HomeMy WebLinkAboutDRC-2003-001061 - 0901a0688080578cI
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2003
NESIIAPS RADON FLUX MEASUREMENT PROGRAM
White Mesa Millsite
BIanding, Utah
Prepared for:
lnternational Uranium (USA) Corporation
P.O. Box 809
6425 South HwY 191
Blanding, Utah
Prepared bY:
Tellco Environmental, LLC
1231 N.23 St', Ste. 206
Grand Junction, Colorado 81501
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Table of Contents
1.0 INTRODUCTION
2.0 SITE DESCRIPTION
3.0 SAMPLER DESCRIPTION
4.0 FMLD OPERATIONS
4.1 General Site Specific lnformation
4.2 Sampler Placement
4.3 Sampler Retrieval
4.4 Site Exit
4.5 Environmental Conditions During Measurement Periods
5.0 LABORATORY OPERATIONS
5.1 Inkoduction
5.2 Apparatus
5.3 Analysis Procedure
5.4 Weighing and Background Counting
5.5 Receipt and Weighing of Exposed Charcoal
5.6 GammaRayCounting
5.7 Quality Conkol Samples
5.8 Data Validation
5.9 Map Preparation
5.10 Calculations
6.0 SAMPLE RESULTS/CALCUIATIONS
Figure I - Large Area Activated Charcoal Collector Diagram
APPENDICES:
Appendix A - Support Documents
Appendix B - QC Recount Data
Appendix C - Individual Field Samples Results and QC Field Blank Data
Appendix D - Figrre 2, Sample Locations Map
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2003 NESIIAPs RADON FLUX MEASTIREMENTPROGRAM
lntemational Uranium (USA) Corporation
P. O. Box 809
6425 South llwy 191
Blanding, Utah
1.0 INTRODI]CTION
During June 2003, Tellco EnvironmenlaT,L.L.C. (Tellco) of Grand Junction, Colorado, provided support
to International Uranium (USA) Corporation (IUC) regarding the required National Emission Standards
for Hazardous Air Pollutants (1.{ESIIAPs) Radon Flux Measurements on Tailings Cells 2 and 3 at the
White Mesa Mill uranium processing facility in Blanding, Utah. These measurements are required of IUC
to show compliance with 40 Code of Federal Regulations, Part 61, Subpart W, National Emission
Standards for Radon Emissions liom Operating Mill Tailings. At present, there are no Subpart T uranium
mill tailings at this site. The regulations limit the amount of radon that can be emitted per unit area (m2)
per unit of time (s). This standard is not an average per facility, but is an average per radon source.
According to subsection 61 .252 Standard, (a) radon-222 emissions to ambient air from an existing uranium
mill tailings pile shall not exceed 20 pCtlmz-s of radon-222. Subsection 61.253, Determining Compliance,
states that: "Compliance with the emission standard in this subpart shall be determined annually through
the use of Method 115 ofAppendix B."
Tellco was contracted to perform the on-site placement and rekieval of the radon collector canisters, as
well as the subsequent lab analysis and reporting for calendar year 2A03. This repofi addresses the
procedures employed by Tellco and IUC to obtain the results presented in Section 6.0 of this report.
2.A SITEDESCRIPTION
The White Mesa Mill is located south of Blanding, Utah on Highway 191. The mill began operations in
1980 for the purpose ofextracting uranium and vanadium from feed stocks. Processing effluents from the
operation are deposited in four "lined" cells, which vary in depth. Cells 1 and 4 are used solely for "liquor"
storage, while Cells 2 and3 are used for sand tailings/liquor deposition.
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Cell2 has a total area of approximately 270,624 square meters (m2). This cell was comprised of two
source regions that required NESHAPs radon monitoring: approximately 263,049 m2 of the cell had a soil
cover of varying thickness, with approximately 7,575 mz of exposed tailings "beaches". There was no
significant standing liquid in "low" elevation areas within Cell2.
Cell 3 has a total area of 288,858 m2. This ce1l was comprised of two source regions that required
NESHAPs radon monitoring: approximately l4l,0gg m2 of the cell had a soil cover of varyng thickness,
with approximately 57,575 m2 of exposed tailings "beaches". The remaining approximately 90,244 m2
was covered by standing liquid in "low" elevation areas.
