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DRC-2013-003004 - 0901a068803b1833
IH9*> State of Utah GARY R HERBERT Governor GREG BELL Lieutenant Governor Department of Environmental Quality Amanda Smith Executive Director DIVISION OF RADIATION CONTROL Rusty Lundberg Director "DRC-2013-003004" MEMORANDUM TO: Phil Goble Uf ' FROM: Dean Henderson DATE: August 22, 2013 SUBJECT: Review of the 1st Quarter 2013 Nitrate Monitoring Report for the Nitrate Contamination Investigation, Energy Fuels Resources (USA) Inc. ("EFR") White Mesa Uranium Mill, near Blanding, Utah The. Utah Division of Radiation Control ("DRC") has reviewed the May 31, 2013, White Mesa Uranium Mill 1st Quarter 2013 Nitrate Monitonng Report ("Report") for the Nitrate Contamination Investigation. For the review of this Report the following regulatory enforcement documents were used: • Corrective Action Plan for Nitrate White Mesa Uranium Mill near Blanding, Utah, May 7, 2012, ("CAP") • The EFR Quality Assurance Plan, June 7, 2012, Revision. 7.2 ("QAP") REVIEW Monitor Well Sampling The following monitor wells were sampled as required in the CAP (see Table 1 below): TWN-1, TWN-2, TWN-3, TWN-4, TWN-7, TWN-18, TW4-22. TWN-18, TWN-22, TWN-24, TWN-25, Piezometer 1, Piezometer 2, and Piezometer 3. The following monitonng wells were purged using the three approved QAP well purging strategies and meet QAP requirements for each strategy: 1. Purging two casing volumes with stable field parameters for specific conductivity, turbidity, pH, redox potential, and water temperature (within 10% RPD): Wells: TWN-1, TWN-4, and TWN-18. 2. Purging a well to dryness and stability of field parameters for pH, specific conductivity, and water temperature only after recovery: 195 North 1950 West • Salt Lake City, UT Mailing Address P O Box 144850 • Salt Lake City, UT 84114-4850 Telephone (801) 536-4250 • Fax (801) 533-4097 • T D D (801) 536-4414 www deq Utah gov Printed on 100% recycled paper Page 2 Wells: TWN-3 and TWN-7 The water samples for the above wells were analyzed for chloride and nitrate plus nitrite as nitrogen as required in the CAP. Chloride and nitrate plus nitrite as nitrogen were analyzed for methods consistent with the requirements of the QAP. QAQC Holding Times The method holding times for each parameter for samples collected at each monitor well were received and analyzed within the required holding times in the QAP. Receipt Temperature All samples were received within the required QAP temperature limit of 6° C. Detection Limits All sample sets were measured and reported to the required QAP reporting limits. Sample Duplicates One duplicate sample was collected. Well TWN-4 and its duplicate sample TWN-65. All analytical results for the sample/duplicate pair were within the 20% acceptance limits as required in the QAP (see Table 2 below). Groundwater Head Monitoring Depth to groundwater was measured in the following wells and/or piezometers as required in Part I.E.3 of the Permit: - • The quarterly groundwater compliance monitonng