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DRC-2021-007429 - 0901a06880ea0288
State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF WASTE MANAGEMENT AND RADIATION CONTROL Douglas J. Hansen Director Div of War4-te Management and Radietlon Control MAY 1 9 2021 MEMORANDUM TO: Phil Goble P116 c5-- /1/202- FROM: Dean Henderson DATE: May 19, 2021 SUBJECT: Review of the February 10, 2021 Annual Seeps and Springs Sampling Report for Energy Fuels Resources (USA), Inc. White Mesa Uranium Mill, near Blanding, Utah On February 16, 2021 the Division of Waste Management and Radiation Control ("DWMRC") received the February 10, 2021 Annual Seep and Springs Sampling Report ("Report") [eDocs: DRC-2021-002283] for the Energy Fuels Resources (USA), Inc. ("EFR") White Mesa Uranium Milt ("Mill"), near Blanding, Utah. For the review of this Report the following regulatory enforcement documents will be used: • White Mesa Uranium Mill Ground Water Quality Assurance Plan ("QAP"). Revision 7.5, dated June 6, 2019. • Groundwater Discharge Permit No. UGW370004 ("Permit"). Permit version that was signed on March 19, 2019. • Sampling Plan for Seeps and Springs In the Vicinity of the White Mesa Uranium Mill. Revision 2. July 8, 2016 ("Plan"). • Utah Department of Environmental Quality Division of Radiation Control Guidance for Groundwater Split Sample Collection at Uranium Mill Operations. August 7, 2007. Summary of Compliance EFR informed the DWMRC in a letter dated June 1, 2020, that EFR would be sampling the seeps and springs on June 16, 2020 (DRC-2020-010821). This letter providing a 15 day notice prior to sampling as required in Section 3 of the Plan. The Report met all of the following reporting requirements in Section 6 of the Plan: 1) Documented the sampling event by means of providing the field sheets recorded at the time of sampling. 2) Provided copies of all field measurements and laboratory results. 3) Provided a water table contour map that includes a water table elevation of all groundwater monitoring wells at the facility (3rd quarter 2020 water level measurements) and the elevations of the phreatic surface observed at each of the seep and springs sampled. - 4) Provided an evaluation and interpretation of the groundwater quality data collected. DRC-20 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144880 • Salt Lake City, UT 84114-4880 Telephone (801) 536-0200 • Fax (801) 536-0222 • T.D.D. (801) 536-4284 www.deq.utah.gov Printed on 100% recycled paper Page 2 On June 16, 2020 DWMRC staff Dean Henderson and Phil Goble observed the EFR staff sample Cottonwood Spring, Entrance Spring, Ruin Spring, Westwater Spring. DWMRC staff collected a split sample with the EFR staff of Entrance Spring and Westwater Spring. The EFR staff had previously collected a sample of Westwater spring on March 25, 2020. At that time Coral Canyon and Corral Seep were found to be dry and therefore no water sample could be collected. DWMRC staff field observations are documented in a memorandum (DRC- 2020-020081) and closeout letter (DRC-2020-011964). Based on DWMRC staff observing the EFR staff perform the sampling and monitoring and after the DWMRC review of the Report, it appears that EFR appropriately followed the QAP and Plan. Duplicate Sample Comparison Comparisons of duplicate samples analytical results are summarized in Tables 6 in Attachment 1 below. To determine if sample results between two samples from the same laboratory are comparable, a relative percent difference ("RPD") of 20% is acceptable (DRC 2007). To determine if sample results between two samples from two different laboratories are comparable a