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Home My WebLink AboutDAQ-2024-0043021 DAQC-1307-23 Site ID 10123 (B4) MEMORANDUM TO: STACK TEST FILE – HF SINCLAIR WOODS CROSS REFINING, LLC THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Robert Sirrine, Environmental Scientist DATE: November 28, 2023 SUBJECT: Source: Heater 20H3 Location: 1070 West 500 South, West Bountiful, Davis County, Utah Contact: F. Travis Smith: (801) 299-6625 Tester: Alliance Source Testing FRS ID #: UT00000049011000013 AO #: DAQE-AN101230057-23, dated November 15, 2023 Action Code: 3A Subject: Review of Stack Test Report dated October 20, 2023 On October 20, 2023, Utah Division of Air Quality (DAQ) received a stack test report for testing of the 20H3 Heater located at the HF Sinclair refinery in West Bountiful, Davis County, Utah. Testing was performed on August 25, 28-30, 2023, to determine compliance with the PM10 test methods and emission limit found in Conditions II.B.1.a, and II.B.6.a. The DAQ calculated results are: Source Test Date RM/Pollutant DAQ Result Test Result Limit 20H3 8/25, 28-30/23 CTM-039/PM10 0.0005* 0.0005* 0.0070* *lbs/MMBtu DEVIATIONS: No deviations were noted. CONCLUSION: The test report appears to be acceptable. RECOMMENDATION: The PM10 emissions appear to have been in compliance with the applicable limit at the time of testing. HPV: No ATTACHMENTS: Heater 20H3 stack test report received October 20, 2023 DAQ generated excel spreadsheets . l- ,.tttFfinctorr October 20,2023 Mr. Bryce Bird, Director Division of Air Quality Utah Dept. of Environmental Quality 195 North 1950 West Salt Lake City, Utah 841l6 RE: Annual PMro Emissions Test Report - 20H3 Reactor Charge Heater HF Sinclair Woods Cross Refining LLC, Davis County Dear Mr. Bird: TJTAH DEPARTMENT OF EIWIRONMENTAL OUAUTY ., -i ? -; '\i:')'.) \b^d Ctetivered DIVISION OF AIR QUALIW Hand Delivered In accordance with Conditions [.B.1.a and tr.B.6.a of Approval Order ANl01230055-23, please find enclosed the results of our recent PMro emissions testing for process heater 20H3. The testing was conducted August 25 and 28-30, 2023. The test results were 0.0005 lbs/IvlMBtu for PMl0. Enclosed, please find a copy of the testing report for process heater 20H3. If you have any questions or need additional information, please contact F. Travis Smith at (801) 299-6625 or email ftravis.smith@hfsinclair.com. I certifu that: Testing was conducted while the source was operating at the rate and/or conditions specified in the applicable approval order, operating permit, or federal regulation; During testing, the source combusted fuels, used raw materials, and maintained process conditions representative ofnormal operations, and operated under such other relevant conditions specified by the Director; Based on information and belief formed after reasonable inquiry, the statements and information contained in the report are true, accurate, and complete. Sincerely,_. (L Ye<\* ),,--^-r-) Dustin Simmonds Vice President and Refinery Manager HF Sinclair Woods Cross Refining LLC 1070 W. 500 S, West Bountiful, UT 84087 801-299-6600 | HFSinclair.com Enclosure c: E. Benson (r)Fi[e2.4.4 K. Arnold J. Barton J. Orr i1,.;,' . ^b1CO...t de C',^Vqn:C-;;i: ,.. Dry!'SlOlJ 0r 41P QUALITYAliare Source Test Report HF Sinclair Woods Cross Refining, LLC 1070 West 500 South West Bountiful, UT 84087 Source Tested: Process Heater 20H3 Test Dates: August 25 & 28-30,2023 Project No. AST-2023- 1 660-0 I 0 Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 pJlt6rrce TECHNICAL GROUP Source Test Rqofi Test Progmm Summary ResulatorY Information Permit No. Source Information DAQE-ANl0l23005s-23 Source Name Refinery Gas Fired Process Heater Contact Information Source ID 20H3 Target Parameters PMIO, PM2.5 Test Location HF Sinclair Woods Cross Refining, LLC 1070 West 500 South West Bountitul, UT 84087 Eric Benson eric.benson@hfsinclair. com (801) 299-6623 F. Travis Smith ftrav is. smith@hfsi nclair.com (801) 299-662s Test Company Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 hoject Manager Charles Horton charles.horton@lliancetg. com (352) 63-7568 Field Team Leader Tobias Hubbard tobias.hubbard@al liancetg.com (605) 645-8562 QA/QC Manager Kathleen Shonk katie. shonk@alliancetg.com (812) 452-478s Report Coordinator Sarah Perry sarah.perry@all iancetg.com Analyical Laboratory Eurofins TestAmerica 5815 Middlebrook Pike Knoxville, TN 37921 Kevin Woodcock kev in.woodcock@testamericainc.com (865) 291-3000 HF Sinclair - West Bountiful, UTAST-2023- 1660-010 2 of20l Page i pul6rrpE) I'ECi.]NICAL GI]OUP Source Test Report Cer t i li cat ion S al e me nt Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the relevant sections in the test report. This report is only considered valid once an authorized representative of Alliance has signed in the space provided below; any other version is considered draft. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer ofthis document. '--,,, '- '4:I t0/t2/2023 Charles Horton, QSTI Alliance Technical Group, LLC Date HF Sinclair - West Bountiful, UTAST-2023-1660-010 3 of20l Page ii puldrpe rEC'r-l NICAi GROUP Source Tesl Repoi Table ofContents TABLE OF CONTENTS l.l Emission Unit and Control Unit Descriptions................. .........................'. l-l 1.3 Site-Specific Test Plan & Notification ........' l-l 3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate ..... 3-l 3.2 U.S. EPA Reference Test Method 3,A - Oxygen/Carbon Dioxide.......... ...'...................... 3-l 3.3 U.S. EPA Reference Test Method 4 - Moisture Content.......... ..'.............. 3-l 3.4 U.S. EPA Conditional Test Method 039 - PMI0/PM2.5.............. .............3-2 3.5 U.S. EPA Reference Test Method l9 - Mass Emission Factors........... ...."............'......... 3-3 3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3A.....................................'.'.. 3-3 LIST OF TABLES Table 2-l: Summary of Results- PMI0/PM2.5. ..........2-l APPENDICES Appendix A Sample Calculations Appendix B Field Data Appendix C Laboratory Data Appendix D Quality Assurance/Quality Control Data Appendix E Process Operating/Control System Data HF Sinclair - West Bountiful, UTAST-2023- 1660-01 0 4 of?Ol Page iii 5 of20l pilr6rpe TECHNICAI GROUP Source Tesl Report Irnroduction 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by HF Sinclair Woods Cross Refining, LLC (HF Sinclair) to conduct compliance testing at the Woods Cross Refinery in West Bountiful" Utah. Portions of the facility are subject to provisions of the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-AN101230055-23. Testing was conducted to determine the emission rates of particulate matter less than or equal to l0 microns (PMl0) and particulate matter less than 2.5 microns (PM2.5) from the exhaust of Process Heater 20H3. Emission Unit and Control Unit Descriptions 1.2 Project Team Personnel involved in this project are identified in the following table. Table 1-1: Project Team 1.3 Site-Specific Test Plan & Notification Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by HF Sinclair. HF Sinclair - West Bountiful, UT Gas Oil Hydrocracker Charge Heater, 39.7 MMBtu/hr HHV, fired on plant gas, natural draft, 6 burners (Next Generation, Ultra Low NOx), and up-fired fumace. Stack Ultra-low NOx burners HF Sinclair Personnel Matthew Howes F. Travis Smith Alliance Personnel Tobias Hubbard Supilani Mailei AST-2023- I 660-0 I 0 6 of20l Page l-l 7 of20l Att6rpe Source Test Reporl Summry ol Results 2.0 Summary of Results Alliance conducted compliance testing at the HF Sinclair facility in West Bountiful, Utah on August 25 and28-30, 2023. Testing consisted of determining the emission rates of PM2.5 and PMl0 at the exhaust of Process Heater 20H3. Table 2-l provides a summary of the emission testing results. Any difference between the summary results listed in the following table and the detailed results contained in appendices is due to rounding for presentation. Table 2-1: Summary of Results - PMl0/PM2.5 R Rrrn 2 Run l 'Bn )ate ,top Time Time Time min 8/25123 8:26 l2:56 240.0 243.7 8t28-8/29/23 8t29-8/30t23 23 03 23:30 3 12 3:38 239.9 251 2(0) INPUT DATA 20,190 18 t3 8,255 25.80 1.t42 0.370 0.00075 2.t6 0.000 2.t6 20,783 18.51 8,265 25.75 I t42 0.170 0.00075 r.4'7 0.000 r47 ruel Gc Flow Rate, scftr {eat Input, MMBtU/hr ruel Factor (O2 dry), dscf,MMBtu ldometric Pressure, in Hg r'Ieter Correction Factot ,lozle Diameter, in \rea of Nozle, ft2 lotal Mcs of PMl0 gm, mg (m2 + mr + mj + mj) iotal Mos of PM <10 pm and >2.5 ym, mg (m2) lotal M6s of PM <2.5 um. mc (m, + m, + m.) (FR) (HI) (Fd) (Pb) (Y) (Dn) (An) (mpuro) (menro-:.s) (m^." J 20,940 t't .27 8,259 25'17 !.142 0.370 0.00075 L54 0.000 154 2t,220 20.13 8,281 25.68 I 142 0.370 0.00075 0.720 0.000 0.720 CTM-039 LOGGER DATA 6.91 0 328 78.6 2.23 288.4 1,840.5 l16 t0.47 2.54 2t.87 0.160 lo4 R 6.86 0.324 78.6 2.22 285.6 1,846.6 Ll6 10.28 2.60 21.42 0.157 103 5 )ilution Flow Rate, dscfm iample Flow Rate, dscfm /olume Sampled, dscf /olume Sampled, dscm /iscosity (eynolds Number lunningham Corection Factor 'articulate Cut Diameter for PMl0 )aniculate Cut Diameter for PM2.5 )ilution Ratio ',loisture Fraction Mecured <nkinetic Samnlino Rate loZ) (Qaar) (Q<"a) 1v1"0) 1vu"a) (r) (N,") (c) (Dso) (Dru) (DR) (BWSmd) 1l\ 7.01 0.333 79.9 226 284.2 1,890.t t.l6 10.09 253 21.94 0 160 r05 I 6.66 0.322 77.1 2.18 244.4 1,809 I l. 15 10.29 2.68 2t.65 0.1 50 t00 5 EMISSION'AI,'III,ATIONS )M l0 Concenration, grair/dscf )M I 0 Concentration, mg/dscm 'Ml0 Emission Rate, lb,hr 'M l0 Emrssron Factor, lb/MMBtu (02) )Ml O Fmission Rrte lh,MMqcf frrel aar (Cruro) (Cpvro) (PMR) (EFpvroo:a) (8R".,,") 0.00042 0.969 2.8E-O2 7.8E-04 I 4F+0O 0.00030 0.680 2 0E-02 4.9E-O4 9 5E-01 0.00014 0.330 9.8E-03 2 4E-04 4 6E-01 0.00029 0.660 t.9E-02 5.0E-04 9 3E-0r PM <10 pm od >2.5 pm Concentration, grair/dscf PM <10 gm md >2.5 pm Concmtration, mg/dscm PM <10 pm and >2.5 pm Emission Rate, lb/hr PM <10 gm ed >2.5 pm Emission Factor, lbiMMBtu (O2) PM <10 um md >2.5 trm Emission Rate. lbMMscf fuel cc (Cpur*r.r) o.oooo (cpurrzr) 0.000 (PMR) 0.0E+00 (EFpuro-r.sora) o.oE+oo (ER"",".,,) o.oE+oo 0.0000 0.000 0.0E+00 0.0E+00 0.08+00 0.0000 0.000 0.0E+00 0.0E+00 0.0E+00 0.0000 0.000 0.0E+00 0.0E+00 0 0E+00 )M <2.5 Concentration, grain/dscf )M <2.5 Concentration, mgldscm 'M <2.5 Emission Rate, lb/hr )M <2.5 Emission Factor, lb/MMBtu (O2) 'M <2 5 um Emission Rate lb.MMscf fuel (C"nr:.r) (Cpu:.r) (PMR) (EFrrr: s oa) (ER".,,.) o.ooo42 0.969 2.8E-02 7.8E-04 I 4E+00 0.00030 0.680 2.0E-02 4.9E-04 9 5E-0 I 0.00014 0.330 9.8E-03 2.4E-04 4 5E-01 0.00029 0.660 t.9E-02 5.0E-04 9.3E-01 HF Sinclair - West Bountiful, UTAST-2023-1660-010 8 of20l Page2-l 9 of20l pj/ldrrc.e TI'CiINICAI GROUP Source Tesl Repofl Testing Methodolog/ 3.0 Testing Methodology The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method descriptions are provided below while quality assurance/quality control data is provided in Appendix D. Table 3-l: Source Testing Methodology 3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA Reference Test Method l. To determine the minimum number of traverse points, the upstream and downstream distances were equated into equivalent diameters and compared to Figure l-l in U.S. EPA Reference Test Method l. Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type thermocouple and pyrometer. Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2. 3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide The oxygen (Oz) and carbon dioxide (COz) testing was conducted in accordance with U.S. EPA Reference Test Method 3,{. Data was collected online and reported in one-minute averages. The sampling system consisted of a stainless-steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.6. 3.3 U.S. EPA Reference Test Method 4 - Moisture Content The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on the same balance to determine the amount of moisture condensed. HF Sinclair- West Bountiful. UT Full Velocity TraversesVolumetric Flow Rate Oxygen / Carbon Dioxide Particulate Matter less than l0 Microns /Constant Rate Sampling AST-2023- I 660-0 I 0 l0 of20l Page 3-l AI ll',ll Source Test Repon Testing Methodolow 3.4 U.S. EPA Conditional Test Method 039 - PMI0/PM2.5 The PMl0 and PM2.5 testing was conducted accordance with U.S. EPA Conditional Test Method 039 (CTM-039). CTM-039 does not include drawing sample gas through impingers, but instead mixes the sample with dilution air in a mixing chamber to replicate the dilution and cooling of the stack effluent in the atmosphere. The filterable and condensable particulate matter is collected together (Section l.l ). The major components of the CTM-039 sampling train are: in-stack PMl0 and PM2.5 cyclones; a heated sample probe; a pre-dilution tee and mixing cone; a mixing (residence) chamber, two blowers and other ancillary equipment (Section 8.4). Per Section 8.6 of CTM-039 the probe, sample venturi, and heated compartment temperatures are to be maintained at least l0 degrees F above the stack gas temperatures; this is not feasible due to the high temperature ofthe stack. The equipment was ran at as high of a temperature as manageable and all heated and unheated components were recovered into the same sample fraction and analyzed together. A PM2.5 cyclone is located after the PMl0 cyclone. Stack gas is extracted at a pre-determined constant sampling rate to achieve near l00o/o isokinetic sampling ratios through the in-stack PMl0 and PM2.5 cyclones. The cyclones separate particles with nominal aerodynamic diameters of greater than l0 pm, less than lOpm and greater than 2.5 pm, and allow particles less than or equal to 2.5 pm and stack gases to continue through the heated sample probe and heated sample venturi to be diluted and cooled in the mixing cone and residence chamber before being captured by the 142-mm filter. Fittered, dehumidified, and temperature adjusted dilution air is added to the stack gas sample (now containing only the particles of less than 2.5 pm) in a mixing cone. After mixing of the dilution air and stack sample gas to allow for particulate condensation, PM2.5 is captured on a glass fiber filter bonded with polytetrafluoroethylene (PFTE) (Section 2.0). A preliminary velocity traverse was performed prior to the first run to veri! the absence of cyclonic flow and determine average velocity. A preliminary moisture run was conducted to target sampling conditions. Sampling was conducted at multiple traverse points during each run. (Section 8.2). The sample train was operated as described in Section 8.6 with data collected electronically (Sections 6.5.1 and 8.6.4.4). Each test consisted of three (3) approximately 240-minute runs. At the completion of each test run, a leak check of the non-diluted sample section was done after removing the cyclones. The leak check was performed by attaching a vacuum pump to the mixing chamber at the dilution air entrance. A vacuum was pulled to verify a leak rate of less than 0.02 cfm using the rotameter on the front end of the vacuum pump (Section 8.5.1.2 and 8.6.4.6). The CTM-039 recovery of the 142- mm filter and rinses were conducted as described in Section 8.7: o Container No. I (Nozzle and Cyclone I) o Great than PMl0 - optional o Container No. 2 (Cyclones I and IV) o PMl0 to PM2.5 acetone rinse o Container No. 3 (Mixing Cone, Residence Chamber, and Filter Holder Inlet) o less than PM2.5 water rinse r Container No. 4 (Cyclone IV, Probe, Sample Venturi, Mixing Cone, Residence Chamber, Filter Holder Inlet) o less than PM2.5 acetone rinse . Container No. 5 (Filter) o 142 mm filter A sample train blank was not collected. Fra AST-2023- l 660-0 I 0 HF Sinclair - West Bountiful. UT Page 3-2 puahrpe ll '-i !\J i. .r irt ai.j [:Source Tesl Reporl 1'estins Methodolosv 3.5 U.S. EPA Reference Test Method 19 - Mass Emission Factors Fuel samples were procured and analyzed onsite by HF Sinclair. Samples were collected as close as possible to each test run for each source. The laboratory analysis was used to calculate a dry Ou based F-Factor in accordance with U.S. EPA Reference Test Method 19. The mass emission factor (lb/\4MBtu) was calculated using the pollutant concentration, 02 concentration and the calculated F-Factor. 3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3A Cylinder calibration gases used met EPA Protocol I (+l- 2o/o) standards. Copies ofall calibration gas certificates can be found in the Quality Assurance/Quality Control Appendix. Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases were sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5%o absolute difference. High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe and the time required for the analyzer reading to reach 95 percent or 0.5%o (whichever was less restrictive) of the gas concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was recorded. Next, Low Level gas was introduced at the probe and the time required for the analyzer reading to decrease to a value within 5.0 percent or 0.5%o (whichever was less restrictive) was recorded. If the Low-Level gas was zero gas, the response was 0.5%o or 5.0 percent ofthe upscale gas concentration (whichever was less restrictive). The analyzer reading was observed until it reached a stable value and this value was recorded. The measurement system response time and initial system bias were determined from these data. The System Bias was within 5.0 percent ofthe Calibration Span or 0.5% absolute difference. High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the analyzer response was stable, the value was recorded. Next, Low Level gas was introduced at the probe, and the analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the Calibration Span or 0.5olo absolute difference or the data was invalidated and the Calibration Error Test and System Bias were repeated. Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.57o absolute difference. Ifthe drift exceeded 3 percent or 0.5Yo, the Calibration Error Test and System Bias were repeated. To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The pollutant concentrations were measured at three points (16.7, 50.0 and 83.3 percent of the measurement line). Each traverse point was sampled for a minimum of twice the system response time. If the diluent concentration at each traverse point did not differ more than 5 percent or 0.3Yo (whichever was less restrictive) of the average pollutant concentration, then single point sampling was conducted during the test runs. If the pollutant concentration did not meet these specifications but differed less than l0 percent or 0.5%o from the average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in diameter - 16.7, 50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter - 0.4, 1.0, and 2.0 meters from the stack wall). Ifthe pollutant concentration differed by more than l0 percent or 0.5o/o from the average concentration, HF Sinclair - West Bountiful, UTAST-2023-1660-010 12 of 201 Page 3-3 put6rrce TECHNICAL GFlOUP Source Test Report Testins Methodoloev thensamplingwasconductedataminimumoftwelve(12)traversepoints. Copiesofstatificationcheckdatacan be found in the Quality Assurance/Quality Control Appendix. A Data Acquisition System with battery backup was used to record the instrument response in one (l) minute averages. The data was continuously stored as a I.CSV file in Excel format on the hard drive of a computer. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data was relinquished to the report coordinator and then a final review was performed by the Project Manager. HF Sinclair - West Bountitul, UTAST-2023- I 660-0 l0 l3 of20l Page 3-4 l4 of20l AIffirrceTECH\iCAL GRO{JP Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Run No. /Method Run I / Method 3,{ Oz - Outlet Concentration (C$, % dry Co,= (Co,-Cor. ( #;) where, Cor, -!{- : average analy zer value during test, o/o dry Co 0.10 = average ofpretest & posttest zero responses,o/o dry Cro A : actual concentration of calibration gas, o/o dry CM 10.92 : average ofpretest & posttest calibration responses, %o dry Co, 7.55 = Oz Concentration,o/o dry 15 of20l allffirrceTECH\ICAL GROUP Location: HF Sinclair Woods Cross Refinins, LLC - West Bountiful. UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Run No. /Method Run I / Method 3,A. COz - Outlet Concentration (C6sJ, 7o dry cco,= (cor.