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HomeMy WebLinkAboutDRC-2015-001369 - 0901a068804f35c0¥.\¥R( A SOLUTIONS February 5, 2015 CD 15-0029 Mr. Rusty Lundberg DRC-2015-001369 Director Utah Division of Radiation Control 195 North 1950 West P.O.Box 144850 Salt Lake City, UT 84114-4850 Dear Mr. Lundberg: In accordance with License Condition 16.F.i, EnergySolutions hereby requests Director approval to receive non-aqueous liquids within waste stream 9105-05. The waste stream is primarily debris for macroencapsulation treatment at the Mixed Waste Facility that may contain small amounts of non-aqueous liquids. Non-aqueous liquids present are solvents, particularly trichloroethylene. Upon receipt, EnergySolutions will examine the waste and segregate out liquids from the debris. The liquids will be treated by thermal desorption. Many hazardous waste codes area associated with this waste; post-treatment analyses will confirm the waste is treated to Land Disposal Restriction requirements prior to disposal. Liquid condensate generated through this treatment will be shipped off-site to a permitted facility for further treatment and subsequent disposal. The solid fractions from this treatment will be disposed in the Mixed Waste Landfill Cell. The profile for waste stream 9105-05 is attached. Note that a conservative approach of examining the upper bound of all nuclides in a single shipment will exceed Class A limits; however, as stated in the Attachment B.5., Physical Properties, section of the profile, the generator will review all shipments against Class A parameters and will not ship wastes that are above Class a limits. This calculation is further checked by Clive personnel prior to the shipment arriving at Clive. In addition to the profile, an evaluation of potentially harmful gases vapors or fumes associated with the waste is included. Should there by any questions please contact me at (801) 649-2144. Timothy L. Orton, P.E. Environmental Engineer and Manager Enclosures cc: Phil Goble, DRC (w/encl.) Otis Willoughby, DSHW (w/encl.) Subject: Radioactive Material License No. UT 2300249, Condition 16.F.i. Non-aqueous Liquid Waste Stream 9105-05 Sincerely, 423 West 300 South, Suite 200 • Salt Lake City, UT 84101 www.energysolutions.com Attachment 1 Waste Profile ENERG\SOLVTIOyS EC-0230 Revision 6 RADIOACTIVE WASTE PROFILE RECORD A. GENERATOR AND WASTE STREAM INFORMATION GENERAL: Complete this form for one waste stream Contact EnergySolutions at (801) 532-1330 if you have any questions while completing this form Please indicate "N/A" if a category docs not apply 1. GENERATOR INFORMATION Generator Name Idaho National laboratory. DOR L:PA ID tt ID4890008952 Generator Contact Bruno Zovi Title MLLW Program Manager Mailmc Address 850 Energy Dr. Idaho Falls. ID 83401 Utah Site Access Permit ft 1110007102 Phone (208)557-0984 Faxi208)5S7-7803 Email James.ZovKSamwtp inl.com Contractor Name Idaho Treatment Group Location of Waste (Citv. State) INI-ZScnville ID Name & Title of Person Completing Form Kris Smith Phone (208)557-6585 Email Kris Smilh(S)amwlp inl.gov 2. WASTE STREAM INFORMATION Waste Stream ID 9105-05 Waste Stream Name VTD Liquids / Mixed Wasle Debris with > 1% Liquid Slate of Origin ID_ Revision ^ Date 01/19/2015 Volume (ft1) 25.000 Delivery Date 2/15/2015 CHECK APPROPRIATE BOXES BELOW. Please verify the required forms requested below are completed and submitted wilh Ihe Radioactive Waste Profile Record. HAZARDOUS WASTE: Is the waste classified as hazardous waste as defined by 40 CFR 26 19 N D If NO, complete and attach the "Low-Level Radioactive Waste Certification Attachment" Y Kl If YES, complete and attach the "Hazardous Wasle Certification Attachment" and check applicable box below Has the waste been treated to meet applicable treatment standards per 40 CFR 268? YD N E Is the waste to be treated by EnergySolutions9 Y H N • LOW-LEVEL RADIOACTIVE WASTE: Is the radioactive waste defined as Low-Level Radioactive Waste in accordance with the Low-Level Radioactive Waste Policy Amendments Act of 1985 or in DOE Order 435 19 Y El If YES, a current copy of a LLRW Compact Export letter authorizing export must be submitted if applicable This authorization is applicable for non-DOE LLRW (i e , Mixed Waste, NORM/NARM, I le (2) material, and waste from DOE do not require a Compact Export Letter) N • If NO, check appropriate box NORM/NARM • 1 le (2) Byproduct Material • Other SPECIAL NUCLEAR MATERIAL: Does the waste stream contain material with uranium enriched in U-235 or any of the following radionuclides U-233, Pu-236, Pu-238. Pu-239, Pu-240, Pu-241. Pu-242, Pu-243. or Pu-2449 Y0 N • If Yes, complete and attach the "SNM Exemption Certification" form (EC-0230-SNM) Supporting statements, analytical results, and documentation must be included with the submittal PCB WASTE: Does the waste contain Polychlorinated Biphenyls (PCB) that arc regulated for disposal per 40 CFR 7619 YD N Kl If Yes, complete and attach the "PCB Waste Certification" form (EC-98279) ASBESTOS: Does the waste contain Asbestos Containing Material9 Y El N D If Yes, Asbestos Containing Material must be managed in accordance with applicable federal regulations Provide a detailed description of the waste containing asbestos in Section B 5 ofthe waste profile. Page 1 of5 ENERGYSOLUTIONS RADIOACTIVE WASTE PROFILE RECORD EC-0230 Revision 6 B. WASTE PHYSICAL PROPERTIES & PACKAGE INFORMATION 1. GENERAL CHARACTERISTICS Docs the waste contain free liquids? Y 13 ND If Yes. whal is the percent of free liquid by waste volume9 >1% If Yes, is the liquid aqueous (water-based)'' Y El N El Does the waste contain absorbent'' Y El ND Density range of the wasle 10 - 150 p/cc l~l lb/ft'El List percentage of waste type by volume Soil 5% Concrete & Metal 43_% DAW 5Q% Resins % Sludge % Other constituents and percentage by volume'' >l% liquid, both aqueous and non-aqueous (VTD) solvents such as TCP. 2. MATERIAL SIZE Gradation of Material Indicate the percentage of waste material that would nass through the following grid sizes For example, 95% of the material would pass through a 12" square. 90% passes through a 4" square, 80% passes through a 1" square, etc 12" 25.