Due to worker health and safety concerns expressed by both IUC site personnel and Tellco monitoring
staff, a portion of the areas of the wet beaches of Cell 3 were not sampled due to the extreme instability of
wet tailings beaches.
3.0 SAMPLERDESCRIPTION
The Large Area Activated Charcoal Canisters (LAACC) used to perform the required radon measurements
were fabricated in confornance with "Radon Flux Measurements on Gardinier and Royster Phosphogyp-
sum Piles near Tampa and Mulberry, Florida" (NTIS Document #PB86-161874) as referenced in 40 CFR,
Part 61, Method 115, Appendix B. This method of performing radon flux measurements involves the
adsorption ofradon on activated charcoal in a large-area collector. The charged collector is placed directly
on the material surface to be measured and is allowed to collect radon for a given time period (24 hours).
The radon collected on the activated charcoal is then measured by means of gamma spectroscopy.
Each LAACC was constructed using a l0-inch PVC cap, a distribution grid that is situated on top of a l/,
inch thick layer of foam and secured under a %inch foam layer and a galvanized steel screen by a retaining
ring (see Figure i).
FIGURE 1 - Large Area Activated Charcoal Collector (LAACC)
FISURE I Large-Area &adon Collector
f in. Thich
Scrubber Fad
'I 12'in. Ihick
Scrubber Pad
1 r2-rn. Ttrict Charcr:;i
Support Grrd
Retainar
Spring
l0-in. dia
PVC End Cap
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Prior to deploynent, each collector was charged with 180 grams of baked charcoal from sealed individual
sample containers (reference Section 5.0 below for laboratory procedures). After the 24-hour exposure
period, the charcoal was transferred to the plastic sample containers, sealed with tape, labeled as to sample
identification along with exposure times/dates, and transferred to the Tellco laboratory (Grand Junction,
Colorado) facilify for analysis.
4.0
4"1
FIELD OPERATIONS
General Site Specific Ilformation
The sampling effort commenced on June 09,2003. Tellco personnel laid out baselines within the cover
regions of Cells 2 and3, and a sample grid location system was developed to accommodate locating the
samplers in the field. Tellco personnel placed a high/low temperature thermometer, located within the
impoundment, to provide a record of ambient air temperatures, thereby assuring compliance with the 35"F
measurement criterion. A rainfall measurement gauge installed within the impoundment was used to
monitor and measure rainfall occutrences, if any (see Section 4.5 for site atmospheric conditions).
4.2 Sampler Placement
Radon measurements were made in conformance with methods described in NTIS Document #pBg6-
161874 for each 100 sample measurement set for each source region. In addition to the 100 samples, each
sample set also contained five field blanks. The spacing distribution for each set of 100 measurements was
determined by visual means and a "best fit" distribution pattern for each source region. Tellco personnel
identified the approximate locations of each collector to generate a sample locations map depicting the
locations of the collectors (see attached Figure 2). Vehicles were used, where appropriate, during
placement on cover material, while the placement on tailings "beaches" was accomplished primarily by
foot travel due to safety concems. As previously stated, a portion of the areas of the wet beaches of Cell 3
were not sampled due to the extreme instability ofwet tailings beaches.
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Sample collection is initiated by placing 180 grams of unexposed charcoal liom a sealed container into the
above-described canister. A pre-measured, unexposed container of charcoal was selected from a batch,
opened and distributed evenly across the area of the suppofi gnd. The collector was then re-assembled and
gently placed face down on the surface to be measured. Care was exercised not to "push" the device into
the soil surface. The collector rim was "sealed" to the surface using a berm of local borrow material
(either tailings or soil) to reduce dilution due to air or wind currents within the collector.
A sample identification number was assigned to each collector. Sample numbers were composed using an
alphanumeric system that began with the charcoal batch letter (i.e., A, B, C . . .) followed by a sequential
number indicating the placement (i.e., 01,02,. . .). This sample identification number was recorded on an
adhesive label and placed on the top of the collector. The sample ID, date, and time of placement were
recorded on a master data sheet for each set of measurements. The empty containers were retained for
sample retrieval upon completion of the measurement time period (approximately 24 hours).