wells. • Existing monitoring well MW-4 and all of the temporary chloroform investigation wells. • Piezometers P-l, P-2, P-3, P-4 and P-5. • MW-20, MW-22 and MW-34 • Nitrate monitoring wells. • The DR piezometers which were installed during the Southwest Hydrologic Investigation. • In addition to the above, depth to water measurements are routinely observed in conjunction with sampling events for all wells sampled during quarterly and accelerated efforts, regardless of the sampling purpose. All well levels used for groundwater contour mapping were measured and recorded within 5 calendar days of each other. Estimation of Pumped Nitrate Mass Removal The reported estimated a total of approximately 128 lbs of nitrate was removed from the chloroform pumping wells (MW-4, MW-26, TW4-4, TW4-19, and TW4-20) and the nitrate pumping wells (TWN-2, TW4-22, TW4-24, and TW4-25). Of the 128 lbs removed approximately 107 lbs, or 83%, was removed by the nitrate pumping wells. In Table 3, the DRC shows calculations that verify these reported estimates. V Page 3 Reporting The Report included the following information as required in the CAP: a) Introduction b) Sampling and Monitoring Plan: i. Desenption of monitor wells sampled; ii. Description of sampling methodology, equipment and decontamination procedures; iii. Identification of all quality assurance samples, e.g. equipment blanks duplicate samples, etc. c) Data Interpretation: i. Interpretation of groundwater levels, gradients, and flow directions. The interpretation will include a discussion on: 1) current site groundwater contour map, 2) hydrographs to show groundwater elevation in each monitor well over time, 3) depth to groundwater measured and groundwater elevation from each monitor well summarized in data table that includes historic groundwater level data for each well, 4) calculations documenting quarterly nitrate mass removed by pumping; ii. Interpretation of all analytical results for each well including a discussion on: 1) a current nitrate isoconcentration map, 2) graphs showing nitrate concentration trends in each well through time and, analytical results for each well summarized in data table that includes histonc analytical results for each well; and iii. An electronic copy of all laboratory results for groundwater quality monitoring conducted during the quarter will be provided to the Executive Secretary. d) Conclusions and Recommendations e) Copies of EFR field reports, laboratory reports, and chain of custody forms. The nitrate plume is defined to include any monitoring well that has concentration of nitrate in excess of 10 mg/L. Conclusions on Compliance with the SCA, Permit and QAP Per the DRC review it appears that the Report complies with CAP and QAP. Therefore, a letter will be drafted for the Director Signature, notifying EFR of the review and closing-out of the 1st Quarter 2013 Nitrate Monitoring Report. Page 4 References Energy Fuels Resources (USA) Inc., June 7,2012, White Mesa Uranium Mill, Ground Water Monitoring Quality