% 4" 25% l"20% 1/4" 12% 1/40" 5% 1/200" 5% Does the waste stream contain oversize debris (l c , no dimension < 10 inches and any dimension > 12 fect)'' YD N El If Yes, include a detailed description (i c . weight, size, drawings, etc ) ofthe oversize debris in the narrative of Section B 5 3. MOISTURE CONTENT For soil or soil-like matenals. please use Std. Proctor Method ASTM D-698 lo determine the optimum moisture content The wasle material must not exceed 3 percentage points above optimum moisture upon arrival at EnergySolutions' disposal facility unless approved by EnergySolutions Optimum Moisture Content NA % al Maximum Dry Density (lb/ft1) NA Average Moisture Content NA % Moisture Content Range NA% - NA% 4. WASTE SHIPPING & PACKAGING Transportation Mode El Highway D Rail Shipping & Container Packages El Drums* (S 85 gallons) El Boxes (S 100 ft') El Soft-Sided Bags (S 10 yd') (Check all that apply) D Intermodal El Scaland D Gondola" D Box Car Other 'Palletized drums are preferred by the disposal site Please specify in the "Other" field if drums will not be palletized "Dimensions of gondola railcars must be between 48 to 65 feet in length and 8 5 lo 12 5 fect in height as measured from the top ofthe rail to the top ofthe railcar unless approved by EnergySolutions 5. NARRATIVE DESCRIPTION AND HISTORY OK WASTE Please submit a narrative description and history ofthe waste as an attachment to the Radioactive Waste Profile Record. This attachment should include the following' • Process that generated the waste • Waste material physical composition and characteristics • Radiological and chemical characterization method • Basis for determining manifested radionuclide concentrations • Description and amounts of absorbents, if applicable • Basis of non-hazardous or hazardous waste determinations • Treatment processes, if applicable • Product information or Material Safety Data Sheets associated with the waste as applicable • Information requested in other sections of this form 9105-05 RevO Page 2 of5 ENERGYSOII™VS RADIOACTIVE WASTE PROFILE RECORD EC-0230 Revision 6 Wasle Stream ID: 9105-05 Revision: 0 C RADIOLOGICAL INFORMATION Date of Revision: 01/OS/201S Obtain sufficient samples to adequately determine a range and weighted average of activity in the waste. Attach the gamma spectroscopy or radiochemistry data supporting the radionuclide information listed below. 1. Docs the waste material contain accessible surfaces with contact dose rates greater than 500 mR/hr? YQ 1. Does the waste material contain any ofthe following isotopes: Aluminum-26, Berkelium-247, Calcium-41. Califomium-250. Chlorine-36, Rhenium-187, Terbium-157, or Terbium-158? Y • NS 3. Please list the following information for each isotope associated with the waste. Provide an explanation in the narrative description of Section B.5 if the waste contains localized "hot spots" or elevated concentrations that significantly exceed the upper concentration range. If additional space is needed, provide an Attachment C 3 to this profile record formatted as below. Isotope Ac-227 Am-241 Manifested Upper Concentration (pCi/g) 1.79E+02 7.00E+03 Weighted Avg per Container (pCi/g) 4.001--01 1.60E+03 Isotope Manifested Upper Concentration (pCi/g) Weighted Avg. per Container (pCi/g) Am-243 Co-60 1.53E+00 1.00E+03 1.50E-01 1.68E-02 Cs-137 Eu-152 2.87 E+04 2.81 E+00 6.00E-02 1.4IE-0I K-40 Np-237 4.97E+00 2.69E-01 2.90E+00 I.30E-01 Pu-238 Pu-239 Pu-240 Pu-241 Pu-242 7.95E+03 1.00E+04 1.54E+03 2.03E+04 2.00E-0I 7.00E+03 1.40E+03 I.30E+04 1.50E-0I Ra-226 Sr-90 5.00E+02 3.16 E+03 1.60E-0I 7.00E-02 Th-232 U-232 U-233 U-234 U-235 U-238 I.00E+02 7.49E+00 I.62E+03 1.00E+04 6.75 E+02 1.50E+04 4.32E-0I 7.50E-0I 1.00E-01 2.30E-01 2.30E-01 5.00E+02 9105-05 RevO Page 3 of5 ENERGYSOLUTKXVS RADIOACTIVE WASTE PROFILE RECORD EC-0230 Revision 6 HAZARDOUS WASTE CERTIFICATION ATTACHMENT This form is required only if the checkbox for Hazardous Waste on page one has been checked YES. Otherwise, complete the Low-Level Radioactive Waste Certification Attachment instead of this attachment. EnergySolutions may waive the chemical laboratory analyses if the material is not amenable to chemical sampling and analysis (e.g., debris items including metal pieces, concrete, plastic, etc.). Justification for waiving the chemical analyses must be provided in Section B.S. D. MINIMUM REQUIRED CHEMICAL ANALYSIS The following parameters must be analyzed by a Utah or NELAC certified laboratory. Typical SW-846 analytical methods have been listed. Other approved methods are acceptable. Attach the most recent or applicable chemical analytical results representing the waste. 1. GENERAL CHEMICAL PARAMETERS SW-846 Analytical Methods pH (Liquid only) NA Method 9045 Please provide the range ofthe pH analyses performed PFLT NA Pass / Fail Method 9095 Nol applicable for liquid radioactive waste streams Analyze the waste for volatile or semi-volatile constituents (Methods 8260 & 8270), and attach the data. Any distinguishing color or odor9 Y • N Kl If Yes, color odor HAZARDOUS WASTE CODES AND TREATMENT STANDARDS (40 CFR 268) List all hazardous waste codes and treatment standards. Include hazardous waste codes that have been removed through treatment and indicate "Former" in the second column. Worst-case concentrations only need to be provided for concentration based treatment standards. If additional space is needed, provide an Attachment D.2 to this profile record formatted as below. Include a description of hazardous waste determinations and any variances, exclusions, etc. in the narrative requested in Section B.S. EPA HW Codes Description, Constituent of Concern, or Subcategory Treatment Standard (mg/kg unless noted as mg/L TCLP or Technology Code) Worst-Case Concentration (mg/kg unless noted as mg/L TCLP) See D 2 Attachment 9105-05 RevO Hazardous Waste Certification Attachment Page 4 of 5 ENERGYSOLUTIONS EC-0230 Revision 6 3. UNDERYLYING HAZARDOUS CONSTITUENTS (40 CFR 268.48) List all underlying hazardous constituents (UHCs) and treatment standards. Include UHCs that have been removed through treatment. Worst-case concentrations only need to be provided for concentration based treatment standards. If additional space is needed, provide an Attachment D.3 to this profile record formatted as below Underlying Hazardous Treatment Standard (mg/kg unless noted as Worst-Case Concentration Constituents mg/L TCLP or Technology Code) (mg/kg unless noted as mg/L TCLP) None D. 4. OTHER CHEMICAL CONSTITUENTS List any other chemical constituents of concern (e.g., PCBs, chelating agents, etc.) and worst-case concentrations. If additional space is needed, provide an Attachment D.4 to this profile record formatted as below. Worst Case Worst-Case Concentration Other Concentration (mg/kg unless noted Hazardous (mg/kg unless noted as ma/L TCLP) Constituents as mg/L TCLP) Other Chemical Constituents None LABORATORY CERTIFICATION INFORMATION • UTAH or NELAC CERTIFIED The Utah or NELAC certified laboratory holds a