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HomeMy WebLinkAboutDRC-2013-002202 - 0901a0688037b1bcENERGY FUELS Energy Fads Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 3039742140 www.enerpvfuels.com II DRG-2013-002202 II Mr. Rusty Lundberg Director Division of Radiation Control Utah Department of Environmental Quality 195 North 1950 West P.O. Box 144850 May 7,2013 Sent VIA OVERNIGHT DELIVERY Salt Lake City, UT 84114-4820 Re: Transmittal of Source Assessment Report for Total Dissolved Solids in MW-29 White Mesa Mil] Groundwater Discharge Permit UGW370004 Conditional Approval of December 13,2012 Plan and Time Schedule Dear Mr. Lundberg: Enclosed are two copies of Energy Fuels Resource (USA) Lie's ("EFRTs") Source Assessment Report ("SAR") for Total Dissolved Solids ("TDS") in MW-29 at the White Mesa Mill. TDS in MW-29 exceeded its Groundwater Compliance Limit ("GWCL") in the second and third quarter of 2012. As required by Part I.G.4(d) of the Groundwater Discharge Permit ("GWDF"), EFRI submitted a Plan and Time Schedule for the assessment of TDS in MW-29 on December 13, 2012. Conditional Approval of the Plan and Time Schedule was received by EFRI on February 7, 2013. Pursuant to the Plan and Time Schedule EFRI has prepared this SAR. This transmittal also includes two CDs each containing a word searchable electronic copy of the report. If you should have any questions regarding this report please contact me. Yours very truly, ENERGY FUELS RESOURCES (USA) INC. Jo Ann Tischler Manager, Compliance and Licensing CC: David C. Frydenlund Harold R. Roberts David E. Turk Katherine A. Weinel SOURCE ASSESSMENT REPORT FOR TDS IN MW-29 WHITE MESA URANIUM MILL Blanding, Utah Prepared for: 225 Union Boulevard, Suite 600 Lakewood, CO 80228 Prepared by: 6000 Uptown Boulevard NE, Suite 220 Albuquerque, New Mexico 87110 May 7, 2013 Google 2009 Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah ES-i May 7, 2013 EXECUTIVE SUMMARY This report is an assessment of the sources, extent, and potential dispersion of the specific constituents at Energy Fuels Resources (USA) Inc.’s White Mesa Mill Site which have exhibited two consecutive exceedances of their respective Groundwater Compliance Limits (“GWCLs”). This report also provides an evaluation of potential remedial action to restore and maintain groundwater quality to ensure that Groundwater Discharge Permit (“GWDP”) limits will not be exceeded at the compliance monitoring point and that, to the extent applicable, discharge minimization technology and best available technology will be reestablished. Given the recent analyses performed by INTERA Incorporated and other analyses and investigations at the site, and as the results of the geochemical analysis will demonstrate, the exceedances of total dissolved solids in MW-29 can be attributed to (1) natural background conditions, and (2) the small sample size of the data set used to calculate the original GWCL in Revised Addendum: Background Groundwater Quality Report: New Wells for Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah (INTERA, 2008). Therefore, a revised GWCL has been proposed, which is based on all available data to date and has been calculated in accordance with the Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site, San Juan County, Utah (“Flowsheet”), which is included as an appendix to this Source Assessment Report. Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah i May 7, 2013 TABLE OF CONTENTS EXECUTIVE SUMMARY ........................................................................................................... i LIST OF TABLES ........................................................................................................................ ii LIST OF FIGURES ...................................................................................................................... ii LIST OF APPENDICES .............................................................................................................. ii ABBREVIATIONS AND ACRONYMS .................................................................................... iii 1.0 INTRODUCTION............................................................................................................. 1 1.1 Constituents and Wells Subject to this Report ........................................................ 3 1.2 Source Assessment Report Layout ......................................................................... 3 2.0 CATEGORIES AND APPROACH FOR ANALYSIS .................................................. 4 2.1 Approach for Analysis ............................................................................................ 4 2.1.1 Other Constituents and Wells .................................................................... 5 2.2 Approach for Setting Revised GWCLs ................................................................... 6 3.0 RESULTS OF ANALYSIS............................................................................................... 7 3.1 Other Constituents and Wells ................................................................................. 7 3.1.1 Total Dissolved Solids ............................................................................... 7 4.0 CONCLUSIONS AND RECOMMENDATIONS .......................................................... 9 5.0 REFERENCES ................................................................................................................ 10 Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah ii May 7, 2013 LIST OF TABLES Table 1 Summary of Findings .............................................................................................. 9 LIST OF FIGURES Figure 1 Location of White Mesa Mill Site Figure 2 Location of Groundwater Monitoring Wells LIST OF APPENDICES Appendix A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Appendix B Geochemical Analysis for TDS in MW-29 B-1 Summary of Geochemical Analysis for TDS in MW-29 B-2 Comparison of Calculated and Measured TDS in MW‐29 B-3 Charge Balance Calculations for Major Cations and Anions in MW‐29 B-4 Descriptive Statistics for TDS in MW-29 B-5 Box Plot for TDS in MW‐29 B-6 Histogram for TDS in MW‐29 B-7 Linear Regressions of TDS in MW‐29 Appendix C Geochemical Analysis for Indicator Parameters in MW-29 C-1 Summary of Geochemical Analysis for Indicator Parameters in MW-29 C-2 Descriptive Statistics for Indicator Parameters in MW-29 C-3 Data Omitted from Statistical Analysis C-4 Box Plots for Indicator Parameters in MW‐29 C-5 Histograms for Indicator Parameters in MW‐29 C-6 Linear Regressions for Normally or Lognormally Distributed Indicator Parameters in MW‐29 C-7 Mann-Kendall Analysis for Indicator Parameters Not Distributed Normally or Lognormally Appendix D Time Concentration Plot Comparison D-1 Time Concentration Plot Comparison for TDS in MW-29 D-2 Time Concentration Plots Comparison for Indicator Parameters in MW-29 Appendix E Flowsheet (Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site (INTERA, 2007a)) Appendix F Input and Output Files (Electronic Only) Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah iii May 7, 2013 ABBREVIATIONS AND ACRONYMS Director Director of the Division of Radiation Control DRC State of Utah Division of Radiation Control EFRI Energy Fuels Resources (USA) Inc. GWCL Groundwater Compliance Limit GWDP State of Utah Ground Water Discharge Permit UGW370004 GWQS Groundwater Quality Standard INTERA INTERA Incorporated mean + 2σ mean plus two sigma mg/L milligrams per liter Mill White Mesa Uranium Mill SAR Source Assessment Report TDS Total Dissolved Solids USEPA United States Environmental Protection Agency Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 1 May 7, 2013 1.0 INTRODUCTION Energy Fuels Resources (USA) Inc. (“EFRI”) (formerly named Denison Mines (USA) Corp.) operates the White Mesa Uranium Mill (the “Mill”), located near Blanding, Utah (Figure 1), under State of Utah Groundwater Discharge Permit UGW370004 (the “GWDP”). This is the Source Assessment Report (“SAR”) required under Part I.G.4 of the GWDP relating to violations of Part I.G.2 of the GWDP with respect to total dissolved solids (“TDS”) in groundwater compliance monitoring well MW-29 (Figure 2). Part I.G.2 of the GWDP provides that out-of-compliance status exists when the concentration of a constituent in two consecutive samples from a compliance monitoring point exceeds a groundwater compliance limit (“GWCL”) in Table 2 of the GWDP. The GWDP was originally issued in March 2005, at which time GWCLs were set on an interim basis, based on fractions of State of Utah Ground Water Quality Standards (“GWQSs”) or the equivalent, without reference to natural background at the Mill site. The GWDP also required that EFRI prepare a background groundwater quality report to evaluate all historical data for the purposes of establishing background groundwater quality at the site and developing GWCLs under the GWDP. As required by then Part I.H.3 of the GWDP, EFRI submitted the following to the Director (the “Director”) of the Utah Division of Radiation Control (“DRC”) (the Director was formerly the Executive Secretary of the Utah Radiation Control Board and the Co-Executive Secretary of the Utah Water Quality Board): • A Revised Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, October 2007, prepared by INTERA Incorporated (INTERA) (the “Existing Wells Background Report”). • A Revised Addendum: Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, November 16, 2007, prepared by INTERA (the “Regional Background Report”). • A Revised Addendum: Background Groundwater Quality Report: New Wells for Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, April 30, 2008, prepared by INTERA (the “New Wells Background Report,” and together with the “Existing Wells Background Report” and the “Regional Background Report,” the “Background Reports”). Based on a review of the Background Reports and other information and analyses, the Director re-opened the GWDP and modified