Loading...
HomeMy WebLinkAboutDRC-2013-002932 - 0901a068803afc59ENERGY FUELS Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO. US, 80228 303 974 2140 www.energyfuels.com VIA EMAIL AND OVERNIGHT DELIVERY "DRC-2013-002932 August 20, 2013 Mr. Bryce Bird Director, Utah Division of Air Quality State of Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT84116 Re: White Mesa Uranium Mill, National Emissions Standards for Radon Emission from Operating Mill Tailings Transmittal of July 2013 Monthly Radon Flux Monitoring Report for Cell 2 Dear Mr. Bird: This letter transmits Energy Fuels Resources (USA) Inc.'s ("EFRI's") radon-222 flux monitoring report for July 2013 (the "Monthly Report") pursuant to 40 CFR 61.254(b), for Cell 2 at the White Mesa Uranium Mill (the "Mill"). Cell 2, which was constructed and placed into operation prior to December 15, 1989 is subject to the requirements in 40 CFR 61.252(a). As discussed in our 2012 Annual Radon Flux Monitoring Report submitted March 29, 2013, Cell 2 was not in compliance with the emissions limits in 40 CFR 61.252(a) of 20 pCi/(m2 -sec) for the calendar year 2012. This Monthly Report is submitted pursuant to 40 CFR 261(b) which requires monthly reporting of monitoring data collected beginning the month immediately following the submittal of the annual report for the year in non- Included with the Monthly Report is a Radon Flux Measurement Program Report, dated July 2013, prepared by Tellco Environmental (the "Tellco July 2013 Monthly Report"). The Tellco July 2013 Monthly Report indicates that for the month of July 2013, the average radon flux from Cell 2 of 24.3 pCi/(m -sec), did not comply with the standard in 40 CFR 61.252(a). If you have any questions, please feel free to contact me at (303) 389-4132. Yours very truly, compliance. Energy Fuels Resources (USA) Inc. Jo Ann Tischler Manager, Compliance and Licensing N:\WMM\Required Reports\NESHAPS Reports\2013 Monthly NESHAPs\Cell 2 July 2013 Monthly NESHAPS\transmtl Cell 2 Radon Flux July 2013.doc Letter to B. Bird August 20, 2013 Page 2 of 2 cc: David C. Frydenlund Phil Goble, Utah DRC Dan Hillsten Rusty Lundberg, Utah DRC Jay Morris, Utah DAQ Harold R. Roberts David E. Turk Kathy Weinel Director, Air and Toxics Technical Enforcement Program, Office of Enforcement, Compliance and Environmental Justice, U. S. Environmental Protection Agency Attachments ENERGY FUELS RESOURCES (USA) INC. 40 CODE OF FEDERAL REGULATIONS 61 SUBPART W WHITE MESA MILL SAN JUAN COUNTY, UTAH TAILINGS CELL 2 MONTHLY COMPLIANCE REPORT FOR JULY 2013 Submitted August 20, 2013 by Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, Colorado 80228 (303) 974-2140 1) Name and Location of the Facility Energy Fuels Resources (USA) Inc. ("EFRI") operates the White Mesa Mill (the "Mill"), located in central San Juan County, Utah, approximately 6 miles (9.5 km) south of the city of Blanding. The Mill can be reached by private road, approximately 0.5 miles west of Utah State Highway 191. Within San Juan County, the Mill is located on fee land and mill site claims, covering approximately 5,415 acres, encompassing all or part of Sections 21, 22, 27, 28, 29, 32, and 33 of T37S, R22E, and Sections 4, 5,6, 8, 9, and 16 of T38S, R22E, Salt Lake Base and Meridian. All operations authorized by the Mill's State of Utah Radioactive Materials License are conducted within the confines of the existing site boundary. The milling facility currently occupies approximately 50 acres and the tailings disposal cells encompass another 275 acres. 2) Monthly Report This Repoit is the monthly report for the Mill's Cell 2 for July 2013, required under 40 Code of Federal Regulations (CFR) 61.254(b). A summary of the events that gave rise to the requirement to file this monthly report under 40 CFR 61.254(b) is set out in Section 4 of this Report. A summary of the radon emissions from Cell 2 measured in July 2013 is set out in Section 5 of this Report. The monthly monitoring data for July 2013 required under 40 CFR 61.254(b) is provided in Attachment 1 to this Report, which contains the Radon Flux Measurement Program Report, dated July 2013, prepared by Tellco Environmental (the "Tellco July 2013 Monthly Report"). The results are summarized in Section 5 of this Report. 3) Name of the Person Responsible for Operation and Preparer of Report Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, Colorado 80228 303.628.7798 (phone) 303.389.4125 (fax) EFRI is the operator of the Mill and its tailings impoundments (Cells 2, 3, and 4A) and evaporation impoundments (Cells 1 and 4B). The Mill is an operating conventional uranium mill, processing both conventional ores and alternate feed materials. The "method of operations" at the Mill is phased disposal of tailings. Compliance with the NESHAP standards at 40 CFR 61.252(a) is determined annually for existing impoundments (i.e., Cells 2 and 3). The annual radon emissions for existing impoundments are measured using Large Area Activated Charcoal Canisters in conformance with 40 CFR, Part 61, Appendix B, Method 115, Restrictions to Radon Flux Measurements, (Environmental Protection Agency ["EPA"1, 2008). These canisters are passive gas adsorption sampling devices used to determine the flux rate of Radon-222 gas from the surface of the tailings material. For impoundments licensed for use after December 15, 1989 (i.e., Cell 4A, and 4B), EFRI employs the work practice standard listed at 40 CFR 61.252(b)(1) in that all tailings impoundments constructed or licensed after that date are lined, are no more than 40 acres in area, and no more than two impoundments are operated for tailings disposal at any one time. EFRI is submitting this monthly compliance report in conformance with the standards in 40 CFR 61.254(b). 2 4) Background Information -- Summary of 2012 Annual Report Facility History Cells 2 and 3, which are 270,624 m2 (approximately 66 acres) and 288,858 m2 (approximately 71 acres), respectively, were constructed prior to December 15, 1989 and are considered "existing impoundments" as defined in 40 CFR 61.251. Radon flux from Cells 2 and 3 is monitored annually, as discussed below. Cells 4A and 4B were constructed after December 15, 1989, and are subject to the work practice standards in 40 CFR 61.252(b)(1), which require that the maximum surface area of each cell not exceed 40 acres. For this reason, Cells 4A and 4B are not required to undergo annual radon flux monitoring. Cell 3, which is nearly filled, and Cell 4A, receives the Mill's tailings sands. Cells 1 and 4B, receive solutions only, and are in operation as evaporative ponds. Cell 2 is filled with tailings, is covered with an interim soil cover, and is no longer in operation. Dewatering of Cell 2 The Utah Division of Water Quality issued Groundwater Discharge Permit ("GWDP') UGW-370004 in 2005. Under Part I.D.3 of the current GWDP, EFRI has been