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HomeMy WebLinkAboutDAQ-2024-0042961 DAQC-1298-23 Site ID 10123 (B4) MEMORANDUM TO: STACK TEST FILE – HF SINCLAIR – Woods Cross Refining, LLC THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Robert Sirrine, Environmental Scientist DATE: November 28, 2023 SUBJECT: Source: Boiler #10 Location: 1070 West 500 South, West Bountiful, Davis County, Utah Contact: F. Travis Smith: (801) 299-6625 Tester: Alliance Source Testing FRS ID #: UT00000049011000013 AO #: DAQE-AN101230057-23, dated November 15, 2023 Action Code: Tr Subject: Review of stack test report dated October 20, 2023 On October 20, 2023, Utah Division of Air Quality (DAQ) received a stack test report for testing of Boiler #10 located at the HF Sinclair Woods Cross Refinery in West Bountiful, Davis County, Utah. Testing was performed August 22-23, 2023, to determine compliance with the PM10 emission limit found in Conditions II.B.1.a, and II.B.6.a. The DAQ calculated results are: Source Test Date RM/Pollutant DAQ Result Test Result Limit Boiler #10 8/22-23/23 CTM-039/PM10 0.00074* 0.00074* 0.0070* *lb/MMBtu DEVIATIONS: No deviations were noted. CONCLUSION: The test report appears to be acceptable. RECOMMENDATION: The Boiler #10 PM10 emissions appear to have been in compliance with the applicable limit at the time of testing. HPV: Yes. ATTACHMENTS: Stack test report received October 20, 2023 DAQ generated excel spreadsheets ,,tttF$nctorr HF Sinclair Woods Cross Refining LLC 1070 W. 500 S, West Bountiful, UT 84087 801 -299-6600 | HFSinclair.com TJTAH DEPAHTMENT OF E}WIRONME}.ITAL OUATITY 0cT 2 0 ",,'"?, October 20,2023 Mr. Bryce Bird, Director Division of Air Quality Utah Dept. of Environmental Quality 195 North 1950 West Salt Lake City, Utah 841l6 RE: Annual PMro Emissions Test Report - Boiler #10 HF Sinclair Woods Cross Refining LLC, Davis County Dear Mr. Bird: ,mib* o#t;$"d,#* Hand Delivered In accordance with Conditions tr.B.l.a and II.B.6.a of Approval OrderANl01230055-23,please find enclosed theresultsofourrecentPMroemissionstestingforBoiler#10. ThetestingwasconductedAugust22-23,2023. The test results were 0.00074 lbs/IvlMBtu for PMro. Enclosed, please find a copy of the testing report for Boiler #10. If you have any questions or need additional information, please contact F. Travis Smith at (801) 299-6625 or email ftravis.smith@hfsinclair.com. I certify that: Testing was conducted while the source was operating at the rate and/or conditions specified in the applicable approval order, operating permit, or federal regulation; During testing, the source combusted fuels, used raw materials, and maintained process conditions representative ofnormal operations, and operated under such other relevant conditions specified by the Director; Based on information and belief formed after reasonable inquiry, the statements and information contained in the report are true, accurate, and complete. Sincerely, Vor,--r [;.^^-.^2- Dustin Simmonds Vice President and Refinery Manager Enclosure c: E. Benson (r\File2.4.4 K. Arnold J. Barton J. Orr UT{II DEPART\IENT OF ENV iROi.l lrtEr',lTAL OUALITY Al;3retr'{ffi Source Test Report HF Sinclair Woods Cross Refining, LLC 1070 West 500 South West Bountiful, UT 84087 Source Tested: Boiler No. 10 Test Dates: August 22 & 23,2023 Project No. AST-2 023 -1660-009 S.*,*Y'ffi'f* Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 pilr6rpe TECI--I NICAL GNCTJ t]Source Test Repoil Test Progmm Summary Regulatorv Information Permit No. DAQE-AN101230055-23 Source Information Source Name Refinery Gas Fired Process Boiler Contact Information Source ID Boiler No. l0 Target Parameters PMIO, PM2.5 Test Location Test Company Analytical Laboratory HF Sinclair Woods Cross Refining, Alliance Technical Group, LLC Eurofins TestAmerica Charles Horton eric.benson@hfsinclair.com charles.horton@lliancetg.com 5815 Middlebrook Pike Knoxville, TN 37921 Kevin Woodcock Project Manager kevin.woodcock@testamericainc.com (865) 291-3000 LLC 1070 West 500 South West Bountiful, UT 84087 Eric Benson (801)299-6623 F. Travis Smith ft rav is. sm ith@hfsinc lair. com (80r)299-662s 3683 W 2270 S, Suite E West Valley City, UT 84120 (352\ 6r3-7s68 Field Team Leader Tobias Hubbard tobias.hubbard@alliancetg.com (60s) 645-8562 QA/QC Manager Kathleen Shonk katie. shonk@alliancetg.com (812\ 4s2-4785 Report Coordinator Sarah Perry sarah.perry@all iancetg.com HF Sinclair - West Bountiful, UTAST-2023-1660-009 2 of 199 Page i puthrpe TFCIlNICAL GIJCUP Source Tesl Reporl C ert irt c ot ion St o t eme nt Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the relevant sections in the test report. This report is only considered valid once an authorized representative ofAlliance has signed in the space provided below; any other version is considered draft. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. ,,' ii,)/ / t/, t0/12t2023 Charles Horton, QSTI Alliance Technical Group, LLC Date HF Sinclair- West Bountiful. UTAST-2023- I 660-009 3 of 199 Page ii N,6rEe TECI-I NICAI GBOUP Source Test Report Table ofContents TABLE OF CONTENTS l.l Emission Unit and Control Unit Descriptions................. ........................... l-l 1.3 Site-Specific Test Plan & Notification ......... l-l 3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate ..... 3-l 3.2 U.S. EPA Reference Test Method 34' - Oxyger/Carbon Dioxide.......... .......................... 3-l 3.3 U.S. EPA Reference Test Method 4 - Moisture Content.......... ................. 3-l 3.4 U.S. EPA Conditional Test Method 039 - PMI0/PM2.5.............. .............3-2 3.5 U.S. EPA Reference Test Method l9 - Mass Emission Factors........... ............................ 3-3 3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3,A'.......................................... 3-3 LIST OF TABLES Table 2-l: Summary of Results- PMI0/PM2.5. ..........2-l APPENDICES Appendix A Sample Calculations Appendix B Field Data Appendix C Laboratory Data Appendix D Quality Assurance/Quality Control Data Appendix E Process Operating/Control System Data FIF Sinclair - West Bountiful, UTAST-2023- I 660-009 4 of 199 Page iii 5 of 199 pilr6rpe TECI-]INICAi GRCUP Source Test Report Introduction 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by HF Sinclair Woods Cross Refining, LLC (HF Sinclair) to conduct compliance testing at the Woods Cross Refinery in West Bountiful, Utah. Portions of the facility are subject to provisions of the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-AN101230055-23. Testing was conducted to determine the emission rates of particulate matter less than or equal to l0 microns (PMl0) and particulate matter less than 2.5 microns (PM2.5) from the exhaust of BoilerNo. 10. l.l Emission Unit and Control Unit Descriptions 1.2 Project Team Personnel involved in this project are identified in the following table. Table l-l: Project Team HF Sinclair Personnel Matthew Howes Alliance Personnel Tobias Hubbard Supilani Mailei 1.3 Site-Specific Test Plan & Notification Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by HF Sinclair. HF Sinclair - West Bountiful, UT Boiler No. l0 Steam boiler, 89.3 MMBtU/hr HFIV, fired on plant gas, forced draft, I burner, side-fired furnace, no air preheat. Stack temperature aooroximatelv 3 l0-500oF. Selective catalytic reduction using aqueous or anhydrous ammonia AST-2023- I 660-009 6 of 199 Page l-l 7 of 199 Source Tesl Reporl Summary of Results 2.0 Summary of Results Alliance conducted compliance testing at the HF Sinclair facility in West Bountiful, Utah on August 22 and 23, 2023. Testing consisted of determining the emission rates of PM2.5 and PM l0 at the exhaust of Boiler No. 10. Table 2-l provides a summary of the emission testing results. Any difference between the summary results listed in the following table and the detailed results contained in appendices is due to rounding for presentation. Table 2-l: Summary of Results - PMl0/PM2.5 Nrrmher Runl Run2 Run3 A )ate itart Time itop Trme 8122/23 l0:56 l5:08 8/22/23 t6 4'7 2l: l3 8/23/23 l0:22 l4:44 INPIIT DATA :uel Go Flow Rate, scflr Ieat Input, MMBtu/hr ruel Factor (O2 dry), dscCMMBtu ldometric Pressure, in. Hg vleter Correction Factor llozle Diameter, in \rea of Nozle, ft2 fotal M6s of PMl0 [m, mg (m2 + m] + mr + mr) total M6s of PM < l0 l.m and >2 5 pm, mg (m2) fotal M6s of PM <2.5 um. mq (m. + m, + m.) (FR) (HI) (Fd) (Pb) (Y) (Dn) (An) (mruru) (mpuro.::) (mpur <) 56,750 48.07 8,288 25.47 1 142 0.240 0.0003 I 3.49 0 089 340 56.7e0 48. l0 8,288 25.79 t.t42 0.260 0 00037 1.83 0.000 1.83 66,970 65.21 8,213 25.8 r t.t42 0.260 0.00037 2.t6 0.000 2.16 60,170 53.79 8,263 25.82 1.t42 o.253 0.00015 249 0.030 .-TM-O3S I,rl.:.:FR DATA )ilution Flow Rate, dscfm iample Flow Rate, dscfm y'olume Sampled, dscf y'olume Sampled, dscm y'iscosity {eynolds Number )unningham Conection Factor 'articulate Cut Diameter for PMl0 )articulate Cut Diamcter for PM2.5 )ilution Ratio !,[oisture Fraction Me6ured sokinetic Samnling Rate /7") (Qr"a) (Q<*a) (V<uai) (Vqrar) (r) (N,") (c) (Dso) (Dso) (DR) (BwSrud) (I) 4.28 0.328 78.8 2.23 230 0 2,23t.5 l.l I 1 0.14 246 14.03 0.140 984 6.98 0.33 I 79.3 2.25 225.4 2,352 4 Lll 9.89 2.32 22.07 o.147 843 5.98 o 327 78.5 2.22 226.7 2,296.0 l.ll 10.05 2.39 19.24 0.146 900 6.67 't7.J 2.19 224 I 2.304.1 l.l I l0.l I 2.39 2t 63 0 I50 474 EMISSION CALCIlLATIONS ,M ,M ,M ,M 0 Concentration, Srairl/dscf 0 Concentration, mg/dscm 0 Emission Rate, lb/hr 0 Emission Factor, lbA4MBtu (O2) 0 Emission Rate- lb/lViMscf fuel ca (Cpvro) (Cprrru) (PMR) (EFruro ozo) (8R,.,,^) 0.00068 1.56 8.2E-02 l.08-03 I 4E+00 0.00036 0.834 4.tE-02 5.6E-04 7.2E'-0t 0.00042 0.960 4.2E-02 6.3E-04 6.3E-01 0.00049 t.t2 5.5E-02 '1.4E-04 9.38-01 PM PM PM PM PM 0 gm and >2.5 pm Concentration, grair/dscf 0 gm and >2.5 [m Concentration, mg/dscm 0 gm and >2.5 gm Emission Rate, lb/hr 0 pm and >2.5 pm Emission Factor, lbA,tMBtu (O2) 0 um and >2 5 um Emission Rate- lb,MMscf fuel ca 0 0000 0.000 0.08+00 0.08+00 0 0E+00 (cpuro-:s) 0.000018 (cpuro-z.s) o.o4o (PMR) 2.l E-03 (EFpvro-: s or) 2.6E-05 (ER,^,,",.) 37E-O2 0.0000 0.0000058 0.000 0.013 0.0E+00 7.08-04 0.0E+00 8 8E-06 0 0E+00 t.2E-02 'M <2.5 Concentration, grain/dscf 'M <2.5 Concentration, mg/dscm 'M <2.5 Emission Rate, lb/hr 'M <2.5 Emission Factor, lbA4MBtu (O2) 'M <2 5 um Emission Rate- lbttr4Mscf fuel sm 0.00067 1.52 '1.9E-02 l.0E-03 l 4E+00 0.00036 0.814 4 tE-02 5.6E-04 7.2E-Ol 0.00042 0.960 4.2E-O2 6.3E-04 6.3E-0t 0.00048 I ll 5.4E-O2 't.3E-O4 9.2E41 (cplr: s) (Cpu: s) (PMR) (EFpu:.r.:a) GR".,,.) HF Sinclair - West Bountiful, UTAST-2023- I 660-009 8ofl99 Page2-l 9 of 199 puahrpe TFCT] NICAI GROUP Source Test Repon Testins Methodolosv 3.0 Testing Methodology The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method descriptions are provided below while quality assurance/quality control data is provided in Appendix D. Table 3-l: Source Testing Methodology 3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Yolumetric Flow Rate The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA Reference Test Method l. To determine the minimum number of traverse points, the upstream and downstream distances were equated into equivalent diameters and compared to Figure l-l in U.S. EPA Reference Test Method l. Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type thermocouple and pyrometer. Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2. 3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide The oxygen (O2) and carbon dioxide (COz) testing was conducted in accordance with U.S. EPA Reference Test Method 3,dt. Data was collected online and reported in one-minute averages. The sampling system consisted of a stainless-steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.6. 3.3 U.S. EPA Reference Test Method 4 - Moisture Content The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on the same balance to determine the amount of moisture condensed. HF Sinclair - West Bountiful, UT Full Velocity Traverses Oxygen / Carbon Dioxide Particulate Matter less than l0 Microns / Particulate Matter less than Mass Emission Factors AST-2023- I 660-009 l0 of 199 Page 3-1 tffi 1r,1 I r._, il. A i i .'\-)I),iir Source Tesl Reg),l Testing Methodolow 3.4 U.S. EPA Conditional Test Method 039 - PMI0/PM2.5 The PMl0 and PM2.5 testing was conducted accordance with U.S. EPA Conditional Test Method 039 (CTM-039). CTM-039 does not include drawing sample gas through impingers, but instead mixes the sample with dilution air in a mixing chamber to replicate the dilution and cooling of the stack effluent in the atmosphere. The filterable and condensable particulate matter is collected together (Section l.l ). The major components of the CTM-039 sampling train are: in-stack PMl0 and PM2.5 cyclones; a heated sample probe; a pre-dilution tee and mixing cone; a mixing (residence) chamber, two blowers and other ancillary equipment (Section 8.4). Per Section 8.6 of CTM-039 the probe, sample venturi, and heated compartment temperatures are to be maintained at least l0 degrees F above the stack gas temperatures; this is not feasible due to the high temperature ofthe stack. The equipment was ran at as high of a temperature as manageable and all heated and unheated components were recovered into the same sample fraction and analyzed together. A PM2.5 cyclone is located after the PMl0 cyclone. Stack gas is extracted at a pre-determined constant sampling rate to achieve near 100%o isokinetic sampling ratios through the in-stack PMl0 and PM2.5 cyclones. The cyclones separate particles with nominal aerodynamic diameters of greater than l0 pm, less than lOpm and greater than 2.5 pm, and allow particles less than or equal to 2.5 pm and stack gases to continue through the heated sample probe and heated sample venturi to be dituted and cooled in the mixing cone and residence chamber before being captured by the 142-mm filter. Filtered, dehumidified, and temperature adjusted dilution air is added to the stack gas sample (now containing only the particles of less than 2.5 pm) in a mixing cone. After mixing of the dilution air and stack sample gas to allow for particulate condensation, PM2.5 is captured on a glass fiber filter bonded with polytetrafluoroethylene (PFTE) (Section 2.0). A preliminary velocity traverse was performed prior to the first run to verify the absence of cyclonic flow and determine average velocity. A preliminary moisture run was conducted to target sampling conditions. Sampling was conducted at multiple traverse points during each run. (Section 8.2). The sample train was operated as described in Section 8.6 with data collected electronically (Sections 6.5.1 and 8.6.4.4). Each test consisted of three (3) approximately 24O-minute runs. At the completion of each test run, a leak check of the non-diluted sample section was done after removing the cyclones. The leak check was performed by attaching a vacuum pump to the mixing chamber at the dilution air entrance. A vacuum was pulled to verif a leak rate of less than 0.02 cfm using the rotameter on the front end of the vacuum pump (Section 8.5.1.2 and 8.6.4.6). The CTM-039 recovery of the 142- mm filter and rinses were conducted as described in Section 8.7: . Container No. I (Nozzle and Cyclone I) o Great than PMl0 - optional r Container No. 2 (Cyclones I and IV) o PMl0 to PM2.5 acetone rinse o Container No. 3 (Mixing Cone, Residence Chamber, and Filter Holder Inlet) o less than PM2.5 water rinse o Container No. 4 (Cyclone IV, Probe, Sample Venturi, Mixing Cone, Residence Chamber, Filter Holder Inlet) o less than PM2.5 acetone rinse r Container No. 5 (Filter) o 142 mm filter A sample train blank was not collected. HF Sinclair - West Bountiful, UTAST-2023- I 660-009 ll ofl99 Page 3-2 AI i i i.r Source Test Report Testing Methodologt 3.5 U.S. EPA Reference Test Method 19 - Mass Emission Factors Fuel samples were procured and analyzed onsite by HF Sinclair. Samples were collected as close as possible to each test run for each source. The laboratory analysis was used to calculate a dry Oz based F-Factor in accordance with U.S. EPA Reference Test Method 19. The mass emission factor (lb/MMBtu) was calculated using the pollutant concentration, O2 concentration and the calculated F-Factor. 3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3A Cylinder calibration gases used met EPA Protocol I (+l- 2o/o) standards. Copies of all calibration gas certificates can be found in the Quality Assurance/Quality Control Appendix. Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Leve[ gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases were sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5o/o absolute difference. High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe and the time required for the analyzer reading to reach 95 percent or 0.5o/o (whichever was less restrictive) of the gas concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was recorded. Next, Low Level gas was introduced at the probe and the time required for the analyzer reading to decrease to a value within 5.0 percent or 0.5o/o (whichever was less restrictive) was recorded. If the Low-Level gas was zero gas, the response was 0.57o or 5.0 percent ofthe upscale gas concentration (whichever was less restrictive). The analyzer reading was observed until it reached a stable value and this value was recorded. The measurement system response time and initial system bias were determined from these data. The System Bias was within 5.0 percent ofthe Calibration Span or 0.5o/o absolute difference. High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the analyzer response was stable, the value was recorded. Next, Low Level gas was introduced at the probe, and the analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the Calibration Span or 0.57o absolute difference or the data was invalidated and the Calibration Error Test and System Bias were repeated. Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.5%o absolute difference. Ifthe drift exceeded 3 percent or 0.5oh, the Calibration Error Test and System Bias were repeated. To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The pollutant concentrations were measured at three points (16.7, 50.0 and 83.3 percent of the measurement line). Each traverse point was sampled for a minimum of twice the system response time. If the diluent concentration at each traverse point did not differ more than 5 percent or 0.3o/o (whichever was less restrictive) ofthe average pollutant concentration, then single point sampling was conducted during the test runs. If the pollutant concentration did not meet these specifications but differed less than l0 percent or 0.5%o from the average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in diameter - 16.7, 50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter - 0.4, L0, and 2.0 meters from the stack wall). Ifthe pollutant concentration differed by more than l0 percent or 0.5%o from the average concentration, trla HF Sinclair West Bountiful. UTAST-2023- l 660-009 l2ofl99 Page 3-3 Altfu TECHNICAL GROUP fuurceTesl Repn Testine MetWologt then sampling was conduct€d at a minimum of twelve (12) taverse points. Copies of sfratification check data can be found in the Quality Assurance/Quality Control Appendix. A Data Acquisition System with battery backup was used to record the insfument response in one (l) minute avorages. The data was continuously stored as a..CSV file in Excel format on the hard drive of a computer. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving fte facility. Once arriving at Alliance's office, all written and electronic data was relinquished to the rcport coordinator and then a final review was performed by the Project Manager. HF Sirclair - West Bountitul, UTAST-2023-166G,009 13 ofl9 Eage 34 l4ofl99 TECI.{\IQAI- GROUP Location; HF Sinclair Woods Cross Refining, LLC - Wesl Bountiful, UT Source: BoilerNo. l0 Project No.: AST-2023-1660 Run No. /Method Run I / Method 3,A' 0z - Outlet Concentration (Cd, % dry Co,= (Cou,-Co). ( #;) where, C*, ..1!1!!-: average aralyzer value during tesr, yo dry Co 0.08 : average ofpretest & posttest zero resporises,% WCue 10.97 = actual concenttation of calibration gar',Yodry Cr-il:i-: average of pretest & posttest calibration responses, o/o dry Co, 4.43 : Oz Conoentration,96 dry l5 of 199 dAlArEeTT*}.f\ICAL GR(}Ui} Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful. UT Source: BoilerNo. l0 Proj ect No. : !$!Q!l - !.66Q Run No. /Method Run I / Method 3A CO: - Outlet Concentration (C6s), 7o dry Cco,: (Cou,-Cor- ( #e;) where, Co6. 9.15 : average analyzer value during test,o/odry C"&=averageofpretest&posttestzeroresponses,o/odry Cn,1o 10.80 :actualconcentrationofcalibration gas,o/odry CM 10.78 : average ofpretest & posttest calibration responses, o/o dry Cco, 9.17 : CO. Concentration,%o dry l6 of 199 #' AIilarrcrEr-f rrt)il$l j{}AL Gn()UP Location: HF Sinclair Woods Cross Refining,LLC - West Bountiful, UT Appendix A Example Calculations Source: Boiler No. l0 Project No.: AST-2023-1660 Run No.: I Parameter: VFR Average Stack Gas Flow at Stack Conditions (Qa), acfm Qa : 60x Vs x At where, Vs 35.8 = stack gas velocity, ftlsec As 13. l0 : cross-sectional area ofslack, ft2 Qa 28,129 : acfm Average Stack Gas Flow at Standard Conditions (Qs), dscfm 8s - 17.647x Qa x (l - BWS)" P' Ts Qa 28,129 = average stack gas flow at stack conditions, acfm BWS 0.140 = moisture fraction, dimensionless PrA= absolute stack gas pressure, in. Hg Ts 792.7 : absolute stack temperature, "R Qs 13,933 : dscfm 17 of 199 1: ''t\'; 'l Conditional Test Method (CTM) 039 Example Hand Calculation QA Facility: HF Sinclair Woods Cross Relining Source: BoilerNo. l0 Run No.: Test Date:8n2n023 Wt./Vol of Aetone Blank (mg/mL); Coraainer No.6 m o - Net Weight of Acetone Blonk (Contqiner No. 6), ng V o - Voltme ofAcetone Blonk, mL 0.79 g cn3 - density ofacetone Net Weight ofPM Due to Acetone, mgi Contairer No. 2 wa = 86.8 x 0.0063 we =0.54s l'., : L'olume ofAcetone, mL C " - Wt. Vol. ofAcetone Blank, mg ml. Nea Weight of P8rticulate Matter (Blank Corrsted), mg; Container No. 2 l[2*o.. = 0-445 - 0.545 [2-"o". = 0.0000 mg m 2 : Weight of Pafliculate Mauer (Container No. 2), hg ll/ " = Nel Weight of PM Due to Acetone, mg rFor csults reponed with negalive rcsuhs.0.0000 sas used fior the calculations Net Weight ofPM Due to Acetone, mg; Contain€r No. 4 wr = l9l.f x 0.0063 wa = 0.790* V ,, : Volume of Acetone, mL C " .- Wt. l/ol. of Acetone Blank, mg mL 'frax allor'ab le sub truct ion Net Weight of Particulate Matter (Blank Corrsted), mgi Contsiner No. 4 [+co" = 1.39 - 0.790 [2-"o"" =0.600 m ! = Weighl of Pqrliculqte Mqrler ((:onlainer No. t), mg W . = Net Weight of PM DLe to Acetone, mg *For resulb rcpoied w-ilh negrtiye rcsult3.0-0000 $s used for the calculations Wt./Vol of DI Wrter Blatrk (mg/mL); Cortainer No. 7 Cr=C-= ^ l.t9L' 239.7 * o.7g Lr - 0.0063 mg/mL 0.0052 my'mr- t.4s 276.7 V" - Net Weight ofAcetone Blank (Container No. 6), mg - Volume ofAcetone Blqnk, mL l8ofl99 ArmrpEr -t Conditional Test Method (CTM) 039 Example Hand Calculation QA Facility: HF Sinclair Woods Cross Refining Source: BoilerNo. l0 Run No.: Test Date:anzno23 Net Weight of PM Due to DI Water, mg; Container No. 3 ww= 185.9 x 0.0052 ww = 0.974 ms V., = Volune of DI Woter, ml- C . : llr. Vol. of Dl lltater Blank, ng ml Net Weight of Particulat€ Matter (Blank Correted), mg; Container No. 3 Dj-"o""= 1.13 - 0.974 IIl3-"o"" = 0.156 mg m j - lleight of Particulote Matter (Contoiner No. 3), mg W * - Net Weight of PM Drc to Dl llater, mg 'For results rcpo(ed rvith nogatiYe resulls. 0.0000 \rd used for th€ calculations Conentration (mg/dscm) LPMIo - (0.0000 + 0.156 + 0.600 + 1.07)cPruto = 0.834 m8/dscm2.19 (l p.rtto Pailiculdte concenffqlion (ng dsch) m2<on-ContqinerNo.2Mass-PM.l0lman.l:'2.5 qm(AcetoneRinse):NetWeightofPar,icilldteMattet(BlqnkCorrected),mg m),oE-ContqinqNo.3Mqss-PM:2.5ym(DIRinse):NetWeightofPqrriculoteMqrter(DlWaterBlankCorrected),mg m a-.oft - Container No. -t Mass - PM --2.5 pm (Acetone Rinse): Nel Weight of Poiliculate Mqtter (Acetone Bldnk Conected), mg mi = Contqiner No. 5 Mass - PM ,.2.5 ln (F iher): Weighr of Pdrticuldte Motter, mg V ",o4 - Sample voluile al stdnddrd conclitions (nt I Emission Rate (lb/MMBtu) D Lttttt - c,rro 20.9v L ?- (zo.o - or)PM to - 3s .3147 x 4s3,sg} E r^r,o Emission rdle (lb,MMBlu) C p111n - Pollulant concentrution (mg dscm) Fd = DryO2 bosedF Factor(lscfMMBtu) O 2 = Slack gas oxygen concenlrotion (o%vd) x 8,287.6 X0.83 20.9Epuro = 3s.3147 X 453,592 l9 of 199 (2O.9 - 4.921 Eprrro = 5.68-04 tb/rvtMBtu EAIilalpEr'1 i:i, rl r{ !{) Al {;':i{'1 l: rl Conditional Test Method (CTM) 039 Example Hand Calculation QA Facility: HF Sinclair Woods Cross Refining Source: BoilerNo. l0 Run No.: Test Date:aDzDO23 M pilfi : Emission rate (lb hr) C pwo : Pollutant concentrqtion (mg dscm) Q s = Stack gasflov rote (dscfm) 60 = Minutes per hour f,f, _ 0.E34 X l3,l19x 60 35.3147 X 4s3,592 Emision Rate (lb/MMscf) Emirsion Rate (lb/hr) Ero, C'Y+:: - xQ"ax 60ro 35 3:,47 x 453 ,592 ^ Y ER ,r ro = M pu to * Fuel- -flow Mpuro = 4.lt-02 lb/hr ERpruro = 7.28-01 lb/MMscf 106 Epnlo = ER p11p - Emission rate (b MMscl) M p.\t!o - Emission rate (lb hr) F-uel Flot - Fuel gas flot, rote (scJh) 4.1E.42 I 56,790 1,000,000 20 of 199 ocT 2 0 2023 2l of 199 {:r-lfd fi*"t_ GirfiL; r Emission Calculations Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT so,.ceT6iiiif6]J6- P.o.lect No. lun Number Runl Run2 Run3 Averase )ate itart Time itop Time lun Time, mrn (e) 8t22t23 I 0:56 I 5:08 240.0 8t22t23 l6:47 2l:13 239.8 8/23123 l0:22 14.44 240.0 239.9 INPTTT DATA Fuel Gas Flow Rate, scfh Heat [nput, MMBtr/hr Fuel Factor (O2 dry), dscf/MMBtu Barometric Pressure, in. Hg Meter Correction Factor Nozzle Diameter, in Area of Nozzle. ft2 Total Mass of PMl0 ;rm, mg (ml + mr + mr + mj) Total Mass of PM <10 pm and >2.5 pm, mg (m2) Total Mass of PM <2.5 [m, mg (ml + m4 + mi) 60, I 70 53.79 8,263 25.82 t t42 0.253 0.00035 2.49 0.030 2.46 (FR) (HD (Fd) (Pb) (Y) (Dn) (An) (mpuro) (mpvr,r,: s) (mo.r.) 56,750 48.07 8,288 25 87 t t42 0.240 0 0003 1 3.49 0 089 340 56,790 48 10 8,288 25.79 I.t42 0.260 0.00037 183 0.000 1.83 66,970 65.2t 8,2t3 2s 8r t.142 0 260 0 00037 2.16 0.000 2.16 CTM-039 I,OGGER DATA Dilution Flow Rate, dscfm Sample Flow Rate, dscfm Volume Sampled, dscf Volume Sampled, dscm Viscosity Reynolds Number Cunningham Correction Factor Particulate Cut Diameter for PM l0 Particulate Cut Diameter for PM2.5 Dilution Ratio Moisture Fraclion Measured lsokinetic Sampling Rate, (%) 5.98 0.327 785 2.22 226.7 ) )oAr], lu 10 05 2.39 t9.24 0.146 900 (Qqoo) (Qq"ay) (V.i*o) (Vn*o) (u) (N,.) (c) (Dso) (Ds,,) (DR) (BWSmsd) (l) 428 0.328 788 : l) 230 0 2,231.5 t ll t0 l4 246 14.03 0.140 984 6.67 0.322 77.3 2.19 224.8 2.304.1 l.ll l0 lI 2.39 2t.63 0.150 874 6.98 0 331 79.3 225 225 4 )7\11 l ll 9.89 232 22.07 0 t17 843 EMISSION CALCULATIONS )M I 0 Concentration, grainldscf )M I 0 Concentration, mg/dscm )Ml0 Emission Rate, lb/hr )M l0 Emission Factor, lb/Ir4MBtu (O2) )M l0 Emission Rate, lb/MMscf fuel gas (Cpurn) (Cpvro) (PMR) (EFpu ro o:o) (ERpv,n) 0 00068 1.56 8 2E-02 l.0E-03 I 4E+00 0 00036 0 834 4.tE-02 5 6E-04 7 2F,-01 0.00042 0 960 4.2E-02 6 3E-04 6.3E-01 0.00049 t.t2 5.5E-02 7.4E-04 9.3E-01 PM< PM< PM< PM< PM< 0 pm and >2.5 pm Concentration, grain/dscf 0 pm and >2.5 pm Concentration, mg/dscm 0 pm and >2.5 pm Emission Rate, IbArr 0 pm and >2.5 pm Emission Factor, lb/MMBtu (O2) 0 pm and >2.5 pm Emission Rate, lb.MMscf fuel gas (Cruro-: s) 0.00001 g (Cpvru,z.s) o.o4o (PMR) 2.lE-03 (EFpy111.' 5s'3) 2.6E-05 (ERpMu-,,) 3.7E-02 0 0000 0.000 0.08+00 0.0E+00 0 0E+00 0.0000 0 000 0.0E+00 0.0E+00 0.08+00 0.0000058 0 013 7.0E-04 8.8E-06 t 2E-02 (Cpu: s) (Cpv: s) (PMR) (EFPM2 5 o2d) (ERpv: s) 0 00067 1.52 7.9E-02 l 0E-03 I 4E+00 0.00036 0 834 4.tE-02 5 68-04 7.2E-0t 0 00042 0.960 4.28-02 6.38-04 6 38-0t 0.00048 tu 5.4E-02 7 3E-04 9 2E-01 )M <2.5 Concentration, grain/dscf )M <2.5 Concentration, mg/dscm )M <2.5 Emission Rate, lb/hr )M <2.5 Emission Factor, lb/MMBtu (O2) )M <2.5 pm Emission Rate, lb/MMscf fuel gas 22 of 199 HF Sinclair Woods Crcss Refining LLC West Boutiful, UT Lab Data Boiler No. l0 Aug6t 22 & 23,2023 Run I Run 2 Run 3 lontainer No. I Mass - PllI >10 um iample No. ileight of Particulate Matter, mg (mr) y'olume of Acetone, mL (V.) {et Weight of Acetone Blank (Container No. 6), mg (m") y'olume of Acetone Blank, mL (V") ilt./Vol. of Acetone Blank, mg/ml (c,) {et Weight of PM Due to Acetone, mg (W") .let Weight of Particulate Matter (Blank Corrected), mg 140-33466-t 0.575 87.4 l.l9 239.7 0.0063 0.549 0.026 140-33466-6 0.26s 7t,o 1.19 239.7 0.0063 0.446 0.0000 140.33466-l I 0.530 96.9 1.19 239.7 0.0063 0.609 0.0000 Container No. 2 Mass - PM <10 um and >2.5 um Sample No. Weight of Particulate Matter, mg (mz) Volume of Acetone, mL (V",) Net Weight of Acetone Blank (Container No. 6), mg (m") Volume of Acetone Blank, mL (V") Wt.iVol. of Acetone Blank, mg/ml (c") Net Weight of PM Due to Acetone, mg (W") Net Weight of Particulate Matter (Blank Corrected), mg 14u33466-2 0.440 55.8 l.l9 239.7 0.0063 0.3s1 0.089 140-33466-7 0.445 86.8 l.l9 239.7 0.0063 0.545 0.0000 140-33466-12 0.0400 32.5 l.l9 239.7 0.0063 0,204 0.0000 Container No.3 Mass - PM <2.5 !m Sample No. Weight of Particulate Matter, mg (ml) Volume of DI Water, mL (V,,,) Net Weight of DI Water Blank (Container No. 7), mg (m,,) Volume of DI Water Blank, mL (V,,) Wt./Vol. of DI Water Blank, mg/ml (c,,) Net Weight of PM Due to DI Water, mg (W,,) Net Weight of Particulate Matter (Blank Correcled), mg 140-33466-3 l.8l 193.4 1.45 276.7 0.0052 1.013 0.797 140-33466-8 1.13 185.9 l.4s 276,7 0.00s2 0.971 0.156 14G33466-13 1.56 176.1 t.4s 276.7 0.0052 0.923 0.637 Container No.4 Mass - PM <2.5 um Sample No. Weight of Particulate Matter, mg (mr) VolumeofAcetone, mL (V*) Net Weight of Acetone Blank (Container No. 6), mg (m,) Volume of Acetone Blank, mL (V") Wt./Vol. of Acetone Blank, mg/ml (c") Net Weight of PM Due to Acetone, mg (W") Net Weight of Particulate Matter (Blank Corrected). ms 14u33466.4 2.48 225.3 l.l9 239.7 0.0063 0.790 1.69 140-33466-9 1.39 191.1 l.l9 239.7 0.0063 0.790 0.600 140-33466-14 1.24 201.2 1.19 239.7 0.0063 0.790 0.45 lontainer No.5 Mass - PM <2.5 um iample No. ileight of Particulate Mafter, mg (ms) 14G.33466-5 0.9r 0 140.33466-10 1.07 14G.33466-ls 1.07 Note l: For results reported with negative results, 0.0000 was used for the calculations Note 2: Regent Blanks from 5/16/23 23 of 199 r:Alibrrce IL( iN LAL (,FOU;' Volumetric Flow Rate Data Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source Boiler No. l0 Project No. AST-2023-1660 Parameter PM (CTM-039) Run Number Runl Run2 Run3 Average Date Start Time Stop Time Run Time, min 8t22/23 l0:56 l5:08 240.0 8t22t23 l6:47 2l:13 239.8 8123123 l0:22 l4:44 240.0 239.9 CALCULATED DATA Pitot Tube Coefficient Barometric Pressure, in. Hg Static Pressure, in. WC Stack Pressure, in. Hg Stack Cross-sectional Area, ft2 Temperature, oF Temperature, oR Moisture Fraction CO2 Concentration,%o 02 Concentration, 7o Molecular Weight, lb/lb-mole (dry) Molecular Weight, lb/lb-mole (wet) Velocity. fVsec (cp) (Pb) (Pe) (Ps) (As) (Ts) (Ts) (BWS) (Coz) (oz) (Md) (Ms) (vs) 0.76r 25.87 -0.r I 25.86 1 3.10 332.7 792.7 0.140 9.17 4.43 29.64 27.46 35.8 0.761 25.79 -0.10 25.79 I 3.10 331.6 791.6 0.150 8.75 4.92 29.60 27.89 34.2 0.761 25.8t -0. l5 25.80 13. l0 333.4 793.4 0.147 8.90 4.45 29.60 27.93 30.5 0.761 25.82 -0.12 25.82 13. l0 332.6 792.6 0.146 8.94 4.60 29.61 27.76 33.5 VOLUMETRIC FLOW RATE A.t Stack Conditions, acfm 4.t Standard Conditions, dscfm 28,129 13,933 (Qa) (Qs) 26,848 l3,l 19 24,010 I 1,753 26,329 12,935 24 of 199 AlffirceTtfitiNtc&L otr4{}ils Cyclonic FIow Check Location HF Sinclair Woods Cross Refinins. LLC - West Bountiful. UT Source Boiler No. l0 Project No. ,4.5T-2023-1660 Date 8122/23 Sample Point Angle (AP=0) I 2 3 4 5 6 7 8 9 l0 1l t2 l3 t4 l5 r6 Averaqe 0 5 5 5 l0 l0 l0 5 5 5 5 l0 l0 l5 l0 5 7.2 25 of 199 I!yAIiarEe TI'C,INI.CAL CHOU ] Method 4Data Location HF Sinclair Woods Cross Refinins. LLC - West Bountiful. UT Source Boiler No. l0 Project No. AST-2023-1660 Parameter(s) Moisture Console Units Run No. Date ;tatus itart Time 0nd Time Run Time, min (0) Vleter II) 1 8t22/23 VALID 9:45 l0:30 60 MB-704 Vleter Correction Factor (Y) )rifice Calibration Value (AH @) VIax Vacuum, in, Hg Post Lak Chmk. ft3lmin (at max vrc.) 0.992 1.860 5 001 (4 5 Meter Volume, ft3 0 5 l0 l5 20 25 30 35 40 45 Total Meter Volume. ft3 (Vm) 4s4.656 457.720 460.785 463.780 466.885 470.015 473.025 476.025 479.045 482 395 27.739 Temperature, oF 0 5 t0 15 20 25 30 35 40 45 AverageTemperature,oF (Tm) AverageTemperature,oR (Tm) Minimum Temperature, oF Maximum TemDerature. oF Meter 87 8l 72 72 70 70 70 7l 70 70 533 70 87 Probe Filter Vacuum 4 5 5 5 5 5 5 5 5 5 5 4 5 Imp. Exit 65 66 65 65 63 63 62 63 63 63 64 62 66 Barometric Pressure, in. Hg (Pb) Meter Orifice Pressure, in. WC (AH) Meter Pressurg in. Hg (Pm) Standard Meter Volume. ft3 (Vmstd) 2s.90 0 600 25.94 23.623 Analysis Type Impinger I, Pre/Post Test, g Impinger 2, Pre/Post Test, g Impinger 3, Pre/Post Test, g Impinger 4, Pre/Post Test, g Volume Water Collected, mL (VIc) Standard Water Volumg ftr (Vwstd) Moisture Fraction Measured (BWS) Gas Molecular \ileight, lbflb-mole (dry) (Md) DGM Calibration Check Value (Yor) Gravimetric H20 H20 Empty Silica 482.1 407.4 249.1 510.4 532.9 426.8 2s4.1 517.5 50.8 t9.4 5.0 7.1 82.3 3.881 0 14l 29.64 0.8 26 of 199 1f 1 ! 9 t ! n 9 9 9 n 1 a ! 1 1 a a 1 1 1 r 1 1 9 n n ! 9 9 9 9 ! ! 1' a 9 9 ! ! ! 1 9 1 t ! ! , 4 ! 9 1 1 9 9 ! n a 9 !1 I f a E; ; - - - - a d - - o o - q c ? r ? q ? ? i a i t q 9 q 9 r i i 9 9 < * i € a q 9 ! t ! 9 9 \ 9 1 9 1 ! 9 ! 9 1 i C e 9 9 i P i 9 - -! ! ! ! ! 9 : t 9 9 ! ! : : 9 9 f !! ! : f l= : f == = = r J l = = : f l: : f lf : = f : f == : 1 = : = = f =: = : = f :: = .3 € a ? t e 1 ? a ? _ ? _ a q ? a n o _ o -= - - - F - - d - o- 4 3 + n+ { . ! - i a i . r 9 i . + a9 € € c q 9 q o € € o o D o a o o o o o € q 9 q 6 q q q o q € o q 9 9 c o q o eq q q . 9 n 9 : a q 'a r = t 5 - 6 - n -. 1 o - r - -. - . a - ? | - - 9 n + @ + q 6 * n 6 1 n 5 r e a + r n - ? q d; ? = i = ; r - a = ! = ! Q I a = = i d a - a F t - . i a i ! a t i t r o= r r i r = ? ;; 6 i 6 + 6 r + 6 6 + ; 6 h 40 - 9 9 € € a € . n9 9 t ! ! ' 1 9t ! ! 9 ! t 9 9 9 9 9 1 9 9 1 9 1 1 1 9 1 n 9 1 1 1 1 1 a 1 1 1 1 1 1 1 1 1 + 1 1 1 1 1 1 1 1 4 1 1 1 1 1 4 4 1 4 1 1 3- d 6 e iS j i s a j i d i d i j i9 i " 1 ! i ? n t i c l t i q n ! i e n 9 i Q 1 ! i ? 6e a € r 5 d; ; ; d 6 - = d d d 56 : 5 6 5 oa - * - ' l! ! 9 9 9 9 9 4 ! 9 n 9 n ! 9 9 9 ! ! a ! a 9 t 1 t t ! ! n 1 ! 9 ! 9 9 ! t ! ! 1 ! ! , a ' a ' a a 1 n 1 1 1 1 9 ! 6 n l t M ! 1 a l -6 + 6 6 r * - 5 t O* F e $ ?9 - . 1 ! n a c 1 n - ? n 9 a - a - a - 9 q € ! 1 q e 1 a - . 9 i 1 9 1 ? ! 1 : l n ! - 9 4 9 - n t q -r r € r N - 5 F 3a 3 3 ; E ; 8 = 3 ; 5 q q s E q E ! = ! E ! 3 X E i 3 3 q ! : s A & = E q E id d ; - - d ; d d d 9 9 9 = = = = = : a l 3 ! ! : : : : : 1 9 3 9 ! 9 9 9 9 !OA Yu :E .? .z .: Ho;'a8.{ :' 6h a € N - o a? n n e a = * - a n a 9 n n n 1 e q 9 9 ? 9 - l Q 9 \ - a Q i - : 9 9 r c 9 + q a i ? - F a - ? - 1 : 9 i ? 1 9 - 1 : a t 9 ! q q q -6 d F - - - € € N =€ F + 6 -. - j . : . ^ - : . - d a6 A F 5 t-;+,E-! s o cg i. --E 27 of 19 9 la 11 1 1 9 q 1 1 n a 9 1 a 1 1 n 19 1 9 9 ! 9 a t 1 a 1 n 1 1 t 1 n a 1 1 1 -a n - 5 q1 : a : n n n a a ? i i i i a n a n - a q ? - r - l a a a n a c 9 l 9 n i t i l a i l a q n l 9 l € ? 3 a t ? i a 1 : 3- . 5 6 GF * S 3 = : K : ; e * 8 X S 8 e 5 = i = 3 + 3 3 R ; $ 5 8= r e P l n : ; 3 8 E 3 : R = F 9 ; G F F S 3 5 = i 4 i + q 6d d i d d d d d d 6 a d = = = = = = = = a a 3 l ! ! = : : 1 = = 9 9 na n ! 9 1 4 1 9 : 1 n 1 1 n 1 1 1 1 1 1 1 aa a a a a l a a a a n a a a n a n a n a a a a q a a n i n n n a n n n n n n n i n n n n t a l n ! a a n n ! n n n n t !! ! ! 1 ! t l t n 1 1 : 1 1 n a a n 1 1 1 9 1 n ! a ! 9 ! 9 a f 1a 1 1 t 1 n n 1 1 1 n l 1 I . a ' 1 ! 4 1 1 1 a 1 1 1 n -, a 6 n - o3 h - 9 - € - 0 - 6- - + 6 il i l d ; ; d - - a a 6 d 5 d o 5 I I r r i n; i ;' ; F : ; ; ; i i n q n h. b b. b 6 F rr r & & d. ; ; d d 5 5 3 5 : - - - : : i : : -. -. - - . - : : I n n n n n n I n n I n I n I n I n I I n f l n I n n I n i n n I i I i I I I n n n n a i n i a a B. E 3. e () i.;p.?.2z +; + ; ; + ; + + ; - ; + t! 9 1 ! ! 