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HomeMy WebLinkAboutDRC-2004-001041 - 0901a0688080578d2004 NESTIAPs RADON FLUX MEASUREMENT PROGRAM White Mesa Millsite Blanding, Utah Prepared for: International Uranium (USA) Corporation P.O. Box 809 6425 South Hrvy 191 Blanding, Utah Prepared by: Tellco Enyironmental, LLC 1231N.23 SL, Ste. 206 Grand Junction, Colorado 81501 t I T I I I t I I I I l T I I Table of Contents 1.0 INTRODUCTION 2.0 SITE DESCRIPTION 3,0 SAMPLERDESCRIPTION 4,0 FIELD OPERATTONS 4.1 General Site Specific Information 4.2 Sampler Placement 4.3 Sampler Retrieval 4.4 Site Exit 4.5 Environmental Conditions During Measurement Periods 5.0 LABORAIORYOPERATIONS 5.1 Introduction 5.2 Apparatus 5.3 Aaalysis Procedure 5.4 Weighing and Background Counting 5.5 Receipt and Weighing of Exposed Charcoal 5.6 Gamma Ray Counting 5.7 Quality Conkol Samples 5.8 Data Validation 5.9 Map Preparation 5-10 Calculations 6.0 SAMPLERESULTS/CAI-CUI.A.TIONS Figure I - Large Area Activated Charcoal Collector Diagram APPENDICES: Appendrx A - Support Documents Appendix B - QC Recount Data Appendix C - Individual Field Samples Results and QC Field Blank Data Appendix D - Figure 2, Sample Locations Map Page I I 2 4 4 4 5 6 6 1 7 1 1 8 9 l0 l0 11 l2 t2 l3 3t I I ! I t I I I I I I I I I I I I I 2004 NESHAPs RADON FLUXMEASUREMENT PROGRAM lntemational Uranium (USA) Corporation P. O. Box 809 6425 South Hwy 191 Blanding, Utah 1.0 INTRODUCTION During June 2004, Tellco Environmental, L.L.C. (Tellco) of Grand Junction, Colorado, provided support to Intemational Uranium (USA) Corporation (IUC) regarding the required National Emission Standards for Hazardous Air Pollutants (NESHAPs) Radon Flux Measurements on Tailings Cells 2 and 3 at the White Mesa Mill uranium processing facility in Blanding, Utah. These measurements are required of IUC to show compliance with 40 Code of Federal Regulations, Part 61, Subpart W, National Emission Standards for Radon Emissions from Operafing Mill Tailings. At present, there are no Subpart T uranium mill tailings at this site. The regulations limit the amount of radon that can be emitted per unit area (m2) per unit of time (s). This standard is not an average per facility, but is an average per radon source. According to subsection 61.252 Standard, (a) radon-222 emissions to ambient air {iom an existing uranium mill tailings pile shall not exceed 20 pCi/m2-s of radon-222. Subsection 61.253, Determining Compliance, states that: "Compliance with the emission standard in this subpart shall be determined annually through the use of Method 115 of Appendix B." Tellco was contracted to perform the on-site placement and retrieval of the radon collector canisters, as well as the subsequent lab analysis and reporting for calendar year 2A04. This report addresses the procedures employed by Tellco and IUC to obtain the results presented in Secfion 6.0 of this report. 2.0 SITE DESCRIPTION The White Mesa MilI is located south of Blanding, Utah on Highway 191. The mill began operations in 1 980 for the purpose of extracting uranium and vanadium from feed stocks. Processing effluents from the operation are deposited in four "lined" cells, which vary in depth. Cells I and 4 are used solely for "liquor" storage, while Cells 2 and3 are used for sand tailings/liquor deposifion.I, T I I I I T t t I I t I I T I I I Cell 2 has a total area of approximately 27A,624 square meters (m2). This cell was comprised of two source regions that required NESFIAPs radon monitoring: approximately 264,973 m2 of the cell had a soil cover of varying thickness, with approximately 5,651 m2 of exposed tailings "beaches". There was no significant standing liquid in "low" eleyation areas within Cell2. Cell 3 has a total area of 288,858 m2. This cell was comprised of two source regions that required NESHAPs radon monitoring: approximately 148,099 m2 of the cell had a soil cover of varying thickness, with approximately 50,5 I 5 m2 of exposed tailings "beaches". The remaining approxim ately 90,244 mz was covered by standing liquid in "low" elevation areas. Due to worker health and safety concems expressed by both IUC site personnel and Tellco monitoring staff, aportion of the areas of the wetbeaches and covered areas of Cell 3 were not sampled due to the extreme instability of wet tailings beaches and soils. 