the GWCLs to be equal to the mean concentration plus two Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 2 May 7, 2013 standard deviations or the equivalent. The modified GWCLs became effective on January 20, 2010. The Director issued a Notice of Violation and Compliance Order, Docket No. UGWll-02 (the “Notice of Violation”), dated May 9, 2011, based on DRC’s findings from the review of the Mill’s first, second, and third quarter 2010 Groundwater Monitoring Reports. The Notice cited five violations of the GWDP, including a violation under the Utah Water Quality Act (UC 19-5- 107) and Part I.C.1 of the GWDP, in that six contaminants exceeded their respective GWCLs, as defined in Table 2 of the GWDP, for two consecutive sampling events. Section E.4 of the Notice ordered EFRI to prepare and submit, within 30 calendar days of receipt of the Notice, a written plan and time schedule for Director approval to fully comply with the requirements of Part I.G.4(c) of the GWDP. In response to the Notice, EFRI submitted the Initial Plan and Time Schedule (“Initial Plan and Time Schedule”) to address constituents that exceeded their respective GWCLs for two consecutive sampling events in the first, second, third, and fourth quarters of 2010 and the first quarter of 2011. The Initial Plan and Time Schedule was submitted June 13, 2011. Subsequent to the Initial Plan and Time Schedule, EFRI submitted a Plan and Time Schedule for the second quarter of 2011 (“Q2 2011 Plan and Schedule”) to address constituents that exceeded their respective GWCLs for two consecutive sampling events in the second quarter of 2011. The Q2 2011 Plan and Schedule was submitted on September 7, 2011. In the first quarter of 2012, TDS in MW-31 was identified as exceeding its respective GWCL for two consecutive sampling events. EFRI requested that no additional plan and time schedule be prepared and that this exceedance be addressed in conjunction with the sulfate exceedances as described in the June 13, 2011, Initial Plan and Time Schedule. DRC agreed with this request in correspondence dated August 1, 2012. Pursuant to the Initial Plan and Schedule and the Q2 2011 Plan and Schedule, EFRI submitted a SAR to DRC on October 10, 2012. The SAR covered the constituents in violation of Part I.G.2 of the GWDP that were identified in the Initial Plan and Time Schedule and in the Q2 2011 Plan and Schedule. On November 15, 2012, EFRI submitted a notice (the “3rd Quarter 2012 Exceedance Notice”) to the Executive Secretary under Part I.G.1(a) of the Permit providing notice that the concentrations of specific constituents in the monitoring wells at the Mill exceeded their respective GWCLs for the third quarter of 2012 and indicating which of those constituents had two consecutive exceedances as of that quarter. A Plan and Time Schedule for the third quarter of 2012 (“Q3 2012 Plan and Time Schedule”) covers the constituent that was identified as being in violation of Part I.G.2 of the Permit. The Q3 2012 Plan and Time Schedule was submitted on Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 3 May 7, 2013 December 13, 2012. The Q3 2012 Plan and Time Schedule was approved by DRC in correspondence dated February 4, 2013. This SAR addresses the constituent that was identified as being in violation of Part I.G.2 of the GWDP in the 3rd Quarter 2012 Exceedance Notice and as described in the DRC-approved Q3 2012 Plan and Time Schedule. 1.1 Constituents and Wells Subject to this Report This SAR covers TDS in MW-29. TDS is the constituent identified as being in violation of Part I.G.2 of the GWDP during the third quarter of 2012 pursuant to the foregoing Exceedance Notice and the Q3 2012 Plan and Time Schedule. 1.2 Source Assessment Report Layout An overview of Sections 2.0 through 5.0 and the appendices included with this SAR is provided below. A description of the approach used for analysis is provided in Section 2.0, and the results of the analysis are presented in Section 3.0. Conclusions and recommendations are reviewed in Section 4.0, and references are included in Section 5.0. The appendices are comprised of the analyses performed for this SAR and are organized in the following manner: Appendix A contains a table showing the exceedances (TDS in MW-29). Appendix B contains the geochemical analysis performed on TDS in MW-29. Appendix C contains the indicator parameter analysis performed on MW-29. Appendix D contains data plots for TDS in MW-29 using all available data to date compared to the data plots from the Background Reports, as well as current data plots of all indicator parameters and plots of indicator parameters from the Background Reports. Appendix E contains the Flowsheet developed based on the United States Environmental Protection Agency’s (“USEPA”) Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance (USEPA, 2009), and approved by DRC prior to completion of the Background Reports. Appendix F is included on the compact disc that accompanies this SAR and contains the electronic input and output files used for statistical analysis. Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 4 May 7, 2013 2.0 CATEGORIES AND APPROACH FOR ANALYSIS Generally, out-of-compliance constituents and wells can be grouped into five categories: 1. Constituents in wells with previously identified rising trends. 2. Constituents in pumping wells. 3. Constituents potentially impacted by decreasing trends in pH across the site. 4. Newly installed wells with interim GWCLs. 5. Other constituents and wells. This SAR addresses one constituent in one well (TDS in MW-29), neither of which falls into any of the first four categories listed above. Therefore, the “other constituents and wells” category will apply. 2.1 Approach for Analysis The first step in the analysis is to perform an assessment of the potential sources for the exceedance to determine whether the exceedance is due to background influences or Mill activities. If the exceedance is determined to be caused by background influences, then it is not necessary to perform any further evaluations on the extent and potential dispersion of the contamination or to perform an evaluation of potential remedial actions. Monitoring will continue, and where appropriate, a revised GWCL will be proposed to reflect changes in background conditions at the site. The assessment for potential sources for the exceedance was accomplished by performing a geochemical analysis to evaluate the behavior of the constituents in the well in question to determine if there have been any changes in the behavior of indicator parameters, such as chloride, sulfate, fluoride, and uranium, since the date of the Background Reports that may suggest a change in the behavior of that well. As discussed in detail in Section 9.0 of the Existing Wells Background Report, chloride is the best indicator of potential tailings cell leakage, followed by fluoride, and then sulfate (due to mobility and abundance in tailings). Uranium is probably the most mobile of trace (metal) elements and is the best indicator parameter for metals and radionuclides. Any potential seepage from tailings impoundments would be expected to exhibit rising concentrations of chloride and possibly fluoride, sulfate, and uranium. However, while uranium may be the most mobile of trace (metal) elements, it is typically retarded behind chloride and would likely not be expressed in groundwater until sometime after chloride concentrations had begun to rise. This is because uranium is a metal cation and behaves as other metals with respect to pH. It is important to note, Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 5 May 7, 2013 however, that while the lack of a rising trend in chloride would indicate that there has been no impact from tailings, a rising trend in chloride could also be due to some natural influences (see Section 12.0 of the Existing Wells Background Report). Therefore, in situations where there is a significant rising trend in chloride, other evaluations would need to be performed, such as a determination as to whether any other indicator parameters have demonstrated a significant rising trend and whether or not the concentrations and mass balance indicate a potential tailings cell leak. The geochemical analysis was supported by a statistical analysis that followed the process outlined in the Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site, San Juan County, Utah (“Flowsheet”) (INTERA, 2007a), a copy of which is provided in Appendix E. The Flowsheet was designed based on USEPA’s Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance (USEPA, 2009), and was approved by DRC prior to completion of the Background Reports. If it was determined through the geochemical analysis of the indicator parameters that the behavior of MW-29 has changed since the Background Report, a mass balance analysis was performed to evaluate the observed concentrations of the constituent in light of the concentrations in Mill tailings and the presence or absence of any mounding at the location of the well in question. Since MW-29 is not distant from the Mill’s tailings cells, a hydrogeologic analysis was not performed to determine the plausibility of impact from Mill tailings. If significant changes were identified that could not be attributed to background influences, then further analysis was proposed to identify the source, extent, and potential dispersion of the contamination, as well as to identify potential remedial actions. Additional analysis specific to the “other constituents and wells” category is described below. 