During the placement of the 400 charcoal flux collectors (100 per region), twenty field blanks (five per
region) were also collected. The procedure for field blanks was to charge a collector with charcoal and
place it inside an airtight container (e.g., plastic bag) throughout the 24-honr sample time period.
4.3 Sampler Retrieval
Retrieval of the collectors followed the same general pattern as placement. The collectors (including
blanks) were disassembled and the charged charcoal was removed, pouring it from the collector into a
large funnel suspended above a sample container. The sample ID number was transferred to the sample
containeq which was sealed and placed in a box for transport. The date and time of retrieval were
recorded on the same data sheet as the sample placement information.
Sample data sheets accompanied the shipment to the laboratory. Tellco personnel maintained custody and
assured timely delivery of the samples to the Tellco Grand Junction laboratory for prompt analysis of the
charcoal samples.
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4.4 Site Exit
Upon completion of on-site activities, the field equipment was alpha scanned for possible contamination
resulting from fieldwork activities. A1l field equipment was surveyed by IUC Radiation Safety personnel
and released for unrestricted use prior to leaving the site.
4.5 Environmental Conditions During Measurement Periods
Referencing 40 CFR, Part 61, Subpart W, Appendix B, Method 115 - Monitoring for Radon-222
Emissions, Subsection 2.1.4 - Restrictions to Radon Flux Measurements, "the following restrictions are
placed on making radon flux measurements:
(u) Measurements shall not be initiated within 24 hours of a rainfall.
(b) If a rainfall occurs during the 24 hours measurement period, the measurement is
invalid if the seal around the lip of the collector has washed away or if the
collector is surrounded by water.
(c) Measurements shall not be performed if the ambient temperature is below 35
degrees F or ifthe ground is frozen."
Site Specific Discussion
(u) For this measurement sampling program, rainfall did not affect measurement initiation and no
measurable rainfall occurred during the 24-hourperiod preceding placement of any of the LAACC
samplers at the site.
(b) There were no measurable rainfall events during any of the Z4-hour sample periods after canister
placement (as indicated by the on-site rain gauge), however, three of the LAACCs were found
surrounded by water at the time of retrieval, caused by rising process liquid levels.
(") During the four 24-hour sample-set placements, the minimum ambient air temperature recorded at
the site was 48 degrees F.
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I 5.0 LAB.RAT'RY
'PERATT,NS' 5.1 Introduction
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The large area activated charcoal gas adsorption collectors are passive sampling devices used to determine
I the flux rate of radon -222 gasfrom a surface area. As previously described, and depicted in Figure 1, the
collectors utilized a lO-inch diameter PVC end cap, spacer pads, screens, and a steel retainer ring.
t Radon gas is adsorbed on the contained charcoal and subsequent radioactive decay ofthe entrained radon
I :esults
in the deposition of radioactive lead-214 and bismuth-Z14 in the canister. These radon progeny
isotopes emit characteristic gamma photons, which can be detected.
I using empirical calibration factors derived from cross-calibration of source standards containing a known
t total activity of radirm-226 in a geometry identical to the samples to be counted.
t 5.2 Apparatus
I . Single- or multi-channel pulse height analysis system, Ludlum Model 2200 witha Teledyne 3" x 3"
I :"-:r:.lrr,,r* well approximately 40 cm deep with 5-cm thick lead walls and a 7-cm thick
I #Tu";t" il:us solution radirm-226absorbed onto 180 grams of activated charcoal. calibration source.
I Ohaus Model C501 balance with 0.1-gram sensitivity.
5.3 Analysis Procedure
Inspection of the Charcoal Container
Charcoal was received at the analltical laboratory in the sealed sample containers. Upon receipt, the
integrity of the container was verified by visual inspection of the plastic container.
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Sample Identification Numbers
Each sample container had a unique sample identificafion number, which was determined in the field, and
written onto a label attached to the sample container.
Drying and Recycling
All charcoal was dried,/baked before use in the field for radon flux measurements. Procedures were the
same for newly prepared charcoal and for charcoal recycled after field use. Charcoal was baked at
approximately 110 degrees C. Baking procedures were as follows:
. Oven temperature set to I l0 degrees C.
Charcoal placed in the oven in a metal baking tray.
Baked for a minimumof 24 hours.