3.0 SAMPLERDESCRIPTION The Large Area Activated Charcoal Canisters (LAACC) used to perform the required radon measurements were fabricated in conforrnance with "Radon Flux Measurements on Gardinier and Royster Phosphogyp- sum Piles near Tampa and Mulberry, Florida" OITIS Document #PB86-161874) as referenced in 40 CFR, Part67, Method 115, Appendix B. This method of performing radon flux measurements involves the adsorption ofradon on activated charcoal in a large-area collector. The charged collector is placed directly on the material surface to be measured and is allowed to collect radon for a given time period (24 hours). The radon collected on the activated charcoal is then measured by means of gamma spectroscopy. Each LAACC was constructed using a 10-inch PVC cap, a distribution grid that is situated on top of a l% I inch thick layer of foam and secured under a % inch foam layer and a galvanized steel screen by a retaining ring (see Figure 1).I: I T I I l -in. Thick Scrubbar Pad I /2-in. Thick Scrubber Pad I /2.ro. fhick Charcoai Support $rrd Retainor Spring t I I T t I I I t I ! I I I I I t I I \ l0"in. dia PVC End Cap fIGURE I Large-Area Radon Collector I t I I T I I I I I T I I I I I I I I Prior to deploynent, each collector was charged with 180 grams of baked charcoal from sealed individual sample containers (reference Section 5.0 below for Iaboratory procedures). A1ter the 24-hour exposure period, the charcoal was transferred to the plastic sample containers, sealed with tape, labeled as to sample identification along wittr exposure times/dates, and hansferred to the Tellco laboratory (Grand Junction, Colorado) facility for analysis. 4.0 4.1 FIELD OPERATIONS General Site Specific Information The sampling effort commenced on June 07,2004 with the placanent of canisters throughout Cell 2 beach region. Tellco personnel laid out baselines within tle cover regions of Cells 2 and 3, and a sample grid location system was developed to accommodate locating the samplers in the field. Tellco personnel placed a higMow temperature thermometer, located within the impoundrnent, to provide a record of ambient air temperatures, thereby assuring compliance with the 35"F measurement criterion. A rainfall measurement gauge installed within the impoundment was used to monitor and measure rainfall occurrences, if any (see Section 4.5 for site atmospheric conditions). 4.2 Sampler Placement Radon measurements were made in conformance with methods described in NTIS Document #pBg6- 161874 for each 100 sample measurement set for each source region. In addition to the 100 samples, each sample set also contained five field blanks. The spacing distribufion for each set of 100 measurements was determined by visual means and a "best fit" disffiution pattern for each source region. Tellco personnel identified the approximate locations of each collector to generate a sample locations map depicting the locations of the collectors (see attached Figure 2). Vehicles were used, where appropriate, during placement on cover material, while the placement on tailings 'beaches" was accomplished primarily by foot travel due to safety concerns. As previously stated, a portion of the areas of Cell 3 were not sampled due to the extreme instability of wet tailings beaches and soils. I T t II I Sample collection is initiated by placing 1 80 grams of unexposed charcoal from a sealed container into the above-described canister- A pre-measured, unexposed container of charcoal was selected from a batch, opened and distributed evenly across the area of the support grid. The collector was then re-assembled and gently placed face down on the surface to be measurcd. Carewas exercised not to ',push" the device into the soil surface. The collector rim was "sealed" to the surface using a berm of local borrow material (either tailings or soil) to reduce dilution due to air or wind currents within the collector. A sample identification number was assigned to each