Assurance Plan (Revision 7.2). HYDRO GEO CHEM, INC, May 7, 2012, Corrective Action Plan for Nitrate White Mesa Uranium Mill near Blanding, Utah Table 1 of 4 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-1 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event TWN-2 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/17/2010 2nd Qtr 5/26/2010 3rd Qtr 9/27/2010 4th Qtr 12/7/2010 1st Qtr 1/26/2011 ' 2nd Qtr 4/20/2011 3rd Qtr 7/26/2011 4 th Qtr 10/17/2011 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 10/17/2012 1st Qtr 2/18/2013 05 0.6 0.6 0.6 0.5 0.5 0.5 0.5 0.6 0.6 0.6 0.43 0.68 17 20 19 14 17 19 14 10 15 17 17 17.5 17.6 1st Qtr 3/24/2010 2nd Qtr 6/2/2010 3rd Qtr 9/29/2010 4th Qtr 12/9/2010 1st Qtr 2/1/2011 2nd Qtr 4/28/2011 3rd Qtr 7/28/2011 4th Qtr 10/20/2011 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/31/2012 4th Qtr 7/17/2012 1st Qtr 2/19/2013 62.1 69 69 _48 "'"'43 40 33 ,„,r33; 31 48 54 22.10 "573 85 97 104 93 " 93 85 74 76 "86 103 93 79 80.5 Monitoring Event TWN-3 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event TWN-4 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/25/2010 2nd Qtr 6/3/2010 3rd Qtr 7/16/2010 4th Qtr 12/10/2010 1st Qtr 2/1/2011* 2nd Qtr 4/28/2011 3rd Qtr 7/29/2011 4th Qtr 10/20/2011 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/31/2012 4th Qtr 10/17/2012 1st Qtr 2/19/2013 ' 25.3 26 27 m 24: """24" 26 25 25 25 24 27 12.1 T£2 111 118 106 117 138 128 134 129 "l43 152 158 149 157 1st Qtr 3/16/2010 2nd Qtr 5/27/2010 3rd Qtr 9/27/2010 4th Qtr 12/8/2010 1st Qtr'l/25/2011 2nd Qtr 4/20/2011 3rd Qtr 7/26/2011 4th Qtr 10/18/2011 1st Qtr 1/9/2012 ' 2nd Qtr4/18/2012 3rd Qtr 7/25/2012 4th Qtr 7/15/2012 1st Qtr 2/18/2013 0.9 1.0 0.9 1.0 0.9 0.9 1.1 0.9 "b'.9 1.1 1.4 1.45 1.5 22 22 19 21 " 21 21 35 20 20 24 25 26.4 25.3 TWN-5 Monitoring Event Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) TWN-6 Monitoring Event Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/16/2010 2nd Qtr 5/26/2010 3rd Qtr 7/12/2010 4th Qtr 12/7/2010 1st Qtr 1/25/2011 2nd Qtr 4/20/2011 3rd Qtr 7/26/2011 4th Qtr 10/17/2011 1st Qtr 1/9/2012 ' 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 10/15/2012 1st Qtr 2013 <0.1 NA 0.3 0.3 0.3 0.3 0.4 0.3 0.3 0.3 0.2 0.3 0.3 43 44 43 45 47 44 44 45 45 39 48 43.5 1st Qtr 3/23/2010 2nd Qtr 6/1/2010 3rd Qtr 7/13/2010 4th Qtr 12/7/2010 1st Qtr 1/26/2011 2nd Qtr 4/20/2011 3rd Qtr 7/27/2011 4th Qtr 10/18/2011 1st Qtr 1/10/2012 2nd Qtr 4/18/2012 3rd Qtr 7/25/2012 4th Qtr 7/15/2012 1st Qtr 2013 1.5 1.4 1.4 1.2 1.1 1.5 11 1.4 " 1.2 1.1 1.4 0.78 19 22 73 21 18 22 17 21 "20 22 22 20.4 NA Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/l NA = Per the CAP and SCO, these wells not sampled 2013 Table 2 of 4 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-7 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event TWN-8 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/17/2010 2nd Qtr 5/28/2010 3rd Qtr 7/14/2010 4th Qtr 12/10/2010 1st Qtr 1/27/2011 2nd Qtr 4/21/2011 3rd Qtr 7/29/2011 4th Qtr 10/19/2011 