9 9 9 ! 1 1 io c o o i 5 i i d i d ?r 1 6 - 6 1 - - r =: ! 6 i 6 Q t r n -n : a n l l l n l n n :l + - . , e 6 6 6 0 0 6 6 d 3l - - - - aa i i i i r ' j i i r : ad d d d d d d d d d d :l q l i ! 1 n - 9 9 ? dd d 5 r d e + 6 r - 5 'a P i r a l ? - q n n a -n 9 I : n 9 e - n 9 ? 28 of 19 9 41 1 9 1 1 1 ! a ! 1 4 1 1 ln n n a n n n n n n a l l 5i 5 o 5 . 5 5 5 i i 5 5 i 5 5 5 5 i ji 5 5 5 . 3 5 5 i o i 5 5 3 5 . i 5 i i = = j i . i i 5 o 5 5 a i 5 q 1 n 1 1 n i a a e I n 9 a 1 a i ! 9 ! 1 I 9 a 1 n n n n I I n : I n 9 I n 1, 4 1 1 1 a ' a ' a a a ? n n q n n ++ = f f r r : f f =f = : = = = l : = f :: = aa 1 1 1 1 1 1 4 4 a 1 a 1 1 1 1 1 1 + 1 + 1 1 1 - 1 1 1 1 1 1 4 1 a 1 1 4 1 1 1 1 1 1 4 1 1 1 1 1 1 1 4 1 ? € 5 6 | 9 5 - N, n - -r r o 1? - la d i d - d- a -a r t h - n - q lr 6 . € ? o r r ? ? a r * o ? e o * r 6 = Q & ? a d I o r F r ! : ? t Q ', 1 = l: 5 n F 6 li - l - q a n a n q a a t l n - Q l l n n f n- - n 1 n 1 - a a a a n n q n n l n a a n - a 1 1 1 1 1 1 1 d- - r o r- r l N 1a 1 f n n a a . L l a ! 1 ! n r r ' a 1 ! ! 1 n 1 1 1 1 I 4 1 1 4 1 1 1 1 ! ! ! l l l 1 9 n 1 ! l 1 n l 1 1 nl n a ! 9 t i t q q - 1 n a 1 9 9 t i I a q - l n ! 1 9 9 9 q ? q Q - - 1 1 1 ! 9 9 i e q ? - : n n 1 ! 9 t: i i . l : i : : 3 I 3 ! ! I l : : f : : f 3* 9i n q 9 : { 1 - e - { 9 n 1 q i 9 r . i l :n l i n 9 q q a n - i ? q 1 i ? i 1 n 9 ? 1 9 n n ? ! 1 i : - dc 3 c s € - i € r - N N e , t? 9 1 n 9 - 9 1 9 n - - n ? a n n n Q 9 n - 9 ! 9 1 n - n q t 1 a { q - a 1 ? a i 9 ? 1 1 q 1 ? i - . 1 1 ! !() I t. 5 8. 9 F!=E QqI,1 l. r r n n n 9 n r r r n a l t l n a a a : t l a a a l a a a a a a a a a a a a l a : : : : 1 4 : a : : 1 9 9 11 n n a 1 1 1 1 1 9 n 9 1 1 1 a 1 1! n 1 \ n 9 9 9 9 1 1 ?s - * c F r F = 6 a l = r s x ?n ^ ? 3 r : - - - n 3 a ? - n - i ? €d h , h d ; d 6 ; o r d r ' ; r h d ;l=l * o - c :t a i a ! 1 1 1 9 1 4 ! 6 6 i + + h 6 ,t ,* r d r - N o 5 , nq Q l - i { a l n a q l t i q l ! €q ? . n 1 ! 9 r q Q . t 1 :f a f : l : 9 . n 4 9 - n a I : : nt n r n a n n n n n n a n n n a a 29 of 19 9 al a a n n a n n l n n n n i n a s 33 : 3 € 3 3 € 9 3 3 € 3 S 3 € € 8 € € 3 € € € 3 € 3 € 8 8 3 3 3 € € 3 8 € 8 3 3 3 3 83 3 8 d5 e , 9 , .d d c F ! 9 ^ nq n a - n 1 1 - n n a a n l - t l l n n l l - q a q n l : : : - ? - n n - - - - a - -- = ?- a= - ^ - + o o e d c - ^ - . ; 6 e s t a j d ; - 6 d- n ; e F - d i j -: > o = = i i i o j i o o o i- N d d n d d ^ d -- e - , r . - . r : - -_ 3 ; 8 ; 3 $ 5 q q q 5 : f i ! 3 a ni q n ! t q t 9 i ? t 9 i ? n 9 i q n ! i q n a e ? a ! * ? a 6€ d d d d d 6 = = ? = = = = = 1 S Qt - a 1 ! i n 9 6 1 a - l a - a n n l i - - q n ? n l i n 1 1 1 n - r ? - - - - - - i - l : - -- - - - ?r o F * 4 9 - r o . . - a6 6 + ' ^ 6 6 r 6 , ++ - a - F- 9 - A a - a t - + r _ 91 n 9 - e € - a 9 n a n 1 n : ! { i 1 i 9 - n ! ! n n n i 9 9 e 1 1 l - a - 1 ? n ? r - h - a dd d d d -- ; 6 i d ; h S d ; 6 5 d - Fi i t s - - - - - 6 o r ?a a ? = = = = n ! ! a n ! n ! 1 = a = 9 9 ! ! 9 9p P I t i l X * I I JJ l r : ji r i : r - n i i i d i ^ n & & N d d d i n n n n i d n A i a N d d i i ^ d i i l n ^ dd ; € r ? ? l a aF ? : F d - ; F s , 5 - o l = t F - a - t l . r n 5: = a - 5= 5 t o ^^ d i d n d ^ d d N ^ i n d ^ ^ n d n n ^ ^ ^ d d d N d ^ n N ^ d d ^ n A i :. 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E p . e € q q E s E s -5 3 iaUA !Ete :HII!: 36 of 19 9 taaa aq q n E q q E q q 6 q 4 q a q c s f i eE q q e q E q B s E E Q s q e q q a q q * r 5 q q ? q q q 3 q ; 1 a q E 6 q $ q i E q i E i B E E i E { e { i1 9 + 1 9 1 a 9 1 ! 9 ! 9 3 a6 a a n a a n r i n t n n n e a n c a q a a t a a n a n n l - n a a a n a a i a n n n n n n i n n ! ! ! a a ! a ! ! a ! ! ! ! n l n n n l l n n n es G s B g $ g E E E E G € g C G € G E G E C e E G G G c B c B S E G G g E E € E E E € € 8 E U E g € € E € € S € € E € C B E € E E g g g E E g E g - i 6t - 6o 1 36 o C, - = +- r 6 a I r N - o 11 o o o ! 9. ? . h - -r 9 q9 - o - - n€ + - 1 6 6 r r 3 3 - e - ? =: 5 = } 6 b b ; 5 5 5 = i 5 5 } d 6 - 5 = 6 = d ' ' ' n = = d . ' d 5 6 ' d ' = = 5 a d = : : . . . ' = = : -- N 6 9 C - r a F 99 q 1 1 - n - 9 9 9 9 ! - 9 . 9 i - 9 . 9 l 1 9 9 ! 9 1 9 ! i t 9 9 a ! i r q 9 e F t € to ^ a r d r ^ 6n L 6 G : e - F 6 r 6 t 6 : r 6 5 € 6 + d 6 6 N - a * c 6 - o d - d -' ; ; d ; c g - . o a . ; € J o 6 G G o ; c d o o o G . . + 6 o r € 6 € o 5 9 . ! 9 9 9 ! ! ! 9 € o 6 h h r : h -n 6 - - ^5 p * ; 3 * a 5 5 3 5 a 5 3 3 ! 3 = F r = 1 = 5 = = r e E 3 3 5 3 3 5 8 3 5 3 3 8 8 8 s 5 3 5 3 : 1 R 8 = i = r 3 = nF t 9 t t r 2 ' - 1r e i 9 i a . * 1 1 q ! a < a =n ! t r ! ! i !* a { ! a 9 ! a ? == i i l a i , =r i n o -i i i s a r r i o6 F r t = I l i : X A = = 9A !E .? .e - .: .: e (. )2u .- n . i i a - - t a : q a - t 9 9 i s a i a a - 9 - 4 9 - : q r - a n - - - - . 9 . . 9 - . ? 1 9 a P l r i n 9 e 1 ! € 1 - - - ? ? q . ! 9 ! i l s6 6 6 6 + + - + 6 6 6 4 o r 6 6 6 6 = h € 6 6 + 6 O 6 6 n 6 6 F € 6 dd d d d dd - d d d d d N - dN A d d qi q E F t F ! 1 E R 3 i a q q s 4 R 3 1 E f i =! l ! 9 = g A E a e p 3 B Y E 3 6 4 S 6 5 3 q 3 a a - S S E E A A s A S q a i C a q E i E E A E i 4 aS a e e : 3 : : : : 3 : R 8 3 3 3 3 3 3 = A A S S S A S S R R A a R R T S R S S R R A S R S S R A F R A A A A S S S R R S e R A a R R R R A R R R -3 S ; 3 c € r S ; 3 ; 8 5 8 = s S E S 5 9 = 3 f r gS F e g 8 3 3 8 = e N 5 S 5 ! * s a E g F A S ; 8 5 8 = 9 - 5 S S ER 3 ; e X C E 8 r s 8 a e e 3 3 s 5 5 a 3 5 S ! 3 5 8 3 3 : = a e l ! e : = l R x t F F s F K R s E S g A s S E E A ? ; q C { i X i i E E A E A E nF F F t s t s t s t s r F r F r 6 r r F F - t s n - - - - - - - - - dq ; i 6 € i a 5 a 5 : d n ; i E € i ! - 8 = : t q i E q E q s 5 S = : ! q + q f r Er { s 5 3 ! F X ! 6 q E E s 3 i - : F S i q e E F S 6 ! i = 3 8 AS A A S E A A A A S E S E S S S S E E S 6 G G G G G G 6 G G G G S S S S G G G G G G G G G G G G S € € € S E B B E G S € € S 3 S $ G B t s € g g 1 3 € =x 6 E - F q F 3 \ q e e E q q ! i i i A i i q p i l F . s i I I I i f . : 3 ! 3 = i I E = I f i 3 : 3 * ? 1 9 f : f g E - : : * = F - E P : ! g ! : f E - E d E d d E - E E E d E E E E d d E E E E E E E E E E d E - E E E d E d d d d d E d d d d 4 & A A I 4 d E I A d T A A E d L d d d d E :3 i E = n T E i f r ia a i a g i i a 9 3 E 3 5 3 t 3 E n s 6 5 6 E 6 E n H f f 5f i E q 5 f i Ef i E3 r q E F E q E 3 f r q 3 n a f i 3X A S 3 { i q i 3 ? 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A a 1 - q q q r 6 @ N r d 6 t e 9 9 n 9 - ?d - ? 6 5: = 5 . 5 t = : . r5 : a == 5 ad r ? . r . : = : = r = = = 5 r r r 5 t t = 5 = = = = = : d 6 = n 6- C - h -- 5 + r - r 3 C a a = 5 d - 5 n1 1 1 1 a a a A n l A 1 1 1 1 1 a a 1 1 1 A 1 A 1 1 1 1 1 n a 1 1 1 a a 1 1 1 1 a 1 1 i a a a a a + 4 1 4 1 1 - 1 - - a a 1 n n - 1 - i a :3 5 = : E = 3 = : = 3 9 3 : : F r : e ! r = f r ! r ! ! a : ! 5 3 9 9 5 5 3 = = = = 3 3 t r 3 = r . ? ? . a ? r , € , o F - . € e i t r 3 e a = .= ; . ; 5 5 1 : 5 ; 5 s 5 ! = ; = ; ; ; = ; ; : ; ; ; ; = - ; ; 3 ; ; ; ; = ; ; ; ; ; ; ; 1 ; ; 1 1 ; = 1 : = : 1 a 1 a 1 a : 1 1 : 1 = - 1 1 ; SE E E 6 E 5 F s E s r q r E E q r E n n e 3 a n e € A q - ! i 3 - s ; 3 ; E i ! Q : q s 4 . E I q ! ? i i 4 i l q ! : i q i = E e { = i 9 F d a d r a d d d 4 4 4 a d a d i l a & a d d L i l o a d d d d d d L d a e d d d d L d d d d d ++ + + r r+ + r r + * * + + { i l n n il i n n i i N ^ d n i d d ^ ^ { i l d n n i ^ n d N ^ N { i ^ ^ n n d n n n n n d n n n d d d d n n n d a d d e n na l n a n n - r q n t 1 1 n a t 1 a 1 n n 9 9 a t 1 t 9 9 ! 1 1 1 1 1 6 ! 9 n t 9 t 9 a i F - ? i i i 9 { 9 r e a q n q 9 q 3 6 d G - & - o 6 6 6 6 6 h h h 6 6 6 -i 6 6 6 6 6 h 6 d; @ d h c* e 6 , 66 o d J € d o r c o i d ! 9 d€ € ; r . s€ € +; d ; od d h d 6 jd d o o 6 e o ; r 6- o o o - ; r6 a + 6 - + + * + + r i , r + - + + h + i + 6 h h h a r 6 + + 6 6 6 6 6 6 6 6 6 Ad N d d ?9 ? 9 ! a - 9 a r 9 q 9 e { nd 6 h 6 66 r 6 6 6 S h o h s € o 6 F G O r F r FF 6 r n F F - - - - 6 5 i F d- A d d d - d d d N N - d d d d - d d ^ d d d d o€ o d d r- - r r r r € t s - -6 - d - d a - n n - n - - ^ & & - - d -- - - 6 tr d - f , a a 1 a a 9 ? 9 - c o- qN F -6 ,h 5 r r A - 5 3 ; oa t. : .a .? EE (J f,{f "9= >€ da € i 6 or N - 6 +6 € r - € 6 o i N - 6 + 6 G t s € 6 6 3 - d e r i €s E s € 3 € € € € 3 S 3 3 3 8 E E G G t G 5 r 5 5 E r S U Z Z ? € ? 8 3 3 € ? g S S C S g ? 3 ? S S g R F F F R F F F S e e i = F F = F F - = 38 of 19 9 na n a n n a n n t t n n n t ! n t l n a n a n e a n a n a n a a a n q a a a a i i a n n e n q a q a a a n a a n l r i a a n a nn n l t l n l n l t l i l t n q t n n i - t l 1 1 l l n n n : n t n 1 - l n l n n l n n t n n l n t n l n - : n t : - l f ln 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 € 9 9 9 9 0 9 9 a 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 !c e a * F- - n h a9 9 ! 1 1 9 ! n 9 ! 9 . 1 9 9 9 9 9 1 9 ! ! 9 M 1 1 1 n 1 1 n 1 1 A a : 1 A 1 1 1 1 1 1 a 1 n a 1 1 1 1 a 1 r n n n n 1 n t :* ! 9 : ? ! = l : * F -, jd e + 6 . r tr o -d d + d 6 a 6 o - d - -6 6F d i 5 jd d + dF i r 5 - d d r == l f :l l * i 9 : It e n ! i Q 1 ! i Q n ! t q t ! i ? ! l t q l n a q 1 ! e ? t t * !Eq .8 .? 6E :HQ -, 1 P , - r - . - o - 9 f rr = ? 5 r 6 = , , - ? l ? 6d Q G ; an n a 1 a n n n n 1 a 1 a 1 1 1 1 1 a 1 : 1 a a 1 1 1 1 4 4 1 a 1 1 1 1 1 1 1 a 1 1 1 4 4 1 1 ! 9 4 1 1 1 1 1 1 1 1 n 1 1 1 i 9 o= c i i r- n = . n- - l - - L4 [ 4 A A& d & G e d r t C 4 r A r d d d e 4 4 d 4 d r d 4 L A d d id 5 : : : : n i l i l i ; ; n ; + ; + + 6 6 6 6 6 € i i i s r i &* & d a a d6 o o d o - : - : i a i d ; ; ; e; + ; d i l d & n i l i l i l n i l i l i l n n d i l d i l d d n d d d n A ^ n ^ d d n d d d a a a n -. ; 6 d. ; ; ; ; ; ; -: ; ; ; ; ' -, ; ; n :?=a an a n n a a n J? = 6 F ; - a r? ? c 1 n q c 1q ! 9 t a a 1 dd d d d d d i 38 8 3 t i = \ !r ! ! ! ! ! ! -- i : - - - : 4n 9 n 9 t 9 a .a - - - -. ^ ^ - 5l a - 6 - i 5 j j 51 4 ^ N N ^ N N N sl - - - * - - - - !1 6 € 6 r - - r 3 =l r h € r - a 3 N j: i i : d d d -n 9 e . r q r A& 4 [ A A A A 56 6 i l i l f 6 & 39 o f l 9 9 ta ! ooE. i p. 2 .:E9 I q9 :,Bi!! 'e ;; ; + + t + + { + + + ; + dd d d d d 5 i 5 d d 5 i 5 5 ?i n 9 9 a 9 q i r r i 9 r Ia q 9 i n ! - q ? n q q l €6 C s * h € 6 h di d d d d d d d n n n n a 9e - a 9 P - n 9 a - n 9 Q Q t9 i 9 i 9 i F 9 9 a 9 9 i dd d i i d d d d i n i d d 6; d d 6 J G d d d 6 d ; 6 dd d d d d d d i d d d d d 4A A & A A A d * & 4 A r r n9 n a 9 Q n a 9 9 t ! ! - ;; ; ; ; ; ; ; ; ; ; ; ; ; 40 o f l 9 9 . !B 6F - a o ! r . 9 t - a d r 6 - =+ o ! 5 X + G : : - - l t 1 - 1 9 T " n ! i q : n t i q - l 9 q ? 1 1 9 1 - n 9 ! ? n 1 9 1 : n t i a - n t i a - n 9 q ? t t i a j l _d - * G -r a r - +d 6 F $ c j 66 G € @ 6 @ O a 6 F F F r r F d r - - 33 3 3 3 3 3 3 3 3 3 3 8 3 E 8 8 8 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 8 3 3 3 8 3 3 3 3 8 3 3 3 3 8 3 3 3 3 3 8 8 3 3 8 3 8 3 3 3 3 3 3 3 n - - - dd t @, - i r t - d - dd n , @ @ d d n , @ € - d - - - dd d d - - r d ; ; ; ; aa a a a ; ; ; ; ; ; ; ; ; ; ; ; x : x = x = = = = 3 t = t t 5 t = 5 = = t 3 E 3 8 3 3 3 3 3 3 3 3 3 3 3 =- E E 8 = 3 3 3 3 8 3 3 3 3 3 3 E 3 E 3 3 r{ q e t l a * * 11 4 ! t 9 9 9 9 9 9 9 9 i 9 i t t i ! a q q 1 q ? q ? - : t l n n n n t l n a n n n t t : - q q ? q " ? ? ? ? ? ? - - n n n n 1 1 9 ?e n ? c a 9 q q n e n ! q ? T 1 9 q a q a : a F aq a a q 5 0 n a . d r i d r ' d h h 6 ; 6 6 ; ; 6 , ^ 6 h i^ d i^ d d d d ; r ' ; ; d ; d d d 6 6 6 6 6 6 d 6 c, 6 d - !. : 1 - " a - i ! - t n ? ! q n q : - a n n q q q q a q n 9 q i 9 a l i - - ! - q e a 1 9 - n t n 9 - q a 9 ? n q - i a 1 q q ! c n i E€ E F F F F E R G g R € S E € 3 3 ; 3 f i F F € g R S = F S R S € g E S ; 3 A S € G € € G . ? € 3 F E P F F 5 E € A G 3 9 3 3 3 3 G F € aa a e e a e e a e e e * a 3 e a a a a e a a a a a e e a a a a a a e a a e a a a e e a e e a a a a a a a a a a e e a a e a e a a e e aa n l n 9 " 1 1 ? 1 Q 9 9 ! a n c 9 n n q t n i l n q 9 - \ - 9 1 a n a - 9 n i e a= ! -- 3 6 a 6 a 3 a C r5 - a - - 5 - 6 5 d^ d A d d d n d d d d 5; d h d ; ; a 6 h 66 6 d d , ^ 6 d d d d6 6 h h d h 66 6 d c ' 6 r . 6 6 d v 66 6 r . 6 h d d 6 6 6 6 d h 3(J A i. s ?. e FEEE EQzpIiz=> 5^ n a ^ Aa g a a e a a a a a € d d d - e d , ed - -, - , @ - a - r- - d i t . r r - - - - € - * d d d * d - o @ @ € *, ts l - - - - . ie - - - O€ c r 6 + 6 r + 6 6 O F o F € n a F O h O 6 6 G 6F F o - 6 4 !n n l l i n n n n n l i n n n n l n l n l l i n n n n n n n n n n e n n q t n l t n a l l l l l n t l t t t n n a a n r n n q n n - ! ? 9 ? a f - . ! r Q a t < 9 € 3c r - € 6 i. . . 5 5 5 - 3 c a i 3 i i i 5 . 3 -. i i d = d i d o i i . . d 5 5 i 3 3 3 i 3 i d 3 3 - d i i 5 5 c i i d o d 5 o o c 9E t E t - t t F 9 i a j i d o d d 3 3 d c i - o d 3 c 5 5 5 3 3 i i i 3 o o - . = i. i i i i d i d o o i i i - 3 3 d i 5 ?! a 9 = 9 - 9 = 9 - € = r q d6 . o d _d + h i N + 6 _ A r 6 _ a r 6 _ i + 6 r d 9t l t t 9 ! < ! ? a a l a i Q c - - - c5 3 5 C 4l of 19 9 t. jg ii = : : : g E = 3 3 : a = : 9 = r B i t r K F F * g ; c : F p! : 9 ; + + + 9 5 ? + 3 ; f i ;3 , : ; a B G s G S S G B g 3= 3 3 3 3 3 8 3 3 3 3 E 3 8 8 3 3 3 E 8 3 8 3 3 3 t 8 E t 8 3 3 3 3 3 8 8 8 3 8 8 3 8 3 3 33 8 3 3 3 3 3 3 3 E - 3 3 a * I l ra a = = = 4a a= a a ! = = { 1 a = a = = = = ! ! = ! = ! ! a = = = = = = a = = = = = = i = a i = = a 2 =a I aa q q - - 1 1 r l t 9 i \ 4 1 ? - n aa - - a ? - ! e l a n ? : ? 9 1 i i 9 ? ! { n c * ? e q n q n t n f t- - € c a l l l ! 1 1 i 9 i a i - 1 ? q 1 n id d d r d d d : 6 ; r d O € U+ i l + 6 U O G F E n t s t s F F t s F o r e € h G h 6 nr 9 n ? i * ? 9 9 n r e 9 q " i * 1 1 ? l q r q 9 9 - n 9 9i t l n 9 n 9 n 1 9 : a r 9 - ? - 1 a 1 1 ? a dn n d n n n n n n i x r x r R r x R i x x K r x x n F r r x n x = x x x E x K x n r r r r E r r r x r = r * r * x i i E 4 ! r 4 F E 3 E E 3 z 66 d d A i a n + 5 - : - - - . = 5 = - = - - - 3 = d d - a r r r d = ; - - n a n - n n e q a a a - a i n a - - - d 1 -. a a n a - I 1 n I n a ! 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Q - l i i l i n a a a l 9 9 i C q - - d r .r i 6 t 5 5 t d 6 66 n 5 t 99 n ! - A - a A n q t t 9 - 9 n 1 n 9 q ! i n l n a 9 a t q ! 9 9 ? p 1 - a 9 n q n l p t * t q i 9 n q i a p t n d- - - - d a N _ = 5 5 5 _ - :- d d N ^ d - c j - 3 - i r r i a i i y r l ? ? i i i ? ? ? ? i " ; i ? i i ; i i ? i i i ? i ? ? i ? ? i i i i i ? ? i i i i i i i q i i ? -- : 9 - 1 4 1 1 1 1 1 1 1 1 4 1 1 1 4 1 1 1 1 a 1 1 1 1 1 1 1 1 a 1 1 1 1 1 1 a a 1 1 1 A 1 1 1 1 a 1 1 1 ! 1 1 4 !- & i ! ai - 6 6 dd d d d s R $ g * r .3 ; I r; e .- ; B € € 3 € $ F R ; - r I F S F R F ; A ! ? S ; 5 A ; 3 g 5 5 E i 3 3 i S I r * S r $ 5 I= = E I E = E I E E E E E = = E = ; E ; = E E E E E E E E E E E E E E E E E E E E E = = = E = = = E = E ; 6O h - o ao c o o :J II n: NA aQAE. E .a .= enEE (JIE} 48 of 19 9 is :a a 9 i { ? - 83 3 8 8 8 3 8 33 3 8 8 8 3 : i fq e r e { e r 9! ! 1 n n - - il n l n n n n ? *i i 9 ! : n a _a .8 .z .: a (Je al t n - : : - lT 9 a 9 9 ! C Pp a i t r i ! : 55 a d ' 5 i 5 ;; ; ; + ; + + 1a l a 1 : 1 1 ea o q t r a a a 1P { i 9 ! a 1 n n i 1 - - : - - - - - - c Q a a s a - - d ts F r F n n - r r r F r r t s F F 6 F F t s F t s d r r E -i g F i q q r i S E n T q F & ! 1 n * a i E 8 l f r q3 q ! 5 = E E q € 8 3 5 n E i s F E 3 i q i q c E 3 i f i iq q 5 8 : i E i. i ; d 6r - d id d + 6 6 d J = - e- 'o 5 . . - 3 3 c 4 3 3 - - = r- : - d d d & d d 83 3 3 3 3 3 t 3 3 8 3 3 3 8 8 3 3 3 8 3 8 8 8 3 3 3 3 8 3 t t 8 8 3 8 8 3 3 8 3 3 3 8 3 3 3 3 3 3 3 8 8 8 8 3 8 8 8 8 8 8 8 d n 6 - - i i n 6 i i - i i i i e n - * r d - - - a a e e d - - @ - d d d d - - - @ - 3E 3 3 3 3 3 8 3 3 t 3 8 3 3 3 3 3 3 3 3 8 3 8 8 3 3 3 8 3 3 3 8 3 8 8 8 8 8 8 8 8 8 8 8 3 8 3 3 8 3 3 8 8 3 3 3 3 3 8 S S 3 t n i - d * 6 6 d A d * - *, d, d - - - d d d * d d d - - @ € - - i - e a i n - * n r; n n * n * ; ; ; ; ; ; -; ; ; ; ; ; 3!€ 8 3 3 ! E E E 3 E € * 3 * 3 S S 3 3 3 3 3 3 8 8 8 3 S S 8 8 8 S 3 8 3 3 8 S 8 * 8 E 3 5 5 D E 5 D 5 E E 5 E 5 E 5 5 5 S E E ;; ; 6 6 6 - 6 d 6 h h h h ; d d 6 6 6 d h 6 h d ; d h - 6 6 d ; a d 6 d 6 6 6 ; 6 ; ; ; ; ; ; ; ; ; ; ; ; !! ! a 1 1 r n l n : : - q a n { a ? r 9 9 9 t 1 1 t n t n : - ? ? q q q a p l t 9 ! 9 1 1 n n 1 - q " a q t e i i 9 9 9 9 n 1 Tt s t s d F F F F F F F 6 F F F F F F F F F F F . ; . . . n d c i i i l i5 E i C 5 5 ! = : ; 3 ! ! = 3 3 ! 3 3 3 3 6 8 3 e : ! = 8 s e a 3 3 : 3 8 5 r 5 5 s ! ! 3 8 s 3 r 3 E : ! : 3 5 3 s = s 8 5 ! 3 e6 6 - 6 6 d d - m -- 6 - F dd d A N d d - - - - r K K K r r S R S r r r S r r F F F F F * r R I r * K S S r r r S F r S r r R r r r r S K r F r K 66 - - ; 6N ^ + N 6h 6 a _ F 6 Er 14 4 4 1 1 4 1 1 n 1 1 1 a 1 + t t t + * + * + + + + r r + + + + + + + r i i + r i i - + + + + + + + + + + + + + ; + ; + ; ; ; iE E E E i F E & E i E F 3 ! i i r , E ! { 3 & E E E X * E R s q E x n t * s X l E r i p R X * r ! [ i E E * f t *p i R r X E I x aa R R a e R R R R s R R a e s R R R a s a * R R a R R l a a s a a a a a a a - a a a a h a s a a a A a a a h a i a S a A R a R ^n a 1 1 1 1 a a 1 1 1 n n t ! 9 0 e F d5 d 5 6 6 6 5 5 5 d 5 6 d d 5 5 5 d 5 - 5 - 5 5 - 5 - 5 5 5 6 - a 5 5 a i b N^ n i n ; ; n n A - i A ^ ^ ^ ^ ^ ^ ^ -; r ; ;- e d e F d 6- e e ; -d . 5 . d i = 3 o a d a 5 d i a a 5 5 j j i 5 d i 5 j j e5 o. 5 o -o o do a 6 i d t 6 i d d C 5 . 5 5 5 C i r 5 & n 5 & 6 6 5 5& n d d a S L L d 4 4 r & d d d d d d d d E E d E d E e E E E E d E E d E d E L L a L L E E E E E E - E E E E " l- , ! t ^. r. . n r I qn - 6 3 | n a a aa n a C - e 5 Aa I i + i i a I i i = il + il = il ; il = n ii n n i i ; ; ; + ;; 6 6 6 ' b e €€ F -+ + + + r r r r + i + i * + + + + + + + i i i + + + + + + + + + + - -- : i ! ! ! a - -: -: I iI J : _ _ _ : i J I: j i _ _ _ _ I I ! _ U t _ : _: _ _ ! L t : a _ _ _ _ _ : : : u 49 of 19 9 la -I nis .a .z .: HQa6 *q ac E E { I - l a q G E a S ! E + s F E 3 : ; t a i € 3 r F i 4 G s E 3 ! E q q F ; E ! q y a S E a = r ; 3 Q ! E i S E i q r a s s ! 5 E a 63 3 q 6 6 E S S q € B E e R F S F F S F T S E - $ $ ! E E E A E 5 S X 3 8 5 t e 8 8 3 3 3 8 5 3 ? = : ! f : s r l R i S S r s E i R s ; S FF F r n r - & - - - - - - , -e - - d U d - - - & - - - d =3 ! . 3 . 3 = 3 ? ? i - 3 i i q 3 q 3 3 E t 8 3 3 E E 3 3 E 3 3 3 3 3 3 8 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 E 3 3 3 3 s 3 s 3 8 E 8 E 3 s 3 3 3 3 3 -t - d - d t d d - d d d d - - d d n * - r n d € -e e - - - - - 6 - l- 3 i q ? . 3 . 3 . 8 . 3 . 