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DRC-2016-004798 - 0901a06880616489
Kv 9 <> ,/f » V®, State of Utah GARY R HERBERT Governor SPENCERJ COX Lieutenant Governor Department of Environmental Quality Alan Matheson Executive Director DIVISION OF WASTE MANAGEMENT AND RADIATION CONTROL Scott T Anderson Director MEMORANDUM TO: Phil Goble / FROM: Dean Henderson DATE: February 4, 2016 SUBJECT: Review of the 3rd Quarter 2015 Nitrate Monitoring Report for the Nitrate Contamination Investigation, Energy Fuels Resources (USA) Inc. (“EFR“) White Mesa Uranium Mill, near Blanding, Utah The Utah Division of Waste Management and Radiation Control (“Division”) has reviewed the EFR November 23, 2015, White Mesa Uranium Mill 3rd Quarter, 2015 Nitrate Monitoring (“Report”) for the Nitrate Contamination Investigation. For the review of this Report the following regulatory enforcement documents were used: • Corrective Action Plan for Nitrate White Mesa Uranium Mill near Blanding, Utah, May 7, 2012, (“CAP”) approved December 12, 2012. • The EFR Quality Assurance Plan, June 7, 2012, Revision. 7.2 (“QAP”) REVIEW Monitor Well Sampling for the 3rd Quarter 2015 In the quarter the following monitor wells were sampled and analyzed for inorganic chloride and nitrate + nitrite (as N) as required in the CAP: TWN-1, TWN-2, TWN-3, TWN-4, TWN-7, TWN-18, TW4-22 (pumping well), TW4-24 (pumping well), and TW4-25 (pumping well), and Piezometer 1, Piezometer 2, and Piezometer 3. In each quarter the monitoring wells were purged using the three approved QAP well purging strategies and meet QAP requirements for each strategy: 195 North 1950 West • Salt Lake City, UT Mailing Address P O. Box 144880 • Salt Lake City, UT 84114-4880 Telephone (801) 536-0200 • Fax (801) 536-0222 -TDD (801) 536^4414 wuxw deq Utah gov Printed on 100% recycled paper Page 2 1. Purging two casing volumes with stable field parameters for specific conductivity, turbidity, pH, redox potential, and water temperature (within 10% RPD): Wells: TWN-1, TWN-4, and TWN-18. 2. Purging a well to dryness and stability of field parameters for pH, specific conductivity, and water temperature only after recovery: Wells: TWN-3 and TWN-7 3. Continuously Pumped Wells that are considered sufficiently evacuated to immediately collect a sample: Wells: TWN-2, TW4-22, TW4-24, and TW4-25 Chloride and nitrate + nitrite (as N) were analyzed for methods consistent with the requirements of the QAP. QAQC Holding Times The method holding times for the quarter and parameter for samples collected at each monitor well were received and analyzed within the required holding times in the QAP. Receipt Temperature All samples were received within the required QAP temperature limit of 6° C. Detection Limits All sample sets were measured and reported to the required QAP reporting limits. Sample Duplicates One duplicate sample was collected for the quarter. A duplicate of TWN-4 was the collected and identified as TWN-65. The duplicate sample analytical results for this sample/duplicate pairs were within the 20% acceptance limits as required in the QAP (see Table 2 