-co). ( #e;) where, CdD" 7.46 = average analyzer value during test,o/odry Co 0.06 = average of pretest & posttest zero responses , % dry CMA 10.74 : actual concentration ofcalibration gas,Vodry CM 10.75 : average ofpretest & posttest calibration responses, o/o dry Cco, 7.43 : CO, Concentration, %o dry l6 of20l alIffirceTTCHNICAL GROUF Location: HF Sinclair Woods Cross Refinin g, LLC - West Bountiful, UT Appendix A Example Calculations Source: Process Heater 20H3 Project No.: AST-2023-1660 Run No.: 1 Parameter: VFR Average Stack Gas Flow at Stack Conditions (Qa), acfm Vs 19.9 : stack gas velocity, fVsec As 18.35 = cross-sectional area ofstack, ft2 Qa 21,946 : acfm Average Stack Gas Flow at Standard Conditions (Qs), dscfm Qa : 60x Vs x k where, gs - 17.647x Qa * (t - BWS)" P' Ts Qa 21,946 : ave.age stack gas flowat stack conditions, acfm BWS ;!![: moisture fraction, dimensionless Ps 25.78 = absolute stack gas pressure, in. Hg Ts 1091.6 : absolute stack temperature, "R Qs 7,684 : dscfm 17 of20l AIffirre Ti: Cl'l f; I CAa {l trC l..l i) Conditional Test Method (CTM) 039 Example Hand Calculation QA Facility: HF Sinclair Woods Cross Refining Source: Heater20H3 Run No.: Test Date:8t29-8BOt23 Wt,tVol of Aetone Blank (mglmL); Contrin€r No. 6 ^ l.l9v' 239.i * o-1.g Lr - 0-0063 mg/mL n " : Net lleight ofAcetone Blank (Contoinet No. 6), mg V " : Volume ofAcetone Blank, mL 0.79 g cmr : density ofqcelone Net Weight ofPM Due to Acetone, mgi Cortainer No. 2 wa = 53.7 x 0.0063 wa = V ", = l/olume of Acetone, mL C " : Wt. Vol. ofAcetone Blank, mg mL Net Weigha of Psrticulate Mataer (Blatrk Correted), mg; Container No. 2 h2-"o". = 0.0000 - 0.337 E2-"o", =0.0000 mg m 2 - lyeight of Pdrticulate Mauer (Contqiner No. 2), mg W " : Net Weight of PM Due to Acetone, mg *For resulb rcpo(ed with negative results,0.0000 ws used for the cdcuhlions. Net Weight of PM Due to Acetone, mg; Contriner No. 4 Wr-207.3 x 0.0063 wa = V o, : Volume ofAcetone, mL 0.790* C . = l{t.'Vol. ofAcetone Blonk, mg'nL *nax a llo$db le sub irct ion Net Weight of Particul.te Mrtter (Blank Corrsted), mgi Coniriner No. 4 h+"o.. = 0,E60 - 0.790 h2-co.. = m t : Weighl ofPotticulqte Matter (Contaiher No. 1), mg W " = Net Weight of PM Due to Acetone, mg *For rcsults reponed with negative rcsults,0-0000 wil used for the calculations WtJVol of DI W8aer Blank (mg/mL); Contriner No. 7 C*= 276.7 v" C*=0.0052 mg/ml 0.337 0.070 t.4s = Net Weight ofAcetone Blank (Container No. 6), mg : Volume ofAcetone Blank, mL l8 of20l lffirrce Ti- irl, - \ :'"s|, ' ' Conditional Test Method (CTM) 039 Example Hand Calculation QA Facility: HF Sinclair Woods Cross Refining Source: Heater20H3 Run No.: Test Date: 8129-880123 Net Weight of PM Due to DI Water, mg; Container No.3 tvw= 166.8 x 0.0052 ww = 0,874 mg V *, - Volune of DI lilater, mL C. = Wt. Vol. of Dl lllater Blank, mg,'ml Net Weight of Prrticulate Mrtter (Bhnk Correted), mg; Container No. 3 h3-"o""= 0.840 - 0.874 lll3-"oo = 0.0000 mg m 3 : Weigfu ofPqrticulate Maner (Contqiner No. 3), mg W " : Net tyeight of PM Due ro Dl lYqter, mg 'For resulb Epo(ed with negative rcsu|ts.0.0000 was used for the calculations Conetraration (mg/dscm) LPMI0 - (0.0000 + 0.0000 + 0.070 + 0.650)CPuro = 0.330 mgldscm2.18 C pLrn : Pqrticuldle concentrqtion (ng'dscm) m 2-@t : Containet No. 2 Mass - PM <10 pm and >2.5 pm (Acetone Rirce); Net Weight ofPqfiiculate Matter (BlonkConected), mg m j-"oo : Container No. 3 Mass - PM <2.5 pm (Dl Riwe): Net Weight of Pqiliculqte Moilet (DI Wdtet BlonkConected), mg m !-con = Container No. I Mass - PM <2.5 pm (Acetone RiNe); Net Weight of Particuldte Mqttet (Acetone Blank Corected), mg m5 = Contqiner No. 5 Mqss - PM .:2.5 pn (Filter): Weight of Parriculate Matter, mg V,roal = Sample volume al standord conditions (m3 ) Emission Rate (lb/MMBtu) D - Cr*ro *p * 20.9L pI4 rn - :-:--:-:-::------:o - 35 .3147 x453,592 ^' o ^ (20 g-olr) E pLrn = Emission rqle (b'MMBtu) C p111s : Pollulant concentmlion (mg/dscm) F a - Dry O 2 bosed F Fqctot (dsclMMBtu) O 2 = Stack gos orygen concenlrdtion (96vd) 0.330 x E.2Et.0 x 20.9Epnro = 3s.3147 X 4s3,s92 l9 of20l ( 20.9 - s.98 ) Eruro = 2.4F.04 tb/tltMBtu punffirpc! l'fal",NICAi Oll()iir Conditional Test Method (CTM) 039 Example Hand Calculation QA Facility: HF Sinclair Woods Cross Refining Source: Heater2OH3 Emission Rate (lb/hr) Er*ro:fuxQ"ax 6o Run No.: Test Date: 8129-880123 M pLrrc : Emission rate (bihr) C p111s : Pollutant concentmlion (mg'dscm) Q s - Stack gasJlo'| rqte (dscfm) 60 : Minules per hour _ 0.33 X 7,903 X 60 J5.3147 X 453,592 Emision Rate (lb/MMscO ER ,* to = M pM to + Fuel- llow Mpuro = 9.8E-03 tb/hr ERpuro = 4.6E-01 Ib/rlrMscf 106 DPMI0 - ER pyp : Emission rqte qb/MMscl) M pMrc - Emission rote qbihr) Fuel Flow : Fuel gasJlm, rute $cJh) 9.8E-03 / 21,220 1,000,000 2O of20l 2l of20l AIffirpeTeei{N1c"{L aRe{Jp Emission Calculations Lo.ution Source Process Heater 20H3 Project No. .{ST-2023-l 660 Prrrret"t lun Number Runl Run2 Run3 Averase )ate itart Time ;top Time lun Time. min (e) 8/25/23 8:26 12:56 240.0 243.7 8t28-8/29/23 8t29-8130/23 23:03 23:30 3:12 3:38 239.9 251 .2 INPUT DATA ruel Gas Flow Rate, scfh {eat Input, MMBtuihr ruel Factor (O2 dry), dscflMMBtu ]arometric Pressure, in. Hg vleter Correction Factor .lozzle Diameter, in \rea of Nozzle, ft2 lotal Mass of PMl0 pm, mg (m2 + m3 + m4 + ms) lotal Mass of PM <10 pm and >2.5 pm, mg (m2) lotal Mass of PM <2.5 um. ms (m. + m" + m.) 20,783 18.51 8,26s 25.75 1.142 0.370 0.00075 1.47 0.000 1.47 (FR) (HD (Fd) (Pb) (Y) (Dn) (An) (mpr,aro) (mpvro-z.s) (m*,,J 20,190 18. 13 8,255 25.80 1.142 0.370 0.00075 2.16 0.000 2.16 20,940 17.27 8,2s9 25.77 1.142 0.370 0.00075 1.54 0.000 1.54 21,220 20.13 8,28 r 2s.68 1.142 0.370 0.00075 0.720 0.000 0.720 CTM-039 LOGGER DATA )ilution Flow Rate, dscfm iample Flow Rate, dscfm r'olume Sampled, dscf y'olume Sampled, dscm y'iscosity leynolds Number )unningham Correction Factor )articulate Cut Diameter for PMl0 )articulate Cut Diameter for PM2.5 )itution Ratio vloisture Fraction Measured sokinetic Samnlins Rate (o/") 6.86 0.328 78.6 aa1 285.6 I,846.6 l. l6 10.28 2.60 21.82 0.t57 103.s (Q,rr",,r) (Q"a,a) (V"r",a) (V"a,a) (u) (N*) (c) (D:o) (Dso) (DR) (BWSmsd) (n 6.91 0.328 78.6 2.23 288.4 1,840.5 L16 10.47 2.s8 21.87 0.160 104 8 7.01 0.333 79.9 2.26 284.2 1,890. I l.l6 10.09 2.53 21.94 0.160 105 I 6.66 0.322 77.1 2.18 2U.4 1,809. I l.l5 r0.29 2.68 21.65 0.150 100.5 EMISSION CALCULATIONS )M l0 Concentration, grain/dscf )Ml0 Concentration, mg/dscm )Ml0 Emission Rate, lb/hr )Ml0 Emission Factor, lb,MMBtu (O2) )Ml0 Emission Rate, lb/MMscf fuel gas (Cpuro) (Cpvro) (PNR) (EFpruro oza) (ERo,n) 0.00042 0.969 2.8E-02 7.8E-04 l.4E+00 0.00030 0.680 2.0E-02 4.9E-04 9.58-0t 0.00014 0.330 9.8E43 2.4E-04 4.68-01 0.00029 0.660 1.9E-02 5.08-04 9.3E-01 PM< PM< PM< PM< PM< 0 pm and >2.5 [m Concentration, grain/dscf 0 pm and >2.5 lrm Concentration, mg/dscm 0 pm and >2.5 pm Emission Rate, lb/hr 0 pm and >2.5 pm Emission Factor, lb/lvlMBtu (O2) 0 um and >2.5 um Emission Rate. lb,MMscf fuel gas (Cpr"lro-z.s) (C"r,n-, s) (PMR) (EFpr',rro-z.s oz,r) (ERo,n-r r) 0.0000 0.000 0.0E+00 0.0E+00 0 0E+00 0.0000 0.000 0.0E+00 0.0E+00 0.0E+00 0.0000 0.000 0.0E+00 0.0E+00 0.0E+00 0.0000 0.000 0.0E+00 0.0E{{0 0.08+{0 ,M <2.5 Concentration, grair/dscf )M <2.5 Concentration, mg/dscm >M <2.5 Emission Rate, lb/hr )M <2.5 Emission Factor, lb/MMBtu (O2) >M <2 5 um Emission Rate lb/N4Mscf fuel sas (Cpu:.s) (Cpv:.s) (PlvR) (EFpr"rz.s oza) (ER"^,,.) 0.00042 0.969 2.8E-02 7.8E-04 I 4E+00 0.00030 0.680 2.OE-02 4.98-04 9 5E-01 0.00014 0.330 9.8E-03 2.48-04 4.6E-01 0.00029 0.660 t9E-02 5.0E-04 9.3E-01 22 of 201 HF Sinclair Wods Crcss Refining LLC west Boutiful, UT Lab Data Process Heater 20H3 August 25 & 28-30, 2023 Run I Run 2 Run 3 lontainer No. I Mass - PM >10 um iample No. fleight of Particulate Matter, mg (mr) y'olume of Acetone, mL (V*) .let Weight of Acetone Blank (Container No. 6), mg (m") /olume of Acetone Blank, mL (V") ilt./Vol. of Acetone Blank, mg/ml (c,) ,Iet Weight of PM Due to Acetone, mg (W") .let Weight of Particulate Matter (Blank Corected), mg 14G33467-l 0.,145 58.2 l.l9 239.7 0.0063 0.366 o.079 140-33467-6 0.280 65.4 1.19 239.7 0.0063 0.41I 0.0000 14u33467-tl 0.0100 60,4 l.l9 239.7 0.0063 0.380 0.00u) lontainer No.2 Mass - PM <10 um and >2.5 um iample No. treight of Particulate Matter, mg (mz) /olume of Acetone, mL (V*) {et Weight of Acetone Blank (Container No. 6), mg (mJ y'olume of Acetone Blank, mL (%) ilt./Vol. of Acetone Blank, mg/ml (cJ {et Weight of PM Due to Acetone, mg (W") ,let Weisht of Particulate Matter (Blank Corrected). mg 140-33467-2 0.230 41.3 l.l9 239.7 0.0063 0.260 0.fi)00 t40-33467-7 0.0000 88.3 l.l9 239.7 0.0063 0.555 0.0000 140-33467-12 0.0000 53.7 l.l9 239.7 0.0063 0.337 0.0000 lontainer No.3 Mass - PM <2.5 [m iample No. ileight of Particulate Matter, mg (mt) y'olume of DI Water, mL (VJ .let Weight of Dl Water Blank (Container No. 7), mg (m*) /olume of DI Water Blank, mL (V") ilt.iVol. of DI Water Blank, mg/ml (c,) .let Weight of PM Due to DI Water, mg (W") ,let Weight of Particulate Matter (Blank Corected), mg 14u33467-3 1.29 160.9 1.4s 216.7 0.00s2 0.843 0.u7 140-33467-8 0.370 137,7 1.45 276.1 0.00s2 o.722 0.0000 140-33467-13 0.840 166.8 l.4s 276,7 0.0052 o.874 0.0000 lontainer No.4 Mass - PM <2.5 um iample No. ileight of Particulate Matter, mg (m+) y'olumeofAcetone, mL (V-) ,let Weight of Acetone Blank (Container No. 6), mg (nU) /olume of Acetone Blank, mL (%) ilt./Vol. of Acetone Blank, mg/ml (c") rlet Weight of PM Due to Acetone, mg (W") .let Weight of Particulate Matter (Blank Corrected), mg 14033467-4 l.7s 193.9 l.l9 239.7 0.0063 0.790 0.960 140-33467-9 1.33 164.0 l.l9 239.7 0.0063 0.790 0.s40 r40-33467-14 0.860 207.3 l.l9 239.7 0.0063 0.790 0.070 lontainer No.5 Mass - PM <2.5 um iample No. ileight of Particulate Matter, mg (ms) 140-33467-5 0.750 14G33467-10 1.00 r4G33467-ts 0.6s0 Note l: For results reported with negative results, 0.0000 was used for the calculations. Note 2: Regent Blanks from 5/16/23 23 of20l gAIiatrcE) TEC-'IN"CAL fiFlOU:) Volumetric Flow Rate Data Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source Process Heater 20H3 Project No. AST-2023-1660 Parameter PM (CTM-039) lun Number Runl Run2 Run3 Average )ate itart Time itop Time lun Time. min 8t25t23 8:26 12:56 240.0 8t28-8/29123 8129-8130123 23:03 23:30 3:12 3:38 239.9 2s1.2 243.7 CALCULATED DATA litot Tube Coefficient farometric Pressure, in. Hg Itatic Pressure, in. WC Itack Pressure, in. Hg itack Cross-sectional Area, ft2 femperature, oF femperature, oR Vloisture Fraction 3O2 Concentration,o/o )2 Concentration, o/o Vlolecular Weight, lb/lb-mole (dry) Molecular Weight, lb/lb-mole (wet) VelociW. fVsec (cp) (Pb) (Pe) (Ps) (As) (Ts) (Ts) (BWS) (Coz) (o, (Md) (Ms) ffs) 0.758 25.80 -0.26 25.78 18.35 631.6 r091.6 0.160 7.43 7.55 29.49 27.78 19.9 0.758 25.77 -0. l9 25.76 18.35 605.0 1065.0 0.160 8.33 5.86 29.57 27.66 19.7 0.758 25.68 -0.19 25.66 r 8.35 602.2 1062.2 0.150 8.46 5.98 29.59 27.77 19.8 0.758 25.75 -0.21 25.73 18.35 612.9 t072.9 0.157 8.08 6.46 29.55 27.74 19.8 VOLUMETRIC FLOW RATE A.t Stack Conditions, acfrn A,t Standard Conditions, dscfm (Qa) (Qs) 21,946 7,684 21,727 7,789 21,809 7,903 21,827 7,792 24 of 201 ellffirEBTTCIINICAL GN$I,' P Cyclonic FIow Check Location HF Sinclair Woods Cross Refinine. LLC - West Bountiful. UT Source Process Heater 20H3 Project No. ASI{023-l{60 D*e 8125123 Sample Point Angle (AP=0) I 2 3 4 5 6 7 8 9 l0 ll t2 l3 t4 15 16 Average 0 0 5 5 5 5 5 0 0 5 5 0 5 l0 5 0 3.4 25 of 2Ol Almrrce TTCIINICAL ENOUTl Method 4Data Location HF Sinclair Woods Cross Relininq' LLC - West Bountiful, UT Source Process Heater 20H3 Project No. AST-20?3- Parameter(s) Moisture Console Units / Method ft3 M4 Run No. Date Status Start Time End Time Run Time, min (e) Mafer ID I 8t2st23 VALID 7:20 8:05 60 MB-704 Meter Correction factor (Y) Orilice Calibration Value (AH @) Max Vacuum, in. Hg Post Lsk Chmk. ft3lmin (at max vac.) 0.992 1.860 4 0.000 Vleter Volume, ft3 0 5 10 ls 20 25 30 35 40 45 fotal Meter Volume, ft3 (Vm) 482.564 485.730 488 835 492.010 495. t60 498.3 l5 50 1.440 504.570 507.700 5 I 0.829 28.26s Temperature, oF 0 5 l0 l5 20 25 30 35 40 43 Average Temperature, oF (Tm) Average Temperature, oR (Tm) Minimum Temperature, oF Mrximum Temnerature. oF Meter 80 76 76 76 76 76 76 77 s36 76 80 Probe Filter Vacuum 4 4 4 4 4 4 4 4 4 4 4 4 4 Imp. f,xit 67 62 60 59 60 60 6l 62 63 63 62 59 67 Sarometric Pressure, in. Hg (Pb) Vleter Orifice Pressure, in. WC (AH) Ueter Pressure, in. IIg (Pm) itandard Meter Volume. ft3 (Vmstd) 25.16 0.600 25.20 23.236 lnalysis Type ,mpinger I, Pre/Post Test, g .mpinger 2, Pre/Post Test, g lmpinger 3, Pre/Post Test, g lmpinger 4, PrelPost Test, g folume Water Collected, mL (Vlc) itandard Water Volume, ftr (Vwstd) Vloisture Fraction Measured (BWS) ]as Molecular Weight, lb/lb-mole (dry) (Md) DGM Calibration Check Value (Yqa) Gravimetric H20 H20 Empty Silica 420.0 427.t 311.4 587.9 460.0 433.5 340.9 591.9 40.0 6.4 29.5 4.0 79.9 3.t6t 0.140 29.49 0.7 26 of 201 3C N € F t3 t t E E t E t E 3 3 S t E 3 3 3 3 E 3 3 E E 3 E 3 E E 3 E E e E E 3 3 E 3 E 8 8 3 8 E E 3 3 E E 3 3 E 3 3 E E 3 3 3 g 3 8 3 E E 8 d ^ d d d ^ ^ d ^ d d d d d d d d d d d ^ d d d d d d d d d d d d d ^ d d d d d ^ N d d ^ d N d d d d d : :3 F R 8 5 E - E s n i $ E $ i : a i q r i i s q i F S a i q n : 6 E s * S E a E q i : s e q i { 5 a E q 3 : S E I q I E i E i i : S j: - - . ; eh r - o 3^ * d { . = o e f e : A A - i = a = = ! I = 5= h n a a * a l l n 9 i e q Q q - - n i l n n i i f nn l n a n n n n n l n a a a a a n n a a a n a n n t ! a e t a q a n n n n n t q9 q P a e a n f :n 1 1 9 9 e q ? e n ? q q - c - q ? e n q - - - - Q e ? - 1 - - Q n - q - - q q e E s S .! - n :s t2Eiaa€t s 8- 1 aq a Q e ? Q ? q i t t t t i t t t \ t i i i i t i t t i i i i i i i r i i i i i i i i i i t t i i i t t i i co q q n ! 9 F 68 6 q q q a s a q q a a q a 5 q q 5 8 s q a i s s 8 8 8 3 a $ q 6 5 6 6 6 6 6 6 6 ; ; a 6 6 a a 5 6 6 5 i n a ; ; i e ; i 6 6 6 6 6 Ca 3 3 - +6 o c F 6+ o o t s i: d d d d d d d d ^ N d d - e - d e d d 6 d e 6 ;; ; + ; , + + 6 6 - 6 OO Yo t. E3. " (J RA F = E ; p S F a F A F f r F B f r f r e E R ; R g p n B g p n ; 8 = f ; 8 : E S E : * s 3 ! E E S i A * 3 : ? S : e q E = . s 6 3 = 9 c E tF :E'E .eIE rF-esa-r 27 of 2 0 l .! * : 3a g ts : : - n n t i q q i 6 9 9 9 < l a a l n n l l n e a i l n r n n a l a l q q n n i a n n a a r r i ?? 9 n n n a l a a a a a a a n n n n l q a n n a a a a a a n a a n a a n a n a a n a a n n a n a a -5 d € r F 6 6 - € aa x q i 9 ! a 9 ? a ! 9 i P q 9 q - a n n q n n a a n n a a a a i i a n a a a n n a n n a n l l n qq q q q q q q n q q q q q q q q q q q a q q q q q q q q q q q q q c q q q q ii i i i r i i t l i \ r i r i t i i i i l i t F i i i i F t i i i t i i i t t t t l i t t i i t 50 ; 9 t a q 1 a { 9 q 1 9 Q 9 n q n n n i - i : 9 n i a q ? 9 * i q c - i i i l 9 9 l a n l q q q ' - ; : = : 9 ! ! ! = = = = = 22 2 2 2 = = = = = = 3 = = = = 3 = = = = = = I = = = = = = 22 2 = = n! Q 9 n q 9 I a A l n : q l 1 q q C 9 l n e C 9 l q : q t ! a - q i 9 a : a t ! n - q t 9 1 n q d? = = = 3 r - e -- - e - r ! 5 : E I 3 :8 C 3 g e ra o * 9 - n i n C a i q l a P t i q q n l 9 q Q - l l ? :: - o d r d 6 d r : : r : : ! 3 3 8 8 8 8 8 8 8 5 E 5 8 5 5 5 8 5 Pq q q q q q q q q 6 3t 3 3 9 3 3 8 3 t t 3 3 t E 3 8 8 3 E 3 3 8 8 8 8 3 3 3 8 3 3 3 8 3 8 8 3 3 3 3 3 3 8 8 ^d ^ i d d d n d d d N d ^ A i N A d d d ^ ^ ^ a d n d i ^ { d n ^ n ^ ^ ^ cc i i i i i i t i t t t i t i t i f t t i i i i i i i i \ t r 33 3 3 e 9: : 9 9 S3 E n e i F E B R a E s s e E B $ 3(r a E. E B. e ?! .9 3 QEat ;e ii 6 ; ; ; d d ; ;5 d i d j j i l i i i i ; ; ; ; +; * ; 6 ; ; f r d ; ; ; d i d d & & d -& & & - - - - - ; e d i 6 A n a a ; 6 i d ; ; ; ; d ; ; d d . d ; ; d d d 6 dd n ; d d d t ; n d e Et }E 4 -? :t s ': -o \ 14 1 1 4 1 4 1 1 1 1 1 6; ; ; d - ; ; d + ; 6 + dd d d d d d d d d d d 33 8 3 E 3 3 3 8 3 8 8 ,h h h 6 r 6 l nq n q a q q q q q q q ;i i i i i i i i i i ; id ; 6 d d r d 6 d i i :n 9 e - n 9 e - n 9 t 6; i d d d d 6 6 6 6 6 28 of 2 0 1 an n n n t n n n n n r t n n n l 9 a n n l n n l t n n n n t t n t n n l - l - - a : aa a a a a a a n a a a a a a n a a a a a a n e a n n n a n n t a l l i i i a i n n a nn n n a a l a a a l l a a a a n i a i n 9 a a e a a l ! a l n a n a a r n r n e a a 88 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 3 3 8 8 8 8 8 3 3 8 8 8 8 99 4 9 e 9 9 9 9 9 9 9 9 ! 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 r 9 ! 9 r ! 9 9 9 9 9 9 9 9 ii i i i t r i i i i i i i i t i i t i i t i i i i i t t i i i q i i i t t t t f it ii e e r e ? q q q q q e P e e e e t t i t i t 9 9 9 t 9 9 9 9 9 9 9 9 t n n 9 n ! ! -o d l r ^ i | : 3 l to + 6 i Q ln t t ! n 1 1 n a 1 a ! a 1 n 1 n n n 1 1 a - a 1 n 9 ! 1 n - r 1 1 9 r n l a ! 9 4 -- o - c o - - qq q q q q q q q q q q q q q n q n q q q q ? q q l q q q q q q l q q q q q q q q q q ti i t \ t \ F i i i i q t r i t t t t i i i t i t t t i \ i t i i i t i t i i i i i at. E 3. 9 6: .: ao3E2 ii i i e i s F ; ; i ; i d d d o' o o o I r : : i i n n ; ; J ; ; ; ; ; 6 6 ; ; G U .b b i -- - - - - i : a i - i : : t n t n n t t t n n n n t t n t n l n t n t n n : t n s l an q a q a a n a a a a a a a n a a a a a a n a a a n n q qq q q q q q q q q q q q q q q q q q q q q q q q q q q q 1a a a a i a a n 9 9 a n q 1 a q q l a a 9 a 1 1 1 ! 9 1 na a a a q 1 a q 1 1 n a a a I n I l t a i 1 1 l l 1 l 1 qq n q q q q q a q q q q q l q q q q q a q q q q q q q q 33 E E 3 3 8 3 3 3 8 8 3 3 3 3 3 3 3 3 3 3 3 3 3 8 E 3 3 ji e i i d d jd + + d d d n j ^ i + d h r - d 6 - r i , it F i i i i i q t i i t t i i i t t r i i i o ! a i i i i ji + G - a j ; d F -d d + € F 6 j; d G d d d r d r 6 - .d d o d d i s : - : : - - - - - : : r d d i l d d d d d d 9: n : 9 : i i 9 : n a 9 : t a n : n i 9 : n : 9 : t l : 29 of 2 0 l a I nn n a l qI n9 a a ! a a 1a l n a l a a a 1 a 1 - : a a a a n n n q !: ! !3 :a,r z !,EIt_ . 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Q n n n l n n 9 Q n i 9 ? n a t 9 a e 9 ? n * 9 Q c 9 9 ? n n 9 9 n a n Q i * 3 9 c r 9 :! a : : : 1 4 : l r : a i a a a a l a a n a a a l i l t a a a : 1 9 9 r 9 9 ? ? : 9 r n r r 9 9 ? n 9 9 9 9 9 9 9 hs € € o €o F F F ,c d r 6 ;R E s ; 8 3 3 a 8 3 ; s ; 8 ; 3 s 5 q q a 5 c q 3 E l q a a n 6 * 4 q e q i E q S i S s E l E q E l E s E i E s q 6d 6 6 6 6 d d d d d - d d d d d d = 9 = = = = = = s a ! ! ! : ! ! l = = : ! : : ! 9 9 9 9 ! : : . ! 3 = = = 3 9 : 9 40 of 2 0 l FE l !n=a il 2 a n- ^ ^ - 4? = r t r ? r ? ? = = ? ? a = 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 3 3 8 8 3 3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 El d ^ N ^ '1 ^ ^ ^ ^ .d ? : : = ? : ? ? ? i ? ? = i r 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 3 3 8 8 3 8 8 3 3 3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 El d d d N f= . : = e r 5 = - 8 S F 3 ; t ; - e 8 A R $ A 9 S $ R 3 3 a 3 F G ; S S R : 3 3 $ F G G ! ; * : 3 X S F € 8 { i { = 5 4 { ( q s i n n j^ ; - ; ; = ! : e = e i t s i R ; ; g e r ? $ s * + B f f fr f r hs ; i E G g F F F F F a s c E g a ; i t E e - E E E 3 = : : : = E ! 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E 3 3 E a A a a A E E E 3 3 3 a E 3 8 3 E A - a A e A E ; nl a a i n Q q e 9 n ! 9 9 9 i i \ i 9 q 1 - a 1 9 i q ? l 1 n l r 9 dd d d s 0a ? c 3 -6 F 1 - q a a q q r 9 l a a a e - 9 q q q q q t 9 n i q q e i 9 ! l il F F F F F F T F F F F F F F F F F F S il n - ^ A d & - A N i9 q i q t Q a n n ? ? : t q - 1 9 i - l t q a q q e l i - t q q n 9 6d - 6 - d+ n n N n N n n n n n l n n n n l t t t l n l n i n l l l l n n n -- - R - ^ - - - - 8S s 5 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 id c i o S a d d o o 3 S = i o o - o 5 5 5 o o o i d i 3 o o o . 3 5 -h 9 a 9 i r i q e i i i r \ t ! ! i { i 9 q i 9 i t t q AA - N d 66 U 6 4 FF F F a d t s r F d t s - - n F F€ s o € € € e € 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 € 9 9 9 9 9 9 € 9 9 9 € 9 9 9 -- S c d d d o d i d d d o o 5 o s s o c c a i i d . - 3 c a o i -6 6 . - 6 h 6 N - 6 6 d - 6 il d d ; & d . d 6 a d o o c o r : r : i i n i n ; - a + ' ; ; ; f r nn t t $ n s n n n n n r a a n n r a n P 9 l a ! a n a n r r n n 44 of 20 1 E s ! !e:+s; 9l n n l I n l I n - q ? q q q q t ! 1 ! ! 9 9 ! 9 1 1 1 9 9 €E 8 2 5 5 5 6 5 ; 5 6 6 6 5 i 6 E E U E e9 9 e n ? q t 9 1 a : ? e i 9 a n - a e 9 9 e n C q i 9 l n A3 E t A E E E E E E 3 3 E 8 3 E 3 3 3 E E 3 3 3 E E E 3 E 3 3E 8 8 E E E E 8 E 8 3 C E 3 E E 3 3 3 E E 8 E 3 3 3 3 3 3 3 3 == = = = 9 = = = = = : = 9 = 3 = C = = = : = = 3 = = = = = = = 9! e q q q : l - q l t q q q l I ? : : q - n a a a 1 9 9 9 ? noa :. i .3 .2 _ (JIH8{i8= ;e-z a tn In n n l i t n i l n n c e n i n t l l n l l t t l t n n l l ?? ? ? ? ? ? ? ? ? 9 ? 9 ? ? ? 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" ? ? ? ? ? ; 9 Q ? ? ? ? ? ? 9 ? ? ? ? ? ? ? l ? ? ? ? ? ? ? d ^ d ^ ^ nN ^ n ^ N n d n ^ ^ N n d N ^d ^ N ^d ^ N d d Es E F a P x s e a e x P s E * 8 8 8 8 3 8 8 t 8 5 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 22 2 2 2 Z 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 Z 2 2 2 2 2 2 2 2 > 2 ; aa a G F F F r & & & * 5 d d d A d 5 5 i r r : i n n n ; ' - - - + + r + h 6 6 6 45 of 2 0 l .^ n o i -- d + 6 F 6 - d 6 8E 3 8 3 3 3 E E 8 E 3 E 3 E 3 3 E E E 8 E E E E E3 3 E E E 8 E E E E 3 E E 3 E E 3 8 3 3 3 3 3 E I eX !- FZE ? ,e2A 1r 9 9 9 e q ? - r a ! 9 9 i t t t l q a q ? a n q tq n ! q q q a 9 q - i d ?? a R 3 8 8 8 R 8 8 8 ?q q q q i 9 a 9 9 q i 9 ! ! ! 9 i i 9 ! ! ! 9 e r@ o 9 9 al t 9 t e q q q - n n l i - - : - - q q q q q q 9{ n < F ! 9 9 a 9 9 9 * { q q 9 9 ! a ! 