3 9 q = 3 Q ! i ; i - 3 q i e 3 8 q E & 3 3 8 3 E 3 8 t 3 3 8 3 8 3 3 3 3 3 3 8 3 3 3 3 3 3 3 8 = 3 r 3 3 3 3 3 3 3 s E 3 4 3 d: i 5 d 5 5 - d d N EE E ! S E S E E I r E $ * I = E = = * = * 8 = r * r * c = E E 3 * * r 3 g S * E = 8 S * S * r * a * 3 a a A * $ * a A a s a a a a a a a a c: ; ; ; 6 6 6 - 6 6 hd d d h 66 h 6 d d d d r ; d 6 ; 6 6 6 6 r: ; ; o 6 6 ; o 6 6 ; ; ; ; ; ; ; ; ; - , ; ; ; ; ia i a i i 3 i B a a a s a E a a i s s i a $ $ $ 3 e $ s e 3 e e a e a s a a e e $ a e a a s e a e a a a a s s e a i e e a s e $ e a a a i dd N n A A A A t o i i ^ a d d A d d i A & & & n A ^ - - - N NN N d A A - d N N d _ e _ ; _ e - - : t: 4 -- : ; e d N ^ ^ d N ^d ^ ^ d dd d N d d d N _ _ 19 c r 9 ! i i - 1 n n 1 I 9 " " t : " 9 n a 9 - - ? a ? 9 9 9 i 9 i 9 9 i ! t - ! a t q l n l a a q ? q € { ! i t n 9 1 : q ? ? n ! t 1 - r€ e € 6 6 6 - r r r F F F F F F F F F F r F F r r r r - - - F R F F F F F * X X X i i F F * l f F R F r -? r ? - e q q l n n 9 - : l q 9 t ! n ! 1 ? ? ? : a 4 q q q ? 1 q q i - i e 9 n : ? 1 r c r r i 9 9 i 9 - 9 9 a ! 9 9 a q 1 9 n - - ? ? n .6 6 . . . 5 5 5 6 5 6 5 d 5 5 5 5 n t - 5 i i . 5 a r t 5 t . n 5 t d t t r n n t t i . n. 6 n 3 : = 5 5 i i c 5 3 5 = 3 5 E i E = : ! : 3 3 3 = 3 3 S 8 3 5 e 5 3 = 3 = = ! 5 8 3 5 8 3 3 = 8 = X e 3 3 - 1 35 5 e 1 t 3 8 5 5 8 3 -6 - 6 - d- - - - a3 ; e ; 4 8 e 3 ; ; ; e a a ; 3 s s 8 ; ; ; ; s 3 i ; 8 ; ; s 8 8 ; ; ; ; 3 a e 3 ! i r e e e * 3 3 s s e 4 3 I e a a 8 5 3 3 8 8 3 e 8 5 = 5 = : e = _" f 5 E 5 = = = : = 5 3 E _: t 3 5 8 S ; 3 3 3 3 5 =- 8 8 = 5 ! E 3 = 3 I 3 ; ; = = = 3 3 a E 3 = 3 I = =, 3 I = e 3 5 : = 3 I f 8 ?? ? ? ? ? " i ? ? ? ? ? ? ? ? ? ? ? a ? ? ? ? ? c ? ? ? ? ? ? ? ? ? ? ? ? ? ? + t t i i ? ? ? ? ? i t + i t i i i i i s r + i r - t i i i Ef r E i E ! E q q N i N E A T 4 S E q B ; S F E A S E F T G C F s s F s f r G R T ; F R F ; 3 S ! P F A s F F R R * E G € G A ; T S F ; F R S dN - d A - d - ^ N d n - i l - & ^ N A a - - - - - - d - N d d d d d 6 .c a . 5 a 5 a a a a 5 a a i 5q 5 3 5 5 4 $ S a e 8 ; ; 3 S 8 8 3 3 E 8 6 e * 3 ; 8 3 ; 8 S $ 3 ; 3 S 3 A 3 s 3 3 8 e 3 3 a e 3 S 3 s e ; e s 3 r e 5 3 S 3 X 3 e a e S dd d A A A A d d N dN N A d N A & N d dN d N d N A A A N -r o o 5 o 6 r o , :4 1 ! a l t a 1 1 a a 1 1 1 1 1 1 t 1 1 a n 1 1 1 i 1 1 i l a a 1 a i l a a a i 9 - i * i i ! ! a a - i i - l g a 6 i a e e a i . e i i n n 4 d E d & L d 4 4 4 c d i l a d e d d d E d E E E E d - - E E e E e E E d E . a d d d i l E E E d d d d E E E E E d E E E E iA i 4 + 3 + : + S i i n E E i E F R i S € n f i 8 ^ p ; 8 ^ i f i 5 i E f i 5 l F n t l = n 3 n F 6 5 ! 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" ? ? ? ; ? ? ? ; ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? 9 ? ? ? ? ? tr dYu :E .3 .i E! :HI lq q n n t t t t l l l n t l l l l n l n n t r i n i n n n i a n i n q r n r n n l l n n l n n n n n n n n n n r n n n n n r n n i n c n q i n n l tn l n n t t l l t l l n l t n l l i n l l t l t l i l n n n l n n n n l t l l l n n t n n n n t l l n l l n t l i i n n n l l t l n n n t n l t i LA A A & A A & & I A & A A A T & & A A A A A & & A 4 A & A 4 A A A 4 4 A A A C T 4 A & A T & A A A A 4 A & -n : ? : r a ? : I 1 Q . n : 9 : l 9 9 1 a 9 Q t 1 t 9 1 a 9 Q 1 a 9 ? t a 9 ? n a . r ? r a t q n a 9 ? a 9 9 ? i n ! ? i a 9 ? i a 9 9 n 1 ! - 1 1 ? ? 9: i a - . - - - : -: : : : : : : : : : . . : : . . - - 4. . : . : : . : : . : i a a a | | f; I I s I n I I n + n n I n n f; i a n a a l n n n I q.qa54?81 ;e 5l of 19 9 iA 8 l t . 53 i l 8 5 = n ; 9 3 ; 8 3 I ! ; € 9 3 5 i p f i 3 R 5 = \ + E S D 3 I = 3 3 = 3 3 I r i l 3 9 5 = 3 + f r F ? E S i e I 8 3 ; s ; 5 $ r ss e s s s t t r i ! i r x r l J a l l l l B r e B s ! r s 3 8 8 8 8 r i 3 3 5 5 5 5 5 ! 5 5 5 * 3 * X 3 3 3 * r e e a a a e e S : E ! E = 33 3 3 3 3 3 3 3 3 3 8 3 8 3 8 8 3 3 3 8 3 3 3 3 3 3 8 3 3 3 3 8 8 8 8 8 3 8 3 3 3 3 3 3 3 3 t 8 8 3 3 8 8 8 3 3 8 8 3 3 8 3 8 3 8 3 3 3 3 6 - - @ d € d i - - ed d r * * * d , 6 - 66 d d d - - dd d id - A; ; -; ; ; ; ; ; ; ; ; ; ; ; ; ; ; - ; q3 3 A i I 3 q i E 3 3 3 A A l r r = i = E 3 F r r ; € e r 3 = 3 8 3 3 3 8 8 8 3 3 3 8 8 8 8 8 8 8 8 8 8 t 8 8 - ? 8 3 3 8 3 3 3 3 8 8 8 8 3 6h , e , 5 -€ - - - - - - - ! r' ; h6 6 d - q - 6 6d d h; d 6 66 6 6 d6 6 6 6q , r , ; h 6 6 d d 6 -; - q o nn - - - - l l f l n a a a : 1 1 9 t l 9 t i i r i t i t t t 9 9 9 9 9 q t i * q q a ? q q q q q q i 9 l n - ? ! t 9 1 a t 1 : ? a { e f 9 _a . a o TF F F F F F F F F F G G E G !e a - ? n - l 9 e a i l t a 9 r a - 9 a i 1 9 i 9 9 9 n 1 ! - 9 ? 1 - t 9 9 9 1 q a t 1 ? 9 S 9 9 q 1 ! n \ q i e 9 \ 9 i 9 ? F aa 6 d a d a d 6 a 5 5 a 6 5 5 a - n a a 5 a n a 6 a 6 6 6 d& d A A N d d - & i i i - N d N d a A ?- q Q A n q q . 1 1 A 9 a a * - < ? n n a : I 9 q a r q 1 ! : q 1 - a n n 9 ? l 1 t ! 9 9 n ! n ? ! ? ? 9 9 i n a 1 1 ! ! t 1 ? t ? 9 ? a n !! * a ! ! 9 t I i 9 9 n t 9 r h F q i o- d d d d 9t t 9 n 1 9 - 1 n ! 9 9 9 ? i l ? q ! n i q i 1 ? 1 a n n 1 n 9 a 9 1 9 1 : N - : ! t ! n : 9 ? n 1 1 - 9 q i t : t 1 * l t i a l f t r n An n e : : ; ; g : : e : = = : : : 3 : : e e : = = = 3 : = h I s p = : = g P s e e F 3 : = : = = : e e = : 3 C i = = e = * 3 : 3 = H = H A 1n n - ? ? 9 t a - : l i a a : q e \ t e i i 9 ! ! 9 < a n n t q t n n l 9 i a i q : ? i t t 9 l r n n n ! e q q 1 1 a : q \ ! 1 n n 9 q a _6 9 _ _ rF o r 6 h - F F - - F d F 6 6 6 0 d 6 r r - - - - r F F 6t 5 G 6 F d d N A d N F 6 - - d - - - - - d n - - - n n n d - r - - - e - r i - - 56 - - 6 & 5 - 5 5 6 i 6 d d d 5 d 6 d d d 6 d d d 6 6 d b 5 5 d o ll l t . l l l l l n l q l l t n n t i n t l n n n t l l f nt l t t n n l n n t n n n i n t n n - l l t l n n n n a n - a a a l t l l OL d O 4 T q A I E A L A O i l A A A A A A & & & d d d d A C d d d { E d E E E E E E E E d E E E E E E E C E E E E E E E E E d E E a? a ! 1 9 : n a 9 : n a ? : n a ? : n a t a n a " i n a " n n a i n a n q r a e : a r a 9 a n a " C h a = r i a " n n n - * - n a i - i a nl n n i . r n n n n n r i . : r n n r n n n n n : r r 9 a a a r r . n n - - - a n - - a i a i i : a a a a i i i i i i a + a i i a i i i i aa l a - = t = a 3 3 E - ! 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" 8 3 8 3 3 3 8 3 8 3 t 8 3 3 3 8 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 t E E 3 3 3 3 3 3 e- 6 . n r * - - - d d @ - d d d d ; d i - i ; o6 € G 6 s G 6 0 6 0 0 4 s G O 6 G G 6 6 4 6 4 6 4 4 6 6 6 t r 6 t r 6 6 6 6 C 6 6 6 6 6 6 9i a 9 ? 1 a a - . - 9 - q 9 1 9 9 a i q q - ? i { n ! a r q * e t i : q 1 a 1 a ? - ? n ? a n - 9 ! a i n n 5 GB 3 B 3 € € C G € G € € € G 6 € € € e € € G G € e E € € € e e € e A 3 3 e 3 S R e S S 3 C A € € ; € € e e C € e F R e s s e e aa a a a a a $ $ a a a a $ a a a a e a a a a e a a a a a a e a a e a a a a e a e e a a a e a a a e s e e e e e s a e a e a a a Ad A n ^ & n A d d dd A & - A a & a ?n n i 9 : - , a 1 n 9 i ? t n 9 r q ? i 9 a - 1 9 : n i 1 - Q 9 9 q - 9 - l q 9 f 9t 9 a q r i - 9 q 9 l i ? q 1 9 1 9 + SS X R G S F F F F F F F F F F F F F F F R R G F P F E P F S F P T S R R E F F F R E E = T P F S F S E R E S ; ; 3 E A 3 9q 1 9 i 1 1 1 1 e 1 9 * 9 r ! ? t t - A n 9 i 9 9 i ? 1 a 9 ? ! - T n l l I a q 9 q ! l 9 1 e t e t l 9 t 1 9 1 q ? 9 9 a 9 - =5 ! = t 3 = 8 = = 3 5 3 3 8 3 3 5 = = 3 = S S 8 = 8 = = 8 3 3 t t 3 3 = 3 f , 88 3 3 : : = 3 3 3 a $ S E : i r r ; : 5 5 8 n X i_ i A- - a- N ^ . . : t d * d , e € - n t d d d d d - - - d6 nd d n r i - - - - a€ d d@ € @ € e d , € d * Nd d A d - - d d - - - - d N d d d i l d - d d - - - A - - oF F F € r - - r r € * o s F F- F r - F h F F F r F F 6 i O 6 r F dd d - d A d d d d a a l a a a a a l a - - F F - - F F - 6 n - rr F r r r F F F F F F il t F i d F t s F d d dd d d d - - d d d - d a - !! ! s s s ! ! 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E .a .? O8- - 2 2 2 22 2 2 22 2 2 2 2 2 2 2 2 2 2 22 2 2 22 2 2 2 2 2 2 2 2 Z 2 2 2 2 > Ei l N I E A O A L E E L A L A 4 A 4 A d A T i l A A A & & T A A A I A A A A T I ;; ; t i ; & ; ; ; ; € ; & ; - ; ; ; d - ; ; ; & € ; ; ; , ; ; - . r 6 - - . - ^r id . jF . ; r d i ^ , h r d- N + 6 r . -- . 6 c - = N- 6 r 33 3 8 3 3 3 3 3 3 3 3 = 3 3 3 t C 3 3 3 3 3 3 3 E 3 3 E 3 3 3 3 i\ i i i t i i i i i i i i i i i i i i i i i t i \ t t t i t \ i aP l n t \ 9 9 9 9 9 , 1 9 9 : A n n a n l l n - C ? q n n n a a t 83 3 3 3 8 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 ra n t : ? ? 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Q l a 9 9 - ! t 9 a n 9 1 a - 1 1 9 6 h h h 6 h 6 o 6 6 66 d ; ; ; ; 6 h h; v . h h ; 6 d h v . 6 r ' 6 o ; r' d; ; d d €d r a n nn t t n n n f n n n n l t l n n i t q q q n n n q c n n n n f ll l l l l l l l n n n l a3 a $ 8 r a e r a a 8 a e 8 a 8 3 8 3 r 3 e a 5 5 5 r 3 8 8 8 e e r 8 8 - 4 3 3 8 8 3 8 na n n n l n n n i l n i t a n a q a a n a t t n a n t t n n n n n n n n q q a n a a n r dE A A A A L N A & T d T d A A A & & A A A A A A Ld I A 4 na 9 : n a 9 : n : ? . r a ? : n : ? : t a ? : n a ? n n 9 ? l n P ? a n l ? a a n ? 1 f aa : i : : : : t l a a a l a l a i s : : : a 1 : f :a n : 9 r r : r ! : ! : 9 9 1 9 1 ! 8l of 19 9 . ! i tYqdI9 !Eg .? .z 6! Q:Ep{qin 33 8 3 3 3 3 3 3 3 3 3 3 8 3 3 3 8 8 3 3 3 3 8 8 3 t 3 8 8 8 3 3 3 3 3 3 8 8 3 3 3 3 3 3 3 3 3 3 3 3 ,- - - - d d - d € d - € - - d - - r - - - - - - - . - r d - - d - - e -6 - A - d d - d d - - * d € ii i \ i i i \ i t i r i r r i i \ i i i i i i i r i i i i i r r i r \ i i i i r i f ir i r r r r 9: : i n n - - - q q q ? ? ? - - i : - i t q : - ? q c c i 9 9 9 n 1 a 1 1 a 1 1 9 ! 9 ! ! 9 9 i ? q 38 3 3 3 t t t 3 8 8 3 3 3 3 3 3 8 8 3 8 3 8 3 8 8 8 8 3 3 3 3 8 8 3 3 8 8 8 8 3 3 8 8 8 3 8 8 3 ll n n c l l l a - - 1 : - : - - : a - - - : - : - a q ? 9 ? ? q 1 q ? q n e r e * c e * q c c € 1 c ; h 6 h d 6 h h 6 6 h h 6 d h d h d 6 6 6 6 6 d 6 h 6 6 6 h h h 99 9 9 9 9 9 n 9 9 9 1 1 1 1 1 a n a n i n l t l n n n - - - - 9 ? ? ? ? ? a q 1 1 1 q P e $E 5 E $ E 5 $ 5 5 5 5 $ $ 5 5 0 $ 5 E 5 E E 5 S $ E S E D D E S 5 5 S E E E S 3 3 S 3 3 S t9 € a ! a n 9 q 9 a n Q \ Q n e i l - q n a n a q 1 t 9 l n t ! 9 q a r 9 - n n e t 9 q q nn n n r n q n n n n q n n n n t c n n n n n n n n n n l l n n n n n n n n c n n n n t l n t t l n n l1 - l 9 1 1 a a l q r 9 I q n a n a l c ? q - q l q : i n n a l q q e q q { - t 9 q e 9 n a i - a - ?? ? ? ? ? ? ? ? ? " ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 6* 6 6 6 In l l n l n l l n l n l r a n n n l t n l l l l n n t n n n n n n l n t l t n l n n f tn l 6C 6 r a a c 5 0 0 c n . o a 5 6 c a . . r . r o c 3 nn n n l l n n r a n n a l n i i n n q q n l t n n n l n a n i n n n t l n n n n n l l n n n 4& 4 A A A A A { A A A A A I E A C E A T A & A A A A & & A A A A A A A T A A A A A A A & A T A T d A ? : I a ? : n a ? : I a I i a t * i I I ? : I : ? : n a ? : n ? 9. : n I ? I n n ? n r . I I I n n 9. I n 82 of 19 9 ri =- 6 € i - p p ? q n q c a ? c ? a a q ? o ? 3 a 9 ? q q ? ? ? ? ? ? ? ? ? ? ? ? a n a 5 n , 1 { r a * a n q * ? a e e e n * t < t e r QF - i n q { i ! - n ; - q q q q c p c c q t i i i i i i i t \ \ i i i i i F i 9 9 i i q q ? - : : - - a - : l l l n l n l - a l l - n -c t 5 t .- - r 6 : e , + r 6 o F r t s , a6 5 t 5 5+ 6 ; a o o 6 O € a O b G a 6 6 a O O O a a O sO a a a O -, a 9 q t a 9 9 - P 1 a t q 9 1 ? - a i 9 n t 9 l q < n n ? n 9 : r i q ? n 9 n ? 9 ? n i n - t T n 1 9 1 c r 9 * i 9 ? : i s; s r s * * s E 3 8 g 3 * E 8 S 8 E 8 gg 3 8 E g 8 S a D S 5 * ! S S S S S s g S i ! ! ; ; 3 ; ; B ; $ * 3 ; F ; a ; ; t t3 r c r 65 5 - n 6 5 d G - - c 6 5 3 0 d d d d sS A a a a a a a a a a s i s a a s s a a a a a a a e 4 a l a a a a a a a a a a a a s a s a e a a a a a s s s s e a s s a $ $ 3 3 3 4 $ ;? ; ; ; ? ; q ? = ? ? ? ? ? ? ? ? 9 ? ? ? ; ? : ? i ? ? i : : 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 t 3 3 E 8 3 3 _ i E 3 = 3 E 8 8 3 3 3 3 3 3 ;; ; ; , ; ; . ; ; ; 6 ; q; h h 6 6 6 h 6 6 6 h , ^ d h 6 6 6 6 6 d 6 6 d 6; 6 6 Y ; 6 6 h h h h ; ; ; 6 h d if i e q q ! s l 3 a E r F F F G G € € € G G € G e 6 G G G s G s € G ; G s G G € G G G E s F s B a 6 e B x B x s s s i ? a ! ! r a = i s i S9 q a q a r q q - - - a a a t + 1 4 1 ? - l n q i 9 - i * l ? € 4 9 " ! i 4 - ' t ! ! l 9 q q n q n a q a ! e n ? 9 ? 9 . 1 1 a - ! q ? 9 i= f r 3 8 3 9 g 6 3 r T g X n E 3 ! 9 = ! : = * e R R S S e i r 9 = R 9 1 9 r 1 = ! 1 = a R n 3 3 : = = 8 3 3 = 8 a e ; 8 S 3 8 3 4 4 8 4 =6 * 5 = = N N F - 6 - -. , 4 + a + + + 5- r - d n + 6 6 G F - 6 5 -: d 6 + 6 a b F * d d = : A - + h o F F - 6 4 - N E !UAE. 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S e n i : 1 ; 9 t s i n 3 t s 3 4 8 € E q f f E i E 6 s r s ; s ; s +$ s i t ? ! * i i i ? 6 E 6 E 6 6 n i q q f i fi qf r fi qf i ff f f qn n 6 3 3 E 3 f r qE E E 6 f r qf r A6 f f S s a 3 i = = 5 :! : : t t : : j na E€!.!i!t8. nYo :t r ,EE! .: H (J:,z&i5a,2l i, 9l of 19 9 .l i iq E a l ! r 1 : 8 3 8 + R i q - € i 3 i : q l i e s s E : q 1 q l q * s x l : E € i € s q s q i n 6 s E R i i € r S i f a s : ; s l e 99 : 9 : S 5 5 E g S S g : p : 3 p E E E S 3 3 3 S 3 g s 3 3 E 3 3 ; s S S S S E s g g E S E P P E P P p E P s S ! . i p . S 9 : C S p . P . g sE e a s a a a a a S s a a a a $ a a a a s a 8 a 5 5 5 - = a - E 5 5 5 5 a = - a - = a - i - - 6 i i i . a i = - - - . = _ - _ - _ - _ - : 6 . 5 = = - i . = . : Fd d d d d d r r r - - n - - i I i L I h h I N I h I h h I n - ^ & N - N N - d d A A A i3 ! 5 - 3 3 i 3 : 4 = = ! 3 5 5 3 = = 3 3 9 3 3 3 3 3 3 . 3 3 i a 3 3 3 3 3 = i = i 3 3 3 3 3 3 3 3 = 3 3 9 8 = 3 € 3 3 3 3 3 = = 3 5 = -3 E i r e a q a q q E s s i s q ? 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F . i ; F q q q 3 3 g q € = P e q p q e e e e e q e e e e g e e e e r a i 2 r a b r o r o e e g g g 9 p q q ; b e G b e i e h t c : 9 b 9 b e A !I Q i q q i € F q e s { € 3 q F i i e 3 i - € q q E € q q e c € q G q C q ! ! q E C E q E q E ! { ! i ! q q ! - q - c E ! ! ! i ! i i i 4 ar i n a s l i = . : : n E = : i I = = = = : = = 3 3 a 3 3 3 3 3 3 3 3 3 3 3 : 3 3 s 3 : 3 3 3 3 : i 3 : : P P F 3 3 3 e F = t 3 ; : 3 3 qe i q i r t = ? i ? ? : : r i 3 8 3 8 8 8 8 R 8 8 3 3 8 3 3 3 3 3 3 3 3 3 8 3 3 8 3 3 3 3 t 3 3 3 8 8 3 8 3 E 3 t 3 3 8 t 8 8 8 3 E 3 3r r p a ? 3 € ; q 5 q \ F + = S G 6 S G € R $ g S ; ; S ; = ; $ i $ S ; ; B $ ; ; S 3 R A 3 ; R 8 8 $ ; 3 t $ $ S 9 3 3 4 4 Q * A * i8 3 A & a E 8 * ; ? 3 : : F a l r s E q a r l q 3 t q a { G i e q 3 E 3 ! s E 6 3 q l = : ? = i ? 1 = a : q i ! l i I a i i = F f q _ ! 6i r c hr r - n n d r 6 6 d O 6 d 6 j- : + o F o &i jc r F F 5d jt l o r - - 6 4 - r : d d 6 + ; ; 6 6 ; 6 6 6 + 6 6 6 - r6 h 6 6 o c 6 c 6 o o il b F F @ i & - - - 6 - - - + 6 6 - + t + + - - n i- n & - d - n d d : - d d n n- ; d - + + - L . o - = A n A ^ : - - i - @ d A A - 3 c a ;d ; ; 6 ; ; ; - ; ; - ; ; - ; ; d ; ; - 6 ; € € o o ; G o o o o 6 i d d d o G d oo o o o J 6 d o € o o U c c o d d i l d a a n & d d A n N d d d N d F - - d d - d d d - 6 - d d d d d d ^ A N N dN N N d N N i l N i l N N N - N i l d A d A d N d d d 5& G + F : - - d o t r 6 ' - - 5 d 6 6 - d = d U E 6 + - - o - r 6 ' 6 : o 6 r o 6 - N 3 6 !* t ^ j s r i = i 5 a 3 = : = s = : r r E F R ; r e F p ; l + s s e i ; H E a ; ; € E B R s x F r S ; E s E 3 ; 5 3 , ' . t 8 4 3 5 5 3 3S : r = ? T 3 € S e $ r 3 = i 3 5 3 ; 6 F 8 * 8 3 e S 3 = 5 3 8 S 3 S 5 3 = ^ ; A [ 3 g F ; S r E e R S ? l E q e S a a 5 ! r S ; + h6 6 6 6 ' 6 d 6 6 6 3- ; 3 ; 8 ; 3 ; 5 s q Q S q 6 A r E q A S A E n 3 n q E : E € E - e e i = li - " i 9 . Q n 9 i ? n 9 i c n ! i ? n n i Q n ! e c a 9 q Q F- d d ; ; ; 6 ; 9 = 9 : = = = = : : 1 3 4 a ! ! : = = = ! ! ! ! : 9 9 9 : 8= 8 5 8 * R + S E G g G S = = : * K S E R E g g g S r A g r A r : : : g B 3 = g : : : s s g s : s s s g : s J r ! t ; I ; : g * = 3 J ; ^: : : : i ^ -i ^ ^ ; ^ ^ ^ ^ ^ d ^ ^ ^ n ^ ^ ^ ^^ d d ^ ^ ^ ^ n ^ ^ ^ dN N N d nd i N N ^n d N d n !agUN i. s .z .z :H(J;821 !: E E E E E E E E E E E E E E E E E d E d E E E E E E E E E E I E - E E E C E A O C A d d T T T A A T A L A A A 4 A T A A q E d :a * = i s i E : n i g : i T E i E ? 3 : s ? 9 : ; $ * l a ? 3 i A ? S n E S s S q n E A H e E i E i : i E i S F E n -5 n A f i E A r , X € r: r : i : i : : i i l M : : : 1 : ! ! 1 : 1 : r : : : : : : 1 : : : ! : ! ! : ! : : : : : : ! i ! ! : ! ! : r : ! : ! : : : : : : i -o * - r r, a ? I a n 1 9 n n a 9 1 9 9 a : - -r q at 9 9 9 ! a | 1 l ? i P n * ? oA 1 . 5 ? 5 ; I ; F ;d F i 5 d b - - - - - - b & & - - i - - n - - € - t & - * s . & G . - € € * .EEE- ;+}E EI2 r? , 92 of 19 9 Fa - + r r r + - + + i + - - -- 6 4 6 =. i 5 i o = . . 5 5 5 3 3 o 53 3 5 c i 5 = = . . c . : 5 : *A g 3 * T E 8 g ; 8 A A 5 $ ? 3 ; ; R i S E F T F F F R F F F F F P F F F T P T F F F iq 9 q 9 9 9 9 o 9 9 9 9 9 9 9 9 9 6 9 9 9 9 9 9 9 9 9 9 9 9 9 q 9 9 9 9 9 9 9 q q 9 9 t9 t - 1 n n 1 a - n ? ? q l e q f nl l ? 1 9 1 1 q 9 1 ? a ! a l ? 1 4 1 9 66 r 6 € +- n - - - 6 @ d € a a a * 4 -= a a 3 * 9 f l 3q * f i a= f r €l s 3 s * x E 3 e 3 = ; s 66 6 a o 33 3 e 8 8 3 8 8 3 3 3 3 3 3 3 3 3 33 := 33 3 3 3 3 3 3 3 3 3 3 3 3 3 3 11 1 : n n a i e n a a a l ts & - - i & d - A N A d d d F Fn i l d 6 d r d & r 6 N d 6 ; - - - 3 F & t s + 6 - 5d 9 - a ? \ C l i e 9 9 9 5: o o * d r + - d d 6 - a - 6n G 6 * . 3€ r 6 6 * - , F ;a - 6 0 s9 6 9 6 6 6 6 6 6 n; ; n + + + - - - a a a 6 r , ia & d A n a d N n -F 6 + N rh r ^ - o € r o i e' E t 3 A* N N d d N 6 - F - d d d d ;- - - - n d d - : 6 o 5 6 o o o G o d 6 ; - - o Do o 6 o € d o € € h h 6 6 6 6 ; h , - d 6 9 9 99 9 9 9 9 n- i l i l i l - d d d N -- - - i - - i : : 5E 5 ; 6 5 5 5 6 6 6€ o o 6 6 o G a € a EE E E d E E E E - E E d E E E E d E E d E d d d d L d A & ;; 3 ^ - . 6 - r i ! ? n a 9 ? a a 9 Q n n 9 ? n a 9 ? n e n ? n 1 r i n : 9 : n : l : ;; i i i i ; d d d ;+ + + - + + + + + !- ! a : : i : : : - - L ! ! - : l ! : :a a ! ! -- l : : ! l a 33s !!E3. 2 UI aE 5 3 i F - \ q F 3 F q F i r q r i r q e ja q e 3 3 q a E 3 3 ; s a S E i i ! ! 5 -- d d 6 d d d = = 9 9 = ;?'E 4 JF+9 J -C . ln - : : n - - a : - ii i d J ; ; d ; d d n! ! 9 ! ! 9 9 9 9 9 1n 9 q 1 i t - q n t ni 4 4 4 d n n i - e 33 3 3 3 3 3 8 8 3 E nn a n a a n a n n n 5d 5 d d d d d d 6 a n6 t i d d d d d d d 6e € € o € @ € a 6 6 r€ a n n q 6 t 9 9 a !9 i a q 1 ? - 1 n 1 nn 9 ? n r 9 9 n a 9 €r ; 6 e e e e 33 8 8 8 3 8 1f = t i l = 93 of 19 9 r*se 1a 1 1 1 a A 1 1 a 1 1 1 a 1 1 a a n A a 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4 4 n 4 4 1 1 1 1 9 9 :: : ! 9 :: : 9 9 : I : : 9 -e : 99 ^e 9 ! 9 ?\ : I 1 - a n t ? i 1 n - 1 a q \ a l i l l n q € q i 9 n 9 Q 9 i q i a l 9 n l t ! 