964 18.963 0.001 94 259272 1.00 1.02
89 Alpha Methyl Styrene 118 19.190 19.193 -0.003 91 261698 1.00 1.04
90 n-Decane 57 19.217 19.219 -0.002 91 309170 1.00 1.06
91 tert-Butylbenzene 119 19.384 19.388 -0.004 94 561126 1.00 1.02
92 1,2,4-Trimethylbenzene 105 19.400 19.401 -0.001 95 501260 1.00 1.02
93 sec-Butylbenzene 105 19.653 19.653 0.000 99 749813 1.00 1.02
94 1,3-Dichlorobenzene 146 19.679 19.683 -0.004 95 385332 1.00 1.00
95 Benzyl chloride 91 19.749 19.752 -0.003 99 346252 1.00 1.01
96 1,4-Dichlorobenzene 146 19.766 19.767 -0.001 97 380809 1.00 1.01
97 4-Isopropyltoluene 119 19.809 19.810 -0.001 98 666883 1.00 1.01
98 1,2,3-Trimethylbenzene 105 19.868 19.872 -0.004 97 518807 1.00 1.03
99 Butylcyclohexane 83 19.911 19.914 -0.003 95 391107 1.00 1.06
100 2,3-Dihydroindene 117 20.121 20.123 -0.002 95 509024 1.00 1.03
101 1,2-Dichlorobenzene 146 20.126 20.129 -0.003 98 378830 1.00 1.00
102 n-Butylbenzene 91 20.239 20.240 -0.001 98 593607 1.00 1.01
103 Indene 116 20.255 20.256 -0.001 96 441596 1.00 1.03
104 Undecane 57 20.529 20.530 -0.001 95 398758 1.00 1.09
105 1,2-Dibromo-3-Chloropropane 157 20.745 20.747 -0.002 95 199223 1.00 1.05
106 1,2,4,5-Tetramethylbenzene 119 21.030 21.033 -0.003 98 672397 1.00 1.03
107 Dodecane 57 21.643 21.648 -0.005 96 420137 1.00 1.36
108 1,2,4-Trichlorobenzene 180 21.858 21.859 -0.001 94 224931 1.00 1.03
109 Naphthalene 128 21.966 21.966 0.000 99 421684 1.00 1.02
110 Hexachlorobutadiene 225 22.095 22.097 -0.002 94 281499 1.00 0.9285
111 1,2,3-Trichlorobenzene 180 22.154 22.155 -0.001 95 189339 1.00 1.17
112 2-Methylnaphthalene 142 22.671 22.675 -0.005 100 181364 1.00 1.07
113 1-Methylnaphthalene 142 22.805 22.805 0.000 100 217054 1.00 1.16
A 115 C8 Range 1 15.349 (15.301-15.408) 0 904700 1.00 1.07
S 116 Xylenes, Total 100 0 3.00 3.04
S 117 1,2-Dichloroethene, Total 1 0 2.00 2.02
QC Flag Legend
Processing Flags
Reagents:
40L6DQP_00050 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 627 of 864
Report Date: 10-Feb-2024 14:45:37 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC06.D
Injection Date:08-Feb-2024 00:44:30 Instrument ID:MS Operator ID:
Lims ID:IC L6 Worklist Smp#:14
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:8
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
Y ( X10
0
0
0
0
)
SZB07IC06[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
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t
h
a
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e

(IS
)(

9
.
9
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)+
* 1
,4-
D
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( 1
2
.
0
4
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)
* C
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-
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(IS
)(
1
6
.
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$ 4
-
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(Su
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r
)(
1
8
.
2
6
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)
3/25/2024
9:50:51 AM
Page 628 of 864
Report Date: 10-Feb-2024 14:45:37 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07IC06.D
Injection Date:08-Feb-2024 00:44:30 Instrument ID:MS
Lims ID:IC L6
Client ID:
Operator ID:ALS Bottle#:8 Worklist Smp#:14
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.2
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
48
Y ( X10
0
0
0
)
SZB07IC06[MS SCAN Chro]:Total
3/25/2024
9:50:51 AM
Page 629 of 864
Report Date: 10-Feb-2024 14:46:01 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Lims ID:ICIS L7
Client ID:
Sample Type:ICIS Calib Level:7
Inject. Date:08-Feb-2024 01:36:30 ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-015
Misc. Info.:663024
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:46:00 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:08-Feb-2024 06:42:31
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.927 -0.001 87 323293 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.046 12.043 0.003 93 1516562 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.652 -0.001 84 1361919 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.265 18.263 0.002 96 1000211 4.08 4.11
6 Chlorodifluoromethane 51 4.170 4.169 0.001 97 293647 2.00 2.00
7 Propene 41 4.181 4.184 -0.003 99 147919 2.00 2.10
8 Dichlorodifluoromethane 85 4.245 4.246 -0.001 100 418690 2.00 1.97
9 Chloromethane 52 4.461 4.465 -0.004 97 26484 2.00 2.01
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.471 4.471 0.000 86 261484 2.00 1.95
11 Acetaldehyde 44 4.649 4.651 -0.002 94 166142 10.0 11.0
12 Vinyl chloride 62 4.670 4.671 -0.001 99 86960 2.00 2.04
14 Butane 43 4.773 4.775 -0.002 88 116024 2.00 2.04
13 Butadiene 54 4.778 4.777 0.001 72 62741 2.00 1.99
15 Bromomethane 94 5.165 5.168 -0.003 98 90169 2.00 1.95
16 Chloroethane 64 5.337 5.336 0.001 89 35871 2.00 1.93
17 Ethanol 31 5.440 5.452 -0.012 99 201240 10.0 10.6
18 Vinyl bromide 106 5.693 5.692 0.001 99 160523 2.00 2.04
19 2-Methylbutane 43 5.741 5.745 -0.004 91 168397 2.00 2.07
20 Trichlorofluoromethane 101 5.999 6.000 -0.001 99 496544 2.00 2.05
21 Acrolein 56 6.010 6.017 -0.007 95 51231 2.00 2.00
22 Acetonitrile 40 6.085 6.092 -0.007 98 66661 2.00 2.18
23 Acetone 58 6.139 6.155 -0.016 98 225001 6.00 6.73
24 Isopropyl alcohol 45 6.236 6.256 -0.020 95 619975 6.00 6.18
25 Pentane 72 6.247 6.250 -0.003 98 27481 2.00 2.07
26 Ethyl ether 31 6.435 6.448 -0.013 95 175916 2.00 2.07
27 1,1-Dichloroethene 96 6.806 6.804 0.002 99 171462 2.00 2.00
28 Acrylonitrile 53 6.919 6.926 -0.007 94 109774 2.00 2.01
29 2-Methyl-2-propanol 59 6.919 6.950 -0.031 95 305031 2.00 2.11
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.989 6.993 -0.004 94 384360 2.00 2.03
31 Methylene Chloride 84 7.188 7.191 -0.003 94 149625 2.00 1.85
3/25/2024
9:50:51 AM
Page 630 of 864
Report Date: 10-Feb-2024 14:46:01 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.204 7.209 -0.005 98 148068 2.00 1.89
33 Carbon disulfide 76 7.382 7.383 -0.001 99 456585 2.00 1.97
34 trans-1,2-Dichloroethene 96 8.076 8.074 0.002 98 175753 2.00 2.00
35 2-Methylpentane 43 8.081 8.084 -0.003 94 346205 2.00 2.08
36 Methyl tert-butyl ether 73 8.194 8.220 -0.026 96 479589 2.00 2.03
37 1,1-Dichloroethane 63 8.533 8.531 0.002 100 303927 2.00 1.99
38 Vinyl acetate 43 8.624 8.628 -0.004 100 348171 2.00 1.90
39 2-Butanone (MEK) 72 9.103 9.116 -0.013 99 83098 2.00 2.10
40 Hexane 56 9.130 9.130 0.000 92 128146 2.00 2.01
41 Isopropyl ether 45 9.286 9.302 -0.016 96 542245 2.00 2.06
42 cis-1,2-Dichloroethene 96 9.571 9.575 -0.004 92 186370 2.00 2.01
43 Ethyl acetate 43 9.738 9.750 -0.012 99 365858 2.00 2.01
44 Chloroform 83 9.926 9.931 -0.005 95 381086 2.00 2.04
45 Tert-butyl ethyl ether 59 9.996 10.013 -0.017 95 530094 2.00 2.08
46 Tetrahydrofuran 42 10.335 10.355 -0.020 92 184147 2.00 2.05
47 1,1,1-Trichloroethane 97 10.970 10.971 -0.001 95 422532 2.00 2.00
48 1,2-Dichloroethane 62 11.072 11.077 -0.005 98 252465 2.00 2.04
49 n-Butanol 31 11.454 11.474 -0.020 87 69839 2.00 2.07
51 Benzene 78 11.540 11.542 -0.002 97 516547 2.00 2.04
50 Cyclohexane 69 11.540 11.541 -0.001 78 80186 2.00 2.05
52 Carbon tetrachloride 117 11.562 11.566 -0.004 97 469149 2.00 2.00
53 2,3-Dimethylpentane 71 11.632 11.633 -0.001 90 118272 2.00 2.05
54 Thiophene 84 11.809 11.809 0.000 94 307792 2.00 2.05
55 Isooctane 57 12.245 12.246 -0.001 99 790653 2.00 2.06
56 n-Heptane 71 12.595 12.594 0.000 92 175717 2.00 2.09
57 1,2-Dichloropropane 63 12.707 12.711 -0.004 88 189149 2.00 2.04
58 Trichloroethene 130 12.740 12.739 0.001 97 288347 2.00 2.01
59 Dibromomethane 93 12.831 12.830 0.001 90 225525 2.00 1.91
60 Dichlorobromomethane 83 12.960 12.962 -0.002 99 406154 2.00 2.08
61 1,4-Dioxane 88 12.966 12.979 -0.013 65 85223 2.00 2.17
62 Methyl methacrylate 41 13.014 13.021 -0.007 94 228104 2.00 2.00
63 Methylcyclohexane 83 13.482 13.482 0.000 96 323432 2.00 1.97
64 4-Methyl-2-pentanone (MIBK) 43 13.848 13.857 -0.009 97 399537 2.00 2.06
65 cis-1,3-Dichloropropene 75 13.918 13.920 -0.002 94 309126 2.00 2.07
66 trans-1,3-Dichloropropene 75 14.590 14.591 -0.001 98 290886 2.00 2.09
67 Toluene 91 14.725 14.721 0.004 94 664285 2.00 2.00
68 1,1,2-Trichloroethane 83 14.795 14.794 0.001 97 191202 2.00 1.99
69 2-Hexanone 58 15.139 15.146 -0.007 94 205236 2.00 2.08
70 n-Octane 85 15.354 15.352 0.002 92 204333 2.00 2.07
71 Chlorodibromomethane 129 15.494 15.492 0.002 98 486888 2.00 2.15
72 Ethylene Dibromide 107 15.779 15.780 -0.001 99 385842 2.00 2.05
73 Tetrachloroethene 129 15.838 15.840 -0.002 96 274359 2.00 1.99
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 94 548293 2.00 2.05
75 Chlorobenzene 112 16.699 16.700 -0.001 96 563148 2.00 2.01
76 Ethylbenzene 91 16.973 16.972 0.001 98 890723 2.00 2.03
77 m-Xylene & p-Xylene 91 17.129 17.127 0.002 98 1370588 4.00 4.08
78 n-Nonane 57 17.501 17.502 -0.001 90 394416 2.00 2.10
80 Styrene 104 17.592 17.591 0.001 97 547979 2.00 2.10
79 Bromoform 173 17.598 17.598 0.000 98 544206 2.00 2.11
81 o-Xylene 91 17.651 17.652 -0.001 99 735040 2.00 1.93
82 1,1,2,2-Tetrachloroethane 83 17.969 17.969 0.000 100 538355 2.00 2.03
83 1,2,3-Trichloropropane 110 18.130 18.131 -0.001 97 167350 2.00 2.00
3/25/2024
9:50:51 AM
Page 631 of 864
Report Date: 10-Feb-2024 14:46:01 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.222 0.000 95 1112998 2.00 1.96
85 N-Propylbenzene 120 18.749 18.748 0.001 100 334381 2.00 2.03
86 2-Chlorotoluene 126 18.803 18.804 -0.001 97 307703 2.00 1.98
87 4-Ethyltoluene 105 18.894 18.894 0.000 99 1173951 2.00 2.01
88 1,3,5-Trimethylbenzene 120 18.964 18.963 0.001 94 505616 2.00 2.00
89 Alpha Methyl Styrene 118 19.195 19.193 0.002 91 514165 2.00 2.05
90 n-Decane 57 19.217 19.218 -0.001 92 585159 2.00 2.01
91 tert-Butylbenzene 119 19.389 19.388 0.001 94 1089089 2.00 1.99
92 1,2,4-Trimethylbenzene 105 19.400 19.401 -0.001 95 973971 2.00 1.99
93 sec-Butylbenzene 105 19.653 19.653 -0.001 99 1452791 2.00 1.99
94 1,3-Dichlorobenzene 146 19.679 19.682 -0.003 96 747571 2.00 1.95
95 Benzyl chloride 91 19.755 19.752 0.003 99 736534 2.00 2.16
96 1,4-Dichlorobenzene 146 19.765 19.767 -0.002 97 741371 2.00 1.97
97 4-Isopropyltoluene 119 19.809 19.810 -0.001 98 1297822 2.00 1.98
98 1,2,3-Trimethylbenzene 105 19.873 19.872 0.001 97 1003187 2.00 2.01
99 Butylcyclohexane 83 19.916 19.915 0.001 95 741261 2.00 2.01
100 2,3-Dihydroindene 117 20.121 20.123 -0.002 95 972736 2.00 1.98
101 1,2-Dichlorobenzene 146 20.126 20.129 -0.003 98 728733 2.00 1.94
102 n-Butylbenzene 91 20.239 20.240 -0.001 98 1132990 2.00 1.94
103 Indene 116 20.255 20.256 -0.001 92 855414 2.00 2.00
104 Undecane 57 20.529 20.529 0.000 95 697607 2.00 1.91
105 1,2-Dibromo-3-Chloropropane 157 20.745 20.747 -0.002 94 412945 2.00 2.18
106 1,2,4,5-Tetramethylbenzene 119 21.035 21.034 0.001 98 1253725 2.00 1.92
107 Dodecane 57 21.643 21.647 -0.004 96 606497 2.00 1.97
108 1,2,4-Trichlorobenzene 180 21.858 21.859 -0.001 94 406494 2.00 1.87
109 Naphthalene 128 21.966 21.966 0.000 99 725133 2.00 1.75
110 Hexachlorobutadiene 225 22.095 22.097 -0.002 94 443226 2.00 1.47
111 1,2,3-Trichlorobenzene 180 22.154 22.155 -0.001 95 311599 2.00 1.93
112 2-Methylnaphthalene 142 22.676 22.675 0.001 100 313477 2.00 1.86
113 1-Methylnaphthalene 142 22.805 22.805 0.000 99 350339 2.00 1.88
A 115 C8 Range 1 15.362 (15.300-15.408) 0 1774965 2.00 2.11
S 116 Xylenes, Total 100 0 6.00 6.01
S 117 1,2-Dichloroethene, Total 1 0 4.00 4.01
QC Flag Legend
Processing Flags
Reagents:
40L7DQP_00050 Amount Added: 200.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 632 of 864
Report Date: 10-Feb-2024 14:46:01 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Injection Date:08-Feb-2024 01:36:30 Instrument ID:MS Operator ID:
Lims ID:ICIS L7 Worklist Smp#:15
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:9
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
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6
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SZB07ICIS07[MS SCAN Chro]:Total
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Page 633 of 864
Report Date: 10-Feb-2024 14:46:01 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Injection Date:08-Feb-2024 01:36:30 Instrument ID:MS
Lims ID:ICIS L7
Client ID:
Operator ID:ALS Bottle#:9 Worklist Smp#:15
Purge Vol:500.000 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column:RTX-5 ( 0.32 mm)Detector MS SCAN
A 115 C8 Range, CAS: STL00834
15.2
Min
0
5
10
15
20
25
30
35
40
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3/25/2024
9:50:51 AM
Page 634 of 864
Calibration / Chlorodifluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.74
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.071293 3.84 342835.0 3.56463 N
2 IC 140-83168/10 0.04 0.0899 3.84 334795.0 2.247489 N
3 IC 140-83168/11 0.08 0.157878 3.84 329376.0 1.973477 Y
4 IC 140-83168/12 0.16 0.298308 3.84 319640.0 1.864422 Y
5 IC 140-83168/13 0.4 0.716685 3.84 325906.0 1.791712 Y
6 IC 140-83168/14 1.0 1.774563 3.84 327506.0 1.774563 Y
7 ICIS 140-83168/15 2.0 3.487872 3.84 323293.0 1.743936 Y
8 IC 140-83168/7 4.0 6.546354 3.84 349180.0 1.636589 Y
9 IC 140-83168/5 8.0 13.058441 3.84 346991.0 1.632305 Y
10 IC 140-83168/3 16.0 24.0212 3.84 327617.0 1.501325 Y
RelResp = [1.74]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 635 of 864
Calibration / Propene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8384
Error Coefficients
Relative Standard Deviation:6.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.022189 3.84 342835.0 1.109432 N
2 IC 140-83168/10 0.04 0.046406 3.84 334795.0 1.160161 N
3 IC 140-83168/11 0.08 0.080548 3.84 329376.0 1.006849 N
4 IC 140-83168/12 0.16 0.148944 3.84 319640.0 0.930897 N
5 IC 140-83168/13 0.4 0.345971 3.84 325906.0 0.864927 Y
6 IC 140-83168/14 1.0 0.884943 3.84 327506.0 0.884943 Y
7 ICIS 140-83168/15 2.0 1.756948 3.84 323293.0 0.878474 Y
8 IC 140-83168/7 4.0 3.319756 3.84 349180.0 0.829939 Y
9 IC 140-83168/5 8.0 6.576353 3.84 346991.0 0.822044 Y
10 IC 140-83168/3 16.0 12.000467 3.84 327617.0 0.750029 Y
RelResp = [0.8384]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 636 of 864
Calibration / Dichlorodifluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.526
Error Coefficients
Relative Standard Deviation:11.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.063799 3.84 342835.0 3.189966 Y
2 IC 140-83168/10 0.04 0.110396 3.84 334795.0 2.759898 Y
3 IC 140-83168/11 0.08 0.196514 3.84 329376.0 2.456427 Y
4 IC 140-83168/12 0.16 0.413097 3.84 319640.0 2.581855 Y
5 IC 140-83168/13 0.4 0.997463 3.84 325906.0 2.493656 Y
6 IC 140-83168/14 1.0 2.615502 3.84 327506.0 2.615502 Y
7 ICIS 140-83168/15 2.0 4.973104 3.84 323293.0 2.486552 Y
8 IC 140-83168/7 4.0 9.143572 3.84 349180.0 2.285893 Y
9 IC 140-83168/5 8.0 18.537112 3.84 346991.0 2.317139 Y
10 IC 140-83168/3 16.0 33.179488 3.84 327617.0 2.073718 Y
RelResp = [2.526]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
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Page 637 of 864
Calibration / Chloromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1568
Error Coefficients
Relative Standard Deviation:15.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.0 3.84 334795.0 0.0 N
3 IC 140-83168/11 0.08 0.020391 3.84 329376.0 0.254882 N
4 IC 140-83168/12 0.16 0.028196 3.84 319640.0 0.176223 Y
5 IC 140-83168/13 0.4 0.076657 3.84 325906.0 0.191643 Y
6 IC 140-83168/14 1.0 0.166905 3.84 327506.0 0.166905 Y
7 ICIS 140-83168/15 2.0 0.314571 3.84 323293.0 0.157285 Y
8 IC 140-83168/7 4.0 0.571491 3.84 349180.0 0.142873 Y
9 IC 140-83168/5 8.0 1.12246 3.84 346991.0 0.140308 Y
10 IC 140-83168/3 16.0 1.95429 3.84 327617.0 0.122143 Y
RelResp = [0.1568]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
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n
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(

