DRC-2016-006043 - 0901a06880621ae1

State ofUtah
GARY R. HERBERT
Governor
SPENCER 1. COX
Lieutenant Governor
Binesh Tharakan
U.S. NRC Region IV
Department of
Environmental Quality
Alan Matheson
Executive Director
DIVISION OF WASTE MANAGEMENT
AND RADIATION CONTROL
Scott T. Anderson
Director
April26,2016
Division ofNuclear Materials Safety
1600E. Lamar Blvd
Arlington, TX 76011-4511
RE: Transportation Incident at the White Mesa Mill Involving an 11e.(2) Shipment
Dear Mr. Tharakan:
On March 29,2016, Energy Fuels Resources Inc.'s (EFRI) White Mesa Uranium Mill contacted the
Division of Waste Management and Radiation Control to report a leaking shipment of lle.(2) material
that had arrived at its facility. The Radiation Safety Officer of the Mill described the material as a white
paste like substance. The 11e.(2) shipment originated from the Cameco-Smith Ranch facility (a Nuclear
Regulatory Commission (NRC) licensed facility) in Wyoming and was sent to the Mill to be disposed in
the Mill's tailings cells.
The Mill's radiation safety staff documented the leak with photographs, radiological surveys and a
written description. Documentation of the leak indicates that 11e.(2) material leaked onto the transport
container, the transport conveyance and U.S. Highway 191 near the Mill. During transport, a winter
storm with rain and snow went through Wyoming, Colorado and Utah when this incident occurred
(March 28 and 29, 2016). Therefore, there is a high probability that any road contamination would have
been washed away and making it impossible to determine when the leaking of the transport began.
A further description of the incident from EFRI dated April4, 2016, including radiological survey
results, is enclosed.
The following regulations are applicable to this incident:
1. 49 CFR 173.427(c)(l)-Transportation requirements for low specific activity (LSA) Class 7
(radioactive) material and surface contaminated objects (SCO).
DRC-20 16-006043 195 North 1950 West • Salt Lake City, UT
Mailing Address: P.O. Box 144880 ·Salt Lake City, UT 84114-4880
Telephone (801 ) 536-0200 • Fax [phone] • T.D.D. [phone]
www.deq.utalz.gov
Printed on I 00% recycled paper
(Over)
2. 49 CFR 173.443-Contamination control
3. 10 CFR 71.43(±)-General standards for all packages
4. 10 CFR 71.71 -Normal conditions of transport
Contrary to 49 CFR 173.427(c)(1), 10 CFR 71.43(±) and 10 CFR 71.71, the Cameco-Smith Ranch
Facility sent an 11e.(2) shipment to the White Mesa Mill in a roll-off container that did not contain the
material under routine (normal) conditions of transport.
Contrary to 49 CFR 173.443, leakage from that container resulted in removable contamination on the
outside of the container that exceeded DOT contamination limits for Alpha and an exterior dose rate
greater than 0.5 mrem per hour.
This is the second incident of this type that has been reported to the Division with the first being
reported on August 21, 2015. The Division requests that NRC take appropriate regulatory action with
Cameco-Smith Ranch to prevent recurrence. Please find enclosed the EFRI report of the incident,
photographs and shipping papers.
If you have any questions, please call Ryan Johnson at [phone].
Sincerely, Lc:x:--c:2
Scott T. Anderson, Director
Division of Waste Management and Radiation Control
STAJRMJ/ka
Enclosures: Documentation Letter, dated April4, 2016 (DRC-2016-006042)
Cameco Smith Ranch Shipping Paperwork (DRC-2016-006041)
Photographs (DRC-2016-006044)
Email from Ryan Johnson, dated March 29,2016 (DRC-2016-006045)
c: Worthy Glover, Jr., MMHRM, CPM, Health Office San Juan Public Health Department
Rick Meyer, Environmental Health Director, San Juan Public Health Department
David Ariotti, P.E., DEQ District Engineer
Ms. Linda Gersey, U.S. NRC Region IV, Division ofNuclear Materials Safety
RyanS. Schierman, State of Wyoming, Wyoming Department of Environmental Quality,
Natural Resources Program Manager
Jennifer Opila, Colorado Department ofPublic Health &the Environment, Hazardous Materials
& Waste Management Division, Radiation Program, Program Manager
.-----/~RGYFIJELS
April 4, 2016
Sent VIA E-MAR. AND EXPRESS DELIVERY
Mr. Scott Anderson
Director
Division of Waste Management and Radiation Control
Utah Department of Environmental Quality
195 North 1950 West
P.O. Box 144880
Salt Lake City, UT 84114-4820
Energy Fuels Resources (USA) Inc.
225 Union Blvd. Suite 600
Lakewood, CO, US, 80228
303 9742140
www.cncrgyfuels.com
Re: Transmittal of Documentation for FoDow-up to Notifications Provided to the Division of Waste
Management and Radiation Control ("DWMRC") for White Mesa Uranium MiD
Dear Mr. Anderson:
Attachment 1 to this letter provides Energy Fuels Resources USA Inc.'s ("EFRI' s") follow·up documentation to
previous notifications to DWMRC Personnel by David Turk on March 29, 2016 regarding Cameco lle.(2)
shipping issues.
Department of Transportation ("DOT'') regulations in 49 CPR 171.15 require that persons in physical
possession of a material during an incident provide notifications to DOT after the occurrence of any incident.
Pursuant to this requirement, Greenfield Logistics made the appropriate notifications to U.S. DOT National
Response Center on March 29, 2016.
If you should have any questions regarding this submittal please contact me at 303-389-4134.
(;;;P~
.ENERGY FuELS REsoURCES (USA) INC.
Kathy Weinel
Quality Assurance Manager
CC: David Frydenlund
Harold Roberts
David Turk
Logan Shumway
Scott Bakken
A TIACHMENT 1
DOCUMENTATION FOR INCIDENT OF MARCH 29, 2016
Name of Reponer to DWMRC
Verbal Notification was provided to the Division of Waste Management and Radiation Control
("DWMRC") by David Turk White Mesa Mill Radiation Safety Officer ("RSO")
Initial written notification via e-mail was provided by David Turk White Mesa Mill RSO
This follow-up notification is provided by Kathy Weinel, EFRI Quality Assurance Manager ("QAM')
Notifications were provided to Mr. Phil Goble and Mr. Ryan Johnson of DWMRC on March 29, 2016.
Name and Address of Person Represented by Reponers
Energy Fuels Resources USA Inc.
225 Union Boulevard, Suite 600
Lakewood, Colorado 80228
For an incident located near:
White Mesa Mill
6425 South Highway 191
Blanding Utah, 84511
Phone Numbers Where Reponers Can Be Contacted
David Turk 435-678-4113
Kathy Weinel 303-389-4134
Date. Time. and Location of Incident
At approximately 0730 hours on Tuesday March 29, 2016, the staff at the White Mesa Mill (the "Mill")
noted that an incoming lntermodal Container ("IMC") from Cameco -Smith Ranch was leaking a white
paste like material. The IMC had traveled from the Cameco Smith-Ranch Facility in Glenrock, Wyoming
overland to the Mill entrance in Blanding, Utah. ·
The incident involved a leaking 11e.(2) disposal shipment from Cameco-Smith Ranch in the Mill entry
way. In addition, some material had spilled out of the container onto US Highway 191.
The Extent of the Injury
No injuries resulted from this incident.
Class or Division. Proper Shipping Name and Quantity of Hazardous Materials Involved
The leaked material is Class 7, UN2912, Radioactive Material, Low Specific Activity (LSA-1).
It is estimated that less than 5 gallons was present at the entrance to the Mill and on the truck and IMC.
Type of Incident and Nature of Hazardous Material involvement and Whether a Continuing Danger to
Life Exists at the Scene
The incident involved an IMC that was leaking a small amount of material. Some material had dripped
from the truck and contacted the highway. The majority of the leaked material remained affixed to the
IMC and transport truck. The leaking material was identified as Class 7, UN2912, Radioactive Material,
Low Specific Activity (LSA-1).
At no time during the incident was there a danger to life.
The materials which were noted on the Highway 191 surfaces, as well as those on Mill property, were
cleaned up following the incident by Mill Personnel.
Chronology of the Incident
• At approximately 0730 hours on Tuesday March 29, 2016, the staff at the Mill noted that an
incoming IMC from Cameco -Smith Ranch was leaking a white paste like material. The IMC
and truck were denied entry to the Mill facility pending investigation and approval from
DWMRC.
