HomeMy WebLinkAboutDAQ-2024-0042961
DAQC-1298-23
Site ID 10123 (B4)
MEMORANDUM
TO: STACK TEST FILE – HF SINCLAIR – Woods Cross Refining, LLC
THROUGH: Harold Burge, Major Source Compliance Section Manager
FROM: Robert Sirrine, Environmental Scientist
DATE: November 28, 2023
SUBJECT: Source: Boiler #10
Location: 1070 West 500 South, West Bountiful, Davis County, Utah
Contact: F. Travis Smith: (801) 299-6625
Tester: Alliance Source Testing
FRS ID #: UT00000049011000013
AO #: DAQE-AN101230057-23, dated November 15, 2023
Action Code: Tr
Subject: Review of stack test report dated October 20, 2023
On October 20, 2023, Utah Division of Air Quality (DAQ) received a stack test report for testing of
Boiler #10 located at the HF Sinclair Woods Cross Refinery in West Bountiful, Davis County, Utah.
Testing was performed August 22-23, 2023, to determine compliance with the PM10 emission limit found
in Conditions II.B.1.a, and II.B.6.a. The DAQ calculated results are:
Source Test Date RM/Pollutant DAQ Result Test Result Limit
Boiler #10 8/22-23/23 CTM-039/PM10 0.00074* 0.00074* 0.0070*
*lb/MMBtu
DEVIATIONS: No deviations were noted.
CONCLUSION: The test report appears to be acceptable.
RECOMMENDATION: The Boiler #10 PM10 emissions appear to have been in compliance with
the applicable limit at the time of testing.
HPV: Yes.
ATTACHMENTS: Stack test report received October 20, 2023
DAQ generated excel spreadsheets
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HF Sinclair Woods Cross Refining LLC
1070 W. 500 S, West Bountiful, UT 84087
801 -299-6600 | HFSinclair.com
TJTAH DEPAHTMENT OF
E}WIRONME}.ITAL OUATITY
0cT 2 0
",,'"?,
October 20,2023
Mr. Bryce Bird, Director
Division of Air Quality
Utah Dept. of Environmental Quality
195 North 1950 West
Salt Lake City, Utah 841l6
RE: Annual PMro Emissions Test Report - Boiler #10
HF Sinclair Woods Cross Refining LLC, Davis County
Dear Mr. Bird:
,mib* o#t;$"d,#*
Hand Delivered
In accordance with Conditions tr.B.l.a and II.B.6.a of Approval OrderANl01230055-23,please find enclosed
theresultsofourrecentPMroemissionstestingforBoiler#10. ThetestingwasconductedAugust22-23,2023.
The test results were 0.00074 lbs/IvlMBtu for PMro.
Enclosed, please find a copy of the testing report for Boiler #10.
If you have any questions or need additional information, please contact F. Travis Smith at (801) 299-6625 or
email ftravis.smith@hfsinclair.com.
I certify that:
Testing was conducted while the source was operating at the rate and/or conditions specified in the
applicable approval order, operating permit, or federal regulation;
During testing, the source combusted fuels, used raw materials, and maintained process conditions
representative ofnormal operations, and operated under such other relevant conditions specified by the
Director;
Based on information and belief formed after reasonable inquiry, the statements and information
contained in the report are true, accurate, and complete.
Sincerely,
Vor,--r [;.^^-.^2-
Dustin Simmonds
Vice President and Refinery Manager
Enclosure
c: E. Benson (r\File2.4.4
K. Arnold
J. Barton
J. Orr
UT{II DEPART\IENT OF
ENV iROi.l lrtEr',lTAL OUALITY
Al;3retr'{ffi
Source Test Report
HF Sinclair Woods Cross Refining, LLC
1070 West 500 South
West Bountiful, UT 84087
Source Tested: Boiler No. 10
Test Dates: August 22 & 23,2023
Project No. AST-2 023 -1660-009
S.*,*Y'ffi'f*
Prepared By
Alliance Technical Group, LLC
3683 W 2270 S, Suite E
West Valley City, UT 84120
pilr6rpe
TECI--I NICAL GNCTJ t]Source Test Repoil
Test Progmm Summary
Regulatorv Information
Permit No. DAQE-AN101230055-23
Source Information
Source Name
Refinery Gas Fired Process Boiler
Contact Information
Source ID
Boiler No. l0
Target Parameters
PMIO, PM2.5
Test Location Test Company Analytical Laboratory
HF Sinclair Woods Cross Refining, Alliance Technical Group, LLC Eurofins TestAmerica
Charles Horton
eric.benson@hfsinclair.com charles.horton@lliancetg.com
5815 Middlebrook Pike
Knoxville, TN 37921
Kevin Woodcock
Project Manager kevin.woodcock@testamericainc.com
(865) 291-3000
LLC
1070 West 500 South
West Bountiful, UT 84087
Eric Benson
(801)299-6623
F. Travis Smith
ft rav is. sm ith@hfsinc lair. com
(80r)299-662s
3683 W 2270 S, Suite E
West Valley City, UT 84120
(352\ 6r3-7s68
Field Team Leader
Tobias Hubbard
tobias.hubbard@alliancetg.com
(60s) 645-8562
QA/QC Manager
Kathleen Shonk
katie. shonk@alliancetg.com
(812\ 4s2-4785
Report Coordinator
Sarah Perry
sarah.perry@all iancetg.com
HF Sinclair - West Bountiful, UTAST-2023-1660-009
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TFCIlNICAL GIJCUP Source Tesl Reporl
C ert irt c ot ion St o t eme nt
Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results
apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within
this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less
than the complete test report without written consent. This report shall not be reproduced in full or in part without
written approval from the customer.
To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this
report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in
accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the
relevant sections in the test report.
This report is only considered valid once an authorized representative ofAlliance has signed in the space provided
below; any other version is considered draft. This document was prepared in portable document format (.pdf) and
contains pages as identified in the bottom footer of this document.
,,' ii,)/ / t/,
t0/12t2023
Charles Horton, QSTI
Alliance Technical Group, LLC
Date
HF Sinclair- West Bountiful. UTAST-2023- I 660-009
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TECI-I NICAI GBOUP Source Test Report
Table ofContents
TABLE OF CONTENTS
l.l Emission Unit and Control Unit Descriptions................. ........................... l-l
1.3 Site-Specific Test Plan & Notification ......... l-l
3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate ..... 3-l
3.2 U.S. EPA Reference Test Method 34' - Oxyger/Carbon Dioxide.......... .......................... 3-l
3.3 U.S. EPA Reference Test Method 4 - Moisture Content.......... ................. 3-l
3.4 U.S. EPA Conditional Test Method 039 - PMI0/PM2.5.............. .............3-2
3.5 U.S. EPA Reference Test Method l9 - Mass Emission Factors........... ............................ 3-3
3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3,A'.......................................... 3-3
LIST OF TABLES
Table 2-l: Summary of Results- PMI0/PM2.5. ..........2-l
APPENDICES
Appendix A Sample Calculations
Appendix B Field Data
Appendix C Laboratory Data
Appendix D Quality Assurance/Quality Control Data
Appendix E Process Operating/Control System Data
FIF Sinclair - West Bountiful, UTAST-2023- I 660-009
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TECI-]INICAi GRCUP Source Test Report
Introduction
1.0 Introduction
Alliance Technical Group, LLC (Alliance) was retained by HF Sinclair Woods Cross Refining, LLC (HF Sinclair)
to conduct compliance testing at the Woods Cross Refinery in West Bountiful, Utah. Portions of the facility are
subject to provisions of the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit
No. DAQE-AN101230055-23. Testing was conducted to determine the emission rates of particulate matter less than
or equal to l0 microns (PMl0) and particulate matter less than 2.5 microns (PM2.5) from the exhaust of BoilerNo.
10.
l.l Emission Unit and Control Unit Descriptions
1.2 Project Team
Personnel involved in this project are identified in the following table.
Table l-l: Project Team
HF Sinclair Personnel Matthew Howes
Alliance Personnel Tobias Hubbard
Supilani Mailei
1.3 Site-Specific Test Plan & Notification
Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by HF Sinclair.
HF Sinclair - West Bountiful, UT
Boiler No. l0 Steam boiler, 89.3 MMBtU/hr HFIV, fired on plant gas,
forced draft, I burner, side-fired furnace, no air preheat.
Stack temperature aooroximatelv 3 l0-500oF.
Selective catalytic reduction using
aqueous or anhydrous ammonia
AST-2023- I 660-009
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Source Tesl Reporl
Summary of Results
2.0 Summary of Results
Alliance conducted compliance testing at the HF Sinclair facility in West Bountiful, Utah on August 22 and 23,
2023. Testing consisted of determining the emission rates of PM2.5 and PM l0 at the exhaust of Boiler No. 10.
Table 2-l provides a summary of the emission testing results. Any difference between the summary results listed in
the following table and the detailed results contained in appendices is due to rounding for presentation.
Table 2-l: Summary of Results - PMl0/PM2.5
Nrrmher Runl Run2 Run3 A
)ate
itart Time
itop Trme
8122/23
l0:56
l5:08
8/22/23
t6 4'7
2l: l3
8/23/23
l0:22
l4:44
INPIIT DATA
:uel Go Flow Rate, scflr
Ieat Input, MMBtu/hr
ruel Factor (O2 dry), dscCMMBtu
ldometric Pressure, in. Hg
vleter Correction Factor
llozle Diameter, in
\rea of Nozle, ft2
fotal M6s of PMl0 [m, mg (m2 + m] + mr + mr)
total M6s of PM < l0 l.m and >2 5 pm, mg (m2)
fotal M6s of PM <2.5 um. mq (m. + m, + m.)
(FR)
(HI)
(Fd)
(Pb)
(Y)
(Dn)
(An)
(mruru)
(mpuro.::)
(mpur <)
56,750
48.07
8,288
25.47
1 142
0.240
0.0003 I
3.49
0 089
340
56.7e0
48. l0
8,288
25.79
t.t42
0.260
0 00037
1.83
0.000
1.83
66,970
65.21
8,213
25.8 r
t.t42
0.260
0.00037
2.t6
0.000
2.16
60,170
53.79
8,263
25.82
1.t42
o.253
0.00015
249
0.030
.-TM-O3S I,rl.:.:FR DATA
)ilution Flow Rate, dscfm
iample Flow Rate, dscfm
y'olume Sampled, dscf
y'olume Sampled, dscm
y'iscosity
{eynolds Number
)unningham Conection Factor
'articulate Cut Diameter for PMl0
)articulate Cut Diamcter for PM2.5
)ilution Ratio
!,[oisture Fraction Me6ured
sokinetic Samnling Rate /7")
(Qr"a)
(Q<*a)
(V<uai)
(Vqrar)
(r)
(N,")
(c)
(Dso)
(Dso)
(DR)
(BwSrud)
(I)
4.28
0.328
78.8
2.23
230 0
2,23t.5
l.l I
1 0.14
246
14.03
0.140
984
6.98
0.33 I
79.3
2.25
225.4
2,352 4
Lll
9.89
2.32
22.07
o.147
843
5.98
o 327
78.5
2.22
226.7
2,296.0
l.ll
10.05
2.39
19.24
0.146
900
6.67
't7.J
2.19
224 I
2.304.1
l.l I
l0.l I
2.39
2t 63
0 I50
474
EMISSION CALCIlLATIONS
,M
,M
,M
,M
0 Concentration, Srairl/dscf
0 Concentration, mg/dscm
0 Emission Rate, lb/hr
0 Emission Factor, lbA4MBtu (O2)
0 Emission Rate- lb/lViMscf fuel ca
(Cpvro)
(Cprrru)
(PMR)
(EFruro ozo)
(8R,.,,^)
0.00068
1.56
8.2E-02
l.08-03
I 4E+00
0.00036
0.834
4.tE-02
5.6E-04
7.2E'-0t
0.00042
0.960
4.2E-02
6.3E-04
6.3E-01
0.00049
t.t2
5.5E-02
'1.4E-04
9.38-01
PM
PM
PM
PM
PM
0 gm and >2.5 pm Concentration, grair/dscf
0 gm and >2.5 [m Concentration, mg/dscm
0 gm and >2.5 gm Emission Rate, lb/hr
0 pm and >2.5 pm Emission Factor, lbA,tMBtu (O2)
0 um and >2 5 um Emission Rate- lb,MMscf fuel ca
0 0000
0.000
0.08+00
0.08+00
0 0E+00
(cpuro-:s) 0.000018
(cpuro-z.s) o.o4o
(PMR) 2.l E-03
(EFpvro-: s or) 2.6E-05
(ER,^,,",.) 37E-O2
0.0000 0.0000058
0.000 0.013
0.0E+00 7.08-04
0.0E+00 8 8E-06
0 0E+00 t.2E-02
'M <2.5 Concentration, grain/dscf
'M <2.5 Concentration, mg/dscm
'M <2.5 Emission Rate, lb/hr
'M <2.5 Emission Factor, lbA4MBtu (O2)
'M <2 5 um Emission Rate- lbttr4Mscf fuel sm
0.00067
1.52
'1.9E-02
l.0E-03
l 4E+00
0.00036
0.814
4 tE-02
5.6E-04
7.2E-Ol
0.00042
0.960
4.2E-O2
6.3E-04
6.3E-0t
0.00048
I ll
5.4E-O2
't.3E-O4
9.2E41
(cplr: s)
(Cpu: s)
(PMR)
(EFpu:.r.:a)
GR".,,.)
HF Sinclair - West Bountiful, UTAST-2023- I 660-009
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TFCT] NICAI GROUP Source Test Repon
Testins Methodolosv
3.0 Testing Methodology
The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method
descriptions are provided below while quality assurance/quality control data is provided in Appendix D.
Table 3-l: Source Testing Methodology
3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Yolumetric Flow Rate
The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA
Reference Test Method l. To determine the minimum number of traverse points, the upstream and downstream
distances were equated into equivalent diameters and compared to Figure l-l in U.S. EPA Reference Test Method l.
Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the
average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement
system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type
thermocouple and pyrometer.
Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was
utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2.
3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide
The oxygen (O2) and carbon dioxide (COz) testing was conducted in accordance with U.S. EPA Reference Test
Method 3,dt. Data was collected online and reported in one-minute averages. The sampling system consisted of a
stainless-steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas
conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated
Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the
probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.6.
3.3 U.S. EPA Reference Test Method 4 - Moisture Content
The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The
gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a
known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on
the same balance to determine the amount of moisture condensed.
HF Sinclair - West Bountiful, UT
Full Velocity Traverses
Oxygen / Carbon Dioxide
Particulate Matter less than l0 Microns /
Particulate Matter less than
Mass Emission Factors
AST-2023- I 660-009
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A
i i .'\-)I),iir Source Tesl Reg),l
Testing Methodolow
3.4 U.S. EPA Conditional Test Method 039 - PMI0/PM2.5
The PMl0 and PM2.5 testing was conducted accordance with U.S. EPA Conditional Test Method 039 (CTM-039).
CTM-039 does not include drawing sample gas through impingers, but instead mixes the sample with dilution air in
a mixing chamber to replicate the dilution and cooling of the stack effluent in the atmosphere. The filterable and
condensable particulate matter is collected together (Section l.l ). The major components of the CTM-039 sampling
train are: in-stack PMl0 and PM2.5 cyclones; a heated sample probe; a pre-dilution tee and mixing cone; a mixing
(residence) chamber, two blowers and other ancillary equipment (Section 8.4).
Per Section 8.6 of CTM-039 the probe, sample venturi, and heated compartment temperatures are to be maintained
at least l0 degrees F above the stack gas temperatures; this is not feasible due to the high temperature ofthe stack.
The equipment was ran at as high of a temperature as manageable and all heated and unheated components were
recovered into the same sample fraction and analyzed together.
A PM2.5 cyclone is located after the PMl0 cyclone. Stack gas is extracted at a pre-determined constant sampling
rate to achieve near 100%o isokinetic sampling ratios through the in-stack PMl0 and PM2.5 cyclones. The cyclones
separate particles with nominal aerodynamic diameters of greater than l0 pm, less than lOpm and greater than 2.5
pm, and allow particles less than or equal to 2.5 pm and stack gases to continue through the heated sample probe
and heated sample venturi to be dituted and cooled in the mixing cone and residence chamber before being captured
by the 142-mm filter. Filtered, dehumidified, and temperature adjusted dilution air is added to the stack gas sample
(now containing only the particles of less than 2.5 pm) in a mixing cone. After mixing of the dilution air and stack
sample gas to allow for particulate condensation, PM2.5 is captured on a glass fiber filter bonded with
polytetrafluoroethylene (PFTE) (Section 2.0).