current certification for the applicable chemical test methods insofar as such official certifications are given. Please provide a copy ofthe laboratory's current certification letter for each parameter analyzed and each method used for chemical analyses required by this form. • OTHER LABORATORY CERTIFICATION (Describe below) NA CERTIFICATION I certify that sample results representative ofthe waste described in this profile were or shall be obtained using state- and EPA- approved analytical methods. I also certify that where necessary representative samples were or shall be provided to EnergySolutions and to qualified laboratories for the analytical results reported herein. I further certify that the waste described in this record is not prohibited from land disposal in 40 CFR 268 (unless prior arrangements are made for treatment at EnergySolutions) and that all applicable treatment standards arc clearly indicated on this form. I also certify that the information provided on this form is complete, true, and correct and is accurately supported and documented by any laboratory testing as required by EnergySolutions. I certify that the results of any said testing have been submitted lo EnergySolutions I certify that the waste does not contain any prohibited items listed in EnergySolutions' Radioactive Material License or RCRA Permit. Generator's Signature Title:Waste Specialist Date: 01/19/2015 9105-05 RevO Hazardous Waste Certification Attachment Page 5 of 5 ATTACHMENT B.5 PHYSICAL PROPERTIES Generator Name- INL for U.S. DOE Waste Stream ID: 9105-05 Revision #. 0 Revision Date: 01/19/2015 1. Process that generated the waste The VTD Liquid/Mixed Waste Debris with Greater than 1 % liquid profile establishes bounding parameters of waste generated as a result of activities at several facilities within the DOE Complex. The wastes were shipped to and stored at the Idaho National Laboratory (INL) formally known as the Idaho National Engineering and Environmental Laboratory (INEEL). The wastes were generated from Decommissioning and Decontamination (D&D), facility modification, facility closure, materials retrieval and equipment maintenance, and waste repackaging efforts. The waste associated with this profile was originally generated at DOE facilities including, but not limited to, Rocky Flats, Mound Facility, Bettis Laboratory, Battelle Columbus Lab and LNL. In July of 2010, AM WTP began accepting waste from other DOE facilities for processing including but not limited to Hanford and Las Alamos National Laboratory. Incoming waste is expected to be Transuranic Waste (TRU) and will be shipped to WIPP however newly generated waste will be generated while handling this waste. Hazardous waste codes have been updated to include any codes associated with incoming waste. The INL's, AMWTP has performed characterization of the waste as part of the TRU process for disposal at the Waste Isolation Pilot Project (WIPP). The wastes were originally believed to be classified as TRU Wastes, however as a result of classification activities at the LNL, some waste has been determined to be Low Level Mixed Waste (LLMW) meeting the definition of LLMW found in the Low Level Radioactive Waste Policy Act, Public law 96-573. The waste radionuclide concentrations have been reviewed against the requirements of the classification tables found in Utah Administrative Code (UAC) R313-15-1008 and meet the requirements as Class A Unstable waste for disposal at the EnergySolutions Bulk Waste Disposal Facility located in Clive, UT. The waste is packaged in metal, wood, and fiberglass containers. Containers are 55 gallon, 83 gallon, 85 gallon, and 100 gallon product drums. Box sizes include, but are not limited to BR-90's M-III/M- rv* Bins, and SWB and half SWBs. The boxes and drums may not have DOT pedigree. If DOT pedigree cannot be provided waste will be shipped in LP-l/IP-2 soft-sided bags or may also be placed in LP-1 or IP-2 sealand/cargos containers for shipping purposes and will be removed from the sealand/cargos for management at Clive. 2. Waste materials physical composition and characteristics Waste shipped under profile 9105-05 will primarily be comprised of debris including, but not limited to electrical components, lead shielding, concrete, laboratory debris, process piping and equipment, and DAW (plastic sheeting, PPE, wood, paper, etc.). Containerized liquids, both aqueous and non- aqueous, are expected to be present in volumes exceeding 1 % of the waste package disposal volume. Newly generated debris will be characterized based on Acceptable Knowledge of the codes and isotopes contaminating new gen waste, operational procedures, operational logs and visual examination of the waste. RTR may also be used in rare cases to assist in characterization of new gen waste. Primary waste will also be characterized utilizing visual examination. In addition to a EC-0230 Attachment B.5 thorough review of historical documentation, each primary waste container has undergone processing through a Real Time Radiography (RTR) system. RTR analyses with container specific content descriptions have been completed for each container and will be made available to Energy Solutions with the 5 day advanced notification. Every effort has been made to ensure waste characterization is accurate and will provide EnergySolutions with the information necessary to safely and compliantly manage this waste stream. An example of RTR container analysis that will be made available to EnergySolutions is provided below: Containers NW J. RTR Review Comments 10000872 Overpacked FRP. electrical cable, rubber hose, scrap metal, glove boxes, metal tubing, sheet metal of lead in glove box (~3"x 14"), electric motor. 3 lead bncks. pliers, metal trays, glass lab wear Cannot penetrate, ~ 2 gallons of liquid in the bagging within the waste , 1/4 cup liquid in plastic bottle, several areas of containerized liquid (total 1 pint) Could not identify the aerosol can the operator called out Greg believes it is actually a connection on the glove box 10001042 Cardboard Liner, plastic liner, scrap inetal tubing with littings, electrical boxes, drum rings, cloth, structural steel. wood, electric motor Large steel object (electric motor00! in bottom comer could not be penetrated 20 ml residual liquid in metal pipe 1 0001048 Cardboard, plastic sheeting, PPE, scrap metal, poly bottles, electrical cord, scissors, metal wire, metal pipes, respirator cartridges. Large dense metal sealed container with ~ I gallon of liquid The impenetrable area appears to be multiple layers of metal pipes, tins area encompasses the lower quarter of the box 2 cups liquid in poly bottles and 2 tablespoons liquid in poly bottle. I cup liquid in bag pocket. 