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HomeMy WebLinkAboutDRC-2014-003822 - 0901a068804467b8W ENERGYFUELS Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 www.energvt'uels.com June 5, 2014 DRC-2014-003822 Sent VIA OVERNIGHT DELIVERY Mr. Rusty Lundberg Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West P.O. Box 144850 Salt Lake City, UT 84114-4820 Re: Response to Utah Division of Radiation Control ("DRC") March 19, 2014 Request for Information ("RFI"), regarding the DRC review of the July 2012 Revised Renewal Application for the White Mesa Mill Groundwater Discharge Permit UGW370004 Dear Mr. Lundberg: This letter responds to DRC's above-named letter dated March 19, 2014, which Energy Fuels Resources (USA) Inc. ("EFRI") received on March 20, 2014, regarding the DRC review of the July 2012 Revised Renewal Application for the White Mesa Mill Groundwater Discharge Permit UGW370004. For ease of review, this letter provides each of DRC's comments verbatim, in italics, below, followed by EFRI's response. The redline text of the GWDP Renewal Application and a complete, revised, clean copy of the entire Application are both attached to this letter for your convenience. Request for Information DRC Comment SECTION: 1.1 and many subsequent sections INTERROGATORY STATEMENT(S): Page 5 of the Renewal Application (RA) refers to the mill operator as Denison Mines (USA) Corp. Because the owner and operator of the mill has changed, please use the new name here and throughout the RA. BASIS FOR INTERROGATORY: The names of the owner and operator of the mill need to be changed throughout the RA text to the new name of Energy Fuels Resources (USA) Inc. June 5, 2014 Sent VIA OVERNIGHT DELIVERY Mr. Rusty Lundberg Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West P.O. Box 144850 Salt Lake City, UT 84114-4820 Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 www.energyfuels.com Re: Response to Utah Division of Radiation Control ("DRC") March 19, 2014 Request for Information ("RFI"), regarding the DRC review of the July 2012 Revised Renewal Application for the White Mesa Mill Groundwater Discharge Permit UGW370004 Dear Mr. Lundberg: This letter responds to DRC's above-named letter dated March 19, 2014, which Energy Fuels Resources (USA) Inc. ("EFRI") received on March 20, 2014, regarding the DRC review of the July 2012 Revised Renewal Application for the White Mesa Mill Groundwater Discharge Permit UGW370004. For ease of review, this letter provides each of DRC's comments verbatim, m italics, below, followed by EFRI' s response. The redline text of the GWDP Renewal Application and a complete, revised, clean copy of the entire Application are both attached to this letter for your convenience. Request for Information DRCComment SECTION: 1.1 and many subsequent sections INTERROGATORY STATEMENT(S): Page 5 of the Renewal Application (RA) refers to the mill operator as Denison Mines (USA) Corp. Because the owner and operator of the mill has changed, please use the new name here and throughout the RA. BASIS FOR INTERROGATORY: The names of the owner and operator of the mill need to be changed throughout the RA text to the new name of Energy Fuels Resources (USA) Inc. Letter to Rusty Lundberg June 5, 2014 Page 2 of20 APPLICABLE RULE(S) OR REGULATION(S): UAC R317-6-6.3.A REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: The name of the owner/operator has been updated throughout the document, except when the organization name is part of the titles of previously submitted reports. The owner/operator names on documents provided as appendices which are still in effect (i.e. are the most recent DRC-approved versions) have also not been changed. DRCComment SECTION: 1.2 INTERROGATORY STATEMENT(S): Page 5 of the Renewal Application (RA) states that In accordance with discussions between Denison management and State of Utah Division of Radiation Control ("DRC") staff on March 12, 2009, this Application includes the information required under R313-6-6.3. Similarly, Page 6 refers to R313-6-6.4C. However, the Utah Code designations applied in these cases are not correct. Please correct them. BASIS FOR INTERROGATORY: The code that provides language identical or nearly identical to that quoted in the RA is found in UAC R317-6-6.4C. No rules labeled as R313-6-6.3 or R313-6-6.4C exist in the UAC. APPLICABLE RULE(S) OR REGULATION(S): UAC R317-6-6 REGULATORY GUIDANCE REFERENCE(S): NIA EFRI Response: The references have been corrected. DRCComment SECTION: 1.2 (cont'd) INTERROGATORY STATEMENT(S): On Page 6, the following wording from R317-6-6.4C is quoted (but misattributed): The Director may issue (or renew) a ground water discharge permit for an existing facility, such as the Mill, provided: 2 Letter to Rusty Lundberg June 5, 2014 Page 3 of20 a) The applicant demonstrates that the applicable class total dissolved solids ("TDS") limits, ground water quality standards and protection levels will be met; b) The monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; c) The applicant utilizes treatment and discharge minimization technology commensurate with plant process design capability and similar or equivalent to that utilized by facilities that produce similar products or services with similar production process technology; and d) There is no current or anticipated impairment of present and future beneficial uses of the ground water. Please demonstrate within the renewal application (and summarize here) that all four conditions listed above are being met as is required for the Director to renew a groundwater discharge permit. BASIS FOR INTERROGATORY: Currently, there are two groundwater plumes identified at the White Mesa Mill property. Please explain how these plumes are being addressed and justify why a groundwater discharge permit should be renewed for the facility in light of these conditions. APPLICABLE RULE(S) OR REGULATION(S): UAC R317-6-6 REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: Section 1.2 has been revised to address the conditions in R317 -6-6.4C. DRCComment SECTION: 2.1 INTERROGATORY STATEMENT(S): Please update the Applicant and Owner name and address. BASIS FOR INTERROGATORY: Since the company has recently changed ownership, please provide the following information required by UAC R317-6-6.3.A: The name and address of the applicant and the name and address of the owner of the facility if different than the applicant. A corporate application must be signed by an officer of the corporation. The name and address of the contact, if different than above, and telephone numbers for all listed names shall be included. APPLICABLE RULE(S) OR REGULATION(S): UAC R317-6-6.3.A REGULATORY GUIDANCE REFERENCE(S): N/A 3 Letter to Rusty Lundberg June 5, 2014 Page 4 of20 EFRI Response: The owner/applicant name and contact information have been updated. DRC Comme nt SECTION: 2.3 INTERROGATORY STATEMENT(S): Page 14 says, The name of the facility is the White Mesa Uranium Mill. The facility is a uranium milling and tailings disposal facility, which operates under a Radioactive Materials License issued by the Director of the Utah Division of Radiation Control under UAC R313-24. In addition to uranium in the form of U30s, the Mill also produces vanadium, in the form of vanadium pentoxide (V20s), ammonia metavanadate (AMV) and vanadium pregnant liquor (VPL), from certain conventional ores and has produced other metals from certain alternate feed materials. Alternate feed materials are uranium bearing materials other than conventionally mined ores. Please describe what "other metals from certain alternate feed materials" have been produced. BASIS FOR INTERROGATORY: The license granted under UAC R313-24 limits production of minerals to certain specified types. APPLICABLE RULE(S) OR REGUIATION(S): UAC R313-24; License UT1900479 REGUlATORY GUIDANCE REFERENCE(S): NIA EFRI Response: NRC License SUA-1358, Amendment 4, Part 10.9, authorized the receipt and processing of source material from Cabot Performance Materials ("CPM") facility in Boyertown, Pennsylvania. As noted in the Technical Evaluation Report, included as Appendix A, EFRI (formerly International Uranium (USA) Corporation) was authorized to receive and process the CPM for the recovery of uranium, tantalum and niobium. The text has been changed to reflect the additional metals allowed for receipt, processing and recovery from CPM alternate feed. DRCComment SECTION: 2.7.1 INTERROGATORY STATEMENT(S): It is stated on Page 27 that "Immediately below the FML, each Cell has a nominal 6-inch thick layer of crushed sandstone that was prepared and rolled smooth as an FML sub-base layer." Please correct this statement to include the other two types of sub-base reported by EFR to exist in places beneath the tailings cells. 4 Letter to Rusty Lundberg June 5, 2014 Page 5 of20 BASIS FOR INTERROGATORY: Materials underlying the FML of Cells 2 and 3 apparently consist of crushed sandstone in most locations. However, characterization of all sub-base or underlay materials beneath the cell liners in Cells 2 and 3 as crushed sandstone is not correct. In some locations, the underlay materials are said to consist of either concrete sand or bare rock. Page 23 of 58 in Denison Mines (2012) says of the underlay materials: The material installed beneath the liners in Cells 2 and 3 consists of crushed Dakota sandstone that was compacted with a smooth drum roller, but in some locations, in which a smooth base grade was available, portions of the liner were placed over in-situ Dakota sandstone (H. Roberts, 2012) (emphasis added). This same document also states that The Second Phase Tailings Management system Construction Report generally is consistent with this observation: Energy Fuels Nuclear Inc. (1983) noted that a gravel-sand mixture derived from crushing of loose [Dakota] sandstone, with some washed concrete sand in some areas, was used to construct the compacted bedding layer immediately beneath the liner in Cell 3; and that a similar process and materials were used for the liner bedding material in Cell 2" (emphasis added). Thus, it is seen that the thickness of crushed sandstone is appreciably less than six inches, being, in fact, zero, in some locations. In some locations, FML is laid directly upon the Dakota Sandstone. In other locations, washed concrete sand is substituted for or added to crushed sandstone. Acknowledgment of these variant types of materials used in the sub-base of the liner in the RA is important since each type of material potentially has different hydraulic properties and has a bearing on the modeling of whether or not "the discharge can be controlled and will not migrate into or adversely affect the quality of any other waters of the state." APPLICABLE RULE(S) OR REGULATION(S): UAC R317-6-6.3.G REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: The sentence "Immediately below the FML, each Cell has a nominal 6-inch thick layer of crushed sandstone that was prepared and rolled smooth as an FML sub-base layer." has been replaced with the following text: The criterion for placement of the FML in Cells 1, 2 and 3 was a smooth sub base with no rocks protruding that could potentially damage the FML. The cells were excavated by ripping the in-place Dakota Sandstone with a large dozer. Where the rock could not be efficiently ripped, explosives were used to loosen the rock. The cell bottom was then graded to the final design contours and rolled with a smooth drum vibrating roller. The smooth drum roller effectively crushed the loose sandstone, filling in small holes, and 5 Letter to Rusty Lundberg June 5, 2014 Page 6 of20 allowed for a smooth surface suitable for liner placement. Due to the excavation methods (ripping and blasting) there were some areas that required little or no fill to meet final grades, while other areas required placement of additional crushed sandstone to meet the final grade. The cell bottom was sometimes re-worked several times to accomplish the desired result. The majority of the cell bottom is covered with a layer (1 to 6 inches) of crushed sandstone while the liner in some areas is placed directly on a smooth rolled surface of Dakota Sandstone with only a thin veneer of re-compacted sandstone. In places where the surface was rough or contained small holes, washed concrete sand was used to fill or smooth the imperfections, and the area was then rolled one last time before FML placement. Areas of crushed sandstone filled sub base versus areas with little or no crushed sandstone base were not documented during construction. Areas filled or smoothed with washed concrete sand is likely less than 0.1% of the cell bottoms. DRCComment SECTION: 2. 7.2.4 INTERROGATORY STATEMENT(S): Page 29 indicates that "Denison submitted an Infiltration and Contaminant Transport Modeling ("ICTM") Report, White Mesa Mill Site, Blanding, Utah ... to fulfill the requirements of Part I.H.ll of the Permit." Please revise the sentence above to show the correct part of the Permit. BASIS FOR INTERROGATORY: The requirements for the ICTM in the Permit are found in Part I.H.2 in the current version of the Permit. APPLICABLE RULE(S) OR REGULATION(S): See Permit No. UGW370004 REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: The reference has been corrected. DRCComment SECTION: 2. 7.6 INTERROGATORY STATEMENT(S): Relative to Roberts Pond, Page 35 says that "an appropriate DMT operation standard", as referenced in Permit, includes "a stipulation that the Mill maintain a minimal wastewater head in this pond based on a 2joot freeboard limit and a ljoot additional operating limit. " Please rewrite this statement to correct it and render it consistent with provisions in the Permit. 6 Letter to Rusty Lundberg June 5, 2014 Page 7 of20 BASIS FOR INTERROGATORY: The statement quoted above uses the phrase "minimal wastewater head, " but this is incorrect. In the existing context, that phrase neither makes sense nor corresponds to the Permit language. What would work in the statement would be language similar to either "minimum distance between the wastewater suiface and the pond-bank crest" or "maximal wastewater head." The minimum distance between the wastewater suiface and the pond-bank crest is equal to the minimum freeboard of two feet, as required by the Permit, plus an additional one foot of freeboard as determined by the Pennittee, these together constituting the operating limit employed by the Permittee for safety purposes. The maximal wastewater head should not exceed the elevation of the pond-bank crest minus three feet, which is the sum of the two feet of freeboard and the one foot of additional operating distance. The language of the Permit itself is as follows: The Pennittee shall operate this wastewater pond so as to provide a minimum 2-footfreeboard at all times. Under no circumstances shall the water level in the pond exceed an elevation of 5,624 feet amsl. In the event that the wastewater elevation exceeds this maximum level, the Permittee shall remove the excess wastewater and place it into containment in Tailings Cell 1 within 72-hours of discovery. It is important to make the distinctions above since a literal interpretation of the existing language would constrain the level in the pond to exceed the limits set by the Pennittee and possibly exceed the limits stated in the Permit. APPLICABLE RULE(S) OR REGUIATION(S): See Permit No. UGW370004 REGUlATORY GUIDANCE REFERENCE(S): NIA EFRI Response: The text has been changed to reflect the requirements from the GWDP .. DRCComment SECTION: 2.7.7.1 INTERROGATORY STATEMENT(S): On Page 35, it says The Permit requires the Mill to continue its existing practice of limiting open air storage of feedstock materials to the historical storage area found along the eastern margin of the Mill site (as defined by the survey coordinates found in Permit Table 4); and one of the following three practices: 1) Store feedstock materials in water-tight contains, or 2) Place feedstock containers in water-tight overpack containers, or 3) place feedstock containers on a hardened suiface that conforms to the requirements spelled out in the permit part l.D.ll d) 1 through 5. 7 Letter to Rusty Lundberg June 5, 2014 Page 8 of20 Please correct that part of the statement following the phrase "one of the following three practices" since that is at variance with the Permit. BASIS FOR INTERROGATORY: The Permit, portions of which are now quoted, actually requires two practices (see Part l.D.ll ), as follows: (1) "Feedstock materials will be stored at all times in water-tight containers, and" (2) compliance with one of the following options is required: (b) Aisle ways will be provided at all times to allow visual inspection of each and every feedstock container, or (c) Each and every feedstock container will be placed inside a water-tight overpack prior to storage, or (d) Feedstock containers shall be stored on a hardened surface to prevent spillage onto subsurface soils, and that conforms with the following minimum physical requirements . . . [emphasis added] which physical requirements are listed specifically in the Permit. Thus, the Permit requires two practices. This is a different requirement from (and twice the number of) "one of ... three practices", which is incorrectly referenced in the RA. The first of the required two practices included in the Permit is that ''feedstock materials will be stored at all times in water-tight containers. " This first practice is thus mandatory regardless of which option is selected for a second practice. As indicated in the Permit, a second required practice is then selected from one of three available options. These three are the options labeled as (b), (c) and (d) shown above. An additional significant point is that only two of the three options for the second practice stated in the Permit as being available are currently listed in the RA. The option about "(b) Aisle ways will be provided at all times to allow visual inspection of each and every feedstock container" is not listed in the RA. It needs to be, since that is one of the options provided in the referenced Permit. Using a different, somewhat more symbolic approach, the RA perspective of (the first practice listed or cor d) needs to be replaced by Permit perspective of (the first practice listed and (b or cor d)). APPLICABLE RULE(S) OR REGULATION(S): See Permit No. UGW370004 REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: EFRI agrees that Part I.D.ll of the GWDP is poorly worded and should be clarified. However, EFRI disagrees with DRC's interpretation as set out in the foregoing Interrogatory, which is inconsistent 8 Letter to Rusty Lundberg June 5, 2014 Page 9 of20 with the intent of DRC as reflected in the September 2009 Statement of Basis that accompanied the applicable revisions to the GWDP. On page 28 of that Statement of Basis, DRC wrote: "On June 20, 2008, DUSA submitted a White Mesa Mill-Containerized Alternate Feedstock Material Storage Procedure. After reviewing the submittal, the DRC found that the procedure again failed to address all of the DRC concerns listed in the April 29, 2008 DRC Request for Additional Information Letter. In order to expedite resolution of these concerns, the DRC has modified Part I.D.11 with new performance requirements for storing feedstock material outside of the ore storage area, with an eye to the following goals: 1) containers are maintained in a water tight condition to prevent soil and groundwater pollution, and 2) aisleways are provided between containers to allow physical entry and visual inspection, early detection, and timely remediation of leakage. In the event that DUSA cannot meet goals 1 and 2, options are provided in Part I.D.ll for DUSA to seek out DRC approval and perform said storage over an engineered surface of concrete or asphalt with certain other performance criteria. Related BAT monitoring requirements were also added at Part I.E.7(d) and (e)." Accordingly, the intention of Part I.D.11 is to provide the Mill with the following three options: 1. Store feedstock materials in water-tight containers, and aisle ways will be provided at all times to allow visual inspection of each and every feedstock container; or 2. Each and every feedstock container will be placed inside a water-tight overpack prior to storage; or 3. Feedstock containers shall be stored on a hardened surface to prevent spillage onto subsurface soils, and that conforms with the following minimum physical requirements ... As currently drafted, Part I.D.11. of the GWDP is confusing because the word "and" between subparagraphs a) and b) is intended to refer to those two subparagraph only, and the word "or" is used to distinguish the other two options. However, the wording is ambiguous because, without knowing the intent, other interpretations are possible. The intention was clearly to avoid the contents from any damaged 55-gallon drums from making contact with the surface of the ground when stored outside the ore storage area. As stated earlier on page 28 of the Statement of Basis: "On May 9, 2007, DRC and NRC staff performed an inspection at the Mill site. During the inspection DRC staff found several hundred 55-gallon drums containing alternate feedstock material; many of which were bent, dented, and rusting at the perimeter of the drum pile. While none were found to be leaking, the DRC staff observed that the drums were triple stacked at least ten deep, with less than a 3-inch spacing between rows of drums, which made it impossible to physically enter and visually inspect the condition of each of the drums." 9 Letter to Rusty Lundberg June 5, 2014 Page 10 of20 Each of the three options delineated above were considered satisfactory to address DRC's concerns relating to bent, dented and rusting drums. The aisle ways were intended to allow the Mill and DRC to determine by inspection that the 55-gallon drums are themselves watertight. Placing bent, dented and rusted drums in water-tight overpacks or on an impermeable surface was also considered satisfactory to address those concerns. There is no need to require water tight containers to also be placed in water-tight overpacks or on an impermeable surface. That would be redundant. Accordingly, EFRI requests that Part I.D.11 of the renewed GWDP be revised to read as follows: "11. BAT Requirements for Feedstock Material Stored Outside the Feedstock Storage Area-the Permittee shall store and manage feedstock materials outside the ore storage pad in accordance with the following minimum performance requirements: a) Feedstock materials will be stored at all times in water-tight containers, and aisle ways will be provided at all times to allow visual inspection of each and every feedstock container, or b) Each and every feedstock container will be placed inside a water-tight overpack prior to storage, or c) Feedstock containers shall be stored on a hardened surface to prevent spillage onto subsurface soils, and that conforms with the following minimum physical requirements ... [remainder of Section remains unchanged]" DRCComment SECTION: 2. 7. 7.2 INTERROGATORY STATEMENT(S): On Page 35, the RA states "For new facilities constructed at the Mill, or reconstruction of existing facilities, Part l.D.3( e) requires the higher standard of secondary containment that would prevent contact of any potential spill with the ground suiface. " Please correct the reference made in this sentence to the Permit. BASIS FOR INTERROGATORY: The correct reference should be Part l.D.3(g). APPLICABLE RULE(S) OR REGULATION(S): See Permit No. UGW370004 REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: The reference has been corrected. 10 Letter to Rusty Lundberg June 5, 2014 Page 11 of 20 DRCComment SECTION: 2.9.1.3 INTERROGATORY STATEMENT(S): Page 39 of the RA says Part l.E.1 (d) of the Permit requires that each point of compliance well must be sampled for the constituents listed in Table 2.9.1.3-1. Further, Part l.E.1.(d)l) of the Permit, requires that, in addition to pH, the following field parameters must also be monitored: • Depth to groundwater • Temperature • Specific conductance The Permittee needs to add to the list of parameters referenced with respect to Part I.E.1(d)(1) the following parameter: redox potential (Eh). BASIS FOR INTERROGATORY: Part 1.E.1(d) of the Permit states the following: d) Compliance Monitoring Parameters -all groundwater samples collected shall be analyzed for the following parameters: 1) Field Parameters -depth to groundwater, pH, temperature, specific conductance, and redox potential (Eh). From this, it is seen that redox potential (Eh) is a field parameter currently left out of the description in the RA. It is important to include Eh as a field parameter in order to estimate redox conditions in the perched water zone. APPLICABLE RULE(S) OR REGULATION(S): See Permit No. UGW370004 REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: Redox potential has been added to the list of required field parameters. DRCComment SECTION: 2.12.1 INTERROGATORY STATEMENT(S): Reference is made to the Tailings and Slimes Drain Sampling Program, Revision 0, November 20, 2008 as Appendix H. Please change the appendix name to Appendix I. 11 Letter to Rusty Lundberg June 5, 2014 Page 12 of20 BASIS FOR INTERROGATORY: Appendix H is not the correct appendix name for this document. The correct appendix name is Appendix I. The name needs to be changed to correspond with the actual paper and electronic copies of the RA. APPLICABLE RULE(S) OR REGULATION(S): N/A REGULATORY GUIDANCE REFERENCE(S): NIA EFRI Response: The Appendix reference has been changed. It is important to note that additional appendices have been added to the document and all subsequent appendix references have been changed accordingly. DRC Comment SECTION: 2.15.2.2 INTERROGATORY STATEMENT(S): As stated in the RA, "Part I.D.3(b)(1) of the Permit requires that Denison must at all times maintain the average wastewater head in the slimes drain access pipe to be as low as reasonable achievable (ALARA) in each tailings cell, in accordance with the approved DMT Plan." However, no data are provided in the RA in support of a demonstration of compliance to this objective. In addition, the RA states in Part I.D.3(b )( 3) that Compliance will be achieved when the average annual wastewater recovery elevation in the slimes drain access pipe, determined pursuant to the currently approved DMT Plan meets the conditions in Equation 1 specified in Part I.D.3(b )( 3) of the Permit. Again, the RA provides no relevant information about the current approach to compliance. For each cell, accordingly please provide the following, where feasible: (1) Historical records over the past four years (2009 to 2012, inclusive) chronicling measurements of "the average wastewater head in the slimes drain access pipe" for Cells 2 and 3, listed by date. Elevations can be obtained by subtracting quarterly measurements of depth to the wastewater, as required by Part I.E. 7(b) of the Permit, from the reference elevation (e.g., top of pipe elevation). (2) Data demonstrating how well, to date, "the average annual wastewater recovery elevation in the slimes drain access pipe, determined pursuant to the currently approved DMT Plan meets the conditions in Equation 1 specified in Part I.D.3(b )( 3) of the Permit." This Equation basically tests each current year's 3-year average slime drain elevation against the previous year's to see if the current year's is less. 12 Letter to Rusty Lundberg June 5, 2014 Page 13 of20 ( 3) Plans for decreasing "the average wastewater head in the slimes drain access pipe" for Cells 2 and 3 in the future, along with a planned schedule for reducing the head to the closure goal of no more than three feet above the FML within the next several years. These plans should include efforts to accelerate drawdown to meet AIARA criteria. BASIS FOR INTERROGATORY: Part I.E. 7(b) of the Permit states Quarterly Slimes Drain Water Level Monitoring: Cells 2 and 3 -the Permittee shall monitor and record quarterly the depth to wastewater in the slimes drain access pipes as described in Part I.D.3 of this Permit and the currently approved DMT Monitoring Plan at Tailings Cells 2 and 3 to determine the recovery head. For purposes of said monitoring, the Permittee shall at each tailings cell: 1) Perform at least 1 separate slimes drain recovery test at each disposal cell in each quarterly period of each calendar year that meets the requirements of Part I.D.3, 2) Designate, operate, maintain, and preserve one water level measuring point at the centerline of the slimes drain access pipe that has been surveyed and certified by a Utah licensed engineer or land surveyor, 3) Make all slimes drain recovery head test (depth to fluid) measurements from the same designated water level measuring point, and 4) Record and report all fluid depth measurements to the nearest 0.01 foot. 5) For Cell 3 these requirements shall apply upon initiation of tailings de-watering operations. Part l.D.3(b)(3) states that Annual Slimes Drain Compliance -shall be achieved when the average annual Wastewater recovery elevation in the slimes drain access pipe, as determined pursuant to the currently approved DMT Monitoring Plan, meets the conditions in Equation 1 below: Equation 1: [ IEy + IEy-t + IEy-2] I [Ny + Ny-t + Ny-2] < [ IEy-1 + IEy-2 + IEy-3] I [Ny-1 + Ny-2 + Ny-3] Where: IEy = Sum of all monthly and quarterly slimes drain tailings fluid elevation measurements that meet the test performance standards found in the sub-paragraphs of Part I.D.3(b)(2), during the calendar year of interest. Hereafter, these water level measurements are referred to as slimes drain recovery elevations (SDRE). Pursuant to the applicable frequency and method of the approved DMT Monitoring Plan at the time of each SDRE test, these recovery tests are to be conducted and the SDRE values reported in units of feet above mean sea level (amsl). However, when monthly and quarteriy 13 Letter to Rusty Lundberg June 5, 2014 Page 14 of20 measurements are combined in the above equation, the quarterly values shall be multiplied by a coefficient of three ( 3 ). IEy-1 = Sum of all SDRE measurements made in the year previous to the calendar year of interest. However, when monthly and quarterly measurements are combined in the equation above, each quarterly value shall be multiplied by a coefficient of three ( 3 ). IEy-2 = Sum of all SDRE measurements made in the second year previous to the calendar year of interest. However, when monthly and quarterly measurements are combined in the equation above, each quarterly value shall be multiplied by a coefficient of three ( 3 ). IEy-3 = Sum of all SDRE measurements made in the third year previous to the calendar year of interest. However, when monthly and quarterly measurements are combined in the equation above, each quarterly value shall be multiplied by a coefficient of three ( 3 ). Ny = Total number of SDRE tests that meet the test performance standards found in Part I.D.3(b)(2), conducted during the calendar year of interest. However, when monthly and quarterly measurements are used in the equation above, each quarterly test shall be counted as three (3) separate tests. Ny-l = Total number of SDRE tests that meet the test performance standards found in Part I.D.3(b)(2), conducted in the year previous to the calendar year of interest. However, when monthly and quarterly measurements are used in the equation above, each quarterly test shall be counted as three ( 3) separate tests. Ny-2 = Total number of SDRE tests that meet the test performance standards found in Part I.D.3( b )(2 ), conducted in the second year previous to the calendar year of interest. However, when monthly and quarterly measurements are used in the equation above, each quarterly test shall be counted as three ( 3) separate tests. Ny-3 = Total number of SDRE tests that meet the test performance standards found in Part l.D.3( b )(2 ), conducted in the third year previous to the calendar year of interest. However, when monthly and quarterly measurements are used in the equation above, each quarterly test shall be counted as three ( 3) separate tests. Prior to January 1, 2013, the following values forE and N values in Equation 1 shall be based on SDRE datafrom the following calendar years. Report for Calendar Year 2010 2011 2012 Source of Data bv Ct.dendar Year {o1· EquaLion 1 Variable-s (right side) Ey Ey-1 Ey-2 Ny Ny-1 Ny-2 2009 2009 2009 2009 2009 2009 2010 2009 2009 2010 2009 2009 2011 2010 2009 2011 2010 2009 Failure to satisfy conditions in Equation 1 shall constitute DMT failure and noncompliance with this Permit. For Cell 3, this requirement shall apply after initiation of de-watering operations [Emphasis added]. If recent performance on reducing the wastewater heads in the cells indicates that the current rate of drawdown may not be sufficient to attain dewatering performance objectives within the next several years, as has recently been indicated by the DRC during ICTM and REC Plan discussions, then plans 14 Letter to Rusty Lundberg June 5, 2014 Page 15 of 20 for remedial activities for the slimes drain will be needed. Equation 1 above will be used to address requirement (2) above. APPLICABLE RULE(S) OR REGULATION(S): See Permit No. UGW370004 REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: At this time, de-watering of Cell 3 has not commenced and no data are available at this time. A statement has been added to Section 2.15.2.2 noting that de-watering of Cell 3 has not started. DRC Comment ( 1) above Measurements of the Cell 2 slimes drain wastewater head are documented in each quarterly DMT report submitted to DRC pursuant to the requirements of Part I.F.1, Table 7 of the GWDP. The quarterly measurement forms and a graphical representation of the Cell 2 slimes data are included each quarter. The requested data has been summarized and included in Appendix J of the GWDP Application. DRC Comment (2) above Annual compliance calculations pursuant to Part I.D.3(b)(3) of the GWDP are submitted to DRC on or before March 1 of the following year. A summary of the annual compliance data, although presented elsewhere, have been added to Appendix J of the GWDP Application DRC Comment (3) above As noted in Appendix J of the GWDP Application, annual slimes drain compliance was not achieved for 2010, in accordance with Part I.D.3 of the Permit. As noted in correspondence with DRC, the monthly monitoring requirements specified in Part I.D.3(b)(2) of the February 2011 revision of the GWDP seriously interfered with EFRI's ability to comply with Parts I.D.3(b)(i) and I.D.3 (b)(3) of the GWDP. The monthly testing requirement resulted in the slimes drain pump being off (not pumping) an average of 6.42 days per month every month which is equivalent to 77 days (11 weeks) per year or 20 percent of the year for performance of the measurements. The GWDP was amended in July 2011 to change the frequency of the slimes drain testing from monthly to quarterly. The average annual wastewater recovery elevation in the slimes drain pipe has been in compliance, that is, less than the previous year's running average since the monitoring frequency changed from monthly to quarterly in July 2011. 15 Letter to Rusty Lundberg June 5, 2014 Page 16 of 20 At the time Equation 1 was added to Part I.D.3(b)(3) of the GWDP, EFRI and DRC had extensive discussions as to what dewatering activities would satisfy the ALARA goal specified in Part I.D.3(b )(i). After reviewing the available options, taking into consideration the design of the cells and their slimes drain systems, DRC and EFRI agreed that operation of the slimes drain systems in a manner that complies with Equation 1 would satisfy the ALARA goal. As can be seen from the data in Appendix J to the GWDP Application, the slimes drain head levels have decreased in compliance with Equation 1, and at a faster rate since the change in monitoring frequency from monthly to quarterly. The Cell2 de-watering results are in compliance with the GWDP requirements and with the ALARA goals and no changes are required to the program at this time. DRCComment SECTIONS: 2.15.3.1, 2.15.3.2, 2.15.4 INTERROGATORY STATEMENT(S): Please fix the wording in these sections in reference to Part I.H.19. BASIS FOR INTERROGATORY: I.H. sections only extend to Part I.H.7. There is no Part I.H.19 in the current Permit. Similar problems appear in other parts of Section 2.15.3.1 and in Sections 2.15.3.2 and 2.15.4. Please adjust the references so they are consistent with the current Permit. APPLICABLE RULE(S) OR REGULATION(S): See Permit No. UGW370004 REGULATORY GUIDANCE REFERENCE(S): NIA EFRI Response: The text has been modified to reference the DRC-approved BAT Operations and Maintenance Plan. DRCComment SECTIONS: 2.19.2 and 2.19.3 INTERROGATORY STATEMENT(S): Page 78 of the RA states in Part 2.19.2 that: "The Mill's Reclamation Plan, Revision 4.0, was approved by the DRC under the Mill License in January 2011." This statement is incorrect. The currently approved reclamation plan is 3.2B, which was approved by the DRC on January 26, 2011. Section 2.19.2 and 2.19.3 also describe the Denison Mines submittal of Revision 5.0 of the Reclamation Plan in September 2011" and that "submission of responses to all first round interrogatory questions will be completed by August 14, 2013." Additional information about the Reclamation Plan is provided in Section 2.19.3 on Page 79. Please update this information to include concepts and data in a new version of the Reclamation Plan modified in response to information shared at recent meetings between the Permittee and the DRC. 16 Letter to Rusty Lundberg June 5, 2014 Page 17 of20 BASIS FOR INTERROGATORY: A meeting was held in Denver Colorado on April 29, 2013 concerning the version of the Reclamation Plan and the related version of the Infiltration and Contaminant Transport Model report then extant. Participating in the meeting were representatives of the Permittee, its consultant (MWH Americas), the DRC, and its consultant (URS Professional Solutions). A number of issues concerning the then-extant version of the Reclamation Plan were raised at this meeting, many were resolved verbally, and others were left as being yet to be resolved. Decisions were made at the meeting related to the Permittee undertaking additional work and responding to questions raised by the DRC. These issues, their resolutions and additional work to be done will help finalize a new version of the Reclamation Plan. The changes in the new version of the Reclamation Plan have need of being discussed in the RA to make it current. APPLICABLE RULE(S) OR REGULATION(S): NIA REGULATORY GUIDANCE REFERENCE(S): N/A EFRI Response: The text of Section 2.19 .2 of the Renewal Application has been updated to reference the current approved Reclamation Plan as Version 3.2B approved by DRC on January 26, 2011. The text of Sections 2.19.2 and 2.19.3 of the Renewal Application have been revised to provide updated information on the status of Revision 5.0 of the Reclamation Plan. DRCComment SECTION: Appendix A INTERROGATORY STATEMENT(S): A number of apparent discrepancies exist between well locations shown in San Juan County plats in Appendix A and well locations shown in Figure 10, White Mesa Site Plan Showing Locations of Perched Wells and Piezometers. Please reconcile these, or provide explanations, if information provided is believed to be correct as is. BASIS FOR INTERROGATORY: There are several types of discrepancies noted when comparing well locations in San Juan County plats in Appendix A of the RA and well locations shown in Figure 10 of the RA, entitled White Mesa Site Plan Showing Locations of Perched Wells and Piezometers. • A San Juan plat for Section 22, T37S, R22E is missing. This plat is important, and it needs to be included in the RA, because wells TWN-12, TWN-16 and TWN-19 are located in Section 22. • The San Juan plats show what appear to be duplicate locations for each of the following pairs of wells, in which each well in each pair is placed in different sections. TW4-19 (two locations: one in Section 28 and one in Section 33 ofT27S, R22E.) TW4-22 (two locations: one in Section 28 and one in Section 33 ofT27S, R22E.) 17 Letter to Rusty Lundberg June 5, 2014 Page 18 of 20 MW-21 (two locations: one in Section 32 of T37S, R22E and one in Section 5 of T38S, R22E.) Please work with San Juan County to correct these apparent discrepancies, in case a mis- mapping could otherwise cause legal or other problems down the road, or even if it only might cause confusion. If the San Juan County plats are corrected, then please include the correct plats in the RA once this is accomplished. • The following abandoned wells are shown as wells in San Juan County plats but are not shown in Figure 10: MW-16 (Section 32 ofT37S, R22E) DR-2 (Section 32 ofT37S, R22E) DR-16 (Section 5 ofT38S, R22E) DR-18 (Section 5 ofT38S, R22E) DR-25 (Section 5 ofT38S, R22E) While it is not necessary from the perspective of the DRC for EFR to take any action on mapping of these wells, since they are abandoned, the DRC does point out the apparent discrepancy between the county plats and Figure 10 with respect to their apparent existence. APPLICABLE RULE(S) OR REGULATION(S): N/A REGULATORY GUIDANCE REFERENCE(S): NIA EFRI Response: EFRI contacted San Juan County to address the discrepancies noted in this comment. San Juan County does not record well locations on plat maps. Pursuant to a telephone conversation with DRC on April 30, 2014, EFRI has provided maps in Appendix B showing land ownership, well locations, surface water features, and structures to address the appropriate GWDP Renewal Application requirements. DRCComment SECTION: Appendix L INTERROGATORY STATEMENT(S): The first listing of "Aluminum Powder" in Appendix Lis out of order alphabetically, and the quantity shown for it, 0 g, is incorrect. Please remove this first listing, inasmuch as there is also a later listing that is ordered alphabetically, which has an entry for the correct quantity. 18 Letter to Rusty Lundberg June 5, 2014 Page 19 of20 BASIS FOR INTERROGATORY:): In the alphabetical listing of laboratory chemicals on site, the item "Aluminum Powder", when first introduced, is listed between "Aluminum Metal, granular" and "Aluminum Nitrate, Nona hydrate. " Furthermore, the quantity given, 0 g, appears to be incorrect, since a subsequent listing for "Aluminum Powder", the one that is listed between "Aluminum Potassium Sulfate 12 Hydrate Crystal" and "Aluminum Reagent 2," has an entry for quantity of 300 g. APPLICABLE RULE(S) OR REGULATION(S): N/A REGULATORY GUIDANCE REFERENCE(S): NIA EFRI Response: The first listing of aluminum powder in the laboratory chemical inventory has been deleted. DRCComment SECTION: Appendix L INTERROGATORY STATEMENT(S): Is the chemical inventory list provided in the RA (Appendix L) complete, listing every chemical either stored or used (either now or in the past) at the facility? If not, then please discuss each exception and indicate why it is not listed, or, alternatively, add it to the inventory list. BASIS FOR INTERROGATORY: The text of the RA refers to Part l.H.l of the Permit. The text states that Part /.H. I "requires that Denison" (now EFR) "complete a historical review and conduct an inventory of all chemical compounds or reagents stored, used, or current in use at the facility, including the types of chemicals and the total volumes present, and historically used, as data is available." It says that, in application to renew the Permit, the Permittee "shall submit an updated inventory report. " However, while the requirements are stated, the list currently submitted as Appendix L of the RA is entitled simply "Laboratory Chemical Inventory." This title by itself conveys the impression, whether rightly or wrongly, of possible insufficient compliance with Permit requirements. Part I.H.l of the Permit refers not to a "laboratory chemical inventory " (which might exclude chemicals used in places at the facility other than in a laboratory) but refers to an "on-site chemicals inventory." The latter title suggests an inventory potentially more comprehensive than simply a laboratory chemical inventory. The Permit says of this on-site chemicals inventory that it must report the names of "all chemical compounds and reagents stored, used or currently in use at the facility". The text of the Permit later specifies that the Permittee "identify all chemicals used in the milling and milling related processes at White Mesa" (emphasis added). If there are chemicals that are currently being used, or that have been used in the past, at the facility, that are not that are not listed in the "Laboratory Chemical Inventory", then these need to be specified at this point by the Permittee in an updated inventory. 19 Letter to Rusty Lundberg June 5, 2014 Page 20 of20 The current submittal does not discuss chemicals formerly used at the facility but not currently found in the laboratory nor does it mention their estimated volumes. This needs to be done. Furthermore, as part of the new inventory to be submitted, the Permittee needs to include a statement attesting that, according to the best information to be had, the listing contained therein includes the names and quantities of every chemical either stored or used (either now or in the past) at the facility. Such a statement is needed to confirm that the requirements of the Permit that names and quantities of all chemicals are being reported. EFRI Response: The 2012 GWDP Renewal Application did include a current chemical inventory for other areas of the Mill and was not limited to only laboratory chemicals as implied by the comment. The 2012 GWDP Renewal Application included the following tables in Appendix L: • L-1 Laboratory Chemical Inventory • L-2 Current Mill Chemical Inventory • L-3 Cleaners • L-4 Chemicals Formerly Used/No Longer Used or Present on Site Appendices L-1 through L-3 have been updated (moved to Appendix 0) to include historic quantities of the chemicals that were used. Appendix L-4 (now 0-4) as submitted with the 2012 GWDP Renewal Application, already included an estimation of the maximum quantity that was historically present/used, and therefore no changes were made to that Appendix. Additional chemicals have been added as necessary. Please contact me if you have any questions or require any further information. Your very lrU I y ~ iN~E Kathy Weinel •S (USA) INC. Quality Assurance Manager cc: David C. Frydenlund Harold R. Roberts David E. Turk Dan Hillsten 20 White Mesa Mill Renewal Application State of Utah Groundwater Discharge Permit No. UGW370004 Energy Fuels Resources (USA) Inc. June 2014 1.0 INTRODUCTION 1.1 Background 1.2 Applicable Standards for Review and Approval of this Application 1.3 Background Groundwater Reports and Re-opening of Permit 2.0 INFORMATION PROVIDED IN SUPPORT OF THE APPLICATION 2.1 Name and Address of Applicant and Owner (R317-6-6.3.A) 2.2 Legal Location of the Facility (R317-6-6.3B) 2.3 Name and Type of Facility (R317-6-6.3.C) 5 5 5 9 17 17 18 18 2.4 A Plat Map Showing All Water Wells, Including The Status And Use Of Each Well, Drinking Water Source Protection Zones, Topography, Springs, Water Bodies, Drainages, And Man-Made Structures Within A One-Mile Radius Of The Discharge. (R317-6-6.3.D)19 2.5 Geologic, Hydrologic, and Agricultural Description of the Geographic Area (R317 -6- 6.3.E) 19 2.5.1 Groundwater Characteristics 19 2.5.1.1 Geologic Setting 19 2.5.1.2 Hydrogeologic Setting 20 2.5.1.3 Perched Zone Hydrogeology 20 2.5.1.4 Perched Groundwater Flow 23 2.5.1.5 Perched Zone Hydrogeology Beneath And Downgradient Of The Tailings Cells 24 2.5.2 Groundwater Quality 26 2.5.2.1 Entrada/Navajo Aquifer 26 2.5.2.2 Perched Groundwater Zone 26 2.5.3 Springs and Seeps 26 2.5.4 Topography 27 2.5.5 Soils 27 2.5.6 Bedrock 28 2.5.7 Agricultural and Land Use Description of the Area 29 2.5.8 Well Logs 29 2.6 The Type, Source, and Chemical, Physical, Radiological, and Toxic Characteristics of the Effluent or Leachate to be Discharged (R317-6-6.3.F) 30 2. 7 Information Which Shows that the Discharge can be Controlled and Will Not Migrate Into or Adversely Affect the Quality of any Other Waters of the State (R317-6-6.3.G) 30 2. 7.1 General 30 2.7.2Cells1,2and3 31 2. 7 .2.1 Design and Construction of Cells 1, 2 and 3 31 1 2.7.2.2 Improved Groundwater Monitoring 2.7.2.3 Operational Changes and Improved Operations Monitoring 2.7.2.4 Evaluation of Tailings Cell Cover System Design 2.7.3 Cell4A 2.7.4 Cell4B 2. 7.5 Future Additional Tailings Cells 2.7.6 Roberts Pond 2.7.7 Other Facilities and Protections 2.7.7.1 Feedstock Storage 2.7.7.2 Mill Site Reagent Storage 2.7.7.3 New Construction 2.7.7.4 Other 2.7.8 Surface Waters 2.7.9 Alternate Concentration Limits 32 33 33 34 36 39 39 39 39 40 40 40 41 41 2.8 For Areas Where the Groundwater Has Not Been Classified by the Board, Information of the Quality of the Receiving Ground Water (R317-6-6.3.H) 41 2.8.1 Existing Wells at the Time of Original Permit Issuance 42 2.8.2 New Wells Installed After the Date of Original Issuance of the Permit 42 2.9 Sampling and Analysis Monitoring Plan (R317-6-6.3.1) 43 2.9.1 Groundwater Monitoring to Determine Groundwater Flow Direction and Gradient, Background Quality at the Site, and the Quality of Groundwater at the Compliance Monitoring Point 43 2.9.1.1 Groundwater Monitoring at the Mill Prior to Issuance of the Permit 43 2.9.1.2 Issuance of the Permit 43 2.9.1.3 Current Ground Water Monitoring Program at the Mill Under the Permit 44 2.9.1.4 Groundwater Flow Direction and Gradient 45 2.9.1.5 Background Quality at the Site 45 2. 9 .1.6 Quality of Ground Water at the Compliance Monitoring Point 46 2.9.2 Installation, Use and Maintenance of Monitoring Devices 47 2.9.2.1 Compliance Well Monitoring 47 2.9.2.2 Leak Detection System in Cell4A and Cell4B 47 2.9.2.3 Other DMT Monitoring Requirements 47 2.9.3 Description of the Compliance Monitoring Area Defined by the Compliance Monitoring Pcin~ ~ 2.9.4 Monitoring of the Vadose Zone 48 2.9.5 Measures to Prevent Ground Water Contamination After the Cessation of Operation, Including Post-Operational Monitoring 48 2.9.5.1 Measures to Prevent Ground Water Contamination After the Cessation of Operation 48 2.9.5.2 Post-Operational Monitoring 2.9.6 Monitoring Well Construction and Ground Water Sampling Which Conform Where Applicable to Specified Guidance 2.9.6.1 Monitoring Well Construction 2.9.6.2 Ground Water Sampling 2.9.7 Description and Justification of Parameters to be Monitored 2 48 48 48 52 53 2.9.8 Quality Assurance and Control Provisions for Monitoring Data 53 2.10 Plans and Specifications Relating to Construction, Modification, and Operation of Discharge Systems (R317-6-6.3.J) 54 2.11 Description of the Ground Water Most Likely to be Affected by the Discharge (R317- 6-6.3.K) 54 2.11.1 General 54 2.11.2 Background Ground Water Quality in the Perched Aquifer 55 2.11.3 GWCL Determination for Field pH 60 2.11.4 Quality of Ground Water at the Compliance Monitoring Point 62 2.12 Compliance Sampling Plan (R317-6-6.3.L) 62 2.12.1 Tailings Cell Wastewater Quality Sampling Plan 62 2.12.2 White Mesa Seeps and Springs Sampling Plan 63 2.12.3 Monitoring of Deep Wells 64 2.13 Description of the Flooding Potential of the Discharge Site (R317-6-6.3.M) 64 2.13 .1 Surface Water Characteristics 64 2.13.2 Flood Protection Measures 65 2.14 Contingency Plan (R317-6-6.3.N) 65 2.15 Methods and Procedures for Inspections of the Facility Operations and for Detecting Failure of the System (R317-6-6.3.0) 65 2.15.1 Existing Tailings Cell Operation 66 2.15.2 Existing Facility DMT Performance Standards 66 2.15.2.1 DMT Monitoring Wells at Cells 1, 2 and 3 66 2.15.2.2 Slimes Drain Monitoring 66 2.15.2.3 Maximum Tailings Waste Solids Elevation 67 2.15.2.4 Wastewater Elevation in Roberts Pond 67 2.15.2.5 Inspection of Feedstock Storage Area 67 2.15.2.6 Monitor and Maintain Inventory of Chemicals 68 2.15.3 BAT Performance Standards for Cell4A 69 2.15 .3 .1 BAT Operations and Maintenance Plan 69 2.15.3.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan 69 2.15.4 BAT Performance Standards for Cell4B 70 2.15.4.1 BAT Operations and Maintenance Plan 70 2.15.4.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan 70 2.15.5 Stormwater Management and Spill Control Requirements 71 2.15.6 Tailings and Slimes Drain Sampling 72 2.15.7 Additional Monitoring and Inspections Required Under the Mill License 72 2.15.7.1 Daily Inspections 72 2.15.7.2 Weekly Inspections 73 2.15.7.3 Monthly Reports 73 3 2.15.7.4 Quarterly Tailings Inspections 2.15.7.5 Annual Evaluations 74 74 2.16 Corrective Action Plan or Identification of Other Response Measures to be Taken to Remedy any Violation of Applicable Ground Water Quality Standards (R317-6-6.3.P) 75 2.16.1 Chloroform Investigation 7 5 2.16.2 Nitrate Investigation 76 2.17 Other Information Required by the Director (R317-6-6.3.Q) 2.17 .1 Chemical Inventory Report 2.17 .2 Southwest Hydrogeologic Investigation 79 79 79 2.18 This Application Performed Under the Direction of a Professional Engineer (R317-6- 6.3.R) 80 2.19 Closure and Post Closure Management Plan Demonstrating Measures to Prevent Ground Water Contamination During the Closure and Post Closure Phases of Operation (R17 -6-6.3.S) 80 2.19.1 Regulatory Requirements for Uranium Mills 80 2.19.1.1 Long Term Custodian 80 2.19 .1.2 Responsibility For And Manner Of Clean Up 80 2.19.1.3 Surface 81 2.19.1.4 Groundwater 81 2.19 .1.5 License Termination 82 2.19.2 Current Reclamation Plan 82 2.19.3 Provisions Included in the Permit Relating to the Mill's Reclamation Plan 83 2.19 .4 Post -Operational Monitoring 85 3.0 CONCLUSIONS 85 4.0 SIGNATURE AND CERTIFICATIONS 86 5.0 REFERENCES 87 4 1.0 INTRODUCTION 1.1 Background Energy Fuels Resources (USA) Inc.1 ("EFRI") operates the White Mesa Uranium Mill (the "Mill"), located approximately six miles south of Blanding, Utah, under State of Utah Ground Water Discharge Permit No. UGW 370004 (the "Permit" or "GWDP"). The Permit was originally issued by the Co-Executive Secretary of the Utah Water Quality Board on March 8, 2005, for 5 years, expiring on March 8, 2010, and was up for timely renewal in accordance with Utah Administrative Code ("UAC") R317-6-6.7. A renewal application was submitted September 1, 2009. At the request of the Director of the Utah Division of Radiation Control, EFRI submitted an updated version of the September 1, 2009 renewal application on July 13, 2012. At the request of the Director of the Utah Division of Radiation Control, EFRI is submitting this updated version of the July 2012 renewal application. Prior to July 1, 2012, the Director of the Utah Division of Radiation Control ("Director") was referred to as the Executive Secretary of the Utah Radiation Control and Board Co-Executive Secretary of the Utah Water Quality Board. Documents referenced in this Application, published prior to that date, refer to the Director, by one or both of these previous titles. In accordance with R317-6-6.7, this is an updated application (the "Application") to the Director for renewal of the Permit for another 5-years under R313-6-6.7. The Mill is also subject to State of Utah Radioactive Materials License No. UT 1900479 (the "Mill License"), which was issued on March 31, 19972 for 10-years and is currently in the process of timely renewal under R313-22-363, and State of Utah Air Quality Approval Order DAQE-AN0112050018-11 (the "Air Approval Order") which was re-issued on March 2, 2011 and is not up for renewal at this time. While the Mill License is referred to in this Application from time to time in order to allow the Director to better understand Mill operations and compliance with applicable regulatory requirements, this is not an application for renewal of the Mill License or Air Approval Order. 1.2 Applicable Standards for Review and Approval of this Application In accordance with discussions between EFRI and State of Utah Division of Radiation Control ("DRC") staff on April 1, 2014, this Application includes the information required under R317- 6-6.3. 1 Prior to July 25, 2012, Energy Fuels Resources (USA) Inc. was named "Denison Mines (USA) Corp ("Denison")". Prior to December 16, 2006, Denison was named "International Uranium (USA) Corporation." 2 The Mill License was originally issued by the United States Nuclear Regulatory Commission ("NRC") as a source material license under 10 CFR Part 40 on March 31, 1980. It was renewed by NRC in 1987 and again in 1997. After the State of Utah became an Agreement State for uranium mills in August 2004, the Mill License was re- issued by the Executive Secretary as a State of Utah Radioactive materials license on February 16, 2005, but the remaining term of the Mill License did not change. 3 A Mill License renewal application was submitted to the Executive Secretary on February 28, 2007, pursuant to R313-22-36. 5 In accordance with R317-6-6.4C, the Director may issue (or renew) a ground water discharge permit for an existing facility, such as the Mill, provided: a) The applicant demonstrates that the applicable class total dissolved solids ("TDS") limits, ground water quality standards and protection levels will be met; b) The monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; c) The applicant utilizes treatment and discharge minimization technology commensurate with plant process design capability and similar or equivalent to that utilized by facilities that produce similar products or services with similar production process technology; and d) There is no current or anticipated impairment of present and future beneficial uses of the ground water. This Permit Application demonstrates how ex1stmg facilities continue to meet applicable regulatory criteria and the monitoring strategies employed to prevent impairment of present and future beneficial uses of the groundwater. EFRI conducts various kinds of environmental monitoring at the White Mesa Mill including but not limited to groundwater, surface water, soil, sediment, tailings waste water, air, and vegetation. Specific groundwater monitoring activities employed are summarized below. Energy Fuels' ground water monitoring program is comprehensive in that it includes all of the 72 monitoring wells at the facility, as described above, although not every well is sampled every quarter. Samples are taken and analyzed for a large number of groundwater contaminants including heavy metals, nutrients, general chemistry analytes, radiologies, and volatile organic compounds ("VOCs"). Exceedences of standards found during this monitoring program have been addressed as described throughout this GWDP Application. Under the License, the Permit, and the Corrective Action Plans, EFRI has completed and is monitoring the 72 groundwater monitoring wells described below. • 27 monitoring wells placed to detect any leaks from the cells. Because the leak detection systems for Cells 1, 2, and 3 utilized older, less sophisticated technology, the DRC required eight new wells be installed adjacent to the tailings cells in 2005. These wells were to be used as a first line of defense to detect any tailings cell leakage. These supplemented the original seven required by NRC. An additional12 wells have been constructed in association with the construction of Cells 4A and 4B. • 34 monitoring wells associated with characterizing the chloroform groundwater contamination. • 12 monitoring wells associated with characterizing the nitrate groundwater contamination. The monitoring results for each well that is sampled are evaluated for compliance with standards for 38 different constituents and, regardless of whether standards are met, for trends in the data that may show a need for further action. 6 Four indicator parameters (chloride, uranium, fluoride, and sulfate) are used at the site to determine if there has been any cell leakage. These constituents were chosen because they are the most mobile and are expected to be seen first with any upward trend in consistent concentrations. If a cell were leaking, it is expected that all four parameters would show increasing trends within two years, based on Kd values and other transport characteristics for the contaminants and site. During a DRC split sampling event in May, 1999, excess chloroform concentrations were discovered in monitoring well MW -4, which is located along the eastern margin of the site. Because these concentrations were above the Utah Ground Water Quality Standard of 70 !lgiL, the DRC initiated enforcement action against EFRI on August 23, 1999 by issuing a Ground Water Corrective Action Order. The Order required completion of: 1) a contaminant investigation report to define and delineate boundaries for the contaminant plume, and 2) a groundwater corrective action plan to clean it up. Twenty new monitoring wells (since increased to 34 wells) were installed at the site as part of the investigation. Table 1.2-1 lists the 34 chloroform monitoring wells. The Director and EFRI determined that the laboratory wastewater sent to sewage leach fields, and not potential leaking from tailings cells, was the most likely source of the chlorof01m plume. As with every groundwater corrective action, the corrective action plan is developed based on assumptions about the source, and those assumptions are tested continuously with groundwater monitoring as corrective action proceeds. With DRC concurrence, EFRI began to pump chloroform contaminated groundwater in April, 2003. Groundwater monitoring results show this initial remediation effort has been effective based on reduction of contaminant concentrations. Reductions of the contaminant concentrations indicates both that the pumping program is working and that there is no continuous source for the contaminants, as would be the case if the cells were leaking. During a review of the EFRI April 30, 2008 New Wells Background Report and other EFRI reports, Nitrate +Nitrite (as N) (hereafter Nitrate) concentrations were observed above the Utah Ground Water Quality Standard (10 mg/L) in five monitoring wells in the mill site area. After the Nitrate Plume was identified, the Executive Secretary and EFRI entered into a January 28, 2009 Stipulated Consent Agreement that required EFRI to complete a Contaminant Investigation Report to determine the potential sources of the Nitrate contamination. Nineteen additional wells were installed to determine the extent of the contamination; nine of these wells have since been abandoned. Table 1.2-2 lists the current and former nitrate wells installed as part of the nitrate corrective actions. EFRI has submitted two reports to DRC regarding the elevated Nitrate concentrations. The reports identify the extent of the Nitrate plume but EFRI and DRC disagreed about what the reports indicated about the likely source of the plume. EFRI does not believe that the results adequately demonstrated an on-site source. 7 EFRI agreed to implement a corrective action plan to clean up the plume. EFRI completed and submitted the Nitrate Corrective Action Plan to the DRC on May 7, 2012. The Corrective Action Plan was approved following a public comment period, and was incorporated into a December 12, 2012 Stipulation and Consent Order, Docket Number UGW12-04. The approval is subject to conditions, stipulated penalties and timelines outlined in the Stipulation and Consent Order. The remediation plan requires EFRI to pump the groundwater and treat it by evaporation and/or use as process water. Pumping under the remediation plan began in January, 2013. Groundwater monitoring results show this initial remediation effort has been effective based on reduction of the plume mass to date. When the DRC began oversight of the Mill, it noted that ground water monitoring had showed elevated concentrations of metals, primarily uranium, in wells MW-3, MW-3A, MW-14, MW- 15, MW-22 on the Mill site. The DRC was concerned about whether the observations meant that tailings cells were leaking. To address its concerns, the DRC commissioned the University of Utah to investigate the elevated concentrations in July 2007. The University completed its study and published a report in May 2008 (the "2008 University Report"). After review of the 2008 University Report, the DRC determined that downgradient wells with elevated total uranium concentrations (including well MW -22) were not being impacted by potentially leaking tailings cells. This conclusion was based on at least three lines of isotopic evidence: 1. Tritium Signature. Wells MW-3, MW-3A, MW-14, MW-15, MW-22 had tritium signatures in groundwater at or below the limit of detection of 0.3 Tritium Units (2008 University Report p. 26). These values are more than an order of magnitude below the corresponding surface water results found in either the tailings cells or the wildlife ponds. This means that the groundwater in these five downgradient wells is older than water in the tailings cells, and is of a different origin than the tailings wastewater. 2. Stable Isotopes of Deuterium and Oxygen-18 in Water. The Deuterium and Oxygen-18 content of the groundwater matrix and tailings wastewater matrix was tested in all of the water sources studied. The 2008 University Report results showed that wells MW-3, MW- 3A, MW-14, MW-15, and MW-22, all downgradient wells with elevated uranium concentrations, had Deuterium and Oxygen-18 signatures that were almost twice as negative as any of the surface water results. (2008 University Report, p. 42.) This shows that groundwater in these downgradient wells had a different geochemical origin than the tailings cell wastewater. 3. Stable Isotopes on Dissolved Sulfate. The University Study evaluated two stable isotopes found in sulfate minerals dissolved in the water samples, Oxygen-18 and Sulfur-34. The evaluation showed that the sulfate solutes in groundwater from downgradient wells MW -3, MW-3A, MW-14, MW-15, and MW-22 had a different isotopic signature than the sulfate minerals dissolved in the tailings wastewater. In the case of Oxygen-18 in sulfate, the downgradient wells showed more negative values than the tailings cells wastewater. For Sulfur-34, the results were inversed, with groundwater showing more positive values than the 8 negative values seen in the tailings wastewater (2008 University Report p. 46.). This shows that the sulfate dissolved in the downgradient wells, with elevated uranium concentrations, has a different origin than the tailings wastewater. In summary, the University Study concluded that wells with high concentrations of metals (MW- 3, MW-14, MW-15, MW-18, and MW-22) bear very different isotopic fingerprints than those of the surface water sites (e.g. wildlife ponds, and tailings cells) (2008 University Report p. 58). Regarding uranium concentrations in well MW -22, the University Study stated that 11 •• .it does not appear that the elevated uranium values are the result of leakage from tailings cells .... 11 (2008 University Report p. 45). The 2008 University Report further theorized that the cause of the increasing contaminant concentrations on the site was artificial recharge from wildlife ponds constructed in 1995, described in Part 1.5.1. This recharge likely leached and mobilized natural uranium and other constituents as a result of new saturation of zones beneath the site that had previously been unsaturated. The Mill drained the wildlife ponds in 2012. As a result, the Mill meets the requirements set out in R317-6-6.4(c). This Application has been prepared under the direction, and bears the seal, of a professional engineer qualified to practice engineering before the public in the state of Utah and professionally registered as required under the Professional Engineers and Professional Land Surveyors Licensing Act rules (UAC 156-22). 1.3 Background Groundwater Reports and Re-opening of Permit In the December 1, 2004 Statement of Basis (the "2004 Statement of Basis") prepared by DRC in connection with the original issuance of the Permit, three monitoring wells (MW-14, MW-15, and MW-17) located downgradient of the Mill's tailings cells were found to have long-term increasing concentration trends for total uranium. These three wells and downgradient well MW-3, had total uranium concentrations above the Utah Ground Water Quality Standard ("GWQS"), found in UAC R317-6-2 (see the 2004 Statement of Basis, pp. 6-7). These findings were of concern to the DRC because they appeared to indicate that the tailings cells had possibly discharged wastewater into the underlying shallow aquifer. To resolve this concern, the Director required EFRI to evaluate groundwater quality data from the thirteen existing wells on site, and submit a Background Ground Water Quality Report for Director approval. The existing wells are those wells which were installed prior to the issuance of the original GWDP on March 8, 2005 and include: MW-1, MW-2, MW-3, MW-5, MW-11, MW-12, MW-14, MW-15, MW-17, MW-18, MW-19, MW-26 (formerly called TW4-15 and installed as part of the chloroform corrective action order), and MW-32 (formerly called TW4-17 and installed as part of the chloroform corrective action order). It is important to note that MW -4 was installed prior to the issuance of the original permit; however, MW -4 is monitored under the chloroform program and was not included in the Existing Background Report. GWCLs have not been established for this well, and MW -4 is not a POC well under the GWDP. One of the purposes of the background report was to provide a critical evaluation of historic groundwater quality data from the facility, and determine representative background quality conditions and reliable groundwater compliance limits ("GWCLs") for the Permit. 9 As required, EFRI submitted the following reports: • Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. (the "Existing Well Background Report"); and • Revised Addendum: --Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, November 16, 2007, prepared by INTERA, Inc. (the "Regional Background Report"). The Existing Well Background Report and the Regional Background Report included a detailed quality assurance evaluation of all existing groundwater quality data collected prior to the date of issuance for the thirteen existing wells, in accordance with criteria established by DRC and United States Environmental Protection Agency ("EPA") guidance. This resulted in a database suitable for statistical and other analyses. Based on an analysis of this updated database, the Existing Well Background Report and Regional Background Report concluded that there had been no impacts to groundwater from Mill activities, based on a number of factors, including the following: • There were a number of exceedances of GWQSs in upgradient and far downgradient wells at the site, which cannot be considered to have been impacted by Mill operations to date. Exceedances of GWQSs in monitoring wells nearer to the site itself are therefore consistent with natural background in the area. • There were numerous cases of both increasing and decreasing trends in constituents in upgradient, far downgradient, and Mill site wells, which provide evidence that there are natural forces at work that are impacting groundwater quality across the entire site. • In almost all cases where there were increasing trends in constituents in wells at the site, there were increasing trends in those constituents in upgradient wells. Furthermore, in no case was there any evidence in the wells in question of increasing trends in chloride, which is very mobile and a good indicator of potential tailings cell leakage at the site. See Section 2.11.2 below for a more detailed discussion of the Existing Well Background Report and Regional Background Report and their conclusions. The Permit also required nine new monitoring wells to be installed around tailings Cells 1 and 2, followed by groundwater sampling and analysis, and later submittal of another Background Ground Water Quality Report to determine reliable background conditions and groundwater compliance limits for the new wells. The new wells are those wells which were installed after the issuance of the original GWDP on March 8, 2005 and include: MW-3A, MW-23, MW-24, MW- 25, MW-27, MW-28, MW-29, MW-30, and MW-31. In response to this requirement, EFRI installed the nine new wells, and submitted to the Director a Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA, Inc. (the "New Well 10 Background Report"), and together with the Existing Well Background Report and the Regional Background Report, are referred to as the "Background Reports"). The New Well Background Report concluded that the sampling results for the new wells confirm that the groundwater at the Mill site and in the region is highly variable naturally and has not been impacted by Mill operations and that varying concentrations of constituents at the site are consistent with natural background variation in the area. See Section 2.11.2 below for a more detailed discussion of the New Well Background Report and its conclusions. During the course of discussions with EFRI staff, and further DRC review, DRC decided to supplement the analysis provided in the Background Reports by commissioning the University of Utah to perform a geochemical and isotopic groundwater study at White Mesa. This resulted in the University of Utah completing a study entitled Summary of work completed, data results, interpretations and recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, May 2008, prepared by T. Grant Hurst and D. Kip Solomon, Department of Geophysics, University of Utah (the "University of Utah Study"). The purpose of the University of Utah Study was to determine if the increasing and elevated trace metal concentrations (such as uranium) found in the monitoring wells at the Mill were due to potential leakage from the on-site tailings cells. To investigate this potential problem, the study examined groundwater flow, chemical composition, noble gas and isotopic composition, and age of the on-site groundwater. Similar evaluations were also made on samples of the tailings wastewater and nearby surface water stored in the northern wildlife ponds at the facility. Fieldwork for the University of Utah Study was conducted from July 17 -26 of 2007. The conclusions in the University of Utah Study supported EFRI's conclusions in the Background Reports As stated above, EFRI prepared Background Reports that evaluated all historic data for the thirteen existing wells and nine new wells for the purposes of establishing background groundwater quality at the site and developing GWCLs under the GWDP. Prior to review and acceptance of the conclusions in these Background Reports, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells and the nine new wells based primarily on the conclusions and analysis in the Background Reports. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. In addition to the thirteen existing wells and the nine new wells there are an additional 7 monitoring wells at the site which are included in the routine groundwater monitoring program. Those 7 wells are: MW-20, MW-22, MW-33, MW-34, MW-35, MW-36, and MW-37. The GWDP dated January 20, 2010 required the completion of eight consecutive quarters of groundwater sampling and analysis of MW-20 and MW-22, and later submittal of another 11 Background Report to determine if wells MW-20 and MW-22 should be added as point of compliance ("POC") monitoring wells. Data from MW-20 and MW-22 were analyzed in the pre- operational and regional background addendum (INTERA 2007a); however there was not a complete data set at the time. Although wells MW-20 and MW-22 were installed in 1994, they were not sampled regularly until the second quarter of 2008. The eighth full round of sampling was completed during the first quarter of 2010, and EFRI submitted to the Director the Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, June 1, 2010, prepared by INTERA, Inc. (the "MW-20 and MW-22 Background Report"). DRC classified MW-20 and MW-22 as general monitoring wells, and GWCLs have not been established for these wells. MW-20 and MW-22 are sampled semiannually. Part I.H.6 of the GWDP dated June 21, 2010 required the installation of three hydraulically downgradient wells adjacent to Tailings Cell 4B (MW-33, MW-34, and MW-35) prior to placement of tailings and/or wastewater in Cell 4B. The purpose of these monitoring wells was to provide early detection of tailings cell contamination of shallow groundwater from Tailings Cell 4B. EFRI installed MW-33, MW-34, and MW-35 as required. Of these three wells installed near tailings Cell4B, only MW-35 was hydraulically acceptable, with five feet or more of saturated thickness. MW-35 was sampled quarterly since fourth quarter 2010 to collect eight statistically valid data points for the completion of the Background Report and calculation of GWCLs. MW-33 and MW-34 had insufficient water for sampling, with saturated thicknesses less than five feet. MW-33 is completely dry, and no samples or depth to water measurements are collected from this well. Quarterly depth to water is measured in MW -34, but no sampling or analysis is required. Pmt I.H.4 of the February 15, 2011 GWDP required the installation of two wells hydraulically downgradient of Tailings Cell 4B as replacements for MW-33 and MW-34. EFRI installed MW-36 and MW-37 as required. MW-36 and MW-37 were sampled quarterly since third quarter 2011 to collect eight statistically valid data points for the completion of the Background Report and calculation of GWCLs. The Background Report for wells MW-35, MW-36, and MW-37 was submitted to the Director on May 1, 2014. The findings of the Background Analysis for wells MW-35, MW-36, and MW- 37 support previous conclusions that the groundwater at the Mill is not being affected by any potential tailings cell seepage. At the time of this application, EFRI was awaiting a response from the Director regarding the Background Report for wells MW-35, MW-36, and MW-37. 1.4 Documents Referenced in This Application The following documents are referenced in this Application. a) The following Permits, Licenses, Statement of Basis, Plans and Related Reports: (i) State of Utah Ground Water Discharge Permit No. UGW370004 dated August 24, 2012, (the "Permit") and previous versions of the Permit dated Janum·y 10, 2010, June 21, 2010, February 15, 2011, and July 14, 2011. 12 (ii) State of Utah Radioactive Materials License No. UT 1900479 (the "Mill License"); (iii) Statement of Basis For a Uranium Milling Facility at White Mesa, South of Blanding, Utah, Owned and Operated by International Uranium (USA) Corporation, December 1, 2004, prepared by the State of Utah Division of Radiation Control (the "2004 Statement of Basis"); (iv) Reclamation Plan White Mesa Mill Blanding, Utah, Source Material License No. SUA-1358 Docket No. 40-8681 Revision 3.2B, January 14, 2011 (the "Reclamation Plan"); and (v) UMETCO Minerals Corporation: White Mesa Mill Drainage Report for Submittal to NRC, January 1990; b) The following Background Groundwater Quality Reports and Related Studies: (i) Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp. 's White Mesa Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. (the "Existing Well Background Report"); (ii) Revised Addendum: --Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, November 16, 2007, prepared by INTERA, Inc. (the "Regional Background Report"); (iii) Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA, Inc. (the "New Well Background Report" and together with the Existing Well Background Report and the Regional Background Report, the "Background Reports"); and (iv) Summary of work completed, data results, interpretations and recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, May 2008, prepared by T. Grant Hurst and D. Kip Solomon, Department of Geophysics, University of Utah (the "University of Utah Study"); (v) Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, June 1, 2010, prepared by INTERA, Inc. (the "MW-20 and MW-22 Background Report"); 13 (vi) Background Groundwater Quality Report for Monitoring Wells MW-35, MW-36 and MW-37 White Mesa Mill Blanding, Utah, May 1, 2014, prepared by INTERA, Inc. (the "MW-35, MW-36, and MW-37 Background Report". c) The following environmental reports and analyses: (i) Environmental Report, White Mesa Uranium Project San Juan County, Utah, January 30, 1978, prepared by Dames & Moore (the "1978 ER"); and (ii) Final Environmental Statement related to operation of White Mesa Uranium Project Energy Fuels Nuclear, Inc., May 1979, Docket No. 40-8681, prepared by the United States Nuclear Regulatory Commission (the "FES"); d) The following engineering, geological and hydrogeological reports: (i) Umetco Groundwater Study, White Mesa Facilities, Blanding, Utah, 1993, prepared by Umetco Minerals Corporation (the operator of the Mill at the time) and Peel Environmental Services; (ii) Hydrogeological Evaluation of White Mesa Uranium Mill, July 1994, prepared by Titan Environmental Corporation (the "1994 Titan Report"); (iii) Evaluation of Potential for Tailings Cell Discharge-White Mesa Mill, November 23, 1998, prepared by Knight-Piesold LLC; (iv) Investigation of Elevated chlorofonn concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah, 2001, prepared by Hydro Geo Chern, Inc.; (v) Letter Report dated August 29, 2002, prepared by Hydro Geo Chern, Inc.; (vi) Hydrogeology White Mesa Uranium Mill Site Near Blanding, Utah, June 6, 2012, prepared by Hydro Geo Chern, Inc.; e) The following plans and specifications relating to construction and operation of the Mill's tailings cells: (i) Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah, June 1979, prepared by D' Appolonia Consulting Engineers, Inc.; (ii) Engineer's Report: Second Phase Design-Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah, May 1981, prepared by D' Appolonia Consulting Engineers, Inc.; 14 (iii) Construction Report: Initial Phase -Tailings Management System, White Mesa Uranium Project Blanding, Utah, February 1982, prepared by D' Appolonia Consulting Engineers, Inc.; (iv) Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project, March 1983, prepared by Energy Fuels Nuclear, Inc. (the operator of the Mill at the time); (v) Cell 4 Design, White Mesa Project Blanding, Utah, April 10, 1989, prepared by Umetco Minerals Corporation (the operator of the Mill at the time); (vi) Construction Report: Tailings Cell 4A, White Mesa Uranium Mill -Tailings Management System, August 2000, prepared by International Uranium (USA) Corporation (the operator of the Mill at the time); (vii) Cell 4A Lining System Design Report For The White Mesa Mill Blanding, Utah, January 2006, prepared by GeoSyntec Consultants; (viii) Cell4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah, July 2008, prepared by Geosyntec consultants; (ix) Cell 4B Design Report, White Mesa Mill, Blanding, Utah, December 8, 2007, prepared by Geosyntec Consultants; and (x) Cell 4B Construction Quality Assurance Report, Volumes 1-3, November 2010, prepared by Geosyntec Consultants. f) The following documents relating to the chloroform investigation at the site: Preliminary Corrective Action Plan, White Mesa Mill Near Blanding, Utah, August 20, 2007, prepared by Hydro Geo Chern, Inc.; (i) Contamination Investigation Report TW4-12 and TW4-27 Areas White Mesa Uranium Mill, Near Blanding Utah, January 23, 2014 prepared by Hydro Geo Chern, Inc.; g) The following documents relating to the pH and other Out of Compliance investigations at the site: (i) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the First, Second, Third and Fourth Quarters of 2010 and First Quarter 2011, June 13, 2011; (ii) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for 15 Constituents in the Second Quarter of 2011, September 7, 2011; (iii) Plan and Time Schedule for Assessment of pH Under Groundwater Discharge Permit UGW370004, April13, 2012 prepared by Hydro Geo Chern, Inc; (iv) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of2012, December 13, 2012; (v) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Fourth Quarter of2012, March 15, 2013; (vi) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the First Quarter of2013, August 28, 2013; (vii) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Second Quarter of2013, September 20, 2013; (viii) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part l.G.2 for Constituents in the Third Quarter of2013, December 5, 2013; (ix) Source Assessment Report, White Mesa Uranium Mill, Blanding Utah, October 10,2012 prepared by INTERA, Inc; (x) pH Report White Mesa Uranium Mill, Blanding Utah, November 9, 2012 prepared by INTERA, Inc; (xi) Investigatiof! of Pyrite in the Perched Zone, White Mesa Uranium Mill, Blanding Utah, December 7, 2012 prepared by Hydro Geo Chern, Inc; (xii) Source Assessment Report for TDS in MW-29, White Mesa Uranium Mill, Blanding Utah, May 7, 2013 prepared by INTERA, Inc; (xiii) Source Assessment Report for Selenium in MW-31, White Mesa Uranium Mill, Blanding Utah, August 30, 2013 prepared by INTERA, Inc; (xiv) Source Assessment Report for Tetrahydrofuran in MW-01, White Mesa Uranium Mill, Blanding Utah, December 17, 2013; prepared by INTERA, Inc. (xv) Source Assessment Report for Gross Alpha in MW-32, White Mesa Uranium Mill, Blanding Utah, January 13,2014 prepared by INTERA, Inc; 16 (xvi) Source Assessment Report for Sulfate in MW-01 and TDS in MW-03A, White Mesa Uranium Mill, Blanding Utah, March 19, 2014 prepared by INTERA, Inc; h) The following documents relating to the nitrate investigations at the site: (i) Stipulated Consent Agreement Docket No. UGW12-03 between Denison Mines (USA) Corp. and the Director of the Division of Radiation Control, July 12, 2012. (ii) Revised Tolling Agreement, Revision 3, between DUSA and the Director, Revision 2, dated August 21, 2011. (iii) Revised Phase 1 (A through C) Work Plan and Schedule for Phase 1 A -C Investigation, May 11, 2011, prepared by INTERA, Inc; (iv) Revised Phase 2 through 5 Work Plan and Schedule, June 3, 2011, prepared by INTERA, Inc; (v) Revised Phase 2 QAP and Work Plan, Revision 2.0, July 12, 2011; and (vi) Nitrate Corrective Action Plan, May 7, 2012, prepared by Hydro Geo Chern, Inc;. (vii) Nitrate Contamination Investigation Report, December 30, 2009, prepared by INTERA, Inc. 2.0 INFORMATION PROVIDED IN SUPPORT OF THE APPLICATION 2.1 Name and Address of Applicant and Owner (R317-6-6.3.A) The Applicant and Mill Operator is Energy Fuels Resources (USA) Inc. ("EFRI"). EFRI is the current holder of the Permit. The Mill is owned by EFRI' s affiliate, EFR White Mesa LLC ("EFRWM"). The address for both EFRI and EFRWM is: 225 Union Boulevard, Suite 600 Lakewood, CO 80228 Telephone: 303-974-2140 Fax: 303-389-4125 Contacts at EFRI, all located at the aforementioned office: Harold R. Roberts, Executive Vice President, and Chief Operating Officer. Direct telephone: 303-389-4160 hroberts @energyfuels.com 17 Frank J. Filas Vice President, Permitting and Environmental Affairs Direct telephone: 303-97 4-2146 ffilas @energyfuels.com Katherine A. Weinel Quality Assurance Manager Direct telephone: 303-389-4134 kweinel @energyfuels.com 2.2 Legal Location of the Facility (R317-6-6.3B) The Mill is regionally located in central San Juan County, Utah, approximately 6 miles (9.5 km) south of the city of Blanding. The Mill can be reached by taking a private road for approximately 0.5 miles west of Utah State Highway 191. See Figure 1. Within San Juan County, the Mill is located on fee land and mill site claims, covering approximately 5,415 acres, encompassing all or part of Sections 21, 22, 27, 28, 29, 32, and 33 of T37S, R22E, and Sections 4, 5, 6, 8, 9, and 16 of T38S, R22E, Salt Lake Base and Meridian ("SLBM"). See Figure 2. All operations authorized by the Mill License are conducted within the existing site boundary. The milling facility currently occupies approximately 50 acres, and the tailings disposal cells encompass another 250 acres. See Figure 2. 2.3 Name and Type of Facility (R317-6-6.3.C) The name of the facility is the White Mesa Uranium Mill. The facility is a uranium milling and tailings disposal facility, which operates under a Radioactive Materials License issued by the Director of the Utah Division of Radiation Control under UAC R313-24. In addition to uranium in the form of U30 8, the Mill also produces vanadium, in the form of vanadium pentoxide ("V 2Q 5 .. ), ammonia metavanadate ("AMV") and vanadium pregnant liquor ("VPL"), from certain conventional ores and has produced other metals from certain alternate feed materials (specifically niobium and tantalum as authorized under NRC license amendment number 4, included as Appendix A). Alternate feed materials are uranium bearing materials other than conventionally mined ores. Construction of the Mill was completed and first operations commenced in May 1980. The Mill does not have a set operating life, and can operate indefinitely, subject to available tailings capacity and license and permit renewals. The conceptual and permitted total capacity is for the quantity of Mill tailings produced from a 15-year operating period at a rate of 2,000 tons per day, operating 340 days per year. Since it commenced operations in 1980, the Mill has operated on a campaign basis, processing conventional ores and alternate feed materials as they become available and as economic conditions warrant. 18 2.4 A Plat Map Showing All Water Wells, Including The Status And Use Of Each Well, Drinking Water Source Protection Zones, Topography, Springs, Water Bodies, Drainages, And Man-Made Structures Within A One-Mile Radius Of The Discharge. (R317-6-6.3.D) There are five deep wells within a one mile radius of the Mill, two of which supply the Mill facility. There are no Drinking Water Source Protection Zones or ordinances within this radius. Routine groundwater monitoring wells have been established for monitoring under the Permit. These monitoring wells are depicted on Figure 10 and in Appendix B to this Application. The depth and purpose of each of these wells is as shown in Tables 1.2-1, 1.2-2, and 2.4-1. See Section 2.9.1.3 below for a detailed description of the Mill's groundwater monitoring program. The surface topography and man-made structures are shown on Figures presented in Appendix B. See Sections 2.5.4 and 2.5.7 below for a more detailed discussion on local topography and land use. The Mill area has several dry drainages, and the only nearby natural water bodies within one mile are Westwater Creek, Corral Creek and Cottonwood Creek. In addition to these are Ruin Spring and several other springs and seeps located within a 1.5 mile radius of the Mill. See Sections 2.5.3 and 2.13 below for discussions relating to seeps and springs in the vicinity of the site and to surface water and drainages, respectively. 2.5 Geologic, Hydrologic, and Agricultural Description of the Geographic Area (R317 -6-6.3.E) 2.5.1 Groundwater Characteristics This Section is based on the Report entitled: Hydrogeology of the White Mesa Uranium Mill, Blanding Utah June 6, 2014, prepared by Hydro Geo Chern, Inc. ("HGC") (the "2014 HGC Report" referred to as HGC, 2014). 2.5.1.1 Geologic Setting The Mill is located within the Blanding Basin of the Colorado Plateau physiographic province. Typical of large portions of the Colorado Plateau province, the rocks underlying the site are relatively undeformed. The average elevation of the site is approximately 5,600 ft (1,707 m) above mean sea level ("amsl"). The site is underlain by unconsolidated alluvium and indurated sedimentary rocks consisting primarily of sandstone and shale. The indurated rocks are relatively flat lying with dips generally less than 3°. The alluvial materials consist mostly of aeolian silts and fine-grained aeolian sands with a thickness varying from negligible to as much as 25 to 30 feet across the site. In some portions of the site the alluvium is underlain by a few feet to as much as 30 feet of Mancos Shale. In other areas, the Mancos Shale is absent. The alluvium and Mancos (where present) are underlain by the Dakota Sandstone and Burro Canyon Formation, which are sandstones having a combined total thickness ranging from approximately 55 to 140 feet (17 to 43 m). Beneath the Burro Canyon Formation lies the Morrison Formation, consisting, in descending order, of the Brushy Basin Member, the Westwater Canyon Member, the Recapture Member, and the Salt Wash Member. The Brushy Basin and Recapture Members of the Morrison Formation, classified 19 as shales, are very fine-grained and have a very low permeability. The Brushy Basin Member is primarily composed of bentonitic mudstone, siltstone, and claystone. The Westwater Canyon and Salt Wash Members are primarily sandstones but are expected to have a low average vertical permeability due to the presence of interbedded shales. See Figure 3 for a generalized stratigraphic column for the region. Beneath the Morrison Formation lies the Summerville Formation, an argillaceous sandstone with interbedded shales, and the Entrada Sandstone. Beneath the Entrada lies the Navajo Sandstone. The Navajo and Entrada Sandstones constitute the primary aquifer in the area of the site. The Entrada and Navajo Sandstones are separated from the Burro Canyon Formation by approximately 1,000 to 1,100 feet (305 to 355 m) of materials having a low average vertical permeability. Groundwater within this system is under artesian pressure in the vicinity of the site, is of generally good quality, and is used as a secondary source of water at the site. 2.5.1.2 Hydrogeologic Setting The site is located within a region that has a dry to arid continental climate, with average annual precipitation of approximately 13.3 inches, and an average annual lake evaporation rate of approximately 47.6 inches. Recharge to the principal aquifers (such as the Navajo/Entrada) occurs primarily along the mountain fronts (for example, the Henry, Abajo, and La Sal Mountains), and along the flanks of folds such as Comb Ridge Monocline. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth of the aquifer (approximately 1,200 feet below land surface [ft bls]) makes access difficult. The Navajo/Entrada aquifer is capable of yielding significant quantities of water to wells (hundreds of gallons per minute [gpm]). Water in on-site wells completed within the Navajo/Entrada rises approximately 800 feet above the base of the overlying Summerville Formation. The shallowest groundwater beneath the site consists of perched water hosted primarily by the Burro Canyon Formation. Perched water is used on a limited basis to the north (upgradient) of the site because it is much shallower and more easily accessible than the deep Navajo/Entrada aquifer. 2.5.1.3 Perched Zone Hydrogeology Perched groundwater originates mainly from precipitation and local recharge sources such as unlined reservoirs (Kirby, 2008) and is supported within the Burro Canyon Formation by the underlying, fine-grained Brushy Basin Member. Perched groundwater at the site is generally of poor quality due to high total dissolved solids ("TDS") in the range of approximately 1,100 to 7,900 milligrams per liter ("mg/L"). Its relatively poor quality is one reason that perched water is used primarily for stock watering and irrigation in areas up gradient (north) of the site. Figure 4 is a contour map showing the approximate elevation of the contact of the Burro Canyon Formation with the Brushy Basin Member, which essentially forms the base of the perched water zone at the site. Based on Figure 4, the Burro Canyon Formation/Brushy Basin Member contact generally dips to the south/southwest beneath the site. 20 Figure 5 is a perched groundwater elevation contour map for the first quarter, 2014. Based on the contoured water levels, groundwater within the perched zone flows generally south to southwest beneath the site. Beneath the tailings cells, perched groundwater flow is generally to the southwest. Perched groundwater discharges from outcrops of the Burro Canyon Formation in seeps and springs along Westwater Creek Canyon and Cottonwood Canyon (to the west-southwest of the mill site and tailings cells) and along Corral Canyon (to the east and northeast of the mill site and tailings cells). Known discharge points include the seeps and springs shown in Figure 5 except Cottonwood Seep. As discussed in (HGC, 2014), Cottonwood Seep is located more than 1,500 feet west of White Mesa in an area where the Dakota Sandstone and Burro Canyon Formation (which hosts the perched water system) are absent due to erosion, and at an elevation approximately 230 feet below the base of the perched zone defined by the contact between the Burro Canyon Formation and the underlying Brushy Basin Member. Cottonwood Seep occurs near the contact between the slope-forming Brushy Basin Member and the underlying Westwater Canyon (sandstone) Member. Contact elevations shown in Figure 4 are based on perched monitoring well drilling and geophysical logs and surveyed land surface elevations, and the surveyed elevations of Westwater Seep and Ruin Spring. The elevations of Westwater Seep and Ruin Spring are included in the kriged contours because they occur at the contact between the Burro Canyon Formation and the underlying Brushy Basin Member. Groundwater elevations shown in Figure 5 include the surveyed elevations of all seeps and springs except Cottonwood Seep. As discussed above, no evidence exists to connect Cottonwood Seep to the perched water system. Although Cottonwood Seep may potentially receive some contribution from perched water, its occurrence near the contact between the Brushy Basin Member and the underlying Westwater Canyon Member indicates that its elevation is not representative of the perched water system. The permeabilities of the Dakota Sandstone and Burro Canyon Formation at the site are generally low. No significant joints or fractures within the Dakota Sandstone or Burro Canyon Formation have been documented in any wells or borings installed across the site (Knight Piesold, 1998). Any fractures observed in cores collected from site borings are typically cemented, showing no open space. Porosities and water contents of the Dakota Sandstone have been measured in samples collected during installation of former well MW-16 and well MW-17 (Figure 5). MW-16 was located immediately downgradient of tailings Cell 3 and MW -17 is located south of tailings Cell 4A at a location primarily cross-gradient with respect to perched water flow. Porosities of the Dakota Sandstone range from 13.4% to 26%, averaging 20%, and water saturations range from 3.7% to 27.2%, averaging 13.5%. The average volumetric water content is approximately 3%. The hydraulic conductivity of the Dakota Sandstone based on packer tests in borings installed at the jte prior to 1994 ranges from 2.71 x 10-6 centimeters per second ("cm/s") to 9.12x 10-4 cm/s, with· a geomelric average of 3.89 x 10-5 cm/s (TITAN, 1994). 21 The average porosity of the Burro Canyon Formation is similar to that of the Dakota Sandstone. Based on samples collected from the Burro Canyon Formation at former well MW-16 porosity ranges from 2% to 29.1 %, averaging 18.3%, and water saturations of unsaturated materials range from 0.6% to 77.2%, averaging 23.4% (TITAN, 1994). These porosities are similar to those reported by MWH (MWH, 2010) for archived samples from borings MW-23 and MW-30. Extensive hydrogeologic characterization of the saturated Burro Canyon Formation has occurred through hydraulic testing of perched monitoring wells and borings at the site. Hydraulic testing of MW -series wells located up gradient, cross-gradient, downgradient, and within the millsite and tailings cell complex, TW 4-series wells located cross-gradient to up gradient of the millsite and tailings cells, TWN-series wells located primarily upgradient of the millsite and tailings cells, and DR-series piezometers, located downgradient of the tailings cells, indicate that the hydraulic conductivity of the perched zone ranges from approximately 2 x 10-8 to 0.01 cm/s. TITAN (1994), reported that the hydraulic conductivity of the Burro Canyon Formation ranges from 1.9 x 10-7 to 1.6 x 10 -3 cm/s, with a geometric mean of 1.01 x 10-5 cm/s, based on the results of 12 pumping/recovery tests performed in monitoring wells and 30 packer tests performed in borings prior to 1994. The range reported by TIT AN ( 1994) is within the hydraulic conductivity range of approximately 2 x 10-8 to 0.01 cm/s reported by HGC (HGC, 2014). In general the highest permeabilities and well yields are in the area of the site immediately northeast and east (upgradient to cross gradient) of the tailings cells. A relatively continuous, higher permeability zone (associated with poorly indurated coarser-grained materials in the general area of the chloroform plume) has been inferred to exist in this portion of the site. Analysis of drawdown data collected from this zone during long-term pumping of MW-4, MW- 26 (TW4-15), and TW4-19 (Figure 5) yielded estimates of hydraulic conductivity ranging from approximately 4 X 10-5 to 1 X 10-3 cm/s (HGC, 2014). The decrease in perched zone permeability south to southwest of this area (south of TW4-4), based on tests at TW4-6, TW4-26, TW4-27, TW4-29 through TW4-31, and TW4-33 and TW4-34, indicates that this higher permeability zone "pinches out". Relatively high conductivities measured at MW-11, located on the southeastern margin of the downgradient edge of tailings Cell 3, and at MW-14, located on the downgradient edge of tailings Cell4A, of 1.4 x 10-3 cm/s and 7.5 x 10-4 cm/s, respectively, may indicate that this higher permeability zone extends beneath the southeastern portion of the tailings cell complex. However, based on hydraulic tests south and southwest of these wells, this zone of higher permeability does not appear to exist within the saturated zone downgradient (south-southwest) of the tailings cells. Slug tests performed at groups of wells and piezometers located northeast (upgradient) of, in the immediate vicinity of, and southwest (downgradient) of the tailings cells indicate generally lower permeabilities compared with the area of the chloroform plume. The following results are based on analysis of automatically logged slug test data using the KGS solution available in AQTESOL VE (HydroSOLVE, 2000). Testing of TWN-series wells installed in the northeast portion of the site as part of nitrate investigation activities yielded a hydraulic conductivity range of approximately 3.6 x 10-7 to 0.01 22 cm/s, with a geometric average of approximately 6 x 10-5 cm/s. The value of 0.01 cm/s estimated for TWN-16 is the highest measured at the site, and the value of 3.6 x 10-7 cm/s estimated for TWN-7 is one of the lowest measured at the site. Testing of MW-series wells MW-23 through MW-32 jn tl.l lled between and at the margins of the tailing ce1l i11 2005 (a.nd using the higher estimate f, r MW-23) yie lded a bydrallJic condu tivi ty r~oe of npproxim·1tely 2 x 10-7 to 1 x 10-4 cm/s with a geometric average f approximately 2 x w-emf . Hydraulic test onducted at DR- eries pj ez meteJ. in talJed as part of the southwest area investigation downgradient of the taiJring · cell yielded hydraulic conductivities ranging from approximately 2 x 10-8 to 4 x 10-4 emf with a geometric average of 9.6 x 10-6 cm/s. The low permeabilities and shallow hydraulic gradients downgradient of the tailings cells result in average perched groundwater pore velocity estimates that are among the lowest on site (approximately 0.26 feet per year (ft/yr) to 0.91 ft/yr). The extensive hydraulic testing of perched zone wells at the site indicates that perched zone permeabilities are generally low with the exception of the apparently isolated zone of higher permeability associated with the chloroform plume east to northeast (cross-gradient to upgradient) of the tailings cells. The geometric average hydraulic conductivity (approximately 1 x 10-5 cm/s) of the DR-series piezometers which cover an area nearly half the size of the total monitored area at White Mesa (excluding MW-22), is nearly identical to the geometric average hydraulic conductivity of 1.01 x 10-5 cm/s reported by TITAN (1994), and is within the range of 5 to 10 feet per year (ft/yr) [approximately 5 x 10-6 cm/s to 1 x 10-5 cm/s] reported by Dames and Moore (1978) [the 1978 ER] for the (saturated) perched zone during the initial site investigation. Because of the generally low permeability of the perched zone beneath the site, well yields are typically low (less than 0.5 gpm), although sustainable yields of as much as 4 gpm (for example, at TW4-19, shown in Figure 5) are possible in wells intercepting the relatively large saturated thicknesses within the higher permeability zone located east to northeast (cross-gradient to upgradient) of the tailings cells at the site. Sufficient productivity can generally be obtained only in areas where the saturated thickness is greater, which is one reason that 1) some perched zone wells completed near the northern wildlife ponds are relatively productive and 2) the perched zone has been used on a limited basis as a water supply to the north (upgradient) of the site. 2.5.1.4 Perched Groundwater Flow Perched groundwater flow at the site has historically been to the south/southwest. Figure 5 groundwater elevations indicate that beneath and south of the tailings cells, in the west central portion of the site, perched water flow is south-southwest to southwest. Flow on the western margin of White Mesa is generally south, approximately parallel to the mesa rim (where the Burro Canyon Formation [and perched zone] is terminated by erosion). On the eastern side of the site, perched water flow is also generally southerly. Near the wildlife ponds, flow direction ranges locally from westerly (west of the ponds) to easterly (east of the ponds) resulting in a generally north-south perched water divide along a line connecting the ponds. Cones of depression result from pumping of chloroform wells MW-4, TW4-4, TW4-19, TW4-20, and MW-26 and nitrate wells TWN-02, TW4-22, TW4-24, and TW4-25. These wells are pumped to reduce chloroform and nitrate mass in the perched zone east and northeast of the tailings cells. 23 In general, perched groundwater elevations have not changed significantly at most of the site monitoring wells since installation, except in the vicinity of the wildlife ponds and the pumping wells. For example, relatively large increases in water levels occurred between 1994 and 2002 at MW-4 and MW-19, located in the east and northeast portions of the site. These water level increases in the northeastern and eastern portions of the site are the result of seepage from wildlife ponds located near piezometers PIEZ-1 through PIEZ-5 shown in Figure 5, which were installed in 2001 for the purpose of investigating these changes. The mounding associated with the wildlife ponds and the general increase in water levels in the northeastern portion of the/ site have resulted in a local steepening of groundwater gradients over portions of the site. Conversely, pumping of chloroform wells MW-4, TW4-4, TW4-19, TW4-20, and MW-26 and nitrate wells TWN-02, TW4-22, TW4-24, and TW4-25 has depressed the perched water table locally and reduced average hydraulic gradients to the south and southwest of these wells. At the request of DRC, water has not been delivered to the northern wildlife ponds since March, 2012. The perched water mound associated with recharge from these ponds is diminishing and is expected to continue to diminish, thereby reducing hydraulic gradients downgradient of the ponds, in particular to the south and southwest. As discussed above, perched water discharges in springs and seeps along Westwater Creek Canyon and Cottonwood Canyon to the west-southwest of the site, and along Corral Canyon to the east of the site. The known discharge points located directly downgradient of the tailings cells are Westwater Seep and Ruin Spring. These features are located more than 2,000 feet west- southwest and more than 9,000 feet south-southwest of the tailings cells at the site as shown in Figure 5. DR-8, located approximately 4,000 feet southwest of the tailings cells, is located near the mesa rim above Cottonwood Seep along a line between the tailings cells and Cottonwood Seep. There is no evidence to connect Cottonwood Seep to the perched water system as it is separated from the perched water by approximately 230 feet of low permeability shales and mudstones. However, under hypothetical conditions that Cottonwood Seep receives some contribution from perched water, perched water passing beneath the tailings cells would presumably pass by DR-8 before continuing on an unidentified potential pathway toward Cottonwood Seep. Figure 5 shows perched water pathlines southwest of the tailings cells based on first quarter, 2014 perched water level data. Paths 1 and 3 represent the shortest pathlines to discharge points Westwater Seep and Ruin Spring, respectively. Path 2 is the shortest pathline to DR-8, located near the edge of the mesa above Cottonwood Seep. A potential pathline is drawn from DR-8 to Cottonwood Seep. Although there is no evidence to connect Cottonwood Seep to the perched water system, this potential pathline is represented to allow for the possibility of an as yet unidentified connection. Westwater Seep is downgradient of tailings Cell 1 and the western portions of Cells 2, 3, and 4B. DR-8 is downgradient of tailings Cells 2, 3 and 4B. Ruin Spring is downgradient of Cell4A, and the eastern portions of Cells 2, 3, and 4B. 2.5.1.5 Perched Zone Hydrogeology Beneath And Down gradient Of The Tailings Cells The perched zone hydrogeology southwest (downgradient) of the tailings cells is similar to other areas of the site except that the saturated thicknesses are generally smaller, portions of the perched zone are dry, and hydraulic gradients and hydraulic conductivities are relatively low. 24 The combination of shallow hydraulic gradients, relatively low permeabilities, and small saturated thicknesses, results in rates of perched water movement that are among the lowest on- site. In the immediate vicinity of the tailings cells, perched water was encountered at depths of approximately 53 to 117ft below the top of casing ("btoc") as of the first quarter of 2014 (Figure 7). Beneath tailings Cell 3, depths to water ranged from approximately 67 feet in the eastern portion of the cell, to approximately 117 ft btoc at the southwest margin of the cell. Assuming an average depth of the base of tailings Cell 3 of 25 feet below grade, this corresponds to perched water depths of approximately 42 to 92 feet below the base of the cell, and an average depth of approximately 65 feet beneath the base of the cell. Beneath tailings Cell 4B, depths to water ranged from approximately 106 ft btoc in the northeastern portion of the cell (at MW-5), to approximately 112ft btoc at the southwest margin of the cell (at MW-35). Assuming an average depth of the base of tailings Cell 4B of 25 feet below grade, this corresponds to perched water depths of approximately 81 to 87 feet below the base of the cell, and an average depth of approximately 84 feet beneath the base of the cell. The saturated thickness of the perched zone in the immediate vicinity of the tailings cells as of the first quarter of 2014 ranges from approximately 80 feet to negligible (Figure 8). Beneath tailings Cell 3, the saturated thickness varies from approximately 60 feet in the eastern portion of the cell to approximately 7 feet in the western portion of the cell. Beneath tailings Cell 4B, the saturated thickness varies from approximately 21 feet in the southeastern portion of the cell to negligible in the southwestern portion of the cell, where a dry zone, defined by MW-33 and former (his tori call y dry) well MW -16, is present. Saturated thicknesses in the southwest area of the site are affected by the ridge-like high in the Burro Canyon Formation/Brushy Basin Member contact (see Figure 4). As shown in Figures 5 and 8, dry to low saturated thickness conditions are associated with this paleoridge. South-southwest of the tailings cells, the saturated thickness ranges from negligible at MW-21 (historically dry) to approximately 25 feet at DR-9. Small saturated thicknesses (less than 3 feet) near DR-6, DR-7, and DR-9 (west and southwest of Cell 4B) result from the paleoridge. The average saturated thickness based on measurements at MW-37, DR-13, MW-3, MW-20, and DR-21, which lay close to a line between the southeast portion of tailings Cell 4B and Ruin Spring, is approximately 8 feet. The average saturated thickness based on measurements at MW- 35, DR-7, and DR-6, which are the points closest to a line between the southeast portion of tailings Cell 3 and Westwater Seep, is approximately 5 feet. Perched zone hydraulic gradients currently range from a maximum of approximately 0.075 feet per foot ("ft/ft") east of tailings cell 2 (near the eastern portion of the chloroform plume) to approximately 0.0022 ft/ft in the northeast corner of the site (between TWN-19 and TWN-16). Hydraulic gradients in the southwest portion of the site are typically close to 0.01 ft/ft, but the gradient is less than 0.005 ft/ft west/southwest of tailings Cell 4B, between Cell 4B and DR-8. The overall average site hydraulic gradient, between TWN-19 in the extreme northeast to Ruin Spring in the extreme southwest, is approximately 0.011 ft/ft. A hydraulic gradient between the 25 west dike of tailings Cell 3 and Westwater Seep is approximately 0.0122 ft/ft, and between the south dike of tailings Cell4B and Ruin Spring, approximately 0.0118 ft/ft 2.5.2 Groundwater Quality 2.5.2.1 Entrada/Navajo Aquifer The Entrada and Navajo Sandstones are prolific aquifers beneath and in the vicinity of the site. Water supply wells at the site are screened in both of these units, and therefore, for the purposes of this discussion, they will be treated as a single aquifer. Water in the Entrada/Navajo Aquifer is under artesian pressure, rising 800 to 900 ft above the top of the Entrada's contact with the overlying Summervillle Formation; static water levels are 390 to 500 ft below ground surface. Within the region, this aquifer is capable of yielding domestic quality water at rates of 150 to 225 gpm, and for that reason, it serves as a secondary source of water for the Mill. Additionally, two domestic water supply wells drawing from the Entrada/Navajo Aquifer are located 4.5 miles southeast of the Mill site on the Ute Mountain Ute Reservation. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth of the aquifer (>1,000 ft bls) makes access difficult. Table 2.5.2.1-1 is a tabulation of groundwater quality of the Navajo Sandstone aquifer as reported in the FES and subsequent sampling. TDS ranges from 244 to 1,110 mg/liter in three samples taken over a period from January 27, 1977, to May 4, 1977. High iron (0.057 mg/liter) concentrations are found in the Navajo Sandstone. Because the Navajo Sandstone aquifer is isolated from the perched groundwater zone by approximately 1,000 to 1,100 ft of materials having a low average vertical permeability, sampling of the Navajo Sandstone is not required under the Mill's previous NRC Point of Compliance monitoring program or under the Permit. However, samples were taken at two other deep aquifer wells (#2 and #5) on site (See Figure 9 for the locations of these wells), on June 1, 1999 and June 8, 1999, respectively, and the results are included in Table 2.5.2.1-1. 2.5.2.2 Perched Groundwater Zone Perched groundwater in the Dakota/Burro Canyon Formation is used on a limited basis to the north (upgradient) of the site because it is more easily accessible. The quality of the Burro Canyon perched water beneath and downgradient from the site is poor and extremely variable. The concentrations of TDS measured in water sampled from upgradient and downgradient wells range between approximately 600 and 5,300 mg/1. Sulfate concentrations measured in three upgradient wells varied between 670 and 1,740 mg/1 (Titan, 1994). The perched groundwater therefore is used primarily for stock watering and irrigation. The saturated thickness of the perched water zone generally increases to the north of the site. See Section 2.11.2 below for a more detailed discussion of background ground water quality in the perched aquifer. 2.5.3 Springs and Seeps As discussed in Section 2.5.1.4, perched groundwater at the Mill site discharges in springs and seeps along Westwater Creek Canyon and Cottonwood Canyon to the west-southwest of the site, and along Corral Canyon to the east of the site, where the Burro Canyon Formation outcrops. 26 Water samples have been collected and analyzed from springs and seeps in the Mill vicinity as part of the baseline field investigations reported in the 1978 ER (See Table 2.6-6 in the 1978 ER). During the period 2003-2004, EFRI implemented a sampling program for seeps and springs in the vicinity of the Mill which had been sampled in 1978, prior to the Mill's construction. Four locations were designated for sampling, as shown on Figure 9. These are Ruin Spring (G3R), Cottonwood Seep (G4R), west of Westwater Creek (G5R) and Corral Canyon (G1R). During the 2-year study period only two of the four locations could be sampled, Ruin Spring and Cottonwood Canyon. The other two locations, Corral Creek and the location west of Westwater Creek were not flowing (seeping), and samples could not be collected. With regard to the Cottonwood seep, while water was present, the volume was not sufficient to complete all determinations, and only organic analyses were conducted. Analysis of the Cottonwood Seep water samples did not detect any organics. Samples at Ruin Spring were analyzed for major ions, physical properties, metals, radionuclides, volatile and semi-volatile organic compounds, herbicides and pesticides, and synthetic organic compounds. With the exception of one chloromethane detection, all organic determinations were at less than detectable concentrations. The detection of chloromethane is not uncommon in groundwater and can be due to natural sources. In fact, chloromethane has been observed by EFRI at detectable concentrations in field blank samples during routine groundwater sampling events. The results of sampling for the other parameters tested are shown in Table 2.5.3-1. The results of the 2003/2004 sampling did not indicate the presence of mill derived groundwater constituents and are representative of background conditions. As required by Part I.E.6 of the Permit, the Mill has implemented a Sampling Plan for Seeps and Springs. Per Part I.E.6 of the Permit, sampling of seeps and springs in required annually. A copy of the approved Sampling Plan for Seeps and Springs Revision 1, dated June 10, 2011, is included as Appendix C to this Application. EFRI submitted Revision 1.0 on June 10, 2011. Revision 1.0 is currently undergoing review by the Director. See Section 2.12.2 below for a more detailed description of the Plan. The first sampling under the Plan was completed in August, 2009. A summary of sampling results from the 2009through 2013 sampling events, performed under the approved Sampling Plan for Seeps and Springs, is provided in Table 2.5.3-2 through Table 2.5.3-5. 2.5.4 Topography The Mill site is located on a gently sloping mesa that, from the air, appears similar to a peninsula, as it is surrounded by steep canyons and washes and is connected to the Abajo Mountains to the north by a narrow neck of land. On the mesa, the topography is relatively flat, sloping at less than one (1) percent to the south and nearly horizontal from east to west. See also Figure 6. 2.5.5 Soils The majority (99%) of the soil at the Mill site consists of the Blanding soil series (1978 ER, Section 2.1 0.1.1 ). The remaining 1% of the site is in the Mellenthin soil series. Because the 27 Mellenthin soil occurs only on the eastern-central edge of the site (1978 ER, Plate 2.10-1), the FES (Section 2.8) concluded that it should not be affected by Mill construction and operation. The Mill and associated tailings cells are located on Blanding silt loam, a deep soil formed from wind-blown deposits of fine sands and silts. Although soil textures are predominantly silt loam, silty-clay-loam textures are found at some point in most profiles (See Appendix D to this Application-Results of Soil Analysis at Mill Site). This soil generally has a 4 to 5 inch reddish- brown, silt-loam A horizon and a reddish-brown, silt-loam to silty-clay-loam B horizon. The B horizon extends downward about 12 to 16 inches where the soil then becomes calcareous silt- loam or silty-clay-loam, signifying the C horizon. The C horizon and the underlying parent material are also reddish-brown in color. The A and B horizon both are non-calcareous with an average pH of about 8.0, whereas the C horizon is calcareous with an average pH of about 8.5. Subsoil sodium levels range up to 12% in some areas, which is close to the upper limit of acceptability for use in reclamation work (1978 ER, Sect. 2.1 0.1.1). Other elements, such as boron and selenium, are well below potentially hazardous levels. Potassium and phosphorus values are high in this soil (1978 ER, Table 2.10-2) and are generally adequate for plant growth. Nitrogen, however, is low (1978 ER, Sect. 2.10.1.1) and may have to be provided for successful revegetation during final reclamation. With well-drained soils, relatively flat topography (see Section 2.5.4), and limited annual precipitation (see Section 2.5.1.2), the site generally has a low potential for water erosion. However, the flows resulting from thunderstorm activity are nearly instantaneous and, without the Mill's design controls, could result in substantial erosion. When these soils are barren, they are considered to have a high potential for wind erosion. Although the soil is suitable for crops, the low percentage of available moisture (6 to 9%) is a limiting factor for plant growth; therefore, light irrigation may be required to establish native vegetation during reclamation. 2.5.6 Bedrock Subsurface conditions at the Mill site area were investigated as part of the 1978 ER by drilling, sampling, and logging a total of 28 borings which ranged in depth from 6.5 to 132.4 ft. Of these borings, 23 were augured to bedrock to enable soil sampling and estimation of the thickness of the soil cover. The remaining 5 borings were drilled through bedrock to below the perched water table, with continuous in situ permeability testing where possible and selective coring in bedrock. The soils encountered in the borings were classified, and a complete log for each boring was maintained. See Appendix A of Appendix H of the 1978 ER. Borings in the footprint of the existing tailings cells reported calcareous, red-brown sands and silts from the surface to a depth of 15 ft, averaging over 7 ft. Borings in the general area of the Mill site and the tailings cells reported calcareous, red-brown sands and silts from the surface to a depth of 14 ft, averaging over 9 ft. Downgradient of the tailings cells, calcareous sands and silts extend to a depth of 17 ft of the surface. The calcareous silts and sands of the near-surface soils grade to weathered claystones or weathered sandstones, inter-layered with weathered claystone and iron staining. At depth, the weathered claystone or weathered clayey sandstone grade into sandstone with inter-layered bands of claystone, gravel, and conglomerate. Some conglomerates are cemented with a calcareous matrix. 28 2.5.7 Agricultural and Land Use Description of the Area Approximately 65.8% of San Juan County is federally owned land administered by the U.S. Bureau of Land Management, the National Park Service, and the U.S. Forest Service. Primary land uses include livestock grazing, wildlife range, recreation, and exploration for minerals, oil, and gas. Approximately 22% of the county is Native American land owned either by the Navajo Nation or the Ute Mountain Ute Tribe. The area within 5 miles of the Mill site is predominantly range land owned by residents of Blanding. The Mill site itself, including tailings cells, encompasses approximately 300 acres. A more detailed discussion of land use at the Mill site, in surrounding areas, and in southeastern Utah, is presented in the FES (Section 2.5). Results of archeological studies conducted at the site and in the surrounding areas as part of the 1978 ER are also documented in the FES (Section 2.5.2.3). 2.5.8 Wen Logs Well/boring logs for wells MW-1, MW-2, MW-3, MW-4 (not a compliance well under the Permit), MW-5, MW-11, MW-12, MW-14, MW-15, MW-16 (not a compliance well under the Permit and abandoned during the construction of Tailings Cell 4B), MW -17, MW -18, and MW- 19, are included as Appendix A to the 1994 Titan Report. A copy of the 1994 Titan Report was previously submitted under separate cover. Lithologic and core logs for wells MW-3A, MW-23, MW-24, MW-25, MW-27, MW-28, MW- 29, MW-30 and MW-31 are included as Appendix A to the Report: Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill April Through June 2005, August 3, 2005, prepared by Hydro Geo Chern, Inc. A copy of that Report was previously submitted under separate cover. Lithologic and core logs for well MW-26 (previously named TW4-15) and well MW-32 (previously named TW4-17) are included as Appendix A to the Letter Report dated August 29, 2002, prepared by Hydro Geo Chern, Inc. and addressed to Harold Roberts. Lithologic and core logs for well MW-33, MW-34 and well MW-35 are included as Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-33, MW-34, and MW-35 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. October 11, 2010. A copy of that Report was previously submitted under separate cover. Lithologic and core logs for well MW-36 and well MW-37 are included as Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-36 and MW-37 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. June 28, 2011. A copy of that Report was previously submitted under separate cover. Installation logs for wells installed after 2011 are included in the As-Built Reports for each well. 29 2.6 The Type, Source, and Chemical, Physical, Radiological, and Toxic Characteristics of the Effluent or Leachate to be Discharged (R317 -6-6.3.F) The Mill is designed not to discharge to groundwater or surface waters. Instead, the Mill utilizes tailings and evaporation Cells for disposal or evaporation of Mill effluents as indicated below: • Cell 1: dedicated to evaporation of Mill waste solutions; • Cell 2: contains Mill tailings, has an interim cover and is closed to future tailings disposal; • Cell 3: contains Mill tailings and is in the final stages of filling; • Cell4A: receives Mill tailings and is used for evaporation of Mill solutions; and • Cell 4B: authorized to receive Mill tailings but currently is used only for evaporation of Mill solutions. See Sections 2.7.2 through 2.7.4 below for a more detailed discussion of the Mill's tailings cells. The projected chemical and radiological characteristics of tailings solutions were assessed by Energy Fuels Nuclear, Inc., a predecessor operator of the Mill, and NRC in 1979 and 1980, respectively. In addition, early samples were assessed by D' Appolonia Engineering as the Mill started operations to further evaluate and project the character of the solutions. Samples of tailings after the Mill was fully operational were collected by NRC (1987), EFRI/UDEQ (2003), and EFRI (2007 -2013),. Samples collected in 2003 were obtained under the oversight of DRC personnel. The Samples collected in 2007 and 2008 were obtained by EFRI on a voluntary basis as the then proposed Tailings and Slimes Drain Sampling Plan (the "Tailings Sampling Plan") had not been approved by the Director at that time. The 2009 samples were collected on August 6, 2009 under the Tailings Sampling Plan that was approved at that time. Subsequent annual sampling has been performed in August 2010, 2011, 2012 and 2013 under an approved Tailings Sampling Plan. A copy of the currently approved Tailings Sampling Plan is included as Appendix L. The chemical and radiological characteristics of the solutions held in the tailings cells, based on the sample results described above, are provided in the tables included in Appendix E, which list the concentration of parameters measured in accordance with the Permit. There is no active discharge from the tailings Cells; therefore, an estimation of the flow rate ("gpd") is not applicable in this instance. However, when operating at full capacity, the Mill discharges approximately 2000 tons per day of dry tailings and approximately 600 gpm of tailings solutions to the Mill's tailings cells. 2.7 Information Which Shows that the Discharge can be Controlled and Will Not Migrate Into or Adversely Affect the Quality of any Other Waters of the State (R317-6-6.3.G) 2.7.1 General The Mill has been designed as a facility that does not discharge to groundwater or surface water. All tailings and other Mill wastes are disposed of permanently into the Mill's tailings system. Excess waters are disposed of in the tailings or evaporation cells, where they are subject to evaporation, or re-processed through the Mill circuit. See Section 2.6. 30 The Mill was also designed ;md constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the tailings cells; and b) diverting runoff from surrounding areas away from the Mill site. The Permit therefore does not authorize any discharges to groundwater or surface water, but is intended to protect against potential inadvertent or unintentional discharges, such as through potential failure of the Mill's tailings system. The Mill's tailings system is currently comprised of four tailings cells (Cells 2, 3 4A, and 4B) and one evaporation pond (Cell 1). Diagrams showing the Mill facility layout, including the existing tailings cells are included as Figures 10 and 11 to this Application. In addition, the Mill has a lined catchment basin, used for temporary storage of Mill process upset fluids, known as "Roberts Pond". Roberts Pond is about 0.7 acres in size, and located approximately 180 feet west of the Mill building and about 200 feet east of the northeast corner of Cell 1. The following sections describe the primary Discharge Minimization Technology ("DMT") and Best Available Technology ("BAT") features of the Mill, which demonstrate that the wastes and tailings at the Mill can be controlled so that they do not migrate into or adversely affect the quality of any waters of the State, including groundwater and surface water. 2. 7.2 Cells 1, 2 and 3 2.7.2.1 Design and Construction of Cells 1, 2 and 3 Tailings Cells 1, 2 and 3 were each constructed more than 25 years ago. Construction of Cell 2 was completed on May 3, 1980, construction of Cell 1 was completed on June 29, 1981, and construction of Cell3 was completed on September 15, 1982. Each of Cells 1, 2 and 3 are constructed below grade. Each has a single 30 rnl PVC flexible membrane liner ("FML") constructed of solvent welded seams on a prepared sub base. A protective soil cover layer was constructed immediately over the FML with a thickness of 12- inches on the cell floor and 18-inches on the interior sideslope. The criterion for placement of the FML in Cells 1, 2 and 3 was a smooth sub base with no rocks protruding that could potentially damage the FML. The cells were excavated by ripping the in-place Dakota Sandstone with a large dozer. Where the rock could not be efficiently ripped, explosives were used to loosen the rock. The cell bottom was then graded to the final design contours and rolled with a smooth drum vibrating roller. The smooth drum roller effectively crushed the loose sandstone, filling in small holes, and allowed for a smooth surface suitable for liner placement. Due to the excavation methods (ripping and blasting) there were some areas that required little or no fill to meet final grades, while other areas required placement of additional crushed sandstone to meet the final grade. The cell bottom was sometimes re-worked several times to accomplish the desired result. The majority of the cell bottom is covered with a layer (1 to 6 inches) of crushed sandstone while the liner in some areas is placed directly on a smooth rolled surface of Dakota Sandstone with only a thin veneer of re-compacted sandstone. In places where the surface was rough or contained small holes, washed concrete sand was used to fill or smooth the imperfections, and the area was then rolled one last time before FML placement. Areas of 31 crushed sandstone filled sub base versus areas with little or no crushed sandstone base were not documented during construction. Areas filled or smoothed with washed concrete sand is likely less than 0.1% of the cell bottoms. Beneath this underlay, native sandstone and other foundation materials were graded to drain to a single low point near the upstream toe of the south cross- valley dike. Inside this layer, is an east-west oriented pipe to gather fluids at the upstream toe of the cross-valley dike. The crushed sandstone layer draining to the pipe at the upstream toe of the dike of the cell was intended to be a leak detection system for each cell. However, because the design of these leak detection systems does not meet current BAT standards, they are not recognized as leak detection systems in the Permit. Each of Cells 2 and 3 also has a slimes drain collection system immediately above the FML, comprised of a nominal 12-inch thick protective blanket layer of soil or comparable material, on top of which is a network of PVC perforated pipe laterals on a grid spacing interval of about 50- feet. These pipe laterals gravity drain to a perforated PVC collector pipe which also drains toward the south dike and is accessed from the ground surface via a non-perforated access pipe. At cell closure, leachate head inside the pipe network will be removed via a submersible pump installed inside the access pipe See Part I.D.1 of the Permit for a more detailed description of the design of Cells 1, 2 and 3. After review of the existing design and construction and consultation with the State of Utah Division of Water Quality, the Director determined, in connection with the issuance of the Permit in 2005, that the DMT required under the groundwater quality protection rules (UAC R317 -6-6.4( c )(3)) for Cells 1, 2 and 3 that pre-dated those rules will be defined by the current or existing disposal cell construction, with modifications that were included in the Permit (see page 25 of the 2004 Statement of Basis). These modifications focus on changes in monitoring requirements, and on improvements to facility closure. The goal of these improvements is to ensure that potential wastewater losses are minimized and local groundwater quality is protected. The modifications are described in Sections 2.7.2.2, 2.7.2.3 and 2.7.2.4 below. 