below). Groundwater Head Monitoring for 3rd Quarter 2015 Depth to groundwater was measured in the following wells and/or piezometers as required in Part I.E.3 of the Permit: • The quarterly groundwater compliance monitoring wells. • Existing monitoring well MW-4 and all of the temporary chloroform investigation wells. • Piezometers P-1, P-2, P-3, P-4 and P-5. • MW-20, MW-22 and MW-34 • Nitrate monitoring wells. Page 3 • The DR piezometers which were installed during the Southwest Hydrologic Investigation. In addition to the above, depth to water measurements are routinely observed in conjunction with sampling events for all wells sampled during quarterly and accelerated efforts, regardless of the sampling purpose. All well levels used for groundwater contour mapping were measured and recorded within 5 calendar days of each other. Estimation of Pumped Nitrate Mass Removal The 3rd Quarter 2015 report reported estimated 118.6 lbs. of nitrate were removed from the chloroform pumping wells (MW-4, MW-26, TW4-1, TW4-2, TW4-4, TW4-11, TW4-19, and TW4-20) and the nitrate pumping wells (TWN-2, TW4-22, TW4-24, and TW4-25). Of the 118.7 lbs. removed approximately 107.6 lbs. or 91%, was removed by the pumping wells inside the nitrate plume. In the attached Table 3, the DWMRC shows calculations that verify these reported estimates. Reporting Each Report included the following information as required in the CAP: a) Introduction b) Sampling and Monitoring Plan: i. Description of monitor wells sampled; ii. Description of sampling methodology, equipment and decontamination procedures; iii. Identification of all quality assurance samples, e.g. equipment blanks duplicate samples, etc. c) Data Interpretation: i. Interpretation of groundwater levels, gradients, and flow directions. The interpretation will include a discussion on: 1) current site groundwater contour map, 2) hydrographs to show groundwater elevation in each monitor well over time, 3) depth to groundwater measured and groundwater elevation from each monitor well summarized in data table that includes historic groundwater level data for each well, 4) calculations documenting quarterly nitrate mass removed by pumping; ii. Interpretation of all analytical results for each well including a discussion on: 1) a current nitrate isoconcentration map, 2) graphs showing nitrate concentration trends in each well through time and, analytical results for each well summarized in data table that includes historic analytical results for each well; and iii. An electronic copy of all laboratory results for groundwater quality monitoring conducted during the quarter will be provided to the Executive Secretary. d) Conclusions and Recommendations Page 4 e) Copies of EFR field reports, laboratory reports, and chain of custody forms. The nitrate plume is defined to include any monitoring well that has concentration of nitrate in excess of 10 mg/L. Evaluation of the Chloroform Contaminate Plume and Its Associated Contaminants Bounding And Hydraulic Control of the Chloroform Plume Groundwater monitoring data up to the 3rd Quarter, 2015 monitoring event appeared