A preliminary velocity traverse was performed prior to the first run to verify the absence of cyclonic flow and
determine average velocity. A preliminary moisture run was conducted to target sampling conditions. Sampling was
conducted at multiple traverse points during each run. (Section 8.2). The sample train was operated as described in
Section 8.6 with data collected electronically (Sections 6.5.1 and 8.6.4.4). Each test consisted of three (3)
approximately 24O-minute runs. At the completion of each test run, a leak check of the non-diluted sample section
was done after removing the cyclones. The leak check was performed by attaching a vacuum pump to the mixing
chamber at the dilution air entrance. A vacuum was pulled to verif a leak rate of less than 0.02 cfm using the
rotameter on the front end of the vacuum pump (Section 8.5.1.2 and 8.6.4.6). The CTM-039 recovery of the 142-
mm filter and rinses were conducted as described in Section 8.7:
. Container No. I (Nozzle and Cyclone I)
o Great than PMl0 - optional
r Container No. 2 (Cyclones I and IV)
o PMl0 to PM2.5 acetone rinse
o Container No. 3 (Mixing Cone, Residence Chamber, and Filter Holder Inlet)
o less than PM2.5 water rinse
o Container No. 4 (Cyclone IV, Probe, Sample Venturi, Mixing Cone, Residence Chamber, Filter Holder Inlet)
o less than PM2.5 acetone rinse
r Container No. 5 (Filter)
o 142 mm filter
A sample train blank was not collected.
HF Sinclair - West Bountiful, UTAST-2023- I 660-009
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i i i.r
Source Test Report
Testing Methodologt
3.5 U.S. EPA Reference Test Method 19 - Mass Emission Factors
Fuel samples were procured and analyzed onsite by HF Sinclair. Samples were collected as close as possible to
each test run for each source. The laboratory analysis was used to calculate a dry Oz based F-Factor in accordance
with U.S. EPA Reference Test Method 19. The mass emission factor (lb/MMBtu) was calculated using the pollutant
concentration, O2 concentration and the calculated F-Factor.
3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3A
Cylinder calibration gases used met EPA Protocol I (+l- 2o/o) standards. Copies of all calibration gas certificates can
be found in the Quality Assurance/Quality Control Appendix.
Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Leve[ gas
concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated
for the High-Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases were
sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5o/o
absolute difference.
High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe and the
time required for the analyzer reading to reach 95 percent or 0.5o/o (whichever was less restrictive) of the gas
concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was
recorded. Next, Low Level gas was introduced at the probe and the time required for the analyzer reading to
decrease to a value within 5.0 percent or 0.5o/o (whichever was less restrictive) was recorded. If the Low-Level gas
was zero gas, the response was 0.57o or 5.0 percent ofthe upscale gas concentration (whichever was less restrictive).
The analyzer reading was observed until it reached a stable value and this value was recorded. The measurement
system response time and initial system bias were determined from these data. The System Bias was within 5.0
percent ofthe Calibration Span or 0.5o/o absolute difference.
High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the
analyzer response was stable, the value was recorded. Next, Low Level gas was introduced at the probe, and the
analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the
Calibration Span or 0.57o absolute difference or the data was invalidated and the Calibration Error Test and System
Bias were repeated.
Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.5%o absolute
difference. Ifthe drift exceeded 3 percent or 0.5oh, the Calibration Error Test and System Bias were repeated.
To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The
pollutant concentrations were measured at three points (16.7, 50.0 and 83.3 percent of the measurement line). Each
traverse point was sampled for a minimum of twice the system response time.
If the diluent concentration at each traverse point did not differ more than 5 percent or 0.3o/o (whichever was less
restrictive) ofthe average pollutant concentration, then single point sampling was conducted during the test runs. If
the pollutant concentration did not meet these specifications but differed less than l0 percent or 0.5%o from the
average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in diameter - 16.7, 50.0
and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter - 0.4, L0, and 2.0 meters from the
stack wall). Ifthe pollutant concentration differed by more than l0 percent or 0.5%o from the average concentration,
trla
HF Sinclair West Bountiful. UTAST-2023- l 660-009
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TECHNICAL GROUP fuurceTesl Repn
Testine MetWologt
then sampling was conduct€d at a minimum of twelve (12) taverse points. Copies of sfratification check data can
be found in the Quality Assurance/Quality Control Appendix.
A Data Acquisition System with battery backup was used to record the insfument response in one (l) minute
avorages. The data was continuously stored as a..CSV file in Excel format on the hard drive of a computer. At the
completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team
Leader before leaving fte facility. Once arriving at Alliance's office, all written and electronic data was
relinquished to the rcport coordinator and then a final review was performed by the Project Manager.
HF Sirclair - West Bountitul, UTAST-2023-166G,009
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TECI.{\IQAI- GROUP
Location; HF Sinclair Woods Cross Refining, LLC - Wesl Bountiful, UT
Source: BoilerNo. l0
Project No.: AST-2023-1660
Run No. /Method Run I / Method 3,A'
0z - Outlet Concentration (Cd, % dry
Co,= (Cou,-Co). ( #;)
where,
C*, ..1!1!!-: average aralyzer value during tesr, yo dry
Co 0.08 : average ofpretest & posttest zero resporises,% WCue 10.97 = actual concenttation of calibration gar',Yodry
Cr-il:i-: average of pretest & posttest calibration responses, o/o dry
Co, 4.43 : Oz Conoentration,96 dry
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Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful. UT
Source: BoilerNo. l0
Proj ect No. : !$!Q!l - !.66Q
Run No. /Method Run I / Method 3A
CO: - Outlet Concentration (C6s), 7o dry
Cco,: (Cou,-Cor- ( #e;)
where,
Co6. 9.15 : average analyzer value during test,o/odry
C"&=averageofpretest&posttestzeroresponses,o/odry
Cn,1o 10.80 :actualconcentrationofcalibration gas,o/odry
CM 10.78 : average ofpretest & posttest calibration responses, o/o dry
Cco, 9.17 : CO. Concentration,%o dry
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Location: HF Sinclair Woods Cross Refining,LLC - West Bountiful, UT
Appendix A
Example Calculations
Source: Boiler No. l0
Project No.: AST-2023-1660
Run No.: I
Parameter: VFR
Average Stack Gas Flow at Stack Conditions (Qa), acfm
Qa : 60x Vs x At
where,
Vs 35.8 = stack gas velocity, ftlsec
As 13. l0 : cross-sectional area ofslack, ft2
Qa 28,129 : acfm
Average Stack Gas Flow at Standard Conditions (Qs), dscfm
8s - 17.647x Qa x (l - BWS)" P'
Ts
Qa 28,129 = average stack gas flow at stack conditions, acfm
BWS 0.140 = moisture fraction, dimensionless
PrA= absolute stack gas pressure, in. Hg
Ts 792.7 : absolute stack temperature, "R
Qs 13,933 : dscfm
17 of 199
1: ''t\'; 'l
Conditional Test Method (CTM) 039
Example Hand Calculation QA
Facility: HF Sinclair Woods Cross Relining
Source: BoilerNo. l0
Run No.:
Test Date:8n2n023
Wt./Vol of Aetone Blank (mg/mL); Coraainer No.6
m o - Net Weight of Acetone Blonk (Contqiner No. 6), ng
V o - Voltme ofAcetone Blonk, mL
0.79 g cn3 - density ofacetone
Net Weight ofPM Due to Acetone, mgi Contairer No. 2
wa = 86.8 x 0.0063 we =0.54s
l'., : L'olume ofAcetone, mL
C " - Wt. Vol. ofAcetone Blank, mg ml.
Nea Weight of P8rticulate Matter (Blank Corrsted), mg; Container No. 2
l[2*o.. = 0-445 - 0.545 [2-"o". = 0.0000 mg
m 2 : Weight of Pafliculate Mauer (Container No. 2), hg
ll/ " = Nel Weight of PM Due to Acetone, mg
rFor csults reponed with negalive rcsuhs.0.0000 sas used fior the calculations
Net Weight ofPM Due to Acetone, mg; Contain€r No. 4
wr = l9l.f x 0.0063 wa = 0.790*
V ,, : Volume of Acetone, mL
C " .- Wt. l/ol. of Acetone Blank, mg mL
'frax allor'ab le sub truct ion
Net Weight of Particulate Matter (Blank Corrsted), mgi Contsiner No. 4
[+co" = 1.39 - 0.790 [2-"o"" =0.600
m ! = Weighl of Pqrliculqte Mqrler ((:onlainer No. t), mg
W . = Net Weight of PM DLe to Acetone, mg
*For resulb rcpoied w-ilh negrtiye rcsult3.0-0000 $s used for the calculations
Wt./Vol of DI Wrter Blatrk (mg/mL); Cortainer No. 7
Cr=C-=
^ l.t9L' 239.7 * o.7g
Lr - 0.0063 mg/mL
0.0052 my'mr-
t.4s
276.7
V"
- Net Weight ofAcetone Blank (Container No. 6), mg
- Volume ofAcetone Blqnk, mL
l8ofl99
ArmrpEr
-t
Conditional Test Method (CTM) 039
Example Hand Calculation QA
Facility: HF Sinclair Woods Cross Refining
Source: BoilerNo. l0
Run No.:
Test Date:anzno23
Net Weight of PM Due to DI Water, mg; Container No. 3
ww= 185.9 x 0.0052 ww = 0.974 ms
V., = Volune of DI Woter, ml-
C . : llr. Vol. of Dl lltater Blank, ng ml
Net Weight of Particulat€ Matter (Blank Correted), mg; Container No. 3
Dj-"o""= 1.13 - 0.974 IIl3-"o"" = 0.156 mg
m j - lleight of Particulote Matter (Contoiner No. 3), mg
W * - Net Weight of PM Drc to Dl llater, mg
'For results rcpo(ed rvith nogatiYe resulls. 0.0000 \rd used for th€ calculations
Conentration (mg/dscm)
LPMIo -
(0.0000 + 0.156 + 0.600 + 1.07)cPruto = 0.834 m8/dscm2.19
(l p.rtto Pailiculdte concenffqlion (ng dsch)
m2<on-ContqinerNo.2Mass-PM.l0lman.l:'2.5 qm(AcetoneRinse):NetWeightofPar,icilldteMattet(BlqnkCorrected),mg
m),oE-ContqinqNo.3Mqss-PM:2.5ym(DIRinse):NetWeightofPqrriculoteMqrter(DlWaterBlankCorrected),mg
m a-.oft - Container No. -t Mass - PM --2.5 pm (Acetone Rinse): Nel Weight of Poiliculate Mqtter (Acetone Bldnk Conected), mg
mi = Contqiner No. 5 Mass - PM ,.2.5 ln (F iher): Weighr of Pdrticuldte Motter, mg
V ",o4 - Sample voluile al stdnddrd conclitions (nt I
Emission Rate (lb/MMBtu)
D
Lttttt
-
c,rro 20.9v L ?-
(zo.o - or)PM to - 3s .3147 x 4s3,sg}
E r^r,o Emission rdle (lb,MMBlu)
C p111n - Pollulant concentrution (mg dscm)
Fd = DryO2 bosedF Factor(lscfMMBtu)
O 2 = Slack gas oxygen concenlrotion (o%vd)
x 8,287.6 X0.83 20.9Epuro =
3s.3147 X 453,592
l9 of 199
(2O.9 - 4.921
Eprrro = 5.68-04 tb/rvtMBtu
EAIilalpEr'1 i:i, rl r{ !{) Al {;':i{'1 l: rl
Conditional Test Method (CTM) 039
Example Hand Calculation QA
Facility: HF Sinclair Woods Cross Refining
Source: BoilerNo. l0
Run No.:
Test Date:aDzDO23
M pilfi : Emission rate (lb hr)
C pwo : Pollutant concentrqtion (mg dscm)
Q s = Stack gasflov rote (dscfm)
60 = Minutes per hour
f,f, _ 0.E34 X l3,l19x 60
35.3147 X 4s3,592
Emision Rate (lb/MMscf)
Emirsion Rate (lb/hr)
Ero, C'Y+::
-
xQ"ax 60ro 35 3:,47 x 453 ,592 ^ Y
ER ,r ro = M pu to * Fuel- -flow
Mpuro = 4.lt-02 lb/hr
ERpruro = 7.28-01 lb/MMscf
106
Epnlo =
ER p11p - Emission rate (b MMscl)
M p.\t!o - Emission rate (lb hr)
F-uel Flot - Fuel gas flot, rote (scJh)
4.1E.42 I 56,790
1,000,000
20 of 199
ocT 2 0 2023
2l of 199
{:r-lfd fi*"t_ GirfiL; r
Emission Calculations
Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
so,.ceT6iiiif6]J6-
P.o.lect No.
lun Number Runl Run2 Run3 Averase
)ate
itart Time
itop Time
lun Time, mrn (e)
8t22t23
I 0:56
I 5:08
240.0
8t22t23
l6:47
2l:13
239.8
8/23123
l0:22
14.44
240.0 239.9
INPTTT DATA
Fuel Gas Flow Rate, scfh
Heat [nput, MMBtr/hr
Fuel Factor (O2 dry), dscf/MMBtu
Barometric Pressure, in. Hg
Meter Correction Factor
Nozzle Diameter, in
Area of Nozzle. ft2
Total Mass of PMl0 ;rm, mg (ml + mr + mr + mj)
Total Mass of PM <10 pm and >2.5 pm, mg (m2)
Total Mass of PM <2.5 [m, mg (ml + m4 + mi)
60, I 70
53.79
8,263
25.82
t t42
0.253
0.00035
2.49
0.030
2.46
(FR)
(HD
(Fd)
(Pb)
(Y)
(Dn)
(An)
(mpuro)
(mpvr,r,: s)
(mo.r.)
56,750
48.07
8,288
25 87
t t42
0.240
0 0003 1
3.49
0 089
340
56,790
48 10
8,288
25.79
I.t42
0.260
0.00037
183
0.000
1.83
66,970
65.2t
8,2t3
2s 8r
t.142
0 260
0 00037
2.16
0.000
2.16
CTM-039 I,OGGER DATA
Dilution Flow Rate, dscfm
Sample Flow Rate, dscfm
Volume Sampled, dscf
Volume Sampled, dscm
Viscosity
Reynolds Number
Cunningham Correction Factor
Particulate Cut Diameter for PM l0
Particulate Cut Diameter for PM2.5
Dilution Ratio
Moisture Fraclion Measured
lsokinetic Sampling Rate, (%)
5.98
0.327
785
2.22
226.7
) )oAr],
lu
10 05
2.39
t9.24
0.146
900
(Qqoo)
(Qq"ay)
(V.i*o)
(Vn*o)
(u)
(N,.)