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IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 638 of 864
Calibration / 1,2-Dichloro-1,1,2,2-tetrafluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.593
Error Coefficients
Relative Standard Deviation:16.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.042036 3.84 342835.0 2.101816 Y
2 IC 140-83168/10 0.04 0.075907 3.84 334795.0 1.897663 Y
3 IC 140-83168/11 0.08 0.125328 3.84 329376.0 1.566599 Y
4 IC 140-83168/12 0.16 0.261702 3.84 319640.0 1.63564 Y
5 IC 140-83168/13 0.4 0.622106 3.84 325906.0 1.555266 Y
6 IC 140-83168/14 1.0 1.645976 3.84 327506.0 1.645976 Y
7 ICIS 140-83168/15 2.0 3.105847 3.84 323293.0 1.552923 Y
8 IC 140-83168/7 4.0 5.573543 3.84 349180.0 1.393386 Y
9 IC 140-83168/5 8.0 11.064965 3.84 346991.0 1.383121 Y
10 IC 140-83168/3 16.0 19.129803 3.84 327617.0 1.195613 Y
RelResp = [1.593]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 639 of 864
Calibration / Vinyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5055
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.015166 3.84 342835.0 0.758289 N
2 IC 140-83168/10 0.04 0.022848 3.84 334795.0 0.571191 Y
3 IC 140-83168/11 0.08 0.044104 3.84 329376.0 0.551297 Y
4 IC 140-83168/12 0.16 0.083782 3.84 319640.0 0.523639 Y
5 IC 140-83168/13 0.4 0.212545 3.84 325906.0 0.531363 Y
6 IC 140-83168/14 1.0 0.509638 3.84 327506.0 0.509638 Y
7 ICIS 140-83168/15 2.0 1.032891 3.84 323293.0 0.516445 Y
8 IC 140-83168/7 4.0 1.85085 3.84 349180.0 0.462712 Y
9 IC 140-83168/5 8.0 3.718865 3.84 346991.0 0.464858 Y
10 IC 140-83168/3 16.0 6.689282 3.84 327617.0 0.41808 Y
RelResp = [0.5055]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 640 of 864
Calibration / Butadiene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3744
Error Coefficients
Relative Standard Deviation:13.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.0 3.84 334795.0 0.0 N
3 IC 140-83168/11 0.08 0.03487 3.84 329376.0 0.435879 Y
4 IC 140-83168/12 0.16 0.070507 3.84 319640.0 0.440671 Y
5 IC 140-83168/13 0.4 0.158122 3.84 325906.0 0.395304 Y
6 IC 140-83168/14 1.0 0.381906 3.84 327506.0 0.381906 Y
7 ICIS 140-83168/15 2.0 0.745223 3.84 323293.0 0.372612 Y
8 IC 140-83168/7 4.0 1.35922 3.84 349180.0 0.339805 Y
9 IC 140-83168/5 8.0 2.649846 3.84 346991.0 0.331231 Y
10 IC 140-83168/3 16.0 4.76154 3.84 327617.0 0.297596 Y
RelResp = [0.3744]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 641 of 864
Calibration / Butane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6771
Error Coefficients
Relative Standard Deviation:10.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.0 3.84 334795.0 0.0 N
3 IC 140-83168/11 0.08 0.060624 3.84 329376.0 0.757797 Y
4 IC 140-83168/12 0.16 0.119174 3.84 319640.0 0.744838 Y
5 IC 140-83168/13 0.4 0.283995 3.84 325906.0 0.709986 Y
6 IC 140-83168/14 1.0 0.710663 3.84 327506.0 0.710663 Y
7 ICIS 140-83168/15 2.0 1.378106 3.84 323293.0 0.689053 Y
8 IC 140-83168/7 4.0 2.504281 3.84 349180.0 0.62607 Y
9 IC 140-83168/5 8.0 4.972885 3.84 346991.0 0.621611 Y
10 IC 140-83168/3 16.0 8.912499 3.84 327617.0 0.557031 Y
RelResp = [0.6771]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 642 of 864
Calibration / Bromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5494
Error Coefficients
Relative Standard Deviation:13.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.026701 3.84 334795.0 0.667537 Y
3 IC 140-83168/11 0.08 0.051635 3.84 329376.0 0.645439 Y
4 IC 140-83168/12 0.16 0.09409 3.84 319640.0 0.588062 Y
5 IC 140-83168/13 0.4 0.227285 3.84 325906.0 0.568213 Y
6 IC 140-83168/14 1.0 0.525795 3.84 327506.0 0.525795 Y
7 ICIS 140-83168/15 2.0 1.071007 3.84 323293.0 0.535503 Y
8 IC 140-83168/7 4.0 1.927929 3.84 349180.0 0.481982 Y
9 IC 140-83168/5 8.0 3.885561 3.84 346991.0 0.485695 Y
10 IC 140-83168/3 16.0 7.143635 3.84 327617.0 0.446477 Y
RelResp = [0.5494]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 643 of 864
Calibration / Chloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2208
Error Coefficients
Relative Standard Deviation:13.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.0 3.84 334795.0 0.0 N
3 IC 140-83168/11 0.08 0.02165 3.84 329376.0 0.270621 Y
4 IC 140-83168/12 0.16 0.040954 3.84 319640.0 0.255963 Y
5 IC 140-83168/13 0.4 0.090902 3.84 325906.0 0.227256 Y
6 IC 140-83168/14 1.0 0.222001 3.84 327506.0 0.222001 Y
7 ICIS 140-83168/15 2.0 0.426067 3.84 323293.0 0.213034 Y
8 IC 140-83168/7 4.0 0.784815 3.84 349180.0 0.196204 Y
9 IC 140-83168/5 8.0 1.582508 3.84 346991.0 0.197814 Y
10 IC 140-83168/3 16.0 2.933814 3.84 327617.0 0.183363 Y
RelResp = [0.2208]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
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Page 644 of 864
Calibration / Ethanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2259
Error Coefficients
Relative Standard Deviation:11.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.1 0.044131 3.84 342835.0 0.441309 N
2 IC 140-83168/10 0.2 0.076228 3.84 334795.0 0.381138 N
3 IC 140-83168/11 0.4 0.135144 3.84 329376.0 0.337861 N
4 IC 140-83168/12 0.8 0.21467 3.84 319640.0 0.268337 Y
5 IC 140-83168/13 2.0 0.488033 3.84 325906.0 0.244016 Y
6 IC 140-83168/14 5.0 1.105056 3.84 327506.0 0.221011 Y
7 ICIS 140-83168/15 10.0 2.390282 3.84 323293.0 0.239028 Y
8 IC 140-83168/7 20.0 4.239088 3.84 349180.0 0.211954 Y
9 IC 140-83168/5 40.0 8.20585 3.84 346991.0 0.205146 Y
10 IC 140-83168/3 80.0 15.359391 3.84 327617.0 0.191992 Y
RelResp = [0.2259]x
Concentration
0 10 20 30 40 50 60 70 80
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 645 of 864
Calibration / Vinyl bromide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9331
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.024261 3.84 342835.0 1.213038 N
2 IC 140-83168/10 0.04 0.042438 3.84 334795.0 1.060948 N
3 IC 140-83168/11 0.08 0.076619 3.84 329376.0 0.957738 Y
4 IC 140-83168/12 0.16 0.155239 3.84 319640.0 0.970242 Y
5 IC 140-83168/13 0.4 0.382414 3.84 325906.0 0.956035 Y
6 IC 140-83168/14 1.0 0.93271 3.84 327506.0 0.93271 Y
7 ICIS 140-83168/15 2.0 1.906655 3.84 323293.0 0.953328 Y
8 IC 140-83168/7 4.0 3.625775 3.84 349180.0 0.906444 Y
9 IC 140-83168/5 8.0 7.413052 3.84 346991.0 0.926632 Y
10 IC 140-83168/3 16.0 13.789491 3.84 327617.0 0.861843 Y
RelResp = [0.9331]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 646 of 864
Calibration / 2-Methylbutane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9649
Error Coefficients
Relative Standard Deviation:6.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.046464 3.84 334795.0 1.161594 N
3 IC 140-83168/11 0.08 0.083626 3.84 329376.0 1.045322 Y
4 IC 140-83168/12 0.16 0.161774 3.84 319640.0 1.011087 Y
5 IC 140-83168/13 0.4 0.40083 3.84 325906.0 1.002075 Y
6 IC 140-83168/14 1.0 0.968929 3.84 327506.0 0.968929 Y
7 ICIS 140-83168/15 2.0 2.000181 3.84 323293.0 1.00009 Y
8 IC 140-83168/7 4.0 3.666728 3.84 349180.0 0.916682 Y
9 IC 140-83168/5 8.0 7.417578 3.84 346991.0 0.927197 Y
10 IC 140-83168/3 16.0 13.568316 3.84 327617.0 0.84802 Y
RelResp = [0.9649]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 647 of 864
Calibration / Trichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.879
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.065222 3.84 342835.0 3.261091 Y
2 IC 140-83168/10 0.04 0.116635 3.84 334795.0 2.915886 Y
3 IC 140-83168/11 0.08 0.233238 3.84 329376.0 2.915477 Y
4 IC 140-83168/12 0.16 0.471122 3.84 319640.0 2.944513 Y
5 IC 140-83168/13 0.4 1.165976 3.84 325906.0 2.914941 Y
6 IC 140-83168/14 1.0 2.926648 3.84 327506.0 2.926648 Y
7 ICIS 140-83168/15 2.0 5.897836 3.84 323293.0 2.948918 Y
8 IC 140-83168/7 4.0 10.87166 3.84 349180.0 2.717915 Y
9 IC 140-83168/5 8.0 21.781521 3.84 346991.0 2.72269 Y
10 IC 140-83168/3 16.0 40.373536 3.84 327617.0 2.523346 Y
RelResp = [2.879]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 648 of 864
Calibration / Acrolein
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3047
Error Coefficients
Relative Standard Deviation:11.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.0 3.84 334795.0 0.0 N
3 IC 140-83168/11 0.08 0.023363 3.84 329376.0 0.292043 N
4 IC 140-83168/12 0.16 0.059947 3.84 319640.0 0.374672 Y
5 IC 140-83168/13 0.4 0.127829 3.84 325906.0 0.319572 Y
6 IC 140-83168/14 1.0 0.296572 3.84 327506.0 0.296572 Y
7 ICIS 140-83168/15 2.0 0.60851 3.84 323293.0 0.304255 Y
8 IC 140-83168/7 4.0 1.148085 3.84 349180.0 0.287021 Y
9 IC 140-83168/5 8.0 2.280886 3.84 346991.0 0.285111 Y
10 IC 140-83168/3 16.0 4.248489 3.84 327617.0 0.265531 Y
RelResp = [0.3047]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 649 of 864
Calibration / Acetonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3625
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.0 3.84 334795.0 0.0 N
3 IC 140-83168/11 0.08 0.038403 3.84 329376.0 0.480035 N
4 IC 140-83168/12 0.16 0.059443 3.84 319640.0 0.371518 Y
5 IC 140-83168/13 0.4 0.144289 3.84 325906.0 0.360722 Y
6 IC 140-83168/14 1.0 0.345371 3.84 327506.0 0.345371 Y
7 ICIS 140-83168/15 2.0 0.791784 3.84 323293.0 0.395892 Y
8 IC 140-83168/7 4.0 1.439467 3.84 349180.0 0.359867 Y
9 IC 140-83168/5 8.0 2.892148 3.84 346991.0 0.361519 Y
10 IC 140-83168/3 16.0 5.476862 3.84 327617.0 0.342304 Y
RelResp = [0.3625]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 650 of 864
Calibration / Acetone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3974
Error Coefficients
Relative Standard Deviation:9.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.06 0.042932 3.84 342835.0 0.71554 N
2 IC 140-83168/10 0.12 0.06844 3.84 334795.0 0.570331 N
3 IC 140-83168/11 0.24 0.120233 3.84 329376.0 0.500972 N
4 IC 140-83168/12 0.48 0.23454 3.84 319640.0 0.488625 N
5 IC 140-83168/13 1.2 0.517607 3.84 325906.0 0.431339 Y
6 IC 140-83168/14 3.0 1.23389 3.84 327506.0 0.411297 Y
7 ICIS 140-83168/15 6.0 2.67251 3.84 323293.0 0.445418 Y
8 IC 140-83168/7 12.0 4.56411 3.84 349180.0 0.380343 Y
9 IC 140-83168/5 24.0 8.983343 3.84 346991.0 0.374306 Y
10 IC 140-83168/3 48.0 16.390839 3.84 327617.0 0.341476 Y
RelResp = [0.3974]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 651 of 864
Calibration / Isopropyl alcohol
Curve Type:Quadratic
Weighting:None
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.225
Second Order:-0.005467
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.06 0.091992 3.84 342835.0 1.533192 N
2 IC 140-83168/10 0.12 0.15335 3.84 334795.0 1.277916 Y
3 IC 140-83168/11 0.24 0.287158 3.84 329376.0 1.196493 Y
4 IC 140-83168/12 0.48 0.579652 3.84 319640.0 1.207609 Y
5 IC 140-83168/13 1.2 1.376424 3.84 325906.0 1.14702 Y
6 IC 140-83168/14 3.0 3.460357 3.84 327506.0 1.153452 Y
7 ICIS 140-83168/15 6.0 7.363921 3.84 323293.0 1.22732 Y
8 IC 140-83168/7 12.0 13.371092 3.84 349180.0 1.114258 Y
9 IC 140-83168/5 24.0 26.629265 3.84 346991.0 1.109553 Y
10 IC 140-83168/3 48.0 46.165305 3.84 327617.0 0.961777 Y
RelResp = [1.225]x + [-0.005467]x^2
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 652 of 864
Calibration / Pentane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1577
Error Coefficients
Relative Standard Deviation:7.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.0 3.84 342835.0 0.0 N
2 IC 140-83168/10 0.04 0.006859 3.84 334795.0 0.171472 Y
3 IC 140-83168/11 0.08 0.012509 3.84 329376.0 0.156368 Y
4 IC 140-83168/12 0.16 0.027451 3.84 319640.0 0.171568 Y
5 IC 140-83168/13 0.4 0.063755 3.84 325906.0 0.159388 Y
6 IC 140-83168/14 1.0 0.159565 3.84 327506.0 0.159565 Y
7 ICIS 140-83168/15 2.0 0.326413 3.84 323293.0 0.163207 Y
8 IC 140-83168/7 4.0 0.608871 3.84 349180.0 0.152218 Y
9 IC 140-83168/5 8.0 1.212774 3.84 346991.0 0.151597 Y
10 IC 140-83168/3 16.0 2.13586 3.84 327617.0 0.133491 Y
RelResp = [0.1577]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 653 of 864
Calibration / Ethyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.011
Error Coefficients
Relative Standard Deviation:4.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.022872 3.84 342835.0 1.143594 N
2 IC 140-83168/10 0.04 0.04035 3.84 334795.0 1.008761 Y
3 IC 140-83168/11 0.08 0.082378 3.84 329376.0 1.029729 Y
4 IC 140-83168/12 0.16 0.169294 3.84 319640.0 1.05809 Y
5 IC 140-83168/13 0.4 0.41967 3.84 325906.0 1.049176 Y
6 IC 140-83168/14 1.0 1.02624 3.84 327506.0 1.02624 Y
7 ICIS 140-83168/15 2.0 2.08949 3.84 323293.0 1.044745 Y
8 IC 140-83168/7 4.0 3.896954 3.84 349180.0 0.974239 Y
9 IC 140-83168/5 8.0 7.843343 3.84 346991.0 0.980418 Y
10 IC 140-83168/3 16.0 14.817482 3.84 327617.0 0.926093 Y
RelResp = [1.011]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 654 of 864
Calibration / 1,1-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.017
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.026871 3.84 342835.0 1.343527 N
2 IC 140-83168/10 0.04 0.04425 3.84 334795.0 1.106253 Y
3 IC 140-83168/11 0.08 0.085689 3.84 329376.0 1.071116 Y
4 IC 140-83168/12 0.16 0.170219 3.84 319640.0 1.063872 Y
5 IC 140-83168/13 0.4 0.402975 3.84 325906.0 1.007437 Y
6 IC 140-83168/14 1.0 1.008981 3.84 327506.0 1.008981 Y
7 ICIS 140-83168/15 2.0 2.036586 3.84 323293.0 1.018293 Y
8 IC 140-83168/7 4.0 3.879513 3.84 349180.0 0.969878 Y
9 IC 140-83168/5 8.0 7.850458 3.84 346991.0 0.981307 Y
10 IC 140-83168/3 16.0 14.785706 3.84 327617.0 0.924107 Y
RelResp = [1.017]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 655 of 864
Calibration / 2-Methyl-2-propanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.717
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.040278 3.84 342835.0 2.01389 N
2 IC 140-83168/10 0.04 0.073326 3.84 334795.0 1.833146 N
3 IC 140-83168/11 0.08 0.140624 3.84 329376.0 1.757797 Y
4 IC 140-83168/12 0.16 0.285765 3.84 319640.0 1.786034 Y
5 IC 140-83168/13 0.4 0.670002 3.84 325906.0 1.675006 Y
6 IC 140-83168/14 1.0 1.709759 3.84 327506.0 1.709759 Y
7 ICIS 140-83168/15 2.0 3.623088 3.84 323293.0 1.811544 Y
8 IC 140-83168/7 4.0 6.733768 3.84 349180.0 1.683442 Y
9 IC 140-83168/5 8.0 13.677804 3.84 346991.0 1.709725 Y
10 IC 140-83168/3 16.0 25.586669 3.84 327617.0 1.599167 Y
RelResp = [1.717]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 656 of 864
Calibration / Acrylonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6474
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.01884 3.84 342835.0 0.941981 N
2 IC 140-83168/10 0.04 0.033102 3.84 334795.0 0.827539 N
3 IC 140-83168/11 0.08 0.05216 3.84 329376.0 0.651997 Y
4 IC 140-83168/12 0.16 0.113143 3.84 319640.0 0.707146 Y
5 IC 140-83168/13 0.4 0.272931 3.84 325906.0 0.682327 Y
6 IC 140-83168/14 1.0 0.648895 3.84 327506.0 0.648895 Y
7 ICIS 140-83168/15 2.0 1.30387 3.84 323293.0 0.651935 Y
8 IC 140-83168/7 4.0 2.463822 3.84 349180.0 0.615956 Y
9 IC 140-83168/5 8.0 5.013178 3.84 346991.0 0.626647 Y
10 IC 140-83168/3 16.0 9.508746 3.84 327617.0 0.594297 Y
RelResp = [0.6474]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 657 of 864
Calibration / 1,1,2-Trichloro-1,2,2-trifluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.25
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.051131 3.84 342835.0 2.556565 Y
2 IC 140-83168/10 0.04 0.09193 3.84 334795.0 2.298242 Y
3 IC 140-83168/11 0.08 0.18165 3.84 329376.0 2.270621 Y
4 IC 140-83168/12 0.16 0.370401 3.84 319640.0 2.315004 Y
5 IC 140-83168/13 0.4 0.903744 3.84 325906.0 2.259361 Y
6 IC 140-83168/14 1.0 2.259462 3.84 327506.0 2.259462 Y
7 ICIS 140-83168/15 2.0 4.56534 3.84 323293.0 2.28267 Y
8 IC 140-83168/7 4.0 8.553375 3.84 349180.0 2.138344 Y
9 IC 140-83168/5 8.0 17.139903 3.84 346991.0 2.142488 Y
10 IC 140-83168/3 16.0 31.587319 3.84 327617.0 1.974207 Y
RelResp = [2.25]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 658 of 864
Calibration / Methylene Chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9621
Error Coefficients
Relative Standard Deviation:20.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.060428 3.84 342835.0 3.021395 N
2 IC 140-83168/10 0.04 0.078074 3.84 334795.0 1.951857 N
3 IC 140-83168/11 0.08 0.110627 3.84 329376.0 1.382833 Y
4 IC 140-83168/12 0.16 0.18144 3.84 319640.0 1.134001 Y
5 IC 140-83168/13 0.4 0.376876 3.84 325906.0 0.942191 Y
6 IC 140-83168/14 1.0 0.907501 3.84 327506.0 0.907501 Y
7 ICIS 140-83168/15 2.0 1.777211 3.84 323293.0 0.888606 Y
8 IC 140-83168/7 4.0 3.329202 3.84 349180.0 0.832301 Y
9 IC 140-83168/5 8.0 6.66005 3.84 346991.0 0.832506 Y
10 IC 140-83168/3 16.0 12.430441 3.84 327617.0 0.776903 Y
RelResp = [0.9621]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 659 of 864
Calibration / 3-Chloro-1-propene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9314
Error Coefficients
Relative Standard Deviation:15.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.029256 3.84 342835.0 1.462814 N
2 IC 140-83168/10 0.04 0.041107 3.84 334795.0 1.027686 Y
3 IC 140-83168/11 0.08 0.101999 3.84 329376.0 1.274993 Y
4 IC 140-83168/12 0.16 0.152391 3.84 319640.0 0.952447 Y
5 IC 140-83168/13 0.4 0.353017 3.84 325906.0 0.882542 Y
6 IC 140-83168/14 1.0 0.847927 3.84 327506.0 0.847927 Y
7 ICIS 140-83168/15 2.0 1.758718 3.84 323293.0 0.879359 Y
8 IC 140-83168/7 4.0 3.671083 3.84 349180.0 0.917771 Y
9 IC 140-83168/5 8.0 6.640307 3.84 346991.0 0.830038 Y
10 IC 140-83168/3 16.0 12.311426 3.84 327617.0 0.769464 Y
RelResp = [0.9314]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 660 of 864
Calibration / Carbon disulfide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.75
Error Coefficients
Relative Standard Deviation:7.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.104917 3.84 342835.0 5.245859 N
2 IC 140-83168/10 0.04 0.149313 3.84 334795.0 3.732816 N
3 IC 140-83168/11 0.08 0.248977 3.84 329376.0 3.112212 Y
4 IC 140-83168/12 0.16 0.471951 3.84 319640.0 2.949693 Y
5 IC 140-83168/13 0.4 1.108042 3.84 325906.0 2.770104 Y
6 IC 140-83168/14 1.0 2.704975 3.84 327506.0 2.704975 Y
7 ICIS 140-83168/15 2.0 5.423212 3.84 323293.0 2.711606 Y
8 IC 140-83168/7 4.0 10.357883 3.84 349180.0 2.589471 Y
9 IC 140-83168/5 8.0 21.142947 3.84 346991.0 2.642868 Y
10 IC 140-83168/3 16.0 40.285464 3.84 327617.0 2.517842 Y
RelResp = [2.75]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 661 of 864
Calibration / trans-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.044
Error Coefficients
Relative Standard Deviation:7.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.027117 3.84 342835.0 1.355848 N
2 IC 140-83168/10 0.04 0.046957 3.84 334795.0 1.173924 Y
3 IC 140-83168/11 0.08 0.090842 3.84 329376.0 1.135529 Y
4 IC 140-83168/12 0.16 0.169967 3.84 319640.0 1.062295 Y
5 IC 140-83168/13 0.4 0.415806 3.84 325906.0 1.039514 Y
6 IC 140-83168/14 1.0 1.055471 3.84 327506.0 1.055471 Y
7 ICIS 140-83168/15 2.0 2.087554 3.84 323293.0 1.043777 Y
8 IC 140-83168/7 4.0 3.969745 3.84 349180.0 0.992436 Y
9 IC 140-83168/5 8.0 7.907241 3.84 346991.0 0.988405 Y
10 IC 140-83168/3 16.0 14.529508 3.84 327617.0 0.908094 Y
RelResp = [1.044]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 662 of 864
Calibration / 2-Methylpentane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.981
Error Coefficients
Relative Standard Deviation:7.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.050672 3.84 342835.0 2.533604 N
2 IC 140-83168/10 0.04 0.081217 3.84 334795.0 2.030425 N
3 IC 140-83168/11 0.08 0.165829 3.84 329376.0 2.072865 Y
4 IC 140-83168/12 0.16 0.335069 3.84 319640.0 2.094181 Y
5 IC 140-83168/13 0.4 0.812218 3.84 325906.0 2.030544 Y
6 IC 140-83168/14 1.0 2.096074 3.84 327506.0 2.096074 Y
7 ICIS 140-83168/15 2.0 4.112143 3.84 323293.0 2.056072 Y
8 IC 140-83168/7 4.0 7.657841 3.84 349180.0 1.91446 Y
9 IC 140-83168/5 8.0 15.106266 3.84 346991.0 1.888283 Y
10 IC 140-83168/3 16.0 27.130865 3.84 327617.0 1.695679 Y
RelResp = [1.981]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 663 of 864
Calibration / Methyl tert-butyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.813
Error Coefficients
Relative Standard Deviation:2.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.072144 3.84 342835.0 3.607193 N
2 IC 140-83168/10 0.04 0.120122 3.84 334795.0 3.003056 N
3 IC 140-83168/11 0.08 0.230055 3.84 329376.0 2.875692 Y
4 IC 140-83168/12 0.16 0.459985 3.84 319640.0 2.874909 Y
5 IC 140-83168/13 0.4 1.131642 3.84 325906.0 2.829105 Y
6 IC 140-83168/14 1.0 2.856486 3.84 327506.0 2.856486 Y
7 ICIS 140-83168/15 2.0 5.696448 3.84 323293.0 2.848224 Y
8 IC 140-83168/7 4.0 11.040522 3.84 349180.0 2.760131 Y
9 IC 140-83168/5 8.0 22.253067 3.84 346991.0 2.781633 Y
10 IC 140-83168/3 16.0 42.784687 3.84 327617.0 2.674043 Y
RelResp = [2.813]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 664 of 864
Calibration / 1,1-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.81
Error Coefficients
Relative Standard Deviation:5.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.037959 3.84 342835.0 1.897963 Y
2 IC 140-83168/10 0.04 0.077765 3.84 334795.0 1.944115 Y
3 IC 140-83168/11 0.08 0.14643 3.84 329376.0 1.83037 Y
4 IC 140-83168/12 0.16 0.304507 3.84 319640.0 1.903166 Y
5 IC 140-83168/13 0.4 0.71791 3.84 325906.0 1.794775 Y
6 IC 140-83168/14 1.0 1.824711 3.84 327506.0 1.824711 Y
7 ICIS 140-83168/15 2.0 3.609975 3.84 323293.0 1.804988 Y
8 IC 140-83168/7 4.0 6.843169 3.84 349180.0 1.710792 Y
9 IC 140-83168/5 8.0 13.945039 3.84 346991.0 1.74313 Y
10 IC 140-83168/3 16.0 26.368132 3.84 327617.0 1.648008 Y
RelResp = [1.81]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 665 of 864
Calibration / Vinyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.173
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.048342 3.84 342835.0 2.417116 N
2 IC 140-83168/10 0.04 0.086872 3.84 334795.0 2.171789 Y
3 IC 140-83168/11 0.08 0.175762 3.84 329376.0 2.197027 Y
4 IC 140-83168/12 0.16 0.372371 3.84 319640.0 2.327318 Y
5 IC 140-83168/13 0.4 0.841144 3.84 325906.0 2.102859 Y
6 IC 140-83168/14 1.0 2.102675 3.84 327506.0 2.102675 Y
7 ICIS 140-83168/15 2.0 4.135495 3.84 323293.0 2.067748 Y
8 IC 140-83168/7 4.0 8.538221 3.84 349180.0 2.134555 Y
9 IC 140-83168/5 8.0 17.9963 3.84 346991.0 2.249538 Y
10 IC 140-83168/3 16.0 35.303733 3.84 327617.0 2.206483 Y
RelResp = [2.173]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
IC 140-83168/3
3/25/2024
9:50:51 AM
Page 666 of 864
Calibration / 2-Butanone (MEK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4691
Error Coefficients
Relative Standard Deviation:3.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.010999 3.84 342835.0 0.549956 N
2 IC 140-83168/10 0.04 0.01834 3.84 334795.0 0.458501 Y
3 IC 140-83168/11 0.08 0.038345 3.84 329376.0 0.479306 Y
4 IC 140-83168/12 0.16 0.077679 3.84 319640.0 0.485496 Y
5 IC 140-83168/13 0.4 0.185964 3.84 325906.0 0.46491 Y
6 IC 140-83168/14 1.0 0.472798 3.84 327506.0 0.472798 Y
7 ICIS 140-83168/15 2.0 0.987019 3.84 323293.0 0.493509 Y
8 IC 140-83168/7 4.0 1.84369 3.84 349180.0 0.460923 Y
9 IC 140-83168/5 8.0 3.754013 3.84 346991.0 0.469252 Y
10 IC 140-83168/3 16.0 7.002092 3.84 327617.0 0.437631 Y
RelResp = [0.4691]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 667 of 864
Calibration / Hexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7565
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.022245 3.84 342835.0 1.112232 N
2 IC 140-83168/10 0.04 0.036749 3.84 334795.0 0.918723 N
3 IC 140-83168/11 0.08 0.065987 3.84 329376.0 0.824832 Y
4 IC 140-83168/12 0.16 0.127319 3.84 319640.0 0.795745 Y
5 IC 140-83168/13 0.4 0.304496 3.84 325906.0 0.76124 Y
6 IC 140-83168/14 1.0 0.779043 3.84 327506.0 0.779043 Y
7 ICIS 140-83168/15 2.0 1.522089 3.84 323293.0 0.761044 Y
8 IC 140-83168/7 4.0 2.9111 3.84 349180.0 0.727775 Y
9 IC 140-83168/5 8.0 5.857889 3.84 346991.0 0.732236 Y
10 IC 140-83168/3 16.0 10.722937 3.84 327617.0 0.670184 Y
RelResp = [0.7565]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 668 of 864
Calibration / cis-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.103
Error Coefficients
Relative Standard Deviation:2.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.024966 3.84 342835.0 1.248321 N
2 IC 140-83168/10 0.04 0.044915 3.84 334795.0 1.122884 Y
3 IC 140-83168/11 0.08 0.091565 3.84 329376.0 1.144564 Y
4 IC 140-83168/12 0.16 0.180251 3.84 319640.0 1.126567 Y
5 IC 140-83168/13 0.4 0.436437 3.84 325906.0 1.091093 Y
6 IC 140-83168/14 1.0 1.115256 3.84 327506.0 1.115256 Y
7 ICIS 140-83168/15 2.0 2.21366 3.84 323293.0 1.10683 Y
8 IC 140-83168/7 4.0 4.311274 3.84 349180.0 1.077818 Y
9 IC 140-83168/5 8.0 8.748134 3.84 346991.0 1.093517 Y
10 IC 140-83168/3 16.0 16.786727 3.84 327617.0 1.04917 Y
RelResp = [1.103]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 669 of 864
Calibration / Ethyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.166
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.049362 3.84 342835.0 2.468079 N
2 IC 140-83168/10 0.04 0.080632 3.84 334795.0 2.015801 N
3 IC 140-83168/11 0.08 0.18524 3.84 329376.0 2.315506 Y
4 IC 140-83168/12 0.16 0.359432 3.84 319640.0 2.246452 Y
5 IC 140-83168/13 0.4 0.843064 3.84 325906.0 2.10766 Y
6 IC 140-83168/14 1.0 2.198855 3.84 327506.0 2.198855 Y
7 ICIS 140-83168/15 2.0 4.345577 3.84 323293.0 2.172789 Y
8 IC 140-83168/7 4.0 8.368853 3.84 349180.0 2.092213 Y
9 IC 140-83168/5 8.0 17.151213 3.84 346991.0 2.143902 Y
10 IC 140-83168/3 16.0 32.751813 3.84 327617.0 2.046988 Y
RelResp = [2.166]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
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Page 670 of 864
Calibration / Chloroform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.218
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.053562 3.84 342835.0 2.678093 N
2 IC 140-83168/10 0.04 0.094854 3.84 334795.0 2.371362 N
3 IC 140-83168/11 0.08 0.179749 3.84 329376.0 2.246867 Y
4 IC 140-83168/12 0.16 0.369632 3.84 319640.0 2.310199 Y
5 IC 140-83168/13 0.4 0.908457 3.84 325906.0 2.271143 Y
6 IC 140-83168/14 1.0 2.275161 3.84 327506.0 2.275161 Y
7 ICIS 140-83168/15 2.0 4.526452 3.84 323293.0 2.263226 Y
8 IC 140-83168/7 4.0 8.595098 3.84 349180.0 2.148775 Y
9 IC 140-83168/5 8.0 17.35849 3.84 346991.0 2.169811 Y
10 IC 140-83168/3 16.0 32.901314 3.84 327617.0 2.056332 Y
RelResp = [2.218]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 671 of 864
Calibration / Tetrahydrofuran
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.066
Error Coefficients
Relative Standard Deviation:2.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.029783 3.84 342835.0 1.489136 N
2 IC 140-83168/10 0.04 0.051235 3.84 334795.0 1.280879 N
3 IC 140-83168/11 0.08 0.086202 3.84 329376.0 1.077528 Y
4 IC 140-83168/12 0.16 0.174592 3.84 319640.0 1.091203 Y
5 IC 140-83168/13 0.4 0.42846 3.84 325906.0 1.071151 Y
6 IC 140-83168/14 1.0 1.076247 3.84 327506.0 1.076247 Y
7 ICIS 140-83168/15 2.0 2.187256 3.84 323293.0 1.093628 Y
8 IC 140-83168/7 4.0 4.137848 3.84 349180.0 1.034462 Y
9 IC 140-83168/5 8.0 8.488933 3.84 346991.0 1.061117 Y
10 IC 140-83168/3 16.0 16.371863 3.84 327617.0 1.023241 Y
RelResp = [1.066]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 672 of 864
Calibration / 1,1,1-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.51
Error Coefficients
Relative Standard Deviation:4.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.055746 3.84 342835.0 2.7873 Y
2 IC 140-83168/10 0.04 0.102734 3.84 334795.0 2.568354 Y
3 IC 140-83168/11 0.08 0.198857 3.84 329376.0 2.485718 Y
4 IC 140-83168/12 0.16 0.41461 3.84 319640.0 2.591315 Y
5 IC 140-83168/13 0.4 0.985927 3.84 325906.0 2.464819 Y
6 IC 140-83168/14 1.0 2.497596 3.84 327506.0 2.497596 Y
7 ICIS 140-83168/15 2.0 5.018738 3.84 323293.0 2.509369 Y
8 IC 140-83168/7 4.0 9.63772 3.84 349180.0 2.40943 Y
9 IC 140-83168/5 8.0 19.567698 3.84 346991.0 2.445962 Y
10 IC 140-83168/3 16.0 37.508864 3.84 327617.0 2.344304 Y
RelResp = [2.51]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 673 of 864
Calibration / 1,2-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.313
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.006781 3.84 1604900.0 0.339042 Y
2 IC 140-83168/10 0.04 0.013555 3.84 1564659.0 0.338865 Y
3 IC 140-83168/11 0.08 0.024502 3.84 1541660.0 0.306278 Y
4 IC 140-83168/12 0.16 0.051223 3.84 1500663.0 0.320146 Y
5 IC 140-83168/13 0.4 0.1262 3.84 1523374.0 0.3155 Y
6 IC 140-83168/14 1.0 0.319467 3.84 1526327.0 0.319467 Y
7 ICIS 140-83168/15 2.0 0.639252 3.84 1516562.0 0.319626 Y
8 IC 140-83168/7 4.0 1.202198 3.84 1623979.0 0.30055 Y
9 IC 140-83168/5 8.0 2.355352 3.84 1661844.0 0.294419 Y
10 IC 140-83168/3 16.0 4.422902 3.84 1597380.0 0.276431 Y
RelResp = [0.313]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 674 of 864
Calibration / n-Butanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.08544
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.002278 3.84 1604900.0 0.113891 N
2 IC 140-83168/10 0.04 0.004145 3.84 1564659.0 0.103629 N
3 IC 140-83168/11 0.08 0.007213 3.84 1541660.0 0.090168 Y
4 IC 140-83168/12 0.16 0.014135 3.84 1500663.0 0.088345 Y
5 IC 140-83168/13 0.4 0.030957 3.84 1523374.0 0.077392 Y
6 IC 140-83168/14 1.0 0.082429 3.84 1526327.0 0.082429 Y
7 ICIS 140-83168/15 2.0 0.176835 3.84 1516562.0 0.088418 Y
8 IC 140-83168/7 4.0 0.348338 3.84 1623979.0 0.087084 Y
9 IC 140-83168/5 8.0 0.698347 3.84 1661844.0 0.087293 Y
10 IC 140-83168/3 16.0 1.318533 3.84 1597380.0 0.082408 Y
RelResp = [0.08544]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 675 of 864
Calibration / Cyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.09916
Error Coefficients
Relative Standard Deviation:10.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.003034 3.84 1604900.0 0.151695 N
2 IC 140-83168/10 0.04 0.00523 3.84 1564659.0 0.130748 N
3 IC 140-83168/11 0.08 0.008397 3.84 1541660.0 0.104957 Y
4 IC 140-83168/12 0.16 0.018201 3.84 1500663.0 0.113758 Y
5 IC 140-83168/13 0.4 0.040828 3.84 1523374.0 0.10207 Y
6 IC 140-83168/14 1.0 0.103484 3.84 1526327.0 0.103484 Y
7 ICIS 140-83168/15 2.0 0.203034 3.84 1516562.0 0.101517 Y
8 IC 140-83168/7 4.0 0.388888 3.84 1623979.0 0.097222 Y
9 IC 140-83168/5 8.0 0.735233 3.84 1661844.0 0.091904 Y
10 IC 140-83168/3 16.0 1.254384 3.84 1597380.0 0.078399 Y
RelResp = [0.09916]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 676 of 864
Calibration / Benzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6405
Error Coefficients
Relative Standard Deviation:10.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.018067 3.84 1604900.0 0.903353 N
2 IC 140-83168/10 0.04 0.029725 3.84 1564659.0 0.743134 N
3 IC 140-83168/11 0.08 0.057339 3.84 1541660.0 0.716734 Y
4 IC 140-83168/12 0.16 0.111984 3.84 1500663.0 0.699899 Y
5 IC 140-83168/13 0.4 0.265543 3.84 1523374.0 0.663857 Y
6 IC 140-83168/14 1.0 0.667068 3.84 1526327.0 0.667068 Y
7 ICIS 140-83168/15 2.0 1.307919 3.84 1516562.0 0.65396 Y
8 IC 140-83168/7 4.0 2.486756 3.84 1623979.0 0.621689 Y
9 IC 140-83168/5 8.0 4.737464 3.84 1661844.0 0.592183 Y
10 IC 140-83168/3 16.0 8.138104 3.84 1597380.0 0.508631 Y
RelResp = [0.6405]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 677 of 864
Calibration / Carbon tetrachloride
Curve Type:Quadratic
Weighting:None
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6057
Second Order:-0.006232
Error Coefficients
Relative Standard Deviation:9.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.012466 3.84 1604900.0 0.623291 Y
2 IC 140-83168/10 0.04 0.022733 3.84 1564659.0 0.568333 Y
3 IC 140-83168/11 0.08 0.04547 3.84 1541660.0 0.568374 Y
4 IC 140-83168/12 0.16 0.076201 3.84 1500663.0 0.476253 Y
5 IC 140-83168/13 0.4 0.226514 3.84 1523374.0 0.566286 Y
6 IC 140-83168/14 1.0 0.541865 3.84 1526327.0 0.541865 Y
7 ICIS 140-83168/15 2.0 1.187905 3.84 1516562.0 0.593953 Y
8 IC 140-83168/7 4.0 2.287513 3.84 1623979.0 0.571878 Y
9 IC 140-83168/5 8.0 4.489019 3.84 1661844.0 0.561127 Y
10 IC 140-83168/3 16.0 8.088323 3.84 1597380.0 0.50552 Y
RelResp = [0.6057]x + [-0.006232]x^2
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 678 of 864
Calibration / 2,3-Dimethylpentane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1464
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.004044 3.84 1604900.0 0.202181 N
2 IC 140-83168/10 0.04 0.006599 3.84 1564659.0 0.164984 N
3 IC 140-83168/11 0.08 0.012292 3.84 1541660.0 0.153653 Y
4 IC 140-83168/12 0.16 0.025517 3.84 1500663.0 0.159482 Y
5 IC 140-83168/13 0.4 0.05963 3.84 1523374.0 0.149075 Y
6 IC 140-83168/14 1.0 0.149595 3.84 1526327.0 0.149595 Y
7 ICIS 140-83168/15 2.0 0.29947 3.84 1516562.0 0.149735 Y
8 IC 140-83168/7 4.0 0.573903 3.84 1623979.0 0.143476 Y
9 IC 140-83168/5 8.0 1.108813 3.84 1661844.0 0.138602 Y
10 IC 140-83168/3 16.0 2.044558 3.84 1597380.0 0.127785 Y
RelResp = [0.1464]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 679 of 864
Calibration / Thiophene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3796
Error Coefficients
Relative Standard Deviation:3.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.009171 3.84 1604900.0 0.458556 N
2 IC 140-83168/10 0.04 0.016215 3.84 1564659.0 0.405374 N
3 IC 140-83168/11 0.08 0.029593 3.84 1541660.0 0.369918 Y
4 IC 140-83168/12 0.16 0.061705 3.84 1500663.0 0.385654 Y
5 IC 140-83168/13 0.4 0.15328 3.84 1523374.0 0.3832 Y
6 IC 140-83168/14 1.0 0.391105 3.84 1526327.0 0.391105 Y
7 ICIS 140-83168/15 2.0 0.779343 3.84 1516562.0 0.389671 Y
8 IC 140-83168/7 4.0 1.529111 3.84 1623979.0 0.382278 Y
9 IC 140-83168/5 8.0 3.035451 3.84 1661844.0 0.379431 Y
10 IC 140-83168/3 16.0 5.688956 3.84 1597380.0 0.35556 Y
RelResp = [0.3796]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 680 of 864
Calibration / Isooctane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9738
Error Coefficients
Relative Standard Deviation:5.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.023917 3.84 1604900.0 1.195858 N
2 IC 140-83168/10 0.04 0.041751 3.84 1564659.0 1.043775 N
3 IC 140-83168/11 0.08 0.079106 3.84 1541660.0 0.988825 Y
4 IC 140-83168/12 0.16 0.162289 3.84 1500663.0 1.014304 Y
5 IC 140-83168/13 0.4 0.399731 3.84 1523374.0 0.999327 Y
6 IC 140-83168/14 1.0 1.008141 3.84 1526327.0 1.008141 Y
7 ICIS 140-83168/15 2.0 2.001967 3.84 1516562.0 1.000984 Y
8 IC 140-83168/7 4.0 3.873288 3.84 1623979.0 0.968322 Y
9 IC 140-83168/5 8.0 7.588335 3.84 1661844.0 0.948542 Y
10 IC 140-83168/3 16.0 13.792381 3.84 1597380.0 0.862024 Y
RelResp = [0.9738]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 681 of 864
Calibration / n-Heptane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2128
Error Coefficients
Relative Standard Deviation:4.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.005596 3.84 1604900.0 0.279823 N
2 IC 140-83168/10 0.04 0.009127 3.84 1564659.0 0.22818 N
3 IC 140-83168/11 0.08 0.016402 3.84 1541660.0 0.205026 Y
4 IC 140-83168/12 0.16 0.034299 3.84 1500663.0 0.214369 Y
5 IC 140-83168/13 0.4 0.086352 3.84 1523374.0 0.215881 Y
6 IC 140-83168/14 1.0 0.22388 3.84 1526327.0 0.22388 Y
7 ICIS 140-83168/15 2.0 0.444923 3.84 1516562.0 0.222461 Y
8 IC 140-83168/7 4.0 0.86049 3.84 1623979.0 0.215123 Y
9 IC 140-83168/5 8.0 1.695639 3.84 1661844.0 0.211955 Y
10 IC 140-83168/3 16.0 3.101847 3.84 1597380.0 0.193865 Y
RelResp = [0.2128]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 682 of 864
Calibration / 1,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2352
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.005166 3.84 1604900.0 0.258289 N
2 IC 140-83168/10 0.04 0.010001 3.84 1564659.0 0.250023 Y
3 IC 140-83168/11 0.08 0.018826 3.84 1541660.0 0.23532 Y
4 IC 140-83168/12 0.16 0.04033 3.84 1500663.0 0.252065 Y
5 IC 140-83168/13 0.4 0.096662 3.84 1523374.0 0.241655 Y
6 IC 140-83168/14 1.0 0.245244 3.84 1526327.0 0.245244 Y
7 ICIS 140-83168/15 2.0 0.478933 3.84 1516562.0 0.239467 Y
8 IC 140-83168/7 4.0 0.917647 3.84 1623979.0 0.229412 Y
9 IC 140-83168/5 8.0 1.780906 3.84 1661844.0 0.222613 Y
10 IC 140-83168/3 16.0 3.218693 3.84 1597380.0 0.201168 Y
RelResp = [0.2352]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 683 of 864
Calibration / Trichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3639
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.008267 3.84 1604900.0 0.413334 Y
2 IC 140-83168/10 0.04 0.014595 3.84 1564659.0 0.36488 Y
3 IC 140-83168/11 0.08 0.02911 3.84 1541660.0 0.363878 Y
4 IC 140-83168/12 0.16 0.060576 3.84 1500663.0 0.378601 Y
5 IC 140-83168/13 0.4 0.145758 3.84 1523374.0 0.364395 Y
6 IC 140-83168/14 1.0 0.372617 3.84 1526327.0 0.372617 Y
7 ICIS 140-83168/15 2.0 0.730107 3.84 1516562.0 0.365053 Y
8 IC 140-83168/7 4.0 1.41743 3.84 1623979.0 0.354357 Y
9 IC 140-83168/5 8.0 2.756891 3.84 1661844.0 0.344611 Y
10 IC 140-83168/3 16.0 5.070912 3.84 1597380.0 0.316932 Y
RelResp = [0.3639]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 684 of 864
Calibration / Dibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2986
Error Coefficients
Relative Standard Deviation:12.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.009197 3.84 1604900.0 0.459872 N
2 IC 140-83168/10 0.04 0.015012 3.84 1564659.0 0.37531 Y
3 IC 140-83168/11 0.08 0.027636 3.84 1541660.0 0.345446 Y
4 IC 140-83168/12 0.16 0.04705 3.84 1500663.0 0.294062 Y
5 IC 140-83168/13 0.4 0.114211 3.84 1523374.0 0.285528 Y
6 IC 140-83168/14 1.0 0.288567 3.84 1526327.0 0.288567 Y
7 ICIS 140-83168/15 2.0 0.571039 3.84 1516562.0 0.285519 Y
8 IC 140-83168/7 4.0 1.155609 3.84 1623979.0 0.288902 Y
9 IC 140-83168/5 8.0 2.165231 3.84 1661844.0 0.270654 Y
10 IC 140-83168/3 16.0 4.053597 3.84 1597380.0 0.25335 Y
RelResp = [0.2986]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 685 of 864
Calibration / 1,4-Dioxane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.09932
Error Coefficients
Relative Standard Deviation:7.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.003077 3.84 1604900.0 0.153849 N
2 IC 140-83168/10 0.04 0.004562 3.84 1564659.0 0.114059 N
3 IC 140-83168/11 0.08 0.008693 3.84 1541660.0 0.108662 N
4 IC 140-83168/12 0.16 0.017311 3.84 1500663.0 0.108192 Y
5 IC 140-83168/13 0.4 0.038423 3.84 1523374.0 0.096058 Y
6 IC 140-83168/14 1.0 0.099363 3.84 1526327.0 0.099363 Y
7 ICIS 140-83168/15 2.0 0.215788 3.84 1516562.0 0.107894 Y
8 IC 140-83168/7 4.0 0.396573 3.84 1623979.0 0.099143 Y
9 IC 140-83168/5 8.0 0.777585 3.84 1661844.0 0.097198 Y
10 IC 140-83168/3 16.0 1.398271 3.84 1597380.0 0.087392 Y
RelResp = [0.09932]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 686 of 864
Calibration / Dichlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4936
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.010257 3.84 1604900.0 0.512869 Y
2 IC 140-83168/10 0.04 0.019263 3.84 1564659.0 0.481577 Y
3 IC 140-83168/11 0.08 0.037171 3.84 1541660.0 0.464632 Y
4 IC 140-83168/12 0.16 0.07988 3.84 1500663.0 0.499251 Y
5 IC 140-83168/13 0.4 0.200581 3.84 1523374.0 0.501453 Y
6 IC 140-83168/14 1.0 0.513708 3.84 1526327.0 0.513708 Y
7 ICIS 140-83168/15 2.0 1.028399 3.84 1516562.0 0.5142 Y
8 IC 140-83168/7 4.0 1.982979 3.84 1623979.0 0.495745 Y
9 IC 140-83168/5 8.0 3.950931 3.84 1661844.0 0.493866 Y
10 IC 140-83168/3 16.0 7.345697 3.84 1597380.0 0.459106 Y
RelResp = [0.4936]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 687 of 864
Calibration / Methyl methacrylate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2886
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.007747 3.84 1604900.0 0.387374 N
2 IC 140-83168/10 0.04 0.012389 3.84 1564659.0 0.309721 N
3 IC 140-83168/11 0.08 0.020651 3.84 1541660.0 0.258143 N
4 IC 140-83168/12 0.16 0.051252 3.84 1500663.0 0.320322 Y
5 IC 140-83168/13 0.4 0.115618 3.84 1523374.0 0.289045 Y
6 IC 140-83168/14 1.0 0.286396 3.84 1526327.0 0.286396 Y
7 ICIS 140-83168/15 2.0 0.577569 3.84 1516562.0 0.288785 Y
8 IC 140-83168/7 4.0 1.138154 3.84 1623979.0 0.284538 Y
9 IC 140-83168/5 8.0 2.269415 3.84 1661844.0 0.283677 Y
10 IC 140-83168/3 16.0 4.281399 3.84 1597380.0 0.267587 Y
RelResp = [0.2886]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 688 of 864
Calibration / Methylcyclohexane
Curve Type:Quadratic
Weighting:None
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.421
Second Order:-0.003232
Error Coefficients
Relative Standard Deviation:3.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.009477 3.84 1604900.0 0.473869 N
2 IC 140-83168/10 0.04 0.016821 3.84 1564659.0 0.420529 N
3 IC 140-83168/11 0.08 0.031222 3.84 1541660.0 0.390281 Y
4 IC 140-83168/12 0.16 0.065858 3.84 1500663.0 0.41161 Y
5 IC 140-83168/13 0.4 0.16213 3.84 1523374.0 0.405326 Y
6 IC 140-83168/14 1.0 0.414734 3.84 1526327.0 0.414734 Y
7 ICIS 140-83168/15 2.0 0.818944 3.84 1516562.0 0.409472 Y
8 IC 140-83168/7 4.0 1.61559 3.84 1623979.0 0.403897 Y
9 IC 140-83168/5 8.0 3.180006 3.84 1661844.0 0.397501 Y
10 IC 140-83168/3 16.0 5.905921 3.84 1597380.0 0.36912 Y
RelResp = [0.421]x + [-0.003232]x^2
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 689 of 864
Calibration / 4-Methyl-2-pentanone (MIBK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4903
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.014758 3.84 1604900.0 0.7379 N
2 IC 140-83168/10 0.04 0.020547 3.84 1564659.0 0.513666 N
3 IC 140-83168/11 0.08 0.039973 3.84 1541660.0 0.499659 Y
4 IC 140-83168/12 0.16 0.081068 3.84 1500663.0 0.506672 Y
5 IC 140-83168/13 0.4 0.19672 3.84 1523374.0 0.491799 Y
6 IC 140-83168/14 1.0 0.495971 3.84 1526327.0 0.495971 Y
7 ICIS 140-83168/15 2.0 1.011645 3.84 1516562.0 0.505822 Y
8 IC 140-83168/7 4.0 1.951485 3.84 1623979.0 0.487871 Y
9 IC 140-83168/5 8.0 3.864445 3.84 1661844.0 0.483056 Y
10 IC 140-83168/3 16.0 7.219622 3.84 1597380.0 0.451226 Y
RelResp = [0.4903]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 690 of 864
Calibration / cis-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3788
Error Coefficients
Relative Standard Deviation:4.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.008051 3.84 1604900.0 0.402567 Y
2 IC 140-83168/10 0.04 0.015152 3.84 1564659.0 0.378807 Y
3 IC 140-83168/11 0.08 0.027653 3.84 1541660.0 0.345664 Y
4 IC 140-83168/12 0.16 0.058859 3.84 1500663.0 0.367869 Y
5 IC 140-83168/13 0.4 0.14932 3.84 1523374.0 0.3733 Y
6 IC 140-83168/14 1.0 0.385712 3.84 1526327.0 0.385712 Y
7 ICIS 140-83168/15 2.0 0.78272 3.84 1516562.0 0.39136 Y
8 IC 140-83168/7 4.0 1.547412 3.84 1623979.0 0.386853 Y
9 IC 140-83168/5 8.0 3.107903 3.84 1661844.0 0.388488 Y
10 IC 140-83168/3 16.0 5.879916 3.84 1597380.0 0.367495 Y
RelResp = [0.3788]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 691 of 864
Calibration / trans-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4089
Error Coefficients
Relative Standard Deviation:4.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.008358 4.0 1420462.0 0.417892 Y
2 IC 140-83168/10 0.04 0.015555 4.0 1386594.0 0.388867 Y
3 IC 140-83168/11 0.08 0.030722 4.0 1365261.0 0.384029 Y
4 IC 140-83168/12 0.16 0.064373 4.0 1336701.0 0.402334 Y
5 IC 140-83168/13 0.4 0.15549 4.0 1362070.0 0.388725 Y
6 IC 140-83168/14 1.0 0.413359 4.0 1368090.0 0.413359 Y
7 ICIS 140-83168/15 2.0 0.854342 4.0 1361919.0 0.427171 Y
8 IC 140-83168/7 4.0 1.684391 4.0 1464940.0 0.421098 Y
9 IC 140-83168/5 8.0 3.438609 4.0 1482931.0 0.429826 Y
10 IC 140-83168/3 16.0 6.647713 4.0 1426322.0 0.415482 Y
RelResp = [0.4089]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
IC 140-83168/3
3/25/2024
9:50:51 AM
Page 692 of 864
Calibration / Toluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9749
Error Coefficients
Relative Standard Deviation:4.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.028695 4.0 1420462.0 1.434744 N
2 IC 140-83168/10 0.04 0.046355 4.0 1386594.0 1.158883 N
3 IC 140-83168/11 0.08 0.083694 4.0 1365261.0 1.046174 Y
4 IC 140-83168/12 0.16 0.16006 4.0 1336701.0 1.000373 Y
5 IC 140-83168/13 0.4 0.389918 4.0 1362070.0 0.974796 Y
6 IC 140-83168/14 1.0 0.990952 4.0 1368090.0 0.990952 Y
7 ICIS 140-83168/15 2.0 1.951026 4.0 1361919.0 0.975513 Y
8 IC 140-83168/7 4.0 3.84727 4.0 1464940.0 0.961818 Y
9 IC 140-83168/5 8.0 7.634807 4.0 1482931.0 0.954351 Y
10 IC 140-83168/3 16.0 14.319807 4.0 1426322.0 0.894988 Y
RelResp = [0.9749]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 693 of 864
Calibration / 1,1,2-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2817
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.006223 4.0 1420462.0 0.311166 Y
2 IC 140-83168/10 0.04 0.011686 4.0 1386594.0 0.292155 Y
3 IC 140-83168/11 0.08 0.023128 4.0 1365261.0 0.289102 Y
4 IC 140-83168/12 0.16 0.045952 4.0 1336701.0 0.2872 Y
5 IC 140-83168/13 0.4 0.111565 4.0 1362070.0 0.278914 Y
6 IC 140-83168/14 1.0 0.284022 4.0 1368090.0 0.284022 Y
7 ICIS 140-83168/15 2.0 0.561566 4.0 1361919.0 0.280783 Y
8 IC 140-83168/7 4.0 1.093085 4.0 1464940.0 0.273271 Y
9 IC 140-83168/5 8.0 2.157109 4.0 1482931.0 0.269639 Y
10 IC 140-83168/3 16.0 4.017194 4.0 1426322.0 0.251075 Y
RelResp = [0.2817]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 694 of 864
Calibration / 2-Hexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2904
Error Coefficients
Relative Standard Deviation:2.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.006451 4.0 1420462.0 0.322571 N
2 IC 140-83168/10 0.04 0.01168 4.0 1386594.0 0.29201 N
3 IC 140-83168/11 0.08 0.020776 4.0 1365261.0 0.259694 N
4 IC 140-83168/12 0.16 0.046431 4.0 1336701.0 0.290192 Y
5 IC 140-83168/13 0.4 0.112893 4.0 1362070.0 0.282232 Y
6 IC 140-83168/14 1.0 0.294139 4.0 1368090.0 0.294139 Y
7 ICIS 140-83168/15 2.0 0.602785 4.0 1361919.0 0.301392 Y
8 IC 140-83168/7 4.0 1.161159 4.0 1464940.0 0.29029 Y
9 IC 140-83168/5 8.0 2.380081 4.0 1482931.0 0.29751 Y
10 IC 140-83168/3 16.0 4.429662 4.0 1426322.0 0.276854 Y
RelResp = [0.2904]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 695 of 864
Calibration / C8 Range
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.128
Error Coefficients
Relative Standard Deviation:7.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.052624 3.84 1604900.0 2.631222 N
2 IC 140-83168/10 0.04 0.094723 3.84 1564659.0 2.368066 N
3 IC 140-83168/11 0.08 0.177456 3.84 1541660.0 2.218201 N
4 IC 140-83168/12 0.16 0.35893 3.84 1500663.0 2.243312 N
5 IC 140-83168/13 0.4 0.895433 3.84 1523374.0 2.238583 Y
6 IC 140-83168/14 1.0 2.276084 3.84 1526327.0 2.276084 Y
7 ICIS 140-83168/15 2.0 4.494287 3.84 1516562.0 2.247144 Y
8 IC 140-83168/7 4.0 8.48965 3.84 1623979.0 2.122412 Y
9 IC 140-83168/5 8.0 16.348488 3.84 1661844.0 2.043561 Y
10 IC 140-83168/3 16.0 29.468374 3.84 1597380.0 1.841773 Y
RelResp = [2.128]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 696 of 864
Calibration / n-Octane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2904
Error Coefficients
Relative Standard Deviation:4.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.006984 4.0 1420462.0 0.349182 N
2 IC 140-83168/10 0.04 0.012145 4.0 1386594.0 0.303622 Y
3 IC 140-83168/11 0.08 0.022413 4.0 1365261.0 0.280166 Y
4 IC 140-83168/12 0.16 0.047257 4.0 1336701.0 0.295354 Y
5 IC 140-83168/13 0.4 0.118358 4.0 1362070.0 0.295895 Y
6 IC 140-83168/14 1.0 0.30098 4.0 1368090.0 0.30098 Y
7 ICIS 140-83168/15 2.0 0.600133 4.0 1361919.0 0.300066 Y
8 IC 140-83168/7 4.0 1.165618 4.0 1464940.0 0.291404 Y
9 IC 140-83168/5 8.0 2.286941 4.0 1482931.0 0.285868 Y
10 IC 140-83168/3 16.0 4.164064 4.0 1426322.0 0.260254 Y
RelResp = [0.2904]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 697 of 864
Calibration / Chlorodibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6661
Error Coefficients
Relative Standard Deviation:8.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.011585 4.0 1420462.0 0.579248 N
2 IC 140-83168/10 0.04 0.022305 4.0 1386594.0 0.557625 N
3 IC 140-83168/11 0.08 0.043523 4.0 1365261.0 0.544035 Y
4 IC 140-83168/12 0.16 0.102078 4.0 1336701.0 0.637989 Y
5 IC 140-83168/13 0.4 0.263208 4.0 1362070.0 0.658021 Y
6 IC 140-83168/14 1.0 0.69213 4.0 1368090.0 0.69213 Y
7 ICIS 140-83168/15 2.0 1.430006 4.0 1361919.0 0.715003 Y
8 IC 140-83168/7 4.0 2.740208 4.0 1464940.0 0.685052 Y
9 IC 140-83168/5 8.0 5.754199 4.0 1482931.0 0.719275 Y
10 IC 140-83168/3 16.0 10.838893 4.0 1426322.0 0.677431 Y
RelResp = [0.6661]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
IC 140-83168/3
3/25/2024
9:50:51 AM
Page 698 of 864
Calibration / Ethylene Dibromide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5526
Error Coefficients