9 9 9 9 n 88 8 5 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 3 8 8 8 8 oi o o o S S o o o o S S S d a d d d d d d o o d -i l n q t l q q q t * n n 9 9 ! i n i n a - - n an n o r d d N d ^ r e d a a d N d d d d d d d d !(. ) A !Eoc _a8. 9 .: H (J n: ? . n 9 I i a : t c i n: ? it a Q : n a 9 : 9 - - - - - - - - -. - . : a i i I n n e q n n s n n I 19 9 a n n a 9 ! 9 1 n q e - q q \ ! a n a n l l ? n ? r e t 9 a 1 - t n ? - ? 9 ! 1 9 9 9 9 5C 3 a C 3 0 0 0 ? C = O a o :9 ? i t a l : q Q 9 ! n n q q i 9 ! a n ? { i l a n - c r 9 ! n a l q t 9 a a : ? * t ! a n 88 3 3 3 3 3 3 3 8 3 8 3 3 3 3 8 E E 3 8 8 3 8 8 3 8 8 8 8 3 3 8 8 8 3 3 8 3 3 3 3 3 3 3 3 8 3E 3 3 E E 3 3 E E E E E E E E E 3 E 3 E E 3 3 3 8 3 3 3 3 8 3 3 3 3 E 3 E 3 3 3 E 3 E E E 3 ?? q * ? I a q q e e e @ a e f te e t * * q q e { r e a q { e € 4 " ! e q e a ? T p a ? Q e !n q 9 I i n n l : q q q q q q q ? : - n n n n n t a n n n i n n a n a n n n l l 9 ! n 9 9 ! li a n a a n - q i 1 a - - n n n a 9 i c € t 9 a a 1 9 r a 1 a t 1 ! 9 q t ? q q q q q e t i aa 1 9 9 9 9 i i i l t 9 t i i 9 q q q q a " q ? 9 Q - - - n c n n l n a l n ! ! 9 9 1 a n a 1{ a 9 9 q 9 ! - - n 1 - q q n Q t q 9 a a l q n 9 P q i q a l ! q t i : 1 9 e i 9 e ! - e ! a9 a n a 1 ! ! 1 l l t a 9 9 e 9 e q q q q - l t a n n n n t q - r n ? 9 ? I i q 9 1 q { e P ?? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? c ? ? ? ? ? ? ? ? t ? ? ? ? ? 9 ? nd d d d { i d d d d d N d N d A d d i d N d d d d d d ^ N d d d d d d d d d d d d N d d d d 2 2 Z 2 2 22 2 2 2 2 Z 2 2 2 2 2 22 2 2 2 2 22 2 2 2 2 2 2 2 2 2 22 2 2 2 > 2 > > > > > > :! : ? : t : ? : t t ? n t 9 9 n t 9 : t a t 9 t a 9 Q r i ! c a : t q n I t e i n 9 9 l t 9 : : "€ : : : : : : : : .E : : : "5 : .5 : : E : 5 : 5 : : : : 5 5 : : : : : 5 : : : : "B E : .E : : i d d d d 3o o d i d i d i d o c 5 5 5 o o d j i = o o c d d d i d d o 5 46 of 20 1 i; 3 .! * p EA i2E ++ 6 d n i d 6 d d 38 3 8 3 3 3 3 8 E EE E E E E s E E E 66 6 6 6 6 6 6 6 d 6tUAYu !E_a8. 9 .EEE QfEu{E '€g6 ;i 1: 9 i n i ? - - q !1 9 9 9 q q 9 q n tn e 9 e e n q - l 66 r 9 9 a P e e q d6 a ? a a a Q a a eq l q r - i q - - l+ ; f i r a 1 n q : €E E E E E E s € aa l 9 i i e n e etRd n: 9 a n : t i n .b od r € € 3E E E E E 8 E E E E E 3 3 8 E 8 A E 3 8 3 8 3 E 3 E 3 E E E E 3 3 3 3 3 8 8 E E E E E E E E E 3 E E 3 E 3E 3 E 3 3 8 3 E E 3 E 3 E E 8 E E E E E E 8 E E E E E E E 3 8 t 8 3 3 3 8 3 E 8 3 3 3 E 8 E E 3 3 3 3 3 d 6 d d d d h 6 h d 6 d 6 6 6 h h 6 6 6 6 6 6 h h 6 6 6 6 ; 6 6 h d d d ; 6 d d; d 6 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 55 5 5 5 E 5 E 5 3 5 5 E E E E E E 8 E E E E E E E E E E 5 E E E 5 8 8 E 8 E E B E 5 E 3 E 3 8 € 8 8 5 3 1Q q : : : i - n n q l t ! l n r n t n n n n n n l l n i l q ? ? 1 n a 9 9 i q r { q q ii ! 1 9 i q - i 9 9 1 9 ! 9 9 9 9 a n n 1 i q q q q e q q - n a l 9 9 c q q q q q - n 9! n 9 a ! n ? Q i n i 9 - q n q Q - t ? 9 t T - q l ! : e t 9 a q Q t q : i i 9 1 ! Q q a 9 9 9 9 n a r 9n ! ! 9 9 9 q r e q q 9 ? ? q * 9 9 9 9 9 9 9 e q q ! 1 n 1 t q : a a 9 9 t i 9 9 i { e n l - q 9 ! ! i ?? - q i - q e q q i i - - - - n - - i q ? 9 q - - n n n i q a n a a l l l n n l l l n l l n a l a 9 ! ! ,9 - r ?? : - a 9 i = o - 6 9 o r n 6 5 1 r 9. N a n ? N n f 9 n t ? 9 n : . n ? a : ? 9 a a 9 ? f I6 ns n t n n n n t l n n l f ; t t n : n * n n t n n n n t n a n n e n n 9 n r t t n n t t t t n n n n t n n nl t n n l l l n n n n t n i l l t t n t n i l n l t n l l l l n n n n n n l n n l l n n n n n l n n t n 47 of 2 0 l 8E8E E E 3 t1:Ea€!t:;] !Fs :E .? , .= 6: I :: F3 : = i r n f l 3 6 s 3 ; = ! 3 $ 8 e r r 3 3 ! ; : = = E ? f f s 3 5 E F i F ! s B i q i i + e i I ? i . € 1 e i 1 : f 3 : i i l : 3 : i : : Ba s s E a = = = i = R t r R = R ; : s F e ? + + s * i 6 6 n E a G ? c 3 3 F R r ' F F R - 3 = * * E i A B E $ = = : H E i E l i i ; a s s d ;. d 5 5 5 5 5 o 56 d d 6 6 6 d a d d d d d d d 6 d 6 6 6 6 5 5 d 6 == = = = = = = = - - * - - 38 8 3 3 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 S 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 E 3 3 3 8 3 8 8 3 8 8 8 8 3 3 3 3 3 3 8 8 8 E E 3 E 8 8 E 3 ;; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; - ; a a e a a a e a d , - * - - - - - € - d ed ; - l I i i - d - - - 6 ; - - 6 - - 88 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 8 8 3 8 8 t 3 3 3 8 3 3 8 E 3 3 3 E 8 3 8 8 8 8 E 8 8 8 8 3 3 3 8 3 8 8 8 3 3 E 8 8 8 8 3 ;; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; - ; ; ; d d d - - - d d d - - d - - & € d d d d d d d d € ; ; - * - d i - € , - - -i l h 6 d 6 - - i a a 6 n 6 6 33 -- - ; 3 A A 8 8 A B B 3 8 8 8 8 A 8 B B 3 3 A 3 *. a a a ?a e e e r p a q ? a c a. q ? r ! ? q q n e P * a ! ? e e ! 4. ?a q ae ! T ? * a e q RN N . . N 3 . ! R R R N N S R R R R R F F S R N R A F E R R A N F R R K & N S F R K F F F R R R K F R S K K R K E F R S S R R N F A K F N in q n f a r g e q r l e r € q - n n l g e t t q n q ? e - 1 n 1 1 : : : : : : 1 1 9 1 i 9 ! : i ! ! l l Q q q q ? ? ? ? ? : 1 e c Q 9 - : 9 eB B ; ; $ $ S C ! ! * A A 3 B S ; t r = * C g * C * * E * S S B g 3 3 3 E B 8 3 g t s B g G * 3 3 * * * * * ; 3 $ $ * * a g * * * * c s * ; g $ 9t q - i a ! 9 \ q 9 a ? q q q Q q n q q ! 9 9 9 1 ! n r n n n q q a i q ? q q e - - - n ? . i i F 6 a ;a 6 d d d d d d d 6 5 6 6 d d d 5 d d d d d d d d d 6 d d d d d d d d d d d d 5 6 6 6 5 6 5 6 5 a 6 5 a 5 5 n- ? - l n l A n n g t q - - q Q Q n 1 9 i q \ q q : ! < 9 n n q a 9 q l 1 ! q 9 9 e l M ! 9 a q n P q q n n n n l i q - i 9 q q - a n ;; ; ; r * * i l 3 f i ; 3 A 3 3 n n 3 3 3 3 3 a n a 3 3 3 3 E S E G S G 5 3 6 6 6 q q f r A A A E G 3 3 B G G 6 G 3 B q q q A S i G G q q q q q di l i l i l a d n a & a A A & d d d d d d d ;E = 5 ? E : F + G : R C * ! X S f f ! r 9 3 ! a i A : a * a l R + 8 e 3 3 8 : S ! 8 ! : Y 6 s ; 3 E e i i 9 i f l i E : f i i $ ? n ? E i 3 € E ** + + t + + = = + E E i i + e e a e ; ; ; ; d q q 8 n s f r f r n ; g n n n n s s f s s E E E f r s f r r s * s B 8 8 s i a = ; - s s s s s a a a i r: : ^: a -: J : l j: : - - : - ! : - l : J I C? 9 q ? q C q q q q r 9 9 A l a q n a l l i l n l - - : : 1 : C C a + o ? " ? ? ? 6 o 6 q € a r € -E E E i a a S = E = = 3 C 3 = = 3 3 = = 3 = = = : = E E 3 E C E E E e e E E E E = e e e a a e e e s e e e a $ a a a a a i s s e f , r r f B lq ! i g t q n n i a n i r n \ - r - n q { t * i 1 - i q Q : e l n 9 q a 1 : 9 i : : e a q n : 9 1 i ! l l e l a a 1 l - l q 1 ! 9 q ? q a *r : : ! = A a a 9 : ! ! ! 9 s s : ! : a = t E t ! ! ! = : : 5 3 = ! s s = a 3 3 = = r : : ! = 5 3 s = ! = : = t 5 = : E ! ! 3 3 3 ! i i f iE - - - 6 ; - n 6 i- e , 6 - - - - - - e- - 6 - 1n . a a 9 9 9 i i * q Q t i ? q r i q q e g e q P g i q q ! ! 1 ! l 1 a n n q 1 : 9 ! ! 9 1 1 - a . L i q q q 9 l q - r n a i q : 9 ! r t- - d d t d d d - 6 6 e e e o R * = * R X f * R X = * R R e R A e R R R R R 3 3 3 3 3 3 e 3 3 3 g B S S g : 3 ; ; ; ; ; ; - - E E g e e g UU U b U U O U O O g U G Q 6 e U U U U U U U U U U U U U U U 6 O O O G 6 6 6 o €q E q q E q a f f E i R R a Q s r € € € € s c G e G G q € q E E E S S T S n S E n n a S G G c S E E H E S g T E E E E E E R R R E H R E A I -F F F - d - d d d dd d n d - - ^ - d ;; i i i i i + i i i i i ; i i i i i i i i + 4 + C + c C q ? ? " e e e ? ? ? ? ? ? q q ? ? ? ? ? ? ? i i ? ? ? ? ? ? ? ? i ? i ? ? i ? i ? &6 j G 5 i d G r - d 6 6 5 - il d - 6 6 6- 6 - + n 6 - - 6 &- < + 6 6 6 6 b 6 6 6 6 6 @ o 9 U U U U U U U U U U U U U 6 o 6 6 G 6 o 9 € o ; ^ ^ ^ Jd d d . ; ^d d ; ; ; d {; ^ d ^ ^ dn ; ; a i ^ id d d d d ^ N ^ ^ {a d { ^ dd d ^ ^ d^ ^ d d d i d a d i d i ^ n n ^^ g E E g g g g g g g g g g g g B g g g g B E E g g g g g g B c g g g g g g g t{ i t t i i ! E I l ! i l l l ; E ; i E t i E E E € l E E i E -o o 3 i d i o o o d d d d a o 5 a - - i o o o o €i 3 ; a x 5 8 a s 8 3 3 S 3 A 3 3 3 3 3 3 8 5 5 3 3 5 5 8 5 t S 5 5 5 5 3 3 E = 3 E ? ; ; = : g ? ; = ; ; : = . : 9 4 ? : ; ; = : ! ! = = -d N N N 6- - - - 6 - - - - -6 - - - - 6 6 6 - - - - 6 - - ; q ; C 1 q d d. d . d 6 d q { a d d 6 d. d d d 5 d d. a a { a a d d d a a q a q q q a q ? ? ? l l q q n q q q q q q n q q q q q q q q q n q q iS d d d d d d d d d d d a a a d i i d d 5 a - a d 5 d d d d d d a a a a d i c 48 of 2 0 l 3E E 3 8 3 3 3 E 3 3 E 3 3 g 3 E E E 3 8 3 8 E E E E E E E E 3 E E 3 3 3 3 3 3 3 3 3 8 3 3 3 3 3 3 3 3 3 E E 3 3 3 3 E E 8 E t 3 E E E 8 3 E E 3 E 3E 8 E 8 E 3 E E 3 3 E 3 3 3 3 8 3 8 3 E 3 8 E E 3 E 3 E 3 3 E E E E E E E E E E E E C E E t E 3 3 3 8 3 3 E 3 3 3 3 3 3 E 3 3 t 3 E E E 3 E E E E .E p il , i t ,E!:;> *- e o - - & * - d 6 6 ; 6 6 h 6 d ; ; ; d ; 6 6 6 6 6 d d d 6 ; 6 h d 6 6 6 6 d o o - h 6 6 6 d c 6 6 d h 6 6 6 d 6 d 6 6 h d d 6 d d h 6 6 h 6 :: - - q q * i 9 ! 9 n ! l : q q e a i 9 9 t t ! ! ! 9 1 1 1 1 9 1 1 9 ! 9 ! 9 9 9 9 t * f qq - n r 9 9 i r q ? - t n n n 1 9 9 9 t e q c ? n n a ,+ l + l EI q- a ! 9 9 9 q n 9 € q q n 9 c l i ? n a 9 a t i q q - n ! * q 1 n n a 1 1 a a 1 9 e ? - q c - n i i 9 i 9 9 n - q ? : q n - - ? ? C a q q 9 9 9 9 !- q t - * 1 r r - n n e e q r 9 - 9 n 9 ! q t - t t - a n q l c t i e n l - ! P t q ! ? : ? 9 q * r - e q 9 9 t t 9 1 9 i a a 1 9 t t n 1 1 n n 1 -- - . -- - : - n 1i n n I l l l I I I n 1n n n n 1f n n I n n | 1 c n I l l n i i 1 t I I n n n n I t 1 l I n n t l t I I n n n I n n c I n 1n a 1a I n a a a s -- i - n a a i F - a a - F a - a F - - & - - - - 6 & & & a o€ 0 € € o o o oo € o o o @ o € G 6 G G 6 0 6 66 6 0 0 0 6 6 € o 6 6 6 6 G o 5 6 G € d n ^ n n d N d ^ ^ ^ N n d d d N ^ n d ^ d { d d N ^ d d ^ d ^ ^ N ^ N d d d d d ^ d d d d d d d d d d d d . . , . i l l q l l a l l 1 $ f g9 9 9 8 g s s s B s E s g g s s g s g g s g s s s s s s s B s g g s g g s s s s s s g s E E E s s E s E E s s s s s s s s B s B s g B s s s g B s \t i 9 9 9 9 1 q n - q 9 q r 9! 9 l e a q a a n n - n l n n : - ? 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P f qe ? e a e ; d F ' a d {, d € 6 j - -' € d i A - d F r o ^ r 6 d 6 i - ; c d d d ; r' F a 1! 9 i P n q Q - n a 1 t n 9 t ? q q ? - n a 1 ! 9 9 \ r q 9 - i n I 1 t 9 ?a ? q q q C l q q q - l q q q q q e e q q 9 9 q A e e q q ? e e e e q 1 1 33 3 3 3 3 3 3 8 3 3 3 3 E E E 8 E E r E 8 3 3 E E E E E E E E 3 3 E 3 3 E 3 qq n q q q l q q a l q q a n a a n l q n q q q q q q q q q q q q q q q q q -- ; - - - : - - - : : - ;: ; d ^ ^ n - N; r 6; d ; d e . o d r - N: - d6 d d d i -' + r !! l A a l a a a l l l l l n n l n t a a a n n r a t n a a n n t a n n n l z 2 2 2 2 2 2 2 2 2 2 22 2 2 22 2 2 2 2 22 2 2 2 2 2 2 22 2 2 2 2 22 2 ?t n n ? n r 9 Q t n ? ? t t t ? t r 9 ? n 9 9 ? l r n : n a 9 : t a 9 : n fr {i l i n i l n i { i l n n n n n i l n n i l n ^ n n { i l n { n n n n n i { n i d d a_a .a .z .: HO;' d ji _ : jd d n d -' ; -: e 1 + + , d ; ; ; 5 6 J 6 F F r F - - - d d d d d aq q q q q q q q q q q q q l q q q s 6 l q qq a q l q n n q n a q q l n a n q q n q q q q q q q q q q q q q q 88 8 8 8 3 8 8 8 8 S 8 8 8 3 8 8 8 8 8 8 8 3 S 8 8 8 3 3 8 3 8 3 8 ti t i t q i t t t t i i t t t i t t i t i i i l t i t l i i t i i F EB € € 3 3 3 € € 3 83 3 € 3 8€ € 3 8 8 3 3 S € € € 3 3 3 € 8 8 ei l ; - - ;j ^ , d ' d n d d - + ^ - ;i n d a 6 a d n n d 6 d a i d d i n d d d F - i d n d d d i d n 99 t q q q q - n a a 9 9 9 i ? q q q i q a ! 9 9 9 l q q q - - n .n a 9 : n : t : l a 9 : n a ! : i a ? : n : 9 : t a ? : q f :: t nn n n a n i a a a a a a a n a : a t a a : : a a : : : a a : : n : -i d d d 60 of 2 0 l .! a iJ 33 3 0 C 5 0 E: ? 6 - - 4 - q t 1 a ^ - - ?9 ? ? o ? q :a 9 - i a q t 1 - q 9 1 1 q t 9 a q q 9 1 2 2 2 2 2 2 2 2 2 Z 2 2 2 Z 2 2 2 2 2 2 2 2 2 a^ e ; d r, 6 6 ; ; ; o ; r i l r i l d sE 8 e i S ; F + 3 i 9 s t 88 3 3 3 t 3 3 3 8 t t E 8 8 3 3 3 E E 3 E E t. 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E .Z .! - !(, ;: -: ;; r hh € ; € € F F r i *d d i 4 a i a . d i 3 o : : : r N d i a - ; ; - + * + a ; ; - d o o ij . i j i i n i; & ; ; t d t; 5 5 i d n { a a n a n a a d N n N n N n d d d a e a n a d d d n e a d n d n n d q n n i n d d i i i n i l i n n n i n n n n n ^ n g 66 of 2 0 l I e ! ;; nq n n a a a a a a a a n a n a a a n n a n a a q a q a a a a a a a a n n a a n a a a a a a n n n a a n a a a a a n a r a a a a a 33 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 5 3 3 3 3 3 3 S 8 t 3 3 3 E t 8 8 8 3 8 E t 8 3 8 5 3 3 3 8 8 3 5 8 3 8 8 3 5 8 3 8 dd d d N i l i l i l d n d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d d { d d d d d d { d i d d d d T9 Q 1 9 I q 88 8 8 8 8 8 te e 8 8 t 8 8 e e e e 8 e 8 e 8 8 a 8 8 8 8 8 8 e 8 8 8 e 8 e t 8 e e e 8 e 8 8 8 8 8 8 e 8 8 8 8 8 e 8 t 8 e 8 8 3p 5 3 ; F E F f i FS 5 s F 3 K s F 5 A i l R 3 R i l ; 3 3 n 8 s s 3 ; 8 ; 3 ; E i s $ E q q E 3 i f r {g n E a a E q s i E € E : 3 E oo o o o o o o o o o o € o o o o o o o o o € o 0 0 0 0 0 0 0 0 c € o 0 0 € € o oo o o 9 0 € o o o a o € € o o o o o o o c o € o -3 3 3 E 3 E a E t E 3 E t 3 E 3 t E 3 E e E E E S E E 3 3 E E 3 t 3 3 3 3 3 = E 3 3 t 3 3 e E 3 3 t 8 E 3 t e E C E E E E 3 E e i! 9 9 9 i i 9 9 1 a 9 q i t i i 9 i t t i 9 9 t t \ 9 c 9 i e 9 9 9 t 9 t i i t t f tt i i i 9 \ ? a t < l i i r ? t i t q i q 88 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 it i t i i i l i i i r t i i t t i t i i i t t \ t \ ! t P i t t i i i i i i i ? t a { q r { " c q 9 e { ! e { - ! e e q * { T r aYu :E .? , .z .: Ho'EZ2a nn t l n n n n n n n n = l l a n a a n n a n t : 1 1 a 1 a 1 a 1 a i : 1 1 1 a 1 1 n t a ! 9 ! n 9 9 q 9 9 9 t 9 9 9 9 6 9 9 9 9 + d- d : ; 6 d a d d r € r 6 j- r d d d n d d F d d d + 6 - 6 j; ; 5 6 d d ; h r 6 i d r 6 d 6 i ; d t - d ! + h d d j; r d d r+ r - n r 6; b € b n i n n & & ; & d d d d d 5 5 d : r j j i i d { ; ; d ; + i { i n n d 6 bi ; 6 r r r r & & d - 6 9n 9 9 9 t 9 ! 9 9 t I n 9 9 9 9 9 9 n 9 9 t 9 9 9 9 9 ? ? ? ? ? ? 9 9 9 ? ? 9 ? 9 9 ? ? 9 9 ? 9 9 9 ? 9 9 q ? 9 q ? ? 9 ? 9 ? ? ;d;: :I cq q q q q l di d d i d d it i t i i i dd d d d d d 3E 3 8 8 3 3 it i t J j j 1- Q i r q i an n n n i a rj d 6 6 - d 9i q e q e : 67 of 2 0 1 5E € € E E € E E E E E I € tq i 9 i e e q q { q e q t 88 8 8 8 8 8 8 8 8 8 8 8 8 dd d d d d d d d d d d d d E€ € E € q € E q € € € q AE I E E E E E E E T S E E :) J ) J J J j j j j j j j dd d d d d d d d d d d d -: - - - a a a - i a - : id d d d d d d d d d d d d 6d d d d d d d d d d d d d di i s : i ! ! = i : e i xx x ; x x x x x x x ; x 6d d 6 d . d 6 d 6 6 J G jJ ; d F 6 o d { G d d - d dd d 6 5 5 5 : : : r a i i q9 Q - - i - a i a i i i : s E< 3Et{EE6 d b: !(, AE. r !. c ,z.! I 68 of 2 0 l E E3 rr r ? : e = 3 e 3 ! ! 3 3 r a ! F = 3 R G 5 ; s 8 E ? e l l E ; E ? + i : q s 5 i l F i s ; 8 3 5 : = * * 3 ; i i q { i E + i : F q i e i :: : ; : I = i : i i e i s : x r B p : : l s ; t t i r i e a ; . i a a ; G € G B F s i s r a ; E s E a ; e x s r E i i E E S = : : : = E I I 3: r 3 8 8 3 3 3 8 3 8 3 3 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 3 3 3 : 8 8 8 8 3 8 3 8 8 3 8 3 8 8 3 3 8 3 E 8 8 8 8 8 8 ;; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; € - - - d d r d d € - - - - - - - i r d - d - - - ed 4 a d d d * d 66 e o 6 6- ; - a E E ( F E i F. i F. F . q q E - F. 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T - n n q 9 l 9 n n i - 1 9 i 9 t 9 P i 9 ! a 1 l - - i - - q t r 55 d d 5 ;; 6 i 6 5 8 E 8 6 5 I 5 E 5 5 6 € o o aUOE. r _a3. 2 .: cQ I: i ' o : 5 : d + 6o r F F 6. 6 6 * - - 6 - - - 6 6 € a 6 6 d a t '- ] = 6 ^ d ? i - i a + 9 ! 9 l 9 6 n l h h 6 h 6 6 6 6 . . a 6 6 a 6 6 6 6 6 6 6 . . . . a 6 6 G o h n h l 9 o , dd d d d N d d N d ss s s s s s s s s s g s B B s s s s s E s s g g B g s B E s s E g s s s B s s B s g g g g g g 9 g g g B 9 9 g g B E g B g E E E g g g E cc i i i . 5 5 o 5 5 d i 6 a d d a a a a o a o o 33 = = f r g 3 K E 9 A E 8 G € € S S S E E A S S F S F F F F F F T S S R S F R F F F F T F F P F T F F F B F F S F F F F F F F P F T T S F =5 5 - : = F N i l d - - - - - n - a - - - - h & - A - n i l d - - d d N fS 5 s c o j i ; . ; c ; J J a J J j i a a J c . . c i i o o o i 3 3 3 c i - i d s d o c d i d J d d o o - o c d i d d o d d d d d o o : c a ,EEsE !i 69 of 2 0 l ii i € a { q i 3 I 5 A q q E N 5 s F q € q ! q & ; E i E i 5 3 S q E 3 € s r c ? n i g E 3 3 s 3 e = I = 3 q E = f *. 3 n 3 6F 5 : ; ; F d j d r 6 d o - i+ o d o -d ' 6 r , a- - - - d - ^ ; ; - a 66 o 3 € Fn t s - - - - - 6 - r 6 i a o - d 5 o : Nd d a n i ; d - 6 dR d d A N N d d d A * n d A & a d d d i l n 9= = : = : i . 3 - 3 _ 3 _ 8 . 3 9 . 3 ? ? I q q 3 E E E 3 E E 3 3 E 8 t t t 3 E 3 3 E 3 3 t e 3 r 3 E E 3 t 3 e 3 3 3 3 E a E E s 3 s -a - - n d t - d - - - - i d d d d d d d d - d d d d d d t d d 66 - - - 6- ; - - - - d d 6 ; ; !r , :nE:: !d 3 3 3 3 3 33 3 5 = E :3 3 3= 3 = 3 3 3 3 3 3 = 3 = = 3 = 3 3 3 3 = = = 3 3 = 3 3 3 : = 33 =- 33 3 t3 = = 3 = 3 3 3 = 3 e6 6 - d - a - o 6 66 6 6 d - - PP p S P P S F P P p F F S F e F P P P P F F € F p p e B s s p F s B p p p F F B F s s s p F p p p e i F F s F B F i F l F q q q q e q c c q q I a a c q- - - - 3 0 0 c I q " cq c q ? q q l qq q q q " r e q q t i i i t 9 9 I -e ; e r F e - e 4 e d 6 e . ; ;d _ _ _ - -d - - - 6 -- d - a - - -d - €o - € - - a - - Ud - - - - - - -U d U U U; i ; xi * i i i { i i i x i i i E x . i E e n : x h i i ; E i E i ; ; 6 i ; i ; ; E i i i n a ; i ' l $ i l i * i i E i a * E ! * i :9 1q 1 9 9 i q Q q ? ? i c q - q Q ? t l a l n n l l a a ! 9 1 9 i 6 q e ? 9 ;s 3 g € H g € e 3 g g s € € 3 € € € € € € € € € € € € E € 3 € € € € € € € !a ! a U5 5 5 U E E E t s E t s . ' € TT F N F F F F F F - - t s F F t s F F F - F F F F F F F F t s t s t s t s t s F F F F F F F F F E 6 h 6 6 s 6 d 6 6 6 6 6 d 6 h h 5 6 6 6 6 6 ; dd d d N d n d N d d d d d d N d d a d d d d d i l i l d n n n i l n a - A a n l € 3 s8 9€ I s s s I I s s s s s s B g8 3 * s s s s € BB * s I s I s s I gs s ** * s s p s s ts g i s s * x x * g s t i 33 3 s s F s E S S E 3 3 3 3 3 3 3 F i 3 i : i i 3 3 8 3 : 8 3 s 3 3 E 3 3 s E E 3 3 3 E s F B E B s s s B B i E B E F E s d - 4 - n- * - d d 6 d- d d d d d d € dd n a a € - d -d - - id - - - * n d @ - - d d d d @ da d - OA Yu !E .8 .= a: .: HU F- - F - - 6 & - @ & & - - - - - n - - t s 6 6 * - ; _ € ; d & b a _ _ _ & d d _ b 5 - & - - n ? i? ? ? ? ? ? ? ? ? i ? ? ? ? ? ? ? e ? ? ? c 9 ? ? 9 ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? t + c i i c a + i i s - f ; ; ; ; * E I 8 * I 5 E 3 s8 s r r :* * A E EH f A HE €3 3 = e € : =: 3 8 € = g3 ; € Ea € : :. : e : B :: : = ;C 3 :: G = n n i d nd N dn d d dN N ^ dd d ^ d dd d ^ ^ n^ ^d d ^ d^ A d n ^{ d i i i ; d d d ^^ ^ ; ; ; : ; : ; : Ei E E E ! : s : , 9 B i d ! a : a : i : a ! a i a : a ! a E E g ! d i i ! i ! i ! i ! i ! d : d g g g i i E E E E E g s g ! i ! , 5 ! i g : d : g g g g E g g g g g g B B c g Ft s i n F n F t s F F F t s t s F F F F F t i F F F F r F F F i l t s r r t s F F F F OO L d A d [ & A T A A T T A A A & d d d E E E E E d E E E E E E E E E E E E E E E E E E E E E , d d d E E E E E E E e E E E 6o A- 6 o n a 6 . d + r i = { + 6 : ^ + 6 - - i 6 - n +6 - t + h - d =+ + + 6 6 ; 6 o 6 6 J r F F r ; e ; ; ; ; 6 5 ; o ;5 r r r i n i l d I ; ; ; ; ++ ; ; - ; ; ; ; ; ;d d F F * a - a ; ; . n r n n n r n n I n I n n n n I n n a n I | * i - - - - n I n n a r - i e i i i i n n n i - -; - 6 6 6 - s -. a -- i : : : : l i t t i t : : j j n: n P 9 n n l q q E3 E E E 8 3 E 3 3 d6 6 6 d d d d d 11 1 9 ! 9 9 t t t :l n a l I n t f l I 9r 9 ! I C - i i ? nn - ; d - d t d ; F YY Y I Y Y Y Y Y Y 99 ! ! ! 9 n 9 1 ! 88 8 8 8 S 3 8 8 8 8 dd d d d i t - d &A A A & C E A A A 70 of 20 1 tE 8 E E t t E 8 E 3 g 8 E t E E E E 3 E 3 3 3 E 3 3 3 3 3 3 3 8 3 3 8 3 8 3 3 E E 3 3 3 E E E E E E t E E 3 E as a s s c t c a o li i t i i i t l t i t i i i i i i i l t i i t t i t i t t i i \ t ii i \ i i i t t t i i i \ t i i i t f i i t q q q q ! q q ? q ai i i i i i i i t i 9 I I 9 I I i i i t t t i t i i q i i i i i i i 9 \ i i 9 9 9 9 I 9 9 9 Ii i i t t i t 9 9 l t n ! 9 9 9 9 9 ! n n n t n a t n t : ? q i 9 9 9 n l n c c q q q q P q € i 9 9 1 ! a 1 1 ee { e \ i t t t i i \ r t t i 9 9 9 9 9 9 9 9 9 9 9 1 n 9 ! ! ! 9 9 ?? ? ? ? ? i " ? ? t ? ? ? ? ? ? ? ? ? ? c ? ? ? ? q ? ? c ? ? ? ? ? a a ? ? ? ? ? 9 9 q ? l ? c a ? e c ? ? ? I !- n ' x3 iee= }E f: qq q q e { Q c a e l r e a r q q r t i i i i i t i t c ? e c q n q q q q ? q q q q a q n q q q q c € i i i i \ 99 9 ! 9 ! 9 ! 1 1 1 1 1 1 1 n l n l r n f n ? a i ? - 1 n i 1 ! q Q q q n 9 a i { n ! : 9 q 9 4 - - - ! n q q i ! ! 1 q ? l t i i q q 9 n n ? 9 a I ? a ll n n n n q n n n r q n n n n n q n n n n n n n n n l l t l l n n n t n n l t t l t n t n l t l l l l n c t l Ps E e * e E r e e e * * * e e 3 8 8 8 8 8 8 8 t 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 t 8 8 8 8 8 8 8 8 8 8 t 8 8 8 8 2 2 Z2 2 22 2 2 2 2 2 2 2 2 22 2 2 2 2 2 2Z Z 2 2 2 2 2 2 2 2 2 2 2 22 2 2 2 2 2 2 2 2 2 22 2 2 2 2 2 2 2 AA A A A A d T T q A A d A A T I T A A A A A A A A & { A A A A A & A T A A A A A A A A 4 A A A A A A A & A A A 9S a 9 ? n n ! Q t a 9 9 C n I a n a n ? s n 9 ? i a 9 : n a 9 : n a n : $ i 9 : t a t : t a r : n a 9 : n ? 9 :: I J I t : ! ! ! i I J : J i -: : - -: - - - - - : -: :: : i : : -: -: - a -: - - Yu !E8. 9 Q et q Q c n l a 9 9 q e ? n 9 ! a 9 € q 9 - l n a - t ! t i 9 q a 1 - - n n ! 