2. 7.2.2 Improved Groundwater Monitoring Improvements were made to the Mill's groundwater monitoring network at the time of issuance of the Permit, to meet the following goals: a) Early Detection Three monitoring wells (MW-24, MW-27 and MW-28) were added immediately adjacent to Cell 1, in order to detect a potential release as early as practicable. b) Discrete Monitoring In order to individually monitor each tailings cell and to be able to pinpoint the source of any potential groundwater contamination that may be detected, the Permit required the addition of three monitoring wells (MW-29, MW-30 and MW-31) between Cells 2 and 3, in addition to the addition of wells MW-24, MW-27 and MW-28 immediately adjacent to Celli. 32 The addition of monitoring wells MW-24, MW-27, MW-28, MW-29, MW-30 and MW-31, together with the existing monitoring wells at the site provides a comprehensive monitoring network to determine any potential leakage from Cells 1, 2 and 3. See Figure 4 and Figure 10 for a map showing the locations of the existing compliance monitoring wells for the site. 2. 7.2.3 Operational Changes and Improved Operations Monitoring The Permit also required changes to disposal cell operation in order to increase efforts to minimize potential seepage losses, and thereby improve protection of local groundwater quality. Examples of these changes are: c) Maximum Waste and Wastewater Pool Elevation Part I.D.3 of the Permit requires that EFRI continue to ensure that impounded wastes and wastewaters for all of the Mill's tailings Cells and Roberts Pond are held within an FML. d) Slimes Drain Maximum Allowable Head Part I.D.3(b) of the Permit requires that the Mill provide constant pumping efforts to minimize the accumulation of leachates over the FML in Cell 2, and upon commencement of dewatering activities, in Cell 3, and thereby minimize potential FML leakage to the foundation and groundwater. See the discussion in Section 2.15.2.2 below. 2.7.2.4 Evaluation of Tailings Cell Cover System Design EFRI submitted an Infiltration and Contaminant Transport Modeling Report, White Mesa Mill Site, Blanding, Utah, November 2007, prepared by MWH Americas, Inc., in November, 2007. EFRI submitted a revised Infiltration and Contaminant Transport Modeling Report, White Mesa Mill Site, Blanding, Utah, March 2010 ("revised ICTM Report") in response to DRC comments. The March 2010 report is currently being reviewed in conjunction with the Reclamation Plan, Revision 5.0. DRC provided interrogatories for the revised ICTM Report in March 2012. EFRI provided responses to these interrogatories in May and September 2012. DRC provided review comments on EFRI's May and September 2012 responses in February 2013. On April 30, 2013, a meeting was held in Denver, Colorado to discuss specific issues identified in DRC's February 2013 review comments for Revision 5.0 of the Reclamation Plan and the revised ICTM Report. As noted in Section 2.19 .2, included in the discussions at this meeting was DRC's request for site-specific tailings data. EFRI proposed a tailings investigation to address DRC's concerns. The tailings investigation was completed in October 2013 and subsequent laboratory testing of samples collected was completed in April 2014. A Tailings Data Analysis Report summarizing the results of the investigation is currently being prepared for submittal to DRC in June 2014. Submission of responses to DRC's February 2013 review comments on the revised ICTM Report are planned to be completed in 2014 after DRC's review of the Tailings Data Analysis Report. The results provided in the Tailings Data Analysis Report will be used to update technical analyses to address DRC's February 2013 review comments on the revised ICTM report. The responses will also incorporate decisions made at the April 30, 2013 meeting on key issues related to the revised ICTM Report. 33 See Section 2.19 below for a more detailed discussion of post -closure requirements for the Mill. 2.7.3 Ce114A Construction of Cell 4A was completed on or about November 1989. Cell 4A was used for a short period of time after its construction for the disposal of raffinates from the Mill's vanadium circuit. No tailings waste or wastewater had been disposed of in Cell 4A since the early 1990s. This lack of waste disposal, and exposure of the FML to the elements, caused Cell 4A to fall into disrepair over the years. Although the original design of Cell4A was an improvement over the design of Cells 1, 2 and 3 (it had a one-foot thick clay liner under a 40 rn1 high density polyethylene ("HDPE") FML, with a more elaborate leak detection system), it was constructed in 1989 and did not meet today's BAT standards. Cell 4A was re-lined in 2007-2008 and was re-authorized for use in November 2008. With the reconstruction of Cell 4A, BAT was required, as mandated by Part I.D.4 of the Permit and as stipulated by the Utah Ground Water Quality Regulations at UAC R317-6-6.4(A). With BAT for Cell 4A, there are also new performance standards that require daily leak detection system monitoring, weekly wastewater level monitoring, and slimes drain recovery head monitoring. The BAT monitoring results are required to be reported and summarized in the Routine DMT and BAT Performance Standard Monitoring Reports. See Section 2.15.3 below for a more detailed discussion relating to the BAT performance standards and monitoring requirements for Cell4A. Tailings Cell 4A Design and Construction was approved by the Director as meeting BAT requirements. The major design elements are set out in Part I.D.5 of the Permit and consist of the following: e) Dikes -consisting of existing earthen embankments of compacted soil, constructed by a previous Mill operator between 1989-1990, and composed of four dikes, each including a 15-foot wide road at the top (minimum). On the north, east, and south margins these dikes have slopes of 3H to 1 V. The west dike has a slope of 2H to 1 V. Width of these dikes varies. Each has a minimum crest width of at least 15 feet to support an access road. Base width also varies from 89-feet on the east dike (with no exterior embankment), to 211-feet at the west dike. f) Foundation -including existing subgrade soils over bedrock materials. Foundation preparation included excavation and removal of contaminated soils, compaction of imported soils to a maximum dry density of 90%. The floor of Cell4A has an average slope of 1% that grades from the northeast to the southwest corners. g) Tailings Capacity-the floor and inside slopes of Cell 4A encompass about 40 acres and have a maximum capacity of about 1.6 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). h) Liner and Leak Detection Systems -including the following layers, in descending order: 34 (i) Primary FML -consisting of an impermeable 60 mil HDPE membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML is in direct physical contact with the tailings material over most of the Cell 4A floor area. In other locations, the primary FML is in contact with the slimes drain collection system (discussed below). (ii) Leak Detection System -includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4A, and drains to a leak detection sump in the southwest corner. Access to the leak detection sump is via an 18-inch inside diameter (ID) HDPE pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe is surrounded with a gravel filter set in the leak detection sump, having dimensions of 10 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer is enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. (iii) Secondary FML-consisting of an impermeable 60-mil HDPE membrane found immediately below the leak detection geonet. This FML also extends across the entire Cell 4A floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. (iv) Geosynthetic Clay Liner -consisting of a manufactured geosynthetic clay liner ("GCL") composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. i) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: (i) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4A that drains to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated, two-part geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southwesterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. (ii) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection ("SDC") pipe found at the downgradient end of the strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast corner downhill to the far southwest corner of Cell 4A where it joins the slimes drain access pipe. 35 (iii) Slimes Drain Access Pipe -consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4A at the southwest corner, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and woven geotextile that serves as a cushion to protect the primary FML. A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. j) North Dike Splash Pads-three 20-foot wide splash pads have been constructed on the north dike to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HDPE membrane that has been installed in the anchor trench and placed down the inside slope of Cell 4A, from the top of the dike, under the inlet pipe, and down the inside slope to a point 5-feet beyond the toe of the slope. k) Emergency Spillway - a concrete lined spillway has been constructed near the southwestern corner of the west dike to allow emergency runoff from Cell 4A to Cell 4B. At this time, all stormwater runoff and tailings wastewaters not retained in Cells 2, 3, and 4A will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. 1) BAT Performance Standards for Tailings Cell 4A-EFRI shall operate and maintain Tailings Cell 4A so as to prevent release of wastewater to groundwater and the environment in accordance with an Operations and Maintenance Plan, as currently approved by the Director, pursuant to Part I.H.19. At a minimum these performance standards shall include: (i) Maximum Allowable Daily Head-on the secondary FML, (ii) Maximum Allowable Daily Leak Detection System Flow Rate (iii) Slimes Drain Monthly and Annual Average Recovery Head Criteria -to be applied after the Mill initiates pumping conditions in the slimes drain layer. See Part I.D.5 of the Permit for a more detailed discussion of the design of Cell4A. A copy of the Mill's Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan is attached as Appendix F to this Application. 2. 7.4 Cell 4B Construction of Cell4B was completed in November 2010. Tailings Cell 4B Design and Construction was approved by the Director as meeting BAT requirements. The major design elements are set out in Part I.D.12 of the Permit and consist of the following: a) Dikes -consisting of newly constructed dikes on the south and west side of the cell, each including a 20-foot wide road at the top (minimum). The exterior slopes of the southern and western dikes have slopes of 3H to 1 V. The interior dikes have slopes of 2H to 1 V. Limited portions of the Cell 4B interior sidelopes in the northwest corner and southeast corner of the cell (where the slimes drain and leak detection sump are located) have a slope of 3H to 1 V. Width of these dikes varies. The base width of the 36 southern dike varies from approximately 92 feet at the western end to approximately 190 feet at the eastern end of the dike, with no exterior embankment present on any other side of the cell. b) Foundation -including existing sub grade soils over bedrock materials. Foundation preparation included excavation and removal of contaminated soils, compaction of imported soils to a maximum dry density of 90%. The floor of Cell4B has an average slope of 1% that grades from the northwest to the southeast corner. c) Tailings Capacity-the floor and inside slopes of Cell 4B encompass about 40 acres and the cell has a maximum capacity 1.9 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: (i) Primary FML -consisting of an impermeable 60 mil HDPE membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML is in direct physical contact with the tailings material over most of the Cell 4B floor area. In other locations, the primary FML is in contact with the slimes drain collection system (discussed below). (ii) Leak Detection System-includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4B, and drains to a leak detection sump in the southeast corner. Access to the leak detection sump is via an 18-inch inside diameter ("ID") HDPE pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe is surrounded with a gravel filter set in the leak detection sump, having dimensions of 15 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer is enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. (iii) Secondary FML -consisting of an impermeable 60-mil HDPE membrane found immediately below the leak detection geonet. This FML also extends across the entire Cell 4B floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. (iv) Geosynthetic Clay Liner -consisting of a manufactured geosynthetic clay liner ("GCL") composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. e) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: (i) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell4B that drains to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated two-part geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southeasterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester 37 fabric filled with well graded filter sand to protect the drainage system from plugging. (ii) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection (SDC) pipe found at the downgradient end of the strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast corner downhill to the far southeast corner of Cell 4A where it joins the slimes drain access pipe. (iii) Slimes Drain Access Pipe -consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell4B at the southeast corner, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and woven geotextile that serves as a cushion to protect the primary FML. A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. f) North and East Dike Splash Pads -nine 20-foot wide splash pads have been constructed on the north and east dikes to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HDPE membrane that has been installed in the anchor trench and placed down the inside slope of Cell4B, from the top of the dike, under the inlet pipe, and down the inside slope to a point 5-feet beyond the toe of the slope. g) Emergency Spillway - a concrete lined spillway has been constructed near the southeastern corner of the east dike to allow emergency runoff from Cell 4A into Cell 4B. This spillway is limited to a 6-inch reinforced concrete slab, with a welded wire fabric installed within its midsection, set directly atop a cushion geotextile placed directly over the primary FML in a 4-foot deep trapezoidal channel. A 100-foot wide, 60-mil HDPE membrane splash pad is installed beneath the emergency spillway. No other spillway or overflow structure will be constructed at Cell 4B unless and until the construction of Cells 5A and 5B. At this time, all stormwater runoff and tailings wastewaters not retained in Cells 2, 3, and 4A will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. h) BAT Performance Standards for Tailings Cell 4B -EFRI shall operate and maintain Tailings Cell 4B so as to prevent release of wastewater to groundwater and the environment in accordance with the currently-approved Cell 4B BAT, Monitoring, Operations and Maintenance Plan. At a minimum these performance standards shall include: (i) Maximum Allowable Daily Head-on the secondary FML, (ii) Maximum Allowable Daily Leak Detection System Flow Rate (iii) Slimes Drain Monthly and Annual Average Recovery Head Criteria -to be applied after the Mill initiates pumping conditions in the slimes drain layer, 38 (iv) Maximum Daily Wastewater Level -to ensure compliance with the minimum freeboard requirements for Cell 4B, and prevent discharge of wastewaters via overtopping. See Part I.D.12 of the Permit for a more detailed discussion of the design of Cell 4B. A copy of the Mill's Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan is attached as Appendix F to this Application. 2. 7.5 Future Additional Tailings Cells Future additional tailings cells at the Mill will require Director approval prior to construction and operation. Future tailings cells at the Mill will be required to satisfy BAT standards at the time of construction. 2.7.6 Roberts Pond Roberts Pond receives periodic floor drainage and other wastewaters from Mill process upsets, is frequently empty, and was re-lined with a new FML in May, 2002. In order to minimize any potential seepage release from Roberts Pond, the Director required the following in Part I.D.3(e) of the Permit: (i) EFRI "shall operate this wastewater pond [Roberts Pond] so as to provide a minimum 2-foot freeboard at all times. Under no circumstances shall the water level in the pond exceed an elevation of 5,624 feet amsl. In the event that the wastewater elevation exceeds this maximum level, the Permittee [EFRI] shall remove the excess wastewater and place it into containment in Tailings Cell 1 within 72-hours of discovery." (ii) At the time of Mill site closure, EFRI will excavate and remove the liner, berms, and all contaminated subsoils in compliance with an approved final reclamation plan under the Mill License. 2.7.7 Other Facilities and Protections 2.7.7.1 Feedstock Storage In order to constrain and minimize potential generation of contaminated stormwater or leachates, Part I.D.ll of the Permit requires the Mill to continue its existing practice of limiting open air storage of feedstock materials to the historical storage area found along the eastern margin of the Mill site (as defined by the survey coordinates found in Permit Table 4). The intent of Section I. D.ll, (based on the SOB for the 2009 GWDP), is to require that feedstock storage outside of the area specified in Table 4 shall meet the following requirements: a) Feedstock materials will be stored at all times in water-tight containers, and aisle ways will be provided at all times to allow visual inspection of each and every feedstock container, or b) Each and every feedstock container will be placed inside a water-tight overpack prior to storage, or 39 c) Feedstock containers shall be stored on a hardened surface to prevent spillage onto subsurface soils, and that conforms with the following minimum physical requirements: 1) A storage area composed of a hardened engineered surface of asphalt or concrete, and 2) A storage area designed, constructed, and operated in accordance with engineering plans and specifications approved in advance by the Director. All such engineering plans or specifications submitted shall demonstrate compliance with Part I.D.4, 3) A storage area that provides containment berms to control stormwater run-on and run- off, and 4) Stormwater drainage works approved in advance by the Director, or 5) Other storage facilities and means approved in advance by the Director. The language Section D.ll is currently ambiguous. Accordingly, EFRI requests that Part I.D.ll of the renewed GWDP be revised as set out above. 2. 7. 7.2 Mill Site Reagent Storage , Part I.D.3(g) of the Permit requires the Mill to demonstrate that it has adequate provisions for spill response, cleanup, and reporting for reagent storage facilities. These provisions are detailed in the Stormwater Best Management Practices Plan, which is designed to prevent potential reagent tank spills or leaks that could release contaminants to site soils or groundwater, and to provide proper spill prevention and control. Contents of this plan are stipulated in Part I.D.8 of the Permit, and submittal and approval of the plan is required under Part I.H.17 of the Permit. For existing facilities at the Mill, secondary containment is required, although such containment may be earthen lined. For new facilities constructed at the Mill, or reconstruction of existing facilities, Part I.D.3(g) requires a higher standard of secondary containment that would prevent contact of any potential spill with the ground surface. A copy of the Mill's Stormwater Best Management Practices Plan, Revision 1.5: September 2012 is attached as Appendix G to this Application. 2. 7. 7.3 New Construction Part I.D.4 of the Permit requires submittal of engineering plans and specifications and Director approval prior to the construction, modification, or operation of waste or wastewater disposal, treatment, or storage facilities. In these plans and specifications, the Mill is required to demonstrate how BAT requirements of the Groundwater Quality Protection Rules have been met. After Director Approval, a construction permit may be issued, and the Permit modified. 2. 7. 7.4 Other The White Mesa Mill Discharge Minimization Technology (DMT) Monitoring Plan, 7112 Revision: Denison-12.1 (the "DMT Plan"), and the White Mesa Mill Tailings Management System, 7/2012 Revision 12.1 (the "Tailings Management Plan"), are attached as Appendix H and Appendix I to this Application, respectively. These plans provide a systematic program for 40 constant surveillance and documentation of the integrity of the tailings system, including monitoring the leak detection systems. The DMT Plan requires daily, weekly, quarterly, monthly and annual inspections and evaluations and monthly reporting to Mill management. See Section 2.15.2 below for a more detailed discussion of the requirements of the DMT Plan. 2. 7.8 Surface Waters The Mill has been designed as a facility that does not discharge to surface waters. Tailings and other Mill wastes are disposed of permanently into the Mill's tailings system. Further, as mentioned above, the Mill was designed and constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the tailings cells; and b) diverting runoff from surrounding areas away from the Mill site. As a result, there is no pathway for liquid effluents from Mill operations to impact surface waters. Under the Mill License, the Mill is required to periodically sample local surface waters to determine if Mill activities may have impacted those waters. The primary pathway would be from air particulates generated during Mill operations that may have landed on or near surface waters, or that may have accumulated in drainage areas that could feed into surface waters. Sampling results since inception of Mill operations show no trends or other impacts of Mill operations on local surface waters. See the Mill's Semi-Annual Effluent Report for the period July 1 to December 31, 2013, a copy of which has previously been provided to the Director. 2.7.9 Alternate Concentration Limits The Mill does not discharge to groundwater or surface water, nor is it designed to do so. Therefore, no alternate concentration limits are currently applicable to the site. 2.8 For Areas Where the Groundwater Has Not Been Classified by the Board, Information of the Quality of the Receiving Ground Water (R317-6-6.3.H) Groundwater classification was assigned by the Director in the Permit on a well-by-well basis after review of groundwater quality characteristics for the perched aquifer at the Mill site. A well-by-well approach was selected by the Director in order to acknowledge the spatial variability of groundwater quality at the Mill, and afford the most protection to those portions of the perched aquifer that exhibited the highest quality groundwater. These groundwater classifications are set out in Part I.A and Table 1 of the Permit. The primary element used by the Director in determining the groundwater classification of each monitoring well at the site, is the TDS content of the groundwater, as outlined in UAC 317-6-3. Groundwater quality data collected by the Mill show the shallow aquifer at the Mill has a highly variable TDS content, with TDS averages ranging from about 1100 to over 7900 mg/L. Another key element in determination of groundwater class is the presence of naturally occurring contaminants in concentrations that exceed their respective GWQS. In such cases, the Director has cause to downgrade aquifer classification from Class II to Class III (see UAC R317-6-3.6). Using all available TDS data and background data, for 24 of the POC and general monitoring wells the Director determined that 4 of those wells exhibit Class II drinking water quality groundwater. The remaining 20 wells exhibited Class III or limited use groundwater at the site. The Director determined that MW-35 will be classified as having Class II drinking water quality 41 groundwater until sufficient background data have been collected and the applicable Background Report is submitted. Wells MW-36 and MW-37 have not been classified at this time. 2.8.1 Existing Wells at the Time of Original Permit Issuance The Director required EFRI to evaluate groundwater quality data from the thirteen existing wells on site, and submit a Background Ground Water Quality Report for Director approval. One of the purposes of that report was to provide a critical evaluation of historic groundwater quality data from the facility, and determine representative background quality conditions and reliable GWCLs for the Permit. EFRI (then Denison) prepared the Existing Well Background Report that evaluated all historic data for the thirteen existing wells for the purposes of establishing background groundwater quality at the site and developing GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the Existing Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells, based primarily on the analysis performed in the Existing Wellls Background Report. It should be noted, however, that, because the GWCLs have been set at the mean plus two standard deviations, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. 2.8.2 New Wells Installed After the Date of Original Issuance of the Permit Because the Permit called for installation of nine new monitoring wells around the tailings cells, background groundwater quality had to be determined for those monitoring points. To this end, the Permit required the Mill to collect at least eight quarters of groundwater quality data, and submit the New Well Background Report for Director approval to establish background groundwater quality for those wells. EFRI (then Denison) prepared the New Well Background Report that evaluated all historic data for the nine new wells for the purposes of establishing background groundwater quality at the site and developing GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the New Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the nine new wells based primarily on the analysis performed in the New Well Background Report. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. 42 2.9 Sampling and Analysis Monitoring Plan (R317-6-6.3.1) The groundwater monitoring plan is set out in the Permit. All groundwater monitoring at the site is in the perched aquifer. The following sections summarize the key components of the Mill's sampling and analysis plan. 2.9.1 Groundwater Monitoring to Determine Groundwater Flow Direction and Gradient, Background Quality at the Site, and the Quality of Groundwater at the Compliance Monitoring Point 2.9.1.1 Groundwater Monitoring at the Mill Prior to Issuance of the Permit At the time of renewal of the Mill license by NRC in March, 1997 and up until issuance of the Permit in March 2005, the Mill implemented a groundwater detection monitoring program , in accordance with 10 CFR Part 40, Appendix A and the provisions of the Mill License condition 11.3A. The detection monitoring program was implemented in accordance with the report entitled, Points of Compliance, White Mesa Uranium Mill, prepared by Titan Environmental Corporation, submitted by letter to the NRC dated October 5, 1994. Under that program, the Mill sampled monitoring wells MW-5, MW-11, MW-12, MW-14, MW-15 and MW-17, on a quarterly basis. Samples were analyzed for chloride, potassium, nickel and uranium, and the results of such sampling were included in the Mill's Semi-Annual Effluent Monitoring Reports that were filed with the NRC up until August 2004 and with the DRC subsequent thereto. Between 1979 and 1997, the Mill monitored up to 20 constituents in up to 13 wells. That program was changed to the Points of Compliance Program in 1997 because NRC had concluded that: • The Mill and tailings system had produced no impacts to the perched zone or deep aquifer; and • The most dependable indicators of water quality and potential cell failure were considered to be chloride, nickel, potassium and natural uranium. 2.9.1.2 Issuance of the Permit On March 8, 2005, the Director issued the Permit, which includes a groundwater monitoring program that superseded and replaced the groundwater monitoring requirements set out in Mill License Condition 11.3A. Condition 11.3A has since been removed from the Mill License. Groundwater monitoring under the Permit commenced in March 2005, the results of which are included in the Mill's Quarterly Groundwater Monitoring Reports that are filed with the Director. On September 1, 2009, EFRI filed a Groundwater Discharge Permit Renewal Application. At the request of the Director of the Utah Division of Radiation Control, EFRI submitted an updated version of the September 1, 2009 renewal application on July 13, 2012. At the request of the Director of the Utah Division of Radiation Control, EFRI is submitting this updated version of the July 2012 renewal application. The Permit remains in timely renewal status awaiting completion of review of the Renewal Application by the Director. 43 2.9.1.3 Current Ground Water Monitoring Program at the Mill Under the Permit The current groundwater monitoring program at the Mill under is used to determine ground water flow direction, gradient, and quality at the compliance monitoring points. This program consists of monitoring at 25 point of compliance monitoring wells: MW-1, MW-2, MW-3, MW- 3A, MW-5, MW-11, MW-12, MW-14, MW-15, MW-17, MW-18, MW-19, MW-23, MW-24, MW-25, MW-26, MW-27, MW-28, MW-29, MW-30, MW-31, MW-32, MW-35, MW-36, and MW-37. The locations of these wells are indicated on Figure 10. Depth to water is measured quarterly in MW-34, but due to limited water is not sampled for POC compliance. MW-33 is completely dry and is not sampled for POC compliance. Part I.E.l.(d) of the Permit requires that each point of compliance well must be sampled for the constituents listed in Table 2.9.1.3-1. Further, Part I.E.l.(d)1) of the Permit, requires that, m addition to pH, the following field parameters must also be monitored: • Depth to groundwater • Temperature • Specific conductance • Redox potential ("Eh") and that, in addition to chloride and sulfate, the following general organics must also be monitored: • Carbonate, bicarbonate, sodium, potassium, magnesium, calcium, and total anions and cations. Sample frequency depends on the speed of groundwater flow in the vicinity of each well. Parts I.E.1 (b) and (c) provide that quarterly monitoring is required for all wells where local groundwater average linear velocity has been found by the Director to be equal to or greater than 10 feet/year, and semi-annual monitoring is required where the local groundwater average linear velocity has been found by the Director to be less than 10 feet/year. Based on these criteria, quarterly monitoring is required at MW-11, MW-14, MW-25, MW-26 and MW-30, and MW-31, and semi-annual monitoring is required at MW-1, MW-2, MW-3, MW-31\, MW-5,MW-12, MW-15, MW-17, MW-18, MW-19,MW-23,MW-24, MW-27, MW- 28, MW-29 and MW-32. Geochemical and indicator parameter analysis during the initial SAA in October of 2012 concluded that upgradient monitoring wells MW -1, MW -18, and MW -19 have not been impacted by Mill activities. i\t that time, EFRI proposed that these upgradient monitoring wells be sampled routinely but not subject to GWCLs. In a letter dated i\pril25, 2013, DRC approved this proposed change to take place at the time of the Permit renewal. 44 Wells MW-35, MW-36 and MW-37 were being sampled quarterly, to collect eight consecutive quarters of background data. The Background Report for wells MW-35, MW-36, and MW-37 was submitted to the Director on May 1, 2014. After review by DRC, the Director will establish groundwater compliance levels for those wells and determine their frequency of sampling. Prior to the February 15, 2011 revision of the GWDP, EFRI collected quarterly groundwater samples from MW-20 and MW-22 for development of background values and potential GWCLs. Part I.E.l.c).3) in the currently approved August 24, 2012 revision of the GWDP now requires that MW-20 and MW-22 be monitored on a semi-annual basis as "General Monitoring Wells," but they are not subject to GWCLs. 2.9.1.4 Groundwater Flow Direction and Gradient Part I.E.3 of the Permit requires that, on a quarterly basis and at the same frequency as groundwater monitoring required by Part I.E.1 and described in Section 2.9 .1.3 above, the Mill shall measure depth to groundwater in the following wells and/or piezometers: i) The point of compliance wells identified in Table 2 of the Permit, as described in Section 2.9.1.3 above; j) Piezometers P-1, P-2, P-3, P-4 and P-5; k) Existing monitoring wells MW-20, MW-22, and MW-34; I) Contaminant investigation wells -any well required by the Director as a part of a contaminant investigation or groundwater corrective action (at this time this includes the chloroform and nitrate investigation wells); and m) Any other wells or piezometers required by the Director. While it is not a requirement of the GWDP, EFRI also measures depth to water in the DR piezometers which were installed during the Southwest Hydrogeologic Investigation. The Mill uses these measurements to prepare groundwater isocontour maps each quarter that show the groundwater flow direction and gradient. The isocontour map for the first quarter of 2014 is attached as Figure 5. 2.9.1.5 Background Quality at the Site A significant amount of historic groundwater quality data had been collected by EFRI and previous operators of the Mill for some wells at the facility. In some cases these data extend back more than 30 years to September 1979. A brief summary of the various studies that had been performed prior to the original issuance of the Permit is set out in Section 2.0 of the Regional Background Report. However, at the time of original issuance of the Permit, the Director had not yet completed an evaluation of the historic data, particularly with regard to data quality, and quality assurance issues. Such an examination needed to include such things as justification of any zero concentration values reported, adequacy of minimum detection limits provided (particularly with respect to the corresponding GWQS), adequacy of laboratory and analytical methods used, consistency of laboratory units or reporting, internal consistency between specific and composite 45 types of analysis (e.g., major ions and TDS), identification and justification of concentration outliers, and implications of concentration trends (both temporal and spatial). As discussed in Section 2.11.2 below, the Director also noted several groundwater quality issues that needed to be resolved prior to a determination of background groundwater quality at the site. These were: 1) a number of constituents exceeded their respective GWQS (including nitrate in one well and manganese, selenium and uranium in several wells); 2) long term trends in uranium in downgradient wells MW-14, MW-15 and MW-17; and 3) a spatial high of uranium in those three downgradient wells. See pages 5-8 of the 2004 Statement of Basis for a more detailed discussion of these points. As a result of the foregoing, the Director required that the Background Reports be prepared to address and resolve these issues. Further, because background groundwater quality at the Mill site had not yet been approved at the time of original Permit issuance, the Director was not able to determine if any contaminant is naturally occurring and therefore detectable or undetectable for purpose of selecting GWCLs in each well. Consequently, the Director initially assigned GWCLs as if they were "undetectable" (i.e., assuming that all natural background concentrations were less than a fraction of the respective GWQS). As discussed in Section 1.3 above and 2.11.2 below, EFRI submitted the Background Reports to the Director. Both the Existing Well Background Report and the New Well Background Report provided GWCLs for all of the constituents in the existing wells and new wells, respectively, based on a statistical intra-well approach. The Director has approved the Background Reports. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells and the nine new wells based primarily on the analysis performed in the Background Reports. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. 2.9.1.6 Quality of Ground Water at the Compliance Monitoring Point There are over 30 years of data for some constituents in some wells at the site, but not for all constituents. However, with the exception of tin, which was added as a monitoring constituent in 2007, all currently required monitoring constituents have been sampled in the wells that were in existence on the date of the original issuance of the Permit commencing with the first quarter of 2005. Further, all constituents in the new compliance monitoring wells have been sampled upon installation of those wells, commencing either in the second or third quarters of 2005. The analytical results from this sampling are reported quarterly in Groundwater Monitoring Reports, which are filed with the Director pursuant to Part I.F.1 of the Permit. 46 2.9.2 Installation, Use and Maintenance of Monitoring Devices Compliance monitoring at the Mill site is accomplished in three ways: the compliance well monitoring program; the leak detection monitoring system in Cells 4A and 4B; and various DMT monitoring requirements. Each of these are discussed below. 2.9.2.1 Compliance Well Monitoring Compliance for tailings Cells 1, 2 and 3 and the remainder of the Mill site, other than Cells 4A and 4B, is accomplished by quarterly or semi-annual sampling of the network of compliance monitoring wells at the site. See Figure 10 for a map that shows the compliance monitoring well locations, and Section 2.9 .1.3 for a description of the monitoring program. 2.9.2.2 Leak Detection System in Cell 4A and Cell 4B BAT was required, as mandated in Part I.D.4 of the Permit and as stipulated by UAC R317 -6- 6.4(a) for the reconstruction of Cell 4A and the construction of Cell 4B. Because tailings Cells 1, 2 and 3 were constructed more than 25 years ago, and after review of the existing design and construction, the Director determined that DMT rather than BAT is required for Cells 1, 2 and 3 (see the discussion in Section 2.7.2 above). BAT for Cell4A and Cell4B included the construction of a modern leak detection system. See Sections 2.7.3 and 2.7.4 above for a description of the key design elements of Cell 4A and Cell 4B respectively, including their leak detection systems. With BAT for Cell 4A and Cell 4B, there are new performance standards in the Permit that require daily leak detection system monitoring, weekly wastewater level monitoring, and slimes drain recovery head monitoring. The BAT monitoring results are required to be reported and summarized in the Routine DMT and BAT Performance Standard Monitoring Reports. See Sections 2.15.3 and 2.15.4 below for a more detailed discussion of the BAT monitoring requirements for Cell 4A and Cell 4B respectively. Because Cell4A and Cell4B have modern leak detection systems, that meets BAT standards and are monitored daily, the leak detection systems in Cell 4A and Cell4B can be considered to be a point of compliance monitoring devices. 2.9.2.3 Other DMT Monitoring Requirements In addition to the foregoing, the additional DMT performance standard monitoring discussed in detail in Section 2.15 below is required to be performed under the Permit 2.9.3 Description of the Compliance Monitoring Area Defined by the Compliance Monitoring Points The compliance monitoring area at the site is the area covered by the groundwater compliance monitoring wells. Figure 10 shows the current locations of the compliance groundwater monitoring wells at the site. 47 At the time of original Permit issuance, the Director reviewed the then recent water table contour maps of the perched aquifer. Those maps identified a significant western component to groundwater flow at the Mill site, which the Director concluded appeared to be the result of wildlife pond seepage and groundwater mounding (see page 23 of the 2004 Statement of Basis). As a consequence, new groundwater monitoring wells were required, particularly along the western margin of the tailings cells, in addition to the monitoring wells already in existence at that time. The Director also concluded that new wells were also needed for DMT purposes and to provide discrete monitoring of each tailings cell. This resulted in the addition of the following compliance monitoring wells to the then existing monitoring well network: MW-23, MW-24, MW-25, MW-26 (which was then existing chloroform investigation well TW4-15), MW-27, MW-28, MW-29, MW-30, MW-31 MW-32 (which was then existing chloroform investigation well TW4-17), MW-35, MW-36, and MW-37. As previously stated MW-33 and MW-34 were installed but are not currently sampled due to limited water and saturated thickness. MW-20 and MW-22 are not POC wells but are general monitoring wells and are sampled semiannually for information purposes only. Based on groundwater flow direction and velocity, the compliance monitoring network, with the foregoing additional new wells, was considered to be adequate for compliance monitoring in the perched aquifer at the site. Further, as mentioned in Section 2.9.2.2 and 2.9.2.3 above, the leak detection systems in Cell4A and 4B can also be considered to be compliance monitoring areas for these cells. 2.9.4 Monitoring of the Vadose Zone Monitoring is not performed in the vadose zone at the site. 2.9.5 Measures to Prevent Ground Water Contamination After the Cessation of Operation, Including Post-Operational Monitoring 2.9.5.1 Measures to Prevent Ground Water Contamination After the Cessation of Operation Please see Section 2.19 below for a detailed discussion of the measures to prevent groundwater contamination after the cessation of operations. 2.9.5.2 Post-Operational Monitoring Groundwater monitoring will continue during the post-operational phase through final closure until the Permit is terminated. EFRI understands that the final closure will take place and the Permit will be terminated upon termination of the Mill License and transfer of the reclaimed tailings cells to the United States Department of Energy pursuant to U.S.C. 2113. See Section 2.19.1.1 below. 2.9.6 Monitoring Well Construction and Ground Water Sampling Which Conform Where Applicable to Specified Guidance 2.9.6.1 Monitoring Well Construction a) New Wells 48 All new compliance monitoring wells installed after the original issuance of the Permit were installed in accordance with the requirements of Part I.E.4 of the Permit. Part I.E.4 requires that new groundwater monitoring wells installed at the facility comply with the following design and construction criteria: a) Located as close as practical to the contamination source, tailings cell, or other potential origin of groundwater pollution; b) Screened and completed in the shallow aquifer; c) Designed and constructed in compliance with UAC R317-6-6.3(1)(6), including the EPA RCRA Ground Water Monitoring Technical Enforcement Guidance Document, 1986, OSWER-9950.1 (the "EPA RCRA TEGD"); and d) Aquifer tested to determine local hydraulic properties, including but not limited to hydraulic conductivity. As-built reports for all new groundwater monitoring wells were submitted to the Director for his approval, in accordance with Part I.F.6 of the Permit. Part I.F.6 requires those reports to include the following information: a) Geologic logs that detail all soil and rock lithologies and physical properties of all subsurface materials encountered during drilling. Said logs were prepared by a Professional Geologist licensed by the State of Utah or otherwise approved beforehand by the Director ; b) A well completion diagram that details all physical attributes of the well construction, including: 1) Total depth and diameters of boring; 2) Depth, type, diameter, and physical properties of well casmg and screen, including well screen slot size; 3) Depth intervals, type and physical properties of annular filterpack and seal materials used; 4) Design, type, diameter, and construction of protective surface casing; and 5) Survey coordinates prepared by a State of Utah licensed engineer or land surveyor, including horizontal coordinates and elevation of water level measuring point, as measured to the nearest 0.01 foot; and c) Aquifer permeability data, including field data, data analysis, and interpretation of slug test, aquifer pump test or other hydraulic analysis to determine local aquifer hydraulic conductivity in each well. Between April and June 2005, EFRI installed wells MW-23, MW-24, MW-25, MW-27, MW-28, MW-29, MW-30, and MW-31. On August 23, 2005, EFRI submitted a Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill April through June 2005 Report, prepared by Hydro Geo Chern, Inc., that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. Between August 30 and September 2, 2010, EFRI installed wells MW-33, MW-34, and MW-35. On October 11, 2010, EFRI submitted Installation and Hydraulic Testing of Perched Monitoring 49 Wells MW-33, MW-34, and MW-35 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. During the week of April 25, 2011, EFRI installed wells MW-36, and MW-37. On June 28, 2011, EFRI submitted Installation and Hydraulic Testing of Perched Monitoring Wells MW-36, and MW-37 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. b) Existing Wells The Existing Wells, MW-1, MW-2, MW-5, MW-11, MW-12, MW-14, MW-15, MW-17, MW- 18, MW-19, MW-26 and MW-32 as well as wells MW-16, MW-20 and MW-22, which are not compliance monitoring wells, and piezometers P-1, P-2, P-3, P-4 and P-5, were all constructed and installed prior to original issuance of the Permit. Some of those wells date back to 1979. During several site visits and four split groundwater sampling events between May 1999 and the date of original issuance of the Permit, and a review of available as built information, DRC staff noted the need for remedial construction, maintenance, or repair at several of these wells, including: (i) (ii) (iii) A. B. c. D. 16 of the existing monitoring wells failed to produce clear groundwater in conformance with the EPA RCRA TEGD, apparently due to incomplete well development. Consequently, the Permit required that MW-5, MW-11, MW-18, MW-19, MW-26, TW4-16, and MW-32 be developed to ensure that groundwater clarity conforms to the EPA RCRA TEGD to the extent reasonably achievable; The Permit required the Mill to install protective steel surface casings to protect the exposed PVC well and piezometer casings for piezometers P-1, P-2, P-3, P-4, and P-5 and wells MW-26 and MW-32; and Several problems were observed with the construction ofMW-3, including: A review of the MW-3 well as-built diagram showed that no geologic log was provided at the time of well installation. Consequently, the Director was not able to ascertain if the screened interval was adequately located across the base of the shallow aquifer; MW-3 was constructed without any filter media or sand pack across the screened interval; An excessively long casing sump (a 9 or 10 foot long non-perforated section of well casing), was constructed at the bottom of the well; and The well screen appeared to be poorly positioned, based on the low productivity of the well, (there is no geologic log to verify proper positioning). 50 The Mill developed the wells as required and installed the protective casings required. The Director concluded that EFRI had fulfilled the requirements and sent EFRI a Closeout Letter on August 5, 2008. With respect to the concerns raised about MW-3, the Mill installed MW-3A approximately 10 feet southeast of MW-3, in order to verify the depth to the upper contact of the Brushy Basin Member of the Morrison Formation (the "UCBM"). After installation, the Director reviewed the geologic log for MW-3 and the as-built reports for both MW-3 and MW-3A and concluded that the well screen for MW-3A is 2.5 feet below the UCBM and the well screen for MW-3 is 4.5 feet above the UCBM. Therefore MW-3 is a partially penetrating well; whereas MW-3A is fully penetrating. The Director concluded that semiannual sampling must continue in both wells until sufficient data is available and the DRC can make a conclusion regarding the effects of partial well penetration and screen length. As a result, the GWDP was modified to require that MW-3A be completed with a permanent surface well completion according to EPA RCRA TEGD. EFRI completed MW-3A as required, and on August 5, 2008 the DRC sent EFRI a Closeout Letter. Both MW-3 and MW-3A are currently sampled semiannually. Subsequent to original Permit issuance, on January 6, 2006, DRC staff performed an inspection of the compliance groundwater monitoring wells at the Mill. During the inspection, well MW -5 was found to have a broken PVC surface casing. The repair of MW -5 was added to the Permit compliance schedule to require the Mill to repair the broken PVC casing to meet the requirements of the Permit. The Permit required EFRI to submit an As-Built report for the repairs of monitoring well MW-5 on or before May 1, 2008. EFRI submitted the required report, and on August 5, 2008 the DRC sent EFRI a Closeout Letter. The groundwater monitoring program at the Mill has historically had numerous wells with elevated turbidity, turbidity levels which could not stabilize to within 10% Relative Percent Difference (10% RPD) or both. Identification of equipment problems and improvements to field sampling practices did not result in improvements to measured turbidities. Ongoing turbidity issues were the result of monitoring requirements which were most likely ill-suited to the site geology. It is suspected that many wells at the Mill might not be capable of attaining a turbidity of 5 NTU due to the natural conditions in the formation hosting the perched monitoring wells (the Burro Canyon Formation and Dakota Sandstone). Clay interbeds occur in both the Burro Canyon Formation and Dakota Sandstone, and friable materials occur within the Burro Canyon Formation. Saturated clays and friable materials will likely continue to be mobilized using standard purging techniques currently in use for the sampling program at the Mill. Mobilized kaolinite (a cementing material within the formation) is expected to be an additional continuing source of turbidity in perched wells. EFRI discussed the turbidity issues with DRC and agreed to complete a redevelopment program for the selected wells at the Mill in a "good-faith" effort to reduce the turbidity level. Surging, bailing, and overpumping were determined to be the preferred well development techniques. The rationale for using surging and bailing followed by overpumping is consistent with U.S. Environmental Protection Agency ("EPA") guidance and guidance provided in other technical papers and publications. 51 Select, nonpumping, chloroform, nitrate and groundwater POC, wells were redeveloped during the period from fall 2010 to spring 2011 by surging and bailing followed by overpumping. The results of the redevelopment are provided in the Report entitled: Redevelopment of Existing Perched Monitoring Wells White Mesa Uranium Mill, Near Blanding Utah, prepared by Hydro Geo Chern, Inc. September 30, 2011 (the "Redevelopment Report"). The Redevelopment Report provides a qualitative description of turbidity behavior before and after redevelopment and provides a number of conclusions and recommendations. A copy of the Redevelopment Report was previously submitted under separate cover. The Redevelopment Report was closed out by the Director in a letter dated November 15, 2012. The closeout denied EFRI recommendations. However, due to other modifications to the sampling strategies, turbidity of the wells is no longer considered an issue. As described above, the ex1stmg wells have been reviewed by the Director, and repairs, modifications, retrofits, etc. have been made as required to conform those wells to the requirements of Pmt I.E.4 of the Permit, to the extent reasonably practicable. 2.9.6.2 Ground Water Sampling Ground water sampling is performed in accordance with the requirements of Part I.E.5 of the Permit, which requires that all monitoring shall be conducted in conformance with the following procedures: a) Grab samples shall be taken of the groundwater, only after adequate removal or purging of standing water within the well casing has been performed; b) All sampling shall be conducted to ensure collection of representative samples, and reliability and validity of groundwater monitoring data. All groundwater sampling shall be conducted in accordance with the currently approved Groundwater Monitoring Quality Assurance Plan; c) All analyses shall be performed by a laboratory certified by the State of Utah to perform the tests required; d) If any monitor well is damaged or is otherwise rendered inadequate for its intended purpose, EFRI shall notify the Director in writing within five days of the discovery; and e) Immediately prior to each monitoring event, EFRI shall calibrate all field monitoring equipment in accordance with the respective manufacturer's procedures and guidelines. EFRI shall make and preserve on-site written records of such equipment calibration in accordance with Part II.G and H of the Permit. Said records shall identify the manufacturer's and model number of each piece of field equipment used and calibration. In accordance with the requirements of Part I.E.1 (a) of the Permit, groundwater sampling at the Mill is performed in accordance with the White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) (the "QAP"), which has been approved by the Director. The QAP complies with UAC R317-6-6.3(1) and (L) and by reference incorporates the relevant requirements of the Handbook of Suggested Practices for Design and Installation of Ground- Water Monitoring Wells (EPN600/4-89/034, March 1991), ASTM Standards on Ground Water and Vadose Investigations (1996), Practical Guide for Ground Water Sampling EPN60012- 52 851104, (November 1985) and RCRA Ground Water Monitoring Technical Enforcement Guidance Document (1986), unless otherwise specified or approved by the Director. A copy of the current version of the QAP, Date: 6-06-12 Revision 7.2, is included as Appendix K. 2.9. 7 Description and Justification of Parameters to be Monitored The groundwater parameters to be monitored are described in Table 2.9.1.3-1. The process of selecting the groundwater quality monitoring parameters for the original Permit included examination of several technical factors. These factors are listed below and discussed in detail in Section 4 on pages 9-19 of the 2004 Statement of Basis. : a) The number and types of contaminants that might occur m feedstock materials processed at the Mill; b) Mill process reagents as a source of contaminants; c) Source term abundance in the Mill's tailings cell solutions, based on historic wastewater quality sampling and analysis that had been done at the Mill's tailings cells; and d) A consideration of contaminant mobility in a groundwater environment, based on site specific .KI information where available and lowest .KI values in the literature where site specific .KI information is not available. One additional parameter, tin, was added to the list of groundwater monitoring constituents in 2007. Tin was not originally a required groundwater monitoring parameter in the Permit, and was omitted from the original Permit due to non-detectable concentrations reported by EFRI in three tailings leachate samples (2004 Statement of Basis, Table 5). With the addition of the alternate feed material from Fansteel Inc., tin was estimated to increase from 9 to 248 tons in the tailings inventory. The Director concluded that, with an estimated .KI of 2.5 to 5, tin is not as mobile in the groundwater environment as other metals; however, with the acidic conditions in the tailings wastewater, tin could stay in solution and not partition on aquifer materials. As a result, tin was added as a monitoring constituent to Table 2 of the Permit. 2.9.8 Quality Assurance and Control Provisions for Monitoring Data Part I.E.1 (d) of the Permit sets out some special conditions for groundwater monitoring. Under those conditions, the Mill must ensure that all groundwater monitoring conducted and reported complies with the following: a) Depth to groundwater measurements shall always be made to the nearest 0.01 foot; b) All groundwater quality analyses reported shall have a minimum detection limit or reporting limit that is less than its respective GWCL concentration defined in Table 2 of the Permit; and c) All gross alpha analysis reported with an activity equal to or greater than the GWCL shall have a counting variance that is equal to or less than 20% of the reported activity concentration. An error term may be greater than 20% of the reported activity concentration when the sum of the activity concentration and error term is less than or equal to the GWCL. 53 As mentioned in Section 2.9.6.2 above, Part I.E.1(a) of the Permit requires that all groundwater sampling shall be conducted in accordance with the currently approved QAP. The detailed quality assurance and control provisions for monitoring data are set out in the QAP, a copy of which is attached as Appendix K to this Application. 2.10 Plans and Specifications Relating to Construction, Modification, and Operation of Discharge Systems (R317 -6-6.3.J) As discussed in Section 2.7.1 above, the Mill has been designed as a facility that does not discharge to groundwater or surface water. Tailings and other wastes associated with Mill operations are designed to be permanently disposed of in the Mill's tailings cells. The Mill's tailings cells can therefore be considered the Mill's discharge system in that they permanently contain discharges from the Mill's process circuits and all other Mill tailings and wastes. The following plans and specifications and as built reports relating to tailings Cells 1, 2, 3, 4A and 4B are referenced in this Application and were previously submitted on the dates noted below under separate cover: a. Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah, June 1979, prepared by D' Appolonia Consulting Engineers, Inc.; b. Engineer's Report: Second Phase Design -Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah, May 1981, prepared by D' Appolonia Consulting Engineers, Inc.; c. Construction Report: Initial Phase -Tailings Management System, White Mesa Uranium Project Blanding, Utah, February 1982, prepared by D' Appolonia Consulting Engineers, Inc.; d. Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project, March 1983, prepared by Energy Fuels Nuclear, Inc.; e. Cell 4 Design, White Mesa Project Blanding, Utah, April 10, 1989, prepared by Umetco Minerals Corporation; f. Construction Report: Tailings Cell 4A, White Mesa Uranium Mill -Tailings Management System, August 2000, prepared by EFRI (then named International Uranium (USA) Corporation); g. Cell 4A Lining System Design Report For The White Mesa Mill Blanding, Utah, January 2006, prepared by GeoSyntec Consultants; and h. Cell4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah, July 2008 prepared by Geosyntec consultants. 1. Cell4B Design Report, White Mesa Mill, Blanding, Utah, December 8, 2007, prepared by Geosyntec Consultants J. Cell 4B Construction Quality Assurance Report, Volumes 1-3, November 2010, prepared by Geosyntec Consultants 2.11 Description of the Ground Water Most Likely to be Affected by the Discharge (R317-6-6.3.K) 2.11.1 General The ground water most likely to be affected by a potential discharge from Mill activities is the perched aquifer. 54 The deep confined aquifer under White Mesa is found in the Entrada and underlying Navajo Sandstones, is hydraulically isolated from the perched aquifer, and is therefore extremely unlikely to be affected by any such potential discharges. The top of the Entrada Sandstone at the site is found at a depth of approximately 1,200 feet below land surface (see the discussion in Sections 2.5.1.1 and 2.5.1.2 above). This deep aquifer is hydraulically isolated from the shallow perched aquifer by at least two shale members of the Morrison Formation, including the Brushy Basin (approximately 295 feet thick) and the Recapture (approximately 120 feet thick) Members. Other geologic units are also found between the perched and deep confined aquifers that include many layers of thin shale interbeds that contribute to hydraulic isolation of these two groundwater systems, including: the Morrison Formation Westwater Canyon (approximately 60 feet thick), and Salt Wash (approximately 105 feet thick) Members, and the Summerville Formation (approximately 100 feet thick). Artesian groundwater conditions found in the deep Entrada/Navajo Sandstone aquifer also reinforce this concept of hydraulic isolation from the shallow perched system. See the discussion on page 2 of the 2004 Statement of Basis. 2.11.2 Background Ground Water Quality in the Perched Aquifer This Section describes the groundwater quality in the perched aquifer. See Sections 2.5.1.3, 2.5.1.4 and 2.5.1.5 above for a more detailed description of the perched aquifer itself, the depth to ground water, the saturated thickness, flow direction, porosity, hydraulic conductivity and flow system characteristics of the perched aquifer. As mentioned in Section 2.9.1.5 above, a significant amount of historic groundwater quality data had been collected by EFRI and previous operators of the Mill for many wells at the facility. However, at the time of original issuance of the Permit, the Director had not yet completed an evaluation of the historic data, particularly with regard to data quality, and quality assurance issues. The Director also noted several groundwater quality issues that needed to be resolved prior to a determination of background groundwater quality at the site, such as a number of constituents that exceeded their respective GWQS and long term trends in uranium in downgradient wells MW -14, MW -15 and MW -17, and a spatial high of uranium in those three downgradient wells. As a result of the foregoing, the Director required that the Existing Well Background Report be prepared to address and resolve these issues. DUSA prepared the Existing Well Background Report that evaluated all historic data for the thirteen existing wells for the purposes of establishing background groundwater quality at the site and developing groundwater compliance limits GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the Existing Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells based primarily on the analysis performed in the Existing Well background Report. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would 55 normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. As required by the Permit, the Existing Well Background Report addressed all available historic data, which includes pre-operational and operational data, for the compliance monitoring wells under the Permit that were in existence at the date of issuance of the Permit. The Regional Background Report focuses on the pre-operational site data and the available regional data to develop the best available set of background data that could not have been influenced by Mill operations. The New Well Background Report, which was required by the Permit, analyzed the data collected from the new wells, which were installed in 2005, to determine background concentrations for constituents listed in the Permit for each new well. The Existing Well Background Report and the New Well Background Report were prepared to satisfy several objectives. First, in the case of the Existing Well Background Report, to perform a quality assurance evaluation and data validation of the existing and historical on-site groundwater quality data in accordance with the requirements of the Permit, and to develop a database consisting of historical groundwater monitoring data for "existing" wells and constituents. Second, in the case of the New Well Background Report, to compile a database consisting of monitoring results for new wells, which were collected subsequent to issuance of the Permit, in accordance with the Mill's QAP data quality objectives. Third, to perform a statistical, temporal and spatial evaluation of the existing well and new well data bases to determine if there have been any impacts to groundwater from Mill activities. Since the Mill is an existing facility that has been in operation since 1980, such an analysis of historic groundwater monitoring data was required in order to verify that the monitoring results to be used to determine background groundwater quality at the site and GWCLs have not been impacted by Mill activities. Finally, since the analysis demonstrated that groundwater has not been impacted by Mill activities, to develop a GWCL for each constituent in each well. The Regional Background Report was prepared as a supplement to the Existing Well Background Report to provide further support to the conclusion that Mill activities have not impacted groundwater. In evaluating the historic data for the existing wells, INTERA used the following approach: • If historic data for a constituent in a well do not demonstrate a statistically significant upward trend, then the proposed GWCL for that constituent is accepted as representative of background, regardless of whether or not the proposed GWCL exceeds the GWQS for that constituent. This is because the monitoring results for the constituent can be considered to have been consistently representative since commencement of Mill activities or installation of the well; and 56 • If historic data for a constituent in a monitoring well represent a statistically significant upward trend or downward trend in the case of pH, then the data is further evaluated to determine whether the trend is the result of natural causes or Mill activities. If it is concluded that the trend results from natural causes, then the GWCL proposed in the Existing Well Background Report will be appropriate. After applying the foregoing approach, JNTERA concluded that, other than some detected chloroform and related organic contamination at the Mill site, which is the subject of a separate investigation and remedial action, and that is the result of pre-Mill activities, and some elevated nitrate concentrations in certain wells which were considered to be associated with the chloroform plume, there have been no impacts to groundwater from Mill activities (See Section 2.16.1 below relating to the chloroform contamination and Section 2.16.2 relating to the nitrate contamination). In reaching this conclusion, JNTERA noted that, even though there are a number of increasing trends in various constituents at the site, none of the trends are caused by Mill activities, for the following reasons: • There are no noteworthy correlations between chloride and uranium in wells with increasing trends in uranium, other than in upgradient wells MW-19 and MW-18, which JNTERA concluded are not related to any potential tailings seepage. JNTERA noted that it is inconceivable to have an increasing trend in any other parameter caused by seepage from the Mill tailings without a corresponding increase in chloride; • There are significant increasing trends upgradient in MW-1, MW-18 or MW-19 in uranium, sulfate, TDS iron, selenium, thallium, ammonia and fluoride and far downgradient in MW-3 in uranium and selenium, sulfate, TDS and pH (decreasing trend). JNTERA concluded that this provides very strong evidence that natural forces at the site are causing increasing trends in these constituents (decreasing in pH) in other wells and supports the conclusion that natural forces are also causing increasing trends in other constituents as well; and • On a review of the spatial distribution of constituents, it is quite apparent that the constituents of concern are dispersed across the site and not located in any systematic manner that would suggest a tailings plume. JNTERA concluded that, after extensive analysis of the data, and given the conclusion that there have been no impacts to groundwater from Mill activities, the GWCLs set out in Table 16 of the Existing Well Background Report are appropriate, and are indicative of background ground water quality. JNTERA did advise, however, that proposed GWCLs for all the trending constituents should be re-evaluated upon Permit renewal to determine if they are still appropriate at the time of renewal. See Table 16 of the Existing Well Background Report for JNTERA's calculation of background ground water quality as represented by the proposed GWCLs. See Section 6.0 of the Existing Well Background Report for a discussion of the statistical manner used to calculate each proposed GWCL. Upon approval of the Existing Wells Background Report, the Director required that the New Well Background Report be prepared to address and resolve similar issues in the newer wells. 57 EFRI prepared the New Well Background Report that evaluated all historic data for the nine new wells for the purposes of establishing background groundwater quality at the site and developing GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the New Well Background Report, the GWCLs for the new wells were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. In evaluating the new well data, INTERA used the same approach in the New Well Background Report that was used in the Existing Well Background Repmt for existing well data. In addition, INTERA compared the groundwater monitoring results for the new wells to the results for the existing wells analyzed in the Existing Well Background Report and to the pre-operational and regional results analyzed in the Regional Background Report. This was particularly important for the new wells because there is no historic data for any constituents in those wells dating back to commencement of Mill operations. A long-term trend in a constituent may not be evident from the available data for the new wells. By comparing the mean concentrations of the constituents in the new wells to the results for the existing wells and regional background data, INTERA was able to determine if the constituent concentrations in the new wells were consistent with background at the site. INTERA concluded that after applying the foregoing approach, there have been no impacts to groundwater in the new monitoring wells from Mill activities. INTERA concluded that the groundwater monitoring results for the new wells are consistent with the results for the existing wells analyzed in the Existing Well Background Report and for the pre-operational and regional wells, seeps and springs analyzed in the Regional Background Report. INTERA noted that there were some detections of chloroform and related organic contamination and degradation products and nitrate and nitrite in the new wells, which are now the subject of two separate investigations (see Sections 2.16.1 and 2.16.2), but that such contamination was the result of pre-Mill activities. As a result, given the conclusion that there have been no impacts to groundwater from Mill activities, INTERA concluded that the calculated GWCLs for new wells set out in Table 10 of the New Well Background Report are appropriate, and are indicative of background ground water quality. Again, INTERA noted that GWCLs for trending constituents should be re- evaluated upon Permit renewal to determine if they are still appropriate at the time of renewal. Additionally, the Flow Sheet states to "Consider an Alternate Approach" for determination of GWCLs in trending constituents. In its report, INTERA recommended, as an alternative, that GWCLs be set at the highest of a) the Flow Sheet approach, b) the highest historical value or c) the fractional approach; provided that in no event would the GWCL be less than mean plus 20% . This approach was rejected by the DRC in favor of the mean plus two standard deviation or equivalent. See Table 10 of the New Well Background Report for INTERA's calculation of background ground water quality as represented by the proposed GWCLs. See Section 2.2 of the New Well Background Report for a discussion of the statistical manner used to calculate each proposed GWCL. The University of Utah Study confirmed INTERA's conclusions in the Background Reports that groundwater at the site has not been impacted by Mill operations (see the discussion in Section 1.3 above). 58 The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the nine new wells based primarily on the analysis performed during the New Well Background Report. It should be noted, however, that, because the GWCLs were set at the mean plus two standard deviations, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. Part I.G.2 of the Permit provides that out-of-compliance status exists when the concentration of a pollutant in two consecutive samples from a compliance monitoring point exceeds a GWCL in Table 2 of the Permit. Per the requirements of Part I.G.4(c) of the Permit, EFRI is required to prepare and submit written plans and time schedules, for Director approval, to fully comply with the requirements of Part I.G.4(c) of the Permit relating to any such out-of-compliance situation, including, but not limited to: (i) submittal of a written assessment of the source(s); (ii) submittal of a written evaluation of the extent and potential dispersion of said groundwater contamination; and (iii) submittal of a written evaluation of any and all potential remedial actions to restore and maintain ground water quality at the facility, for the point of compliance wells and contaminants in question, to ensure that: 1) shallow groundwater quality at the facility will be restored and 2) the contaminant concentrations in said point of compliance wells will be returned to and maintained in compliance with their respective GWCLs. Seven Plans and Time Schedules and six Source Assessment Reports ("SARs") have been submitted to address consecutive exceedances other than pH which have been noted in wells since the establishment of the GWCLs in the January 20, 2010 GWDP. The Plans and Time Schedules and the SARs are included in Table 2.11.2-1. These Plans and Time Schedules and SARs were previously submitted under separate cover. On July 12, 2012, EFRI and the Director entered into a Stipulated Consent Agreement relating to the implementation of the June 13, 2011 Plan and Time Schedule and the September 7, 2011 Plan and Time Schedules. The Stipulated Consent Agreement required the completion of a SAR to meet the requirements of the June 13, 2011 Plan and Time Schedule and the September 7, 2011 Plan and Time Schedules. Subsequent Plan and Time Schedules submitted to the Director have been approved by the Director in letters to EFRI. The submission dates and the associated DRC approval dates of the Plans and Time Schedules and the associated SARs are listed on Table 2.11.2-1. Given the varied background groundwater quality at the site, previously identified rising trends in some wells and other factors, it cannot be assumed that consecutive exceedances of a constituent in a monitoring well means that contamination has been introduced to groundwater in that well. The exceedances may very well be the result of background influences. The approach 59 in these Plans therefore is to first determine if the recent exceedances are the result of background influences. If they are determined to be the result of background influences, then no remedial actions are required. If, however, they are determined to not be the result of natural background influences, then further analyses will be required. Based on the information available at this time, EFRI believes that the GWCL exceedances observed are the result of natural influences and reflect the need to adjust some of the GWCLs for the site. 2.11.3 GWCL Determination for Field pH During the completion of the 4th Quarter 2010 Quarterly Groundwater Monitoring Report, EFRI noted eleven perched groundwater monitoring wells with pH measurements below the GWCLs. These wells are located upgradient, cross-gradient, and downgradient of the Mill and tailings cells. Investigation into the eleven pH GWCLs in question indicated that the GWCLs for groundwater pH in all wells established in the January 20, 2010 GWDP were erroneously based on historic laboratory results instead of field measurements as contemplated by Table 2 of the GWDP. EFRI notified DRC that the existing GWCLs for groundwater pH were incorrectly based on laboratory results rather than field measurements and proposed to submit revised descriptive statistics for field pH to be used as revised pH GWCLs by the end of the second quarter 2011. EFRI received approval from DRC to proceed with the revision of the pH GWCLs based on field measurements. The data processing and statistical assessments necessary to revise the GWCLs based on historic field pH data were completed. The data processing and statistical assessments completed were based on the DRC-approved methods in the logic flow diagram included as Figure 17 of the New Well Background Report. Following the statistical evaluation of pH data, EFRI compared the Mill's groundwater pH data from the 2nd Quarter of 2011, including accelerated sampling results through June 2011, and noted that all of the June 2011 groundwater results, and many of the other results from the 2nd Quarter, were already outside the revised GWCLs to be proposed based on the logic flow diagram. It was noted that the historical trend of decreasing pH, which was addressed in the Background Study Reports, appeared to be present in nearly all wells throughout the Mill site area, including upgradient, downgradient, and cross-gradient wells in the groundwater monitoring program. As of June 2011, all groundwater monitoring wells demonstrated a downward trend in the field pH data over time. EFRI notified DRC that the 2nd Quarter 2011 data exceeded the recalculated GWCLs. EFRI advised DRC that, as a result of these findings, EFRI did not believe it was appropriate to continue with its efforts to reset the GWCLs for pH based on field pH data, as originally planned, but instead it appeared that it would be more appropriate to undertake a study to determine whether the decreasing trends in pH are due to natural influences and, if so, to determine a more appropriate way to determine GWCLs. EFRI and DRC agreed on further investigations to be completed, as well as the steps and milestone dates to be incorporated into a pH Report. The procedures for investigating the decreasing site-wide pH trends is documented in the Plan to Investigate pH Exceedances in 60 Perched Groundwater Monitoring Wells White Mesa Uranium Mill Blanding, Utah, Prepared by Hydro Geo Chern, Inc, April 13, 2012 (the "pH Plan and Time Schedule"). The pH Plan and Time Schedule described the pH investigation, which was incorporated into the July 12, 2012 Stipulated Consent Agreement referred to above. The pH Plan and Time Schedule was previously submitted under separate cover. The Stipulated Consent Agreement of July 12, 2012 specified that a pH Report be completed as well as a separate investigation into the natural phenomenon that was causing the site-wide trend. As a result, two reports investigating and describing the causes of the pH trend were completed. These reports are the pH Report, dated November 9, 2012 (INTERA, 2012b) and the Investigation of Pyrite in the Perched Zone, White Mesa Uranium Mill ("Pyrite Report"), dated December 7, 2012 (HGC, 2012b). The pH Report consists of a statistical and geochemical evaluation of the decline in pH in groundwater wells at the Mill. The primary conclusion from the pH Report was that the historical trend of decreasing pH, which was addressed in the Background Study Reports, appears to be present in nearly all wells throughout the Mill site area, including upgradient, downgradient, and crossgradient wells in the groundwater monitoring program, and there seems to be no abatement of the trend. The wide-spread nature of the decrease in pH in upgradient, downgradient, and crossgradient wells suggests that the pH decreases result from a natural phenomenon unrelated to Mill operations, which is also confirmed by the indicator parameter analysis conducted as part of the pH Report. As discussed in The Pyrite Report, the most likely cause of declining pH across the site appears at this time to be the oxidation of pyrite, possibly due to increasing water levels at the site attributed primarily to recharge of wildlife ponds and/or the introduction of oxygen into the perched water zone as a result of increased groundwater sampling frequency. Based on the conclusion that the pH trend was caused by natural phenomenon, the pH Report recalculated the Groundwater Compliance Limits ("GWCLs") for all compliance monitoring wells at the site. The Pyrite Report evaluated and quantified the presence of pyrite throughout the Mill site, and identified and quantified the mechanism by which it contributes to the sitewide decline in pH. The results of the investigation support pyrite oxidation as the most likely mechanism to explain decreases in pH and increases in sulfate concentrations in site wells and indicates that pyrite must be considered in assessing perched water chemistry in the future. The complex interaction of the various naturally occurring factors identified at the site, including the presence of pyrite at varying concentrations, variable oxygen transport, and variable carbonate species concentrations, is expected to result in relatively large background variations in pH, sulfate (and therefore TDS) concentrations, as well as variations in background concentrations of pH sensitive analytes such as metals. The expected impact of these various factors on pH and analyte concentrations, all of which are unrelated to Mill operations, is generally consistent with site analytical results, suggesting that pyrite oxidation plays a significant role in perched water chemistry at the site. The primary conclusion from the activities conducted to date and described above is that the pH trends are not due to potential tailings leakage or Mill activities, but to a natural phenomenon unrelated to Mill operations. 61 In an effort to diminish any trends that may have resulted in whole or in part, from increasing water levels attributed to the Wildlife ponds at the Mill, EFRI discontinued recharging the two most northern of these ponds, commencing in March 2012. 2.11.4 Quality of Ground Water at the Compliance Monitoring Point The analytical results from groundwater sampling are reported quarterly in Groundwater Monitoring Reports, which are filed with the Director pursuant to Part I.F.1 of the Permit. 2.12 Compliance Sampling PJan (R317-6-6.3.L) The Mill's plan for sampling groundwater compliance monitoring points is discussed in detail in Section 2.9 .1.3 above, and the plan for sampling the leak detection systems in Cells 4A and 4B is discussed in Section 2.15.3 below. This section addresses other sampling required under the Permit. As the Mill is designed not to discharge to groundwater, there are no flow monitoring requirements in the Permit. 2.12.1 Tai1ings CeH Wastewater Qua]ity Sampling PJan Part I.E.10 of the Permit requires that, on an annual basis, EFRI collect wastewater quality samples from each wastewater source at each tailings cell at the facility, including wastewaters in surface impoundments, and slimes drains. The sampling is conducted in August of each calendar year in compliance with an approved plan. The Tailings SAP (dated July 30, 2012) was approved by the Director on August 2, 2012. A copy of the approved Tailings and Slimes Drain Sampling Program, Revision 2.1, July 30,2012 is attached as Appendix L to this Application. The purpose of the Tailings SAP is to characterize the source term quality of all tailings cell wastewaters, including impounded wastewaters or process waters in the tailings cells, and wastewater or leachates collected by internal slimes drains. The Revision 2.1, Tailings SAP requires: • Collection of samples from the pond area of each active cell and the slimes drain of each cell that has commenced de-watering activities; • Samples of tailings and slimes drain material will be analyzed at an offsite contract laboratory and subjected to the analytical parameters included in Table 2 of the Permit and general inorganics listed in Part I.E.1(d)(2)(ii) of the Permit, as well as semi-volatile organic compounds; • A detailed description of all sampling methods and sample preservation techniques to be employed; • The procedures utilized to conduct these analyses will be standard analytical methods utilized for groundwater sampling and as shown in Section 8.2 of the QAP; • The contracted laboratory will be certified by the State of Utah in accordance with UAC R317 -6-6.12A; and • 30-day advance notice of each annual sampling event must be given, to allow the Director to collect split samples of all tailings cell wastewater sources. 62 The tailings and slimes drain sampling events are subject to the currently approved QAP, unless otherwise specifically modified by the Tailings SAP to meet the specific needs of this type of sampling. The QAP has been approved by the Director and satisfies the most applicable requirements of the following references, unless otherwise specified by the Director through his approval of the Tailings SAP: • Standard Methods for the Examination of Water and Wastewater, twentieth edition, 1998; Library of Congress catalogue number: ISBN: 0-87553-235-7; • E.P.A. Methods for Chemical Analysis of Water and Wastes, 1983; Stock Number EPA- 600/4-79-020; • Techniques of Water Resource Investigations of the U.S. Geological Survey, (1998); Book 9; • Monitoring requirements in 40 CFR parts 141 and 142, 2000 ed., Primary Drinking Water Regulations and 40 CFR parts 264 and 270, 2000 ed.; and • National Handbook of Recommended Methods for Water-Data Acquisition, GSA-GS edition; Book 85 AD-2777, U.S. Government Printing Office Stock Number 024-001- 03489-1. 2.12.2 White Mesa Seeps and Springs Sampling Plan The initial Permit required EFRI to submit a plan for groundwater sampling and analysis of all seeps and springs found downgradient or cross gradient from the tailings cells for Director review and approval. The Director approved the plan on March 17, 2009. A copy of the Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill, Revision: 1, June 10, 2011, is attached as Appendix C to this Application. As of this writing, Revision 1.0 of this SAP is undergoing review by the Director. Under the Seeps and Springs SAP, sampling is conducted on an annual basis between May 1 and July 15 of each year, to the extent sufficient water is available for sampling, at six identified seeps and springs near the Mill. The sampling locations were selected to correspond with those seeps and springs sampled for the initial Mill site characterization performed in the 1978 ER, plus additional sites located by EFRI, the United States Bureau of Land Management and Ute Mountain Ute Indian Tribe representatives. Samples are analyzed for all groundwater monitoring parameters found in Table 2 of the Permit. The laboratory procedures utilized to conduct the analyses of parameters listed in Table 2 are the same as utilized for groundwater sampling and as shown in Section 8.2 of the QAP. In addition to these laboratory parameters, the pH, temperature and conductivity of each sample will be measured and recorded in the field. Laboratories selected by EFRI to perform analyses of seeps and springs samples are required to be certified by the State of Utah in accordance with UAC R317-6-6.12.A. The seeps and springs sampling events are subject to the currently approved QAP, unless otherwise specifically modified by the Seeps and Springs SAP to meet the specific needs of this type of sampling. The QAP has been approved by the Director and satisfies the applicable requirements of the references listed in Section 2.12.1 above, unless otherwise specified by the Director through his approval of the Seeps and Springs SAP. 63 2.12.3 Monitoring of Deep Wells Due to the fact that the deep confined aquifer at the site is hydraulically isolated from the shallow perched aquifer (see the discussion in Section 2.11.1 above) monitoring of the deep aquifer is not required under the Permit. 2.13 Description of the Flooding Potential of the Discharge Site (R317 -6-6.3.M) 2.13.1 Surface Water Characteristics The Mill site is located on White Mesa, a gently sloping (1% SSW) plateau that is physically defined by the adjacent drainages which have cut deeply into regional sandstone formations. There is a small drainage area of approximately 62 acres (25 ha) above the site that could yield surface runoff to the site. Runoff from the mesa is conveyed by the general surface topography to either Westwater Creek, Corral Creek, or to the south into an unnamed branch of Cottonwood Wash. Local porous soil conditions, topography and low average annual rainfall of 13.3 inches (reported as 11.8 by Dames and Moore in historic reports) cause these streams to be intermittently active, responding to spring snowmelt and local rainstorms (particularly thunderstorms). Surface runoff from approximately 624 acres of the Mill drains westward and is collected by Westwater Creek, and runoff from another 384 acres drains east into Corral Creek. The remaining 4,500 acres of the southern and southwestern portions of the site drain indirectly into Cottonwood Wash (1978 ER, p. 2-143). The site and vicinity drainages carry water only on an intermittent basis. The major drainages in the vicinity of the Mill are depicted in Figure 12 and their drainage areas are tabulated in Table 2.13.1-1. Total runoff from the mesa (total yield per watershed area) is estimated to be less than 0.5 inch annually (1978 ER, p. 2-143). There are no perennial surface waters on or in the vicinity of the Mill site. This is due to the gentle slope of the mesa on which the site is located, the low average annual rainfall of 13.3 inches per year at Blanding, local soil characteristics and the porous nature of local stream channels. Prior to Mill construction, three small ephemeral catch basins were present to the northwest and northeast of the Mill site. Corral Creek is an intermittent tributary to Recapture Creek. The drainage area of that portion of Corral Creek above and including drainage from the eastern portion of the site is about 5 square miles. Westwater Creek is also an intermittent tributary of Cottonwood Wash. The Westwater Creek drainage basin covers nearly 27 square miles at its confluence with Cottonwood Wash 1.5 miles west of the Mill site. Both Recapture Creek and Cottonwood Wash are similarly intermittently active, although they carry water more often and for longer periods of time due to their larger watershed areas. They both drain to the south and are tributaries of the San Juan River. The confluences of Recapture Creek and Cottonwood Wash with the San Juan River are approximately 18 miles south of the Mill site. The San Juan River, a major tributary for the upper Colorado River, has a drainage of 23,000 square miles measured at the USGS gauge to the west of Bluff, Utah (1978 ER, p. 2-130). Storm runoff in these streams is characterized by a rapid rise in flow rates, followed by rapid recession primarily due to the small storage capacity of the surface soils in the area. For 64 example, on August 1, 1968, a flow of 20,500 cubic feet per second was recorded in Cottonwood Wash near Blanding. The average flow for that day, however, was only 4,340 cfs. By August 4, the flow had returned to 16 cfs (1978 ER, p. 2-135). Monthly streamflow summaries as updated from Figure 2.4 of the FES are presented in Figure 13 for Cottonwood Wash, Recapture Creek and Spring Creek. Flow data are not available for the two smaller water courses closest to the Mill site, Corral Creek and Westwater Creek, because these streams carry water infrequently and only in response to local heavy rainfall and snowmelt, which occurs primarily in the months of April, August, and October. Flow typically ceases in Corral Creek and Westwater Creek within 6 to 48 hours after precipitation or snowmelt ends. 2.13.2 Flood Protection Measures The Mill was designed and constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the tailings cells; and b) diverting runoff from surrounding areas away from the Mill site via three drainage ditches that have been constructed north (upslope) of the Mill facility. , A detailed description of the flooding potential of the site, including the 6-hour probable maximum precipitation (which is more conservative than the 100-year flood plain), and applicable flood protection measures is provided in the UMETCO Minerals Corporation: White Mesa Mill Drainage Report for Submittal to NRC, January 1990. In addition to the foregoing designed control features, the facility has developed a Stormwater Best Management Practices Control Plan which includes a description of the site drainage features and the best management practices employed to ensure appropriate control and routing of stormwater. A copy of the Mill's Stormwater Best Management Practices Plan is included as Appendix G to this Application. 2.14 Contingency Plan (R317-6-6.3.N) As required by Part I.H.15 of the Permit, the Mill has a Contingency Plan for regaining and maintaining compliance with the Permit limits and for re-establishing best available technology as defined in the Permit. A copy of the most cmrent approved version of the Mill's Contingency Plan is included as Appendix M to this Application. 2.15 Methods and Procedures for Inspections of the Facility Operations and for Detecting Failure of the System (R317-6-6.3.0) Part I.D. of the Permit sets out a number of DMT and BAT standards that must be followed. Part I.E. of the Permit sets out the Ground Water Compliance and Technology Performance Monitoring requirements, to ensure that the DMT and BAT standards are met. These provisions of the Permit, along with the DMT Plan, Cell 4A and Cell 4B BAT Monitoring Operations and Maintenance Plan and other plans and programs developed pursuant to these Parts, set out the methods and procedures for inspections of the facility operations and for detecting failure of the system. 65 In addition to the programs discussed above, the following additional DMT and BAT performance standards and associated monitoring are required under Parts I.D and I.E. of the Permit 2.15.1 Existing Tailings Cel1 Operation Part I.D.2 of the Permit provides that authorized operation and maximum disposal capacity in each of the existing tailings Cells, 1, 2 and 3 shall not exceed the levels authorized by the Mill License and that under no circumstances shall the freeboard be less than three feet, as measured from the top of the FML. Part I.E.7(a) of the Permit requires that the wastewater pool elevations in Cells 1 and 3 must be monitored weekly to ensure compliance with the maximum wastewater elevation criteria mandated by Condition 10.3 of the Mill License. However, a letter from the Director dated January 27, 2011, which approved the use of Cell 4B, and a subsequent letter dated March 14, 2011, stated that authorization of the use of Cell 4B and approval of the DMT and Cell 4A Operations and Maintenance ("O&M") Plans effectively eliminated the former freeboard elevation requirements for tailings Cell 3. Part I.D.2 further provides that any modifications by EFRI to any approved engineering design parameter at these existing tailings cells requires prior Director approval, modification of the Permit and issuance of a construction permit. 2.15.2 Existing Facility DMT Performance Standards Part I.D.3 of the Permit requires EFRI to operate and maintain certain Mill site facilities and the existing tailings disposal cells to minimize the potential for wastewater release to groundwater and the environment, including, but not limited to the following additional DMT measures: 2.15.2.1 DMT Monitoring Wells at Cells 1, 2 and 3 Parts I.D.3 (a) and (d) require that at all times EFRI operate and maintain Cells 1, 2 and 3 to prevent groundwater quality conditions in any nearby monitoring wells from exceeding the GWCLs in Table 2 of the Permit. The groundwater compliance monitoring program described in detail in Section 2.9.1.3, is designed to provide early detection of a system failure in these tailings cells. 2.15.2.2 Slimes Drain Monitoring Part I.D.3(b)(l) of the Permit requires that EFRI at all times maintain the average wastewater head in the slimes drain access pipe to be as low as reasonably achievable (ALARA) in each tailings disposal cell, in accordance with the approved DMT Plan. Compliance is achieved when the average annual wastewater recovery elevation in the slimes drain access pipe, determined pursuant to the currently approved DMT Plan, meets the conditions in Equation 1of Part I.D.3(b)(3) of the Permit. Part I.E.7(b) of the Permit requires that EFRI monitor and record quarterly the depth to wastewater in the slimes drain access pipes as described in the currently approved DMT Plan at Cell 2, and upon commencement of de-watering activities, at Cell 3, in order to ensure 66 compliance with Part I.D.3(b)(3) of the Permit. At this time, de-watering of Cell 3 has not commenced. Quarterly measurements of the wastewater head in Cell 2 are reported in the quarterly DMT reports submitted to DRC pursuant to the requirements of Part I.F.1, Table 7 of the GWDP. The historic measurements for 2009 through 2013 are included in Appendix J. Annual compliance calculations pursuant to Part I.D.3(b)(3) of the GWDP are submitted to DRC on or before March 1 of the following year. The annual compliance calculations submitted to date for Cell 2 are summarized in Appendix J. As noted in Appendix J, annual slimes drain compliance was not achieved for 2010, in accordance with Part I.D.3 of the Permit. As noted in correspondence with DRC, the monthly monitoring requirements specified in Part I.D.3(b)(2) of the February 2011 revision of the GWDP seriously interfered with EFRI's ability to comply with Parts I.D.3(b)(i) and I.D.3 (b)(3) of the GWDP. The monthly testing requirement resulted in the slimes drain pump being off (not pumping) an average of 6.42 days per month every month which is equivalent to 77 days (11 weeks) per year or 20 percent of the year for performance of the measurements. The GWDP was amended in July 2011 to change the frequency of the slimes drain testing from monthly to quarterly. The average annual wastewater recovery elevation in the slimes drain pipe has been in compliance (that is, less than the previous year's running average) since the monitoring frequency changed from monthly to quarterly in July 2011. 2.15.2.3 Maximum Tailings Waste Solids Elevation Part I.D.3(c) of the Permit requires that upon closure of any tailings cell, EFRI must ensure that the maximum elevation of the tailings waste solids does not exceed the top of the FML liner. 2.15.2.4 Wastewater Elevation in Roberts Pond Part I.D.3(e) of the Permit requires that Roberts Pond be operated so as to provide a minimum 2- foot freeboard at all times, and that under no circumstances will the water level in the pond exceed an elevation of 5,624 feet above mean sea level. Part I.D.3(e) also provides that in the event the wastewater elevation exceeds this maximum level, EFRI must remove the excess wastewater and place it into containment in Cell 1 within 72 hours of discovery. Part I.E.7(c) of the Permit requires that the wastewater level in Roberts Pond must be monitored and recorded weekly, in accordance with the currently approved DMT Plan, to determine compliance with the DMT operations standard in Part I.D.3( e) of the Permit; 2.15.2.5 Inspection of Feedstock Storage Area Part I.D.3(f) of the Permit requires that open-air or bulk storage of all feedstock materials at the Mill facility awaiting Mill processing must be limited to the eastern portion of the Mill site (the "ore pad") described by the coordinates set out in that Part of the Permit, and that storage of feedstock materials at the facility outside of this defined area, must meet the requirements of Part I.D.11 of the Permit. Part I.D.ll requires EFRI to store and manage feedstock materials outside the defined ore storage pad in accordance with an approved Feedstock Management Plan. On 67 June 20, 2008, EFRI submitted a White Mesa Mill Containerized Alternate Feedstock Material Storage Procedure for Director review and approval. A copy of that procedure is included as Appendix N to this Application. The Director is currently reviewing that procedure. Part I.E.7(d) of the Permit requires that EFRI inspect the feedstock storage areas weekly to: a) Confirm that the bulk feedstock materials are maintained within approved feedstock storage defined by Table 4 of the Permit; and b) Verify that all alternate feedstock materials located outside the feedstock storage area defined in Table 4 are stored in accordance with the requirements found in Part I.D.11. Part I.E.7(d) further provides that EFRI must implement the Feedstock Material Storage Procedure immediately upon Director approval. The Mill's procedure under the Mill License for inspection of the Mill's ore pad is contained in Section 3.3 of the DMT Plan, a copy of which is attached as Appendix H to this Application. 2.15.2.6 Monitor and Maintain Inventory of Chemicals Part I.D.3(g) of the Permit requires , EFRI to provide secondary containment to capture and contain all volumes of reagent(s) that might be released at any individual storage area. This requirement applies to all chemical reagents stored at existing storage facilities and held for use in the milling process. Response to spills, cleanup thereof, and required reporting must comply with the provisions of an approved Emergency Response Plan as found in the approved Stormwater Best Management Practices Plan, stipulated by Parts I.D.10 and I.D.3(g) of the Permit. Part I.D.3(g) further provides that for any new construction of reagent storage facilities, such secondary containment and control must prevent any contact of the spilled or otherwise released reagent or product with the ground surface. Part I.E.9 of the Permit requires that EFRI monitor and maintain a current inventory of all chemicals used at the facility at rates equal to or greater than 100 kg/yr. This inventory is to be maintained on-site, and must include: (i) Identification of chemicals used in the milling process and the on-site laboratory; and (ii) Determination of volume and mass of each raw chemical currently held in storage at the facility. A copy of the Mill's chemical Inventory is attached as Appendix 0 to this Application. A copy of the Mill's Stormwater Best Management Practices Plan, Revision 1.5; September 2012 is attached as Appendix G to this Application. 68 2.15.3 BAT Performance Standards for Cell 4A 2.15.3.1 BAT Operations and Maintenance Plan Part I.D.6 of the GWDP requires EFRI to operate and maintain Cell4A so as to prevent release of wastewater to groundwater and the environment in accordance with a BAT Operations and Maintenance Plan. At a minimum such plan must include the following performance standards: a) The fluid head in the leak detection system shall not exceed 1 foot above the lowest point in the lower membrane liner; b) The leak detection system maximum allowable daily leak rate shall not exceed 24,160 gallons/day; c) After EFRI initiates pumping conditions in the slimes drain layer in Cell 4A, EFRI will provide continuous declining fluid heads in the slimes drain layer, in a manner equivalent to the requirements found in Part I.D.3(b) for Cells 2 and 3; and d) Under no circumstances shall the freeboard be less than 3-feet in Cell 4A, as measured from the top of the FML. The BAT Operations and Maintenance Plan required under Part I.D.6 was approved by the Director on December 21, 2011. A copy of the most current! y-approved BAT Operations and Maintenance Plan is included as Appendix F to this Application. 2.15.3.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan Part I.E.8 of the Permit provides that, after Director approval of the Tailings Cell 4A BAT Operations and Maintenance Plan, EFRI must immediately implement all monitoring and recordkeeping requirements contained in the plan. At a minimum, such BAT monitoring shall include: a) Weekly Leak Detection System (LDS) Monitoring-including: (i) continuous operation of the leak detection system pumping and monitoring equipment, including, but not limited to, the submersible pump, pump controller, head monitoring, and flow meter equipment approved by the Director. Failure of any pumping or monitoring equipment not repaired and made fully operational within 24-hours of discovery shall constitute failure of BAT and a violation of the Permit; (ii) measurement of the fluid head above the lowest point on the secondary FML by the use of procedures and equipment approved by the Director. Under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower FML on the cell floor. For purposes of 69 compliance monitoring this 1-foot distance shall equate to 2.28 feet above the leak detection system transducer; (iii) measurement of the volume of all fluids pumped from the leak detection system. Under no circumstances shall the average daily leak detection system flow volume exceed 24,160 gallons/day; and (iv) operation and maintenance of wastewater levels to provide a 3-foot Minimum of vertical freeboard in tailings Cell 4A. Such measurements must be made to the nearest 0.1 foot. b) Slimes Drain Recovery Head Monitoring Immediately after the Mill initiates pumping conditions in the Cell 4A slimes drain system, monthly recovery head tests and fluid level measurements are to be made in accordance with the requirements of Parts I.D.3 and I.E.7(b) of the Permit and any plan approved by the Director. 2.15.4 BAT Performance Standards for Cell 4B 2.15.4.1 BAT Operations and Maintenance Plan Part I.D.13 requires EFRI to operate and maintain Cell 4B so as to prevent release of wastewater to groundwater and the environment in accordance with a BAT Operations and Maintenance Plan, and that at a minimum such plan must include the following performance standards: e) The fluid head in the leak detection system shall not exceed 1 foot above the lowest point in the lower membrane liner; f) The leak detection system maximum allowable daily leak rate shall not exceed 26,145 gallons/day; g) After EFRI initiates pumping conditions in the slimes drain layer in Cell 4B, EFRI will provide continuous declining fluid heads in the slimes drain layer, in a manner equivalent to the requirements found in Part I.D.3(b) for Cells 2, 3 and 4A; and h) Under no circumstances shall the freeboard be less than 3-feet in Cell4B, as measured from the top of the FML. As mentioned above, the BAT Operations and Maintenance Plan was approved by the Director on December 21, 2011. A copy of the most currently-approved BAT Operations and Maintenance Plan, is included as Appendix F to this Application. 2.15.4.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan Part I.E.12 of the Permit provides that EFRI must implement all monitoring and recordkeeping requirements contained in the Tailings Cell 4B BAT Operations and Maintenance Plan. At a minimum, such BAT monitoring includes: c) Weekly Leak Detection System (LDS) Monitoring-including: 70 (i) continuous operation of the leak detection system pumping and monitoring equipment, including, but not limited to, the submersible pump, pump controller, head monitoring, and flow meter equipment approved by the Director. Failure of any pumping or monitoring equipment not repaired and made fully operational within 24-hours of discovery shall constitute failure of BAT and a violation of the Permit; (ii) measurement of the fluid head above the lowest point on the secondary FML by the use of procedures and equipment approved by the Director. Under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower FML on the cell floor. For purposes of compliance monitoring this 1-foot distance shall equate to 2.25 feet above the leak detection system transducer; (iii) measurement of the volume of all fluids pumped from the leak detection system. Under no circumstances shall the average daily leak detection system flow volume exceed 26,145 gallons/day; and (iv) operation and maintenance of wastewater levels to provide a 3-foot Minimum of vertical freeboard in tailings Cell 4B. Such measurements must be made to the nearest 0.1 foot. d) Slimes Drain Recovery Head Monitoring Immediately after the Mill initiates pumping conditions in the Cell 4B slimes drain system, monthly recovery head tests and fluid level measurements are to be made in accordance with the requirements of Parts I.D.3 and I.E.7(b) of the Permit and any plan approved by the Director. 2.15.5 Stormwater Management and Spill Control Requirements Part I.D.10 of the Permit requires EFRI to manage all contact and non-contact stormwater and control contaminant spills at the facility in accordance with an approved stormwater best management practices plan. Such plan must include the following minimum provisions: a) Protect groundwater quality or other waters of the state by design, construction, and/or active operational measures that meet the requirements of the Ground Water Quality Protection Regulations found in UAC R317-6-6.3(G) and R317-6-6.4(C); b) Prevent, control and contain spills of stored reagents or other chemicals at the Mill site; c) Cleanup spills of stored reagents or other chemicals at the Mill site immediately upon discovery; and d) Report reagent spills or other releases at the Mill site to the Director in accordance with UAC 19-5-114. The Mill's Stormwater Best Management Practices Plan dated June 12, 2008, was approved by the Director on July 1, 2008. A copy of the most recently approved Mill's Stormwater Best Management Practices Plan Revision dated 1.5 September 2012, is included as Appendix G to this Application. 71 2.15.6 Tailings and Slimes Drain Sampling Part I.E.1 0 of the Permit requires EFRI to annually collect wastewater quality samples from each wastewater source at each tailings cell at the facility, including surface impounded wastewaters, the leak detection systems (if present) and slimes drain wastewaters. All such sampling must be conducted in August of each calendar year in compliance with the approved Tailings Sampling Plan. See Section 2.12.1 above for a more detailed description of this program. The Mill's Tailings and Slimes Drain Sampling Program was approved by the Director. The most recently approved version is included as Appendix L to this Application. 2.15.7 Additional Monitoring and Inspections Required Under the Mill License Under the Mill License daily, weekly, and monthly inspection reporting and monitoring are required in accordance with NRC Regulatory Guide 8.31, Information Relevant to Ensuring that Occupational Radiation Exposures at Uranium Recovery Facilities will be As Low As is Reasonable Achievable, Revision 1, May 2002 ("Reg Guide 8.31"), by Section 2.3 of the Mill's ALARA Program and by the Mill's Environmental Protection Manual ("EPM"). These requirements are over and above the inspections described above that are required under the Permit. Additional daily, weekly, monthly, quarterly, and annual inspection and reporting requirements are specified in the EFRI DMT Plan and Tailings Management System Procedure (Section 3.1 of the EPM). The DMT Plan and Tailings Management System are included as Appendix H and Appendix I to this Application, respectively. 2.15.7.1 Daily Inspections Three types of daily inspections are performed at the Mill under the Mill License: a) Radiation Staff Inspections Paragraph 2.3.1 of Reg. Guide 8.31 provides that the Mill's Radiation Safety Officer ("RSO") or designated health physics technician should conduct a daily walk-through (visual) inspection of all work and storage areas of the Mill to ensure proper implementation of good radiation safety procedures, including good housekeeping that would minimize unnecessary contamination. These inspections are required by Section 2.3.1 of the Mill's ALARA Program, and are documented and on file in the Mill's Radiation Protection Office. b) Operating Foreman Inspections 30 CFR Section 56.18002 of the Mine Safety and Health Administration regulations requires that a competent person designated by the operator must examine each working place at least once each shift for conditions which may adversely affect safety or health. These daily inspections are documented and on file in the Mill's Radiation Protection Office. 72 c) Daily Tailings Inspection Section 3.1 of the Mill's EPM requires that during Mill operation, the Shift Foreman, or other person with the training specified in paragraph 2.4 of the Tailings Management Procedure, designated by the RSO, will perform an inspection of the tailings line and tailings area at least once per shift, paying close attention for potential leaks and to the discharges from the pipelines. Observations by the Inspector are recorded on the appropriate line on the Mill's Daily Inspection Data form. 2.15.7.2 Weekly Inspections Three types of weekly inspections are performed at the Mill under the Mill License: a) Weekly Inspection of the Mill Forms Paragraph 2.3.1 of Reg. Guide 8.31 provides that the RSO and the Mill foreman should, and Section 2.3.2 of the Mill's ALARA Program provides that the RSO and Mill foreman or their respective designees shall, conduct a weekly inspection of all Mill areas to observe general radiation control practices and review required changes in procedures and equipment. Particular attention is to be focused on areas where potential exposures to personnel might exist and in areas of operation or locations where contamination is evident. b) Weekly Ore Storage Pad Inspection Forms Paragraph 3.3 of the DMT Plan and Part I.E.7.(d of the Permit requires that weekly feedstock storage area inspections be performed by the Radiation Safety Department to confirm that the bulk feedstock materials are stored and maintained within the defined area of the ore pad and that all alternate feed materials located outside the defined ore pad area are maintained in accordance with the requirements of the Permit. The results of these inspections are recorded on the Mill's Ore Storage/Sample Plant Weekly Inspection Report. c) Weekly Tailings and DMT Inspection Section 3.1 of the EPM requires that weekly inspections of the tailings area and DMT requirements be performed by the radiation safety department. 2.15. 7.3 Monthly Reports Two types of monthly reports are prepared by Mill staff: a) Monthly Radiation Safety Reports The RSO reviews the results of daily and weekly inspections, including a review of all monitoring and exposure data for the month, and provides to the Mill Manager a monthly report containing a written summary of the month's significant worker protection activities (Section 2.3.4 of the ALARA Program). 73 b) Monthly Tailings Inspection Reports Section 3.1 of the EPM, requires that a Monthly Inspection Data form be completed for the monthly tailings inspection. This inspection is typically performed in the fourth week of each month and is in lieu of the weekly tailings inspection for that week. Mill staff also prepares a monthly summary of all daily, weekly, monthly and quarterly tailings inspections. 2.15.7.4 Quarterly Tailings Inspections Section 3.1 of the EPM requires that the RSO or his designee perform a quarterly tailings inspection. 2.15.7.5 Annual Evaluations The following annual evaluations are performed under the Mill License, as set out in Section 3.1 of the EPM. a) Annual Technical Evaluation An annual technical evaluation of the tailings management system must be performed by a registered professional engineer (PE), who has experience and training in the area of geotechnical aspects of retention structures. The technical evaluation includes an on-site inspection of the tailings management system and a thorough review of all tailings records for the past year. The Technical Evaluation also includes a review and summary of the annual movement monitor survey (see Section (b) below). All tailings cells and corresponding dikes are inspected for signs of erosion, subsidence, shrinkage, and seepage. The drainage ditches are inspected to evaluate surface water control structures. In the event tailings capacity evaluations were performed for the receipt of alternate feed material during the year, the capacity evaluation forms and associated calculation sheets will be reviewed to ensure that the maximum tailings capacity estimate is accurate. The amount of tailings added to the system since the last evaluation will also be calculated to determine the estimated capacity at the time of the evaluation. As discussed above, tailings inspection records consist of daily, weekly, monthly, and quarterly tailings inspections. These inspection records are evaluated to determine if any freeboard limits are being approached and to identify any areas of potential concern. The evaluation also involves discussion with the Environmental and/or Radiation Technician and the RSO regarding activities around the tailings area for the past year. During the annual inspection, photographs of the tailings area are taken. The training of individuals is also reviewed as a part of the Annual Technical Evaluation. 74 The registered engineer obtains copies of selected tailings inspections, along with the monthly and quarterly summaries of observations of concern and the corrective actions taken. These copies are then included in the Annual Technical Evaluation Report. The Annual Technical Evaluation Report must be submitted by September 1st of every year to the Directing Dam Safety Engineer, State of Utah, Natural Resources. b) Annual Movement Monitor Survey A movement monitor survey is conducted by a licensed surveyor annually during the second quarter of each year. The movement monitor survey consists of surveying monitors along dikes 3-S, 4A-W, and 4A-S to detect any possible settlement or movement of the dikes. The data generated from this survey is reviewed and incorporated into the Annual Technical Evaluation Report of the tailings management system. c) Annual Leak Detection Fluid Samples Annually, the leak detection system fluids in Cells 1, 2, 3, 4A and 4B are sampled when present as described in the Tailings Sampling Plan in Section 2.12.1. 2.16 Corrective Action Plan or Identification of Other Response Measures to be Taken to Remedy any Violation of Applicable Ground Water Quality Standards (R317-6-6.3.P) There are two circumstances where applicable groundwater standards have been exceeded at the site that are not associated with natural background: chloroform contamination, and nitrate contamination. As discussed below, none of these circumstances appear to be related to discharges from milling activities. See Section 2.11.2 for a discussion of the current investigation into exceedances of GWCLs for certain constituents and decreasing pH trends at the site, which EFRI believes are associated with natural background. 2.16.1 Chloroform Investigation In May, 1999, excess chloroform concentrations were discovered in monitoring well MW-4, which is screened in the shallow perched aquifer along the eastern margin of the Mill site. Because these concentrations were above the GWQS for chloroform, the Executive Secretary of the Utah Water Quality Board initiated enforcement action against the Mill on August 23, 1999 through the issuance of a Groundwater Corrective Action Order (UDEQ Docket No. UG0-20- 01), which required completion of: 1) a contaminant investigation report to define and bound the contaminant plume, and 2) a groundwater corrective action plan to clean it up. Repeated groundwater sampling by both the Mill and DRC have confirmed the presence of chloroform in concentrations that exceed the GWQS along the eastern margin of the site in wells that are upgradient or cross gradient from the tailings cells. Other VOC contaminants and nitrate and nitrite have also been detected in these samples. After installation of 27 new monitoring wells at the site, groundwater studies appear to have defined the boundaries of the chloroform plume. Based on the location of the plume and characterization studies completed to date, the contamination appears to have resulted from the operation of temporary laboratory facilities that were located at the site prior to and during construction of the Mill facility, and septic drainfields 75 that were used for laboratory and sanitary wastes prior to construction of the Mill's tailings cells. Interim measures have been instituted in order to contain the contamination and to pump contaminated groundwater into the Mill's tailings cells. To that end, the Mill has equipped five of the wells (MW-4, TW4-4, MW-26 (previously named TW4-15), TW4-19 and TW4-20) with pumps to recover water impacted by chloroform and to dispose of such water in the Mill's tailings cells. In the 2004 Statement of Basis, DRC noted on page 3 that, while the contaminant investigation and groundwater remediation plan are not yet complete, the DRC believes that additional time is available to resolve these requirements based on the following factors: 1) hydraulic isolation found between the shallow perched aquifer in which the contamination has been detected and the deep confined aquifers which are a source of drinking water in the area, 2) the large horizontal distance and the long groundwater travel times between the existing groundwater contamination on site and the seeps and springs where the shallow aquifer discharges at the edge of White Mesa, and 3) lack of human exposure for these shallow aquifer contaminants along this travel path. EFRI submitted a Preliminary Corrective Action Plan, White Mesa Mill Near Blanding, Utah, August 20, 2007, prepared by Hydro Geo Chern, Inc., on August 21, 2007, and a Preliminary Contamination Investigation Report, White Mesa Mill Near Blanding, Utah, November 20, 2007, prepared by Hydro Geo Chern, Inc., on December 21, 2007. DRC has requested changes to the proposed plans. When a Corrective Action Plan is approved by the Director, it will be subject to public comments. As part of the active strategy in the first phase of the Corrective Action Plan, EFRI has operated a chloroform capture system, referred to as the "Long-term Pump Test" continuously since January 31, 2010. The purpose of the test is to serve as an interim action that will remove a significant amount of chloroform-contaminated water while gathering additional data on hydraulic properties in the area of investigation. Chloroform-contaminated water is captured by pumping six wells located within the identified chloroform plume, and transferred via an above- ground piping network to Tailings Cell 1 for disposal. Effectiveness of the first phase of the Corrective Action is evaluated and documented in quarterly reports to the Director. EFRI estimates that, as of the first quarter of 2014, 699 lbs. of chloroform have been extracted through the capture system. 2.16.2 Nitrate Investigation During review of the New Well Background Report and other reports, a Nitrate contaminant plume was identified by DRC staff in five monitoring wells in the Mill site area, including wells: MW-30, MW-31, TW4-22, TW4-24, and TW4-25. TW4-25 is located upgradient of the Mill's tailings cells. Elevated concentrations of chloride also appear to be associated with the nitrate plume. On September 30, 2008, the Director issued a request for a voluntary plan and schedule for EFRI to investigate and remediate this Nitrate contamination. On November 19, 2008 EFRI submitted a plan and schedule prepared by INTERA, Inc., which identified a number of potential sources 76 for the contamination, including several potential historic and offsite sources. On January 27, 2009, the Director and EFRI signed a Stipulated Consent Agreement ("SCA") by which EFRI agreed to conduct an investigation of the Nitrate contamination, determine the sources of pollution, and submit a report by January 4, 2010. EFRI submitted a Contaminant Investigation Report ("CIR") on December 30, 2009. On October 5, 2010 the Director issued a Notice of Additional Required Action ("NARA") letter that notified EFRI of the Director's determination that the 2009 CIR was incomplete. On December 20, 2010 EFRI and the Director entered into Revision 0 of a Tolling Agreement, allowing a tolling period until April 30, 2011 in order to provide time for EFRI to prepare a Plan and Schedule for Director review addressing additional investigations to resolve open issues identified in the October 5, 2010 NARA, and to execute a revised SCA. EFRI submitted a Plan and Schedule on February 14, 2011 and a revised Plan and Schedule on February 18, 2011. The Director provided comments on the revised Plan and Schedule on March 21, 2011. In an April 20, 2011 meeting, EFRI and the Director agreed that the Plan and Schedule to conduct additional nitrate investigations would be composed of four to five phases of study, including geoprobe drilling and soil sampling/analysis to investigate natural nitrate salt reservoir sources in the vadose zone beyond the Mill site, potential Mill sources, and other potential sources; groundwater sampling and analysis of existing monitoring wells for non- isotopic analytes; deep bedrock core sampling/analysis of possible natural nitrate reservoir and potential nitrate source locations; stable isotopic sampling/analysis of groundwater in existing monitoring wells; and stable isotopic sampling/analysis of soil/core samples, if needed. On April 28, 2011, EFRI and the Director entered into Revision 1 of the Tolling Agreement to extend the Tolling Period through June 30, 2011 and adopt the agreements made on April 20, 2011. Under the Tolling Agreement Revision 1, EFRI agreed to submit a Revised Phase 1 (A through C) Work Plan on or before May 6, 2011 and a Revised Phase 2 through 5 Work Plan and Schedule on or before June 3, 2011. EFRI submitted a May 6, 2011 Revised Phase 1 Work Plan and Schedule for the Phase 1 A-C investigation for Director review. EFRI conducted field and laboratory work for the Phase 1 A-C study in May and June, 2011. EFRI submitted a Revised Phase 2 through 5 Work Plan and Schedule for Director review on June 3, 2011. The Director provided comments on this document on June 23, 2011 and advised EFRI that in order to revise the 2009 SCA to incorporate needed deliverables and timelines, the Phase 2 through 5 Work Plan would need to be expanded to the same level of detail as was provided for Phase 1 in Attachment 1 of the Revision 1 Tolling Agreement. On June 30, 2011, EFRI and the Director entered into Revision 2 of the Tolling Agreement extending the Tolling Period to August 31, 2011, to facilitate the revision of the Phase 2 through 5 Work Plan to provide the required level of detail to construct a replacement SCA. EFRI submitted a separate July 1, 2011 detailed Revision 0 of the Work Plan and Quality Assurance Plan ("QAP") for the Phase 2 investigation. The Director provided comments on this document on July 7, 2011. EFRI provided a July 12, 2011 Revision 1.0 to the Phase 2 QAP and Work Plan, 77 which DRC conditionally approved in a letter dated July 18, 2011. On August 1 and 2, 2011 EFRI submitted by email preliminary laboratory results for the Phase 1 A-C study to the Director. On August 4, 2011, EFRI provided a Revision 1.0 to the Phase 2 - 5 Work Plan for Director review. The Director provided comments on the Phase 2-5 Work Plan, Revision 1.0 and the August 1, 2011 preliminary laboratory results on August 11, 2011. EFRI submitted Revision 2.0 of the Phase 2-5 Work Plan for Director review on August 11, 2011. On August 25, 2011, the Director determined that based on review of the Revision 2.0 Phase 2-5 Work Plan, a finalized Plan and Schedule that meets the satisfaction of the Director, and which would allow the preparation of a replacement SCA, was not possible at that time; and that the development of a replacement SCA for continued contaminant investigation activities was not supported. At a meeting on August 29, 2011, EFRI and DRC agreed that: 1. After more than two years of investigation it has been determined that there are site conditions that make it difficult to determine the source(s) of the contamination at the White Mesa site; 2. As a result, resources will be better spent in developing a CAP in accordance with UAC R317-6-6.15(D), rather than continuing with further investigations as to the source(s) of the contamination. In discussions during October 2011, EFRI and the Director acknowledged that it has not been possible to date to determine the source(s), cause(s), attribution, magnitudes of contribution, and proportion(s) of the local nitrate and chloride in groundwater, and thereby cannot eliminate Mill activities as a potential cause, either in full or in part, of the contamination. As a result, EFRI and the Director agreed that resources will be better spent in developing a Corrective Action Plan in accordance with UAC R317 -6-6.15(D), rather than continuing with further investigations. On October 3, 2011 EFRI and the Director entered into a revised Stipulated Consent Agreement which required EFRI to submit a Corrective Action Plan for Director review that included plans to: Phase I -determine the physical extent of soil contamination observed at the Ammonium Sulfate Crystal Tanks, and provide a control measure consisting of either removal of the areal extent of contamination down to bedrock, or a Plan and Schedule for covering the areal extent of contamination with at least 6 inches of concrete, followed by removal action during or before site closure. Phase II -implement near term active remediation of the nitrate contamination by pumping contaminated water into the Mill's tailings cells for disposal. This phase is to include development, implementation, operation, and monitoring of a pumping well network to contain and hydraulically control the nitrate plume; monitoring of chloride concentrations; and any required increases to the Mill's surety for activities in this Phase. Phase III -develop, if necessary, a comprehensive long-term solution for the nitrate contamination at the Mill Site. This Phase is to be determined after public participation 78 and Director approval, and may include continuation of Phase I and II activities alone or in combination with any of the following: monitored natural attenuation, additional remediation and monitoring, determination of additional hydrogeologic characterization, contaminant travel times, points of exposure to public or wildlife, risk analysis, cost/benefit analysis, and possible development and petition of the Board for alternate corrective action concentration limits. EFRI submitted a Draft Corrective Action Plan on November 30, 2011. The Director provided comments on the Draft Corrective Action Plan on January 19, 2012. EFRI provided Revision 1.0 of the Corrective Action Plan on February 27, 2012, and received comments from the Director on March 19, 2012. Pursuant to the revised SCA, EFRI provided Revision 2.0 to the Director on May 7, 2012. On December 12, 2012, DRC signed the Stipulation and Consent Order ("SCO"), Docket Number UGW12-04, which approved the EFRI CAP, dated May 7, 2012. The SCO ordered EFRI to fully implement all elements of the May 7, 2012 CAP. Based on the schedule included in the CAP and as delineated and approved by the SCO, the activities associated with the implementation of the CAP began in January 2013. The reporting requirements specified in the CAP and SCO are included in the quarterly nitrate reports. 2.17 Other Information Required by the Director (R317-6-6.3.Q) As discussed below, a chemical inventory report and a Hydrogeologic investigation report for the southwest portion of the Mill site have been completed at the request of the Director. No other information has been specifically required by the Director to be included in this Application at this time. EFRI will provide additional information as requested by the Director. 