collector. Sample numbers were composed using an alphanumeric system that began with the charcoal batch letter (i.e., A, B, C . . .) followed by a sequential number indicating the placement (i.e., 01, 02, . . .). This sample identification number was recorded on an adhesive label and placed on the top of the collector. The sample ID, date, and time of placement were recorded on a master data sheet for each set of measurements. The ernpty containers were retained for sample retrieval upon completion of the measurement time period (approximately 24 hours). During the placement of the 400 charcoal flux collectors (100 per region), twenty field blanks (five per region) were also collected. The procedure for field blanks was to charge a collector with charcoal and place it inside an airtight container (e.g., plastic bag) throughout tle 24-hour sample time period. 4.3 Sampler Retrieval Retrieval of the collectors followed the same general pattem as placement. The collectors (including blanks) were disassernbled and the charged charcoal was removed, pouring it from the collector into a large funnel suspended above a sample container. The sample ID number was tansferred to the sarnple container, which was sealed and placed in a box for transport. The date and time of rekieval were recorded on the same data sheet as the sample placernent information. Sample data sheets accompanied the shipment to the laboratory. Tellco perso6el maintained custody and assured timely delivery of the samples to the Tellco Grand Junction laboratory for prompt analysis of the charcoal samples. t I I t t T I I I I I I I I I I I T I t t 4.4 Site ExitI Upon completion of on-site activities, the field equipment was alpha scanned for possible contarnination t resulting from fieldwork activities. All field equipment was surveyed by IUC Radiation Safety personnel and released for unrestricted use prior to leaving the site. t 4.5 Environmental Conditions Durinq Measurement periods Referencing 40 CF& Parl 61, Subpart W, Appendix B, Method 115 - Monitoring for Radon-222 Emissions, Subsection 2.1.4 - Restrictions to Radon Flux Measurements, "the following restrictions are placed on making radon flux measurements: (a) Measurements shall not be initiated within 24 hours of a rainfall. (b) If a rainfall occurs during the 24 hours measurement period, the measurement isinvalid if the seal around the lip of the collector has washed away or if the collector is surrounded by water. (c) Measurements shall not be performed if the ambient temperature is below 35 degrees F or if the ground is frozen.,' I , site specific Discussion I (a) HJH#?'ffiT:::ffil:*,lJif,?#ffi:#J::"ffi;i::tffitrii#:rflLffJs I ' G) ;:";:;-r*n rainfau events during any of the 24-hour sampre periods after canisterplacement (as indicated by the on-site rain gauge). During rekieval of the- LAACCs in Cell 3 I Beaches region, the seals around fourteen of the LAACCs were observed to be eitherI cornpromised or completely missing due to high winds overnight, invalidating those samples. I (c) During the four 24-bow sample-set placements, the minimum ambient air temperature recorded at I the site was 48 degrees F. ll T t I t I I 5.0 LABORATORYOPERATIONS I , 5.1 Introduction f The large area activated charcoal gas adsorption collectors are passive sampling devices used to determine I the flux rate of radon -222 gas from a surface area. As previously described, and depicted in Figure l, the , collectors utilized a l0-inch diameter PVC end cap, spacer pads, screens, and a steel retainer ring.I Radon gas is adsorbed on the contained charcoal and subsequent radioactive decay ofthe entrained radon t results in the deposition of radioactive lead-2l4and bismuth -214 inthe canister. These radon progeny , isotopes emit characteristic gamma photons, which can be detected.I , fte original total activity of the adsorbed radon can be calculated from these gamma ray measurementsI ffi::ffi:1;:#*ffi:"ffiiffiil1;.H:,:,T;:::T.#dardsc'n'1ainingakn'wn I . 