. Immediately after the tray was removed ftom the oven, the charcoal was transferred and sealed into
clean sample containers.
Weishins and Background Counting
Proper balance operation was verified daily by checking with a standard weight. The balance readout
should agree with the known standard weight to within * 0.lo/o. If a discrepant readout were to occur, the
balance would be re-zeroed, the check weight wiped with a soft, lint-free cloth, and re-weighed. If the
discrepancy persisted, the balance would be removed from service and tagged "Out of Service." For this
project, the scale conformed for each day of use (See Appendix A, Balance Operation Daily Check forms).
After acceptable balance checkout, each empty container was individually placed on the balance and the
tare weight of the container was documented to the nearest 0.1 grams on the labeI. The scale was re-
zeroed with the container on the balance" Charcoal was carefully added to the container until the readout
registered 180 grams. The lid was immediately placed on the container and sealed with plastic tape. The
tape was stretched slightly while wrapping around the container. The end of the tape was folded to form a
tab for easy tape removal. The balance was checked for readout drift between each container-weighing
step.
5.4
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Ten sets of five one-minute background counts were acquired for 10% of containers selected at random to
represent the "batch"- Each sealed container was placed individually in the shielded counting well, with
the bottom of the container centered over the detector. Five one-minute background counts were then
documented for each container in that batch, and subsequently documented on the respective radon flux
field data sheet. If the background counts were too high to achieve a sufficiently low sensitivity level
(Lower Level of Detection, LLD), the entire batch was labeled non-conforming and recycled through the
dryrng process.
Gamma ray counting system checkout was performed as described in Section Observed empty
counting well background counts must fall within the established three-sigma range (see Appendix A,
system operation performance records) using the aforementioned Ludlum/Teledyne counting system with
shielded well.
5.5 Receipt and Weiehinq of Exposed Charcoal
Containers of exposed charcoal were hand delivered to the Tellco radon laboratory in Grand Junction, CO
for analysis. The laboratory staff was responsible for weighing and inspecting the containers of exposed
charcoal, reviewing the documentation forms and entering the required documentation into data base
spreadsheets.
When the containers were received, the following items were inspected:
" Container was closed and sealed with tape.
. Container was not damaged.
. Data sheet was complete.
' Discrepancies found during the receipt inspection were documented on the data sheet.
Containers received open or damaged resulting in seal failure were considered void. Out of the 400
collectors placed during the sampling effort from June 09 - 13,2003, a total of 398 samples were collected
and subsequently received at the laboratory in good physical condition and validated. Two samples llom
Cell 2 Cover Region (D32 and D100) were spilled and lost during the retrieval process.
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All of the containers that were received at the laboratory conformed and were weighed on a balance to the
nearest 0.1 gram and the gross weight was logged on the field data sheets under the appropriate column"
5.6 Gamma Ray Counting
Source/Background Checks
The charcoal gamma ray counting system was subjected to performance checks daily when used. These
checks included background and radium-226 calibration source measurements. (Appendix A of this report
contains daily counting system performance check records.)
Sample Analysis
. The length of count time was determined by the activity of the sample being analyzed. A data quality
objective establishing a minimum accruement of 1000 counts for any given sample was followed
during sample analyses.
' The sample container was placed in the counting well with the lid side up and the center on the NaI
detector and the shielded well door was set into place.
. One sample count was accrued and the mid-sample count time and date was documented on the field
data sheet.
. The sample counts were documented on the field data sheet for data reduction,
. The above steps were repeated for each exposed sample collector.
. Every tenth container counted on a given date was selected for recounting. These containers were
recounted within three days following the original analysis, as described above.
5.7 Quality Control Samples
Charcoal flux measurement QC samples included the following intraJaboratory analytical objectives as
required in 40 CF& Part 61, Subpart W, Appendix B, Method 115, 4.0 - Quality Assurance Procedures for
Measuring Ra-222 Flux, D.:
. Recounts, 1002, and
. Field blanks, 5%.
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Samples were statistically evaluated for completeness, precision, and accuracy.
5.8 Data Validation
All sample canister data were subjected to data validation protocols. The results are as follows:
Forfy recount measurements were performed by conducting replicate analyses of individual field samples.