9 ! q n q i q p Q - n n 1 i : n - oo o o € o o o o o l- - - : l f l n - : - - i n 1 : - n l n n l i i i t n n l n t n t n n n n i n i n n q l n n n n n l n t n l t n- q r 9 9 a n - n 1 9 9 a r : 33 3 3 8 3 3 8 3 3 3 t 3 3 8 E 11 1 a t n n t n 1 - : - 9 ? ? 9l l a a a n a n n - : - q 9 a td 5 d a d d d d d 5 d 5 d 5 d 6j 6 6 d F d d + d + d : i d 6 nc n n n q n n n c n t l l n t c? q 9 - 1 : ! 9 1 a a ! 9 i T r !9 9 9 p 9 9 9 9 r 9 9 9 9 9 r 5 oo o @ a a a o o € a € YY Y Y Y Y Y Y Y Y Y Y I I T Y 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 nl t l i n l n l l t l n n n CO E E A O T A E O A q A A & 7l of 2 0 1 ,a h _ F -d + o - +j d h F - o d , 6 d i - d 6 F a j d , d - d d + 63 O O O O O - i - E8 8 3 e 8 8 E t t e 3 8 8 3 3 8 3 3 E 8 C 3 8 a E E E E 8 E A 3 E E E 8 E E E t 3 3 E E E E E 8 8 3= EIE) it i t t i i i t i i \ i i t i i i i i l i t i t i t i i t i i t i i i i i t i i i i i \ \ i i i r i9 \ 9 9 9 9 9 9 i i 9 t i i i t q C C C { q q q q q a C q ? ? a ? C - - : q 1 1 - a i t n n f tq e! n q a a 9 n i 9 q a e 9 r 9 l q q c ! i q 9 q i q e q 9 ! n ! n 1 n l 9 q ? a r a q a 9 l c 9 q 9F - - O - r € r C 3 !E. i .a .i O ?i ? ? ? i ? ? ? i i i ? ? i ; i i i i i ? i i i i ; ? i i i i ? ? i ? i ? i ? i ? ? ? ? i ? i i i o_ N r o oo o € o € o o 6 0 't 1 ". ) . j 1 I a q t I a I a a a ., { ". } a ? a a .t . t . } 1 t I .t t. : 1 ? a. t I I I a 1 q q a a 1 f a a I II I : I I i I I i ! i i I I F ^ 5 ^ E ^ E ^ s I q I q q ^ 5 I ^ E I E p I q q I ^ 8 ^ E ^ 3 ^ E i ^ E I ^ B ^ E - E - E : E ! - 5 q9 9 9 9 ! ! 9 9 i { q i t 9 9 t - q q Q ? : Q q a l l 9 9 9 t P i i e I q e t e e e q q * l i { q e nt l n n n l t l t t q q t t n l n q n t n l n n l n q n n l n l l l n n n n n l l l l n n l l t l -? n q t 9 l l t q q n * i 9 i i q t t i P ? q ? \ c i q q 9 ! 65 6 6 5 5 6 . ; 6 5 5 e E ; ; Z E ; 6 ; 5 9n n n ? n n : ? n n ! ? t n I ? a n I ? n ? 9 9 n a t : t a 9 : t i t : n t n : n a n : * : n : n a9 9 n q : q { i 9 1 q - q I t 9 1 a - q q 3E 3 3 3 3 E 3 E E E E E t 3 E 8 3 3 3 E A i\ r i i i i i i i i i i r i i i i i r i i 99 9 9 e 9 9 9 ! 9 ! ! 9 9 9 9 9 9 9 9 9 r F ii t i i t i t i i i t t i i c € q q a e q an a a l a a l a a n n a ! n : a a : a : a q9 9 A 9 C e q l q ! q ?\ a ! 9 9 9 9 a C C q q q a a € i 9 9 ! r nn t t n t i l l n n n n l l i n n n q n n i t i i t i i I i E i I i i i E E -€ E ^E i -E 72 of 20 1 oo € o o o o a G EE E E 8 E E t 8 E 3 T 3 3 3 3 3 3 8 E 3 t 3 3 E 3 E E E E 3 E 3 E 8 E E E E E 3 E 3 8 -- r d d @€ - - r d - i - - & - - n - d n d n d €€ € i - d d d n ii t i i t \ t i i t i i i i i i t i i l i i i i i i i t i i \ i f \i t t i i t i i i -: : - - - - n n l l n l t a n n i n n - a a t n I l a l a ! a 9 1 1 1 1 a 1 n 1 a n n !,; 9 9 1 ! 9 9 9 t i i a q q q a ? Q q q e l. . ] c q - -- - - - ? q q q q - I a 1 n I I I nq 9 a ? 9 9 4 < \ a 9 q ! q ! 1 l q a r 1 a q - 1 P 9 9 q n - n a i 1 q l 9 ! 9 n n 9 :q q - i - n l a a l 1 a I q a 9 ! h n 9 ! 9 9 9 9 9 9 i \ i i i i 9 9 9 9 i a a n n n 66 € d d 6 6 6 o € o o @ € € € 6 € d !UAYu !E .? , .z I 99 1 n 1 1 9 1 ! a n n - l P t I t ? Q i 9 t q r ? t n q q a 9 9 a - Q q 9 a a n n l a ra a ! ! = a 1 = f ! = f a a a l i - i 33 3 € G B 8 € € € 8 € 3 € e e e e € 3 3 3 3 3 3 8 3 3 3 3 e 3 8 3 3 € 3 e e € 3 e G 8 nn n l l - - n n l i n - n n i i q n n n s q t l n l n l t n i l l l i i n i q n n n l o€ o € o o € € € o o € € € o a G 6 6 d i l d d n d ^ i d d N ^ N d ^ ^ d d n d ^ N d i ^ d d ^ ^ N d d d d €E 5 8 E 5 8 5 E E E E E 5 E 3 8 E € 5 € 5 5 € € 5 8 r E 8 5 5 3 8 8 8 8 8 8 8 5 8 8 5 + + + +; dn n G q o o ri l r ; i J ; ; d A; ; i -- i N nd ; ; n ' n , ; ; + nl n n n n l n n n l l n n n e n n f l na a n t ! a n r a 9 a a a a n a a n n e i t i a 6r d o i N+ G d 5 - - ; 6 3E 3 3 8 = 8 3 3 3 3 E 3 3 3 3 3 3 E e 3 8 8 8 8 8 3 3 n- € r & €d d d - d * - i\ i i i i t i t \ \ \ t i t t i i i i i t i i i \ t i nn n n 1 1 1 1 1 a 1 1 1 1 1 1 1 A a 1 1 a a n n n 1 - 11 1 1 1 1 1 4 1 1 ! n t l n ? ii ! a a a - e 9 t n q q 9 9 9 ? Q 9 ! t ! - ! q : - ? td d d d dd d - d d d * - - i d € - i d d d d d ^ d d d d d d d ^ N N d d a N N N 83 8 8 8 8 t 8 S 8 8 8 8 8 8 8 8 8 8 8 8 3 t 8 8 S 8 8 Si o d d dd o o 3 i i d o d FF F F F t s t s d nr n n n n l t n r n n r r i n n q t n n n t t t n i n ll l l l n l l n n i r n a q a a n q n a n a n q i n n tn : n a t i 3 a 9 : i a 9 : n a 9 : i a 9 : n r 9 : a aa a : : : - : : : : - : a n n t t l n n t n f l ti n n 73 of 2 0 l c3 n: q e l 9 1 a - ? e t ! l n i q a 9 t n t Q q n 9 9 r r Q q t 9 a q : 9 q FF r r - - - 6 8E E t 8 I 8 3 3 3 3 t E E E 3 E 3 3 3 3 E E E 3 3 E E E E E E 3 E E E E 3 d -, - dd - - a € - id d - - e -€ dd - - - dd d - b nq n n t i n q n q n n n n q i n c n n t t n n n n n t l l t n n n t t t n aL) A !E .8 .e - E:U:EI tt t t t i t i t 9 9 9 i i i i q ? q n c a i i i i t i t i i i i i ? r r q q 88 8 8 8 8 4 8 8 8 e 6O 6 6 d O 6 d d 6 O 6 O O G O . o o o o o o o 11 1 1 4 a 1 4 : n ! n l 9 4q 9 9 1 1 ! ! 9 n 9 9 9 t q n t - 1 a n - q i { q q q q i 9 9 i i e e \ 9 == = = = = = = = = = = = = = = = - = = = : ? Q ? = = Q ? ? ? e ? ? a ? ?a 6 d 6 6 ; d d d ; d ; h; ; 6 ; d h 6; 6 6 6 d d d. ; qn q q q c n q c { { * e * q c q q q q q q q { q ? q r r I r ? e e f f r 9 : : : : : : : : : "E : 5 : : E : : : : "E 5 : : : "€ : "E : : : : : : "3 : 5 : : nn l n l n n f n n n n t n q n n n n i l l n i n q n n l l n n n n l f nn ?? ? 9 ? 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E 8. 9 (. ) n! 9 ! 1 n 1 1 t I ? 4 1 : ? q l q i i r r q 16 4 ; a _ 1 ^ I n ! l q ? - - ^ l l n n n d 1d 6 d r f ! 9 9 L 5 t t ! = a a a * 4 4 2 2 88 8 8 8 8 8 8 8 8 8 8 8 8 8 55 5 E 5 E E E Gt&d oj e ; € d i n + 6 ja j. : 6 d 6 j n + dd 5 d + d r a i ; d d d d ^ + 6 d a 33 E t 8 8 8 E E 8 8 3 3 t 8 8 3 3 3 8 3 8 3 8 3 3 8 E 3 e 3 3 3 3 4 8 3 8 e dd d d * - - d d d d nn 4 * - - * r - - - - d d d - d d d i - @ d - d d d * ii t i t i t t i i t i i i i i i i i i i i i \ i \ i i i t i i i t t i i i t Pa q q c q c q i - - - - - i - i i n l n q q a n q q n a a a a a q n q l l l 1n ? q : - - - - n n l n n n n n n i a n n t : - q q 9 q q r q i i i i 9 9 9 9 1! 9 l a a r r t t l l - ? -- d d d i - - - - - i - d - d d d d - t d - d d d d d d d d d d d - { d t d * 99 r 9 9 9 9 9 9 9 \ i i e e q l e { q q q q q ? ? ? - : - r r n r i r r l n 9q i a : ? - n c 9 q 1 . 9 i q i \ 9 a a a q a i 9 a i t 9 9 9 i - n a n 9 1 9 9! a a 1 . r : n 9 i l n a l q t t q - n n n 9 i i 9 I q : : n 1 n i 9 r e ? - ?? ? ? ? ? 9 ? ? 9 ? ? ? ? ? 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E E { E C l i ! 9 8 8 r E 8 5 8 8 E 8 E E E E 5 E 8 s 8 r 8 E S 8 8 8 8 5 8 5 8 8 8 E E E 8 8 E 8 S E S 5 F6 F F F F F F F F F d F F F N F F F F F F F F F F F F F F F !l i t ! ! ! ! ! 1 ! ! ! ! q e n l t l n n l i n n l n n n n n i l n l t t n n n n t n n q n q n n t n n t n n n l l n d n n nn n E 3 I 9 9 r r n 9 n 9 3 a n n ! 9 n t 9 9 n 9 9 9 t n ? ? n a n . t a 9 a n * : : a 1 a : a a a i i : 9 - n dd - 6 6 76 of 2 0 l ;; E3 e 3 8 t 3 t 8 td . d ; d t d @ It t i i i t t i n- Q e q ? e t 9 nn - q q e i 9 ! -- 6 - - ; - n - <! : - : q q n 9 ln t t l i n l a -? 9 9 ? e A q € l= = = = = = : : nn n t n l l a n OA i. r .? .z EE !L)qI*q r 8- a '€!9=: -l l - - i n - i ?9 ? ? ? ? C C ? dd d d d d d d d 11 n : n n n n l oo o o o tE 3 E 3 E 3 3 3 3 E E 3 3 3 3 3 E 3 3 3 E E 3 E E E E 3 3 I t E E E 3 E 8 E 3 3 3 E E € d a - - - - € d d - - - d d - - d 6 6 - d d € i 6 d a . & 6 @ - - - i - a @ 1n - q e 9 ! r n 9 q t 9 1 ! : q P q tE E E E E E E E S E E E E E s E E 8 .d d d d - * - - d d d - - i - @ d d it t i i i t i t i i i t i t i t t i t t F i i t \ t i \ \ t i i t i i i t \ ! i i i i i t t i i t i i i i i i i i i i i t -- : ? q ? q 9 c ? q ? c ? a : - : - n n l i - n n : - - 9 - ? ? ? ? q q q c q q q q q e P e e e P q i i t 9 9 9 ! 1 1 n n qq e i i i i i t c c ? q n q q q q q q r r i i i i 9 9 9 9 9 9 9 ! ! ! ! ! ! a 1 n n a 1 f :- ? ? Q a q q q c q q q i i 9 qa q q - : q c 9 - q ? ? q 9 9 1 a q : a n 9 9 9 a a 1 1 9 i l 9 r 9 - 9 q l q ? 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" 9 9 9 ? a e 9 t e ? e ? ? a 9 9 a C ? ? e ? ? ? a ? ? ? ? 9 9 e ? ? a ? ? ? i - : : : : . : i i !(J O Ym !E .? .9 _ !(J ,e:!]e,: E 78 of 2 0 1 -6 6 A 6 r N C 5 F A + d - a - O h d - '- - O - an r n r - + i + 3- 8 E 8 E E E E E E E E E 3 E E E I E 8 E E 3 E E 3 8 E 8 E t 3 3 3 3 3 E E 3 3 E E E E 3 E 8 3 E t E E E E A E 8 E 3 I E 8 E E 3 E E 3 3 E 3 3 E - dd d d d - d - - d d d d - d d - d - - - d -d - -d $ - dd € dd 6 d d d - - - 6 d 6 d- n € - - @ € @ @ e - @d ii i i i i r i i \ i i i i t i i i \ \ \ \ i t t i \ t i i i \ t t l i t t i t i i i i i i i i i \ t i i i i i i i i t i i i i t t t i i i t \ i t i1 - a : - - : - - - - - i r i n i a a a n a n q n n q : n - - e ? q e ? a q ? a e a c a q t c q e q Q 9 ? - - - : - n l l l r a a a a l 9 ! 9 9 9 f:Ez;e ee q q q 9 - : r n n n r r n n n n n n n n n n 1 a 1 1 a 1 1 9 9 9 6 9 9 9 9 9 9 9 9 9 9 9 9 i i l i q i e * q q q c q ? ? q q ? - - - - -- - @ - 6 - - - & - - - - nq 9 n a n q 9 - - q ? 1 n 9 q 9 ! a { 9 r 9 a - a q i q € - q ! - n n q q e r l - ! q 9 q 1 - 9 f ie - q : q ? ? 9 a 1 a i n P t * q l n ! t q a r- o F - od c F r *c - - € 2 l- - a 1 | l l | - : - - n : n n q q - - - n n - n : n l n n - - . - - - _ - - - . 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(J e E a 3 q p E x q F s E q r 5 E q r E i il R 3 & ; s 5 e q E 5 - 3 - 5 - 3 a ^E i ! i 5 n E 4 E I r 4 q { q * 85 of 2 0 l Nd d d d d a - & N d d d d d -- - - - a e e 6 - a= 8 9 8 8 8 ; * g $ 8 8 8 ; g S A S e ; 8 ; e S S S t e a e A e e e S t A a a 3 E q l E E a -- A & & & & - - € - - - - € 6 - - - - - & - - - - - - - & € A t P - * { { e q ? e e e e e P 5 i 5 5 3 o = c. i 3 = i. i o o i 3 . d d 3 i 3 o dd a 5a o o o o o. ss s s E s s s s g 8 E s s 3 s 3 3 8 8 8 8 3 3 S 3 B 8 3 3 3 3 3 3 3 33 3 € € € E 5 8 3 € € 5 G E 3 3 3 3 € 8 5 8 S 3 3 3 33 € € E E ;; € ; o o ; 6 d d 6 o @ oo o 6 6 o € € 6 c c o o € 6 d d G d d D 9e ? q q * - =X 1 - X A E 88 8 8 3 S 3 5 5 3 8 t 8 8 8 8 5 3 3 3 3 8 3 3 3 3 t 8 54 5 5 4 5 5 -r r F r r r r F F F F r r r F r r r P r F F F r r r r P r r r tt i i l F i F i t t && A A l a A ^ - A A A A d d 38 3 8 8 8 3 3 3 8 3 3 3 E E = E E E 3 3 3 3 E 3 8 8 3 3 E e E 3 3 8 8 E E 3 E E E 8 E E 3 ? a5 $ i l G R F 3 e 3 = = F : r ; a S F s e a s e I q ? i 3 c e 3 s E € ! i a i q q c E r € 4 s ^F - F - - - d d N ;F i j A di 3 & 6 F a; q i - 5 ; 3 ; : ;A ; ? :, : ? C" : 9 - o @d d d 6 d d = 9 9 = = = = = 1 66 6 6 6 6 o 6 6 € 6 6 6 € 56 b b 6 J J A r b G S d b O b b G O a e O o € o o o a o o 88 8 nr c - r € € id - - - - - - - i - - - - - d * - * - - - t - - - € e 6 - dd d d 6 6 o d d 6 FF F F F F F F r r r F F F T T ti i i i i 99 q q 9 9 9 b 9 9 9 9 9 9 9 9 9 9 9 s 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 il d d d d d N d d d s3 € € 3 S q i * i n : a 6 i i a E q n B S € F q q x 3 E 3 5 ! ; i t F q S E q q : : E F E S -i i r d 6 ; d - d d r t O h + - ; ; d t ; a j d d ; 6 6 d d d -- - - - _d a _ 6 _ r o ? 1 _ _ q a 9 _ T ;J ; J n * * t i 4 4 6 A d & - - * - d 6 - 6 d d - - - - n 4 - - - d d d 6 6 6 FF F F F - 6 - - - A - A - - - - - - - - - A - d o- d U ; 4 6 ; 3 6 ; i r a - F + - F + : F + - - -6 d 6 6 ^A d , 6 n - - r + + n + r r h -- - - + r+ + + + + + + r t + . t + + + i + + + +t r r + oo € € € o o a € oo G € F o € O O O =. i 5 5 i i o - . . . 3 i 3 c a 3 o ce € f ? r e e e { + * e a ? e f rP r e e q r 33 3 3 3 3 €6 € 9 e 9 9 9 9 9 9 9 t t i i t i i 9 ii i t i t t t i i l t t i t i i i \ \ i t i t 33 3 3 3 3 E 3 8 8 8 3 3 8 3 3 8 8 8 8 E 3 3 8 d6 6 h 6 ; ; 6 ; d d h h 6 6 6 6 6 6 - d 6 6 h ob c € o dd N N d d d d N d d d d d d a n s a o r r a i de - 6 6 -- n ; + + + + + + r + { + a- d = c - 5 - d - 6 6 i : e 6 6 d d jd ; d- or r * t ?! 9 q - a 9 q - a 9 a - n 9 1 : n 9 q - n 9 q *+ + 6 n ; 6 ; ; S U r r n i & . - € 6 4 ; ; d aa a n n n i l n i l n d N & N d N & ^ N ^ ^ ^ n n 83 3 3 3 3 3 : 3 t 8 8 8 3 3 3 t 3 = ir d ir3. e ?! .: Q (J 6O 6 _ 9 _ O_ a_ O_ a d F d t d r l C a ." - a a ? - - ? 9 : a : 9 : : + o | i | ? n . 9 9 | n n o d . 9 9 | r l ? 1 n d; : i i n A d d - -t n t t - n n n l n t r t n a a n n r n n n n r r n ! r a l n n n n n 9 a a a : a : a n a a ad d d d .;Ie' - !:;] 86 of 2 0 l !! ! n 9 1 1 1 1 a l l 1 1 1 n 1 1 a n a i a r i 1 n n n l l r n n n a l n a n 5i i 5 i d i i i d i S S d 5i S S o o o o d i d o o o o S o 66 6 6 6 c 6 6 6 6 6 G 6 € 6 e 99 ! ! 9 E i l t t I P q q q Q r * Q = = Q i ? ? q a ? = ? ? ? A ? = ? i r : : ll n 9 r i 9 r i e q q q q F €€ € € € € G S S € € G G € U G € € G € 6 6 € € € S S € € € S 6 € 6 9 € € S G G do € € o @d o c d € d € 6 d c d d € qq q q c 9 ? q ? 9 9 9 c q q q q 9 ? - - - ? q ? e - ? 1 Q ? Q ? ? - ? a - - : ii i i i i t i i i \ i \ i t i i i i i i t i i i i t i i t i i t t t i i i \ t EE !! 3E 8 8 8 E 3 3 3 8 8 8 8 3 3 3 8 3 8 3 8 8 3 3 3 3 3 3 8 3 3 3 E 9 3 4 3 3 3 33 = C a :d:,ia;j :EC UA is8. e 6!o .d 6 6 6 @- d r d ; + 6 d d 6 6 d 6 d - d F r - o ni n n a i n n n l i t t l n l t n n t t - - 1 t l l 1 n 1 : : - : n n l n n n _o ^ I t ** d d o d 5 6 9 9 a ? : I ? I : n : ? : e : ? : I 9 9 a n 9 Q n a I Q f a ! ? | n 6 ? I n I 5 ;^ i :; 99 9 9 9 9 9 9 9 9 3 9 1 9 9 9 9 9 9 9 t t t t n n n r 9 9 ! n 9 9 9 r 9 5 5 5 ^: : : : : ! ! ! : : : ! ! ! ! ! = ! : ! : : : : __ € d a -- r + , Oo o € € .6 a o C ia q q q - n a l a ! 9 i ? P q ? - n n i l n 9 t i { 1 q - t l n n 9 9 9 i P q a€ c o 6 d 6 € € € o d o o o o a o d @ na a a a a a i n n n n t n n - n n t n l a n n n n n a a a a 38 8 3 8 8 3 3 3 3 3 A 3 8 3 3 3 3 3 3 4 3 4 3 3 E 3 t t 3 E -: 9 : : 9 9 9 9 ! 9 9 9 ! 9 ! dd d d d d d d d d d i l d d d d d d d d i l d d d d N d d i N d dh 6 i r *- - - A d nn n n n r l t t t - t n n n n t t l l n - - - t t l t t t n i. + 6 d -a i d + d - 5 i d !9 e q n ! { ? r 9 q : n 9 e : n 9 P : t 9 q a ! 9 q a a q e :9 9 t i 9 Q t n r 9 n n 9 Q l i r ? n a l - a t n : t a t : aT : ? a a a n ? a a = : 7 a 9 a n a 1 1 a t : n a n f a: 9 QT r r - P q e c e q q ? ? ? f !e ? q r € r 87 of 2 0 l 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 6r 3 6 0 5 6 0 ad r r o 6r F d d d d - d N : 3 - 5 6 F n 6 6 a N + d oo € o € -- e - - - a - = EB ,EE} E3 3 3 3 t 3 3 3 E a E E 3 3 E E E E E E 3 8 8 E E E 8 3 g 3 3 8 ?? = = Q ? a o a s FF F F F € g C 6 A F € F ,e Q - _ _ a @ Fr o r + o r * - r o t . - d6 6 d 5 je 6 6e d - -; 6 ; ; - - tr l t 9 i t ! q Q : i i n 1 9 9 t i e q 9 : n l a a ! 9 9 r T q !\ ? q ! i q n ! i Q n n t e i n i q n 9 i q n 9 l ? n n q q n 9 I 3QAE. i 8. e FE.: .: Ll (J nn n l n n l i n n i l i a a a a a a a n n a a n l n a n n i a a n n n n n la ! = ! a i ! ! 9 4 9 ! 9 9 9 t r t r 9 t r ! 9 t r t r 9 t r q * E c - o o q ao . ! t6 5 8 t 5 5 5 5 5 5 5 5 ; t 6 ; 5 5 5 d A 5 d 5 5 5 5 5 ; ; ; ; t d ; ; = 6s 6 6 c od o 6 6 d 6 € 6 d 6 € € o . rF r r r r t s r ii i i r i t i t i i i t i i i t t i i i i i i t i t \ t i i t i i t t i i 3E 3 3 8 3 3 3 3 e E E 3 3 3 t E E 8 t E 3 8 t C E E E 3 3 E 8 E 8 3 3 3 E ,+ 6 h 6 - a 6 a di l d i l ; ; ; ; d a q " i o oo 3 0 0 :- - : - !L : ! - a ! ! ! : Ji I J : l l i J : _ _ : 88 of 2 0 l oo o € o € O O O G G G G € € O € 6 o a G G G G G o 6 6 d 6 € 6 o € 6 e 6 o c € € 6 d o € 6 € a @ € c d 6 d d 6 o o d 6 € o 6 G 6 4O a h + 5c . o c 5 3 c 5 o o . js d i i j i : - : - - : jj : j _ : : : _ _ _ _ _ j l ii d i i c d c i o d d d i d d d i o d 5 S d d d d d d d d d d o . S o o o S S d S S i . 66 5 6 5 6 6 6 5 6 6 4 6 5 ; 6 6 - - n - 6 a a a a E e 8 8 8 8 8 8 8 a a 8 8 8 e ; ; ; a i i i t t \ i t t t i t i i i i r F F ts r F F F F ts t s F F ts F F F ts F ts F F F F dd d d - 38 8 8 8 8 8 3 8 8 8 8 8 8 8 3 8 8 8 3 3 8 t t 8 8 8 8 8 8 8 8 8 8 8 8 t 8 8 t t 8 8 8 8 66 6 6 6 h 6 d 6 6 6 6 ; d 6 d d h d h 6 6 6 d d d d d d ; d d h h d 6 h ; ; ; ; ; ; ; ; 9t i 1 ! i i 9 i n: : n t 1 a ! ! n a n a 1 1 ! a n - - - 6 6 o - n - d - & d d d d - 6 - d - A SR R R S R R S A R R S S S R R R S R R R S R R R R R R R R R i R R R R R R i i R R : R 3 9 9 9 9 I 9 9 9 9 9 9 9 I 9 9 9 9 9 9 9 I 9 6. e e 9 9 9 9 9 9 9 9 9 9 9 9 9 I 9 9 I 9 9 I 66 6 6 d 6* q q q q q q q S q q E q q q E q 6 6 * * a a G a G s € € 6 8 e 3 a a a e e 3 a a a a a dd d ^ ^ d d d ^ ^ d d d d ^ A ^ d d d d d N d d d d d d d !q 4 5 6 6 S q ! 4 S q i S E B A q A S A A A B a t e I e e E ! a r r 8 h t r r s 5 5 5 5 6 d d 6 6 d d d 6 dd d d d d d d d d d 9 d d = 96 5 d 6 d d 6 6 d d o $a ^ - e € 6 + O - - - ; - 6 d + 6 i l - - - 6 i l 4 L - , - L r@ o - € -o a @ 6 5 d d 6 - SR i E E E S E E E E € E E 5 E E 5 5 A S e F 8 E 5 e E 5 8 3 3 = = = : : : = = a e r ! ! 46 6 d - - 6 - 6 6 - d - d d 6 d d - d 6 * & a a dd d d d A d - d - - - - - - 6d 6 6 d 6 G d 6 a & 6 6 - - ;d d d d j i 6 G d d : - h o - i - d 6 6 d d - - ;d d d i : ; 6 c ; . - : ; a FF T T F T F F F F F d d F F F F - - F F F F F F FF - 6 C - a N - + 6 6 6 F - 6 0 - : - ; 4 6 6 G -6 d 6 6 d d 6 d 6 6 6 6 d 6 d 6 6 d d o € € G F d d i d r r r i i r r ; d d d d d - ; ; 66 6 6 - 6 4 6 6 - 6- 6 - - ;; ; ; ; o d d d i i j - n n d d; d ; d * + + + d 6 6 6 6 d d d - - d d 6 6 a Q n a 9 Q 6 o ^ - h - d - - O n - d. n - 6 - i - 6 = - i 6 = il + 6 = d; ; ; o ' s o d J : l J i d d { ; n ; ; + + + + h n d 6 ; 6 6 6 4 i l i i ; ; & & d d i d 4 :- - - n t i n n n n t n d d n t l t n n n a f f "n t a a a a t n n - - - - - n i i a i !d !oaE. s Z. e EE aao tIt q'E!{le1 }E 89 of 2 0 l €a € € € 4 o 6 6 6 A- v . - t 6+ 6 6 6 6 6 6 6 6 6 6 6 6 6 6 e o e € e € € 6 6 6 6 6 O 9 6 O 6 6 € 6 6 6 6 6 6 O 6 9 6 6 6 6 6 6 6 O G 6 6 6 6 6 6 6 6 6 6 6 € € € 6 FF t s t s t s F t s 43 8 3 e E E 3 8 3 8 8 8 8 8 t 8 3 8 8 8 8 8 8 8 3 8 8 8 8 8 8 3 8 8 8 3 3 3 3 8 3 3 3 3 8 8 8 3 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 33 6 6 6 ; ; 6 ; ; ; ; h h h 6 6 ; ; 6 6 6 a 6 6 r . 6 ; 6 6 d 6 d 6 6 6 6 6 6 6 6 6 6 6 - 6 d 6 6 -N r e € ! ! ! q q r P l q e q q q n l l l i i n l l l l l a a n l a l l l l l n l l l l l 9 i 9 n t P t e i { i 9 9 9 9 t 9 6 r - r r 4 !; a i e = = = : = = = : ? = = = = : = = : : = : = = = = = = = = = = = = = = = = = : = = = = = = l l a t ? ? a a a = e ? : o o - - - - ?+ - r o ?a 6 6 6 66 6 6 d 6 d 6 d d d d d o o G o o o e e € € e € € a e € 6 e e e € s € € € G G € € a o o o 6 b b b b b o 6 F F F F F F + + d n { n n d ^ d dn d ^ ^d d d d ^ N nn d d A N n ^ ^ ^ n d n ^ ^ dd d ^ N^ ^ dd i d !(, a :. 9 .? .2 - F:e: .: H I 3 Q- d 6 € 66 6 6 5 d 5 5 -- 6 d o r d - e d d € - - - - a d dA d N A d - N N N dd N d - d - - - d d d d ir 4 + ! E ; i ! B r ; f r R a 3 F , 3 ; R E G e S S r E € : 3 G E 5 f s 3 ? S 3 F r 3 E e . 8 i ? E x i E C 3 E i 5 3 R s 3 € 3 8 S S 8 G 5 Ia 8 3 = E E a = r = 1 = l i r I E I e : : : : : a 3 + + * t * ; | i l * h a ; s : € 5 3 - = i i s F R ; ! J € 5 a ; l l * E e = " i H i a -6 € 6 6 - - € 6 - - - 6 - - - - - 6 - d - - * & A & - - - - - - - - & - i a 9r ^ o , 66 G r - 5 6 . - N - F +6 aF - - 6 a j ^ A a r 6 o b n - t o 3 rr + i * n + + ?n e i ? n ! i q n e i q i e i q E q r B a q e g A s s € A q E s i q ; 5 i 3 ! i i ! ? 5 q E { q l f i q i q i q i q E : i q { : i e { -- - d A d d ; ; ; . i + * i 6 6 6 6 6 6 u 6 r d r r d d - - d d d d 9 = 9 9 = = = = s : ! ! ! ! ! ! : : J = ! 9 ! ! 9 9 9 9 . .' " i . -$ 9 = E+ }EdF ra r : n n 9 i t a 9 : r a 9 : a a 9 : 1 a 9 : t a Q : a = i . : - a l . : n i a a a i " : n a a - r i a : n : i a i i a : 9 n - = r i i ,r q ? ? ? ? a ? a ? - - - - n d ^ d a -6 6 6 6 6 6 :I l i : -- : t : t - - i - ji r : l l _ : : _ !! ! r a i J J _ _ :EIz3?n=' 90 of 2 0 l i3 i $ s r s s E r s a s * ! B r $ s s s 3 3 8 B $ s $ * 3 3 3 s g s 3 a * * i r r s * ; * * c E * * * * g * s s * * !! ! ! ! ! ! ! n ! ! ! 9 9 ! ! 9 9 9 ! ! ! 9 q 9 9 9 h 9 9 9 ! n 9 9 ! 9 a 9 h n n 9 € 9 9 9 9 9 9 9 9 q 9 9 9 9 9 9 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 i 9 t i i i i 9 9 € € 9 9 9 9 9 9 9 9 9 9 9 9 9 3E 3 3 3 3 3 8 E E E t E 3 E 8 E 3 3 3 t E E E E E E 3 3 E E E E E E E E E 3 3 S 3 3 3 E 3 3 E 3 3 8 3 E 3 8 3 3 E 3 iR?n €e € c a a 9 c ? € a e a a e q q ? ? q ? P e P ? P e P T r f Pa ! c e € € { q r ? T q a { r q Q r q q ? r r r t e e == = = = = = = : = : = = = ii i i i i i t t t i t t i i i t t i i t i i i i i i i t i r t i i i i t i i i l \ i i i i t i t t i t i i i i i i \ ri i i t i i i i t i i i i i r i r r r t \ \ i t r i \ r i r t c i i i l i r i i i r r i i r 9 9 9 9 9 9 9 9 9 9 9 t is8. " (J nq l l q l a - a 9 e q 9 : \ i t t i - i - - - l n e n i - i e c 9 q ? a a i n a i l 9 9 a q : q a n 9 1 9 n l a 9 q F6 O F r o3 0 0 0 ++ r * i + i r i r i . r r , 66 6 6 6 6 6 6 6 6 66 o 6 6 6 6 6 6 gR e B n a s = E s = r T = R s = e ; E R r E ? p 8 B : 5 g t a a * l B s $ n r D ; 1 g q : E a s i e : 6 q : C q i C r: = = = = = = = = = = = = = = = = = la n ! 9 9 t i * q ? - - t n a ! ! 9 t e q q q l t n a l 9 9 i q e 1 q : : n n a ! 9 9 i q q q ? - n a a 1 9 9 i q c Ee E - ! q F q F a r s E ; r E R i l R a R ; e € e q E E e q - g= H - i i I Q 5 : f r tB i q q q i q A A i E E = -6 dd d 9 9 = 9= . : : ! t ! : ! l l M ! : : : : ! 2 Z2 2 Z 2 2 2 2 22 2 2 2 2 2 2 22 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 > 2 2 2 2 2 2Z 2 > > 2 > > > > Z > .I ? n n I I r I 9 9 n r r ? r n n I n n r Q r n n a n a I a n t 9 a n a a: a a a: I a a: n I n : I : I : n a a. ac o c o :: : - - - d ^ i ^ n n i l n n n n n i l i i i i d n n A 4 ^ ^ ^ ^ n N { ^ i ^ d { A d n A i i n i l i l { n n n i l n n n i i {e c e ? ! e r e e r a 66 6 6 6 6 6 6 6 6 6 d 99 9 9 9 9 9 9 r 9 9 9 nn a a a n n a a a n a ?d d d d d d d d d d d :5 6 6 6 dd d d d d d d d d d d it t i i i t i i i i i 88 8 8 8 8 8 3 8 8 8 3 In t t t l l n n n n l +j d t d d d d d 5 i i 1! n P ! - I 9 - r 1 - -n n 1 1 n 9 i f ! q ? :a 9 q : 1 9 e - n 9 e :n l ? i 9 n ? t a ! ? 