1 g* 3 s i * 3 3 3 S $ $ * ; * ; * g 3 J = r S S ; ! 3 $ ! g ! * * E S $ C 3 * g $ D S i 6h r o o C6 6 9 r o6 - o - d o F . -A - e e nn n i i a r ! r n n n t ! a n l t n n n l l l n i n 9 n n n n n l l a a a a n i i 9 a 38 3 3 8 8 3 8 8 t 3 3 8 8 3 8 8 8 8 3 8 33 3 3 3 3 3 8 8 3 33 3 3 3 8 E 3 3 3 3 t! i 9 n 9 i q n ! i q n n i q l n t 9 n 9 i c n n F !tJ dE. i _a8. 2 FE a:O.!I€l+r i- o =1 66 r G 6 G + 6 h 6 a + , +, 64 , o O O 6e - n - - - - - - 66 - d ; 6 - ; d 6 6 d € c o 6d d d d d € € 6 € € ; h 6 6 d 6 6 € € 6 6 6 ; a6 n i - ? q i 9 9 a t : q ? l . . : n: ? q i 9 9 1 l q q e 9 ! a n - ? e t n a n - 9 1 r- 3 d r € - a - GG 6 6 6 G 6 6 6 6 EE E E E E L C d d d d L d A d i l T & A A T T A A A 4 A A A A d & [ A { E A A A A A A 4 ^& ^ ^ A N d n n i l N N d i l d d d & & d a a a n n e d l d d n n n d n n n N N N N d ^ n d d d d d d d d N d d d N N dd d d ^ ^ d ^ ^ ^ N ^N A d d ^ d d n^ N N ^ n +a r r i i i i r n ll a I r . r : aa 1 1 e- - d e 6 e e e d r- ; F : -- - n n n d ; rn n n i n n n t n t f n a a n r a i i n n r n n n n 69 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 ?! 9 : n - Q q - n 9 ? i 9 n 9 9 a r : 9 - i n n n - 19 9 i i 9 9 9 9 i 9 9 9 ! 9 ! ! 9 q ! 9 , a 1 9 1 a 9 33 8 3 8 3 3 E 3 3 3 3 3 3 3 3 E 3 8 3 8 3 3 8 8 8 3 nt 9 1 9 i P 1 ! 9 i * n 9 a 9 a d€ o o o o d a J a 6 d o o ; d ; € € o d ; dN a ; - ; ; i r i 6 6 d d o o o dr F F F &E d A & A A d A A q ! & & & T A A A A A A A A 4 E T na 9 : n r 9 - n a 9 i n l ! i e 1 9 : l a 9 : n a n : J - - : - - - : - - ^ l ^ ^ n n ^ r n r n r n n n a 94 of 19 9 3e E8 8 8 8 8 8 8 8 8 S 8 8 3 8 8 8 8 8 8 5 8 an n n n t n n a n n a i i i n l l l l a n n i r r n r n l n a n n r n l 56 F 6 + - N o d F G 6 - d 5 5& O h - N : q a 9 9 - q : q P 9 n l n ? q f n- - ; i d i n ; ; ; i n + r . 66 6 6 h h 6 6 6 6 -- l i a a a n + l l n a n n r n a i i n 9 n a a n n n n n a a n a n a a o- r - a a = - 6 r d c -6 A d n il d N N d -- ; - 6 33 . 3 5 c5 o 3 = d3 . 5 i 3 5 6r r 6 - GD o + N F 6 & O O o; c o J 6 o ; 6 d - - e o 6 d 6 o d d + ; 4 6 @ 5o r . € e e ! ;e - - - - - - 6 - '3 3 [ * 3 S S = 5 3 S = 5 B E * 3 S D * S -d 5 : d - a + 6 o il t s t s t s r ai ? i ! - a i ! \ a n 9 i c n 9 i ? r ! i ? n 9 i ? n n e ? 1 9 * bi b b b b b 6 € b 9? C 9 n q ! ? i e q 9 n 9 r 1 1 9 r a q t t ! - 9 n 9 i c 1 i n 1 9 1 l &r r r & d - € - * - r r r - aF j r : ^ 6= d d d 5 - F r 6 6 d O a - EE E E E E E E E E E d C E A A [ 4 A T A A A q O i l i l d G A d A A d O C E r6 r A + a : A r 6 - a 1 a : n 1 i : a r 5 - n : ? : n 1 q - a 1 3 : i a tn n n t n n a a a n t n l n n l a n n : a a l n l n n l r a a l n n n n aUAEr 3. 9 U3,E IE: ?g 5- 6 +r r + r a 1 a a a 1 1 1 1 1 1 1 1 1 a a a 1 1 1 4 1 a 1 1 1 1 1 1 j dn n r i n n t n n n n l l l l t l l n n l n n n n r l l n l n a n 6G G G 6 6 6 6 b € :: : : : : : : : : : : : - ' ^ ' :i i l r . ? 1 9 9 \ 9 q 9 l i q n ? a i 1 i - - 9 - a i ! -- - - - c i - d - ;; h + 6 ; 6 + 6 + 6 r 6 h o qr a r 9 - - 1 9 r t a a 1 t : q 9 r n q Q n q i 9 i 1 1 q . a n 9 66 6 O 6 d € 6 € s -e - 6 - J- & - - -- - ^ - - - A ^ - 33 8 E E 8 8 E 3 3 3 3 3 3 8 : 8 3 3 3 3 3 8 E E 3 3 3 3 3 3 3 E 3 ,a ? ? ? - n * a q q q e r r { a a { e q q * € € q * * e * * P r r .5 a d d ,r N + € @ 9 - 5 ;; ; ; ; Gd o d € €6 o . € 6 i 6 6 o o 6 € 6 dd d d N o6 6 G r F t s F r - OO 5 a 3 ++ i + , d. a - 4 6 + h o € F - 1 ? - - n n 1 t 9 9 F * q q : - 1 n n t 9 9 bF F F F F F F F F fi i 5 - 6 & - ; 4 6 - 6 4 - : - 6 € : - E- d d d d d d E d d d A A A A A 4 A E AA A A C E & A A h3 6 - € - O - € -- - - + 5 - a + a 95 of 19 9 :: 9 : : : : g : : : : : - 5 : s5 8 8 8 8 8 8 8 8 8 € 8 5 5 5 3 8 8 8 88 8 5 8 8 : ; ; ; d . 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I | | n n q a 1 I n ? n l 1 1 1 ! ! -- - - - - - - - - ;3 8 8 A 8 3 5 3 e 8 F 3 G € X 3 5 3 S F 3 * 9 : 5 9 3 n ; n 5 E 3 5 ! i 9 E ! i ! : I s s i s I : s s p B B g s t : : P a s E t s E : r- F' : s P P. s P. 5 e E E p 3 -- i 9 n I f ! q a 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 -1 E E 5 5 3 3 8 3 -5 3 3 3 3 3 3 3 3 i 5 3 3 3 = dd A d d d d d d d d a d d d d d d n d d d d d d d a* * a * a e 8 $ * * * JJ s E s = E 8 E $ E a ; ; ; * * e a 8 ; ; e S ; e e a ; ;; ; d d d d d d 5 5 5 d d d d d d 6 6 d d d d d d d d d 6 d d 6 6 5 d d 6 6 6 6 5G 5 i d a : 6 n - 5G i 1 - n5 6 n a - n - - a n i q l o - F e l l l 6 a o^ + ai ; i - - - - a 4 i ; - n - a r i d j nh & h e - n - - & - 6 + + - - d - e d - o N d d -- - 6 6 Ni l N N N A i l d I N d d A d d d d N d d dd d o e o o a d 6 6 s s o . € € € € 9 9 9 9 9 9 q 9 € € a d& n - F F ^ - - A Nd N N N N d A d d - i l d d d 56 i i l - d - 6 6 a a . d - 66 i - - 6 n o 6 - ^ 5r r € + - - 3 1 t 9 n - : - ? I 65 5 5 6 6 5 o i o o e O 6 6 O U O o € 3€ o a 6 o o o € 5 55 jn - a + 6 6 r - & d 5 : d n i i 6 A F q Q q Q i i t 9 l n q i ? I q ? - n n FF F F F F F F F F F F F T T T n t s F i F n F F F F F F T T ; 5 i E S 5 q q ! q E E * 3 A q 4 3 4 e C : E q A = E : { : i I i : !' c ! : I E ? EE d E E E E d E E E E E E a d E E E E e e d - d 4 E d d d d a d A d L d e d n -' R 3 3 8 - S ; 8 - - a a - n a Q - n + 3 I - + I - r t c :4 . a ? . i 6 3 n a n ? .. ++ + ; ; 6 6 6 4 O e, A - - - - - a + + + + r + r ^^ i i ^ n i l d n n a a a n d i l n ^ N n i n d i n N N ^ n d d n n n ^ i n { d n ,E la ! f,Ea{f ;ez4 !E. g 3. 2 ?: .: l d (J 96 of 19 9 n1 3* - ? r J ; e i ^ 3 t F ; I : , 3 ; . e i ! { i 5 i F 3 + 3 R E i F 3 4 ; s E e r H ; K = l r 3 $ R 3 ! ! : i . E i ! : * i : : = } : i f i : f :: ; : ; ; = : : r = R ^ r E x s ; : B F g ; q + s ? a i l a s i e ; G € G 6 R s r F r F ; c t E * B e e s = e = = E ! E i ! r i = = r : : ir : r = r q ? r ? : r ? : r r 8 8 8 8 3 3 3 8 3 3 8 8 8 3 8 3 8 3 3 3 8 8 3 3 8 3 3 8 8 3 3 8 8 3 3 8 3 8 3 8 3 3 3 8 3 8 8 8 E 3 3 3 8 td d - d i n t - - 6 - - a * - - - n t d - - - - o- - - - - - d 6 e 33 : 3 3 3 3 3 3 3 8 3 3 3 3 = 3 3 3 3 3 8 = 3 3 3 3 3 3 8 : 3 = = = = E : : 3 3 3 3 3 3 3 3 = 3 = 3 = 3 3 3 3 3 3 = 3 3 3 = = . = = 1 3 E ;; ; ; ; ; - ; ; ; ; ; d d d - - - - - , i - F - d a 6 -& ; i d d d d - t - - d - n - d € - - - . € - - € - !! 3 s E ! ! ! 3 ! ! ! ! q 3 ! ! S ! & A q 3 3 S C I 3 & E ! $ q q q r C a a E ! ! ! 3 3 ! ! S ! ! ! ! ! i ! ! i i ! ! E ! ! 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I I = 5 E 5 6 A A E ! a 3 5 6 C 5 : 3 3 8 5 E 3 ! = 3 = 3 i : 3 _ ! j ! : 9 5 ! a = 8 9 ; l 3 s 3 a x 5 3 e i ; = = 8 5 3 8 q 3 : : : : ; 66 A d d d- - - e - 6 a N - : fn n n l t t t n t n n n n i f l f f l n c i q n n n q l f t n l l n n n n n n n l l n i i n n a n q r n n l l i l l n n q n i n q n n n an a a n 1 n 9 9 9 9 9 9 9 a i a n 1 I n n 1 n n 1 1 a 1 9 * 9 n n q 9 a 9 9 f n q e r 9 1 n l a a n n a ! i ? - - . - . - € 9 i q n a 1 r - -i d d d n : j - i 6- 6 6 - :. s G 3 = f f $ 3 F + € F t 8 3 8 = e : = ! ! ! ! 9 e e e f r = = : ! : r : ! ! e 3 = 3 8 8 F G f i 5 1 S i F 3 3 i n E 3 I l I ; 3 ! 1 ! i - !\ P a n q e 3 e ? ? ? - : - - - . 1 l l l l | l 1 n n l n n l n n l ! . l I n n n . n e n n n | a 1 1 1 1 1 :: E 5 X X : r h r : i E I I 5 5 h e 5 h h F E h 5 E I r 5 h h r 5 5 I i E I 5 I 5 5 h : : I : n 5 5 : 5 h E 5 5 5 h h h E I 5 I I h h h II i E A € E I S D E S H r H s E X a F F i E f * E X P g $ q 9 * X S n f r g r r i S A a g $ F F r = F I : = F F € 3 p = 5 F A e € e 6 F nQA :u:E .? .2 - a ,- 5 - F d r n r F * * & 6 - r r & 6 6 6F € 6 - G F d r F a - a - - F- 5 o o -i . - l - - . n n . n n n n n \ ^ l ^ n i - - - - - - n n - ^ . 1 - n 1 - n . ] 1 1 a ] ] 1 : 1 ^ ^ == 5 5 5 5 : : 3 = = = = 3 = 3 . 5 d 5* r a . * r 3 - jh - d ; 6 6 r r n d - i 3 - : - i ^ - d ^ A ^ ^ 33 4 5 5 r= E ? t t t t ? t t t = ? 3 1 ? l = ? l l t l l l i l l l ? l l l e l l l l l l l l l ? ? 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C = . 3 . 5 3 i: - : - -^ ^ ^ l 10 8 of 19 9 ri i9 9 a a ! i q ? q . t a ! ! a t t 9 i { q - - d !9 9 9 ! 9 9 ! 9 n ! 9 ! ! 9 ! ! 9 n n 9 ! ! ! n ! n t 9 ! 9 ! n ! ! 9 ! :e q q a a q q n q q , 33 3 3 3 3 3 3 3 3 3 8 3 E 8 3 t t E E 8 3 E 3 3 8 3 8 8 8 E 8 3 8 8 E 8 it t i i i i i t i i i i i i i i f ti i i t t i t i i t i t i i i i t i an n n a n l a l 9 9 9 i i t i i i q a q ? q l - - - n l n a n r a l a l od & & d I c [ & d d c I o d o l a c d L d n a a a a a c a a A A A r a a ;; 6 ; d ; ; d ; ; n i d ; & & ; d ; d d 5 5 5 5 r : : r d A ^ ^ ; - d . f il n n n n i ^ n n i l i l n n i n n n { i d d n ^ d ^ -t n ! a 9 ? n q 9 l 1 n - 1 a 1 a 9 n n € q : - n ? i 9 q ? a 9 1 i l q -a q 9 q < ! a a ! 9 ! q 9 1 c n r i { i 1 9 ? 1 q ? ? q q q 1 a 1 1 1 a nn n n r e n n n n n r r r n r n n n n t n n n n a n n n n n a n a n n n r9 n s : = s ! : s ! l = co r t r - 6 fi i t t t t t i t i t t i i t t i i \ i i t i t t i q r \ i i r r i r i 38 3 3 3 3 3 3 8 3 8 3 3 8 3 3 3 3 3 3 3 3 5 5 S 5 5 5 5 5 S A 5 3 S 5 5 qa a n n q e q a a a n a a n a a a a a a a a n a a i n a i l n n a l l l : nir .2 , .= .: HUfa2{i8- a >1=] d; r . - d + d i i i r € - 5 i + 6 d in + 6 d €€ o o r 33 3 8 8 8 8 8 3 8 8 8 8 8 8 8 8 3 8 8 8 8 3 8 8 8 8 3 8 3 8 3 3 € e € € d .d d d@ ' @ -, t td t * d d d - na l : : ? ? q ? ? a * 1 q q ? a ? " q 9 ? e - - i l n t n i n n n q qc e t 9, n l ! 9 i q Q 3 -n a ar 9 99 9 9t 1 c i 9 9 i ? 1 q iq q ? 9 9 ? n a t a r 9 ? 1 1 t n ? - 9 n n ? 1 q q ? ? i a l t -n 1 9 1 n q a ! n i ? q ? f t9 a 1 9 n i 1 ? - Q i n a 1 ! n ? 9 ? ?? ; ? ? ? ? ? ?? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? l ? ll n n n n n n t l t n n n f nt l n n l n n l l f t t n l i t l eI E o a r & & e o a a a rF F ; * -i - - A d ^ ^ 6 F : e- = d a r e o a d a r a o a a n n n d n n n n n a e d d n n I 09 of 19 9 FiEE aoaYu ?t rA. e (J:ni" - >1 99 ! a a l i t - q q o na Q a 9 9 r 1 1 n n n : : ? a q r { t 9 € 9 9 a r n n l 33 E 8 E 3 3 8 3 3 3 e 3 3 3 3 8 8 8 3 t t 8 E 8 3 3 8 8 3 8 3 3 3 i 3 3 3 3 3 3 ?a ? q q { q i 9 9 n 1 n n 1 n 1 1 n ! n a l n n r t t l l n r n a l n l - - : - Q! q n n 1 1 - q q i { ?a l i a q 9 : t 1 9 1 ! 9 - 1 t q ? n 1 q 9 ! t q - n 1 -- = 3 5 ii t i t t t t i i t \ t i t t i i i i i i i l i i i i i t t i i i t i t t t i t aa n a n n i n - : a a q e e - - : - l l n n - : - ? ? ? 9 q - - - l - - Q q a q ?q n a q a q 9 1 n n 9 ? - a t q q : a : ? q r e r i t t n e . t t a n - - Q q e 41 n : f -a 1 a a 9 q q Q ? ? 1 q l n ? - Q Q r l r l - a i t i ! n 1 ! 4 9 9 9 9 30 c 5 0 0 a o c 3 30 0 c a 0o 6 0 0 aa a a e n q n e n a a - a a a a n a i a n a a l l l a a l n i n n i n c n n n i nn n q q n n i q n q q t n n n q n l n l n l t l n n l t l n l l n l q n n n n q n &a a o e r a a d o e o I a a o r a o E o a r a E a a [ [ { 4 i l d a d & & & a a a _a c _ _ nr a a e n n n a t n n n t n n n n n n t r n t a a l a a : a a l a a : a a : : : I l0 of 19 9 Em issions Calculations Alffirpe Location HF Sinclair woods cross Refining ,LLC -west Bountiful, UTT t-{l 1l f", rcA } {} F] ()tJ :; Source BoilerNo. l0 Project No. AST-2023- 1660 Run Number Runl Run2 Run3 Averase Date Start Time Stop Time 8122123 l0:5 I l5:09 8t22t23 8t23t23 16:42 10:15 2l:14 14:39 Calculated Data - Outlet )z Concentration, %o dry co, 4.43 4.92 4.45 4.60 3Oz Concentration, 7o dry cco, 9.17 8.75 8.90 8.94 lllofl99 */twAIATEe TTCH'!,JCAL GROLJP Runl-RMData Location: HF Sinclair Woods Cross Refinin LLC - West Bountiful. UT Source: Boiler No. l0 Projcct No.: AST-2023-1660 Date: 8122123 Time Unit Status Or - Outlet COr - Outletohdry Y"dry Valid Valid l0:51 l0:52 l0:53 l0:54 l0:55 l0:56 l0:57 I 0:58 l0:59 I l:00 I l:01 I l:02 I l:03 I l:04 I l:05 I l:06 I l:07 I l:08 I l:09 I l:10 ll:ll ll:12 ll:13 ll:14 ll:15 ll:16 ll:17 ll:18 I l:19 I l:20 ll:21 ll:22 I l:23 ll:24 |.25 ll:26 ll:27 I l:28 ll:29 I l:30 ll:31 ll:32 I l:33 I l:34 I l:35 I l:36 I l:37 I l:38 I l:39 I l:40 I l:41 I l:42 I l:43 ll:44 I l:45 I l:46 ll:47 I l:48 I l:49 I l:50 I l:51 ll:52 I l:53 I l2 of 199 2.93 3.39 3. l9 3.40 3.l s 3.09 3.31 3.28 3.26 3.09 3.29 3.46 3.33 3. l5 3.30 3.33 3.25 3. t6 3.44 3.7 t 3.5 t 3.78 3.49 3.90 4.07 4.43 4.59 4.85 4.84 4.66 5.64 4.',73 4.U 4.07 3.96 4.12 4.06 4.38 4,35 3.9 4.12 3.85 3.63 3.45 3.89 3.98 3.',12 3.92 3.91 3.80 3.70 3.88 3.84 4.08 4.1 I 3.93 3.56 4.01 3.88 4.04 3.80 4.00 402 10.1 7 9.89 10.04 9.90 t0.01 10.t2 9.97 10.00 10.04 10.23 10.10 9.96 10.05 10.l8 10.07 10.04 10.08 10.13 9.96 9.77 9.93 9.73 9.89 9.7 5 9.65 9.37 9.22 9.09 9.09 9.18 8.64 9.tI 9.23 9.44 9.48 9.4s 9.50 9.34 9.37 9,5s 9.46 9.61 9.71 9.82 9.56 9.54 9.69 9.55 9.58 9.64 9.69 9.54 9.s8 9.45 9.44 9.54 9.78 9.50 9.57 9.50 9.62 9.52 9.5 t *2AIiarEe TECHNICT\L. GfqtflJP L*"tioot Snrrce' RnilerNn lO Runl-RMData Project No.: AST-2023-1660 Dzte:812223 Time Unit Status O: - Outlet COz - Outlet "/"dry "/odryValid Valid I l:54 I l:55 I l:56 I l:57 I l:58 I l:59 l2:00 l2:01 12:02 l2:03 l2:04 l2:05 l2:06 l2:07 l2:08 l2:09 l2:10 l2:ll 12:12 l2: l3 12:14 l2:15 12:16 12:17 l2:1 8 l2:19 l2:20 l2:21 l2:22 l2:23 l2:24 l2:25 l2:26 l2:27 l2:28 l2:29 l2:30 l2:31 l2:32 l2:33 l2:34 l2:35 l2:36 12:37 l2:38 12:39 l2:40 12:41 12:42 12:43 12:44 12:45 l2:46 12:47 12:48 12:49 12:50 12:51 12:52 12:53 12:54 l2:55 l2:56 I 13 of 199 3.79 4.05 3.86 4.t3 4.18 4.07 3.8',1 4.25 4.06 4.t9 4.09 4.58 4.52 4.67 4.s2 4.28 4.29 4.51 4.34 4.44 4.47 4.37 4.55 4.7 | 4.97 4.70 4.91 4.81 5.09 4.54 4.99 s.02 4.93 5.05 5.15 5.06 5.36 5.21 5.01 5. l9 5.21 5.23 5.09 5.22 5.13 4.78 4.91 4.84 4.66 4.6s 4.98 4.6t 4.79 4.62 4.70 4.73 4.88 4.65 4,89 s.07 5.01 4.93 5.0t 9.61 9.47 9.57 9.43 9.42 9.48 9.59 9.39 9.47 9.39 9.44 9.21 9.20 9.12 9.23 9.34 9.35 9.21 9.25 9. l6 9.14 9.22 9.1 I 9.03 8.85 8.98 8.85 8.94 8.77 9.05 8.84 8.80 8.84 8.7 t 8.69 8.77 8.62 8.67 8.76 8.69 8.69 8.68 8.76 8.70 8.73 8.95 8.87 8.92 8.99 9.03 8.84 9.03 8.97 9.0s 9.02 8.99 8.85 8.93 8.85 8.72 8.'.tz 8.77 8.77 Runl-RMData AIffiIrc.B'T i: c l--'l N ic A t- $ H l,ocation: HnsinclairwoodsCrossRefiningLLC-westBountitul'ur Sor.aa,ffi Project No.: AST-2023-1660 Drftt 8n2D3 Or - Outlet COr - Outlel Y"dry Yodry Valid Valid Time Unit Status t2.57 l3:08 l3:09 l3:10 l3:ll l3: l2 l3: l3 I 3:14 l3:15 I 3:16 l3:17 l 3:18 l3: l9 l3:20 l3:21 l3:22 l3:23 l3:24 13.25 l3:26 13.27 l3:28 l3:29 l3:30 l3:31 l3:32 l3:33 13.34 l3:35 l3:36 t3.37 l3:38 l3:39 l3:40 l3:41 l3:42 l3:43 13.44 l3:45 l3:46 l3:47 l3:48 l3:49 l3:50 l3:51 l3:52 I 3:53 I 3:54 l3:55 l3:56 l3:57 l3:58 l3:59 14:00 l4:01 l4:02 l4:03 l4:04 l4:05 I 4:06 l4:07 l4:08 l4:09 I l4 of 199 5. l4 5.06 5.0t 4.97 5.04 5.07 4.78 4.95 4.93 4.83 4.82 5.1 I 4.84 5.04 4.87 5.1 I 4.91 5.t7 5.15 4.99 4.76 4.97 5.03 4.88 4.95 4.83 4.88 4.56 4.67 4.61 4.50 4.28 4.67 4.55 4.63 4.63 4.46 4.26 4.47 4.74 4.45 4.74 4.38 4.77 4.79 4.50 4.76 4.54 4.73 4.39 4.53 4.34 4.07 3.84 4.01 4.35 4.24 4.20 4.56 4.31 4.57 4.54 4.44 8.69 8.69 8.'12 8.72 8.70 8.70 8.85 8.78 8.79 8.84 8.84 8.67 8.83 8.71 8.80 8,66 8.76 8.63 8.64 8.74 8.86 8.77 8.73 8.82 8.78 8.88 8.86 9.04 8.99 9.04 9.08 9.20 9.03 9. l0 9.06 9.06 9.14 9.24 9.14 9.00 9.t6 9.01 9.t9 9.01 9.00 9.15 9.03 9. l5 9.05 9.24 9.17 9.29 9.43 9.56 9.49 9.29 9.33 9.36 9.17 9.27 9. l6 9.13 9.t5 #AIibTpe T r c i-"1 N lc A L G ff ', lJ p mdsCrossRefinins.LlC-westBountitul.ur Run 1- RM Data Source: Boiler No. l0 Project No.: AST-2023-1660 D^tet 8122123 Time Unit Status Or - Outlet COr - Outlet "/"dry "hdryValid Valid l4:10 l4:ll l4:12 l4:1 3 l4:14 l4:15 l4:16 l4:17 l4:18 l4:19 l4:20 l4:21 l4:22 l4:23 l4:24 l4:25 l4:26 l4:27 l4:28 l4:29 l4:30 l4:31 l4:32 14.33 14.34 l4:35 l4:36 l4:37 l4:38 l4:39 l4:40 l4:41 l4:42 l4:43 l4:44 l4:45 14.46 l4:47 14.48 14.49 14:50 l4:51 l4:52 l4:53 t4'.54 l4:55 l4:56 l4:57 l4:58 l4:59 l5:00 l5:01 l5:02 l5:03 l5:04 l5:05 l5:06 l5:07 l5:08 4.23 4.09 4.64 4.66 4.57 4.51 4.7 5 4.53 4.55 4.57 4.76 4.70 4.42 4.',II 4.42 4.73 4.7 5 4.35 4.68 4.63 4.54 4.20 4.49 4.54 4.20 4.50 4.53 4.47 4.31 4.14 4.72 4.39 4.68 4.47 4.72 4.74 4.53 4.82 4.55 4.57 4.63 4.65 4.56 4.37 4.67 4.87 5.09 5.51 s.42 5.74 5.85 5.60 5.80 5.7 5 5.52 5.09 4.81 4.99 s02 9.23 9.29 9.04 9.00 9.08 9. l0 8.95 9.08 9.04 9.05 8.93 8.95 9.1 I 8.92 9.09 8.94 8.93 9. l3 8.96 8.98 9.02 9.19 9.06 9.04 9.20 9.05 9.02 9.03 9.13 9.21 8.93 9.09 8.96 9.06 8.92 8.91 9.03 8.89 9.00 9.01 8.99 8.98 9.02 9.07 8.95 8.85 8.80 8.57 8.57 8.38 8.30 8.39 8.27 8.31 8.44 8.65 8.83 8.73 876 ll5ofl99 anlmncxe Y E c H hl i{) A l'- {} rq o t' l-*rnon, HFsinclairwmdscrossRefinins,LLC-westBountitul.UT Run 1- RM Data Source: BoilerNo. l0 Project No.: AST-2023-1660 D*e:822123 ValidValid Time Unit Status Or - Outlet COr - Outlet "/"dry "/.dry Uncorrected Run Aversge (Cob,) Cal Gas Concentration (CM^) Pretest System Zero Response Posttest System Z€ro Response Average Z€ro Response (Co) Pretest System Cal Response Postt€st System Cal Response Average Cal Response (Cy) Corrected Run 4.48 10.97 0.09 0.06 0.08 10.97 10.96 10.97 4.43 9.t5 10.80 0.01 0.02 0.02 10.79 10.77 10.78 9.17 I l6 of 199 alImrpe.IEC'--INiQAI* $q(}LJil Run2-RMData Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: BoilerNo. l0 Project No.: 4ST202l:! 