2.1.1 Other Constituents and Wells TDS does not fall into one of the previous categories and has been included in the “other constituents and wells” category. Although TDS in MW-29 does not fall into any of the first four categories listed in Section 2.0, the primary focus for the source assessment for MW-29 is the same as in those categories: to determine whether or not there is any new information that would suggest that the previous analysis conducted in the Background Reports has changed since the dates of those reports. The first step for this category was to perform a geochemical analysis evaluating the behavior of the constituents in MW-29 to determine if there have been any changes in the behavior of indicator parameters, such as chloride, sulfate, fluoride, and uranium, since the dates of the Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 6 May 7, 2013 Background Reports that may suggest a change in the behavior of that well since the dates of those reports. If it was determined through the geochemical analysis of the indicator parameters that the behavior of MW-29 has changed since the Background Report, a mass balance analysis was performed to evaluate the observed concentrations of the constituent in light of the concentrations in Mill tailings and the presence or absence of any mounding at MW-29. 2.2 Approach for Setting Revised GWCLs If the foregoing approaches resulted in the conclusion that the previous analysis in the Background Reports has not changed and that the out-of-compliance status of MW-29 is due to natural influences, then a new GWCL was proposed for the constituent. In proposing the revised GWCL, we have adopted the approach in the Flowsheet. Appendix B-1 summarizes the geochemical analysis and presents the revised GWCL for TDS in MW-29 based on an application of the Flowsheet. It is assumed that once a revised GWCL is accepted for TDS in MW-29, accelerated monitoring for that constituent will cease. Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 7 May 7, 2013 3.0 RESULTS OF ANALYSIS This section describes the results of the analysis, a summary of which is provided in Appendix B-1, Appendix C-1, and Appendix D. 3.1 Other Constituents and Wells TDS in MW-29 was subjected to a geochemical analysis that compared current data and analysis to the results of analysis at the time of the New Wells Background Report to determine if the behavior of the well had changed since the dates of those reports. The primary focus of this analysis was to determine whether or not there was any new information that would suggest that conditions supporting the previous analysis conducted in the Background Reports have changed since the dates of those reports. 3.1.1 Total Dissolved Solids The concentration of TDS has been out of compliance in MW-29 for three consecutive quarters in 2012. The results of the geochemical analysis of TDS in MW-29 show that concentrations are not behaving differently than they were at the time of the Background Report. TDS in MW-29 was decreasing (not significantly) at the time of the Background Report. Appendix B indicates that at the time of this SAR, the trend line for TDS is still slightly sloping downward (r= -0.02), however, no real trend is observed. Chloride analysis at the time of the Background Report displayed a decreasing trend that was not significant. At the time of this SAR, chloride is showing a significantly decreasing trend. Sulfate concentrations are also showing a decreasing trend, however the trend is not significant. Uranium concentrations are increasing in MW-29. However, that trend is not identified as being significant in the Mann-Kendal trend analysis. Further, without the increase of other indicator parameters, increasing uranium concentrations can be attributed to natural influences at the site rather than any potential tailings cell seepage. The foregoing geochemical analysis indicates that because there is not a rising trend in TDS and the key indicator parameter chloride is decreasing, the groundwater in MW-29 is not behaving differently than at the time of the Background Report. It is therefore appropriate to revise the GWCL for TDS in MW-29 to better reflect natural background conditions. The major difference between what the data show for TDS in MW-29 at the time of the Background Report and the time of this SAR is that there are more data. At the time of the Background Report, although there were ten data results, two were identified and removed as extreme outliers, resulting in the GWCL for TDS being calculated using the minimum required eight results. At the time of this SAR, 25 results are available. Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 8 May 7, 2013 At the time of the New Wells Background Report (using eight data points for analysis) TDS in MW-29 was not normally or lognormally distributed. Non parametric statistics were used, and according to the Flowsheet, the GWCL was set at the highest historical value of 4,400 milligrams per liter (“mg/L”). With 25 data points available at the time of this SAR, TDS concentrations in MW-29 are normally or lognormally distributed, which allows the GWCL to be calculated by adding the mean plus two standard deviations, for a proposed revised GWCL of 4,570 mg/L. As a result, the out-of-compliance status of TDS in MW-29 is likely due to natural variations in the well that were not recognized at the time of the background report due to a small sample size (data set of eight results). For this reason, EFRI proposes that the GWCL in MW-29 be adjusted to take into account additional data. The current GWCL for TDS in MW-29 is 4,400 mg/L. The newly calculated proposed GWCL for TDS in MW-29 is 4,570 mg/L, which was calculated in accordance with the Flowsheet as the mean + 2σ, based on all data available to date. Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 9 May 7, 2013 4.0 CONCLUSIONS AND RECOMMENDATIONS Background at the Mill site was recently thoroughly studied in the Background Reports and in the University of Utah Study (Hurst and Solomon, 2008). Both the Background Reports and the University of Utah Study (Hurst and Solomon, 2008) concluded that groundwater at the site has not been impacted by Mill operations. Both of those studies also acknowledged that there are natural influences at play at the site that have given rise to increasing water trends and general variability of background groundwater at the site. The focus of this SAR was therefore to identify any changes in the circumstances identified in those studies. A geochemical analysis for the indicator parameters in MW-29 was performed. The results of the analyses show that there has not been a significant change in the behavior of TDS in MW-29. TDS has not increased over time in MW-29, and the geochemical analysis of indicator parameters indicates that there has been no impact in MW-29 from mill operations. This means that the exceedances of TDS observed in MW-29 are the result of setting GWCLs at the time of the Background Report using too few data. Table 1 Summary of Findings Well Out-of-Compliance Constituent Summary Path Forward MW-29 TDS No significantly increasing trend in any of the indicator parameters. Consistent with background conditions. Revise GWCL Based on these findings and the application of the Flowsheet, EFRI proposes a revised GWCL for TDS in MW-29 of 4,570 mg/L. Source Assessment Report for TDS in MW-29 White Mesa Uranium Mill, Blanding, Utah 10 May 7, 2013 5.0 REFERENCES Hurst, T.G., and Solomon, D.K., 2008. Summary of Work Completed, Data Results, Interpretations and Recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah. Prepared by Department of Geology and Geophysics, University of Utah. INTERA Incorporated, 2007a. Revised Background Groundwater Quality Report: Existing Wells for Dension Mines (USA) Corp.’s White Mesa Uranium Mill Site, San Juan County, Utah. October. ––––––, 2007b. Revised Addendum: Evaluation of Available Pre-Operational and Regional Background Data, Background Groundwater Quality Report: Existing Wells for Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah. November 16. ––––––, 2008. Revised Addendum: Background Groundwater Quality Report: New Wells for Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah. April 30. USEPA, 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities EPA 530/R-09-007. FIGURES Cell No. 1 Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond Mill Site Cell No. 4B MW-37 MW-36 MW-35 MW-34MW-33 MW-32MW-31MW-30 MW-29 MW-28 MW-27 MW-26 MW-25 MW-24 MW-23 MW-22 MW-21 MW-20 MW-19 MW-18 MW-17 MW-15 MW-14 MW-12 MW-11 MW-05 MW-04 MW-03 MW-02 MW-01 MW-03A S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\Task_4_NOV\Fig01_LocationMap.mxd Date: 9/14/2012 Figure 1Location of White Mesa Mill SiteWhite Mesa Uranium Mill 1,000 0 1,000500 Feet Source(s): Aerial – NAIP Utah 2011;Wells – HGC, Inc., May 2008 report. Legend Groundwater Monitoring Wells U T A HUTAH White MesaUranium Mill Cell No. 1 Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond Mill Site Cell No. 4B MW-37 MW-36 MW-34MW-33 MW-32 MW-31 MW-30 MW-29 MW-28 MW-27 MW-26 MW-25 MW-24 MW-23 MW-18 MW-17 MW-15 MW-14 MW-12 MW-11 MW-05 MW-04 MW-03 MW-02 MW-03A MW-35 S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\Fig02_TDSMW_29SAR.mxd Date: 5/7/2013 Figure 2Wells with GWCL exceedences during 3Q 2012White Mesa Uranium Mill 500 0 500250 Feet Source(s): Aerial – NAIP Utah 2011;Wells – HGC, Inc., May 2008 report; Legend TDS exceedence Monitoring Wells APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class)Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP Q1 2010 Sample Date Q1 2010 Result Q2 2010 Sample Date Q2 2010 Result May 2010 Monthly Sample Date May 2010 Monthly Result June 2010 Monthly Sample Date June 2010 Monthly Result July 2010 Monthly Sample Date July 2010 Monthly Result August 2010 Monthly Sample Date August 2010 Monthly Result Q3 2010 Sample Date Q3 2010 Result October 2010 Monthly Sample Date October 2010 Monthly Result Q4 2010 Sample Date Q4 2010 Result December 2010 Monthly Sample Date December 2010 Monthly Result MW-11 (Class II) Manganese (ug/L) 131.29 2/10/10 134 4/28/10 137 5/24/10 122 6/16/10 99 7/20/10 123 8/25/10 138 9/8/10 128 10/20/10 141 11/11/10 133 12/15/10 158 Manganese (ug/L) 2230.30 2060 2070 NA NA NA NA 1920 NA 1980 NA Field pH (S.U.) 6.5 - 8.5 6.45 6.29 6.36 6.45 7.19 6.48 6.51 6.60 6.37 6.47 Field pH (S.U.) 6.5 - 8.5 