9! 9 9 9 9 9 : r r ? 9 9l of 2 0 l idg8:3E} it t i 9 9 9 9 9 9 9 9 9 i r - r r i i i t i i i t t i i l i i t t i i t i i i i i i i F t i i i i i \ -: - - N -- & - 6 .5 5 5 6 56 5 6 6 @ - 6 6 r - 5 @ - * * - c € - € c c e a e c q e e a q 4 qa . q a < eP *. q q q a c * c q c ? r r a a < ? 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I I I n n I I n ^ i I n n l I & A & & n d N d n n n n N d N n d n d d n 99 9 9 i i i t 9 9 9 9 9 i i i na q a a n n a a r t n n n ! n e q n a n a a n a a t€ e ? c € c € c t t e ? e q { { e q q e c ? q { c 38 3 3 8 8 99 9 9 9 e 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 i ti t i t i i i i t i i i r i i i i t i i i i t i i 3E E E 3 3 3 3 E E E 3 C 3 E 8 E E E E E 3 E 3 3 E ;e ; r r r h h 6 d dd d 6 d F F F d - d d t 6 6 6 ft i n n n a n a n : : a t : n a 9 : f a ? : t 1 ? rn n n n n n n n a a e n n n r n l n n n n n 9 t t re 9 9 9 9 9 i i i 9 9 ! 9 9 9 i i r i i3 3 C E E E 3 g = E E 9 i = 3 = C 3 i 93 of 2 0 l :IE: . >€ ic i i q i i i i i t F i i F t t i F i i i i r i i i i \ r i i i t i t i t E3 3 8 E 3 3 3 3 3 E t A E g E 3 E 3 3 E E E E E E E E E E E E 3 E 8 3 3 3 ii i i i i i i i r r t i t r r \ \ i \ i r i t i i i c i r t i i r F i r i o" r + h e h 6F O ^ 6 0- 6 6 3 - h - 5d i : : i ^ d d d 66 o d o d d d d d d - d d r i 6 a !E. E 2. 2 (. ) n! 9 ! ! ! 9 ! ! 9 1 ! 9 9 4 1 9 9 9 n ! ! 9 9 4 ! ! n ! 1 9 9 ! ! n ! 9 9 4@ @ - - € - - q9 n 9 9 n q i n q i 1 . q l - e 9 n ! n a q 9 n q 9 n q 9 a q 9 a q t n a €5 5 5 E 5 nE q q q ? r ? q a q q ! qq q q * q q q q P I a a q q 6 q 5. a d qq si d i d i i o i i i o d S S d o o d d r: 1- 1 6 = n a * ? q - r F a ri i i i : i i i d i i a o i i o a a > i6 6 6 5 6 ' n 83 3 3 8 3 8 8 8 3 3 8 8 3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 6; d d d d 6 6 -; 6 6 6 6 6 6 6 b ; 6 d 6 6 6 6 c. 6 - Fi i i i t t t i i - i i t t 9 i i 9 d d d d d n n n n d d n n i n n d N ^ ^ ^ ^ N d N N N ^ i O6 s F r o r r - r - = t :- - d d d n d 9t r q q q - n n ! t n 9 i e * q Q - n n n a 9 9 i i - n " - - a CG G G G S S S S G S S S G E S G G G € G G G B B B B E G B € G S 9i * ? 9 : i a n : n a I . s : t : a : n a n a 9 : n a n : l a 9 : I 9 9 9 9 9 9 I I n 9 n : ? t 9 9 9 99 9 1 I n : y 1 n n t I t n oo € o € o6 € o € € d 6 6 d o o a d G d 6 d c i do c o 94 of 2 0 l o6 € o o o o o o o 5{ ? 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E 3. 9 c4o 3E 3 E 3 S E S t E E E E E E E s E E t 3 E E E E B E E I E S !! ! ! ! 9 ! ! ! ! ! ! 9 9 : = : : ! : 9 : : : : : : : = 9 : n9 1 9 9 9 i 9 ! ! \ 9 i i ! ! 9 9 i 9 9 9 9 ! 9 9 9 9 i t i 88 8 8 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 8 8 8 3 8 8 8 8 8 8 8 {< < ? r e ? c q r { e < a < c c { c a * r q e a € q ? c P e ci i t i i i t i i i i i i \ i i i i i q i r q i i r i i r i ii c i i c i i i i i i \ i i i i t t t t i t t i t t i t a i 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 ?9 ? 9 ? ? : - - - - - - - : -- : - - - - - ? 5 o 6r - i d + 6 F 6 5 d ' 6 F 5 o d , d F o jN + 6 o3 - : - -: - j i N d N d d d d i N N n d ; ; ; ; .. : - - - d d d N - ; 6 - i r i ! ; ; d d dO d d F i d F d r9 ? t n t 9 t r n 9 t r : 9 n n 9 ? n r 9 Q n t 9 9 l n 9 9 :: : : : : t f n n n t n t i n n n n n n l n n n l n n n n n 95 of 2 0 l 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 ir r r i i i r i i l i i i i i l i i c i i i i i t i q i i i i i i t r r i i i i i r i i t t F a8 ; 8 8 8 8 8 e a 8 e 8 ; e 3 a 8 8 8 8 4 ; ; ; e 8 8 8 8 ; ; A ; ; ; 8 8 8 a 8 8 a 8 8 $ S r1 ? ? ? : = 1 1 1 = M r : ? ! ! ! 1 ? 1 1 1 1 ! ? ? 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S E _ 1 ! p A :d ; ; ; d ; = : 9 9 a R S F & 5 3 ; S : 3 8 ? ; t 9 $ $ ; 3 f i 3 f r 8 G g 3 G g e S E p F A ; $ 3 S g e a 3 8 S E E i E E 9 : : l : : 3 - ,+ a i 6 6e o o o 6 6 6 d; h 6 6 ; ; h h d d G 6 6 h 6 6 6 d 6 v ' d 6 6 d d a ' d h 6 d h h h h ; h 6 h h 6 6 d d d 6 d d 6 ; - - - - ; ; ; - ; ; ; ; ; ; ; ; ; ; u-n { 9 n a i l 9 q l 9 9 a q q l : a n : 9 9 q t q q q q e - a 1 - - q q q : 9 : - - q n n - 1 t n a a 1 1 a 9 9 9 9 9 9 9 9 9 i i 9 9 9 11 : q r t i i c l q ? n n n n n n n a a a n Q q P ? i e ? c { a 9 i - - - t i 1 9 9 i i i i i t 9 9 9 9 ! a I - 1 p -- - - - - 6 4 & re : a ! 1 a i l c c a a ! 9 ? q ? : 1 1 1 ! ! 1 9 9 ! i 9 9 9 9 i l a ! l ! a 9 i ! a n q r 1 l r ! a r n t i - 9 q t 9 1 9 1 9 9 9 9 1 ! i fS a a S a 3 e B a a a a s s a E E E E E E € 3 t 3 t 8 8 8 8 8 3 8 8 8 8 8 8 8 8 3 3 8 3 3 8 8 8 8 8 8 3 8 8 8 3 e * $ S 9 e S s e e 3 $ o€ € O O G 9 O O O O O O O O D a O O 6 O O 6 b 6 6 6 6 6 h h 6 6 h td IeIdE8- : 1A =7 r Ca 9 9 o o6 9 6 6 o € € 6 d 6 9 9 9 9 9! ! 9 r d 6 o n d 6 ; ; ; oe o o e od n o r q d 6 + =- q 9 * q q - n q l 9 n q l q q n 9 n l a 9 q i ! q a P i - - i n q n i ! f a q t q l 9 q 9 9 i q l l 9 n 1 q f n 1 - q ? i a ? 1 9 ? a !E -n =: 3 t 54 e 5 35 3 -3 3e 3 3E E 5 = I l 3 R r, r ? 3I 3 5 3 e =: = 5 3 S 3 8 5 e 8 3 3: = = 3I = 5 r B 55 R I R e =5 = I o@ r r - 5r € F F - - - o F F G F r r r o - - 6 r i - - F F G G G F 6 5 6 F ?? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? i i i f i ? ? ? ? ? ? ? ? ? 9 ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? 9 ? ? ? C ? ? ? ? ? ? ? ? ? e b6 o - F o6 d a + - & 4 5 3 + - ; d r 6 - F F 6 h a 6 6 -o r - € or F oh ,r F . - + 6- 3 4 6 6 r - F .a ? ; ; i q . : r . J f . } a f f a ? . l . l ' t 1 " J T t . J ' : i t . r . ] T T T ? T a a r t . t a a l . n ' t ? a q a a q a a a . : a a . : . : a a i l + . t . : . t q q . r !E?. e E} E' (J ?? r - ! ! 6 d 9 ! - t 3 9 t a 5 3 6 t ?? = - o 6r r r ^ F 6 d i h 6 0 0 0 __ d N d d - F n 5o o d 5 o o o 5 i i - 3 o -. i = o i 5 5 d d o o 5 i i . o o d i o o o o o dd d d d d o 5 d d i 3 i i o c . i i o -6 - a o a e € 6 d 66 6 9 i P t i f - a n 9 i f r l q q q q q - : - - - - i n n n l n l n N ^ - : - l a a n 9 t t i r i t i i t i i t i t 9 € c i e q l l l dG d ! = 9 9 ! r = = = = = = = = = 1 1 1 1 9 9 1 9 1 1 9 1 1 9 1 1 1 1 1 9 1 9 1 1 1 1 9 9 1 3 1 1 X 9 1 X X 1 X X 1 9 : : 9 r = = = = = !E C E E E E E € E C E E € ! ! E ! € E € E E E s E E E € E E E E E E 5 E E 3 3 E E 3 E 8 8 S S E 5 8 5 8 8 5 5 8 8 5 € 8 8 8 5 8 5 8 8 S & & A A A & A & T A T A 4 A A A A A A A O I T O A A A A A A A 4 i C C dE E d d d E E E E E E E E E E E E E E E E E d d E d d E N6 6 O d ^- 6 a d a 6 o i ; 6 - n ; ia - = = - ! a e r i ' { n n = n ; * ; 6 f r f r d 6 6 6 i l i ; d ; ; ; ; a A 6 d a 6 d d : : : i n n n n ; - - - * ; = * - - ; d ; 6 6 ; i l d i ,* + + i + + + + .- - - ! : - : : : J ] : j J : - - - - L ! : : : : ! ! ! ! . ! : ' . ! . - - ! : J ] ] I j j : j J J : : : - ln n l n n n 1 l l n n l n n n n n n n n i n n i n 1 n 1 l l n n | | l l n n n n n n n n l n n n n 1 n l l n n l l n n 3- . o e ao a a o o a 5 a a a S S j j j i S S Aa i i - i ^ A F a - F - - & F - - i ^ d ^ - ^ n i ^ d - - - - - - N d d d - 97 of 2 0 l 83 3 3 3 = A I 3 3 3 3 E E E 3 E 3 E 8 8 E E E E E E 3 E E 3 3 E 3 3 E 3 3 E 3 3 3 3 3 3 E E 3 3 E 3 E E E E E E E E E E 99 9 9 9 9 9 9 9 9 9 9 P 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 qq q q q q n ! q t ! 9 t 9 ! a a a i : ? Q q ? q q 9 ? : : 9 q e e f 99 9 9 a a - q € ! q q q i 9 9 9 9 i 9 9 9 t 9 i a 9i - 9 i t 1 a ! i e ? q i 9 9 l 9 n ? 1 9 i i i l ! 9 9 9 1 9 ! n ! ! l 9 9 9 9 9 n n a 1 1 l n - q 9 9 9 A Q Q - - e A an n : ? c q q a 9 ? ? q q * * i 9 9 1 t n n ? 1 i 9 9 9 9 9 n ! l l n I n n n a n - - - i q q a q q a q i 9 ! 9 ! 9 9 9 9- ? 1 1 9 i ? n n - n n i 9 i 9 * n n - ! t ! q 9 : : \ l t q n ! ! 9 ? n ! t n e - 1 q t ? ? Q 9 r l ! a - 9 ! 9 t a 9 nn n n n l n l l l n l l n n t t t n n n t l t q n n n n c i t n n n n n n n n n q n n n q q n i n l n n n n l t n n l n d d n - * - € € - d d d 6 - - - ; dd d d - - dd d d i d n - d - d- - - i t d * d * d d d d d - d d d d - - e nl l n i l l l l l n l l n n i i n n n n q q n n q n n t t l n n n n l l n n t i n l l n n n n t l t s n n l t n n n n n q:ga{E21 'e le n n n n n l r n - Q P r 9 t r t t i i ! ! ! 9 9 9 i t 9 ! t a 9 9 a a n a n a 9 9 9 t q q q € i 9 a 9 9 9 i 9 9 n \ 9 E. q 8. e O ?9 9 ? ? ? ? ? ? ? ? ? ? ? ? ? " ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? l ? ? ? ? ? ? ? ? ? ? ? ? ? 9 9 C ? ? ? 9 ? 9 9 ? ? ? la a l t l n n n n q a n n a n l l n l l l n l r n t n r l n n l n n l t t n a t n n n t a n n l t n n n n n n n i a a a : : 5 : : "E : : : 5 : : : : : : : : .€ -5 : : : : : .5 "E : : : : : : : : : " : : : E : : : : : : : : : : : : : : : : : : : : -- - ; a 66 - d - 5 r : r r M n ; J ; ; ; ; + + ; ; ; ; 66 6 6 - 5 0 . - - o o 3 5 . 5 . o 4 6 6 6 0 0 0 0 d+ 6 d 5 : ; 6 r ; 33 3 3 8 3 3 3 8 3 Nd J J ; ; J ; J J 99 9 9 9 9 9 9 9 9 99 l a n n n I n n ni q n q q - a 1 ti 9 n a n 9 i 9 9 dd d 6 d d - - - d 9t l = = 9 9 9 9 9 IY Y Y Y I I I Y Y an t l n l l a l a E8 E 8 € 5 5 5 8 5 AA A A I 9: n a l i n i n i 98 of 2 0 l !t A8 E 8 3 3 3 E E 8 A 3 E 8 E 3 8 E 3 3 3 3 I E 3 3 E E 3 3 E 3 E E E E E 3 8 E E E E E T E E 8 A E t 3 3 t 3 d d 6 6 d d d d d d 6 d d d 6 - d d d h 6 d 6 d h d q o n n 6 6 6 h d d 6 6 6 ?9 q q q q q a q q q q a a r * i 9 9 9 9 ! ! 9 ! l l n a n a n n n t n q - c 9 q q q q 9 i - - - : - - - n i- a - 9 n q i a q 9 : ! q r a 9 . 9 q i l i 9 9 e n ? a n 1 - q a n 9 a q t Q \ s i - t n a 9 9 T 1 a t a oo . 3 - -c o 1 6 5 . - - nn l n l l l n l l l l l l n l n l n l l n n n n i n n n n l n n n n n n n t t n n q n n n l l t l n n l n n- q q q q a e q q ? q i 9 9 ! ! ! l n n n l t l l l n n - - 9 9 c q 1e i 9 9 9 9 i t q 1 1 ? ? - i - - - Tl a i q ? q q q q - a 1 1 9 9 9 9 1 1 9 e q c - q 9 - n t q l t c q l - n a q n 9 1 - n 1 1 t a 1 a a 9 q !1 1 1 1 1 1 n n t n t t : : q q e \ F ln n n n n n t n t n n r n l l n l n a a q q n q q l n n n n n t n n n t l n n l n n n l n l l t a n l l l ?? ? ? ? " ? " ? ? ? i ? ? ? ? ? ? c c ? ? 9 9 9 ? ? ? ? 9 4 ? a c ? e ? ? a a e ? ? ? i a e 9 ? ? ? ? ? q na i l n a a a a t a a a a t n n a n l n t r n n ! n n t n n t n n l n t n n n r t t e n a t a i i a n a n 53 E E E E E E E 3 E E E E 3 8 E 5 5 E 8 E E E E 3 E 8 E 5 5 E 5 5 8 E 5 E 8 € € s S E E E E E E E € € € E (J A YuE. E .? .= F: .: H !(- ) ez- - EN=a a€ o o € 6 0 € o c € a 6 6 N- 6 0 d 5: r r r i il n n ; ' ; ; ; ; ; ; ; - -; F F i i & d t -; a d; d 5 d 5: : J: i i l ^ n; n n; + nn n d d n n n N n ^ n ^ n n ^ d ^ A n N N ^ n { d d & n n a n i n n ; n n n d i l n n n n i l d d n n n n n n a! q q e n n q e 9 a - r 9 a - c 3A E E 3 E 3 8 3 3 3 e E t E E g nq e q q q a q q q q - 1 a l a 1 9n n r 1 ! 9 i q q 9 q * q ? 1 q ql q - 9 n 9 q n 9 - q 1 9 ? a n ! 9! 9 \ r 9 t r q r t t 9 9 c i 9 t -a - - : 1 : : i i a a q a n n e r r r r r r i aa o F o o 6 d^ d d d d d d d d d d it i { E i l E l E i I i l t E E ?n n ? ? n a t a t a t : i a 9 : U? 9 ? ? ? P P ? ? ? : 99 of 20 1 o^ + ; F a - ^ r 6 d 5 - ; d r d d d r d d d : i r € - 6 : F ; 6 € - o N 6 6 r r - d Tt t 3 t t E 3 t 3 3 3 3 3 3 E 3 t 8 E E E E E E E 8 3 E E E E E E E E E E 3 3 E E 3 8 8 E 3 a3 0 a o €q € € € E dd d 6 6 n 6 6 6 6 d d d d 6 6 6 ; d d ; . ; h 6 d d o q d r q n d q i9 1 4 1 9 * 9 r r 1 1 n n n a r 9 9 9 9 ! ! 1 ! 9 ! ! l l a 9 i r n q q q e e l 9 9 i i l i qn t q ! a a 1 9 f n! q 9 r ! 9 q l i ? 9 9 ! 1 n q q 9 i a a l 1 i a c n i - ! n a : ! - q qq q - a n t 1 - n 1 l - - l i r n l a n a a t a q nt n e n t t n n t n n n l n n n a i a a n a l n l l n l l n t t l n l n t t n n n t n n n n 5E E 3 E 5 E 5 E E E 3 E B E 5 E E E 8 E E € € E E 5 E € 5 5 8 8 € 8 5 8 8 8 8 5 8 5 5 5 8 8 ll l t n n n t n n t n n n l t l n n n l n i n n n n n n i n n n n n n n n n n n i n n l t l Ed i3 . IEIa" - ;> 99 9 t n l a l n t i a n a n a n n n i - q 9 q q 9 q q q q q q q q t? 8 8 3 3 3 8 t 8 8 e e 8 8 8 8 8 8 8 8 8 8 S 8 8 S S s S S A S A OA Yu :E3. 9 Q oo e 6 € nl l f n a n a i l n l n n a q q n n n t n t l n t n n n n t i t t n n n l n n n n a a l n n IY Y Y r ?Y Y : Y a l a Y i i Y i a r Y i i r i r i i Y t i i 5 I r : I il n n i ; ; ; ; ; ; + + 6 ; ; ; sj 6 .b . b F F F F d - & - 6 6 r d 3 o o o - : : : & i na n n a n n n n l a n n a n n l n n r n n a n n a a i n n n a a a a a a a 9 : : a a a a : : 88 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 3 8 8 dd - d e d d € d d - - d d d - @ d d - € d e @ qd o q o t- : : - Q ? 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G € 3 3 3 3 3 3 3 3 3 3 3 € 3 € aF E R l K R R I x 5 s 8 9 E 5 5 8 E E E E E t g t 3 8 8 3 S E g : E E S E 5 E E 8 5 8 8 t B E 5 5 * E a E - a E 3 * 3 e B r - f - P i s *: ' ; F d 6 d 6 - - i; r s 1 : = 3 a 5 3 ; 3 f i 5 $ 5 3 h ; $ ; S $ 3 5 S $ 9 S $ ! 3 + ? ? + 3 $ q ; e 3 5 3 1 ! ; = 8 a e a t 8 X 3 3 * t 3 8 3 ; 9 g i E a1 - a ! ! ! a a a a - t a l a a a 1 a ! a a 1 1 a 1 1 1 a a l 1 1 a 1 n a a l l a 1 a a a l a a a n l n n l l . a . n n n n n n n n n a ? T i q q q t. i i i q, l q f i a f l l a l. t i, i . qi i l, l . q, l. l t l l l f f f a l q l .l i + a q a l .l l a a a a l l c' a .} q i q q .l i l ?r ! 1 9 t 9 t q n i 9 q e - ! 9 ! ? n l q i ! - i a q 9 1 q ? ! : 9 \ q l 9 n q q l - c 9 q n l q n \ - q 9 \ 1 r - ? q n n l q a i 9 8: : = 3 8 S e S 3 5 e= 3 5 3 3 3 3 3 5 e r 58 E 58 3 3e - 3 3I = 8 3 3 e 5 5 =: = 3 3 5 3 3 iE !? = 3 0 A - E E = 3E 4 g = 3 -: A- - - - ; tr dY. i ' 8. 9 LC .: 9O,Ei- . al a ! ! ! 9 ! 9 ! ! A ! a a a = = = a = = !E E ! ! r { { ! c - E { ! 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E ? q ? . 8 ! _ e : q q q _ E q = dd - d - d - d - d d 6 6 - - @ d d d - - - - - d - - - - 6 6- 6 6 6 66 4 ; A i i l d - - ; - - - 6 3 3 5 3 3 3 3 3 3 3 3 s 3 = E 3 5 s I 3 8 8 E 3 3 3 3 8 3 3 a 3 3 3 8 3 3 - 3 E 3 3 3 3 3 3 3 3 3 = 3 -i - 8 3 3 3 e I 3 -; ; ; ; ; ; ; ; ; ; ; ; ; ; ; - ; ; ; ; d ; ; d ; - d d d - € @ a d d - € € € € " - ;; t ; ; ; d d d ; i l u i l 6 - a d e6 6 - od d c 6 o a a o 3 €€ - o - ;; d 6 + i r 6 6 6 6 6 8 O 9 6 6 6 6 6 6 6 G 6 6 € 6 0 e e d- - - - - - - F - A - d d d d d d d N II I I N i I - I I N N n d - N N d d N d - d - - d A N N d :3 : f : = ! 9 * * 5 * 5 9 9 ; ; * S f S l ; f i AA f r il ; ; f r ;i l 3 ; + G A A ; 3 f r ;4 3 € 3 8 8 3 3 S r 8 8 3 3 4 5 ;; ; ; ; ; ; n ; ; . a a i d d - a ;6 a 6 ; 6 6 - ; ; . . i n d ^; ^ ; ^ ^ ^ ^ ^ ^ ^ - d d ^ N ^ n i i d d i l N N ^ d ^ d { d d i l d n ^ d I d d d d i l N N d d ^ d d d i d { n n cB c c E g g g g g E g g g g g g g g g g B g g g g B g g g g g B B g S g g g g g g g g g g B g E E g g g g B g B g g E : - = - - = = - a = a; a c - a a d a a a = a d i . : i 3 : c c 5 c d 5 d i d d do j i 3 d id i 5 . . 5 d . b6 6 6 6 b 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 n 6 4 4 6 6 6 6 E 6 6 6 4 4 6 6 6 6 6 6 6 6 G 8 € e O € 9 9 9 9 9 9 99 9 il . . i " . i i i l " j a i i . i ; i . 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F c- a e i i; ; ; ; ; ; ; ; ; d ; n 6 i9 ! n t - n t l a l n t ? ? : n t q l ! ! 9 9 9 9 i q l a 9 t i t i 9 9 q it 9 a 9 9 9 a q q a 1 e q t t t n t n a 9 n 9 q 1 9 1 9 - c c a q q ? n t 63 t n c 5 c . o o 5 0 5 0 6 o+ d t r h A 5 - 6 6 : - o - ,^ F d id + ; a 6 j6 d o* o d d 6 F r o d , d d o -- : ; € d d d -. 4 - - + + + - + b 6 6 6 6 6 38 8 8 8 8 8 8 8 8 3 3 3 3 3 8 3 8 3 8 8 3 3 3 E 8 E t e 8 8 E 8 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 -: - - - - a ! i q - n t a a i : - 9 Q q c a l T q a * c 9 e € q dF r t s r r r r r - a - - * - q9 i n : 9 9 a i 9 n n 9 a q ! \ 9 a 9 ! - 1 9 n 9 q 9 i - : i - 5a - i - o o c 3 O . o 3 o O o o 6 6 C Ca o s o - - - in n n n n a l 9 9 r e e q q 9 c q c q 9 q a ? q q Q q 9 q q 9 q r lq q n q ? ? - l n l 1 1 1 ! ! 9 9 ! 9 9 9 qn n l n t n n l n n n n n n l i n n n q n n n n l l q n n l n n ?e n ? a a : : ? q q Q - - q a q q q q n q - - - q 1 9 1 4 1 1 9 N= = = a l ! ! ! ! l t : ! a a 1 ^ e8 € € B 3 3 G G e 8 G € 3 3 € € 3 3 € 3 3 3 3 3 3 3 8 8 3 3 3 3 qn n t i : i - n n n - n n n q n n q n n n n l l n n n n n l n n ?? t ? ? ? ? ? ? ? ? ? ? ? ? ? ? 9 Q ? ? ? ? ? ? ? ? e ? ? ? ? 9 an n l a l a a l n n a i n t n n t n l ! n q l a a a a n a n n n 53 5 € E E 8 3 E 5 E E 5 E 5 3 E 3 5 5 5 5 E E 5 5 E 5 5 E E 8 E et t t ? t = t t t = t = e t t t = l l l l l l l ? l ? l l e l l 9: n a 9 i l a n : n : 9 - n : r i l a : : n a 9 : l a 9 : l : ! €6 € € F F F F a9 9 n 9 9 n 9 1 t 1 3 9 9 9 ? ? ? t n a ! a 9 9 9 r 9 n 1 9 9 9 10 8 of 2 0 l = E3 n9 ii41 6F i 5 d + 6 r a :d r d - o - d 6 r - i d ' 6 r 6 EE 3 A E 3 3 E 3 E E E E I E A E E 9 I 3 8 E E E 3 3 E 3 E 3 99 ! 9 1 1 a a n n n - - - : i q ? 9 q q { t 9 9 t a a n l - i9 i e * q q q r e i e q q - - q a q n ? r l 1 1 l n : i 9 9 nn l 9 9 a i q q q q q q a * a i i e i i e ? r e i 9 9 9 1 i 60 5 0 0 c 3 3 5 0 a o li ? ? ? ? ; ? ? ? i ; i i i " ? i ? ? ? ? i i ? ? ? ? e c ? ? 9€ € O 0 0 -- ? q q q " q 9 q q q q q q q q q q q q q e ? q r r r 9 9 n - 1: 9 i: - q r ? - q q a a i c 9. c q n 9 a ? n q - 9 ! q ? * 65 5 4 O _ q eI n l a 1 a l n l 1 1 a l n n n n 1 1 l n t a i 1 1 1 a a 1 Ii t -5 I t^ E I 5 tE I { E €i i { E i I EI E i { € I E I I n ! ? l -. 6 q I T r I l n n ? l n 9 ? a1 ? qn a nq n n n 9 :i i i : : n l l l n n n e n i n n n n n n $ t a n t n t n n !90 !E_a .Z .2 _ Uaa{!8l :: !l a n n l n l l t t - - a - q q q q q q q e t i 9 9 9 9 a a 3* 6 6 - A- . a r s - o N; d F 6 d N + 6 c o j -6 6€ o ^ 3E E E E E 3 E E E E E E E 8 E E E E 8 E 3 E E E E 3 3 3 E E 3 3 3 3 3 3 E E 3 it i i 9 9 l 9 i 9 i i i i i i { P p * r < q q ? f ee e c * e e i i i 9 9 9 9 -- - : q Q Q q - - - - - - - l n l n l a a a a a n a a n n l - - - - ? q q q c ?t 1 a l 9 e 9 i - - 1 a - a i q t n r t t l 9 9 9 n q ? q q q ! 9 q q a i - 9 nl t t l i n n l n l l l n n e i n i n l n n n t l t l n n n n r n n n n n n n q- l I n 1 n 1 9 9 i t 9 9 a 9 q ? - 1 n n a : q : l a t ! 9 9 ! 1 a 1 9 t t { 9 nq a a a q ? ? a a q - . - - l l n a q n t n n n l n n n n t n n n t t t - - : ?? ? ? ? ? ? ? ? ? ? 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N d ^ N { N N d d d N d ^ ^ ^ i d ^ N d d d d d d d d d d d d d d d N ss s s s E E s s s s S g s B s g g E s s s s B s s g B g B g g g s B B s B s s Nd d A d d d d N - 10 9 of 2 0 l a u1 !Isb8l !?E} tq !9AYu :E .3 .? .: H I 1n - : ? e q q ! \ i 9 9 9 9 a a a a n n - : q - q 9 9 9 q q q q q q q q q f re f e e e f 5: 6 6 r 6 o d + 6 F 6 j6 6 o- i d d 6 F a - d + d d d j 3E 3 E E 3 3 t I I E E E 3 t E E E 3 E E 3 E E E E E E E E E E E E 3 3 3 3 3 3 8 3 3 E E E 3 ;- - - € d d € 6 - - & € d d E 6 . , d d , d d - d r * - d . d d d d - d d d - - d d i - d € in q a c i i 9 9 9 9 1 a e n t - : 9 q q q q q q q q q q q ? ? 9 q q q q 9 q q l q - : - 1 1 ? qQ - n a - - a 9 e q c q q - n n n n n l ? - n a a ! 9 1 n 1 t 1 1 a r n ? q q q q q q e i 9 n aa l n n i i l - - c q q q r t 9 9 9 n n 1 l n n i l t - - - - - - ? ? q a a { e { * e q e ! 9 qn i t n q q n n n q n q n n n n q n i l n q n n q n n n e n n n q q q n n n n n q n i n q n n n- q e r f : - q - q q i q q a ! 1 a n 1 - ? : ? q a q i e ! ? * i a n l n r n - : q q q r ? f rr a a = r 1 = a a a ! t 9 ! ! ! r r ! ! ! ! ! ! ! a a ! a ! ! a E E E { E E I E : I -E E E E E E C E q ! E E C I -5 C E M E E I t q E E ! -E i _3 -E : I ! -E qt l n r q l q n - q n q n l l l r l n ! * q - 9 9 - 9 n n i l l 9 ? 9 q q ! ! 9 l q q i l l a l- l l n n n n n i : - n n c - n : l n n a : - - - - - - i : - - - - - - a - - i - - a i - ?? ? ? c c ? 9 ? 9 ? ? 9 ? 9 ? ? ? ? ? ? 9 ? ? ? C ? ? ? ? ? a ? ? e ? ? ? ? ? ? ? 9 9 9 ? nl a a . i l a n l a a a l a a a a a l a ! a M 1 t a a a 1 a a a a 1 a 1 1 : a a a 1 1 d d d d o 5 d - !: i N d d d ; 6 d ; + + n + 6 h; n b i 6 b F F r i d nn f l n a n n n n a a a a a a a n n a a e a n n i r a a i n r n n a a n .i i ' i i . i i i F F f 6 ; a - d sn i s n n n n n n n n I l0 of 2 0 l pyllffinse TTCHNICAL GROUP Emissions Calculations Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Sou.ce Project No. AST-2023- 1660 Run Number Runl Run2 Run3 Averase Date Start Time Stop Time 8t25t23 8/28-8/29t23 8/29-8t30/23 8:20 22:58 23:25 12:,51 3:13 3:51 Calculated Data - Outlet Oz Concentrati on, o/o dry coh 7.55 5.86 5.98 6.46 CO: Concentration, % dry cco, 7.43 8.33 8.46 8.08 pullffiircB T E c H N {cA L G rq * u ?o."ooo, HFSinclairwoodsCrossRefinins.Llc-westBountitul.ur Runl-RMData Source: Process Heater 20H3 Project No.: AST-2023-1660 Date:8/25123 Time Unit Stetus Or - Outlet COr - Outlet Y,dry Y"drl Valid Valid 8:20 8:21 8:22 8:23 8'_24 8:25 8:26 8:27 8:28 8:29 8:30 8:31 8:32 8:33 8:34 8:35 8:36 8:37 8:38 8:39 8:40 8:41 8:42 8:43 8:44 8:45 8:46 8.47 8:48 8:49 8:50 8:51 8:52 8:53 8:54 8:55 8:56 8:57 8:58 8:59 9:00 9:01 9:02 9:03 9:04 9:05 9:06 9:07 9:08 9:09 9:10 9:l I 9:12 9:13 9:14 9:15 9:16 9:17 9:18 9:19 9:20 9:21 9:22 112 of 201 7.14 7.18 7.15 7.15 7.13 7.t4 7.1 I 7.12 7.21 7.26 7.25 7.38 7.45 7 .41 7.45 7.39 7.40 1.45 7.45 7.42 7.4t 7.4t 7.40 7.39 7.42 '1.40 1.46 7.46 7.44 7.42 7.48 7.47 7.59 7.59 7.52 7.54 7.50 7.52 7,52 7.53 7.4t 7.38 7.29 7.31 7.33 7.33 7.33 7.26 7.27 7.28 7.20 7.35 7.39 7.39 7.43 7.64 7.67 7.70 7.62 7.71 7.65 7.61 7.58 7.72 7.69 7.71 7.71 7.73 7.72 7.72 7 .72 7 .67 7 .65 7.66 7 .54 7 .47 7.49 7.48 7 .51 7.50 7.48 7.49 7.50 7.50 7.s0 7.5t 7.52 7 .51 7.s2 7 .47 '7 .47 1.48 7.48 7 .45 7 .45 7.38 7.38 7 .44 7.43 7.46 7 .44 7,40 7.41 7.50 7.53 7.60 7.59 7.58 7.58 7.58 7.60 7.59 7.60 7.64 7.58 7.55 7.56 7.49 7.36 7.30 7.29 7.34 7.29 7.33 7.36 7.39 nnffirrce TECHNICAL GROL-'P Runl-RMData Location: HF Sinclair Woods Cross Refining. LLC - West Bountiful, UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Date:8,25123 Time Unit Ststus Oz - Outlet CO, - OutletY"dry Y"dry Valid Vdid 9.23 9:24 9:25 9:26 9:27 9:28 9:29 9:30 9:31 9:32 9:33 9:34 9:35 9:36 9:37 9:38 9:39 9:40 9:41 9:42 9:43 9:44 9:45 9:46 9:47 9:48 9:49 9:50 9:51 9:52 9:53 9'_54 9:55 9:56 9:57 9:58 9:59 10:00 l0:01 l0:02 l0:03 l0:04 l0:05 l0:06 l0:07 l0:08 l0:09 l 0:10 l0:ll l0:1 2 10: l3 l0: l4 l0:15 l0: l6 l0: l7 l0: l8 l0: l9 l0:20 10:21 l0:22 l0:23 l0:24 l0:25 1 l3 of20 I 7.60 7.61 7.65 7.61 7.68 7.65 7.75 7.83 7.90 7.89 7.82 7.86 7.',18 7.80 7.80 7.78 7.86 7,80 1.76 7.77 7.70 7.79 7.80 7.74 7.81 7.83 7.89 7.91 7.94 7.92 7.m 7.93 7.83 7.88 7.87 7.88 7.87 7.83 7.83 7.90 7.84 7.75 7.76 7.75 7.75 7.81 7.19 7.78 7.82 7.80 7.81 7.87 '1.82 7.78 '1.92 7.85 7.89 7.91 1 .9t 7.80 7.74 7 .78 7.78 7.38 7 .35 7.38 7 .3s 7 .36 7.29 7.22 7 .t6 7.16 7.23 7.24 1)1 7.28 7.29 7.29 7.23 7.26 7.28 7.28 7 .31 7.25 7.25 7.29 7.24 7.24 7.20 7. l8 7.17 7.18 7.20 7.18 7.23 7.21 7.21 7.21 7.20 7.20 7.20 7.19 7.27 7.30 7.26 7.26 7.25 7.23 7.25 7.26 7.25 7.24 7.23 7.20 7.24 7.29 7 .19 7.22 7.22 7.20 1 .19 1.24 7.27 7.27 7.28 N:ffirpe"r r c H N i c A L (3 R o o ?