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 3rd Qtr 7/26/2012 4th Qtr 10/16/2012 1st Qtr 2/19/2013 0.8 1.2 1.8 1 1.3 1.7 0.7 2.2 " 2.3 1.2 0.9 0.64 0.59 6 6 7 4 6 6 5 6 5 6 6 5.67 5.68 1st Qtr 3/16/2010 2nd Qtr 5/26/2010 3rd Qtr 7/12/2010 4th Qtr 12/7/2010 1st Qtr 1/25/2011 2nd Qtr 4/19/2011 3rd Qtr 7/26/2011 4th Qtr 10/17/2011 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 7/15/2012 1st Qtr 2013 <0.1 <0.1 <0.1 <0.1 <o.i <0.1 <0.1 <0.1 <"6.1 <0.1 <0.1 <0.1 NA ' 11 11 11 9 ' 13 10 18 10 11 15 11 11.4 Monitoring Event TWN-9 Monitoring Event Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) TWN-10 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/23/2010 2nd Qtr 6/1/2010 3rd Qtr 7/15/2010 4thi Qtr 12/9/2010 lstQtr 2/1/2011 2nd Qtr 4/28/2011 3rd Qtr 7/29/2011 4th Qtr 10/20/2011 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/31/2012 4th Qtr 10/17/2012 1st Qtr 2013 7.6 7.7 10.7 8.0 9.5 10.0 11.0 10.9 12.2 10.6 123 12.5 NA 183 175 210 172 217 192 208 134 202 209 215 194 lstQtr 3/23/2010 2nd Qtr 6/2/2010 3rd Qtr 7/14/2010 4th Qtr 12/8/2010 1st Qtr 1/26/2011 " 2nd Qtr 4/21/2011 3rd Qtr 7/27/2011 4th Qtr 10/18/2011 1st Qtr i/10/2012 2nd Qtr 4/19/2012 3rd Qtr 7/25/2012 4th Qtr 7/16/2012 1st Qtr 2013 1.5 1.0 0.2 1.3 0.3 1.2 0.1 0.2 0.8 0.9 0.6 0.12 54 30 21 28 *40 28 28 33 44 28 33 30.8 NA Monitoring Event TWN-11 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event TWN-12 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/17/2010 2nd Qtr 6/1/2010 3rd Qtr 9/27/2010 4th Qtr 12/8/2010 1st Qtr1/27/2011 ' 2nd Qtr 4/26/2011 3rd Qtr 7/27/2011 4th Qtr 10/17/2011 1st Qtr 1/10/2011 2nd Qtr 4/19/2012 3rd Qtr 7/25/2012 4th Qtr 10/16/2012 lstQtr 2013 1.4 1.3 1.4 1.4 1.4 1.4 01 1.6 1.6 1.6 1.8 1.84 73 72 76 72 ' 84 76 76 76 " 6$ 71 77 76.4 NA 1st Qtr 3/17/2010 2nd Qtr 5/26/2010 3rd Qtr 7/12/2010 4th Qtr 12/7/2010 1st Qtr'l/26/2011 2nd Qtr 4/26/2011 3rd Qtr 7/26/2011 4th Qtr 10/17/2011 1st Qtr 1/10/2012 2nd Qtr 4/18/2012 3rd Qtr 7/25/2012 4th Qtr 7/16/2012 1st Qtr 2013 0.7 0.8 0.7 0.7 4.2 1.0 0.6 1.2 '0.$ 12 1.4 1.41 113 106 112 103 87 109 102 87 104 106 102 101 NA Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/l NA = Per the CAP and SCO, these wells not sampled 2013 Table 3 of 4 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-13 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event TWN-14 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/17/2010 2nd Qtr 5/26/2010 3rd Qtr 9/27/2010 4th Qtr 12/7/2010 lstQty1/25/2011™ 2nd Qtr4/26/2011 3rd Qtr 7/26/2011 4th Qtr 10/17/2011 1st Qtr 1/9/2012 2nd Qtr 4/18/2012 3rd Qtr 7/24/2012 4th Qtr 10/15/2012 1st Qtr 2013 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 NA 0.1 0.2 0.4 1.6 0.1 0.1 47 49 53 57 "l03 49 49 48 46 53 48 47.3 1st Qtr 3/24/2010 2nd Qtr 6/2/2010 3rd Qtr 7/15/2010 4th Qtr 12/10/2010 1st Qtr 1/28/2011 2nd Qtr 4/27/2011 3rd Qtr 7/29/2011 4th Qtr 10/19/2011 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 7/17/2012 1st Qtr 2013 2.9 2.9 3.5 4.2 3.7 3.5 3.5 3.9 3.5 3.4 3.7 4.03 24 30 26 28 24 30 25 