Relative Standard Deviation:2.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.013148 4.0 1420462.0 0.657392 N
2 IC 140-83168/10 0.04 0.022475 4.0 1386594.0 0.56188 Y
3 IC 140-83168/11 0.08 0.043007 4.0 1365261.0 0.53759 Y
4 IC 140-83168/12 0.16 0.087167 4.0 1336701.0 0.544793 Y
5 IC 140-83168/13 0.4 0.221604 4.0 1362070.0 0.55401 Y
6 IC 140-83168/14 1.0 0.562653 4.0 1368090.0 0.562653 Y
7 ICIS 140-83168/15 2.0 1.13323 4.0 1361919.0 0.566615 Y
8 IC 140-83168/7 4.0 2.237708 4.0 1464940.0 0.559427 Y
9 IC 140-83168/5 8.0 4.451174 4.0 1482931.0 0.556397 Y
10 IC 140-83168/3 16.0 8.477508 4.0 1426322.0 0.529844 Y
RelResp = [0.5526]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 699 of 864
Calibration / Tetrachloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.405
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.009031 4.0 1420462.0 0.451543 Y
2 IC 140-83168/10 0.04 0.016939 4.0 1386594.0 0.423484 Y
3 IC 140-83168/11 0.08 0.032961 4.0 1365261.0 0.412009 Y
4 IC 140-83168/12 0.16 0.065044 4.0 1336701.0 0.406523 Y
5 IC 140-83168/13 0.4 0.163701 4.0 1362070.0 0.409252 Y
6 IC 140-83168/14 1.0 0.413496 4.0 1368090.0 0.413496 Y
7 ICIS 140-83168/15 2.0 0.805801 4.0 1361919.0 0.402901 Y
8 IC 140-83168/7 4.0 1.56111 4.0 1464940.0 0.390277 Y
9 IC 140-83168/5 8.0 3.07333 4.0 1482931.0 0.384166 Y
10 IC 140-83168/3 16.0 5.703957 4.0 1426322.0 0.356497 Y
RelResp = [0.405]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 700 of 864
Calibration / Chlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8214
Error Coefficients
Relative Standard Deviation:5.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.019937 4.0 1420462.0 0.996859 N
2 IC 140-83168/10 0.04 0.034447 4.0 1386594.0 0.861175 Y
3 IC 140-83168/11 0.08 0.067378 4.0 1365261.0 0.84222 Y
4 IC 140-83168/12 0.16 0.138792 4.0 1336701.0 0.867453 Y
5 IC 140-83168/13 0.4 0.334136 4.0 1362070.0 0.835339 Y
6 IC 140-83168/14 1.0 0.838144 4.0 1368090.0 0.838144 Y
7 ICIS 140-83168/15 2.0 1.653984 4.0 1361919.0 0.826992 Y
8 IC 140-83168/7 4.0 3.243431 4.0 1464940.0 0.810858 Y
9 IC 140-83168/5 8.0 6.306138 4.0 1482931.0 0.788267 Y
10 IC 140-83168/3 16.0 11.560517 4.0 1426322.0 0.722532 Y
RelResp = [0.8214]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 701 of 864
Calibration / Ethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.291
Error Coefficients
Relative Standard Deviation:3.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.032271 4.0 1420462.0 1.61356 N
2 IC 140-83168/10 0.04 0.0537 4.0 1386594.0 1.342498 Y
3 IC 140-83168/11 0.08 0.103473 4.0 1365261.0 1.293416 Y
4 IC 140-83168/12 0.16 0.210201 4.0 1336701.0 1.313757 Y
5 IC 140-83168/13 0.4 0.511433 4.0 1362070.0 1.278583 Y
6 IC 140-83168/14 1.0 1.313317 4.0 1368090.0 1.313317 Y
7 ICIS 140-83168/15 2.0 2.616082 4.0 1361919.0 1.308041 Y
8 IC 140-83168/7 4.0 5.174202 4.0 1464940.0 1.293551 Y
9 IC 140-83168/5 8.0 10.227284 4.0 1482931.0 1.27841 Y
10 IC 140-83168/3 16.0 19.140752 4.0 1426322.0 1.196297 Y
RelResp = [1.291]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 702 of 864
Calibration / m-Xylene & p-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9859
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.04 0.047359 4.0 1420462.0 1.183981 N
2 IC 140-83168/10 0.08 0.083566 4.0 1386594.0 1.044574 Y
3 IC 140-83168/11 0.16 0.160277 4.0 1365261.0 1.001732 Y
4 IC 140-83168/12 0.32 0.331889 4.0 1336701.0 1.037152 Y
5 IC 140-83168/13 0.8 0.80331 4.0 1362070.0 1.004137 Y
6 IC 140-83168/14 2.0 2.03246 4.0 1368090.0 1.01623 Y
7 ICIS 140-83168/15 4.0 4.025461 4.0 1361919.0 1.006365 Y
8 IC 140-83168/7 8.0 7.827029 4.0 1464940.0 0.978379 Y
9 IC 140-83168/5 16.0 15.028621 4.0 1482931.0 0.939289 Y
10 IC 140-83168/3 32.0 27.060181 4.0 1426322.0 0.845631 Y
RelResp = [0.9859]x
Concentration
0 10 20 30 40
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 703 of 864
Calibration / n-Nonane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5527
Error Coefficients
Relative Standard Deviation:6.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.013911 4.0 1420462.0 0.695548 N
2 IC 140-83168/10 0.04 0.024457 4.0 1386594.0 0.611426 N
3 IC 140-83168/11 0.08 0.045029 4.0 1365261.0 0.562859 Y
4 IC 140-83168/12 0.16 0.092374 4.0 1336701.0 0.577336 Y
5 IC 140-83168/13 0.4 0.227771 4.0 1362070.0 0.569427 Y
6 IC 140-83168/14 1.0 0.578801 4.0 1368090.0 0.578801 Y
7 ICIS 140-83168/15 2.0 1.158413 4.0 1361919.0 0.579206 Y
8 IC 140-83168/7 4.0 2.202023 4.0 1464940.0 0.550506 Y
9 IC 140-83168/5 8.0 4.246682 4.0 1482931.0 0.530835 Y
10 IC 140-83168/3 16.0 7.557281 4.0 1426322.0 0.47233 Y
RelResp = [0.5527]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 704 of 864
Calibration / Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7681
Error Coefficients
Relative Standard Deviation:6.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.016642 4.0 1420462.0 0.832124 Y
2 IC 140-83168/10 0.04 0.030183 4.0 1386594.0 0.754583 Y
3 IC 140-83168/11 0.08 0.058002 4.0 1365261.0 0.725026 Y
4 IC 140-83168/12 0.16 0.123112 4.0 1336701.0 0.76945 Y
5 IC 140-83168/13 0.4 0.308947 4.0 1362070.0 0.772369 Y
6 IC 140-83168/14 1.0 0.807464 4.0 1368090.0 0.807464 Y
7 ICIS 140-83168/15 2.0 1.609432 4.0 1361919.0 0.804716 Y
8 IC 140-83168/7 4.0 3.215198 4.0 1464940.0 0.803799 Y
9 IC 140-83168/5 8.0 5.985039 4.0 1482931.0 0.74813 Y
10 IC 140-83168/3 16.0 10.615011 4.0 1426322.0 0.663438 Y
RelResp = [0.7681]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 705 of 864
Calibration / Bromoform
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.02535
Slope:0.7691
Error Coefficients
Relative Standard Deviation:6.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.009904 4.0 1420462.0 0.495191 N
2 IC 140-83168/10 0.04 0.018765 4.0 1386594.0 0.469135 N
3 IC 140-83168/11 0.08 0.033813 4.0 1365261.0 0.422666 Y
4 IC 140-83168/12 0.16 0.107049 4.0 1336701.0 0.669054 Y
5 IC 140-83168/13 0.4 0.279436 4.0 1362070.0 0.698591 Y
6 IC 140-83168/14 1.0 0.761877 4.0 1368090.0 0.761877 Y
7 ICIS 140-83168/15 2.0 1.598351 4.0 1361919.0 0.799175 Y
8 IC 140-83168/7 4.0 2.763734 4.0 1464940.0 0.690933 Y
9 IC 140-83168/5 8.0 6.431358 4.0 1482931.0 0.80392 Y
10 IC 140-83168/3 16.0 11.502926 4.0 1426322.0 0.718933 Y
RelResp = [-0.02535] + [0.7691]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
Intercept = 0.0330
3/25/2024
9:50:51 AM
Page 706 of 864
Calibration / o-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.119
Error Coefficients
Relative Standard Deviation:9.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.027729 4.0 1420462.0 1.38645 Y
2 IC 140-83168/10 0.04 0.047625 4.0 1386594.0 1.190615 Y
3 IC 140-83168/11 0.08 0.087837 4.0 1365261.0 1.097959 Y
4 IC 140-83168/12 0.16 0.185466 4.0 1336701.0 1.15916 Y
5 IC 140-83168/13 0.4 0.431185 4.0 1362070.0 1.077962 Y
6 IC 140-83168/14 1.0 1.093408 4.0 1368090.0 1.093408 Y
7 ICIS 140-83168/15 2.0 2.158836 4.0 1361919.0 1.079418 Y
8 IC 140-83168/7 4.0 4.202558 4.0 1464940.0 1.05064 Y
9 IC 140-83168/5 8.0 8.451678 4.0 1482931.0 1.05646 Y
10 IC 140-83168/3 16.0 16.005076 4.0 1426322.0 1.000317 Y
RelResp = [1.119]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 707 of 864
Calibration / 1,1,2,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7791
Error Coefficients
Relative Standard Deviation:6.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.017991 4.0 1420462.0 0.899566 Y
2 IC 140-83168/10 0.04 0.031346 4.0 1386594.0 0.783647 Y
3 IC 140-83168/11 0.08 0.061773 4.0 1365261.0 0.77216 Y
4 IC 140-83168/12 0.16 0.125419 4.0 1336701.0 0.78387 Y
5 IC 140-83168/13 0.4 0.309012 4.0 1362070.0 0.77253 Y
6 IC 140-83168/14 1.0 0.786483 4.0 1368090.0 0.786483 Y
7 ICIS 140-83168/15 2.0 1.581166 4.0 1361919.0 0.790583 Y
8 IC 140-83168/7 4.0 3.032053 4.0 1464940.0 0.758013 Y
9 IC 140-83168/5 8.0 5.930296 4.0 1482931.0 0.741287 Y
10 IC 140-83168/3 16.0 11.241683 4.0 1426322.0 0.702605 Y
RelResp = [0.7791]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 708 of 864
Calibration / 1,2,3-Trichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2463
Error Coefficients
Relative Standard Deviation:7.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.005922 4.0 1420462.0 0.296101 Y
2 IC 140-83168/10 0.04 0.009701 4.0 1386594.0 0.242537 Y
3 IC 140-83168/11 0.08 0.018889 4.0 1365261.0 0.236109 Y
4 IC 140-83168/12 0.16 0.040398 4.0 1336701.0 0.252487 Y
5 IC 140-83168/13 0.4 0.096994 4.0 1362070.0 0.242484 Y
6 IC 140-83168/14 1.0 0.248735 4.0 1368090.0 0.248735 Y
7 ICIS 140-83168/15 2.0 0.491512 4.0 1361919.0 0.245756 Y
8 IC 140-83168/7 4.0 0.949775 4.0 1464940.0 0.237444 Y
9 IC 140-83168/5 8.0 1.87428 4.0 1482931.0 0.234285 Y
10 IC 140-83168/3 16.0 3.634285 4.0 1426322.0 0.227143 Y
RelResp = [0.2463]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 709 of 864
Calibration / Isopropylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.672
Error Coefficients
Relative Standard Deviation:9.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.041358 4.0 1420462.0 2.067919 Y
2 IC 140-83168/10 0.04 0.070036 4.0 1386594.0 1.750909 Y
3 IC 140-83168/11 0.08 0.132757 4.0 1365261.0 1.659463 Y
4 IC 140-83168/12 0.16 0.264514 4.0 1336701.0 1.653212 Y
5 IC 140-83168/13 0.4 0.657373 4.0 1362070.0 1.643432 Y
6 IC 140-83168/14 1.0 1.65321 4.0 1368090.0 1.65321 Y
7 ICIS 140-83168/15 2.0 3.268911 4.0 1361919.0 1.634455 Y
8 IC 140-83168/7 4.0 6.386828 4.0 1464940.0 1.596707 Y
9 IC 140-83168/5 8.0 12.570198 4.0 1482931.0 1.571275 Y
10 IC 140-83168/3 16.0 23.807194 4.0 1426322.0 1.48795 Y
RelResp = [1.672]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 710 of 864
Calibration / 4-Bromofluorobenzene (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7156
Error Coefficients
Relative Standard Deviation:2.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/3 4.08 3.077527 4.0 1426322.0 0.754296 Y
2 IC 140-83168/5 4.08 2.938235 4.0 1482931.0 0.720156 Y
3 IC 140-83168/7 4.08 2.902642 4.0 1464940.0 0.711432 Y
4 IC 140-83168/9 4.08 2.845987 4.0 1420462.0 0.697546 Y
5 IC 140-83168/10 4.08 2.874511 4.0 1386594.0 0.704537 Y
6 IC 140-83168/11 4.08 2.888544 4.0 1365261.0 0.707976 Y
7 IC 140-83168/12 4.08 2.895621 4.0 1336701.0 0.709711 Y
8 IC 140-83168/13 4.08 2.904089 4.0 1362070.0 0.711786 Y
9 IC 140-83168/14 4.08 2.93055 4.0 1368090.0 0.718272 Y
10 ICIS 140-83168/15 4.08 2.937652 4.0 1361919.0 0.720013 Y
RelResp = [0.7156]x
Concentration
0 1 2 3 4 5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/3
IC 140-83168/5IC 140-83168/14ICIS 140-83168/15
3/25/2024
9:50:51 AM
Page 711 of 864
Calibration / N-Propylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4829
Error Coefficients
Relative Standard Deviation:6.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.011174 4.0 1420462.0 0.558691 Y
2 IC 140-83168/10 0.04 0.018636 4.0 1386594.0 0.46589 Y
3 IC 140-83168/11 0.08 0.036904 4.0 1365261.0 0.461304 Y
4 IC 140-83168/12 0.16 0.077612 4.0 1336701.0 0.485075 Y
5 IC 140-83168/13 0.4 0.192959 4.0 1362070.0 0.482398 Y
6 IC 140-83168/14 1.0 0.491167 4.0 1368090.0 0.491167 Y
7 ICIS 140-83168/15 2.0 0.982088 4.0 1361919.0 0.491044 Y
8 IC 140-83168/7 4.0 1.918615 4.0 1464940.0 0.479654 Y
9 IC 140-83168/5 8.0 3.748738 4.0 1482931.0 0.468592 Y
10 IC 140-83168/3 16.0 7.120095 4.0 1426322.0 0.445006 Y
RelResp = [0.4829]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 712 of 864
Calibration / 2-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4559
Error Coefficients
Relative Standard Deviation:5.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.010143 4.0 1420462.0 0.507159 Y
2 IC 140-83168/10 0.04 0.018295 4.0 1386594.0 0.45738 Y
3 IC 140-83168/11 0.08 0.037391 4.0 1365261.0 0.467383 Y
4 IC 140-83168/12 0.16 0.076155 4.0 1336701.0 0.475967 Y
5 IC 140-83168/13 0.4 0.181089 4.0 1362070.0 0.452723 Y
6 IC 140-83168/14 1.0 0.465332 4.0 1368090.0 0.465332 Y
7 ICIS 140-83168/15 2.0 0.903734 4.0 1361919.0 0.451867 Y
8 IC 140-83168/7 4.0 1.753685 4.0 1464940.0 0.438421 Y
9 IC 140-83168/5 8.0 3.440554 4.0 1482931.0 0.430069 Y
10 IC 140-83168/3 16.0 6.595938 4.0 1426322.0 0.412246 Y
RelResp = [0.4559]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 713 of 864
Calibration / 4-Ethyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.718
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.040283 4.0 1420462.0 2.014133 Y
2 IC 140-83168/10 0.04 0.068225 4.0 1386594.0 1.705618 Y
3 IC 140-83168/11 0.08 0.133862 4.0 1365261.0 1.67327 Y
4 IC 140-83168/12 0.16 0.275762 4.0 1336701.0 1.723516 Y
5 IC 140-83168/13 0.4 0.682993 4.0 1362070.0 1.707482 Y
6 IC 140-83168/14 1.0 1.738792 4.0 1368090.0 1.738792 Y
7 ICIS 140-83168/15 2.0 3.447932 4.0 1361919.0 1.723966 Y
8 IC 140-83168/7 4.0 6.682556 4.0 1464940.0 1.670639 Y
9 IC 140-83168/5 8.0 13.243265 4.0 1482931.0 1.655408 Y
10 IC 140-83168/3 16.0 25.048338 4.0 1426322.0 1.565521 Y
RelResp = [1.718]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 714 of 864
Calibration / 1,3,5-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7437
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.016741 4.0 1420462.0 0.837052 Y
2 IC 140-83168/10 0.04 0.029883 4.0 1386594.0 0.747082 Y
3 IC 140-83168/11 0.08 0.059089 4.0 1365261.0 0.738613 Y
4 IC 140-83168/12 0.16 0.123007 4.0 1336701.0 0.768796 Y
5 IC 140-83168/13 0.4 0.294094 4.0 1362070.0 0.735234 Y
6 IC 140-83168/14 1.0 0.758055 4.0 1368090.0 0.758055 Y
7 ICIS 140-83168/15 2.0 1.48501 4.0 1361919.0 0.742505 Y
8 IC 140-83168/7 4.0 2.892097 4.0 1464940.0 0.723024 Y
9 IC 140-83168/5 8.0 5.695728 4.0 1482931.0 0.711966 Y
10 IC 140-83168/3 16.0 10.796025 4.0 1426322.0 0.674752 Y
RelResp = [0.7437]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 715 of 864
Calibration / Alpha Methyl Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7365
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.015049 4.0 1420462.0 0.752431 N
2 IC 140-83168/10 0.04 0.025951 4.0 1386594.0 0.648784 N
3 IC 140-83168/11 0.08 0.05078 4.0 1365261.0 0.63475 N
4 IC 140-83168/12 0.16 0.114069 4.0 1336701.0 0.712931 Y
5 IC 140-83168/13 0.4 0.284332 4.0 1362070.0 0.71083 Y
6 IC 140-83168/14 1.0 0.765148 4.0 1368090.0 0.765148 Y
7 ICIS 140-83168/15 2.0 1.510119 4.0 1361919.0 0.75506 Y
8 IC 140-83168/7 4.0 3.035917 4.0 1464940.0 0.758979 Y
9 IC 140-83168/5 8.0 5.997466 4.0 1482931.0 0.749683 Y
10 IC 140-83168/3 16.0 11.25105 4.0 1426322.0 0.703191 Y
RelResp = [0.7365]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 716 of 864
Calibration / n-Decane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.856
Error Coefficients
Relative Standard Deviation:12.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.019813 4.0 1420462.0 0.990664 Y
2 IC 140-83168/10 0.04 0.034998 4.0 1386594.0 0.87495 Y
3 IC 140-83168/11 0.08 0.073015 4.0 1365261.0 0.912683 Y
4 IC 140-83168/12 0.16 0.149107 4.0 1336701.0 0.931921 Y
5 IC 140-83168/13 0.4 0.367776 4.0 1362070.0 0.919439 Y
6 IC 140-83168/14 1.0 0.903946 4.0 1368090.0 0.903946 Y
7 ICIS 140-83168/15 2.0 1.718631 4.0 1361919.0 0.859315 Y
8 IC 140-83168/7 4.0 3.210054 4.0 1464940.0 0.802513 Y
9 IC 140-83168/5 8.0 5.895516 4.0 1482931.0 0.73694 Y
10 IC 140-83168/3 16.0 10.046068 4.0 1426322.0 0.627879 Y
RelResp = [0.856]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 717 of 864
Calibration / tert-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.605
Error Coefficients
Relative Standard Deviation:9.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.037864 4.0 1420462.0 1.893187 Y
2 IC 140-83168/10 0.04 0.06768 4.0 1386594.0 1.691988 Y
3 IC 140-83168/11 0.08 0.129651 4.0 1365261.0 1.620642 Y
4 IC 140-83168/12 0.16 0.269589 4.0 1336701.0 1.684932 Y
5 IC 140-83168/13 0.4 0.646492 4.0 1362070.0 1.616231 Y
6 IC 140-83168/14 1.0 1.640611 4.0 1368090.0 1.640611 Y
7 ICIS 140-83168/15 2.0 3.198689 4.0 1361919.0 1.599345 Y
8 IC 140-83168/7 4.0 6.149781 4.0 1464940.0 1.537445 Y
9 IC 140-83168/5 8.0 11.726043 4.0 1482931.0 1.465755 Y
10 IC 140-83168/3 16.0 20.766335 4.0 1426322.0 1.297896 Y
RelResp = [1.605]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 718 of 864
Calibration / 1,2,4-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.435
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.033724 4.0 1420462.0 1.686212 Y
2 IC 140-83168/10 0.04 0.059299 4.0 1386594.0 1.482482 Y
3 IC 140-83168/11 0.08 0.115412 4.0 1365261.0 1.442655 Y
4 IC 140-83168/12 0.16 0.244465 4.0 1336701.0 1.527903 Y
5 IC 140-83168/13 0.4 0.586396 4.0 1362070.0 1.465989 Y
6 IC 140-83168/14 1.0 1.465576 4.0 1368090.0 1.465576 Y
7 ICIS 140-83168/15 2.0 2.860584 4.0 1361919.0 1.430292 Y
8 IC 140-83168/7 4.0 5.504471 4.0 1464940.0 1.376118 Y
9 IC 140-83168/5 8.0 10.486592 4.0 1482931.0 1.310824 Y
10 IC 140-83168/3 16.0 18.558648 4.0 1426322.0 1.159916 Y
RelResp = [1.435]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 719 of 864
Calibration / sec-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.144
Error Coefficients
Relative Standard Deviation:8.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.049446 4.0 1420462.0 2.472294 Y
2 IC 140-83168/10 0.04 0.089044 4.0 1386594.0 2.226102 Y
3 IC 140-83168/11 0.08 0.173502 4.0 1365261.0 2.168779 Y
4 IC 140-83168/12 0.16 0.358566 4.0 1336701.0 2.24104 Y
5 IC 140-83168/13 0.4 0.862725 4.0 1362070.0 2.156813 Y
6 IC 140-83168/14 1.0 2.192291 4.0 1368090.0 2.192291 Y
7 ICIS 140-83168/15 2.0 4.266894 4.0 1361919.0 2.133447 Y
8 IC 140-83168/7 4.0 8.258626 4.0 1464940.0 2.064657 Y
9 IC 140-83168/5 8.0 16.00044 4.0 1482931.0 2.000055 Y
10 IC 140-83168/3 16.0 28.619807 4.0 1426322.0 1.788738 Y
RelResp = [2.144]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 720 of 864
Calibration / 1,3-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.128
Error Coefficients
Relative Standard Deviation:9.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.027633 4.0 1420462.0 1.381663 Y
2 IC 140-83168/10 0.04 0.047079 4.0 1386594.0 1.176985 Y
3 IC 140-83168/11 0.08 0.087863 4.0 1365261.0 1.098288 Y
4 IC 140-83168/12 0.16 0.185283 4.0 1336701.0 1.158019 Y
5 IC 140-83168/13 0.4 0.447199 4.0 1362070.0 1.117997 Y
6 IC 140-83168/14 1.0 1.126628 4.0 1368090.0 1.126628 Y
7 ICIS 140-83168/15 2.0 2.19564 4.0 1361919.0 1.09782 Y
8 IC 140-83168/7 4.0 4.280287 4.0 1464940.0 1.070072 Y
9 IC 140-83168/5 8.0 8.488074 4.0 1482931.0 1.061009 Y
10 IC 140-83168/3 16.0 15.934537 4.0 1426322.0 0.995909 Y
RelResp = [1.128]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 721 of 864
Calibration / Benzyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9996
Error Coefficients
Relative Standard Deviation:10.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.02226 4.0 1420462.0 1.113018 N
2 IC 140-83168/10 0.04 0.03565 4.0 1386594.0 0.891249 N
3 IC 140-83168/11 0.08 0.066569 4.0 1365261.0 0.832112 N
4 IC 140-83168/12 0.16 0.131856 4.0 1336701.0 0.8241 Y
5 IC 140-83168/13 0.4 0.347662 4.0 1362070.0 0.869155 Y
6 IC 140-83168/14 1.0 1.012366 4.0 1368090.0 1.012366 Y
7 ICIS 140-83168/15 2.0 2.163224 4.0 1361919.0 1.081612 Y
8 IC 140-83168/7 4.0 4.333611 4.0 1464940.0 1.083403 Y
9 IC 140-83168/5 8.0 8.718534 4.0 1482931.0 1.089817 Y
10 IC 140-83168/3 16.0 16.58971 4.0 1426322.0 1.036857 Y
RelResp = [0.9996]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
IC 140-83168/3
3/25/2024
9:50:51 AM
Page 722 of 864
Calibration / 1,4-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.108
Error Coefficients
Relative Standard Deviation:8.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.026411 4.0 1420462.0 1.320556 Y
2 IC 140-83168/10 0.04 0.043773 4.0 1386594.0 1.094336 Y
3 IC 140-83168/11 0.08 0.090233 4.0 1365261.0 1.127916 Y
4 IC 140-83168/12 0.16 0.18557 4.0 1336701.0 1.159814 Y
5 IC 140-83168/13 0.4 0.439907 4.0 1362070.0 1.099767 Y
6 IC 140-83168/14 1.0 1.113403 4.0 1368090.0 1.113403 Y
7 ICIS 140-83168/15 2.0 2.177431 4.0 1361919.0 1.088715 Y
8 IC 140-83168/7 4.0 4.248895 4.0 1464940.0 1.062224 Y
9 IC 140-83168/5 8.0 8.373916 4.0 1482931.0 1.04674 Y
10 IC 140-83168/3 16.0 15.398927 4.0 1426322.0 0.962433 Y
RelResp = [1.108]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 723 of 864
Calibration / 4-Isopropyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.923
Error Coefficients
Relative Standard Deviation:6.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.043237 4.0 1420462.0 2.161832 Y
2 IC 140-83168/10 0.04 0.07964 4.0 1386594.0 1.990994 Y
3 IC 140-83168/11 0.08 0.152671 4.0 1365261.0 1.90839 Y
4 IC 140-83168/12 0.16 0.323663 4.0 1336701.0 2.022891 Y
5 IC 140-83168/13 0.4 0.772377 4.0 1362070.0 1.930943 Y
6 IC 140-83168/14 1.0 1.949822 4.0 1368090.0 1.949822 Y
7 ICIS 140-83168/15 2.0 3.811745 4.0 1361919.0 1.905873 Y
8 IC 140-83168/7 4.0 7.453255 4.0 1464940.0 1.863314 Y
9 IC 140-83168/5 8.0 14.544491 4.0 1482931.0 1.818061 Y
10 IC 140-83168/3 16.0 26.880584 4.0 1426322.0 1.680036 Y
RelResp = [1.923]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 724 of 864
Calibration / 1,2,3-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.468
Error Coefficients
Relative Standard Deviation:4.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.034532 4.0 1420462.0 1.726621 N
2 IC 140-83168/10 0.04 0.063491 4.0 1386594.0 1.587271 N
3 IC 140-83168/11 0.08 0.119582 4.0 1365261.0 1.494769 Y
4 IC 140-83168/12 0.16 0.249058 4.0 1336701.0 1.556612 Y
5 IC 140-83168/13 0.4 0.601564 4.0 1362070.0 1.503909 Y
6 IC 140-83168/14 1.0 1.51688 4.0 1368090.0 1.51688 Y
7 ICIS 140-83168/15 2.0 2.946393 4.0 1361919.0 1.473196 Y
8 IC 140-83168/7 4.0 5.740099 4.0 1464940.0 1.435025 Y
9 IC 140-83168/5 8.0 11.341288 4.0 1482931.0 1.417661 Y
10 IC 140-83168/3 16.0 21.595104 4.0 1426322.0 1.349694 Y
RelResp = [1.468]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 725 of 864
Calibration / 2,3-Dihydroindene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.444
Error Coefficients
Relative Standard Deviation:10.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.034913 4.0 1420462.0 1.745629 Y
2 IC 140-83168/10 0.04 0.060257 4.0 1386594.0 1.506425 Y
3 IC 140-83168/11 0.08 0.116388 4.0 1365261.0 1.45485 Y
4 IC 140-83168/12 0.16 0.244375 4.0 1336701.0 1.527342 Y
5 IC 140-83168/13 0.4 0.58503 4.0 1362070.0 1.462575 Y
6 IC 140-83168/14 1.0 1.488276 4.0 1368090.0 1.488276 Y
7 ICIS 140-83168/15 2.0 2.856957 4.0 1361919.0 1.428478 Y
8 IC 140-83168/7 4.0 5.546133 4.0 1464940.0 1.386533 Y
9 IC 140-83168/5 8.0 10.486481 4.0 1482931.0 1.31081 Y
10 IC 140-83168/3 16.0 18.124839 4.0 1426322.0 1.132802 Y
RelResp = [1.444]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 726 of 864
Calibration / 1,2-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.103
Error Coefficients
Relative Standard Deviation:12.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.027549 4.0 1420462.0 1.377439 Y
2 IC 140-83168/10 0.04 0.048487 4.0 1386594.0 1.212179 Y
3 IC 140-83168/11 0.08 0.087271 4.0 1365261.0 1.09089 Y
4 IC 140-83168/12 0.16 0.187064 4.0 1336701.0 1.169147 Y
5 IC 140-83168/13 0.4 0.440729 4.0 1362070.0 1.101823 Y
6 IC 140-83168/14 1.0 1.107617 4.0 1368090.0 1.107617 Y
7 ICIS 140-83168/15 2.0 2.140312 4.0 1361919.0 1.070156 Y
8 IC 140-83168/7 4.0 4.15543 4.0 1464940.0 1.038858 Y
9 IC 140-83168/5 8.0 7.912811 4.0 1482931.0 0.989101 Y
10 IC 140-83168/3 16.0 13.966386 4.0 1426322.0 0.872899 Y
RelResp = [1.103]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 727 of 864
Calibration / n-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.719
Error Coefficients
Relative Standard Deviation:13.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.04416 4.0 1420462.0 2.208014 Y
2 IC 140-83168/10 0.04 0.071441 4.0 1386594.0 1.786031 Y
3 IC 140-83168/11 0.08 0.138523 4.0 1365261.0 1.731537 Y
4 IC 140-83168/12 0.16 0.300609 4.0 1336701.0 1.878805 Y
5 IC 140-83168/13 0.4 0.690493 4.0 1362070.0 1.726233 Y
6 IC 140-83168/14 1.0 1.735579 4.0 1368090.0 1.735579 Y
7 ICIS 140-83168/15 2.0 3.327628 4.0 1361919.0 1.663814 Y
8 IC 140-83168/7 4.0 6.452696 4.0 1464940.0 1.613174 Y
9 IC 140-83168/5 8.0 12.184758 4.0 1482931.0 1.523095 Y
10 IC 140-83168/3 16.0 21.224655 4.0 1426322.0 1.326541 Y
RelResp = [1.719]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 728 of 864
Calibration / Indene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.253
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.029968 4.0 1420462.0 1.498386 Y
2 IC 140-83168/10 0.04 0.049653 4.0 1386594.0 1.241315 Y
3 IC 140-83168/11 0.08 0.094203 4.0 1365261.0 1.17754 Y
4 IC 140-83168/12 0.16 0.207292 4.0 1336701.0 1.295578 Y
5 IC 140-83168/13 0.4 0.500036 4.0 1362070.0 1.25009 Y
6 IC 140-83168/14 1.0 1.291131 4.0 1368090.0 1.291131 Y
7 ICIS 140-83168/15 2.0 2.512378 4.0 1361919.0 1.256189 Y
8 IC 140-83168/7 4.0 4.973623 4.0 1464940.0 1.243406 Y
9 IC 140-83168/5 8.0 9.587397 4.0 1482931.0 1.198425 Y
10 IC 140-83168/3 16.0 17.285014 4.0 1426322.0 1.080313 Y
RelResp = [1.253]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 729 of 864
Calibration / Undecane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.07
Error Coefficients
Relative Standard Deviation:18.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.028684 4.0 1420462.0 1.434181 N
2 IC 140-83168/10 0.04 0.052474 4.0 1386594.0 1.311848 N
3 IC 140-83168/11 0.08 0.10253 4.0 1365261.0 1.281623 Y
4 IC 140-83168/12 0.16 0.21305 4.0 1336701.0 1.331562 Y
5 IC 140-83168/13 0.4 0.459783 4.0 1362070.0 1.149456 Y
6 IC 140-83168/14 1.0 1.165882 4.0 1368090.0 1.165882 Y
7 ICIS 140-83168/15 2.0 2.048894 4.0 1361919.0 1.024447 Y
8 IC 140-83168/7 4.0 3.883425 4.0 1464940.0 0.970856 Y
9 IC 140-83168/5 8.0 7.061553 4.0 1482931.0 0.882694 Y
10 IC 140-83168/3 16.0 12.075397 4.0 1426322.0 0.754712 Y
RelResp = [1.07]x
Concentration
0 10 20
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 730 of 864
Calibration / 1,2-Dibromo-3-Chloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5563
Error Coefficients
Relative Standard Deviation:9.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.012148 4.0 1420462.0 0.607408 Y
2 IC 140-83168/10 0.04 0.020188 4.0 1386594.0 0.50469 Y
3 IC 140-83168/11 0.08 0.035466 4.0 1365261.0 0.443322 Y
4 IC 140-83168/12 0.16 0.090195 4.0 1336701.0 0.56372 Y
5 IC 140-83168/13 0.4 0.215716 4.0 1362070.0 0.539289 Y
6 IC 140-83168/14 1.0 0.582485 4.0 1368090.0 0.582485 Y
7 ICIS 140-83168/15 2.0 1.212833 4.0 1361919.0 0.606416 Y
8 IC 140-83168/7 4.0 2.147654 4.0 1464940.0 0.536913 Y
9 IC 140-83168/5 8.0 4.782647 4.0 1482931.0 0.597831 Y
10 IC 140-83168/3 16.0 9.30248 4.0 1426322.0 0.581405 Y
RelResp = [0.5563]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
IC 140-83168/3
3/25/2024
9:50:51 AM
Page 731 of 864
Calibration / 1,2,4,5-Tetramethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.914
Error Coefficients
Relative Standard Deviation:10.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.052355 4.0 1420462.0 2.61774 N
2 IC 140-83168/10 0.04 0.09132 4.0 1386594.0 2.283004 N
3 IC 140-83168/11 0.08 0.171516 4.0 1365261.0 2.143949 Y
4 IC 140-83168/12 0.16 0.360012 4.0 1336701.0 2.250073 Y
5 IC 140-83168/13 0.4 0.77907 4.0 1362070.0 1.947675 Y
6 IC 140-83168/14 1.0 1.965944 4.0 1368090.0 1.965944 Y
7 ICIS 140-83168/15 2.0 3.682231 4.0 1361919.0 1.841115 Y
8 IC 140-83168/7 4.0 7.183259 4.0 1464940.0 1.795815 Y
9 IC 140-83168/5 8.0 13.869317 4.0 1482931.0 1.733665 Y
10 IC 140-83168/3 16.0 26.105536 4.0 1426322.0 1.631596 Y
RelResp = [1.914]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 732 of 864
Calibration / Dodecane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9037
Error Coefficients
Relative Standard Deviation:29.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.037751 4.0 1420462.0 1.887555 N
2 IC 140-83168/10 0.04 0.068914 4.0 1386594.0 1.722855 N
3 IC 140-83168/11 0.08 0.134887 4.0 1365261.0 1.686088 N
4 IC 140-83168/12 0.16 0.283172 4.0 1336701.0 1.769824 N
5 IC 140-83168/13 0.4 0.482627 4.0 1362070.0 1.206568 Y
6 IC 140-83168/14 1.0 1.22839 4.0 1368090.0 1.22839 Y
7 ICIS 140-83168/15 2.0 1.781301 4.0 1361919.0 0.890651 Y
8 IC 140-83168/7 4.0 3.300261 4.0 1464940.0 0.825065 Y
9 IC 140-83168/5 8.0 5.563471 4.0 1482931.0 0.695434 Y
10 IC 140-83168/3 16.0 9.213485 4.0 1426322.0 0.575843 Y
RelResp = [0.9037]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 733 of 864
Calibration / 1,2,4-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6396
Error Coefficients
Relative Standard Deviation:8.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.022818 4.0 1420462.0 1.140896 N
2 IC 140-83168/10 0.04 0.033706 4.0 1386594.0 0.84264 N
3 IC 140-83168/11 0.08 0.05625 4.0 1365261.0 0.703126 Y
4 IC 140-83168/12 0.16 0.116484 4.0 1336701.0 0.728024 Y
5 IC 140-83168/13 0.4 0.243494 4.0 1362070.0 0.608735 Y
6 IC 140-83168/14 1.0 0.65765 4.0 1368090.0 0.65765 Y
7 ICIS 140-83168/15 2.0 1.193886 4.0 1361919.0 0.596943 Y
8 IC 140-83168/7 4.0 2.487477 4.0 1464940.0 0.621869 Y
9 IC 140-83168/5 8.0 4.915155 4.0 1482931.0 0.614394 Y
10 IC 140-83168/3 16.0 9.380204 4.0 1426322.0 0.586263 Y
RelResp = [0.6396]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 734 of 864
Calibration / Naphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.214
Error Coefficients
Relative Standard Deviation:19.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.045701 4.0 1420462.0 2.285031 N
2 IC 140-83168/10 0.04 0.064264 4.0 1386594.0 1.606599 Y
3 IC 140-83168/11 0.08 0.11492 4.0 1365261.0 1.436502 Y
4 IC 140-83168/12 0.16 0.230466 4.0 1336701.0 1.440412 Y
5 IC 140-83168/13 0.4 0.458461 4.0 1362070.0 1.146153 Y
6 IC 140-83168/14 1.0 1.232913 4.0 1368090.0 1.232913 Y
7 ICIS 140-83168/15 2.0 2.129739 4.0 1361919.0 1.064869 Y
8 IC 140-83168/7 4.0 4.242339 4.0 1464940.0 1.060585 Y
9 IC 140-83168/5 8.0 7.889249 4.0 1482931.0 0.986156 Y
10 IC 140-83168/3 16.0 15.269957 4.0 1426322.0 0.954372 Y
RelResp = [1.214]x
Concentration
0 10 20
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 735 of 864
Calibration / Hexachlorobutadiene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8864
Error Coefficients
Relative Standard Deviation:28.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.028303 4.0 1420462.0 1.415173 N
2 IC 140-83168/10 0.04 0.048129 4.0 1386594.0 1.203236 N
3 IC 140-83168/11 0.08 0.093951 4.0 1365261.0 1.174391 Y
4 IC 140-83168/12 0.16 0.19242 4.0 1336701.0 1.202625 Y
5 IC 140-83168/13 0.4 0.348892 4.0 1362070.0 0.872231 Y
6 IC 140-83168/14 1.0 0.823042 4.0 1368090.0 0.823042 Y
7 ICIS 140-83168/15 2.0 1.301769 4.0 1361919.0 0.650885 Y
8 IC 140-83168/7 4.0 2.38164 4.0 1464940.0 0.59541 Y
9 IC 140-83168/5 8.0 4.145202 4.0 1482931.0 0.51815 N
10 IC 140-83168/3 16.0 7.073486 4.0 1426322.0 0.442093 N
RelResp = [0.8864]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 736 of 864
Calibration / 1,2,3-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4732
Error Coefficients
Relative Standard Deviation:12.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.02 0.022804 4.0 1420462.0 1.140192 N
2 IC 140-83168/10 0.04 0.032497 4.0 1386594.0 0.812422 N
3 IC 140-83168/11 0.08 0.058556 4.0 1365261.0 0.731948 N
4 IC 140-83168/12 0.16 0.113575 4.0 1336701.0 0.709845 N
5 IC 140-83168/13 0.4 0.214926 4.0 1362070.0 0.537315 Y
6 IC 140-83168/14 1.0 0.553586 4.0 1368090.0 0.553586 Y
7 ICIS 140-83168/15 2.0 0.915176 4.0 1361919.0 0.457588 Y
8 IC 140-83168/7 4.0 1.826778 4.0 1464940.0 0.456694 Y
9 IC 140-83168/5 8.0 3.387354 4.0 1482931.0 0.423419 Y
10 IC 140-83168/3 16.0 6.568792 4.0 1426322.0 0.410549 Y
RelResp = [0.4732]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 737 of 864
Calibration / 2-Methylnaphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4946
Error Coefficients
Relative Standard Deviation:8.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.020001 0.02607 4.0 1420462.0 1.303455 N
2 IC 140-83168/10 0.040002 0.034144 4.0 1386594.0 0.85356 N
3 IC 140-83168/11 0.080004 0.056564 4.0 1365261.0 0.707009 N
4 IC 140-83168/12 0.160008 0.068452 4.0 1336701.0 0.427804 N
5 IC 140-83168/13 0.40002 0.172699 4.0 1362070.0 0.431726 Y
6 IC 140-83168/14 1.00005 0.530269 4.0 1368090.0 0.530243 Y
7 ICIS 140-83168/15 2.0001 0.920692 4.0 1361919.0 0.460323 Y
8 IC 140-83168/7 4.000199 2.067689 4.0 1464940.0 0.516896 Y
9 IC 140-83168/5 8.000399 3.972387 4.0 1482931.0 0.496524 Y
10 IC 140-83168/3 16.000797 8.509495 4.0 1426322.0 0.531817 Y
RelResp = [0.4946]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
IC 140-83168/3
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9:50:51 AM
Page 738 of 864
Calibration / 1-Methylnaphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5473
Error Coefficients
Relative Standard Deviation:8.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 140-83168/9 0.020001 0.033355 4.0 1420462.0 1.667684 N
2 IC 140-83168/10 0.040002 0.047287 4.0 1386594.0 1.182118 N
3 IC 140-83168/11 0.080004 0.074564 4.0 1365261.0 0.93201 N
4 IC 140-83168/12 0.160008 0.100139 4.0 1336701.0 0.625838 N
5 IC 140-83168/13 0.40002 0.222411 4.0 1362070.0 0.556001 Y
6 IC 140-83168/14 1.00005 0.634619 4.0 1368090.0 0.634587 Y
7 ICIS 140-83168/15 2.0001 1.028957 4.0 1361919.0 0.514453 Y
8 IC 140-83168/7 4.000199 2.186331 4.0 1464940.0 0.546556 Y
9 IC 140-83168/5 8.000399 4.033965 4.0 1482931.0 0.504221 Y
10 IC 140-83168/3 16.000797 8.443942 4.0 1426322.0 0.52772 Y
RelResp = [0.5473]x
Concentration
0 10 20
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
)
IC 140-83168/9
IC 140-83168/10
IC 140-83168/11
IC 140-83168/12
IC 140-83168/13
IC 140-83168/14
ICIS 140-83168/15
IC 140-83168/7
IC 140-83168/5
3/25/2024
9:50:51 AM
Page 739 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/06/2024 02:20
03/05/2024 15:18
03/06/2024 00:47
ICV 140-84237/17
RTX-5
Lab File ID:RZC05LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Chlorodifluoromethane 1.6391.639 1.60 1.60 0.0 35.0Ave
Propene 0.71930.7355 1.56 1.60 -2.2 35.0Ave
Dichlorodifluoromethane 2.8462.642 1.72 1.60 7.7 35.0Ave
Chloromethane 0.28630.2971 1.54 1.60 -3.6 35.0Ave
1,2-Dichloro-1,1,2,2-tetrafl
uoroethane 2.0472.044 1.60 1.60 0.2 35.0Ave
Acetaldehyde 0.37210.4467 6.66 8.00 -16.7 35.0Ave
Vinyl chloride 1.0881.083 1.61 1.60 0.5 35.0Ave
1,3-Butadiene 0.78630.7886 1.60 1.60 -0.3 35.0Ave
Butane 1.5591.540 1.62 1.60 1.2 35.0Ave
Bromomethane 1.0621.084 1.57 1.60 -2.0 35.0Ave
Chloroethane 0.57850.5689 1.63 1.60 1.7 35.0Ave
Ethanol 0.34850.4687 5.95 8.00 -25.6 35.0Ave
Vinyl bromide 1.1211.094 1.64 1.60 2.5 35.0Ave
2-Methylbutane 1.0901.107 1.58 1.60 -1.5 35.0Ave
Trichlorofluoromethane 2.8202.853 1.58 1.60 -1.1 35.0Ave
Acrolein 0.33100.2948 1.80 1.60 12.3 35.0Ave
Acetonitrile 0.38450.3944 1.56 1.60 -2.5 35.0Ave
Acetone 0.55360.5253 1.69 1.60 5.4 35.0Ave
Pentane 0.20650.1962 1.68 1.60 5.3 35.0Ave
Isopropyl alcohol 1.4901.275 1.87 1.60 16.9 35.0Ave
Ethyl ether 1.0260.995 1.65 1.60 3.1 35.0Ave
1,1-Dichloroethene 1.1091.119 1.59 1.60 -0.9 35.0Ave
Acrylonitrile 0.72600.6794 1.71 1.60 6.9 35.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 2.4832.456 1.62 1.60 1.1 35.0Ave
tert-Butyl alcohol 1.9021.930 1.58 1.60 -1.4 35.0Ave
Methylene Chloride 1.1491.210 1.52 1.60 -5.0 35.0Ave
3-Chloropropene 1.0161.069 1.52 1.60 -4.9 35.0Ave
Carbon disulfide 3.2553.303 1.58 1.60 -1.5 35.0Ave
trans-1,2-Dichloroethene 1.1441.168 1.57 1.60 -2.1 35.0Ave
2-Methylpentane 1.9502.117 1.47 1.60 -7.9 35.0Ave
Methyl tert-butyl ether 3.1303.075 1.63 1.60 1.8 35.0Ave
1,1-Dichloroethane 2.0262.007 1.61 1.60 0.9 35.0Ave
Vinyl acetate 2.3482.124 1.77 1.60 10.5 35.0Ave
n-Hexane 0.84020.8267 1.63 1.60 1.6 35.0Ave
2-Butanone (MEK)0.53460.5317 1.61 1.60 0.5 35.0Ave
Isopropyl ether 3.4643.268 1.70 1.60 6.0 35.0Ave
cis-1,2-Dichloroethene 1.2691.231 1.65 1.60 3.1 35.0Ave
Ethyl acetate 2.1652.259 1.53 1.60 -4.2 35.0Ave
Chloroform 2.5512.583 1.58 1.60 -1.2 35.0Ave
Tert-butyl ethyl ether 3.3653.471 1.55 1.60 -3.1 35.0Ave
FORM VII TO-15
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9:50:51 AM
Page 740 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/06/2024 02:20
03/05/2024 15:18
03/06/2024 00:47
ICV 140-84237/17
RTX-5
Lab File ID:RZC05LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Tetrahydrofuran 1.0901.099 1.59 1.60 -0.8 35.0Ave
1,1,1-Trichloroethane 2.5022.528 1.58 1.60 -1.0 35.0Ave
1,2-Dichloroethane 0.35520.3469 1.64 1.60 2.4 35.0Ave
Cyclohexane 0.11820.1148 1.65 1.60 2.9 35.0Ave
Benzene 0.78360.7629 1.64 1.60 2.7 35.0Ave
1-Butanol 0.0832 1.51 1.60 -5.6 35.0Lin2
Carbon tetrachloride 0.5648 1.52 1.60 -4.9 35.0QuaF
2,3-Dimethylpentane 0.17060.1679 1.63 1.60 1.6 35.0Ave
Thiophene 0.43290.4320 1.60 1.60 0.2 35.0Ave
2,2,4-Trimethylpentane 1.1461.145 1.60 1.60 0.1 35.0Ave
n-Heptane 0.26110.2534 1.65 1.60 3.0 35.0Ave
1,2-Dichloropropane 0.28230.2790 1.62 1.60 1.2 35.0Ave
Trichloroethene 0.37170.3617 1.64 1.60 2.8 35.0Ave
Dibromomethane 0.33190.3314 1.60 1.60 0.2 35.0Ave
Bromodichloromethane 0.57600.5632 1.64 1.60 2.3 35.0Ave
1,4-Dioxane 0.10530.1107 1.52 1.60 -4.9 35.0Ave
Methyl methacrylate 0.27660.2911 1.52 1.60 -5.0 35.0Ave
Methylcyclohexane 0.56210.4540 1.98 1.60 23.8 35.0Ave
4-Methyl-2-pentanone (MIBK)0.51660.5270 1.57 1.60 -2.0 35.0Ave
cis-1,3-Dichloropropene 0.45330.4336 1.67 1.60 4.5 35.0Ave
trans-1,3-Dichloropropene 0.46760.4410 1.70 1.60 6.0 35.0Ave
Toluene 1.1351.096 1.66 1.60 3.5 35.0Ave
1,1,2-Trichloroethane 0.32950.3230 1.63 1.60 2.0 35.0Ave
2-Hexanone 0.31800.3131 1.63 1.60 1.6 35.0Ave
Octane 0.35130.3317 1.69 1.60 5.9 35.0Ave
Dibromochloromethane 0.69260.6318 1.75 1.60 9.6 35.0Ave
1,2-Dibromoethane (EDB)0.61390.5823 1.69 1.60 5.4 35.0Ave
Tetrachloroethene 0.40650.3940 1.65 1.60 3.2 35.0Ave
2,3-Dimethylheptane 0.77540.8789 1.41 1.60 -11.8 35.0Ave
Chlorobenzene 0.90630.8810 1.65 1.60 2.9 35.0Ave
Ethylbenzene 1.4581.413 1.65 1.60 3.2 35.0Ave
m-Xylene & p-Xylene 1.1661.105 3.38 3.20 5.5 35.0Ave
Nonane 0.62180.6086 1.63 1.60 2.2 35.0Ave
Styrene 0.82900.7698 1.72 1.60 7.7 35.0Ave
Bromoform 0.66950.5537 1.93 1.60 20.9 35.0Ave
o-Xylene 1.1911.152 1.65 1.60 3.4 35.0Ave
1,1,2,2-Tetrachloroethane 0.86430.8592 1.61 1.60 0.6 35.0Ave
1,2,3-Trichloropropane 0.25710.2478 1.66 1.60 3.8 35.0Ave
Isopropylbenzene 1.6681.551 1.72 1.60 7.5 35.0Ave
Propylbenzene 0.47010.4351 1.73 1.60 8.0 35.0Ave
2-Chlorotoluene 0.43050.3906 1.76 1.60 10.2 35.0Ave
FORM VII TO-15
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9:50:51 AM
Page 741 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/06/2024 02:20
03/05/2024 15:18
03/06/2024 00:47
ICV 140-84237/17
RTX-5
Lab File ID:RZC05LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
4-Ethyltoluene 1.6191.587 1.63 1.60 2.0 35.0Ave
1,3,5-Trimethylbenzene 0.77930.6604 1.89 1.60 18.0 35.0Ave
Alpha Methyl Styrene 0.67380.6517 1.65 1.60 3.4 35.0Ave
Decane 0.85900.8356 1.64 1.60 2.8 35.0Ave
tert-Butylbenzene 1.5421.429 1.73 1.60 7.9 35.0Ave
1,2,4-Trimethylbenzene 1.4681.366 1.72 1.60 7.5 35.0Ave
sec-Butylbenzene 2.1111.965 1.72 1.60 7.5 35.0Ave
1,3-Dichlorobenzene 0.9970.9543 1.67 1.60 4.5 35.0Ave
Benzyl chloride 1.1431.109 1.65 1.60 3.0 35.0Ave
1,4-Dichlorobenzene 0.9950.9562 1.66 1.60 4.1 35.0Ave
4-Isopropyltoluene 1.7811.667 1.71 1.60 6.8 35.0Ave
1,2,3-Trimethylbenzene 1.1021.386 1.27 1.60 -20.5 35.0Ave
Butylcyclohexane 1.1121.096 1.62 1.60 1.4 35.0Ave
Indane 1.3991.323 1.69 1.60 5.7 35.0Ave
1,2-Dichlorobenzene 0.97420.9271 1.68 1.60 5.1 35.0Ave
Butylbenzene 1.7891.689 1.69 1.60 5.9 35.0Ave
Indene 1.0391.079 1.54 1.60 -3.7 35.0Ave
Undecane 1.0070.9846 1.64 1.60 2.3 35.0Ave
1,2-Dibromo-3-Chloropropane 0.43400.4625 1.50 1.60 -6.2 35.0Ave
1,2,4,5-Tetramethylbenzene 1.6351.699 1.54 1.60 -3.8 35.0Ave
Dodecane 1.0861.175 1.48 1.60 -7.5 35.0Ave
1,2,4-Trichlorobenzene 0.84120.8755 1.54 1.60 -3.9 35.0Ave
Naphthalene 1.9591.963 1.60 1.60 -0.2 35.0Ave
Hexachlorobutadiene 0.6590 1.46 1.60 -8.6 35.0QuaF
1,2,3-Trichlorobenzene 0.74040.6904 1.72 1.60 7.2 35.0Ave
2-Methylnaphthalene 1.0581.100 1.54 1.60 -3.8 50.0Ave
1-Methylnaphthalene 1.1761.159 1.62 1.60 1.5 50.0Ave
4-Bromofluorobenzene (Surr)0.74360.7311 4.15 4.08 1.7 35.0Ave
FORM VII TO-15
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9:50:51 AM
Page 742 of 864
Report Date: 06-Mar-2024 12:42:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05LCS.D
Lims ID:ICV
Client ID:
Sample Type:ICV
Inject. Date:06-Mar-2024 02:20:30 ALS Bottle#:13 Worklist Smp#:17
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031853-017
Misc. Info.:662934 80mL s253
Operator ID:Instrument ID:MR
Sublist:chrom-MS_TO15A*sub1
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:06-Mar-2024 12:42:40 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1677
First Level Reviewer: U3SA Date:06-Mar-2024 12:42:40
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.364 0.005 95 211954 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.553 0.005 94 983393 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.427 16.422 0.005 87 888941 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.072 0.000 90 674231 4.08 4.15
6 Chlorodifluoromethane 51 3.788 3.782 0.006 97 144785 1.60 1.60
7 Propene 41 3.793 3.793 0.000 97 63526 1.60 1.56
8 Dichlorodifluoromethane 85 3.852 3.847 0.005 100 251302 1.60 1.72
9 Chloromethane 52 4.057 4.052 0.005 97 25286 1.60 1.54
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.068 4.063 0.005 94 180747 1.60 1.60
11 Acetaldehyde 44 4.246 4.246 0.000 100 164310 8.00 6.66
12 Vinyl chloride 62 4.251 4.246 0.005 98 96119 1.60 1.61
13 Butane 43 4.349 4.343 0.006 84 137698 1.60 1.62
14 Butadiene 54 4.349 4.343 0.006 69 69442 1.60 1.60
15 Bromomethane 94 4.710 4.705 0.005 99 93785 1.60 1.57
16 Chloroethane 64 4.872 4.866 0.006 98 51091 1.60 1.63
17 Ethanol 31 5.023 5.023 0.000 94 153875 8.00 5.95
18 Vinyl bromide 106 5.206 5.201 0.005 98 99003 1.60 1.64
19 2-Methylbutane 43 5.260 5.255 0.005 90 96248 1.60 1.58
20 Trichlorofluoromethane 101 5.503 5.497 0.005 99 249089 1.60 1.58
21 Acrolein 56 5.546 5.540 0.006 94 29235 1.60 1.80
22 Acetonitrile 40 5.616 5.616 0.000 98 33961 1.60 1.56
23 Acetone 58 5.680 5.670 0.010 97 48893 1.60 1.69
25 Pentane 72 5.745 5.734 0.011 97 18241 1.60 1.68
24 Isopropyl alcohol 45 5.804 5.799 0.005 96 131587 1.60 1.87
26 Ethyl ether 31 5.955 5.950 0.005 93 90572 1.60 1.65
27 1,1-Dichloroethene 96 6.279 6.274 0.005 100 97944 1.60 1.59
29 Acrylonitrile 53 6.419 6.414 0.005 94 64119 1.60 1.71
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.468 6.462 0.006 95 219257 1.60 1.62
28 2-Methyl-2-propanol 59 6.468 6.484 -0.016 95 167942 1.60 1.58
31 Methylene Chloride 84 6.667 6.662 0.005 90 101516 1.60 1.52
3/25/2024
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Report Date: 06-Mar-2024 12:42:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05LCS.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.683 6.673 0.010 96 89722 1.60 1.52
33 Carbon disulfide 76 6.834 6.829 0.005 99 287467 1.60 1.58
34 trans-1,2-Dichloroethene 96 7.530 7.525 0.005 99 100996 1.60 1.57
35 2-Methylpentane 43 7.541 7.536 0.005 91 172176 1.60 1.47
36 Methyl tert-butyl ether 73 7.676 7.681 -0.005 96 276455 1.60 1.63
37 1,1-Dichloroethane 63 7.983 7.978 0.005 100 178940 1.60 1.61
38 Vinyl acetate 43 8.096 8.096 0.000 99 207358 1.60 1.77
40 Hexane 56 8.576 8.571 0.005 80 74198 1.60 1.63
39 2-Butanone (MEK) 72 8.582 8.582 0.000 96 47214 1.60 1.61
41 Isopropyl ether 45 8.749 8.754 -0.005 94 305948 1.60 1.70
42 cis-1,2-Dichloroethene 96 9.018 9.018 0.000 92 112062 1.60 1.65
43 Ethyl acetate 43 9.218 9.218 0.000 99 191184 1.60 1.53
44 Chloroform 83 9.380 9.374 0.006 96 225325 1.60 1.58
45 Tert-butyl ethyl ether 59 9.461 9.466 -0.006 95 297136 1.60 1.55
46 Tetrahydrofuran 42 9.816 9.822 -0.006 88 96305 1.60 1.59
47 1,1,1-Trichloroethane 97 10.437 10.426 0.011 96 220932 1.60 1.58
48 1,2-Dichloroethane 62 10.555 10.550 0.005 98 145554 1.60 1.64
50 Cyclohexane 69 11.019 11.014 0.005 94 48426 1.60 1.65
51 Benzene 78 11.024 11.024 0.000 96 321085 1.60 1.64
52 Carbon tetrachloride 117 11.046 11.041 0.005 96 231444 1.60 1.52
49 n-Butanol 31 11.035 11.051 -0.016 68 34095 1.60 1.51
53 2,3-Dimethylpentane 71 11.127 11.116 0.011 90 69897 1.60 1.63
54 Thiophene 84 11.305 11.299 0.006 94 177368 1.60 1.60
55 Isooctane 57 11.758 11.752 0.006 98 469714 1.60 1.60
56 n-Heptane 71 12.124 12.119 0.005 88 106998 1.60 1.65
57 1,2-Dichloropropane 63 12.238 12.232 0.006 89 115660 1.60 1.62
58 Trichloroethene 130 12.265 12.265 0.000 97 152293 1.60 1.64
59 Dibromomethane 93 12.367 12.362 0.005 96 135999 1.60 1.60
60 Dichlorobromomethane 83 12.502 12.502 0.000 98 236032 1.60 1.64
61 1,4-Dioxane 88 12.540 12.545 -0.005 91 43156 1.60 1.52
62 Methyl methacrylate 41 12.588 12.588 0.000 96 113328 1.60 1.52
63 Methylcyclohexane 83 13.052 13.047 0.005 95 230334 1.60 1.98
64 4-Methyl-2-pentanone (MIBK) 43 13.489 13.494 -0.005 96 211672 1.60 1.57
65 cis-1,3-Dichloropropene 75 13.543 13.543 0.000 93 185742 1.60 1.67
66 trans-1,3-Dichloropropene 75 14.265 14.265 0.000 98 166273 1.60 1.70
67 Toluene 91 14.395 14.389 0.006 93 403620 1.60 1.66
68 1,1,2-Trichloroethane 83 14.475 14.476 -0.001 97 117159 1.60 1.63
69 2-Hexanone 58 14.874 14.880 -0.006 95 113086 1.60 1.63
70 n-Octane 85 15.074 15.074 0.000 88 124897 1.60 1.69
71 Chlorodibromomethane 129 15.209 15.209 0.000 98 246266 1.60 1.75
72 Ethylene Dibromide 107 15.511 15.511 0.000 99 218296 1.60 1.69
73 Tetrachloroethene 129 15.575 15.570 0.005 97 144527 1.60 1.65
75 2,3-Dimethylheptane 43 16.460 16.455 0.006 90 275714 1.60 1.41
74 Chlorobenzene 112 16.476 16.476 0.000 95 322243 1.60 1.65
76 Ethylbenzene 91 16.756 16.756 0.000 98 518591 1.60 1.65
77 m-Xylene & p-Xylene 91 16.918 16.918 0.000 98 829452 3.20 3.38
78 n-Nonane 57 17.317 17.312 0.005 85 221090 1.60 1.63
80 Styrene 104 17.398 17.398 0.000 99 294760 1.60 1.72
79 Bromoform 173 17.403 17.404 -0.001 96 238073 1.60 1.93
81 o-Xylene 91 17.457 17.457 0.000 98 423525 1.60 1.65
82 1,1,2,2-Tetrachloroethane 83 17.786 17.786 0.000 99 307307 1.60 1.61
83 1,2,3-Trichloropropane 110 17.943 17.943 0.000 97 91436 1.60 1.66
3/25/2024
9:50:51 AM
Page 744 of 864
Report Date: 06-Mar-2024 12:42:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05LCS.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.029 18.029 0.000 96 593000 1.60 1.72
85 N-Propylbenzene 120 18.547 18.547 0.000 99 167153 1.60 1.73
86 2-Chlorotoluene 126 18.601 18.595 0.006 97 153077 1.60 1.76
88 4-Ethyltoluene 105 18.687 18.687 0.000 99 575651 1.60 1.63
87 1,3,5-Trimethylbenzene 120 18.757 18.757 0.000 92 277110 1.60 1.89
89 Alpha Methyl Styrene 118 18.983 18.978 0.005 87 239592 1.60 1.65
90 n-Decane 57 19.005 19.005 0.000 94 305443 1.60 1.64
91 tert-Butylbenzene 119 19.167 19.167 0.000 91 548264 1.60 1.73
92 1,2,4-Trimethylbenzene 105 19.183 19.178 0.005 96 521907 1.60 1.72
93 sec-Butylbenzene 105 19.426 19.426 0.000 99 750695 1.60 1.72
94 1,3-Dichlorobenzene 146 19.458 19.453 0.005 98 354659 1.60 1.67
95 Benzyl chloride 91 19.528 19.528 0.000 98 406268 1.60 1.65
96 1,4-Dichlorobenzene 146 19.539 19.539 0.000 94 353817 1.60 1.66
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 633262 1.60 1.71
98 1,2,3-Trimethylbenzene 105 19.641 19.641 0.000 98 391718 1.60 1.27
99 Butylcyclohexane 83 19.679 19.679 0.000 95 395224 1.60 1.62
100 2,3-Dihydroindene 117 19.889 19.884 0.005 95 497371 1.60 1.69
101 1,2-Dichlorobenzene 146 19.895 19.889 0.006 97 346386 1.60 1.68
103 n-Butylbenzene 91 20.003 20.003 0.000 98 636227 1.60 1.69
102 Indene 116 20.019 20.013 0.006 89 369447 1.60 1.54
104 Undecane 57 20.283 20.278 0.005 93 358094 1.60 1.64
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.488 0.000 97 154308 1.60 1.50
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.763 0.000 97 581241 1.60 1.54
107 Dodecane 57 21.378 21.378 0.000 94 386321 1.60 1.48
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 299114 1.60 1.54
109 Naphthalene 128 21.744 21.744 0.000 99 696575 1.60 1.60
110 Hexachlorobutadiene 225 21.890 21.890 0.000 94 234337 1.60 1.46
111 1,2,3-Trichlorobenzene 180 21.949 21.949 0.000 94 263255 1.60 1.72
112 2-Methylnaphthalene 142 22.488 22.489 -0.001 99 376381 1.60 1.54
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 418286 1.60 1.62
A 116 C8 Range 1 15.085 (15.026-15.133) 0 1027727 1.60 1.57
S 117 Xylenes, Total 100 0 4.80 5.03