*"nrn, HF sinclair woods cross Refining, LLC - west Bountitul, ur Run 1- RM Data Source: Process Heater 20H3 Project No.: AST-2023-1660 Dile:8/25123 Time Unit Status Or - Outlet CO, - Outletn/"dry Y"dry Valid Valid l0:26 l0:27 l0:28 l0:29 l0:30 l0:31 l0:32 l0:33 l0:34 l0:35 l0:36 l0:37 l0:38 l0:39 l0:40 l0:41 l0:42 l0:43 l0:44 l0:45 l0:46 l0:47 l0:48 l0:49 l0:50 10:51 l0:52 l0:53 l0:54 l0:55 l0:56 l0:57 l0:58 l0:59 I l:00 I l:01 I l:02 I l:03 I l:04 I l:05 I l:06 I l:07 I 1:08 I l:09 l 1:10 ll:ll ll:12 I l:13 I l:14 I l:15 l l:16 I l:17 l l:18 ll:19 I l:20 I l:21 ll:22 ll:23 ll:24 ll:25 ll:26 ll:27 I l:28 I l4 of20 I 7.79 7.83 7.74 7.63 '1.69 7.s6 7.16 7.77 7.58 7.62 7.46 7.56 7.64 7.56 7 .61 7.61 7 .51 7.60 7.55 7.56 7 .51 7.48 7 .4'.1 7.48 7.43 7.38 7.36 7.50 7.42 7.42 7.s2 7.43 7.49 7 .4',1 7.28 '1.27 7.35 '1.3t 7 .35 '1.32 1.36 7.31 7.32 7.27 7.38 7 .50 7 .61 7.46 7.54 7.51 7.51 7.47 7.43 7.40 7.31 7.34 7.37 7.47 7.45 7.45 7.43 7.40 130 7.27 7.24 7.31 7 .37 7.35 7.43 7.30 7.31 7.43 7.40 7.51 7.44 1.39 '1.46 7.40 7 .41 7 .49 7 .41 7.4',1 7 .45 '1.48 7.51 7 .54 7.53 7 .55 7.57 7.59 7.5t 7.57 7.57 7.52 7 .59 1 .54 7 .56 7.68 7.7t 7.65 7.67 7.65 7.65 7.63 7.66 7.66 11i 7.65 I .)3 't.45 7.54 7.49 7.51 7.51 7.52 7 .57 '1.58 7.63 7.62 7 .59 7 .54 7.56 7.55 7.57 7 .59 '1.65 putffiircB TEC'-INiCAL GNOUP Runl-RMData Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Date:8125123 Time Unit Strftrs Or - Outlet COz - Outlet "hdry "hdry Valid Valid ll:29 I l:30 I l:31 ll:32 I l:33 l1:34 I l:35 I l:36 ll:37 1 l:38 I l:39 I l:40 I l:41 ll:42 I l:43 ll:44 I l:45 I 1:46 ll:47 I l:48 l1:49 1l:50 ll:51 ll:52 11:53 I 1:54 I l:55 I l:56 I l:57 I 1:58 I 1:59 l2:00 l2:01 l2:02 l2:03 l2:04 l2:05 l2:06 l2:07 l2:08 12:09 l2: l0 l2:11 12:12 l 2:13 12:14 12:15 12:16 12:17 l2: l8 12:19 l2:20 12:21 12:22 12:23 12:24 12:25 12:26 12:27 l2:28 12:29 l2:30 l2:31 ll5 of20l 7.40 7.45 7.46 7.40 7.38 7.30 7.43 7.51 7.55 7.53 7.48 7.48 7.41 7.43 7.43 7.58 7.51 '1.57 7.43 7.44 7 .53 7.62 7.54 7.64 7.59 7.62 7.57 7.61 7.59 't .55 7.40 7.52 7.49 7.62 7.60 7.67 7.59 7.55 7.49 7.67 7.67 7.66 7.66 7.62 7.66 7.70 7.37 7.28 7.45 7.30 7.28 7.34 7.45 7.35 7 .56 7.65 7.63 7.63 7.66 7.63 7.64 7.62 7.63 '1.60 7 _56 7.58 7.60 7.62 7.66 7.59 7.55 7.51 7.53 7.55 '1 .55 7.59 1.58 7 .59 7 .5t 7 .54 7.52 7 .61 7.60 7 .55 7 .47 7.52 7.47 7.50 7.46 7.48 7.46 '1.46 7.47 56 52 55 50 50 7.44 7.49 7.49 7.53 7.45 7.43 7.45 7.4s 7.48 7.41 7.41 7.63 7.70 7 .61 7.72 7.75 7.76 7.67 7.71 7.55 50 53 54 52 5l 7.49 7.49 7.46 AlmrEBrU*fihI ,(:AL (:ROtJP Locatioo, Source, Runl-RMData Project No.: AST-2023-1660 Date:8/25123 Time Unit Status Or - Outlet CO, - OutletY"dry Y"dry Valid Valid l2:32 l2:33 l2:34 l2:35 l2:36 12:37 l2:38 l2:39 l2:40 l2:41 l2:42 12.43 12:44 12.45 12:46 l2:47 l2:48 12.49 l2:50 7.64 7.53 7 .54 7 .55 7 .57 7.60 7.58 7 .59 7 .57 '1.65 7 .71 7.59 7 .59 7 .58 7.52 7.56 7.56 7.70 7.82 '7 .47 7 .54 7.54 '7.52 7 .49 7.46 7 .47 7.48 '1.50 7 .45 7.40 7.47 7.48 7.47 7.51 7.49 7.48 7.37 7.23 Prmmeter Uncorrected Run Average (Co5,) Cal Gas Concentration (Cp1) Pretest System Z€ro Response Posttest System Zero Response Average Zerc Response (Co) Pretest System Cal Response Posttest System Cal Response Average Cal Response (Cy) Corrected Run A Or - Outlet COr - Outlet 7 .56 7.46 t0.95 10.'14 0.lz 0.05 0.07 0.07 0.10 0.06 t0.95 10.76 10.88 10.74 10.92 10.75 7 _55 1.43 I l6 of20l auffirrce T s c f'|i\.t lcA L G R o o ?*"noo, HFsinclairwoodscrossRefinins.LLc-westBountitul.ur Run2-RMData Source: Process Heater 20H3 Projrct No.: AST-2023-1660 Datet 8/28-8/29123 Time Unit Strftrr Or - Outlet COr - Outleto/"dry "/'dry Valid Valid 22:58 22:59 23:00 23:01 23:02 23:03 23:04 23:05 23:06 23.07 23:08 23:09 23: l0 23:ll 23..t2 23: l3 23:14 23:15 23.16 23:17 23:18 23:19 23:20 23:21 2322 23:23 23:24 23:25 23:26 23:27 23:28 23:29 23:30 23:31 23:32 23:33 23:34 23:35 23:36 23:37 23:38 23:39 23:40 23.41 23:42 23:43 23:44 23:45 23:46 23:47 23:48 23.49 23:50 23:51 23:52 23:53 23:54 23:55 23:56 23:57 23:58 23:59 0:00 ll7 of20l 6.72 6.73 6.68 6.55 6.02 5.72 5.70 5.76 5.9 6.23 6.35 6.43 6.48 6.54 6.55 6.50 6.49 6.45 6.28 6.23 6.21 6.15 6. l0 6.06 6.01 5.97 5.97 5.90 5.89 5.85 5.83 5.88 5.87 5.81 5.95 6.01 5.99 5.94 6.05 6.00 6.08 6.07 6. l3 6. l0 6.t4 6. l3 6.1 I 6.1 I 6.08 6. l0 6.t2 6. l3 6.23 6.27 6.37 6.37 6.45 6.51 6.58 6.63 6.s9 6.59 6.s6 7 .51 7 .54 7 .54 7.65 8.10 8.36 8.37 8.3s 8.24 8.l l 8.04 8.01 8.00 7.96 7,96 7.98 7.99 8.01 8.tI 8.t5 8. l8 8.21 8.2s 8.28 8.32 8.34 8.34 8.36 8.39 8.41 8.44 8.41 8.41 8.45 8.39 8.36 8.38 8.41 8.34 8.37 8.34 8.33 8.31 8.30 8.28 8.29 8.32 8.30 8.32 8.32 8.29 8.30 8.25 8.22 8.t7 8. l6 Ll2 8.08 8.04 8.02 8.04 8.04 8.07 anl6rrce T E n F-'l N I c A L G fi * ' ?o."non, HF Sinclair woods Cross Refining, LLC - west Bountitul. ur Run2-RMData Source: Process Heats 20H3 Project No.: AST-2023-1660 Datez 8128-8129123 Time Unit Strtus O: - Outlet COr - Outlet Y"dry "/"dry Valid Valid 0:01 0:02 0:03 0:04 0:05 0:06 0:07 0:08 0:09 0:10 0:l I 0:12 0:13 0: l4 0:15 0:16 0:17 0:18 0:19 0:20 0:21 0:22 0:23 0:24 0:25 0:26 0:27 0:28 0:29 0:30 0:31 0:32 0:33 0:34 0:35 0:36 0:37 0:38 0:39 0:40 0:41 0:42 0:43 0:44 0:45 0:46 0.47 0:48 0.49 0:50 0:51 0:52 0:53 0:54 0:55 0:56 0:57 0:58 0:59 l:00 l:01 l:02 l:03 118 of20l 6.50 6.48 6.4t 6.28 6.20 6.07 6.05 5.99 6.05 5.99 5.96 5.98 6.00 5.94 5.95 5.90 5.89 5.80 5.69 5.64 5.70 5.73 5.69 5.60 5.61 5.67 s.62 5.56 5.56 5.51 5.46 5.54 s.84 5.92 5.91 5.85 5.7 5 5.67 5.57 5.71 5.96 5.98 5.96 5.87 5.90 5.88 5.89 5.87 5.88 5.93 5.90 s.92 5.85 5;t 5 5.69 5.72 s.70 5.66 5.69 5.7 4 5.78 5.84 s.84 8.09 8.r0 8.15 8.22 8.26 8.32 8.33 8.37 8.35 8.37 8.38 8.38 8.36 8.40 8.39 8.42 8.42 8.48 8.53 8.56 8.53 8.52 8.53 8.58 8.58 8.55 8.58 8.60 8.61 8.63 8.65 8.62 8.46 8.40 8.40 8.44 8.49 8.54 8.58 8.52 8.38 8.36 8.38 8.42 8.40 8.42 8.40 8.40 8.40 8.36 8.38 8.37 8.4t 8.47 8.49 8.47 8.49 8.50 8.s0 8.47 8.43 8.42 8.41 anIffiIEe TTCHNICAL GROUP Run2-RMData L*"tioo, Sor.cu, Prnienf Nn . AqT-r0r1-1660 Date: 8/28-8129123 Time Unit Status Oz - Outlet COr - OutletY"dry Y"dry Valid Valid l0 ll l2 l3 l4 l5 l6 l7 l:04 l:05 l:06 l:07 l:08 l:09 5.79 5.84 5.89 s.89 5.87 s.9l s.92 5.89 5.87 5.84 5.76 5.70 5.68 5.64 5.63 5.56 5.48 5.68 5.86 5.84 5.79 5.72 5.72 s.69 5.67 5.64 s.57 5.60 8.43 8.41 8.39 8.38 8.37 8.36 8.36 8.37 8.39 8.41 8.45 8.48 8.48 8.49 8.50 8.55 8.60 8.49 8.39 8.40 8.41 8.46 8.45 8.46 8.48 8.49 8.54 8.51 8.55 8.55 8.56 8.53 8.55 8.53 8.54 8.53 8.54 8.50 8.54 8.55 8.52 8.55 8.58 8.55 8.58 8.58 8.57 8.s8 8.60 8.60 8.58 8.52 8.54 8.57 8.58 8.49 8.53 8.49 8.53 8.52 8.52 8.61 8.59 1:18 1:19 1:20 l:21 l:22 l:23 l:24 l:25 l:26 27 28 29 30 3l 32 JJ 34 54 53 52 59 58 l:35 l:36 l:37 l:38 l:39 l:40 l:41 l:42 l:43 l:44 1:45 l:46 l:47 l:48 l:49 l:50 l:51 l:52 l:53 l:54 l:55 l:56 l:5'1 l:58 l:59 2:00 2:01 2:02 2:03 2:04 2:05 2:06 5.s7 5.s4 5.57 5.59 5.64 5.54 5.53 5.60 5.53 s.49 5.55 5.51 5.50 5.50 s.49 s.45 5.44 5.46 5.57 5.52 5.49 5.47 5.64 5.61 5.66 5.61 5.62 5.61 5.45 5.45 I l9 of201 Run2-RMDataan6rrceTrrHN{cAL GR ?o."tion,nrsi*rui.w*arc^.n Source: Process Heater 20H3 Project No.: AST-2023-1660 Datet 8128-8129123 O: - Outlet COr - Outlet Y"dry o/"dry Valid Valid Time Unit Status l0 2:14 2:15 2:16 2:17 2:18 2.19 2:20 2:21 2:22 2:23 2:24 2:25 2:26 2:27 2:28 2:29 2:30 2:31 2:32 2:33 2:34 2:35 2:36 2:31 2:38 2:39 2:40 2:41 2:42 2:43 2:44 2.45 2:46 2:47 2:07 2:08 2:09 5.42 5.33 s.40 5.37 5.32 5.42 5.31 5.30 5.27 5.25 5.31 5.33 5.30 5.39 5.32 5.22 5.29 5.23 5.31 5.31 5.30 5.27 5.22 5.24 5.31 5.21 5.2t 5.24 s.25 5.38 5.46 5.56 s.56 5.67 5.67 5.70 5.73 5.80 5.85 5.86 5.89 5.84 5.7 5 5.80 5.94 5.76 5.70 5.76 5.84 5.78 5.7 | 5.65 5.76 5.88 5.87 5.91 5.98 5.98 6.16 6.19 6.18 6.1I 6.03 8.61 8.66 8.63 8.64 8.68 8.63 8.67 8.69 8.69 8.70 8.68 8.67 8.69 8.64 8.66 8.70 8.68 8.72 8.68 8.67 8.68 8.70 8.72 8.71 8.66 8.70 8.71 8.71 8.71 8.64 8.60 8.55 8.55 8.50 8.49 8.47 8.46 8.42 8.40 8.39 8.38 8.40 8.45 8.42 8.38 8.60 8.64 8.56 8.48 8.50 8.52 8.53 8.43 8.34 8.34 8.32 8.28 8.30 8.21 8. 19 8.22 8.24 8.29 2:48 2:49 2:50 2:51 2:52 2:53 2:54 2'.55 2:56 2:57 2:58 2:59 3:00 3:01 3:02 3:03 3:04 3:05 3:06 3:07 3:08 3:09 l2O of 2Ol Run2-RMData TECHNICAI, GRGUP Location: HF Sinclair Woods Crcs Refinins. LLC - West Bountifirl. UT Sou"a", P*ject No., Da're: 8128-8,129/23 Or - Outlet CO, - Outlet '/. dry o/o dry Time Unlt Status 3:10 3;l I 3:12 6.06 6.2s 6.24 8.27 8.17 8.18 Or - Outlet COr- Outlet Uncorrccted Run Avenge (C.u) Cll Grs ConccDtratior (Cp1) Pretest Systcm Zero Response Posttsst System Zero Responsc Average Zero Rcsponse (Co) Pretest Systed C&l Response Po8ttcst System Cal Response Average Cal Responsc (Cy) 8.42 t0.74 0.07 0.09 0.08 10.87 10.78 10.83 8.33 5.82 10.95 0.02 0.02 0.02 10.87 10.85 10.86 5.86 l2l of201 nllffirrce TECilNI(}AL GROUP Run3-RMData Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, LrT Source: Process Heater 20H3 Project No.: 4ql?023-166q Datez 8129-tl30D3 Time Or - Outlet COr - Outlet Unit "h dry Status Valid o/o dry Valid 23:25 23:26 23:2'1 23:28 23:29 23:30 23:31 23:32 23:33 23:34 23:35 23:36 23:37 23:38 23:39 23:40 23:41 23:42 23:43 23:44 23:45 23:46 23:47 23:48 23:49 23:50 23:51 23:52 23:53 23:54 23:55 23:56 23:57 23:58 23:59 0:00 0:01 0:02 0:03 0:04 0:05 0:06 0:07 0:08 0:09 0:10 5.92 5.70 5.66 5.79 5.81 5.89 5.93 5.87 5.95 5.D 6.02 5.95 6.00 5.90 5.89 5.86 5.86 5.95 5.89 5.79 5.81 6.00 5.89 5.86 5.80 5.91 6.02 5.98 6.08 5.97 6.05 6.01 5.94 6.01 6. ls 6.37 6.26 6. l6 6.l l 6.04 5.96 5.98 6.01 6.0s 6.06 6.0'1 6.09 6,09 6.08 6.05 6.04 5.90 5.89 5.93 5.90 5.86 5.84 5.80 5.70 5.7s 5.69 5.69 5.69 8.44 8.56 8.56 8.50 8.50 8.46 8.44 8.48 8.42 8.41 8.39 8.43 8.40 8.47 8.48 8.49 8.48 8.44 8.4'l 8.53 8.50 8.39 8.45 8.48 8.51 8_45 8.38 8.41 8.35 8.41 8.38 8.40 8.43 8.40 8.32 8.20 8.27 8.31 8.35 8.37 8.41 8.41 8.40 8.37 8.35 8.35 8.34 8.35 8.36 8.38 8.39 8.47 8.48 8.46 8.47 8.49 8.50 8.50 8.56 8.52 8.s7 8.57 8.58 0:11 0:12 0:13 0:14 0:15 0:16 0:17 0:18 0:19 0:20 0:21 0:22 0:23 0:24 0:25 0:26 0:27 122 of 201 E Run 3 - RM DataAIATGe T E c l-"1 hl I c A L G H ?ocation: HFsinclairwoodscrossRefining,LLC-westBountitul,ur Sou.aa, Project No.: AST-2023-1660 Date: 8/29-8130123 Or - Outlet COr - Outlel "hdry o/"dry Time Unit Status Valid 0:28 0:29 0:30 0:31 0:32 0:33 0:34 0:35 0:36 0:37 0:38 0:39 0:40 0:41 0:42 0:43 0:44 0:45 0:46 0:47 0:48 0:49 0:50 0:51 0:52 0:53 0:54 0:55 0:56 0:57 0:58 0:59 l:00 l:01 l:02 l:03 l:04 l:05 l:06 l:07 l:08 l:09 l:10 l:l I t2 t3 l4 l5 5.76 5.7 5 5.71 s.64 5.66 5.74 5.7 5 5.80 5.83 5.77 5.7 5 5.80 5.77 5.79 5.80 5.77 5.78 5.82 5.82 5.81 5.78 s.80 5.80 s.78 5.79 s.82 5.77 5.7 5 5.78 5.76 5.81 5.75 5.88 5.95 5.92 5.88 5.87 5.86 5.81 5.83 5.81 5.77 5.70 5.70 5.69 5.67 5.67 s.73 5.77 5.79 5.81 5.91 5.94 5.96 5.96 5.94 5.94 5.90 5.86 5.93 s.94 s.92 5.96 8.53 8.55 8.57 8.60 8.59 8.s4 8.55 8.51 8.50 8.54 8.53 8.52 8.53 8.51 8.50 8.51 8.50 8.48 8.47 8.49 8.51 8.51 8.53 8.54 8.s3 5l 54 55 53 54 52 l: l6 l:17 l:18 l:19 l:20 l:21 l:22 l:23 l:24 l:25 l:26 l:27 l:28 l:29 l:30 8.54 8.48 8.44 8.46 8.48 8.48 8.49 8.51 8.51 8.52 8.56 8.58 8.58 8.59 8.59 8.60 8.s6 8.51 8.51 8.49 8.44 8.41 8.40 8.42 8.41 8.40 8.42 8.44 8.41 8.41 8.43 8.42 123 of20l E Run 3 - RM DataAlArEe T EC l-{ N I cAL G R ?*"tiro, Sortau, Project No.: AST-2023-1660 D*e: 8/29-8130/23 Or - Outlet COr - Outlet "/"dry Y"dry Valid Valid Time Unit Status l:31 l:32 l:33 l:34 l:35 l:36 l:37 l:38 l:39 l:40 l:41 l:42 l:43 l:44 l:45 l:46 l:47 l:48 l:49 50 5l 52 53 54 5s 56 57 58 59 5.92 5.89 5.94 5.95 5.87 5.81 5.84 5.83 5.83 5.7 5 5.78 5.76 5.79 s.80 5.83 5.81 5.80 5.85 s.81 5.85 5.81 5.84 5.80 5.80 5.8t 5.86 5.82 5.79 5.75 5.77 5.83 5.90 6.24 6.28 6.35 6.35 6.34 6.29 6.17 6.07 6.06 6.09 6.03 6.03 6.26 6.46 6.51 6.45 6.44 6.35 6.36 6.27 6. l0 6.02 5.82 5.84 5.90 5.88 5.96 6.18 6.18 6.20 621 8.44 8.46 8.41 8.42 8.46 8.50 8.48 8.46 8.46 8.50 8.51 8.50 8.48 8.48 8.46 8.47 8.47 8.47 8.44 8.46 8.49 8.46 8.49 8.48 8.47 8_48 8.49 8.49 8.5t 8.51 8.48 8.42 8. l4 8.07 8.05 8.03 8.06 8.08 8,20 8.30 8.32 8.29 8.32 8.32 8. l6 8,01 7.98 8.00 8.00 8.05 8.05 8.14 8.28 8.35 8.49 8_47 8.43 8.42 8.36 8. l9 8. l8 8. l6 8. l4 2:00 2:01 2:02 2:03 2:04 2:05 2:06 2:07 2:08 2:09 2:10 2:l I 2:12 2:13 2:14 2:15 2:16 2:17 2:18 2:19 2:20 2:21 2:22 2:23 2:24 2:25 2:26 2:27 2:28 2:29 2:30 2:31 2:32 2:33 124 of201 Al6rrce TTC!.1NICAL (3HOUP Run3-RMData Locrtion: HF Sinclair Wmds Crms Refinins. LLC - West Bomtiful. t T Source: Prmess Heater 20H3 Project No.: AST-2023-1660 D*e: 8129-813O/23 Time Unit Strtus Or - Outlet COr - Outlet Y"dry o/"dry Valid Valid 2:34 2:35 2:36 2:37 2:38 2:39 2:40 2:41 2:42 2:43 2:44 2:45 2:46 2:4'l 2:48 2:49 2:50 2:51 2:52 2:53 2:54 2:55 2:56 2:57 2:58 2:59 3:00 3:01 3:02 3:03 3:04 3:05 3:06 3'.07 3:08 3:09 3:10 3:l I 3:12 3:13 3:14 3: l5 3:16 3:17 3:18 3:19 3:20 3:21 3:22 3:23 3:24 3:25 3:26 3:27 3:28 3:29 3:30 3:31 3:32 3:33 3:34 3:35 3:36 125 of 201 6.27 6.24 6. l0 5.96 5.87 6.13 6.1 I 5.91 6.00 5.98 6.06 5.93 6.0t 6.04 6.0s 6.06 6.13 6.05 6.03 5.97 s.93 5.87 5.81 5.86 5.84 5.81 5.79 5.86 5.88 5.82 5.89 5.88 5.86 5.87 5.91 5.88 5.94 5.95 5.98 6.00 5.98 5.98 6.00 5.97 6.01 5.99 5,96 5.93 6.01 6.03 6.00 6.01 6.00 5.98 6.00 5.96 5.98 6.04 6.00 6.07 6.02 5.9',1 596 8.1 I 8. l4 8.26 8.35 8.42 8.30 8.29 8.40 8.37 8.37 8.34 8.40 8.36 8.34 8.33 8.32 8.30 8.34 8.35 8.38 8.38 8.41 8.46 8.43 8.44 8.46 8.46 8.43 8.43 8.45 8.42 8.43 8.43 8.42 8.40 8.40 8.39 8.38 8.36 8.36 8.36 8.37 8.36 8.36 8.34 8.34 8.36 8.38 8.35 8.34 8.34 8.34 8.34 8.36 8.35 8_37 8.36 8.35 8.38 8.34 8.36 8.38 838 anlffirrce T E c H N icAL G $tr c! ti 13 mdscrossRefinins.LlC-westBountitul.UT Run3-RMData Source: Process Heater 20H3 Project No.: AST-2023-1660 Date: 8/29-8/30/23 Time Unit Status 0: - Outlet CO: - Outlet "hdry "hdryValid Valid 3:37 3:38 3:39 3:40 3:41 3:42 3:43 3.44 3:45 3'.46 3:47 3:48 3:49 3:50 5.88 5.90 5.86 5.86 5.83 5.95 5.90 5.91 5.89 5.88 5.95 5.9t 5.81 5.84 5.93 10.95 0.06 0.04 0.05 10.79 10.85 10.82 s.98 8.43 8.41 8.43 8.43 8.44 8.39 8.41 8.41 8.43 8.43 8.4r 8.42 8.47 8.46 COr - Outlet Uncorrected Run Average (qb,) Cal Gas Concentration (Cm) Pretest System Zcro Response Posttest System Zero Response Avcroge Zero Response (Co) Pretest System Cal Response Posttest Systcm Csl Response Avcrage Cal Response (CM) orrected Run 8.41 t0.74 0.06 0.05 0.06 10.66 10.66 t0.66 8.46 126 of20l 127 of20l $3 eurofins Environment Testing ANALYTICAL REPORT fJ} PREPARED FOR Attn: Austin Abranovic Alliance Source Testing, LLC 214 Central Circle SW Decatur, Alabama 35603 Generated 101212023 9:10:30AM Revision 1 JOB DESCRIPTION HF Sinclair Woods - CTM-039 JOB NUMBER 140-33467-1 This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager. Eurcfins Knoxville is a laboratory within TestAmeica Laboratoies, lnc., a company within Eurofins Environment Testing Group of Companies Page 2 of 35 129 of 2Ol €*1.{ "ga"t f,ffi 1".0,,, o,.o o* Arth"rk"d f"-"b"." by Revision 1 Courtney Adkins, Project Manager ll Courtney.Adkins(Aet.eurofi nsus.com (865)291-301 I 101212023 (Rev. 1) Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM{39 Laboratory Job lD: 140-33467-1 Table of GontentsCoverPage ...... 1 TableofContents... 3 .Definitions/Glossary 4 Case Narrative 5 Detection Summary 7 Client Sample Results 9 Default Detection Limits 24 QC Association Summary 25 Lab Chronicle 26 CertificationSummary.. 29 Method Summary 30 Sample Summary 31 ChainofCustody... 32 ReceiptChecklists... 35 F:t-!:eW E Page 3 of 35 130 of20l Eurofins Knoxville 1012t2023 (Rev. 1) Deflnitions/Glossary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. n Listed under the "D" column to designate that the result is reported on a dry weight basis o/oR Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Enor Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, lN lndicates a Dilution, Re-analysis, Re-e)draction, or additional lnitial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level" MDA Minimum DetectableActivity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MOL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative i Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too NumerousTo Count Eurofins Knoxville Page 4 of 35 101212023 (Rev. 1) 131 of20l Case Narrative Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Job lD: 140-33467-1 Laboratory: Eurofins Knoxville Narrative H Job Narrative 140-33467-1 Revision Notes This report was revised to include initial sample volumes. Receipt The samples were received on 911212023 9:30 AM. Unless otherwise noted below, the samples arrived in good condition, and where required, properly preserved and on ice. The temperature of the cooler at receipt was 21.9o C. Receipt Exceptions The container label for the following samples did not match the information listed on the Chain-of-Custody (COC): 20H3 - >PM10 ACETONE RTNSE - RUN 1 (140-33467-1),20H3 - PM10-PM2.5ACETONE RINSE - RUN 1 (140-33467-2),20H3 - <PM2.5 DIWATER RINSE - RUN 1 (140-33467-3),20H3 - <PM2.5ACETONE RINSE - RUN 1 (140-334674) and 20H3 - <PM2.5 FILTER - 142MM - RUN'l (140-33467-5). COC list collection date as 8-28-23,labels list 8-25-23,8-27-23,8-28-23- Logged per COC. The Field Samplerwas not listed on the Chain of Custody. The Chain-of-Custody (COC) was incomplete as received and/or improperly completed. Sample matrix not listed. General Chemistry Particulate Mafter by CTM-O39-Particulate Matter was determined for samples derived from Conditional Test Method 039 sampling trains. The filter samples were dried in a desiccator over anhydrous calcium sulfate for a minimum of 24 hours. Acetone rinses were evaporated in TeflonrM beaker liners in a hood at ambient temperature instead of aluminum pans in order to avoid possible reactions between acidic stack contents and the aluminum pans. The aqueous impinger catch was simmered to less than 10 mL, and then evaporated to dryness in an unheated forced draft oven. Data are reported to 0.01 mg as specified in the cited method. The reporting limit was lowered to the readability of the balance used (0.0'l mg). Method CTM 039: A deviation from the Standard Operating Procedure (SOP) occurred. Details are as follows: Beaker liners were weighed three times and the average of all three was used as the liner tare weight per PM and consultant request. Method CTM 039: Samples 20H3 - <PM2.5 FILTER - 142MM - RUN 't (140-33467-5), 20H3 - >PM10 ACETONE RINSE - RUN 3 ('140-33467-11) and 20H3 - <PM2.5 ACETONE RINSE - RUN 3 (140-33467-14) did not achieve constant weight as described in SOP KNOX-WC-0006 section 11.12.6 the last two gross weights were averaged and used as final sample weight. MethodCTM039: Samples20H3-<PM2.5FILTER-142MM-RUN1(140-33467-5),20H3-<PM2.5FILTER-142MM-RUN2 (140-33467-10) and 20H3 - <PM2.5 FILTER - 142MM - RUN 3 ('t40-33467-15) arrived with significant damage to the filters (tares, frayed edges, missing pieces). The analyst was careful to get all loose filter pieces weighed with the sample. However the damage may reflect a low bias in the data. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Eurofins Knoxville Page 5 of 35 101212023 (Rev. 1) 132 of 201 Job 140-33467: Sample Volumes Sample lD Volume (mL) I-40-33467-A-1 58.2 L40-33467-A-2 47.3 L40-33467-A-3 160.9 L40-33467-A4 193.9 L40-33467-A-6 65.4 L40-33467-A-7 88.3 140-33457-A-8 737.7 L40-33467-A-9 164.0 140-33467-A-11 60.4 L40-33467-A-Lz 53.7 740-33467-A-L3 166.8 140-33467-A-L4 207.3 w ',1::::,. ..' .:: Page 6 of 35 1Ol2l2O23 (Rev. 1) 133 of20l Detection Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Client Sample lD: 20H3 - >PM10 ACETONE RINSE - RUN 1 Lab Sample lD: 140-33467-1 I Analyte ] P*ti"rrrt" ltr"tt", Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample 1 CTM 039 Job lD: 140-33467-1 0.445 Client Sample ID: 20H3 - PMl0-PM2.5 ACETONE RINSE - RUN 1 Lab Sample lD: 140-33467-2 I Analyte Particulate Matter t.