RPD of 30% is acceptable (DRC 2007). For radiologics, to determine if sample results between two samples or two laboratories are comparable, a replicate error ratio ("RER") of < 2 is acceptable (DRC 2007). EFR Duplicate Sample Comparison EFR collected a duplicate of Cottonwood Spring and identified it as "Back Spring". The RER comparisons for gross alpha < 2. The RPD comparisons between the analytical results were all below 20% with the exception of TDS at 39.3% (862 mg/1 and 1280 mg/1). Since 2009 annual TDS results for Cottonwood Spring have ranged from 900 to 1100 mg/1 and that TDS analytical results are close to historical concentrations it is recommended that no further action is necessary to resolve this RPD exceedance. All other the analytical results are comparable (see Table 6). DWMRC Sample Comparison to EFR The RPD comparison between the analytical results for the DWMRC Entrance Spring and Westwater Spring samples and EFR Entrance Spring and Westwater Spring samples were below 30% with the exception of the following contaminates summarized in the table below: Contaminates GWQS EFR Entrance Spring Results DWMRC Entrance Spring Results RPD Nitrate 10 mg/1 2.46 mg/1 1.8 mg/1 31% Manganese 800 pg/1 56.3 ttgn 29 ttg/1 64% EFR Westwater Spring Results DWMRC Westwater Spring Results Manganese 800 ttg/1 35.4 ttg/1 430 ttg/1 169.6% Uranium 30 ttga 12.9 ttga 3.5 ttg/1 114.6% Sulfate none 307 mg/1 480 mg/1 44% Sodium none 245 mg/1 160 mg/1 42% Potassium none 5.28 mg/1 3.4 mg/1 43.3% None of the above contaminates in the table above exceeded GWQS and concentration were within or very close to historical concentrations. Therefore, it is recommended that no further action is necessary to resolve this RPD exceedance. All other the analytical results are comparable (see Table 6). The RER comparison between the gross alpha analytical results for the DWMRC Entrance Spring and Westwater Spring sample and EFR Entrance Spring and Westwater Spring sample were <2 and comparable. Page 3 Mill Operations Impact on the Seeps and Springs. The analytical results for the 2020 seeps and springs monitoring event are summarized in Tables 1 through 6 in Attachment 1 below. Cottonwood Spring EFR collected a duplicate sample of Cottonwood Spring and identified as Back Spring. Nutrients ammonia and nitrate were concentration were non-detected typical of historic concentrations. The only metals detected was uranium below its GWQS and typical of historic concentrations. No VOCs were detected. Major ions were detected. A comparison of the historic data since 2009 data shows that the concentrations of most detected analytes remained approximately the same with no concentrations exceeding GWQS. Overall, the data reported Cottonwood Spring sample results appear to show no indication of Mill impact (see tables 1 and 2 below). Entrance Spring DWMRC collected a split a sample of Entrance Spring with EFR. Ammonia had non-detectable concentration and nitrate had detectable concentrations well below GWQS and typical of historic concentrations. The only metals detected were manganese, molybdenum, selenium, and uranium that were below GWQS and typical of historic concentrations. No VOCs concentrations detected. Gross alpha was below GWQS. Major ions were detected. Historic data since 2009 data shows that the concentrations of most detected analytes remained approximately the same. Overall, the data reported for Entrance Spring sample results appear to show no indication of Mill impact (see tables 1 and 3 below). Ruin Spring Ammonia had a non-detectable concentration and nitrate had a detectable concentration well below GWQS and typical