•
•
•
•
•
•
•
•
•
•
•
The RSO was notified. The RSO immediately examined the container and truck and took
photographs.
The RSO contacted Mr. Phil Goble with the State of Utah Division Of Waste Management and
Radiation Control at approximately 0800 hours. The notification to Mr. Goble, included notice
that a leaking lle.(2) disposal shipment from Cameco-Smith Ranch arrived at the Mill and was
sitting in the Mill entry way. Mr. Goble was also notified that there was white material that had
spilled out of the container onto US Highway 191 near the entrance to the Mill property.
After notification was given to the DWMRC, the RSO made contact with EFRI Corporate Staff .
Ms. Kathy Weinel was notified via phone at approximately 0830 hours. Photographs were sent to
EFRI Corporate Staff via text messaging.
Ms. Weinel phoned the site RSO for Cameco Smith Ranch, a Mr. Travis Coleman. Mr. Coleman
was not in the office and a voicemail was left.
Ms. Weinel then contacted the Mine Manager, Mr. Craig Hiser to report the spill. This was the
first notice to Mr. Hiser of an issue with the shipment as Greenfield Logistics, the shipping
company, had not yet notified Smith Ranch Personnel of the incident.
The RSO returned to the inbound shipment and took multiple photographs of the tractor, trailer
and IMC and began a radiological survey of the material that was visible on US Highway 191 and
EFRI entrance road.
The white material on the asphalt highway and roadway ranged from 5,850 to 9,360 dpm/100cm2
for alpha and 0.04 to 0.08 mrernlhr beta/gamma.
There were four removable alpha swipes taken on the asphalt roadways. Those readings came
back at 383 to 492.5 dpm/100cm2•
During the radiological survey, the RSO was contacted by the Greenfield Logistics dispatcher,
Mr. Chris Hartley, to make sure that we were aware of the leaking container. He was told that
EFRI was aware of the situation and that EFRI was in the process of gathering information and
data for the report to DWMRC. Mr. Hartley was also notified that the container would not be
released, because the container would need to be fully cleaned before allowing it to leave the
facility. Due to the deteriorating weather conditions the cleaning process for that container was
not possible at that time.
The Mill Personnel went to the conveyance and performed a radiological survey on all
components where there was visible material. The material came back with a total alpha
measurement of between 35,100 to 58,500 dpm/100cm2• The beta/gamma survey on the same
material was 5.0 mrernlhr. A series of removable alpha swipes were collected. Those readings
ranged from the lowest on the tires at 438.8 dpm/100cm2 to the highest on the beam under the
potential source at 2,551.3 dpm/100cm2•
The RSO spoke with the Greenfield driver, Mr. Doug Angell. He stated that he noticed the
leaking container when he pulled onto our entrance way at 2330 hours on Monday March 28,
2016. He stated he then texted his dispatcher at that time about the leak. He also stated that on
Monday March 28, 2016, while traveling near Meeker, Colorado, a deer ran in front of the truck
and he had to hit the brakes hard. That was the only time during the trip that there was any
sudden jarring of the load. He stated that he had filled up with fuel in Rawlins, Wyoming and, at
that time, there was no leakage. It should be noted that all seals were still intact that Cameco
installed prior to the container leaving their site.
4
• At approximately 0945 hours on Tuesday March 29, 2016, the RSO allowed the load onto the
property pursuant to approval from DWMRC Personnel. The main reason for the allowing the
truck and IMC onto the Mill property was that rain was starting to fall and washing some of the
material off of the container and onto the ground. In order to prevent a larger cleanup, the
decision was made to move the truck and IMC to the Mill Restricted Area.
• The area on US Highway 191 and the EFRI entrance way was washed and any contaminated soil
(approximately 5 to 6 cubic yards) was excavated and taken into the Mill Restricted Area and
then out to Cell 3 for disposal. The cleanup area extended approximately % of a mile north on
US Highway 191. The area was surveyed after the rain/snow storm stopped. Data from these
scans is summarized below.
Summary of Scan Results
Location Background Pre-Cleanup Results Post-aeanup Results
Units Units Units
EFRI Entrance Road 212 dpm/100cm'l and 10 5,850 dpm/100cm'l and S Bkg and 23 J!Rihr
J!R/hr 0.04 mrem/hr
US Highway 191 212 dpm/100cml and 10 9,360 dpm/100cml and S Bkg and 20 J!Rlhr
turnout J.I.R/hr 0.08 mrem/hr
US Highway 191 212 dpm/100cm'l and 10 5,850 dpm/100cm2 and S Bkg and 10 J!Rlhr
J.I.R/hr 0.04 mremlhr
Greenfield Truck 212 dpm/100cm'l and 35,100 dpm/100cm2 and S Bkg and S 0.04
0.04 mremlhr 5.0 mrem/hr mremlhr
Greenfield IMC 212 dpm/100cm2 and 58,500 dpm/100cm2 and Is still in the process of
0.04 mrem/hr 5.0 mrem/hr being cleaned
• The inbound IMC was dumped on Cell 3 and the then moved to the vicinity of the Old
Decontamination pad in order for EFRI to perform a detailed decontamination of the unit once
conditions improve. The truck was taken through the Old Decontamination wash station. The
truck was released from the site at 1130 hours. All release surveys on the truck met applicable
standards.
• At approximately 1830 hours on March 29, 2016, Greenfield Logistics reported the incident to
DOT National Response Center. Kevin Williams at the National Response Center took the call
and issued Case# 1144028. Shane Johnson of Greenfield Logistics received a call from DOT to
review the details of the report. Per e-mail communications from Greenfield Logistics, DOT
considers the incident report closed.
• At approximately 0900 hours on March 30, 2016, Ms. Weinel spoke with Mr. Travis Coleman.
Mr. Coleman was notified that this was the second incident of this type involving this material.
EFRI recommended Smith-Ranch Personnel conduct an internal investigation into this incident to
prevent recurrence.
• The US. Nuclear Regulatory Commission ("NRC") requested that Cameco retrace the route of the
shipment to investigate the potential for additional released material. The Cameco team obtained
a detailed account of the route. In the event that additional released material was identified,
Cameco's Emergency Response contractor was standing by to respond.
• On April 1, 2016 a Cameco team comprised of the Smith Ranch RSO, Mr. Travis Coleman, a
Smith Ranch Health Physics Technician ("HPT''), Mr. Chris Pendleton, and Mr. Ken Vaughn, the
Cameco Director of Communications traveled to the Mill in Blanding Utah. They arrived at 1830
on Friday, April I, 2016.
• The Carneco team surveyed Highway 191 from the Mill entrance to the 4-way intersection in
Blanding in 1..4 mile increments. No readings above background were noted.
• On April 2, 2016, the Cameco team retraced the shipping route and surveyed at points along the
road. Additional data were collected in and around Meeker, Colorado due to the Greenfield
5
driver stating he had to stop quickly to avoid a deer in that area. Due to the potential for
additional spillage, this area was surveyed at a higher frequency.
• Photographs are included on the CD attached to the hardcopy of this notice.
Conclusion
After final decontamination of the IMC to appropriate release standards, the IMC will be released. No
further cleanup activities at the Mill, on Highway 191, or the travel way are required. EFRI has requested
that Cameco Smith-Ranch personnel complete an investigation of the cause of this incident and take
appropriate actions to prevent recurrence in the future. Cameco Resources has suspended all waste
shipments from Smith Ranch-Highland and Crow Butte until the issue(s) that resulted in the incident are
fully addressed. Cameco's investigation will address both the type of material and method of shipment
(regarding no free liquid).
6
.
Shipper No-:l/1("1
STRAIGHT BILL OF LADING
ORIGINAL-NOT NEGOTIABLE
Greenfield Logistics
!Name of Carrie, (SCAC)
Carrier No. ____ _
Date ] /a Pl. I
on Called: on Delivery lhipmlnll,lhe letters COO must &ppea' befOre t:OnlignM's,.. or as olherwise From: Shipper CAMECO RESOURCES. INC. piO'Iided in nem 430, Sec. 1.
To: Consignee . J:nergy Fuels Street: 762 RossRd
Street 6425 South HWY 191 City Douglas State WV Zip Code 82633
. City Blandino State UT Zip Code _M5:11 24 hr. Emergency Contact Tel. No: iDS-88~-874~ •·
~
Rollte: Vehicle:
Number ...