6.53 7.2 NA NA NA NA 6.58 NA 6.36 NA Cadmium (ug/L) 1.5 1.26 1.44 NA NA NA NA 1.4 NA 1.26 NA Chloride (mg/L) 35 31 31 NA NA NA NA 31 NA 31 NA Uranium 6.5 5.93 6.43 NA NA NA NA 6.57 NA 5.89 NA Nitrate + Nitrite (as N) (mg/L)0.62 1.3 2 0.3 0.4 0.6 0.6 0.7 0.4 0.2 0.4 Uranium (ug/L) 41.8 58.7 66.7 37.4 36.6 34.4 71.8 72.7 37.5 30.4 29.6 Chloroform (ug/L) 70 700 1700 800 940 900 2800 2100 1000 1900 1400 Chloride (mg/L) 58.31 72 57 80 47 52 49 64 52 48 52 Field pH (S.U.) 6.74 - 8.5 6.59 7.18 6.36 6.98 6.45 6.39 6.60 6.61 6.49 6.45 Dichloromethane (Methylene Chloride) (ug/L) 519.9 NR 2.2 12 24 45 5.5 16 1.2 Nitrate + Nitrite (as N) (mg/L)2.5 16.1 15.8 17 15.3 7/21/10 16 8/24/10 16 15 15 15 16 Chloride (mg/L) 128 127 97 NS NS NS NS NS NS 111 NS 126 NS Uranium (ug/L) 8.32 6.82 6.82 NS NS NS NS NS NS 7.10 NS 6.64 NS Selenium (ug/L) 34 32 35.3 NS NS 7/27/10 33.5 8/24/10 35.6 32.6 32.4 32.2 30.5 Nitrate + Nitrite (as N) (mg/L)5 21.7 22.5 5/21/10 23 6/15/10 21.1 7/21/10 20 8/24/10 22 21 10/19/10 20 20 20 TDS (mg/L) 1320 1150 1220 NS NA NS NA NS NA NS NA 1330 NS NA 1320 NS Chloride (mg/L) 143 128 128 NS NA NS NA NS NA NS NA 139 NS NA 138 NS Selenium (ug/L) 71 60.8 59.6 NS NA NS NA NS NA NS NA 64.4 NS NA 60 NS Sulfate (mg/L) 532 507 522 NS NA NS NA NS NA NS NA 527 NS NA 539 NS Manganese (ug/L) 200 NA NA NA NA NA NA NA NA 698 NA Thallium (ug/l) 0.5 NA NA NA NA NA NA NA NA 1.14 NA Molybdenum (ug/L) 10 NA NA NA NA NA NA NA NA <10 NA Gross Alpha minus Rn & U (pCi/L)3.75 NA NA NA NA NA NA NA NA 2.6 NA Selenium (ug/L) 12.5 NA NA NA NA NA NA NA NA ND NA Uranium (ug/L) 7.5 NA NA NA NA NA NA NA NA 27.2 NA Manganese (ug/L) 289 NA 212 NA NA NA NA NA NA 275 NA Tetrahydrofuran (ug/L) 11.5 NA 7.8 NA NA NA NA NA NA 10.7 NA Sulfate (mg/L) 838 NA 805 NA NA NA NA NA NA 792 NA MW-2 (Class III)Gross Alpha minus Rn & U (pCi/L)3.2 NS NA 4/27/10 1.2 NS NA NS NA NS NA NS NA NS NA NS NA 11/17/10 3.5 NS NA Selenium (ug/L) 37 NA 37.2 NA NA NA NA 35.5 NA 38.8 NA Field pH (S.U.) 6.5 - 8.5 NA 6.14 (6.25)NA NA NA NA 6.39 NA 6.35 NA Fluoride (mg/L) 0.68 NA 0.71 NA NA NA NA 0.63 NA 0.77 NA Field pH (S.U.) 6.5 - 8.5 NA 6.23 (6.24)NA NA NA NA 6.42 NA 6.21 NA Sulfate (mg/L) 3640 NA 3680 NA NA NA NA 3630 NA 3850 NA Nitrate + Nitrite (as N) (mg/L)1.3 NA 1.0 NA NA NA NA NA NA 1.2 NA TDS (mg/L) 5805 NA 5860 NA NA NA NA 5470 NA 5330 NA Selenium (ug/L) 89 NA 81.4 NA NA NA NA NS NA 94.8 NA MW-5 (Class II) Uranium (ug/L) 7.5 NS NA 4/26/10 0.39 NS NA NS NA NS NA NS NA NS NA NS NA 11/11/10 11.6 NS NA Field pH (S.U.) 6.5 - 8.5 NA 7.16 NA NA NA NA 6.62 NA 6.47 NA Selenium (ug/L) 25 NA 25.7 NA NA NA NA 31.9 NA 27.6 NA Selenium (ug/L) 128.7 NA 100 NA NA NA NA NA NA 99.5 NA Iron (ug/L) 81.7 NA ND NA NA NA NA NA NA ND NA Required Quarterly Sampling Wells Q1 2010 Results Q2 2010 Results Q3 2010 Results Q4 2010 Results 9/8/10 10/20/10 NS NS NS NS NS NS NS NS 9/20/10 11/19/10 MW-31 (Class III) 2/9/10 4/20/10 9/13/10 11/9/10 12/14/10 NS NS NS NS NS MW-35 (Class II)11/30/10NS NS NS NS NS NS NS NS MW-14 (Class III) 2/2/10 4/21/10 5/21/10 6/16/10 7/20/10 8/25/10 MW-25 (Class III) 2/26/2010 4/28/2010 9/8/2010 11/10/10 11/10/10 12/15/10 MW-15 (Class III)4/21/10 NS 11/11/10 MW-12 (Class III)4/27/10 9/20/10 11/19/10 NS NS NS NS NS MW-3A (Class III)5/4/10 9/21/10 11/22/10 Required Semi-Annual Sampling Wells MW-3 (Class III)5/3/10 NS NS NS NS NS NS NS NS NS NSMW-01 (Class II)5/5/2010 11/18/2010 11/15/10 12/15/10 NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-26 (Class III) 2/2/10 4/22/10 5/21/10 6/16/10 7/21/10 8/16/10 9/26/10 10/20/10 MW-30 (Class II) 2/9/10 4/27/10 5/21/10 6/15/10 9/14/10 10/19/10 11/9/10 12/14/10 Page 1 of 8 APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class)Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP Q1 2010 Sample Date Q1 2010 Result Q2 2010 Sample Date Q2 2010 Result May 2010 Monthly Sample Date May 2010 Monthly Result June 2010 Monthly Sample Date June 2010 Monthly Result July 2010 Monthly Sample Date July 2010 Monthly Result August 2010 Monthly Sample Date August 2010 Monthly Result Q3 2010 Sample Date Q3 2010 Result October 2010 Monthly Sample Date October 2010 Monthly Result Q4 2010 Sample Date Q4 2010 Result December 2010 Monthly Sample Date December 2010 Monthly Result Required Quarterly Sampling Wells Q1 2010 Results Q2 2010 Results Q3 2010 Results Q4 2010 Results Thallium (ug/l) 1.95 NA 3.73 NA NA NA NA 3.64 NA 3.57 NA Sulfate (mg/L) 1938.9 NA 1950 NA NA NA NA 1930 NA 1910 NA Field pH (S.U.) 6.25-8.5 NA 6.2 NA NA NA NA 7.23 NA 6.37 NA TDS (mg/L) 3198.77 NA 3280 NA NA NA NA 3190 NA 3030 NA Field pH (S.U.) 6.78-8.5 NA 6.61 (6.66)NA NA NA NA 6.93 NA 6.8 NA Gross Alpha minus Rn & U (pCi/L)2.36 NA 0.9 NA NA NA NA NA NA 1.2 NA Nitrate + Nitrite (as N) (mg/L)2.83 NA 2.6 NA NA NA NA NA NA 2.4 NA Field pH (S.U.) 6.5 - 8.5 NA 6.18 NA NA NA NA 7.05 NA 6.44 NA Manganese (ug/L) 550 NA 184 NA NA NA NA NS NA 65 NA Cadmium (ug/L) 2.5 NA 4.28 NA NA NA NA 5.06 NA 3.22 NA Fluoride (mg/L) 0.36 NA 0.14 NA NA NA NA NA NA 0.18 NA Thallium (ug/L) 1 NA 1.3 NA NA NA NA 1.57 NA 1.09 NA Field pH (S.U.) 6.5 - 8.5 NA 5.91 (5.78)NA NA NA NA 6.64 NA 6.1 NA Nitrate + Nitrite (as N) (mg/L)5.6 NA 5.8 NA NA NA NA 5.9 NA 5.7 NA Chloride (mg/L) 38 NA 42 NA NA NA NA 42 NA 45 NA Sulfate (mg/L) 462 NA 469 NA NA NA NA 461 NA 452 NA Field pH (S.U.) 6.5-8.5 NA 6.78 NA NA NA NA 7.68 NA 6.89 NA TDS (mg/L) 1075 NA 1160 NA NA NA NA 1060 NA 1110 NA Gross Alpha minus Rn & U (pCi/L)2 NA 1.6 NA NA NA NA NA NA 2.4 NA Chloride (mg/L) 105 NA 108 NA NA NA NA 106 NA 107 NA Manganese (ug/L) 1837 NA 1550 NA NA NA NA NA NA 1510 NA Field pH (S.U.) 6.1 - 8.5 NA 5.67 NA NA NA NA 5.91 NA 5.72 NA Iron (ug/L) 1869 NA 1630 NA NA NA NA NA 1490 NA Manganese (ug/L) 5624 NA 4820 NA NA NA NA NA 4890 NA TDS (mg/L) 4400 NA 4400 NA NA NA NA NA 4390 NA Field pH (S.U.) 6.46 - 8.5 NA 6.82 NA NA NA NA NA 6.17 NA Gross Alpha minus Rn & U (pCi/L)3.33 NA 4.5 NA NA NA NA 2.9 NA 8.8 NA Field pH (S.U.) 6.4 - 8.5 NA 6.03 NA NA NA NA 6.33 NA 6.05 NA Notes: MW-18 (Class III)5/4/10 9/15/10 11/18/10 MW-23 (Class III)4/22/10 9/14/10 11/22/10 MW-19 (Class III)5/4/10 9/15/10 11/18/10 NS 11/12/10 MW-24 (Class III)5/6/10 9/21/10 11/17/10 MW-28 (Class III)4/19/10 11/12/10 MW-27 (Class III)5/3/10 9/14/10 MW-29 (Class III)4/27/10 NS NA 11/9/10 MW-32 (Class III)4/20/10 9/13/10 11/10/10NS NS NS GWCL values are taken from the August 24, 2012 version of the GWDP. NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 9/14/10 NS NS NS NS NS NS NS NS NS NS NS NS Exceedances are shown in yellow. NA = Not Applicable NR = Required and Not Reported pCi/L = picocuries per liter Values in () parentheses are the field pH measurements for the resampled ug/L = micrograms per liter mg/L = milligrams per liter NS = Not Required and Not Sampled SU = Standard Units Page 2 of 8 APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class) Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP January 2011 Monthly Sample Date January 2011 Monthly Sample Result Q1 2011 Sample Date Q1 2011 Result March 2011 Monthly Sample Date March 2011 Monthly Result Q2 2011 Sample Date Q2 2011 Result May 2011 Monthly Sample Date May 2011 Monthly Result June 2011 Monthly Sample Date June 2011 Monthly Result July 2011 Monthly Sample Date July 2011 Monthly Result Q3 2011 Sample Date Q3 2011 Result September 2011 Monthly Sample Date September 2011 Monthly Result Q4 2011 Sample Date Q4 2011 Result November 2011 Monthly Sample Date November 2011 Monthly Result December 2011 Monthly Sample Date December 2011 Monthly Result MW-11 Manganese (ug/L) 131.29 1/11/11 121 2/2/11 145 3/15/11 68 4/4/2011 148 5/10/2011 170 6/15/2011 121 7/6/2011 151 8/3/2011 118 9/7/2011 106 10/4/2011 112 11/9/2011 105 12/14/2011 100 Manganese (ug/L) 2230.30 NA 2020 NA 2140 NA NA NA 1990 NA 1960 NA NA Field pH (S.U.) 6.5 - 8.5 6.37 6.22 6.76 6.63 6.37 5.83 6.4 6.23 (6 41) 6.50 6.71 (6.82) 6.63 6.84 Field pH (S.U.) 6.5 - 8.5 6.44 6.66 6.79 6.7 6.1 5.77 6.29 8/3/2011 8/30/11 6.42 (6.54)6.54 6.6 6.51 6.87 Cadmium (ug/L) 1.5 NA 1.34 NA 1.27 NA NA NA 8/30/2012 1.19 NA 1.27 NA NA Chloride (mg/L) 35 NA 30 NA 31 NA NA NA 32 NA 32 NA NA Uranium 6.5 7.02 4.77 6.8 5.56 6.72 7.06 6.74 6.37 5.96 5.27 6.56 6.1 Nitrate + Nitrite (as N) (mg/L)0.62 0.2 0.25 0.6 0.8 0.4 0.3 0.9 0.6 2.4 0.9 1.3 2.3 Uranium (ug/L) 41.8 32 69.3 31.8 60.2 57.4 18.5 57.1 19.0 56.1 58.9 55.6 57 Chloroform (ug/L) 70 800 730 1200 390 1900 730 300 1000 1300 440 1200 1400 Chloride (mg/L) 58.31 52 59 64 64 54 39 64 60 66 61 55 62 Field pH (S.U.) 6.74 - 8.5 6.83 6.06 6.89 6.22 6.43 6.52 6.35 6.07 (6.58)6.71 6.82 6.75 7.1 Dichloromethane (Methylene Chloride) (ug/L) 5 <1.0 10 14 3.1 20 7 2.4 10 7.9 2.6 8.9 11 Nitrate + Nitrite (as N) (mg/L)2.5 15 2/1/11 16 17 16 16 17 17 14 16 16 16 16 Chloride (mg/L) 128 NS 134 NS 134 128 127 127 126 145 129 122 124 Uranium (ug/L) 8.32 NS 5.97 NS 6.49 NS NS NS 8 NS 9.83 NS NS Selenium (ug/L) 34 36.2 34.7 34 44.4 38.3 38.7 32.4 39.7 32.4 36.6 36.8 38 Nitrate + Nitrite (as N) (mg/L)5 19 21 22 21 20 22 22 20 21 21 21 21 TDS (mg/L) 1320 1240 1220 1250 1370 1290 1330 1280 1300 1300 1320 1290 1330 Chloride (mg/L) 143 NS 145 NS 143 143 145 148 148 148 145 145 148 Selenium (ug/L) 71 NS 64.6 NS 65.2 NS NS NS 66.2 NS 68.8 NS NS Sulfate (mg/L) 532 NS 538 531 503 512 540 532 537 541 539 552 530 Manganese (ug/L) 200 NA 248 NA 369 NA NA 348 267 270 271 283 247 Thallium (ug/l) 0.5 NA < 0.50 NA < 0.50 NA NA NA 0.52 NA 0.57 < 0.50 0.63 Molybdenum (ug/L) 10 NA <10 NA <10 NA NA NA <10 NA <10 NA NA Gross Alpha minus Rn & U (pCi/L)3.75 NA 2.6 NA 3.7 NA NA NA 4.5 NA 4.4 4.7 4.2 Selenium (ug/L) 12.5 NA ND NA ND NA NA NA 9.3 NA 10.5 NA NA Uranium (ug/L) 7.5 NA 12.7 NA 21.7 NA NA 24.2 18.3 22.3 20.1 24 23.6 Manganese (ug/L) 289 NA NA NA 4/11/2011 218 NA NA NA NA NA 206 NA NA Tetrahydrofuran (ug/L) 11.5 NA NA NA 4/19/2011 10.7 NA NA NA NA NA 7.82 NA NA Sulfate (mg/L) 838 NA NA NA 4/11/2011 704 NA NA NA NA NA 713 NA NA MW-2 (Class III) Gross Alpha minus Rn & U (pCi/L)3.2 NS NA 2/14/11 1.1 NS NA 4/12/2011 1.2 NS NA NS NA NS NA 8/8/2011 0.5 NS NA 10/5/2011 1.3 NS NA NS NA Selenium (ug/L) 37 NA 40.5 