of historic concentrations. The only metals detected was molybdenum, selenium, and uranium. None exceeded GWQS and typical of historic concentrations. No VOCs concentrations detected. Gross alpha was below GWQS. Major ions were detected. A comparison of the historic data since 2009 shows that the concentrations of most detected analytes remained approximately the same. Overall, the data reported for Ruin Spring sample results appear to show no indication of Mill impact (see tables 1 and 4 below). Westwater Spring EFR collected a sample at Westwater spring on March 25, 2020 and DWMRC staff collected a split sample with EFR June 16, 2020. Page 4 Ammonia and nitrate had non-detectable concentrations with the exception of ammonia in the March 25, 2020 sample that was well below GWQS. All had typical historic concentrations. The only metals detected in the EFR May 25, 2020 sample was iron, manganese, and uranium. None exceeded GWQS and typical of historic concentrations. The only metals detected in the June 16, 2020 EFR and DWMRC samples was cobalt, iron, manganese, molybdenum, selenium, and uranium. All metal concentration were below GWQS and typical of historic concentrations. No VOC were detected, and gross alpha was below GWQS. Major ions were detected. Overall, the data reported for Ruin Spring sample results appear to show no indication of Mill impact (see tables 1 and 5 below). Conclusions on Compliance with the Permit and QAP Per the Division review it appears that the Report complies with Permit, QAP, and Plan. Therefore, a letter will be drafted notifying EFR of the review and closing out of for the Seeps and Springs 2020 Monitoring Report. Page 5 References Energy Fuels, White Mesa Uranium Mill Ground Water Quality Assurance Plan, Revision 7., June 5, 2019. Sampling Plan for Seeps and Springs In the Vicinity of the White Mesa Uranium Mill. Revision 2. July 8, 2016. Energy Fuels, White Mesa Uranium Mill Annual Seeps and Springs Sampling, June 1, 2020. (DRC-2020-010821) Energy Fuels, White Mesa Uranium Mill 2020 Annual Seeps and Springs Sampling Report, February 10, 2021. (DRC-2021-002283) Utah Department of Environmental Quality Division of Waste Management and Radiation Control, Memorandum, 2020 Annual Seeps and Springs Monitoring, June 29, 2020. (DRC-2020-020081) Utah Department of Environmental Quality Division of Waste Management and Radiation Control, 2020 Annual Seeps and Springs Monitoring Event Closeout Letter, July 13, 2020. (DRC-2020-011964) Utah Department of Environmental Quality Division of Waste Management and Radiation Control, Memorandum, 2020 Annual Seeps and Springs Monitoring, June 29, 2020. (DRC-2020-020081) Utah Department of Environmental Quality, Groundwater Discharge Permit No. UGW370004 Permit version that was signed on March 19, 2019. Utah Department of Environmental Quality Division of Radiation Control Guidance for Groundwater Split Sample Collection at Uranium Mill Operations, August 7, 2007. Page 6 Attachment 1 Tables 1 through 6 Table 1 Summary of The 2020 Seeps and Springs Sample Analytical Data (1) Contaminants (2)GWQS (for comparison purposes only) Cottonwood Spring -- BaCk Spring (EFR . Duplicate of Cottonwood Sp mg) Entrance . Spring (EFR sample) Entrance Spring (DWMRC sample) Rui'n Sprng i Westwater Seep Westwater Seep (EFR sample) Westwater Seep (DWMRC sample) 6/16/2020 6/16/2020 6/16/2020 6/16/2020 3/25/2020 6/16/2020 Ammonia (as N) 25 <0.05 <0.05 Nutrients (mi/L) 1.8 <0.1 <0.05 0.0593 <0.05 <0.05 Nitrate + Nitrite (as N) 10 <0.1 <0.1 2.46 1.8 1.39 <0.1 <0.1 <0.1 Heavy Metals (ig/L) Arsenic 50 <5 <5 <5.0 <5.0 <5 <5 <5 <5.0 Beryllium 4 