2.17.1 Chemica/Inventory Report Part I.H.1 of the Permit requires that EFRI complete a historical review and conduct an inventory of all chemical compounds or reagents stored, used, or currently in use at the facility. including the types of chemicals and the total volumes present, and historically used, as data is available. EFRI submitted a chemical inventory report on June 7, 2005, and submitted additional related information on November 17, 2006. Part I.H.1 requires that at the time of Permit renewal, the Permittee shall submit an updated inventory report. Part I.E.9 requires that the inventory address chemicals used in the milling process and the on-site laboratory. The updated inventory report is provided in Appendix 0 of this Application. 2.17.2 Southwest Hydrogeologic Investigation Part I.H.6 of the Permit required that EFRI perform a detailed Southwest Hydrogeologic Investigation to define, demonstrate and characterize: 1) the hydraulic connection and local groundwater flow directions between the area near Tailings Cell 4B, and the western margin of 79 White Mesa, and 2) the full physical extent of the unsaturated area between former well MW -16, MW-33 and the western margin of White Mesa. During 2011, EFRI installed 18 piezometers to define the geologic and physical extent of the apparent unsaturated structural high between Tailings Cell 4B and the western margin of White Mesa and the location and direction of groundwater flow paths between Tailings Cell 4B and Westwater and Cottonwood Seeps and Ruin Spring. Consistent with Part I.H.6.c) of the Permit, EFRI submitted an investigation report, the Hydrogeology of the Perched Groundwater Zone in the Area Southwest of the Tailings Cells, White Mesa Uranium Mill Site (the "Southwest Hydrogeology Report"), prepared by Hydro Geo Chern, on January 12, 2012. The Director provided comments in a conference call during May 2012, and in a letter dated May 30, 2012. EFRI submitted a revised version of the Report on August 3, 2012 and agreed to repeat slug testing of piezometer DR-08. DRC's September 20, 2012 review Summary and RFI, specifically requested that EFRI: • repeat slug testing of piezometer DR-08, • recalculate hydraulic properties, and • recalculate travel times if necessary based on new data. The Second Revision to the Report, addressing the data and re-calculations resulting from retesting of piezometer DR-08, was submitted on November 7, 2012. 2.18 This Application Performed Under the Direction of a Professional Engineer (R317-6-6.3.R) This Application has been performed under the direction, and bears the seal, of Harold R. Roberts, Executive Vice President and Chief Operating Officer EFRI. Mr. Roberts is a Registered Professional Engineer in the State of Utah, No. 165838. 2.19 Closure and Post Closure Management Plan Demonstrating Measures to Prevent Ground Water Contamination During the Closure and Post Closure Phases of Operation (R17 -6-6.3.8) 2.19.1 Regulatory Requirements for Uranium Mills 2.19.1.1 Long Term Custodian One unique feature of the regulatory scheme for uranium mill tailings is that Section 83 of the Atomic Energy Act of 1954, as amended by the Uranium Mill Tailings Radiation Control Act of 1978 ("UMTRCA") (the Atomic Energy Act of 1954 as so amended is referred to herein as the "AEA")4 requires that, prior to license termination, title to uranium mill tailings (lle.(2) byproduct material) must be transferred to the United States Department of Energy ("DOE") or the State in which the activity occurred, if the State so elects, for custody and long term care. 10 CFR 40.28 provides a general license to DOE or the State for that purpose. 2.19.1.2 Responsibility For And Manner Of Clean Up UMTRCA amended the AEA to require that all Title ll facilities (i.e., active mills) comply with 4 See 42 U.S.C. 2113. 80 the decontamination, decommissioning, and reclamation standards prescribed by the Commission5 and to require that such facilities post reclamation bonds or surety6. Responsibility for reclamation of Title II facilities rests with the licensee. 10 CFR Part 40 Appendix A Criterion 6A requires the adoption of a Director-approved reclamation plan for the site, Criterion 9 requires that financial surety must be established to fund the cost of reclamation in accordance with such plan, and Criterion 10 requires that each licensee include in its financial surety an amount equivalent to $250,000 (1978 dollars) to cover the costs of long-term surveillance by the long-term government custodian (DOE). Criteria 6, 9 and 10 have been incorporated by reference into the Utah rules by UAC R313-24-4. 2.19.1.3 Surface The reclamation plan adopted by the Mill at the outset, as required by 10 CFR Part 40, Appendix A, Criterion 9, addresses the decontamination and decommissioning of the Mill and Mill site and reclamation of tailings and other waste disposal areas. As is the case for most uranium mills, the Mill's reclamation plan requires that, upon closure, all mill buildings, unsalvageable equipment, contaminated soils (impacted by Mill operations within the Mill site itself as well as surrounding areas that may be impacted by windblown radioactive dusts from milling operations) etc. be deposited in the tailings cells and the tailings cells capped in place. Appendix A, Criterion 6(6) sets the standard for determining when all impacted areas, other than the tailings impoundments have been adequately cleaned up. Criterion 6(6) provides that byproduct material containing concentrations of radionuclides other than radium in soil, and surface activity on remaining structures, must not result in a total effective dose equivalent (TEDE) exceeding the dose from cleanup of radium contaminated soil to the benchmark standard of 5pCi/g concentration of radium in the upper 15 em (6 in) of surface soils and 15 pCi/g concentration of radium in the subsurface soils, and must be at levels which are ALARA. If more than one residual radionuclide is present, the sum of the ratios for each radionuclide present will not exceed "1" (unity). Further details on the NRC's approach to evaluating reclamation plans and release criteria for uranium mill sites, including the manner of modeling the release standard set out in Criterion 6(6), are contained in NUREG-1620, Rev 1, Standard Review Plan for the Review of a Reclamation Plan for Mill Tailings Sites Under Title II of the Uranium Mill Tailings Radiation Control Act of 1978, Final Report, June 2003 ("NUREG-1620"). 2.19.1.4 Groundwater Each uranium mill is required to have a groundwater monitoring program. In the case of the Mill, the Permit implements the applicable requirements of U AC R317 -6. If there is groundwater contamination after cessation of operations, the requirements of UAC R317-6.15 must be satisfied. 5 See 42 U.S.C. 2113. 6 See 42 U.S.C. 2201. 81 2.19.1.5 License Termination Section 83.7 of the ABA 7 provides that material and land transferred to the long term custodian must be transferred without cost to the long-term custodian other than administrative and legal costs incurred in carrying out such transfer. In order to cover the costs of long-term surveillance, Criterion 10 requires that a minimum charge of $250,000 (1978 dollars) must be paid by each mill operator to the general treasury of the United States or to an appropriate State agency prior to the termination of a uranium mill license. In most cases if there is a groundwater contamination problem, the problem must be remediated prior to license termination, or an alternate corrective action concentration limit under R317 -6- 6.15.0 must be achieved that is protective of public health and the environment. In some circumstances DOE may agree to take some additional actions after it takes title to the site, such as additional monitoring, if not onerous and provided adequate funding is provided. Upon the Director and the NRC being satisfied that all regulatory requirements have been met and the site is reclaimed in a manner that satisfies all applicable standards, the Mill's license will be terminated upon transfer of the tailings to DOE. 10 CFR 40.28 provides a general license in favor of the long-term custodian for custody of and long-term care of the tailings impoundments and any surrounding lands transferred to it. 8 The surrounding areas not transferred to DOE would generally be free-released. 2.19.2 Current Reclamation Plan The Mill's Reclamation Plan, Revision 3.2B, was approved by DRC under the Mill License on January 26, 2011. The Reclamation Plan sets out the requirements to be met by EFRI for the final reclamation and closure of the Mill facility, including the tailings cells and all impacted surrounding areas, in accordance with the requirements of 10 CFR Part 40, Appendix A (which have since been incorporated by reference into UAC R313-24). A copy of the Mill's Reclamation Plan, Revision 4.0 was previously submitted to the Director in November 2009 and is on file at the DRC. EFRI submitted Revision 5.0 of the Reclamation Plan in September 2011. DRC provided one round of interrogatories for this document in March 2012. EFRI provided responses to these interrogatories in May and August 2012. DRC provided review comments on EFRI's May and August 2012 responses in February 2013. On April 30, 2013, a meeting was held in Denver, Colorado to discuss specific issues identified in DRC's February 2013 review comments, including, but not limited to, DRC's request for site- specific tailings data and a probabilistic seismic hazard analysis (PSHA) for the Mill site. Representatives of DRC, DRC's consultant (URS Professional Solutions, LLC), EFRI, and 7 See 42 U.S.C. 2113. 8 In circumstances where the facility has a groundwater contamination plume, additional lands may be acquired by the licensee in order to bound the plume. In these circumstances these additional lands would be transferred along with the capped tailings impoundments, to DOE. 82 EFRI's technical consultant (MWH Americas, Inc.) attended the meeting. During the meeting, EFRI proposed a tailings investigation to address the request for site-specific tailings data. A work plan for this investigation was provided to DRC on June 24, 2013, and DRC provided approval of the work plan verbally to EFRI on September 12, 2013. The tailings investigation was completed in October 2013, and subsequent laboratory testing of collected samples was completed in April 2014. A Tailings Data Analysis Report summarizing the results of the investigation is currently being prepared for submittal to DRC in June 2014. A PSHA for the Mill site is being prepared for submittal to DRC in June 2014 as well. Submission of responses to DRC's February 2013 review comments on Revision 5.0 of the Reclamation Plan are planned to be completed in 2014 after DRC's review of the Tailings Data Analysis Report and PSHA for the Mill site. The results provided in the Tailings Data Analysis Report and PSHA for the Mill site will be used to update technical analyses to address DRC's February 2013 review comments on Revision 5.0 of the Reclamation Plan. The responses will also incorporate decisions made at the April30, 2013 meeting on key issues related to Revision 5.0 of the Reclamation Plan. 2.19.3 Provisions Included in the Permit Relating to the Mill's Reclamation Plan The Mill License is currently in timely renewal. As part of the Mill License Renewal, DRC is re-examining the Mill's Reclamation Plan for content and adequacy. At the time of original issuance of the Permit, the Director had not completed his review of the Mill's Reclamation Plan. As a result, new requirements were added to the Permit to ensure that the final reclamation design approved by the Director on his re-examination of the Reclamation Plan will provide adequate performance criteria to protect local groundwater quality. To this end, three requirements were included in Part I.D.8 of the Permit to ensure that the cover system for each tailings cell will be designed and constructed to: a) Minimize the infiltration of water into the radon barrier and underlying tailings waste; b) Prevent the accumulation of leachates within the tailings that might create a bathtub effect and thereby spill over the maximum elevation of the FML inside any disposal cell; thereby causing a release of contaminants to the environment; and c) Protect groundwater quality at the compliance monitoring wells by ensuring that contaminant concentrations there do not exceed their respective GWQS or GWCL defined in Part I.C.l and Table 2 of the Permit. To provide consistency with the performance criteria stipulated by the Director at other lle.(2) disposal operations, a 200-year minimum performance period was required for all three of these criteria. In addition, Part I.D.9 was included in the Permit, which provides that upon commencement of decommissioning, EFRI will reclaim the Mill site and all related facilities, stabilize the tailings cells, and construct a cover system over the tailings cells in compliance with all engineering design and specifications of the approved reclamation plan. Part I.D.7 also provides that the Director reserves the right to require modifications to the Mill's Reclamation Plan for purposes of compliance with the Utah Ground Water Quality Protection Regulations, including but not limited to containment and control of contaminants, or discharges, or potential discharges to waters of the State. 83 Finally, Part I.D.9 was added to the Permit to provide the Director an opportunity to ensure that: a) The post-closure performance requirements for the tailings cell cover system in Part I.D.8 is fully and adequately integrated into the Mill's Reclamation Plan. Part I.H.2 was also added to the Permit to require EFRI to complete an infiltration and contaminant transport model of the final tailings cell cover system to demonstrate the long-term ability of the cover to protect nearby groundwater quality. As a part of this cover system performance modeling required by Part I.H.2, the Director will determine if changes to the cover system are needed to ensure compliance with the Part I.D.8 performance criteria; b) All other facility demolition and decommissioning activities outlined in the Reclamation Plan will be done in a manner adequate to protect local groundwater quality. Issues or concerns to be considered and resolved include: (i) Identification, isolation, and authorized disposal of any un-used chemical reagents held in storage at the Mill site at the time of closure; (ii) Demolition, excavation, removal, and authorized disposal of all contaminated man-made structures, including, but not limited to: buildings, pipes, power lines, tanks, access roads, drain fields, leach fields, fly-ash disposal ponds, feedstock storage areas, Mill site wastewater storage ponds, solid waste disposal landfills, and all related appurtenances; and (iii) Excavation, removal, and authorized disposal of all contaminated soils found anywhere outside of the tailings cells at the facility. Through this process, the Director will be able to ensure that DMT has been adequately established for both the final tailings cell cover system and reclamation of the facility. EFRI submitted an Infiltration and Contaminant Transport Modeling Report, White Mesa Mill Site, Blanding, Utah, November 2007, prepared by MWH Americas, Inc., in November, 2007. EFRI submitted a revised Infiltration and Contaminant Transport Modeling Report, White Mesa Mill Site, Blanding, Utah, March 2010 ("revised ICTM Report") in response to DRC comments. The March 2010 report is currently being reviewed in conjunction with the Reclamation Plan, Revision 5.0. DRC provided interrogatories for the revised ICTM Report in March 2012. EFRI provided responses to these interrogatories in May and September 2012. DRC provided review comments on EFRI's May and September 2012 responses in February 2013. On April 30, 2013, a meeting was held in Denver, Colorado to discuss specific issues identified in DRC's February 2013 review comments for Revision 5.0 of the Reclamation Plan and the revised ICTM Report. As noted in Section 2.19.2, included in the discussions at this meeting was DRC's request for site-specific tailings data. EFRI proposed a tailings investigation to address DRC's concerns. The tailings investigation was completed in October 2013 and subsequent laboratory testing of samples collected was completed in April 2014. A Tailings Data Analysis Report summarizing the results of the investigation is currently being prepared for submittal to DRC in June 2014. Submission of responses to DRC's February 2013 review comments on the revised ICTM Report are planned to be completed in 2014 after DRC's review of the Tailings Data Analysis Report. The results provided in the Tailings Data Analysis Report 84 will be used to update technical analyses to address DRC's February 2013 review comments on the revised ICTM report. The responses will also incorporate decisions made at the April 30, 2013 meeting on key issues related to the revised ICTM Report. 2.19.4 Post-Operational Monitoring Monitoring will continue under the Permit after cessation of operations, during reclamation and after reclamation has been completed until such time as the Mill License and Permit are terminated and the reclaimed tailings impoundments are transferred to the Department of Energy for perpetual care and maintenance. 3.0 CONCLUSIONS This Application describes the key monitoring and DMT performance standard requirements and other protections contained in the Permit. EFRI believes that with this Application, the accompanying Background Reports and other documentation, the Director has been provided sufficient information to determine that: a) EFRI has demonstrated that the applicable class TDS limits, ground water quality standards and protection levels will be met; b) The monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; c) EFRI utilizes treatment and discharge minimization technology at the Mill commensurate with plant process design capability and similar or equivalent to that utilized by facilities that produce similar products or services with similar production process technology; and d) There is no current or anticipated impairment of present and future beneficial uses of the ground water. 85 4.0 SIGNATURE AND CERTIFICATIONS This Application is dated June 5, 2014 and is being submitted by Energy Fuels Resources (USA) Inc. Energy Fuels Resources (USA) Inc. By: tZ?fl£ Frank J. Filas Vice President, Permitting and Environmental Affairs I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the~ · Hit e and imprisonment for knowing violations. c;:/7 Vice President, Permitting and Environmental Affairs CERTIFICATION BY REGISTERED PROFESSIONAL ENGINEER I hereby certify that the foregoing Application has been prepared under my direction, that I have reviewed this Application, that I am familiar with the Mill facilities, and attest that this Application has been prepared in accordance with good engineering practices. 'B'.arold R. Roberts 86 5.0 REFERENCES American Society for Testing and Materials. 1996. Standards on Ground Water and Vadose Investigations. Dames & Moore. January 30, 1978. Environmental Report, White Mesa Uranium Project San Juan County, Utah. D' Appolonia Consulting Engineers, Inc. June 1979. Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah. D' Appolonia Consulting Engineers, Inc. May 1981. Engineer's Report: Second Phase Design - Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah. D' Appolonia Consulting Engineers, Inc. February 1982. Construction Report: Initial Phase - Tailings Management System, White Mesa Uranium Project Blanding, Utah. Division of Radiation Control, Utah. December 1, 2004. Statement of Basis For a Uranium Milling Facility at White Mesa, South of Blanding, Utah, Owned and Operated by International Uranium (USA) Corporation. EFRI. August 2000. Construction Report: Tailings Cell 4A, White Mesa Uranium Mill - Tailings Management System. Prepared by EFRI (formerly International Uranium (USA) Corporation). Energy Fuels Nuclear, Inc. March 1983. Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project. Energy Fuels Nuclear, Inc. January 14, 2011. Revised Phase 2 QAP and Work Plan, Revision 2.0. Energy Fuels Nuclear, Inc. July 12, 2011. Reclamatin Plan for the White Mesa Mill, Blanding, Utah. Source material License No.SUA-1358 Docket No. 40-8681 Revision. Environmental Protection Agency. March, 1991. Handbook of Suggested Practices for Design and Installation of Ground-Water Monitoring Wells (EP A/600/4-89/034 ). Environmental Protection Agency. November, 1985. Practical Guide for Ground Water Sampling (EPA/600/2-851104). GeoSyntec Consultants. January 2006. Cell 4A Lining System Design Report For The White Mesa Mill Blanding, Utah. Geosyntec Consultants. July 2008. Cell 4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah. Geosyntec Consultants. November 2010. Construction Quality Assurance Report. Geosyntec Consultants. December 8, 2012, Cell 4B Design Report, White Mesa Mill, Blanding Utah 87 Hydro Geo Chern, Inc. 2001. Update to report: Investigation of Elevated chloroform concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah. Hydro Geo Chern, Inc. August 29, 2002. Letter Report. Hydro Geo Chern, Inc. August 20, 2007. Preliminary Corrective Action Plan, White Mesa Mill Near Blanding, Utah. Hydro Geo Chern, Inc. April 13, 2012. (2012a). Plan and Time Scheduler for Assessment of pH Uner Groundwater Discharge Permit UGW370004. Hydro Geo Chern, Inc. May 7, 2012. (2012b). Nitrate Corrective Plan. Hydro Geo Chern, Inc. December 7, 2012. (2012c). Investigation of Pyrite in the Perched Zone, White Mesa Uranium Mill, Blanding, Utah. Hydro Geo Chern, Inc. June 6, 2014 Hydrogeology of the White Mesa Uranium Mill Site Near Blanding, Utah. HydroSOL VB, Inc. 2000. AQTESOL VB for Windows. Users Guide. INTERA, Inc. October 2007. (2007a). Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA Inc. November 16, 2007. (2007b). Revised Addendum: --Evaluation of Available Pre- Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA Inc. April 30, 2008. Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA, Inc. December 30, 2009 Nitrate Contamination Investigation Report White Mesa Uranium Mill Site Blanding, Utah. INTERA, Inc. June 1, 2010 Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA, Inc. May 11, 2011. Revised Phase 1 (A through C) Work Plan and Schedule for Phase 1 A - C Investigation. INTERA, Inc. June 3, 2011. Revised Phase 2 through 5 Work Plan and Schedule. 88 INTERA, Inc. October 10, 2012. Source Assessment Report, White Mesa Uranium Mill, Blanding Utah.INTERA, Inc. November 9, 2012. pH Report White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. May 7, 2013. Source Assessment Report for TDS in MW-29, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. August 30, 2013.Source Assessment Report for Selenium in MW-31, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. December 17, 2013. Source Assessment Report for Tetrahydrofuran in MW-01, White Mesa Uranium Mill, Blanding, Utah. INTERA, Inc. January 13, 2014. Source Assessment Report for Gross Alpha in MW-32, White Mesa Uranium Mill, Blanding, Utah. INTERA, Inc. March 19, 2014. Source Assessment Report for Sulfate in MW-01 and TDS in MW -03A, White Mesa Uranium Mill, Blanding, Utah. INTERA, Inc. May 1, 2014. Background Groundwater Quality Report for Wells MW-35, MW- 36 and MW-37 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. Kirby, 2008. Geologic and Hydrologic Characterization of the Dakota-Burro Canyon Aquifer Near Blanding, San Juan County, Utah. Utah Geological Survey Special Study 123. Knight-Piesold LLC. November 23, 1998. Evaluation of Potential for Tailings Cell Discharge -White Mesa Mill. MWH Americas. March, 2010. Revised Infiltration and Contamination Transport Modeling Report, White Mesa Mill Site, Blanding Utah, Denison Mines (USA) Corp. Nuclear Regulatory Commission. May 1979. Final Environmental Statement related to operation of White Mesa Uranium Project Energy Fuels Nuclear, Inc., Docket No. 40-8681. Resource Conservation Recovery Act. 1986. Ground Water Monitoring Technical Enforcement Guidance Document. Revised Tolling Agreement, Revision 3, between DUSA and the Director, Revision 2. August 21, 2011. Stipulated Consent Agreement Docket No. UGW12-03 between Denison Mines (USA) Corp. and the Director of the Division of Radiation Control. July 12, 2012. T. Grant Hurst and D. Kip Solomon, Department of Geophysics, University of Utah. May 2008. Summary of work completed, data results, interpretations and recommendations for the 89 July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah. United States Geological Survey. 1998. Techniques of Water Resource Investigation of the US Geological Survey, Book 9. TITAN Environmental Corporation. July 1994. Hydrogeological Evaluation of White Mesa Uranium Mill. Umetco Minerals Corporation. April 10, 1989. Cell 4 Design, White Mesa Project Blanding, Utah. Umetco Minerals Corporation. January 1990. White Mesa Mill Drainage Report for Submittal to NRC. Umetco Minerals Corporation and Peel Environmental Services. 1993. Groundwater Study, White Mesa Facilities, Blanding, Utah. Utah, State of. January 20,2010. Ground Water Discharge Permit No. UGW370004 Utah, State of. June 21, 2010. Ground Water Discharge Permit No. UGW370004 Utah, State of. February 15, 2011. Ground Water Discharge Permit No. UGW370004 Utah, State of. June 13, 2011. Ground Water Discharge Permit UGW370004 Plan and Time Shceduler Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the First, Second, Third and Fourth Quarters of 2010 and First Quarter 2011. Utah, State of. September 7, 2011. Ground Water Discharge Permit UGW370004 Plan and Time Shceduler Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the First, Second, Third and Fourth Quarters of 2010 and First Quarter 2011. Utah, State of. July 14, 2011. Ground Water Discharge Permit No. UGW370004 Utah, State of. August 24, 2012. Ground Water Discharge Permit No. UGW370004 Utah, State of. Radioactive Materials License No. UT 1900479 (the "Mill License"). Utah, State of. December 13, 2012. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. Utah, State of. March 15, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. 90 Utah, State of. August 28, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. Utah, State of. September 20, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. Utah, State of. December 5, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. 91 Table No. 1.2-1 ............. . 1.2-2 ............. . 2.4-1 .............. . 2.5.2.1-1 ......... . 2.5.3-1 ........... . 2.5.3-2 .......... .. 2.5.3-3 ........... . 2.5.3-4 .......... .. 2.5.3-5 ........... . 2.9.1.3-1. ....... .. 2.11.2-1 ......... .. 2.13.1-1 ........... . INDEX OF TABLES Description Chloroform Monitoring Wells (Depth and Purpose) Nitrate Monitoring Wells (Depth and Purpose) Groundwater Monitoring Wells (Depth and Purpose) Water Quality of Groundwater in the Mill Vicinity Results of Quarterly Sampling Ruin Spring (2003-2004) Results of Annual Sampling Ruin Spring (2009-2013) Results of Annual Sampling Cottonwood Seep (2009-2013) Results of Annual Sampling Westwater Seep (2009-2013) Results of Annual Sampling Entrance Spring (2009-2013) Groundwater Monitoring Constituents Listed in Table 2 of the Permit Plan & Time Schedule and Source Assessment Report Status Drainage Areas of Mill Vicinity and Region Table 1.2-1 Chloroform Monitoring Wells (Depth and Purpose) ,eiJ Location Tgtal Depth I Purpose =='=" ~ TW4-1 111.04 Chloroform Monitoring Well TW4-2 121.125 Chloroform Monitoring Well TW4-3 141.00 Chloroform Monitoring Well TW4-4 114.50 Chloroform Pumping Well TW4-5 121.75 Chloroform Monitoring Well TW4-6 98.55 Chloroform Monitoring Well TW4-7 119.80 Chloroform Monitoring Well TW4-8 126.00 Chloroform Monitoring Well TW4-9 121.33 Chloroform Monitoring Well TW4-10 111.00 Chloroform Monitoring Well TW4-11 100.00 Chloroform Monitoring Well TW4-12 101.50 Chloroform Monitoring Well TW4-13 102.50 Chloroform Monitoring Well TW4-14 93.00 Chloroform Monitoring Well MW-26 121.33 Chloroform Pumping Well/Groundwater Monitoring Well TW4-16 142.00 Chloroform Monitoring Well MW-32 130.60 Chloroform Pumping Well/Groundwater Monitoring Well TW4-18 137.50 Chloroform Monitoring Well TW4-19 121.33 Chloroform Pumping Well TW4-20 106.00 Chloroform Pumping Well TW4-21 120.92 Chloroform Monitoring Well TW4-22 113.50 Chloroform Monitoring Well/Nitrate Pumping Well Well Location Total Depth Purpos I TW4-23 113.50 Chloroform Monitoring Well TW4-24 113.50 Chloroform Monitoring Well/Nitrate Pumping Well TW4-25 134.80 Chloroform Monitoring Well/Nitrate Pumping Well TW4-26 86.00 Chloroform Monitoring Well TW4-27 96.00 Chloroform Monitoring Well TW4-28 105.00 Chloroform Monitoring Well TW4-29 91.00 Chloroform Monitoring Well TW4-30 90.00 Chloroform Monitoring Well TW4-31 104.00 Chloroform Monitoring Well TW4-32 113.00 Chloroform Monitoring Well TW4-33 84.70 Chloroform Monitoring Well TW4-34 94.00 Chloroform Monitoring Well TW4-35 Installation in Chloroform Monitoring Well Progress TW4-36 Installation in Chloroform Monitoring Well Progress Table 1.2-2 Nitrate Monitoring Wells (Depth and Purpose) W:ell Locatio,n To,talD pth Purpose ~ ,.._ TWN-1 112.50 Nitrate Monitoring Well TWN-2 95.00 Nitrate Pumping Well TWN-3 110.00 Nitrate Monitoring Well TWN-4 136.00 Nitrate Monitoring Well TWN-5 155.00 Abandoned TWN-6 135.00 Water Level Monitoring Well TWN-7 120.00 Nitrate Monitoring Well TWN-8 160.00 Abandoned TWN-9 102.50 Abandoned TWN-10 107.50 Abandoned TWN-11 147.50 Abandoned TWN-12 115.00 Abandoned TWN-13 120.00 Abandoned TWN-14 135.00 Water Level Monitoring Well TWN-15 155.00 Abandoned TWN-16 100.00 Water Level Monitoring Well TWN-17 100.00 Abandoned TWN-18 100.00 Nitrate Monitoring Well TWN-19 110.00 Water Level Monitoring Well Table 2.4-1 Permit Monitoring Wells (Depth and Purpose) WeD Location Total Depth Ptu:po e MW-1 115.00 Semi-Annual Groundwater Compliance MW-2 125.00 Semi-Annual Groundwater Compliance MW-3 96.00 Semi-Annual Groundwater Compliance MW-3A 95.00 Semi-Annual Groundwater Compliance MW-4 122.00 No Longer Included In Groundwater Program MW-5 138.50 Semi-Annual Groundwater Compliance MW-11 135.00 Quarterly Groundwater Compliance MW-12 129.00 Semi-Annual Groundwater Compliance MW-14 127.00 Quarterly Groundwater Compliance MW-15 134.00 Semi-Annual Groundwater Compliance MW-17 110.00 Semi-Annual Groundwater Compliance MW-18 148.50 Semi-Annual Groundwater Compliance MW-19 149.00 Semi-Annual Groundwater Compliance MW-20 114.50 Semi-Annual Groundwater Monitoring MW-22 140.00 Semi-Annual Groundwater Monitoring MW-23 129.00 Semi-Annual Groundwater Compliance MW-24 119.90 Semi-Annual Groundwater Compliance MW-25 115.10 Quarterly Groundwater Compliance MW-26 121.33 Quarterly Groundwater Compliance MW-27 91.00 Semi-Annual Groundwater Compliance MW-28 106.00 Semi-Annual Groundwater Compliance MW-29 125.00 Semi-Annual Groundwater Compliance I MW-30 107.00 Quarterly Groundwater Compliance MW-31 129.00 Quarterly Groundwater Compliance MW-32 133.70 Semi-Annual Groundwater Compliance MW-33 103.50 Dry, Not sampled MW-34 109.00 Water Level Monitoring only MW-351 123.60 Quarterly Groundwater for Background MW-361 119.90 Quarterly Groundwater for Background MW-3i 120.20 Quarterly Groundwater for Background Notes: 1 -The Background Report for MW-35, MW-36, and MW-37 was submitted on May 1, 2014. These wells will continued to be sampled quarterly until such a time that the Background Report is approved. Table 2.5.2.1-1 Water Quality of Entrana!Navajo Aquifer in the Mill Vicinity FES, Test Well Well#2 Well #5 Parameter (G2R) 6/01/991 6/08/991 (1/27177-3/231781) Field Specific Conductivity 310 to 400 (umhos/cm) Field pH 6.9 to 7.6 Temperature (0C) 11 to 22 Estimated Flow m/hr (gpm) 109(20) pH 7.9to8.16 Uet~ruition., mg/Uter TDS (@ 180°C) 216to1110 Redox Potential 211 to 220 Alkalinity (as CaCOS3) 180 to 224 Hardness, total (as CaC03) 177 to 208 Bicarbonate 226 214 Carbonate (as CO,) 0.0 <1.0 <1.0 Aluminum 0.003 0.058 Aluminum, dissolved <0.1 Ammonia (as N) 0.0 to 0.16 <0.05 <0.05 Antimony <0.001 <0.001 Arsenic, total .007 to 0.014 0.018 <0.001 Barium, total 0.0 to 0.15 0.119 0.005 Beryllium <0.001 <0.001 Boron, total <0.1 to 0.11 Cadmium, total <0.005 to 0.0 <0.001 O.ot 8 Calcium 50.6 39.8 Calcium, dissolved 51 to 11 2 Chloride 0.0 to 50 <1.0 2.3 Sodium 7.3 9.8 Sodium, dissolved 5.3 to 23 Silver <0.001 <0.001 Silver, dissolved <0.002 to 0.0 Sulfate 28.8 23.6 Sulfate, dissolved (as S04) 17 to 83 Vanadium 0.003 0.003 Vanadium, dissolved <.002 to 0.16 Manganese 0.011 0.032 Manganese, dissolved 0.03 to 0.020 Chromium, total 0.02 to 0.0 0.005 0.005 Copper, total 0.005 to 0.0 0.002 0.086 Fluoride 0.18 0.1 8 Fluoride_, dissolved 0.1 to 0.22 Iron, total 0.35 to 2.1 0.43 0.20 Iron~ dissolved 0.30 to 2.3 Lead, total 0.02 -0.0 <0.001 0.018 Magnesium 20.4 21.3 Magnesium, dissolved 15 to 21 1 Zero values (0.0) are below detection limits. ~ FES, Test Well Well #2 Well #5 Parameter (G2R) 6/01/991 6/08/991 I' (1/27n7-3123nS1) Molybdenum, dissolved 0.004 to 0.010 Nickel <0.001 0.004 Nitrate +Nitrate as N <0.10 <0.10 Nitrate (as N) <.05 to 0.12 Phosphorus, total (asP) <0.01 to 0.03 Potassium 3.1 3.3 Potassium, dissolved 2.4 to 3.2 Selenium <0.001 <0.001 Selenium, dissolved <.005 to 0.0 Silica, dissolved (as Si02) 5.8 to 12 Strontium, total 0.5 to 0.67 Thallium <0.001 <0.001 Uranium, total (as U) <.002 to 0.16 0.0007 0.0042 Uranium, dissolved (as U) <.002 to 0.031 Zinc 0.010 0.126 Zinc, dissolved 0.007 to 0.39 Total Or£anic Carbon 1.1 to 16 Chemical Oxygen Demand <1 to 66 Oil and Grease 1 Total Suspended Solids 6 to 1940 <1.0 10.4 Turbidity 5.56 19.1 Determination ~p_Cilliter) - Gross Alpha <1.0 Gross Alpha + precision 1.6+ 1.3 to 10.2+2.6 Gross Beta <2.0 Gross Beta + precision 8+8 to 73+19 Radium 226 + precision 0.3+0.2 Radium 228 <1.0 Ra-226 +precision 0.1 +.3 to 0.6+0.4 Th-230 + precision 0.1+0.4 to 0.7+2.7 Pb-210 +precision 0.0+4.0 to 1.0+2.0 Po-210 +_Qrecision 0.0+0.3 to 0.0+0.8 Source: Adapted from FES Table 2.25 with additional Mill sampling data Parameter Major Ions (ml!fl} Alkalinity Carbon Dioxide Carbonate Bicarbonate Hydroxide Calcium Chloride ·Fluoride Magnesium Nitrogen, Ammonia As N Nitrogen, Nitrate+Nitrite as N Phosphorous Potassium Sodium Sulfate 111 Physical Properties Conductivity (umbos/em) pH TDS (mg/L) TSS (mg!L) Turbidity (NTU) Metals-Dissolved (mg/L) Aluminum Antimony Arsenic Barium Ber:yllium Cadmium Chromium Copper Iron Lead Manganese Mercury Molybdenum Nickel Selenium Silver Thallium Uranium Vanadium Zinc Radionuclides (pCi/L) Gross Alpha Minus Rn & U Lead 210 Radium 226 Thorium 230 Thorium 232 Thorium 228 Table 2.5.3-1 Results of Quarterly Sampling Ruin Spring (2003-2004) Ruin Spring Ql-03 Q2-03 Q3-03 Q4-3 --196 198 --ND ND --ND ND --239 241 -ND ND 153 156 149 158 28.1 21.5 27.4 28.0 --ND 0.5 34.8 34.2 31.7 34.2 ND ND ND ND 1.6 1.5 1.4 1.4 0.10 ND -ND 2.6 3.3 3.3 3.9 110 105 103 113 503 501 495 506 . . 1440 1410 . -7.91 7.98 . . 1040 1000 . . 13.5 ND -. 0.16 0.13 ND ND 0.40 ND ND ND ND ND 0.001 ND ND 0.001 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.082 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.013 0.012 0.012 0.012 ND ND ND ND ND ND ND ND 0.009 0.011 0.010 0.010 ND ND ND ND 0.014 ND ND ND . --. 42 ND ND ND 0.3 ND 0.3 ND 0.3 0.2 0.5 ND --ND ND -. ND ND . Ql-04 Q2-04 Q3-04 Q4-04 193 191 195 183 ND ND 12 ND ND ND ND ND 235 232 238 223 ND ND ND ND 158 162 176 186 29.3 28.5 26 25 0.5 0.6 0.6 0.6 35.8 35.1 37.1 38.6 ND 0.06 ND 0.06 1.73 1.85 1.34 1.7 ND ND ND ND 3.4 3.6 4.0 3.7 104 110 113 116 539 468 544 613 I 1390 1440 1320 1570 - -- 1050 1110 1050 1070 ND ND ND ND ND 0.12 -- ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.012 0.012 0.012 0.012 ND ND ND ND ND ND ND ND 0.011 0.011 0.009 0.010 ND ND ND ND ND ND ND ND ND ND 1.4 ND ND ND ND ND ND ND 1.3 ND ND ND 0.4 ND ND ND ND - ND ND -- Constituent 2009 Carbonate <1 Bicarbonate 233 Calcium 151 Chloride 28 Fluoride 0.5 Magnesium 32.3 Nitrogen- Ammonia 0.09 Nitrogen- Nitrate 1.4 Potassium 3.3 Sodium 104 Sulfate 528 TOS 1010 Arsenic <5 Beryllium < 0.5 Cadmium <0.5 Chromium <25 Cobalt <10 Copper <10 Iron <30 Lead <1.0 Manganese <10 Mercury <0.5 Molybdenum 17 Nickel <20 Selenium 12.2 Silver <10 Thallium <0.5 Tin <100 Uranium 9.11 Vanadium <15 Zinc <10 um ;prmg - Table 2.5.3-2 Results of Annual Sampling R . S . (2009 2013) RuinSor"nl! 2011-2011- 2010 May July 2012 Mu..ior Ioru lnl2/i) <1 <1 1 <1 254 241 239 237 136 145 148 147 23 25 44 28 0.53 0.45 0.5 0.52 29.7 30.6 31.1 31.9 <0.05 NO <0.05 <0.05 1.7 1.7 1.6 1.6 3.07 3.2 3.3 3.5 93.4 110 111 115 447 486 484 464 903 942 905 1000 Metals (ui!I'J.)r· <5 <5 <5 <5 < 0.5 < 0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <25 <25 <25 <25 <10 <10 <10 <10 <10 <10 <10 <10 <30 <30 <30 <30 <1.0 <1.0 <1.0 <1.0 <10 <10 <10 <10 <0.5 <0.5 <0.5 <0.5 17 16 17 16 <20 <20 <20 <20 10 11.8 10.2 10.8 <10 <10 <10 <10 <0.5 <0.5 <0.5 <0.5 <100 <100 <100 <100 8.47 9.35 8.63 8.68 <15 <15 <15 <15 <10 <10 <10 <10 Range of Average I Historic Values for Monitoring Ave 2003- 2013 WeDs 1 * 20042 <1 208 -~ 149 -- 26.3 NO-213 27 0.538 NO-1.3 0.6 32.1 -- <0.05 ,:_, -=~ 1.56 -- 3.46 -,;; 118 -- 553 NO-3455 521 952 1019-5548 1053 <5 =" - <0.5 --- <0.5 NO-4.78 O.Dl <25 ---· <10 --- <10 -· -- <30 NO -7942 25 <1.0 - <10 ND-34,550 5 <0.5 --, -~ 16.1 -- <20 NO-61 ~ 0.05 10.2 NO-106.5 12.1 <10 --- <0.5 -- <100 - 9.12 NO-59.8 10 <15 -- <10 - Radilllu~ics (pClll) Gross Alpha <0.2 <0.2 <-0.3 <-0.05 <-0.09 <1.0 NP ~3g 0.28 VQ(!;S '{u :IX~) Acetone <20 <20 <20 <20 <20 <20 ~ -- Benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ---- Carbon tetrachloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --· Chloroform <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --·- Chloromethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ---- MEK <20 <20 <20 <20 <20 <20 --- Methylene Chloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -e - Naphthalene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- Tetrah ydrofuran <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 .. - I Toluene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --- Xylenes <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- From Figure 3, Table 10 and Appendix B of the Revzsed Addendum, Background Groundwater Quality Report. New Wells for Denison Mines (USA) Corp's White Mesa Mill Site, San Juan County, Utah, April30, 2008, prepared by INTERA, Inc. and Table 16 and Appendix D of the Revised Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.'s White Mesa Uranium Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. 2 From Figure 9 of the Revised Addendum, Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan Couinty, Utah, November 16, 2007, prepared by INTERA, Inc. *Range of average historic values for On-Site Monitoring Wells as reported on April 30, 2008 (MW-1, MW-2, MW-3,MW-3A,MW-4,MW-5,MW-11,MW-12,MW-14,MW-15,MW-l7,MW-18,MW-19,MW-20,MW- 22, MW-23, MW-24, MW-25, MW-26, MW-27, MW-28, MW-29, MW-30, MW-31 andMW-32i Table 2.5.3-3 Results of Annual Sampling 0 on woo eep -c tt d s (2009 2013) Cottonwood See) Range of ] ~ Average Historic Values for 2011-2011-Monitoring Ave 1977- Constituent 2009 2010 May .Tulv 2012 2013 Wells1* 1982 I 'l\1a·or Ions (mgll) Carbonate <1 <1 <1 6 <1 <1 -·- Bicarbonate 316 340 330 316 326 280 ,. - Calcium 90.3 92.2 95.4 94.2 101 87.9 I -- Chloride 124 112 113 134 149 118 ND-213 31 Fluotide 0.4 0.38 0.34 0.38 0.38 0.417 ND-1.3 0.8 Ma2,ncsium 25 24.8 25.2 25.2 27.7 23.6 -"" - Nitrogen-<0.05 <0.05 <0.05 <0.05 Ammonia <0.05 <0.05 -~ -'"- Nitrogen-Nitrate 0.1 <0.1 0.1 <0.1 <0.1 <0.1 -- Potassium 5.7 5.77 6 5.9 6.2 5.53 ·--- Sodium 205 214 229 227 247 217 --- Sulfate 383 389 394 389 256 403 ND-3455 230 TDS 1010 900 1030 978 1040 996 1019-5548 811 Mcta.ls'(ug/1) Arsenic <5 <5 <5 <5 <5 <5 --- Beryllium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 -- Cadmium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ND-4.78 Chromium <25 <25 <25 <25 <25 <25 -~ - Cobalt <10 <10 <10 <10 <10 <10 -- Copper <10 <10 <10 <10 <10 <10 """ Iron <30 <30 53 <30 <30 <30 ND -7942 150 Lead <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- <10 <10 <10 <10 ND - Manganese <10 <10 34,550 580 Mercury <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 -- Molybdenum <10 <10 <10 <10 <10 <10 .... Nickel <20 <20 <20 <20 <20 <20 ND-61 - Selenium <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 ND-106.5 ·- Silver <10 <10 <10 <10 <10 <10 -. Thallium <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ~ -- Tin <100 <100 <100 <100 <100 <100 -- Uranium 8.42 8.24 7.87 8.68 8.17 8.95 ND-59.8 - Vanadium <15 <15 <15 <15 <15 <15 - Zinc <10 <10 <10 <10 <10 <10 - RsdioJo.Ribs,(liCill) Gross Alpha <0.2 <0.2 <0.1 <-0.1 <-0.2 <1.0 ~D-36 7.2 V.OCS (IIWL) Acetone <20 <20 <20 <20 <20 <20 --- Benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --~ Carbon tetrachloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -·~ Chloroform <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -- Chloromethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --.. MEK <20 <20 <20 <20 <20 <20 . ..,. ~'- Methylene Chloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ~ - Naphthalene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --- Tetrahydrofuran <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --- Toluene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --- Xylenes <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --- I From Figure 3, Table 10 and Appendtx B of the Revzsed Addendum, Background Groundwater Quality Report. New Wells for Denison Mines (USA) Corp's White Mesa Mill Site, San Juan County, Utah, April30, 2008, prepared by INTERA, Inc. and Table 16 and Appendix D of the Revised Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.'s White Mesa Uranium Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. *Range of average historic values for On-Site Monitoring Wells as reported on April30, 2008 (MW-1, MW-2, MW-3,MW-3A,MW-4,MW-5,MW-11,MW-12,MW-14,MW-15,MW-17,MW-18,MW-19,MW-20,MW- 22, MW-23, MW-24, MW-25, MW-26, MW-27, MW-28, MW-29, MW-30, MW-31 and MW-32) Constituent 2009 Carbonate <1 Bicarbonate 465 Calcium 191 Chloride 41 Fluoride 0.7 Magnesium 45.9 Nitrogen-Ammonia <0.05 Nitrogen-Nitrate 0.8 Potassium 1.19 Sodium 196 Sulfate 646 pH (s.u.) 8.01 TDS 1370 Arsenic <5 Beryllium <0.5 Cadmium <0.5 Chromium <25 Cobalt <10 Copper <10 Iron 89 Lead <1.0 Manganese 37 Mercury <0.5 Molybdenum 29 Nickel <20 Selenium <5.0 Silver <10 Thallium <0.5 Tin <100 Uranium 15.1 Vanadium <15 Zinc <10 Table 2.5.3-4 Results of Annual Sampling Westwater Seep (2009-2013) ~· Westw111er-Seep k 2011-2011- 2010 May Jul}' Mtl'or Ions (mi1J <1 <1 450 371 179 247 40 21 0.6 0.54 44.7 34.7 Not 0.5 0.06 Sampled -Dry <0.1 <0.1 6.57 3.9 160 112 607 354 7.38 7.2 1270 853 Metals (uw'l) <5 12.3 <0.5 0.91 <0.5 0.9 <25 <25 <10 <10 <10 16 56 4540 <1.0 41.4 87 268 Not <0.5 <0.5 Sampled 29 <10 -Dry <20 29 <5.0 <5.0 <10 <10 <0.5 <0.5 <100 <100 46.6 6.64 <15 34 <10 28 Range of Average Historic Values for Monitoring 2012 2013 Wells1 * -- -- -- NO-213 NO-1.3 Not Not -- Sampled Sampled- -Dry Dry - -· - - NO-3455 6.7-8.9 1019-5548 ---- NO-4.78 - ·~ - - NO -7942 - Not Not NO-34.550 Sampled Sampled----Dry Dry -'" NO-61 NO-106.5 - -- - ND-59.8 - - IJ Rn.diQJb!!i('S.foClfl). Not Not Not 0.5 Sampled Sampled Sampled- Gross Alpha < -0.1 <0.3 -Dry -Dry Dry ND -36, V0€.5'(~) Acetone <20 <20 ND - Benzene <1.0 <1.0 ND -- Carbon tetrachloride <1.0 <1.0 ND .. Chloroform <1.0 <1.0 ND - Chloromethane <1.0 <1.0 ND Not Not Not - MEK <20 <20 ND Sampled Sampled Sampled-- Meth_yJene Chloride <1.0 <1.0 ND -Dry -Dry Dry -- Naphthalene <1.0 <1.0 ND -- Tetrah ydrofuran <1.0 <1.0 ND - Toluene <1.0 <1.0 ND .. Xylenes <1.0 <1.0 ND 1 From Figure 3, Table 10 and Appendix B of the Revised Addendum, Background Groundwater Quality Report: New Wells for Denison Mines (USA) Corp's White Mesa Mill Site, San Juan County, Utah, Apri130, 2008, prepared by INTERA, Inc. and Table 16 and Appendix D of the Revised Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.'s White Mesa Uranium Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. *Range of average historic values for On-Site Monitoring Wells as reported on Apri130, 2008 (MW-1, MW-2, MW-3, MW-3A, MW-4,MW-5, MW-11, MW-12,MW-14,MW-15,MW-17,MW-18,MW-19, MW-20, MW-22, MW-23,MW-24,MW-25, MW-26, MW-27, MW-28, MW-29, MW-30, MW-31 and MW-32) II Constituent 2009 Carbonate <I Bicarbonate 292 Calcium 90.8 Chloride 60 Fluoride 0.7 Magnesium 26.6 Nitrogen-Ammonia 0.28 Nitrogen-Nitrate 1.4 Potassium 2.4 Sodium 61.4 Sulfate 178 TDS 605 Arsenic <5 Beryllium <0.5 Cadmium <0.5 Chromium <25 Cobalt <10 Copper <10 Iron <30 Lead <1.0 Manganese 54 Mercury <0.5 Molybdenum <10 Nickel <20 Selenium 12.1 Silver <10 Thallium <0.5 Tin <100 Uranium 15.2 Vanadium <15 Zinc <10 Gross Alpha 0.9 Table 2.5.3-5 n ranee spnng -3 Results of Annual Sampling E t S . (2009 201 ) Entrance Sorio2 2011-2011- 2010 Mav Jul.y Maior Ions (J112/)) <I <I 7 332 270 299 96.5 88.8 96.6 63 49 64 0.73 0.58 0.58 28.9 26.4 28.4 <0.05 <0.05 0.32 I 1.4 0.5 2.74 2.6 2.9 62.7 62.5 68.6 179 166 171 661 571 582 Metals (uWJ) <5 <5 <5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <25 <25 <25 <10 <10 <10 <10 <10 <10 <30 37 55 <1.0 <1.0 <1.0 11 47 84 <0.5 <0.5 <0.5 <10 <10 <10 <20 <20 <20 9.2 13.1 5.5 <10 <10 <10 <0.5 <0.5 <0.5 <100 <100 <100 17.8 18.8 15.3 <15 <15 <15 <10 <10 <10 Radiololtics (pCi/1) <0.5 1.5 1.6 Range of Average Historic VaJues 2012 2013 for Monitoring Wells1* <I <I -- 298 292 -- 105 121 _, 78 139 ND-213 0.64 0.71 ND -1.3 32.7 43 <0.05 <0.05 -- 2.8 2.06 -- 2 3.83 77.4 127 ""' 171 394 ND-3455 660 828 1019-5548 - <5 <5 -- <0.5 <0.5 - <0.5 <0.5 ND-4.78 <25 <25 -<10 <10 <10 <10 ~ 34 162 ND -7942 <1.0 <1.0 - <10 259 ND-34.550 <0.5 <0.5 -· <10 <10 ~ <20 <20 ND-61 13.2 11.2 ND -106.5 <10 <10 - <0.5 <0.5 <100 <100 - 21.1 38.8 ND-59.8 <15 <15 <10 <10 - 0.5 2.3 ND-36 VOCSCuiUL) Acetone <20 <20 <20 <20 <20 <20 -- Benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -· Carbon tetrachloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Chloroform <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Chloromethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ·- MEK <20 <20 <20 <20 <20 <20 -- Methylene Chloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Naphthalene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 -~ Tetrah ydrofuran <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1- Toluene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - Xylenes <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ~ I From Figure 3, Table 10 and Appendix B of the Revtsed Addendum, Background Groundwater Qualtty Report. New Wells for Denison Mines (USA) Corp's White Mesa Mill Site, San Juan County, Utah, April30, 2008, prepared by INTERA, Inc. and Table 16 and Appendix D of the Revised Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.'s White Mesa Uranium Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. *Range of average historic values for On-Site Monitoring Wells as reported on April30, 2008 (MW-1, MW-2, MW-3,MW-3A,MW-4,MW-5,MW-ll,MW-12,MW-14,MW-15,MW-17,MW-18,MVV-19,MVV-20,MW-22, MW-23, MW-24, MW-25, MW-26, MW-27, MW-28, MW-29. MW-30, MW-31 and MW-32) Table 2.9.1.3-1 Groundwater Monitoring Constituents Listed in Table 2 of the Permit Nutrients: Ammonia (as N) Nitrate & Nitrite (as N) Heavy Metals: Arsenic Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Mercury Molybdenum Nickel Selenium Silver Thallium Tin Uranium Vanadium Zinc Radiologies: Gross Alpha Volatile Organic Compounds: Acetone Benzene 2-Butanone (MEK) Carbon Tetrachloride Chloroform Chloromethane Dichloromethane Naphthalene Tetrahydrofuran Toluene Xylenes (total) Others: Field pH (S.U.) Fluoride Chloride Sulfate TDS Table 2.11.2-1 Plan & Time Schedule and Source Assessment Report Status Plan and Time Schedule (P&TS) Monitoring DRCP&TS Date Periods Covered ApprovaJ Date SARDate SAR ApprovaJ Date Constituents Q1, Q2, Q3, Q4 I of2010, Q1 of I 6/13/2011 2011 7112/2012 10110/2012 4/25/2013 Multiple 917/2011 Q22011 7112/2012 10110/2012 4/25/2013 MuJtiple I pH report -11/9112 I 4113/2012 Multiple 7/12/2012 Pyrite Report-1217112 4/25/2013 pH-multiple wells 12/13/2012 Q3 2012 2/4/2013 5/8/2013 7/23/2013 TDS -MW-29 3115/2013 Q4 2012 5/30/2013 8/30/2013 9117/2013 Se-MW-31 I 8/28/2013 Q1 2013 9117/2013 12117/2013 117/2014 THF-MW-01 9/20/2013 Q2 2013 10/16/2013 1113/2014 3110/2014 Gross Alpha-MW-32 S04-MW-01, TDS -MW- 12/5/2013 Q3 2013 12118/2013 Submitted 3119114 03A Table 2.13.1-1 Drainage Areas of Mill Vicinity and Region I Basin Descrlption Dtairn\,ge Are-a SQ.~S km:z ~~ Corral Creek at confluence with Recapture Creek 5.8 15.0 Westwater Creek at confluence with Cottonwood Wash 26.6 68.8 Cottonwood Wash at USGS Gauge west of project site :::::205 <531 Cottonwood Wash at confluence with San Juan River :::::332 <860 Recapture Creek at USGS gauge 3.8 9.8 Recapture Creek at confluence with San Juan River :::::200 <518 San Juan River at USGS gauge downstream at Bluff, Utah :::::23,000 <60,000 Source: Adapted from 1978 ER, Table 2.6-3 Figure No. 1 ....................... . 2 ....................... . 3 ....................... . 4 ....................... . 5 ....................... . 6 ....................... . ? ...................... .. 8 ....................... . 9 ....................... . 10 ....................... . 11 ....................... . INDEX OF FIGURES Description White Mesa Mill Location Map White Mesa Mill Land Map Generalized Stratigraphy of White Mesa Mill Approximate Elevation of Top of Brushy Basin Kriged 1st Quarter, 2014 Water Levels Showing Inferred Perched Water Flow Paths Southwest of Tailings Cells Seeps and Springs on USGS Topographic Base White Mesa 1st Quarter, 2014 Depths to Perched Water, White Mesa Site 1st Quarter, 2014 Perched Water Saturated Thickness White Mesa Site Groundwater (Well and Spring) Sampling Stations in the White Mesa Vicinity White Mesa Mill Site Plan Showing Locations of Perched Wells and Piezometers Mill Site Layout 12 ... ... .. .. .. ... .. .. ..... Drainage Map of the Vicinity of the White Mesa Mill 13. . . . . . . . . . . . . . . . . . . . . .... Streamflow Summary Blanding, UT Vicinity WYOMING UTAH Legend * Public Land Ownership White Mesa Mill Private • Town • Village -Highway --Road -·---··Stream --Intermittent Stream Tribal Land Bureau of Land Management Forest Service State Trust Land 1:300,000 3 1.5 0 MILES REVISIONS N Date: By 3 ~ County: San Juan State: Utah Locat1on Portions of T37S R22E S2~ Authoc areither FIGURE 1 WHITE MESA MILL LOCATION MAP Date: 5/20/2014 Drafted By: areither W.IUSA\Utah\Mill\MappiO!li\G'MJis.:harg~PamutAW\LandOwner.;lti~fltlop,m)((l' /6/212014 10:26:23 AM by IT!hefilll!l\on 24 C .-25 ~_;J4_ntl t~~t seh.ool Sect•on ----............ 1 '-..... \ \ ' I /I \ " ' ' \ ' \12 \ \ \ \13 \ ' """ .,.,.,----·~· Surface Land Ownership CJ Private ·~ Mill Site Claim ~ Utah State Lease 18 19 Bureau of Land Management \.,.. .... 31 COTTONWOOD I ( . ' \ ?:- 19 / ' ,, I \ 0 Bureau of Land Management \.~ I \,_ ) I I J ! I I '1 20 ' \ \ •, I ---r 8 I B~reau of Land Management 17 20_..-----,.. .. ·-( -, I ... , __ ~? \34 \. 1 !; 10 ' CJ)C (l.l>lif '::T::r o ~ ~r;; 2 ~·6. :i~ g ·~ ' CJ Blanding Municipal Boundary J - CJ Utah Land Trust School Section I ! ' ...., ~·, ~ ._ i.; \1 ·I ~ -' I · I .~.lii:PJ,I'i~,~lll~_20·13 ?/ttoni31 <?.e,09~~e:l11~ Societl,~cubed CJ Ute Mountain Ute 30 Legend U JjProperty Boundary c::JTownship and Range 0 Structures CJ Section Ov Seep or Spring ----Canyon Rim Well c._·· Pond • Active -----Drainage -$-Abandoned 29 Coordinate System: NAD 1983 StatePiane Utah South FIPS 4303 Feet N 1 IN = 3,000 FT t 3,000 1,500 0 3,000 SCALE IN FEET r I ... /~ ;/ J' / i . t£' .-ev ENERGYFUELS REVISIONS I Project: WHITE MESA MILL Data: By: I County: San Juan illtata: Utah Location: PortiOns oiT37S R22E FIGURE 2 WHITE MESA MILL LAND MAP Author: mhenington Data: 6/2/2014 Drafted By: mhenington 'I..() ~ ~J 1 . Le t 0 CD z . 0 "" ' " '· '• ', ' ' ' -, ', ' ' ' ' "" ' "'-\_ "" "'-, " " '· '-, ' "-. EOLIAN SAND COVERED BY UNCONSOLIDATED ALLUVIUM, COLLUVIUM AND TALUS SAND AND SILT, REDDISH BROWN VERY FINE-GRAINED ~-= MANCOS SHALE:::---~-= = SHALE, LIGHT GRAY, SOFT DAKOTA SANDSTONE SANDSTONE, QUARTZ, LIGHT YELLOW BROWN, POORLY SORTED, IRON CONCREATIONS, WELL INDURATED Q) , , ---" , ' BURRO CANYON FORMATION SANDSTONE, QUARTZ, LIGHT GRAY TO LIGHT BROWN, CROSS-BEDDED, CONGLOMERATIC, POORLY SORTED INTERBEDDED WITH GRAY-GREEN SHALE z . 0 0 n z (/) (/) w z ~ 0 0 CD I I- w I-<( . 0 ~ ..q- N X z 0 a: a.. a.. <( 0 L1) n z . 0 0 . 0 0 N z . L1) CXJ - ', "\_ '· -, "·"' ',""' ',"' ', ' - - --· -- r I ' I : Taken from Stratigraphic SecUon near Water Well # 3 BRUSHY BASIN MEMBER -------- WESTWATER CANYON MEMBER ----------- RECAPTURE MEMBER SALT WASH MEMBER SUMMERVILLE FORMATION ------------ ENTRADA SANDSTONE ------------ NAVAJO SANDSTONE -·---- z 0 i= <( ~ a: 0 u. z 0 C/) a: a: 0 ~ SHALE, GRAY, Gfli\Y-GREEN.I\ND f'Uf"Wl.E. Sll.lY Ill! PART WITH SOI,1£ SANO$T0NE LENSES SANDSTONE, ARKOSIC, YELLOW TO GREENISH GRAY, FINE TO COARSE GRAINED, INTERBEDDED WITH GREENISH-GRAY TO REDDISH-BROWN SHALE SHALE, REDDISH-GRAY SILTY TO SANDY INTERBEDDED WITH SANDSTONE, ARKOSIC, REDDISH-GRAY, TO YELLOW-BROWN, FINE-TO MEDIUM-GRAINED SANDSTONE, QUARTZ, YELLOWISH-TO REDDISH BROWN, FINE-TO COARSE-GRAINED INTERBEDDED WITH REDDISH-GRAY SHALE SANDSTONE, RED-BROWN, THIN-BEDDED, WITH RIPPLE MARKS, ARGILLACEOUS WITH SHALE INTERBEDS SANDSTONE, QUARTZ WHITE TO GRAYISH BROWN, MASSIVE, CROSS-BEDDED, FINE-TO MEDIUM-GRAINED SANDSTONE, QUARTZ, LIGHT YELLOWISH-BROWN TO LIGHT-GRAY AND WHITE, MASSIVE, CROSS-BEDDED, FRIABLE, FINE-TO MEDIUM-GRAINED Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO 80228 ~ -~ -DR-25 kriged top of Brushy Basin elevation contour and label approximate axis of Brushy Basin paleoridge approximate axis of Brushy Basin paleovalley X s386 abandoned boring showing elevation in feet amsl MW-5 ·5·191 TW4-12 0 5521 TWN-7 Q 5545 perched monitoring well showing elevation in feet amsl temporary perched monitoring well showing elevation in feet amsl temporary perched nitrate monitoring well showing elevation in feet amsl PIEZ-1 perched piezometer showing _, 5551 elevation in feet amsl TW4-32 temporary perched monitoring well ~5499 installed September, 2013 showing elevation in feet amsl RUIN SPRING 6 531)0 seep or spring showing elevation in teet amsl HYDRO GEO CHEM,INC. APPROVED APPROXIMATE ELEVATION OF TOP OF BRUSHY BASIN WHITE MESA SITE DilTS REFERENCE H :!718000!71802/ 201 4_GWDP _rehewal_app/Ubbel1 4rv.sr! FIGURE 4 .,.-... __....,.,rfo 0 inferred perched water path line potential perched flow pathline (assuming hypothetical connection to Cottonwood Seep) kriged perched water level contour and label kriged nitrate> 10 mg/L within area addressed by nitrate CAP kriged chloroform > 1 0 ug/L estimated area having saturated thickness less than 5 feet ® estimated dry area MW-5 e perched monil<!lring well TW4-12 0 ternporary perched monitoring well TWN-7 <> temporary perched nitrate monitoring well NOTE: MW:4, MW-26. TW4-•h TW4-19. and TW4~20 are chloroform PIEZ-1 ~ perched piezometer TW4-32 temporary perched monitoring well ~ installed September, 2013 RUIN SPRING b seep or spring HYDRO GEO CHEM,INC. KRIGED 1st QUARTER, 2014 WATER LEVELS SHOWING INFERRED PERCHED WATER FLOW PATHS SOUTHWEST OF TAILINGS CELLS APPROVED DATE REFERENCE H:/718000/71802/ 2014_GWDP _renewal_app/Uwl0314path.srf FIGURE 5 :2 "-m U) c..; 9 a 0 N ,_.: li; .0 E "' a. Q) (/) >. "' '0 lt ~ E (!) N a a a co ':::: (/) a 17 0.5 -·--0.5 -- i I •.-"' ~ ! I '- :\ ~t "-~ ! \.,... .~. ·' \ f' . ~/ .,.J 'Wo '::·~ ... \ 1f" + ---· ... _____. \_ ·-{,)--1-_., Mile \~ \~ / SEEPS AND SPRINGS ON USGS TOPOGRAPHIC BASE WHITE MESA g • WESTWATER Seep or Spring __. EM INC rpproved § L ____ ~54~68~----~E:I:ev:a:ti:o:n~(f:ee:t~):ab:o=v=e~m:e:a~n~s=ea~le~ve=I--------------~N~O~R~T!H~~~~~~~C~li~~~,~~~~·~S~J~S~~~~L_~~~v~-~--~v~ .. ~-~~--~-~-~--~---_.----~ ':::: "' Figure ·s ( ..... _, ® MW·5 .106 TW4-12 0 43 TWN-7 Q s6 PIEZ-1 ~63 TW4·32 ~49 estimated area having saturated thickness less than 5 feet estimated dry area perched monitoring well showing depth to water in feet temporary perched monitoring well showing depth to water in feet temporary perched nitrate monitoring well showing depth to water in feet perched piezometer showing depth to water in feet temporary perched monitoring well installed September, 2013 showing depth to water in feet RUIN SPRING o seep or spring NOTE: MW-4, MW-26, TW~. TW4-19, and TW4-20 are chloroform HYDRO GEO CHEM,INC. APPROVED DATE -llb~De1f alf:lnf.J ood ~,5 ~ ·~ 1st QUARTER, 2014 DEPTHS TO PERCHED WATER WHITE MESA SITE REFERENCE H :/718000/71802/ 2014_ GWDP _renewal_ app/Udtw0314.srf FIGURE 7 - ® MW-5 .12 TW4--12 0 29 TWN-7 ~18 PIEZ-1 Q 4Q TW4-32 ~64 estimated area having saturated thickness less than 5 feet estimated dry area perched monitoring well showing saturated thickness in feet temporary perched monitoring well showing saturated thickness in feet temporary perched nitrate monitoring well showing saturated thickness in feet perched piezometer showing saturated thickness in feet temporary perched monitoring well installed September, 2013 showing saturated thickness in feet RUIN SPRING b seep or spring HYDRO GEO CHEM,INC. p.PPROVED :~bong_onc9 lWN<n tw~l' 1st QUARTER, 2014 PERCHED ZONE SATURATED THICKNESSES WHITE MESA SITE DATE REFERENCE H:m 8ooom 802/ 2014_ GWDP _renewal_app/Usat0314.srf we.lls FIGURE 8 .. .. .. 4t • .. ' .; ..,__ .... • " '·"-~! ... I , .. -~ \"'··r; r;,'•" , . .. J, .... ~ ... ( ...... ~ .. !:. ~··-,) \ -\.~~ ,...J l # ,~ I .~-· 'L. ~ ./'1'' ·-'4t .. .. .. l : ;/ ,I I ! oj i -: .. , ~~ \ '\ ~\ •. I 0 JO· I ./ .. ! G1R \ A : N .,, __...-;,)~ E n ~ .. - s ~ 500' 0 1500' 3000' ~~ I I SCALE: 1" = 3,000' -:•~ '~ I .• ., ~ ;· , .... : I .• - -I ~ 1\ I I' i :·~··~··1 ··~··1 ····· ~ I ,., , = -~ •• •• . '-· I ' ».•• ~. ,. .... ~ . ~ ~ .· ~. i I ) 'I ~~ r I I f . ' ' l '· . . . ) I \ \ i j .-_::11!.1'?• <.... .. -r ~ ~ ":r ,,, , .. ... .. I ____.I I--~ A ~ I ~ \ ,~._.~...,.. -l·r ··· . C".;_/'' ~ I .. wf _,_/ ~ • " I >~~•'''""// .. -• ~· ·~.,. \ ./·. I !"' .. "'·""' (_ / ~ • GSR ... ./\ ' . . .. . # • ' : ,, . ~. .. ' ... r-~ .G4. > .. .. , .. • \ I ; I ~ r • • . .. • ..t ~ -4 .,. .. . .. . ' • • . -• I . .. G2R ---· ' I • : • .... 5 • • • • • • I • I • • • • • .:\\ ... ' ., ... 'I.e \ ... -:.,..\ "' \. • I _. ••• ~ ~~· ... ' --. .. ~ \ \~.-... ~ "1 : ~; ~ ~ - ~ ~~ \ ..... ; .. .. I ·:,'\I ~\""' -• ,, _ _,, ' ~ #~.fl~ 0 r I ··.! ~ ,, ........ ~ \,. ~ # ~.....,...,.. ) ... . ~ ., s . .... ... ,_..,_ o ' ~ ~ ~\ )~ - •• ~I t~· ~ ... i - "*,.r}'J.-.\....... ' , '\..,:· ' '· ·. \ .. ( \ ,, I)\ ... >\ ~ I • .. l , •• l •••• , •• ··~·· • I Ruin Spring • It G3RA • • • 1 ~(·.,., ' ; ': ',, ,.. .. ' Q; --..··'1 .· ~ I Q j ~~~ ..... ~~ •,.; ) '-\ ... • • ' .. \ \ .. .. #~ \ ' .. ..; # .,.. .. ~ • (_) L ... ""\. '·· .... ~~-·~~ ; I I • : '11 •• , •• 1 .... :It-• • ._ ! \:._";) > -, I\ I ... •. ' • (. .. , ,'I.') 4o • \ I # "-. \ ~ ~ ii I \ ·-....) I • ' ,, ' ' I! -. ... ' ; . I ..... ~ "" -. l ,_,.,w \ I '\.. \ \ I 1 • ,J># ~ --...,,~ \~ _) ..... I 1 .: \ ... ........_._ _ _) ( I! ... I ···---. ~ ( 1 .. ...,.wt.t't 1.(,;0 ·.) .. ' ~ ./ , .. .· ... !.(,; ( , ~ ~ .. ....... _. ·. .. ~ ,, ..... ) •• 1 ~ ·~-- .... • • • • i • I -~ , ¥ I * '·· . 1 . .. • I • • . .. •• • ~~·/t···· ' .. rn ~' . ~ ... I • .. \ ~ ~- ' "'' ... ~--... ..... ....,. .. ~~-• ,, 1"14. .. .. .... -A! l UTE ' . ~ \~, ~> .. ~~ • _A. G4R GROUNDWATER (WELL OR SPRING) SAMPLING LOCATION -•1• •1• •1• PROPERTY BOUNDARY RESERVATION BOUNDARY 5+ WATER SUPPLY WELL -··-··-CANYON RIM TW4-35 ¢ TW4-19 EB MW-5 • TW4-12 0 TWN-7 ~ PIEZ-1 ~ TW4-32 ~ ptoposed lemporary parohe.d msni1oring well perched chloroform or nitrate pumping well perched monitoring well temporary perched monitoring well temporary perched nitrate monitoring well perched piezometer temporary perched monitoring well installed September, 2013 RUIN SPRING b seep or spring HYDRO GEO CHEM,INC. APPROVED ~f-"d 1Wtl,n ~. <Q . ~. M¥1;18 -~, WHITE MESA MILL SITE PLAN SHOWING LOCATIONS OF PERCHED WELLS AND PIEZOMETERS DATE REFERENCE H:/718000/71802/ 2014_ GWDP _renewal_app/Uwelloc14.srf FIGURE 10 oo oo ~~:~-~' AMMs;>NIA SALT Q sx BUILDING Q KEROSENE 0 ~ 0 - oo 0 • SODIUM CHLORATE SAMPLE PLANT I I D TOPS<?IL :-\] j ) ·7 ,•) v ·· .. -----· .-· .. 100 50 N s 100 200 SCALE IN FEET Resources (USA) Inc, Energy Fuels Blvd Suite 600 225 Umon d CO 80228 Lakewoo • • 1 USGS GAUGE NO. 09376900 • 2 USGS GAUGE NO. 09378630 • 3 USGS GAUGE NO. 09378700 81ACK 1:\~!>.l• V1Tf '6ci6' J I \ I 400 I-350 UJ UJ u.. uJ 300 -0:: (.,) <( AVERAGE ANNUAL FLOW=950 AF-(1966-2001) DRAINAGE AREA=3,77 SQ. MI. AVERAGE ANNUAL YIELD=252.1 AF/SQ. MI. - .---YIELD-AF/SQ, Ml MIN. AVG, 1600 t:u 1400 UJ u.. ~ 1200 (.,) MAX $ 250 ~-~1000 0 _, u.. ~ 200 . I I-150 z 0 :::;; UJ 100 (.!) ~ 50 -UJ ~ t:u 400 UJ u.. uJ 0:: 350 300 2.7 252 (1990) - ,- . JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC MONTH RECAPTURE CREEK NEAR BLANDING USGS GAUGE 09378630 AVERAGE ANNUAL FLOW=7757 AF-(1966-1971) DRAINAGE AREA=4,95 SQ. MI. AVERAGE ANNUAL YIELD=153 AF/SQ. MI. 881 (1983) ~ $ 0 YIELD-AF/SQ. Ml _, u.. ~ I t-z 0 :::;; 250 200 150 UJ ~ 100 I MIN. AVG. 46.9 153 (1971) UJ 50 ~ ~ 0 JAN FEB 0MAR APR MAY JUN :::SEP~DECJ MONTH SPRING CREEK ABOVE DIVERSIONS, USGS GAUGE 09376900 0 _, u.. >-_, I I-z 0 :::;; UJ (.!) ~ UJ ~ MAX. 262 (1966) 800 600 400 200 - AVERAGE ANNUAL FLOW=6547 AF-(1965-1986) DRAINAGE AREA=205 SQ. MI. AVERAGE ANNUAL YIELD=32 AF/SQ. MI. - YIELD-AF/SQ. Ml MIN. AVG. MAX. 4.9 (1976) 32 88 (1983) I - -Lr lit JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV d MONTH COTTONWOOD WASH NEAR BLANDING USGS GAUGE 09378700 NOTES 1. FOR THE LOCATION OF WATER COURSES SUMMARIZED, SEE FIGURE 3.7-1 2. SOURCE OF DATA, WATER RESOURCES DATA RECORDS. COMPILED AND PUBLISHED BY USGS. REVISIONS Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO 80228 WHITE MESA MILL Date By I c.;oun!y: San Juan 1 ::;tate: utah 5-1 4 DLS Location: ::;cate: N/A Figure 13 Streamflow Summary Blanding UT Vicinity j Date: Aug, 2009 j DraltedBy: D.Siedd Streamflow Summary dwg Figure 13 I Appendix A .................... . B .................... . c .................... . D .................... . E .................... . F .................... . G .................... . H .................... . !. ..................... . J ..................... .. K ..................... . L ..................... .. M ...................... .. N ..................... .. INDEX OF APPENDICES Description Radioactive Materials License Amendment No. 4: March 31,2007 White Mesa Mill Site Maps with Well Locations Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill, Revision: 1, June 10, 2011. Results of Soil Analysis at Mill Site Tables: Chemical and Radiological Characteristics of Tailings Solutions, Leak Detection Systems and Slimes Drains Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan 07 Ill Revision: Denison 2.3 Stormwater Best Management Practices Plan, Revision 1.5: September 2012 White Mesa Mill Discharge Minimization Technology (DMT) Monitoring Plan, 7/2012, Revision: Denison-12.1 White Mesa Mill Tailings Management System, 7/2012, Revision: Denison 12.1 Cell 2 Slimes Drain Calculations and Figure 2009-2013 White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) Date 6/6/2012 Revision 7.2 Tailings and Slimes Drain Sampling Program, Revision 2.1, July 30,2012 Contingency Plan, 12111 Revision: DUSA-4 White Mesa Mill Containerized Alternate Feedstock Material Storage Procedure, PBL- 19, Revision: 1.0, December 18, 2012 0 .... .. ... . . . .... .. . . . .. . White Mesa Mill Chemical Inventory Appendix A Radioactive Materials License Amendment No.4: March 31,2007 ~.15.1937 t:33JM 1'().340 P.4 TECHNICAL EVALUA TlON REPORT REQUEST TO RECEIVE AND PROCESS AL ~NATE FEED MATERIAL DOCKET NO. 40-8681 LICENSEE: International Uranium (USA) Corporation FACILilY; \Nhite Mesa Uranium Mill PROJECT MANAGER= James Park SUMMARY AND CONCLUSIONS: LICENSE NO. SUA-1358 The U.S. NuClear Regulatory Commission staff has reviewed Energy Fuels Nuclear, Inc.'s (EFN's) request dated Apnl s, ·i 997, to receive and process uranium-bearing material currently contained at Cabot Performance Materials' (CPM's) facility near Boyertown, Pennsylvania. The material would be processed at the White Mesa mill, of which EFN is the former owner. The current 0\lllner of the mill and NRC licensee, International Uranium (USA) Corporation (IUC), previously has agreed to abide by all commitments and representation made _by EFN. Based en its review of the Apnl 3, 1997, submittal and additional information provided by letters dated May 6, May 19, June 20, and August 6, 1997, the NRC staff considers the amendment request acceptable. DESCRIPTION OF LICENSEE'S AMENDMENT REQUEST: By its submittal dated April3, 1997, EFN requested that NRC Source Material Ucense SUA-1358 be amended to allow receipt and processing of alternate feed material (i.e., material other than natural uranium ore) at its White Mesa uranium miU located near Blanding, Utah. This uranium-bearing material, weighing approximately 16,000 dry tone, is held curTently by CPM at its facility near Boyertown, Pennsylvania. The material is a moist solid (up to 40 percent moisture content) which contains uranium at an average concentration of 0.3 percent by weiahft and P,...onomically attractive cancentrations of tantalum and niobium. CPM is authorized to po688SS this material under NRC Source Material Ucense SMB-920. The material will be shipped by train and exclusive-use trucks from CPM's facility to the White Mesa mill in intermodal containers. After being loaded and sealed at CPM's facility, the containers will be transported by truck to a nea1rby intermOdal rail terminal. The containers will be loaded on flatbed railcars and transported crcss-country to the final ran destination (either Grand Junction, Colorado or Green River, Utah), where they will be transferred to tnJcks fer the final leg of the journey to the White Mesa mill. Each container has a capacity of 25 cubic yards, and it is expected that approximately 15 containers will be loaded and transported each day. At the mill site, the uranium-bearing material will be emptied from the intermodal containers into the ore receiving hopper. From there, the materiaJ will be processed through the semi- autogenous grtnd (SAG) mill, where water will be added to aeate a slurry, which is then 1 fl,X;.15.1997 t:34A1 t<l. 34e P.S pumped to .a pulp storage tank and from there into the leach cln:uil 1n tha 1each circuit. the slurry will be treated to separate the uranium frotn the tantalum and niobium, and IUC wm ublize the uranium and vanadium solvent extraction circuitB, respectively. to recover these metals. IUC plans to add two filter presses and some additional piping to its mill circuit to aid in the processing of this material. Watsr spray systems will be utilized to reduce the potential for dust dispersion and airtome contamination in emptying the intennodal containers. Other than the slight circuit cnanges mentiOned previously, IUC anticipates that processing the uranium-bearing material will not differ from processing natural uranium/vanadium ores. IUC will provide per&onal protective equipment (coveralls, gloves, and full-face respirators (to be used if needed)) to individuals engaged in processing the material. The efficiency of airborne contamination control measures during the material handling operations will be assessed in the immediate vicinity of these operations. Alrbome particulate samples and breathing zone samples will be cclledad during initial material processing activities and analyzed for gross alpha. Sampling results will be used to establish health and safety guidelines to be implemented throughout the processing operations. Additional environmental air samples wiD be collected at nearby locations to the material prccessjng activities and analyzed to ensure that the established contamination control measures arw adequate and effective. Trucks used to transport the material to the mill site wiD be radiometricaUy scanned upon arrival to ensure that leakage has not occurred and that radiation levels are_ within appropriate limits. TruckS will again be scanned prior to theiT release from the site restricted area. In addition, the intermodal containers used to transport the material will be properly closed, cleaned (if necessary), surveyed, and documented before leaving the site. TECHNICAL EVALUATION: The NRC staff has review8d JUC'a raquest In accordance With 1 o CFR Part 40, Appendix A. requirements and NRC staff guidance ~mal Position and Guidance on the Use of Uranium Mill Feed Material Other Than Nmural Ores" (60 FR 49296; September 22, 1995). This guidance (referred to hereinafter aa the alternate feed guidance) requires that the staff make the following determinations in its revtewa of Hcensee requests to pnx:es\!1 material other than natural uranium ores. 1. Whether the feed material meets the definition of "ore;"' 2. 'lllhether the feed matetial contain& hazardous waste: and 3. Whether the ore is being p~ primarily fur its source-material content. 2 AUG.15.1997 1:34PM t-«J. 34e p. 6 Deteanination of whether the feed material js "ore" For the tailings and wastes from the proposed processing to qualify as 11 e.(2) byproduct material, the feed material must qualify as "ore." In the alternate feed guidance, ore is defined as " ... a naturat or native matter that may be 1'11ined and treated for the extraction of any of its constituents or any other matter from which source material is extracted in a licensed uranium or thorium mill ... lhe proposed alternate feed material contains uranium at an average concentration of 0.3 percent by weight therefore, it meets the definition of "source materia~" as defined at 1 o CFR 40.4. IUC i& proposing to extract this uranium. Therefore, the material meets the definition of ore, because it Is a "matter from which source material Is extracted In a licensed uranium or thorium mill." Determination of whether the feed material contains tevatdOJJS.waste Under the aHemate feed guidance, proposed feed material which contains a listed hazardous waste wm not be apprawd by the NRC staff for processing at a licensed min. F~ materials which exhibit only a characteristic of hazartlous waste (I.e., lgnitablllty, corroalvity, reactivity, or toxicity) would not be regulated as hazardous waste and could therefore be approved by the staff for recycling and sxtradian of source matenal. However, this does not apply to residues from water treatment. Therefore, NRC staff acceptance of such raidues as feed material would depend on their not containing any hazardous or Characteristic hazardous waste. The NRC staff has reviewed the following sources of information in detennining whether the uranium-bearing material i& or contains hazardous waste: (1) the average c:ompoaition data for the material, as submitted by IUC on June 20, 1997, (2) 1he results of additional testing, as provided by letter dated May e. 1997 I (3) NRC files for the Boyertown fadlity, which address, in part. the proceu used to produce the material and the methods used to store the material, and (4) supplementary information concerning the State of Pennsylvania Department of Environmental Protection's hazardous waste regulations. In additionw as an attachment to a Jetter dated August 6, 1997, IUC provided an atradavit from CPM In which CPM affirmed that the material is not and does nat contain hazardous waata. Based on its revieW, the NRC atatr finds that the uranium-bearing material ia not hazardous wasta and does not contain hazardous waste. The NRC staff has determined alBa that the uranium-bearing material is not • residue from water ~nent. This material is the result of the initial processing of raw ares containing tantalum and nlabtum. Therefore, the NRC staff considers the uranium-bearing material acceptable for recycling and extraction of source materiaL 3 ~.15.1997 1=35PM 1'(). 348 P. 7 - OeterminifAgn of whether tt1e feed material js being proce§Sed prjmantv fcc its soyrce:material content · To show that potential alternate~ material is being processed primarily for itB source- material content, a licensee must either (1) demonstrate that the material would be approved for disposal in the tailings impoundment under the 11Rnal Revised Guidance on Disposal of Nan- Atomic Energy Ad of 1954, Section 11e.(2) Byproduct ~aterial in Tailings Impoundments;" or (2) certify, under oath or affirmation, that the material i& being processed primanly for the recovery of uranium and for no other primary purpose. Any such certification must be supported by an appropriate justification and accompanying doaJmentation. The licensee has provided a signed affirmation that the uranium-bearing material is being processed primarily for the recovery of uranium and for no other primary purpese. IUC states that the uranium content of the material, in conjunction with the reduced uranium processing costs associated with the recovery of the tantalum and niobium, makes processing the CPM material economically attractive to IUC. The NRC staff has discussed with IUC the business arrangements regarding the material and finds that IUC is paying CPM for the acquisition of the material. The NRC staff has reviewed the anaJytical data provided by IUC and infannation contained in the NRC's flies fbr the CPM facility, and finds that the uraniUm concentration in the material is comparable With th• in natural uranium ores which are and were normally processed by uranium mills in the U.S.. These natural ores contained uranium at concentrations of 0.3 percent and below. Therefore, the NRC staff conside1'1!1 IUC'a justification to be acceptable. Conclusjons concerning alternate feed material designation Based on the information provided by the licensee, the NRC staff finds that the CPM's uranium- bearing matenal is altema1e feed material because: (1) It meets the deftnltion of •are," (2) tt does not contain hazardous waste, and (3) it Is being processed primarily for its source-material content Other cgnsjc;leratigns The NRC staff has alsa concluded that the proce&slng af this material wtl not mutt In (1) a significant change or Increase In the types or amounts of effluents that may be released offsite; (2) a significant Increase In Individual or cumulative occupational radiation exposure; (3) a significant construction impact; or (4) a significant increase In the potential for or consequences from radiological accidents. Thill canctuslon fa based on the following fnfonnation: a. Yelowcake produced from the processing of this matartal will nat causa the currantJy- approved yeOowcake pnxtuction limit of 4380 tons per year to be exceeded. In addition, and aa a resutt. radiological doses to members of the public in the Vicinity of the mill will not be elevated above levels previously assessed and approved. 4 . . ~.15.1997 1:35PM 1'().34e P.8 b. The-physicaf changes to the miU cira.Jit that JUC wil implement to process this material are not significant. No c:onstruction impacts beyond those previously assessed will be involVed with these changes. c. Tailings produced by the processing af this material wiU be disposed of on-site in an existing lined tailings impoundment (Cell 3). The addition of these tailings (a maximum of 16,000 tonsj to Cell3 w111 increase the tctP1 amount of tailings in the cell by one percent, to a total at approximately 69 percent of cell capacity; therefore, no new impoundments are necessary. The design of the existing impoundments previously has been approved by the NRC, and IUC iS required by its NRC license to conduct regular monitcring of the Impoundment liners and of the groundwater around the impounclments to detect leakage if it should occur. d. The uranium-bearing material contains metals and other parameters which already are present In the mill taiHngs dispoaed of in the Cell 3 impoundment. Analysie of samples from the uranium-bearing material and from Cell 3 show that the only.pc.. i::ll.netens present in significantly higher concentrations in the uranium-bearing material are fluorine and carbon. Howaver, these concentrc •i ....... should not hava an advenla impact on the overall Cell 3 tamngs composition, because the amount af tail~gs (a maximum of 16,000 tons) produced by processing the material is not significant in comparison to the total amount of tailings currently in the cell (approximately 1.4 mDIIon tons). Additional~. as stated previously, IUC is requi~ ta conduct regular monitoring of the impoundment leak detection systems and of the groundwater in the vicinity of the Impoundments to detect leakage if it should ccc:ur. e. For the following reasons, it is not expected that transportation impacts associated with the movement of the material by train and truck fram Pennsylvania to the White Mesa mill will be significant: • The material will be shipped as '"low specific a~ material in exclusMHJ&e containcl"'i (I.e., no other materials will be In the cont.inel"'i with the uranium- bearing material). The containeR will be appropriately labeled. placarded, and manifested, and shipment& will be tracked by tha shipping company from CPM's facility until they reach the Write M8S11 mnl. • On average during 1998, 370 trucks per day traveled the stJ etch of State Road 191 between Monticello, UT and Blanding, UT (penaonal communication wfth the State d Utah Department of Transportation). An additional15 trudcs per day travelng this roule to the mill represents an incre8sed tratriG load of only four percent. Shipnenta are expected to take place over the course of a limited time period (three to siX months). • The containers and trucks involved in transporting the material to the mm site will be surveyed and decontaminated, as necessary, prior to leaving CPM's factllty for Whita Meaa and again prior to leaving the mnl site for the retum trip . 5 AUG.15.1997 1:36PM 1'(),34a P.9 f. Mll~proyees Involved in handling the material wil be prtwided Wfth personal protective equipment. including respirat~ry protadlon. AJrbome particulate and breathing zone sampling resurts wt11 be used to establish health and safety guideHnes to be implemented throughout 1he processing operations. RECOMMENDED LICENSE CHANGE: Pursuant to Trtte 10 of the Code of Federal Regulations, Part 40, Source Material Ucense SUA-1358 will be amended by the addition of License Condition No. 10.9 as fallow&: 10.9 The licensee ia authorized to receive and process source material from Cabot Perfonnance Materials' facility near Boyertown, Pennsylvania, in accordance with the amendment request dated April 3, 1997, aa amended by submittals dated May 19, and August 6, 1997. ENVIRONMENTAL ;;.A?ACT EVALUATION: Because IUC's receipt and processing of the .,:ner;al wm not result in (1) a significant change or inaeas~ in the types or amounts of efftuer.ts that may be raleased otfBite; (2) a significant increase in indiVidual or cumulative occupational radiation exposure; (3) a significant construdion impact; or (4) a significant inCJ8ase In the potential for or conuquences from radiological accidents, an environmental review was not performed since actions meeting theSe criteria are categorically exduded under 10 CFR 51.22(c)(11). 6 lliiiitli'WWW1iililWWlliWWWtp U.S. NUCLEAR REGULATORY COIOIISSION MATERIALS UCENSE ............... ,. ~"AGE 1 ~ · 8 ~P.t..ees Putsuaot to tbe Atomic: EDeqy AA:t of J9S4, u amended, the Et1ergy Rcorpniuti01l Act of 1974 (Public Law 93-438), aucS Title 10, Code of Federal Regulatioa.s, Chapter I. Puts 30, J I, 32, 33. 34. 35. 36. 39, 40. and 70. ud in teliance on statemrnu IJid repRXDwions hetetofore made by tbe licellsee.. a license iJ hen!by issued aulborizin~ the licensee to receive, acquim. possess. uui transfer byptoduc:t. source, and special nuclear materi31 designated below; to ase mc:h material far !he ~(1) md at tbe place(s) de.sipated below; to deli vet or uaDJfer 1ucb material to penOWI authorized to rec:eive it in acconfana: with uae n:gulatio111 of the applicable Put(s). This license shall be deemed to contain the conditious specified in Section 183 of tbc Atomic EDergy Act of 1954, u amended, and is 1ubject to all ;~ppliuble rul~. regulatiODI, and orders of the Nuclear RegulatOJ1' Commission now or hereafter in effect an4 tO my conditiom specified below. --------------------------------r-------------------------------~ 2. International Uranium (USA) Corporation [Applicable Amendments: 2.] 6425 S. HighWay 191 P.O. Boxaoi Blanding, utah 84511 3. License Number 6. Byproduct, Source, .mdlor Special Ntl(;l~ Ma&cri~ 7. Chemical audlor P11y ~....1 . Form . 8. Muirm•m Amount tiW l.itJ':nsec May Poaaeu at AtJ.y One ThDc UDderlbis License Natural Uranium Any SECTION 9: Admlnlstratlva Conditions .. 9.1 The authorized place of use shall be the liCensee's V'Jh1ta Mesa ~ium mil6ng facrlity, located in San Juan County, Utah. · 9.2 All written noticeS and reports to the NRC raquirad under this liCense, with the exception of incident and event notiftcations under 10 CFR 20'..2202 and 10 CFR -40.60 requiring telephone notJftcation, shall be addressed to the 01ief, Uranium Recovery Branch, Division of Waste Management. Ofllce of Nudear Material Safety and Safeguards. Incident and event notifications that require telephone notification shall be made to the NRC Operations Canter at (301) 816-6100. 9.3 The licensee shall conduct operations in accordance with statements, representations, and conditiOnS contained in the ficense renewal application submitted by letter dated August 23, 1991, as revised by submittals dated J~nuary 13, and April7, 1992, November 2.2, 1994, July zr. 1995, Oecen'mer 13, and December 31, 1998, and January 30, 1997, whiCh are hereby Incorporated by reference, and for the standby Trust Agreement. dated April 29, 1997, except where superseded by license conditions bakJw. \Nhenever the ward "wilr is used in the above rafar~~nced documents, it shall denote a requirement [Applicable Amendments: 2] 9.4 A The licensee may, without prior NRC approval, and subject to the c;onditions speQf'Jed in Part B of this condition: (1) Make changes in the facility or process, as presented in the application. AUG.15.1997 1:37PM P.11 ~·a. 'A' A a· 'A~~.~~ .. ~ 7A" ... ~'a· ·a· ·a· ·a a -MATERIALS LICENSE SUPPLEMENTARY SHEET August 15, 1997 (2) Make changes in the procedures presented in the application. (3) Conduct tests or experiments net presented in the a~pplicaticn. B. The r.censee shall file an application for an amendment to the license, unless the following conditions are satisfied. (1) 'The change, tet. or experiment does not conflict Mth any requirement specifically stated in thiS license, or impair the licensee's ability to meet au applicable NRC regulations. r:;:n --:- (2) There i& r.o degtad~?;in ~ ~\r;~ or environmental comr,litments in the llcenSfRppU~on. or provided tJY tht:t .aj,proved reclamation plan • • ~. ,'l ....,.4 .. v •. <..' ··~ ., .. ~ (3) The ~riga, test, or_ experiment Is consistent ~lte condusions of actions an~ and selected in the i:A dated FebNary 1~~ ·~ . . .. .-... . c. The n~·s 'd~enrinations concerning Part B pf-tfl~r'fdition, shall be made by a "Safety and Envt~trtal Review Panel (S~~: ·:The S~lthall co~lat of a mlnlrnum of three incfMduals. One .member'af,~~ERP shal~Mv& expertise In management and ~ ~ponSib(e-for~al and fina),cial eppi'OVQJ ch~nges; one member shall h~ve ~rti~ in operat!o.~~ar con~rt and shall have respq()Sibility tor lfnP.Ien'lenting -atrj ~'!ill; ~ilnges; and, oq,, member shall be the COlJlOrate radlatan ~·-~ \CR~) ~.~lent. with~ ~ponslbifrty ot assurtng chan~.ccnfalm to. rlldfi11191) 1saf8tY . .ahd ~~'tequlrements. Additl011al rnernl:iers may be incfud8d 11'1 .thti SE~ ~:approp~. to address technical asp·adts.'such ~ ~ ~~~d~~~r ~. sw. water hydrology, spacffl~,.alih sdf[!t1~ an6o~A« ' :n~1:~9anes, T~~~ry members or pecmane!)t members, othef than 1he three a~speQfief.t.1ndJviduals. may be consuhaiits: :.: ·:r1 • ·~~ ·) I ' ' •• )J" '~· ·:-• • ~~"-.. ,• •• t \ I •., ~"~ D. The ftcansee~"J maintain ~ids of any chang~~a pursuant to th:J condition until rrcense tem'linat{pn. These records s~~ i!'clUV.,~n safety and environf1'8ntal evaluations, made tJYltle SERP, ~ ~·basis for detemining changes are in compliance with the requlniftMtnlj.(Bfitjt~ td'ln Part B of this condition. The licensee shall furnish. ln an .tMual111port to NRC, a description of such changes. tests, or expetirrieilts, lnduding a summary of the safety and environmental evaluation of each. In addition, the licensee shaU annually submit ta the NRC changed pages to the Operations Plan and Reclamation Plan of the approved license application to reflect changes ~ under this condition. The licensee's SERP shall function in accordance with the standard operating procedures submitted by letter dated June 10, 1997. [Applicable Amendments: 3) NRC FOAM 314A (7 .... 1 9.5 9.6 •••••••••••••••• ¥ 1997 The licensee shall maintain an NRc-approved financial surety arrangement. consistent wtth 10 CFR 40, Appendix A. Crtteria 9 and 1 a, adequate 1o caver the estimated costs, if accomplished by a thirU party, for decommissioning and dec:ontan'tination of the mill and mm site, for reclamation of any tailings or waste disposal areas, ground-water restoration as warranted and for the long-term surveillance fee. Within three months of NRC approval of a revised reclamation/dec:ommissioning plan, the ncensee shall submit, fOr NRC reView' and approval, a proposed revision to the financial surety arrangement if estimated costs in the ne'Niy approved plan exceed the amount covered in the existing financial surety. The revised surety shall then be in effect within 3 months Of 'Mitten NRC approwl. Annual updates to the ~mo~~~O. CFR 40, Appendix A, crnena 9 and 10, shall be submitted to tne NRC:.&Meast' 3 moritRS.;n·tD~e anniversary data which is designated as June ~ {Jr ;actf yesr. If the NRC has nOt'll&ep,coved a proposed revisicn to the surety coverage 3Q:&ffS·pnorto the expiration date of the tixi~ surety arrangement. the licensee shaJI extena;1he existing sunrty ai'T3ngament for 1 yif~,AJong with each proposed revision or annui:"iipdate, the Jfcensee shall submit supporting~dc;:umentation showing a breakdown o~tt)e costs-and the basis for the ccst estfmat~th':ir$Jstments for inflation, ma~n~enanct ·or..a mfnrtn~~ percent contlngencv.f~.:~ ih.:!t'glnee~ng plans, activities petlbrmed an~ .any. other conditions affec::jing· mated costs for site closure. The basis forth& cost estimate" i$ !he 'NRC app~tM~d,r8ci~nl~i!lsioning plan or NRC approved l'e'tisions to th&_J'I~.,:-Tlle previously P.~ldance e~ •Reccmmefldad Outtlne for 'Stta Spedftc ~on 3Qd $abt~~ ~ ~..ouUJnes the minii'T1Um considerations used ·ay.fhe ~C ~r:t·~e revtewof,~~~ure:estimaf!,%. Reclamati~eco~•ianlng 'plaiJ5 ~cj. ~~·p~es should foll~this outfine. •,I ' ' • I I ! f I • • I • f ! • The eurrentfV'approvecfsLIJBty i~nti: Performanett:B!)nd 18-2~1; issued by National Union Fira lrmkr:anca ~ny .in faVOr .of tha N~S ~~;tft8 associ~ Standby Trust Agreement, ~ Aprfl29, .,997·, ~a11 .be ecintlh~&inaintained:lfl an amount not less than $11,278,1.34 for the purpl):Se of COh'lp~ ~·~ CFR 40t~ndlx A. Criteria 9 and 10, until a repl~nt is authorized by 111a NRC: 1 • • ,. '*·· • · . . . . ' ,.,. ·• ' !.. ·~:1 [Applicable Amandr,1811~: 2, 3] l·~ ... ' I \ 11 .~ '" ,.._, Standard operating proceddtti shall t1,e·e~~~~ followed far an operationai process activities involving radiaactivw matariaiS-ihat fll1! handled, processed, or stonld. SOPs for operational adivities shaD enumerate pertinent radlation 811fety practices to be followed. AdditionallY, written procedures shall be established fOr non-operational activities to Include in--plant and environmental monitoring, bioassay analyses, and Instrument calibrations. An up-to-date c:Dpy of each written pnx:edure shall be kept in the mill ~ to which it applies. An written pnxedura for both operatlonal and non-openltianal activities shall be reviewed and approved in writiog by the radiation safety offtcer (RSO} before implementation and whenever a cflange in procedure is proposed to ensure that proper radiation protection principles are being applied. In addition, the RSO shall perform.a documented review of all existing operating proceduru at least annually. 9. 7 Before engaging in any activity not previously assessed by the NRC, the licensee shall administer a cultural resoun:e inventory. All disturbances associated with the proposed development 'Will be completed In compliance with the National Historic Preservation Act (as .. AUG.15.1997 1:38PM U.S. NUCL~R REGULATOOY C01MSSa0N 1 -~MATElUALS LICENSE SUPPLEMENTARY SHEET amended} and its implementing regulations (36 CFR 800), and the An::haeological Resources Protection Act (as amended) and its implementing regulations (43 CFR 7). In order to ensure that no unapproved disturbance of c:::ultural resources occurs, any work resulting in the discovery Of previously unknown cultural artifacts shan cease. llle artifacts shan be Inventoried and evaluated in accordance with 36 CFR Part 800, and no disturbance shall occur until the licensaa has received authorb;ation from the NRC to proceed. The licensee shaH ~oid by project design, where feasible, the archeological sites designated "conttfbuting" in the report submitted by letter dated July 28, 1988. When it is not feasible to avoid a site designated "contrjb~nsOtn tf\l)~d~tf)e licensee .shall institute a data recovety program fOr that site based qb-tt)&~ ~ ~.,~ by letter from C. E. Baker of Energy Fuels Nuclear.*"'M.~Metvin T. Smith, Utah ~rt~c Preservation Officer (SH~). dated ~~:~.~;~i981. 't1,;: .• , The licensee s~~er through archeological excavation ai~.:SSntnbuting" sites listed in the report whid))'are-1o~ed in or within 100 feet of borrow ~ile areas, construction ~. o~!! ~eter of.the reclaimed ~l.lng~ Jmp~dmenl Data recovery fieldwork at ~ch site ~:1hese criteria shaU beco~ltted prior to the start of any pn:~ject related disturbance Within 100 feet of the sfte,. J.Jat.analysis a~.report preparation need not be complete. · '. \ :~··.:; · -~ ., . · t ,. • .. t : "; I •"•.' • • ~ Additionali'yf tJ,e licen~ Shaf\:~~uct·~·te:mng··~.b required to.~able the Commission to detennlne. if those.~ites Cleitgr:'Bte9 .fS ... U!J_!:i~~~" in ,the repo~~1ld located within 100 feet otf)resent o~il,1.own ~11!t·~·~f88S are: of ~ch s~lftcance to warrant their redes~tion o ·~r:itributlhg.." In·~~,,~~ such t~ shall ~'eompleted befOre any aspec:tofth~ .. w~ertakinQ . .'~~·~~·~· ~1 1 .!~· ··:: .. ,.A~ · ~~· 0 t. f •I I .. I \.o • o • t • ~ 0 ·~-· '"I\ ? ... ArcheologfcaJ~tractoii Shiill-be a~'veei.iR ~i,Ji~ the Cq•fi~lan. The Commission wtll approve an tlr,aheologfcal c:On~orWba ~~ minlmu~~dards for a principal investigator set foJ1tl in 38 CFR Part.f58.; Atianfndix c,··and ~quaURcations are found acceptable by the oi-:1~. ~~ .. ~ 9.8 The licensee is hereby ~o posseSSr~uct material In 1he fonn of uranium Wlilste taDings and other urantum,&J~ _.. gaoerated by the licensee's mflllng operations authorized by this license. Mill tailings shaU not be transferred fram the site without specific prior approval of 1he NRC in the fon'n of a license amendment. The licensee shall rnai 1tain a permanent record of all transfers made under the provisions of thi.s condition. 9.9 The licensee is hereby exempted from the requirements of Section 20.1902 (e) of 10 CFR Part 20 for areas wiihin the mill, prov;dec:t that all entrances to the nill are conspicuously posted in accordance with Section 20.1902 (e) and.-. the 'M)rds, •Any area within this rmll may contain radioactNe material. • 9.10 Release of equipment or packages from the restricted area shall be In accordance with "Guidelines for Oeccntamlnation of Facttitfes and equipment Prtor to Release far Unrestricted Use or Tetmination of Ucenses for Byproduct. Souree, or Special Nuctear Material," dated May 1987, or suitable alternative proceduru. appi"DVed by the NRC prier to any such release. ~.15.1997 1:39PM NRC FORM 374A (7-861 u..S. NUCLEAR REGULATORY COfAISSION -MATERIALS LICENSE SUPPLEMENTARY SHEET SECTION 10: Operational Controls, Limits, and Restrictions 10.1 10.2 10.3 10.4 10.5 10.6 10.7 10.8 The mill production rate shall not exceed ~0 tons of yenowcake per year. All flquid effluents from mill precess buildings, with the exception of sanitary wastes, shall be retwned to the mill drcuit or discharged to the tailings impoundment. Freeboard rrmits for Cells 1-1, 3, and 4A, and tonnage limits for Cell3. shan be as stated in Section 3.0 to Appendix E of the approved ncense application. Disposal of material and equip~,~n(~.._.,e mill site shall be conducted as described in the licensee~ subMiftals~ ~ 12, 1994 and May 23, 1 ~. with the following addition: ."'"... ·~ ,.,. ·•• · ·~ .:i · .. , r•, .. "'-' '''t' :, ... : ·~yf ;} A. The maximyin..ltfl thickness for matP.Iials placad over't:aftri:igs shall be less than 4-feet thick. Su~uent ltfts .shall be less than 2-feet thick. Eiicti lift shall be compacted by trackins;¢ ~~-equipment. such as a cat ~~ at le~ ~ prior to placement of subsaquant littS:.r. .. _ . · · ·' ·" , · ' • I!. " .~::~ • o·"' I ~.J .... ~ • .... -' • " \ ,.• I ' • / o In accordai,'K:e with the Dcansee'& submittal dated~;20i 1993, the11q!tnsee Is hereby authorized tQ:dlspose of 1JYpr:Uquc:t ~~ gen~ .U·Ucensed irt'SitU leac:O facilities, b . ..,.,. to hi.-_ foflowi • ~ ' I l'• • ""' su ~-U'ftJ ng c:on~:u.avn&: • · ,· .:·~ :· .. ~> a • • "'. I • '• • • ' J, • f • ' r.., -0 (/ 0 1 , 00 I I 0 0 .l ... •; '.,• ,. \Q.''• A. Disposal of wast& is limbd'lb 5QQO eub~~:~m .-single ~~rca. •• • • • J) •' • .. ·.. .. ;., ., .... i 'IIi . .. '., -•' . .. .. ;: . B. All ~n~~9Uipme~.~~l ~'Cit~~. ~. or ~oned to minimize void spat:e5. Bilt't'!t•.~ntainingc ~ tder thm:.~Oit or sludjJ)S shaU be emptied into the ~al area)nd-ihe ~at'tet,;~: ~~ contain.~·son or sludges shall be verified \Q.be t\JII prior to disposid. ~~Is f'Otdotnpletetyt~t-:wtl be filled with tailings ,.. .... -11 ) 1 • ,I,~J, ) ' ._tP•, "" :M.II • • .... 'I\ '!\.. "-" .... ' t f , I',: 'J '•J ... ·~· ... , l"l\~ :· c. All waste shaii.de:Ouried in ceo No.3 unless prior~ approval iS obtained fre1n the NRC for attarrtatii bu~ location~. , \, ~ ~~ ,( ..:. . 'l-"~ 14 ::b_..__. o<J.~ D. All disposal aCtiVitieS shaD -tMi d~ti:ijh8~. ·, ne documentation shall include desctiptians of 1t\e waste and the disposal tacatlo~. as w.=ll as an actiOns required by this condltfon. An annual SU1TWT1aTy of the amounts of waste disposed of frtlm off-s-ite generators shall be sant to the NRC. The ncansee is authorized to racaive and process soun:e materialS from the Allied Signal Corporation's Metropolis, Illinois, facility in accordance with the amendment request dated June 15, 1993. The licensee is authorized to receive and process source material from Allied Signal, Inc. of MetJ:opolis, Illinois, in accordance With the amendment requ~st dated September 20, 1996, and amended by letters dated OCtober 30, and November 11, 1998. The licensee is authorized to 1'11C8ive and process source materia,, in accordance with the amendment request dated March 5, 1997. [Applicable Amendments: 1] .fL'G. 15 1997 1: 39='M ., •••••••••••••••.•••• ~:J:-~it •••• , ~ NIJCI..EAR REGULATORY COflftiiSSIOfll P!11oGe ,:; r;:,. R !IAQ!S ~~~~-~~N~~~~--~~~~~--~~~-- M.ATElUALS UCENSE -. SUPPi.EIIENTARY SHEET ~1 I A _4 <:lii:Q 4,.,..,. Auoust 15. 1997 1 0. 9 The licensee is authorized to receive and proce~~ source material from cabot Perfonnance Materials' facility near Boyerto\Nn, Pennsylvania, in accordance with the amendment request dated April3, 1997, as l!lrnended by submittals dated May 19, and August 6, 1997. [Applicable Amendments; 4] SECTION 11: Monitoring, Recording, and Bookkeeping Requirements 11.1 11.2 11.3 The results of sampling, analyses, surveys and monitoring, the reautts of calibration of equipment, reportS on audlts .. ~~.f~=tings and training courses required by this license and any su~~ews; lnv . ~ ns~;and corrective actions, srall be documented. Unle$6 Qthemise specified In the NR~~Ialions all such documentation shall be maintaine~, ~.r'-r'period of at least five (5) years.~-: .~ .. ~ :-.,~-.,:" ~ .. ct •••• The licensee s~.:finplement the effluent and environmental mO.RitOring program specified in Section S.S of tbe re"ewj!l application as revised with the followinr/P,odiffcations or additions: .. . . . . . • I , ,t I <# • • '" I .., ,. . A. stack' sainpllng shall i~du.de a detarmlnation..af'.ftow i'Bte. . ..... 1 . • • • • • I ~·' • • W\ o I I I ,I "· ,. ~ B. St.~rface water sampkt$ sttan af&~ 0e analyzed terfiiannualfy fO't,Ultal and dissolved U. nat, Ra-226, and Th-23'01 with the except]~ Qt.y,ewestwater~ek. which shall be sampled annually for Water sedlrnetrf:5' and~~ as above .. ~sediment sample shatt not be taken in place df a walE!f: s.a"TP~uhtess. a water s~ple was not available. ' '~ f• h , ~ , ... ' '• • r . •. • •. c. GroUJ1dwater ~A1P.~ng shall.h!! ~n~~·fn a~~~ requirements In Ucense Condition 1.1.3. . · 1 • •• :·· • '"""" • ~ I o • .. I I o I I : • o o. • • ~!; :' ~.-... ' I "''-•t• ');1":1 D. The licensee shalt' utilize lowe'r: Ur'nlas of det~tfln acco~ with Section 5 of Regul.tcry, Guide 4.14 (Revision 1)1 for an~ of efllu~nd environmental samples.. · , · ' .''-..., () . ~ ·, . . . ~ .. ; E. The inspection~·~ertarmed semiannually of tQ.~ ~ ~riflce assembly commtttad to in the submittal dated M~ ~,.1~ .. ~~ ~~mented. The critfcal Offfice assembly shall be calibrat.ct:at 1.-st eWiy 2 years against a posHive displacement Roots matw to obtain the reqUired calibration curve. The licensee shall implement a groundwater detection monitoring program to ensure compliance to 10 CFR Part 40, Appendix A. The detection monitoring program shall be in accordance \Wh the report entitled, "Points of Compliance, VVhite Mesa Uranium Mill," submitted by letter dated October 5, 1994, as modified by the following: A. The leak detection system for all ponds wfl1 be checked weekly. If liquid is present, it shall be analyzed for chloride, sulfate, selenium. and pH. The samples will be statlstically analyzed 1o determine if significant linear trends exist, and the results will be submittad to NRC tar re"~~iew. ---------------------~--------._~--~~ 11.4 11.5 11.6 1'«).34e P.16 vwwawwwwwwwww~ww ''*"***********·*' u.S. NUClEAR REGULATOIIIY COWIISSOflt ~ 7 OF A ~ ~u~c~-~-.~~-~~--------~------~----- MATERIALS UCENSE -,SUPPLEMI!!NTARY SHEET ~IJA-1::1..~ A-... ""'' ·- An oea .. ·-·- August 15, 1997 B. If a significant linear trend is indicated, the licensee will submit a proposed con-ective action for review and approval to NRC The corrective action shall indude a discussion on delineation of the areal extent and concentration of hazardous constituents. C. The licensee shan sample monitoring wells VVMMN-5, -11, -12, -14, -15, and -17, on a quarterly basis. Samples shall be analyzed for chloridet potassium, nickel, and uranium, and the results of such sampling shall be included with the environmental monitoring reports submitted in accordance with 1 o CFR 40.65. During extended periods of mill standby, !!.ight-hour annual sampling for U-nat, Ra-226, Th- 230 and Pb-210 may be eHmin~·ifro~A81Birbo$'1e sampling show levels below 10 percent of the appropriate 10 CFR PBrt. ~~imits. · ·~ ~! 'L ~: 1,1 1i._-> '. :;:~'!· • ••· .... • ~·:. AJ During periods of~.~. sampling frf""'"~"!cies for area a'iw;bo.cpe uranium sampling YJithi'1 the mill may be ~ to quarter1y, provided measured levels remain below 10 percent of the deriVed air ~l:entration (OAC). If these levels exceed 10 ~n:ent of the OAC, the sampling frequency should follow the recommendations in R•~laiQry Guide 8.30. ' . ) . .. ·. ) . calibration of i~lant 8ir a'~ radiation monitoring eqtif~inftm ·~hall ti6'performed as spedfied in the license renewal ap~icaiicn, unde_rSer=tfon 3;0 .~~ "Radlatfon•l?,rctectlon Procedures Manual," with-the exception thm i~lant~lir S8f11'PI~Uipment sha)l \)8 calibrated at least quarterty and air sampling eqUipment c;hecks shllllll tle'...Oo.Cumented. \:,. 1 _: 1 I 1 \. • . . , . I . C, . '•. The licensea-shall perfonn an an~ual ALA~.~~t;~ttia radtatJon S{i~ prog~m in accordance-With R~latory Guide 8~31.' ·: r ·: 1 • · · • , ..... ~ ,•J • ' o I I . · .. •'~o ,. ..... .. SECTION 12: Reporting ReqUirementS ~~ i .~· ; .• ' ... :'): '.t') 12.1 • • , t _,.- The licensee stl311-~bmit to N~C fQr.ravfew,.~ Jtin~.~o, 199J(~atafled reclamation plan for the authorized t~Uings disposal area whi~ Includes the ~l'lt:IWina: •. • .• .:># A A post-operati~~ inteom stabiriZ3tion plan which ~ils methods to prevent wind and water erosion and recnQ'tge ~.~~ill~"* 41,.'-~ ~->·~ I B. A plan to detennine the best methodology to dewater and/or c;onsolidate the tailings cells prior to placement of the final reclamation cowr. C. Plan and aoss-sectional views af a final111clamation cover which details the location and elevation of tailings. The plan shaU indude details an cover thickness, physical characteristics of cover materials, proposed testing of cover materials (specifications and quality assu111nce), the estimated volumes of cover materiaJs and their avanability and location. D. Detailed plans for placement of rock or vegetative cover on the final redaimed tamngs pile and mill site areL E. A proposed implementation schedule for items A through D above which defines the sequence of events and expected time ranges. -.._.._ ~---··---------------.------.--.._- 12.2 MATERIALS LICENSE -SUPPLEMENTARY SHEET August 15, 1997 F. An analysis to show that the proposed type and thickness of soil cover is adequate to provide attenuation of radon and is adequate to assure Jong..term stability, as well as an analysis and proposal on methodology and tfrne required to restore ground water in confonnance to regulatory requin!ments. G. The licensee shall indude a detailed cost analysis of each phase of the reclamation plan to indude contractor costs, prcjected costs of Inflation based upon the schedule proposed in item e. a proposed contingency cost. and the costs of long-term maintenance and monitoring. .. .. ·' .. '-• ... -:' ,· .... ~ ., ·. i=t,X; • 15. 1997 1 : 3:J=IM 1'().343 P.4 TECHNICAL EVALUATION REPORT REQUESTTO RECEIVE AND PROCESS ALTERNATE FEED MATERIAL DOCKET NO. 40-8681 LICENSEE: International Uranium (USA) Corporation FACILilY: \Nhite Mesa Uranium Mill PROJECT MANAGER: James Park SUMMARY AND CONCLUSIONS: LICENSE NO. SUA-1358 The U.S. Nuclear Regulatory Commission staff has reviewed Energy Fuels Nuclear, Inc.'s (EFN's) request dated Apnl s, "i997, tc receive and process uranium-bearing material currently contained at Cabot Perfonnance Materials' (CPM's) fadlity near Boyertown, Pennsylvania. The material would be processed at the White Mesa mill, of which EFN is the former owner. The current CMner of the mill and NRC licensee, International Uranium (USA) Corporation (IUC), previously has agreed to abide by all commitments and representation made _by EFN. Based en its review of the Apnl 3, 1997, submittal and additional information provided by letters dated May 6, May 19, June 20, and August 6, 1997, the NRC staff considers the amendment request acceptable. DESCRIPTION OF LICENSEE'S AMENDMENT REQUEST: By its submittal dated April 3, 1997, EFN requested that NRC Source Material Ucense SUA-1358 be amended to allow receipt and proce5Sing of alternate feed material (i.e., material ether than natural ur11nium ore) at its White Mesa uranium mill located near Blanding, Utah. This uranlum-~ring material, weighing approximately 16,000 dry tons, is held currently by CPM at its facility near Boyertown, Pennsylvania. The material i& a moist solid (up to 40 pen::ent moisture content) which contains uranium at an· average concet tb ation of 0.3 percent by welght1 and P".Onomically attractive concentrations of tantalum and niobium. CPM Is authorized to possess this material under NRC Source Material Ucense SMB-920. The material will be shipped by train and exdusive-use trucks frorr, CPM's facility to the White Mesa mill in intermodal containens. After being loaded and sealed at CPM's facility, the containers will be transported by truck to a nearby intermodal rail terminal. The containers Will be loaded on flatbed railcars and transported cross--ccuntry to the final ran destination (either Grand Junction, Colorado or Green River, Utah), where they will be transferred to trucks for the final leg of the joumey to the White Mesa mill. Each container ha& a capacity of 25 cubic yards, and it is expected that approximately 15 containers will be loaded and transported each day. At the mill site, the uranium-bearing material win be emptied from the intermodal containers into the are receiving hopper. From there. the material will be processed through the semi- autogenous grind (SAG) mill, where water will be added to aeate a sluny, which is then 1 AUG.15.1997 1:34PM I'(). 34el p. 5 pumped to-41 pulp storage tank and from there into the leach circuit. ln the leach circuit, the slurry Will be treated to separate the uranium from the tantalum and niobium, and IUC wm ublize the uranium and vanadium solvent extraction circuits, respectively, tD recover these metals. lUC plans to add two filter presses and same additional piping to its mill circuit to aid in the processing of this material. Wat6 spray systems will be utilized to reduce the potential fer dust dispersion and airborne contamination in emptying the intennodal ex~ntainers. Other than the slight circuit changes mentiOned previously, IUC anticipates that processing the uranium-bearing material will not differ from precessing natural uranium/vanadium ores. IUC will provide personal protective equipment (coveraHs, gloves, and full-face respirators (to be used if needed)) to individuals engaged in processing the material. The efficiency of airborne contamination central measures durtng the material handling operations will be assessed in the immediate vicinity cf these operations. Airborne particulate samples and breathing zane samples will be collected during initial material processing activities and analyzed for gross alpha. Sampling results will be used to establish health and safety guidelines to be implemented throughout the processing operations. Additional environmental air samples will be collected at nearby locations to the material processing activities and analyzed to ensure that the established contamination control measures are adequate and effective. Trucks used to transport the material tc the mill site wiD be radiometricaUy scanned upon arriVal to ensw. that leakage has not occurMCI and that radiation rev. are_ within appropriate limits. TruckS will again be scanned prior to their release from the site restrict$d area. In addition, the intermodal ex~ntalners used to transport the material will be proper1y closed, cleaned (if necessary), surveyed, and documented before leaving the site. TECHNICAL EVALUATION: The NRC staff has reviawad IUC's request in accordance With 10 CFR Part 40, Appendix A. requirements and NRC staff guidance '"Fmal Position and Guidance on the Use of Uranium Mill Feed Material Other Than l\!9tural Ores" (60 FR 49296; September 22, 1995). This gutdance (referred to hereinafter as the alternate feed guidance) raqulres that the staff make the following determinations in its reviews of Hcensee requests to procet58 material ather than natui'CII uranium ores. 1. Whether tfw feed material meets the definition of "ore;" 2. 'Mlether the feed material contains hazardous waste: and 3. Whether tne ere is being p~ primarily for it& source-material content. 2 ~.15.1997 1=34PM t-().340 P.6 Determination af whether the feed material js "om" Fer the tailings and wastes from the propased processing to qualify as 11 e. (2) byproduct material, the feed material must qualify as "ore." fn the alternate feed guidance, ore is defined as " ... a naturat or native matter that may be rt"ined and treated for the extraction of any of its constituents or any other matter from which source material is extracted in a licensed uranium or thorium mill." The proposed alternate feed material contains uranium at an average concentration of 0.3 percent by weight therefore, it meets the detimticn Of "source materia~" as defined at 1 o CFR 40.4. IUC I& proposing to extract this uranium. Therefore, the material meets the definition of ore, because it Is a "matter from which source material Is extracted In a licensed uranium or thorium mill. • Determination of whether tbe feed material contajns tmzardous WJ18te Under the alternate feed guidance, proposed feed material which contains a listed hazardous waste will not be approved by the NRC staff for processing at a licensed min. Feed materials which exhibit only a characteristic of hazardous waste (I.e., lgnltabillty, COJTCSivtty, reactivity, or toxicity) would not be regulated as hazardous waste and could therefore be approved by the staff for recycling and extradian of source matenal. However, this does not apply to residues from water treatment. Therefore, NRC staff acceptance of such residue& as feed material would depend on their not containing any hazardous or CharacteliStic hazardous waste. The NRC staff has reviewed the following sources of information in detennining whether the uranium-bearing material is ar contains hazardous waste: (1) the average Q)ITlpo&ition data for the material, as submitted by IUC an June 20, 1997, (2) the results of additional testing, u provided by letter dated May 6, 1997, (3) NRC files for the Boyertown facility, which address, in part, the prac:eu used to produce the material and the me1hods used to store the material, and (4) supplementary information concerning the State of Pennsylvania Department of Environmental Protection's hazardous waste regulations. In addition, as an attachment to a letter dated Augu&t 6, 1997, IUC provfded an anadaYit from CPM In which CPM affinned that the material is not and does nat contain hazardous waste. Based on tts revieW, tne NRC statr finds tttat the uranium-bearing material is nat hazardous wasta and does not coma;, hazardoUB wast.. The NRC staff has determined alaa that the uranium-beanng material is nut a rwidue from water treatment. This material is the result of the initial pi"'QQSSfng of raw ares containing tantahJm and niobium. Therefore, the NRC 8taff considers the uranium-bearing material acceptable for recycling and extraction of source materiaL 3 AUG.15.1997 1:35PM 1'().340 P.7 - Oeterroinaqpo of whether the feed material :is being proceged cdmarily foe jts soycce;naterial content ~ Ta show that potential alternate fee<1 material is being processed primarily for its source- material content, a licensee must either (1) demonstrate that the material would be approved far disposal in the tailings impoundment under the "Final Revised Guidance on Disposal Of Non· Atomic Energy Ad of 1954, Section 11e.(2) Byproduct ~aterial in Tailings Impoundments;'" or (2) certify, under oath or amnnauon, that the material is being procesaed primanly for the recovery of uranium and for no other primary purpose. Any such certification must be supported by an appropriate justification and accompanying doa.~mentation. The licensee has provided a signed affirmation that the uranium-bearing material is being precessed primarily for tf1e recovery of uraniUITI and for no other primary purpose. IUC states that the uranium content of the matern.l, In conjunction with the reduced uranium processing costs associated with 1he recovery of the tantalum and niobium, makes processing the CPM material economically attractive to IUC. The NRC starr has discussed with IUC the business arrangements regarding the material and finds that IUC is paying CPM for the acquisition of the material. The NRC staff has reviewed the analytiCal data provided by IUC and infarmation contained in the NRC's files for the CPM facility, and finda that the uraniUm concentration in the material iS comparable With thilt In nab.Jral uraniLim ores Whid1 are and were normally processed by uranium mills In the U.S.. 1l1e$e natural ores contained uranium at concentrations of 0.3 percent and betaw. Therefore, the NRC staff considers IUC's justiftcation to be acceptable. Conclusjons concerning alternate feed matedal designation Based on the information provided by the licerwee, the NRC staff ftnda that tha CPM's uranium- bearing material is alternate feed material because: (1) It meets the deftnttlon af "ore, .. (2) ft does net contain hazardous waste, and (3) it is being procassed primarily for Its source-material content Other cgnsjclenltions The NRC staff has aiBD concluded that the processing af this material wll not mutt In ('1) ~ significant change or Ina-ease In the types or amounts of eftluent:a that may be released offsite; (2) a significant increase In Individual or cumulative occupational radiation exposure; (3) a significant construction impact or (~) a significant ine~ruse In the potential for or consequences from radiological accidents. This conctusion ia based on the following infonnlltion: a. YeUowcake produced from the processing of thls materfal will not cauae the currently- approved yeRowcake production limit of 4380 tons per year ta be exceeded. In addition, and aa a result. radiological doses to members of the public In 1he Yidnity of the mill will net be elevated above levels previously assessed and approved. 4 !=tJ;. 15. 1997 1: 3SPM l'fJ.34e P.B b. lhe-physicaf changes to the miU circuit that IUC will implement to process this material are not significant No construction impacts beyond those previously assessed will be involVed with these changes. c. Tailings produced by the processing af this material wiD be disposed of an-site In an existing lined tailings impoundment (Cell 3). The adcfltion of these tailings (a malcimum of 16,000 tons) to Cell 3 will increase the totP• amount Of tailings in the cell by one percent, to a total of approximately 69 percent of cell capacity; therefore, no new impoundments are necessary. The design of the existing inpoundments previOusly has been approved by the NRC, and IUC iS required by its NRC license to condud regular manitaring of the impoundment liners and of the groundwater around the impoundments to detect leakage If it should occur. d. The uranium-bearing material contains metals and other parameters which already are present in the mill tamngs dispoeed of in the Cell 3 impoundment. Analysis of samples from the uranium-bearing material and from Cell3 show that the only.~~:~~,netars present in significantly higher concentrations in the uranium-bearing material are fluorine and carbon. Howaver, these conce11b ~ •: ....... should not have an advenle impact on the overall Cell3 tailings campositian, because the amount aftaR!!1gs (a maximum of 16,000 tons) produced by processing the material is not significant in comparison to the total amount of tailings currently In the cell (approximately 1.4 mHiion tons). Additional~. as stated previously, IUC is required tD conduct regular monitoring of the impoundment leak detection systems and of the groundwater in the viCinity of the impoundments to detect leakage if It should occur. e. For the following reasons, it is not expected that transportation impact& associated with the movement of the material by train and truck frum Pennsytvania to the White Mesa mill will be significant • The material will be shipped as "low specific activity" material in exciU&ive-u&e containers (I.e., no other materials will be in the containers with the uranium- bearing material). The containers will be appropriately labeled, placarded, and manifested, and shipments will be tracked by the shipping company from CPM's facility until they reach the VVhite Mesa mill. • On average during 1998, 370 trucks per day traveled the sb etch of State Road 191 between Monticello. UT ana Blanding., UT (personal communication with the State d Utah Department of Transportation). An additional16 trucks per day travelng this lOUie to the mHI represents an incre8sed trafliG load of only four percent Shiprnentl!l are expected to take place over the catne of a limited time period (three to SiX months). • The containers and trucks inYoiYed in transporting the material to the mnl site wm be surveyed and decontaminated, as necessary, prior to leaving CPM's facility for 'Mlita Meea and again prior to leaving the mnl site for the retum bip. 5 AUG.15.1997 1:36PM 1'().340 P.9 f. Mill-employees involved In handling the material wil be provided with personal protective equipment. including respiratory protection. AJrbome partictJiate and breathing zone sampling result& wm be used to estabfJSh health and safety guidelines to be implemented throughout the processing operations. RECOMMENDED LICENSE CHANGE: Pursuant to Title 1 0 of the Code of Federal Regulations, Part 40, Source Material Ucense SUA-1358 will be amended by the addition of License Condition No. 10.9 as fallow&: 10.9 The licensee is authorized to receive and process source material from Cabot Perfonnance Materials' facility near Boyertown, Pennsylvania. in accordance with the amendment request dated April 3, 1997, as amended by submittals dated May 19, and August 6, 1997. ENVIRONMENTAL ;;wi?ACT EVALUATION: Because IUC's receipt and processing of the 'Tl!Jtefial will not result in (1) a significant change or lncreass In the types or amounts of effluents that may be relealled offillte; (2) a significant increase In indiVidual or cumulative occupational radiation exposure; (3) a significar)\ construction imp•ct; or (4) a significant inCf8aae in the potential for or consequences from radiological accidents, an environmental review was not performed since actions meeting these criteria are categorically exduded under 10 CFR 51.22(c)(11 ). 6 Appendix B White Mesa Mill Site Maps with Well Locations 1 z ~ .~ i ~ ! ~ 'a i '~ ~ ~ :0. ,. ' TWN-15 ~ ; / MW-03 ~ I 1W4-32 1W4-13 ·TW,:4.-P'2 MW-04 t 1W4'-08 I 1W4-36 I 1W4-01 MW-32 1W4-64 1W4-14 34 I YWY5 Bureau of Land Ma Copyright:© 2013 National Geographic Socjety~bcub Legend U U Property Boundary D Structure o-r Seep or Spring Well -$-Abandoned Monitoring Well ** -$-Active Monitoring Well ** Potable Water Well D Township and Range O section ----Canyon Rim Surface Land Ownership C]Private ~ Mill Site Claim ~ Utah State Lease D Bureau of Land Management D Blanding Municipal Boundary D Utah Land Trust School Section D Ute Mountain Ute Pond ----Drainage ** Monitoring well depths are listed in Tables 1.2-1, 1.2-2, and 2.4-1 Coordinate System: NAD 1983 StatePiane Utah South FIPS 4303 Feet N 2,000 1 IN= 1,500 FT 1,000 0 ! 2,000 Date: By: County: San Juan State: Utah Location: PORTIONS OF T37S R22E APPENDIX 8-1 WHITE MESA MILL (NORTH) ! t ~ ~ ~--------------------------------------------------------------------------------------------------------------------------------------_l __ _l_j~A~u~~o~~m~h~e~nin~g~ron~:2D~~~e!6/~V~20~14~==~D~~oo~By~m~h!en:in!~~on~ -o X E ~ ~ d .. ::;; a. ~ (I) c ;. 0 1:! ~ Q_ 5 § (I) "-Q) ~ &\ ~ S! g> ·a. a. .. :.;; :::; --' ~ ~ 5 ~ r COTTONWOOQ I • MW-03 ~ -'1 " .f IN-5 ~lNG' '10 Copyright:© 2013 National Geographic Society, i-cubed Legend II II Property Boundary 0 Structure Ov-Seep or Spring Well -$-Abandoned Monitoring Well** -$-Active Monitoring Well** Potable Water Well C) Township and Range L__=-_] Section ------Canyon Rim Surface Land Ownership C) Private ~ Mill Site Claim ~ Utah State Lease D Bureau of Land Management D Blanding Municipal Boundary D Utah Land Trust School Section D Ute Mountain Ute Pond Drainage ** Monitoring well depths are listed in Tables 1.2-1, 1.2-2, and 2.4-1 Coordinate System: NAD 1983 StatePiane Utah South FIPS ~3~~ N 1 IN = 1 '500 FT I 1,000 0~=~~~~2~,000 SCALE IN FEET 2,000 WHITE MESA MILL Dme: By: County: San Juan State: Utah Location: PORTIONS OF T37S R22E APPENDIX B-2 WHITE MESA MILL (SOUTH) ;2 ~ ~---------------------------------------------------------------------------------------------------------------------------------------L--_.~~A~ut~ho~r.m~h~en-in~gt~on--~D~m~e~6/~~2~0-14----~Drn~ftoo~-~By~m~h~en~in~gt~on~ Appendix C Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill, Revision: 1, June 10, 2011. White Mesa Uranium Mill SAMPLING AND ANALYSIS PLAN FOR SEEPS AND SPRINGS State of Utah Groundwater Discharge Permit No. UGW370004 Prepared by: Denison Mines (USA) Corp. Suite 950, 1050 17th Street Denver CO 80265 June 10, 2011 Table of Contents 1.0 Introduction and Objectives .................................................................................................................... 3 2.0 Seeps and Springs Sampling locations .................................................................................................... 3 2.1 Timing of Sample Collection ................................................................................................................ 3 3.0 Field and Sampling Procedures ............................................................................................................... 4 3.1 Field Data ............................................................................................................................................. 5 3.2 Decontamination ................................................................................................................................. 5 3.3 Field QC ............................................................................................................................................... 5 3.4 Sample Handling .................................................................................................................................. 6 4.0 QA and Data Evaluation .......................................................................................................................... 6 5.0 laboratory Analysis ................................................................................................................................. 6 5.1 Analytical Quality Control. ............................................................................................................. 6 5.2 Evaluation of Analytical Data-.............................................................................................................. 7 6.0 Reporting ........................................................................................................................................... 7 1.0 Introduction and Objectives This Sampling and Analysis Plan ("SAP") describes the procedures for sampling seeps and springs in the vicinity of the Denison Mines (USA) Corp. ("Denison") White Mesa Uranium Mill ("the Mill") in Blanding, Utah as required by the State of Utah Groundwater Discharge Permit ("GWDP") No. UGW370004. The objective of the seeps and springs sampling program is to collect annual surface water samples from the locations identified below as required by the GWDP. This SAP specifies the sample collection requirements, procedures, analytical methodologies and associated quality control ("QC") checks, sample handling protocols and reporting requirements for the annual seeps and springs sampling program. 2.0 Seeps and Springs Sampling Locations The annual seeps and springs sampling locations correspond with those seeps and springs sampled for the initial site characterization performed for the Environmental Assessment as shown on Plate 2.6-10 of the Environmental Report (Dames & Moore, 1978), and additional sites located by Denison, the BLM and Ute Mountain Tribal representatives. The locations included in the annual seeps and springs sampling event are: • Cottonwood Seep • Westwater Seep • Ruin Spring • Corral Canyon Seep • Entrance Spring • Corral Springs The Permit Section I.F.7 (g) requires that survey data for the seeps and springs be submitted prior to the collection of samples. UDEQ previously clarified the requirement to submit survey data only prior to the first sampling and not on an annual basis. The survey data submitted with the first annual seeps and springs report in 2009 was incorrect. In response to the incorrect data, DUSA completed another survey of the seeps and springs in December 2009. Those survey data are included in Table 1 of this SAP and the locations are shown on Figure 1 included in Tab A. The surveyed coordinates and elevations of the seeps and springs were within 1 foot of the highest point of the saturated seepage face on the day of the survey 2.1 Timing of Sample Collection Seeps and spring sampling will be conducted on an annual basis and will be scheduled between May 1 and July 15 of each year. This sampling period is aimed at maximizing the opportunity for flow but excludes the potential for surface water influence occasioned by late summer "monsoon" conditions. For each annual sampling period, the locations noted above will be visited a minimum of three times in order to attempt collection of a sample. Should a visit reveal a change in conditions at any of these dry locations which may yield water sampling opportunities, Denison will proceed with limited hand tool excavation of the sampling location. The hand-dug excavation will be left open for a maximum of 48 hours and allowed to fill with water. If water collects in the excavation, it will be sampled. If the location is excavated with hand tools, it will be filled after sampling has been completed, with the soil that was removed from it per the Bureau of Land Management (BLM) request included in Tab C. Should three annual visits at seeps and springs locations reveal only dry conditions, and a continued absence of physical development opportunities, a sample will not be collected and such conditions (and the inability to sample) will be recorded on the field data sheet and reported along with the results of collected samples for that annual sampling event. Denison will provide at least 15 days notice of sampling in order to allow the Executive Secretary to collect split water quality samples of the seeps and springs. 3.0 Field Sampling Procedures The field sampling and data collection program will obtain samples to be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP. Analyses will be completed by a State of Utah certified laboratory using the methods specified in the currently approved Denison Quality Assurance Plan for Groundwater sampling ("QAP"). Minimum detection limits or reporting limits for seeps and springs analyses will be less than or equal to the Groundwater Quality Standards defined in Table 2 of the GWDP. The minimum detection limits for total dissolved solids ("TDS"), sulfate, and chloride will be 10 mg/L, 1 mg/L, and 1 mg/L respectively. Field activities include collecting samples, recording of field data and field parameters, and preparing and shipping samples to the analytical laboratory. Sampling procedures employed at each location will be dependent on the site location and access. Several sampling methodologies may be employed during one annual event based on access limitations and flow rates of the seeps and springs that are sampled. Potential sampling methodologies are briefly described below. Direct Collection Direct collection of the samples involves collecting the sample directly into the sample container from the surface water feature or from spring out-flow. In instances where direct collection is employed the parameters which require filtration will be collected by one of two methods. In the first method the peristaltic pump will be used to draw the sample from the out-flow and pump it through a 0.45 micron filter directly into the appropriate sample container. The second method is used in situations with limited access for the generator required to run the peristaltic pump. When the generator cannot be used, a large, unused sample jug will be used to collect the sample. The peristaltic pump will then be used to transfer the sample from the large sample jug to the sample bottles through a 0.45 micron filter. This filtration and pumping will be completed at a location where there is access for the generator. Peristaltic Pump Sample collection with a peristaltic pump involves collecting the sample from the source or out-flow using the peristaltic pump. The peristaltic pump is used to deliver the sample from the source or out-flow to the sample bottles. Filtered parameters are pumped through a 0.45 micron filter prior to delivery to the sample bottle. Sample Ladle Sample collection using a ladle involves dipping or filling a ladle made from an inert material into the surface water source or out-flow and filling the ladle. The sample is transferred from the ladle to the sample bottles. This process is repeated until the sample bottles are filled. Filtered parameters are collected into a large, unused sample jug. The peristaltic pump is then used to transfer the sample from the large sample jug to the sample bottles through a 0.45 micron filter. 3.1 Field Data In addition to the analytical parameters noted above, field data will be recorded at the time of sample collection. Field parameters required by the GWDP include pH, specific conductance and temperature. Additional field parameters such as oxidation reduction potential (REDOX) and turbidity may be measured as available sample volume allows. Field data will be recorded on the Field Data Record included in Tab B of this SAP. As previously noted, the dates of the site visits, the availability of surface water for sampling, and the possibility for development will be recorded on the field data sheets for inclusion in the annual report. 3.2 Decontamination Decontamination of sampling equipment will be completed if non-dedicated and/or non-disposable sampling equipment is used to collect samples. Decontamination procedures will be as described in the approved QAP. Rinsate blanks will be collected daily after decontamination of sampling equipment. If disposable or dedicated sampling equipment is used to collect samples then rinsate blanks will not be collected. 3.3 Field QC The field QC samples generated during the annual seeps and springs sampling event will include sample duplicates, trip blanks, and rinsate blank samples as appropriate. Sample Duplicates Sample duplicates will be collected at a frequency of one duplicate per 20 field samples. Sample duplicates will be collected by filling the sample container for a certain analytical parameter for the duplicate immediately following the collection of the parent sample for that parameter. Trip Blanks Trip blank samples will be included in every shipment of samples that has field samples to be analyzed for Volatile Organic Compounds ("VOCs"). Trip blank samples are VOC sample containers filled by the analytical laboratory with laboratory grade deionized water and shipped to the site. Trip blank samples are taken into the field with the sample containers, never opened, and kept with the field samples from collection through shipment to the analytical laboratory for analysis. Trip blanks are analyzed to determine if the sample concentration of VOCs have been effected by the "trip" from collection through shipment. Rinsate Blank Samples Rinsate blank samples are collected at a frequency of one per day when non-disposable, non-dedicated, reusable sampling equipment is used to collect samples. If the sampling equipment has a disposable component that comes in contact with the samples and the component is changed prior to sampling at each location then a rinsate blank sample will not be collected. For example, if a peristaltic pump is used to collect and filter seeps and springs samples and the tubing used in the peristaltic is changed at each location and never reused for more than one sample, no rinsate blank sample would be required. 3.4 Sample Handling Seeps and springs sampling events will be subject to the applicable sample handling requirements noted in the approved White Mesa Mill Groundwater Quality Assurance Plan ("QAP"), Revision 6, dated March 22, 2010. 4.0 QA and Data Evaluation The Permit requires that the annual seeps and springs sampling program be conducted in compliance with the requirements specified in the Mill's approved QAP, the approved SAP and the Permit itself. To meet this requirement, the data validation for the seeps and springs sampling program will utilize the requirements outlined in the QAP, the Permit and the approved SAP as applicable. The Mill QA Manager will perform a QA/QC review to confirm compliance of the monitoring program with requirements of the Permit, QAP and SAP. As required in the QAP, data QA includes preparation and analysis of field QC samples, review of field procedures, an analyte completeness review, and quality control review of laboratory data methods and data. The QAP and the Permit identify the data validation steps and data quality control checks required for the seeps and springs monitoring program. Consistent with these requirements, the Mill QA Manager will performed the following evaluations: a field data QA/QC evaluation, a receipt temperature check, a holding time check, an analytical method check, a reporting limit check, a trip blank check, a QA/QC evaluation of sample duplicates, a gross alpha counting error evaluation and a review of each laboratory's reported QA/QC information. The corrective action procedures described in the approved QAP will be followed as necessary when data validation and QC reviews indicate a non-compliant situation. 5.0 Laboratory Analysis Samples will be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP using the analytical methods and specified reporting limits contained in the approved QAP. Laboratories used for the seeps and springs sampling program will be Utah certified as required by the GWDP Part l.E.6 (c). Laboratory data will be validated as described in the approved QAP and as described in Section 4.0 above. Analytical QC is described below. 