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HomeMy WebLinkAboutDRC-2009-007083 - 0901a0688015a1f1tJ^C'c^-^t'^IC^d VIA FEDERAL EXPRESS December 30, 2009 Mr. Dane Finerfrock, Executive Secretary Utah Radiation Control Board Utah Department of Environmental Quality 168 North 1950 West P.O. Box 144810 Sah Lake City, UT 84114-4810 Dear Mr. Finerfrock: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver, CO 80265 USA Tel : 303 628-7798 Fax : 303 389-4125 www.denisonmines.com Re: White Mesa Uranium Mill, Stipulated Consent Agreement, Docket No. UGW09-03 - Submittal of Nitrate Contamination Investigation Report Reference is made to the Stipulated Consent Agreement (the "Agreement") between Denison Mines (USA) Corp. ("Denison") and the Utah Water Quality Board, Docket No. UGW09-03, conceming potential violations of the Utah Water Quality Act, including sections 19-5-104, - 106, -111 and -115, Utah Code Annotated and in accordance with the Utah Administrative Procedures Act, UCA 63G-4-101 to -601. Pursuant to paragraph 6A of the Agreement, please find enclosed two copies of the Nitrate Contamination Investigation Report, dated December 30, 2009 (the "Report"), prepared by INTERA, Inc. on behalf of and under the direction of Denison. Also enclosed are two CDs each containing an electronic copy of the Report. I certify under penalty of law that the Report and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, tme, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. If you should have any questions or require additional information, please contact the undersigned or David C. Frydenlund, Denison's Vice President, Regulatory Affairs and Counsel at 303 389-4132. OENISONI)~~ MINES VIA FEDERAL EXPRESS December 30, 2009 Mr. Dane Finerfrock, Executive Secretary Utah Radiation Control Board Utah Department of Environmental Quality 168 North 1950 West P.O. Box 144810 Salt Lake City, UT 84114-48 10 Dear Mr. Finerfrock: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver, CO 80265 USA Tel : 303 628-7798 Fax: 303 389-4125 www.denlsonmines.com Re: White Mesa Uranium Mill, Stipulated Consent Agreement, Docket No. UGW09-03 -Submittal of Nitrate Contamination Investigation Report Reference is made to the Stipulated Consent Agreement (the "Agreement") between Denison Mines (USA) Corp. ("Denison") and the Utah Water Quality Board, Docket No. UGW09-03, concerning potential violations of the Utah Water Quality Act, including sections 19-5-104, - 106, -III and -1 15, Utah Code Atmotated and in accordance with the Utah Administrative Procedures Act, UCA 63G-4-1 0 I to -601. Pursuant to paragraph 6A of the Agreement, please find enclosed two copies of the Nitrate Contamination In vestigation Report, dated December 30, 2009 (the "Report"), prepared by INTERA, lnc. on behalf of and under th e direction of Denison. Also enclosed are two CDs each containing an electronic copy of the Report. I certify under penalty of law that the Report and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. If you should have any questions or require additional information, please contact the undersigned or David C. Frydenlund, Denison's Vice President, Regulatory Affairs and Counsel at 303389-4132. Yours very truly, DENISON MINES (USA) CORP. By: Harold R. Roberts, P.E. Executive Vice President, US Operations cc: Ron F. Hochstein David C. Frydenlund Steven D. Landau David E. Turk CERTIFICATION BY REGISTERED PROFESSIONAL ENGINEER I hereby certify that the Report has been prepared under my direction, that I have reviewed the Report, that I am familiar with the White Mesa Mill facilities, and attest that the Report has been prepared in accordance with good engineerin g practices. OENISONI)~~ MINES 2 Nitrate Contamination Investigation Report White Mesa Uranium Mill Site Blanding, Utah Prepared for: Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver, Colorado 80265 Prepared by: 6000 Uptown Blvd. NE, Suite 100 Albuquerque, New Mexico 87110 December 30, 2009 Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 i TABLE OF CONTENTS LIST OF FIGURES .......................................................................................................................ii LIST OF TABLES..........................................................................................................................ii LIST OF ATTACHMENTS ............................................................................................................ii LIST OF ACRONYMS AND ABBREVIATIONS........................................................................... iii 1.0 INTRODUCTION...............................................................................................................1 1.1 Documents Incorporated by Reference.................................................................2 2.0 CONTAMINATION INVESTIGATION ACTIVITIES...........................................................4 2.1 Possible Sources of the Pollution at the Facility....................................................4 2.1.1 Potential Tailings Cell Source.................................................................5 2.1.2 Potential Mill Circuit Source....................................................................6 2.1.3 Potential Fly Ash Pond Source...............................................................7 2.1.4 Potential Septic System Sources............................................................7 2.1.5 Potential Frog Pond Water Sources.......................................................7 2.1.6 Livestock Activity at Wildlife Ponds and Historic Pond ...........................9 2.1.7 Agricultural Sources................................................................................9 2.2 New Wells ...........................................................................................................10 2.3 Groundwater Sampling........................................................................................10 2.3.1 Sampling Design...................................................................................10 2.3.2 Sampling Quality Assurance/Quality Control........................................10 2.3.3 Laboratory QA/QC and Reporting ........................................................11 3.0 CHARACTERIZATION OF POLLUTION ........................................................................12 3.1 Characteristics of Contaminants in Groundwater and Contributing Surficial Contaminants ......................................................................................................12 3.1.1 Amount, Form, Concentration, and Toxicity of Contaminants ..............12 3.1.2 Environmental Fate and Transport.......................................................13 3.2 The Areal and Vertical Extent of the Contaminant Concentration, Distribution and Chemical Make-Up..............................................................................................14 3.2.1 New Wells.............................................................................................15 3.2.2 Hydrogeological Report of New Wells..................................................16 3.2.3 Groundwater Analysis of New Wells.....................................................17 3.3 Contaminant Migration ........................................................................................17 3.3.1 Velocities ..............................................................................................18 3.3.2 Multiple Sources...................................................................................19 3.3.3 Combination of Faster Travel Times and an Off-Site Source...............19 3.3.4 Expected Future Migration....................................................................21 4.0 CHARACTERIZATION OF THE FACILITY.....................................................................23 4.1 Contaminant Substance Mixtures Present and Media of Occurrence.................23 4.2 Hydrogeologic Conditions Underlying and, Upgradient and Downgradient of the Facility .................................................................................................................23 4.3 Surface Waters in the Area .................................................................................23 4.4 Climatologic and Meteorologic Conditions in the Area of the Facility..................24 4.5 Possible Sources of the Pollution at the Facility: Type, Location, and Description ............................................................................................................................24 4.6 Groundwater Withdrawals, Pumpage Rates, and Usage Within a 5-Mile Radius of the Mill.............................................................................................................26 5.0 DATA USED AND DATA GAPS .....................................................................................28 6.0 ENDANGERMENT ASSESSMENT................................................................................29 7.0 PROPOSED CORRECTIVE ACTION PLAN UAC R317-6-6.15 (D)...............................30 8.0 REFERENCES................................................................................................................31 Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 ii LIST OF FIGURES Figure 1 Mill Site Map Figure 2 New Nitrate Monitoring Well Locations Figure 3 Nitrate Concentration Map Figure 4 Chloride Concentration Map Figure 5 Chloroform Plume Map Figure 6 Possible Sources of Nitrate and Chloride in the Vicinity of the Mill Figure 7 Potential Nitrate and Chloride Sources at Mill Site Figure 8 Groundwater Elevation Map Figure 9 Nitrate and Chloride Plumes with Estimated Capture Zones LIST OF TABLES Table 1 Sampling Design Table 2 Sample Results LIST OF ATTACHMENTS Attachment 1 Request for Voluntary Plan and Schedule to Investigate and Remediate Nitrate Contamination at the White Mesa Mill Site, Near Blanding, dated September 30, 2008. Attachment 2 Source Review Report for Nitrate and Chloride in Groundwater at the White Mesa Mill (Tischler, 2009) Attachment 3 White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) State of Utah Groundwater Discharge Permit No. UGW370004. Revision 4.0, Denison Mines (USA) Corp. April 16, 2009. Attachment 4 Initial Nitrate Monitoring Report, dated December 2009 Attachment 5 Site Hydrogeology and Estimation of Groundwater Pore Velocities in the Perched Zone White Mesa Uranium Mill Site near Blanding, Utah (Hydro Geo Chem, 2009) Attachment 6 Calculation to Evaluate Potential Tailings Cell Source Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 iii LIST OF ACRONYMS AND ABBREVIATIONS Board Utah Water Quality Board CAP Corrective Action Plan CIR Contamination Investigation Report cms centimeters per second DUSA Denison Mines (USA) Corp. EPA U.S. Environmental Protection Agency Executive Secretary Co-Executive Secretary of the Utah Water Quality Board ft/yr foot/feet per year gpm gallons per minute GWDP Groundwater Discharge Permit No. UGW370004 GWQS Groundwater Quality Standard HGC Hydro Geo Chem, Inc. INTERA INTERA, Incorporated mg/L milligrams per liter Mill White Mesa Mill Site QA/QC quality assurance/ quality control QAP Quality Assurance Plan Request Request for Voluntary Plan and Schedule to Investigate and Remediate Nitrate Contamination at the White Mesa Mill RfD reference dose Site White Mesa Mill Site UAC Utah Administrative Code UDEQ Utah Department of Environmental Quality Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 1 1.0 INTRODUCTION Denison Mines (USA) Corp. (DUSA) received a Request for Voluntary Plan and Schedule to Investigate and Remediate Nitrate Contamination at the White Mesa Mill (the “Mill”) Site, near Blanding, Utah (the “Request”) (Attachment 1). The Request was dated September 30, 2008 and was received from the Co-Executive Secretary (the “Executive Secretary”) of the Utah Water Quality Board, of the Utah Department of Environmental Quality (UDEQ). In the Request, the Executive Secretary noted that groundwater nitrate levels have exceeded the State water quality standard of 10 milligrams per liter (mg/L) in certain monitoring wells at the Mill Site. Figure 1 is a regional map showing the location of the Mill Site. As a result of the Request, DUSA agreed to submit a plan of action and a schedule for Executive Secretary approval for completion of a Contamination Investigation Report (CIR) to determine the physical cause(s), location(s), transfer mechanism(s) and characteristics of all source(s) of the nitrate contamination in order to form a basis for and facilitate later submittal of a groundwater Corrective Action Plan (CAP) that meets the requirements of Utah Administrative Code (UAC) R317-6-6.15D, or to demonstrate conclusively that DUSA did not cause or contribute to the nitrate contamination in any manner and that, as a result, such a CAP is not necessary. DUSA retained INTERA, Incorporated (INTERA) to develop a plan and schedule for completing this CIR and, if necessary, a CAP. A Plan and Schedule for Nitrate Contamination Investigation Report and Groundwater Corrective Action Plan (The Plan) (INTERA, 2008) was submitted to the Executive Secretary on November 19, 2008. A Stipulated Consent Agreement (Agreement) between DUSA and the Utah Water Quality Board (Board) was entered into in January, 2009. Subsequently, in a letter dated December 1, 2009, UDEQ noting that elevated chloride concentrations exist, apparently coincident with elevated nitrate concentrations, recommended that DUSA also address and explain the elevated chloride concentrations in this Report. Therefore, this Report will serve as a CIR for both nitrate and chloride at the Mill Site. The purpose of this Report is to characterize nitrate and chloride contamination in groundwater at the Mill Site. The contamination investigation activities follow The Plan, as amended by the Agreement and the requirements found in UAC R317-6-6.15(D). As will be discussed in detail in Sections 2 and 3, the following conclusions are reached in this CIR: Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 2 1. The nitrate and chloride are extensive and appear to originally come from the same source. 2. That source is upgradient of the Mill property more than 1.2 miles from the Mill facilities, is not the result of Mill activities and was not caused or contributed to in any manner by Mill activities. As a result, DUSA has concluded that it should not be required to prepare a CAP for nitrate/chloride contamination that is from an off-site source. 1.1 Documents Incorporated by Reference The Mill has been the subject of numerous studies. According to UAC R317-6-6.15 (C), this CIR may incorporate by reference information already provided to the Executive Secretary. As described in more detail below, DUSA will summarize and incorporate by reference in this CIR information from a number of documents, which may include the following:  White Mesa Uranium Mill; Environmental Report in Support of License Renewal Application, February 28, 2007, prepared by DUSA (DUSA, 2007);  Environmental Report, White Mesa Uranium Project San Juan County, Utah, dated January 1978, prepared by Dames & Moore;  Final Environmental Statement for the Mill prepared by the Nuclear Regulatory Commission, 1979;  Summary of Work Completed, Data Results, Interpretations and Recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, prepared by T. Grant Hurst and D. Kip Solomon, Department of Geology and Geophysics, University of Utah, May 2008 (the “University of Utah Study”);  Revised Background Groundwater Quality Report; Existing Wells For Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, Prepared by INTERA, October 2007 (the “Background Report”);  Revised Addendum: Evaluation of Available Pre-Operational and Regional Background Data; Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, prepared by INTERA, November 16, 2007; Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 3  Revised Addendum: Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, prepared by INTERA, April 30, 2008;  Utah Division of Radiation Control, 2004, Statement of Basis for a Uranium Milling Facility South of Blanding, Utah, Owned and Operated by Denison Mines (USA) Corporation, Permit No. UGW37004 (Statement of Basis);  DUSA Quarterly Groundwater Reports;  DUSA Quarterly Chloroform Reports;  Site Hydrogeology and Estimation of Groundwater Pore Velocities in the Perched Zone, White Mesa Uranium Mill Site, Near Blanding, Utah, dated December 29, 2009, prepared by Hydro Geo Chem, Inc.;  Source Review Report for Nitrate and Chloride in Groundwater at the White Mesa Mill, dated December 30, 2009, prepared by Jo Ann Tischler;  Initial Nitrate Monitoring Report, dated December, 2009, prepared by DUSA; and  the Reclamation Plan, White Mesa Mill Blanding Utah, Radioactive Materials License No. UT1900479, Revision 4.0, November 2009 (the “Reclamation Plan, Rev. 4.0”). Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 4 2.0 CONTAMINATION INVESTIGATION ACTIVITIES All potential contributing surficial sources that could generate nitrate and chloride in the perched aquifer that have been identified to date, have been described in Sections 2, 3, 4 and 5 of the Source Review Report for Nitrate and Chloride in Groundwater at the White Mesa Mill dated December 30, 2009, prepared by Ms. Jo Ann Tischler (the Source Report), a copy of which is appended to this CIR as Attachment 2. Contamination investigation activities included the above referenced analysis of possible sources at the Facility, installation of new perched groundwater wells, sampling of groundwater in the new wells, and analyses of groundwater in all wells and wildlife ponds. Installation of 19 new monitoring wells (Figure 2) has allowed the nitrate and chloride plumes to be fully bounded at the Site (Figures 3 and 4). On Figure 3, nitrate iso- contours start at 5 mg/L because that value appears to separate the plume from background. However, as evident from Figure 3, the 10 mg/L contour that defines the groundwater compliance limit for nitrate at a number of wells at the Site as specified in the Groundwater Discharge Permit No. UGW370004 (GWDP) is completely closed and defined at the Site. Per discussions with UDEQ, the nitrate plume is considered to have been bounded when the concentrations of nitrate in monitoring wells upgradient, downgradient, and in both crossgradient directions are less than 10 mg/L. There is no groundwater standard for chloride but the iso-contours start at 100 mg/L because that value appears to separate the plume from background. A feature of the plume maps is that the nitrate (Figure 3) and chloride plumes (Figure 4) are co-located geographically. Almost all locations that have elevated nitrate concentrations also have elevated chloride concentrations, implying that the nitrate and chloride impacts to groundwater had the same source. However, the nitrate plume shows a lobe extending to the southeast coincident with the chloroform plume (Figure 5) but the chloride plume does not. This indicates that elevated nitrate was present in the chloroform plume but chloride was not. The chloride plume demonstrates that there are two distinct plumes; a nitrate-chloride plume and the chloroform plume with distinctly different sources. 2.1 Possible Sources of the Pollution at the Facility As discussed in detail in Section 3, based on new well installation and recent groundwater sampling, the source of nitrate and chloride contamination is off the DUSA Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 5 property to the northeast (see Figures 6 and 7). However, the Source Report, which is appended to this Report (Attachment 2), identified the following possible sources of nitrate and/or chloride in groundwater at the Site:  The septic leach fields at the site;  The municipal sewage plant discharge water used historically as Mill water makeup;  Livestock activities at the wildlife ponds;  Livestock activities at the Historic Pond;  Agricultural activities;  The former Fly Ash Pond;  Potential historic spills of ammonia-bearing and/or chloride-bearing process chemicals;  Potential breach in the Mill circuit floor drains or tailings transfer lines; and  A potential leak in the Mill’s tailings cells. As will be discussed in more detail below, the municipal sewage plant discharge water used historically as Mill water makeup is the best candidate for the source of both elevated nitrate and elevated chloride in groundwater. However the following sections will review potential sources and compare their potential for contributing nitrate and chloride to groundwater based on data collected during this study. 2.1.1 Potential Tailings Cell Source Elevated nitrate and chloride concentrations at TWN-3 are clearly a part of the plume. This monitoring well is more than 1,000 feet upgradient of the tailings cells. It is unlikely that tailings solutions could travel this distance horizontally in the vadose zone. Further the plume at TWN-3 is clearly spatially and chemically related to the plume at TWN-19 which is more than 7,200 feet upgradient of any tailings cell. Other suggested possibilities include a groundwater mound from the tailings cells that might cause elevated nitrate and chloride concentrations upgradient. A quick calculation for nitrate to evaluate this possibility (a calculation for chloride would be similar) suggests that on the order of eleven percent tailings solution (assuming the highest recently observed nitrate concentration in the tailings of 290 mg/L) would have to mix with unimpacted groundwater (assuming 1 mg/L) in order to account for the observed Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 6 mass of nitrate in groundwater, assuming an average nitrate concentration in the plume above the 20 mg/L isopleth of 30 mg/L. The size of the nitrate plume above 20 mg/L is approximately 40 acres, or 1,800,000 square feet in map area (Figure 3). Assuming 45 feet of saturation (Chloroform Investigation Report) and a porosity of 0.2, there are 16,200,000 cubic feet or 121,176,000 gallons of groundwater in that area. Eleven percent of that is 13,329,360 gallons (approximately 41 acre feet) which is a conservative estimate of the volume of tailings solution that would have to be mixed with groundwater to account for the mass of nitrate in the portion of the plume above 20 mg/L nitrate. That amount of seepage from the tailings cells would certainly generate a groundwater mound. Such a mound would have to be on the order of 5 feet on average over the entire 40 acres, but would likely be much higher than that at the centroid of the plume and would taper off toward the edges of the plume. However, no such mounding exists under the tailings cells. While groundwater mounding can be observed towards the eastern portion of the site, away from the tailings cells, it is clearly related to the wildlife ponds and not the tailings cells (See Figure 8). As a final point, if the concentration of nitrate in tailings documented in the Statement of Basis (24 mg/L) were used in the calculation, no amount of tailings solution would bring the plume concentration to 30 mg/L. Based on the results of the nitrate investigation, the discussion above, and recent studies by the University of Utah (Solomon and Hurst, 2008) indicating that the Mill’s tailings cells have not leaked, the tailings cells have been removed from the list of potential sources of nitrate and chloride at the Site. 2.1.2 Potential Mill Circuit Source The Mill circuit is located downgradient of elevated nitrate and chloride concentrations at TWN-3, and the same argument advanced for the tailings cells applies. The plume at TWN-3 is clearly spatially and chemically related to the plume at TWN-19 which is more than 6,900 feet upgradient of TWN-3. Additionally, there is no known history of leaks or spills of the magnitude required to supply the mass of nitrate currently observed in groundwater. Further, as noted in the Source Report, spills of these materials are too finite a phenomenon to account for an ongoing plume on their own. Therefore, a Mill circuit source has been removed from the list of potential sources of nitrate and chloride at the Site. Similar arguments rule out a Mill laboratory source from the list of potential sources of nitrate and chloride at the site. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 7 2.1.3 Potential Fly Ash Pond Source As with the potential tailings cell and Mill circuit the former Fly Ash Pond is also considerably downgradient of demonstrated elevated levels of nitrate and chloride in groundwater in samples from TWN-3 and TWN-19. The contents of the Fly Ash Pond were removed and the pond was covered and closed in 1989. The Fly Ash Pond was called a pond because it was located at a low point that collected storm run-off water. However, standing water in the pond was pumped regularly to the tailings cells thereby reducing the pond’s ability to drive any recharge to groundwater. Further, a component of fly ash is lime (CaO). This chemical reacts with water (H2O) to form calcium hydroxide [Ca(OH)2]. This property of fly ash leads to the formation of a kind of natural cement that would tend to form a barrier to infiltration (Scott and Thomas, 2007), favoring evaporation of pond solutions rather than groundwater recharge. Therefore, a Fly Ash Pond source, while possible, is less likely than potential sources upgradient of TW4-25. This potential source has been removed from the list of potential sources of nitrate and chloride at the Site. 2.1.4 Potential Septic System Sources As above, this potential source cannot explain the nitrate and chloride plume far to the north of the Mill Site. However, a number of septic leach fields exist at the Mill Site, and septic systems have caused regional nitrate contamination in many areas (McQuillan, 2004). Figure 7 shows five separate leach fields at the Mill Site along with associated piping. Two of the Site leach fields, the Former Office Leach Field and the Scale House Leach Field, apparently gave rise to the chloroform plume that is currently under remediation. It is worth noting that the nitrate and chloride plume is chemically distinct from the chloroform plume in that the chloroform plume has distinctly lower levels of chloride. Therefore, this potential source has been removed from the list of potential sources of nitrate and chloride at the Site. Any nitrate in the chloroform plume that has resulted from these leach fields will be remediated under the chloroform investigation. 2.1.5 Potential Frog Pond Water Sources Until the early 1990s, process water for the Mill was limited to the deep water supply wells on Site, and the Mill sought additional sources of process water. Recapture Reservoir was not constructed until 1988-1989, and the pipeline from Recapture Reservoir to the Mill was not completed until around 1991-1992. From the mid 1980s until the Recapture Reservoir water was first piped to the Mill in 1991-1992, the Frog Pond served as an additional water source for Mill operations. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 8 This source is considered to be the most likely explanation for the distribution of the nitrate and chloride plume. The waste water treatment facility described in the Source Report is located several miles upgradient of the Mill Site (Figure 6) but discussions with Mill staff indicate that effluent from that facility was allowed to flow to a pond (Frog Pond) near the Mill boundary where it was subsequently piped to the northern-most Wildlife Pond at the Site and to another holding pond on Site for Mill makeup water (Lawzy Lake, see Figures 6 and 7). The Mill staff reports that this water had a bad odor and may have had a high sludge content. Nitrate and chloride are commonly associated with wastewater treatment effluent (McQuillan, 2004). At the Frog Pond an electric pump carried the water for use at the Mill via underground pipe to ponds at the rate of about 200 gallons per minute (gpm). Just north of the Mill’s restricted area, the water could be diverted to either the northern most wildlife pond or to a secondary pond, referred to as “Lawzy Lake”. At the wildlife pond a diesel pump was activated when water was needed in the Mill. Water was then pumped from the northern wildlife pond to the Mill’s pre-leach tanks, which acted as water storage for the Mill. The water in Lawzy Lake was gravity fed to a sump (the “Lawzy Sump”) within the restricted area. Once the water reached the sump, it was pumped to the pre-leach tanks for water storage (Figure 7). Neither the wildlife pond nor Lawzy Lake is lined. This potential source term was a high priority during this contamination investigation for several reasons. The period of Mill use of water from the waste water treatment plant was from the mid 1980s to about 1991 or 1992 when it was replaced with water from Recapture Reservoir. As documented in the Background Report (INTERA, 2007), groundwater levels at the Site have been influenced by the Wildlife Ponds so we know that the head in those ponds has been sufficient to drive infiltration to the water table. The “slug” like character of the nitrate and chloride plume is consistent with a source that has been removed. The distances from the northern-most Wildlife Pond and Lawzy Lake to the centroid of the nitrate plume are approximately 2,300 feet and 2,100 feet, respectively. Assuming 26 years since nitrate/chloride laden water entered the system, groundwater would have had to travel at an average velocity of 88 feet per year (ft/yr) from the northern-most Wildlife Pond and 81 ft/yr from Lawzy Lake to account for the current distribution of nitrate concentrations. The velocity of 88 ft/yr from the northern- most Wildlife Pond is a relatively high velocity compared to other values that have been calculated for the Site, but possible given the high gradient in this limited portion of the Site due to mounding at the wildlife ponds. Further, the eastern portion of the Site is Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 9 known to have higher permeability than the western portion (see the Preliminary Contamination Investigation Report [HGC, 2007]). The Lawzy Sump is even closer to the plume. The Frog Pond was constructed prior to Mill operations, by creation of a dike to capture surface water, by local ranchers in order to capture available surface waters. The Mill was not involved in any way in the construction of the Frog Pond. For the above reasons Lawzy Lake, the Lawzy Sump, and the northern-most Wildlife Pond are likely infiltration points for Frog Pond water. These potential infiltration points have been addressed by installation of two monitoring wells. One (TWN-3) was installed half way along a line between the north end of the Mill building and Lawzy Lake. Analytical results of samples of groundwater from well TWN-3 (29 mg/L nitrate and 106 mg/L chloride) indicate that this well may be near a potential source. The other monitoring well (TWN-4) was installed on a line approximately half way between the north end of the Mill building and the northern-most Wildlife Pond. Groundwater samples from TWN-4 contained 0.4 mg/L nitrate and 11 mg/L chloride. Another possible explanation for the distribution of nitrate and chloride using the Frog Pond water source is that the pipeline from the Frog Pond to the northern wildlife pond and Lawzy Lake may have leaked. However, it seems likely that leaks would have been noticed, particularly leaks of enough volume to travel to groundwater and add the observed mass of nitrate and chloride. 2.1.6 Livestock Activity at Wildlife Ponds and Historic Pond The northern-most Wildlife Pond was a stock watering pond for years prior to construction of the Mill. The Historic Pond, which no longer exists, but was located where the Mill’s sulfuric acid tank is currently located, (Figure 7) pre-existed construction of the Mill by several decades, tracing back possibly to the 1920s. Livestock can generate nitrate in and around stock watering ponds and salt licks for livestock can generate chloride, and the water head in the ponds could potentially drive those nitrates into the groundwater. However these mechanisms alone would be unlikely to generate enough mass to account for the current mass of nitrate and chloride observed in groundwater. 2.1.7 Agricultural Sources The Mill is located south of Blanding, Utah in a rural agricultural region of the state. Land uses proximal to the Mill include farming, ranching, cattle grazing and feed and Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 10 grain silos. Those activities could generate both nitrate and chloride to groundwater. While it is possible that agricultural practices on neighboring properties that occurred at some time in the past (but which no longer occur) could have contributed a slug of both nitrate and chloride contamination to groundwater, this is difficult to quantify and appears much less likely than the Frog Pond source discussed above. 2.2 New Wells TWN-1 through TWN-19, were drilled, completed, and developed in the same manner as the chloroform investigation wells as specified under UAC R 317-6-6.3 (I) (6) and the Mill’s State of Utah Division of Water Quality GWDP. The locations of the new wells are shown in Figure 2. 2.3 Groundwater Sampling Groundwater in all groundwater wells on Site, including groundwater in the 19 new TWN wells was collected and analyzed for nitrate and chloride as part of the contamination investigation. The rationale behind the groundwater sampling plan is described below. 2.3.1 Sampling Design New sampling locations have been determined based on concentrations of nitrate and chloride from previous analytical results, including quarterly groundwater and chloroform reports and an analysis of potential sources (see Section 2.1 above). Groundwater samples were collected according to Section 6 “Ground Water Sampling and Measurement of Field Parameters” of the White Mesa Uranium Mill Groundwater Monitoring Quality Assurance Plan (the QAP) (DUSA, 2009, Attachment 3). Sample locations, parameters, and rationale are listed in Table 1 of this Report. Table 1 of the QAP presents the analytical method, reporting limit, maximum holding time, and sample preservation requirements (including temperature) for nitrate and chloride samples. 2.3.2 Sampling Quality Assurance/Quality Control Sample collection, handling, identification, and shipping were performed according to the QAP. See the Initial Nitrate Monitoring Report included as Attachment 4, for a QA/QC analysis and for identification of any deviations from the requirements of the QAP. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 11 2.3.3 Laboratory QA/QC and Reporting To ensure quality of laboratory analysis, the Mill’s contract analytical laboratory (Energy Laboratories, Inc.) was required to analyze quality assurance/quality control (QA/QC) samples as specified by the analytical method. This QA/QC was performed in the same manner as the quarterly groundwater and chloroform analysis, and according to the QAP. See the Initial Nitrate Monitoring Report included as Attachment 4. Laboratory analytical reports were submitted to DUSA and INTERA in the form of an Electronic Data Deliverable, which was verified by INTERA. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 12 3.0 CHARACTERIZATION OF POLLUTION The following sections describe the characterization of pollution as required by R317-6- 6.15 D 1. 3.1 Characteristics of Contaminants in Groundwater and Contributing Surficial Contaminants The contaminants of concern have been identified as nitrate and chloride in the perched aquifer at the Mill Site. Characteristics of nitrate and chloride in groundwater are described in the following sections. 3.1.1 Amount, Form, Concentration, and Toxicity of Contaminants Based on Figure 3 and Figure 4, elevated concentrations of nitrate and chloride appear to be co-located across the Site, suggesting derivation from the same source. 3.1.1.1 Nitrate Groundwater from Site monitoring wells has been sampled and nitrate has been measured as nitrate+nitrite and reported as nitrogen. Nitrate (NO3-) and nitrite (NO2-) are naturally occurring inorganic ions that are part of the nitrogen cycle. Because nitrite is easily oxidized to nitrate, nitrate is the compound predominantly found in groundwater. Nitrates themselves are relatively nontoxic. However, when swallowed, they are converted to nitrites that can react with hemoglobin in the blood, oxidizing its divalent iron to the trivalent form and creating methemoglobin. This methemoglobin cannot bind oxygen, which decreases the capacity of the blood to transport oxygen, so less oxygen is transported from the lungs to the body tissues, thus causing a condition known as methemoglobinemia (Argonne National Laboratory, 2005). The U.S. Environmental Protection Agency (EPA) has developed toxicity values to estimate the risk of non-cancer health effects from ingesting nitrates and nitrites. The toxicity value used to estimate a non-cancer effect following ingestion is called a reference dose (RfD). An RfD is an estimate of the highest dose that can be taken in every day without causing an adverse effect. The RfD for nitrate was developed considering the concentration at which methemoglobinemia was indicated at levels above 10% for 0- to 3-month-old infants. This was based on a daily intake of formula made with water containing 10 mg/L of nitrate as nitrogen. This reflects the amount of nitrogen within a nitrate molecule, where 1 mg nitrate as nitrogen = 4.4 mg nitrate as measured in the water. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 13 Most cases of infant methemoglobinemia are associated with exposure to formula prepared with drinking water at nitrate-nitrogen levels at least two times higher, or exceeding 20 mg/L nitrate-nitrogen. For nitrite, the RfD is based on a 10-kilogram (22- pound) child drinking 1 liter, or about 1 quart, of water every day. The RfD represents a “safe daily dose” and so is compared to the amount an individual is estimated to take in every day, as a ratio (Argonne National Laboratory, 2005). Thus the EPA Standard for nitrate in groundwater is 10 mg/L as nitrogen. With respect to the amount and concentration of nitrate in the plume, the highest nitrate level that has been detected at the Site is 45.3 mg/L in monitor well TW4-24 in a sample collected on June 25, 2008. Nitrate levels in that well have declined and the most recently measured value in a sample of groundwater, taken on September 15, 2009, is 30.7 mg/L. Typical concentrations in the area of the nitrate plume range from 5 mg/L to 25 mg/L. The areal extent of the plume is depicted on Figure 3. The vertical extent is the perched groundwater zone within the area of the plume. 3.1.1.2 Chloride Chloride is considered to be a major element that occurs in almost all groundwater (Hem, 1992) and occurs as a chloride ion (Cl-). There is no human health standard for chloride in groundwater. The EPA Standard for chloride in drinking water (250 mg/L) is an aesthetic standard related to the salty taste of water with chloride concentrations in excess of that amount. The recommended EPA criterion for the propagation of wildlife is 1,500 mg/L. With respect to the amount and concentration of chloride in the plume, the highest chloride level that has been detected at the Site is 1,180 mg/L, again in monitor well TW4-24 in a sample collected on September 10, 2008. Chloride levels in that well have declined and the most recently measured value in a sample of groundwater, taken on September 15, 2009, is 618 mg/L. Typical concentrations in the area of the nitrate plume range from 100 mg/L to 300 mg/L. The areal extent of the plume is depicted on Figure 4. The vertical extent is the perched groundwater zone within the area of the plume. 3.1.2 Environmental Fate and Transport Nitrate and chloride behave in a similar way in many groundwater systems. With some exceptions described below, both are non-reactive and conservative constituents whose concentrations are diminished in groundwater only by diffusion and dispersion with travel distance. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 14 3.1.2.1 Nitrate Since it is very soluble and does not bind to soils, nitrate has a high potential to migrate to ground water. Because it does not evaporate, nitrate/nitrite is likely to remain in water until consumed by plants or other organisms (http://www.epa.gov/safewater/ contaminants/dw_contamfs/nitrates.htm). The retardation factor (R) is one of the coefficients that describe the migration abilities of particular components in groundwater. It shows how many times the migration of the substance subjected to adsorption is slower than the actual speed of water flow in pores. The average intensity of nitrate adsorption is described as low, and the retardation factor ranges between 1 and 2 (Deutch, 1997). However, if nitrate is discharged into anoxic ground water, or if oxic ground water containing nitrate either migrates into anoxic conditions or is made anoxic by anthropogenic discharges, de-nitrification can occur, converting nitrate to nitrogen gas (N2) (McQuillan, 2004). 3.1.2.2 Chloride Chloride ions do not significantly enter into oxidation or reduction reactions and they form no important solute complexes with other ions unless the chloride concentration is extremely high. Chloride ions do not form salts of low solubility, are not significantly adsorbed on mineral surfaces, and play few vital biochemical roles. Thus, the attenuation of chloride ions in the hydrologic cycle is largely through the physical processes of hydrodynamic dispersion and diffusion (Hem, 1992). 3.2 The Areal and Vertical Extent of the Contaminant Concentration, Distribution and Chemical Make-Up Groundwater at the Mill has been monitored for the past 30 years; therefore, certain characteristics of nitrate and chloride contamination have already been determined. Prior to the contamination investigation activities, the nitrate and chloride plumes were well constrained in the downgradient direction. They had clear boundaries to the west and to the south. On the east side, apparently nitrate partially comingles with nitrate associated with the chloroform plume. Groundwater extraction for remediation of chloroform may have caused additional comingling in this area obscuring any relationship that may have existed between the two plumes. New wells have defined an elongated plume extending over a mile to the northeast from the northern-most wildlife pond to DUSA’s property boundary (Figures 3 and 4). Sampling has confirmed the association of nitrate with chloride in this plume. The plume exists in two distinct parts divided by a zone of low concentrations in the vicinity of the northern-most wildlife pond. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 15 3.2.1 New Wells The new monitoring wells were installed according to UAC R317-6-6.3(I)(6). Initially, DUSA installed four new monitoring wells (TWN-1 through TWN-4) in late January, 2009 as described in the Plan (INTERA, 2008). Sampling of those wells revealed that elevated nitrate and chloride concentrations exist north of the Mill Site proper and north of the ore pads (in TWN-3). Based on this information, an additional six monitoring wells were installed in July 2009 (TWN-5 through TWN-10). Sampling of those wells revealed that elevated nitrate and chloride concentrations exist still further north at TWN-9. Therefore, an additional nine monitoring wells were installed (TWN-11 through TWN-19) in late September and early October, 2009 to further bound the plume. Figures 3 and 4 present nitrate and chloride data, respectively, from November 2009 and contoured by the krieging routine in SURFER 8. On Figure 3, nitrate iso-contours start at 5 mg/L because that value appears to separate the plume from background. However, as evident from Figure 3, the 10 mg/L contour that defines the groundwater compliance limit for nitrate at a number of wells at the Site as specified in the GWDP is completely closed and defined at the Site. Above the 10 mg/L contour, nitrate contours increase in 10 mg/L increments. There is no groundwater standard for chloride but the iso-contours start at 100 mg/L because that value appears to separate the plume from background and thereafter chloride contours increase in 100 mg/L increments. These figures demonstrate that a plume exists in groundwater that is clearly unrelated to the tailings cells and other Mill facilities and is apparently moving southwest with groundwater flow from a source northeast of the Mill Site. This plume is distinctive in its association of nitrate with chloride and, as described in Section 2, can be distinguished from the chloroform plume based on its distinctive chemistry. The most upgradient location within the nitrate-chloride plume is the new monitoring well TWN-19, approximately 1.4 miles upgradient of the tailings cells and at the north east boundary of the Mill property, where nitrate concentrations are 7.4 mg/L and chloride concentrations are 125 mg/L. Currently, the centroid of the plume is downgradient of the Mill office building, at TW4-24 where current nitrate concentrations in groundwater are near 30 mg/L and chloride concentrations are near 600 mg/L. The current plume configuration appears to approximate “plug-flow” behavior, where a “slug” of contamination moves as a mass with groundwater. If so, the distribution of nitrate and chloride concentrations suggest a point source of nitrate contamination Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 16 upgradient of the Mill property that contributed to groundwater for a finite period of time and has subsequently been removed. 3.2.2 Hydrogeological Report of New Wells Hydraulic testing of new monitoring wells TWN-1 through TWN-19 was conducted to estimate perched zone hydraulic properties in the vicinity of each new well. The complete Perched Nitrate Monitoring Well Hydraulic Tests report (HGC, 2009) is included in this Report as Attachment 5. Slug test data were collected and analyzed using AqtesolvTM software. Estimates of hydraulic conductivity range from 3.6 x 10 -7 centimeters per second (cm/s) at TWN-7 to 0.0142 cm/s at TWN-16. Except for the hydraulic conductivity estimate at TWN-16, values are within the range previously reported for the Site. Pore zone velocities along hypothetical pathways through elevated nitrate areas have been calculated as approximately 0.55 ft/yr to 7 ft/yr in the northeast area plume. Pore velocity for the Mill area plume is 23 ft/yr. These values are lower than might be expected. However, coupling the fact that the highest conductivity ever measured at the Site is located in this area and the relatively small number of measurement locations (19 over an approximately one square mile area) it is unlikely that these are accurate estimates of actual pore velocities. Note that wells installed at a higher density in a smaller area for the chloroform investigation (Hydro Geo Chem, 2007) confirmed higher hydraulic conductivities in that area. Another line of evidence that hydraulic conductivities in the area of the nitrate and chloride plume might be higher than the sample would indicate lies in the shape of the water table surface (Figure 8). Note that southwest of the Mill Facility itself, groundwater flow directions change to more westerly and the gradient steepens. This is a classic example of flow crossing a boundary from a zone of higher permeability to a zone of lower permeability. The gradient steepens to accommodate the lower permeability and flow is refracted into a new direction. This is known as the tangent refraction law. Analytically, a refraction of flow lines occur such that the permeability ratio of the two zones equals the ratios of the tangents of the angles the flow lines make with the normal to the boundary (Domenico and Schwartz, 1990). The nitrate and chloride plume occurs in the area of high conductivity where the water table is behaving in a similar way to the area of known higher conductivities associated with the chloroform plume (Figure 5). Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 17 3.2.3 Groundwater Analysis of New Wells The Sampling Plan submitted to the Executive Secretary as part of The Plan (INTERA, 2008) sets out a plan to define the north and northeast boundary of the nitrate plume. The following activities have been completed according to the Plan and the following deliverables have been prepared and will be submitted to the Executive Secretary along side this Report:  Drilled, installed, and completed 19 new monitoring wells (TWN-1 through TWN- 19);  A recovery test and aquifer testing to determine hydraulic conductivity was performed on each of the new monitoring wells;  The 19 new monitoring wells were developed and sampled for nitrate and chloride;  A hydrogeological report (“Site Hydrogeology and Estimation of Groundwater Pore Velocities in the Perched Zone, White Mesa Uranium Mill Site Near Blanding, Utah” [HGC, 2009]) including the results from the recovery tests and aquifer testing on the new monitoring wells was prepared (Attachment 5); and  A QA/QC analysis was performed on all nitrate and chloride sample results for the 19 new wells, as contained in the Initial Nitrate Report (Attachment 4). The results of groundwater sampling for nitrate and chloride are presented in Table 2. 3.3 Contaminant Migration As stated above, calculated pore zone velocities along hypothetical pathways are approximately 0.55 ft/yr to 7 ft/yr in the northeast area plume. Calculated pore velocity for the Mill area plume is 23 ft/yr. These travel times are not long enough to have transported nitrate and chloride from the upgradient to the downgradient portions of the two areas within a reasonable time frame. Assuming the 23 ft/year pore velocity and a source just upgradient of the DUSA property boundary in the vicinity of TWN-19, it would take over 300 years for nitrate and chloride to arrive at monitor well TW4-24. Yet the plume at TW4-24 is clearly spatially and chemically related to the plume at TW4-19. Spatially, it can be traced on a trajectory from TWN-19 to MW-19 where it is separated from the Mill area plume by only a few hundred feet. Chemically, the areas of elevated nitrate correspond to the areas of elevated chloride suggesting a common source for the two constituents and both plume areas. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 18 Possible explanations for the above observations include: 1) actual pore velocities are higher than calculated pore velocities, 2) each nitrate area has resulted from multiple localized sources that have the same water type, or 3) some combination of the above. The following discussions will examine each of these possibilities in detail. 3.3.1 Velocities Pore velocities are calculated by multiplying the measured hydraulic conductivity times the hydraulic gradient and dividing the result by the effective porosity of the aquifer matrix. The measured hydraulic conductivities are the average of conductivities in the various sedimentary facies over the entire saturated thickness at the well where testing is done. This means that if sandstone and claystone are both within the saturated thickness at a well, the resulting measured hydraulic conductivity is an average of the conductivity of both aquifer matrix types. However, the bulk of groundwater flow will be in the sandstone that could result in an underestimate of hydraulic conductivity. Fluvial environments such as those represented by the Burro Canyon Formation comprise lens-like interfingering of the following deposit types (sedimentary facies):  Channel floor deposits comprising coarse sand or gravel;  Point bar deposits of fine-grained sand; and  Flood plain deposits comprising silt and mud. As sediment deposition occurs over time, these deposit types are distributed back and forth across the larger stream channel, producing the characteristic discontinuous lens-like nature of a fluvial geologic unit. In general, groundwater moves relatively quickly through the coarse channel sand and gravel but much more slowly through silt and clay flood plain deposits. Hydraulic heads can be maintained within the unit but the bulk of groundwater flow will be restricted to the gravel and sand facies. In general, measured hydraulic conductivities are higher to the north and east of the Mill tailings impoundments and lower to the south and west. The plume is in the north and east where some of the highest conductivities have been measured, so it may be appropriate to assume an increased hydraulic conductivity and a corresponding increased pore velocity. However, given the distance of 1.4 miles from TWN-19 to TW4- 24, it would take 60 years for contamination to make the trip assuming a pore velocity of 120 ft/yr. This value is almost five times higher than any calculated and not consistent with Site observations, for example at MW-30 downgradient of the highest plume Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 19 concentrations where chloride concentrations of 128 mg/L in 2005 have declined to 113 mg/L in February 2009. 3.3.2 Multiple Sources Nitrate and chloride in monitor well TWN-19 clearly have their source off of DUSA’s property to the north indicating that the ultimate source of contamination lies off of the DUSA property. Potential sources to the north include extensive agricultural irrigation just to the north of the property boundary that is plainly visible on aerial photographs (Figure 6) and the Frog Pond to the northeast. Nitrate contamination from the use of fertilizers during agricultural irrigation is well documented (Hem, 1992; McQuillan, 2005) and Hem cites an example in Arizona where 83 mg/L nitrate in groundwater was accompanied by 205 mg/L chloride, which is in the general range observed in the plume at White Mesa. Furthermore, water table contours (Figure 8) show what may be the toe of a groundwater mound located directly north of TWN-12 where mounding from irrigation might be expected. However, nitrate and chloride contamination appears to be coming from the east of TWN-12, suggesting the Frog Pond as a potential source. The presence of associated nitrate and chloride in septic and wastewater treatment systems is well documented (McQuillan, 2005). Currently, the Frog Pond does not contain elevated levels of nitrate and chloride. However, anecdotal evidence suggests that water in the pond has exhibited a septic/sewage odor in the past (which could have been mistaken for a marshy smell). Furthermore, there is a wastewater treatment facility located 1.2 miles north of the Frog pond. Effluent from the water treatment plant overflows into an arroyo that leads to Corral Canyon, just east of the Mill Site. This overflow was dammed by local ranchers prior to construction of the Mill to form the Frog Pond. DUSA has no information on current or past operating practices at the treatment facility. If either agricultural irrigation or the Frog Pond is the ultimate source of the nitrate and chloride plume, the dilemma of the long travel times required to move the plume to its current location remains to be explained. 