1/2 cup liquid in bag pocket behind edge of dense piping. Waste Management The AM WTP has completed due diligence efforts to ensure identification and exclusion of waste items that are not in compliance with EnergySolutions Waste Acceptance Criteria and applicable licenses and permits. There remains, however, some small probability that non-conforming items will be identified during sort and segregation operations. Should non-conforming items be identified, AMWTP will be notified immediately and an alternate disposition path forward will be implemented. Prior to waste processing, the RTR summary will be reviewed by EnergySolutions site personnel for each container as necessary. The focus of the review will be to pre-identify items that may require treatment other than macroencapsulation. These items may include: Liquids: Most liquids are believed to be contained. Liquids, both aqueous and non-aqueous, will be segregated for processing through the vacuum-assisted thermal desorption unit (VTD). VTD condensate will be shipped off-site for incineration. VTD residues will be sampled and stabilized (if necessary) prior to disposal. Aerosol Cans: AK documentation indicates the potential presence of aerosol cans in this waste stream. RTR provides an indication of whether or not the cans have been depressunzed. All aerosol cans will be segregated and inspected for depressurization. Depressurized aerosol cans will be managed as debris and macroencapsulated. Aerosol cans believed to be pressurized will be returned to the LNL AMWTP, or be managed by Energy Solutions as appropriate. Sealed Sources: AMWTP recognizes that EnergySolutions is prohibited from the receipt of sealed sources. Every effort has been made to ensure sources are not present in this waste stream. However, as a legacy waste there exists a very small potential that physical segregation activities reveals the EC-0230 Attachment B.5 presence of a source. Should a source be identified, AMWTP is to be immediately contacted and arrangements will be made for return shipment to the INL. Incidental Soils/Sludges: Incidental (<5% by volume) soils or sludges will not be segregated from the debris waste stream. Soils or sludges present in appreciable volumes (>50% per waste container) will be segregated, sampled, and stabilized (if required). PCB Items: PCB items will not be shipped in the 9105-05 profile but rather another EnergySolutions profile specifically established for the management of PCBs. Lead Acid Batteries: Lead acid batteries may be found within debris boxes and will need to be removed and drained by Energy Solutions. The following may be present in the waste and requires special labeling and handling. Asbestos: Debris waste may contain small volumes of friable asbestos in the form of D&D waste. Suspected asbestos waste will be properly packaged and containers will be properly marked and labeled. Beryllium: A percentage of containers will be labeled with Beryllium stickers. The concentration of Beryllium in the containers is known to be less than 2 ug/g, as was measured at AMWTP. AMWTP monitors for Beryllium due to the acceptable knowledge documentation but has never had to control worker environments from an IH perspective due to Beryllium measurements in the waste. AK Debris Constituents: Most of the low-density debris material is organic in that it is a chemical compound that contains carbon (blotter paper, plastics, cotton cloth). Low-density hazardous debris is comprised of the following: • Plastic materials (polyethylene, polyurethane, and PVC) primarily used for radioactive contamination control purposes (bags, sheets, tubing, HEPA ventilation duct), and personnel protective equipment (PPE-bubble hoods, booties, shoe covers) • PPE - Tyvek, cloth anti-contamination clothing, rubber, latex and neoprene gloves, leather gloves, respirator cartridges, rubber boots • Miscellaneous - Masslin wipes, terry towels, blotter paper, duct tape, filters, cotton, tools and equipment, scrap metal • Graphite molds and cores • Plexiglas and Benelex materials • Blacktop (asphalt, concrete, dirt and sand) • Fire brick and insulation materials • Filter media and CWS Filters • Leaded rubber gloves and aprons, bricks, sheets, etc. • Wood - pieces of dimensional lumber, plywood, used pallets. Organic constituents are typically associated with various EPA listed waste numbers applied to the debris. The listed waste codes are applicable to the debris enveloped by this waste stream because it has come in contact with listed organic waste contaminants. See Attachment D.2. for a list of the applicable EPA hazardous waste numbers. EC-0230 Attachment B.5 Inorganic Constituents: Lead is suspected to be present in the form of standard 2"x 4"x 8" brick or pieces of brick, lead blankets enclosed in plastic, lead wool, lead plates and sheets, lead shot, and various molded lead configurations to conform to the shape of pipes, valves, and other components for the purpose of radiological shielding. Metal debris items consist of generic stainless and carbon steel shapes and sizes, pieces of chain, nuts and bolts, brass, bronze, cadmium plates and sheet, copper, leaded cable, fuel racks with cadmium sheeting or filters with cadmium plated metal housings. 5. Radiological and chemical characterization methods The waste containers have been characterized for radionuclide content by direct method measurement utilizing WIPP certified spectral gamma measurement techniques. The spectral gamma measurements for all containers in this waste stream have identified nuclides below the lower limit of detectibility for the instrumentation and geometry utilized. While it is not possible to define an accurate radiological source term for individual drums that fall below the LLD of the NDA instrumentation, it is possible to define an aggregate radiological source term for a defined waste stream. The method used to define such a source term is based on the simple summation of the gamma ray spectra associated with the NDA measurements of the individual drums in the waste stream. This composite spectrum is then analyzed using the same algorithms that are applied to the individual measurements. This method provides a means to determine the radiological content of the entire waste stream; the radiological content of the individual containers may then be estimated based on the assumption that the radiological source term is evenly distributed