5.1 Analytical Quality Control Analytical QC samples and protocols are described in the approved QAP. Laboratory QC procedures will meet, at a minimum, the requirements set forth in the analytical methods that the laboratory is certified for by the State of Utah. The analytical QC samples included at least the following: a method blank, a laboratory control spike ("LCS"), a matrix spike ("MS") and a matrix spike duplicate ("MSD"), or the equivalent, where applicable. It should be noted that: • Laboratory fortified blanks are equivalent to LCSs. • Laboratory reagent blanks are equivalent to method blanks. • Post digestion spikes are equivalent to MSs. • Post digestion spike duplicates are equivalent to MSDs. • For method E900.1, used to determine gross alpha, a sample duplicate was used instead of a MSD. All qualifiers, and the corresponding explanations reported in the QA/QC Summary Reports for any of the analytical QC samples for any of the analytical methods will be reviewed by the Mill QA Manager. The effect on data usability will be discussed in the evaluation section of the annual report. 5.2 Evaluation of Analytical Data An evaluation of the analytical data will be completed in the annual report. A discussion of the results will be included which will summarize the data relative to any detections reported in the samples with comparisons as appropriate to the Mill groundwater quality data. 6.0 Reporting DUSA will collect seeps and springs samples annually as required by the GWDP Part l.F.7. Each report will: 1) document the sampling event by means of providing the field sheets recorded at the time of sampling; 2) transmit copies of all field measurements and laboratory results; 3) provide a water table contour map that includes water table elevation of all groundwater monitoring wells at the facility and the elevations of the phreatic surfaces observed at each of the seeps and springs sampled; and 4) provide an evaluation and interpretation of the groundwater quality data collected. Specific reporting requirements for the seeps and springs sampling program will include but are not limited to: • The annual seeps and springs monitoring report will be included with the 3'd quarter Routine Groundwater Monitoring Report due on December 1, of each year. • The seeps and springs water table contour map will include all water level data measurements from all monitoring wells at the site from the 3'ct quarter groundwater monitoring event for each year. • The seeps and springs water table contour map shall be at the map scale such that all seeps and springs listed in this Plan and monitor wells at the site may be seen on one map. Table 1 s L eeps an dS . S I~ f iprmgs urvey n orma 100 December 2009 Survey Location Latitude (N) Longitude (W) Elevation FROG POND 37°33'03.5358" 109°29'04.9552" 5589.56 CORRAL CANYON 37°33'07.1392" 109°29'12.3907" 5623.97 ENTRANCE SPRING 37°32'01 .6487" 109°29'33.7005" 5559.71 CORRAL SPRINGS 37°29'37.9192" 109°29'35.8201" 5383.35 RUIN SPRING 37°30'06.0448" 109°31'23.4300" 5380.03 COTTONWOOD 37°31'21.7002" 109°32'14.7923" 5234.33 WESTWATER 37°31'58.5020" 1 09°31'25. 7345" 5468.23 Verification Survey July 2010 RUIN SPRING 37°30'06.0456" 109°31'23.4181" 5380.01 COTTONWOOD 37°31'21.6987" 109°32'14.7927" 5234.27 WESTWATER 37°31'58.5013" 109°31'25.7357" 5468.32 Attachment A I'' I Field Data Record-Seeps and Springs Sampling Seep or Spring Location: ---------------------- Date For Initial Sampling Visit: ________ Time: _________ _ Sample Collected: o Yes o No Date For Second Sampling Visit: ________ Time: _________ _ Sample Collected: o Yes o No Date For Third Sampling Visit: ________ Time: _________ _ Sample Collected: o Yes o No Sampling Personnel: Weather Conditions at Time of Sampling: ________________ _ Estimated Seep or Spring Flow Rate: ------------------ Field Parameter Measurements: -pH -Temperature (°C) --------------~ -Conductivity !!MHOC/cm ------------ -Turbidity (NTU) (if measured). __________ _ -Redox Potential Eh (m V) (if measured) ______ _ Analytical Parameters/Sample Collection Method: Par~ter Sample Taken Fifter~ = S.ampling, Method Direc~ ,JYe-ri tattle Lad~ 11, l-ump VOCs o Yes oNo o Yes oNo 0 0 0 THF o Yes oNo o Yes oNo 0 0 0 Nutrients o Yes oNo o Yes oNo 0 D 0 Other Non o Yes oNo o Yes oNo 0 0 0 Radiologies Gross Alpha o Yes oNo o Yes oNo 0 D D QC Samples Associated with this Location: o Rinsate Blank o Duplicate Duplicate Sample Name: ___________ _ (t)ther Cd critie in no~s,sectio~"l 0 0 0 0 0 Notes: ______________________________ _ Appendix D Results of Soil Analysis at Mill Site { \..._ --·-·-~ Results Of Soil Analyses At Mill Site a ';:! -e~ l Jlf I'! ~-~~ •iJ~ .!! t-a '"il,-. !'"' .... '!l ...... ~! i1 fll,Q .J. :a--~ ~t ,:..; .§ ~ r=.~ ~ a ~£ !!•0 >O"'"""' .... o.l'-' .... ...... Ea .... Fo <~ f..:! ......... J1-~ ~ ..... Q.o .. ,t ~ Bllillding 4 0-4 SiL 7.6 36.0 7.4 7.9 0.3 .15 1.2 1.1 .63 15 (Bnd) Ustollic 4-12 SiCL 8.7 49.0 7.6 8.0 0.3 0.14 0.8 0.2 0.53 3 Hep!llrgid Pinc·silty, 18-40 SiCL 8.0 43.7 8.0 8.5 2.0 0.30 0.7 0,6 0.42 3 mixeil 9 0-5 SiL 8.9 38.7 7.6 8.1 0.3 0.17 0.9 1.8 0.53 10 5-12 SIL 9.3 45.6 8.0 8.4 0.3 0.18 0.9 1.4 0.47 2 18-40 SiL 8.0 38.7 8.5 9.0 3.8 0.18 1.2 11.5 0.37 2 40-50 SiCL 9.0 38,9 8.8 9.2 1.6 0.18 1.0 12.5 0.26 1 Source: Adapted from 1978 ER Table 2.10-2.2 SiCL = $ilty clay loam: SiL = slit loam . ~ ... -~,.,_ • ._..___ •••-• <o l o -•. , a ' ( •• .• - ~---~ ]a c:.lg ti~ ~~ i Q.o 198 12.8 170 16.6 165 14.9 182 13.1 138 10.9 123 11.9 .. 161 15.9 ·~~ o=•: :\~.':1"'~, •. \Ll' • \v • • \o\'oo'fll·• Appendix E Tables: Chemical and Radiological Characteristics of Tailings Solutions, Leak Detection Systems and Slimes Drains Celli Ch emtca I d R d' I I Ch an a 10 og1ca t . f arac ens tcs ~-~ Constituent 1987 2003 2007 2008 2009 2010 2011 2012 2013 2013 (Avg) (Avg) _ _(resample} , Major Ions Crtagll_l Carbonate <5 <1 ND ND <1 <1 <1 <1 <1 NS Bicarbonate <5 NA ND ND <1 <1 <1 <1 <1 NS Calcium 630 307 483.8 604 635 711 577 426 768 NS Chloride 8000 6728 37340 9830 20700 7440 33800 78000 9900 NS Fluoride <100 3005 31.72 0.3 0.4 28.4 69.2 62.9 4130 NS Magnesium 7900 5988 21220 6550 16200 5410 14300 16000 4470 NS Nitrogcn-Ammonla 7800 3353 10628 5250 15200 8120 12900 9750 3900 NS Nitrogen-Nitrate <100 41.8 269.4 64.9 142 58 212 556 128 NS Potassium NA 647 5698 1880 4140 1840 4510 9750 6580 NS Sodium 10000 8638 62600 13200 39000 16700 29500 41700 15900 NS Sulfate 190000 63667 287600 118000 232000 107000 182000 158000 100000 NS pH (s.u.) 0.70 1.88 0.80 1.53 1.15 2.73 2.23 1.9 2.74 NS TDS 120000 94700 357400 131000 140000 130000 216000 342000 149000 NS Conductivily:(umhos/cm) NA NA NA NA 365000 110000 112000 136000 94200 NS Metals '(ugfl} = -Arsenic 440000 121267 849000 271000 436000 74400 299000 25500 9800 NS Beryllium 780 475 2262 500 410 338 1270 3180 415 NS Cadmium 6600 3990 29320 8790 9120 2940 13700 30700 2380 NS Chromium 13000 6365 29940 6760 18700 5620 22700 12100 8350 NS Cobalt 120000 NA 88240 23500 97500 16200 56000 53100 25500 NS Ca1mer 740000 196667 881000 360000 168000 125000 483000 885000 544000 NS Iron 3400000 2820000 13480000 3280000 2390000 3400000 8940000 840000 1420000 NS Lead <20000 3393 27420 11200 10600 9240 23600 17000 2810 NS Manganese 140000 162500 990200 206000 723000 173000 735000 1560000 188000 NS Mercury NA NA ND ND 7.61 7.2 61.4 117 6.16 NS Molji_bdenum 240000 50550 415600 106000 142000 35300 235000 434000 16800 NS Nickel 370000 36950 40860 32000 156000 27500 43700 15000 39100 NS Selenium <20000 1862 15420 13000 14800 5220 11600 8090 2690 NS Silver <5000 NA 1559.2 449 558 155 1110 4310 329 NS Thallium 45000 NA 407.8 165 387 193 560 13 63.3 NS Tin <5000 NA 6512 1240 2290 263 1500 <100 <100 NS Uranium 105000 134517 788600 416000 578000 159000 838000 1450000 140000 NS Vanadium 280000 348000 2208200 1200000 773000 752000 2500000 1940000 98200 NS Zinc 1300000 NA 642940 476000 229000 171000 398000 811000 228000 NS .Ra'ili.oiQgic~.(pCUl)_ ' -- Gross Alpha NA 1693331 29380 21900 16500 11300 3610 12600 32700 NS VO~(uWL) Acetone 35 NA 66.5 110 710 260 80 310 41.1 NS Benzene <5 NA ND ND <1 <1 <1 <I <I NS Carbon tetrachloride <5 NA ND ND <1 <1 <1 <I <1 NS Chloroform 8 NA ' 6.7 6.6 16 4.9 13 19 7.62 NS Chloromethane NA NA ND 9.4 11 4.4 3.6 4.0 5 NS MEK NA NA ND ND 120 65 <1 200 <20 NS Mclllylene Chloride 11 NA ND ND 2.0 <1 <1 2 <1 NS Naphthalene <10000 NA <10 ND 1.1 5.4 2 3 <1 NS Tctrahydrofuran NA NA ISO <20 <100 <10 <500 2.9 <1 NS Toluene <5 NA ND ND <1 <1 <1 <1 <1 NS Xylene.~ <5 NA ND ND <1 <1 <1 <1 <1 NS SVO~(ilalLl. -= 1.2.4-Trichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 1,2-Dichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 1,3-Dichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 1.4-Dichlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 1-Methylnaphthalene NA NA NA NA <50 <10 <10 <10 <10.8 <10 2.4,5-Trichlorophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 2,4,'6-Trichlorophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 2.4-Dichlorophenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 2,4-Dinwthylphenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 2,4-Dinitrophenol NA NA NA NA <250 <20 <20 <20 <21.6 <20 2.4'-Dinirrotol.uer1e NA NA NA NA <50 <10 <10 <10 <10.8 <10 Celli Ch em1ca an a 10 og1c I d.R d. I al Ch t arac enshcs · opl!tllu _n I 1987 2003 2007 2008 2009 2010 2()11 2012 ,, 2013 2013 (Avg) (Avg) 1, .• lregampl e.r__ Mn,lor lu.ns (nWl) F" 2.6-Dinitrotoluene NA NA NA NA <50 <10 <10 <10 <10.8 <10 2-Chloron~hthalene NA NA NA NA <50 <10 <10 <10 <10.8 <10 2-Chforopheno'J NA NA NA NA <50 <10 <10 <10 <10.8 <10 2d\1cthylnaphthaleoe. NA NA NA NA <50 <10 <10 <10 <10.8 <10 2-M!!lhy!pheno1 NA NA NA NA <50 <10 <10 <10 <10.8 <10 2-Niwmbenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 3&4-Methylphenol NA NA NA NA <22 <10 <10 <10 <10.8 <10 3.3'-Dichlorobenzidine NA NA NA NA <100 <10 <10 <10 <10.8 <10 4,6-Dinitro-2-methylphenol NA NA NA NA <250 <10 <10 <10 <10.8 <10 4-BromophcnylphcnyJ ether NA NA NA NA <50 <10 <10 <10 <10.8 <10 4-Chloto-3·1Ilclhylpl'tenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 4-Chloropllenyl phenyl ether NA NA NA NA <50 <10 <10 <10 <10.8 <10 4-Nitrophenol NA NA NA NA <250 <10 <10 <10 <10.8 <10 Ac¢naphthene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Acenaphtltylcm: NA NA NA NA <50 <10 <10 <10 <10.8 <10 Anthracene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Azobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Bonz(a)anihracene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Benzidine NA NA NA NA <100 <10 <10 <10 <10.8 <10 Benzo(~)pyrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Benzo(b)fluorant.hene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Henzo(g.h,i)_pervlene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Benzo(k)fl.uornnthene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Bi~(2-chloroethoxy)methane NA NA NA NA <50 <10 <10 <10 <10.8 <10 TIUi{2-chlomcLhyl), ether NA NA NA NA <50 <10 <10 <10 <10.8 <10 Bis(2-chJoroisopropyl) ether NA NA NA NA <50 <10 <10 <10 <10.8 <10 BisC2-etbylhcxyl) pluhalate NA NA NA NA <50 27 <10 <10 <10.8 <10 But:Yt benzyl phllialate NA NA NA NA <50 <10 <10 <10 <10.8 <10 Chrysenc NA NA NA NA <50 <10 <10 <10 <10.8 <10 Dibenz(a.h)anlhraccne NA NA NA NA <50 <10 <10 <10 <10.8 <10 Die.UI yl J]hthilJate NA NA NA NA 170 <10 <10 <10 <10.8 <10 Dimetl1yl pbthalnte NA NA NA NA <50 <10 <10 <10 <10.8 <10 DI-n-butyl phthala1e NA NA NA NA <50 <10 <10 <10 <10.8 <10 Di-o-octyl phthalate NA NA NA NA <50 <10 <10 <10 <10.8 <10 Fluoranthene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Fluorene NA NA NA NA <50 <10 <10 <10 <10.8 <10 lfexachlorobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 lfexachlorobutadiene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Hex~chlorocvclopentudiene NA NA NA NA <50 <10 <10 <10 <10.8 <10 lfexachloroethane NA NA NA NA <50 <10 <10 <10 <10.8 <10 I ntlenQ(l,2,3-cd)pyrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 lso~h()rone NA NA NA NA <50 <10 <10 <10 <10.8 <10 Naphthalene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Nitrobenzene NA NA NA NA <50 <10 <10 <10 <10.8 <10 N-NitrosodimatbyJami ne NA NA NA NA <50 <10 <10 <10 <10.8 <10 N-Ni!rosodi-n-propylamine NA NA NA NA <50 <10 <10 <10 <10.8 <10 N.:Niti'osodfph~nylamine NA NA NA NA <50 <10 <10 <10 <10.8 <10 Pentachlorophenol NA NA NA NA <250 <10 <10 <10 <10.8 <10 Phenanthrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Phenol NA NA NA NA <50 <10 <10 <10 <10.8 <10 Pyrene NA NA NA NA <50 <10 <10 <10 <10.8 <10 Pyridine NA NA NA NA <50 <10 <10 <10 <10.8 <10 r Historic values reported for Gross Alpha from 1987 and 2003 are total gross alpha reported in pCi!L. All other gross alpha data are reported as Gross Alpha minus Rn & U. Ch ennca ' ~ Miffor'lons (mg/l) Carbonate Bicarbonate Calcium Chloride Fluoride Magnesium Nitrogen-Ammonia Nitrogen-Nitrate Potassium Sodium Sulfate pH (s.u.) TDS Conductivity (umhos/cm) M~t1ils (U.W)} Arsenic Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Mercury Molybdenum Nickel Selenium Silver Thallium Tin Uranium Vanadium Zinc Radiologies (pCi/1) Gross Alpha VOCS(uJV'L) Acetone Benzene Carbon tetrachloride Chloroform Chi oromethane MEK MetJ1y!ene. Chloride Naphthalene Tetrahydrofuran Toluene XvJenes SVOCS (ugfL) 1 ,2,4-Trichlorobenzene 1 ,2-Dichlorobenzene 1 ,3-Dichlorobenzene 1 A-Dichlorobenzene 1-Methylnaphthalene 2.4.5-Trichlorophenol 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene an a 10 ogaca aractensbcs Cell 2 Slimes Drain d R d' I I Ch 2007 2008 I 2009 201,'0 ND ND <1 <1 ND ND <1 <1 572 528 508 496 3700 3860 2750 3510 3.3 ND <0.1 2.4 4100 4030 3750 3790 4020 3620 3240 3820 30.9 20.3 38 126 636 560 689 620 4050 4600 4410 4770 60600 74000 72200 63700 3.18 3.24 3.11 3.39 84300 74600 84100 79900 NA NA 88700 60200 - 26900 19300 14200 23500 298 245 271 267 5500 5840 5510 6370 2750 2450 2230 2510 46500 43800 38700 48200 106000 154000 170000 148000 2770000 3310000 3230000 2720000 566 528 403 586 117000 130000 160000 144000 ND ND <0.5 <4 4080 3190 2240 4630 123000 122000 108000 126000 422 647 726 844 ND ND <10 <10 361 703 368 470 ND ND <100 <100 23000 29200 29900 30600 409000 463000 536000 469000 767000 750000 582000 652000 1290 1570 1580 1000 550 410 570 460 ND ND <1 <1 ND ND <1 <1 20 17 16 15 1.8 ND 2.2 2.3 65 ND 100 83 ND ND <1 <1 14 7.5 16 17 15 NA <100 <10 1.7 ND 2.6 2.6 1.5 ND <1 2.2 NA NA <11 <10 NA NA <11 <10 NA NA <11 <10 NA NA <11 <10 NA NA <U <10 NA NA <11 <10 NA NA <11 <10 NA NA <11 <10 NA NA <51 <20 NA NA <11 <10 NA NA <11 <10 2011 20f2 2013 <1 <1 <l <1 <1 <1 474 462 465 3110 3730 3270 2.1 1.32 161 3640 3760 3320 2940 3540 1880 38 27 47.2 636 611 622 4590 4380 3980 64200 58300 83700 3.18 3.0 3.02 80200 83800 92200 51400 52900 51100 = 17800 19400 21000 231 251 262 5580 5290 5780 2380 2350 2290 42500 48700 44900 132000 138000 137000 2960000 2850000 2810000 501 619 515 123000 141000 122000 11.1 1.9 <0.5 3510 3610 3650 111000 125000 108000 714 711 678 <10 <10 <10 371 338 278 <100 <100 <100 27100 33400 22800 454000 475000 452000 574000 639000 631000 1230 1370 2270 (2400)* = ~ 690 600 384 <1 <1 <1 <1 <1 <1 20 16 21.4 2 3 2.04 130 100 95.5 <1 <1 <1 13 12 16.8 <10 3.2 3.98 3 2 3.23 <1 2 5.97 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <20 <10 <LO <10 <20 <20 <10 <10 <10 Cell 2 Slimes Drain Ch em1ca an d R di I I Ch a Ologlca t . f arac ens Ics 1\fu.ior lons-(nu((l) 2007 2008 2009 2010 2011 2012 2013 i 2,6-Dinitrotoluene NA NA <11 <10 <10 <10 <10 2-Chloronaphthalene NA NA <11 <10 <10 <10 <10 2-Chlorophenol NA NA <11 <10 <10 <10 <10 2-Methylnaphthalene NA NA <11 <10 <10 <10 <10 2-Methylphenol NA NA <11 <10 <10 <10 <10 2-Nitrophenol NA NA <11 <10 <10 <10 <10 3&4-Methylphenol NA NA <21 <10 <10 <10 <10 I 3,3 '-Dichlorobenzidine NA NA <51 <10 <10 <10 <10 4,6-Dinitro-2-methylphenol NA NA <11 <10 <10 <10 <10 4-Bromop_henyl phenyl ether NA NA <11 <10 <10 <10 <10 4-Chloro-3-methyl phenol NA NA <11 <10 <10 <10 <10 4-Chlorophenyl phenyl ether NA NA <51 <10 <10 <10 <10 4-Nitrophenol NA NA <11 <10 <10 <10 <10 Acenaphthene NA NA <11 <10 <10 <10 <10 Acenaphthylene NA NA <11 <10 <10 <10 <10 Anthracene NA NA <11 <10 <10 <10 <10 Azobenzene NA NA <11 <10 <10 <10 <10 Benz(a)anthracene NA NA <21 <10 <10 <10 <10 Benzidine NA NA <11 <10 <10 <10 <10 Benzo(a)pyrcne NA NA <11 <10 <10 <10 <10 Benzo(b )fluoranthene NA NA <11 <10 <10 <10 <10 Benzo(g,h,i)pery1ene NA NA <11 <10 <10 <10 <10 Benzo(k)fluoranthene NA NA <11 <10 <10 <10 <10 Bis(2-chloroethoxy)methane NA NA <11 <10 <10 <10 <10 Bis(2-ch1oroethyl) ether NA NA <11 <10 <10 <10 <10 Bis(2-chloroisopropyl) ether NA NA <11 <10 <10 <10 <10 Bis(2-ethylhexvl) phthalate NA NA <11 <10 <10 <10 <10 Butyl benzyl phthalate NA NA <11 <10 <10 <10 <10 Chrysene NA NA <11 <10 <10 <10 <10 Dibenz( a,h )anthracene NA NA <11 <10 <10 <10 <10 Diethy1 phthalate NA NA <11 <10 <10 <10 <10 Dimetqyl Qhthalate NA NA <11 <10 <10 <10 <10 Di-n-butyl phthalate NA NA <11 <10 <10 <10 <10 Di-n-octyl phthalate NA NA <11 <10 <10 <10 <10 F!uoranthene NA NA <11 <10 <10 <10 <10 Fluorene NA NA <11 <10 <10 <10 <10 Hexachlorobenzene NA NA <11 <10 <10 <10 <10 Hexachlorobutadiene NA NA <11 <10 <10 <10 <10 Hexachlorocyclopentadiene NA NA <11 <10 <10 <10 <10 Hexachloroethane NA NA <11 <10 <10 <10 <10 lndeno(l ,2,3-cd)pyrene NA NA <11 <10 <10 <10 <10 Isophorone NA NA <11 <10 <10 <10 <10 Naphthalene NA NA <11 <10 <10 <10 <10 Nitrobenzene NA NA <11 <10 <10 <10 <10 N-Nitrosodimethylamine NA NA <11 <10 <10 <10 <10 N-Nitrosodi-n-propylamine NA NA <11 <10 <10 <10 <10 N-Nitrosodiphenylamine NA NA <51 <10 <10 <10 <10 Pentachlorophenol NA NA <11 <10 <10 <10 <10 Phenanthrene NA NA <11 <10 <10 <10 <10 Phenol NA NA <11 10.7 <10 <10 <10 Pvrene NA NA <11 <10 <10 <10 <10 Pyridine NA NA <11 <10 <10 <10 <10 .. *Sample was reanalyzed due to comparab1hty w1th the duphcate sample. The reanalysis data are m (parenthesis). Cell2 LDS Ch enuca an a 10 OgtCa d R d. I I Ch t . t' arac ens 1cs Gon's'tituent 2009 ".20111.""' 2011 2012 2013 .MO:ior Ions (niWI) Carbonate <1 <1 Not Sampled Not Sampled Not Sampled Bicarbonate 168 324 Calcium 711 615 Chloride 1750 1360 Fluoride 0.4 0.4 Magnesium 596 454 Nitto"en-Ammonia 32.6 0.7 Nitrog_en-Nltratc 2.8 2.2 Potassium 22 13.0 Sodium 412 318 Sulfate 2700 1780 _IJ_H (s.u.) 6.60 7.36 TDS 6750 5310 Conductivity (wnhos/cm) 11000 6500 Metals "(l!Wll ~ ... Arsenic <5 <5 Not Sampled Not Sampled Not Sampled Beryllium <0.50 <0.50 Cadmium 33.4 1.10 Chromium <25 <25 Cobalt 314 <10 Copper 59 12 Iron 208 37 Lead <1.0 <1.0 I Man~nes~ 1810 395 Mercury <0.50 0.52 Molybdenum 21 13 Nickel 948 <20 Selenium 7.9 9.4 Silver <10 <10 Thallium 0.92 <0.50 Tin <100 <100 Uranium 83.8 79.6 Vanadium 22 <15 Zinc 4220 78 Radiol~iics· (pCiliJ '- Gross AIDba 13.5 7.3 Not Sampled Not Samjlled Not Samp).L'<i vecs (uli[L<I) = ~ Acetone <20 <20 Not Sampled Not Sampled Not Sampled Benzene <1 <1 Carbon tetrachloride <1 <1 Chloroform <1 <1 Chloromethane <1 <1 MEK <20 <20 Methylene Chloride <1 <1 Naphtllalene <1 <1 Tctrallydrofuran <100 6.13 Toluene <1 <1 Xylenes <1 <1 no_rS.lul!l[;)~ l .2,4-Trichlorobenzene NA <10 Not Sampled Not Sampled Not Sampled 1 ,2-0ichlorobenzene NA <10 1,3-Dichlorobenzene NA <10 1.4-Dichlorobenzene NA <10 1-Methylnaphthalene NA <10 2.4,5-Trichlorophcnol NA <10 2,4,6-lrichlo,·ophcnol NA <10 2,4-Dichlorophcnol NA <10 2.4-Dimcthylpheno! NA <10 2,4-Dinitrophenol NA <20 Cell2 LDS Ch I d R d' I I Ch ermca an a JO O_gJca t . f arac ens Ics Constlillent 2009 -20TO 2011 2012 2013 =, MaJor lons.{mill) 2.4-Dinitrotoluene NA <10 Not Sampled Not Sampled Not Sampled 2,,6-Dinitrotoluone NA <10 2-ChloronDphlhl\lene NA <LO 2-Chlo·rophenol NA <10 2-Melhvlnaphthalene NA <10 2-'Metllvlphenol NA <10 2-Nitrophenol NA <10 3&4-Met hylphcuol NA <10 3.3 '-Dichlorobenzidine NA <10 4,6-Dinitrn-2-methy1phenol NA <10 4-BromophenyJ phenvJ ether NA <10 4-Chloro-J -ntethylphenol NA <10 4-Chlorophenyl phenyl ether NA <10 4-NIII'Ophcno] NA <10 Accnaphthene NA <10 Acenrtphtbylene NA <10 Anthracene NA <10 Azobenzene NA <10 llcnz(a)antfh'lleene NA <10 Benzidine NA <10 Benzo(n)pyrcne NA <10 Benzo(bjfluorantbene NA <10 B'enzo(g.h.i)perylt:ne NA <10 Benzo(k)fluoranthcne NA <10 Bis(2·chlol'()cthoxy)ml:ll1lane NA <10 __Bis(2-chloroelhyl)_ ether NA <10 Bis(2-cbloro1sopropy.l) ether NA <10 'Bis(2-ethylhexyl) phthalate NA <10 .Butyl benzyl phthalate NA <10 Chr¥scnc NA <10 DlbCJ1Z(n)l)Q.J1lbl'llt'ene NA <10 Oietbyl phUUllate NA <10 Dimetbyl phlhilll!lc NA <10 DJ-n-butyl pblba.late NA <10 Di-n-octyl vhthalme NA <10 Fluoranthene NA <10 Fluorene NA <10 Hexachlorobenzene NA <10 Hexachlorobutadiene NA <10 Hex-achlorocvclopcn!adiene NA <10 Hexachloroethane NA <10 1nduno(1 ,2',3--'cd)pyrone NA <10 lsophmone NA <10 Nap.hthn!cnc NA <10 Nitrobenzene NA <10 N-Nitrosodimethylamine NA <10 N-NlLrosodi-n-pn)pylamiue NA <10 N-Nirrosodiphcnylaminc NA <10 Pentachlorophenol NA <10 Phenanthrene NA <10 Phenol NA <10 Pyrenc NA <10 Pyridine NA <10 Cell3 Ch em1ca an a 10 OgiC8 I d U d' I l Ch t . f arac ens 1cs 1,.... = Constituent 1987 2003 2007 2008 2009 2010 2011 2012 2013 2013 I (Avg) (Avg) {feiamvle} 1 -. I 'Maior Ions (.ruWJ)_ ~ Carbonate NA <1 ND ND <1 <1 <1 <1 <1 NS Bicarbonate <5 NA ND ND <1 <1 <1 <1 <1 NS Calcium 300 418 887 478 628 560 200 591 586 NS Chloride NA 2460 15965 15400 17200 3470 40400 8880 38400 NS Fluoride <100 667 42.8 1.4 0.6 54.8 64.1 2300 12400 NS Mtumesium 5400 3386 15767 13100 17100 2500 22100 5680 15400 NS Ni~rogen-Arnmon.ia 13900 1302 13867 9010 21600 2650 6470 6840 100 NS Nllrogen-Nitrate <100 20 102 44 142 26 261 64 277 NS Potassium NA 254 6657 4760 3820 782 2590 1190 2110 NS Sodium 5900 3198 25583 22900 28600 5620 47900 6660 34400 NS Sulfate 180000 33400 173667 167000 214000 40400 197000 80000 440000 NS pH (s.u.) 0.82 2.28 1.60 1.79 1.4 2.18 1.27 2.4 1.05 NS TDS 189000 51633 228500 193000 243000 56200 296000 120000 410000 NS Conductivity ~umhos/crn) NA NA NA NA 304000 59800 86400 80300 84300 NS ~I.JI)s_(u~:r ~ Arsenic 163000 32867 256500 489000 ND 52900 263000 4340 66000 NS BervUium 540 430 913 840 905 206 1570 678 2570 NS Cadmium 2600 1958 9260 15400 ND 1960 12200 3460 24000 NS Chromium 12000 3742 14883 12800 ND 3360 22800 10900 30600 NS Cobalt 48000 NA 82783 57000 ND 13000 76000 76100 99700 NS Copper 360000 87333 505000 345000 ND 89000 768000 379000 954000 NS Iron 2100000 1278333 4874500 4400000 5970000 1460000 1.02E+7 3400000 9700000 NS Lead <20000 2507 9647 16900 ND 17200 16700 1860 14400 NS Manganese 82000 144000 496833 313000 ND 101000 587000 3110000 2470000 NS Mcr:cm·y ND NA ND 16 ND <4 30.9 9.6 21.6 NS Molyb@:num 52000 12250 122167 209000 14 21300 96200 790 56100 NS Nickel 170000 20917 131833 241000 ND 23800 75800 150000 122000 NS Selenium <2000 910 5856 10200 ND 3080 6900 2460 7060 NS Silver <2500 NA 305 1010 ND 101 792 1850 3380 NS Thallium 4700 NA 446 1200 ND 190 518 1080 694 NS Tin NA NA 1090 _1070 ND 155 325 <100 <100 NS Uranium 118000 67833 332333 636000 3690 180000 458000 835000 1200000 NS Vanadium 210000 158333 935000 1130000 ND 692000 2370000 836000 3220000 NS Zinc 590000 NA 748833 515000 ND 134000 726000 652000 1430000 NS Rallio!Qgics {pQitn I Gross Alphu NA 101583 16533 21700 17000 4030 11100 1530 81900 NS VOCS '(uJilL1 Acetone 28 NA 80 100 67 37 330 64 302 159 Benzene <5 NA ND ND <1 <1 <1 <1 <5 <1 Carbon tetrachloride <5 NA ND ND <1 <1 <1 <1 <5 <1 Chloroform 6 NA ND 11 4.2 2.6 31 2 56.3 21 Chloromethane NA NA ND ND 1.4 1.8 3.5 1 <5 2.58 MEK NA NA ND ND <1 <1 67 <20 <100 24.5 Mcthyh;ne Chloride 10 NA ND ND <1 <1 7.4 <1 6.95 <1 Naphthalene <10000 NA ND <10 <1 2.1 1.2 <1 <5 <1 Tct•·ahydrofuran NA NA 150 <20 <100 <10 <10 <1 <5 <1 Toluene <5 NA ND ND <1 <1 <1 <1 <5 <1 Xylcnes <5 NA ND ND <1 <1 <I <1 <5 <1 SVOC'SauWL-) "" 1,2,4-TticWnmbcnzenc NA NA NA NA <11 <10 <10 <10 <10.5 <10 1.2-Djchlorobcnzeoe NA NA NA NA <11 <10 <10 <10 <10.5 <10 1,3· Dichlorobenzene NA NA NA NA <11 <10 <10 <10 <10.5 <10 1.4-Di ch'lorobenzene NA NA NA NA <11 <10 <10 <10 <10.5 <10 1-Melhylnag_hthalen~ NA NA NA NA <11 <10 <10 <10 <10.5 <10 2,4,5-Trichlorophonol NA NA NA NA <11 <10 <10 <10 <10.5 <10 2,4,6-Trichloropncnol NA NA NA NA <11 <10 <10 <10 <10.5 <10 2,4-Di.c_hlOJ'OPhenot NA NA NA NA <11 <10 <10 <10 <10.5 <10 2,4-Di metbjllphcnol NA NA NA NA <11 <10 <10 <10 <10.5 <10 2.4-Di.nitrophenol NA NA NA NA <53 <20 <20 <20 <21.1 <20 2A-DinitrotolucnE:_ NA NA NA NA <11 <10 <10 <10 <10.5 <10 Cell3 Ch em1ca an 3' o ogica d R di I I Ch aracterisbcs ~- Constituent 1987 2003 2007 2008 2009 2010 1011 2012 2013 2013 I• (Avg) (Avg) (resample) l\1djor Ions C'mgl)) I 2,6-Dinitrotoluene NA NA NA NA <11 <10 <10 <10 <10.5 <10 2-Chloronap_bthalcnc NA NA NA NA <11 <10 <10 <10 <10.5 <10 2-Cblorophenol NA NA NA NA <11 <10 <10 <10 <10.5 <10 2-MethylnaphLbalenc NA NA NA NA <11 <10 <10 <10 <10.5 <10 2-Mclllylphenol NA NA NA NA <11 <10 <10 <10 <10.5 <10 2-Nitrophcnol NA NA NA NA <11 <10 <10 <10 <10.5 <10 3&4-Methylphenol NA NA NA NA <11 <10 <10 <10 <10.5 <10 3.3 '-Dich1orobenzidine NA NA NA NA <21 <10 <10 <10 <10.5 <10 4,6· Dinitro-2-rncr.hyl~nol NA NA NA NA <53 <10 <10 <10 <10.5 <10 4-Brom,Qph~nyl phenyl ether NA NA NA NA <11 <10 <10 <10 <10.5 <10 4-Chloro-3-mc:thyl phenol NA NA NA NA <II <10 <10 <10 <10.5 <10 4-Chlorophenyl phenyl ether NA NA NA NA <11 <10 <10 <10 <10.5 <10 4-Nitropbenol NA NA NA NA <53 <10 <10 <10 <10.5 <10 Acenaphtbene NA NA NA NA <11 <10 <10 <10 <10.5 <10 AccnaphLhyleoe NA NA NA NA <11 <10 <10 <10 <10.5 <10 Anthracene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Azobenzene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Benz(a)unthracene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Benzidine NA NA NA NA <21 <10 <10 <10 <10.5 <10 BenzoCa)pyr:ene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Bonzo(b)fluordn\hell_(.:_ NA NA NA NA <11 <10 <10 <10 <10.5 <10 Benzo(g,h,i)perylene NA NA NA NA <11 <10 <10 <10 <10.5 <10 .Bcnzo(k)fluor-anr.bcnc NA NA NA NA <11 <10 <10 <10 <10.5 <10 B W-2-oh l.oroelhoxy)metlmnc NA NA NA NA <11 <10 <10 <10 <10.5 <10 Bis(2-chloroer.hyl) ether NA NA NA NA <11 <10 <10 <10 <10.5 <10 Bfs(2-chl oroisopf'opyl) ether NA NA NA NA <11 <10 <10 <10 <10.5 <10 Bls{2-ethylhexyl) phU1alat~: NA NA NA NA <11 10.6 <10 <10 <10.5 <10 Butyl b~anzyl phthaHtte NA NA NA NA <11 <10 <10 <10 <10.5 <10 Cfuvscne NA NA NA NA <1 1 <10 <10 <10 <10.5 <10 Dlbenz(a,h)anthracene NA NA NA NA <11 <10 <10 <10 <10.5 <10 DieH1yl _phLhalate NA NA NA NA <11 <10 <10 <10 <10.5 <10 Dimethyl ph~halate NA NA NA NA <1 1 <10 <10 <10 <10.5 <10 Di-n-butyl phthalate NA NA NA NA <11 <10 <10 <10 <10.5 <10 Di-n.octyl phtbalatc NA NA NA NA <11 <10 <10 <10 <10.5 <10 Fluoranthene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Fluorene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Hexachlorobenzene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Hexachlorobutadiene NA NA NA NA <11 <10 <10 <10 <10.5 <10 J·lc.x.acltloroc_ycl bpenlndiene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Hexachloroethane NA NA NA NA <11 <10 <10 <10 <10.5 <10 lndeno( 1.2 3-cd)pyrenc NA NA NA NA <11 <10 <10 <10 <10.5 <10 l:;ophorone NA NA NA NA <11 <10 <10 <10 <LO.S <10 Naphdlah.me NA NA NA NA <11 <10 <10 <10 <10.5 <10 Nitrobenzene NA NA NA NA <11 <10 <10 <10 <10.5 <10 ~-Nitrosodimcli1_ylamine NA NA NA NA <11 <10 <10 <10 <10.5 <10 N-Nitrosodi-n-propylamine NA NA NA NA <11 <10 <10 <10 <10.5 <10 N-Nitrosodlphenylamine NA NA NA NA <11 <10 <10 <10 <10.5 <10 Pentachlorophenol NA NA NA NA <53 <10 <10 <10 <10.5 <10 Phenanthrene NA NA NA NA <11 <10 <10 <10 <10.5 <10 Phenol NA NA NA NA <11 <10 <10 <10 <10.5 <10 Pyrena NA NA NA NA <11 <10 <10 <10 <10.5 <10 Pyridine NA NA NA NA <11 <10 <10 <10 <10.5 <10 1 Historic values reported for Gross Alpha from 1987 and 2003 are total gross alpha reported in pCi/L. All other gross alpha data are reported as Gross Alpha minus Rn & U. Ce114A ermca an a 0 OgJCa Ch I d R di I J Ch aractenstics ConslitueoJ. """ 11 ZO® 2010 2JfU 2012 2013 Mujl)r Ions (JQSllll Carbonate <1 <1 <1 <1 <1 Bicarbonate <1 <1 <1 <I <1 Calcium 627 598 558 591 668 Chloride 4650 7350 5870 4980 4530 Fluoride 0.3 21.6 30.6 43 1130 Magnesium 3250 4940 4720 2230 3660 Njtrogen-Arnmonia 3140 5230 4930 1540 1340 Nitrogen-Nitrate 28 52 44 27 38.2 Potassium 980 1440 1450 558 773 Sodium 5980 11300 11400 7130 6860 Sulfate 67600 87100 267000 64900 83300 pH (s.u.) 1.40 1.99 1.73 1.2 1.47 TDS 81400 107000 108000 76000 90000 Conductivity (umhos!cm) 131000 101000 82100 78100 66300 -= MetalS 'fiiilll Arsenic 626000 109000 86600 60500 73700 Beryllium 296 215 323 167 247 Cadmium 1920 3670 2190 844 1450 Chromium 3220 7500 5900 5990 5220 Cobalt 9440 26500 22500 22900 22900 Copper 99200 168000 181000 433000 540000 ...Iron 2360000 2920000 3390000 3190000 2620000 Lead 5360 11800 11000 5270 11500 Mtmgnne.'ic 178000 209000 131000 112000 143000 Mercury 1.19 <4 15.2 2.4 0.786 Molybdenum 24300 43800 24200 58200 25500 Nickel 17100 40900 43500 41300 43300 Selenium 4620 5810 4460 1310 2080 Silver 78 193 216 J27 144 Thallium 162 350 410 250 256 Tin 257 378 319 169 118 Uranium 118000 217000 153000 91000 112000 Vanadium 918000 1090000 730000 237000 461000 Zinc 142000 224000 286000 200000 183000 R"~'•louics (pCUJ): Gross Alph(l 8910 3400 8290 16300 15800 VOCSWgzLJ = Acetone 60 55 100 25 28.4 Benzene <l <1 <1 <1 <1 Carbon tetrachloride <1 <1 <1 <1 <1 Chloroform 4.0 8.5 10 <1 <1 Chloromethane 3.4 5.5 7.9 <1 <1 MEK <1 <1 <1 <1 <20 Methylune Chloride <1 <1 <1 <20 <1 Naphthalene 1.8 <1 <1 <1 <l Tctrnhydrofurnn <100 <10 <10 1.36 <1 Toluene <1 <1 <1 <1 <1 Xylenes <1 <1 <1 <1 <1 ~ svocs ffiltfll,' 1_.2,4-Trichlorobenzene <11 <10 <10 <10 <10 L2-DicbJ:orobenzenc <11 <10 <10 <10 <10 I ,3-Dichlorobenzene <11 <10 <10 <10 <10 1,.4-Dichlorobenzene <11 <10 <10 <10 <10 1-Methyln.aphtl1ahme <11 <10 <10 <10 <10 2.4.S:rrichlorop11enol <11 <10 <10 <10 <10 2,4;6~Triohlorophcnol <11 <10 <10 <10 <10 2,4-Dichlorophcnol <11 <10 <10 <10 <10 2,4-Dimethylphcnol <11 <10 <10 <10 <10 2.4-Dinitrophenol <53 <20 <20 <20 <20 2,4-Dinitrotoluene <11 <10 <10 <10 <10 2.6-Dihitrololuene <11 <10 <10 <10 <10 2-.Chfotonaphthallolne <11 <10 <10 <10 <10 Ce114A Ch I em1ca an d R d" 1 l Ch a ·1o 02Jca aractenstlcs -Consl.iluent 2009 ;z()!h' 201J 2012 2013 Mil or 1ons (nWll 2-Cbloropl)cnol <11 <10 <10 <10 <10 2-Methylnaphth&lerJe <11 <10 <10 <10 <10 2-Methylphenol <11 <10 <10 <10 <10 2-Nitroohenol <11 <10 <10 <10 <10 3&4-MeihyJphenol <11 <10 <10 <10 <10 3,3 '-Dichlorobenzidine <21 <10 <10 <10 <10 4,6-Dinitm-2-methvlphennl <53 <10 <10 <10 <10 4-.Bromoohenyl pherwl ether <11 <10 <10 <10 <10 4-Chlom-3-methylphenol <11 <10 <10 <10 <10 4-C::hloropher\yl phenyl ether <11 <10 <10 <10 <10 4-Nitropllcnol <53 <10 <10 <10 <10 Accnapi'IIJ1ene. <11 <10 <10 <10 <10 Acenaphthylene <11 <10 <10 <10 <10 Anthracene <11 <10 <10 <10 <10 Azobenzene <11 <10 <10 <10 <10 Uen~(n)ilhthra·cenc <11 <10 <10 <10 <10 Benzidine <21 <10 <10 <10 <10 Benzo(o)pyrcne <11 <10 <10 <10 <10 Bem•.o(b)Ouoranthene <11 <10 <10 <10 <10 Beri7-9(~.h.i)perylene <11 <10 <10 <10 <10 Bene-o(l\)fluot'8 nthene <11 <10 <10 <10 <10 Bis(2-chlnruethoxy)methanc <11 <10 <10 <10 <10 Bis(2-.chlomclhyl) ether <11 <10 <10 <10 <10 Bis(2-chloroisopropyl) ether <11 <10 <10 <10 <10 Bis(2-~thylhexyl) phthalate <11 19.6 <10 <10 <10 Butyl benzvl phthalate <11 <10 <10 <10 <10 Chryscne <11 <10 <10 <10 <10 Dibcnz(a,h)anthracene <11 <10 <10 <10 <10 Diethyl ph.thlllate <11 <10 <10 <10 <10 Dimethyl ohtholnte <11 <10 <10 <10 <10 DI-n-butyl phthalate <11 <10 <10 <10 <10 Di-n.-octyl phthalate <11 <LO <10 <10 <10 Fluoranthene <11 <10 <10 <10 <10 Fluorene <11 <10 <10 <10 <10 Hexach1orobenzene <11 <10 <10 <10 <10 Hexachlorobutadiene <11 <10 <10 <10 <10 Hexacllloro<:Yclooe.nt;,~dicne <11 <10 <10 <10 <10 Hexachloroethane <11 <10 <10 <10 <10 l11(!e.no(l ,2.3-cd)pyrcnc <11 <10 <10 <10 <10 lsophorOJlC <11 <10 <10 <10 <10 _NaplHhalene <11 <10 <10 <10 <10 Nitrobenzene <11 <10 <10 <10 <10 N-Nitr.osQdimelhy1amine <11 <10 <10 <10 <10 N-Nitrosodi-n-propylaminc <11 <10 <10 <10 <10 N-Nitrosodip!wnylaminc. <11 <10 <10 <10 <10 Pentnchl.oraphenol <53 <10 <10 <10 <10 Phenanthrene <11 <10 <10 <10 <10 Phenol <11 <10 <10 <10 <10 Pyreoe <11 <10 <10 <10 <10 Pyridine <11 <10 <10 <10 <10 Cell4A LDS ermca an a 10 OgJCa Ch I d R d. I I Ch aractenstlcs ~onstHuent = 2009 20lf) 2.0ll 2QJZ ~R _t'\lla_jor Ions ~ ~ --'="' Carbonate <1 <1 <1 <1 <1 Bicarbonate <1 <1 <1 <1 <1 Calcium 558 474 470 453 429 Chloride 7570 4670 6040 2710 1910 Fluoride 0.7 39.4 46 27 1970 Magnesium 6390 3240 5100 2070 1710 Nilrogen-Arnmonia 4480 2290 3480 1320 1010 Nifrogen-Nitrate 69 183 94 15 28.9 Potassium 1960 934 1500 503 305 Sodium 12600 6700 11000 3500 2930 Sulfate 92400 41700 77400 39600 31400 pH (s.u.} 1.98 2.53 2.32 2.1 2.32 TDS 117000 56900 93800 55400 49700 Conductivity (umhqs/crn) 150000 49000 66600 39600 31300 lfufuls;(u~TJ' Arsenic 133000 54000 74700 44100 35700 Beryllium 536 295 367 180 188 Cadmium 4010 2650 3160 921 1170 Chromium 9140 3890 5940 3930 2630 Cobalt 37300 15200 21700 22300 44300 Copper 222000 116000 150000 481000 754000 Iron 3940000 1420000 2530000 2460000 1370000 Lead 5270 3400 4520 2300 165 Manganese 389000 157000 207000 95200 86300 Mcrcurr 2.66 6.2 14.7 0.7 <0.5 Motylrdcoum 49200 23900 29300 10200 1200 Nickel 43900 23900 29600 35000 54600 Selenium 5250 2820 3780 1260 1020 Silver 204 62 127 44 24.8 Thallium 252 194 290 332 171 Tin 504 180 119 <100 <100 Uranium 284000 145000 168000 90200 75000 Vanadium 1150000 518000 770000 240000 157000 Zinc 298000 152000 204000 181000 163000 ~ Radlofoglcs·(pC)/1) . Gross AJph.a 7020 3230 7440 4730 6930 vocs (US!liJJ . Acetone 240 130 120 55 57 Benzene <1 <1 <1 <1 <1 Carbon tetrachloride <1 <1 <1 <1 <1 Chloroform 23 52 26 42 110 Chloromethane 7.9 13 3.8 6 9.93 MEK 78 50 82 36 <20 MetHylene Chloride <1 <1 <1 <1 <1 Naphtha~ne <1 1.5 <1 1 2.35 Tetrah ydrofu ran 140 158 102 117 39.1 Toluene <1 <1 <1 <1 <1 ]<y1C:nes <I <1 <1 <1 <1 -S_VOCS lug/£1 ~ 1,2,4~ Trichlorobenzene <11 <10 <10 <10 <10 1.2-Dichlorobenzene <11 <10 <10 <10 <10 1,3-Dichlorobenzene <11 <10 <10 <10 <10 1 ,4-Dichlorobcnzene <11 <10 <10 <10 <10 1-Melhylnapot,halcne <11 <10 <10 <10 <10 2,4,5-Trichlorophenol <11 <10 <10 <10 <10 2,4,6-Trichlorophcnol <ll <10 <10 <10 <10 2.4-Dichlorophenol <11 <10 <10 <10 <10 '2,4-Dimethvlphcnol <11 <10 <10 <10 <10 Cell4A LDS Ch I em1ca an d Raili I . al Ch 0 OgiC t . f arac ens 1cs cUmilittient. 2009 2010 2011 2012 2013 I Ma.ior Ions CtJ:fU/ll 2.4-Dinllrophenol <64 <20 <20 <20 <20 2,4-Dioiu·otolucne <11 <10 <10 <10 <10 2.6-Dinitrmnlucne <11 <10 <10 <10 <10 2-Chloronaplrtha.lcne <11 <10 <10 <10 <10 2 -Chlorophenol <11 <10 <10 <10 <10 2-Methylnaph!halene <11 <10 <10 <10 <10 2-Methyl phenol <11 <10 <10 <10 <10 2-Nltrophenol <11 <10 <10 <10 <10 3&4-Methylphcnol <11 <10 <10 <10 <10 3.3 '-Dichlorobenzidine <22 <10 <10 <10 <10 4.6-Dinitro-2-methylpbenol <54 <10 <10 <10 <10 4-Brom,ephenyl phenyl ether <11 <10 <10 <10 <10 4-Chloro-3-methylphenol <11 <10 <10 <10 <10 4-Cblorophcnyl phenyl ether <11 <10 <10 <10 <10 4-Nitrophenol <54 <10 <10 <10 <10 AcenaphtheM <11 <10 <10 <10 <10 Accnuphlhylene <11 <10 <10 <10 <10 Anthracene <11 <10 <10 <10 <10 Azobenzene <11 <10 <10 <10 <10 Bcnz(a)unthraccne <11 <10 <10 <10 <10 Benzidine <22 <10 <10 <10 <10 Benzo(a)pyrene <11 <10 <10 <10 <10 Henzo(b)fluoranthtlne <11 <10 <10 <10 <10 Benz.o(g,h,i)~C!rylene <11 <10 <10 <10 <10 Benzo(k)fluoranthene <11 <10 <10 <10 <10 .Bis(2-ch1oroethoxy)methane <11 <10 <10 <10 <10 Bis(2-chlorcJt:thyJ) ether <11 <10 <10 <10 <10 Bis(2-chloroisopropyl) ether <11 <10 <10 <10 <10 Bis(2-t:rhylhexyl) phlhalate <11 54.9 54-9 16.6 <10 "Butyl bonzyl phthalate <11 <10 <10 <10 <10 Chrvscnc <11 <10 <10 <10 <10 Dibenz{a,h)aJJthracene <11 <10 <10 <10 <10 Dielhyl phtbalat~: <11 <10 <10 <10 <10 Dimethyl phthalate <11 <10 <10 <10 <10 Di-n-butyl phthalate <11 <10 <10 <10 <10 Di-n-ocryJ phthalare <11 <10 <10 <10 <10 Fluoranthene <11 <10 <10 <10 <10 Fluorene <11 <10 <10 <10 <10 Hexachlorobenzene <11 <10 <10 <10 <10 Hexachlorobutadiene <11 <10 <10 <10 <10 Hexach1orocyclopentadiene <11 <10 <10 <10 <10 Hexachloroethane <11 <10 <10 <10 <10 lndeno(l,2,3-cd)pyrene <11 <10 <10 <10 <10 'Jsophol'one <11 <10 <10 <10 <10 Nllphthalcne <11 <LO <10 <10 <10 Nitrobenzene <11 <10 <10 <10 <10 N-Ni~rosodimethylnminc <11 <10 <10 <10 <10 N-Nitrosodi-n-propylamine <11 <10 <10 <10 <10 N-Nitrosodiphenylamine <11 <10 <10 <10 <10 Penlc'lch'lorophenol <54 <10 <10 <10 <10 Phenanthrene <11 <10 <10 <10 <10 Phenol 33 23.5 <10 <10 <10 Fyrene· <11 <10 <10 <10 <10 P_yricline <11 <10 <10 <10 <10 Cell4B em1ca an a JO_Oil IC3 Ch I d R d. I I Ch aractenshcs Co)l!Hitut:nt 2011 2012' 2013 M ~iorJons 'fnut/1) Carbonate <1 <1 <1 Bicarbonate <1 <1 <1 Calcium 570 580 662 Chloride 8290 8170 4570 Fluoride 26.7 23.3 1050 Magnesium 3910 4500 3560 Nitrogen-Ammonia 5220 5580 2060 Niu:ot!en-Nitrate 39 42 51.4 Potassium 1370 1650 1110 Sodium 9050 11700 3150 Sulfate 134000 119000 98100 I'JH (s.u.) 1.87 1.5 1.65 TDS 98000 128000 108000 Conductivity (umhos/cm) 76900 86900 72800 ~ Me HilS (uK/J) = Arsenic 67400 80000 65400 _B <!fY IIi UJil 311 356 334 Cadmium 1990 2540 1990 Chromium 6860 8280 6390 Cobalt 17800 29300 21300 Copper 193000 340000 340000 Iron 2960000 3580000 2830000 Lead 9960 11600 9820 Man!!anese 128000 148000 154000 Mercury 13.7 2.6 1.49 Molybdenum 21400 27600 26100 Nickel 33900 50500 35100 Selenium 4670 4470 3900 Silver 137 169 137 Thallium 237 368 243 Tin 196 215 163 Uranium 133000 171000 110000 Vanadium 660000 783000 163000 Zinc 191000 270000 184000 Radiololrlcs (pCi/1) Gross Alpha 8590 13600 14600 VOCS(uwiT Aceto.ne 130 94 43.5 Benzene <1 <1 <1 Carbon tetrachloride <1 <1 <1 Chloroform 9.4 4 8.06 Chloromethane 8.5 8 7.12 MEK <1 <1 <20 Methylene Chloride <1 <1 <1 Naphthalene <1 <1 <1 Tetmhvdrofumn <10 11.1 <1 Toluene <1 <1 <1 Xylcncs <1 <1 <1 SVOCS"[ui!ZQ 1,2,4-Trichlorobenzene <10 <10 <10 1.2-Dic.:hlorobcnzcne <10 <10 <10 1.3.·Dichlorobenzene <10 <10 <10 1,4rDichlorobenzene <10 <10 <10 1-Methylnaphthalcne. <10 <10 <10 2 ,4,.5-11·ic:llloropHcn<)l <10 <10 <10 2,4,6-Tricb.lotophenol <10 <10 <10 2,4-Dichlorophe.nol <10 <10 <10 2,4-Dimethylphenol <10 <10 <10 2,4-Dinitrophcn<:ll <20 <20 <20 2.4-Dinitrotoluene <10 <10 <10 Cell4B .,., ~ Chemical and Radiolooieal Characteristics C(mstituenL 2{)11 2012 ·r~ 20.f3' lVl-1\iot Ions (mg!l) 2.6-Dinitrotoluene <10 <10 <10 2-ChiOl'OllO()bthale:ne <10 <10 <10 2-Chlorophenol <10 <10 <10 2-Me-lhylnophtbalenc <10 <10 <10 2-Me.thYlphenol <10 <10 <10 2-Nitrophenol <10 <10 <10 3&4-Methylphcnol <10 <10 <10 3,3 '-Dich1orobenzidine <10 <10 <10 4,6-Dinitro-2-methylphenol <10 <10 <10 4-Bromophenyl phenyl ether <10 <10 <10 4-Chloro-3-methylpht!nol <10 <10 <10 4-C hlQrophenyl piJenyl ether <10 <10 <10 4-Nitrophenol <10 <10 <10 Acenaphthene <10 <10 <10 Acenaphthylene <10 <10 <10 Anthracene <LO <10 <10 Azobenzene <10 <10 <10 Benz( a)anthracene <10 <10 <10 Benzidine <10 <10 <10 Bcnzo(o)pyrcne <10 <10 <10 Benzo(b).Uuoranthenc <10 <10 <10 Benzo(g,h ,i )perylene <10 <10 <10 Bcnzo(k)Jluornnthene <10 <10 <10 Bis(2-chloroethoxy)methane <10 <10 <10 Bis(2-chloroethyl) ether <10 <10 <10 Bis(2-chloroisopropyl) ether <10 <10 <10 'Bis(2-ethylhexyl) phthalate 410 19 <10 Bu9'j benzyl ]J_hthalate <10 <10 <10 Chrysene <10 <10 <10 Uibcnz(a,b)antht'3.cenc <10 <10 <10 Diethyl phthalate <10 <10 <10 Dimethyl phthalate <10 <10 <10 Di-n-butyl phthalate <10 <10 <10 Ui-n-odyl Rhtbalo_te <10 <10 <10 Fluoranthene <10 <10 <10 Fluorene <10 <10 <10 Hexachlorobenzene <10 <10 <10 Hexachlorobutadiene <10 <10 <10 Hexachlorocyclopentadiene <10 <10 <10 Hexachloroethane <10 <10 <10 l'ndenoC 1,2_,J.cd}pyn:mc <10 <10 <10 _Isophorone <10 <10 <10 Naphthalene <10 <10 <10 Nitrobenzene <10 <10 <10 N-Nitrosodimeth_}'lamine <10 <10 <10 N-Nitrosodi -n-propy !amine <10 <10 <10 N-Nitrosodiphcnylamine <10 <10 <10 PentachlOrophenol <10 <10 <10 Phenanthrene <10 <10 <10 Phenol <10 <10 <10 Pyrone <10 <10 <10 Pyridine <10 <10 <10 Ce114B LDS Ch I ermca an a ao og 1ca d R d. 1 I Ch t . f arac er1s 1cs Constituent 2011 2012 2013 Major Ions (mg/l) II' Carbonate <1 <1 Not Sampled- Bicarbonate <1 <1 dry Caldum 486 456 Chloride 3630 6850 Fluoride 28.4 22 Magnesium 3230 3360 Nitrogen-Ammonia 4260 4090 Nitrogen-Nitrate 30 31 Potassium 1130 1060 Sodium 8240 8080 Sulfate 59900 99100 pH (s.u.) 2.23 2.4 TDS 85800 90200 Conductivity (umhos/cm_) 63000 62400 MetaJs (og/1) Arsenic 54200 41200 Not Sampled- Beryllium 274 271 dry Cadmium 1670 1740 Chromium 6250 5930 Cobalt 15600 19000 Copper 176000 181000 Iron 2450000 2120000 Lead 6060 4420 Manganese 118000 162000 Mercury 12.3 3_ Molybdenum 16700 15000 Nickel 30700 33700 Selenium 3710 2880 Silver Ill 117 Thallium 179 175 Tin 332 <100 Uranium 111000 132000 Vanadium 518000 428000 Zinc 172000 182000 Radiologies (pCi/1) = Gross Alpha 6000 7500 Not Sampled- dry VOCS (oWl) Acetone 390 370 Not Sampled - Benzene <1 <1 dry Carbon tetrachloride <1 <1 Chloroform 20 19 Chloromethane 11 11 MEK 240 180 Methylene Chloride <1 <1 Naphthalene <1 <1 Tetrahydrofuran 198 3_22 Toluene <1 <1 Xylenes <1 <1 SVOCS (oWl) 1 ,2.4-Trichlorobenzene <10 <10 Not Sampled - 1 ,2-Dichlorobenzene <10 <10 dry l ,3-Dichlorobenzene <10 <10 1.4-Dichlorobenzene <10 <10 1-Methylnaphthalene <10 <10 2.4.5-Trichloropheno1 <10 <10 2,4,6-Trichlorophenol <10 <10 2,4-Dichlorophenol <10 <10 2,4-Dimethy_lphenol <10 <10 2.4-Dinitrophenol <20 <20 2,4-Dinitrotoluene <10 <10 2,6-Dinitrotoluene <10 <10 Ceii4B LDS Chennca and Radiologtcal Characteristics .21)12 2-Chloronaphthalene <1 0 <10 2-Chlero_t:rheool <10 <10 2-Methyln<lphthaJcne <1 o <1 o '~--------~2~-~M~c~t~hy~l~p·lh~e~n~o~l----------+-----~<~10~----+-----~<~10~--~ 2-Nilrophenol <1 o <1 o 3&4-Methylphenol <10 <10 3.3'-Dichlorobenzidine <10 <10 4,6-Dinitro-2-methylphenol <10 <10 4-BI'omophcnyl phenyl ether <I 0 <I 0 4-Chloro-3-mcthylph~nol <I 0 <1 0 4-Chloropltenyl phenyl ether <1 0 <I 0 4-NitrOIJbenol <10 <10 Acenaphthenc <1 0 <1 0 Acenaphrhylene <10 <10 Anthracene <10 <10 Azobenzene <10 <10 Bcn~(a}anthmcene <10 <10 Benzidine <10 <10 Ben~o(a)pyrene <10 <10 Br.}rrlo('o)fluoramflcne <10 <10 .Benzo(g.h.i)perylene <10 <10 Be117..0(k)fluoramhene <10 <10 Bis(2-chloroethoxy)methane <10 <10 Bis(2-chloroerhyl) ether <10 <10 Uis(2-<:hioroillopropyl) ether <10 <10 Bi.s(2-ethylhexyl) phthalate 191 191 But vi berrLyl P.IHhalatc <10 <10 Chrvsooe <10 <10 Dibenz(a.h)anthracene <10 <10 Dicthyl phthalate <10 <10 Di niethyj _p_hthalatc <10 <10 Di-n-butyl phthal.ate <10 <10 Di-n-octyl ph!hala!c <10 <10 F1uoranthene <10 <10 Fluorene <10 <10 Hexachlorobenzene <10 <10 Hexachlorobutadiene <10 <10 .Hex<l..chlorocyclopentadiunc <10 <10 Hexachloroethane <10 <10 l.ndeno(l.2.3-cd)pyrene <10 <10 lsophorone <10 <10 Naphthalene <10 <10 Nitrobenzene <10 <10 N-Nitrosodimethylarnine <10 <10 N-Nitmsodi-n-Qropylaminc <10 <10 N-Ni.Lro$odiphenylamine <10 <10 Pcntltclilorcmhenol <10 <10 Phenanthrene <10 <10 Phenol <10 <10 Pyrenc <10 <10 Pyridine <10 <10 2013 Not Sampled - dry -a1 mgs 1980 2003 IUC/NRC T T as ewa er Wt t s I "'.t amp1es· Constituent ' ~ ~Minimum Maximum -~ pH (Std units) 0.7 2.33 Nutrients (mg/L) ~ Ammonia (N) 3.0 13900 Nitrite (N) <100 <100 Nitrate (N) 24 24 Nitrate+Nitrite (N) 17.0 49.2 Phosphorus -total 88.1 620 TKN (N) 4900 5300 Inor~anics (mWJ.,) Bicarbonate (HC03) <5 <5 Bromide <500 <500 Carbonate (C03) <1 <5 Chloride 2110 8000 Cyanide-total 0.022 0.022 Fluoride 0.02 4400 Phosphate <500 <500 Silica 110 400 Sulfate 29800 190000 Sulfide <5 <5 TDS 43100 189000 TOC 76.0 81 TSS 31.0 115 I Metals (m2/J) - Aluminum 330 2530 Antimony <20 <20 Arsenic 0.3 440 Barium 1.021 0.1 Beryllium 0.347 0.78 Boron 3.5 11.3 Cadmium 1.64 6.6 Calcium 90.0 630 Chromium 1.0 13 Cobalt 14.0 120 Copper 72.2 740 Iron 1080 3400 Gallium <30 <30 Lead 0.21 6.0 Lithium <10 <20 Magnesium 1800 7900 Manganese 74.0 222 Mercury 0.0008 17.6 Molybdenum 0.44 240 Nickel 7.2 370 Potassium 219.0 828 Selenium 0.18 2.4 Silver 0.005 0.14 Sodium 1400 10000 Strontium 3.6 14 Thallium 0.7 45 Tin <5 <5 Titanium 6.5 33.3 Uranium 5.0 154 Vanadium 136 510 Zinc 50 1300 Zirconium 2.3 38.5 Radiolo~cs (pCi/L) ----- Gross Alpha 14000 189000 Gross Beta 74 116000 Lead-210 680 20700 Thori urn-230 3650 76640 Thorium-232 49 121 Polonium-21 0 1410 1410 Radiurn-226 40 1690 Radiurn-228 1.9 1.9 1980 2003 IUC/NRC T T -aa mg,s Wt t s as ewa er ampJes· Constituent -..=. Minimum Maximum Total Radium 42 1700 Selected VOCs (ug/L) Acetone 28 514 Benzene <5 <5 2-butanone (MEK) 11 15.13 Carbon Disulfide 16 16 Carbon Tetrachloride <5 <5 Chloroform 6 16.84 1,1-Dichloroethane <5 <5 1,2-Dichloroethane <5 <5 Dichloromethane 10 11 Tetrahydofuran NIA N/A Toluene <5 6.25 Vinyl Chloride <10 <10 Xylene (total) <5 <5 Selected Semivolatiles (oWl) Uun~o(a)p~imme <10 <10 Bis(2-crhylhexyl)phtha latc 1 1 Chrysene <10 <10 Diethyl phthalate <10 18.1 Dimethylphthalate 2.7 2.7 Di-n-buty1phthalate 1.08 1.08 Fluoranthene <10 <10 2-Methylnaphthalene <10 <10 Naphthalene 2.44 2.44 Phenol <10 38.4 *Reproduced from the Utah Division of Radiation Control Groundwater Quality Discharge Permit, Statement of Basis for a Uranium Mining Facility at White Mesa, South of Blanding, Utah, dated December 1, 2004. 1The data in the Utah Division of Radiation Control Groundwater Quality Discharge Permit, Statement of Basis are based on historical data collected from Cell 1, Cell2, and Cell 3. The date of collection reflects which cells were operational at the time of sampling. The location of the samples and date of collection is referenced in the Statement of Basis, Appendix F Cell4A and 4B BAT Monitoring, Operations and Maintenance Plan 07111 Revision: Denison 2.3 07/2011 Revision Denison 2.3 Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan. TABLE OF CONTENTS 1.0 Introduction .............................................................................................................. 2 2.0 Cell Design ............................................................................................................... 2 2.1 Cell 4A Design ................................................................................................. 2 2.2 Cell 4B Design .................................................................................................. 5 3.0 Cell Operation .......................................................................................................... 8 3.1 Solution Discharge to Cell4A .......................................................................... 8 3.2 Solution Discharge to Ce114B .......................................................................... 8 3.3 Initial Solids Discharge into Cell 4A ................................................................ 9 3.4 Initial Solids Discharge into Cell4B ................................................................ 9 3.5 Equipment Access to Ce114A and Ce114B ..................................................... 10 3.6 Reclaim Water System at Cel14A .................................................................. 10 3.7 Reclaim Water System at Ce114B .................................................................. 10 3.8 Interim Solids Discharge to Cell 4A ............................................................... 11 3.9 Interim Solids Discharge to Ce114B ............................................................... 11 3.10 Liner Maintenance and QA/QC for Cell 4A ............................................... 11 3.11 Liner Maintenance and QA/QC for Ce114B ............................................... 11 4.0 BAT Performance Standards for Tailings Cell4A and 4B .................................... 11 5.0 Routine Maintenance and Monitoring ................................................................... 13 5.1 Solution Elevation .......................................................................................... 13 5.2 Leak Detection System ................................................................................... 13 5.3 Slimes Drain System ...................................................................................... 15 6.0 Tailings Emergencies ............................................................................................. 16 7.0 Solution Freeboard Calculations ............................................................................ 16 8.0 List of Attachments ................................................................................................ 18 N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for perrnit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 1 07/2011 Revision Denison 2.3 1.0 Introduction Constmction of Cell 4A was authorized by the Utah Department of Environmental Quality, Division of Radiation Control ("DRC) on June 25, 2007. The construction authorization provided that Cell 4A shall not be in operation until after a BAT Monitoring, Operations and Maintenance Plan is submitted for Executive Secretary review and approval. The Plan shall include requirements in Part I.F.3 of the Groundwater Discharge Pennit No. UGW370004 ("GWDP") and fulfill the requirements of Parts I.D.6, I.E.8, and I.F.9 of the GWDP. Construction ofCell4B was authorized by DRC on June 21 ,2010. The constmction authorization provided that Cell4B shall not be in operation until after a BAT Monitoring, Operations and Maintenance Plan is submitted for Executive Secretary review and approval. The Plan shall include requirements in Part I.F.3 of the GWDP and fulfill the requirements of Parts I.D.12, I.E.12, and I.F.9 of the GWDP 2.0 Cell Design 2.1 Cell4A Design Tailings Cell 4A consists of the following major elements: a) Dikes -consisting of earthen embankments of compacted soil, constructed between 1989-1990, and composed of four dikes, each including a 15-foot wide road at the top (minimum). On the north, east, and south margins these dikes have slopes of 3H to 1 V . The west dike has an interior slope of 2H to 1 V . Width of these dikes varies; each has a minimum crest width of at least 15 feet to support an access road. Base width also varies from 89-feet on the east dike (with no exterior embankment), to 211-feet at the west dike. b) Foundation -including sub grade soils over bedrock materials. Foundation preparation included excavation and removal of contaminated soils, compaction of imported soils to a maximum dry density of 90%. Floor of Cell 4A has an average slope of 1% that grades from the northeast to the southwest comers. c) Tailings Capacity-the floor and inside slopes of Cell4A encompass about 40 acres and have a maximum capacity of about 1.6 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: 1) Primary Flexible Membrane Liner (FML)-consisting of impermeable 60 N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page2 07/2011 Revision Denison 2.3 mil high density polyethylene (HDPE) membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML will be in direct physical contact with the tailings material over most of the Cell 4A floor area. In other locations, the primary FML will be in contact with the slimes drain collection system (discussed below). N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for perrnit\Cell 4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page3 Cel14A BAT Monitoring, Operations and Maintenance Plan Ol/21/2010 Revision Denison 2.2 2) Leak Detection System-includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4A, and drains to a leak detection sump in the southwest corner. Access to the leak detection sump is via an 18-inch inside diameter (ID) PVC pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe will be surrounded with a gravel filter set in the leak detection sump, having dimensions of 10 feet by 10 feet by 2 feet deep. In tum, the gravel filter layer will be enclosed in an envelope of geotexti1e fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. 3) Secondary FML-consisting of an impermeable 60-mil HDPE membrane found immediately below the leak detection geonet. Said FML also extends across the entire Cell 4A floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. 4) Geosynthetic Clay Liner-consisting of a manufactured geosynthetic clay liner (GCL) composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. Prior to disposal of any wastewater in Cell 4A, the Permittee shall demonstrate that the GCL has achieved a moisture content of at least 50% by weight. This item is a revised requirement per DRC letter to DUSA dated September 28,2007 e) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: 1) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4A that drain to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated two-part geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric . The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southwesterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. 2) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection (SDC) pipe found at the downgradient end of the strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted laterally by sandbags on each side of the backbone of the berm. N:\Cell4B1July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for perrnit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page4 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 In tum, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast comer downhill to the far southwest corner of Cell 4A where it joins the slimes drain access pipe. 3) Slimes Drain Access Pipe-consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4A at the southwest comer, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and nonwoven geotextile that serves as a cushion to protect the primary FML. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted by sandbags.A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. f) Dike Splash Pads - A minimum of eight (8) 20-foot wide splash pads are installed on the interior dike slopes to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HDPE membrane that is placed down the inside slope of Cell 4A, from the top of the dike and down the inside slope. The pads extend to a point 5-feet beyond the toe of the slope to protect the liner bottom during initial startup of the Cell. The exact location of the splash pads is detailed on the As-Built Plans and Specifications. g) Rub Protection Sheets -In addition to the splash pads described in f) above, rub sheets are installed beneath all piping entering or exiting Cell 4A that is not located directly on the splash pads. h) Emergency Spillway - a concrete lined spillway constructed near the western corner of the north dike to allow emergency runoff from Cell 3 into Cell4A. This spillway will be limited to a 6-inch reinforced concrete slab set directly over the primary FML in a 4-foot deep trapezoidal channel. A second spillway has been constructed in the southwest corner of Cell 4A to allow emergency runoff from Cell 4A into Cell 4B. All stormwater runoff and tailings wastewaters not retained in Cells 3 and 4A, will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. 2.2 Cell4B Design Tailings Cell 4B consists of the following major elements: a) Dike -consisting of a newly-constructed dike on the south side of the cell with a 15-foot wide road at the top (minimum) to support an access road. The grading plan for the Cell 4B excavation includes interior slopes of 2H to 1 V. The exterior slope of the southern dike will have the typical slopes of 3H to 1 V. Limited portions of the Cell 4B interior sideslopes in the N:\Cell4BVuly 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc PageS Cell4A BAT Monitoring, Operations and Maintenance Plan 0112112010 Revision Denison 2.2 northwest corner and southeast comer of the cell (where the slimes drain and leak detection sump will be located) will also have a slope of 3H to 1 V. The base width of the southern dike varies from approximately 100 feet at the western end to approximately 190 feet at the eastern end of the dike, with no exterior embankment present on any other side of the cell. b) Foundation -including sub grade soils over bedrock materials. Foundation preparation included 6-inch over excavation of rock and placement and compaction of imported soils to a maximum dry density of 90% at a moisture content between +3% and -3% of optimum moisture content, as determined by ASTM D-1557. The floor of Cell 4B has an average slope of 1% that grades from the northwest comer to the southeast corner. c) Tailings Capacity -the floor and inside slopes of Cell 4B encompass about 45 acres and the cell will have a water surface area of 40 acres and a maximum capacity of about 1.9 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: 1) Primary Flexible Membrane Liner (FML) -consisting of 60 mil high density polyethylene (HDPE) membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML will be in direct physical contact with the tailings material over most of the Cell 4B floor area. In other locations, the primary FML will be in contact with the slimes drain collection system (discussed below). 2) Leak Detection System -includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4B, and drains to a leak detection sump in the southeast corner. Access to the leak detection sump is via an 18-inch inside diameter (ID) PVC pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe will be surrounded with a gravel filter set in the leak detection sump, having dimensions of 10 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer will be enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. 3) Secondary FML -consisting of a 60-mil HDPE membrane found immediately below the leak detection geonet. Said FML also extends across the entire Cell 4B floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. 4) Geosynthetic Clay Liner-consisting of a manufactured geosynthetic clay liner (GCL) composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. Prior to disposal of any wastewater in Cell 4B, the Permittee shall demonstrate that the GCL has achieved a moisture content of at least 50% by weight. N:\Cell4BVuly 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for pennit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 6 Cell4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 e) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: 1) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4B that drain to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated two-part geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southeasterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. 2) Horizontal Slimes Drain Collection Pipe System-includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection (SDC) pipe found at the downgradient end of the strip drain lines. This pipe is in tum overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted by sandbags. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northwest corner downhill to the far southeast corner of Cell 4B where it joins the slimes drain access pipe. 3) Slimes Drain Access Pipe-consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4B at the southeast comer, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and non-woven geotextile that serves as a cushion to protect the primary FML. The non-woven geotextile material is overlain at the surface by a woven geotextile fabric, which is ballasted laterally by sandbags on each side of the backbone of the berm. A reducer connects the horizontal 18- inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. f) Cell 4B North and East Dike Splash Pads -Nine 20-foot-wide splash pads will be constructed on the north and east dikes to protect the primary FML from abrasion and scouring by tailings slurry. These pads will consist of an extra layer of textured, 60 mil HDPE membrane that will be installed in the anchor trench and placed down the inside slope of Cell 4B, from the top of the dike, under the inlet pipe, and down the inside slope to a point at least 5 feet onto the Cell 4B floor beyond the toe of the slope. N:\Cell 4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for permit\Cell 4A and 4B 0 lVI Plan Rev 2.2 July 2011 clean.doc Page 7 Cell4A BAT Monitoring, Operations and Maintenance Plan 01/2112010 Revision Denison 2.2 g) Rub Protection Sheets -In addition to the splash pads described in f) above, rub sheets are installed beneath all piping entering or exiting Cell 4B that is not located directly on the splash pads. h) Emergency Spillway - a concrete lined spillway constructed near the southern corner of the east dike to allow emergency runoff from Cell 4A into Cell 4B. This spillway will be limited to a 6-inch reinforced concrete slab, with a welded-wire fabric installed within its midsection, set atop a cushion geotextile placed directly over the primary FML in a 4-foot deep trapezoidal channel. A 100 foot wide, 60 mil HDPE geomembrane splash pad will be installed beneath the emergency spillway. No other spillway or overflow structure will be constructed at Cell 4B. All stormwater runoff and tailings wastewaters not retained in Cells 2, 3 and 4A, will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. 3.0 Cell Operation 3.1 Solution Discharge to Cell4A Cell 4A will initially be used for storage and evaporation of process solutions from the Mill operations. These process solutions will be from the uranium/vanadium solvent extraction circuit, or transferred from Cell 1 evaporation pond or the free water surface from Cell 3, or transferred from Cell 2 tailings dewatering operations. The solution will be pumped to Ce114A through appropriately sized pipelines. The initial solution discharge will be in the southwest corner of the Cell. The solution will be discharged in the bottom of the Cell, away from any sand bags or other installation on the top of the FML. Building the solution pool from the low end of the Cell will allow the solution pool to gradually rise around the slimes drain strips, eliminating any damage to the strip drains or the sand bag cover due to solution flowing past the drainage strips. The solution will eventually be discharged along the dike between Cell 3 and Cell4A, utilizing the Splash Pads described above. The subsequent discharge of process solutions will be near the floor of the pond, through a discharge header designed to discharge through multiple points, thereby reducing the potential to damage the Splash Pads or the Slimes Drain system. At no time, subsequent to initial filling, will the solution be discharged into less than 2 feet of solution. As the cell begins to fill with solution the discharge point will be pulled back up the Splash Pad and allowed to continue discharging at or near the solution level. 3.2 Solution Discharge to Cell4B Cell 4B will initially be used for storage and evaporation of process solutions from the Mill operations. These process solutions will be from the uranium/vanadium solvent extraction circuit, or transferred from Cell 1 evaporation pond or the free water surface from Cell 3 or Cell 4A, or transferred N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 8 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/2112010 Revision Denison 2.2 from Cell 2 dewatering operations. The solution will be pumped to Cell 4B through appropriate sized pipelines pipelines. The initial solution discharge will be in the southeast comer of the Cell. The discharge pipe will be routed down the Splash Pad provided in the southeast comer of the Cell at the spillway to protect the primary FML. The solution will be discharged in the bottom of the Cell, away from any sand bags or other installation on the top of the FML. Building the solution pool from the low end of the Cell will allow the solution pool to gradually rise around the slimes drain strips, eliminating any damage to the strip drains or the sand bag cover due to solution flowing past the drainage strips. The solution will eventually be discharged along the dike between Cell 3 and Cell 4B, utilizing the Splash Pads described above. The subsequent discharge of process solutions will be near the floor of the pond, through a discharge header designed to discharge through multiple points, thereby reducing the potential to damage the Splash Pads or the Slimes Drain system. At no time, subsequent to initial filling , will the solution be discharged into less than 2 feet of solution. As the cell begins to fill with solution the discharge point will be pulled back up the Splash Pad and allowed to continue discharging at or near the solution level. 3.3 Initial Solids Discharge into Cell 4A Once Cell 4A is needed for storage for tailings solids the slurry discharge from No. 8 CCD thickener will be pumped to the cell through appropriately sized pipelines. The pipelines will be routed along the dike between Cell 3 and Cell 4A, with discharge valves and drop pipes extending down the Splash Pads to the solution level. One or all of the discharge points can be used depending on operational considerations. Solids will settle into a cone, or mound, of material under the solution level, with the courser fraction settling out closer to the discharge point. The initial discharge locations are shown on Figure 1 A. Figure 2A illustrates the general location of the solution and slurry discharge pipelines and control valve locations. The valves are 6" or 8" stainless steel knife-gate valves. The initial discharge of slurry will be at or near the toe of the Cell slope and then gradually moved up the slope, continuing to discharge at or near the water surlace. This is illustrated in Section A-A on Figure 2A. Because of the depth of Cell 4A, each of the discharge points will be utilized for an extended period of time before the cone of material is above the maximum level of the solution. The discharge location will then be moved further to the interior of the cell allowing for additional volume of solids to be placed under the solution level. The solution level in the cell will vary depending on the operating schedule of the Mill and the seasonal evaporation rates. The tailings slurry will not be allowed to discharge directly on to the Splash Pads, in order to further protect the FML. The tailings slurry will discharge directly in to the solution contained in the Cell, onto an additional protective sheet, or on to previously deposited tailings sand. 3.4 Initial Solids Discharge into Cell 4B Once Cell 4B is needed for storage for tailings solids the slurry discharge from No. 8 CCD thickener will be pumped to the cell through appropriately sized N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3Vuly 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page9 Cell4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 pipelines. The pipelines will be routed along the dike between Cell 3 and Cell 4B, with discharge valves and drop pipes extending down the Splash Pads to the solution level. One or all of the discharge points can be used depending on operational considerations. Solids will settle into a cone, or mound, of material under the solution level, with the courser fraction settling out closer to the discharge point. The initial discharge locations are shown on Figure lB. Figure 2B illustrates the general location of the solution and slurry discharge pipelines and control valve locations. The valves are 6" or 8" stainless steel knife-gate valves. The initial discharge of slurry will be at or near the toe of the Cell slope and then gradually moved up the slope, continuing to discharge at or near the water surface. This is illustrated in Section A-A on Figure 2B. Because of the depth of Cell 4B, each of the discharge points will be utilized for an extended period of time before the cone of material is above the maximum level of the solution. The discharge location will then be moved further to the interior of the cell allowing for additional volume of solids to be placed under the solution level. The solution level in the cell will vary depending on the operating schedule of the Mill and the seasonal evaporation rates. The tailings slurry will not be allowed to discharge directly on to the Splash Pads, in order to further protect the FML. The tailings slurry will discharge directly in to the solution contained in the Cell, onto an additional protective sheet, or on to previously deposited tailings sand. 3.5 Equipment Access to Cell4A and Cell 4B Access will be restricted to the interior portion of the cells due to the potential to damage the flexible membrane liners. Only low pressure rubber tired all terrain vehicles or foot traffic will be allowed on the flexible membrane liners. Personnel are also cautioned on the potential damage to the flexible membrane liners through the use and handling of hand tools and maintenance materials. 3.6 Reclaim Water System at Cell4A A pump barge and solution recovery system is operating in the southwest corner of the cell to pump solution from the cell for water balance purposes or for re-use in the Mill process. Figure 3A illustrates the routing of the solution return pipeline and the location of the pump barge. The pump barge will be constructed and maintained to ensure that the flexible membrane liner is not damaged during the initial filling of the cell or subsequent operation and maintenance activities. The condition of the pump barge and access walkway will be noted during the weekly Cell inspections. 3. 7 Reclaim Water System at Cell 4 B A pump barge and solution recovery system will be installed in the southeast corner of the cell to pump solution from the cell for water balance purposes or for re-use in the Mill process. Figure 3B illustrates the routing of the solution return pipeline and the location of the pump barge. The pump barge will be constructed and maintained to ensure that the flexible membrane liner is not damaged during N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 10 Cell 4A BAT Monitoring, Operations and Maintenance Plan 01/21/2010 Revision Denison 2.2 the initial filling of the cell or subsequent operation and maintenance activities. The condition of the pump barge and access walkway will be noted during the weekly Cell inspections. 3.8 Interim Solids Discharge to Cell4A Figure 4A illustrates the progression of the slurry discharge points around the north and east sides of Cell 4A. Once the tailings solids have been deposited along the north and east sides of the Cell, the discharges points will subsequently be moved to the sand beaches, which will eliminate any potential for damage to the liner system. 3.9 Interim Solids Discharge to Cell4B Figure 4B illustrates the progression of the slurry discharge points around the north and east sides of Cell 4B. Once the tailings solids have been deposited along the north and east sides of the Cell, the discharges points will subsequently be moved to the sand beaches, which will eliminate any potential for damage to the liner system. 3.10 Liner Maintenance and QA/QC for Cell4A Any construction defects or operational damage discovered during observation of the flexible membrane liner will be repaired, tested and documented according to the procedures detailed in the approved Revised Construction Quality Assurance Plan for the Construction of the Cell 4A Lining System, May 2007, by GeoSyntec Consultants. 3.11 Liner Maintenance and QA/QC for Cell4B Any construction defects or operational damage discovered during observation of the flexible membrane liner will be repaired, tested and documented according to the procedures detailed in the approved Construction Quality Assurance Plan for the Construction of the Cell 4B Lining System, October 2009, by Geosyntec Consultants. 4.0 BAT Performance Standards for Tailings Cell 4A and 4B DUSA will operate and maintain Tailings Cell 4A and 4B so as to prevent release of wastewater to groundwater and the environment in accordance with this BAT Monitoring Operations and Maintenance Plan, pursuant to Part I.H.8 of the GWDP. These performance standards shall include: 1) Leak Detection System Pumping and Monitoring Equipment-the leak detection system pumping and monitoring equipment in each cell N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for permit\Cell 4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page ll Cel14A BAT Monitoring, Operations and Maintenance Plan 01121/2010 Revision Denison 2.2 includes a submersible pump, pump controller, water level indicator (head monitoring), and flow meter with volume totalizer. The pump controller is set to maintain the maximum level in the leak detection system in each cell at no more than 1 foot above the lowest level of the secondary flexible membrane, not including the sump. A second leak detection pump with pressure transducer, flow meter, and manufacturer recommended spare parts for the pump controller and water level data collector is maintained in the Mill warehouse to ensure that the pump and controller can be replaced and operational within 24 hours of detection of a failure of the pumping system. The root cause of the equipment failure will be documented in a report to Mill management with recommendations for prevention of a re-occurrence. 2) Maximum Allowable Head-the Permittee shall measure the fluid head above the lowest point on the secondary flexible membrane in each cell by the use of procedures and equipment specified in the White Mesa Mill Tailings Management System and Discharge Minimization Technology (DMT) Monitoring Plan, 10/10 Revision: Denison~10.2, or the currently approved DMT Plan. Under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower flexible membrane liner, not including the sump. 3) Maximum Allowable Daily LDS Flow Rates-the Permittee shall measure the volume of all fluids pumped from each LDS on a weekly basis, and use that information to calculate an average volume pumped per day. Under no circumstances shall the daily LDS flow volume exceed 24,160 gallons/day for Cell4A or 26,145 gallons/day for Cell 4B. The maximum daily LDS flow volume will be compared against the measured cell solution levels detailed on the attached Table 1A or 1B for Cells 4A or 4B, respectively, to determine the maximum daily allowable LDS flow volume for varying head conditions in the cell. 4) 3-foot Minimum Vertical Freeboard Criteria-the Permittee shall operate and maintain wastewater levels to provide a 3-foot Minimum of vertical freeboard in Tailings Cell4A and Cell4B. Said measurements shall be made to the nearest 0.1 foot. 5) Slimes Drain Recovery Head Monitoring-immediately after the Permittee initiates pumping conditions in the Tailings Cell4A or Cell 4B slimes drain system, quarterly recovery head tests and fluid level measurements will be made in accordance with a plan approved by the DRC Executive Secretary. The slimes drain system pumping and monitoring equipment, includes a submersible pump, pump controller, water level indicator (head monitoring), and flow meter with volume totalizer. N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 12 Cell4A BAT Monitoring, Operations and Maintenance Plan 5.0 Routine Maintenance and Monitoring 01121/2010 Revision Denison 2.2 Trained personnel inspect the White Mesa tailings system on a once per day basis. Any abnormal occurrences or changes in the system will be immediately reported to Mill management and maintenance personnel. The inspectors are trained to look for events involving the routine placement of tailings material as well as events that could affect the integrity of the tailings cell dikes or lining systems. The daily inspection reports are summarized on a monthly basis and reviewed and signed by the Mill Manager and RSO. 5.1 Solution Elevation Measurements of solution elevation in Cell 4A and Cell 4B are to be taken by survey on a weekly basis, and measurements of the beach area in Cell4A and Cell 4B with the highest elevation are to be taken by survey on a monthly basis, by the use of the procedures and equipment specified in the latest approved edition of the DMTPlan. 5.2 Leak Detection System The Leak Detection System in Cell 4A and Cell 4B is monitored on a continuous basis by use of a pressure transducer that feeds water level information to an electronic data collector. The water levels are measured every hour and the information is stored for later retrieval. The water levels are mea~ured to the nearest 0.10 inch. The data collector is currently programmed to store 7 days of water level information. The number of days of stored data can be increased beyond 7 days if needed. The water level data is downloaded to a laptop computer on a weekly basis and incorporated into the Mill's environmental monitoring data base, and into the files for weekly inspection reports of the tailings cell leak detection systems. Within 24 hours after collection of the weekly water level data, the information will be evaluated to ensure that: 1) the water level in the Cell 4A and Cell 4B leak detection sumps did not exceed the allowable level (5556.14 feet amsl in the Cell 4A LDS sump and 5558.5 feet amsl in the Cell4B sump), and 2) the average daily flow rate from the LDS did not exceed the maximum daily allowable flow rate at any time during the reporting period. For Cell 4A and Cell 4B, under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower flexible membrane liner, not including the sump. To determine the Maximum Allowable Daily LDS Flow Rates in the Cell 4A and Cell 4B leak detection system, the total volume of all fluids pumped from the LDS of each cell on a weekly basis shall be recovered from the data collector, and that information will be used to calculate an average volume pumped per day for each cell. Under no circumstances shall the daily LDS flow volume exceed 24,160 gallons/day from Cell 4A or 26,145 gallons/day from Cell 4B. The N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\July 2011 BAT 0 and M Revision for perrnit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 13 Cell4A BAT Monitoring, Operations and Maintenance Plan 01/2112010 Revision Denison 2.2 maximum daily LDS flow volume will be compared against the measured cell solution levels detailed on the attached Tables 1A and lB, to determine the maximum daily allowable LDS flow volume for varying head conditions in Cell 4A and Cell 4B. Any abnormal or out of compliance water levels must be immediately reported to Mill management. The data collector on each cell is also equipped with an visual strobe light that flashes on the control panel if the water level in the leak detection sump exceeds the allowable level (5556.14 feet ams1 in the Cell 4A LDS sump and 5558.5 feet amsl in the Cell 4B sump). The current water level is displayed at all times on each data collector and available for recording on the daily inspection form. Each leak detection system is also equipped with a leak detection pump, EPS Model # 25505- 3 stainless steel, or equal. Each pump is capable of pumping in excess of 25 gallons per minute at a total dynamic head of 50 feet. Each pump has a 1.5 inch diameter discharge, and operates on 460 volt 3 phase power. Each pump is equipped with a pressure sensing transducer to start the pump once the level of solution in the leak detection sump is approximately 2.25 feet (elevation 5555.89 in the Cell 4A LDS sump and 5557.69 feet amsl in the Cell 4B sump) above the lowest level of the leak detection sump (9 inches [0.75 feet] above the lowest point on the lower flexible membrane liner for Cell 4A and 2 114 inches [0.19 feet] for Cell 4B), to ensure the allowable 1.0 foot (5556.14 feet amsl in the Cell 4A LDS sump and 5558.5 feet amsl in the Cell 4B sump) above the lowest point on the lower flexible membrane liner is not exceeded). The attached Figures 6A and 6B (Cell 4A and 4B, respectively), Leak Detection Sump Operating Elevations, illustrates the relationship between the sump elevation, the lowest point on the lower flexible membrane liner and the pump-on solution elevation for the leak detection pump. The pump also has manual start and stop controls. The pump will operate until the solution is drawn down to the lowest level possible, expected to be approximately 4 inches above the lowest level of the sump (approximate elevation 5554.0 and 5555.77 ft amsl for Cells 4A and 4B, respectively). The pump discharge is equipped with a 1.5 inch flow meter, EPS Paddle Wheel Flowsensor, or equal, that reads the pump discharge in gallons per minute, and records total gallons pumped. The flow rate and total gallons are recorded by the Inspector on the weekly inspection form. The leak detection pump is installed in the horizontal section of the 18 inch, perforated section of the PVC collection pipe. The distance from the top flange face, at the collection pipe invert, to the centerline of the 22.5 degree elbow is 133.4 feet in Cell 4A and 135.6 feet in Cell 4B, and the vertical height is approximately 45 feet in Cell4A and approximately 42.5 feet in Cell4B. The pump is installed at least 2 feet beyond the centerline of the elbow. The bottom of the pump will be installed in the leak detection sump at least 135.4 feet in Cell 4A and 137.6 feet in Cell4B or more from the top of the flange invert. A pressure transducer installed within the pump continuously measures the solution head and is N:\Cell 4BVuly 2011 Bat O&M Plan Revision 2.3Vuly 2011 BAT 0 and M Revision for perm.it\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 14 Cell4A BAT Monitoring, Operations and Maintenance Plan 0 l/21/20 10 Revision Denison 2.2 programmed to start and stop the pump within the ranges specified above. The attached Figure 5, illustrates the general configuration of the pump installation. A spare leak detection pump with pressure transducer, flow meter, and manufacturer recommended spare parts for the pump controller and water level data collector will be maintained in the Mill warehouse to ensure that the pump and controller on either cell can be replaced and operational within 24 hours of detection of a failure of the pumping system. The root cause of the equipment failure will be documented in a report to Mill management with recommendations for prevention of a re-occurrence. 5.3 Slimes Drain System (i) A pump, Tsurumi Model # KTZ23.7-62 stainless steel, or equal, will be placed inside of the slimes drain access riser pipe of each cell and a near as possible to the bottom of the slimes drain sump. The bottom of the slimes drain sump in Cell 4A and Cell 4B are 38 and 35.9 feet below a water level measuring point, respectively, at the centerline of the slimes drain access pipe, near the ground surface level. Each pump discharge will be equipped with a 2 inch flow meter, E/H Model #33, or equal, that reads the pump discharge in gallons per minute, and records total gallons pumped. The flow rate and total gallons will be recorded by the Inspector on the weekly inspection form. (ii) The slimes drain pumps will be on adjustable probes that allow the pumps to be set to start and stop on intervals determined by Mill management. (iii)The Cell 4A and Cell 4B slimes drain pumps will be checked weekly to observe that they are operating and that the level probes are set properly, which is noted on the Weekly Tailings Inspection Form. If at any time either pump is observed to be not working properly, it will be repaired or replaced within 15 days; (iv)Depth to wastewater in the Cell 4A and Cell 4B slimes drain access riser pipes shall be monitored and recorded weekly to determine maximum and minimum fluid head before and after a pumping cycle, respectively. All head measurements must be made from the same measuring point, to the nearest 0.01 foot. The results will be recorded as depth-in-pipe measurements on the Weekly Tailings Inspection Form; (v) After initiation of pumping conditions in Tailings Cell 4A or 4B, n a quarterly basis, each slimes drain pump will be turned off and the wastewater in the slimes drain access pipe will be allowed to stabilize for at least 90 hours. Once the water level has stabilized (based on no change in water level for three (3) successive readings taken no less than one (1) hour apart) the water level of the wastewater will be measured and recorded as a depth-in-pipe measurement on a Quarterly Data fonn, by measuring the depth to water below the water level measuring point on the slimes drain access pipe; N:\Cell4BVuly 2011 Bat O&M Plan Revision 2.3Vuly 2011 BAT 0 and M Revision for perrnit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 15 Cell4A BAT Monitoring, Operations and Maintenance Plan 01121/2010 Revision Denison 2.2 The slimes drain pumps for each cell will not be operated until Mill management has determined that no additional process solutions will be discharged to that cell, and the cell has been partially covered with the first phase of the reclamation cap. The long term effectiveness and performance of the slimes drain dewatering will be evaluated on the same basis as the currently operating slimes drain system for Cell2. 6.0 Tailings Emergencies Inspectors will notify the Radiation Safety Officer and/or Mill management immediately if, during their inspection, they discover that an abnormal condition exists or an event has occurred that could cause a tailings emergency. Until relieved by the Environmental or Radiation Technician or Radiation Safety Officer, inspectors will have the authority to direct resources during tailings emergencies. Any major catastrophic events or conditions pertaining to the tailings area should be reported immediately to the Mill Manager or the Radiation Safety Officer, one of whom will notify Corporate Management. If dam failure occurs, notify your supervisor and the Mill Manager immediately. The Mill Manager will then notify Corporate Management, MSHA (303-231-5465), and the State of Utah, Division of Dam Safety (801-538-7200). 7.0 Solution Freeboard Calculations The maximum tailings cell pond wastewater levels in Cell 1, Cell 2, Cell 3, Cell4A, and Cell4B are regulated by condition 10.3 of the White Mesa Mill 11e.(2) Materials License. However, freeboard limits are no longer applicable to Cell 2, Cell 3, and Cell 4A, as discussed below. Condition 10.3 states that "Freeboard limits, stormwater and wastewater management for the tailings cells shall be determined as follows: A. The freeboard limit for Cell 1 shall be set annually in accordance with the procedures set out in Section 3.0 to Appendix E of the previously approved NRC license application, including the January 10, 1990 Drainage Report. Discharge of any surface water or wastewater from Cell 1 is expressly prohibited. B. The freeboard limit for Cell4B shall be recalculated annually in accordance with the procedures established by the Executive Secretary. Said calculations for freeboard limits shall be submitted as part of the Annual Technical Evaluation Report (ATER), as described in Condition 12.3 below [of the license and not included herein]. Based on approved revisions to the DMT Plan dated January 2011, the freeboard limit is no longer applicable to Cells 2, N:\Cell4B\July 2011 Bat O&M Plan Revision 2.3\.July 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 16 Cell 4A BAT Monitoring, Operations and Maintenance Plan 3 and4A. 01/2112010 Revision Denison 2.2 C. The discharge of any surface water, stormwater, or wastewater from Cells 3, 4A, and 4B shall only be through an Executive Secretary authorized spillway structure. [Applicable NRC Amendment:16] [Applicable UDRC Amendment: 3] [Applicable UDRC Amendment:4]" The freeboard limits set out in Section 6.3 of the DMT Plan are intended to capture the Local6-hour Probable Maximum Precipitation (PMP) event, which was determined in the January 10, 1990 Drainage Report for the White Mesa site to be 10 inches. Based on the PMP storm event, the freeboard requirement for Cell 1 is a maximum operating water level of 5615.4 feet above mean sea level (amsl). The Celli freeboard limit is not affected by operations or conditions in Cells 2, 3, 4A, or 4B. Cells 2 and 3 have no freeboard limit because those Cells are full or near full of tailings solids. Cell 4A has no freeboard limit because it is assumed that all precipitation falling on Cell4A will overflow to Cell4B. All precipitation falling on Cell2, 3, and 4A and the adjacent drainage areas must be contained in Cell 4B. The flood volume from the PMP event over the Cell2, 3, and Cell4A pond areas, plus the adjacent drainage areas, which must be contained in Ce114B, is 159.4 acre-feet of water. The flood volume from the PMP event over the Cell4A area is 36 acre-feet of water (40 acres, plus the adjacent drainage area of 3.25 acres, times the PMP of 10 inches). For the purposes of establishing the freeboard in Cell4B, it is assumed Cell4A has no freeboard limit and all of the flood volume from the PMP event will be contained in Cell 4B. The flood volume from the PMP event over the Cell 4B area is 38.1 acre-feet of water ( 40 acres, plus the adjacent drainage area of 5.7 acres, times the PMP of 10 inches). This would result in a total flood volume of 197.5 acre-feet, including the 123.4 acre-feet of solution from Cells 2 and 3 and 36 acre-feet of solution from Cells 2, 3, and 4A that must be contained in Cell4B. The procedure for calculating the freeboard limit for Ce114B is set out in the DMT Plan. The Groundwater Quality Discharge Permit, No. UGW370004, for the White Mesa Mill requires that the minimum freeboard be no less than 3.0 feet for Cells 1, 4A, and 4B but based on License condition 10.3 and the procedure set out in the DMT Plan, the freeboard limits for Cells 1, 4A, and 4B will be at least three feet. Figure 7, Hydraulic Profile Schematic, shows the relationship between the Cells, and the relative elevations of the solution pools and the spillway elevations. The required freeboard for Cell4B will be recalculated annually. N:\Cell4BVuly 2011 Bat O&M Plan Revision 2.3Vuly 2011 BAT 0 and M Revision for permit\Cell4A and 4B 0 M Plan Rev 2.2 July 2011 clean.doc Page 17 Cel14A BAT Monitoring, Operations and Maintenance Plan 8.0 List of Attachments 0112112010 Revision Denison 2.2 1) Figures 1A and lB, Initial Filling Plan, Geosyntec Consultants 2) Figure 2A and 2B, Initial Filling Plan, Details and Sections, Geosyntec Consultants 3) Figure 3A and 3B, Initial Filling Plan, Solution and Slurry Pipeline Routes, Geosyntec Consultants 4) Figure 4A and 4B, Interim Filling Plan, Geosyntec Consultants 5) Figure 5, Leak Detection System Sumps for Cell 4A and 4B, Geosyntec Consultants 6) Figure 6A and 6B, Leak Detection Sump Operating Elevations, Geosyntec Consultants 7) Figure 7, Hydraulic Profile Schematic 8) Cell 4A and Cell 4B Freeboard Calculations 9) Table 1A, Calculated Action leakage Rates for Various Head Conditions, Cell 4A, White Mesa Mill, Blanding, Utah, Geosyntec Consultants 1 0) Table 1 B, Calculated Action leakage Rates for Various Head Conditions, Cel14B, White Mesa Mill, Blanding, Utah, Geosyntec Consultants 11) White Mesa Mill Tailings Management System and Discharge Minimization Technology (DMT) Monitoring Plan. • The most recent, approved version of the DMT Plan is included as Attachment G to this Application. 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GEOMEMBRA~l (IEXTUI<EO) ...-1;~0NE-:- -CUSHION Gt:O':BOU SECTION LEAK DETECTION SYSTEM -SUMP t(T_S, -c8"X~·· RECJltCfJI -t;"X4" Rt:OUC<"Jl -LEAK OOECTIOt-1 S'I".£Tf).l _.-" SCHEOUL.f 40 P\'( -<4" ~ ::iCtltPI.JL.t: "0 PVC .. ''\':\...~--(ji£0S"!TO'!Hl<lC ClAY LINt'H , '-60 MIL 1-101'~ ·~OIJO..IB~.ANE (SijOOTl-1) .... '-CUS);IQ/01 GE018\11U:C LEAK DETECilON sYSTEM SUMP Cel.,l5 AA ANO 48 ~OING, UTAI-I Geosyntecl>l o•.~ ocroeaU.01!l oonsultaDts Pom.Jilel ~Q. SC0049 I'IGU~ 5 1 J:•i" ,. •I •+ I I ,. .... ' o I i i m 11:1 ~ I jl I ~ .J m §1 I 1: I il I I I I I I I I I I i am I m !i I Sl ~~ I I m ~~ I ! I ~ i ----.: i ~ PMP \tCI.l.l\4!; 38.1 N:·fr. PW!.159.40AC•R'fi\ONI CEW • --- 2,3,A~IJ4A 'ttl'TAL !97.50 ~H -::w~ .. FREEiiOARO UMil' 'iS!I" .&l FT. MSL ~ PMP'J,::li.!M€,36AC·FT. PWSl2.UAC.f1'FROM j CEIU.fdiiDCElU --..;:------ lS9.40 ACri'T 0\IERFlOWS'T'O CZlL46 PMP 'lOLLlYI!. 123.-4-Aa-FT ~OWSTOO:U.u IIIOY'TO !iC"ll; tl'm~W~Uc PROFILE SCHEMATIC C&1.L48 l!t.ANDftll6.tS'r.Aiol GeosyntecC> a:II1Sflltlmts Dllf&: OCTOBER':.KI10 PAOJ&<7!'~ SCQ:S49 -7 Geosynt~ Consultants Table 1A Ca!CY.lated Action t.ea.kage Rates for Various Head Conditions cell 4A, White Mesa M1JI Blandtng, Utah Head Above Uner C.kullted Adlan l.•kap Rate System (feet) (plfans/•Cte/ot) s 222.04 -· - -- 1-10 31.4.0 -15 384.58 --1-----20 444.08 -----2S 496.5 --30 543.88 --------35 587.5 ---~ --37 ()04.0 Geos~ntec Consultants Table 18 Calculated Actlo.n Leakage .Rates for Varlous Head Conditions CeU 48, White Mesa Mill Blanding, Utah Head Above Uner System C.Jculated Actfon lealc111e Rate (feet) (pllanJ/Icte/dayJ 5 211.4 ----·-10 317.0 -15 369.9 20 422.7 25 475.6 ~-------30 528.4 ~-------35 570.0 -------= 37 581.2 Appendix G Stomzwater Best Management Practices Plan, Revision 1.5: September 2012 STORMWATER BEST MANAGEMENT PRACTICES PLAN for White Mesa Uranium Mill 6425 South Highway 191 P.O.Box809 Blanding, Utah September 2012 Prepared by: Energy Fuels Resources (USA) Inc. 1050 17th Street, Suite 950 Denver, CO 80265 TABLE OF CONTENTS Best Management Practices Plan Revision 1.5: September 2012 1.0 INTRODUCTION/PURPOSE ................................................................................................................................ 2 2.0 SCOPE ................................................................................................................................................................... 3 3.0 RESPONSIBILIT¥ ................................................................................................................................................ 4 4.0 BEST MANAGEMENT PRACTICES .................................................................................................................. S 4.1 General Management Practices Applicable to All Areas ......................................................................... S 4.1.1 Keep Potential Pollutants from Contact with Soil, and Surface Water: .............................................. 5 4.1.2 Keep Potential Pollutants from Contact with Precipitation .............................................................. 5 4.1.3 Keep Paved Areas from Becoming Pollutant Sources ...................................................................... 5 4.1.4 Inspection and Maintenance of Diversion Ditches and Drainage Channels within the Process and Reagent Storage Area .................................................................................................................. 5 4.1.5 Recycle Fluids Whenever Possible: .................................................................................................. 5 4.2 Management Practices for Process and Laboratory Areas ....................................................................... 6 4.2.1 Clean Up Spills Properly .................................................................................................................. 6 4.2.2 Protect Materials Stored Outdoors .................................................................................................... 6 4.2.3 Management ..................................................................................................................................... 6 4.2.4 Materials Management ..................................................................................................................... 6 4.3 Management Practices for Maintenance Activities .................................................................................. 7 4.3.1 Keep a Clean Dry Shop .................................................................................................................... 7 4.3.2 Manage Vehicle Fluids ..................................................................................................................... 7 4.3.3 Use Controls During Paint Removal ................................................................................................ 7 4.3.4 Use Controls During Paint Application and Cleanup ....................................................................... 7 4.4 Management Practices for Ore Pad, Tailings Area, and Heavy Equipment ............................................ 8 4.4.1 Wash Down Vehicles and Equipment in Proper Areas .................................................................... 8 4.4.2 Manage Stockpiles to Prevent Windbome Contamination ............................................................... 8 4.4.3 Keep Earthmoving Activities from Becoming Pollutant Sources .................................................... 8 Figures Figure 1: White Mesa Mill Site Layout ...................................................................................................................... 17 Figure2: White Mesa Mill Site Drainage Basins ........................................................................................................ 18 Figure 3: Energy Fuels Resources (USA) Inc.-White Mesa Mill Management Organization Chart ........................ 20 Figure 4: Energy Fuels Resources (USA) Inc. -Corporate Management Organizational Chart ............................... 22 Tables TABLE 1.0: White Mesa Mill Management Personnel Responsible for Implementing This BMPP ........................ 10 TABLE 2.0: REAGENT YARD LIST ....................................................................................................................... ll TABLE 3.0: LABORATORY CHEMICAL INVENTORY LIST 1 .......................................................................... 12 TABLE 4.0: REAGENT YARD/SMALL QUANTITY CHEMICALS LIST 1 ........................................................ 13 TABLE 5.0: EAGENT YARD/BULK CHEMICALS LIST 1 ................................................................................... 14 TABLE 6.0: PETROLEUM PRODUCTS AND SOLVENTS LIST 1 ...................................................................... 15 Page 1 1.0 INTRODUCTION/PURPOSE Best Management Practices Plan Revision 1.5: September 2012 Energy Fuels Resources (USA) Inc. ("EFR") operates the White Mesa Uranium Mill ("the Mill) in Blanding, Utah. The Mill is a net water consumer, and is a zero-discharge facility with respect to water effluents. That is, no water leaves the Mill site because the Mill has: • no outfalls to public stormwater systems, • no surface runoff to public stormwater systems, • no discharges to publicly owned treatment works ("POTWs"), and • no discharges to surface water bodies. The State of Utah issued Groundwater Discharge Permit No. UGW370004 to EFRon March 8, 2005. As a part of compliance with the Permit, EFR is required to submit a Stormwater Best Management Practices Plan ("BMPP") to the Executive Secretary of the Division of Radiation Control, Utah Department of Environmental Quality. This BMPP presents operational and management practices to minimize or prevent spills of chemicals or hazardous materials, which could result in contaminated surface water effluents potentially impacting surface waters or ground waters through runoff or discharge connections to storm water or surface water drainage routes. Although the Mill, by design, cannot directly impact stormwater, surface water, or groundwater, the Mill implements these practices in a good faith effort to minimize all sources of pollution at the site. Page 2 2.0 SCOPE Best Management Practices Plan Revision 1.5: September 2012 This BMPP identifies practices to prevent spills of chemicals and hazardous materials used in process operations, laboratory operations, and maintenance activities, and minimize spread of particulates from stockpiles and tailings management areas at the Mill. Storage of ores and alternate feeds on the ore pad, and containment of tailings in the Mill tailings impoundment system are not considered "spills" for the purposes of this BMPP. The Mill site was constructed with an overall grade and diversion ditch system designed to channel all surface runoff, including precipitation equivalent to a Probable Maximum Precipitation/Probable Maximum Flood ("PMP/PMF") storm event, to the tailings management system. In addition, Mill tailings, all other process effluents, all solid waste and debris (except used oil and recyclable materials), and spilled materials that cannot be recovered for reuse are transferred to one or more of the tailings cells in accordance with the Mill's NRC license conditions. All of the process and laboratory building sinks, sumps, and floor drains are tied to the transfer lines to the tailings impoundments. A site map of the Mill is provided in Figure I. A sketch of the site drainage basins is provided in Figure 2. As a result, unlike other industrial facilities, whose spill management programs focus on minimizing the introduction of chemical and solid waste and wastewater into the process sewers and storm drains, the Mill is permitted by NRC license to manage some spills via draining or wash down to the process sewers, and ultimately the tailings system. However, as good environmental management practice, the Mill attempts to minimize: 1. the number and size of material spills, and 2. the amount of unrecovered spilled material and wash water that enters the process sewers after a spill cleanup. Section 4.0 itemizes the practices in place at the Mill to meet these objectives. This BMPP addresses the management of storm water, and the prevention of spills of chemicals and hazardous materials, at the Mill site. Detailed requirements and methods for management, recordkeeping, and documentation of hazardous material spills are addressed separately in the EFR White Mesa Mill Spill Prevention, Control and Countermeasures ("SPCC") Plan, the Emergency Response Plan ("ERP"), and the housekeeping procedures incorporated in the White Mesa Mill Standard Operating Procedures ("SOPs"). Page 3 3.0 RESPONSIDILITY Best Management Practices Plan Revision 1.5: September 2012 All Mill personnel are responsible for implementation of the practices in this BMPP. EFR White Mesa Mill management is responsible for providing the facilities or equipment necessary to implement the practices in this BMPP. The Mill Management Organization is presented in Figure 3. The EFR Corporate Management Organization is presented in Figure 4. An updated spill prevention and control notification list is provided in Table 1. Page4 Best Management Practices Plan Revision 1.5: September 2012 4.0 BEST MANAGEMENT PRACTICES A summary list and inventory of all liquid and solid materials managed at the Mill is provided in Tables 2 through 5. 4.1 General Management Practices Applicable to All Areas 4.1.1 Keep Potential Pollutants from Contact with Soil, and Surface Water: • Store hazardous materials and other potential pollutants in appropriate containers. • Label the containers. • Keep the containers covered when not in use. 4.1.2 Keep Potential Pollutants from Contact with Precipitation • Store bulk materials in covered tanks or drums. • Store jars, bottle, or similar small containers in buildings or under covered areas. • Replace or repair broken dumpsters and bins. • Keep dumpster lids and large container covers closed when not in use (to keep precipitation out). 4.1.3 Keep Paved Areas from Becoming Pollutant Sources • Sweep paved areas regularly, and dispose of debris in the solid waste dumpsters or tailings area as appropriate. 4.1.4 Inspection and Maintenance of Diversion Ditches and Drainage Channels within the Process and Reagent Storage Area • Diversion ditches, drainage channels and surface water control structures in and around the Mill area will be inspected at least monthly in accordance with the regularly scheduled inspections required by Groundwater Discharge Permit No. UGW370004, and by product Materials License #UT1900479. Areas requiring maintenance or repair, such as excessive vegetative growth, channel erosion or pooling of surface water runoff, will be reported to site management and maintenance departments for necessary action to repair damage or perform reconstruction in order for the control feature to perform as intended. Status of maintenance or repairs will be documented during follow up inspections and additional action taken if necessary. 4.1.5 Recycle Fluids Whenever Possible: • When possible, select automotive fluids, solvents, and cleaners that can be recycled or reclaimed • When possible, select consumable materials from suppliers who will reclaim empty containers. • Keep spent fluids in properly labeled, covered containers until they are picked up for recycle or transferred to the tailings area for disposal. PageS Best Management Practices Plan Revision 1.5: September 2012 4.2 Management Practices for Process and Laboratory Areas 4.2.1 Clean Up Spills Properly • Clean up spills with dry cleanup methods (absorbents, sweeping, collection drums) instead of water whenever possible. • Clean spills of stored reagents or other chemicals immediately after discovery. • (Groundwater Discharge Permit No. UGW370004, Section I.D.l O.c.) • Recover and re-use spilled material whenever possible. • Keep supplies of rags, sorbent materials (such as cat litter), spill collection drums, and personnel protective equipment ("PPE") near the areas where they may be needed for spill response. • If spills must be washed down, use the minimum amount of water needed for effective cleanup. 4.2.2 Protect Materials Stored Outdoors • If drummed feeds or products must be stored outdoors, store them in covered or diked areas when possible. • If drummed chemicals must be stored outdoors, store them in covered or diked areas when possible. • Make sure drums and containers stored outdoors are in good condition and secured against wind or leakage. Place any damaged containers into an overpack drum or second container. 4.2.3 Management • When possible, recycle and reuse water from flushing and pressure testing equipment. When possible, wipe down the outsides of containers instead of rinsing them off in the sink. • When possible, wipe down counters and work surfaces instead of hosing or rinsing them off to sinks and drain 4.2.4 Materials Management • Purchase and inventory the smallest amount of laboratory reagent necessary. • Do not stock more of a reagent than will be used up before its expiration date. • All new construction of reagent storage facilities will include secondary containment which shall control and prevent any contact of spilled reagents, or otherwise released • reagent or product, with the ground surface. (Groundwater Discharge Permit No. • UGW370004, Section I.D.3.g.) Page 6 Best Management Practices Plan Revision 1.5: September 2012 4.3 Management Practices for Maintenance Activities 4.3.1 Keep a Clean Dry Shop • Sweep or vacuum shop floors regularly. • Designate specific areas indoors for parts cleaning, and use cleaners and solvents only in those areas. • Clean up spills promptly. Don't let minor spills spread. • Keep supplies of rags, collection containers, and sorbent material near each work area where they are needed. • Store bulk fluids, waste fluids, and batteries in an area with secondary containment (double drum, drip pan) to capture leakage and contain spills. 4.3.2 Manage Vehicle Fluids • Drain fluids from leaking or wrecked/damaged vehicles and equipment as soon as possible. Use drip pans or plastic tarps to prevent spillage and spread of fluids . • Promptly contain and transfer drained fluids to appropriate storage area for reuse, recycle, or disposal. • Recycle automotive fluids, if possible, when their useful life is finished. 4.3.3 Use Controls During Paint Removal • Use drop cloths and sheeting to prevent windborne contamination from paint chips and sandblasting dust. • Collect, contain, and transfer, as soon as possible, accumulated dusts and paint chips to a disposal location in the tailings area authorized to accept waste materials from maintenance or construction activities. 4.3.4 Use Controls During Paint Application and Cleanup • Mix and use the right amount of paint for the job. Use up one container before opening a second one. • Recycle or reuse leftover paint whenever possible. • Never clean brushes or rinse or drain paint containers on the ground (paved or unpaved). • Clean brushes and containers only at sinks and stations that drain to the process sewer to the tailings system. • Paint out brushes to the extent possible before water washing (water-based paint) or solvent rinsing (oil-based paint). • Filter and reuse thinners and solvent whenever possible). Contain solids and unusable excess liquids for transfer to the tailings area Page 7 Best Management Practices Plan Revision 1.5: September 2012 4.4 Management Practices for Ore Pad, Tailings Area, and Heavy Equipment Detailed instructions for ore unloading, dust suppression, and tailings management are provided in the Mill SOPs. 4.4.1 Wash Down Vehicles and Equipment in Proper Areas • Wash down trucks, trailers, and other heavy equipment only in areas designated for this purpose (such as wash down pad areas and tile truck wash station). • At the truck wash station, make sure the water collection and recycling system is working before turning on water sprays. 4.4.2 Manage Stockpiles to Prevent Wind borne Contamination • Water spray the ore pad and unpaved areas at appropriate frequency in accordance with Mill SOPs. • Water spray stockpiles as required by opacity standards or weather conditions. • Don't over-water. Keep surfaces moist but minimize runoff water. 4.4.3 Keep Earthmoving Activities from Becoming Pollutant Sources • Schedule excavation, grading, and other earthmoving activities when extreme dryness and high winds will not be a factor (to prevent the need for excessive dust suppression). • Remove existing vegetation only when absolutely necessary. • Seed or plant temporary vegetation for erosion control on slopes. Page 8 TABLES Page 9 Personnel Dan Hillsten Wade Hancock Scot Christensen David E. Turk Garrin Palmer Personnel Stephen P. Antony, Harold R. Roberts David C. Frydenlund Jo Ann Tischler TABLE 1 White Mesa Mill Management Personnel Responsible for Implementing This BMPP Mill Staff Title Work Phone Mill Manager 435-678-4105 Maintenance 435-678-4166 Superintendent Mill Superintendent 435-678-2221 Manager, Environment, 435-678-4113 Health and Safety Mill Environmental Compliance Coordinator 435-678-4115 Corporate Management Staff Title Work Phone President and Chief 303-974-2142 Operating Officer Executive Vice 303-389-4160 President and Chief Operating Officer Sr. Vice President 303-389-4130 Regulatory Affairs and General Counsel Director; Compliance 303-389-4132 Home Phone/ Other Contact Number Cell: 435-979-3041 435-678-2753 Cell: 435-979-0410 435-678-2015 435-678-7802 Cell: 435-459-9786 CeU: 435-459-9463 Home Phone/ OtJter Contact Number Cell: 303-378-8254 Cell: 303-902-2870 303-221-0098 Cell: 303-808-6648 Cell: 303-501-9226 Page 10 REAGEN'T .. - AMMONIUM SULFATE(BULK) AMMONIUM SULFATE(BAGS) ANHYDROUS AMMONIA TRIDECYLALCOHOL DIESEL FUEL GRINDING BALLS KEROSENE POL OX PROPANE SALT (BAGS) SALT (BULK) SODA ASH (BAGS) SODA ASH (BULK) SODIUM CHLORATE SODIUM HYDROXIDE SULFURIC ACID UNLEADED GASOLINE USED OIL TABLE 2 REAGENT YARD LIST QIJANTI:rY NUMBER: eJF' (~BS)-· ~sr®~GE TANKS · ---~· ' . 54,000 2 26,000 - 107,920 2 45,430 --- 2 1 72,000 --- 1,344 1 2 10,360 --- 1 39,280 -- 0 1 1 39,280 --- 84,100 1 1 101,128 1 1 1 0 1 4,801,440 1 1 1 1-.~ARACIT't -,_ ~'G~[(f>NS} .. . . ' 24,366 31,409 250 6,000 10,315 10,095 25,589 13,763 18,864 16,921 8,530 16,921 22,561 29,940 19,905 1,394,439 3,000 5,000 Page 11 TABLE 3.0 LABORATORY CHEMICAL INVENTORY LIST 1 Chemical In Lab R~ Quantitv in Stock Aluminum nitrate 2270 kg 1.8 kg Ammonium bifluoride 45.4 kg 2.27 kg Ammonium chloride 2270 kg 2.27 kg Ammonium oxalate 2270 kg 6.8 kg Ammonium thiocyanate 2270 kg 7.8 kg Antimony potassium tatrate 45.4 kg 0.454 ' n-8utyl acetate 2270 kg 4L Cyclohexane 454 kg 24 L Ferric chloride 454 kg 6.81 kg Ferrous ammonium sulfate 454 kg 0.57 Potassium chromate 4.54 kg 0.114kg Sodium nitrite 45.4 kg 2.5 kg Sodium phosphate tribasic 2270kg 1.4 Zinc acetate 454 kg 0.91 kg Chemical. in Volatiles and RQ" Quantit)f in Stock Flammables Lockers fA.BCl Chloroform 4.54 kg 8L Formaldehyde 45.4 kg <1 L of 37% solution Nitrobenzene 454 kg 12 L Toluene 454 kg 12 L Chemical in Acid Shed RQ" Quantity in Stock Chloroform 4.54 kg 55 gal Hydrochloric acid 2,270 kg 58 gal Nitrate acid 454 kg 5L Phosphoric Acid 2,270 kg 10 L Sulfuric acid 454 kg 25 L Hydrofluoric acid 45.4 kg 1 L Ammonium hydroxide 454 kg 18 L 1. This list identifies chemicals which are regulated as hazardous substances under the Federal Water Pollution Control Act 40 CFR Part 117. The lab also stores small quantities of other materials that are not hazardous substances per the above regulation. 2. Reportable Quantities are those identified in 40 CFR Part 117 Table 117.3: "Reportable Quantities of Hazardous Substances Designated Pursuant to Section 311 of the Clean Water Act." Page 12 TABLE 4.0 REAGENT YARD/SMALL QUANTITY CHEMICALS LIST 1 CHEMICAL B.Q: " ·QUA.TYIN --. I _, sto . _ "<3'~ ' .. .c'tJ Ml?aLitfD, - Acetic Acid .. GlaciaJ 1.000 lbs 4gal Ammonium Hydroxide 1,000 lbs 5L Calcium Hypochlorite 10 lbs 2 kg (4.4 lbs) Chlorine 10 lbs Olbs Ferrous Sulfate Heptahydrate 1 000 lbs 5 kg (111bs) Hydrochloric 5,000 lbs 60 gal of 40% solution Nitric Acid 1,000 lbs 10 L Potassium Permanganate 0.1 N 32 gal 5 kg (111bs} Sodium Hypochlorite 5.5% 1001bs 2 kg (11 lbs) of 5.5% solution Silver Nitrate 1 lb Olbs Trichloroethylene 1001b 2L 1. This list identifies chemicals which are regulated as hazardous substances under the Federal Water Pollution Control Act 40 CFR Part 117, Materials in this list are stored in a locked storage compound near the bulk storage tank area. The Mill also stores small quantities of other materials that are not hazardous substances per the above regulation. 2. Reportable Quantities are those identified in40 CFR Part 117 Table 117.3: "Reportable Quantities of Hazardous Substances Designated Pursuant to Section 311 of the Clean Water Act." Page 13 TABLE 5.0 REAGENT YARD/BULK CHEMICALS LIST1 REAGENT RQ' QUANTITY IN REAGENT YARD Sulfuric Acid 1,000 lbs 9,000,000 lbs Hyperfloc 1 02 None 1,500 lbs Ammonia -East Tank 1001bs Olbs Ammonia-West Tank 1001bs 105,000 lbs Kerosene 100 gal 500 gal Salt (Bags) None 20,000 lbs Soda Ash Dense (Bag) None 50,000 lbs Polyox None 490 lbs Tributyl phosphate None 9,450 lbs Diesel 100 gal Approx. 3300 gal Gasoline 100 gal Approx. 6000 gal Alamine 336 drums None 8,250 gal Salt( Bulk Solids) None 50,000 lbs Salt(Bulk Solutions) None 9,000 gal Caustic Soda I 1,000 lbs 16,000 lbs Ammonium Sulfate None 150,000 lbs Sodium Chlorate None 350,000 lbs Alamine 310 Bulk None 0 lbs lsodecanol None 2,420 gal Vanadium Pentoxide3 10001bs 30,000 lbs Yellowcake3 None <1 00,000 lbs Ammonia Meta Vanadate 10001bs Olbs Floc 655 21,000 lbs Floc 712 1,250 lbs 1. This list identifies all chemicals in the reagent yard whether or not they are regulated as hazardous substances under the Federal Water Pollution Control Act 40 CFR Part 117. 2. Reportable Quantities are those identified in 40 CFR Part 117 Table 117.3: "Reportable Quantities of Hazardous Substances Designated Pursuant to Section 311 of the Clean Water Act." 3. Vanadium Pentoxide and Yellowcake, the Mill's products, are not stored in the Reagent Yard itself, but are present in closed containers in the Mill Building and/or Mill Yard Page 14 TABLE 6.0 PETROLEUM PRODUCTS AND SOLVENTS LIST1 PRODUCT BQ QUANTITY IN WAREHOUSE Lubricating Oils in 55 gallon drums 100 gal 1 ,540 gallons Transmission Oils 100 gal 110 gallons Water Soluble Oils 100 gal 110 gallons Xylene (mixed isomers) 100 gal 0 gallons Toluene 1000 gal 0 gallons Varsol Solvent 100 gal 0 gallons (2% trimethyl benzene in petroleum distillates) 1. This list includes all solvents and petroleum-based products in the Mill warehouse petroleum and chemical storage aisles. 2. Reportable Quantities are those identified in 40 CFR Part 117 Table 117.3: "Reportable Quantities of Hazardous Substances Designated Pursuant to Section 311 of the Clean Water Act." Page 15 FIGURES Page 16 Figure 1 White Mesa Mill Mill Site Layout Page 17 Figure 2 White Mesa Mill Mill Site Drainage Basins Page 18 I I 00000 o o~o D o 0oo ALTERNATE FEED CIRCUIT • DRY REAGENT STORAGE c:::l REAGENT YARD ~ SUBSTATION sx BUILDING • .. OQwATER TANK Cl:1 GRIZZLY 0 OLD DECONTAMINATION f:::::::JPAD 0 0 PROCESS WATER 0 0 • VPL STORAGE 11 o· o· • oO 0 1 SODIUM CHLORATE D 0 SHOP .. ORE PAD SAMPLE PLANT I D TOPSOIL (, '\J I t r a: t ~ z :::> 0 lXI iZ a: <C 0 ~ w 1-~ e: en w a: f I -..::::::::=, X )( 100 50 100 SCALE IN FEET Energy Fuels Resources . (USA) Inc. . •. rojocl. White Mesa Mill SanJuan l!l! UT MILL SITE bAY OUT FIGURE 1 ~ CELL4B DRAINAGE BASIN •p 44.67 AC. PMF CONTAINED WITHIN BASIN 1000 0 1000 ~ DRAINAGE BASI 42.14AC. 1 Sufrace Water Flow Drainage Basins Diversion Ditches Diversion Berm l "' Energy Fuels Resources (USA) Inc. 05/1 eJOe f!M 06111/08 BM 1219108 DLS ln/08 11M '"'"~< 11 r.u I "'1dnor HRR White Mesa Mill ;uue: Ul MILL SITE DRAINAGE BASINS FIGURE 2 Qlle 200!5 l)(o.m<lo Oy Figure 3 White Mesa Mill Mill Management Organization Chart Page 19 Sr. VP Regulatory Affairs & General •;. ~ 1•~'\o Figure3 Energy Fuels Resources (USA) Inc. White Mesa Mill Management Organizational Structure ""l",i- President & CEO Executive VP and Chief Operating Officer Mill Manager 'tl -----------------------,---t-·-~-~-----·----~----,--•----------------r--~---------------- Mill Radiation Safety Officer 11 ~' 1 I Mill .. : Mill Operations Personnel ~ I ~ I Figure 4 Wbite Mesa Mill Energy Fuels Resources (USA) Inc. Organizational Structure Page 22 Figure 4 Energy Fuels Resources (USA) Inc. Organizational Structure ~~ President & CEO Sr. VP Regulatory Affairs & General Counsel Director, Compliance Executive VP and Chief Operating Officer ;(, '" II ·~!El'~&::iJ'i4~t£)i)@t(;-•N· .. ~:. ...... ~, Mill Manager Manager, Environmental, Health, and Safety Appendix H White Mesa Mill Discharge Minimization Technology (DMT) Monitoring Plan, 7/2012, Revision: Denison-12.1 WHITE MESA MILL DISCHARGE MINIMIZATION TECHNOLOGY (DMT) MONITORING PLAN Revision 12.1 July 2012 Prepared by: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver, CO 80265 White Mesa Mill-Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denisonl2.1 Page 2 of26 WHITE MESA MILL DISCHARGE MINIMIZATION TECHNOLOGY (DMT) MONITORING PLAN TABLE OF CONTENTS 1. INTRODUCTION .................................................................................................................. 3 1.1. Background ...................................................................................................................... 3 2. DAILY TAILINGS INSPECTIONS ...................................................................................... 4 2.1. Daily Inspection ............................................................................................................... 4 3. WEEKLY TAILINGS AND DMT INSPECTION ................................................................ 5 3 .1. Weekly Tailings Inspections ............................................................................................ 5 Northing .................................................................................................................................. 9 Easting ..................................................................................................................................... 9 3.2. Weekly Inspection of Solution Levels in Roberts Pond ................................................ 12 3.3. Weekly Feedstock Storage Area Inspections ................................................................. 12 4. ANNUAL EVALUATIONS ................................................................................................. 12 4.1. Freeboard Limits ............................................................................................................. 13 4.1.1. RobertsPond ........................................................................................................... 13 4.2. Annual Leak Detection Fluid Samples ........................................................................... 13 4.3. Annual Inspection of the Decontamination Pads ........................................................... 13 4.4. Annual Inspection of the Ammonium Sulfate Pad ......................................................... 14 5. OTHER INSPECTIONS ....................................................................................................... 14 6. REPORTING REQUIREMENTS ......................................................................................... 14 6.1. DMT Reports .................................................................................................................. 14 Attachment A Attachment B Attachment C ATTACHMENTS Forms Feedstock Storage Area Tables N:\DMT Plan\DMT Plan 06.2012 Revision 12. I \DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan 1. INTRODUCTION 7/12 Revision: Denisonl2.1 Page 3 of26 This DMT Monitoring Plan ("DMT Plan") sets out the procedures to demonstrate compliance with Discharge Minimization Technology ("DMT") as specified throughout Parts I.D, I.E and I.F of the White Mesa Mill's (the "Mill's") Groundwater Discharge Permit ("GWDP") Number 370004. Additional procedures for monitoring the tailings cell systems as required under State of Utah Radioactive Materials License No. UT19004 79 (the "RML ") are set out in the Tailings Management System procedure for the Mill, which comprises Chapter 3.1 of the Mill's Environmental Protection Manual. This DMT Plan and the Tailings Management System procedure when implemented in concert are designed as a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system including dike stability, liner integrity, and transport systems, as well as monitoring of water levels in Roberts Pond and feedstock storage areas at the Mill. This DMT Plan is issued as a stand-alone document, while the Tailings Management System procedure is published and maintained in the Mill's Environmental Protection Manual. 1.1. Background The Tailings Management System procedure was originally developed as Chapter 3.1 of the Mill's Environmental Protection Manual, under the Mill's NRC Source Material License, and constituted a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system. Upon the State of Utah becoming an Agreement State for uranium mills in 2004, the Mill's Source Material License was replaced by the State of Utah RML and the State of Utah GWDP. The GWDP required that Denison develop the initial DMT Plan in response to GWDP requirements. In developing the initial DMT Plan, Denison combined the existing Tailings Management System procedure set out as Chapter 3 .1 of the Mill's Environmental Protection Manual with a number of new DMT requirements from the GWDP to form the initial DMT Plan. The initial DMT Plan and subsequent revisions (through revision 11.5) maintained the requirements from the RML (i.e., Chapter 3.1 of the Mill's Environmental Protection Manual) and the DMT requirements of the GWDP in a single document. However, after several years of implementing the DMT Plan, Denison concluded that it is preferable to separate the RML portions of the DMT Plan from the GWDP portions of the DMT Plan, into two separate documents. This DMT Plan continues to be a stand-alone plan that contains the DMT requirements from the GWDP except for the daily recording of the Cells 1, 2, and 3 LDS measurements as noted below. However, the portions of the initial DMT Plan that flowed from the RML and not from the GWDP have been separated from the DMT Plan and have been returned to N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill -Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denisonl2.1 Page 4 of26 their original status as the Tailings Management System procedure, which comprises Chapter 3.1 of the Mill's Environmental Protection Manual. This allows the DMT Plan to be managed, inspected and enforced under the requirements of the G WDP and this Tailings Management System procedure to be managed, inspected and enforced under the requirements of the RML. This division of the requirements was discussed with DRC on October 26,2011. DRC agreed with the division of the requirements into two distinct documents as noted in their correspondence dated December 20, 2011. Pursuant to a written request from DRC, dated May 30, 2012, the RML requirements for the inspections of the Cells 1, 2, and 3 Leak Detection Systems ("LDSs") has been included in this DMT Plan. The inclusion of this RML requirement into this DMT Plan is to address the DRC request for uniformity in monitoring and reporting requirements for Cells 1, 2, and 3 and to address anticipated GWDP modifications regarding the LOS monitoring in Cells 1, 2, and 3. 2. DAILY TAILINGS INSPECTIONS The following daily tailings inspections shall be performed: 2.1. Daily Inspection On a daily basis, including weekends, the Cells 1, 2, 3, 4A, and 4B leak detection systems must be inspected either under the DMT Plan or the Tailings Management System procedure. The Radiation Safety Officer (RSO) or his designee is responsible for performing these daily tailings inspections. The RSO may designate other individuals with training, as described in Section 2.4 below, to perform these inspections. Observations made by the inspector will be recorded on Attachment A to this DMT Plan. The inspector will place a check by all inspection items that appear to be operating properly. Those items where conditions of potential concern are observed should be marked with an "X". A note should accompany the "X" specifying what the concern is and what corrective measures will resolve the problem. This observation of concern should be noted on the form until the problem has been remedied. The date that corrective action was taken should be noted as well. See the Tailings Management System procedure for additional daily inspection requirements. a) Daily measurements in the leak detection system sumps of Cells 1, 2, 3, (as required by the RML) and Cells 4A, and 4B (as required by the GWDP) are recorded. For simplicity, the leak detection system measurements for all cells have been combined on the Daily Inspection Data Form included as Attachment A-1 to this DMT Plan regardless of the origin ofthe requirement. The triggers for further action and the associated actions when evaluating Cells 1, 2, and 3, leak detection systems are discussed in the Tailings Management N :\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan System procedure, Section 2.1 q). 7/12 Revision: Denisonl2.1 Page 5 of26 The solution level in Cell 4A or 4B leak detection system is not allowed to be more than 1.0 foot above the lowest point on the bottom flexible membrane liner (FML) (Cell4A FML elevation is 5555.14 amsl and with the addition of the 1.0 foot of solution the solution elevation is 5556.14 feet amsl. For Cell4B the FML elevation is 5557.50 amsl and with the addition of the 1.0 foot of solution the solution elevation is 5558.50 feet amsl). If any of these observations are made, the Mill Manager should be notified immediately and the leak detection system pump started. In addition, the requirement to notify the Executive Secretary in accordance with Parts I.D.6 and I.G.3 of the Groundwater Discharge Pennitmust be adhered to when the solution level trigger for Cell 4A or 4B has been exceeded. 