NA 45.4 NA NA NA 46 NA 46.7 NA NA Field pH (S.U.) 6.5 - 8.5 NA 6.09 NA 6.46 NA NA NA 6.32 NA 6.53 (6.83) NA NA Fluoride (mg/L) 0.68 NA 0.69 NA 0.68 NA NA NA 0.96 NA 0.91 NA NA Field pH (S.U.) 6.5 - 8.5 NA 6.05 NA 6.58 NA NA NA 6.19 NA 6.5 (6.92) NA NA Sulfate (mg/L) 3640 NA 3730 NA 3350 NA NA NA 3560 NA 3750 NA NA Nitrate + Nitrite (as N) (mg/L)1.3 NA NA NA 1.2 NA NA NA NA NA 1.1 NA NA TDS (mg/L) 5805 NA 5770 NA 5720 NA NA NA 5810 NA 5630 NA NA Selenium (ug/L) 89 NA 99 NA 85.8 NA NA NA 88.5 NA 95 NA NA MW-5 (Class II)Uranium (ug/L) 7.5 NS NA 2/14/11 29.5 NS NA 4/12/2011 7.16 NS NA NS NA NS NA 8/9/2011 0.5 NS NA 10/10/2011 4.52 NS NA NS NA Field pH (S.U.) 6.5 - 8.5 NA 6.43 NA 6.67 NA NA NA 6.13 NA 6.7 (6.97) NA NA Selenium (ug/L) 25 NA 39 NA 21.7 NA NA NA 25.4 NA 35.4 NA NA Selenium (ug/L) 128.7 NA NA NA 116 NA NA NA NS NA NA 112 NA NA Iron (ug/L) 81.7 NA NA NA <0.50 NA NA NA NS NA NA 137 NA NA 6/20/2011 7/6/2011 9/7/2011 10/12/2011 11/9/2011 9/7/2011 Q4 2011 Results Required Quarterly Sampling Wells Q1 2011 Results Q2 2011 Results Q3 2011 Results 12/12/201111/9/20117/5/2011 8/3/2011 9/8/2011 3/15/11 4/4/2011 5/11/2011 5/10/2011 6/15/2011 8/3/2011 MW-31 (Class III) 1/10/11 2/1/11 6/20/2011 7/5/2011 8/3/2011 9/7/2011 10/4/2011 11/8/20111/10/11 MW-3 (Class III) 9/7/11MW-35 (Class II)2/15/11 6/7/2011 7/20/11 8/30/2011 6/20/2011 7/6/2011 MW-25 (Class III) 1/11/11 2/2/11 MW-14 (Class III)1/11/11 2/7/11 3/14/11 4/4/2011 MW-15 (Class III) MW-12 (Class III) MW-3A (Class III) Required Semi-Annual Sampling Wells NS NS NS NS NS NS NS NS8/11/2011 10/11/2011 NS 10/4/2011 11/9/2011 1212/2011 12/12/2011 10/4/2011 12/14/11 12/12/2011 12/14/2011 MW-01 (Class II)NS NS NS MW-30 (Class II) MW-26 (Class III)1/12/11 2/16/11 3/15/11 4/1/2011 5/10/2011 8/3/2011 8/30/11 NS NS NS NS NS NS NS NS NS NS NS NS 2/16/11 2/15/11 4/13/2011 4/13/2011 NS NSNS 10/10/2011NS NSNS 2/15/11 4/5/2011 NS NS 4/12/2011NS NS NS NS NS 8/10/2011 10/10/2011 8/9/2011 10/6/2011 NS 10/11/2011 NS NS NS NS NS NS NS 3/14/11 4/11/2011 5/10/2011 NS NS 3/14/11 4/1/2011 5/10/2011 6/20/2011 7/5/2011 8/2/2011 9/6/2011 10/3/2011 11/8/2011 10/3/11 11/8/2011 Page 3 of 8 APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class) Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP January 2011 Monthly Sample Date January 2011 Monthly Sample Result Q1 2011 Sample Date Q1 2011 Result March 2011 Monthly Sample Date March 2011 Monthly Result Q2 2011 Sample Date Q2 2011 Result May 2011 Monthly Sample Date May 2011 Monthly Result June 2011 Monthly Sample Date June 2011 Monthly Result July 2011 Monthly Sample Date July 2011 Monthly Result Q3 2011 Sample Date Q3 2011 Result September 2011 Monthly Sample Date September 2011 Monthly Result Q4 2011 Sample Date Q4 2011 Result November 2011 Monthly Sample Date November 2011 Monthly Result December 2011 Monthly Sample Date December 2011 Monthly Result Q4 2011 Results Required Quarterly Sampling Wells Q1 2011 Results Q2 2011 Results Q3 2011 Results Thallium (ug/l) 1.95 NA 3.49 NA 3.74 NA NA NA 4.0 3.39 NA 3.83 NA NA Sulfate (mg/L) 1938.9 NA 1770 NA 1780 NA NA NA 1910 NA 2020 NA NA Field pH (S.U.) 6.25-8.5 NA 6.27 NA 6.71 NA NA NA 5.95 (6 30) NA 6.55 (6.63) NA NA TDS (mg/L) 3198.77 NA 3250 NA 3250 NA NA NA 3190 NA 3220 NA NA Field pH (S.U.) 6.78-8.5 NA 6.78 NA 7.03 NA NA NA 6.65 NA 6.88 (7.02) NA NA Gross Alpha minus Rn & U (pCi/L)2.36 NA NA NA 0.5 NA NA NA NA NA 0.6 NA NA Nitrate + Nitrite (as N) (mg/L)2.83 NA NS NA 2.6 NA NA NA NS NA 4.0 NA NA Field pH (S.U.) 6.5 - 8.5 NA 6.13 NA 7.14 NA NA NA 6.38 NA 6.56 (6.77) NA NA Manganese (ug/L) 550 NA NS NA 32 NA NA NA NS NA 551 NA NA Cadmium (ug/L) 2.5 NA 2.78 NA 2.61 NA NA NA 1.46 NA 1.78 NA NA Fluoride (mg/L) 0.36 NA NA NA 0.19 NA NA NA NA NA 0.36 NA NA Thallium (ug/L) 1 NA 1.42 NA 1.07 NA NA NA <0.50 NA 0.62 NA NA Field pH (S.U.) 6.5 - 8.5 NA 5.73 NA 6.12 NA NA NA 6.45 NA 6.44 NA NA Nitrate + Nitrite (as N) (mg/L)5.6 NA 6 NA 6.4 NA NA NA 6 NA 6.3 NA NA Chloride (mg/L) 38 NA 46 NA 43 NA NA NA 43 NA 44 NA NA Sulfate (mg/L) 462 NA 455 NA 442 NA NA NA 424 NA 456 NA NA Field pH (S.U.) 6.5-8.5 NA 6.71 NA 6.79 NA NA NA 6.39 NA 7.17 (7.24) NA NA TDS (mg/L) 1075 NA 1090 NA 1190 NA NA NA 1090 NA 1110 NA NA Gross Alpha minus Rn & U (pCi/L)2 NA 0.7 NA 1.1 NA NA NA 0.8 NA 1.5 NA NA Chloride (mg/L) 105 NA 114 NA 109 NA NA NA 105 NA 143 NA NA Manganese (ug/L) 1837 NA NA NA 1690 NA NA NA NA NA 1540 NA NA Field pH (S.U.) 6.1 - 8.5 NA 5.69 NA 6.01 NA NA NA 5.78 NA 6.07(6.11)NA NA Iron (ug/L) 1869 NA NS NA NA 3010 NA NA NA 1080 NA 1220 NA NA Manganese (ug/L) 5624 NA NS NA NA 4900 NA NA NA NA NA 4800 NA NA TDS (mg/L) 4400 NA NS NA NA 4080 NA NA NA NA NA 4280 NA NA Field pH (S.U.) 6.46 - 8.5 NA NS NA NA 6.45 NA NA NA 6.20 NA 6.52 NA NA Gross Alpha minus Rn & U (pCi/L)3.33 NA 1.5 NA 4.6 NA NA NA 1.9 NA 3.7 NA NA Field pH (S.U.) 6.4 - 8.5 NA 5.99 NA 6.14 NA NA NA 6.10 (6.20)NA 6.35 NA NA Notes: MW-18 (Class III)2/15/11 NS NS 2/21/2011 MW-23 (Class III) MW-19 (Class III) NS 2/9/2011NS MW-27 (Class III) MW-24 (Class III) 2/9/2011 MW-29 (Class III) MW-28 (Class III) 4/5/2011 Exceedances are shown in yellow. Values in () parentheses are the field pH measurements for the ug/L = micrograms per liter mg/L = milligrams per liter NS = Not Required and Not Sampled NR = Required and Not Reported GWCL values are taken from the August 24, 2012 version of the GWDP. MW-32 (Class III)2/9/2011NS NS NS NSNSNS NS4/1/2011 8/2/2011 8/30/11 10/3/2011 NS NS NS NS 7/20/3011 10/12/2011NS NS NS NS8/4/2011 10/6/2011NS 8/4/2011 10/11/2011 NS NS NS 2/10/2011 NS NS NS NS NS NS NS NS 2/14/2011NS 4/11/2011 NS NS NS NS NS 4/6/2011 NS NS 4/5/2011 NS NS NS NS NS NS NS NS NS NS NS 4/18/2011 8/9/2011 NS 4/5/2011 4/5/2011 10/5/2011 8/8/2011 10/5/2011NS NS NS 8/10/2011 9/21/11 10/11/2011 NSNS 8/8/2011 10/5/2011 NS NS NS NS NS NS NS NS NA = Not Applicable pCi/L = picocuries per liter SU = Standard Units Page 4 of 8 APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class)Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP January 2012 Monthly Sample Date January 2012 Monthly Result Q1 2012 Sample Date Q1 2012 Result March 2012 Monthly Sample Date March 2012 Monthly Result April 2012 Monthly Sample Date April 2012 Monthly Result Q2 2012 Sample Date Q2 2012 Result June 2012 Monthly Sample Date June 2012 Monthly Result Q3 2012 Sample Date Q3 2012 Result August 2012 Monthly Sample Date August 2012 Monthly Result September 2012 Monthly Sample Date September 2012 Monthly Result October 2012 Monthly Sample Date October 2012 Monthly Result Q4 2012 Sample Date Q4 2012 Result December 2012 Monthly Sample Date December 2012 Monthly Result Sample Frequency MW-11 (Class II) Manganese (ug/L) 131.29 1/26/2012 102 2/13/2012 154 3/13/2012 121 4/10/2012 132 5/8/2012 127 6/19/2012 122 7/11/2012 135 8/7/2012 166 9/19/2012 130 10/23/2012 161 11/12/2012 138 12/24/2012 137 Quarterly Manganese (ug/L) 2230.30 NA 1790 NA NA 2360 NA 2100 2300 2140 2110 2100 1950 Quarterly Field pH (S.U.) 6.5 - 8.5 6.36 6.57 6.51 6.97 6.73 6.90 6.89 6.58 7.08 6.83 6.52 6.60 Quarterly Field pH (S.U.) 6.5 - 8.5 6.63 6.83 6.55 6.58 6.73 6.99 6.88 6.55 6.54 6.54 6.47 6.62 Quarterly Cadmium (ug/L) 1.5 NA 1.31 NA NA 1.33 NA 1.24 NA NA NA 1.56 NA Quarterly Chloride (mg/L) 35 NA 30 NA NA 30 NA 33 NA NA NA 28.8 NA Quarterly Uranium 6.5 6.6 6.5 6.93 6.52 5.90 7.6 6.45 6.72 6.01 6.37 6.61 4.83 Quarterly Nitrate + Nitrite (as N) (mg/L)0.62 1.9 2/15/2012 1.2 3 3.4 2.9 2.3 1.9 1.6 1.8 3.5 0.55 1.46 Quarterly Uranium (ug/L) 41.8 64.6 2/21/2012 59.4 31.2 42.2 18.2 66.0 28.4 67.4 64.9 26.9 56.8 51.3 Quarterly Chloroform (ug/L) 70 1900 3300 2900 2900 1700 2400 8/16/2012 970 2200 2300 4720 4020 1250 Quarterly Chloride (mg/L) 58.31 68 40 74 82 74 85 7/11/2012 78 78 67 2.62 52.9 65.9 Quarterly Field pH (S.U.) 6.74 - 8.5 6.59 2/15/2012 2/21/2012 6.72 (6.91) (6.71)6.39 6.88 7.00 (7.01) 7.00 7/11/2012 8/16/2012 7.10 (6.80)6.60 7.40 6.63 6.60 6.78 Quarterly Dichloromethane (Methylene Chloride) (ug/L) 5 13 2/15/2012 24 27 20 10 16 8/16/2012 4.9 17 9.8 15.0 34.6 5.5 Quarterly Nitrate + Nitrite (as N) (mg/L)2.5 17 17 18 17 16 15 17 18 16 16.2 18.5 17.2 Quarterly Chloride (mg/L) 128 124 126 128 128 124 131 128 139 130 135 114 122 Quarterly Uranium (ug/L) 8.32 NS NA 7.42 8.38 7.84 6.81 7.8 7.64 8.04 7.67 7.86 7.03 5.80 Quarterly Selenium (ug/L) 34 1/24/2012 33.3 35 39.5 39.1 32.3 37 38.5 38.4 41.9 45.2 36 31.6 Quarterly Nitrate + Nitrite (as N) (mg/L)5 21 21 22 21 20 21.6 21 21 21 18 23.6 22.2 Quarterly TDS (mg/L) 1320 1360 1240 1400 1380 1410 1460 1400 1400 1460 1320 1230 1270 Quarterly Chloride (mg/L) 143 155 150 152 160 151 138 161 175 172 157 189 170 Quarterly Selenium (ug/L) 71 NS 67.8 NS NS 70.2 NA 74 NA NA NA 76.9 NA Quarterly Sulfate (mg/L) 532 539 538 517 547 532 497 529 571 561 545 557 664 Quarterly Manganese (ug/L) 200 264 253 269 277 258 304 272 273 283 253 241 240 Quarterly Thallium (ug/l) 0.5 < 0.50 0.65 0.71 0.59 0.66 < 0.50 0.57 0.61 0.54 0.517 0.554 0.5 Quarterly Molybdenum (ug/L) 10 <10 <10 NA NA <10 NA <10 NA NA NA 30.4 NA Quarterly Gross Alpha minus Rn & U (pCi/L)3.75 6.5 4.1 6.2 4.1 4.5 4.9 3.5 4.2 5.4 4.31 4.23 6.5 Quarterly Selenium (ug/L) 12.5 NA 19.7 NA NA 11.4 7.0 15.9 18.8 8.2 19.0 15.4 12.1 Quarterly Uranium (ug/L) 7.5 16.1 24.7 24.9 22.4 22.2 22.5 24.5 26.2 22.9 22.4 21.8 21 Quarterly Manganese (ug/L) 289 NA NA NA NA 176 NA NA NA NA NA 315 NA Semi-Annually Tetrahydrofuran (ug/L)11.5 NA NA NA NA 10.3 NA NA NA NA NA 21.8 NA Semi-Annually Sulfate (mg/L) 838 NA NA NA NA 659 NA NA NA NA NA 846 NA Semi-Annually MW-2 (Class III)Gross Alpha minus Rn & U (pCi/L)3.2 NS NA 2/22/2012 0.6 NS NA NS NA 5/9/2012 0.6 NS NA 7/16/2012 0.9 NS NA NS NA NS NA 11/27/2012 1.46 NS NA Semi-Annually Selenium (ug/L) 37 NA 43.1 NA NA 52.8 NA 51.1 NA NA NA 58.9 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.63 NA NA 6.67 NA 6.99 NA NA NA 6.55 NA Semi-Annually Fluoride (mg/L) 0.68 NA 0.86 NA NA 1.04 NA 0.96 NA NA NA 1.26 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.46 NA NA 6.68 NA 7.01 NA NA NA 6.35 NA Semi-Annually Sulfate (mg/L) 3640 NA 3020 NA NA 3220 NA 