required to accelerate dewatering of the solutions in the Cell 2 slimes drain. Dewatering of Cell 2 began in 2008. In mid-2011, changes were made in the pumping procedures for slimes drain dewatering of Cell 2 that resulted in an acceleration of dewatering since that time. As discussed in more detail below, studies performed by EFRI indicate that the increase in radon flux from Cell 2 has likely been caused by these dewatering activities. No other changes appear to have occurred in condition, use, or monitoring of Cell 2 that could have resulted in an increase in radon flux from the cell. The average water level in the Cell 2 slimes drain standpipe for each of the years 2008 through 2012 indicate that water levels in Cell 2 have decreased approximately 3.25 feet (5600.56 to 5597.31 fmsl) since 2008. Of this decrease in water level, approximately 1 foot occurred between 2010 and 2011, reflecting the improved dewatering that commenced part way through 2011, and approximately 2 feet between 2011 and 2012, reflecting improved dewatering for all of 2012. Radon Flux Monitoring of Cell 2 Tellco performed the 2012 radon flux sampling during the second quarter of 2012 in the month of June. On June 25, 2012, Tellco advised EFRI that the average radon flux for Cell 2 from samples taken in June 2012 was 23.1 pCi/(m2 -sec) (referred to in the Tellco report as pCi/m2"s), which exceeded the Subpart W requirement. The result of the 2012 radon-222 flux monitoring for Cell 3 was 18 pCi/(m2 -sec). Cell 3, therefore, was in compliance with this standard for 2012. 40 CFR 61.253 provides that: "When measurements are to be made over a one year period, EPA shall be provided with a schedule of the measurement frequency to be used. The schedule may be submitted to EPA prior to or after the first measurement period." EFRI advised the Utah Division of Air Quality ("DAQ"), by notices submitted on August 3 and September 14, 2012, that EFRI planned to collect additional samples from Cell 2 in the third and fourth quarters of 2012. These samples were collected on September 9, October 21, and November 21, 2012, 3 respectively. As the June monitoring for Cell 3 indicated that it was in compliance with the standard, further monitoring of Cell 3 was not performed. The result of the 2012 radon-222 flux monitoring for Cell 2 was 25.9 pCi/(m2 -sec) (averaged over four monitoring events). The measured radon flux from Cell 2 in 2012 therefore exceeded the standard in 40 CFR 61.252(a) of 20 pCi/(m2 -sec). The Cell 2 and Cell 3 radon flux results were reported in EFRI's 2012 Annual Radon Flux Monitoring Report (the "2012 Annual Report"). The provisions of 40 CFR 61.254(b) requires that: "If the facility is not in compliance with the emission limits of paragraph 61.252 in the calendar year covered by the report, then the facility must commence reporting to the Administrator on a monthly basis the information listed in paragraph (a) of this section, for the preceding month. These reports will start the month immediately following the submittal of the annual repoit for the year in non-compliance and will be due 30 days following the end of each month." This Report is the required monthly repoit for July 2013 for Cell 2. Monthly monitoring will continue until US EPA or DAQ determines that it is no longer required. Evaluation of Potential Factors Affecting Radon Flux In an attempt to identify the cause of the increase in radon flux at Cell 2, EFRI conducted a number of evaluations including: • Excavation of a series of 10 test pits in the Cell 2 sands to collect additional information needed to ascertain factors affecting radon flow path and flux, • Evaluation of radon trends relative to slimes drain dewatering, • Development of correlation factors relating dewatering rates to radon flux, and • Estimation of the thickness of temporary cover that would be required to achieve compliance with the radon flux standard of 20 pCi/(m2 -sec), during the dewatering process. These studies and results are discussed in detail in EFRI's 2012 Annual Radon Flux Repoit and summarized in the remainder of this section. Slimes drain dewatering data indicate that a lowering of the water level in Cell 2 has resulted in an increase in the average radon flux, and that an increase in water level has resulted in a decrease in the average radon flux. Changes in radon flux have consistently been inversely proportional to changes in water levels in Cell 2 since 2008. For the last three years the change in radon flux has been between 3 and 5 pCi/(m2-sec) per each foot of change in water level. It is also noteworthy that the significant increases in radon flux from Cell 2 which occurred between 2010 and 2011 and between 2011 and 2012 coincided with the periods of improved (accelerated) dewatering of Cell 2. EFRI has evaluated these results and has concluded that the increase in radon-222 flux from Cell 2 that has resulted in the exceedance of the 20 pCi/(m2 -sec) standard in 40 CFR 61.252 (a) in 2012 is most likely the unavoidable result of Cell 2 dewatering activities mandated by the Mill's State of Utah GWDP. This is due to the fact that saturated tailings sands attenuate radon flux more than dry tailings sands, and 4 the thickness of saturated tailings sands decrease as dewatering progresses. There appear to have been no other changes in conditions at Cell 2 that could have caused this increase in radon flux from Cell 2. These conclusions are supported by evaluations performed by SENES Consultants Limited ("SENES"), who were retained by EFRI to assess the potential effects of dewatering on the radon flux from Cell 2 and to provide calculations of the thickness of temporary cover required to achieve the radon flux standard during the dewatering process. SENES' evaluations were presented in a report provided as an attachment to EFRI's 2012 Annual Repoit. SENES estimated a theoretical radon flux from the covered tailings at Cell 2 for various depths (thicknesses) of dry tailings, and predicted future increases in radon flux as a function of decreases in water levels. In order to explore potential interim actions that could be taken to maintain radon flux within the 20 pCi/(m2-sec) standard, the SENES study also evaluated the extent to which radon emanations from the cell can be reduced by increasing the thickness of the current interim cover on Cell 2. 5) July 2013 Results Detailed results for July 2013 for Cell 2 are contained in the Tellco July 2013 Monthly Repoit. As described in the Tellco July 2013 Monthly Repoit, monitoring was performed consistent with 40 CFR 61 Subpart W Appendix B, Method 115 radon emissions reporting requirements. The radon monitoring consisted of 100 separate monitoring points at which individual radon flux measurements have been made by collection on carbon canisters. The individual radon flux measurements were averaged to determine compliance with 40 CFR Part 61.252. The average radon flux for Cell 2 in July 2013 was reported by Tellco to be 24.3 pCi/(m2 -sec). This radon flux value exceeds the 20 pCi/(m2 -sec) standard in 40 CFR 61.252. 