These recount measurements comprised approximately l0o/o of the total number of samples analyzed. The
overall precision of all recount measurements ranged from less than 1%o to ll.8Yo with an average
precision of approximately 3.lYo.
Twenty field blanks were analyzed by measuring the radon progeny activity in samples subjected to all
aspects of the measurement process, excepting exposure to the source region. These blank sample
measurements comprised 5o/o of the field samples. The results of the blank sample analyses ranged ffom
-0.02 to 0.13 pCi/m2-s. The average blank value of 0.04 pCi/mz-s corresponds to less than l% of the
regulatory limit of 20 pCi/m2-s (the regional averages reported were not adjusted by the blanks results).
The accuracy of the field measurements was assessed by counting laboratory control samples with known
Ra 226 content in a geometry idenfical to the fie1d samples each day that the field samples were analyzed.
'l'lre accuracy (percent error) of these lab conkol sample measurements ranged from _35Y, to 3 .4o/o, with
an arithmetic average of -0.1o/o (see Appendix A).
Ninety-eight samples from Cell 2 Cover region were validated, representing 98oh completeness in that
region. A1l samples from Cell 2 Beaches, Cell 3 Beaches and Cell 3 Cover regions were validated,
representing 100% completeness in those regions.
The QC data validation met the objective requirement for assessing the sampling program's precision,
sensitivity, accuracy, and completeness. Reference Appendix B for QC recount analyses results.l.
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5.9 Sample Map Preparation
The approximate sample locations are depicted on Figure 2 and at the end of this report. The regional
boundaries and other features depicted are based on aerial photography and field observations.
5. l0 Calculations
Radon flux rates rvere calculated for charcoal collection samples using calibration factors derived from
cross-calibration to sources with known total activity with identical geometry as the charcoal containers.
A leld efficiency factor was used to calculate the total activity of the sample charcoal containers.
Individual field sample result values presented were not reduced by the results of the field blank analyses.
In practice, radon flux rates were calculated by a database computer program. The algorithms utilized by
the data base program were as follows:
Equation 5.1:
pCi Rn-2221m'r"" : *ffi;Ar,r,r,,
where: N
Ts
b
Equation 5.2:
Error,2o = 2x
: net sample count rate, cpm under 220-662 keV peak: sample duration, seconds: instrument calibration factor, cpm per pCi; values used:
0.11 20, for M-0 1,1D-21 and
A.1128, forM-021D-20: decay time, elapsed hours between sample mid-time and count mid-time: areaof the collector, m2
@dSample,cpmr-a-
! SampleCount, t, min Backgrorurd Count, t, min
N"LcP- x SamPle Concentration
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(a)
(b)
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Equatiion 5.3:
,r^ j:.71+(4.65XSbILLU
['fsxAxb*o.5rd/e-l7s\
where: 2.71
4.6s
Su
Ts
b
: constant: confidence interval factor: standard deviation ofthe background count rate: sample duration, seconds: instrument calibration factor, cpm per pCi; values used:
0.11 2A, for M-0 1lD-21 and
A.n28,forM-021D-20: decay time, elapsed hours between sample mid{ime and count mid-time: area of the collector, m2
6.0 SAMPLE RESULTS/CALCULATIONS
Referencinlg 40 CFR, Part 61, Subpart W, Appendix B, Method 1i5 - Monitoring for Radon-222
Emissions, Subsection 2.1.1 - Calculations, "the mean radon flux for each region of the pile and for the
total pile strall be calculated and reported as follows:
The individual radon flux calculations shall be made as provided in Appendix A EPA
86(1). The mean radon flux for each region of the pile shall be calculated by summing all
individual flux measurements for the region and dividing by the total number of flux
measurements for the region.
The mean radon flux for the total uranium mill tailings pile shall be calculated as follows:
, JrAr +...J?& [+l ...J4;t- *A,
Where: J,: Mean flux for the total pile (pCi/m2-s)
Ji : Mean flux measured in region i (pCi/m2-s)
A; : Area of region i (m2)
,{1: Total area of the pile (m2)
2.1.8 Reporting. The results of individual flux measurements, the approximate locations
on the pile, and the mean radon flux for each region and the mean radon flux for the total
stack [pile] shall be included in the emission test report. Any condition or unusual event
that occurred during the measurements that could significantly affect the results should be
reporled."