-... Result Oualifier RL MDL Unit Dil Fac D Method Prep Type 0.230 1 cTM 0390.0100 0.0100 mg/sample Client Sample lD: 20H3 - <PM2.5 Dl WATER RINSE - RUN 1 Lab Sample lD: 140-33467-3 I anatyte I ParticLrlate Matter Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample1.29 1 cTM 039 CIient Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 1 Lab Sample lD: 140-33467-4 l ] Analyte ] P*ti""l"rte tutatier Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 175 0.0100 0.0100 mg/sample 1 CTM 039 Total/NA Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN 1 Lab Sample lD: 140-33467-5 fenaryte L Particulate Matter Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample 1 cTM 039 Client Sample lD: 20H3 - >PM10 ACETONE RINSE - RUN 2 Lab Sample lD: 140-33467-6 I I Analyte I P*ti."rlrt. Mrtt r Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample 1 CTM 039 0.750 0.280 Client Sample lD: 20H3 - PM10-PM2.5 ACETONE RINSE - RUN 2 Lab Sample lD: 140-33467-7 [ - No Detections. Client Sample lD: 20H3 - <PM2.5 Dl WATER RINSE - RUN 2 Lab Sample lD: 140-33467-8 -i Analyte I Particulate Matter 1...... Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample Client Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 2 Lab Sample lD: 140-33467-9 l-Analyte Parti.\rlate tvlatterL Result Qualifier RL MDL Dil Fac D Method Prep Type 1.33 0.0100 0.0100 mg/sample Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN 2 Lab Sample lD: 140-33467-10 I Analyte I P*t-rrrt rrrrtt*L Client Sample lD: 20H3 - >PM10 ACETONE RINSE - RUN 3 Lab Sample lD:140-33467-11 Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Particulate Matter 0.0100 0.0100 0.0100 mg/sample 1 CTM 039 Total/NA 0.370 1 cTM 039 1 CTM 039 Result Qualifier RL MDL Unit Dil Fac D Method Prep Type Page 7 of 35 134 of20l Eurofins Knoxville 1Ol2l2O23 (Rev. 1) This Detection Summary does not include radiochemical test results. Detection Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample !D: 20H3 - PMl0-PM2.5 ACETONE RINSE - RUN 3 Lab Sample lD: 140-33467-12 [' No Deteaions Client Sampte lD: 20H3 - <PM2.5 Dl WATER RINSE - RUN 3 Lab Sample lD: 140-33467-13 a I Analyte Particulate Matter L 0.0100 0.0100 mg/sample Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.840 1 CTM 039 Client Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 3 Lab Sample lD: 140-33467-14 Particulate Matter Result Oualifier RL MDL Unit Dil Fac D Method Prep Type Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN 3 Lab Sample lD: 140-33467-15 fanalyte I Partrcl,late l,/tatter Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample Eurofins Knoxville 101212023 (Rev. 1) 0.650 1 CTM 039 This Detection Summary does not include radiochemical test results Page 8 of 35 135 of20l Client Sample Results Client Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: '140-334167-1 Client Sample ID: 20H3 - >PMl0 ACETONE RINSE - RUN 1 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample lD: 140-33467-1 Matrix: Air General Chemistry Analyte Result Qualifier D Prepared Analyzed Dil FacMDL Unlt Partlculate Matter (EPA CTltlI 039)0.0100 0.0100 mg/sample Eurofins Knoxville 10m2023 (Rev. 1) L?11)& l'ff r ;:r:! lil,,1;4 Page 9 of 35 135 of20l Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample !D: 20H3 - PMl0-PM2.5 ACETONE RINSE - RUN 1 Date Collected: 08/28/23 00:00 Date Received: 09/1223 09:30 Sample Container: Clear Glass 500mL - unpreserued Lab Sample lD: 140-33467-2 Matrix: Air General Chemlstry Analyte Result Qualifier MDL Unit D Prepared Analyzed Particulate Matter (EPA CTM 039) Dll Fac 10.0100 0.0100 mg/sample Ogl20l23 10:23 Eurofins Knoxville 101212023 (Rev.1) iill(irirlilii: Page 10 of35 137 of20l Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF SinclairWoods - CTM{39 Job lD: '140-33467-1 Client Sample ID: 20H3 - <PM2.5 DIWATER RINSE - RUN 1 Date Collected: 08/28/23 00:00 Date Received: 09/1?23 09:30 Samole Container: Clear Glass 500mL - unoreserved Lab Sample lD: 140-33467-g Matrix: Air General Chemistry Analyte Result Ouallfler MDL Unit D Prepared rercffi€mmM trDll Fac Particulate Matter (EPA CTM 039)0.0100 mg/sample O9l2Ol23 10:23 Eurofins Knoxville 1Ol2l2O23 (Rev.1)Page 11 of35 138 of201 Client Sample Results i1.l{.!j:*: :$eg. gi; -Wiin:'i: Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Glient Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 1 Date Collected: 08/28123 00:00 DaG Received: 09/1 2/23 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample lD: 140-33467-4 Matrix: Air GeneralChemistry Analyte Particulate Matter (EPA CTM 039) ffi ffi# tr r":i ::'t":;::a ,lr i',:. ,li::i:{} :t!', 1*:!i-. E. 1.78 Result Qualifier 0.0100 0.0100 mg/sample MDL Unit D Prepared Analyzed Dil Fac 0912012310:23 Eurofins Knoxville 1Ont2O23 (Rev.1)Page '12 of 35 139 of20l Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair \A/oods - CTM-039 Job lD: 14U33/,67-1 Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN I Date Collected: 08/28123 00:00 Date Received: 09/1 223 09:30 Samole C.ontainer: Petri/Filter Lab Sample lD: {40-33467-5 Matrix: Air GeneralChemistry Result Qualifier MDL Unlt D Prepared Analyzed ost2u2310'.n Dil Fac Partlculate Matter (EPA CTM 039)0.750 0.0100 0.0100 mg/sample Eurofins Knoxville 101212A23 (Rev.1) tr '';.i.il {i' ,tW #+r$f.;i *:... 3, ;$s..qt Page 13 of35 140 of20l Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample lD: 20H3 - >PMl0 ACETONE RINSE - RUN 2 Date Collected: 08/28/23 00:00 Date Received: 09/1 2/23 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample lD: {40-33467-6 Matrix: Air General Chemistry Particulate Matter (EPA CTM 039)0.280 Result Qualifier MDL 0-ol oo O Prepared Analyzed o9t20t2310'.23 Dll Fac 0.0100 Page 14 of35 141 of20l Eurofins Knoxville 1012t2023 (Rev. 1) Glient Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: '140-33467-1 Client Sample lD: 20H3 - PMl0-PM2.5 ACETONE RINSE - RUN 2 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreseryed Lab Sample lD: 140-33467-7 Matrix: Air GeneralChemistry Analyte Result Ouallfler MDL Unit D Prepared Particulate Matter (EPA CTM 039)0.0100 0.0100 mg/sample ogl20l23 10:23 Eurofins Knoxville 101212023 (Rev.1) ..rir ttll'lr 1 1g ": i*6i,ig Page 15 of35 142 of 201 CIient Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 14443467-1 Client Sample lD: 20H3 - <PM2.5 Dl WATER RINSE - RUN 2 Date Collected: 08/28123 00:00 Date Received: 09/1 223 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample lD: 140-33467-8 Matrix: Air Partlculate Mafter (EPA CTM 039) General Chemistry Analyte Result Quallffer ffi*Mffi^=g Eurofins Knoxville 101212023 (Rev.1) MDL o.oloo O P.epared ':rlti.1:.altaata 'l)lll , l!,|'ri r' r'..rtt:: M'€ilslI {ls , lK *s#it,i * Sr,1 Page 16 of35 143 of201 Client Sample Results Client Alliance Sourc,e Testing, LLC ProjecUSite: HF SinclairWoods - CTM-039 Job lD: 14043/,67-1 Client Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 2 Date Collected: 08128/23 00:00 Date Received: 09/1?23 09:30 Sample Container: Clear GIass 500mL - unpreserved Lab Sample ID: 140-33467-9 Matrix: Air General Chemistry Analyte Partlculato Matter (EPA CTil 039) 1.33 Result Quallfier RL l,lDL Unit D Prepared Analyzed Dll Fac :l'iiil,:atli: tr0.0100 0.0100 mg/sample ogl20l23 10:23 1 Eurofins Knoxville 1Al2t2O23 (Rev. 1) :?t;i'l, Page 17 of35 144 of201 Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33r',67-'l Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN 2 Date Collected: 08/28123 00:00 Date Received: 09/12123 09:30 Sample Container: Petri/Filter Lab Sample lD: 140-33467-10 Matrix: Air General Chemistry Analyte Partlculate Matter (EPA CTM 039) ,.4 . i..i:a:a f;ffiffi-ffiffisW tr ,,,,,, ,,ll:.,' .:l 'i !P!a' ,.:, 1!., &it,96 -' -ii-:l Dil Fac 1 Result Qualifier 1.00 RL MDL 0.0100 0.0100 mg/sample D Prepared Analyzed o9120t2310'.23 Page 18 of 35 145 of20l Eurofins Knoxville 1Ol2l2O23 (Rev.1) Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Glient Sample lD: 20H3 - >PMl0 ACETONE RINSE - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/12123 09:30 Samole Container: Clear Glass 500mL - unpreserved Lab Sample lD: 140-33467-11 Matrix: Air General Chemistry Analyte Result Qualifier MDL Unlt D Prepared Analyzed Dil Fac Partlculate Mafter (EPA CTM 039)0.0100 0.0100 mg/sample ogl2ol2310:29 Eurofins Knoxville 1012n023 (Rev.'l) ffiem tr .,,,,,,,1.: lll{iillliilliri* . ,:-iitaj ill!$E!!rds*f rrg; iSLrffi Page 19 of35 146 of201 Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF SinclairWoods - CTM-039 Job lD: 140-33467-1 Client Sample lD: 20H3 - PMl0-PM2.5 ACETONE RINSE - RUN 3 Date Collected: 08130/23 00:00 Date Receivedt 09112123 09:30 Sample Container: Clear Glass 500mL - unpreserued Lab Sample lD: 140-33467-12 Matrix: Air General Chemistry Result Qualifter MDL Unit D Prepared Dil Fac 1Particulate Mafter (EPA CTM 039)0.0100 0.0100 mg/sample Ogl20l23 10:29 Eurofins Knoxville 101212023 (Rev. 1) ...:; -:.. :aL::: ryffiGs &t! tr x.ii, ::*,,'f' shffi&$':a a,' Page 20 of 35 147 of20l Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample lD: 20H3 - <PM2.5 DIWATER RINSE - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09112123 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample ID: 140-33467-13 Matrix: Air Particulate Matter (EPA CTill 039) General Chemistry Analyte Result Quallfier O Prepared Analyzed o9t2u23 10'.n Dll Fac Eurofins Knoxville 101212023 (Rev. 1) RL ooloo MDL Unit 0.0100 mg/sample Me6ru# W! tr :'l;"*. * t-"? Page21 of35 148 of20l Glient Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/12!123 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample !D: 140-33467-14 Matrix: Air feenerat Chemistry I Analyte I Particnlato Matter (EP,Particulate Matter (EPA CTM 039) Result Qualifier moL 0-0100 D Prepared Oll Fac 1 ffi ffi[ tr -Fl:l{li t':s&r:,W; *ii.$is'r S'ffi: 0.0'100 Page 22 of 35 149 of20l O9l2Ot23 1A:29 Eurofins Knoxville 1Ot2t2O23 (Rev.1) Client Sample Results Clienl Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Glient Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/12123 09:30 Sample Container: Petri/Filter Lab Sample lD: 140-33467-15 Matrix: Air General Chemistry Analyte Result Oualifier MDL Unit D Prepared Dil Fac ffi#t trParticulate Matter (EPA CTM 039)0.0100 0.0100 mg/sample Ogl20l23 10:23 Eurofins Knoxville 1Ol2t2O23 (Rev.1) rl,s*qutll,'r:, g1 ;t!$. r 3, Page 23 of 35 150 of20l Default Detection Limits Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 GeneralChemistry MDL Unitsf-Analyte I FaacuratelfreEer ME}wx ff&ilIlm E t$j'a -!i.t 0.0100 mg/sample Page 24 of 35 l5l of20l Eurofins Knoxville 101212023 (Rev. 1) QC Association Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 General Chemistry Analysis Batch: 77958 Lab Sample lD Client Sample lD Prep Type 140-33467-1 20H3 - >PM10 ACETONE RINSE - RUN 1 TotayNA 140-33467-2 140-33467-3 140-334674 140-33467-5 1 40-33467-6 140-33467-7 140-33467-8 't40-33467-9 't40-33467-10 140-33467-11 140-33467-12 140-33467-13 't40-33467-14 140-33467-15 Method cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 Prep Batch Eurofins Knoxville 101212023 (Rev. 1) Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air 20H3 - PM10-PM2.5 ACETONE RINSE - RUN 1 TotaUNA 20H3 - <PM2.5 Dl WATER RINSE - RUN 1 Total/NA 2OH3 - <PM2.5 ACETONE RINSE - RUN 1 TOTAI/NA 2OH3 . <PM2.5 FILTER - 142MM - RUN 1 TotaUNA 20H3 - >PM10 ACETONE RINSE - RUN 2 Total/NA 20H3 - PM10-PM2.5 ACETONE RINSE - RUN 2 Total/NA 20H3. <PM2.5 DI WATER RINSE. RUN 2 TotaI/NA 20H3. <PM2.5 ACETONE RINSE - RUN 2 TotaI/NA 20H3 - <PM2.5 FILTER - 142MM - RUN 2 TotaUNA 20H3 - >PM10 ACETONE RINSE - RUN 3 TotayNA 20H3. PMlO-PM2.5 ACETONE RINSE. RUN 3 TOTAI/NA 20H3 - <PM2.5 Dl WATER RINSE - RUN 3 TotaUNA 20H3 - <PM2.5 ACETONE RINSE - RUN 3 Total/NA 20H3 - <PM2.5 FILTER - 142MM - RUN 3 Total/NA Page 25 of 35 152 of 201 Lab Chronicle Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample lD: 20H3 - >PM10 ACETONE RINSE - RUN 1 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-1 Matrix: Air Batch Batch Dil lnitial Final Batch Run Factor Amount Amount Number Prepared or Analyzed Ogl2ol23 1O:23 Analyst LabPrep Type Type Method Analysis CTM 039 lnstrument lD: NOEQUIP EET KNX Client Sample lD: 20H3 - PMl0-PM2.5 ACETONE RINSE - RUN 1 Date Collected: 08/28/23 00:00 Date Received: 09112123 09:30 Lab Sample lD: 140-33467-2 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Oil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Osl20l23 1O:23 Analyst Lab 1 EET KNX Client Sample lD: 20H3 - <PM2.5 Dl WATER RINSE - RUN 1 Date Collected: 08/28123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-3 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Amount Number Prepared orAnalyzed Ogl2ol23 10:23 Analyst Lab 1 EET KNX Glient Sample ID: 20H3 - <PM2.5 ACETONE RINSE - RUN 1 Date Collected: 08/28/23 00:00 Date Received: 09112123 09:30 Lab Sample lD: 140-33467-4 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Ogl2ol23 1O:23 Analyst Lab 1 EET KNX Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN I Date Collected: 08/28123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-5 Matrix: Air Prep Type Batch Type Batch Method Run Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Ogl2ol23 10:23 Analyst Lab Analysis Cftl 039 lnstrument lD: NOEQUIP EET KNX Client Sample lD: 20H3 - >PMl0 ACETONE RINSE - RUN 2 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-G Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Amount Batch Prepared Number or Analyzed Analyst Lab 09120123 10:23 SJF EET KNX1 Page 26 of 35 t53 of20l Eurofins Knoxville 101212023 (Rev. 1) Lab Chronicle Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample !D: 20H3 - PM10-PM2.5 ACETONE RINSE - RUN 2 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-7 Matrix: Air | ,,"o rrr"l'*Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Dil lnitial Factor Amount Final Batch Prepared Amount Number orAnalyzed 1 Analyst Lab o9l2ol23 10:23 SJF EET KNX Client Sample lD: 20H3 - <PM2.5 Dl WATER RINSE - RUN 2 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-8 Matrix: Air tr Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Prepared Amount Number or Analyzed Analyst Lab Ogl2ol23 10:23 SJF EET KNX Client Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 2 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-9 Matrix: Air Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Analyst Ogl2ol23 10:23 SJF EET KNX Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN 2 Date Collected: 08/28/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-10 Matrix: Air | ,,"o t o" l'"-A Batch Bakh Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Dil lnitial Final Batch Factor Amount Amount Number 1 Prepared or Analyzed Ogl2ol23 1O:23 Analyst Lab EET KNX Client Sample lD: 20H3 - >PMl0 ACETONE RINSE - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-11 Matrix: Air Batch Batch Dil lnitial Final Batch Run Factor Amount Amount Number Prepared or Analyzed 09120123 10:29 Analyst LabPrep Type Type Method Analysis CTM 039 lnstrument lD: NOEQUIP EET KNX Client Sample lD: 20H3 - PMI0-PM2.5 ACETONE RINSE - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-12 Matrix: Air Prep Type 1 Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Dll lnitial Factor Amount Final Batch Amount Number Prepared orAnalyzed Ogl2ol23 1O:29 Analyst Lab EET KNX Eurofins Knoxville 1Ol2l2O23 (Rev. 1)Page 27 of 35 154 of20l Lab Chronicle Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Client Sample lD: 20H3 - <PM2.5 Dl WATER RINSE - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/1 2/23 09:30 Lab Sample lD: f 40-33467-13 Matrix: Air fr,"o rro" lur*- Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed ognom 1t2g Analyst Lab 1 EET KNX Client Sample lD: 20H3 - <PM2.5 ACETONE RINSE - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-14 Matrix: Air Prep Type Batch Batch Type illethod Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Prepared Amount Number or Analyzed Analyst Ogl2ol23 10:29 SJF EET KNX Client Sample lD: 20H3 - <PM2.5 FILTER - 142MM - RUN 3 Date Collected: 08/30/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33467-15 Matrix: Air Batch Batch Dil Initial Factor AmountType Method Analysis CTM 039 lnstrument lD: NOEOUIP Laboratory References: EET KNX = Eurofins Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 Page 28 of 35 155 of20l Analyst Lab Ogl2ol23 10:23 SJF EET KNX Final Batch Prepared Amount Number orAnalyzed 1 Eurofins Knoxville 101212023 (Rev. 1) Accreditation/Certification Sum mary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Laboratory: Eurofins Knoxville All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report Authority Program ldentificationNumber ExpirationDate ANAB ANAB ANAB Arkansas DEQ Colorado Connecticut Florida Georgia (DW) Hawaii Kansas Kentucky (DW Louisiana (All) Louisiana (DW) Maryland Michigan Nevada New Hampshire New Jersey NewYork North Carolina (DW North Carolina (\ A //SW Oklahoma Oregon Pennsylvania Tennessee Texas US Fish & Wildlife USDA Utah Virginia Washington West Virginia (DW West Virginia DEP Wsconsin AFCEE Dept. of Defense ELAP Dept. of Energy lso/tEc 1702s State State State NELAP State State NELAP State NELAP State State State State NELAP NELAP NELAP State State State NELAP NELAP State NELAP US Federal Programs US Federal Programs NELAP NELAP State State State State N/A L2311 L2311.01 L2311 88-0688 TNo0009 PH4223 E87177 906 NA E-1 0349 901 01 83979 LAO19 277 9933 TN00009 2999 TNOOl 10741 21705 64 9415 TNl0189 68-00576 02014 T104704340-2344 058448 525-22-279-18762 TN00009 460176 c593 9955C 345 998044300 02-13-25 02-13-25 02-13-25 06-16-24 02-29-24 09-30-23 o6-30-24 07-27-25 07-27-24 10-31-23 12-31-23 06-go-24 12-31-23 03-31-24 07-27-25 07-31-24 01-17-24 07-01-24 o3-3'.t-24 07-31-24 12-31-23 't2-31-23 01-01-24 12-01-23 07-27-25 08-31-24 07-31-24 1 0-06-25 07-31-24 09-14-24 01-19-24 12-31-23 04-30-24 08-31-24 Page 29 of 35 156 of20l Eurofins Knoxville 10t212023 (Rev. 1) Method Summary Client: Alliance Source Testing, LLC ProjecUSite: HF SinclairWoods - CTM-039 Job lD: 140-33467-1 ilethod crM o3e Illlethod Description Protocol References: EPA = US Environmental Protection Agency Laboratory References: EET KNX = Eurofins Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 Protocol Laboratory EPA EET K}.IX &''&Bq t*&11 Eurofins Knoxville l Page 30 of 35 1Ol2l2O23 (Rev. 1) 157 of20l Sample Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33467-1 Lab Sample lD :Ho-33467,1 140-33467-2 140-33467-3 140-334674 140-33467-5 140-33467-6 140-33467-7 140-33467-8 140-33467-9 140-33467-10 140-33467-11 140-33467-12 140-33467-13 140-33467-14 140-33467-'.t5 Matrix Air Air Air Air Air Air Air Air Air Air Air Air Air Air Air Collected oan8l23 w.oo oal2al23 OO:OO OAl2Al23 OO:OO OOl28l23 OO:OO OBl28l23 OO:OO OA2A|23 OO:OO OAl28l23 OO:OO ogl28l23 00:oo 08128123 OO:OO 08/28123 00:00 08/30/23 00:00 08/30/23 00:00 08/30/23 00:00 08/30/23 00:00 08/30/23 00:00 Received o,tl2mot3o 09112123 09:30 09112123 09:30 09112123 09:30 09112123 09:30 O9l'12123 09:30 Ogl12l23 O9:3O Ogl12123 09:30 Ogl12123 09:30 Ogl12123 09:30 Ogl12123 09:30 Ogl12123 09:30 09112123 O9:30 Ogl12l23 09:30 ogl'12123 09:30 Client Sample lD 2OH3 - PM1O.PM2.5 ACETONE RINSE . RUN 1 20H3. <PM2.5 DI WATER RINSE. RUN 1 20H3. <PM2.5 ACETONE RINSE - RUN 1 20H3. <PM2.5 FILTER. 142MM - RUN 1 2OH3 . >PM1 O ACETONE RINSE - RUN 2 20H3. PMlO-PM2.5 ACETONE RINSE . RUN 2 2OH3 - <PM2.5 DI WATER RINSE. RUN 2 2OH3 - <PM2.5 ACETONE RINSE - RUN 2 20H3. <PM2.5 FILTER. 142MM - RUN 2 2OH3 . >PM1 O ACETONE RINSE - RUN 3 2OH3 - PM1O.PM2.5 ACETONE RINSE - RUN 3 20H3. <PM2.5 DI WATER RINSE - RUN 3 20H3. <PM2.5 ACETONE RINSE - RUN 3 2OH3 - <PM2.5 FILTER. 142MM . RUN 3 Page 31 of35 158 of20l Eurofins Knoxville 101212023 (Rev. 1) tsoNflEo6EaItotar i Io+ot(,dzEor IE oz:. )c )))o ll i?i c f o P 3: ,F .p ' 3 t {C2(.Eqaa.qEqq, Eo@ooCo!ots(otoos EI _gfieDvIECIaE 6coEEoo{oEoEo5CTotoaoEIoJotr6E@c dz3EIIgo)I5:)tciE@ioz@(r > too3 cnta' sl 9a @=o6f idEoof o6ct oo .\\ .. . \ rt oEo >coEo'1 GoEo xI \>ooo6ooY I E@.>@I@ oa.ogoo5Eoo:oooY o6co(,o ooo 6e l } n r 3 ) ) ) ) ) ! ) (N rl . l OS W / S Y l u o l J a d ( N /l I al d U E S pa a t ! : oEoI:!o6zI0ooz!nttoo!iio-(, IIt(!6sIE6oof- ;lHl = EE €F :Iiht, l 'o SL SE E fE F tr =1 1 ut -l E Ef l I ;e l E= l *E l E3 l ; E €I i A PI i ; .E l i o\ 'd) of oE@o3 id=Dol 6!oz,gEoEoorGcE=0oo xoL=oF o=ucoEaooE ,l,a2a)l(fz5r5l IIIII IEo - EE E E e ?N H N i IEtsF tr t r t r t r iEr$ (= i* g t !\ a*- =.oqEo') c64Eo:t c6oEo,) o=oEE EF lr t f- . 1 o-a . 9 E6 Ec l o .- X r i\\' \ o6Eo(,oo oJU' idooFU'oE@F@gfo(r ,oac.g uloloaoU'oFNN= c(h=cIc0 ,toq.EoEoooo=(Lo!oN E=doE.otroooqN=o-o=o-oo EdocE,oo=6u?Nc-oN cfdo-cEogooog?N=(LoIoN cftEENoLqN=(Lo!oN NEtoGocoooo=0-o-oN N=toe.oooou?N=(LoLoIoN Nc=docE@6=6oci=ooIoN NcEoce@Eo@oqN=.L!2!oN NcuEENo=u-qN=o-ooN ztrIfo6E6ooEoao \.'