(c)
(Dso)
(Ds,,)
(DR)
(BWSmsd)
(l)
428
0.328
788
: l)
230 0
2,231.5
t ll
t0 l4
246
14.03
0.140
984
6.67
0.322
77.3
2.19
224.8
2.304.1
l.ll
l0 lI
2.39
2t.63
0.150
874
6.98
0 331
79.3
225
225 4
)7\11
l ll
9.89
232
22.07
0 t17
843
EMISSION CALCULATIONS
)M I 0 Concentration, grainldscf
)M I 0 Concentration, mg/dscm
)Ml0 Emission Rate, lb/hr
)M l0 Emission Factor, lb/Ir4MBtu (O2)
)M l0 Emission Rate, lb/MMscf fuel gas
(Cpurn)
(Cpvro)
(PMR)
(EFpu ro o:o)
(ERpv,n)
0 00068
1.56
8 2E-02
l.0E-03
I 4E+00
0 00036
0 834
4.tE-02
5 6E-04
7 2F,-01
0.00042
0 960
4.2E-02
6 3E-04
6.3E-01
0.00049
t.t2
5.5E-02
7.4E-04
9.3E-01
PM<
PM<
PM<
PM<
PM<
0 pm and >2.5 pm Concentration, grain/dscf
0 pm and >2.5 pm Concentration, mg/dscm
0 pm and >2.5 pm Emission Rate, IbArr
0 pm and >2.5 pm Emission Factor, lb/MMBtu (O2)
0 pm and >2.5 pm Emission Rate, lb.MMscf fuel gas
(Cruro-: s) 0.00001 g
(Cpvru,z.s) o.o4o
(PMR) 2.lE-03
(EFpy111.' 5s'3) 2.6E-05
(ERpMu-,,) 3.7E-02
0 0000
0.000
0.08+00
0.0E+00
0 0E+00
0.0000
0 000
0.0E+00
0.0E+00
0.08+00
0.0000058
0 013
7.0E-04
8.8E-06
t 2E-02
(Cpu: s)
(Cpv: s)
(PMR)
(EFPM2 5 o2d)
(ERpv: s)
0 00067
1.52
7.9E-02
l 0E-03
I 4E+00
0.00036
0 834
4.tE-02
5 68-04
7.2E-0t
0 00042
0.960
4.28-02
6.38-04
6 38-0t
0.00048
tu
5.4E-02
7 3E-04
9 2E-01
)M <2.5 Concentration, grain/dscf
)M <2.5 Concentration, mg/dscm
)M <2.5 Emission Rate, lb/hr
)M <2.5 Emission Factor, lb/MMBtu (O2)
)M <2.5 pm Emission Rate, lb/MMscf fuel gas
22 of 199
HF Sinclair Woods Crcss Refining LLC
West Boutiful, UT Lab Data Boiler No. l0
Aug6t 22 & 23,2023
Run I Run 2 Run 3
lontainer No. I Mass - PllI >10 um
iample No.
ileight of Particulate Matter, mg (mr)
y'olume of Acetone, mL (V.)
{et Weight of Acetone Blank (Container No. 6), mg (m")
y'olume of Acetone Blank, mL (V")
ilt./Vol. of Acetone Blank, mg/ml (c,)
{et Weight of PM Due to Acetone, mg (W")
.let Weight of Particulate Matter (Blank Corrected), mg
140-33466-t
0.575
87.4
l.l9
239.7
0.0063
0.549
0.026
140-33466-6
0.26s
7t,o
1.19
239.7
0.0063
0.446
0.0000
140.33466-l I
0.530
96.9
1.19
239.7
0.0063
0.609
0.0000
Container No. 2 Mass - PM <10 um and >2.5 um
Sample No.
Weight of Particulate Matter, mg (mz)
Volume of Acetone, mL (V",)
Net Weight of Acetone Blank (Container No. 6), mg (m")
Volume of Acetone Blank, mL (V")
Wt.iVol. of Acetone Blank, mg/ml (c")
Net Weight of PM Due to Acetone, mg (W")
Net Weight of Particulate Matter (Blank Corrected), mg
14u33466-2
0.440
55.8
l.l9
239.7
0.0063
0.3s1
0.089
140-33466-7
0.445
86.8
l.l9
239.7
0.0063
0.545
0.0000
140-33466-12
0.0400
32.5
l.l9
239.7
0.0063
0,204
0.0000
Container No.3 Mass - PM <2.5 !m
Sample No.
Weight of Particulate Matter, mg (ml)
Volume of DI Water, mL (V,,,)
Net Weight of DI Water Blank (Container No. 7), mg (m,,)
Volume of DI Water Blank, mL (V,,)
Wt./Vol. of DI Water Blank, mg/ml (c,,)
Net Weight of PM Due to DI Water, mg (W,,)
Net Weight of Particulate Matter (Blank Correcled), mg
140-33466-3
l.8l
193.4
1.45
276.7
0.0052
1.013
0.797
140-33466-8
1.13
185.9
l.4s
276,7
0.00s2
0.971
0.156
14G33466-13
1.56
176.1
t.4s
276.7
0.0052
0.923
0.637
Container No.4 Mass - PM <2.5 um
Sample No.
Weight of Particulate Matter, mg (mr)
VolumeofAcetone, mL (V*)
Net Weight of Acetone Blank (Container No. 6), mg (m,)
Volume of Acetone Blank, mL (V")
Wt./Vol. of Acetone Blank, mg/ml (c")
Net Weight of PM Due to Acetone, mg (W")
Net Weight of Particulate Matter (Blank Corrected). ms
14u33466.4
2.48
225.3
l.l9
239.7
0.0063
0.790
1.69
140-33466-9
1.39
191.1
l.l9
239.7
0.0063
0.790
0.600
140-33466-14
1.24
201.2
1.19
239.7
0.0063
0.790
0.45
lontainer No.5 Mass - PM <2.5 um
iample No.
ileight of Particulate Mafter, mg (ms)
14G.33466-5
0.9r 0
140.33466-10
1.07
14G.33466-ls
1.07
Note l: For results reported with negative results, 0.0000 was used for the calculations
Note 2: Regent Blanks from 5/16/23
23 of 199
r:Alibrrce
IL( iN LAL (,FOU;'
Volumetric Flow Rate Data
Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Source Boiler No. l0
Project No. AST-2023-1660
Parameter PM (CTM-039)
Run Number Runl Run2 Run3 Average
Date
Start Time
Stop Time
Run Time, min
8t22/23
l0:56
l5:08
240.0
8t22t23
l6:47
2l:13
239.8
8123123
l0:22
l4:44
240.0 239.9
CALCULATED DATA
Pitot Tube Coefficient
Barometric Pressure, in. Hg
Static Pressure, in. WC
Stack Pressure, in. Hg
Stack Cross-sectional Area, ft2
Temperature, oF
Temperature, oR
Moisture Fraction
CO2 Concentration,%o
02 Concentration, 7o
Molecular Weight, lb/lb-mole (dry)
Molecular Weight, lb/lb-mole (wet)
Velocity. fVsec
(cp)
(Pb)
(Pe)
(Ps)
(As)
(Ts)
(Ts)
(BWS)
(Coz)
(oz)
(Md)
(Ms)
(vs)
0.76r
25.87
-0.r I
25.86
1 3.10
332.7
792.7
0.140
9.17
4.43
29.64
27.46
35.8
0.761
25.79
-0.10
25.79
I 3.10
331.6
791.6
0.150
8.75
4.92
29.60
27.89
34.2
0.761
25.8t
-0. l5
25.80
13. l0
333.4
793.4
0.147
8.90
4.45
29.60
27.93
30.5
0.761
25.82
-0.12
25.82
13. l0
332.6
792.6
0.146
8.94
4.60
29.61
27.76
33.5
VOLUMETRIC FLOW RATE
A.t Stack Conditions, acfm
4.t Standard Conditions, dscfm
28,129
13,933
(Qa)
(Qs)
26,848
l3,l 19
24,010
I 1,753
26,329
12,935
24 of 199
AlffirceTtfitiNtc&L otr4{}ils Cyclonic FIow Check
Location HF Sinclair Woods Cross Refinins. LLC - West Bountiful. UT
Source Boiler No. l0
Project No. ,4.5T-2023-1660
Date 8122/23
Sample Point Angle (AP=0)
I
2
3
4
5
6
7
8
9
l0
1l
t2
l3
t4
l5
r6
Averaqe
0
5
5
5
l0
l0
l0
5
5
5
5
l0
l0
l5
l0
5
7.2
25 of 199
I!yAIiarEe
TI'C,INI.CAL CHOU ]
Method 4Data
Location HF Sinclair Woods Cross Refinins. LLC - West Bountiful. UT
Source Boiler No. l0
Project No. AST-2023-1660
Parameter(s) Moisture
Console Units
Run No.
Date
;tatus
itart Time
0nd Time
Run Time, min (0)
Vleter II)
1
8t22/23
VALID
9:45
l0:30
60
MB-704
Vleter Correction Factor (Y)
)rifice Calibration Value (AH @)
VIax Vacuum, in, Hg
Post Lak Chmk. ft3lmin (at max vrc.)
0.992
1.860
5
001 (4 5
Meter Volume, ft3
0
5
l0
l5
20
25
30
35
40
45
Total Meter Volume. ft3 (Vm)
4s4.656
457.720
460.785
463.780
466.885
470.015
473.025
476.025
479.045
482 395
27.739
Temperature, oF
0
5
t0
15
20
25
30
35
40
45
AverageTemperature,oF (Tm)
AverageTemperature,oR (Tm)
Minimum Temperature, oF
Maximum TemDerature. oF
Meter
87
8l
72
72
70
70
70
7l
70
70
533
70
87
Probe Filter Vacuum
4
5
5
5
5
5
5
5
5
5
5
4
5
Imp. Exit
65
66
65
65
63
63
62
63
63
63
64
62
66
Barometric Pressure, in. Hg (Pb)
Meter Orifice Pressure, in. WC (AH)
Meter Pressurg in. Hg (Pm)
Standard Meter Volume. ft3 (Vmstd)
2s.90
0 600
25.94
23.623
Analysis Type
Impinger I, Pre/Post Test, g
Impinger 2, Pre/Post Test, g
Impinger 3, Pre/Post Test, g
Impinger 4, Pre/Post Test, g
Volume Water Collected, mL (VIc)
Standard Water Volumg ftr (Vwstd)
Moisture Fraction Measured (BWS)
Gas Molecular \ileight, lbflb-mole (dry) (Md)
DGM Calibration Check Value (Yor)
Gravimetric
H20
H20
Empty
Silica
482.1
407.4
249.1
510.4
532.9
426.8
2s4.1
517.5
50.8
t9.4
5.0
7.1
82.3
3.881
0 14l
29.64
0.8
26 of 199
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Em issions Calculations
Alffirpe Location HF Sinclair woods cross Refining ,LLC -west Bountiful, UTT t-{l 1l f", rcA } {} F] ()tJ :;
Source BoilerNo. l0
Project No. AST-2023- 1660
Run Number Runl Run2 Run3 Averase
Date
Start Time
Stop Time
8122123
l0:5 I
l5:09
8t22t23 8t23t23
16:42 10:15
2l:14 14:39
Calculated Data - Outlet
)z Concentration, %o dry co, 4.43 4.92 4.45 4.60
3Oz Concentration, 7o dry cco, 9.17 8.75 8.90 8.94
lllofl99
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TTCH'!,JCAL GROLJP
Runl-RMData
Location: HF Sinclair Woods Cross Refinin LLC - West Bountiful. UT
Source: Boiler No. l0
Projcct No.: AST-2023-1660
Date: 8122123
Time
Unit
Status
Or - Outlet COr - Outletohdry Y"dry
Valid Valid
l0:51
l0:52
l0:53
l0:54
l0:55
l0:56
l0:57
I 0:58
l0:59
I l:00
I l:01
I l:02
I l:03
I l:04
I l:05
I l:06
I l:07
I l:08
I l:09
I l:10
ll:ll
ll:12
ll:13
ll:14
ll:15
ll:16
ll:17
ll:18
I l:19
I l:20
ll:21
ll:22
I l:23
ll:24
|.25
ll:26
ll:27
I l:28
ll:29
I l:30
ll:31
ll:32
I l:33
I l:34
I l:35
I l:36
I l:37
I l:38
I l:39
I l:40
I l:41
I l:42
I l:43
ll:44
I l:45
I l:46
ll:47
I l:48
I l:49
I l:50
I l:51
ll:52
I l:53
I l2 of 199
2.93
3.39
3. l9
3.40
3.l s
3.09
3.31
3.28
3.26
3.09
3.29
3.46
3.33
3. l5
3.30
3.33
3.25
3. t6
3.44
3.7 t
3.5 t
3.78
3.49
3.90
4.07
4.43
4.59
4.85
4.84
4.66
5.64
4.',73
4.U
4.07
3.96
4.12
4.06
4.38
4,35
3.9
4.12
3.85
3.63
3.45
3.89
3.98
3.',12
3.92
3.91
3.80
3.70
3.88
3.84
4.08
4.1 I
3.93
3.56
4.01
3.88
4.04
3.80
4.00
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10.04
9.90
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10.04
10.23
10.10
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10.05
10.l8
10.07
10.04
10.08
10.13
9.96
9.77
9.93
9.73
9.89
9.7 5
9.65
9.37
9.22
9.09
9.09
9.18
8.64
9.tI
9.23
9.44
9.48
9.4s
9.50
9.34
9.37
9,5s
9.46
9.61
9.71
9.82
9.56
9.54
9.69
9.55
9.58
9.64
9.69
9.54
9.s8
9.45
9.44
9.54
9.78
9.50
9.57
9.50
9.62
9.52
9.5 t
*2AIiarEe
TECHNICT\L. GfqtflJP
L*"tioot
Snrrce' RnilerNn lO
Runl-RMData
Project No.: AST-2023-1660
Dzte:812223
Time
Unit
Status
O: - Outlet COz - Outlet
"/"dry "/odryValid Valid
I l:54
I l:55
I l:56
I l:57
I l:58
I l:59
l2:00
l2:01
12:02
l2:03
l2:04
l2:05
l2:06
l2:07
l2:08
l2:09
l2:10
l2:ll
12:12
l2: l3
12:14
l2:15
12:16
12:17
l2:1 8
l2:19
l2:20
l2:21
l2:22
l2:23
l2:24
l2:25
l2:26
l2:27
l2:28
l2:29
l2:30
l2:31
l2:32
l2:33
l2:34
l2:35
l2:36
12:37
l2:38
12:39
l2:40
12:41
12:42
12:43
12:44
12:45
l2:46
12:47
12:48
12:49
12:50
12:51
12:52
12:53
12:54
l2:55
l2:56
I 13 of 199
3.79
4.05
3.86
4.t3
4.18
4.07
3.8',1
4.25
4.06
4.t9
4.09
4.58
4.52
4.67
4.s2
4.28
4.29
4.51
4.34
4.44
4.47
4.37
4.55
4.7 |
4.97
4.70
4.91
4.81
5.09
4.54
4.99
s.02
4.93
5.05
5.15
5.06
5.36
5.21
5.01
5. l9
5.21
5.23
5.09
5.22
5.13
4.78
4.91
4.84
4.66
4.6s
4.98
4.6t
4.79
4.62
4.70
4.73
4.88
4.65
4,89
s.07
5.01
4.93
5.0t
9.61
9.47
9.57
9.43
9.42
9.48
9.59
9.39
9.47
9.39
9.44
9.21
9.20
9.12
9.23
9.34
9.35
9.21
9.25
9. l6
9.14
9.22
9.1 I
9.03
8.85
8.98
8.85
8.94
8.77
9.05
8.84
8.80
8.84
8.7 t
8.69
8.77
8.62
8.67
8.76
8.69
8.69
8.68
8.76
8.70
8.73
8.95
8.87
8.92
8.99
9.03
8.84
9.03
8.97
9.0s
9.02
8.99
8.85
8.93
8.85
8.72
8.'.tz
8.77
8.77
Runl-RMData
AIffiIrc.B'T i: c l--'l N ic A t- $ H
l,ocation: HnsinclairwoodsCrossRefiningLLC-westBountitul'ur
Sor.aa,ffi
Project No.: AST-2023-1660
Drftt 8n2D3
Or - Outlet COr - Outlel
Y"dry Yodry
Valid Valid
Time
Unit
Status
t2.57
l3:08
l3:09
l3:10
l3:ll
l3: l2
l3: l3
I 3:14
l3:15
I 3:16
l3:17
l 3:18
l3: l9
l3:20
l3:21
l3:22
l3:23
l3:24
13.25
l3:26
13.27
l3:28
l3:29
l3:30
l3:31
l3:32
l3:33
13.34
l3:35
l3:36
t3.37
l3:38
l3:39
l3:40
l3:41
l3:42
l3:43