S 118 1,2-Dichloroethene, Total 1 0 3.20 3.22
T 143 2-Methylthiophene TIC 97 14.556 14.556 0.000 97 316550 1.60 1.42
T 144 3-Methylthiophene TIC 97 14.761 14.767 -0.006 99 309158 1.60 1.39
T 146 2-Ethylthiophene TIC 97 16.864 16.864 0.000 97 379738 1.60 1.71
T 153 1,2-Dimethyl-4-Ethylbenzene TIC 119 20.369 20.364 0.005 98 476732 1.60 2.15
T 156 1,2,3,5-Tetramethylbenzene TIC 119 20.822 20.822 0.005 95 345066 1.60 1.55 a
T 155 1,2,3,4-Tetramethylbenzene TIC 119 21.248 21.247 0.000 97 464633 1.60 2.09 a
T 157 Benzo(b)thiophene TIC 134 21.825 21.825 0.000 99 374460 1.60 1.68
QC Flag Legend
Processing Flags
Review Flags
a - User Assigned ID
Reagents:
40CV101S_00253 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 745 of 864
Report Date: 06-Mar-2024 12:42:41 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05LCS.D
Injection Date:06-Mar-2024 02:20:30 Instrument ID:MR Operator ID:
Lims ID:ICV Worklist Smp#:17
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:13
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
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RZC05LCS[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 746 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/19/2024 07:40
03/05/2024 15:18
03/06/2024 00:47
CCVIS 140-84584/2
RTX-5
Lab File ID:RCCVZC19.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Chlorodifluoromethane 1.6531.639 1.61 1.60 0.9 30.0Ave
Propene 0.71280.7355 1.55 1.60 -3.1 30.0Ave
Dichlorodifluoromethane 2.3352.642 1.41 1.60 -11.6 30.0Ave
Chloromethane 0.28600.2971 1.54 1.60 -3.7 30.0Ave
1,2-Dichloro-1,1,2,2-tetrafl
uoroethane 1.8892.044 1.48 1.60 -7.6 30.0Ave
Acetaldehyde 0.38990.4467 6.98 8.00 -12.7 30.0Ave
Vinyl chloride 1.1111.083 1.64 1.60 2.7 30.0Ave
Butane 1.4711.540 1.53 1.60 -4.5 30.0Ave
1,3-Butadiene 0.77230.7886 1.57 1.60 -2.1 30.0Ave
Bromomethane 0.95531.084 1.41 1.60 -11.9 30.0Ave
Chloroethane 0.51480.5689 1.45 1.60 -9.5 30.0Ave
Ethanol 0.32080.4687 5.48 8.00 -31.6 *30.0Ave
Vinyl bromide 1.2141.094 1.78 1.60 11.0 30.0Ave
2-Methylbutane 1.2981.107 1.88 1.60 17.3 30.0Ave
Trichlorofluoromethane 3.2502.853 1.82 1.60 13.9 30.0Ave
Acrolein 0.37940.2948 2.06 1.60 28.7 30.0Ave
Acetonitrile 0.44900.3944 1.82 1.60 13.8 30.0Ave
Pentane 0.24270.1962 1.98 1.60 23.7 30.0Ave
Ethyl ether 1.0720.995 1.72 1.60 7.8 30.0Ave
1,1-Dichloroethene 1.1591.119 1.66 1.60 3.6 30.0Ave
Acrylonitrile 0.76960.6794 1.81 1.60 13.3 30.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 2.5442.456 1.66 1.60 3.6 30.0Ave
tert-Butyl alcohol 2.0381.930 1.69 1.60 5.6 30.0Ave
Methylene Chloride 1.1491.210 1.52 1.60 -5.0 30.0Ave
3-Chloropropene 1.0331.069 1.55 1.60 -3.4 30.0Ave
Carbon disulfide 3.1463.303 1.52 1.60 -4.8 30.0Ave
trans-1,2-Dichloroethene 1.1021.168 1.51 1.60 -5.7 30.0Ave
2-Methylpentane 1.9882.117 1.50 1.60 -6.1 30.0Ave
Methyl tert-butyl ether 3.0553.075 1.59 1.60 -0.6 30.0Ave
1,1-Dichloroethane 1.9962.007 1.59 1.60 -0.6 30.0Ave
Vinyl acetate 2.0262.124 1.53 1.60 -4.7 30.0Ave
n-Hexane 0.89200.8267 1.73 1.60 7.9 30.0Ave
2-Butanone (MEK)0.55200.5317 1.66 1.60 3.8 30.0Ave
Isopropyl ether 3.6743.268 1.80 1.60 12.4 30.0Ave
cis-1,2-Dichloroethene 1.2611.231 1.64 1.60 2.4 30.0Ave
Ethyl acetate 2.2612.259 1.60 1.60 0.0 30.0Ave
Chloroform 2.6442.583 1.64 1.60 2.3 30.0Ave
Tert-butyl ethyl ether 3.5493.471 1.64 1.60 2.2 30.0Ave
Tetrahydrofuran 1.1051.099 1.61 1.60 0.6 30.0Ave
1,1,1-Trichloroethane 2.3942.528 1.52 1.60 -5.3 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 747 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/19/2024 07:40
03/05/2024 15:18
03/06/2024 00:47
CCVIS 140-84584/2
RTX-5
Lab File ID:RCCVZC19.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,2-Dichloroethane 0.37190.3469 1.72 1.60 7.2 30.0Ave
Cyclohexane 0.11900.1148 1.66 1.60 3.6 30.0Ave
Benzene 0.78730.7629 1.65 1.60 3.2 30.0Ave
1-Butanol 0.0807 1.47 1.60 -8.2 30.0Lin2
Carbon tetrachloride 0.5535 1.49 1.60 -6.9 30.0QuaF
2,3-Dimethylpentane 0.17070.1679 1.63 1.60 1.7 30.0Ave
Thiophene 0.43530.4320 1.61 1.60 0.8 30.0Ave
2,2,4-Trimethylpentane 1.1851.145 1.66 1.60 3.5 30.0Ave
n-Heptane 0.26180.2534 1.65 1.60 3.3 30.0Ave
1,2-Dichloropropane 0.28550.2790 1.64 1.60 2.3 30.0Ave
Trichloroethene 0.38500.3617 1.70 1.60 6.4 30.0Ave
Dibromomethane 0.35010.3314 1.69 1.60 5.6 30.0Ave
Bromodichloromethane 0.62920.5632 1.79 1.60 11.7 30.0Ave
1,4-Dioxane 0.11170.1107 1.61 1.60 0.9 30.0Ave
Methyl methacrylate 0.32250.2911 1.77 1.60 10.8 30.0Ave
Methylcyclohexane 0.60320.4540 2.13 1.60 32.9 *30.0Ave
4-Methyl-2-pentanone (MIBK)0.59360.5270 1.80 1.60 12.7 30.0Ave
cis-1,3-Dichloropropene 0.49890.4336 1.84 1.60 15.1 30.0Ave
trans-1,3-Dichloropropene 0.47630.4410 1.73 1.60 8.0 30.0Ave
Toluene 1.1321.096 1.65 1.60 3.3 30.0Ave
1,1,2-Trichloroethane 0.33330.3230 1.65 1.60 3.2 30.0Ave
2-Hexanone 0.33360.3131 1.71 1.60 6.6 30.0Ave
Octane 0.35580.3317 1.72 1.60 7.3 30.0Ave
Dibromochloromethane 0.67140.6318 1.70 1.60 6.3 30.0Ave
1,2-Dibromoethane (EDB)0.59500.5823 1.64 1.60 2.2 30.0Ave
Tetrachloroethene 0.39690.3940 1.61 1.60 0.7 30.0Ave
2,3-Dimethylheptane 0.85650.8789 1.56 1.60 -2.5 30.0Ave
Chlorobenzene 0.91230.8810 1.66 1.60 3.6 30.0Ave
Ethylbenzene 1.4741.413 1.67 1.60 4.3 30.0Ave
m-Xylene & p-Xylene 1.1981.105 3.47 3.20 8.4 30.0Ave
Nonane 0.68670.6086 1.81 1.60 12.8 30.0Ave
Styrene 0.83620.7698 1.74 1.60 8.6 30.0Ave
Bromoform 0.63240.5537 1.83 1.60 14.2 30.0Ave
o-Xylene 1.2421.152 1.72 1.60 7.8 30.0Ave
1,1,2,2-Tetrachloroethane 0.86990.8592 1.62 1.60 1.2 30.0Ave
1,2,3-Trichloropropane 0.26380.2478 1.70 1.60 6.4 30.0Ave
Isopropylbenzene 1.7101.551 1.76 1.60 10.2 30.0Ave
Propylbenzene 0.45500.4351 1.67 1.60 4.6 30.0Ave
2-Chlorotoluene 0.41750.3906 1.71 1.60 6.9 30.0Ave
4-Ethyltoluene 1.5071.587 1.52 1.60 -5.1 30.0Ave
1,3,5-Trimethylbenzene 0.71850.6604 1.74 1.60 8.8 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 748 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/19/2024 07:40
03/05/2024 15:18
03/06/2024 00:47
CCVIS 140-84584/2
RTX-5
Lab File ID:RCCVZC19.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Alpha Methyl Styrene 0.59170.6517 1.45 1.60 -9.2 30.0Ave
Decane 0.86650.8356 1.66 1.60 3.7 30.0Ave
tert-Butylbenzene 1.4131.429 1.58 1.60 -1.1 30.0Ave
1,2,4-Trimethylbenzene 1.3641.366 1.60 1.60 -0.1 30.0Ave
sec-Butylbenzene 1.9491.965 1.59 1.60 -0.8 30.0Ave
1,3-Dichlorobenzene 0.90710.9543 1.52 1.60 -4.9 30.0Ave
Benzyl chloride 1.0771.109 1.55 1.60 -2.9 30.0Ave
1,4-Dichlorobenzene 0.90520.9562 1.51 1.60 -5.3 30.0Ave
4-Isopropyltoluene 1.6341.667 1.57 1.60 -2.0 30.0Ave
1,2,3-Trimethylbenzene 1.0221.386 1.18 1.60 -26.2 30.0Ave
Butylcyclohexane 1.0521.096 1.54 1.60 -4.0 30.0Ave
Indane 1.2821.323 1.55 1.60 -3.1 30.0Ave
1,2-Dichlorobenzene 0.89000.9271 1.54 1.60 -4.0 30.0Ave
Butylbenzene 1.6821.689 1.59 1.60 -0.4 30.0Ave
Indene 0.92271.079 1.37 1.60 -14.5 30.0Ave
Undecane 0.99230.9846 1.61 1.60 0.8 30.0Ave
1,2-Dibromo-3-Chloropropane 0.39340.4625 1.36 1.60 -14.9 30.0Ave
1,2,4,5-Tetramethylbenzene 1.4791.699 1.39 1.60 -12.9 30.0Ave
Dodecane 1.0281.175 1.40 1.60 -12.5 30.0Ave
1,2,4-Trichlorobenzene 0.72580.8755 1.33 1.60 -17.1 30.0Ave
Naphthalene 1.7191.963 1.40 1.60 -12.4 30.0Ave
Hexachlorobutadiene 0.5846 1.27 1.60 -20.3 30.0QuaF
1,2,3-Trichlorobenzene 0.63220.6904 1.47 1.60 -8.4 30.0Ave
2-Methylnaphthalene 0.73701.100 1.07 1.60 -33.0 50.0Ave
1-Methylnaphthalene 0.84111.159 1.16 1.60 -27.4 50.0Ave
4-Bromofluorobenzene (Surr)0.79660.7311 4.45 4.08 9.0 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 749 of 864
Report Date: 20-Mar-2024 14:48:51 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RCCVZC19.D
Lims ID:CCVIS
Client ID:
Sample Type:CCVIS
Inject. Date:19-Mar-2024 07:40:30 ALS Bottle#:9 Worklist Smp#:2
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031988-002
Misc. Info.:S253 80 ML 662934
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub19
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 14:48:51 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 14:48:51
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.364 9.364 0.000 90 223690 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.553 11.553 0.000 95 990806 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.433 16.433 0.000 87 960495 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.072 0.000 87 780430 4.08 4.45
6 Chlorodifluoromethane 51 3.788 3.788 0.000 97 154044 1.60 1.61
7 Propene 41 3.799 3.799 0.000 98 66432 1.60 1.55
8 Dichlorodifluoromethane 85 3.858 3.858 0.000 100 217659 1.60 1.41
9 Chloromethane 52 4.063 4.063 0.000 98 26659 1.60 1.54
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.068 4.068 0.000 95 176039 1.60 1.48
12 Vinyl chloride 62 4.252 4.252 0.000 99 103594 1.60 1.64
11 Acetaldehyde 44 4.252 4.252 0.000 99 181722 8.00 6.98
13 Butane 43 4.349 4.349 0.000 84 137067 1.60 1.53
14 Butadiene 54 4.354 4.354 0.000 69 71982 1.60 1.57
15 Bromomethane 94 4.715 4.715 0.000 99 89039 1.60 1.41
16 Chloroethane 64 4.872 4.872 0.000 91 47980 1.60 1.45
17 Ethanol 31 5.023 5.023 0.000 87 149479 8.00 5.48
18 Vinyl bromide 106 5.211 5.211 0.000 98 113120 1.60 1.78
19 2-Methylbutane 43 5.260 5.260 0.000 89 120980 1.60 1.88
20 Trichlorofluoromethane 101 5.503 5.503 0.000 99 302899 1.60 1.82
21 Acrolein 56 5.546 5.546 0.000 89 35363 1.60 2.06
22 Acetonitrile 40 5.621 5.621 0.000 100 41849 1.60 1.82
23 Acetone 58 5.681 5.681 0.000 96 71307 1.60 2.33
25 Pentane 72 5.745 5.745 0.000 99 22625 1.60 1.98
24 Isopropyl alcohol 45 5.810 5.810 0.000 98 161933 1.60 2.18
26 Ethyl ether 31 5.956 5.956 0.000 90 99946 1.60 1.72
27 1,1-Dichloroethene 96 6.279 6.279 0.000 98 108070 1.60 1.66
29 Acrylonitrile 53 6.419 6.419 0.000 95 71727 1.60 1.81
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.468 6.468 0.000 95 237074 1.60 1.66
28 2-Methyl-2-propanol 59 6.479 6.479 0.000 95 189936 1.60 1.69
31 Methylene Chloride 84 6.667 6.667 0.000 93 107068 1.60 1.52
3/25/2024
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Page 750 of 864
Report Date: 20-Mar-2024 14:48:51 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RCCVZC19.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.678 6.678 0.000 99 96239 1.60 1.55
33 Carbon disulfide 76 6.835 6.835 0.000 99 293193 1.60 1.52
34 trans-1,2-Dichloroethene 96 7.530 7.530 0.000 99 102665 1.60 1.51
35 2-Methylpentane 43 7.536 7.536 0.000 92 185279 1.60 1.50
36 Methyl tert-butyl ether 73 7.681 7.681 0.000 96 284714 1.60 1.59
37 1,1-Dichloroethane 63 7.983 7.983 0.000 100 186074 1.60 1.59
38 Vinyl acetate 43 8.096 8.096 0.000 99 188786 1.60 1.53
40 Hexane 56 8.571 8.571 0.000 83 83142 1.60 1.73
39 2-Butanone (MEK) 72 8.582 8.582 0.000 97 51447 1.60 1.66
41 Isopropyl ether 45 8.754 8.754 0.000 95 342409 1.60 1.80
42 cis-1,2-Dichloroethene 96 9.018 9.018 0.000 94 117534 1.60 1.64
43 Ethyl acetate 43 9.218 9.218 0.000 99 210692 1.60 1.60
44 Chloroform 83 9.374 9.374 0.000 97 246396 1.60 1.64
45 Tert-butyl ethyl ether 59 9.461 9.461 0.000 95 330750 1.60 1.64
46 Tetrahydrofuran 42 9.817 9.817 0.000 89 102998 1.60 1.61
47 1,1,1-Trichloroethane 97 10.431 10.431 0.000 96 223154 1.60 1.52
48 1,2-Dichloroethane 62 10.550 10.550 0.000 98 153542 1.60 1.72
50 Cyclohexane 69 11.019 11.019 0.000 96 49107 1.60 1.66
51 Benzene 78 11.024 11.024 0.000 97 325015 1.60 1.65
52 Carbon tetrachloride 117 11.046 11.046 0.000 97 228494 1.60 1.49
49 n-Butanol 31 11.041 11.041 0.000 68 33313 1.60 1.47
53 2,3-Dimethylpentane 71 11.121 11.121 0.000 90 70456 1.60 1.63
54 Thiophene 84 11.299 11.299 0.000 96 179722 1.60 1.61
55 Isooctane 57 11.758 11.758 0.000 98 489240 1.60 1.66
56 n-Heptane 71 12.141 12.141 0.000 89 108098 1.60 1.65
57 1,2-Dichloropropane 63 12.254 12.254 0.000 87 117844 1.60 1.64
58 Trichloroethene 130 12.292 12.292 0.000 97 158931 1.60 1.70
59 Dibromomethane 93 12.394 12.394 0.000 97 144537 1.60 1.69
60 Dichlorobromomethane 83 12.540 12.540 0.000 99 259772 1.60 1.79
61 1,4-Dioxane 88 12.572 12.572 0.000 90 46113 1.60 1.61
62 Methyl methacrylate 41 12.621 12.621 0.000 96 133127 1.60 1.77
63 Methylcyclohexane 83 13.084 13.084 0.000 96 249029 1.60 2.13
64 4-Methyl-2-pentanone (MIBK) 43 13.526 13.526 0.000 96 245078 1.60 1.80
65 cis-1,3-Dichloropropene 75 13.575 13.575 0.000 93 205959 1.60 1.84
66 trans-1,3-Dichloropropene 75 14.292 14.292 0.000 98 182982 1.60 1.73
67 Toluene 91 14.416 14.416 0.000 93 435063 1.60 1.65
68 1,1,2-Trichloroethane 83 14.497 14.497 0.000 98 128056 1.60 1.65
69 2-Hexanone 58 14.896 14.896 0.000 95 128170 1.60 1.71
70 n-Octane 85 15.096 15.096 0.000 90 136684 1.60 1.72
71 Chlorodibromomethane 129 15.225 15.225 0.000 98 257942 1.60 1.70
72 Ethylene Dibromide 107 15.532 15.532 0.000 98 228616 1.60 1.64
73 Tetrachloroethene 129 15.586 15.586 0.000 96 152493 1.60 1.61
75 2,3-Dimethylheptane 43 16.465 16.465 0.000 94 329067 1.60 1.56
74 Chlorobenzene 112 16.487 16.487 0.000 94 350509 1.60 1.66
76 Ethylbenzene 91 16.767 16.767 0.000 98 566449 1.60 1.67
77 m-Xylene & p-Xylene 91 16.929 16.929 0.000 98 920489 3.20 3.47
78 n-Nonane 57 17.317 17.317 0.000 88 263810 1.60 1.81
80 Styrene 104 17.404 17.404 0.000 99 321268 1.60 1.74
79 Bromoform 173 17.409 17.409 0.000 96 242950 1.60 1.83
81 o-Xylene 91 17.463 17.463 0.000 98 477001 1.60 1.72
82 1,1,2,2-Tetrachloroethane 83 17.792 17.792 0.000 99 334218 1.60 1.62
83 1,2,3-Trichloropropane 110 17.943 17.943 0.000 98 101334 1.60 1.70
3/25/2024
9:50:51 AM
Page 751 of 864
Report Date: 20-Mar-2024 14:48:51 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RCCVZC19.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.034 18.034 0.000 95 656897 1.60 1.76
85 N-Propylbenzene 120 18.547 18.547 0.000 99 174792 1.60 1.67
86 2-Chlorotoluene 126 18.601 18.601 0.000 97 160409 1.60 1.71
88 4-Ethyltoluene 105 18.687 18.687 0.000 99 578929 1.60 1.52
87 1,3,5-Trimethylbenzene 120 18.757 18.757 0.000 92 276063 1.60 1.74
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 88 227341 1.60 1.45
90 n-Decane 57 19.005 19.005 0.000 93 332913 1.60 1.66
91 tert-Butylbenzene 119 19.167 19.167 0.000 92 543002 1.60 1.58
92 1,2,4-Trimethylbenzene 105 19.183 19.183 0.000 96 523984 1.60 1.60
93 sec-Butylbenzene 105 19.426 19.426 0.000 98 748780 1.60 1.59
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 99 348492 1.60 1.52
95 Benzyl chloride 91 19.528 19.528 0.000 98 413737 1.60 1.55
96 1,4-Dichlorobenzene 146 19.539 19.539 0.000 94 347790 1.60 1.51
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 627671 1.60 1.57
98 1,2,3-Trimethylbenzene 105 19.641 19.641 0.000 98 392746 1.60 1.18
99 Butylcyclohexane 83 19.679 19.679 0.000 95 404220 1.60 1.54
100 2,3-Dihydroindene 117 19.884 19.884 0.000 94 492705 1.60 1.55
101 1,2-Dichlorobenzene 146 19.889 19.889 0.000 96 341925 1.60 1.54
103 n-Butylbenzene 91 20.003 20.003 0.000 98 646106 1.60 1.59
102 Indene 116 20.019 20.019 0.000 89 354502 1.60 1.37
104 Undecane 57 20.278 20.278 0.000 94 381242 1.60 1.61
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.488 0.000 98 151155 1.60 1.36
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.763 0.000 97 568351 1.60 1.39
107 Dodecane 57 21.378 21.378 0.000 96 395069 1.60 1.40
108 1,2,4-Trichlorobenzene 180 21.615 21.615 0.000 94 278845 1.60 1.33
109 Naphthalene 128 21.744 21.744 0.000 99 660592 1.60 1.40
110 Hexachlorobutadiene 225 21.890 21.890 0.000 94 224620 1.60 1.27
111 1,2,3-Trichlorobenzene 180 21.949 21.949 0.000 94 242904 1.60 1.47
112 2-Methylnaphthalene 142 22.483 22.483 0.000 99 283166 1.60 1.07
113 1-Methylnaphthalene 142 22.613 22.613 0.000 99 323163 1.60 1.16
A 116 C8 Range 1 15.098 (15.036-15.144) 0 1155246 1.60 1.75
S 117 Xylenes, Total 100 0 4.80 5.19
S 118 1,2-Dichloroethene, Total 1 0 3.20 3.15
T 143 2-Methylthiophene TIC 97 14.578 14.578 0.000 97 336822 1.60 1.40
T 144 3-Methylthiophene TIC 97 14.788 14.788 0.000 99 332974 1.60 1.39
T 146 2-Ethylthiophene TIC 97 16.875 16.875 0.000 97 414917 1.60 1.73
T 153 1,2-Dimethyl-4-Ethylbenzene TIC 119 20.369 20.369 0.000 98 474332 1.60 1.98
T 156 1,2,3,5-Tetramethylbenzene TIC 119 20.822 20.822 0.000 95 339039 1.60 1.41 a
T 155 1,2,3,4-Tetramethylbenzene TIC 119 21.248 21.248 0.000 97 450662 1.60 1.88 a
T 157 Benzo(b)thiophene TIC 134 21.825 21.825 0.000 99 344385 1.60 1.43
QC Flag Legend
Processing Flags
Review Flags
a - User Assigned ID
Reagents:
40CV101S_00253 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 752 of 864
Report Date: 20-Mar-2024 14:48:52 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RCCVZC19.D
Injection Date:19-Mar-2024 07:40:30 Instrument ID:MR Operator ID:
Lims ID:CCVIS Worklist Smp#:2
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:9
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
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3
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7
8
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10
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13
14
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)
RCCVZC19[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 753 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/20/2024 07:06
03/05/2024 15:18
03/06/2024 00:47
CCVIS 140-84603/2
RTX-5
Lab File ID:RCCVZC20.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Chlorodifluoromethane 1.6071.639 1.57 1.60 -1.9 30.0Ave
Propene 0.71320.7355 1.55 1.60 -3.0 30.0Ave
Dichlorodifluoromethane 2.1982.642 1.33 1.60 -16.8 30.0Ave
Chloromethane 0.29420.2971 1.58 1.60 -1.0 30.0Ave
1,2-Dichloro-1,1,2,2-tetrafl
uoroethane 1.8822.044 1.47 1.60 -7.9 30.0Ave
Acetaldehyde 0.39670.4467 7.10 8.00 -11.2 30.0Ave
Vinyl chloride 1.1511.083 1.70 1.60 6.3 30.0Ave
Butane 1.4121.540 1.47 1.60 -8.3 30.0Ave
1,3-Butadiene 0.76810.7886 1.56 1.60 -2.6 30.0Ave
Bromomethane 1.0111.084 1.49 1.60 -6.8 30.0Ave
Chloroethane 0.55310.5689 1.56 1.60 -2.8 30.0Ave
Ethanol 0.36190.4687 6.18 8.00 -22.8 30.0Ave
Vinyl bromide 1.2101.094 1.77 1.60 10.7 30.0Ave
2-Methylbutane 1.3551.107 1.96 1.60 22.4 30.0Ave
Trichlorofluoromethane 3.0322.853 1.70 1.60 6.3 30.0Ave
Acrolein 0.36900.2948 2.00 1.60 25.2 30.0Ave
Acetonitrile 0.45060.3944 1.83 1.60 14.2 30.0Ave
Acetone 0.72840.5253 2.22 1.60 38.7 *30.0Ave
Pentane 0.22040.1962 1.80 1.60 12.3 30.0Ave
Isopropyl alcohol 1.5151.275 1.90 1.60 18.8 30.0Ave
Ethyl ether 0.99410.995 1.60 1.60 -0.0 30.0Ave
1,1-Dichloroethene 1.0371.119 1.48 1.60 -7.4 30.0Ave
Acrylonitrile 0.67460.6794 1.59 1.60 -0.7 30.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 2.3082.456 1.50 1.60 -6.0 30.0Ave
tert-Butyl alcohol 1.7891.930 1.48 1.60 -7.3 30.0Ave
Methylene Chloride 1.0571.210 1.40 1.60 -12.6 30.0Ave
3-Chloropropene 0.97541.069 1.46 1.60 -8.7 30.0Ave
Carbon disulfide 3.1153.303 1.51 1.60 -5.7 30.0Ave
trans-1,2-Dichloroethene 1.0791.168 1.48 1.60 -7.6 30.0Ave
2-Methylpentane 1.8992.117 1.44 1.60 -10.3 30.0Ave
Methyl tert-butyl ether 2.9303.075 1.52 1.60 -4.7 30.0Ave
1,1-Dichloroethane 1.9612.007 1.56 1.60 -2.3 30.0Ave
Vinyl acetate 2.2912.124 1.73 1.60 7.8 30.0Ave
n-Hexane 0.81350.8267 1.57 1.60 -1.6 30.0Ave
2-Butanone (MEK)0.52580.5317 1.58 1.60 -1.1 30.0Ave
Isopropyl ether 3.5123.268 1.72 1.60 7.5 30.0Ave
cis-1,2-Dichloroethene 1.1561.231 1.50 1.60 -6.0 30.0Ave
Ethyl acetate 2.1162.259 1.50 1.60 -6.3 30.0Ave
Chloroform 2.4012.583 1.49 1.60 -7.0 30.0Ave
Tert-butyl ethyl ether 3.1923.471 1.47 1.60 -8.0 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 754 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/20/2024 07:06
03/05/2024 15:18
03/06/2024 00:47
CCVIS 140-84603/2
RTX-5
Lab File ID:RCCVZC20.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Tetrahydrofuran 1.0811.099 1.57 1.60 -1.6 30.0Ave
1,1,1-Trichloroethane 2.3092.528 1.46 1.60 -8.7 30.0Ave
1,2-Dichloroethane 0.32380.3469 1.49 1.60 -6.6 30.0Ave
Cyclohexane 0.11400.1148 1.59 1.60 -0.7 30.0Ave
Benzene 0.76640.7629 1.61 1.60 0.5 30.0Ave
Carbon tetrachloride 0.5174 1.39 1.60 -13.0 30.0QuaF
1-Butanol 0.0799 1.46 1.60 -9.0 30.0Lin2
2,3-Dimethylpentane 0.16590.1679 1.58 1.60 -1.1 30.0Ave
Thiophene 0.42280.4320 1.57 1.60 -2.1 30.0Ave
2,2,4-Trimethylpentane 1.0851.145 1.52 1.60 -5.3 30.0Ave
n-Heptane 0.24560.2534 1.55 1.60 -3.1 30.0Ave
1,2-Dichloropropane 0.26810.2790 1.54 1.60 -3.9 30.0Ave
Trichloroethene 0.34930.3617 1.55 1.60 -3.4 30.0Ave
Dibromomethane 0.30330.3314 1.46 1.60 -8.5 30.0Ave
Bromodichloromethane 0.53060.5632 1.51 1.60 -5.8 30.0Ave
1,4-Dioxane 0.09550.1107 1.38 1.60 -13.7 30.0Ave
Methyl methacrylate 0.26950.2911 1.48 1.60 -7.4 30.0Ave
Methylcyclohexane 0.52120.4540 1.84 1.60 14.8 30.0Ave
4-Methyl-2-pentanone (MIBK)0.55080.5270 1.67 1.60 4.5 30.0Ave
cis-1,3-Dichloropropene 0.46510.4336 1.72 1.60 7.3 30.0Ave
trans-1,3-Dichloropropene 0.46620.4410 1.69 1.60 5.7 30.0Ave
Toluene 1.1101.096 1.62 1.60 1.3 30.0Ave
1,1,2-Trichloroethane 0.32900.3230 1.63 1.60 1.8 30.0Ave
2-Hexanone 0.32210.3131 1.65 1.60 2.9 30.0Ave
Octane 0.34200.3317 1.65 1.60 3.1 30.0Ave
Dibromochloromethane 0.66210.6318 1.68 1.60 4.8 30.0Ave
1,2-Dibromoethane (EDB)0.59280.5823 1.63 1.60 1.8 30.0Ave
Tetrachloroethene 0.41790.3940 1.70 1.60 6.1 30.0Ave
2,3-Dimethylheptane 0.74520.8789 1.36 1.60 -15.2 30.0Ave
Chlorobenzene 0.83710.8810 1.52 1.60 -5.0 30.0Ave
Ethylbenzene 1.3441.413 1.52 1.60 -4.9 30.0Ave
m-Xylene & p-Xylene 1.0751.105 3.11 3.20 -2.7 30.0Ave
Nonane 0.58950.6086 1.55 1.60 -3.1 30.0Ave
Styrene 0.74880.7698 1.56 1.60 -2.7 30.0Ave
Bromoform 0.59760.5537 1.73 1.60 7.9 30.0Ave
o-Xylene 1.0961.152 1.52 1.60 -4.8 30.0Ave
1,1,2,2-Tetrachloroethane 0.78500.8592 1.46 1.60 -8.6 30.0Ave
1,2,3-Trichloropropane 0.23160.2478 1.50 1.60 -6.5 30.0Ave
Isopropylbenzene 1.5181.551 1.57 1.60 -2.1 30.0Ave
Propylbenzene 0.41860.4351 1.54 1.60 -3.8 30.0Ave
2-Chlorotoluene 0.38870.3906 1.59 1.60 -0.5 30.0Ave
FORM VII TO-15
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9:50:51 AM
Page 755 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MR
03/20/2024 07:06
03/05/2024 15:18
03/06/2024 00:47
CCVIS 140-84603/2
RTX-5
Lab File ID:RCCVZC20.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
4-Ethyltoluene 1.4701.587 1.48 1.60 -7.4 30.0Ave
1,3,5-Trimethylbenzene 0.71020.6604 1.72 1.60 7.5 30.0Ave
Alpha Methyl Styrene 0.57040.6517 1.40 1.60 -12.5 30.0Ave
Decane 0.83020.8356 1.59 1.60 -0.6 30.0Ave
tert-Butylbenzene 1.3811.429 1.55 1.60 -3.3 30.0Ave
1,2,4-Trimethylbenzene 1.3241.366 1.55 1.60 -3.0 30.0Ave
sec-Butylbenzene 1.9171.965 1.56 1.60 -2.4 30.0Ave
1,3-Dichlorobenzene 0.90930.9543 1.52 1.60 -4.7 30.0Ave
Benzyl chloride 1.0361.109 1.50 1.60 -6.6 30.0Ave
1,4-Dichlorobenzene 0.90210.9562 1.51 1.60 -5.7 30.0Ave
4-Isopropyltoluene 1.6091.667 1.54 1.60 -3.5 30.0Ave
1,2,3-Trimethylbenzene 1.0001.386 1.15 1.60 -27.8 30.0Ave
Butylcyclohexane 1.0391.096 1.52 1.60 -5.2 30.0Ave
Indane 1.2641.323 1.53 1.60 -4.5 30.0Ave
1,2-Dichlorobenzene 0.88270.9271 1.52 1.60 -4.8 30.0Ave
Butylbenzene 1.6541.689 1.57 1.60 -2.1 30.0Ave
Indene 0.90511.079 1.34 1.60 -16.1 30.0Ave
Undecane 0.97890.9846 1.59 1.60 -0.6 30.0Ave
1,2-Dibromo-3-Chloropropane 0.38400.4625 1.33 1.60 -17.0 30.0Ave
1,2,4,5-Tetramethylbenzene 1.4561.699 1.37 1.60 -14.3 30.0Ave
Dodecane 1.0001.175 1.36 1.60 -14.8 30.0Ave
1,2,4-Trichlorobenzene 0.72980.8755 1.33 1.60 -16.6 30.0Ave
Naphthalene 1.7181.963 1.40 1.60 -12.5 30.0Ave
Hexachlorobutadiene 0.5865 1.28 1.60 -20.0 30.0QuaF
1,2,3-Trichlorobenzene 0.64130.6904 1.49 1.60 -7.1 30.0Ave
2-Methylnaphthalene 0.79171.100 1.15 1.60 -28.0 50.0Ave
1-Methylnaphthalene 0.91571.159 1.26 1.60 -21.0 50.0Ave
4-Bromofluorobenzene (Surr)0.75550.7311 4.22 4.08 3.3 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 756 of 864
Report Date: 21-Mar-2024 15:06:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RCCVZC20.D
Lims ID:CCVIS
Client ID:
Sample Type:CCVIS
Inject. Date:20-Mar-2024 07:06:30 ALS Bottle#:3 Worklist Smp#:2
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031995-002
Misc. Info.:S253 80 ML 662934
Operator ID:Instrument ID:MR
Sublist:chrom-MR_TO15*sub19
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 15:06:04 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1634
First Level Reviewer: CJS9 Date:21-Mar-2024 15:06:04
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.374 0.000 91 207389 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.558 0.000 95 971071 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.438 16.438 0.000 87 875539 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.078 18.078 0.000 89 674720 4.08 4.22
6 Chlorodifluoromethane 51 3.799 3.799 0.000 97 138895 1.60 1.57
7 Propene 41 3.809 3.809 0.000 98 61625 1.60 1.55
8 Dichlorodifluoromethane 85 3.869 3.869 0.000 100 189929 1.60 1.33
9 Chloromethane 52 4.074 4.074 0.000 98 25425 1.60 1.58
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.084 4.084 0.000 96 162631 1.60 1.47
12 Vinyl chloride 62 4.262 4.262 0.000 87 99474 1.60 1.70
11 Acetaldehyde 44 4.262 4.262 0.000 100 171384 8.00 7.10
13 Butane 43 4.360 4.360 0.000 92 122006 1.60 1.47
14 Butadiene 54 4.365 4.365 0.000 96 66373 1.60 1.56
15 Bromomethane 94 4.726 4.726 0.000 99 87342 1.60 1.49
16 Chloroethane 64 4.883 4.883 0.000 92 47791 1.60 1.56
17 Ethanol 31 5.055 5.055 0.000 88 156381 8.00 6.18
18 Vinyl bromide 106 5.222 5.222 0.000 99 104573 1.60 1.77
19 2-Methylbutane 43 5.271 5.271 0.000 89 117061 1.60 1.96
20 Trichlorofluoromethane 101 5.513 5.513 0.000 99 262038 1.60 1.70
21 Acrolein 56 5.562 5.562 0.000 91 31883 1.60 2.00
22 Acetonitrile 40 5.637 5.637 0.000 98 38935 1.60 1.83
23 Acetone 58 5.708 5.708 0.000 96 62944 1.60 2.22
25 Pentane 72 5.756 5.756 0.000 96 19045 1.60 1.80
24 Isopropyl alcohol 45 5.859 5.859 0.000 99 130896 1.60 1.90
26 Ethyl ether 31 5.977 5.977 0.000 93 85906 1.60 1.60
27 1,1-Dichloroethene 96 6.290 6.290 0.000 98 89596 1.60 1.48
29 Acrylonitrile 53 6.436 6.436 0.000 93 58290 1.60 1.59
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.479 6.479 0.000 96 199435 1.60 1.50
28 2-Methyl-2-propanol 59 6.549 6.549 0.000 94 154595 1.60 1.48
31 Methylene Chloride 84 6.678 6.678 0.000 92 91377 1.60 1.40
3/25/2024
9:50:51 AM
Page 757 of 864
Report Date: 21-Mar-2024 15:06:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RCCVZC20.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 6.689 6.689 0.000 97 84288 1.60 1.46
33 Carbon disulfide 76 6.845 6.845 0.000 99 269151 1.60 1.51
34 trans-1,2-Dichloroethene 96 7.536 7.536 0.000 99 93217 1.60 1.48
35 2-Methylpentane 43 7.546 7.546 0.000 92 164129 1.60 1.44
36 Methyl tert-butyl ether 73 7.708 7.708 0.000 96 253169 1.60 1.52
37 1,1-Dichloroethane 63 7.989 7.989 0.000 100 169460 1.60 1.56
38 Vinyl acetate 43 8.113 8.113 0.000 99 197932 1.60 1.73
40 Hexane 56 8.582 8.582 0.000 92 70297 1.60 1.57
39 2-Butanone (MEK) 72 8.603 8.603 0.000 98 45437 1.60 1.58
41 Isopropyl ether 45 8.770 8.770 0.000 95 303463 1.60 1.72
42 cis-1,2-Dichloroethene 96 9.029 9.029 0.000 93 99933 1.60 1.50
43 Ethyl acetate 43 9.234 9.234 0.000 99 182833 1.60 1.50
44 Chloroform 83 9.385 9.385 0.000 96 207505 1.60 1.49
45 Tert-butyl ethyl ether 59 9.488 9.488 0.000 95 275809 1.60 1.47
46 Tetrahydrofuran 42 9.838 9.838 0.000 88 93424 1.60 1.57
47 1,1,1-Trichloroethane 97 10.437 10.437 0.000 96 199541 1.60 1.46
48 1,2-Dichloroethane 62 10.555 10.555 0.000 98 131029 1.60 1.49
50 Cyclohexane 69 11.024 11.024 0.000 96 46115 1.60 1.59
51 Benzene 78 11.030 11.030 0.000 97 310089 1.60 1.61
52 Carbon tetrachloride 117 11.051 11.051 0.000 96 209328 1.60 1.39
49 n-Butanol 31 11.084 11.084 0.000 68 32343 1.60 1.46
53 2,3-Dimethylpentane 71 11.132 11.132 0.000 90 67143 1.60 1.58
54 Thiophene 84 11.305 11.305 0.000 95 171070 1.60 1.57
55 Isooctane 57 11.763 11.763 0.000 98 438830 1.60 1.52
56 n-Heptane 71 12.146 12.146 0.000 88 99354 1.60 1.55
57 1,2-Dichloropropane 63 12.265 12.265 0.000 89 108494 1.60 1.54
58 Trichloroethene 130 12.292 12.292 0.000 98 141329 1.60 1.55
59 Dibromomethane 93 12.394 12.394 0.000 97 122734 1.60 1.46
60 Dichlorobromomethane 83 12.540 12.540 0.000 99 214694 1.60 1.51
61 1,4-Dioxane 88 12.594 12.594 0.000 90 38652 1.60 1.38
62 Methyl methacrylate 41 12.637 12.637 0.000 96 109034 1.60 1.48
63 Methylcyclohexane 83 13.090 13.090 0.000 96 210904 1.60 1.84
64 4-Methyl-2-pentanone (MIBK) 43 13.548 13.548 0.000 97 222877 1.60 1.67
65 cis-1,3-Dichloropropene 75 13.580 13.580 0.000 97 188203 1.60 1.72
66 trans-1,3-Dichloropropene 75 14.298 14.298 0.000 98 163281 1.60 1.69
67 Toluene 91 14.422 14.422 0.000 92 388800 1.60 1.62
68 1,1,2-Trichloroethane 83 14.503 14.503 0.000 98 115205 1.60 1.63
69 2-Hexanone 58 14.918 14.918 0.000 95 112802 1.60 1.65
70 n-Octane 85 15.096 15.096 0.000 90 119757 1.60 1.65
71 Chlorodibromomethane 129 15.231 15.231 0.000 98 231891 1.60 1.68
72 Ethylene Dibromide 107 15.533 15.533 0.000 98 207602 1.60 1.63
73 Tetrachloroethene 129 15.592 15.592 0.000 96 146345 1.60 1.70
75 2,3-Dimethylheptane 43 16.471 16.471 0.000 93 260994 1.60 1.36
74 Chlorobenzene 112 16.487 16.487 0.000 94 293181 1.60 1.52
76 Ethylbenzene 91 16.767 16.767 0.000 98 470773 1.60 1.52
77 m-Xylene & p-Xylene 91 16.929 16.929 0.000 98 753223 3.20 3.11
78 n-Nonane 57 17.323 17.323 0.000 86 206463 1.60 1.55
80 Styrene 104 17.404 17.404 0.000 99 262235 1.60 1.56
79 Bromoform 173 17.409 17.409 0.000 96 209273 1.60 1.73
81 o-Xylene 91 17.463 17.463 0.000 98 383956 1.60 1.52
82 1,1,2,2-Tetrachloroethane 83 17.792 17.792 0.000 99 274904 1.60 1.46
83 1,2,3-Trichloropropane 110 17.948 17.948 0.000 97 81118 1.60 1.50
3/25/2024
9:50:51 AM
Page 758 of 864
Report Date: 21-Mar-2024 15:06:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RCCVZC20.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.035 18.035 0.000 96 531702 1.60 1.57
85 N-Propylbenzene 120 18.547 18.547 0.000 99 146607 1.60 1.54
86 2-Chlorotoluene 126 18.606 18.606 0.000 98 136128 1.60 1.59
88 4-Ethyltoluene 105 18.692 18.692 0.000 99 514715 1.60 1.48
87 1,3,5-Trimethylbenzene 120 18.757 18.757 0.000 93 248714 1.60 1.72
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 87 199747 1.60 1.40
90 n-Decane 57 19.011 19.011 0.000 94 290752 1.60 1.59
91 tert-Butylbenzene 119 19.167 19.167 0.000 93 483807 1.60 1.55
92 1,2,4-Trimethylbenzene 105 19.183 19.183 0.000 96 463807 1.60 1.55
93 sec-Butylbenzene 105 19.426 19.426 0.000 99 671391 1.60 1.56
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 98 318464 1.60 1.52
95 Benzyl chloride 91 19.528 19.528 0.000 98 362939 1.60 1.50
96 1,4-Dichlorobenzene 146 19.539 19.539 0.000 94 315943 1.60 1.51
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 563382 1.60 1.54
98 1,2,3-Trimethylbenzene 105 19.641 19.641 0.000 98 350356 1.60 1.15
99 Butylcyclohexane 83 19.685 19.685 0.000 95 363993 1.60 1.52
100 2,3-Dihydroindene 117 19.890 19.890 0.000 93 442735 1.60 1.53
101 1,2-Dichlorobenzene 146 19.895 19.895 0.000 95 309145 1.60 1.52
103 n-Butylbenzene 91 20.003 20.003 0.000 98 579394 1.60 1.57
102 Indene 116 20.019 20.019 0.000 92 316986 1.60 1.34
104 Undecane 57 20.283 20.283 0.000 94 342827 1.60 1.59
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.488 0.000 97 134500 1.60 1.33
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.763 0.000 97 509852 1.60 1.37
107 Dodecane 57 21.378 21.378 0.000 96 350381 1.60 1.36
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 255587 1.60 1.33
109 Naphthalene 128 21.745 21.745 0.000 99 601842 1.60 1.40
110 Hexachlorobutadiene 225 21.890 21.890 0.000 94 205400 1.60 1.28
111 1,2,3-Trichlorobenzene 180 21.949 21.949 0.000 94 224606 1.60 1.49
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 277294 1.60 1.15
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 320723 1.60 1.26
A 116 C8 Range 1 15.101 (15.047-15.155) 0 1023378 1.60 1.58
S 117 Xylenes, Total 100 0 4.80 4.64
S 118 1,2-Dichloroethene, Total 1 0 3.20 2.98
T 143 2-Methylthiophene TIC 97 14.583 14.583 0.000 97 300019 1.60 1.37
T 144 3-Methylthiophene TIC 97 14.794 14.794 0.000 99 297013 1.60 1.36
T 146 2-Ethylthiophene TIC 97 16.875 16.875 0.000 97 344517 1.60 1.57
T 153 1,2-Dimethyl-4-Ethylbenzene TIC 119 20.369 20.369 0.000 98 424501 1.60 1.94
T 156 1,2,3,5-Tetramethylbenzene TIC 119 20.822 20.822 0.000 95 306047 1.60 1.40 a
T 155 1,2,3,4-Tetramethylbenzene TIC 119 21.248 21.248 0.000 97 400410 1.60 1.83 a
T 157 Benzo(b)thiophene TIC 134 21.825 21.825 0.000 99 318116 1.60 1.45
QC Flag Legend
Processing Flags
Review Flags
a - User Assigned ID
Reagents:
40CV101S_00253 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 759 of 864
Report Date: 21-Mar-2024 15:06:05 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RCCVZC20.D
Injection Date:20-Mar-2024 07:06:30 Instrument ID:MR Operator ID:
Lims ID:CCVIS Worklist Smp#:2
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:3
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
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3
4
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6
7
8
9
10
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)
RCCVZC20[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 760 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MS
02/08/2024 04:07
02/07/2024 15:26
02/08/2024 01:36
ICV 140-83168/18
RTX-5
Lab File ID:SZB07LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Chlorodifluoromethane 1.9421.740 1.79 1.60 11.6 35.0Ave
Propene 0.94930.8384 1.81 1.60 13.2 35.0Ave
Dichlorodifluoromethane 3.0902.526 1.96 1.60 22.3 35.0Ave
Chloromethane 0.17730.1568 1.81 1.60 13.1 35.0Ave
1,2-Dichloro-1,1,2,2-tetrafl
uoroethane 1.8111.593 1.82 1.60 13.7 35.0Ave
Acetaldehyde 0.17970.1788 8.04 8.00 0.5 35.0Ave
Vinyl chloride 0.56860.5055 1.80 1.60 12.5 35.0Ave
1,3-Butadiene 0.39540.3744 1.69 1.60 5.6 35.0Ave
Butane 0.76560.6771 1.81 1.60 13.1 35.0Ave
Bromomethane 0.56150.5494 1.64 1.60 2.2 35.0Ave
Chloroethane 0.23820.2208 1.73 1.60 7.9 35.0Ave
Ethanol 0.18150.2259 6.43 8.00 -19.6 35.0Ave
Vinyl bromide 1.0960.9331 1.88 1.60 17.5 35.0Ave
2-Methylbutane 1.0960.9649 1.82 1.60 13.6 35.0Ave
Trichlorofluoromethane 3.1602.879 1.76 1.60 9.8 35.0Ave
Acrolein 0.36550.3047 1.92 1.60 20.0 35.0Ave
Acetonitrile 0.39780.3625 1.76 1.60 9.8 35.0Ave
Acetone 0.46100.3974 1.86 1.60 16.0 35.0Ave
Isopropyl alcohol 1.493 1.97 1.60 22.9 35.0QuaF
Pentane 0.18600.1577 1.89 1.60 18.0 35.0Ave
Ethyl ether 1.1691.011 1.85 1.60 15.7 35.0Ave
1,1-Dichloroethene 1.1211.017 1.76 1.60 10.3 35.0Ave
Acrylonitrile 0.73510.6474 1.82 1.60 13.6 35.0Ave
tert-Butyl alcohol 1.8241.717 1.70 1.60 6.2 35.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 2.4902.250 1.77 1.60 10.7 35.0Ave
Methylene Chloride 0.98000.9621 1.63 1.60 1.9 35.0Ave
3-Chloropropene 0.96070.9314 1.65 1.60 3.2 35.0Ave
Carbon disulfide 2.9622.750 1.72 1.60 7.7 35.0Ave
trans-1,2-Dichloroethene 1.1321.044 1.73 1.60 8.4 35.0Ave
2-Methylpentane 2.0771.981 1.68 1.60 4.9 35.0Ave
Methyl tert-butyl ether 3.1172.813 1.77 1.60 10.8 35.0Ave
1,1-Dichloroethane 1.9841.810 1.75 1.60 9.6 35.0Ave
Vinyl acetate 2.3452.173 1.73 1.60 7.9 35.0Ave
2-Butanone (MEK)0.51540.4691 1.76 1.60 9.9 35.0Ave
Hexane 0.83980.7565 1.78 1.60 11.0 35.0Ave
Isopropyl ether 3.6023.122 1.85 1.60 15.4 35.0Ave
cis-1,2-Dichloroethene 1.2461.103 1.81 1.60 13.0 35.0Ave
Ethyl acetate 2.2852.166 1.69 1.60 5.5 35.0Ave
Chloroform 2.4942.218 1.80 1.60 12.5 35.0Ave
Tert-butyl ethyl ether 3.2443.023 1.72 1.60 7.3 35.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 761 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MS
02/08/2024 04:07
02/07/2024 15:26
02/08/2024 01:36
ICV 140-83168/18
RTX-5
Lab File ID:SZB07LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Tetrahydrofuran 1.1751.066 1.76 1.60 10.2 35.0Ave
1,1,1-Trichloroethane 2.7502.510 1.75 1.60 9.6 35.0Ave
1,2-Dichloroethane 0.35340.3130 1.81 1.60 12.9 35.0Ave
1-Butanol 0.08830.0854 1.65 1.60 3.3 35.0Ave
Benzene 0.74690.6405 1.87 1.60 16.6 35.0Ave
Cyclohexane 0.11350.0992 1.83 1.60 14.5 35.0Ave
Carbon tetrachloride 0.6658 1.79 1.60 12.0 35.0QuaF
2,3-Dimethylpentane 0.16180.1464 1.77 1.60 10.5 35.0Ave
Thiophene 0.42470.3796 1.79 1.60 11.9 35.0Ave
2,2,4-Trimethylpentane 1.1280.9738 1.85 1.60 15.8 35.0Ave
Heptane 0.24590.2128 1.85 1.60 15.5 35.0Ave
1,2-Dichloropropane 0.26940.2352 1.83 1.60 14.5 35.0Ave
Trichloroethene 0.41370.3639 1.82 1.60 13.7 35.0Ave
Dibromomethane 0.32270.2986 1.73 1.60 8.1 35.0Ave
Bromodichloromethane 0.57300.4936 1.86 1.60 16.1 35.0Ave
1,4-Dioxane 0.10110.0993 1.63 1.60 1.8 35.0Ave
Methyl methacrylate 0.31850.2886 1.77 1.60 10.3 35.0Ave
Methylcyclohexane 0.5515 2.13 1.60 33.2 35.0QuaF
4-Methyl-2-pentanone (MIBK)0.55690.4903 1.82 1.60 13.6 35.0Ave
cis-1,3-Dichloropropene 0.44260.3788 1.87 1.60 16.8 35.0Ave
trans-1,3-Dichloropropene 0.47920.4089 1.88 1.60 17.2 35.0Ave
Toluene 1.1020.9749 1.81 1.60 13.0 35.0Ave
1,1,2-Trichloroethane 0.31390.2817 1.78 1.60 11.4 35.0Ave
2-Hexanone 0.32480.2904 1.79 1.60 11.9 35.0Ave
Octane 0.33670.2904 1.86 1.60 15.9 35.0Ave
Dibromochloromethane 0.78950.6661 1.90 1.60 18.5 35.0Ave
1,2-Dibromoethane (EDB)0.63330.5526 1.83 1.60 14.6 35.0Ave
Tetrachloroethene 0.45620.4050 1.80 1.60 12.6 35.0Ave
2,3-Dimethylheptane 0.81870.7860 1.67 1.60 4.2 35.0Ave
Chlorobenzene 0.95410.8214 1.86 1.60 16.2 35.0Ave
Ethylbenzene 1.4891.291 1.85 1.60 15.4 35.0Ave
m-Xylene & p-Xylene 1.1640.9859 3.78 3.20 18.1 35.0Ave
Nonane 0.65980.5527 1.91 1.60 19.4 35.0Ave
Styrene 0.90010.7681 1.87 1.60 17.2 35.0Ave
Bromoform 0.8793 1.86 1.60 16.4 35.0Lin2
o-Xylene 1.2131.119 1.73 1.60 8.4 35.0Ave
1,1,2,2-Tetrachloroethane 0.87430.7791 1.80 1.60 12.2 35.0Ave
1,2,3-Trichloropropane 0.27570.2463 1.79 1.60 11.9 35.0Ave
Isopropylbenzene 1.9091.672 1.83 1.60 14.2 35.0Ave
Propylbenzene 0.57210.4829 1.90 1.60 18.5 35.0Ave
2-Chlorotoluene 0.52760.4559 1.85 1.60 15.7 35.0Ave
FORM VII TO-15
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9:50:51 AM
Page 762 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MS
02/08/2024 04:07
02/07/2024 15:26
02/08/2024 01:36
ICV 140-83168/18
RTX-5
Lab File ID:SZB07LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
4-Ethyltoluene 1.8741.718 1.75 1.60 9.1 35.0Ave
1,3,5-Trimethylbenzene 0.96130.7437 2.07 1.60 29.3 35.0Ave
Alpha Methyl Styrene 0.84940.7365 1.85 1.60 15.3 35.0Ave
Decane 0.97950.8560 1.83 1.60 14.4 35.0Ave
tert-Butylbenzene 1.8331.605 1.83 1.60 14.2 35.0Ave
1,2,4-Trimethylbenzene 1.6231.435 1.81 1.60 13.1 35.0Ave
sec-Butylbenzene 2.4542.144 1.83 1.60 14.4 35.0Ave
1,3-Dichlorobenzene 1.2561.128 1.78 1.60 11.3 35.0Ave
Benzyl chloride 1.1611.000 1.86 1.60 16.1 35.0Ave
1,4-Dichlorobenzene 1.2301.108 1.78 1.60 11.0 35.0Ave
4-Isopropyltoluene 2.1351.923 1.78 1.60 11.0 35.0Ave
1,2,3-Trimethylbenzene 1.2501.468 1.36 1.60 -14.8 35.0Ave
Butylcyclohexane 1.1871.083 1.75 1.60 9.5 35.0Ave
Indane 1.6101.444 1.78 1.60 11.4 35.0Ave
1,2-Dichlorobenzene 1.2191.103 1.77 1.60 10.5 35.0Ave
Butylbenzene 1.9201.719 1.79 1.60 11.7 35.0Ave
Indene 1.2381.253 1.58 1.60 -1.3 35.0Ave
Undecane 1.1721.070 1.75 1.60 9.5 35.0Ave
1,2-Dibromo-3-Chloropropane 0.54520.5563 1.57 1.60 -2.0 35.0Ave
1,2,4,5-Tetramethylbenzene 1.9721.914 1.65 1.60 3.1 35.0Ave
Dodecane 0.97010.9037 1.72 1.60 7.3 35.0Ave
1,2,4-Trichlorobenzene 0.66390.6396 1.66 1.60 3.8 35.0Ave
Naphthalene 1.1731.214 1.55 1.60 -3.4 35.0Ave
Hexachlorobutadiene 0.70100.8864 1.27 1.60 -20.9 35.0Ave
1,2,3-Trichlorobenzene 0.51540.4732 1.74 1.60 8.9 35.0Ave
2-Methylnaphthalene 0.43000.4946 1.39 1.60 -13.1 50.0Ave
1-Methylnaphthalene 0.51130.5473 1.49 1.60 -6.6 50.0Ave
4-Bromofluorobenzene (Surr)0.71330.7156 4.07 4.08 -0.3 35.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 763 of 864
Report Date: 10-Feb-2024 14:48:10 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07LCS.D
Lims ID:ICV
Client ID:
Sample Type:ICV
Inject. Date:08-Feb-2024 04:07:30 ALS Bottle#:14 Worklist Smp#:18
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031497-018
Misc. Info.:662930 S252 80ML
Operator ID:Instrument ID:MS
Sublist:
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:47:32 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 14:48:10
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.926 9.926 0.000 86 326069 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.040 12.046 -0.006 93 1514898 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.651 16.651 0.000 84 1358477 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.265 18.265 0.000 96 988434 4.08 4.07
6 Chlorodifluoromethane 51 4.170 4.170 0.000 97 263890 1.60 1.79
7 Propene 41 4.181 4.181 0.000 98 128972 1.60 1.81
8 Dichlorodifluoromethane 85 4.245 4.245 0.000 100 419761 1.60 1.96
9 Chloromethane 52 4.461 4.461 0.000 96 24095 1.60 1.81
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.466 4.471 -0.005 93 246045 1.60 1.82
11 Acetaldehyde 44 4.649 4.649 0.000 94 122047 8.00 8.04
12 Vinyl chloride 62 4.670 4.670 0.000 99 77248 1.60 1.80
14 Butane 43 4.773 4.773 0.000 83 104014 1.60 1.81
13 Butadiene 54 4.773 4.778 -0.005 73 53715 1.60 1.69
15 Bromomethane 94 5.165 5.165 0.000 98 76285 1.60 1.64
16 Chloroethane 64 5.332 5.337 -0.005 90 32356 1.60 1.73
17 Ethanol 31 5.440 5.440 0.000 99 123317 8.00 6.43
18 Vinyl bromide 106 5.687 5.693 -0.006 98 148931 1.60 1.88
19 2-Methylbutane 43 5.741 5.741 0.000 90 148913 1.60 1.82
20 Trichlorofluoromethane 101 5.999 5.999 0.000 99 429378 1.60 1.76
21 Acrolein 56 6.015 6.010 0.005 96 49659 1.60 1.92
22 Acetonitrile 40 6.091 6.085 0.006 99 54050 1.60 1.76
23 Acetone 58 6.150 6.139 0.011 98 62635 1.60 1.86
24 Isopropyl alcohol 45 6.247 6.236 0.011 93 202779 1.60 1.97
25 Pentane 72 6.247 6.247 0.000 98 25274 1.60 1.89
26 Ethyl ether 31 6.440 6.435 0.005 95 158872 1.60 1.85
27 1,1-Dichloroethene 96 6.806 6.806 0.000 99 152336 1.60 1.76
28 Acrylonitrile 53 6.914 6.919 -0.005 93 99879 1.60 1.82
29 2-Methyl-2-propanol 59 6.924 6.919 0.005 95 247771 1.60 1.70
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.989 6.989 0.000 94 338284 1.60 1.77
31 Methylene Chloride 84 7.193 7.188 0.005 94 133147 1.60 1.63
3/25/2024
9:50:51 AM
Page 764 of 864
Report Date: 10-Feb-2024 14:48:10 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07LCS.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.204 7.204 0.000 98 130523 1.60 1.65
33 Carbon disulfide 76 7.382 7.382 0.000 99 402457 1.60 1.72
34 trans-1,2-Dichloroethene 96 8.070 8.076 -0.006 97 153832 1.60 1.73
35 2-Methylpentane 43 8.081 8.081 0.000 94 282249 1.60 1.68
36 Methyl tert-butyl ether 73 8.199 8.194 0.005 96 423517 1.60 1.77
37 1,1-Dichloroethane 63 8.528 8.533 -0.005 100 269529 1.60 1.75
38 Vinyl acetate 43 8.619 8.624 -0.005 100 318633 1.60 1.73
39 2-Butanone (MEK) 72 9.103 9.103 0.000 98 70029 1.60 1.76
40 Hexane 56 9.125 9.130 -0.005 92 114094 1.60 1.78
41 Isopropyl ether 45 9.286 9.286 0.000 96 489353 1.60 1.85
42 cis-1,2-Dichloroethene 96 9.571 9.571 0.000 92 169340 1.60 1.81
43 Ethyl acetate 43 9.738 9.738 0.000 99 310445 1.60 1.69
44 Chloroform 83 9.926 9.926 0.000 95 338859 1.60 1.80
45 Tert-butyl ethyl ether 59 9.996 9.996 0.000 95 440774 1.60 1.72
46 Tetrahydrofuran 42 10.335 10.335 0.000 91 159579 1.60 1.76
47 1,1,1-Trichloroethane 97 10.970 10.970 0.000 95 373688 1.60 1.75
48 1,2-Dichloroethane 62 11.072 11.072 0.000 98 223053 1.60 1.81
49 n-Butanol 31 11.465 11.454 0.011 87 55705 1.60 1.65
51 Benzene 78 11.540 11.540 0.000 97 471438 1.60 1.87
50 Cyclohexane 69 11.540 11.540 0.000 79 71642 1.60 1.83
52 Carbon tetrachloride 117 11.562 11.562 0.000 98 420230 1.60 1.79
53 2,3-Dimethylpentane 71 11.632 11.632 0.000 90 102107 1.60 1.77
54 Thiophene 84 11.809 11.809 0.000 94 268050 1.60 1.79
55 Isooctane 57 12.245 12.245 0.000 99 712091 1.60 1.85
56 n-Heptane 71 12.589 12.595 -0.005 91 155222 1.60 1.85
57 1,2-Dichloropropane 63 12.707 12.707 0.000 90 170039 1.60 1.83
58 Trichloroethene 130 12.740 12.740 0.000 97 261139 1.60 1.82
59 Dibromomethane 93 12.831 12.831 0.000 90 203669 1.60 1.73
60 Dichlorobromomethane 83 12.960 12.960 0.000 99 361666 1.60 1.86
61 1,4-Dioxane 88 12.966 12.966 0.000 77 63817 1.60 1.63
62 Methyl methacrylate 41 13.014 13.014 0.000 94 201020 1.60 1.77
63 Methylcyclohexane 83 13.482 13.482 0.000 96 348083 1.60 2.13
64 4-Methyl-2-pentanone (MIBK) 43 13.848 13.848 0.000 97 351498 1.60 1.82
65 cis-1,3-Dichloropropene 75 13.918 13.918 0.000 94 279386 1.60 1.87
66 trans-1,3-Dichloropropene 75 14.590 14.590 0.000 99 260375 1.60 1.88
67 Toluene 91 14.719 14.725 -0.006 94 598709 1.60 1.81
68 1,1,2-Trichloroethane 83 14.795 14.795 0.000 97 170578 1.60 1.78
69 2-Hexanone 58 15.139 15.139 0.000 94 176506 1.60 1.79
70 n-Octane 85 15.354 15.354 0.000 92 182960 1.60 1.86
71 Chlorodibromomethane 129 15.489 15.494 -0.005 98 428990 1.60 1.90
72 Ethylene Dibromide 107 15.779 15.779 0.000 99 344106 1.60 1.83
73 Tetrachloroethene 129 15.838 15.838 0.000 96 247896 1.60 1.80
74 2,3-Dimethylheptane 43 16.678 16.678 0.000 94 444849 1.60 1.67
75 Chlorobenzene 112 16.699 16.699 0.000 96 518471 1.60 1.86
76 Ethylbenzene 91 16.968 16.973 -0.005 98 809358 1.60 1.85
77 m-Xylene & p-Xylene 91 17.124 17.129 -0.005 99 1265065 3.20 3.78
78 n-Nonane 57 17.501 17.501 0.000 90 358542 1.60 1.91
80 Styrene 104 17.587 17.592 -0.005 98 489088 1.60 1.87
79 Bromoform 173 17.598 17.598 0.000 98 477827 1.60 1.86
81 o-Xylene 91 17.651 17.651 0.000 99 659219 1.60 1.73
82 1,1,2,2-Tetrachloroethane 83 17.969 17.969 0.000 100 475077 1.60 1.80
83 1,2,3-Trichloropropane 110 18.130 18.130 0.000 97 149788 1.60 1.79
3/25/2024
9:50:51 AM
Page 765 of 864
Report Date: 10-Feb-2024 14:48:10 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07LCS.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.222 18.222 0.000 95 1037195 1.60 1.83
85 N-Propylbenzene 120 18.749 18.749 0.000 100 310854 1.60 1.90
86 2-Chlorotoluene 126 18.803 18.803 0.000 97 286667 1.60 1.85
87 4-Ethyltoluene 105 18.894 18.894 0.000 99 1018237 1.60 1.75
88 1,3,5-Trimethylbenzene 120 18.964 18.964 0.000 94 522344 1.60 2.07
89 Alpha Methyl Styrene 118 19.190 19.195 -0.005 91 461572 1.60 1.85
90 n-Decane 57 19.217 19.217 0.000 91 532255 1.60 1.83
91 tert-Butylbenzene 119 19.389 19.389 0.000 94 996263 1.60 1.83
92 1,2,4-Trimethylbenzene 105 19.400 19.400 0.000 95 881688 1.60 1.81
93 sec-Butylbenzene 105 19.652 19.653 0.000 99 1333600 1.60 1.83
94 1,3-Dichlorobenzene 146 19.679 19.679 0.000 95 682259 1.60 1.78
95 Benzyl chloride 91 19.749 19.755 -0.006 99 630885 1.60 1.86
96 1,4-Dichlorobenzene 146 19.765 19.765 0.000 97 668108 1.60 1.78
97 4-Isopropyltoluene 119 19.809 19.809 -0.001 98 1160355 1.60 1.78
98 1,2,3-Trimethylbenzene 105 19.868 19.873 -0.005 97 679476 1.60 1.36
99 Butylcyclohexane 83 19.916 19.916 0.000 95 644877 1.60 1.75
100 2,3-Dihydroindene 117 20.121 20.121 0.000 95 874636 1.60 1.78
101 1,2-Dichlorobenzene 146 20.126 20.126 0.000 99 662359 1.60 1.77
102 n-Butylbenzene 91 20.239 20.239 0.000 98 1043192 1.60 1.79
103 Indene 116 20.255 20.255 0.000 92 672451 1.60 1.58
104 Undecane 57 20.529 20.529 0.000 95 636650 1.60 1.75
105 1,2-Dibromo-3-Chloropropane 157 20.745 20.745 0.000 95 296244 1.60 1.57
106 1,2,4,5-Tetramethylbenzene 119 21.030 21.035 -0.005 98 1071810 1.60 1.65
107 Dodecane 57 21.643 21.643 0.000 96 527118 1.60 1.72
108 1,2,4-Trichlorobenzene 180 21.858 21.858 0.000 94 360775 1.60 1.66
109 Naphthalene 128 21.966 21.966 0.000 99 637349 1.60 1.55
110 Hexachlorobutadiene 225 22.095 22.095 0.000 94 380921 1.60 1.27
111 1,2,3-Trichlorobenzene 180 22.154 22.154 0.000 95 280060 1.60 1.74
112 2-Methylnaphthalene 142 22.676 22.676 0.000 99 233663 1.60 1.39
113 1-Methylnaphthalene 142 22.805 22.805 0.000 100 277823 1.60 1.49
A 115 C8 Range 1 15.354 (15.300-15.408) 0 1586845 1.60 1.89
S 116 Xylenes, Total 100 0 4.80 5.51
S 117 1,2-Dichloroethene, Total 1 0 3.20 3.54
T 150 1,2,3,5-Tetramethylbenzene TIC 119 20.621 20.627 -0.008 89 863765 1.60 2.54
QC Flag Legend
Processing Flags
Reagents:
40CV101S_00252 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 766 of 864
Report Date: 10-Feb-2024 14:48:10 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07LCS.D
Injection Date:08-Feb-2024 04:07:30 Instrument ID:MS Operator ID:
Lims ID:ICV Worklist Smp#:18
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:14
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
Y ( X10
0
0
0
0
)
SZB07LCS[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
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e