3. WEEKLY TAILINGS AND DMT INSPECTION 3.1. Weekly Tailings Inspections Weekly tailings inspections are to be conducted by the RSO or his designee and include the following: a) Leak Detection Systems Each tailings cell's LDS shall be checked weekly (as well as daily) to determine whether it is wet or dry. If marked wet, the liquid levels need to be measured and reported. In Cells 1, 2, and 3 the LDS is measured by use of a dual probe system that senses the presence of solutions in the LDS (comparable to the systems in Cell4A and Cell4B) and indicates the presence of solution with a warning light. The Cell4A and 4B leak detection systems are monitored on a continuous basis by use of a pressure transducer that feeds water level information to an electronic data collector. The pressure transducer is calibrated for fluid with a specific gravity of 1.0. The water levels are measured every hour and the information is stored for later retrieval. The water levels are measured to the nearest 0.10 inch. The data collector is currently programmed to store 7 days of water level information. The number of days of stored data can be increased beyond 7 days if needed. For Cells 1, 2, and 3, the water level data is recorded on the Daily Tailings Inspection Form included as Attachment A-1 of this DMT Plan. For Cells 4A and 4B, the water level data is downloaded to a laptop computer periodically and incorporated into the Mill's environmental monitoring data storage. The data are reviewed during the weekly inspections of the tailings cell leak detection systems. N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan 7112 Revision: Denisonl2.1 Page 6 of26 If an LDS monitoring system becomes inoperable, alternate methods for LDS fluid measurements may be employed with Executive Secretary approval. If sufficient fluid is present in the leak detection system of any cell, the fluid shall be pumped from the LDS, to the extent reasonably possible, and record the volume of fluid recovered. Any fluid pumped from an LDS shall be returned to a disposal cell. For Cells 1, 2, and 3, if fluid is pumped from an LDS, the procedures specified in the Tailings Management System procedure Section 3.1 a) shall be implemented. For Cells 1, 2, and 3, upon the initial pumping of fluid from an LDS, a fluid sample shall be collected and analyzed in accordance with paragraph 11.3C of the RML as described in the Tailings Management System procedure. For Cell4A and 4B, under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower flexible membrane liner. To determine the Maximum Allowable Daily LDS Flow Rates in the Cell 4A and 4B leak detection systems, the total volume of all fluids pumped from the LDS on a weekly basis shall be recovered from the data collector, and that information will be used to calculate an average volume pumped per day. Under no circumstances shall the daily LDS flow volume exceed 24,160 gallons/day for Cell4A or 26,145 gallons/day for Cell4B. The maximum daily LDS flow volume will be compared against the measured cell solution levels detailed on Table lA and lB (for Cells 4A and 4B, respectively) in Attachment C, to determine the maximum daily allowable LDS flow volume for varying head conditions in Cel14A and 4B. b) Slimes Drain Water Level Monitoring (i) Cell 3 is nearly full and will commence closure when filled. Cell 2 is partially reclaimed with the surface covered by platform fill. Each cell has a slimes drain system which aids in dewatering the slimes and sands placed in the cell; (ii) Denison re-graded the interim fill on Cell 2 in order to reduce the potential for the accumulation of storm water on the surface ofCell2. As a result of the re-grading of the interim cover and the placement of an additional 62,000 cubic yards of fill material on Cell 2, the slimes drain access pipe was extended 6.97 feet. The extension pipe is 6.97 feet in length, and therefore the new measuring point is 37.97 feet from the bottom of the slimes drain. The measuring point on the extension pipe was surveyed by a Utah-Certified Land Surveyor. The measuring point elevation is 5618.73 fmsl. For the quarterly recovery test described in section vi below, this extension has no effect on the data measurement procedures. Cell 2 has a pump placed inside of the slimes drain access pipe at the bottom of the N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill -Discharge Minimization Technology Monitoring Plan 7112 Revision: Denisonl2.1 Page 7 of26 slimes drain. As taken from actual measurements, the bottom of the slimes drain is 37.97 feet below a water level measuring point which is a notch on the side ofthe Cell2 slimes drain access pipe .. This means that the bottom of the slimes drain pool and the location of the pump are one foot above the lowest point of the FML in Cell 2, which, based on construction reports, is at a depth of 38.97 feet below the water level measuring point on the slimes drain access pipe for Cell 2; (iii) The slimes drain pump in Cell 2 is activated and deactivated by a float mechanism and water level probe system. When the water level reaches the level of the float mechanism the pump is activated. Pumping then occurs until the water level reaches the lower probe which turns the pump off. The lower probe is located one foot above the bottom of the slimes drain standpipe, and the float valve is located at three feet above the bottom of the slimes drain standpipe. The average wastewater head in the Cell 2 slimes drain is therefore less than 3 feet and is below the phreatic surface of tailings Cell2, about 27 feet below the water level measuring point on the slimes drain access pipe. As a result, there is a continuous flow of wastewater from Cell 2 into the slimes drain collection system. Mill management considers that the average allowable wastewater head in the Cell 2 slimes drain resulting from pumping in this manner is satisfactory and is as low as reasonably achievable. (iv)All head measurements must be made from the same measuring point (the notch at the north side ofthe access pipe 5618.73 fmsl), and made to the nearest 0.01 foot. The equation specified in the GWDP will be used to calculate the slimes drain recovery elevation (SDRE). To calculate the SDRE contemplated by the GWDP, the depth to wastewater in the Cell2 slimes drain access pipe (in feet) will be subtracted from the surveyed elevation of the measuring point. The calculation is as follows: 5618.73-Depth to wastewater in the Cell2 slimes drain access pipe= SDRE (v) Effective July 11,2011, on a quarterly basis, the slimes drain pump will be turned off and the wastewater in the slimes drain access pipe will be allowed to stabilize for at least 90 hours. Once the water level has stabilized (based on no change in water level for three (3) successive readings taken no less than one (1) hour apart) the water level of the wastewater will be measured and recorded as a depth-in-pipe measurement on Quarterly Data form, by measuring the depth to water below the water level measuring point on the slimes drain access pipe; (vi)No process liquids shall be allowed to be discharged into Cell2; ( vii)If at any time the most recent average annual head in the Cell2 slimes drain is found to have increased above the average head for the previous calendar year, the Licensee will comply with the requirements of Part I.G.3 of the GWDP, including the requirement to provide notification to the Executive Secretary orally within 24 hours followed by written notification; (viii) Because Cell3, Cell4A, and 4B are currently active, no pumping from the Cell3, Cell4A, or 4B slimes drain is authorized. Prior to initiation of tailings dewatering operations for Cell3, Cell4A, or Cell4B, a similar procedure will be developed for N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill -Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denisonl2.1 Page 8 of26 ensuring that average head elevations in the Cell3, Cell4A, and 4B slimes drains are kept as low as reasonably achievable, and that the Cell 3, Cell 4A, and Cell 4B slimes drains are inspected and the results reported in accordance with the requirements of the permit. c) Tailings Wastewater Pool Elevation Monitoring Solution elevation measurements in Cells 1, 4A, and 4B and Roberts Pond are to be taken by survey on a weekly basis. The beach area in Cell 4B with the maximum elevation is to be taken by survey on a monthly basis when beaches are first observed, as follows: (i) The survey will be performed by the Mill's Radiation Safety Officer or designee (the "Surveyor") with the assistance of another Mill worker (the "Assistant"); (ii) The survey will be performed using a survey instrument (the "Survey Instrument") accurate to 0.01 feet, such as a Sokkai No. B21, or equivalent, together with a survey rod (the "Survey Rod") having a visible scale in 0.01 foot increments; (iii) The Reference Points for Cells 1, Cell 4A, and 4B, and Roberts Pond are known points established by professional survey. For Celli and Roberts Pond, the Reference Point is a wooden stake with a metal disk on it located on the southeast comer of Cell 1. The elevation of the metal disk (the "Reference Point Elevation") for Celli and Roberts Pond is at 5,623.14 feet above mean sea level ("FMSL"). For Cell4A and 4B, the Reference Point is a piece of stamped metal monument located next to the transformer on the south side of Cell4A and 4B. The elevation at the top of this piece ofrebar (the Reference Point Elevation for Cell4A and 4B) is 5600.49 fmsl. The Surveyor will set up the Survey Instrument in a location where both the applicable Reference Point and pond surface are visible. (iv)Once in location, the Surveyor will ensure that the Survey Instrument is level by centering the bubble in the level gauge on the Survey Instrument; (v) The Assistant will place the Survey Rod vertically on the Reference Point (on the metal disk on the Celll/Roberts Pond Reference Point on the top ofthe rebar on the Cell4A and 4B Reference Point. The Assistant will ensure that the Survey Rod is vertical by gently rocking the rod back and forth until the Surveyor has established a level reading; (vi) The Surveyor will focus the cross hairs of the Survey Instrument on the scale on the Survey Rod, and record the number (the "Reference Point Reading"), which represents the number of feet the Survey Instrument is reading above the Reference Point; (vii) The Assistant will then move to a designated location where the Survey Rod can be placed on the surface of the main solution pond in the Cell 1, Cell4A, Cell4B, or Roberts Pond, or the area of the beach in Cell4B with the highest elevation, as the case may be. These designated locations, and the methods to be used by the Assistant to consistently use the same locations are as follows: N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill -Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denisonl2.1 Page 9 of26 For a newly-constructed cell, when the cell is first placed into operation, the solution level is typically zero feet above the FML or a minimal elevation above the FML due to natural precipitation. For newly-constructed cells, measurement of solution level will commence within 30 days of authorization for use. Measurements will be conducted as described above in items d) (i) through d) (vii) of this Section consistent with current Mill health and safety procedures. The measurements will be completed using survey equipment and the appropriate length survey rod (either 25' or 45'). A. Pond Surface Measurements I. Cell4A The Assistant will walk down the slope in the northeast comer of Cell 4A and place the Survey Rod at the liquid level. II. Cell4B The Assistant will walk down the slope in the southeast comer of Cell4B and place the Survey Rod at the liquid level. III. Celli A mark has been painted on the north side of the ramp going to the pump platform in Cell 1. The Assistant will place the Survey Rod against that mark and hold the rod vertically, with one end just touching the liquid surface; and IV. Roberts Pond A mark has been painted on the railing of the pump stand in Roberts Pond. The Assistant will place the Survey Rod against that mark and hold the rod vertically, with one end just touching the liquid surface. Based on the foregoing methods, the approximate coordinate locations for the measuring points for Roberts Pond and the Cells are: Northing Easting Roberts Pond 323,041 2,579,697 Celli 322,196 2,579,277 Cell4A 320,300 2,579,360 Cell4B 320,690 2,576,200 N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denisonl2.1 Page 10 of26 B. These coordinate locations may vary somewhat depending on solution elevations in the Pond and Cells; Cell4B Beach Elevation Beach elevations in Cell4B will commence when beaches are first observed. The Assistant will place the Survey Rod at the point on the beach area of Cell 4B that has the highest elevation. If it is not clear which area of the beach has the highest elevation, then multiple points on the beach area will be surveyed until the Surveyor is satisfied that the point on the Cell4B beach area with the highest elevation has been surveyed. If it is clear that all points on the Cell 4B beach area are below 5,593 FMSL, then the Surveyor may rely on one survey point; (i) The Assistant will hold the Survey Rod vertically with one end ofthe Survey Rod just touching the pond surface. The Assistant will ensure that the Survey Rod is vertical by gently rocking the rod back and forth until the Surveyor has established a level reading; (ii) The Surveyor will focus the cross hairs of the Survey Instrument on the scale on the Survey Rod, and record the number (the "Pond Surface Reading"), which represents the number of feet the Survey Instrument is reading above the pond surface level. The Surveyor will calculate the elevation of the pond surface as FSML by adding the Reference Point Reading for the Cell or Roberts Pond, as the case may be, to the Reference Point Elevation for the Cell or Roberts Pond and subtracting the Pond Surface Reading for the Cell or Roberts Pond, and will record the number accurate to 0.01 feet. d) Decontamination Pads (i) New Decontamination Pad The New Decontamination Pad is located in the southeast corner of the ore pad, near the Mill's scale house. A. In order to ensure that the primary containment of the New Decontamination Pad water collection system has not been compromised, and to provide an inspection capability to detect leakage from the primary containment, vertical inspection portals have been installed between the primary and secondary containments; B. These portals will be visually observed on a weekly basis as a means of detecting any leakage from the primary containment into the void between the primary and secondary containment. The depth to water N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean. doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan 7112 Revision: Denisonl2.1 Page 11 of26 in each portal will be measured weekly, by physically measuring the depth to water with an electrical sounding tape/device. All measurements must be made from the same measuring point and be made to the nearest 0.01 foot; C. These inspections will be recorded on the Weekly Tailings Inspection form; D. The water level shall not exceed 0.1 0 foot above the concrete floor in any standpipe, at any time. This will be determined by subtracting the weekly depth to water measurement from the distance from the measuring point in the standpipe to the dry concrete floor The depth to water from the top (elevation 5589.8 feet amsl) of any of the three (3) observation ports to the standing water shall be no less than 6.2 feet. Depths less than 6.2 feet shall indicate more that 0.1 foot of standing water above the concrete floor (elev. 5583.5 feet amsl), and shall indicate a leak in the primary containment. E. Any observation of fluid between the primary and secondary containments will be reported to the Radiation Safety Officer (RSO). F. In addition to inspection of the water levels in the standpipes, the New Decontamination Pad, including the concrete integrity of the exposed surfaces of the pad, will be inspected on a weekly basis. Any soil and debris will be removed from the New Decontamination Pad immediately prior to inspection of the concrete wash pad for cracking. Observations will be made of the current condition of the New Decontamination Pad. Any abnormalities relating to the pad and any damage to the concrete wash surface of the pad will be noted on the Weekly Tailings Inspection form. If there are any cracks greater than 118 inch separation (width), the RSO must be contacted. The RSO will have the responsibility to cease activities and have the cracks repaired. (ii) Existing Decontamination Pad The Existing Decontamination Pad is located between the northwest comer of the Mill's maintenance shop and the ore feeding grizzly. Weekly inspection requirements for the Existing Decontamination Pad are discussed in the Tailings Management System Procedure. e) Summary N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean. doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denison12.1 Page 12 of26 In addition, the weekly inspection should summarize all activities concerning the tailings area for that particular week. Results of the weekly tailings inspection are recorded on the Weekly Tailings and DMT Inspection form. An example of the Weekly Tailings and DMT Inspection form is provided in Appendix A to the Tailings Management System and as Attachment A to this DMT Plan. 3.2. Weekly Inspection of Solution Levels in Roberts Pond On a weekly basis, solution elevations are taken on Roberts Pond, in accordance with the procedures set out in Section 3.1 d) above. The Weekly solution level in Roberts Pond is recorded on the Weekly Tailings and DMT Inspection form. Based on historical observations, the FML at the Pond Surface Reading area for Roberts Pond is approximately six inches above the lowest point on the pond's FML. If the pond solution elevation at the Pond Surface Reading area is at or below the FML for that area, the pond will be recorded as being dry. 3.3. Weekly Feedstock Storage Area Inspections Weekly feedstock storage area inspections will be performed by the Radiation Safety Department to confirm that: a) the bulk feedstock materials are stored and maintained within the defined area described in the GWDP, as indicated on the map attached hereto as Attachment B; b) a 4 ft. buffer is maintained at the periphery of the storage area which is absent bulk material in order to assure that the materials do not encroach upon the boundary of the storage area; and c) all alternate feedstock located outside the defined Feedstock Area are maintained within water tight containers. The results of this inspection will be recorded on the Ore Storage/Sample Plant Weekly Inspection Report, a copy of which is contained in Attachment A. Any variance in stored materials from this requirement or observed leaking alternate feedstock drums or other containers will be brought to the attention of Mill Management and rectified within 15 days. 4. ANNUAL EVALUATIONS The following annual evaluations shall be performed: N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan 4.1. Freeboard Limits 4.1.1. Roberts Pond 7112 Revision: Denisonl2.1 Page 13 of26 The freeboard limit for Roberts Pond is a liquid maximum elevation of5,624.0 feet above mean sea level, as specified in the GWDP. 4.2. Annual Leak Detection Fluid Samples Pursuant to Part I.E.10(c) of the GWDP, a sample will be collected from the Cells 4A and 4B leak detection systems annually as part of the Tailings Cell Wastewater Quality Monitoring. Sampling procedures are described in the Tailings Sampling and Analysis Plan. 4.3. Annual Inspection of the Decontamination Pads a) New Decontamination Pad During the second quarter of each year, the New Decontamination Pad will be taken out of service and inspected to ensure the integrity of the wash pad's exposed concrete surface. If any abnormalities are identified, i.e. cracks in the concrete with greater than 1/8 inch separation (width) or any significant deterioration or damage of the pad surface, repairs will be made prior to resuming the use of the facility. All inspection findings and any repairs required shall be documented on the Annual Decontamination Pad Inspection form. The inspection findings, any repairs required and repairs completed shall be summarized in the 2nd Quarter DMT Monitoring Report due September 1 of each calendar year. b) Existing Decontamination Pad During the second quarter of each year, the Existing Decontamination Pad will be taken out of service and inspected to ensure the integrity of the steel tank. Once the water and any sediment present is removed from the steel tank containment, the walls and bottom of the tank will be visually inspected for any areas of damage, cracks, or bubbling indicating corrosion that may have occurred since the last inspection. If any abnormalities are identified, defects or damage will be reported to Mill management and repairs will be made prior to resuming the use of the facility. All inspection findings and any repairs required shall be documented on the Annual Decontamination Pad Inspection form. A record of the repairs will be maintained as a part of the Annual Inspection records at the Mill site. The inspection findings, any repairs required and repairs completed shall be summarized in the 2nd Quarter DMT Monitoring Report due September 1 of each calendar year. N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan 4.4. Annual Inspection of the Ammonium Sulfate Pad 7/12 Revision: Denison12.1 Page 14 of26 During the second quarter of each year, the Ammonium Sulfate Pad will be inspected to ensure the integrity of the pad's exposed concrete surface. If any abnormalities are identified, i.e. cracks in the concrete with greater than 1/8 inch separation (width) or any significant deterioration or damage of the pad surface, repairs will be made within 7 calendar days of the inspection. All inspection findings and any repairs required shall be documented on the Annual Decontamination Pad/Ammonium Sulfate Pad Inspection form. The in..c;pection frnd ings any repairs req uired an l repairs completed shall be summarized in the 2nd Quarter DJVIT Monitoring Report due eptembcr l of each calendar year. The first inspection of the Ammonium Sulfate Pad will be conducted during the second quarter in the year following installation/completion of the pad. 5. OTHER INSPECTIONS All daily, weekly, monthly, quarterly and annual inspections and evaluations should be performed as specified in this DMT Plan. See also the Tailings Management System procedure included in the EPM for additional inspection requirements. However, additional inspections should be conducted after any significant storm or significant natural or man-made event occurs. 6. REPORTING REQUIREMENTS In addition to the forms included in this DMT Plan, the following additional reports shall also be prepared: 6.1. DMT Reports Quarterly reports ofDMT monitoring activities, which will include the following information, will be provided to the Executive Secretary on the schedule provided in Table 5 of the GWDP: a) On a quarterly basis, all required information required by Part l.F.2 of the GWDP relating to the inspections described in Section 3.1 (a) (Leak Detection Systems Monitoring), Section 3.1 (b) (Slimes Drain Water Level Monitoring), 3.1 (c) (Tailings Wastewater Pool Elevation Monitoring), 3.l(d) (Tailings Wastewater Pool and Beach Area Elevation Monitoring), 3.2 (Weekly Inspection of Solution Levels in Roberts Pond) and 3.3 (Weekly Feedstock Storage Area Inspections); b) On a quarterly basis, a summary of the weekly water level (depth) inspections for the quarter for the presence of fluid in all three vertical inspection portals for each of the three chambers in the concrete settling tank system for the New Decontamination Pad, which will include a table indicating the water level measurements in each portal during the quarter; N:\DMT Plan\DMT Plan 06.2012 Revision 12.1 \DMT Plan July 2012 Rev 12.1 clean. doc White Mesa Mill -Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denison 12.1 Page 15 of26 c) With respect to the annual inspection of the New Decontarrlination Pad described in Section 6.5(a), the inspection findings, any repairs required, and repairs completed shall be summarized in the 2nd Quarter report, due September 1 of each calendar year; d) With respect to the annual inspection of the Existing Decontamination Pad described in Section 6.5(b), the inspection findings, any repairs required, and repairs completed shall be summarized in the 2nd Quarter report, due September 1 of each calendar year; and e) An annual summary and graph for each calendar year of the depth to wastewater in the Cell2 slimes drain must be included in the fourth quarter report. After the first year, and beginning in 2008, quarterly reports shall include both the current year monthly values and a graphic comparison to the previous year. N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan ATTACHMENT A FORMS N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc 7112 Revision: Denison12.l Page 16 of26 White Mesa Mill -Discharge Minimization Technology Monitoring Plan 7/12 Revision: Denisonl2.1 Page 17 of26 Attachment A-1 DAILY INSPECTION DATA Any Item not "OK" must be documented. A check mark= OK, X= Action Required VII. DAILY LEAK DETECTION CHECK Cell 1 Cell2 Cell3 Inspector: _______ _ Date;, ________ _ Accompanied by· .. ____ _ Time: ________ _ Cei14A Cei14B Leak Checked Checked Checked Checked Checked Detection System Wet Dry Wet Dry Wet Dry Wet Dry Wet Checked Initial level Initial level Initial level Initial level Initial level Final Final Final Final Final level level level level level Gal. Gal. Gal. Gal. Gal. pumped pumped .pumped pumped pumped Record Observations of Potential Concern and Actions Required on the Daily Inspection Form included in the Tailings Management System (Appendix A-1) N:\DMT Plan\DMT Plan 06.2012 Revision 12.1 \DMT Plan July 2012 Rev 12.1 clean. doc Dry White Mesa Mill-Discharge Minimization Technology Monitoring Plan 12112 Revision: Denisonl2.2 Page 18 of26 ATTACHMENT A-2 DENISON MINES (USA) CORP. WEEKLY TAILINGS INSPECTION Date: Inspectors: ------------- 1. Pond and Beach elevations Cell 1: (a) Pond Solution Elevation (msl, ft) (b) FML Bottom Elevation 5597. __ _ (c) Depth of Water above FML ((a)-(b)) _____ _ Cell4A: (a)Pond Solution Elevation (b)FML Bottom Elevation 5555.14_ (c)Depth of Water above FML ((a)-(b)) _____ _ Cell 4B: (a)Pond Solution Elevation Roberts (b )FML Bottom Elevation 5557.50 (c)Depth of Water above FML ((a)-(b)) _____ _ (d)Elevation of Beach Area with Highest Elevation (monthly) Pond: (a)Pond Solution Elevation (b )FML Bottom Elevation __ 5612.3_ (c)Depth of Water above FML ((a)-(b)) _____ _ 2. Leak Detection Systems Observation: New Decon Pad, New Decon Pad, New Decon Pad Porta11 Portal2 Portal3 Is LOS (Portal) __ wet __ dry __ wet __ dry __ wet __ dry wet or dry? If wet, Record Ft to Ftto Ftto liquid level: Liquid Liquid Liquid If wet, Report to RSO * Does Level exceed 12 mches above the lowest pomt on the bottom flexible membrane liner (solution elevation of 5556.14 amsl for Cell4A and 5558.50 for Cell4B)? no __ yes If Cell 4A leak detection system level exceeds 12 inches above the lowest point on the bottom flexible membrane liner (elevation 5556.14 amsl), notify supervisor or Mill manager immediately. 3. New Decontamination Pad (concrete): -------------------- White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT A-3 7112 Revision: Denisonl2.1 Page 19 of26 ORE STORAGE/SAMPLE PLANT WEEKLY INSPECTION REPORT Week of ____ through ____ Date oflnspection: _______ _ Inspector:. ___________ _ Weather conditions for the week: Blowing dust conditions for the week: Corrective actions needed or taken for the week: Are all bulk feedstock materials stored in the area indicated on the attached diagram: yes: no: ___ _ comments: __________________________________ _ Are all alternate feedstock materials located outside the area indicated on the attached diagram maintained within water-tight containers: yes: no: __ _ comments (e.g., conditions of containers): _________________ _ Are all sumps and low lying areas free of standing solutions? Yes: No: __ _ If"No", how was the situation corrected, supervisor contacted and correction date? Is there free standing water or water running off of the feedstock stockpiles? Yes: No: ---Comments: ------------------------------------------ N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan Other comments: N:\DMT Plan\DMT Plan 06.2012 Revision 12.1 \DMT Plan July 2012 Rev 12.1 clean. doc 7/12 Revision: Denison12.1 Page 20 of26 White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENT A-4 7/12 Revision: Denisonl2.1 Page 21 of26 ANNUAL DECONTAMINATION/AMMONIUM SULFATE PAD INSPECTION Date oflnspection: _______ _ Inspector: ------------ New Decontamination Pad: Are there any cracks on the wash pad surface greater than 118 inch of separation? Yes No Is there any significant deterioration or damage of the pad surface? __ Yes __ No Findings: Repair Work Required: Existing Decontamination Pad: Were there any observed problems with the steel tank? __ Yes __ No Findings: Repair Work Required: N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc White Mesa Mill-Discharge Minimization Technology Monitoring Plan Ammonium Sulfate Pad: 7/12 Revision: Denison 12.1 Page 22 of26 Are there any cracks on the concrete pad surface greater than 1/8 inch of separation? Yes _No Is there any significant deterioration or damage of the pad surface? __ Yes __ No Findings: Repair Work Required: Note: For the annual inspection of the Existing, New Decontamination Pads and the Ammonium Sulfate Pad, the annual inspection findings, any repairs required, and repairs completed, along with a summary of the weekly inspections of the Decontamination Pads, shall be discussed in the 2nd Quarter report, due September 1 of each calendar year N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean. doc White Mesa Mill -Discharge Minimization Technology Monitoring Plan ATTACHMENTB FEEDSTOCK STORAGE AREA N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc 7/12 Revision: Denisonl2.1 Page 23 of26 White Mesa Mill-Discharge Minimization Technology Monitoring Plan N l N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean. doc 7/12 Revision: Denisonl2. I Page 24 of26 White Mesa Mill-Discharge Minimization Technology Monitoring Plan ATTACHMENT C TABLES N:\DMT Plan\DMT Plan 06.2012 Revision 12.1 \DMT Plan July 2012 Rev 12.1 clean. doc 7/12 Revision: Denison12.1 Page 25 of26 White Mesa Mill -Discharge Minimization Technology Monitoring Plan 7112 Revision: Denisonl2.1 Page 26 of26 Table 1A Calculated Action leakage Rates for Various head Conditions Cell4A White mesa Mill Blanding, Utah Head above Liner System (feet) Calculated Action leakage Rate 5 10 15 20 25 30 35 37 ( gallons I acre I day) Table lB Calculated Action leakage Rates for Various head Conditions Cell4B White mesa Mill Blanding, Utah 222.04 314.01 384.58 444.08 496.50 543.88 587.46 604.01 Head above Liner System (feet) Calculated Action leakage Rate ( gallons I acre I day ) 5 211.40 10 317.00 15 369.90 20 422.70 25 475.60 30 528.40 35 570.00 37 581.20 N:\DMT Plan\DMT Plan 06.2012 Revision 12.1\DMT Plan July 2012 Rev 12.1 clean.doc Appendix I White Mesa Mill Tailings Management System, 7/2012, Revision: Denison 12.1 WHITE MESA MILL TAILINGS MANAGEMENT SYSTEM Revision 2.1 July 2012 Prepared by: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver, CO 80265 White Mesa Mill-Standard Operating Procedures Book II: Environmental Protection Manual, Section 3.1 7/I2 Revision: Denison 2.1 Page 2 of37 WHITE MESA MILL TAILINGS MANAGEMENT SYSTEM TABLE OF CONTENTS 1. INTRODUCTION .................................................................................................................. 3 1.1. Background ...................................................................................................................... 3 2. DAILY TAILINGS INSPECTIONS ...................................................................................... 4 2.1. Daily Comprehensive Tailings Inspection ....................................................................... 4 2.2. Daily Operations Inspection ............................................................................................. 7 2.3. Daily Operations Patrol .................................................................................................... 7 2.4. Training ............................................................................................................................ 7 2.5. Tailings Emergencies ......................................................................................................... 7 3. WEEKLY TAILINGS AND DMT INSPECTION ................................................................ 8 3.1. Weekly Tailings Inspections ............................................................................................ 8 4. MONTHLY TAILINGS INSPECTION ............................................................................... 11 5. QUARTERLY TAILINGS INSPECTION ........................................................................... 12 6. ANNUAL EVALUATIONS ................................................................................................. 13 6.1. Annual Technical Evaluation ......................................................................................... 13 6.2. Movement Monitors ........................................................................................................ 14 6.3. Freeboard Limits ............................................................... -............................................. L4 6.3.1. Ce111 ....................................................................................................................... 15 6.3.2. Ce112 ....................................................................................................................... 15 6.3.3. Cell 3 .................................................................................................. , .................... 15 6.3.4. Cel14A .................................................................................................................... 15 6.3.5. Cel14B .................................................................................................................... 15 7. OTHER INSPECT! ONS ........................................................................................................ 18 8. REPORTING REQUIREMENTS ........................................................................................ 18 8.1. Monthly Tailings Reports .............................................................................................. 18 Appendix A Appendix B Appendix C Appendix D APPENDICES Forms Tailings Inspector Training Certification Form Example Freeboard Calculations for Cell 4B N:\Tailings Management System Procedure\ Tailings Management System· June 2012\Tai1ings Management System Rev 2.1 June 2012 c1ean.doc White Mesa Mill -Standard Operating Procedures Book 11 : Environmental Protection Manual, Section 3.1 1. INTRODUCTION 7/12 Revision: Denison 2.1 Page 3 of37 This Tailings Management System procedure for the White Mesa Mill (the "Mill") provides procedures for monitoring the tailings cell systems as required under State of Utah Radioactive Materials License No. UT1900479 (the "RML"). The procedures to demonstrate compliance with Discharge Minimization Technology ("DMT") as specified throughout Parts I.D, I.E and I.F of the Mill's Groundwater Discharge Permit ("GWDP") Number 370004, are presented in the DMT Monitoring Plan ("DMT Plan"), which is a separate Plan. This Tailings Management System procedure and the DMT Plan when implemented in concert are designed as a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system including dike stability, liner integrity, and transport systems, as well as monitoring of water levels in Roberts Pond and feedstock storage areas at the Mill. This Tailings Management System is published and maintained in the Mill's Environmental Protection Manual while the DMT Plan is issued as a stand-alone document. 1.1. Background This Tailings Management System procedure was originally developed as Chapter 3.1 of the Mill's Environmental Protection Manual, under the Mill's NRC Source Material License, and constituted a comprehensive systematic program for constant surveillance and documentation of the integrity of the tailings impoundment system. Upon the State of Utah becoming an Agreement State for uranium mills in 2004, the Mill's Source Material License was replaced by the State of Utah RML and the State of Utah GWDP. The GWDP required that Denison develop the initial DMT Plan in response to GWDP requirements. In developing the initial DMT Plan, Denison combined the existing Tailings Management System procedure set out as Chapter 3 .1 of the Mill's Environmental Protection Manual with a number of new DMT requirements from the GWDP to form the initial DMT Plan. The initial DMT Plan and subsequent revisions (through revision 11.5) maintained the requirements from the RML (i.e., Chapter 3.1 of the Mill's Environmental Protection Manual) and the DMT requirements of the GWDP in a single document. However, after several years of implementing the DMT Plan, Denison concluded that it is preferable to separate the RML portions of the DMT Plan from the GWDP portions of the DMT Plan, into two separate documents. The DMT Plan continues to be a stand-alone plan that contains the DMT requirements from the GWDP except for the daily recording of the Cells 1, 2, and 3 LDS measurements as noted below. However, the portions of the DMT Plan that flow from the RML and not from the GWDP have been separated from the DMT Plan and have been returned to their original status as this Tailings Management System procedure, which comprises Chapter 3.1 of the Mill's Environmental Protection Manual. This allows the DMT Plan to be managed, inspected and N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7112 Revision: Denison 2.1 Page 4 of37 enforced under the requirements of the GWDP and this Tailings Management System procedure to be managed, inspected and enforced under the requirements of the RML. This division of the requirements was discussed with DRC on October 26, 2011. DRC agreed with the division of the requirements into two distinct documents as noted in their correspondence dated December 20, 2011. Pursuant to a written request from DRC, dated May 30, 2012, the RML requirements for the inspections of the Cells I, 2, and 3 Leak Detection Systems ("LDSs") have been included in this DMT Plan. The inclusion of this RML requirement is to address the DRC request for uniformity in monitoring and reporting requirements for Cells I, 2, and 3 and to address anticipated GWDP modifications regarding the LDS monitoring in Cells I, 2, and 3. 2. DAILY TAILINGS INSPECTIONS The following daily tailings inspections shall be performed: 2.I. Daily Comprehensive Tailings Inspection On a daily basis, including weekends, all areas connected with the evaporation cell (Celli) and the four tailings cells (Cells 2, 3, 4A, and 4B) will be inspected. Observations will be made of the current condition of each cell, noting any corrective action that needs to be taken. The Radiation Safety Officer (RSO) or his designee is responsible for performing the daily tailings inspections. The RSO may designate other individuals with training, as described in Section 2.4 below, to perform the daily tailings inspection. Observations made as required by this Tailings Management System by the inspector will be recorded on the Daily Inspection Data form (a copy of which is included in Appendix A to this Tailings Management System procedure). The daily leak detection check for Cells I, 2, and 3 will be recorded on the Daily Inspection Data form included as Attachment A-I of the DMT Plan. The Daily Inspection Data form included with this Tailings Management System procedure contains an inspection checklist, which includes a tailings cells map, and spaces to record observations, especially those of immediate concern and those requiring corrective action. The inspector will place a check by all inspection items that appear to be operating properly. Those items where conditions of potential concern are observed should be marked with an "X". A note should accompany the "X" specifying what the concern is and what corrective measures will resolve the problem. This observation of concern should be noted on the form until the problem has been remedied. The date that corrective action was taken should be noted as well. Additional inspection items are required under the DMT Plan, which requires that the daily inspection form requirements in Attachment A to the DMT Plan also be completed. Areas to be inspected include the following: Celli, 2, 3, 4A and 4B, the liners of Cells I, 2, and 3, Dikes 4A-S, 4A-E, and 4B-S, wind movement of tailings, effectiveness of dust minimization N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7112 Revision: Denison 2.1 Page 5 of37 methods, spray evaporation, Cell2 spillway, Cell3 spillway, Cell4A spillway, Cell3, Cell4A and 4B liquid pools and associated liquid return equipment, and the Cell 1, 2, and 3 leak detection systems. Operational features of the tailings area are checked for conditions of potential concern. The following items require visual inspection during the daily tailings inspection: a) Tailings slurry and SX raffinate transport systems from the Mill to the active disposal cell(s), and pool return pipeline and pumps. Daily inspections of the tailings lines are required to be performed when the Mill is operating. The lines to be inspected include the: tailings slurry lines from CCD to the active tailings cell; SX raffinate lines that can discharge into Cell 1, Cell4A or Cell4B; the pond return line from the tailings area to the Mill; and, lines transporting pond solutions from one cell to another. b) Celli. c) Cell2. d) Cell 3. e) Cell4A. f) Cell4B. g) Dike structures including dikes 4A-S, 4A-E, and 4B-S. h) The Cell2 spillway, Cell3 spillway, Cell4A spillway, Cell3, Cell4A and Cell 4B liquid pools and associated liquid return equipment. i) Presence of wildlife and/or domesticated animals in the tailings area, including waterfowl and burrowing animal habitations. j) Spray evaporation pumps and lines. k) Wind movement of tailings and dust minimization. Wind movement of tailings will be evaluated for conditions which may require initiation of preventative dust minimization measures for cells containing tailings sand. During tailings inspection, general surface conditions will be evaluated for the following: 1) areas of tailings subject to blowing and/or wind movement, 2) N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill-Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7112 Revision: Denison 2.1 Page 6 of37 liquid pool size, 3) areas not subject to blowing and/or wind movement, expressed as a percentage of the total cell area. The evaluations will be reviewed on a weekly basis, or more frequently if warranted, and will be used to direct dust minimization activities. I) Observation of flow and operational status of the dust control/spray evaporation system(s). m) Observations of any abnormal variations in tailings pond elevations in Cells 1, 3, 4A, and 4B. n) Locations of slurry and SX discharge within the active cells. Slurry and SX discharge points need to be indicated on the tailings cells map included in the Daily Inspection Data form. o) An estimate of flow for active tailings slurry and SX line(s). p) An estimate of flow in the solution return line(s). q) Daily measurements in the leak detection system sumps of the tailings Cells 1, 2, and 3 will be made when warranted by changes in the solution level of the respective leak detection system. Measurement of fluids in the Cells 4A and 4B leak detection system and recording of the daily measurements of the Cells 1, 2, and 3 leak detection systems sumps are discussed in the DMT Plan. The trigger for further action when evaluating the measurements in the Cells 1, 2, and 3 leak detection systems is a gain of more than 12 inches in 24 hours. If observations of trigger levels of fluids are made, the Mill Manager should be notified immediately and the leak detection system pump started. Whenever the leak detection system pump is operating and the flow meter and totalizer is recording on Cells 1, 2, and 3, a notation of the date and the time will be recorded on the Daily Inspection Data form. This data will be used in accordance with License Condition 11.3 .B through 11.3 .E of the Mill's Radioactive Materials License, to determine whether or not the flow rate into the leak detection system is in excess of the License Conditions. If an LDS monitoring system becomes inoperable, alternate methods for LDS fluid measurements may be employed following notification to the Executive Secretary. Items (a), (m), (n), and (o) are to be done only when the Mill is operating. When the Mill is down, N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 these items cannot be performed. 2.2. Daily Operations Inspection 7/12 Revision: Denison 2.1 Page 7 of37 During Mill operation, the Shift Foreman, or other person with the training specified in Section 2.4 below, designated by the Radiation Safety Officer, will perform an inspection ofthe tailings line and tailings area at least once per shift, paying close attention for potential leaks and to the discharges from the pipelines. Observations by the Inspector will be recorded on the appropriate line on the Operating Foreman's Daily Inspection form. 2.3. Daily Operations Patrol In addition to the inspections described in Sections 2.1 and 2.2 above, a Mill employee will patrol the tailings area at least twice per shift during Mill operations to ensure that there are no obvious safety or operational issues, such as leaking pipes or unusual wildlife activity or incidences. No record of these patrols need be made, but the inspectors will notify the RSO and/or Mill management in the event that during their inspection they discover that an abnormal condition or tailings emergency has occurred. 2.4. Training All individuals performing inspections described in Sections 2.1 and 2.2 above must have Tailings Management System training as set out in the Tailings Inspection Training procedure, which is attached as Appendix B. This training will include a training pack explaining the procedure for performing the inspection and addressing inspection items to be observed. In addition, each individual, after reviewing the training pack, will sign a certification form, indicating that training has been received relative to his/her duties as an inspector. 2.5. Tailings Emergencies Inspectors will notify the RSO and/or Mill management immediately if, during their inspection, they discover that an abnormal condition exists or an event has occurred that could cause a tailings emergency. Until relieved by the Environmental or Technician or RSO, inspectors will have the . authority to direct resources during tailings emergencies. Any major catastrophic events or conditions pertaining to the tailings area should be reported immediately to the Mill Manager or the RSO, one of whom will notify Corporate Management. If dam failure occurs, notify your supervisor and the Mill Manager immediately. The Mill Manager will then notify Corporate Management, MSHA (303-231-5465), and the State of Utah, Division of Dam Safety (801-538-7200). N:\Tailings Management System Procedure\Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 3. WEEKLY TAILINGS AND DMT INSPECTION 3.1. Weekly Tailings Inspections 7/12 Revision: Denison 2.1 Page 8 of37 Weekly tailings inspections are to be conducted by the Radiation Safety Department and include the following: a) Leak Detection Systems Each tailings cell's leak detection system shall be checked weekly (as well as daily) to determine whether it is wet or dry. If marked wet, the liquid levels need to be measured and reported. In Cell 1, 2, and Cell 3 the leak detection system is measured by use of a dual-probe system that senses the presence of solutions in the LDS system (comparable to the systems in Cells 4A and 4B) and indicates the presence of solution with a warning light. The water levels are measured to the nearest 0.10 inch. The water level data in Cells 1, 2, and 3 is recorded on the Daily Tailings Inspection Form included as Attachment A-1 of the DMT Plan. If sufficient fluid is present in the leak detection system of Cells 1, 2, and 3, the fluid shall be pumped from the LDS, to the extent reasonably possible, and the volume of fluid recovered will be recorded. Any fluid pumped from an LDS shall be returned to a disposal cell. For Cells 1, 2, and 3, if fluid is pumped from an LDS, the flow rate shall be calculated by dividing the recorded volume of fluid recovered by the elapsed time since fluid was last pumped or increases in the LDS fluid levels were recorded, whichever is the more recent. This calculation shall be documented as part of the weekly inspection. For Cells 1 and 3, upon the initial pumping of fluid from an LDS, a fluid sample shall be collected and analyzed in accordance with paragraph 11.3 C. of the RML. The LDS requirements for Cells 4A and 4B are discussed in the DMT Plan. b) Slimes Drain Water Level Monitoring (i) Cell 3 is nearly full and will commence closure when filled. Cell 2 is partially reclaimed with the surface covered by platform fill. Each cell has a slimes drain system which aids in dewatering the slimes and sands placed in the cell; (ii) Denison re-graded the interim fill on Cell 2 in order to reduce the potential for the accumulation of storm water on the surface ofCell2. As a result of the re-grading of N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7/12 Revision: Denison 2.1 Page 9 of37 the interim cover and the placement of an additional 62,000 cubic yards of fill material on Cell 2, the slimes drain access pipe was extended 6.97 feet. The extension pipe is 6.97 feet in length, and therefore the new measuring point is 37.97 feet from the bottom of the slimes drain. The measuring point on the extension pipe was surveyed by a Utah-Certified Land Surveyor. The measuring point elevation is 5618.73 fmsl. For the quarterly recovery test described in section vi below, this extension has no effect on the data measurement procedures. Cell 2 has a pump placed inside of the slimes drain access pipe at the bottom of the slimes drain. As taken from actual measurements, the bottom of the slimes drain is 37.97 feet below a water level measuring point which is a notch on the side of the Cell2 slimes drain access pipe. This means that the bottom of the slimes drain pool and the location of the pump are one foot above the lowest point of the FML in Cell 2, which, based on construction reports, is at a depth of 3 8.97 feet below the water level measuring point on the slimes drain access pipe for Cell 2; (iii) The slimes drain pump in Cell2 is activated and deactivated by a float mechanism and water level probe system. When the water level reaches the level of the float mechanism the pump is activated. Pumping then occurs until the water level reaches the lower probe which turns the pump off. The lower probe is located one foot above the bottom of the slimes drain standpipe, and the float valve is located at three feet above the bottom of the slimes drain standpipe. The average wastewater head in the Cell 2 slimes drain is therefore less than 3 feet and is below the phreatic surface of tailings Cell 2, about 27 feet below the water level measuring point on the slimes drain access pipe. As a result, there is a continuous flow of wastewater from Cell 2 into the slimes drain collection system. Mill management considers that the average allowable wastewater head in the Cell 2 slimes drain resulting from pumping in this manner is satisfactory and is as low as reasonably achievable. (iv)The Cell 2 slimes drain pump is checked weekly to observe that it is operating and that the water level probe and float mechanism are working properly, which is noted on the Weekly Tailings Inspection Form. If at any time the pump is observed to be not working properly, it will be fixed or replaced within 15 days; (v) Depth to wastewater in the Cell 2 slimes drain access pipe shall be monitored and recorded weekly to determine maximum and minimum fluid head before and after a pumping cycle, respectively. The extension ofthe Cell 2 slimes drain access pipe did not require any changes to the measurement procedure. The surveyed measuring point on the extended pipe is used as required. The elevation of the measuring point is 5618.73 fmsl. The head measurements are calculated in the same manner, using the same procedures as those used prior to the extension of the Cell 2 slimes drain access pipe; however, the total depth to the bottom of the pipe is now 37.97 feet as noted on the corrected form in Attachment A. All head measurements must be made from the same measuring point (the notch at the north side of the access pipe 5618.73 fmsl), and made to the nearest 0.01 foot. The results will be recorded as depth-in-pipe measurements on the Weekly Tailings N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7/12 Revision: Denison 2.1 Page 10 of37 Inspection Form. The quarterly recovery test specified in the GWDP is discussed in the DMT Plan. It is important to note that the extension of the Cell 2 slimes access pipe has not changed the method of calculation of the pre-and post-pump head calculations, only the constant (Cell 2 slimes drain access pipe height) used in the calculation has changed. The head is calculated by subtracting the depth to liquid from 37.97 feet rather than from the previous measurement of 38 feet. The weekly Tailings Inspection form included in Attachment A has been changed to reflect the extension height; (vi)No process liquids shall be allowed to be discharged into Cell 2; (vii) Because Cell3, Cell4A, and 4B are currently active, no pumping from the Cell3, Cell4A, or 4B slimes drain is authorized. Prior to initiation of tailings dewatering operations for Cell3, Cell4A, or Cell4B, a similar procedure will be developed for ensuring that average head elevations in the Cell3, Cell4A, and 4B slimes drains are kept as low as reasonably achievable, and that the Cell3, Cell4A, and Cell4B slimes drains are inspected and the results reported in accordance with the requirements of the permit. c) Wind Movement ofTailings An evaluation of wind movement of tailings or dusting and control measures shall be taken if needed. d) Decontamination Pads (i) New Decontamination Pad The New Decontamination Pad is located in the southeast corner of the ore pad, near the Mill's scale house. Weekly and annual inspection requirements for the New Decontamination Pad are discussed in the DMT Plan. (ii) Existing Decontamination Pad The Existing Decontamination Pad is located between the northwest corner of the Mill's maintenance shop and the ore feeding grizzly. A. The Existing Decontamination Pad will be inspected on a weekly basis. Any soil and debris will be removed from the Existing Decontamination Pad immediately prior to inspection of the concrete wash pad for cracking Observations will be made of the current condition of the Existing Decontamination Pad, including the concrete integrity of the exposed surfaces of the pad. Any abnormalities relating to the pad and N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7112 Revision: Denison 2.1 Page 11 of37 any damage or cracks on the concrete wash surface of the pad will be noted on the Weekly Tailings Inspection form. If there are any cracks greater than 1/8 inch separation (width), the RSO must be contacted. The RSO will have the responsibility to cease activities and have the cracks repaired. e) Summary In addition, the weekly inspection should summarize all activities concerning the tailings area for that particular week. Results of the weekly tailings inspection are recorded on the Weekly Tailings and DMT Inspection form. An example of the Weekly Tailings Inspection form is provided in Appendix A of this Tailings Management System procedure. A similar form containing DMT inspection requirements is provided as Attachment A ofthe DMT Plan. 4. MONTHLY TAILINGS INSPECTION Monthly tailings inspections will be performed by the RSO or his designee from the Radiation Safety Department and recorded on the Monthly Inspection Data form, an example of which is contained in Appendix A. Monthly inspections are to be performed no sooner than 14 days since the last monthly tailings inspection and can be conducted concurrently with the quarterly tailings inspection when applicable. The following items are to be inspected: a) Tailings Slurry Pipeline When the Mill is operating, the slurry pipeline will be visually inspected at key locations to determine pipe wear. The critical points of the pipe include bends, slope changes, valves, and junctions, which are critical to dike stability. These locations to be monitored will be determined by the Radiation Safety Officer or his designee from the Radiation Safety Department during the Mill run. b) Diversion Ditches Diversion ditches 1, 2 and 3 shall be monitored monthly for sloughing, erosion, undesirable vegetation, and obstruction of flow. Diversion berm 2 should be checked for stability and signs of distress. c) Sedimentation Pond Activities around the Mill and facilities area sedimentation pond shall be summarized for the month. N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 d) Overspray Dust Minimization 7112 Revision: Denison 2.1 Page 12 of37 The inspection shall include an evaluation of overspray minimization, if applicable. This entails ensuring that the overspray system is functioning properly. In the event that overspray is carried more than 50 feet from the cell, the overspray system should be immediately shut-off. e) Remarks A section is included on the Monthly Inspection Data form for remarks in which recommendations can be made or observations of concern can be documented. f) Summary of Daily, Weekly and Quarterly Inspections The monthly inspection will also summarize the daily, weekly and, if applicable, quarterly tailings inspections for the specific month. In addition, settlement monitors are typically surveyed monthly and the results reported on the Monthly Inspection Data form. 5. QUARTERLY TAILINGS INSPECTION The quarterly tailings inspection is performed by the RSO or his designee from the Radiation Safety Department, having the training specified in Section 2.4 above, once per calendar quarter. A quarterly inspection should be performed no sooner than 45 days since the previous quarterly inspection was performed. Each quarterly inspection shall include an Embankment Inspection, an Operations/Maintenance Review, a Construction Review and a Summary, as follows: a) Embankment Inspection The Embankment inspection involves a visual inspection of the crest, slope and toe of each dike for movement, seepage, severe erosion, subsidence, shrinkage cracks, and exposed liner. b) Operations/Maintenance Review The Operations/Maintenance Review consists of reviewing Operations and Maintenance activities pertaining to the tailings area on a quarterly basis. N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book II: Environmental Protection Manual, Section 3 .I c) Construction Review 7/12 Revision: Denison 2.1 Page 13 of37 The Construction Review consists of reviewing any construction changes or modifications made to the tailings area on a quarterly basis. An estimate of the percentage of the tailings beach surface area and solution pool area is made, including estimates of solutions, cover areas, and tailings sands for Cells 3, 4A and 4B. d) Summary The summary will include all major activities or observations noted around the tailings area on a quarterly basis. If any of these conditions are noted, the conditions and corrective measures taken should be documented in the Quarterly Inspection Data form. An example of the Quarterly Inspection Data form is provided in Appendix A. 6. ANNUAL EVALUATIONS The following annual evaluations shall be performed: 6.1. Annual Technical Evaluation An annual technical evaluation of the tailings management system is performed by a registered professional engineer (PE), who has experience and training in the area of geotechnical aspects of retention structures. The technical evaluation includes an on-site inspection of the tailings management system and a thorough review of all tailings records for the past year. The Technical Evaluation also includes a review and summary of the annual movement monitor survey (see Section 5.2 below). All tailings cells and corresponding dikes will be inspected for signs of erosion, subsidence, shrinkage, and seepage. The drainage ditches will be inspected to evaluate surface water control structures. In the event tailings capacity evaluations (as per SOP PBL-3) were performed for the receipt of alternate feed material during the year, the capacity evaluation forms and associated calculation sheets will be reviewed to ensure that the maximum tailings capacity estimate is accurate. The amount of tailings added to the system since the last evaluation will also be calculated to determine the estimated capacity at the time of the evaluation. Tailings inspection records will consist of daily, weekly, monthly, and quarterly tailings inspections. N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7/12 Revision: Denison 2.1 Page 14 of37 These inspection records will be evaluated to determine if any freeboard limits are being approached. Records will also be reviewed to summarize observations of potential concern. The evaluation also involves discussion with the Environmental and/or Radiation Technician and the RSO regarding activities around the tailings area for the past year. During the annual inspection, photographs of the tailings area will be taken. The training of individuals will be reviewed as a part ofthe Annual Technical Evaluation. The registered engineer will obtain copies of selected tailings inspections, along with the monthly and quarterly summaries of observations of concern and the corrective actions taken. These copies will then be included in the Annual Technical Evaluation Report. The Annual Technical Evaluation Report must be submitted by November 15th of every year to the Executive Secretary and to the Assistant State Engineer, Utah Division of Water Rights at the address specified below. Assistant State Engineer Utah Division of Water Rights 1594 West North Temple, Suite 220 P.O. Box 146300 Salt Lake City, Utah 84114-6300 6.2. Movement Monitors A movement monitor survey is to be conducted by a licensed surveyor annually during the second quarter of each year. The movement monitor survey consists of surveying monitors along dikes 4A- E, 4A-S, and 4B-S to detect any possible settlement or movement of the dikes. The data generated from this survey is reviewed and incorporated into the Annual Technical Evaluation Report of the tailings management system. 6.3. Freeboard Limits The freeboard limits set out in this Section are intended to capture the Local 6-hour Probable Maximum Precipitation (PMP) event, which was determined in the January 10, 1990 Drainage Report (the "Drainage Report") for the White Mesa site to be 10 inches. The flood volume from the PMP event over the Cell 1 pond area plus the adjacent drainage areas, was calculated in the Drainage Report to be 103 acre feet of water, with a wave run up factor of 0.90 feet. The flood volume from the PMP event over the Cell2 and Cell3 pond areas, plus the adjacent drainage areas was calculated in the Drainage Report to be 123 .4 acre-feet of water. N :\Tailings Management System Procedure\ Tailings Management System -June 2012\ Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7112 Revision: Denison 2.1 Page 15 of37 The flood volume from the PMP event over the Cell 4A area was calculated in the Drainage Report to be 36 acre-feet of water (40 acres, plus the adjacent drainage area of 3.25 acres), times the PMP of 10 inches), with a wave run up factor of0.77 feet. The flood volume from the PMP event over the Cell 4B area has been calculated to be 38.1 acre- feet of water (40 acres, plus the adjacent drainage area of 5.72 acres), times the PMP of 10 inches, with a wave run up factor of 0. 77 feet. The total pool surface area in Cell 1 is 52.9 acres, in Cell4A is 40 acres, and in Cell4B is 40 acres. The top ofthe flexible membrane liner ("FML") for Cell1 is 5,618.2 FMSL, for Cell4A is 5,598.5 FMSL and for Cell4B is 5600.4 FMSL. Based on the foregoing, the freeboard limits for the Mill's tailings cells will be set as follows: 6.3.1. Cell 1 The freeboard limit for Cell1 will be set at 5,615.4 FMSL. This will allow Cell1 to capture all of the PMP volume associated with Cell 1. The total volume requirement for Cell 1 is 1 03 acre feet divided by 52.9 acres equals 1.95 feet, plus the wave run up factor of0.90 feet equals 2.85 feet. The freeboard limit is then 5,618.2 FMSL minus 2.85 feet equals 5,615.4 FMSL. Under Radioactive Materials License condition 10.3, this freeboard limit is set and is not recalculated annually. 6.3.2. Cell 2 The freeboard limit for Cell 2 is inapplicable, since Cell 2 is filled with solids. All of the PMP volume associated with Cell2 will be attributed to Cell4A (and/or any future tailings cells). 6.3.3. Cell 3 The freeboard limit for Cell 3 is inapplicable, since Cell3 is close to being filled with solids, and all of the PMP flood volume associated with Cell 3 will be attributed to Cell 4B (and/or any future tailings cells). 6.3.4. Cell 4A The freeboard limit for Cell4A is inapplicable since all ofthe PMP flood volume associated with Cell4A will be attributed to Cell4B. A spillway has been added to Cell4A to allow overflow into Cell4B. 6.3.5. Cell4B The freeboard limit for Cell4B will be set assuming that the total PMP volume for Cells 2, 3, 4A, and 4B of 159.4 acre feet will be accommodated in Cell 4B. The procedure for calculating the freeboard limit for Cell4B is as follows: N:\Tailings Management System Procedure\Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 (a) When the Pool Surface Area is 40 Acres 7/12 Revision: Denison 2.1 Page 16 of37 When the pool surface area in Cell4B is 40 acres (i.e., when there are no beaches), the freeboard limit for Cell4B will be 5,594.6FMSL, which is 5. 7 feet below the FML. This freeboard value was developed as follows: PMP Flood Volume Overflow from Cell 4A assuming no storage in Cell 3 or 4A Sum of PMP volume and overflow volume Depth to store PMP an overflow volume = 197.5 acre-feet/40 acres Wave run up factor Total required freeboard 38.1 acre-feet 159.4 acre-feet 197.5 acre-feet 4.9 feet 0.77 feet 5.7 feet (all values in the above calculation have been rounded to the nearest one-tenth of afoot); (b) When the Maximum Elevation of the Beach Area is 5,594 FMSL or Less When the maximum elevation ofthe beach area in Cell4B is 5594 FMSL or less, then the freeboard limit will be 5,594.6 FMSL, which is the same as in (a) above. This allows for the situation where there may be beaches, but these beaches are at a lower elevation than the freeboard limit established in (a) above, and there is therefore ample freeboard above the beaches to hold the maximum PMP volume. The maximum elevation of the beach area will be determined by monthly surveys performed by Mill personnel in accordance with the Mill's DMT Plan. (c) When the Maximum Elevation of the Beach Area First Exceeds 5,594 FMSL When the maximum elevation of the beach area in Cell 4B first exceeds 5,594 FMSL, then the freeboard limit for the remainder of the ensuing year (period t=O) (until the next November 1) will be calculated when that elevation is first exceeded (the "Initial Calculation Date"), as follows: i) The total number of dry tons of tailings that have historically been deposited into Cell 4B prior to the Initial Calculation Date ("To") will be determined; ii) The expected number of dry tons to be deposited into Cell4B for the remainder of the ensuing year (up to the next November 1), based on production estimates for that period ("L:lo*"), will be determined; iii) L:l0* will be grossed up by a safety factor of 150% to allow for a potential underestimation of the number of tons that will be deposited in the cell during the remainder of the ensuing year. This grossed up number can be referred to as the "modeled tonnage" for the period; iv) The total design tailings solid storage capacity of Cell 4B will be accepted as 2,094,000 dry tons of tailings; v) The available remaining space in Cell4B for solids as at the Initial Calculation Date will be calculated as 2,094,000 dry tons minus To; vi) The reduction in the pool surface area for the remainder of the ensuing year will be assumed to be directly proportional to the reduction in the available space in Cell4B N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7112 Revision: Denison 2.1 Page 17 of37 for solids. That is, the reduced pool surface area for period t=O ("RP Ao"), after the reduction, will be calculated to be: (1-(~0 * x 1.5) I (2,094,000-To)) x 40 acres= RPAo vii) The required freeboard for Cell 4B for the remainder of the period t=O can be calculated in feet to be the wave run up factor for Cell 4B of 0.77 feet plus the quotient of 197.5 acre feet divided by the RPA0. The freeboard limit for Cell4B for the remainder of period t=O would then be the elevation ofthe FML for Cell4B of 5594.0 FMSL less this required freeboard amount, rounded to the nearest one-tenth of a foot; and viii) The foregoing calculations will be performed at the Initial Calculation Date and the resulting freeboard limit will persist until the next November 1. An example of this calculation is set out in Appendix F. (d) Annual Freeboard Calculation When the Maximum Elevation of the Beach Area Exceeds 5,594 FMSL On November 1 of each year (the "Annual Calculation Date"), the reduction in pool area for the ensuing year (referred to as period t) will be calculated by: i) First, calculating the Adjusted Reduced Pool Area for the previous period (ARP At-I) to reflect actual tonnages deposited in Cell 4B for the previous period (period t-1). The RP At-I used for the previous period was based on expected tonnages for period t- 1, grossed up by a safety factor. The ARP At-I is merely the RP A that would have been used for period t-1 had the actual tonnages for year t-1 been known at the outset of period t-1 and had the RP A been calculated based on the actual tonnages for period t-1. This allows the freeboard calculations to be corrected each year to take into account actual tonnages deposited in the cell as of the date of the calculation. The ARP At-I can be calculated using the following formula: (1 -~t-1 I (2,094,000-Tt-I)) x ARP At-2 = ARP At-! Where: • ~t-I is the actual number of dry tons of tailings solids deposited in Cell4B during period t-1; • T1_1 is the actual number of dry tons of tailings solids historically deposited in Cell4B prior to the beginning of period t-1; and • ARP At-2 is the Adjusted Reduced Pool Area for period t-2. If period t-2 started at the Initial Calculation Date, then ARP At-2 is 40 acres; ii) Once the ARP At-I for the previous period (period t -1) has been calculated, the RP A for the subject period (period t) can be calculated as follows: (1-(~t* x 1.5) I (2,094,000-Tt)) x ARPAt-1 = RPAt N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 Where: 7112 Revision: Denison 2.1 Page 18 of37 • ~~* is the expected number of dry tons of tailings to be deposited into Cell4B for the ensuing year (period t), based on production estimates for the year (as can be seen from the foregoing formula, this expected number is grossed up by a safety factor of 1.5); • T1 is the actual number of dry tons of tailings solids historically deposited in Cell4B prior to the beginning of period t; and • ARP A1_1 is the Adjusted Reduced Pool Area for period t-1, which is the pool urface area for the previous period (period .-1) that should have applied during that period, had modeled tonnages (i.e., expected tonnages grossed up by the 150% safety factor) equaled actual tonnages for the period; iii) The required freeboard for peri d t can be cal culated in feet to be the wave run up factor for Cell 4B of 0.77 feet plns the qu tient f J 97.5 acre feet di ided by the RP A1• The freeboard limit for Cell 4B for period t would then be th elev~tion of the FML for Cell4B of5594.0 FMSL less tbis required freeboard amount rounded to the nearest one-tenth of a foot; and iv) The foregoing calculations will be performed at the Annual Calculation Date for period t and the resulting freeboard limit will persist until the next Annual Calculation Date for period t+ 1. An example of this calculation is set out in Appendix D. (e) When a Spillway is Added to Cell 4B that Allows Overflow Into a New Tailings Cell When a spillway is added between Cell4B and a new tailings cell then, if an approved freeboard limit calculation method for the new cell is set to cover the entire PMP event for Cells 2, 3, 4A, 4B and the new tailings cell, the freeboard limit for Cell4B will be inapplicable, except for approved provisions to prevent storm water runoff from overtopping dikes. 7. OTHER INSPECTIONS All daily, weekly, monthly, quarterly and annual inspections and evaluations should be performed as specified in Sections 2, 3, 4, 5 and 6 above. However, additional inspections should be conducted after any significant storm or significant natural or man-made event occurs. 8. REPORTING REQUIREMENTS In addition to the Daily inspection forms included as Appendix A to this Tailings Management System procedure, the inspection forms included as Attachment A of the DMT Plan and the Operating Foreman 's Daily Inspection form the following additional reports shall also be prepared: 8.1. Monthly Tailings Reports Monthly tailings reports are prepared every month and summarize the previous month's activities around the tailings area. If not prepared by the RSO, the report shall be submitted to the RSO for N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3 .I 7/12 Revision: Denison 2.1 Page 19 of37 review. The Mill Manager will review the report as well before the report is filed in the Mill Central File. The report will contain a summary of observations of concern noted on the daily and weekly tailings inspections. Corrective measures taken during the month will be documented along with the observations where appropriate. All daily and weekly tailings inspection forms will be attached to the report. A monthly inspection form will also be attached. Quarterly inspection forms will accompany the report when applicable. The report will be signed and dated by the preparer in addition to the Radiation Safety Officer and the Mill Manager. N:\Tailings Management System Procedure\Tailings Management System-June 20 12\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 APPENDIX A FORMS 7/12 Revision: Denison 2.1 Page 20 of37 N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clearLdoc White Mesa Mill-Standard Operating Procedures Book II: Environmental Protection Manual, Section 3.1 7/12 Revision: Denison 2.1 Page 21 of37 APPENDIX A-1 DAILY INSPECTION DATA Inspector: _______ _ Date; ----------Accompanied by:. ___ _ Time: --------- Any Item not "OK" must be documented. A check mark= OK, X= Action Required I. TAILINGS SLURRY TRANSPORT SYSTEM I Tnsp_ecrion Items Conditions ofPotential Concern Celli Cell2 Cell3 Slurry Pipeline Leaks, Damage, Blockage, Sharp Bends Pipeline Joints Leaks. Loose Connections Pipeline Supports Damage, Loss of Support Valves Leaks, Blocked, Closed Point(s) of Discharge Improper Location or Orientation II. OPERATIONAL SYSTEMS and INTERIOR of CELLS Inspection Items Conditions ofPotential Concern Celli Cell2 Cell3 N s E w Interior Cell Walls Liner Observable Liner Damage Water Level Greater Than Operating Level, Large Change Since Previous Inspection Beach Cracks, Severe Erosion, Subsidence Liner and Cover Erosion of cover, Exposure of Liner - N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc Cell4A Cell4B Celi4A Cell4B N S E w NS E w -- White Mesa Mill-Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 III. DIKES AND EMBANKMENTS InsQection Items Conditions of Potential Concern Slopes Sloughs or Sliding Cracks, Bulges, Subsidence, Severe Erosion, Moist Areas, Areas of Seepage Outbreak Crest Cracks, Subsidence, Severe Erosion IV. FLOWRATES Slurrv Line(s) GPM Dike 1-1 No visible exterior slope or dike to inspect No visible exterior slope or dike to inspect J 7/12 Revision: Denison 2.1 Page 22 of37 Dike 1-Dike 2 Dike3 1A No No No visible visible visible exterior exterior exterior slope or slope or slope or dike to dike to dike to inspect inspect inspect No No No visible visible visible exterior exterior exterior slope or slope or slope or dike to dike to dike to inspect inspect inspect Dike 4A-S Pond Return S-X Tails V. PHYSICAL INSPECTION OF SLURRY LINES(S) Walked to Discharge Point Obsetved Entire Discharge Line VI. DUST CONTROL Dusting Wind Movement of Tailings Precipitation: inches liquid Yes ------Yes ------ Cell2 Cell3 N:\Tailings Management System Procedure\ Tail ings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc Dike Dike 4A-E 48-S ~- Sorav Svstem ------'No No _____ __:: Cell4A Cell4B White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7112 Revision: Denison 2.1 Page 23 of37 I General Meteorological conditions: I I I I I Vll. DAILY LEAK DETECTION CHECK Daily Leak Detection Checks are recorded on the Daily Inspection Data form included as Attachment A-1 of the DMT Plan VITI OBSERVATIONS OF POTENTIAL CONCERN N:\Tailings Management System Procedure\ Tailings Management System -June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc Action Required White Mesa Mill-Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7/12 Revision: Denison 2.1 Page24 of37 ~~ :!. ::.: --· f i --~----. ~' ' ~-~ a (~ / r ~ I " ,---.,~ . . ~ !' '~ . . F I , r i ·-·~:-, ~ ~ ~ I ~ I ·---,~ ~~ • ·' n n .. . 0 ' 0 =-!a m · rn 1 · , ill o· r-. I ITI '§ = ,_ lj F t"' ::a -. --/ ~ I "' :z g -8 ""' o -.. -·-,, _o , 1 0 If o ill-. g _, ' . . -0 ""' ITI · } c.> , 1T1 r.' 1 _.. -" r-. . b · r-~ -r-t; ;;,, r-' I i5 .if ~ t!5 . I " "" . ~ I I ' [ ~ ~ ·---. 4:(-t-o-.. f ( I ~ F I "--, /L ---= -~ m - iTI .,.,....._.._., -------2! N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures 12/12 Revision: Denison 2.2 Page 25 of37 Book 11: Environmental Protection Manual, Section 3.1 APPENDIX A-2 DENISON MINES (USA) CORP. WEEKLY TAILINGS INSPECTION Date: _______ _ fuspectors: ------------- 1. Slimes Drain Liquid Levels Cell 2 Pump functioning properly ___ _ ------~Depth to Liquid pre-pump _______ Depth to Liquid Post-pump (all measurements are depth-in-pipe) Pre-pump head is 37.97' -Depth to Liquid Pre- pump= __ _ Post-pump head is 37.97' -Depth to Liquid Post- pump= __ _ 2. Existing Decontamination Pad (concrete) ___________________ _ 3. Tailings Area fuspection (Note dispersal of blowing tailings): 4. Control Methods Implemented:.~--------------------- 5. Remarks: ________________________________ _ 6. Designated Disposal Area for Non-Tailings Mill Waste (awaiting DRC approval) White Mesa Mill -Standard Operating Procedures Book II: Environmental Protection Manual, Section 3 .I 7/12 Revision : Denison 2.1 Page 26 of37 APPENDIX A-3 MONTmY INSPECTION DATA Inspector: __________________________ __ Date: ------------------------------- 1. Slurry Pipeline: 2. Diversion Ditches and Diversion Berm: Observation: Diversion Ditches: Sloughing Erosion Undesirable Vegetation Obstruction of Flow Diversion Berm: Stability Issues Signs ofDistress Comments: Diversion Ditch 1 ---~yes __ no ---~yes __ no ---~yes __ no ____yes __ no ---~yes __ n 0 ---~yes __ n 0 Diversion Ditch 2 Diversion Ditch 3 Diversion Berm 2 ____yes _____ no ____yes __ no ____yes __ no ____yes __ no ____yes __ no ____yes __ no ____yes __ no ____yes __ no ------------------------------------------------------------------------ 3. Summary of Activities Around Sedimentation Pond: ------------------- N :\Tailings Management System Procedure\ Tailings Management System-June 201 2\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill-Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 4. Overspray Dust Minimization: Overspray system functioning properly: __ _____, es __ ~no 7112 Revision: Denison 2.1 Page 27 of37 Overspray carried more than 50 feet from the cell: __yes no If "yes", was system immediately shut off? __yes __ no Comments: ------------------------------------------------------------------ 5. Remarks: ______________________________________________________________ __ 6. Settlement Monitors Cell2 Wl: Cel12W3-S: Cell3-1N: ----------Cell2 W2: Cel12El-N: ____ _ Cell3-1C: ____ _ Cell2 W3: Cel12El-1S: _____ _ Cell3-1S: ____ _ Cell2 W4: Cell2El-2S: ____ _ Cell3-2N: ____ _ Cell 2W7-C: _______ _ Cell2 East: Cell2W5-N: --------Cell2 W7N: -----------Cell2 W7S: -----------Cel12 W6N: ____ _ Cell 2 W6C: ______ _ Cell 2 W6S: ____ _ Cell 2 W4N: ____ _ Cell 4A-Toe: ____ _ Cell2 W4S: ____ _ Cell 2 WSC: ____ _ Cell 3-2C: ____ _ Cell3-2S: Cel12 WSS: Cel13-3S: _____ _ Cell 3-3C; _____ _ Cell3-3N: ------Cell3-4N: -------Cell3-6N: ------Cell3-7S: ____ _ Cell 3-7C: _____ _ Cell3-7N: _____ _ Cell3-8S: ____ _ Cell 3-SC: _____ _ Cell 3-SN: ____ _ 7. Movement Monitors: (Is there visible damage to any movement monitor or to adjacent surfaces)? 8. Summary of Daily, Weekly and Quarterly Inspections:----------------------- N:\Tailings Management System Procedure\Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book II : Environmental Protection Manual, Section 3 .I 7/12 Revision: Denison 2. I Page 28 of37 APPENDIX A-4 WHITE MESA MILL TAILINGS MANAGEMENT SYSTEM QUARTERLY INSPECTION DATA Inspector: __________________________ __ Date: __________________________ __ 1. Embankment Inspection: 2. Operations/Maintenance Review: ------------------------------ 3. Construction Activities: ------------------------------------------ 4. Estimated Areas: Cell3 Cell4A Cell4B Estimated percent of beach surface area Estimated percent of solution pool area Estimated 2ercent of cover area Comments: ------------------ N:\Tailings Management System Procedure\ Tailings Management System -June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 APPENDIXB TAILINGS INSPECTOR TRAINING 7/12 Revision: Denison 2.1 Page 29 of37 This document provides the training necessary for qualifying management-designated individuals for conducting daily tailings inspections. Training information is presented by the Radiation Safety Officer or designee from the Environmental Department. Daily tailings inspections are conducted in accordance with the White Mesa Mill Tailings Management System and Discharge Minimization Technology (DMT) Monitoring Plan. The Radiation Safety Officer or designee from the Radiation Safety Department is responsible for performing monthly and quarterly tailings inspections. Tailings inspection forms will be included in the monthly tailings inspection reports, which summarize the conditions, activities, and areas of concern regarding the tailings areas. Notifications: The inspector is required to record whether all inspection items are normal (satisfactory, requiring no action) or that conditions of potential concern exist (requiring action). A "check" mark indicates no action required. If conditions of potential concern exist the inspector should mark an "X" in the area the condition pertains to, note the condition, and specify the corrective action to be taken. If an observable concern is made, it should be noted on the tailings report until the corrective action is taken and the concern is remedied. The dates of all corrective actions should be noted on the reports as well. Any major catastrophic events or conditions pertaining to the tailings area should be reported immediately to the Mill Manager or the Radiation Safety Officer, one of whom will notify Corporate Management. If dam failure occurs, notify your supervisor and the Mill Manager immediately. The Mill Manager will then notify Corporate Management, MSHA (303-231-5465), and the State of Utah, Division ofDam Safety (801-538-7200). Inspections: All areas of the tailings disposal system are routinely patrolled and visible observations are to be noted on a daily tailings inspection form. Refer to Appendix A of this Tailings Management System procedure. A similar form containing DMT inspection requirements is provided as Attachment A of the DMT Plan. The inspection form contained in this Tailings Management System procedure is summarized as follows: 1. Tailings Slurry Transport System: The slurry pipeline is to be inspected for leaks, damage, and sharp bends. The pipeline joints N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 7/12 Revision: Denison 2.1 Page 30 of37 are to be monitored for leaks, and loose connections. The pipeline supports are to be inspected for damage and loss of support. Valves are also to be inspected particularly for leaks, blocked valves, and closed valves. Points of discharge need to be inspected for improper location and orientation. 2. Operational Systems: Operating systems including water levels, beach liners, and covered areas are items to be inspected and noted on the daily inspection forms. Sudden changes in water levels previously observed or water levels exceeding the operating level of a pond are potential areas of concern and should be noted. Beach areas that are observed as having cracks, severe erosion or cavities are also items that require investigation and notation on daily forms. Exposed liner or absence of cover from erosion are potential items of concern for ponds and covered areas. These should also be noted on the daily inspection form. Cells 1, 3, 4A and 4B solution levels are to be monitored closely for conditions nearing maximum operating level and for large changes in the water level since the last inspection. All pumping activities affecting the water level will be documented. In Cells 1 and 3, the PVC liner needs to be monitored closely for exposed liner, especially after storm events. It is important to cover exposed liner immediately as exposure to sunlight will cause degradation of the PVC liner. Small areas of exposed liner should be covered by hand. Large sections of exposed liner will require the use of heavy equipment These conditions are considered serious and require immediate action. After these conditions have been noted to the Radiation Safety Officer, a work order will be written by the Radiation Safety Officer and turned into the Maintenance Department. All such repairs should be noted in the report and should contain the start and finish date of the repairs. 3. Dikes and Embankments: Inspection items include the slopes and the crests of each dike. For slopes, areas of concern are sloughs or sliding cracks, bulges, subsidence, severe erosion, moist areas, and areas of seepage outbreak. For crests, areas of concern are cracks, subsidence, and severe erosion. When any of these conditions are noted, an "X" mark should be placed in the section marked for that dike. In addition, the dikes, in particular dikes 4A-S, 4A-E, and 4B-S, , should be inspected closely for mice holes and more importantly for prairie dog holes, as the prairie dogs are likely to burrow in deep, possibly to the liner. If any of these conditions exist, the inspection report should be marked accordingly. N:\Tailings Management System Procedure\Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 4. Flow Rates: 7112 Revision: Denison 2.1 Page 31 of37 Presence of all flows in and out of the cells should be noted. Flow rates are to be estimated in gallons per minute (GPM). Rates need to be determined for slurry lines, pond return, SX- tails, and the spray system. During non-operational modes, the flow rate column should be marked as "0". The same holds true when the spray system is not utilized. 5. Physical Inspection of Slurry Line(s): A physical inspection of all slurry lines has to be made every 4 hours during operation of the mill. If possible, the inspection should include observation of the entire discharge line and discharge spill point into the cell. If "fill to elevation" flags are in place, the tailings and build-up is to be monitored and controlled so as to not cover the flags. 6. Dust Control: Dusting and wind movement of tailings should be noted for Cells 2, 3, 4A, and 4B. Other observations to be noted include a brief description of present weather conditions, and a record of any precipitation received. Any dusting or wind movement of tailings should be documented. In addition, an estimate should be made for wind speed at the time of the observed dusting or wind movement of tailings. The Radiation Safety Department measures precipitation on a daily basis. Daily measurements should be made as near to 8:00 a.m. as possible every day. Weekend measurements will be taken by Environmental, Health and Safety personnel as close to 8:00 a.m. as possible. All snow or ice should be melted before a reading is taken. 7. Observations of Potential Concern: All observations of concern during the inspection should be noted in this section. Corrective action should follow each area of concern noted. All work orders issued, contacts, or notifications made should be noted in this section as well. It is important to document all these items in order to assure that the tailings management system records are complete and accurate. 8. Map of Tailings Cells: The last section of the inspection involves drawing, as accurately as possible, the following items where applicable. N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean. doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 1. Cover area 2. Beach/tailing sands area 3. Solution as it exists 4. Pump lines 7/12 Revision: Denison 2.1 Page 32 of37 5. Activities around tailings cell (i.e. hauling trash to the dump, liner repairs, etc.) 6. Slurry discharge when operating 7. Over spray system when operating 9. Safety Rules: All safety rules applicable to the mill are applicable when in the tailings area. These rules meet the required MSHA regulations for the tailings area. Please pay particular notice to the following rules: 1. The posted speed limit on Cell4A and 4B dike is 5 mph, and the posted speed limit for the tailings area (other than the Cell4A and 4B dike) is 15 mph. These limits should not be exceeded. 2. No food or drink is permitted in the area. 3. All personnel entering the tailings area must have access to a two-way radio. 4. Horseplay is not permitted at any time. 5. Only those specifically authorized may operate motor vehicles in the restricted area. 6. When road conditions are muddy or slick, a four-wheel drive vehicle is required in the area. 7. Any work performed in which there is a danger of falling or slipping in the cell will require the use of a safety belt or harness with attended life line and an approved life jacket. A portable eyewash must be present on site as well. 8. Anytime the boat is used to perform any work; an approved life jacket and goggles must be worn at all times. There must also be an approved safety watch with a two-way hand- held radio on shore. A portable eyewash must be present on site as well. 10. Preservation ofWildlife: Every effort should be made to prevent wildlife and domesticated animals from entering the tailings area. All wildlife observed should be reported on the Wildlife Report Worksheet during each shift. Waterfowl seen near the tailings cells should be discouraged from landing by the use of noisemakers. 11. Certification: Following the review of this document and on-site instruction on the tailings system inspection program, designated individuals will be certified to perform daily tailings inspections. The Radiation Safety Officer authorizes certification. Refer to the Certification N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3 .I 7/12 Revision: Denison 2.1 Page 33 of37 Form, Appendix C. This form should be signed and dated only after a thorough review ofthe tailings information previously presented. The form will then be signed by the RSO and filed. N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean. doc White Mesa Mill-Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 APPENDIXC CERTIFICATION FORM Date: -------------------------- Name: ------------------------- 7/12 Revision: Denison 2.1 Page 34 of37 I have read the document titled "Tailings Management System, White Mesa Mill Tailings Inspector Training" and have received on-site instruction at the tailings system. This instruction included documentation of daily tailings inspections, analysis of potential problems (dike failures, unusual flows), notification procedures and safety. Signature I certify that the above-named person is qualified to perform the daily inspection of the tailings system at the White Mesa Mill. Radiation Safety Personnel/ Tailings System Supervisor N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book ll: Environmental Protection Manual, Section 3. I 7112 Revision: Denison 2.1 Page 35 of37 Assumptions and Factors: APPENDIXD Example of Freeboard Calculations For Ceii4B o Total PMP volume to be stored in Cell4B-159.4 acre feet o Wave runup factor for Cell4B-0.77 feet o Total capacity ofCell4B-2,094,000 dry tons o Elevation ofFML ofCe114B-5,600.35 FMSL o Maximum pool surface area of Cell 4B-40 acres o Total tailings solids deposited into Cell 4B at time beach area first exceeds 5,594 FMSL -1,000,000 dry tons* o Date beach area first exceeds 5,594, FMSL-March 1, 2012* o Expected and actual production is as set forth in the following table: Time Period Expected Expected Tailings Actual Tailings Solids Tailings Solids Solids Disposition into Disposition into Cell 4B Disposition into Cell 4B at the determined at end of Cell4B beginning of the the period (dry tons)* Determined at period, multiplied by the beginning of 150% Safety Factor the period (dry (dry tons) tons)* March 1, 2012 to 150,000 225,000 225,000 November L 2012 November 1, 2012 to 300,000 450,000 275,000 November t 2013 November 1, 2013 to 200,000 300,000 250,000 November 1, 2014 *These expected and actual tailings and production numbers and dates are fictional and have been assumed for illustrative purposes only. Based on these assumptions and factors, the freeboard limits for Cell4B would be calculated as follows: 1. Prior to March 1, 2012 Prior to March 1, 2012, the maximum elevation of the beach area in Cel14B is less than or equal to 5,594 FMSL, therefore the freeboard limit is set at 5,594.6 FMSL. N:\Tailings Management System Procedure\Tai1ings Management System-June 2012\Tai1ings Management System Rev 2.1 June 2012 clean"doc White Mesa Mill -Standard Operating Procedures Book 11: Environmental Protection Manual, Section 3.1 2. March L 2012 to November 1. 2012 The pool surface area would be reduced to the following amount 7/12 Revision: Denison 2.1 Page 36 of37 (1 -225,000 I (2,094,000-1 ,000,000)) x 40 acres= 31.77 acres Based on this reduced pool area, the amount of freeboard would be 197.5 acre feet divided by 31.77 acres equals 6.22 feet. When the wave run up factor for Cell4B of0.77 feet is added to this, the total freeboard required is 6.99 feet. This means that the freeboard limit for Cell4B would be reduced from 5594.6 FMSL to 5592.2 FMSL (5594.6 FMSL minus 6.22 feet, rounded to the nearest one- tenth of a foot). This calculation would be performed at March 1, 2012, and this freeboard limit would persist until November 1, 2012. 3. November 1. 2012 'lo November 1. 2013 The pool surface area would be reduced to the following amount: First, recalculate the pool surface area that should have applied during the previous period, had modeled tonnages (i.e., expected tonnages grossed up by the 150% safety factor) equaled actual tonnages for the period. Since the actual tonnage of225,000 dry tons was the same as the modeled tonnage of225,000 dry tons, the recalculated pool surface area is the same as the modeled pool surface area for the previous period, which is 31.77 acres. Then, calculate the modeled pool surface area to be used for the period: (1 -450,000 I (2,094,000-1,000,000 -225,000)) x 31.77 acres= 15.32 acres Based on this reduced pool area, the amount of freeboard would be 197.5 acre feet divided by 15.32 acres equals 12.89 feet. When the wave run up factor for Cell4B of0.77 feet is added to this, the total freeboard required is 13.66 feet. This means that the freeboard limit for Cell4B would be reduced from 5592.2 FMSL to 5586.7 FMSL (5600.35 FMSL minus 13.66 feet, rounded to the nearest one-tenth of a foot). This calculation would be performed at November 1, 2012, and this freeboard limit would persist until November 1, 2013. 4. November 1, 2013 to November 1, 2014 The pool surface area would be reduced to the following amount: First, recalculate the pool surface area that should have applied during the previous period, had modeled tonnages (i.e., expected tonnages grossed up by the 150% safety factor) equaled actual tonnages for the period. Since modeled tonnages exceeded actual tonnages, the pool area was reduced too much during the previous period, and must be adjusted. The recalculated pool area for the previous period is: (1 -275,000 I (2,094,000-1,000,000-225,000) x 31.77 acres= 21.72 acres. N:\Tailings Management System Procedure\ Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc White Mesa Mill -Standard Operating Procedures Book ll: Environmental Protection Manual, Section 3 .l 7112 Revision: Denison 2.1 Page 37 of37 This recalculated pool surface area will be used as the starting point for the freeboard calculation to be performed at November 1, 2013. Then, calculate the modeled pool surface area to be used for the period: (1-300,000 I (2,094,000 -1,000,000-225,000-275,000)) x 21.72 acres= 10.75 acres Based on this reduced pool area, the amount of freeboard would be 197.5 acre feet divided by 10.75 acres equals 18.37 feet. When the wave run up factor for Cell4B of0.77 feet is added to this, the total freeboard required is 19.14 feet. This means that the freeboard limit for Cell4B would be reduced from 5586.7 FMSL to 5581.2 FMSL (5600.4 FMSL minus 18.4 feet, rounded to the nearest one-tenth of a foot). This calculation would be performed at November 1, 2013, and this freeboard limit would persist until November 1, 2014. N :\Tailings Management System Procedure\Tailings Management System-June 2012\Tailings Management System Rev 2.1 June 2012 clean.doc Appendix J Cell2 Slimes Drain Calculations and Figure 2009-2013 n tD --N (,/) --· 3 1 Vl tD ro ..... "' ;;:;· Vl c N .., QJ -· ::::J I N 0 0 U) .. .-- N :;- 0 ro QJ ..... ~ 0 VI ro .. ..... ;;:;· N Vl N 0 ~ ~ .. N 0 ~ N .. 20 N 0 ~ w N .j:>. 0 0 N N 0 0 Feet Below Top of Standpipe N 0 0 0 1-' 00 0 0 1-' 0"1 0 0 1-' .j:>. 0 0 I I I •n ;J 11/30/2009 3/30/2009 5/30/2009 7/30/2009 9/30/2009 11/30/2009 1/31/2010 -3/31/2010 -5/31/2010 7/31/2010 9/30/2010 11/30/2010 1/31/2011 3/31/2011 5/31/2011 7/31/2011 9/30/2011 -11/30/2011 -1/31/2012 3/31/2012 5/31/2012 7/31/2012 9/30/2012 11/30/2012 -1/31/2013 -3/31/2013 5/31/2013 -7/31/2013 9/30/2013 Table J-1 Cell2 Slimes Drain Recovery Head and SDRE Values from 2009- 2013 2013 Test Closing Elevation of Reported SDRE Values Measurement Point Date (fmsl)** Level (feet) (Reported as fmsl) 3/25/2013 5618.73 21.85 5596.88 6/24/2013 5618.73 22.16 5596.57 9/23/2013 5618.73 22.25 5596.48 11119/2013 5618.73 22.35 5596.38 IE2ol3* 67158.93 N2o13* 12 2012 Test Closing Elevation of Reported SDRE Values Measurement Point Date (fmsl) Level (feet) (Reported as fmsl) 3112/2012 5618.73 20.90 5597.83 5/29/2012 5618.73 21.10 5597.63 9/27/2012 5618.73 21.84 5596.89 12117/2012 5618.73 21.84 5596.89 IE2012* 67167 .72 N2o12* 12 2011 Test Closing Elevation of Reported SDRE Values Measurement Point Date (fmsl) Level (feet) (Reported as fmsl) 112112011 5611.76 13.15 5598.61 2/28/2011 5611.76 10.42 5601.34 3118/2011 5611.76 11.31 5600.45 4/25/2011 5611.76 11.57 5600.19 5/20/2011 5611.76 13.17 5598.59 6/23/2011 5611.76 12.18 5599.58 7/19/2011*** 5611.76 12.59 5599.17 12119/2011 *** 5611.76 12.86 5598.90 IE2o11 * 67192.97 N2ou* 12 Table J-1 Cell 2 Slimes Drain Recovery Head and SDRE Values from 2009- 2013 2010 Test Closing Elevation of Reported SDRE Values Measurement Point Date (fmsl) Level (feet) (Reported as fmsl) 1115/2010 5611.76 13.96 5597.80 2/2112010 5611.76 12.50 5599.26 3/15/2010 5611.76 11.04 5600.72 4112/2010 5611.76 10.40 5601.36 5/19/2010 5611.76 10.43 5601.33 6/30/2010 5611.76 10.13 5601.63 8/2/2010 5611.76 10.74 5601.02 911/2010 5611.76 10.65 5601.11 9/24/2010 5611.76 11.50 5600.26 10/25/2010 5611.76 12.35 5599.41 11/23/2010 5611.76 10.81 5600.95 12/22/2010 5611.76 11.58 5600.18 IE20io* 67205.03 N2o10* 12 2009 Test Closing Elevation of Reported SDRE Values Measurement Point Date (fmsl) Level (feet) (Reported as fmsl) 1130/2009 5614.83 11.25 5603.58 2/27/2009 5614.83 9.35 5605.48 3/28/2009 5614.83 8.84 5605.99 4/27/2009 5614.83 11.98 5602.85 5/20/2009 5614.83 10.28 5604.55 6/22/2009 5614.83 13.00 5601.83 7/30/2009 5614.83 13.00 5601.83 8/31/2009 5614.83 11.04 5603.79 9/28/2009 5614.83 11.46 5603.37 10/30/2009 5614.83 13.35 5601.48 11/23/2009 5614.83 12.49 5602.34 12/14/2009 5614.83 13.12 5601.71 IE2oo9* 67238.80 N2oo9 12 *Per the requirement of the GWDP Part I.D.3 when monthly and quarterly measurements are combined in the GWDP required equation, the quarterly values shall be multiplied by a coefficient of three (3). ** The standpipe elevation was extended and surveyed in 2011. This change in elevation has no effect on the resulting slimes drain elevation values listed in and used in the calculations. ***Per the Permit Part I.D.3.(b).2 effective July 11, 2011, the frequency of the Cell2 slimes drain recovery tests was changed from monthly to quarterly. Table J-2 ' Cell 2 Slimes Drain ~ -.. Annual SDRE C0'ilipliance Data Date Submitted Compliance for Compared to in the DMT Calendar year* SDRE Value (fmsl) Calendar Year* SDRE Value (fmsl) Difference (ft.) Report** 2013 5597.77 2012 5599.05 1.28 1/29/2014 2012 5599.05 2011 5600.00 0.95 2/28/2013 2011 5600.00 2010 5600.25 0.25 2/27/2012 2010 5603.32 2009 5603.23 -0.09 2/25/2011 2009 5603.33 2008 5603.63 0.30 2/26/2010 Annual slimes drain compliance was not achieved in accordance with Part 1.0.3 ofthe Permit in 2010. However, it was determined that noncompliance was due to the frequent downtime of the slimes drain pump in order to meet monthly sampling requirements. As such the frequency of the slimes drain recovery tests was changed from monthly to quarterly in accordnace with Part 1.0.3.(b).2 ofthe Permit effective July 11, 2011. Annual compliance has been achieved each year since the monitoring frequency was changed. * -Annual slimes drain compliance is determined by calculating the 3 year average as required by Part 1.0.3 of the Permit, dated August 24, 2012. **-The details of the annual slimes drain compliance calculations and the supporting data can be found the in 4th Quarter OMT reports which were submitted to UOEQ on the dates provided in the table above. Appendix K White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) Date 6/6/2012 Revision 7.2 Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) WHITE MESA URANIUM MILL GROUNDWATER MONITORING QUALITY ASSURANCE PLAN (QAP) State of Utah Groundwater Discharge permit No. UGW370004 Denison Mines (USA) Corp. P.O. Box 809 Blanding, UT 84511 Page I of61 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) TABLE OF CONTENTS Date: 06-06-12 Revision 7.2 Page 2 of61 1.0 INTRODUCTION 6 2.0 ORGANIZATION AND RESPONSIBILITIES 6 2.1 Functional Groups 6 2.2 Overall Responsibility For the QA/QC Program 6 2.3 Data Requestors/Users 6 2.4 Data Generators 7 2.4.I Sampling and QC Monitors 7 2.4.2 Analysis Monitor 8 2.4.3 Data Reviewers/Approvers 8 2.5 Responsibilities Of Analytical Laboratory 8 3.0 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT OF DATA 9 3.1 Precision 9 3.2 Accuracy 10 3.3 Representativeness 10 3.4 Completeness 10 3.5 Comparability 10 4.0 FIELD SAMPLING QUALITY ASSURANCE METHODOLOGY 11 4.1 Controlling Well Contamination 11 4.2 Controlling Depth to Groundwater Measurements 11 4.3 Water Quality QC Samples 11 4.3.I VOC Trip Blanks 1I 4.3.2 Equipment Rinsate Samples II 4.3.3 Field Duplicates 12 4.3.4 Defmition of"Batch" 12 5.0 CALIDRA TION 12 5.1 Depth to Groundwater Measurements 12 5.2 Water Quality 12 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 3 of61 6.0 GROUNDWATER SAMPLING AND MEASUREMENT OF FIELD PARAMETERS 12 6.1 Groundwater Head Monitoring 12 6.1.1 Location and Frequency of Groundwater Head Monitoring 13 6.1.2 Groundwater Head Monitoring Frequency 13 6.2 Ground Water Compliance Monitoring 13 6.2.1 Location and Frequency of Groundwater Compliance Monitoring 13 6.2.2 Quarterly and Semi-Annual Sampling Required Under Parts I.E.l.b) or I.E.l.c) of the GWDP 14 6.2.3 Quarterly or Monthly Sampling Required Under Paragraphs I.G.1 or I.G.2 of the GWDP 14 6.2.4 Sampling Equipment for Groundwater Compliance Monitoring 14 6.2.5 Decontamination Procedure 15 6.2.6 Pre-Purging/ Sampling Activities 15 6.2. 7 Well Purging/Measurement of Field Parameters 15 6.2.8 Samples to be taken and order of taking samples 16 7.0 SAMPLE DOCUMENTATION TRACKING AND RECORD KEEPING 16 7.1 Field Data Worksheets 16 7.2 Chain-Of-Custody and Analytical Request Record I 7 7.3 Record Keeping 18 8.0 ANALYTICAL PROCEDURES AND QA/QC 18 8.1 Analytical Quality Control 19 8.1.2 Spikes, Blanks and Duplicates 19 8.2 Analytical Laboratory Procedures 20 9.0 INTERNAL QUALITY CONTROL CHECKS 24 9.1 Field QC Check Procedures 24 9.1.1 Review of Compliance With the Procedures Contained in this QAP 24 9.1.2 Analyte Completeness Review 24 9.1.3 Blank Comparisons 24 9.1.4 Duplicate Sample Comparisons 25 9.2 Analytical Laboratory QA Reviews 26 9.3 QA Manager Review of Analytical Laboratory Results and Procedures 26 9.4 Analytical Data 27 10.0 CORRECTIVE ACTION 28 10.1 When Corrective Action is Required 28 10.2 Procedure for Corrective Action 28 Mill-Groundwater Discharge Permit Date: 06-06-12 Revision 7.2 Groundwater Monitoring Quality Assurance Plan (QAP) Page 4 of 61 11.0 REPORTING 29 12.0 SYSTEM AND PERFORMANCE AUDITS 30 12.1 QA Manager to Perform System Audits and Performance Audits 30 12.2 System Audits 30 12.3 Performance Audits 31 12.4 Follow-Up Actions 31 12.5 Audit Records 31 13.0 PREVENTIVE MAINTENANCE 31 14.0 QUALITY ASSURANCE REPORTS TO MANAGEMENT 32 14.1 Ongoing QA/QC Reporting 32 14.2 Periodic Reporting to Management 32 15.0 AMENDMENT 32 16.0 REFERENCES 33 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) ATTACHMENTS Attachment 1 Field and Data Forms Attachment 1-1 Quarterly Depth to Water Data Sheet Date: 06-06-12 Revision 7.2 Page 5 of61 Attachment 1-2 White Mesa Uranium Mill Field Data Work Sheet for Groundwater Attachment 1-3 Example COC Forms Attachment 2 Field Procedures Attachment 2-1 Groundwater Head (Depth to Water) Measurement Procedures Attachment 2-2 Decontamination Procedures Attachment 2-3 Purging Procedures Attachment 2-4 Sample Collection Procedures Attachment 2-5 Field QC Samples APPENDICES Appendix A Chloroform Investigation Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Appendix B Nitrate Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 1.0 INTRODUCTION Date: 06-06-12 Revision 7.2 Page 6 of61 This Groundwater Monitoring Quality Assurance Plan (the "QAP") details and describes all sampling equipment, field methods, laboratory methods, qualifications of environmental analytical laboratories, data validation, and sampling and other corrective actions necessary to comply with UAC R317-6-6.3(1) and (L) at the White Mesa Uranium Mill (the "Mill"), as required under paragraph I.H.6 of State of Utah Groundwater Discharge Permit No. UGW370004 (the "GWDP") for the Mill. This Procedure incorporates the applicable provisions of the United States Environmental Protection Agency ("EPA") RCRA Groundwater Monitoring Technical Enforcement Guidance Document (OSWER-9950.1, September, 1986), as updated by EPA's RCRA Ground-Water Monitoring: Draft Technical Guidance (November 1992). Activities in an integrated program to generate quality data can be classified as management (i.e., quality assurance or "QA") and as functional (i.e., quality control or "QC"). The objective of this QAP is to ensure that monitoring data are generated at the Mill that meet the requirements for precision, accuracy, completeness, representativeness and comparability required for management purposes and to comply with the reporting requirements established by applicable permits and regulations. 2.0 ORGANIZATION AND RESPONSIBILITIES 2.1 Functional Groups This QAP specifies roles for a QA Manager as well as representatives of three different functional groups: the data users; the data generators, and the data reviewers/approvers. The roles and responsibilities of these representatives are described below. 2.2 Overall Responsibility For the QA/QC Program The overall responsibility for ensuring that the QA/QC measures are properly employed is the responsibility of the QA Manager. The QA Manager is typically not directly involved in the data generation (i.e., sampling or analysis) activities. The QA Manager is designated by Denison Mines (USA) Corp. ("DUSA") corporate management. 2.3 Data Requestors/Users The generation of data that meets the objectives of this QAP is necessary for management to make informed decisions relating to the operation of the Mill facility, and to comply with the reporting requirements set out in the GWDP and other permits and applicable regulations. Accordingly, the data requesters/users (the "Data Users") are therefore DUSA's corporate management and regulatory authorities through the implementation of such permits and regulations. The data quality objectives ("DQOs") required for any groundwater sampling event, such as acceptable minimum detection limits, are specified in this QAP. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 2.4 Data Generators Date: 06-06-12 Revision 7.2 Page 7 of61 The individuals who carry out the sampling and analysis activities at the request of the Data Users are the data generators. For Mill activities, this involves sample collection, record keeping and QA/QC activities conducted by one or more sampling and quality control/data monitors (each a "Sampling and QC Monitor"). The Sampling and QC Monitors are qualified Mill personnel as designated by the QA Manager. The Sampling and QC Monitors perform all field sampling activities, collect all field QC samples and perform all data recording and chain of custody activities in accordance with this QAP. Data generation at the contract analytical laboratory (the "Analytical Laboratory") utilized by the Mill to analyze the environmental samples is performed by or under an employee or agent (the "Analysis Monitor") of the Analytical Laboratory, in accordance with specific requirements of the Analytical Laboratory's own QA/QC program. The responsibilities ofthe data generators are as follows: 2.4.1 Sampling and QC Monitors The Sampling and QC Monitors are responsible for field activities. These include: a) Ensuring that samples are collected, preserved, and transported as specified in this QAP; b) Checking that all sample documentation (labels, field data worksheets, chain-of- custody records,) is correct and transmitting that information, along with the samples, to the Analytical Laboratory in accordance with this QAP; c) Maintaining records of all samples, tracking those samples through subsequent processing and analysis, and, ultimately, where applicable, appropriately disposing of those samples at the conclusion of the program; d) Preparing quality control samples for field sample collection during the sampling event; e) Preparing QC and sample data for review by the QA Manager; and t) Preparing QC and sample data for reporting and entry into a computerized database, where appropriate. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 2.4.2 Analysis Monitor Date: 06-06-12 Revision 7.2 Page 8 of61 The Analysis Monitor is responsible for QA/QC activities at the Analytical Laboratory. These include: a) Training and qualifying personnel in specified Analytical Laboratory QC and analytical procedures, prior to receiving samples; b) Receiving samples from the field and verifying that incoming samples correspond to the packing list or chain-of-custody sheet; and c) Verifying that Analytical Laboratory QC and analytical procedures are being followed as specified in this QAP, by the Analytical Laboratory's QA/QC program, and in accordance with the requirements for maintaining National Environmental Laboratory Accreditation Program ("NELAP") certification. 2.4.3 Data RcviewcJ'S/ Approvers The QA Manager has broad authority to approve or disapprove project plans, specific analyses and final reports. In general, the QA Manager is responsible for reviewing and advising on all aspects of QA/QC, including: a) Ensuring that the data produced by the data generators meet the specifications set out in this QAP; b) Making on-site evaluations and submitting audit samples to assist in reviewing QA/QC procedures; c) Determining (with the Sampling and QC Monitor and Analysis Monitor) appropriate sampling equipment and sample containers, in accordance with this QAP, to minimize contamination; and d) Supervising all QA/QC measures to assure proper adherence to this QAP and determining corrective measures to be taken when deviations from this QAP occur. The QA Manager may delegate certain of these responsibilities to one or more Sampling and QC Monitors or to other qualified Mill personnel. 2.5 Responsibilities Of Analytical Laboratory Unless otherwise specified by DUSA corporate management, all environmental analysis of groundwater sampling required by the GWDP or by other applicable permits, will be performed by a contract Analytical Laboratory. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 9 of61 The Analytical Laboratory is responsible for providing sample analyses for groundwater monitoring and for reviewing all analytical data to assure that data are valid and of sufficient quality. The Analytical Laboratory is also responsible for data validation in accordance with the requirements for maintaining NELAP certification. In addition, to the extent not otherwise required to maintain NELAP certification, the Analytical Laboratory must adhere to U. S. EPA Guideline SW-846 and, to the extent consistent with NELAP and EPA practices, the applicable portions of NRC Regulatory Guide 4.14. The Analytical Laboratory will be chosen by DUSA and must satisfy the following criteria: (1) experience in analyzing environmental samples with detail for precision and accuracy, (2) experience with similar matrix analyses, (3) operation of a stringent internal quality assurance program meeting NELAP certification requirements and that satisfies the criteria set out in Section 8 below, (4) ability to satisfy radionuclide requirements as stipulated in the applicable portions ofNRC Regulatory Guide 4.14, and (5) certified by the State ofUtah for and capable of performing the analytical methods set out in Table 1. The analytical procedures used by the Analytical Laboratory will be in accordance with Utah Administrative Code R317-6-6.3L. 3.0 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT OF DATA The objective of this QAP is to ensure that monitoring data are generated at the Mill that meet the requirements for precision, accuracy, representativeness, completeness, and comparability required for management purposes and to comply with the reporting requirements established by applicable permits and regulations (the Field and Analytical QC samples described in Sections 4.3 and 8.1 below are designed to ensure that these criteria are satisfied). Data subject to QA/QC measures are deemed more reliable than data without any QA/QC measures. 3.1 Precision Precision is defined as the measure of variability that exists between individual sample measurements of the same property under identical conditions. Precision is measured through the analysis of samples containing identical concentrations of the parameters of concern. For duplicate measurements, precision is expressed as the relative percent difference ("RPD") of a data pair and will be calculated by the following equation: RPD = [(A-B)/{(A+B) /2}] X 100 Where A (original) and B (duplicate) are the reported concentration for field duplicate samples analyses (or, in the case of analyses performed by the Analytical Laboratory, the percent recoveries for matrix spike and matrix spike duplicate samples) (EPA SW -846, Chapter 1, Section 5.0, page 27-28). Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 3.2 Accuracy Date: 06-06-12 Revision 7.2 Page 10 of61 Accuracy is defined as a measure of bias in a system or as the degree of agreement between a measured value and a known value. The accuracy of laboratory analyses is evaluated based on analyzing standards of known concentration both before and during analysis. Accuracy will be evaluated by the following equation: %Recovery= (I A-B I /C) x 100 Where: A = the concentration of analyte in a sample B =the concentration of analyte in an unspiked sample C = the concentration of spike added 3.3 Representativeness Representativeness is defined as the degree to which a set of data accurately represents the characteristics of a population, parameter, conditions at a sampling point, or an environmental condition. Representativeness is controlled by performing all sampling in compliance with this QAP. 3.4 Completeness Completeness refers to the amount of valid data obtained from a measurement system in reference to the amount that could be obtained under ideal conditions. Laboratory completeness is a measure of the number of samples submitted for analysis compared to the number of analyses found acceptable after review of the analytical data. Completeness will be calculated by the following equation: Completeness = (Number of valid data points/total number of measurements) x 100 Where the number of valid data points is the total number of valid analytical measurements based on the precision, accuracy, and holding time evaluation. Completeness is determined at the conclusion ofthe data validation. Executive Secretary approval will be required for any completeness less than 100 percent. 3.5 Comparability Comparability refers to the confidence with which one set of data can be compared to another measuring the same property. Data are comparable if sampling conditions, collection techniques, measurement procedures, methods, and reporting units are consistent for all samples within a sample set. Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) . Date: 06-06-12 Revision 7.2 Page 11 of61 4.0 FIELD SAMPLING QUALITY ASSURANCE METHODOLOGY 4.1 Controlling Well Contamination Well contamination from external surface factors, is controlled by installation of a cap over the surface casing and cementing the surface section of the drill hole. Wells have surface covers of mild steel with a lockable cap cover. Radiation Safety staff has access to the keys locking the wells. 4.2 Controlling Depth to Groundwater Measurements Monitoring of depth to groundwater is controlled by comparing historical field data to actual measurement depth. This serves as a check of the field measurements. 4.3 Water Quality QC Samples Quality assurance for groundwater monitoring consists of the following QC samples: 4.3.1 VOC Trip Blanks Trip blanks will be used to assess contamination introduced into the sample containers by volatile organic compounds ("VOCs") through diffusion during sample transport and storage. At a minimum (at least) one trip blank will be in each shipping container containing samples to be analyzed for VOCs. Trip blanks will be prepared by the Analytical Laboratory, transported to the sampling site, and then returned to the Analytical Laboratory for analysis along with the samples collected during the sampling event. The trip blank will be unopened throughout the transportation and storage processes and will accompany the technician while sampling in the field. 4.3.2 Equipment Rinsate Samples Where portable (non-dedicated) sampling equipment is used, a rinsate sample will be collected at a frequency of one rinsate sample per 20 field samples. Rinsate blanks will be collected after decontamination and prior to subsequent use. Rinsate blank samples for a non-dedicated pump are prepared by pumping de-ionized water into the sample containers. Rinsate blank samples for a non-disposable or non-dedicated bailerare prepared by pouring de-ionized water over and through the bailer and into the sample containers. Equipment rinsate blanks will be analyzed only for the contaminants required during the monitoring event in which they are collected. Equipment rinsate blank sampling procedures are described in Attachments 2-2 and 2-5. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 12 of61 4.3.3 Field Duplicates Field duplicate samples are collected at a frequency of one duplicate per 20 field samples. Field duplicates will be submitted to the Analytical Laboratory and analyzed for the same constituents as the parent sample. Field duplicate sampling procedures are described in Attachment 2-5. 4.3.4 Definition of "Batch" For the purposes of this QAP, a Batch is defined as 20 or fewer samples. 5.0 CALIBRATION A fundamental requirement for collection of valid data is the proper calibration of all sample collection and analytical instruments. Sampling equipment shall be calibrated in accordance with manufacturers' recommendations, and Analytical Laboratory equipment shall be calibrated in accordance with Analytical Laboratory procedures. 5.1 Depth to Groundwater Measurements Equipment used in depth to groundwater measurements will be checked prior to each use as noted in Attachment 2 to ensure that the Water Sounding Device is functional. 5.2 Water Quality The Field Parameter Meter will be calibrated prior to each sampling event and at the beginning of each day of the sampling event according to manufacturer's specifications (for example, by using two known pH solutions and one specific conductance standard.) Temperature will be checked comparatively by using a thermometer. Calibration results will be recorded on the Field Data Worksheet. 6.0 GROUNDWATER SAMPLING AND MEASUREMENT OF FIELD PARAMETERS 6.1 Groundwater Head Monitoring Groundwater head measurements ("depth to water") will be completed as described in Attachment 2 using the equipment specified in Attachment 2. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 6.1.1 Location and Frequency of Groundwater Head Monitoring Date: 06-06-12 Revision 7.2 Page 13 of61 Depth to groundwater shall be measured quarterly in the following wells and piezometers: a) All Point of Compliance wells listed in the GWDP Parts I.E.1 (b) and (c) and I.E.2; b) Monitoring well MW-34; c) All piezometers (P-1, P-2, P-3, P-4, P-5 and the Dry Ridge piezometers); d) All contaminant investigation wells required by the Executive Secretary as part of a contaminant investigation or groundwater corrective action (chloroform and nitrate wells). 6.1.2 Groundwater Head Monitoring Frequency Depth to groundwater is measured and recorded in any well that is being sampled for groundwater quality prior to sampling. In addition, a depth to groundwater measurement campaign will be completed each quarter. The data from the quarterly campaign will be used for modeling purposes and will be completed within a 5 day period. The data from the quarterly campaign will be recorded on a data sheet. An example of a Quarterly Depth to Water data sheet is included Attachment 1. Data from the quarterly depth to water campaign will be recorded by hand on hardcopy forms in the field, but may be entered into an electronic data management system (spreadsheet or database). The data from the quarterly depth to water measurements will be included in the quarterly groundwater report. The depth to groundwater measured immediately prior to purging/sampling will be recorded on data sheet for each well. An example of a Field Data Work Sheet for Groundwater is included in Attachment 1. The data sheets included herein are examples and may be changed to accommodate additional data collection. If a change is made to a data sheet to accommodate additional information, a copy will be provided to the Executive Secretary. Changes to field forms will not eliminate any data collection activity without written approval of the Executive Secretary. 6.2 Ground Water Compliance Monitoring 6.2.1 Location and Frequency of Groundwater ompliance Monitorin-g Groundwater quality shall be measured in the following wells at the following frequencies: Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 14 of61 a) Semi-annually in the following Point of Compliance wells: MW-1, MW-2, MW- 3, MW-3A, MW-5, MW-12, MW-15, MW-17, MW-18, MW-19, MW-23, MW- 24, MW-27, MW-28, MW-29, and MW-32; b) Semi-annually in the following General Monitoring Wells: MW-20 and MW-22; c) Quarterly in the following Point of Compliance wells: MW-11, MW-14, MW-25, MW-26, MW-30, MW-31, MW-35, MW-36 and MW-37; and d) Quarterly in the Chloroform Investigation and Nitrate Corrective Action wells. In addition, quarterly or monthly sampling may be required for certain parameters in certain wells based on the requirements specified in Parts I.G.1 or I.G.2 of the GWDP. Sampling personnel should coordinate with the QA Manager prior to conducting any monitoring well sampling to determine if any parameters in any wells are subject to accelerated monitoring. 6.2.2 Quarhwly and Scmi..;A.bn ual Sampling Required Under Part I.E.l.b) m· I.E.l.c) ofthc GWDP All quarterly and semi-annual samples collected under.Parts I.E.l.b) or I.E.l.c) ofthe GWDP shall be analyzed for the following parameters: a) Field parameters-depth to groundwater, pH, temperature, specific conductance, redox potential (Eh) and turbidity; and b) Laboratory Parameters: (i) All parameters specified in Table 2 of the GWDP; and (ii) General inorganics -chloride, sulfate, carbonate, bicarbonate, sodium potassium, magnesium, calcium, and total anions and cations. 6.2.3 Quartel'ly m· Monthly Sampling Regui1·ed Under Paragraphs 1.G.l or LG.2 of the GWDP Any quarterly or monthly accelerated sampling required under paragraphs I.G.l. or I.G.2. of the GWDP shall be analyzed for the specific parameters as required by previous sampling results as determined by the QA Manager. 6.2.4 Sampling Equipment for· Gro,md:water Compliance Monitoring All equipment used for purging and sampling of groundwater which enters the well or may otherwise contact sampled groundwater, shall be made of inert materials. Purging and sampling equipment is described in Attachment 2-3 of this QAP. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 15 of61 Field parameters are measured by using a flow cell system that enables the measurements to be taken on a real-time basis without exposing the water stream to the atmosphere; 6.2.5 Decontamination Procedure Portable (non-dedicated) sampling equipment will be decontaminated prior to each sampling event, at the beginning of each day during the sampling event, and between each sampling location (well). Non-dedicated sampling equipment will be decontaminated using the procedure described in Attachment 2-2. 6.2.6 Pre-Purging/ Sampling Activities Pre-purging and sampling activities are described in Attachment 2-3 . The purging and sampling techniques used at each well will be a function of the well's historic recovery rates, the equipment used for purging, and the analytical suite to be completed. 6.2.7 Well Purging/Measurement of Field Parameters The purging techniques described in Attachment 2-3 will be used for all groundwater sampling conducted at the Mill unless otherwise stated in the program-specific QAPs for the chloroform and nitrate investigations. The program-specific QAPs for the chloroform and nitrate investigations are included as Appendix A and Appendix B respectively. Purging wells prior to sampling removes the stagnant water column present in the well casing and assures that representative samples of the formation water are collected. Purging will be completed as described in Attachment 2-3. There are three purging strategies that will be used to remove stagnant water from the well casing during groundwater sampling at the Mill. The three strategies are as follows: 1. Purging three well casing volumes with a single measurement of field parameters 2. Purging two casing volumes with stable field parameters (within 10% RPD) 3. Purging a well to dryness and stability of a limited list of field parameters after recovery Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 16 of61 6.2.8 Samples to be taken and order of taking samples For each quarterly or semi-annual sampling event, samples will be collected for the analyte specified in Table 2 of the GWDP. The following is a list of the sample containers that will be collected to provide sample aliquots to the Analytical Laboratory for the completion of the analyses specified in Table 2 of the GWDP . The Analytical Laboratory will provide the sampling containers and may request that certain analytes be combined into a single container due to like sampling requirements (filtering) and/or like preservation. The container requirements will be determined by the Analytical Laboratory and specified with the bottles supplied to the Field Personnel. Bottle requirements may change if the Analytical Laboratory is changed or if advances in analytical techniques allow for reduced samples volumes. The following list is a general guideline. a) VOCs, 3 sample containers, 40 ml each; b) Nutrients (ammonia, nitrate and nitrite), 1 sample container, 100 ml; c) All other non-radiologies (fluoride, general inorganics, TDS, total cations and anions), 1 sample container, 250 ml,; and d) Gross alpha and heavy metals, 1 sample container, 1,000 ml, filtered. The sample collection containers and sample volumes for chloroform and nitrate program sampling are specified in Appendices A and B to this document. Accelerated samples will be analyzed for a limited list of analytes as determined by previous sampling results. Only the containers for the specific list of analytes will be collected for accelerated monitoring samples. 7.0 SAMPLE DOCUMENTATION TRACKING AND RECORD KEEPING 7.1 Field Data Worksheets Documentation of observations and data from sampling provide important information about the sampling process and provide a permanent record for sampling activities. All observations and field sampling data will be recorded in waterproof ink on the Field Data Worksheets, which will be maintained on file at the Mill. The Field Data Worksheets will contain the following information: • Name ofthe site/facility • description of sampling event • location of sample (well name) • sampler's name(s) and initials(s) • date(s) and time(s) of well purging and sample collection Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 17 of61 • type of well purging equipment used (pump or bailer) • previous well sampled during the sampling event • well depth • depth to groundwater before purging and sampling • field measurements (pH, specific conductance, water temperature, redox potential, turbidity) • calculated well casing volume • volume of water purged before sampling • volume of water purged when field parameters are measured • type and condition of well pump • description of samples taken • sample handling, including filtration and preservation • volume of water collected for analysis • types of sample containers and preservatives • weather conditions and external air temperature • name of certified Analytical Laboratory. The Field Data Worksheets will also contain detailed notes describing any other significant factors noted during the sampling event, including, as applicable: condition of the well cap and lock; water appearance, color, odor, clarity; presence of debris or solids; any variances from this procedure; and any other relevant features or conditions. An example of a Field Data Worksheet that incorporates this information is attached in Attachment 1. The data sheets included herein are examples and may be changed to accommodate additional data collection. If a change is made to a data sheet to accommodate additional information, a copy will be provided to the Executive Secretary. Changes to field forms will not eliminate any data collection activity without written approval of the Executive Secretary. 7.2 Chain-Of-Custody and Analytical Request Record A Chain-of-Custody and Analytical Request Record form (the "COC Form"), provided by the Analytical Laboratory, will accompany the samples being shipped to the Analytical Laboratory. Examples of the Chain of Custody Forms used are attached as Attachment 2. If the Chain of Custody Form changes at any time, the Company shall provide a copy of the new or revised Chain of Custody Form to the Executive Secretary and substitute the new form for the old form in Attachment 2. Standard Chain-of-Custody protocol is initiated for each sample set. A COC Form is to be completed for each set of samples collected in a shipping container (cooler) and is to include the following: • sampler's name • company name • date and time of collection • sample type (e.g., water) Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) • sample location • number of sample containers in the shipping container • analyses requested • signatures of persons involved in the chain of possession Date: 06-06-12 Revision 7.2 Page 18 of61 • internal temperatures of the shipping container when opened at the laboratory • remarks section to identify potential hazards or to relay other information to the Analytical Laboratory. Chain-of-Custody reports will be placed inside a re-sealable bag and taped to the inside lid. Custody seals will be placed on the outside of each cooler. The person shipping the samples to the Analytical Laboratory will sign the COC Form, document shipment method, and send the original and the second copy of the COC Form with the samples. Upon receipt of the samples, the person receiving the samples will sign the COC Form and return the second copy to the Mill's RSO. Copies ofthe COC Forms and other relevant documentation will be retained at the Mill. 7.3 Record Keeping The Field Data Worksheets are retained at the Mill. Data from the Analytical Laboratory, showing the laboratory analytical results for the water samples, are maintained at the Mill. Copies of the current Utah certifications of the Analytical Laboratory or Laboratories and a list of Utah Bureau of Laboratory Improvement approved parameters and methods used to perform analysis during the monitoring events conducted during the quarter will be maintained at the Mill. DUSA will ensure that the Analytical Laboratory or Laboratories used, have certifications for each parameter and method required by Section 8.2, Table 1 of the QAP. Once all the data for the quarter (all wells sampled during the quarter) is completed, key data from the Field Data Worksheets and from the data packages are managed using electronic data management software The data management software will be managed and administered by the QA Manager or designee. The Mill Personnel will have read-only access to the electronic data management software. 8.0 ANALYTICAL PROCEDURES AND QA/QC Analytical Laboratory QA provides a means for establishing consistency in the performance of analytical procedures and assuring adherence to analytical methods utilized. Analytical Laboratory QC programs include traceability of measurements to independent reference materials and internal controls. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 8.1 Analytical Quality Control Date: 06-06-12 Revision 7.2 Page 19 of61 Analytical QA/QC will be governed by the QA/QC program of the Analytical Laboratory. In choosing and retaining the Analytical Laboratory, DUSA shall ensure that the Analytical Laboratory is certified by the State of Utah and by NELAP, is capable of performing the analytical procedures specified in Section 8.2, and that the QA/QC program of the Analytical Laboratory includes the spikes, blanks and duplicates described in Section 8.1.2. 8.1.2 Spikes, Blanks and Duplicates Analytical Laboratory QC samples will assess the accuracy and precision of the analyses. The following describes the type of QC samples that will be used by the Analytical Laboratory to assess the quality of the data. The following procedures shall be performed at least once with each analytical Batch of samples: a) Matrix Spike/Matrix Spike Duplicate A spiked field sample analyzed in duplicate may be analyzed with every analytical batch (depending on the analytical method requirements and or method limitations). Analytes stipulated by the analytical method, by applicable regulations, or by other specific requirements may be spiked into the samples. Selection of the sample to be spiked depends on the information required and the variety of conditions within a typical matrix. The matrix spike sample serves as a check evaluating the effect of the sample matrix on the accuracy of analysis. The matrix spike duplicate serves as a check of the analytical precision. b) Method Blanks Each analytical batch shall be accompanied by a method blank. The method blank shall be carried through the entire analytical procedure. Contamination detected in analysis of method blanks will be used to evaluate any Analytical Laboratory contamination of environmental samples which may have occurred. c) Surrogate Compounds Every blank, standard, and environmental sample (including matrix spike/matrix duplicate samples) for analysis ofVOCs (or other organics only) shall be spiked with surrogate compounds prior to purging or extraction. Surrogates are organic compounds which are similar to analytes of interest in chemical composition, extraction, and chromatography, but which are not normally found in environmental samples. Surrogates shall be spiked into samples according to the appropriate organic analytical methods. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) d) Check ample Date: 06-06-12 Revision 7.2 Page 20 of61 Each analytical batch shall contain a number of check samples. For each method, the Analytical Laboratory will normally analyze the following check samples or their equivalents: a method blank, a laboratory control spike, a matrix spike, and a matrix spike duplicate, or the equivalent, with relative percent difference reported. 8.2 Analytical Laboratory Procedures The analytical procedures to be used by the Analytical Laboratory will be as specified in Table 1, or as otherwise authorized by the Executive Secretary. With respect to Chloroform Investigation and Nitrate Corrective Action sampling, the analytical procedures for parameters monitored under those programs are specified in Appendix A and B respectively. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Contaminant Analytical Methods to be Used Nutrients Ammonia (as N) A4500- NH3 Gor E350.1 Nitrate & N itrite E353.1 or (as N) E353.2 Heavy Metals Arsenic E200.7 or E200.8 Beryllium E200.7 or E200.8 Cadmium E200.7 or E200.8 Chromium E200.7 or E200.8 Cobalt E200.7 or E200.8 Copper E200.7 or E200.8 Iron E200.7 or E200.7 Lead E200.7 or E200.8 Manganese E200.7 or E200.8 Mercury E 245.1 or E200.7 or E200.8 Molybdenum E200.7 or E200.8 Nickel E200.7 or E200.8 Selenium E200.7 or E200.8 Silver E200.7 or E200.8 Thallium E200.7 or E200.8 Date: 06-06-12 Revision 7.2 Page 21 of61 Table 1 Reporting Maximum Sample Sample Limit1 Holding Preservation Temperature Times Requirement Requirements s 0.05 mg/L 28 days H2S0 4 to .:5 6°C pH<2 0.1 mg/L 28 days H2S04 to .:5 6°C pH<2 5 j..tg/L 6 months HN03to pH<2 None 0.50 j..tg/L 6 months HN03to pH<2 None 0.50 j..tg/L 6 months HN03to pH<2 None 25 j..tg/L 6 months HN03to pH<2 None 10 j..tg/L 6 months HN03to pH<2 None 10 j..tg/L 6 months HN03to pH<2 None 30 j..tg/L 6 months HN03to pH<2 None 1.0 j..tg/L 6 months HN03to pH<2 None 10 j..tg/L 6 months HN03to pH<2 None 0.50 j..tg/L 28 days HN03to pH<2 None 10 1-lg/L 6 months HN03to pH<2 None 20 1-lg/L 6 months HN03to pH<2 None 5!