13.44
l3:45
l3:46
l3:47
l3:48
l3:49
l3:50
l3:51
l3:52
I 3:53
I 3:54
l3:55
l3:56
l3:57
l3:58
l3:59
14:00
l4:01
l4:02
l4:03
l4:04
l4:05
I 4:06
l4:07
l4:08
l4:09
I l4 of 199
5. l4
5.06
5.0t
4.97
5.04
5.07
4.78
4.95
4.93
4.83
4.82
5.1 I
4.84
5.04
4.87
5.1 I
4.91
5.t7
5.15
4.99
4.76
4.97
5.03
4.88
4.95
4.83
4.88
4.56
4.67
4.61
4.50
4.28
4.67
4.55
4.63
4.63
4.46
4.26
4.47
4.74
4.45
4.74
4.38
4.77
4.79
4.50
4.76
4.54
4.73
4.39
4.53
4.34
4.07
3.84
4.01
4.35
4.24
4.20
4.56
4.31
4.57
4.54
4.44
8.69
8.69
8.'12
8.72
8.70
8.70
8.85
8.78
8.79
8.84
8.84
8.67
8.83
8.71
8.80
8,66
8.76
8.63
8.64
8.74
8.86
8.77
8.73
8.82
8.78
8.88
8.86
9.04
8.99
9.04
9.08
9.20
9.03
9. l0
9.06
9.06
9.14
9.24
9.14
9.00
9.t6
9.01
9.t9
9.01
9.00
9.15
9.03
9. l5
9.05
9.24
9.17
9.29
9.43
9.56
9.49
9.29
9.33
9.36
9.17
9.27
9. l6
9.13
9.t5
#AIibTpe
T r c i-"1 N lc A L G ff ', lJ p
mdsCrossRefinins.LlC-westBountitul.ur
Run 1- RM Data
Source: Boiler No. l0
Project No.: AST-2023-1660
D^tet 8122123
Time
Unit
Status
Or - Outlet COr - Outlet
"/"dry "hdryValid Valid
l4:10
l4:ll
l4:12
l4:1 3
l4:14
l4:15
l4:16
l4:17
l4:18
l4:19
l4:20
l4:21
l4:22
l4:23
l4:24
l4:25
l4:26
l4:27
l4:28
l4:29
l4:30
l4:31
l4:32
14.33
14.34
l4:35
l4:36
l4:37
l4:38
l4:39
l4:40
l4:41
l4:42
l4:43
l4:44
l4:45
14.46
l4:47
14.48
14.49
14:50
l4:51
l4:52
l4:53
t4'.54
l4:55
l4:56
l4:57
l4:58
l4:59
l5:00
l5:01
l5:02
l5:03
l5:04
l5:05
l5:06
l5:07
l5:08
4.23
4.09
4.64
4.66
4.57
4.51
4.7 5
4.53
4.55
4.57
4.76
4.70
4.42
4.',II
4.42
4.73
4.7 5
4.35
4.68
4.63
4.54
4.20
4.49
4.54
4.20
4.50
4.53
4.47
4.31
4.14
4.72
4.39
4.68
4.47
4.72
4.74
4.53
4.82
4.55
4.57
4.63
4.65
4.56
4.37
4.67
4.87
5.09
5.51
s.42
5.74
5.85
5.60
5.80
5.7 5
5.52
5.09
4.81
4.99
s02
9.23
9.29
9.04
9.00
9.08
9. l0
8.95
9.08
9.04
9.05
8.93
8.95
9.1 I
8.92
9.09
8.94
8.93
9. l3
8.96
8.98
9.02
9.19
9.06
9.04
9.20
9.05
9.02
9.03
9.13
9.21
8.93
9.09
8.96
9.06
8.92
8.91
9.03
8.89
9.00
9.01
8.99
8.98
9.02
9.07
8.95
8.85
8.80
8.57
8.57
8.38
8.30
8.39
8.27
8.31
8.44
8.65
8.83
8.73
876
ll5ofl99
anlmncxe
Y E c H hl i{) A l'- {} rq o t'
l-*rnon, HFsinclairwmdscrossRefinins,LLC-westBountitul.UT
Run 1- RM Data
Source: BoilerNo. l0
Project No.: AST-2023-1660
D*e:822123
ValidValid
Time
Unit
Status
Or - Outlet COr - Outlet
"/"dry "/.dry
Uncorrected Run Aversge (Cob,)
Cal Gas Concentration (CM^)
Pretest System Zero Response
Posttest System Z€ro Response
Average Z€ro Response (Co)
Pretest System Cal Response
Postt€st System Cal Response
Average Cal Response (Cy)
Corrected Run
4.48
10.97
0.09
0.06
0.08
10.97
10.96
10.97
4.43
9.t5
10.80
0.01
0.02
0.02
10.79
10.77
10.78
9.17
I l6 of 199
alImrpe.IEC'--INiQAI* $q(}LJil
Run2-RMData
Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Source: BoilerNo. l0
Project No.: 4ST202l:! 660
Date:8122123
Time
Unit
Status
Or - Outlet CO: - Outlet
"/"dry "hdryValid Valid
l6:42
l6:43
l6:44
l6:45
l6:46
l6:47
l6:48
l6:49
l6:50
l6:51
l6:52
I 6:53
16.s4
l6:55
l6:56
l6:5'l
l6:58
l6:59
l7:00
l7:01
17:02
l7:03
17:04
l7:05
17:06
17:07
l7:08
l7:09
l7:10
l7:l I
l'l:12
17:13
l7:14
l7: l5
l7: l6
l7:17
l7: l8
17:19
t7.20
17:21
17:22
17:23
17:24
17:25
17:26
17:27
17.28
17:29
l7:30
17:31
17:32
17:33
17:34
17:35
l'1:36
11:37
l7:38
11 .39
17.40
17:41
17:42
17:43
17:44
ll7ofl99
4.94
4.',79
4.60
4.58
4.92
4.92
4.7'l
4.85
4.93
4.92
4.61
4.95
4.74
4.80
4.89
4.89
4.76
4.72
5.05
4.81
4.96
4.91
4.81
5.07
4.76
5.03
5.02
4.94
4.75
4.84
5.08
4.89
4.90
4.95
4.69
4.83
4.87
4.81
4.73
4.97
4.91
4.98
4.79
4.97
4.80
5.02
4.93
4.74
5.20
5.55
5.56
5.43
5.86
s.94
5.7 5
5.81
5.78
5.61
5.68
5.60
5.44
5.12
5.23
8.82
8.89
8.97
9.02
8.84
8.83
8.91
8.87
8.82
8.80
8.95
8.80
8.89
8.87
8.81
8.82
8.90
8.94
8.76
8.87
8.79
8.81
8.87
8.72
8.87
8.74
8.7s
8.80
8.90
8.86
8.74
8.81
8.83
8.77
8.93
8.85
8.83
8.83
8.90
8.76
8.80
8.75
8.84
8.72
8.83
8.74
8.78
8.89
8.6',1
8.50
8.48
8.51
8.27
8.20
8.29
8.26
8.26
8.35
8.33
8.38
8.44
8.60
8.60
RIIffirrce
TfrilI-{'T]CAL GROUP
Location: HF Sinclair Woods Cross Refinins. LLC - West Bountiful. UT
Run2-RMData
Source: Boiler No. l0
Project No.:AST-2023-1660
D.tet 8122/23
Time
Unit
Status
Or - Outlet COr - Outlet
"hdry "/"dry
Valid Valid
17 .45
17:46
t7 .47
17:48
17:49
I 7:50
17:51
17:52
17:53
l7:54
l7:55
l7:56
17:57
I 7:58
17:59
I 8:00
l8:01
l8:02
l8:03
l8:04
l8:05
l8:06
18:07
18:08
18:09
18: l0
l8:l I
l8:12
1 8:13
l 8:14
l8:15
l8:16
l8:17
l8:18
l8:19
l8:20
l8:21
l8:22
l8:23
l8:24
l8:25
l8:26
l8:27
l8:28
I 8:29
l8:30
l8:31
I 8:32
l8:33
I 8:34
l8:35
I 8:36
18:37
18:38
18:39
l8:40
l8:41
18:42
l8:43
18:44
l8:45
18:46
18:47
ll8ofl99
5. l8
5. l3
4.99
s.08
4.96
4.88
5.03
4.90
4.85
5.03
4.84
5.03
5.05
4.95
4.74
4.90
5.05
4.94
5.07
4.92
5.04
4.95
5.09
4.83
4.87
5.00
4.93
4.7 5
4.5s
4.98
4.79
5.03
4.84
5.01
5.01
4.78
4.98
4.95
4.76
4.92
4.69
4.86
4.87
4.80
4.61
4.7 5
5,01
4.83
4.97
4.86
4.99
4.70
4.92
4.95
4.88
4.69
4.78
5.03
4.82
5.03
4.79
4.95
4.86
8.62
8.69
8.75
8.71
8.76
8.81
8.70
8.77
8.82
8.72
8.83
8.7 5
8.74
8.78
8.84
8.78
8.68
8.75
8.71
8.80
8.73
8.79
8.72
8.84
8.85
8.78
8.80
8.86
8.97
8.73
8.84
8.74
8.84
8.75
8.76
8.87
8.77
8.78
8.88
8.19
8.91
8.84
8.83
8.87
8,96
8.90
8.76
8.86
8.76
8.82
8.7 5
8.89
8.81
8.78
8.81
8.90
8.89
8.75
8.84
8.73
8.86
8.75
8.81
d Run 2 - RM DataAIATEe
T [: c l"j hl : c A l'- G fi
l,ocation: HF Sinclair woods cross Refining, LLC - west Bountitul, UT
Soua"",
Project No.: AST-2023-1660
Date:8122123
Or - Outlet COr - Outlet
Y.dry Y.dry
Valid Valid
Time
Unit
Strtus
l8:48
l8:49
l8:50
l8:51
l8:52
l8:53
l8:54
I 8:55
I 8:56
I 8:57
I 8:58
I 8:59
l9:00
l9:01
l9:02
l9:03
l9:04
l9:05
l9:06
l9:07
l9:08
l9:09
l9: l0
l9:ll
19:12
l9:13
l9: l4
l9:15
l9: l6
l9:17
l9: l8
l9: l9
l9:20
19:21
l9:22
t9.23
19:24
19:25
19:26
19:27
19:28
19:29
l9:30
l9:31
19:32
l9:33
19:34
19:35
19:36
19:37
l9:38
l9:39
19:40
19:41
19:42
l9:43
19:44
19:45
19:46
19:47
l9:48
19:49
l9:50
I l9 of 199
4.68
4.84
4.80
s.0l
4.80
4.98
4.68
4.90
4.91
4.81
4.55
4.87
4.91
4.7 |
4.90
4.7 s
4.92
4.7 t
4.96
4.98
4.77
4.95
4.92
4.64
4.87
4.89
4.84
4.68
4.69
5.03
4.79
4.92
4.79
4.92
4.77
4.77
4.75
4.87
4.88
4.96
4.93
5. l0
4.82
4.',71
4.80
4.67
4.85
4.89
4.81
4.46
4.72
4.7 5
4.72
4.77
4.60
4.90
4.76
4.98
4.78
4.80
4.96
4.92
4.78
8.90
8.84
8.8s
8.73
8.85
8.76
8.92
8.81
8.81
8.85
8.97
8.82
8.78
8.90
8.80
8.88
8.79
8.89
8.79
8.76
8.87
8.78
8.78
8.92
8.82
8.82
8.83
8.91
8.92
8.75
8.86
8.?8
8.87
8.79
8.83
8.86
8.87
8.83
8.84
8.81
8.82
8.74
8.88
8.92
8.89
8.94
8.85
8.84
8.89
9.05
8.94
8.92
8.94
8.92
9.00
8.88
8.93
8.82
8.91
8.91
8.83
8.84
8.91
#AlAlEEr-r E c H N l(]A L' $ fito u
?o.rnon, HFsinclairwoodscrossRefining.LLc-westBountitut,ur
Run2-RMData
Source: BoilerNo. l0
Project No.: AST-2023-1660
Date:8/22/23
Time
Unit
Status
Or - Outlet COr - Outlet
T,dry "hdryValid Valid
l9:51
l9:52
l9:53
19.54
l9:55
1956
19:57
l9:58
l9:59
20:00
20:01
20:02
20'.03
20:04
20:05
20:06
20:07
20:08
20:09
20: l0
20:1 I
20:12
20: l3
20:14
20:15
20:16
20:17
20: l8
20.19
20:20
20:21
20:22
20:23
20:24
20:25
20:26
20:27
20:28
20:29
20:30
20:31
20:32
20:33
20:34
20:35
20:36
20:37
20:38
20:39
20:40
20:41
20:42
20:43
20:44
20:45
20.46
20:47
20:48
20:49
20:50
20:51
20.52
20.53
120 of 199
4.59
4.91
4.95
4.78
4.78
4.82
4.84
4.67
4.54
4.72
4.88
4.68
4.94
4.88
4.88
5.60
5.59
5.61
5.86
5.89
5.62
5.53
5.',|2
5.21
4.4s
3.80
3.95
4.58
5.10
4.89
4.56
4.29
4.49
4.42
4.92
4.82
4.53
4.20
4.t2
4.7 t
4.76
4.60
4.52
4.11
4.27
4.24
4.27
4.24
4.31
4.43
4.68
5.01
5.20
4.81
5.34
5.44
5.53
5,7 5
5.84
s.80
5.68
6.05
6.ts
9.01
8.87
8.83
8.93
8.91
8.m
8.87
8.97
9.06
8.95
8.87
8.96
8.85
8.86
8.90
8.54
8.50
8.49
8.33
8.29
8.42
8.48
8.37
8.62
9.01
9.36
9.32
9.00
8.72
8.81
8.97
9. l3
9.02
9.06
8.82
8.85
9.01
9.l6
9.21
8.93
8.89
8.99
9.01
9.21
9.t4
9.t6
9. l5
9. l8
9.ls
9.07
9.00
8.85
8.76
8.94
8.6s
8.50
8.48
8.33
8.28
8.25
8.33
8. l3
8.05
dAlAnsE)
TTCiJN:CAL $fi(}I,Ji:
Run2-RMData
Location: HF Sinclair Woods Cross Refining. LLC - West Bountiful. UT
Source: BoilerNo. l0
Project No.: AST-2023-1660
Date:8/22/23
Time
Unit
Status
Oz - Outlet COz - Outlet
"/"dry "hdry
Valid Valid
20:54
20:55
20.s6
20:57
20:58
20.59
2t:00
2l:01
2l:02
2l:03
2l:04
2l :05
2l:06
2107
2l:08
2l:09
2l: l0
2l:ll
2t.tz
2l:13
Uncorrected Run Average (Cnu)
Cal Gas Concentr.tion (Cm)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Avcr.ge Crl Response (Cu)
5.94
6.06
5.84
6.05
6.03
5.73
s.6 t
4.97
4.35
4.42
4.72
5.54
s.63
s.78
5.49
5.41
5.16
5.01
4.87
477
4.95
10.9s
0.06
0.07
0.07
10.96
10.92
10.94
8. l6
8.10
8.21
8.09
8. l0
8.26
8.31
8.63
8.98
8.92
8.76
8.37
8.32
8.25
8.39
8.42
8.58
8.63
8.72
875
8.78
10.7 4
0.02
0.07
0.05
10.77
t0.76
10.77
7
l2l of 199
#Ali-arpe
T {:{] i'-{ N 1c&L Gfi ot'T,o."non,HFsinclairwoodscrossReflnins.LLC-westBountitul.ur
Run3-RMData
Source: BoilerNo. l0
Project No.: AST-2023-1660
Date:8/23D3
Time
Unit
Status
Or - Outlet COr - Outlet
Y,dry %,dry
Valid Valid
l0:15
l0:16
l0: l7
l0:18
l0:19
l0:20
l0:21
l0:22
l0:23
l0:24
l0:25
l0:26
l0:27
l0:28
l0:29
l0:30
l0:31
l0:32
l0:33
l0:34
l0:35
l0:36
l0:37
l0:38
l0:39
l0:40
l0:41
10.42
l0:43
l0:44
l0:45
l0:46
l0:47
10:48
l0:49
10:50
l0:51
l0:52
l0:53
l0:54
l0:55
l0:56
l0:57
l0:58
l0:59
I l:00
I l:01
I l:02
I l:03
I l:04
I l:05
I l:06
I l:07
I l:08
I l:09
I l:10
ll:ll
ll:12
I l:13
ll:14
ll:15
I l:16
I l:17
122 of 199
4.76 8.77
4.96 8.62
4.65 8.79
4.80 8.73
4.67 8.80
4.85 8.71
4.s8 8.85
4.81 8.74
4.77 8.77
4.38 8.95
4.67 8.80
4.70 8.80
4.59 8.84
4.4t 8.94
4.78 8.',15
4.75
4.M
4.67
4.42
4.62
4.61
4.43
4.38
4.44
4.23
4.41
4.53
4.56
4.19
4.43
4.47
4.39
4.44
4.68
4.47
4.47
4.61
4.s5
4.29
4.22
4.34
4.51
4.34
4.s4
4.32
4.40
4.46
4.40
4.21
4.57
4.36
4.59
4.36
4.57
4.46
4.30
4.54
4.44
4.54
4.40
4.53
4.42
4.t7
8.76
8.92
8.80
8.92
8.84
8.84
8.92
8.97
9.01
9. l8
9.01
8.93
8.90
9.08
8.96
8.92
8.96
8.95
8.85
8.93
8.91
8.83
8.85
8.95
9.01
8.95
8.89
8.95
8.87
8.97
8.95
8.89
8.93
9.04
8.85
8.95
8.84
8.9',7
8.85
8.91
9.00
8.89
8.95
8.89
8.98
8.89
8.94
9.06
anlffirrce
I I, C -I FJ' CA L (: I]O LJ i)
Location: HF Sinclair Woods Cross Refinine. LLC - West Bountiful. UT
Run3-RMData
Source: BoilerNo. l0
Project No.: AST-2023-1660
Date:8123123
Time
Unit
Or - Outlet COr - Outlel
t:"dry %"dry
ValidStatus Valid
ll:18
ll:19
I l:20
ll:21
ll:22
ll:23
ll:24
ll:25
I l:26
ll:27
I l:28
1t.29
I l:30
ll:31
ll:32
I l:33
I l:34
I l:35
I l:36
ll:37
I l:38
I l:39
I l:40
I l:41
n.42
I l:43
I l:44
I l:45
I l:46
ll:47
I l:48
I l:49
I l:50
I l:51
ll:52
I l:53
I l:54
I l:55
1 l:56
I l:57
I l:58
I l:59
l2:00
l2:01
12:02
l2:03
12:04
l2:05
l2:06
12.07
l2:08
l2:09
12:10
l2:l I
12:12
12:13
12:14
12:15
12:16
12:11
l2:18
l2:19
l2:20
123 of 199
4.59
4.43
4.34
4.53
4.53
4.35
4.13
4.49
4.34
4.33
4.39