3.3.3 Combination of Faster Travel Times and an Off-Site Source A plausible explanation that would account for the observed spatial and chemical relationships that characterize the plume relies on water from the Frog Pond transported to secondary storage at the Mill Site. Until the early 1990s, process water for the Mill Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 20 was limited to the deep water supply wells on Site, and the Mill sought additional sources of process water. Recapture Reservoir was not constructed until 1988-1989, and the pipeline from Recapture Reservoir to the Mill was not completed until around 1991-1992. From the mid 1980s until the Recapture Reservoir water was first piped to the Mill in 1991-1992, the Frog Pond served as an additional water source for Mill operations. The timing of these events suggests the following scenario: The unlined Frog Pond contained nitrate and chloride, which entered the groundwater and began migrating to the southwest. Meanwhile, DUSA pumped nitrate and chloride laden Frog Pond water to the northern-most wildlife pond and Lawzy Lake during the period from the early 1980’s to the early 1990’s where it began to seep into groundwater aided by the artificial head maintained on those ponds. The artificial head created a groundwater mound (notably still present under the wildlife ponds) and began driving elevated concentrations of nitrate and chloride west from the wildlife pond and south from Lawzy Lake, but also northeast toward TWN-9 due to circular gradients away from the mound. This nitrate and chloride laden water could also have reached the perched zone from the Lawzy Sump. When Recapture Reservoir water replaced the Frog Pond in the early 1990’s, Lawzy Lake was abandoned and the wildlife ponds were refilled with clean Recapture Reservoir water. The groundwater mound beneath Lawzy Lake dissipated and contamination from that infiltration point continued to migrate south, meanwhile the clean groundwater mound beneath the wildlife ponds continued to push already contaminated groundwater to the north where it impinged upon and joined with the plume traveling southwest from the Frog Pond. The wildlife pond’s groundwater mound is also still pushing contamination to the west and the slug that is now centered on TW4-24 is moving southwest away from the stagnant zone in groundwater that results from the mound upgradient of TWN-12 impinging on the wildlife mound. Hydro Geo Chem concludes (HGC, 2009) that the presence of higher permeability horizons within the nitrate/chloride plume (by analogy with the area near MW-4 in the chloroform plume) would allow greater spreading of perched zone nitrate/chloride within the applicable time frames. Hydro Geo Chem notes that the high hydraulic conductivity estimated at TWN-16 indicates the possible existence of such a horizon, although such a horizon does not appear to be penetrated by other TWN-series wells. However, Hydro Geo Chem notes that additional data might reveal the presence of a zone Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 21 analogous to the chloroform plume near MW-4 that may have transported nitrate and chloride over longer distances. This scenario would explain the co-located nitrate and chloride in both the upper and lower plumes. INTERA considers this to be the best explanation for the nitrate and chloride plume that has been observed on and up-gradient of the Mill site. 3.3.4 Expected Future Migration The nitrate and chloride are already being removed by pumping from the chloroform remediation. The extent of future migration of the nitrate and chloride will depend upon factors that include: 1) the rate of future mass removal by pumping, 2) perched zone hydraulic gradients, 3) perched zone permeabilities downgradient of the nitrate and chloride plume, and 4) natural attenuation processes including denitrification of nitrate and hydrodynamic dispersion of both nitrate and chloride. Pumping of MW-4, MW-26 (TW4-15), TW4-19, and TW4-20 for chloroform remediation, directly removes nitrate and chloride mass from the perched zone, and reduces the magnitude of the hydraulic gradients in the downgradient portions of the plume. As a result of this pumping, nitrate and chloride concentrations are reduced within the plume and the rate of downgradient migration is slowed. Figure 9 is a map showing the nitrate/chloride plume boundary superimposed over the estimated combined chloroform capture zones of MW-26 (TW4-15), TW4-19, and TW4- 20, and the estimated capture zone for MW-4 (from HGC, 2009). A portion of the southern half of the plume is currently outside the estimated capture zone. Although the extent of the capture zone is expected to increase over time, including expansion to the south, it is unlikely that complete hydraulic capture of the plume is achievable with the current pumping scheme. However, pumping in the southern (downgradient) extremity of the plume is impractical due to low permeability and low saturated thickness (HGC, 2005), as discussed below. The estimated range of perched zone permeabilities over much of the area of the nitrate and chloride plume is one to two orders of magnitude greater than estimates for areas downgradient of the nitrate and chloride plume and the tailings cells as discussed above. This reduction in permeability to the south and southwest is interpreted as a "pinching out" of a coarser-grained, higher permeability zone identified during installation of many of the temporary wells (HGC, 2005). The pinching out of this zone is important in limiting the rate of downgradient migration of nitrate and chloride, in Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 22 stabilizing the plume boundaries, and in allowing natural attenuation to be more effective in limiting plume migration. The combination of relatively high permeability and relatively large saturated thickness in the upgradient portions of the plume that make the productivity of the perched zone high and allow relatively high nitrate and chloride mass removal rates via interim pumping, is absent at downgradient wells such as TW4-4 and TW4-6. The combination of relatively low permeability and small saturated thickness near these downgradient wells makes pumping at these wells impractical. Because low permeability conditions to the south and southwest, and flattening hydraulic gradients resulting from upgradient pumping will reduce rates of downgradient migration, natural attenuation will likely be effective in treating that portion of the plume that will remain outside hydraulic capture (Attachment 2). Natural attenuation processes that will reduce concentrations are primarily limited to denitrification and hydrodynamic dispersion that relies on mixing with recharge and waters outside the plume lowering concentrations with distance. As a result of ongoing nitrate and chloride mass removal by pumping, and natural attenuation processes, the plume at present appears to be relatively stable. However it will be necessary to collect additional data to assess stability over time. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 23 4.0 CHARACTERIZATION OF THE FACILITY As required by UAC R317-6-6.15 D 1. b., the characterization of the facility includes a description of the following items. 4.1 Contaminant Substance Mixtures Present and Media of Occurrence The contamination has been identified as a nitrate and chloride plume in the perched aquifer at the Mill Site. The Source Report has analyzed potential contaminant substance mixtures at the Mill Site and surrounding properties, identified to date, that could have generated nitrate and/or chloride in the perched aquifer. The Source Report summarizes nitrate and chloride compounds or sources that are present at the Site, the uses of the compound, if the compound can generate nitrate and chloride, and if there are off-Site sources. 4.2 Hydrogeologic Conditions Underlying and, Upgradient and Downgradient of the Facility Hydraulic testing of new monitoring wells TWN-1 through TWN-19 was conducted to estimate perched zone hydraulic properties in the vicinity of each new well. This information is detailed in an updated Site Hydrogeology and Estimation of Groundwater Pore Velocities in the Perched Zone, White Mesa Uranium Mill Site near Blanding, Utah (HGC, 2009) included in this Report as Attachment 5. Slug test data were collected and analyzed using AqtesolvTM software. Estimates of hydraulic conductivity range from 3.6 x 10 -7 cm/s at TWN-7 to 0.0142 cm/s at TWN-16. Except for the hydraulic conductivity estimate at TWN-16, values are within the range previously reported for the Site. Pore zone velocities along hypothetical pathways through elevated nitrate/chloride areas have been calculated as approximately 0.55 ft/yr to 7 ft/yr in the northeast area plume. Pore velocity for the Mill area plume is 23 ft/year. 4.3 Surface Waters in the Area The Mill is located on White Mesa, a gently sloping (1 percent SSW) plateau that is physically defined by the adjacent drainages which have cut deeply into regional sandstone formations. There is a small drainage area of approximately 62 acres (25 ha) above the Site that could yield surface runoff to the Site. Runoff from the mesa discharges into an unnamed branch of Cottonwood Wash. Surface runoff from 624 acres of the Mill Site drains westward and is collected by Westwater Creek. Runoff from another 384 acres drains east into Corral Creek, while the remaining southern portions Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 24 of the Site drain indirectly into Cottonwood Wash. Total runoff from the mesa is estimated to be less than 0.5 inch annually (Dames & Moore, 1978). With the exception of the wildlife ponds, which were made or maintained by DUSA to divert birds and other animals from the tailings cells, there are no perennial surface waters on or in the vicinity of the Mill Site. This is due to the gentle slope of the mesa on which the Site is located. Sampling of these ephemeral surface waters in the vicinity is possible only during major precipitation events (DUSA, 2007). See Section 1.4 of the Reclamation Plan, Rev. 4.0 for further details on surface waters in the area of the Mill. 4.4 Climatologic and Meteorologic Conditions in the Area of the Facility The climate of southeastern Utah is classified as dry to arid continental. Climate in the vicinity of the Mill can be considered semi-arid with average annual precipitation of approximately 13.32 inches. The area receives two separate rainfall seasons: one from August to October and the other from December to March. The mean annual relative humidity is about 44 percent and is normally highest in January and lowest in July. The weather in Blanding is typified by warm summers and cold winters and the mean annual temperature is about 50.3 degrees Fahrenheit. The predominant wind directions during 2008 were north-northeasterly. Northerly winds are drainage winds occurring during the nighttime. The southerly winds are upslope winds occurring during daytime hours. The annual mean wind speed was 3.5 m/s (McVehil-Monnett Associates, Inc., 2009). See Section 1.1 of the Reclamation Plan, Rev. 4.0 for further details on the climatologic and meteorologic conditions in the area of the Mill. 4.5 Possible Sources of the Pollution at the Facility: Type, Location, and Description As discussed in Section 3, based on new well installation, the source of nitrate and chloride contamination is believed to be off the DUSA property to the northeast. At this point the municipal sewage plant discharge water used historically as Mill water makeup appears to be the best candidate for the source of elevated nitrate and chloride in groundwater. The waste water treatment facility described in the Source Report is located several miles upgradient of the Mill Site but discussions with Mill staff indicate that effluent from Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 25 that facility was allowed to flow to a pond (Frog Pond) near the Mill boundary where it was subsequently piped to the northern-most Wildlife Pond at the Site and to another holding pond on Site for Mill makeup water (Lawzy Lake, see Figures 6 and 7). The Mill staff reports that this water had a bad odor and may have had a high sludge content. Nitrate and chloride are commonly associated with wastewater treatment effluent (McQuillan, 2004). This potential source term was a high priority during this contamination investigation for several reasons. The period of Mill use of water from the Frog Pond was from the mid 1980s to about 1991 or 1992 when it was replaced with water from Recapture Reservoir. As documented in the Background Report (INTERA, 2007), groundwater levels at the Site have been influenced by the Wildlife Ponds so we know that the head in those ponds has been sufficient to drive infiltration to the water table. The “slug” like character of the nitrate and chloride plume is consistent with a source that has been removed. The distances from the northern-most Wildlife Pond and Lawzy Lake to the centroid of the nitrate and chloride plume are approximately 2300 feet and 2100 feet, respectively. Assuming 26 years since nitrate/chloride laden water entered the system, groundwater would have had to travel at an average velocity of 88 ft/yr from the northern-most Wildlife Pond and 81 ft/yr from Lawzy Lake to account for the current distribution of nitrate concentrations. The velocity of 88 ft/yr from the northern-most Wildlife Pond is high relative to other values that have been calculated for the Site, but possible given the high gradient in this limited portion of the Site due to mounding at the wildlife ponds. Further, the eastern portion of the Site is known to have higher permeability (consistent with the 88 ft/yr velocity required) than the western portion (see the Chloroform Contaminant Investigation Report). The Lawzy Sump is even closer to the plume. For the above reasons Lawzy Lake, the Lawzy Sump, and the northern-most Wildlife Pond are likely potential infiltration points for Frog Pond water. These potential infiltration points have been addressed by installation of two monitoring wells. One (TWN-3) was installed half way along a line between the north end of the Mill building and Lawzy Lake. Analytical results of samples of groundwater from well TWN-3 show 29 mg/L nitrate and 106 mg/L chloride, indicate that this well may be near a potential infiltration point. The other monitoring well (TWN-4) was installed on a line approximately half way between the north end of the Mill building and the northern-most Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 26 Wildlife Pond. Groundwater samples from TWN-4 contained 0.4 mg/L of nitrate and 11 mg/L chloride. The northern-most Wildlife Pond was a stock watering pond for years prior to construction of the Mill. The Historic Pond, which no longer exists, but was located where the Mill’s sulfuric acid tank is currently located, pre-existed construction of the Mill by several decades, tracing back possibly to the 1920s. Livestock can generate nitrate in and around stock watering ponds as salt licks for livestock can generate chloride, and the water head in the ponds could potentially drive those nitrates into the groundwater. Therefore, livestock activity at these ponds had the potential to contribute nitrate and chloride to groundwater but these mechanisms alone would be unlikely to generate enough mass to account for the current mass of nitrate and chloride observed in groundwater. 4.6 Groundwater Withdrawals, Pumpage Rates, and Usage Within a 5-Mile Radius of the Mill Two hundred sixty one groundwater appropriation applications, within a five-mile radius of the Mill site (which includes a 2-mile radius from the nitrate/chloride plume), are on file with the Utah State Engineer's office. A summary of the applications is presented in Table 1.5-4 and shown on Figure 1.5-8 of the Reclamation Plan, Rev. 4.0. The majority of the applications are by private individuals and for wells drawing small, intermittent quantities of water, less than eight gpm, from the Burro Canyon formation. For the most part, these wells are located upgradient (north) of the Mill site. Domestic water, stock watering, and irrigation are listed as primary uses of the majority of the wells. It is important to note that no wells completed in the perched groundwater of the Burro Canyon formation exist directly downgradient of the site within the five-mile radius. Two water wells, which available data indicate are completed in the Entrada/Navajo sandstone, exist approximately 4.5 miles southeast of the site on the Ute Mountain Ute Reservation. These wells supply domestic water for the Ute Mountain Ute White Mesa Community, situated on the mesa along Highway 191. Data supplied by the Tribal Environmental Programs Office indicate that both wells are completed in the Entrada/Navajo sandstone, which is approximately 1,200 feet below the ground surface. Insufficient data are available to define the groundwater flow direction in the Entrada/Navajo sandstone in the vicinity of the Mill. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 27 The well yield from wells completed in the Burro Canyon formation within the White Mesa site is generally lower than that obtained from wells in this formation upgradient of the site. For the most part, the documented pumping rates from on-site wells completed in the Burro Canyon formation are less than 0.7 cubic feet per second. Even at this low rate, the on-site wells completed in the Burro Canyon formation are typically pumped dry within a couple of hours. This low productivity suggests that the Mill is located over a peripheral fringe of perched water; with saturated thickness in the perched zone discontinuous and generally decreasing beneath the site, and with conductivity of the formation being very low. See Section 1.5.6 of the Reclamation Plan, Rev. 4.0 Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 28 5.0 DATA USED AND DATA GAPS Data used for this CIR consists of existing data and new data collected specifically for the nitrate and chloride investigation. Data collected for use in this CIR, are included in the Initial Nitrate Monitoring Report (Attachment 3). The Initial Nitrate Monitoring Report includes laboratory analytical reports and QA/QC reports. Data gaps were encountered as drilling and field sampling began. These gaps were addressed by installing additional wells as needed. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 29 6.0 ENDANGERMENT ASSESSMENT As discussed above, the nitrate/chloride contamination appears to be from a source (the Frog Pond) upgradient of the Mill property, which was not caused or contributed to by Mill activities. DUSA has taken the position that the responsibility for the contamination should not be attributed to the Mill, and DUSA should not be required to prepare a CAP for contamination resulting from a source off of its property. However, were a CAP to be required, and were such a CAP to propose standards under UAC R317-6-6.15F.2 or Alternate Corrective Action Concentration Limits that are higher than the applicable State of Utah Groundwater Quality Standards, an endangerment assessment would be performed. The endangerment assessment would contain any risk evaluation necessary to support a proposal for a standard under UAC R317-6-6.15F.2 or Alternate Corrective Action Concentration Limits that are higher than the groundwater quality standards. The schedule for completion of any such endangerment analysis would be agreed upon prior to commencement of the analysis. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 30 7.0 PROPOSED CORRECTIVE ACTION PLAN UAC R317-6-6.15 (D) As discussed above, the nitrate/chloride contamination appears to be from a source (the Frog Pond) upgradient of the Mill property, which was not caused or contributed to by Mill activities. DUSA has taken the position that the responsibility for the contamination should not be attributed to the Mill, and DUSA should not be required to prepare a CAP for contamination resulting from a source off of its property. However, were a CAP to be required, such a CAP would include an explanation of the construction and operation of the proposed corrective action, addressing the factors to be considered by the Executive Secretary as specified in R317-6-6.15.E and would include such other information as the Executive Secretary may require. It would also include a proposed schedule for completion of the proposed corrective action. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 31 8.0 REFERENCES Argonne National Laboratory, 2005, Environmental Science Division (EVS), http://www.ead.anl.gov/pub/doc/nitrate-ite.pdf, Human Health Fact Sheet, August 2005 Dames & Moore, 1978, Environmental Report, White Mesa Uranium Project San Juan County, Utah, dated January 1978. Denison Mines (USA) Corp. (DUSA), 2007, White Mesa Uranium Mill; Environmental Report in Support of License Renewal Application, February 28, 2007. ———. March 14, 2008.2008 White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) State of Utah Groundwater Discharge Permit No. UGW370004 April 16, 2009. ———. 2009a White Mesa Uranium Mill Initial Nitrate Monitoring Report State of Utah Stipulated Consent Agreement Docket No. UGQ09-03 2009 Sampling Events. December 30, 2009. ———. 2009b Reclamation Plan White Mesa Mill Blanding, Utah. Radioactive Materials License No. UT1900479 Revision 4.0 November 2009. Deutsch, W.J., 1997, Groundwater Geochemistry Fundamentals and Applications to Contamination. New York: Lewis Publishers. Domenico, P.A. and F.W. Schwartz, 1990, Physical and Chemical Hydrogeology, First Edition. New York: Wiley & Sons Inc. Hem, John D., 1992. Study and Interpretation of the Chemical Characterization of Natural Water, U.S. Geological Survey Water-Supply Paper 2254, United States Government Printing Office, Washington, DC, 263 p. Hydro Geo Chem (HGC), 2007, Preliminary Contaminant Investigation Report, White Mesa Uranium Mill Near Blanding Utah, Prepared for Denison Mines, Inc., by Hydro Geo Chem, November 20, 2007. Nitrate Contamination Investigation Report White Mesa Mill Site December 30, 2009 32 ———. HGC, 2009, Site Hydrogeology and Estimation of Groundwater Pore Velocities in the Perched Zone, White Mesa Uranium Mill Site near Blanding, Utah. December 23, 2009. INTERA, 2006, Background Groundwater Quality report: Existing Wells for Denison Mines (USA) Corp.’s White Mesa Uranium Mill Site, San Juan County, Utah December 2006. ———. October, 2007. Revised Background Groundwater Quality report: Existing Wells for Denison Mines (USA) Corp.’s White Mesa Uranium Mill Site, San Juan County, Utah, October 2007. ———. 2008, Revised Addendum: Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, April 30, 2008. McQuillan, Dennis, 2004, Ground-Water Quality Impacts from On-Site Septic Systems, Proceedings, National Onsite Wastewater Recycling Association, 13th Annual Conference, Albuquerque, NM, November 7-10, 2004. McVehil-Monnett Associates, Inc., 2009, Semi-Annual Monitoring Report July1- December 31, 2008 and Annual Monitoring Summary for 2008 White Mesa Mill Meteorological Station, January 20, 2009. Scott, Allan N.; and Thomas, Michael D. A. (January/February 2007). Evaluation of Fly Ash From Co-Combustion of Coal and Petroleum Coke for Use in Concrete. ACI Materials Journal 104 (1): 62–70. American Concrete Institute. NRC, 1979, Final Environmental Statement for the Mill prepared by the Nuclear Regulatory Commission. Solomon, D. Kip, and T. Grant Hurst, 2008, Summary of Work Completed, Data Results, Interpretations and Recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, prepared by Department of Geology and Geophysics, University of Utah. Tischler, Jo Ann, 2009, Preliminary Source Review Report for Nitrate and Chloride in Groundwater at the White Mesa Mill Figures Figure 1 Regional Location Map of White Mesa Mill Near Blanding, Utah Salt Lake City Denver Phoenix Albuquerque UTAH COLORADO ARIZONA NEW MEXICO Colorado Plateau White Mesa Mill Site N S 10 0 30 Miles MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18 TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8 TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31 MW-30 MW-28 TW4-10 TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25 MW-11 MW-29 MW-05 MW-14 Cell No. 1 Mill Site Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19 TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 FROG POND CORAL CANYON SEEP ENTRANCE SEEP S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223WellMap.mxd Figure 2Nitate Well Location Map 800 0 800400 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report. Legend Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Lawzy Lake MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31 MW-30 MW-28 TW4-10 TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25 MW-11 MW-02 MW-24 MW-29 MW-12 MW-05 MW-23 MW-16 MW-15 MW-14 MW-17 MW-03AMW-03 MW-20 MW-21 MW-22 Cell No. 1 Mill Site Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 5 10 15 20 25 25 5 5 30 2015 10 5 5 5600 5560 WESTWATER SEEP ENTRANCE SPRING CORAL CANYON SEEP 5500 5 5 2 0 5 5 4 0 5 480 5460 5440 FROG POND Lawzy Lake 5 5 6 0 5 5 8 0 5580 5585 5600 S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223NitrateMap.mxd Figure 3Nitrate Concentrations with Groundwater Elevations 1,200 0 1,200600 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report. Legend Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Nitrate Concentration (mg/L) Groundwater Elevation Contours 10FtGroundwater Elevation Contours 5ft Nitrate data from September, October, or November of 2009. A single data point was used for each well. MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18 TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31MW-30 MW-28 TW4-10 TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25MW-11 MW-02 MW-24 MW-29 MW-12 MW-05 MW-23 MW-16 MW-15 MW-14 MW-17 MW-03AMW-03 MW-20 MW-21 MW-22 Cell No. 1 Mill Site Cell No. 2 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 5600 5560 WESTWATER SEEP ENTRANCE SPRING CORAL CANYON SEEP 5500 5 5 2 0 5 5 4 0 5480 5460 100 Cell No. 3 100 2 0 0 2 0 0 300 300 400 5 0 0 100 100 100Lawzy Lake FROG POND 5 5 6 0 55 8 0 5 5 8 5 5 5 8 5 5600 S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223ChlorideMap.mxd Figure 4Chloride Concentrations withGroundwater Elevations 1,200 0 1,200600 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report.Legend Monitoring Well Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Chloride Concentration (mg/L) Groundwater Elevation Contours 10FtGroundwater Elevation Contours 5ft Chloride data from September, October, or November of 2009. A single data point was used for each well. MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31MW-30 MW-28 TW4-10 TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25MW-11 MW-02 MW-24 MW-29 MW-12 MW-05 MW-23 MW-16 MW-15 MW-14 MW-17 MW-03A MW-03 MW-20 MW-21 MW-22 Cell No. 1 Mill Site Cell No. 2 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 5600 5560 WESTWATER SEEP ENTRANCE SPRING CORAL CANYON SEEP 5500 5 5 2 0 5 540 5 5 6 0 54 80 5460 Cell No. 3 Lawzy Lake FROG POND 5 5 6 0 5 580 5 5 8 5 5 5 8 5 5600 S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223ChlorofofmMap.mxd Figure 5Ground Water Elevations and Chloroform Plume 1,200 0 1,200600 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report.Legend Chloroform Plume (>70 ug/L) Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Groundwater Elevation Contours 10FtGroundwater Elevation Contours 5ft Chloroform plume from HGC, 2009 MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31MW-30 MW-28 TW4-10TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25MW-11 MW-02 MW-24 MW-29 MW-12 MW-05 MW-23 MW-16 MW-15 MW-14 MW-17 Cell No. 1 Mill Site Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 FROG POND PIEZ-5 CORAL CANYON SEEP ENTRANCE SEEP WESTWATER SEEP Wastewater Treatment Plant Lawzy Pipeline Lawzy Lake S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223SourceMap.mxd Figure 6Possible Sources ofNitrate and Chloride in theVicinity of the Mill 1,300 0 1,300650 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report.Legend Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Possible Nitrate and Chloride Sources Lawzy Pipeline Lawzy Lake MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18 TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 MW-26 TW4-10 Mill Site WildlifePond WildlifePond TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 Fly Ash Pond Former Office Leach Field Scale House Leach Field Main Leach Field Historic LandfillCCD Cell 1 Leach Field V2O5 Oxidation Tanks SX Mini Lab Ammonia Tanks V2O5 Mini Lab &V2O5 Precip Lawzy Sump SAG Leach Field Lawzy Lake Chem Lab Met Lab Sewage Vault U n d e r g r o u n d S e w e r l i n e YC Precip Mini Lab Pip elin e Lawzy Pipeline S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223MillSourceMap.mxd Figure 7Potential Nitrate and ChlorideSources at the Mill Site 250 0 250125 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report. Legend Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Potential Nitrate and Chloride Sources Lawzy Pipeline Lawzy Lake Frog Pond approx. 1 mile NEWastewater Treatment Plant approx. 2 miles NE MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31 MW-30 MW-28 TW4-10 TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25MW-11 MW-02 MW-24 MW-29 MW-12 MW-05 MW-23 MW-16 MW-15 MW-14 MW-17 MW-03AMW-03 MW-20 MW-21 MW-22 Cell No. 1 Mill Site Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 5600 5560 WESTWATER SEEP ENTRANCE SPRING CORAL CANYON SEEP 5500 5 5 2 0 554 0 548 0 FROG POND Lawzy Lake 5600 5580 5 5 6 0 S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223GWElevMap.mxd Figure 8Groundwater Elevations 1,200 0 1,200600 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report. Legend Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Groundwater Elevation Contours 10FtGroundwater Elevation Contours 5ft Groundwater elevation measurements collected december 11 trhough December 16, 2009. A single data point was used for each well. MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18 TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8 TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31 MW-30 MW-28 TW4-10 TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25 MW-11 MW-29 MW-05 MW-14 MW-17 Cell No. 1 Mill Site Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19 TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 5600 ENTRANCE SPRING CORAL CANYON SEEP 5500 5 5 2 0 5 5 4 0 FROG POND Lawzy Lake 5600 5580 5 5 6 0 S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223CaptureZones.mxd Figure 9Nitrate and Cloride Plumes with Estimated Capture Zones 800 0 800400 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report.Legend Estimated Capture Zone MW-4 Estimated Combined Capture Zone (MW-26, TW4-19, and TW4-20) Chloride Plume Nitrate Plume Groundwater Elevation Contours 10FtGroundwater Elevation Contours 5ft Tables Table 1 Sampling Design Sample Location Analysis Notes New Monitoring Well TWN-1 Nitrate, Chloride Test Main Leach Field as source and fill data gap to east of TW4-25 New Monitoring Well TWN-2 Nitrate, Chloride Test SAG Leach Field, Lawzy Sump and Historic Pond as sources and fill data gap to north of TW4-25 New Monitoring Well TWN-3 Nitrate, Chloride Test Lawzy Lake as source and fill data gap to north of TW4-25 New Monitoring Well TWN-4 Nitrate, Chloride Test Upper Wildlife Pond as source and fill data gap to northeast of TW4-25 New Monitoring Wells TWN-5, TWN-6, TWN-7, TWN-8, TNW-18 Nitrate, Chloride Test area north of Lawzy Lake as source and fill data gap to the northwest New Monitoring Wells TWN-9, TWN, 10, TWN-14 Nitrate, Chloride Step out from 6.8 mg/L nitrate found in PIEZ 1 New Monitoring Wells TWN-11, TWN-12, Wells TWN-13, TWN-14, TWN-15, TWN-16, TWN-17, TWN- 18, TWN-19 Nitrate, Chloride Define plume to the northeast TW4-3, TW4-5, TW4-9, TW4-10, TW4-12, TW4-18, TW4-19, TW4-20, TW4-21, TW4-22, TW4-23, TW4-24, TW4-25 Nitrate, Chloride Provide current and quarterly concentrations of nitrate and chloride in chloroform wells. MW-5, MW-11, MW-25, MW-26, MW-27, MW-28, MW-29, MW-30, MW-31 and MW-32 Nitrate, Chloride Provide current and quarterly concentrations of nitrate and chloride in monitoring wells Piezometer 1, Piezometer 2, Piezometer 3 Nitrate, Chloride Additional groundwater sampling point Table 2 Nitrate and Chloride Sampling Results Well Sample Date Nitrate (mg/L) Chloride (mg/L) MW-01 10/19/2009 0.2 17 MW-02 10/21/2009 <0.1 6 MW-03 10/26/2009 0.2 46 MW-03A 10/28/2009 1 42 MW-04 9/14/2009 5.3 43 MW-05 10/12/2009 <0.1 51 MW-11 10/19/2009 <0.1 30 MW-12 10/13/2009 <0.1 67 MW-14 10/20/2009 <0.1 17 MW-15 10/20/2009 0.1 38 MW-17 10/21/2009 0.9 35 MW-18 10/21/2009 <0.1 58 MW-19 10/19/2009 2.2 25 MW-20 10/28/2009 6.2 71 MW-22 10/27/2009 3.8 67 MW-23 10/20/2009 0.1 8 MW-24 10/28/2009 0.1 46 MW-25 10/13/2009 <0.1 34 MW-26 10/13/2009 0.1 58 MW-27 10/12/2009 5.2 44 MW-28 10/12/2009 0.1 104 MW-29 10/26/2009 <0.1 35 MW-30 10/14/2009 15 129 MW-31 10/14/2009 22.6 138 MW-32 10/14/2009 <0.1 32 PIEZ-1 10/27/2009 7.4 61 PIEZ-2 10/27/2009 0.6 7 PIEZ-3 10/27/2009 1.2 19 TW4-01 9/15/2009 7.3 36 TW4-02 9/15/2009 6.6 43 TW4-03 9/15/2009 2.8 21 TW4-04 9/15/2009 8.4 39 TW4-05 9/15/2009 8.3 48 TW4-06 9/15/2009 5 37 TW4-07 9/15/2009 4.1 37 TW4-08 9/15/2009 <0.1 44 TW4-09 9/15/2009 2.5 30 TW4-10 9/15/2009 8.1 51 TW4-11 9/15/2009 7 49 TW4-12 9/15/2009 5.1 22 TW4-13 9/15/2009 4.7 63 TW4-14 9/15/2009 1.5 38 TW4-15 9/14/2009 0.1 46 TW4-16 9/15/2009 8.8 79 TW4-17 9/15/2009 0.1 33 TW4-18 9/15/2009 5.9 26 TW4-19 9/14/2009 <0.1 43 Table 2 Nitrate and Chloride Sampling Results Well Sample Date Nitrate (mg/L) Chloride (mg/L) TW4-20 9/14/2009 3.3 153 TW4-21 9/15/2009 9.2 281 TW4-22 9/15/2009 40.3 391 TW4-23 9/15/2009 <0.1 43 TW4-24 9/15/2009 30.7 618 TW4-25 9/15/2009 3.3 328 TWN-01 10/28/2009 0.5 18 TWN-02 11/2/2009 20.8 55 TWN-03 11/2/2009 29 106 TWN-04 10/28/2009 0.4 11 TWN-05 11/10/2009 0.2 48 TWN-06 11/3/2009 1.4 21 TWN-07 11/10/2009 0.1 7 TWN-08 11/3/2009 <0.1 12 TWN-09 11/10/2009 12 205 TWN-10 11/10/2009 1.4 26 TWN-11 11/3/2009 1.3 74 TWN-12 11/3/2009 0.5 109 TWN-13 11/4/2009 0.5 83 TWN-14 11/4/2009 3.4 32 TWN-15 11/10/2009 1.1 78 TWN-16 11/4/2009 1 39 TWN-17 11/4/2009 6.7 152 TWN-18 11/2/2009 1.3 57 TWN-19 11/2/2009 7.4 125 Upper Wildlife Pond 10/27/2009 0.1 3 Attachment 1 Request for Voluntary Plan and Schedule to Investigate and Remediate Nitrate Contamination at the White Mesa Mill Site, Near Blanding, dated September 30, 2008 State of Utah _ JON M. HUNTSMAN, JR. Governor GARY HERBERT Lieutella1lt Governor CERTIFIED MAIL Department of Environmental Quality Richard W. Sprott Executive DireclOr DIVISION OF RADIATION CONTROL Dane L. Finerfrock Director September 30, 2008 RETURNED RECEIPT REQUESTED Mr. David Frydenlund Vice President, Regulatory Affairs Denison Mines (USA) Corporation (DUSA) Independence Plaza, Suite 950 1050 17th Street Denver, CO 80265 RECEIVED OCT n 0 Z008 J:>,,"======== >''i!! SUBJECT:· Nitrate Contamination Investigation and Corrective Action Plan, White Mesa Uranium near Blanding. Utah. Request for Voluntary Plan and Schedule to Investigate and Remediate. Dear Mr. Frydenlund: On September 16, 2008 the Utah Division of Radiation Control (DRC) sent an bye-mail request for a meeting with DUSA concerning nitrate concentrations that exceeded the Utah Ground Water Quality Standard (GWQS) of 10 mgIL at the White Mesa Uranium Mill (facility) near Blanding. DRC attached a draft letter documenting DRC finilings concerning the nitrate concentrations exceeding the GWQS. A meeting was held by a conference call with DRC and DUSA representatives on September 24, 2008. In this meeting both parties agreed that: 1) Nitrate concentrations have exceeded the GWQS in the groundwater at the facility in five monitoring wells, most of which are not located within the confines of the known chloroform groundwater plume (MW-30, MW-31, TW4-22, TW4-24, and TW4-25). 2) For the monitor wells in question multiple samples in each have been found in excess of the nitrate GWQS, beginning as early as June 22, 2005 (2nd quarter 2005 monitoring event). 3) The nitrate plume has migrated in a different direction than the chloroform plume. 4) The physical boundaries of the nitrate plume are not fully defined. 5) The source(s) of the nitrate contamination are currently unknown. 168 North 1950 West· Salt Lake City, UT Mailing Address: P.O. Box 144850. SaltL1.ke City, UT 84114-4850 Telephone (SOl) 536-4250· Fax (801-533-4097· TO.D. (801) 536-4414 www.deq.urah.gov Printed on lOO% recycled paper Page 2 Request for Voluntary Plan and Schedule During the September 24, 2008 conference call DRC staff informed DUSA that the DRC intends to use discretion in this matter, on an interim basis, including forbearance on use of formal enforcement and up-front monetary penalties, provided that: 1. On or before December 15, 2008 DUSA submits a plan of action and schedule for Executive Secretary approval, for completion and submittal of: A. A Contamination Investigation (CI) report; and B. A Groundwater Corrective Action Plan (CAP). 2. DUSA shows good faith in submittal of the plan and schedule above, in a timely manner and with appropriate content, so as to allow the Executive Secretary to fully review and evaluate the proposal before December 15, 2008. 3. DUSA receives Executive Secretary approval of the proposed plan of action and schedule cited in Item I, above, on or before December 15, 2008. 4. DUSA enters into a Stipulated Consent Agreement by January 15, 2009 with the Executive Secretary, including defined milestones, deadlines, deliverables, and stipulated penalties related to the approved plan of action and schedule. DUSA agreed that it would comply with the above Voluntary Plan and Schedule rather than have DRC issue a Notice of Violation. In regard to the content of the CI Report and Groundwater CAP, outlined in Item 1 above, Executive Secretary approval will be based on determination of clear performance standards and objectives, tangible deliverables, and measurable deadlines that meet all the information reqnirements found in UAC R317-6-6.15(D). For your reference, the requirements of UAC R317-6-6.15(D) are as follows: D. Contamination Investigation and Corrective Action Plan -Requirements 1. Contamination Investigation -The contamination investigation shall include a characterization of pollution, a characterization of the facility, a data report, and. if the Corrective Action Plan proposes standards under R317-6-6.15.F.2. or Alternate Corrective Action Concentration Limits higher than the ground water quality standards. an endangerment assessment. a. The characterization of pollution shall include a description of (1) The amount, form, concentration, toxicity. environmental fate and transport. and other significant characteristics of substances present. for both ground water contaminants and any-contributing surficial contaminants; (2) The areal and vertical ·extent of the contaminant concentration, distribution and chemical make-up; and Page 3 (3) The extent to which contaminant substances have migrated and are expected to migrate. b. The characterization of the facility shall include descriptions of" (1) Contaminant substance mixtures present and media of occurrence; (2) Hydrogeologic conditions underlying and, upgradient and downgradient of the facility; (3) Suiface waters in the area; (4) Climatologic and meteorologic conditions in the area of the facility; and (S) Type, location and description of possible sources of the pollution at the facility; (6) Groundwater withdrawals, pumpage rates, and usage within a 2-mile radius. c. The report of data used and data gaps shall include: (1) Data packages including quality assurance and quality control reports; (2) A description of the data used in the rep0l1; and (3) A description of any data gaps encountered, how those gaps affect the analysis and any plans to fill those gaps. d. The endangerment assessment shall include descriptions of any risk evaluation necessary to support a proposal for a standard under R317-6-6.15.F.2 or for an Alternate Corrective Action Concentration Limit. e. The Contamination Investigation shall include such other information as the Executive Secretary requires. 2. Proposed Corrective Action Plan The proposed Corrective Action Plan shall include an explanation of the construction and operation of the proposed Corrective Action, addressing the factors to be considered by the Executive Secretary as specified in R317-6-6.IS.E. and shall include such other information as the Executive Secretary requires. It shall also include a proposed schedule for completion. 3. The Contaminant Investigation and Corrective Action Plan must be peiformed under the .direction, and bear the seal, of a professional engineer or professional geologist. It should be noted that in accordance with UAC R317-6-6.15(C) " .. Aperson subject to this rule who has been notified that the Executive Secretary is exercising his or her authority under R317-6- 6.15 to require submission of a Contamination Investigation and Corrective Action Plan, shall, within 30 days of that notification, submit to the Executive Secretary a proposed schedule for those submissions, which may include different deadlines for different elements of the Investigation and Plan .. ". This Request for Voluntary Plan and Schedule does not constitute fonnal notice under UAC R317-6-6.15(C). As a result, the Executive Secretary is allowing DUSA to haye up to 90 days from the September 16, 2008 (date that DUSA was first notified bye-mail of nitrate exceeding the GWQS) to develop and secure Executive Secretary approval of an appropriate plan of action and schedule to meet the requirements of U AC R317 -6-6 .15 (D). Page 4 We appreciate your corporation in this matter. If you have any questions please call Dean Henderson at (801) 536-0046. UTAH WATER QUALITY BOARD D1ff.f:t::! Co -Executi ve Secretary DCH:dh Attachment 2 Source Review Report (Tischler, 2009) MEMORANDUM To: Denison Mines (USA) Corp. From: Jo Ann Tischler Date: December 30, 2009 Subject: Source Review Report for Nitrate and Chloride in Groundwater at the White Mesa Mill Introduction In correspondence dated September 15 and September 30, 2008. At that time, the DRC noted that on a review of the 13 quarterly groundwater monitoring reports for the White Mesa Mill (Mill), submitted by Denison Mines (USA) Corp. (Denison) to DRC since the second quarter of 2005, groundwater nitrate levels had exceeded the State water quality standard of 10 mg/L in certain monitoring wells at the Mill site. Specifically, DRC noted that: 1. Nitrate concentrations have exceeded the Ground Water Quality Standard (GWQS) in the groundwater at the facility in five monitoring wells, most of which are not located within the confines of the known chloroform groundwater plume (MW-30, MW-31, TW4-22, TW4-24, and TW4-25); 2. For the monitor wells in question multiple samples in each have been found in excess of the nitrate GWQS, beginning as early as June 22, 2005 (2nd quarter 2005 monitoring event); 3. The nitrate plume has migrated in a different direction than the chloroform plume; 4. The physical boundaries of the nitrate plume are not fully defined; and 5. The source(s) of the nitrate contamination are currently unknown. A map indicating the location of all monitoring wells under the Mill’s Groundwater Discharge Permit (GWDP) and chloroform investigation, which includes the five monitoring wells in question, is attached to this report as Figure 1. A map indicating the 1st Quarter 2008 water levels and direction of groundwater flow in the perched aquifer is attached to this report as Figure 2. In correspondence dated December 1, 2009, the Utah Division of Radiation Control stated their observation that “an apparent chloride plume is in concert with the nitrate contamination plume” at the white Mesa Mill. The observation was based on data from chloroform investigation wells and tailings cell compliance wells during the fourth quarter of 2008 and the first quarter of 2009. DRC’s letter included a nitrate and chloride plume map. DRC noted that chloride concentrations ranged from 113 to 1010 mg/L inside the 100 mg/L iso-concentration line. DRC has recommended that Denison address and explain the chloride concentrations in the nitrate Contamination Investigation Report (CIR) that is due to DRC, on or before January 4, 2010. My report of November 19, 2008 addressed my findings and conclusions regarding sources of nitrate at, and proximal to, White Mesa Mill. The purpose of the current report is to perform an evaluation of the “type, location and description of possible sources of pollution at the facility,” which is required by R317-6-6.15b.(4) to be included in the CIR. This report expands the analysis in the November 19, 2008 report to address sources of groundwater chloride, as well as potential sources that may result in the presence of both nitrogen and chloride. To perform this evaluation, I have considered: 1. What are the current and historic sources of nitrogen-bearing chemicals and biological nitrogen at the Mill? 2. What off-site sources of chemical and biological nitrogen exist within proximity of the Mill? 3. What are the current and historic sources of chloride-bearing chemicals at the Mill? 4. What off-site sources of chemical chloride exist within the proximity of the Mill? 5. Do mechanisms exist for the nitrogen and chloride to reach groundwater? 6. Do mechanisms exist for the nitrogen to reach groundwater as nitrate? 7. Are the known volumes and concentration of the sources consistent with ongoing nitrogen and chloride presence in groundwater? 1.0 Basis and Limitations of this Evaluation This evaluation was limited to a qualitative process source review. That is, it considered a broad range of nitrogen and chloride sources present on or in the vicinity of the Mill and narrowed them down to those most likely to affect groundwater. The review did not limit the potential sources based on quantitative factors in groundwater hydrogeology or geochemistry. The evaluation in this report is based on the following information: 1. Interviews with Denison corporate staff during October 2008, to gather information on nitrogen-bearing materials used or present on site throughout the Mill’s operating history. 2 2. Interviews with Denison corporate staff during October 2008, to gather information on historical use of pits, ponds, landfills, and offsite water sources at the Mill. 3. Interviews with Denison corporate staff during December 2009 to supplement previous operations information to address chloride, as well as nitrate, sources. 4. Current and historic site maps provided by Denison corporate staff. 5. The Mill’s process and equipment description from Denison’s Radioactive Materials License renewal application dated February 2007. 6. Tailings solution sample data provided by Denison corporate staff. 7. Reagent, Laboratory Chemical Inventory, and Petroleum Products tables from the White Mesa Mill Spill Prevention, Control, and Countermeasures (SPCC) Plan (2001). 8. DRC Draft Request for Additional Information (RFI) regarding nitrate exceeding Utah GWQSs dated September 15, 2008, and DRC Request for Voluntary Plan and Schedule to Investigate and Remediate dated September 30, 2008. 9. Summary of Work Completed, Data Results, Interpretations and Recommendations for the July 2007 Sampling Event at the Denison Mines, USA, White Mesa Uranium Mill Near Blanding Utah, prepared by T. Grant Hurst and D. Kip Solomon, Department of Geology and Geophysics, University of Utah, May 2008. 10. Revised Background Groundwater Quality Report; Existing Wells for Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, Prepared by INTERA, Inc., October 2007. 11. Revised Addendum: Evaluation of Available Pre-Operational and Regional Background Data; Background Groundwater Quality Report: Existing Wells For Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, prepared by INTERA, Inc., November 16, 2007. 12. Revised Addendum: Background Groundwater Quality Report: New Wells For Denison Mines (USA) Corp.’s White Mesa Mill Site, San Juan County, Utah, prepared by INTERA, Inc., April 30, 2008). 13. Data from the 2nd Quarter 2008 Chloroform Monitoring Report – White Mesa Uranium Mill. 3 14. Nitrate and chloride plume maps prepared by Intera from 2008 Mill groundwater data. 15. Reference documents cited at the end of this report. 2.0 Overview of Environmental and Human (Anthropogenic) Nitrogen Sources In both the natural and industrial environments, nitrogen exists in three chemical forms: either as free nitrogen gas (N2), “fixed” in inorganic compounds or “bound” into organic compounds, as discussed below. 2.1 Biological Nitrogen Cycle Apart from free atmospheric nitrogen (gaseous N2), nitrogen exists in the natural environment in four chemical forms: • Organic nitrogen (urea, uric acid, amines, amino acids, nucleic acids, alkaloids, proteins, etc.); • Inorganic free ammonia, that is present in equilibrium between its non-ionic form (NH3) at high pH, and ionized form (NH4OH) at neutral and low pH; • Inorganic nitrite, an intermediate oxidized form (NO2); and • Inorganic nitrate, a stable oxidized form (NO3). Nitrogen is ubiquitous in the living environment and is part of the living tissues, digestive wastes, and decomposition products of every living thing on the earth’s surface. As a result, there are many natural sources that mobilize nitrates into surface water and many mechanisms for nitrates to enter groundwater. Nitrogen is continuously converted and recycled through the biosphere in a series of processes that comprise the nitrogen cycle. The wastes from living things and the proteins in dead plant and animal tissues are decomposed by ammonification bacteria to form ammonia. Specialized nitrifying bacteria convert the available ammonia to nitrite and/or nitrate in aquatic environments and soils. Nitrite is relatively short-lived in water and hydrated environments because aquatic bacteria convert it rapidly to nitrate. Organisms such as fungi and denitrifying bacteria use the nitrates as a source of oxygen, releasing the bound nitrogen back to the atmosphere as gaseous nitrogen. In aquatic environments, the least stable form of nitrogen in water is ammonia. In oxygenated aquatic environments, it is readily converted to nitrite and nitrate. In oxygen- deficient waters it may be converted to nitrogen gas and hydrogen ions. 2.2 Anthropogenic Nitrogen Nitrogen compounds are some of the most widely synthesized, converted, and consumed materials in every human industrial, commercial, and domestic activity. Human activity introduces nitrogen into the environment from four major types of sources: 4 • Agricultural; • Combustion-related; • Sewage and septic-related; and • Industrial chemicals. Agricultural By far the largest source of nitrogen compounds introduced to the environment by human activity are from agricultural sources. Per the US EPA, the largest loads of ammonium and nitrite/nitrate nitrogen reach the environment from agricultural, domestic and commercial runoff to surface water bodies and infiltration to groundwater from overuse of fertilizers, as well as feedlots, cattle yards, slaughterhouses and dairies. In the western US particularly, nitrate/nitrite overloads from agricultural sources far outweigh by several orders of magnitude all the chemical/industrial loads to most surface receiving waters. Combustion The second largest source is the combustion of fossil fuels, resulting in atmospheric nitrogen both from the nitrogen bound in the fuel (particularly in coal) and the conversion of atmospheric nitrogen to oxygenated compounds at combustion temperatures in motor vehicles, power plants, boilers, incinerators, kilns, and other fired heaters. In stationary equipment, depending on the efficiency of combustion, some nitrate may remain bound in compounds in the resulting fly ash and/or bottom ash. Per even the oldest literature on the topic, all coal sources worldwide average from 1.0 to 1.5 percent (10,000 to 15,000 ppm or 10,000,000 to 15,000,000 ppb) bound nitrogen. More modern data indicates the range to be as wide as 0.5 to 2 percent. Nitrogen in coal is generally bound into complex heterocyclic molecules (ring compounds containing both carbon and nitrogen). The nitrogen content of ash resulting from coal combustion varies, and may have even higher levels, depending on the type of burner and type of emissions control. Both stack gases and residual ash exhibit nitrogen in oxidized form, as nitrite/nitrate. In fact, historically, the earliest industrial attempts at synthesis of ammonia and nitrate compounds for the chemical industry were based on converting this nitrogen content of coal. Sewage and Septic Sources The third largest sources are from septic systems and sewage plant byproducts. Ubiquitous and relatively uncontrolled leach fields and septic systems load nitrogen in a variety of compounds and forms (from sanitary wastes, food wastes, detergents, and cleaning chemicals) directly to surface and subsurface soils. Both the US EPA and US Geological Survey consider septic systems to be one of the largest uncontrolled threats to surface water and drinking water quality nationwide. Recent source investigations published by Dennis McQuillan at the 2004 National Onsite Wastewater Recycling Conference for nearly 1,200 water wells in New Mexico indicated that, in that setting, 5 on-site septic systems contaminated more acre-feet of groundwater, and more public supply systems, than all other sources in the region combined. Land disposal or land application of sludges and solids from aerators, digesters, and other municipal sewage treatment plant processes, which convert, dewater, and concentrate multiple forms of nitrogen from treated influent water have a comparable or greater effect on receiving soils. Wastewater plants also add nitrogen to the atmosphere through the off-gases from driers, digesters and open process equipment. Table 1 presents data on nitrate levels in influent liquids and residual solids from a wide range of municipal sewage treatment plants as studied by Metcalf and Eddy. Both primary sludges and digester sludges range as high as 60,000 mg/L (ppm) of total nitrogen. Historic Sewage Treatment Practices Very little specific information is available regarding the Blanding municipal sewer treatment plant or Publicly-Owned Treatment Works (POTW). However, general historic information on wastewater management history provides some idea of what operations were likely in a rural POTW which was already in operation before the construction of White Mesa Mill in the late 1970s, and may have been in operation as early as the first decades of the twentieth century. Data from the USEPA wastewater treatment inventory indicates that in 1945, only 5,786 sewer treatment plants operated throughout the entire US. By 1974, this number had increased to 21,011. These numbers indicate that prior to and during this period, a large number of communities managed sewage waste by untreated direct discharge to surface water bodies, deep wells, land disposal areas, and septic fields. The data also indicates that as recently as 1974, primarily in rural areas, 78 percent of the existing treatment plants had less than 1 million gallons per day (MGD) capacity and 14 percent still had no secondary treatment (no biological or chemical processes to remove organic content). Of all 21,011 plants of all types operating in 1974, 95 percent had no post-treatment nitrogen or chloride removal. According to the US EPA 1974 Needs Survey, the most common type of treatment design in facilities of less than 1 MGD, and in many above that size, was aerobic stabilization ponds. This type of treatment attempts to increase the oxygen content available to treatment bacteria by aeration and mixing, or by aeration and mixing coupled with algae growth for additional oxygen. These types of facilities are defined as suspended growth treatment processes. In suspended growth treatment, the biomass is mixed and suspended throughout the wastewater. After microbial contact and treatment, the majority of the biomass (bacteria and algae) exits the pond with the treated water. If there is little or no downstream solids removal processing, nearly the entire solids mass exits with the treated water. 