No. of units & HM Basic Description Total Quantity Weight Charges container type Proper Shipping Name, Hazard Class, (Weight, Volume, (Subject to RATE (FerC8rrier
... Identification Number (UN or NA), Packing Group, per 172.101, 172.202, 172.203 Gallons, etc.) Correction) U~O~Iy)
1 Roll off XX UN2912, RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY
. {LSA-'1t_ CLASS 7 9.9m3 (13yct3)
RADIONUCLIDE: RESIDUAL NATURAL URANIUM & ASSOCIATED
DAUGHTER PRODUCtS
PHYSICAL FORM: SOUD
CHEMICAL FORM: NATURAL URANIUM OXIDE U0.-2H20
TOTAL ACTIVITY:1.83E9Bq (.05Ci}
TRANSPORT INDEX: NJA AS PER 49CFR172.203(d)(5)
PLACARDS: RADIOACTIVE 7
EXCLUSIVE USE SHIPMENT: THIS VEHICLE IS ASSIGNED FOR
EXCLUSIVE USE OF CAMECO RESOURCES, INC. UNDER
ff PROVISIONS OF 49 CFR 173.427 INCLUDING EXEMPTING FROM
MARKING AND LABELING REQUIREMENTS
DO NOT LOAD OTHER FREIGHT IN THIS VEHICLE, TRANSFER EN
ROUTE
~ . ·.·.
PLACARDS TENDERED: NOD REMIT C.O.D. TO:
ADDRESS '" '~
'*"*-111 ~llllttlllets~on-.tlliPPM-requlnd lo-lpKilclllyon lllmby clec:I-.I1MIIl1Nt -of U1ls COD Aml:l C.O.O,fl!l!; -.gliNtllgNCif--olllle~.-'-:TIIItllgNCCW-c:onsiQtlmlftl .. fully a_...,.........., PREPAIDO .... , .... .._., .. ~.......,-IJI'IIIIIsl\lpplflolleOOI ...... IJI' .. _IIIIppilv_llld_
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SHIPPER: C,4.MECO RESOURCES, INC.
PER ~
DATE ] /"1.,~
Rev 3-Apr 02,2015
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PER ~ I "' A ll.-~1
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J:\4} Radiation Protection Program\WYO-RPP-01 (Volume IV-Health Physics)\WYO -RPP-01 (Forms)\WYO-RPP-01.070 Bill ofLading-By-Product-
LSA.doc
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CONTAINER# (QEL., ... I "S' 0
LocATioN Se/en,·Hrl'1 Pla~tf
TOTALYAROS /JJ'tl
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VOLUME PER VERTICAL FOOT
Yards per ln.
1". 0.31
Yards per Ft.
1'. -4.31
2'. 8.61
3'. 12.92
3.5'• 15.1
... • 17.22
Full 19.38
Power Resources
Smilll ftllldl • H~IICI Urelllum Projta
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SHIPPER:
RECEIVER:
(.
Cameco
RELEASE AUTHORIZATION FOR BY-PRODUCT MATERIAL
(Complies with D. 0. T. Hazardous Material Regulations, 49 CFR Parts 100-199)
Cameco Resources
Smith Ranch Highland Operation
762 Ross Road
Douglas, WY 82633
License No. SUA-1548
Energy Fuels
6425 S. Hwy 191
Blanding. Utah 84511
License No. UT1900479 Amendment #4
SHIPPING DATE: 3/'l..lfl' --~~~~-------
SRH SHIPMENT#: _.J::....:/...;;l;z..{_-_1 ___ _
TOTAL MAXIMUM ACTIVITY OF LOAD: (o.os-c.J
CONTENTS:
CAMECO RESOURCES
Smith Ranch-Highland
Operation
Mail:
P.O. Box 1210
Glenrock, WY
82637 USA
T~:(307)35BH5541
Fax:[phone]
www.cameco.com
[B'(JN 2912, Radioactive Material, Low Specific Activity (LSA-1 ), Class 7 Shipment contains by-product material from an
in-situ uranium mine.
O RQ, UN 2912, Radioactive Material, Low Specific Activity (LSA-1), Class 7 Shipment contains by-product material from
an in-situ uranium mine.
0 UN 2913, Radioactive Material, Surface Contaminated Objects (SCO-I), Class 7 Shipment contains by-product material
from an in-situ uranium mine.
0 RQ, UN 2913, Radioactive Material, Surface Contaminated Objects (SC0-1), Class 7 Shipment contains by-product
material from an in-situ uranium mine.
By execution below, it is represented that the byproduct material being transported is properly classified, described, loaded
and labeled; and, that the byproduct material is completely contained and in proper condition for transportation, according to
the applicable regulations for the state and federal transportation departments.
The shipper certifies the byproduct material is not listed hazardous waste as defined in the Resource Conservation and
Recovery Act, as amended, 40 CFR 261 et. seq. or comparable state laws. The byproduct material has not been mixed or
commingled with hazardous waste as defined in 40 CFR 261 et. seq .. No processes are operated on the site which is RCRA-
Iisted processes as defined in 40 CFR 261 et. seq. All of the Byproduct Material is byproduct material as defined under
Section ll(e)2 of the Atomic Energy Act of 1954 as amended, 42 U.S.C. §2014(eX2) and 10 CFR §40.4(a-i). The chemical
analysis as listed in Paragraph 2(C) of the Byproduct Disposal Agreement dated June 1, 2010 has been completed for this
shipment.
DATE: ) {"l,f/1( BY:
NUCLEAR. The Clean Air Energy.
DRIVER RESPONSIBILITY STATEMENT
have read and understand the Driver Instructions including Emergency
Procedures provided by Cameco Resources. It is understood that I will be
responsible for proper care and handling of all materials in the trucks and/or
trailers under my jurisdiction.
DATE: 3/28,/ ll..~
SIGNA1URE: ~ -ra ~,.u.
Rev0-Nov07
Page 1 of I
J:\4) Radiation Protection Program\SRH-RPP-01 (Volume: IV-Health Physics)\SRH-RPP-01 (Forms)\SRH-RPP-01.050 Driver
Responsibility Statement (F-4-9-7).doc
~@t
Cameco
WYOMING OPERATIONS
BYPRODUCT MATERIAL SHIPMENT TRUCK
SURVEY
Cameco Resources
METERSN 1.4 (l7 METER MODEL 1
CALIBRATION DATE 5' H /1 ~
METER MODEL ~
METERSN ~1
4
rn
CALIBRATION DATE ---+....,_._-....::._.._li_.Ll£.__ __
Yes
Swipe Survey @
0-09
mRihr Driver's Seat
&445
Surface
0.>
dprn/1 00 cm2
mR/hr
6.6' (2 meters)
5o
Surface
_L/:...:'2::..5L-..._ dpm/1 00 cm2
Oualitv Control Checklist (49CFR 173.475)
As Per SHEQ Management System Volume IV-Transportati
The container is in good condition? ~
The container has been closed properly? __,::::_
The container has been tilled properly? ~
Exterior contamination/ Radiation levels below ./
the limits?
o.~
SHIPMENT NO. .) II' ... p t~~~ON: SfJTf?l~;:;:-
RSOffiST SIGWP;
BACKGROUND 0. OJ mRihr
BACKGROUND --=O:...__ __ dmp/100 cm2
C..IIIW\ ~·e4L
CARRIER NAME ,
TRACTOR NO.
)f(C;
mRfhr
J.O
mR/hr "1. 0 0. 5'
Surface 6.6' (2 Meters)
mR/hr /2.{ ).(}
Surface 6.6' (2 Meters)
dpm/100 cm2
Limits
Gamma= 200 mR/hr at surface
Gamma= I 0 mR/hr at 2 meters
Gamma = 2 mRihr in cab
Alpha= I 000 dpm/1 00cm2 for swipe survey
Alpha-2200 dpm/100 cm2 for instrument survey
6.6' (2 Meters) Surface
Rev2-August 14,2014
Page I of I
7tJ~ dpm/100 cm2
Surface
J:\4) Radiation Protection Program\WYO-RPP-01 (Volume tV-Health Physics)\WYO-RPP-01 (Fonns)\WYO-RPP-01.048 Byproduct Material Shipment
Truck Survey.doc
~· Cameco
WYOMING OPERATIONS
SHEQ MANAGEMENT SYSTEM
EMERGENCYPROCEDURES~AL
VOLUME VIII
Transportat_ion Accident Response Guide (Instructions to the Driver)
1.) Introduction
Transportation accidents during the shipment of radioactive concentrates from uranium
recovery facilities (yellowcake, brine, resin, byproduct, or slurry) occur infrequently on
public highways and at trucking terminals. This material is classified by DOT as
Radioactive (Class 7) material. Leakage or spillage of the contents from its container can
be a potential health hazard to persons if they ingest or inhale the materials.