5.2 Apparatus I , ' Single- or multi-channel pulse height analysis system, Ludlum Model 2200 witha Teledyne 3', x 3,' I ' o ;*"::::*,t- welr approximately 40 cm ,rleep with 5-cm thick lead warls and a 7-cm thick I ' . -* J,:::::r, sorution raditm-226absorbed onto 180 grams or activated charcoar calibration source. I r . Ohaus Model C50l balance with 0.l-gram sensitivity. I 5.3 Analysis Procedure I Inspection of the Charcoal Container Charcoal was received at the analytical laboratory in the sealed sample containers. Upon receipt, the I integrity of the container was verified by visual inspection of the plastic container. t I t t I Sample Identifi cation Numbers I Each sample container had a unique sample identification number, which was determined in the field, and wntten onto a label attached to the sample container. I I T I I I Dryrng and Recycling All charcoal was dried/baked before use in the field for radon flux same for newly prepared charcoal and for charcoal recycled after approximately 110 degrees C. Baking procedures were as follows: measurements. Procedures were the field use. Charcoal was baked at into Oven temperature set to I l0 degrees C. Charcoal placed in the oven in a metal baking hay. Baked for a minimumof 24hours. ' Immediately after the tray was removed from the oven, the charcoal was transferred and sealed clean sample containers. 5.4I t TJ I Weiehins and Background Countins Proper balance operation was verified daily by checking with a standard weight. The balance readout should agree with the known standard weight to within * 0.1%.If a discrepant readout were to occur, the balance would be re-zeroed the check weight wiped with a soft, lint-free cloth, and re-weighed. If the discrepancy persisted, the balance would be removed from service and tagged "Out of Service." For this project, the scale conforrned for each day of use (See Appendix A, Balance Operation Daily Check forms). After acceptable balance checkout, each empty container was individually placed on the balance and the tare weight of the containerwas documented to the nearest 0.1 grams on the label. The scale was re- zeroed with the container on the balance. Charcoal was carefully added to the container until the readout registered 180 grams. The lid was immediately placed on the container and sealed with plastic tape. The tape was stretched slightly while wrapping around the container. The end of the tape was folded to form a tab for easy tape removal. The balance was checked for readout drift between each container-weighing step. t I I I I I I I I T I I II I t Ten sets of five one-minute background counts were acquired for 10% of containers selected at random to represent the "batch". Each sealed container was placed individually in the shielded counting well, with the bottom of the container centered over the detector. Five one-minute background counts were then documented for each container in that batch, and subsequently documented on the respective radon flux field data sheet. If the background counts were too high to achieve a sufficiently low sensitivity level. (Lower Level of Detection, LLD), the entire batch was labeled non-conforming and recycled through the dryrng process. Gamma ray counting system checkout was performed as described in Section 5.6. Observed empfy counting well background counts must fall within the established three-sigma range (see Appendix A, system operation performance records) using the aforementioned Ludlum/Teledyne counting system with shielded well. 5.5 Receipt and Weiehins of Exposed Charcoal Containers of exposed charcoal were hand delivered to the Tellco radon laboratory in Grand Junction, CO for analysis. The laboratory staff was responsible for weighing and inspecting the containers of exposed charcoal, reviewing the documentation forrns and entering the required documentation into data base spreadsheets. When the containers were received, the following items were inspected: . Container was closed and sealed with tape. . Container was not damaged. . Data sheet was complete. ' Discrepancies found during the receipt inspection were documented on the data sheet. Containers received open or damaged resulting in seal failure were considered void. Out of the 400 collectors placed during the sampling effort from June 07 - ll,2OO4, a total of 385 sarnples were received at the laboratory in good physical condition and subsequently validated. In addition to the fourteen samples lost from Cell 3 Beaches region (as previously mentioned), one sample from Cell 2 Beaches region was spilled during the retrieval process. l. t I t l'. I I I I I I t t All of the containers that were received at the laboratory were weighed on a balance to the nearest 0.1 I ' Oum and the gross weight was logged on the field data sheets under the appropriate column. I ' ,.u Gamma Rav CountinsI I ilXff:[H ffitry system was subjected to perrormance checks daily when used. rhese I I checks included background and radium-226 calibration source measurements. (Appendix A of this report I contains daily counting system performance check records.) I I SampteAnatysis ,l - ' The length of count time was determined by the activity of the sample being analyzed. A data quality I objective establishing a minimum accruement of 1000 counts for any given sample was followed ; ' ' ; -*pl" --"J::as placed in the counting well with the lid side up and the center on the NarI detector and the shielded well door was set into place. I , ' ffi:f;Ii]" count was accrued and the mid-sample count time and date was docurnented on the field I : ;::"ffi::",",.#:_:_:::"_,':::da'1areduc'ii'n I , ' :"::T"[x']ff11il::::]:'iff]:ff:i,Xfr:"ffi#:[:::f:ffi:;:H?; con,ainers were t r 5.7 Oualitv Conhol Samples I , Charcoal flux measurement QC samples included the following intraJaboratory analytical objectives as required in 40 CFR, Part 61, Subpart W, Appendix B, Method 115,4.0 - Quality Assurance Procedures for I , Measuring Fta-zlzFlux, D.:I . Recounts, lfYo,and I , .. Fieldblanks,5o%. T I I l0 t t T T I II II lI I Samples were statistically evaluated for completeness, precision, and accuracy. 5.8 Data Validation All sample canister data were subjected to data validation protocols. The results are as follows: Forff recount measurements were performed by conducting replicate analyses of individual field samples. These recount measurements comprised approximately l0%o of the tokl number of samples analyzed. The overall precision of all recount rneasurements ranged from less than lYoto 8. ohwith an avetageprecision of approxim ately 4. lYo. Twenty field blanks were analyzed by measuring the radon progeny activity in samples subjected to all aspects of the measurement proc€ss, excepting exposure to the source region. These blank sample measurernents comprised 5o/o of the field samples. The results of the blank sample analyses ranged from 0'04 to 0.14 pCilm2-s. The arithmetic average blank value of 0.09 pCi/m2-s corresponds to less than 1% of the regulatory limit of 20 pCilm2-s (the regional averages reported were not adjusted by the blanks results). The accuracy of the field measurernents was assessed by counfing laboratory control samples with known Ra-226 content in a geometry identical to the field samples each day that the field samples lvere analyzed. The accuracy (percent error) of these Iab control sample measurernents ranged from *l .6% to 1.5olo, with an arithmetic average of -0. lYo (see Appendix A). Ninety-nine samples from Cell 2 Beaches region were validated, representing 99o/o completeness in that region. Eighty-six samples from Cell 3 Beaches region were validated, represennng 86"/o cornpleteness in that region. All of the samples from Cell 2 Cover and Cell 3 Cover regions were validated, representing 100% completeness in those regions. The arithmetic average completeness for the project was 96.3yo. The QC data validation met the objective requirernent for assessing the sampling program's precision, sensitivify, accuracy, and completeness. Reference Appendix B for QC recount analyses results. T I t I I t:, t I t I I I ll I I 5.9 Sample Map PreparationI The approximate sample locations are depicted on Figure 2 and. at the end of this report. The regional I boundaries and other feafures depicted are based on aeialphotography and field observations. t 5.10 Calcutations I Radon flux rates were calculated for charcoal collection samples using calibration factors derived fromI cross-calibration to sources with known total activity with identical geometry as the charcoal containers. I A leld efficiency factor was used to calculate the total activity of the sample charcoal containers. I lndividual field sample result values presented were not reduced by the results of the field blank analyses. I In practice, radon flux rates were calculated by a database computer progam. The algorithms utilized by the data base program were as follows: T I Equation 5.1: pci Rn_222tmrsec : rr.