6 It should also be noted that biological treatment, whether suspended or fixed type, is designed primarily to convert, not remove, organic carbon and nitrogen content. While the sewage carbon and nitrogen compound levels are reduced during bio-treatment, they are converted into an increase in biomass (microbes and algae). Unless solids reduction steps follow the bio-treatment, nearly the same carbon and nitrogen levels exit in the treated water, just in different forms. Suspended growth systems are far more prevalent in rural settings than the more sophisticated attached growth processes (trickling filters, rotating biological contactors, and packed bed reactors) used in large urban plants, in which the biomass is attached to an engineered surface, wastewater passes through the mass for bio-treatment, and exits with lower suspended and dissolved solids content. Application of a Time-Relevant Case Study For two years during the late 1970’s, I participated in a sampling and analysis study of municipal sewage treatment plant outfalls and nearby receiving waters in a non-urban area of northern New Jersey. The study was part of an ongoing program to assess nitrogen-based pollutant loads and other sources of chemical and biochemical oxygen demand exiting from small-community secondary treatment plant discharges into the upper reaches of the Hackensack Meadowlands. Water samples from drainages that received flows from industrial/commercial outfalls just upstream and downstream were also sampled for comparison. The work was published by Dr. R. Trattner in “Water Quality in a Recovering Ecosystem” in 1978. While the receiving environments differed from the Blanding area situation (surface water versus soil and groundwater), the wastewater treatment plant sources in New Jersey were of comparable vintage and type to warrant the extension of some observations to the Blanding situation. The most significant observation from two years of monthly monitoring was that with respect to effluent nitrate, the plants were generally in upset conditions more often than they were in controlled conditions. The upsets included the periodic overtopping of settling and solids removal equipment and discharge of high total suspended solids (TSS), indicating that bio sludge was exiting via the effluent water instead of through the solids management circuit. The other significant observation was that the receiving waters outside the sewer plant outfalls exhibited amine and nitrate levels orders of magnitude higher than receiving waters near the industrial outfalls, including outfalls from nitrogen-wasting processes including tanning and dyeing, leather finishing, rendering, and meat-packing plants. While the above findings resulted from monitoring of aqueous waste to surface water discharges (not aqueous waste to soil to groundwater), the indications are consistent with the USEPA and McQuillan opinions regarding the relatively greater importance of sewage nitrogen than industrial nitrogen as an environmental pollutant. 7 Industrial Chemicals Industrial chemicals and chemical wastes are generally a smaller source of nitrogen than those identified above. In the US chemical industry, non-gaseous industrial nitrogen compounds typically reach the environment through: • Industrial discharges into municipal wastewater treatment systems followed by treatment and water discharge into surface water bodies; • On-site wastewater treatment to permit-driven standards and discharge into surface receiving waters; • Land disposal of the solids and sludges from either of these types of treatments; and • Direct spills of nitrogen-bearing chemical products or chemical/industrial wastes. As mentioned above, however, in biotic environments, nearly all inorganic nitrogen compounds, upon exposure to water and oxygen, are readily converted to nitrites, then nitrates, by ubiquitous natural biochemical processes in surface water bodies and runoff channels. Therefore, nearly any industrial spill or release of inorganic nitrogen compounds that is exposed to atmospheric oxygen and soil or water bacteria will eventually be converted to nitrate. For this reason, ammonia nitrogen compounds that reach groundwater through surface spills will eventually be exhibited in groundwater as nitrate, not ammonia, nitrogen. 3.0 Overview of Natural and Anthropogenic Chloride Sources 3.1 Natural Sources and Properties The chloride ion is present in one of the most ubiquitous materials on earth – seawater and natural brines. In inland areas, inorganic chloride compounds may be present in regional geologies as residual salts and mineral deposition from ancient inland seas. Chloride as sodium chloride is present in biotic systems almost universally as a dilute saline component of cellular fluids in both micro- and macro-species. Chloride is a polar ion that in many forms (chlorates, chlorites, hypochlorites, chlorine dioxide, metal chlroides) is a strong oxidizer, generally destructive to both microscopic and macroscopic life. Since the late 19th century chlorine-containing bleaches and preparations have seen increasingly widedspread use as germicides and sterilants, beginning even before their ability to destroy microbes by penetration and disruption of their cell membranes was understood. However, unlike the plethora of nitrogen-bearing chemicals and biochemicals in biotic systems, few or no organo-chlorine compounds exist in nature. Organo-chlorine species (arochlors, chloroohenols, dioxins, chloramines, chlorinated olefins, chlorosulfonic compounds) are also disruptive to biotic processes, hence their extensive use during the 8 20th century of chlorinated organics as tissue-soluble pesticides and herbicides. Overwhelmingly, the chloro-organic compounds present in the natural environment today are the products of synthetic organic chemistry and/or the secondary chlorination of synthetic and natural organic chemicals in wastewater treatment settings. 3.2 Anthropogenic Sources Sewage and Septic Sources Chloride is a relatively non-reactive solute that occurs in all sewage. It enters sewage from two sources – household chemicals and wastes discharged into the sewer system, and additional chloride added during sewage treatment. Chloride-bearing household chemicals include primarily bleaches, cleaners, and water softener salts used and disposed in relatively large volumes, and pharmaceuticals, solvents and pesticides generally present in domestic wastewater at very low levels. US EPA data from the past decade indicates that domestic water entering a typical household increases in chloride content from 20 to 50 times before it reaches the sanitary sewer or septic sump. For households using salt-regenerated water softeners, this ratio of increase may be one or more orders of magnitude higher. Data from the same period indicates that from tap water to the effluent of a sewage treatment plant, chloride levels increases an average of 74 times and up to 200 times. That is, the municipal treatment of domestic wastewater not only does not remove the chloride ion prior to discharge, it adds significantly to its concentration. Chloride addition in wastewater treatment is discussed below. Disinfection in Sewage Treatment Plants Chlorine, in one of several forms, is the most common disinfectant in wastewater treatment throughout the world. Depending on plant size, safety considerations, and economic factors, it is applied either as free chlorine gas, sodium hypochlorite, calcium hypochlorite, and/or chlorine dioxide. Chlorine in one of these forms is added to generate an excess of solubilized chlorine, in the form of hypochlorous acid. Chlorine reacts first with inorganic ions in biotreated sewage to form chloride ions. The effluent from most wastewater treatment aerobic steps contains significant amounts of nitrogen in either the ammonia form, or as nitrate if the plant is designed to achieve nitrification. As additional chlorine is added, and the inorganic demand is satisfied, free chlorine reacts readily with the ammonia content of bio-treated wastewater to form mono-, di- and tri-chloramines, which act as disinfectants. Some chloramines are eventually oxidized to nitrous oxide and nitrogen. The point beyond oxidation, at which all the reaction demands have been met and all added chlorine remains as free chlorine, is referred to as the break point. The majority of chlorinated compounds formed up to the breakpoint, other than the nitrous oxide and nitrogen gas, precipitate as solids and increase the sludge volume. The goal of 9 wastewater plant chlorination is to add chlorine far in excess of the breakpoint over the process from biotreatment through discharge. As a result, treated effluent may contain heavy loads of excess chlorine, to ensure disinfection. Metcalf and Eddy indicate that wastewater plants running optimally may have residual chlorine levels (all forms) in effluent from the biotreatment step only, as ranging from less than 1 ppm to as much as 7 ppm. They do not report chlorine addition levels for the subsequent steps of the process prior to discharge, which is where the heaviest chlorine use takes place. If the plant does not have a de-chlorination process step, the chlorine residuals remain in the discharged effluent. The levels of chloride and chlorinated compounds that exit the plant during upset conditions, or when impoundments overtop and sludges and sludge solutions exit the plant, are significantly higher than what is exhibited at the exit of the biotreatment step. Other Uses in Typical Wastewater Plants Chlorine is added widely throughout other parts of typical sewage plants, also adding to the effluent chloride load. In the collection area it may be applied for slime growth control, corrosion protection, and odor control. In the treatment section it may be applied for grease removal, BOD reduction, oxidation of ferrous sulfate, filter process control, reduction of sludge bulking, oxidation of supernatant form digesters and control of foaming in digesters, ammonia oxidation, odor control and oxidation of bio-refractory (non-degraded) compounds. It is also heavily used in the disposal section of most plants for disinfection (bacteria reduction) and odor control. In the New Jersey case study for example, 10 of the 11 monitored sewer plant designs were based on aerated stabilization ponds, and one was an anaerobic Imhoff tank design. Typical of the era, the Imhoff plant and nine of the aerobic plants used inorganic forms of chlorine, primarily hypochlorites, at multiple points in the process for odor control, slime and microbe control, corrosion control, general disinfection and microbe destruction prior to effluent discharge. One aerobic plant used a UV/bromine treatment for the same purpose. Also typical of the era, 10 of the 11 had no tertiary treatment for nitrogen removal, and none of the 11 had any polishing treatment for chloride or bromide removal. Industrial Chemicals The production of chlorine (gas), primarily via the hydrolysis of natural brines, is one of the most important heavy chemical industries, ranking as one of the top three chemicals produced in the US, both by tonnage and dollar value. Chlorine’s organic and inorganic chloride products are used in a wide spectrum of chemical processes including pulp and paper, solvents and degreasers, polymers and plastics, pesticides, refrigerants, bleaches and sanitizers, heat transfer fluids, dry cleaning, military chemical weapons (nerve and blister agents), road de-icing, and metallurgy. Industrial chlorine or chloride enters the environment via the same routes as described for industrial nitrogen, above, that is, wastewater treatment associated with chemical manufacture or use, or direct spills of chemical products. 10 In industrial settings, the presence of chloride in environmental media may be affected significantly by all of the industrial and domestic use of inorganic chlorides (salts), synthetic chemicals, and sewer treatment sources. In rural and non-industrial settings, where the presence of synthetic industrial chlorinated chemicals are present at household (or ranch or farm) sized quantities, the effects of inorganic salts (salt licks, road deicing, water softeners) and sewage treatment sources, tend to predominate. 4.0 Potential Sources of Groundwater Nitrate Table 2a provides a summary of industrial, commercial, agricultural and municipal sources of nitrogen compounds from which potential candidate sources for the Mill nitrogen can be elicited. The list does not itemize every scientifically known nitrogen compound. That is, it does not include short-lived or rare compounds synthesized solely for research purposes. For brevity, in many cases the list presents a class of compounds or types in lieu of naming every species in the category. The upper section of the table identifies those compounds and classes of materials that could be expected to be present on the Mill site or in the vicinity of the Mill. The lower section completes a broader survey of compounds and sources and indicates why they are not, or are likely not, present at or proximal to the Mill. The potential sources are evaluated and discussed in more detail in the sections below. 4.1 On-Site Nitrate Sources at the Mill The Mill commenced operations in May 1980, and operated on a campaign basis at near full capacity on conventional ores from the Colorado Plateau (uranium-vanadium ores) and Arizona Strip (uranium ores) until 1991. The Mill also processed conventional ores for short durations in 1995 from the Arizona Strip, in 1999 from the Colorado Plateau, and in 2008 and 2009 from the Henry Mountains complex and the Colorado Plateau.. In addition, commencing in 1993, the Mill processed finite volumes of alternate feed materials from several Formerly Utilized Sites Remedial Action Program (FUSRAP) sites and from other uranium and metal industry sources. As indicated in my evaluations of alternate feed characteristics since 1997, alternate feed materials have never been an appreciable source of nitrogen compounds, never exhibiting more than ppm levels in finite volumes of materials that have either been stored in closed containers or have remained on the ore pad less than a few months before processing. Based on this history, the potentially larger sources of nitrogen introduction into the Mill likely preceded and were independent of the alternate feed program. Tables 3a and 3b provide integrated lists of nitrogen-bearing laboratory and bulk reagents stored and used on the Mill site. Potential sources of groundwater nitrogen from among these and other materials on the Mill site are discussed below. 11 Septic Leach Fields As mentioned above, both the US EPA and US Geological Survey consider septic systems to be one of the largest sources of nitrate loads to surface water and groundwater, nationwide. The Mill has several operating or historic septic leach fields. The locations of these leach fields are indicated on the attached Figure 3. Some key facts relating to these leach fields are discussed below. The Former Office Leach Field (located south east of the Mill’s Administration Building) is no longer in use. It was used in the early 1980’s to accept septic waste from the Mill’s administration building. For a short period of time, it also accepted wastes from the Mill’s chemical and metallurgical laboratories, until Cell 1 was competed in 1981; The Scale House Leach Field (located south west of the Scale House) may no longer be in use (see discussion under Main Leach Field below). It was used until the mid 1980’s to accept septic waste from the restroom in the Scale House. It also accepted laboratory wastes from the temporary laboratory in the Scale House from around 1977 until the main laboratories in the Mill’s administration building were commissioned in 1980; The Cell 1 Leach Field (located just east of Cell 1) is currently used to accept septic wastes from the restrooms in the Mill’s Central Control Room and SX Building; The SAG Leach Field (located just north of the Mill building) was used to accept septic waste from the restroom in the Shifter’s Office near the SAG Mill. It is currently operable, but that office and restroom have been closed since the 1999 Mill run. The toilet at that location is currently not operable. The Main Leach Field (located east of the ore pad) was put into use in the mid 1980’s and is currently in use. Septic wastes from the restrooms in the Administration Building, the Maintenance Shop, the Warehouse and the Changing/Shower rooms are piped to the Sewage Vault, located under the current yellowcake storage area, where it is pumped to the Main Leach Field. There is a pipe from the Scale House to the Sewage Vault. However, effluent is not entering the Sewage Vault from that pipe, which suggests that the waste from the Scale House restroom is still being discharged into the Scale House Leach Field, or that there could possibly be a breach in the pipe and the Scale House waste may be discharging at that point. Two of these leach fields (the Scale House Leach Field, and the Former Office Leach Field) are believed to be the source of the existing chloroform contamination at the Mill, due to the historic disposal of laboratory wastes in those leach fields (see the discussion below relating to Mill Laboratories). Nitrate, along with chloroform, has been sampled in all of the chloroform investigation wells as part of the chloroform investigation. Attached as Table 4 to this report is a list of all chloroform and nitrate sample results from the chloroform investigation, as taken from the Mill’s most recent Chloroform 12 Monitoring Report. Attached as Table 5 to this report is a table prepared by DRC and attached to the draft September 15, 2008 Request for Additional Information, which shows nitrate concentrations in monitoring wells within the chloroform contamination plume and highlights in yellow nitrate concentrations in those wells that have exceeded the GWQS of 10 mg/L. Table 6, provided by Denison Corporate staff, is a tabulation of chloride and nitrate data from Mill monitoring wells and test wells collected during the last quarter of 2009. In addition, as described below, prior to the construction of Cell 1, the Mill laboratories have also discharged a variety of non-septic nitrogen-bearing chemical solutions to several of the leach fields. From this information, it is clear that the Scale House Leach Field and Former Office Leach Field have contributed nitrate to groundwater at the site. It is possible that the other septic leach fields alone, or in conjunction with these two leach field, have given rise to or contributed to the nitrate contamination that is the subject of this report. A number of these other leach fields are either upgradient or cross-gradient to such nitrate contamination. In particular, the SAG Leach Field is located upgradient of the nitrate plume. The Main Leach Field has been the Mill’s main septic leach field since the mid 1980’s, and is located upgradient/crossgradient of the nitrate plume. Because the SAG Leach Field is upgradient of the nitrate plume and the Main Leach Field is located upgradient/crossgradient of the nitrate plume, they should be given a high priority in the Sampling Plan. Frog Pond Until the early 1990s, process water for the Mill was limited to the deep water supply wells on site, and the Mill sought additional sources of process water. Recapture Reservoir was not constructed until 1988-1989, and the pipeline from Recapture Reservoir to the Mill was not completed until around 1991-1992. From the mid 1980s until the Recapture Reservoir water was first piped to the Mill in 1991-1992, effluent from the regional sewage treatment plant, north-east and upgradient of the Mill site served as an additional water source for Mill operations. The two ponds associated with the water treatment facility are unlined. Effluent and seepage from the water treatment plant flows to Corral Canyon, just east of the Mill site. This flow was dammed by local ranchers prior to construction of the Mill to form a pool just north of the entrance to Corral Canyon. This pool exists today and is referred to as the “Frog Pond”. Discussions with personnel at the City of Blanding have confirmed that the water in the Frog Pond is fed by the water treatment facility. At the Frog Pond an electric pump carried the water for use at the Mill via an underground pipe at the rate of about 200 gallons per minute (gpm). Just north of the Mill’s restricted area, the water could be diverted to either the northern most wildlife pond (the “Upper Wildlife Pond”) or to a secondary pond, referred to as “Lawzy Lake”. 13 At the Upper Wildlife Pond a diesel pump was activated when water was needed in the Mill. Water was then pumped from the Upper Wildlife Pond to the Mill’s pre-leach tanks, which acted as water storage for the Mill. The water in Lawzy Lake was gravity fed via a pipe to a sump (the “Lawzy Sump”) within the restricted area. Once the water reached the Lawzy Sump, it was pumped via a pipe to the pre-leach tanks for water storage. None of the ditches, the Upper Wildlife Pond, or Lawzy Lake are lined. The locations of the water treatment ponds, the Frog Pond, the Upper Wildlife Pond and Lawzy Lake are shown on Figure 4. The various ditches and pipelines connecting Lawzy Lake to Lawzy Sump, the wildlife ponds to the SAG leach field, and the sewage vault to the Main Leach Field are also shown on the attached Figures 5. Water was pumped from the Frog Pond to the Upper Wildlife Pond and/or Lawzy Lake as needed during operations. During periods of full operations, those ponds were filled with water from the Frog Pond several times per year, and sometimes several times per month. Anecdotal evidence suggests that the waste treatment facility experienced upsets and leakages in their post-treatment sludge ponds, resulting in discharges of sewage sludge and/or sludge-laden water from the plant to the Frog Pond. The sludge-laden waters exhibited a septic/sewage odor in the channel, in each ponded area, in the Lawzy Sump, and where it entered the uranium leach circuit. Various Mill staff described adding the water to the Mill process at rates varying from 25 to 200 gpm depending on the specific needs of the ore run (at normal operating rates the Mill consumes and evaporates approximately 650 gpm). This use of pond water was finite and lasted until about 1992, when Recapture Reservoir water became available. As discussed above, sanitary sewage byproducts are extraordinarily high in nitrates and other nitrogen-bearing compounds concentrated in the precipitation, concentration and digestion steps of the sewage treatment process. As mentioned in Table 1, typical sludge exhibits nitrogen contents ranging up to 60,000 ppm. Because sewage sludge has already undergone physical/chemical treatment (primary treatment) and, in some plants, bio- oxidation (secondary treatment), the majority of the nitrogen content is present in the nitrated form. This source review did not include any study of the size, process configuration or operational practices of the regional sewage treatment plant at the time of reuse of its effluent at the Mill. It is not known whether the plant had primary (suspended solids), secondary (biological treatment and disinfection), or tertiary (color, odor and nitrate/chloride conversion and polishing) treatment. Based on the location and time period under consideration it is likely the plant was limited to primary and/or secondary treatment. The data in Table 1 is relevant and representative because it represents an overview of nationwide treatment plants, including some of greater sophistication, collected in the late 1970s through 1980, a period when the Blanding treatment plant operated but the Mill was not yet constructed. 14 Although the Mill’s use of sewage-based water ceased in the early 1990’s, sediments and residuals from the Frog Pond and transfer ponds remained and may still be detectable by soil sampling or additional groundwater sampling. However, nitrate concentrations would be expected to diminish significantly over time due to natural biodegradation, and current nitrate levels would be expected to be lower than when these structures were actively used. This source could be the sole or a significant contributor to the nitrate plume at the Mill site, and is upgradient to the most upgradient well in question (TW4-25). Furthermore, the fact that the water from the Frog Pond was conveyed on the surface via pipeline to the Mill site, could explain why high nitrate concentrations have not been observed in the Mill’s most upgradient monitoring wells, MW-1, MW-18 and MW-19, as noted by DRC. For these reasons, the Upper Wildlife Pond, Lawzy Lake and the Lawzy Sump are likely sources of nitrate in on-site groundwater. Fly Ash Pond From 1980 to 1989, the Mill used a coal-fired steam boiler for operations. Fly ash and bottom ash from combustion of bituminous Colorado Plateau coal were disposed of primarily in tailings Cell 2. However, the ash disposal system did not always work as intended, due to the high clinker volume in the ash. In upset situations, the fly ash was disposed of in a pit referred to as the “Fly Ash Pond” that was located just north of TW4- 24. The Fly Ash Pond was originally built to hold construction water. The location of the Fly Ash Pond is indicated on Figure 3. The Fly Ash pond was located in the area of the Mill close to tailings Cell 1 that was designed to catch surface runoff from the site and direct it into the tailings cells, that is, it was a low area. As a result, the pit was often filled with water after rainfalls, and came to be referred to as a pond. Because it was often the focal point for runoff from the Mill’s ore pad and process facilities, it may also have accumulated any runoff from surface spills of re-agents or process streams that could potentially have occurred during the history of Mill operations. For example, any potential upsets in the nearby vanadium circuit (which could contain nitrates, as discussed below) that may have resulted in spills to the surface could have potentially impacted the Fly Ash Pond. The Fly Ash pond was emptied out and the deposited fly ash was disposed of in Cell 2 in 1989. The emptied pit was filled with random fill and use of the pit ceased at that time. However, because the area where the Fly Ash Pond had been located is at a relatively low point, it has until recently continued to pool rainwater and has frequently been covered in standing water during storms, overflowing onto the surrounding surface. This area was re-graded and re-contoured in 2007 in an effort to better direct the runoff water to tailings Cell 1 and to thereby minimize this pooling. As discussed in Section 2, above, coal and coal-based combustion ash may exhibit up to percent levels (tens of thousands of ppm) of bound or oxidized nitrogen. As also 15 mentioned, oxidized, distilled, and treated coal residuals were the chemical industry’s most important source of nitrogen chemicals before the advent of high pressure synthesis technology. The Fly Ash Pond could therefore be considered to be a potential source for nitrate contamination in groundwater at the site. However, because the Fly Ash Pond is located several hundred feet downgradient of TW4-25 and the upgradient boundary of the plume, the Fly Ash Pond is not likely the most significant contributing source to the plume. Potential Spills from Uranium and Vanadium Circuit Chemicals The Mill uses ammonia or amine compounds at several points in the processing circuits. A summary of nitrogen-bearing compounds used in the Mill’s processes, from the Operations Chemical Inventory in the Mill’s SPCC Plan is provided in Table 3a. Anhydrous ammonia is stored as a gas in the tank farm before it is volatilized in a vaporizer for 1) introduction to the yellowcake precipitation area and 2) pH adjustment in the vanadium circuit. In these circuits, ammonia is dissolved into aqueous process streams as ammonium hydroxide. Ammonium sulfate, purchased and stored both as powdered solid and aqueous solution, is added to the vanadium precipitation circuit. An organic amine, purchased and stored as a liquid, is added to the solvent extraction (SX) circuit; however it is present in only trace amounts in both the SX and counter-current decantation (CCD) areas. Spills and overflows of these materials within the process buildings enter the floor drains and are transferred to the tailings system. The process circuits and floor drains and sumps that could historically have held or carried these solutions are designated on Figure 3. Based on information from Mill personnel, there has been no history of failures or upsets of the storage tanks, drums, or powder containers of the liquid or solid materials in the tank farm or in transfer to the Mill buildings. Although some of these materials contain high concentrations of fixed or bound nitrogen, spills of these materials are too finite a phenomenon to account for an ongoing plume on their own. There is no history of spills or upsets of the anhydrous ammonia tank system. If an upset were to occur in this system it would, in any case, generate primarily a gaseous emission, not a liquid or solid discharge to the tank farm pads and berms. The only potential ongoing source within the current Mill operations is theoretically the vanadium and/or uranium circuit floor drain systems. Within the process buildings, spills, overflows, wash-downs and other process waters containing ammonium hydroxide (generated from the anhydrous ammonia), ammonium sulfate, and organic amine enter the floor drain system from time to time and are transferred by above-ground pipe to the tailings system. The floor drains are typical concrete box channels with top gratings, designed to receive, collect, and channel spills, vessel overflows and drain-outs, and 16 wash-down waters to the tailings transfer lines. The types of activities that transfer nitrogen-bearing solutions to the floor drains are ongoing and can be relatively frequent during operational periods. At the current time, there is no reason to expect that there are breaches or breaks in the floor drains or the tailings transfer lines. As a result, the floor drains and transfer system are an unconfirmed potential source. However, for the foregoing reasons, and because all of the process circuits, floor drains and sumps are located downgradient of TW4-25 and the upgradient boundary of the plume, these should be considered to be low priority potential sources and hence given a low priority in the Sample Plan. Mill Laboratories Table 3b lists nitrogen-bearing chemicals used and stored in small quantities in the Mill’s on-site chemical and metallurgical laboratories. The laboratories stored and used small (from 100ml vials to kilogram and liter quantities) of a variety of nitrogen-bearing compounds as reagents, titrants, indicators, separating agents, and surfactants, for sample preparation, extraction, and testing steps and received additional nitrogen-bearing process samples from various points in the vanadium circuit for QC testing. Testing materials, residuals, rinsates and other chemicals that reached the lab sinks and lab drain systems were, as required by the Mill’s license conditions, discharged to the tailings system commencing in June 1981, after completion of tailings Cell 1. Between around May 1980 and June 1981, laboratory wastes were discharged to the Former Office Leach Field. Some nitrogen may therefore have been discharged to the Former Office Leach Field prior to June 1981. In addition, potential leaks or breaches in the lab drain system could also theoretically be a potential source of groundwater nitrogen, in part due to the sheer number of different types of nitrogen compounds they may have transported. However, the mass of nitrogen contained in the small volumes of bottled reagents and process samples in the labs, even if their contents entered the drains in their entirety, are likely too insignificantly small to account for the observed nitrate plume. Furthermore, the Mill’s laboratory is located downgradient of TW4-25 and the upgradient boundary of the nitrate plume. Therefore, the labs are a relatively low-priority source. Tailings The Mill’s tailings cells contain nitrogen in both the ammonia and nitrate forms. Mill tailings solutions have been sampled from time to time over the Mill’s history. Care must be taken in interpreting sample results, because the concentrations of analytes in tailings solutions can vary significantly from one sample event to another, depending on: • whether or not the Mill is operating, • whether or not it is re-circulating tailings solutions into the process or adding fresh water to the process, and 17 • the extent to which evaporation or rainfall have affected concentration or dilution prior to sampling. The Statement of Basis for the Mill’s GWDP reports that sample data from September 1980 through March 2003 showed a range for nitrite /nitrate in the Mill’s tailings solutions of 17.0 mg/L to 49.2 mg/L, with an average of 30.91 mg/L. Recent sample results obtained in August 2009 show concentrations of nitrite and nitrate in the solutions in the slimes drain for Cell 2 of 38 mg/L that are consistent with these historic results. The average concentrations for nitrite and nitrate in the pond solutions in Cells 1 and 3 were 254 mg/L and 102 mg/L, respectively, which are somewhat higher than those historic numbers, possibly demonstrating the results of evaporation in those ponded areas prior to sampling. The presence of nitrate, as well as ammonia, in the Mill’s tailings is reasonable and expected for the reasons discussed above, and summarized here: • The Mill uses ammonia and amine nitrogen in several locations in the process and re-circulates solutions of these materials to the tailings system – yielding large masses and concentrations of ammonia nitrogen in tailings; • The Mill introduced nitrate nitrogen, albeit for a finite period of two years, into the uranium circuit and ultimately to the tailings system – yielding smaller masses and concentrations of nitrate nitrogen in tailings; and • Other sources of nitrogen (such as fly ash ) and surface runoff containing nitrogen compounds, were exposed to atmospheric oxidizing conditions before they were transferred to tailings – yielding smaller masses and concentrations of nitrate nitrogen in tailings. As a result, it is reasonable to expect and detect both a low level of nitrate and a higher level of ammonia nitrogen in the tailings. As discussed above, in biotic systems, ammonia nitrogen is readily converted to nitrite and nitrate. In abiotic (non-living) systems, such as the tailings, this is not the case. Ammonia nitrogen is soluble and stable in water in a non-living, non-oxidized system. It remains in water in either ionized or unionized form, switching easily between the two, depending on the pH of the solution. In aqueous systems with high pH, ammonia remains in the non-ionized NH3 form. At neutral pHs and in low pH (acidic) systems such as tailings, ammonia is present primarily in the ammonium ion form (NH4+). In the abiotic, hot, acidic, low-oxygen, nutrient- and microbe-deficient environment of the tailings solutions, ammonia nitrogen is not converted to nitrate (however, nitrate that enters the system as nitrate remains as nitrate). Like abiotic aqueous systems, groundwater also does not normally exhibit either the aggressive chemical oxidizing or biologically enzyme-catalyzed conditions to convert ammonia nitrogen into nitrite/nitrate. Hence, ammonia nitrogen that reaches groundwater directly through failure of surface impoundment or structure liners, which has not been exposed to atmospheric oxygen and bacteria before reaching groundwater, generally 18 would be expected to remain and be detected as ammonia or ammonia nitrogen, not nitrate/nitrite, in groundwater. In order for an ammonia nitrogen source to appear in groundwater as nitrate, it would need to reach groundwater via a surface spill in which it would have time to be converted to nitrate by chemical or biological processes before reaching groundwater. Because the Mill’s tailings contain nitrate, the tailings cells are included here as a potential source of nitrate in groundwater. However, given that: • recent studies have indicated that the Mill’s tailings cells are not leaking , (including the July 2007 Hurst and Solomon Mill sampling event summary, the INTERA Revised Background Groundwater Quality Report, November 2007 INTERA Revised Evaluation of Pre-Operational Background Data, and the April 2008 INTERA Revised Background Groundwater Quality Report). • the nitrate plume has been detected in high concentrations in TW4-25, which is almost a quarter of a mile upgradient of the Mill’s tailings cells; • There appears to be no groundwater mounding under the tailings cells (see Figure 2 from the Stewart report), it would appear that although the Mill’s tailings cells are a potential source of the nitrate contamination, they are not a likely source of the contamination and should not be given a high priority in the Sample Plan. Other Surface Disposal Areas During the Mill’s earlier history, the site contained a short-lived landfill for non- contaminated Mill solid wastes. The landfill received non-hazardous debris and office trash until it was shutdown in approximately 1982. All of the contents of that landfill were excavated and disposed of in the solid waste disposal area of tailings Cell 2. The location of this landfill is indicated on Figure 3. While the landfill may have contained nitrogen-bearing compounds from food waste, soap containers, and organic garbage, it would have been present at minutely low levels. Unless chemical materials or sewage related solids were inadvertently placed there, it is unlikely that the former landfill could pose an important source for the groundwater nitrate plume, and should not be given a high priority in the Sample Plan. Historic Pre-Mill Sources Prior to construction of the Mill and related facilities, the Mill property was privately owned and was used for cattle grazing. A barn and corral were located in the area close to the current dike between Cell 1 and Cell 2, west of monitoring well TW4-24. Also, a stock watering pond (the “Historic Pond”) was located northwest of the Mill’s administration building, where the Mill’s sulfuric acid tank is currently located. There 19 was no irrigation or agriculture on the land. An aerial photo depicting the land use prior to construction of Mill facilities is attached as Figure 5. The Historic Pond was dammed and put in place many years prior to construction of the Mill. In fact, it had the recognition of being the first dam built in Utah by a gas-powered tractor, so it probably dates back to approximately the 1920s. The Historic Pond was displaced by Mill facilities when the Mill was constructed. The main sulfuric acid tank at the Mill is currently located on the site of the former Historic Pond. Many years of livestock watering at the Historic Pond could have contributed significant amounts of nitrate to the local soils and the pond. Pooled water in the pond could have provided a sufficient head to drive this nitrate to groundwater. As the Historic Pond is a reasonable source of nitrate over many years, and is located upgradient of the nitrate plume, it should be given a priority in the Sample Plan. It is also possible that the historic barn and corral could have been a source of nitrate at the site. However, in the absence of standing water at that location, it is not likely that such a source could have impacted groundwater. Also, the location of this potential source is downgradient of the upgradient boundary of the current nitrate plume. For these reasons, this potential historic source of nitrate should not be given a high priority in the Sample Plan. 4.2 Offsite Sources The Mill is located south of Blanding, Utah in a rural agricultural region of the state. Land uses proximal to the Mill include farming, ranching, cattle grazing, feed and grain silos, and the municipal wastewater treatment plant that serves Blanding and some of the surrounding area. A substantial number of farms and ranches are likely not connected to the municipal treatment facility and likely use septic systems for domestic sewage. Direct fertilization with swine or cattle manure is also still practiced in rural Utah. The town of Blanding, population 3,162 (2000 census), is approximately 5 miles north- northeast of the Mill boundary. One potential offsite source of nitrate is the management of livestock on properties adjacent to the Mill’s restricted area, which are subject to cattle grazing leases. Such cattle use the wildlife ponds for drinking water, and may have contributed nitrate to the wildlife pond area. However, any addition of nitrate into the wildlife ponds from livestock would be commingled with, and minimal compared to, the addition of nitrate into the wildlife ponds from the Frog Pond waters. Therefore there is no need to perform any additional investigations relating to livestock influences at the wildlife ponds. If the wildlife ponds are determined to be the source of the nitrate plume, then it would be reasonable to assume that the nitrate in the wildlife ponds could have originated from a combination of the Frog Pond Water and these livestock activities. It should be noted that nitrate in surface waters, estuarine, riparian, and humic surfaces is a plant nutrient (hence the widespread use of nitrate fertilizers in agriculture). Nitrate in these environments will be uptaken and converted by terrestrial and aquatic plants, 20 plankton, and algae in a cycle over time (nitrates are stable and non-volatile so they do not vaporize directly to air from aqueous solutions). The total nitrate mass in such a system is re-distributed among the sediments and precipitates, benthic materials, aquatic plants and microorganisms, terrestrial plants and microorganisms, and macro-organisms in the system in a cycle, whether the nitrate entered the system through aqueous transport or soil deposition. Therefore the wildlife ponds could once have exhibited higher concentrations of nitrate and been the source or contributor to a nitrate plume, even though the current water in the wildlife ponds does not presently demonstrate high concentrations of nitrate Although this study did not include a rigorous itemization of all regulatory-listed sites or contamination sources upgradient and side gradient of the Mill, overall, there are many potential past and ongoing agricultural and domestic sources that may also affect the nitrogen balance in groundwater entering the Mill boundary. However, because upgradient monitoring wells MW-1, MW-18, and MW-19 do not indicate high concentrations of nitrate, it is unlikely that any of these offsite sources are a continuing source of the nitrate contamination. While it is possible that agricultural practices on neighboring properties that occurred at some time in the past (but which no longer occur) could have contributed a slug of nitrate contamination to groundwater that has passed by the upgradient monitoring wells and that now forms the nitrate plume at the site, this would appear to be unlikely and should not be a high priority in the investigation. 5.0 Potential Sources of Groundwater Chloride For the discussion in the following section, it should be noted that, like the nitrate plume, the chloride plume appears to originate to the northwest end of the Mill property, generally upgradient of the tailings area, the Mill process buildings, and the outdoor chemical storage areas. 5.1 On-Site Sources at the Mill Processing and Laboratories As indicated in my evaluations of alternate feed characteristics, alternate feed materials have never been an appreciable source of chloride compounds, never exhibiting more than ppm levels in finite volumes of materials that have either been stored in closed containers or have remained on the ore pad less than a few months before processing. Based on this history, chloride introduction into the Mill groundwater was likely independent of the alternate feed program. Table 3c lists chloride-bearing chemicals used in the Mill operations. Sodium chloride is stored as bulk salt and used in regeneration of ion exchange resins in the uranium recovery circuit. Sodium chlorate is stored in two fiberglass tanks (17,700 gallons and 10,500 gallons) within a dike east of the solvent extraction building. Other inorganic chlorine compounds including sodium perchlorate, sodium hypochlorite, calcium hypochlorite, and hydrochloric acid are stored in the tank farm or storage dike areas for 21 use throughout the process. Smaller quantities of inorganic and chloro-organic compounds such as Ajax, bowl cleaner, and PVC cements are stored and used in the Mill building and shops. Based on information from Mill personnel, there has been no history of failures or upsets of the storage tanks, drums, or powder containers of the liquid or solid materials in the tank farm or in transfer to the Mill buildings. Although the salt storage area contains a large volume of sodium chloride, spills of this material is too finite a phenomenon to account for an ongoing plume by itself, as are sodium chlorate spills from the tank dikes outside the solvent extraction tank area. There is no history of spills or upsets of the chlorine tank system. If an upset were to occur in this system it would, in any case, generate primarily a gaseous emission, not a liquid or solid discharge to the tank farm pads and berms. The only potential ongoing source within the current Mill operations is theoretically the vanadium and/or uranium circuit floor drain systems. As discussed above, the types of activities that transfer chloride solutions to the floor drains are ongoing and can be relatively frequent during operational periods, however, at the current time, there is no reason to expect that there are breaches or breaks in the floor drains or the tailings transfer lines. More importantly, all of the process circuits, floor drains and sumps are located downgradient of TW4-25 and the upgradient boundary of the chloride and nitrate plumes, and as a result, cannot be the primary source of the groundwater contamination. Table 3d lists chloride-bearing chemicals used and stored in small quantities in the Mill’s on-site chemical and metallurgical laboratories. The laboratories stored and used small (from 100ml vials to kilogram and liter quantities) of ammonium chloride and chlorine- containing color indicators. However, the mass of chlorides contained in the small volumes of bottled reagents and process samples in the labs, even if their contents entered the laboratory drains in their entirety, are likely too insignificantly small to account for the observed chloride plume. Furthermore, the Mill’s laboratory is located downgradient of TW4-25 and the upgradient boundary of the chloride plume. Therefore, the labs could be considered only a relatively low-priority source. While there exist a number of different nitrogen-bearing and chloride bearing chemicals at the Mill, the only single compound containing both a nitrogen and chloride source is ammonium chloride. Ammonium chloride is stored in reagent bottle quantities in the laboratory, and has never been inventoried in bulk quantities anywhere on site. Its presence in the laboratory and occasionally in the laboratory drain system is not sufficient to explain ongoing and coincident plumes of nitrate and chloride. Tailings The single largest mass of chloride in the Mill is the tailings system. USDOE data for mills operating in the Moab area on Colorado Plateau ores indicates that tailings cell chlorides average 310 mg/L. Data on Cell 3 indicate chloride levels from 3,191 mg/L 22 (Titan Enviornmental studies 1994) to 30,600 mg/L (Hazen studies 2001). Nitrate content was not analyzed during these studies. If a source the size of the 3 million gallon Cell 3 impoundment were continuously leaking a solution of these levels of chlorides, it could potentially produce or contribute to an appreciable chloride plume. However, the Mill tailings system is not likely a primary source of chloride for two reasons. First, if the tailings system were leaking at an appreciable rate, there would be a sizeable hydraulic mound under the tailings cells and chloride would not be the only ion detected in a measurable plume. That is, other tailings constituents would be detected as well. Second the plumes in question originate in the northeast corner of the site, and the tailings system is side-gradient, and down-gradient of the majority of the affected wells. 5.2 Off-site Sources Table 2b provides a summary of industrial, commercial, agricultural and municipal sources of chloride compounds from which potential candidate sources for the Mill chloride can be elicited. Due to the large number of synthetically created chlorinated species in modern use, the table summarizes and addresses classes of chemicals rather than individual compounds. Potential sources proximal to the Mill site are discussed below. The upper section of the table identifies those compounds and classes of materials that could be expected to be present on the Mill site or in the vicinity of the Mill. The lower section completes a broader survey of compounds and sources and indicates why they are not, or are likely not, present at or proximal to the Mill. Sewage Sources As mentioned above, chloride is present in all domestic wastewater and all septic and sewage treatment effluent. In fact, per the McQuillan study, the presence of chloride in nitrate contaminated groundwater is a primary parameter indicating for groundwater nitrate originating from sewage sources. In sewage-related groundwater contamination, groundwater chloride generally increases with nitrate level. In groundwaters affected by septic system effluents, the relationship may be linear, as indicated in the New Mexico studies. In surface waters receiving municipal treated sewage effluent, the relationship varies with both treatment plant factors and receiving water factors, but still increases with nitrate level. Sewage sources are the most likely explanation for the coincident chloride and nitrate plumes for several reasons. As discussed above, the coincident plumes appear to originate northwest and upgradient of the Mill’s tailings, processing and storage areas. The major potential source upgradient of the Mill is the Blanding POTW effluent discharge system that reaches the Frog Pond, the Upper Wildlife Pond, Lawzy Lake, and the Lawzy Sump. As evidenced by anecdotal information specific to the plant, it has had multiple upsets that could have discharged sludge-bearing liquids to the ditches and ponds upgradient of the site. As indicated in the technical literature on sewage treatment plants from its time period, it very likely discharged both high nitrate and high chloride loaded waters even in non-upset conditions. As evidenced by Mill operating history, 23 these wastewaters were transported on-site to the Mill for use as makeup water for the leach circuit into the early 1990’s. Moreover, the POTW effluent was a continuous source at one time. Unlike the Mill chemical inventories, which are stored in finite quantities and can reach the environment primarily by finite spills, the POTW effluent continually “recharges” the pond and ditch systems upgradient of the identified plumes. However, management practices at the POTW may have changed, and nitrate and chloride concentrations in effluent may have decreased over time. This could have resulted in a “sludge flow” effect in the vicinity of the site. Agricultural Sources In rural, non-industrial environments, the uses of inorganic chloride salts outweigh synthetic organic chloride chemicals. Primary uses include road and surface de-icing, water softening, septic system odor control, salt licks, meat curing and preserving, and disinfectants in dairies and slaughter areas. Recent data from the middle Rio Grande Valley indicate that the highest ratios of chloride to nitrate are generated in plumes from dairies (likely a combination of nitrogen from cattle wastes and chlorine from dairy surface disinfection). To a lesser degree, some organic chlorides are still applied in agricultural areas in the form of pesticides, herbicides, and grain and legume silo fumigants Per the pre-operational baseline information for the Mill site, the site was used as ranchland prior to construction of the Mill. The exact nature of historic operations is unclear, that is, it is not known whether the ranch supported dairy cattle or beef cattle, fertilized and grew feed and fodder of any type, maintained deer and cattle salt licks, drained slops from slaughtering, or cured slaughtered meat, as well as where on the site each activity occurred, and when the activity ceased. Hence it is plausible, but cannot be confirmed, that on site agricultural activities using chloride salts, or generating chloride byproducts and nitrogen wastes occurred. Industrial Sources The Blanding area and southeastern Utah in general are notable for their lack of chemical production and heavy chemical use industries. None of the industrial processes that use chlorine or chlorinated compounds as reagents, solvents or intermediates are present on or near the Mill area. The presence of synthetic chloro-chemical sources in the region can be assumed to be limited to small quantities of cleaners and solvents in homes, ranches and farms, dry cleaners, and machine maintenance shops. With the exception of the agricultural uses described in the paragraphs above, these uses are likely either too small or too remote to have an appreciable effect on Mill site groundwater. 