The purpose of this guideline is to provide direction for persons responding to a shipping
accident involving radioactive materials, particularly when the contents have leaked from
their containers. Leakage or spillage can range in severity depending on the specific
accident conditions. Although this guideline addresses the worst-case situation, Jesser
response activities are envisioned for less severe accidents.
The guideline provides instructions to the driver and to other persons who are the first to
arrive at the accident scene. These instructions request notifications be made to the shipper
and the carrier. If warranted, the shipper will dispatch an initial response team to assist with
accident investigation and response. The shipper will also alert a clean-up crew for possible
duty and provide guidance for securing clean-up equipment and services. Clean-up
methods, monitoring, sampling, release levels, and concluding activities are also described.
You are advised per these instructions to transport the items defined on the attached
shipping documents under "EXCLUSIVE USE" provisions.
"EXCLUSIVE USE" (also referred to as "Sole Use" of "Full Load" as used in IAEA
regulations) means any shipment:
From a single consignor having the exclusive use of a transport vehicle or of an
aircraft, or of a hold or compartment of an inland watercraft, or of a hold, compartment, or
defined deck area of a seagoing vessel; and
For which all initial, intermediate, and final loading and unloading is carried out by
or under the direction of the consignor, consignee, or his designated agent.
Document Title: Instructions to
Driver Page: B-3
Transportation Accident Response Guide (Instructions to the Driver)
Special remarks concerning exclusive use:
DO NOT transfer the shipment from the originating carrier vehicle.
DO NOT load other packages on the originating carrier vehicle.
Deliver the shipment directly to consignor.
Special routing may be required per attachment.
Transportation Accident Response Guide (Instructions to the Driver)
2.) Emergency Response Procedures Provided to Carrier
TO WHOM IT MAY CONCERN:
• Rescue and lifesaving may be conducted with minimal potential hazards from the cargo
on this truck. If possible, avoid breathing dust from spilled cargo. DO NOT DELAY
RESCUE EFFORTS!
• After needed rescue, lifesaving, first aid or fire fighting, please read the attached
instructions in the event of cargo spillage.
• Please note that this truck is equipped with emergency equipment. It is accessible in
the storage area on the neck of the trailer or is (write
in location if not located in the trailer neck storage area).
TO THE DRIVER: Keep tlzese emergency procedures witlt your slt.ipping papers,
along witlt Emergency Information For Carriers Form and Guide 162 Radioactive
Materials ERG 2012.
This vehicle contains radioactive materials, which may be in the form of dry uranium oxide
(yellowcake, U308), yellowcake, brine, resin, slurry, or byproduct (waste) material. The
color of concentrated material is yellow. The slurry is a liquid material containing solid
yellowcake. The material cannot bum or explode. In the event of an accident involving
spillage of material, the following actions are recommended in the order given if
appropriate:
1. Lijesavi11g, Rescue, and Firefigltting
This may be done with minimal potential hazards from the material. If possible,
avoid breathing and/or swallowing yellowcake dust, slurry, or byproduct material. The
radioactive material on the skin or clothing is relatively harmless and simple washing
methods will remove it.
If you believe you may have been contaminated with the material, please remove any
contaminated clothing and place in plastic bag, use soap and water to wash contaminates
Document Title: Instructions to
Driver Page: B-4
from hands or exposed area, and notify the Cameco Resources Emergency Response Team
(CR ERT) upon their arrival at the accident site. To avoid ingestion of the material, do not
eat, drink, or smoke while near the spill.
Transportation Accident Response Guide (Instructions to the Driver)
2. Contact tlte Local Law Enforcement Agency
Tell the police of the accident with spillage of "LOW SPECIFIC ACTIVITY" (LSA)
radioactive material called "yellowcake", "slurri' or "byproduct material". Ask them to
notify the state health department. Give them the location of the accident site and tell them
of any injured persons.
Nebraska State Police:
Wyoming State Police:
Colorado State Police:
(Emergency Dispatch -24 hours)
Utah Highway Patrol:
3. Cover tlze Spilled Material
[phone] or [phone]
1-800-442-9090
[phone]
[phone]
[phone]
This vehicle carries a spill kit containing gloves, disposable coveralls, shoe covers,
radioactive material signs, approved dust respirators with instructions, plastic sheeting,
stakes, nails, a hammer, and a knife. Put on coveralls, respirator, gloves, and shoe covers,
then cover the spilled material with the plastic. Secure the edges of the plastic to the ground
using the stakes, or to the vehicle floor, etc., using the nails. The radioactive material signs
should be positioned to provide notice to bystanders.
Unnecessary personnel should be instructed to stand upwind of the spill and 150 feet or
more from it. Undamaged containers lying on the road may be moved to the side of the
road. Caution: Full drums of yellowcake are very heavy, usually weighing in excess of
500 pounds for slurry and 800 pounds for dry product.
4. Fill Out tlze Attached Questiomzaire
Please obtain all of the information requested on the attached form that you can. Please
relay this information to the carrier and the shipper listed below. See the final pages of
these instructions for additional emergency phone numbers.
Document Title: Instructions to
Driver Page: B-5
Transportation Accident Response Guide (Instructions to the Driver)
5. Telepltone tlte Carrier and tile Shipper (Call Collect)
• The carrier is:
• The shipper is:
Cameco Resources
Douglas, Wyoming
[phone]
After hours
[phone] ext. 450
The Cameco Resources phone in the Central Plant (ext. 450) is manned 24-hours per day,
7-days per week. Please read the completed questionnaire to whoever answers your call. If
necessary for their understanding, read the questionnaire a second time.
6. Wizen Help Arrives
Cooperate with all civil authorities and carrier and shipper personnel who arrive at the
scene. Follow their health-safety instructions on checking for possible contamination of
your clothing or body.
Please be assured that your exposure to this material will be relatively harmless if you have
followed these instructions. The radiological safety personnel who will arrive will be glad
to answer any questions you have about this matter.
Thank you very much.
Document Title: Instructions to
Driver Page: B-6
Transportation Accident Response Guide (Instructions to the Driver)
3.) Accident Evaluation Guide
I. Name of Trucking Company: ________________ _
2. Truck Number or Tag No::__ ________________ _
3. Name ofDriver: ------------------------------4. Name of Police Department Notified: ________________ _
5. Phone Number of Police Notified: ______________ _
6. Place of Accident: ______________________ _
7. Is the Driver Injured? ___________________ _
8. Other Injured? _____________________ _
9. Bill of Lading Number: _________________ _
10. Destination of Shipment: ____________________ _
11. Time of Accident: ____________________ _
12. Was There aFire? ____________________ _
13. Is It Raining or Was Water Used to Put Out Fire or Wash Off Road? ___ _
14. Are Drwns Outside of the Truck? ______________ _
15. About How Many? __________________ _
16. Are Contents ofDrwns or Tanks Spilled? ____________ _
I 7. Has the Spill Been Covered? ________________ _
18. Is the Spill on the Ground? ________________ _
19. Is the Spill in Water? Lake? Stream? ____ _
20. Is the Spill Near a Building? ________________ _
21. Is the Accident Area Lighted at Night? ____________ _
22.NameofNear~tLargeCizy? _______________ ___
23. Other Comments: ____________________ _
24. Your Name Please. ___________________ _
a. Can You Be Reached By Phone Near the Accident Site? _____ _
b. Phone number:
c. Home or Business Phone: ________________ _
d. Your Address:. ___________________ _
Date:. __________ _
Document Title: Instructions to
Driver Page: B-7 Revision Date:
January 7, 2016
Transportation Accident Response Guide (Instructions to the Driver)
Shipper Notification -Cameco Resources Personnel -call in order listed until one is
reached)
Mine Management
1.
2.
3.
4.
Work Phone
Craig Hiser [phone] ext. 415
Mine Manager
Travis Coleman [phone] ext. 431
RSO
Ken Garoutte-[phone] ext. 476
Safety, Health,
Environment and Quality Manager
Smith Ranch Central Plant Operator [phone] ext. 450
24 hours per day /7 days per week
North Butte Operations
5. Erik Heide
Mine Manager
Casper Management
1. Brent Berg
President
2. Mike Thomas
SHEQ Manager-DIV
Document Title: Instructions to
Driver
[phone] ext. 456
Work Phone
[phone]
[phone]
Page: B-8
Home Phone
[phone]
[phone]
[phone]
[phone]
[phone]
[phone]
Home Phone
[phone]
[phone]
Transportation Accident Response Guide (Instructions to the Driver)
Emergency Response Telephone Number Guide
State Agencies
Colorado:
State Police -Denver
Health Department (24 hours)
Illinois:
Highway Patrol General Headquarters
Deputy Director
Crash Report #
Iowa:
State Patrol Headquarters (Des Moines)
Calls made after 4:30pm will automatically transfer to 911
Kansas:
Highway Patrol General Headquarters
After hours: Dial *47 for highway help
Dial *582 for turnpike help
Michigan:
Highway Headquarters
(24 hours)
Minnesota:
Highway Patrol
Dept. ofTransportation-Admin. Office
Missouri:
General Headquarters
Document Title: Instructions to
Driver Page: B-9
Telephone No.