660 Date:8122123 Time Unit Status Or - Outlet CO: - Outlet "/"dry "hdryValid Valid l6:42 l6:43 l6:44 l6:45 l6:46 l6:47 l6:48 l6:49 l6:50 l6:51 l6:52 I 6:53 16.s4 l6:55 l6:56 l6:5'l l6:58 l6:59 l7:00 l7:01 17:02 l7:03 17:04 l7:05 17:06 17:07 l7:08 l7:09 l7:10 l7:l I l'l:12 17:13 l7:14 l7: l5 l7: l6 l7:17 l7: l8 17:19 t7.20 17:21 17:22 17:23 17:24 17:25 17:26 17:27 17.28 17:29 l7:30 17:31 17:32 17:33 17:34 17:35 l'1:36 11:37 l7:38 11 .39 17.40 17:41 17:42 17:43 17:44 ll7ofl99 4.94 4.',79 4.60 4.58 4.92 4.92 4.7'l 4.85 4.93 4.92 4.61 4.95 4.74 4.80 4.89 4.89 4.76 4.72 5.05 4.81 4.96 4.91 4.81 5.07 4.76 5.03 5.02 4.94 4.75 4.84 5.08 4.89 4.90 4.95 4.69 4.83 4.87 4.81 4.73 4.97 4.91 4.98 4.79 4.97 4.80 5.02 4.93 4.74 5.20 5.55 5.56 5.43 5.86 s.94 5.7 5 5.81 5.78 5.61 5.68 5.60 5.44 5.12 5.23 8.82 8.89 8.97 9.02 8.84 8.83 8.91 8.87 8.82 8.80 8.95 8.80 8.89 8.87 8.81 8.82 8.90 8.94 8.76 8.87 8.79 8.81 8.87 8.72 8.87 8.74 8.7s 8.80 8.90 8.86 8.74 8.81 8.83 8.77 8.93 8.85 8.83 8.83 8.90 8.76 8.80 8.75 8.84 8.72 8.83 8.74 8.78 8.89 8.6',1 8.50 8.48 8.51 8.27 8.20 8.29 8.26 8.26 8.35 8.33 8.38 8.44 8.60 8.60 RIIffirrce TfrilI-{'T]CAL GROUP Location: HF Sinclair Woods Cross Refinins. LLC - West Bountiful. UT Run2-RMData Source: Boiler No. l0 Project No.:AST-2023-1660 D.tet 8122/23 Time Unit Status Or - Outlet COr - Outlet "hdry "/"dry Valid Valid 17 .45 17:46 t7 .47 17:48 17:49 I 7:50 17:51 17:52 17:53 l7:54 l7:55 l7:56 17:57 I 7:58 17:59 I 8:00 l8:01 l8:02 l8:03 l8:04 l8:05 l8:06 18:07 18:08 18:09 18: l0 l8:l I l8:12 1 8:13 l 8:14 l8:15 l8:16 l8:17 l8:18 l8:19 l8:20 l8:21 l8:22 l8:23 l8:24 l8:25 l8:26 l8:27 l8:28 I 8:29 l8:30 l8:31 I 8:32 l8:33 I 8:34 l8:35 I 8:36 18:37 18:38 18:39 l8:40 l8:41 18:42 l8:43 18:44 l8:45 18:46 18:47 ll8ofl99 5. l8 5. l3 4.99 s.08 4.96 4.88 5.03 4.90 4.85 5.03 4.84 5.03 5.05 4.95 4.74 4.90 5.05 4.94 5.07 4.92 5.04 4.95 5.09 4.83 4.87 5.00 4.93 4.7 5 4.5s 4.98 4.79 5.03 4.84 5.01 5.01 4.78 4.98 4.95 4.76 4.92 4.69 4.86 4.87 4.80 4.61 4.7 5 5,01 4.83 4.97 4.86 4.99 4.70 4.92 4.95 4.88 4.69 4.78 5.03 4.82 5.03 4.79 4.95 4.86 8.62 8.69 8.75 8.71 8.76 8.81 8.70 8.77 8.82 8.72 8.83 8.7 5 8.74 8.78 8.84 8.78 8.68 8.75 8.71 8.80 8.73 8.79 8.72 8.84 8.85 8.78 8.80 8.86 8.97 8.73 8.84 8.74 8.84 8.75 8.76 8.87 8.77 8.78 8.88 8.19 8.91 8.84 8.83 8.87 8,96 8.90 8.76 8.86 8.76 8.82 8.7 5 8.89 8.81 8.78 8.81 8.90 8.89 8.75 8.84 8.73 8.86 8.75 8.81 d Run 2 - RM DataAIATEe T [: c l"j hl : c A l'- G fi l,ocation: HF Sinclair woods cross Refining, LLC - west Bountitul, UT Soua"", Project No.: AST-2023-1660 Date:8122123 Or - Outlet COr - Outlet Y.dry Y.dry Valid Valid Time Unit Strtus l8:48 l8:49 l8:50 l8:51 l8:52 l8:53 l8:54 I 8:55 I 8:56 I 8:57 I 8:58 I 8:59 l9:00 l9:01 l9:02 l9:03 l9:04 l9:05 l9:06 l9:07 l9:08 l9:09 l9: l0 l9:ll 19:12 l9:13 l9: l4 l9:15 l9: l6 l9:17 l9: l8 l9: l9 l9:20 19:21 l9:22 t9.23 19:24 19:25 19:26 19:27 19:28 19:29 l9:30 l9:31 19:32 l9:33 19:34 19:35 19:36 19:37 l9:38 l9:39 19:40 19:41 19:42 l9:43 19:44 19:45 19:46 19:47 l9:48 19:49 l9:50 I l9 of 199 4.68 4.84 4.80 s.0l 4.80 4.98 4.68 4.90 4.91 4.81 4.55 4.87 4.91 4.7 | 4.90 4.7 s 4.92 4.7 t 4.96 4.98 4.77 4.95 4.92 4.64 4.87 4.89 4.84 4.68 4.69 5.03 4.79 4.92 4.79 4.92 4.77 4.77 4.75 4.87 4.88 4.96 4.93 5. l0 4.82 4.',71 4.80 4.67 4.85 4.89 4.81 4.46 4.72 4.7 5 4.72 4.77 4.60 4.90 4.76 4.98 4.78 4.80 4.96 4.92 4.78 8.90 8.84 8.8s 8.73 8.85 8.76 8.92 8.81 8.81 8.85 8.97 8.82 8.78 8.90 8.80 8.88 8.79 8.89 8.79 8.76 8.87 8.78 8.78 8.92 8.82 8.82 8.83 8.91 8.92 8.75 8.86 8.?8 8.87 8.79 8.83 8.86 8.87 8.83 8.84 8.81 8.82 8.74 8.88 8.92 8.89 8.94 8.85 8.84 8.89 9.05 8.94 8.92 8.94 8.92 9.00 8.88 8.93 8.82 8.91 8.91 8.83 8.84 8.91 #AlAlEEr-r E c H N l(]A L' $ fito u ?o.rnon, HFsinclairwoodscrossRefining.LLc-westBountitut,ur Run2-RMData Source: BoilerNo. l0 Project No.: AST-2023-1660 Date:8/22/23 Time Unit Status Or - Outlet COr - Outlet T,dry "hdryValid Valid l9:51 l9:52 l9:53 19.54 l9:55 1956 19:57 l9:58 l9:59 20:00 20:01 20:02 20'.03 20:04 20:05 20:06 20:07 20:08 20:09 20: l0 20:1 I 20:12 20: l3 20:14 20:15 20:16 20:17 20: l8 20.19 20:20 20:21 20:22 20:23 20:24 20:25 20:26 20:27 20:28 20:29 20:30 20:31 20:32 20:33 20:34 20:35 20:36 20:37 20:38 20:39 20:40 20:41 20:42 20:43 20:44 20:45 20.46 20:47 20:48 20:49 20:50 20:51 20.52 20.53 120 of 199 4.59 4.91 4.95 4.78 4.78 4.82 4.84 4.67 4.54 4.72 4.88 4.68 4.94 4.88 4.88 5.60 5.59 5.61 5.86 5.89 5.62 5.53 5.',|2 5.21 4.4s 3.80 3.95 4.58 5.10 4.89 4.56 4.29 4.49 4.42 4.92 4.82 4.53 4.20 4.t2 4.7 t 4.76 4.60 4.52 4.11 4.27 4.24 4.27 4.24 4.31 4.43 4.68 5.01 5.20 4.81 5.34 5.44 5.53 5,7 5 5.84 s.80 5.68 6.05 6.ts 9.01 8.87 8.83 8.93 8.91 8.m 8.87 8.97 9.06 8.95 8.87 8.96 8.85 8.86 8.90 8.54 8.50 8.49 8.33 8.29 8.42 8.48 8.37 8.62 9.01 9.36 9.32 9.00 8.72 8.81 8.97 9. l3 9.02 9.06 8.82 8.85 9.01 9.l6 9.21 8.93 8.89 8.99 9.01 9.21 9.t4 9.t6 9. l5 9. l8 9.ls 9.07 9.00 8.85 8.76 8.94 8.6s 8.50 8.48 8.33 8.28 8.25 8.33 8. l3 8.05 dAlAnsE) TTCiJN:CAL $fi(}I,Ji: Run2-RMData Location: HF Sinclair Woods Cross Refining. LLC - West Bountiful. UT Source: BoilerNo. l0 Project No.: AST-2023-1660 Date:8/22/23 Time Unit Status Oz - Outlet COz - Outlet "/"dry "hdry Valid Valid 20:54 20:55 20.s6 20:57 20:58 20.59 2t:00 2l:01 2l:02 2l:03 2l:04 2l :05 2l:06 2107 2l:08 2l:09 2l: l0 2l:ll 2t.tz 2l:13 Uncorrected Run Average (Cnu) Cal Gas Concentr.tion (Cm) Pretest System Zero Response Posttest System Zero Response Average Zero Response (Co) Pretest System Cal Response Posttest System Cal Response Avcr.ge Crl Response (Cu) 5.94 6.06 5.84 6.05 6.03 5.73 s.6 t 4.97 4.35 4.42 4.72 5.54 s.63 s.78 5.49 5.41 5.16 5.01 4.87 477 4.95 10.9s 0.06 0.07 0.07 10.96 10.92 10.94 8. l6 8.10 8.21 8.09 8. l0 8.26 8.31 8.63 8.98 8.92 8.76 8.37 8.32 8.25 8.39 8.42 8.58 8.63 8.72 875 8.78 10.7 4 0.02 0.07 0.05 10.77 t0.76 10.77 7 l2l of 199 #Ali-arpe T {:{] i'-{ N 1c&L Gfi ot'T,o."non,HFsinclairwoodscrossReflnins.LLC-westBountitul.ur Run3-RMData Source: BoilerNo. l0 Project No.: AST-2023-1660 Date:8/23D3 Time Unit Status Or - Outlet COr - Outlet Y,dry %,dry Valid Valid l0:15 l0:16 l0: l7 l0:18 l0:19 l0:20 l0:21 l0:22 l0:23 l0:24 l0:25 l0:26 l0:27 l0:28 l0:29 l0:30 l0:31 l0:32 l0:33 l0:34 l0:35 l0:36 l0:37 l0:38 l0:39 l0:40 l0:41 10.42 l0:43 l0:44 l0:45 l0:46 l0:47 10:48 l0:49 10:50 l0:51 l0:52 l0:53 l0:54 l0:55 l0:56 l0:57 l0:58 l0:59 I l:00 I l:01 I l:02 I l:03 I l:04 I l:05 I l:06 I l:07 I l:08 I l:09 I l:10 ll:ll ll:12 I l:13 ll:14 ll:15 I l:16 I l:17 122 of 199 4.76 8.77 4.96 8.62 4.65 8.79 4.80 8.73 4.67 8.80 4.85 8.71 4.s8 8.85 4.81 8.74 4.77 8.77 4.38 8.95 4.67 8.80 4.70 8.80 4.59 8.84 4.4t 8.94 4.78 8.',15 4.75 4.M 4.67 4.42 4.62 4.61 4.43 4.38 4.44 4.23 4.41 4.53 4.56 4.19 4.43 4.47 4.39 4.44 4.68 4.47 4.47 4.61 4.s5 4.29 4.22 4.34 4.51 4.34 4.s4 4.32 4.40 4.46 4.40 4.21 4.57 4.36 4.59 4.36 4.57 4.46 4.30 4.54 4.44 4.54 4.40 4.53 4.42 4.t7 8.76 8.92 8.80 8.92 8.84 8.84 8.92 8.97 9.01 9. l8 9.01 8.93 8.90 9.08 8.96 8.92 8.96 8.95 8.85 8.93 8.91 8.83 8.85 8.95 9.01 8.95 8.89 8.95 8.87 8.97 8.95 8.89 8.93 9.04 8.85 8.95 8.84 8.9',7 8.85 8.91 9.00 8.89 8.95 8.89 8.98 8.89 8.94 9.06 anlffirrce I I, C -I FJ' CA L (: I]O LJ i) Location: HF Sinclair Woods Cross Refinine. LLC - West Bountiful. UT Run3-RMData Source: BoilerNo. l0 Project No.: AST-2023-1660 Date:8123123 Time Unit Or - Outlet COr - Outlel t:"dry %"dry ValidStatus Valid ll:18 ll:19 I l:20 ll:21 ll:22 ll:23 ll:24 ll:25 I l:26 ll:27 I l:28 1t.29 I l:30 ll:31 ll:32 I l:33 I l:34 I l:35 I l:36 ll:37 I l:38 I l:39 I l:40 I l:41 n.42 I l:43 I l:44 I l:45 I l:46 ll:47 I l:48 I l:49 I l:50 I l:51 ll:52 I l:53 I l:54 I l:55 1 l:56 I l:57 I l:58 I l:59 l2:00 l2:01 12:02 l2:03 12:04 l2:05 l2:06 12.07 l2:08 l2:09 12:10 l2:l I 12:12 12:13 12:14 12:15 12:16 12:11 l2:18 l2:19 l2:20 123 of 199 4.59 4.43 4.34 4.53 4.53 4.35 4.13 4.49 4.34 4.33 4.39 4.26 4.38 4.34 4.20 4.41 4.37 4.5't 4.26 4.42 4.39 4.27 4.t I 4.53 4.56 4.44 4.63 4.45 4.45 4.50 4.31 4.06 4.33 4.29 4.34 4.27 4.34 4.43 4.37 4.24 4.29 4.29 4.45 8.86 8.95 8.99 8.90 8.90 8.99 9.07 8.91 8.97 8.98 8.99 9.04 9.00 9.01 9.07 8.99 8.97 8.90 9.04 8.9s 8.92 8.96 9.06 8.86 8.86 8.95 8.88 8.96 8.97 8.93 9.0t 9.14 9.05 9.05 9.04 9.06 9.05 8.99 9.01 9.08 9.05 9.05 8.94 9.07 8.88 9.01 8.9t 8.91 8.97 9.07 8.94 8.88 9.03 8.95 9.04 8.91 9.01 8.95 8.92 8.97 9.05 8.87 8.91 l5 58 3l 54 4.s4 4,44 4.23 4.52 4.60 4.31 4.46 4.30 4.57 4.32 4.46 4.52 4.44 4.25 4.62 4.49 dAllarpe TSCilNiC&L {;fi,i}L' T Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Run3-RMData Source: BoilerNo. l0 Project No.: AST-2023-1660 Datez 823123 Time Unit Status Or - Outlet CO, - Outlet "/" dry "/" dry Valid Valid l2:21 l2:22 l2:23 l2:24 12:25 l2:26 '12:27 12:28 l2:29 l2:30 12.3t l2:32 l2:33 l2:34 l2:35 l2:36 l2:37 l2:38 l2:39 l2:40 t2.41 12:42 12.43 12:44 12:45 l2:46 l2:47 l2:48 12:49 I 2:50 l2:5 I tz.5z t2'.53 12:54 12:55 12:56 12:57 l2:58 12:59 13:00 l3:01 l3:02 l3:03 l3:04 l3:05 l3:06 l3:07 l3:08 l3:09 l3:10 l3:ll l3:12 l3:13 l3:14 l3:15 l3:16 l3:1 7 l3: l8 l3: l9 l3:20 l3:21 13:22 l3:23 124 of 199 4.38 4.45 4.3s 4.48 4.38 4.18 4.36 4.40 4.40 4.36 4.41 4.37 4.36 4.30 4.40 4.61 4.43 4.63 4.65 4.50 4.43 4.52 4.41 4.31 4.20 4.47 4.50 4.37 4.56 4.46 4.34 4.71 4.91 4.70 4.36 4.62 4.48 4.59 4.63 4.58 4.81 4.56 4.72 4.77 4.66 4.45 4.45 4.75 4.55 4.57 4.45 4.55 4.54 4.55 4.33 4.65 4.46 4.46 4.6s 4.67 4.74 4.53 4.72 8.97 8.90 8.97 8.93 8.96 9.06 9.01 8.95 8.98 8.98 8.97 8.97 8.97 9.01 8.97 8.84 8.91 8.84 8.83 8.90 8.94 8.90 8.93 8.98 9.05 8.91 8.90 8.96 8.86 8.91 8.94 8.89 8.89 8.86 8.96 8.82 8.89 8.86 8.85 8.89 8.76 8.90 8.81 8.78 8.82 8.92 8.93 8.79 8.88 8.86 8.94 8.89 8.90 8.90 9.01 8.84 8.91 8.93 8.84 8.8s 8.80 8.91 8.82 #AIiarpEr TrcHhlicAL {}ft*t"Jf3 Locationt Snnma. Roilcr Nn lO Run3-RMData Project No.: AST-2023-1660 Drtet 8/23123 Time Unit Status Or - 0utlet CO. - OutletT.dry "/"dry Valid Valid 13:24 13.25 13:26 l3:27 13:28 13:29 13:30 13:31 13:32 13:33 13:34 l3:35 l3:36 I 3:37 l3:38 l3:39 l3:40 l3:41 l3:42 l3:43 l3:44 l3:45 13:46 13:4'l l3:48 l3:49 I 3:50 l3:51 l3:52 l3:53 I 3:54 13:55 13:56 13:57 l3:58 13:59 14:00 14:01 l4:02 l4:03 l4:04 l4:05 l4:06 l4:07 l4:08 l4:09 l4:10 l4:ll l4:12 I 4:13 l4:14 l4:15 l4: l6 l4l'l l4: l8 l4: l9 14.20 l4:21 t4.22 l4:23 14.24 l4:25 t4'.26 125 of 199 4.72 4.60 4.37 4.51 4.66 4.47 4.63 4.62 4.7 t 4.79 4.83 4.63 4.67 4.62 4.43 4.51 4.35 4.55 4.62 4.45 4.78 4.79 4.56 4.73 4.66 4.43 4.19 4.44 4.5',1 4.44 4.59 4.38 4.62 4.53 4.44 4.69 4.66 4.6t 4.25 4.50 4.66 4.41 4.67 4.39 4.52 4.49 4.45 4.24 4.47 4.45 4.38 4.42 4.45 4.44 4.23 4.7 | 4.53 4.44 4.s4 4.46 4.51 4.47 4.33 8.82 8.87 8.99 8.93 8.83 8.92 8.86 8.93 8.99 8.94 8.87 8.94 8.88 8.85 8.92 8.88 8.96 8.90 8.89 9.0t 8.9t 9. l3 9.45 9.24 8.90 8.96 9.07 8.95 8.88 8.94 8.88 8.91 8.85 8.90 8.96 8.81 8.81 8.84 9.03 8.92 8.84 8.97 8.84 8.97 8.90 8.89 8.90 9.03 8.94 8.93 8.96 8.93 8.93 8.95 9.06 8.80 8.88 8.91 8.87 8.92 8.93 8.91 8.99 aIlmrpe T f * i-.{ l\I 1 CAL G R {) U r} Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Run3-RMData Source: BoilerNo. l0 Project No.: AST-2023-1660 Datet 8123/23 Valid Time Unit Strtus Or - Outlet COr - Outlel %,dry o/odry Valid l4:27 l4:28 l4:29 l4:30 l4:31 l4:32 l4:33 l4:34 l4:35 l4:36 l4:37 l4:38 4.32 4.16 4.49 4.29 4.50 4.24 4.30 4.32 4.28 4.21 4.56 4.39 8.98 9.05 8.91 9.01 8.91 9.01 8.95 8.9't 9.02 9.06 8.88 8.96 Uncorrected Run Average (C.6,) Crl Grs Concentration (Cm) Pretest System ZEro Response Posttest System Zero Response Average Zero Response (Co) Pretest Syst€m Cal Response Posttcst Systcm Cal Response Average Cal Response (Cy) 4.48 10.95 0.08 0.07 0.08 10.93 r0.88 t0.9t 4.45 8.93 t0.74 0.l0 0.01 0.06 t0.77 t0.76 10.7'l 8.90 126 of 199 DrvlstoN oF AtR Ot-r4111y 127 of 199 $3 eurofins Environment Testing ANALYTICAL REPORT PREPARED FOR Attn: Austin Abranovic Alliance Source Testing, LLC 214 Central Circle SW Decatur, Alabama 35603 Generated 101212023 9:03:25AM Revision 1 JOB DESCRIPTION HF Sinclair Woods - CTM-039 JOB NUMBER 140-33466-1 This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager. Eurofins Knoxville is a laboratory within TestAmeica Laboratoies, lnc., a company within Eurofins Environment Testing Group of Companies Page 2 of 34 129 of 199 &*!ar{Ua-1, Generated L-,V I 1ot2t2o23 e:03:25 AM Arth"ri*d f"-"|"r." by Revision 1 Courtney Adkins, Project Manager ll Courtney.Adkins@et.eurofinsus.com (86s)291 -301 I 101212023 (Rev. 1) Client: Alliance Source Testing, LLC ProjecVSite: HF Sinclair Woods - CTM-039 Laboratory Job lD: 140-33466-1 1 3 4 5 7 9 24 25 26 29 30 31 32 Table of Contents Cover Page Table of Contents . . . Definitions/Glossary . . . Case Narrative Detection Summary Client Sample Results Default Detection Limits QC Association Summary Lab Chronicle . Certification Summary . . Method Summary Sample Summary Chain of Custody . . . Eurofins Knoxville 101212023 (Rev. 1)Page 3 of 34 130 of 199 Definitions/Glossary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. q Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, lN lndicates a Dilution, Re-analysis, Re-extraction, or additional lnitial metaldanion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOO Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level" MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive OC Ouality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radaochemistry) RPD Relative Percent Difference, a measure of the relative differen@ between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too NumerousTo Count Eurofins Knoxville Page 4 of 34 101212023 (Rev. 'l ) l3 I of 199 Case Narrative Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Job lD: 140-33466-1 Laboratory : Eurofins Knoxville Narrative a ']r....,l.Job Narrative 140-33466-1 Revision Notes This report was revised to include initial sample volumes. Receipt The samples were received on 911212023 9:30 AM. Unless otheruvise noted below, the samples arrived in good condition, and where required, properly preserved and on ice. The temperature of the cooler at receipt was 2'l .9o C. Receipt Exceptions The Field Sampler was not listed on the Chain of Custody. The Chain-of-Custody (COC) was incomplete as received and/or improperly completed. Sample matrix not listed. General Ghemistry Particulate Matter by CTM-O3g-Particulate Matter was determined for samples derived from Conditional Test Method 039 sampling trains. The filter samples were dried in a desiccator over anhydrous calcium sulfate for a minimum of 24 hours. Acetone rinses were evaporated in TeflonrM beaker liners in a hood at ambient temperature instead of aluminum pans in order to avoid possible reactions between acidic stack contents and the aluminum pans. The aqueous impinger catch was simmered to less than 10 mL, and then evaporated to dryness in an unheated forced draft oven. Data are reported to 0.01 mg as specified in the cited method. The reporting limit was lowered to the readability of the balance used (0.01 mg). Method CTM 039: A deviation from the Standard Operating Procedure (SOP) occurred. Details are as follows: Beaker liners were weighed three times and the average of all three was used as the liner tare weight per PM and consultant request. Method CTM 039: Samples BOILER 10 - <PM2.5 FILTER - 142MM - RUN 1 (140-33466-5) did not achieve constant weight as described in SOP KNOX-WC-0006 section 11.12.6 the last two gross weights were averaged and used as final sample weight. Method CTM 039: Sample BOILER 1 0 - <PM2.5 Dl WATER RINSE - RUN 3 (140-33466-1 3)did not reach constant weight as described in the SOP KNOX-WC-0006 section 11 .12.6. The three gross weights were averaged and used as final sample weight. Method CTM 039: Samples BOILER 10 - <PM2.5 FILTER - 142MM - RUN 2 (140-33466-10) and BOILER 10 - <PM2.5 FILTER - 142MM - RUN 3 (140-33466-15) arrived with significant damage to the filters (tares, frayed edges, missing pieces). The analyst was careful to get all loose filter pieces weighed with the sample. However the damage may reflect a low bias in the data. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Page 5 of 34 132 of 199 Eurofins Knoxville 1012t2023 (Rev. 1) Job 140-33466: Sample Volumes Sample lD Volume (mL) 140-33466-A-1 87.4 L40-33466-A-2 55.8 140-33466-A-3 r93.4 140-33456-A4 225.3 t40-33466-4-6 7t.o L40-33456-A-7 86.8 140-33466-A-8 185.9 140-33466-A-9 191.1 140-33466-A-11 95.9 140-33466-A-12 32.5 140-33465-A-13 L76.L 140-33465-A-14 20L.2 tr Page 6 of 34 133 of 199 101212023 (Rev. 1) Detection Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN ,l Lab Sample lD: 140-33466-1 I lnatyte I Prrti""l'rt"{/att* Result Qualifier RL MDL Unit 0.575 0.0100 0.0100 mg/sample Dil Fac D Method Prep Type Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - RUN 1 Lab Sample lD: 140-33466-2 I Analyte Particulate MatterL Result Qualifier RL MDL Unit 0.440 Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample 1 CTM 039 Total/NA Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN 1 Lab Sample lD: 140-33466-3 An?brte Particulate Matter I Result Qualifier RL MDL Unit 1.81 0.0100 0.0100 mg/sample Dil Fac D Method Prep Type 1 CTM 039 Client Sample !D: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 1 Lab Sample lD: 140-33466-4 I lnatyte I eartiarr'ate f*atter Result Oualifier RL MDL 2.48 0.0100 0.0100 Dil Fac D Method Prep Type mg/sample 1 CTM 039 TotaUNA Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 1 Lab Sample lD: 140-33466-5 Analyte Result Qualifier RL MDL Unit 0.910 0.0100 0.0100 mg/sample Dil Fac D Method Prep Type Particulate Matter CIient Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN 2 Lab Sample lD: 140-33466-6 Analyte Result Qualifier RL MDL Unit 0.265 Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample 1 CTM 039 Total/NAParticulate Matter Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - RUN 2 Lab Sample lD: 140-33466-7 I enatyte I eat^,ht" rrl"tt. Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN 2 Lab Sample lD: 140-33466-8 Result Qualifier RL MDL Unit Dil Fac D Method Prep Type 0.0'100 0.0'100 mg/sample 1 CTM 039 Total/NAParticulate Matter 1.13 Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 2 Lab Sample lD: 140-33466-9 Result Qualifier MDL Unit Dil Fac D 1- Prep Type ,Particulate Matter 1 .39 0.0100 Page 7 of 34 134 of 199 Eurofins Knoxville 101212023 (Rev. 1) This Detection Summary does not include radiochemical test results. 