24 6.0 Conclusions Based on the foregoing information, it can be concluded that: There are several reasonable potential sources for nitrates in Mill groundwater: • The septic leach fields at the site; • The municipal sewage plant discharge water used historically as Mill water makeup; • Livestock activities at the wildlife ponds; • Livestock activities at the Historic Pond; • The former Fly Ash Pond; • Potential historic spills of ammonia-bearing process chemicals; • Potential breach in the vanadium circuit floor drains or tailings transfer lines; and • A potential leak in the Mill’s tailings cells. There are several plausible sources for chloride in Mill groundwater: • The septic leach fields at the site; • The municipal sewage plant discharge water used historically as Mill water makeup; • Potential historic spills of chloride-bearing process chemicals; • A potential leak in the Mill’s tailings cells. • Agricultural/ranching activities on the site prior to Mill operations. To date, the nitrate and chloride plumes have been identified to extend upgradient of TW4-25, and to the northeast boundary of the Mill property. Of the potential sources listed above, the only ones that originate upgradient of TW4-25 are: 1. the waters from the Frog Pond, the Upper Wildlife Pond, Lawzy Lake and the Lawzy Sump, including potential livestock activity near the wildlife ponds; 2. possible livestock activity near the Historic Pond; and 3. possible influences from septic leach fields at the site, in particular the SAG Leach Field and the Main Leach Field. The other on-site potential sources would not appear to be able to explain the nitrate and chloride contamination in TW4-25 or further upgradient. In addition, contamination due to spills would appear to be too small and infrequent to give rise to the identified plumes, and there is no apparent reason to expect a breach in process facilities and drains that would give rise to the plume. Based on the currently available process and historic information, the most plausible source for apparently coincident chloride and nitrate plumes would be a chlorinated sewage-based source north or northwest of the Mill. 25 Jo Ann Tischler Consulting Chemical Engineer cc: David C. Frydenlund Steven D. Landau Harold R. Roberts Ron F. Hochstein Enclosures: Attachments 26 References 1. Austin, George T. Shreve’s Chemical Process Industries. Fifth Edition. New York. Mc-Graw-Hill. 1984. 2. Davidson, Robert. Nitrogen in Coal. Center for Applied Energy Research. January 1994. 3. Haber, Fritz. The Synthesis of Ammonia from Its Elements. Nobel Prize Lecture June 2, 1920. 4. Metcalf and Eddy, Inc. Revised by George Tchobanoglous. Wastewater Engineering: Treatment, Disposal, Reuse. Second Edition. New York. McGraw-Hill. 1979 5. McQuillan, Dennis. Ground-Water Quality Impacts from On-Site Septic Systems. Proceedings, National Onsite Wastewater Recycling Association, 13th Annual Conference. Albuquerque. November 2004. 6. Sax, N. Irving, and Lewis, Richard J. Sr. Editors. Hawley’s Condensed Chemical Dictionary, Eleventh Edition. New York. Van Nostrand Reinhold Company. 1987 7. Trattner, Richard et.al. Water Quality in a Recovering Ecosystem. Newark. New Jersey Institute of Technology. 1978 8. United Kingdom, Department of Environment, Food and Rural Affairs. Nitrogen Dioxide in the United Kingdom. Accessed October 27, 2008 at http://www.defra.gov.uk/environment/airquality/publications/nitrogen- dioxide/nd-chapter2.pdf 9. US EPA. Consumer Factsheet on: Nitrates/Nitrites. Accessed October 15, 2008 at http://epa.gov/volunteer/stream/vms57.html 10. US EPA. Monitoring and Assessing Groundwater Quality 5.7 Nitrates. Accessed October 15, 2008 at http://epa.gov/safewater/dwh/c-ioc/nitrates.html 11. US EPA. Technical Factsheet on: Nitrate/Nitrite. Accessed October 15, 2008 at http://epa.gov/safewater/dwh/c-ioc/nitrates.html 12. U.S.Geological Survey. BASIN: General Information on Nitrogen. Accessed October 10, 2008 at http://bcn.boulder.co.us/basin/data/NUTRIENTS/info/NO3+NO2.html 27 28 13. U.S.Geological Survey. USGS Nitrate Study Shows Water Supply Threatened from Residential Septic Systems. Accessed October 28, 2008 at http://www.usgs.gov/newsroom/article.asp?ID=1816             Tables Sludge Table 1: Nitrogen from Sewage Sources Sewage Plant Inf (liquid) luent Sewage Plan Sludge t Primary s Sewage Plant Pri Sewag mary Sludges Sewage Plant Digested e Plant Digested Sludge Rang (mg/L ppm) e or Me (mg pp an /L or m) R (pe ange rcent) (p Typical ercent) Range (mg/L or ppm) Typical mg/L or ppm) Rang (perce e nt) Typica (percen l t) Range (mg/L or ppm) Typical (mg/L or ppm) Organic N 8 to 35 21.5 --- --- --- --- --- --- --- --- Free Ammonia 12 to 50 31 --- --- --- --- --- --- --- --- Nitrite 0 0 --- --- --- --- --- --- --- --- Nitrates 0 0 --- --- --- --- --- --- --- --- Total N 20 to 85 52.5 1.5 to 6.0 2.0 15000 to 60,000 20,000 1.6 to 6.0 4.0 16000 to 60,000 40,000 Source: Metcalf & Eddy. Wastewater Engineering Treatment/Disposal/Reuse Second Edition Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Adogen 283, 382, 2364, 2382 Fabric softeners,ore separation, detergents, corrosion inhibitors, bactericides, inks, antislip agent, waterproofing, chemical intermediates. Yes. Process reagent. Yes None identified. Aluminum nitrate Yes. Process reagent. Yes None identified. Ammonia and ammonium hydroxide As a fertilizer or in synthesis of fertilizer compounds. Manufacture of nitric acid, hydrazine hydrate, hydrogen cyanide, urethanes, acrilonitriles, fuel cells. Used as refrigerant, in nitriding steel, developing diazo films, dyeing, as a condensation catalyst, yeast nutrient, latex preservative, neutralizer in the petroleum industry. Used in synthesis of synthetic fibers, urea formaldehyde, nitroparaffins, melamine, ethylenediamine, rocket fuel. Yes. Anhydrous used in vanadium circuit and yellowcake precipitation. Yes Wastewater plant and sludge overflow, agricultural sources. Ammonio-cupric sulfate (ammoniated copper sulfate) Calico printing, manufacture of copper arsenate, insecticide, fiber treatment. No. None of these processes are present at the Mill. Yes Possible. Agriculural sources. Ammonium Possible AgriculturalAmmonium dimethyldithiocarbamate Fungicide Not used at the Mill. Yes Possible. Agricultural sources. Ammonium dinitro-o- cresolate Herbicide Not used at the Mill. Yes Possible. Agricultural sources. Ammonium linoleate Emulsifier for oils, waxes, hydrocarbon solvents, detergents, water-repellants, surface tension reducer. No. None of these processes are present at the Mill. Yes Wastewater plant and sludge overflow. Ammonium nitrate NH4NO3 Fertilizer, explosives, pyrotechnics, herbicide, insecticide, synthesis of nitrous oxide, solid rocket proellant, freezing mixtures, nutrient for antibiotic and yeast synthesis. Possibly. 1. Trace quantities only in ore. 2. Trace quantities only in lawn care and topsoil fertilizing. Yes Wastewater plant and sludge overflow, agricultural sources. Ammonium polyphosphate (urea ammonium polyphosphate) Liquid fertilizer. Possibly. Yes Wastewater plant and sludge overflow, agricultural sources. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonium sulfate (NH4)2SO4 Fertilizers, water treatment, fermentation, fireproofing compounds, viscose rayon, tanning, food additive. Yes. Used in vanadium precipitation. Yes Possible. Agriculural sources. Ammonium vanadate (ammonium metavanadate) Catalyst as vanadium pentoxide, dyes, varnishes, indelible inks, drier for inks and paints, photography, analytical reagent. Yes. Intermediate in vanadium circuit. Yes. None identified. Ammonium chlorate Explosives. Yes. Possibly trace levels in ores. Yes None identified. Barbituric Acid Indicator, dyes, polymerization agent, pharmaceuticals Yes. Lab reagent. Yes. None identified. Barium diphenylamine sulfonate Separation agent Yes. Process and lab reagent. Yes. None identified. Brucine sulfate Separation agent Yes. Lab reagent. Yes. None identified. Calcium ammonium nitrate CaNH4NO3 As 60% ammonium nitrate, 40% limestone in fertilizers Possibly. Trace quantities only in lawn care and topsoil fertilizing. Yes Wastewater plant and sludge overflow, agricultural sources. Calcium nitrate Ca(NO3)2.H2O Saltpeter. Pyrotechnics, explosives, matches, fertilizers, preparation of C-14 for nuclear irradiation. yq only in ore. 2. Trace quantities only in lawn care and topsoil fertilizing.Yes Wastewater plant and sludge overflow, agricultural sources.Ca(NO3)2 H2O nuclear irradiation.fertilizing.Yes agricultural sources. Cationic polyacrylamides Thickening agent, suspending agent, adhesive additive, food additive. Yes. Process reagent. Yes. None identified. Coal and coal combustion products Formerly widely used in utility, industrial and residential heaters, boilers, and direct firing. Historically, destructive distillation of coal was significant source of coal tar compounds, ammonia nitrogen, pharmaceutical, and other organic compounds. Used as source of coke for iron and steel manufacture, synthetic fuels, oils, synthesis gas (CO and H2). Yes. Former coal fired burners and coal flyash pond near process buidlings. Yes None identified. Dicapthon (CH20)2P(S)OC6H3(Cl)NO3 Insecticide No. Not used at Mill. Yes Wastewater plant overflow, wastewater sludge overflow, agricultural sources. Dipyridyl a Reagent for iron determination Yes. Lab reagent. Yes. None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Hydrazine Rocket fuel, oxygen scavenger in boiler water treatment. Yes. Small quantities in drummed solutions used in boiler area. Sulfate form used in lab. Yes None identified. Nitrites Corrosion inhibitors in boilers and process water treatment. Yes. Low levels in boiler area. Yes None identified. o-Nitrobiphenyl/nitro diphenyl Dyes, fungicide, plasticizer for cellulose, wood preservative, No. None of these processes are present at the Mill. Yes Wastewater plant overflow, wastewater sludge overflow, agricultural sources. Nitrofuran (furazolidone) Former antibiotic drug for cows. No. Not used at Mill. Yes Possible. Agricultural sources. Nitrofurantoin Antibacterial agent. No. Not used at Mill. Yes Possible in wastewater plant overflow, wastewater sludge overflow. Nitroglycerin Explosives, medicinals. Yes. Possible trace levels inores. Yes None identified. Nitro toluenes (mono, di and tri) Explosives, urethane synthesis, organic synthesis, toluidines, dyes. Yes. Possible trace levels in ores. Yes None identified. Whfl Other organo amines Water treatment, enhancement of solvent extraction Yes, Used in Mill's SX circuit. Yes None identified. Other organo ureas, amino acids, proteins Ubiquitous in human waste, animal waste, food decomposition, domestic sewage. Yes. In leach fields, sewage sludge overflow ponds. Yes Wastewater plant overflow, wastewater sludge overflow, agricultural sources. Potassium nitrate KNO3 Pyrotechnics, explosives, matches, fertilizer, meat curing, tobacco, glass manufacture, tempering steel. Possibly. 1. Trace quantities only in ore. 2. Trace quantities only in lawn care and topsoil fertilizing. Yes Wastewater plant overflow, wastewater sludge overflow, agricultural sources. Potassium thiocyanate Manufacture of sulfocyanides, thioureas, textile dyeing, photofinishing, dyestuffs, medicine. Yes. Process and lab reagent. Yes None identified. Silver Nitrate Photofilm, catalyst for ethylene oxide, silverpalting, inks, mirror plating, hair dye, germicide, antisepic and cauterizing agent, lab reagent. Yes. Process and lab reagent. Yes None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Sodium nitrate NaNO3 Solid rocket fuel, fertilizer, solder flux, glass manufacture, refrigerant, matches, dynamite and gunpowder, pharnaceuticals, aphrodisiac, color fixative/preservative for meat and fish, enamel for pottery, tobacco products. Yes. Process and lab reagent. Also possibly in fertilizer. Yes Wastewater plant overflow, wastewater sludge overflow, agricultural sources. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonio ferric sulfate (ferric ammonium sulfate) Medicine, textile dyeing. No. None of these processes are present at the Mill. NA None identified. Ammonium acetate Analytical reagent, drugs, textile dyeing, meat preserving, foam rubber, vinyl plastics, explosives. No. None of these processes are present at the Mill. NA None identified. Ammonium benzene sulfonate Igniter, chemical synthesis. No. None of these processes are present at the Mill. NA None identified. Ammonium benzoate Medicine, latex preservative. No. None of these processes are present at the Mill. NA None identified. Ammonium bicarbonate Production of ammonium salts, dyes, leavening for cookies, crackers, pastry dough, fire extinguishers, pharmaceuticals, foam rubber blowing, boiler scale removal, compost treatment, degreasing textiles., No. None of these processes are present at the Mill. NA None identified. Ammonium bifluoride Ceramics, reagent, glass etching, laundry sour, brewery and dairy sterilizer, beryllium electroplating. No. None of these processes are present at the Mill. NA None identified. Analytical reagent, ink removal from No. None of these processes Ammonium bioxalate yg, fabrics. p are present at the Mill. NA None identified. Ammonium bisulfate Catalyst in organic synthesis, permanent wave hair solutions. No. None of these processes are present at the Mill. NA None identified. Ammonium bitartrate Baking powder. No. None of these processes are present at the Mill. NA None identified. Ammonium borate Fireproofing compounds, electrical condensers, herbicide. No. None of these processes are present at the Mill. NA None identified. Ammonium bromide Photographic silver precipitation, medicine, engraving, textile finishing, fire retardant, anticorrosive agents, analytcial chemistry. No. None of these processes are present at the Mill. NA None identified. Ammonium cadmium bromide (cadmium ammonium bromide) Plating and preparation of metals. No. None of these processes are present at the Mill. NA Agricultural sources. Ammonium caprylate Pesticide, photo emulsions, chemical intermediate. No. None of these processes are present at the Mill. NA Agricultural sources. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonium carbamate Fertilizer. No. None of these processes are present at the Mill. NA Agricultural sources. Ammonium carbonate Ammonium salts, medicine, baking powder, smelling salts, fire extinguishers, pharmaceuticals, textiles, wine fermentation, ceramics, wool washing, organic sythesis. No. None of these processes are present at the Mill. NA Agricultural sources. Ammonium chloride Dry batteries, dye and printing mordant, solderflux, synthesis of ammonia compounds, fertilizer, pickling agent in zinc processing, electoplating, washing powders, melt retardant for snow treating, urea formaldehyde resins, bakery products. No. None of these processes are present at the Mill. NA None identified. Ammonium chromate Dye mordant, photogrpahic coatings, anlaytical reagent, catalyst, corrosion inhibitor. No. None of these processes are present at the Mill. NA None identified. Ammonium chromium sulfate (chromium ammonium sulfate) Dye mordant, tanning. No. None of these processes are present at the Mill. NA None identified. Ph i l fi Ammonium citrate Pharmaceuticals, rustproofing, cotton printing, plasticizer, analyzing phosphate in fertilizer. No. None of these processes are present at the Mill. NA None identified. Ammonium cobaltous phosphate (cobaltous ammonium phosphate) Plant nutrient, glass coloring, glazes, enamels, anlaytical chemistry. No. None of these processes are present at the Mill. NA None identified. Ammonium cobalt sulfate Ceramics, cobalt plating, catalyst. No. None of these processes are present at the Mill. NA None identified. Ammonium dichromate (ammoniumbichromate) Dyeing, pigments, manufacture of alizarin, chrome alum, oil purification, pickling, manufacture of catalysts, tanning, perfumes, photography, engraving, lithography, chromic oxide,pyrotechnics. No. None of these processes are present at the Mill. NA None identified. Ammonium dithiocarbamate Synthesis of heterocyclic compounds, anlaytical reagent. No. None of these processes are present at the Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonium fluoride Fluoride synthesis, analytical chemistry, disinfectant in brewing, glass etching, textile mordant, wood preserving, mothproofing. No. None of these processes are present at the Mill. NA None identified. Ammonium fluosilicate Laundry sours, mothproofing, disinfectant in brewing, glass etching, electroplating, light metal casting. No. None of these processes are present at the Mill. NA None identified. Ammonium formate Analytical chemistry for precipitating metals. No. None of these processes are present at the Mill. NA None identified. Ammonium gluconate Emulsifying agent in cheese and salad dressing. No. None of these processes are present at the Mill. NA None identified. Ammonium glutamate (sodium glutamate) Flavor enhancer in foods. No. None of these processes are present at the Mill. NA None identified. Ammonium hexachloro- osmate Plating. No. None of these processes are present at the Mill. NA None identified. Ammonium hexachloroplatinate Plating, platinum sponge. No. None of these processes are present at the Mill. NA None identified. Ammonium hexafluoro germanate Plating. No. None of these processes are present at the Mill. NA None identified. Textiles, rayon, rubber, fertilizers, Ammonium hydroxide y refrigeration, condensation polymerization, photography, pharmaceuticals, soaps, lubricants, fireproofing, ink, explosives, ceramics, ammonium compounds, saponifying fats and oils, detergents, food additives, household cleansers, organic synthesis. No. None of these processes are present at the Mill. NA None identified. Ammonium hypophosphite (phosphine) Organic preparations, doping agent for semiconducors, polymerization initiator, condensation catalyst. No. None of these processes are present at the Mill. NA None identified. Ammonium ichthosulfonate (ichthammol) Pharmaceutical preparations, cosmetic preparations, dermatological soaps. No. None of these processes are present at the Mill. NA None identified. Ammonium iodate Oxidizing agent. No. Mill does not use this oxidizer. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonium iodide Iodides, medicine, photography. No. None of these processes are present at the Mill. NA None identified. Ammonium laurate Production of oil-water emulsions, cosmetics. No. None of these processes are present at the Mill. NA None identified. Ammonium lignin sulfate (lignin sulfonate) Dispersing agent in concrete and rubber mixes, tanning, oil well drilling mud, ore flotation, production of vanillin, industrial cleaners, gypsum, dyes,pesticides. No. Not used in ore flotation at the Mill. None of these processes are present at the Mill. NA None identified. Ammonium molybdate Reagent, pigments, dehydrogenation and desulfurization catalyst in petroleum refining, production of molybdenum. No. None of these processes are present at the Mill. NA None identified. Ammonium-12- molybdophosphate Reagent, ion exchange columns, photographic additive, water resistance additive. No. None of these processes are present at the Mill. Not used in Mill's ion exchange NA None identified. Ammonium-12- molybdosilicate Catalyst, reagent, precipitant and ion exchange mediumin nuclear fuel cycle, photofixing and photo-oxidizing agent, No. None of these processes are present at the Mill. NA None identified. Ammonium nickel chloride Electroplating, dyeing. No. None of these processes are present at the Mill. NA None identified. Ammonium nickel sulfate Electroplating. No. None of these processes are present at the Mill. NA None identified. Ammonium nitroso-b- phenylhydroxyl amine (cupferron) Analytical reagent for separation of metals (coper, vanadium, iron). Not used at the Mill. Yes None identified. Ammonium oleate Emulsifying agent in cosmetics. No. None of these processes are present at the Mill. NA None identified. Ammonium oxalate Analytical chemistry, safety explosives, manufacture of oxalates, rust and scale removal. No. None of these processes are present at the Mill. NA None identified. Ammonium palmitate Thickening agent of rpetroleum-derived solvents and lubricants, waterproofing agent. No. None of these processes are present at the Mill. NA None identified. Ammonium pentaborate Intermediate for boron chemicals, power level controller in nuclear submarine reactors. No. None of these processes are present at the Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonium perchlorate Explosives,pyrotechnics, etching and engraving, analytical chemistry, smokeless rocket and jet propellant. No. None of these processes are present at the Mill. NA None identified. Ammonium permanganate Strong oxidizer. No. Mill does not use this oxidizer. NA None identified. Ammonium perrhenate Mild oxidizer. No. Mill does not use this oxidizer. NA None identified. Ammonium persulfate Oxidizer, bleaching agent, photography, printed circuit board etching, copper,plating, deodorizing and bleaching oils, analine dyes, foodpreservative, washing yeast, depolarizing batteries. No. Mill does not use this oxidizer. None of these processes are present at the Mill. NA None identified. Ammonium phosphate (monobasic, hembasic, dibasic) Wood flameproofing, matches, fertilizer, feed additive, plant nutrient, manufacture of yeast, vinegar, bread, solder flux fortin, copper, brass, zinc, purifying sugar, toothpastes, pH buffer,metal ceaning. No. None of these processes are present at the Mill. NA None identified. Ammonium phosphite Reducing agent, corrosion inhibitor added to lubricants and greases. No. None of these processes are present at the Mill. NA None identified. Ammonium No. None of these processes phosphotungstate Chemical reagent, ion exchange media. p are present at the Mill. NA None identified. Ammonium picrate Pyrotechnic, explosives. Possibly traces in ore. Yes None identified. Ammonium polymanuronate (ammonium alginate) Thickening agent and food stabilizer. No. None of these processes are present at the Mill. NA None identified. Ammonium polysulfide Analytical reagent, insecticide. No. None of these processes are present at the Mill. NA None identified. Ammonium selenate Mothproofing. No. None of these processes are present at the Mill. NA None identified. Ammonium selenite Alkaloid testing, glass coloring. No. None of these processes are present at the Mill. NA None identified. Ammonium stearate Vanising creams, shaving cream, cosmetics, waterproofing of cements, concrete, stucco, paper, textiles. No. None of these processes are present at the Mill. NA None identified. Ammonium sulfamate Flameproofing of textiles and paper, weed and brush killer, electroplatin, production of nitrous oxide. No. None of these processes are present at the Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonium sulfate nitrate Strong oxidizer. No. Mill does not use this oxidizer. NA None identified. Ammonium sulfide Textiles, photo developer, brass and bronze coloring, soda ash production, synthetic flavors. No. None of these processes are present at the Mill. NA None identified. Ammonium sulfite Chemical intermediate, medicine,permanent wave solutions, photography, metal lubricant. No. None of these processes are present at the Mill. NA None identified. Ammonium sulforicinoleate Medicine, furniture polish. No. None of these processes are present at the Mill. NA None identified. Ammonium tartrate Textiles, medicine. No. None of these processes are present at the Mill. NA None identified. Ammonium tetrathiocyanodiammono chromate (Reinecke salt) Precipitating agent for organic bases in pharmaceuticals, amines,amino acids, mercury. No. None of these processes are present at the Mill. NA None identified. Ammonium tetrathiotungstate Producing high purity tungsten disulfide for catalysts, lubricants, semiconductors. No. None of these processes are present at the Mill. NA None identified. photography, freezing solutions, rocket propellants, zinc coating, weed killer, soil sterilization, defoliant, iron pickling, Ammonium thiocyanate sterilization, defoliant, iron pickling, electroplating, polymerization catalyst, separator for gold, iron, hafnium, zirconium. No. None of these processes are present at the Mill. NA None identified. Ammonium thioglycolate Hair waving, hair removal. No. None of these processes are present at the Mill. NA None identified. Ammonium thiosulfate Photographic fixer, reagent, fungicide, reducing agent, silverplating, zinc and metal casting cleaner, fog screens, hair waving solutions. No. None of these processes are present at the Mill. NA None identified. Ammonium titanium oxalate Cellulose and leather dyeing. No. None of these processes are present at the Mill. NA None identified. Ammonium tungstate Preparation of tungsten compounds. No. None of these processes are present at the Mill. NA None identified. Ammonium valerate Flavoring material No. None of these processes are present at the Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Ammonium zirconifluoride (zirconium ammonium fluoride) Chemical reagent. No. None of these processes are present at the Mill. NA None identified. Ammonium zirconyl carbonate Water repellant for paper and textiles, catalyst, latex paint stabilizer, floor wax additive, glass fiber fabrication. No. None of these processes are present at the Mill. NA None identified. Ammonobasic mercuric chloride (ammoniated mercury) Topical germicide, medicines. No. None of these processes are present at the Mill. NA None identified. Amobarbitol Medicine, pharmaceutical, hypnotic. No. None of these processes are present at the Mill. NA None identified. Aniline Dyestuffs, rubber accelerators and antioxidants, shoe polish, photographic chemicals, isocyanates for urethanes, explosives, petroleum refining, synthesis of pharmaceuticals, phenolics, herbicides, fungicides. No. None of these processes are present at the Mill. NA None identified. Beryllium nitrate BeNO3 Oxidizer No beryllium oxidizers used in Mill circuit. NA None identified. Auto lacquers, explosives, collodion for Cellulose nitrate/nitrocellulose q,p , wound dressing and gun cotton, rocket fuel, printing ink, bookbinder's cloth, leather finishing, celluloid film, flashless powder. No. None of these processes are present at the Mill. NA None identified. Ceric ammonium nitrate Oxidant for organic compounds, azide manufacture, polymerization catalyst for polyolefins. No. None of these processes are present at the Mill. NA None identified. 4-Chloro-3-nitrobenzenoic acid Dyes, perfumes, flavors, pharmaceuticals. No. None of these processes are present at the Mill. NA None identified. 2-Chloro-3-nitrobenzene sulfonamide Dyes, pharmaceuticals No. None of these processes are present at the Mill. NA None identified. 6-Chloro-3-nitro benzene sulfonic acid sodium salt Dyes, pharmaceuticals No. None of these processes are present at the Mill. NA None identified. 4-Chloro-3-nitro benzoic trifluoride Dyes, synthesis of agricultural chemicals, pharmaceuticals. No. None of these processes are present at the Mill. NA None identified. 4 Chloro -2 nitrophenol Dyes, synthesis of amino chlorophenols No. None of these processes are present at the Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Chromium nitrate/chromic nitrate Catalyst, corrosion inhibitor. No. No catalysts used. No chrome-based inhibitors used. NA None identified. Di-isocyanates Sythesis of urethane plastics and foams, cross-linking agent for nylon. No. None of these processes are present at the Mill. NA None identified. Dinitrogen tetroxide Primarily sythesized as hydrazine oxidizer in rocket fuels. No. None of these processes are present at the Mill. NA None identified. Ferric nitrate Dyes, tanning, analytical chemistry. No. None of these processes are present at the Mill. NA None identified. Lithium nitrate Ceramics, pyrotechnics, salt baths, refrigeration, heat exchange media, rocket propellant. No. No refrigeration fluids or heat exchange salts used at Mill. No other uses at Mill. NA None identified. Magnesium nitrate Pyrotechnics, synthesis of concentrated nitric acid. No. None of these processes are present at the Mill. NA None identified. Manganous nitrate Ceramics, catalyst, chemical intermediate. No. None of these processes are present at the Mill. NA None identified. Manufacture of ammonium nitrate fertilizer, explosives, dyes, drugs, cellulose nitrate, hihilfli No. Leach circuit is based on sulfuric acid, no nitric used. No ore flotation conducted at mill. No spent fuel reprocessing is conducted at the Mill. No other h Nitric acid photoengraving, etching steel, ore flotation, urethanes, rubber, spent nuclear fuel. processes are present at the Mill. NA None identified. Strontium nitrate Oxidizizer, pyrotechnics, railroad flares, matches, marine signals. No. None of these processes are present at the Mill. NA None identified. Thallium Nitrate Analysis, green pyrotechnics No. None of these processes are present at the Mill. NA None identified. Silver nitrate AgNO3 Photofilm, ethylene oxide catalyst, inks, silverplating, mirrors, germicide (wall spray), dyes, antiseptic, wound cauterization, lab reagent. No. None of these processes are present at the Mill. NA None identified. Silver nitrite AgNO2 Alcohol synthesis, preparation of oliphatic nitrogen compounds, standards for water anlaysis. No. None of these processes are present at the Mill. NA None identified. Nitroacetanilide NO2C6H4NHCOCH3 Manufacture of nitroaniline. No. None of these processes are present at the Mill. NA None identified. p-Nitro o-aminophenol O2NC6H4NH2 Dyes. No. None of these processes are present at the Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 m-Nitroaniline Dye intermediate. No. None of these processes are present at the Mill. NA None identified. o-Nitroaniline Dye, synthesis of phtographic antifog, coccidiostats, o-phenylenediamine No. None of these processes are present at the Mill. NA None identified. p-Nitroaniline Dye intermediate, corrosion inhibitors, gasoline gum inhibitors, antioxidants. No. None of these processes are present at the Mill. NA None identified. o-nitroanisole C6H4OCH3NO2 Dyes, pharmaceuticals. No. None of these processes are present at the Mill. NA None identified. p-nitroanisole C6H4OCH3NO2 Dyes. No. None of these processes are present at the Mill. NA None identified. Nitrobenzaldehyde Dyes, pharmaceuticals, surface active agents (surfactants), mosquito repellant, vapor phase corrosion inhibitor. No. None of these processes are present at the Mill. Yes. None identified. Nitrobenzene C6H5NO2 Manufacture of aniline, cellulose eteher solvent, cellulose acetate, metal polish, shoe plish, manufacture of benzidine, quinoline. No. None of these processes are present at the Mill. NA None identified. Nitorbenzene azo resorcinol Determination of magnesium. No. None of these processes are present at the Mill. NA None identified. m-Nitrobenzene sulfonic No None of these processesm-Nitrobenzene sulfonic acid Organic synthesis, anti-reduction agent. No. None of these processes are present at the Mill. NA None identified. 6-Nitrobenzimide azole Photo antifogging agent. No. None of these processes are present at the Mill. NA None identified. Nitrobenzoic acid C6H4(NO2)COOH Dyes, reagent for alkaloids, organic synthesis. No. None of these processes are present at the Mill. NA None identified. m-Nitrobenzoyl chloride Dyes, photochemicals, pharmaceuticals. No. None of these processes are present at the Mill. NA None identified. p-Nitrobenzyl chloride Dyes, photochemicals, intermediate for procaine hydrochloride (novocaine). No. None of these processes are present at the Mill. NA None identified. p-Nitrobenzyl cyanide Dyes, pharmaceuticals, syntheis of p-nitro phenyl acetic acid No. None of these processes are present at the Mill. NA None identified. Nitrobromoform (bromo picrin) Military poison, organic synthesis No. None of these processes are present at the Mill. NA None identified. 2-Nitro, 1-butanol Organic synthesis No. None of these processes are present at the Mill. NA None identified. Nitro carbon nitrate Strong oxidizer. No. Not used at Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 Nitro chlorobenzene (Chloro nitrobenzene) Dyes, parathion manufacture, agricultural chemicals, rubber chemicals. No. None of these processes are present at the Mill. NA None identified. 2-Nitro p-cresol Chemical synthesis intermediate. No. None of these processes are present at the Mill. NA None identified. o-Nitro diphenylamine Chemical synthesis intermediate; stabilizer for nitrogylcerine. No. None of these processes are present at the Mill. NA None identified. Nitroethane Solvent for nitrocellulose, cellulose acetate, dyes, vinyl and alkyd resins, waxes, fats. Used as fuel additive. No. None of these processes are present at the Mill. NA None identified. 2-Nitro-2-ethyl-1,3- propanediol Organic synthesis. No. None of these processes are present at the Mill. NA None identified. Nitrous oxide (N2O or laughing gas) Anaesthetic No. None of these processes are present at the Mill. NA None identified. Picramic acid Azo dye synthesis, reagent for aluminum No. None of these processes are present at the Mill. NA None identified. Picric acid Explosives, matches,electric batteries, etching of copper, textile dyeing. No. None of these processes are present at the Mill. NA None identified. Picrolinic acid Analytical chemistry for estimation of calcium, identification of alkaloids No. None of these processes are present at the Mill. NA None identified. No None of these processes Picrotoxin Medicine fomulations No. None of these processes are present at the Mill. NA None identified. Picryl chloride Explosives No. This type of explosive is not used in mining. NA None identified. Sodium Azide Air bag explosive anisters, preservative for diagnostic medicines, intermediate in explosive manufacture. No. None of these processes are present at the Mill. NA None identified. Toluene diamines Chain extender and cross linker, sythesis of dyes, polymers,polyurethanes. No. None of these processes are present at the Mill. NA None identified. Toluidines (amino toluenes) gy,y,g lignin, reagent for nitrite, vulcanization accelerator. No. None of these processes are present at the Mill. NA None identified. Zirconium nitrate Zr(NO3)2.5H2O Preservative. No. None of these processes are present at the Mill. NA None identified. Zirconium nitride ZrN Crucibles, cermets, refractories. No. None of these processes are present at the Mill. NA None identified. Table 2 Nitrogen Compound Sources Nitrogen Compound or Source1 Uses2,3 Present on Mill Site4 If Present at or Near Mill, Can It Generate Nitrate? Potential Off Site Sources5 NOTES 1. Does not include short-lived intermediates and isotopes, research compounds, and insoluble gases. 2. Many of the compounds below, while not synthesized or used regionally or at the Mill, are present at low levels in domestic products in the Mill offices, kitchen areas, shops, and labs. 3. In some cases, only one entry is given for multiple compounds of the same class and same use. 4. Additional chemicals inventoried from 100 ml to kilogram/liter levels at the laboratories are identifed in Table 3a. 4. Most nitrogen-bearing organic compounds in sewage plant influent will be present in a converted form as nitrate/nitrite in effluent and sludge. Table 2 Nitrogen Compound Sources Chloride Compounds and Classes 1,2,3 Uses2,3 Present on Mill Site4 Present Near Mill Site Potential Off Site Sources 5 chloramines Dye intermediates, disinfectant, oxidizer, Yes Yes As disinfectant in drining water and wastewater treatment plants chlorates and perchlorates pulp bleaching, synthesis of solid rocket propellants, herbicides, defoliants, explosives. Yes No NA chlorine oxides, sodium hypochlorite, calcium hypochlorites Bleach, germicides, sterilants, odor control agents Possibly. At very low levels in cleaning compounds. Yes As disinfectant in drinking water and wastewater treatment plants, Blanding OTW, and upgradient and downgradient septic leach systems. chlorine Reagent in wiide range of organic and inorganic synthesis including polymers, pesticides, herbicides, colors, pharmaceuticals, hydrochloric and inorganic acids, agricultural chemicals, flame retardants. Disinfectant and sterilant. Syntheisi of mace and tear gas. Formerly used in combat gas,defoliants and other chemical weapon formulation. Used as disinfectant in food processing, drinking water, and wastewater treatment. Yes Possibly As disinfectant in drining water and wastewater treatment plants calcium chlorides de-icing (primarily roads and traffic surfaces) Possibly Yes County and/or municipal road de- icing Sodium Chloride Wide range of domestic, agricultural, industrial uses as feed chemical chemical for choralkali production, regenerant for ion exchange resins, dyeing, curing, food preserving, de-icing. Yes Yes Water treatment plants, household water softeners, wastewater treatment, cattle salt licks, road de-icing, meat and game curing. chlorophenols and derivatives Organic synthesis intermediate, dyes, drugs, alcohol denaturants, antiseptics, solvents, insecticides, fungicides No No NA chlorosulfo compounds (inorganic and organic) Detergents, phamaceuticals, intermediates, pesticides, ion exchange resins, smoke-prodcuing chemicals, anhydrous HCl synthesis, rubber-based plastics, rayon, solvents, dehydrating agent, acrylation reactions, chemical No No NA Table 2 Nitrogen Compound Sources Chloride Compounds and Classes 1,2,3 Uses2,3 Present on Mill Site4 Present Near Mill Site Potential Off Site Sources 5 chlorinated aromatic compounds Syntheis of phenols, chloronitroaromatics, aniline, dyes. Carriers for isocyanate production, heat transfer fluid, solvents, pesticide intermediate. No No NA chlorine oxides Bleaching wood pulp, fats and oils, watertreament, odor control, biocides, maturing agents for flour, esterificaton catalysts. No Possibly As disinfectant in drinking water and wastewater treatment plants chloroanilines Pharmaceuticals, syntheis of agricultural chemicals, intermediate for dyes and quinones. No NA chlorofluorocarbons Formerly as refrigerants, aerosol propellants, flame suppressants. No Possibly In finite quantities as refrigerants in air conditioning and chilling systems chlorine, chlorine dioxide, sodium hyprochlorite, calcium hyposchlorite, chloramines, taste control agents potable water treatment No ???? TBD???? chlorocarbons, chloroaromatics, oxychlorinated compounds pesticides herbicides and fumigants No Yes grain silos bean and legume silosoxychlorinated compounds pesticides, herbicides, and fumigants No Yes grain silos, bean and legume silos vinyl chloride and derivatives vinyl, vinylidene, chlorinated olfin polymers and plastics No No NA Table 2 Nitrogen Compound Sources Chloride Compounds and Classes 1,2,3 Uses2,3 Present on Mill Site4 Present Near Mill Site Potential Off Site Sources 5 other inorganic chemical production metal chlorides for catalyst use, acids, plating solutions, printing inks, mirror coatings, ceramic colors. No No NA ethylene dichloride ethylene oxide and propylene oxide production No No NA other chlorinated alkane hydrocarbons epoxies, flame resistant olefins, synthetic caffeine, photography, antifreezes, perfumes. No No NA chlorine, chlorine dioxide and other bleaching agents in paper production pulp and paper No No NA NOTES 1. Chemicals are generally adressed in this table as classes of materials rather than individual compounds. 2. Many chlorinated compounds , while not synthesized or used regionally or at the Mill, are present at low levels in domestic products in the Mill offices, kitchen areas, shops, and labs. 3. Compunds containing both nitrogen and chlorine are addressed in Table 2a. 4. Additional chemicals inventoried from 100 ml to kilogram/liter levels at the laboratories are identifed in Table 3d. Potassium Table 3a Nitrogen Compounds in Mill Operations Inventory Adogen 283 Adogen 382 Adogen 2364 Adogen 2382 Aluminum nitrate solution Anhydrous ammonia Ammonia inhalants Ammonia sulfate Ammonia meta-vanadate Ammonium hydroxide Aqua ammonia Barium diphenylamine sulfonate Cationic Polyacrylamides Silver Nitrate Table 3b Nitrogen Compounds in Laboratory Inventory Amino, 4-amino-1-naphthalane sulfonic acid Hydroxylamine sulfate Ammonium acetate Methyl red Ammonium chloride Methylene blue Ammonium hydroxide Monoethanolamine Ammonium iodide Naphthy, N-(1-naphthy) ethylene-diamine dihydrochloride Ammonium meta-vanadate Nitrazine yellow Ammonium molybdate Nitric acid Ammonium nitrate Nitro-benzene Ammonium oxalate, monohydrate Phenanthroline, 1, 10 Ammonium persulfate Phenanthroline, 1, 10 ferrous sulfate Ammonium phosphate, dibasic Phenanthroline, 1, 10 monohydrate Ammonium phosphate, monobasic Phenyl benzohy, N-phenylbenohy-droxamic acid Ammonium pyrolidine, dithiocarbamateAmmonium pyrolidine, dithiocarbamate Potassium cyanide cyanide Ammonium sulfate Potassium nitrate Ammonium thiocyanate Potassium nitrite Ammonium vanadate Potassium thiocyanate Ammonium chloride Primene, JM-T solvent Barbituric acid Pyridine Brucine sulfate Quinoline Cobalt nitrate Hydroxyquinoline Cupferron Rhodamine Cyclohexanedintrilotetraacetic acid Silver nitrate Diphenylamine sulfonic acid sodium salt Sodium ammonium phosphate Diphenyl, 1,3-diphenyl-1,3-propanedione Sodium cyanide Dipyridyl a Sodiumnitrate Disodium ethylenediamine tetraacetate Sodium nitrite EDTA Sodium thiocyante Ethylenedinitrilo tetraacetic acid disodium salt Sulfanilamide Ethyl, 1-ethyl-2-[(1,4 dimethyl-2-phenyl-6- pyrimidinylidene)-methyl] quinolone chloride Sulfanilic acid Ferric ammonium sulfate Thallic nitrate Hydrazine sulfate Tris (hydroxymethyl) aminomethane Hydroxyquinolone Thorin thorium determination Hydroxylamine hydrochloride Urea Note to Tables 3a and 3b: Nitrogen may also be present in adhesives, cements, hardeners, sufactants, detergents, flocculants, paints and cleaning agents used in lab and mill equipment cleaning, and general maintenance. Ajax Barium chloride Calcium hypochlorite Chlorine Hydrochloric acid Penchlor solution PVC cement Sodium chlorate Sodium chloride (salt) Sodium hypochlorite Sodium perchlorate Tetrachloroethylene Vanish Bowl Cleaner (HCl solution) Ammonium chloride Ethyl, 1-ethyl-2-[(1,4 dimethyl-2-phenyl-6- pyrimidinylidene)-methyl] quinolone chloride Hydroxylamine hydrochloride Methylene blue Table 3c Chlorine Compounds in Mill Operations Inventory Table 3d Chlorine Compounds in Laboratory Inventory Table 4 Nitrate, Chloride and Chlorinated Organics from Quarterly Chloroform Monitoring Report MW-4 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetracilloride Chloride (ugll) (ugll) (ugll) (ugll) (mgll) (mgll) 28-Sep-99 6200 28-Sep-99 5820 28-Sep-99 6020 15-Mar-00 5520 15-Mar-OO 5430 2-Sep-00 5420 9.63 30-Nov-00 6470 9.37 29-Mar-01 4360 8.77 22-Jun-Ol 6300 9.02 20-Sep-01 5300 9.45 8-Nov-01 5200 8 26-Mar-02 4700 8.19 22-May-02 4300 8.21 -"--12-Sep-02 6000 8.45 24-Nov-02 2500 8.1 28-Mar-03 2000 8.3 -30:Apr-03 3300 NA 30-May-03 3400 8.2 23-Jun-03 4300 8.2 30-Jul-03 3600 8.1 --~ ... -. 29-Aug-03 4100 8.4 12-Sep-03 3500 _1l.:.L. . __ .. _---.--------.~-15-0ct-03 3800 8.1 8-Nov-03 3800 8.0 -~~- 29-M.r-04 NA NA "22-Jun-04 NA NA .. _---_ ... -.,-_._------ 17-Sep-04 3300 6.71 17-Nov-04 4300 7.5 16-M.r-05 2900 6.3 25-May-05 3170 7.1 31-Aug-05 3500 7.0 I-Dec-OS 3000 7.0 . 9-Mar-06 3100 6.0 14-Jun-06 3000 6.0 20-Jul-06 2820 1.2 9-Nov-06 2830 6.4 15-Aug-07 2600 6.2 10-Oct-07 2300 6.2 26-Mar-08 2400 5.8 25-Jun-08 2500 6.09 10-Sep-08 1800 6.36 15-0ct-08 2100 5.86 12-Sep-02 5700 8.3 24-Nov-02 5000 8.5 28-Mar-03 4500 8.2 23-Jun-03 4700 8.4 12-Sep-03 3400 8.6 10-Nov-03 4500 8.4 29-Mar-04 NA 22-Jun-04 NA 17-Sep-04 3300 6.83 MW·4 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloriile (ugll) (ugll) (ugll) (ugll) (mgll) (mgll) 17·Nov·04 4100 8 16·M.r·05 3700 7.1 25·May·05 3740 7.8 31·Aug·05 3800 <10 <10 <10 6.9 12/1/2005 3000 <50 <50 <50 7 NA 7/20/2006 2820 <50 <50 <50 1.2 48 Il19J2006 2830 2.1 1.4 <1 6.4 50 3/912006 3100 <50 <50 50 6 49 6/14/2006 3000 <50 <50 50 6 49 2/28/2007 2300 1.6 <1 <1 6.3 47 612712007 2000 1.8 <I <I 7 45 8/1512007 2600 1.9 <I <1 6.2 47 10/1012007 2300 1.7 <I <1 6.2 45 312612008 2400 1.7 <I <1 5.8 42 612512008 2500 1.6 <1 <1 609 42 911012008 1800 1.8 <I <1 6.36 35 10/1512008 2100 1.7 <1 <1 5.86 45 3/412009 2200 1.5 <1 <I 5.7 37 612312009 1800 1.3 <1 <1 5.2 34 9/1412009 2000 1.4 <1 <1 5.3 43 TW4-1 Chloroform Carbon Chloromethane Methylene Nitrate Chloride (ug/l) (ug/l) Chloride (mg/l) . (mg/l) (uom (u!!lll 170Il 7. 5.79 i" III J4! 6-Jun-00 15: 2320 5.58 3440 7.79 2340 7.15 6000 .11 11 t,8 8-Nov-OI 3200 !.4 3200 13.1 2800 12.7 3300 12.8 3500 3666 ~3 3600 1: ·03 2700 12.5 s:NQV:03 34C 11.8 32~ 11 22-Jun-04 31C 8.78 1'7:5en-04 2800 10.8 I" 3000 ILl 2700 9.1 3080 10.6 3i:AlI~-o5 2900 <10 <10 <10 9.8 i <50 -<SO <50 9.6 7, n;; <SO <50 <50 9.7 51 11/8/2006 1.4 <I <I 9.4 47 2700 <50 <50 <50 9.2 49 6 ~ 2200 <50 --<50 <50 9.2 48 ~ 1900 1.2 <I <I 8.9 47 )7 1900 1.4 <I <I 9 45 811512007 2300 1.3 <I <I 8.4 4 r 2000 13 -<I <I 7.8 4 3f '/?on~ 200f 1.3 <I <I 7.6 12008 1900 Ll <I <I 8.68 3 97Wt2008 171 )0 1.3 <I <I 8_15 3 ~ 17i iO 1"3 <1 < 9.3 4 3111/2009 17110 Ll <I <I 7.5 6 1500 1 <1 <1 6.9 37 ~ 1700 -<I <1 <l 7.3 36 TW4·2 Chloroform Carbon Chloromethane Nitrate Olloride (ugll) (ugll) (ugll) (ugll) (mg/I) (mg/I) 2510 5220 4220 10.7 3890 10.2 5500 9.67 20-Sep-01 4900 11.4 5300 10.1 5100 '.98 4700 .78 1, 6000 '.44 5400 10.4 4700 9.5 5100 9.6 3200 8.6 4700 9.7 ~: 4200 9.14 4300 8.22 4100 8.4 17-Nov-04 4500 8.6 16-Mar-05 3700 7.7 3750 8.6 31-Aug-05 3900 <10 <10 <10 8.0 121112005 3500 <50 <SO <SO 7.8 3800 <50 <SO <50 7.5 56 611412006 3200 <50 <50 <SO 7.1 56 4120 <SO <SO <SO 7.4 54 111812 )6 3420 2.3 <1 <1 7.6 55 21 2900 1.8 <1 <1 7.3 54 3000 2.5 <1 <1 7.8 50 8flSl: )7 340 2.2 <1 <1 7.3 49 II 3200 2.1 <1 <1 6.9 51 ~ 3300 2.3 <1 <1 6.9 48 3100 2.2 <1 <1 7.44 46 911012008 2800 2.4 <I <1 42 II 3200 2.4 <2 <2 7.99 47 311112009 3100 2.2 <1 <I 6.5 46 612412009 2800 2 <1 <I 6.4 44 911512009 3000 2 <1 <I 6.6 43 ::" TW4-3 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ugll) (uon) (ugll) (liOn) (mgll) (mgll) 28-lun-99 3S00 7.6 29-Nov-99 702 IS-Mar-OO 834 2-Sen-00 836 1.56 29-Nov-OO 836 1.97 27-M.r-01 347 1.8S 21-lun-01 390 2.61 20-Sep·01 300 3.06 7-Nov·Ol 170 3.6 ---~-"'--" 26-Mar-02 II 3.87 21-Mav-02 204 4.34 12-Sw:.02 203 4.32 24·Nov-02 102 4.9 28-Mar-03 ND 4.6 23-lun·03 ND 4.8 12·Sw:.03 ND 4.3 8-Nov-03 ND 4.8 --29-Mar-04 ND 4.48 22-lun·04 ND 3.68 17 -Sel'cQ.4:.. __ ND 3.88 17·Nov-04 ND 4.1 16·Mar·OS ND 3.S 2S·M;;V::OS ND 3.7 31-Au.·OS ND <1 <1 <1 3.S I-Dec·OS ND <1 2.3 <1 3.3 9-Mar·06 ND <1 2.2 <1 3.3 26 14-lun·06 ND <1 <1 <1 3.2 26 20-lul·06 ND <1 1.6 <1 2.9 26 8-Nov·06 ND <1 <1 <1 I.S 23 28-Fcb-07 ND <1 <1 <1 3.1 22 27-lun·07 ND <1 <1 <1 3.3 23 IS-Aug-2007 ND <1 <1 <1 3.1 24 10/1012007 ND <1 <1 <1 2.8 27 26-Mar·08 ND <1 <1 <1 2.8 21 -2S-lul'1'OS ND <1 <1 <1 2.SS 19 IO-Sep-OS ND <1 <1 <1 2.66 19 15-0ct·OS ND <1 <1 <1 2.63 22 4-M.r-09 ND <1 <1 <1 2.S 21 24-lun·09 ND <1 <1 <1 2.9 20 IS-Sep-09 ND <1 <1 <1 2.8 21 TW4·4 (:hloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ugll) (ul!iJ) (ugll) (ul!iJ) (mgll) (mgll) 6-Jun-00 NO 2·Sep-00 NO 28-Nov-00 3.85 28-Mar-01 2260 1.02 20-Jun-01 3100 14.5 20-Sep-01 3200 14 8-Nov-01 2900 14.8 26-Mar·02 3400 15 22-May-02 3200 13.2 12-Sep-02 4000 13.4 24-Nov-02 3800 12.6 28-Mar-03 3300 13.4 23·Jun-03 3600 12.8 12-Sep-03 2900 12.3 8-Nov-03 3500 12.3 29-Mar-04 3200 12.2 22-Jun-04 3500 12.1 17-Sep:04 3100 11.1 17-Nov-04 3600 10.8 --16-Mar·05 3100 11.6 25-May-05 2400 10 31-Aug-05 3200 <10 <10 <10 11.3 I-Dee-OS 2800 50 50 50 10.2 9-Mar-06 2900 50 50 50 9.5 51 14-Jun-06 2600 50 50 50 8.6 48 20-Jul-06 2850 50 50 50 9.7 50 8-Nov-06 2670 1.7 <1 <1 10.1 49 28-Feb-07 2200 1.5 <1 <1 9 49 27-Jun-07 2400 1.7 <1 <1 9.4 47 15-Aug-07 2700 1.5 <1 <1 9.5 45 1O-0et-07 2500 1.5 <1 <1 9.5 47 26-Mar-08 2800 1.6 <1 <1 9.2 43 25-Jun-08 2500 1.5 <1 <1 10.8 42 10-Sep-08 2200 1.4 <1 <1 8.83 39 15-0ct-08 2500 2 <2 <2 10.1 44 4-Mar-09 2200 1.2 <1 <1 10.2 37 24-Jun-09 1800 1.2 <1 <1 8.2 34 . ~~------15-Sep-09 2000 1.1 <1 <1 8.4 39 TW4-5 Chloroform Carbon Ch]orom~thanc Methylene Nitrate Chloride tetracbloride Chloride (ugll) (ugll) (ugll) (ugll) (mg/l) (mg/l) 20-Dec-99 29.5 15-Mar-00 49 2-Sep-00 124 29-Nov-00 255 2S-Mar-01 236 20-Jun-01 240 20-Sep-01 240 7-Nov-01 260 26-Mar-02 260 22-May-02 300 12-Sep-02 330 24-Nov-02 260 2S-Mar-03 240 23-Jun-03 290 12-8ep-03 200 S-Nov-03 240 29-Mar-04 210 22-Jun-04 200 17-8ep-04 150 17-Nov-04 1S0 16-Mar-05 120 25-May-05 113 31-Aug-05 S2 <2.5 5.S <2.5 6 I-Dec-OS 63 <2.5 <2.5 <2.5 6 9-Mar-06 66 <2.5 3.1 <2.5 6 52 14-Jun-06 51 <1 <2.5 <2.5 5.9 51 20-Jul-06 53.7 <1 <1 <1 6.7 54 S-Nov-06 47.1 <1 <1 <1 2.9 55 28-Feb-07 33 <1 <1 <1 7.8 57 27-Juo-07 26 <1 <1 <1 7 45 15-Aug-07 9.2 <1 <1 <1 7.7 38 1O-0ct-07 9.4 <1 <1 <1 8.2 39 26-Mar-OS 11 <1 <1 <1 7.4 36 25-Juo-OS 9.3 <1 <1 <1 S.7 37 10-Sep-OS 11 <1 <1 <1 7.91 34 15-0ct-08 10 <1 <1 <1 9.3 37 4-Mar-09 12 <1 <1 <1 7.9 34 24-Jun-09 13 <1 <1 <1 7.5 37 15-8ep-09 12 <1 <1 <1 8.3 48 -- TW4-6 Chloroi'oml Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ugll) (ugll) (ugll) (ug/l) (mgll) (mgll) 6-Jun-OO NO 2-Sep-OO NO 28-Nov-OO NO NO 26-Mar-01 NO ,13 20-Jun-01 NO NO 20-Sep-01 3,6 NO 7-Nov-01 1,00 NO 26-Mar-02 NO NO 21-May-02 , NO NO 12-Sep-02 NO NO 24-Nov-02 NO NO 28-Mar-03 NO 0,1 23-Jun-03 NO NO 12-Sep-03 NO NO 8-Nov-03 NO NO 29-Mar-04 NO NO 22-Jun-04 NO NO 17-Sep-04 NO NO 17-Nov-04 NO NO 16-Mar-05 NO 0,2 25-May-05 NO 0.4 3i-Aug-05 10,0 <iO 2,8 dO 0,8 I-Dee-05 17 <1 1.3 <1 0,9 9-Mar-06 31 <1 <1 <1 1.2 31 14-Jun-06 19 <1 <1 <1 1.0 30 20-1ul-06 11 <1 <1 <1 0,6 37 8-Nov-06 42,8 <1 <1 <1 1.4 65 28-Feb-07 46 <1 <1 <1 1.5 32 27-Jull-07 11 <1 <1 <1 0,6 38 15-Aug-07 18 <1 <1 <1 0,7 36 1O-0Cl-07 18 <1 <1 <1 0,8 38 26-3-08 52 <1 <1 <1 1.1 33 25-Jun-08 24 <1 <1 <1 0,9 35 ~-" IO-Sep-08 39 <1 <1 <1 1.14 35 15-0ct-08 37 <1 <1 <1 1,01 33 -,--"-81 ------- 11-Mar-09 <1 <1 <1 2_2 35 24-Jun-09 120 <1 <1 <1 2.7 37 -; 280 ------.... --. 15-Sep-09 <1 <1 <1 37 ----_. __ ... TW4-7 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Cldoride (ugll) (ulUl) (ugll) (ulUl) (mgll) (mgll) 29-Nov-99 256 15-Mar-00 616 2-Sep-00 698 29-Nov-00 684 1.99 28-Mar-Ol 747 2.46 20-Jun-Ol 1100 2.65 20-Sep-Ol 1200 3.38 8-Nov-Ol 1100 2.5 26-Mar-02 1500 3.76 23-May-02 1600 3.89 12-Sep-02 1500 3.18 24-Nov-02 2300 4.6 28-Mar-03 1800 4.8 23-Jun-03 5200 7.6 12-Sep-03 3600 7.6 8-Nov-03 4500 7.1 29-Mar-04 2500 4.63 22-Jun-04 2900 4.83 17-Sep-04 3100 5.59 17-Nov-04 3800 6 16-Mar-05 3100 5.2 25-May-05 2700 5.4 31-Aug-05 3100 <10 <10 <10 5.2 I-Dee-05 2500 <50 <50 <50 5.3 9-Mar-06 1900 <50 <50 <50 1.0 48 14-1un-06 2200 <50 <50 <50" 4.5 47 20-Jul-06 2140 <50 <50 <50 4.7 51 .- 8-Nov-06 2160 1.5 <1 1 4.6 49 28-Feb-07 1800 1 .1 <1 1 5 47 27-1un-07 2600 1.5 <1 1 5.1 45 14-Aug-07 2300 1.4 <1 1 4.7 44 1O-0cl-07 1900 1.2 <1 1 4.7 45 26-Mar-08 2200 1.3 <1 1 4.2 43 i----';;, 1800 1.3 <1 1 4.8 43 25-1un-08 10-Sep-08 1600 1.4 <1 1 4.16 35 •. 15-0ct-08 1900 <2 <2 2 4.01 40 ll-Mar-09 1800 1.2 <1 1 3.7 35 ._---~, .. 24-Jun-09 1400 <1 <1 1 3.8 37 15-Sep-09 1500 <1 <1 1 4.1 37 TW4·8 Chlorofonn Carbon Chloromethane Methylene Nitra.te Chloride tetr~~:~;ridC Chloride (ugll) (ugll) (u!!ll) (mgll) (mgll) 29-Nov-99 NO 15-Mar-00 21.8 2-S00:00 102 29-Nov-00 107 NO 26-Mar-01 116 NO 20-Jun-01 180 NO 20-800:01 180 0.35 7-Nov-01 180 NO 26-Mar-02 190 0.62 22-Mav-02 210 0.77 12-Sep-02 300 NO 24-Nov-02 450 NO 28-Mar-03 320 0.8 23-Jun-03 420 NO 12-800:03 66 NO 8-Nov-03 21.0 0.1 29-Mar-04 24 0.65 22-Jun-04 110 0.52 17-800:04 120 NO 17-Nov-04 120 NO 16-Mar-05 10.0 NO .... -,,-25-May-05 NO 0.2 31-Au"-05 1.1 NO -I-Dee-OS NO <1 1.7 <1 NO 9-Mar-06 1.3 <1 <1 <1 0.3 39 ".,," "._- 14-Jun-06 NO <1 2.1 <1 NO 37 20-Jul-06 NO <1 1.8 <1 0.1 39 8-Nov-06 NO <1 1 <1 NO 40 28-Feb-07 2.50 <1 1 <1 0.7 39 ----._-. 27-Jun-07 2.5 <1 1 <1 0.2 42 15-Au1t.Q7 1.5 <1 1 <1 NO 42 1O-0et-07 3.5 <1 1 <1 0.5 43 26-Mar-08 NO <1 1 <1 0.1 46 25-Jun-08 NO <1 1 <1 NO 45 10-Sen-08 NO <1 1 <1 NO 39 15-0ct-08 NO <1 1 <1 NO 44 4-Mar-09 NO <1 1 <1 NO 42 24-Jun-09 NO <1 1 <1 NO 44 15-8eo..09 NO <1 1 <1 NO 44 TW4-9 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ugll) (ugll) (ugll) (ugll) (mgll) (mgll) 20-0ec-99 4,24 15-Mar-00 1,88 2-Sep-00 14,2 29-Nov-00 3904 NO 27-Mar-01 43.6 NO 20-Jun-01 59 .15 20-Sep-01 19 0040 7-Nov-01 49 0.1 26-Mar-02 41 0,5 22-Mav-02 38 0.65 12-Sep-02 49 0.2 24-Nov-02 51 0.6 --28-Mar-03 34 0.6 23-Jun-03 33 0.8 12-Sep-03 32 1.1 8-Nov-03 46 1.1 29-Mar-04 48 0.82 22-Jun-04 48 0.75 17-Sep-04 39 0.81 17-Nov-04 26 1.2 16-Mar-05 3.8 1.3 25-May-05 1.2 l.3 31-Aug-05 NO <1 2.9 <1 1.3 I-Dec-05 ND <1 <1 <1 1.3 9-Mar-06 ND <1 2.6 <1 1.5 38 14-Jun-06 ND <1 2.7 <1 1.5 39 20-Jul-06 NO <1 <1 <1 0.9 41 8-Nov-06 NO <1 <1 <1 0.7 44 28-Feb-07 NO <1 <1 <1 0.6 44 27-Jun-07 21 <1 <1 <1 U 42 15-Aug-07 9.5 <1 <1 <1 1.8 38 1O-0ct-07 8.7 <1 <1 <1 2 40 26-Mar-08 1.3 <1 <1 <1 2.1 35 25-Juo-08 1.0 <1 <1 <1 2.3 35 .