4.26
4.38
4.34
4.20
4.41
4.37
4.5't
4.26
4.42
4.39
4.27
4.t I
4.53
4.56
4.44
4.63
4.45
4.45
4.50
4.31
4.06
4.33
4.29
4.34
4.27
4.34
4.43
4.37
4.24
4.29
4.29
4.45
8.86
8.95
8.99
8.90
8.90
8.99
9.07
8.91
8.97
8.98
8.99
9.04
9.00
9.01
9.07
8.99
8.97
8.90
9.04
8.9s
8.92
8.96
9.06
8.86
8.86
8.95
8.88
8.96
8.97
8.93
9.0t
9.14
9.05
9.05
9.04
9.06
9.05
8.99
9.01
9.08
9.05
9.05
8.94
9.07
8.88
9.01
8.9t
8.91
8.97
9.07
8.94
8.88
9.03
8.95
9.04
8.91
9.01
8.95
8.92
8.97
9.05
8.87
8.91
l5
58
3l
54
4.s4
4,44
4.23
4.52
4.60
4.31
4.46
4.30
4.57
4.32
4.46
4.52
4.44
4.25
4.62
4.49
dAllarpe
TSCilNiC&L {;fi,i}L' T
Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Run3-RMData
Source: BoilerNo. l0
Project No.: AST-2023-1660
Datez 823123
Time
Unit
Status
Or - Outlet CO, - Outlet
"/" dry "/" dry
Valid Valid
l2:21
l2:22
l2:23
l2:24
12:25
l2:26
'12:27
12:28
l2:29
l2:30
12.3t
l2:32
l2:33
l2:34
l2:35
l2:36
l2:37
l2:38
l2:39
l2:40
t2.41
12:42
12.43
12:44
12:45
l2:46
l2:47
l2:48
12:49
I 2:50
l2:5 I
tz.5z
t2'.53
12:54
12:55
12:56
12:57
l2:58
12:59
13:00
l3:01
l3:02
l3:03
l3:04
l3:05
l3:06
l3:07
l3:08
l3:09
l3:10
l3:ll
l3:12
l3:13
l3:14
l3:15
l3:16
l3:1 7
l3: l8
l3: l9
l3:20
l3:21
13:22
l3:23
124 of 199
4.38
4.45
4.3s
4.48
4.38
4.18
4.36
4.40
4.40
4.36
4.41
4.37
4.36
4.30
4.40
4.61
4.43
4.63
4.65
4.50
4.43
4.52
4.41
4.31
4.20
4.47
4.50
4.37
4.56
4.46
4.34
4.71
4.91
4.70
4.36
4.62
4.48
4.59
4.63
4.58
4.81
4.56
4.72
4.77
4.66
4.45
4.45
4.75
4.55
4.57
4.45
4.55
4.54
4.55
4.33
4.65
4.46
4.46
4.6s
4.67
4.74
4.53
4.72
8.97
8.90
8.97
8.93
8.96
9.06
9.01
8.95
8.98
8.98
8.97
8.97
8.97
9.01
8.97
8.84
8.91
8.84
8.83
8.90
8.94
8.90
8.93
8.98
9.05
8.91
8.90
8.96
8.86
8.91
8.94
8.89
8.89
8.86
8.96
8.82
8.89
8.86
8.85
8.89
8.76
8.90
8.81
8.78
8.82
8.92
8.93
8.79
8.88
8.86
8.94
8.89
8.90
8.90
9.01
8.84
8.91
8.93
8.84
8.8s
8.80
8.91
8.82
#AIiarpEr
TrcHhlicAL {}ft*t"Jf3
Locationt
Snnma. Roilcr Nn lO
Run3-RMData
Project No.: AST-2023-1660
Drtet 8/23123
Time
Unit
Status
Or - 0utlet CO. - OutletT.dry "/"dry
Valid Valid
13:24
13.25
13:26
l3:27
13:28
13:29
13:30
13:31
13:32
13:33
13:34
l3:35
l3:36
I 3:37
l3:38
l3:39
l3:40
l3:41
l3:42
l3:43
l3:44
l3:45
13:46
13:4'l
l3:48
l3:49
I 3:50
l3:51
l3:52
l3:53
I 3:54
13:55
13:56
13:57
l3:58
13:59
14:00
14:01
l4:02
l4:03
l4:04
l4:05
l4:06
l4:07
l4:08
l4:09
l4:10
l4:ll
l4:12
I 4:13
l4:14
l4:15
l4: l6
l4l'l
l4: l8
l4: l9
14.20
l4:21
t4.22
l4:23
14.24
l4:25
t4'.26
125 of 199
4.72
4.60
4.37
4.51
4.66
4.47
4.63
4.62
4.7 t
4.79
4.83
4.63
4.67
4.62
4.43
4.51
4.35
4.55
4.62
4.45
4.78
4.79
4.56
4.73
4.66
4.43
4.19
4.44
4.5',1
4.44
4.59
4.38
4.62
4.53
4.44
4.69
4.66
4.6t
4.25
4.50
4.66
4.41
4.67
4.39
4.52
4.49
4.45
4.24
4.47
4.45
4.38
4.42
4.45
4.44
4.23
4.7 |
4.53
4.44
4.s4
4.46
4.51
4.47
4.33
8.82
8.87
8.99
8.93
8.83
8.92
8.86
8.93
8.99
8.94
8.87
8.94
8.88
8.85
8.92
8.88
8.96
8.90
8.89
9.0t
8.9t
9. l3
9.45
9.24
8.90
8.96
9.07
8.95
8.88
8.94
8.88
8.91
8.85
8.90
8.96
8.81
8.81
8.84
9.03
8.92
8.84
8.97
8.84
8.97
8.90
8.89
8.90
9.03
8.94
8.93
8.96
8.93
8.93
8.95
9.06
8.80
8.88
8.91
8.87
8.92
8.93
8.91
8.99
aIlmrpe
T f * i-.{ l\I 1 CAL G R {) U r}
Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Run3-RMData
Source: BoilerNo. l0
Project No.: AST-2023-1660
Datet 8123/23
Valid
Time
Unit
Strtus
Or - Outlet COr - Outlel
%,dry o/odry
Valid
l4:27
l4:28
l4:29
l4:30
l4:31
l4:32
l4:33
l4:34
l4:35
l4:36
l4:37
l4:38
4.32
4.16
4.49
4.29
4.50
4.24
4.30
4.32
4.28
4.21
4.56
4.39
8.98
9.05
8.91
9.01
8.91
9.01
8.95
8.9't
9.02
9.06
8.88
8.96
Uncorrected Run Average (C.6,)
Crl Grs Concentration (Cm)
Pretest System ZEro Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest Syst€m Cal Response
Posttcst Systcm Cal Response
Average Cal Response (Cy)
4.48
10.95
0.08
0.07
0.08
10.93
r0.88
t0.9t
4.45
8.93
t0.74
0.l0
0.01
0.06
t0.77
t0.76
10.7'l
8.90
126 of 199
DrvlstoN oF AtR Ot-r4111y
127 of 199
$3 eurofins
Environment Testing
ANALYTICAL REPORT
PREPARED FOR
Attn: Austin Abranovic
Alliance Source Testing, LLC
214 Central Circle SW
Decatur, Alabama 35603
Generated 101212023 9:03:25AM Revision 1
JOB DESCRIPTION
HF Sinclair Woods - CTM-039
JOB NUMBER
140-33466-1
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager.
Eurofins Knoxville is a laboratory within TestAmeica Laboratoies, lnc., a company within Eurofins Environment Testing Group of Companies
Page 2 of 34
129 of 199
&*!ar{Ua-1, Generated
L-,V I 1ot2t2o23 e:03:25 AM
Arth"ri*d f"-"|"r." by
Revision 1
Courtney Adkins, Project Manager ll
Courtney.Adkins@et.eurofinsus.com
(86s)291 -301 I
101212023 (Rev. 1)
Client: Alliance Source Testing, LLC
ProjecVSite: HF Sinclair Woods - CTM-039
Laboratory Job lD: 140-33466-1
1
3
4
5
7
9
24
25
26
29
30
31
32
Table of Contents
Cover Page
Table of Contents . . .
Definitions/Glossary . . .
Case Narrative
Detection Summary
Client Sample Results
Default Detection Limits
QC Association Summary
Lab Chronicle .
Certification Summary . .
Method Summary
Sample Summary
Chain of Custody . . .
Eurofins Knoxville
101212023 (Rev. 1)Page 3 of 34
130 of 199
Definitions/Glossary
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
q Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, lN lndicates a Dilution, Re-analysis, Re-extraction, or additional lnitial metaldanion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOO Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
OC Ouality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radaochemistry)
RPD Relative Percent Difference, a measure of the relative differen@ between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too NumerousTo Count
Eurofins Knoxville
Page 4 of 34 101212023 (Rev. 'l )
l3 I of 199
Case Narrative
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Job lD: 140-33466-1
Laboratory : Eurofins Knoxville
Narrative
a
']r....,l.Job Narrative
140-33466-1
Revision Notes
This report was revised to include initial sample volumes.
Receipt
The samples were received on 911212023 9:30 AM. Unless otheruvise noted below, the samples arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 2'l .9o C.
Receipt Exceptions
The Field Sampler was not listed on the Chain of Custody.
The Chain-of-Custody (COC) was incomplete as received and/or improperly completed. Sample matrix not listed.
General Ghemistry
Particulate Matter by CTM-O3g-Particulate Matter was determined for samples derived from Conditional Test Method 039 sampling trains.
The filter samples were dried in a desiccator over anhydrous calcium sulfate for a minimum of 24 hours. Acetone rinses were evaporated
in TeflonrM beaker liners in a hood at ambient temperature instead of aluminum pans in order to avoid possible reactions between acidic
stack contents and the aluminum pans. The aqueous impinger catch was simmered to less than 10 mL, and then evaporated to dryness
in an unheated forced draft oven. Data are reported to 0.01 mg as specified in the cited method. The reporting limit was lowered to the
readability of the balance used (0.01 mg).
Method CTM 039: A deviation from the Standard Operating Procedure (SOP) occurred. Details are as follows: Beaker liners were weighed
three times and the average of all three was used as the liner tare weight per PM and consultant request.
Method CTM 039: Samples BOILER 10 - <PM2.5 FILTER - 142MM - RUN 1 (140-33466-5) did not achieve constant weight as described in
SOP KNOX-WC-0006 section 11.12.6 the last two gross weights were averaged and used as final sample weight.
Method CTM 039: Sample BOILER 1 0 - <PM2.5 Dl WATER RINSE - RUN 3 (140-33466-1 3)did not reach constant weight as described in
the SOP KNOX-WC-0006 section 11 .12.6. The three gross weights were averaged and used as final sample weight.
Method CTM 039: Samples BOILER 10 - <PM2.5 FILTER - 142MM - RUN 2 (140-33466-10) and BOILER 10 - <PM2.5 FILTER - 142MM -
RUN 3 (140-33466-15) arrived with significant damage to the filters (tares, frayed edges, missing pieces). The analyst was careful to get
all loose filter pieces weighed with the sample. However the damage may reflect a low bias in the data.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Page 5 of 34
132 of 199
Eurofins Knoxville
1012t2023 (Rev. 1)
Job 140-33466: Sample Volumes
Sample lD Volume (mL)
140-33466-A-1 87.4
L40-33466-A-2 55.8
140-33466-A-3 r93.4
140-33456-A4 225.3
t40-33466-4-6 7t.o
L40-33456-A-7 86.8
140-33466-A-8 185.9
140-33466-A-9 191.1
140-33466-A-11 95.9
140-33466-A-12 32.5
140-33465-A-13 L76.L
140-33465-A-14 20L.2
tr
Page 6 of 34
133 of 199
101212023 (Rev. 1)
Detection Summary
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN
,l
Lab Sample lD: 140-33466-1
I lnatyte
I Prrti""l'rt"{/att*
Result Qualifier RL MDL Unit
0.575 0.0100 0.0100 mg/sample
Dil Fac D Method Prep Type
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE -
RUN 1
Lab Sample lD: 140-33466-2
I Analyte
Particulate MatterL
Result Qualifier RL MDL Unit
0.440
Dil Fac D Method Prep Type
0.0100 0.0100 mg/sample 1 CTM 039 Total/NA
Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN
1
Lab Sample lD: 140-33466-3
An?brte
Particulate Matter
I
Result Qualifier RL MDL Unit
1.81 0.0100 0.0100 mg/sample
Dil Fac D Method Prep Type
1 CTM 039
Client Sample !D: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
1
Lab Sample lD: 140-33466-4
I lnatyte
I eartiarr'ate f*atter
Result Oualifier RL MDL
2.48 0.0100 0.0100
Dil Fac D Method Prep Type
mg/sample 1 CTM 039 TotaUNA
Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
1
Lab Sample lD: 140-33466-5
Analyte Result Qualifier RL MDL Unit
0.910 0.0100 0.0100 mg/sample
Dil Fac D Method Prep Type
Particulate Matter
CIient Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN
2
Lab Sample lD: 140-33466-6
Analyte Result Qualifier RL MDL Unit
0.265
Dil Fac D Method Prep Type
0.0100 0.0100 mg/sample 1 CTM 039 Total/NAParticulate Matter
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE -
RUN 2
Lab Sample lD: 140-33466-7
I enatyte
I eat^,ht" rrl"tt.
Result Qualifier RL MDL Unit Dil Fac D Method Prep Type
0.0100 0.0100 mg/sample
Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN
2
Lab Sample lD: 140-33466-8
Result Qualifier RL MDL Unit Dil Fac D Method Prep Type
0.0'100 0.0'100 mg/sample 1 CTM 039 Total/NAParticulate Matter 1.13
Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
2
Lab Sample lD: 140-33466-9
Result Qualifier MDL Unit Dil Fac D
1-
Prep Type
,Particulate Matter 1 .39 0.0100
Page 7 of 34
134 of 199
Eurofins Knoxville
101212023 (Rev. 1)
This Detection Summary does not include radiochemical test results.