to show that the nitrate contaminate plume (“Plume”) is bound by up gradient, cross gradient, and down gradient wells that have a nitrate concentrations of <10 mg/L (GWQS = 10 mg/L). In addition, based on water level data, groundwater contour, and capture zone maps in the Report it appears that upgradient of pumping wells TW4-19, TW4-20, TW4-22, TW4-24, and TW4-37 the nitrate Plume is being captured. Conclusions on Compliance with the CAP, QAP Per the Division review it appears that the 3rd Quarter 2015 Nitrate Monitoring Report for the Nitrate Contamination Investigation, Energy Fuels Resources (USA) Inc. complies with the CAP and QAP. Therefore, a letter will be drafted for the Director Signature, notifying EFR of the review and closing- out of this report. Page 5 References Energy Fuels Resources (USA) Inc., June 7, 2012, White Mesa Uranium Mill, Ground Water Monitoring Quality Assurance Plan (Revision 7.2). HYDRO GEO CHEM, INC, May 7, 2012, Corrective Action Plan for Nitrate White Mesa Uranium Mill near Blanding, Utah Page 5 References Energy Fuels Resources (USA) Inc., June 7, 2012, White Mesa Uranium Mill, Ground Water Monitoring Quality Assurance Plan (Revision 7.2). HYDRO GEO CHEM, INC, May 7, 2012, Corrective Action Plan for Nitrate White Mesa Uranium Mill near Blanding, Utah Table 1 of 1 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-1 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-2 (Pumping well starting in January 2013) Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/17/2010 2nd Qtr 5/26/2010 3rd Qtr 9/27/2010 4th Qtr 12/7/2010 1st Qtr 1/26/2011 2nd Qtr4/20/2011 3rd Qtr 7/26/2011 4th Qtr 10/17/2011 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 10/17/2012 1st Qtr 2/18/2013 2nd Qtr 4/23/2013 3rd Qtr 8/27/2013 4th Qtr 10/16/2013 1st Qtr 1/14/2014 2nd Qtr 5/6/2014 3rd Q.tr 8/5/2014 4th Qtr 10/8/2014 1st Qtr 2/18/2015 TWN-65 dup of TWN-1 2nd Qtr 5/13/2015 3rd Qtr 8/25/2015 0.5 0.6 0.6 0.6 6.5 0.5 0.5 0.5 17 20 19 14 1st Qtr 3/24/2010 2nd Qtr 6/2/2010 3rd Qtr 9/29/2010 4th Qtr12/9/2010 17 19 14 10 1st Qtr 2/1/2011 2nd Qtr4/28/2011 3rd Qtr 7/28/2011 4th Qtr 10/20/2011 0.6 0.6 0.6 0.43 15 17 17 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/31/2012 17.5 4th Qtr 7/17/2012 Nitrate Pumping System Started in January 2013 0.68 0.84 1.24 1.61 1.47 1.63 1.7 1.46 1.37 1.41 0.65 0.624 17.6 17.4 24.1 26.8 29.2 31.1 28 27.6 27.8 29.0 29.2 33.2 1st Qtr 2/19/2013 2nd Qtr4/24/2013 3rd Qtr 8/27/2013 4th Qtr 7/16/2013 1st Qtr 1/13/2014 2nd Qtr 5/7/2014 3rd Qtr 8/6/2014 4th Qtr 10/8/2014 1st Qtr 2/18/2015 2nd Qtr 5/12/2015 3rd Qtr 8/25/2015 62.1 69 69 __48 43 40 33 33 ......31 48 54 22.10 .:-57,3 57.7 80.0 111 42.6 44.7 42.0 71 48.6 52.8 49.7 85 97 104 93 93 85 74 76 86 103 93 79 80.5 82.1 75.9 70.4 72.4 84.9 80 81 87.8 83.6 87.8 Monitoring Event TWN-3 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-4 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/25/2010 2nd Qtr 6/3/2010 3rd Qtr 7/16/2010 4th Qtr 12/10/2010 1st Qtr 2/1/2011 2nd Qtr 4/28/2011 3rd Qtr 7/29/2011 4th Qtr 10/20/2011 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/31/2012 