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <1.0 Cadmium 5 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <1.0 Chromium 100 <25 <25 <25 <3.0 <25 <25 <25 <3.0 Cobalt 730 <10 <10 <10 <1.0 <10 <10 <10 1.0 Copper 1,300 <10 <10 <10 <2.0 <10 <10 <10 <2.0 Iron 11,000 <30 <30 <30 <100 <30 401 <100 Lead 15 <1 <1 <1 <1.0 <1 <1 <1 <1.0 Manganese 800 <10 <10 56.3 29 <10 369 56.3 430 Mercury 2 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.5 <.2 Molybdenum 40 <10 <10 <10 3.7 18.7 <10 <10 3.5 Nickel 100 <20 <20 <20 <2.0 <20 <20 <20 <2.0 Selenium 50 <5 <5 15 16 10.5 <5 15 <5.0 Silver 100 <10 <10 <10 <1.0 <10 <10 <10 <1.0 Thallium 2 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <1.0 Tin 17,000 <100 <100 <100 <10 <100 <100 <100 <10 Uranium 30 10.5 10.7 24.7 25 9.32 2.34 12.9 3.5 Vanadium 60 <15 <15 <15 <5.0 <15 <20 <20 <5.0 Zinc 5,000 <10 <10 <10 <10 <10 <10 <10 <10 Radiologics (pCi/L) Gross Alpha 1510.256+1-0.209 -0.00212+/-0.191 10.453+1-0.229 2.54+/-1.58 -0.423+/-0.231 0.559+/-0.300 10.119+/-0.191 2.86±2.4 VOC (pg/L Acetone 700 <20 <20 <20 <10 <20 <20 <20 <10.0 Benzene 5 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 2-Butanone (MEK) 4,000 <20 <20 <20 <6.0 <20 <20 <20 <6.0 Carbon Tetrachloride 5 <1.0 <1.0 ,0.1 <1.0 <1.0 <1.0 <1.0 <1.0 Chloroform 70 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Chloromethane 30 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <2.0 Dichloromethane 5 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <2.0 Naphthalene 100 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Tetrahydrofuran (THF) 46 <1.0 <1.0 <1.0 <7.0 <1.0 <1.0 <1.0 <7.0 Toluene 1,000 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Xylenes (total) 10,000 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <1.0 <2.0 Others Field pH (S.U.) 6.5 - 8.5 7.09 7.09 7.73 7.5 7.19 7.32 6.4 7.9 Fluoride (mg/L) 4 0.233 0.24 0.638 0.54 0.473 0.555 0.638 <0.5 Chloride (mg/L) NG 146 147 76.7 75 25.8 26.6 76.7 36 Sulfate (mg/L) NG 417 424 317 300 474 307 317 480 TDS (mg/L) NG 860 1,280 964 870 1,240 1,200 964 1,100 General Inorganics Listed in Part I.E.1.(c) 2)(ii) Carbonate (mg/L) NG <1.0 <1 NA <1 <1 <1 NA Bicarbonate (mg/L) NG 280 284 242 NA 186 270 242 NA Sodium (mg/L) NG 273 282 108 91 139 117 108 160 Potassium (mg/L) NG 7.14 7.23 4.31 3.8 4.09 1.76 4.31 3.4 Magnesium (mg/L) NG 32.9 33.7 45.1 42 36.9 30.8 45.1 44 Calcium (mg/L) NG 120 124 144 120 169 118 144 160 Total anions (meq/L) NG 18.4 18.7 13.7 NA 14.2 12.6 13.7 NA Total cations (meq/L) NG 20.8 21.4 15.7 NA 17.6 13.6 15.7 NA DWMRC = Utah Division of Waste Management and Radian Control EFR = Energy Fuels Resources NA = Not analyzed. Shaded = exceeded Ground Water Quafitty Standared (GWQS). However, the GWQS are for compahson perposes only and are not compliance standards for this spring. 1. Contaminants listed in Table 2 of the Groundwater Quality Assurance Plan for EFR. 2. The Ground Water Qualtity Stantandards (GWQS) are for compahson perposes only and are not compliance standards for this spring. (4)GWCtS (for comparison only) 7/25/1977 (1)D&M EFR 11/10/1977 7/7/2009 (3)Contaminants Ammonia (as N) 25 0.13 <0 1 <0.05 Nitrate + Nitrite (as N) 10 0.06 0.261 0.1 Arsenic 50 T<10 NA <0.05 Beryllium „4 .1`1!? N/,'k <0.5 Cadmium 5 T4 T2 <0.5 Chromium 100 T20 "r<10 <25 Cobalt 730 NA NA <10 Copper 1,300 r<5 <10 iron , Lead 11,000 „18 3,,200 11p t,<50 <30 <1 Manganese 800 1100 60 <10 Mercury „ ? T2 T.1 <0.5 Molybdenum Nickel 40. .190 <19 NA NA- NA „ <10 <20 Selenium 50 140 NA <5 Silver 100 4 NA <10 Thallium 2 NA NA <0.5 Tin 17,000 NA NA <100 Uranium 30 4 niA 8.42 Vanadium , 60 6 <io <19. Zinc 5,000 60 156 <10 Gross Alpha 15 10.2±3.1 NA 