0.0100 mg/sample cTM 039
Detection Summary
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
2
Lab Sample lD: 140-33466-10
Analyte
Pa rti.'rJlate tv!atterL
Result Qualifier RL MDL Unit
1.07
Dil Fac D Method Prep Type
0.0100 0.0100 mg/sample 1 CTM 039 Total/NA
Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN
3
Lab Sample lD: 140-33466-11
t-Analyte
Partic'rrlate fu!atterL
Result QualifierQualifier RL MDL Unit
0.530 0.0100 0.0100 mg/sample
Dil Fac D Method Prep Type
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE -
RUN 3
Lab Sample lD: 140-33466-12
Result Qualifier RL MDL Unit
0.0400
Dil Fac D Method Prep Type
0.0100 0.0100 mg/sampleParticulate Matter
Client Sample !D: BOILER 10 - <PM2.5 DIWATER RINSE - RUN
3
Lab Sample !D: 140-33466-13
I
I Analyte
I Particulate Matter
t
Result Qualifier RL MDL Unit
1.56
Dil Fac D Method Prep Type
0.0100 0.0100 mg/sample I CTM 039 Total/NA
Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
3
Lab Sample lD: 140-33466-14
Analyte
Particulate Matter
L-_
Result Qualifier RL MDL Unit
1.24
Dil Fac D Method Prep Type
0.0100 0.0100 mg/sample
Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
3
Lab Sample lD: 140-33466-15
Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type
Total/NA
Eurofins Knoxville
101212023 (Rev. 1)
Particulate Matter 1.07 0.0100 0.0100 mg/sample cTM 039
Page 8 of 34
135 of 199
This Detection Summary does not include radiochemical test results
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Client Sample lD: BOILER 10 - >PMl0 ACETONE RINSE - RUN Lab Sample lD: {40-33466-1
1
Date Collected: 08122123 00:00
Date Received: 09/1223 09:30
Sample Container: Clear Glass 500mL - unpreserved
Matrix: Air
.,,.., : .
.
Job lD: 140-33466-1
GeneralChemistry
Analyte
Partlculate Matter (EPA CTM 039) 0.575 0.0100 0.0100 mg/sample
R$ult Qualifier RL illDL Unit D Prepared Analyzed Dil Fac
O9l2Ol23 10:23 1
&p4W
1F1H'
tr
Page 9 of 34
136 of 199
Eurofins Knoxville
101212023 (Rev.1)
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE -
RUN 1
Date Col lected: 08 I 221 23 O0 :O0
Date Received: 09/12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
Lab Sample lD: 140-33466-2
Matrix: Air
Result Qualifier MDL Unit D Prepared Analyzed Dil Fac
Ogl2ol23 10:23 10.0100 0.0100 mg/sample
Page 10 of34
137 of 199
Eurofins Knoxville
1Ol2l2O23 (Rev. 1)
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Client Sample ID: BOILER 10 - <PM2.5 DIWATER RINSE - RUN Lab Sample lD: 140-33466-3
1
Date Gollected: 08122123 00:OO
Date Receive d: 091 12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
Matrix: Air
Job lD: 140-33466-1
GeneralChemistry
Analyte
Partlculato Matter (EPA CTM 039) 1.81
Result Qualifier RL MDL Unit D Prspared Analyzed Dll Fac
0.0100 0.0100 mg/sample Ogl2ol23 10:23 I
"ffiwsMtr
Page 11 of34
138 of 199
Eurofins Knoxville
101212023 (Rev. 1)
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
GIient Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN Lab Sample lD: 140-334664
1
Date Collected:. 08122123 O0:O0
Date Received: 09/1 2/23 09:30
Samole Container: Clear Glass 500mL - unpreserved
Matrix: Air
,.]||i"tgl
Job lD: 140-33466-1
Genera! Chemistry
Analyte
Partaculate MattEr (EPA CTM 039) 2.4A
Result Quallfler RL MDL Unlt D Preparod Analyzed Dil Fac
ffiffi
1lXt.t lltfei#!
tr0.0100 0.0100 mg/sample Agl2Al23 1Oi23 1
Eurofins Knoxville
Page 12 of 34 141212023 (Rev.'t)
139 of 199
CIient Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
1
Date Collected: 08/22123 00:00
Date Received: 09/12123 09:30
Sample Container: Petri/Filter
Lab Sample lD: 140-33466-5
Matrix: Air
General Chemistry
Analyte Result Qualifier D Prepared Analyzed
Ogl2ol23 10:23
MDL Unit Dil Fac
Particulate Matter (EPA CTM 039)0.0100 0.0100 mg/sample
Eurofins Knoxville
101212023 (Rev. 1)Page 13 of34
140 of 199
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN
2
Date Collected: 08/22123 00:00
Date Received: 09/12123 09:30
Sample Container: Glear Glass 500mL - unpreserved
Lab Sample lD: 140-33466-6
Matrix: Air
General Chemistry
Analyte Result Qualifier D Prepared Analyzed
Ogl2ol23 10:23
MDL Unit Dil Fac
Particulato Matter (EPA CTM 039)0.0100 0.0100 mg/sample
Eurofins Knoxville
101212023 (Rev. 1)Page 14 of34
14l of 199
Glient Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - Lab Sample lD: 140-33466-7
RUN 2
Date Collected: 08/22123 00:00 Matrix: Air
Date Received: 09/12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
Job lD: 140-33466-1
General Chemistry
Analyte
Particulate Matter (EPA CTM 039) 0.445
Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac
0.0100 0.0100 mg/sample O9l2Ol23 10:23 1
Page 15 of34
142 of 199
Eurofins Knoxville
101212023 (Rev. 1)
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUsite: HF Sinclair Woods - CTM-039
Client Sample !D: BOILER {0 - <PM2.5 DIWATER RINSE - RUN Lab Sample lD: 140-33466-8
2
Date Collected: 08122123 00:.00
Date Received: 0911?23 09:30
Sample Container: Clear Glass 500mL - unpreserved
Matrix: Air
T
I GeneralChemistry
I Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac
':;r, irrlrrf
Job lD: 140-33466-1
$ry "*&
:d;.n{&
tr
Page 16 of 34
143 of 199
Eurofihs Knoxville
101212023 (Rev.1)
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF SinclairWoods - CTM-039
Job lD: 140-33466-1
CIient Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
2
Date Col lected: 08 I 221 23 00:00
Date Received: 09/12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
Lab Sample !D: 140-33466-9
Matrix: Air
General Chemistry
Analyte Result Qualifier MDL Unit D Prepared
Particulate Mafter (EPA CTM 039)0.0100 0.0100 mg/sample
Analyzed
Ogl2ol23 10:23
Dil Fac
Page 17 of34
144 of 199
Eurofins Knoxville
101212023 (Rev. 1)
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
2
Date Co! lected: 081221 23 00 :00
Date Received: 09/12123 09:30
Sample Container: Petri/Filter
Lab Sample lD: 140-33466-10
Matrix: Air
Result Qualifier MDL Unit D Prepared
1.07 0.0'100 0.0100 mg/sample
Analyzed Dil Fac
Ogl2il23 10:23 1
Eurofins Knoxville
'101212023 (Rev. 1)Page 18 of34
145 of 199
Client Sample Results ;:{t 'ft
Job lD: 140-33466-1
w:ffi
ffiffiu
Client: Alliance Source Testing, LLC
ProjecUSite: HF SinclairWoods - CTM-039
Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN Lab Sample lD: 140-33466-11
3
Date Gollected: 08/23/23 00:00 Matrix: Air
Date Received: 09/12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
GeneralChemistry
Analyte
Partlculate Matter (EPA CTM 039) 0.530 0.0100 0.0100 mg/sarnple Ogl20l23 10i23 1
Eurofins Knoxville
1Ol2l2A23 (Rev. 1)
Result Qualifier RL ftttDL Unit D Prepared Analyzed Dil Fac
Page 19 of34
146 of 199
Client Sample Results
Client Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - Lab Sample lD: 140-33466-12
RUN 3
Date Collected: 08/23/23 00:00 Matrix: Air
Date Received: 09/12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
t"
I GeneralChemistry
I enaryte Result Qualifier RL MDL Unit D Prepared Analyzed Oil Fac
Job lD: 140-33466-1
ffi
tr
Page 20 of 34
147 of 199
Eurofins Knoxville
101212023 (Rev. 1)
GIient Sample Results
Client: Alliance Source Testing, LLC
Project/Site: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN
3
Date Collected: 08/23123 00:00
Date Received: 09/12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
Lab Sample lD: 140-33466-13
Matrix: Air
Result
156
MDL Unit D Prepared Analyzed
Ogl2ol23 10:23
Dil Fac
s-s;l
fi,*ffal#|)
tr0.0100 0.0100 mg/sample
Page 21 of34
148 of 199
Eurofins Knoxville
1012t2023 (Rev. 1)
Glient Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
3
Date Collected: 08/23123 00:00
Date Received: 09/12123 09:30
Sample Container: Clear Glass 500mL - unpreserved
Lab Sample lD: 140-33466-14
Matrix: Air
General Ghemistry
Analyte
Particulate Matter (EPA CTM 039)
Result Qualifier MDL Unlt D Prepared Analyzed Dil Fac
1
i(,rilr
tr**0.0100 0.0100 mg/sample Ogl2ol23 10:23
Eurofins Knoxville
101212023 (Rev. 1)Page 22 of 34
149 of 199
Client Sample Results
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample !D: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
3
Date Collected: 08/23123 00:00
Date Received: 09/12123 09:30
Sample Container: Petri/Filter
Lab Sample lD: 140-33466-15
Matrix: Air
General Chemistry
Analyte Result Oualifier MDL Unit D Prepared Analyzed Dil Fac
Particulate Matter (EPA CTM 039)0.0100 0.0100 mg/sample Ogl2ol23 1O:23
Eurofins Knoxville
101212023 (Rev. 1)Page 23 of 34
150 of 199
Default Deteetion Limits tt': ';i"i:':,::.1{ aitr\
Job lD: 140-33466-1Client: Alliance Source Testing, LLC
ProjecUsite: HF Sinclair Woods - CTM{39
General Ghemistry
l'nnatyte
I FertiEGParticulate Matter
RL MDL Unlts
0.0100 0.0100 mg/sample
Page 24 of34
151 of 199
Eurofins Knsxville
10ru2023 (Rev. 1)
QC Association Summary
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
General Chemistry
Analysis Batch:77958
Lab Sample lD
140-33466-1
140-33466-2
140-33466-3
140-33466-4
140-33466-5
140-33466-6
't40-33466-7
't40-33466-8
140-33466-9
140-33466-1 0
1 40-33466-1 1
140-33466-12
140-33466-1 3
140-33466-14
140-33466-1 5
Client Sample lD
BOILER 10. PM1O.PM2.5 ACETONE RINSE - R
BOILER 1O - <PM2.5 DI WATER RINSE. RUN 1
BOILER 10. <PM2.5 ACETONE RINSE . RUN 1
BOILER .IO - <PM2.5 FILTER. 142MM . RUN 1
BOILER 1O - >PM1O ACETONE RINSE - RUN 2
BOILER 1O - PMlO-PM2.5 ACETONE RINSE - R
BOILER ,IO - <PM2.5 DI WATER RINSE. RUN 2
BOILER 1O - <PM2.5 ACETONE RINSE - RUN 2
BOILER 1O - <PM2.5 FILTER - 142MM . RUN 2
BOILER 1O - >PM1O ACETONE RINSE . RUN 3
BOILER 1O - PMlO-PM2.5 ACETONE RINSE - R
BOILER 1O - <PM2.5 DI WATER RINSE - RUN 3
BOILER 1O - <PM2.5 ACETONE RINSE - RUN 3
BOILER 10. <PM2.5 FILTER - 142MM - RUN 3
Prep Type Matrix
Total/NA Air
Total/NA
TotaYNA
Total/NA
TotaUNA
Total/NA
Total/NA
Total/NA
TotaYNA
Total/NA
Total/NA
Total/NA
Total/NA
Total/NA
Total/NA
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Method
Cnvl 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
cTM 039
CTM 039
Prep Batch
Eurofins Knoxville
101212023 (Rev. 1)Page 25 of 34
152 of 199
Lab Chronicle
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - >PMI0 ACETONE RINSE - RUN
1
Date Collected: O8122123 O0:O0
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-1
Matrix: Air
| ,,"o rro"
L..n-
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final
Amount
Batch Prepared
Number or Analyzed Analyst Lab
1 77958 Ogl2ol2310:23 SJF EET KNX
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE -
RUN 1
Date Collected: 081 22123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-2
Matrix: Air
I ,,"r rro"
] ".n-
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEOUIP
Dit
Factor
lnitial
Amount
Final Batch Prepared
Amount Number orAnalyzed
Ogl2Ol23 1O:23
Analyst
SJF EET KNX
Client Sample lD: BOILER 10 - <PM2.5 Dl WATER RINSE - RUN
1
Date Collected: 08122123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-3
Matrix: Air
Prep Type
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEOUIP
Dil lnitial
Factor Amount
Final
Amount
Batch Prepared
Number or Analyzed Analyst Lab
1 77958 Ogl21l2310:23 SJF EET KNX
Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
1
Date Collected: 08122123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-4
Matrix: Air
| ","o
rro"
tT*
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final
Amount
Batch Prepared
Number or Analyzed Analyst Lab
O9l2Ol23 10:23 SJF EET KNX1
Client Sample ID: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
1
Date Collected:. OBl22l23 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-5
Matrix: Air
Prep Type
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final Batch
Amount Number
Prepared
or Analyzed
Ogl2ol23 10:23
Analyst
SJF1
Page 26 of 34
153 of 199
EET KNX
Eurofins Knoxville
101212023 (Rev. 1)
Lab Chronicle
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN
2
Date Collected: OBl22l23 0O:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-6
Matrix: Air
Prep Type
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final Batch
Amount Number
Prepared
or Analyzed Analyst
09120123 10:23 SJFI EET KNX
Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE -
RUN 2
Date Collected: 08122123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-7
Matrix: Air
I ,,"o t o"
I
..r..Type Method
Analysis CTM 039
lnstrument lD: NOEOUIP
Oil lnitial
Factor Amount
Final Batch
Amount Number
Prepared
or Analyzed
Ogl2ol23 1O:23
Analyst Lab
EET KNX
Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN
2
Date Collected: 08122123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33465-8
Matrix: Air
Prep Type
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEOUIP
Dil lnitial
Factor Amount
Final Batch Prepared
Amount Number orAnalyzed
1
Analyst Lab
Ogl2ol23 10:23 SJF EET KNX
Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
2
Date Gollected: 08122123 00:00
Date Received: 09/12123 09:30
Lab Sample !D: 140-33466-9
Matrix: Air
[ ,."o rro"
lr""r*
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final Batch Prepared
Amount Number orAnalyzed
I
Analyst Lab
Ogl2ol23 10:23 SJF EET KNX
Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
2
Date Collected: 08122123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-10
Matrix: Air
Batch Batch
Prep Type Type Method
Totaul.lA Analysrs Cnvt 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final Batch Prepared
Amount Number or Analyzed Analyst Lab
Ogl2ol23 10:23 SJF EET KNX
Eurofins Knoxville
101212023 (Rev. 1)Page 27 of 34
154 of 199
Lab Ghronicle
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: '140-33466-1
Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN
3
Date Collected: 08/23/23 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-11
Matrix: Air
| ,."o rro"
]
.rn-Type Method
Dil lnitial
Factor Amount
Final Batch
Amount Number
Prepared
or Analyzed Analyst
Ogl2ol2310:23 SJF EET KNXAnalysis CTM 039
lnstrument lD: NOEOUIP
Client Sample lD: BOILER '10 - PM10-PM2.5 ACETONE RINSE -
RUN 3
Date Collected: 08/23123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-12
Matrix: Air
I ,."r rro"
Total/t,lA
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dit
Factor
lnitial Final Batch
Amount Amount Number
Prepared
or Analyzed
Ogl21l23 10:23
Analyst Lab
I EET KNX
CIient Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN
3
Date Collected: 08/23/23 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-13
Matrix: Air
Prep Type
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final
Amount
Batch Prepared
Number or Analyzed Analyst Lab
Ogl20l23 10:23 SJF EET KNX1
CIient Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN
3
Date Collected: 08/23123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33465-14
Matrix: Air
Final Batch Prepared
Run Factor Amount Amount Number orAnalyzed Analyst
77958 Ogl21t23 10:23 SJF EET KNX
Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN
3
Date Collected: 08/23123 00:00
Date Received: 09/12123 09:30
Lab Sample lD: 140-33466-15
Matrix: Air
Prep Type
l".r--
Batch Batch
Type Method
Analysis CTM 039
lnstrument lD: NOEQUIP
Dil lnitial
Factor Amount
Final Batch
Amount Number
Prepared
or Analyzed
ogl2ol23 1O:23
Analyst Lab
EET KNX
Eurofins Knoxville
101212023 (Rev. 1)
Laboratory References:
EET KNX = Eurofins Knoxville, 581 5 Middlebrook Pike, Knoxville, TN 37921 , TEL (865)291-3000
Page 28 of 34
l55ofl99
Accreditation/Certification Sum mary
Client: Alliance Source Testing, LLC
POecUSite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
La boratory: Eurofins Knoxville
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Proqram ldentificationNumber ExpirationDate
ANAB
ANAB
ANAB
Arkansas DEO
Colorado
Connecticut
Florida
Georgia (DW
Hawaii
Kansas
Kentucky (DW
Louisiana (All)
Louisiana (DW
Maryland
Michigan
Nevada
New Hampshire
New Jersey
New York
North Carolina (DW)
North Carolina (\ M//SW
Oklahoma
Oregon
Pennsylvania
Tennessee
Texas
US Fish & \A/ildlife
USDA
Utah
Mrginia
Washington
West Virginia (DvV)
West Varginia DEP
_Wsconsin
AFCEE
Dept. of Defense ELAP
Dept. of Energy
tso/rEc 17025
State
State
State
NELAP
State
State
NELAP
State
NELAP
State
State
State
State
NELAP
NELAP
NELAP
State
State
State
NELAP
NETAP
State
NELAP
US Federal Programs
US Federal Programs
NELAP
NELAP
State
State
State
State
N/A
L2311
L2311.01
L2311
88-0688
TN00009
PH4223
E87177
906
NA
E-10349
901 01
83979
LAO19
277
9933
TN00009
2999
TNOOl
10781
21705
64
941 5
TNl0189
68-00576
02014
Tl 04704380-23-1 8
058448
s25-22-279-18762
TN00009
460176
c593
9955C
345
998044300
02-13-25
o2-13-25
o2-13-25
06-16-24
02-29-24
09-30-23
06-30-24
07-27-25
07-27-24
10-31-23
12-31-23
06-30-24
12-31-23
o3-31-24
07-27-25
07-31-24
o1-17-24
07-01-24
03-31-24
07-31-24
12-31-23
12-31-23
o1-01-24
12-01-23
07-27-25
08-31-24
07-31-24
1 0-06-25
07-31-24
o9-14-24
o1-19-24
12-31-23
o4-30-24
08-31-24
Page 29 of 34
156 of 199
Eurofins Knoxville
10t212o23 (Rev. 1)
Method Summary
Glient Alliance Sourqe Testing, LLC
ProjeeUsite: HF Sinclair Woods - CTM-039
Job lD: 140-33466-1
iiethod Meihod Detcrlptlon
CTM 039 ParticulaGs
Protcol Refercnees:
EPA = US Envirqnmentat Protection Agency
Laboratiory References:
EET KNX = Eurofins Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000
Protocol LaboratoryEm- EETr.ttx
Eurotins Knoxville
Page 30 of 34 1012DA23 (Rev. 1)
157 of199
*ilslla
Sample Summary
Client: Alliance Source Testing, LLC
ProjecUSite: HF Sinclair Woods - CTM-039
Job lD: '140-33466-1
Lab Sample lD
140-33466r
1 40-33466-2
1 40-33466-3
140-33466-4
140-33466-5
140-33466-6
140-33466-7
140-33466-8
140-33466-9
140-33466-1 o
140-33466-11
1 40-33466-1 2
1 40-33466-1 3
140-33466-14
140-33466-1 5
Client Sample lD Matrix Collected Received
BOILER .10 . >PM1O ACETONE RINSE - RUN 1
BOILER 1O - PMlO-PM2.5 ACETONE RINSE .