4th Qtr 10/17/2012 1st Qtr 2/19/2013 2nd Qtr 4/24/2013 3rd Qtr 8/28/2013 4th Qtr 10/17/2013 1st Qtr 1/15/2014 2nd Qtr 5/7/2014 3rd Qtr 8/6/2014 4th Qtr 10/9/2014 1st Qtr 2/19/2015 2nd Qtr5/14/2015 3rd Qtr 8/26/2015 25.3 26 27 24 111 118 106 117 1st Qtr 3/16/2010 2nd Qtr 5/27/2010 3rd Qtr 9/27/2010 4th Qtr 12/8/2010 24 26 25 25 138 128 134 129 1st Qtr 1/25/2011 2nd Qtr 4/20/2011 3rd Qtr 7/26/2011 4th Qtr10/18/2011 25 24 27 12.1 143 152 158 149 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/25/2012 4th Qtr 7/15/2012 Nitrate Pumping System Started in January 2013 22.2 27.2 20.9 23.5 19.6 23.6 19.5 19.1 19.4 17.2 16.2 157 158 171 163 160 168 174 153 164 141 156 1st Qtr 2/18/2013 2nd Qtr 4/23/2013 3rd Qtr 8/27/2013 4th Qtr 7/16/2013 1st Qtr 1/14/2014 2nd Qtr 5/6/2014 3rd Qtr 8/5/2014 4th Qtr 10/8/2014 1st Qtr 2/18/2015 2nd Qtr 5/13/2015 3rd Qtr 8/25/2015 TWN-65 dup of TWN-4 0.9 1.0 0.9 1.0 0.9 0.9 1.1 0.9 0.9 1.1 1.4 1.45 1.5 1.63 1.6 1.69 1.4 1.6 2.0 1.44 1.48 0.733 0.974 1.160 22 22 19 21 21 21 35 20 ....20 24 ....25 26.4 25.3 24.4 27.2 29.4 28.4 29.6 28 30.7 31.5 31.9 35.2 35.2 Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I Table 1 of 2 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-5 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-6 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/16/2010 2nd Qtr 5/26/2010 0.3 43 44 1st Qtr 3/23/2010 2nd Qtr 6/1/2010 1.5 1.4 19 22 3rd Qtr 7/12/2010 4th Qtr12/7/2010 1st Otr1/25/2011... 2nd Qtr 4/20/2011 3rd Qtr 7/26/2011 4th Qtr10/17/2011 0.3 0.3 0.3 0.4 0.3 0.3 0.3 43 45 47 44 44 45 3rdQtr 7/13/2010 4th Qtr 12/7/2010 1st Qtr 1/26/2011 1.4 1.2 73 21 1.1 1.5 18 222nd Qtr 4/20/2011 3rd Qtr 7/27/2011 4th Qtr 10/18/2011 1.1 1.4 17 21 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 10/15/2012 0.2 0.3 0.3 <0.1 45 39 48 43.5 1st Qtr 1/10/2012 2nd Qtr 4/18/2012 3rd Qtr 7/25/2012 4th Qtr 7/15/2012 1.2 1.1 20 22 1.4 0.78 22 20.4 1st Qtr 2013 NA 2nd Qtr 2013 NA 1st Qtr 2013 2nd Qtr 2013 NA NA TWN-5 abandoned on July 31, 2013 3rd Qtr 2013 4th Qtr 2013 NA NA 1st Qtr 2014 2nd Qtr 2014 3rd Qtr 2014 NA NA 4th Qtr 2014 1st Qtr 2015 2nd Qtr 2015 3rd Qtr 2015 NA NA NA NA NA Monitoring Event TWN-7 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-8 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/17/2010 2nd Qtr 5/28/2010 3rd Qtr 7/14/2010 4th Qtr12/10/2010 1st Qtr 1/27/2011 2nd Qtr 4/21/2011 3rd Qtr 7/29/2011 4th Qtr10/19/2011 0.8 1.2 1.8 1 1.3 1.7 0.7 2.2 1st Qtr 3/16/2010 2nd Qtr 5/26/2010 3rd Qtr 7/12/2010 4th Qtr 12/7/2010 <0.1 <0.1 <0.1 11 11 11 <0.1 1st Qtr 1/25/2011 2nd Qtr 4/19/2011 3rd Qtr 7/26/2011 4th Qtr 10/17/2011 <0.1 <0.1 <0.1 <0.1 9....13 10 18. 