throughout the waste stream. The advantage of this approach is that the composite spectrum represents a significantly longer data acquisition time than is practical on an individual container basis. This increase in the effective data acquisition time results in significantly improved counting statistics. This allows for a determinate measurement of the radiological source term for the waste stream. A description of the spectral summation methodology is provided as an attachment to this profile. The LLD for an NDA measurement is defined as; The LLD is that level of radioactivity, which, if present, yields a measured value greater than the critical level with a 95% probability, where the critical level is defined as that value which measurements of the background will exceed with 5% probability.1 It turns out that the LLD is entirely due to the quality of the counting statistics, and, as a rule of thumb the LLD corresponds to a measurement for which the uncertainty, due to counting statistics, is approximately 30%. The radionuclide distribution comes from two sources depending on the original generator of the waste. Waste covered by this profile was generated during the development of radioactive sources for the production of heat for conversion to electric power (Heat Source Plutonium - HSP) and waste generated for the production of nuclear weapons (Weapons Grade Materials - WGM). 1 Contact-Handled Transuranic Waste Acceptance Criteria for the Waste Isolation Pilot Plant, DOE/WIPP- 02-3122 Rev. 3.0 EC-0230 Attachment B.5 Nuclides that are not identifiable, by the use of gamma ray spectroscopy, were scaled using scaling factors developed from the expected nuclide distribution identified in the respective AK document. Any waste stream, per AK document, that identifies the presence of Cs-137 will also carry the appropriate Sr-90 contribution based on a one to one scaling. Chemical content determinations are made by review of available AK documentation. Each waste stream has been subject to an extensive document review and has been characterized as having a chemical constituent, if in the processes that generated the waste involved the use of an identified chemical constituent. In many cases, materials were identified during the inspection of the waste materials at the LNL AMWTP. If during the inspection processes a hazardous material identification was made, the appropriate hazardous waste code was applied to the container. An example of this is, a waste code applied to a waste container after head gas measurement confirmed the presence of a volatile organic. Basis for determining manifested radionuclide concentrations The methodology that will be used to develop radionuclide activities that are entered on the manifest will utilize a nuclide distribution for Weapons Grade Materials and/or Heat Source Plutonium Materials. The nuclide distribution is developed by utilizing the actual nuclide activity or LLD for the detection system and establishing an average nuclide concentration. This concentration is then multiplied by the net weight of the waste materials to establish the total manifested activity for the given waste volume. Nuclides that were identified in a small number of containers will be identified in those specific containers. An example of those nuclides are U-233, which was identified in approximately seven containers will be manifested in those containers. The concentration value of each container will be determined using the appropriate nuclide distribution model. This method should provide a conservative radionuclide concentration for a given container. In some cases, both nuclide distributions will be utilized for a single container. These containers will be those that contain "Super Compacted" drums from multiple generators and placed into the same large over pack container. In these cases, the individual compacted drum will be characterized and the total contents will be added together to obtain the final waste activities. The nuclide distribution for HSP generated waste is Pu-238 (80% to 83.5%), Pu-239 (13.8% to 16.5%), Pu-240 (2.0% to 3.05%), Pu-241 (0.39% to 0.8%) and Pu-242 (0.08% to 0.2%). The nuclide distribution for WGM is Pu-238 (.01 to .05%), Pu-239 (92.8% to 94.4%), Pu-240 (4.85% to 6.5%), Pu-241 (0.3% to 1%) and Pu-240 (0.005% to 0.06%). This source term may also contain a small amount of Enriched Uranium (enrU) contaminated waste. The distribution of nuclides associated with the enrU is Th-231 (<0.001%), Th-234 (< 0.001%) U-234 (~ 0.1%), U-235 (90% to 93%), U-236 (-0.4%) and U-238 (-5.3%) There could also be a small amount of Depleted Uranium (depU) contaminated waste identified in this waste stream. The nuclide distribution for depU is Th-231 (<.001%), Th-234 (< 0001%), U-234 (<.0001%), U-235 (~. 02%) and U-238 (99.8%). Other isotopes that have been identified in the WGM waste stream include small quantities of fission products that were added due to research and development activities at the initial generator sites. EC-0230 Attachment B.5 Natural occurring isotopes have also been identified in the waste materials during analysis. These isotopes include Th-232, Ra-226 and K.-40. New gen pallets were generated for shipment on New Gen 8 campaign. Pallets would not fit into the assay unit. Source term was determined by determining the surface activity and applying it across the surface area of the pallets and /or the average concentration distributed according to the waste mass, as appropriate. Basis of non-hazardous or hazardous waste determinations a. Listed Hazardous Waste: The EPA listed hazardous waste codes associated with this campaign are as follows: F001, F002, F003, F004, F005, F006, F007, F009, P030, P098, P099, P106, U003, U103, U108, U134 and U151. These codes originate from listed waste that has come in contact with the debris addressed in this waste stream. This determination is based upon knowledge of the parent waste streams and processes involved in the generation of the waste, and are documented by the applicable Acceptable Knowledge Documents identified in the reference section. The application of these listed hazardous waste codes is per the "Contained-In Rule" 261.3(f)(2). No appreciable concentrations of solvents or other listed hazardous wastes (per respective hazardous waste code) are expected. Containers that have containerized liquids and are subject to U134 EPA Hazardous Waste Code will not be shipped to Energy Solutions for treatment and/or disposal. Containers that do not have containerized liquids and have been assigned the U134 EPA