0.0100 mg/sample cTM 039 Detection Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 2 Lab Sample lD: 140-33466-10 Analyte Pa rti.'rJlate tv!atterL Result Qualifier RL MDL Unit 1.07 Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample 1 CTM 039 Total/NA Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN 3 Lab Sample lD: 140-33466-11 t-Analyte Partic'rrlate fu!atterL Result QualifierQualifier RL MDL Unit 0.530 0.0100 0.0100 mg/sample Dil Fac D Method Prep Type Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - RUN 3 Lab Sample lD: 140-33466-12 Result Qualifier RL MDL Unit 0.0400 Dil Fac D Method Prep Type 0.0100 0.0100 mg/sampleParticulate Matter Client Sample !D: BOILER 10 - <PM2.5 DIWATER RINSE - RUN 3 Lab Sample !D: 140-33466-13 I I Analyte I Particulate Matter t Result Qualifier RL MDL Unit 1.56 Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample I CTM 039 Total/NA Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 3 Lab Sample lD: 140-33466-14 Analyte Particulate Matter L-_ Result Qualifier RL MDL Unit 1.24 Dil Fac D Method Prep Type 0.0100 0.0100 mg/sample Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 3 Lab Sample lD: 140-33466-15 Analyte Result Qualifier MDL Unit Dil Fac D Method Prep Type Total/NA Eurofins Knoxville 101212023 (Rev. 1) Particulate Matter 1.07 0.0100 0.0100 mg/sample cTM 039 Page 8 of 34 135 of 199 This Detection Summary does not include radiochemical test results Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Client Sample lD: BOILER 10 - >PMl0 ACETONE RINSE - RUN Lab Sample lD: {40-33466-1 1 Date Collected: 08122123 00:00 Date Received: 09/1223 09:30 Sample Container: Clear Glass 500mL - unpreserved Matrix: Air .,,.., : . . Job lD: 140-33466-1 GeneralChemistry Analyte Partlculate Matter (EPA CTM 039) 0.575 0.0100 0.0100 mg/sample R$ult Qualifier RL illDL Unit D Prepared Analyzed Dil Fac O9l2Ol23 10:23 1 &p4W 1F1H' tr Page 9 of 34 136 of 199 Eurofins Knoxville 101212023 (Rev.1) Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - RUN 1 Date Col lected: 08 I 221 23 O0 :O0 Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample lD: 140-33466-2 Matrix: Air Result Qualifier MDL Unit D Prepared Analyzed Dil Fac Ogl2ol23 10:23 10.0100 0.0100 mg/sample Page 10 of34 137 of 199 Eurofins Knoxville 1Ol2l2O23 (Rev. 1) Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Client Sample ID: BOILER 10 - <PM2.5 DIWATER RINSE - RUN Lab Sample lD: 140-33466-3 1 Date Gollected: 08122123 00:OO Date Receive d: 091 12123 09:30 Sample Container: Clear Glass 500mL - unpreserved Matrix: Air Job lD: 140-33466-1 GeneralChemistry Analyte Partlculato Matter (EPA CTM 039) 1.81 Result Qualifier RL MDL Unit D Prspared Analyzed Dll Fac 0.0100 0.0100 mg/sample Ogl2ol23 10:23 I "ffiwsMtr Page 11 of34 138 of 199 Eurofins Knoxville 101212023 (Rev. 1) Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 GIient Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN Lab Sample lD: 140-334664 1 Date Collected:. 08122123 O0:O0 Date Received: 09/1 2/23 09:30 Samole Container: Clear Glass 500mL - unpreserved Matrix: Air ,.]||i"tgl Job lD: 140-33466-1 Genera! Chemistry Analyte Partaculate MattEr (EPA CTM 039) 2.4A Result Quallfler RL MDL Unlt D Preparod Analyzed Dil Fac ffiffi 1lXt.t lltfei#! tr0.0100 0.0100 mg/sample Agl2Al23 1Oi23 1 Eurofins Knoxville Page 12 of 34 141212023 (Rev.'t) 139 of 199 CIient Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 1 Date Collected: 08/22123 00:00 Date Received: 09/12123 09:30 Sample Container: Petri/Filter Lab Sample lD: 140-33466-5 Matrix: Air General Chemistry Analyte Result Qualifier D Prepared Analyzed Ogl2ol23 10:23 MDL Unit Dil Fac Particulate Matter (EPA CTM 039)0.0100 0.0100 mg/sample Eurofins Knoxville 101212023 (Rev. 1)Page 13 of34 140 of 199 Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN 2 Date Collected: 08/22123 00:00 Date Received: 09/12123 09:30 Sample Container: Glear Glass 500mL - unpreserved Lab Sample lD: 140-33466-6 Matrix: Air General Chemistry Analyte Result Qualifier D Prepared Analyzed Ogl2ol23 10:23 MDL Unit Dil Fac Particulato Matter (EPA CTM 039)0.0100 0.0100 mg/sample Eurofins Knoxville 101212023 (Rev. 1)Page 14 of34 14l of 199 Glient Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - Lab Sample lD: 140-33466-7 RUN 2 Date Collected: 08/22123 00:00 Matrix: Air Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved Job lD: 140-33466-1 General Chemistry Analyte Particulate Matter (EPA CTM 039) 0.445 Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 0.0100 0.0100 mg/sample O9l2Ol23 10:23 1 Page 15 of34 142 of 199 Eurofins Knoxville 101212023 (Rev. 1) Client Sample Results Client: Alliance Source Testing, LLC ProjecUsite: HF Sinclair Woods - CTM-039 Client Sample !D: BOILER {0 - <PM2.5 DIWATER RINSE - RUN Lab Sample lD: 140-33466-8 2 Date Collected: 08122123 00:.00 Date Received: 0911?23 09:30 Sample Container: Clear Glass 500mL - unpreserved Matrix: Air T I GeneralChemistry I Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac ':;r, irrlrrf Job lD: 140-33466-1 $ry "*& :d;.n{& tr Page 16 of 34 143 of 199 Eurofihs Knoxville 101212023 (Rev.1) Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF SinclairWoods - CTM-039 Job lD: 140-33466-1 CIient Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 2 Date Col lected: 08 I 221 23 00:00 Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample !D: 140-33466-9 Matrix: Air General Chemistry Analyte Result Qualifier MDL Unit D Prepared Particulate Mafter (EPA CTM 039)0.0100 0.0100 mg/sample Analyzed Ogl2ol23 10:23 Dil Fac Page 17 of34 144 of 199 Eurofins Knoxville 101212023 (Rev. 1) Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 2 Date Co! lected: 081221 23 00 :00 Date Received: 09/12123 09:30 Sample Container: Petri/Filter Lab Sample lD: 140-33466-10 Matrix: Air Result Qualifier MDL Unit D Prepared 1.07 0.0'100 0.0100 mg/sample Analyzed Dil Fac Ogl2il23 10:23 1 Eurofins Knoxville '101212023 (Rev. 1)Page 18 of34 145 of 199 Client Sample Results ;:{t 'ft Job lD: 140-33466-1 w:ffi ffiffiu Client: Alliance Source Testing, LLC ProjecUSite: HF SinclairWoods - CTM-039 Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN Lab Sample lD: 140-33466-11 3 Date Gollected: 08/23/23 00:00 Matrix: Air Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved GeneralChemistry Analyte Partlculate Matter (EPA CTM 039) 0.530 0.0100 0.0100 mg/sarnple Ogl20l23 10i23 1 Eurofins Knoxville 1Ol2l2A23 (Rev. 1) Result Qualifier RL ftttDL Unit D Prepared Analyzed Dil Fac Page 19 of34 146 of 199 Client Sample Results Client Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - Lab Sample lD: 140-33466-12 RUN 3 Date Collected: 08/23/23 00:00 Matrix: Air Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved t" I GeneralChemistry I enaryte Result Qualifier RL MDL Unit D Prepared Analyzed Oil Fac Job lD: 140-33466-1 ffi tr Page 20 of 34 147 of 199 Eurofins Knoxville 101212023 (Rev. 1) GIient Sample Results Client: Alliance Source Testing, LLC Project/Site: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN 3 Date Collected: 08/23123 00:00 Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample lD: 140-33466-13 Matrix: Air Result 156 MDL Unit D Prepared Analyzed Ogl2ol23 10:23 Dil Fac s-s;l fi,*ffal#|) tr0.0100 0.0100 mg/sample Page 21 of34 148 of 199 Eurofins Knoxville 1012t2023 (Rev. 1) Glient Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 3 Date Collected: 08/23123 00:00 Date Received: 09/12123 09:30 Sample Container: Clear Glass 500mL - unpreserved Lab Sample lD: 140-33466-14 Matrix: Air General Ghemistry Analyte Particulate Matter (EPA CTM 039) Result Qualifier MDL Unlt D Prepared Analyzed Dil Fac 1 i(,rilr tr**0.0100 0.0100 mg/sample Ogl2ol23 10:23 Eurofins Knoxville 101212023 (Rev. 1)Page 22 of 34 149 of 199 Client Sample Results Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample !D: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 3 Date Collected: 08/23123 00:00 Date Received: 09/12123 09:30 Sample Container: Petri/Filter Lab Sample lD: 140-33466-15 Matrix: Air General Chemistry Analyte Result Oualifier MDL Unit D Prepared Analyzed Dil Fac Particulate Matter (EPA CTM 039)0.0100 0.0100 mg/sample Ogl2ol23 1O:23 Eurofins Knoxville 101212023 (Rev. 1)Page 23 of 34 150 of 199 Default Deteetion Limits tt': ';i"i:':,::.1{ aitr\ Job lD: 140-33466-1Client: Alliance Source Testing, LLC ProjecUsite: HF Sinclair Woods - CTM{39 General Ghemistry l'nnatyte I FertiEGParticulate Matter RL MDL Unlts 0.0100 0.0100 mg/sample Page 24 of34 151 of 199 Eurofins Knsxville 10ru2023 (Rev. 1) QC Association Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 General Chemistry Analysis Batch:77958 Lab Sample lD 140-33466-1 140-33466-2 140-33466-3 140-33466-4 140-33466-5 140-33466-6 't40-33466-7 't40-33466-8 140-33466-9 140-33466-1 0 1 40-33466-1 1 140-33466-12 140-33466-1 3 140-33466-14 140-33466-1 5 Client Sample lD BOILER 10. PM1O.PM2.5 ACETONE RINSE - R BOILER 1O - <PM2.5 DI WATER RINSE. RUN 1 BOILER 10. <PM2.5 ACETONE RINSE . RUN 1 BOILER .IO - <PM2.5 FILTER. 142MM . RUN 1 BOILER 1O - >PM1O ACETONE RINSE - RUN 2 BOILER 1O - PMlO-PM2.5 ACETONE RINSE - R BOILER ,IO - <PM2.5 DI WATER RINSE. RUN 2 BOILER 1O - <PM2.5 ACETONE RINSE - RUN 2 BOILER 1O - <PM2.5 FILTER - 142MM . RUN 2 BOILER 1O - >PM1O ACETONE RINSE . RUN 3 BOILER 1O - PMlO-PM2.5 ACETONE RINSE - R BOILER 1O - <PM2.5 DI WATER RINSE - RUN 3 BOILER 1O - <PM2.5 ACETONE RINSE - RUN 3 BOILER 10. <PM2.5 FILTER - 142MM - RUN 3 Prep Type Matrix Total/NA Air Total/NA TotaYNA Total/NA TotaUNA Total/NA Total/NA Total/NA TotaYNA Total/NA Total/NA Total/NA Total/NA Total/NA Total/NA Air Air Air Air Air Air Air Air Air Air Air Air Air Air Method Cnvl 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 cTM 039 CTM 039 Prep Batch Eurofins Knoxville 101212023 (Rev. 1)Page 25 of 34 152 of 199 Lab Chronicle Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - >PMI0 ACETONE RINSE - RUN 1 Date Collected: O8122123 O0:O0 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-1 Matrix: Air | ,,"o rro" L..n- Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Amount Batch Prepared Number or Analyzed Analyst Lab 1 77958 Ogl2ol2310:23 SJF EET KNX Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - RUN 1 Date Collected: 081 22123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-2 Matrix: Air I ,,"r rro" ] ".n- Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Dit Factor lnitial Amount Final Batch Prepared Amount Number orAnalyzed Ogl2Ol23 1O:23 Analyst SJF EET KNX Client Sample lD: BOILER 10 - <PM2.5 Dl WATER RINSE - RUN 1 Date Collected: 08122123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-3 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Dil lnitial Factor Amount Final Amount Batch Prepared Number or Analyzed Analyst Lab 1 77958 Ogl21l2310:23 SJF EET KNX Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 1 Date Collected: 08122123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-4 Matrix: Air | ","o rro" tT* Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Amount Batch Prepared Number or Analyzed Analyst Lab O9l2Ol23 10:23 SJF EET KNX1 Client Sample ID: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 1 Date Collected:. OBl22l23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-5 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Ogl2ol23 10:23 Analyst SJF1 Page 26 of 34 153 of 199 EET KNX Eurofins Knoxville 101212023 (Rev. 1) Lab Chronicle Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN 2 Date Collected: OBl22l23 0O:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-6 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Analyst 09120123 10:23 SJFI EET KNX Client Sample lD: BOILER 10 - PM10-PM2.5 ACETONE RINSE - RUN 2 Date Collected: 08122123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-7 Matrix: Air I ,,"o t o" I ..r..Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Oil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Ogl2ol23 1O:23 Analyst Lab EET KNX Client Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN 2 Date Collected: 08122123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33465-8 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEOUIP Dil lnitial Factor Amount Final Batch Prepared Amount Number orAnalyzed 1 Analyst Lab Ogl2ol23 10:23 SJF EET KNX Client Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 2 Date Gollected: 08122123 00:00 Date Received: 09/12123 09:30 Lab Sample !D: 140-33466-9 Matrix: Air [ ,."o rro" lr""r* Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Prepared Amount Number orAnalyzed I Analyst Lab Ogl2ol23 10:23 SJF EET KNX Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 2 Date Collected: 08122123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-10 Matrix: Air Batch Batch Prep Type Type Method Totaul.lA Analysrs Cnvt 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Prepared Amount Number or Analyzed Analyst Lab Ogl2ol23 10:23 SJF EET KNX Eurofins Knoxville 101212023 (Rev. 1)Page 27 of 34 154 of 199 Lab Ghronicle Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: '140-33466-1 Client Sample lD: BOILER 10 - >PM10 ACETONE RINSE - RUN 3 Date Collected: 08/23/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-11 Matrix: Air | ,."o rro" ] .rn-Type Method Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed Analyst Ogl2ol2310:23 SJF EET KNXAnalysis CTM 039 lnstrument lD: NOEOUIP Client Sample lD: BOILER '10 - PM10-PM2.5 ACETONE RINSE - RUN 3 Date Collected: 08/23123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-12 Matrix: Air I ,."r rro" Total/t,lA Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dit Factor lnitial Final Batch Amount Amount Number Prepared or Analyzed Ogl21l23 10:23 Analyst Lab I EET KNX CIient Sample lD: BOILER 10 - <PM2.5 DIWATER RINSE - RUN 3 Date Collected: 08/23/23 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-13 Matrix: Air Prep Type Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Amount Batch Prepared Number or Analyzed Analyst Lab Ogl20l23 10:23 SJF EET KNX1 CIient Sample lD: BOILER 10 - <PM2.5 ACETONE RINSE - RUN 3 Date Collected: 08/23123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33465-14 Matrix: Air Final Batch Prepared Run Factor Amount Amount Number orAnalyzed Analyst 77958 Ogl21t23 10:23 SJF EET KNX Client Sample lD: BOILER 10 - <PM2.5 FILTER - 142MM - RUN 3 Date Collected: 08/23123 00:00 Date Received: 09/12123 09:30 Lab Sample lD: 140-33466-15 Matrix: Air Prep Type l".r-- Batch Batch Type Method Analysis CTM 039 lnstrument lD: NOEQUIP Dil lnitial Factor Amount Final Batch Amount Number Prepared or Analyzed ogl2ol23 1O:23 Analyst Lab EET KNX Eurofins Knoxville 101212023 (Rev. 1) Laboratory References: EET KNX = Eurofins Knoxville, 581 5 Middlebrook Pike, Knoxville, TN 37921 , TEL (865)291-3000 Page 28 of 34 l55ofl99 Accreditation/Certification Sum mary Client: Alliance Source Testing, LLC POecUSite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 La boratory: Eurofins Knoxville All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Proqram ldentificationNumber ExpirationDate ANAB ANAB ANAB Arkansas DEO Colorado Connecticut Florida Georgia (DW Hawaii Kansas Kentucky (DW Louisiana (All) Louisiana (DW Maryland Michigan Nevada New Hampshire New Jersey New York North Carolina (DW) North Carolina (\ M//SW Oklahoma Oregon Pennsylvania Tennessee Texas US Fish & \A/ildlife USDA Utah Mrginia Washington West Virginia (DvV) West Varginia DEP _Wsconsin AFCEE Dept. of Defense ELAP Dept. of Energy tso/rEc 17025 State State State NELAP State State NELAP State NELAP State State State State NELAP NELAP NELAP State State State NELAP NETAP State NELAP US Federal Programs US Federal Programs NELAP NELAP State State State State N/A L2311 L2311.01 L2311 88-0688 TN00009 PH4223 E87177 906 NA E-10349 901 01 83979 LAO19 277 9933 TN00009 2999 TNOOl 10781 21705 64 941 5 TNl0189 68-00576 02014 Tl 04704380-23-1 8 058448 s25-22-279-18762 TN00009 460176 c593 9955C 345 998044300 02-13-25 o2-13-25 o2-13-25 06-16-24 02-29-24 09-30-23 06-30-24 07-27-25 07-27-24 10-31-23 12-31-23 06-30-24 12-31-23 o3-31-24 07-27-25 07-31-24 o1-17-24 07-01-24 03-31-24 07-31-24 12-31-23 12-31-23 o1-01-24 12-01-23 07-27-25 08-31-24 07-31-24 1 0-06-25 07-31-24 o9-14-24 o1-19-24 12-31-23 o4-30-24 08-31-24 Page 29 of 34 156 of 199 Eurofins Knoxville 10t212o23 (Rev. 1) Method Summary Glient Alliance Sourqe Testing, LLC ProjeeUsite: HF Sinclair Woods - CTM-039 Job lD: 140-33466-1 iiethod Meihod Detcrlptlon CTM 039 ParticulaGs Protcol Refercnees: EPA = US Envirqnmentat Protection Agency Laboratiory References: EET KNX = Eurofins Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 Protocol LaboratoryEm- EETr.ttx Eurotins Knoxville Page 30 of 34 1012DA23 (Rev. 1) 157 of199 *ilslla Sample Summary Client: Alliance Source Testing, LLC ProjecUSite: HF Sinclair Woods - CTM-039 Job lD: '140-33466-1 Lab Sample lD 140-33466r 1 40-33466-2 1 40-33466-3 140-33466-4 140-33466-5 140-33466-6 140-33466-7 140-33466-8 140-33466-9 140-33466-1 o 140-33466-11 1 40-33466-1 2 1 40-33466-1 3 140-33466-14 140-33466-1 5 Client Sample lD Matrix Collected Received BOILER .10 . >PM1O ACETONE RINSE - RUN 1 BOILER 1O - PMlO-PM2.5 ACETONE RINSE . RUN 1 BOILER 1O - <PM2.5 DI WATER RINSE - RUN 1 BOILER 1O - <PM2.5 ACETONE RINSE. RUN 1 BOILER 1O - <PM2.5 FILTER. 142MM . RUN 1 BOILER 1O - >PM1O ACETONE RINSE . RUN 2 BOILER 1O . PM1O,PM2.5 ACETONE RINSE - RUN 2 BOILER 1O - <PM2.5 DI WATER RINSE. RUN 2 BOILER 1O - <PM2.5 ACETONE RINSE. RUN 2 BOILER 1O - <PM2.5 FILTER - 142MM - RUN 2 BOILER 1O - >PMlO ACETONE RINSE - RUN 3 BOILER 1O - PMlO-PM2.5 ACETONE RINSE . RUN 3 BOILER 10. <PM2.5 DI WATER RINSE - RUN 3 BOILER 1O - <PM2.5 ACETONE RINSE. RUN 3 BOILER 1O - <PM2.5 FILTER. 142MM. RUN 3 Air Air 08122123 OO:OO 08122123 OOIO0 O8122123 OO:OO 08122123 OO:OO 08122123 00:00 OAl22l23 OO:OO OBl22l23 OO:OO OAl22l23 OO:OO ogl22l23 00100 OAl22123 O0:OO 08123123 O0:O0 08123123 00:00 OBl23l23 O0:OO OAl23l23 00:00 08123123 00:00 Ogl12l23 09:30 Ogl12123 09:30 Ogl12l23 09:30 Ogl12l23 09:30 Ogl1Z23 09:30 Ogl12123 09:30 Ogl12123 09:30 Ogl12123 09:30 Ogl12123 09:30 Ogl12123 09:30 Ogl12123 O9t3O Ogl12123 09:30 O9112123 09:30 Ogl12123 09:30 Ogl12123 09:30 Air Air Air Air Air Air Air Air Air Air Air Air Air Page 31 of34 158 of 199 Eurofins Knoxville 101212023 (Rev. 1) FoNEoG!I{totNooJ+C)odz=oL E qi 8I E E '= I 3 X OI E N El s : f; l l iU2oDs4Deztr=otrEGEoo- !,LoooE!toooo.g(Eo oE1 os o >! Q x* E cl s x o6 - o 6 r oi SB €E E: 9€ =R i EE gH 6G ts PE €€ IIII -l EIol3lol :lslotol@I SI otql ol$l-l >o6s €EEE LA<! tL o -9EEo!E= gE o-,qEo6oto@tooo@=o-UJc6p)o6oILGo63 iEg - . - E9 9 S e EN i d { EeFF tr t r o u 10 1 2 1 2 0 2 3 (R e v . 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'6 90 o, =9E3E o. o e9ef r o> f9 , .d g 6.oo6tEo:Booooos6o9)ot. . roooooo69= -0 6 0. e €. - sr o i i o -? *c a [i ,- o 9\ o . E e ^i ! i5 J6 €' o\ooEo6EO \oLoo\ c. .EoEpA.c i .Eo6oe(Eoo.EBhe. r (0 9( 9 -$ ii c. ) 3( f ) o\F- c{ \ooo6i \oc. l q)za0 IFa,lOEUJ2zFOiUrizp.DzFazUFFiUHE] -]2U) ldJtlXzQk]Fthtr : (Dz&ri 10 1 2 1 2 0 2 3 (R e v . 1) Pa g e 3 4 o f 3 4 162 of 199 NAliarrce TL[;II Ni{:AI. {]NC}U2 Ifistion HF Sinclsir Woods Crosi Refining' LLC - Wst Bounaiful, UT QA/QC Data Source Boiler No. l0 Project No. AST-20211560 Prrrmeter PM (CTM-039) Drte Nozle ID Nozzle lriometer (in.) lll #2 #3 Dn (Avcrace) Dilfercnce Criteria 8t22t23 al22/23 N20lA-3 N20lA-5 0.240 0.260 0.240 0.260 0.240 0.260 0.240 0.260 0.000 0.000 3 0.004 in D.te Pitot ID Evidcnce of Evidence of LrllDrtoon or Ranrir reouired? 