10 11 15 11 11.4 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 3rd Qtr 7/26/2012 4th Qtr 10/16/2012 2.3 1.2 0.9 0.64 5’ 6 6 5.67 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 7/15/2012 <0.1 <0.1 <0.1 <0.1 1st Qtr 2/19/2013 2nd Qtr 4/24/2013 3rd Qtr 8/28/2013 4th Qtr 10/16/2013 1st Qtr 1/15/2014 2nd Qtr 5/7/2014 3rd Qtr 8/6/2014 4th Qtr 10/9/2014 1st Qtr 2/19/2015 2nd Qtr 5/14/2015 3rd Qtr 8/6/2014 Nitrate Pumping System Started in January 2013 0.59 1.16 0.835 0.986 0.882 0.564 ...0.9 0.968 1.04 0.779 0.348 5.68 5.88 6.96 5.7 5.75 5.26 ....6 5.93 5.58 6.18 6.12 1st Qtr 2013 2nd Qtr 2013 NA NA TWN-8 abandoned on July 31, 2013 Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I NA = Per the CAP and SCO, these wells not sampled 2013 Table 1 of 3 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-9 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-10 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/23/2010 2nd Qtr 6/1/2010 3rd Qtr 7/15/2010 4th Qtr 12/9/2010 7.6 7.7 10.7 8.0 183 175 1st Qtr 3/23/2010 1.5 210 172 2nd Qtr 6/2/2010 3rd Qtr 7/14/2010 4th Qtr12/8/2010 1.0 54 30 0.2 1.3 21 28 1st Qtr 2/1/2011 2nd Qtr 4/28/2011 3rd Qtr 7/29/2011 4th Qtr 10/20/2011 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/31/2012 4th Qtr 10/17/2012 1st Qtr 2013 2nd Qtr 2013 9.5 10.0 11.0 10.9 12.2 10.6 12.3 12.5 217 192 208 134 202 209 215 194 1st Qtr 1/26/2011 0.3 2nd Qtr 4/21/2011 1.2 40 28 3rd Qtr 7/27/2011 4th Qtr 10/18/2011 0.1. 0.2 28 33 1st Qtr 1/10/2012 2nd Qtr 4/19/2012 0.8 0.9 3rd Qtr 7/25/2012 0.6 4th Qtr 7/16/2012 0.12 44 28 ....33 30.8 NA NA 1st Qtr 2013 2nd Qtr 2013 NA NA TWN-9 abandoned on July 31, 2013 TWN-10 abandoned on July 31, 2013 Monitoring Event TWN-11 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-12 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/17/2010 2nd Qtr 6/1/2010 3rd Qtr 9/27/2010 1.4 1.3 73 72 1st Qtr 3/17/2010 2nd Qtr 5/26/2010 0.7 0.8 113 106 1.4 4th Qtr 12/8/2010 1.4 76 72 3rd Qtr 7/12/2010 0.7 4th Qtr12/7/2010 0.7 1st Qtr 1/27/2011 2nd Qtr 4/26/2011 3rd Qtr 7/27/2011 4th Qtr 10/17/2011 1.4 1.4 0.1 84 76 1st Qtr 1/26/2011 2nd Qtr 4/26/2011 4.2 1.0 1.6 76 76 3rd Qtr 7/26/2011 0.6 4th Qtr 10/17/2011 1.2 1st Qtr 1/10/2011 2nd Qtr 4/19/2012 3rd Qtr 7/25/2012 4th Qtr 10/16/2012 1.6 1.6 69 71 1st Qtr 1/10/2012 2nd Qtr 4/18/2012 0.9 1.2 1.8 1.84 77 76.4 3rd Qtr 7/25/2012 4th Qtr 7/16/2012 1.4 1.41 112 103 ...87 109 102 87 104 106 102 101 1st Qtr 2013 2nd Qtr 2013 NA NA 1st Qtr 2013 2nd Qtr 2013 NA NA TWN-11 abandoned on July 31, 2013 TWN-12 abandoned on July 31, 2013 Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I NA = Per the CAP and SCO, these wells not sampled 2013 Table 1 of 4 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-13 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-14 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/17/2010 2nd Qtr 5/26/2010 3rd Qtr 9/27/2010 <0.1 47 1st Qtr 3/24/2010 2.9 2.9 24 300.1 4th Qtr12/7/2010 0.2 0.4 49 53 57 2nd Qtr 6/2/2010 3rd Qtr 7/15/2010 4th Qtr12/10/2010 1st Qtr 1/25/2011 2nd Qtr 4/26/2011 3rd Qtr 7/26/2011 4th Qtr 10/17/2011 1.6 <0.1 103 49 0.1 <0.1 49 48 1st Qtr 1/28/2011 2nd Qtr 4/27/2011 3rd Qtr 7/29/2011 4th Qtr 10/19/2011 3.5 4.2 3.7 3.5 3.5 3.9 26 28 24 30 25 27 26 27 27 27.4 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 10/15/2012 <0.1 <0.1 <0.1 46 53 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 0.1 48 47.3 3rd Qtr 7/27/2012 4th Qtr 7/17/2012 1st Qtr 2013 3.5 3.4 3.7 4.03 1st Qtr 2013 2nd Qtr 2013 NA NA TWN-13 abandoned on July 31, 2013 2nd Qtr 2013 3rd Qtr 2013 NA NA NA 