6) Other Information Status of Proposed Updated Final Cover Design As part of developing the Mill's final reclamation plan required to achieve the radon flux standard of 20 pCi/(m2-sec), a final engineered cover design was submitted by TITAN Environmental in 1996 and approved by the US Nuclear Regulatory Commission ("NRC"). An updated final cover design for the Mill's tailings system, submitted in November 2011, is under review by the Utah Division of Radiation Control ("DRC"), and is not currently approved. DRC provided a second round of interrogatories on the proposed cover design and associated Infiltration and Contaminant Transport Model ("ICTM") in February 2013, for which EFRI and its consultant, MWH Inc. are preparing responses. 7) Additional Information Required for Monthly Reports a) Controls or Other Changes in Operation of the Facility 40 CFR 61.254(b)(1) requires that in addition to all the information required for an Annual Report under 40 CFR 61.254(b), monthly reports shall also include a description of all controls or other changes in operation of the facility that will be or are being installed to bring the facility into compliance. Based on the evaluations described in Section 4, above, and as discussed during EFRI's March 27, 2013 meeting with DAQ and DRC staff, in addition to the monthly monitoring reported in this Monthly Report, 5 EFRI has proposed the following steps to ensure that radon emissions from Cell 2 are kept as low as reasonably achievable and to bring the facility into compliance with the applicable standard: Construction and Monitoring of Interim Cover Test Area, and Application of Additional Random Fill i. EFRI proposes to construct and monitor a test-scale application to confirm the effect of the addition of one foot of additional soil cover. EFRI proposes to apply one foot of random fill at 90% compaction to a test area on Cell 2 of 100 feet by 100 feet. This test area would be established on or before September 2013 subject to DRC confirmation as discussed below. The radon flux in the test area would be measured both before and after placement of the additional fill and periodically over a six month period. Design of the test soil cover area is underway. ii. If the desired reduction (to within compliance levels) is achieved on the test area, EFRI will apply one foot of additional random fill at 90% compaction, to the remainder of Cell 2, on or before July 1, 2014. EFRI will perform the 2014 annual radon flux monitoring of Cell 2 after placement of the fill over the entire Cell 2 area. The foregoing proposed test and construction activities will be conditional upon DRC confirming that such activities will not be prejudicial to or inconsistent with the final approved cover design currently under review, and will be credited toward the final cover design. As of the date of this report, EFRI has not received DRC's confirmation that the test and construction activities will not be prejudicial to or inconsistent with the final approved cover design, or will be credited toward the final cover design. Interim Corrective Action EFRI has taken the following additional steps to provide interim mitigation of radon flux from Cell 2. EFRI has identified the areas of elevated radon flux associated with known sources of radiological contamination at or near the surface of the cell cover. Specifically: • the location associated with the former tailings discharge line, • the perimeter area near the north of Cell 2 containing disturbed or windblown material, and • the location of specific alternate feed tailings disposal with elevated radionuclide content. EFRI has implemented corrective measures, which began in June 2013 and are in progress at the time of this monthly report. The corrective measures include the addition of cover material to the known source areas, and/or the excavation and reburying of any amount of contaminated material that may be detected at the surface of the source areas. EFRI has completed an initial step of adding and compacting cover soil in a dry condition on Cell 2 during July 2013. This step has not affected the hot spots sufficiently to reduce the average flux to below the limit of 20 pCi/(m2 -sec). During August 2013, the additional soil already added to Cell 2 will be sprayed with water and re-compacted to improve (reduce) the permeability of the added cover. The Mill will have the completed prior to the upcoming August sampling event, to quantify how much effect this approach may have on the average flux. a) Facility's Performance Under Terms of Judicial or Administrative Enforcement Decree The Mill is not under a judicial or administrative enforcement decree. 6 r 8) Certification I Certify under penalty of law that I have personally examined and am familiar with the information submitted herein and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the submitted information is true, accurate and complete. I am aware that there are significant penaltie^ for submitting false information including the possibility of fine and imprisonment. Spi 18, W.S.C. 1001. Signed: //// SA ' Date: _ David C. Frypenlpnd Senior Vice President, General Counsel and Corporate Secretary ATTACHMENT 1 National Emissions Standards for Hazardous Air Pollutants 2013 Radon Flux Measurement Program July 2013 Sampling Results National Emission Standards for Hazardous Air Pollutants 2013 Radon Flux Measurement Program White Mesa Mill 6425 South Highway 191 Blanding, Utah 84511 July 2013 Sampling Results Cell 2 Prepared for: Energy Fuels Resources (USA) Inc. 6425 S. Highway 191 P.O. Box 809 Blanding, Utah 84511 Prepared by: Tellco Environmental P.O. Box 3987 Grand Junction, Colorado 81502 TABLE OF CONTENTS Page 1. INTRODUCTION 1 2. SITE HISTORY AND DESCRIPTION 1 3. REGULATORY REQUIREMENTS FOR THE SITE 2 4. SAMPLING METHODOLOGY 2 5. FIELD OPERATIONS 3 5.1 Equipment Preparation 3 5.2 Sample Locations, Identification, and Placement 3 5.3 Sample Retrieval 3 5.4 Environmental Conditions 4 6. SAMPLE ANALYSIS 4 6.1 Apparatus 4 6.2 Sample Inspection and Documentation 4 6.3 Background and Sample Counting 5 7. QUALITY CONTROL (QC) AND DATA VALIDATION 5 7.1 Sensitivity 5 7.2 Precision 5 7.3 Accuracy 6 7.4 Completeness 6 8. CALCULATIONS 6 9. RESULTS 7 9.1 Mean Radon Flux 7 9.2 Site Results 8 References 9 Figure 1 10 Appendix A. Charcoal Canister Analyses Support Documents Appendix B. Recount Data Analyses Appendix C. Radon Flux Sample Laboratory Data, Including Blanks Appendix D. Sample Locations Map (Figure 2) 1. INTRODUCTION During July 22-23, 2013 Tellco Environmental, LLC (Tellco) of Grand Junction, Colorado, provided support to Energy Fuels Resources (USA) Inc. (Energy Fuels) to conduct radon flux measurements regarding the required National Emission Standards for Hazardous Air Pollutants (NESHAPs) Radon Flux Measurements. These measurements are required of Energy Fuels to show compliance with Federal Regulations (further discussed in Section 3 below). The standard is not an average per facility, but is an average per radon source. The standard allows mill owners or operators the option of either making a single set of measurements or making measurements over a one year period (e.g., weekly, monthly, or quarterly intervals). Energy Fuels is presently on a monthly radon flux sampling plan for Cell 2. This report presents the radon flux measurements results for Cell 2 for July 2013; the results of each monthly sampling event are presented in separate reports. Prior to 2012, Energy Fuels had chosen to make a single set of measurements to represent the radon flux each year; however, as the radon flux levels in Cell 2 began exceeding the regulatory standard of 20 picoCuries per square meter per second (pCi/m2-s) in 2012, Energy Fuels decided to make the radon flux measurements on a more frequent basis. During June and July 2013, Energy Fuels placed additional cover materials at selected sample locations of Cell 2 in an attempt to reduce the radon flux levels. The additional material was approximately 18-24 inches thick and approximately 100 feet in diameter, centered around selected sample location points where previous sampling had identified radon flux greater than 40 pCi/m2-s. Tellco was contracted to provide radon canisters, equipment, and canister placement personnel as well as lab analysis of samples. Energy Fuels personnel provided support for loading and unloading charcoal from the canisters. This report details the procedures employed by Energy Fuels and Tellco to obtain the results presented in Section 9.0 of this report. 2. SITE DESCRIPTION The White Mesa Mill facility is located in San Juan County in southeastern Utah, six miles south of Blanding, Utah. The mill began operations in 1980 for the purpose of extracting uranium and vanadium from feed stocks. Processing effluents from the operation are deposited in four lined cells, which vary in depth. Cell 1, Cell 4A, and Cell 4B did not require radon flux sampling, as explained in Section 3 below. Cell 2, which has a total area of approximately 270,624 square meters (m2), has been filled and covered with interim cover. This cell is comprised of one region; a soil cover of varying thickness, which requires NESHAPs radon flux monitoring. The Cell 2 cover region is the same size in 2013 as it was in 2012. There are no exposed tailings or standing liquid within Cell 2. Cell 3, which has a total area of 288,858 m2, is nearly filled with tailings sand and is undergoing pre- closure activities. This cell is comprised of two source regions that require NESHAPs radon monitoring: a soil cover region of varying thickness and an exposed tailings "beaches" region. The l remaining area is covered by standing liquid in lower elevation areas. The sizes of the regions vary due to the continuing advancement of interim cover materials and varying water levels. 3. REGULATORY REQUIREMENTS FOR THE SITE Radon emissions from the uranium mill tailings at this site are regulated by the State of Utah's Division of Radiation Control and administered by the Utah Division of Air Quality under generally applicable standards set by the Environmental Protection Agency (EPA) for Operating Mills. Applicable regulations are specified in 40 CFR Part 61, Subpart W, National Emission Standards for Radon Emissions from Operating Mill Tailings, with technical procedures in Appendix B. At present, there are no Subpart T uranium mill tailings at this site. These regulations are a subset of the NESHAPs. According to subsection 61.252 Standard, (a) radon-222 emissions to ambient air from an existing uranium mill tailings pile shall not exceed an average of 20 pCi/m2-s for each pile or region. Subsection 61.253, Determining Compliance, states that: "Compliance with the emission standard in this subpart shall be determined annually through the use of Method 115 of Appendix B." The repaired Cell 4A, and newly constructed Cell 4B, were both constructed after December 15, 1989 and each was constructed with less than 40 acres surface area. Cell 4A and 4B comply with the requirements of 40 CFR 61.252(b), therefore no radon flux measurements are required on either Cell 4A or 4B. 4. SAMPLING METHODOLOGY Radon emissions were measured using Large Area Activated Charcoal Canisters (canisters) in conformance with 40 CFR, Part 61, Appendix B, Method 115, Restrictions to Radon Flux Measurements, (EPA, 2012). These are passive gas adsorption sampling devices used to determine the flux rate of radon-222 gas from a surface. The canisters were constructed using a 10-inch diameter PVC end cap containing a bed of 180 grams of activated, granular charcoal. The prepared charcoal was placed in the canisters on a support grid on top of a Vi inch thick layer of foam and secured with a retaining ring under 1XA inches of foam (see Figure 1, page 10). One hundred sampling locations were distributed throughout Cell 2 (which consisted of one region) as depicted on the Sample Locations Map (see Figure 2, Appendix D). Each charged canister was placed directly onto the surface (open face down) and exposed to the surface for 24 hours. Radon gas adsorbed onto the charcoal and the subsequent radioactive decay of the entrained radon resulted in radioactive lead-214 and bismuth-214. These radon progeny isotopes emit characteristic gamma photons that can be detected through gamma spectroscopy. The original total activity of the adsorbed radon was calculated from these gamma ray measurements using calibration factors derived from cross-calibration of standard sources containing known total activities of radium-226 with geometry identical to the counted samples and from the principles of radioactive decay. After approximately 24 hours, the exposed charcoal was transferred to a sealed plastic sample container (to prevent radon loss and/or further exposure during transport), identified and labeled, and transported to the Tellco laboratory in Grand Junction, Colorado for analysis. Upon completion of on- site activities, the field equipment was alpha and beta-gamma scanned for possible contamination resulting from fieldwork activities. All field equipment was surveyed by Energy Fuels Radiation Safety personnel and released for unrestricted use. Tellco personnel maintained custody of the samples from collection through analysis. 