(IS
)(

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.
9
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+
* 1
,4-
D
i
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u
o
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o
b
e
n
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e
( 1
2
.
0
4
0
)
* C
h
l
o
r
o
b
e
n
zen
e
-
d5
(IS
)(
1
6.656)
+
$ 4
-
B
r
o
m
o
f
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u
o
r
o
b
e
n
zen
e

(Su
r
r
)(
1
8
.
2
65)
3/25/2024
9:50:51 AM
Page 767 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MS
03/21/2024 06:46
02/07/2024 15:26
02/08/2024 01:36
CCVIS 140-84641/2
RTX-5
Lab File ID:SCCVZC21.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Chlorodifluoromethane 2.0781.740 1.91 1.60 19.5 30.0Ave
Propene 0.72500.8384 1.38 1.60 -13.5 30.0Ave
Dichlorodifluoromethane 4.0462.526 2.56 1.60 60.2 *30.0Ave
Chloromethane 0.30660.1568 3.13 1.60 95.6 *30.0Ave
1,2-Dichloro-1,1,2,2-tetrafl
uoroethane 3.2241.593 3.24 1.60 102.4 *30.0Ave
Acetaldehyde 0.32680.1788 14.6 8.00 82.7 *30.0Ave
Vinyl chloride 1.0500.5055 3.32 1.60 107.7 *30.0Ave
1,3-Butadiene 0.73190.3744 3.13 1.60 95.5 *30.0Ave
Butane 1.3760.6771 3.25 1.60 103.2 *30.0Ave
Bromomethane 1.2230.5494 3.56 1.60 122.7 *30.0Ave
Chloroethane 0.51720.2208 3.75 1.60 134.3 *30.0Ave
Ethanol 0.29860.2259 10.6 8.00 32.2 *30.0Ave
Vinyl bromide 0.98990.9331 1.70 1.60 6.1 30.0Ave
2-Methylbutane 0.88520.9649 1.47 1.60 -8.3 30.0Ave
Trichlorofluoromethane 4.5152.879 2.51 1.60 56.8 *30.0Ave
Acrolein 0.23760.3047 1.25 1.60 -22.0 30.0Ave
Acetonitrile 0.28840.3625 1.27 1.60 -20.4 30.0Ave
Acetone 0.38040.3974 1.53 1.60 -4.3 30.0Ave
Isopropyl alcohol 1.164 1.53 1.60 -4.4 30.0QuaF
Pentane 0.14950.1577 1.52 1.60 -5.2 30.0Ave
Ethyl ether 0.70661.011 1.12 1.60 -30.1 *30.0Ave
1,1-Dichloroethene 0.92941.017 1.46 1.60 -8.6 30.0Ave
Acrylonitrile 0.55990.6474 1.38 1.60 -13.5 30.0Ave
tert-Butyl alcohol 1.6041.717 1.50 1.60 -6.6 30.0Ave
1,1,2-Trichloro-1,2,2-triflu
oroethane 2.6442.250 1.88 1.60 17.5 30.0Ave
Methylene Chloride 0.84660.9621 1.41 1.60 -12.0 30.0Ave
3-Chloropropene 0.91930.9314 1.58 1.60 -1.3 30.0Ave
Carbon disulfide 2.4992.750 1.45 1.60 -9.1 30.0Ave
trans-1,2-Dichloroethene 0.94311.044 1.44 1.60 -9.7 30.0Ave
2-Methylpentane 1.4861.981 1.20 1.60 -25.0 30.0Ave
Methyl tert-butyl ether 2.8502.813 1.62 1.60 1.3 30.0Ave
1,1-Dichloroethane 1.7791.810 1.57 1.60 -1.7 30.0Ave
Vinyl acetate 1.6522.173 1.22 1.60 -24.0 30.0Ave
2-Butanone (MEK)0.38090.4691 1.30 1.60 -18.8 30.0Ave
Hexane 0.69370.7565 1.47 1.60 -8.3 30.0Ave
Isopropyl ether 2.4613.122 1.26 1.60 -21.2 30.0Ave
cis-1,2-Dichloroethene 0.98811.103 1.43 1.60 -10.4 30.0Ave
Ethyl acetate 1.6722.166 1.24 1.60 -22.8 30.0Ave
Chloroform 2.8082.218 2.03 1.60 26.6 30.0Ave
Tert-butyl ethyl ether 2.6833.023 1.42 1.60 -11.3 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 768 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MS
03/21/2024 06:46
02/07/2024 15:26
02/08/2024 01:36
CCVIS 140-84641/2
RTX-5
Lab File ID:SCCVZC21.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Tetrahydrofuran 0.76251.066 1.14 1.60 -28.5 30.0Ave
1,1,1-Trichloroethane 3.4572.510 2.20 1.60 37.7 *30.0Ave
1,2-Dichloroethane 0.40920.3130 2.09 1.60 30.7 *30.0Ave
1-Butanol 0.04640.0854 0.869 1.60 -45.7 *30.0Ave
Benzene 0.61520.6405 1.54 1.60 -3.9 30.0Ave
Cyclohexane 0.09330.0992 1.51 1.60 -5.9 30.0Ave
Carbon tetrachloride 0.8743 2.37 1.60 47.9 *30.0QuaF
2,3-Dimethylpentane 0.11980.1464 1.31 1.60 -18.2 30.0Ave
Thiophene 0.32090.3796 1.35 1.60 -15.5 30.0Ave
2,2,4-Trimethylpentane 0.82520.9738 1.36 1.60 -15.3 30.0Ave
Heptane 0.17670.2128 1.33 1.60 -17.0 30.0Ave
1,2-Dichloropropane 0.20110.2352 1.37 1.60 -14.5 30.0Ave
Trichloroethene 0.35170.3639 1.55 1.60 -3.3 30.0Ave
Dibromomethane 0.34300.2986 1.84 1.60 14.9 30.0Ave
1,4-Dioxane 0.07550.0993 1.22 1.60 -24.0 30.0Ave
Bromodichloromethane 0.62740.4936 2.03 1.60 27.1 30.0Ave
Methyl methacrylate 0.24500.2886 1.36 1.60 -15.1 30.0Ave
Methylcyclohexane 0.4276 1.65 1.60 2.9 30.0QuaF
4-Methyl-2-pentanone (MIBK)0.38000.4903 1.24 1.60 -22.5 30.0Ave
cis-1,3-Dichloropropene 0.37020.3788 1.56 1.60 -2.3 30.0Ave
trans-1,3-Dichloropropene 0.39750.4089 1.56 1.60 -2.8 30.0Ave
Toluene 0.89270.9749 1.47 1.60 -8.4 30.0Ave
1,1,2-Trichloroethane 0.26230.2817 1.49 1.60 -6.9 30.0Ave
2-Hexanone 0.21500.2904 1.18 1.60 -26.0 30.0Ave
Octane 0.26920.2904 1.48 1.60 -7.3 30.0Ave
Dibromochloromethane 0.81260.6661 1.95 1.60 22.0 30.0Ave
1,2-Dibromoethane (EDB)0.53820.5526 1.56 1.60 -2.6 30.0Ave
Tetrachloroethene 0.45310.4050 1.79 1.60 11.9 30.0Ave
2,3-Dimethylheptane 0.64290.7860 1.31 1.60 -18.2 30.0Ave
Chlorobenzene 0.83010.8214 1.62 1.60 1.1 30.0Ave
Ethylbenzene 1.2651.291 1.57 1.60 -2.0 30.0Ave
m-Xylene & p-Xylene 1.1650.9859 3.78 3.20 18.1 30.0Ave
Nonane 0.47980.5527 1.39 1.60 -13.2 30.0Ave
Styrene 0.72730.7681 1.52 1.60 -5.3 30.0Ave
Bromoform 0.9119 1.93 1.60 20.6 30.0Lin2
o-Xylene 1.1671.119 1.67 1.60 4.3 30.0Ave
1,1,2,2-Tetrachloroethane 0.67140.7791 1.38 1.60 -13.8 30.0Ave
1,2,3-Trichloropropane 0.25570.2463 1.66 1.60 3.8 30.0Ave
Isopropylbenzene 1.6821.672 1.61 1.60 0.6 30.0Ave
Propylbenzene 0.42980.4829 1.42 1.60 -11.0 30.0Ave
2-Chlorotoluene 0.43160.4559 1.51 1.60 -5.3 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 769 of 864
FORM VII
Lab Name:Job No.:
AIR - GC/MS VOA CONTINUING CALIBRATION DATA
140-35862-1Eurofins Knoxville
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.32(mm)
MS
03/21/2024 06:46
02/07/2024 15:26
02/08/2024 01:36
CCVIS 140-84641/2
RTX-5
Lab File ID:SCCVZC21.D Heated Purge: (Y/N)NConc. Units:ppb v/v
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
4-Ethyltoluene 1.6291.718 1.52 1.60 -5.2 30.0Ave
1,3,5-Trimethylbenzene 0.79710.7437 1.71 1.60 7.2 30.0Ave
Alpha Methyl Styrene 0.62490.7365 1.36 1.60 -15.2 30.0Ave
Decane 0.76100.8560 1.42 1.60 -11.1 30.0Ave
tert-Butylbenzene 1.7391.605 1.73 1.60 8.4 30.0Ave
1,2,4-Trimethylbenzene 1.5961.435 1.78 1.60 11.2 30.0Ave
sec-Butylbenzene 2.1212.144 1.58 1.60 -1.1 30.0Ave
1,3-Dichlorobenzene 1.0781.128 1.53 1.60 -4.5 30.0Ave
Benzyl chloride 1.0341.000 1.65 1.60 3.4 30.0Ave
1,4-Dichlorobenzene 1.0791.108 1.56 1.60 -2.6 30.0Ave
4-Isopropyltoluene 2.0231.923 1.68 1.60 5.2 30.0Ave
1,2,3-Trimethylbenzene 1.1831.468 1.29 1.60 -19.4 30.0Ave
Butylcyclohexane 0.94301.083 1.39 1.60 -13.0 30.0Ave
Indane 1.3701.444 1.52 1.60 -5.2 30.0Ave
1,2-Dichlorobenzene 1.0921.103 1.58 1.60 -1.0 30.0Ave
Butylbenzene 1.7721.719 1.65 1.60 3.1 30.0Ave
Indene 0.98841.253 1.26 1.60 -21.1 30.0Ave
Undecane 0.84831.070 1.27 1.60 -20.7 30.0Ave
1,2-Dibromo-3-Chloropropane 0.43870.5563 1.26 1.60 -21.2 30.0Ave
1,2,4,5-Tetramethylbenzene 1.7831.914 1.49 1.60 -6.8 30.0Ave
Dodecane 0.80200.9037 1.42 1.60 -11.2 30.0Ave
1,2,4-Trichlorobenzene 0.87380.6396 2.19 1.60 36.6 *30.0Ave
Naphthalene 1.6901.214 2.23 1.60 39.2 *30.0Ave
Hexachlorobutadiene 1.7390.8864 3.14 1.60 96.2 *30.0Ave
1,2,3-Trichlorobenzene 1.0730.4732 3.63 1.60 126.7 *30.0Ave
2-Methylnaphthalene 0.80460.4946 2.60 1.60 62.7 *50.0Ave
1-Methylnaphthalene 1.0400.5473 3.04 1.60 90.1 *50.0Ave
4-Bromofluorobenzene (Surr)0.85920.7156 4.90 4.08 20.1 30.0Ave
FORM VII TO-15
3/25/2024
9:50:51 AM
Page 770 of 864
Report Date: 22-Mar-2024 13:48:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SCCVZC21.D
Lims ID:CCVIS
Client ID:
Sample Type:CCVIS
Inject. Date:21-Mar-2024 06:46:30 ALS Bottle#:11 Worklist Smp#:2
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0032009-002
Misc. Info.:P220 80 ML 663004
Operator ID:Instrument ID:MS
Sublist:chrom-MS_TO15A*sub2
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 13:48:45 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 13:48:45
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.915 9.915 0.000 77 226667 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.035 12.035 0.000 95 1082080 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.640 16.640 0.000 91 969868 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.248 18.248 0.000 94 850017 4.08 4.90
6 Chlorodifluoromethane 51 4.170 4.170 0.000 96 196279 1.60 1.91
7 Propene 41 4.186 4.186 0.000 94 68472 1.60 1.38
8 Dichlorodifluoromethane 85 4.245 4.245 0.000 100 382077 1.60 2.56
9 Chloromethane 52 4.466 4.466 0.000 50 28959 1.60 3.13
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.471 4.471 0.000 86 304481 1.60 3.24
11 Acetaldehyde 44 4.654 4.654 0.000 95 154300 8.00 14.6
12 Vinyl chloride 62 4.670 4.670 0.000 100 99137 1.60 3.32
13 Butadiene 54 4.773 4.773 0.000 77 69125 1.60 3.13
14 Butane 43 4.778 4.778 0.000 79 129932 1.60 3.25
15 Bromomethane 94 5.165 5.165 0.000 96 115551 1.60 3.56
16 Chloroethane 64 5.337 5.337 0.000 89 48851 1.60 3.75
17 Ethanol 31 5.434 5.434 0.000 96 141006 8.00 10.6
18 Vinyl bromide 106 5.692 5.692 0.000 93 93495 1.60 1.70
19 2-Methylbutane 43 5.741 5.741 0.000 88 83598 1.60 1.47
20 Trichlorofluoromethane 101 6.005 6.005 0.000 99 426399 1.60 2.51
21 Acrolein 56 6.010 6.010 0.000 96 22438 1.60 1.25
22 Acetonitrile 40 6.085 6.085 0.000 97 27236 1.60 1.27
23 Acetone 58 6.139 6.139 0.000 100 35928 1.60 1.53
24 Isopropyl alcohol 45 6.241 6.241 0.000 49 109938 1.60 1.53
25 Pentane 72 6.252 6.252 0.000 93 14119 1.60 1.52
26 Ethyl ether 31 6.440 6.440 0.000 91 66737 1.60 1.12
27 1,1-Dichloroethene 96 6.801 6.801 0.000 96 87779 1.60 1.46
28 Acrylonitrile 53 6.919 6.919 0.000 55 52878 1.60 1.38
29 2-Methyl-2-propanol 59 6.924 6.924 0.000 95 151497 1.60 1.50
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.989 6.989 0.000 91 249745 1.60 1.88
31 Methylene Chloride 84 7.188 7.188 0.000 95 79957 1.60 1.41
3/25/2024
9:50:51 AM
Page 771 of 864
Report Date: 22-Mar-2024 13:48:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SCCVZC21.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
32 3-Chloro-1-propene 39 7.204 7.204 0.000 88 86820 1.60 1.58
33 Carbon disulfide 76 7.382 7.382 0.000 96 235972 1.60 1.45
34 trans-1,2-Dichloroethene 96 8.065 8.065 0.000 96 89075 1.60 1.44
35 2-Methylpentane 43 8.081 8.081 0.000 89 140346 1.60 1.20
36 Methyl tert-butyl ether 73 8.189 8.189 0.000 94 269193 1.60 1.62
37 1,1-Dichloroethane 63 8.528 8.528 0.000 98 168048 1.60 1.57
38 Vinyl acetate 43 8.614 8.614 0.000 99 156031 1.60 1.22
39 2-Butanone (MEK) 72 9.092 9.092 0.000 97 35973 1.60 1.30
40 Hexane 56 9.114 9.114 0.000 86 65515 1.60 1.47
41 Isopropyl ether 45 9.275 9.275 0.000 88 232392 1.60 1.26
42 cis-1,2-Dichloroethene 96 9.566 9.566 0.000 94 93323 1.60 1.43
43 Ethyl acetate 43 9.727 9.727 0.000 98 157874 1.60 1.24
44 Chloroform 83 9.926 9.926 0.000 70 265179 1.60 2.03
45 Tert-butyl ethyl ether 59 9.985 9.985 0.000 96 253351 1.60 1.42
46 Tetrahydrofuran 42 10.319 10.319 0.000 88 72010 1.60 1.14
47 1,1,1-Trichloroethane 97 10.964 10.964 0.000 94 326532 1.60 2.20
48 1,2-Dichloroethane 62 11.067 11.067 0.000 98 184512 1.60 2.09
49 n-Butanol 31 11.454 11.454 0.000 88 20917 1.60 0.8688
50 Cyclohexane 69 11.535 11.535 0.000 64 42060 1.60 1.51
51 Benzene 78 11.535 11.535 0.000 97 277386 1.60 1.54
52 Carbon tetrachloride 117 11.556 11.556 0.000 97 394176 1.60 2.37
53 2,3-Dimethylpentane 71 11.621 11.621 0.000 87 54009 1.60 1.31
54 Thiophene 84 11.798 11.798 0.000 96 144704 1.60 1.35
55 Isooctane 57 12.234 12.234 0.000 95 372040 1.60 1.36
56 n-Heptane 71 12.584 12.584 0.000 84 79683 1.60 1.33
57 1,2-Dichloropropane 63 12.702 12.702 0.000 75 90678 1.60 1.37
58 Trichloroethene 130 12.729 12.729 0.000 93 158560 1.60 1.55
59 Dibromomethane 93 12.820 12.820 0.000 91 154638 1.60 1.84
60 Dichlorobromomethane 83 12.950 12.950 0.000 97 282867 1.60 2.03
61 1,4-Dioxane 88 12.950 12.950 0.000 34 34043 1.60 1.22
62 Methyl methacrylate 41 13.003 13.003 0.000 89 110483 1.60 1.36
63 Methylcyclohexane 83 13.471 13.471 0.000 92 192792 1.60 1.65
64 4-Methyl-2-pentanone (MIBK) 43 13.837 13.837 0.000 96 171316 1.60 1.24
65 cis-1,3-Dichloropropene 75 13.907 13.907 0.000 97 166913 1.60 1.56
66 trans-1,3-Dichloropropene 75 14.580 14.580 0.000 96 154212 1.60 1.56
67 Toluene 91 14.709 14.709 0.000 93 346317 1.60 1.47
68 1,1,2-Trichloroethane 83 14.779 14.779 0.000 93 101767 1.60 1.49
69 2-Hexanone 58 15.128 15.128 0.000 93 83409 1.60 1.18
70 n-Octane 85 15.338 15.338 0.000 82 104428 1.60 1.48
71 Chlorodibromomethane 129 15.478 15.478 0.000 96 315238 1.60 1.95
72 Ethylene Dibromide 107 15.768 15.768 0.000 96 208797 1.60 1.56
73 Tetrachloroethene 129 15.828 15.828 0.000 92 175792 1.60 1.79
74 2,3-Dimethylheptane 43 16.667 16.667 0.000 88 249395 1.60 1.31
75 Chlorobenzene 112 16.688 16.688 0.000 92 322026 1.60 1.62
76 Ethylbenzene 91 16.957 16.957 0.000 99 490614 1.60 1.57
77 m-Xylene & p-Xylene 91 17.113 17.113 0.000 99 903643 3.20 3.78
78 n-Nonane 57 17.490 17.490 0.000 81 186123 1.60 1.39
80 Styrene 104 17.576 17.576 0.000 97 282164 1.60 1.52
79 Bromoform 173 17.587 17.587 0.000 95 353753 1.60 1.93
81 o-Xylene 91 17.641 17.641 0.000 97 452723 1.60 1.67
82 1,1,2,2-Tetrachloroethane 83 17.958 17.958 0.000 95 260481 1.60 1.38
83 1,2,3-Trichloropropane 110 18.114 18.114 0.000 94 99210 1.60 1.66
3/25/2024
9:50:51 AM
Page 772 of 864
Report Date: 22-Mar-2024 13:48:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SCCVZC21.D
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
84 Isopropylbenzene 105 18.211 18.211 0.000 98 652495 1.60 1.61
85 N-Propylbenzene 120 18.738 18.738 0.000 99 166753 1.60 1.42
86 2-Chlorotoluene 126 18.792 18.792 0.000 97 167438 1.60 1.51
87 4-Ethyltoluene 105 18.878 18.878 0.000 98 632087 1.60 1.52
88 1,3,5-Trimethylbenzene 120 18.948 18.948 0.000 91 309224 1.60 1.71
89 Alpha Methyl Styrene 118 19.179 19.179 0.000 87 242438 1.60 1.36
90 n-Decane 57 19.206 19.206 0.000 96 295221 1.60 1.42
91 tert-Butylbenzene 119 19.373 19.373 0.000 90 674748 1.60 1.73
92 1,2,4-Trimethylbenzene 105 19.384 19.384 0.000 96 618989 1.60 1.78
93 sec-Butylbenzene 105 19.642 19.642 0.000 97 822779 1.60 1.58
94 1,3-Dichlorobenzene 146 19.669 19.669 0.000 98 418041 1.60 1.53
95 Benzyl chloride 91 19.739 19.739 0.000 97 400962 1.60 1.65
96 1,4-Dichlorobenzene 146 19.755 19.755 0.000 96 418532 1.60 1.56
97 4-Isopropyltoluene 119 19.792 19.792 0.000 96 784783 1.60 1.68
98 1,2,3-Trimethylbenzene 105 19.857 19.857 0.000 99 459063 1.60 1.29
99 Butylcyclohexane 83 19.900 19.900 0.000 91 365817 1.60 1.39
100 2,3-Dihydroindene 117 20.110 20.110 0.000 92 531465 1.60 1.52
101 1,2-Dichlorobenzene 146 20.115 20.115 0.000 95 423585 1.60 1.58
102 n-Butylbenzene 91 20.228 20.228 0.000 97 687591 1.60 1.65
103 Indene 116 20.239 20.239 0.000 92 383433 1.60 1.26
104 Undecane 57 20.513 20.513 0.000 91 329077 1.60 1.27
105 1,2-Dibromo-3-Chloropropane 157 20.734 20.734 0.000 97 170183 1.60 1.26
106 1,2,4,5-Tetramethylbenzene 119 21.019 21.019 0.000 96 691770 1.60 1.49
107 Dodecane 57 21.638 21.638 0.000 91 311148 1.60 1.42
108 1,2,4-Trichlorobenzene 180 21.847 21.847 0.000 94 338997 1.60 2.19
109 Naphthalene 128 21.960 21.960 0.000 98 655708 1.60 2.23
110 Hexachlorobutadiene 225 22.089 22.089 0.000 94 674629 1.60 3.14
111 1,2,3-Trichlorobenzene 180 22.149 22.149 0.000 94 416089 1.60 3.63
112 2-Methylnaphthalene 142 22.665 22.665 0.000 99 312163 1.60 2.60
113 1-Methylnaphthalene 142 22.794 22.794 0.000 98 403662 1.60 3.04
A 115 C8 Range 1 15.338 (15.290-15.386) 0 996718 1.60 1.66
S 116 Xylenes, Total 100 0 4.80 5.45
S 117 1,2-Dichloroethene, Total 1 0 3.20 2.88
T 141 2-Methylthiophene TIC 97 14.859 14.859 0.000 97 282589 1.60 1.17
T 142 3-Methylthiophene TIC 97 15.058 15.058 0.000 88 279663 1.60 1.15
T 144 2-Ethylthiophene TIC 97 17.065 17.065 0.000 58 391801 1.60 1.62
T 149 1,2-Dimethyl-4-Ethylbenzene TIC 119 20.605 20.605 0.000 93 553199 1.60 2.28
T 150 1,2,3,5-Tetramethylbenzene TIC 119 21.078 21.078 0.000 91 412457 1.60 1.70
T 151 1,2,3,4-Tetramethylbenzene TIC 119 21.519 21.519 0.000 93 510840 1.60 2.11
T 152 Benzo(b)thiophene TIC 134 22.030 22.030 0.000 87 313108 1.60 1.29
QC Flag Legend
Processing Flags
Reagents:
40CV101S_00252 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 773 of 864
Report Date: 22-Mar-2024 13:48:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SCCVZC21.D
Injection Date:21-Mar-2024 06:46:30 Instrument ID:MS Operator ID:
Lims ID:CCVIS Worklist Smp#:2
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:11
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
44
Y ( X10
0
0
0
0
)
SCCVZC21[MS SCAN Chro]:Total
* C
h
l
o
r
o
b
r
o
m
o
m
e
t
h
a
n
e

(IS
)(

9
.
9
1
5
)
* 1
,4-
D
i
f
l
u
o
r
o
b
e
n
zen
e
( 1
2
.
0
3
5
)
* C
h
l
o
r
o
b
e
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zen
e
-
d5
(IS
)(
1
6
.
6
4
0
)
$ 4
-
Bro
m
o
f
l
u
o
r
o
b
e
n
zen
e