\ i ,i\j: E t- - >oEoEIaqE@ ioEocq=o oE@EI=qc6 dc o- z^ ;o60gE rOEEgo it r6G !o iozE :o3g )oUO .F oooEtAoE'ooouE6ot r o=f , (J E U oFAL 6 (E + -c t r o =otrEEEl leo.bIstt ) tud.eEa o= -o'r -H C} s Y od s# :; lU y in 6 .9 P EC ? b* =E €E !s 6; iP TE €€ - '1 0 1 2 1 2 0 2 3 (R e v . 1) Pa g e 3 2 o f 3 5 FIN!o6!jI{;otr$io?=(, (. ,o2Eor IE Eo(,otrrE 6 ot r o=EoE rh Li oL 6 (u t st r o 8l E i .E I i * PI E ! $l l E=otroEa g3 =q>! a5s Y 5e BE FO (E v d6 .9 P HC E+ =E EE E. H -o i EE PE CT 3E 6=SE 6X T,oEs-9oEo@tooEooo=(L ll J=6=q)o6@o-r@o=o-UJ !@I6EoggE6o6@ ,N i d d -FF tr t r D t r '-93s - . - Eg g s 10 t 2 t 2 0 2 3 (R e v . 1) Pa g e 33 of 3 5 oo!o FoctrU I: Fi(-la-ttt:e Lo=-tolc 6=89 .! oxc0 ooL2o.ooo. e. l \ooe' l&\oc. loo;NNs]g€o Io. E '5 .. d<P \o i l x9oo . H AD ' :i I >o I ;E . s . . a= ! e 4 62 4 Z EE * E o- J t < od! oF 6.E0o0o6oz oL0ooUtr 56o-: eootr 3< >z EE a EOoE I3 v t ae a .s > . o F5 F q9 , l q eo v o. E o v5 v 3 EU E I ( ooleo€oOtl oo=;\EO ?:o. . '= e EE vEEU IAy o oo - Zr ooAE E * r- ' a E; o ., , 3 2 "s E Z (J O ( J oo o (J U U bo o rEa2 o r \ e6 q€ )o. r u) a) EE o(. )oFoGoZr vEEU UUoo-lozoaE oo(,oUE QoQocozUoUE] ooeoLo()UE e)oooUUtr oooFEIotr o=9s! FPa? , dg ;" i =E o 2x i \o o -! o E9 t r ooaq(Eqotr l !oogE Ecgo!oE -oolEoaoAE z \ \ \ ) \ z \ \ \ \ \ \ \ \ \ \ ) \ \ Eccq Looooboaoo;' ro6Eo.toooodoosE6gc) c. r ooA6oo()oooooo c' : E? i t- E r; . E P.= ^ _O=9BF I I $, P sI J =: / Hr l E3 f i e Ft .. t ' . t sg o b *g E E 8} E E oH b' i €: F 8 s Fq = +g H ( J ooNootE oooooLo6oooE6ocoor; ooooo.,q(,ooooo.ootE; (JC)odEqo,o6O^ .= oEE OF () - o3 o. E EO 6^oO HJ c- rooooUOoooaGq) (Ho?ooq; G.ooooooo6ooEo6.olDoi c- .C)o(JooooLooo(g=c; G.ooltoE6oovo6ooo roo6ooL.oEooo6ooIe. i EooaE6oox6C) 'oq)Et-o(!oooo U)Eoo(JUB+ qOIBooooo6goB 6.9@ooooor . t9'891 4 'd x0 -( ) "o 36 E5 tr vE9 9; o> ts b 'd g FooI.Edo-oooooEE6oot- r6oo{)ooo5 ar a 9: .o € o H €. I y \o .i i o . ! E6 * oA s =- o o€ g >r H ' i o ^i 9 i5 g6 qt 6.o\ooo6o6i@c7 )ohoi boIjaooo6(so6E6hc; c. l oGoaoooo&oo. 6U) N 3r o -5 f ii co -3 <' l ;, :ozo0Jt-a.iUtr lUI2zFaf- IUri&zoF"zFzUFrr l (J li lFl2rnFI rl IXozQ&tr l2.FariazE.o 10 1 2 1 2 0 2 3 (R e v . 1) Pa g e 3 4 o f 3 5 Client: Alliance Source Testing, LLC Login Number:33467 List Number: I Creator: Dameron, Bryan K Question Login Sample Receipt Checklist Answer Comment Job Number: 1 40-33467 -'l List Source: Eurofins Knoxville Radioactivity wasn't checked or is </= background as measured by a survey meter. The cooler's custody seal, if present, is intact. Sample custody seals, if present, are intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. ls the Field Sampler's name present on COC? There are no discrepancies between the containers received and the COC. Samples are received within Holding Time (excluding tests with immediate HTS) Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. Sample Preservation Verifi ed. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs Containers requiring zero headspace have no headspace or bubble is <6mm ('ll4"). Muftiphasic samples are not present. Samples do not require splitting or compositing. Residual Chlorine Checked. Page 35 of 35 162. of 201 g Eurofins Knoxville 101212023 (Rev. 1) 153 of20l AIl6rpe TECI..INI(]AL flfiffUII Irotio! EF Sinchir woods Cross Refining, LLC - Wcst Bouoaiful' UT QA/QC Data Sourcc Procctt Hcrtcr 20H3 Projcct No. AST-2023-r660 P.rrmeter PM (CTM-039) Irrtc Nozzle ID Nozlc Diamctcr (in.) #1 #2 #3 Dn (Avcrrse) Dilference Criteria 8t25123 N20lA-10 0 370 0.370 0.370 0.370 0 000 S 0.004 in. Dete Pitot ID lrvadctrcc ol Evidcncc of LtuDrf,non or Drnoir Barrird, al25l23 P-761 no no no Drte Probe ID Rclbrcncc Itrdicrtcd Difierctrce Criteria 8125123 P-761 790 79.2 o.oyo I 5 % (abrclute) Drte Barometric Pt6surc Evidcncc of Rcrding Vcrilied Lt[Drauon or Danoir rcarirad, 8D5t23 Weather Station NA NA NA 164 of20l Alm]rce TECHNICAL GROIJP QA Data Location HF Sinclair W Project No. AST-2023-1660 Prrameter(s) Moisture Field Balance Check Date 08t2st23 Balance ID:5A288r026 Iest Weight ID:SLC-IKG Certified Weight (g):1000.0 Measured Weight (g):999.9 Weight Difference (g):0.1 Date Barometric Pressure Evidence of Reading Verified Calibration or Renair reouired?Weather Station Location 8/25t23 Weather Station NA NA NA West Bountiful, UT Dete Meter Box ID Positive Pressure Leak Check 8/25/23 MB-704 Pass 165 of20l DGM Calibration-Orifi ces DGument lt 620004 Revisior B.A Effective Dai 1/25/21 lssuing Departmenl Ish Seruices Paqt 1of 1 Equipment Detail - Dry Gas Meter Console lD: tvl8-704 tvleter S/N: 18392989 Critical Orifice S/N: 1330 Calibration Detail nitial Barometric Pressure, in. Hg (Pbi :inal Barometric Pressure, in. Hg (Pbr) \veraoe Barometric Pressure, in. Ho (Pb) 25.45 25.48 25.47 Critifcal Orifice lD (Y) K' Factor, ft3 R'/2 / in. wc.min (K) Vacuum Pressure, in. Hg (Vp) lnitial DGM Volume, ft3 (vmr) Final DGM Volume, ft3 (VmF) Total DGM Volume. ft3 (Vm) 1330-31 0.8429 13.0 753.100 769.643 16.543 1330-31 1330-25 0 6728 15.0 782 800 796.038 13.238 1330-25 1330{9 0.5186 16.0 806.000 816.437 10.437 1330-19 0.8429 0.673 0 519 13.0 769.643 780.710 11.067 15.0 796.038 804.888 8 850 16.0 816 783 823.493 6.710 Ambient Temperature, 'F (Ta) Initial DGM Temperature,'F (Im) Final DGM Temperature, "F Omr) Averaqe DGM Temperature,'F (Tm) 72 73 74 74 72 74 75 75 73 74 l4 74 73 74 75 a< 74 75 75 75 75 75 75 1t Elapsed Time (O) Meter Orifice Pressure, in. WC (AH) Standard Meter volume, ft3 (Vmstd) Standard Critical Orifice Volume, ft3 (vcr) Meter Correction Factor (Y) Tolerance Orifice Calibration Value (AH @) Tolerance Orifice Cal Chec< 15.00 3.40 14.0740 13.9631 0.992 0.000 1.878 0 018 10.00 3.40 9.3976 9.3087 0 991 0.001 1.874 0.014 15.00 2.10 11.2099 11.1348 0.993 0.001 1.815 0.0M 10 00 2.10 7.4871 7.4232 0.991 0.000 1.814 0.046 15 00 1.30 8.8012 8.5148 0.974 0 018 '1.887 0 027 10.00 1.30 5 6584 5.7112 '1.009 0.017 1.891 0.031 0.'11 011 0.06 Meter Correction Factor m 0.992 Orifice Calibration Value (AH @)1.860 Positive Pressure Leak Check Yes Eouioment Detail - Thermocouole Sensor Reference Calibrator Make: OMEGA Reference Calibrator Model: CL23A Reference Calibrator S/N: I -197207 Calibration Detail Reference Temp.Display Temp Accuracy Difference OF oR r Vo OF 0 68 100 460 528 560 0 66 98 460 526 558 0.0 04 04 0 2 2 223 248 273 683 708 733 223 248 274 683 708 734 0.0 0.0 -0.1 0 0 1 300 400 500 600 700 800 900 1,000 1,100 r.200 760 860 960 1,060 1,160 1,260 1,360 1,460 1,560 'l 660 300 399 498 600 702 801 901 1,002 1,102 1 )Ct) 760 859 958 1,060 1,162 1,261 1,361 1,462 1,562 1,662 0.0 0.1 0.2 00 -0.2 -0.1 -0.1 -0.1 -0.1 -0.'1 0 1 2 0 2 1 1 2 2 2 Personnel 6/20/2023 166 of 20 I Calibration By: Calibration Date. Reviewed By: RYAN LYONS plltffirrce TECHNICAL GAOUP Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT QA Data Source Process Heater 20H3 Project No. AST-2023-1660 Parameter O, - Outlet COz - Outlet Make SERVOMEX SERVOMEX Model t440 1440 S/N 1240013279 14150/3279 l)nerafinq Renqe 0-2s 0-25 Cylinder ID Znro Low Mid Hieh NA NA E80078899 SGI64824BAL NA NA EB0078899 SGI64824BAL Cylinder Certifed Values 7.c.ro Low Mid Hieh NA NA 10.95 24.58 NA NA 10.7 4 23.78 Cylinder Expiration Date 7*ro Low Mid Hish NA NA 7n3/29 2n3t3t NA NA 7n3/29 2lt313t 167 of2ol Rlt6]rce YE e H \ lcA L o n:":";"", HF SinclairwoodscrossRefining,LLC -westBountitul,UT Response Times Source: Process Heater 20H3 Project No.: AST-2023-1660 seconds Parameter Or - Outlet COr - Outlet Zero Low Mid Hish 30 NA 30 30 30 NA 30 30 Averase 30.0 30.0 168 of20l RllmrpeTt*!-{\*reAL {}FC)UF'Calibration Data Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Datez 8125123 Parameter Oz - Outlet COz - Outlet Expected Average Concentration 8.00 8.00 Span Between Low High Desired Span 8.00 40.00 24.s8 8.00 40.00 23.78 Low Range Gas Low Hish NA NA NA NA Mid Range Gas Low Hish 9.83 14.75 9.51 14.27 High Range Gas Low Hioh NA NA NA NA Actual Concentration (% or ppm) Zero Low Mid Hish 0.00 NA 10.95 24.58 0.00 NA 10.74 23.78 Resoonse Time (seconds)30.00 30.00 Upscale Calibration Gas (Cy,a)Mid Mid Instrument Response (% or ppm) Zero Low Mid Hieh 0.09 NA I1.06 24.64 0.03 NA 10.83 23.69 Performance (7o of Span or Cal. Gas Conc.) Zero Low Mid Hish 0.37 NA 0.45 0.24 0.r3 NA 0.38 0.38 Performance Criteria Zero Low Mid Hish 2.00 NA 2.00 2.00 2.00 NA 2.00 2.00 Status Zero Low Mid Hish PASS NA PASS PASS PASS NA PASS PASS 169 of20l Alffi]EeTEC'-{\]CAL GNOUP Calibration Data Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Date:8/28123 Parameter O, - Outlet COz - Outlet Expected Average Concentration 7.56 7.46 Span Between Low High Desired Span 7.56 37.79 24.s8 7.46 37.29 23.78 Low Range Gas Low Hish NA NA NA NA Mid Range Gas Low Hioh 9.83 14.75 9.51 t4.27 High Range Gas Low Hioh NA NA NA NA Actual Concentration (% or ppm) Zero Low Mid Hish 0.00 NA 10.95 24.58 0.00 NA 10.74 23.78 Uoscale Calibration Gas (C Mid Mid Instrument Response (% or ppm) Zero Low Mid Hieh 0.02 NA 10.90 24.48 0.02 NA t0.97 23.89 Performance (% of Span or Cal. Gas Conc.) Zero Low Mid Hish 0.08 NA 0.20 0.41 0.08 NA 0.97 0.46 Status Zero Low Mid Hish PASS NA PASS PASS PASS NA PASS PASS 170 of 20 I aIlmrrceTEfiH\,CAL $H()UP Calibration Data Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Date:8129123 Parameter Oz - Outlet COr - Outlet Exoected Averase Concentration 7.56 7.46 Span Between Low High Desired Span 7.56 37.79 24.58 7.46 37.29 23.78 Low Range Gas Low Hish NA NA NA NA Mid Range Gas Low Hish 9.83 14.75 9.51 t4.27 High Range Gas Low Hioh NA NA NA NA Actual Concentration (% or ppm) Zero Low Mid Hish 0.00 NA 10.95 24.58 0.00 NA 10.74 23.78 Upscale Calibration Gas (C.n)Mid Mid Instrument Response (% or ppm) Zero Low Mid Hieh 0.04 NA 10.83 24.32 0.02 NA 10.74 23.36 Performance (7o of Span or Cal. Gas Conc.) Zero Low Mid Hish 0.16 NA 0.49 1.06 0.08 NA 0.00 t.77 Status Zero Low Mid Hish PASS NA PASS PASS PASS NA PASS PASS 17l of2Ol dAIhrrce TT.CHNI*AL GROI-,'l, Bias/Drift Determinations Lo."tiont Source: Process Heater 20H3 Project No.: AST-2023-1660 Parameter Oz - Outlet COr - Outlet Run 1 Date 8nsn3 ipan Value .nitial Instrument Zero Cal Response .nitial Instrument Upscale Cal Response lretest System Zero Response losttest System Zero Response lretest System Upscale Response hsffest Swcfem I In<cale Resnonse 24.6 0.1 ll.l 0.1 0.1 I1.0 10.9 23.8 0.0 108 0.1 0.1 10.8 10.'t Bias (%) Pretest Zero Posttest Zero Pretest Span Posttest Span 0.1 -0.1 -0.4 -0.7 0.t 0.2 -0.3 -0.4 Drift(%) Zero Mid -02 -0.3 0.1 -0.1 Run 2 Date 8D8-429n3 Span Value Instrument Zero Cal Response Instrument Upscale Ca[ Response Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest Svstem Uoscale Resoonse 246 0.0 10.9 0.0 0.0 r0.9 10.9 23.8 0.0 l l.0 0l 0.1 10.9 108 Bias (%) Pretest Zero Posttest Zero Pretest Span Posttest SDan 0.0 0.0 -0.1 -0.2 0.2 0.3 -04 -0.8 Drift(%) Zero Mid 0.0 -0.1 0.1 -0.4 Run 3 Date 8129-8/30123 Span Value lnstrument Zero Cal Response lnstrument Upscale Cal Response Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Pnstfesf Svstem I Inscale Resnonse 246 0.0 10.8 0l 0.0 10.8 10.9 23.8 0.0 10.7 0.1 0.1 10.7 10.7 Sias (%) )retest Zero )osttest Zero )retest Span )osttest Snan 0.t 0.0 -0.2 0.1 0.2 0.1 -0.3 -0.3 )rift (%) Lero vlid -0.1 0.2 00 00 172 of 201 Airga$ a,l ArLiquicr6 company AftEEs Speciafv C,ases AirgasUSALtC 545 North Indrxtrial Laop Road Tooele, UT&o7+ Airgas.com CERTIFICATE OF AIYALYSIS Grade of Product EPA PROTOCOL STANDARD Part Number: Cylinder Number: Laboratory: PGVP Number: Gas Code: E03N152E15A38Q7 SGg164824BAL '124 - Tooele (SAP) - UT 872023 C02,02.BALN Reference Numbec'153-402661 010-1 CylinderVolume: 164.0CF Cylinder Pressure: 2015 PSIG Valve OuUel 296 Certification Date: Feb 13, 2023 Use I nE 9ylnder below 10O Nlq, i.e. 0. ANALYTICALREST]LTS Component Requar&d Goncentration Actual Concentration Protocol Total RelativeMethod Uncertainty Assay Dates CARBON DIOXIOE OXYGEN NITROGEN 24.OO'lc 21.A0 % Balance ?3.78% 24.58% G2 G2 +/- 0.8% NIST Traceable +A 0.6% NIST Traceabie 0211312023 0!1312023 CALIBRATION STANDARDS Type LotlD CylinderNo Concentradon Uncertainty Expkadon Date NTRM NTRM 13060802 09061434 @4r53S7 @282492 2,I.fi % CARBON DIOXIDSNITROGEN 22.53 E6 OXYGENNTROGEN o.6% 0.40h Dec11.2025 Mav 13.2025 lnstumentlMakelModel A}IALYTICAI EQUIPMENT Analytical Principle l-ast Muhipoint Calibralion Hodba MA-510 SV4MEUTJ @2 Horiba MPA-s,0 ri,603MM58 02 CO2 NDIR (Dixon) O2 Paramagnelic (Mason) Feb Gl,2023 Feb 09,2023 Triad Data Available Upon Request 173 of 201 Page t of 'l :80078899 25371 9OO PSIG .2021062&0 Certification Data: Expiratlon OaE: MFG Facltity: Lot Numbsr: Tracking Number: Previous Cerilfication Dates: Red Ball Technical Gas Service 555 Graig Kennedy lffay ShrevepoG LA 71107 800-551{150 PGVP vendor iD # Gr2021 vh5n021 fln3nazs Sh6vaMrl - I A t8/.nog76 l#PJI,Adkd& Accreditstion #6454 Cylinder Number: Product lD Number: Cylinder Pressure: coA# Customer PO. NO.: Customer: EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS This calibration standard has been certified per fle May 201 2 EPA u531, 1. Concentration Uncartalnty Anatytical Prlnciple Assayed On Data Available online. 11629€@25 06/3012021 1152980025 06t217@.1 SM,ARTCERT This is b cedry he gases referenced have been calibratedbsted, and vetified to meet he defined spedfica0ons. This calibratton/test was performed using Gases or Scales tiat are traceabb fi'ough Nalional hslitute of Siandards and Tec*lnotogy (NtsT) b t'le lntemauonal system of units (sD. The basis of comdiance siaEd is a compatison of the meanurcment paftrmeteG to $e spedfied or required calibrationtesting process. The clQanded uncertainties use a ooverage tacdor of k=2 t' approximaie the 95% confidence level of the measuremer( unless otheru,ise nobd. Th'ls calibration oedificate apdies onty b the iterrdesdibed and shall not be reproduced other $an in full, without written approval frotn Red Ball Technical Gas Services" li not iilduded, the uncertainty of celibratioN are availabb upon request and were Eken itrto eccouttt when determining Pass orfail. ry- Anthony CYr Assistart Operations iianager A&saylaboratorlf Red BallTGS Ve6im 02J. Revised n 201&0+17 174 of20l nllffirrce TECF.I \}CAL GROUP Location: HF Sinclair Woods Cross Refinins, LLC - West Bountiful, UT Source: Process Heater 20H3 Project No.: AST-2023-1660 Datez 812512023 Traverse Point Time o2 (o/ol Coz lo/^\ A-I 2 3 8: l2 8: l3 8: l4 7.t5 7.ll 7.14 7.74 7.75 7.73 Averase 7.r3 7.74 Criteria Met Sinsle Point Sinele Point 175 of201 't0.3.2 The temperature data recorded in the field shall be considered valid. lf, during calibration, the absolute temperature measured with the sensor being calibrated and the reference sensor agree within 1.5 percent, the temperature data taken in the field shall be considered valid. Otherwise, the pollutant emission test shall either be considered invalid or adjustments (if appropriate) of the test results shall be made, subject to the approval of the Administrator. Date Sensor ID Reference Tem n lor') Indicated Temn. (of,')Difference Criteria 3/1U20 3nt/20 3nv20 3/1U20 3trt/20 3fi1/20 3nv20 3/1y20 3/1v20 Stack Probe Sample Venturi Oven Exhaust Mix I Dil I Dilution Venturi Dilution Aux 1000.0 250.0 250.0 300.0 30.0 70.0 50.0 30.0 68.0 1001.0 251.7 251.2 301.8 30.9 70.5 54.8 30.6 68.6 0.lo/o 0.2% 0.2% 0.z%o 0.2o/o 0.lo/o 0.9Yo 0.lYo 0.r% L 1.5 Yo (absolute) 2l?fsfl\b you may use the manufacture/s recommended procedure for calibrating the RH sensors. Verify the dilution air and mixed gas RH sensor calibrations within three months of each test by attaching the two sensors to each other and drawing ambient air with approximately 50 to 70 percent relative humidity simultaneously through both sensors. Because the difference between the two RH sensors is very important in calculating stack gas moisture concentration using this method, the two RH sensors must agree within 2.8 percent of reading when monitoring the same gas stream. Date Console ID Dilution Air RH (%) Mixed Air RH (%)Difference Criteria 3lrv20 FPM-C-5017 64.2 6l.l 0.6% r.2.80h (absolute) 2lysf12\ Dilution Venturi lnstrument Range 10 Reference lnstrumen Absolute Difference Percent Difference 10.00 9.00 7.00 5.00 3.00 1.50 0.00 9.88 9.01 7.08 5.01 3.02 1.59 0.14 0.125 0.009 0.082 0.005 0.017 0.087 0.143 1.3 0.1 0.8 0.0 0.2 0.9 1.4 Average o.67 Venturi lnstrument Ranse 5 Reference lnstru ment Absolute Difference Percent Difference 5.00 4.00 3.00 2.00 1.00 0.00 4.90 3.93 2.92 1.94 0.93 o_lo 0.098 0.073 0.076 0.062 0.07 0 2.O 1.5 1,5 L.2 L.4 0.0 Average L.26 Pitot lnstrument Rang€5 Reference lnstru ment Absolute Difference Percent Difference 5.00 4.00 3.00 2.00 1.00 0.00 4.95 3.95 2.95 1.95 0.95 0.02 0.055 0.047 0.051 0.052 0.0s1 0'o:2 t.L 0.94 t.o2 L.O4 L.O2 0.44 Average 0.93 2lrsfrgb otsqN.qo oqooqoYooEo YE.9oooE Ete'tIE-.doGU zE.€o@od oNoNFo{lNss Io - I<vilx. .. t -l+. t -t I {l L .I,tEI ol il t-l* *l I a- - .!Inr:JqqNs qcITe?@,eE! .?I qqqol I.i EcqoqqF*o.qa.! q\nooqNF.?r:Ns :@.F@.s IoE qqc?cioq c?cintsoc,qo\s act tsIoEosoi qciqq.lci oqso \ 3ci4I\c; Nso q qci r:|:Iciqqcisoi olFgIoiqc; zl T s f l \ \ qFoq9qq\ciolF FFF\Ici tstsqts@. c; tss qtsci IqnoF qqFciccnq E E Ye oq a EF Itai it .e € e -! 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Ts F 631.60 605.00 602.20 Front Half Emissions Summary CO2 - FCO2 8.46 8.33 7.43 Run 1 Run 2 Run 3 Run 4 Avg. O2 5.98 5.86 7.55 gr./dscf 0.0004 0.00030 0.0001 0.0003 N2+C 85.56 85.81 85.02 lbs/hr 0.0276 0.0200 0.0092 0.0189 lbs/MW-hr 0.0001 0.0000 0.0000 0.0000 Md 29.59 29.57 29.49 lbs/MMBtu 0.00068 0.00049 0.00025 0.00047 Ms 27.89 27.77 27.91 Y 1.1420 1.1420 1.1420 Cp 0.76 0.76 0.76 Total Emissions Summary w/back half condensable Vm cf 78.60 79.90 77.10 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 79.90 79.90 79.90 gr./dscf 0.0004 0.0003 0.0001 0.0003 AVG. Tm F 87.00 86.15 80.85 lbs/hr 0.0276 0.0200 0.0092 0.0189 lbs/MW-hr 0.0001 0.0000 0.0000 0.0000 Vm std 80.60 79.50 82.30 lbs/MMBtu 6.840E-04 4.905E-04 2.496E-04 0.0005 Vw std 3.76 3.76 3.76 Bws 0.15 0.16 0.14 S Bws 1.00 1.00 1.00 Avg. Sqrt Dlp 0.25 0.25 0.25 Vs 19.88 19.69 19.65 F factor used scfm wet 9.12E+03 9.25E+03 9.22E+03 8265 acfm 2.19E+04 2.17E+04 2.18E+04 Qsd dscfh 4.67E+05 4.69E+05 4.77E+05 # Sample Points 20.00 20.00 20.00 Dn 0.370 0.370 0.370 An 7.47E-04 7.47E-04 7.47E-04 Start Time End Time Total Test time 240.00 240.00 240.00 Time @ point 20.00 20.00 20.00 O2 CO2 lbs/M Page 1 Summary 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 2 Run 1 Holly Frontier Refinery - Process Heater 20H3 Flow & Moisture Test Date 8/25, 28-30/23 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 18.35 25.80 -0.26 25.78 632 8.46 5.98 85.56 29.59 27.89 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 160.4303 1.1420 0.76 78.600 79.90 87.00 80.600 3.761 0.1470 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.2490 19.88 9,122 21,946 4.67E+05 20 0.37 240 20.00 1.160000 FALSE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 0.000 0.06 1.16 632 82.9 91.1 Wt. (Final) Wt. (Initial) lc 2 78.600 0.06 1.16 632 82.9 91.1 460.0 420.0 40.0 3 433.5 427.1 6.4 4 340.9 311.4 29.5 5 591.9 587.9 4.0 6 0.0 7 8 Isokinetics 88.4 9 Test Date 8/25, 28-30/23 10 Start Time enter enter 11 0.2330 enter 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holly Frontier Refinery - Process Heater 20H3 Flow & Moisture Test Date 5/13/2009 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 18.35 25.77 -0.19 25.76 605 8.33 5.86 85.81 29.57 27.77 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 132.9213 1.1420 0.76 79.900 79.90 86 79.500 3.761 0.1550 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.2490 19.69 9,250 21,727 4.69E+05 20 0.37 240 20.00 1.16 FALSE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 0.000 0.06 1.16 605.0 90.9 81.4 Wt. (Final) Wt. (Initial) lc 2 79.900 0.06 1.16 605.0 90.9 81.4 460.0 420.0 40.0 3 433.5 427.1 6.4 4 340.9 311.4 29.5 5 591.9 587.9 4.0 6 0.0 7 8 Isokinetics 88.5 9 Test Date 8/25, 28-30/23 10 Start Time enter 11 0.2330 enter 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holly Frontier Refinery - Process Heater 20H3 Flow & Moisture Test Date 5/13/2009 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 18.348 25.68 -0.19 25.67 602 7.43 7.55 85.02 29.49 27.91 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 130.6820 1.1420 0.76 77.100 79.90 81 82.300 3.761 0.1380 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.2490 19.65 9,224 21,809 4.77E+05 20 0.37 240 20.00 1.16 FALSE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 0.000 0.06 1.16 602.2 79.2 82.5 Wt. (Final) Wt. (Initial) lc 2 77.100 0.06 1.16 602.2 79.2 82.5 460.0 420.0 40.0 3 433.5 427.1 6.4 4 340.9 311.4 29.5 5 591.9 587.9 4.0 6 0.0 7 8 Isokinetics 86.3 9 Test Date 8/25, 28-30/23 10 Start Time enter 11 0.2330 enter 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1