RUN 1
BOILER 1O - <PM2.5 DI WATER RINSE - RUN 1
BOILER 1O - <PM2.5 ACETONE RINSE. RUN 1
BOILER 1O - <PM2.5 FILTER. 142MM . RUN 1
BOILER 1O - >PM1O ACETONE RINSE . RUN 2
BOILER 1O . PM1O,PM2.5 ACETONE RINSE -
RUN 2
BOILER 1O - <PM2.5 DI WATER RINSE. RUN 2
BOILER 1O - <PM2.5 ACETONE RINSE. RUN 2
BOILER 1O - <PM2.5 FILTER - 142MM - RUN 2
BOILER 1O - >PMlO ACETONE RINSE - RUN 3
BOILER 1O - PMlO-PM2.5 ACETONE RINSE .
RUN 3
BOILER 10. <PM2.5 DI WATER RINSE - RUN 3
BOILER 1O - <PM2.5 ACETONE RINSE. RUN 3
BOILER 1O - <PM2.5 FILTER. 142MM. RUN 3
Air
Air
08122123 OO:OO
08122123 OOIO0
O8122123 OO:OO
08122123 OO:OO
08122123 00:00
OAl22l23 OO:OO
OBl22l23 OO:OO
OAl22l23 OO:OO
ogl22l23 00100
OAl22123 O0:OO
08123123 O0:O0
08123123 00:00
OBl23l23 O0:OO
OAl23l23 00:00
08123123 00:00
Ogl12l23 09:30
Ogl12123 09:30
Ogl12l23 09:30
Ogl12l23 09:30
Ogl1Z23 09:30
Ogl12123 09:30
Ogl12123 09:30
Ogl12123 09:30
Ogl12123 09:30
Ogl12123 09:30
Ogl12123 O9t3O
Ogl12123 09:30
O9112123 09:30
Ogl12123 09:30
Ogl12123 09:30
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Air
Page 31 of34
158 of 199
Eurofins Knoxville
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NAliarrce
TL[;II Ni{:AI. {]NC}U2
Ifistion HF Sinclsir Woods Crosi Refining' LLC - Wst Bounaiful, UT
QA/QC Data
Source Boiler No. l0
Project No. AST-20211560
Prrrmeter PM (CTM-039)
Drte Nozle ID
Nozzle lriometer (in.)
lll #2 #3 Dn (Avcrace) Dilfercnce Criteria
8t22t23
al22/23
N20lA-3
N20lA-5
0.240
0.260
0.240
0.260
0.240
0.260
0.240
0.260
0.000
0.000
3 0.004 in
D.te Pitot ID Evidcnce of Evidence of LrllDrtoon or
Ranrir reouired?
8t22/23 P-761 no no no
Drte Probe ID Rcfercrce Indicrted Dilference Criteri.
an2l23 P-761 92.0 92.0 0.oyo 1.5 % (absolute)
Date Barometric Pr6sure Evidetrcc of Rcading Vcrified LrttDranotr or
Reorir reouired?
8t22123 weather Station NA NA NA
163 of 199
dmAlialpe
TtCllN:CAL *11 C, lii,
QA Data
Location HF Sinclair Woods Cross Refining. LLC - West Bountiful, UT
Source Boiler No. l0
Project No. AST-2023-1660
Parameter(s) Moisture
Field Balance Check
Date 08t22t23
Balance ID:5A2881026
Test Weight ID:slc- 1 ks-3
Certified Weight (g):1000.0
Measured Weight (g):999.9
Weight Difference (g):0.1
Date Barometric
Pressrr re
Evidence of Reading
Verified
Celibretion or
Renair reouired?Weflther Station Locetion
8/22/23 Weather Station NA NA NA West Bountiful, UT
Date Meter Box ID Positive Pressure Leak Check
8t22/23 MB-704 Pass
t64 of 199
DGM Calibration-Orifices
Doaument lI 620 004
Revisior 23.0
Effective Dat(1/25/23
lssuing Departmenl Tech Setuices Paq(lofl
Equipment Detail - Dry Gas Meter
Console lD: N.48-704
N,4eter S/N: 18392989
Critical Orifice S/N: 1330
Calibration Detail
lnitial Barometric Pressure, in. Hg (Pb)
Final Barometric Pressure, in. Hg (PbF)
Averaqe Barometric Pressure, in. Hq (Pb)
25 45
25 48
25 47
Critifcal Orifice lD (Y)
K'Factor, ft3 R"2 / in. wC min (K)
Vacuum Pressure, in. Hg (Vp)
lnitial DGM volume, ftr (Vml)
Final DGM Volume, ft3 CVm,
Tntel f.)Gh,l \/nL rma ft'3 fvm\
1330-31
0.8429
13.0
753 100
769.643
16 543
'1330-31 1330-25
0 6728
15.0
782.800
796.038
13.238
1330-25 133019
0.5186
16.0
806.000
816.437
10.437
1330-19
08429 0.673 0.519
13.0
769.643
780.710
11.067
15.0
796.038
804.888
8.850
160
816 783
823.493
6.710
Ambient Temperature, 'F [ta)
lnitial Dctvl Temperature,'F (Tmr)
Final DGM Temperature, 'F (Imr)
Averaoe DGM Temperature, 'F ( Tm)
72
73
74
74
72
74
75
75
73
74
74
74
73
74
75
75
74
15
75
75
75
75
75
Elapsed Time (O)
Meter Orifice Pressure, in. WC (AH)
Standard Meter volume, ft3 lvmstd)
Standard Critical Orifice Volume, ft3 (Vcr)
Meter Correction Factor (Y)
Tolerance
Orifice Calibration Value (AH @)
Tolerance
Orifice Cal Check
15.00
340
14.0740
13 9631
0 992
0.000
1.878
0 018
10.00
3.40
9.3976
9.3087
0.991
0.001
1 874
0.014
15 00
2.10
11.2099
i1 1348
0.993
0.001
1.815
0.044
10.00
210
7 4871
7 4232
0.991
0.000
1.814
0.046
15.00
1.30
8.8012
8.5148
0.974
0 018
1.887
0 027
10 00
1.30
5.6584
5.7112
1 009
0.017
1.891
0.031
0.11 0.11 0.06
Meter Correction Factor m 0992
Orifice Calibration Value (AH @)1.860
Positive Pressure Leak Check Yes
Equioment Detail - Thermocouple Sensor
Reference Calibrator Make: OMEGA
Reference Calibrator l'/odel: CL23A
Reference Calibrator S/N: T{97207
Calibration Detail
Reference Temp Display Temp.Accuracy Difference
r %OF
0
68
'100
460
528
550
0
66
98
460
526
558
0.0
0.4
0.4
0
2
2
223
248
273
683
708
733
223
248
274
683
708
734
0.0
00
-0.1
0
0
1
300
400
500
600
700
800
900
1,000
1,100
1,200
760
860
960
1,060
1,160
1,260
1,360
1,4ffi
1,560
1.660
300
399
498
600
702
801
901
1,002
1,102
1,202
760
859
958
1,060
1,162
1,261
1,361
1,462
1,562
1,662
0.0
0.1
0.2
0.0
-0.2
-0.1
-01
-0 1
-01
-0.1
0
1
2
0
2
,1
1
2
2
2
Personnel
Stacey Cunninqham
165 of 199
Calibration By:
Calibration Date:
Reviewed By:
RYAN LYONS
6/20/2023
lrlIffirpED
TEC i".,I }.t i{],q L G R OU 3
QA Data
Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Source BoilerNo. l0
Project No. AST-2023-l 660
Parameter Oz - Outlet COz - Outlet
Make SERVOMEX SERVOMEX
Model 1440 1440
s/N 14200t3279 14150/3279
Ooeratins Ranee 0-25 0-25
Cylinder ID
7*ro
Low
Mid
Hioh
NA
NA
EB0078899
SG9I64824BAL
NA
NA
EB0078899
SG9I64824BAL
Cylinder Certifed Values
Zero
Low
Mid
Hish
NA
NA
10.95
24.58
NA
NA
t0.7 4
23.78
Cylinder Expiration Date
Zero
Low
Mid
Hish
NA
NA
7n3129
2n313t
NA
NA
7^3t29
2^3t31
166 of 199
Rlrffi]Ee
TE{:H\iCAL {::NCUP
Response Times
Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Source: BoilerNo. l0
Project No.: AST-2023-1660
Times, seconds
Parameter 0z - Outlet COr - Outlet
Zero
Low
Mid
Hish
30
NA
30
30
30
NA
30
30
Averase 30.0 30.0
167 of 199
RlIffirpe"i"IOillJ]CAL SROUP Calibration Data
Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Source: BoilerNo. l0
Project No.: AST-2023-1660
Date:8122123
Parameter O, - Outlet COz - Outlet
Exnected Averase Concentration 8.00 8.00
Span Between
Low
High
Desired Soan
8.00
40.00
24.58
12.00
60.00
23.78
Low Range Gas
Low
Hish
NA
NA
NA
NA
Mid Range Gas
Low
Hiph
9.83
14.75
9.51
t4.27
High Range Gas
Low
Hiph
NA
NA
NA
NA
Actual Concentration (% or ppm)
Zero
Low
Mid
Hish
0.00
NA
10.97
24.58
0.00
NA
10.80
23.'78
Response Time (seconds)30.00 30.00
Upscale Calibration Gas (Cro)Mid Mid
Instrument Response (% or ppm)
Zero
Low
Mid
Hish
0.07
NA
I 1.03
24.65
0.01
NA
r 0.93
23.88
Performance (7o of Span or Cal. Gas Conc.)
Zero
Low
Mid
Hish
0.28
NA
0.24
0.28
0.04
NA
0.55
0.42
Performance Criteria
Zero
Low
Mid
Hish
2.00
NA
2.00
2.00
2.00
NA
2.00
2.00
Status
Zero
Low
Mid
Hish
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
168 of 199
pulffirpe
TgC]{\']:CAL GHOUP Calibration Data
Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Source: BoilerNo. l0
Project No.: A!T.lQ2l:&{q
Date: 8/23/23
Parameter Or - Outlet COz - Outlet
Exoected Average Concentration 4.48 9. l5
Span Between
Low
High
Desired Span
4.48
22.39
24.58
9. l5
45.77
23.78
Low Range Gas
Low
Hish
NA
NA
NA
NA
Mid Range Gas
Low
Hish
9.83
14.75
9.5 r
14.27
High Range Gas
Low
Hish
NA
NA
NA
NA
Actual Concentration (% or ppm)
Zero
Low
Mid
Hish
0.00
NA
10.95
24.58
0.00
NA
10.74
23.78
Upscale Calibration Gas (Cy1)Mid Mid
Instrument Response (% or ppm)
Zero
Low
Mid
Hieh
0.05
NA
I l.0l
24.63
0.02
NA
10.87
23.77
Performance (% of Span or Cal. Gas Conc.)