10.3+/-0.5 Acetone 700 NA NA <20 Benzene „ NA N!N. <1.0 2-Butanone (MEK) 4,000 NA NA <20 Carbon Tetrachloride 5 NA INV! . <1.0 Chloroform 70 NA NA <1.0 Cnloromethane 39 NA N!N. „ <1.0 Dichloromethane 5 NA NA <1.0 Naphthalene 100 NA 1•!, . <1.9 Tetrahydrofuran (THF) 46 NA NA <1.0 Toluene _ 1,000 NA NA <1;p Xylenes (total) 10,000 NA NA <1.0 1 151DRC EFR 07/06/10 7/7/10 <0.05 0.08 <0.1 EFR EFR 5/31/2011 7/13/2011 <0.05 <0.05 0.1 <0 1 < 0.10 <5 <0.5 <0 5 <25 <10 <10 53 <1 <10 <0.5 <10 <20 <5 <10 <0.5 <100 7.87 <15 <10 <5 <0.5 <0.5 <25 <10 <10 <30 <1 <10 <0.5 <10 <20 <5 <10 <0.5 <100 . 8.68 <15 <10 <5 <0.5 <0 2 <5 <9 „ <9 <?9 1.33 24.4 <0,2 <8...... <5 5•74 <5 <1 <25:: <10, , „ 1;1:3 <10 <5 <0.5 <0.5 <25 <10 <10 <30 <1 <10 <0 5 <10 <20 <5 <10 <0.5 <100 8.24 <15 _ <10 <1 <9,5 < 5 <1 0 326 252 2-54 280 . .. , „ 247 198 , 194 217 6.2 9-0 , 6.1 5.53 27.7 29.9 24.7 23.6 101 89.9 89.9 87.9 17 ts,k,e,k , , , , , NA , 17 3 18.2 NA NA 15.9 5 Sample collected by DRC/DWMRC. D&M = Dames and Moore DWMRC = Utah Division of Waste Management and Radian Control EFR = Energy Fuels Resources <1.0 251 ??7 6.18 29 99 7 17.3 , 15.9 <10 <1 0 <6.0 <1.0 <1 0 <2.0 <2.0 <1.9 <7.0 <1.0 <2.0 <10 <1 0 <6.0 <1.0 <1.0 <2.0 <2.0 <1.0 <7.0 <1.0 „ „ <2.0 <20 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 7.3 7.83 7.86 0.318 0.37 0.37 133 130 130 5 2 <0.2 <2 0 „ „ <2 0 <5 0 <1.0 <1.0 <10 8 5 <5 0 <10.0 4.27+/-2.10 <5 <1 <1 <1 <1 1.92 <1 <1 <1 <20 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 0 „ <1.0 <20 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <1:0 <1.0 <1.0" <1.0 <20 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 7 34 0.35 109 386 1080 8.04 0.38 134 389 978 7.47 7.55 0.38 0.34 112 113 389 394 900 1030 5.7 <2 <1 ..., <1.9 9 197 340 330 316 221 214 , 229 227 3 ' 26 ' 5277 6 5.9 32 6 , 24.8 25.2 25.2 90.. ' 8 92.2 95.4 94.2 14,k. 22.3 16.8 17.3 NA 21 8 17 16.8 1, Dames and Moore January 30, 1978, Environmental Report White Mesa Uraium Project San Juan County, Utah, Energy Fuels, Inc 2. THF sampled on November 3, 2010. 3. Contaminants listed in Table 2 of the Groundwater Quality Assurance Plan for EFR 1 4. The Ground Water Qualtity Stantandards (GWQS) are for comparison perposes only and are not compliance standards for this spring. F.100, p!-4.(:!-L) p.5 - 8 5 .7.0 8.1 7 3 Fluoride (mg/L) 4 0.5 0.4 Chloride (mg/L) NG 1 71 124 Sulfate (mg/L) NG 333 243 383 TDS (mg/L) NG 1270 780 1,010 Carbonete,(mg/L) , NG <1 <1„ <1 Bicarbonate (mg/L) NG NA NA " 316 P9041191,10-1 NP . , 4,00 11,5 205 Potassium (mg/L) NG 6.6 4.3 ' MNr.1,§iYr.n (TO-) „ NP„ , , , _19 , 28 „. 25 Calcium (mg/L) NG 58 133 90.3 rn Total anions (eq/L) NG NA NA 16.7 Total cations (meq/L) NG NA NA 15.6 .214t4gis1. 0.5+/-0.4 0.1+/-0.2 -0.1+/-0.4 1-0.2 +/-0.2 0.198+1-5.75 0.127+/-5.02 <1.0 <0 05 <0.1 l<0.05 EFR <20 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.9 <1.0 7.53 0.38 149 356 1,040 Table 2 Historic Cottonwood Spring Sample Analitical Data up to 2020 Sampling Event 151DR EFCm ( uplicate) (split (st 15113WMRC 151DWMRC sample with D ' 'DRC 1 EFR EFR EFR (split sample with (Duplicate EFR) "Spring 1") 6/20/2012 7/16/2013 6/17/2014 6/16/2015 Nutrients (mg/L) 0.061 0.05 <0.05 <0.05 0.05121<0.10 l<0.10 <0.05 <0.1 <0.1 <0.1 <0 1 l<0.1 Heavy Metals (pg/L) <5 <5 <5 <5 <5 <5 <5 <1 0 <1 0 <0.5 <0.5 <0.5 <1 0 <1.0 <1 ,o, 1.q <0.5 <0.5 <0.5 <1 9 <1.9 . <3.0 <3 0 <25 <25 <25 <3.0 <3.0 <1.0 <1.0 <10 <10 <10 <1.0 <1.0 <2_ <10 <10 <10 <2 :100 , , <Apo, <30 <3.9 <30 <100, <100 ,. <1.0 <1.0 <1 <1 <1 <1 0 <1.0 <9.? . 