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Site Specific sampre Resurts (reference Figure 2 and Appendix c)
I (a) The mean radon flux for each region within each cell is as follows:
I cell 2 -cover Area : 13.3 pci/m2-s (based on 263,049 m2 area)
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- Beach Areas : lr.5 pci/m2-s (based on7,575 mz area)
Cell 3 - Cover Area : 7.8 pCi/m2-s (based on 147,099 mz area)
- Beach Areas : 4g.TpCilm2-s (based on 57,515 m2 area)
- Standing Liquid Areas : 0 pCrlm2-s (based on 90,244 mz area)
Note: Reference Appendix C of this reporl for entire summary for individual measurement
results.
t @) Using the data presented above, we have calculated the total mean radon flux for each pile (cell) as
follows:
Cell2: 14.9 pCt/mz-s
( 13.3\(263.049\ + (J t.s)0 .s7 s)
270,624
Cell3:13.6pCi/m2-s
(7.8X141.099) + (4e.0X57.s15) + (0x90.244)
2gg,g5g
I No condition or unusual event occurred during the measurements that could significantly affect the results.
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APPENDIX A
Support Documents
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BALANCE OPERATION DAILY CHECK
I Barance Moder: Oltqrr> ?ol-- - |ra,n s.N. r z3o1
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Date Pre-check (g)Post-check (g)o.K. t 0.1 0/o ?By
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CHARCOAL CANISTER ANALYSIS SYSTEM
srrEr-ocArroN, \yJh',|e Mero Ml tl - 'B l"r.r d','i'1 , ut+'iL-_-=-]--
.LIENT: I ,1+ t',;-flrli+\ o'-' 4 \ Lf, v^^ '4" tl '--r ('d) r-P '
Calibration Check Loe
Systemio: [v\- "rr /D -t, calibrationDate:4lz4loS DueDate: 4lzq la4
ScalerSAJ: St1-i2 (n-il)-Highvoltage: ll0O window: 4.42 Thrshld:
Source ID/SN, Ra" hr/AS P+Source Activity: {4" 3 (PC,
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YN: Y : average background and source cpm falls within the control limits.
N : average background and source cpm does not fall within the control limits.
The acceptable ranges were determined from prior background and source check data.
Al1 counts times are one minute.
Source Counts (1 min. eachCounts (l min. each
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C}IARCOAL CANISTER ANALYSIS SYSTEM
srrELocArro*, W 1l:tz Ml es^ iVr', I I - B lan .{i n,g, U*r, f.
cI-reNr' f"r *e rn a*',or,,al Lt v^,",t,l\ u lrt Co rP,
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Calibration Dare: 4 lz4 I 0 3 Drr-Da.re: 4 I 24 ( a +
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N : average background and source cpm does not fall within the control limits.
The acceptable ranges were determined frompriorbackground and source check data.
Al1 counts t'imes are one minute.
Date By Backsround Counts (1 min. each)Source Counts (l min. each)ok?
Y/N#1 #2 #3 Avs.#1 #2 #3 Averape
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SystemlD: -$:O-L'>-"2-C, CalibrationDate: 4lz4 l 03 DueDare:41241 o4-
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rechnician: \> t- A**
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N: average background and source cpm does not fall within the control limits.
The acceptable ranges were determined fiom prior background and source check data.
cLrENr: 7 ^l<..
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Date By Backffound Counts (l min. each)Source Counts (1 min. each)ok?
YN#1 #2 #3 Avs-#1 #2 #3 Average
Gllt,lo\rti /^a 14-r l4t ?B l1:1 t Abrfi tob'zA-Io114 ia1 tP,v
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CHARCOAI CANISTER ANALYSIS SYSTEM
srrELocAlo*' ra.i h',f e i'(esa \\''\\ - 'Bto*Ji^q
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Calibration Check Los
System ID:il,\-CI'z_l b - zo Catibration aate: Ai 24 I o S Due Date:jf A4 l O y
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rechnician: >L/fr{f- -
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N : average backgror.rnd and source cpm does not fall within the control limits.
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T4l*,
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Date By Back$ound Counts (1 mia. each)Source Counts (1 min. each)ok?
YN.J#l #3 Avs.#1 #2 #3 Averase
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QC Recount Data
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