2 5. FIELD OPERATIONS 5.1 Equipment Preparation All charcoal was dried at 110°C before use in the field. Unused charcoal and recycled charcoal were treated the same. 180-gram aliquots of dried charcoal were weighed and placed in sample containers. Proper balance operation was verified daily by checking a standard weight. The balance readout agreed with the known standard weight to within ± 0.1 percent. After acceptable balance check, empty containers were individually placed on the balance and the scale was re-zeroed with the container on the balance. Unexposed and dried charcoal was carefully added to the container until the readout registered 180 grams. The lid was immediately placed on the container and sealed with plastic tape. The balance was checked for readout drift between readings. Sealed containers with unexposed charcoal were placed individually in the shielded counting well, with the bottom of the container centered over the detector, and the background count rate was documented. Three five-minute background counts were conducted on ten percent of the containers, selected at random to represent the "batch". If the background counts were too high to achieve an acceptable lower limit of detection (LLD), the entire charcoal batch was labeled non-conforming and recycled through the heating/drying process. 5.2 Sample Locations, Identification, and Placement On July 22, 2013, the sampling locations were spread out throughout the Cell 2 region. The same sampling locations that were established for the previous sampling of Cell 2 were used for the July 2013 sampling, although the actual sample identification numbers (ID) are different. An individual ID was assigned to each sample point, using a sequential alphanumeric system indicating the charcoal batch and physical location within the region (e.g., G01 ...G100). This ID was written on an adhesive label and affixed to the top of the canister. The sample ID, date, and time of placement were recorded on the radon flux measurements data sheets for the set of one hundred measurements. Prior to placing a canister at each sample location, the retaining ring, screen, and foam pad of each canister were removed to expose the charcoal support grid. A pre-measured charcoal charge was selected from a batch, opened and distributed evenly across the support grid. The canister was then reassembled and placed face down on the surface at each sampling location. Care was exercised not to push the device into the soil surface. The canister rim was "sealed" to the surface using a berm of local borrow material. Five canisters (blanks) were similarly processed and the canisters were kept inside an airtight plastic bag during the 24-hour testing period. 5.3 Sample Retrieval On July 23, 2013 at the end of the 24-hour testing period, all canisters were retrieved, disassembled and each charcoal sample was individually poured through a funnel into a container. Identification numbers were transferred to the appropriate container, which was sealed and placed in a box for 3 transport. Retrieval date and time were recorded on the same data sheets as the sample placement information. The blank samples were similarly processed. The charcoal samples from all 100 canisters were successfully containerized during the unloading process. 5.4 Environmental Conditions A rain gauge and thermometer were in place at the White Mesa Mill site to monitor rainfall and air temperatures during sampling in order to ensure compliance with the regulatory measurement criteria. In accordance with 40 CFR, Part 61, Appendix B, Method 115: • Measurements were not initiated within 24 hours of rainfall. • Approximately 0.01 inches of rainfall occurred after placement of the canisters, but all of the canister seals remained intact and none of the canisters were surrounded by water. • The minimum ambient air temperature during the sampling period was 66 degrees F. 6. SAMPLE ANALYSIS 6.1 Apparatus Apparatus used for the analysis: • Single- or multi-channel pulse height analysis system, Ludlum Model 2200 with a Teledyne 3" x 3" sodium iodide, thallium-activated (Nal(Tl)) detector. • Lead shielded counting well approximately 40 cm deep with 5-cm thick lead walls and a 7- cm thick base and 5 cm thick top. • National Institute of Standards and Technology (NIST) traceable aqueous solution radium- 226 absorbed onto 180 grams of activated charcoal. • Ohaus Model C501 balance with 0.1 -gram sensitivity. 6.2 Sample Inspection and Documentation Once in the laboratory, the integrity of each charcoal container was verified by visual inspection of the plastic container. Laboratory personnel checked for damaged or unsealed containers and verified that the data sheet was complete. All of the 100 sample containers and 5 blank containers received and inspected at the Tellco analytical laboratory were verified as valid and no damaged or unsealed containers were observed. 6.3 Background and Sample Counting The gamma ray counting system was checked daily, including background and radium-226 source measurements prior to and after each counting session. Based on calibration statistics, using two sources with known radium-226 content, background and source control limits were established for each Ludlum/Teledyne counting system with shielded well (see Appendix A). Gamma ray counting of exposed charcoal samples included the following steps: • The length of count time was determined by the activity of the sample being analyzed, according to a data quality objective of a minimum of 1,000 accrued counts for any given sample. • The sample container was centered on the Nal detector and the shielded well door was closed. • The sample was counted over a determined count length and then the mid-sample count time, date, and gross counts were documented on the radon flux measurements data sheet and used in the calculations. • The above steps were repeated for each exposed charcoal sample. • Approximately 10 percent of the containers counted were selected for recounting. These containers were recounted within a few days following the original count. 7. QUALITY CONTROL (QC) AND DATA VALIDATION Charcoal flux measurement QC samples included the following intra-laboratory analytical frequency objectives: • Blanks, 5 percent, and • Recounts, 10 percent All sample data were subjected to validation protocols that included assessments of sensitivity, precision, accuracy, and completeness. All method-required data quality objectives (EPA, 2012) were attained. 