-10-Sep-08 ND <1 <1 <1 2.79 28 15-0ct-08 NO <1 <1 <1 1.99 58 4-Mar-09 NO <1 <1 <1 2.5 30 --~. 24-Jun-09 NO <1 <1 <1 2.3 30 15-Sep-09 NO <1 <1 <1 2.5 30 _0-. 'fW4·10 Chloroform Carbon Chloro~ethalle Methylene Nitrate Chloride tetrachloride Chloride (ugll) (u!!ll) (ugll) (u!!ll) (mgll) (mgll) 21·Jan·02 14 26·Mar·02 16 0.14 21-May-02 17 0.11 12-Sep-02 6.0 NO 24-Nov-02 14 NO 2B-Mar-03 29 0.2 23-Jun-03 110 0.4 12-Sep-03 74 0.4 B-Nov-03 75 0.3 29-Mar-04 22 0.1 22-Jun-04 32 NO 17-Sep-04 63 0046 17-Nov-04 120 004 16-Mar-05 140 1.6 25-May-05 62.4 0.8 31-Aug-05 110 1.1 I-Dec-OS 300 <2.5 <2.5 6.2 3.3 9-Mar-06 190 <5 <50 <50 2.4 50 14-Jun-06 300 <5 <50 <50 3.5 54 20-Jul-06 504.00 <5 <50 <50 6.8 61 8-Nov-06 452.00 <1 1.6 1 5.7 58 2S-Feb-07 500 <1 <1 1 7.6 62 27-Jul1-07 350 <1 <1 1 5.1 54 15-Aug-07 660 <1 <1 1 7.3 59 1O-0ct-07 470 <1 <1 1 6.7 59 26-Mar-OS 620 <1 <1 1 7.3 55 25-Jul1-0S 720 <1 <1 1 9.91 58 10-Sep-OS 680 <1 <1 1 9.23 51 15-0ct-OB 1200 <2 <2 2 10.5 61 11-Mar-09 1100 <1 <1 1 11.6 64 24-Jun-09 1200 <1 <1 1 9.B 62 15-Sep-09 910 <1 <1 1 8.1 51 : i i I I I TW4-11 21 26-Mar-0: c. 1 'd 22-Jun-04 \U~-, .-Dee-C 14-.11 In-Of> ?O-.IIII.Of> uo 17 1 lu-ve[-u, 26-Mar-08 1,_ Tnn_OR 15-0ct-08 11 Chloroform Carbon (uglI) (u!!lll 4700 4900 5200 4600 5200 5300 <10 <100 4400 <50 4300 <50 4080 <50 3660 1.7 3500 1.3 3800 1.6 4500 1.7 4400 1.6 340 <1 640 <1 900 <1 1000 <: 1100 <' 980 <' 1000 <' ChlQl"omethane Nitrate Chloride (uglI) (uglI) (mglI) (mglI) 9.60 9.07 8.84 9.7 9.7 9.4 9.9 9.3 9.07 1.7' 0.3 <10 <10 9.4 <100 <100 9.4 <50 <50 9.2 56 <50 <50 10 56 <50 <50 10 55 2.7 1.3 10 55 <1 1.6 10.1 5' <1 ,1 10.6 5: <1 1.1 10.2 5: <1 1.2 9.8 53 <1 <1 7.7 63 <1 < 7.2 <1 < 7.9 <: <: 9 < < < < < < i I ! TW4-12 12-Sep-02 24-Nov-02 28-Mar-03 23-Jun-03 12-Seo:03 9-Nov-03 29-Mar-04 22-Jun-04 17-Sen-04 17-Nov-04 16-Mar-05 2S-May-OS 31-Aug-OS I-Dee-OS 9-Mar-06 14-Jun-06 20-Jul-06 8-Nov-06 2S-Feb-07 27-Jun-07 Aug-I 5-07 1O-0el-07 26-Mar-OS 2S-Jun-08 IO-Sen-OS 15-0e1-08 4-Mar-09 24-Jun-09 15-Sep-09 Chloroform Carbon tetra::~~ride (ugll) (u ) 1.5 NO NO NO NO NO NO NO NO NO NO NO NO <1 NO ND <1 ND <1 ND <1 ND <1 ND <1 ND <1 ND <1 ND <1 ND <1 ND <1 ND <1 NO <1 NO <1 NO <1 NO <1 Chloromethane Methylene Nitrate Chloride Chloride (ugll) (UI!!I) (mgll) (mgll) 2.54 2.2 1.9 1.8 1.8 1.6 1.58 1.4 1.24 1.5 1.4 1.6 5.8 <1 I.S <1 <1 1.4 <1 <1 1.3 19 <1 <1 1.4 16 <1 <1 1.4 16 <1 <1 1.4 16 <1 <1 I.S 16 <1 <1 1,5 18 <1 <1 1.4 29 <1 <1 1.4 16 <1 <1 1.6 16 <1 <1 2.69 19 <1 <1 2.65 18 <1 <1 2.47 22 <1 <1 2.4 23 <1 <1 3.8 22 <1 <1 5.1 22 TW4-l3 Chloroform Carbon Chloromethane Methylene Nitrate Chloride (ugll) tetrachloride (ugll) Chloride (mgll) (mgll) (u!!ll) (u!!ll) 12-Sep-02 ND ND 24-Nov-02 ND ND 28-Mar-03 ND 0.2 23-Jun-03 ND 0.2 12-Scp-03 ND ND 9-Nov-03 ND 0.9 29-Mar-04 ND 0.12 22-Jun-04 ND 0.17 17-Sep-04 ND 4.43 17-Nov-04 ND 4.7 16-Mar-05 ND 4.2 25-May-05 ND 4.3 31-Aug-05 ND <1 3.1 <1 4.6 I-Dec-05 ND <1 <1 <1 4.3 9-Mar-06 ND <1 1.7 <1 4.2 67 14-Jun-06 ND <1 1.4 <1 4.9 66 20-Ju1-06 ND <1 <1 <1 4.3 65 8-Nov-06 ND <1 <1 <1 0.8 33 28-Feb-07 ND <1 <1 <1 4 59 27-Jun-07 ND <1 <1 <1 4.6 59 15-Aug-07 ND <1 <1 <1 4.4 58 10-Oct-07 ND <1 <1 <1 4.1 58 26-Mar-08 ND <1 <1 <1 3.S 54 25-Jun-08 ND <1 <1 <1 4.24 58 10-Sep-OS ND <1 <1 <1 4.26 50 15-0ct-08 ND <1 <1 <1 4.63 58 4-Mar-09 ND <1 <1 <1 3.7 58 -24-Jun-09 ND <1 <1 <1 1.2 57 1_it.~~p-09 ND <1 <1 <1 4.7 63 -r---------------------------.- TW4-14 Chloroform Carbon Chlorometbane Methylene Nitrate Chloride tetrachloride Chloride (ug/l) (ug/l) (ng/l) (uom (mgll) (mgll) --_._- 8-Nov-06 ND ND ND ND 2.4 37 28-Feb·07 ND ND ND ND 2.3 38 ... -.. , .. -.~ .. --- 27-Jun-07 ND ND ND ND 1.4 38 lS-Aug-07 ND ND ND ND 1.1 36 1O-0ct-08 ND ND ND ND 0.8 38 26-Mar-08 ND ND ND ND 0.4 57 2S-Jun-08 ND ND ND ND 1.56 35 10-Sep-08 ND ND NO NO 1.34 34 15-0ct-08 ND ND NO NO 0.76 40 4-Mar-09 NO NO NO NO 1.6 35 24-Jun-09 NO NO NO NO 1.4 36 15-Sep-09 ND ND ND ND 1.5 38 TW4-15 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ug!!) (ugll) (ug!!) (ugll) (mg!!) (mg!!) 12-Sep-02 2.6 ND 24-Nev-02 ND ND 28-Mar-03 ND 0.1 23-Jun-03 7800 14.5 IS-Aug-03 7400 16.8 12-Sep-03 2S00 2.7 2S-Sep-03 2600 2.5 29-0c\-03 3100 3.1 -._-- 8-Nev-03 3000 2.8 29-Mar-04 NA NA 22-1un-04 NA NA 17-Sep-04 1400 0.S3 17-Nov-04 300 0.2 16-Mar-OS 310 0.3 30-Mar-OS 230 0.2 2S-May-05 442 0.2 31-Aug-OS 960 <5 5.4 <5 0.2 I-Dee-OS 1000 <50 <50 0.3 9-Mar-06 llOO <50 <50 <50 0.2 52 14-1un-06 830 <50 <50 <50 0.2 52 20-Jul-06 2170 <50 <50 <50 1.4 65 8-Nev-06 282 <1 <1 2.8 0.3 54 28-Feb··07 570 <1 <1 5.5 0.5 56 27-1un-07 300 <1 <1 13 0.4 49 IS-Aug-07 1400 <1 <1 36 I 57 1O-0cI-07 2000 <1 <1 14 0.6 57 26-Mar-08 930 <1 <1 40 0.1 49 25-Jun-08 1300 <1 <1 53 0.56 57 IO-Sep-08 630 <1 <1 24 0.24 44 15-0ct-08 1700 <1 <1 100 0.65 64 4-Mar-09 950 <1 <1 51 0.4 49 24-Jun-09 410 <1 <1 12 0.2 48 15-Sep-09 850 <1 <1 30 0.1 46 _c .. ._------------ I i i I , I i i ! TW4-16 l2-Sep-02 24-Nov-02 28-Mar-03 23-Jun-03 12-Sep-03 8-Nov-03 29-Mar-04 22-Jun-04 17-Sep·04 17-Nov-04 16-Mar-05 25-Mav-05 31-Aug-05 I-Dee-OS 9-Mar-06 14-Jun-06 20-Jul-06 8-Nov-06 28-Feb-07 27-.lun-07 15-Aug-07 1O-0ct-07 26-Mar-08 25-Jul1-08 IO-Sep-08 15-0ct-08 4-Mar-09 24-Jun-09 15-Sen-09 ----. __ . _ .. ,,---... _- Chloroform Carbon (ugll) tetra:~~ride (u ) 140 200 260 370 350 400 430 530 400 350 240 212 85 <1 14 <1 39 <1 13 <1 5 <1 13.6 <1 8.70 <1 2.60 <1 7.10 <1 1.40 <1 11.00 <1 ND <1 10.00 <1 3.9 <1 ND <1 ND <1 ND <1 Chloromethane Methylene Nitrate Chloride (ugll) qd~~e (mgll) (mgll) (u" ) ND ND ND ND ND ND ND ND ND ND ND ND 3.2 43 ND 2.6 5.9 1.4 1.1 21 3.0 60 2.4 8.9 1.9 55 <1 2.7 2.7 60 <1 9.2 5.6 62 <1 6.5 12.3 79 <1 1.8 9.9 75 <1 5.1 5.4 66 <1 <1 4.4 69 <1 26 ND 52 <1 <1 1.46 58 <1 14 10.5 71 <1 6.6 9.82 89 <1 <1 9.6 78 <1 <1 8.9 76 <1 <1 8.8 79 ---_.- TW4,17 Chlorofonn Carbon .Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ug/!) (uw'll (ug/!) (uw'l) (mg/!) (mg/!) 12-Sep-02 1.6 ND 24-Nov-02 ND ND 28-Mar-03 ND ND 23-Jun-03 ND ND 12-Sep-03 ND ND 8-Nov-03 ND ND 29-Mar-04 ND ND 22-Jun-04 ND ND 17-Sep-04 ND ND 17-Nov-04 ND ND 16-Mar-OS ND ND 30-Mar-05 ND ND 2S-May-05 ND ND 31-Aug-05 NO <1 3.2 <1 ND I I I I-Dee-05 ND <1 1 ND 32 9-Mar-06 ND <1 1 ND 30 14-Jun-06 ND <1 3.5 ND 32 20-Jul-06 NO <1 1.8 NO 31 8-Nov-06 ND <1 1.5 NO 32 28-Feb-07 NO <1 <1 NO 32 27-Jun-07 NO <1 <1 NO 31 15-Aug-07 NO <1 <1 ND 32 10-OcI-07 ND <1 <1 NO 31 26-Mar-08 NO <1 <1 NO 29 2S-Jun-08 NO <1 <1 ND -~ _._. 1O-Sep-08 NO <1 <1 NO 26 15-0cl-08 NO <1 <1 NO 30 4-Mar-09 NO <1 <1 NO 31 ~_.15-Sep-09 NO <1 <1 NO 33 _. - TW4-18 Chloroform ~arbon Chloromethane Methylene Nitrate . Chloride tetrachloride Chloride (ug/l) (ug/l) (ugIJ) (ug/l) (mgIJ) (mgIJ) 12-Sep-02 440 1.49 24-Noy-02 240 13.3 28-Mar-03 160 13.1 23-Jun-03 110 19 12-Sep-03 68 19.9 9-NoY-03 84 20.7 29-Mar-04 90 14 22-Jun-04 82 12.1 17-Sep-04 38 145 17-Noy-04 51 17.3 16-Mar-05 38 14.1 25-May-05 29.8 12.9 31-Aug-05 39 13.3 I-Dec-05 14 <1 2.8 <1 7.3 9-Mar-06 12 <1 1.1 <1 5.9 5.9 14-Jun-06 12 <1 1.6 <1 4.7 35 20-Jul-06 10.80 <1 2.7 <1 6.1 35 g-Noy-06 139.00 <1 <1 <1 8.7 34 28-Feb-07 9.2 <1 <1 <1 5.1 30 27-Jun-07 8.0 <1 <1 <1 4.9 28 15-Aug-07 8.9 <1 <1 <1 5 32 IO-Oct-08 7A <1 <1 <1 4.4 27 26-Mar-08 6.4 <1 <1 <1 0.7 23 ~ _0- 25-Jun-08 5.7 <1 <1 <1 4.55 23 10-Sep-08 8.0 <1 <1 <1 4.68 26 ~~.-9.4 <1 <1 <1 5,15 30 15-0cl-08 4-Mar-09 11.0 <1 <1 <1 5.2 29 24-Jun-09 16.0 <1 <1 <1 6.2 30 15-Sep-09 13.0 <1 <1 <1 5.9 26 -.----- TW4-19 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ugll) (u!!ll) (ugll) (u!!ll) (mgll) (mgll) 12-Scp-02 7700 47.6 24-Nov-02 5400 42 28-Mar-03 4200 61.4 15-May-03 4700 NA 23-Jun-03 4500 11.4 15-Jul-03 2400 6.8 15-Aug-03 2600 4 12-Sep-03 2500 5.7 25-Scp-03 4600 9.2 29-0ct-03 4600 7.7 9-Nov-03 2600 4.8 29-Mar-04 NA NA 22-Jun-04 NA NA 16-Aug-04 7100 9.91 17-Sep:04 2600 4.5 17-Nov-04 1800 3.6 16-Mar-05 2200 5.3 25-M.y-05 1200 5.7 31-Aug-05 1400 <5 <5 <5 4.6 I-Dec-OS 2800 50 <50 <50 ND 9-Mar-06 1200 50 <50 <50 4.0 86 14-Jun-06 1100 50 <50 <50 5.2 116 20-Jul-06 1120 50 <50 <50 4.3 123 8-Nov-07 lO50 1.6 2.6 <1 4.6 134 2S-Feb-07 1200 1.3 <1 <1 4 133 .----_._-- 27-Jun-07 1800 2.3 15-Aug-07 1100 1.9 <1 <1 4.1 129 -10-Oct-08 1100 1.9 <1 <1 4 132 26-Mar-OS 1800 2.9 <1 <1 2.2 131 ... n._". _____ " 2S-Jun-08 1000 1 <1 <1 2.81 128 10-Sep-08 3600 8.6 <1 <1 36.2 113 15-0ct-08 4200 12 <1 <1 47.8 124 4-Mar-09 1100 1.2 <1 <1 3.2 127 24-Jun-09 990 1.2 <1 <1 2.4 132 15-Sep-09 6600 15 <1 <1 0.1 43 -_._--_. ---Carbon Methylene TW4·20 Chloroform tetrachloride Chloromethane Chloride Nitrate Chloride (ugll) (ugl!) (ugll) (ug/l) (mgll) (mgll) 25-May-OS 39000 NS NS NS lOJ NS 31-Aug-05 3800 NO NO NO 2.9 NS .. " .. --. I-Dee-OS 19000 NO NO ND 1.8 131 9-Mar-06 9200 NO NO NO 3.8 120 14-Jul1-06 61000 NO NO NO 9.4 235 20-Jul-06 5300 NO NO NO 2.9 134 8-Nov-06 11000 7.1 1.9 2.2 3.5 124 2S-Peb-07 4400 3.1 NO 1.1 4.2 124 27-Jul1-07 1800 2.2 NO NO 2.3 112 IS-Aug-07 5200 3.5 ND 1.8 2.1 117 1O-0ct-08 9000 6.8 NO 1.9 5.6 170 . - 26-Mar-OS 13000 9.0 NO 1.5 0.9 132 25-Jun-OS 30000 13 NO 1.2 7.96 191 -----IO-Sep-OS 21000 15 NO 3.7 4,44 156 15-0ct-08 NS NS NS NS 5.51 166 4-Mar-09 8200 5.7 ND 5.2 5.1 164 24-Jun-09 6800 4.9 NO 4.2 2.9 164 ---- 15·Sep·09 13000 8,4 NO 4.4 3.3 153 ~ ----Methylene TW4-21 Chloroform Carbon Chlorometbane Nitrate Chloride tetrachloride Chloride (ngll) (uoll) (ngll) (n.ll) (mgll) (mgll) 1--._-25~May~05 192 NS NS NS 14.6 NS 31 ~ Au!t0~5.~ .. ~ 78 ND ND ND 10.1 NS ----._-----I~Dec~05 86 ND 1.0 ND 9.6 353 9~Mar~06 120 ND ND ND 8.5 347 14-Jull~06 130 ND ND ND 10.2 318 20-Jul~06 106 ND ND ND 8.9 357 8~Nov-06 139 2.0 ND ND 8.7 296 ! .' 28-Feb~07 160 1.8 ND ND 8.7 306 27-Jun~07 300 5.8 ND ND 8.6 327 15-Aug-07 140 ND ND ND 8.6 300 10-Oct-07 120 ND ND ND 8.3 288 26~Mar-08 390 7.0 ND ND 14.3 331 25-Jun-08 160 1.7 ND ND 8.81 271 1O-S;;';;:08 120 1.6 ND ND 7.57 244 1S-0ct-08 170 2.0 ND ND 8.0 284 11-Mar-09 180 ND ND ND 8.3 279 24-Jun-09 200 ND ND ND 8.1 291 _. __ .. -,,_ .• 1S-Seo-09 200 ND ND ND 9.2 281 I TW4·22 Chloroform Carbon Chloromethane Methylene Nitrate Chloride (ugll) tetra~~~ride (ugll) Ch~~~e (mglI) (mgll) _. (ll) (u 25·Mav..05 ----_. 340 NS NS NS 18.2 NS 31-AU;;::OS 290 NO NO NO 15.7 NS I-Dec-OS 320 NO NO NO 15.1 263 9-Mar-06 390 NO NO NO 15.3 236 06114/06 280 NO NO NO 14.3 221 07120106 864 NO NO NO 14.5 221 11/08/06 350 NO 1.6 NO 15.9 236 28-Feb-07 440 NO NO NO 20.9 347 06/27/07 740 NO ND NO 19.3 273 Aug-IS-07 530 NO NO NO 19.3 259 Oct-IO-08 440 NO NO NO 18.8 238 -----._-.,~-. .. -.. _--,-----"-03/26108 1400 NO ND NO 39.1 519 0612S/08 1200 NO ND ND 41.9 271 i 10-500:08 6300 1.3 ND ND 38.7 524 15-0ct-08 630 NO ND NO 36.3 539 11-Mar-09 390 NO ND NO 20.7 177 I 24-Jun-09 730 NO NO NO 20.6 177 15-Seo-09 2300 NO ND ND 40.3 391 TW4-23 Chlorotorm Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ugll) (lIgIl) (ugll) (ugll) (mgll) (mgll) _. -06127107 ND ND ND ND ND 47 Aug-15-07 ND ND ND ND ND 46 Oct-IO-08 ND ND ND ND ND 43 03126/08 ND ND ND ND ND 41 06125108 ND ND ND ND ND 41 10-Sep-08 ND ND ND ND ND 35 15-0ct-08 ND ND ND ND ND 51 11 -Mar-09 ND ND ND ND ND 41 24-Jun-09 ND ND ND ND ND 43 -~~-. --.-.---- 15-Sep-09 ND ND ND ND ND 43 TW4-24 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetracbloride Chloride (ugll) (ul!!l) (ugll) (ugll) (mg/l) (mgll) 06/27/07 2.6 ND ND ND 26.1 770 Aug-15-07 2.2 ND ND ND 29.0 791 Oct-lO-08 1.5 ND ND ND 24.7 692 03126/08 1.5 ND ND ND 24.4 740 06/25/08 1.4 ND ND ND 45.3 834 1O-Sep-08 2.9 ND ND ND 38.4 1180 15-0ct-OB ND ND ND ND 44.6 1130 -----7'--1.4 ND ND ND 11-Mar-09 30.5 1010 24-Jun-09 1.5 ND ND ND 30.4 759 ~~-~ 15-Sep-09 1.4 ND ND ND 30.7 618 TW4·25 Chloroform Carbon Chloromethane Methylene Nitrate Chloride tetrachloride Chloride (ugll) (n!!iIl (ugll) (ugll) (mgll) (mgll) 06/27/07 NO NO NO NO 17.1 395 Aug·15·07 NO NO NO NO 16.7 382 Oct·10-08 NO NO NO NO 17.0 356 03126/08 NO NO NO NO 18.7 374 06/25108 NO NO NO NO 22.1 344 10-Sep-08 NO NO NO NO 18.8 333 15-0ct·08 NO NO NO NO 21.3 366 11-Mar-09 NO NO NO NO 15.3 332 24-Jun-09 NO NO NO NO 15.3 328 -. 15-Sep-09 NO NO NO NO 3.3 328 I , Monitoring Event MW-4 MW-26 TW4-1 TW4-2 TW4-4 TW4-7 TW4-9 TW4-10 TW4-11 TW4-19 TW4-20 TW4-21 1st Quarter 2005 6.3 0.3 9.1 7.7 10.0 5.2 1.3 1.6 8.7 5.3 WNI WNI 2nd Quarter 2005 7.1 0.2 10.6 8.6 11.3 5.4 1.3 0.8 10.3 5.7 10.1 14.6 3rd Quarter 2005 7.0 0.2 9.8 8.0 9.9 5.2 1.3 1.1 9.4 4.6 2.9 10.1 4th Quarter 2005 7.0 0.3 9.7 7.8 10.2 5.3 1.3 3.3 9.4 <0.1 1.8 9.6 1st Quarter 2006 6.0 0.2 9.4 7.5 9.5 1.0 1.5 2.4 9.2 4.0 3.8 8.5 2nd Quarter 2006 6.0 0.2 9.6 7.1 8.6 4.5 1.5 3.5 10.0 5.2 9.4 10.2 3rd Quarter 2006 1.2 1.4 9.2 7.4 9.7 4.7 0.9 6.8 10.0 4.3 2.9 8.9 4th Quarter 2006 6.4 0.3 9.2 7.6 10.1 4.6 0.7 5.7 10.0 4.6 3.5 8.7 1st Quarter 2007 6.3 0.6 8.9 7.3 9.0 6.0 0.6 7.3 10.1 4.0 4.2 8.7 2nd Quarter 2007 7.0 0.4 9.0 7.8 9.4 5.1 1.3 5.1 10.6 NS 2.3 8.6 3rd Quarter 2007 6.2 1.0 8.4 7.3 9.5 4.7 1.8 7.3 10.2 4.1 2.1 8.6 4th Quarter 2007 6.2 0.6 7.8 6.9 9.5 4.7 2.0 6.7 9.8 4.0 5.6 8.3 1st Quarter 2008 5.8 0.1 7.6 6.9 9.2 4.2 2.1 7.3 7.7 2.2 0.9 14.3 2nd Quarter 2008 6.1 0.6 8.7 7.4 10.8 4.8 2.3 9.9 7.3 2.8 8.0 8.8 Table 5 Nitrate (as N) Concentrations in Wells Inside the 70 µg/L Isoconcentration Boundary Line. White Mesa Uranium Mill near Blanding Utah Monitor Well * First monitoring event NS = Not sample because of the University of Utah Hydrogeologic Study. WNI = Well was not installed High lighted nitrate concentrations = nitrate concentrations that have exceeded the GWQS of 10 mg/L. Source: appeared as Table 2 in Utah DRC September 15, 2008 Request for Additional Information TABLE A: Chloride and Nitrate in On Site Wells 4th Quarter 2009 PT_NAME SDATE Report Chloride Nitrate MW-01 10/19/2009 C09100882 17 0.2 MW-02 10/21/2009 C09100882 6 0.1 U MW-03 10/26/2009 C09101105 46 0.2 MW-03A 10/28/2009 C09101105 42 1 MW-04 9/14/2009 C09090634 43 5.3 MW-05 10/12/2009 C09100623 51 0.1 U MW-11 10/19/2009 C09100882 30 0.1 U MW-12 10/13/2009 C09100623 67 0.1 U MW-14 10/20/2009 C09100882 17 0.1 U MW-15 10/20/2009 C09100882 38 0.1 MW-16 MW-17 10/21/2009 C09100882 35 0.9 MW-18 10/21/2009 C09100882 58 0.1 U MW-19 10/19/2009 C09100882 25 2.2 MW-20 10/28/2009 C09101105 71 6.2 MW-21 MW-22 10/27/2009 C09101105 67 3.8 MW-23 10/20/2009 C09100882 8 0.1 MW-24 10/28/2009 C09101105 46 0.1 MW-25 10/13/2009 C09100623 34 0.1 U MW-26 10/13/2009 C09100623 58 0.1 MW-27 10/12/2009 C09100623 44 5.2 MW-28 10/12/2009 C09100623 104 0.1 MW-29 10/26/2009 C09101105 35 0.1 U MW-30 10/14/2009 C09100623 129 15 MW-31 10/14/2009 C09100623 138 22.6 D MW-32 10/14/2009 C09100623 32 0.1 U PIEZ-1 10/27/2009 C09101104 61 7.4 PIEZ-2 10/27/2009 C09101104 7 0.6 PIEZ-3 10/27/2009 C09101104 19 1.2 PIEZ-4 46 1.80 PIEZ-5 18 0.70 TW4-1 9/15/2009 C09090634 36 7.3 TW4-10 9/15/2009 C09090634 51 8.1 TW4-11 9/15/2009 C09090634 49 7 TW4-12 9/15/2009 C09090634 22 5.1 TW4-13 9/15/2009 C09090634 63 4.7 TW4-14 9/15/2009 C09090634 38 1.5 TW4-15 9/14/2009 C09090634 46 0.1 D TW4-16 9/15/2009 C09090634 79 8.8 TW4-17 9/15/2009 C09090634 33 0.1 TW4-18 9/15/2009 C09090634 26 5.9 TW4-19 9/14/2009 C09090634 43 0.1 TW4-2 9/15/2009 C09090634 43 6.6 U TW4-20 9/14/2009 C09090634 153 3.3 TW4-21 9/15/2009 C09090634 281 9.2 TW4-22 9/15/2009 C09090634 391 40.3 TW4-23 9/15/2009 C09090634 43 0.1 TW4-24 9/15/2009 C09090634 618 30.7 TW4-25 9/15/2009 C09090634 328 3.3 TW4-3 9/15/2009 C09090634 21 2.8 TW4-4 9/15/2009 C09090634 39 8.4 TW4-5 9/15/2009 C09090634 48 8.3 TW4-6 9/15/2009 C09090634 37 5 TW4-7 9/15/2009 C09090634 37 4.1 TW4-8 9/15/2009 C09090634 44 0.1 TW4-9 9/15/2009 C09090634 30 2.5 TWN-1 10/28/2009 C09101104 18 0.5 TWN-10 11/10/2009 C09110461 26 1.4 TWN-11 11/3/2009 C09110253 74 1.3 TWN-12 11/3/2009 C09110253 109 0.5 TWN-13 11/4/2009 C09110253 83 0.5 TWN-14 11/4/2009 C09110253 32 3.4 TWN-15 11/10/2009 C09110461 78 1.1 TWN-16 11/4/2009 C09110253 39 1 TWN-17 11/4/2009 C09110253 152 6.7 TWN-18 11/2/2009 C09110253 57 1.3 TWN-19 11/2/2009 C09110253 125 7.4 TWN-2 11/2/2009 C09110253 55 20.8 TWN-3 11/2/2009 C09110253 106 29 TWN-4 10/28/2009 C09101104 11 0.4 TWN-5 11/10/2009 C09110461 48 0.2 TWN-6 11/3/2009 C09110253 21 1.4 TWN-7 11/10/2009 C09110461 7 0.1 TWN-8 11/3/2009 C09110253 12 0.1 TWN-9 11/10/2009 C09110461 205 12 CORAL CANYON 11/27/2009 FROG POND 11/27/2009 COTTONWOOD 11/27/2009 WESTWATER 11/27/2009 RUIN SPRINGS 11/27/2009 CORRAL SPRINGS 11/27/2009 ENTRANCE SPRING 11/27/2009 Upper Wildlife Pond 10/27/2009 C09101104 3 0.1 U             Figures r" J' > PROPERTY --- BOUNDARY (f "'- ~V // II 1/ II II 1/ ~I (9 ~ II 1/ II /f II ~ MW-01 • 28 MW-18 • MW-27 --] PIEZ-1 .. MW-19 • PIEZ-2 .. PIEZ-3 .. c --]+ ~?E CELL NO. 1 ~__ -9-4-21 ~-+-------->======= ____ ~----_M~W~-~2r-____ -r ___ MW48 W~2 -~~-~~~frw~r---~~~~~=t~~==~--~r=4 \-~---+--l:f TWt22 TW4-20 OTW4-5 MW-02 • I M -26 TW~1a:>TW4-9 I 0 OTW4-3 OTW4-12 , W-29 CELL NO.2 N o SCALE IN FEET EXPLANATION MW-20 • perched monitoring well TW4-19 MW-2 + MW-16 • MW-03 • MW-20 • 3000 o temporary perched monitoring well wildlife pond PIEZ-1 " MW-31 -+-TW4-20 -¢- TW4-23 ~ perched piezometer perched monitoring well installed April, 2005 temporary perched monitoring well installed April,2005 new temporary perched monitoring well installed MaY,2007 (locations approximate) HYDRO GEO CHEM, INC. MW-17 • APPROVED SJS OTW4-1EbTW4_11 OTW~13 0131,4;1,. TW~7c»'mW:t-8 OTW4-1 PIEZ-4 .. PIEZ-5 .. T37S T388 OTW~OTW4_14 OTW~ti MW-22 • /I // // // // // // // // // // SITE PLAN AND PERCHED WELL LOCATIONS WHITE MESA SITE DA"IE REFERENCE 5/28/08 H:n18000/may08/welloc.srf o W-20 .5461 0 5552 PIEZ-1 .. 5592 MW-31 -+-5545 -¢-5573 ~5540 - N SCALE IN FEET EXPLANATION perched monitoring well showing elevation in feet amsl temporary perched monitoring well showing elevation in feet amsl perched piezometer showing elevation in feet amsl perched monitoring well installed April, 2005 showing elevation in feet amsl temporary perched monitoring well installed April, 2005 showing elevation in feet amsl temporary perched monitoring well installed May, 2007 showing approximate elevation PROPERTY BOUNDARY ~3000 -... - MW-18 .5585 MW-22 -'5450 PIEZ-1 e5592 II // // // // // // // // // // NOTES: Locations and elevations for TW4-23, TW4-24, and TW4-25 are approximate; Water levels for MW-02, MW-20, and MW·22 are from the fourth uarter, 2007 HYDRO GEO CHEM, INC. KRIGED 1 st QUARTER, 2008 WATER LEVELS WHITE MESA SITE APPROVED DATE SJS 5/28/08 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18 TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 MW-26 TW4-10 Mill Site WildlifePond WildlifePond TWN-6 TWN-8 TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 Fly Ash Pond Former Office Leach Field Scale House Leach Field Main Leach Field Historic Landfill CCD Cell 1 Leach Field V2O5 Oxidation Tanks SX Mini Lab Ammonia Tanks V2O5 Mini Lab &V2O5 Precip Lawzy Sump SAG Leach Field Lawzy Lake Chem Lab Met Lab Sewage Vault Underground S e w e r l i n e YC Precip Mini Lab Pipelin e Law z y P i p e l i n e S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223MillSourceMap.mxd Figure 3Potential Nitrate and ChlorideSources at the Mill Site 250 0 250125 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report. Legend Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Potential Nitrate and Chloride Sources Lawzy Pipeline Lawzy Lake Frog Pond approx. 1 mile NE Wastewater Treatment Plant approx. 2 miles NE MW-01 MW-18 PIEZ-1 MW-19 PIEZ-2 MW-27 TW4-21 PIEZ-3 TW4-22 TW4-20 TW4-19 TW4-18 TW4-5 TW4-25 TW4-24 TW4-9 TW4-12 TW4-13TW4-2 TW4-8 TW4-1 MW-04 TW4-11TW4-16 MW-26 MW-32MW-31 MW-30 MW-28 TW4-10 TW4-3 TW4-23 TW4-6 TW4-4 TW4-14 PIEZ-4 MW-25 MW-11 MW-02 MW-24 MW-29 MW-12 MW-05 MW-23 MW-16 MW-15 MW-14 MW-17 Cell No. 1 Mill Site Cell No. 2 Cell No. 3 Cell No. 4A WildlifePond WildlifePond WildlifePond TW4-7 TWN-9 TWN-13 TWN-17 TWN-19TWN-12TWN-11 TWN-16 TWN-15 TWN-14 TWN-10 TWN-6 TWN-8TWN-5 TWN-7 TWN-18 TWN-3 TWN-2 TWN-4 TWN-1 FROG POND PIEZ-5 CORAL CANYON SEEP ENTRANCE SEEP WESTWATER SEEP Wastewater Treatment Plant Lawzy Pipeline Lawzy Lake S:\Projects\IUC-001-01-001 Denison Mines\GIS\mapdocs\20091223SourceMap.mxd Figure 4Possible Sources ofNitrate and Chloride in theVicinity of the Mill 1,300 0 1,300650 Feet Source(s): Aerial – Utah GIS Portal website;Wells – HGC, Inc., May 2008 report.Legend Monitoring Well (MW) Piezometer Seep Spring Surface Water Chloroform MW Nitrate MW Possible Nitrate and Chloride Sources Lawzy Pipeline Lawzy Lake Figure 5 Historic Aerial Photograph (circa.~1979) White Mesa Mill Site Orepad Administration Building Historic Pond Upper Wildlife Pond Historic Barn and Corral 0 0.5 1 Miles N Attachment 3 White Mesa Uranium Mill Ground Water Monitoring Quality Assurance Plan (QAP) State of Utah Groundwater Discharge Permit No. UGW370004. Denison Mines (USA) Corp. April 16, 2009. Mill -Groundwater Discharge Permit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) WHITE MESA URANIUM MILL GROUND WATER MONITORING QUALITY ASSURANCE PLAN (QAP) STATE OF UTAH GROUNDWATER DISCHARGE PERMIT No. UGW370004 Denison Mines (USA) Corp. P.O. Box 809 Blanding, UT 84511 Page 10f43 Mill -Groundwater Discharge Pennit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 2 of43 1. 2. 2.1. 2.2. 2.3. 2.4. 2.4.1. 2.4.2. 2.4.3. 2.5. 3. 3.1. 3.2. 3.3. 3.4. 3.5. 4. 4.1. 4.2. TABLE OF CONTENTS INTRODUCTION ............................................................................. .. ORGANIZATION AND RESPONSIBILITIES ......................................... . Functional Groups .................................................................................. . Overall Responsibility For the AQ/QC Program .............................................. . Data Requestors/Users ......................................................................... . Data Generators .................................................................................. . Sampling and QC Monitors .................................................................... . Analysis Monitor. ............................................................................... . Data Reviewers/ Approvers .................................................................... . Responsibilities of Analytical LaboratOlY .................................................... . QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT OF DATA ... Precision ......................................................................................... . Accuracy ......................................................................................... . Representati veness .............................................................................. . Completeness .................................................................................... . Comparabili ty .................................................................................... . FIELD SAMPLING QUALITY ASSURANCE METHODOLOGy .............. . Controlling Well Contamination .............................................................. . Controlling Depth to Groundwater Measurements ............................................ . Page 6 6 6 6 6 7 7 8 8 9 9 9 10 10 10 11 11 11 11 Mill-Groundwater Discharge Petmit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 3 of43 4.3. 4.3.1. 4.3.2. 4.3.3. 4.3.4. 5. 5.1. 5.2. Water Quality QC Samples ................................................................... . VOC Trip Blanks ............................................................................... . Equipment Rinsate Samples ................................................................... . Field Duplicates ................................................................................. . Definition of "Batch" ........................................................................... . CALIBRATION ................................................................................ . Depth to Groundwater Measurements ....................................................... . Water Quality ................................................................................... . 6. GROUND WATER SAMPLING AND MEASUREMENT OF FIELD PARAMETERS ...................................................................................... . 6.1. 6.1.1. 6.1.2. 6.1.3. Groundwater Head Monitoring ........ , ............................. , ....................... . Location and Frequency of Groundwater Head Monitoring ............................. . Equipment Used For Groundwater Head Monitoring ............. , ....................... . Field Sampling Procedure for Groundwater Head Monitoring .......................... . 11 11 12 12 12 12 13 13 13 13 13 14 14 6.2. Ground Water Compliance Monitoring................................................... .... 14 6.2.1. Location and Frequency of Groundwater Compliance MonitOling... ....... ...... ....... 14 6.2.2. Quarterly and Semi-Annual Sampling Required (Paragraphs I.E. La) orLE.1.b) of the 15 GWDP) ..................................................................................................... . 6.2.3. Quarterly or Monthly Sampling Required Under Paragraphs LG.l or LG.2 of the 15 GWDP ............................................................................................ . 6.2.4. Sampling Equipment for Groundwater Compliance Monitoring... ... ............ ... .... 15 6.2.5. Decontamination Procedure................................................................. ... 16 6.2.6. Pre-Purging/Sampling Activities................................................................ 17 6.2.7. Well Purging/Measurement ofField Parameters............................................. 17 6.2.S. Samples to be Taken and Order of Taking Samples....................................... ... 20 6.2.9. Field Duplicate Samples ....................................................................... '" 20 6.2.10. VOCs and Nutrient Sampling... ................. .... ............ .... ........... ...... .......... 21 6.2.11. Heavy Metals, All Other Non-Radiologies and Gross Alpha Sampling................... 21 6.2.12. Procedures to Follow After Sampling ........................................................ '" 24 7. SAMPLE DOCUMENTATION TRACKING AND RECORD KEEPING....... 25 7.1. Field Data Worksheets......................................................................... 25 7.2. Chain-Of-Custody and Analytical Request Record.................................... .... 26 7.3. Record Keeping..................... ............................................................ 26 Mill -Groundwater Discharge Pennit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 4 of43 8. 8.1. 8.1.2. 8.2. 9. 9.1. 9.1.1. 9.1.2. 9.1.3. 9.1.4. 9.2. 9.3. 9.4. 10. 10.1. 10.2. 11. 12. 12.1. 12.2. 12.3. 12.4. 12.5. 13. ANALYTICAL PROCEDURES AND QA/QC .......................................... .. Analytical Quality ControL .................................................................. .. Spikes, Blanks and Duplicates ............................................................... . Analytical Laboratory Procedures ........................................................... . INTERNAL QUALITY CONTROL CHECKS ........................................ .. Field QC Check Procedures .................................................................. . Review of Compliance With the Procedures Contained in this Plan .................... . Analyte Completeness Review ............................................................... . Blank Comparisons ........................................................................... .. Duplicate Sample Comparisons .............................................................. . Analytical Laboratory QA Reviews ........................................................ .. QA Manager Review of Analytical Laboratory Results and Procedures ............... . Analytical Data ................................................................................. . CORRECTIVE ACTION ..................................................................... . When Corrective Action is Required ................ , ...................................... .. Procedure for Corrective Action ............................................................. . REPORTING .................................................................................... . SYSTEM AND PERFORMANCE AUDITS .............................................. . QA Manager to Perform System Audits and Performance Audits ....................... . System Audits ................................................................................. .. Performance Audits ........................................................................... .. Follow-Up Actions ............................................................................ .. Audit Records ................................................................................... . PREVENTIVE MAINTENANCE ........................................................ . 27 27 27 28 31 31 31 31 31 31 32 33 34 34 34 35 35 36 36 36 37 37 37 37 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page 5 of43 14. QUALITY ASSURANCE REPORTS TO MANAGEMENT........................ 38 14.1. Ongoing QA/QC Reporting................................................................... 38 14.2. Periodic Reporting to Management........................................................... 38 15. AMENDMENT.................................................................................. 39 16. REFERENCES............ ... .................. ..... .... ... ...... ... ... ......... ......... ..... ... 39 Appendices Appendix A-Chloroform Investigation Monitoring Quality Assurance Program Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) 1. INTRODUCTION Date:4-16-09 Revision-4 Page 6 of43 This Groundwater Monitoring Quality Assurance Plan (the "Plan") details and describes all sampling equipment, field methods, laboratOlY methods, qualifications of environmental analytical laboratories, data validation, and sampling and other corrective actions necessary to comply with UAC R317-6-6.3(I) and (L) at the White Mesa Uranium Mill (the "Mill"), as required under paragraph LH.6 of State of Utah Groundwater Discharge Permit No. UGW370004 (the "GWDP") for the Mill. This Procedure incorporates the applicable provisions of the United States Environmental Protection Agency ("EP A") RCRA Groundwater Monitoring Technical Enforcement Guidance Document (OSWER-9950.1, September, 1986), as updated by EPA's RCRA Ground-Water Monitoring: Draft Technical Guidance (November 1992). Activities in an integrated program to generate quality data can be classified as management (i.e., quality assurance or "QA") and as functional (i.e., quality control or "QC"). The objective of this Plan is to ensure that monitoring data are generated at the Mill that meet the requirements for precision, accuracy, completeness, representativeness and comparability required for management purposes and to comply with the reporting requirements established by applicable permits and regulations. 2. ORGANIZATION AND RESPONSIBILITIES 2.1. Functional Groups This Plan specifies roles for a QA Manager as well as representatives of three different functional groups: the data users; the data generators, and the data reviewers/approvers. The roles and responsibilities ofthese representatives are described below. 2.2. Overall Responsibility For the QAlQC Program The overall responsibility for ensuring that the QA/QC measures are properly employed is the responsibility of the QA Manager. The QA Manager is typically not directly involved in the data generation (i.e., sampling or analysis) activities. At the Mill, the QA Manager is the Mill's Radiation Safety Officer ("RSO") or other qualified person designated by Denison Mines (USA) Corp. ("DUSA") corporate management. 2.3. Data Requestors/Users The generation of data that meets the objectives of this Plan is necessary for management to make informed decisions relating to the operation of the Mill facility, and to comply with the reporting requirements set out in the GWDP and other permits and applicable regulations. Accordingly, the data requesters/users (the "Data Users") are therefore DUSA's corporate MiU-Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page 7 of43 management and regulatory authorities through the implementation of such permits and regulations. The data quality objectives ("DQOs") required for any groundwater sampling event, such as acceptable minimum detection limits, are specified in this Plan. 2.4. Data Generators The individuals who carry out the sampling and analysis activities at the request of the Data Users are the data generators. For Mill activities, this involves sample collection, record keeping and QA/QC activities conducted by one or more sampling and quality control/data monitors (each a "Sampling and QC Monitor"). The Sampling and QC Monitors are radiation and environmental technicians or other qualified Mill personnel as designated by the QA Manager. The Sampling and QC Monitors perform all field sampling activities, collect all field QC samples and perform all data recording and chain of custody activities in accordance with this Plan. Data generation at the contract analytical laboratory (the "Analytical Laboratory") utilized by the Mill to analyze the environmental samples is performed by or under an employee or agent (the "Analysis Monitor") of the Analytical Laboratory, in accordance with specific requirements of the Analytical Laboratory's own QA/QC program. The responsibilities of the data generators are as follows: 2.4.1. Sampling and QC Monitors The Sampling and QC Monitors are responsible for field activities. These include: a) Ensuring that samples are collected, preserved, and transported as specified in Plan; b) Checking that all sample documentation (labels, field data worksheets, chain-of- custody records, packing lists) is correct and transmitting that information, along with the samples, to the Analytical Laboratory in accordance with this Plan; c) Maintaining records of all samples, tracking those samples through subsequent processing and analysis, and, ultimately, where applicable, appropriately disposing of those samples at the conclusion of the program; d) Preparing quality control samples for field sample collection during the sampling event; e) Preparing QC and sample data for review by the QA Manager; and f) Preparing QC and sample data for reporting and entry into a computer data base, where appropriate. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 2.4.2. Analysis Monitor Date:4-16-09 Revision-4 Page 8 of43 The Analysis Monitor is responsible for QA/QC activities at the Analytical Laboratory. These include: a) Training and qualifying personnel in specified Analytical Laboratory QC and analytical procedures, prior to receiving samples; b) Receiving samples from the field and verifying that incoming samples correspond to the packing list or chain-of-custody sheet; and c) Verifying that Analytical Laboratory QC and analytical procedures are being followed as specified in this Plan, by the Analytical Laboratory's QA/QC program, and in accordance with the requirements for maintaining National Environmental Laboratory Accreditation Program ("NELAP") and/or National Voluntary Laboratory Accreditation Program ("NA VLAP") certification. 2.4.3. Data ReviewerslApprovers The QA Manager has broad authority to approve or disapprove project plans, specific analyses and final reports. In general, the QA Manager is responsible for reviewing and advising on all aspects of QA/QC, including: a) Ensuring that the data produced by the data generators meet the specifications set out in this Plan; b) Making on-site evaluations and submitting audit samples to assist in reviewing QA/QC procedures; c) Determining (with the Sampling and QC Monitor and Analysis Monitor) appropriate sampling equipment and sample containers, in accordance with this Plan, to minimize contamination; and d) Supervising all QA/QC measures to assure proper adherence to this Plan and determining corrective measures to be taken when deviations from this Plan occur. The QA Manager may delegate certain of these responsibilities to one or more Sampling and QC Monitors or to other qualified Mill personnel. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 2.5. Responsibilities Of Analytical Laboratory Date:4-16-09 Revision-4 Page 9 of43 Unless otherwise specified by DUSA corporate management, all environmental analysis of groundwater sampling required by the GWDP or by other applicable permits, will be performed by a contract Analytical Laboratory. The Analytical Laboratory is responsible for providing sample analyses for groundwater monitoring and for reviewing all analytical data to assure that data are valid and of sufficient quality. The Analytical Laboratory is also responsible for data validation in accordance with the requirements for maintaining NELAP and/or NAVLAP certification. In addition, to the extent not otherwise required to maintain NELAP and or NAVLAP certification, the Analytical Laboratory must adhere to U. S. EPA Guideline SW-846 and, to the extent consistent with NELAP and EPA practices, the applicable portions of NRC Regulatory Guide 4.14. The Analytical Laboratory will be chosen by DUSA and must satisfy the following criteria: (1) experience in analyzing environmental samples with detail for precision and accuracy, (2) experience with similar matrix analyses, (3) operation of a stringent internal quality assurance program meeting NELAP and/or NA VLAP certification requirements and that satisfies the criteria set out in Section 8 below, (4) ability to satisfy radionuc1ide requirements as stipulated in the applicable portions of NRC Regulatory Guide 4.14, and (5) certified by the State of Utah for and capable of performing the analytical methods set out in Table 1. The analytical procedures used by the Analytical Laboratory will be in accordance with Utah Administrative Code R317-6-6.3L. 3. QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT OF DATA The objective of this Plan is to ensure that monitoring data are generated at the Mill that meet the requirements for precision, accuracy, representativeness, completeness, and comparability required for management purposes and to comply with the reporting requirements established by applicable permits and regulations (the Field and Analytical QC samples described in Sections 4.3 and 8.1 below are designed to ensure that these criteria are satisfied). Data subject to QA/QC measures are deemed more reliable than data without any QA/QC measures. 3.1. Precision Precision is defined as the measure of variability that exists between individual sample measurements of the same property under identical conditions. Precision is measured through the analysis of samples containing identical concentrations of the parameters of concern. For duplicate measurements, precision is expressed as the relative percent difference ("RPD") of a data pair and will be calculated by the following equation: Mill-Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) RPD= [(A-B)/{(A+B)/2}] X 100 Date:4-16-09 Revision-4 Page 10 of43 Where A (original) and B (duplicate) are the reported concentration for field duplicate samples analyses (or, in the case of analyses performed by the Analytical Laboratory, the percent recoveries for matrix spike and matrix spike duplicate samples) (EPA S W -846, Chapter 1, Section 5.0, page 28). 3.2. Accuracy Accuracy is defined as a measure of bias in a system or as the degree of agreement between a measured value and an accepted or measured value. The accuracy of laboratory analyses is evaluated based on analyzing standards of known concentration both before and during analysis. Accuracy will be evaluated by the following equation (EPA SW -846, Chapter 1, Section 5.0, page 24): Where: % Recovery = (I A-B I /C) x 100 A = the concentration of analyte in a sample B = the concentration of analyte in an un spiked sample C = the concentration of spike added 3.3. Representativeness Representativeness is defined as the degree to which a set of data accurately represents the characteristics of a population, parameter, conditions at a sampling point, or an environmental condition. Representativeness is controlled by performing all sampling in compliance with this Plan. 3.4. Completeness Completeness refers to the amount of valid data obtained from a measurement system in reference to the amount that could be obtained under ideal conditions. Laboratory completeness is a measure of the number of samples submitted for analysis compared to the number of analyses found acceptable after review of the analytical data. Completeness will be calculated by the following equation: Completeness = (Number of valid data points/total number of measurements) x 100 Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page II of 43 Where the number of valid data points is the total number of valid analytical measurements based on the precision, accuracy, and holding time evaluation. Completeness is detennined at the conclusion of the data validation. Executive Secretary approval will be required for any completeness less than 100 percent. 3.5. Comparability Comparability refers to the confidence with which one set of data can be compared to another measuring the same property. Data are comparable if sampling conditions, collection techniques, measurement procedures, methods, and reporting units are consistent for all samples within a sample set. 4. FIELD SAMPLING QUALITY ASSURANCE METHODOLOGY 4.1. Controlling Well Contamination Well contamination from external surface factors, is controlled by installation of a cap over the surface casing and cementing the surface section of the drill hole. Wells have surface covers of mild steel with a lockable cap cover. Radiation Safety staff has access to the keys locking the wells. Subsurface well stagnation, for pumped wells, is reduced by pumping two well casing volumes of water from the wells, to the extent practicable. This ensures, to the extent practicable, that the aquifer zone water is being drawn into the well and is a representative sample. 4.2. Controlling Depth to Groundwater Measurements Monitoring of depth to groundwater is controlled by comparing historical field log data to actual measurement depth. This serves as a check of the field measurements. 4.3. Water Quality QC Samples Quality assurance for ground water monitoring consists of the following QC samples: 4.3.1. VOC Trip Blanks Trip blanks will be used to assess contamination introduced into the sample containers by volatile organic compounds ("VOCs") through diffusion during sample transport and storage. At a minimum (at least) one trip blank will be in each shipping container containing samples to be analyzed for VOCs. Trip blanks will be prepared by the Analytical Laboratory, transported to the sampling site, and then returned to the Analytical LaboratOlY for analysis Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Date: 4-16-09 Revision-4 Page 12 of43 along with the samples collected during the sampling event. The trip blank will be unopened throughout the transportation and storage processes and will accompany the technician while sampling in the field (DTG, Field and Laboratory Quality Assurance/Quality control, 7.8, pages 7-30, 7-31) 4.3.2. Equipment Rinsate Samples Where a portable (non-dedicated) pump is used, a rinsate sample will be collected prior to using and after decontaminating the sampling equipment at the beginning of each sampling event and at the beginning of each day of the sampling event (TEGD) Field QA/QC Program, page 119). Where a non-dedicated bailer is used a rinsate sample will be collected prior to any well sampling or purging and after decontamination at the beginning of each sampling event and at the beginning of each day of the sampling event. In the case of equipment rinsate blank samples for a pump, the sample will be prepared by pumping de-ionized water into the sample containers. In the case of equipment rinsate blank samples for a non- disposable or non-dedicated bailer, the sample will be prepared by pouring de-ionized water over and through the bailer and into the sample containers. . During quarterly/semi-annual monitoring events, equipment rinsate blanks will need to be analyzed only for the contaminants required during the accelerated monitoring event. 4.3.3. Field Duplicates One Duplicate set of samples submitted with each Batch (defined in Section 4.3.4) of samples (DTG, Field and Laboratory Quality Assurance/Quality Control, 7.8), taken from one of the wells being sampled and will be submitted to the Analytical Laboratory and analyzed for all contaminants listed in Table 2 of the GWDP (EPA SW-846, Chapter 1, Section 3.4.1). 4.3.4. Definition of "Batch" For the purposes of this Plan, a Batch is defined as 20 or fewer samples (PA SW-846, Chapter 1, Section 5.0, page 23). 5. CALIBRATION A fundamental requirement for collection of valid data is the proper calibration of all sample collection and analytical instruments. Sampling equipment shall be calibrated in accordance with manufacturers' recommendations, and Analytical Laboratory equipment shall be calibrated in accordance with Analytical Laboratory procedures. Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) 5.1. Depth to Groundwater Measurements Date:4-16-09 Revision-4 Page 13 of43 Equipment used in depth to groundwater measurements will be checked prior to each use to ensure that the Water Sounding Device is functional. 5.2. Water Quality The Field Parameter Meter will be calibrated prior to each sampling event and at the beginning of each day of the sampling event according to manufacturer's specifications (for example, by using two known pH solutions and one specific conductance standard.) Temperature will be checked comparatively by using a thermometer. Calibration results will be recorded on the Field Data Worksheet. 6. GROUND WATER SAMPLING AND MEASUREMENT OF FIELD PARAMETERS 6.1. Groundwater Head Monitoring 6.1.1. Location and Frequency o/Groundwater Head Monitoring Depth to groundwater shall be measured quarterly in the following wells and piezometers: a) All Point of Compliance wells listed in paragraphs 6.2.1 a), b) and c) below; b) Monitoring wells MW-20 and MW-22; c) All piezometers (P-l, P-2, P-3, P-4 and P-5); d) All chloroform contaminant investigation wells required to be monitored during the quarter under State of Utah Notice of Violation and Groundwater Corrective Action Order UDEQ Docket No. UGQ-20-01, not already included in paragraph (a). On November 17, 2006, such chloroform contaminant investigation wells were the following: • MW-4 • TW4-10 • TW4-1 • TW4-11 • TW4-2 • TW4-12 • TW4-3 • TW4-13 • TW4-4 • TW4-14 • TW4-5 • TW4-16 • TW4-6 • TW4-18 • TW4-7 • TW4-19 • TW4-8 • TW4-20 Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) • TW4-9 • TW4-21 TW4-22; Date:4-16-09 Revision-4 Page 14 of43 e) In any other wells or piezometers required by the Executive Secretary of the Utah Radiation Control Board, as indicated by the Mill's RSO. 6.1.2. Equipment Used For Groundwater Head Monitoring Measurement of depth to groundwater is accomplished by using a Solinist -IT 300 or equivalent device (the "Water Sounding Device"). 6.1.3. Field Sampling Procedure for Groundwater Head Monitoring In the case of any well that is being sampled for groundwater quality, depth to groundwater is measured prior to sampling. Depth to groundwater is measured from the top of the inner well casing, or for the piezometers, from the top of the casing, and is recorded on the Field Data Worksheet for Groundwater described in Section 7.1 (the "Field Data Worksheet"). Readings are taken by lowering the Water Sounding Device into the casing until the Device alarms, indicating that the water surface has been reached. The depth to groundwater is then determined by reference to the distance markings on the line attached to the Device. Data is recorded on the Field Data Worksheet as Depth to Water, to the nearest 0.01 of a foot. 6.2. Ground Water Compliance Monitoring 6.2.1. Location and Frequency of Groundwater Compliance Monitoring Groundwater quality shall be measured in the following wells at the following frequencies: a) Semi-annually in the following Point of Compliance wells: MW-l, MW-2, MW- 3, MW-5, MW-12, MW-15, MW-17, MW-18 and MW-19; b) Quarterly in the following Point of Compliance wells: MW -11, MW -14, MW -20, MW-22, MW-26 and MW-32; and c) Quarterly in the following new Point of Compliance wells, until 8 quarters of background data are obtained: MW-23, MW-24, MW-25, MW-27, MW-28, MW-29, MW-30 and MW-31. Thereafter, these wells will be sampled on a quarterly or semi-annual basis, as required by the GWDP. Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-l6-09 Revision-4 Page 15 of43 d) Chlorofonn Investigation sampling will collected from the locations and at the frequencies listed at Item 2) in the Chloroform Investigation Monitoring Quality Assurance Program (Appendix A to this document) In addition, quarterly or monthly sampling may be required for certain parameters in certain wells for which accelerated monitoring is required under paragraph I.G.I or I.G.2 of the GWDP. It is important to confinn with the Mill's RSO prior to conducting any monitoring well sampling, whether or not any parameters in any wells are subject to this accelerated monitoring. 6.2.2. Quarterly and Semi-Annual Sampling Required Under Paragraphs I.E.I.a) or I.E.I.b) o/the GWDP All quarterly and semi-annual samples collected under paragraphs 6.2.1 a), b) and c) above (paragraphs I.E.I.a) or I.E.I.b) of the GWDP) shall be analyzed for the following parameters: a) Field parameters -depth to groundwater, pH, temperature, specific conductance, redox potential (Eh) and turbidity in the manner specified in paragraph 6.2.7 d) (v); and b) Laboratory Parameters: (i) All parameters specified in Table 2 of the GWDP; and (ii) General inorganics -chloride, sulfate, carbonate, bicarbonate, sodium potassium, magnesium, calcium, and total anions and cations. 6.2.3. Quarterly or Monthly Sampling Required Under Paragraphs I.G.I or I.G.2 o/the GWDP Any quarterly or monthly sampling required under paragraphs I.G.I. or I.G.2. of the GWDP shall be in the wells and for the specific parameters required by those paragraphs of the GWDP, as specified by the Mill's RSO. Mill -Groundwater Discharge Pennit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 16 of43 6.2.4. Sampling Equipment/or Groundwater Compliance Monitoring . All equipment used for purging and sampling of groundwater which enters the well or may otherwise contact sampled groundwater, shall be made of inert materials. For the purposes of this QAP the following equipment definitions shall apply: • Dedicated Bailer: A bailer that is dedicated to be used at one specific well for the use of purging or sampling. Said bailer well remain with and in side the well casing suspended and secured. • Non -Dedicated Bailer: A bailer that is used for purging and sampling at one or more well. • Dedicated Pump: A pump that is dedicated to one specific well for the use of purging or sampling. Said pump well remain with and in side the well casing suspended and secured. • Non -Dedicated Pump: A pump that is used for purging and sampling at one or more wells. Groundwater compliance monitoring IS accomplished by usmg the equipment, or the equivalent listed below a) Bailer made of inert materials for purging (DTG, 7.3, page 7-10) b) If a dedicated pump is installed in the well, use the dedicated pump, otherwise use a 1.8 inch (outside diameter) air-driven sampling pump, or equivalent; c) 150 psi air compressor and ancillary equipment, or equivalent; d) Field parameters shall be measured using a YSI-556 with Flow Cell Multi- Parameter Meter system or equivalent that allows a continuous stream of water from the pump to the meter that enables measurements to be taken on a real-time basis without exposing the water stream to the atmosphere. The Field Parameter Meter measures the following parameters: (i) Water temperature; (ii) Specific conductivity; (iii)Total Dissolved Solids (TDS); (iv) Standard pH; (v) Redox potential (Eh). Field parameters are measured by using a flow cell system that enables the measurements to be taken on a real-time basis without exposing the water stream to the atmosphere; Mill-Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page 17 of43 e) Turbidity measuring instrument capable of determining if turbidity is:::: 5 NTU; f) 0.45 micron high capacity disposable inline filters; g) Field preservation chemicals (as provided by the Analytical Laboratory); h) Five gallon calibrated sample bucket; i) Stopwatch; j)Sea1ed sterile Polyethylene sample containers as provided by the Analytical Laboratory; k) De-ionized water; 1) One new, unused, clean disposable single check valve bailer, or the equivalent, for each well to be sampled for VOCs; and m) If any portable (non-dedicated) pumps are used, the following equipment, supplies and solutions, or the equivalent, necessary for decontamination procedures: (i) 15 gallons of de-ionized water (ii) 5 gallons of de-ionized water/nonphosphate detergent (such as Liqui-Nox); (iii)5 gallons of de-ionized water/HN03 solution (a mixture of approximately 4 and 112 gallons of de-ionized water and Yz gallon ofHN03); (iv)Rubber gloves; and (v) Sterile sample containers from the Mill laboratory. 6.2.5. Decontamination Procedure If a portable (non-dedicated) pump is to be used, prior to each sampling event, at the beginning of each day during the sampling event, and between each sampling location (well), decontaminate the portable (non-dedicated) sampling pump prior to its use for purging or sampling using the following procedure: a) wash the pump probe, probe sheath and other pump equipment that may come in contact with the sampling well inner casing or well water (the "Sampling Equipment") with a nonphosphate detergent; b) rinse the Sampling Equipment with de-ionized water; c) rinse the Sampling Equipment with dilute (.IN) hydrochloric or nitric acid; and Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) d) rinse the Sampling Equipment with de-ionized water. Date:4-16-09 Revision-4 Page 18 of43 The probe should then be placed in the decontaminated probe sheath, or otherwise protected from contamination until used for purging or sampling. All water produced during decontamination will be containerized. Containerized water will be disposed of in Tailings Cell 1. All sampling and purging equipment that has been decontaminated as per the foregoing procedure shall be covered with a plastic sheet to shield such equipment from dust or other materials that may contaminate the equipment when traveling to and between purging/sampling locations. 