4th Qtr 2013 1st Qtr 2014 2nd Qtr 2014 NA NA 3 r d Qt r 2 014 4th Qtr 2014 NA NA NA 1st Qtr 2015 2nd Qtr 2015 3rd Qtr 2015 NA NA NA Monitoring Event TWN-15 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-16 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/18/2010 2nd Qtr 5/28/2010 3rd Qtr 7/13/2010 4th Qtr12/9/2010 0.7 1.0 1.0 1.2 43 39 36 38 1st Qtr 3/17/2010 2nd Qtr 5/27/2010 3rd Qtr 9/27/2010 4th Qtr 12/9/2010 1st Qtr 1/27/2011 2nd Qtr 4/27/2011 3rd Qtr 7/28/2011 4th Qtr 10/19/2011 1.4 1.6 1.6 1.3 43 49 47 38 1st Qtr 1/27/2011 2nd Qtr 4/27/2011 3rd Qtr 7/27/2011 4th Qtr 10/18/2011 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 3rd Qtr 7/26/2012 4th Qtr 10/17/2012 1.5 1.6 2.1 1.79 38 46 50 47 1st Qt r 1/10/2 012 2nd Qtr 4/19/2012 3rd Qtr 7/25/2012 4th Qtr 7/16/2012 1.2 1.3 2.6 2 4.6 1.6 2.4 2.6 2.8 2.0 2.4 2.50 35 35 35 30 34 39 31 34 33 50 33 32.1 1st Qtr 2013 2nd Qtr 2013 NA NA TWN-15 abandoned on July 31, 2013 1st Qtr 2013 2nd Qtr 2013 3rd Qtr 2013 4th Qtr 2013 NA NA NA NA 1st Qtr 2014 2 n d Qt r 2 014 3rd Qtr 2014 4th Qtr 2014 NA NA NA NA 1st Qtr 2015 2nd Qtr 2015 3rd Qtr 2015 NA NA NA Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I NA = Per the CAP and SCO, these wells not sampled 2013 Table 1 of 5 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-17 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TWN-18 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/24/2010 2nd Qtr 6/3/2010 3rd Qtr 7/15/2010 4th Qtr 12/10/2010 10.4 11 8.9 8 78 87 1st Qtr 2/1/2011 8.6 66 65 90 1st Qtr 3/17/2010 2nd Qtr 6/1/2010 3rd Qtr 9/27/2010 4th Qtr 12/9/2010 1st Qtr 1/27/2011 1.6 1.8 1.8 1.6 1.4 1.8 42 63 64 59 61 67 65 60 64 64 67 67.5 2nd Qtr 4/28/2011 3rd Qtr 7/29/2011 8.5 81 74 2nd Qtr 4/26/2011 3rd Qtr 7/28/2011 4th Qtr 10/20/2011 8.1 71 4th Qtr 10/18/2011 1.8 1.9 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 10/17/2012 8.7 9.1 9.5 9.65 79 80 1 85 84.8 1st Qtr 1/10/2012 2nd Qtr 4/19/2012 3rd Qtr 7/26/2012 4th Qtr 7/16/2012 Nitrate Pumping System Started in January 2013 1.9 2.1 2.3 1.95 1st Qtr 2013 2nd Qtr 2013 3rd Qtr 2013 NA NA NA TWN-17 abandoned on July 31, 2013 1st Qtr 2/18/2013 2nd Qtr 4/23/2013 3rd Qtr 8/27/2013 4th Qtr 10/16/2013 1st Qtr /14/2014 2nd Qtr 5/6/2014 3rd Qtr 8/5/2014 4th Qtr 10/8/2014 1st Qtr 2/18/2015 2nd Qtr 5/13/2015 TW4-6S dup of TW4-18 3rd Qtr 8/25/2015 <0.10 2.27 2.32 2.04 2.15 2.33 2.18 1.8 1.47 1 1.35 0.35 68.7 64.3 70.4 67.3 68.4 76.5 70 74'8 73.3 76.6 76.9 81.3 Monitoring Event TWN-19 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event Upper Wildlife Pond (UMLP) Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/23/2010 2nd Qtr 6/1/2010 3rd Qtr 9/27/2010 4th Qtr 12/9/2010 1st Qtr 2/1/2011 2nd Qtr 4/28/2011 3rd Qtr 7/28/2011 4th Qtr 10/18/2011 7.2 6.2 7.2 7.0 7.0 6.9 7.1 6.5 118 113 1st Qtr 3/18/2010 2nd Qtr 6/2/2010 113 107 114 120 113 3rd Qtr 7/19/2010 4th Qtr 12/10/2010 1st Qt r 1/31/2011 2nd Qtr 4/25/2011 3rd Qtr 7/25/2011 <0.1 <0.1 <0.1 <1.0 <1.0 <1.0 <0.1 0.1 <0.1 <0.1 <1.0 <1.0 108 114 117 117 118 4th Qtr 10/19/2011 <0.1 <1.0 1st Qtr 1/10/2012 2nd Qtr 4/19/2012 3rd Qtr 7/26/2012 4th Qtr 10/16/2012 