7.1 Sensitivity A total of five blanks were analyzed by measuring the radon progeny activity in samples subjected to all aspects of the measurement process, excepting exposure to the source region. These blank sample measurements comprised approximately 5 percent of the field measurements. The results of the blank sample radon flux rates ranged from -0.02 to 0.01 pCi/m2-s, with an average of approximately 0.00 pCi/m2-s. The lower limit of detection (LLD) was approximately 0.03 pCi/m2-s. 7.2 Precision Ten recount measurements, distributed throughout the sample set, were performed by replicating analyses of individual field samples (see Appendix B). These recount measurements comprised approximately 10 percent of the total number of samples analyzed. The precision of all recount 5 measurements, expressed as relative percent difference (RPD), ranged from less than 0.1 percent to 6.7 percent with an overall average precision of approximately 1.4 percent RPD. 7.3 Accuracy Accuracy of field measurements was assessed daily by counting two laboratory control samples with known Ra-226 content. Accuracy of these lab control sample measurements, expressed as percent bias, ranged from approximately -3.0 percent to -0.5 percent. The arithmetic average bias of the lab control sample measurements was approximately -1.5 percent (see Appendix A). 7.4 Completeness One hundred samples from the Cell 2 Cover Region were verified, representing 100 percent completeness for the July 2013 radon flux sampling. 8. CALCULATIONS Radon flux rates were calculated for charcoal collection samples using calibration factors derived from cross-calibration to sources with known total activity with identical geometry as the charcoal containers. A yield efficiency factor was used to calculate the total activity of the sample charcoal containers. Individual field sample result values presented were not reduced by the results of the field blank analyses. In practice, radon flux rates were calculated by a database computer program. The algorithms utilized by the data base program were as follows: Equation 8.1: 2 N pCi Rn-222/m sec = rrs*A*b*0 5(d/9i 75)j where: N = net sample count rate, cpm under 220-662 keV peak Ts = sample duration, seconds b = instrument calibration factor, cpm per pCi; values used: 0.1699, for M-01/D-21 and 0.1702, for M-02/D-20 d = decay time, elapsed hours between sample mid-time and count mid-time A = area of the canister, m2 Equation 8.2: Error, 2cr = 2 x Gross Sample, cpm Background Sample, cpm + Sample Count, t, min Background Count,t,mm x Sample Concentration Net,cpm 6 Equation 8.3: 2.71+(4.65K&.) LLD- rrs*A*b*0.5(d/9T75)] where: 2.71 = constant 4.65 = confidence interval factor Sb = standard deviation of the background count rate Ts = sample duration, seconds b = instrument calibration factor, cpm per pCi; values used: 0.1699, for M-01/D-21 and 0.1702, for M-02/D-20 d = decay time, elapsed hours between sample mid-time and count mid-time A = area of the canister, m2 9. RESULTS 9.1 Mean Radon Flux Referencing 40 CFR, Part 61, Subpart W, Appendix B, Method 115 - Monitoring for Radon-222 Emissions, Subsection 2.1.7 - Calculations, "the mean radon flux for each region of the pile and for the total pile shall be calculated and reported as follows: (a) The individual radon flux calculations shall be made as provided in Appendix A EPA 86(1). The mean radon flux for each region of the pile shall be calculated by summing all individual flux measurements for the region and dividing by the total number of flux measurements for the region. (b) The mean radon flux for the total uranium mill tailings pile shall be calculated as follows: J1A1. + ... J7A2H .. • J,A, Js = At Where: Js = Mean flux for the total pile (pCi/m2-s) J, = Mean flux measured in region i (pCi/m2-s) A, = Area of region i (m2) At = Total area of the pile (m2)" 40 CFR 61, Subpart W, Appendix B, Method 115, Subsection 2.1.8, Reporting states "The results of individual flux measurements, the approximate locations on the pile, and the mean radon flux for each region and the mean radon flux for the total stack [pile] shall be included in the emission test report. Any condition or unusual event that occurred during the measurements that could significantly affect the results should be reported." 7 9.2 Site Results Site Specific Sample Results (reference Appendix C) (a) The mean radon flux for the Cell 2 Cover Region at the site is as follows: Cell 2 - Cover Region = 24.3 pCi/m2-s (based on 270,624 m2 area) Note: Reference Appendix C of this report for the entire summary of individual measurement results, (b) Using the data presented above, the calculated mean radon flux for Cell 2 is, as follows: Cell 2 = 24.3 pCi/m2-s (24.3V270.624) =24.3 270,624 As shown above, the arithmetic mean radon flux of the July 2013 samples for Cell 2 at Energy Fuels White Mesa milling facility is above the NRC and EPA standard of 20 pCi/m2-s. The extremely dry weather at the site for the past several years was especially severe during 2012 and is continuing now in 2013. The result of this dry weather is likely a lowered water table in the containment cell and reduced moisture content in surface soils, which could result in increased radon flux rates at the site. The additional cover material placed at the selected locations of Cell 2 (refer to the "comments" column of the radon flux measurements spreadsheet in Appendix C) did not significantly reduce the radon flux rates at those locations. The permeability of the additional cover material is likely a result of low moisture content and partly because of the porosity of the materials used. Appendix C presents the summary of individual measurement results, including blank sample analysis. Sample locations are depicted on Figure 2, which is included in Appendix D. The map was produced by Tellco. 8 References U. S. Environmental Protection Agency, Radon Flux Measurements on Gardinier and Royster Phosphogypsum Piles Near Tampa and Mulberry, Florida, EPA 520/5-85-029, NTIS #PB86- 161874, January 1986. U. S. Environmental Protection Agency, Title 40, Code of Federal Regulations, July 2012. U. S. Nuclear Regulatory Commission, Radiological Effluent and Environmental Monitoring at Uranium Mills, Regulatory Guide 4.14, April 1980. U. S. Nuclear Regulatory Commission, Title10, Code of Federal Regulations, Part 40, Appendix A, January 2013. 9 Figure 1 Large Area Activated Charcoal Canisters Diagram 12 HI Tlncx Ciid'coa L-in Tn»cd 1/4 in Vent Ho e Scrubbm Pad S,2ir reick &crub3i!i Pa a 1 8» Spnnp ft 25 \ tO-iii »a PVC End C»p FlGtWE l Large-Ar&a Ratfon Collector 10 Appendix A Charcoal Canister Analyses Support Documents A ACCURACY APPRAISAL TABLE JULY 2013 SAMPLING ENERGY FUELS RESOURCES WHITE MESA MILL, BLANDING, UTAH 2013 NESHAPs RADON FLUX MEASUREMENTS CELL 2 SAMPLING DATES- 07/22/13-07/23/13 SYSTEM I D DATE Bkg Counts (1 mm. each) #1 #2 #3 Source Counts (1 mm each) #1 #2 #3 AVG NET cpm YIELD cpm/pCi FOUND pCi SOURCE ID KNOWN pCi M-01/D-21 7/23/2013 129 127 141 10101 10119 10337 10053 0 1708 58860 GS-04 59300 M-01/D-21 7/23/2013 126 127 132 10287 10124 10121 10049 0 1708 58835 GS-04 59300 M-01/D-21 7/24/2013 121 125 132 10249 10138 10216 10075 0 1708 58987 GS-04 59300 M-01/D-21 7/24/2013 133 114 141 10075 10107 10105 9966 0 1708 58351 GS-04 59300 M-01/D-21 7/23/2013 129 127 141 10156 10071 10124 9985 0.1708 58458 GS-05 59300 M-01/D-21 7/23/2013 126 127 132 10230 10152 10179 10059 0 1708 58891 GS-05 59300 M-01/D-21 7/24/2013 121 125 132 10049 9956 10028 9885 0 1708 57875 GS-05 59300 M-01/D-21 7/24/2013 133 114 141 10056 10264 10181 10038 0 1708 58769 GS-05 59300 M-02/D-20 7/23/2013 114 136 122 10135 10248 10290 10100 0.1727 58485 GS-04 59300 M-02/D-20 7/23/2013 128 137 119 10106 10133 10158 10004 0.1727 57929 GS-04 59300 M-02/D-20 7/24/2013 112 125 137 10250 10276 10189 10114 0 1727 58562 GS-04 59300 M-02/D-20 7/24/2013 126 131 112 10236 10199 10226 10097 0 1727 58467 GS-04 59300 M-02/D-20 7/23/2013 114 136 122 10214 10270 10023 10045 0.1727 58164 GS-05 59300 M-02/D-20 7/23/2013 128 137 119 10368 10029 10076 10030 0 1727 58076 GS-05 59300 M-02/D-20 7/24/2013 112 125 137 9967 10295 9911 9933 0.1727 57516 GS-05 59300 M-02/D-20 7/24/2013 126 131 112 10144 10120 10212 10036 0 1727 58110 GS-05 59300 AVERAGE PERCENT BIAS FOR ALL ANALYTICAL SESSIONS -1 5% CHARCOAL CANISTER ANALYSIS SYSTEM SITELOCAnoN^kVV^ Hec^ U ^ ^\^A\vy^ J g T CLIENT- w-g^si r~u t \ S ^•^si?uvT.