6.2.6. Pre-Purging/Sampling Activities a) If a portable (non-dedicated) pump is to be used, prior to commencing the event's sampling activities, check the pumping equipment to ensure that no air is leaking into the discharge line, in order to prevent aeration of the sample; b) If a portable (non-dedicated) pump is to be used, prior to each sampling event and at the beginning of each day during the sampling event, decontaminate the sampling pump using the procedure set forth in Section 6.2.5; c) If a portable (non-dedicated) pump is to be used, after completion of decontamination and prior to the beginning of each day of each sampling event, prepare one Equipment Rinsate Sample by following the procedure set forth in Section 4.3.2; and d) Prior to leaving the Mill office, place the Trip Blank(s) into a cooler that will preserve the VOC samples. The Trip Blank(s) will accompany the groundwater samplers throughout the monitoring event. 6.2.7. Well Purging/Measurement of Field Parameters a) Remove the well casing cap and measure and record depth to groundwater by following the procedures set out in paragraph 6.1.3 above; b) Determine the casing volume (V) in gallons, where h is column height of the water in the well (calculated by subtracting the depth to groundwater in the well fi:om the total depth of the well), V= O.653*h, for a 4" casing volume and V = .367*h for a 3" casing volume. Record the casing volume on the Field Data Worksheet; c) If the RSO has advised the field technician that immiscible contaminants (i.e., LNAPLs or DNAPLs) are known to occur or could potentially occur in the Mill-Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-l6-09 Revision-4 Page 19 of43 subsurface at the location of the well, follow the additional procedures, to be provided by the RSO, prior to well purging; d) Purging, Where Use of Pump is Effective (See paragraph 6.2.7 e)) below, where bailer is required) If a portable (non-dedicated) pump is used, ensure that it has been decontaminated in accordance with Section 6.2.5 since its last use in a different well, lower the pump into the well, making sure to keep the pump at least five feet from the bottom of the well. Be sure never to drop the pump into the well, as this will cause degassing of the water upon impact. Once the pump is lowered into the well, or if the well has a dedicated pump, perform the following steps: (i) Commence pumping; (ii) Determine pump flow rate by using a stopwatch and a calibrated bucket by measuring the number of seconds required to fill to the one-gallon mark. Record this in the "pumping rate" section of the Field Data Worksheet; (iii)Calculate the amount of time to evacuate two casing volumes; (iv)Evacuate two casing volumes (if possible) by pumping for the length of time determined in paragraph (iii); (v) Take measurements of field parameters (pH, specific conductance, temperature, redox potential and turbidity) during well purging, using the Field Parameter Meter and turbidity measuring instrument. These measurements will be recorded on the Field Data Worksheet. Purging is completed after two casing volumes have been removed and the field parameters pH, temperature, specific conductance, redox potential (Eh) and turbidity have stabilized to within 10% over at least two consecutive measurements. The groundwater in the well should recover to within at least 90% of the measured groundwater static surface before sampling. In addition, turbidity measurement in the water should be .:S 5 NTU prior to sampling (DTG Well Development 6.7, page 6-48) unless the well is characterized by water that has a higher turbidity. A flow-cell needs to be used for field parameters. If the well is purged to dryness or is purged such that full recovery exceeds two hours, the well should be sampled as soon as a sufficient volume of groundwater is available to fill sample containers (DTG, Well Purging, 7.2.4, page 7-9); (vi) If the well yields two casing volumes, the individual performing the sampling should immediately proceed to Section 6.2.8); Mill-Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) (vii) If the well cannot yield two casing volumes, Date:4-16-09 Revision-4 Page 20 of43 A. Evacuate the well to dryness and record the number of gallons evacuated on the Field Data Worksheet; and B. Prior to sampling, measure and record depth to groundwater on the Field Data Worksheet following the procedures set out in paragraph 6.1.3 above; e) Purging, Where Use of Pump is Not Effective For wells where a pump is not effective for purging and/or sampling (wells with shallow water columns, i.e., where the water column is less than five feet above the bottom of the well casing or the well takes over two days to recover from purging), a disposable bailer, made of inert materials, may be used. If a bailer is used, the following procedure will be followed: (i) Use the sound level instrument to determine the water column and figure the amount of water that must be evacuated; (ii) Attach a 3" disposable bailer to a rope and reel; (iii)Lower the bailer into the well and listen for contact with the solution. Once contact is made, allow the bailer to gradually sink in the well, being careful not to allow the bailer to come in contact with the bottom sediment; (iv) After the bailer is full, retrieve the bailer and discharge the water from the bailer into 5 gallon buckets. By doing this, one can record the number of gallons purged; (v)After the bailer is emptied, lower the bailer back into the well and gain another sample as before. This process will continue until the two casing volumes have been collected or until no more water can be retrieved. When the process is finished for the well, the bailer will be disposed of; and (vi)Take field measurements referred to in paragraph 6.2.7 (v) above from the water in the buckets; Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 6.2.8. Samples to be taken and order a/taking samples Date:4-16-09 Revision-4 Page 21 of43 For each sampling event, unless sampling for a specific parameter under the accelerated monitoring requirements of paragraphs LG.1 or LG.2 of the GWDP as specified by the RSO, the following separate samples shall be taken in the following order from each monitoring well: a) VOCs,3 sample containers, 40 ml each, (a bailer is used); b) Nutrients (ammonia, nitrate and nitrite), 1 sample container, 100 ml (a bailer is used); c) Heavy metals, 1 sample container, 250 ml, filtered; d) All other non-radiologics (fluoride, general inorganics, TDS, total cations and anions), 1 sample container, 250 ml, filtered; and e) Gross alpha, 1 sample container, 1,000 ml, filtered. f) The sample collection containers and sample volumes for chloroform sampling are specified at Item 3) of the Chloroform Investigation Monitoring Quality Assurance Program (Appendix A to this document) The number of sample containers and the quantities taken shall be as set out above, unless otherwise dictated by the Analytical Laboratory, as specified by the RSO. 6.2.9. Field Duplicate Samples a) One duplicate set of samples is required for each Batch of samples (see Section 4.3.4) for definition of Batch) (EPA SW-846, Chapter 1, Section 3.4.1). Field duplicate samples will be analyzed for the contaminants listed in Table 2 of the GWDP; b) The duplicate samples should be as near to split samples as reasonably practicable, rather than merely taking a second set of samples from the same well after the field samples have been taken from that well. This can be accomplished by alternately partially filling the field sample containers and duplicate containers until both sets of containers are full. MiU-Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) 6.2.10. VOCs and Nutrient Sampling Date:4-16-09 Revision-4 Page 22 of43 When sampling for VOCs and Nutrients, the following procedure shall be followed: a) Obtain specifically identified sample containers for the type of sample to be taken, as provided by the Analytical Laboratory; b) Add the quantity of specified preservative provided by the Analytical Laboratory to each sample container; c) Sample the well using an unused, clean, disposable, single check valve bailer, or the equivalent; d) Sample water should be transferred to sample containers in a controlled manner that will minimize sample agitation and aeration; e) In the case of VOC samples, be sure that the sample containers are filled as full as possible with no airspace in the containers; f) After each sample container is filled, rinse the lid of the container with water, and tighten lid onto container; and, g) Discard the bailer. 6.2.11. Heavy Metals, All Other Non-Radiologies and Gross Alpha Sampling When sampling for heavy metals, all other non-radiologics and for gross alpha, the following procedure shall be followed: a) Obtain the specifically identified sample container for the type of sample to be taken, as provided by the Analytical Laboratory; b) Add the quantity of specified preservative provided by the Analytical Laboratory to each sample container; c) When using a pump to sample (wells without shallow water columns, i.e., where the water column is more than five feet above the bottom of the well casing or the well takes less than two days to recover from purging): (i) Place a new 0.45 micron filter on the sample tubing; Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page 23 of43 (ii) Pump the sample through the filtration unit, and into the sample container at the same rate or a lesser pumping rate than was used to purge the well; (iii)The pump should be operated in a continuous manner so that it does not produce samples that are aerated in the return tube or upon discharge; (iv)Remove pump from the well; and (v) If using a portable (non-dedicated pump), decontaminate pump as per Section 6.2.5. Do not place decontaminated pump on the ground or on other contaminated surfaces; d) When using a bailer to sample (wells with shallow water columns, i.e., where the water column is less than five feet above the bottom of the well casing or the well takes over two days to recover from purging), then one of the following two procedures will be used: (i) Filtering Water Samples at the Well Head A. The sample water is collected by use of a 3 inch Teflon bailer, or the equivalent, that is capable of being attached to a hand-operated pressure pump, or the equivalent. Only disposable parts of the pressure pump may come into contact with the sample water; B. Attach the pump to the disposable bailer and activate the pump in accordance with manufacturer's instructions, such that the sample water in the bailer is forced through a clean, un-used, disposable 0.45 micron filter into a clean previously unused sample container, in a manner such that only disposable parts of the pump mechanism come into contact with the sample water; C. Sample water should be transferred to sample containers in a controlled manner that will minimize sample agitation and aeration; D. Rinse lid of sample container with any remaining filtered water, after container is filled with filtered water, and tighten lid onto container; E. Unless dedicated to a particular well, dispose of the bailer, filter and any parts of the pump mechanism that come into contact with the sample water; and F. No rinsate sample is needed, because everything that comes into contact with the sample water is clean and unused prior to sampling, and disposed of after sampling the well; (ii) Filtering Water Samples at the Mill Laboratory Mill -Groundwater Discharge Pennit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 24 of43 A. A new, clean 1 gallon raw sample container must be used to capture waters needed to be filtered; B. The sample water is collected by use of a 3 inch Teflon bailer, or the equivalent, and then discharged into the 1 gallon container; c. After all the samples have been collected for the well and placed in the field sample container, which contains blue ice to keep the samples at the required temperature, the sampler will then proceed directly back to the Mill laboratory and perform the filtration on the sample; D. Unless the bailer is dedicated to a particular well, it will be disposed of after completion of sampling in the well; E. Upon arrival at the administration building, all other samples from the well (that do not require filtration) will be placed in the sample holding refrigerator in the locked sample storage room; F. The sampler will then carry the sample that requires filtration in the cooler to the laboratory and set up the equipment to be used for filtration of the sample; G. The equipment needed for this process consists of: • 2000 ml glass filter flask • 250 ml bell and glass frit for a micro-filtration 0.45 micron filter setup • 0.45 micron filter paper H. The glass filter flask and micro-filtration equipment will go through a cleaning and rinsate process. The processing will included the following: • Rinsing of the equipment using DI water • Rinsing the equipment with a mixture ofDI water and HN03 • Rinsing the equipment with a mixture ofDI water and Liqui- Nox soap • Rinsing the equipment with DI water • Finally the collection of the final process rinsate solutions are placed in the sample collection cooler and labeled as a filtration equipment rinsate sample; 1. The flask is attached to the vacuum system in the laboratOlY using Tygon Vacuum Tubing, or the equivalent; J. The micro-filtration system is then inserted into the filter flask; K. A 0.45 micron filter paper is then placed between the bell and the glass frit and clamped in place to prevent solution leaking out; L. The water sample is then slowly added into the bell and the vacuum is turned on; M. As the vacuum draws the water through the filter paper, additional solutions are added until the flask is full; Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page 25 of43 N. When the flask is full, the vacuum is turned off and the bell is unclamped from the frit. The Tygon tubing is then removed from the flask. The glass frit is then pulled out of the flask; O. The filtered solutions are then poured into the various remaining sample collection bottles. Sample water should be transferred to sample containers in a controlled manner that will minimize sample agitation and aeration; P. Rinse lid of sample container with any remaining filtered water, after container is filled with filtered water, and tighten lid onto container; Q. If additional filtered water is required to complete the sample requirements, the sample bottles will be placed in the field cooler along with the raw sample and housed there while the filtration system is being hooked back up and the procedures set out in paragraphs I to P above are repeated until sufficient sample water has been filtered to fill up the required number of sample bottles; R. After all samples from the well that require filtration have been filtered in accordance with the foregoing procedure and placed in the proper sample bottles, the remainder of the raw sample is then discharged into the laboratory sink, which runs to tails; and S. The filtered samples are then transported to the locked sample storage room and placed in the sample holding refrigerator. The time lapse between the actual sampling times to the completion of the filtration process is approximately 12 hour. Samples are always in the field sample container, except for when the raw sample is pulled from the cooler and poured in the bell on the filter flask. 6.2.12. Procedures to Follow After Sampling a) In each case, once a sample is taken, identify and label the sample container with: • Sample location/facility • Date and time of sample • Any preservation method utilized • Sampler's initials • Filtered or unfiltered • Parameters requested to be analyzed b) Place each sample in an ice-packed cooler, immediately upon taking the sample and labeling the sample container; c) Replace the casing cap on the well. Lock the well; Mill-Groundwater Discharge Permit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 26 of43 d) Before leaving the sampling location, thoroughly document the sampling event on the Field Data Worksheet, by recording the items required in paragraph 7.1; and e) Upon returning to the office, the samples must be stored in a refrigerator at less than or equal to 6° C. These samples shall be received by the Analytical Laboratory at less than or equal to 6° C. Samples will then be re-packed in the plastic ice-packed cooler and transported via these sealed plastic containers by postal contract services to the Analytical Laboratory. 7. SAMPLE DOCUMENTATION TRACKING AND RECORD KEEPING 7.1. Field Data Worksheets Documentation of observations and data from sampling provide important information about the sampling process and provide a permanent record for sampling activities. All observations and field sampling data will be recorded in waterproof ink on the Field Data Worksheets, which will be maintained on file at the Mill. The Field Data Worksheets will contain the following information: • Name of the site/facility • description of sampling event • location of sample (well name) • sampler's name(s) and signature(s) • date(s) and time(s) of well purging and sample collection • type of well purging equipment used (pump or bailer) • previous well sampled during the sampling event • well depth • depth to groundwater before purging and sampling • results of in-field measurements (pH, specific conductance, water temperature) • redox potential (Eh) measurements • turbidity measurements • calculated well casing volume • volume of water purged before sampling • volume of water purged when field parameters are measured • type and condition of well pump • description of samples taken • sample handling, including filtration and preservation • volume of water collected for analysis • types of sample containers and preservatives Mill-Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) • weather conditions and external air temperature • name of certified Analytical Laboratory. Date:4-16-09 Revision-4 Page 27 of43 The Field Data Worksheets will also contain detailed notes describing any other significant factors during the sampling event, including, as applicable: condition of the well cap and lock; water appearance, color, odor, clarity; presence of debris or solids; any variances from this Procedure; and any other relevant feature or condition. An example of a form of Field Data Worksheet that incorporates this infOlmation is attached as Attachment 1. 7.2. Chain-Of-Custody and Analytical Request Record A Chain-of-Custody and Analytical Request Record form (the "COC Form"), provided by the Analytical Laboratory, will accompany the samples being shipped to the Analytical Laboratory. An example of the Analytical Laboratory's Chain of Custody Form is attached as Attachment 2. If the Chain of Custody Form changes at any time, the Company shall provide a copy of the new or revised Chain of Custody FOlm to the Executive Secretary and substitute the new form for the old fOlm in Attachment 2. Standard Chain-of-Custody protocol is initiated for each sample set. A COC FOlm is to be completed for each set of samples collected in a shipping container (cooler) and is to include the following: • sampler's name • company name • date and time of collection • sample type (e.g., water) • sample location • number of sample containers in the shipping container • analyses requested • signatures of persons involved in the chain of possession • internal temperatures of the shipping container when opened at the laboratory • remarks section to identify potential hazards or to relay other information to the Analytical Laboratory. Chain-of-Custody reports will be placed inside a re-sealable bag and taped to the inside lid. Custody seals will be placed on the outside of each cooler. The person shipping the samples to the Analytical Laboratory will sign the COC Form, document shipment method, and send the original and the second copy of the COC FOlm with the samples. Upon receipt of the samples, the person receiving the samples will sign the COC Form and return the second copy to the Mill's RSO. Copies of the COC Forms and other relevant documentation will be retained at the Mill. Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) 7.3. Record Keeping The Field Data Worksheets are retained at the Mill. Date:4-16-09 Revision-4 Page 28 of43 Original Certificates of Analysis from the Analytical Laboratory, showing the laboratory analytical results for the water samples, are maintained at the Mill. Once all the data for the quarter (all wells sampled during the quarter) is completed, key data from the Field Data Worksheets and from the Certificates of Analysis are typed into a computer file. Key data entered into the computer file will include well I.D., sample date, depth to groundwater, average field data, and all laboratory analytical data. These computer files are maintained at the Mill. 8. ANAL YTICAL PROCEDURES AND QA/QC Analytical Laboratory QA provides a means for establishing consistency in the performance of analytical procedures and assuring adherence to analytical methods utilized. Analytical Laboratory QC programs include traceability of measurements to independent reference materials and internal controls. 8.1. Analytical Quality Control Analytical QA/QC will be governed by the QA/QC program of the Analytical Laboratory. In choosing and retaining the Analytical Laboratory, DUSA shall ensure that the Analytical Laboratory is certified by the State of Utah and by NELAP and/or NAVLAP, is capable of performing the analytical procedures specified in Section 8.2, and that the QA/QC program of the Analytical Laboratory includes the spikes, blanks and duplicates described in Section 8.1.2. 8.1.2. Spikes, Blanks and Duplicates Analytical Laboratory QC samples will assess the accuracy and precision of the analyses. The following describes the type of QC samples that will be used by the Analytical Laboratory to assess the quality of the data. The following procedures shall be performed at least once with each Batch of samples: a) Duplicate Spike (Matrix Spike) A split/spiked field sample shall be analyzed with every analytical batch. Analytes stipulated by the analytical method, by applicable regulations, or by other specific requirements must be spiked into the sample. Selection of the sample to be spiked and/or split depends on the information required and the variety of conditions within a Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page 29 of43 typical matrix. The duplicate spike (matrix spike) sample serves as a check evaluating the effect of the sample matrix on the accuracy of analysis. b) Blanks Each batch shall be accompanied by a reagent blank. The reagent blank shall be carried through the entire analytical procedure. Contamination detected in analysis of reagent blanks will be used to evaluate any Analytical Laboratory contamination of environmental samples which may have occun-ed. c) Field Samples/Sun-ogate Compounds Every blank, standard, and environmental sample (including matrix spike/matrix duplicate samples) shall be spiked with surrogate compounds prior to purging or extraction. Sun-ogates are organic compounds which are similar to analytes of interest in chemical composition, extraction, and chromatography, but which are not normally found in environmental samples. Surrogates shall be spiked into samples according to the appropriate organic analytical methods. d) Check Sample Each analytical batch shall contain a number of check samples. For each method, the Analytical Laboratory will normally analyze the following check samples or their equivalents: a method blank, a laboratory control spike, a matrix spike, and a matrix spike duplicate, or the equivalent, with relative percent difference reported. 8.2. Analytical Laboratory Procedures The analytical procedures to be used by the Analytical Laboratory will be as specified in Table 1, or as otherwise authorized by the Executive Secretary. With respect to Chloroform Investigation sampling, the analytical procedures for parameters monitored under that program are specified at Item 4) of the ChlorofOlm Investigation Monitoring Quality Assurance Program (Appendix A to this document) Mill -Groundwater Discharge Pelmit Groundwater Monitoring Quality Assurance Plan (QAP) Contaminant Analytical Methods to be Used Nutrients Ammonia (as N) A4500- NH3G Nitrate & Nitrite E353.2 (as N) Heavy Metals Arsenic E200.8 Beryllium E200.8 Cadmium E200.8 Chromium E200.8 Cobalt E200.8 Copper E200.8 Iron E200.7 Lead E200.8 Manganese E200.8 Mercury E200.8 Molybdenum E200.8 Nickel E200.8 Selenium E200.8 Silver E200.8 Thallium E200.8 Tin E200.8 Uranium E200.8 Vanadium E200.8 Zinc E200.8 Radiologics Gross Alpha E900.1 Volatile Organic Compounds Acetone SW8260B Benzene SW8260B 2-Butanone SW8260B Date:4-16-09 Revision--4 Page 30 of43 Table 1 Reporting Maximum Sample Sample Limit! Holding Preservation Temperature Times Requirements Requirements 0.05 mglL 28 days H2S04 to ::; 6°C pH<2 0.1 mglL 28 days H2S04 to ::; 6°C pH<2 5 !J,glL 6 months HN03 to pH<2 None 0.50 !J,glL 6 months HN03 to pH<2 None 0.50 !J,glL 6 months HN03 topH<2 None 25 !J,glL 6 months HN03 to pH<2 None 10 !J,glL 6 months HN03 to pH<2 None lOllgiL 6 months HN03 to pH<2 None 30 11 giL 6 months HN03 to pH<2 None 1.01lgiL 6 months HN03 topH<2 None lOllgiL 6 months HN03 to pH<2 None 0.50 !J,g/L 28 days HN03 to pH<2 None 10 11 giL 6 months HN03 to pH<2 None 20 !J,glL 6 months HN03 topH<2 None 5 !J,glL 6 months HN03 to pH<2 None 10 !J,g/L 6 months HN03 to pH<2 None 0.50 !J,glL 6 months HN03 to pH<2 None 100 !J,glL 6 months HN03 topH<2 None 0.30 !J,glL 6 months HN03 to pH<2 None 15 !J,g/L 6 months HN03 to pH<2 None 10 !J,glL 6 months HN03 to pH<2 None 1.0 pCi/L 6 months HN03 to pH<2 None 20 !J,glL 14 days HCI to pH<2 ::; 6°C 1.0 !J,glL 14 days HCI to pH<2 ::; 6°C 20 !J,glL 14 days HCI to pH<2 ::; 6°C Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) Contaminant Analytical Methods to be Used (MEK) Carbon SW8260B Tetrachloride Chloroform SW8260B Chloromethane SW8260B Dichloromethane SW8260B (Methylene Chloride) Naphthalene SW8260B Tetrahydrofuran SW8260B Toluene SW8260B Xylenes (total) SW8260B Others Field pH (S.U.) A4500-H B Fluoride A4500-F C TDS A2540 C General Inorganics Chloride A4500-Cl B Sulfate A4500- S04E Carbonate as A2320 B C03 Bicarbonate as A2320 B HC03 Sodium E200.7 Potassium E200.7 Magnesium E200.7 Calcium E200.7 Date:4-16-09 Revision-4 Page 31 of43 Reporting Maximum Sample Sample Limitl Holding Preservation Temperature Times Requirements Requirements 1.0~g/L 14 days HCl to pH<2 :S 6°C 1.0~g/L 14 days HCl to pH<2 :S 6°C 1.0~g/L 14 days HCl to pH<2 <6°C 1.0~g/L 14 days HCl to pH<2 :S 6°C 1.0~g/L 14 days HCl to pH<2 <6°C 1.01lg/L 14 days HCl to pH<2 <6°C 1.0~g/L 14 days HCl to pH<2 :S 6°C 1.0~g/L 14 days HCl to pH<2 :S 6°C 0.01 s.u. Immediate None None 0.1 mg/L 28 days None None 10 mg/L 7 days None :S 6°C 1 mg/L 28 days None None 1 mg/L 28 days None :S 6°C 1 mg/L 14 days None :S 6°C 1 mg/L 14 days None :S 6°C 0.5 mg/L 6 months HN03 to pH<2 None 0.5 mg/L 6 months HN03 to pH<2 None 0.5 mg/L 6 months HN03 topH<2 None 0.5 mg/L 6 months HN03 to pH<2 None .. 1. The Analyttcal Laboratory wIll be reqUlred to meet the reportmg hmits ("RLs") m the foregomg Table, unless the RL must be increased due to sample matrix interference (i.e., due to dilution gain), in which case the increased RL will be used, or unless otherwise approved by the Executive Secretary. Mill -Groundwater Discharge Permit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 32 of43 9. INTERNAL QUALITY CONTROL CHECKS Internal quality control checks are inherent in this Plan. The QA Manager will monitor the performance of the Sample and QC Monitors, and, to the extent practicable, the Analysis Monitor to ensure that they are following this Plan. In addition, either the QA Manager or a Sampling and QC Monitor will review and validate the analytical data generated by the Analytical Laboratory to ensure that it meets the DQOs established by this Plant. Finally, periodic system and performance audits will be performed, as detailed in Section 12 below. 9.1. Field QC Check Procedures The QA Manager will perform the following QA/QC analysis of field procedures: 9.1.1. Review of Compliance With the Procedures Contained in this Plan Observation of technician performance is monitored by the QA Manager on a periodic basis to ensure compliance with this Plan. 9.1.2. Analyte Completeness Review The QA Manager will review all Analytical Results to confirm that the analytical results are complete (i.e., there is an analytical result for each required constituent in each well). The QA Manager shall also identify and report all instances of non-compliance and non- conformance (see Part I.E. 1. (a) of the Permit. Executive Secretary approval will be required for any completeness (prior to QA/QC analysis) less than 100 percent. Non-confonnance will be defined as a failure to provide field parameter results and analytical results for each parameter and for each well required in Sections 6.2.2 and 6.2.3, for the sampling event, without prior written Executive Secretary approval. 9.1.3. Blank Comparisons Trip blanks, and equipment rinsate samples will be compared with original sample results. Non-conformance conditions will exist when contaminant levels in the blank(s)/samples(s) are within an order of magnitude of the original sample result. (TEGD, Field QA/QC Program, page 119). 9.1.4. Duplicate Sample Comparisons The following analyses will be performed on duplicate field samples: Mill -Groundwater Discharge Pelmit Groundwater Monitoring Quality Assurance Plan (QAP) a) Relative Percent Difference. Date:4-16-09 Revision--4 Page 33 of43 RPDs will be calculated in comparisons of duplicate and original field sample results. Non-conformance will exist when the RPD ~20%, unless the measured activities are less than 5 times the required detection limit (Standard Methods, 1998) (EPA Contract Laboratory Program National Functional Guidelines for Inorganic Data Review, February 1994,9240.1-05-01, p. 25). b) Radiologies Counting Enor Term All gross alpha analyses shall be reported with an error term. All gross alpha analysis reported with an activity equal to or greater than the GWCL, shall have a counting variance that is equal to or less that 20% of trhe reported activity concentration. An error term may be greater than 20% of the reported activity concentration when the sum of the activity concentration and enol' telm is less than or equal to the GWCL. c) Radiologies, Duplicate Samples Comparability of results between the original and duplicate radiologic samples will be evaluated by determining compliance with the following formula: Where: A = the first duplicate measurement B = the second duplicate measurement sa2 = the uncertainty of the first measurement squared sb2 = the uncertainty of the second measurement squared Non-conformance exists when the foregoing equation is 2: 2. (EP A Manual for the Certification of Laboratories Analyzing Drinking Water, Criteria and Procedures Quality Assurance, January 2005, EPA 815-R-05-004, p. VI-9). If the QA Managers review finds any situations of non-conformance, see Section 10. Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) 9.2. Analytical Laboratory QA Reviews Date:4-16-09 Revision-4 Page 34 of43 Full validation will include recalculation of raw data for a minimum of one or more analytes for ten percent of the samples analyzed. The remaining 90% of all data will undergo a QC review which will include validating holding times and QC samples. Overall data assessment will be a part of the validation process as well. The Analysis Monitor or data validation specialist will evaluate the quality of the data based on SW-846, the applicable portions of NRC guide 4.14 and on analytical methods used. The reviewer will check the following: (1) sample preparation information is correct and complete, (2) analysis information is correct and complete, (3) appropriate Analytical Laboratory procedures are followed, (4) analytical results are correct and complete, (5) QC samples are within established control limits, (6) blanks are within QC limits, (7) special sample preparation and analytical requirements have been met, and (8) documentation is complete. The Analytical Laboratory will prepare and retain full QC and analytical documentation. The Analytical Laboratory will report the data as a group of one batch or less, along with the QA/QC data. The Analytical Laboratory will provide the following information: (1) cover sheet listing samples included in report with a narrative, (2) results of compounds identified and quantified, and (3) reporting limits for all analytes. Also to be included are the QA/QC analytical results. 9.3. QA Manager Review of Analytical Laboratory Results and Procedures. The QA Manager shall perform the following QA reviews relating to Analytical Laboratory procedures: a) Reporting Limit (RL) Comparisons The QA Manager shall confirm that all reporting limits used by the Analytical Laboratory are in conformance with the reporting limits set out on Table 1. Non-conformance shall be defined as: 1) a reporting limit that violates these provisions, unless the reporting limit must be increased due to sample matrix interference (i.e., due to dilution gain); or 2) a reporting limit that exceeds the respective GWQS listed in Table 2 of the GWDP. b) Laboratory Methods Review The QA Manager shall con film that the analytical methods used by the Analytical Laboratory are those specified in Table 1, unless otherwise approved by the Executive Secretary. Non- confOlmance shall be defined when the Analytical Laboratory uses analytical methods not listed in Table 1 and not otherwise approved by the Executive Secretary. Mill -Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) c) Holding Time Examination Date:4-16-09 Revision-4 Page 35 of43 The QA Manager will review the analytical reports to verify that the holding time for each contaminant was not exceeded. Non-conformance shall be defined when the holding time is exceeded. d) Sample Temperature Examination The QA Manager shall review the analytical reports to verify that the samples were received by the Analytical Laboratory at a temperature no greater than the approved temperature listed in Table 1. Non-conformance shall be defined when the sample temperature is exceeded. 9.4. Analytical Data All QA/QC data and records required by the Analytical Laboratory's QA/QC program shall be retained by the Analytical Laboratory and shall be made available to DUSA as requested. Analytical data submitted by the Analytical Laboratory should contain the date/time the sample was collected, the date/time the sample was received by the Analytical Laboratory, the date/time the sample was extracted (if applicable), and the date/time the sample was analyzed. All out-of-compliance results will be logged by the Analysis Monitor with corrective actions described as well as the results of the cOlTective actions taken. All raw and reduced data will be stored according to the Analytical Laboratory's record keeping procedures and QA program. All Analytical Laboratory procedures and records will be available for on-site inspection at any time during the course of investigation. lfre-runs occur with increasing frequency, the Analysis Monitor and the Mill's QA Manager will be consulted to establish more appropriate analytical approaches for problem samples. 10. CORRECTIVE ACTION 10.1. When Corrective Action is Required The Sampling and QC Monitors and Analytical Laboratory are responsible for following procedures in accordance with this Plan. COlTective action should be taken for any procedure deficiencies or deviations noted in this Plan. All deviations from field sampling procedures will be noted on the Field Data Worksheets or other applicable records. Any QA/QC problems that arise will be brought to the immediate attention of the QA Manager. Analytical Laboratory deviations will be recorded by the Analysis Monitor in a logbook as well. Mill -Groundwater Discharge Permit Groundwater Monitoring Date:4-16-09 Revision--4 Quality Assurance Plan (QAP) Page 36 of43 When non-confOlmance is identified, DUSA shall: a) When non-confOlmance occurs as specified in Sections 9.1.3, 9.1.4 or 9.3, the data shall be qualified to denote the problem. In addition, DUSA shall determine the root cause, and provide specific steps to resolve problems(s) in accordance with the procedure set forth in Section 10.2. Any non-conformance with QAP requirements in a given quarterly ground water monitoring period will be corrected and reported to the Executive Secretary on or before submittal of the next quarterly ground water monitoring report. b) When a sample is lost, sample container broken, or the sample or analyte was omitted, resample within 10 days of discovery and analyze again in compliance with all requirements of this Plan. The results for this sample(s) should be included in the same quarterly monitoring report with other samples collected for the same sampling event; and c) For any other material deviation from this Plan, the procedure set forth in Section 10.2 shall be followed. 10.2. Procedure for Corrective Action The need for cOlTective action for non-conformance with the requirements of this Plan, may be identified by system or performance audits or by standard QA/QC procedures. The procedures to be followed if the need for a cOlTective action is identified, are as follows: a) Identification and definition of the problem; b) Assignment of responsibility for investigating the problem; c) Investigation and determination of the cause of the problem; d) Determination of a cOlTective action to eliminate the problem; e) Assigning and accepting responsibility for implementing the corrective action; f) Implementing the cOlTective action and evaluating its effectiveness; and g) VerifYing that the cOlTective action has eliminated the problem. The QA Manager shall ensure that these steps are taken and that the problem which led to the cOlTective action has been resolved. A memorandum explaining the steps outlined above will be placed in the applicable monitoring files and the Mill Central Files, and the cOlTective action will be documented in a Report prepared in accordance with Section 11. Mill-Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) 11. REPORTING Date:4-16-09 Revision-4 Page 37 of43 As required under paragraph I.F.1 of the GWDP, the Mill will send a groundwater monitoring report to the Executive Secretary on a quarterly basis. Both the Routine Groundwater Monitoring Reports (pertinent to Part LF.1 of the Permit) and Chloroform Investigation Reports shall be submitted according to the following schedule: Quarter Period Due Date First January -March June 1 Second April-June September 1 Third July -September December 1 Fourth October -December March 1 The Routine Groundwater Monitoring Reports (pertinent to Part LF.1 of the Permit) will include the following information: • Description of monitor wells sampled • Description of sampling methodology, equipment an decontamination procedures to the extent they differ from those described in this Plan • A summary data table of historic groundwater levels for each monitor well and piezometer • A summary data table showing the results of the sampling event, listing all wells and the analytical results for all constituents and identifying any constituents that are subject to accelerated monitoring in any particular wells pursuant to Part LG.l of the GWDP or are out of compliance in any particular wells pursuant to Part I.G.2 of the GWDP • Copies of Field Data Worksheets • Copies of Analytical Laboratory results • Copies of Chain of Custody Forms • - A Water Table Contour Map showing groundwater elevation data for the quarter will be contemporaneous for all wells on site, not to exceed a maximum time difference of five calendar days. • Evaluation of groundwater levels, gradients and flow directions • Quality assurance evaluation and data validation description (see Section 9 for further details) • All non-confonnance with this Plan and all corrective actions taken. • Recommendations and Conclusions. With respect to the chloroform investigation reporting requirements, these are specified at Item 5) of the Chloroform Investigation Monitoring Quality Assurance Program (Appendix A to this document. Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-16-09 Revision-4 Page 38 of43 In addition, an electronic copy of all analytical results will be transmitted to the Executive SecretalY in comma separated values (CSV) format, or as otherwise advised by the Executive Secretary. Further reporting may be required as a result of accelerated monitoring under paragraphs LG.l and LG.2 of the GWDP. The frequency and content of these reports will be defined by DUSA corporate management working with the Executive Secretary. 12. SYSTEM AND PERFORMANCE AUDITS 12.1. QA Manager to Perform System Audits and Performance Audits DUSA shall perform such system audits and perfOlmance audits as it considers necessary in order to ensure that data of known and defensible quality are produced during a sampling program. The frequency and timing of system and performance audits shall be as determined by DUSA. 12.2. System Audits System audits are qualitative evaluations of all components of field and Analytical Laboratory QC measurement systems. They determine if the measurement systems are being used appropriately. System audits will review field and Analytical Laboratory operations, including sampling equipment, laboratory equipment, sampling procedures, and equipment calibrations, to evaluate the effectiveness of the QA program and to identify any weakness that may exist. The audits may be calTied out before all systems are operational, during the program, or after the completion of the program. Such audits typically involve a comparison of the activities required under this Plan with those actually scheduled or performed. A special type of systems audit is the data management audit. This audit addresses only data collection and management activities. 12.3. Performance Audits The perfOlmance audit is a quantitative evaluation of the measurement systems of a program. It requires testing the measurement systems with samples of known composition or behavior to evaluate precision and accuracy. With respect to performance audits of the analytical process, either blind performance evaluation samples will be submitted to the Analytical Laboratory for analysis, or the auditor will request that it provide results of the blind studies that the Analytical Laboratory must provide to its NELAP and/or NA VLAP accreditation agency on an annual basis. The performance audit is carried out without the knowledge of the analysts, to the extent practicable. Mill -Groundwater Discharge Petmit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 39 of43 12.4. Follow-Up Actions Response to the system audits and perfonnance audits is required when deviations are found and corrective action is required. Where a corrective action is required, the steps set out in Section 10.2 will be followed. 12.5. Audit Records Audit records for all audits conducted will be retained in Mill Central Files. These records will contain audit reports, written, records of completion for corrective actions, and any other documents associated with the audits supporting audit findings or corrective actions. 13. PREVENTIVE MAINTENANCE Preventive maintenance concerns the proper maintenance and care of field and laboratory instruments. Preventive maintenance helps ensure that monitoring data generated will be of sufficient quality to meet QA objectives. Both field and laboratory instruments have a set maintenance schedule to ensure proper functioning of the instruments. Field instruments will be maintained as per the manufacturer's specifications and established sampling practice. Field instruments will be checked and calibrated prior to use, in accordance with Section 5. Batteries will be charged and checked daily when these instruments are in use. All equipment out of service will be immediately replaced. Field instruments will be protected from adverse weather conditions during sampling activities. Instruments will be stored properly at the end of each working day. Calibration and maintenance problems encountered will be recorded in the Field Data Worksheets or logbook. The Analytical Laboratory is responsible for the maintenance and calibration of its instruments in accordance with Analytical Laboratory procedures and as required in order to maintain its NELAP and/or NAVLAP certifications. Preventive maintenance will be perfonned on a scheduled basis to minimize downtime and the potential interruption of analytical work. 14. QUALITY ASSURANCE REPORTS TO MANAGEMENT 14.1. Ongoing QA/QC Reporting The following reporting activities shall be undertaken on a regular basis: a) The Sample and QC Monitors shall report to the QA Manager regularly regarding progress of the applicable sampling program. The Sample and QC Monitors will Mill -Groundwater Discharge Pennit Groundwater Monitoring Date:4-16-09 Revision-4 Quality Assurance Plan (QAP) Page 40 of43 also brief the QA Manager on any QA/QC issues associated with such sampling activities. b) The Analytical Laboratory shall maintain detailed procedures for laboratory record keeping. Each data set report submitted to the Mill's QA Manager or his staff will identify the analytical methods performed and all QA/QC measures not within the established control limits. Any QA/QC problems will be brought to the QA Manager's attention as soon as possible; and c) After sampling has been completed and final analyses are completed and reviewed, a brief data evaluation summary report will be prepared by the Analytical Laboratory for review by the QA Manager, by a Sampling and QC Monitor or by such other qualified person as may be designated by the QA Manager. The report will be prepared in accordance with NELAP and/or NAVLAP requirements and will summarize the data validation efforts and provide an evaluation of the data quality. 14.2. Periodic Reporting to Management The QA Manager shall present a report to DUSA's ALARA Committee at least once per calendar year on the performance of the measurement system and the data quality. These reports shall include: a) Periodic assessment of measurement quality indicators, i.e., data accuracy, precision and completeness; b) Results of any perfOlmance audits, including any corrective actions; c) Results of any system audits, including any corrective actions; and d) Significant QA problems and recommended solutions. 15. AMENDMENT This Plan may be amended from time to time by DUSA only with the approval of the Executive Secretary. Mill-Groundwater Discharge Pennit Groundwater Monitoring Quality Assurance Plan (QAP) 16. REFERENCES Date:4-16-09 Revision-4 Page 41 of43 16.1. United States Environmental Protection Agency, November 2004, Test Methods for Evaluating Solid Waste, EPA SW-846. 16.2. United States Environmental Protection Agency, September, 1986, RCRA Ground- Water Monitoring Technical Enforcement Guidance Document (TEGD), Office of Solid Waste and Emergency Response, OSWER-9950.1. 16.3. United States Environmental Protection Agency, November 1992, RCRA Ground- water Monitoring Draft Technical Guidance (DTG), Office of Solid Waste. 16.4. Standard Methods for the Examination of Water and Wastewater, 20th Edition, 1998. American Public Health Association, American Water Works Association, Water Environment Federation. Washington, D.C. p. 1-7. Mill-Groundwater Discharge Pelmit Groundwater Monitoring Quality Assurance Plan (QAP) Date:4-l6-09 Revision-4 Page 42 of43 ATTACHMENT 1 WHITE MESA URANIUM MILL FIELD DATA WORKSHEET FOR GROUND WATER Description of Sampling Event ______________________ _ Sampler Location (well name) _________ Name and initials __________ _ Date and Time for Purging ______ and Sampling (if different) ________ _ Well Purging Equip Used: ~ump or _bailer Well Pump (if other than Bennet) ____ _ Sampling Event __________ _ Prevo Well Sampled in Sampling Event. __ _ pH Buffer 7.0 _________ _ pH Buffer 4.0 __________ _ Specific Conductance ____ uMHOS/cm Well Depth. ____________ _ Depth to Water Before Purging ______ Casing Volume (V) 4" Well: ____ (.653h) 3" Well: (.367h) Conductance (avg) ________ _ pH of Water (avg) _________ _ Well Water Temp. (avg) _____ _ Redox Potential (Eh) __ Turbidity __ _ Weather Condo --------Ext'l Amb. Temp.(prior to sampling event) ____ _ Time: ____ Gal. Purged ____ _ Time: ____ Gal. Purged _____ _ Conductance Conductance ------------------------- pH _____________ _ pH ______________ ___ Temperature __________ _ Temperature -------------- Redox Potential (Eh) _______ _ Redox Potential (Eh) ________ _ Turbidity ------------Turbidity ____________ _ Time: _____ Gal. Purged ____ _ Time: _____ Gal. Purged ____ _ Conductance Conductance ------------------------- pH _____________ _ pH ______________ ___ Temperature -----------Temperature ------------ Redox Potential (Eh) _______ _ Redox Potential (Eh) ________ _ Mill -Groundwater Discharge Permit Groundwater Monitoring Quality Assurance Plan (QAP) Turbidity ___________ _ Date:4-16-09 Revision-4 Page 43 of43 Turbidity _____________ _ Volume of Water Purged When Field Parameters are Measured" ___________ _ Pumping Rate Calculation Flow Rate (Q), in gpm. S/60 = Time to evacuate two casing volumes (2V) T= 2V/Q = -------------- Number of casing volumes evacuated (if other than two) ---------------- If well evacuated to dryness, number of gallons evacuated ---------------- Name of Celiified Analytical Laboratory if Other Than Energy Labs _________ _ TYl!e of Saml!le Saml!le Saml!le Volume Filtered Preservative Added Taken (indicate if other (circle) (circle} (circle} than as sl!ecified below) VOCs Y N 3x40 ml Y N HCL Y N Nutrients Y N 100 ml Y N H2SO4 Y N Heavy Metals Y N 250 ml Y N RN03 Y N All Other Non-Y N 250 ml Y N No Preservative Added Radiologics Gross Alpha Y N 1,000 ml Y N H2SO4 Y N Other (specify) Y N Sample volume Y N Y N If a preservative is used, Specify Type and Quantity of Preservative: Comments -------------------------------- Appendix A Chloroform Investigation Monitoring Quality Assurance Program White Mesa Uranium Mill B landing, Utah Chlorofonn Investigation Monitoring Quality Assurance Program White Mesa Uranium Mill Blanding, Utah This document sets out the quality assurance plan to be used by Denison Mines (USA) Corp. for Chlorofonn Investigation conducted pursuant to State of Utah Notice of Violation and Groundwater Corrective Action Order (UDEQ Docket No. UGW-20-01) (the "Order). Specifically, the mill will use the same sampling regimen for the Chlorofonn Investigation that is utilized for groundwater sampling under its groundwater discharge pennit, as set forth in the attached groundwater discharge pennit Quality Assurance Plan (QAP), except as set forth below: 1) Dedicated Purge Pump Chlorofonn Investigation samples are collected by means of dedicated bailer(s) that remain inside the well casing (suspended and secured with a rope) or by means of a disposable bailer used only for the collection of a sample only from an individual well and disposed subsequent to the sampling. The wells are purged by means of a p0l1able pump. Each quarterly pumping and sample collection event begins at the location least affected by chlorofonn (based on the previous quarters sampling event) and proceeds by affected concentration to the most affected location. -. Decontamination of All sampling equipment will follow the decontamination procedure outlined in section 6.2.5 of the QAP. 2) ChlorofOlID Investigation Sampling Frequency, Order and Locations The chlorofonn investigation wells listed below are required to be monitored on a quarterly basis under State of Utah Notice of Violation and Groundwater Corrective Action Order UDEQ Docket No. UGQ-20-01. ChlorofOlID wells shall be collected from the least contaminated to the most contaminated as based on the most recent quarterly results. • MW-4 • TW4-11 • TW4-1 • TW4-12 • TW4-2 • TW4-13 • TW4-3 • TW4-14 • TW4-4 • (MW-26) • TW4-5 • TW4-16 • (MW-32) • TW4-6 • TW4-18 • TW4-7 • TW4-19 • TW4-8 • TW4-20 • TW4-9 • TW4-21 • TW4-10 • TW4-22 • TW4-23 • TW4-24 • TW4-25 Note: Wells MW-26 and MW-32may be monitored under either the Chloroform Investigation Program or the Groundwater Discharge Permit Monitoring Program. 3) Chloroform Investigation Sample Containers and Collection Volume The chloroform investigation sampling program requires a specific number of sampling containers and the collection of specific volumes of sample. Accordingly, the following sample volumes are collected by bailer from each sampling location: • For Volatile Organic Compounds (VOC), collect three samples into three separate 40 ml containers. • For NitratelNitrite determinations, collect one sample into a 100 ml container. • For inorganic Chloride, collect one sample into a 100 ml container. 4) Laboratory Requirements Collected samples which are gathered for chloroform investigation purposes are delivered to an outside laboratory where the requisite analyses are performed. At the laboratory the following analytical specifications must be adhered to: Analytical Analytical Reporting Maximum Sample Sample Parameter Method Limit Holding Preservation Temperature Times Requirement Requirement Nitrate & Nitrite E353.2 0.1 mg/L 28 days H2S04 to :S 6°C (as N) pH<2 Carbon SW8260B 1.0 1lg/L 14 days HCl to pH<2 :S 6°C Tetrachloride ChlorofOlm SW8260B 1.0 Ilg/L 14 days HCl to pH<2 <6°C Dichloromethane SW8260B 1.0 1lg/L 14 days HCl to pH<2 :S 6°C (Methylene Chloride) Chloromethane SW8260B 1.0 Ilg/L 14 days HCl to pH<2 :S 6°C Inorganic A4500-CI B 1 mg/L 28 days None :S 6°C Chloride 5) Field Parameters In the case of chloroform pumping wells only one set of field parameters is required to be measured prior to sampling. This includes the following weills: MW-4, MW-26, TW-4-19 and TW-4-20. 