Zero
Low
Mid
Hish
0.20
NA
0.24
0.20
0.08
NA
0.55
0.04
Zero
Low
Mid
Hieh
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
169 of 199
dAliarpe
l-ECi-'{NICAL [}!:t*UP
Bias/Drift Determinations
Lo.ation,
Source: BoilerNo. l0
Project No.: AST-2023- 1660
Parametcr O, - Outlet CO, - Outlel
Run I Dete 8n423
ipan Value
nitial Instrument Zero Cal Response
.nitial Instrument Upscale Cal Response
lretest System Zero Response
)osttest System Zero Response
Jretest System Upscale Response
)osttest Svstem I Jnscale Resnonse
24.6
0.1
l l.0
0l
0.1
l 1.0
1 1.0
23.8
0.0
10.9
0.0
0.0
108
108
)ias (%)
)retest Zero
losttest Zero
)retest Span
)osffest Snan
0.1
00
-0.2
-03
00
0.0
-06
-0.7
)rift(%\
lero
\4id
-0.1
00
0.0
-0 1
Run 2 Date 8122/23
ipan Value
.nstrument Zero Cal Response
.nstrument Upscale Cal Response
Jretest System Zero Response
)osttest System Zero Response
)retest System Upscale Response
)osttest Svstem I Inscale Resnonse
24.6
0l
I 1.0
0.1
0. I
I1.0
10.9
238
00
10.9
00
0.t
10.8
10.8
Sias (%)
lretest Zero
losttest Zero
?retest Span
)osttest Snan
0.0
0.0
-0.3
-0.4
0.0
0.3
-u. /
-0.7
Drift(%)
Zero
Mid
0.0
-0.2
0.2
0.0
Run 3 Date Ann3
Span Value
lnstrument Zero Cal Response
lnstrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Uoscale Response
24.6
0.1
I 1.0
0.1
0.1
10.9
109
23.8
0.0
10.9
0.1
00
10.8
10.8
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Snan
0.1
0.1
-0.3
-0.5
03
0.0
-0.4
-05
Drift(%)
Zero
Mid
0.0
_nl
-0.4
0.0
170 of 199
&irwe$
an Air Uquide company
Airgas Specialty Gases
Airgas USA LIC
S2S North Industrial loop Road
Tooele, UT8+o74
Airgas.om
CERTIFICATE OF ANALYSIS
Grade of Product: EPA PROTOCOL STANDARD
Part Number:
Cylinder Number:
Laboratory:
PGVP Number:
Gas Code:
E03Nr52E15A38Q7
SG9164824BAL
124 - Tooele (SAP) - UT
872023
C02,02,BALN
Reference Number: 153-402661010-'1
Cylinder Volume: 154.0 CF
Cylinder Pressure: 2015 PSIG
Valve Outlet 296
Certification Date: Feb 13,2023
Date: Feb I
Certifcation pertqmed in sccordanc€ with'EPA Traceability Protml for Assay and Certiication of Gaseous Calibration Srandads Na, 2012)' ooct ment gpe
600/R-12531, using the sssay gocodures listed. Analytical Methodology does not requks corection for anatytical inE.ference- Ttris iytirider has a btal anaMicalunceriainty as slat€d bdw with a coofidence level of g5%, There arE no signitcant impurities which afiect the uae of this catibrauon mixture. Alt concentralions are on amole/mole basis unless othelwise noted. The resulls relateonly to the items tesled. The rBpo.l shall not b€ rEprcdrced except in fuff without appro\fat ofthe laborator. Oo
Not Use Thls Cylinder
Component
ANAIYTICAI RESULTSActuat Protocof-Coneentration Method
Requested
Goncentration
Total Relative
Uncertainty
Assay
Dates
CARBON DIOXIDE
OXYGEN
NITROGEN
24.AO%
24.00 o/o
Balance
23.75%
24.58%
G2 i/- 0,8% NIST Traceable
+/- 0.6% NIST Traceable
0u13t2023
o?,1312023
CALTBRATION STANDARDSType Lot lD Cylinder No Concentration Uncertainty Expiration Date
NTRM
NTRM
1 3060802
09061434
cc415337
cc2E2492
24.04 YO CARBON DIOXIDE/NITROGEN
22.53 0/6 OXYGENNITROGEN
0.6'/o
o.40/"
Dec 1 1, 2025
Mav 13.2025
lnstrumenUMake/Model
AIVALYTICd.L EQUIPMENT
Analytical Principle Last MulUpoint Calibration
Horiba VtA-510 SV4MEUTJ COz
Horiba MPA-510 \ /603MM58 02
GO2 NDIR (Dixon)
02 Paramagnetc (Mason)
Feb 09,2023
Feb 09.2023
Triad Data Available Upon Request
l7l of 199
Page 1 of I
/#
--lI1**.*Accreditation #62754
Red Ball Technical Gas Service
555 Craig Kennedy Way
ShrevepoG LA 71107
800-551-8150
PGVP Vendor lD # G12021
EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS
Cylinder Number:
Product lD Number:
Cylinder Pressure:
coA#
Customer Po. NO.:
Customer:
:80078899
125371
9OO PSIG
:80078E99.2021 0623-o
Certificat'on Oate:
Expiration Oate:
MFG Facility:
Lot Number:
Tracking Number:
Previous Certif, cation Dates:
)7h5n021
)7t13no29
=80078899.2021
0623
)u270876
SMART-CERT
This calibration standard has been certified per the May 20t2 1,
G1.
I l!^ N.rt I lce Thi< (:vlindar Rcl^w {On mid aO 7 Mmr.as.rll I- G'rtirrei.eoncenffifr6;tCi
Analytical Measurement Data Available Online.
Reference Standard{s)
Carbon Dioxide
O:<ygen
Concentiation
1A.74%
10.95 o/o
Unertalnty
iO.05 %
10.09 %
AnaMical Principle
NDIR
MPA
Assayed On
07t15t2021
07n12021
Balance
This is b cediry the gases referenced have been calibratedtested, and verltied to meet the defined specr'lica$ons. This
calibGtionltest was performed using Gases or scales tnat are tfaceable tirough National lnttitljte of standads and
Tecfinology (NlsT) to the lntemagonal s)6tem of units (sl}. The basis of compliance stated is a comparison of the
measureffent parameteG lo $e speclfed or required calibratiorutesijng process. The expended uncertainties use a coverage
?aclor of k=2 to approximate the 95% confidence level of lhe measuremenl unless otheMise noted. This calibration certticate
apdies only b fie item described and shall not be reproduced o$er than in tull, without witten approval fom Red Ball
Tecinical Gas SeNices. f not induded, the uncertainty of celibrations are available upon request and were taken into accounl
when determining pass or fail.
Assistant Oparations Manager
P'ssay Laboratoo/: Red Ball TGS
Ve8im 02J. Revised q 201&0$17
172 of 199
c-/Aliatrce
TIC!"t\icAL Gnt}ilp
Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT
Source: BoilerNo. l0
Project No.: AST-2023-1660
Datez 8122/2023
Traverse Point Time o2
(o/"1
CO,
(oAl
A-l
2
J
9:56
9:57
9:58
3.76
3.94
3.93
9.66
9.57
9.57
Averase 3.88 9.60
Criteria Met Sinsle Point Sinsle Point
173 of 199
10.3.2 The temperature data recorded in the field shall be considered valid. lf, during calibration, the absolute
temperature measured with the sensor being calibrated and the reference sensor agree within '1.5 percent, the
temperature data taken in the field shall be considered valid. OtheMise, the pollutant emission test shall either be
considered invalid or adjustments (if appropriate) of the test results shall be made, subject to the approval of the
Administrator.
Date Sensor ID Reference
Tcmn /oEt
Indicated
Temn (o[')Difference Criteria
3ilv20
3nt/20
3nU20
3ltt/20
3nt/20
3nU20
3nU20
3tnt20
3ltU20
Stack
Probe
Sample Venturi
Oven
Exhaust
Mix I
Dil I
Dilution Venturi
Dilution Aux
1000.0
250.0
250.0
300.0
30.0
70.0
50.0
30.0
68.0
I 001 .0
251.7
251.2
301 .8
30.9
70.5
54.8
30.6
68.6
0.lo/o
0.2o/o
0.2o/o
0.2Yo
0.2%
0.l%o
0.9%
0.loh
0.lo/o
L | .5 Yo (absolute)
2ITsfr:&,
You may use the manufacturer's recommended procedure for calibrating the RH sensors. Verify
the dilution air and mixed gas RH sensor calibrations within three months of each test by
attaching the two sensors to each other and drawing ambient air with approximately 50 to 70
percent relative humidity simultaneously through both sensors. Because the difference between
the two RH sensors is very important in calculating stack gas moisture concentration using this
method, the two RH sensors
must agree within 2.8 percent of reading when monitoring the same gas stream.
Date Console ID Dilution Air
RH (%)
Mixed Air
RH (%)Difference Criteria
3nu20 FPM-C-5o17 64.2 6l. r 0.6%
r 2.8 o/o
(absolute)
2lH"'f ,$
Dilution Venturi
lnstrument Rang€ 10
Reference lnstru ment
Absolute
Difference
Percent
Difference
10.00
9.00
7.00
5.00
3.00
1.50
0.00
9.88
9.01
7.08
5.01
3.02
1.59
o.L4
0.125
0.009
0.082
0.005
0.017
0.087
0.143
1.3
0.1
0.8
0.0
0.2
0.9
L.4
Averase o.67
Venturi
lnstrument Rans€5
Reference lnstru ment
Absolute
Difference
Percent
Difference
s.00
4.00
3.00
2.00
1.00
0.00
4.90
3.93
2.92
7.94
0.93
0.00
0.098
0.073
0.076
0.062
0.07
:
2.0
1.5
1.5
t.2
t.4
0.0
Averase t.26
Pitot
lnstrument Rang€5
Reference lnstrumen
Absolute
Difference
Percent
Difference
5.00
4.00
3.00
2.00
1.00
0.00
4.95
3.95
2.95
1.95
0.9s
0.02
0.055
0.o47
0.0s1
0.0s2
0.051
0.022
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193 of 199
HF Sinclair Woods Cross Refining LLC
PM10 Source Testing
Boiler 10
Source Production Data
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8122/2023 10:56 AM 3:09 PM 56.75 847.07 56.75 48.O7
812212023 4:47 PM 9:14 PM 56.79 847.O7 56.79 48.10
812312023 10:22 AM 2:44PM 66.97 973_77 66.97 65.21
194 of 199
Boiler 10 Test Process Data_PM Testing
Year 2023
Meter: 51Fl-457
Descriptior FuelGas flow to Boiler 70
Units: mscf/h
Notes:
Test Data
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199 of 199
DIVISION OFAIR OUALIW
Source Information
Division of Air Quality
Compliance Demonstration
Source Information
Company Name Holly Refinery - Boiler #10
Company Contact:Travis Smith
Contact Phone No.801-299-6625
Source Designation:Boiler #10
Test & Review Dates
Test Date: 8/22-23/23
Review Date: 11/29/2023
Observer:Robert Sirrine
Reviewer:Robert Sirrine
Particulate Emission Limits
lbs/MMBtu lbs/hr lbs/MW-hr
0.0070 0.500
Emission Rates - "Front Half"
lbs/MMBtu lbs/hr lbs/MW-hr
0.00074 0.0553 0.0001
Test Information
Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn
49.00 13.10 1.1420 1.68 0.761 25.87 -0.11
0.240
Contractor Information
Contracting Company: Alliance Source Testing
Contact: Andrew Bellard
Phone No.: 225-270-6246
Project No.:
8263
Circular
10100
9780
9860
9190
8710
8710
8710
10540
10640
11950
320
10610
10200
10390
1970
1800
1910
1420
1040
1190
1250
F factor used
F factors for Coal, Oil, and Gas
Anthrocite 2
Lignite
Natural
Propane
Butane
COAL
OIL
GAS
Bituminous 2
Fd Fw Fc
scf/MMBtu scf/MMBtu scf/MMBtu O2
CO2
lbs/MMBtu
Page 1
Summary
Division of Air Quality
Reference Methods 5 - TSP
Compliance Demonstration of
Holly Refinery - Boiler #10
Testing Results Lab Data - grams collected
Test Date 8/22-23/23 8/22-23/23 8/22-23/23 8/22-23/23 Lab Data Probe Filter Back
Circular Run 1 Run 2 Run 3 Run 4 Run 1 0 0.00349
As ft^2 13.10 13.10 13.10 Run 2 0 0.00183
Pbar 25.87 25.87 25.81 Run 3 0 0.00216
Pq (static)-0.11 -0.11 -0.15 Run 4
Ps 25.86 25.78 25.80
Avg. Ts F 332.70 331.60 333.40 Front Half Emissions Summary
CO2 - FCO2 9.17 8.75 8.90 Run 1 Run 2 Run 3 Run 4 Avg.
O2 4.43 4.92 4.45 gr./dscf 0.00068 0.00037 0.00042 0.0005
N2+C 86.40 86.33 86.65 lbs/hr 0.0816 0.0419 0.0424 0.0553
lbs/MW-hr 0.0002 0.0001 0.0001 0.0001
Md 29.64 29.60 29.60 lbs/MMBtu 0.00102 0.00056 0.00063 0.00074
Ms 28.13 28.09 28.09
Y 1.1420 1.1420 1.1420
Cp 0.76 0.76 0.76 Total Emissions Summary w/back half condensable
Vm cf 78.80 77.30 79.30 Run 1 Run 2 Run 3 Run 4 Avg.
Vlc 82.30 82.30 82.30 gr./dscf 0.0007 0.0004 0.0004 0.0005
AVG. Tm F 74.65 80.85 84.70 lbs/hr 0.0816 0.0419 0.0424 0.0553
lbs/MW-hr 0.0002 0.0001 0.0001 0.0001
Vm std 78.80 77.30 79.30 lbs/MMBtu 0.0010 0.00056 0.00063 0.0007
Vw std 3.87 3.87 3.87
Bws 0.13 0.13 0.13
S Bws 1.00 1.00 1.00
Avg. Sqrt Dlp 0.52 0.50 0.53
Vs 35.35 34.08 36.15 F factor used
scfm wet 1.60E+04 1.54E+04 1.63E+04 8263
acfm 2.81E+04 2.68E+04 2.40E+04
Qsd dscfh 8.36E+05 8.03E+05 7.05E+05
# Sample
Points 12.00 12.00 12.00
Dn 0.240 0.260 0.260
An 3.14E-04 3.69E-04 3.69E-04
Start Time
End Time
Total Test
time 240.00 240.00 240.00
Time @ point 20.00 20.00 20.00
O2
CO2
lbs/M
Page 1
Run 1
Holly Refinery - Boiler #10 Flow & Moisture Test Date 8/22-23/23
As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms
13.10 25.87 -0.11 25.86 333 9.17 4.43 86.40 29.64 28.13
Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 8.5921
1.1420 0.76 78.800 82.30 74.65 78.800 3.874 0.1300 0.9990 0.999
Avg. Sqrt
Dlp Vs scfm wet acfm Qsd dscfh
# Sample
Points Dn
Total Test
time (minutes)
Time @ point
(minutes)Avg. Dlh
0.521 35.35 15,992 28,129 8.36E+05 12 0.24 240 20.00 1.110000
FALSE
Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected
1 0.000 0.271 1.11 333 76 73.1 Wt. (Final) Wt. (Initial) lc
2 78.800 0.271 1.11 333 76 73.1 532.9 482.1 50.8
3 426.8 407.4 19.4
4 254.1 249.1 5.0
5 517.5 510.4 7.1
6 0.0
7
8 Isokinetics 87.9
9 Test Date 8/22-23/23
10 Start Time enter enter
11 0.2330 enter
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
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Page 1
Run 2
Holly Refinery - Boiler #10 Flow & Moisture Test Date 5/13/2009
As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms
13.10 25.79 -0.10 25.78 332 8.75 4.92 86.33 29.60 28.09
Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 8.4882
1.1420 0.76 77.300 82.30 81 77.300 3.874 0.1300 0.9990 0.999
Avg. Sqrt
Dlp Vs scfm wet acfm Qsd dscfh
# Sample
Points Dn
Total Test
time (minutes)
Time @ point
(minutes)Avg. Dlh
0.501 34.08 15,389 26,775 8.03E+05 12 0.26 240 20.00 1.11
FALSE
Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected
1 0.000 0.25 1.11 332 81 81.0 Wt. (Final) Wt. (Initial) lc
2 77.300 0.25 1.11 332 81 81.0 532.9 482.1 50.8
3 426.8 407.4 19.4
4 254.1 249.1 5.0
5 517.5 510.4 7.1
6 0.0
7
8 Isokinetics 75.4
9 Test Date 8/22-23/23
10 Start Time enter
11 0.2330 enter
12
13
14
15
16
17
18
19
20
21
22
23
24
25
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Page 1
Run 3
Holly Refinery - Boiler #10 Flow & Moisture Test Date 5/13/2009
As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms
13.095 25.81 -0.15 25.80 333 8.90 4.45 86.65 29.60 28.09
Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 8.6967
1.1420 0.76 79.300 82.30 85 79.300 3.874 0.1300 0.9990 0.999
Avg. Sqrt
Dlp Vs scfm wet acfm Qsd dscfh
# Sample
Points Dn
Total Test
time (minutes)
Time @ point
(minutes)Avg. Dlh
0.531 36.15 16,297 24,010 7.05E+05 12 0.26 240 20.00 1.11
FALSE
Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected
1 0.000 0.282 1.11 333 85 Wt. (Final) Wt. (Initial) lc
2 79.300 0.282 1.11 333 85 532.9 482.1 50.8
3 426.8 407.4 19.4
4 254.1 249.1 5.0
5 517.5 510.4 7.1
6 0.0
7
8 Isokinetics 72.5
9 Test Date 8/22-23/23
10 Start Time enter
11 0.2330 enter
12
13
14
15
16
17
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Page 1