2.66 <10 <10 <10 4 9 <2 <0,2 , , , <0.5 , <0.5 <0,5 , <0.2 <2 3.31, <10 <10 <10 <2 <2 <20 <20 <20 <20 <5 <5 <5 <5 <5 <2 <2 <10 <10 <10 <1.0 <1 <1 <0.5 <0.5 <0.5 <1.0 <? . „ <100 <100 <100 <10 .62 - 8 3 .o.i7 1,4.p 8.95 9 9.12 <2 5.37 5.38 <10 <10 7.63 7.25 0.34 0.417 113 118 128 374 403 417 1040 1,020 968 General Inorganics Listed <15 <15 <15 <5.0 <10 <10 <10 <10.0 Radiologics (pCi/L) <1.0 10.0198 +/-0.112 4.59+/-1.98 VOC (pg/L) <1.0 <1.0 <1 0 Others 7.18 <1 EFR 6/16/2016 EFR 6/6/2017 EFR 151DWMRC (split sample with EFR) June 26, 2018 151DWMRC (Duplicate "Spring 1") 1 EFR 6/11/2019 1 Cottonwood Spring 6/16/2020 Back Spring (EFR Duplicate of Cottonwood Sping) <0.05 <0.05 <0.05 <0.10 <0.10 <0.05 <0.05 I.<0 05 <0.1 0.124 0.108 <0 1 <0.1 <0 1 <0.1 l<0.1 <5 <5 <5 <5 0 <5.0 <5 <5 <5 <0.5 <0 5 <0.5 <1 0 <1.0 <0.5 <0 5 <9.9 <0,5,_ <0 5 <0.5 <1.9„ <0:5 <9.5 <25 <25 <25 <3.0 <3 0 <25 <25 <25 <10 <10 <10 <1 0 <1.0 <10 <10 <10 <10 <10 <10 <2.0 <2 0 „ „ <19„. .„.. <10, , <1.9. <30 <39 <30 <199 <100 <39 <30 „ <30 <1 <1 <1 <1.0 <1.0 <1 <1 <1 <10 <10 <10 2 3 3.2 <10 <10 <10 <0.5 <0.5 <0.5 <0.2 <0.2 <0 5 <0.5 <0.5 , <10 „ „ . „ <10 <10 , <0,2, <0.2 <10 <10 <10 <20 <20 <20 <2.0 <2.0 <20 <20 <29„ <8 <8 <5.0 <8 <5 , <10 <10 <10 <1.0 <1.0 <10 <10 <10 <0.5 <0.5 <0.5 <1.0 <1.0 <0.5 <0.5 <0.5 <100 <100 <100 <10 <10 <100, <100, <log , 8.84 9.17 10 3 9.2 9:8 10 10:5 10 7 <15 <15 <15 <5.0 <5.0 <15 <15 <15 <10 <10 <10 <10 <10 <10 <10 <10 0.149+/-0.167 0.648+1-0.945 10.726+/-0.608 1%Xigrip4'1,414.4?.44iforagt 0.393+/-0 257 0.256+1-0.209 -0 00212+/-0.191 <20 <20 <20 <6 0 <6.0 <6.0 <20 <20 <1.0 <1.0 <1 0 <1.0 <1.0 <1.0 <1.0 <1 0 <20 <20 <20 <6 <6 <6 <20 <20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 0 <1.0 <1.0 <1.0 <1 0 <2.0 <2.0 <2.0 <1.0 <1.0 <1.0 <1 0 <1.0 <2.0 <2.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1 9 <1.0 <1.0 <1 0 <1-0 <1.0 <1.0 <1.0 <1.0 <7.0 <7.0 <7 0 <1:0. <1,9 <1.9 <1.0 <1.0 <1.0 <1.0 <1.,0 <1.9„ <1.0 <1.0 <1 o o <2.0 <2.0 <1.0 <1.0 7.3 6.59 7.1 7.6 7.7 7 7 7 09 7.09 0 466 0.344 0.282 0 36 0.36 0.36 0.233 0.24 138 129 153 130 140 140 146 147 443 1,070 409 1,080 428 1 ,080 460 1 ,100 460 1,100 460 1,100 417 860 424 1,280 <1 0 .. , „ <1- 0 „ „ <1.9 , <5.0 <5.0 < 0 <1. 0 <1 256 280 283 289 236 280 " ' 289 284 221 213 234 240 240 240 273 282 6.11 „ 29.5 _. 5 72 .. . 27,1 6. 35 „.... „ „ „ . 30.2 6.4 „ .. „ 28 „ 26 „ „ „ 6 4 „ 28 7.14 .3?.9 7.?9 102 99,6 „ 109 100 100 100 120 . 1?4 18 2 „ . „ 17.8 ' „ 16. „ . niA ' ' r:iik NA 18.4 18.7 17.3 16.6 18.3 NA NA NA 26. 21.4 <5 <0 5 <0.5 <25 <10 <10 <30 <1 <10 <9.9. <10 <20 <5 <10 <0.5 <199 „ 8.17 <15 <10 <5 <1 <5 <1 <1 <5 <5 <20 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 <5 <1 <1 <5 <1 <1 <1 <1 <1 <1 <1 <1 7.71 0.34 112 374 1030 <20 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <1.0 442 410 410 1,020 1100 1100 n Part I.E.1.(c)(2 (ii) <1 „„ <5 <5 „ „ 200 -269 259 126 230 250 3.14 5.7 8-1 24 31.8 26 „ 162 , „ 92 100 15„.8 NA NA 16.3 NA NA = Not analyzed NG = No GWCL T = indicates metals analyzed as totals = exceeded Ground Water Qualitty Standared (GWQS). However, the GWQS are for comparison perposes only and are not compliance standards for this spring. Table $ Historic Westwater Seep Analyical Data up to 2020 Monitoring Event 131Contaminants (4)GWQS (for comparison only) EFR EFR EFR EFR EFR EFR EFR EFR DWMRC sample EFR EFR DWMRC sample 11/18/2009 7/8/2010 5/31/2011 12) 6/16/2015 10/24/2016 Nutrients 10/27/2017 (mg/L) 10/23/2018 3/27/2019 6/11/2019 3/25/2020 6/16/2020 Ammonia (as N) 25 <0.05 0.051 0 06 0.123 0.1231<0.05 0.0832 <0 05 <0 10 0.0593 <0 05 j<0.1 Nitrate + Nitrite (as N) 10 0.8 <0 1 l<0 1 <0.1 <0.1 <0.1 <0.1 <0.1 <0 1 <0.1 <0 1 <0 1 Heavy Metals (pg/L) Arsenic 50 <5 12 3 <5 <5.0 <5 <5.0 Beryllium 4 <0.5 <0.5 0.91 <0 5 <0 5 <0.5 <0.5 <0.5 <1.0 <0.5 <0 5 <1.0 Cadmium 5 <0 5 <0.5 0 9 <0 5 <0.5 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <1.0 Chromium 100 <25 <25 <25 <25 <25 <25 <25 <25 <3.0 <25 <25 <3 0 Cobalt 730 <10 <10 <10 <10 <10 <10 <10 <10 1 7 <10 <10 1.0 Copper 1,300 <10 <10 1 16 <10 <10 <10 <10 <10 2 4 <10 <10 <2.0 iron 11,000 <30 56 I 4 AAri <30 40 181 575 1,200 2,800 401 <30 <100 Lead 15 <1 <1 41 4 <1 <1 <1 <1 <1 n <1 <1.0 <1 0 Manganese 800 37 871 26ti 171 55 5 144 312 528 0 369 35.4 430 Mercury 2 <0.5 <0 5 <0.5 <0.5 <0.5 <0.5 <0.5 <0 5 <U 2 <0 5 <0 5 <0.2 Molybdenum 40 <10 29 <10 <10 <10 <10 <10 <10 <0.2 <10 <10 3.5 Nickel 100 <20 <20 I 29 <20 <20 <20 <20 <20 <2.0 <20 <20 <2.0 Selenium 50 <5 <5 1<5 <5 <5 <5 <5 <5 <5 0 16 Silver 100 <10 <10 1<10 <10 <10 <10 <10 <10 <1.0 <10 <10 <1.0 Thallium 2 <0 5 <0 5 1<0 5 <0.5 <0.5 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <1.0 Tin 17,000 <100 <1nn 1<100 <100 <100 <100 <100 <100 <10 <100 <100 <10 Uranium 30 15 1 6.64 2.1 19 5.17 13.2 5 <1 0 2 34 12 9 3.5 Vanadium 60 <15 <1 o 34 <15 <15 <15 <15 <20 <5.0 <20 <15 <5.0 Zinc 5,000 <10 <10 26 <10 <10 <10 <10 <10 <10 <10 <10 <10 Radiologics (pCi/L) Gross Alpha 15 0 3+/-0.2 0 3+/-0 3 0 5+/-0.2 -0.0116+/-0.126 0.00612+/-0.193 0.810+/-0.254 0.0688+/-0.220 0.232+/-0.270 1.02±0.555 0 559+/-0.300 0.119+/-0.191 2.86±2 4 VOC (pg/L) Acetone 700 <20 <20 <20 <20 <20 23 1 <20 <20 <10 0 <20 <20 <10 Benzene 5 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 0 <1 0 <1 0 <1 0 <1.0 2-Butanone (MEK) 4,000 <20 <20 <20 <20 <20 <20 <20 <20 <6 <20 <20 <6.0 arbon Tetrachloride 5 <1.0 <1.0 <1.0 <1.0 <1.0 <1 0 <1 0 <1.0 <1.0 <1 0 <1 0 <1.0 hloroform 70 <1.0 <1 0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 0 <1.0 hloromethane 30 <1.0 <1.0 <1 0 <1 0 <1.0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <2.0 Dichloromethane 5 <1 0 <1 0 <1.0 <1.0 <1 0 <1.0 <1.0 <1.0 <2.0 <1.0 <1.0 <2.0 Naphthalene 100 <1 0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 Tetrahydrofuran (THF) 46 <1.0 <1 0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <7.0 <1.0 <1.0 <7.0 Toluene 1,000 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1 0 <1 0 <1.0 <1.0 <1.0 Xylenes (total) 10,000 <1.0 <1.0 <1.0 <1.0 <1.0 <1 0 <1.0 <1.0 <2.0 <1.0 <1.0 <2 0 Others Field pH (S U ) 6.5 - 8 5 8.01 7.38 7.2 7.24 7.24 6.87 6.70 7.6 7.9 Fluoride (mg/L) 4 0.7 0.6 0.54 0.424 0 618 0.574 0.659 0.505 <0.5 0 555 0.429 <0.5 hloride (mg/L) NG 41 40 21 32.6 38 27.5 36 2 41 6 36 26.6 40.6 36 Sulfate (mg/L) NG 646 607 354 392 573 318 580 436 390 307 460 480 TDS (mg/L) NG 1,370 1,270 853 896 1,060 820 1,220 1,110 990 1,200 1,480 1,100 General Inorganics Listed in Part I.E.1.(c)(2)(ii) Carbonate (mg/L) NG <5 <1 <1 <1 <1 <1 <1 <1 <10.0 <1 <1 NA Bicarbonate (mg/L) NG 465 450 371 359 399 369 444 450 330 270 450 NA Sodium (mg/L) NG 195 160 112 139 185 133 218 152 130 117 245 160 Potassium (mg/L) NG 2.4 6.57 3.9 1.98 2.32 2.33 2.94 3.99 3 4 1.76 5.28 3.4 Magnesium (mg/L) NG 26.6 44.7 34.7 34 47.3 31.7 56.6 43.7 35 30.8 54.6 44 Calcium (mg/L) NG 191 179 247 150 176 125 204 185 140 118 204 160 Total anions (meq/L) NG 22.3 22 3 14 1 16 3 21.0 14.8 22 0 19 3 NA 12.6 13.7 NA Total cations (meq/L) NG 21.8 21 8 20.1 16 4 20.8 14.7 24 4 19.6 NA 13.6 15.7 NA 1 THF sampled on November 3, 2010 2 Water samples collected are most likely due to surface water from recent within 48 hours) rain from storms. 