*fr aaorzf.. I [IS'A'D'U.)*" ''] where: N : net sample count rate, cpm under 220_662 keV peak t Ts : sample durafion, secondsr t ;.',x'ff1:'ir:t'iffii','#tor' cpm perpci; varues used: t . 3'1331;!iY-"0,1fl,;3oo".;* between sampre mid-time and count mid-timeA = area of the collector, m2 Equation 5.2: t2 I ! T I t t I I SampleCount, t, min Background Count, t, minError,2o = 2x x Sample ConcentrationNet,cprn t I T Equation 5.3: LLD:#ffiff')",,r d A I I I t I T where: 2.71 4.65 Su Ts b : constant: confidence interval factor: standard deviation ofthe background count rate: sample duration, seconds: instrument calibration factor,cpm perpCi; values used: 0.1 69 4, for M-0 1,4D-2 1 and 0.1823,forM-021D-2A: decay time, elapsed hours between sample mid-time and count mid-tirne: area of the collector, m' I I II l, T t TI I I T 6.0 SAMPLE RE SULTS/CALCULATIONS Referencing 40 CF& Part 61, Subpart W, Appendix B, Method ll5 - Monitoring for Radon-222 Emissions, Subsection 2.1-7 - Calculations, "t}re mean radon flux for each region ofthe pile and for the total pile shall be calculated and reported as follows: The individual radon flux calculations shall be made as provided in Appendix A EpA86(1)' The mean radon flux for each region of the pile shait be catculated by summing allindividual flux measurements for the region and dividing by the total number of fluxmeasurements for the region. The mean radon flux for the total uranium mill tailings pile shall be calculated as follows: r_ = JrArl-.=J:-Az I+l . . . JAJs At Where: J, : Mean flux for the total pile (pCi/m2-s) J; : Mean flux measured in region i (pCi/m2-s) Ai : Area of region i (mr) ,A1 = Total area of*re pile (m2) 2'1'8 Reporting. The results of individual flux measurements, the approximate locations on the pile, and the mean radon flux for each region and the mean radon flux for the total stack [pile] shall be included in the emission test report. Any condition or unusual event that occurred during the measurements that could significantly affect the results should be reported." (a) (b) l3 I 1 I II I I Site Specific Sample Results (reference Figure 2 and Appendix C) I ' ,a) The mean radon flux for each region within each cell is as follows: I ' aell 2 - Cover Area : l2.6pCi/m2-s (based on264,973 mz area) I - Beach Areas : 73 .7 di/m2-s (based on 5,651 m2 area) T Cell3-CoverArea : 7.9pCilm2-s(basedon 148,099m2area) - Beach Areas : 38.5 pCi/m2-s (based on 50,515 m2 area) - Standing Liquid Areas : 0 pCi/m2-s (based on 90,244 mz area) Note: Reference Appardix C of this report for entire summary for individual measurement results. t 1 ", "t,1il:;:,"" O*t"nted above, we have calculated the total mean radon flux for each pile (cell) as I , cer2:l3.epci/m2-s I W I , cer 3: ro.8 pci/mz-s (7.9X148.099) + (38.$(sO.sls) + (0X90.244) t ., '88'8s8 I , Os presented above, the results of the measurements are below the regulatory standard of 20 pCi/m2-s. 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ScalerS/II: 6 ri f :- (iil'c') Highvortage: l i o c window: 4.42 Thrshld: 2.20 DerectorslN, C 4 i533 tD-Zi) SourcerD/sN,R.o,7'b /G9r-ot+Sotuce Activity: 51 ,-3 {'P(; Blank Canister Bkgd. Range, cpm: 2 o: I \ C to i5Z to: 44 to i b-)> Gross Sowce Range, cpm:z": ) Y17 t ic 437 3o: ql +c n i o5-7=- rechnician: Y7 I 2r"f- CHARCOAL CANISTER ANALYSIS SYSTEM Y/N: Y: average background and source cpm falls within the conkol limits. N - average backgrormd and source cpm does not fall within fte control limits. The acceptable ranges were determined frorn prior background and source check data. I I I T I I I I I I l' I CLIENT: i ,t { 't r' r''\ 4'1 t r..