-lgiL 6 months HN03to pH<2 None 10 1-lg/L 6 months HN03tO pH<2 None 0.50 1-lg/L 6 months HN03to pH<2 None Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Contaminant Analytical Methods to be Used Tin E200.7 or E200.8 Uranium E200.7 or E200.8 Vanadium E200.7 or E200.8 Zinc E200.7 or E200.8 Radiologies Gross Alpha E 900.0 or E900.1 Volatile Organic Compounds Acetone SW8260B or SW8260C Benzene SW8260B or SW8260C 2-Butanone SW8260B (MEK) or SW8260C Carbon SW8260B Tetrachloride or SW8260C Chloroform SW8260B or SW8260C Chloromethane SW8260B or SW8260C Dichloromethane SW8260B (Methylene or Chloride) SW8260C Naphthalene SW8260B or SW8260C Tetrahydrofuran SW8260B Date: 06-06-12 Revision 7.2 Page22 of61 Reporting Maximum Sample Sample Limie Holding Preservation Temperature Times Requirement Requirements s 100 llg!L 6 months HN03to pH<2 None 0.30 11g/L 6 months HN03to pH<2 None 15 llgiL 6 months HN03to pH<2 None 10 llgiL 6 months HN03to pH<2 None 1.0 pCi/L 6 months HN03to pH<2 None 20 llgiL 14 days HCl to pH<2 ~6°C 1.0 11g/L 14 days HCl to pH<2 .::;6°C 20 11g/L 14 days HCl to pH<2 .::;6°C 1.0 11g/L 14 days HCl to pH<2 .::;6°C 1.0 11g/L 14 days HCl to pH<2 .::;6°C I 1.0 11g/L 14 days HCl to pH<2 .::;6°C 1.0 11g/L 14 days HCl to pH<2 .::;6°C 1.0 11g/L 14 days HCl to pH<2 .::;6°C 1.0 11g/L 14 days HCl to pH<2 .::;6°C Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Contaminant Analytical Methods to be Used or SW8260C Toluene SW8260B or SW8260C Xylenes (total) SW8260B or SW8260C Others Field pH (S.U.) A4500-H B Fluoride A4500-F C or E300.0 TDS A2540 C General In organics Chloride A4500-Cl B or A4500-Cl E or E300.0 Sulfate A4500- S04 E or E300.0 Carbonate as A2320 B C03 Bicarbonate as A2320 B HC03 Sodium E200.7 Potassium E200.7 Magnesium E200.7 Calcium E200.7 Date: 06-06-12 Revision 7.2 Page 23 of61 Reporting Maximum Sample Sample Limit1 Holding Preservation Temperature Times Requirement Requirements s 1.0 ).lg/L 14 days HCl to pH<2 ~6°C 1.0 ).lg/L 14 days HCl to pH<2 <6°C 0.01 s.u. Immediate None None 0.1 mg/L 28 days None None 10 mg/L 7 days None <6°C 1 mg/L 28 days None None 1 mg/L 28 days None :S 6°C 1 mg/L 14 days None :::; 6°C 1 mg/L 14 days None S 6°C 0.5 mg/L 6 months HN03to pH<2 None 0.5 mg/L 6 months HN03to pH<2 None 0.5 mg/L 6 months HN03to pH<2 None 0.5 mg/L 6 months HN03to pH<2 None 1. The Analytical Laboratory will be requrred to meet the reportmg limits ("RLs") in the foregoing Table, unless the RL must be increased due to sample matrix interference (i.e., due to dilution gain), in which case the increased RL will be used, or unless otherwise approved by the Executive Secretary. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 24 of61 9.0 INTERNAL QUALITY CONTROL CHECKS Internal quality control checks are inherent in this QAP. The QA Manager will monitor the performance of the Sample and QC Monitors, and, to the extent practicable, the Analysis Monitor to ensure that they are following this QAP. In addition, either the QA Manager or a Sampling and QC Monitor will review and validate the analytical data generated by the Analytical Laboratory to ensure that it meets the DQOs established by this QAP. Finally, periodic system and performance audits will be performed, as detailed in Section 12 below. 9.1 Field QC Check Procedures The QA Manager will perform the following QA/QC analysis of field procedures: 9.1.1 Review of Compliance With the PJ·ocedure Contained in this QAP Observation of technician performance is monitored by the QA Manager on a periodic basis to ensure compliance with this QAP. 9.1.2 Analyte Completeness Review The QA Manager will review all Analytical Results to confirm that the analytical results are complete (i.e., there is an analytical result for each required constituent in each well). The QA Manager shall also identify and report all instances of non-compliance and non- conformance (see Part I.E.1(a) of the Permit. Executive Secretary approval will be required for any completeness (prior to QAIQC analysis) less than 100 percent. Non-conformance will be defined as a failure to provide field parameter results and analytical results for each parameter and for each well required in Sections 6.2.2 and 6.2.3, for the sampling event, without prior written Executive Secretary approval. 9.1.3 Blank Comparisons Trip blanks, method blanks, and equipment rinsate samples will be compared with original sample results. Non-conformance conditions will exist when contaminant levels in the samples(s) are not order of magnitude greater than the blank result. (TEGD, Field QA/QC Program, page 119). Corrective actions for blank comparison non-conformance shall first determine if the non- conformance is a systematic issue which requires the procedures described in Section 10. If the non-conformance is limited in scope and nature, the QA Manager will 1. Review the data and determine the overall effect to the data quality, 2. Notify the laboratory ofthe discrepancy (if it is a laboratory generated blank), and 3. Request the laboratory review all analytical results for transcription and calculation errors, and (for laboratory generated blanks) Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 25 of61 4. If the samples are still within holding time, the QA Manager may request the laboratory re-analyze the affected samples. If re-analysis is not possible, qualifiers may be applied to the samples associated with a non-conforming blank. Recommendations regarding the usability of the data may be included in the quarterly report. 9.1.4 Duplicate Sample Comparisons The following analyses will be performed on duplicate field samples: a) Relative Percent Difference. RPDs will be calculated in comparisons of duplicate and original field sample results. Non-conformance will exist when the RPD :::._20%, unless the measured concentrations are less than 5 times the required detection limit (Standard Methods, 1998) (EPA Contract Laboratory Program National Functional Guidelines for Inorganic Data Review, February 1994,9240.1-05-01, p. 25). b) Radiologies Counting Error Term All gross alpha analyses shall be reported with an error term. All gross alpha analysis reported with an activity equal to or greater than the GWCL, shall have a counting variance that is equal to or less that 20% of the reported activity concentration. An error term may be greater than 20% of the reported activity concentration when the sum of the activity concentration and error term is less than or equal to the GWCL. c) Radiologies, Duplicate Samples Comparability of results between the original and duplicate radiologic samples will be evaluated by determining compliance with the following formula: Where: A = the first duplicate measurement B = the second duplicate measurement s/ = the uncertainty of the first measurement squared sb 2 = the uncertainty of the second measurement squared Non-conformance exists when the foregoing equation is> 2. (EPA Manual for the Certification of Laboratories Analyzing Drinking Water, Criteria and Procedures Quality Assurance, January 2005, EPA 815-R-05-004, p. VI-9). Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 26 of61 Corrective actions for duplicate deviations shall first determine if the deviation is indicative of a systematic issue which requires the procedures described in Section 10. If the non- conformance is limited in scope and nature, the QA Manager will: 1. Notify the laboratory, 2. Request the laboratory review all analytical results for transcription and calculation errors, and 3. If the samples are still within holding time, the QA Manager may request the laboratory re-analyze the affected samples. 9.2 Analytical Laboratory QA Reviews Full validation will include recalculation of raw data for a minimum of one or more analytes for ten percent of the samples analyzed. The remaining 90% of all data will undergo a QC review which will include validating holding times and QC samples. Overall data assessment will be a part of the validation process as well. The Analysis Monitor or data validation specialist will evaluate the quality of the data based on SW-846, the applicable portions ofNRC guide 4.14 and on analytical methods used. The reviewer will check the following: (1) sample preparation information is correct and complete, (2) analysis information is correct and complete, (3) appropriate Analytical Laboratory procedures are followed, (4) analytical results are correct and complete, (5) QC samples are within established control limits, (6) blanks are within QC limits, (7) special sample preparation and analytical requirements have been met, and (8) documentation is complete. The Analytical Laboratory will prepare and retain full QC and analytical documentation. The Analytical Laboratory will report the data as a group of one batch or less, along with the QA/QC data. The Analytical Laboratory will provide the following information: (1) cover sheet listing samples included in report with a narrative, (2) results of compounds identified and quantified, (3) reporting limits for all analytes, and (4) QA/QC analytical results. 9.3 QA Manager Review of Analytical Laboratory Results and Procedures The QA Manager shall perform the following QA reviews relating to Analytical Laboratory procedures: a) Reporting Limit (RL) Comparisons Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 27 of61 The QA Manager shall confirm that all reporting limits used by the Analytical Laboratory are in conformance with the reporting limits set out on Table 1. Non-conformance shall be defined as: 1) a reporting limit that violates these provisions, unless the reporting limit must be increased due to sample matrix interference (i.e., due to dilution); or 2) a reporting limit that exceeds the respective GWQS listed in Table 2 of the GWDP unless the reported concentration is greater than the raised reporting limit. b) Laboratory Methods Review The QA Manager shall confirm that the analytical methods used by the Analytical Laboratory are those specified in Table 1, unless otherwise approved by the Executive Secretary. Non-conformance shall be defined when the Analytical Laboratory uses analytical methods not listed in Table 1 and not otherwise approved by the Executive Secretary. c) Holding Time Examination_ The QA Manager will review the analytical reports to verify that the holding time for each contaminant was not exceeded. Non-conformance shall be defined when the holding time is exceeded. d) Sample Temperature Examination The QA Manager shall review the analytical reports to verify that the samples were received by the Analytical Laboratory at a temperature no greater than the approved temperature listed in Table 1. Non-conformance shall be defined when the sample temperature is exceeded. 9.4 Analytical Data All QA/QC data and records required by the Analytical Laboratory's QA/QC program shall be retained by the Analytical Laboratory and shall be made available to DUSA as requested. Analytical data submitted by the Analytical Laboratory should contain the date/time the sample was collected, the date/time the sample was received by the Analytical Laboratory, the date/time the sample was extracted (if applicable), and the date/time the sample was analyzed. All out-of-compliance results will be logged by the Analysis Monitor with corrective actions described as well as the results of the corrective actions taken. All raw and reduced data will be stored according to the Analytical Laboratory's record keeping procedures and QA program. All Analytical Laboratory procedures and records will be available for on-site inspection at any time during the course of investigation. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 28 of61 If re-runs occur with increasing frequency, the Analysis Monitor and the QA Manager will be consulted to establish more appropriate analytical approaches for problem samples. 10.0 CORRECTIVE ACTION 10.1 When Corrective Action is Required The Sampling and QC Monitors and Analytical Laboratory are responsible for following procedures in accordance with this QAP. Corrective action should be taken for any procedural or systematic deficiencies or deviations noted in this QAP. All deviations from field sampling procedures will be noted on the Field Data Worksheets or other applicable records. Any QA/QC problems that arise will be brought to the immediate attention of the QA Manager. Analytical Laboratory deviations will be recorded by the Analysis Monitor in a logbook as well. When a procedural or systematic non-conformance is identified, DUSA shall: a) When non-conformance occurs as specified in Sections 9.1.3 or 9.1.4 the data shall be qualified to denote the problem and the QC sample-specific corrective actions in Sections 9.1.3, 9.1.4 or 9.3 will be followed. Ifthe non-conformance is deemed to be systematic or procedural, DUSA shall determine the root cause, and provide specific steps to resolve problems(s) in accordance with the procedure set forth in Section 1 0.2. Any non-conformance with QAP requirements in a given quarterly groundwater monitoring period will be corrected and reported to the Executive Secretary on or before submittal of the next quarterly ground water monitoring report. b) When a sample is lost, sample container broken, or the sample or analyte was omitted, resample within 1 0 days of discovery and analyze again in compliance with all requirements of this QAP. The results for this sample(s) should be included in the same quarterly monitoring report with other samples collected for the same sampling event; and c) For any other material deviation from this QAP, the procedure set forth in Section 10.2 shall be followed. 10.2 Procedure for Corrective Action The need for corrective action for non-conformance with the requirements of this QAP, may be identified by system or performance audits or by standard QA/QC procedures. The procedures to be followed if the need for a corrective action is identified, are as follows: a) Identification and definition of the problem; b) Assignment of responsibility for investigating the problem; c) Investigation and determination ofthe cause ofthe problem; Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 29 of61 d) Determination of a corrective action to eliminate the problem; e) Assigning and accepting responsibility for implementing the corrective action; f) Implementing the corrective action and evaluating its effectiveness; and g) Verifying that the corrective action has eliminated the problem. The QA Manager shall ensure that these steps are taken and that the problem which led to the corrective action has been resolved. A memorandum explaining the steps outlined above will be placed in the applicable monitoring files and the Mill Central Files, and the corrective action will be documented in a Report prepared in accordance with Section 11. 11.0 REPORTING As required under paragraph I.F.1 of the GWDP, the Mill will send a groundwater monitoring report to the Executive Secretary on a quarterly basis. Both the Routine Groundwater Monitoring Reports (pertinent to Part I.F.1 of the Permit) and Chloroform Investigation and Nitrate Corrective Action Reports shall be submitted according to the following schedule: Quarter Period I Due Date First January-March June 1 Second April-June September 1 Third July -September December 1 Fourth October-December March 1 The Routine Groundwater Monitoring Reports (pertinent to Part I.F .1 of the Permit) will include the following information: • Description of monitor wells sampled • Description of sampling methodology, equipment an decontamination procedures to the extent they differ from those described in this QAP • A summary data table of groundwater levels for each monitor well and piezometer • A summary data table showing the results of the sampling event, listing all wells and the analytical results for all constituents and identifying any constituents that are subject to accelerated monitoring in any particular wells pursuant to Part I.G.1 of the GWDP or are out of compliance in any particular wells pursuant to Part I.G.2 of the GWDP • Copies of Field Data Worksheets • Copies of Analytical Laboratory results • Copies of Chain of Custody Forms (included in the data packages) Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 30 of61 • A Water Table Contour Map showing groundwater elevation data for the quarter will be contemporaneous for all wells on site, not to exceed a maximum time difference of five calendar days. • Evaluation of groundwater levels, gradients and flow directions • Quality assurance evaluation and data validation description (see Section 9 for further details) • All non-conformance with this QAP and all corrective actions taken. • Recommendations and Conclusions. With respect to the Chloroform Investigation and Nitrate Corrective Action reporting requirements, these are specified in Appendix A and B to this document. In addition, an electronic copy of all analytical results will be transmitted to the Executive Secretary in comma separated values (CSV) format, or as otherwise advised by the Executive Secretary. Further reporting may be required as a result of accelerated monitoring under paragraphs I.G.l and I.G.2 ofthe GWDP. The frequency and content ofthese reports will be defined by DUSA corporate management working with the Executive Secretary. 12.0 SYSTEM AND PERFORMANCE AUDITS 12.1 QA Manager to Perform System Audits and Performance Audits DUSA shall perform such system audits and performance audits as it considers necessary in order to ensure that data of known and defensible quality are produced during a sampling program. The frequency and timing of system and performance audits shall be as determined by DUSA. 12.2 System Audits System audits are qualitative evaluations of all components of field and Analytical Laboratory QC measurement systems. They determine if the measurement systems are being used appropriately. System audits will review field and Analytical Laboratory operations, including sampling equipment, laboratory equipment, sampling procedures, and equipment calibrations, to evaluate the effectiveness of the QA program and to identify any weakness that may exist. The audits may be carried out before all systems are operational, during the program, or after the completion of the program. Such audits typically involve a comparison of the activities required under this QAP with those actually scheduled or performed. A special type of systems audit is the data management audit. This audit addresses only data collection and management activities. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 12.3 Performance Audits Date: 06-06-I 2 Revision 7.2 Page 31 of61 The performance audit is a quantitative evaluation of the measurement systems of a program. It requires testing the measurement systems with samples of known composition or behavior to evaluate precision and accuracy. With respect to performance audits of the analytical process, either blind performance evaluation samples will be submitted to the Analytical Laboratory for analysis, or the auditor will request that it provide results of the blind studies that the Analytical Laboratory must provide to its NELAP accreditation agency on an annual basis. The performance audit is carried out without the knowledge of the analysts, to the extent practicable. 12.4 Follow-Up Actions Response to the system audits and performance audits is required when deviations are found and corrective action is required. Where a corrective action is required, the steps set out in Section 10.2 will be followed. 12.5 Audit Records Audit records for all audits conducted will be retained in Mill Central Files. These records will contain audit reports, written records of completion for corrective actions, and any other documents associated with the audits supporting audit fmdings or corrective actions. 13.0 PREVENTIVE MAINTENANCE Preventive maintenance concerns the proper maintenance and care of field and laboratory instruments. Preventive maintenance helps ensure that monitoring data generated will be of sufficient quality to meet QA objectives. Both field and laboratory instruments have a set maintenance schedule to ensure proper functioning of the instruments. Field instruments will be maintained as per the manufacturer's specifications and established sampling practice. Field instruments will be checked and calibrated prior to use, in accordance with Section 5. Batteries will be charged and checked daily when these instruments are in use. All equipment out of service will be immediately replaced. Field instruments will be protected from adverse weather conditions during sampling activities. Instruments will be stored properly at the end of each working day. Calibration and maintenance problems encountered will be recorded in the Field Data Worksheets or logbook. The Analytical Laboratory is responsible for the maintenance and calibration of its instruments in accordance with Analytical Laboratory procedures and as required in order to maintain its NELAP certifications. Preventive maintenance will be performed on a scheduled basis to minimize downtime and the potential interruption of analytical work. Mill-Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 32 of61 14.0 QUALITY ASSURANCE REPORTS TO MANAGEMENT 14.1 Ongoing QA/QC Reporting The following reporting activities shall be undertaken on a regular basis: a) The Sample and QC Monitors shall report to the QA Manager regularly regarding progress of the applicable sampling program. The Sample and QC Monitors will also brief the QA Manager on any QA/QC issues associated with such sampling activities. b) The Analytical Laboratory shall maintain detailed procedures for laboratory record keeping. Each data set report submitted to the Mill's QA Manager or his staff will identify the analytical methods performed and all QA/QC measures not within the established control limits. Any QA/QC problems will be brought to the QA Manager's attention as soon as possible; and c) After sampling has been completed and final analyses are completed and reviewed, a brief data evaluation summary report will be prepared by the Analytical Laboratory for review by the QA Manager, by a Sampling and QC Monitor or by such other qualified person as may be designated by the QA Manager. The report will be prepared in accordance with NELAP requirements and will summarize the data validation efforts and provide an evaluation of the data quality. 14.2 Periodic Reporting to Management The QA Manager shall present a report to DUSA's ALARA Committee at least once per calendar year on the performance of the measurement system and the data quality. These reports shall include: a) Periodic assessment of measurement quality indicators, i.e., data accuracy, precision and completeness; b) Results of any performance audits, including any corrective actions; c) Results of any system audits, including any corrective actions; and d) Significant QA problems and recommended solutions. 15.0 AMENDMENT This QAP may be amended from time to time by DUSA only with the approval of the Executive Secretary. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 16.0 REFERENCES Date: 06-06-12 Revision 7.2 Page 33 of61 United States Environmental Protection Agency, November 2004, Test Methods for Evaluating Solid Waste, EPA SW-846. United States Environmental Protection Agency, September, 1986, RCRA Ground-Water Monitoring Teclmical Enforcement Guidance Document (TEGD), Office of Solid Waste and Emergency Response, OSWER-9950.1. United States Environmental Protection Agency, November 1992, RCRA Ground-water Monitoring Draft Teclmical Guidance (DTG), Office of Solid Waste. Standard Methods for the Examination of Water and Wastewater, 20th Edition, 1998. American Public Health Association, American Water Works Association, Water Environment Federation. Washington, D.C. p. 1-7. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) ATTACHMENT 1 Field and Data Forms Date: 06-06-12 Revision 7.2 Page 34 of61 Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Attachment 1-1 Quarterly Depth to Water Data Sheet NAME: ----------------------------------DATE: TIME WELL Static level TIME WELL Static Level TIME Date: 06-06-12 Revision 7.2 Page 35 of61 WELL Static Level Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 36 of6l ATTACHMENT 1-2 WHITE MESA URANIUM MILL FIELD DATA WORKSHEET FOR GROUNDWATER o Ntsor!l MIN~S lle5cziptiaa ofSmipJillc Evmt: Field SmJpJe m n. mdl'imefar ~ .__ ______ _, -~(ifdiftitnat) WellPuqiDcEqaipUsed: @]pumpor @]NilK Wtlll'uq,(uo1hsthmBe!met) -~ .... 7.1 l'lqiDc Metbod. Used: [§]2 CiiSinp [§)3 ~ Sampliac Ewat Pmr. Wtil$mwlltd mSampliacEwat I.._ ______ _, pH:Bnffer7.o ._I ___ __. pHBuf&s-4.0 Spec:i&.c: ~ ~I ____ _,I!'MHOSI c:m Well.Depth(O.Olft): Dlpth tu w-. Betm Purgiug ._1 ___ _, Well WaterTaap. (~ Tm I I Gal.Pmpd I Caadul:tmc!t I I pH I Temp. "C I I :R.edaPcMai:W Eh (aiV) I I l'mbidity (NTU) I I ~ I I Gal.Purpd I Ccuiadmce I I pH I Temp. "C I I :R.-P....WEit (mV) I I Tmbidity (NTU) I I ~ Vobm. (V} 4" wen:J ,(.653b) l"Well:t-1_ ----;_(:367h) pH ofWar <~~ ~Po~(Eh)'-1 __ _, Turbidity),_ __ _, Exrl Amb. Temp. 'C (p.Jior Simpnn~ ell1!flt)L.I __ ___, Time I I GalParpd. I I I c~ I I pHI I T...,_"C I I belen ~EhCmV> I I Turbidity (NTU) I I I "'Ii.ule I I GalParpd. I I I c~ I I pHI I T...,_ "C I I bdox PvlmtWEh (mV) I I ~(NTU) I I 11111 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Mil--llisclwrp......m -~QIIftv---,_,1~ V~ofW~~ ~~ --------~ Date: 06-06-12 Revision 7.2 Page 37 of61 11111!0~-· 7.1 gallon(s) Flow lW! (Q), in gpm.. SJ60 = ... I -----~ T:ooe ID ~two ~,;·olumes (2V) T=2VIQ= I Sample Taken Sample Vol (indicate Filtued Preserntn"i! Added Type of Sample if o1her-than as Preien"ative Type y N specified below) y N y N VOCs a 0 3x4Uml 0 a l:iCL a a I Nutrients a a lOOml a D H2S04 0 a &-:n-y Mmls 0 0 2S0ml a a HN03 a 0 All Other Non lUdiologi~ 0 0 2SOml a a [No Preserv. a a Gross Alpha -a D l,OOOml 0 a BN03 a a Other (5pecify) 0 0 Sample -wlome a a 0 0 H pmeanlive is used, spec:ify Type md. QliiiDiily af~: FDW.Depth ~..I ____ _, Sample Time L. See iDslrud:i.on 2 all rirtiiJJ 2ifl•WB!'f' ~---~ ... ~ ..... . ·-· ---···--·· ····-· ···-··-·· ------·-·--· COmpany Name: Project Name, PWS, Permit, Etc. Sample origin EPNState Compliance: State: Yes 0 No 0 Report Mail Acldress: Contact Name: PhonetFax: Email: Sampler: (Please Print) Invoice Address: ln11olce Colllact & PhoM: Purchase Order: ! Quotel8ottle Order: Special Report/Fonnats: 3::: &fl!LM,W@!l@ 00~ .. Contact Ell prior to onoppooar. 0 -RUSH sample submittal "'0 "' for charges and Co0o1.r Ill(&): ~aJ;g~l:;; -0 [ R scheduling-See D ow 0 EDD/EDT(Eiedrooio Date) ·~~~i~ UJ lnstruellon Page :r:: '0 RIICGipt T tmp. 0 POTWfWWTP Format: ~~~~~:.§' () <: Comments: O state: 0 LEVEL IV e a;sg ·2 ~ ~ u oc "' 0 other: 0 NELAC ~~r:a;'? E On teo: V N <( ::> ~-!~&~ I-s UJ "E c,..tody s.a..r E :§!J UJ {!l One«U• V N "' C/) OnCOOIIr V N en 1: ,g H lnlli<;l v Ill (J) SAMPLE IDENTIRCAnON Collection Collection MATRIX sro••""" y N (Numc. Location. lnteM!I, OO:.l Date Time Mate~\ ~ 2 ~ a ~. ~ ~· 5 ~ s ~ 7 ~ • ~ e ·~ 10 "d) Custody ROinquiihtcl by(oriml '1:1010""""' Sl;no>tu. ... :oca\Yod by {prirt}: alofT-............ Record ii.-.-b!'!Pill-1 Q<icj .... _ ... -••"'d by(PJ!rt): OolofT"" 01!1'010•"'· MUST be Signed IUtCOIVIh.• DY .. aoonnory:: UIIBJIITII'. ~!gmi)U'ry> SnmDio Dlsnot-1!: R&lum IQ C1kml: l.!lb.~posal: ~ --~------- In certan circumstances, samples slJbmijted to Energy Lab01atories, Inc, may be subcontracted to other c11rtilied laboratorles in order to complete the analysia requ""flci. This !lerves as notice or this possibility. All sul>-contract data will be clearly notated on your enatytlc:.ot rapott. VIall our web site at www.energylab.ccrn for addlllonal information, downloadable lee schedule, forms, and linl(s. ~ ~ ~> r>-3 ~>-3 n> ~~n ~z~ ooo~ ~>-3 n .... ~~ >-3 g ~ .00'7 ~ .... ,;::.. ~ 0 ::..: ~§­q P-0 >::;: .... Vl l» 0 Vl ..... ~ =; ~ ::l l» ':7 P-::l ,;::.. ::;: (") 0 l» (!) ::s ..... ~ ~· ~ ;-Qo ::s s· ;n· ::0 (Jq g. > ~ 0 (!) '"t:l ~ (!) w 00 0 ...., 0'1 ,_. l. ..... t:l ~ 0 0\ ' 0 ?' ..... N ~ < ;n· g· -.l tv Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) OENISO MINES Date: 06-06-12 Revision 7.2 Page 39 of61 CHAIN OF CUSTODY Samples Shipped to: Contact Chain of Custody/Sampling Analysis Request Project Samplers Name Samplers Signature Date Collecte Time Sample 10 d Collected Laboratory Analysis Requested Please notify Tanner Holliday of Receipt temperature on these samples Immediately! Thank you. Relinquished Date/Tim Received By:(Signature) e By:(Signature) Date/Time Relinquished Date/Tim Received By: (Signature) e By:(Signature) Date/Time Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) ATTACHMENT 2 Field Procedures Date: 06-06-12 Revision 7.2 Page 40 of61 Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 41 of61 Attachment 2-1 Groundwater Head (Depth to Water) Measurement Procedures Measure and record all depth to water data to the nearest 0. 01 feet. Equipment Used For Groundwater Head Monitoring Measurement of depth to groundwater is accomplished by using a Solinist -IT 300 or equivalent device (the "Water Level Indicator"). Equipment Checks Equipment used in depth to groundwater measurements will be checked prior to each use to ensure that the Water Sounding Device is functional. Check the Water Sounding Device as follows: • Turn the Water Level Indicator on. • Test the Water Level Indicator using the test button located on the instrument. • If the Water Level Indicator alarms using the test button it is considered operational and can be used for depth to water measurements. Measurement of Depth to Water All depth to water measurements (quarterly and immediately prior to sample collection) will be completed using the following procedure: • For monitoring wells -Measure depth to water from the top of the inner well casing at the designated measurement point. • For the piezometers -Measure depth to water from the top of the casing at the designated measurement point. • Measurements are taken by lowering the Water Level Indicator into the casing until the device alarms, indicating that the water surface has been reached. • Record the depth to groundwater on the appropriate form in Attachment 1 as the distance from the measuring point to the liquid surface as indicated by the alarm. The distance is determined using the tape measure on the Water Level Indicator. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Attachment 2-2 Decontamination Procedures Date: 06-06-12 Revision 7.2 Page 42 of61 Non-dedicated sampling equipment will be decontaminated usmg the following procedures: Water level meter Decontaminate the water level meter with a detergent/deionized ("DI") water mixture by pouring the solutions over the water level indicator. Rinse the water level indicator with fresh DI water rinse by pouring the DI water over the water level indicator. Field Parameter Instrument (Hydrolab or equivalent) Rinse the field parameter instrument probe unit with DI water pnor to each calibration. Wash the cup of the flow through cell with a detergent/DI water mixture and rinse with fresh DI water prior to each calibration. Non-Dedicated Purging/Sampling Pump Non-dedicated sampling/purging equipment will be decontaminated after each use and prior to use at subsequent sampling locations using the following procedures: a) submerge the pump into a 55-gallon drum of nonphosphate detergent/DI water mixture; b) pump the detergent/DI water solution through the pump and pump outlet lines into the drain line connected to Cell 1; c) pump as much of the detergent/DI water mixture from the drum through the pump and outlet lines as possible; d) submerge the pump into a 55-gallon drum ofDI water; e) pump the DI water solution through the pump and pump outlet lines into the drain line connected to Cell 1 ; f) pump as much of the detergent/DI water mixture from the drum through the pump and outlet lines as possible; Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 43 of61 g) if an equipment rinsate blank is required, submerge the pump into a fresh 55- gallon drum of DI water and pump 50% or more of the DI water through the pump and pump outlet lines; h) if required, collect the equipment rinsate blank directly from the pump outlet lines into the appropriate sample containers (filtering the appropriate aliquots as needed). All water produced during decontamination of a non-dedicated pump will pumped to an appropriate drain line which outlets into Cell 1. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Attachment 2-3 Purging Procedures The following equipment will be used for groundwater purging and sampling: Page 44 of61 • Disposable Bailer: A bailer that is used at one specific well for one event for purging and/or sampling. These bailers are single use and are disposed of as trash after sampling in accordance with Mill disposal requirements for Mill-generated solid waste. • Dedicated Pump: A pump that is dedicated to one specific well for the use of purging or sampling. A dedicated pump remains inside the well casing suspended and secured. • Non-Dedicated Pump: A pump that is used for purging and sampling at one or more wells. • Field Parameter Meter: A meter used to measure ground water quality parameters as listed below. Field parameters shall be measured using a Hydrolab M-5 with Flow Cell Multi-Parameter Meter system or equivalent that allows a continuous stream of water from the pump to the meter that enables measurements to be taken on a real-time basis without exposing the water stream to the atmosphere. The Field Parameter Meter measures the following parameters: ~ Water temperature; ~ Specific conductivity; ~ Turbidity; ~ pH; ~ Redox potential (Eh). • Water Level Indicator: A tape measure with a water level probe on the end that alarms when contact is made with water. • Diesel Generator: Mobile power supply to provide power for submersible pump. • 150 psi air compressor and ancillary equipment, or equivalent to operate dedicated "bladder" pumps. Additional supplies for purging and sampling are as follows: • Field Data Sheets • 45 micron in-line filters (when metals and gross alpha analyses are required) • Calculator • Clock, stopwatch or other timing device • Buckets • Sampling containers(as provided by the Analytical Laboratory) • Field preservation chemicals (as provided by the Analytical Laboratory) • Disposable gloves • Appropriate health and safety equipment • Sample labels and COCs (as provided by the Analytical Laboratory) Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Pre-Purging/ Sampling Activities Date: 06-06-12 Revision 7.2 Page 45 of61 If a portable (non-dedicated) pump is to be used, prior to commencing the event's sampling activities, 1. check the pumping equipment to ensure that no air is leaking into the discharge line, in order to prevent aeration of the sample; 2. decontaminate the sampling pump using the procedure described in Attachment 2-2 and collect a equipment rinsate blank as required; and 3. Prior to leaving the Mill office, place the Trip Blank(s) into a cooler that will transport the VOC samples. The Trip Blank(s) will accompany the groundwater (VOC) samples throughout the monitoring event. Well Purging The purging techniques described below will be used for all groundwater sampling conducted at the Mill unless otherwise stated in the program-specific QAPs for the chloroform and nitrate investigations. The program-specific QAPs for the chloroform and nitrate investigations are included as Appendix A and Appendix B respectively. Purging is completed using the equipment described above. Purging is completed to remove stagnant water from the casing and to assure that representative samples of formation water are collected for analysis. There are three purging strategies that will be used to remove stagnant water from the casing during groundwater sampling at the Mill. The three strategies are as follows: 1. Purging three well casing volumes with a single measurement of field parameters 2. Purging two casing volumes with stable field parameters (within 10% RPD) 3. Purging a well to dryness and stability of a limited list of field parameters after recovery The groundwater in the well should recover to within at least 90% of the measured groundwater static surface before sampling. If after 2 hours, the well has not recovered to 90% the well will be sampled as soon as sufficient water for the full analytical suite is available. Turbidity measurement in the water should be .:S 5 NTU prior to sampling unless the well is characterized by water that has a higher turbidity. A flow-cell needs to be used for field parameters. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 46 of61 Procedure a) Determine the appropriate purging strategy based on historic performance of the well (3 casing volumes, 2 casing volumes and stable parameters, or purging the well to dryness) b) Remove the well casing cap and measure and record depth to groundwater as described in Attachment 2-1 above; c) Determine the casing volume (V) in gallons, where h is column height of the water in the well (calculated by subtracting the depth to groundwater in the well from the total depth ofthe well), V = 0.653*h, for a 4" casing volume and V = .367*h for a 3" casing volume. Record the casing volume on the Field Data Worksheet; If a portable (non-dedicated) pump is used: • Ensure that it has been decontaminated in accordance with Attachment 2-2 since its last use. • Lower the pump into the well. Keep the pump at least five feet from the bottom of the well. If a non-dedicated pump or dedicated pump is used: (i) Commence pumping; (ii) Determine pump flow rate by using a stopwatch or other timing device and a calibrated bucket by measuring the number of seconds required to fill to the one-gallon mark. Record this in the "pumping rate" section of the Field Data Worksheet; (iii) Calculate the amount of time to evacuate two or three casing volumes; (iv)Evacuate two or three casing volumes by pumping for the length of time determined in paragraph (iii); (v) If two casing volumes will be purged: Take measurements of field parameters (pH, specific conductance, temperature, redox potential and turbidity) during well purging, using the Field Parameter Meter. These measurements will be recorded on the Field Data Worksheet. Purging is completed after two casing volumes have been removed and the field parameters pH, temperature, specific conductance, redox potential (Eh) and turbidity have stabilized to within 10% RPD over at least two consecutive measurements. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 47 of61 (vi)Ifthree casing volumes will be purged: Take one set of measurements of field parameters (pH, specific conductance, temperature, redox potential and turbidity) after three casing volumes have been purged immediately prior to sample collection using the Field Parameter Meter. Record these measurements on the Field Data Worksheet. (vii) If the well is purged to dryness: Record the number of gallons purged on the Field Data Worksheet. The well should be sampled as soon as a sufficient volume of groundwater is available to fill sample containers. Upon arrival at the well after recovery or when sufficient water is available for sampling measure depth to water and record on the Field Data Worksheet. Take one set of measurements of field parameters for pH, specific conductance and temperature only. Collect the samples into the appropriate sample containers. Take an additional set of measurements of field parameters for pH, specific conductance and temperature after the samples have been collected. If the field parameters of pH, specific conductance and temperature are within 1 0% RPD the samples can be shipped for analysis. If the field parameters of pH, specific conductance and temperature are not within 10% RPD, dispose of the sample aliquots, and purge the well again as described above. Repeat this process if necessary for three complete purging events. If after the third purging the event, the parameters of pH, specific conductance and temperature do not stabilize to within 10% RPD, the well is considered sufficiently purged and collected samples can be submitted for analysis. Purging using a disposable bailer For wells where a pump is not effective due to shallow water columns, a disposable bailer, made of inert materials, will be used. When a bailer is used, the following procedure will be followed: Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page48of61 (i) Use the water level meter to determine the water column and figure the amount of water that must be evacuated. (ii) Attach a disposable bailer to a rope and reel. (iii) Lower the bailer into the well and listen for contact with the solution. Once contact is made, allow the bailer to gradually sink in the well, being careful not to allow the bailer to come in contact with the bottom sediment. (iv)After the bailer is full, retrieve the bailer and pour the water from the bailer into 5 gallon buckets. By doing this, one can record the number of gallons purged. (v) Repeat this process until either two casing volumes have been collected or until no more water can be bailed. When the process is finished for the well, the bailer will be disposed of. (vi)Take field measurements from the water in the buckets. All water produced during well purging will be containerized. Containerized water will be disposed of into an active Tailings Cell. After the collection of all samples, and prior to leaving the sampling site, replace the well cap and lock the casing. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Sample Collection Order Attachment 2-4 Sample Collection Procedures Date: 06-06-12 Revision 7.2 Page 49 of61 Regardless of the purging method employed samples will be collected in the order specified below. All containers and preservatives will be provided by the Analytical Laboratory. Collect the samples in accordance with the volume, container and preservation requirements specified by the Analytical Laboratory which should be provided with the supplied containers. VOCs; Nutrients (ammonia, nitrate and nitrite); All other non-radiologies (fluoride, general inorganics, TDS, total cations and anions); and Gross alpha and heavy metals (filtered). Sample Filtering When sampling for heavy metals and for gross alpha, the following procedure shall be followed: a) Obtain the specifically identified sample container for the type of sample to be taken, as provided by the Analytical Laboratory; b) Add the quantity of specified preservative provided by the Analytical Laboratory to each sample container; c) When using a pump to sample: (i) Place a new 0.45 micron filter on the sample tubing; (ii) Pump the sample through the filter, and into the sample container containing the preservative; (iii) The pump should be operated in a continuous manner so that it does not produce samples that are aerated in the return tube or upon discharge; d) When using a bailer to sample (wells with shallow water columns, i.e., where the water column is less than five feet above the bottom of the well casing), then the following procedure will be used to filter samples: (i) Collect samples from the bailer into a large, unused sample jug that does not contain any preservatives. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 50 of61 (ii) Add the appropriate preservatives to the appropriate sample container provided by the Analytical Laboratory. (iii) Place clean unused tubing in the peristaltic pump. (iv) Use the peristaltic pump to transfer the unpreserved sample from the large sample jug to the sample containers through a 0.45 micron filter. Procedures to Follow After Sampling a) In each case, once a sample is taken, identify and label the sample container using the labels provided by the Analytical Laboratory. The labels may include the following information depending on the type of analysis requested: • Sample location • Date and time of sample • Any preservation method utilized • Filtered or unfiltered b) Immediately after sample collection, place each sample in an ice-packed cooler; and c) Before leaving the sampling location, thoroughly document the sampling event on the Field Data Worksheet, by recording all pertinent data. Upon returning to the office, the samples must be stored in a refrigerator at less than or equal to 6° C. These samples shall be received by the Analytical Laboratory at less than or equal to 6° C. Samples will then be re-packed in the plastic ice-packed cooler and transported via these sealed plastic containers by overnight delivery services to the Analytical Laboratory. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Field Duplicates Attachment 2-5 Field QC Samples Date: 06-06-12 Revision 7.2 Page 51 of61 Field duplicates are required to be collected at a frequency of one duplicate per every 20 field samples. Field duplicate samples are analyzed for the same analytes as the parent sample. Field duplicate samples should be as near to split samples as reasonably practicable. Collection of field duplicates is completed as follows: Fill a single VOC vial for the parent sample. Collect a second VOC vial for the duplicate sample. Collect the second set of VOC vials for the parent immediately followed by the duplicate sample. Fill the third set of VOC vials in the same manner. Repeat this parent/duplicate process for the remaining analytes in the order specified in Attachment 2-4 blind to the Analytical Laboratory. Field duplicate samples are labeled using a "false" well number such as MW-65 and MW-70. Equipment Rinsate Samples Where portable (non-dedicated) sampling equipment is used, a rinsate sample will be collected at a frequency of one rinsate sample per 20 field samples. Equipment rinsate samples are collected after the decontamination procedure in Attachment 2-2 is completed as follows: Submerge the pump into a fresh 55-gallon drum of DI water and pump 50% or more of the DI water through the pump and pump outlet lines; Collect the equipment rinsate blank directly from the pump outlet lines into the appropriate sample containers (filtering the appropriate aliquots as needed). Equipment rinsate blanks are labeled with the name of the subsequently purged well with a terminal letter "R" added (e.g. MW-llR). Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Appendix A Chloroform Investigation Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Page 52 of61 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Chloroform Investigation Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Date: 06-06-12 Revision 7.2 Page 53 of61 This document sets out the quality assurance plan to be used by Denison Mines (USA) Corp. for Chloroform Investigation conducted pursuant to State of Utah Notice of Violation and Groundwater Corrective Action Order (UDEQ Docket No. UGW-20-01) (the "Order"). Specifically, the Mill will use the same sampling regimen for the Chloroform Investigation that is utilized for groundwater sampling under its groundwater discharge permit, as set forth in the attached groundwater discharge permit Quality Assurance Plan (QAP), except as set forth below: 1) Dedicated Purge Pump/Sampling Chloroform Investigation samples are collected by means of disposable bailer(s) the day following the purging . The disposable bailer is used only for the collection of a sample from an individual well and disposed subsequent to the sampling. The wells are purged prior to sampling by means of a portable pump. Each quarterly purging event begins at the location least affected by chloroform (based on the previous quarters sampling event) and proceeds by affected concentration to the most affected location. Although purging will generally follows this order, the sampling order may deviate slightly from the generated list. This practice does not affect the samples for these reasons: any wells sampled in slightly different order have either dedicated pumps or are sampled via a disposable bailer. This practice does not affect the quality or usability of the data as there will be no cross-contamination resulting from sampling order. Decontamination of all sampling equipment will follow the decontamination procedure outlined in Attachment 2-2 of the QAP. 2) Chloroform Investigation Sampling Frequency, Order and Locations The chloroform investigation wells listed below are required to be monitored on a quarterly basis under State of Utah Notice of Violation and Groundwater Corrective Action Order UDEQ Docket No. UGW-20-01. Chloroform wells shall be purged from the least contaminated to the most contaminated as based on the most recent quarterly results. • MW-4 • TW4-13 • TW4-1 • TW4-14 • TW4-2 • MW-26 • TW4-3 • TW4-16 • TW4-4 • MW-32 • TW4-5 • TW4-18 • TW4-6 • TW4-19 Mill -Groundwater Discharge Permit Date: 06-06-12 Revision 7.2 Groundwater Monitoring Quality Assurance Plan (QAP) Page 54 of61 • TW4-7 • TW4-20 • TW4-8 • TW4-21 • TW4-9 • TW4-22 • TW4-10 • TW4-23 • TW4-11 • TW4-24 • TW4-12 • TW4-25 • TW4-26 • TW4-27 Note: Wells MW-26 and MW-32 may be monitored under either the Chloroform Investigation Program or the Groundwater Discharge Permit Monitoring Program. 3) Chloroform Investigation Sample Containers and Collection Volume The chloroform investigation sampling program requires a specific number of sampling containers and the collection of specific volumes of sample. Accordingly, the following sample volumes are collected by bailer from each sampling location: • For Volatile Organic Compounds (VOC), collect three samples into three separate 40 ml containers. • For Nitrate/Nitrite determinations, collect one sample into a 100 ml container. • For Inorganic Chloride, collect one sample into a 100 ml container. The Analytical Laboratory will provide the sampling containers and may request that certain analytes be combined into a single container due to like sampling requirements and/or like preservation. The container requirements will be determined by the Analytical Laboratory and specified with the bottles supplied to the Field Personnel. Bottle requirements may change if the Analytical Laboratory is changed or if advances in analytical techniques allow for reduced samples volumes. The above list is a general guideline. 4) Laboratory Requirements Collected samples which are gathered for chloroform investigation purposes are shipped to an analytical laboratory where the requisite analyses are performed. At the laboratory the following analytical specifications must be adhered to: Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Analytical Analytical Parameter Method Nitrate & Nitrite E353.1 or (as N) E353.2 Carbon SW8260B Tetrachloride or SW8260C Chloroform SW8260B or SW8260C Dichloromethane SW8260B (Methylene or Chloride) SW8260C Chloromethane SW8260B or SW8260C Inorganic A4500-Cl B Chloride or A4500-Cl E or E300.0 5) Field Parameters Date: 06-06-12 Revision 7.2 Page 55 of61 Reporting Maximum Sample Sample Limit Holding Preservation Temperature Times Requirement Requirement 0.1 mg/L 28 days H2S04 to ::::; 6°C pH<2 1.0 JlgiL 14 days HCl to pH<2 ::::; 6°C 1.0 JlgiL 14 days HCl to pH<2 ::::; 6°C 1.0 JlgiL 14 days HCl to pH<2 ::::; 6°C 1.0 Jlg/L 14 days HCl to pH<2 ::::; 6°C 1 mg/L 28 days None ::::; 6°C Only one set of field parameters are required to be measured prior to sampling in chloroform pumping wells. This includes the following wells: MW-4, MW-26, TW4-4, TW-4-19 and TW-4-20. However, if a pumping well has been out of service for 48 hours or more, DUSA shall follow the purging requirements outlined in Attachment 2-3 of the QAP before sample collection. Field parameters will be measured in chloroform wells which are not continuously pumped as described in Attachment 2-3 of the groundwater QAP. 6) Chloroform Investigation Reports The Chloroform Investigation Reports will include the following information: a) Introduction b) Sampling and Monitoring Plan • Description of monitor wells • Description of sampling methodology, equipment and decontamination procedures Mill -Groundwater Discharge Permit Groundwater Monitoring . Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 56 of61 • Identify all quality assurance samples, e.g. trip blanks, equipment blanks, duplicate samples c) Data Interpretation • Interpretation of groundwater levels, gradients, and flow directions. Interpretations will include a discussion on: 1) A current site groundwater contour map, 2) hydrographs to show groundwater elevation in each monitor well over time, 3) depth to groundwater measured and groundwater elevation from each monitor well summarized in a data table, that includes historic groundwater level data for each well, and 4) an evaluation of the effectiveness of hydraulic capture of all contaminants of concern. • Interpretation of all analytical results for each well, including a discussion on: 1) a current chloroform isoconcentration map with one of the isosconentration lines showing the 70 ug/L boundary, 2) graphs showing chloroform concentration trends in each well through time and, 3) analytical results for each well summarized in a data table, that includes historic analytical results for each well. • Calculate chloroform mass removed by pumping wells. Calculations would include: 1) total historic chloroform mass removed, 2) total historic chloroform mass removed for each pumping well, 3) total chloroform mass removed for the quarter and, 4) total chloroform mass removed from each pumping well for the quarter. d) Conclusions and Recommendations e) Electronic copy of all laboratory results for Chloroform Investigation monitoring conducted during the quarter. f) Copies of DUSA field records, laboratory reports and chain of custody forms. Except as otherwise specified above, the Mill will follow the procedure set out in the Mill's QAP. Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) AppendixB Nitrate Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Page 57 of61 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Nitrate Corrective Action Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah Date: 06-06-12 Revision 7.2 Page 58 of61 This document sets out the quality assurance plan to be used by Denison Mines (USA) Corp. for Nitrate Corrective Action Monitoring ("Nitrate Program") conducted pursuant to State of Utah Stipulated Consent Agreement Docket Number UGW-09-03-A. Specifically, the Mill will use the same sampling regimen for the Nitrate program that is utilized for groundwater sampling under its groundwater discharge permit, as set forth in the attached groundwater discharge permit Quality Assurance Plan (QAP), except as set forth below: 1) Purge Pump/Sampling The Nitrate program wells are purged and sampled by means of a portable pump. If the well is purged to dryness the samples are collected the following day by means of disposable bailer(s).The disposable bailer is used only for the collection of a sample from an individual well and disposed subsequent to the sampling. Each quarterly purging event begins at the location least affected by nitrate (based on the previous quarters sampling event) and proceeds by affected concentration to the most affected location. Purging and sampling follows this order if the wells are not purged to dryness and the samples are collected immediately after purging using the portable pump. If the well is purged to dryness and sampled with a disposable bailer, the sampling order may deviate slightly from the generated list. This practice does not affect the samples collected with a bailer for this reason: there is no cross- contamination resulting from sampling order when the samples are collected with a disposable bailer. Decontamination of all non-disposable sampling equipment will follow the decontamination procedure outlined in Attachment 2-2 of the QAP. 2) Nitrate Program Sampling Frequency, Order and Locations The Nitrate Program wells listed below are required to be monitored on a quarterly basis under State of Utah Docket No. UGW-09-03-A. DUSA has submitted a Corrective Action Plan ("CAP") as required by the Stipulated Consent Agreement. In that CAP, DUSA has proposed the abandonment of a number of the wells listed below. The implementation of the CAP, shall supersede any requirements contained in this QAP and Appendix. Nitrate Program wells shall be purged from the least contaminated to the most contaminated as based on the most recent quarterly results. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) • TWN-1 • TWN-2 • TWN-3 • TWN-4 • TWN-5* • TWN-6** • TWN-7 • TWN-8* • TWN-9* • TWN-10* • TWN-11* • TWN-12* *Recommended for abandonment Date: 06-06-12 Revision 7.2 Page 59 of61 • TWN-13* • TWN-14** • TWN-15* • TWN-16** • TWN-17* • TWN-18 • TWN-19** • Piezometer-0 1 • Piezometer-02 • Piezometer-03 **Recommended for depth to water measurements only. DUSA has proposed that monitoring cease. 7) Nitrate Program Sample Containers and Collection Volume The Nitrate Program sampling requires a specific number of sampling containers and the collection of specific volumes of sample. Accordingly, the following sample volumes are collected by bailer from each sampling location: • For Nitrate/Nitrite determinations, collect one sample into a 100 ml container. • For Inorganic Chloride, collect one sample into a 100 ml container. The Analytical Laboratory will provide the sampling containers and may request that certain analytes be combined into a single container due to like sampling requirements and/or like preservation. The container requirements will be determined by the Analytical Laboratory and specified with the bottles supplied to the Field Personnel. Bottle requirements may change if the Analytical Laboratory is changed or if advances in analytical techniques allow for reduced samples volumes. The above list is a general guideline. 8) Laboratory Requirements Collected samples which are gathered for Nitrate Program purposes are shipped to an analytical laboratory where the requisite analyses are performed. At the laboratory the following analytical specifications must be adhered to: Mill -Groundwater Discharge Permit Groundwater Monitoring Date: 06-06-12 Revision 7.2 Quality Assurance Plan (QAP) Page 60 of61 Analytical Analytical Reporting Maximum Sample Sample Parameter Method Limit Holding Preservation Temperature Times Requirement Requirement Nitrate & Nitrite E353.1 or 0.1 mg/L 28 days H2S04 to S 6°C (as N) E353.2 pH<2 Inorganic A4500-Cl B 1 mg/L 28 days None S 6°C Chloride or A4500-Cl E or E300.0 9) Field Parameters Field parameters will be measured in Nitrate Program wells as described in Attachment 2-3 of the groundwater QAP. 1 0) Nitrate Program Investigation Reports The Nitrate Program Reports will include the following information: a) Introduction b) Sampling and Monitoring Plan • Description of monitor wells • Description of sampling methodology, equipment and decontamination procedures • Identify all quality assurance samples, e.g. trip blanks, equipment blanks, duplicate samples c) Data Interpretation • Interpretation of groundwater levels, gradients, and flow directions. Interpretations will include a discussion on: 1) A current site groundwater contour map, 2) hydrographs to show groundwater elevation in each monitor well over time, 3) depth to groundwater measured and groundwater elevation from each monitor well summarized in a data table, that includes historic groundwater level data for each well, and 4) an evaluation of the effectiveness of hydraulic capture of all contaminants of concern. • Interpretation of all analytical results for each well, analytical results for each well summarized in a data table, that includes historic analytical results for each well. • Calculate nitrate mass removed by pumping wells (as the pumps are installed and operational). Calculations would include: 1) total nitrate Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 06-06-12 Revision 7.2 Page 61 of61 mass removed, 2) total historic nitrate mass removed for each pumping well, 3) total nitrate mass removed for the quarter and, 4) total nitrate mass removed from each pumping well for the quarter. d) Conclusions and Recommendations e) Electronic copy of all laboratory results for Nitrate Program monitoring conducted during the quarter. f) Copies ofDUSA field records, laboratory reports and chain of custody forms. Except as otherwise specified above, the Mill will follow the procedure set out in the Mill's QAP. Appendix L Tailings and Slimes Drain Sampling Program, Revision 2.1, July 30, 2012 White Mesa Uranium Mill SAMPLING AND ANALYSIS PLAN FOR TAILINGS CELLS, LEAK DETECTION SYSTEMS AND SLIMES DRAINS State of Utah Groundwater Discharge Permit No. UGW370004 Prepared by: Denison Mines (USA) Corp. Suite 950, 1050 1 ih Street Denver CO 80265 July 30, 2012 Tailings Cell, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 2.1 July 30, 2012 Contents 1.0 Introduction ............................................................................................................................... 3 2.0 Sampling Frequency and Monitoring Requirements ................................................................ 3 3.0 Field Sampling Procedures ....................................................................................................... 3 3.1 Tailings Cell Sampling .......................................................................................................... 4 3 .1.1 Sampling with a Peristaltic Pump .................................................................................. 4 3 .1.2 Sampling with a Ladle ................................................................................................... 5 3.1.3 Sampling with a Bailer ................................................................................................... 5 3.2 LDS Sampling ....................................................................................................................... 5 3.2.1 Cells 1, 2 and 3 LDS ...................................................................................................... 5 3.2.2 Cells 4A and 4B LDS .................................................................................................... 5 3.3 Slimes Drain Sampling .......................................................................................................... 5 3.4 Decontamination ................................................................................................................... 6 3.5 Field QC ................................................................................................................................ 6 3.5.1 Sample Duplicates ......................................................................................................... 6 3.5.2 Trip Blanks ...................................................................................................................... 6 3.5.3 Rinsate Blank Samples .................................................................................................. 6 4.0 QA and Data Evaluation ........................................................................................................... 7 5.0 Laboratory Analysis ................................................................................................................. 7 5.1 Analytical Quality Control ............................................................................................... 7 6.0 Reporting .......................................................................... ., ....................................................... 8 7.0 Agency Notification ................................................................................................................. 8 2 Tailings Cell, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 2.1 July 30, 2012 1.0 Introduction This Sampling and Analysis Plan ("SAP") describes the procedures for sampling the tailings cells, Leak Detection Systems ("LDS") and slimes drains at the White Mesa Mill in Blanding, Utah as required under Part I.E.1 0 of the Groundwater Discharge Permit ("GWDP") No. UGW3 70004. The objective of the tailings cell, LDS and slimes drain sampling is to collect annual samples from the locations identified below as required by the GWDP. This SAP specifies the sample collection requirements, procedures, analytical methodologies, and associated Quality Control ("QC") checks, sample handling protocols and reporting requirements for the annual tailings, LDS and slimes drain sampling program. 2.0 Sampling Frequency and Monitoring Requirements The sampling frequency and sample monitoring requirements for the tailings cells, LDS and slimes drains are as specified in the GWDP. Sampling is required to be conducted on an annual basis in August of each year for the solutions in tailings Cells 1, 3, 4A, and 4B, the solutions in the slimes drains in Cells 2, 3, 4A, and 4B (for Cells 3, 4A, and 4B after the commencement of dewatering), the solutions in the LDS in Cells 4A and 4B and any detected solutions in the LDS in Cells 1, 2, and 3 at the time of the August sampling event. Sampling locations are shown in Attachment 1. 3.0 Field Sampling Procedures The field sampling and data collection program will obtain samples to be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP. Analyses will be completed by a State of Utah certified laboratory using methods specified in the currently approved Denison Quality Assurance Plan ("QAP") for Groundwater. Additionally per the GWDP requirements, tailings cell, LDS and slimes drain samples will be collected and analyzed for Semivolatile Organic Compounds ("SVOCs"). Per the GWDP, the SVOCs will be analyzed by Environmental Protection Agency ("EPA") Method 8270D. Minimum detection limits or reporting limits for tailings, LDS and slimes drain samples for those analytes which have Groundwater Quality Standards (GWQSs") defined in Table 2 of the GWDP, will be less than or equal to the GWQS. The minimum detection or reporting limits for total dissolved solids ("TDS") sulfate, chloride and SVOCs are specified in the GWDP and are: • TDS will be less than or equal to 1,000 mg/L, • Sulfate will be less than or equal to 1,000 mg/L, • Chloride will be less than or equal to 1 mg/L, and • SVOCs will have reporting limits less than or equal to the lower limit of quantitation for groundwater listed in Table 2 ofEPA Method 8270D Revision 4, dated February 2007. Field activities include collecting samples, recording field data and field parameters, and preparing and shipping samples to the analytical laboratory. Sampling information will be recorded on the Tailings and Slimes Drain Field Sheet, (or its equivalent), included in Attachment 2. 3 Tailings Cell, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 2.1 July 30, 2012 Sample handling and preservation requirements for tailings cell, LDS and slimes drain samples are as specified in the QAP, except for SVOCs which are not routinely collected for any other Mill sampling program. SVOCs do not require any chemical preservation per EPA Method 8270D; however, SVOCs are required to be chilled. Receipt temperatures, for all analytes except SVOCs, are as specified in the QAP. The receipt temperature requirement for SVOCs is less than or equal to 6°C. Sample collection procedures for tailings cell, LDS and slimes drain samples are as described below. Where more than one sampling method is described, field personnel will choose a sampling method based on field conditions and safety considerations at the time of sampling. The gross alpha and metals sample aliquots from the tailings cells, LDSs and slimes drains will not be field filtered or field preserved due to safety concerns associated with the filtering apparatus and the backpressure created by the increased viscosity of these samples. The gross alpha and metals aliquots will be filtered and preserved by the analytical laboratory within 24 hours of receipt. Field preservation of the gross alpha and metals sample aliquots may interfere with the laboratory's ability to filter the samples upon receipt. It is important to note that field preservation of the samples is to preclude biological growth and prevent the inorganic analytes from precipitating. Based on the 2011 field data, the tailings, LDS and slimes drain samples were at a pH of 3.0 or less at the time of collection without additional preservative. The addition of preservatives in the field would add minimal if any protection from biological growth or precipitation. The VOC sample aliquots will be preserved in the field. Clean sample containers utilized for this sampling effort will be provided by the analytical laboratory. 3.1 Tailings Cell Sampling As noted in Section 2.0, sampling is required to be conducted on an annual basis in August of each year for the solutions in tailings Cells 1, 3, 4A, and 4B. Tailings cell samples may be collected using a ladle, a peristaltic pump or a bailer. The procedures for each sampling method are described below. In all instances the sampling equipment will be either disposable or dedicated and decontamination procedures and rinsate blanks will not be required. Sampling equipment will be inert and non-reactive. 3 .1.1 Sampling with a Peristaltic Pump Tailings samples may be collected using a peristaltic pump. Samples collected with the peristaltic pump will be collected by extending collection tubing approximately 6ft. from the edge ofthe sampling station. The tubing will be attached to a horizontal rod with sufficient tubing attached to lower the suction end of the tubing to approximately 1/3 of the distance between the liquid surface and the underlying solids. The collection tubing will be attached to a peristaltic pump. The tubing will be replaced prior to each use to preclude cross contamination and to eliminate the need for decontamination of sampling equipment. Due to the nature of the peristaltic pump, sample fluids do not come in contact with any surface other than the interior of the tubing, and decontamination of the pump or rinsate blanks is therefore not required. The sample containers will be filled directly from the peristaltic pump outflow. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required, as noted in Section 3.0. 4 Tailings Cell, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 2.1 July 30, 2012 3.1.2 Sampling with a Ladle Tailings samples may be collected using a ladle. Samples collected with the ladle will be collected by dipping the ladle directly into the tailings solution taking care not to stir up any solids below the liquid surface. Sample bottles will be filled directly from the ladle. Ladles used for sampling will be dedicated to each location or will be disposed after each use to preclude cross contamination and to eliminate the need for decontamination of sampling equipment. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be completed as noted in Section 3.0. 3.1.3 Sampling with a Bailer Tailings samples may be collected using a disposable bailer. Samples collected with the bailer will be collected by submerging the bailer into the tailings solution and allowing it to fill, taking care not to stir up any solids below the liquid surface. The bailer will withdrawn from the tailings solution and the sample bottles will be filled directly from the bailer. Bailers used for sampling will be disposed after each use to preclude cross contamination and to eliminate the need for decontamination of sampling equipment. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required as noted in Section 3.0. 3.2 LDS Sampling The LDS systems will be sampled as noted below. 3.2.1 Cells 1, 2 and 3 LDS The Cells 1, 2 and 3 LDSs will only be sampled if there is fluid present during the August sampling event. If fluids are present during the annual August sampling event, samples will be collected using the dedicated pumps installed in the riser pipe. Fluid level will be measured using the electronic pressure transducers currently installed in the LDS systems in the Cells. Samples will be collected directly from the pump outflow lines into the sample containers. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required as noted in Section 3.0. 3.2.2 Cells 4A and 4B LDS Solution from the Cell 4A and 4B LDS will be collected into a dedicated stainless steel bucket. Sample bottles will be filled from the stainless steel bucket using either the peristaltic pump or a ladle. If the peristaltic pump is used to transfer the solution to the sample bottles, the tubing in the pump will be disposed of and not reused, thereby eliminating the need for decontamination of equipment or rinsate blanks. If a ladle is used to transfer the solution to the sample bottles, the ladle will be either disposed of or will be dedicated to that location thereby eliminating the need for decontamination or rinsate blanks. Field filtering and field preservation of the gross alpha and metals sample aliquots will not be required as noted in Section 3.0. 3.3 Slimes Drain Sampling Once a tailings cell has started de-watering procedures, a sample should be collected from the slimes drain system. At this time Cell 2 is the only slimes drain that should be sampled. The location of the slime drain for Cell2 is depicted on Attachment 1. While Cell 3,Cell4A and 4B are each equipped with a 5 Tailings Cell, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 2.1 July 30, 2012 slimes drain sample access location, these Cells have not started dewatering and the slimes drain will not be sampled until dewatering operations are underway. Because dewatering in Cell 2 is ongoing, this cell will be included in the annual sampling effort. The CeJJ 2 slimes drain will be sampled using a disposable bailer. A disposable bailer will be used to collect Cell 2 slimes drain samples and will be used to fill clean sample containers. The bailer will be disposed of and not reused, thereby eliminating the need for decontamination of equipment or rinsate blanks. 3.4 Decontamination Decontamination of sampling equipment will be completed if non-dedicated and/or non-disposable sampling equipment is used to collect samples. Decontamination procedures will be as described in the approved QAP. Rinsate blanks will be collected daily after decontamination of sampling equipment. If disposable or dedicated sampling equipment is used to collect samples, then rinsate blanks will not be coJJected. 3.5 Field QC The field QC samples generated during the annual tailings cell, LDS and slimes drain sampling event will include sample duplicates, trip blanks, and rinsate blank samples as appropriate. 3.5 .l Sample Duplicates Sample duplicates will be collected at a frequency of one duplicate per 20 field samples. Sample duplicates will be collected by filling the sample container for a certain analytical parameter for the duplicate immediately following the collection of the parent sample for that parameter. 3.5.2 Trip Blanks Trip blank samples will be included in every shipment of samples that has field samples to be analyzed for Volatile Organic Compounds ("VOCs"). Trip blank samples are VOC sample containers filled by the analytical laboratory with laboratory grade deionized water and shipped to the site. Trip blank samples are taken into the field with the sample containers, never opened, and kept with the field samples from collection through shipment to the analytical laboratory for analysis. Trip blanks are analyzed to determine if the sample concentration of VOCs have been effected by the "trip" from collection through shipment. 3.5.3 Rinsate Blank Samples Rinsate blank samples are collected at a frequency of one per day when non-disposable, non-dedicated, reusable sampling equipment is used to collect samples. If the sampling equipment has a disposable component that comes in contact with the samples and the component is changed prior to sampling at each location then a rinsate blank sample will not be collected. For example, if a peristaltic pump is used to collect and filter tailings, LDS and slimes drain samples and the tubing used in the peristaltic pump is changed at each location and never reused for more than one sample, no rinsate blank sample would be required. 6 Tailings Cell, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 2.1 July 30, 2012 4.0 QA and Data Evaluation The Permit requires that the annual tailings cell LDS and slimes drain sampling program be conducted in compliance with the requirements specified in the Mill's approved QAP, the approved SAP and the Permit itself. To meet this requirement, the data validation for the tailings cell LDS and slimes drain sampling program will utilize the requirements outlined in the QAP, the Permit and the approved SAP as applicable. The Mill QA Manager will perform a QA/QC review to confirm compliance of the monitoring program with requirements of the Permit, QAP and SAP. As required in the QAP, data QA includes preparation and analysis of field QC samples, review of field procedures, an analyte completeness review, and quality control review of laboratory data methods and data. The QAP and the Permit identifY the data validation steps and data quality control checks required for the tailings cell LDS and slimes drain monitoring program. Consistent with these requirements, the Mill QA Manager will performed the following evaluations: a field data QA/QC evaluation, a receipt temperature check, a holding time check, an analytical method check, a reporting limit check, a trip blank check, a QAIQC evaluation of sample duplicates, a gross alpha counting error evaluation and a review of each laboratory's reported QA/QC information. The corrective action procedures described in the approved QAP will be followed as necessary when data validation and QC reviews indicate a non-compliant situation. 5.0 Laboratory Analysis As previously stated, samples will be analyzed for the groundwater compliance parameters listed in Table 2 of the GWDP and SVOCs using the analytical methods specified in the approved QAP and EPA Method 8270D for SVOCs. The Laboratories used for the tailings cell LDS and slimes drain sampling program will be Utah certified as required by the GWDP Part l.E.6 (c). Laboratory data will be validated as described in the approved QAP and as described in Section 4.0 above. Analytical QC is described below. 5.1 Analytical Quality Control Analytical QC samples and protocols are described in the approved QAP. Laboratory QC procedures will meet, at a minimum, the requirements set forth in the analytical methods that the laboratory is certified for by the State ofUtah. The analytical QC samples included at least the following: a method blank, a laboratory control spike ("LCS"), a matrix spike ("MS") and a matrix spike duplicate ("MSD"), or the equivalent, where applicable. It should be noted that: • Laboratory fortified blanks are equivalent to LCSs. • Laboratory reagent blanks are equivalent to method blanks. • Post digestion spikes are equivalent to MSs. • Post digestion spike duplicates are equivalent to MSDs. • For method E900.1, used to determine gross alpha, a sample duplicate was used instead of a MSD. 7 Tailings Cell, Leak Detections System and Slimes Drain Sampling and Analysis Plan Revision 2.1 July 30, 2012 All qualifiers, and the corresponding explanations reported in the QA/QC Summary Reports for any of the analytical QC samples for any of the analytical methods will be reviewed by the Mill QA Manager. The effect on data usability will be discussed in the evaluation section of the annual report. 6.0 Reporting A Tailings Cells Wastewater Quality Sampling Report will be included with the 3rd Quarter Groundwater Monitoring Report, due each year on December 151• Each Tailings Cel1 Wastewater Sampling Report will include the following information: • Introduction, • A description of sampling methodology, equipment and decontamination procedures identifY all quality assurance samples, e.g. trip blanks, equipment blanks, duplicate samples, • Analytical data interpretation for each tailing cell, slimes drain, and leak detection system sample, • A written summary and conclusions of analytical results, • A table summarizing historic analytical results, • A QA evaluation, • All field data sheets accompanying the sampling event, • Copies of the laboratory reports, and • A "Tailings and Slime Drains System Sample Locations Map". 7.0 Agency Notification At least 30 days advanced notice will be given to DRC prior to sampling activities described under this Tailings and Slimes Drain Sampling Program in order to allow the Executive Secretary to collect split samples of all tailing cell wastewater sources. 8 Attachment 1 9 ,... t 0 0.. MW..02 • \ MW..03 • 5CO' 0 500' 1,000' SCAlE: 1• a 1,000' CELL 1 MW-17 • 33 PIEZ·2 PIEZ-3 • • OTW4..S TW4·1flTW4•9 0 OTW4-3 OTW4-12 •1'bTW4·11 OTW4-13 TW4-~-8 OTW4·1 OTW4-4CTW4·14 OTW4·6 PIEZ-4 • PIEZ-5 • Denison Mines (USA) Corp San Juan Aurnor: unknown ANNUAL TAILINGS SAMPLE LOCATIONS Qale: Aug. 2008 Orabel By: 10 ., 0 /t_ 1.\ :c ·0 •·· CELL 1 LEAK DETECTION SAMPLE -==-=====-------~·~~~--~~--~W4& LOCATION 32 1-21 MW-D2 • CELL 48 MW-03 • 500' 1,000' -.......1'-----0 500' SCALE: 1' •1,000' MW-17 • CELL 2 33 PIEZ·2 • PIEZ-3 • OTW4-6 M ~26 TW4·1PJW4-9 0 OTW4-3 OTW4·12 OJW4-13 1W4-n8.a OTW4·1 PIEZ-4 • PIEZ·5 • Denison Mines (USA) Corp REVISIONS roject: White Mesa Mill Date By County: San Juan State: UT oca110n: 1~00 .~G~M~----~----------------------~ SLIMES AND LEAK DETECTION SAMPLE LOCATIONS Aulhor. unknown DIBltod By: Attaclunent 2 10 Field Data Record-Tailings, LDS and Slimes Drain Sampling Location: _________ Sampling Personnel: _________ _ Is this a Slimes Drain? DYes D No If this is a Slimes Drain, measure depth to wastewater immediately before sampling. DTW immediately before sampling (slimes only): ___________ _ Weather Conditions at Time of Sampling: _________________ _ Field Parameter Measurements: -pH -Temperature (°C) ----------------- Analytical Parameters/Sample Collection Method: Parameter Sample Taken Filtered i Sampling Method "'= -- VOCs o Yes DNo DYes DNo THF DYes DNo o Yes DNo Nutrients o Yes DNo o Yes oNo Other Non o Yes DNo DYes oNo Radiologies Gross Alpha DYes DNo DYes oNo SVOCs DYes DNo o Yes oNo Conductivity DYes DNo o Yes oNo QC Samples Associated with this Location: D Rinsate Blank D Duplicate Peristaltic r Bailer"" Pump D D D D D D 0 D D D D D D D Duplicate Sample Name: ____________ _ Ladle D D D 0 D D D Lab Name Notes: __________________________________ _ Appendix M Contingency Plan, 12/11 Revision: DUSA-4 White Mesa Mill-Standard Operating Procedures Book # 19-Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 1 of 15 WHITE MESA URANIUM MILL CONTINGENCY PLAN As Contemplated by Part I.G.4(d) of State of Utah Groundwater Discharge Permit No.UGW370004 Prepared by: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver CO 80265 December 2, 2010 White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 2 of 15 TABLE OF CONTENTS 1.0 INTRODUCTION ................................................................................................... 3 2.0 PURPOSE ................................................................................................................ 3 3.0 GROUNDWATER CONTAMINATION ............................................................... 3 3.1 Notification ........................................................................................................... 4 3.2 Continuation of Accelerated Monitoring ............................................................. 4 3.3 Submission of Plan and Timetable ....................................................................... 4 3.4 Groundwater Remediation Plan ........................................................................... 5 4.0 MILL DISCHARGE VIOLATIONS-INCLUDING UNAUTHORIZED DISCHARGE OR RELEASE OF PROHIBITED CONTAMINANTS TO THE TAILING CELLS ............................................................................................................... 6 4.1 Notifications ......................................................................................................... 6 4.2 Field Activities ..................................................................................................... 6 4.3 Request for Approvals and/or Waivers ................................................................ 7 5.0 DMT VIOLATIONS ............................................................................................... 7 5.1 Tailings Cell Wastewater Pool Elevation Above the Maximum Elevations ....... 7 5.2 Excess Head in Tailings Cells 2, 3, 4A, and 4B Slimes Drain Systems .............. 8 5.3 Excess Cell4A Leak Detection System Fluid Head or Daily Leak Rate ............ 9 5.4 Excess Cell 4B Leak Detection System Fluid Head or Daily Leak Rate ........... 10 5.5 Excess New Decontamination Pad Leak Detection System Fluid Head ........... 11 5.6 Cracks or Physical Discrepancies on New Decontamination Pad Wash Pad .... 11 5.7 Excess Elevation For Tailings Solids ................................................................. 12 5.8 Roberts Pond Wastewater Elevation .................................................................. 13 5.9 Feedstock Storage Area ....................................................................................... 13 5.10 Mill Site Chemical Reagent Storage .............................................................. 14 5.11 Failure to Construct as per Approval.. ............................................................ 15 5.12 Failure to Comply with Stormwater Management and Spill Control Requirements ................................................................................................................ 15 White Mesa Mill-Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 3 of 15 WHITE MESA URANIUM MILL CONTINGENCY PLAN State of Utah Groundwater Discharge Permit No. UGW370004 1.0 INTRODUCTION The State of Utah has granted Ground Water Discharge Permit No. UGW370004 (the "GWDP") for Denison Mines (USA) Corp.'s ("Denison's") White Mesa Uranium Mill (the "Mill"). The GWDP specifies the construction, operation, and monitoring requirements for all facilities at the Mill that have a potential to discharge pollutants directly or indirectly into the underlying aquifer. 2.0 PURPOSE This Contingency Plan (the "Plan") provides a detailed list of actions Denison will take to regain compliance with GWDP limits and Discharge Minimization Technology Plan ("DMT") and the Best Available Technology Plan ("BAT") requirements defined in Parts I.C, I.D, and I.H.4 of the GWDP. The timely execution of contingency and corrective actions outlined in this Plan will provide Denison with the basis to exercise the Affirmative Action Defense provision in Part I.G.3.c) ofthe GWDP and thereby avoid noncompliance status and potential enforcement action 1• The contingency actions required to regain compliance with GWDP limits and DMT and BAT requirements defined in Parts I.C, I.D, and I.H.4 of the GWDP are described below. 3.0 GROUNDWATER CONTAMINATION Since there are many different possible scenarios that could potentially give rise to groundwater contamination, and since the development and implementation of a remediation program will normally be specific to each particular scenario, this Plan does not outline a definitive remediation program. Rather, this Plan describes the steps that 1 Part I.G.3.c) of the GWDP provides that, in the event a compliance action is initiated against Denison for violation of permit conditions relating to best available technology or DMT, Denison may affirmatively defend against that action by demonstrating that it has made appropriate notifications, that the failure was not intentional or caused by Denison's negligence, that Denison has taken adequate measures to meet permit conditions in a timely manner or has submitted an adequate plan and schedule for meeting permit conditions, and that the provisions ofUCA 19-5-107 have not been violated. White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 4 of 15 will be followed by Denison in the event Denison is found to be out of compliance with respect to any constituent in any monitoring well, pursuant to Part I.G.2 of the GWDP. When the concentration of any parameter in a compliance monitoring well is out of compliance, Denison will, subject to specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: 3.1 Notification Denison will notify the Executive Secretary of the out of compliance status within 24 hours after detection of that status followed by a written notice within 5 days after detection, as required under Part I.G.4.a) of the GWDP. 3.2 Continuation of Accelerated Monitoring Denison will continue accelerated sampling for the parameter in that compliance monitoring well pursuant to Part I.G.l ofthe GWDP, unless the Executive Secretary determines that other periodic sampling is appropriate, until the facility is brought into compliance, as required under Part I.G.4.b) of the GWDP. If the accelerated monitoring demonstrates that the monitoring well has returned to compliance with respect to a parameter in a well, then, with written approval from the Executive Secretary, Denison will cease accelerated monitoring for that parameter, and will continue routine monitoring for that parameter. 3.3 Submission of Plan and Timetable If the accelerated monitoring confirms that the Mill is out of compliance with respect to a parameter in a well, then, within 30 days of such confirmation, Denison will prepare and submit to the Executive Secretary a plan and a time schedule for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain ground water quality to ensure that permit limits will not be exceeded at the compliance monitoring point and that DMT or BAT will be reestablished, as required under part I.G.4.c) of the GWDP. This plan will normally include, but is not limited to: a) The requirement for Denison to prepare a detailed and comprehensive operational history of the facility and surrounding areas which explores all activities that may have contributed to the contamination; White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 5 of 15 b) A requirement for Denison to complete an evaluation, which may include geochemical and hydrogeological analyses, to determine whether or not the contamination was caused by Mill activities or was caused by natural forces or offsite activities; c) If it is concluded that the contamination is the result of current or past activities at the Mill, Denison will prepare a Characterization Report, which characterizes the physical, chemical, and radiological extent of the ground water contamination. This will normally include a description of any additional wells to be used or installed to characterize the plume and the hydrogeologic characteristics of the affected zone, the analytical parameters to be obtained, the samples of ground water to be taken, and any other means to measure and characterize the affected ground water and contamination zone; and d) If it is concluded that the contamination is the result of current or past activities at the Mill, Denison will evaluate potential remedial actions, including actions to restore and maintain groundwater quality to ensure that permit limits will not be exceeded at the compliance monitoring point and that DMT and BAT will be reestablished, as well as actions that merely allow natural attenuation to operate and actions that involve applying for Alternate Concentration Limits ("ACLs"). ACLs require approval of the Water Quality Board prior to becoming effective. If groundwater remediation is required, Denison will prepare and submit for Executive Secretary approval a Ground Water Remediation Plan, as described in Section 3.4 below. 3.4 Groundwater Remediation Plan If the Executive Secretary determines that ground water remediation is needed, Denison will submit a Ground Water Remediation Plan to the Executive Secretary within the time frame requested by the Executive Secretary. The Ground Water Remediation Plan will normally include, but is not limited to: a) A description and schedule of how Denison will implement a corrective action program that prevents contaminants from exceeding the ground water protection levels or ACLs at the compliance monitoring point(s) or other locations approved by the Executive Secretary, by removing the contaminants, treating them in place, or by other means as approved by the Executive Secretary; b) A description of the remediation monitoring program to demonstrate the effectiveness of the plan; and c) Descriptions ofhow corrective action will apply to each source of the pollution. White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 6 of 15 Denison will implement the Ground Water Remediation Plan in accordance with a schedule to be submitted by Denison and approved by the Executive Secretary. 4.0 MILL DISCHARGE VIOLATIONS-INCLUDING UNAUTHORIZED DISCHARGE OR RELEASE OF PROHIBITED CONTAMINANTS TO THE TAILING CELLS Part I.C.2. of the GWDP provides that only lle.(2) by-product material authorized by the Mill's State of Utah Radioactive Materials License No. UT-2300478 (the "Radioactive Materials License") shall be discharged to or disposed of in the Mill's tailings cells. Part I.C.3 of the GWDP provides that discharge of other compounds into the Mill's tailings cells, such as paints, used oil, antifreeze, pesticides, or any other contaminant not defined as lle.(2) material is prohibited. In the event of any unauthorized disposal of contaminants or wastes (the "Unauthorized Materials") to the Mill's tailings cells, Denison will, subject to any specific requirements ofthe Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: 4.1 Notifications a) Upon discovery, the Mill Manager or RSO will be notified immediately; and b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery. 4.2 Field Activities a) Upon discovery, Mill personnel will immediately cease placement of Unauthorized Materials into the Mill's tailings cells; b) To the extent reasonably practicable and in a manner that can be accomplished safely, Mill personnel will attempt to segregate the Unauthorized Materials from other tailings materials and mark or record the location of the Unauthorized Materials in the tailings cells. If it is not reasonably practicable to safely segregate the Unauthorized Material from other tailings materials, Mill personnel will nevertheless mark or record the location of the Unauthorized Materials in the tailings cells; White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 7 of 15 c) To the extent reasonably practicable and in a manner that can be accomplished safely, Mill personnel will attempt to remove the Unauthorized Material from the tailings cells; and d) Denison will dispose of the removed Unauthorized Material under applicable State and Federal regulations with the approval of the Executive Secretary. 4.3 Request for Approvals and/or Waivers If it is not reasonably practicable to safely remove the Unauthorized Materials from the tailings cells, then Denison will, in accordance with a schedule to be approved by the Executive Secretary: a) Submit a written report to the Executive Secretary analyzing the health, safety and environmental impacts, if any, associated with the permanent disposal of the Unauthorized Material in the Mill's tailings cells; b) Apply to the Executive Secretary for any amendments that may be required to the GWDP and the Radioactive Materials License to properly accommodate the permanent disposal ofthe Unauthorized Material in the Mill's tailings cells in a manner that is protective of health, safety and the environment; and c) Make all applications required under the United States Nuclear Regulatory Commission's ("NRC's") Non-lle.(2) Disposal Policy (NRC Regulatory Issue Summary 2000-23 (November 2000), Interim Guidance on Disposal of Non- Atomic Energy Act of 1954, Section 11 e. (2) Byproduct Material in Tailings Impoundments), including obtaining approval ofthe Department of Energy as the long term custodian of the Mill's tailings, in order to obtain approval to permanently dispose of the Unauthorized Material in the Mill's tailings cells. 5.0 DMT VIOLATIONS 5.1 Tailings Cell Wastewater Pool Elevation Above the Maximum Elevations Part I.D.2 and Part I.D.6.d) of the GWDP provide that authorized operation and maximum disposal capacity in each of the existing tailings cells shall not exceed the levels authorized by the Radioactive Materials License and that under no circumstances shall the freeboard be less than three feet, as measured from the top of the flexible membrane liner ("FML"). White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 8 of 15 In the event that tailings cell wastewater pool elevation in any tailings cell exceeds the maximum elevations mandated by Part I.D.2 and Part I.D.6.d) of the GWDP, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; c) Upon discovery, Mill personnel will cease to discharge any further tailings to the subject tailings cell, until such time as adequate freeboard capacity exists in the subject tailings cell for the disposal of the tailings; d) To the extent reasonably practicable, without causing a violation of the freeboard limit in any other tailings cell, Mill personnel will promptly pump fluids from the subject tailings cell to another tailings cell until such time as the freeboard limit for the subject tailings cell is in compliance. If there is no room available in another tailings cell, without violating the freeboard limit of such other cell, then, as soon as reasonably practicable, Mill personnel will cease to discharge any further tailings to any tailings cell until such time as adequate freeboard capacity exists in all tailings cells; e) If it is not reasonably practicable to pump sufficient solutions from the subject tailings cell to another tailings cell, then the solution levels in the subject tailings cell will be reduced through natural evaporation; and f) Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to minimize the chance of a recurrence. 5.2 Excess Head in Tailings Cells 2, 3, 4A, and 4B Slimes Drain Systems Part I.D.3.b)l) of the GWDP provides that Denison shall at all times maintain the average wastewater head in the slimes drain access pipe in Cell 2 to be as low as reasonably achievable, in accordance with the Mill's currently approved DMT Monitoring Plan, and that for Cell3, this requirement shall apply only after initiation of de-watering operations. Similarly, Part I.D.6.c) of the GWDP provides that after Denison initiates pumping conditions in the slimes drain layer in Cell 4A, Denison will provide: 1) continuous declining fluid heads in the slimes drain layer, in a manner equivalent to the requirements found in Part I.D.3.b); and 2) a maximum head of 1.0 feet in the tailings (as measured from the lowest point of the upper FML) in 6.4 years or less. White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12111 Revision: DUSA-4 Page 9 of15 In the event that the average wastewater head in the slimes drain access pipe for Cell2 or, after initiation of de-watering activities, Cell 3 or initiation of pumping conditions in the slimes drain layer in Cell 4A exceeds the levels specified in the DMT Monitoring Plan, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Mill personnel will promptly pump the excess fluid into an active tailings cell, or other appropriate containment or evaporation facility approved by the Executive Secretary; c) If the exceedance is the result of equipment failure, Mill personnel will attempt to repair or replace the equipment; d) If the cause of the exceedance is not rectified within 24 hours, Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; and e) If not due to an identified equipment failure, Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to minimize the chance of a recurrence. 5.3 Excess Cell4A Leak Detection System Fluid Head or Daily Leak Rate Part I.D.6.a) provides that the fluid head in the Leak Detection System ("LDS") for Cell 4A shall not exceed 1 foot above the lowest point in the lower membrane liner, and Part I.D.6.b) of the GWDP provides that the maximum allowable daily leak rate measured in the LDS for Cell4A shall not exceed 24,160 gallons/day. In the event that the fluid head in the LDS for Cell 4A exceeds 1 foot above the lowest point in the lower membrane layer or the daily leak rate measured in the Cell4A LDS exceeds 24,160 gallons/day, Denison will, subject to any specific requirements ofthe Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Mill personnel will promptly pump the excess fluid into an active tailings cell, or other appropriate containment or evaporation facility approved by the Executive Secretary, until such time as the cause of exceedance is rectified or until such time as otherwise directed by the Executive Secretary; White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 10 of 15 c) If the exceedance is the result of equipment failure, Mill personnel will attempt to repair or replace the equipment; d) If the cause of the exceedance is not rectified within 24 hours, Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; and e) If not due to an identified equipment failure, Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to remediate the exceedance and to minimize the chance of a recurrence. 5.4 Excess Cell4B Leak Detection System Fluid Head or Daily Leak Rate Part I.D.13.a) provides that the fluid head in the Leak Detection System ("LDS") for Cell 4B shall not exceed 1 foot above the lowest point in the lower membrane liner, and Part I.D.13.b) of the GWDP provides that the maximum allowable daily leak rate measured in the LDS for Cell4B shall not exceed 26,145 gallons/day. In the event that the fluid head in the LDS for Cell4B exceeds 1 foot above the lowest point in the lower membrane layer or the daily leak rate measured in the Cell4B LDS exceeds 26,145 gallons/day, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Mill personnel will promptly pump the excess fluid into an active tailings cell, or other appropriate containment or evaporation facility approved by the Executive Secretary, until such time as the cause of exceedance is rectified or until such time as otherwise directed by the Executive Secretary; c) If the exceedance is the result of equipment failure, Mill personnel will attempt to repair or replace the equipment; d) If the cause of the exceedance is not rectified within 24 hours, Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; and If not due to an identified equipment failure, Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to remediate the exceedance and to minimize the chance of a recurrence. White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/ll Revision: DUSA-4 Page 11 of 15 5.5 Excess New Decontamination Pad Leak Detection System Fluid Head In order to ensure that the primary containment of the New Decontamination Pad water collection system has not been compromised, and to provide an inspection capability to detect leakage from the primary containment in each of the three settling tanks, a vertical inspection portal has been installed between the primary and secondary containment of each settling tank. Section 3.1 (e) of the Mill's DMT Monitoring Plan provides that the fluid head in the LDS for the New Decontamination Pad shall not exceed 0.10 feet above the concrete floor in any ofthe three standpipes. Compliance is defined in Part I.D.l4 a) ofthe GWDP as a depth to standing water present in any of the LDS access pipes of more than or equal to 6.2 feet as measured from the water measuring point (top of access pipe). In the event that the fluid head in the standpipe for a settling tank exceeds 0.10 feet above the concrete floor in the standpipe, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within the ensuing 24 hours followed by a written notification within five days; c) Mill personnel will promptly pump the fluid from the settling tank's LDS as well as the fluids in the settling tank into another settling tank or into an active tailings cell, or other appropriate containment or evaporation facility approved by the Executive Secretary, until such time as the cause of the exceedance is rectified or until such time as otherwise directed by the Executive Secretary; and d) Denison will perform a root cause analysis of the exceedance and, if appropriate, will implement new procedures or change existing procedures to remediate the exceedance and to minimize the chance of a recurrence. 5.6 Cracks or Physical Discrepancies on New Decontamination Pad Wash Pad. Soil and debris will be removed form the wash pad of the NDP in accordance with the currently approved DM1 Monitoring Plan. In the event that racks ofgreater than 1/8 inch (width) are observed on the concrete wash pad, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: White Mesa Mill -Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 12 of 15 a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) The NDP shall be taken out of service and the cracks will be repaired utilizing industry standard materials and procedures appropriate for the defect within five working days of discovery. Following recommended cure times, the cracks or deficiencies will be re-inspected and, if acceptable, the NDP will be placed back into service. c) A record of the repairs will be maintained as a part of the inspection records at the White Mesa Mill. 5.7 Excess Elevation For Tailings Solids Part I.D.3.c) ofthe GWDP provides that upon closure of any tailings cell, Denison shall ensure that the maximum elevation of the tailings waste solids does not exceed the top of the FML. In the event that, upon closure of any tailings cell, the maximum elevation of the tailings waste solids exceeds the top of the FML, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; c) To the extent reasonably practicable, without causing a violation ofthe freeboard limit in any other tailings cell, Mill personnel will promptly remove tailings solids from the subject tailings cell to another tailings cell, or other location approved by the Executive Secretary, until such time as the maximum elevation of the tailings waste solids in the subject tailings cell does not exceed the top of the FML; and d) Denison will perform a root cause analysis of the exceedance and will implement new procedures or change existing procedures to minimize the chance of a recurrence. White Mesa Mill-Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures 5.8 Roberts Pond Wastewater Elevation Date: 12/11 Revision: DUSA-4 Page 13 ofl5 Part I.D.3.e) of the GWDP provides that the Permittee shall operate Roberts Pond so as to provide a minimum 2-foot freeboard at all times and that under no circumstances shall the water level in Roberts Pond exceed an elevation of 5,624 feet above mean sea level. In the event that the wastewater elevation exceeds this maximum level, Denison shall remove the excess wastewater and place it into containment in Tailings Celli within 72 hours of discovery, as specified in Part I.D.3.e) of the GWDP. In the event that, Denison fails to remove the excess wastewater within 72 hours of discovery, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; and b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification and proposed corrective actions within five days of discovery. 5.9 Feedstock Storage Area Part I.D.3.f) and Part I.D.ll of the GWDP provide that open-air or bulk storage of all feedstock materials at the Mill facility awaiting Mill processing shall be limited to the eastern portion of the Mill site area described in Table 4 ofthe GWDP, and that storage of feedstock materials at the facility outside that area shall be performed in accordance with the provisions ofPart I.D.ll ofthe GWDP. In the event that, storage of any feedstock at the Mill is not in compliance with the requirements specified in Part I.D.3.f) and Part I.D.ll of the GWDP, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; c) Mill personnel will: White Mesa Mill-Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures Date: 12/11 Revision: DUSA-4 Page 14 of 15 (i) move any open-air or bulk stored feedstock materials to the portion of the Mill site area described in Table 4 of the GWDP; (ii) ensure that any feedstock materials that are stored outside of the area described in Table 4 of the GWDP are stored and maintained in accordance with the provisions ofPart I.D.11 ofthe GWDP; and (iii) to the extent that any such containers are observed to be leaking, such leaking containers will be placed into watertight over-pack containers or otherwise dealt with in accordance with the provisions of Part I.D .11 of the GWDP, and any impacted soils will be removed and will be deposited into the Mill's active tailings cell; and d) Denison will perform a root cause analysis of the non-compliant activity and will implement new procedures or change existing procedures to minimize the chance of a recurrence. 5.10 Mill Site Chemical Reagent Storage Part I.D.3.g) of the GWDP provides that for all chemical reagents stored at existing storage facilities, Denison shall provide secondary containment to capture and contain all volumes ofreagent(s) that might be released at any individual storage area, and that for any new construction of reagent storage facilities, the secondary containment and control shall prevent any contact of the spilled reagent with the ground surface. In the event that Denison fails to provide the required secondary containment required under Part I.D.3.g) of the GWDP, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification within five days of discovery; and c) Denison will promptly remediate any spilled re-agent resulting from the failure to provide the required secondary containment under Part I.D .3 .g) of the GWDP, by removal of the contaminated soil and disposal in the active tailings cell. White Mesa Mill-Standard Operating Procedures Book # 19 -Groundwater Discharge Permit Plans and Procedures 5.11 Failure to Construct as per Approval Date: 12/11 Revision: DUSA-4 Page 15 of 15 Part I.D.4 of the GWDP provides that any construction, modification, or operation of new waste or wastewater disposal, treatment, or storage facilities shall require submittal of engineering design plans and specifications, and prior Executive Secretary review and approval, and that a Construction Permit may be issued. In the event that, any new waste or wastewater disposal, treatment, or storage facilities are constructed at the Mill facility without obtaining prior Executive Secretary review and approval, or any such facilities are not constructed in accordance with the provisions of any applicable Construction Permit, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; and b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification and proposed corrective actions within five days of discovery. 5.12 Failure to Comply with Stormwater Management and Spill Control Requirements Part I.D.lO ofthe GWDP provides that Denison will manage all contact and non-contact stormwater and control contaminant spills at the Mill facility in accordance with the currently approved Stormwater Best Management Practices Plan. In the event that any contact or non-contact stormwater or contaminant spills are not managed in accordance with the Mill's approved Storm water Best Management Practices Plan, Denison will, subject to any specific requirements of the Executive Secretary as set forth in any notice, order, remediation plan or the equivalent, implement the following process: a) Upon discovery, the Mill Manager or RSO will be notified immediately; b) Denison will provide verbal notification to the Executive Secretary within 24 hours of discovery followed by a written notification and proposed corrective actions within five days of discovery; and c) To the extent still practicable at the time of discovery, Denison will manage any such contaminant spill in accordance with the Mill's approved Storm water Best Management Practices Plan. To the extent it is no longer practicable to so manage any such spill, Denison will agree with the Executive Secretary on appropriate clean up and other measures. Appendix N lVhite Mesa Mill Containerized Alternate Feedstock Material Storage Procedure, PBL-19, Revision: 1.0, December 18, 2012 No.: PBL-19 ENERGY FUELS RESOURCES (USA) INC. Rev. No.: 1 STANDARD OPERATING PROCEDURES Page 1 of3 Date: December 18, Title: Containerized Alternate Feedstock Material Storage 2012 Procedure 1.0 Purpose The purpose of this procedure is to assure that storage of feedstock material is conducted in a manner so as to preclude the release of Mill feed! material to the environment. 2.0 Scope Feed materials delivered to the White Mesa Mill must be stored in a manner which precludes the release of the materials to the environment. In the case ofbulk materials, such as unrefined natural ores and alternate feeds delivered in inter-modal containers, these materials are offloaded from the truck or shipping container directly onto the approved ore pad where migration of material is precluded by the pad's design and operating procedures (i.e. low permeability pad material, dust control procedures and limited stockpile height). However, certain feeds are received in drums or other containers which serve to effectively contain the material during storage and, as such, are amenable for storage either on the ore pad or at locations other than the ore pad. It is the intent of this procedure to describe the environmental safety precautions utilized for contained feed storage. 3.0 Procedure 3.1 Contained Feed Material Inspections All contained feed materials received at the White Mesa Mill are inspected upon arrival to determine that the containers are not leaking and to assure container integrity prior to placing the material into storage. Each container will be observed on all sides for damage or leakage of contents. All containers exhibiting signs of leakage will be re-packed or placed in over-pack containers prior to placing the materials into storage. Dented drums are acceptable if the dent is not located near a seam or when the dent is n.ot accompanied by a damage crease on the drum surface. Drums damaged by dents near the seam, crease damaged drums or containers that have been otherwise compromised during shipment are re-packed or placed in over-pack containers prior to storage. Containers which are not damaged at the time of receipt are transferred directly for placement at the storage location. 3.2 Storage Locations 3.2.1 Defined Feedstock Storage Feedstock materials stored at the defined storage location indicated on the map attached hereto as Attachment A) the "Defined Feedstock Area" can be stored in containers or in bulk form and are subject to the routine inspections described by the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan in Section 3.3 of the Mill's Environmental Protection Manual. I \ No.: PBL-19 Rev. No.: 1 !. ENERGY FUELS RESOURCES (USA) INC. STANDARD OPERATING PROCEDURES Page 2 of3 Date: December 18, 2012 Title: Containerized Alternate Feedstock Material Storage Procedure 3.2.2 Storage of Contained Feeds in Location Other Than the Defined Feedstock Area a) Over-pack Containers Materials received or transferred into over-pack containers can be stored at locations other than the Defined Feedstock Area absent a hardened ground surface or containment berms due to the fact that the over-pack container provides a secondary containment for the packaged material. Over-pack materials are subject to the routine inspections described by the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan at Section 3.3. b) Hardened Surface Storage Locations Contained feed materials, including materials in containers which have not been provided with over-pack protection, can be stored at locations other than the Defined Feedstock Area when a hardened ground surface storage location is used and has been provided with containment berms. These materials are subject to the routine inspections described by the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan at Section 3.3. c) Single Lined Containers Stored Outside the Defined Feedstock Area Where Hardened Surfaces and Containment Berms Are Not Utilized Contained feeds can also be stored in locations, other than the Defined Feedstock Area, that have been selected to avoid impact by site drainage and/or pooling. Prior to storage at these locations, planks or pallets are placed beneath the drum storage locations in order to raise the container from the ground surface and avoid corrosion from water which may accumulate during precipitation events (despite site selection) and from rusting due to soil moisture when drums are stored directly on the ground. These contained materials are subject to the more particular storage protocols and inspections outlined below. 3.3 Storage Protocol Single Lined Containers In accordance with MSHA requirements, container storage must be implemented in such a manner as t limit the potential for a container to tip or fall onto a worker. For drummed materials, the agency limits such stacks to three drums in height due to stability considerations. In keeping with these concerns, Denison will configure single lined storage drums (stored off the Designated Feedstock Area) in rows no more than two containers wide at the base and may place a one- container row either on top of a single row or in the middle of a lower two- container row, in each case so as to straddle the tops of drums in the lower container row(s). This stacking configuration distributes the single upper row No.: PBL-19 ENERGY FUELS RESOURCES (USA) lNC. Rev. No.: 1 STANDARD OPERATING PROCEDURES Page 3 of3 Date: December 18, Title: Containerized Alternate Feedstock Material Storage 2012 Procedure across bottom row(s) of containers in such a manner as to hold the bottom row(s) from leaning and allowing for limited stacking on top of these lower row(s). accordingly, when stacking is necessary, this configuration minimizes the risk of falling drums, limits stacking height for safety reasons and allows for a thorough inspection of each of the individual containers from the outside of the container row(s). 