1st Qtr 2013 2nd Qtr 2013 NA NA 3rd Qtr 2013 4th Qtr 2012 NA NA 1st Qtr 2014 2nd Qtr 2014 NA NA 3rd Qtr 2014 4th Qtr 2014 NA NA 1st Qtr 2015 2nd Qtr 2015 3rd Qtr 2015 NA NA NA 7.0 6.8 7.5 7.7 1st Qtr 1/31/2012 0.1 Pond no longer in service Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I NA = Per the CAP and SCO, these wells not sampled 2013 NS = Not sampled Table 1 of 6 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event Piezometer 1 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event Piezometer 2 Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 2010 2nd Qtr 6/2/2010 3rd Qtr 7/19/2010 4th Qtr 12/10/2010 NS NS 7.2 52 1s t Qt r 2 010 2nd Qtr 6/2/2010 NS NS 0.6 0.6 0.2 0.3 0.3 0.1 0.1 0.1 0.1 0.2 0.2 0.19 6.8 6.5 52 60 3rd Qtr 7/19/2010 4th Qtr12/10/10 1st Qtr 1/31/2011 2nd Qtr 4/25/2011 3rd Qtr 7/25/2011 4th Qtr 10/19/2011 1st Qtr 1/11/2012 1st Qtr 1/10/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 10/17/2012 6.8 60 58 1st Qtr 1/31/2011 2nd Qtr 4/25/2011 53 6.6 7.1 55 78 3rd Qtr 7/25/2011 4th Qtr 10/19/2011 1st Qtr 1/11/2012 9 8 ....9 8 9 1 8 ’ ’ 9 9.5 7.0 6.6 114 58 7.2 56 1st Qtr 1/31/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 7.66 55 4th Qtr 7/17/2012 Nitrate Pumping System Started in January 2013 1st Qtr 2/19/2013 2nd Qtr 4/24/2013 3rd Qtr 8/28/2013 ,4th Qtr 10/16/2013 1st Qtr 1/13/2014 2nd Qtr 5/7/2014 8.11 8.88 7.83 6.68 6.79 7.57 5.1 56.7 53.3 55.1 54.1 56.2 52.1 55 1st Qtr 2/19/2013 2nd Qtr 4/24/2013 3rd Qtr 8/28/2013 4th Qtr 10/16/2013 0.22 0.172 0.198 0.36 0.169 0.736 0.8 0.755 9.67 10.3 9.66 9.22 11.4 H.4 123rd Qtr 8/6/2014 4th Qtr 10/8/2014 1st Qtr 2/18/2015 2nd Qtr 5/12/2015 3rd Qtr 8/26/2015 5.75 6.41 5.95 4.96 57.6 55.9 57.5 64.2 1st Qtr 1/13/2014 2nd Qtr 5/7/2014 3rd Qtr 8/6/2014 4th Qtr10/8/2014 1st Qtr 2/18/2015 2nd Qtr 5/12/2015 3rd Qtr 8/6/2014 0.749 0.646 0.7 12.2 12.5 13.1 15.5 Piezometer 3 Monitoring Event Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event Pond D Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 3/24/2010 2nd Qtr 6/2/2010 3rd Qtr 7/19/2010 4th Qtr 12/9/2010 1.7 1.6 1.8 1.8 116 36 35 25 1st Qtr 2010 2nd Qtr 2010 3rd Qtr 2010 4th Qtr 2010 NS NS NS NS NS NS NS NS 1st Qtr 1/31/2011 2nd Qtr 4/25/2011 3rd Qtr 7/25/2011 4th Qtr 10/19/2011 1.8 40 1st Qtr 1/31/2011 1.7 1.8 1.7 35 61 2nd Qtr 2011 12 3rd Qtr 2011 4th Qtr 2011 NS NS NS 0.1 NS NS NS NS NS NS NS 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 10/17/2012 1.8 1.7 20 53 1st Qtr 2012 NS 2nd Qtr 2012 NS 1.8 2.75 21 20.1 3rd Qtr 2012 4th Qtr 2012 NS NS Nitrate Pumping System Started in January 2013 1st Qtr 2/24/2013 2nd Qtr 4/24/2013 3rd Qtr 8/28/2013 4th Qtr 10/16/2013 1st Qtr 1/13/2014 2nd Qtr 5/7/2014 3rd Qtr 8/6/2014 4th Qtr 10/8/2014 1.85 1.83 1.81 1.8 1.7 1.79 1.7 1.74 21 21.2 22.4 23.5 26 23.9 26 28.3 1st Qtr 2013 2nd Qtr 2013 3rd Qtr 2013 4th Qtr 2013 1st Qtr 2014 2nd Qtr 2014 3rd Qtr 2014 4th Qtr 2014 NA NA NA NA NA NA NA NA 1st Qtr 2/18/2015 2nd Qtr 5/12/2015 3rd Qtr 8/26/2015 1.82 1.75 1.87 27.3 30.2 54.8 1st Qtr 2015 2nd Qtr 2015 3rd Qtr 2015 NA NA NA NS = Not sampled NA = Per the CAP and SCO, these wells not sampled 