6) Chloroform Investigation Reports The Chloroform Investigation Reports will include the following information: a) Introduction b) Sampling and Monitoring Plan • Description of monitor wells • Description of sampling methodology, equipment and decontamination procedures • Identify all quality assurance samples, e.g. trip blanks, equipment blanks, duplicate samples • c) Data Interpretation • Interpretation of groundwater levels, gradients, and flow directions. Interpretations wold include a discussion on: 1) A current site groundwater contour map, 2) hydro graphs to show groundwater elevation in each monitor well over time, 3) depthe to groundwater measured and groudnwateelevation form each monitor well summarized in a data table, that includes historic groundwater level data for each well, and 4) an evaluation of rhe effectiveness of hydraulic capture of all contaminants of concern. • Interpretation of all analytical results for each well, including a discussion on: 1) a current chloroform isoconcentration map with one of the isosconentration lines showing the 70 ug/L boundary, 2) graphs showing chloroform concentration trends in each well thru time and, 3) analytical results for each well summarized in a data table, that includes historic analytical results for each well. • Calculate chloroform mass removed by pumping wells. Calculations would include: 1) total historic chloroform mass removed, 2) total historic chloroform mass removed for each pumping well, 3) total chloroform mass removed for the quarter and, 4) total chloroform mass removed fmID each pumping well for the quarter. d) Conclusions and Recommendations e) Electronic copy of all laboratory results for groundwater quality monitoring conducted during the quarter. £) Copies ofDUSA field records, laboratory reports and chain of custody forms. Except as otherwise specified above, the Mill will follow the procedure set out in the Mill's groundwater discharge permit QAP. Attachment 4 Initial Nitrate Monitoring Report 3 laboratory analysis and quality assurance documentation under Tab F of this report, and the Field Data Worksheets for those samplings are provided at Tab B. Regularly scheduled sampling of compliance monitoring wells under the Mill’s State of Utah Groundwater Discharge Permit No UGW370004 (the “GWDP”) and under the chloroform investigation for nitrate and chloride are reported in the applicable quarterly groundwater monitoring reports for those sampling events. 2.1.3 Constituents Monitored Wells sampled as an element of the Nitrate Investigation were analyzed for the following constituents:  Nitrogen, Nitrate + Nitrite as N  Chloride 2.1.4 Groundwater Head Monitoring Depth to groundwater measurements were taken in the following wells and/or piezometers at the time of sample collection for the purposes of the Nitrate Investigation: a) All nitrate contaminant investigation wells listed in paragraph 2.1.1 above; and b) Site Piezometers – P-1, P-2, P-3, P4, and P5 (Routine GWDP 12-11-09) 2.2. Sampling Methodology, Equipment and Decontamination Procedures The sampling methodology, equipment and decontamination that were applied to the nitrate contaminant investigation can be summarized as follows: 2.2.1 Well Purging and Depth to Groundwater a) A list was prepared of the wells in order of increasing nitrate contamination. The order for purging was established in accordance with this listing. Mill personnel started purging with the lowest concentration well (as initially determined by nitrate field test strips and later by means of laboratory results as the Investigation proceeded) and then moved to the more contaminated wells in order of nitrate contamination; and With respect to sampling that was done prior to October 29, 2009, before leaving the Mill office, the pump and hose were decontaminated utilizing the cleaning agents described in Section 6.2.5 of the White Mesa Mill Groundwater Monitoring Quality Assurance Plan (QAP) (the “QAP”). Mill personnel then proceeded to the first well, that being the well indicating the lowest concentration of nitrate either at the time of well construction or by means of further laboratory analyses as the project proceeded. Well depth measurements were taken and the two casing volumes were calculated (measurements were made using the same. 7 3.1 Analytical Results 3.2.1 Copy of Laboratory Results Included under Tab F of this Report are copies of all laboratory analytical results for the groundwater quality samples collected in 2009 during the Nitrate Investigation. 3.2.2 Electronic Data Files and Format (Tab G) DUSA is providing the Executive Secretary an electronic copy of all laboratory results for groundwater quality monitoring conducted under the Nitrate Investigation, in Comma Separated Values (CSV). These transmissions will be sent via email on or before January 4, 2010. 3.2.3 Current Nitrate Isoconcentration Map Included under Tab C of this Report are current nitrate and chloride isoconcentration maps for the Mill site. 3.2.4 Data and Graphs Showing Nitrate and Chloride Concentration Attached under Tab H is a table summarizing nitrate and chloride values reported in 2009 for each sampling point under investigation. Attached under Tab I are graphs showing nitrate and chloride concentration trends in each sampling point during 2009 3.3. Quality Assurance Evaluation And Data Validation Quality assurance evaluation and data validation procedures described in the Mill’s Quality Assurance Program for Groundwater Monitoring (QAP) were in effect at the time of sampling events and were deemed applicable to the Nitrate Investigation. These procedures involve three basic types of evaluations: Field QC checks; Analytical Laboratory checks; and checks performed by DUSA personnel, as described below. 3.3.1 Field QC Checks Field Quality Control samples for the Nitrate Investigation consisted of a field duplicate samples, DI blank samples and equipment rinsate samples. The results of these analyses are included with the routine analyses under Tab F. 3.3.2 Analytical Laboratory QA/QC Procedures The Analytical Laboratory has provided summary reports of the analytical quality assurance/quality control (QA/QC) measurements necessary to maintain conformance 12 The QA Manager reviewed the Analytical Laboratory’s QA/QC Summary Reports and made the following conclusions; i. Check samples were analyzed for each method used in analyzing the Nitrate investigation samples. These methods were: Parameter Method Nitrogen, (Nitrate + Nitrite as N)E353.2 Chloride A4500-CL B and E300.0 ii. The check samples included at least the following: a method blank, a laboratory control spike (sample), a matrix spike and a matrix spike duplicate; iii. All qualifiers, if any and the corresponding explanations in the summary reports are reviewed by the QA Manager. The only qualifiers reported were for matrix interference in some of the analyzed monitoring location samples. However, despite the increase in detection limit, sample results were detected. The laboratory holding time for all analyses was within specification and sample temperature was acceptable upon receipt. 4.0 Corrective Actions Based upon the review of sample procurement and the exceptions noted in Section 3.3.3.b) above, sample collection activities require improvement. Accordingly, necessary corrective actions in accordance with Section 10 of the QAP are as described below: 4.1 Identification and definition of the problem The problems identified during the review of Field Data Worksheets included:  Failure to decontaminate non-dedicated pumping equipment between sampling locations during the February, July and August sampling events.  Failure to evacuate 2 casing volumes during purging operations,  Failure to measure at least 2 field parameter data sets within +/- 10%, and  Failure to maintain turbidity below 5 NTU in collected samples. Tab A 1,200 600 o 1,200 Foe' ---- S;V>rajeds\IUC-001·01·00 I o Monitoring Wei (MW) e Piezometer • Sa .. • Spring Loom! • SUrface Water • CIllornform MN o Nitrate MW --N"lIrate COOC8nlJation (mglL) --Groundwater Elevallon Contours 10Ft ---Groundwater Elevallon Contours 5ft Source(s): Aerial -Utah GIS Portal webslle; Walls -HGC, Inc., May 2008 naport Figure 3 Nitrate Concentrations with Groundwater Elevations 1,200 600 o 1.200 F." ---- J.ogO!l!l o Monitoring Well a Surface water • Piezometer • Chloroform MW • Seep ~ Nitrate MW • Spring --Chloride Concentration (mwt) --Groundwater Elevallon Contours 10Ft • - -Groundwater Elevation Contours 5ft S;'f'rojedsll\JC-001·01-(JQ1 Denison "'flH\GIS\mapdoo;sl20091 223CliotideMllI.m,xd Source(s): Aerial -Utah GIS Portal website: WellS -HGC, Inc., May 2008 report. Figure 4 Chloride Concentrations with Groundwater Elevations Tab B February Sampling Event 4356782224 Illlelllallollal uranium MiD -Groundw.!., Disclmrgo P",wil Gwunaw&er Monitoring Quality JI.o;smance I'llm (QAP) ;.-- I 10 49 06 a m. 12-23-2009 ( Date: 2.25.07 Revision: 2 Page40of4i rJ.,o h.p / A'ITACHMENT 1 WE!ll'H'E MESA URAl\lIDM Mal. FmLD DATA WOI!'JffiHEET FOR GROUND WATER Description of Sampling Even!:,-"!l!.1LL;'-'J~",~",----,1'-LCa!r.u!zz!,",A",-_________ _ Sampler --r-//' Location (well name) TINN' J Name and initials JaM"">' 1/ flJ,,~;:1 Date and Time for Purging 2 ' h . 200'1 and Sampling (if different), ___ ---- Well Purging Equip Used: ..kPuliip or _bailer Well Pump (if other than Bennet) (;","-f G~ Sampling Event~;(j!L,.e.j_'c"'_ ____ _ pH Buffer 7.0 1.6 Specific Conductance 11 fS uMHOS/cm Depth to Water Before Purging LJ 1. 7/ Well Water Temp. (avg)' ____ _ Prev. Well Sampled, in S"!,,pling Event -fIN IV ' 3 pH Buffer4.0,_--'7'.~._"O'__~,~7-='J__ CiM.t.V W~llDel!th . Casing Volume (V) 4" Well: J 'I. t! (.653h) " 3' Well: (.367h) PH,o,~;)Y'~~r'(itV!1),. ' ·R~&{F6tSrii~{(fu,) __ Tu~bidity ." ---, We.therCOnd.,_.,---~ ____ Ext'IAmb. Temp.(pnorto sampling event) If; (; TIme:--,' '_-'-c-:"''' c.,' Gal. Purged.~_~_ CondUctance 7:);;l: .1 pH Trod Temperature IllY, t RedoxPotent,ial (Eb),_~",O::.:~::.....-' __ _ Twbidily __ ...<7'--'-IO=.0""----__ _ Time: ____ GaI. Purged, ___ _ COnductance' _________ _ pH~ ________________ _ Temperature _________________ _ Redox Potential (Eb) ______ _ Conducta,nce.--__ ~-' ... ___ --c'-~ pH~ __ ~ ________________ __ Temperature, _________ _ Redox Potential (Eh), _______ _ Turbidity __________ _ Time: ____ Gal.,Purged ____ _ Conductance, _________ _ pH~ __________________ __ Temperature. _________ _ Redox Potential (Eb), _________ __ 8 /19 C';" .... ... .'.'i!' /1356782224 Inleulatlonal UlcHlIUIll 10"4925a lll 12-23 -2009 9 /19 ( i aru! -Groull4wp.tel" lJisdwge Pelmii Grouadv/lJter Mouitoli1lg Data: J.U7.06 Revi,icn: I Qwlity Assurance Piw (QAr) Page ~·l of41 r-. TurbidilJ ________ _ TurbidilJ __ --'----==-_____ _ Volume of Waler Purged Wilen Field Parameters are Measured'--_~ __ ' _____ _ pumping Rate Calculation Flow Rate (Q), in gpm. j S/60 = ='-------l>r.z~ __ _ Time to evacUlll.e ~o CllBffig volumes (2V) T = 2V1Q = . 1 110 "" Number of casffig volumeS evacuated {if other than two)c-__ ----,.,-______ _ "---- If well evacuated to dryness, number of gallonS evacuated, __________ _ Name of Certified Analytical Laboratory if Other TilllD·Ed.lrgy Labs'--______ _ If a preservative is used, Specify Type and Quantity of Preservative: .:r.vr '11.1/ 6/. 26 J~j ,t'f~ 1/ 1/. !O $, '''11''( /3'os;- 4356782224 InternatIOnal uralllUITI Mill -Groundwa!er Discharge Pe,rrut Groundwater Monitoring Quality Assllfl!llCe PI1lll (QAP) r ! 10·49 48 a .m . 12-23-2009 ( Date: 2.25.07 Revision: 2 Page Ij{) of <t I ATIACIIMENTl 'Wm'lrE P.mSA URANIUM MULL lFIiEUHM.1!'A WO~ET FOR GROUND 'WATER Description of Srunpling Event'-.<4"''/..t../Ll>%'''v1l.",,---, ~-#~dt."" ",!t",O~i.""ldi",c _________ _ Location (well nllJTle) JAiN -2... Sampler /J Na~e aM initials'_~..L/a,,-n'1.!"!.r.<rc...nJl:.:.. -!!r4'f,,,,~~r..:.,- D.te and Time for Purging :2 -f, . cOO 1 and Sampling (if different),-.:-__ -__ _ Well Purging Equip Used: '~p or _bailer Well Pwnp (if other than Bennet) Sampling Event,...L.:ItJ"-"'-J...>.C~< _____ _ pH Buffer 7.o,_-,---7L..:;J.(}L-___ _ Specific Conductance 11[( uMHOS/cm Depth to Water Before Purging IS .32, Condifctaltce'(avg)_' ~~ __ ',,-, _-'-~''-;'' WeU Wafer Temp. (avg) - Prev. Well 1!ampled in Sampling Event n.w -'f pH Buffer4.0,~_-,· j.lc.:.~,:::():...' ____ _ Well De)'th . qS- (.653h) (.367h) Casing Volume (V) 4" WeU:fJ&{., ~ .. _-,;:': :. ... i:· 3"W~L ..--I'Jl1!f:\Wa.'(e~Javg)",,~,;..,. ,-' '---'-~----"--- . " ..... ,.~. '" '.'. .,. .. . Ri,{f~~ ~~~H~r;ab)--Turhidity __ _ o Weather Cond. ck;6cv ",? Ex!'l Amb. Temi>.(Il~or tci$llmpling event) 2(6 . ~J/WA~ Time: )1s'~, ,(1a1. !:'urged Sif Condlicia"ce Jb tS" pH_--'?e...:<""b,<;''''--____ _ Tempemture_..Ll",,3c:...' '1...'1 &iL-___ _ Redox Potential (Eh)_ .... LI.;:.0-ff ___ _ Turbidity_-='b..=g".:.., ../...1 ____ _ Time: ____ -GaI. Purg"';!" ___ _ Conductance_-\-_--:f-____ _ P~----7~----- Tempemture_-,I-__ --.:::."=~ __ Redox poten, (Eh) ______ _ .;.:.. . . ConducblIlce'-'\-___ 'f·,'C-__ ~- Pn-~ __ ~~L-____ ___ Temper.ture, __ .,L-_~ ____ _ Redox Potential (Eh) _______ _ Turbidity __________ _ Time: ____ GaI.Purged ___ _ pH ______ ~~----------- Temperature-l-________ _ Redox Potential (Ehl ______ _ 10 /19 C,~·, , ,,' '., " -.- 4356782224 . _ J Internateonal uraruulll 10 5008allL 12-23-2009 ( Mill -Grol!lldMl!er Dischllt"" i'e<rillt Oroum!wllter lV/ol1itorillg Date: lLi7.06 l'.evj~ion: 1 Qt!lliity Assurance Plllll (QAF) Tmtidity ____ -====-__ ~ 'fIubic!ity~· ________ _ Volume ofWaier Pmged When Field Parameters are Measured, _________ _ Pumping Rate Calculation Flow Rate (Q). in gpm, / 8/60 = ='------.,\<,!,:z:L.. __ Time to evacuate two cMing volumes (2V) T =2V/Q-________ _ Number of casing vollimes evacuated (if'other than two)'-___ ~_:-------- If well evacuated to dryness. number of gallons evacuated' ___________ _ Name of Certified Analytical Laboratory if Other 't1ial1'Brl:ergy Lilbs. ________ _ If a preservative is'used, Specify Type apd Quantity ofP!eservative: 1 1 /19 /5':.32 {)-c/n+ Comments J;At1:l.."'-'=--L:t.L.!.'...:L~Cjyj'-"'--.E~'-"L-__!!!:::_SJ~~~.iJr.r.e~ '",,-~ I b. 7cS 7~.I /"7 L p " ~ ',k./ : '" 4356782224 Inler naLrorra l urarrrurrr 10:5031 a.rrr 12-23-2009 12 119 Mill -Groum!ware .. DiBc'.nrgo PeiUlit GroUndWD~eI Monitoring Qtmlily Assm/ll1Ce !'lfill (QAP) ( ( Dcr.: 2.25.07 Revision: 2 Page 40 of41 A'ITAClfIMEl1fU VVlfIl'rn MlESA URANWM' M1U .. mILD DA 'fA WorumDEET )FOR GROUMJi W ATEfft Description of Sampling EVenl:-.L!1/LLl/'.k.:l:lJ1:::J~~te-1..(fj~~W,-<:"y'''~ __________ _ Sampler Location (well name) ThIN ~ 3 NlllI!e aDd initials 7;:-1,,<-, ;.I. Date and Time for Purging ;:2. {, . 2007 and Sampling (if different} ______ _ WeU Purging Equip Used:v{ump or _haiier . WeUPump (if other than Bennet) b ru..) ;::;.l Sampling Event jilJ L PIl'V. Well Sampled in Sampling Event ~.", Specific Conductance 11 fL uMHOS/cm pH Buffer 7.0, ___ LI..-' "'0 ___ _ pH Buffer4.0, __ q!.C. . ..!oQ~. -----=~,s=_ Well Depth , /16 Gz -;]) Depth to Water Before Purging .3 0 .73 Casing Volume (V) 4" Well: S /:'ft, (.653h) .' . ' .. ' ... ' . ." 3" .Well:, ___ (.367h) Condudi!nce(a\lg}'---.,._--,--~.-z:. ::::...-,--~ jiH Qf)Vati;r~(avg),. ' -,--_ .. : .. <t·_~',-:, ... : ;.;-. Well Waier Temp, (avg) ____ _ R~a!>~ P6ie~il#i &it)' . -Turbidity __ _ < WelitherCond.C~ ... Lo A ) Ext'IAmb. Temp.(prior to $aIDplitig event) / 8' L .-J.,. ;" .. : .. , 'rime: ;[1-/ S-,' . dat ?urged ,'11 Conductance 2 Z. (, I pH +,Li Temperature~-"1.>"---'S=---.!.( ____ _ Redox Potential (Eh)_LLI '{"'1>"'--__ _ Turbidity_,,/-'tI"')"-_____ _ Time: _____ Gal. Purged ___ _ Conductance _________ _ pH __________________ __ Temperature _________ _ Redox Potential (Eb) ______ _ Conductance.~ ___ ~"___ __ ___+~ pH~ ____________________ __ Temperature'-________ _ Redox Potential (Eh), _______ _ Turbidity __________ _ . Time: ____ GaI.Purged, ___ -- Conductance _________ _ pH~ ____________________ _ Temperature _________ _ Redox Potential (Eb) ______ _ l' . ~ ~C:" "-' . .; , , ., .' 1\356782221\ ~. Inler na!IQllal ur allium 105050am 1 2~23~2009 ( Mill-GlOuOOWatt.;~ J[)is:;na,JlO ?emti! G-;:OuiJdw~rer Moooorrog note: lU7~06 lliJvWicr.: ) Qmillty Ass!!I1lnce Pion (QAP) Pogo 4·) of 41 'j'm:oidily ________ _ Turbidity ________ _ Volt1llW ofWa!er Purged When Field Parameters am Measured. _________ _ l"illIlping nare Calculation Flow Rate (Q), in gpm. C S/60= =,-----l<I<22--__ ~ Time to evacuate l1vc casing volumes (2V) T=2V/Q-J3 /<1;" NU!Jlber of casing vohillies evacuated (if other than IWO)'---__________ _ If well evacuared to dryness, Dumber of galimis ei"icuiired, ___________ _ Name of Certified Analytical Laboratory if Other~n Energy Labs. _______ _ If. preservative is Used, Spe<;ify Type and Quantity of Preservative: 16'. g' 13/19 I'--:J L ~.( ':>6, Ii ku . ("I/<.' I. .if J/?t 4356782224 Int er natrona l uramurn Mill -GroundwRtGf Discharge Permit Groundwater Morutoring Quality J\-""",'ance I'hm (QAP) 12-23-2009 ( Date: 2.25.07 Revision: 2 Page40of4i ATI'ACHMlEN'fl WmTH!: MESA URANIIlIM MiLL FJ{ElLllH}ATA WO~l(sm:l!;r FO.R GROUND WATER Desciiplion of Sampling Bvent:'-LI0!:c'CI.b?:f"..~t"--"e.j~uc,~",it:"",,,!£',k,-,,--__________ _ Sampler ~ Location (well name) $/11-I{ Na~e and initials /""4«' 1-1 Date and Time for Purging ;2. (;. ZaJ"i and Sampling (if different), ___ ---- Well Purging Equip Used: ~p or _bailer wdi Pump (if other than Bennet) G~u-l F'<-s Sampling Event'-L(t!-"-'f'--'t:..=-___ _ Prevo Well Sampled in Sampling Evcnt 'f"-''''-J pH Buffer 7.0,_---'1''---''0'---___ _ '1.0 pHBuffer4.0, ______ ~ __ _ Specific Conductance 1115 uMHOSlcm WeIlDepth"""--c.,.-L1",,3~b"'--~-I-'.u,-,,J,--_ Depth to Water Before l'urginj;.g_.:..tf:..u_4:..:o:.....-_ Casing Volume (V) 4" Well: <Iff 1'( (.653h) . 3" Well: ___ ,(.367h) CilnductaRl:e(avg) ':jlrf~l'wltl;; (~y'g)'4:'~'---'---'---- ',::'~::, -"-' , J". ~. Well Water Temp, (avg)' ____ _ ~i<Powii!i4i cEn)_' _Turbidity " y,. -- Weather Cilnd._______ Ext'l Amb. Temp,«(lri0r to sampling eveot) ___ '_'_ "-~' ... , Time: Mdt::· dal. Purged 3{" -. " .. ". Coodticia!lce'_...L1 ..... 'i_' '1--____ _ Conducll).nce,_---~--'----......,'---'- pH --:{, 4& pH ________________ ~--- Tempemture I q. 21 Temperature, _________ _ ~ Redox Potential (Eh),_ ..... 'Ic.:O'-'O"" ___ _ ~ Turbidity __ I/..LI-J...' ____ _ Redox Potential (Eh), _______ _ Turbidity _________ _ Time: Gal. Purged, ___ _ Time: ____ Gal.·Purged. ___ _ Conductance~ ________ _ Conductance, __________ _ pH _________ _ pH ____________________ __ Tem~mrure------------Tem~rature,---------- Redox Potential (Eh) ______ _ Redox Potential (Eh), _______ _ 14 /19 c ,,' .. ; ., -' 4356782224 Inter national uramurn 10 S1 33a m 12-23-2009 , .3 Mil! -G:<lIm!Iw.ler Disch&ge Perrilli iliOUlidwni:« MOilitorillg Q""lh'y J\sSllfllllce Plru! (QAP) n&te: 1l.17.06 Revician: 1 • Pllge ~l of 41 Tulbidity· _______ -==-~Thrbidity ________ _ Volume of Water Purged Wheil Field Parametel'S are Measured, __ -_--=---=--=-' ____ _ Pumping Rilte Calculation Flow Rate (0). in gpm. S/60= Time to evacuate t~JO cruing volumes (2V) T=2V1Q-' It 1'1'~ Nwnber of casing volumes evacuat.id (if other Ulan iw(j), ____ .::~"'==:, _____ _ If well evacuated to dryness. number of gallOli. evacuate'!l,,,,· ____ -_______ _ Name of Certified Analytical Laboratory if Other'Than B~ergy Labsi __ ' ______ _ if a preservative is Osoo; SpecifY, Type IIl1d Quantity of Preservative: f~( -"'.5 ", // ~f _ Ui!D 10/.", IE2 ~ 15 fl9 :~ 4356782224 InternatlollalurallltHlI Mill -(l;olliluwarer Dischargo Permit Grollrowater Monitoring Quality AsslEance PII1II (QIe!'l / , 10:51 .56cLll1 12-23-2009 ( D,re: 2.25.07 Revision: 2 Page40of~l ATTACHMENT! WHITE MESA. UP.ANWM MIlLL FrnLD DATA 'WORKSHEET FOR GROUND 'WATER Description of Sampling Event:'-Ad/,:.c,k~A!::·s-~i.--12.vku£.""Y""'rclJ.k~. __________ _ Location (well name) t?!?P "'''rV~ 60 Sampler Na~e aiId initials '14 rf,~r !l ;ij.~ fl Date and Time for Purging ::2. {, . 2M 1 and Sampling (if different)~ __ ----- Well Purging Equip Used: -6'uinp or _bailer WellPump (if other than Bennet) tuu"/Gs Sampling Event l1!ii",'1; j dd~ .. k. Prev, We.!1 Sampled in Sampling Event -0/4 pH Buffer 7.0, __ __''lL.:l:lf''--___ _ pH Buffer 4.0, __ 'i!::'..::::O ______ _ Specific Conductance 11t uMHOS/cm Well Del'tb,~._7'~=,;-~-~_--- Depth to Water Before Purgin6.g __ -___ Casing Volume (V) 4" Well:--.:.~_=--'(.6~3h) 3" Well: (.367h) Con'dilciance '(ai.lg,) . .. ilj"" "r' ., .. " " '~ __ ~~_~,""' ,p~.,."y.;£te~!li.vg)"",:...,,------,--- .---Well W.terTemp. (avgl, ____ ~ R'~6~pgte;it1~i ~) Turbidity __ _ , ~'" '., : Weather COnd.________ E't'l Amb. TemP:<\ll:iorto sampling eventl_' ___ _ ..... '< • COnduciance---,-, "'(,'--_~ ___ _ Conductance, __ --~--""-:. ___ +'-~ pH~ ____________________ __ Temperature........L\"!>"". ""0"'-9'+-____ _ Temperature~ _________ _ Redox Potential (Eh),_4 .... ', '6=-~.!......... ___ _ Redox Potential (Eh), _______ _ Turbidity--,-O,L',--,C..t...) _____ _ Turbidity __________ _ Time: ____ GaI. Purged, ___ _ Time: ____ GaI.Purged ____ _ CODd~tanre' __________________ __ Conductanre __________ _ pH ____ --------------__ _ pH ____________________ _ Temperature _________ _ Ternperature __________ _ Redox Potential (Eb) ______ _ Redox Potential (Eh) _______ _ 16 /19 C"', .' ; ',,' " 4356782224 Inter 'latlOllal ura.lIUITl 1052 101 a III t 2-23-2009 Min -Oil)lli!li~'8ter DisclJllrge PO!'mit GiuundwnliOf Moilli:O!1;,g DIlle: ll.i7_(J/j I'.eVWiOil: 1 QurJity Assl!fanoo Pin" (QAP) P.ge~-i of41 Turoidity _____ ----__ -__ .----Tutbidity _________ _ Volume of Water Purged When Field Parameters are Measured'--________ _ Pum!ling Rate Calcu!~lion Flow Rate (Q). in gpm_ S/60= = _____ r---___ _ Tim" to evacuate two C/lSing volwnes (2V) T = 2V1Q = --== Number of casing volumes evacuated (if oilier lha"n two),_-___ --; _______ _ If well evacuated to dryness. number of galions evacuatedc--__ --.:-='-______ _ -----Name of Certified Analytical Laboratory if Other Than Erietgy Labs, _______ _ -, If a preservative is used, Specify Typearui Qu,Wtlty of Preservative: P_I !6jleN l efT ~ • , ., ~ /14 _..1 _ 17 119 :"...! :=. ~~'l5 6 .... , -135678222-1 Intelllatlonal lHolIIWIl Mill-Groundwarer Dischm-ge l'emJit Ground\lwter Monitoring Quality Ass",ance Plan (QAF) 10 52 39 a ilL 12-23-2009 ( Date: 2.25.07 Revision: 2 Page 40 of 41 ATTACHMENT] Wlfm'E MESA URANIUM MILL FlElLIDI DATA 'WORK§HEE'J; FOR GROUI'ID 'W A'fER DescripliOl1 of Sampling Event:-J-;V;,-,I'-"~.!c.J[=i~.i,--:J.d,,,,· ",k<L''-'' k""-_________ _ Sampler . Location (well name) TklltJ-/, J Na~e and initials ]g,,,", II /!,M I' Date and Time for Purging ,,2, b . 2 00f and Sampling (if different) ___ -__ _ Well Purging Equip Used: /pump or _bailer Well Pump (if other than BeDllet) (b'l,Jh5 Sampling Event /l/,fr-~ 01£",;4 Prev, Well Sampled in Sampling Event~ __ pH Buffer 7,0, __ 7-,-,-, 0,,-' ____ _ pH Bnffer4,O __ 'Y"': . ..::o ______ _ Specific Conductance "/1g uMHOS/cm Well Depth /'Jf.I-" .. ,',.,-,---<-,"'--,------- Depth to Water B~fore Purgin,,,g __ "--__ Casing Volume (V) 4" Well: ___ ~(,653h) """" . 3" Well:. (,367h) Condu<:tance'(aifg),_' ---~~----"-'i"" pI,li\f!W-iit1;r(ilVg)"',,_-'-·,.'---'---- ,: .. ;:!;:'~':.~;'':''':'. '.:/~:: ., Wen Water Temp, (avg) __ c:-__ . . R~x Po!eriilMOUtLc_Turbidity --=_ . -;. ,~. , Weather Cnnd, ~jy ala.q U", ( Ext'l Amb, Temp,(peipdo sampling event) ,5,-" r. Time:;_.,,-.~"-' Gal. Purged,-"-__ _ Cnndudance'_lLQ~\,---,-_____ _ CODduc!(U1ce,-,-___ ~_"_ __ ~~ pH S28 pHI~'--_____________ _ Temperature,_ ..... '6"-. ,,/$-+7 ____ _ Temperature _________ _ Redox Po(ent,ial (Eh)-""S=..d_Vl,-· __ _ Redox Potential (Eh), _______ _ '\ b Turbidity __ .:."'--=-______ _ Turbidity, _________ _ Time: ____ Gal. Purged ___ _ Time: ____ GaI.Purged, ____ _ CODductance~ _______ _ Cnnductance _________ _ pH~ ______________ __ pHc _____________________ __ Tempel1lture, ___ -,-_____ _ Temperature, _________ _ Redox Potential (Eb), ______ _ Redox Potential (Eh) _______ _ 1 B /19 C~'· .... '-. ·35678222. Inter.ratlOnal UlanrUII1 10 52 57 a liI 12-23-2009 ( Mill -(lrol. .... dMller Disch&rge l'w-.illt Gwl!1lllmlter Moilitoriilg Date: 11.l7.06 .Revision: ! Qlllilily Assurnnce Pilli! (QAI') Pege 41 of ~·l . Tutbidity ________ _ Turbidity _________ _ Volume of Wilier Purged When Field Parameters am Measured, _________ _ PumpiJJg Rate Calcldatioil Flow Rate (Q), in gpm. ! S/60 = =,---'-.--J;2[,:,'--__ Time to eVllCWIIe two casing volumes (2V) T=2V/Q = . Number of CllBiog volumes eV8Clilited {if'6the .. than tWo), ____ -,..._'--____ _ H well evacuated to dryness, number of galions evacUI.teill:..· . ___________ _ Name of Certified Analytical Laboratory if OtherThBh'Energy Lahs, _______ _ If a preservative is Used, Specify Type .lI!ld Quantity of I'reSerV8tlve: 19 /19 4356782224 Int ernatlollal uralllUlll MiII-'G-W!illdw<\[~r Disclu!.-go I'emli! GiOtmdvmter Mooii:oring QualiTi .A ...... lUlOO "11ll1 (QAP) 12-23-2009 c Dille: 2.25.07 l'",vision: 2 Pnge40 of4! D&te mill Time fot Purging :< ·11, 200 'l and Samp!iQg:(ifjiifferent), ______ _ Welll'urging Equip Used: -JiwiJi'cIlr LOOller W,eIlPmnpl(if.1iIher than Bennel), ___ _ Sampling Event S<Ok'l4n~ i ' pH BUffer 7.0, __ ---'-7 .:,.:."'--___ _ Specific Conductance 141/ uMHOS/cmVi~Up!'j!iI!,= .. C". ,--;c~N~,"(I'-. ,",' ~~_""-_ DeptbtlD Water Before!Put:gin ... _____ CaaingVoliune1V)4' Well: ",1.1. (,{)53h) , , . '. ". C'~'; , "".:" ,. '3" W~II,:. ' "n'" (.3611) Coni!tirnilliC;;;(a~gf;. ~. """-PM-B£,'Wiillli:{(:'"m { ',' 0 " 0 " '.' Well Water Temp, (avg) " O)~r;i~l ~idi~~_' __ WeatlrerCond. i2~::/ f/m<-Ext'IAtilD: Teilli\~;V~:n,g'eveiit} ,,'" ~ : {b/,,,,,,. , .... ,.: .. :,:~.: . pH Tem~;---<.:;I():..;." ... 2'-'1~.,.._--- rurbid!!Y_---J.1""'O""'3 ____ _ Time:_c-----Gal.l'urged~ ___ __ Conductance . .,.:,..;:c-_____ ~-- pH--------"''V'''---, TempeJlltore; __ T-__ ----'~-- Redox'I'otential (Eh), _____ _ -... ; ~ .'-. pB~~~~ __ ~ ___ _ Tem~.~~~--~~-----~- Redox PCitetif ' .,~"-_----"-=-~ ____ _ Turbil!i,~ __________ _ Time: __ ~-GaI,I'uJEed~--- Conductance'--"~7''------- pH, _____ ~~~----- Temperatme+ ____ --'>.=-__ __ Redox P filil(Eb) ________ _ " 6119 Co" . ... ~. ',: '; " 4356782224 Inlemalionalllrallllllll I " Mia -ffiU'~t2 IJiochcrge i'e.wit Qro\Jnd=? Pl:mil(llillg Q1:».lliy A!SliIl:!!CO PJ.!!II (QAY) 104834 al1l 12-23-2009 PI!fle 41 of 41 ~~y--~====~----- Volume ofW1l!fJPurged When Field ParometelB1lmJ.Ilwnred'--_______ __ Pumpjn~ PU!Ie C!ilcuW,!ioo Flow P.t'le (Q1 ill gpm. Sf(IJ~ ~' __ "",,::,. ___ _ Ttrm>:f;o:e.l'll!:l~ two cru;llg volUllleS (2V) T=:Z¥iQ~ ~ . Nwnber of casing volt!in& evacWired (if o'ther ihan'two'-") ___ --: __ ---' ___ _ If well evru:uaWl /0 dryness, number of galioris'ev3l:Iiaiel!:..' _---=====--___ __ NODIlO ofCertifiedAnalyticnl LaboratoJYil'oiIierTbliii~Lahs _______ _ : H II preservative is USed, specify, ty"",.a.n~ . Quantity ofPieservative: 7 !19 .- .< , \ 4356782224 Intematlonal uranium MiU -Groumlwal£r Discharge Pei11lil Grounrlw.te< Monitoring QualilY Assurance PI"" (QAP) (' 10 4727 alll 12-23-2009 ( \ Dole: 2.25-07 Revision: 2 Page 40 of41 A'ITACBMIThJT 1 WHIn; MESA VRANnlM Ml'LIL WIELD 1M,1'A WO~'SHEE1)roR GXWUJ\'IDJ WATER Descliption of Sampling Even1:-<tl",/,.!...:k",v'It=-+,c---<C",-It4_£I",;?'",· "--_________ _ () Sampler IJ · f) Location (well name) At?-2 N~e and initials tv'( "-~ &1.........-- Date and Time for Purging J -}UJ '1 and Sampling (if different) __ ----- Well Pnrging Equip Used: -pump or X bailer Well Pump (if other than Bennet) ___ _ Prev. Well Sampled in Sampling Event /'A'1 pH Buffer 7.0,_--:--'-+_-_° ___ _ pH Buffer 4.0. ____ --0/-· 0 ___ _ Specific Conductance 11 J' uMHOS/cm WeU Depth.~.~_~~_,___:_~---- Depth 10 Water Before Purgin,&.g _____ Casing Volume (V) 4" Well:_--=:--_,(.653h) _ 3" Well: -(.367h) ~. Condti~ianCe'(~vg) ___ ~ __ __'_"_, ,,1;1 9f:W~Ji;r (8.vg):: .... .:--.. " " -0' .".. __ -, ! ,',;' . F· Ri;ifoR pote'rit\4i@i). . 'l'Urbidity _~_ Well Water Temp. (.vg) __ -===-:-- Weather Condo (lla-.. IhI /;-Yu( , . Ext'l Amb. Temp.(prior to ~mpling'event) . ... Time:;_--'-,....·':'-.. ~ QiiI. Purged'---__ _ Conduciance~..::S-,--,,-J.!:(.,--_~ __ _ Conductanc.~;::-___ ...:.-"-::. 7"'''--,",,"- pHI_~~~·~r~J---___ PA-~ __ ~~ ________ ___ Temperature---'/....:o_.-'..I .L..'I _____ _ Temperature:,...:::...-__ ----''''' ____ _ Redox Potential·(Bh),-=:>::....=::U""-___ _ Redo otential (Bh), _______ _ Turbidity :< 1 . .s Tnrbidity, __________ __ T' e:. ____ Gal. Purged~_~_ Timet' _____ Gal. Purged, ____ _ Condue ee----'7""----Conduct ee~ ____ -----,_=--__ p~----_7~-----------pHI _____ --'~~---------- Tempera~";---T_------Temperatnre~-----.:~----- Redox otential (Bh), ______ _ Redox Potential (Bh) ______ _ 4 f19 C·~:··· .... .-. "" :.: ., -' 4356782224 Intelllalional uramum 10 47 46 am 12-23-2009 Mill -GrollilUW .. te;· i)isclJ.'ge Pe;-mit GrouruiMlOOf Moruio .. illg D"",: l U 7.% Irevj,ion: 1 Qu.nlity ASSUfllilce PI." (QAP) Poge410f41 Turbidily ________ _ 1'ur1Jidity~-=-===-~ __ Volume ofW!l!er Purged When Field Parameters are Measuredl __ -===='--___ _ pumping Rille Calculation Flow Rate (Q). in gpm. 8/60= "'. ______ _ Time to eVl!Cllllie tw~ casing volumes (2V) T"'2WQ"' ________ _ Number of casing volumes evacuated (if other than two) ____ -,-______ _ If well evacus~d to dryness. l1umber of gallonS ev"cwited. ___________ _ ~. Name of Celtified Analytical LaboIlltOly if OtherThah Energy Labs. _______ _ If. preselvative is used, Specify. Type '!I'd Qoantily of Pr'eServative: 5 /1 9 4356782224 Illlel llallOllal ulamUIIl !\I1i1l -Groumilw.iF..l Disclmrge Ferrill, Grouildwater MouitOIWg QualilY J\.ssL"'nce Pllill (lAP) 10:46:29 a.lIl. 12-23-2009 ( D.te: 2.25.07 Rev;sio,,: 2 P>!ge 40 of 41 A1flrACHMEN'i!' j) WlHUl'fE MESA VlP.ANJlUM MIlLlL FmlLJIj) DATA 'WOJ.U(§lmE'f lFijlR GlWUMli 'Will 1l'lEIP. Descriptio-II of Slllilpli!1g Bve!!t:.....£-M~,C!'Ir:::.:,;il:..::...4i i:........ft;dJk;U!'i::: .. ~.,k"'''' __________ _ j)SilmpIer /J /J Location (IVell mUlle) frt"Z 3 Nail!e and L,itials Pf"'~ p«-r Date Iltld Time for Purging j!. '2-/ 2Mf ' and Sampling (if different)' ______ _ Well Purging Equip USed: _pruilp or 2:O.bailer WeI/Pump (if other than Bennet)' ___ _ Sampling Event ¥.t'£, pH Buffer 7.0 fitJ Specific Conductance,----'---c....·· __ uMHOS/cm . WeItDi:ptl),~ .. -.."..,,--=--'~-.:_;;_ -_ -_ -_-~_ .,. ~ ,.;;:.:. '.~ , ., ,. _.. . . .,:, ~iij;!='urg~L""--~""- Cott:diwtanCe, __ 4.!..·::....s-.r.I _____ _ pH /! J"O Temperntll!" II)' fr i5 ,;,. Redox POt~tial~),_' ·~5.",6",3=,· ___ _ ,g-k~ Ttntlidity,_--=::.....:.=~_,---__ _ Time:('~ ___ Gal, Purged' ___ _ Conductance'..::::....,..-___ -,L __ _ pHl _______ ~~------- Tempernture'_,L ____ ~---- Redox Po tial(Eh), ______ _ Co'ndi1cti'"c~~'-;-~~...:·'--, __ ='-+-_ : " ;e ,., pHl~~~_~~L'--. _____ __ Temp~awre'_~~_~~------ Redox Po tisl (Eh), _____ '--__ Twbiruty, __________ _ Time::_=:::,..,...._ Gal. Purged, __ --:;".--- Conductance' __ ----'''''''......",.L. ___ _ pH, _____ ~--~----- TeIilpernljllfe ______ ----="".... __ _ Redox Potential (Bb)I ______ _ 2 11 9 10"6 56alll 12-23·2009 111leillallo11al UI alllUIil .M5U -GiG-:J.oormt'!f Dwcl!crge Permit (hwOOlI<lrtm MGaitoring Date: I U 7.C5 Ji'.evi.ioir 1 Qwiliiy ft..6BtlrOilOO PUll (QAP) Pl>ge4Iof4! Tuibitlitr _______ _ TurtJidity, _________ _ Volume of V'!arer Purged Vfl.len Field Pammete!ll am Measured, ________ _ Pumping Rate Calculutio.:! Flow Rate (Q). in gpm. ~OO= =~ ______ __ Time .\0 evac!we two ca~ vollilll!'S (2V) T =til/Q Number of casing volumes eViiciulrid (ittitl!er tltao t\Vo), ____ -,c.....--__ -_-~ ___ _ c If well cVacUllted to dryness. number of gallons evacuaW.dl. ___________ _ . . ... ', .... ""'\' ',. . Name of Certified Analytical Labol'lltoiy if Other l'hilD:EJiergy Lab,,_· _______ _ Other ke«del~.,.& ...... [f a presetvative is .Used. Specify1'Y.~ apd Quantity ofP¢silrvative: 3/19 I· July Sampling Event Mil! -Gmm'~\Vnt'"' Kl>1sc!wrgo1i'ermit Ui"Ottildwntei IV!onitor~i1g Quclity Ass;rrnnce JiliN! (QAP) D.Ie: 2.25.07 Rev;sio,,: 2 li'Dge40 of4! An AJCillIMlEMl' .il L VUJHill1l'lE J.\hllE§/;\ l!mJhl<lill[JJMf tllllLlL lFHOOLITlIlIJ)&'H' WI!JJ!l&liillllillEiE1T' JFI !l& lltl!)JllJl\lIIJI WI & 'll'n lDesci'ipi1oi1 of Saml'iillg Evell1:.-J-x.' .. °lli>J..L-4LJ.-I.=='=-f __________ _ J.AJclltion (welD !lnrtIe) 1Wd-I .' SaJi)p.ler NlliY!e Ilitcl i~itiaJs '1tw.u /I. 1 4?t"", 12 Date mui Time for Purging 1· 2 (. 0 1 and Sampling (if clifferenl) ___ ----- Well Purging Equip l[Jsed: 'J1luillP 0. _Iniiler Welt Pump (if olher than Remlct) 6 ""~( Fu-s Sampling Bvent~If/"-',:/!..!ly''''J.'''__''t..:{.J.C4b:w/u..:f.~1£1~l!!l.§ __ pH Buffer 7.0,_-,-_1-'-'.0'--___ _ Specific Conductance 11 ~ ".;' :,;G~).' ?urg¢'-"'Le __ Con,dtidancc . ':!5;l,. I PH __ --II&"'--"6:c..,'l.It-__ _ Tempcrnture_. -,-/-,--,7-+.1-11 __ _ RedoKPolen~nl'<ElJ) 330 Turbidity ___ .f-'& ........ 6'--__ _ ''''''..,.,.. ___ Ga!. Purged, ___ _ Cond~ctauc.""'---;7-<------ pH~_~~~ ____ __ Temper RedqJ' Potential (Eh), ______ _ Prev·Well snr~p,leli !n Sa/llpling Event fill pH nuffer~,Oc,.,. .. -"--;~' _4_. {) __ ~ __ _ Tempemture,_"'7L...-'t-______ _ RedOJ' p/" Ia! (Bh) 1Urbi~------------ Time\',' ,..--___ Ga!. Purged,-"7 ___ _ Tenwe.ature~--..>...:,._------ Redox B tentia! (Bh) _______ _ C',,: .. .... ,,' '.' . , " ...... .- ( fl,im -Gwumlvlflter Jiliscfim:ge Permit GlOiH1£t\FJl.!i:er Mo-llitormg Qim!ily AIlGt!mace Ploo (Q/iP) ( !)~te: I Ll7.05 iReviGicfl: I P"ge ~1 of41 Tl!f,.,i!!ity, ____ ~= ____ _ ThrbirliIY_--k~~ ______ _ Volmue of Wate, Plu'geel "Wl!~," hi il4\Ilea8l!red rtf ,,,/W Pumping Rate Cnlculatioll Flow IRate (Q), in /Will. ! S/61) = =, __ ----"(Q::L.. __ _ Time to evncel&te two c!!Sing volwnes (2V) T = 2V1Q -L< , If "";_ Number of casing volumes evacuated (if other I1mo IWO), ____ ----________ _ ----If well evaclUlted to dlYness, number of gallollS evacuare,dL-__________ _ Name of Certified Analytical LaboratolY if Oilier Than Energy Labsi---<=---==_' _____ _ 'lfyE o[ Srn""l!!le Som!!!l. SJin'!iie V"! ... ,,. ,ID'iIte...,.n Pll'eServalJive Addeall 'I'ol<en I jjnilicateJrof!i~r .w.'eI£} (clr4:iel I 'ooiliru.8l!ecilied 1i.loM " 0 voes Y ' ,N 3x40ml y " N " Nutrients (y)" N 100ml Y Il'D HeftvV Metals Y ,N 250'Dif . Y N , All OilIer Non-1'iJ ' N. 250 0.1 Y @ Radiololrics , , ". GrossAloha Y N 1,000 mI Y N Other (specify) Y N Sample volume Y N , , StA.""fW: 4-rl~ ~7'j1tPA ''IeI' t/s"d ~ aliter ~"'f~ SA"']' Ie WM JI!ec-rtP ;l1' I S ~3 ,ldrcle) HCL Y. N H,!\O. ('1) N HlIl'o, Y N N" Preservative Added H,SO. Y N Y N If a preservative is used, Specify Type and Quantity of1'!"eservalive: :."i.' Min -Qmu:mhnl[llts'Oi:!c!28.i'ge lP'~mit OiOiJ,iiraWareS MOf"tftorii1g Ql!!2lity Aszu("",,, !"Oml (QAP) ) )),te: 2.25.fJ7 .Revis;"!!: 2 AI'J1'I!'AClHll&IW'R WllillI'lI'iE lVill!i:§A ~ naIL IFHUlID lID& 'lI' 'W([])mlIffilHliEllW' '. ffi 1Gm.([])lUNI!Ji \I'if AI 'l!'lEL~ De8c;'i~i41!] of S@MpliligiE'leii1l:'-!.J!!.L(}1.lfj./L.-4l"',-· u.' 4()~t.[,!i~e ~!:"" ___________ _ Lrr~8!i0I1 (Vlel! Imrul'l6}...:1k.i tJ -1 '1 ~:&l~.i irtit!~s' i,~~ II, i 4u~ 12 DDIe 0001 Time fo. Jl>mgiIJg T:2 (. 67 F.m! Sampling (if differenl)!...-__ -___ _ Welll1'iJlgiflg /ilqioip uh)~: 'J1;lI~P or _~ilil~' "~Ml;~;t:n.1) (if oti!er lImn Benne!) {; vu".,{ &s SlUilv"ng 13vellt ffj,fr",k. j, (kIM ,i§ pH Buffer 7.0 -:;.0 Specific CmulllclDnce 11 X uMHOS/clD lOeplll to Water Before ~rginJt. (; C, Redodioten~ai hlh) :521 . ",.,.. . ...... . nUbidityr __ -.!....i .::...5..::...' L/ __ ' _ '['me: . Gal. Purged' ___ _ Conduclallce, __ -"'._-_..,.o:::...-_ ~.~------~~-------- Terape!'aL~'"~'==-___ -l>-___ _ Ref t Potenti~1 (Eh)I ______ ---, p'~~Jr9,1I $~p'!~!1J S,llf~pling E.vent 1IA1N-! pH BllfferAO . """ "/-(,fL .... ..., .. ':':'.;.: .. "~ .. '."., "tj,'> . '. WeIH1el!·!)t: ..... '.' ... , n .. " " ' .... , .... " '. ,.'<~·,';:~, .. ~r.::: .. i·'~ .. "';',;;~;.00(,_~ ... '" , . - Cmsitig. V~lillne M 4" Well: S I, Sf (.65311) •• < ' •• -. . •••••• ~do" POlpfitiial l',"')_~~~_--=:::....=- r~im~e:::: ===:-_ Gal..Purged'_--:-r_ COndll.ctauc", ___ ~-'7""'-----_ PJn-______ ~--~~------- Tempemtm __ . ___ .-::"'--__ _ Roo(j gte)lliai (Eb), ____ ,..,.-,.-==__ .~. .. . , .. ' ('~'" . ; .... .' ~' ": . , ., -' ( ( fJJill-Ga"O-llllUVm£eZ Dis~~my~e P'6!'p!t Grcawltli'~r lWomtol'IT!g IDZlte: HJ7.fi.fi wvillinn: I Qm>Ii\V Ar.oumm:" li'i!lil (QJili') Tm"oilli,y_, _________ _ F~ow llt!l1e (Q). in /ljlffi, ! S/611 = "" ___ -"-(f2.<--___ _ 'JI'm"ilic1ity ___________ _ Time'to eVllCilll!e lVJ" cnsing IfO!UlJlljS (2V) 'i!'=2V1Q= I r MIAJ • Nmnber of cnSLO/l volumes eVlICunte<l (if other tllUn two),_' ___ -, ________ _ If well evacuated to dryness, number of gallons evacuated"', ____________ _ Name of Certified Analytical Laboratory if Other Titan Energy Labs, ________ _ If n preservative is used, Sp'ecify Type '!I'd Quantity of PreServative: Min -Grmmdwntef IDlsCbllig~ l:J'afliili Growldwatef MmJiiioriag Qilnliljl A,s1r(m,ce ii'lrul (Q/IP) ) Dille: 2.25.07 Hev;sio!!: 2 AI'J['H'ACJlfIlfi!lEl\J'1[1 wmIJ!'Jl'lIi: llhiiE.§A. WANl!lIJlMI ilfdlULll.. . .' ~J1IF.lLIID lID&'Ji' ~iI})lOO'~lRlly;.IJ))1l' ~ lGiiW)1!JJ\ll!]) 'W t\\'ll'JE/ft li)8!lc!ll![AWIl of Sa!1''';iJ~mg l'lveli£:.-t.~/:.L.1J[ill,t:...-"': '--l...m(.!<!)t.~!!iJl~< ~~"'~ ___________ _ ,., .$piYlll.lel . .,' ' i.Al'C~.!iOii (wei! n~me) IiNN -3 N~rne alid illiliais 1two ... /I. i U¥"N 12 Date ulilll Time for IPUrgmg 2·2 (. () 1 m1Il Samplillg (if different} ___ ---- SumplingEvent ffI,:fy",(" J (b{M,iG pH Buffer 7.0 1.0 Specific Conductance 11 8 ullaHOS(cm Depth to Water Before li'oJ~gillg .3:<. /1 ~ . ".', w~i\ Water'feril!'. (avg), __ -----__ ~ ;'., Temp~ra~re'~,_i/LS!2...,....J.7:.J.7l..----. ',' ., '" . ~~OK P,q~~~iJl.:dlljl · :}a r R~doK Potent;~Elt)I __ ~ ___ _ Turbidityr __ .!::2:::....:...r.::f:)~ __ _ Purged, ___ _ Time;: _____ Gal.-Purged. ___ _ Condu e pHL _____ ~~~---- Temperature, __ ..y"-_~~ __ _ :Pclten!tiai 'DUJ ____ ---'._..--· -., ,I 'R~aQlt Pot!lD .nl (llil) •• 1; .... f···.· .. .... Co, .. " ; .... . . : .•. ~, r,' .~.' . , " ' \ '.: ...... ". .... Mfm -GW~ll~V/Iltffi' JiJisrh111rge .W'0rmii: Grolli1~vtlJ~rBr naorutmiJg Q'milily iltJ"HftlllCo !'ioo (QJill') ~W:bidlity ___ ~ _______ _ PMwillg Rale Cnlcu!ntiol1 Fiow IItnte (Q), in gl'1a. ! S/@==. __ -->!!2J.4-___ _ Time to evacuate two ca~g volumes (2V) T =2WQ-__ ~/~?~.~~ ________ _ N1I1nbe;r or cnsiug volumes evacutited (if oilier tltau Iwo), ____ -'-"----------:==== ____ _ II wen evacuated t(l dryness, !lumber of galtonS evacmil~dl:.'.,: ____ __=.=====_ __ _ Name ofCerlified Analytical Laboratory ifOiberTlinhtliitirgy Labs, ________ _ N Y N If a preservative is' wed, SPCi:ify ~e IllId Quantity of Preservative: Mill -llioumHtrJRter h)'isc!lKige 1P'erfilli: aJiOlliIllWtleI MmiliOri"g Q!!nlily A~s£ij'I!it{}; IP'lml (QJlf') 1iJ~le: 2.2>.07 l'.evision:? ii'Ilge4()of41 D&te Ill101 Time fo.1"Urgiilg 7':2 (. (; 1 and Sampling (if differeil1)' ___ ----- I ,I ' . I~ ~ -;." • ;_ J.; "~I ' Well Pm-ging Equip !Used: 'J4ll.iillp or _!iniier W'~iiIPump (if oUler I/Ilm DeMet) <6 v"..,,( res -" . .' ~Z S!lI!ljliing EVG!!! fII':/v",4-;t C {rlMI~(§ p~.v,l'!{c;;Il;I?~!~~,!" ~nIJlPlingEvent~"';s.,)f'" TtvN-6 Y pH Buffe. 7.0 1.0 P.l!f.Jtt\lffe.r1.;Q;;.;,::;":.,,4,.cJ .: .:: .. .': ... ~ Specific Conductance 11 ~ uMHOS/c!ll .. 'iJ~~l.t:v.~~ij~.:;:;':A;f..f 1-,'.. ("". " . Deplh to Water Before Pui-ging 3'7. (, r ' .. RedOK rQtent.i~ .~) :> ( r , •••. , -d ' •••. Tl!fbidity 'I, .r Time:: ____ Gnl. !>urgoo, ___ _ Time:: ____ Gnl.·Purged, ____ _ CoUduc1nilce~c-____ ~,...:::.::.-_ COnducronl~~ ____ ,L~ __ _ pHl ____ -+~-----pH, _____ ~~~----- Tempemtl!t-e, __ , "L--~-----'ll'eb11l'erlllUi:e,-;,L-__ ...:..,__----- RedOJ( otentia! {E1l),_--:,) _____ _ .. , .... ". C· .. : .. .. ,' "-' :.; ., ./ ( flit! -(iiCU!i.riumI:B.r Discli:.rige ll)~~'mii €JlmmlivfBt~r I'Jfmutmmg Qmillly P13e'lmnCe i'lilll (QAP) Flow RIlle (Q), ill gpill. ! S/@==· __ --'(Q'""-___ _ 'Flli/}iclilY ___ -=~'--_____ _ Time'lo evv.cuate lwo c.sing volumes (2V) T = ZV/Q = / f m/", , Number of CDsing volmnes eVDCl!Rted (ifuiliet /han two)c-___ -, ________ _ If well eVDClIJIted to dryness, number of gaUoM evncuale)l.""-___________ _ Nrune of Certified Analytic.1 Laboratory if Otllei:fllai.'En';;'gy Labs, ________ _ , If a preservative is used. SPecify, Typ~ 8.!'d Quantity ofPreserifittive: MiL1 -G.10lltHivmtt;f Dlsdwrg01F'erruH GmliJ1rd\r/llte.f Ma-.litm·liIg Qmilily Millan"" l'fllll (QAP) m'.I1lCJH!1\1illEl'lJ[' n '!IlIlHIll'l!'J JMliE§A iiijftM\llllLirur OOlflLlL .' r. ~illElLIlD ]j])&' 'H' y¥l[])llW~Jll!lEi!!:!F' ~jft (G~I[])TUI~fJ)J \\'if &'lJ'1Eb~ ))esmp!t61l or S~mplplllg Jlllleillt'-I..l!/.1JJj{j,ciL_',u· -!..mlJ~",,-!!i&!3.I''f:!:~ ___________ _ Loc&!iml {weH f!lfJJll.e).-:r WN~ ts= .:.~:I!~d ~tl~S 'f ~''''u /I. i t2yUN t2 MU Sampling (if tlifferent)~_~ ___ _ _ .' • .., _ 'h V • • Wen Ptlrging l'll!uip us&i: "ViiUli'ip 01' _baUer . W~I(:iF(;m!> (if oilIer 11m;'! Benne!) 6 v«vo{ Fu-\ Sampling 1i!veill AMrttk.. j (blU4 li~ Pl"7:v".W~!I.$,~ji!~ ~!Sa1\lpling Event , Ta/N -tt.·. pH BUffer 7.0._, _:--_1:...._0_---oc--:-- Specific Conuuctailce 11 ~ . ' ¢oi\ih\9ttw.ce"" -..,..,'~' ...."..~-":..'. -.:..:.-~~ -:. pH _______________ __ rernpemture~ _______________ __ Redo" P(Jtential (Eh)'--______ _ Turbldity _____ -.,-__ _ Turbidily· ___________ _ Time:, ____ , Gal. Purged'--__ _ 'j:ime: _____ GnI.·i"dI'ged, ____ _ COuductllllce. ________________ _ Couductailce, _________________ _ , Ream: Potential (llll) ______ _ P.ooOK Potential (Eh), ________ _ " C··: .. .... \.' ' .. , , " --.' ( Mill-Q~·(J·m.dtrmte~· Dic!::fmrge P~'mit Gmtmrilwl!~~j' lWmIitmsg ![}ate: HJ7.U-S Revicim:r: f Q.miill' Ami""Ol1ce !'1"~ (Q'M') J?lJge ~·l of 411 1!'lli'1JitJily_' __________ _ PloVi ~ate (QJ), ill g~m. ! Sf6fr: ,= __ ---'(Q"'-___ _ Time'fro eVRcru:le two cv.srng volumes (2V) T:2V1Q: ________ _ Number of ~.fi8l!ig."!!lililles evacmited {if olber than IVlO), ____ -:--_______ _ If well evaclIllled to dryness, number of galions evacuate:dc:.·' ____________ _ Name of Certified Analylicl1l Laboratory if <YdleI'Tlla~ Energy Labs. ________ _ N , vol\U!1e ~ •• , 11'1 . .,... • Y N If a preservative is ' u'sed, Sjiecify TYP,~ ~d Quantity of PreselviItive: -~"''':''.'= ,-.-.-:::.:; ... - . _'.~~H.'_ .' ~ -.:_=~~;.::_. -~~~~~~i: .. ~~:::iir ~ ---. Mm -tlriH .. m!J!VJllrer Disc!mrge Permil Gmimdwll~r n~{fwUJrJ!Jg Qmility Aw",nn!J.31f'11m (QAP) i!}ete: 2.25.07 IRevisio~: 2 AI ,][1l' ACl!II!MilEi'\J'll' ] VulHlLl'lfJE I~A WAI\JHIlJTh1l MJjjILll, lF1llliJL1lJ) Ill!A'JI' \%,(j]))f&l[.§JH1I!llE'lf' 'IlUGli"R(j]){tffiJlJHillA'iI'lii:ll! )Jecc~ip!iuii of £Ull'!,\ll~g EV~'11:'-/"£/1.°="u.._'>Il' '-l.' '.<C' (jJ'~,,~' i<~.r!;;" ___________ _ ILIIWlioll (welhwloo) T WfII -6() " ~~~I'li i1ii['i~is 1tt_flLr/( i 4~~ t2 Dllte ruKiI Time fu. li'urging T 2 (. () 1 ~mj Sampling (if differeilt), ___ ----- Sampling ISvel!t,"""",AII..LI)!..!!"t"'~{.."'-.o!3..J.C..,tkl1lkiJ!,.u!l.!!I:~~e __ pli Buffer 7.o'----::-_1c.:. . .:.o_~,......,.- Specific Col1d~c!rulce 11 ~ uMIHOS!cl.l1 Tem~e~, q.~S~G, , Redox r.o!¢~~al (illi)~. -,-'1_'1'-'1"--__ Turbidity ____ ..;:6"--__ _ Time:....,.,..__--Gal. Purged, ___ _ ': "~., '. Re!!oJt i?oteiltir.! (Eb), ______ _ Tu(bidity, __________ _ Time;_"' __ Gal..Purged, ___ ~"'" COl1dUCIaIlCe_.~,'"--...,.,~ ____ _ pH. ___ ~~~~_~~·~ __ _ .... :., . ., ... RedoK Potential (Eh), ___ --L ___ _ . : ~; :.: ,". \ ' , ("' .. ..... \.' '.; . , ., -~ nilii!-(i]aTl.'ll~v![M"::· DH;Cll~'!'g~ Il'c.!"lLilil GlamH~\~lll~"l\a(iruiJJ.r[.ijg Q"".!i\V PJJ""",",c.1?1w (QAP) 'Ji\lFiiliiHi,y __________ _ ~{lW Rnte (Q). ill gpm, ! SI611; ~, __ ---.!(f2~ ___ _ ']!'I!,~icl!i~_· ____________ _ Time' ~o eVllclmle liwIl c2sil'll Ifolililles (2\!) T =2V/Q-_________ _ NOlinl,",' uf c~GiMg vvllllueG eVl!Cunterl (if oilier 111ao ti'lo) _____ :-________ _ If wen evacllJl~d t() dryness, number of g.UoilS evacuate.do.:.' ____________ _ Name of Certified An.lytic"J Laboi'atolt}' if OillerThim'Erlei-gl' Labs, ________ _ ffi;-~I.) .. If a preservative is used, Sp~ify Type and QUantity of Preservative: ) l'.&m -Growldlwl{~r .liJ!ir.c~im·g01:r1;!'ml( Gi'mmoi\zl~i:ej Mm .. 1titor~lIg [I.Ie: 2.Z5.07 J!l.ev;siG!l: 2 QUn!i1y J\.sSltrlll100 J!>l!L~ (Q/I!?) fi\'1l:1l'AtCJID.Rr~\l1 n WlHill'll'iE )MliE§A 1lJ~AAl1IiIJlMI MlllLIL . .' ~rniLlID IIJ)A,;&X~:Hr~IHIIE}n;r ~JlWJJm1Ul\llID 'IFf A'Il1EI!X Desci'jltH)i!i of S!lollplmg lElvei11:_ ! . ',-,-C4.1r",b",~",,&,""i?;=-~ ___________ _ Lm:g,ioa (welO HUlMe) T0W, &3 'i ~:~~:~ inili~ls i'~fU-ll i r2y~jJ. Date mul Time for li'i!rgiilg T 2 t· () 1 &luI Sarlllpling (if differeilt)c-__ ----- Well fI'llrgiiig I'lq,ilip Use&J1;uiiip or _~ail~r 'W:eh:~:li1p(if oH~er IilUii BernIe!) 6 v«",,! F~\ Smnglling IEve;!I,--<.AlLLl..!.!O:J."",J.",,·, -,,3c.1(-lk:J#(b'Ult11.eI~!li.le __ pH 3uffur 7.o'----,:--.,-1'-'.~o __ ,___ P!·7~,W~II,~(\f~p.1r~·!r.~ar,(lplil!g Event~--,-,~ ~~~.,~.tiflJrr.~:~;"." .. : :'1.(: ~ " -,I ~ uMHOS~c~ i. :.~~:p~~u,.~ .. : ~.~";'~; ._ " ',_". .'" '," I. .-".........-. ".' Specific CGndlwlnnce 11 8 lDeptll to Water llIefor. fi'll.;gio:---_._. -. -. ---ljl~~~~;:2=:<'~~?~;):~ Well Wnterl'eli1~, (I!V~) ..----- . ' Temr"l;>!f~r~., Z t, ¢ I Redo~Po!¢~~!lI 'OOh)~g,-14-/-,--__ TurlJidity 0 '~ __ ~. Gal. Purged, ___ _ VHL ______ ~----~~---- Tempera!l!re_"'?,,_""-_____ _ RedOl; P()te~ ,ml (Eh)c-_-">.... ___ _ f2(~SOcTV RedOJ( P9~ential(Eh),-__ -=-__ _ / TIme,~ GlII.·Ptu·ged onduclnnce~ -----;7"0------- ' .. pH, ______ -T~---~------ Temperat\!re:'Y' ____ ~---"!..; '_s_' _ Redox. Potential (Eb), _______ _ o C", .. " ; .... ( Mill -Gfa~i1raW[!ter ID.isd!f~·ge P6~lEit GlOt'-llrlWl!ter lWoziltcrillg Q"lliKy il.ro!!f8ilce ]PI"" (QAP) Tmwirliily ___________ _ PUli113lllg Rule C~lci!laii.o~ NOW iRnte (Q), ill gpm. ! Sf6f) = -'--_--1(£2""---___ _ ( fuiiliility ___________ _ Titl1e 10 eVD.Cimi'e two CIlsrng volUines (2V) T=2V1Q-_________ _ Nmnber of eUDing volmnes eVnCuatetl (if oilier U,all two ), ____ ---, ________ _ H welt evacuated 10 dryuer.s, number of galiolls evacudte'dL' ____________ _ Name ofCerHfied Analytical Laboratory if OIherTlirudJti~rgy LnbsL' _'_-'-_____ _ NOII- ". Y N ~ ..... Y N If n preservative is' used, Specify Type "!"i Quantity of P!'eServative: : .. ~. IVliU -GiounC;vl'tlter Dischafge Permit Gmlmdwll.ter Moilitoring Qul!!ity Assl!fance !'lml (QAP) Dute: 2.25.01 Revisio,,: 2 I?uge ~n of <! J AITACillII\IffiNlI' n 'VOOlI'iE MlE§A rrmANlI1UM MlllLlL lFlIIElL~ IDlA1I'A 'jr,PIP'J[§IHIlEIE1f )Fq:»~ ~llRl()lUI\JIDI VI' A lI'lElft Descriptioll of Sa.!llpling Eveili:~I1IL/./-diJ.Yt2.dt"""-~.",f-{'~"",W. ... b",,-,,I/;l,,,I,--_______ ,--__ / Sampler ____ # /J Locution (weli nume) WAf-it r N~e and initials /;:'111tC;I r r Date und Timefor Purging 7-2 /. 01 and Sampling (if differenO'--_____ _ Well Purging Equip Used: ~liJp or _bailer Well Pump (if other than Bennet) brn.d&.5 --Sampling Evellt~ _______ _ -------Prevo Well Sampled in Sampli ng Event. __ _ pH Buffer 7.o, ___ 7z.J.,..::.(/ ___ _ pH Buffer4.0, ___ ~!..:.,_"O"_ ___ _ Specific Conductance 11K uMHOS/cm Well Depth,~.---~======------- ,..------Casing Volume (V) 4" Well: -(.653b) Depth to Water Before Purging CondUci:nnce ·(avg)--_--.::~:..... __ -_~ . 3" Well: ____ (.367bJ pH~i"*at~~.(ayg)~-.--c;:-----=----'---- . ....,.;. 1'" !.; --./ Well Water Temp. (nvg) _____ Rei!~1(PoieIiii~I(~~) __ Turbidity __ _ Weather Cond, UUf(tlO Er.!'1 Amb, Temp.(p(ior to sampling event) d£ G Time:. __ ~~Gal. Purged'--__ _ Tiipe',-,..".... ____ Gal. Purged' __ .,.........:......~ Conduciance,_ ... 5,-,-, 7-'-_____ _ Conductanc."" ____ ----=_=-==;o;'-" pH 1-'fC pH~ __ ~ __ ~~ ___ ___ Temperatur",_.z"'-'<:'--.J..I.f..,b>--__ _ Redox: Potential (Eh).-,,2~7---,"},--__ _ TurbiditY_----'D~ ____ ~_ Tempernture,-:;~-_'_<_------- Redox P~ ntinl (Eh),_\---'I _____ _ Turbidity ______ l'---____ _ Tirue: __ ---oc-Gal.l'urg,':)"'--__ _ Time:---.,,---__ Gal, Purged. ____ _ COllduclunce'--~:-:-r-------Conductance.--'>"...-____ .....".L-__ _ pH ___ -r_-"'.;;:--___ _ pH, _______ ~~----------- Temporal!! e ____ -= ____ _ Temperature. ____ "" _____ _ \ Redox Potential (E1t), ______ _ Re!loK Potential (Eh) _______ _ C·c:-. .... j' : '-.... ;. ( MlU -Groundwater lJilchflrge Pennil Grouudwflter Monitoring Ql!pjily Assurance Plnn (QP.P) Dnle: U.17.06 Revicion: I Pnge 41 oUl·1 Turbidity ~rbiditY __________ _ -----~~-------~ Volume of Water Putged When l'leid Parameters are MelIS1tfW.=.....:::--'=--______ _ Pumping Rate Calculation Plow Rate (Q). in gpm. S/60= Time to evacuate two casing volumes (2V) T=2V1Q= ________ _ Number of casing volumes evacuated (if other tllan two), ____ ...,-______ _ H well evacuated to dryness. number of gallons evacuate.d' ___________ _ Name of Certified Annlyticnl Laboratory if OUler Than Energl' Labs, ________ _ f']i';~ "f Presel-vative Addled Taken 'iI'oth" (circle) (circle) . 'tho;; n' lIelow) IVOCs y N 13x40ml -Yo N " IHCL Y N ~\s ~ 1'1 lOOmI Y c1P ~ @ )f . Y N I 250ihi Y N Y N" IAiT~ Non-ff) N 250ml Y (l)Y No , Adc'ed '. ~A1DlIn Y N l.OOilIIIl y N H,SO. Y N I Other Yi Y N .... -y N Y N . . H a preservative is used, Specify Type and Quantity of Preservative: Mill -GJmm;1rml<;' Ji)Jiscillll'g(lP&,uil G-ri}lmtiviL~/~!lr.m~nrwg QtJJlily Ji.I!r,'!!!S!rell'ln.. (QAPJ .. \ Il'nl:e: 2.2S.07 P..evisio!l::i! Ji'ege 41l of4!i Wl!ll!!:iI1E lWfIi'lilA lUIlW<J11llJThl .M1llL1l, lii'lilEILlIJ) Jj))&'li'm([»~!E'il' JFiO!R GW([»l[ffiJ]!JJ WIll, 'll'JEm D<>'lcriplilEl.m Sumpiiilg JElvell!: .'kL/i~"o!.]IT'--1t:-· ",C,",I1i",DD""J!I·a,.."Lc(,.i __________ _ LoClllioo1.w~Jlm!il1e) Per. / .' .. ~~~I~d illitinls -r,;:,.#, I/. j ~lld4 Dille ooil\1!iindor li'urging and Slll1Ilpling (if different) 1 ·/1l;; f Well Pil@ggiJJ!]llip 1lJ1i~ ~P'1ll ~.wjm~P;;mp (if olherIDDliBenneO'--__ _ Samplil){t[ll'lilll !//!{yg,k ~ rhkad, Pie.v, W,c;,~1 §'lR,IR1~ i!',~nmp1ilJ!?EV~l)t "jI/ I} . pH Buffet"laJ "l.U pHJ~!Iff~r1:9,:;,: ,,;'. If-P ,," '. Casing' Villunie (V) 4" Well: ___ -c-\( .• 6531j) ' .. Well Water.Temp. (Ilvg)._.,--__ ~ ~~(,:, .~.< ,}~~ .. ~:~l~~!G~(I ..... ""-'--..,,~)"-~: ''-.; ~~t1m . (·:~~:::~~~~i,~~~:'''7:q~~lp~r~~' .. -· '::> .~:r,:</)·< :i:·.~:::< . to'blltic/«(1il.~ . i 421 .. .. ' ',,' . ~, pH 1 ~z Temp~~ I. ~ ,1 &-Tempemture7":::..... ___ ~ _____ _ Redox t>0'¢il1wl'(Eb),:--' ',,",,3~\2...t( __ _ ThrbidilY.· , .. _ ... ~. 3~~.L::'-"g',--__ Re7 lenlial (Eb) _______ "' __ Tutbidily __________ _ ·, ... ·me~: :--__ Gal. Purged, __ ---;;o_ T~im::e::: ::::::::-_ Gal .. PlJl'ged'--___ .. COnduclnnce, __ --""..-_-==-___ _ VH, _____ ~~.-------_ pH ______ ~~~------___ Te.-!l!lelratu7 ..... ______ ~:__---Tell1pe~' Red~~). ___ ---'~ !RedoJt Polen!iru (Bh), _____ """'::-- " ("'-, .,' . ~ .. ~.~ . - -- '. 1 :.; \ ',s ~.~ \ ( J1@'U-Grn·m!f!t:(Il'!ter Dfucblr~ Pfu-mli OroilliutrRlter MOmWllng Qll.~Y jl.1lS!!fDllCe Phm (QP.P) 'l.lliilidily ~ F"&041of4l 1'l!Wiclity __ ~,,-_________ _ VolUiilll of Water i'iU'gel'l ~~~il:IllI~J,pP~at"Jliiev!l:.c~.J"'· il!il!·",,,.j\!'t~~8>!l!l!l1~i!il!i·il;ag'b---,-=:::======-__ PmnuiIlgllilte Cn\culntioll Flow Rllte (Q). ill gpill. ._____. S/6f)~ =. ___ ~,:<:", __ _ Time to ffVllclmteIwo Cll!ling volumes (2V) T = 2V1Q ---=-----= Number of Clllling volumes eviicUJlted (if other than twO) ____ :-'------= _____ _ If well cvacunted to dryness. number of gallons evacuat~d, ____ ~~~ ______ _ Nome of Certified Analytical Laboratory if otJierThah\ilni;{gyI.abB'--_ .... ;~.c.... ____ _ ," Non- If n preservative is wed, Specify Typ .. nod Quantity ofPi'eservntive: .! Mill -(irCilmi?rifl~er ~.scdC!r~ lil'ernlit Qmlli1dTjilfl1:!.~l!fl;illt-crifig QllIllity /imlii!,u>; Ii':iIlI! (QAP) J!Me: 2.25.07 l~evisiOll::;! AI TI'!MCilillMllENlf n WlmIE J.l,jjfE§A, 1I1mllruJlffJM J¥l!lJL1L lFlIlElLlID lIJ)&AlJ;Q)ll!Wffii..HllEJE"JI' )!i\01Jlt IGL~Q)llUNlID WA 1l'nrut l)3SCriplirJII'.rif Smnpliflg l'lvelli: P.Ir.L{)~'''''IT'---It_· -kCd.ItILLkG'!Jj~l2a,,,,6(~i; __________ _ (l . :r Jjf!lr1!pIFf '., ___ d JJ Locntion[welllilllme) Mer 2. Nn~e mirl i1iilillls !tlWU/ /I, j 7t1tir Date 1UJi}1Itii®for Purging !lilt! S!lI~pJing (if rliffeJrent) lll{ 4 'f Well PnW!!tBqUi~ U8~--liiliilp'lll' ~er~~ii'p;unp (if otlIer dllm BeruJet) . ___ _ S!l!npliljgE"enl l/lf't.{!l!k J dtiua.dd J?reny~,\I§I\Wp.t~jnS,~pIiQ~llv~l\t ifNI}, pU Buffet"7(J) -:; , 0 pl;l.l'~!Iffer 4;0., . . c ' If:. () . . . ...... : .. :.' .,. ". ... Specifictlmt1hu:tance qql uMHOS/cm . Y\'e.y.P-~I?tf} .. : ,:,.,., ,. ; . '; Deptl) to''IV.l\~''·iilefol'e i'u(gillg /,s-. 'ii / ",' Well Wnter~emp. (avg)I_~ __ ~ -:,.1 We&t1uir',troild.· , .... ,'.. . Ext'l.AlnJj. T~m"'~"d'':,tCi~''ndiifeveiii)' .' .. ~ .. ':; ,::~:~ ~ ·:::~q::'71:::~,,;ri'.) '. . ... ~).,. ··.-t::~ ,.;);~~~~:~~;n:;·5t~ ;':::C' ';., . ~-. ~ . -·:':';' .. ·.l'i '.'. \'. Turle: "(lft:~~f,~)t"(j'1ibiffirgecr~' ,." ',,\.. ..:'iri.· ~ ,;:#i: ····.'-··:~'~.?·.\~~.t~/e;~.i?~i~~g~·:i~.:: :~':':~;Iy/;'':: ':'~'. '.1~ .', "". 1~.).,~-:,;".':'.!:j,·~:;~<,\· .. 1' -. ----, -.,: I Co'iJCI~alu\b; hi), .:2 . . , PH" .' . <J,31 ' . pIt ";~i.:.:' .. , .' '. Temperp!liI~ I Of. q 5' ' ... , ., .' Tempemture'..,...L. ___ ....:>...--___ _ Red~x J>o~~(ijJii~),~~",aJ,.;,.., 1-",,5~' __ __ ThrbiditY.I-__ ·...:.,1 f5~, (~ __ ReZ tentilll (Eh) Tutbitlity, _________ _ 'I.ll!~:----Gill. Putgedl ___ ~ T~im~' ~e~: === __ GaI.·Pmged, _____ ,,- pHI _______ ~C-~~-------- Tempemt.'YI=-_____ -+ ___ _ Ret!w. POlf;ijjm,lflb}, ____ ~---Redox Potential (Eh), _____ ..::>...;:--_ ,(.:--, ~ -.. ' . - " " j :.; '" ... j :.1.' ( ~ -llioJJu;tctlifp.te..r Dicr;Jwge Permit Oroi.!!clrJmer Iworui:mmg Q'<ll'Ji\jl P..s'ilftmce Pum (QAP) Tl!1'jJjilily ~ ll'oge41 0f 41 -'fmviclity_--=-----=--________ _ Voll.!ll!e of Wflte, Ptu'ge!l ~t:ll;,jjg~affiiiiii1lii!ics!.e;wl!ls'l!a!'Ct'atolD;\IIl!ae!!ll!!lll!l!Ifi"3;£l~=-~:::::======_ __ Pu.mpingRllte CalcpJntion Flow Rllte (Q). ill gpill.~, S/6f)= ='--__ ... ~"'-__ _ Time to evl.!cunm two cllBing vol= (2V) T = 2V1Q --=-=== Nwnberof CllSing volwnes evrictil!lerl (if o'ther than tVlO), ____ -,-"-----"'--______ _ If weU evacuated to dryness. number of gallons evricUlite.d'--___ ~~c:.. ______ _ Nnme of Certified Analytical LnbomtOIy if Oilier'fhitiJ. EoergyI.ab8,--_~;""~,,,-___ _ -. If n preservative is used. Specify Type and Quantity of Pi'eservative: ,.t : .• '.! Mill -GrolIili~'mtff Disclm!ga Permit (Jr6!lJldi1I1lC!ij!~llitoring Q.ulliy J'JJiM!~'.D" Pill.' (Qfol') An AICIlill\.1llER!'l!' n 'WI"..J!I1I'1E IV_A W AI\JllllJlW MlIlLlL lFJllEILllJJ llJJ.Bl.'Jl'4 if(j)i~l!' .' lR GlR(j)i1UN@ W &1J'lEiR Descri¢.l1iI.rif S!l!Ilplifi!g Evem:-tl!ll ,/ Q' -~~ _________ _ LoclltiolJ.\(l'I6llimroo) R-te 3 :~~~~~d illitiEiii; t:,:,;U<l' II. j ~tld4 Dnte p.niJill:imofor li'Il.l'gLlg and Sati1pling (if differelJt) 1/1/ il'f Wellli'n!itlg~lljl1!ip Used: ---JfuJiiP'01 ~er We!i'.p;,mp (if otller dllm Bennet) , SnmplillglJ9.e1ll /1./1' {(tuft 1 chlJlfMk Pl~~ ,y.:~~,! §1!lI1!