(Su
r
r
)(
1
8
.
2
4
8
)
3/25/2024
9:50:51 AM
Page 774 of 864
Report Date: 06-Mar-2024 12:39:48 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05BFB.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:05-Mar-2024 13:59:30 ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Sample Info:140-0031853-001
Misc. Info.:BFBz
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:06-Mar-2024 12:39:47 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1677
First Level Reviewer: U3SA Date:06-Mar-2024 12:39:47
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
$ 5 BFB 95 6.642 6.642 0.000 0 577420 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
40MXBFB_00004 Amount Added: 40.00 Units: mL
3/25/2024
9:50:51 AM
Page 775 of 864
Report Date: 06-Mar-2024 12:39:48 Chrom Revision: 2.3 23-Feb-2024 16:51:14
MS Tune Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05BFB.D
Injection Date:05-Mar-2024 13:59:30 Instrument ID:MR
Lims ID:BFB
Client ID:
Operator ID:ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Tune Method: BFB Method 8260
$ 5 BFB
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
m/z
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
0
0
)
Tune Spec :Average 1066-1068( 6.64-6.64 ) Bgrd 1051( 6.60)
95
174
75
50 74
9468
965137
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 20.3
75 30 to 60%of m/z 95 51.3
96 5 to 9%of m/z 95 7.0
173 Less than 2%of m/z 174 0.8 (1.1)
174 50 to 120%of m/z 95 79.7
175 5 to 9%of m/z 174 6.1 (7.6)
176 Greater than 95%but less than 101%of m/z 174 77.2 (96.8)
177 5 to 9%of m/z 176 5.0 (6.5)
3/25/2024
9:50:51 AM
Page 776 of 864
Report Date: 06-Mar-2024 12:39:48 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05BFB.D\MR_TO15.rslt\spectra.d
Injection Date:05-Mar-2024 13:59:30
Spectrum:Tune Spec :Average 1066-1068( 6.64-6.64 ) Bgrd 1051( 6.60)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:118
m/z Y m/z Y m/z Y m/z Y
29.00 130 65.00 333 103.00 181 143.00 3362
30.00 34 66.00 79 104.00 1862 144.00 196
31.00 12218 67.00 1096 105.00 375 145.00 295
32.00 1222 68.00 39512 106.00 1705 146.00 562
33.00 3903 69.00 39168 107.00 407 147.00 228
36.00 3849 70.00 3217 110.00 314 148.00 872
37.00 20504 71.00 144 111.00 388 149.00 199
38.00 18352 72.00 2271 112.00 266 150.00 412
39.00 6701 73.00 17224 113.00 399 152.00 148
40.00 270 74.00 65152 115.00 504 153.00 254
42.00 37 75.00 188864 116.00 1479 154.00 140
43.00 249 76.00 16189 117.00 2270 155.00 864
44.00 2814 77.00 2136 118.00 1302 156.00 265
45.00 3440 78.00 1592 119.00 2060 157.00 601
46.00 360 79.00 14796 123.00 37 158.00 121
47.00 4172 80.00 4213 124.00 224 159.00 325
48.00 2512 81.00 15158 125.00 143 161.00 335
49.00 16210 82.00 3437 126.00 115 168.00 39
50.00 74640 83.00 314 128.00 1282 169.00 33
51.00 22808 86.00 426 129.00 578 170.00 93
52.00 1086 87.00 15630 130.00 1453 171.00 195
55.00 1058 88.00 15096 131.00 505 172.00 314
56.00 6825 91.00 1706 134.00 39 173.00 3098
57.00 11319 92.00 10289 135.00 678 174.00 293376
58.00 546 93.00 15676 136.00 49 175.00 22408
60.00 3657 94.00 43544 137.00 657 176.00 284096
61.00 18488 95.00 368192 139.00 43 177.00 18568
62.00 18288 96.00 25776 140.00 278 178.00 629
63.00 14567 97.00 699 141.00 3134
64.00 1327 103.00 47 142.00 437
3/25/2024
9:50:51 AM
Page 777 of 864
Report Date: 06-Mar-2024 12:39:48 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05BFB.D
Injection Date:05-Mar-2024 13:59:30 Instrument ID:MR Operator ID:
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.5 3.8 4.1 4.4 4.7 5.0 5.3 5.6 5.9 6.2 6.5 6.8 7.1 7.4 7.7 8.0 8.3 8.6 8.9 9.2 9.5
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
Y ( X10
0
0
0
0
)
RZC05BFB[MS SCAN Chro]:Total
$ B
F
B
(
6
.
6
4
2
)
3/25/2024
9:50:51 AM
Page 778 of 864
Report Date: 20-Mar-2024 14:47:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RBFBZC19.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:19-Mar-2024 07:09:30 ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Sample Info:140-0031988-001
Misc. Info.:BFBZ
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 14:47:45 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 14:47:45
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
$ 5 BFB 95 6.642 6.642 0.000 0 666217 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
40MXBFB_00004 Amount Added: 40.00 Units: mL
3/25/2024
9:50:51 AM
Page 779 of 864
Report Date: 20-Mar-2024 14:47:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
MS Tune Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RBFBZC19.D
Injection Date:19-Mar-2024 07:09:30 Instrument ID:MR
Lims ID:BFB
Client ID:
Operator ID:ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Tune Method: BFB Method 8260
$ 5 BFB
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
m/z
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
0
0
)
Tune Spec :Average 1066-1068( 6.64-6.64 ) Bgrd 1051( 6.60)
95
174
75
50 74
9468
965137
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 19.9
75 30 to 60%of m/z 95 51.4
96 5 to 9%of m/z 95 6.6
173 Less than 2%of m/z 174 0.8 (1.1)
174 50 to 120%of m/z 95 74.4
175 5 to 9%of m/z 174 5.6 (7.5)
176 Greater than 95%but less than 101%of m/z 174 72.4 (97.3)
177 5 to 9%of m/z 176 4.6 (6.3)
3/25/2024
9:50:51 AM
Page 780 of 864
Report Date: 20-Mar-2024 14:47:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RBFBZC19.D\MR_TO15.rslt\spectra.d
Injection Date:19-Mar-2024 07:09:30
Spectrum:Tune Spec :Average 1066-1068( 6.64-6.64 ) Bgrd 1051( 6.60)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:115
m/z Y m/z Y m/z Y m/z Y
29.00 133 64.00 1276 103.00 176 141.00 3484
30.00 34 65.00 390 104.00 1907 142.00 471
31.00 11959 67.00 1096 105.00 585 143.00 3811
32.00 1078 68.00 45648 106.00 1720 144.00 166
33.00 3241 69.00 45704 107.00 428 145.00 421
36.00 3830 70.00 3426 110.00 261 146.00 569
37.00 22128 71.00 149 111.00 354 147.00 186
38.00 19128 72.00 2133 112.00 281 148.00 900
39.00 6798 73.00 19848 113.00 312 149.00 324
40.00 206 74.00 73816 115.00 500 150.00 391
43.00 282 75.00 219712 116.00 1336 152.00 179
44.00 2757 76.00 18744 117.00 2440 153.00 276
45.00 3814 77.00 2282 118.00 1533 154.00 191
46.00 308 78.00 1621 119.00 2038 155.00 1041
47.00 5286 79.00 13980 122.00 43 156.00 110
48.00 2928 80.00 4032 123.00 146 157.00 675
49.00 18944 81.00 14124 124.00 242 159.00 390
50.00 85304 82.00 3378 125.00 52 161.00 455
51.00 26864 83.00 332 126.00 147 170.00 37
52.00 1198 86.00 441 127.00 65 170.00 101
55.00 1060 87.00 17272 128.00 1261 171.00 151
56.00 6777 88.00 16704 129.00 776 172.00 651
57.00 12682 91.00 1676 130.00 1313 173.00 3450
58.00 505 92.00 11794 131.00 633 174.00 318400
59.00 35 93.00 17696 135.00 629 175.00 23856
60.00 3928 94.00 48024 136.00 73 176.00 309760
61.00 20512 95.00 427776 137.00 710 177.00 19496
62.00 20384 96.00 28320 139.00 136 178.00 530
63.00 15752 97.00 923 140.00 199
3/25/2024
9:50:51 AM
Page 781 of 864
Report Date: 20-Mar-2024 14:47:45 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RBFBZC19.D
Injection Date:19-Mar-2024 07:09:30 Instrument ID:MR Operator ID:
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.5 3.8 4.1 4.4 4.7 5.0 5.3 5.6 5.9 6.2 6.5 6.8 7.1 7.4 7.7 8.0 8.3 8.6 8.9 9.2 9.5
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
Y ( X10
0
0
0
0
)
RBFBZC19[MS SCAN Chro]:Total
$ B
F
B
(
6
.
6
4
2
)
3/25/2024
9:50:51 AM
Page 782 of 864
Report Date: 21-Mar-2024 15:01:24 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RBFBZC20.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:20-Mar-2024 06:37:30 ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Sample Info:140-0031995-001
Misc. Info.:BFBZ
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 15:01:24 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1634
First Level Reviewer: CJS9 Date:21-Mar-2024 15:01:24
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
$ 5 BFB 95 6.651 6.651 0.000 0 671994 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
40MXBFB_00004 Amount Added: 40.00 Units: mL
3/25/2024
9:50:51 AM
Page 783 of 864
Report Date: 21-Mar-2024 15:01:24 Chrom Revision: 2.3 23-Feb-2024 16:51:14
MS Tune Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RBFBZC20.D
Injection Date:20-Mar-2024 06:37:30 Instrument ID:MR
Lims ID:BFB
Client ID:
Operator ID:ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Tune Method: BFB Method 8260
$ 5 BFB
20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
m/z
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
0
0
)
Tune Spec :Average 1069-1071( 6.65-6.65 ) Bgrd 1054( 6.60)
95
174
75
50
74
9468
965137
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 20.3
75 30 to 60%of m/z 95 50.4
96 5 to 9%of m/z 95 6.6
173 Less than 2%of m/z 174 0.7 (0.9)
174 50 to 120%of m/z 95 78.4
175 5 to 9%of m/z 174 5.6 (7.2)
176 Greater than 95%but less than 101%of m/z 174 75.1 (95.8)
177 5 to 9%of m/z 176 5.0 (6.6)
3/25/2024
9:50:51 AM
Page 784 of 864
Report Date: 21-Mar-2024 15:01:24 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RBFBZC20.D\MR_TO15.rslt\spectra.d
Injection Date:20-Mar-2024 06:37:30
Spectrum:Tune Spec :Average 1069-1071( 6.65-6.65 ) Bgrd 1054( 6.60)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:121
m/z Y m/z Y m/z Y m/z Y
29.00 102 65.00 375 105.00 511 142.00 367
30.00 37 66.00 52 106.00 1987 143.00 3594
31.00 13149 67.00 1110 107.00 447 144.00 217
32.00 1108 68.00 44752 110.00 260 145.00 314
33.00 3587 69.00 44344 111.00 340 146.00 548
36.00 4021 70.00 3612 112.00 252 147.00 243
37.00 22512 71.00 109 113.00 266 148.00 855
38.00 20304 72.00 2185 115.00 404 149.00 316
39.00 7277 73.00 18944 116.00 1348 150.00 335
40.00 314 74.00 73280 117.00 2455 152.00 176
43.00 236 75.00 213888 118.00 1428 153.00 337
44.00 2855 76.00 18008 119.00 2144 154.00 221
45.00 4084 77.00 2648 122.00 118 155.00 1003
46.00 377 78.00 1678 123.00 86 156.00 189
47.00 5234 79.00 14377 124.00 241 157.00 660
48.00 2706 80.00 4224 125.00 43 158.00 93
49.00 18768 81.00 14804 126.00 163 159.00 391
50.00 86216 82.00 3491 127.00 169 161.00 383
51.00 25648 83.00 399 128.00 1408 169.00 36
52.00 1085 86.00 460 129.00 582 170.00 175
53.00 44 87.00 18280 130.00 1276 171.00 168
55.00 1252 88.00 16832 131.00 569 172.00 975
56.00 7447 91.00 1491 132.00 37 173.00 3129
57.00 12290 92.00 11933 134.00 69 174.00 332544
58.00 463 93.00 16872 134.00 79 175.00 23912
59.00 81 94.00 47888 135.00 717 176.00 318656
60.00 4157 95.00 424064 136.00 100 177.00 21048
61.00 21128 96.00 27896 137.00 693 178.00 510
62.00 20512 97.00 682 139.00 153
63.00 16021 103.00 193 140.00 247
64.00 1379 104.00 1913 141.00 3544
3/25/2024
9:50:51 AM
Page 785 of 864
Report Date: 21-Mar-2024 15:01:24 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RBFBZC20.D
Injection Date:20-Mar-2024 06:37:30 Instrument ID:MR Operator ID:
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.5 3.8 4.1 4.4 4.7 5.0 5.3 5.6 5.9 6.2 6.5 6.8 7.1 7.4 7.7 8.0 8.3 8.6 8.9 9.2 9.5
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
Y ( X10
0
0
0
0
)
RBFBZC20[MS SCAN Chro]:Total
$ B
F
B
(
6
.
6
5
1
)
3/25/2024
9:50:51 AM
Page 786 of 864
Report Date: 10-Feb-2024 14:47:32 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZBFBB07.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:07-Feb-2024 14:06:30 ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Sample Info:140-0031497-001
Misc. Info.:BFB
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:10-Feb-2024 14:47:32 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1608
First Level Reviewer: T5MR Date:10-Feb-2024 14:47:32
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
$ 5 BFB 95 5.160 5.160 0.000 0 1133135 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
40MXBFB_00004 Amount Added: 40.00 Units: mL
3/25/2024
9:50:51 AM
Page 787 of 864
Report Date: 10-Feb-2024 14:47:32 Chrom Revision: 2.3 02-Feb-2024 10:24:08
MS Tune Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZBFBB07.D
Injection Date:07-Feb-2024 14:06:30 Instrument ID:MS
Lims ID:BFB
Client ID:
Operator ID:ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Tune Method: BFB Method 8260
$ 5 BFB
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210
m/z
0
5
10
15
20
25
30
35
40
45
50
55
60
65
Y ( X10
0
0
0
)
Tune Spec :Average 311-313( 5.15-5.17 ) Bgrd 303( 5.11)
174 176
95
75
50 74
94
17796
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 16.7
75 30 to 60%of m/z 95 45.8
96 5 to 9%of m/z 95 6.7
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 108.2
175 5 to 9%of m/z 174 7.7 (7.2)
176 Greater than 95%but less than 101%of m/z 174 106.1 (98.1)
177 5 to 9%of m/z 176 7.0 (6.6)
3/25/2024
9:50:51 AM
Page 788 of 864
Report Date: 10-Feb-2024 14:47:32 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZBFBB07.D\MS_TO15A.rslt\spectra.d
Injection Date:07-Feb-2024 14:06:30
Spectrum:Tune Spec :Average 311-313( 5.15-5.17 ) Bgrd 303( 5.11)
Base Peak:174.00
Minimum % Base Peak:0
Number of Points:130
m/z Y m/z Y m/z Y m/z Y
31.00 13128 68.00 57536 108.00 124 144.00 444
32.00 154 69.00 57240 109.00 67 145.00 738
33.00 2967 70.00 4382 110.00 138 146.00 1036
34.00 55 72.00 2738 111.00 668 147.00 360
36.00 4506 73.00 23200 112.00 299 148.00 1369
37.00 23736 74.00 94760 113.00 676 149.00 467
38.00 21616 75.00 284352 115.00 635 150.00 802
39.00 8621 76.00 24144 116.00 2442 152.00 500
40.00 439 77.00 2696 117.00 4238 153.00 579
43.00 39 78.00 1889 118.00 2678 154.00 599
44.00 2062 79.00 16760 119.00 3430 155.00 1808
45.00 4398 80.00 5564 120.00 76 156.00 388
46.00 421 81.00 16576 122.00 238 157.00 1254
47.00 6205 82.00 4191 123.00 277 158.00 189
48.00 2765 83.00 382 124.00 512 159.00 930
49.00 20552 84.00 32 125.00 264 161.00 872
50.00 103872 85.00 39 126.00 230 162.00 63
51.00 31456 86.00 386 127.00 182 163.00 63
52.00 1400 87.00 22608 128.00 2366 165.00 58
53.00 27 88.00 22208 129.00 1133 172.00 151
55.00 1215 91.00 1854 130.00 2584 174.00 671616
56.00 7310 92.00 16640 131.00 1145 175.00 48048
57.00 14282 93.00 25168 132.00 121 176.00 658624
58.00 735 94.00 69616 134.00 268 177.00 43416
59.00 54 95.00 620480 135.00 1261 178.00 1278
60.00 4602 96.00 41632 136.00 280 179.00 188
61.00 23064 97.00 1037 137.00 1343 191.00 12
62.00 23712 98.00 15 138.00 74 193.00 23
63.00 18400 103.00 185 139.00 282 207.00 54
64.00 1800 104.00 2496 140.00 556 208.00 53
65.00 140 105.00 765 141.00 7220 210.00 53
66.00 142 106.00 2753 142.00 820
67.00 775 107.00 757 143.00 7732
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Page 789 of 864
Report Date: 10-Feb-2024 14:47:32 Chrom Revision: 2.3 02-Feb-2024 10:24:08
m/z Y m/z Y m/z Y m/z Y
31.00 13128 68.00 57536 108.00 124 144.00 444
32.00 154 69.00 57240 109.00 67 145.00 738
33.00 2967 70.00 4382 110.00 138 146.00 1036
34.00 55 72.00 2738 111.00 668 147.00 360
36.00 4506 73.00 23200 112.00 299 148.00 1369
37.00 23736 74.00 94760 113.00 676 149.00 467
38.00 21616 75.00 284352 115.00 635 150.00 802
39.00 8621 76.00 24144 116.00 2442 152.00 500
40.00 439 77.00 2696 117.00 4238 153.00 579
43.00 39 78.00 1889 118.00 2678 154.00 599
44.00 2062 79.00 16760 119.00 3430 155.00 1808
45.00 4398 80.00 5564 120.00 76 156.00 388
46.00 421 81.00 16576 122.00 238 157.00 1254
47.00 6205 82.00 4191 123.00 277 158.00 189
48.00 2765 83.00 382 124.00 512 159.00 930
49.00 20552 84.00 32 125.00 264 161.00 872
50.00 103872 85.00 39 126.00 230 162.00 63
51.00 31456 86.00 386 127.00 182 163.00 63
52.00 1400 87.00 22608 128.00 2366 165.00 58
53.00 27 88.00 22208 129.00 1133 172.00 151
55.00 1215 91.00 1854 130.00 2584 174.00 671616
56.00 7310 92.00 16640 131.00 1145 175.00 48048
57.00 14282 93.00 25168 132.00 121 176.00 658624
58.00 735 94.00 69616 134.00 268 177.00 43416
59.00 54 95.00 620480 135.00 1261 178.00 1278
60.00 4602 96.00 41632 136.00 280 179.00 188
61.00 23064 97.00 1037 137.00 1343 191.00 12
62.00 23712 98.00 15 138.00 74 193.00 23
63.00 18400 103.00 185 139.00 282 207.00 54
64.00 1800 104.00 2496 140.00 556 208.00 53
65.00 140 105.00 765 141.00 7220 210.00 53
66.00 142 106.00 2753 142.00 820
67.00 775 107.00 757 143.00 7732
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Report Date: 10-Feb-2024 14:47:32 Chrom Revision: 2.3 02-Feb-2024 10:24:08
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZBFBB07.D
Injection Date:07-Feb-2024 14:06:30 Instrument ID:MS Operator ID:
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.4 3.7 4.0 4.3 4.6 4.9 5.2 5.5 5.8 6.1 6.4
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
Y ( X10
0
0
0
0
)
SZBFBB07[MS SCAN Chro]:Total
$ B
F
B
(
5
.
1
6
0
)
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Report Date: 22-Mar-2024 13:45:28 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SBFBZC21.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:21-Mar-2024 06:18:30 ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Sample Info:140-0032009-001
Misc. Info.:BFBz
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 13:45:28 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 13:45:28
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
$ 5 BFB 95 5.160 5.160 0.000 0 928128 NR NR 8
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
8 - Failed MS Tune Ratio Test
Reagents:
40MXBFB_00004 Amount Added: 40.00 Units: mL
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Page 792 of 864
Report Date: 22-Mar-2024 13:45:28 Chrom Revision: 2.3 23-Feb-2024 16:51:14
MS Tune Report
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SBFBZC21.D
Injection Date:21-Mar-2024 06:18:30 Instrument ID:MS
Lims ID:BFB
Client ID:
Operator ID:ALS Bottle#:16 Worklist Smp#:1
Injection Vol:500.0 mL Dil. Factor:1.0000
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Tune Method: BFB Method 8260
$ 5 BFB
20 40 60 80 100 120 140 160 180 200 220 240 260
m/z
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X10
0
0
0
)
Tune Spec :Average 311-313( 5.16-5.17 ) Bgrd 303( 5.11)
95 174 176
75
7450
9468
79 96 17737
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 21.1
75 30 to 60%of m/z 95 60.4*
96 5 to 9%of m/z 95 6.6
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 99.1
175 5 to 9%of m/z 174 7.2 (7.3)
176 Greater than 95%but less than 101%of m/z 174 97.2 (98.0)
177 5 to 9%of m/z 176 6.4 (6.6)
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Report Date: 22-Mar-2024 13:45:28 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SBFBZC21.D\MS_TO15A.rslt\spectra.d
Injection Date:21-Mar-2024 06:18:30
Spectrum:Tune Spec :Average 311-313( 5.16-5.17 ) Bgrd 303( 5.11)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:140
m/z Y m/z Y m/z Y m/z Y
29.00 532 70.00 5296 115.00 1161 151.00 103
31.00 16172 71.00 240 116.00 3754 152.00 326
32.00 1369 72.00 3303 117.00 6248 153.00 372
33.00 7147 73.00 28568 118.00 3621 154.00 578
36.00 4353 74.00 113616 119.00 5292 155.00 2174
37.00 26768 75.00 313216 120.00 195 156.00 176
38.00 24312 76.00 26256 122.00 369 157.00 1573
39.00 9104 77.00 2362 123.00 297 158.00 108
40.00 165 79.00 34784 124.00 486 159.00 1183
42.00 74 80.00 10896 125.00 333 160.00 81
43.00 546 81.00 34696 126.00 264 161.00 1185
44.00 4040 82.00 8495 127.00 231 162.00 76
45.00 4755 83.00 879 128.00 3156 163.00 58
46.00 664 84.00 131 129.00 1529 165.00 110
47.00 3745 85.00 109 130.00 2872 171.00 67
48.00 3439 86.00 491 131.00 1234 171.00 65
49.00 23920 87.00 13558 132.00 142 172.00 2974
50.00 109424 88.00 13122 133.00 229 174.00 514432
51.00 30832 91.00 3899 134.00 298 175.00 37320
52.00 1299 92.00 20960 135.00 2273 176.00 504320
53.00 306 93.00 31112 136.00 504 177.00 33248
55.00 1963 94.00 76640 137.00 2005 178.00 1016
56.00 10786 95.00 518912 138.00 122 179.00 139
57.00 18256 96.00 34464 139.00 186 190.00 59
58.00 806 97.00 1037 140.00 850 193.00 331
60.00 5556 103.00 398 141.00 12127 196.00 56
61.00 30312 104.00 4392 142.00 906 197.00 190
62.00 29600 105.00 1325 143.00 13055 204.00 60
63.00 26504 106.00 5007 144.00 784 205.00 85
64.00 2681 107.00 794 145.00 1325 208.00 81
65.00 2194 108.00 51 146.00 1094 220.00 50
66.00 231 110.00 1011 147.00 704 239.00 97
67.00 542 111.00 1300 148.00 1770 249.00 74
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Report Date: 22-Mar-2024 13:45:28 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SBFBZC21.D\MS_TO15A.rslt\spectra.d
Injection Date:21-Mar-2024 06:18:30
Spectrum:Tune Spec :Average 311-313( 5.16-5.17 ) Bgrd 303( 5.11)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:140
m/z Y m/z Y m/z Y m/z Y
68.00 64464 112.00 953 149.00 554 252.00 57
69.00 61680 113.00 1261 150.00 665 255.00 71
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Page 795 of 864
Report Date: 22-Mar-2024 13:45:28 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SBFBZC21.D
Injection Date:21-Mar-2024 06:18:30 Instrument ID:MS Operator ID:
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.4 3.7 4.0 4.3 4.6 4.9 5.2 5.5 5.8 6.1 6.4
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
Y ( X10
0
0
0
0
)
SBFBZC21[MS SCAN Chro]:Total
$ B
F
B
(
5
.
1
6
0
)
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Page 796 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84584/5
Matrix:RZC19MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/19/2024 09:44
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane ND 0.20 0.072
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 0.20 0.035
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
ND 0.20 0.024
133.4179-00-5 1,1,2-Trichloroethane ND 0.20 0.038
98.9675-34-3 1,1-Dichloroethane ND 0.20 0.027
96.9475-35-4 1,1-Dichloroethene ND 0.20 0.032
120.19526-73-8 1,2,3-Trimethylbenzene ND 0.20 0.090
181.45120-82-1 1,2,4-Trichlorobenzene ND 1.0 0.089
120.2095-63-6 1,2,4-Trimethylbenzene ND 0.20 0.050
187.87106-93-4 1,2-Dibromoethane (EDB)ND 0.20 0.031
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 0.20 0.030
147.0095-50-1 1,2-Dichlorobenzene ND 0.40 0.078
98.96107-06-2 1,2-Dichloroethane ND 0.20 0.025
112.9978-87-5 1,2-Dichloropropane ND 0.20 0.025
120.20108-67-8 1,3,5-Trimethylbenzene ND 0.40 0.16
54.09106-99-0 1,3-Butadiene ND 0.40 0.048
147.00541-73-1 1,3-Dichlorobenzene ND 0.20 0.040
147.00106-46-7 1,4-Dichlorobenzene ND 0.20 0.040
72.1178-93-3 2-Butanone (MEK)ND 1.0 0.18
100.20591-78-6 2-Hexanone ND 0.50 0.14
120.20622-96-8 4-Ethyltoluene ND 0.40 0.053
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
ND 1.0 0.14
78.1171-43-2 Benzene ND 0.20 0.033
126.58100-44-7 Benzyl chloride ND 0.40 0.095
163.8375-27-4 Bromodichloromethane ND 0.20 0.044
252.7575-25-2 Bromoform ND 0.20 0.066
94.9474-83-9 Bromomethane ND 0.20 0.055
76.1475-15-0 Carbon disulfide ND 0.40 0.087
153.8156-23-5 Carbon tetrachloride ND 0.20 0.032
112.56108-90-7 Chlorobenzene ND 0.20 0.056
64.5275-00-3 Chloroethane ND 0.20 0.079
119.3867-66-3 Chloroform ND 0.20 0.036
FORM I TO-15
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9:50:51 AM
Page 797 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84584/5
Matrix:RZC19MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/19/2024 09:44
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 1.0 0.16
96.94156-59-2 cis-1,2-Dichloroethene ND 0.20 0.025
110.9710061-01-5 cis-1,3-Dichloropropene ND 0.40 0.048
84.16110-82-7 Cyclohexane ND 0.40 0.093
208.28124-48-1 Dibromochloromethane ND 0.20 0.034
120.9175-71-8 Dichlorodifluoromethane ND 0.20 0.035
46.0764-17-5 Ethanol ND 5.0 2.2
88.11141-78-6 Ethyl acetate ND 2.0 0.15
106.17100-41-4 Ethylbenzene ND 0.20 0.033
260.7687-68-3 Hexachlorobutadiene ND 1.0 0.080
88.151634-04-4 Methyl tert-butyl ether ND 1.0 0.13
98.19108-87-2 Methylcyclohexane ND 0.20 0.050
84.9375-09-2 Methylene Chloride ND 1.0 0.34
106.17179601-23-1 m-Xylene & p-Xylene ND 0.20 0.073
100.21142-82-5 n-Heptane ND 0.40 0.035
86.17110-54-3 n-Hexane ND 0.40 0.063
128.26111-84-2 Nonane ND 0.40 0.11
106.1795-47-6 o-Xylene ND 0.20 0.038
104.15100-42-5 Styrene ND 0.20 0.060
165.83127-18-4 Tetrachloroethene ND 0.20 0.029
72.11109-99-9 Tetrahydrofuran ND 1.0 0.18
92.14108-88-3 Toluene ND 1.0 0.057
96.94156-60-5 trans-1,2-Dichloroethene ND 0.20 0.033
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 0.20 0.049
131.3979-01-6 Trichloroethene ND 0.20 0.033
137.3775-69-4 Trichlorofluoromethane ND 0.20 0.028
86.09108-05-4 Vinyl acetate ND 1.0 0.070
62.5075-01-4 Vinyl chloride ND 0.40 0.065
%RECCAS NO.LIMITSQSURROGATE
99 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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9:50:51 AM
Page 798 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84584/5
Matrix:RZC19MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/19/2024 09:44
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane ND 1.1 0.39
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
ND 1.4 0.24
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
ND 1.5 0.18
133.4179-00-5 1,1,2-Trichloroethane ND 1.1 0.21
98.9675-34-3 1,1-Dichloroethane ND 0.81 0.11
96.9475-35-4 1,1-Dichloroethene ND 0.79 0.13
120.19526-73-8 1,2,3-Trimethylbenzene ND 0.98 0.44
181.45120-82-1 1,2,4-Trichlorobenzene ND 7.4 0.66
120.2095-63-6 1,2,4-Trimethylbenzene ND 0.98 0.25
187.87106-93-4 1,2-Dibromoethane (EDB)ND 1.5 0.24
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
ND 1.4 0.21
147.0095-50-1 1,2-Dichlorobenzene ND 2.4 0.47
98.96107-06-2 1,2-Dichloroethane ND 0.81 0.10
112.9978-87-5 1,2-Dichloropropane ND 0.92 0.12
120.20108-67-8 1,3,5-Trimethylbenzene ND 2.0 0.79
54.09106-99-0 1,3-Butadiene ND 0.88 0.11
147.00541-73-1 1,3-Dichlorobenzene ND 1.2 0.24
147.00106-46-7 1,4-Dichlorobenzene ND 1.2 0.24
72.1178-93-3 2-Butanone (MEK)ND 2.9 0.53
100.20591-78-6 2-Hexanone ND 2.0 0.57
120.20622-96-8 4-Ethyltoluene ND 2.0 0.26
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
ND 4.1 0.57
78.1171-43-2 Benzene ND 0.64 0.11
126.58100-44-7 Benzyl chloride ND 2.1 0.49
163.8375-27-4 Bromodichloromethane ND 1.3 0.29
252.7575-25-2 Bromoform ND 2.1 0.68
94.9474-83-9 Bromomethane ND 0.78 0.21
76.1475-15-0 Carbon disulfide ND 1.2 0.27
153.8156-23-5 Carbon tetrachloride ND 1.3 0.20
112.56108-90-7 Chlorobenzene ND 0.92 0.26
64.5275-00-3 Chloroethane ND 0.53 0.21
119.3867-66-3 Chloroform ND 0.98 0.18
FORM I TO-15
3/25/2024
9:50:51 AM
Page 799 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84584/5
Matrix:RZC19MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/19/2024 09:44
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane ND 2.1 0.33
96.94156-59-2 cis-1,2-Dichloroethene ND 0.79 0.099
110.9710061-01-5 cis-1,3-Dichloropropene ND 1.8 0.22
84.16110-82-7 Cyclohexane ND 1.4 0.32
208.28124-48-1 Dibromochloromethane ND 1.7 0.29
120.9175-71-8 Dichlorodifluoromethane ND 0.99 0.17
46.0764-17-5 Ethanol ND 9.4 4.1
88.11141-78-6 Ethyl acetate ND 7.2 0.54
106.17100-41-4 Ethylbenzene ND 0.87 0.14
260.7687-68-3 Hexachlorobutadiene ND 11 0.85
88.151634-04-4 Methyl tert-butyl ether ND 3.6 0.47
98.19108-87-2 Methylcyclohexane ND 0.80 0.20
84.9375-09-2 Methylene Chloride ND 3.5 1.2
106.17179601-23-1 m-Xylene & p-Xylene ND 0.87 0.32
100.21142-82-5 n-Heptane ND 1.6 0.14
86.17110-54-3 n-Hexane ND 1.4 0.22
128.26111-84-2 Nonane ND 2.1 0.58
106.1795-47-6 o-Xylene ND 0.87 0.17
104.15100-42-5 Styrene ND 0.85 0.26
165.83127-18-4 Tetrachloroethene ND 1.4 0.20
72.11109-99-9 Tetrahydrofuran ND 2.9 0.53
92.14108-88-3 Toluene ND 3.8 0.21
96.94156-60-5 trans-1,2-Dichloroethene ND 0.79 0.13
110.9710061-02-6 trans-1,3-Dichloropropen
e
ND 0.91 0.22
131.3979-01-6 Trichloroethene ND 1.1 0.18
137.3775-69-4 Trichlorofluoromethane ND 1.1 0.16
86.09108-05-4 Vinyl acetate ND 3.5 0.25
62.5075-01-4 Vinyl chloride ND 1.0 0.17
%RECCAS NO.LIMITSQSURROGATE
99 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 800 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84584/5
Matrix:RZC19MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/19/2024 09:44
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
Number TICs Found:TIC Result Total:00
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
Tentatively Identified Compound None
FORM I-TIC TO-15
3/25/2024
9:50:51 AM
Page 801 of 864
Report Date: 20-Mar-2024 15:03:20 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19MBA.D
Lims ID:mb
Client ID:
Sample Type:MB
Inject. Date:19-Mar-2024 09:44:30 ALS Bottle#:16 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031988-004
Misc. Info.:MB500.200
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:03:14 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:03:20
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.364 0.010 87 242777 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.553 0.005 95 1080236 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.438 16.433 0.005 87 1081984 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.078 0.000 87 797842 4.08 4.03
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 802 of 864
Report Date: 20-Mar-2024 15:03:20 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19MBA.D
Injection Date:19-Mar-2024 09:44:30 Instrument ID:MR Operator ID:
Lims ID:mb Worklist Smp#:5
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:16
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Y ( X10
0
0
0
0
)
RZC19MBA[MS SCAN Chro]:Total
* C
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3/25/2024
9:50:51 AM
Page 803 of 864
Report Date: 20-Mar-2024 15:03:20 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\RZC19MBA.D
Lims ID:mb
Client ID:
Sample Type:MB
Inject. Date:19-Mar-2024 09:44:30 ALS Bottle#:16 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031988-004
Misc. Info.:MB500.200
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 15:03:14 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 15:03:20
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.03 98.88
3/25/2024
9:50:51 AM
Page 804 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84603/6
Matrix:RZC20BLK35930A2B.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/20/2024 08:52
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone ND 7.5 1.4
60.1067-63-0 Isopropyl alcohol ND 2.0 0.24
%RECCAS NO.LIMITSQSURROGATE
95 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 805 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84603/6
Matrix:RZC20BLK35930A2B.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/20/2024 08:52
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone ND 18 3.3
60.1067-63-0 Isopropyl alcohol ND 4.9 0.59
%RECCAS NO.LIMITSQSURROGATE
95 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 806 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84603/6
Matrix:RZC20BLK35930A2B.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/20/2024 08:52
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ppb v/vUnits:
Number TICs Found:TIC Result Total:00
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
Tentatively Identified Compound None
FORM I-TIC TO-15
3/25/2024
9:50:51 AM
Page 807 of 864
Report Date: 21-Mar-2024 15:15:23 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20BLK35930A2B.D
Lims ID:mb
Client ID:
Sample Type:MB
Inject. Date:20-Mar-2024 08:52:30 ALS Bottle#:1 Worklist Smp#:6
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031995-004
Misc. Info.:12491
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 15:14:44 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1634
First Level Reviewer: CJS9 Date:21-Mar-2024 15:15:23
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.369 9.374 -0.005 87 225746 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.558 0.000 95 1054746 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.438 16.438 0.000 88 986359 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.078 18.077 0.000 89 701973 4.08 3.89
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 808 of 864
Report Date: 21-Mar-2024 15:15:23 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20BLK35930A2B.D
Injection Date:20-Mar-2024 08:52:30 Instrument ID:MR Operator ID:
Lims ID:mb Worklist Smp#:6
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:1
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Y ( X10
0
0
0
0
)
RZC20BLK35930A2B[MS SCAN Chro]:Total
* C
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3/25/2024
9:50:51 AM
Page 809 of 864
Report Date: 21-Mar-2024 15:15:23 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\RZC20BLK35930A2B.D
Lims ID:mb
Client ID:
Sample Type:MB
Inject. Date:20-Mar-2024 08:52:30 ALS Bottle#:1 Worklist Smp#:6
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031995-004
Misc. Info.:12491
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 15:14:44 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1634
First Level Reviewer: CJS9 Date:21-Mar-2024 15:15:23
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 3.89 95.43
3/25/2024
9:50:51 AM
Page 810 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84641/5
Matrix:SZC21CAN11296MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/21/2024 08:06
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone ND 7.5 1.4
60.1067-63-0 Isopropyl alcohol ND 2.0 0.24
%RECCAS NO.LIMITSQSURROGATE
114 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 811 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84641/5
Matrix:SZC21CAN11296MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/21/2024 08:06
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ug/m3Units:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone ND 18 3.3
60.1067-63-0 Isopropyl alcohol ND 4.9 0.59
%RECCAS NO.LIMITSQSURROGATE
114 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 812 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:MB 140-84641/5
Matrix:SZC21CAN11296MBA.DLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
200(mL)
0.32(mm)
Date Analyzed:03/21/2024 08:06
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ppb v/vUnits:
Number TICs Found:TIC Result Total:00
QRTCOMPOUND NAME RESULTCAS NO.MATCH
QUALITY
Tentatively Identified Compound None
FORM I-TIC TO-15
3/25/2024
9:50:51 AM
Page 813 of 864
Report Date: 22-Mar-2024 13:56:17 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21CAN11296MBA.D
Lims ID:mb
Client ID:
Sample Type:MB
Inject. Date:21-Mar-2024 08:06:30 ALS Bottle#:5 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0032009-003
Misc. Info.:11296
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 13:56:17 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 13:56:17
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.916 9.915 0.001 75 217427 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.030 12.035 -0.005 95 1020063 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.640 16.640 0.000 92 907363 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.249 18.248 0.001 94 753495 4.08 4.64
21 Acrolein 56 6.032 6.010 0.022 59 1935 0.1122
104 Undecane 57 20.513 20.513 0.000 8 1194 0.004919
108 1,2,4-Trichlorobenzene 180 21.847 21.847 0.000 90 6664 0.0459
109 Naphthalene 128 21.960 21.960 0.000 98 24182 0.0878
QC Flag Legend
Processing Flags
Reagents:
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 814 of 864
Report Date: 22-Mar-2024 13:56:17 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21CAN11296MBA.D
Injection Date:21-Mar-2024 08:06:30 Instrument ID:MS Operator ID:
Lims ID:mb Worklist Smp#:5
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:5
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
Y ( X10
0
0
0
0
)
SZC21CAN11296MBA[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 815 of 864
Report Date: 22-Mar-2024 13:56:17 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Knoxville
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\SZC21CAN11296MBA.D
Lims ID:mb
Client ID:
Sample Type:MB
Inject. Date:21-Mar-2024 08:06:30 ALS Bottle#:5 Worklist Smp#:5
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0032009-003
Misc. Info.:11296
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 13:56:17 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 13:56:17
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.64 113.77
3/25/2024
9:50:51 AM
Page 816 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:LCS 140-84584/1002
Matrix:-RCCVZC19-LCS.dLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
500(mL)
0.32(mm)
Date Analyzed:03/19/2024 07:40
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
133.4171-55-6 1,1,1-Trichloroethane 1.52 0.080 0.029
167.8579-34-5 1,1,2,2-Tetrachloroethan
e
1.62 0.080 0.014
187.3876-13-1 1,1,2-Trichloro-1,2,2-tr
ifluoroethane
1.66 0.080 0.0096
133.4179-00-5 1,1,2-Trichloroethane 1.65 0.080 0.015
98.9675-34-3 1,1-Dichloroethane 1.59 0.080 0.011
96.9475-35-4 1,1-Dichloroethene 1.66 0.080 0.013
120.19526-73-8 1,2,3-Trimethylbenzene 1.18 0.080 0.036
181.45120-82-1 1,2,4-Trichlorobenzene 1.33 0.40 0.036
120.2095-63-6 1,2,4-Trimethylbenzene 1.60 0.080 0.020
187.87106-93-4 1,2-Dibromoethane (EDB)1.64 0.080 0.012
170.9276-14-2 1,2-Dichloro-1,1,2,2-tet
rafluoroethane
1.48 0.080 0.012
147.0095-50-1 1,2-Dichlorobenzene 1.54 0.16 0.031
98.96107-06-2 1,2-Dichloroethane 1.72 0.080 0.010
112.9978-87-5 1,2-Dichloropropane 1.64 0.080 0.010
120.20108-67-8 1,3,5-Trimethylbenzene 1.74 0.16 0.064
54.09106-99-0 1,3-Butadiene 1.57 0.16 0.019
147.00541-73-1 1,3-Dichlorobenzene 1.52 0.080 0.016
147.00106-46-7 1,4-Dichlorobenzene 1.51 0.080 0.016
72.1178-93-3 2-Butanone (MEK)1.66 0.40 0.072
100.20591-78-6 2-Hexanone 1.71 0.20 0.056
120.20622-96-8 4-Ethyltoluene 1.52 0.16 0.021
100.16108-10-1 4-Methyl-2-pentanone
(MIBK)
1.80 0.40 0.056
78.1171-43-2 Benzene 1.65 0.080 0.013
126.58100-44-7 Benzyl chloride 1.55 0.16 0.038
163.8375-27-4 Bromodichloromethane 1.79 0.080 0.018
252.7575-25-2 Bromoform 1.83 0.080 0.026
94.9474-83-9 Bromomethane 1.41 0.080 0.022
76.1475-15-0 Carbon disulfide 1.52 0.16 0.035
153.8156-23-5 Carbon tetrachloride 1.49 0.080 0.013
112.56108-90-7 Chlorobenzene 1.66 0.080 0.022
64.5275-00-3 Chloroethane 1.45 0.080 0.032
119.3867-66-3 Chloroform 1.64 0.080 0.014
FORM I TO-15
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9:50:51 AM
Page 817 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:LCS 140-84584/1002
Matrix:-RCCVZC19-LCS.dLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
500(mL)
0.32(mm)
Date Analyzed:03/19/2024 07:40
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84584 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
50.4974-87-3 Chloromethane 1.54 0.40 0.064
96.94156-59-2 cis-1,2-Dichloroethene 1.64 0.080 0.010
110.9710061-01-5 cis-1,3-Dichloropropene 1.84 0.16 0.019
84.16110-82-7 Cyclohexane 1.66 0.16 0.037
208.28124-48-1 Dibromochloromethane 1.70 0.080 0.014
120.9175-71-8 Dichlorodifluoromethane 1.41 0.080 0.014
46.0764-17-5 Ethanol 5.48 2.0 0.88
88.11141-78-6 Ethyl acetate 1.60 0.80 0.060
106.17100-41-4 Ethylbenzene 1.67 0.080 0.013
260.7687-68-3 Hexachlorobutadiene 1.27 0.40 0.032
88.151634-04-4 Methyl tert-butyl ether 1.59 0.40 0.052
98.19108-87-2 Methylcyclohexane 2.13 0.080 0.020
84.9375-09-2 Methylene Chloride 1.52 0.40 0.14
106.17179601-23-1 m-Xylene & p-Xylene 3.47 0.080 0.029
100.21142-82-5 n-Heptane 1.65 0.16 0.014
86.17110-54-3 n-Hexane 1.73 0.16 0.025
128.26111-84-2 Nonane 1.81 0.16 0.044
106.1795-47-6 o-Xylene 1.72 0.080 0.015
104.15100-42-5 Styrene 1.74 0.080 0.024
165.83127-18-4 Tetrachloroethene 1.61 0.080 0.012
72.11109-99-9 Tetrahydrofuran 1.61 0.40 0.072
92.14108-88-3 Toluene 1.65 0.40 0.023
96.94156-60-5 trans-1,2-Dichloroethene 1.51 0.080 0.013
110.9710061-02-6 trans-1,3-Dichloropropen
e
1.73 0.080 0.020
131.3979-01-6 Trichloroethene 1.70 0.080 0.013
137.3775-69-4 Trichlorofluoromethane 1.82 0.080 0.011
86.09108-05-4 Vinyl acetate 1.53 0.40 0.028
62.5075-01-4 Vinyl chloride 1.64 0.16 0.026
%RECCAS NO.LIMITSQSURROGATE
109 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
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Page 818 of 864
Report Date: 20-Mar-2024 14:48:53 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\-RCCVZC19-LCS.d
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:19-Mar-2024 07:40:30 ALS Bottle#:9 Worklist Smp#:1002
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031988-002
Misc. Info.:S253 80 ML 662934
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 14:48:51 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 14:48:51
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.364 9.364 0.000 90 223690 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.553 11.553 0.000 95 990806 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.433 16.433 0.000 87 960495 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.072 18.072 0.000 87 780430 4.08 4.45
6 Chlorodifluoromethane 51 3.788 3.788 0.000 97 154044 1.60 1.61
7 Propene 41 3.799 3.799 0.000 98 66432 1.60 1.55
8 Dichlorodifluoromethane 85 3.858 3.858 0.000 100 217659 1.60 1.41
9 Chloromethane 52 4.063 4.063 0.000 98 26659 1.60 1.54
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.068 4.068 0.000 95 176039 1.60 1.48
12 Vinyl chloride 62 4.252 4.252 0.000 99 103594 1.60 1.64
11 Acetaldehyde 44 4.252 4.252 0.000 99 181722 8.00 6.98
13 Butane 43 4.349 4.349 0.000 84 137067 1.60 1.53
14 Butadiene 54 4.354 4.354 0.000 69 71982 1.60 1.57
15 Bromomethane 94 4.715 4.715 0.000 99 89039 1.60 1.41
16 Chloroethane 64 4.872 4.872 0.000 91 47980 1.60 1.45
17 Ethanol 31 5.023 5.023 0.000 87 149479 8.00 5.48
18 Vinyl bromide 106 5.211 5.211 0.000 98 113120 1.60 1.78
19 2-Methylbutane 43 5.260 5.260 0.000 89 120980 1.60 1.88
20 Trichlorofluoromethane 101 5.503 5.503 0.000 99 302899 1.60 1.82
21 Acrolein 56 5.546 5.546 0.000 89 35363 1.60 2.06
22 Acetonitrile 40 5.621 5.621 0.000 100 41849 1.60 1.82
23 Acetone 58 5.681 5.681 0.000 96 71307 1.60 2.33
25 Pentane 72 5.745 5.745 0.000 99 22625 1.60 1.98
24 Isopropyl alcohol 45 5.810 5.810 0.000 98 161933 1.60 2.18
26 Ethyl ether 31 5.956 5.956 0.000 90 99946 1.60 1.72
27 1,1-Dichloroethene 96 6.279 6.279 0.000 98 108070 1.60 1.66
29 Acrylonitrile 53 6.419 6.419 0.000 95 71727 1.60 1.81
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.468 6.468 0.000 95 237074 1.60 1.66
28 2-Methyl-2-propanol 59 6.479 6.479 0.000 95 189936 1.60 1.69
31 Methylene Chloride 84 6.667 6.667 0.000 93 107068 1.60 1.52
32 3-Chloro-1-propene 39 6.678 6.678 0.000 99 96239 1.60 1.55
3/25/2024
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Page 819 of 864
Report Date: 20-Mar-2024 14:48:53 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\-RCCVZC19-LCS.d
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
33 Carbon disulfide 76 6.835 6.835 0.000 99 293193 1.60 1.52
34 trans-1,2-Dichloroethene 96 7.530 7.530 0.000 99 102665 1.60 1.51
35 2-Methylpentane 43 7.536 7.536 0.000 92 185279 1.60 1.50
36 Methyl tert-butyl ether 73 7.681 7.681 0.000 96 284714 1.60 1.59
37 1,1-Dichloroethane 63 7.983 7.983 0.000 100 186074 1.60 1.59
38 Vinyl acetate 43 8.096 8.096 0.000 99 188786 1.60 1.53
40 Hexane 56 8.571 8.571 0.000 83 83142 1.60 1.73
39 2-Butanone (MEK) 72 8.582 8.582 0.000 97 51447 1.60 1.66
41 Isopropyl ether 45 8.754 8.754 0.000 95 342409 1.60 1.80
42 cis-1,2-Dichloroethene 96 9.018 9.018 0.000 94 117534 1.60 1.64
43 Ethyl acetate 43 9.218 9.218 0.000 99 210692 1.60 1.60
44 Chloroform 83 9.374 9.374 0.000 97 246396 1.60 1.64
45 Tert-butyl ethyl ether 59 9.461 9.461 0.000 95 330750 1.60 1.64
46 Tetrahydrofuran 42 9.817 9.817 0.000 89 102998 1.60 1.61
47 1,1,1-Trichloroethane 97 10.431 10.431 0.000 96 223154 1.60 1.52
48 1,2-Dichloroethane 62 10.550 10.550 0.000 98 153542 1.60 1.72
50 Cyclohexane 69 11.019 11.019 0.000 96 49107 1.60 1.66
51 Benzene 78 11.024 11.024 0.000 97 325015 1.60 1.65
49 n-Butanol 31 11.041 11.041 0.000 68 33313 1.60 1.47
52 Carbon tetrachloride 117 11.046 11.046 0.000 97 228494 1.60 1.49
53 2,3-Dimethylpentane 71 11.121 11.121 0.000 90 70456 1.60 1.63
54 Thiophene 84 11.299 11.299 0.000 96 179722 1.60 1.61
55 Isooctane 57 11.758 11.758 0.000 98 489240 1.60 1.66
56 n-Heptane 71 12.141 12.141 0.000 89 108098 1.60 1.65
57 1,2-Dichloropropane 63 12.254 12.254 0.000 87 117844 1.60 1.64
58 Trichloroethene 130 12.292 12.292 0.000 97 158931 1.60 1.70
59 Dibromomethane 93 12.394 12.394 0.000 97 144537 1.60 1.69
60 Dichlorobromomethane 83 12.540 12.540 0.000 99 259772 1.60 1.79
61 1,4-Dioxane 88 12.572 12.572 0.000 90 46113 1.60 1.61
62 Methyl methacrylate 41 12.621 12.621 0.000 96 133127 1.60 1.77
63 Methylcyclohexane 83 13.084 13.084 0.000 96 249029 1.60 2.13
64 4-Methyl-2-pentanone (MIBK) 43 13.526 13.526 0.000 96 245078 1.60 1.80
65 cis-1,3-Dichloropropene 75 13.575 13.575 0.000 93 205959 1.60 1.84
66 trans-1,3-Dichloropropene 75 14.292 14.292 0.000 98 182982 1.60 1.73
67 Toluene 91 14.416 14.416 0.000 93 435063 1.60 1.65
68 1,1,2-Trichloroethane 83 14.497 14.497 0.000 98 128056 1.60 1.65
69 2-Hexanone 58 14.896 14.896 0.000 95 128170 1.60 1.71
70 n-Octane 85 15.096 15.096 0.000 90 136684 1.60 1.72
71 Chlorodibromomethane 129 15.225 15.225 0.000 98 257942 1.60 1.70
72 Ethylene Dibromide 107 15.532 15.532 0.000 98 228616 1.60 1.64
73 Tetrachloroethene 129 15.586 15.586 0.000 96 152493 1.60 1.61
75 2,3-Dimethylheptane 43 16.465 16.465 0.000 94 329067 1.60 1.56
74 Chlorobenzene 112 16.487 16.487 0.000 94 350509 1.60 1.66
76 Ethylbenzene 91 16.767 16.767 0.000 98 566449 1.60 1.67
77 m-Xylene & p-Xylene 91 16.929 16.929 0.000 98 920489 3.20 3.47
78 n-Nonane 57 17.317 17.317 0.000 88 263810 1.60 1.81
80 Styrene 104 17.404 17.404 0.000 99 321268 1.60 1.74
79 Bromoform 173 17.409 17.409 0.000 96 242950 1.60 1.83
81 o-Xylene 91 17.463 17.463 0.000 98 477001 1.60 1.72
82 1,1,2,2-Tetrachloroethane 83 17.792 17.792 0.000 99 334218 1.60 1.62
83 1,2,3-Trichloropropane 110 17.943 17.943 0.000 98 101334 1.60 1.70
84 Isopropylbenzene 105 18.034 18.034 0.000 95 656897 1.60 1.76
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Report Date: 20-Mar-2024 14:48:53 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\-RCCVZC19-LCS.d
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
85 N-Propylbenzene 120 18.547 18.547 0.000 99 174792 1.60 1.67
86 2-Chlorotoluene 126 18.601 18.601 0.000 97 160409 1.60 1.71
88 4-Ethyltoluene 105 18.687 18.687 0.000 99 578929 1.60 1.52
87 1,3,5-Trimethylbenzene 120 18.757 18.757 0.000 92 276063 1.60 1.74
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 88 227341 1.60 1.45
90 n-Decane 57 19.005 19.005 0.000 93 332913 1.60 1.66
91 tert-Butylbenzene 119 19.167 19.167 0.000 92 543002 1.60 1.58
92 1,2,4-Trimethylbenzene 105 19.183 19.183 0.000 96 523984 1.60 1.60
93 sec-Butylbenzene 105 19.426 19.426 0.000 98 748780 1.60 1.59
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 99 348492 1.60 1.52
95 Benzyl chloride 91 19.528 19.528 0.000 98 413737 1.60 1.55
96 1,4-Dichlorobenzene 146 19.539 19.539 0.000 94 347790 1.60 1.51
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 627671 1.60 1.57
98 1,2,3-Trimethylbenzene 105 19.641 19.641 0.000 98 392746 1.60 1.18
99 Butylcyclohexane 83 19.679 19.679 0.000 95 404220 1.60 1.54
100 2,3-Dihydroindene 117 19.884 19.884 0.000 94 492705 1.60 1.55
101 1,2-Dichlorobenzene 146 19.889 19.889 0.000 96 341925 1.60 1.54
103 n-Butylbenzene 91 20.003 20.003 0.000 98 646106 1.60 1.59
102 Indene 116 20.019 20.019 0.000 89 354502 1.60 1.37
104 Undecane 57 20.278 20.278 0.000 94 381242 1.60 1.61
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.488 0.000 98 151155 1.60 1.36
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.763 0.000 97 568351 1.60 1.39
107 Dodecane 57 21.378 21.378 0.000 96 395069 1.60 1.40
108 1,2,4-Trichlorobenzene 180 21.615 21.615 0.000 94 278845 1.60 1.33
109 Naphthalene 128 21.744 21.744 0.000 99 660592 1.60 1.40
110 Hexachlorobutadiene 225 21.890 21.890 0.000 94 224620 1.60 1.27
111 1,2,3-Trichlorobenzene 180 21.949 21.949 0.000 94 242904 1.60 1.47
112 2-Methylnaphthalene 142 22.483 22.483 0.000 99 283166 1.60 1.07
113 1-Methylnaphthalene 142 22.613 22.613 0.000 99 323163 1.60 1.16
A 116 C8 Range 1 15.098 (15.036-15.144) 0 1155246 1.60 1.75
S 117 Xylenes, Total 100 0 4.80 5.19
S 118 1,2-Dichloroethene, Total 1 0 3.20 3.15
T 143 2-Methylthiophene TIC 97 14.578 14.578 0.000 97 336822 1.60 1.40
T 144 3-Methylthiophene TIC 97 14.788 14.788 0.000 99 332974 1.60 1.39
T 146 2-Ethylthiophene TIC 97 16.875 16.875 0.000 97 414917 1.60 1.73
T 153 1,2-Dimethyl-4-Ethylbenzene TIC 119 20.369 20.369 0.000 98 474332 1.60 1.98
T 156 1,2,3,5-Tetramethylbenzene TIC 119 20.822 20.822 0.000 95 339039 1.60 1.41 a
T 155 1,2,3,4-Tetramethylbenzene TIC 119 21.248 21.248 0.000 97 450662 1.60 1.88 a
T 157 Benzo(b)thiophene TIC 134 21.825 21.825 0.000 99 344385 1.60 1.43
QC Flag Legend
Processing Flags
Review Flags
a - User Assigned ID
Reagents:
40CV101S_00253 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 821 of 864
Report Date: 20-Mar-2024 14:48:53 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\-RCCVZC19-LCS.d
Injection Date:19-Mar-2024 07:40:30 Instrument ID:MR Operator ID:
Lims ID:LCS Worklist Smp#:1002
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:9
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Y ( X10
0
0
0
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)
-RCCVZC19-LCS[MS SCAN Chro]:Total
* C
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3/25/2024
9:50:51 AM
Page 822 of 864
Report Date: 20-Mar-2024 14:48:53 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\-RCCVZC19-LCS.d
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:19-Mar-2024 07:40:30 ALS Bottle#:9 Worklist Smp#:1002
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031988-002
Misc. Info.:S253 80 ML 662934
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240317-31988.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:20-Mar-2024 14:48:51 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: CJS9 Date:20-Mar-2024 14:48:51
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.45 108.96
3/25/2024
9:50:51 AM
Page 823 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:LCS 140-84603/1002
Matrix:-RCCVZC20-LCS.dLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
500(mL)
0.32(mm)
Date Analyzed:03/20/2024 07:06
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84603 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 2.22 J 3.0 0.56
60.1067-63-0 Isopropyl alcohol 1.90 0.80 0.096
%RECCAS NO.LIMITSQSURROGATE
103 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 824 of 864
Report Date: 21-Mar-2024 15:06:06 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\-RCCVZC20-LCS.d
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:20-Mar-2024 07:06:30 ALS Bottle#:3 Worklist Smp#:1002
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031995-002
Misc. Info.:S253 80 ML 662934
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 15:06:04 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1634
First Level Reviewer: CJS9 Date:21-Mar-2024 15:06:04
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.374 9.374 0.000 91 207389 3.84 3.84
* 2 1,4-Difluorobenzene 114 11.558 11.558 0.000 95 971071 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.438 16.438 0.000 87 875539 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.078 18.078 0.000 89 674720 4.08 4.22
6 Chlorodifluoromethane 51 3.799 3.799 0.000 97 138895 1.60 1.57
7 Propene 41 3.809 3.809 0.000 98 61625 1.60 1.55
8 Dichlorodifluoromethane 85 3.869 3.869 0.000 100 189929 1.60 1.33
9 Chloromethane 52 4.074 4.074 0.000 98 25425 1.60 1.58
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.084 4.084 0.000 96 162631 1.60 1.47
12 Vinyl chloride 62 4.262 4.262 0.000 87 99474 1.60 1.70
11 Acetaldehyde 44 4.262 4.262 0.000 100 171384 8.00 7.10
13 Butane 43 4.360 4.360 0.000 92 122006 1.60 1.47
14 Butadiene 54 4.365 4.365 0.000 96 66373 1.60 1.56
15 Bromomethane 94 4.726 4.726 0.000 99 87342 1.60 1.49
16 Chloroethane 64 4.883 4.883 0.000 92 47791 1.60 1.56
17 Ethanol 31 5.055 5.055 0.000 88 156381 8.00 6.18
18 Vinyl bromide 106 5.222 5.222 0.000 99 104573 1.60 1.77
19 2-Methylbutane 43 5.271 5.271 0.000 89 117061 1.60 1.96
20 Trichlorofluoromethane 101 5.513 5.513 0.000 99 262038 1.60 1.70
21 Acrolein 56 5.562 5.562 0.000 91 31883 1.60 2.00
22 Acetonitrile 40 5.637 5.637 0.000 98 38935 1.60 1.83
23 Acetone 58 5.708 5.708 0.000 96 62944 1.60 2.22
25 Pentane 72 5.756 5.756 0.000 96 19045 1.60 1.80
24 Isopropyl alcohol 45 5.859 5.859 0.000 99 130896 1.60 1.90
26 Ethyl ether 31 5.977 5.977 0.000 93 85906 1.60 1.60
27 1,1-Dichloroethene 96 6.290 6.290 0.000 98 89596 1.60 1.48
29 Acrylonitrile 53 6.436 6.436 0.000 93 58290 1.60 1.59
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.479 6.479 0.000 96 199435 1.60 1.50
28 2-Methyl-2-propanol 59 6.549 6.549 0.000 94 154595 1.60 1.48
31 Methylene Chloride 84 6.678 6.678 0.000 92 91377 1.60 1.40
32 3-Chloro-1-propene 39 6.689 6.689 0.000 97 84288 1.60 1.46
3/25/2024
9:50:51 AM
Page 825 of 864
Report Date: 21-Mar-2024 15:06:06 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\-RCCVZC20-LCS.d
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
33 Carbon disulfide 76 6.845 6.845 0.000 99 269151 1.60 1.51
34 trans-1,2-Dichloroethene 96 7.536 7.536 0.000 99 93217 1.60 1.48
35 2-Methylpentane 43 7.546 7.546 0.000 92 164129 1.60 1.44
36 Methyl tert-butyl ether 73 7.708 7.708 0.000 96 253169 1.60 1.52
37 1,1-Dichloroethane 63 7.989 7.989 0.000 100 169460 1.60 1.56
38 Vinyl acetate 43 8.113 8.113 0.000 99 197932 1.60 1.73
40 Hexane 56 8.582 8.582 0.000 92 70297 1.60 1.57
39 2-Butanone (MEK) 72 8.603 8.603 0.000 98 45437 1.60 1.58
41 Isopropyl ether 45 8.770 8.770 0.000 95 303463 1.60 1.72
42 cis-1,2-Dichloroethene 96 9.029 9.029 0.000 93 99933 1.60 1.50
43 Ethyl acetate 43 9.234 9.234 0.000 99 182833 1.60 1.50
44 Chloroform 83 9.385 9.385 0.000 96 207505 1.60 1.49
45 Tert-butyl ethyl ether 59 9.488 9.488 0.000 95 275809 1.60 1.47
46 Tetrahydrofuran 42 9.838 9.838 0.000 88 93424 1.60 1.57
47 1,1,1-Trichloroethane 97 10.437 10.437 0.000 96 199541 1.60 1.46
48 1,2-Dichloroethane 62 10.555 10.555 0.000 98 131029 1.60 1.49
50 Cyclohexane 69 11.024 11.024 0.000 96 46115 1.60 1.59
51 Benzene 78 11.030 11.030 0.000 97 310089 1.60 1.61
52 Carbon tetrachloride 117 11.051 11.051 0.000 96 209328 1.60 1.39
49 n-Butanol 31 11.084 11.084 0.000 68 32343 1.60 1.46
53 2,3-Dimethylpentane 71 11.132 11.132 0.000 90 67143 1.60 1.58
54 Thiophene 84 11.305 11.305 0.000 95 171070 1.60 1.57
55 Isooctane 57 11.763 11.763 0.000 98 438830 1.60 1.52
56 n-Heptane 71 12.146 12.146 0.000 88 99354 1.60 1.55
57 1,2-Dichloropropane 63 12.265 12.265 0.000 89 108494 1.60 1.54
58 Trichloroethene 130 12.292 12.292 0.000 98 141329 1.60 1.55
59 Dibromomethane 93 12.394 12.394 0.000 97 122734 1.60 1.46
60 Dichlorobromomethane 83 12.540 12.540 0.000 99 214694 1.60 1.51
61 1,4-Dioxane 88 12.594 12.594 0.000 90 38652 1.60 1.38
62 Methyl methacrylate 41 12.637 12.637 0.000 96 109034 1.60 1.48
63 Methylcyclohexane 83 13.090 13.090 0.000 96 210904 1.60 1.84
64 4-Methyl-2-pentanone (MIBK) 43 13.548 13.548 0.000 97 222877 1.60 1.67
65 cis-1,3-Dichloropropene 75 13.580 13.580 0.000 97 188203 1.60 1.72
66 trans-1,3-Dichloropropene 75 14.298 14.298 0.000 98 163281 1.60 1.69
67 Toluene 91 14.422 14.422 0.000 92 388800 1.60 1.62
68 1,1,2-Trichloroethane 83 14.503 14.503 0.000 98 115205 1.60 1.63
69 2-Hexanone 58 14.918 14.918 0.000 95 112802 1.60 1.65
70 n-Octane 85 15.096 15.096 0.000 90 119757 1.60 1.65
71 Chlorodibromomethane 129 15.231 15.231 0.000 98 231891 1.60 1.68
72 Ethylene Dibromide 107 15.533 15.533 0.000 98 207602 1.60 1.63
73 Tetrachloroethene 129 15.592 15.592 0.000 96 146345 1.60 1.70
75 2,3-Dimethylheptane 43 16.471 16.471 0.000 93 260994 1.60 1.36
74 Chlorobenzene 112 16.487 16.487 0.000 94 293181 1.60 1.52
76 Ethylbenzene 91 16.767 16.767 0.000 98 470773 1.60 1.52
77 m-Xylene & p-Xylene 91 16.929 16.929 0.000 98 753223 3.20 3.11
78 n-Nonane 57 17.323 17.323 0.000 86 206463 1.60 1.55
80 Styrene 104 17.404 17.404 0.000 99 262235 1.60 1.56
79 Bromoform 173 17.409 17.409 0.000 96 209273 1.60 1.73
81 o-Xylene 91 17.463 17.463 0.000 98 383956 1.60 1.52
82 1,1,2,2-Tetrachloroethane 83 17.792 17.792 0.000 99 274904 1.60 1.46
83 1,2,3-Trichloropropane 110 17.948 17.948 0.000 97 81118 1.60 1.50
84 Isopropylbenzene 105 18.035 18.035 0.000 96 531702 1.60 1.57
3/25/2024
9:50:51 AM
Page 826 of 864
Report Date: 21-Mar-2024 15:06:06 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\-RCCVZC20-LCS.d
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
85 N-Propylbenzene 120 18.547 18.547 0.000 99 146607 1.60 1.54
86 2-Chlorotoluene 126 18.606 18.606 0.000 98 136128 1.60 1.59
88 4-Ethyltoluene 105 18.692 18.692 0.000 99 514715 1.60 1.48
87 1,3,5-Trimethylbenzene 120 18.757 18.757 0.000 93 248714 1.60 1.72
89 Alpha Methyl Styrene 118 18.984 18.984 0.000 87 199747 1.60 1.40
90 n-Decane 57 19.011 19.011 0.000 94 290752 1.60 1.59
91 tert-Butylbenzene 119 19.167 19.167 0.000 93 483807 1.60 1.55
92 1,2,4-Trimethylbenzene 105 19.183 19.183 0.000 96 463807 1.60 1.55
93 sec-Butylbenzene 105 19.426 19.426 0.000 99 671391 1.60 1.56
94 1,3-Dichlorobenzene 146 19.458 19.458 0.000 98 318464 1.60 1.52
95 Benzyl chloride 91 19.528 19.528 0.000 98 362939 1.60 1.50
96 1,4-Dichlorobenzene 146 19.539 19.539 0.000 94 315943 1.60 1.51
97 4-Isopropyltoluene 119 19.582 19.582 0.000 97 563382 1.60 1.54
98 1,2,3-Trimethylbenzene 105 19.641 19.641 0.000 98 350356 1.60 1.15
99 Butylcyclohexane 83 19.685 19.685 0.000 95 363993 1.60 1.52
100 2,3-Dihydroindene 117 19.890 19.890 0.000 93 442735 1.60 1.53
101 1,2-Dichlorobenzene 146 19.895 19.895 0.000 95 309145 1.60 1.52
103 n-Butylbenzene 91 20.003 20.003 0.000 98 579394 1.60 1.57
102 Indene 116 20.019 20.019 0.000 92 316986 1.60 1.34
104 Undecane 57 20.283 20.283 0.000 94 342827 1.60 1.59
105 1,2-Dibromo-3-Chloropropane 157 20.488 20.488 0.000 97 134500 1.60 1.33
106 1,2,4,5-Tetramethylbenzene 119 20.763 20.763 0.000 97 509852 1.60 1.37
107 Dodecane 57 21.378 21.378 0.000 96 350381 1.60 1.36
108 1,2,4-Trichlorobenzene 180 21.620 21.620 0.000 94 255587 1.60 1.33
109 Naphthalene 128 21.745 21.745 0.000 99 601842 1.60 1.40
110 Hexachlorobutadiene 225 21.890 21.890 0.000 94 205400 1.60 1.28
111 1,2,3-Trichlorobenzene 180 21.949 21.949 0.000 94 224606 1.60 1.49
112 2-Methylnaphthalene 142 22.489 22.489 0.000 99 277294 1.60 1.15
113 1-Methylnaphthalene 142 22.618 22.618 0.000 99 320723 1.60 1.26
A 116 C8 Range 1 15.101 (15.047-15.155) 0 1023378 1.60 1.58
S 117 Xylenes, Total 100 0 4.80 4.64
S 118 1,2-Dichloroethene, Total 1 0 3.20 2.98
T 143 2-Methylthiophene TIC 97 14.583 14.583 0.000 97 300019 1.60 1.37
T 144 3-Methylthiophene TIC 97 14.794 14.794 0.000 99 297013 1.60 1.36
T 146 2-Ethylthiophene TIC 97 16.875 16.875 0.000 97 344517 1.60 1.57
T 153 1,2-Dimethyl-4-Ethylbenzene TIC 119 20.369 20.369 0.000 98 424501 1.60 1.94
T 156 1,2,3,5-Tetramethylbenzene TIC 119 20.822 20.822 0.000 95 306047 1.60 1.40 a
T 155 1,2,3,4-Tetramethylbenzene TIC 119 21.248 21.248 0.000 97 400410 1.60 1.83 a
T 157 Benzo(b)thiophene TIC 134 21.825 21.825 0.000 99 318116 1.60 1.45
QC Flag Legend
Processing Flags
Review Flags
a - User Assigned ID
Reagents:
40CV101S_00253 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 827 of 864
Report Date: 21-Mar-2024 15:06:06 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\-RCCVZC20-LCS.d
Injection Date:20-Mar-2024 07:06:30 Instrument ID:MR Operator ID:
Lims ID:LCS Worklist Smp#:1002
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:3
Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
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)
-RCCVZC20-LCS[MS SCAN Chro]:Total
* C
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3/25/2024
9:50:51 AM
Page 828 of 864
Report Date: 21-Mar-2024 15:06:06 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\-RCCVZC20-LCS.d
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:20-Mar-2024 07:06:30 ALS Bottle#:3 Worklist Smp#:1002
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0031995-002
Misc. Info.:S253 80 ML 662934
Operator ID:Instrument ID:MR
Method:\\chromfs\Knoxville\ChromData\MR\20240318-31995.b\MR_TO15.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:21-Mar-2024 15:06:04 Calib Date:06-Mar-2024 00:47:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MR\20240305-31853.b\RZC05ICIS7.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1634
First Level Reviewer: CJS9 Date:21-Mar-2024 15:06:04
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.22 103.34
3/25/2024
9:50:51 AM
Page 829 of 864
FORM I
AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:140-35862-1Eurofins Knoxville
SDG No.:
Client Sample ID:Lab Sample ID:LCS 140-84641/1002
Matrix:-SCCVZC21-LCS.dLab File ID:
Date Collected:TO-15Analysis Method:
Air
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
500(mL)
0.32(mm)
Date Analyzed:03/21/2024 06:46
ID:RTX-5
% Solids:
Heated Purge: (Y/N)Purge Volume:pH:
Analysis Batch No.:84641 ppb v/vUnits:
CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR
WEIGHT MDL
58.0867-64-1 Acetone 1.53 J 3.0 0.56
60.1067-63-0 Isopropyl alcohol 1.53 0.80 0.096
%RECCAS NO.LIMITSQSURROGATE
120 60-140460-00-4 4-Bromofluorobenzene (Surr)
FORM I TO-15
3/25/2024
9:50:51 AM
Page 830 of 864
Report Date: 22-Mar-2024 13:48:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Target Compound Quantitation Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\-SCCVZC21-LCS.d
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:21-Mar-2024 06:46:30 ALS Bottle#:11 Worklist Smp#:1002
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0032009-002
Misc. Info.:P220 80 ML 663004
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 13:48:45 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 13:48:45
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
* 1 Chlorobromomethane (IS) 128 9.915 9.915 0.000 77 226667 3.84 3.84
* 2 1,4-Difluorobenzene 114 12.035 12.035 0.000 95 1082080 3.84 3.84
* 3 Chlorobenzene-d5 (IS) 117 16.640 16.640 0.000 91 969868 4.00 4.00
$ 4 4-Bromofluorobenzene (Surr) 95 18.248 18.248 0.000 94 850017 4.08 4.90
6 Chlorodifluoromethane 51 4.170 4.170 0.000 96 196279 1.60 1.91
7 Propene 41 4.186 4.186 0.000 94 68472 1.60 1.38
8 Dichlorodifluoromethane 85 4.245 4.245 0.000 100 382077 1.60 2.56
9 Chloromethane 52 4.466 4.466 0.000 50 28959 1.60 3.13
10 1,2-Dichloro-1,1,2,2-tetrafluoro 135 4.471 4.471 0.000 86 304481 1.60 3.24
11 Acetaldehyde 44 4.654 4.654 0.000 95 154300 8.00 14.6
12 Vinyl chloride 62 4.670 4.670 0.000 100 99137 1.60 3.32
13 Butadiene 54 4.773 4.773 0.000 77 69125 1.60 3.13
14 Butane 43 4.778 4.778 0.000 79 129932 1.60 3.25
15 Bromomethane 94 5.165 5.165 0.000 96 115551 1.60 3.56
16 Chloroethane 64 5.337 5.337 0.000 89 48851 1.60 3.75
17 Ethanol 31 5.434 5.434 0.000 96 141006 8.00 10.6
18 Vinyl bromide 106 5.692 5.692 0.000 93 93495 1.60 1.70
19 2-Methylbutane 43 5.741 5.741 0.000 88 83598 1.60 1.47
20 Trichlorofluoromethane 101 6.005 6.005 0.000 99 426399 1.60 2.51
21 Acrolein 56 6.010 6.010 0.000 96 22438 1.60 1.25
22 Acetonitrile 40 6.085 6.085 0.000 97 27236 1.60 1.27
23 Acetone 58 6.139 6.139 0.000 100 35928 1.60 1.53
24 Isopropyl alcohol 45 6.241 6.241 0.000 49 109938 1.60 1.53
25 Pentane 72 6.252 6.252 0.000 93 14119 1.60 1.52
26 Ethyl ether 31 6.440 6.440 0.000 91 66737 1.60 1.12
27 1,1-Dichloroethene 96 6.801 6.801 0.000 96 87779 1.60 1.46
28 Acrylonitrile 53 6.919 6.919 0.000 55 52878 1.60 1.38
29 2-Methyl-2-propanol 59 6.924 6.924 0.000 95 151497 1.60 1.50
30 1,1,2-Trichloro-1,2,2-trifluoroe 101 6.989 6.989 0.000 91 249745 1.60 1.88
31 Methylene Chloride 84 7.188 7.188 0.000 95 79957 1.60 1.41
32 3-Chloro-1-propene 39 7.204 7.204 0.000 88 86820 1.60 1.58
3/25/2024
9:50:51 AM
Page 831 of 864
Report Date: 22-Mar-2024 13:48:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\-SCCVZC21-LCS.d
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
33 Carbon disulfide 76 7.382 7.382 0.000 96 235972 1.60 1.45
34 trans-1,2-Dichloroethene 96 8.065 8.065 0.000 96 89075 1.60 1.44
35 2-Methylpentane 43 8.081 8.081 0.000 89 140346 1.60 1.20
36 Methyl tert-butyl ether 73 8.189 8.189 0.000 94 269193 1.60 1.62
37 1,1-Dichloroethane 63 8.528 8.528 0.000 98 168048 1.60 1.57
38 Vinyl acetate 43 8.614 8.614 0.000 99 156031 1.60 1.22
39 2-Butanone (MEK) 72 9.092 9.092 0.000 97 35973 1.60 1.30
40 Hexane 56 9.114 9.114 0.000 86 65515 1.60 1.47
41 Isopropyl ether 45 9.275 9.275 0.000 88 232392 1.60 1.26
42 cis-1,2-Dichloroethene 96 9.566 9.566 0.000 94 93323 1.60 1.43
43 Ethyl acetate 43 9.727 9.727 0.000 98 157874 1.60 1.24
44 Chloroform 83 9.926 9.926 0.000 70 265179 1.60 2.03
45 Tert-butyl ethyl ether 59 9.985 9.985 0.000 96 253351 1.60 1.42
46 Tetrahydrofuran 42 10.319 10.319 0.000 88 72010 1.60 1.14
47 1,1,1-Trichloroethane 97 10.964 10.964 0.000 94 326532 1.60 2.20
48 1,2-Dichloroethane 62 11.067 11.067 0.000 98 184512 1.60 2.09
49 n-Butanol 31 11.454 11.454 0.000 88 20917 1.60 0.8688
50 Cyclohexane 69 11.535 11.535 0.000 64 42060 1.60 1.51
51 Benzene 78 11.535 11.535 0.000 97 277386 1.60 1.54
52 Carbon tetrachloride 117 11.556 11.556 0.000 97 394176 1.60 2.37
53 2,3-Dimethylpentane 71 11.621 11.621 0.000 87 54009 1.60 1.31
54 Thiophene 84 11.798 11.798 0.000 96 144704 1.60 1.35
55 Isooctane 57 12.234 12.234 0.000 95 372040 1.60 1.36
56 n-Heptane 71 12.584 12.584 0.000 84 79683 1.60 1.33
57 1,2-Dichloropropane 63 12.702 12.702 0.000 75 90678 1.60 1.37
58 Trichloroethene 130 12.729 12.729 0.000 93 158560 1.60 1.55
59 Dibromomethane 93 12.820 12.820 0.000 91 154638 1.60 1.84
60 Dichlorobromomethane 83 12.950 12.950 0.000 97 282867 1.60 2.03
61 1,4-Dioxane 88 12.950 12.950 0.000 34 34043 1.60 1.22
62 Methyl methacrylate 41 13.003 13.003 0.000 89 110483 1.60 1.36
63 Methylcyclohexane 83 13.471 13.471 0.000 92 192792 1.60 1.65
64 4-Methyl-2-pentanone (MIBK) 43 13.837 13.837 0.000 96 171316 1.60 1.24
65 cis-1,3-Dichloropropene 75 13.907 13.907 0.000 97 166913 1.60 1.56
66 trans-1,3-Dichloropropene 75 14.580 14.580 0.000 96 154212 1.60 1.56
67 Toluene 91 14.709 14.709 0.000 93 346317 1.60 1.47
68 1,1,2-Trichloroethane 83 14.779 14.779 0.000 93 101767 1.60 1.49
69 2-Hexanone 58 15.128 15.128 0.000 93 83409 1.60 1.18
70 n-Octane 85 15.338 15.338 0.000 82 104428 1.60 1.48
71 Chlorodibromomethane 129 15.478 15.478 0.000 96 315238 1.60 1.95
72 Ethylene Dibromide 107 15.768 15.768 0.000 96 208797 1.60 1.56
73 Tetrachloroethene 129 15.828 15.828 0.000 92 175792 1.60 1.79
74 2,3-Dimethylheptane 43 16.667 16.667 0.000 88 249395 1.60 1.31
75 Chlorobenzene 112 16.688 16.688 0.000 92 322026 1.60 1.62
76 Ethylbenzene 91 16.957 16.957 0.000 99 490614 1.60 1.57
77 m-Xylene & p-Xylene 91 17.113 17.113 0.000 99 903643 3.20 3.78
78 n-Nonane 57 17.490 17.490 0.000 81 186123 1.60 1.39
80 Styrene 104 17.576 17.576 0.000 97 282164 1.60 1.52
79 Bromoform 173 17.587 17.587 0.000 95 353753 1.60 1.93
81 o-Xylene 91 17.641 17.641 0.000 97 452723 1.60 1.67
82 1,1,2,2-Tetrachloroethane 83 17.958 17.958 0.000 95 260481 1.60 1.38
83 1,2,3-Trichloropropane 110 18.114 18.114 0.000 94 99210 1.60 1.66
84 Isopropylbenzene 105 18.211 18.211 0.000 98 652495 1.60 1.61
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Page 832 of 864
Report Date: 22-Mar-2024 13:48:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\-SCCVZC21-LCS.d
Compound Sig
RT
(min.)
Adj RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ppb v/v
OnCol Amt
ppb v/v Flags
85 N-Propylbenzene 120 18.738 18.738 0.000 99 166753 1.60 1.42
86 2-Chlorotoluene 126 18.792 18.792 0.000 97 167438 1.60 1.51
87 4-Ethyltoluene 105 18.878 18.878 0.000 98 632087 1.60 1.52
88 1,3,5-Trimethylbenzene 120 18.948 18.948 0.000 91 309224 1.60 1.71
89 Alpha Methyl Styrene 118 19.179 19.179 0.000 87 242438 1.60 1.36
90 n-Decane 57 19.206 19.206 0.000 96 295221 1.60 1.42
91 tert-Butylbenzene 119 19.373 19.373 0.000 90 674748 1.60 1.73
92 1,2,4-Trimethylbenzene 105 19.384 19.384 0.000 96 618989 1.60 1.78
93 sec-Butylbenzene 105 19.642 19.642 0.000 97 822779 1.60 1.58
94 1,3-Dichlorobenzene 146 19.669 19.669 0.000 98 418041 1.60 1.53
95 Benzyl chloride 91 19.739 19.739 0.000 97 400962 1.60 1.65
96 1,4-Dichlorobenzene 146 19.755 19.755 0.000 96 418532 1.60 1.56
97 4-Isopropyltoluene 119 19.792 19.792 0.000 96 784783 1.60 1.68
98 1,2,3-Trimethylbenzene 105 19.857 19.857 0.000 99 459063 1.60 1.29
99 Butylcyclohexane 83 19.900 19.900 0.000 91 365817 1.60 1.39
100 2,3-Dihydroindene 117 20.110 20.110 0.000 92 531465 1.60 1.52
101 1,2-Dichlorobenzene 146 20.115 20.115 0.000 95 423585 1.60 1.58
102 n-Butylbenzene 91 20.228 20.228 0.000 97 687591 1.60 1.65
103 Indene 116 20.239 20.239 0.000 92 383433 1.60 1.26
104 Undecane 57 20.513 20.513 0.000 91 329077 1.60 1.27
105 1,2-Dibromo-3-Chloropropane 157 20.734 20.734 0.000 97 170183 1.60 1.26
106 1,2,4,5-Tetramethylbenzene 119 21.019 21.019 0.000 96 691770 1.60 1.49
107 Dodecane 57 21.638 21.638 0.000 91 311148 1.60 1.42
108 1,2,4-Trichlorobenzene 180 21.847 21.847 0.000 94 338997 1.60 2.19
109 Naphthalene 128 21.960 21.960 0.000 98 655708 1.60 2.23
110 Hexachlorobutadiene 225 22.089 22.089 0.000 94 674629 1.60 3.14
111 1,2,3-Trichlorobenzene 180 22.149 22.149 0.000 94 416089 1.60 3.63
112 2-Methylnaphthalene 142 22.665 22.665 0.000 99 312163 1.60 2.60
113 1-Methylnaphthalene 142 22.794 22.794 0.000 98 403662 1.60 3.04
A 115 C8 Range 1 15.338 (15.290-15.386) 0 996718 1.60 1.66
S 116 Xylenes, Total 100 0 4.80 5.45
S 117 1,2-Dichloroethene, Total 1 0 3.20 2.88
T 141 2-Methylthiophene TIC 97 14.859 14.859 0.000 97 282589 1.60 1.17
T 142 3-Methylthiophene TIC 97 15.058 15.058 0.000 88 279663 1.60 1.15
T 144 2-Ethylthiophene TIC 97 17.065 17.065 0.000 58 391801 1.60 1.62
T 149 1,2-Dimethyl-4-Ethylbenzene TIC 119 20.605 20.605 0.000 93 553199 1.60 2.28
T 150 1,2,3,5-Tetramethylbenzene TIC 119 21.078 21.078 0.000 91 412457 1.60 1.70
T 151 1,2,3,4-Tetramethylbenzene TIC 119 21.519 21.519 0.000 93 510840 1.60 2.11
T 152 Benzo(b)thiophene TIC 134 22.030 22.030 0.000 87 313108 1.60 1.29
QC Flag Legend
Processing Flags
Reagents:
40CV101S_00252 Amount Added: 80.00 Units: mL
40MXISSUR_00004 Amount Added: 40.00 Units: mL Run Reagent
3/25/2024
9:50:51 AM
Page 833 of 864
Report Date: 22-Mar-2024 13:48:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\-SCCVZC21-LCS.d
Injection Date:21-Mar-2024 06:46:30 Instrument ID:MS Operator ID:
Lims ID:LCS Worklist Smp#:1002
Client ID:
Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:11
Method:MS_TO15A Limit Group:MSA TO14A_15 Routine ICAL
Column: RTX-5 ( 0.32 mm)
3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0
Min
0
2
4
6
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-SCCVZC21-LCS[MS SCAN Chro]:Total
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3/25/2024
9:50:51 AM
Page 834 of 864
Report Date: 22-Mar-2024 13:48:46 Chrom Revision: 2.3 23-Feb-2024 16:51:14
Eurofins Environment Testing
Recovery Report
Data File:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\-SCCVZC21-LCS.d
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:21-Mar-2024 06:46:30 ALS Bottle#:11 Worklist Smp#:1002
Purge Vol:500.000 mL Dil. Factor:1.0000
Sample Info:140-0032009-002
Misc. Info.:P220 80 ML 663004
Operator ID:Instrument ID:MS
Method:\\chromfs\Knoxville\ChromData\MS\20240319-32009.b\MS_TO15A.m
Limit Group:MSA TO14A_15 Routine ICAL
Last Update:22-Mar-2024 13:48:45 Calib Date:08-Feb-2024 01:36:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Knoxville\ChromData\MS\20240207-31497.b\SZB07ICIS07.D
Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN
Process Host:CTX1619
First Level Reviewer: CJS9 Date:22-Mar-2024 13:48:45
Compound
Amount
Added
Amount
Recovered %Rec.
$4 4-Bromofluorobenzene (Surr)4.08 4.90 120.08
3/25/2024
9:50:51 AM
Page 835 of 864
Lab Name:Job No.:
AIR - GC/MS VOA ANALYSIS RUN LOG
Eurofins Knoxville 140-35862-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
MS
83168
Start Date:
End Date:02/08/2024 05:55
02/07/2024 14:06
BFB 140-83168/1 RTX-5 0.32(mm)102/07/2024 14:06 SZBFBB07.D
IC 140-83168/3 RTX-5 0.32(mm)102/07/2024 15:26 SZB07IC10.D
IC 140-83168/5 RTX-5 0.32(mm)102/07/2024 17:08 SZB07IC09.D
IC 140-83168/7 RTX-5 0.32(mm)102/07/2024 18:49 SZB07IC08.D
IC 140-83168/9 RTX-5 0.32(mm)102/07/2024 20:28 SZB07IC01.D
IC 140-83168/10 RTX-5 0.32(mm)102/07/2024 21:19 SZB07IC02.D
ZZZZZ RTX-5 0.32(mm)102/07/2024 21:19
ZZZZZ RTX-5 0.32(mm)102/07/2024 21:19
IC 140-83168/11 RTX-5 0.32(mm)102/07/2024 22:11 SZB07IC03.D
ZZZZZ RTX-5 0.32(mm)102/07/2024 22:11
ZZZZZ RTX-5 0.32(mm)102/07/2024 22:11
IC 140-83168/12 RTX-5 0.32(mm)102/07/2024 23:02 SZB07IC04.D
ZZZZZ RTX-5 0.32(mm)102/07/2024 23:02
ZZZZZ RTX-5 0.32(mm)102/07/2024 23:02
IC 140-83168/13 RTX-5 0.32(mm)102/07/2024 23:54 SZB07IC05.D
ZZZZZ RTX-5 0.32(mm)102/07/2024 23:54
ZZZZZ RTX-5 0.32(mm)102/07/2024 23:54
IC 140-83168/14 RTX-5 0.32(mm)102/08/2024 00:44 SZB07IC06.D
ICIS 140-83168/15 RTX-5 0.32(mm)102/08/2024 01:36 SZB07ICIS07.D
ICV 140-83168/18 RTX-5 0.32(mm)102/08/2024 04:07 SZB07LCS.D
ZZZZZ RTX-5 0.32(mm)102/08/2024 05:55
TO-15
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Page 836 of 864
3/25/2024
9:50:51 AM
Page 837 of 864
Eurofins Knoxville GC/MS Air - Initial Calibration Data Review Checklist
Methods: TO-14 and TO-15 - KNOX-MS-0001, Rev 23 & KNOX-MS-0023, Rev 6