[phone]
[phone]
[phone]
[phone]
( 515) 725-6090
[phone]
[phone]
[phone]
[phone]
Transportation Accident Response Guide (Instructions to the DriYer)
Emergency Response Telephone Number Guide
State Agencies
Nebraska:
Highway Patrol -Scottsbluff, NE.
Lincoln, NE.
Health and Human Services (8 a.m. - 5 p.m. Central)
(After Business Hours-Call,Hwy. Patrol-Lincoln)
NDEQ (8 a.m. -5 p.m. Central)
(After Business Hours -Call Hwy. Patrol -Lincoln)
South Dakota:
Division Headquarters
Utah:
Highway Patrol -Price, UT. (Section 9)
Division of Radiation Control (24 hour)
Wisconsin:
State Patrol Division Headquarters
Wyoming:
State Highway Police
WDEQ (24 hour)
Wyo. Emergency Mgmt. Agency (Homeland Security)
Wyoming Department ofTransportation
Telephone No.
[phone]
[phone]
[phone]
[phone]
[phone]
[phone]
[phone]
[phone]
[phone]
[phone]
1-800-442-9090
[phone]
[phone]
[phone]
Transportation Accident Response Guide (Instructions to the Driver)
Federal & Canadian Agencies
Nuclear Regulatory Commission
Operations Center -Bethesda, Md.
Department of Transportation-
National Response Center
Ontario:
Provincial Police (24 hours)
Document Title: Instructions to
Driver Page: B-10
Telephone No.
[phone] or
[phone] or
(30 1) 415-0550
[phone] or
[phone]
[phone]
ON-SITE Transportation Accident Response Guide
For Pulling Unit Operators
1.) Introduction
Transportation accidents during the transport of radioactive concentrates from uranium
recovery facilities (byproduct, or wellfield equipment that will be stored and reused) occur
infrequently on public highways. This material is classified by DOT as radioactive material
shipped as excepted package or Surface Contaminated Object SC0-1 . Leakage or spillage
of the contents from its container can be a potential health hazard to persons if they ingest
or inhale the materials.
The purpose of this guideline is to provide direction for persons responding to a shipping
accident involving radioactive materials, particularly when the contents have leaked from
their containers. Leakage or spillage can range in severity depending on the specific
accident conditions.
The guideline provides instructions to the driver and to other persons who are the first to
arrive at the accident scene. These instructions request notifications be made to the shipper
and the carrier. If warranted, the shipper will dispatch an initial response team to assist with
accident investigation and response. The shipper vvill also alert a clean-up crew for possible
duty and provide guidance for securing clean-up equipment and services.
TO WHOM IT MAY CONCERN:
• Rescue and lifesaving may be conducted with minimal potential hazards from the cargo
on this truck. If possible, avoid breathing dust from spilled cargo. DO NOT DELAY
RESCUE EFFORTS!
• After needed rescue, lifesaving, first aid or firefighting, please read the attached
instructions in the event of cargo spillage.
Lifesavillg, Rescue, a11d Firefiglzting
This may be done with minimal potential hazards from the material. If possible, avoid
breathing and/or swallowing material that may be adhered to byproduct material or
wellfield equipment. The radioactive material on the skin or clothing is relatively harmless
and simple washing methods will remove it. If you believe you may have been
contaminated with the material, please notify first responders upon their arrival at the
accident site. To avoid ingestion of the material, do not eat, drink, or smoke while near the
spill.
Document Title: Instructions to
Driver Page: B-1 1
This vehicle contains radioactive materials, which may be in the fom1 of natural uranium
and associated daughter products. The color of the material may be red/orange or
white/yellow. The material cannot bum or explode. In the event of an accident involving
spillage of material, the following actions are recommended in the order given if
appropriate:
Co11tact S11pervisor
Contact your supervisor and give them the location of the accident site and tell them of any
injured persons. The supervisor will communicate with the SHEQ Department and the
RSO or their designees. Depending on the severity of the situation the Emergency
Response Team may also be initiated.
Initial respo11se
In the event of spilled radioactive materials, clean-up methods, monitoring, sampling and
release levels will be performed under the direction of the RSO or designee. Addition
requirements may also be applicable as per SHEQ Management System volume VIII.
Document Title: Instructions to
Driver Page: B-12
~¢;
Cameco
Cameco Resources
WYOMING OPERATIONS
EMERGENCY INFORMATION FOR CARRIERS
Approvals
Operations:
Project RSO: -~ CC>i.eM o.f)
Revision Date: ln/2016
TIDS VEHICLE CONTAINS: (CHECK THE APPROPRIATE DESCRIPTION OF THE CARGO)
0 URANIUM ORE CONCENTRATE (U30s or Yellowcake). The color may be black, greenish brown or
yellow, with a dry granular to powdery texture.
@ SOLID WASTE BYPRODUCT MATERIAL FROM THE PROCESSING OF URANIUM-
Material may vary from white sludge to contaminated pipe, pumps and assorted trash.
0 ION EXCHANGE RESIN CONTAINING ADSORBED URANIUM ON RESIN SURF ACE
IN THE EVENT OF AN ACCIDENT INVOLVING SPIT.LAGE THE FOLLOWING ACTIONS
ARE RECOMMENDED:
1. LIFESAVING
A. USE FIRST AID TREATMENT-according to the nature of the injury.
B. RADIOACTIVE MATERIAL-degree of hazard will vary from little to moderate.
C. AVOID SWALLOWING OR BREATHING DUST. DO NOT EAT, DRINK OR SMOKE
NEAR THE SPILL
D. LOW LEVEL RADIOACTIVE MATERIAL ON THE SKIN OR CLOTHING IS
RELATIVELY HARMLESS
E. REMOVE AND ISOLATE SUSPECTED CONTAMINATED CLOTHING AND SHOES
AS SOON AS POSSIBLE AND WASH AFFECTED SKIN AREAS WITH SOAP AND
WATER-DO NOT EAT, DRINK OR SMOKE UNTIL FREE OF CONTAMINATION.
2. FIRE FIGHTING
A. DO NOT MOVE DAMAGED CONTAINERS; MOVE UNDAMAGED CONTAINERS
OUT OF THE FIRE ZONE
B. SMALL FIRES: DRY CHEMICAL, C02, WATER SPRAY OR REGULAR FOAM.
C. LARGE FIRES: WATER SPRAY, FOG OR REGULAR FOAM.
3. SPILL OR LEAK
A. DO NOT TOUCH DAMAGED CONTAINERS OR SPIT.LED MATERIAL.
B. COVER DRY (POWDER) SPILL WITH PLASTIC SHEET OR TARP, TO MINIMIZE
SPREADING
C. ISOLATE AREA OF SPILL
D. KEEP UNNECESSARY PEOPLE AT LEAST 150 FEET UPWIND OF SPILL;
GREATER DISTANCES FOR PEOPLE DOWNWIND
Rev IS-Jan 7, 2016
Page I of2
J:\6) Emergency Preparedness and Response Program\\WYO-EPRP-01 (Volume VIII-Emergency Procedures)\ WYO-EPRP-01 (Forms)\ WYO-
EPRP-0 1.006 Emergency Information for Carriers .doc
~@-
Cameco WYOMING OPERATIONS
EMERGENCY INFORMATION FOR CARRIERS
Cumeeo Resources
NOTIFICATIONS
1. NOTIFY LOCAL LAW ENFORCEMENT AGENCY GIVING THEM SPECIFIC DETAILS RE-
GARDING THE ACCIDENT AND REQUEST THEY NOTIFY THE STATE HEALTH DEPART-
MENT AND TELL THEM CARGO IS:
D URANIUM ORE CONCENTRATE (UJOs OR YELLOWCAKE). "LOW SPECIFIC
ACTIVITY" (LSA) RADIOACTIVE MATERIAL
~OLIO WASTE BYPRODUCT MATERIAL FROM THE PROCESSING OF URANIUM
"LOW SPECIFIC ACTIVITY" (LSA) RADIOACTIVE MATERIAL OR SURF ACE
CONTAMINATED OBJECT (SC0-1)
0 ION EXCHANGE RESIN CONTAINING ABSORBED URANIUM ON RESIN SURF ACE
"LOW SPECIFIC ACTIVITY (LSA-1) RADIOACTIVE MATERIAL
2. NOTIFY ONE OF THE FOLLOWING CAMECO RESOURCES PERSONNEL AT [phone] DURING
BUSINESS HOURS OR CALL IN THE ORDER LISTED UNTIL ONE IS REACHED.