Hazardous Waste Code because of possible contact with Hydrofluoric Acid could be shipped to Energy Solutions for treatment and/or disposal. Containers that have containerized powders and are subject to P098, P099 and PI06 EPA Hazardous Waste Codes will not be shipped to Energy Solutions for treatment and/or disposal. Containers that do not have containerized powders and have been assigned the P098, P099 and PI 06 EPA Hazardous Waste Code because of possible contact with potassium cyanide, potassium silver cyanide and sodium cyanide could be shipped to Energy Solutions for treatment and/or disposal. Attachment D.2. provides a list of the hazardous waste codes. b. Characteristic Hazardous Waste: The waste contains various metallic lead items, cadmium metal pieces, residues from various metal handling and chemical operations. The waste was also generated through the decontamination and decommissioning efforts of the various facilities. The EPA waste code numbers are: D001, D002, D004, D005, D006, D007, D008, D009, DO 10, DOI 1, DOI 8, DO 19, D021, D022, D026, D027, D028, D029, D030, D031, D032, D033, D034, D035, D036, D037, D038, D039, D040, and D043 and applied based upon knowledge of the material itself and/or historical handling and clean up from the handling of such materials as discussed herein. D001 is also applicable when a container is noted as having an aerosol can present. The aerosol can will be separated from the debris and treated appropriately. EC-0230 Attachment B.5 The low-density debris is declared to exhibit the toxicity characteristic for lead, cadmium, chromium, arsenic, barium, and mercury. The D006 and D008 EPA waste numbers are typically declared for the low density debris because it was used in or around processes where it was known to have come in contact with lead and cadmium metal, or was exposed to lead or cadmium in the form of small particles, oxides, or pigments. In addition, data (TCLP, EP Toxicity, and Total Metals) from historical sampling and analysis efforts and additional process knowledge information supports declaration of EPA waste numbers D002 (corrosive - batteries), D004 (arsenic), D005 (barium), D007 (chromium), D009 (mercury - low mercury subcategory), DO 10 (selenium) and DOI 1 (silver). When container contents warrant regulatory subcategories they will be applied appropriately (i.e. batteries will receive a "Radioactively contaminated cadmium / mercury battery category'' and elemental lead will receive the "'Radioactive Lead Solids Subcategory". Some of the debris in this campaign may have come in contact with waste carrying the following characteristic codes: DOI8 (Benzene), DOI9 (Carbon Tetrchlonde), D021 (Chlorobenzene), D022 (chloroform), D026 (Cresol Mixtures), D027 P-Dichlorobenzene, D028 (1,2-Dichloroethane), D029 (1,1-Dichloroethylene), D030 -2,4-Dinrtrotoluene, D031 (Heptachlor), D032 (Hexachlorobenzene), D033 (Hexachlorobutadiene ), D034 (Hexachlorobutadiene), D035 (Methyl ethyl ketone), D036 (Nitrobenzene), D037 (Pentachlorophenol) D038 (Pyridine ), D039 (Tetrachloroethylene), D040 (trichloroethylene) and D043 (Vinyl Chloride). This debris consists of gloves, bag cutters, parts of plastic liners and PPE. Codes are applied based on the potential of the debris to come in contact with waste. In summary, application of characteristic EPA waste numbers is based primarily upon process knowledge of the material itself (e.g. metallic lead, cadmium, silver or lead solder) as documented in Acceptable Knowledge documents identified in Section 10, References. Waste numbers applied to the low-density debris is also based upon process knowledge of the debris and are declared based upon that knowledge as described above. Historical data exists that supports declaration of the EPA waste numbers for these items but in some cases is specific processes (PPE generated while handling lead or cadmium, discarded leather gloves) and is used generically to support declaration of EPA waste numbers. 8. Treatment Processes, if applicable The debris waste stream has not been subject to treatment processes. Some items are identified for segregation prior to treatment to ensure proper treatment in compliance with the Land Disposal Restrictions. 9. Information requested in other sections of this form a. Special Nuclear Materials The waste contains Special Nuclear Materials (SNM) in solid physical form. The SNM are in the metal oxides with a very small fraction (<1%) as metal nitrate form. The wastes were generated as a result of nuclear weapons production or heat source production operations. The SNM isotopes are distributed through the waste essentially uniformly as contaminated debris materials. There are no discrete objects or point source materials within the waste matrix containing SNM. EC-0230 Attachment B.5 The document "Determination of Radioisotopic Content in TRU Waste Based on Acceptable Knowledge" AMWTP-RPT-TRUW-07 is the basis for determination ofthe SNM content ofthe wastes. Each container of waste has received nuclide identification by WLPP certified spectral gamma measurement techniques. Nuclides that are not identifiable by the use of gamma ray spectroscopy were scaled using scaling factors developed from the expected nuclide distribution defined in the respective AK documentation. The LLD for an NDA measurement is defined as; The LLD is that level of radioactivity, which, if present, yields a measured value greater than the critical level with a 95% probability, where the critical level is defined as that value which measurements of the background will exceed with 5% probability. It turns out that the LLD is entirely due to the quality of the counting statistics, and, as a rule of thumb the LLD corresponds to a measurement for which the uncertainty due to counting statistics is approximately 30%. Gram concentrations are developed by utilizing specific activity calculations for the identified nuclides applied to the waste mass. In many cases, gram quantities have been verified by neutron analysis of the containers. The debris waste stream containers are expected to contain less than 10 grams of fissionable materials. 