3.4 Single Lined Container Storage Area Inspections The single lined container storage area(s) that are off of the Designated Feedstock Area will be inspected on a weekly basis (and after significant precipitation events) on both sides of any row in order to assure that the stored materials remain intact, that standing water has not accumulated and that materials are not leaking or migrating from the storage area. 3.5 Single Lined Container Storage Inspection Records Denison will record all instances where single lined containers are received damaged (or leaking) and require re-packing or the provision of an over-pack container. This information will be recorded on a container receipt form (see Attachment B) which documents the receipt of drummed materials to be stored in locations other than the Defined Feedstock Area. Similarly, each weekly inspection shall be recorded on the inspection form referred to in the White Mesa Mill Tailings Management System Discharge Minimization Technology (DMT) Monitoring Plan at Attachment A-3 and attached as Attachment C to this procedure. Such inspections require the documentation of container condition, the drainage conditions in the storage location, the presence of leakage, if any, and any corrective actions taken due to leakage of containers or standing water at the storage location. Attachment A ( l ) Denison Mines (USA) Corp. JD ProjBtt WHITE MESA MILL Feedstock Storage Area Map Attachment B ) Containerized Alternate Feed Receipt Inspection Date:---------- Inspector:--------- Number of containers/drums in shipment:-------- Radiation Activity Levels:---------- Location of Storage:------------ Observations (note dented or damaged drums): Corrective Action Taken for Damaged Drums: Inspector Signature Attachment C ( ( - ) ( White Mesa Mill-Discharge Minimization Technology Monitoring Plan ATTACHMENT A-3 7/12 Revision: Denison12.1 Page 19 of26 ORE STORAGE/SAMPLE PLANT WEEKLY INSPECTION REPORT Week of ____ through _____ Date oflnspection:. _______ _ Inspector:. ___________ _ Weather conditions for the week: Blowing dust conditions for the week: Corrective actions needed or taken for the week: Are all bulk feedstock materials stored in the area indicated on the attached diagram: yes: no: ___ _ comments: __________________________________ _ Are all alternate feedstock materials located outside the area indicated on the attached diagram maintained within water-tight containers: yes: no: __ _ comments (e.g., conditions of containers); ________________ _ Are all sumps and low lying areas free of standing solutions? Yes: No: __ _ lf"No", how was the situation corrected, supervisor contacted and correction date? .Is there free standing water or water running off of the feedstock stockpiles? Yes: No: ---Commeo~: _________________________________________________________ _ E:\Mill SOP MastcrCopy\Book II_Environmental Procedures\07 License Renewai\EFR\DMT Plan July 2012 Rev 12 l.doc ( White Mesa Mill-Discharge Minimization Technology Monitoring Plan Other comments: 7/12 Revision: Denisonl2.1 Page 20 of26 E:\Mill SOP Master Copy\Book ll_Envlronmental Procedures\07 License Renewai\EFR\DMT Plan July 20 12 Rev 12 I. doc Appendix 0 White Mesa Mill Chemical Inventory Location Key Chern Lab CL Maintenance Shop/Ware house MSW Bulk Around the Mill Mill Chemical Name 1,10 Phenanthroline 1,10 Phenanthroline Ferrous Sulfate 1,2-Cyclohexylene Dinitrilo Tetraacetic Acid 1,4 Dioxane 1,5 Diphenylcarbazone 1-Amino-2-Naphthol-4-Sulfonic Acid 1-Butanol 1-Ethyl-2( ( 1 ,4dimethy 1-2-phenyl-6- pyrimidiny lidenemethal) Quinolinium Chloride 1-Hydroxyethylidene diphosphoric acid 3, 6-disulfonic Acid Disodium Salt 2-(5-Bromo-2-pyridylazo )-5- ( diethy I amino )phenol 2,2-BiPyridine 2-Butoxy ethanol 2-Carboxy-2'-hydroxy-5'-Sulfoformazyl 2-Propanol (Isopropanol) 3,6-Disulfaric-Acid Disodium 3-(i-decoxy) Propanoic Acid 3-(n-octoxy-n-decoxy) Propanoic Acid 4,4,4-Trifluoro-1-(2-Thienyl)-1 ,3- Butenediane 4-amine-1-naphthalene Sulfuric Acid 4-Amino-2-Naphthalene-Sulfonic Acid 5-( 4-Dime thy laminobenzy lidene) Rhodamine 8-Hydroxyquinoline Acetic Acid Acetic Anhydride Acetone Acrysol II-935 Adogen 2382 Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 90 g 1.25 72 3,400 g * 50 g 1.48 34 12,360 g 1.03 12,000 20 g 1.19 17 25 g 1.627 15 3,240 g 0.81 4,000 1 g * 435 g 1.45 300 0 g 0 5 g * 10 g 1.106 9 38 lb 0.9012 5 0 g 0 104,625 g 0.785 16,000 0 g 0 0 g 0 * 100 50 g 1.415 35 0 g 0 25 g 1.502 17 10 g 1.368 7 1,900 g 1.034 1,838 0 g 1.049 0 2,052 g 1.08 1,900 1,225 g 0.79 1,550 * 500 180 g 0.898 200 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 200 g 9 kg mL 200 g mL 47 L mL 20 g mL 10 g mL 20 L 5 g mL 10 g mL 40 g 5 g mL 1 L gal 20 L mL 5 g mL 18 L mL 10 g mL 0.1 L mL 0.1 L mL 50 g mL 0.1 L mL 25 g mL 10 g mL 2 kg mL 170 L mL 34 L mL 252 L mL 1 L mL 1 L Chemical Name Adogen 283 Adogen 382 AF9000 Alamine 308 Alamine 310 Alcohol Solvent, Denatured Alcohol, Alfol 12LE Alcohol, n-Amyl Alcohol, Reagent Aliquat 336 Alizarin Red Alizarin Yell ow Aluminum 1000 mg!L Aluminum Chloride Aluminum Hydroxide Aluminum Metal, granular Aluminum Nitrate Solution Aluminum Nitrate, Nonahydrate Aluminum Potassium Sulfate 12 Hydrate Crystal Aluminum Powder Aluminum Reagent 2 Aluminum STD 5000 ppm Aluminum Sulfate Crystal Aluminum Wire Amber lite AMCO Clear Turbidity 1.0 NTU AMCO Clear Turbidity 10 NTU AMCO Clear Turbidity 100 NTU AMCO Clear Turbidity 1000 NTU Ammonia Standard Ammonium 1-Pyrrolidine Carbodithioate Ammonium Acetate Ammonium Bicarbonate Ammonium Bifluoride Ammonium Chloride Ammonium Fluoride Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 898 g 0.898 1,000 359 g 0.898 400 * 1,000 * 800 * 1,500 8,982 g 0.791 11,355 1,660 g 0.83 2,000 0 g 0 28 kg 0.79 35 1 g 0.88 1 25 g 1.06 24 10 g * 500 g 1 500 800 g 2.44 328 500 g 2.4 208 750 g 2.7 278 104,099 g 1.1 25 98,000 g 1.058 92,628 500 g 1.757 285 300 g 2.7 111 * 56 0 g 0 250 g 1.69 148 400 g 2.7 148 500 g 1.02 490 100 g 1 100 4,000 g 1 4,000 4,000 g 1 4,000 4,000 g 1 4,000 0 g 0 25 g * 3,000 g 1.07 2,804 11,150 g 1.586 7,030 4,536 g 1.5 3,024 5,268 g 1.52 3,466 1,600 g 1.11 1,441 Historic volume or mass used (1978-2013) 1cm 3 -1 mL Quantity Unit mL 1 L mL 1 L mL 1 L mL 8 L mL 8 L mL 40 L mL 1 L mL 1 L L 4,156 L L 1 L mL 30 g 10 g mL 7 L mL 1 kg mL 1.5 kg mL 1 kg gal 385 gal mL 100 kg mL 0.5 k_g mL 5 kg mL 0.06 L mL 5 L mL 1 kg mL 0.5 kg mL 0.5 kg mL 16 L mL 16 L mL 16 L mL 16 L mL 1 L 30 g mL 3 kg mL 12 kg mL 5 kg mL 10 kg mL 2 kg Chemical Name Ammonium Hydroxide Ammonium Iodide Ammonium Meta-Vanadate Ammonium Molybdate-4-Hydrate Crystal Ammonium Nitrate Ammonium Oxalate Ammonium Peroxy Disulfate Ammonium Persulfate Ammonium Phosphate Monobasic Ammonium Sulfate Ammonium Thiocyanate Ammonium Vanadate Anion Exchange Resin Antimony Potassium Tartrate Antimony Powder Arsenic 1000 mg/L Arsenic Trioxide Ascarite Barbituric Acid Barium 1000 mg/L Barium 5000 ppm STD Barium Chloranilate Barium Chloride Barium DiPhenylamine sulfonate Barium Hydroxide Monohydrate Barium Nitrate Earlene, 310 I Bentonite Benzaldehyde Benzoic Oxime Beryllium 1000 mg/L Beryllium Sulfate Bismuth Powder Boron 1000 mg/L Boraxo Boric Acid Boron 1000 mg/L Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 38,165 g 0.898 42,500 4,000 g 2.51 1,594 650 g 2.32 280 2,300 g 2.498 921 11,022 g 1.72 6,408 19,300 g 1.5 12,867 3,000 g 1.98 1,515 2,100 g 1.98 1,061 5 lbs * 9,000 g 1.77 5,085 20,100 g 1.3 15,462 7,000 g 2.32 3,017 450 g 0.7 643 500 g 2.6 192 5 g 6.69 1 631 g 1.01 625 2,002 g 3.738 536 908 g 0.9 1,009 100 g 1.455 69 0 g 1.013 0 0 g 0 20 g * 6,800 g 3.856 1,763 10 g * 454 g 3.743 121 908 g 3.23 281 394 g 0.787 500 2,500 g 2.4 1,042 4,166 g 1.0415 4,000 700 g 1.13 619 * 250 113 g 2.443 46 20 g 9.8 2 0 g 0 0 g 1.73 0 30,000 g 1.435 20,906 0 g 1 0 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 64 L mL 4 kg mL 0.8 kg mL 3 kg mL 7.5 kg mL 33 kg mL 3 kg mL 200 g 3 kg mL 42 kg mL 30 kg mL 1 kg mL 0.5 kg mL 0.5 kg mL 5 g mL 5.5 L oz. 5,010 g mL 10 kg mL 100 g mL 0.125 L mL 2 L 25 g mL 63 kg 5 g mL 10 kg mL 1 kg mL 0.5 L mL 2.5 kg mL 4 L mL 1 kg mL 250 mL mL 0.2 kg mL 20 g mL 1 L mL 25 kg mL 10 kg mL 0.5 L Chemical Name Brake Fluid Bromine Bromo Padap Bromo Thymol blue Bromocresol Green Bromophenol blue Bromothymol Blue Brucine Sulfate buffer solution 1 PH buffer solution 1.65 PH buffer solution 10 PH buffer solution 12.45 PH Buffer Solution 2 pH Buffer Solution 4 pH Buffer Solution 7 pH Burco LAP-180 Burco LAF-6 Cadmium 1000 mg/mL Cadmium 5000 ppm STD Cadmium Metal Cadmium Nitrate Cadmium Powder Calcium Calcium 1000 mg!L Calcium Acetate Calcium Carbonate Calcium Chloride Dihydrate Calcium Chloride, Anhydrous Calcium Cyanide Calcium Fluoride Calcium Hydroxide Calcium Nitrate Calcium Oxide Calcium Sulfite Calumet 400-500 solvent Carbons, Granular Gwar Carboxy Methyl Carminic Acid Appendix 0-1 Laboratory Chemical lnventol'y Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 974 g 1.03 946 * 50 5 g 1.39 4 60 g 1.25 48 5 g 0.981 5 68 g 0.954 71 0 g 0 10 g * 0 g 0 0 g 0 38,000 g 1 38,000 0 g 0 1,900 g 1 1,900 3,800 g 1 3,800 2,000 g 1 2,000 * 400 400 g 1 400 * 500 0 g 0 500 g 8.64 58 454 g 2.455 185 10 g 8.64 1 25 g 1.54 16 300 g 1 300 453 g 1.5 302 24,100 g 2.93 8,225 2,500 g 1.71 1,462 1,500 g 1.086 1,381 1,000 g 1.853 540 950 g 3.18 299 3,100 g 2.24 1,384 2,768 g 2.36 1,173 4,268 g 3.3 1,293 3,000 g 2.5 1,200 3,000 g 0.83 2 16,500 g 0.95 17,368 720 g * 10 g 1.87 5 Historic volume or mass used (1978-2013) 1cm 3 -1 mL Quantity Unit mL 1 L mL 0.1 L mL 5 g mL 100 g mL 10 g mL 310 g mL 40 g 10 g mL 158 L mL 10 L mL 158 L mL 2 L mL 147 L mL 210 L mL 194.5 L mL 1 L mL 1 L 0 0.5 L mL 2 L mL 0.5 kg mL 0.5 kg mL 0.5 kg mL 25 g mL 6.5 L mL 0.5 kg mL 100 g mL 3 kg mL 2 kg mL 4 kg mL 3 kg mL 10 kg mL 3 kg mL 5 kg mL 4 kg L 4 L mL 1 kg 1 kg mL 10 g Chemical Name Caustlag Ceric Ammonium Sulfate Dihydrate Ceric Sulfate Cerium Oxalate Cesium Nitrate Chem-FAC 100 Chesterton Moisture Shield Chloramine-T-Hydrate Chloride standard Chloroform Chromium 1000 mg/L Chromium 5000 mg/L Chromium Cr 6 Standard Chromium Trioxide Citric Acid Anhydrous Citric Acid Monohydrate Cobalt Chloride Cobalt Metal Cobalt Nitrate 6-Hydrate Cobalt Powder Compressed Gas (Argon) Compressed Gas (Nitrogen) Compressed Gas (Helium) Compressed Gas (oxygen) Compressed Gas (Ammonia Anhydrous) Compressed Gas Acetylene Compressed Gas Nitrous Oxide Compressed Gas Propane Conductivity Calibration Standard, NIST Traceable Conductivity Traceable 1,000 !!S Conductivity Traceable 150,000 j..tS Conostan 75 base oil for AA diluent Contract 70 . Copper Copper 1000 mg/L Com Starch Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 0 g 0 2,020 g * 500 g 3.01 166 0 g 0 5 g 3.685 1 * 250 397 g 0.8 496 10 g 1.4 7 0 g 1 0 1,484 g 1.484 1,000 70 g 1 70 100 g 1 100 0 g 2.7 0 100 g 2.7 37 5,100 g 1.542 3,307 0 g 0 250 g 3.35 75 600 g 1.03 583 500 g 1.88 266 5 g 8.9 1 6,000 cf * 5,500 cf * 10,000 cf * 5 cf * 8 cf * 0 cf 0 cf 500 cf * 927 g 1.03 900 9,500 g 1 9,500 1,000 g 1 1,000 0 g 0 21,200 g 1.06 20,000 430 g 8.92 48 203 g 1.014 200 454 g 0.67 678 Historic volume or mass used (1978-2013) 1cm 3 -1 mL Quantity Unit mL 3 kg 3 kg mL 3 kg mL 1 kg mL 5 g mL 0.25 L mL 0.5 kg mL 25 g mL 1 L mL 1978 L mL 1.5 L mL 2 L mL 0.125 L mL 0.5 kg mL 10 kg mL 1 kg mL 25 g mL 1 kg mL 0.5 kg mL 5 g 497,364 cf 152,775 cf 30,583 cf 1,600 cf 1,600 cf 1,600 cf 1,600 cf 17,829 cf mL 32 L mL 26 L mL 1 L mL 1 L mL 20 L mL 1 kg mL 3 L mL 5 lb Chemical Name CP 1400P CP 2000P Crystal Violet Crystalline silica Cupferron Crystal Cupric Sulfate 5-Hydrate Cupric Sulfate Anhydrous Curcumin Crystalline Cyanex 923 Cyclohexane Decyl Alcohol 99% DEHPA DEHPA in Kerosene DF53A DF-57-85-1 D-Gluconic Acid D-Gluconic Acid Calcium Salt 99% Dialkyl Methyl amine Diaminocyclohexane Diatamacious Earth Dibenzoyl Methane 98% Dibutyl phosphate Digestion Solution for COD, (83% sulfuric acid, 1% mercuric sulfate) Dimethyl Sulfoxide Dinitropheny lazo Dioctylsodium Sulfosuccinate DiPhenyl amine 4 sulfuric Acid Diphenyl-carbazone DiPhenylThioCarbazone Diphonix Resin DiPyridal Disodium Ethylenediamine Tetraacetate Ditex 1812C d-Tartaric Acid Ecopol-LLDS Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 300 g * 50 g * 25 g 1.19 21 0 g 0 2,600 g * 2,300 g 2.284 1,007 454 g 3.603 126 10 g 1.279 8 24 Kg 0.88 28 18,285 g 0.7781 23,500 1,230 g 0.82 1,500 17,873 g 0.974 18,350 974 g 0.974 1,000 * 250 * 250 500 g 1.763 284 0 g 0 1,070 g 1.07 1,000 0 g 0.931 0 0 g 0.26 0 50 g 1.138 44 529 g 1.058 500 0 g 0 550 g 1.1 500 0 0 275 g 1.1 250 10 g * 1 g 1.19 1 5 g 1.2 4 13,300 g 0.3 44,333 5 g 1.106 5 500 g 1.01 495 * 1,000 10,300 g 1.8 5,722 1,000 g * 1,000 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit 0.1 kg 0.1 kg mL 25 g mL 1 kg 23.8 kg mL 3 kg mL 0.5 kg mL 10 _g L 30 L mL 20 L mL 5 L mL 1 L mL X X mL 0.25 L mL 0.25 L mL 0.5 kg mL 0.1 kg mL 1 L mL 0.5 kg mL 100 kg mL 500 g mL 0.5 L mL 1 L mL 0.5 L 0 50 g mL 1 kg 110 g mL 20 g mL 20 g mL 2 kg mL 5 g mL 0.5 kg mL 1 L mL 12 kg mL 1 kg Chemical Name Elan 6100 DRC Set up/ Stab/ Masscal Sol. Elan DRC Smart Tune Electrode filling solution (Ag/AgCl) Electrode storage solution (KCl soln.) Empigen BS/FQ Eriochrome black Escaid 115 Ethanol absolute Ether Anhydrous Ethyl Acetate EthyleneDiamine Tetraacetic Acid Ethylene Dinitrilo Tetraacetic acid Ethylene Glycol Monobutyle Ether Ferric Ammonium Sulfate Dodecahydrate Ferric chloride 6-Hydrate Ferrous Ammonium Sulfate Ferrous Chloride Ferrous Sulfate Ferrous Sulfate Heptahydrate Elan 6100 DRC Wash Solution Flexane 94 liquid Floc 912 SH Floc 920 SH Floc Acrylamide Homopolymer Floc ChemTreat P-802E Floc DVS4F011 Floc Ethylene Oxide Polymer WSR 205 (2195) Floc Ethylene Oxide Polymer WSR Coagulant (2331) Floc Hycem AF 102 Floc Hycem AF 104 Floc Hycem AF 105 Floc Hycem AF 205 Floc Hycem AF 306 Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume * 800 * 1,000 0 mL * 0 0 g 0 * 500 35 g 1.109 32 * 20,000 3,156 g 0.789 4,000 2,854 g 0.7134 4,000 9,471 g 0.902 10,500 1,000 g 0.86 1,163 75 g 0.86 87 0 g 0 0 g 1.71 0 1,800 g 1.82 989 5,000 g 1.86 2,688 1,000 g 3.16 316 0 0 6,000 g 0.999 6,006 0 g 1 0 908 g * 1,000 0 g 0 0 g 0 0 g 0 0 lb 0 * 100 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 2 L mL 12 L mL 5 L mL 20 L mL 0.5 L mL 10 g mL 20 L mL 4 L mL 10 L mL 15 L mL 3.1 kg mL 0.1 kg mL 0.25 L mL 2 kg mL 3.75 kg mL 144 kg mL 1 kg mL 5 kg mL 43.5 kg mL 0.5 L mL 1 L mL 150 g mL 150 g mL 50 g gal 18 kg mL 100 mL mL 250 g mL 250 g mL 20 g mL 20 g mL 20 g mL 20 g mL 20 g Chemical Name Floc Hycem AF 308 Floc Hycem AF 311 Floc Hycem NF 301 Floc Hycem NF 305 Floc Hyperfloc AF 104 Floc Hyperfloc AF 208 Floc Hyperfloc AF 250 Floc Hyperfloc AF 302 Floc Hy_perfloc AF 303 Floc Hyperfloc AF 304 Floc Hyperfloc AF 305 Floc Hyperfloc AF 306 Floc Hyperfloc AF 307 Floc Hyperfloc AF 308 Floc Hyperfloc AF 309 Floc Hyperfloc AF 312 Floc Hyperfloc AF 314 Floc Hy_perfloc AF MG 653 Floc Hyperfloc CB 478 .Floc Hyperfloc CP 624 Floc Hyperfloc CP 757 Floc Hyperfloc CP 902 H Floc Hyperfloc CP 903 Floc Hyperfloc MG 653 Floc Hyperfloc MG 655 Floc Hyperfloc MG 656 Floc Hyperfloc NF 201 Floc Hyperfloc NF 301 Floc Hysperse 1015 Floc Hysperse 1016 Floc Hysperse 1018 Floc MagnaFloc 10 Floc MagnaFloc 1011 Floc MagnaFloc 156 Floc MagnaFloc 333 Floc MagnaFloc 336 Floc MagnaFloc 338 Floc MagnaFloc 342 Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 50 g * 50 g * 100 g * 100 g * 100 g * 50 g * 50 g * 50 g * 50 g * 50 g * 50 g * 100 g * 100 g * * 90 * 45 * 10 50 g * 50 g * 100 g * 40 g * 50 g * 40 g * 50 g * 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 20 g mL 20 g mL 20 g mL 20 g mL 25 g 50 g 50 g 100 g 100 _g 100 g 50 g 50 g 50 g 50 g 50 g 50 g 100 g 23 kg mL 90 mL mL 45 mL gal 10 gal 50 g 50 g 100 g 40 g 50 g 40 g 50 _g mL 0.1 L mL 0.1 L mL 0.1 L mL 80 g mL 80 g mL 80 g mL 80 g mL 80 g mL 80 g mL 80 g Chemical Name Floc MagnaFloc 351 Floc MagnaFloc 358 Floc MagnaFloc 371 Floc MagnaFloc 455 Floc MagnaFloc 7117 Floc MagnaFloc 7692 Floc MagnaFloc 919 Floc Nalco DVS4F011 Floc NEO NS 4507 Floc NEO NS 4525 Floc NEO NS 6500 Floc NEO NS 6501 Floc NEO NS 6502 Floc NEO NS 6502m Floc NEO NS 6511 Floc NEO NS 6555 Floc Non-ionic Floc Percol 156 Floc Percol 333 Floc Percol 336 Floc Percol 338 Floc Percol 342 Floc Percol 351 Floc Percol 352 Floc Percol 358 Floc Percol371 Floc Percol 408 Floc Percol 455 Floc Percol 727 Floc Percol 728 Floc Percol 919 Floc Percol E10 Floc Ucarfloc Polymer 30x B-6070 Floc Ucarfloc Polymer 30x B-6107 Floc Ucarfloc Polymer 30x Batch 155836 Floc Ucarfloc Polymer 30x C-6076 Floc Ucarfloc Polymer 30x C-6102 Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 0 g 0 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 80 g mL 80 g mL 80 g mL 80 g mL 80 g mL 80 g mL 80 g mL 250 mL mL 20 g mL 20 g mL 20 g mL 20 g mL 20 g mL 20 g mL 20 g mL 20 g mL 23 kg mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 50 g mL 0.25 kg mL 0.25 kg mL 0.25 kg mL 0.25 kg mL 0.25 kg Chemical Name Floc Ucarfloc Polymer 30x H-6049 Floc Ucarfloc Polymer 30x R-6046 Floc Ucarfloc Polymer 30x S-6045 Fluoride w/TISAB Std 1 ppm Fluoride w/TISAB Std 10ppm Fluoride w/TISAB Std 100ppm Fluoride standard solution Formaldehyde Fritz EP-9LMwB Gallium Metal Gentian Violet Glacial Acetic Acid Glycerin Gold 1000 mg/L Greatfloc 5410 Greatfloc 5413 Greatfloc 5420 Hexanes Hyamine, Hydroxide Hydrazine Sulfate Hydrobromic acid 49% Hydrochloric acid Hydrochloride (0.1N) Hydrochloride (1N) Hydroflouric Acid Hydrogen Peroxide Hydroiodic acid Hydroquinone Hydroxy Naphthol blue Hydroxylamine Hydrochloride Hydroxylamine Sulfate ICP-MS Internal Standard ICP-MS Interference Check Sol. #1 ICP-MS Interference Check Sol. #2 Iodine Monochloride Solution Iodine Solution 1N Iodine Sublimes Ionquest 801 Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 0 g 0 0 g 0 0 g 0 * 950 * 475 * 950 425 g 1 425 1,041 g 1.1 946 0 g 0 1 _g 5.904 0 100 g 1.19 84 11,020 g 1.0495 10,500 126 g 1.2636 100 * 125 0 g 0 0 g 0 0 g 0 13,000 g 0.66 20 467 g 0.933 500 1,600 g 1.37 1,168 10,200 g 1.49 6,846 39,100 g 1.15 34,000 * 100 13,800 g 1.15 12,000 2,500 g 1.25 2,000 2,260 g 1.13 2,000 1,000 g 1.96 510 600 g 1.32 455 26 g 2.13 12 1,500 g 1.67 898 1,000 g 1.86 538 * 500 * 125 * 125 1,060 g 1.06 1,000 500 g 1 500 454 g 3.835 118 * 350 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 0.25 kg mL 1 kg mL 0.5 kg mL 5 L mL 5 L mL 5 L mL 20.5 L mL 1 L mL 0.1 L mL 1 g mL 200 g mL 40 L mL 12 L mL 125 mL mL 50 g mL 50 g mL 50 g L 25 L mL 0.5 L mL 5 kg mL 12 kg mL 4,826 L mL 30 L mL 30 L mL 231 L mL 92 L mL 1 kg mL 1 kg mL 10 g mL 19.5 kg mL 1 kg mL 4 L mL 125 mL mL 125 mL mL 1 L mL 2.5 L mL 1 k_g mL 1 L Chemical Name Iron 1000 mg/L Iron 5000 ppm STD Iron Metal Iron Pyrites Iron Sulfate Hydrate !so-Octane Jet Fuel Type A KP5000 Lanthanum 1000 mg/L Lanthanum Oxide L-Ascorbic Acid Lead (II) Acetate Trihydrate Lead (II) Carbonate Lead 1000 ~-tg/mL Lead Metal Lead Nitrate Lead Oxide Lithium 1000 ~-tg/mL Lithium Fluoride Lithium M -borate Lithium borates (with Bromide) Lithium borates (with Iodide) Lithium Chloride Lithium Tetra borate LIX 664N-LV LIX 984 N Magnesium 1000 mg/L Magnesium Carbonate Magnesium Nitrate Magnesium Nitrate Hexahydrate Magnesium Oxide Magnesium Perchlorate Magnesium Sulfate Manganese 1000 ~-tg/ mL Manganese 5000 ppm STD Manganese Carbonate Manganese Chloride Manganese Dioxide Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 508 g 1.015 500 0 g 0 3,000 g 7.86 382 5,436 g 5.1 1,066 2,500 g 3.097 807 40 Kg 0.692 58 16 Kg 0.8 20 0 g 0 500 g 1 500 520 g 6.51 80 4,150 g 1.954 2,124 500 g 2.55 196 500 g 6.14 81 408 g 1.02 400 34,050 g 11.34 3,003 454 g 4.53 100 2,400 g 9.53 252 0 g 1.03 0 3,400 g 2.64 1,288 100 g 1.4 71 19,000 g * 5,500 g 1.4 3,929 500 g 2.068 242 250 g 0.25 1,000 * 500 * 500 432 g 1.016 425 0 g 0 200 g 0.889 225 1,000 g 1.63 613 479 g 3.58 134 500 g 2.21 226 3,000 g 1.07 2,804 0 g 1.015 0 0 g 0 2,350 g 3.12 753 200 g 2.98 67 2,650 g 5.02 528 Historic volume or mass used (1978-2013) 1cm 3 -1 mL Quantity Unit mL 6.5 L mL 1 L mL 1.2 kg mL 6 kg mL 3 kg L 1,304 L L 20 L mL 1 kg mL 1.25 L mL 6.1 kg mL 5 kg mL 1 kg mL 0.5 kg mL 2.5 L mL 100 lb mL 0.5 kg mL 3 kg mL 2.5 L mL 4 kg mL 0.5 kg 25 kg mL 20 kg mL 1 kg mL 1 kg mL 0.5 L mL 2 L mL 7 L mL 0.1 kg mL 3.5 kg mL 1 kg mL 1 kg mL 1 kg mL 9 kg mL 4 L mL 1 L mL 3 kg mL 0.2 kg mL 3 kg Chemical Name Manganese Flake Manganese Sulfate M-Cresol purple Mercuric Acetate Mercuric Chloride Mercuric Iodide Mercuric lithinate Mercuric Nitrate ( .1410 N) Mercuric Nitrate Monohydrate Mercuric Sulfate Mercury Cm Oxide Mercury 1000 [!g/mL Mercury Metal Methanol Methyl Red Methyl Ethyl Ketone Methyl isobutyl ketone Methyl orange Methyl Red Hydrochloride Methyl Red Sodium Salt Methyl violet Methylene blue Methylene Chloride Molybdenum 1000 mg/L Molybdenum Powder Molybdenum STD 5000 ppm Molybdenum Trioxide Molybdic Anhydride Monoethanol Amine MS-811 MSA-1 (New Resin) N-(lnaphthyl) ethylene Diarnine Dihydrochloride n-Amyl Alcohol n-Butyl Acetate n-Butyl-Phosphate n-Decanal NEA-96 Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 0 g 7.3 0 2,800 g 3.25 862 26 g 1.37 19 100 g 3.29 30 250 g 5.44 46 150 g 6.36 24 0 g 0 35,120 g 4.39 8,000 1,500 g 4.3 349 113 g 6.47 17 100 g 11.14 9 g * 1,000 8 lb 13.54 251 7,515 g 0.791 9,500 2.5 g 0 3,220 0.805 4,000 18 g 0.802 23 195 g 0.987 198 125 g 0.8 156 60 g 0.791 76 100 g * 25 g 1 25 15,816 g 1.318 12,000 500 g 1 500 100 g 10.3 10 0 g 0 1,700 g 4.692 362 453 g 4.692 97 1,018 g 1.018 1,000 * 500 0 g 0 50 g * 398 g 0.8416 473 720 g 0.9 800 66,776 g 0.982 68,000 0 g 0 1,218 g 2.435 500 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 50 g mL 0.5 kg mL 395 g mL 0.1 kg mL 0.25 kg mL 400 g mL 0.1 kg mL 274 L mL 2 kg mL 0.2 kg mL 0.1 kg mL 1 L mL 10 kg mL 154 L mL 1 kg mL 12 L mL 152 L mL 10 g mL 10 g mL 130 g 5 g mL 200 g mL 100 L mL 4.5 L mL 0.1 kg mL 1 L mL 2 kg mL 1 kg mL 1 L mL 0.5 L mL 0.5 L 50 g mL 1 L mL 1 L mL 289 L mL 1 L mL 0.5 L Chemical Name Nesslers Reagent Nickel Nickel 1000 mg/L Nickel 5000 mg!L Nickel Nitrate Nickel Powder Niobium 1000 mg/L Nitrate ISA Nitrate, nitrogen STD Nitrazine yellow Nitric Acid Nitrobenzene NonEmulsifier 19N Nonoxynol-4 N-Phenylbenzohydroxamic Acid Octyl Acid Phosphate Oleic Acid (Solution) Oleic Acid (Solid) Orform ORP Standard 0-Tolidine Dihydrochloride Oxalic Acid Oxicol P-802E Flocculent Paraffin PE Sciex Coolant Pentyl Acetate Perchloric Acid Phenanthroline Phenol Red Phenolphtalein Phosphoric Acid Phosphorus 1000 f.tg/rnL Phosphorus 5000 ppm STD Polymer 300 Polymer 302 Polymer 304 Polyol Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g!cm3 Volume 1,600 g 1.28 1,250 110 g 8.9 12 0 g 1.014 0 0 g 0 3,000 g 2.05 1,463 10 g 8.9 1 * 105 3,111 g 1.31 2,375 2,500 g 1 2,500 20 g * 43,594 g 1.42 30,700 1,440 g 1.2 1,200 460 g 0.92 500 0 g 0 50 g 1.27 39 1,000 g 1 1,000 4,923 g 0.895 5,500 3,000 g 1.09 2,752 * 5,750 200 g 1 200 100 g 1.03 97 1,200 g 1.9 632 0 g 0 0 g 0 400 g * * 5,000 1,000 g 0.876 1,142 4,184 g 1.6736 2,500 0 0 25 g 1.477 17 226 g 1.299 174 49,820 g 1.88 26,500 250 g 1 250 0 g 0 0 g 0 0 g 0 1,000 g * 1,100 g * Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit rnL 2.5 L rnL 0.2 kg rnL 3.5 L rnL 1 L rnL 3 kg rnL 10 g rnL 250 rnL rnL 2 L rnL 2 L 20 g rnL 3,109 L rnL 15 L rnL 0.5 L rnL 0.5 L rnL 25 g rnL 1 L rnL 10 L rnL 5 kg rnL 6 L rnL 1 L rnL 100 g rnL 5 kg rnL 10 g rnL 1 L 10 kg rnL 25 L rnL 1 kg rnL 1,487 L rnL 0.25 kg rnL 25 g rnL 0.25 kg rnL 1,665 L rnL 5.5 L rnL 1 L rnL 0.25 L rnL 0.25 L 0.25 L 1 L Chemical Name Polyox Polyox WSR Coagulant Polyox WSR-205 Potassium 1000 f-lg/mL Potassium 5000 r-tg/mL Potassium Acetate Potassium Bicarbonate Potassium Biiodate Potassium Biphthalate Potassium Biphthalate Buffer Potassium Bromate Potassium Bromide Potassium Carbonate Potassium Chlorate Potassium Chloride Potassium Chloride solution 4 M Potassium Chromate Potassium Cyanide Potassium dichromate Potassium ferricyanide Potassium Ferrocyanide trihydrate Potassium Fluoride Potassium Iodate Potassium Iodide Potassium Iodide-Iodate Potassium Nitrate Potassium Nitrite Potassium Oxalate Monohydrate Potassium Perchlorate Potassium Permanganate Potassium Permanganate Solution Potassium Perrhenate Potassium Persulfate Potassium Phosphate Potassium pyrosulfate Potassium Sodium Tartrate 4-Hydrate Potassium Sulfate Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g!cm3 Volume 1,000 * 500 g * 500 g * 304 g 1.013 300 0 g 0 250 g 1.57 159 500 g 2.17 230 50 g * 1,800 g 1.64 1,098 0 g 1.636 0 500 g 3.27 153 5,600 g 3.119 1,795 400 g 2.43 165 2,250 g 2.32 970 1,500 g 1.98 758 296 g 1 10 200 g 2.732 73 454 g 1.52 299 5,150 g 7.14 721 1,100 g 1.85 595 500 g 1.85 270 600 g 2.48 242 500 g 3.93 127 16,140 g 1.32 12,227 0 g 1 0 250 g 2.109 119 250 g 1.92 130 5,000 g 2.127 2,351 500 g 2.52 198 9,300 g 1.01 9,208 3,000 g 1 3,000 10 g 4.887 2 100 g 2.47 40 0 g 2.564 0 500 g 2.28 219 1,400 g 1.05 1,333 2,000 g 2.66 752 Historic volume or mass used (1978-2013) 1cm 3 -1 mL Quantity Unit 10 kg 1 L 0.5 L mL 8 L mL 1 L mL 100 g mL 0.5 kg 3 L mL 2 kg mL 2 L mL 0.5 kg mL 6 kg mL 0.5 kg mL 3 kg mL 10 kg oz 20 L mL 0.2 kg mL 1 kg mL 6 kg mL 1 kg mL 0.5 kg mL 0.5 kg mL 0.5 kg mL 0.5 kg mL 0.5 L mL 100 g mL 0.25 kg mL 392 kg mL 3 kg mL 50 kg mL 1 L mL 10 g mL 0.2 kg mL 50 g mL 500 g mL 1.5 kg mL 1 kg Chemical Name Potassium Thiocyanate Primene Primene 81-R Amine Primene JM-T Amine PrimeneMD Primene TOA Amine Propylether Chloride Guar Gum Pyridine Pyrogallate Absorption stable solution, (Potassium Hydroxide Solution) Quinhydrone Quinoline Rantec KP5000 Red Gaye Oil Rexyn 101 Rexyn 300 SAG 101 Salt (kiln dried) Salt, Medium Scandium 1000 mg/L Sea sand Selenium 1000 ~-tg/mL Selenium Oxide Silicon 1000 mg/L Silicon 5000 mg/L Silicon Carbide Silver 1000 ~-tg/mL Silver Chloride Silver Nitrate (Solid) Silver Nitrate (Solution) Silver sulfate Smart Tune Solution Sodium 1000 mg/L Sodium Acetate Anhydrous Sodium Acetate trihydrate Sodium Ammonium Phosphate Sodium Arsenite Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 9,750 g 1.886 5,170 0 g 0 1,230 g 0.82 1,500 40,032 g 0.834 48,000 * 100 1,078 g 0.77 1,400 330 g 1.3 254 7,855 g 0.9819 8,000 0 g 0 2,100 g 1.32 1,591 545 g 1.09 500 920 g * 0 g 0.826 0 500 g 1.2 417 200 g 1.2 167 0 g 0 45 lb 1.199 17,024 270 g 1.199 225 * 450 10,000 g 2.6 3,846 0 g 1.02 0 10 g 4.81 2 485 g 0.97 500 0 g 0 0 g 0 125 g 1 125 0 g 0 2,600 g 4.35 598 69,600 g 4.35 16,000 200 g 5.45 37 * 1,000 405 g 1.013 400 2,300 g 1.528 1,505 2,450 g 1.45 1,690 950 g 1.54 617 500 g 1.87 267 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 4.5 kg mL 8 L mL 1 L mL 100 L mL 1 L mL 1 kg mL 1 kg mL 47 L mL 1 L mL 5 kg mL 0.5 L 1 kg mL 2 L mL 0.5 kg mL 1.5 kg mL 0.5 L mL 50 kg mL 50 kg mL 0.5 L mL 50 kg mL 1.5 L mL 10 g mL 8 L mL 1 L mL 25 g mL 1 L mL 4 L mL 24.5 kg mL 32 L mL 0.5 kg mL 12 L rnL 5 L mL 37 kg mL 36 kg mL 4 kg mL 1.5 kg Chemical Name Sodium Bicarbonate Sodium Bisulfate Sodium Borate Sodium Carbonate, Anhydrous Sodium Chlorate Sodium Chloride Sodium Chloride Solution Sodium Citrate Sodium Cyanide Sodium Diphenylamine Sodium Diphenylamine-4-Sulfonate Sodium Fluoride Sodium Hydrosulfide Sodium Hydroxide Sodium Hydroxide (1N) Sodium Hydroxide (50%) Sodium Hydroxide pellets Sodium m-Bisulfite Sodium Molybdate Sodium Nitrate Sodium Nitrite Sodium Oxalate Sodium Peroxide Sodium Persulfate Sodium phosphate deca-hydrate Sodium Phosphate Tribasic Sodium Phosphate, Dibasic 12-Hydrate Sodium Pyrophosphate Decahydrate P.A. Sodium reconditioning solution Sodium Salicylate Sodium Silicate Sodium Sulfate, 12-Hydrate Sodium Sulfate, Anhydrous Sodium Sulfide Sodium Sulfite, Anhydrous Sodium Sulfonate Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g!cm3 Volume 11,200 _g 2.16 5,185 3,000 g 2.1 1,429 400 g 1.73 231 8,500 g 2.53 3,360 6,555 g 2.49 2,633 10,950 g 1.199 9,133 0 g 1 0 6,000 g 1.008 5,952 500 g 1.6 313 20 g * 25 g * 10,050 g 1.02 9,853 3,500 g 1.79 1,955 5,791 _g 1.53 1 13,520 g 1.04 13,000 1,530 g 1.53 1,000 12,000 g 1.515 7,921 17,500 g 1.48 11,824 1,000 _g 3.78 265 17,000 g 1.1 15,455 7,500 g 2.168 3,459 400 g 2.34 171 500 g 2.8 179 150 g 2.4 63 500 g 1.82 275 1,350 g 1.62 833 750 g 1.52 493 500 g 2.534 197 2,850 g 1 2,850 400 g 0.35 1,143 600 g 2.33 258 0 g 0 4,500 g 2.68 1,679 0 g 0 12,000 g 2.63 4,563 0 g 1 0 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 15 kg mL 10 kg mL 1.5 kg mL 125.5 kg mL 10 kg mL 96 kg mL 10 L mL 15 kg mL 4 kg 100 g 60 _g mL 70.6 kg mL 1 kg gal 42 kg mL 256 L mL 32 L mL 30 kg mL 25 kg mL 1 kg mL 20 kg mL 10 kg mL 1 kg mL 3 kg mL 0.5 kg mL 0.5 kg mL 1 kg mL 1 kg mL 0.25 kg mL 3 L mL 0.5 kg mL 1 kg mL 3 kg mL 10 kg mL 0.2 kg mL 23 kg mL 0.5 L Chemical Name Sodium Tartrate Dihydrate Sodium Thiocyanate Sodium Thiosulfate Anhydrous Sodium tripoly phosphate Sodium Tungstate, Dihydrate Soltrol220 (Aliphatic Hydrocarbene) Soluble Starch Stannous Chloride, Dihydrate Starch Solution Starch, soluble potato, powder Stearic Acid Stilbene Strontium 1000 f-tg/mL Strontium Carbonate Strontium Chloride Succinic Anhydride Sulfa salicylic Acid Dihydrate Sulfa Ver 4 (sulfate reagent) Sulfarnic Acid Sulfanilamide Sulfanilic Acid Sulfate Anion STD Sulfosalicy lie Acid Sulfur I ,000 ppm Sulfur Sublimed Sulfuric Acid Sulfuric Acid (.IN) Sulfuric Acid (IN) Surfactant, Tergitol NP-7 SX diluent (Conoco) SX Solvent Extraction Diluent TA-100 Sample Tannic Acid Tantalum I 000 J-tg/mL TCHEM Defoamer 4I1 0 Tetrasodium (salt dihydrate) TFE Paste Thalic Nitrate Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 1,050 g 1.82 577 3,850 g 1.295 2,973 14,680 g 1.01 14,535 500 g 0.4 1,250 400 g 4.179 96 402 g 0.803 500 40 g 1.5 27 2,700 g 2.71 996 1,000 g 1 1,000 300 g 1.5 200 575 g 0.84 685 1 g 1.14 1 0 g 1 0 450 g 3.7 122 250 g 3 83 250 g 1.572 159 4,620 g 0.8 5,775 450 g 2.68 168 2,000 g 2.12 943 100 g 1.08 93 100 g 1.485 67 0 g 0 0 g 1.705 0 100 g I IOO 500 g 2.36 212 28,600 g I 28,600 I7,000 g I I7,000 3I,280 g 1.84 17,000 * 1,010 0 g 0 0 g 0 * I,300 I,400 g 2.I29 658 * 125 * 200 800 g * * 118 25 g * 125 Historic volume or mass used (1978-2013) lcm 3 -1 mL Quantity Unit mL 2 kg mL 5 kg mL 20 kg mL 0.5 kg mL 0.5 kg mL 1 L mL 1 kg mL 5 kg mL 1.5 L mL 3 kg mL 25 g mL 5 g mL 0.125 L mL 0.5 kg mL 0.25 kg mL 0.25 kg mL 3 kg mL 0.5 kg mL 23.5 kg mL 100 g mL 200 g mL 1 L mL 1 kg mL 2.5 L mL I kg mL 2,245 L mL 30 L mL 63 L mL 1.5 L mL 0.2 L mL 0.5 L mL 0.5 L mL 2 kg mL 2.6 L mL I L I kg mL I20 mL mL 25 g Chemical Name Thallium Nitrate THAM (tris (Hydroxymethyl) Amino methane) also TRIS Tharin ThenoylTriFluoroacetone Thio Acetamide Thorin Thorium 1000 mg/L Thymol blue Tin Metal TISAB Buffer Solution TISAB Il w/CDTA TISAB Ill w/CDTA TISAB w/CDTA Titanic Oxide Titanium 1000 mg/L Toluene Trans-1,2-DiAminocyclohexane Tetra Acetic Acid Tricapryl Methyl Ammonium Chloride Trichloroethylene Triethanolamine Triethanolamine Triethylamine Tri-N-Octylamine Trioctylphosphine Oxide Turbidity Standard Uranium 1000 !lg/mL Uranium Oxide Uranyl Acetate Urea Vacuum Pump Oil Vanadium 1000 !lg/mL Vanadium 5000 !lg/mL Vanadium Pentoxide V anady 1 Sulfate Varsol110 Solvent Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 1 g 5.55 1 5,010 g 1.353 3,703 0 g 0 50 g * 900 g 1.37 657 15 g * 625 g 1 625 10 g * 500 g 7.3 68 * 6,000 6,195 g 1.07 5,790 1,017 g 1.07 950 0 g 0 500 g 4.26 117 * 150 10,363 g 0.8636 12,000 0.5 g * 0 g 0 18,375 g 1.47 12,500 21,809 g 1.13 19,300 0 g 1.13 0 2,555 g 0.73 3,500 2,754 g 0.81 3,400 1,200 g 0.88 1,364 4,500 g 1 4,500 592 g 1.03 575 0 g 10.96 0 1,816 g 2.89 628 40,000 g 1.335 29,963 37 lb 0.9 5 * 500 0 g 0 800 g 6.11 131 250 g 2.5 100 3,699 g 0.822 4,500 Historic volume or mass used (1978-2013) 1cm 3 -1 mL Quantity Unit mL 1 g mL 10 kg mL 50 g 50 g mL 5 kg 15 g mL 1.5 L 10 g mL 0.5 kg mL 20 L mL 8 L mL 3 L mL 9 L mL 0.5 kg mL 1.5 L mL 15 L 10 g mL 0.1 L mL 10 L mL 3 kg mL 255 L mL 16 L mL 24 L mL 3 kg mL 36 L mL 10 L mL 2 kg mL 10 kg mL 407 kg gal 150 L mL 5 L ml 1 L mL 100 g mL 6.6 kg mL 5 L Chemical Name Victawat 12 Vinegar Viscocity Standard 100 Viscocity Standard 1000 Witbreak 770 Witbreak DRI-9026 Witbreak RTC-426 Witconate P-1020Bust Witconol DNP-45 Witconol NP-40 YSl 3682 Zobell solution Zinc 5000 ppm STD Zinc Acetate Zinc Metal Zinc Sulfate Zinc on Zirconium 1000 mg/L Zirconium Chloride Zirconium Oxide Zirconium Sulfate Zirconyl Chloride Appendix 0-1 Laboratory Chemical Inventory Current Volume and Mass at the Mill Quantity Unit Density g/cm3 Volume 0 g 0 0 g 0 * 3,000 * 1,000 1,020 g 1.02 1,000 * 500 118 g 1.18 100 250 g 1.05 250 500 g 1.06 500 500 g 1.06 500 * 0 0 g 0 700 g 1.84 380 1,500 g 7.14 210 500 g 1.005 498 2 g * 102 g 1.02 100 100 g 2.8 36 453 g 5.89 77 0 g 0 0 g 0 lcm3 -1 mL mL mL rnL mL mL rnL mL mL rnL mL mL mL mL rnL mL mL mL mL mL rnL *Pursuant to Section I.E.9b) of the GWDP dated August 24, 2012, the Permittee shall provide "Determination of volume and mass of each raw chemical currently held in storage at the facility." Both mass and volume are provided when specific gravity data are available. Laboratory chemicals are stored in the laboratory or in the laboratory storage areas adjacent to the laboratory. Abbreviations: lbs =pounds gal = gallons cf = cubic feet ml =milliliters g = grams kg = kilograms L =liters oz =ounces Historic volume or mass used (1978-2013) Quantity Unit 10 L 4 L 5 L 3 L 1 L 0.5 L 1 L 0.25 L 0.5 L 0.5 L 0.125 L 1 L 1 kg 1.5 kg 1 kg 2 g 4 L 1 L 1 kg 0.1 kg 50 g Appendix 0-2 Current Mill Chemical Inventory Current Volume and Mass at the Mill4 Quantity Specific Gravity Approximate Location Chemical Name (lbs) or Bulk Density Volume (gal) Mill Alamine 336 Drums 0 0.80 sp.g 0 Alarnine 336 Totes 30,600 0.80 sp.g 4,592 Mill Ammonia (East) 55,554 5.15 lb/gal 1,295 Ammonia (West) 109,794 5.15 lb/gal 2,559 Mill Ammonium sulfate (North) 53,787 65.00 lb/cu.ft 99 Mill Ammonium sulfate (South) 50,248 65 .00 lb/cu.ft 93 Ammonium Sulfate Super Mill Sacks 18,000 65.00 lb/cu.ft 33 Mill Caustic 50% 71,525 1.00 sp.g 8,586 De-Scaler (ChemSearch Mill 150 or equivalent) 660 1.16 sp.g 68 Diatomaceous Earth Filter Mill Aid 70,200 2.30 S.Q.g 3,664 Mill Flocculant 6551 39,600 0.80 sp.g 5,942 Mill Hydrogen Peroxide 50% 7,189 1.20 sp.g 722 Mill Hyper Floc 757 Coagulant 0 0.80 sp.g 0 Mill Kerosene 20,545 0.82 sp.g 3,026 Mill Liquified Natural Gas 89,425 0.40 sp.g 26,838 Mill Perlite Filter Aid 10,623 2.30 sp.g 554 Mill Propane 23,605 0.50 sp.g 5,622 Mill Salt 117,470 2.16 sp.g 6,529 Mill Soda ash silo 61,328 0.99 sp.g 7,437 Mill Soda ash Super Sacks 82,000 0.99 sp.g 9,943 Mill Sodium chlorate 1-50% 19,825 6.13 lb/gal 388 Mill Sodium chlorate 2-50% 67,171 6.13 sp.g 1,315 Mill Sodium chlorate 3-50% 0 6.13 sp.g 0 Sodium Chlorate Super Mill Sacks 46,000 1.32 sp.g 4,199 Mill Sulfuric Acid 94% 3,752,986 1.84 sp.g 244,858 Mill Tri -decyl alcohol 3 23,485 0.83 sp.g 3,397 1The Mill uses a number of comparable polymer flocculants depending on the specific feed. 2 Current tertiary amine product name as purchased from BASF. Alternatively, the Mill has and may continue to use other tertiary arnines with comparable chemical properties. 3Current alcohol used as modifier. Alternatively, the Mill has and may continue to use other secondary and tertiary alcohols, including isodecanol, among others, to improve tertiary arnine!U/kerosene solubility. Historic volume or mass used (1978-2013) Quantity Unit 1,538,782 lbs :j: lbs 34,861,910 lbs :j: 44,266,008 lbs :j: lbs :j: lbs 42,332,116 lbs 3,960 lbs 1,000,000 lbs 1,149,225 lbs 537,973 lbs 1,395 lbs 15,067,139 lbs 23,371,465 lbs 604,158 lbs 7,309,158 lbs 63,111,955 lbs 76,472,417 lbs :j: lbs 30,978,629 lbs :j: lbs :j: lbs :j: lbs 757,297,581 lbs 967,383 lbs 4Pursuant to Section I.E.9b) of the GWDP dated August 24,2012, the Permittee shall provide "Determination of volume and mass of each raw chemical currently held in storage at the facility." Both mass and volume are provided when specific gravity data are available. t -Historic values reported are the total quantity used at all locations. The historic quantities are reported as a single total for the first location listed. Abbreviations: lbs =pounds lb/gal-pounds per gallon lb/cu.ft =pounds per cubic foot sp.g = specific gravity Appendix 0-3 Cleaners and Maintenance/Miscellaneous Chemicals Historic volume or mass Current used (1978-2013) Location Cleaners Quantity Units Quantity Unit MSW #2 EP Grease Shell Retinax LXZ 796 lbs 3300 lbs MSW #5182 Pyroshield Grease I oil 4,560 lbs 21660 lbs MSW #7 4 AB compound 334 lbs 1587 lbs MSW 150 Gear Oil 880 gal 4312 gal MSW 15-40w Motor Oil 2,035 gal 8435 gal MSW 220 Gear Oil 5,720 gal 26000 gal MSW 2-cycle oil 5.25 gal 20 gal MSW 2pH Buffer 38.6 gal 206 gal MSW 30w motor oil Rotella T 660 gal 2805 gal MSW 460 Gear Oil 1,540 gal 6718 gal MSW 4pH Buffer 39.6 gal 211 gal MSW 5w-30 synthetic blend oil 110 gal 421 gal MSW 680 gear oil 4,015 gal 17514 gal MSW 7pH Buffer 46 gal 245 gal MSW 80-90w gear oil 110 gal 110 gal MSW Acetylene bottle 32,754 cf 141008 cf MSW Air tool lubricant 16.4 gal 67 gal MSW Ajax 164 gal 697 gal CL Ajax 4,257 ml :j: CL Alcon ox 5,500 g 500 kilos CL Alcotabs 3,060 g 60 kilos MSW Alumina Desiccant 1,500 lbs 1,500 lbs MSW Aluminum spray paint 13 gal 61 gal MSW Anti-Freeze 990 gal 4,377 gal MSW Anti-seize lubricant 23 gal 109 gal MSW Argon mixed gas 15,226 cf 63,114 cf MSW Argon T -large 6,289 cf 27,074 cf MSW Auto Trans Fluid 220 gal 1,096 gal CL Baking Soda 5,235 g 60 kilos MSW Blue spray _paint 20.98 gal 85 gal MSW Brake cleaner 75 gal 338 gal MSW Brake fluid 21 gal 101 gal MSW Bredel hose lubricant 583 gal 2,857 gal CL Chromerge 0 L 3 L MSW Cutting oil coolant 24 gal 104 gal CL Dawn (dish soap) 5,842 ml 300 L MSW Devcon Brushable Ceramic 2 lbs 2 lbs MSW Devcon Flexane Putty 92 lbs 437 lbs MSW Donax TC-50 Transmission Oil 550 gal 3,529 gal Appendix 0-3 Cleaners and Maintenance/Miscellaneous Chemicals Historic volume or mass Current used (1978-2013) Location Cleaners Quantity Units Quantity Unit MSW Dura pro cream 2 gal 2 gal Electronic Instrument Componet MSW Cleaner 4 gal 22 gal Endurbond intermediate primer #2 MSW red 65 gal 438 gal MSW Endurbond Primer # 1 green 55 _gal 438 gal MSW Endurbond Tack Cement #3 Black 150 gal 920 gal MSW Fantastik 444 gal 1,777 gal CL Fantastik 946 ml :j: MSW Ferric Chloride 660 gal 660 gal MSW General Epoxey 0.31 gal 0 gal MSW glass bead blast media 35 gal 35 gal MSW Glossy black spray paint 248 _gal 1,054 gal MSW Glossy white sprayiJaint 320.6 _gal 1,313 gal MSW Go-Jo hand cleaner 918 lbs 4,004 lbs MSW Gray primer spray paint 107 gal 438 gal MSW Grease tubes 2,320 lbs 6,874 lbs MSW Green Spray paint 8 gal 38 gal MSW Hydraolic jack oil 24 gal 117 gal MSW Hydraulic oil #68 4,455 gal 18,467 gal MSW Industrial Degreaser 3 gal 20 gal MSW Ingersol Rand Coolant 40 gal 40 gal MSW Iso Heat gas line 6 gal 20 gal CL Compound 454 g 100 g MSW Juvenile Gray paint 6 gal 6 gal MSW Laundry Soap 17,610 lbs 72,996 lbs MSW Liquid Flexane 94 Devcon 104 lbs 460 lbs CL Liqui-Nox Cleaner 0 200 L MSW Long term grease cart. 4 lbs 4 lbs MSW Lubriplate Polymer Grease Tube 2 gal 2 gal CL Lysol 1,500 ml :j: MSW Lysol 390 gal 1,543 gal MSW Mask out paint -tan 1.22 gal 1 gal MSW Metal Set A4 4 lbs 16 lbs MSW Methyl Ethyl Ketone #366 605 gal 3,286 gal MSW Mop&Glo 74 gal 338 gal CL Mop&Glo 100 ml :j: MSW Never wet spray coating kit 0.11 gal 0 gal MSW Oil absorbent floor dry 7,950 lbs 31,800 lbs Appendix 0-3 Cleaners and Maintenance/Miscellaneous Chemicals Historic volume or mass Current used (1978-2013) Location Cleaners Quantity Units Quantity Unit MSW Orange spray paint 27 gal 113 gal MSW Oxygen Cylinder TOX 75,900 cf 303,600 cf MSW paint marker 1 gal 7 gal MSW Pipe Dope 39 gal 156 gal MSW Plastic Epoxy 0.31 gal 0 gal MSW Pledge (Lemon) 18.2 gal 75 gal CL Pledge 2,124 g :j: MSW Power Steering Fluid 80 gal 297 gal CL Professional Drain Cleaner 950 mL 4 L MSW PVC Cement #711 39 gal 158 gal MSW PVC primer #9-70 purple 30 gal 132 gal MSW Ridgid thread cutting oil 25 gal 109 gal MSW Safety Red Paint 52 gal 52 gal MSW Safety Yell ow Paint 24 gal 24 gal MSW Safety Yell ow spray paint 143 gal 609 gal MSW Scotch Kote, coating 1 gal 5 gal MSW Silicone Adhesive 3 gal 15 gal MSW Silicone Sealant 230 gal 955 gal MSW small propane cylinders 96 lbs 409 lbs MSW Spa Blue Paint 490 gal 1,182 gal MSW Spa Blue Spray Paint 96 gal 265 gal MSW Spraflex Lubricant 10 gal 46 gal MSW Starting fluid 90 gal 307 gal MSW Sullair Coolent 490 gal 2,259 gal MSW Sweeping compound oil base 7,350 lbs 29,066 lbs MSW T-Chlor liquid chlorine 12% 45 gal 96 gal MSW Tellas 32 Hydroaulic oil 385 gal 385 gal MSW The works bowl cleaner 21 gal 42 gal MSW Tidy pearl pink liquid soap 185 _gal 787 gal MSW WD-40 150 _gal 496 gal MSW White Metal Marker 2 gal 9 gal MSW Windex 240 gal 995 gal CL Windex 968 ml :j: MSW Windshield washer fluid 251 gal 1,053 gal :j: -Historic values reported are the total quantity used at all locations. The historic quantities are reported as a single total for the first location listed. Abbreviations: lbs =pounds 1 Location 1 gal = gallons cf = cubic feet ml = milliliters g =grams kilos = kilograms L =liters Appendix 0-3 Cleaners and Maintenance/Miscellaneous Chemicals Historic volume or mass Current used (1978-2013) Cleaners Quantity I Units Quantity I Unit Location. of Storage or Use Leach circuit Leach circuit UraniumSX Uranium SX Appendix 0-4 Historic/Formerly Used Chemicals Chemicals Formerly Used at Mill/No Longer Used or Present on Site 1 Time Period of Total Quantity Chemical Form Use Used 2 Several months Dry solid in during 1997 or No more than several Ammoniu m Bi-tluoride SuperSaks 1998 thousand lbs. Several months during 1997 or No more than 10,000 Hydrochloric Acid Drummed liquid 1998 gallons Several months during 1997 or No more than 2,000 J-Mt primary amine Drummed Liquid 1998 .gallons Several months Tri octyl phosphine during 1997 or No more than 2,000 oxide ("TOPO") Drummed liquid 1998 gallons Current Status None on site since 1998 None on site since 1998 3 None on site since 1998 None on site since 1998 1. These reagents were used during processing of one alternate feed for 6 months in 1997/1998, and have not been used before or since. 2. Total quantities used are also the total quantities purchased over life of the alternate feed project, that is, total on site was this quantitiy or less. 3. Unused residual consumed from 1997 to 1999 for cleaning purposes. 1.0 INTRODUCTION 5 1.1 Background 5 1.2 Applicable Standards for Review and Approval of this Application 5 1.3 Background Groundwater Reports and Re-opening of Permit 9 2.0 INFORMATION PROVIDED IN SUPPORT OF THE APPLICATION 2.1 Name and Address of Applicant and Owner (R317-6-6.3.A) 2.2 Legal Location of the Facility (R317-6-6.3B) 18 2.3 Name and Type of Facility (R317-6-6.3.C) 2.4 A Plat Map Showing All Water Wells, Including The Status And Use Of Each Well, Drinking Water Source Protection Zones, Topography, Springs, Water Bodies, Drainages, And Man-Made Structures Within A One-Mile Radius Of The Discharge. (R317-6-6.3.D) 1!WJ 2.5 Geologic, Hydrologic, and Agricultural Description of the Geographic Area (R317-6-6.3.E) 2.5.1 Groundwater Characteristics 2.5.1.1 Geologic Setting 2.5.1.2 Hydrogeologic Setting 2.5.1.3 Perched Zone Hydrogeology 2.5.1.4 Perched Groundwater Flow 2.5.1.5 Perched Zone Hydrogeology Beneath And Downgradient OfThe Tailings Cells 2.5.2 Groundwater Quality 2.5.2.1 Entrada/Navajo Aquifer 2.5.2.2 Perched Groundwater Zone 2.5.3 Springs and Seeps 2.5.4 Topography 2.5.5 Soils 2.5.6 Bedrock 2.5.7 Agricultural and Land Use Description of the Area 2.5.8 Well Logs 2~ 2019 2019 20 21~ 25B 27~ 28~ 28~ 28~ 29~ 3~ 3~ 3~ .2!~ 31~ 2.6 The Type, Source, and Chemical, Physical, Radiological, and Toxic Characteristics of the Effluent or Leachate to be Discharged (R317-6-6.3.F) 32a9 2.7 Information Which Shows that the Discharge can be Controlled and Will Not Migrate Into or Adversely Affect the Quality of any Other Waters of the State (R317-6-6.3.G) 33iQ 2.7.1 General 3339 2.7.2 Cells 1, 2 and 3 33M 2.7.2.1 Design and Construction of Cells 1, 2 and 3 33M 2.7.2.2 Improved Groundwater Monitoring 3~ 2.7.2.3 Operational Changes and Improved Operations Monitoring 35~ 2.7.2.4 Evaluation ofTailings Cell Cover System Design 35~ 2.7.3 Ceii4A 36~ 2.7.4 Ceii4B 1 2.7.5 Future Additional Tailings Cells 2.7.6 Roberts Pond 2.7. 7 Other Facilities and Protections 2.7.7.1 Feedstock Storage 2.7.7.2 Mill Site Reagent Storage 2.7.7.3 New Construction 2.7.7.4 Other 2.7.8 Surface Waters 2.7.9 Alternate Concentration Limits 41~ 41~ 42~ 42~ 4349 4349 4349 444± 444± 2.8 For Areas Where the Groundwater Has Not Been Classified by the Board, Information of the Quality of the Receiving Ground Water (R317-6-6.3.H) ~ 2.8.1 Existing Wells at the Time of Original Permit Issuance 45Q 2.8.2 New Wells Installed After the Date of Original Issuance of the Permit 45Q 2.9 Sampling and Analysis Monitoring Plan (R317-6-6.3.1) 4643 2.9.1 Groundwater Monitoring to Determine Groundwater Flow Direction and Gradient, Background Quality at the Site, and the Quality of Groundwater at the Compliance Monitoring Point 46~ 2.9.1.1 Groundwater Monitoring at the Mill Prior to Issuance of the Permit 46~ 2.9.1.21ssuance of the Permit 4~ 2.9.1.3 Current Ground Water Monitoring Program at the Mill Under the Permit 2.9.1.4 Groundwater Flow Direction and Gradient 2.9.1.5 Background Quality at the Site 2.9.1.6 Quality of Ground Water at the Compliance Monitoring Point 2.9.2 Installation, Use and Maintenance of Monitoring Devices 2.9.2.1 Compliance Well Monitoring 2.9.2.2 Leak Detection System in Cell 4A and Cell 4B 2.9.2.3 Other DMT Monitoring Requirements 2.9.3 Description of the Compliance Monitoring Area Defined by the Compliance Monitoring Points 2.9.4 Monitoring of the Vadose Zone 2.9.5 Measures to Prevent Ground Water Contamination After the Cessation of Operation, Including Post- Operational Monitoring 524& 2.9.5.1 Measures to Prevent Ground Water Contamination After the Cessation of Operation 524& 2.9.5.2 Post-Operational Monitoring 524& 2.9.6 Monitoring Well Construction and Ground Water Sampling Which Conform Where Applicable to Specified Guidance 524& 2.9.6.1 Monitoring Well Construction 524& 2.9.6.2 Ground Water Sampling 2.§-Q 2.9.7 Description and Justification of Parameters to be Monitored 56-9 2.9.8 Quality Assurance and Control Provisions for Monitoring Data 57-9 2.10 Plans and Specifications Relating to Construction, Modification, and Operation of Discharge Systems (R317- 6-6.3.J) 58i4 2.11 Description of the Ground Water Most Likely to be Affected by the Discharge (R317-6-6.3.K) 2.11.1 General 2.11.2 Background Ground Water Quality in the Perched Aquifer 2.11.3 GWCL Determination for Field pH 2.11.4 Quality of Ground Water at the Compliance Monitoring Point 2.12 Compliance Sampling Plan (R317-6-6.3.L) 2.12.1 Tailings Cell Wastewater Quality Sampling Plan 2.12.2 White Mesa Seeps and Springs Sampling Plan 2 5855 58~ 59~ 64W 66~ 2.12.3 Monitoring of Deep Wells 2.13 Description of the Flooding Potential of the Discharge Site (R317-6-6.3.M) 2.13.1 Surface Water Characteristics 2.13.2 Flood Protection Measures 2.14 Contingency Plan (R317-6-6.3.N) 2.15 Methods and Procedures for Inspections of the Facility Operations and for Detecting Failure of the System (R317-6-6.3.0) 7oei 2.15.1 Existing Tailings Cell Operation 2.15.2 Existing Facility DMT Performance Standards 2.15.2.1 DMT Monitoring Wells at Cells 1, 2 and 3 2.15.2.2 Slimes Drain Monitoring 2.15.2.3 Maximum Tailings Waste Solids Elevation 2.15.2.4 Wastewater Elevation in Roberts Pond 2.15.2.5 Inspection of Feedstock Storage Area 2.15.2.6 Monitor and Maintain Inventory of Chemicals 2.15.3 BAT Performance Standards for Ceii4A 7oe& 719& 719& 71~ 72~ 72~ 7268 7368 7369 2.15.3.1 BAT Operations and Maintenance Plan 7369 2.15.3.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan 7469 2.15.4 BAT Performance Standards for Ceii4B 75+-G 2.15.4.1 BAT Operations and Maintenance Plan 75+-G 2.15.4.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan 75+-G 2.15.5 Stormwater Management and Spill Control Requirements 77':74 2.15.6 Tailings and Slimes Drain Sampling 77~ 2.15.7 Additional Monitoring and Inspections Required Under the Mill License 77~ 2.15.7.1 Daily Inspections 78~ 2.15.7.2 Weekly Inspections 7873 2.15.7.3 Monthly Reports 7973 2.15.7.4 Quarterly Tailings Inspections 2.15.7.5 Annual Evaluations 2.16 Corrective Action Plan or Identification of Other Response Measures to be Taken to Remedy any Violation of Applicable Ground Water Quality Standards (R317-6-6.3.P) 81-1-5 2.16.1 Chloroform Investigation 81~ 2.16.2 Nitrate Investigation 83-7e 2.17 Other Information Required by the Director (R317-6-6.3.Q) 8679 2.17.1 Chemical Inventory Report 8679 2.17.2 Southwest Hydrogeological Investigation 868Q 2.18 This Application Performed Under the Direction of a Professional Engineer (R317-6-6.3.R) 8739 2.19 Closure and Post Closure Management Plan Demonstrating Measures to Prevent Ground Water Contamination During the Closure and Post Closure Phases of Operation (R17-6-6.3.S) 8739 2.19.1 Regulatory Requirements for Uranium Mills 878Q 2.19.1.1 Long Term Custodian 878Q 2.19.1.2 Responsibility For And Manner Of Clean Up 87&± 2.19.1.3 Surface 88&± 2.19.1.4 Groundwater 88~ 2.19.1.5 License Termination 88~ 2.19.2 Current Reclamation Plan 89~ 3 2.19.3 Provisions Included in the Permit Relating to the Mill's Reclamation Plan 2.19.4 Post-Operational Monitoring 3.0 CONCLUSIONS 4.0 SIGNATURE AND CERTIFICATIONS 5.0 REFERENCES 4 1.0 INTRODUCTION 1.1 Background Prior to July 1, 2012, the Director of the Utah Division of Radiation Control ("Director") was referred to as the Executive Secretary of the Utah Radiation Control and Board Co-Executive Secretary of the Utah Water Quality Board. Documents referenced in this Application, published prior to that date, refer to the Director, by one or both of these previous titles. In accordance with R317 -6-6.7, this is an updated application (the "Application") to the Director for renewal of the Permit for another 5-years under R313-6-6.7. fu this Application, Denison is HOt proposing any modifleationc; to the terms and sonditions of lhe Permit. The Mill is also subject to State of Utah Radioactive Materials License No. UT 1900479 (the "Mill License"), which was issued on March 31, 19972 for 10-years and is currently in the process of timely renewal under R313-22-363, and State of Utah Air Quality Approval Order DAQE-AN0112050018-11 (the "Air Approval Order") which was re-issued on March 2, 2011 and is not up for renewal at this time. While the Mill License is referred to in this Application from time to time in order to allow the Director to better understand Mill operations and compliance with applicable regulatory requirements, this is not an application for renewal of the Mill License or Air Approval Order. 1.2 Applicable Standards for Review and Approval of this Application I PriartoJul y 25, 2.011. Energ)' UI':)S Rcsnul'Ci'S I s [nc. \ us numcrl ''Dt:njs n iJ.in •q I A) c~lm ("DMj:.:on'1)", Prior to December 16, 2006, Denison was named "International Uranium (USA) Corporation." 2 The Mill License was originally issued by the United States Nuclear Regulatory Commission ("NRC") as a source material license under 10 CFR Part 40 on March 31, 1980. It was renewed by NRC in 1987 and again in 1997. After the State of Utah became an Agreement State for uranium mills in August 2004, the Mill License was re- issued by the Executive Secretary as a State of Utah Radioactive materials license on February 16, 2005, but the remaining term of the Mill License did not change. 3 A Mill License renewal application was submitted to the Executive Secretary on -February 28, 2007, pursuant to R313-22-36. 5 In accordance with discussions between DeHisoH EFRI maHagemeHt and State of Utah Division of Radiation Control ("DRC") staff on Mareh 12, 2009April 1, 2014, this Application includes the information required under R31J ]-6-6.3. In accordance with JHHR317-6-6.4C, the Director may issue (or renew) a ground water discharge permit for an existing facility, such as the Mill, provided: a) The applicant demonstrates that the applicable class total dissolved solids ("TDS") limits, ground water quality standards and protection levels will be met; b) The monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; c) The applicant utilizes treatment and discharge minimization technology commensurate with plant process design capability and similar or equivalent to that utilized by facilities that produce similar products or services with similar production process technology; and d) There is no current or anticipated impairment of present and future beneficial uses of the ground water. ompleLcd and is· 6 contarrd nation. Th moni1oring, re. ull f< r ach wdl I hat i ·· ·ampled are evaluated for compliance with standards for 38 different constituents and. re2:ardless of whether standards are met, for trends in the data that may show a need for further action. chloroform monitoring wells. mino.Led [!rQLlndwatcr rn April. how this initial remediation effort has been effective based on reduction of contaminant concentrations. Reductions of the contaminant concentrations inclicarc bolh Lh<ll the pumping prooram is working nd that Lhere is no contintl contaminants, as would be the case if the cells were leaking. Durin2 a revi ew of he EFRI April 30. 2 0 ew Wells B ckeround Repo&t and other EFRl reports, Nitrate + Nitrite (as N) (hereafter Nitrate) concentrations were observed above the Utah Ground Wmer Qua lity Standar (I 0 mg!L) in ftv m oit01ine welli· in U1e mill ite are . have since been abandoned. pn of ilie ni trate corrective acti n . 7 EFRI has submitted two roporl5 to DR r garding the ele ntcd iu·ate concentrations. The reports identifv the extent of the Nitrate plume but EFRI and DRC disagreed about what the report · indicated aboul the likely ourcc of th plume. E " I doc. not believe that the results adequately demonstrated an on-site source. EFR · agreed to implement a corrective action plan to Lean up the plume. EFRl completed and submitted the Nitrate Corrective Action Plan t the DRC on May 7, 2012. The Corrective thi · initial remediation effort has been eft! ctive based on evidence: cell wastewater. 3. Sta lc h:otopes n Dissolved Sulfate. The 8 A-l#lough DeAiS(lfl is aot prOJ30Siag any :;ignitictml changer; to l:Be original Permit, lThis Application has eeverH1elC!;S been performed prepared under the direction, and bears the seal, of a professional engineer qualified to practice engineering before the public in the state of Utah and professionally registered as required under the Professional Engineers and Professional Land Surveyors Licensing Act rules (UAC 156-22). 1.3 Background Groundwater Reports and Re-opening of Permit In the December 1, 2004 Statement of Basis (the "2004 Statement of Basis") prepared by DRC in connection with the original issuance of the Permit, three monitoring wells (MW-14, MW-15, and MW-17) located downgradient of the Mill's tailings cells were found to have long-term increasing concentration trends for total uranium. These three wells and downgradient well MW-3, had total uranium concentrations above the Utah Ground Water Quality Standard ("GWQS"), found in UAC R317-6-2 (see the 2004 Statement of Basis, pp. 6-7). These findings were of concern to the DRC because they appeared to indicate that the tailings cells had possibly discharged wastewater into the underlying shallow aquifer. To resolve this concern, the Director required Deaisoa EFRI to evaluate groundwater quality data from the thirteen existing wells on site, and submit a Background Ground Water Quality Report for Director approval. The existing wells are those wells which were installed prior to the issuance of the original GWDP on March 8, 2005 and include: MW-1, MW-2, MW-3, MW-5, MW-11, MW-12, MW-14, MW-15, MW-17, MW-18, MW-19, MW-26 (formerly called TW4- 9 15 and installed as part of the chloroform corrective action order), and MW-32 (formerly called TW 4-17 and installed as part of the chloroform corrective action order). It is important to note that MW -4 was installed prior to the issuance of the original permit; however, MW -4 is monitored under the chloroform program and was not included in the Existing Background Report. GWCLs have not been established for this well, and MW -4 is not a POC well under the GWDP. One of the purposes of tflat:-Lh ba ·kgr und report was to provide a critical evaluation of historic groundwater quality data from the facility, and determine representative background quality conditions and reliable groundwater compliance limits ("GWCLs") for the Permit. As required, Denison EFRI submitted the following reports: • Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. (the "Existing Well Background Report"); and • Revised Addendum: --Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, November 16, 2007, prepared by INTERA, Inc. (the "Regional Background Report"). The Existing Well Background Report and the Regional Background Report included a detailed quality assurance evaluation of all existing groundwater quality data collected prior to the date of issuance for the thirteen exi~ting wells, in accordance with criteria established by DRC and United States Environmental Protection Agency ("EPA") guidance. This resulted in a data-base suitable for statistical and other analyses. Based on an analysis of this updated data-base, the Existing Well Background Report and Regional Background Report concluded that there have hnd been no impacts to groundwater from Mill activities, based on a number of factors, including the following: • There are-were a number of exceedances of GWQSs in upgradient and far downgradient wells at the site, which cannot be considered to have been impacted by Mill operations to date. Exceedances of GWQSs in monitoring wells nearer to the site itself are therefore consistent with natural background in the area. • There are-were numerous cases of both increasing and decreasing trends in constituents in upgradient, far downgradient, and Mill site wells, which provide evidence that there are natural forces at work that are impacting groundwater quality across the entire site. • In almost all cases where there are-were increasing trends in constituents in wells at the site, there are--were increasing trends in those constituents in upgradient wells. Furthermore, in no case is--was there any evidence in the wells in question of increasing trends in chloride, which is very mobile and a good indicator of potential tailings cell leakage at the site. See Section 2.11.2 below for a more detailed discussion of the Existing Well Background Report and Regional Background Report and their conclusions. 10 The Permit also required nine new monitoring wells to be installed around tailings Cells 1 and 2, followed by groundwater sampling and analysis, and later submittal of another Background Ground Water Quality Report to determine reliable background conditions and groundwater compliance limits for the new wells. The new wells are those wells which were installed after the issuance of the original GWDP on March 8, 2005 and include: MW-3A, MW-23, MW-24, MW- 25, MW-27, MW-28, MW-29, MW-30, and MW-31. In response to this requirement, DeHisoH EFRI installed the nine new wells, and submitted to the Director a Revised Addendum: -- Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA, Inc. (the "New Well Background Report"), and together with the Existing Well Background Report and the Regional Background Report, are referred to as the "Background Reports"). The New Well Background Report concluded that the sampling results for the new wells confirm that the groundwater at the Mill site and in the region is highly variable naturally and has not been impacted by Mill operations and that varying concentrations of constituents at the site are consistent with natural background variation in the area. See Section 2.11.2 below for a more detailed discussion of the New Well Background Report and its conclusions. During the course of discussions with DeHisoH EFRI staff, and further DRC review, DRC decided to supplement the analysis provided in the Background Reports by commissioning the University of Utah to perform a geochemical and isotopic groundwater study at White Mesa. This resulted in the University of Utah completing a study entitled Summary of work completed, data results, interpretations and recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, May 2008, prepared by T. Grant Hurst and D. Kip Solomon, Department of Geophysics, University of Utah (the "University of Utah Study"). The purpose of the University of Utah Study was to determine if the increasing and elevated trace metal concentrations (such as uranium) found in the monitoring wells at the Mill were due to potential leakage from the on-site tailings cells. To investigate this potential problem, the study examined groundwater flow, chemical composition, noble gas and isotopic composition, and age of the on-site groundwater. Similar evaluations were also made on samples of the tailings wastewater and nearby surface water ~ tared in the northern wildlife ponds at the facility. Fieldwork for the University of Utah Study wru conducted fi: m July 17 -26 of 2007. The conclusions in the University of Utah Study supported DenisoA-+EFRl's conclu ions in the Background Reports As stated above, DUSA EFRI prepared Background Reports that evaluated all historic data for the thirteen existing wells and nine new wells for the purposes of establishing background groundwater quality at the site and developing GWCLs under the GWDP. Prior to review and acceptance of the conclusions in these Background Reports, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells and the nine new wells based primarily on the conclusions and analysis in the Background Reports. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, 11 exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. In addition to the thirteen existing wells and the nine new wells there are an additional 7 monitoring wells at the site which are included in the routine groundwater monitoring program·. Those 7 wells are: MW-20, MW-22, MW-33, MW-34, MW-35, MW-36, and MW-37. The GWDP dated January 20, 2010 required the completion of eight consecutive quarters of groundwater sampling and analysis of MW-20 and MW-22, and later submittal of another Background Rep l't to determine if wells MW-20 and MW-22 should be added as point of compliance C POC:) monitoring wells. Data from MW-20 and MW-22 were analyzed in the pre- operational and regional background addendum (INTERA 2007a); however there was not a complete data set at the time. Although wells MW-20 and MW-22 were installed in 1994, they were not sampled regularly until the second quarter of 2008. The eighth full round of sampling was completed during the first quarter of 2010, and Deaisoa EFRI submitted to the Director the Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, June 1, 2010, prepared by INTERA, Inc. (the "MW-20 and MW-22 Background Report"). DRC classified MW-20 and MW-22 a general m.onHoring weJJs~ and oo--GWCL · have n_Lb~en ealeu lated tabti hed for tb e weU . MW-20 and M.W-22 _are amplcd emiannuaJJy. Part I.H.6 of the +he-GWDP dated June -l-121 , ~2010, Puti: l.H.6 required the installation of three hydraulically downgradient wells adjacent to Tailings Cell4B (MW-33, MW-34, and MW- 35) prior to placemen of fffiY potentinl tailing and/or wastewater in Cell 4R Th purpo e of these monitoring wells was to provide early detection of tailings cell contamination of shallow groundwater from Tailings Cell 4B. Deaisoa EFRI installed MW-33, MW-34, and MW-35 as required. Of these three wells installed near tailings Cell 4B, only MW-35 was hydraulically acceptable, with five feet or more of saturated thickne . MW-35 ha:s eeenwa ample-d quarterly since fourth quarter 2010 to collect eight coaseeuti'le qU~;:t~i:·tati:tically alid data point for the completion of the Background Report and calculation of GWCLs. MW-33 and MW-34 had insufficient water for sampling, with saturated thicknesses less than five feet. MW -33 is completely dry, and no samples or depth to water measurements are collected from this well. Quarterly depth to water is measured in MW-34, but no sampling or analysis is required. Part I.H.4 of the February 15, 2011 GWDP required the installation of two wells hydraulically downgradient of Tailings Cell 4B as replacements for MW-33 and MW-34. Deaisoa EFRI installed MW-36 and MW-37 as required. MW-36 and MW-37 H.a·;e beeawere sampled quarterly since third quarter 2011 to collect eight eeaseeulive q~ull·ters o-f tali ticailv valid data points for the completion of the Background Report and calculation of GWCLs. 1.4 Documents Referenced in This Application 12 The following documents are referenced in this Application,_ aRd are a part of this ApplicatioR: a) The following Permits, Licenses, Statement of Basis, Plans and Related Reports: (i) Slate of wh Omund Water Discharg--Permit No. UGW370 04 dat d Aut?.u ·t 24. 2012. (the "Permit") and previous versions of the Permit doted Janu~uy 10. 2010. June 21 ,2010, Februarv 15.201 1. and July 14 .201 L (ii) State of Utah Radioactive Materials License No. UT 1900479 (the "Mill License"); (iii) Statement of Basis For a Uranium Milling Facility at White Mesa, South of Blanding, Utah, Owned and Operated by International Uranium (USA) Corporation, December 1, 2004, prepared by the State of Utah Division of Radiation Control (the "2004 Statement of Basis"); (iv) Reclamation Plan White Mesa Mill Blanding, Utah, Source Material License No. SUA-1358 Docket No. 40-8681 Revision 4:()3.2B, Novemeer 2009January 14. 2011 (the "Reclamation Plan"); and (v) UMETCO Minerals Corporation: White Mesa Mill Drainage Report for Submittal to NRC, January 1990; b) The following Background Groundwater Quality Reports and Related Studies: (i) Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, October 2007, prepared by INTERA, Inc. (the "Existing Well Background Report"); (ii) Revised Addendum: --Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, November 16, 2007, prepared by INTERA, Inc. (the "Regional Background Report"); (iii) Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA, Inc. (the "New Well Background Report" and together with the Existing Well Background Report and the Regional Background Report, the "Background Reports"); and (iv) Summary of work completed, data results, interpretations and recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, May 2008, prepared by T. Grant Hurst and D. 13 Kip Solomon, Department of Geophysics, University of Utah (the "University of Utah Study"); (v) Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah, June 1, 2010, prepared by INTERA, Inc. (the "MW-20 and MW-22 Background Report"); (vi) Background Groundwater Quality Report for Monitoring Wells MW-35, MW-36 and MW-37 White Mesa Mill Blanding, Utah, May 1, 2014, prepared by INTERA, Inc. (the "MW-35, MW-36, and MW-37 Background Report". c) The following environmental reports and analyses: (i) Environmental Report, White Mesa Uranium Project San Juan County, Utah, January 30, 1978, prepared by Dames & Moore (the "1978 ER"); and (ii) Final Environmental Statement related to operation of White Mesa Uranium Project Energy Fuels Nuclear, Inc., May 1979, Docket No. 40-8681, prepared by the United States Nuclear Regulatory Commission (the "FES"); d) The following engineering, geological and hydrogeological reports: (i) Umetco Groundwater Study, White Mesa Facilities, Blanding, Utah, 1993, prepared by Umetco Minerals Corporation (Lh c perat r of th ill at th and Peel Environmental Services; (ii) Hydrogeological Evaluation of White Mesa Uranium Mill, July 1994, prepared by Titan Environmental Corporation (the "1994 Titan Report"); (iii) (iv) Evaluation of Potential for Tailings Cell Discharge-White Mesa Mill, November 23, 1998, prepared by Knight-Piesold LLC; Update Lo repoFl Investigation of Elevated chloroform concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah, 2001, prepared by Hydro Geo Chern, Inc.; Hytiffl~lie Tes:ing ttt .'he White Mest1 UreRium Mill Netlr Blm1tlffig, Uf.B}l DuriHg ~002 Allgttst 22, 2002 prepares I:Jy Hydro Gee Caem lee.· fvi-).(yl_Letter Report dated August 29, 2002, prepared by Hydro Geo Chern, Inc.; (vii) Perclu:ti-Men:it&ring Well Jnstal!flfiert-and Testirtg til flw Whi~e Me.~e (;}nmium-l'lf.i.U Af;F#-Thrrmgh hwe 2005, Augu:st 3, 'lGQ5 preptuea b,y Hydro Gee Cb:em lnc .. ; 14 ('v111) She H.wi·r&gt't~lfJgy and l£:;1it~uaimr-ef GretmtA1•£l,"t'r Tttli'el Timet~ Tn The Perdwd Zt:Pw WhUe MeNtt Urt:lRiHHt-Jil+ll Silt• l'lcttr B/(;lfl diRg, CJt.uh, Auglwt 27, 2009;- prepared by Hydro Gee Chern, Inc.; f:i*JtilHydrogeology White Mesa Uranium Mill Site Near Blanding, Utah, June 6, 2012, prepared by Hydro Geo Chern, Inc.; (*) Hydregealfft:Y ej rhe Pc.•rohed......frffltmeu.'t11er Zrme--emi t .. ssoeiateeJ St!ejiS fflNl ~g.Y Neer the White .~1esti Unmiiim J.l/ill Sile, BI8Rtiil18 Ult~h. Noveffiber t2 2010, prepared by Hydro Gee Chern. Inc.; ami (xi) e) The following plans and specifications relating to construction and operation of the Mill's tailings cells: (i) Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah, June 1979, prepared by D' Appolonia Consulting Engineers, Inc.; (ii) Engineer's Report: Second Phase Design -Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah, May 1981, prepared by D' Appolonia Consulting Engineers, Inc.; (iii) Construction Report: Initial Phase-Tailings Management System, White Mesa Uranium Project Blanding, Utah, February 1982, prepared by D' Appolonia Consulting Engineers, Inc.; (iv) Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project, March 1983, prepared by Energy Fuels Nuclear, Inc. (the operator of the Mill at the time); (v) Cell 4 Design, White Mesa Project Blanding, Utah, April 10, 1989, prepared by Umetco Minerals Corporation (Lhe op rator of the MiJI al lhe tim ); (vi) Construction Report: Tailings Cell 4A, White Mesa Uranium Mill -Tailings Management System, August 2000, prepared by Denison (then named International Uranium (USA) Corporation Clh p · ralor of the Mill at the time»; (vii) Cell 4A Lining System Design Report For The White Mesa Mill Blanding, Utah, January 2006, prepared by GeoSyntec Consultants; (viii) Cell4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah, July 2008, prepared by Geosyntec consultant · Aiy1; (ix) Cell 4B Design Report, White Mesa Mill, Blanding, Utah, December 8, 2007, prepared by Geosyntec Consultants; and 15 (x) Cell 4B Construction Quality Assurance Report, Volumes 1-3, November 2010, prepared by Geosyntec Consultants. f) The following documents relating to the chloroform investigation at the site: (i) Preliminary Corrective Action Plan, White Mesa Mill Near Blanding, Utah, August 20,2007, prepared by Hydro Geo Chern, Inc.; aatl (ii) (:-itt1(i) ,ontaminalion bwestigati " Reporr TW4-12 and TW4-27 Areas Uranium Mill, Near Blanding Utllh. Januarv 2 .. 20 14 prepured b Chern. Inc.; gL__The following documents relating to the Ailraw and pH t and ther Out of Compliance investigations at the site: gt-- (i) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for Constituents in the First, Second, Third and Fourth Quarters of 2010 and First Quarter 2011, June 13, 2011; (ii) White Mesa Mill State of Utah Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part l.G.2 for Constituents in the Second Quarter of 2011, September 7, 2011; (ill) Plan and Time Schedule for Assessment of pH Under Groundwater Discharge Permit UGW370004, April13, 2012 prepared by Hydro Geo Chern, Inc; (iv) White Me. a Mill Srate v( Uwh rowzdwater Di. charge Permit U W370004 Plan and Time Schedule Under part l.G.4 (d) for Violations of Part I.G.2 for 'u nstilll ms in !he Third Omu-ter o(2012. ecember 13. 20l2; (V) White Meso Mill Swre of Uw h Groundwa1er Disduu·ge Permit U ~ 370004 Pllm and Time Schedule Under part I.G.4 (d) for Violations of Part l.G.2 (or urth Otwrrer o[2012. Mar h I 5. 2013; ( i) White Mesa Mill Stcu of tail Ground1 at •r Discharge Permit U lV. 70004 Plan and Time Schedule Under part I.G.4 (d) (or Violations of Part l.G.2 for Constituents in the First Quarter of2013. August 28. 2013: ( •ii) 16 o[ Part lG.2 for (ix) Source Assessment Report. White Mesa Uranium Mill. Blandin g Utah. October 10,2012 prepared by INTERA. Inc; (x) pH Report White Mesa Uranium Mill. Blanding Utctli , November 9, 2012 prepared by INTERA, Inc; (xi } (xiiJ (xi ii) (.tv ) h) (i) (ii) (iii) (iv) (v) Uranium Mill. Blanding Utah. May 7. 201 . Stipulated Consent Agreement Docket No. UGW12-03 between Denison Mines (USA) Corp. and the Director of the Division of Radiation Control, July 12, 2012. Revised Tolling Agreement, Revision 3, between DUSA and the Director, Revision 2, dated August 21, 2011. Revised Phase 1 (A through C) Work Plan and Schedule for Phase 1 A -C Investigation, May 11, 2011, prepared by INTERA, Inc; Revised Phase 2 through 5 Work Plan and Schedule, June 3, 2011, prepared by INTERA, Inc; Revised Phase 2 QAP and Work Plan, Revision 2.0, July 12, 2011; and ..~..(v~i~) ___ .Nitrate Corrective Action Plan, May 7, 2012, prepared by Hydro Geo Chern, Inc;. Nilrate Contaminatiofl In vestigation Report. December 0. 2009, prepared b\ 17 INTERA. Inc. 2.0 INFORMATION PROVIDED IN SUPPORT OF THE APPLICATION 2.1 Name and Address of Applicant and Owner (R317-6-6.3.A) The Applicant is Deni:soe }.ofmes (U8:l\) Go:f}'). (' Denisofl") ami p rat r i. Energy "uel Resources (USA) Inc. ("EFRI"). Deaisoa EFRI is the current holder of the Permit. The Mill is owned by Deeisoe' s EFRI' s affiliate, Deeisoe "\Vhite MesaEFR White Mesa LLC ("D'.VMEFRWM"). The address for both DeaisoA and D'NM EFRI and EFRWM is: 1050 1th St. Suite 950225 Uni n Boulevard. Suit 600 -f>etwer. CO 80265Lak o I, CO 228 Telephone: 303 628 7798303-974 2140 Fax: 303 389 4130303-389-4125 Contacts at DeeisoaEFRI, all located at the foregoieg aforementioned office: Harold R. Roberts, Executive Vice President, US Operu~and hief Operating Officer. Direct telephone: 303-389-4160 hrobert @deRisonm-ieesenergyfueJ .c m Frank J. Filas Vice Pre. idenL Permitling and Environmental Afl airc David C. Frydeelued Vice Presideat, Regulatory A:ffairs aad Geeeral Gouesel Direct telephone: 303~97 4-4-1-3{)2146 dfn•dealuadlula, @denisoAm ineseneruvfud .com Jo Aee TisefilerKatherine A. Weinel Director, Complionce ttAd Pem1ittjngOuulitv A. uraJH.:e Manag--.;r Direct telephone: 303-389-413~ jtischler@defrit;eR.mines.comkw inel@energ fu el . om 2.2 Legal Location of the Facility (R317-6-6.3B) The Mill is regionally located in central San Juan County, Utah, approximately 6 miles (9.5 km) south of the city of Blanding. The Mill can be reached by taking a private road for approximately 0.5 miles west of Utah State Highway 191. See Figure 1. Within San Juan County, the Mill is located on fee land and mill site claims, covering approximately 5,415 acres, encompassing all or part of Sections 21, 22, 27, 28, 29, 32, and 33 of T37S, R22E, and Sections 4, 5, 6, 8, 9, and 16 of T38S, R22E, Salt Lake Base and Meridian C"SLBM"). See Figure 2. 18 All operations authorized by the Mill License are conducted within the eoafiaes of the existing site boundary. The milling facility currently occupies approximately 50 acres, and the tailings disposal cells encompass another 250 acres. See Figure 2. 2.3 Name and Type of Facility (R317-6-6.3.C) The name of the facility is the White Mesa Uranium Mill. The facility is a uranium milling and tailings disposal facility, which operates under a Radioactive Materials License issued by the Director of the Utah Division of Radiation Control under UAC R313-24. In addition to uranium in the form of U30 8, the Mill also produces vanadium, in the form of vanadium pentoxide C:V20 5.. ammonia metavanad, te t:AMV.:J and anad iu m pregnant liquor • VPL_:), (rom certain conventional ores and has produced other metals from certain alternate feed materials (. pccifically niobium and tantalum · uLhorized under NRC Jicen ·e men ment numb r 4, induded a<; Apo ndi. AJ. Alternate feed materials are uranium bearing materials other than conventionally mined ores. Construction of the Mill was completed and first operations commenced in May 1980. The Mill does not have a set operating life, and can operate indefinitely, subject to available tailings capacity and license and permit renewals. The conceptual and permitted total capacity is for the quantity of Mill tailings produced from a 15-year operating period at a rate of 2,000 tons per day, operating 340 days per year. Since it commenced operations in 1980, the Mill has operated on a campaign basis, processing conventional ores and alternate feed materials as they become available and as economic conditions warrant. 2.4 A Plat Map Showing All Water Wells, Including The Status And Use Of Each Well, Drinking Water Source Protection Zones, Topography, Springs, Water Bodies, Drainages, And Man-Made Structures Within A One-Mile Radius Of The Discharge. (R317-6-6.3.D) There are five deep wells within a one mile radius of the Mill, two of which supply the Mill facility. There are no Drinking Water Source Protection Zones or ordinances within this radius. Routine groundwater monitoring wells have been established for monitoring under the Permit. These monitoring wells are depicted on Figure 104 and have beea plotted oH 8aa Juaa County, Utah plat maps in Appendix BA to this Application. The depth and purpose of each of these wells is as shown in Table§. 1.2-1, 1.2-2, and 2.4-1. See Section 2. 9 .1.3 below for a detailed description of the Mill's groundwater monitoring program. The surface topography vlithia this one mile zone is relatively flat, and man-made structures are .J..i.mtt.etHe-t.fie-Mill facilities, h wn < n FLur s ore me I in Appendix B. See Sections 2.5.4 and 2.5.7 below for a more detailed discussion on local topography and land use. The Mill area has several dry drainages, and the only nearby natural water bodies within one mile are Westwater Creek, Corral Creek and Cottonwood Creek. In addition to these are Ruin Spring and several other springs and seeps located within a 1.5 mile radius of the Mill. See Sections 2.5.3 and 2.13 below for discussions relating to seeps and springs in the vicinity of the site and to surface water and drainages, respectively. 19 2.5 Geologic, Hydrologic, and Agricultural Description of the Geographic Area (R317-6-6.3.E) 2.5.1 Groundwater Characteristics This Section is excerpted frombased on the Report entitled: ~Hydrogeology of the White Me ·a Uranium Mill. Bhmdim: Utah fH~rt(tfttm e.f CrfJimdwe!er Travt•l Timc.'i ffi The .fJ.e.Feht'd Zom: w;,,;,"C Me.w Urmrium Mill Sitt' ·"'lelir Blemclilr.~, U1ah, July Jun ·H)§, ~2014, prepared by Hydro Geo Chern, Inc. ("HGC") (the "~2014 HGC Report" referred to as HGC, ~2014). 2.5.1.1 Geologic Setting The Mill is located within the Blanding Basin of the Colorado Plateau physiographic province. Typical of large portions of the Colorado Plateau province, the rocks underlying the site are relati vely undefOJ~med. The average ele ation of the ite i. approximately 5,600 ft (1 707 m ab ve meao sea lev I ·am I_ . The site is underlain by unconsolidated alluvium and indurated sedimentary rocks consisting primarily of sandstone and shale. The indurated rocks are relatively flat lying with dips generally less than 3°. The alluvial materials consist mostly of aeolian silts and fine-grained aeolian sands with a thickness varying from negligible to as much as 25 to 30 feet across the site. In some portions of the site the alluvium is underlain by a few feet to as much as 30 feet of Mancos Shale. In other areas, the Mancos Shale is absent. The alluvium and Mancos (where present) are underlain by the Dakota Sandstone and Burro Canyon Formation, which are sandstones having a combined total thickness ranging from approximately 55 to 140 feet (17 to 43 m). Beneath the Burro Canyon Formation lies the Morrison Formation, consisting, in descending order, of the Brushy Basin Member, the Westwater Canyon Member, the Recapture Member, and the Salt Wash Member. The Brushy Basin and Recapture Members of the Morrison Formation, classified as shales, are very fine-grained and have a very low permeability. The Brushy Basin Member is primarily composed of bentonitic mudstone, siltstone, and claystone. The Westwater Canyon and Salt Wash Members are primarily sandstones but are expected to have a low average vertical permeability due to the presence of interbedded shales. See Figure 3 for a generalized stratigraphic column for the region. Beneath the Morrison Formation lies the Summerville Formation, an argillaceous sandstone with interbedded shales, and the Entrada Sandstone. Beneath the Entrada lies the Navajo Sandstone. The Navajo and Entrada Sandstones constitute the primary aquifer in the area of the site. The Entrada and Navajo Sandstones are separated from the Burro Canyon Formation by approximately 1,000 to 1,100 feet (305 to 355 m) of materials having a low average vertical permeability. Groundwater within this system is under at1esian pressure in the vicinity of the site, is of generally good quality, and is used as a secondary source of water at the site. 2.5.1.2 Hydrogeologic Setting The site is located within a region that has a dry to arid continental climate, with average annual precipitation of approximately 13.3 inches, and an average annual lake evaporation rate of approximately 47.6 inches. Recharge to the principal aquifers (such as the Navajo/Entrada) 20 occurs primarily along the mountain fronts (for example, the Henry, Abajo, and La Sal Mountains), and along the flanks of folds such as Comb Ridge Monocline. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth of the aquifer (approximately 1,200 feet below land surface [ft bls]) makes access difficult. The Navajo/Entrada aquifer is capable of yielding significant quantities of water to wells (hundreds of gallons per minute [gpm]). Water in on-site wells completed within the Navajo/Entrada rises approximately 800 feet above the base of the overlying Summerville Formation. The shallowest groundwater beneath the site consists of perched water hosted primarily by the Burro Canyon Formation. Perched water is used on a limited basis to the north (upgradient) of the site because it is much shallower and more easily accessible than the deep Navajo/Entrada aquifer. 2.5.1.3 Perched Zone Hydrogeology Perched groundwater originates mainly from precipitation and local recharge sources such as unlined reservoirs (Kirby, 2008) and is supported within the Burro Canyon Formation by the underlying, fine-grained Brushy Basin Member. Perched groundwater at the site has a generally lewis generally of poor quality due to high total dissolved solids LTDS:.) in the range of approximately 1,100 to 7,900 milligrams per liter (~mg/L:). Geneml ly It. relatively poor quality is one reason that perched water is used primarily for stock watering and irrigation in areas upgradient (north) of the site. Figure 4 is a contour map showing the approximate elevation of the contact of the Burro Canyon Formation with the Brushy Basin Member, which essentially forms the base of the perched water zone at the site. Based on Figure 4, the Burro Canyon Formation/Brushy Basin Member contact generally dips to the south/southwest beneath the site. Figure 5 is a perched groundwater elevation contour map for the first quarter, 2011.~. Based on the contoured water levels, groundwater within the perched zone flows generally south to southwest beneath the site. Beneath the tailings cells, perched groundwater flow is generally to the southwest. Perched groundwater discharges from outcrops of the Burro Canyon Formation in seeps and springs along Westwater Creek Canyon and Cottonwood Canyon (to the west-southwest of the millsite and tailings cells) and along Corral Canyon (to the east and northeast of the millsite and tailings cells). Known discharge points include all-the seeps and springs shown in Figure 5 except Cottonwood Seep. As discussed in .(HGC.l-2014), Cottonwood Seep is located more than 1,500 feet west of White Mesa in an area where the Dakota Sandstone and Burro Canyon Formation (which hosts the perched water system) are absent due to erosion, and at an elevation approximately 230 feet below the base of the perched zone defined by the contact between the Burro Canyon Formation and the underlying Brushy Basin Member. Cottonwood Seep occurs near the contact between the slope-forming Brushy Basin Member and the underlying Westwater Canyon (sandstone) Member. 21 Contact elevations shown in Figure 4 are based on perched monitoring well drilling and geophysical logs and surveyed land surface elevations, and the surveyed elevations of Westwater Seep and Ruin Spring. The elevations of Westwater Seep and Ruin Spring are included in the kriged c n1. urs because they occur at the contact between the Burro Canyon Formation and the underlying Brushy Basin Member (HGC, 2012a). Groundwater elevations shown in Figure 5 include the surveyed elevations of all seeps and springs except Cottonwood Seep. As discussed above, no evidence exists to connect Cottonwood Seep to the perched water system. Although Cottonwood Seep may potentially receive some contribution from perched water, its occurrence near the contact between the Brushy Basin Member and the underlying Westwater Canyon Member indicates that its elevation is not representative of the perched water system. The permeabilities of the Dakota Sandstone and Burro Canyon Formation at the site are generally low. No significant joints or fractures within the Dakota Sandstone or Burro Canyon Formation have been documented in any wells or borings installed across the site (Knight Piesold, 1998). Any fractures observed in cores collected from site borings are typically cemented, showing no open space. Porosities and water contents of the Dakota Sandstone have been measured in samples collected during installation of former well MW-16 and well MW-17 (Figure 5). MW-16 was located immediately downgradient of tailings Cell 3 and MW -17 is located south of tailings Cell 4A at a location primarily cross-gradient with respect to perched water flow. Porosities of the Dakota Sandstone range from 13.4% to 26%, averaging 20%, and water saturations range from 3.7% to 27.2%, averaging 13.5%. The average volumetric water content is approximately 3%. The hydraulic c ndu tivily of the Dakota and -~one ba ed on packer te t in boring · in ·tall eel at the ite prior t0 1994 range from 2.71 x to·6centimeter-per cond C.:cm/s~ to 9.12x 104 cm/, with a geomelric average of3.89 x 10'5 ml (TITAN, 1994). Extensive hydrogeologic characterization of the saturated Burro Canyon Formation has occurred through hydraulic testing of perched monitoring wells and borings at the site. Hydraulic testing of MW -series wells located up gradient, cross-gradient, downgradient, and within the millsite and tailings cell complex, TW4-series wells located cross-gradient to upgradient of the millsite and tailings cells, TWN-series wells located primarily upgradient of the millsite and tailings cells, and DR-series piezometer . lo ai "d downgradlen l f Lhe Lnilings el l indicate that the hydraulic conductivity of the perched zon tange.J from approx imately .;.1_x 10·& to 0.01 crnls. 22 HyQf!hl!ic tesl:ing of \veHs MW l MW 3, MW 5, ~AV.' t7, to.PN l8 MW 19, ~ MW 23 ~ MW~MW 27. MW 28, M'N 29, MW 30. :MVl 3 L NIW 3:!, MW 35 MW 36, ttfla MV/ 37 (Figure 5) located up~ss gradjeFH dm•;ngradient and 't'<'ithin the area oF tRe 23 failings cel l~~~~~ed hydraulie-eeAtl~tie~ nmging from lif)proximtHely 2 N -!-Q4 cmls to J J\ 10~-e-mls (HGC. 2002; HGC, 2005· HGC, 291Gfl.;-afld HGC, 20J Ia) H~~eJ.nt&He testi-ng of MW 11 anel J!I.<JW I ·1 (Joei.lted '>Vithi n aRd ia1rneai •Hely dowagradient-eHt'te-ttt+H+.:f~· cell compjex) ytd-Eietl-ftydraulie cond.l.f€ti¥fli~; of appfe*i.rnately 1 Jt l0-,3 c:mls aB:CI 7 x 1.0 ~ Fespeetively. ~e,·jes p~rneterts wen~ iflsltilled in May, 2011 to i•wesligale peffifled ;•one con~ ulhwe!ll (downgraElieatj·of the tailings eeiJ:; (Figure 5). Hydruulie t . tiag of DR 5, QR 8. OR 9. DR 1 0, DR 11 , DR 13, DR 111. 9R: 17 DR 19. DR 20. DR ") 1, DR 23. and DR 24 (f'igme 5) yielded hydmulic eonuueti·.-ity eMimmes (bases OR-+be KGS sl, test analy:;i<r ofa.utoma~cally ffiggeel eatttJ-·Htnging fron~ately 3 x lO...s--em/!i LO l x J 0 em!!. wits a geomelrie average of approx-ima~ly l x 10~ ~ *7-t~pontry perciJea zone chlorofomlm:onitor.tng wells (TW4 serien wells ifl r•gure 5) and 19· ~ ~one Aitrate meRiiering--wetln (T\VM .,erie:; \'t'ells ia Figure 5) luwe-feen in:>tulled lO ifr\le5t+gate ele•hlted niu·aleeoaceatrnhoA:S detected initially ifl }t4"W 4 LIBEl some of the T\¥~ series wells . TW4 seees wells ore located northeusl (upgroclieru) lie ea5l (en~~s gradient} of ~he ~ilings cells and :Y\VN series well·• ex~end to t.fte-t'teftheast (upo-railieat) of the Alil lsite Lllld Eailiags eeHB. Hydraulie testing of Lhe TWN series wellti ) ieltleJ bydraltJ.ic eoeduct:ivilies ranging l'rom apprmumawly 1 * 10..;: an/s to 0.0 I cm/s wilh a geometric .:werage of approximate~-1-9-!> enlJls (HOC 2009). TestiAg of TW'J 20, TW4 21 . ana TW4 22 (HGG 2005) una T'.l/11 23 . TW~ 24, aed TW1 25 (HGC 2007e) yjeleled hydmullc conductis.·ilies rMging from approximutely 4 1\ ~ to approJ<:imately 2 x 10 Cil'l/~. Testing ol:.!f.\N1 4 yieleled a hy<iraulie eoRffiK-t-h·ily of Bf'~I'&JH.ffia~ely J .7 n 10-:l emls, tuld testing of TW"+ 6, T\¥4 26. aAd TW4 27 (loemee downg.radie nl of TW4 4) yielded hydruulie conduelivilies ri:l:Ag~prmtimate!y 7 x. LO~ emls to 2 x 10~ em/!; (HGC, 20 LOe-a-tffi.-14 GC 1 01 l h) .• '\:nalysis of Lhe drawtlown dttta ceJlecteEl ~na terRl pum~ing lesL eo:B:eucied at MW 4, TW·I 19, and M'W" 26 using TW1 s · v.·eJ!s ~ observaLien wells yieleed hydraulic conductivity estimate, rane;ing -froFH-t~pprmtiml~ely ~ ~ -~".,(."ffiRi lO 1 * 10 Ciu/5 (J.JGC, 200'1). Some of tl=te courser grainee and congk}merutit mt:Heriuls ee:counlered within the perched LOae during .inMulhttion--~e TW4 series wells are eelieved to be par::ly eeRLi:Ruous with or a1 least a:ssocitued wiU1 a rel~mn relatively contim.IOtHl zoae-ef hjgherpeffl7eu.l:JiliLy (International Yntnium [USA] Corpnralion [lUS.'\1 and HGC, 200J ). The ftigher pefillCOl3ility zone-€1efined by •.veJis completed in the zone is geAera lly located eru;t to nor~hea'it of tae tai lings cells at the site, t\nd is hydra-elicaHy em::~s gradient lo uporodieat of tbe Hli linas cells whh respecl lO ~erched ~ ·sed oa-tH'l&!yses or flliRlpiRg resls ~H: M\V 4 ttliEI driUing logs Cram Hearby temporary wells, the ~ie conductivity of Lhi$ Fehu iYely ~fiin coar<;er grai ned zone was estimareelle be flff-high as 2.5 x. 10-:4 cm/!9. Rektl-Wely-fligf-1 wnducrMiies me~sured at MW J J. located 01~ lhe so~:tlheastern :!Bftrgin of the aowngradienl edge of tailings Cell 3, ~:md <:H MW J 1, loetueel on !he clowngraejent edge of tltilings Cei.J 4-A, of J. 'l x-I{) oml!; artd 7.5 '* W4 cmls, respect ivel y (UMETCO 1993), fl'Hiy-indieate that this zone e.xtena!'. he nee:L:b the sou Lheastem portion of lhe tailiags cell complex . 24 -lttwever bttsetl en hydra · , ·~'tel' perrneabiJity-El· . t-a~ar to exffit withm LRe-sffit:lrated wee dewngruffieftl--(3ouliHetH:I't'Nesl) of lbe lftili:ng:, cells nor to lhe south of T\V4 '1. The apparenl abseooe-ef the zett u1i1 of TW,.~ ·1 aed south Aouthwest ef the tai.J.i-~TgS cells suggests that it "13iaches out" (HGC, 2007a). The appareRt pinching out of this zon~with h;drat:~lie tests at tempe~-k TVl4 6, T'N4 26 aad T'N4 27 (located dowagradieat of TW 4 4), and tests at DR series pieli:lm ers (leGated dovrttgfadieAt of the teiliRgs cell cornp , ). As discussed abo'¥e, the flydnHJlie coaducti·vilies of TW4 6.1'V/JI 1 6 6:ftd TVPI 27 raJTgetl from apprmlimately 7 Jt W-+--ffi 2 * H.ra.~s, approximately two to three orders of magnitude lo·.ver iJ:tan the eoRdl:lotivity aF +-W4 4 (ap_p~llt*ely '2 * 1-G..J -€fflls). The hyc}m~i-Ytt~tf-dH~ DR '!eries piezomelt~FS (bused eft-a:Balysis of automatically logged slug tes~ eata usinv Lhe KGS solul ion) raaged fn~m appf'OAimately 3 }1: lO · t·o 1 J> 10-'~ em/!;, (one to :fh•e order'1 of magnifatle lo• .... er Lhan ctt MW-+1-1 with a geelnelri£ avera"e of approximately I Jl 10-j cmh> (two nrders of magnttuEI:e lower llmfl al MV·/ 11). The eHeel of this muJsil::ion from higl:ler to lovw'er per!Tleabilily in to reduc-e-Hte rate of ~<Wefl:leJtt-s lh of TW4 '1 and south seuthv.-es! of taillng!i Cel:l4A. The extensive hydraulic testing of perched zone wells at the site indicates that perched zone permeabilities are generally low with the exception of the apparently isolated zone of higher permeability associated with the chloroform plume east to northeast (cross-gradient to upgradient) of the tailings cells. The geometric average hydraulic conductivity (approximately 1 x 10-5 cm/s) of the DR-series piezometers which cover an area nearly half the size of the total monitored area at White Mesa (excluding MW-22), is nearly identical to the geometric average hydraulic conductivity of 1.01 x 10-5 cm/s reported by TITAN (1994), and is within the range of 5 to 10 feet per year (ft/yr) [approximately 5 X w-6 cm/s to 1 X 10-5 cm/s] reported by Dames and Moore (1978) [the 1978 ERJ for the (saturated) perched zone during the initial site investigation. Because of the generally low permeability of the perched zone beneath the site, well yields are typically low (less than 0.5 gpm), although sustainable yields of as much as 4 gpm (for example, at TW4-19, shown in Figure 5) are possible in wells intercepting the relatively large saturated thicknesses within the higher permeability zone located east to northeast (cross-gradient to upgradient) of the tailings cells at the site. Sufficient productivity can generally be obtained only in areas where the saturated thickness is greater, which is one reason that 1) some perched zone we.l l complete u ar the n rthcrn w11 li e pontl · are rdaliv ly producti c nd 2) the perched zone has been used on a limited basis as a water supply to the north (upgradient) of the site. 2.5.1.4 Perched Groundwater Flow Perched groundwater flow at the site has historically been to the south/southwest. Figure 5 groundwater elevations indicate that beneath and south of the tailings cells, in the west central portion of the site, perched water flow is south-southwest to southwest. Flow on the western margin of White Mesa is generally south, approximately parallel to the mesa rim (where the Burro Canyon Formation [and perched zone] is terminated by erosion). On the eastern side of the site .. perched water flow is also generally southerly. Near the wildlife ponds, flow direction ranges locally from westerly (west of the ponds) to easterly (east of the ponds) resulting in a generally north-south perched water divide along a line connecting the ponds. Cones of depression result from pumping of •hl roform we lls wells MW-4, TW4-4, TW4-19, TW4-20, 25 and ~VV-26_an=· ~d~n~iu~·a~'~~~~~~~~~:=~~~~~=-~~~ pumped to reduce chloroform and nitrate mass in the perched zone east and northeast of the tailings cells. In general, perched groundwater elevations have not changed significantly at most of the site monitoring wells since installation, except in the vicinity of the wildlife ponds and the pumping wells. For example, relatively large increases in water levels occurred between 1994 and 2002 at ~-4 and ~VV-19, located in the east and northeast portions of the site. tts di5eussecl in HGC (2007a). These water level increases in the northeastern and eastern portions of the site are the result of seepage from wildlife ponds located near piezometers PIEZ-1 through PIEZ-5 shown in Figure 5, which were installed in 2001 for the purpose of investigating these changes. The mounding associated with the wildlife ponds and the general increase in water levels in the northeastern portion of the site have resulted in a local steepening of groundwater gradients over portions of the site. Conversely, pumping of bl roform wells ~W-4, TW4-4, TW4-19, TVV4-20, and ~-26 and nitrate w Jls T WN--· 4-_2, TW4-24, and TW -25 has depressed the perched water table locally and reduced average hydraulic gradients to the south and southwest of these wells. At the request f DRC. water has not been deli red to the northern wildli~ ponds ~ince March. 2012. T he p r hed water mound~ . iated \ ilh re barge lrom tbe:e p nd. i. liminishin= and i e. pe fl:d to conlinue to di mini~h. ther by redWJi ng hydraulic gradients downg:railicnt of the pond.'\, in parti ulnr to the south and southwest. As discussed above, perched water discharges in springs and seeps along VV estwater Creek Canyon and Cottonwood Canyon to the west-southwest of the site, and along Corral Canyon to the east of the site. The known discharge points located directly downgradient of the tailings cells are Westwater Seep and Ruin Spring. These features are located more than 2,000 feet west- southwest and more than 9,000 feet south-southwest of the tailings cells at the site as shown in Figure 5. DR-8, located approximately 4,000 feet southwest of the tailings cells, is located near the mesa rim above Cottonwood Seep along a line between the tailings cells and Cottonwood Seep. Although tihere is no evidence to connect Cottonwood Seep to the perched water system a. it i eparated ti·om the p rch d warcr by appro, imal Jv 2 0 f~.::el f 1 v perme· bi litv sh le and mudstones. However, under hypothetical conditions that Cottonwood Seep receives some contribution from perched water, perched water passing beneath the tailings cells would presumably pass by DR-8 before continuing on an unidentified potential pathway toward Cottonwood Seep. Figure e-+5 shows perched water pathlines southwest of the tailings cells based on first quarter, ~2014 perched water level data. Paths 1 and 3 represent the shortest pathlines to discharge points VVestwater Seep and Ruin Spring, respectively. Path 2 is the shortest pathline to DR-8, located near the edge of the mesa above Cottonwood Seep. A potential pathline is drawn from DR-8 to Cottonwood Seep. Although tb r i · no vidence to connect ' tt nwood ecp t the per hed wat r ·y tern . this p t nlial patl1J in i. repres nled t allo ~ r lh pos:ibiliLy of ll D as yet unidentified connection. Westwater Seep is downgradient of tailings Cell 1 and the western portions of Cells 2, 3, and 4B. DR-8 is downgradient of tailings Cells 2, 3 and 4B. Ruin Spring is downgradient of Ce114A, and the eastern portions of Cells 2, 3, and 4B. 26 2.5.1.5 Perched Zone Hydrogeology Beneath And Downgradient Of The Tailings Cells The perched zone hydrogeology southwest (downgradient) of the tailings cells is similar to other areas of the site except that the saturated thicknesses are generally smaller, portions of the perched zone are dry, and hydraulic gradients and hydraulic conductivities are relatively low. The combination of shallow hydraulic gradients, relatively low permeabilities, and small saturated thicknesses, results in rates of perched water movement that are among the lowest on- site. In the immediate vicinity of the tailings cells, perched water was encountered at depths of approximately ~53 to -~ l L 7 fl below the top of casing ("btoc") as of the first quarter of 2014.g, (Figure 7). Beneath tailings Cell 3, depths to water ranged from approximately 6&1 feet in the eastern portion of the cell, to approximately -l--l-§--117 ft btoc at the southwest margin of the cell. Assuming an average depth of the base of tailings Cell 3 of 25 feet below grade, this corresponds to perched water depths of approximately ~2 to 9Q-92 feet below the base of the cell, and an average depth of approximately ~65_feet beneath the base of the cell. Beneath tailings Cell 4B, depths to water ranged from approximately 106 ft btoc in the northeastern portion of the cell (at MW-5), to approximately 112ft btoc at the southwest margin of the cell (at MW-35). Assuming an average depth of the base of tailings Cell 4B of 25 feet below grade, this corresponds to perched water depths of approximately 81 to 87 feet below the base of the cell, and an average depth of approximately 84 feet beneath the base of the cell. The saturated thickness of the perched zone in the immediate vicinity of the tailings cells as of the first quarter of ~q.._20J4 ranges from approximately 8J-80 feet to negligible (Figure 8). Beneath tailings Cell 3, the saturated thickness varies from approximately ~60 feet in the eastern portion of the cell to approximately 7 feet in the western portion of the cell. Beneath tailings Cell 4B, the saturated thickness varies from approximately 21 feet in the southeastern portion of the cell to negligible in the southwestern portion of the cell, where a dry zone, defined by MW-33 and former (historically dry) well MW-16, is present. Saturated thicknesses in the southwest area of the site are affected by n-lhe ridge-like high in the Burro Canyon Formation/Brushy Basin Member contact ( Figur • 4 ). The iaflueaee of this paleoridge is discussed ia HGC (2012a). As shown in Figures 5 and 8~ dry eoaditioas orto low saturated thickness conditions are associated with this paleoridge. South-southwest of the tailings cells, the saturated thickness ranges from negligible at MW-21 (historically dry) to approximately 25 feet at DR-9. Small saturated thicknesses (less than 3 feet) near DR-6, DR-7, and DR-9 (west and southwest of Cell4B) result from this-the paleoridge. The average saturated thickness based on measurements at MW-37, DR-13, MW-3, MW-20, and DR-21, which lay close to a line between the southeast portion of tailings Cell 4B and Ruin Spring, is approximately 8 feet. The average saturated thickness based on measurements at MW- 35, DR-7, and DR-6, which are the points closest to a line between the southeast portion of tailings Cell 3 and Westwater Seep, is approximately 5 feet. 27 northea..;;l to Ruin &~te--\¥H:ie.--pef0hed zofle hydraulic gmdimw> l1'i of the fimt quetner of 20112 nmge froffif\ I'Jl8X:imum of oppreximately 0.07 feet per foe~ :L of util:i:ng;, Cell 2 to upprE»:.in'lately 0-:-QO l ftlft iJT--l-1-le nonbeuzilern portioe of the site (betweeA TWM 15 and M\V I). HycffiH:tli-e ~radienLs in Lhe soullw•esl per~ a--ef-1~-te are Lypi-ea~ly close to 0.0 I ftlfL etlt lhe gradient is less lhan 0.005 ft/ft wesllsot:t4:fi.we';l of tailings Gell 4B between CeiJ 'IB and DR 8. Tb _ hydraulic gradient between the west dike of tailings Cell 3 and Westwater Seep is approximately 0.0122 ft/ft, and between the south dike of tailings Cell 4B and Ruin Spring, approximately 0.0118 ft/ft 2.5.2 Groundwater Quality 2.5.2.1 Entrada/Navajo Aquifer The Entrada and Navajo Sandstones are prolific aquifers beneath and in the vicinity of the site. Water :Llpply wells at the site are screened in both of these units, and therefore, ·f, r the purp , e of this eli cu ion, they will be treated as a single aquifer. Water in the Entrada/Navajo Aquifer is under artesian pressure, rising 800 to 900 ft above the top of the Entrada · cont act with th overlying Summervillle Formation; static water levels are 390 to 500 ft below ground surface. Within the region, this aquifer is capable of yielding domestic quality water at rates of 150 to 225 gpm, and for that reason, it serves as a secondary source of water for the Mill. Additionally, two domestic water supply wells drawing from the Entrada/Navajo Aquifer are located 4.5 miles southeast of the Mill site on the Ute Mountain Ute Reservation. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth of the aquifer (>1,000 ft bls) makes access difficult. Table 2.5.2.1-1 is a tabulation of groundwater quality of the Navajo Sandstone aquifer as reported in the FES and subsequent sampling. TDS ranges from 244 to 1,110 mg/liter in three samples taken over a period from January 27, 1977, to May 4, 1977. High iron (0.057 mglliter) concentrations are found in the Navajo Sandstone. Because the Navajo Sandstone aquifer is isolated from the perched groundwater zone by approximately 1,000 to 1,100 ft of materials having a low average vertical permeability, sampling of the Navajo Sandstone is not required under the Mill's previous NRC Point of Compliance monitoring program or under the Permit. However, samples were taken at two other deep aquifer wells (#2 and #5) on site (See Figure 9 for the locations of these wells), on June 1, 1999 and June 8, 1999, respectively, and the results are included in Table 2.5.2.1-1. 2.5.2.2 Perched Groundwater Zone Perched groundwater in the Dakota/Burro Canyon Formation is used on a limited basis to the north (upgradient) of the site because it is more easily accessible. The quality of the Burro Canyon perched water beneath and downgradient from the site is poor and extremely variable. 28 The concentrations of TDS measured in water sampled from upgradient and downgradient wells range between approximately 600 and 5,300 mg/1. Sulfate concentrations measured in three upgradient wells varied between 670 and 1,740 mg/1 (Titan, 1994). The perched groundwater therefore is used primarily for stock watering and irrigation. The saturated thickness of the perched water zone generally increases to the north of the site. See the-Section 2.11.2 below for a more detailed discussion of background ground water quality in the perched aquifer. 2.5.3 Springs and Seeps As discussed in Section 2.5.1.4, perched groundwater at the Mill site discharges in springs and seeps along Westwater Creek Canyon and Cottonwood Canyon to the west-southwest of the site, and along Corral Canyon to the east of the site, where the Burro Canyon Formation outcrops. Water samples have been collected and analyzed from springs and seeps in the Mill vicinity as part of the baseline field investigations reported in the 1978 ER (See Table 2.6-6 in the 1978 ER). During the period 2003-2004, Denison EFRI implemented a sampling program for seeps and springs in the vicinity of the Mill which had been sampled in 1978, prior to the Mill's construction. Four locations were designated for sampling, which areas shown on Figure 9. These are Ruin Spring (G3R), Cottonwood Seep (G4R), west of Westwater Creek (G5R) and Corral Canyon (G 1R). During the 2-year study period only two of the four locations \vere able tecould be sampled, Ruin Spring and Cottonwood Canyon. The other two locations, Corral Creek and the location west of Westwater Creek were not flowing (seeping), and samples could not be collected. With regard to the Cottonwood seep, while water was present, the volume was not sufficient to complete all determinations, and only organic analyses were conducted. +he results of the organic aAnalysis of the ollom · od Seep \ ater ~uno! s did not detect any detectable organics. Samples at Ruin Spring were analyzed for major ions, physical properties, metals, radionuclides, volatile and semi-volatile organic compounds, herbicides and pesticides, and synthetic organic compounds. With the exception of one chloromethane detection, all organic determinations were at less than detectable concentrations. The detection of chloromethane is not uncommon in groundwater and can be due to natural sources. In fact, chloromethane has been observed by Denison EFRI at detectable concentrations in field blank samples during routine groundwater sampling events. The results of sampling for the other parameters tested are shown in Table 2.5.3-1. The results of the 2003/2004 sampling did not indicate the presence of mill derived groundwater constituents and are representative of background conditions. As required by Part I.E.6 of the Permit, the Mill has implemented a Sampling Plan for Seeps and Springs. Per Part I.E.6 -of the Permit, sampling of seeps and springs in required annually. A copy of the approved Sampling Plan for Seeps and Springs Revision lG, dated March 17, ~June 10, 2011,-is included as Appendix B-~to this Application. Denison EFRI submitted Revision 1.0 on June 10, 2011. Revision 1.0 is currently undergoing review by the Director. See Section 2.12.2 below for a more detailed description of the Plan. The first sampling under the Plan was completed in August, 2009. A summary of sampling results from the 2009, 2010, and 2Q.i--l.through -2013 sampling events, performed under the approved Sampling Plan for Seeps and Springs, is provided in Table 2.5.3-2 through Table 2.5.3-5. 29 2.5.4 Topography The Mill site is located on a gently sloping mesa that, from the air, appears similar to a peninsula, as it is surrounded by steep canyons and washes and is connected to the Abajo Mountains to the north by a narrow neck of land. On the mesa, the topography is relatively flat, sloping at less than one (1) percent to the south and nearly horizontal from east to west. See also Figure 6. 2.5.5 Soils The majority (99%) of the soil at the Mill site consists of the Blanding soil series (1978 ER, Section 2.10.1.1). The remaining 1% of the site is in the Mellenthin soil series. Because the Mellenthin soil occurs only on the eastern-central edge of the site (1978 ER, Plate 2.10-1), the FES (Section 2.8) concluded that it should not be affected by Mill construction and operation. The Mill and associated tailings cells are located on Blanding silt loam, a deep soil formed from wind-blown deposits of fine sands and silts. Although soil textures are predominantly silt loam, silty-clay-loam textures are found at some point in most profiles (See Appendix G-IlJo this Application-Results of Soil Analysis at Mill Site). This soil generally has a 4 to 5 inch reddish- brown, silt-loam A horizon and a reddish-brown, silt-loam to silty-clay-loam B horizon. The B horizon extends downward about 12 to 16 inches where the soil then becomes calcareous silt- loam or silty-clay-loam, signifying the C horizon. The C horizon and the underlying parent material are also reddish-brown in color. The A and B horizon both are non-calcareous with an average pH of about 8.0, whereas the C horizon is calcareous with an average pH of about 8.5. Subsoil sodium levels range up to 12% in some areas, which is close to the upper limit of acceptability for use in reclamation work (1978 ER, Sect. 2.1 0.1.1 ). Other elements, such as boron and selenium, are well below potentially hazardous levels. Potassium and phosphorus values are high in this soil (1978 ER, Table 2.10-2) and are generally adequate for plant growth. Nitrogen, however, is low (1978 ER, Sect. 2.10.1.1) and may have to be provided for successful revegetation during final reclamation. With well-drained soils, relatively flat topography (see Section 2.5.4), and limited annual precipitation (see Section 2.5.1.2), the site generally has a low potential for water erosion. However, the flows resulting from thunderstorm activity are nearly instantaneous and, without the Mill's design controls, could result in substantial erosion. When these soils are barren, they are considered to have a high potential for wind erosion. Although the soil is suitable for crops, the low percentage of available moisture (6 to 9%) is a limiting factor for plant growth; therefore, light irrigation may be required to establish native vegetation during reclamation. 2.5.6 Bedrock Subsurface conditions at the Mill site area were investigated as part of the 1978 ER by drilling, sampling, and logging a total of 28 borings which ranged in depth from 6.5 to 132.4 ft. Of these borings, 23 were augured to bedrock to enable soil sampling and estimation of the thickness of the soil cover. The remaining 5 borings were drilled through bedrock to below the perched water table, with continuous in situ permeability testing where possible and selective coring in 30 bedrock. The soils encountered in the borings were classified, and a complete log for each boring was maintained. See Appendix A of Appendix H of the 1978 ER. Borings in the footprint of the existing tailings cells reported calcareous, red-brown sands and silts from the surface to a depth of 15 ft, averaging over 7 ft. Borings in the general area of the Mill site and the tailings cells reported calcareous, red-brown sands and silts from the surface to a depth of 14 ft, averaging over 9 ft. Downgradient of the tailings cells, calcareous sands and silts extend to a depth of 17 ft of the surface. The calcareous silts and sands of the near-surface soils grade to weathered claystones or weathered sandstones, inter-layered with weathered claystone and iron staining. At depth, the weathered claystone or weathered clayey sandstone grade into sandstone with inter-layered bands of claystone, gravel, and conglomerate. Some conglomerates are cemented with fLCalcareous matrix. 2.5.7 Agricultural and Land Use Description of the Area Approximately 65.8% of San Juan County is federally owned land administered by the U.S. Bureau of Land Management, the National Park Service, and the U.S. Forest Service. Primary land uses include livestock grazing, wildlife range, recreation, and exploration for minerals, oil, and gas. Approximately 22% of the county is Native American land owned either by the Navajo Nation or the Ute Mountain Ute Tribe. The area within 5 miles of the Mill site is predominantly range land owned by residents of Blanding. The Mill site itself, including tailings cells, encompasses approximately 300 acres. A more detailed discussion of land use at the Mill site, in surrounding areas, and in southeastern Utah, is presented in the FES (Section 2.5). Results of archeological studies conducted at the site and in the surrounding areas as part of the 1978 ER are also documented in the FES (Section 2.5.2.3). 2.5.8 Well Logs Well/boring logs for wells MW-1, MW-2, MW-3, MW-4 (not a compliance well under the Permit), MW-5, MW-11, MW-12, MW-14, MW-15, MW-16 (not a compliance well under the Permit and abandoned during the construction of Tailings Cell4B), MW-17, MW-18, and MW- 19, are included as Appendix A to the 1994 Titan Report. A copy of the 1994 Titan Report was previously submitted under separate cover. Lithologic and core logs for wells MW-3A, MW-23, MW-24, MW-25, MW-27, MW-28, MW- 29, MW-30 and MW-31 are included as Appendix A to the Report: Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill April Through June 2005, August 3, 2005, prepared by Hydro Geo Chern, Inc. A copy of that Report was previously submitted under separate cover. Lithologic and core logs for well MW-26 (previously named TW4-15) and well MW-32 (previously named TW 4-17) are included as Appendix A to the Letter Report dated August 29, 2002, prepared by Hydro Geo Chem, Inc. and addressed to Harold Roberts. Lithologic and core logs for well MW-33, MW-34 and well MW-35 are included as Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-33, MW-34, and 31 MW-35 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. October 11, 2010. A copy of that Report was previously submitted under separate cover. Lithologic and core logs for well MW-36 and well MW-37 are included as Appendix A to the Installation and Hydraulic Testing of Perched Monitoring Wells MW-36 and MW-37 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. June 28, 2011. A copy of that Report was previously submitted under separate cover. 2.6 The Type, Source, and Chemical, Physical, Radiological, and Toxic Characteristics of the Emuent or Leachate to be Discharged (R317-6-6.3.F) The Mill is designed not to discharge to groundwater or surface waters. Instead, the Mill utilizes tailings and evaporation Cells for disposal or evaporation of Mill effluents as indicated below: • Cell 1: -dedicated to evaporation of Mill waste solutions; • Cell 2:_-contains Mill tailings, has an interim cover and is closed to future tailings disposal; • Cell 3: -contains Mill tailings and is in the final stages of filling; • Cell4A: -receives Mill tailings and is used for evaporation of Mill solutions; and • Cell 4B: -aulb l'iz d lo receive Mill tailing atltl-but currently i. u ed onl y for evaporation of Mill solutions. See Sections 2.7.2 through 2.7.4 below for a more detailed discussion of the Mill's tailings cells. The projected chemical and radiological characteristics of tailings solutions were assessed by Energy Fuels Nuclear, Inc., a predecessor operator of the Mill, and NRC in 1979 and 1980, respectively. In addition, early samples were assessed by D' Appolonia Engineering as the Mill started operations to further evaluate and project the character of the solutions. Samples of tailings after the Mill was fully operational were collected by NRC (1987), DeaisoeEFRI/UDEQ (2003), and DeHiseH EFRI (2007 -2013), DeHiseH (2008) and DeHiseH (2009). Samples collected in 2003 were obtained under the oversight of DRC personnel. The Samples collected in 2007 and 2008 were obtained by DeHiseH EFRI on a voluntary basis as the then proposed Tailings and Slimes Drain Sampling Plan (the "Tailings Sampling Plan") had not been approved by the Director at that time. The 2009 samples were collected on August 6, 2009 under the appre·1ed Tailings Sampling Plan tbat was appro cd at lhat time. Subsequent annual amplinghas been pedormed in Aug\.1 t 2010. 20 11. 20 12 and ~2013 under an t-Re approved Tailings Sampling Plan. of this writiRg, DeAisetl bas st:lbR-1iHed Revbioa 2.0 of tl:ie TailiAgs SampliAg Plifll. wlti€fl-is curreml·y-tHHlergeing nniew by the Di rector. A copy of th urrently appr ved Tailin 2. Sampling Plan is included as Agp nd.L'\. L. The chemical and radiological characteristics of the solutions held in the tailings cells, based on the sample results described above, are provided in the tables included in Appendix D,E, which list the concentration of parameters measured in accordance with the Permit. There is no active discharge from the tailings Cells; therefore, an estimation of the flow rate C:gpd:_) is not applicable in this instance. However, when operating at full capacity, the Mill 32 discharges approximately 2000 tons per day of dry tailings and approximately 600 gpm of tailings solutions to the Mill's tailings cells. 2.7 Information Which Shows that the Discharge can be ControiJed and Will Not Migrate Into or Adversely Affect the Quality of any Other Waters of the State (R317-6-6.3.G) 2. 7.1 General The Mill has been designed as a facility that does not discharge to groundwater or surface water. All tailings and other Mill wastes are disposed f permanently into the Mill's tailings system. Excess waters are disposed of in the tailing r evaporati n -cells, where they are subject to evaporation, or re-processed through the Mill circuit. See Section 2.6. The Mill was also designed and constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the tailings cells; and b) diverting runoff from surrounding areas away from the Mill site. The Permit therefore does not authorize any discharges to groundwater or surface water, but is intended to protect against potential inadvertent or unintentional discharges, such as through potential failure of the Mill's tailings system. The Mill's tailings system is currently comprised of four tailings cells (Cells 2, 3 4A, and 4B) and one evaporation pond (Cell 1). Diagrams showing the Mill facility layout, including the existing tailings cells are included as Figures 10 and 11 to this Application. In addition, the Mill ha .. a lined catchmenr ba jJl, u ed for temporary torage of Mill pn~ces up el fl uid , known a Rober Pond'. Robens P nd i about 0.4G-l_acr in .ize and round l med approximately 180 feet west of the Mill building and about 200 feet east of the northeast corner of Cell 1. The following sections describe the primary Discharge Minimization Technology ("DMT") and Best Available Technology ("BAT") features of the Mill, which demonstrate that the wastes and tailings at the Mill can be controlled so that they do not migrate into or adversely affect the quality of any waters of the State, including groundwater and surface water. 2.7.2 Cells 1, 2 and 3 2. 7.2.1 Design and Construction of Cells 1, 2 and 3 Tailings Cells 1, 2 and 3 were each constructed more than 25 years ago. Construction of Cell 2 was completed on May 3, 1980, construction of Cell 1 was completed on June 29, 1981, and construction of Cell 3 was completed on September 15, 1982. 33 Each of Cells 2 and 3 also has a slimes drain collection system immediately above the FML, comprised of a nominal 12-inch thick protective blanket layer of soil or comparable material, on top of which is a network of PVC perforated pipe laterals on a grid spacing interval of about 50- feet. These pipe laterals gravity drain to a perforated PVC collector pipe which also drains toward the south dike and is accessed from the ground surface via a non-perforated access pipe. At cell closure, leachate head inside the pipe network will be removed via a submersible pump installed inside the access pipe See Part I.D.1 of the Permit for a more detailed description of the design of Cells 1, 2 and 3. After review of the existing design and construction and consultation with the State of Utah Division of Water Quality, the Director determined, in connection with the issuance of the Permit in 2005, that the DMT required under the groundwater quality protection rules (UAC R317 -6-6.4( c )(3)) for Cells 1, 2 and 3 that pre-dated those rules will be defined by the current or existing disposal cell construction, with a-few-modifications that were included in the Permit (see page 25 of the 2004 Statement of Basis). These modifications focus on changes in monitoring requirements, and on improvements to facility closure. The goal of these improvements is to ensure that potential wastewater losses are minimized and local groundwater quality is protected. Th modifications are described in Sections 2.7.2.2, 2.7.2.3 and 2.7.2.4 below. 2.7.2.2 Improved Groundwater Monitoring Improvements were made to the Mill's groundwater monitoring network at the time of issuance of the Permit, to meet the following goals: 34 a) Early Detection Three monitoring wells (MW-24, MW-27 and MW-28) were added immediately adjacent to Cell 1, in order to detect a potential release as early as practicable. b) Discrete Monitoring In order to individually monitor each tailings cell and to be able to pinpoint the source of any potential groundwater contamination that may be detected, the Permit required the addition of three monitoring wells (MW-29, MW-30 and MW-31) between Cells 2 and 3, in addition to the addition of wells MW-24, MW-27 and MW-28 immediately adjacent to Celll. The addition of monitoring wells MW-24, MW-27, MW-28, MW-29, MW-30 and MW-31, together with the existing monitoring wells at the site provides a comprehensive monitoring network to determine any potential leakage from Cells 1, 2 and 3. See Figure 4 and Figure 10 for a map showing the locations of the existing compliance monitoring wells for the site. 2. 7.2.3 Operational Changes and Improved Operations Monitoring The Permit also required changes to disposal cell operation in order to increase efforts to minimize potential seepage losses, and thereby improve protection of local groundwater quality. Examples of these changes are: c) Maximum Waste and Wastewater Pool Elevation Part I.D.3 of the Permit requires that Denison EFRI continue to ensure that impounded wastes and wastewaters for all of the Mill's tailings Cells and Roberts Pond are held within an FML. d) Slimes Drain Maximum Allowable Head Part I.D.3(b) of the Permit requires that the Mill provide constant pumping efforts to minimize the accumulation of leachates over the FML in Cell 2, and upon commencement of dewatering activities, in Cell 3, and thereby minimize potential FML leakage to the foundation and groundwater. See the discussion in Section 2.15.2.2 below. 2. 7.2.4 Evaluation of Tailings Cell Cover System Design 35 See Section 2.19 below for a more detailed discussion of post -closure requirements for the Mill. 2.7.3 Celi4A Construction of Cell 4A was completed on or about November 1989. Cell 4A was used for a short period of time after its construction for the disposal of raffinates from the Mill's vanadium circuit. No tailings waste or wastewater had been disposed of in Cell 4A since the early 1990s. This lack of waste disposal, and exposure of the FML to the elements, caused Cell 4A to fall into disrepair over the years. Although the original design of Cell4A was an improvement over the design of Cells 1, 2 and 3 (it had a one-foot thick clay liner under a 40 ml high density polyethylene ("HDPE") FML, with a more elaborate leak detection system), it was constructed in 1989 and did not meet today' s BAT standards. Cell 4A was re-lined in 2007-2008 and was re-authorized for use in November 2008. With the reconstruction of Cell 4A, BAT was required, as mandated by Part I.D.4 of the Permit and as 36 stipulated by the Utah Ground Water Quality Regulations at UAC R317-6-6.4(A). With BAT for Cell 4A, there are also new performance standards that require daily leak detection system monitoring, weekly wastewater level monitoring, and slimes drain recovery head monitoring. The BAT monitoring results are required to be reported and summarized in the Routine DMT and BAT Performance Standard Monitoring Reports. See Section 2.15.3 below for a more detailed discussion relating to the BAT performance standards and monitoring requirements for Cell4A. Tailings Cell 4A Design and Construction was approved by the Director as meeting BAT requirements. The major design elements are set out in Part I.D.5 of the Permit and consist of the following: e) Dikes -consisting of existing earthen embankments of compacted soil, constructed by a previous Mill operator between 1989-1990, and composed of four dikes, each including a 15-foot wide road at the top (minimum). On the north, east, and south margins these dikes have slopes of 3H to 1 V. The west dike has a slope of 2H to 1 V. Width of these dikes varies. Each has a minimum crest width of at least 15 feet to support an access road. Base width also varies from 89-feet on the east dike (with no exterior embankment), to 211-feet at the west dike. f) Foundation -including existing subgrade soils over bedrock materials. Foundation preparation included excavation and removal of contaminated soils, compaction of imported soils to a maximum dry density of 90%. The floor of Cel14A has an average slope of 1% that grades from the northeast to the southwest corners. g) Tailings Capacity -the floor and inside slopes of Cell 4A encompass about 40 acres and have a maximum capacity of about 1.6 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). h) Liner and Leak Detection Systems -including the following layers, in descending order: (i) Primary FML -consisting of an impermeable 60 mil HDPE membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored in a trench at the top of the dikes on all four sides. The primary FML is in direct physical contact with the tailings material over most of the Cell 4A floor area. In other locations, the primary FML is in contact with the slimes drain collection system (discussed below). (ii) Leak Detection System-includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4A, and drains to a leak detection sump in the southwest corner. Access to the leak detection sump is via an 18-inch inside diameter (ID) HDPE pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe is surrounded with a gravel filter set in the leak detection sump, having dimensions of 10 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer is enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. (iii) Secondary FML -consisting of an impermeable 60-mil HDPE membrane found immediately below the leak detection geonet. This FML also extends across the 37 entire Cell 4A floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. (iv) Geosynthetic Clay Liner -consisting of a manufactured geosynthetic clay liner CGCL:) composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. i) Slimes Drain Collection System -including a two-prut system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: (i) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4A that drains to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated .. two-patt geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southwesterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. (ii) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection CSDC:) pipe found at the downgradient end of the strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast corner downhill to the far southwest corner of Cell 4A where it joins the slimes drain access pipe. (iii) Slimes Drain Access Pipe -consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell 4A at the southwest corner, above the primary FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and woven geotextile that serves as a cushion to protect the primary FML. A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. j) North Dike Splash Pads-three 20-foot wide splash pads have been constructed on the north dike to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HDPE membrane that has been installed in the anchor trench and placed down the inside slope of Cell 4A, from the top of the dike, under the inlet pipe, and down the inside slope to a point 5-feet beyond the toe of the slope. k) Emergency Spillway - a concrete lined spillway has been constructed near the southwestern corner of the west dike to allow emergency runoff from Cell 4A to Cell 4B. At this time, all stormwater runoff and tailings wastewaters not retained in Cells 38 2, 3, and 4A will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. I) BAT Performance Standards for Tailings Cell 4A -DenisonEFRI shall operate and maintain Tailings Cell 4A so as to prevent release of wastewater to groundwater and the environment in accordance with an Operations and Maintenance Plan, as currently approved by the Director, pursuant to Part I.H.19. At a minimum these performance standards shall include: (i) Maximum Allowable Daily Head-on the secondary FML, (ii) Maximum Allowable Daily Leak Detection System Flow Rate (iii) Slimes Drain Monthly and Annual Average Recovery Head Criteria -to be applied after the Mill initiates pumping conditions in the slimes drain layer.:.; (iv) M~Lximum Da*y Wastewater LeYel to ensure compliance wilh 1he minimum +t:eeooord ret:Juiremeats for Cell .:!A, and f3revenl tliselHtf"~ of wastewnters \'ia overtopping. See Part I.D.5 of the Permit for a more detailed discussion of the design of Cell 4A. A copy of the Mill's Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan is attached as Appendix :g_F to this Application. 2.7.4 Cell 4B Construction of Cell4B was completed in November ~2010. Tailings Cell 4B Design and Construction was approved by the Director as meeting BAT requirements. The major design elements are set out in Part I.D.12 of the Permit and consist of the following: a) Dikes -consisting of newly constructed dikes on the south and west side of the cell, each including a 20-foot wide road at the top (minimum). The exterior slopes of the southern and western dikes have slopes of 3H to 1 V. The interior dikes have slopes of 2H to 1 V. Limited portions of the Cell 4B interior sidelopes in the northwest corner and southeast corner of the cell (where the slimes drain and leak detection sump are located) have a slope of 3H to 1 V. Width of these dikes varies. The base width of the southern dike varies from approximately 92 feet at the western end to approximately 190 feet at the eastern end of the dike, with no exterior embankment present on any other side of the cell. b) Foundation -including existing sub grade soils over bedrock materials. Foundation preparation included excavation and removal of contaminated soils, compaction of imported soils to a maximum dry density of 90%. The floor of Cell4B has an average slope of 1% that grades from the northwest to the southeast corner. c) Tailings Capacity -the floor and inside slopes of Cell 4B encompass about 40 acres and the cell has a maximum capacity 1.9 million cubic yards of tailings material storage (as measured below the required 3-foot freeboard). d) Liner and Leak Detection Systems -including the following layers, in descending order: (i) Primary FML -consisting of an impermeable 60 mil HDPE membrane that extends across both the entire cell floor and the inside side-slopes, and is anchored 39 in a trench at the top of the dikes on all four sides. The primary FML is in direct physical contact with the tailings material over most of the Cell4B floor area. In other locations, the primary FML is in contact with the slimes drain collection system (discussed below). (ii) Leak Detection System -includes a permeable HDPE geonet fabric that extends across the entire area under the primary FML in Cell 4B, and drains to a leak detection sump in the southeast corner. Access to the leak detection sump is via an 18-inch inside diameter C.~ID:_',) HDPE pipe placed down the inside slope, located between the primary and secondary FML liners. At its base this pipe is surrounded with a gravel filter set in the leak detection sump, having dimensions of 15 feet by 10 feet by 2 feet deep. In turn, the gravel filter layer is enclosed in an envelope of geotextile fabric. The purpose of both the gravel and geotextile fabric is to serve as a filter. (iii) Secondary FML -consisting of an impermeable 60-rnil HDPE membrane found immediately below the leak detection geonet. This FML also extends across the entire Cell 4B floor, up the inside side-slopes and is also anchored in a trench at the top of all four dikes. (iv) Geosynthetic Clay Liner -consisting of a manufactured geosynthetic clay liner C.~GCL:) composed of 0.2-inch of low permeability bentonite clay centered and stitched between two layers of geotextile. e) Slimes Drain Collection System -including a two-part system of strip drains and perforated collection pipes both installed immediately above the primary FML, as follows: (i) Horizontal Strip Drain System -is installed in a herringbone pattern across the floor of Cell 4B that drains to a "backbone" of perforated collection pipes. These strip drains are made of a prefabricated two-part geo-composite drain material (solid polymer drainage strip) core surrounded by an envelope of non-woven geotextile filter fabric. The strip drains are placed immediately over the primary FML on 50-foot centers, where they conduct fluids downgradient in a southeasterly direction to a physical and hydraulic connection to the perforated slimes drain collection pipe. A series of continuous sand bags, filled with filter sand cover the strip drains. The sand bags are composed of a woven polyester fabric filled with well graded filter sand to protect the drainage system from plugging. (ii) Horizontal Slimes Drain Collection Pipe System -includes a "backbone" piping system of 4-inch ID Schedule 40 perforated PVC slimes drain collection (SDC) pipe found at the downgradient end of the strip drain lines. This pipe is in turn overlain by a berm of gravel that runs the entire diagonal length of the cell, surrounded by a geotextile fabric cushion in immediate contact with the primary FML. In turn, the gravel is overlain by a layer of non-woven geotextile to serve as an additional filter material. This perforated collection pipe serves as the "backbone" to the slimes drain system and runs from the far northeast corner downhill to the far southeast corner of Cell 4A where it joins the slimes drain access pipe. (iii) Slimes Drain Access Pipe-consisting of an 18-inch ID Schedule 40 PVC pipe placed down the inside slope of Cell4B at the southeast corner, above the primary 40 FML. Said pipe then merges with another horizontal pipe of equivalent diameter and material, where it is enveloped by gravel and woven geotextile that serves as a cushion to protect the primary FML. A reducer connects the horizontal 18-inch pipe with the 4-inch SDC pipe. At some future time, a pump will be set in this 18-inch pipe and used to remove tailings wastewaters for purposes of de-watering the tailings cell. f) North and East Dike Splash Pads -nine 20-foot wide splash pads have been constructed on the north and east dikes to protect the primary FML from abrasion and scouring by tailings slurry. These pads consist of an extra layer of 60 mil HDPE membrane that has been installed in the anchor trench and placed down the inside slope of Cell4B, from the top of the dike, under the inlet pipe, and down the inside slope to a point 5-feet beyond the toe of the slope. g) Emergency Spillway - a concrete lined spillway has been constructed near the southeastern corner of the east dike to allow emergency runoff from Cell4A into Cell 4B. This spillway is limited to a 6-inch reinforced concrete slab, with a welded wire fabric installed within its midsection, set directly atop a cushion geotextile placed directly over the primary FML in a 4-foot deep trapezoidal channel. A 100-foot wide, 60-mil HDPE membrane splash pad is installed beneath the emergency spillway. No other spillway or overflow structure will be constructed at Cell 4B_unless and until the construction of Cells SA and 5B. At this time, all stormwater runoff and tailings wastewaters not retained in Cells 2, 3, and 4A will be managed and contained in Cell 4B, including the Probable Maximum Precipitation and flood event. h) BAT Performance Standards for Tailings Cell 4B -DenisonEFRI shall operate and maintain Tailings Cell 4B so as to prevent release of wastewater to groundwater and the environment in accordance with the currently-approved Cell4B BAT, Monitoring, Operations and Maintenance Plan. At a minimum these performance standards shall include: (i) Maximum Allowable Daily Head-on the secondary FML, (ii) Maximum Allowable Daily Leak Detection System Flow Rate (iii) Slimes Drain Monthly and Annual Average Recovery Head Criteria -to be applied after the Mill initiates pumping conditions in the slimes drain layer, (iv) Maximum Daily Wastewater Level -to ensure compliance with the minimum freeboard requirements for Cell 4B, and prevent discharge of wastewaters via overtopping. See Part I.D.12 of the Permit for a more detailed discussion of the design of Cell 4B. A copy of the Mill's Cell 4A and 4B BAT Monitoring, Operations and Maintenance Plan is attached as Appendix B--F to this Application. 2.7.5 Future Additional Tailings Cells Future additional tailings cells at the Mill will require Director approval prior to construction and operation. All--ffuture tailings cells at the Mill will be required to satisfy BAT standards at the time of construction. 2.7.6 Roberts Pond 41 Roberts Pond receives periodic floor drainage and other wastewaters from Mill process upsets, is frequently empty, and was re-lined with a new FML in May, 2002. In order to minimize any potential seepage release from Roberts Pond, the Director has determined tool iffi ap19ropriale DMT opembions s~aAdurd would be two fold, us reqliired eyrequired the following in Part I.D.3( e) of the Permit: (i) EFRI "shall operate this wastewater pond [Rob Pond] so as to orovide a minimu m 2-foot freeboard at all times. Under no circumstances shall the water level in the pond exceed an elevation of 5,624 feet amsl. In the event that the wastewater elevation exceeds this maximum level, the Permittee [EFRil shall remove the excess wastewater and plac" it int containment in Tailing ell l within 72-h urs of disc very."A mipulalioR thnl tl:!e Mill mftintain a minimal was~e·water heud iA lb:is pond-l:'ltl!led OA a+ foot:-t=Feeboard limit uno a 1 fool adtlitioncll epemting limil: nne (ii) At the time of Mill site closure, Denison~FRI will excavate and remove the liner, berms, and all contaminated subsoils in compliance with an approved final reclamation plan under the Mill License. 2.7.7 Other Facilities and Protections 2.7.7.1 Feedstock Storage In order to constrain and minimize potential generation of contaminated stormwater or leachates, Part I.D.ll of the Permit requires the Mill to continue its existing practice of limiting open air storage of feedstock materials to the historical storage area found along the eastern margin of the Mill site (as defined by the survey coordinates found in Permit Table 4). The intent of Section I. D.l l. (ba:ed on l'he OB for the 2 09 GWDP). i ' Lo require lhllt feeJ, to k storage olltsiue of the area ·p Hi d in Table 4 hall meel lhe following requirem nrs:; tlfld oAe of U1e fo llowiRg lht=ee ~ractioes: 11 Store reeds leek muteria:f:; in ·.vuter tight contAins, or 2) Plaee feed!:toc lt containers in '<¥iller liglit overpack eo:nlffiJ'lers, or 3) pJaee feedstoele coRtainers on a hardeneekurfuee that eon forms to fhe requirerHetl£S speUeel Ol:ll in the permit part J.D . II d) I thro~ a) ecd rock materjals will be ~t r d al ali time in wat.er-ti1Ih l c nwiner . and ai ·] feedstock container. or storage, or 42 3) A storage area that provides containment berms to control storm water run-on and run- off. and 4) Stormwater dminage w art I.D.I L of the renewed GWDP be revised as set out above. 2. 7. 7.2 Mill Site Reagent Storage ~~tential reagenl tunk ~;pil ls or leit ' ~hat cottki-Te-J.et¥.ie-eeA1aminm=t~i-le soils or groundwater. anEI to prm':ide pffiper spill pt"e.,·enli:en ttA d coB:!fe-1., Part I.D.3(g) of the Permit requires the Mill to demonstrate that it has adequate provisions for spill response, cleanup, and reporting for reagent storage facilities,_. _ nnd EO iae!ude tbese i:a ttTb ·e pr visi n are detailed in the Stormwater Best Management Practices Plrul', ' hicb is tl iened to prev nl p Lenti 11 reagenl tank pill" or I aks that cou ld relca c contnminru1l! to site soil· or groundwater. and to pro id pr per ·pjlJ preventi n and nlr l. Contents of this plan are stipulated in Part I.D.8 of the Permit, and submittal and approval of the plan is required under Part I.H.17 of the Permit. For existing facilities at the Mill, secondary containment is required, although such containment may be earthen lined. For new facilities constructed at the Mill, or reconstruction of existing facilities, Part I.D.3(eg) requires fhe-g_higher standard of secondary containment that would prevent contact of any potential spill with the ground surface. A copy of the Mill's Stormwater Best Management Practices Plan, Revision 1.~2: Juae 12, ~September 2012 is attached as Appendix F-G to this Application. 2. 7. 7.3 New Construction Part I.D.4 of the Permit requires submittal of engineering plans and specifications and Director approval easures that all prior to the construction, modification, or operation of waste or wastewater disposal, treatment, or storage facilities requires submittal of eagiaeeriag plaas aad speeifieatioas aad prior Director approval. In these plans and specifications, the Mill is required to demonstrate how BAT requirements of the Groundwater Quality Protection Rules have been met. After Director Approval, a construction permit may be issued, and the Permit modified. 2. 7. 7.4 Other The White Mesa Mill TttiUngs Mtttutgentent System ttmi Discharge Minimization Technology (DMT) MonitorirP Plan, .Q-1112 Revj ion: Denison+h-SL2.J ~the DMT Pl an ), and th White Mesa Mill Tailing Mcmagernent -vswm, 7/20 12 Revi ion l2.1 (the Tailing Management Plan ), u co~ of \Uhich it: are attached as Appendix G-H and Appendix I to this Application .. r pe li ely., _is ft@_aesigned asTh ·e plan. pre vide a systematic program for constant surveillance and documentation of the integrity of the tailings system .. including monitoring the leak detection systems. The DMT Plan requires daily, weekly, quarterly, monthly and annual 43 inspections and evaluations and monthly reporting to Mill management. See Section 2.15.2 below for a more detailed discussion of the requirements of the DMT Plan. 2.7.8 Surface Waters The Mill has been designed as a facility that does not discharge to surface waters. AlHiailings and other Mill wastes are disposed of permanently into the Mill's tailings system. Further, as mentioned above, the Mill was designed and constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the tailings cells; and b) diverting runoff from surrounding areas away from the Mill site. As a result, there is no pathway for liquid effluents from Mill operations to impact surface waters. Under the Mill License, the Mill is required to periodically sample local surface waters to determine if Mill activities may have impacted those waters. The primary pathway would be from air particulate§. freflrgenerated during Mill operations that may have landed on or near surface waters, or that may have accumulated in drainage areas that could feed into surface waters. Sampling results since inception of Mill operations show no trends or other impacts of Mill operations on local surface waters. See the Mill's Semi-Annual Effluent Report for the period July_] to December 31, 201..J3_, a copy of which has previously been provided to the Director. 2.7.9 Alternate Concentration Limits The Mill does not discharge to groundwater or surface water, nor is it designed to do so. Therefore, no alternate concentration limits are currently applicable to the site. 2.8 For Areas Where the Groundwater Has Not Been Classified by the Board, Information of the Quality of the Receiving Ground Water (R317-6-6.3.H) Groundwater classification was assigned by the Director in the Permit on a well-by-well basis after review of groundwater quality characteristics for the perched aquifer at the Mill site. A well-by-well approach was selected by the Director in order to acknowledge the spatial variability of groundwater quality at the Mill, and afford the most protection to those portions of the perched aquifer that exhibited the highest quality groundwater. These groundwater classifications are set out in Part I. A and Table 1 of the Permit. The primary element used by the Director in determining the groundwater classification of each monitoring well at the site, is the TDS content of the groundwater, as outlined in UAC 317-6-3. Groundwater quality data collected by the Mill show the shallow aquifer at the Mill has a highly variable TDS content, with TDS averages ranging from about 1100 to over 7900 mg/L. Another key element in determination of groundwater class is the presence of naturally occurring contaminants in concentrations that exceed their respective GWQS. In such cases, the Director has cause to downgrade aquifer classification from Class IT to Class Ill (see UAC R317-6-3.6). Using all available TDS data and background data, for 24 of the POC and general monitoring wells the Director determined that 4 of those wells exhibit Class IT drinking water quality groundwater. The remaining 20 wells exhibited Class lll or limited use groundwater at the site. The Director determined that MW -35 will be classified as having Class IT drinking water quality 44 groundwater until sufficient background data have been collected and the applicable Background Report is submitted. Wells MW-36 and MW-37 have not been classified at this time. 2.8.1 Existing Wells at the Time of Original Permit Issuance The Director required DenisonEFRI to evaluate groundwater quality data from the thirteen existing wells on site, and submit a Background Ground Water Quality Report for Director approval. One of the purposes of that report was to provide a critical evaluation of historic groundwater quality data from the facility, and determine representative background quality conditions and reliable GWCLs for the Permit. DU8A EFR1 (then Den L on) prepared the Existing Well Background Report that evaluated all historic data for the thirteen existing wells for the purposes of establishing background groundwater quality at the site and developing groundv1ater COHlflliance limits GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the Existing Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells, based primarily on the analysis performed in the Existing Wellls Background Report. It should be noted, however, that, because the GWCLs have been set at the mean plus second two standard deviation~, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. 2.8.2 New Wells Installed After the Date of Original Issuance of the Permit Because the Permit called for installation of nine new monitoring wells around the tailings cells, background groundwater quality had to be determined for those monitoring points. To this end, the Permit required the Mill to collect at least eight quarters of groundwater quality data, and submit the New Well Background Report for Director approval to establish background groundwater quality for those wells. DU8A EFRI (then Denison) prepared the New Well Background Report that evaluated all historic data for the nine new wells for the purposes of establishing background groundwater quality at the site and developing groundvlater compliance limits GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the New Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the nine new wells based primarily on the analysis performed in the New Well :SBackground Report. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are 45 expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. 2.9 Sampling and Analysis Monitoring Plan (R317-6-6.3.1) The groundwater monitoring plan is set out in the Permit. All groundwater monitoring at the site is in the perched aquifer. The following sections summarize the key components of the Mill's sampling and analysis plan. 2.9.1 Ground ¥water Monitoling to Detcnnine Ground-W1_ater Flow Dir ction and Gradient, Background Quality at the Site, and the Quality of Ground..W~ater at the Compliance Monitoring Point 2.9.1.1 Groundwater Monitoring at the Mill Prior to Issuance of the Permit At the time of renewal of the Mill license by NRC in March, 1997 and up until issuance of the Permit in March 2005, the Mill implemented a groundwater detection monitoring program te ens:tJre cornpliailCe Lo 10 CFR Part ·10 i\ppeH~, in accordance with 10 CFR Part 40, Appendix A and the provisions of then Mill License condition 11.3A. The detection monitoring program was implemented in accordance with the report entitled, Points of Compliance, White Mesa Uranium Mill, prepared by Titan Environmental Corporation, submitted by letter to the NRC dated October 5, 1994. Under that program, the Mill sampled monitoring wells MW-5, MW-11, MW-12, MW-14, MW-15 and MW-17, on a quarterly basis. Samples were analyzed for chloride, potassium, nickel and uranium, and the results of such sampling were included in the Mill's Semi-Annual Effluent Monitoring Reports that were filed with the NRC up until August 2004 and with the DRC subsequent thereto. Between 1979 and 1997, the Mill monitored up to 20 constituents in up to 13 wells. That program was changed to the Points of Compliance Program in 1997 because NRC had concluded that: • The Mill and tailings system had produced no impacts to the perched zone or deep aquifer; and • The most dependable indicators of water quality and potential cell failure were considered to be chloride, nickel, potassium and natural uranium. 