TRAVIS COLEMAN RADIATION SAFETY OFFICER
KEN GAROUTTE SHEQ MANAGER
CRAIG HISER MINE MANAGER
Rev 15-Jan 7,2016
Page 2 of2
OFFICE [phone] ext.43l
HOME [phone]
HOME [phone]
J:\6) Emergency Preparedness and Response Program\\WYO-EPRP-01 (Volume VIII-Emergency Procedures)\ WYO-EPRP-01 (Forms)\ WYO-
EPRP-01.006 Emergency Information for Carriers .doc
lhDioACTM MATIRIAU
(LowtoMODIIATI I.JVELIADLA110N)
• Radiallon praunla minimal rlak to tran1port workora, emargancy reaponae peraonntl, and
the public during tranaportallon eccldanta. Packaging durability 11 ralaled lo polanllal
.. ·: hazarda of malarial.
• Undamaged paekagu are nle; contents or damaged packagea may cauae external and/or
lnt11nal radlallon exposure.
'·
• Low radiation hazard when matarlallalnalde container. If material Ia rtluaed from pec:kaga
or bulk container, hazard will vary from low to modarala. level of hnard will daptnd on the
type and amount or radloacllvlly, the kind of malarial II I& In, and/or lht aurlaollllla on.
• Soma material may bt relaued from packagea during accidents of modtrate aeverlly, Thlt
paualllllt rllk to p•opls.
• Reltand radloacllvt malerlala or contaminated objeeta uaually will be vlalblelr pukaglng fall a.
• Some txclusivt uu thlpmenta of bulk and packaaad matarlalt will not have
'RADIOACTIVE'Iabtla. • Placerda, marking a, and ahlpplng papera provldaldanllncatlon.
• Soma paciagaa may hava a 'RADIOACTIVE' label and a ucond hazard label, The aacond
hazard Ia uaually greatarlhan the radiation huard; ao follow lhla Guida u wellatlha
raapanu Guide for the ucond hazarct claulabal.
f ~ •
' • Some radloacliva material a cannot be deleeted by commonly avallablalnalrumanla,
• RunoH from control or cargo fire may cauaelovt·lavel pollution.
r ' . "lti'~MIM&lbR ' I l I
• Some ol theu maltrlala may burn, but moat do nollgnlla readily.
I. • Uranium and Thorium metal cutting a or granulaa may Ignite tponlaneoualy Jr expoud to air (ue Gulda136).
• Nllratuare
i~ I::~·.' ,: ' Paper not or no anawer, refer to approp.rlata number . ... .
... ' · Ina Ide back cover. ,
1
;.;.:' : • Prlorlllu for reuu•,llf•·•avlng, flrttald,and control of flrt and other hnarda are
' •• '. ·... higher than the prhult~ for mtaauriDIJ radiation levela, ~'.' ·!.~ • Radiation Authority must ba nottned of accldant condition a, end Is ueually reeponalble for
.. :~ · :· radiological declalona.
· '! .: , • laolate aplll or leak ern Immediately for alleaat 25to 60 mele11 (80 to 180 feel) In all
·.~ .. ··•· dlfecllona. • Slay upwind. • Keep unauthorized peraonntlaway. '~:;; ··~ • De11tn or l•olate uninJured peraona or tqulpmentauapectad to be contaminated; delay -'l:.l.·.~·· decontamlnellon end cleanup unllltnatrucllona ate received from Redlellon Authority. :f~BtiMIOieam41AI .1(:··~1: • Poaltlve prauuia aelf-contalned breathing apparalua (SCBA) and alruclural flreftghtera' protective clothing will provide adequate protection.
~;c 11 1\I.#U,I\
. ~ Lara• Spill · ;;;-.:,1, • Conaldtr Initial downwind evacuation for allual1 00 me lara (330 feel).
,,:~··'·: Fir•
.( ,.,
·'
. ' . !· I, . ~.~
:r '' ·: · When a laru•. quenllly of thla material h Involved In a maJor nra, fonalder an lnlllal
lfil ., r . .: ".·:~::~lon d~tlanct ol 300 mut•n I tooo feel) In all dlr~c~.~~~.': ... , ~·,., ,.,...·=•···"··•····"'·r ..... .-·---·--·
,• I
~
• Pruance of radloacUve materiel will not chango effecllvaneu of nre controltechnlqu
• Uove contelnera lram hre area II you can do 11 wllhout rlak. "·
• Po not move damagad packagaa: move undamaged pukaget out of fire zone l11all Fires ·
• Dry chemical, CO,, Wiler apray or regular foam.
Large Ftrta
• Walar spray, fog (flooding amounta).
• Olkt fill• control water for later dlapoul.
Plt11itiMtW
• Do not touch damaged packlgea or aplllad material.
Liquid I pUla .
• Covar With a and, nrth or olhar noncombiJallble ab•orbent malarial.
1 Pika to collacllaraellquld apllla.
1 Covtr powdoraplll wllh plaallo thtal or tarp to minimize apr11dlng,
I'INitXib
• Medical problamalakt priority ovar radiological concern a.
• Uu ftratald treatmantacoordlng lo I he natura of lhalnJury.
• Do no I delay cart and Iran aport of a aarlously Injured penon.
• Apply artlnclal reaplrallon II vlclfm Ia not breathing.
• Admlnlaleroxygen If breathing Ia difficult.
• In oa1n of llonlaal with aubtiiiOCII, wlpt from skin Immediately· flush akin or eyaa wllh runn ng water far atlt~al20 mlnute1• '
• lnJu1rlldtpdtrtDil& who contacted relaaud malarial may be a minor contamination problem 10 .;..: con ac t pa11ona, equipment and faclllllaa •
• Enaurethat medloal pertoftnelara aware of the material( a) Involved and take praoaullona to protaclthamaalvaa. '
.~e-
Cameco
Conforms to ANSI Z400.1/Z129.1-2010 Standard-United States, Canada
Safety Data Sheet
Uranium Peroxide Hydrate
11. Product and company identification
Product name Uranium Peroxide Hydrate
Common name
Material uses
MSDS#
Supplier/Manufacturer
MSDS authored by
In case of emergency
12. Hazards identification
Emergency overview
Physical state
Color
Odor
GHS Label Elements
Pictogram
Signal word
Hazard statements
Precautionary
measures
OSHA/HCS status
Routes of entry
Version: 3
U04, peroxide yellowcake, yellowcake, peroxide uranium ore concentrate, uranyl
peroxide
Concentrate produced from the milling of the uranium ore for processing at a
refinery
Cameco 141 E
Rabbit Lake Operation
c/o Cameco Corporation
2121 11th Street West
Saskatoon, Saskatchewan
Canada S7M1J3
Tel: [phone]
Fax: [phone]
KMK Regulatory Services Inc.
1 905 885 8745
Solid (Powder)
Yellow
No odor
DANGER
Toxic by inhalation and ingestion
Danger of cumulative effects
May damage kidneys
Cameco Resources
Crow Butte Operation
86 Crow Butte Roa~
Crawford, NE 6933!:!
USA
Tel: [phone]
Fax: [phone]
· Cameco Resources
Smith Ranch Highland
P.O. Box 1210
Glenrock; Wy 82637
USA
Tel: [phone]
Fax: [phone]
Do not breathe dust. Do not ingest. Do not get on skin or clothing. Use only with adequate
ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes.
Keep container closed. Wash thoroughly after handling.
This material is considered hazardous by the OSHA Hazard Communication Standard (29
CFR 1910.1200)
Dermal contact, via cuts abrasion or open wounds. Eye contact. Inhalation. Ingestion.
1110 Date: 01 Oct 2015
Potential acute health effects
Inhalation
Ingestion
Skin
Eyes
Uranium Peroxide Hydrate 2119
Harmful if inhaled. Kidney damage can occur due to chemical toxicity. Dissolution ·halftime
of UOaH20 is fast for the synthetic lung fluid solubility test. Oust inhalation can result in
an internal dose from alpha, beta and gamma radiation.