27 26 27 27 27.4 NA Monitoring Event TWN-15 Monitoring Event TWN-16 Nitrate, Nitrate + Chloride (mg/l) Nitrate, Nitrate + Chloride (mg/l) 1st Qtr 3/18/2010 4th Qtr 12/9/2010 1st Qtr 1/27/2011 2nd Qtr 4/27/2011 3rd Qtr 7/28/2011 4th Qtr 10/19/2011 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 3rd Qtr 7/26/2012 4th Qtr 10/17/2012 1st Qtr 2013* 0.7 L0 43 39 1.0 1.2 1.4 1.6 1.6 1.3 1.5 1.6 2.1 1.79 36 38 "43 49 47 38 38 46 50 47 NA 1st Qtr 3/17/2010 2nd Qtr 5/27/2010 3rd Qtr 9/27/2010 4th Qtr 12/9/2010 1st Qtr 1/27/2011 2nd Qtr 4/27/2011 3rd Qtr 7/27/2011 4th Qtr 10/18/2011 1st Qtr l/10/20i2 2nd Qtr 4/19/2012 3rd Qtr 7/25/2012 4th Qtr 7/16/2012 1st Qtr 2013 1.2 35 1.3 ""2.6 [ 2 4.6 1.6 2.4 2.6 2.8 2.0 2.4 2.50 35 ""35 30 "34 39 31 34 "33 50 33 32.1 NA Monitoring Event TWN-17 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event TWN-18 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/24/2010 .?n^Qtr 6/3/2010 3rd 01^7715^010"* 4th Qtr 12/10/2010 1st Qtr 2/1/2011 2nd Qtr 4/28/2011 3rd Qtr 7/29/2011 4th Qtr 10/20/2011 1st Qtr 1/12/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 10/17/2012 1st Qtr 2013 10.4 _ 8.9 8 8.6 9 8.5 8.1 8.7 9.1 9.5 9.65 78 87 66 65 90 81 74 71 79 80 85 84 8 NA 1st Qtr 3/17/2010 2nd Qtr 6/1/2010 3rd Qtr 9/27/2010 4th Qtr 12/9/2010 1st Qtr 1/27/2011 2nd Qtr 4/26/2011 3rd Qtr 7/28/2011 4th Qtr 10/18/2011 1st Qtr 1/10/2012 2nd Qtr 4/19/2012 3rd Qtr 7/26/2012 4th Qtr 7/16/2012 1st Qtr 2/18/2013 ' 1.6 1.8 1.8 1.6 1.4 1.8 1.8 1.9 1.9 2.1 2.3 1.95 2 27 42 63 64 59 61 67 65 60 ""64 64 67 67.5 68.7 Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/l NA = Per the CAP and SCO, these wells not sampled 2013 Table 4 of 4 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations Nitrate Contamination Investigation White Mesa Uranium Mill Denision Mines Corp. Monitoring Event TWN-19 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event Upper Wildlife Pond (UMLP) Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) IltQtr3/23/2010„ 4 th Qtr12/9/2010 1st Qtr 2/1/2011 2nd Qtr 4/28/2011 3rd Qtr 7/28/2011 4th Qtr 10/18/2011 1st Qtr 1/10/2012 2nd Qtr 4/19/2012 3rd Qtr 7/26/2012 4th Qtr 10/16/2012 1st Qtr 2013 7.2 6.2 7.2 7-0 "7.O 6.9 7.1 6.5 7.0 6.8 7.5 7.7 118 113 113 107 114 120 113 108 114 117 117 118 NA 1st Qtr 3/18/2010 2nd Qtr 6/2/2010 3rd Qtr 7/19/2010 4th Qtr 12/10/2010 1st Qtr 1/31/2011 2nd Qtr 4/25/2011 3rd Qtr 7/25/2011 4th Qtr 10/19/2011 1st Qtr 1/31/2012 2nd Qtr 2012 3rd Qtr 2012 4th Qtr 2012 1st Qtr 2013 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 NS NS NS NA 0.1 0.1 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NS NS NS Monitoring Event Piezometer 1 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event Piezometer 2 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) lstQtr2010 3rd"c^ 771972616"" 4th Qtr 12/10/2010 1st Qtr 1/31/2011 2nd Qtr 4/25/2011 3rd Qtr 7/25/2011 4th Qtr 10/19/2011 1st Qtr 1/11/2012 1st Qtr 1/10/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 10/17/2012 1st Qtr 2/19/2013 NS NS 7.2 6.8 6.5 7 