2.9.1.2 Issuance ofthe Permit On March 8, 2005, the Director issued the Permit, which includes a groundwater monitoring program that superseded and replaced the groundwater monitoring requirements set out in Mill License Condition 11.3A. Condition 11.3A has since been removed from the Mill License. Groundwater monitoring under the Permit commenced in March 2005, the results of which are included in the Mill's Quarterly Groundwater Monitoring Reports that are filed with the Director. On September 1, 2009, DenisonEFRI filed a Groundwater Discharge Permit Renewal Application. A1 Lhe reque ·t of [he DirecLOr of the Utah Di i ion f adiati n nlrol. ~RI 46 ubmitted an updated version of the enr .mber I,_ 0 rene a! applic Lion n July 13.2012. At the request of the Director of the Utah Div.U·jon of Radiation ControL EFRI is submittin!! this updaLed r. ion f t.he Julv 2012 r newal application.This document is afl: amendment and ~-e--e:f.-tfle-Refl~·.-al Af.)VIi~~ in being subn'litted at rhe reques1 ef the Director. The Permit remains in timely renewal status awaiting completion of review of the Renewal Application by the Director. 2.9.1.3 Current Ground Water Monitoring Program at the Mill Under the Permit The current groundwater monitoring program at the Mill under the Permit, which is used to determine ground water flow direction, and-gradient, and quality of the ground water at the compliance monitoring points-. hi. pro.,ram consists of monitoring at 25 point of compliance monitoring wells: MW-1, MW-2, MW-3, MW-3A, MW-5, MW-11, MW-12, MW-14, MW-15, MW-17,MW-18,MW-19,MW-23,MW-24,MW-25,MW-26,MW-27,MW-28,MW-29,MW- 30, MW-31, MW-32, MW-35, MW-36, and MW-37. The locations of these wells are indicated on Figure 410. Depth to water is measured quarterly in MW-34, but due to limited water is not sampled for POC compliance. MW-33 is completely dry and is not sampled for POC compliance. Part I.E.l.( d) of the Permit requires that each point of compliance well must be sampled for the constituents listed in Table 2.9.1.3-1. Further, Part I.E.l.( d) 1) of the Permit, requires that, in addition to pH, the following field parameters must also be monitored: • Depth to groundwater • Temperature _• _Specific conductance, • Redox potential C"Eh") and that, in addition to chloride and sulfate, the following general organics must also be monitored: • Carbonate, bicarbonate, sodium, potassium, magnesium, calcium, and total anions and cations. Sample frequency depends on the speed of ground-water flow in the vicinity of each well. Parts I.E.1 (b) and (c) provide that quarterly monitoring is required for all wells where local groundwater average linear velocity has been found by the Director to be equal to or greater than 10 feet/year, and semi-annual monitoring is required where the local groundwater average linear velocity has been found by the Director to be less than 10 feet/year. Based on these criteria, quarterly monitoring is required at MW-11, MW-14, MW-25, MW-26 and MW-30, and MW-31, and semi-annual monitoring is required at MW-1, MW-2, MW-3, MW-3A, MW-5, MW-12, MW-15, MW-17, MW-18, MW-19, MW-23, MW-24, MW-27, MW- 28, MW -29 and MW -32. 47 Prior to the February 15 .. 2011 revision of the GWDP, DeHisoHEFRI collected quarterly groundwater samples from MW-20 and MW-22 for development of background v lues and potential GWCLs. Part I.E.l.c).3) in the currently approved July 201lAugu ·t _4, 2012 revision of the GWDP now requires that MW-20 and MW-22 be monitored on a semi-annual basis as "General Monitoring Wells," but they are not subject to GWCLs. 2.9.1.4 Groundwater Flow Direction and Gradient Part I.E.3 of the Permit requires that, on a quarterly basis and at the same frequency as groundwater monitoring required by Part I.E.1 and described in Section 2.9.1.3 above, the Mill shall measure depth to groundwater in the following wells and/or piezometers: i) The point of compliance wells identified in Table 2 of the Permit, as described in Section 2.9.1.3 above; j) Piezometers-:-P-1, P-2, P-3, P-4 and P-5; k) Existing monitoring wells-:-MW-20, MW-22, and MW-34; 1) Contaminant investigation wells-:-_-_ any well required by the Director as a part of a contaminant investigation or groundwater corrective action (at this time this includes atl-lhe chloroform and nitrate investigation wells); and m) Any other wells or piezometers required by the Director. While it is not a requirement of the GWDP, DeHisoHEFRI also measures depth to water in the DR piezometers which were installed during the Southwest Hydrogeologic Investigation. As-a result of these measuremeHts, tihe Mill u e. these measurements to prepare-s groundwater isocontour maps each quarter that sbow the groundwater flow direction and gradient. The isocontour map for the first quarter of ~ 2014 i attached as Figure 5. 2.9.1.5 Background Quality at the Site A significant amount of historic groundwater quality data had been collected by DeHisoHEFRI and previous operators of the Mill for ~some wells at the facility. In some cases these data extend back more than 30 years to September 1979. A brief summary of some of the various studies that had been performed prior to the original issuance of the Permit is set out in Section 2.0 of the Regional Background Report. 48 However, at the time of original issuance of the Permit, the Director had not yet completed an evaluation of the historic data, particularly with regard to data quality, and quality assurance issues. Such an examination needed to include such things as justification of any zero concentration values reported, adequacy of minimum detection limits provided (particularly with respect to the corresponding GWQS), adequacy of laboratory and analytical methods used, consistency of laboratory units or reporting, internal consistency between specific and composite types of analysis (e.g., major ions and TDS), identification and justification of concentration outliers, and implications of concentration trends (both temporal and spatial). As discussed in Section 2.11.2 below, the Director also noted several groundwater quality issues that needed to be resolved prior to a determination of background groundwater quality at the site. These were: 1) a number of constituents exceeded their respective GWQS (including nitrate in one well and manganese, selenium and uranium eaeft-in several wells); 2) long term trends in uranium in downgradient wells MW-14, MW-15 and MW-17; and 3) a spatial high of uranium in those three downgradient wells. See pages 5-8 of the 2004 Statement of Basis for a more detailed discussion of these points. As a result of the foregoing, the Director required that the Background Reports be prepared to address and resolve these issues. Further, because background groundwater quality at the Mill site had not yet been approved at the time of original Permit issuance, the Director was not able to determine if any contaminant is naturally occurring and therefore detectable or undetectable for purpose of selecting GWCLs in each well. Consequently, the Director initially assigned GWCLs as if they were "undetectable" (i.e., assuming that all natural background concentrations were less than a fraction of the respective GWQS). As discussed in Section 1.3 above and 2.11.2 below, DeHisoHEFRI submitted the Background Reports to the Director. Both the Existing Well Background Report and the New Well Background Report provided GWCLs for all of the constituents in the existing wells and new wells, respectively, based on a statistical intra-well approach. The Director has approved the Background Reports. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells and the nine new wells based primarily on the analysis performed in the Background Reports. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. 2.9.1.6 Quality of Ground Water at the Compliance Monitoring Point There are over 30 years of data for some constituents in some wells at the site, but not for all constituents iH aHy wells. However, with the exception of tin, which was added as a monitoring constituent in 2007, all currently required monitoring constituents have been sampled in all-the 49 wells that were in existence on the date of the original issuance of the Permit commencing with the first quarter of 2005. Further, all constituents in aH-the new compliance monitoring wells have been sampled upon installation of those wells, commencing either in the second or third quarters of 2005. All of tbeThe analytical results from this sampling are reported quarterly in Groundwater Monitoring Reports, which are filed with the Director pursuant to Part LF.l of the Permit. 2.9.2 Installation, Use and Maintenance of Monitoring Devices Compliance monitoring at the Mill site is accomplished in three ways: the compliance well monitoring program; monitoring the leak detection moni !oring system in Cells 4A and 4B; and various DMT monitoring requirements. Each of these are discussed below. 2.9.2.1 Compliance Well Monitoring Compliance for tailings Cells 1, 2 and 3 and the remainder of the Mill site, other than Cells 4A and 4B, is accomplished by quarterly or semi-annual sampling of the network of compliance monitoring wells at the site. See Figure 104 for a map that shows the compliance monitoring well locations, and Section 2. 9 .1.3 for a description of the monitoring program. 2.9.2.2 Leak Detection System in Cell 4A and Cell4B With the recotl5t:fl:l€fi.en of Cell 4A, BAT was required, as mandated in Part LD.4 of the Permit and as stipulated by UAC R317-6-6.4(a) for the reconstruction of Cell4A and the construction of Cell 4B . Because tailings Cells 1, 2 and 3 were constructed more than 25 years ago, and after review of the existing design and construction, the Director determined that DMT rather than BAT is required for Cells 1, 2 and 3 (see the discussion in Section 2.7.2 above). BAT for Cell4A and Cell4B included the construction of a modern leak detection system. See Section~ 2.7.3 and 2.7.4 above for a description of the key design elements of Cell 4A and d L 4B te pecti ely, inclu Ling ·i-ffi-thei r leak detection. sy tem.§.. With BAT for Cell 4A nd II 4 , there are new performance standards in the Permit that require daily leak detection system monitoring, weekly wastewater level monitoring, and slimes drain recovery head monitoring. The BAT monitoring results are required to be reported and summarized in the Routine DMT and BAT Performance Standard Monitoring Reports. See Section§. 2.15.3 and 2.15.4 below for a more detailed discussion of the BAT monitoring requirements for Cell 4A and II 48 respectively. Because Cell 4A and Cell 4B has-have a-modern leak detection system= that meets BAT "tandard and ffi-.~monitored daily the leak dete tion y te ...: in Cell 4A..:<::;:;tn..,d:....==-.....:.=. considered to be a point of compliance monitoring device§.. 2.9.23 Let~!c DeteetitJn System in CeU 4/J ~EIHired for CeiJ ~B . e. aAeloled in Parl I.DA of the Pennlt and as Slipulated by UAC R317 6 6.4(a). 50 See-Section 2.7A a~or 1:1 description of lbe l~ey Elesi"fl elemenl:fj of Cell fB .i:ncluding it!, .J.eaJi-c~-ieft--sy&~;em. Perfonmmce standard!; for Cell 4:8 jn lhe Permil req1:1ire elai ly leak del:ection sysleffi ffiOflitorjng, '+'+1eek:ly ""'astewA:~~e>fe~-H'*ffl·~~riFig ana slimes dmin recovery head meftitoriag. The BAT monitoring resell!; are required lobe reported &Ad smnmacizecl in lhe ~ tffie DMT aRd-BAT Performance StaA€1-~ffit.efi·ng Repoi"t-s-:---See 8eelfeR ~.15.4 below for a more deHi:Hed diieli!,Sioa of U1e 131\T moflii:Oring reEJUiremeeb ffit· Cell 4B. Beca;~se CeU 4B hEt:l a·tnodem-leak-det·et.;>{ffln sys~em that-meetn BAT sla:ndard~-efeEI Eht:ily, lhe leak detection system iA CeU 48 can be considered ~o be a point of eomplianee monitoring device. 2.9.2.4J.. Other DMT Monitoring Requirements In addition to the foregoing, the additional DMT performance standard monitoring discussed in detail in Section 2.15 below is required to be performed under the Permit 2.9.3 Description of the Compliance Monitoring Area Defined by the Compliance Monitoring Points The compliance monitoring area at the site is the area covered by the groundwater compliance monitoring wells. Figure 4-10 shows the mest-current locations of the compliance groundwater monitoring wells at the site. At the time of original Permit issuance, the Director reviewed the then recent water table contour maps of the perched aquifer. Those maps identified a significant western component to groundwater flow at the Mill site, which the Director concluded appeared to be the result of wildlife pond seepage and groundwater mounding (see page 23 of the 2004 Statement of Basis). As a consequence, new groundwater monitoring wells were required, particularly along the western margin of the tailings cells, in addition to the monitoring wells already in existence at that time. The Director also concluded that new wells were also needed for DMT purposes and to provide discrete monitoring of each tailings cell. This resulted in the addition of the following compliance monitoring wells to the then existing monitoring well network: MW-23, MW-24, MW-25, MW-26 (which was then existing chloroform investigation well TW4-15), MW-27, MW-28, MW-29, MW-30, MW-31 MW-32 (which was then existing chloroform investigation well TW4-17), MW-35, MW-36, and MW-37. As previously stated MW-33, and MW-34 were installed but are not currently sampled due to limited water and saturated thickness. MW-20 and MW -22 are not POC wells but are general monitoring wells and are sampled semiannually for information purposes only. Based on groundwater flow direction and velocity, the compliance monitoring network, with the foregoing additional new wells, was considered to be adequate for compliance monitoring in the perched aquifer at the site. Further, as mentioned in Section 2.9.2.2 and 2.9.2.3 above, the leak detection systems in Cell4A and 4B can also be considered to be compliance monitoring areas for these cells. 51 2.9.4 Monitoring of the Vadose Zone Monitoring is not performed in the vadose zone at the site.,-tmd Lhere are .ao curret1L inlen~ perform ooy fulure moAitoring in the vttdese zoAe at the site. 2.9.5 Measures to Prevent Ground Water Contamination After the Cessation of Operation, Including Post-Operational Monitoring 2.9.5.1 Measures to Prevent Ground Water Contamination After the Cessation of Operation Please see Section 2.19 below for a detailed discussion of the measures to prevent ground-water contamination after the cessation of operations. 2.9.5.2 Post-Operational Monitoring Groundwater monitoring will continue during the post-operational phase through final closure until the Permit is terminated. DenisonEFRI understands that the final closure will take place and the Permit will be terminated upon termination of the Mill License and transfer of the reclaimed tailings cells to the United States Department of Energy pursuant to U.S.C. 2113. See Section 2.19 .1.1 below. 2.9.6 Monitoring Well Construction and Ground Water Sampling Which Conform Where Applicable to Specified Guidance 2.9.6.1 Monitoring Well Construction a) New Wells All new compliance monitoring wells installed after the original issuance of the Permit were installed in accordance with the requirements of Part I.E.4 of the Permit. Part I.E.4 requires that all-new groundwater monitoring wells installed at the facility Malt-comply with the following design and construction criteria: a) Located as close as practical to the contamination source, tailings cell, or other potential origin of groundwater pollution; b) Screened and completed in the shallow aquifer; c) Designed and constructed in compliance with UAC R317-6-6.3(I)(6), including the EPA RCRA Ground Water Monitoring Technical Enforcement Guidance Document, 1986, OSWER-9950.1 (the "EPA RCRA TEGD"); and d) Aquifer tested to determine local hydraulic properties, including but not limited to hydraulic conductivity. As-built reports for all new groundwater monitoring wells were submitted to the Director for his approval, in accordance with Part I.F.6 of the Permit. Part I.F.6 requires those reports to include the following information: 52 a) Geologic logs that detail all soil and rock lithologies and physical properties of all subsurface materials encountered during drilling. Said logs were prepared by a Professional Geologist licensed by the State of Utah or otherwise approved beforehand by the Director ; b) A well completion diagram that details all physical attributes of the well construction, including: 1) Total depth and diameters of boring; 2) Depth, type, diameter, and physical properties of well casing and screen, including well screen slot size; 3) Depth intervals, type and physical properties of annular filterpack and seal materials used; 4) Design, type, diameter, and construction of protective surface casing; and 5) Survey coordinates prepared by a State of Utah licensed engineer or land surveyor, including horizontal coordinates and elevation of water level measuring point, as measured to the nearest 0.01 foot; and c) Aquifer permeability data, including field data, data analysis, and interpretation of slug test, aquifer pump test or other hydraulic analysis to determine local aquifer hydraulic conductivity in each well. Between April and June 2005, DeRisoREFRI installed wells MW-23, MW-24, MW-25, MW-27, MW-28, MW-29, MW-30, and MW-31. On August 23, 2005, DeRisoREFRI submitted a Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill April through June 2005 Report, prepared by Hydro Geo Chern, Inc., that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. Between August 30 and September 2, 2010, DeRisoREFRI installed wells MW-33, MW-34, and MW-35. On October 11, 2010, DeRisoREFRI submitted Installation and Hydraulic Testing of Perched Monitoring Wells MW-33, MW-34, and MW-35 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. _During the week of April 25, 2011, DeRisoREFRI installed wells MW-36, and MW-37. On June 28, 2011, DenisonEFRI submitted Installation and Hydraulic Testing of Perched Monitoring Wells MW-36, and MW-37 at the White Mesa Uranium Mill Near Blanding Utah, prepared by Hydro Geo Chern, Inc. that documented how these wells had been installed in accordance with requirements of the Permit. A copy of that Report was previously submitted under separate cover. b) Existing Wells The Existing Wells, MW-1, MW-2, MW-5, MW-11, MW-12, MW-14, MW-15, MW-17, MW- 18, MW-19, MW-26 and MW-32 as well as wells MW-16, MW-20 and MW-22, which are not compliance monitoring wells, and piezometers P-1, P-2, P-3, P-4 and P-5, were all constructed and installed prior to original issuance of the Permit. Some of those wells date back to 1979. During several site visits and four split groundwater sampling events between May 1999 and the date of original issuance of the Permit, and a review of available as built information, DRC staff 53 noted the need for remedial construction, maintenance, or reprur at several of these wells, including: (i) (ii) 16 of the ex1stmg monitoring wells failed to produce clear groundwater in conformance with the EPA RCRA TEGD, apparently due to incomplete well development. Consequently, the Permit required that MW-5, MW-11, MW-18, MW-19, MW-26, TW4-16, and MW-32 be developed to ensure that groundwater clarity conforms to the EPA RCRA TEGD to the extent reasonably achievable; The Permit required the Mill to install protective steel surface casings to protect the exposed PVC well and piezometer casings for piezometers P-1, P-2, P-3, P-4, and P-5 and wells MW-26 and MW-32; and (iii) A. Several problems were observed with the construction of MW-3, including: A review of the MW -3 well as-built diagram showed that no geologic log was provided at the time of well installation. Consequently, the Director was not able to ascertain if the screened interval was adequately located across the base of the shallow aquifer; B. c. D. MW-3 was constructed without any filter media or sand pack across the screened interval; An excessively long casing sump (a 9 or 10 foot long non-perforated section of well casing), was constructed at the bottom of the well; and The well screen appeared to be poorly positioned, based on the low productivity of the well, aa€1--(there is no geologic log to verify proper positioning}. As a resul~he Permit, requin~el Denison lo verify the def»J:\. ~e lhe up~er contact f ffie fum;hy BL1:1in Member of the MorriSOFI Foimalion in the imme4·ftt:e 'licinity of 'Neil 'MVl 3. Tiie Permit aloo LeqH:ireEl-t.buL :in the tn·enl thul lhe Direcler determ.ifted he well sefPen has been i naee~t•ately q1nstrueted the Mm shall relrefil, recanslfucr or replace moaitoriag well M'N 3. The Mill developed the wells as required and installed the protective casings required. The Director concluded that DeaisoaEFRI had fulfilled the requirements and sent DeaisoaEFRI a Closeout Letter on August 5, 2008. With respect to the concerns raised about MW-3, the Mill installed MW-3A approximately 10 feet southeast of MW -3, in order to verify the depth to the upper contact of the Brushy Basin Member of the Morrison Formation (the "UCBM"). After installation, the Director reviewed the geologic log for MW -3 and the as-built reports for both MW -3 and MW -3A and concluded that the well screen for MW-3A is 2.5 feet below the UCBM and the well screen for MW-3 is 4.5 feet above the UCBM. Therefore MW-3 is a partially penetrating well; whereas MW-3A is fully penetrating. The Director concluded that semiannual sampling must continue in both wells until sufficient data is available and the DRC can make a conclusion regarding the effects of partial well penetration and screen length. As a result, the GWDP was modified to require that MW-3A be completed with a permanent surface well completion according to EPA RCRA TEGD. EFRI c mpl led MW-3A as required, and on Augu . I 5, 200 t.h R · ·e.nr EFRI a lose ul Leucr. Both MW-3 and MW-3A are currently sampled semiannually. 54 Denisol'l coRTf*~·ed; BAd Oft Aogt1st 5 2008 l.fte DRC seM-"9eAisoA a Closeout Letter. Subsequent to original Permit issuance, on January 6, 2006, DRC staff performed an inspection of the compliance groundwater monitoring wells at the Mill. During the inspection, well MW -5 was found to have a broken PVC surface casing. The repair of MW-5 was added to the Permit compliance schedule to require the Mill to repair the broken PVC casing to meet the requirements of the Permit. The Permit required DeeisoeEFRI to submit an As-Built report for the repairs of monitoring well MW-5 on or before May 1, 2008. DeeisoeEFRI submitted the required report, and on August 5, 2008 the DRC sent DeeisoeEFRI a Closeout Letter. The groundwater monitoring program at the Mill has historically had numerous wells with elevated turbidity, turbidity levels which could not stabilize to within 10% Relative Percent Difference (10% RPD) or both. Identification of equipment problems and improvements to field sampling practices did not result in improvements to measured turbidities. Ongoing turbidity issues were the result of monitoring requirements which were most likely ill-suited to the site geology. It is suspected that many wells at the Mill might not be capable of attaining a turbidity of 5 NTU due to the natural conditions in the formation hosting the perched monitoring wells (the Burro Canyon Formation and Dakota Sandstone). Clay interbeds occur in both the Burro Canyon Formation and Dakota Sandstone, and friable materials occur within the Burro Canyon Formation. Saturated clays and friable materials will likely continue to be mobilized using standard purging techniques currently in use for the sampling program at the Mill. Mobilized kaolinite (a cementing material within the formation) is expected to be an additional continuing source of turbidity in perched wells. DeeisoeEFRI discussed the turbidity issues with DRC, and Bfld, despite the facl that Lhe available evideA£e tlemoAst::ri:tl:e<llhalltlfl:lidity i:JS~:~es are caused by the formatioe, Deeisoe agreed to complete a redevelopment program for the appropriate selected wells at the Mill in a "good-faith" effort to .reduce the turbiditv level. Surging, bailing, and overpumping were determined to be the preferred well development techniques. The rationale for u ing urging and bailing followed by overpumping i cousi te nt with U.S. Environment.al Protection Agency t EPA:.,) guidance and guidance provided in other techni.cal paper and publications. Select, nonpumping, chloroform, nitrate and groundwater POC, wells were redeveloped during the period from fall2010 to spring 2011 by surging and bailing followed by overpumping. The results of the redevelopment are provided in the Report entitled:_Redevelopment of Existing Perched Monitoring Wells White Mesa Uranium Mill, Near Blanding Utah, prepared by Hydro Geo Chern, Inc. September 30, 2011 (the "Redevelopment Report"). The Redevelopment Report provides a qualitative description of turbidity behavior before and after redevelopment and provides a number of conclusions and recommendations. A copy of the Redevelopment Report was previously submitted under separate cover. The Redevelopment Report is curreetly -uftEiefwas review by lhe Dii:eclorclosed out by the Direclor in a letter d· ted No mber J 5. 2012. The closeout denied EFRI recommendations. However. due t other moclili ation L lbe 55 As described above, aH-the existing wells have been reviewed by the Director, and repairs, modifications, retrofits, etc. have been made as required to conform those wells to the requirements of Part I.E.4 of the Permit, to the extent reasonably practicable. 2.9.6.2 Ground Water Sampling Ground water sampling is performed in accordance with the requirements of Part I.E.5 of the Permit, which requires that all monitoring shall be conducted in conformance with the following procedures: a) Grab samples shall be taken of the groundwater, only after adequate removal or purging of standing water within the well casing has been performed; b) All sampling shall be conducted to ensure collection of representative samples, and reliability and validity of groundwater monitoring data. All groundwater sampling shall be conducted in accordance with the currently approved Groundwater Monitoring Quality Assurance Plan; c) All analyses shall be performed by a laboratory certified by the State of Utah to perform the tests required; d) If any monitor well is damaged or is otherwise rendered inadequate for its intended purpose, DenisonEFRI shall notify the Director in writing within five days of the discovery; and e) Immediately prior to each monitoring event, DenisonEFRI shall calibrate all field monitoring equipment in accordance with the respective manufacturer's procedures and guidelines. DenisonEFRI shall make and preserve on-site written records of such equipment calibration in accordance with Part II.G and H of the Permit. Said records shall identify the manufacturer's and model number of each piece of field equipment used and calibration. In accordance with the requirements of Part I.E.1(a) of the Permit, ii-1+-groundwater sampling at the Mill is performed in accordance with the White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) (the "QAP"), which has been approved by the Director. The QAP complies with UAC R317-6-6.3(1) and (L) and by reference incorporates the relevant requirements of the Handbook of Suggested Practices for Design and Installation of Ground-Water Monitoring Wells (EP A/600/4-89/034, March 1991 ), ASTM Standards on Ground Water and Vadose Investigations (1996), Practical Guide for Ground Water Sampling EPA/600/2-851104, (November 1985) and RCRA Ground Water Monitoring Technical Enforcement Guidance Document ( 1986), unless otherwise specified or approved by the Director ~r virtue-e-10-fti&-ttppro-.-ing the QAP. A copy of the current version of the QAP, Date: 6- 06-12 Revi ion 7.2 i inCluded a Appendix HK. 2.9.7 Description and Justification of Parameters to be Monitored The groundwater parameters to be monitored are described in Table 2.9.1.3-1. The process of selecting the groundwater quality monitoring parameters for the original Permit included examination of several technical factors. EacA. of tA.ese is discussedThese factors are listed 56 below and discussed in detail in Section 4 on pages 9-19 of the 2004 Statement of Basi ·.:...;--ttRti iaclude the followiag: a) The number and types of contaminants that might occur m feedstock materials processed at the Mill; b) Mill process reagents as a source of contaminants; c) Source term abundance in the Mill's tailings cell solutions, based on l-imited historic wastewater quality sampling and analysis that had been done at the Mill's tailings cells; and d) A consideration of contaminant mobility in a groundwater environment, based on site specific ~ information where available and lowest ~ values in the literature where site specific ~ information is not available. Please--se~I_'Hlges 9 19 of th~04 8tutemeAt of Ba:;is feF-·a-more detailed dif;cuS!'ien a~ · ·J.Fttioa Mtljustifiealion of J3a:rameteffi te-be atOflil:efefi.:. One additional parameter, tin, was added to the list of groundwater monitoring constituents in 2007. Tin was not originally a required groundwater monitoring parameter in the Permit, and was omitted from the original Permit due to non-detectable concentrations reported by DeaisoaEFRI in three tailings leachate samples (2004 Statement of Basis, Table 5). With the addition of the alternate feed material from Fansteel Inc., tin was expected to eJ(perieace aa estimated _!Q_increase from 9 to 248 tons in the tailings inventory-.ffem 9 lO 24 8 tow.,. The Director concluded that, with an estimated ~ of 2.5 to 5, tin is not as mobile in the groundwater environment as other metals; however, with the high-acid ic conditions in the tailings wastewater, tin could stay in solution and not partition on aquifer materials. As a result, tin was added as a monitoring constituent to Table 2 of the Permit. 2.9.8 Quality Assurance and Control Provisions for Monitoring Data Part I.E.l (d) of the Permit sets out some special conditions for groundwater monitoring. Under those conditions, the Mill must ensure that all groundwater monitoring conducted and reported complies with the following: a) Depth to groundwater measurements shall always be made to the nearest 0.01 foot; b) All groundwater quality analyses reported shall have a minimum detection limit or reporting limit that is less than its respective GWCL concentration defined in Table 2 of the Permit; and c) aAll gross alpha analysis reported with an activity equal to or greater than the GWCL shall have a counting variance that is equal to or less than 20% of the reported activity concentration. An error term may be greater than 20% of the reported activity concentration when the sum of the activity concentration and error term is less than or equal to the GWCL. As mentioned in Section 2.9.6.2 above, Part I.E.l(a) of the Permit requires that all groundwater sampling shall be conducted in accordance with the currently approved QAP. The detailed quality assurance and control provisions for monitoring data are set out in the QAP, a copy of which is attached as Appendix H-K to this Application. 57 2.10 Plans and Specifications Relating to Construction, Modification, and Operation of Discharge Systems (R317 -6-6.3.J) As discussed in Section 2. 7.1 above, the Mill has been designed as a facility that does not discharge to groundwater or surface water. All-tiailings and other wastes associated with Mill operations are designed to be permanently disposed of in the Mill's tailings cells. The Mill's tailings cells can therefore be considered the Mill's discharge system in that they permanently dispose contain sf-discharges from the Mill's process circuits and all other Mill tailings and wastes. The following plans and specifications and as built reports relating to tailings Cells 1, 2, 3, 4A and 4B are referenced in this Application and were previously submitted on the dates noted below under separate cover: a. Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah, June 1979, prepared by D' Appolonia Consulting Engineers, Inc.; b. Engineer's Report: Second Phase Design -Cell 3 Tailings Management System, White Mesa Uranium Project Blanding, Utah, May 1981, prepared by D' Appolonia Consulting Engineers, Inc.; c. Construction Report: Initial Phase -Tailings Management System, White Mesa Uranium Project Blanding, Utah, February 1982, prepared by D' Appolonia Consulting Engineers, Inc.; d. Construction Report: Second Phase Tailings Management System, White Mesa Uranium Project, March 1983, prepared by Energy Fuels Nuclear, Inc.; e. Cell 4 Design, White Mesa Project Blanding, Utah, April 10, 1989, prepared by Umetco Minerals Corporation; f. Construction Report: Tailings Cell 4A, White Mesa Uranium Mill -Tailings Management System, August 2000, prepared by DenisonEFRI (then named International Uranium (USA) Corporation); g. Cell 4A Lining System Design Report For The White Mesa Mill Blanding, Utah, January 2006, prepared by GeoSyntec Consultants; and h. Cell4A Construction Quality Assurance Report, White Mesa Mill Blanding, Utah, July 2008 prepared by Geosyntec consultants (disk only). 1. Cell4B Design Report, White Mesa Mill, Blanding, Utah, December 8, 2007, prepared by Geosyntec Consultants j. Cell 4B Construction Quality Assurance Report, Volumes 1-3, November 2010, prepared by Geosyntec Consultants 2.11 Description of the Ground Water Most Likely to be Affected by the Discharge (R317 -6-6.3.K) 2.11.1 General The ground water most likely to be affected by a potential discharge from Mill activities is the perched aquifer. The deep confined aquifer under White Mesa is found in the Entrada and underlying Navajo Sandstones, is hydraulically isolated from the perched aquifer, and is therefore extremely 58 unlikely to be affected by any such potential discharges. The top of the Entrada Sandstone at the site is found at a depth of approximately 1,200 feet below land surface (see the discussion in Sections 2.5.1.1 and 2.5.1.2 above). This deep aquifer is hydraulically isolated from the shallow perched aquifer by at l~ast two shale members of the Morrison Formation, including the Brushy Ba in (approximately 295 feet thick) and the Recapture (approximately 120 feet thick) Members. Other fermaliions ge I gic unit! are al o found between the perched and deep confined aquifers, Lbat ftlfte-include many layers of th.i.n hale interbeds that contribute to hydraulic isolation of these two 1!1' ·undwater ·ystem , incJ udittg: the Morrison Formation Westwater eCanyon (approximately 60 feet thick), and Salt Wash (approximately 105 feet thick) Members, and the Summerville Formation (approximately 100 feet thick). Artesian groundwater conditions found in the deep Entrada/Navajo Sandstone aquifer also reinforce this concept of hydraulic isolation from the shallow perched system. See the discussion on page 2 of the 2004 Statement of Basis. 2.11.2 Background Ground Water Quality in the Perched Aquifer This Section describes the groundwater quality in the perched aquifer. See Sections 2.5.1.3, 2.5.1.4 and 2.5.1.5 above for a more detailed description of the perched aquifer itself, the depth to ground water, the saturated thickness, flow direction, porosity, hydraulic conductivity and flow system characteristics of the perched aquifer. As mentioned in Section 2.9.1.5 above, a significant amount of historic groundwater quality data had been collected by DenisonEFRI and previous operators of the Mill for many wells at the facility. However, at the time of original issuance of the Permit, the Director had not yet completed an evaluation of the historic data, particularly with regard to data quality, and quality assurance issues. The Director also noted several groundwater quality issues that needed to be resolved prior to a determination of background groundwater quality at the site, such as a number of constituents that exceeded their respective GWQS and long term trends in uranium in downgradient wells MW -14, MW -15 and MW -17, and a spatial high of uranium in those three downgradient wells. As a result of the foregoing, the Director required that the Existing Well Background Report be prepared to address and resolve these issues. DUSA prepared the Existing Well Background Report that evaluated all historic data for the thirteen existing wells for the purposes of establishing background groundwater quality at the site and developing groundwater compliance limits GWCLs under the GWDP. Prior to review and acceptance of the conclusions in the Existing Well Background Report, the GWCLs were set on an interim basis in the GWDP. The interim limits were established as fractions of the state GWQSs for drinking water, depending on the quality of water in each monitoring well at the site. The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the thirteen existing wells based primarily on the analysis performed in the Existing Well background Report. It should be noted, however, that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily 59 represent impacts to groundwater from Mill operations. As required by the Permit, the Existing Well Background Report addressed all available historic data, which includes pre-operational and operational data, for the compliance monitoring wells under the Permit that were in existence at the date of issuance of the Permit. The Regional Background Report focuses on all-the pre-operational site data and all-the available regional data to develop the best available set of background data that could not conceivably have been influenced by Mill operations. The New Well Background Report, which was required by the Permit, analyzed the data collected from the new wells, which were installed in 2005, to determine background concentrations for constituents listed in the Permit for each new well. The purpose of the Existing Well Background Report and the New Well Background Report was- were prepared to satisfy several objectives-:--'-fifstFirst, in the case of the Existing Well Background Report, to perform a quality assurance evaluation and data validation of the existing and historical on-site groundwater quality data in accordance with the requirements of the Permit, and to develop a database consisting of historical groundwater monitoring data for "existing" wells and constituents. Second, in the case of the New Well Background Report, to compile a database consisting of monitoring results for new wells, which were collected subsequent to issuance of the Permit, in accordance with the Mill's QAP data quality objectives. Third, to perform a statistical, temporal and spatial evaluation of the existing well and new well data bases to determine if there have been any impacts to groundwater from Mill activities. Since the Mill is an existing facility that has been in operation since 1980, such an analysis of historic groundwater monitoring data was required in order to ensure verify that the monitoring results to be used to determine background groundwater quality at the site and GWCLs have not been impacted by Mill activities. Finally, since the analysis demonstrategs that groundwater has not been impacted by Mill activities, to develop a GWCL for each constituent in each well. The Regional Background Report was prepared as a supplement to the Existing Well Background Report to provide further support to the conclusion that Mill activities have not impacted groundwater. In evaluating the historic data for the existing wells, INTERA used the following approach: • If historic data for a constituent in a well do not demonstrate a statistically significant upward trend, then the proposed GWCL for that constituent is accepted as representative of background, regardless of whether or not the proposed GWCL exceeds the GWQS for that constituent. This is because the monitoring results for the constituent can be considered to have been consistently representative since commencement of Mill activities or installation of the well; and • If historic data for a constituent in a monitoring well represent a statistically significant upward trend or downward trend in the case of pH, then the data is further evaluated to 60 determine whether the trend is the result of natural causes or Mill activities. If it is concluded that the trend results from natural causes, then the GWCL proposed in the Existing Well Background Report will be appropriate. After applying the foregoing approach, INTERA concluded that, other than some detected chloroform and related organic contamination at the Mill site, which is the subject of a separate investigation and remedial action, and that is the result of pre-Mill activities, and some elevated nitrate concentrations in certain wells which were considered to be associated with the chloroform plume, there have been no impacts to groundwater from Mill activities (See Section 2.16.1 below relating to the chloroform contamination and Section 2.16.2 relating to the nitrate contamination). In reaching this conclusion, INTERA noted that, even though there are a number of increasing trends in various constituents at the site, none of the trends are caused by Mill activities, for the following reasons: • Chloride ~ U::llEJtlestieatH*y-the best iadicalor parumeter, and tl:lefe are Ae sigRificafl!- trends in chloride in any of the v;ells; • There are no noteworthy correlations between chloride and uranium in wells with increasing trends in uranium, other than in upgradient wells MW-19 and MW-18, which INTERA concluded are not related to any potential tailings seepage. INTERA noted that it is inconceivable to have an increasing trend in any other parameter caused by seepage from the Mill tailings without a corresponding increase in chloride; • There are significant increasing trends upgradient in MW-1, MW-18 or MW-19 in uranium, sulfate, TDS iron, selenium, thallium, ammonia and fluoride and far downgradient in MW-3 in uranium and selenium, sulfate, TDS and pH (decreasing trend). INTERA concluded that this provides very strong evidence that natural forces at the site are causing increasing trends in these constituents (decreasing in pH) in other wells and supports the conclusion that natural forces are also causing increasing trends in other constituents as well; and • On a review of the spatial distribution of constituents, it is quite apparent that the constituents of concern are dispersed across the site and not located in any systematic manner that would suggest a tailings plume. INTERA concluded that, after extensive analysis of the data, and given the conclusion that there have been no impacts to groundwater from Mill activities, the GWCLs set out in Table 16 of the Existing Well Background Report are appropriate, and are indicative of background ground water quality. INTERA did advise, however, that proposed GWCLs for all the trending constituents should be re-evaluated upon Permit renewal to determine if they are still appropriate at the time of renewal. See Table 16 of the Existing Well Background Report for INTERA's calculation of background ground water quality as represented by the proposed GWCLs. See Section 6.0 of the Existing Well Background Report for a discussion of the statistical manner used to calculate each proposed GWCL. 61 In evaluating the new well data, INTERA used the same approach in the New Well Background Report that was used in the Existing Well Background Report for existing well data. In addition, INTERA compared the groundwater monitoring results for the new wells to the results for the existing wells analyzed in the Existing Well Background Report and to the pre-operational and regional results analyzed in the Regional Background Report. This was particularly important for the new wells because there is no historic data for any constituents in those wells that geesgating back to commencement of Mill operations. A long-term trend in a constituent may not be evident from the available data for the new wells. By comparing the means concentrations of fer-the constituents in the new wells to the results for the existing wells and regional background data, INTERA was able to determine if the constituent concentrations ef in the new wells are-were consistent with background at the site. INTERA concluded that after applying the foregoing approach, there have been no impacts to groundwater in the new monitoring wells from Mill activities. INTERA concluded that the groundwater monitoring results for the new wells are consistent with the results for the existing wells analyzed in the Existing Well Background Report and for the pre-operational and regional wells, seeps and springs analyzed in the Regional Background Report. INTERA noted that there were some detections of chloroform and related organic contamination and degradation products and nitrate and nitrite in the new wells, which are now the subject of two separate investigations (see Sections 2.16.1 and 2.16.2), but that such contamination was the result of pre-Mill activities. M-a-res til of the foregoifln the Director required leat Lhe New WeU Backgrounel Report be prepared lo address end resolve lhes · ues. DUSi\ prepared the New Well BuckNound Repe11 ~l~al e\'tHuated al l hisl'offi:Hiotu for the Rine new welb fer lRe pt'lfJ*7SCS of e::;tablisloling biwlcgrouad 62 gro~:tndv+'lller quRiiLy at 11'\e site a:Ad de¥elepieg G\VCLs tlAder lRe GW9P. Prior to re-view--ai*i a€eeJ*a~e-e(*l€.1u:;ion!< in the New--WeH Bat:k"rol:lfl&-Report, !he G\VCL; 11vere 5iel ee ttn imerim basis jn the GWDP . The jnle.fi.ffl-limits were estai:Htshe<l ns frRclions of the stule G\VQSs for driA~ Jffig-en rl=te quttJily of 'NUter in eacll moffiwring well aH-A~ The University of Utah Study confirmed INTERA's conclusions in the Background Reports that groundwater at the site has not been impacted by Mill operations (see the discussion in Section 1.3 above). The January 20, 2010 GWDP established GWCLs that reflect background groundwater quality for the nine new wells based primarily on the analysis performed during the New Well Background Report. It should be noted, however, that, because the GWCLs have beenwere set at the mean plus second two standard deviation§., or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. Part I.G.2 of the Permit provides that out-of-compliance status exists when the concentration of a pollutant in two consecutive samples from a compliance monitoring point exceeds a GWCL in Table 2 of the Permit. Per the requirements of Part I.G.4(c) of the Permit, DenisonEFRI is required to prepare and submit written plans and time schedules, for Director approval, to fully comply with the requirements of Part I.G.4(c) of the Permit relating to any such out-of- compliance situation, including, but not limited to: (i) submittal of a written assessment of the source(s); (ii) submittal of a written evaluation of the extent and potential dispersion of said groundwater contamination; and (iii) submittal of a written evaluation of any and all potential remedial actions to restore and maintain ground water quality at the facility, for the point of compliance wells and contaminants in question, to ensure that: 1) shallow groundwater quality at the facility will be restored and 2) the contaminant concentrations in said point of compliance wells will be returned to and maintained in compliance with their respective GWCLs. +we-ven p,flan and tTjme·. _cheduJe, and i ource A c m nt Rep 1t: (' AR '') have been submitted to address consecutive exceedances other than pH which have been noted in wells since the establishment of the GWCLs in the January 20, 2010 GWDP. The Plans and tiime -s.S,chedules and the SARs are included in Table 2.11.2-1 the Initial Plan and Schedule and lhe Q2 20 I I Plan and Schedule--te--addres:,~ anruy her !has pl:I in oul of compilanee sttltus. Those plans were submitted June 13, and September 7, 2011, respecti•1ely. Time chedules and 'ARs were pr iously ·ubmitted under parate over. !J!hose plan•; will-be irflfJJemenled COACLlHent ·.vilh Lhe pH inveSU 0 illiOA described belO'iiV aOO ~cribea is the pH pion and Time sc hedule submiued ro l:heDireclor Ofl: i\pfil l3 2012. The plans were pre-viow,ly submittee 1::1mler separale 63 Sub ·cgoent Plan and Tim appr 'ed bv the Director in letters to EFRI. The submission dates and the associated DRC approval dates of the Plans and Time Schedules and the associated SARs are listed on Table 2.11.2-1. Given the varied background groundwater quality at the site, previously identified rising trends in some wells and other factors, it cannot be assumed that consecutive exceedances of a constituent in a monitoring well means that contamination has been introduced to groundwater in that well. The exceedances may very well be the result of background influences. The approach in these Plans therefore is to first determine if the recent exceedances are the result of background influences. If they are determined to be the result of background influences, then no remedial actions are required. If, however, they are determined to not be the result of natural background influences, then further analyses will be required. Based on the information available at this time, DeHisoHEFRI believes that the GWCL exceedances observed are the result of natural influences and reflect the need to adjust some of the GWCLs for the site. During the completion of the 4th Quarter 201 0 Quarterly Groundw ter Monitoring Report, ~R noted eleven perched groundwater monitoring well · with pH mea urements below the· GWCLs. The e weLl s are located upgradient cro -g1:adient, and -downgradient of the Mill and tailings cells. Investigation into the eleven pH GWCLs in question indicated that the GWCLs for groundwater pH in all wells established in the January 20, 2010 GWDP were erroneously based on historic laboratory results instead of field measurements as contemplated by Table 2 of the GWDP. DenisonEFRI notified DRC that the existing GWCLs for groundwater pH were incorrectly based on laboratory results rather than field measurements and proposed to submit revised descriptive statistics for field pH to be used as revised pH GWCLs by the end of the second quarter 20 11. DeHisoHEFRI received approval from DRC to proceed with the revision of the pH GWCLs based on field measurements. The data processing and statistical assessments necessary to revise the GWCLs based on historic field pH data were completed. The data processing and statistical assessments completed were based on the DRC-approved methods in the logic flow diagram included as Figure 17 of the New Well Background Report. Following the statistical evaluation of pH data, ~en-.. .;RJ compared the Mill's groundwater pH data from the 2nd Quarter of 2011, including accelerated sampling results through June 2011, and noted that all of the June 2011 groundwater results, and many of the other results from the 2nd Quarter, were already outside the revised GWCLs to be proposed based on the logic flow diagram. 64 It was noted that the historical trend of decreasing pH, which was addressed in the Background Study Reports, appeared to be present in nearly all wells throughout the Mill site area, including upgradient, downgradient, and cross-gradient wells in the groundwater monitoring program. As of June 2011, all groundwater monitoring wells demonstrated a downward trend in the field pH data over time. DenisonEFRI notified DRC that the 2nd Quarter 2011 data exceeded the recalculated GWCLs. DenisonEFRI advised DRC that, as a result of these findings, DenisonEFRI did not believe it was appropriate to continue with its efforts to reset the GWCLs for pH based on field pH data, as originally planned, but instead it appeared that it would be more appropriate to undertake a study to determine whether the decreasing trends in pH are due to natural influences and, if so, to determine a more appropriate way to determine GWCLs. DenisonEFRI and DRC htwe-agreed on further investigations to be completed, as well as the steps and milestone dates to be incorporated into a pH PlanReport. The procedures for in e~ · 2aling in ,•esUgation law the decreasing site-wide pH trends is documented in the Plan to Investigate pH Exceedances in Perched Groundwater Monitoring Wells White Mesa Uranium Mill Blanding, Utah, Prepared by Hydro Geo Chern, Inc, April 13, 2012 (the "pH Plan and Time Sche ule ). The pH Plan ur d Time S he lule de ribe~g lhe pH inve ·tigation.:. hich \Va incorp rated int fo pursuant to the July 12, 2012a Stipulated Consent Agreement referred to above. The pH Plan and Time Sch du [e was previously submitted under separate cover. The pH Report consists of a statistical and geochemical evaluation of the decline in pH in groundwater wells at the Mill. The primary conclusion from the pH Report was that the historical trend of decreasing pH, which was addressed in the Background Study Reports, appears to be present in nearly all wells throughout the Mill site area, including upgradient, downgradient, and crossgradient wells in the groundwater monitoring program, and there seems to be no abatement of the trend. The wide-spread nature of the decrease in pH in upgradient, downgradient, and crossgradient wells suggests that the pH decreases result from a natural phenomenon unrelated to Mill operations, which is also confirmed by the indicator parameter analysis conducted as part of the pH Report. As discussed in The Pyrite Report, the most likely cause of declining pH across the site appears at this time to be the oxidation of pyrite, possibly due to increasing water levels at the site attributed primarily to recharge of wildlife ponds and/or the introduction of oxygen into the perched water zone as a result of increased groundwater sampling frequency. Based on the conclusion that the pH trend was caused by natural phenomenon, the pH Report recalculated the Groundwater Compliance Limits ("GWCLs") for all compliance monitoring wells at the site. 65 The Pyrite Report evaluated and quantified the presence of pyrite throughout the Mill site, and identified and quantified the mechanism by which it contributes to the sitewide decline in pH. The results of the investigation support pyrite oxidation as the most likely mechanism to explain decreases in pH and increases in sulfate concentrations in site wells and indicates that pyrite must be considered in assessing perched water chemistry in the future. The complex interaction of the various naturally occurring factors identified at the site, including the presence of pyrite at varying concentrations, variable oxygen transport, and variable carbonate species concentrations, is expected to result in relatively large background variations in pH, sulfate (and therefore TDS) concentrations, as well as variations in background concentrations of pH sensitive analytes such as metals. The expected impact of these various factors on pH and analyte concentrations, all of which are unrelated to Mill operations, is generally consistent with site analytical results, suggesting that pyrite oxidation plays a significant role in perched water chemistry at the site. The primary conclusion from the activities conducted to date and de c.:ribed u e is that the pH tr nd · are not due t p t nlial tailine:' I aktt e r Mill a li ilit: . but to~~ · dee reasiftg-fJH, ~"Nhich was addressed ifl the Bac~m:J Repert:; uppeurs to b~e:tll in netwly ttll well·; throBglloul the Mill si~e arei:i, ineli:Kliee upgru.dieet downgrudienl, aB£1 cros!:>gratl-ioo~ wells in the groundwater moaiteriAg pregram aAd there seef!'ls te be no aeatemenl or tB:e trena. Tfie wide spread eature of the decrease ie pH ie upgradieBt, dm.vegradieet aed erossgradieet wells, suggests that the pH decrease results from a natural phenomenon unrelated to Mill operations. ln an effort to ~ni ·b anv i{ lflese lrends thal may have re ul ted in whole or in part from increasing water levels attributed to the Wildlife ponds at the Mill, DenisonEFRI ha& committed to stopdiscontinued recharging the two most northern of these ponds, commencing in March 2012. 2.11 .~ Quality of Ground Water at the Compliance Monitoring Point -A-~The analytical results from groundwater sampling are reported quarterly in Groundwater Monitoring Reports, which are filed with the Director pursuant to Part I.F.l of the Permit. 2.12 Compliance Sampling Plan (R317-6-6.3.L) The Mill's plan for sampling groundwater compliance monitoring points is discussed in detail in Section 2.9.1.3 above, and the plan for sampling the leak detection systems in Cells 4A and 4B is discussed in Section 2.15.3 below. This 8ectioe section 2.12 will addresses other sampling required under the Permit. As the Mill is designed not to discharge to ground-water, there are no flow monitoring requirements in the Permit. 2.12.1 Tailings Cell Wastewater Quality Sampling Plan Part I.E.l 0 of the Permit requires that, on an annual basis, DeeisoBEFRI ml¥.Tf-collect wastewater quality samples from each wastewater source at each tailings cell at the facility, including \ a. l wat -r in urface impoundeEim nt ' wastewaters, and , lime drai n~ 'tVEt~ilewalers. All such The sampling reust beis conducted in August of each calendar year in compliance with an approved plan. The Tailings SAP (dated No-..'ereber 21, 2008July 30. 2012) was approved by the Director on March 3, 2009Acum t 2, 2012. A copy of the approved Tailings and Slimes Drain 66 Sampling Program, Revision Qil, No¥ember 2Q, 2QQ8July 30, 2012 is attached as Appendix H II h' A 1' 0 A f 11" 0 • T'\An;~ A B ·~ ~ R: 0 0 J l l ' A 0 _'tl..J_lo t IS pp 1catwn. ns o H:IS wntmg, ~oAas so mHeevl:::.lOf\ _ . w ue •s l:lfldergoiHg review by the Director. The purpose of the Tailings SAP is to characterize the source term quality of all tailings cell wastewaters, including impounded wastewaters or process waters in the tailings cells, and wastewater or leachates collected by internal slimes drains. The Revision Qil,_Tailings SAP requires: • Collection of samples from the pond area of each active cell and the slimes drain of each cell that has commenced de-watering activities; • Samples of tailings and slimes drain material will be analyzed at an offsite contract laboratory and subjected to the analytical parameters included in Table 2 of the Permit and general inorganics listed in Part I.E.1(d)(2)(ii) of the Permit, as well as semi-volatile organic compounds; • A detailed description of all sampling methods and sample preservation techniques to be employed; • The procedures utilized to conduct these analyses will be standard analytical methods utilized for groundwater sampling and as shown in Section 8.2 of the QAP; • The contracted laboratory will be certified by the State of Utah in accordance with UAC R317-6-6.12A; and • 30-day advance notice of each annual sampling event must be given, to allow the Director to collect split samples of all tailings cell wastewater sources. The tailings and slimes drain sampling events '<vill beare subject to the currently approved QAP, unless otherwise specifically modified by the Tailings SAP to meet the specific needs of this type of . ampling. T he QAP ha been approved by th Director and ·ati fie. th e rno L ~~roprmle L ppli abl-requirement of the fo llewing references tmle therwi. e pecified by lhe Director through his approval of the Tailings SAP: • Standard Methods for the Examination of Water and Wastewater, twentieth edition, 1998; Library of Congress catalogue number: ISBN: 0-87553-235-7; • E.P.A. Methods for Chemical Analysis of Water and Wastes, 1983; Stock Number EPA- 600/4-79-020; • Techniques of Water Resource Investigations of the U.S. Geological Survey, (1998); Book 9; • Monitoring requirements in 40 CFR parts 141 and 142, 2000 ed., Primary Drinking Water Regulations and 40 CFR parts 264 and 270, 2000 ed.; and • National Handbook of Recommended Methods for Water-Data Acquisition, GSA-GS edition; Book 85 AD-2777, U.S. Government Printing Office Stock Number 024-001- 03489-1. +Ae-anreetly approved Tailings SAP is a~ed 1.0 rhis Application. As previausly stated, DeAisan has su9miUed Revision 2.1 ·.vhieh i'i m;dergoing rSJf'iew by th~ r. 67 2.12.2 White Mesa Seeps and Springs SampJing Plan The initial Permit required DeeisonEFRI to submit a plan for groundwater sampling and analysis of all seeps and springs ("SSSP") found downgradient or Jalenl:l cross gradient from the tailings cells for Director review and approval. The Director approved the plan on e&-March 17, 2009. A copy of the Sampling Plan for Seeps and Springs in the Vicinity of the White Mesa Uranium Mill, Revision: Ql, March 17, 2009June 10, 2011, is attached as Appendix B-~to this Application. A · of tl1i. writing ~on has-stl-Bmiued Revisi n 1.0~1-flt-efl of this SAP i undergoing review by the Director. Under the 888PSeeps and Springs SAP, seeps and springs sampling will beis conducted on an annual basis between May 1 and July 15 of each year, to the extent sufficient water is available for sampling, at six identified seeps and springs near the Mill. The sampling locations were selected to correspond with those seeps and springs sampled for the initial Mill site characterization performed in the 1978 ER, plus additional sites located by DenisonEFRI, the United States Bureau of Land Management and Ute Mountain Ute Indian Tribe representatives. Samples will beare analyzed for all ground-water monitoring parameters found in Table 2 of the Permit. The laboratory procedures utilized to conduct the analyses of parameters listed in Table 2 will be thoseare the same as utilized for groundwater sampling and as shown in Section 8.2 of the QAP. In addition to these laboratory parameters, the pH, temperature and conductivity of each ample will be mea. qred and rec rded in the field: Laboratorie selected by ~I to perform analyse of :eeps and spdng ample .,.•ill hear requi red Lo be certified by U1e tate of Utah in accordance with UAC R317-6-6.12.A. The seeps and springs sampling events will beare subject to the currently approved QAP, unless otherwise specifically modified by the S8SfL ecp. and pri ngs AP to meet the specific needs of this type of sampling. The QAP has been approved by the Director and satisfies the mest appropriateapplicable requirements of the references listed in Section 2.12.1 above, unless otherwise specified by the Director through his approval of the 888PSeeps and Springs SAP. P!eane:-see the atrached cop:; of the SSSP f~ delttils. 2.12.3 Monitoring of Deep Wells Due to the fact that the deep confined aquifer at the site is hydraulically isolated from the shallow perched aquifer (see the discussion in Section 2.11.1 above) tie-monitoring of the deep aquifer is not required under the Permit. 2.13 Description of the Flooding Potential of the Discharge Site (R317 -6-6.3.M) 2.13.1 Surface Water Characteristics As discussed above, tThe Mill site is located on White Mesa, a gently sloping (1% SSW) plateau that is physically defined by the adjacent drainages which have cut deeply into regional sandstone formations. There is a small drainage area of approximately 62 acres (25 ha) above the site that could yield surface runoff to the site. Runoff from the mesa is conveyed by the general surface topography to either Westwater Creek, Corral Creek, or to the south into an 68 unnamed branch of Cottonwood Wash. Local porous soil conditions, topography and low average annual rainfall of 13.3 inches (reported as 11.8 by Dames and Moore in historic reports) cause these streams to be intermittently active, responding to spring snowmelt and local rainstorms (particularly thunderstorms). Surface runoff from approximately 624 acres of the Mill drains westward and is collected by Westwater Creek, and runoff from another 384 acres drains east into Corral Creek. The remaining 4,500 acres of the southern and southwestern portions of the site drain indirectly into Cottonwood Wash (1978 ER, p. 2-143). The site and vicinity drainages carry water only on an intermittent basis. The major drainages in the vicinity of the Mill are depicted in Figure 12 and their drainage areas are tabulated in Table 2.13 .1-1. Total runoff from the mesa (total yield per watershed area) is estimated to be less than 0.5 inch annually (1978 ER, p. 2-143). There are no perennial surface waters on or in the vicinity of the Mill site. This is due to the getJtle lope of the me a on which the site i located, the low average annual rainfall of 13.3 tfe1eeF"i:e-d as 1 L.8 by Dames and Moore in l1i~1eri c rep !$f-inches per year at Blanding, local soil charac~eri lie and tbc p.orou nature of local :tream channels. Prior to Mill construction, three ~mall ephemeral cat h ba ins were presenl oe the :;ite to the northwest and northeast of the Mill site. Corral Creek is an intermittent tributary to Recapture Creek. The drainage area of that portion of Corral Creek above and including drainage from the eastern portion of the site is about 5 square miles. Westwater Creek is also an intermittent tributary of Cottonwood Wash. The Westwater Creek drainage basin covers nearly 27 square miles at its confluence with Cottonwood Wash 1.5 miles west of the Mill site. Both Recapture Creek and Cottonwood Wash are similarly intermittently active, although they carry water more often and for longer periods of time due to their larger watershed areas. They both drain to the south and are tributaries of the San Juan River. The confluences of Recapture Creek and Cottonwood Wash with the San Juan River are approximately 18 miles south of the Mill site. The San Juan River, a major tributary for the upper Colorado River, has a drainage of 23,000 square miles measured at the USGS gauge to the west of Bluff, Utah (1978 ER, p. 2-130). Storm runoff in these streams is characterized by a rapid rise in flow rates, followed by rapid recession primarily due to the small storage capacity of the surface soils in the area. For example, on August 1, 1968, a flow of 20,500 cubic feet per second was recorded in Cottonwood Wash near Blanding. The average flow for that day, however, was only 4,340 cfs. By August 4, the flow had returned to 16 cfs (1978 ER, p. 2-135). Monthly streamflow summaries as updated from Figure 2.4 of the FES are presented in Figure 13 for Cottonwood Wash, Recapture Creek and Spring Creek. Flow data are not available for the two smaller water courses closest to the Mill site, Corral Creek and Westwater Creek, because these streams carry water infrequently and only in response to local heavy rainfall and snowmelt, which occurs primarily in the months of April, August, and October. Flow typically ceases in Corral Creek and Westwater Creek within 6 to 48 hours after precipitation or snowmelt ends. 2.13.2 Flood Protection Measures As mentioned above, tihe Mill was designed and constructed to prevent runon or runoff of storm water by a) diverting runoff from precipitation on the Mill site to the tailings cells; and b) 69 diverting runoff from surrounding areas away from the Mill site via three drainage ditches that have been constructed north (upslope) of the Mill facility. See Lhe UMETCO 44i·lero 19 Co··po··at;3'l' '·\14:le Weso ·'1 il ' Drcjncgt· '?"·n··• ftr Su 1Jwi1'9 1 '() ... . " , • ~ , , n , . , , , J 1.-r • • , , ., 'T· , ~ r If .. • , • , • • NRC, JanuaTy 1990, ~]'--ek¥fl.k:>.ft-fte EHlpaAies this Af713J.i.ettties , for aA more detailed description of the flooding potential of the site, including the 6-hour probable maximum precipitation (which is more conservative than the 100-year flood plain), and applicable flood protection measures '· pro icled in Lhe UM!::.7CO Minerals Corporation: Whju~ Mest1 Mill Drainage Reporr fo r ubmiftal to NRC, Jam arv 1990. In addition to the foregoing designed control features, the facility has developed a Stonnwater Best Management Practices Control Plan which includes a description of the site drainage features and the best management practices employed to ensure appropriate control and routing of stormwater. A copy of the Mill's Stormwater Best Management Practices Plan is included as Appendix F-G to this Application. 2.14 Contingency Plan (R317-6-6.3.N) As required by Part I.H.15 of the Permit, the Mill currently has a Contingency Plan for regaining and maintaining compliance with the Permit limits and for re-establishing best available technology as defined in the Permit. A copy of the most current approved version of the Mill's Contingency Plan is included as Appendix J-M to this Application. 2.15 Methods and Procedures for Inspections of the Facility Operations and for Detecting Failure of the System (R317-6-6.3.0) Part I.D. of the Permit sets out a number ofDMT and BAT standards that must be followed. Part I.E. of the Permit sets out the Ground Water Compliance and Technology Performance Monitoring requirements, to ensure that the DMT and BAT standards are met. These provisions of the Permit, along with the DMT Plan, Cell 4A GJtd Cell 4B BAT Monitoring Operations and Maintenance Plan and other plans and programs developed pursuant to these Parts, set out the methods and procedures for inspections of the facility operations and for detecting failure of the system. In addition to the programs discussed above, the following additional DMT and BAT performance standards and associated monitoring are required under Parts I.D and I.E. of the Permit 2.15.1 Existing Tailings Cell Operation Part I.D.2 of the Permit provides that authorized operation and maximum disposal capacity in each of the existing tailings Cells, 1, 2 and 3 shall not exceed the levels authorized by the Mill License and that under no circumstances shall the freeboard be less than three feet, as measured from the top of the FML. Part I.E.7(a) of the Permit requires that the wastewater pool elevations in Cells 1 and 3 must be monitored weekly to ensure compliance with the maximum wastewater elevation criteria mandated by Condition 10.3 of the Mill License. Howe er, leuer from the Director dated January 27, 2011, which approved the use of Cell 4B, and a subsequent letter dated March 14, 2011, stated that authorization of the use of Cell 4B an aQpr val of the DMT 70 Part I.D.2 further provides that any modifications by DeaisoaEFRI to any approved engineering design parameter at these existing tailings cells requires prior Director approval, modification of the Permit and issuance of a construction permit. 2.15.2 Existing Facility DMT Performance Standards Part I.D.3 of the Permit requires DeaisonEFRI to operate and maintain certain Mill site facilities and the existing tailings disposal cells to minimize the potential for wastewater release to groundwater and the environment, including, but not limited to the following additional DMT measures: 2.15.2.1 DMT Monitoring Wells at Cells 1, 2 and 3 Parts I.D.3 (a) and (d) require that at all times DeaisonEFRI flffiSt-operate and maintain Cells 1, 2 and 3 to prevent groundwater quality conditions in any nearby monitoring wells from exceeding the GWCLs in Table 2 of the Permit. This is moaitored for detecting failure of the system tlu ougl<l tThe ground-water com..pHance m nit01j ng program d~ cribcd in detail in Section 2.9.1.3. is designed to provide early detection of a svstern failure in these tailings cells. above. 2.15.2.2 Slimes Drain Monitoring Part I.D.3(b)(l) of the Permit requires that DenisonEFRI mu-st-at all times maintain the average wastewater head in the slimes drain access pipe to be as low as reasonably achievable (ALARA) in each tailings disposal cell, in accordance with the approved DMT Plan. Compliance will beis achieved when the average annual wastewater recovery elevation in the slimes drain access pipe, determined pursuant to the currently approved DMT Plan .. meets the conditions in Equation 1of specified in Part I.D.3(b)(3) of the Permit. Part I.E.7(b) of the Permit requires that Deaison,EFRI fffiiSf-monitor and record quarterly the depth to wastewater in the slimes drain access pipes as described in the currently approved DMT Plan at Cell 2, and upon commencement of de-watering activities, at Cell 3, in order to ensure compliance with Part I.D.3(b)(3) of the Permit. At thi · li me. le-wa1erin., f ·II h . not commenced. 71 The GWDP was amended in July 20 l 1 to 'ha ngc the frequ -ncy of Lbe ·limes drain te ling fr m m nthly to guarler.ly. The averal!e urmua l a ·t· · lt:r re-cove ry elevation jn th ~l ime · drain pipe has been in compliance (that is. less than lh previous vear's running average) since the m ni l ring fregueo y changed Jrom monthly to quarterly in July 201 L 2.15.2.3 Maximum Tailings Waste Solids Elevation Part I.D.3(c) of the Permit requires that upon closure of any tailings cell, DenisonEFRI must ensure that the maximum elevation of the tailings waste solids does not exceed the top of the FML liner. 2.15.2.4 Wastewater Elevation in Roberts Pond Part I.D.3(e) of the Permit requires that Roberts Pond be operated so as to provide a minimum 2- foot freeboard at all times, and that under no circumstances will the water level in the pond exceed an elevation of 5,624 feet above mean sea level. Part I.D.3(e) also provides that in the event the wastewater elevation exceeds this maximum level, DenisonEFRI must remove the excess wastewater and place it into containment in Cell 1 within 72 hours of discovery. Part I.E.7(c) of the Permit requires that the wastewater level in Roberts Pond must be monitored and recorded weekly, in accordance with the currently approved DMT Plan, to determine compliance with the DMT operations standard in Part I.D.3(e) of the Permit; 2.15.2.5 Inspection of Feedstock Storage Area Part I.D.3(f) of the Permit requires that open-air or bulk storage of all feedstock materials at the Mill facility awaiting Mill processing must be limited to the eastern portion of the Mill site (the "ore pad") described by the coordinates set out in that Part of the Permit, and that storage of feedstock materials at the facility out ide of. this defined area mu t meet the requirements of Part I.D.ll of the Permit. Part I.D.ll require !:hal Deffi5eftEFRT fFH:tSl:--L t re and manage feedstock materials outside the defined ore storage pad in accordance with an approved Feedstock Management Plan. On June 20, 2008, Oenisen____Rl submitted a White Mesa Mill Containerized Alternate Feedstock Material Storage Procedure for Director review and approval. A copy of that procedure is included as Appendix ~N__to this Application. The Director is currently reviewing that procedure. Part I.E.7(d) of the Permit requires that DenisonEFRI inspect the feedstock storage areas weekly to: a) Confirm that the bulk feedstock materials are maintained within approved feedstock storage defined by Table 4 of th Permit; and b) Verify that all alternate feedstock materials located outside the feedstock storage area defined in Table 4 are stored in accordance with the requirements found in Part I.D.ll. 72 Part I.E.7(d) further provides that DeaisonEFRI must implement the Feedstock Material Storage Procedure immediately upon Director approval. The Mill's .StaAdard Operuting Preeedure procedure under the Mill License for inspection of the Mill's ore pad is contained in Section 3.3 of the DMT Plan, a copy of which is attached as Appendix G-H to this Application. 2.15.2.6 Monitor and Maintain Inventory of Chemicals Part I.D.3(g) of the Permit requires that for all chel.'llical reageats stored at e,;~dstiag storage facilities aH:d held for Hse ia the l.'llilliag process, DeaisoaEFRI TRttSt-!Q_provide secondary containment to capture and contain all volumes of reagent(s) that might be released at any individual storage area. Tlli: 1 quirement appli ~ L all ch mical reagents "·tored at existing . tora2 fac · 'tie, and h ·ld for u c in the milling proce: . Response to spills, cleanup thereof, and required reporting must comply with the provisions of an approved Emergency Response Plan as found in aH--the approved Storm water Best Management Practices Plan, stipulated by Parts I.D.1 0 and I.D.3(g)_of the Permit. Part I.D.3(g) further provides that for any new construction of reagent storage facilities, such secondary containment and control must prevent any contact of the spilled or otherwise released reagent or product with the ground surface. Part I.E.9 of the Permit requires that DeaisoaEFRI ffiHSt-monitor and maintain a current inventory of all chemicals used at the facility at rates equal to or greater than 100 kg/yr. This inventory TfHffi'~-_i _t_be maintained on-site, and must include: (i) Identification of chemicals used in the milling process and the on-site laboratory; and (ii) Determination of volume and mass of each raw chemical currently held in storage at the facility. A copy of the Mill's chemical Inventory is attached as Appendix b-Q_to this Application. A copy of the Mill's Stormwater Best Management Practices Plan, Revision l.l4; October ~September 2012 is attached as Appendix F-G to this Application. 2.15.3 BAT Performance Standards for Cell 4A 2.15.3.1 BAT Operations and Maintenance Plan Part I.D.6 of the GWDP pro','ides thatrequires DeaisonEFRI fflHSt-!Q_operate and maintain Cell 4A so as to prevent release of wastewater to groundwater and the environment in accordance w'it'h a BAT Operation and Maintenance Plan..:.> as approved by the Direc~or, puPlU61~l to Pilrl 1.1-t 19 of the P-ermit. and that at a minimum . uch plan mu t include t.be fo.Uowin g performance standards: a) The fluid head in the leak detection system shall not exceed 1 foot above the lowest point in the lower membrane liner; b) The leak detection system maximum allowable daily leak rate shall not exceed 24,160 gallons/day; 73 c) After DenisonEFRI initiates pumping conditions in the slimes drain layer in Cell 4A, DenisonEFRI will provide continuous declining fluid heads in the slimes drain layer, in a manner equivalent to the requirements found in Part I.D.3(b) for Cells 2 and 3; and d) Under no circumstances shall the freeboard be less than 3-feet in Cell 4A, as measured from the top of the FML. The BAT Operations and Maintenance Plan required under Part I.H.19I.D.6 was submitted on September 16, 2008 and approved by the Director on September 17, 2008December 21, 2011. A copy of the most currently-approved BAT Operations and Maintenance Plan Revision 2.3 dated :fuly 201 t is included as Appendix B-F to this Application. 2.15.3.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan Part I.E.8 of the Permit provides that, after Director approval of the Tailings Cell 4A BAT Operations and Maintenance Plan, ~t LH .J9 er lhe Permit, DenisOfiEFRI must immediately implement all monitoring and recordkeeping requirements contained in the plan. At a minimum, such BAT monitoring shall include: a) Weekly Leak Detection System (LDS) Monitoring-including: (i) .f) ·, A m.-u:il p~ontinuous operation of the leak detection system pumping and monitoring equipment, including, but not limited to, the submersible pump, pump controller, head monitoring, and flow meter equipment approved by the Director. Failure of any pumping or monitoring equipment not repaired and made fully operational within 24-hours of discovery shall constitute failure of BAT and a violation of the Permit; (ii) Denison HTUst measurem nl f the fluid head above the lowest point on the secondary FML by the use of procedures and equipment approved by the Director. Under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower FML on the cell floor. For purposes of compliance monitoring this 1-foot distance shall equate to 2.28 feet above the leak detection system transducer; (iii) f}eni so n must measurement of the volume of all fluids pumped from the leak detection system. Under no circumstances shall the average daily leak detection system flow volume exceed 24,160 gallons/day; and (iv) Denie•Ofl musl operate aAe-.-mtr~Rktttlopcration and maintenance of wastewater levels to provide a 3-foot Minimum of vertical freeboard in tailings Cell 4A. Such measurements must be made to the nearest 0.1 foot. b) Slimes Drain Recovery Head Monitoring Immediately after the Mill initiates pumping conditions in the Cell 4A slimes drain system, monthly recovery head tests and fluid level measurements '+Vill beare to be made in accordance 74 with the requirements of Parts I.D.3 and I.E.7(b) of the Permit and any plan approved by the Director. 2.15.4 BAT Performance Standards for Cell 4B 2.15.4.1 BAT Operations and Maintenance Plan Part I.D.13 provides requires that DenisonEFRI ffiH'St-!Q_operate and maintain Cell 4B so as to prevent release of wastewater to groundwater and the environment in accordance with a BAT Operations and Maintenance Plan, as approved by lAC Director, pursuaRl lo Part J.H.I9 of lhe PerFH:it, and that at a minimum such plan must include the following performance standards: e) The fluid head in the leak detection system shall not exceed 1 foot above the lowest point in the lower membrane liner; f) The leak detection system maximum allowable daily leak rate shall not exceed 26,145 gallons/day; g) After DenisonEFRI initiates pumping conditions in the slimes drain layer in Cell 4B, DenisonEFRI will provide continuous declining fluid heads in the slimes drain layer, in a manner equivalent to the requirements found in Part I.D.3(b) for Cells 2, 3 and 4A; and h) Under no circumstances shall the freeboard be less than 3-feet in Cell 4B, as measured from the top of the FML. As mentioned above, the BAT Operations and Maintenance Plan~ v1as submitted on September 16, 2008 and approved by the Director on Saf3tembet December l7, 200821. 2 11. A copy of the most currently-approved BAT Operations and Maintenance Plan, Revision 2.3 dated July ::!0 II, is included as Appendix B.E to this Application. 2.15.4.2 Implementation of Monitoring Requirements Under the BAT Operations and Maintenance Plan Part I.E.12 of the Permit provides that DenisonEFRI must implement all monitoring and recordkeeping requirements contained in the Tailings Cell 4B BAT Operations and Maintenance Plan. At a minimum, such BAT monitoring includes: c) Weekly Leak Detection System (LDS) Monitoring-including: (i) Denison must provide continuous operation of the leak detection system pumping and monitoring equipment, including, but not limited to, the submersible pump, pump controller, head monitoring, and flow meter equipment approved by the Director. Failure of any pumping or monitoring equipment not repaired and made fully operational within 24-hours of discovery shall constitute failure of BAT and a violation of the Permit; (ii) Denison must mea ·urem nl of lhe fluid head above the lowe. l poim n the secondary FML by the use of procedures and equipment approved by the Director. Under no circumstance shall fluid head in the leak detection system sump exceed a 1-foot level above the lowest point in the lower FML on the cell 75 floor. For purposes of compliance monitoring this 1-foot distance shall equate to 2.25 feet above the leak detection system transducer; (iii) Denison must measurement of the volume of all fluids pumped from the leak detection system. Under no circumstances shall the average daily leak detection system flow volume exceed 26,145 gallons/day; and (iv) &ellison must operate £md r'Aain~ainop ration an 1 maintenance of -wastewater levels to provide a 3-foot Minimum of vertical freeboard in tailings Cell 4B. Such measurements must be made to the nearest 0.1 foot. d) Slimes Drain Recovery Head Monitoring Immediately after the Mill initiates pumping conditions in the Cell 4B slimes drain system, monthly recovery head tests and fluid level measurements will-are to be made in accordance with the requirements of Patts I.D.3 and I.E.7 (b) of the Permit and any plan approved by the Director. J . .J5.1.J lmpkmenlalie11 tJj'Me11i11JFiRg Requirem~nls Y~rdeFihe llt\1' ().pe(·eliens end Meintell6rt~e PhHt .J2.aft l.E.l2 of the Peru=t:it provffies that. arter Director a~re,.·aL of the Tailings Cell 4B Of!el1ttions and Maintenance Plan Denison musl immediately iFnplemeat all raanitoFing and recordkeeping req1:1irements centrtined in rhef3lmt:--Ai-~1un1, !iuch 'BAT monitoring tdutll iee-~ a) \71/eckly beai~Qe~ction Sy.,~em (:60S) Monitoring iflcludiflg: (i) Denison mus1 pro,· ide eominuo1:1s operaLion of lhe leak del-eefien systeffi flUmpirlg und ffiOiliWring eq~em ind1:1tl:i-agrl3ul not Jimi~ed to, the submersiale pump. j*tmp eoutreller, head moAiloring, and Row--FAeter equif>ment approved by lhe Director. Fai l uflHtf~ . . . ::. . ~nd maae fully epet:ational within "~4 hours of discovery ::;hnll uoo~tilute failu1·e of BAT and a ·iiolatien of the Permit; (ii) Denisoa must measure lhe fluiEI--heu£1 abo•f'e the lowest point on lhe seeondary Mh-9y-t-l:le-'tf~e of procedures and equif*llent approved by the Director. Under no ei remr~shmce bluill [I u iu hencl ifl lfte lenk: deleetioe sysLem su rnp exceed a l feolte'l·el Llbove lhe lowest peffit in the tower FML on the eell..fleor.--For purpO!i · of eompliwwe monitorjno tb:is J fool Eltslaaee sball eql:lale to 2.25 feet abo·re Lke lealc detectiofl Sj'stem traflsducer; Fti) Denit.on mu&t mea:;ure the '<'Oiume of all fluids pumped [rom I:Ae leak deteerion sy.,tem. Unser no circumslancec; !'hall t.Re average daHy leRJt detection :;ysttffil- flov; volume exceed 26,14 5 gallons,lday; and (+¥) Dooi-son musl openne an~tflf:tinraja wastewater levels to~\'ide a 3 foo!- Minim~:~m of "J'erli:c:'J u:eeboard Jn-t:Clili:ags CeH 48. Such measurements musl be made to the nearest 0.1 foot. 76 f) Slimes Drain Recovery Head Monitoring Immediately after the Mill initiates pumping conditions in the Cell 4B slimes drain system, flWA-llliy reeovery head leSLH and fluid J~trements wiU be made in accordanee-wti:IH:fle ~:et:Tteftts of Pnfts I.D.3 ana f.fi.7(b) of lhe Permit and any plae aj:)proved by U1e Direeter. 2.15.5 Stormwater Management and Spill Control Requirements Part I.D.1 0 of the Permit requires that DenisonEFRI will-!Q_manage all contact and non-contact stormwater and control contaminant spills at the facility in accordance with an approved stormwater best management practices plan. Such plan must include the following minimum provisions: a) Protect groundwater quality or other waters of the state by design, construction, and/or active operational measures that meet the requirements of the Ground Water Quality Protection Regulations found in UAC R317 -6-6.3(G) and R317 -6-6.4(C); b) Prevent, control and contain spills of stored reagents or other chemicals at the Mill site; c) Cleanup spills of stored reagents or other chemicals at the Mill site immediately upon discovery; and d) Report reagent spills or other releases at the Mill site to the Director in accordance with UAC 19-5-114. The Mill's Stormwater Best Management Practices Plan dated June 12, 2008, was approved by the Director on July 1, 2008. A copy of the most recently approved Mill's Stormwater Best Management Practices Plan Revision dated 1.24 September 20120ctober 2011, is included as Appendix F--G to this Application. 2.15.6 Tailings and Slimes Drain Sampling Part I.E.1 0 of the Permit requires that on aH annual basis, DenisonEFRI mu-st-to annually collect wastewater quality samples from each wastewater source at each tailings cell at the facility, including surface impounded wastewaters, the leak detection systems (if present) and slimes drain wastewaters. All such sampling must be conducted in August of each calendar year in compliance with the approved :J!i:\i I ing!l Cell-Tailings Sampling Plan. See Section 2.12.1 above for a more detailed description of this program. The Mill's Tailings and Slimes Drain Sampling Program was approved by the Director. The most recently approved version is included as Appendix I-.L_to this Application. As of this wrHing, DenisoA [195 submitted Revisien 2.1 v:hioh is ~=tneergoiag l'eview by tbe Direetor. 2.15.7 Additional Monitoring and Inspections Required Under the Mill License Under r,he Mill Lice11 e daily, weekly, and monthly inspection reporting and monitoring are required ~i n ccordancc with NRC Regulatory Guide 8.31, Information Relevant to Ensuring that Occupational Radiation Exposures at Uranium Recovery Facilities will be As Low As is Reasonable Achievable, Revision 1, May 2002 ("Reg Guide 8.31"), by Section 2.3 of the Mill's 77 ALARA Program and by the Mill's Environmental Protection Manual ("EPM")1.....3 ~ requi rement ru over and above the inspections described above that are required under the Permit. eftisefl-feC-eFH:~l7fl.litted for--Btreetor appro.,.a1. a re•{i:seEJ.Addilional dai ly. week ly. m nlhly. quarterly. and annual insp eli n and rep rting r quirem nt are ~R illcd in lbc EFRl DMT Plan and Tailings Management System Procedure (Section 3.1 of the EPM) to separate the RML 9MT reql::lirements from ~he GWDP DMf re£-Juirtlmenls, into two separate documents. As of this writiag, eelh~Hl:tese plaAs are t:mdergoing revie•.v by the Di:reetor. The DMT Plan and Tailings M<magem nl SysLcm are in ludcd a. Appendix H and Appendix I to this Appli ulion . respectively. 2.15.7.1 Daily Inspections Three types of daily inspections are performed at the Mill under the Mill License: a) Radiation Staff Inspections Paragraph 2.3.1 of Reg. Guide 8.31 provides that the Mill's Radiation Safety Officer ("RSO") or designated health physics technician should conduct a daily walk-through (visual) inspection of all work and storage areas of the Mill to ensure proper implementation of good radiation safety procedures, including good housekeeping that would minimize unnecessary contamination. These inspections are required by Section 2.3.1 of the Mill's ALARA Program, and are documented and on file in the Mill's Radiation Protection Office. b) Operating Foreman Inspections 30 CFR Section 56.18002 of the Mine Safety and Health Administration regulations requires that a competent person designated by the operator must examine each working place at least once each shift for conditions which may adversely affect safety or health. These daily inspections are documented and on file in the Mill's Radiation Protection Office. c) Daily Tailings Inspection Section 3.1 of the Mill's EPM requires that during Mill operation, the Shift Foreman, or other person with the training specified in paragraph 2.4 of the Tailings Management Procedure, designated by the RSO, will perform an inspection of the tailings line and tailings area at least once per shift, paying close attention for potential leaks and to the discharges from the pipelines. Observations by the Inspector are recorded on the appropriate line on the Mill's Daily Inspection Data form. 2.15.7.2 Weekly Inspections Three types of weekly inspections are performed at the Mill under the Mill License: a) Weekly Inspection of the Mill Forms 78 Paragraph 2.3.1 of Reg. Guide 8.31 provides that the RSO and the Mill foreman should, and Section 2.3.2 of the Mill's ALARA Program provides that the RSO and Mill foreman, or their respective designees, shall .. conduct a weekly inspection of all Mill areas to observe general radiation control practices and review required changes in procedures and equipment. Particular attention is to be focused on areas where potential exposures to personnel might exist and in areas of operation or locations where contamination is evident. b) Weekly Ore Storage Pad Inspection Forms Paragraph 3.3 of the DMT Plan and Part I.E.7.(d of the Permit requires that weekly feedstock storage area inspections will-be performed by the Radiation Safety Department, to confirm that the bulk feedstock materials are stored and maintained within the defined area of the ore pad and that all alternate feed materials located outside the defined ore pad area are maintained in accordance with the requirements of the Permit. The results of these inspections are recorded on the Mill's Ore Storage/Sample Plant Weekly Inspection Report. c) Weekly Tailings and DMT Inspection Section 3.1 of the EPM requires that weekly inspections of the tailings area and DMT requirements be performed by the radiation safety department. 2.15.7.3 Monthly Reports Two types of monthly reports are prepared by Mill staff: a) Monthly Radiation Safety Reports At least monthly, ([he RSO reviews the results of daily and weekly inspections, including a review of all monitoring and exposure data for the month .. and provides to the Mill Manager a monthly report containing a written summary of the month's significant worker protection activities (Section 2.3.4 of the ALARA Program). b) Monthly Tailings Inspection Reports Section 3.1 of the EPM, requires that a Monthly Inspection Data form be completed for the monthly tailings inspection. This inspection is typically performed in the fourth week of each month and is in lieu of the weekly tailings inspection for that week. Mill staff also prepares a monthly summary of all daily, weekly, monthly and quarterly tailings inspections. 2.15. 7.4 Quarterly Tailings Inspections Section 3.1 of the EPM requires that the RSO or his designee perform a quarterly tailings inspection. 79 2.15.7.5 Annual Evaluations The following annual evaluations are performed under the Mill License, as set out in Section 3.1 of the EPM. a) Annual Technical Evaluation An annual technical evaluation of the tailings management system must be performed by a registered professional engineer (PE), who has experience and training in the area of geotechnical aspects of retention structures. The technical evaluation includes an on-site inspection of the tailings management system and a thorough review of all tailings records for the past year. The Technical Evaluation also includes a review and summary of the annual movement monitor survey (see Section (b) below). All tailings cells and corresponding dikes are inspected for signs of erosion, subsidence, shrinkage, and seepage. The drainage ditches are inspected to evaluate surface water control structures. In the event tailings capacity evaluations were performed for the receipt of alternate feed material during the year, the capacity evaluation forms and associated calculation sheets will be reviewed to ensure that the maximum tailings capacity estimate is accurate. The amount of tailings added to the system since the last evaluation will also be calculated to determine the estimated capacity at the time of the evaluation. As discussed above, tailings inspection records consist of daily, weekly, monthly, and quarterly tailings inspections. These inspection records are evaluated to determine if any freeboard limits are being approached aDd ro ld ntifv any area. of p tcnlial concern . Records will a-lso be revie\Yed EO sttmtnalize observa~i ons or pol:eatil±l concem. The evaluation also involves discussion with the Environmental and/or Radiation Technician and the RSO regarding activities around the tailings area for the past year. During the annual inspection, photographs of the tailings area are taken. The training of individuals is also reviewed as a part of the Annual Technical Evaluation. The registered engineer obtains copies of selected tailings inspections, along with the monthly and quarterly summaries of observations of concern and the corrective actions taken. These copies are then included in the Annual Technical Evaluation Report. The Annual Technical Evaluation Report must be submitted by September 1st of every year to the Directing Dam Safety Engineer, State of Utah, Natural Resources. b) Annual Movement Monitor Survey A movement monitor survey is conducted by a licensed surveyor annually during the second quarter of each year. The movement monitor survey consists of surveying monitors along dikes 3-S, 4A-W, and 4A-S to detect any possible settlement or movement of the dikes. The data generated from this survey is reviewed and incorporated into the Annual Technical Evaluation Report of the tailings management system. 80 c) Annual Leak Detection Fluid Samples Annually, the leak detection system fluids in Cells 1, 2, 3, 4A and 4B V<'ill beare sampled when present as described in the Tailings Sampling Plan in Section 2.12.1. 2.16 Corrective Action Plan or Identification of Other Response Measures to be Taken to Remedy any Violation of Applicable Ground Water Quality Standards (R317-6-6.3.P) There are two circumstances where applicable groundwater standards have been exceeded at the site that are not associated with natural background: chloroform contamination, and nitrate contamination. As discussed below, none of these circumstances appear to be related to discharges from milling activities. See Section 2.11.2 for a discussion of the current investigation into exceedances of GWCLs for certain constituents and decreasing pH trends at the site, which DenisonEFRI believes are associated with natural background. 2.16.1 Chloroform Investigation In May, 1999, excess chloroform concentrations were discovered in monitoring well MW-4, ffi which is screened in the the shallow perched aquifer along the eastern margin of the Mill site. Because these concentrations were above the GWQS for chloroform, the Executive Secretary of the Utah Water Quality Board initiated enforcement action against the Mill on August 23, 1999 through the issuance of a Groundwater Corrective Action Order (UDEQ Docket No. UG0-20- 01), which required completion of: 1) a contaminant investigation report to define and bound the contaminant plume, and 2) a groundwater corrective action plan to clean it up. Repeated groundwater sampling by both the Mill and DRC have confirmed the presence of chloroform in concentrations that exceed the GWQS along the eastern margin of the site in wells that are upgradient or cross gradient from the tailings cells. Other VOC contaminants and nitrate and nitrite have also been detected in these samples. After installation of 27 new monitoring wells at the site, groundwater studies appear to have defined the boundaries of the chloroform plume. Based on the location of the plume and characterization studies completed to date, the contamination appears to have resulted from the operation of temporary laboratory facilities that were located at the site prior to and during construction of the Mill facility, and septic drainfields that were used for laboratory and sanitary wastes prior to construction of the Mill's tailings cells. Interim measures have been instituted in order to contain the contamination and to pump contaminated groundwater into the Mill's tailings cells. To that end, the Mill has equipped .§-five of the wells (MW-4, TW4-4, MW-26 (previously named TW4-15), TW4-19 and TW4-20) with pumps to recover water impacted by chloroform and to dispose of such water in the Mill's tailings cells. In the 2004 Statement of Basis, DRC noted on page 3 that, while the contaminant investigation and groundwater remediation plan are not yet complete, the DRC believes that additional time is available to resolve these requirements based on the following factors: 1) hydraulic isolation found between the shallow perched aquifer in which the contamination has been detected and the deep confined aquifers which are a source of drinking water in the area, 2) the large horizontal distance and the long groundwater travel times between the existing groundwater contamination on site and the seeps and springs where the shallow aquifer discharges at the edge of White 81 Mesa, and 3) lack of human exposure for these shallow aquifer contaminants along this travel path. MinimiZe-et'--jJFe'l'ent-fH.fi:.Aer dovmgra&ient migration of the c:Riowferm plmne hy a con=tbination of pumping end rel in nee on naluntl aHenuaL:ioa; Prevent ehloroform concentra~ion~-eeeflffio the acfion le\·el froFA FnigraLing soulh or soutlwrest of the tailiags cells; Mooitor te track chaRges in-.eoncentralions •.vithin the f)lume--ftflfi..-t:e-estab!ish whe ther tbe plume boundtt:ries are eKpanding. conEr!:lEH·ing or sk:lhle:- Pro'ride contingenay plans to address poteAtial continued t*pcrasion of the p:tume and the need .f-oHtdGitional monitoring imd/or pumping points; an& Ultitftalely £educe ch::loroform eoncentre~Lions al ull moe:itorie:g 1oonLion:s to Lhe octiun level below. To achieYe !hese objecti~lle proposed CorrclctiYe AeHon Plan J3Foposes a phased ~tpproac+. !J:he tirst plt&.ie consists of £! comb}nution of "eclive and pit5siye .. sl:rategies. The aCii't'e str"~tegy eoasis!s of ret:ao•!':iAg eh-loroform tll~5-ntf-*dly as 19ractiea1 by pwnp~s-t.flttt..ftt:we ~fl a relative bAc;is) both high ehlereferm coAeeAiraL:ioAs, aad high prociLtetivily. Continued tHenitn•ing •.viUU:a aad outside the plume is considere~ of the active slrategy. The pa·;sh·a Slntlegy coosisP.; of relying OA Aflturnl aueountien processes lo refftOYe clilorefonB: m<Hi~ ancl reffi:lee-eaHeefltrn-tion9 . Redtlctions in eontentrttLion:; wo&l&-t1e achieved hy physjcal -processes sucb as volatilization hyElrodyfl:llil'lie dispef£ien, ami abiotic Elegradtuion. i±Bd Lhrough atffiffit-! biological degrndation of ehloroferm. These are essentially rhe same processes thal have eeen relied UflOB ia the iaterim aetioa. ~t-l--i:ttiefl.~teFt-ki--~e€H~-feeUce ehlorofof!ll concentrations vtilh-ifl-H~e entire :Plum HoweYer within upgtadienl poFtiOfl:S o:f lbe plume tfi.al aeeur .HI l1igbeF pern=1eabWty mtueri~:~Js thnt are affteeable te pumping, direct mass removal via pumping ·Nill be the primary meant> to reduce eoneentratioss. In downgradief!l poftioas of lhe plume where permeabilities nre lew, ~ten f'£Hes are lmv , and mass remfWttl-1:1-y pum~ing is A:OL praclica:l because -aehievabJe pumping ruLes wetti-EI be very low na~f:ten will be the-pffiflffi.'j'-ffieaflfr- reduce eoReeRtratioas. The second phetse rel ie:. on naturctl t\ltenual:ioa (witheul pumping) to reduce eltloroform eetlCeftf:ffifiens al:-aJI meAilering locations to acli ofl--1.e¥~ncenlrations duriag Phase 1 are-judged k~l-ffieiently lo'N that Phase1 will be effeuti ·,,e. 82 As patt of the active strategy in the first phase of the Corrective Action Plan, DenisonEFRI has operated a chloroform capture system, referred to as the "Long-term Pump Test" continuously since January 31, 2010. The purpose of the test is to serve as an interim action that will remove a significant amount of chloroform-contaminated water while gathering additional data on hydraulic properties in the area of investigation. Chloroform-contaminated water is captured by pumping six wells located within the identified chloroform plume, and transferred via an above- ground piping network to Tailings Cell 1 for disposal. Effecli en ss of the fir t phas of tbe orrecUve Action i. eva luated and documen ed in quarter:ly report to the Director. DeaisoaEFRI e t.imates that to EltHear of the fir t quarter of -14, ~99 Jb ·. f chl oroform ba e been extrc,tcted thr ll0 b the captu re y tern. 2.16.2 Nitrate Investigation During review of the New Well Background Report and other reports, a Nitrate contaminant plume was identified by DRC staff in five monitoring wells in the Mill site area, including wells: MW-30, MW-31, TW4-22, TW4-24, and TW4-25. TW4-25 is located upgradient of the Mill's tailings cells. Elevated concentrations of chloride also appear to be associated with the nitrate plume. On September 30, 2008, the Director issued a request for a voluntary plan and schedule for DenisonEFRI to investigate and remediate this Nitrate contamination. On November 19, 2008 DenisonEFRI submitted a plan and schedule prepared by INTERA, Inc., which identified a number of potential sources for the contamination, including several potential historic and offsite sources. On January 27, 2009, the Director and DenisonEFRI signed a Stipulated Consent Agreement ("SCA") by which DenisonEFRI agreed to conduct an investigation of the Nitrate contamination, determine the sources of pollution, and submit a report by January 4, 2010. DenisonEFRI submitted a Contaminant Investigation Report ("CIR") on December 30, 2009. On October 5, 2010 the Director issued a Notice of Additional Required Action ("NARA") letter that notified DenisonEFRI of the Director's determination that the 2009 CIR was incomplete. On December 20, 2010 DenisonEFRI and the Director entered into Revision 0 of a Tolling Agreement.. allowing a tolling period until April 30, 2011 in order to provide time for DenisonEFRI to prepare a Plan and Schedule for Director review addressing additional investigations to resolve open issues identified in the October 5, 2010 NARA, and to execute a revised SCA. DenisonEFRI submitted a Plan and Schedule on February 14, 2011 and a revised Plan and Schedule on February 18, 2011. theThe Director provided hls-comments on the revised Plan and Schedule on March 21, 2011. In an April 20, 2011 meeting, DenisonEFRI and the Director agreed that the Plan and Schedule to conduct additional nitrate investigations would be composed of four to five phases of study, including geoprobe drilling and soil sampling/analysis to investigate natural nitrate salt reservoir sources in the vadose zone beyond the Mill site, potential Mill sources, and other potential sources; groundwater sampling and analysis of existing monitoring wells for non-isotopic analytes; deep bedrock core sampling/analysis of 83 possible natural nitrate reservoir and potential nitrate source locations; stable isotopic sampling/analysis of groundwater in existing monitoring wells; and stable isotopic sampling/analysis of soil/core samples, if needed. On April 28, 2011, DeH:isoHEFRI and the Director entered into Revision 1 of the Tolling Agreement to extend the Tolling Period through June 30, 2011 and adopt the agreements made on April 20, 2011. Under the Tolling Agreement Revision 1, DeH:isoHEFRI agreed to submit a Revised Phase 1 (A through C) Work Plan on or before May 6, 2011 and a Revised Phase 2 through 5 Work Plan and Schedule on or before June 3, 2011. DeHisoHEFRI submitted a May 6, 2011 Revised Phase 1 Work Plan and Schedule for the Phase 1 A - C investigation for Director review. DeHisoHEFRI conducted field and laboratory work for the Phase 1 A-C study in May and June, 2011. DeHisoHEFRI submitted a Revised Phase 2 through 5 Work Plan and Schedule for Director review on June , 20 L 1. The Director provided comments on this document on June 23, 2011 and advised eni~on ·FRJ that in order to revise the 2009 SCA to incorporate needed deliverables and timelines, the Phase 2 through 5 Work Plan would need to be expanded to the same level of detail as was provided for Phase 1 in Attachment 1 of the Revision 1 Tolling Agreement. On June 30, 2011, DeH:isoHEFRI and the Director entered into Revision 2 of the Tolling Agreement extending the Tolling Period to August 31, 2011, to facilitate the revision of the Phase 2 through 5 Work Plan to provide the required level of detail to construct a replacement SCA. DeH:isoHEFRI submitted a separate July 1, 2011 detailed Revision 0 of the Work Plan and Quality Assurance Plan ("QAP") for the Phase 2 investigation. The Director provided comments on this document on July 7, 2011. DeHisofiEFRI provided a July 12, 2011 Revision 1.0 to the Phase 2 QAP and Work Plan, which DRC conditionally approved in a letter dated July 18, 2011. On August 1 and 2, 2011 DeHisoHEFRI submitted by email preliminary laboratory results for the Phase 1 A-C study to the Director. On August 4, 2011, DeH:isoHEFRI provided a Revision 1.0 to the Phase 2 - 5 Work Plan for Director review. The Director provided comments on the Phase 2-5 Work Plan, Revision 1.0 and the August 1, 2011 preliminary laboratory results on August 11, 2011. DeHisoHEFRI submitted Revision 2.0 of the Phase 2-5 Work Plan for Director review on August 11, 2011. On August 25, 2011, the Director determined that based on review of the Revision 2.0 Phase 2-5 Work Plan, a finalized Plan and Schedule that meets the satisfaction of the Director, and which would allow the preparation of a replacement SCA, was not possible at that time; and that the development of a replacement SCA for continued contaminant investigation activities was not supported. At a meeting on August 29, 2011, DeHisoHEFRI and DRC agreed that: 1. After more than two years of investigation it has been determined that there are site conditions that make it difficult to determine the source(s) of the contamination at the White Mesa site; 84 2. As a result, resources will be better spent in developing a CAP in accordance with UAC R317-6-6.15(D), rather than continuing with further investigations as to the source(s) of the contamination. In discussions during October 2011, DenisonEFRI and the Director acknowledged that it has not been possible to date to determine the source(s), cause(s), attribution, magnitudes of contribution, and proportion(s) of the local nitrate and chloride in groundwater, and thereby cannot eliminate Mill activities as a potential cause, either in full or in part, of the contamination. As a result, DenisonEFRI and the Director agreed that resources will be better spent in developing a Corrective Action Plan in accordance with UAC R317-6-6.15(D), rather than continuing with further investigations. On October 3, 2011 Denison_BFRI and the Director entered into a revised Stipulated Consent Agreement which required DenisonEFRI to submit a Corrective Action Plan for Director review wh-tel:r-ifl~Sf-+he Following three phaaes l1f acti'l·i~that inclllded plan . t : Phase I --te-determine the physical extent of soil contamination observed at the Ammonium Sulfate Crystal Tanks, and provide a control measure consisting of either removal of the areal extent of contamination down to bedrock, or a Plan and Schedule for covering the areal extent of contamination with at least 6 inches of concrete, followed by removal action during or before site closure. Phase II-to ineludeimplement near term active remediation of the nitrate contamination by pumping contaminated water into the Mill's tailings cells for disposal. This phase is to inclllde development, implementation, operation, and monitoring fer--Q[_a pumping well network to contain and hydraulically control the nitrate plume; monitoring of chloride concentrations; and any required increases to the Mill's surety for activities in this Phase. Phase III -·if necessary, to includcde elop. if nece. ary. a comprehensive long-term solution for the nitrate contamination at the Mill Site. This Phase is to be determined after public participation and Director approval, and may include continuation of Phase I and II activities alone or in combination with any of the following: monitored natural attenuation, additional remediation and monitoring, determination of additional hydrogeologic characterization, contaminant travel times, points of exposure to public or wildlife, risk analysis, cost/benefit analysis, and possible development and petietion of the Board for alternate t£orrective action concentration limits. DenisonEFRI submitted a Draft Corrective Action Plan on November 30, 2011. The Director provided comments on the Draft Corrective Action Plan on January 19, 2012. DenisonEFRI provided Revision 1.0 of the Corrective Action Plan on February 27, 2012, and received comments from the Director on March 19, 2012. Pursuant to the revised SCA, ~ n FRI provided Revision 2.0 to the Director on May 7, 2012. The Director prepared a drAft StiptiiB:IteA Rnd Consent Order Md a £talemefll efBasi!.l on J~ ~ 85 EFRl to fullv irnol ment all elements of the Mav 7, 2012 CAP. 2.17 Other Information Required by the Director (R317-6-6.3.Q) 2.17.1 Chemical Inventory Report Part I.H.1 of the Permit requires that DenisonEFRI complete a historical review and conduct an inventory of all chemical compounds or reagents stored, used, or currently in use at the facility. including th types of chemicals and the total volumes present, and historically used, as data is available. -&etltwnEFRI submitted a chemical inventory report on June 7, 2005, and submitted additional related information on November 17, 2006. Part I.H.1 requires that at the time of Permit renewal, the Permittee shall submit an updated inventory report. Part I.E.9 requires that the -inventory address chemicals used in the milling process and the on-site laboratory. The updated inventory report is provided in Appendix b-Q_of this Application. 2.17.2 Southwest Hydrogeological Investigation Part I.H.6 of the Permit required that DenisonEFRI perform a detailed Southwest Hydrogeologic Investigation to define, demonstrate and characterize: 1) the hydraulic connection and lo al groundwater flow directions between the area near Tailings Cell 4B, and the weslefffl-wcstem margin of White Mesa, and 2) the full physical extent of the unsaturated area between former well MW-16, MW-33 and the western margin of White Mesa. During 2011, DenisonEFRI installed 18 piezometers to demon.stt:ate-define the geologic and physical extent of the apparent unsaturated structural high between Tailings Cell 4B and the western margin of White Mesa, and to demonstrate the location and direction of groundwater flow paths between Tailings Cell 4B and Westwater and Cottonwood Seeps and Ruin Spring. Consistent with Part I.H.6.c) of the Permit, DenisonEFRI submitted an investigation report, the Hydrogeology of the Perched Groundwater Zone in the Area Southwest of the Tailings Cells, White Mesa Uranium Mill Site (the "Southwest Hydrogeology Report"), prepared by Hydro gGeo_ Chern, on January 12, 2012. The Director provided comments in a conference call during May 2012, and in a letter dated May 30, 2012. In an additional conference call following f)effison s receipt of the May 30 let.ffir Denison and lhe Di rector agreed thttl Denison would 86 • repeat slu2 testing of piezometer DR-08. • recal ulate b d.raulic propcrtie. , and • recalculate travel times if necessary based on new data. from No other infon:tUtfiea--has-been t:ipeeiftea.U.y-required by the DireeleF-to be iAeluded 1n IAts AtlPiienLion at this Lime . DeAison wil l provide additioB£11 iAfoffl'HH.ion as ;ecji,•esLed by lhe DH=eetor 2.18 This Application Performed Under the Direction of a Professional Engineer (R317-6-6.3.R) This Application has been performed under the direction, and bears the seal, of Harold R. Roberts, E culive Vice Pre~ident and Chjef Operating Officer ExecutP.•e Vice President. US Operatiorts of DeHisortEFRI. Mr. Roberts is a Registered Professional Engineer in the State of Utah, No. 165838. 2.19 Closure and Post Closure Management Plan Demonstrating Measures to Prevent Ground Water Contamination During the Closure and Post Closure Phases of Operation (R17 -6-6.3.8) 2.19.1 Regulatory Requirements for Uranium MiHs 2.19.1.1 Long Term Custodian One unique feature of the regulatory scheme for uranium mill tailings is that Section 83 of the Atomic Energy Act of 1954, as amended by the Uranium Mill Tailings Radiation Control Act of 1978 ("UMTRCA") (the Atomic Energy Act of 1954 as so amended is referred to herein as the "AEA")4 requires that, prior to license termination, title to uranium mill tailings (11e.(2) byproduct material) must be transferred to the United States Department of Energy ("DOE") or the State in which the activity occurred, if the State so elects, for custody and long term care. 10 CFR 40.28 provides a general license to DOE or the State for that purpose. 2.19.1.2 Responsibility For And Manner Of Clean Up UMTRCA amended the AEA to require that all Title II facilities (i.e., active mills) will-comply with the decontamination, decommissioning, and reclamation standards prescribed by the Commission5 and to require that such facilities post reclamation bonds or surety6. 4 See 42 U.S.C. 2113. 5 See 42 U.S.C. 2113. 6 See 42 U.S.C. 2201. 87 Responsibility for reclamation of Title ll fa ilitiesrests with the licensee. 10 CFR Part 40 Appendix A Criterion 6A requires the adoption of a Director-approved reclamation plan for the site, Criterion 9 requires that financial surety must be established to fund the cost of reclamation in accordance with such plan, and Criterion 10 requires that each licensee include in its financial surety an amount equivalent to $250,000 (1978 dollars) to cover the costs of long-term surveillance by the long-term government custodian (DOE). Criteria 6, 9 and 10 have been incorporated by reference into the Utah rules by UAC R313-24-4. 2.19.1.3 Surface The reclamation plan adopted by the Mill at the outset, as required by 10 CFR Part 40, Appendix A, Criterion 9, flffiSt-addresses the decontamination and decommissioning of the Mill and Mill iLe and reclamali.on of aay-tailing .. ar<m I oth r waste di .. po. al area . As is the case for most uranium mills, the Mill's reclamation plan ~require~ that ... upon closure, all mill buildings, unsalvageable equipment, contaminated soils (impacted by Mill operations within the Mill site itself as well as surrounding areas that may be impacted by windblown radioactive dusts from milling operations) etc. 'fl'lflSt-be deposited in the tailings cells and the tailings cells capped in place. Appendix A, Criterion 6(6) sets the standard for determining when all impacted areas, other than the tailings impoundments have been adequately cleaned up. Criterion 6(6) provides that byproduct material containing concentrations of radionuclides other than radium in soil, and surface activity on remaining structures, must not result in a total effective dose equivalent (TEDE) exceeding the dose from cleanup of radium contaminated soil to the benchmark standard of 5pCi/g concentration of radium in the surface upper 15 em (6 in) of surface soils and 15 pCi/g concentration of radium in the subsurface soils, and must be at levels which are ALARA. If more than one residual radionuclide is present, the sum of the ratios for each radionuclide present will not exceed "1" (unity). Further details on the NRC's approach to evaluating reclamation plans and release criteria for uranium mill sites, including the manner of modeling the release standard set out in Criterion 6(6), are contained in NUREG-1620, Rev 1, Standard Review Plan for the Review of a Reclamation Plan for Mill Tailings Sites Under Title II of the Uranium Mill Tailings Radiation Control Act of 1978, Final Report, June 2003 ("NUREG-1620"). 2.19.1.4 Groundwater Each uranium mill is required to have a groundwater monitoring program. In the case of the Mill, the Permit implements the applicable requirements of U AC R317 -6. If there is groundwater contamination after cessation of operations, the requirements of UAC R317-6.15 must be satisfied. 2.19.1.5 License Termination Section 83.7 of the AEA7 provides that material and land transferred to the long term custodian must be transferred without cost to the long-term custodian other than administrative and legal 7 See 42 U.S.C. 2113. 88 costs incurred in carrying out such transfer. In order to cover the costs of long-term surveillance, Criterion 10 requires that a minimum charge of $250,000 (1978 dollars) must be paid by each mill operator to the general treasury of the United States or to an appropriate State agency prior to the termination of a uranium mill license. In most cases if there is a groundwater contamination problem, the problem must be remediated prior to license termination, or an alternate corrective action concentration limit under R317 -6- 6.15.G must be ~htaineda hi ·ved l Htl L pr tecli e of pub lic h aJLh and the environmc.nt;-t-ker-eby resolving the proelem. In some circumstances DOE may agree to take some additional actions after it takes title to the site, such as additional monitoring, if not onerous and provided adequate funding is provided. Upon the Director and Lh NR being satisfied that all regulatory requirements have been met and the site is reclaimed in a manner that satisfies all applicable standards, the Mill's license will be terminated upon transfer of the tailings to DOE. 10 CFR 40.28 provides a general license in favor of the long-term custodian for custody of and long-term care of the tailings impoundments and any surrounding lands transferred to it. 8 The surrounding areas not transferred to DOE would generally be free-released. 2.19.2 Current Redamation PJan The Mill's Reclamation Plan, Revision 4-:G3.2B, was approved by DRC under the Mill License ffi...-.Qn_January~ 2011. The Reclamation Plan sets out the requirements to be met by DenisonEFRI for the final reclamation and closure of the Mill facility, including the tailings cells and all impacted surrounding areas, in accordance with the requirements of 10 CFR Part 40, Appendix A (which have since been incorporated by reference into UAC R313-24). A copy of the Mill's Reclamation Plan, Revision 4.0 was previously submitted to the Director in November 2009 and is on file at the DRC. 8 In circumstances where the facility has a groundwater contamination plume, additional lands may be acquired by the licensee in order to bound the plume. In these circumstances these additional lands would be transferred along with the capped tailings impoundments, to DOE. 89 Reclamation Plan. 2.19.3 Provisions Included in the Permit Relating to the Mill's Reclamation Plan The Mill License is currently in timely renewal. As part of the Mill License Renewal, DRC is re-examining the Mill's Reclamation Plan for content and adequacy. At the time of original issuance of the Permit .. the Director had not completed his review of the Mill's Reclamation Plan. As a result, new requirements were added to the Permit to ensure that the final reclamation design approved by the Director on his re-examination of the Reclamation Plan will provide adequate performance criteria to protect local groundwater quality. To this end, three requirements were included in Part I.D.8 of the Permit to ensure that the cover system for each tailings cell will be designed and constructed to: a) Minimize the infiltration of water into the radon barrier and underlying tailings waste; b) Prevent the accumulation of leachates within the tailings that might create a bathtub effect and thereby spill over the maximum elevation of the FML inside any disposal cell; thereby causing a release of contaminants to the environment; and c) Protect groundwater quality at the compliance monitoring wells by ensuring that contaminant concentrations there do not exceed their respective GWQS or GWCL defined in Part I.C.l and Table 2 of the Permit. To provide consistency with the performance criteria stipulated by the Director at other lle.(2) disposal operations, a 200-year minimum performance period was required for all three of these criteria. In addition, Part I.D.9 was included in the Permit, which provides that upon commencement of decommissioning, DeaisoaEFRI will reclaim the Mill site and all related facilities, stabilize the tailings cells, and construct a cover sy tern over the tailings cells in compliance with all engineering design and specifications ~f Lh approved reclamation plan. Part I.D.7 also provides that the Director reserves the right to require modifications to the Mill's Reclamation Plan for purposes of compliance with the Utah Ground Water Quality Protection Regulations, 90 including but not limited to containment and control of contaminants, or discharges, or potential discharges to waters of the State. Finally, Part I.D.9 was added to the Permit to provide the Director an opportunity to ensure that: a) The post-closure performance requirements for the tailings cell cover system in Part I.D.8 is fully and adequately integrated into the Mill's Reclamation Plan. Part I.H.2 was also added to the Permit to require DenisonEFRI to complete an infiltration and contaminant transport model of the final tailings cell cover system to demonstrate the long-term ability of the cover to protect nearby groundwater quality. As a part of this cover system performance modeling required by Part I.H.2, the Director will determine if changes to the cover system are needed to ensure compliance with the Part I.D.8 performance criteria; b) All other facility demolition and decommissioning activities outlined in the Reclamation Plan will be done in a manner adequate to protect local groundwater quality. Issues or concerns to be considered and resolved include: (i) Identification, isolation, and authorized disposal of any un-used chemical reagents held in storage at the Mill site at the time of closure; (ii) Demolition, excavation, removal, and authorized disposal of all contaminated man-made structures, including, but not limited to: buildings, pipes, power lines, tanks, access roads, drain fields, leach fields, fly-ash disposal ponds, feedstock storage areas, Mill site wastewater storage ponds, solid waste disposal landfills, and all related appurtenances; and (iii) Excavation, removal, and authorized disposal of all contaminated soils found anywhere outside of the tailings cells at the facility. Through this process, the Director will be able to ensure that DMT has been adequately established for both the final tailings cell cover system and reclamation of the facility. respon 91 2.19.4 Post-Operational Monitoring Monitoring will continue under the Permit after cessation of operations, during reclamation and after reclamation has been completed until such time as the Mill License and Permit are terminated and the reclaimed tailings impoundments are transferred to the Department of Energy for perpetual care and maintenance. 3.0 CONCLUSIONS This Application describes the key monitoring and DMT performance standard requirements and other protections contained in the Permit. DeaisoaEFRI believes that with this Application, the accompanying Background Reports and other documentation, the Director has been provided sufficient information to determine that: a) DeaisoaEFRI has demonstrated that the applicable class TDS limits, ground water quality standards and protection levels will be met; b) The monitoring plan, sampling and reporting requirements are adequate to determine compliance with applicable requirements; c) Defl:isoaEFRI utilizes treatment and discharge minimization technology at the Mill commensurate with plant process design capability and similar or equivalent to that utilized by facilities that produce similar products or services with similar production process technology; and d) There is no current or anticipated impairment of present and future beneficial uses of the ground water. DeaisoA would be pleased to provide at+y-fi.u'lber information re~H:te-9tf€€tef:. 92 4.0 SIGNATURE AND CERTIFICATIONS By: I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Frank J. Filas Vice Pt·-ident, Permilting and Envir ~ Vice Presideat, Regulatory Affairs arJ:d Geaeral Couasel CERTIFICATION BY REGISTERED PROFESSIONAL ENGINEER I hereby certify that the foregoing Application has been prepared under my direction, that I have reviewed this Application, that I am familiar with the Mill facilities, and attest that this Application has been prepared in accordance with good engineering practices. Harold R. Roberts 93 Registered Professional Engineer State of Utah No. 165838 (seal) 94 5.0 REFERENCES American Society for Testing and Materials. 1996. Standards on Ground Water and Vadose Investigations. Dames & Moore. January 30, 1978. Environmental Report, White Mesa Uranium Project San Juan County, Utah. D' Appolonia Consulting Engineers, Inc. June 1979. Engineers Report: Tailings Management System, White Mesa Uranium Project Blanding, Utah. D' Appolonia Consulting Engineers, Inc. May 1981. 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Site Hydrogeology and &tifflation of Groundv.'ater +f.a\·el Times In The Perched Zone While Mesa Urafti±tm Mill Site }-kar Bla:ndiAg UHtlr. .f=J.ytlro Gee Chen1 1Ac. October H , 3010 Inslal lalion tlild H~·8:ra1:1lie Testing Elf Perched Monitoring Well" MW 33, M\¥ 3'1 anEI M\¥ 35 at the Whft.e-Meso UntAium M iU Nett£ Blandiag Utah. :Hydro Gee Chem,IR~er 12, 20 I 0 Hydrogee-logy of tf1e Perched Groundwater Zone flfld .«.sseeiuted Seeps ar1d Spring5 Near L-Re Wltite Me~iQ lh-aaium MHl Sile. Slalll#Ag tJ.t.a!:t: ~eo Cf:lem h'le. Jtme 28, 20 I 1 I11stal~ und Hydraul ic Testing of PerchecJ-Menitering We!.Jt;-MW 36 HAd MW 37 itt the Whi te Me:ou Unmffim....M.H.I Near BlaHEI-ing Uralr. 96 Hydro Geo Chern, Inc. May 8, 2012June 6, 2014 8-ae-Hydrogeology ilfl:d EstimatioB of GrouBdvlater Tra'rel Times iB the Perehed ZoBeof the White Mesa Uranium Mill Site Near Blanding, Utah. INTERA, Inc. October 2007. (2007a). Revised Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA Inc. November 16, 2007. (2007b). Revised Addendum:--Evaluation of Available Pre- Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA Inc. April 30, 2008. Revised Addendum: --Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. INTERA, Inc. December 30, 2009 Nitrate Contamination Investigation Report White Mesa Uranium Mill Site Blanding, Utah. INTERA, Inc. June 1, 2010 Background Groundwater Quality Report for Wells MW-20 and MW-22 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah:.':';" INTERA, Inc. May 11, 2011. Revised Phase 1 (A through C) Work Plan and Schedule for Phase 1 A - C Investigation. INTERA, Inc. June 3, 2011. Revised Phase 2 through 5 Work Plan and Schedule. INTERA, Inc. October 10, 2012. Source Assessment Report, White Mesa Uranium Mill, Blanding Utah:.INTERA, Inc. November 9, 2012. pH Report White Mesa Uranium Mill, Blanding Utah:., INTERA, Inc. May 7, 2013. Source Assessment Report for TDS in MW-29, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. August 30, 2013.Source Assessment Report for Selenium in MW-31, White Mesa Uranium Mill, Blanding Utah. INTERA, Inc. December 17, 2013. Source Assessment Report for Tetrahydrofuran in MW-01, White Mesa Uranium Mill, Blanding, Utah. 97 INTERA, Inc. January 13, 2014. Source Assessment Report for Gross Alpha in MW-32, White Mesa Uranium Mill, Blanding, Utah. INTERA, Inc. March 19, 2014. Source Assessment Report for Sulfate in MW-01 and TDS in MW-03A, White Mesa Uranium Mill, Blanding, Utah. INTERA, Inc. May 1, 2014. Background Groundwater Quality Report for Wells MW-35, MW- 36 and MW-37 for Denison Mines (USA) Corp.'s White Mesa Mill Site, San Juan County, Utah. Kirby. 2008. Geologic and Hydrologic Characterization of the Dakota-Burro Canyon Aquifer Near Blanding, San Juan County, Utah. Utah Geological Survey Special Study 123. Knight-Piesold LLC. November 23, 1998. Evaluation of Potential for Tailings Cell Discharge -White Mesa Mill. MWH Americas. March, 2010. Revised Infiltration and Contamination Transport Modeling Report, White Mesa Mill Site, Blanding Utah, Denison Mines (USA) Corp. Nuclear Regulatory Commission. May 1979. Final Environmental Statement related to operation of White Mesa Uranium Project Energy Fuels Nuclear, Inc., Docket No. 40-8681. Resource Conservation Recovery Act. 1986. Ground Water Monitoring Technical Enforcement Guidance Document. Revised Tolling Agreement, Revision 3, between DUSA and the Director, Revision 2. August 21, 2011. Stipulated Consent Agreement Docket No. UGW12-03 between Denison Mines (USA) Corp. and the Director of the Division of Radiation Control. July 12, 2012. T. Grant Hurst and D. Kip Solomon, Department of Geophysics, University of Utah. May 2008. Summary of work completed, data results, interpretations and recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah. United States Geological Survey. 1998. Techniques of Water Resource Investigation of the US Geological Survey, Book 9. TITAN Environmental Corporation. July 1994. Hydrogeological Evaluation of White Mesa Uranium Mill. Umetco Minerals Corporation. April 10, 1989. Cell 4 Design, White Mesa Project Blanding, Utah. 98 Umetco Minerals Corporation. January 1990. White Mesa Mill Drainage Report for Submittal to NRC. Umetco Minerals Corporation and Peel Environmental Services. 1993. Groundwater Study, White Mesa Facilities, Blanding, Utah. Utah, State of. January 20, 2010. Ground Water Discharge Permit No. UGW370004 Utah, State of. June 21, 2010. Ground Water Discharge Permit No. UGW370004 Utah, State of. February 15, 2011. Ground Water Discharge Permit No. UGW370004 Utah, State of. June 13, 2011. Ground Water Discharge Permit UGW370004 Plan and Time Shceduler Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the First, Second, Third and Fourth Quarters of 2010 and First Quruter 2011. Utah, State of. September 7, 2011. Ground Water Discharge Permit UGW370004 Plan and Time Shceduler Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the First, Second, Third and Fourth Quarters of 2010 and First Quarter 2011. Utah, State of. July 14, 2011. Ground Water Discharge Permit No. UGW370004 Utah, State of. August 24,2012. Ground Water Discharge Permit No. UGW370004 Utah, State of. Radioactive Materials License No. UT 1900479 (the "Mill License"). Utah, State of. December 13, 2012. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. Utah, State of. March 15, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. Utah, State of. August 28, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. Utah, State of. September 20, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. Utah, State of. December 5, 2013. Groundwater Discharge Permit UGW370004 Plan and Time Schedule Under part I.G.4 (d) for Violations of Part I.G.2 for Constituents in the Third Quarter of 2012. 99