MS017r53, 08/28/2023
Analysis Date: 2/7/23 Instrument: MS Chrom WL #: 31497
TALS
Batch &
Event #
TO14/15: 83168/4892 DOD5: 83171/4895
DOD: 83169/4893 OHIO: 83170/4894
Chrom/Worklist Review 1st Comments 2nd
1. Re-read each Limit Group [method editor-limit groups] na
2. Verify LODV in Chrom [method editor -> edit -> MDL] na
3. Are the reagents and init/final volumes correct and first level “unlock/clear”?
(Verify reagents & amt. injected at each level)
Y
4. Files linked properly to calibration levels? [Sample List- Lab ID vs. Info] Y
5. Did BFB meet tune criteria? [F8] Y
6. Were all standards injected within 24 hr of BFB? [F7] Y
7. High point checked for saturation and point removed if so? [Chrom] Y
8. If manual integrations performed, are they properly performed, correct, baseline
clearly identified, and correct reason given? [Chrom]
NA
9. RT for each IS +20 sec avg. RT? [F6 IstdRec] Y
10. Area for each IS + 40% avg. area? [F6 IstdRec] Y
11. Each analyte + 0.06 RRT of avg. RRT? [F6 - RRT] Y
12. Elution order checked on isomeric pairs? [Chrom]
 dichlorodifluoromethane / 1,2-dichlorotetrafluoroethane Y
 2-methyl butane / acrolein Y
 trichlorofluoromethane / 1,1,2-trichlorotrifluoroethane Y
 vinyl acetate / hexane Y
 cis- and trans- isomers Y
 ethyl benzene / m/p-xylene / o-xylene Y
 n-propylbenzene/4-ethyl toluene/1,3,5-trimethylbenzene/1,2,4-
trimethylbenzene/
sec-butylbenzene/1,2,3-trimethylbenzene
Y
 tert-butylbenzene/4-isopropyltoluene Y
 1,3- , 1,4- , and 1,2-dichlorobenzene Y
 1,2-dimethyl-4-ethylbenzene/1,2,4,5-, 1,2,3,5-, and 1,2,3,4-tetramethylbenzenes NA
 1,2,4- and 1,2,3-trichlorobenzenes Y
 2-, and 1-methylnaphthalene Y
13. “Range” analytes & internal standard RIC ID’d correctly, inspected for
interferences & proper integration?
Y
MLG Review TO DOD DOD
5
OH Comments

TO DOD DOD
5
OH
14. Is %RSD for all target analytes < 30%? (with up to 2 compounds with RSD
< 40%) 1& 2 methylnaphthalene < 50% (NONE for DOD5) [F6 ∑ ]
Y Y Y Y
15. Were at least 5 levels of each compound analyzed? [F6] Y Y Y Y
16. Is low level std at or <RL and are the remaining points consec.? [F6] Y Y Y Y
17. At least 6 consec. points used for quad curves; at least 5 consec. points for
linear curves? (Note: Ohio does not allow quad) [F6]
Y Y Y Y
18. If curves were used, is correlation coefficient >0.990? [F6] Y Y Y Y
19. Is the intercept less than the RL for each curve? [F6] Y Y Y Y
20. For quadratic: is a tangent’s slope to the curve entirely positive or negative
and continuous.
na Y Y Y na
21. Is the readback for each point within criteria?
(<40 for all points, low point < 50 %, except CLC/provisionary < 80%)
Y Y Y Y
22. Is the second source analysis within limits? [F8 - icv] Y Y Y Y
TALS Review TO DOD DOD
5
OH Comments TO DOD DOD
5
OH
23. Upload ICAL na na na na
24. Graphics uploaded?
[paperclip]
Y Y Y Y
25. All points are in the most recent active calibration event?
[Calibration Events –‘Fix ICAL linkage’ if needed]
Y Y Y Y
26. Runs linked to BFB? [QC Links] Y Y Y Y
27. Run Checklist and acknowledge findings [F8] Y Y Y Y
28. If criteria not met, was a NCM generated? NA NA NA NA
29. After review in TALS, approve the method in TALS. na na na na Y Y Y Y
30. After verifying TALS is correct, lock method in Chrom na na na na Y Y Y Y
31. Checklist scanned, attached & assigned properly? na na na na Y Y Y Y
Analyst/date: 2nd Level Reviewer/date: LL 2/12/2024
Comments:
3/25/2024
9:50:51 AM
Page 838 of 864
Lab Name:Job No.:
AIR - GC/MS VOA ANALYSIS RUN LOG
Eurofins Knoxville 140-35862-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
MR
84237
Start Date:
End Date:03/06/2024 04:47
03/05/2024 13:59
BFB 140-84237/1 RTX-5 0.32(mm)103/05/2024 13:59 RZC05BFB.D
IC 140-84237/3 RTX-5 0.32(mm)103/05/2024 15:18 RZC05L10.D
IC 140-84237/5 RTX-5 0.32(mm)103/05/2024 16:55 RZC05L9.D
IC 140-84237/7 RTX-5 0.32(mm)103/05/2024 18:30 RZC05L8.D
IC 140-84237/9 RTX-5 0.32(mm)103/05/2024 20:04 RZC05L1.D
IC 140-84237/10 RTX-5 0.32(mm)103/05/2024 20:51 RZC05L2.D
ZZZZZ RTX-5 0.32(mm)103/05/2024 20:51
ZZZZZ RTX-5 0.32(mm)103/05/2024 20:51
IC 140-84237/11 RTX-5 0.32(mm)103/05/2024 21:39 RZC05L3.D
ZZZZZ RTX-5 0.32(mm)103/05/2024 21:39
ZZZZZ RTX-5 0.32(mm)103/05/2024 21:39
IC 140-84237/12 RTX-5 0.32(mm)103/05/2024 22:24 RZC05L4.D
ZZZZZ RTX-5 0.32(mm)103/05/2024 22:24
ZZZZZ RTX-5 0.32(mm)103/05/2024 22:24
IC 140-84237/13 RTX-5 0.32(mm)103/05/2024 23:11 RZC05L5.D
ZZZZZ RTX-5 0.32(mm)103/05/2024 23:11
ZZZZZ RTX-5 0.32(mm)103/05/2024 23:11
IC 140-84237/14 RTX-5 0.32(mm)103/05/2024 23:59 RZC05L6.D
ICIS 140-84237/15 RTX-5 0.32(mm)103/06/2024 00:47 RZC05ICIS7.D
ICV 140-84237/17 RTX-5 0.32(mm)103/06/2024 02:20 RZC05LCS.D
ZZZZZ RTX-5 0.32(mm)103/06/2024 04:47
TO-15
3/25/2024
9:50:51 AM
Page 839 of 864
3/25/2024
9:50:51 AM
Page 840 of 864
Eurofins Knoxville GC/MS Air - Initial Calibration Data Review Checklist
Methods: TO-14 and TO-15 - KNOX-MS-0001, Rev 23 & KNOX-MS-0023, Rev 6

MS017r53, 08/28/2023
Analysis Date: 3/5/24 Instrument: MR Chrom WL #: 31853
TALS
Batch &
Event #
TO14/15: 84237/4937 DOD5: 84240/4940
DOD: 84238/4938 OHIO: 84239/4939
Chrom/Worklist Review 1st Comments 2nd
1. Re-read each Limit Group [method editor-limit groups] na
2. Verify LODV in Chrom [method editor -> edit -> MDL] na
3. Are the reagents and init/final volumes correct and first level “unlock/clear”?
(Verify reagents & amt. injected at each level)
Y
4. Files linked properly to calibration levels? [Sample List- Lab ID vs. Info] Y
5. Did BFB meet tune criteria? [F8] Y
6. Were all standards injected within 24 hr of BFB? [F7] Y
7. High point checked for saturation and point removed if so? [Chrom] Y
8. If manual integrations performed, are they properly performed, correct, baseline
clearly identified, and correct reason given? [Chrom]
NA
9. RT for each IS +20 sec avg. RT? [F6 IstdRec] Y
10. Area for each IS + 40% avg. area? [F6 IstdRec] Y
11. Each analyte + 0.06 RRT of avg. RRT? [F6 - RRT] Y
12. Elution order checked on isomeric pairs? [Chrom]
 dichlorodifluoromethane / 1,2-dichlorotetrafluoroethane Y
 2-methyl butane / acrolein Y
 trichlorofluoromethane / 1,1,2-trichlorotrifluoroethane Y
 vinyl acetate / hexane Y
 cis- and trans- isomers Y
 ethyl benzene / m/p-xylene / o-xylene Y
 n-propylbenzene/4-ethyl toluene/1,3,5-trimethylbenzene/1,2,4-
trimethylbenzene/
sec-butylbenzene/1,2,3-trimethylbenzene
Y
 tert-butylbenzene/4-isopropyltoluene Y
 1,3- , 1,4- , and 1,2-dichlorobenzene Y
 1,2-dimethyl-4-ethylbenzene/1,2,4,5-, 1,2,3,5-, and 1,2,3,4-tetramethylbenzenes NA
 1,2,4- and 1,2,3-trichlorobenzenes Y
 2-, and 1-methylnaphthalene Y
13. “Range” analytes & internal standard RIC ID’d correctly, inspected for
interferences & proper integration?
Y
MLG Review TO DOD DOD
5
OH Comments

TO DOD DOD
5
OH
14. Is %RSD for all target analytes < 30%? (with up to 2 compounds with RSD
< 40%) 1& 2 methylnaphthalene < 50% (NONE for DOD5) [F6 ∑ ]
Y Y Y Y
15. Were at least 5 levels of each compound analyzed? [F6] Y Y Y Y
16. Is low level std at or <RL and are the remaining points consec.? [F6] Y Y Y Y
17. At least 6 consec. points used for quad curves; at least 5 consec. points for
linear curves? (Note: Ohio does not allow quad) [F6]
Y Y Y Y
18. If curves were used, is correlation coefficient >0.990? [F6] Y Y Y Y
19. Is the intercept less than the RL for each curve? [F6] Y Y Y Y
20. For quadratic: is a tangent’s slope to the curve entirely positive or negative
and continuous.
na Y Y Y na
21. Is the readback for each point within criteria?
(<40 for all points, low point < 50 %, except CLC/provisionary < 80%)
*bromoform Y Y Y Y
22. Is the second source analysis within limits? [F8 - icv] Y Y Y Y
TALS Review TO DOD DOD
5
OH Comments TO DOD DOD
5
OH
23. Upload ICAL na na na na
24. Graphics uploaded?
[paperclip]
Y Y Y Y
25. All points are in the most recent active calibration event?
[Calibration Events –‘Fix ICAL linkage’ if needed]
Y Y Y Y
26. Runs linked to BFB? [QC Links] Y Y Y Y
27. Run Checklist and acknowledge findings [F8] Y Y Y Y
28. If criteria not met, was a NCM generated? NA NA NA NA
29. After review in TALS, approve the method in TALS. na na na na Y Y Y Y
30. After verifying TALS is correct, lock method in Chrom na na na na Y Y Y Y
31. Checklist scanned, attached & assigned properly? na na na na Y Y Y Y
Analyst/date: 2nd Level Reviewer/date: LL 3/7/2024
Comments:
3/25/2024
9:50:51 AM
Page 841 of 864
Lab Name:Job No.:
AIR - GC/MS VOA ANALYSIS RUN LOG
Eurofins Knoxville 140-35862-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
MR
84584
Start Date:
End Date:03/20/2024 02:42
03/19/2024 07:09
BFB 140-84584/1 RTX-5 0.32(mm)103/19/2024 07:09 RBFBZC19.D
CCVIS 140-84584/2 RTX-5 0.32(mm)103/19/2024 07:40 RCCVZC19.D
LCS 140-84584/1002 RTX-5 0.32(mm)103/19/2024 07:40 -RCCVZC19-LCS.d
ZZZZZ RTX-5 0.32(mm)103/19/2024 08:53
ZZZZZ RTX-5 0.32(mm)103/19/2024 09:44
MB 140-84584/5 RTX-5 0.32(mm)103/19/2024 09:44 RZC19MBA.D
140-35862-1 03072024-1 RTX-5 0.32(mm)4.0103/19/2024 20:19 RZC19P110.D
140-35862-2 03072024-2 RTX-5 0.32(mm)3.9503/19/2024 21:05 RZC19P111.D
140-35862-3 03072024-3 RTX-5 0.32(mm)4.1603/19/2024 21:50 RZC19P112.D
140-35862-4 03072024-4 RTX-5 0.32(mm)4.0103/19/2024 22:36 RZC19P113.D
140-35862-5 03072024-5 RTX-5 0.32(mm)4.4503/19/2024 23:21 RZC19P114.D
ZZZZZ RTX-5 0.32(mm)103/20/2024 00:14
ZZZZZ RTX-5 0.32(mm)103/20/2024 01:06
ZZZZZ RTX-5 0.32(mm)103/20/2024 01:56
ZZZZZ RTX-5 0.32(mm)103/20/2024 02:42
TO-15
3/25/2024
9:50:51 AM
Page 842 of 864
3/25/2024
9:50:51 AM
Page 843 of 864
3/25/2024
9:50:51 AM
Page 844 of 864
Lab Name:Job No.:
AIR - GC/MS VOA ANALYSIS RUN LOG
Eurofins Knoxville 140-35862-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
MR
84603
Start Date:
End Date:03/21/2024 03:19
03/20/2024 06:37
BFB 140-84603/1 RTX-5 0.32(mm)103/20/2024 06:37 RBFBZC20.D
CCVIS 140-84603/2 RTX-5 0.32(mm)103/20/2024 07:06 RCCVZC20.D
LCS 140-84603/1002 RTX-5 0.32(mm)103/20/2024 07:06 -RCCVZC20-LCS.d
ZZZZZ RTX-5 0.32(mm)103/20/2024 08:01
ZZZZZ RTX-5 0.32(mm)103/20/2024 08:52
ZZZZZ RTX-5 0.32(mm)103/20/2024 08:52
MB 140-84603/6 RTX-5 0.32(mm)103/20/2024 08:52 RZC20BLK35930A2
B.D
ZZZZZ RTX-5 0.32(mm)103/20/2024 11:16
ZZZZZ RTX-5 0.32(mm)103/20/2024 12:49
ZZZZZ RTX-5 0.32(mm)103/20/2024 13:35
ZZZZZ RTX-5 0.32(mm)103/20/2024 14:22
ZZZZZ RTX-5 0.32(mm)103/20/2024 15:17
ZZZZZ RTX-5 0.32(mm)103/20/2024 16:11
140-35862-1 03072024-1 RTX-5 0.32(mm)4.0103/20/2024 16:56 RZC20P107.D
140-35862-2 03072024-2 RTX-5 0.32(mm)3.9503/20/2024 17:43 RZC20P108.D
140-35862-3 03072024-3 RTX-5 0.32(mm)4.1603/20/2024 18:30 RZC20P109.D
ZZZZZ RTX-5 0.32(mm)47.0703/20/2024 19:17
ZZZZZ RTX-5 0.32(mm)1.6103/20/2024 20:03
ZZZZZ RTX-5 0.32(mm)1.4803/20/2024 20:52
ZZZZZ RTX-5 0.32(mm)2.0303/20/2024 21:42
ZZZZZ RTX-5 0.32(mm)103/20/2024 22:29
ZZZZZ RTX-5 0.32(mm)103/20/2024 23:17
ZZZZZ RTX-5 0.32(mm)103/21/2024 00:05
ZZZZZ RTX-5 0.32(mm)103/21/2024 00:55
ZZZZZ RTX-5 0.32(mm)4040.8
203/21/2024 01:42
ZZZZZ RTX-5 0.32(mm)103/21/2024 02:33
ZZZZZ RTX-5 0.32(mm)103/21/2024 03:19
ZZZZZ RTX-5 0.32(mm)103/21/2024 03:19
TO-15
3/25/2024
9:50:51 AM
Page 845 of 864
3/25/2024
9:50:51 AM
Page 846 of 864
3/25/2024
9:50:51 AM
Page 847 of 864
Lab Name:Job No.:
AIR - GC/MS VOA ANALYSIS RUN LOG
Eurofins Knoxville 140-35862-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
MS
84641
Start Date:
End Date:03/22/2024 02:01
03/21/2024 06:18
BFB 140-84641/1 RTX-5 0.32(mm)103/21/2024 06:18 SBFBZC21.D
CCVIS 140-84641/2 RTX-5 0.32(mm)103/21/2024 06:46 SCCVZC21.D
LCS 140-84641/1002 RTX-5 0.32(mm)103/21/2024 06:46 -SCCVZC21-LCS.d
ZZZZZ RTX-5 0.32(mm)103/21/2024 08:06
MB 140-84641/5 RTX-5 0.32(mm)103/21/2024 08:06 SZC21CAN11296MB
A.D
ZZZZZ RTX-5 0.32(mm)103/21/2024 10:11
ZZZZZ RTX-5 0.32(mm)72.6503/21/2024 11:02
ZZZZZ RTX-5 0.32(mm)64.0803/21/2024 11:53
ZZZZZ RTX-5 0.32(mm)198.6403/21/2024 13:38
ZZZZZ RTX-5 0.32(mm)65.3103/21/2024 14:29
ZZZZZ RTX-5 0.32(mm)206.3203/21/2024 15:22
ZZZZZ RTX-5 0.32(mm)3612.2
403/21/2024 16:19
ZZZZZ RTX-5 0.32(mm)95.103/21/2024 17:11
140-35862-4 03072024-4 RTX-5 0.32(mm)4.0103/21/2024 18:00 SZC21P109.D
140-35862-5 03072024-5 RTX-5 0.32(mm)4.4503/21/2024 18:50 SZC21P110.D
ZZZZZ RTX-5 0.32(mm)103/21/2024 21:27
ZZZZZ RTX-5 0.32(mm)103/21/2024 22:22
ZZZZZ RTX-5 0.32(mm)103/21/2024 23:17
ZZZZZ RTX-5 0.32(mm)103/22/2024 00:12
ZZZZZ RTX-5 0.32(mm)103/22/2024 01:06
ZZZZZ RTX-5 0.32(mm)103/22/2024 02:01
TO-15
3/25/2024
9:50:51 AM
Page 848 of 864
Eurofins Knoxville GC/MS Air - Batch Data Review Checklist
Methods: TO-14 and TO-15 - KNOX-MS-0001, Rev 23 & KNOX-MS-0023, Rev 6

MS017r53, 08/28/2023
Instrument/Date Routine DOD DOD5 OHIO VAP
CCAL Chrom
WL # CCAL Batch #
ICAL Chrom
WL # ICAL Batch # /
Event # / / / /
Chrom Review 1st If No, why is data reportable? 2nd
1. Are the reagents & init/final volumes correct? (Verify reagents &
amt. injected) [WL Sample Reagent Tab]
na
2. Did BFB meet tune criteria? [F8] □ [Failed TO-14A, but passes TO-15]
3. Was the CCAL compared to the most recent & correct ICAL
(correct last ICal File batch #/start/end Cal date/time)? [F8]
List Target analytes outside CCV limits:
___________________________________________________
___________________________________________________
________________________________________________

4. Elution order checked on isomeric pairs? [Chrom]
 dichlorodifluoromethane / 1,2-dichlorotetrafluoroethane
 2-methyl butane / acrolein
 trichlorofluoromethane / 1,1,2-trichlorotrifluoroethane
 vinyl acetate / hexane
 cis- and trans- isomers
 ethyl benzene / m/p-xylene / o-xylene
 n-propylbenzene/4-ethyl toluene/1,3,5-trimethylbenzene/1,2,4-
trimethylbenzene/sec-butylbenzene/1,2,3-trimethylbenzene

 tert-butylbenzene/4-isopropyltoluene
 1,3- , 1,4- , and 1,2-dichlorobenzene
 1,2-dimethyl-4-ethylbenzene/1,2,4,5-, 1,2,3,5-, and 1,2,3,4-
tetramethylbenzenes

 1,2,4-trichlorobenzene/1,2,3-trichlorobenzene
 2-, and 1-methylnaphthalene
5. “Range” analytes & internal standard RIC ID’d correctly,
inspected for interferences & proper integration?

6. Has the RT been updated to the method?
Analyst/date 2nd Level Reviewer/date
7. Was an instrument leak check performed successfully?
8. Has the vol injected been verified vs Entech & corrected if actual
amount differs >5%?
[WL Sample Info: init amt = sample amt; final amt = 500 mL]

9. Do the lab ID, Info 1 and Dilution Factor columns correlate in
Chrom? [Sample List - Lab ID vs. Info 1 vs. Dilution]

10. Can dilution history verified? [Mgmt Report]
11. Are all analytes present in the system blank < RL? (<1/2 RL for
DoD). If no, list blank ID:
□ Method Blank – Report, ND (NCM#_____)
□ Method Blank – Report, 10X (NCM#_____)
□ Method Blank –Report >MDL <RL/PQL (NCM#_____)

12. All runs - peaks ID’d correctly and false positives removed?
13. If manual integrations performed, are they properly performed,
baseline clearly identified, and correct reason given?

14. IS/Surr within limits? List samples and reason (e.g., 1 thru 5):
[Batch Results IS & SUR Tab]
Sample Reason Sample Reason
__________ ________ __________ ________
__________ ________ __________ ________
□ (1) Surrogate – Matrix (NCM#_____)
□ (2) Surrogate – High, ND (NCM#_____)
□ (3) ISTD – RA/RA Concurs (NCM#_____)
□ (4) Surrogate –RX concur, Report both (NCM#_____)
□ (5) ISTD – Matrix, DL required (NCM#_____)

15. Samples outside calibration range scheduled for dilution? □ ICAL – Range Exceeded; Minimum Dilution
Chrom Review 1st If No, why is data reportable? 2nd
16. For first analysis that is at a dilution, is highest target analyte
>20% cal range?
List samples and reason:
Sample Reason Sample Reason
__________ ________ ________ __________
__________ ________ ________ __________
□ (1) Reporting Limit – Dilution, Matrix (NCM#_____)
□ (2) Reporting Limit – Dilution, Non-Target (NCM#_____)
□ (3) Issues with initial collection volume; see DRC.

17. RIC inspected for proper integration for TPH?
18. Obvious non-TPH peaks excluded?
19. Individual TPH peak area < octane high point area?
Ms 3/21/2024
32009 84641
3)497 83168 4892
-
/-
-ethano
V
E
1
NA
-
Supe tal 3/22/2024
-
-
/
/
-
-
-
-
NA
/
#12 limited vol NCM 5 4100
it
3/25/2024
9:50:51 AM
Page 849 of 864
Eurofins Knoxville GC/MS Air - Batch Data Review Checklist
Methods: TO-14 and TO-15 - KNOX-MS-0001, Rev 23 & KNOX-MS-0023, Rev 6

MS017r53, 08/28/2023

TALS Review

1st

If No, why is data reportable?

2nd
20. Graphics uploaded? [open one paperclip]
21. NCM generated if BFB failed TO-14A criteria, but passes TO-15? □ [Failed TO-14A, but passes TO-15] (NCM#__________)
22. Is the %D ≤ 30% for all target analytes?
[< 50% for 1&2 methylnaphthalene]
No LCS variances are allowed for DoD5
[Chrom-F8] [TALS-Sample Results Tab]
□ CCV - %D - LCS criteria met (NCM#_________________)
□ CCV - %D high - outside criteria, samples ND, Sample IDs
Included (NCM#___________________________________)

23. Undiluted volume analyzed meets the method requirement (200
mL vs. 500 mL)?

na
24. Did alternative units calculate correctly?
(“ug/m3 (Air)” should not be used for this method)

25. Project & sample special instructions verified?
26. If samples were Tedlar bags, was the 72 hr HT met?
** Narrate transfer to can.
□ Air Analysis - Air Sample Transfer to Canister (NCM#____)
27. Sample analyses done within analytical holding time? □ Holding Time – Received w/Insufficient Time (NCM#_____)
□ Holding Time – Receipt (NCM#________)

28. Did the LCS meet criteria (70-130% with a limited # allowed 60-
140% (see table) provisional analyte limit 60-140% with a limited
# allowed 50-150%, and no two consecutive MEs).
[Sample Results Tab]
Note: No LCS required for OH VAP.
Number of target analytes in
LCS
# marginal exceedances of
LCS
control limits allowed
>90 5
71 - 90 4
51 - 70 3
31 - 50 2
11 - 30 1
< 11 0

□ Marginal Exceedances - Within ME Limits and Random;
Report (NCM# ___)
□ LCS/LCSD - %R High (NCM#_____)

29. Suffixes assigned properly (DL/RE)? [Sample List Tab]
30. Each job has QC created (BFB, CCV, LCS, MB)?
[Sample List Tab]

31. Analytes over calibration range set to secondary
[Conditions Review Tab]

32. Samples not reported set to ‘Acceptable’ or ‘Rejected’?
[Sample Results Tab]

33. DUP done per 20 samples and are all RPDs within limits? (for
target analytes >5x RL, <25% RPD; no criteria for n-butanol)
(If DUP not reported - set to ‘Acceptable’ for each job)

34. Samples linked to proper blank (200 mL or 500 mL)? [QC links] 500 mL blank ID: ______ 200 mL blank ID: ________
35. Samples linked to job’s BFB/CCV/LCS/MB? [QC Links]
36. Correct ICV linked to each MB and all the samples? [QC Links]
37. Were all samples/QC analyzed within 24 hr of BFB? [F7]
38. If criteria were not met, was a NCM generated, and assigned to
proper QC & samples? [Also see Conditions Review Tab]

39. Run Checklist and acknowledge findings [F8]
40. Runs set to 1st level review? Runs set to 2nd level review?
41. QC checker run and items addressed? -na-
42. Checklist scanned, attached & assigned properly?

Analyst: Date: 2nd Level Reviewer : Date:
Comments: Comments:

Example Calculation:
On-column ppbv x Final Vol (mL)/Entech Initial Vol (mL) x Canister Dilution Log DF

--53958
--54099
/
NA
--53764
-
-
-
-
NA
-
I
E #4 #5
-
/
/
-
Supter th 3/22/2024
140 -35862 -4 IPA
34 .48176 x 500/40 +4 .01 =28
3/25/2024
9:50:51 AM
Page 850 of 864
Eurofins Knoxville GC/MS Air - Batch Data Review Checklist
Methods: TO-14 and TO-15 - KNOX-MS-0001, Rev 23 & KNOX-MS-0023, Rev 6

MS017r53, 08/28/2023
Instrument/Date MS 3/21/2024 Routine DOD DOD5 OHIO VAP
CCAL Chrom
WL # 32009 CCAL Batch # 84641 NA
ICAL Chrom
WL # 31497 ICAL Batch # /
Event # 83168/4892 / / 83170/4894
Chrom Review 1st If No, why is data reportable? 2nd
1. Are the reagents & init/final volumes correct? (Verify reagents &
amt. injected) [WL Sample Reagent Tab]
na
2. Did BFB meet tune criteria? [F8] □ [Failed TO-14A, but passes TO-15] N
3. Was the CCAL compared to the most recent & correct ICAL
(correct last ICal File batch #/start/end Cal date/time)? [F8]
List Target analytes outside CCV limits:
___________________________________________________
___________________________________________________
________________________________________________
Y
4. Elution order checked on isomeric pairs? [Chrom]
 dichlorodifluoromethane / 1,2-dichlorotetrafluoroethane Y
 2-methyl butane / acrolein Y
 trichlorofluoromethane / 1,1,2-trichlorotrifluoroethane Y
 vinyl acetate / hexane Y
 cis- and trans- isomers Y
 ethyl benzene / m/p-xylene / o-xylene Y
 n-propylbenzene/4-ethyl toluene/1,3,5-trimethylbenzene/1,2,4-
trimethylbenzene/sec-butylbenzene/1,2,3-trimethylbenzene
Y
 tert-butylbenzene/4-isopropyltoluene Y
 1,3- , 1,4- , and 1,2-dichlorobenzene Y
 1,2-dimethyl-4-ethylbenzene/1,2,4,5-, 1,2,3,5-, and 1,2,3,4-
tetramethylbenzenes
Y
 1,2,4-trichlorobenzene/1,2,3-trichlorobenzene Y
 2-, and 1-methylnaphthalene Y
5. “Range” analytes & internal standard RIC ID’d correctly,
inspected for interferences & proper integration?
Y
6. Has the RT been updated to the method? Y
Analyst/date 2nd Level Reviewer/date: LL 3/22/2024
7. Was an instrument leak check performed successfully?
8. Has the vol injected been verified vs Entech & corrected if actual
amount differs >5%?
[WL Sample Info: init amt = sample amt; final amt = 500 mL]
Y
9. Do the lab ID, Info 1 and Dilution Factor columns correlate in
Chrom? [Sample List - Lab ID vs. Info 1 vs. Dilution]

Y
10. Can dilution history verified? [Mgmt Report] Y
11. Are all analytes present in the system blank < RL? (<1/2 RL for
DoD). If no, list blank ID:
□ Method Blank – Report, ND (NCM#_____)
□ Method Blank – Report, 10X (NCM#_____)
□ Method Blank –Report >MDL <RL/PQL (NCM#_____)
Y
12. All runs - peaks ID’d correctly and false positives removed? Y
13. If manual integrations performed, are they properly performed,
baseline clearly identified, and correct reason given?
Y
14. IS/Surr within limits? List samples and reason (e.g., 1 thru 5):
[Batch Results IS & SUR Tab]
Sample Reason Sample Reason
__________ ________ __________ ________
__________ ________ __________ ________
□ (1) Surrogate – Matrix (NCM#_____)
□ (2) Surrogate – High, ND (NCM#_____)
□ (3) ISTD – RA/RA Concurs (NCM#_____)
□ (4) Surrogate –RX concur, Report both (NCM#_____)
□ (5) ISTD – Matrix, DL required (NCM#_____)
Y
15. Samples outside calibration range scheduled for dilution? □ ICAL – Range Exceeded; Minimum Dilution NA
Chrom Review 1st If No, why is data reportable? 2nd
16. For first analysis that is at a dilution, is highest target analyte
>20% cal range?
List samples and reason:
Sample Reason Sample Reason
__________ ________ ________ __________
__________ ________ ________ __________
□ (1) Reporting Limit – Dilution, Matrix (NCM#_____)
□ (2) Reporting Limit – Dilution, Non-Target (NCM#_____)
□ (3) Issues with initial collection volume; see DRC.
Y
17. RIC inspected for proper integration for TPH? Y
18. Obvious non-TPH peaks excluded? Y
19. Individual TPH peak area < octane high point area? Y
3/25/2024
9:50:51 AM
Page 851 of 864
Eurofins Knoxville GC/MS Air - Batch Data Review Checklist
Methods: TO-14 and TO-15 - KNOX-MS-0001, Rev 23 & KNOX-MS-0023, Rev 6

MS017r53, 08/28/2023

TALS Review

1st

If No, why is data reportable?

2nd
20. Graphics uploaded? [open one paperclip] Y
21. NCM generated if BFB failed TO-14A criteria, but passes TO-15? □ [Failed TO-14A, but passes TO-15] (NCM#__________) Y
22. Is the %D ≤ 30% for all target analytes?
[< 50% for 1&2 methylnaphthalene]
No LCS variances are allowed for DoD5
[Chrom-F8] [TALS-Sample Results Tab]
□ CCV - %D - LCS criteria met (NCM#_________________)
□ CCV - %D high - outside criteria, samples ND, Sample IDs
Included (NCM#___________________________________)
Y
23. Undiluted volume analyzed meets the method requirement (200
mL vs. 500 mL)?

na
24. Did alternative units calculate correctly?
(“ug/m3 (Air)” should not be used for this method)
Y
25. Project & sample special instructions verified? Y
26. If samples were Tedlar bags, was the 72 hr HT met?
** Narrate transfer to can.
□ Air Analysis - Air Sample Transfer to Canister (NCM#____) Y
27. Sample analyses done within analytical holding time? □ Holding Time – Received w/Insufficient Time (NCM#_____)
□ Holding Time – Receipt (NCM#________)
Y
28. Did the LCS meet criteria (70-130% with a limited # allowed 60-
140% (see table) provisional analyte limit 60-140% with a limited
# allowed 50-150%, and no two consecutive MEs).
[Sample Results Tab]
Note: No LCS required for OH VAP.
Number of target analytes in
LCS
# marginal exceedances of
LCS
control limits allowed
>90 5
71 - 90 4
51 - 70 3
31 - 50 2
11 - 30 1
< 11 0

□ Marginal Exceedances - Within ME Limits and Random;
Report (NCM# ___)
□ LCS/LCSD - %R High (NCM#_____)
Y
29. Suffixes assigned properly (DL/RE)? [Sample List Tab] Y
30. Each job has QC created (BFB, CCV, LCS, MB)?
[Sample List Tab]
Y
31. Analytes over calibration range set to secondary
[Conditions Review Tab]
NA
32. Samples not reported set to ‘Acceptable’ or ‘Rejected’?
[Sample Results Tab]
Y
33. DUP done per 20 samples and are all RPDs within limits? (for
target analytes >5x RL, <25% RPD; no criteria for n-butanol)
(If DUP not reported - set to ‘Acceptable’ for each job)
Y
34. Samples linked to proper blank (200 mL or 500 mL)? [QC links] 500 mL blank ID: __4__ 200 mL blank ID: 5_ Y
35. Samples linked to job’s BFB/CCV/LCS/MB? [QC Links] Y
36. Correct ICV linked to each MB and all the samples? [QC Links] Y
37. Were all samples/QC analyzed within 24 hr of BFB? [F7] Y
38. If criteria were not met, was a NCM generated, and assigned to
proper QC & samples? [Also see Conditions Review Tab]
NA
39. Run Checklist and acknowledge findings [F8] Y
40. Runs set to 1st level review? Runs set to 2nd level review? Y
41. QC checker run and items addressed? -na- Y
42. Checklist scanned, attached & assigned properly? Y

Analyst: Date: 2nd Level Reviewer : LL Date: 3/22/2024
Comments: Comments:

Example Calculation:
On-column ppbv x Final Vol (mL)/Entech Initial Vol (mL) x Canister Dilution Log DF