3700 NA NA NA 2780 NA Semi-Annually Nitrate + Nitrite (as N) (mg/L)1.3 NA NA NA NA 1.1 NA NA NA NA NA 1.31 NA Semi-Annually TDS (mg/L) 5805 NA 5690 NA NA 5730 NA 5720 NA NA NA 5610 NA Semi-Annually Selenium (ug/L) 89 NA 65.8 NA NA 85.1 NA 99.3 NA NA NA 111 NA Semi-Annually MW-5 (Class II) Uranium (ug/L) 7.5 NS NA 2/28/2012 18.6 NS NA NS NA 5/9/2012 1.23 NS NA 7/16/2012 0.75 NS NA NS NA NS NA 11/27/2012 0.402 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.81 NA NA 6.91 NA 6.98 NA NA NA 6.54 NA Semi-Annually Selenium (ug/L) 25 NA 27.2 NA NA 19.6 NA 20.7 NA NA NA 23 NA Semi-Annually Selenium (ug/L) 128.7 NA NA NA NA 152 NA 120 NA NA NA 117 NA Semi-Annually Iron (ug/L) 81.7 NA < 30 NA NA < 30 NA < 30 NA NA NA <30 NA Semi-Annually Q1 2012 Results Q3 2012 Results 7/11/2012 7/10/2012 7/11/2012 6/19/2012 6/18/2012 6/19/2012 8/8/2012 3/14/2012 8/7/2012 9/18/2012 8/6/2012 9/18/20124/9/2012 5/2/2012 5/7/2012 6/26/2012 4/12/2012 Q2 2012 Results 3/14/2012MW-14 (Class III) 1/24/2012 NS NS NS NS 7/10/2012 8/8/2012 9/19/2012 7/18/2012 6/19/2012 NS NS NS 4/10/2012 5/14/2012 5/2/2012 5/1/2012 NS NS NS NS 7/17/2012 MW-3 (Class III)2/29/2012 MW-31 (Class III) 1/24/2012 2/13/2012 NS NS 3/1/2012 MW-3A (Class III) 2/21/2012 MW-25 (Class III) MW-30 (Class II) 1/24/2012 2/14/2012 1/25/2012 2/14/2012 3/14/2012 4/10/2012 5/2/2012 MW-26 (Class III) 1/25/2012 3/14/2012 4/11/2012 2/15/2012 Q4 2012 Results Required Quarterly Sampling Wells Required Semi-Annual Sampling Wells NSMW-01 (Class II) NS NS NS NS NS NS 5/9/2012 5/15/2012 5/10/2012 NSMW-15 (Class III) 7/19/2012 7/17/20122/22/2012 MW-12 (Class III) 2/29/2012NS NS NS NS NS NS NS NS NS NS NS 11/27/2012 11/28/2012 11/29/2012 11/27/2012 11/14/2012 NS NS NS NS NS NS 3/13/2012 4/9/2012 2/14/12MW-35 (Class II) 1/24/2012 3/13/12 11/27/2012 11/12/2012 9/19/2012 11/13/2012 11/6/2012 11/13/2012 12/18/2012 12/24/2012 12/26/2012 12/18/2012 12/18/2012 8/6/2012 9/18/2012 5/9/2012 10/23/2012 10/22/2012 6/18/2012 7/10/2012 8/7/2012 9/19/2012 10/24/2012 11/15/2012 12/24/2012 10/23/2012 10/22/2012 10/23/2012 NS NS NS 5/2/2012 6/18/2012 6/29/2012 7/9/2012 Page 5 of 8 APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class)Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP January 2012 Monthly Sample Date January 2012 Monthly Result Q1 2012 Sample Date Q1 2012 Result March 2012 Monthly Sample Date March 2012 Monthly Result April 2012 Monthly Sample Date April 2012 Monthly Result Q2 2012 Sample Date Q2 2012 Result June 2012 Monthly Sample Date June 2012 Monthly Result Q3 2012 Sample Date Q3 2012 Result August 2012 Monthly Sample Date August 2012 Monthly Result September 2012 Monthly Sample Date September 2012 Monthly Result October 2012 Monthly Sample Date October 2012 Monthly Result Q4 2012 Sample Date Q4 2012 Result December 2012 Monthly Sample Date December 2012 Monthly Result Sample Frequency Q1 2012 Results Q3 2012 ResultsQ2 2012 Results Q4 2012 Results Required Quarterly Sampling Wells Thallium (ug/l) 1.95 NA 3.63 NA NA 3.51 NA 3.73 NA NA NA 3.2 NA Semi-Annually Sulfate (mg/L) 1938.9 NA 1920 NA NA 1790 NA 1900 NA NA NA 1210 NA Semi-Annually Field pH (S.U.) 6.25-8.5 NA 6.6 NA NA 6.59 NA 6.64 NA NA NA 6.51 NA Semi-Annually TDS (mg/L) 3198.77 NA 3230 NA NA 3280 NA 3220 NA NA NA 3160 NA Semi-Annually Field pH (S.U.) 6.78-8.5 NA 6.83 NA NA 6.86 NA 7.21 NA NA NA 6.71 NA Semi-Annually Gross Alpha minus Rn & U (pCi/L)2.36 NA NA NA NA 0.9 NA NA NA NA NA 4.86 NA Semi-Annually Nitrate + Nitrite (as N) (mg/L)2.83 NA 3.9 NA NA 3.7 NA 4 NA NA NA 3.96 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.61 NA NA 6.74 NA 7.10 NA NA NA 6.61 NA Semi-Annually Manganese (ug/L) 550 NA 51 NA NA 49 NA 117 NA NA NA 54.3 NA Semi-Annually Cadmium (ug/L) 2.5 NA 2.25 NA NA 2.01 NA 4.7 NA NA NA 1.35 NA Semi-Annually Fluoride (mg/L) 0.36 NA NA NA NA 0.14 NA NA NA NA NA 0.558 Thallium (ug/L) 1 NA 0.96 NA NA 0.74 NA 1.36 NA NA NA 0.666 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.03 NA NA 6.21 NA 6.45 NA NA NA 6.01 NA Semi-Annually Nitrate + Nitrite (as N) (mg/L)5.6 NA 6.4 NA NA 6.2 NA 6.7 NA NA NA 6.9 NA Semi-Annually Chloride (mg/L) 38 NA 45 NA NA 46 NA 47 NA NA NA 44.2 NA Semi-Annually Sulfate (mg/L) 462 NA 451 NA NA 446 NA 453 NA NA NA 451 NA Semi-Annually Field pH (S.U.) 6.5-8.5 NA 7.24 NA NA 7.03 NA 7.40 NA NA NA 6.69 NA Semi-Annually TDS (mg/L) 1075 NA 1140 NA NA 1170 NA 1150 NA NA NA 1070 NA Semi-Annually Gross Alpha minus Rn & U (pCi/L)2NA2.3 NA NA 0.8 NA 1.2 NA NA NA 1.33 NA Semi-Annually Chloride (mg/L) 105 NA 109 NA NA 114 NA 7/16/2012 105 NA NA NA 115 NA Semi-Annually Manganese (ug/L) 1837 NA NA NA NA 1850 NA 8/1/2012 1660 NA NA NA 1680 NA Semi-Annually Field pH (S.U.) 6.1 - 8.5 NA 6.22 NA NA 6.15 NA 7/16/2012 8/1/2012 6.38 (5.81)NA NA NA 5.98 NA Semi-Annually Iron (ug/L) 1869 NA 1310 NA NA 1400 NA 7/16/2012 1270 NA NA NA 1350 NA Semi-Annually Manganese (ug/L) 5624 NA NA NA NA 6140 NA 8/1/2012 5190 NA NA NA 5040 NA Semi-Annually TDS (mg/L) 4400 NA NA NA NA 4600 NA 8/1/2012 4420 NA NA NA 4430 NA Semi-Annually Field pH (S.U.) 6.46 - 8.5 NA 7.12 NA NA 6.47 NA 7/16/2012 8/1/2012 6.68 (6.45)NA NA NA 6.48 NA Semi-Annually Gross Alpha minus Rn & U (pCi/L)3.33 NA 1.8 NA NA 2.4 NA 1.4 NA NA NA 2.97 NA Semi-Annually Field pH (S.U.) 6.4 - 8.5 NA 6.57 NA NA 6.40 NA 6.72 NA NA NA 6.23 NA Semi-Annually Notes: NS NS NS NS NS 7/18/2012 7/19/2012 7/17/2012 7/18/20125/10/2012 5/1/2012 5/8/2012 GWCL values are taken from the August 24, 2012 version of the GWDP. MW-32 (Class III) 2/21/2012 MW-19 (Class III)2/28/2012 NS NS NS NS NS NS NS NS NS 4/30/2012 5/16/2012 5/16/2012 NS NS NS NS NS MW-29 (Class III) NS NS NSMW-23 (Class III) MW-18 (Class III) 7/16/2012 7/9/2012 2/22/2012 MW-28 (Class III) 2/28/2012 MW-27 (Class III)2/28/2012 2/27/2012 2/20/2012 MW-24 (Class III)2/23/2012 5/8/2012 NS 4/30/2012 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 11/26/2012 12/13/2012 12/5/2012 11/29/2012 11/13/2012 11/14/2012 11/14/2012 11/6/2012 NS NS NS NS NS NS NS NS NS NS NS Exceedances are shown in yellow. Values in () parentheses are the field pH measurements for the ug/L = micrograms per liter mg/L = milligrams per liter NS = Not Required and Not Sampled NR = Required and Not Reported NA = Not Applicable pCi/L = picocuries per liter SU = Standard Units Page 6 of 8 APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class)Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP January 2013 Monthly Sample Date January 2013 Monthly Result Q1 2013 Sample Date Q1 2013 Result March 2013 Monthly Sample Date March 2013 Monthly Result Sample Frequency MW-11 (Class II) Manganese (ug/L) 131.29 1/23/2013 115 2/20/2013 139 3/20/2013 164 Quarterly Manganese (ug/L) 2230.30 1930 2250 2110 Quarterly Field pH (S.U.) 6.5 - 8.5 6.48 6.52 6.48 Quarterly Field pH (S.U.) 6.5 - 8.5 6.65 6.62 6.41 Quarterly Cadmium (ug/L) 1.5 NS 1.35 1.40 Quarterly Chloride (mg/L) 35 NS 36.1 NS Quarterly Uranium 6.5 5.97 5.39 5.68 Quarterly Nitrate + Nitrite (as N) (mg/L)0.62 1.66 1.38 1.61 Quarterly Uranium (ug/L) 41.8 65.7 57.8 69 Quarterly Chloroform (ug/L) 70 1270 1500 1340 Quarterly Chloride (mg/L) 58.31 63.5 77 73.6 Quarterly Field pH (S.U.) 6.74 - 8.5 6.51 6.71 6.70 Quarterly Dichloromethane (Methylene Chloride) (ug/L) 5 6.49 5.53 8.31 Quarterly Nitrate + Nitrite (as N) (mg/L)2.5 19.2 21.4 14.3 Quarterly Chloride (mg/L) 128 128 129 126 Quarterly Uranium (ug/L) 8.32 8.36 7.4 6.85 Quarterly Selenium (ug/L) 34 37.2 42.3 39 Quarterly Nitrate + Nitrite (as N) (mg/L)5 22.8 19.3 19.1 Quarterly TDS (mg/L) 1320 1270 1390 1420 Quarterly Chloride (mg/L) 143 176 174 168 Quarterly Selenium (ug/L) 71 NS 74.1 81.8 Quarterly Sulfate (mg/L) 532 611 644 611 Quarterly Manganese (ug/L) 200 247 272 246 Quarterly Thallium (ug/l) 0.5 <0.5 <0.5 0.505 Quarterly Molybdenum (ug/L) 10 NS <10 <10 Quarterly Gross Alpha minus Rn & U (pCi/L)3.75 6.62 5.09 9.51 Quarterly Selenium (ug/L) 12.5 11.0 10.8 22.6 Quarterly Uranium (ug/L) 7.5 23.6 21.3 22.1 Quarterly Manganese (ug/L) 289 NA 173 NA Semi-Annually Tetrahydrofuran (ug/L) 11.5 NA 12.6 NA Semi-Annually Sulfate (mg/L) 838 NA 761 NA Semi-Annually MW-2 (Class III)Gross Alpha minus Rn & U (pCi/L)3.2 NS NA 3/5/2013 1.06 NS NA Semi-Annually Selenium (ug/L) 37 NA 51.8 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.20 NA Semi-Annually Fluoride (mg/L) 0.68 NA 0.902 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.84 NA Semi-Annually Sulfate (mg/L) 3640 NA 3480 NA Semi-Annually Nitrate + Nitrite (as N) (mg/L)1.3 NA 1.22 NA Semi-Annually TDS (mg/L) 5805 NA 5750 NA Semi-Annually Selenium (ug/L) 89 NA 88.7 NA Semi-Annually MW-5 (Class II) Uranium (ug/L) 7.5 NS NA 3/11/2013 36 NS NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.56 NA Semi-Annually Selenium (ug/L) 25 NA 19.6 NA Semi-Annually Selenium (ug/L) 128.7 NA 137 NA Semi-Annually Iron (ug/L) 81.7 NA <30 NA Semi-Annually MW-12 (Class III) NS 3/6/2013 NS MW-15 (Class III) NS 3/5/2013 NS MW-3A (Class III)NS 3/13/2013 NS MW-3 (Class III)NS 3/12/2013 NS MW-01 (Class II) NS 3/12/2013 NS Required Semi-Annual Sampling Wells MW-35 (Class II) 1/23/2013 2/26/2013 3/19/13 MW-31 (Class III) 1/22/2013 2/19/2013 3/19/2013 1/23/2013MW-30 (Class II)2/26/2013 3/20/2013 MW-26 (Class III) 1/24/2013 3/20/20132/20/2013 MW-25 (Class III) 1/22/2013 2/20/2013 3/19/2013 Q1 2013 Results MW-14 (Class III) 1/23/2013 2/26/2013 3/20/2013 Required Quarterly Sampling Wells Page 7 of 8 APPENDIX A GWCL Exceedances for First Quarter 2013 under the August 24, 2012 GWDP Source Assessment Report for TDS In MW-29 White Mesa Uranium Mill, Blanding, Utah May 7, 2013 Monitoring Well (Water Class)Constituent Exceeding GWCL GWCL in August 24, 2012 GWDP January 2013 Monthly Sample Date January 2013 Monthly Result Q1 2013 Sample Date Q1 2013 Result March 2013 Monthly Sample Date March 2013 Monthly Result Sample Frequency Q1 2013 Results Required Quarterly Sampling Wells Thallium (ug/l) 1.95 NA 3.26 NA Semi-Annually Sulfate (mg/L) 1938.9 NA 1270 NA Semi-Annually Field pH (S.U.) 6.25-8.5 NA 6.35 NA Semi-Annually TDS (mg/L) 3198.77 NA 3350 NA Semi-Annually Field pH (S.U.) 