- ; ,,-. All counts times are one rninute. Date By Backsround Counts (1 min. each)Source Counts (1 min. each)ok? YAJ#t #2 #3 Avg.#1 #2 #3 AveraseLlt i i;+t)t L.t,r,r'Lq \41 i /rZ \44 otql i(i/r"1<ir:744 to33qI tt4. ir-;/;l)i1e..*irq \ztL [i-c) I .t1?iOrr-{i r'rt'z l?i o l-t.l 1,\/ i,. I i,t. lc t,)/jci,iau \+i i'l t:3 ci\4 lc'2- lq talqu,t c tnor livio +)l.C*ic t"- I \3t1 1q(}' -:'-+L,C,.A +IO 24fi totl+tQlraQi^.f t) LIpc*i7 "<t?*4-t1t ,.'7 a iaar t <l{) V41 I O2.?A lo Zu.€tl tl lo4-"t/ t;,,i \2,0 \4:-i5'L 1{: | 4-4 iC iZr tfi.) I ,0t?jt I l, ' I t t ,' I ,',l:.jl,,t ti. 1., l, l'i' I 1, "'" ll I l' "' I SITE LOCATION: CHARCOAL CANISTER ANALYSIS SYSTEM .,-,.1 t* Calibration Check Loe Calibration Date: '-; 123 ,i .{ i. DueDate: -J ,'23,, i ,]- ScalerSA.l: --' , -i -l 'Z ,. i"i - r- ;i HighVoltage: I i C'{-' Window: 4.42 Thrshld: 2.20 Detectors/N: a'1 Ii;:j i*ai 7 \}SourcelD/sN: ili..ttt,,r''f--'-.-L-r-sou.".Activity:-i?,;f pf; BlankCanisterBkgd.Range,cpm:2o: ilO a i5'L 3o__ ,1?t to tL3 Gross Source Range, cpm:,r* z.OdCl * ic31{lto: 440J ,o tc4-73 Technician: L)l (t',1 .. Y,Ai: Y = average backgro,nd and source cpm falls within the control limits.N: average background and sowce cpm does not fall within the control limits. The acceptable ranges were determined fiom prior background and source check data. All counts times are one minute. Date By Background Counts (1 min. each)Source Counts (1 min. each)ok? Y/NHI#2 #3 Avs.#1 #2 #3 Averase t 5i':,*DlJ"n',.z,a | /Y'7 i +'2-:Ji Q) ij'C/{r5 !;!i -, r;)s)-'rf ! 4z+t7 "7 l?:i l!:i :, {c'4-iC<2r i (.'-.?.7 ai- ! ,. J .. ;iUttr/-+'f7X-i{.t tt{-i)?iiic ir :)c)i l (-r{ (/, :)i C:,I.;AI1 !liiit;,*I l: !i -].- I i7i)?_+},.1 -il i cltz 3 q qbT i'Jlai:?- []1L,..,^)'i <'.:t fi l1r &:l i' 41- >i -'(- IJ /,'? 1( 'l-7))) 3c:t A-7..at t .1..-yli7 )t -1 .!' I ..4\1: 't'/i 1i)(?->-t- I I T I I t I I t t I T t I l. I t t I CHARCOAL CANISTER ANALYSIS SYSTEML sIrELocArroN, ''^i l,'*: \Lt r ',.', i r ;' , ii t,. .,. .7,,,,, u(f-__________+_rj , CLIENT: Calibration Check Loe SystemlD: Y\-O Z I n ZC cahbration Darc: 4 f :Z )> f L,zi oueoate: /l I 2.3 f : .{ scalersN: -5 | 5 G 3 (v\- ,.t-) Highvottage: -7 SCt window: 4.42 Thrshld: 2.20 DetectorS4.I' o4IS 3 Z Iii zc) sourceID/SN, frrrz''"/GS-oqsourceActiviry: aj,?.i /-5:t(t Blank CanisterBkgd. Range, cpm: 2 o : I i O ro lut-3 3o:q1 to l1a Gross Source Range, cpm:2a= lC7@; to t\\-7;1)3o: tOGAI to tlZ't>t Technician: YN: Y : average background and source cpm falls within the control limits.N: average background and source cpm does not fall within the control limits. The acceptable ranges were determined from prior background and source check data. All counts times are one minute. Date By Background Counts (l min. each)Source Counts (1 min. each)ok? YAJ#1 #2 #3 Avs.#1 #2 #3 Averagea l, \/nt i-tr'/,'.l+t aa tv I i3B lCir.q'i;,i Q ti.4 1"I s 9'74 lc b'14-V z l i;l()L )l L-jLj,llv iz- l rE r la)1 tlQA2 rOq r>l* 22-ltul c 4-Y,r,-h"llpi i'7-?,72-t'LV tr-. tzl-to'zs(\oi'?I(:)VatL''/ it..'/ t l,l+4 I L<-| ,L'7-t-1 -l ra F. (:) \-1rf i I Q'4 1,-<tf:ftr44/e'1;=ioii,w* L,*'n I t-ttj t14 i- O t'1 r o.Q,'?_q t r.?A-i,).4rtl.c'n'2 r,,',ti'l ii,l ?,//;A )41 1An \+t IO'7G \ 014q i a4;?<t i)A a I t I I I" I I. :: I I I t i t :; I I l. I I ,ll T I ScalersA.r: 5^ f S u i Lp'r'aZ\Highvottage: -i 5t, . window: 4.42 Thrshld: z.z0 - Detector saJ: J; + t-s3'Z Cn -ZO) Sowce rD/sN:SourceActiviy, Sl 7 f f(i Blank Canister Bkgd. Range, cpm: 2 o: I \ C to lb3 3o: 71 to 171 3o: iOrcZt, to il I. l bGross Source Range, cpm:2o: lC-]L4- to l\\t1 rechnician: Y>i (y* Systern ro' l,\ - C'-Z / Tr Z C CHARCOAL CANISTER ANALYSIS SYSTEM i Calibration Check Loe Calibration out", 4 I Z => I .''4owoarc, 4 [ 2 3 I a 1l' ') YA.{: Y = average background and source cpm falls within the control limits. N : average background and source cpm does not fall within the control limits. The acceptable ranges were determined ftom prior background and source check data srrELocAneNr. ,r\i h,l l\'\{ (r, i\'\ \\ , 1r, I ,,,, 4l ,,,.', .,i j ,; GLIENT: i ,,, l. -r 'r n, ,. I ', I r', :'', i Ll d't1 r\ rL', ',-.71 L o ,- st All counts times are one minute. Date By Background Cormts (1 min each)Source Counts (1 min. each)ok? YN#t #2 #3 Avs.