8t22/23 P-761 no no no Drte Probe ID Rcfercrce Indicrted Dilference Criteri. an2l23 P-761 92.0 92.0 0.oyo 1.5 % (absolute) Date Barometric Pr6sure Evidetrcc of Rcading Vcrified LrttDranotr or Reorir reouired? 8t22123 weather Station NA NA NA 163 of 199 dmAlialpe TtCllN:CAL *11 C, lii, QA Data Location HF Sinclair Woods Cross Refining. LLC - West Bountiful, UT Source Boiler No. l0 Project No. AST-2023-1660 Parameter(s) Moisture Field Balance Check Date 08t22t23 Balance ID:5A2881026 Test Weight ID:slc- 1 ks-3 Certified Weight (g):1000.0 Measured Weight (g):999.9 Weight Difference (g):0.1 Date Barometric Pressrr re Evidence of Reading Verified Celibretion or Renair reouired?Weflther Station Locetion 8/22/23 Weather Station NA NA NA West Bountiful, UT Date Meter Box ID Positive Pressure Leak Check 8t22/23 MB-704 Pass t64 of 199 DGM Calibration-Orifices Doaument lI 620 004 Revisior 23.0 Effective Dat(1/25/23 lssuing Departmenl Tech Setuices Paq(lofl Equipment Detail - Dry Gas Meter Console lD: N.48-704 N,4eter S/N: 18392989 Critical Orifice S/N: 1330 Calibration Detail lnitial Barometric Pressure, in. Hg (Pb) Final Barometric Pressure, in. Hg (PbF) Averaqe Barometric Pressure, in. Hq (Pb) 25 45 25 48 25 47 Critifcal Orifice lD (Y) K'Factor, ft3 R"2 / in. wC min (K) Vacuum Pressure, in. Hg (Vp) lnitial DGM volume, ftr (Vml) Final DGM Volume, ft3 CVm, Tntel f.)Gh,l \/nL rma ft'3 fvm\ 1330-31 0.8429 13.0 753 100 769.643 16 543 '1330-31 1330-25 0 6728 15.0 782.800 796.038 13.238 1330-25 133019 0.5186 16.0 806.000 816.437 10.437 1330-19 08429 0.673 0.519 13.0 769.643 780.710 11.067 15.0 796.038 804.888 8.850 160 816 783 823.493 6.710 Ambient Temperature, 'F [ta) lnitial Dctvl Temperature,'F (Tmr) Final DGM Temperature, 'F (Imr) Averaoe DGM Temperature, 'F ( Tm) 72 73 74 74 72 74 75 75 73 74 74 74 73 74 75 75 74 15 75 75 75 75 75 Elapsed Time (O) Meter Orifice Pressure, in. WC (AH) Standard Meter volume, ft3 lvmstd) Standard Critical Orifice Volume, ft3 (Vcr) Meter Correction Factor (Y) Tolerance Orifice Calibration Value (AH @) Tolerance Orifice Cal Check 15.00 340 14.0740 13 9631 0 992 0.000 1.878 0 018 10.00 3.40 9.3976 9.3087 0.991 0.001 1 874 0.014 15 00 2.10 11.2099 i1 1348 0.993 0.001 1.815 0.044 10.00 210 7 4871 7 4232 0.991 0.000 1.814 0.046 15.00 1.30 8.8012 8.5148 0.974 0 018 1.887 0 027 10 00 1.30 5.6584 5.7112 1 009 0.017 1.891 0.031 0.11 0.11 0.06 Meter Correction Factor m 0992 Orifice Calibration Value (AH @)1.860 Positive Pressure Leak Check Yes Equioment Detail - Thermocouple Sensor Reference Calibrator Make: OMEGA Reference Calibrator l'/odel: CL23A Reference Calibrator S/N: T{97207 Calibration Detail Reference Temp Display Temp.Accuracy Difference r %OF 0 68 '100 460 528 550 0 66 98 460 526 558 0.0 0.4 0.4 0 2 2 223 248 273 683 708 733 223 248 274 683 708 734 0.0 00 -0.1 0 0 1 300 400 500 600 700 800 900 1,000 1,100 1,200 760 860 960 1,060 1,160 1,260 1,360 1,4ffi 1,560 1.660 300 399 498 600 702 801 901 1,002 1,102 1,202 760 859 958 1,060 1,162 1,261 1,361 1,462 1,562 1,662 0.0 0.1 0.2 0.0 -0.2 -0.1 -01 -0 1 -01 -0.1 0 1 2 0 2 ,1 1 2 2 2 Personnel Stacey Cunninqham 165 of 199 Calibration By: Calibration Date: Reviewed By: RYAN LYONS 6/20/2023 lrlIffirpED TEC i".,I }.t i{],q L G R OU 3 QA Data Location HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source BoilerNo. l0 Project No. AST-2023-l 660 Parameter Oz - Outlet COz - Outlet Make SERVOMEX SERVOMEX Model 1440 1440 s/N 14200t3279 14150/3279 Ooeratins Ranee 0-25 0-25 Cylinder ID 7*ro Low Mid Hioh NA NA EB0078899 SG9I64824BAL NA NA EB0078899 SG9I64824BAL Cylinder Certifed Values Zero Low Mid Hish NA NA 10.95 24.58 NA NA t0.7 4 23.78 Cylinder Expiration Date Zero Low Mid Hish NA NA 7n3129 2n313t NA NA 7^3t29 2^3t31 166 of 199 Rlrffi]Ee TE{:H\iCAL {::NCUP Response Times Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: BoilerNo. l0 Project No.: AST-2023-1660 Times, seconds Parameter 0z - Outlet COr - Outlet Zero Low Mid Hish 30 NA 30 30 30 NA 30 30 Averase 30.0 30.0 167 of 199 RlIffirpe"i"IOillJ]CAL SROUP Calibration Data Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: BoilerNo. l0 Project No.: AST-2023-1660 Date:8122123 Parameter O, - Outlet COz - Outlet Exnected Averase Concentration 8.00 8.00 Span Between Low High Desired Soan 8.00 40.00 24.58 12.00 60.00 23.78 Low Range Gas Low Hish NA NA NA NA Mid Range Gas Low Hiph 9.83 14.75 9.51 t4.27 High Range Gas Low Hiph NA NA NA NA Actual Concentration (% or ppm) Zero Low Mid Hish 0.00 NA 10.97 24.58 0.00 NA 10.80 23.'78 Response Time (seconds)30.00 30.00 Upscale Calibration Gas (Cro)Mid Mid Instrument Response (% or ppm) Zero Low Mid Hish 0.07 NA I 1.03 24.65 0.01 NA r 0.93 23.88 Performance (7o of Span or Cal. Gas Conc.) Zero Low Mid Hish 0.28 NA 0.24 0.28 0.04 NA 0.55 0.42 Performance Criteria Zero Low Mid Hish 2.00 NA 2.00 2.00 2.00 NA 2.00 2.00 Status Zero Low Mid Hish PASS NA PASS PASS PASS NA PASS PASS 168 of 199 pulffirpe TgC]{\']:CAL GHOUP Calibration Data Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: BoilerNo. l0 Project No.: A!T.lQ2l:&{q Date: 8/23/23 Parameter Or - Outlet COz - Outlet Exoected Average Concentration 4.48 9. l5 Span Between Low High Desired Span 4.48 22.39 24.58 9. l5 45.77 23.78 Low Range Gas Low Hish NA NA NA NA Mid Range Gas Low Hish 9.83 14.75 9.5 r 14.27 High Range Gas Low Hish NA NA NA NA Actual Concentration (% or ppm) Zero Low Mid Hish 0.00 NA 10.95 24.58 0.00 NA 10.74 23.78 Upscale Calibration Gas (Cy1)Mid Mid Instrument Response (% or ppm) Zero Low Mid Hieh 0.05 NA I l.0l 24.63 0.02 NA 10.87 23.77 Performance (% of Span or Cal. Gas Conc.) Zero Low Mid Hish 0.20 NA 0.24 0.20 0.08 NA 0.55 0.04 Zero Low Mid Hieh PASS NA PASS PASS PASS NA PASS PASS 169 of 199 dAliarpe l-ECi-'{NICAL [}!:t*UP Bias/Drift Determinations Lo.ation, Source: BoilerNo. l0 Project No.: AST-2023- 1660 Parametcr O, - Outlet CO, - Outlel Run I Dete 8n423 ipan Value nitial Instrument Zero Cal Response .nitial Instrument Upscale Cal Response lretest System Zero Response )osttest System Zero Response Jretest System Upscale Response )osttest Svstem I Jnscale Resnonse 24.6 0.1 l l.0 0l 0.1 l 1.0 1 1.0 23.8 0.0 10.9 0.0 0.0 108 108 )ias (%) )retest Zero losttest Zero )retest Span )osffest Snan 0.1 00 -0.2 -03 00 0.0 -06 -0.7 )rift(%\ lero \4id -0.1 00 0.0 -0 1 Run 2 Date 8122/23 ipan Value .nstrument Zero Cal Response .nstrument Upscale Cal Response Jretest System Zero Response )osttest System Zero Response )retest System Upscale Response )osttest Svstem I Inscale Resnonse 24.6 0l I 1.0 0.1 0. I I1.0 10.9 238 00 10.9 00 0.t 10.8 10.8 Sias (%) lretest Zero losttest Zero ?retest Span )osttest Snan 0.0 0.0 -0.3 -0.4 0.0 0.3 -u. / -0.7 Drift(%) Zero Mid 0.0 -0.2 0.2 0.0 Run 3 Date Ann3 Span Value lnstrument Zero Cal Response lnstrument Upscale Cal Response Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest System Uoscale Response 24.6 0.1 I 1.0 0.1 0.1 10.9 109 23.8 0.0 10.9 0.1 00 10.8 10.8 Bias (%) Pretest Zero Posttest Zero Pretest Span Posttest Snan 0.1 0.1 -0.3 -0.5 03 0.0 -0.4 -05 Drift(%) Zero Mid 0.0 _nl -0.4 0.0 170 of 199 &irwe$ an Air Uquide company Airgas Specialty Gases Airgas USA LIC S2S North Industrial loop Road Tooele, UT8+o74 Airgas.om CERTIFICATE OF ANALYSIS Grade of Product: EPA PROTOCOL STANDARD Part Number: Cylinder Number: Laboratory: PGVP Number: Gas Code: E03Nr52E15A38Q7 SG9164824BAL 124 - Tooele (SAP) - UT 872023 C02,02,BALN Reference Number: 153-402661010-'1 Cylinder Volume: 154.0 CF Cylinder Pressure: 2015 PSIG Valve Outlet 296 Certification Date: Feb 13,2023 Date: Feb I Certifcation pertqmed in sccordanc€ with'EPA Traceability Protml for Assay and Certiication of Gaseous Calibration Srandads Na, 2012)' ooct ment gpe 600/R-12531, using the sssay gocodures listed. Analytical Methodology does not requks corection for anatytical inE.ference- Ttris iytirider has a btal anaMicalunceriainty as slat€d bdw with a coofidence level of g5%, There arE no signitcant impurities which afiect the uae of this catibrauon mixture. Alt concentralions are on amole/mole basis unless othelwise noted. The resulls relateonly to the items tesled. The rBpo.l shall not b€ rEprcdrced except in fuff without appro\fat ofthe laborator. Oo Not Use Thls Cylinder Component ANAIYTICAI RESULTSActuat Protocof-Coneentration Method Requested Goncentration Total Relative Uncertainty Assay Dates CARBON DIOXIDE OXYGEN NITROGEN 24.AO% 24.00 o/o Balance 23.75% 24.58% G2 i/- 0,8% NIST Traceable +/- 0.6% NIST Traceable 0u13t2023 o?,1312023 CALTBRATION STANDARDSType Lot lD Cylinder No Concentration Uncertainty Expiration Date NTRM NTRM 1 3060802 09061434 cc415337 cc2E2492 24.04 YO CARBON DIOXIDE/NITROGEN 22.53 0/6 OXYGENNITROGEN 0.6'/o o.40/" Dec 1 1, 2025 Mav 13.2025 lnstrumenUMake/Model AIVALYTICd.L EQUIPMENT Analytical Principle Last MulUpoint Calibration Horiba VtA-510 SV4MEUTJ COz Horiba MPA-510 \ /603MM58 02 GO2 NDIR (Dixon) 02 Paramagnetc (Mason) Feb 09,2023 Feb 09.2023 Triad Data Available Upon Request l7l of 199 Page 1 of I /# --lI1**.*Accreditation #62754 Red Ball Technical Gas Service 555 Craig Kennedy Way ShrevepoG LA 71107 800-551-8150 PGVP Vendor lD # G12021 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number: Product lD Number: Cylinder Pressure: coA# Customer Po. NO.: Customer: :80078899 125371 9OO PSIG :80078E99.2021 0623-o Certificat'on Oate: Expiration Oate: MFG Facility: Lot Number: Tracking Number: Previous Certif, cation Dates: )7h5n021 )7t13no29 =80078899.2021 0623 )u270876 SMART-CERT This calibration standard has been certified per the May 20t2 1, G1. I l!^ N.rt I lce Thi< (:vlindar Rcl^w {On mid aO 7 Mmr.as.rll I- G'rtirrei.eoncenffifr6;tCi Analytical Measurement Data Available Online. Reference Standard{s) Carbon Dioxide O:<ygen Concentiation 1A.74% 10.95 o/o Unertalnty iO.05 % 10.09 % AnaMical Principle NDIR MPA Assayed On 07t15t2021 07n12021 Balance This is b cediry the gases referenced have been calibratedtested, and verltied to meet the defined specr'lica$ons. This calibGtionltest was performed using Gases or scales tnat are tfaceable tirough National lnttitljte of standads and Tecfinology (NlsT) to the lntemagonal s)6tem of units (sl}. The basis of compliance stated is a comparison of the measureffent parameteG lo $e speclfed or required calibratiorutesijng process. The expended uncertainties use a coverage ?aclor of k=2 to approximate the 95% confidence level of lhe measuremenl unless otheMise noted. This calibration certticate apdies only b fie item described and shall not be reproduced o$er than in tull, without witten approval fom Red Ball Tecinical Gas SeNices. f not induded, the uncertainty of celibrations are available upon request and were taken into accounl when determining pass or fail. Assistant Oparations Manager P'ssay Laboratoo/: Red Ball TGS Ve8im 02J. Revised q 201&0$17 172 of 199 c-/Aliatrce TIC!"t\icAL Gnt}ilp Location: HF Sinclair Woods Cross Refining, LLC - West Bountiful, UT Source: BoilerNo. l0 Project No.: AST-2023-1660 Datez 8122/2023 Traverse Point Time o2 (o/"1 CO, (oAl A-l 2 J 9:56 9:57 9:58 3.76 3.94 3.93 9.66 9.57 9.57 Averase 3.88 9.60 Criteria Met Sinsle Point Sinsle Point 173 of 199 10.3.2 The temperature data recorded in the field shall be considered valid. lf, during calibration, the absolute temperature measured with the sensor being calibrated and the reference sensor agree within '1.5 percent, the temperature data taken in the field shall be considered valid. OtheMise, the pollutant emission test shall either be considered invalid or adjustments (if appropriate) of the test results shall be made, subject to the approval of the Administrator. Date Sensor ID Reference Tcmn /oEt Indicated Temn (o[')Difference Criteria 3ilv20 3nt/20 3nU20 3ltt/20 3nt/20 3nU20 3nU20 3tnt20 3ltU20 Stack Probe Sample Venturi Oven Exhaust Mix I Dil I Dilution Venturi Dilution Aux 1000.0 250.0 250.0 300.0 30.0 70.0 50.0 30.0 68.0 I 001 .0 251.7 251.2 301 .8 30.9 70.5 54.8 30.6 68.6 0.lo/o 0.2o/o 0.2o/o 0.2Yo 0.2% 0.l%o 0.9% 0.loh 0.lo/o L | .5 Yo (absolute) 2ITsfr:&, You may use the manufacturer's recommended procedure for calibrating the RH sensors. Verify the dilution air and mixed gas RH sensor calibrations within three months of each test by attaching the two sensors to each other and drawing ambient air with approximately 50 to 70 percent relative humidity simultaneously through both sensors. Because the difference between the two RH sensors is very important in calculating stack gas moisture concentration using this method, the two RH sensors must agree within 2.8 percent of reading when monitoring the same gas stream. Date Console ID Dilution Air RH (%) Mixed Air RH (%)Difference Criteria 3nu20 FPM-C-5o17 64.2 6l. r 0.6% r 2.8 o/o (absolute) 2lH"'f ,$ Dilution Venturi lnstrument Rang€ 10 Reference lnstru ment Absolute Difference Percent Difference 10.00 9.00 7.00 5.00 3.00 1.50 0.00 9.88 9.01 7.08 5.01 3.02 1.59 o.L4 0.125 0.009 0.082 0.005 0.017 0.087 0.143 1.3 0.1 0.8 0.0 0.2 0.9 L.4 Averase o.67 Venturi lnstrument Rans€5 Reference lnstru ment Absolute Difference Percent Difference s.00 4.00 3.00 2.00 1.00 0.00 4.90 3.93 2.92 7.94 0.93 0.00 0.098 0.073 0.076 0.062 0.07 : 2.0 1.5 1.5 t.2 t.4 0.0 Averase t.26 Pitot lnstrument Rang€5 Reference lnstrumen Absolute Difference Percent Difference 5.00 4.00 3.00 2.00 1.00 0.00 4.95 3.95 2.95 1.95 0.9s 0.02 0.055 0.o47 0.0s1 0.0s2 0.051 0.022 L.L 0.94 t.o2 1.04 1.02 0.44 Average 0.93 2lrBf t'gb Nq oqoqoYoEo NcoY.9ooou E;,IOzo2ootr i lql<Vltx o;f.cu oNaNF$$ F- " -ia_ ' aCt il \I a:.!n6i3@.N qq.i1qqEris :tscq q ol .. 1Fsi IEqqenIqs cn^i tsq\ 9qJIq c9c? .. 16ioqdci .!c2oclci Ns JciciqIciNs qnIci 9Fiqc,ci c,q\IIqos co 2l T s f ,? h qc;qq9s F\cilqqos .!g<inlaF @oqoiaqs o Y- - oe aEE !} o9 66 FF a g9 Yi E F" o -t - t ? ol - l -. 2 el i l i- o ll e In!!FF .9 ., !E 0 ;g H S e gd ^ e E I5 ^ c- P a = o !i ; ! ^ r c i d a P e Id - e . s -l - l E^ *l f r l 3 E5 ll E ,r , ,, , ! ^ dd fl E E =8 3 E!^ 60 EPE E i 3 =e o :- L E I I .c B I I 3 - sl r l E e- :l e l s: I I +E il n? i 56 ts F : s 9e aE IIEE zz aE=o E)!=6F;E=ga :! t oE !c>; !=Eo o cl = l ' l |" 1 E{ E *3 s =i E oNoNN loca ro t- (f ) IFoIzotrtm=ot:)FzTULU-JLaTL ]L :" a >r !v:qo- >c rs !Eo r iF = -ds or=E *l -t - t -l -l * l ln n tt : E ao a o l,oo.EoUo,rUI cEre;qI UEctU\ UcioU@ oUt!c; .- !UoUNq EUoEqUqECJ EUciEci IUIq E.iUoEUsio qU.i8c;U oriUeoIodurio UEri6iuqq ud3niU6io o;c2UriUa IoUFJUFcq uEou uriciUn8o.1 U.ieU8oil UriE!Io 2l $ d f )} b qIuEIUqo o-9 oaq o-Eo oaFUU o:ez o; ! 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Ts F 332.70 331.60 333.40 Front Half Emissions Summary CO2 - FCO2 9.17 8.75 8.90 Run 1 Run 2 Run 3 Run 4 Avg. O2 4.43 4.92 4.45 gr./dscf 0.00068 0.00037 0.00042 0.0005 N2+C 86.40 86.33 86.65 lbs/hr 0.0816 0.0419 0.0424 0.0553 lbs/MW-hr 0.0002 0.0001 0.0001 0.0001 Md 29.64 29.60 29.60 lbs/MMBtu 0.00102 0.00056 0.00063 0.00074 Ms 28.13 28.09 28.09 Y 1.1420 1.1420 1.1420 Cp 0.76 0.76 0.76 Total Emissions Summary w/back half condensable Vm cf 78.80 77.30 79.30 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 82.30 82.30 82.30 gr./dscf 0.0007 0.0004 0.0004 0.0005 AVG. Tm F 74.65 80.85 84.70 lbs/hr 0.0816 0.0419 0.0424 0.0553 lbs/MW-hr 0.0002 0.0001 0.0001 0.0001 Vm std 78.80 77.30 79.30 lbs/MMBtu 0.0010 0.00056 0.00063 0.0007 Vw std 3.87 3.87 3.87 Bws 0.13 0.13 0.13 S Bws 1.00 1.00 1.00 Avg. Sqrt Dlp 0.52 0.50 0.53 Vs 35.35 34.08 36.15 F factor used scfm wet 1.60E+04 1.54E+04 1.63E+04 8263 acfm 2.81E+04 2.68E+04 2.40E+04 Qsd dscfh 8.36E+05 8.03E+05 7.05E+05 # Sample Points 12.00 12.00 12.00 Dn 0.240 0.260 0.260 An 3.14E-04 3.69E-04 3.69E-04 Start Time End Time Total Test time 240.00 240.00 240.00 Time @ point 20.00 20.00 20.00 O2 CO2 lbs/M Page 1 Run 1 Holly Refinery - Boiler #10 Flow & Moisture Test Date 8/22-23/23 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 13.10 25.87 -0.11 25.86 333 9.17 4.43 86.40 29.64 28.13 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 8.5921 1.1420 0.76 78.800 82.30 74.65 78.800 3.874 0.1300 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.521 35.35 15,992 28,129 8.36E+05 12 0.24 240 20.00 1.110000 FALSE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 0.000 0.271 1.11 333 76 73.1 Wt. (Final) Wt. (Initial) lc 2 78.800 0.271 1.11 333 76 73.1 532.9 482.1 50.8 3 426.8 407.4 19.4 4 254.1 249.1 5.0 5 517.5 510.4 7.1 6 0.0 7 8 Isokinetics 87.9 9 Test Date 8/22-23/23 10 Start Time enter enter 11 0.2330 enter 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holly Refinery - Boiler #10 Flow & Moisture Test Date 5/13/2009 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 13.10 25.79 -0.10 25.78 332 8.75 4.92 86.33 29.60 28.09 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 8.4882 1.1420 0.76 77.300 82.30 81 77.300 3.874 0.1300 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.501 34.08 15,389 26,775 8.03E+05 12 0.26 240 20.00 1.11 FALSE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 0.000 0.25 1.11 332 81 81.0 Wt. (Final) Wt. (Initial) lc 2 77.300 0.25 1.11 332 81 81.0 532.9 482.1 50.8 3 426.8 407.4 19.4 4 254.1 249.1 5.0 5 517.5 510.4 7.1 6 0.0 7 8 Isokinetics 75.4 9 Test Date 8/22-23/23 10 Start Time enter 11 0.2330 enter 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holly Refinery - Boiler #10 Flow & Moisture Test Date 5/13/2009 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 13.095 25.81 -0.15 25.80 333 8.90 4.45 86.65 29.60 28.09 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 8.6967 1.1420 0.76 79.300 82.30 85 79.300 3.874 0.1300 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.531 36.15 16,297 24,010 7.05E+05 12 0.26 240 20.00 1.11 FALSE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 0.000 0.282 1.11 333 85 Wt. (Final) Wt. (Initial) lc 2 79.300 0.282 1.11 333 85 532.9 482.1 50.8 3 426.8 407.4 19.4 4 254.1 249.1 5.0 5 517.5 510.4 7.1 6 0.0 7 8 Isokinetics 72.5 9 Test Date 8/22-23/23 10 Start Time enter 11 0.2330 enter 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1