Harmful if swallowed. Kidney damage can occur due to chemical toxicity.
Skin dermatitis may result from skin contact.
Irritating to eyes.
Potential chronic health effects
Chronic effects
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental
effects
Fertility effects
Target organs
May cause target organ damage, based on animal data. Repeated or prolonged inhalation
of dust may lead to chronic respiratory irritation.
Not listed as a carcinogenic material by IARC or OSHA. Soluble and insoluble compounds
of uranium are listed as potential occupational carcinogens by NIOSH, and confirmed
human carcinogens by ACGIH, based on evidence from epidemiological studies.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
May cause damage to following organs: kidneys
Over-exposure signs/symptoms
Inhalation
Ingestion
Skin
Eyes
Medical conditions
aggravated by over-
exposure
Adverse symptoms may include the following:
respiratory tract irritation, coughing
Chemical toxicity is largely shown in kidney damage that may not be reversible
Prolonged contact can result in dermatitis
Adverse symptoms may include the following:
pain or irritation
watering
redness
Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk
may be aggravated by over-exposure to this product.
See toxicological information (Section 11)
13. Composition/information on ingredients
United States
Name
Uranium Peroxide Hydrate
Canada
Name
Uranium Peroxide Hydrate
CAS number
19525-15-6
CAS number
19525-15-6
%
>95
%
>95
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health of the environment and hence require reporting in this section.
14. First aid measures
Eye contact
Version: 3
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for
at least 20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention.
Date: 01 Oct 2015
Skin contact
Inhalation
Ingestion
Protection of first-
aiders
Notes to
physician
Uranium Peroxide Hydrate 3/10
In case of contact, immediately flush skin with plenty of water for at least 20 minutes.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical
attention immediately.
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical doctor or
poison control center immediately.
No acticn shall be taken involving any personal risk or without suitable training. If it is
suspected that dust is present. It may be dangerous to the person providing aid to give
mouth-to mouth resuscitation. Rescuer should wear and appropriate mask or self-
contained breathing apparatus. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves.
No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
Is. Fire-fighting measures
Flammability of
the product
Extinguishing media
Suitable
Not suitable
Special exposure
hazards
Hazardous thermal
decomposition
products
Special protective
equipment for fire-
fighters
Special remarks on
fire hazards
Not flammable
COz, dry chemical, foam, alcohol-type foam, water fog
None known.
Possible presence of radioactive uranium dust. No action shall be taken involving any
personal risk or without suitable training.
Uranium peroxide hydrate decomposes to produce uranium trioxide (U03) powder and
oxygen (02) gas at high temperatures. Steam will be generated from water of hydration.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-shield operated in positive pressure mode.
Uranium peroxide hydrate decomposes to produce uranium trioxide (U03) powder and
oxygen (02) gas at high temperatures. The 02 gas will increase the explosive limit range
and rate of burning for flammable and combustible materials in the vicinity.
Is. Accidental release measures
Personal
precautions
Environ mental
precautions
Methods for cleaning up
Small Spill
Version: 3
No action shall be taken involving any personal risk or without suitable training. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Do not breathe dust. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment (see Section 8).
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers by covering with a suitable cover. Drums of the material are to be shipped to the
nearest Cameco Corporation facility or other licensed repository that can handle the
material. Forward any contaminated clothing or equipment in separate marked drums.
Inform the relevant authorities if the product has caused environmental pollution in sewers,
waterways soil or air.
Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum dust
with equipment fitted with a HEPA filter and place in a closed, labeled waste container.
Dispose of via a licensed waste disposal contractor. Note: See Section 1 for emergency
contact information and Section 13 for waste disposal.
Date: 01 Oct 2015
(4; Uranium Peroxide Hydrate 4/1jJ
Camcco
Large Spill Move containers from spill area. Cover suitably to prevent dispersal by wind and
precipitation. Prevent entry into sewers, water courses, basements or confined areas.
Approach release from upwind. Avoid dust generation. Do not dry sweep. Vacuum dust
with equipment fitted with a HEPA filter and place in a closed, labeled waste container.
Dispose of via a licensed waste disposal contractor. Note: See Section 1 for emergency
contact information and Section 13 for waste disposal.
11. Handling and storage ·---------~
Handling Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas. Do
not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in use.
Empty containers retain product residue and can be hazardous. Do not reuse container. In
extremely rare occurrences, sealed drums of uranium peroxide can become pressurized
with oxygen gas from decomposition. If signs of pressurization are observed (bulging lids
and/or bottoms), do not handle the drums until they are evaluated by qualified uranium
fuel cycle personnel who will determine safe handling procedures.
Storage Uranium peroxide concentrates is shipped from the uranium mill to the refinery in a 200 L
sealed steel drum. Store in accordance with radiation protection regulations in sealed
containers. Store in original container away from extreme heat, incompatible materials
(see Section 1 0) and food and drink. Keep container tightly closed and sealed until ready
for use. Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination. In extremely rare occurrences, sealed drums of
uranium peroxide can become pressurized with oxygen gas from decomposition. If signs
of pressurization are observed (bulging lids and/or bottoms), do not handle the drums until
they are evaluated by qualified uranium fuel cycle personnel who will determine safe
handling procedures.
Ia. Exposure controls/personal protection
United States
Ingredient Exposure limits
Uranium peroxide ACGIH TLV (United States, 3/2012) TWA: 0.2 mg/m3, (as U) 8 hours
hydrate STEL: 0.6 mo/m3, ·(as t..h 15 minutes
OSHA PEL (United States, 6/2010) TWA: 0.25 mg/m3, (as U) 8 hours
NIOSH REL (United States, 6/2009) TWA: 0.2 mg/m3, (as U) 1 0 hours
STEL: 0.6 mq/m3, (as U) 15 minutes
Canada
Occupational exposure TWA (8 hours) STEL (15 mins) Ceiling
limits
Ingredient List name ppm mg/m3 Other ppm mg/m3 Other ppm mg/m3 Other ~otations
Uranium USACGIH 0.2 0.6
peroxide 3/2012
hydrate, as U AB 4/2009 0.2 0.6
BC 4/2012 0.2 0.6
ON 7/2010 0.2 0.6
QC 9/2011 0.2 0.6
Version: 3 Date: 01 Oct 2015
(~· Uranium Peroxide Hydrate 5/10
Came co
Consult local authorities for acceptable exposure limits.
Recommended
monitoring
procedures
Engineering
measures
Hygiene measures
Personal protection
Respiratory
Hands
Eyes
Skin
Environmental
exposure controls
If this product contains ingredients with exposure limits, personal, workplace, atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation
or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to appropriate monitoring standards. Reference to national
guidance documents for methods for the determination of hazardous substances will also
be required.
Use only with adequate ventilation. Use process enclosures or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. This may require HEPA filtration of exhaust air.
Wash hands, forearms and face thoroughly after handling, before eating, smoking and
using the lavatory and at the end of the working period. Appropriate techniques should be
used to remove potentially contaminated clothing. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers are close to the workstation
location. Contamination monitoring may be required for activities with direct exposure.
Use a properly fitted particulate filter respirator complying with an approved standard.
Respirator selection must be based on known or anticipated exposure levels, the hazards
of the product and the safe working limits of the selected respirator.
Chemical resistant impervious gloves complying with an approved standard should be
worn at all times when handling. Considering the parameters specified by the glove
manufacturer, check during use that the gloves are still retaining the protective properties.
It should be noted that the time to breakthrough for any glove material may be different for
different glove manufacturers. Recommended : Rubber or neoprene for normal industrial
use
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles
Personal protective equipment for body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product. Recommended: long sleeved coveralls
Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary
to reduce emissions to acceptable levels.
js. Physical and chemical properties
Physical state Solid (Powder)
Flash point
Burning time
Burning rate
Auto-ignition
temperature
Flammable limits
Color
Odor
Taste
Version: 3
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Yellow
Odorless
Not applicable
Date: 01 Oct 2015
~~GI
Cameco
Molecular weight
Molecular formula
pH
Boiling/condensation
point
Melting/freezing point
Critical temperature
Specific Gravity
Vapor pressure
Volatility
Odor threshold
Evaporation rate
SADT
Viscosity
tonicity (in water)
Dispersibility
properties
Solubility
Partition coefficient
(log Kow)
Physical/chemical
properties comments
11 D. Stability and reactivity
Chemical stability
Conditions to
avoid
Incompatible
materials
Hazardous
decomposition
products
Possibility of
hazardous
reactions
Uranium Peroxide Hydrate
338 g/mole
U04.2H20
Not applicable
Decomposes
Decomposition temperature: 160 to 230 cc (320 to 446 °F)
Not applicable
4 to 4.4
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Negligible
Not applicable
Not applicable
•
The product is stable under normal* conditions.