10. REFERENCES: a. AMWTP-RPT-TRUW-05, Current Rev., Waste Matrix Code Reference Manual b. AWMTP-RPT-TRUW-07, Current Rev., Determination of Radioisotopic Content in TRU Waste Based on Acceptable Knowledge c. AMWTP-RPT-TRUW-12, Current Rev., AMWTP Waste Stream Designations d. AMWTP-RPT-TRUW-l 3, Current Rev., Acceptable Knowledge Document for LNL Stored Transuranic Waste - Mound Plant Waste e. AMWTP-RPT-TRUW-56, Current Rev., Acceptable Knowledge Document for LNL Stored Transuranic Waste - Rocky Flats Plant f. AMWTP - TRUW-30, Current Rev., Acceptable Knowledge Summary for Supercompacted Debris Waste (BN510) g. AMWTP-TRUW-04, Current Re., Acceptable Knowledge for Battelle Columbus Laboratories Building JN-4 Plutonium Laboratory h. AMWTP-RPT-TRUW-83, Current Rev. Acceptable Knowledge Summary for Supercompacted Debris (BN510.1) l. EDF-0775, Engineering Design File, Mixed Low Level Waste Debris Characterization , K.A. Smith j. AMWTP-RPT-TRUF-92, Acceptable Knowledge Document for Select Idaho National Laboratory (LNL) Facilities k. An NDA Technique for the disposition of Mixed Low Level Waste at the Advanced Mixed Waste treatment Project, M.J. Clapham, J.V. Seamans EC-0230 Attachment B.5 Attachment D.2 to Waste Profile 9105-05 Rev 0 This revision is submitted to include newly generated containers, characterization established based on a new revision of RPT-TRUW-12. New codes are a result of waste shipped to AMWTP for processing. As a result ofthe process activities new gen waste codes are assumed to be contaminated with all codes of associated primary waste. Hazardous Waste Codes and Treatment Standards (40 CFR 268) EPA Hazardous Waste Code Description, Constituent of Concern or Subcategory Treatment Standard D00I lgnitable RORGS:CMBST: or POLYM D002 Corrosives & (Batteries) MACRO D004 Arsenic MACRO D005 Barium MACRO D006 Cadmium MACRO D006 Radioactively Contaminated Cadmium Containing Batteries MACRO D007 Chromium (Total) MACRO D008 Radioactive Lead Solids MACRO D008 Lead MACRO D008 Lead Acid Battery RLEAD D009 Low Subcategory Mercury MACRO D009 High Subcategory Mercury MACRO D009 Radioactively Contaminated Mercury Containing Batteries MACRO D010 Selenium MACRO D011 Silver MACRO D018 Benzene MACRO D019 Carbon Tetrachloride MACRO D021 Chlorobenzene MACRO LX)22 Chloroform MACRO D026 Cresol Mixtures (o-, m-, p-) MACRO D027 P-Dichlorobenzene MACRO D028 1,2-Dichloroethane MACRO D029 1,1 -Dichloroethylene MACRO D030 2,4-Dinitrotoluene MACRO D031 Heptachlor MACRO D032 Hexachlorobenzene MACRO D033 Hexachlorobutadiene MACRO D034 Hexachloroethane MACRO D03S Methyl ethyl ketone MACRO D036 Nitrobenzene MACRO D037 Pentachlorophenol MACRO D038 Pyridine MACRO D039 Tetrachloroethylene MACRO D040 Trichloroethylene MACRO D043 Vinyl chloride MACRO F001 1,1,1 -Trichloroethane MACRO FOOT 1,1,2-Trichloro-1,2,2-tjjfluoroethanc MACRO F001 Carbon Tetrachloride MACRO F001 Methylene Chloride MACRO F001 Tetrachloroethylene MACRO F001 Trichloroethylene MACRO F001 Trichlorofluromethane MACRO 9105-05 Rev 0 EPA Hazardous Waste Code Description, Constituent of Concern or Subcategory Treatment Standard F002 1,2-dichlorobenzcne MACRO F002 1,1,1 -Trichloroethane MACRO F002 1,1,2-Trichloroethane MACRO F002 1,1,2-Trichloro-1,2,2-trifluoroethane MACRO F002 Carbon Tetrachloride MACRO F002 Methylene Chloride MACRO F002 Tetrachloroethylene MACRO F002 Chlorobenzene MACRO F002 Trichloroethylene MACRO F002 Trichlorofluromethane MACRO F003 Acetone MACRO F003 1-butanol MACRO F003 Cyclohcxanone MACRO F003 Ethyl Benzene MACRO F003 Ethyl Ether MACRO F003 Methanol MACRO F003 Methyl Isobutyl Ketone MACRO F003 Xylenes - mixed isomers MACRO F004 Cresols MACRO F004 Nitrobenzene MACRO F005 2-Ethoxyethanol MACRO FOOS 2-Nitropropane MACRO FOOS Benzene MACRO FOOS Carbon Disulfide MACRO F005 Isobutanol (Isobutyl Alcohol) MACRO F005 Methyl Ethyl Ketone MACRO F005 Pyridine MACRO F005 Toluene MACRO F006 Electroplating Sludges MACRO F007 Cyanides Plating Bath Solutions MACRO F009 Chromium (Total) MACRO F009 Cyanides Cleaning Bath Solutions MACRO P030 Cyanides (soluble salts and complexes) MACRO P098 Potassium Cyanide MACRO P099 Potassium Silver Cyanide MACRO P106 Sodium Cyanide MACRO U003 Acetonitrile MACRO UI03 Dimethyl sulfate MACRO U108 1,4-Dioxane MACRO U-134 Hydrogen Fluoride MACRO U151 Mercury MACRO The basis of characterization for this waste stream is founded on the definition of debris per 40 CFR §268.2 (g). In particular, "A mixture of debris that has not been treated to the standards provided by § 268.4S and other material is subject to the regulation as debris if the mixture is comprised primarily of debris, by volume based on visual inspection." These hazardous waste codes are applicable to waste forms that meet the definition of hazardous debris and may be treated in accordance with the alternative treatment standards for hazardous debris, 40 CFR 268.45. 9105-05 Rev 0 CL-WM-PR-001 F3 (EC-0230-SNM) Revision 4 SPECIAL NUCLEAR MATERIAL EXEMPTION CERTIFICATION The Special Nuclear Material Exemption Certification form must be completed and signed by each generator certifying to the following conditions. Please attach this form and all required information to the Radioactive Waste Profile Record (EC-0230). A completed and signed copy of this form must also accompany each waste manifest. Waste Stream ID: 9105-05 Manifest No. ENERGYSOLUTIONS 1. Check applicable category below for the waste stream: Uranium Enrichment Percent Weight Percent of Chemicals in Condition 2c Weight Percent of Materials in Condition 2d U-235 Concentration (pCi/g) Measurement Uncertainty* (pCi/g) • < 10% < 20 % < 1 % < 1,900 <285 • Unlimited < 20 % < 1 % < 1,190 < 179 Unlimited Sum of both < 45 % of waste by weight <680 < 102 • Unlimited Unlimited Unlimited <26 < 10 • Not Applicable - Enriched U-235 is not present in the waste. * A concentration value is used for the maximum measurement uncertainty limit rather than a percentage value to allow greater flexibility for generators with waste having very low SNM concentrations 2. Certify to the following requirements by checking applicable boxes, A-E for solid waste or A-F if waste includes liquid: ISI a. Concentrations of SNM in individual waste containers do not exceed the applicable values listed in the above table and SNM isotope concentrations listed in Table 1. El b. The SNM is homogeneously distributed throughout the waste or the SNM concentrations in any contiguous mass of 600 kilograms (1,323 lbs) do not exceed on average the specified limits. (Based on process knowledge or testing). c. Except as allowed by Condition 1, the waste does not contain "pure forms" of chemicals containing carbon, fluorine, magnesium, or bismuth in bulk quantities (e.g., a pallet of drums, a B-25 box). By "pure forms," it is meant that mixtures of the above elements such as magnesium oxide, magnesium carbonate, magnesium fluoride, bismuth oxide, etc. do not contain other elements. (Based on process knowledge or testing). £3 d. Except as allowed by Condition 1, the waste does not contain total quantities of beryllium, hydrogenous material enriched in deuterium, or graphite above one percent ofthe total weight ofthe waste. (Based on process knowledge, physical observations, or testing). ^ e. Waste packages do not contain highly soluble forms of uranium greater than 350 grams of uranium- 235 or 200 grams of uranium-233. If the waste contains mixtures of U-233 and U-235, the waste meets the sum of the fractions rule. Highly soluble forms of uranium include, but are not limited to: uranium sulfate, uranyl acetate, uranyl chloride, uranyl formate, uranyl fluoride, uranyl nitrate, uranyl potassium carbonate, and uranyl sulfate. (Based on process knowledge or testing). 