3 Contaminants listed in Table 2 of the Groundwater Quality Assurance Plan for EFR 4 The Ground Water Qualtity Stantandards (GWQS) are for companson perposes only and are not compliance standards for this spnng NG = No GWQS DWMRC = Utah Division of Waste Management and Radiation Control. EFR = Energy Fuels Resourses , .thided = exceecic3KQUOCI Watgi,40ahtty Standared (GWQS) However, the GWQS are for companson perposes only and are not compliance standards for this spnng Table 6 RPD and RPR for DWMRC Duplicate QA/QC Samples and Comparing to EFR Duplicate QA/QC Samples Sample Date June 16, 2020 (2IContaminants EFR Sample Comparison EFR and DWMRC Sample Comparison ottonwoo C d Spring Back Spring (EFR Duplicate of Cottonwood Sping) RPD/RPR Entrance Spring (EFR sample) Entrance Spring (DWMRC sample) RPD/RPR Westwater Spring (EFR sample) Westwater SPring (DWMRC sample) RPD/RPR Nutrients (mg/L) Ammonia (as N) Nitrate + Nitrite (as N) <0.05 <0.1 <0.05 <0.1 NC NC I 1.6 2.46 <0.1 1,8 NC 31,0 <0.05 <0.1 <0.1 <0.1 NC NC Heavy Metals (pg/L) Arsenic <5 <5 NC <5.0 <5.0 I NC <5 <5.0 NC Beryllium <0.5 <0.5 NC <0.5 <1.0 NC <0.5 <1.0 NC Cadmium <0.5 <0.5 NC <0.5 <1.0 NC <0.5 <II .0 NC Chromium <25 <25 NC <25 <3.0 NC <25 <3.0 NC Cobalt <10 <10 NC <10 <1.0 NC <10 1.0 NC Copper <10 <10 NC <10 <2.0 NC <10 <2.0 NC Iron <30 <30 NC <30, <100 NC <30 <100 NC Lead <1 , <1 NC <1 <1.0 Np <1.0 <1.0 NC Manganese <I10 <10 NC 56.3 $'' ' 35.4 439 awe Mercury <0.5 <0 5 . „ „ NC <0:5 <0.2 NC <0.5 <.2 NC Molybdenum <10 <10 NC <10 3.7 NC <10 3.5 NC Nickel <20 <20 NC <20 <2.0 NC <20 <2.0 NC Selenium <5 <5 NC 15 16 -6,5 <5 <5.0 NC Silver <10 , <10 NC <10 ,<1.0 NC <10 <1.0 NC Thallium <0.5 <0.5 NC <0.5 <1.0 NC <0.5 <1.0, NC Tin <100 <100 NC <100 <10 NC <100 , <10 NC Uranium 10.5 10.7 -1.9 24.7 25 -1.2 12.8. 3.5 114.6 Vanadium <15 <15 NC <15 <5.0 NC <15 <5.0 NC Zinc <10 <10 NC <10 <10 NC <10 <10 NC Radiologics (pCi/L) ("PER for Gross Alpha 0.256+/-0.209 -0.00212+/-0.191 (0ER)0.9 0.453+/-0.229 2.54+/-1.58 (RER)0,13 0.119+/-0.191 2.86±2.4 O'ER)LI VOC (pg/L) Acetone <20 <20 NC <20 <10 NC <20 <10 NC Benzene <1.0 <1.0 NC <1.0 <1.0 NC <1.0 <1.0 NC 2-Butartorte (MEK) <20 ,<20 NC <29 <6.0 NC <20 <6.0 NC Carbon Tetrachloride <1.0 <1.0 NC <II .0 <1.0 NC <1.0 <1.0 NC Chloroform <1.0 <1.0 NC <1.0 <1.0 NC <1.0 <1.0 NC Chloromethane <1.0 <1.0 NC <1.0 , <2.0 NC <1.0 <2.0 Np, Dichloromethane <1.0 ,<1.0 NC <1.0 <2.0 NC <1.0 <2.0 NC Naphthalene <1.0 <1,0 NC <1.0 <7.0 Nic <1.0 <7.0 NC Tetrahydrofuran (THF) <1.0 <1.0 NC <1.0 <1.0 NC <1.0 <1.0 NC Toluene <1.0 ,<1.0 NC <1.0 <1,0 NC <1,,0 <1.0 NC Xylenes (total) <1.0 <1.0 NC <1.0 <2.6 NC <1.0 <2.0 NC Others Field pH (S.U.) 7.09 , 7.09 0.0 7.73 7.5 NC 8.4 , 7.9 NC Fluoride (mg/L) 0.233 0.24 -3.0 0.638 0.54 16.6 0.555 ,0.5 NC Chloride (mg/L) 146 147, -0.7 76.7 75 2.2 26.6 36 -30.0 Sulfate (mg/L) 417 424 -1.7 317 300 5.5 307 480 -44.0 TDS (mg/L) 860 1,280 -39.3 964 870 10.3 1,200 1,100 8.7 Genera Inorganics Listed in Part l E.1.(c)(2)(1i) Carbonate (mg/L) <1.0 , NC , <1 NA NC <1 <1 NC Bicarbonate (mg/L) 260 284 -1.4 242 NA NC 450 NA NC Sodium (mg/L) 273 282 -3.2 108 91 17.1 245 160 $42.0 Potassium (mg/L) 7.14 7.23 -1.3 431 3.8 12.6 5.28 3.4 ' 43.3 Magnesium (mg/L) 32.9 33.7 -2.4 45.1 42 7.1 54.6 44 21.. Calcium (mg/L) 120 124 -3.3 144 120 18.2 204 160 24.2 DWMRC = Utah Division of Waste Ma agernent and Radian Control EFR = Energy Fuels Resources NA = Not Analyzed NC = RPD not calculated because one or both of the concentration were below laboratory detiction limits NG = No GWCL RER = Replicate error ratio RPD = Relative Percent Difference RPD exceeding 20% for ES their duplicate sarnples SRO exceeding 30% for ORC comparing their duplicate sample with ES sample 1. Non-comfonnance exists when the RER z 2 2. Contaminants listed in Table 2 of the Groundwater Quality Assurance Plan for EFR. 3. The Ground Water Qualtity Stantandards (GWQS) are for comparison perposes only and are not compliance standards for this spdng.