3/25/2024
9:50:51 AM
Page 852 of 864
Lab Name:Job No.:
SDG No.:
AIR - GC/MS VOA BATCH WORKSHEET
140-35862-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Barlozhetskaya, Anna F02/07/24 14:0683168
Batch Method:
Eurofins Knoxville
TO-15
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount 40CV101S 00252 40L1-3DQP
00099
40L10DQP 00052 40L4DQP 00063Matrix
500 mL 500 mLTO-15BFB 140-83168/1
500 mL 500 mL 200 mLTO-15IC 140-83168/3
500 mL 500 mLTO-15IC 140-83168/5
500 mL 500 mLTO-15IC 140-83168/7
500 mL 500 mL 50 mLTO-15IC 140-83168/9
500 mL 500 mL 100 mLTO-15IC 140-83168/10
500 mL 500 mL 200 mLTO-15IC 140-83168/11
500 mL 500 mL 200 mLTO-15IC 140-83168/12
500 mL 500 mLTO-15IC 140-83168/13
500 mL 500 mLTO-15IC 140-83168/14
500 mL 500 mLTO-15ICIS
140-83168/15
500 mL 500 mL 80 mLTO-15ICV
140-83168/18
Lab Sample ID Client Sample
ID
Method Chain Basis 40L5DQP 00053 40L6DQP 00050 40L7DQP 00050 40L8DQP 00049 40L9DQP 00051 40MXBFB 00004Matrix
40 mLTO-15BFB 140-83168/1
TO-15IC 140-83168/3
200 mLTO-15IC 140-83168/5
200 mLTO-15IC 140-83168/7
TO-15IC 140-83168/9
TO-15IC 140-83168/10
TO-15IC 140-83168/11
TO-15IC 140-83168/12
200 mLTO-15IC 140-83168/13
200 mLTO-15IC 140-83168/14
200 mLTO-15ICIS
140-83168/15
TO-15ICV
140-83168/18
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 2TO-15
3/25/2024
9:50:51 AM
Page 853 of 864
Lab Name:Job No.:
SDG No.:
AIR - GC/MS VOA BATCH WORKSHEET
140-35862-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Barlozhetskaya, Anna F02/07/24 14:0683168
Batch Method:
Eurofins Knoxville
TO-15
Lab Sample ID Client Sample
ID
Method Chain Basis 40MXISSUR
00004
Matrix
TO-15BFB 140-83168/1
40 mLTO-15IC 140-83168/3
40 mLTO-15IC 140-83168/5
40 mLTO-15IC 140-83168/7
40 mLTO-15IC 140-83168/9
40 mLTO-15IC 140-83168/10
40 mLTO-15IC 140-83168/11
40 mLTO-15IC 140-83168/12
40 mLTO-15IC 140-83168/13
40 mLTO-15IC 140-83168/14
40 mLTO-15ICIS
140-83168/15
40 mLTO-15ICV
140-83168/18
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 2TO-15
3/25/2024
9:50:51 AM
Page 854 of 864
Lab Name:Job No.:
SDG No.:
AIR - GC/MS VOA BATCH WORKSHEET
140-35862-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Royce, Robert D03/05/24 13:5984237
Batch Method:
Eurofins Knoxville
TO-15
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount 40CV101S 00253 40L1-3DQP
00099
40L10DQP 00052 40L5DQP 00053Matrix
500 mL 500 mLTO-15BFB 140-84237/1
500 mL 500 mL 200 mLTO-15IC 140-84237/3
500 mL 500 mLTO-15IC 140-84237/5
500 mL 500 mLTO-15IC 140-84237/7
500 mL 500 mL 50 mLTO-15IC 140-84237/9
500 mL 500 mL 100 mLTO-15IC 140-84237/10
500 mL 500 mL 200 mLTO-15IC 140-84237/11
500 mL 500 mL 80 mLTO-15IC 140-84237/12
500 mL 500 mL 200 mLTO-15IC 140-84237/13
500 mL 500 mLTO-15IC 140-84237/14
500 mL 500 mLTO-15ICIS
140-84237/15
500 mL 500 mL 80 mLTO-15ICV
140-84237/17
Lab Sample ID Client Sample
ID
Method Chain Basis 40L6DQP 00050 40L7DQP 00050 40L8DQP 00049 40L9DQP 00051 40MXBFB 00004 40MXISSUR
00004
Matrix
40 mLTO-15BFB 140-84237/1
40 mLTO-15IC 140-84237/3
200 mL 40 mLTO-15IC 140-84237/5
200 mL 40 mLTO-15IC 140-84237/7
40 mLTO-15IC 140-84237/9
40 mLTO-15IC 140-84237/10
40 mLTO-15IC 140-84237/11
40 mLTO-15IC 140-84237/12
40 mLTO-15IC 140-84237/13
200 mL 40 mLTO-15IC 140-84237/14
200 mL 40 mLTO-15ICIS
140-84237/15
40 mLTO-15ICV
140-84237/17
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
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Lab Name:Job No.:
SDG No.:
AIR - GC/MS VOA BATCH WORKSHEET
140-35862-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Royce, Robert D03/05/24 13:5984237
Batch Method:
Eurofins Knoxville
TO-15
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 2TO-15
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Page 856 of 864
Lab Name:Job No.:
SDG No.:
AIR - GC/MS VOA BATCH WORKSHEET
140-35862-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Khachitpongpanit, Suphawana 103/19/24 07:0984584
Batch Method:
Eurofins Knoxville
TO-15
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount 40CV101S 00253 40MXBFB 00004 40MXISSUR
00004
Matrix
500 mL 500 mL 40 mLTO-15BFB 140-84584/1
500 mL 500 mL 80 mL 40 mLTO-15CCVIS
140-84584/2
200 mL 500 mL 40 mLTO-15MB 140-84584/5
03072024-1 40 mL 500 mL 40 mLTO-15 T140-35862-A-1 Air
03072024-2 40 mL 500 mL 40 mLTO-15 T140-35862-A-2 Air
03072024-3 40 mL 500 mL 40 mLTO-15 T140-35862-A-3 Air
03072024-4 40 mL 500 mL 40 mLTO-15 T140-35862-A-4 Air
03072024-5 50 mL 500 mL 40 mLTO-15 T140-35862-A-5 Air
500 mL 500 mL 80 mL 40 mLTO-15LCS
140-84584/1002
Batch Notes
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 1TO-15
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Page 857 of 864
Lab Name:Job No.:
SDG No.:
AIR - GC/MS VOA BATCH WORKSHEET
140-35862-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Khachitpongpanit, Suphawana 103/20/24 06:3784603
Batch Method:
Eurofins Knoxville
TO-15
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount 40CV101S 00253 40MXBFB 00004 40MXISSUR
00004
Matrix
500 mL 500 mL 40 mLTO-15BFB 140-84603/1
500 mL 500 mL 80 mL 40 mLTO-15CCVIS
140-84603/2
200 mL 500 mL 40 mLTO-15MB 140-84603/6
03072024-1 10 mL 500 mL 40 mLTO-15 T140-35862-A-1 Air
03072024-2 10 mL 500 mL 40 mLTO-15 T140-35862-A-2 Air
03072024-3 20 mL 500 mL 40 mLTO-15 T140-35862-A-3 Air
500 mL 500 mL 80 mL 40 mLTO-15LCS
140-84603/1002
Batch Notes
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 1TO-15
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Page 858 of 864
Lab Name:Job No.:
SDG No.:
AIR - GC/MS VOA BATCH WORKSHEET
140-35862-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Khachitpongpanit, Suphawana 103/21/24 06:1884641
Batch Method:
Eurofins Knoxville
TO-15
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount 40CV101S 00252 40MXBFB 00004 40MXISSUR
00004
Matrix
500 mL 500 mL 40 mLTO-15BFB 140-84641/1
500 mL 500 mL 80 mL 40 mLTO-15CCVIS
140-84641/2
200 mL 500 mL 40 mLTO-15MB 140-84641/5
03072024-4 40 mL 500 mL 40 mLTO-15 T140-35862-A-4 Air
03072024-5 50 mL 500 mL 40 mLTO-15 T140-35862-A-5 Air
500 mL 500 mL 80 mL 40 mLTO-15LCS
140-84641/1002
Batch Notes
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 1TO-15
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Page 859 of 864
Summa Canister Dilution Worksheet
Job No.: 140-35862-1Client: Clean Harbors Environmental Services Inc
Project/Site: Carbon Beds Test
Canister Preadjusted
Lab Sample ID (L)("Hg)(atm)(L)(psig)(atm)(L)Factor Factor Date Analyst Initals
Volume Pressure
Preadjusted Adjusted
Pressure
Preadjusted
Volume Pressure
Adjusted
Pressure
Adjusted
Volume Dilution
Final
Dilution
Initial
Volume
(mL)
140-35862-1 6 0.77 4.64-6.8 03/18/24 8:444.014.013.1030.9 18.61
ID
Pressure
Gauge
G5 ACE
140-35862-2 6 0.79 4.72-6.4 03/18/24 8:583.953.953.1030.9 18.61 G5 ACE
140-35862-3 6 0.74 4.44-7.8 03/18/24 9:004.164.163.0730.5 18.45 G5 ACE
140-35862-4 6 0.80 4.78-6.1 03/18/24 9:024.014.013.1932.2 19.14 G5 ACE
140-35862-5 6 0.75 4.50-7.5 03/13/24 12:121.501.501.121.8 6.73 G5 ACE
140-35862-5 6 1.03 6.180.9 03/18/24 9:034.452.973.0630.3 18.37 G5 ACE
Formulae:
Preadjusted Volume (L)= ((Preadjusted Pressure ("Hg) + 29.92 "Hg) * Vol L ) / 29.92 "Hg
Adjusted Volume (L) = (( Adjusted Pressure (psig) + 14.7 psig )* Vol L ) / 14.7 psig
Dilution Factor = Adjusted Volume (L) / Preadjusted Volume (L)
Where:
29.92 "Hg = Standard atmospheric pressure in inches of Mercury (“Hg)
14.7 psig = Standard atmospheric pressure in pounds per square inch gauge (psig)
Eurofins Knoxville
3/25/2024
9:50:51 AM
Page 860 of 864
Shipping and
Receiving
Documents
3/25/2024
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Gauge ID:G5
Date/Time:3/13/24 1209
Analyst Sample ID
Pressure @ Receipt
(-in Hg or +psig)/initial
pressurisation (if applicable) Asset #Cleaning Job
Cert
Type
Size
(L)Comments
ACE 140-35862-a-1 -5.6 11605 140-35186-a-12 B 6
ACE 140-35862-a-2 -5.3 10809 140-35186-a-14 B 6
ACE 140-35862-a-3 -6.8 34002161 140-35186-a-10 B 6
ACE 140-35862-a-4 -5.1 11995 140-35186-a-15 B 6
ACE 140-35862-a-5 -7.5/+1.8 11198 140-35186-a-6 B 6
Eurofins Knoxville - Air Canister Initial Pressure Check
140-35862-a-1 MS038 r16, 2/12/223/25/2024
9:50:51 AM
Page 864 of 864
Sampler:Bryan Lunt
Sample ID Batch ID Can #Cleaning/Cert
Date
Before Sample
Vacuum
Ending
Vacuum Analyst Project ID Method Date Beginning
Time Ending Time Difference Time (hr)Flow
Control#
03072024-1 140-35862-1 11605 -24 -3 Carbon Bed TO-15 3/7/2024 10:10 11:20 1:10 1.2 11091
03072024-2 140-35862-1 10809 -26 -3 Carbon Bed TO-15 3/7/2024 11:25 12:40 1:15 1.3 11103
03072024-3 140-35862-1 3400216 -21 -4 Carbon Bed TO-15 3/7/2024 12:50 13:55 1:05 1.1 10907
03072024-4 140-35862-1 11995 -25 -5 Carbon Bed TO-15 3/7/2024 14:00 15:25 1:25 1.4 7485
03072024-5 140-35862-1 11198 -24 -5 Carbon Bed TO-15 3/7/2024 15:30 16:30 1:00 1.0 7224
Start Stop
Temperature °F 35 40
Pressure 25.76 25.76 Sea level pressure (in HG)
Velocity Traverse Data (Subpart CC Compliance)
Location:Near Carbon Beds Date of Test:3/7/24 FV = Qo-QI/An
Time started: 7:45 AM Qo 1117 SCFPM
Qi 0 SCFPM
Meadured Duct Radius, in:6.84 An 5.5 ft^2
Cross Sectional Area, ft^2:1.019506 FV=202 fpm
Technicians:Kenneth Banks
*Port #
1
1
1
1
1
1
1
1
1
1
ft/min
SCFPM
The VF must at least be 200 fpm or greater
*this is a referance point and not all ports are used during sampling
Time ended:8:00 AM
*Traverse of Port #Inches from port Measurment (ft/min)Comments:
West 13.3 1673
West 12.6 1484
West 11.7 1335
West 10.6 1224
West 9.0 1185
West 6.5 1080
West 5.7 908
West 4.8 803
West 3.7 676
West 2.2 588
Average Standard Velocity 1095.60
Standard Volumetric Flow Rate 1116.97
Port #2
P
o
Port #4
Port #1
2024 Aragonite Backup Vent System Analyses
Backup Vent System Analysis
Date Sampled 3/7/2024 3/7/2024 3/7/2024 3/7/2024 3/7/2024 Average Maximum Model use
Model
assumption
Time Sampled 10:10 11:25 12:50 14:00 15:30
Name of Sample 03072024-1 03072024-2 03072024-3 03072024-4 03072024-5
Units ppbv ppbv ppbv ppbv ppbv ppbv ppbv ppbv ppbv
Compound
1,1,1-Trichloroethane 3.6 4.1 3.3 2.2 2 3.04 4.1 4.1 43.1
1,1,2,2-Tetrachloroethane 0 0 0 0 0 0 0 0
1,1,2-Trichloro-1,2,2-trifluoroethane 1 0.95 0.7 0.5 0.43 0.716 1 1
1,1,2-Trichloroethane 0 0 0 0 0 0 0 0
1,1-Dichloroethane 20 23 18 11 9.7 16.34 23 23
1,1-Dichloroethene 0 0 0 0 0 0 0 0
1,2,3-Trimethylbenzene 4.6 8.3 9.8 9.5 7.9 8.02 9.8 9.8
1,2,4-Trichlorobenzene 0 0 0 0 0 0 0 0
1,2,4-Trimethylbenzene 18 30 35 34 27 28.8 35 35
1,2-Dibromoethane (EDB)0 0 0 0 0 0 0 0
1,2-Dichloro-1,1,2,2-tetrafluoroethane 0 0 0 0 0 0 0 0
1,2-Dichlorobenzene 0 0 0 0 0 0 0 0
1,2-Dichloroethane 0 0 0 0 0 0 0 0
1,2-Dichloropropane 0 0 0 0 0 0 0 0
1,3,5-Trimethylbenzene 6.6 11 13 11 10 10.32 13 13
1,3-Butadiene 0 0 0 0 0 0 0 0
1,3-Dichlorobenzene 0 0 0 0 0 0 0 0
1,4-Dichlorobenzene 0 0 0 0 0 0 0 0
2-Butanone (MEK)160 210 200 150 150 174 210 210 395
2-Hexanone 0 0 0 0 0 0 0 0
4-Ethyltoluene 5.2 8.5 9.8 9.9 9 8.48 9.9 9.9
4-Methyl-2-pentanone (MIBK)43 55 42 30 37 41.4 55 55
Acetone 140 180 260 230 230 208 260 260 260
Benzene 150 110 99 81 86 105.2 150 150
Benzyl chloride 0 0 0 0 0 0 0 0
Bromodichloromethane 0 0 0 0 0 0 0 0
Bromoform 0 0 0 0 0 0 0 0
Bromomethane 0 0 0 0 0 0 0 0
Carbon disulfide 0 0 0 0 0 0 0 0
Carbon tetrachloride 0 0 0 0 0 0 0 0 0
Chlorobenzene 0 0 0 0 1.1 0.22 1.1 1.1
Chloroethane 0 0 0 0 0 0 0 0
Chloroform 1.4 0.84 0.8 0.79 0.85 0.936 1.4 1.4
Chloromethane 0 0 0 0 0 0 0 0
cis-1,2-Dichloroethene 49 57 44 27 24 40.2 57 57
cis-1,3-Dichloropropene 0 0 0 0 0 0 0 0
Cyclohexane 99 76 62 47 47 66.2 99 99
Dibromochloromethane 0 0 0 0 0 0 0 0
Dichlorodifluoromethane 0 0 0 0 0 0 0 0
Ethanol 160 160 170 130 150 154 170 170 170
Ethyl acetate 42 18 13 10 11 18.8 42 42
Ethylbenzene 27 26 25 19 18 23 27 27
Hexachlorobutadiene 0 0 0 0 0 0 0 0
Isopropyl alcohol 3500 3300 2300 1700 2000 2560 3500 3500 3500
Methyl tert-butyl ether 0 0 0 0 0 0 0 0
Methylcyclohexane 150 140 110 86 83 113.8 150 150
Methylene Chloride 19 9.3 9 9.1 9.9 11.26 19 19 102.5
m-Xylene & p-Xylene 100 92 91 71 70 84.8 100 100
n-Heptane 190 150 130 92 91 130.6 190 190
n-Hexane 240 170 140 100 100 150 240 240 786
Nonane 44 65 63 49 51 54.4 65 65
o-Xylene 31 30 31 24 24 28 31 31
Styrene 4.1 1.8 1.6 1.3 1.3 2.02 4.1 4.1
Tetrachloroethene 29 39 37 25 25 31 39 39 39
Tetrahydrofuran 0 89 130 72 100 78.2 130 130
Toluene 200 220 190 140 140 178 220 220 599.8
trans-1,2-Dichloroethene 0 0 0 0 0 0 0 0
trans-1,3-Dichloropropene 0 0 0 0 0 0 0 0
Trichloroethene 560 690 600 400 370 524 690 690
Trichlorofluoromethane 0 0 0 0 0 0 0 0
Vinyl acetate 0 0 0 0 0 0 0 0
Vinyl chloride 0 0 0 0 0 0 0 0
Totals:6546.4 5895.4
Amount of Carbon for each bed=4000 lbs
Number of Carbon beds=2
Calgon Carbon Corporation VaporAds Report
Flow (stan. ft^3/min)=1117
VPR=3340
Pressure (atm)=1
70 F 80 F 100 F
Methylene Chloride 0.103 35.83 49.96 59.05
Acetone 0.26 30.91 44.21 51.08
Ethanol 0.17 24.19 36.58 41.29
N-Propanol 3.5 18.72 33.33 36.91
2-Butanone (MEK)0.395 21.40 20.64 20.86
1,1,1-Trichloroethane 0.0431 6.23 6.41 6.91
Tetrachloroethene 0.039 5.39 5.63 6.20
Carbon Tetrachloride 0
Hexane 0.786 4.87 5.10 5.61
Toluene 0.5998 1.55 1.61 1.76
Winter Summer
Usage rates (lbs/day)149.089 229.676
Hour per Carbon Bed =644 418
Days per Carbon Bed 26.83 17.42
Concentration (ppmv)Adsorbent Use Rate (lbs/day)
Assumed 50% RH under all conditions
Sum of Reporting Result Sum of Reporting Result Sample ID
03072024-1 03072024-2 03072024-3 03072024-4 03072024-5 Grand Total Analyte 03072024-1 03072024-2 03072024-3 03072024-4 03072024-5 Grand Total
1,1,1-Trichloroethane 3.6 4.1 3.3 2.2 2 15.2 1,1,1-Trichloroethane 3.6 4.1 3.3 2.2 2 15.2
1,1,2,2-Tetrachloroethane 0 0 0 0 0 0 1,1,2,2-Tetrachloroethane 0 0 0 0 0 0
1,1,2-Trichloro-1,2,2-trifluoroethane 1 0.95 0.7 0.5 0.43 3.58 1,1,2-Trichloro-1,2,2-trifluoroethane 1 0.95 0.7 0.5 0.43 3.58
1,1,2-Trichloroethane 0 0 0 0 0 0 1,1,2-Trichloroethane 0 0 0 0 0 0
1,1-Dichloroethane 20 23 18 11 9.7 81.7 1,1-Dichloroethane 20 23 18 11 9.7 81.7
1,1-Dichloroethene 0 0 0 0 0 0 1,1-Dichloroethene 0 0 0 0 0 0
1,2,3-Trimethylbenzene 4.6 8.3 9.8 9.5 7.9 40.1 1,2,3-Trimethylbenzene 4.6 8.3 9.8 9.5 7.9 40.1
1,2,4-Trichlorobenzene 0 0 0 0 0 0 1,2,4-Trichlorobenzene 0 0 0 0 0 0
1,2,4-Trimethylbenzene 18 30 35 34 27 144 1,2,4-Trimethylbenzene 18 30 35 34 27 144
1,2-Dibromoethane (EDB)0 0 0 0 0 0 1,2-Dibromoethane (EDB)0 0 0 0 0 0
1,2-Dichloro-1,1,2,2-tetrafluoroethane 0 0 0 0 0 0 1,2-Dichloro-1,1,2,2-tetrafluoroethane 0 0 0 0 0 0
1,2-Dichlorobenzene 0 0 0 0 0 0 1,2-Dichlorobenzene 0 0 0 0 0 0
1,2-Dichloroethane 0 0 0 0 0 0 1,2-Dichloroethane 0 0 0 0 0 0
1,2-Dichloropropane 0 0 0 0 0 0 1,2-Dichloropropane 0 0 0 0 0 0
1,3,5-Trimethylbenzene 6.6 11 13 11 10 51.6 1,3,5-Trimethylbenzene 6.6 11 13 11 10 51.6
1,3-Butadiene 0 0 0 0 0 0 1,3-Butadiene 0 0 0 0 0 0
1,3-Dichlorobenzene 0 0 0 0 0 0 1,3-Dichlorobenzene 0 0 0 0 0 0
1,4-Dichlorobenzene 0 0 0 0 0 0 1,4-Dichlorobenzene 0 0 0 0 0 0
2-Butanone (MEK)160 210 200 150 150 870 2-Butanone (MEK)160 210 200 150 150 870
2-Hexanone 0 0 0 0 0 0 2-Hexanone 0 0 0 0 0 0
4-Ethyltoluene 5.2 8.5 9.8 9.9 9 42.4 4-Ethyltoluene 5.2 8.5 9.8 9.9 9 42.4
4-Methyl-2-pentanone (MIBK)43 55 42 30 37 207 4-Methyl-2-pentanone (MIBK)43 55 42 30 37 207
Acetone 140 180 260 230 230 1040 Acetone 140 180 260 230 230 1040
Benzene 150 110 99 81 86 526 Benzene 150 110 99 81 86 526
Benzyl chloride 0 0 0 0 0 0 Benzyl chloride 0 0 0 0 0 0
Bromodichloromethane 0 0 0 0 0 0 Bromodichloromethane 0 0 0 0 0 0
Bromoform 0 0 0 0 0 0 Bromoform 0 0 0 0 0 0
Bromomethane 0 0 0 0 0 0 Bromomethane 0 0 0 0 0 0
Carbon disulfide 0 0 0 0 0 0 Carbon disulfide 0 0 0 0 0 0
Carbon tetrachloride 0 0 0 0 0 0 Carbon tetrachloride 0 0 0 0 0 0
Chlorobenzene 0 0 0 0 1.1 1.1 Chlorobenzene 0 0 0 0 1.1 1.1
Chloroethane 0 0 0 0 0 0 Chloroethane 0 0 0 0 0 0
Chloroform 1.4 0.84 0.8 0.79 0.85 4.68 Chloroform 1.4 0.84 0.8 0.79 0.85 4.68
Chloromethane 0 0 0 0 0 0 Chloromethane 0 0 0 0 0 0
cis-1,2-Dichloroethene 49 57 44 27 24 201 cis-1,2-Dichloroethene 49 57 44 27 24 201
cis-1,3-Dichloropropene 0 0 0 0 0 0 cis-1,3-Dichloropropene 0 0 0 0 0 0
Cyclohexane 99 76 62 47 47 331 Cyclohexane 99 76 62 47 47 331
Dibromochloromethane 0 0 0 0 0 0 Dibromochloromethane 0 0 0 0 0 0
Dichlorodifluoromethane 0 0 0 0 0 0 Dichlorodifluoromethane 0 0 0 0 0 0
Ethanol 160 160 170 130 150 770 Ethanol 160 160 170 130 150 770
Ethyl acetate 42 18 13 10 11 94 Ethyl acetate 42 18 13 10 11 94
Ethylbenzene 27 26 25 19 18 115 Ethylbenzene 27 26 25 19 18 115
Hexachlorobutadiene 0 0 0 0 0 0 Hexachlorobutadiene 0 0 0 0 0 0
Isopropyl alcohol 3500 3300 2300 1700 2000 12800 Isopropyl alcohol 3500 3300 2300 1700 2000 12800
Methyl tert-butyl ether 0 0 0 0 0 0 Methyl tert-butyl ether 0 0 0 0 0 0
Methylcyclohexane 150 140 110 86 83 569 Methylcyclohexane 150 140 110 86 83 569
Methylene Chloride 19 9.3 9 9.1 9.9 56.3 Methylene Chloride 19 9.3 9 9.1 9.9 56.3
m-Xylene & p-Xylene 100 92 91 71 70 424 m-Xylene & p-Xylene 100 92 91 71 70 424
n-Heptane 190 150 130 92 91 653 n-Heptane 190 150 130 92 91 653
n-Hexane 240 170 140 100 100 750 n-Hexane 240 170 140 100 100 750
Nonane 44 65 63 49 51 272 Nonane 44 65 63 49 51 272
o-Xylene 31 30 31 24 24 140 o-Xylene 31 30 31 24 24 140
Styrene 4.1 1.8 1.6 1.3 1.3 10.1 Styrene 4.1 1.8 1.6 1.3 1.3 10.1
Tetrachloroethene 29 39 37 25 25 155 Tetrachloroethene 29 39 37 25 25 155
Tetrahydrofuran 0 89 130 72 100 391 Tetrahydrofuran 0 89 130 72 100 391
Toluene 200 220 190 140 140 890 Toluene 200 220 190 140 140 890
trans-1,2-Dichloroethene 0 0 0 0 0 0 trans-1,2-Dichloroethene 0 0 0 0 0 0
trans-1,3-Dichloropropene 0 0 0 0 0 0 trans-1,3-Dichloropropene 0 0 0 0 0 0
Trichloroethene 560 690 600 400 370 2620 Trichloroethene 560 690 600 400 370 2620
Trichlorofluoromethane 0 0 0 0 0 0 Trichlorofluoromethane 0 0 0 0 0 0
Vinyl acetate 0 0 0 0 0 0 Vinyl acetate 0 0 0 0 0 0
Vinyl chloride 0 0 0 0 0 0 Vinyl chloride 0 0 0 0 0 0
Grand Total 5997.5 5974.79 4838 3572.29 3886.18 24268.76 Grand Total 5997.5 5974.79 4838 3572.29 3886.18 24268.76
6.5 6.5 6.5
Chloroethane Total 0.4 0.55 0.4 0.4 6.5 8.25
Chloroform 0.18 0.49 1.1 1.4 2.99
0.25 1.1 1.1
2.9 2.9 2.9
Chloroform Total 0.49 1.1 1.1 1.4 2.9 6.99
Chloromethane 0.8 10 8 3.6 21.6
1.1 6.4 6.4
13 13 13
Chloromethane Total 10 6.4 8 3.6 13 41
cis-1,2-Dichloroethene 0.13 0.13 0.13 0.31 0.57
0.17 0.17 0.17
2 2 2
cis-1,2-Dichloroethene Total 0.13 0.17 0.13 0.31 2 2.74
cis-1,3-Dichloropropene 0.24 0.24 0.24 0.24 0.72
0.33 0.33 0.33
3.9 3.9 3.9
cis-1,3-Dichloropropene Total 0.24 0.33 0.24 0.24 3.9 4.95
Cyclohexane 0.47 4.2 13 20 37.2
0.64 16 16
7.6 35 35
Cyclohexane Total 4.2 16 13 20 35 88.2
Dibromochloromethane 0.17 0.17 0.17 0.17 0.51
0.23 0.23 0.23
2.8 2.8 2.8
Dibromochloromethane Total 0.17 0.23 0.17 0.17 2.8 3.54
Dichlorodifluoromethane 0.18 0.63 0.91 2.1 3.64
0.24 1 1
2.9 2.9 2.9
Dichlorodifluoromethane Total 0.63 1 0.91 2.1 2.9 7.54
Ethanol 11 97 430 630 1157
15 530 530
180 680 680
Ethanol Total 97 530 430 630 680 2367
Ethyl acetate 0.75 4.6 27 27 58.6
1 28 28
12 14 14
Ethyl acetate Total 4.6 28 27 27 14 100.6
Ethylbenzene 0.17 1.2 6.4 20 27.6
0.23 7.2 7.2
2.7 8.3 8.3
Ethylbenzene Total 1.2 7.2 6.4 20 8.3 43.1
Hexachlorobutadiene 0.4 0.4 0.4 0.4 1.2
0.55 0.55 0.55
6.5 6.5 6.5
Hexachlorobutadiene Total 0.4 0.55 0.4 0.4 6.5 8.25
Isopropyl alcohol 1.2 150 980 450 1580
1.7 980 980
20 9200 9200
Isopropyl alcohol Total 150 980 980 450 9200 11760
Methyl tert-butyl ether 0.65 5.7 40 210 255.7
0.9 45 45
11 53 53
Methyl tert-butyl ether Total 5.7 45 40 210 53 353.7
Methylcyclohexane 0.25 6.4 44 78 128.4
0.35 52 52
4.1 27 27
Methylcyclohexane Total 6.4 52 44 78 27 207.4
Methylene Chloride 1.7 3.6 8.6 44 56.2
2.3 10 10
28 30 30
Methylene Chloride Total 3.6 10 8.6 44 30 96.2
m-Xylene & p-Xylene 0.37 7.5 44 140 191.5
0.5 54 54
6 42 42
m-Xylene & p-Xylene Total 7.5 54 44 140 42 287.5
n-Heptane 0.18 33 35 73 141
0.24 41 41
2.9 16 16
n-Heptane Total 33 41 35 73 16 198
n-Hexane 0.32 27 13 24 64
0.43 15 15
5.2 5.2 5.2
n-Hexane Total 27 15 13 24 5.2 84.2
Nonane 0.55 9.9 21 26 56.9
0.76 26 26
9 9 9
Nonane Total 9.9 26 21 26 9 91.9
o-Xylene 0.19 5.7 11 33 49.7
0.26 14 14
3.1 12 12
o-Xylene Total 5.7 14 11 33 12 75.7
Styrene 0.3 0.3 1.9 1.4 3.6
0.41 2.4 2.4
4.9 15 15
Styrene Total 0.3 2.4 1.9 1.4 15 21
Tetrachloroethene 0.15 1.7 1.2 1.4 4.3
0.2 1.1 1.1
2.4 92 92
Tetrachloroethene Total 1.7 1.1 1.2 1.4 92 97.4
Tetrahydrofuran 0.9 0.77 20 37 57.77
1.2 23 23
15 15 15
Tetrahydrofuran Total 0.77 23 20 37 15 95.77
Toluene 0.29 28 48 110 186
0.39 55 55
4.7 46 46
Toluene Total 28 55 48 110 46 287
trans-1,2-Dichloroethene 0.17 0.3 0.17 0.27 0.74
0.23 0.23 0.23
2.7 2.7 2.7
trans-1,2-Dichloroethene Total 0.3 0.23 0.17 0.27 2.7 3.67
trans-1,3-Dichloropropene 0.25 0.25 0.25 0.25 0.75
0.34 0.34 0.34
4 4 4
trans-1,3-Dichloropropene Total 0.25 0.34 0.25 0.25 4 5.09
Trichloroethene 0.17 1.1 2.7 8.9 12.7
0.23 3.2 3.2
2.7 13 13
Trichloroethene Total 1.1 3.2 2.7 8.9 13 28.9
Trichlorofluoromethane 0.14 0.22 0.22 0.27 0.71
0.19 0.25 0.25
2.3 2.3 2.3
Trichlorofluoromethane Total 0.22 0.25 0.22 0.27 2.3 3.26
Vinyl acetate 0.35 0.35 0.35 0.35 1.05
0.48 0.48 0.48
5.7 5.7 5.7
Vinyl acetate Total 0.35 0.48 0.35 0.35 5.7 7.23
Vinyl chloride 0.33 0.33 0.33 0.33 0.99
0.45 0.45 0.45
5.3 5.3 5.3
Vinyl chloride Total 0.33 0.45 0.33 0.33 5.3 6.74
Grand Total 546.36 2739.52 2497.42 2502.29 11299.8 19585.39
Sample ID Analyte Result MDL Reporting Result Unit Method
03072024-1 1,1,1-Trichloroethane 3.6 1.4 3.6 ppb v/v TO-15
03072024-1 1,1,2,2-Tetrachloroethane ND 0.7 0 ppb v/v TO-15
03072024-1 1,1,2-Trichloro-1,2,2-trifluoroethane 1 0.48 1 ppb v/v TO-15
03072024-1 1,1,2-Trichloroethane ND 0.76 0 ppb v/v TO-15
03072024-1 1,1-Dichloroethane 20 0.54 20 ppb v/v TO-15
03072024-1 1,1-Dichloroethene ND 0.64 0 ppb v/v TO-15
03072024-1 1,2,3-Trimethylbenzene 4.6 1.8 4.6 ppb v/v TO-15
03072024-1 1,2,4-Trichlorobenzene ND 1.8 0 ppb v/v TO-15
03072024-1 1,2,4-Trimethylbenzene 18 1 18 ppb v/v TO-15
03072024-1 1,2-Dibromoethane (EDB)ND 0.62 0 ppb v/v TO-15
03072024-1 1,2-Dichloro-1,1,2,2-tetrafluoroethane ND 0.6 0 ppb v/v TO-15
03072024-1 1,2-Dichlorobenzene ND 1.6 0 ppb v/v TO-15
03072024-1 1,2-Dichloroethane ND 0.5 0 ppb v/v TO-15
03072024-1 1,2-Dichloropropane ND 0.5 0 ppb v/v TO-15
03072024-1 1,3,5-Trimethylbenzene 6.6 3.2 6.6 ppb v/v TO-15
03072024-1 1,3-Butadiene ND 0.96 0 ppb v/v TO-15
03072024-1 1,3-Dichlorobenzene ND 0.8 0 ppb v/v TO-15
03072024-1 1,4-Dichlorobenzene ND 0.8 0 ppb v/v TO-15
03072024-1 2-Butanone (MEK)160 3.6 160 ppb v/v TO-15
03072024-1 2-Hexanone ND 2.8 0 ppb v/v TO-15
03072024-1 4-Ethyltoluene 5.2 1.1 5.2 ppb v/v TO-15
03072024-1 4-Methyl-2-pentanone (MIBK)43 2.8 43 ppb v/v TO-15
03072024-1 Acetone 140 110 140 ppb v/v TO-15
03072024-1 Benzene 150 0.66 150 ppb v/v TO-15
03072024-1 Benzyl chloride ND 1.9 0 ppb v/v TO-15
03072024-1 Bromodichloromethane ND 0.88 0 ppb v/v TO-15
03072024-1 Bromoform ND 1.3 0 ppb v/v TO-15
03072024-1 Bromomethane ND 1.1 0 ppb v/v TO-15
03072024-1 Carbon disulfide ND 1.7 0 ppb v/v TO-15
03072024-1 Carbon tetrachloride ND 0.64 0 ppb v/v TO-15
03072024-1 Chlorobenzene ND 1.1 0 ppb v/v TO-15
03072024-1 Chloroethane ND 1.6 0 ppb v/v TO-15
03072024-1 Chloroform 1.4 0.72 1.4 ppb v/v TO-15
03072024-1 Chloromethane ND 3.2 0 ppb v/v TO-15
03072024-1 cis-1,2-Dichloroethene 49 0.5 49 ppb v/v TO-15
03072024-1 cis-1,3-Dichloropropene ND 0.96 0 ppb v/v TO-15
03072024-1 Cyclohexane 99 1.9 99 ppb v/v TO-15
03072024-1 Dibromochloromethane ND 0.68 0 ppb v/v TO-15
03072024-1 Dichlorodifluoromethane ND 0.7 0 ppb v/v TO-15
03072024-1 Ethanol 160 44 160 ppb v/v TO-15
03072024-1 Ethyl acetate 42 3 42 ppb v/v TO-15
03072024-1 Ethylbenzene 27 0.66 27 ppb v/v TO-15
03072024-1 Hexachlorobutadiene ND 1.6 0 ppb v/v TO-15
03072024-1 Isopropyl alcohol 3500 19 3500 ppb v/v TO-15
03072024-1 Methyl tert-butyl ether ND 2.6 0 ppb v/v TO-15
03072024-1 Methylcyclohexane 150 1 150 ppb v/v TO-15
03072024-1 Methylene Chloride 19 6.8 19 ppb v/v TO-15
03072024-1 m-Xylene & p-Xylene 100 1.5 100 ppb v/v TO-15
03072024-1 n-Heptane 190 0.70 190 ppb v/v TO-15
03072024-1 n-Hexane 240 1.3 240 ppb v/v TO-15
03072024-1 Nonane 44 2.2 44 ppb v/v TO-15
03072024-1 o-Xylene 31 0.76 31 ppb v/v TO-15
03072024-1 Styrene 4.1 1.2 4.1 ppb v/v TO-15
03072024-1 Tetrachloroethene 29 0.58 29 ppb v/v TO-15
03072024-1 Tetrahydrofuran ND 3.6 0 ppb v/v TO-15
03072024-1 Toluene 200 1.1 200 ppb v/v TO-15
03072024-1 trans-1,2-Dichloroethene ND 0.66 0 ppb v/v TO-15
03072024-1 trans-1,3-Dichloropropene ND 0.98 0 ppb v/v TO-15
03072024-1 Trichloroethene 560 0.66 560 ppb v/v TO-15
03072024-1 Trichlorofluoromethane ND 0.56 0 ppb v/v TO-15
03072024-1 Vinyl acetate ND 1.4 0 ppb v/v TO-15
03072024-1 Vinyl chloride ND 1.3 0 ppb v/v TO-15
03072024-2 1,1,1-Trichloroethane 4.1 1.4 4.1 ppb v/v TO-15
03072024-2 1,1,2,2-Tetrachloroethane ND 0.69 0 ppb v/v TO-15
03072024-2 1,1,2-Trichloro-1,2,2-trifluoroethane 0.95 0.47 0.95 ppb v/v TO-15
03072024-2 1,1,2-Trichloroethane ND 0.75 0 ppb v/v TO-15
03072024-2 1,1-Dichloroethane 23 0.53 23 ppb v/v TO-15
03072024-2 1,1-Dichloroethene ND 0.63 0 ppb v/v TO-15
03072024-2 1,2,3-Trimethylbenzene 8.3 1.8 8.3 ppb v/v TO-15
03072024-2 1,2,4-Trichlorobenzene ND 1.8 0 ppb v/v TO-15
03072024-2 1,2,4-Trimethylbenzene 30 0.99 30 ppb v/v TO-15
03072024-2 1,2-Dibromoethane (EDB)ND 0.61 0 ppb v/v TO-15
03072024-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane ND 0.59 0 ppb v/v TO-15
03072024-2 1,2-Dichlorobenzene ND 1.5 0 ppb v/v TO-15
03072024-2 1,2-Dichloroethane ND 0.49 0 ppb v/v TO-15
03072024-2 1,2-Dichloropropane ND 0.49 0 ppb v/v TO-15
03072024-2 1,3,5-Trimethylbenzene 11 3.2 11 ppb v/v TO-15
03072024-2 1,3-Butadiene ND 0.95 0 ppb v/v TO-15
03072024-2 1,3-Dichlorobenzene ND 0.79 0 ppb v/v TO-15
03072024-2 1,4-Dichlorobenzene ND 0.79 0 ppb v/v TO-15
03072024-2 2-Butanone (MEK)210 3.6 210 ppb v/v TO-15
03072024-2 2-Hexanone ND 2.8 0 ppb v/v TO-15
03072024-2 4-Ethyltoluene 8.5 1 8.5 ppb v/v TO-15
03072024-2 4-Methyl-2-pentanone (MIBK)55 2.8 55 ppb v/v TO-15
03072024-2 Acetone 180 110 180 ppb v/v TO-15
03072024-2 Benzene 110 0.65 110 ppb v/v TO-15
03072024-2 Benzyl chloride ND 1.9 0 ppb v/v TO-15
03072024-2 Bromodichloromethane ND 0.87 0 ppb v/v TO-15
03072024-2 Bromoform ND 1.3 0 ppb v/v TO-15
03072024-2 Bromomethane ND 1.1 0 ppb v/v TO-15
03072024-2 Carbon disulfide ND 1.7 0 ppb v/v TO-15
03072024-2 Carbon tetrachloride ND 0.63 0 ppb v/v TO-15
03072024-2 Chlorobenzene ND 1.1 0 ppb v/v TO-15
03072024-2 Chloroethane ND 1.6 0 ppb v/v TO-15
03072024-2 Chloroform 0.84 0.71 0.84 ppb v/v TO-15
03072024-2 Chloromethane ND 3.2 0 ppb v/v TO-15
03072024-2 cis-1,2-Dichloroethene 57 0.49 57 ppb v/v TO-15
03072024-2 cis-1,3-Dichloropropene ND 0.95 0 ppb v/v TO-15
03072024-2 Cyclohexane 76 1.8 76 ppb v/v TO-15
03072024-2 Dibromochloromethane ND 0.67 0 ppb v/v TO-15
03072024-2 Dichlorodifluoromethane ND 0.69 0 ppb v/v TO-15
03072024-2 Ethanol 160 43 160 ppb v/v TO-15
03072024-2 Ethyl acetate 18 3 18 ppb v/v TO-15
03072024-2 Ethylbenzene 26 0.65 26 ppb v/v TO-15
03072024-2 Hexachlorobutadiene ND 1.6 0 ppb v/v TO-15
03072024-2 Isopropyl alcohol 3300 19 3300 ppb v/v TO-15
03072024-2 Methyl tert-butyl ether ND 2.6 0 ppb v/v TO-15
03072024-2 Methylcyclohexane 140 0.99 140 ppb v/v TO-15
03072024-2 Methylene Chloride 9.3 6.7 9.3 ppb v/v TO-15
03072024-2 m-Xylene & p-Xylene 92 1.4 92 ppb v/v TO-15
03072024-2 n-Heptane 150 0.69 150 ppb v/v TO-15
03072024-2 n-Hexane 170 1.2 170 ppb v/v TO-15
03072024-2 Nonane 65 2.2 65 ppb v/v TO-15
03072024-2 o-Xylene 30 0.75 30 ppb v/v TO-15
03072024-2 Styrene 1.8 1.2 1.8 ppb v/v TO-15
03072024-2 Tetrachloroethene 39 0.57 39 ppb v/v TO-15
03072024-2 Tetrahydrofuran 89 3.6 89 ppb v/v TO-15
03072024-2 Toluene 220 1.1 220 ppb v/v TO-15
03072024-2 trans-1,2-Dichloroethene ND 0.65 0 ppb v/v TO-15
03072024-2 trans-1,3-Dichloropropene ND 0.97 0 ppb v/v TO-15
03072024-2 Trichloroethene 690 0.65 690 ppb v/v TO-15
03072024-2 Trichlorofluoromethane ND 0.55 0 ppb v/v TO-15
03072024-2 Vinyl acetate ND 1.4 0 ppb v/v TO-15
03072024-2 Vinyl chloride ND 1.3 0 ppb v/v TO-15
03072024-3 1,1,1-Trichloroethane 3.3 1.5 3.3 ppb v/v TO-15
03072024-3 1,1,2,2-Tetrachloroethane ND 0.73 0 ppb v/v TO-15
03072024-3 1,1,2-Trichloro-1,2,2-trifluoroethane 0.7 0.5 0.7 ppb v/v TO-15
03072024-3 1,1,2-Trichloroethane ND 0.79 0 ppb v/v TO-15
03072024-3 1,1-Dichloroethane 18 0.56 18 ppb v/v TO-15
03072024-3 1,1-Dichloroethene ND 0.67 0 ppb v/v TO-15
03072024-3 1,2,3-Trimethylbenzene 9.8 1.9 9.8 ppb v/v TO-15
03072024-3 1,2,4-Trichlorobenzene ND 1.9 0 ppb v/v TO-15
03072024-3 1,2,4-Trimethylbenzene 35 1 35 ppb v/v TO-15
03072024-3 1,2-Dibromoethane (EDB)ND 0.64 0 ppb v/v TO-15
03072024-3 1,2-Dichloro-1,1,2,2-tetrafluoroethane ND 0.62 0 ppb v/v TO-15
03072024-3 1,2-Dichlorobenzene ND 1.6 0 ppb v/v TO-15
03072024-3 1,2-Dichloroethane ND 0.52 0 ppb v/v TO-15
03072024-3 1,2-Dichloropropane ND 0.52 0 ppb v/v TO-15
03072024-3 1,3,5-Trimethylbenzene 13 3.3 13 ppb v/v TO-15
03072024-3 1,3-Butadiene ND 1 0 ppb v/v TO-15
03072024-3 1,3-Dichlorobenzene ND 0.83 0 ppb v/v TO-15
03072024-3 1,4-Dichlorobenzene ND 0.83 0 ppb v/v TO-15
03072024-3 2-Butanone (MEK)200 3.7 200 ppb v/v TO-15
03072024-3 2-Hexanone ND 2.9 0 ppb v/v TO-15
03072024-3 4-Ethyltoluene 9.8 1.1 9.8 ppb v/v TO-15
03072024-3 4-Methyl-2-pentanone (MIBK)42 2.9 42 ppb v/v TO-15
03072024-3 Acetone 260 58 260 ppb v/v TO-15
03072024-3 Benzene 99 0.69 99 ppb v/v TO-15
03072024-3 Benzyl chloride ND 2 0 ppb v/v TO-15
03072024-3 Bromodichloromethane ND 0.92 0 ppb v/v TO-15
03072024-3 Bromoform ND 1.4 0 ppb v/v TO-15
03072024-3 Bromomethane ND 1.1 0 ppb v/v TO-15
03072024-3 Carbon disulfide ND 1.8 0 ppb v/v TO-15
03072024-3 Carbon tetrachloride ND 0.67 0 ppb v/v TO-15
03072024-3 Chlorobenzene ND 1.2 0 ppb v/v TO-15
03072024-3 Chloroethane ND 1.6 0 ppb v/v TO-15
03072024-3 Chloroform 0.8 0.75 0.8 ppb v/v TO-15
03072024-3 Chloromethane ND 3.3 0 ppb v/v TO-15
03072024-3 cis-1,2-Dichloroethene 44 0.52 44 ppb v/v TO-15
03072024-3 cis-1,3-Dichloropropene ND 1 0 ppb v/v TO-15
03072024-3 Cyclohexane 62 1.9 62 ppb v/v TO-15
03072024-3 Dibromochloromethane ND 0.71 0 ppb v/v TO-15
03072024-3 Dichlorodifluoromethane ND 0.73 0 ppb v/v TO-15
03072024-3 Ethanol 170 46 170 ppb v/v TO-15
03072024-3 Ethyl acetate 13 3.1 13 ppb v/v TO-15
03072024-3 Ethylbenzene 25 0.69 25 ppb v/v TO-15
03072024-3 Hexachlorobutadiene ND 1.7 0 ppb v/v TO-15
03072024-3 Isopropyl alcohol 2300 10 2300 ppb v/v TO-15
03072024-3 Methyl tert-butyl ether ND 2.7 0 ppb v/v TO-15
03072024-3 Methylcyclohexane 110 1 110 ppb v/v TO-15
03072024-3 Methylene Chloride 9 7.1 9 ppb v/v TO-15
03072024-3 m-Xylene & p-Xylene 91 1.5 91 ppb v/v TO-15
03072024-3 n-Heptane 130 0.73 130 ppb v/v TO-15
03072024-3 n-Hexane 140 1.3 140 ppb v/v TO-15
03072024-3 Nonane 63 2.3 63 ppb v/v TO-15
03072024-3 o-Xylene 31 0.79 31 ppb v/v TO-15
03072024-3 Styrene 1.6 1.2 1.6 ppb v/v TO-15
03072024-3 Tetrachloroethene 37 0.60 37 ppb v/v TO-15
03072024-3 Tetrahydrofuran 130 3.7 130 ppb v/v TO-15
03072024-3 Toluene 190 1.2 190 ppb v/v TO-15
03072024-3 trans-1,2-Dichloroethene ND 0.69 0 ppb v/v TO-15
03072024-3 trans-1,3-Dichloropropene ND 1.0 0 ppb v/v TO-15
03072024-3 Trichloroethene 600 0.69 600 ppb v/v TO-15
03072024-3 Trichlorofluoromethane ND 0.58 0 ppb v/v TO-15
03072024-3 Vinyl acetate ND 1.5 0 ppb v/v TO-15
03072024-3 Vinyl chloride ND 1.4 0 ppb v/v TO-15
03072024-4 1,1,1-Trichloroethane 2.2 1.4 2.2 ppb v/v TO-15
03072024-4 1,1,2,2-Tetrachloroethane ND 0.7 0 ppb v/v TO-15
03072024-4 1,1,2-Trichloro-1,2,2-trifluoroethane 0.5 0.48 0.5 ppb v/v TO-15
03072024-4 1,1,2-Trichloroethane ND 0.76 0 ppb v/v TO-15
03072024-4 1,1-Dichloroethane 11 0.54 11 ppb v/v TO-15
03072024-4 1,1-Dichloroethene ND 0.64 0 ppb v/v TO-15
03072024-4 1,2,3-Trimethylbenzene 9.5 1.8 9.5 ppb v/v TO-15
03072024-4 1,2,4-Trichlorobenzene ND 1.8 0 ppb v/v TO-15
03072024-4 1,2,4-Trimethylbenzene 34 1 34 ppb v/v TO-15
03072024-4 1,2-Dibromoethane (EDB)ND 0.62 0 ppb v/v TO-15
03072024-4 1,2-Dichloro-1,1,2,2-tetrafluoroethane ND 0.6 0 ppb v/v TO-15
03072024-4 1,2-Dichlorobenzene ND 1.6 0 ppb v/v TO-15
03072024-4 1,2-Dichloroethane ND 0.5 0 ppb v/v TO-15
03072024-4 1,2-Dichloropropane ND 0.5 0 ppb v/v TO-15
03072024-4 1,3,5-Trimethylbenzene 11 3.2 11 ppb v/v TO-15
03072024-4 1,3-Butadiene ND 0.96 0 ppb v/v TO-15
03072024-4 1,3-Dichlorobenzene ND 0.8 0 ppb v/v TO-15
03072024-4 1,4-Dichlorobenzene ND 0.8 0 ppb v/v TO-15
03072024-4 2-Butanone (MEK)150 3.6 150 ppb v/v TO-15
03072024-4 2-Hexanone ND 2.8 0 ppb v/v TO-15
03072024-4 4-Ethyltoluene 9.9 1.1 9.9 ppb v/v TO-15
03072024-4 4-Methyl-2-pentanone (MIBK)30 2.8 30 ppb v/v TO-15
03072024-4 Acetone 230 28 230 ppb v/v TO-15
03072024-4 Benzene 81 0.66 81 ppb v/v TO-15
03072024-4 Benzyl chloride ND 1.9 0 ppb v/v TO-15
03072024-4 Bromodichloromethane ND 0.88 0 ppb v/v TO-15
03072024-4 Bromoform ND 1.3 0 ppb v/v TO-15
03072024-4 Bromomethane ND 1.1 0 ppb v/v TO-15
03072024-4 Carbon disulfide ND 1.7 0 ppb v/v TO-15
03072024-4 Carbon tetrachloride ND 0.64 0 ppb v/v TO-15
03072024-4 Chlorobenzene ND 1.1 0 ppb v/v TO-15
03072024-4 Chloroethane ND 1.6 0 ppb v/v TO-15
03072024-4 Chloroform 0.79 0.72 0.79 ppb v/v TO-15
03072024-4 Chloromethane ND 3.2 0 ppb v/v TO-15
03072024-4 cis-1,2-Dichloroethene 27 0.5 27 ppb v/v TO-15
03072024-4 cis-1,3-Dichloropropene ND 0.96 0 ppb v/v TO-15
03072024-4 Cyclohexane 47 1.9 47 ppb v/v TO-15
03072024-4 Dibromochloromethane ND 0.68 0 ppb v/v TO-15
03072024-4 Dichlorodifluoromethane ND 0.7 0 ppb v/v TO-15
03072024-4 Ethanol 130 44 130 ppb v/v TO-15
03072024-4 Ethyl acetate 10 3 10 ppb v/v TO-15
03072024-4 Ethylbenzene 19 0.66 19 ppb v/v TO-15
03072024-4 Hexachlorobutadiene ND 1.6 0 ppb v/v TO-15
03072024-4 Isopropyl alcohol 1700 4.8 1700 ppb v/v TO-15
03072024-4 Methyl tert-butyl ether ND 2.6 0 ppb v/v TO-15
03072024-4 Methylcyclohexane 86 1 86 ppb v/v TO-15
03072024-4 Methylene Chloride 9.1 6.8 9.1 ppb v/v TO-15
03072024-4 m-Xylene & p-Xylene 71 1.5 71 ppb v/v TO-15
03072024-4 n-Heptane 92 0.70 92 ppb v/v TO-15
03072024-4 n-Hexane 100 1.3 100 ppb v/v TO-15
03072024-4 Nonane 49 2.2 49 ppb v/v TO-15
03072024-4 o-Xylene 24 0.76 24 ppb v/v TO-15
03072024-4 Styrene 1.3 1.2 1.3 ppb v/v TO-15
03072024-4 Tetrachloroethene 25 0.58 25 ppb v/v TO-15
03072024-4 Tetrahydrofuran 72 3.6 72 ppb v/v TO-15
03072024-4 Toluene 140 1.1 140 ppb v/v TO-15
03072024-4 trans-1,2-Dichloroethene ND 0.66 0 ppb v/v TO-15
03072024-4 trans-1,3-Dichloropropene ND 0.98 0 ppb v/v TO-15
03072024-4 Trichloroethene 400 0.66 400 ppb v/v TO-15
03072024-4 Trichlorofluoromethane ND 0.56 0 ppb v/v TO-15
03072024-4 Vinyl acetate ND 1.4 0 ppb v/v TO-15
03072024-4 Vinyl chloride ND 1.3 0 ppb v/v TO-15
03072024-5 1,1,1-Trichloroethane 2 1.3 2 ppb v/v TO-15
03072024-5 1,1,2,2-Tetrachloroethane ND 0.62 0 ppb v/v TO-15
03072024-5 1,1,2-Trichloro-1,2,2-trifluoroethane 0.43 0.43 0.43 ppb v/v TO-15
03072024-5 1,1,2-Trichloroethane ND 0.68 0 ppb v/v TO-15
03072024-5 1,1-Dichloroethane 9.7 0.48 9.7 ppb v/v TO-15
03072024-5 1,1-Dichloroethene ND 0.57 0 ppb v/v TO-15
03072024-5 1,2,3-Trimethylbenzene 7.9 1.6 7.9 ppb v/v TO-15
03072024-5 1,2,4-Trichlorobenzene ND 1.6 0 ppb v/v TO-15
03072024-5 1,2,4-Trimethylbenzene 27 0.89 27 ppb v/v TO-15
03072024-5 1,2-Dibromoethane (EDB)ND 0.55 0 ppb v/v TO-15
03072024-5 1,2-Dichloro-1,1,2,2-tetrafluoroethane ND 0.53 0 ppb v/v TO-15
03072024-5 1,2-Dichlorobenzene ND 1.4 0 ppb v/v TO-15
03072024-5 1,2-Dichloroethane ND 0.45 0 ppb v/v TO-15
03072024-5 1,2-Dichloropropane ND 0.45 0 ppb v/v TO-15
03072024-5 1,3,5-Trimethylbenzene 10 2.8 10 ppb v/v TO-15
03072024-5 1,3-Butadiene ND 0.85 0 ppb v/v TO-15
03072024-5 1,3-Dichlorobenzene ND 0.71 0 ppb v/v TO-15
03072024-5 1,4-Dichlorobenzene ND 0.71 0 ppb v/v TO-15
03072024-5 2-Butanone (MEK)150 3.2 150 ppb v/v TO-15
03072024-5 2-Hexanone ND 2.5 0 ppb v/v TO-15
03072024-5 4-Ethyltoluene 9 0.94 9 ppb v/v TO-15
03072024-5 4-Methyl-2-pentanone (MIBK)37 2.5 37 ppb v/v TO-15
03072024-5 Acetone 230 25 230 ppb v/v TO-15
03072024-5 Benzene 86 0.59 86 ppb v/v TO-15
03072024-5 Benzyl chloride ND 1.7 0 ppb v/v TO-15
03072024-5 Bromodichloromethane ND 0.78 0 ppb v/v TO-15
03072024-5 Bromoform ND 1.2 0 ppb v/v TO-15
03072024-5 Bromomethane ND 0.98 0 ppb v/v TO-15
03072024-5 Carbon disulfide ND 1.5 0 ppb v/v TO-15
03072024-5 Carbon tetrachloride ND 0.57 0 ppb v/v TO-15
03072024-5 Chlorobenzene 1.1 1 1.1 ppb v/v TO-15
03072024-5 Chloroethane ND 1.4 0 ppb v/v TO-15
03072024-5 Chloroform 0.85 0.64 0.85 ppb v/v TO-15
03072024-5 Chloromethane ND 2.8 0 ppb v/v TO-15
03072024-5 cis-1,2-Dichloroethene 24 0.45 24 ppb v/v TO-15
03072024-5 cis-1,3-Dichloropropene ND 0.85 0 ppb v/v TO-15
03072024-5 Cyclohexane 47 1.7 47 ppb v/v TO-15
03072024-5 Dibromochloromethane ND 0.61 0 ppb v/v TO-15
03072024-5 Dichlorodifluoromethane ND 0.62 0 ppb v/v TO-15
03072024-5 Ethanol 150 39 150 ppb v/v TO-15
03072024-5 Ethyl acetate 11 2.7 11 ppb v/v TO-15
03072024-5 Ethylbenzene 18 0.59 18 ppb v/v TO-15
03072024-5 Hexachlorobutadiene ND 1.4 0 ppb v/v TO-15
03072024-5 Isopropyl alcohol 2000 4.3 2000 ppb v/v TO-15
03072024-5 Methyl tert-butyl ether ND 2.3 0 ppb v/v TO-15
03072024-5 Methylcyclohexane 83 0.89 83 ppb v/v TO-15
03072024-5 Methylene Chloride 9.9 6.1 9.9 ppb v/v TO-15
03072024-5 m-Xylene & p-Xylene 70 1.3 70 ppb v/v TO-15
03072024-5 n-Heptane 91 0.62 91 ppb v/v TO-15
03072024-5 n-Hexane 100 1.1 100 ppb v/v TO-15
03072024-5 Nonane 51 2.0 51 ppb v/v TO-15
03072024-5 o-Xylene 24 0.68 24 ppb v/v TO-15
03072024-5 Styrene 1.3 1.1 1.3 ppb v/v TO-15
03072024-5 Tetrachloroethene 25 0.52 25 ppb v/v TO-15
03072024-5 Tetrahydrofuran 100 3.2 100 ppb v/v TO-15
03072024-5 Toluene 140 1.0 140 ppb v/v TO-15
03072024-5 trans-1,2-Dichloroethene ND 0.59 0 ppb v/v TO-15
03072024-5 trans-1,3-Dichloropropene ND 0.87 0 ppb v/v TO-15
03072024-5 Trichloroethene 370 0.59 370 ppb v/v TO-15
03072024-5 Trichlorofluoromethane ND 0.50 0 ppb v/v TO-15
03072024-5 Vinyl acetate ND 1.2 0 ppb v/v TO-15
03072024-5 Vinyl chloride ND 1.2 0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 ppb v/v TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
0 TO-15
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0 TO-15
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