2013 Table 1 of 7 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. TW4*22( Pumping well starting in January 2013) Monitoring Event Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I)Monitoring Event TW4-24 (Pumping well stating in January 2013) Nitrate, Nitrate + Nitrite (mg/I) Chloride (mg/I) 1st Qtr 2/11/2013 2nd Qtr 6/5/2013 3rd Qtr 9/3/2013 4th Qtr 10/29/2013 58 50.2 29.7 45.2 635 586 487 501 1st Qtr 2/11/2013 2nd Qtr 6/5/2013 3rd Qtr 9/3/2013 4th Qtr 10/3/2013 1st Qtr 1/27/2014 2nd Qtr 5/19/2014 3rd Qtr 8/11/2014 4th Qtr 10/21/2014 54.6 47.2 41.5 54.9 598 614 540 596 1st Qtr 1/27/2014 2nd Qtr 5/19/2014 3rd Qtr 8/11/2014 4th Qtr 10/21/2014 1st Qtr 3/9/2015 2nd Qtr 6/8/2015 3rd Qtr 8/31/2015 69.2 47.1 64.7 675 390 557 1st Qtr 3/9/2015 2nd Qtr 6/8/2015 3rd Qtr 8/11/2014 35.9 23.7 32.6 34.6 31.6 35 31.5 35.7 34.6 31.8 25.3 596 916 998 1,030 809 1,020 1,150 1,050 944 1290 788 TW4-25 (Pumping well starting in January 2013) Monitoring Event Nitrate, Nitrate + Nitrite (mg/I) 1st Qtr 2/11/2013 2nd Qtr 6/5/2013 3rd Qtr 9/3/2013 4th Qtr 10/29/2013 1st Qtr 1/27/2014 2nd Qtr 5/19/2014 3rd Qtr 8/11/2014 4th Qtr10/21/2014 9 5.24 5.69 6.1 2.16 1.21 1.6 1.03 1st Qtr 3/9/2015 2nd Qtr 6/8/2015 3rd Qtr 8/31/2015 14.4 1.14 1.63 Chloride (mg/I) 190 136 119 88.6 85.7 51.1 67 58.1 310 58.3 69.2 Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I Table 2 Summary of QA/QC Duplicate Sample 3rd Quarter 2015 Parameter GWQS Duplicate of TWN-4 TWN-4 TWN-65 RPD Nitrate + Nitrite (as N)10 mg/L 0.974 1.16 -17.4 Chloride none 35.2 35.2 0.0 Tabel 3 DRC Nitrate Mass Removal Calculations Energy Fuels Resorses Inc. White Mesa Mill, Bland, Utah 3rd Quarter 2015 Data Discriptions MW4 MW-26 Chloroform Pumping Wells TW4-1 TW4-2 TW4-4 TW4-11 TW4-19 TW4-20 TW4-21 Nitrate Pumping Wells TW4-37 TWN-2 TW4-22 TW4-24 TW4-25 Nitrate (mg/L) Nitrate (g/L) Nitrate (Ibs/L) Nitrate (Ibs/gal) Total gallons pumped lbs of nitrate removed Gallons of nitrate removed 48 4 79E-03 1 06E-05 4 01E-05 89,521 3 59 0 29 07 6 84E-04 1 51E-06 5 72E-06 21,042 0 12 0 01 63 6 28E-03 1 39E-05 5 25E-05 23,652 1 24 0 10 38 3 76E-03 8 31E-06 3 14E-05 21,587 0 68 0 06 65 6 45E-03 1 43E-05 5 39E-05 64,333 3 47 0 28 96 9 61E-03 2 12E-05 8 04E-05 3,584 0 29 0 02 11 6 1 16E-02 2 56E-05 9 70E-05 116,504 11 30 0 92 93 9 27E-03 2 05E-05 7 75E-05 17,657 1 37 0 11 14 7 1 47E-02 3 25E-05 1 23E-04 125,285 15 40 1 25 32 4 3 24E-02 7 16E-05 2 71E-04 118,064 31 99 2 60 49 7 4 97E-02 1 10E-04 4 16E-04 48,617 20 21 1 64 64 7 6 47E-02 1 43E-04 5 41E-04 24,620 13 32 1 08 25 3 2 53E-02 5 59E-05 2 12E-04 66,313 14 03 1 14 1 6 1 63E-03 3 60E-06 1 36E-05 124,137 1 69 0 14 Total lbs of nitrate removed from pumping wells inside nitrate plume Total gallons of nitrate removed from pumping wells inside nitrate plume 107.62 8.76 Total lbs of nitrate removed from pumping wells outside nitrate plume Total gallons of nitrate removed from pumping wells outside nitrate plume Total lbs nitrate removed from all pumping wells Total gallons of nitrate removed from all pumping wells % lbs of nitrate removed by pumping wells inside nitrate plume 10.79 0.88 118.41 9 63 90 89