-g £ Calibration Check Log System ID- NAwO t / -2. ) Calibration Date Due Date. fr/W//^ _ Scaler S/N ^~l9^~2- High Voltage Window 4 42 Thrshld _ 2 20 Detector S/N- O 4<b ^3 Source ID/SN. ^IJ^^^G^'O \f Source Activity £^3£p£» Blank Canister Bkgd Range, cpm: 2o = _ Gross Source Range, cpnr .to. to to Technician-JP — All counts times are one minute. Fbsf Date By Background Counts (1 min each) #1 #2 #3 #1 Source Counts (1 mm each) #2 #3 Average ok'f Y/N J2a JL*L \<=>[Q \ iDon< ! Y/N Y = average background and source cpm falls within the control limits. N = average background and source cpm docs not fall within the control limits. The acceptable ranges were determined from pnor background and source check data. CHARCOAL CANISTER ANALYSIS SYSTEM SITE LOCATION: CT IENT £*ygr^y FVJL-CU Res purees System ID Scaler S/N: ^ Calibration Check Log :M-oi /r> — *Z> I Cahbrahon Date Due Dale gT> ^ 7 ^ High Voltage: J^A_?_ Window: 4,42 Thrshld- 2.20 Detector S/N Q H i^33 Source 1D/SN: ^oP'^/^ " Source Activity. ^« p£« Blank Canister Bkgd Range, cpm: 2 cr - t0 tS 3 a (tP) to (~7 [ Gross Souicc Range, cpm 2 a = tyfo^S _ to lOS*l U 3 a = °)~7 to 10C?7 / Technician* All counts times arc one minute Date Posi- By Background Counts (1 min each) #2 #3 Avg. '1 Source Counts (1 nun, each) #2 #3 Average ok'' Y/N IS • 3 \ 7,7 IQ2.3Q toil Y/N- Y = average background and source cpm falls within the control limits. N - average background and source cpm does not fall within the control limits. The acceptable ranges were determined from prior background and source check data. CHARCOAL CANISTER ANALYSIS SYSTEM SIT E LOCATION. CLIENT £-^-cW^ y Fl/l^ts U(TC<5 System ID rV<? ^/D~ 2X> Scalci S/N S"' 3 Detector S/N Calibration Check Log _ Calibration Date fr/*4/l3 Due Date </ _ High Voltage- |P3-£~ Window. 4 42 Thrshld 2 20 Source ID/SN. Source Activity "78 to tS"l 3<T= UO to L70 Blank Canister Bkgd Range, cpm 2 a = 2a- q^Sq to iOS~-2T7 3a- 3 9 '7 to fiUA Gross Source Range, cpm Technician- Alt counts times are one minute Fbsf rb^T~[7/a^//?" Dale By Background Counts (1 tnin each) #1 #2 #3 Avg. #1 Source Counts (1 mm each) #2 #3 Average ok1' Y/N lite. I-2--Z-10-2.2,^ J3a 113 IQi3X IfX. iX5" 13. LL2=, »23 Y'N Y = average background and source cpm falls within the control limits N = average background and source cpm docs not fall within the control limits. The acceptable ranges were determined from prior background and source check data CHARCOAL CANISTER ANALYSIS SYSTEM SITE LOCATION. CLIEN'I Calibration Check Lop System ID |^"P%/7)-2-0 Calibration Date £/ /M7 * 3 Scaler S/N: Detector S/N ^HlS^^- Blank Canister Bkgd Range, cpm: 2 o = Gross Source Range, cpm DueDatc- /iH High Voltage. jO'ZS' Window 4 42 Thrshld _. 2 20. Source ID/SN Source Activity' .-*>K fQ to IS^( 3a= GC? to <7Q 2a- Technician: qg^k to io- ^^63 to ioU,/ All counts times are one minute Date By Background Counts (1 min each) #2 tf3 Avg. Source Counts (I mm. each) #1 #2 #3 Average ok° Y'N iQ2J' ioxio 12-: -LVX IPOS'?) 5 L^ Y/N: Y = average background and source cpm falls within the control limits. N = average background and source cpm docs not fall within the control limits. The acceptable ranges were determined Gom prior background and source check data. BALANCE OPERATION DAILY CHECK Balance Model: O hqut^, Vor^ ~ O ~ <g m Wi Standard Weight (g): Q-OQ • Q ^ Date Pre-check (g) TOO, O Post-check (g) O.K. ± 0.1 % ? y^s By Appendix B Recount Data Analyses B CLIENT- ENERGY FUELS RESOURCES PROJECT: RADON FLUX MEASUREMENTS, WHITE MESA MILL PROJECT NO.: 13004 00 PILE. 2 BATCH: G SURFACE" SOIL AIR TEMP MIN: 66°F WEATHER. RAINED 0.01 in. AFTER PLACEMENT AREA-COVER DEPLOYED. 7 22 13 RETRIEVED: 7 23 13 CHARCOAL BKG. 148 cpm Wt. Out. 180.0 g. FIELD TECHNICIANS: TE.DLC COUNTED BY: DLC DATA ENTRY BY: DLC TARE WEIGHT 29.2 g. COUNTING SYSTEM I.D.: M01/D21, M02/D20 CAL DUE: 6/14/14 GRID SAMPLE RETRIV ANALYSIS MID-TIME CNT GROSS GROSS RADON + LLD PRECISION LOCATION I. D. HR MIN HR MIN MO DA YR HR MIN (MIN) COUNTS WT IN pCi/m2s pCi/m2s pCi/m2s % RPD G10 RECOUNT G20 RECOUNT G3 0 RECOUNT G40 RECOUNT G50 RECOUNT G60 RECOUNT G70 RECOUNT G80 RECOUNT G90 RECOUNT GlOO RECOUNT G10 G10 G20 G20 G3 0 G30 G4 0 G40 G50 G50 G60 G60 G70 G70 G80 G80 G90 G90 GlOO GlOO 8 8 8 8 8 8 9 9 9 9 10 10 10 10 10 10 11 11 15 15 32 32 52 52 20 20 40 40 1 1 10 15 10 15 33 33 54 54 12 12 8 8 8 8 8 8 8 8 9 9 9 9 9 9 9 9 9 9 10 10 24 24 36 36 46 46 55 55 0 0 11 11 19 19 33 33 57 57 19 19 7 23 13 20 7 24 13 7 7 23 13 20 7 24 13 7 23 13 24 13 7 23 13 7 24 13 23 13 24 13 20 7 20 7 7 23 13 20 7 24 13 7 23 13 20 24 13 7 7 23 13 20 7 24 13 7 20 7 7 23 13 21 7 24 13 7 23 24 13 13 21 7 2 7 10 7 17 8 25 8 34 10 41 10 49 11 59 12 8 16 16 16 33392 31264 17493 15848 12394 11688 1500 1371 34097 32075 28247 26092 5590 5501 1560 1478 1072 1006 1835 1719 226 .1 226 .1 222 .3 222 .3 223 .5 223 .5 223 .1 223 .1 226.5 226 .5 220 . 9 220 . 9 224 .7 224 .7 224 .5 224 .5 220.8 220 .8 225.5 225 .5 51.1 52 . 0 26.7 26.3 19.0 19 .4 53.8 54 . 8 44.8 44 . 8 1.0 1.0 0.6 0.6 1.2 1.2 5.1 5.2 2.7 2 . 6 1 . 9 1.9 0.2 0.2 5.4 5.5 4.5 4 . 5 0.9 0.9 0 .1 0.1 0.1 0.1 0.1 0.1 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0. 03 0.03 0.03 0.03 0.03 0.03 0.03 1.7* 1.5s 2 .1% 0.0'- 1. 8% 0. 0s 6 . 7! 0 . 0% 0 . 0% 0 . 0! AVERAGE PERCENT PRECISION FOR THE CELL 2 COVER REGION: 1.4% Page 1 of 1 Appendix C Radon Flux Sample Laboratory Data (including Blanks) CLIENT: ENERGY FUELS RESOURCES PROJECT: RADON FLUX MEASUREMENTS, WHITE MESA MILL PILE: 2 BATCH: G SURFACE: SOIL AREA: COVER DEPLOYED: 7 22 13 RETRIEVED: 7 FIELD TECHNICIANS: TE.DLC COUNTED BY. DLC COUNTING SYSTEM ID.: M01/D21, M02/D20 CAL. DUE: 6/14/14 AIR TEMP MIN:66°F 23 13 CHARCOAL BKG: DATA ENTRY BY: DLC GRID LOCATION G01 G02 G03 G04 G05 G06 G07 G08 G09 GIO Gil G12 G13 G14 G15 G16 G17 G18 G19 G20 G21 G22 G23 G24 G25 G26 G27 G28 G29 G30 G31 G32 G33 G34 G35 G36 G37 SAMPLE DEPLOY RETRIV ANALYSIS MID-TIME CNT GROSS I. D. HR MIN HR MIN MO DA YR HR MIN (MIN) COUNTS G01 G02 G03 G04 G05 G06 GO 7 G08 G09 GIO Gil G12 G13 G14 G15 G16 G17 G18 G19 G20 G21 G22 G23 G24 G25 G26 G27 G28 G29 G30 G31 G32 G33 G34 G35 G36 G37 3 4 5 7 8 9 11 12 13 15 16 17 19 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 55 6 9 11 13 15 16 20 20 21 21 22 22 22 23 23 24 24 25 25 26 26 32 33 34 35 36 37 38 38 39 39 43 44 45 46 46 47 48 49 50 52 53 53 23 23 23 7. 