#l 4a #1 Average 'z/ i 5lt',DLL.,,;,\+l t+f tvl t3t-)I Co{4:i tO a.-7 4-!r:7-'1 -3 lL, g!4n 'n I ti l;i4-\],/ LI"-A tjb 2-.1 I 1'-)I 1t t () ?*,.'\ I tG2-l 0,n 72-L L}? Lb ,",, bllal c:*-D/i:at It)t"?*Ft lZ'z*\:LV i041L I () U:',jl u:rC4?a i., li',. I ii,)t4.,;;!*r /.{r 2-1 I 42-\ 1'-7 lc,:t l4s t C 7t'L,1c,.2 D I iL\,a?t{";ltl/c*7/J.,\.2r4-t2-C)lVt i or+2-1 tD4,+5 tCfl'3 t >trGb ty t?!!-i{nL-Dt-l;atv-t+1 t3 U,t ^P3 t a-l lC?: -4 7 il OLt2 i\ CE-"-<cf-i+ BALANCE OPERATION DAILY CHECK BalanceModel: C h*ir, t {- 5C'i " 7,:.1 * c\,n'?t+1" t; l.,, l7-'i':;'} _ --.,r..: 'P-\Standard Weight (g): z i '*' t-' I I I l' I .t I' ,- ::, LlIi ll '1t, ti l', :t fl, t, i, ', i,: I li "' I t .,, i. , lu' I Date Pre-check (g)Post-check (9)o.K.r0.1%?By ,,,ftsloa-z-co.c LC-o, c)v (5 \)/ r",,6_ (",f n" l'lj-z- oc'J ;ii'O.O aj 45 D /r',-rr- .t-iG / | I / L',11 ?-o0 . C,':_'-'r' , L)v f': f1\.- i /+;l-,L (di-W-\ t I I I I ! j I i I I 1 I IJ l, t t1 I I I I APPENDIX B QC Recount Data ? m rJ t}]o rl () U)d OJ t;lo IEIr,I t:lprIEIUl4 I r,It@ l-lrfl'1EIU r,tEH xoE zoHmHU FTHp{ EtrlUfrHtr F](, frE] 4 irF dP irp orp dp oF dp o\o dp optoo't.r;:,orA:14ocod to c! t',-' * "; * d ; ; ; .:.: ..: : : ,,A. o\ m .<. or .n '|b,,'riil, or .n A.i,. ot .. a ;. o\ mrr orr or-r or-r oJ oJ o; o; 6j od.o o o o...<) o o o (> o o o o o o d d o o (f, o) t t T I I t t T I I I I I I I I I I I Q c.ro-'PKi Or 11 Fro tno..6b . ..r{ F i.,Jd01: 6:,.:;.'i+ ')',,: ,,,.. ''lr.: .r't .f,i:,,,it*i+,,'t*.,t\i;,,:rtt,:. :,1,:1,:): I i(Jt;i#,',u? i{66a, lq "'ir i+,a l.:..'r .. 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Lr-l JO I t I I I t t I t I t I I I T I I I I oo Q c.rE*a- Ol::oo 11oo r-N:ioo @ool .o oo 11(\ (..lr{ rlci c\l rl@coooorJ ri <r D-.o ciNR rn cniH ii<r rirrl -ic\i N OrN\o$oo rJ F{ U)lr)'i:; 9r <*r 9.,gd <;Oaoo-*=g:6fr E*k[lE= \o t..rl rl\o a-i-l r-l ooNN oo NN \o \o co@ \0 \o Ot ol oo rf)m mrarnm (o r.,aoa.- O'+f;d--ildlq dff=B LUO?o.Rt', Sa ()=tZ-6_;(,9! a,.ci>!{ aIgqE -H3*: *dtse= ffi =t! Fa F c./)<)(D =fr=6 =^O(, FYlJ-tz z --FFl'.'.iaz o5pd3 Io.<ILQ d. @@ ooNNUU ... Fl OD.c.toUU,' Eld,::jfr;a: .l qI o C)tr'dOl i t;loIr{C'r'l* I o r'1xfrl oU N Fflf EIU ts] H NoE{ oH crrHUtrlilA EtllUilE]A trlu4d r'1 4 {dPI.dPotsoFoF+dpc).oda o .ri F- ..t Lrr t- n A d. 'i:. ., .l ... . .. . oo =FAT"(9 =LU-B LU(. F c2 OZ d o(e': C) o z xtr ! oLU-L<F- =LUo-B )I U)til2 LUFIB U'FzuJ Lr-tcl =a LU xfJLL z. O n F(-) LU-otL a:l O =az. LLIJo I T I I I T I I t I T I I I t I I t I \o l- tO '. €6. \o a- icl 'e. \o r- fO do \o r-o o ,c,u:Q... o o o <> o o o o o o.:i' :..:, ..o o oi!r,' o o o o o o .o (, o o \o .9: \o r--o.o. o o ' '-'.'::; .: ":o"e,.(, o o 9nOJ6 Xi d d ilr-{ N.n o o .o:6 0o ilr"t4 !,1!1 '.;.g:,'O rl rl .1,'t:,"4, a{ c{ C, O :ii .r1:. o O '',:, .: , . -,: :1'o o ifr:,:'.V:,, \o ulm b ..1.a':: .'/t '€1'l:'::llil r'l rlo o '*4:::::ir:i' . ' .,.1::: '' '-l)1":.;:::.,.1,,r:.j:. 1:n 't':@ @ riitj::4.';, co @ rnm :tilij;t;#,. Nc.rr{ rr f.J;:11.15::;t rt ..1N N !!l,:ad.: ct c! -!... : ... ; .' a:::.t.!'-o ra ril.; Fr,, \D Orco or .W..(r.,, N \oc.r rr :A:.'*, c,l orl rl 1$1',:f,4, rJ rl .r,. '. Y1 NOI ??if \tlNN YY NNri rJNN o\ \oo@rlOl'- \o '$.,.,:{'l 'il $ '::1. 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'zoI)d,,oAUrn j:r,,.: ;ii.,!i,'r.fi .1...i.J*..;::it;:!/it!?::,t1,,!;1" _6T-A1,+,'b,Fl. r 6\F,i:,:,:7;/.? .t', 1:. i;,;.,ii:..::, ,.;,:.)l::i.:t': .,j,t:?;l'f.. a,Hit#,: .::.:ti.::::..: Xil'$w.!tW 't:,::,li;,i:., oo$s'oo APPENDIX C Individual Field Samples Results and QC Field BlankData o) o) /<IY(,;g tut Foo oz.O=a-d de-: o o(Jzz IYb IUo) LU .L 'f-l-t_*utt= U)) ) Fz[tlo t I I I I I I I t I T I I I I I t t I .q.,q o o.lsl'tqr! o o|p'g) o o,ij o o or o o\ o or o.o\ o o1 o 01rr o.:r1 o .i.7:,..9 .r o ir,. . -{ o il1.o i o ; o ; o ; 5 i o .i oooooooooooo oooo oooo ooo oooo 9 c.r Ep : N Ir-N ? rlN o\o t) rl \o @rl sfl tr)rJ \o ol ar <lo dlo n co, or bfr,, .,'E _i i^..,^a'rt.v vr e*, E_i f;,='= , fr.Q. o: roFH:1d \OI -J 7::Y! \$'.t?ta:t:;f;.' f.i'L': : j'1. t"o;,;*-.l' .|i,..;>t'.t'(t'r;a4 co hrN;-,iJ- o ir.ry "t\- Nl' | :,, 1: nirL lr.ui: tl olt} tO, -li 9C^ \o. 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