6.78-8.5 NA 6.50 NA Semi-Annually Gross Alpha minus Rn & U (pCi/L)2.36 NA 1.11 NA Semi-Annually Nitrate + Nitrite (as N) (mg/L)2.83 NA 3.61 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.37 NA Semi-Annually Manganese (ug/L) 550 NA 137 NA Semi-Annually Cadmium (ug/L) 2.5 NA 2.0 NA Semi-Annually Fluoride (mg/L) 0.36 NA 0.355 NA Thallium (ug/L) 1 NA 0.88 NA Semi-Annually Field pH (S.U.) 6.5 - 8.5 NA 6.29 NA Semi-Annually Nitrate + Nitrite (as N) (mg/L)5.6 NA 7.94 NA Semi-Annually Chloride (mg/L) 38 NA 50.3 NA Semi-Annually Sulfate (mg/L) 462 NA 431 NA Semi-Annually Field pH (S.U.) 6.5-8.5 NA 7.03 NA Semi-Annually TDS (mg/L) 1075 NA 1140 NA Semi-Annually Gross Alpha minus Rn & U (pCi/L)2 NA <1.0 NA Semi-Annually Chloride (mg/L) 105 NA 110 NA Semi-Annually Manganese (ug/L) 1837 NA 1680 NA Semi-Annually Field pH (S.U.) 6.1 - 8.5 NA 6.00 NA Semi-Annually Iron (ug/L) 1869 NA 1350 NA Semi-Annually Manganese (ug/L) 5624 NA 5340 NA Semi-Annually TDS (mg/L) 4400 NA 4500 NA Semi-Annually Field pH (S.U.) 6.46 - 8.5 NA 6.36 NA Semi-Annually Gross Alpha minus Rn & U (pCi/L)3.33 NA 5.02 NA Semi-Annually Field pH (S.U.) 6.4 - 8.5 NA 6.52 NA Semi-Annually Notes: MW-32 (Class III) NS 2/19/2013 NS MW-29 (Class III) NS 3/6/2013 NS MW-28 (Class III) NS 3/5/2013 NS MW-27 (Class III)NS 2/25/2013 NS MW-24 (Class III)NS 3/13/2013 NS MW-23 (Class III) NS 3/11/2013 NS MW-19 (Class III)NS 3/13/2013 NS MW-18 (Class III)NS 2/25/2013 NS GWCL values are taken from the August 24, 2012 version of the GWDP. Exceedances are shown in yellow. Values in () parentheses are the field pH measurements for the resampled analyses. ug/L = micrograms per liter mg/L = milligrams per liter NS = Not Required and Not Sampled NR = Required and Not Reported NA = Not Applicable pCi/L = picocuries per liter SU = Standard Units Page 8 of 8 APPENDIX B Geochemical Analysis for TDS in MW-29 Appendix B-1: Summary of Geochemical Analysis for TDS in MW-29 Wp Normally or Lognormally distributed? r 2 p Flowsheet GWCL Rationale MW-29 TDS 25 0 4347 112 0.9485 0.2314 Yes 0.0006 0.908 No No 4600 4570 4400 4400 4570 Mean +2SD Notes: σ = sigma N = number of valid data points %ND = percent of non-detected values p = probability µg/L = micrograms per liter W = Shapiro Wilk test value mg/L = milligrams per liter r2 = The measure of how well the trendline fits the data where r2=1 represents a perfect fit. Distribution = Distribution as determined by the Shapiro-Wilk distribution test for constituents with % Detect > 50% and N>8 Mean = The arithmatic, Cohen, or Aitchison mean as determined for normally or log-normally distributed constituents with % Detect > 50% Standard Deviation = The standard deviation as determined for normally or log-normally distributed constituents with % Detect > 85% Highest Historical Value = The highest observed value for constituents with % Detect < 50% Significant Trend Previously Identified Increasing Trend? Flowsheet GWCL Standard Deviation Shapiro-Wilks Test for Normality Well Constituent N % Non- Detected Values Mean Highest Historical Value (HHV) Mean + 2σ BKG Rpt Proposed GWCL Current GWCL Least Squares Regression Trend Analysis APPENDIX B Geochemical Analysis for TDS in MW-29 Source Assessment Report for TDS in MW-29 May 7, 2013 Page 1 of 7 Appendix B‐2 Comparison of Calculated and Measured TDS in MW‐29 Well Date CO3+HCO3 as Alkalinity (mg/L) Calcium (mg/L) Chloride (mg/L) Potassium (mg/L) Magnesium (mg/L) Sodium (mg/L) Sulfate (mg/L) Measured TDS (mg/L) Calculated TDS (mg/L)Ratio MW‐29 3/19/2008 345 461 39 17.2 206 466 2840 4430 4374.2 98.74% MW‐29 6/3/2008 321 470 38 16.8 218 486 2840 4190 4389.8 104.77% MW‐29 8/5/2008 330 524 35 17.5 238 494 2810 4340 4448.5 102.50% MW‐29 11/5/2008 328 518 32 18.1 231 508 2920 4380 4555.1 104.00% MW‐29 2/3/2009 331 508 31 13.7 228 377 2710 4180 4198.7 100.45% MW‐29 5/13/2009 339 437 30 15.2 201 439 2790 4260 4251.2 99.79% MW‐29 8/24/2009 349 496 34 17.5 220 501 2720 4230 4337.5 102.54% MW‐29 10/26/2009 352 488 35 17 216 455 2960 4260 4523 106.17% MW‐29 4/27/2010 358 506 35 17.4 225 516 2770 4400 4427 100.62% MW‐29 11/9/2010 355 470 39 17.4 211 454 2690 4390 4236 96.50% MW‐29 4/5/2011 351 482 38 17.3 213 496 2600 4080 4197 102.88% MW‐29 10/5/2011 327 476 37 16.7 213 435 2850 4280 4355 101.75% MW‐29 5/8/2012 347 496 40 19.9 227 487 2750 4600 4367 94.93% MW‐29 11/14/2012 283 483 36.9 17.2 219 487 1340 4430 2866 64.70% APPENDIX B Geochemical Analysis for TDS in MW-29 Source Assessment Report for TDS in MW-29 May 7, 2013 Page 2 of 7 Appendix B‐3 Charge Balance Calcultions for Major Cations and Anions in MW‐29 Well Date Calcium (meq/L) Sodium (meq/L) Magnesium (meq/L) Potassium (meq/L) Total Cation Charge (meq/L) HCO3 (meq/L) Chloride (meq/L) SO4 (meq/L) Total Anion Charge (meq/L) Percent Difference MW‐29 3/19/2008 23.00 20.27 16.95 0.44 60.66 ‐5.65 ‐1.10 ‐59.13 ‐65.88 ‐8.61% MW‐29 6/3/2008 23.45 21.14 17.94 0.43 62.96 ‐5.26 ‐1.07 ‐59.13 ‐65.46 ‐3.98% MW‐29 8/5/2008 26.15 21.49 19.58 0.45 67.66 ‐5.41 ‐0.99 ‐58.51 ‐64.90 4.08% MW‐29 11/5/2008 25.85 22.10 19.00 0.46 67.41 ‐5.38 ‐0.90 ‐60.80 ‐67.07 0.50% MW‐29 2/3/2009 25.35 16.40 18.76 0.35 60.86 ‐5.42 ‐0.87 ‐56.42 ‐62.72 ‐3.07% MW‐29 5/13/2009 21.81 19.10 16.54 0.39 57.83 ‐5.56 ‐0.85 ‐58.09 ‐64.49 ‐11.52% MW‐29 8/24/2009 24.75 21.79 18.10 0.45 65.09 ‐5.72 ‐0.96 ‐56.63 ‐63.31 2.73% MW‐29 10/26/2009 24.35 19.79 17.77 0.43 62.35 ‐5.77 ‐0.99 ‐61.63 ‐68.38 ‐9.68% MW‐29 4/27/2010 25.25 22.44 18.51 0.45 66.65 ‐5.87 ‐0.99 ‐57.67 ‐64.53 3.19% MW‐29 11/9/2010 23.45 19.75 17.36 0.45 61.00 ‐5.82 ‐1.10 ‐56.01 ‐62.92 ‐3.15% MW‐29 4/5/2011 24.05 21.57 17.52 0.44 63.59 ‐5.75 ‐1.07 ‐54.13 ‐60.96 4.14% MW‐29 10/5/2011 23.75 18.92 17.52 0.43 60.62 ‐5.36 ‐1.04 ‐59.34 ‐65.74 ‐8.44% MW‐29 5/8/2012 24.75 21.18 18.68 0.51 65.12 ‐5.69 ‐1.13 ‐57.26 ‐64.07 1.61% MW‐29 11/14/2012 24.10 21.18 18.02 0.44 63.74 ‐4.64 ‐1.04 ‐27.90 ‐33.58 47.32% Notes: HCO3 = Bicarbonate SO4 = Sulfate meq/L= milliequivalent per liter APPENDIX B Geochemical Analysis for TDS in MW-29 Source Assessment Report for TDS in MW-29 May 7, 2013 Page 3 of 7 Appendix B-4 Descriptive Statistics for TDS in MW-29 N Mean Geometric Mean Standard Deviation Q25 Median Q75 Minimum Maximum Range Skewness 2013 All 25 4347 4346 112 4260 4380 4400 4080 4600 520 -0.26 Bkgr rpt Without extremes 8 4380 4380 27 4375 4385 4400 4320 4400 80 -1.9 Bkgr rpt All 10 4381 4381 68 4370 4385 4400 4250 4520 270 0.1 Data Set APPENDIX B Geochemical Analysis for TDS in MW-29 Source Assessment Report for TDS in MW-29 May 7, 2013 Page 4 of 7 Appendix B‐5 Box Plot for TDS in MW‐29 Box Plot TDS in MW-29 4000 4100 4200 4300 4400 4500 4600 4700 To t a l D i s s o l v e d S o l i d s ( m g / L ) Median = 4380 25%-75% = (4260, 4400) Non-Outlier Range = (4080, 4600) Outliers Extremes Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; %  *HRFKHPLFDO $QDO\VLV IRU 7'6 LQ 0:  3DJH  RI  Appendix B‐6 Histogram for TDS in MW‐29 Histogram TDS in MW-29 SW-W = 0.9485, p = 0.2314 3.60 3.61 3.62 3.63 3.64 3.65 3.66 3.67 Log Transformed Result 0 2 4 6 8 10 12 14 No o f o b s Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; %  *HRFKHPLFDO $QDO\VLV IRU 7'6 LQ 0:  3DJH  RI  Appendix B‐7 Linear Regression of TDS in MW‐29 Linear RegressionTDS in MW-29 r = -0.0244, p = 0.9080; r2 = 0.0006 1/14/04 5/28/05 10/10/06 2/22/08 7/6/09 11/18/10 4/1/12 8/14/13 Date Sampled 4000 4100 4200 4300 4400 4500 4600 4700 To t a l D i s s o l v e d S o l i d s ( m g / L ) Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; %  *HRFKHPLFDO $QDO\VLV IRU 7'6 LQ 0:  3DJH  RI  APPENDIX C Geochemical Analysis for Indicator Parameters in MW-29 Appendix C-1: Summary of Geochemical Analysis for Indicator Parameters in MW-29 Wp Normally or Lognormally distributed? r 2 pSp MW-29 Chloride (mg/L) 24 0 37 3 0.8996 0.0211 No -67 0.049 No DecreasingMW-29 Fluoride (mg/L) 23 0 0.792 0.063 0.9669 0.6146 Yes 0.239 0.0179 No DecreasingMW-29 Sulfate (mg/L) 23 0 2787 89 0.9627 0.519 Yes 0.011 0.6363 No No MW-29 Uranium (µg/L) 23 0 11 0.96 0.8644 0.005 No 55 0.0758 No No Notes: σ = sigma N = number of valid data points S = MannKendall statistic %ND = percent of non-detected values p = probability µg/L = micrograms per liter W = Shapiro Wilk test value mg/L = milligrams per liter r2 = The measure of how well the trendline fits the data where r2=1 represents a perfect fit. a = A regression test was performed on data that was determined to have normal or log-normal distribution b = The Mann-Kendall test was performed on data that are not normally or lognormally distributed Shapiro-Wilks Test for Normality Least Squares Regression Trend Analysisa Mann-Kendall Trend Analysisb Significant Trend Previously Identified Increasing Trend? Standard DeviationWell Constituent N % Non- Detected Values Mean APPENDIX C Geochemical Analysis for Indicator Parameters in MW-29 Source Assessment Report for TDS in MW-29 May 7, 2013 Page 1 of 10 Appendix C-2 Descriptive Statistics for Indicator Parameters in MW-29 Data Set Parameter Mean N Minimum Maximum Std.Dev. Range Geometric Mean Skewness Q25 Median Q75 All Chloride (mg/L) 37 24 30 41 3 11 37 -0.92 35 37 39 Extremes Removed Fluoride (mg/L) 0.79 23 0.68 0.95 0.06 0.27 0.79 0.83 0.76 0.78 0.83 All Fluoride (mg/L) 0.81 24 0.68 1.10 0.09 0.42 0.80 1.86 0.76 0.79 0.84 Extremes Removed Sulfate (mg/L) 2787 23 2600 2980 89 380 2786 0.41 2720 2780 2840 All Sulfate (mg/L) 2727 24 1340 2980 308 1640 2702 -4.27 2715 2775 2840 Extremes Removed Uranium (ug/L) 11 23 8 13 0.96 5 11 -1.31 11 11 12 All Uranium (ug/L) 13 24 8 49 7.80 41 12 4.78 11 11 12 APPENDIX C Geochemical Analysis for Indicator Parameters in MW-29 Source Assessment Report for TDS in MW-29 May 7, 2013 Page 2 of 10 Appenidx C-3 Data Omitted from Analysis Reason Well Sample Date Chemical Result Qualifier Detection Limit Units Extreme outlier MW‐29 11/14/2012 Sulfate 1340 1000 mg/L Extreme outlier MW‐29 12/14/2005 Uranium 49 0.3 ug/L Extreme outlier MW‐29 6/24/2005 Fluoride 1.1 mg/L APPENDIX C Geochemical Analysis for Indicator Parameters in MW-29 Source Assessment Report for TDS in MW-29 May 7, 