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 13 19 13 19 13 19 13 19 13 19 13 19 13 20 13 20 13 13 20 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 55 55 56 56 59 59 1 1 2 2 4 4 5 5 7 7 8 8 10 10 11 11 13 13 14 14 16 16 17 17 19 19 20 20 22 22 23 2223 17910 1594 25307 1451 1156 3364 17178 2259 33392 15520 44760 18072 14898 6841 5042 30632 26242 23532 17493 31494 26093 20297 20330 34547 1572 22155 14091 65936 12394 22913 19664 28965 3496 17863 27663 17349 Page 1 of 3 PROJECT NO 13004.00 WEATHER: RAINED 0.01 in. AFTER PLACEMENT 148 cpm WtOut 180.0 g TARE WEIGHT- 29.2 g. WT IN pCi/m2s pCi/m2s pCi/m2s COMMENTS: 219 .0 220.5 221.9 227 .2 222 .2 220 . 8 224 225 229 226 221 226 224 227 222 .6 223 .4 224 220 222 222 231 226 223 225 220 223 230 222 . 0 216 .0 223 235 227 221 225 223 220 227 3 27 2 38 0 1 4 26 3.2 51.1 23 . 7 68 .6 27.7 22 .7 10 7 47 40 36 26 48 40 31 31 53 2.2 34.1 21.6 102 . 0 19.0 35.4 30.5 45.1 5.2 27.8 43 .1 27 . 0 0.3 2.7 0.2 3.9 0.1 0.2 0.5 2.6 0. 5 . 2 . 6 . 2 . 2 . 1. 0. 4 . 4 . 3 . 2 . 4 . 4 . 3 . 3 5, 0 3 2 , 10 1 3 3 4 0 2 4 2 0.03 0.03 0.03 0.03 0 . 03 0.03 0.03 0 . 03 0 .03 0.03 0 . 03 0.03 0.03 0. 03 03 03 0.03 0.03 0 . 03 0.03 0.03 0.03 0.03 0.03 0. 03 0 . 03 0 . 03 0.03 0.03 0.03 0 . 03 0 . 03 0.03 0 . 03 0.03 0.03 0.03 NEW COVER NEW COVER NEW COVER NEW COVER NEW COVER NEW COVER CLIENT: ENERGY FUELS RESOURCES PROJECT: RADON FLUX MEASUREMENTS, WHITE MESA MILL PROJECT NO 13004.00 PILE: 2 BATCH. G SURFACE. SOIL AREA: COVER DEPLOYED. 7 22 13 RETRIEVED: 7 FIELD TECHNICIANS: TE.DLC COUNTED BY: DLC COUNTING SYSTEM I.D.: M01/D21, M02/D20 CAL. DUE: 6/14/14 AIR TEMP MIN:66°F 23 13 CHARCOAL BKG: DATA ENTRY BY- DLC WEATHER: RAINED 0.01 in. AFTER PLACEMENT 148 cpm WtOut. 180 0 g. TARE WEIGHT: 29.2 g GRID LOCATION G38 G39 G40 G41 G42 G43 G44 G45 G46 G47 G48 G4 9 G50 G51 G52 G53 G54 G55 G56 G57 G58 G59 G60 G61 G62 G63 G64 G65 G66 G67 G68 G69 G70 G71 G72 G73 G74 SAMPLE I . D. G38 G39 G40 G41 G42 G43 G44 G45 G46 G47 G48 G49 G50 G51 G52 G53 G54 G55 G56 G57 G58 G59 G60 G61 G62 G63 G64 G65 G66 G67 G68 G69 G70 G71 G72 G73 G74 DEPLOY RETRIV ANALYSIS MID-TIME CNT GROSS GROSS RADON + LLD HR MIN HR MIN MO DA YR HR MIN (MIN) COUNTS WT IN pCi/m2S pCi/m2S pCi/m2 s COMMENTS: 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 17 19 20 22 25 27 30 32 33 35 37 38 40 41 42 44 46 49 52 55 57 59 1 2 4 5 7 8 10 12 13 14 15 17 18 20 21 54 54 55 55 55 56 56 57 57 59 59 0 0 1 1 2 2 3 8 9 10 10 11 12 12 13 13 14 14 16 17 18 19 20 20 21 22 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 13 20 23 25 25 26 27 29 29 31 31 32 32 34 34 35 35 37 37 38 38 40 40 41 41 43 43 44 44 46 46 47 47 49 49 50 50 52 52 1151 33840 1500 5006 1803 1580 43887 129362 5075 35586 51920 10681 34097 9463 19139 2790 19755 3371 72076 28670 10767 8930 28247 5399 5409 2815 22450 16807 31945 22125 2928 4927 5590 22122 21712 20576 12875 224 .3 223 .4 223 .1 225 .3 222 .8 225.9 225 . 0 227.4 220 .1 223 .8 227 . 8 224 226 . 221. 221, 222 216 227 224 , 222 .4 223 .1 221.6 220.9 222 . 8 222 .5 223 . 223 . 221 . 217. 221. 225 . 223 . 224 . 225 . 220.8 229.8 226.5 1.6 53.0 2.1 7.6 1.2 0.2 5.3 0.2 0.8 1 69 204 7 56 81 16 30 4 31 5 114 45 16 14 44 8 8 4 35 26 50 35 4 53.8 14 . 8 1 2 2 1 2 4 9 0 8 4 4 3 7 ,7 .9 ,2 ,5 7.7 8.7 35.3 34 .6 32 .8 20.4 0 0 6 , 20 0 5 8 . 1 5 1 3 0.4 3.1 0 11, 4 , 1 , 1 4 0 0.8 0.8 0.03 0.03 0.03 0.03 0.03 0 . 03 0.03 0 .03 0.03 0.03 0.03 0.03 0.03 0.03 0 . 03 0.03 0 . 03 0.03 0.03 0 . 03 0. 03 0 . 03 0 . 03 0 . 03 0.03 0.03 0.03 0 .03 0 . 03 0 . 03 0.03 0 . 03 0 . 03 0.03 0.03 0.03 0.03 NEW COVER NEW COVER NEW COVER NEW COVER NEW COVER NEW COVER NEW COVER Page 2 of 3 CLIENT". ENERGY FUELS RESOURCES PROJECT. RADON FLUX MEASUREMENTS, WHITE MESA MILL PROJECT NO: 13004.00 PILE: 2 BATCH. G SURFACE: SOIL AREA. COVER DEPLOYED: 7 22 13 RETRIEVED. 7 FIELD TECHNICIANS: TE.DLC COUNTED BY: DLC COUNTING SYSTEM I.D.: M01/D21, M02/D20 CAL. DUE: 6/14/14 AIR TEMP MIN: 66°F 23 13 CHARCOAL BKG. DATA ENTRY BY: DLC WEATHER: RAINED 0.01 in AFTER PLACEMENT 148 cpm Wt.Out: 180.0 g. TARE WEIGHT: 29.2 g LOCATION G75 G76 G77 G78 G79 G80 G81 G82 G83 G84 G85 G86 G87 G88 G89 G90 G91 G92 G93 G94 G95 G96 G97 G98 G99 GlOO SAMPLE DEPLOY RETRIV ANALYSIS MID-TIME CNT GROSS GROSS RADON + LLD I. D. HR MIN HR MIN MO DA YR HR MIN (MIN) COUNTS WT IN pCi/m2 s pCi/m2 s pCi/m2 s COMMENTS: G75 G76 G77 G78 G79 G80 G81 G82 G83 G84 G85 G86 G87 G88 G89 G90 G91 G92 G93 G94 G95 G96 G97 G98 G99 GlOO 10 23 10 24 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 11 11 11 11 11 11 11 27 29 31 33 35 37 39 40 42 44 10 46 10 47 52 54 56 58 59 1 3 5 7 10 11 12 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 10 10 10 10 10 10 10 10 10 23 24 25 27 30 33 35 38 40 42 44 46 47 48 55 57 59 2 4 6 8 10 12 13 17 19 23 13 23 20 23 13 23 13 13 20 20 23 13 23 13 23 13 23 13 20 20 20 21 21 13 21 23 23 13 21 23 13 21 23 13 21 23 13 21 23 13 21 21 23 13 23 13 23 23 23 13 23 13 23 23 13 23 13 23 13 23 13 23 13 21 13 21 13 21 21 21 13 21 21 21 21 21 21 53 53 56 56 58 59 1 2 3 3 5 5 6 6 8 8 10 10 11 11 13 13 14 14 15 16 1276 1329 1039 1693 3081 1560 6511 11302 15451 1971 3945 8880 3373 5095 10504 1072 1448 1876 6725 2873 1528 1585 14785 2721 1327 1835 223 227 230 227 220 . 0 224 .5 226.9 221.7 222 .6 222 .8 226 .4 223 .2 223 .6 222.1 218 .6 220 . 8 227 .1 223 209 230 226 220 229 221 230 225 1 1 0 2 4 1 10 17 .9 24 .6 14 . 0 5.2 7, 16, 0, 2 , 2.8 10.5 4.3 2 2 23, 4 1 1 0.8 1.7 0.4 0.2 0.1 0.03 0.03 0.03 0 . 03 0 . 03 0.03 0.03 0.03 0.03 0.03 0 . 03 0.03 0.03 0 . 03 0 . 03 0.03 0.03 0 . 03 0 . 03 0 . 03 0.03 0 . 03 0.03 0.03 0.03 0.03 AVERAGE RADON FLUX RATE FOR THE CELL 2 COVER REGION: 24.3 pCi/m2s BLANK CANISTER ANALYSIS" LOCATION G BLANK 1 G BLANK 2 G BLANK 3 G BLANK 4 G BLANK 5 SAMPLE G BLANK 1 G BLANK 2 G BLANK 3 G BLANK 4 G BLANK 5 RETRIV ANALYSIS MID-TIME HR MIN HR MIN MO DA YR HR MIN (MIN) COUNTS WT IN pCi/m2 s pCi/m2 s pCi/m2 s COMMENTS 20 20 20 20 20 15 15 15 15 15 23 23 23 23 23 13 13 13 13 13 21 21 21 21 21 25 25 36 36 47 10 10 10 10 10 1533 1451 1489 1378 1501 213.6 209.9 208 . 9 207 . 9 209.6 0. 01 0.00 0 . 00 -0 . 02 0.00 0.02 0.02 0 . 02 0 . 02 0 . 02 0.03 0.03 0.03 0.03 0 . 03 CONTROL CONTROL CONTROL CONTROL CONTROL AVERAGE BLANK CANISTER ANALYSIS FOR THE CELL 2 COVER REGION: 0.00 pCi/m2s Page 3 of 3 Appendix D Sample Locations Map (Figure D EE -CELLI Pb WHITE MESA MILL BLANDING, UTAH NESHAPS 2013 1? (=9 SAMPLE LOCATIONS MAP JULY 2013 -CELL 3 PREPARED FOR ENERGY FUELS RESOURCES LEGEND GOI O SAMPLE LOCATION ON FIGURE 2 -CELL4B -CELL4A reueo ENVIRONMENTAL, LLC