6.8 7 6.6 7.1 7.0 6.6 7.2 7.66 8.11 52 52 60 *60 58 53 55 78 114 58 56 55 56.7 lstQtr2010 2nd"dVr"67272qio"" 3"rdQtr"77lWor6" 4th Qtr 12/10/10 1st Qtr 1/31/2011 2nd Qtr 4/25/2011 3rd Qtr 7/25/2011 4th1 Qtr 10/19/2011 1st Qtr 1/11/2012 1st Qtr 1/31/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 7/17/2012 1st Qtr 2/19/2013 ' NS NS 0.6 0.6 0.2 0.3 0.3 0.1 0.1 " 0.1 0.1 0.2 0.2 0.19 0.22 8 8 6 *9 8 9 8 *9 1 8 9 9.5 9.67 Monitoring Event Piezometer 3 Nitrate, Nitrate + Nitrite (mg/i) Monitoring Event Chloride (mg/l) Pond D Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 3/24/2010 .2nlP^r„6/2/iPi?.„. 3rd"Qtr 7/19/2016"" 4th Qtr 12/9/2010 1st Qtr 1/31/2011 2nd Qtr 4/25/2011 3rd Qtr 7/25/2011 4th Qtr 10/19/2011 1st Qtr 1/11/2012 2nd Qtr 4/20/2012 3rd Qtr 7/27/2012 4th Qtr 10/17/2012 1st Qtr 2/19/2013 1.7 1.6 1.8 1.8 I-8 1.7 1.8 1.7 1.8 1.7 1.8 2.75 1.85 116 36 35 25 40 35 61 12 20 53 21 20.1 21 1st Qtr 2010 2ndQtr2010 3rdQtr2010 4th Qtr 2010 1st Qtr 1/31/2011 2nd Qtr 2011 3rd Qtr 2011 4th Qtr 2011 1st Qtr'2OI2 2nd Qtr 2012 3rd Qtr 2012 4th Qtr 2012 1st Qtr 2013 NS NS NS NS NS NS NS NS NS NS NS NA 0.1 NS NS NS NS NS NS NS NS NS NS NS Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/l NS = Not sampled NA = Per the CAP and SCO, these wells not sampled 2013 Monitoring Event TW4-22 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) Monitoring Event TW4-24 Nitrate, Nitrate + Nitrite (mg/l) Chloride (mg/l) 1st Qtr 2/11/2013 635 1st Qtr 2/11/2013 1,260 Monitoring Event TW4-25 Nitrate, Nitrate + Nitrite (mg/l) lstQtr 2/11/2013 Chloride (mg/l) 190 Table 2 Summary of QA/QC Duplicate Sample 1st Quarter 2013 Parameter GWQS Duplicate of TWN 4 TWN-4 TWN-65 RPD Nitrate + Nitrite (as N) Chloride 10 mg/L none 1.51 25.3 1.51 25.9 0.0 -2.3 Tabel 3 DRC Nitrate Mass Removal Calculations Energy Fuels Resorses Inc. White Mesa Mill, Bland, Utah 1st Quarter 2013 Data Discriptions MW4 Chloroform Pumping Wells MW-26 TW4-4 TW4-19 TW4-20 TWN-2 Nitrate Pumping Wells TW4-22 TW4-24 TW4-25 Nitrate (mg/L) 1st Quarter 2013 Nitrate (g/L) Nitrate (Ibs/L) Nitrate (lbs/gal) Total gallons pumped 1st qtr 2013 lbs of nitrate removed Gallons of nitrate removed 4.8 4.80E-03 1.06E-05 4.01 E-05 62,944 2.53 0.21 2.3 2.30E-03 5.08E-06 1.92E-05 22,651 0.44 0.04 7.4 7.40E-03 1.63E-05 6.19E-05 58,717 3.63 0.30 8.0 8.00E-03 1.77E-05 6.69E-05 210,908 14.11 1.15 9.1 9.1 OE-03 2.01 E-05 7.61 E-05 18,177 1.38 0.11 57.3 5.73E-02 1.27E-04 4.79E-04 99,370 47.62 3.87 58.0 5.80E-02 1.28E-04 4.85E-04 16,677 8.09 0.66 35.9 3.59E-02 7.93E-05 3.00E-04 144,843 43.49 3.54 9.0 9.00E-03 1.99E-05 7.53E-05 99,370 7.48 0.61 Total lbs of nitrate removed from chloroform pumping wells Total gallons of nitrate removed chloroform pumping wells 22.09 1.80 Total lbs of nitrate removed from nitrate pumping wells Total gallons of nitrate removed nitrate pumping wells 106.67 8.68 Total lbs of nitrate removed from from all pumping wells Total gallons of nitrate removed from all pumping wells % lbs of nitrate removed by nitrate pumping wells 128.76 10.48 82.8