153 f. For containers of liquid waste with more than 600 kilograms of waste, the total activity (pCi) of SNM in the manifested container does not exceed the SNM concentration in the above table or Table 1 times 600 kilograms of waste (based on process knowledge or testing). For example, the maximum activity of Pu-239 in any manifested container of liquid waste is 6.0 mCi (6.0E+09 pCi) as shown below: 10,000 f x 600,000g = 6.0X109 pCi = 6.0mCi Pu-239 Page I of2 ENERGYSOLUTIONS CL-WM-PR-001 F3 (EC-0230-SNM) Revision 4 SPECIAL NUCLEAR MATERIAL EXEMPTION CERTIFICATION Table 1. Maximum concentrations of SNM in individual waste containers (refer to above table for U-235 limits). Radionuclide Maximum Concentration (pCi/g) Measurement Uncertainty (pCi/g) Radionuclide Maximum Concentration (pCi/g) Measurement Uncertainty (pCi/g) U-233 75,000 11,250 Pu-241 350,000 50,000 Pu-236 500 75 Pu-242 10,000 1,500 Pu-238 10,000 1,500 Pu-243 500 75 Pu-239 10,000 1,500 Pu-244 500 75 Pu-240 10.000 1.500 3. Indicate that the following information is attached to the Radioactive Waste Profile Record by checking each box. (Note: Only the two-page Special Nuclear Material Exemption Certification form needs to be included with each manifest). a. Provide a description of how the waste was generated, list the physical forms in the waste, and identify the uranium chemical composition. b. Provide a general description of how the waste was characterized (including the volumetric extent of the waste, and the number, location, type, and results of any analytical testing), the range of SNM concentrations, and the analytical results with error values used to develop the concentration ranges. c. Describe the process by which the waste was generated showing that the spatial distribution of SNM must be uniform, or other information supporting spatial distribution. ^ d. Describe the methods to be used to determine the concentrations on the manifests. These methods could include direct measurement and the use of scaling factors. Describe the uncertainty associated | with sampling and testing used to obtain the manifest concentrations. 4. Generator's certification of compliance with the SNM exemption: 1 certify that the information provided on this form is complete, true, and correct and is based on process knowledge, physical observations, or approved laboratory testing. I also certify that sampling and radiological testing of waste containing SNM was performed in accordance with EnergySolutions' Radioactive Material License and that any supporting documentation and analytical results have been submitted to EnergySolutions. Kris A. Smith Waste Specialist 1/19/2015 Authorize d)S ignature Printed Name Title Date Page 2 of2 Attachment 2 Non Aqueous Liquid Assessment EN ERGYSOLUTIONS MEMORANDUM Date: To: From: Subject: February 5, 2015 Vern Rogers Tim Orton Non Aqueous Liquid Assessment Waste Stream 9105-05 The purpose of this memo is to evaluate Waste Stream 9105-05 for compliance with Radioactive Material License conditions 16.B and 16.C. EnergySolutions intends to treat the liquids associated with this waste stream by solidifying at the Mixed Waste Facility and disposing at LLRW. License conditions 16.B and 16.C address the waste's potential to be explosive under normal conditions, explosively reactive with water, or capable of generating toxic gases, vapors, or fumes during the waste management process. As transporting, handling and disposal of the waste does not occur under extreme conditions, the waste in question is analyzed assuming normal environmental conditions (International Union of Pure and Applied Chemistry [IUPAC] standard temperature and pressure) apply. Waste Stream 9105-05 is primarily debris for macroencapsulation treatment, but also contains non-aqueous liquids (solvents, primarily trichloroethylene) that need to be segregated from the debris and managed separately. The Clive Facility will remove non- aqueous liquids as they are found and manage them through the thermal desorption system. Condensate generated from this treatment will be sent off-site for incineration; solid material will be disposed in the Mixed Waste Landfill Cell. For this review, the MSDS for trichloroethylene was examined. A description of the hazards identified follow. Trichloroethylene Trichloroethylene is moderately stable under normal conditions, decomposing very slowly to phosgene, hydrochloric acid, and dichloroacetic acid. This decomposition is accelerated by direct sunlight, excessive heat, and moisture. As such, trichloroethylene should be transported apart from open flame sources and kept under standard environmental conditions, away from the heat of the sun. Other than the slight acceleration in decomposition, trichloroethylene does not 423 West 300 South, Suite 200 • Salt Lake City, Utah 84101 (801) 649-2000 • Fax (801) 321-0453 • www energysolutions com react with water. Trichloroethylene has no measurable flash point and is not flammable under most conditions - high temperature and a strong flame would be required to reach flammability limits. The autoignition temperature for trichloroethylene under normal situations is approximately 420 °C (-788 °F). All waste containers will remained closed during transport and storage and will only be opened for management within controlled environments where incompatible material will not be present. Based on the MSDS information described above, this waste stream is not capable of generating toxic gases, vapors or fumes in quantities that are harmful to persons participating in the transporting, handling, or disposing of this waste under standard temperatures and pressure. It is not considered water reactive, nor does it appear unstable or explosive under standard temperature and pressure. 423 West 300 South, Suite 200 • Salt Lake City, Utah 84101 (801) 649-2000 • Fax (801) 321-0453 • www energysolutions com