6/10
* Normal conditions in an operating environment: pressure 0.9 bar to 1.1 bar, oxygen 21%
v/v, temperature from 0 to 30 oc
Avoid extremely high temperatures.
Strong mineral acids such as nitric, sulphuric or hydrochloric acids.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced. Uranium peroxide hydrate decomposes to produce uranium trioxide
(U03) powder and oxygen {Oz) gas at temperatures at high temperatures.
Under normal conditions of storage and use, hazardous reactions will not occur.
111. Toxicological information
Acute toxicity
Uranium is a nephrotoxin {a kidney poision). Studies indicate that long term exposure may result in kidney impairment.
While an LDso of 70 mg/kg has been estimated for soluble uranium salts{ Kathren and Burklin (2008)], but insoluble
uranium compounds were found to be practically non-toxic, indicating LDso for insoluble salts such as uranium peroxide
hydrate should be much higher.
Version: 3 Date: 01 Oct 2015
ᢥ
Cumcco
Chronic toxicity
There is no data available
Irritation/Corrosion
Skin
Eyes
Respiratory
Sensitizer
Skin
Respiratory
Carcinogenicity
Classification
Product/ingredient
name
Uranium peroxide
hydrate
Mutagenic it\!
Uranium Peroxide Hydrate
There is no data available
There is no data available
There is no data available
There is no data available
There is no data available
ACGIH I ARC
A1 -
EPA
-
7/10
NIOSH NTP OSHA
+ --
There is some evidence of genetic effects from radiation in animal studies, however there has been no evidence
reported in human studies.
Teratogenicity
There is no data available
Reprodcutive toxicity
There is limited available data on the reproductive toxicity in humans.
IDLH 10 mg U/m3
112. Ecological information
Ecotoxicity
Aquatic ecotoxicity
Green algae LOEC 70-170 fJQ/l; mussels ECso 380-600 J.Jg/L (Warne et al. 2009)
Persistence/degradabilitv
Sediments act as sinks for insoluble uranium compounds.
113. Disposal considerations
Waste disposal Scrap uranium peroxide hydrate should be recycled through an appropriate licenced
facility. Contaminated uranium peroxide hydrate must be disposed of as radioactive waste,
rather than as hazardous chemical waste. It is recommended to consult local state and
federal regulations and Cameco corporation to determine appropriate disposal routes for
uranium peroxide hydrate waste.
Disposal should be in accordance with applicable national, regional and local Jaws and regulations.
Refer to Section 7: HANDLING AND STORAGE and SECTION 8. EXPOSURE CONTROL/PERSONAL PROTECTION for additional
handling information and protection of employees.
14. Transport information
Regulatory I UN number J Proper shipping I Classes I PG•
information name
Version: 3
I Label I Additional
information
Date: 01 Oct 2015
ᢥ
Came co
DOT
Classification
TOG
Classification
IMDG Class
IATA-DGR Class
UN2912
UN2912
UN2912
UN2912
Uranium Peroxide Hydrate
RADIOACTIVE
MATERIAL, LOW
SPECIFIC
ACTIVITY (LSA-1)
(non fissile or
fissile excepted)
RADIOACTIVE
MATERIAL, LOW
SPECIFIC
ACTIVITY (LSA-1)
(non fissile or
fissile excepted)
RADIOACTIVE
MATERIAL, LOW
SPECIFIC
ACTIVITY (LSA-1}
(non fissile or
fissile excepted)
7
7
7
RADIOACTIVE 7
MATERIAL, LOW
SPECIFIC
ACTIVITY (LSA-1}
(non fissile or
fissile excepted)
PG*: Packing group Exemptions to the above classification may apply. AERG : 162
115. Regulatory information
United States
HCS
Classification
U.S. Federal
regulations
Clean Air Act
Sction 112 (b)
Hazardous Air
Pollutants (HAPs)
Clean Air Act
Section 602 Class
I Substances
DEA List II
Chemicals
(Precursor
Chemicals)
DEA List II
Chemicals
(Essential
Chemicals)
SARA 302/304
Toxic material
Carcinogen
Target organ effects
TSCA S(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA8b}: Not determined
Not listed
Not listed
Not listed
Not listed
Composition/information on ingredients
No products were found
Version: 3
8/10
Emergency
schedules
(EmS) F-1,
S-S
Date: 01 Oct 2015
~SARA 304RQ
SARA 311/312
Classification
Uranium Peroxide Hydrate
Not applicable
Not applicable
Composition/information on ingredients
No products were found.
State regulations
Massachusetts
New York
New Jersey
Pennsylvania
California Prop. 65
Canada
WHMIS(Canada)
Canadian lists
Canadian NPRI
Canadian ARET
CEPA Toxic
substances
Alberta
Designated
Substances
Ontario
Designated
Substances
Quebec
Designated
Substances
Canada Inventory
International regulations
International lists
This material is not listed
This material is not listed
This material is not listed
This material is not listed
No products were found
Class D-18: Material causing immediate and serious toxic effects (roxie)
Class D-2A: Material causing other toxic effects (Very Toxic)
This material is not listed.
This material is not listed.
This material is not listed.
This material is not listed.
This material is not listed.
This material is not listed.
This material is listed or exempted.
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
9/10
New Zealand Inventory of Chemicals (NZioC): Not determined. Philippines inventory
(PICCS): Not determined.
Taiwan inventory (CSNN): Not determined.
116. Other information
Hazardous Material
Information System (U.S.A)
Health a fl
~Flammability ~m-
lllllllllmliiiit~
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing
llersion: 3 Date: 01 Oct 2015
(@t
CanJCco
Uranium Peroxide Hydrate 10/10
significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer
may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered
mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purcha11ed exclusively from J. J. Keller
(SOD) 327-6868. The customer is responsible for determining the PPE code for this material.
National Fire Protection
Association (U.S.A) He~tth ~ FJ.mmability
~ Instability
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material
is not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is
intended to be interpreted and applied only by properly trained individuals to identify fire, health and
reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with
recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether
the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at
their own risk.
History
Date of Issue
Date of previous
issue
Version
Revised
Section(s)
Notice to reader
01 October 2015
12 December 2013
3
2, 16
To the best of our knowledge the information contained herein is accurate. However, neither the above named supplier,
no any of the subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information
contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards that exist.
MSD~M.}I
~~~''~ .... ~·,.~~-.~~,~v.ooeft,."'C..'
Version: 3 Date: 01 Oct2015
3129/2016 State of Utah Mail-Notification of leaking 11e.(2) shipment arriving at the White Mesa Uranium Mill
Ryan Johnson <[e-mail]>
Notification of leaking 11e.(2) shipment arriving at the White Mesa Uranium Mill
1 message
Ryan Johnson <[e-mail]> Tue, Mar 29 , 2016 at 2:07PM
To: [e-mail], [e-mail]
Cc : "Goble, Phillip" <[e-mail]>, Scott Anderson <[e-mail]>
Linda,
This morning the RSO of the White Mesa Uranium contacted the Utah Division of Waste Management and
Radiation Control (DWMRC). He informed the DWMRC that a 11e.(2) shipment arrived at their facility with
evidence that some of the contents had leaked from the shipping container. This shipment originated from the
Cameco-Smith Ranch in Wyoming, with the contents of the shipment to be disposed of in White Mesa's tailing
cells .
We are notifying you of this incident because Cameco-Smith Ranch is an NRC licensed facility (NRC RML SUA
1548). This is the second incident that the DWM RC is aware of with 11 e(2) shipments originating from the
Cameco-Smith Ranch facility in Wyoming. The last incident occurred on August 20 , 2015. We will send you
more information when the Mill send us their formal report on the incident
Ryan Johnson, P.G.
Environmental Scientist/Health Physicist
Utah Division of Waste Management and Radiation Control
Disclaimer:
Statements made in this e-mail do not constitute the official position of the Director of the Division of Waste
Management and Radiation Control. If you desire a statement of the Director's position, please submit a written
request to this office, on paper, including documents relevant to your request
https://mail.google.com/mail/u/O/?ui=2&ik=309d40f566&view=pt&search=sent&th=153c3fce2681d645&siml=153c3fce2681d645 1/1