2013 Page 3 of 10 Appendix C‐4 Box Plots for Indicator Parameters in MW‐29 Chloride in MW-29 28 30 32 34 36 38 40 42 Ch l o r i d e ( m g / L ) Median 25%-75% Non-Outlier Range Outliers Extremes Sulfate in MW-29 2550 2600 2650 2700 2750 2800 2850 2900 2950 3000 Su l f a t e ( m g / L ) Median 25%-75% Non-Outlier Range Outliers Extremes Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; &  *HRFKHPLFDO $QDO\VLV IRU ,QGLFDWRU 3DUDPHWHUV LQ 0: Page 4 of 10 Appendix C‐4 Box Plots for Indicator Parameters in MW‐29 Uranium in MW-29 7 8 9 10 11 12 13 Ur a n i u m ( u g / L ) Median 25%-75% Non-Outlier Range Outliers Extremes Fluoride in MW-29 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 Fl u o r i d e ( m g / L ) Median 25%-75% Non-Outlier Range Outliers Extremes Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; &  *HRFKHPLFDO $QDO\VLV IRU ,QGLFDWRU 3DUDPHWHUV LQ 0: Page 5 of 10 Appendix C‐5 Histograms for Indicator Parameters in MW‐29 Histogram Chloride in MW-29 SW-W = 0.8996, p = 0.0211 1.46 1.48 1.50 1.52 1.54 1.56 1.58 1.60 1.62 1.64 Log Result 0 1 2 3 4 5 6 7 8 9 No o f o b s Histogram Fluoride in MW-29 SW-W = 0.9669, p = 0.6146 -0.20 -0.18 -0.16 -0.14 -0.12 -0.10 -0.08 -0.06 -0.04 -0.02 0.00 Log Result 0 2 4 6 8 10 12 No o f o b s Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; &  *HRFKHPLFDO $QDO\VLV IRU ,QGLFDWRU 3DUDPHWHUV LQ 0: Page 6 of 10 Appendix C‐5 Histograms for Indicator Parameters in MW‐29 Histogram Sulfate in MW-29 SW-W = 0.9627, p = 0.5190 3.40 3.41 3.42 3.43 3.44 3.45 3.46 3.47 3.48 3.49 Log Result 0 1 2 3 4 5 6 7 8 9 No o f o b s Histogram Uranium in MW-29 SW-W = 0.8644, p = 0.0050 0.88 0.90 0.92 0.94 0.96 0.98 1.00 1.02 1.04 1.06 1.08 1.10 1.12 1.14 Log Result 0 1 2 3 4 5 6 7 8 No o f o b s Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; &  *HRFKHPLFDO $QDO\VLV IRU ,QGLFDWRU 3DUDPHWHUV LQ 0: Page 7 of 10 Appendix C‐6 Linear Regressions for Normally or Lognormally Distributed  Indicator Parameters in MW‐29 Linear Regression for Fluoride in MW-29 r = -0.4891, p = 0.0179; r2 = 0.2392 2/17/2005 3/24/2006 4/28/2007 6/1/2008 7/6/2009 8/10/2010 9/14/2011 10/18/2012 Date Sampled 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 Fl u o r i d e ( m g / L ) Linear Regression for Sulfate in MW-29 r = -0.1041, p = 0.6363; r2 = 0.0108 2/17/2005 3/24/2006 4/28/2007 6/1/2008 7/6/2009 8/10/2010 9/14/2011 10/18/2012 Date Sampled 2550 2600 2650 2700 2750 2800 2850 2900 2950 3000 Su l f a t e ( m g / L ) Source Assessment Report TDS in MW-29 May 7, 2013 $33(1',; &  *HRFKHPLFDO $QDO\VLV IRU ,QGLFDWRU 3DUDPHWHUV LQ 0: Page 8 of 10 Appendix C‐7 Mann‐Kendal Analysis for Indicator Parameters Not Distributed Normally or Lognormally Chloride User Selected Options    Date/Time of Computation   3/7/2013 23:29 From File   Cl.wst Full Precision   OFF Confidence Coefficient   0.95 Level of Significance   0.05 Chloride General Statistics Number of Values 24 Minimum 30 Maximum 41 Mean 36.79 Geometric Mean 36.68 Median 37 Standard Deviation 2.858 SEM 0.583 Mann‐Kendall Test Test Value (S)‐67 Critical Value (0.05)‐1.645 Standard Deviation of S 39.9 Standardized Value of S ‐1.654 Approximate p‐value 0.049 Statistically significant evidence of a decreasing trend at the specified level of significance. Source Assessment Report for TDS in MW-29 May 7, 2013 Page 9 of 10 Appendix C‐7 Mann‐Kendal Analysis for Indicator Parameters Not Distributed Normally or Lognormally Uranium User Selected Options    Date/Time of Computation   3/7/2013 23:27 From File   U.wst Full Precision   OFF Confidence Coefficient   0.95 Level of Significance   0.05 Uranium General Statistics Number of Values 23 Minimum 8.1 Maximum 12.7 Mean 11.07 Geometric Mean 11.03 Median 11.1 Standard Deviation 0.955 SEM 0.199 Mann‐Kendall Test Test Value (S)55 Critical Value (0.05)1.645 Standard Deviation of S 37.66 Standardized Value of S 1.434 Approximate p‐value 0.0758 Insufficient evidence to identify a significant  trend at the specified level of significance. Source Assessment Report for TDS in MW-29 May 7, 2013 Page 10 of 10 APPENDIX D Time Concentration Plot Comparison Appendix D-1 Time Concentration Plot Comparison for TDS in MW-29 Linear Regression TDS in MW-29 r = -0.0244, p = 0.9080; r2 = 0.0006 1/14/04 5/28/05 10/10/06 2/22/08 7/6/09 11/18/10 4/1/12 8/14/13 Date Sampled 4000 4100 4200 4300 4400 4500 4600 4700 To t a l D i s s o l v e d S o l i d s ( m g / L ) TDS in MW-29 From the New Wells Background Report r = -0.1573, p = 0.7098; r2 = 0.0248 2/17/05 5/28/05 9/5/05 12/14/05 3/24/06 7/2/06 10/10/06 1/18/07 4/28/07 8/6/07 11/14/07 2/22/08 Date 4310 4320 4330 4340 4350 4360 4370 4380 4390 4400 4410 TD S ( m g / L ) Source Assessment Report TDS in MW‐29 May 7, 2013 Appendix D-2 Time Concentration Plots Comparison for Indicator Parameters in MW-29 Linear Regression for Chloride in MW-29 r = -0.2246, p = 0.2913; r2 = 0.0505 1/14/2004 5/28/2005 10/10/2006 2/22/2008 7/6/2009 11/18/2010 4/1/2012 8/14/2013 Date Sampled 28 30 32 34 36 38 40 42 Ch l o r i d e ( m g / L ) Chloride in MW-29 From the New Wells Background Report r = -0.4064, p = 0.2439; r2 = 0.1652 2/17/05 5/28/05 9/5/05 12/14/05 3/24/06 7/2/06 10/10/06 1/18/07 4/28/07 8/6/07 11/14/07 2/22/08 Date 35 36 37 38 39 40 41 42 Ch l o r i d e ( m g / L ) Source Assessment Report TDS in MW‐29 May  7, 2013 Appendix D-2 Time Concentration Plots Comparison for Indicator Parameters in MW-29 Linear Regression for Fluoride in MW-29 r = -0.4891, p = 0.0179; r2 = 0.2392 2/17/2005 3/24/2006 4/28/2007 6/1/2008 7/6/2009 8/10/2010 9/14/2011 10/18/2012 Date Sampled 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 Fl u o r i d e ( m g / L ) Fluoride in MW-29 From the New Wells Background Report r = -0.2504, p = 0.4853; r2 = 0.0627 2/17/05 9/5/05 3/24/06 10/10/06 4/28/07 11/14/07 Date 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 1.05 1.10 1.15 Fl u o r i d e ( m g / L ) Source Assessment Report TDS in MW‐29 May  7, 2013 Appendix D-2 Time Concentration Plots Comparison for Indicator Parameters in MW-29 Linear Regression for Sulfate in MW-29 r = -0.1041, p = 0.6363; r2 = 0.0108 2/17/2005 3/24/2006 4/28/2007 6/1/2008 7/6/2009 8/10/2010 9/14/2011 10/18/2012 Date Sampled 2550 2600 2650 2700 2750 2800 2850 2900 2950 3000 Su l f a t e ( m g / L ) Sulfate in MW-29 From the New Wells Background Report r = 0.2296, p = 0.5234; r2 = 0.0527 2/17/05 5/28/05 9/5/05 12/14/05 3/24/06 7/2/06 10/10/06 1/18/07 4/28/07 8/6/07 11/14/07 2/22/08 Date 2650 2700 2750 2800 2850 2900 2950 3000 Su l f a t e ( m g / L ) Source Assessment Report TDS in MW‐29 May  7, 2013 Appendix D-2 Time Concentration Plots Comparison for Indicator Parameters in MW-29 Linear Regression for Uranium in MW-29 r = 0.4436, p = 0.0340; r2 = 0.1968 1/14/2004 5/28/2005 10/10/2006 2/22/2008 7/6/2009 11/18/2010 4/1/2012 8/14/2013 Date Sampled 7 8 9 10 11 12 13 Ur a n i u m ( u g / L ) Uranium in MW-29 From the New Wells Background Report r = 0.2046, p = 0.5974; r2 = 0.0419 5/28/05 9/5/05 12/14/05 3/24/06 7/2/06 10/10/06 1/18/07 4/28/07 8/6/07 11/14/07 2/22/08 Date 9.4 9.6 9.8 10.0 10.2 10.4 10.6 10.8 11.0 11.2 11.4 11.6 11.8 12.0 12.2 12.4 Ur a n i u m ( u g / L ) Source Assessment Report TDS in MW‐29 May  7, 2013 APPENDIX E Flowsheet (Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site (INTERA, 2007a)) Negative Value? Zero Value? Truncated Value? Duplicate Value? Units Consistant? Non-detects Exceeding Criteria Specified by URS Memo* Analysis Internally Consistent?(TDS and Charge Balance Check) YesNo No Yes No No No Yes Yes No Yes Yes Yes Radionuclide? Yes Remove from DatasetDetection Limit and U-Flag Data Qualifier NoNo Review for Units Remove from Dataset If chloride, sulfate, or TDS, Remove from Dataset Correct Value Confirmed? Remove from Dataset Remove from Dataset Determine Percentage Non-Detects in Remaining Data Plot Data Sets as Box Plots to Identify Extreme Values As Specified in Background Report. Extreme Value? No Remove from Dataset Yes At Least 8 Data Points Remaining? Defer Analysis Until Eight Data Points Avalible 0-15 Percent Non-Detects >15-50 Percent Non-Detects >90 Percent Non-Detects No Yes No Substitute One Half of Detection Limit Log Transform Data Use Probability Plots to Determine if Cohen’s or Aitchison’s Method Calculate Descriptive Statistics (Redo Tables In Background Report) Screen for Trends Using Least Squares Regression. Calculate GWCL (Mean +2Sigma) Calculate Descriptive Statistics (Redo Tables In Background Report) Yes No Calculate GWCL (Mean +2Sigma) Calculate GWCL Using Greater of Fraction Approach under UAC R317-6-4-4.5(B)(2) or 4.6(B)(2) or Poisson Prediction Limit Yes No >50-90 Percent Non-Detects Calculate Upper Prediction Limit (Highest Historical Value) Calculate GWCL Using Greater of Fraction Approach under UAC R317-6-4-4.5(B)(2) or 4.6(B)(2) or the Highest Historic Value Estimate Mean and Standard Deviation Screen for Trends Using Mann-Kendall Screen for Trends Using Mann-Kendall Yes Use Non-Parametric StatisticsNo Screen for Trends Using Least Squares Regression Groundwater Data Preparation and Statistical Process Flow for Calculating Groundwater Protection Standards, White Mesa Mill Site, San Juan County, Utah Upward Trend?Upward Trend? No No Yes Consider Modified Approch to GWCL Upward Trend?Upward Trend? No No Yes Consider Modified Approch to GWCL Log Transform Data Log-Normal or Normal?Shapiro WilkProbability PlotsHistograms Log-Normal or Normal?Shapiro WilkProbability PlotsHistograms *A non-detect considered “insensitive” will be the maximum reporting limit in a dataset and will exceed other non-detects by, for example, an order of magnitude (e.g., <10 versus <1.0 µg/L). In some cases, insensitive non-detects may also exceed detectable values in a dataset (e.g., <10 versus 3.5 µg/L). Groundwater Data Preparation and Statistical Process Flow for Calculating Ground Water Compliance Limits, White Mesa Mill Site, SanJuan County, Utah. Database of Wells and Analytes Listed in the Statement of Basis APPENDIX F Input and Output Files (Electronic Only)