\!,e<!. ~I. S,~mp!i.I,Ig Ev~nt II IV;j . pH Bulfei"la.J 7 .0 pHIluffer.a.O .. " Ll,Q , " A'.' .:.:.' • !. "':: . ~ . Specific·ltDhl!llclJlnce qq 1 uMllOS/cm . ~e,n;Pt~~ .. ". ":,,,' .,;'-' :,' DepUI to':WJiil~flllefore l?tuging J t ' oj'" Casmg.VolUine (V) 4" Well:. ___ ...c(.653Jj) , ,.".; ";,;.;:" '.; ," J" Well:,:;, , (.31!71il on.;. ··~i~~j~;!'i'!.:ri·b~,\';!/.'. " , ". j. '-'§<.:---·"~ut~!.{""l~"'l~Vr~,!~~~. , .'.-.'J"~:.:_1·'''A· .: .~: "-,,lIuucw",!~,\f' Ill', ,;",:,;, ",' .. .., , .. " .... ;. 'M!,oA~.\¥.il",r"av!l' 'f ,'""., .. ' .J" .... ""~"';:·%1:«.;:'I1.~lf'~Ji~~i~t.~)·: ',',' I' ""~!1:"~:;. '. ~JI;-,if¥~~~~114' .... 3i-j~·! \;. :,,'..;,;)')': Willi Wlilfll'~CriJp. (avg)' ____ ~,· " :~f~~~~;%$i}~~~O/-t)( ,)·~Tijrbidity __ _ wet~r:~:~,:::'~;i';f:X ' '". ;~i'J.1r~~:7!'J~rfl:f~1~~!fu::e~~~i)'~';-:'7"-"":";'-'~'.,' "., ~irii~;:, " . ,\!~:~,;::~~:';::~~/~~~~";" .': ~::;."'. :~ ·:~:;~:':~~F?~~::~~'~~)t~~~~:~:~ ... ;.:.<.~ .. ~.~.i)y~~"~':'!~/; .. ': dln:dudiillM ',·/2 n . ,-. ~~r ____ ~12~.l~1L' ____ _ Tempe~_ "/ Q.13 ..... '.': I,.. .' Redox I'Q¢j@ii~~?I.,.. •. ....r;/)~ .. /~)_· __ _ ThrbidilJ. }J 1 ~,JJ·!!!iM!"O;: ___ Gal. Purged. ____ ~ pHl ______ ~~---- Red POlWlW:{lliJ), ___ ~_- Temperatul-e,...,..~ ___ --,>~ ___ _ Redo9 tentilll (Eh) ~dity , T!..' I~'m~e:: === __ Gal.Purgedl ____ ~ Conducmnoo' ___ ~c_--~~------- pH' ______ ~~~------ TemjleKatul'!V"' ______ >l.-__ _ P.edor. Potential (Eh), _______ ~"" ", . ~:, " .. -- \ ( ll/iill-G!OOE<l\~nler Visclmrga Fe,-",i. Onm.rulP!8t*f MOil.lI:CJimg illate: .U.I1.CS Re-1.i!i!rnL ! QlillIiiy Ass!!11l!!Cil PIEn (QJlP) 1illi:biility ~ ~---Th!~iclity_--,~ ________ _ PumDi!!gRllte Cnlculntion Flow Rnte (Q), ill gpill, ____ . S/60= = ----'----"""""'---- Time to evIlcllllle two cru:ing volumea (2V) T=2V/Q-~ NWilbcrofcasing volumes evilcWJted (if othe!' than two)'--___ :"-----= _____ _ If well evacunted to dzyneBS, nnmber of gallonS evacunte.d, ____ ~~=_ ______ _ Name of Certified Annlyticnl Lnboratory ifotIierThiiD Enei-gyI.abs'--_~ • ..,'~"'_ ____ _ Non-' Other If n preservative is med. Specify Type nod Quantity ofP!eservative: ,I ,1 ! :1 1 ) I , r 'r: l " t Ii: '.: ;- Min -(1-rumilvJf!!er Discilllrge lP'errmt Grol!iIr1V7lO12.l~(}uitormg Qil&lky JiNu,.Vf<f)fJ I!'l!m (QlIPj DC!te: 2.25.07 JRevlliion:2 li'nge 40 of til a'll"H'AClHlMilEN1l' n 'WIlllllJj'lE lUITE§A 1IlJaANJllURl,! MlilLIL IFlIlEIL!iJl JilJU4 WI[]IJJm§1BiJElE'i!' )li'\Ill~ GIlUJlIlll'.Jl!]) 'W AI.'1l'lEll! DescriFlilm'aI Sampling Event: NHu.:rf 1 eWe! rJc. 1\, S,l!IIlpler....--/J !l Locfllion1.1'!eJlilllJile) r, f£ L/ Nruiui aiul initia!s },,7",,*'-I/, j t'Awdr , I Date aniJ'ilmfor Purging and SllI1Ipling (if ciifferent) 1, I'l 111 Welll"miliggillquip Used: -pump,or ~er Welfli'lImp (if other limn BelUlet)'--__ _ Samplillg:lJ=l AINYfI'h J drkaltitf Prev, Wen SIlJ1II"ed in Sllmpling Event 6 IV/) pH Buffct'7{O'--__ '..!..I..:.., ~() __ _ pH Buffer4,O, __ '.-:.l.f._, 0"--___ _ Spedfid:lllnllu.ctance qq 1 uMHOSlcm We.!l.Dept\l~,,-, -.-,.,---.,. ______ _ • Depth tdWJ.\!fxJlefore Purging ,:20, r'i--Casing Volume (V) 4" Well:, ___ -:(,6531i) , , " '" ' , " 3" Well: (.367li) Ccndlic~(,,;,g),_' ;~~ ___ ~_~~ ~Im!~~~i~r.~H)-'!:i-'~, '",,:,,-: ---"--- : ;. ·:.1}1<;,t .•.. ::., t i ~ Re<lil~1>'6te'riWii'ti';,·), 't~bidit .... ,'''''''--y---, ",,',' , Well WnlctTemp, (Ilvg), ____ ~ WeIltheraIDn'd vb.... $ s/4 tJ-I5r~t::cG--; Ext'l Amb, Temp;(p'~jflriosal!iplingevenl), ___ ' _' _ .~ I, . .:... ... rid ' ' , 'riJiie: Iw.t · G'iij; ~i:g<;dL-__ ~ . . , .... , Colidtici81ICe 39 7 i Condllc~nce ", pH<---_ &""-,, &:.cc:2.-'-___ _ p"~~~------~~---------- Tempel1illiI1L 2 (,j. 25 , " Tempernture'7""-___ ..,."".,-___ _ Redox POleiItlJii(Eb) , ').£i TurbidilY._--,-13",-,-~ ...... / ___ _ R7 [ential (Eh), _____ "" __ Tutbidity __________ _ T~im::e.::: ==:::::-_ Gal. Purged~ ___ , Conduclmtce, __ "",-..-_'7"""'-__ pH ______ ,~~~--------pH ______ ~~~~----__ Temp:;'rnmrc, ____ ~---- ReaZW,lElJ)' ____ "" __ TempernlUll:r-______ "" ___ _ Redoll Polelltinl (E!J), _____ -::...,,-_ -' ( It@!-(h"o~ild(1ll!t6r Discitm:ge P&'Bt Grol!!idrlllter M'oaito.rltlg (t.mlily P,sBl!fDnre Plnn (QP.P) P"ge~·l of"l TurlJiility ~ 1'uroidity __ -=-________ _ Volume ofWlli:er Ptu-ged Wt.S? F~flnaGhicwlJ 616 MeaBHf89 Pumping P.ate Calculation Flow Rate (Q), in gpm. ____ - S160= =~ __ ~oC.-__ _ Time to eVl!cnnle two Cruling volumes (2V) T = 2V/Q -.........--=--: Nwnber of casing volumes evncllJ!ted (if o!bex!ban IWO), ____ --;-'----= ______ _ If well evacuated 10 dryness, number of gallons evacuate.dc-____ ----=-______ _ Name of Certified AnalyticulLaboralOl:Y if OtherTban Energy J..abs~_~;"'......._:=="'--____ _ :J!'ym ofSam~e SsuWI£ ~nmi!H. Vol"",. Fillered I!reserrvntive a.ldell ~ andicate Itollier (circle) (circle) (circle) . 'tliolinS soeclfied bOIoWJ , . VOCs Y N 3i40'm1 Y "N ,-HCL Y N Nutrients CP N lOOml Y IN! .H,sO. WN Heavy Merola Y N 250 ihl Y N lIND, y N All Other Non-~ N 250ml Y ~ No Preservative Added Rndiololtics ; .' ., GrossAlpbn Y N 1,000 mI Y N H2SO4 Y N Other (specify) Y N Sample volume Y N Y N . , If a preservative is used, Specify Type and Quantity ofPreservntive: \ ! :1 ; J I, i ; 1 • I. I'. r !: ,. Mil! -Urilllllill'Jr.ief li);EclllUllo Ji'eruili Gwv.i1dVJ1flG!.?J!Dillloring QiiDlity k .. ~oe 1'100 (QAP) Page 40 of 4! AnACIH!I~Nl!' B lJlIJfI!!!'jj'JE J.MIIE!!A ~ lWlffi,lL Jli1lIElLllD l!J>AI'll'4 ~iOI~ )FqJI1lR lG~iOI11IDJ!I]) Wi! A'll'lim. Desciip!ii7l1'df S!lI1l/liiDlg Even!: tvHrrc:.cr f [,It/op,! rir. , n, ",$.!lf~pl~~, """ ,. _____ /I j d. /J Loc!llIOll!rPmll'1lllme) -y>q ,s" NUli!e!!l!d lllitmls !r;lff%<I'lt, '711r{( Date l!lliEliirnefor Ji'urging mid Sampling (if different) 1.flj-41 Well JPnW~g;B!JllipUsed: ' ---Jli.m'!P!Ol~erWeii·.p;;mp (if other .!han Befinet),--_' __ _ SumplnJ/iJJqeJij /l.1NY€lIk ~ rltluruik Prex,,~e,IJ§~p..~e4, ~lS,Ilf,IIP\iI!g EV~fit i!f IV /J . 1. () pH-BUffer!W,#,,-,'-. -",.~.' --,:L!,",-., -".,f);-,-' ~. c'-!,-<-"'¥"~ . .. ~"',:. ",. (.""~~-'~ Spe<:ific'll~!iilnciance q q 1 uMHOSlcm Depth to'WlilJo,dlefore I!'Iqging t; ->. Z () Well Wa!!lt.Thmp, (nvg)._---'-_~~ pH '. 7, 10 Tempernll!le ,;;)3:2- Red~~ ~o~~~~):-' ·'7'3;.c:.. u/ 6:L-__ 1\!rbidi~"" m: b pH __ , .. _-7"-~----- Temp~~rum/'~,---~~, __ ----- )Ve,'!U?1l~Il}.,:: ."",.: . ,.: ....... " , .', Casing VoItime (V) 4" Well:. ___ -,-':(.6534) , . TIm:,:'::e::: =:::::-_ GnI,.Pu;'ged'--___ ;- pH ________ ~~~--------- Tem!'erat~'--------~---- RedoK Poten!iu\ (Eh). _____ ~ " ( I\!.fill-Gl'ir.ri:«Wfli:Br Duwill!rg~ PC-writ emllrill{1Jllt~! l't«omtn.rmg Qu!!liiy P.Ds!!wn"" PlmI (QP&» Dale: H.l7.U.s P.mririion: ! TnrOi~ity,~_~=-______ _ ---- Volume of Wlll:er Purged ~~J~rE;G15=;rireE!!1:.CiS'!S'1m!l!·l!>e.j\li~q,,!!lem!llI!i'!ii;!.s:t:' =---==:::=====~ __ PumlfingP..ate Cnlcl!lation lFIow Rllt6 (Q). ill gpU). _____ StuD: :, ___ ~~ __ _ TIme to evllCunmnvo CIlSIDg volumes (2V) T=2VtQ= --------= Numbuof casing volumes eVlicunted (if o!her tlw.n IVlO), ____ .,.------=-_____ _ If well evacWl!ed to dryness. munber of gallruis eviicU/itC.d'--___ "'~OC_. _____ _ Nrune of Certified AnalyticulLnboflllory if OtlierTIiall,Enei-gyI.ab~'___~;"'~~----- tJ8~ _ If a preservative is Used, Specify Type and Quantity of 1'!'Cservative: ,( ; . .t;,.. ) Mill -Grilmlili'&U'i Disclmrgo il'e..-mil GrOlll1dwatcilfwllitoong Q,,",ity J\9rn:.filll.re]lJ1!il (QAP) IDa~: 2.25.1)7 !<!evisioEl: 2 .A'li'1I'A(c1!II!lIillEN1i' n VfVllilll'lI'lE !MlJE.§A IlJlM.Nlll[JM MillLlL l!!!lJEiLIl)) lll!Al1!'A 1'I'JiIlJIU§IHllE/irn'IDR IGRI01[JJ\JljJ) W'&':il11l~ D~5cl'iplimn:i'i:llnmplillg IJve!il:_fI >:teale tI Gh Ipr;'J e. 'i "'l>'1vlj~ g, ," $~p,l~r ------)' II' \ Location (wcltlmme) M W I ~ Noii!e lliIlI initials :JwIlGc 'jo .' rAf"'~ D.le andl TID1e"lfur Purging 1·-i"\ -~c\, mid SflJUlpling (if differentL.) _.JJI\<LI/.jl;iI ___ _ pH Iiuffer1~O'--...,-Ll""'O"__ ___ _ pH B.uff~r 4.0. ,,' yO . . "."):-'.:" ,;-; .. \,~. < .," , . , . SpecificConjfuCbmce~'l.CI~c:..k __ uMH,OSlcm We..I.!p'~~.tJ,t.: .. ';'" ,I.~~I" '. ' Depth 10 Wmer'Jleflire JPII.;gialg 7 I· ') lj COil'd«~~xA~ '(""):;&7 . , '. { ,,'" . Well Walei.Iiell)ll. (avg) , Y . '3,0 CoMu.i:f4nt~:..~3"","S-.>J",,.-,SL·: __ -- pH CoSY Tem~eraIt!I'e...,.-:-'-I-L\:....: . ..:.1 ;:;0 ___ _ Redox Pot~~I!;ri~?:,_· .,....,llS::..G=--__ _ Turbidity 0 Time: on 6 ._ Oal. Purged '+C, L\ Co~duclllDce--1o.L)5 .... q;_"_'S~ _____ _ RedOK PoteJ11iiilWllb),_-,-,l G~:7-,--___ _ Q CasillgVolufue(V}4"Well: 'lOg, , ',:oI!dtiCI~,~¢~;,:;)s. 75 , . ". . ~~"i":6:>j~:· . Tempera,ure'-+.i y~,d,z>' ..... 1 ______ _ P.e<iOJ( Potential {Bh)-.l..,h_I ____ _ Turbidity __ --'O"-_____ _ Time: 0'600 Gal. Purged '3 (,.-:, Conductance :Sf) O'S '. pH c,.')\ Temperlllllr<l i L/ ,. 's:) Redo}, Potential (Bh),--'17 ........ 7L ____ _ (';" .... .' ( Mm -6Imillw.nt~.f Dkcb~~ t'c;Imt Oi.lJUEr!tTill~r Il.~oill(ui"ing Qmiliiy AEnlliW"" J?bm (QAP) D",te: 11.17.65 Rl3vjnlau: i 1\<!'ilillit.Y.:......:·--'-________ _ 1rwbidi!y~-=======~ __ Flow Rallo (Q). in gp;n. S/6fJ=" • 33 Time to eVI!cllllle two coomg volumes (2V) T =2V/Q-;It.J7 iJ.,;" Number·of w;ing vol\!mes evllCwiied (if othe," llta11 two), ___ --..:".,:y"'Bc-_____ _ If well cvnCllllted to dryness, nnmber of g,;]Jons evacuate:d'--__ ~()"-{/"'ft"_ _____ _ Name of Certified An.lyticnlLnboratory if Otller TbJulEnergy Labs. __ -'.1""I.c../..qQ ____ _ If a preservative is used, Specify. Type and Quantity ofP¢servntive: \ \ J ) Mill -Grl3tmU'I'lmr Dischmge Pe.rmit GWVlldwnrei J!li'rulOring QtmI'ly J\J;s!!"1lF>ll:lHon (QM') Dn",: 2.25.417 l~evisioll: 2 Poge40of41 A'll"iI'AC'l!III\.illEN1i'n WlI1ll!'Jl'1E J.lhI!E§A llm&Nffl[JM MflR..!L lFillEiLID> JIDA'lI'A Wl!lJmrwJHIlElE'lI' m~ lGiitl!lJUNIll> 'WA":iIlEiP. Descrip!iomifSlliil.lllillg Bvelli: A I -tr«\< #. d, lor: 1<.. ~"'rJ:·''ft . Samp.ler /.. LocgtiOi1 (wmhrnme) M vJ Iq N~e Iliid initials I.once Idol!. ~f"'1 Date and Tim.e:fur Purging 1-i L\ -Oc:\, and Sampling (if different)_.!I!\u.!(:p.It:'-___ _ Well Plllgi!lgll¢." Used: :;Lpv.mp or _bailer WelllPump (if oUter iliaD Benne!) 0 EO D- SmnplingEv.ertt N:\r.\, d Ghlo~<\< Prev. Well Sll1nl'ledinSrunplingEvent ;vll.1 18 pH Buffer 4.0. ___ · ",Wl.-'()~ ____ _ Specific COIiihu:llmce '1 q If uMHOSlcm Well Depth,-o-.-JlwLiwqL. _____ _ DepUl to Water.1Jefore Pll.(ging ~ 51.13 CcndtiCiiliICf,>:(rl\!ii),_.l./ Y..L3;).3~~_~ Well Watetli'.el\l'p. (avg) IS . 00,. Casing Volume (V) 4" Well: (,3.(10 (.653h) .' .' ,. .... 3" Wen, AilI} (.367h) pH.~!~ri~r,(aili>·-",·~7~·.!...I'i~---'~-- , ;.t. :,i,'. ./ ", . Rei!~~ Pii~~ii~ ·@(t)).'l3 Turbidity Wentber Conill •. _S2.c!:!!.A!.!l'4'!--'-__ _ Ext'l Amb. Temp.(p'\'ip~ to ~arupling event) "')'3 . '3 . <.. . : -. . -, ",' " ,', .J .••• Tii!te;. 6106 '. . QlIl. ftirged 'lSS,. " " . ConaucillllCC_':t,!..:°l.,6L-____ _ Condl!ct~nce'~--.Jl\-. 2-'" D~\.,---,,,--_~,-,",-,-,- pH! ____ '7.!..;:;·O~"\~ ____ _ pn'~'~'~-17~.I~I ________ ___ Temperature,--~If..iS2..· .1.Q<.:D=-____ _ Temperature I !)-.I""> Redox Po!ertlilil,r.Eb)'_d.l",S~7:...-. __ _ Redox Potenti.l (Elt),~?-==-=t5c..clL... ___ _ Tl!1bidity b Turbidity I . X Time: 09~D _ Oal. Pllrged ?-1·45 Time: 190;' GnI. Purged,_3;:>.·"'-'-__ Conductance 131Lj COndllCI!!I1Ce'--""-3"b""3..L _______ _ pH :z 15 pH 7.;)..1 Tempei1llllre __ ..-l. t)..!.:..!. 1...!o8~ ___ _ Temperature'_-L1 s.d.,;..O""S~ ____ _ RedOl; Potenfial@.h) :') 07 Redox Potential (Eht.--,-::':=..;...i 34-. ___ _ --r:rb _~3:>-.Q8 __ _ (-: .. .... '. C": .. .-.' ' .... , ( [>!,ilO -lJwl£ndrlO!£;-Disc!!llrge PeaEtit /JrOmWFlll,;;; MGirltoring Q'!l'liiY As2ilitmce Plno (QP~P) ( Date: lJ..I7.U5 Revision: I Page4lof41 Tt!lilil!itY._----________ _ ThrtJiclily'_~===::::=~ __ _ PumPing Pill!e Calculation Flow Rale (Q), in geill. S/60= ,33 Time to evncilllle two casing volumes (2V) T =2V/Q= 3'67 M'", NllIDber of casing volumes evacuated {if other than two) __ -!., .::;,:.:1-;-______ _ If well evacunted to dryness, number of gallons evacullledc-_--'''"'=/'''!\. ______ _ Name of Certified Analytical Laboratory if Other Than Energy Labs'-_-"A"'IL/,qJj ____ _ ~ofSrump!e SlIlIml. Samlile Volume lFiInered jEre.'ll"VDtive Added Token (Wdlcateif iitiier (clrde}" (circle) (cltde)' . ·tlialia.i:'8I!!!£i6ed ""ICily) . -, .. ' voes y ·N 3f40 mI y . N ,-HCL ¥ N Nutrients (X) N 100m! y (Nl H2SO4 O? N Heavy Metals y N 250 mt Y N aN'o, y N All Other Non-(!)N 250 ml Y @ No Preservative Added Radiologies " ., Gross Aloha Y N I,OOO m! Y N H2SO4 Y N Other (specify) Y N Sample volume Y N Y N .. If a preservative is used, . Specify Type and Quantity of P!eservative: I I I August Sampling Event !Viill -G,O!",dwaler llJli,eh1)j'ge Parmit GrOiliIDwtll'..r MOiiitoring Qillllity lI->sill'IlJlGe FInn (QPJ') -~ LOClltioil (well "!lme) lIN AI -5 Dale: 2.25.07 Rev;sio~: 2 Pngc40of41 Dale and Time for Purgillg f{/5"' of and Sampling (if different) 'to :21-0f Well i>"urging Equip u~~~ '~i1wip or ~~r ·w.~\f~;l!np (if oUler than Bennet) &'1kJ 6/P'tti17;/I} &,,' k/ SamplnngBvent ;:[,,;hJ 1(>.(" ~~,W.711 S~pled;!I1.S.lI!1'pling Event till · pH Buffer 7.0,_-;--'1.c.:..-"O'----:_--,-_ . 110 pHBuffer,4.0 ... , .. 7, ... '.. . .. 'i . • • r' .~! I ':' ": ': '. ..;. ~. '. . .; • Well;D~p.th "". is!?, v,~", ,/.6'0. D' 0 •• : "., '·:~·I:.'·';· ",: '1-'! .. r..:.\ :'1',. " " ; .':--<" " " Tempernture'--__ y"-_____ _ Redo"p~a Tnrbi;hty ______ ---=>.,-__ _ Ti=~o:==::::::::__-GI1I, Purgecl'--__ _ 'J'ime: ____ Gal.·Purged, ____ _ COllductance._-->.;:--________ ___ Conductauce._~ __ -----7"''--- pH------~r--~~ __ _ pH, _____ ~~---___ 'i'empem\'J£e,_-",...,:::._"""" ____ _ Temperalllfe'7-"'--__ --\-_____ _ RedOl[ P Lentin! (Bh), ___ -"-__ _ Reaox Potential (Eli), __ ---'''=''''-__ .... . . , ~t. «: .. . ," ; .... l ··: .. j ..... ~ ( r~ -Gm,ll£l:rt.Wlltet IDmc5wlge Permit Grouua~rt!t6!~ Mmlilorffig QfrPlily fI.1lmlmnce PI!lfl (QAP) Volume of Willer !'t'Iged '\TV1!eil k7ieio1 Pm:amelefs VIe Measurea'-----__ ....----------=-=::=-____ _ Pumping Rllte Ca!culatioil Plow Rllle (Q). ill gpm , Time'to eVllCiiule tVJO casing VO[1lll1IlS (2V) S/6I)= = ~--------------T = 2V/Q _--"~:::=====-___ _ Number of casing volumes evawated (if eillier !Ilan two), ___ -'-----=-:-_______ _ If well evacllilted to diyness. nnmber (If gallons evacuiile.dcc" ___ ------________ _ Name of Certified Analytical Laboratory if O!lltii:Tlla~'Eliefgy Labs ' ~ If a preservative is' Used, Ii ify Typ and pee , ~, . Quantity ofP¢serVative: Mill -C")"~m!~wg!er h);sc!lIl'l5" Permit GHmu<l.Jgter Mouitoring Qmilily h smrutce i'hlll «(lAP) ATI'AClHllVill!ffil'iI'1t 'WiHili'Jl'Jij; lWlE§A 1l.mAlWllJIW lWlllLll.. Vale: 2.25.07 P.evisio!l: 2 lFiIJIi:iLJJJJ llM 'JI'A WUIllJ. .:§ J m:'iI' J Jfg GIf&IJ)IlJj\J)]JJ 'W AI 'Ji' " !)e.'lcripi[{)!1 of Smllplirng lElven!: I' <'j ,-' t ~ /" /" ;J vt I " $.Wr.tp,l~r . .' 14 -/) Localioil (weli ruime) fhJ AI· b . Nai'rici aM iiti!i~ls ~d l1u"",,</ 20;-' I Date antll Time for Pwgillg 8'.l!® {; ci Illid Sampling (if diffe;rent),_u-~,-,,~,,-_ Welll!'urgDng l'lqijipU8~~: '~ililip or vbiiti~[ 'Wklf~;(mp (if other Ihoo Bennet) k.J 6~,Io, cQ7 c...-;J,., 'L/ Sampling Event :J;;,./-,-v.! ,&5 ,.. Well, Waler tell1p, (ayg)_-:-~ _______ =_~ coMi1cl?~lce It 2 7:, . pH -:fic/':' " f Temperature . (3.11 . ~ed~~~o~n~QI~~j""'··''7"'}L.., . ...:5--,!f,-· __ _ Twbidity' __ -L.6",-{:..::;Z~ __ _ Time.,' ____ Gal. Purged, ___ _ Conductllllce'_---"'r'';7..:::: ____ _ pH, __ ~~~r------ RedOIl Potential (Eh), ______ _ Prell, W~JI.SI\II1l!lediq S,8f1lpling Event /0?' .' .': ' ,.. •• -I. •••. .' • ~~~ '. ,,'".:,., .. , Ti,'III<=,--__ GI1I..Purged,_-==--__ Conductallce' __ ~,.L.=-------- pH __ ~--~------ Te~ ronue, ___ -\ ______ _ RedoK Potential (Eh) _______ _ '. ~ (> .' '. ~' :.; ., .. ' (' , lV,till-(PllPSll~~VJai:el1D1£;dwrge Permit GrouiilltiiI'Btlf.! lWnillfarmg n "te: H.17.!15 Ro vinioll: I Q~pli(y Alls,"~nce !i'lnn (QiJl') Page 410[41 rmbiilily, _____ -.-::.-------------=___ ThWiclity_-------________ _ PmlljJwg P..nte CIllCIIMioll FiG1II RI!te (Q). ill g)!lm. S/60= .-'--___ 1--__ _ Time'lIl evacilule two cm;mg VOIIliIi"8 (2V) T = 2V 10. -_____________ ? Number of casing volunies evaclIuted (if other than twO), ___ --=--------: ________ _ -------If well evac\lll!ed to dryness. number of gallOlis evacuiite.d • ..:,,-, ___________ _ Name of Certified Analytical Laboratory if OtllerThiinEtie'rgy Labs._~_· _' _. _____ _ If a preservative is used, Specify Typ~ 1I'ld Quantity of Preservative: Mm -Gsm.El1ovmt-r;r JDIfficburge lPemlit Gwund,',o!M MMiloring Dme: 2.25.07 lkvisio,,: 2 Qu!lliiy Ammwrn:e i"lflil (OM ) A'JI'1I'AIC'lH!J'¥!IEWll'R WlliIJI'lI'JE Jl..1l!!!:§A\ ~ RIJlIlLIL fage ~AI of 4 i IF_IID]]JJA'll'A;rm .l!lffii: 'I,lli' ~. ~~1UMJJ 'VIl ' Descripiillll of Sampling EVelil::-Us..'::.:l'~:rtJflf.J,~UJ,!J1JJ:f!,~U;rL--,.J-.,IJ!J.£JL,MW.+-__ _ Location (welD i'!ume) 1'[,.,)61-1 ,. ~~p'!er , Np.~e aiid iliitialCI""'11LlU'-I-=!JO.<"'--__ _ Date PJlca Time for Purging g. 2 ~ -(;1 /1111(1 Sampling (jf different) r: Z 7-'0 ? WeI! Purging IElIi\UiP'iU;eiI; ':":pilii'ip or ~ii~r 'w'~il'~~mp (if other thad enne£) i?nb 4xfbc<-~ &. ,'k.l( Sampling Eveut ;r;.,if,.j 141 Pfe~, ,Well ~~p.t~d, ~l Sl!O!plingE)'ent /VI[., pH Buffer 7.0 1-0 pH,; Y!#];,er,,4J!;: ',", ?t,t:?, ",: "" SpecificCondllct1lllce ~~~~ ~~:/cm , ,w.~,~;~~gt!r,,; ;:',;,;'",~ ,,, JIJ~, 00 JDeplll to Water l!Iefore ,~. 1.f!: rll Casilig Volume (V) 4': Well:.r-(.653h) , " " , ; : "" :~)';" ", -;;.1, 3'!' Well:. "..,.---(.367h) cQiUlaHiin'~;(Mg:f< .;~ , .. ;:j{l~f~i~li£~1:(a9~):t ' '\""';';" ,; " '. I. ". 4 ;· ... ',..·'·l.;{~t .)I~¥fr.A!·:';;'?:'j"'''~'' .J ._ " Wellwoter TemP. (avg) ----=--= l~~~~8~tltft~;M' ~bidit ----::~ .'···~;::~f;l;.~V,~::;f,~Th.l.d~:~~ ". . y -~- Wealli~(Cond.·,~ ,.c-::: Ei;t'IAmb: t"infJ:(j'rI!lr:itfBiim:pIiIi~'i:veiit>"~ , '.', ,,':,";'i·{ .. ;::>:',Ji;~~:· ',":' ,t~~>;'::'~;~:~f~:::i;'~}V!;})r;,,:,: '. T' ' . '.!'i\ilt;: .. : ,;,~~:~~J~l\rr.~rge,if '/ ' .. ' .:::··~f':'""!iC;'';:F·?i:'q~J;~ii'f~\i4 ' ?:~'~~":;'''': " toi\!1~cl;wce : "116 1, , ' PH ' -1.ls· TempemJl!re ,/5: 6 i. Red~~potentini~~) ,~, '6"1 T~bidity . 9f " , Tp1'Ilw.::==---...:::--Gal. Purged, ____ --:- COllductance, __ --'>~-:::,,-==---- pH, ______ ~~~:--------- Tempe e, _____ --'''''_. __ RaUOK Potential (Eh) _________ _ rempernt~~ ____ ~ ____________ _ ox Potential (Eh),--'t--------- Turbidity _______ """"o--__ _ ime:-"._---Gal..Purged,----- COnductance'--""' ____ --:~-='---- pH ________ ~~ __ --------- TeiiIperainre~------..:;o..=---- RellO" !ential (Eb) _______ _ . ... . !; ;"1'. , C":" " i .... "" '" , . " -' ( " ,.. Will! -(l,,,,,,,,lwnlel Discharge Pelmil IJw!ll<lwalel'Mollilarillg D&te: H.17.1l5 )i'"wisioil: I Qunlily AI;sl!fance PI"" (QAP) Pago 41 oUIl TiLobirlily ThrlJitlily < _______________ • VolUllle of Water Purged When Field Parameters rue Me~sured,----",-=--==--=== ______ _ Pmnlling Rare Calculation ",. , FIDW Rate (Q). in gpm. 8/60= =' ___ -'-__ _ Time' 10 ewella!e iwo~IDgVgjlUIles (2V) T=2V1Q-__ ~~",,-_____ _ Number of CaBing voluoies evlicl!aled (if oilier tban two), ___ .::.--------'--_______ _ If well evacua~ 10 dryness, number of galiOli" eVaciJali:\'dl.:i·',,-,· _-...C.-----=--________ _ Name of Certified Analytical Laboratory if OUl~{t~ Erii;'rgy Labs . .------------: (specify) cU-r)f.J P.-esenrllltive Addeo!! ~"c" ••• :' If a preservative is"used, Sp\:cify.~~ Quantity of l'ie8eriiative: 1t4m -Gi.m.!:rnh/IJli~ej· [Hscimrge JP'errilil GW!!OO,JIlto< MiCiuEaring Qwruljl Mlli'anCe i'lml «(!lAP) pH Btlffer 7.o'_-.,-_1L/~O,---___ _ Tcmper~t~re :. N. IS-, Red~~I'O!¢n~hI·~b).' 41,2, Turbidity, __ ....J.:t-'!.!=3~ ___ _ Time:: ______ GaL PurgOO,_7""'==--_ Couduclu!lce,_....:::....-_".::.:...-. ___ _ pHl _____ ~L-~~------ Tempemtu:;;""' _____ -\-____ _ llooOl[ Potential (EII), ___ '--__ _ D"le: 2.25.07 )[evisiml: 2 J!'o.ge4Gof4R ('~;', .... ').'emperatul'Y':"'-'_~,<-______ _ ROOOJ' otential (Elt), __ --"."" ___ _ .' Turbidity, ___________ _ l'ime:: _______ GaL·Purged. ______ _ Conl'luctance' __ -2> ____ ==---- pH' ___ ~~~~ ___ ___ Temp~ ~, _______ ~~ __ _ Ream[ Potential (BiJ), _________ _ \.' :.; ., .. ' .. fVlill-araml~wlltel Disc~:lllrge PemIii: aJ.ro1!llfiwtlWl'MoaHoring /!}8(''; II. 17JJ,s Ravinion: I Q'.wliiy AnsormlC<: finn (Q)Ll") Page~·1 of4·1 TlL®jdity _____ ~~=~_ 'fufbicli'Y~_-!==::::::===~~ __ Volm11tl Gf Water Purged 'WIleil Field Pammelers m'll MeasuredL_~======== ___ _ Pumping Rille Calculation l:llow Rlll:e (Q), in gl'ill. S/6f)= -. ____ ....l' ___ _ Time to eVOocimle two casing volumes (2V) T =2V/Q-~ Number of casing volumes evacuated (if other tbali two) ___ :o ..... ---------:;=:::=------- If well evacuated to dryness, number of gallons evaculite.de:.; __ ~-----;=:::=-______ _ Name of Certified Annlyticl1! Laboratory if Oillei:Tl1an Enei·gy Labs ~ Non- -'. y If a preservative is' used, Spl'Cify Typ" ~d Quantity of Pieserirative: .... 4356782224 Illlernatronal uranrurn 10:5330 a.lIl. 12-23-2009 (~ Mill -Grmmdwtllfl IHSG{mj~ Peff~~ UffiiJi.dv,"8!:g MOf!if:Ofing Q"Iill,y Assl!<8!!Oe PlIm (QM') ( 11!>!e: 2.25.07 Revision: 2 l'p..ge 4{) of 41 Dille .mlTime for Purging g. ;IS, 01 and &m,.ulitlg (if different) 'fC?J -{f1 Welll'twgirJg Equip Used: 'Junip O'lvbaii~/Wil{*~ (if otller IIlIln Benne!) 150/ £J' "II. f1" )./ S.mplingBvent ;J:;'kJ 10,1" ~v.<WeHi~~pt~jnSlipipiingEv~lIt ... ~ pH Btiffer 7.0 70 pH Biiffer4 0 , , ... ~c . ;-/{t?"" SpecillcConducronce 11 g uMHOS/cm ;~~~;'~~~~;::~:".,;; .. ,~%J:,,~& i . . ' " ,&S,I({J D~th to Water Before PuiWDg ..:;;------- ;: '.'-. temP!'1?,I~"",..c_·;,-.. -"-.L:..,:<::..J:~ ___ _ ~e4~xp~wp~(]~Ii), .• .,., •• ..,;JH,iu.?2(...· __ _ Twbidity {. ? . Turbidity, ____ ---'------ Time:: ____ Gal. PlJrgedl ___ _ 'J.'i e: GaI,Purged, ___ _ Conductonee,' __ :::,.., _____ <>::::--Conductance'_-.::"'-..,-__ "'----- pHl ____ ~~~~----pH, ___ ~~ __ ~ ____ _ Tempe re' ________ ~---Temp ~, ______ +-__ _ Redox otential (EIi), _______ _ Reilox Potential (Eh), ______ _ 2 !3 4356782224 Ifllelllational uranium 105-1 10 a Jll 12-23-2009 Mill -G:Olli..v:!wnt..: D;aciJ&"iJ1' l'emrit (fiu!.!1lllMk.· Mltllifnring Dare: H.l7.06 ReviD;aF.: 1 Qtrniitj Afis' ... i-cnce Plail (QJJ') I'llIle 4! of 4! --------Tmt idity_ .... _______ _ 'fm:iJitlity:.:.' __ -..:=======-__ VollID1fl of Water l'ilrgedWhen Field Parame!ern RID lVle~v)U'ed~ __ ..--_______ _ Pumping RAte Calooliliioil 7 ... J. . -",' Fimv Rme (Q). in gpm. S/60= -'---,-' ____ ~ T!IK!"ro ~vac!lllle IWo casing "o!urges (2V) T =2V1Q ...::.,.~===-___ _ If well ewwl!1ItCd to dryness. niunber of galiO)ii< \;vl\b~~t.~~29':...' __ ...:L=====-___ _ .' Nome of Certified Analytical Labnratoiyif Qih~l:tll)ftI1liteliw Laiisi::·· .. :.::.' .. ~·.;·.g/::· '===-.-::. .. :.... ~ -v, . t'rS"'< l -z."",~ .. ' If a preservative is' Used. SI'\l<;ify,'tYll.i~ ,." Qtiantiq; Of preservlitive: 3 /3 Mill -GiOtlluiwnter DJscimrge 1P'ermi~ (lrav-!1l1wD1e.i Moillroriug Dote: 2.25.07 !l.el,zsioll: 2 Qimlity AS61!W1ice Ii'll!ll (Q'M') J?age40 of4i A n AClH!Mllli"\l'U 'tI8lHlll'll'JE R4IJE§& lIillANJrlUlMl MIJILH.. . . ~I!DIlliA'lI'~,m~jWJBllElEl!'npl!R G~~WA'i! 'JR DegcnpifOO of SllllljlIlllg JBver;1: J tWm,k ' . '-'" . ~ .. , S!l!i)p.l~r , J / Location (well name) I fNIJ-1 () Np.~e ruad iiiiti~!s ~"",-r Date ami Time forli'urging ?>-.2->·{)'7 and Snmpiing (ifdifferent) g.J J .() 7 Well Purging EqtiiP:US~:' ~pumjJ 01' ~'~r w:~\ii' Aj!t(ife!hwhai!-BelWet)~k~i &I/J",ti Sllmpling Event :1",. +~ ~.,-.--Pre.;:.\JV,9l1 ~~.mp.led.!n Sampling Evenl fi/4 . pH Buffer 7.0 "7, () pH BufferA.O .... fiJ>.. . . .. . ' . .... : ••••• ' ": ••• .J •• :,..... , ....... .. . qli <./ .' ~. I /1S v <> Specific Conductance ( <'l uMHOS/cm Well·Pep-th ......... .J.~ " t·' .'. u'" .' . %;:2. &: . "" .... " ...... ".,"""., " •. ", ...... , ': " .. i . Deplh to Water Befol'eX"u\'gmg ~ Casing V~iilme (V) 4" Well: (.65311) Cnii(/uI;fiih~~;(Mg)," .'.."",,:.:..;' :,-;' ~",' i~~:c. ... ~ .. ,-. --,' ·:-"'"ft ~ '~ell WnterTe!lll). (nvg) ____ ~ . ' . .. ' ---"'1'1 '. , . ......,Jt · .,. -. '., . W"aU\pr &J!id .. ., I ' .; .• ~ohdqclrmce " LjjitS'tf ..... ' PH" ." ~.13 ' Temp~l!11u,:e J ~ ./8 Red~~}>ot¢n~i" :~~)",,·,...,Lft...::.'()..::.0=-· __ _ nrrbidity ' I;;: t Time: ____ GIlI. Purged ___ _ ondnclallce __ -";:----:;:>.L ___ _ pH ___ ~.L---\ ____ _ Tempemoo?' ____ ,---"; ____ _ RerlOll Potential (Eb) ______ _ .. '. . RedOJe P?rential (Blt)_--...::-"-___ _ Turbidity __________ _ rim~e.:::· =::::::-GnI .. Purged~ __ _ Condilclauce'--__ ""',....:=--____ _ pH ___ ~L--~------ Tem~e!~u~--------~~------- RedOJe Potential (EIt} ________ _ •. ! C':-' .... ',' ,! ., . " . , ( I:.([ill -lGm~.m1l;;JlItet lfJisc!u;rge Pel'mil Grouru!~!!!Wr Monitoring D-ate: H.17.Ua Kevlz!cm.: ! Qlmlity A!JS3f8ficel'iflll (Qfty) rl!lf;i.dity ______ ~==_____ 'Furoidi1y ____ ~ ____ , ___ _ ~-Volm118 (If Water l>urged WlJeillf1ielrl Pamme!em Dre l\IleasUled~ _________ _ Pumping Rate Calcu!ntiotl Flow Rru:e (Q). ill gpm, S/6O= = '------- Time to evncuate two CMJBg volumes (2V) T = 2V1Q-_---'...------~ ______ _ Ni!1llber of casing volutD.es eVllClU!ted (if other than twO)'-_"'=:~:'" _,---______ _ If well evacuated to dtyness. nnrober of gaUo1!S evncuate.d __ -,~==-____ -;-__ _ Nrunc of Certified Analytical Laboratory if Ofuei-TlUUl Energy Lalis __ ~_' _____ _ '. P~C8erv"lJlv", Addeall (cl~cl,;) , .. ' If a preservative is'used, SP\lCify Typ~ aud Quantity of~elv.tive: .... :'.~ ',' September Sampling Event Mill -CJ:;mmrlweter Ofscltflrll" Il'o'mii G""I!mJvlIl["'-Mmiirori"g Q~lllity AJJ",-mm:e Plall (QAJ?) i /)\'lFll'M;lHl!MlJENll' n 'W/HlJI'JI'JE l1!IlE§Al 1!JllR&I\llIlUlMi MIIlLIL Date: 2.25.07 Revision: 2 lli'1IIEiL1!J) 1ID&1[·tI\ IYJ~noo;lJHl1EiE'll' mllR GilR~1[}M!Jl Wi! A 1l'lEllR Deuc-i.lli1<Jfl (If Saill!llillg Eveuil: 3!" Gl",,;'d~; A) ,lccJe /en Lo'-'c."'J ..... L,,~ ____ _ 'r,.~Pil)p.i~r; , . "'. '. . LUCBtiOll (well DruOO) 'nN,v -I Niirlili iiitd initioJs :r<'ow 11.11:&" ~ ~P" PO/MCr ~ . Date amil Time for !1'Ilrgillg. '1-~ I ~ ()!\ and Sm:OIl'ling (if different) 1-z Z . 6,' . ~ ....... ~. ,:{! . ,~.' '. . 't!" "'-1.'~\;·~.}f.·'~'1'1~: WelD Purging ![jlllui/> 1USed:' 1.j:iwiip or _bailer . w.~U ~limp (if ollieI' fll nn Bennet) (l.r""'~.ros S'!iIpl~lg Event p".Au I~ 1\' ;l,J'/c.hlo';J,c ~~i,!Vlj~,lI':~~pte,~;!!l ,~~rli.!,g'~Y"!i!;r")M ';· I !l. pH Buffer 7.0 7,0 Specific Condu~tllnce . q j Q Dep!!! to Wa~r JMol'e JP'ufgin,,,,g_,-,-,,-.• "-.. ~.~_C'.SiJ~i"VOlliJiiile ~~~i~E~~~~: Tem!",~~~W",~ ; , I/LXJ, I · '. , &~o,~P:~i~9~li{(il~i}, 4! b j Turbidi~ ,;2. I COl1ductauce~ __ ~ __ '7"""-__ p~------~~-------- TemperntQ~I~-----~--------- OK i?otenlia! {Eb) _______ _ '::-:. ; ',J't • f1}~~iitj~~~~~'\;,;' ..:('\~n; iPr " .,:' .>~'.'.' ;.t/~ } .... t ',' , Redox ~iltial (Eh)-,---____ -- Conductauce, ____ /"L.. _____ _ pH ___ ~~ ______ _ Tempe ~e~ __________ _ P.ellOll Potential (Ell), ______ _ C"; .. " i ' .. ' ( Itf.[ill-Ot'allil1VJD.£er lDiscbEge P.6m:llt Gml!lli!wlllBT rliollitarmg Jrl~l.: lLI7.U.s Revieiofl: I ([<wlity P..sfllifDP.CC Fi@ (QJIt") Fil>w Rn/e (Q), in gpm. S/6O", =,------'6(,>----- Time',o evacuate two casing volumes (2V) T=2V/Q= /.2., .... ,,;' Nwnber of Cn9lllg volum&: eVl::cwtled (iii o'fuel' 1i11l11 two)~'~. =======:::...... __ _ Iff \"",11 eVllCl1n~ to d.tyness. number of galiOlis e\r"ciiiit~dL'_--,======-____ _ -,':' ; ~ ' .... ::, tr'T~~ /'112 y If a preservative is' used. Speci.fy,Typ~,1Wd Quantity of pfesetilative: IVIilS -GFuu~wP.tei· Disdmrge Fermi! Gmv.mlw.ter Maiiiwfmg Qwl..i.y AIl8t11lll1ca i'11l11 (QAP) !lov.le: 2.25.07 P.evisiol!: 2 ii'.ge (<0 of 41 A'll"iI'AICJll!I\illill"\J'li' n IY)'l!!ill'iI'lE lM!lE§A lUllUlIl\llIlUlMi MIIILIL lFlII?U,1lD lIDA'lI'AI 'W({))~HmlHflElE'J!' Jii'({))J!t GJ!t1!l>1IJNII]) \i'U AI'li'lElR j)e8crrp!ioli of Sarnplilig Ilvellt: yJ-. l)\b(j.d~ C' A) :if ,,ie /cb loc;d L ., Spr~p.ler . Lucation (well liI!!roo) 'nul\! -d Nmhii Mil fuitials'--==-llJl-"-"''''\;--'--"''irQ!!!..A P.IMer Dllte Mel Time for Purging q -d,l -Oq !lIl1l Sll11l1J1ing (if different)-+-lT.J-...l.L.lo--__ Sampling Event Qao'\<r I~ "il,J'/ chloo'J, pH Buffer 7.0 /.0 pH Buffer.4.0 . . ... , "1.·0. . ,,,';,' ',". '.' :":-: ... ;. '. . ." Specific Conducl1lnce q qg uMHOS/cm Wl.'IJ,D~iith , ... S{,. ...., '" ," ., ': :~':": .. ''':.,\ ·t,q .. • .. ·'.'·.1 ., " \ ~ .'," .' .. WeI! WaleI' Temp. (Ilvg),_...:.·.--/ __ ~ W~jlli'I'C~nd. :~'f,~"l" : . ~" ••• ,~ .. ~>" .• ~~.;:,.;~ : .... , :::i .'" '~'''~ : :·~.:t ".~ :.-' ' .. ' 7-~ 0/ pH~ __ ~~~ __________ __ . ~on~qt¥f~·"": . .;.,~ .~:""::'-;'.;--~..;"«---. "" .. -'-~~' "'.,:. ~' '::;'.f/,?:.~ .. Tem~erntuIe"::",..-,-',;(S-:o,..,.:·.-'[(~7------Tempemtru~~~ ________ _ Redox Powntiat :(i3h) : Lf io ~bidity '2L k . Redox 11 ntial (Eb) _______ _ Y idity __________ _ TilD3:, ____ G.I. PurgedC-. __ ---"...._ 'j.'ime: ____ Ga\..Purged,_-".-L __ COlldudal1ce ______ ..".~ __ COndI!C!BllCe' ____ ~L.------ pi .... " -----7""'-------pH, _____ ~~------_------ , 0)[ Potential (Eh) T~ re : .~dOK Po,entiru (Eh), _______ _ (':" '.,' l ',: "-. , . .. -' ( ( UfiH -(jWi1fi{~Wllter IDischE!rge Permit Grom1d~lllt~ MOniWliIlg note: n 17.(15 Revi~ic,,: ! Qilplity AMarnfiCll Pillll (QJJ» Tl.!rlJiilily.-:.=====-__ _ 'ifIlrilidily_~==:::::===~ __ _ PumJJWg P-ate Calculntion Flow Rnle (QI), in gpm. S/6!) = =, __ -.\;;,>--__ _ Time'to evacuate two cusing volumes (2V) T=2V/Q-1"{,'VI"v Number of casing volrunes evacru>tecl (if otlter thac two)'-___________ _ If well eyacWlled 10 dt)ll1ess, number of gallons evllcuated, ____________ _ Nume of Certified Allruyticru Laborntory it' Other'Tliim Ene'rgy Labs; __ .J.A\L'ILJ/A'L-___ _ If n prese<vative is'used, Specify Type and Quantity of Preservative: MiD -G,"'~luJw"1"r Iiliscl,.i·g" Petmi. I[)wl!lKl",aler l\1,mitor'"g lD'&te: 2.25.07 l~evJsio,,: 2 Qu1ll1lJ AuSlli'llfice f1vJl (QAP) A'1il!'AC1HlIVillEN'Ji' n WtllHilI'l!'lE B§A 1IJllRJillITllU MKILlL JFHIJij[,]]}) ]]})A'li'A 'W1DllU§JHIIEIl1'Jr JIi'ilJllft GlftilJllLJNJl)l WA'li'lElR DeGc,'ip1i~i!i of SlLiilplilig lEvenl: 3[J.. Gibed;; A) .\cc.\-e ,Ie", !cc.~!t~ __ Wage «J of ~ I ." ~pJijP.i~r: " ' " . :;,' Locatiun (well miJiui) ·n.lA.! -.3 . Name iilicl iliitials Y'oov H.i/;J." • fuoA. pal",.".. . " ~ Dale anm Time for J!'urgi!1g 1 ;;(./. 01 DlIII sm:"pli!!g (if differrent),_1..>:'-,' l~1;-' .:=.b-\'\,--__ _ " ' ,1,-_-,', . '. ~. ,.,,~ t. .',-.. ~"''i'!'' ! Well PI!!gi.~g f!'l.iJii)u~eti: 'j":"j:iu~p or _bailer W~it~imj1 (if oilier tltllit Bennet) Gr",",I.fos SamP.!ilig)8vent !,).,aA.cI~ Nih.Jclchl,,;J, p~,~! .w.~!!;~~.rf.Iit~:d;!fj ,~."f~pli.l)gE)i¢llt;rl'l&1 ,;,,) « . . " pH Buffer '1,0 7. 0 '"'B' .'1<;" 4 0" JJ 0 PR' w.~r, ; :,,'.' .. ,.,:'. :a.-......... ,,,.,. .. ,, ... ' . '. ·-:"'~~(;"~·~'::'i·.'·~'-~~;·'···,;:'~" "., r ' • '" "i'-..... ". "" ' SpecilicCCilduct;lnce .9'1& uMHOS/C !\l .' _\>L'~ii;Oip.lh .. "h.(,;' eft. .. ,,,,..,,,,,,,,,, ... ;,., , .' '.'. ',.': '.' :~\! ... ~,···, .... ~·.;1:·~:~·.~·t~·.t:·,···,.·· .. ! ··.-·L"'~ .~.:' ." Depth ID Water Bilfol-e l1'u.gil!g--L,,,",~2=-• ./-1 ~iG'--C."iJ!Ig-,\roi~iirte .' CoiiililHiWce • c":Z 113. ";.. .. 'o p~:':' . ·:t. 1t'" t ';: ' Tem~~'J\I~,e,', .. Y:! ',r 1·, ~~~~~~~\\t.\h(~~!t}: ;:. fiJI . " .' ... ~ .. ,.,;. ++--1---- Turbidity:--_-'3"'----'t..;.., ""2'--__ '., J#dOJ' ~entii.1 (Eh)--:-____ -- 1;i=:...". .. ~ .. _,.......,_Gal. Pum~~ __ -::;_ ti!'ie! ____ GvJ .. l'utgedc--::;,.'-__ Coud~ctal1ce _______ "7"'-__ Conduclance ______ '?"""'-_____ _ pH, ________ ~~---------pH~ ____ ~~------------ Teillperal~~i '.:... ___ -:-______ _ Tempe ' i'c, _________ _ )} _OJ{ Potential (Eb) ______ _ ReilGl' Pollmtial (Eb), _______ _ .. : '.' ,: .. ' . - .i. ~:;;. '.' ( ( l~n -(j'm~iillwHt~· IiJiSf;Kt~'ge Permit Gn:n.m!RIl/12Lff MaIDtO-.l'mg Dme: HJ'l.tJ6 Revisifm: l QwlilJI ilJlS.!mllce PlOD (QflP) Tux'oitlityr_:======:"-' __ _ 'furlliliity_-.:.=======-__ _ Pumlliil~ Rate Ca!cu!plio!l Flow R!!le (QJ), in gplll. 8/61)= ='---_G.>----- Time .to eVllcuute .wo cllSing volullles (2V) T=2V1Q= I i ,,,:(,., . Nmnbew of casing voluines evlicmited (it dtJiedil&lil two)_·~.,-· ___ -,---_______ _ If well evacua~ to dryness, !lumber of g~lioriS e;,ii.cuil't@",,~, ___________ _ If a preservative is' used, SI'\:Cify.TyI'~ 'Wd . Quantity Of preserviitive: Mill -a,.",mdiwalel" IDi,c!wrge Ji'emlil Crou.mivmteJ-n~oillrof5!1g QUfllilY ASSLOfIlfiGe P!VJ! (Q.llP) Dai'C: 2.25.07 JRelf~sion: 2 ii'age40 of4i .m&,ClBll~'lI' n 'iIlI1Hl1!'l!'IE lWIE§A IUWhlIllIlIJMi l¥IlliL1L IFHIElLIlD IlDA'll'A 'W(1J)li"Jf(§Jil!lE1lii'll' JF(JIm a;:IIW!llJNJi]J 'W &. 'lI'g DBilcr.plwfi of Sa..~li~g Bven!: 3]"'" Q,wd;;-A 1.\ c cJ.e. ,LLh.[o'-'c'cuJ"pc,... ____ _ tnention (weli iliimi:) 'TIN iJ -L/ Date amiTirne for Jl>urging '121· 0 7 Sampling Event Qlw\<r.I~ "it'.l,/Chlo';J, pKHluffer 7.1(} '7 0 . " .. ~ii)!jP.i~li <, , '.' . 'i. . = . Name ruid milials :f.nnv H. II :L~ ~ ~ a~ P.I",er and Sfillipllng (if different} ___ ---- ~,v,:,W,~,I!~~~!il~,jl!. ~a1J!~Ii,ng.Jj)!~)lt:r,,) iJ ~.' Y R i>H~iiff,<r,.4.iL ,;" ,':', !;j.eL ......... ".".' .. • ,-:1 :';1 .,.~ .. ':. !,:,~,~ .:.,1.,), < -. ",' " '." •• ;:.-.:" ". _, •• . , ., '"1 Specific Cond~ctance "I'll{ uMHO.s!.~W ,.W~}.!i~f.g~{·~~:>l¥·~.~./;,:·::~ ':d;,':.'.'· "-', Depill to Water BefOl.., ~gia.:;.~ -,3::.:~::..:.--=~.::c'5_--::--. Cas:,ilig·"oili(iiie ;'", Redox I)' lfentiial(Eh),~ .. ______ _ Time:...,.., .. -..,,--Gol. Pum«d. ___ --:;~ tj~e:~---Ga! .. Pllrgedl..-_;7~- Condllctallce' _____ --"'7L.. __ _ Conduclance' ____ "'7~ _____ _ p,~------~~--------pH ____ -7~ ______ _ Temp~mu~ _________________ _ Tempe . ute. ________________ _ ). OJ( Potential (EbL. _____ _ '.' II I~ /6 -l~£'#o 3t.8>- 't'l,¥s : l' .-: . , ., >.' ( lw.m -Qm~ii~wRi:er liJi51::bl.:?ge Permit 6!Ol:lli.I1~!tloc..,. Mmllimmg /!la[e: H.!7.US Revl.ion: I QiWlitjl AC&l"'<ll!c.Pl"~ (QM') Turbj~nl:)l:~======-__ _ l'umiclily_-========-__ _ PwtI[ling !Me Calcwplioll FIGlfl Rate (Q). in gpm. S/6fJ = '---_--l6<>--__ _ Tim~'~ ~vncuute ""'2 c!lsijJg VQ!lillles (2V) T=2V/Q=. 1'1 /?1uV Number of cusiHg voluirie's evacuated (if othei"tltali iwo)_'_,'--_.-.:---:::::. _______ _ If well evacuatCd to diyness. [lnmber of galjon~evacuiit~:iI!:::·,,"_, __ ...:::==== _____ _ Name of Ce,lified Analytical L.b9l"11tOry if Oiil~i:Tllii~;Eil:ei:gy Laiis'---_...J·A,,·}.LI"'A'---__ -- If n preservative is' used, SIiecify,Typ~!Wd Quantity «If P~erviiti,;e: Mill -iliomlllwlIl,,. j)F,scl1orge !'em;;! GroUi1oiV'Jtlt~ Mooitoriflg Quniily ASSlli'Bi1Ge flu,., (QAP) Date: 2.25.07 Revision: 2 li'agalJOof41 A'J!'1l'AlClllliWfElmI' n 'WlHIIl'll'JE J.WJll§f.I 1IJllRARTlfl!iThil1MIlllLlL WmLI!D W&'ll'f.I '(j)IP'JIffilBIlElE'll'm1l1 GLlRmUNIDi W&1rJE~ DellCiipiiu!I of Sarop1i1ig 13vei'i!: '3f Q\~t~ C' A I :-tccJc:. / en loc:d e ", $.~pl~r, , ...:; ". ~ Locatioil (weli nalne) X\NA.i .5 Name iiild iilitiiils J?oo,," H. /I.k,. • ~ a~ P.IMer , ~ Dale amJ Time forl?ul'gillg '12 10 7 anrlSarlil'llng(ifdiffe'eilt) C; 12'· or Well Purging E~ui~ 'iUi&i: '){puWipor "'::'billi~tW~~\~~~p (if oilier IItnil Bermet) lYe "'nJ.ro ~ Snmrtling lEve!!t Q,w~d~ '" ii"Jr/Gh1o+ 1!i'~Y,1'~%9,1J'~'.\l\'!pt~A!1.~<l1JIplilJ~'''YC.llt;:rIA).''1 c' 5 1\., .,' pH Btiffer 7.0 7 . 0 p~;!t~f.WM:o,/)::;;-:.,-~.·O~: .. ;~: ... ,,,.,, .. , specific Cah(luct;mce 9 q [S DeptJI !II Water Before lPU,ging 70. b 1 Q)ita~iiilii.ii~if@!~"f;"l!:)i .7" ";::;fi. . ,.; ..... . . ,., w.ell Wat~rTel!ll), ~.' <V!l!'_~_~----" . :' ,~~ '.' ,:', .':.' Temr~'1l:~"\'", :.)1:: ,tiJf Retlo~r~i~l!~liroi~)'; , 35'8' ~, .. ~.,. , ..... , .':1,.;;.: •..•. Thrbidity ___ 'L!:C"":LZ>L:---__ /;WdaJ( ~tential (Bh)...,-_____ _ Time~: ~_,--Gnl. Pu~~~ __ ~,....-'j'i!lie:_---GIlI..Pllrged,--;7""-- Couducmnoo"-____ -._r:::....... __ Conooctauce ____ --O>,L. _____ _ pH ____ --::~-----pH ____ -7~ ______ _ Temp8nnUf~-----__ ----------. Tempe re"-_________ _ _ or. Potenlinl (ElI) _______ _ ~eilox Potential (Ell) ( iif1ill-CGfmU1~>lillttgr Dis!::~wrge f.fffi'mit GroarulWDlJa;'lVio11il0I'ing D~t,,: n17JNi ,I'.evision: ! Qw,iiy A8Sili"RCe .!linn {QM'} 1."go4,! of4x Tm,bid1ily~====== ___ _ 'i!'ur~iditjl'_--======= __ _ Pilmllmg P.ate Calculatioll Flow Jilru:e {Q}. Rli gjlill, Sf@= -, __ -"~~ __ _ 'fim,<'\O evacuate two c~sillg volUl1le8 (2V) T=2V/Q= , 17 MtAl Ni!lIlbSi' of casiug voluiiies eviicl!!i!e<1 (if lilliei U,an tivo}._' ,;..' ___ -;-______ _ If weI! evnclla~ to dryness. ,mmber nf galioilii evaCUiili;ilc::"''-' __________ _ ; .,. lJ'Id ," i: ' ... : ",' Idr IPd, , ' If a preservative is'iliied, Sp~ify,TyI'!(,~ , Quantity OfpteSeriintive: MiII-G'rmmiIVOi<lf lDischm-ge JP'mmil GmumJvJlllei J\I!o;,iWTir.g QllIllity AJ;strrll,lOO Pl1m (QM') A'lf,['AC18ltVmm II Wlflill'lI'lE Mffi:.§A 1I111UiW1IlUTh1I llhliIlLlL JP'age 4Ii oHI iii'1IIEJLllII Ji))Al11'A ,(iJJl!RJ(ffi!HflElID')f mm G~([JI1lmJ]j)) 'W.& 'Ji'lElJt Description of Smji!iiig Even!: "3! Q,.,.iff;;'; ).\c ,.leo ,Ie to (oe, de..., "'i,;,§iii.lR1~!'\":"'7 "!':' ", i ",' I,' LOClltio.,(weli iuiiiW) -aNA.! -(,l\Y~meiiMWtlars :I2nnv Holl:e!... t ~o~ P.I",cr Date alj!D Time for ll'mgillg 1 J.2 () j /;lm) Sarlipling (if different). ,L " Welll!'~rging E\'.ili~ !idid'it~~iil(jii';W 'bid~~!VWj1~, (if oilIer iltoUi Bennet) &;",~jfo~ •. . .. -.•.. '-J ., .. ,. ~ • :'1 " .,' ' ... SlilllplillgEvent (,dw\~r,l~ !" ;hl, /c.~lo';~c , "r¥$v,~~~!!),~~w~t~il~~~~,'ilJi!im~,,~Y«Ji.t;:r"~N~ , ;",,(., pH Biiffer 7,0 7 ,0 .. ,' ..... " .•....... -..... .. ,'. COriil~cbillCe. __ ~~ __ 7L.=-__ Conduclllilcee-___ ""7L-_____ _ p'.~------~~---------P'~----~~--------------- Teoopemnw~------_----, TeinM 'ec..' -: -' ---c------- ZOtWliai'(B!i),..,.,, ____ ---: ____ _ " " ( ,-; '--" ( rf.lnH -Gw:>w]w"t6lliJiGchorge P€ffi1it firoilliilWllillr llIionilul'mg QlIvlilY JI.us"""llCC Flon (QAP) ( jIJ,,[e: H.!7.U6 Rev;Gioa: I 'fl~idily~======-__ _ l'lIl!I1pin~ liMe Calculntion .\ ,', Flow Rllie (Q), iii gpm. S/oo= = " 'lI'imeto eVRcuate lWI} cllSing volwnes (lV) T='zvii:f-:',' " J:ZM'~' . NW!lber of casing voluililsevhCwlted (If iiafrii'illaii tWd),.ei_' :'" -'--_'-'-_______ _ J'f well evac~a~ to dryneG", number of g.~mi~ llV'dcti'ihl.i~I:ijJ;'_, _______ --'--' __ NUlDe of Certified Analyticnl Laboratory if QJI¢f'.i1tlili,'Hl?4-~Y Labs,':,,' '..:'~,-'" ~::" .:J.··,Il.,Il.J/A!O'.......:........;.,...........:-.:. . I ..•.•. .-' . : : '~'. , If a preservative i~' ;mea 8Pl'c.ify, 'fYP~""'Il~ , . QtianlitY IlrP!'&etvnlivei fir AC /3;=3 '" ,<, Mill -Ur81100W!lEo .. 1!Jl;'C!Wi·ge Permit Groilll,;warer M""i~ariog Dale: 2.25.07 l~evfu;ion: 2 Quori'iy AsSt!lIlllCe Flllli (QAP) Page 49 of 41 A'1l'1rACiHl..IM!iEJ.~'Jl' ~ W>llHill1!'lE R6!JiI'§A l!JM.Nl!IIJR6! J.W1IILIL JFI!lE1LHD HDA'll'A WII'I1])JP>.JK§JHlJEE'll'llI'l1])m GIffi.I1])IlJNTJ]) WA'JI'JE!W. DeBcrip'i~IHJf S!ltil!plilig l3venl: ?}'J-. QII.q.d~ C' A} ;1cc'\-e. / en (ac,A e . ,,' ~~Ii!I!.I~r, ' .... '. ::: ~ Date nn~ Time for Purgiug '1-~ I 0 '1 SnmplinglEvenl Q'd<'I<c I~ ",;h<\c/c~lo~~( pH Buffer 7.0 7. 0 Specific Conductance q'l [) Depth to Water Befote ll'u(ging . ,', . ,. ~onilili:lfjil~e ' . ·13·19: .•• , . ';. ". ~., ... ':~. ': '. . ',' .., ... t ~;·; " .. pH 737 tem~~l,1lJI!'''\; (~ )17., ' ~~~l{~ci.~~tif~fiJ':C:·;.:cif?t.:JS.3c,;;' L-! __ _ rurbidity 173 . Namiiriiidi.iilitluii; :reo"", HolI:k" ~ ~ IIml Sl1iVlpl,ng (if diffe.-ent) ___ ---- ., RedOJ( ~entinl(Eh),-,-_____ _ ~ime: . ...,...,--,..,,-_ Gal. Purge<iL-__ -,,_ Ti!1le: ____ G~l.Putged,_~"'-_ '. ! . COllduclance, ____ --?'L-.-_ Cond!!ctnnce, ____ -;;-L. _____ _ pH _______ ~/----------pH, ______ -?~ ____________ __ Temp3ra!llre~ _________ _ Tempe'· ur;). ____________ _ ) ox 1?otential (Eh), ____ _ ~ei!(lll Pote!l!iai (Eh), ________ _ " , .. ,' ; , (.',~"J.~. -.. /. ":. <':j:.", .,. «; .. " i .... l' ., ., , ........ .•. ( l\@.i -G:flnmriwflie? Discllifli"ge Permit Grouudwc.~· Momtofwg Qmilit)l ft..llsumrrce Plan (QiJ» 'Fl.!1bill.ity---======-__ _ Pioooillg P..ale Calculrrti01I fllow Rate (Q). in gpm. S/(i1) = =,---1;;,,>----- ( Pege ~·I of 4·1 T~fbidily~-===::::===_ __ _ 'jfime'~o evacuate ~wo cusmg volumes (2'0 T=2V/Q-~~ ,S-..-vi~., Number of casing volumes evilcmiled {if 6thetUtun tWo},--' :...' __ -'-'--"'~= _____ _ -------H well evuc1l1lt~ to dryness, number of g.~o~ eliiiCuiil!~jl,,:,,,2'." ___________ _ . ' .:' ,.: ...... ,.:. ,l'~:·. '. , Name ofCerlified Analytical Laboratory if Olllti;'Tli!ili'Eifergy Labs._' _":...' '_' ...:"",'I'.1./'£o'A,-_'-.-__ .. (L~ / H a preservative iltitsed; SIl~ify,Typ~}Wd , Quaotity clfpteierViitive: 1356782221 Internallollal ur cHlium 1224.42 pill 12-23-2009 ( !11m -GrrOOI!D1WflW'-DiOClw"ll" li'emJil (lrOO!JliMlf:er RlioiliWrW>': D~!e: 2.25.G7 li!evisioll: 2 Q.1lliIy i\ssn"!IIGe l'Irut (QIlP) Page 411 of 41 "r_,: ,-.',:} /-.... , .. ·.':.';"i',~i:i~~&.hf.: . j Well Purging EqUip U8ed: 'l-ifiliiip or _bailer W~Il;I!tnl1p (if oIher than Bennet) G-r<AnJ-tos Samp);~gEvent !.dw\<rl~ ·+0'/Gh!o';J" Pre~HY~!!"~\WP,t~j!JS,~rop!ilJ& ~Y~I)~T"m,; ff R., ,,- pH Bilffet 7.0 70 , !,~:~.jjf,If&~:9,;;;~:~r;:' -.~-()·d,:·,,"':;i _. Specific Condu~l<Ut~e . q y, uMHOS(~!l1 i W.~ji:ij~~iii:;;,,,,_\ !':t~i-:;;;_h"d-',"' ". " . ", -, ... \i:,,-t~,!(., .• ;.t:.f::"~.;;r1,'~t.; .•. ,.;) :r,", ,;.,. .. ' pH~;~ __ -L~L-__ ~ ____ __ Tem~7~,., J~;~];.,,: Re<lo~I'il~tliil'~i; ;i d,x ,,' ~i~::"";'" . C '3-'; " ' ~ox ~i1ti.l(Eb)~ ________ _ COnducffince, ________ ~~---------- pA-______ ~~----~-pH; ______ ~~--------__ --- Temperaturr-____ --, _________ __ Te~~~e~,".~-------------------- ox Potential (BIi) ______ _ -ilx Potential {Bb),_· ________ _ 2 /15 ~' --: • < ., .' '135678222'1 Intel national UI allium 1225 37p l1l 12-23-2009 I\llin -GrOIl:il.1VJDter Dj~Jwge l'emlit tlro!!!l1wzci Mooilming Qt.wIi!Y ABs<ill1lllCe Pla. (QAP) Dote: H.l7.(}5 Revision: I ( Peg'''! of41 Trul>iL!ily-======~ __ 1\Jrbidii.y::.:.-' _======-_~_ VI}IW!lf)ofWlli:erPurged~iiCij4ltl:y'1fBd I@ Fging!We Calcule.lioil Flow RlJte «D. in gpm. 5;60" =,---~_'_~~", '>""" Number of C!iliug viil_'eVlilii1li'lM(ifi~f:~liii(iW(i}C:.; '-""_'"''''':0.." "'--'-;-_--'--~-'--_'--~ If well evaC\lA~ to wynes8. nillnber,ofgaii,o~ llVa);~'jl\")",i~,,, . .'~" "_--'-___ '--_---'-_-'-_ . ':. ' .. Nome of certified .Analytjclll Lab~lyl,fQlii~tJiMiij~ L~iJ~' 'N "AI LA .. '; . • , , •• _': 0 .', • , r . .:, .. ,o·s . ; ~' .. 3 /15 4356782221\ Inlematlonal UI allium 122628pm 12·23-2009 ( Mil! -(J;;oorn!,..arer Dlscha,!?" l"ao"i! al"m.mdwlller M""itorill6 QucliIy Assm'Il,''''' fIlm (QAP) '&"'l('1l'1.\1C11!l!MIIEN1l' ~ WYlHllI1!'1E l\4!E§A ~I.IRllfl[J1W MiilLI', fJUEiLJlli DA'Ji'A ,01P'JrmJllllEJlIT ro~ GI1WiUIIlKD 'W A1!'JEIlt DeflCi"iplion of SE.'nfiling Bve!it: ?J" Q\~;;-A) ,'tcc.l-c /(\:\(oc:J .. Hl,S,~pj~r ... '-' ,,;.:. ~ .' Ndiilidiruti~(s :Go"", HuU;J... ~ . ( Localioli (weli~j -oJ'" -r Date ~.n!l Time for Purging 1 .22· 0 1 and S/iinpling (if different}' ___ -__ _ : ;.< .:.:.~ -~; .'.~ .. '. .' ·::,,:·!jk~~tXi\.Ji: Well Purging 13qilip IUsed:' uuiiip 01 _brule!" . W.e,I~~p (if oilier !han pe!lJlet) Gr""J-\'os Sa1il!1Hng Bvent Q. ... A<C I~ .);lrre\clc~I ,,;J, .. ~.i(j':!'l[~U)~\\Wnl~,~,~>QI)1p.liIJgEv~i1t;:p'W"' :1 1\ pH BiI/fec 7.0 7-0 !"!!~'[.J,.1t;:;':~t::·}·.o~::~;~~",,,,:·,-.. uMHOS/cm .i.'Wel1)~"-jjtJt;:.W'''·.,.: , ..• tA-"".n"·"';" <." .• , . '-,"". ', .. ~:'~;~~~ .. ~f.i·:1:_'f~":':;';:;\";':"'" l .... :·0"" '.,' ." Specific Condl!c,tanoo } ~ f$ ' .. ' .: ~ox ~-.reotii,. (Eb)c....--___ --.,-__ Time:'..".,-,.,..,--.,,-_Gal: Purg~.-:-__ --"....--Time:_---Gill. Piirged_-"..c<-_ \.:;,;'.; Conductance, ______ 7"''''-__ Conductanoo. ____ ~~----- pHl ____ ""7~ ___ _ pH,_~~~~--------- Te~v---------Te~~-,,~._------------------ ox Potential (Eli). ______ _ " oXPotelitiill {Eh) . " ", . . -',,, '1 /15 (":--.... l' '.: . -'-;' 4356782224 International uramum 12 27 20 p JIl 12-23-2009 ( U!ill-IGra!mdwr.tell1JisrllErg6 Permif GilllliiliWllIti Mll3ilnrmg Qu.cli'y AIis,;rano:e l'l8n (QAP) IMre: ILl'i.66 Navi.io,,: I ~.nIli!li!y-======--~_ '. ;':'., Pumping Rlite CalculHlion ~e41 of4! FioW/ R»J:e (Q), iio p . Timet<! evacWite Iwo C1l8rng VQIUIIleS (2Y) S/fJJ= "''--_---'--',;;>-~--".."-,..:. ...... T=2Wlj":!" :-::; M :;,j ' , ", If well eV/icuakdlo dryness, number of (laU,o,l1 il~(f~f~)i!',)"'iJ.,.: • ....ll. __ ;-~ __ -'-'-''--_ .' ,::' .. Nome of Certified Allalyt!cal Laborl!!oly :lfQ~i~!t1;llliii'~y taii~",·.~c::.i{:c.~l·""j·'·AoMI.LI.",A_-'-'-o_··-'· ~ •.. . .., ... , .... '. -. ,.' .". 5115 " 435678222-1 Intel national uranium 122810p lll 12·23·2009 c· ( Mill -(];room<Jw,Ie;' Disc!l~rge Permit Gmy.!ldWll!el MOiiifnring Dote: 2.25.37 mevisioR: 2 Q>muiy Amwi"= i'lV.!l (QAP) AnACIH!MlENT] 'WllIDl'iriE MiE§i! ~ MlUi.L lJo'/IEiLlDlliMTA W(()llP'J[§JH!l!ill']['·!FOR GilWIUl1Ilf» WA'ii'Eil: Denc~io"ll of S!!iuP!ilPg Eve.it: ?}"J-. Q,....:ctt c' j,) :bJe./cb (oc,it, . ",.:;,iijj1p.li;r" . ", . . . . N'a dilti iilitilils --r;;""", H. 11 :,6 ~ ~ Of' t and SWlipl!llg (if different)c.. __ -___ _ Locl!lion (wdhlfuoo) -nJN -16 Dare I)I1cJ Time fQr Purging q. 22 . () J {F .:, .• ;.;, , ... ; .' . ~:' If tf"';:':'<".' ~~.,.: ," Welll'Wging Equip l:1~eit 'L ptliiip or '-:'liiiiier W.~jlI!i~ (if o!lier IJm~ DeMet) Gr "",Jto S SarnplingEve/it 6.A,~.f<rl~ ",;+,,,lr/c~lo';~( pH IMler 7.0 7. 0 &it~C4rtHt:·· ,:{ i/Qh (P '" , PH;"'~} ··~··:;(':2 6 ~:>· Temi'Fmiure , ,. / 9,,30, ~e4;~;:~~~i~\j'iz{,·t Tmbidity I £(. i COnductnilce. _____ --,,.""'-__ _ p .. ~--------~--------- Terape[ll,,'9"'-________ _ OK Polmtial (Eh), ______ _ P>.~~ic~*'11~~W!tt~~;jit~~"IlIi!lWIl~~lit;i:,,'.&) ~ /0 ((, . ': lWdox ~'htial (Eh),~ .. _____ _ Conductancec-__ ---:;7"''---____ _ pH~ __ ~~ _______ _ Tern·· ~Iiite.~--------_ . 0)( Potential (Eh),_. ______ _ ." 6/15 C-:-· .... :,:,) 435678222.01 Inler natronal ur allium MiU -iGffiU'.1dW.1tOi liJlsciw,ge P.m>it GroUl,dwnrei MDiWM'ing Quw.>y 1'..,,"'8= PIOll (QM') 11&\<): H.17.% Revinio,,: ! rmbidit)(.-:=====_~_ 'VoluIDelbfWmr P!!.rged ~.49!ilIf;:~~iI@l!! ; " , 12:29:04 p.Ol 1i Wen ""acua!~ to dryness, niunber.()f.gaJ.i~ll\h!i!~~~lli.]i;"ii'::'··:"""L. ~''-''_'"'---'''---,_~''o. .. ,-,.~_ . . i· . Nome of certified AillIlyticlll L!lboralolyjf.oih';I\~_y.tliiJiI ; iNc/c,,) IA.·· , . . -... '.: .: ... -.' .... , . --;>.; ... -~'-;".-.. ;. -. . -. 12-23-2009 (imservative iB'a~tili; . ~:tJfrit.~KtHle:·· -~.. , 7 !15 ) Min -G;OtindW8~~1 Dischflrge i?errai{ Gwunrlwute, M(luitoring J!Me: Z.ZS.1Y7 Nevi,ioll::>: Qv.tility 1\.1)807'"'00 It/on (QJW) J?age 4lJ of 4, A'll'FAlCJlllIMlIEN1I' n WIIlHi1TIl'1E J.¥liE§A li./lUNlfIIJlMi J.¥!iilLli, iFlllEiLUD lIJJ& 'jf A WlOllOOK§1HI1E1E1I' Jii'IOlJR GIlRIOlIUNID> 'W &'jfg ](le1lcrip1ioll of Samplilig Bvent: 2J'Jc Gll!.O.d~; A) .\cc.J.e, Ie h loc.At., Lacmion (wei! i1~riW}---=nOLNiJ~-c.-'.,O.1-___ ·'!·:r~~t~& illiti~(s._· _:ro'-".!.!1"n",v=-w/J.,-"/I,,,,;J.""J\;-'!~--AR¥t~"'M'-P./Mer ~ Dale Imd Time for l"urgillg q. J/) , 01 , mnel Sampling (if lIifferent)c..' __ ----- Well Purging Equib:ri~ "£iii!iJip or -':'b~l~tW61t~%p (if ollJerihnn .Bennet) (3.r"'nJ~o ~ SamplinglEvent ~.o,f<r I~ ,,;h.Jclch/,o";~c P~i'.),~~,I!;~~,rop.tM;ilj.~~,Ij;,p-!inwW~iIt;:r)'!M ~,q p!HMfer 7.0 7,0 Specific ConducQlnce q n , . ~()ll' "ui·c·'~ '"e"~' i _:. ",.,i ~·,·~· ;;:,' "",,' ",' ~c-'",-,:"-'-."....:..~"-,-" ~ .•. ,!oA "1 ~}UI,', .. _,' .• ,... c .,,' i': .. ;~-:",' ~(l\.1~!i~q/li!1ijtii.~%:S8,;1L~C;.,::..:....:.*~: ~:;:: 'f?i~;:\: pHL:~ ____ ~ ____ ~ ____ __ . '.' : :-.' It ": ." Redox ~htial (Bh) . Turbidity __ .,-__ -,-___ _ rime:~,.._...."..-Oal, PiI,g~",-__ ~_ time:~---Gal..Purged,-__,,4_-- COllduclance'--__ ~--'7"..:::..-__ Conductouce'--___ "'7'''''''-_______ _ pH, ________ ~~--__ ----- Temp~mu~>~----------__ ---- Y"'doJ[ Potential (Illi) ______ _ eGOK Potential (1311), _______ _ \), -:::r . ," (~;. . . ' ; .... .... " Mm -tfimlliic1wn!e, Dkc!u;,ge P~,mlt Grmmliwllter l\l.{aa!iCrrng ilJare: H .I7J/6 .i;>'eviololl: ! QmllilY ft.llOlliGllOO l'lruJ (QP,p} Tm~icliiy_======_. __ _ TUllliooly'_--======~ __ Pumping P.a!e enICi.!!p-timl ". 1'1!!}W RIlte «D. in gpm. S/6fJ = '------1:;(,>---__ 'fim~\o evacuate two casing volwll~; (2V) T=2WQ-_· __________ __ Nmnber of casing volt/Jilli's evncootco1 (if 611iei II!rui tVJo),_' .:..' ___ .,-______ _ If well evacllilted 10 dryneso. number of gallonS eviicu.~.ilc:.·,.:... ____ --_____ _ Nmne of Certified Analytical Laboratory ifbiiIJi;'T~ E.firgy Laiis._"_·_' _·"'!\)"'I"'A'-___ _ If a preservative is'~ed, Si'\lCify,TyiJI(.'!1,'~ . Quantity lif Pi'eSeiViUive: . , lVlill-(lrdlum3wnter i'JIisclln,Ll" P"'T<lil Gwnmivmle..r Mooitoring Date: 2.25.07 ]Revision: 2 QUIlUly ASSI!'!Il!ice Flan (QAP) .&'j]']'AClRiMIIEI~1f' ] WlH!Jl1l'll!: JMliE§ilI 1lJ1i&A\lJl!IUMi lWUlL.R.. lFillElLlIJ) WATA W((]JJG:§Jll!IElE'll' J!i'((]JJ~ 1Gl1JR((]JlUNlili W A'll'lElJR Descripii.oll of SaI11[ililig Bvent: ;r" QIbW{~;' A) ,\ccJe /ClD loe,A t- !'8geiJ9 of41 o ~i' ~jl~'#P.l¢fi li_., ',~. ;;;.' Lowiwll (weli llrune) 'ntJAl -I!? Name Md iilitiuls "JOonu: H.I{:,ll' ~ M P.I"cr Date amlTiille for i!'mgiog q -;;l.\ -0'\ &lid Sampling (if diffe''''lt} __ ~= ___ _ Wen Furging E'liiJiprtrJg~; 'biJ~iipor ~!iliji~/''W~jt;g;~p (if oilier IIwn Bennet) c;.r"'nJ.\'o ~ .. . .... . . Snmpliag Event f0w\.;r I~ ",;+",\rlc~I?";J, . ",1.' pH Buffer 7.0 7,0 , I ,< Speeific Conductance 'I q f5 ul\ilHOS/~tt1 ., .:W:eil,p.~tilli~., . .' ; "wO" .... ,'''''' ;;,;",.,1, .,'" . '. . .' .. ! 't ~~"~:·'·'·'.,.t:t:·!~··'~'>F)\'l':· ... , •. '~ '.~·1'" "'f' .. , Depill to Water Befotell'urgin ... g......LN"'/;.cil-<-___ (:asi~«·y1ilii(iie.( , ' . " ". w~ii V(literT~!iip. (a\ig),~. --'--,--~~--c : ,'.'" . ',.' ';', ..... '., ,', . C":" " . ',.' i .-. :F~,~~~~!~!j!(7:~*:Sq:+:~1L~;,~+4il ... ,::~~{;r';,~ pH~:~ __ ~~~~~~ __ __ .-J,' : .;.. . ,i Tem~~~~r/l,.; .... ! ,J, ~s, , Re40){r,~~!1~ii;·:~~i"." ''1,,-\' '""q~b,,-'_' __ _ ~bi~ity'''' " ~'G' ... R,.~dox ~lenti.al(Eh),...,-_____ _ Time:--:-_..,,-_ Gal. Pu!'g~d, ___ -"....--Ti',lie'_---GI.l\.P\lrgoo'----;;r""-- Conductailce. ______ "7'L.. __ Conductance ____ /"L-_____ _ pH~ ____ , ___ ~~ ______ __ pH ______ ~~------__ ----- OK ~oreJJtiflH (Eb) ______ _ Te~ure : ~i:lOlt Poicntial (E!J:) _______ _ Tempemll!p·«..... __ -:-______ _ ( .-: .. " ......... ~ ( Mm -(!fflllilaPJlltei' Disdll,rge P~wt Gwwulv.'1l[er lVlarutcr'",g Di2le: H.17.0!i Revie!Oil: I Q.!llity fo.JlBI!IGJ1Ce Pllm (QAP) Tmbillily_======-__ _ TtHllirli'Y'_-======= __ _ Volume of Vi/arer Pillged ~Glf;;!I~~---1I..>..bAS-,-____ _ Fll>w Rcte (Q), in gpm. S/6!) = ='--~---..I;;r;,-----Tiroe".ro ewc!lute two cllSUlg volumes (2V) 'f = 2V/Q = /IN A Number of casing voluiries evilculited'(ii' dllier tllan twci)_'_·'----__ .LA"").L1..£!l'-_____ _ If well evacliat~ to dryness, number of galiotfueV'acuii't?.dcc"'c-' ___ IV......J./ .. A'-\. ______ _ If a preservative i.j' u.ed; SP\lCify,Typt~ QUantity of Presel.'Vlitive: rJliIn -GmlIrulW1Iter Disch'lrg. Permit (imum:2l"Ja£ef IMimilcormg Quv!ity A1ls,!11l1IGe Wini1 (QM ) A'1!"iI'AlClllliMiill:R1'Jl' n 'WIHill'lflE ~A 1!/ll.WmJIM! Ml!lLlL 1iJ~le: 2.25.01 Hev;,;oll: 2: IFlllEiLlID llllA'll'A Wq])B:§lHIIEElf ]ii'q])ll& IGliRq])l!JI\IIJJl W AI 'Jl'JEIR ))escrijl!cmwf Sa!!lpiiliigEvefi1: 3f'" Q\..ifl.~ c· il) ,'tccJ.~ ,Iek> loc,J L Location (weli mime) Thl/J -tQ, ,!,~~ti~d' fuitiJI~ --Y;;nw H.li :J,,;. ~ a~ P.I"cr Da!e llRl! Time for Purging ~ l-CYl and Slimpllng (if diffemnt) g ~ do ~ ~ O~ . Sliinpling EveRt Q,wf~cl~ ,,;t'.JclChl?';~, pXHluffer 7.0 7.0 Jil'!';,v,:,.w.:wJ:~~wji\~~.i1j :~lir~plillg'~lYellt;:r\.)t.J ": I PH.i,~,¥((e,i;'·1:b,;{/,:; ;r"":,~~().;: ,',:;""'"" '.: '. " Specific Conductance 'I q g : I.'~ uMHOS/ciII .:l Weil)D~~i1i'"L'''.''''''' Nllh ... ·:,·"o< .. , •. ' , . .,'. "";·I:·~~~u.:·".~ ... ~·.:1:·'H·.~:.~~n ...... ""'q ,:-... <~~ '''j' ," Depl:hto &ii(!tic~iie·"':,:L2.~' . ". I,'" .:~. :: ...,' '.1 "".! :' ':"',' '.' . pH , + 77 temp:~i~l!fe::.,.:. 17d.!j ~<:<1~x:l'P~~,~'~i~.';(;>;~ t Twbidity u. a R¥OJ' .l)!tential(EIt),--:. ______ _ tjn1Z;-,-~-,,-.-Gal. Pum¥, _______ ti~e:.~---Gal.Purged\....---;,.c... __ ...... Conductailce, ______ "/""-__ Conductauce, ____ "/L:.. _____ _ pH ________ ~~ ____ ----pH~ ____ ~~------------- Te!J!llemt!!l:;:'v ________ _ ,~e'il(jK PCiteiiltial (Iil!J), ______ _ ''0' \ '''' I n 5C{f' ( .; ',' C": .. '.,' .' ~' ',: , . . , .. ' ( MiiI-GWlli1rlwnte? DisG~lltge r'~1>1ii GrouruiwiJ1er MoailOling JOate: I.I.17.U5 Ravinioil:: I Qit'lliy Allm!fllllCe I'lruJ (OM) Page IIi of 4l! Tmti.!lity-======::'-'-__ l1i1:11illily_-======= __ _ Pllli'\lling Rale Clllculntioil FIIPt'l Rille (Q), itl gpm, 5/6D= ='---__ ,'--__ TIme·.~o ev!!cuu1e !:wo CllSllll vollfillCS (2V) T = 2V/Q -'IJ; /~ . Number of c~sing VOIUineS eVilcll!lted (if diller tilan tu/o)_'_,'---'-'N"'I,.,liOla:--______ _ If well evacun~ to dryness, number of galiorlS e1i'aci!a't~jJ,"" __ --"-'rJ"-'-/_'klL.. ______ _ NllII'le of Certified Anulyticlll Lnborarory if bJldi:fl{~~ ilD;ii:gy Labsc-' '_:~" A"'J.L/",A,--_~ __ . ." " ;~" ' .. :,\ , , , . 0({57 • i t.r.l-vtc al 0901 " ' " If a preservative ti"itBed, Sl'(:Cify, 1)'p9., ~ Quantity of P!:eSerilative: :'.":o! \ !Vim -G;~a;wwr.ler J);';G11&rll" Permit OrOll,mivJI]re; M(>l]itcriDg Quoliiy AO§!<{llru;e Plnn (QA!1') Dute: 2,25J11 l!tevi.<:iC!l: 2 l?age 49 of 41 A'lliI'iM::mnWlEl\J'll' H WlIIIll1l'JE IMil!!;§../;\ IlmJ.\RJlIlUM lMllllLlL LIi']lJElLlID lIJ1&'J/'& WI[J)IlhlfWl!lIlEJEll' JFl[J)lll GllRl[J)lUNID> Vii A'J!'1Iill. DBscripti!lll of SHmp~itig EVeUt 3[" O,~;,: A).'t c ~e. ,Ie b (CCI d t- ," $.Am~i~~ , ',,':' ",' , Niiili~ lihd ihltiais,--:ro'-'."'"illM"'--l'HlJI.""I",;J.,""Io~-'~'--'R""~\-,O!!.C.A P./""er l .ocntiol! (weI! iWroo) 'lJ,lAl -3 K. Dale ancl Time for Purging q, JJ. iJ 1 and Sampling (if diffe!'eilt)_I\c..ILC/-I'.A='-___ _ Well Purging JflqiJi~ bilelt ;:Ziluiiip~r _bi;i~~ "w4lfii{~p (if oilIer Ihall Bermel) (l.r .... nJ~o~ Sampling Event Q"9A"c1~ "; \'1 cI c~lu'; J, ~~).~~,ll1~~W!il~\lii!!, ~N~p.!ig&,.E)i~hkT'.)N"'.2 " ': " pH Btiffer 7.0 7. 0 , '" ' p~,~9~f,,~:;~;<:::~;,:~:,:"~·O,::(,;.~:"",,:: Specific Conduclance 9HS uMHO.sfellt " w.~ii;p.;p.~t-,;;:'.'it2,;;, •• 4. J""',,,(,,,,,,, . .. ( .... 1 ;,,!.o;"~".~.~'. :'~;"'~'.;"$"t';' ": .... :~ -.-.,-', ''OJ' ," Deplh to Walter llefv1id\wgiing _____ C,~si,ri.g:·Viillii~iie w~fi,Waiet 'lfeWli. ("vg)_.c...,..~~~ : ,',.;,. " ,;', ',', ' .... ; pHL:~~~L-__ ~ __ _ 'temr.~w~.~,'"" !.tl/~ , ~e4o~£iO~l)iiii.ih~):;;:, t( at T~i~ity" ',-,", ',.,'')} £1 R<;dOK lJ' erelltiat (Eh),~, ____ ~-- Tim,e : Gal. Pu, moo , Time: GHI .. Purged ~.,-..,......-'..,------,,,.--" ----'--;>-«---",f," Conductntlce. ______ ....".""--__ COnductance, ____ ....".L.. _____ _ ~L-__ --~~ ______ _ pH~ __ ~~ _______ ___ Temp~~>~ ___________ ___ OJl Pot~,J\,in! (Eb) _______ _ ~~i:I(j)( Potential (Eh) ______ -- «: .. .' ; .... l ": . ,; ,.' '.' ( Mill-GmW!dt~/Rt~ Disch~rgB Permit Groi!i!!lwn!(If MOOOO1ir1g lJ1ll:e: H.l7.1l5 Revw;oil: I QwlilJl AIlsllianoe f'iruJ (Qflfl') rmbirlily......:======-__ _ 'furoirli,y_-=======-__ _ VOiUiiW ofWater Ptlrged ~~'-_-JI,-,,(,,-=!),l...-____ _ Pumping Rate Calculation Plow Rate {Q). in gp!:!. S/6O= ='--_b--- TIme',l;/) evacuate ,wo cru;ing volwlles (2V) T = 2V/Q ----"''''4''''-, _____ _ Number of caGing voltillies evricilli!ed (it otlier limo two)_'_''--_--'o.ul/'i-, ';"} ______ _ l'f well evacUllt~ to dryness. nomher of galio~ eV'acu~t~il'_', .. '--_..I.N."'v,ui3:h, _______ _ Name of Certified Analytical Labnlll10ry it'bii,di:Tmi'~ Eti-e'i-gy Laiis~'<_"'--"A"'"}.LI",A,--_~ __ , , . If a preservative is' used, Sl'ecify;Typ~ ~ Quantity dfl'ieserilltthie: '. Mill -Gl"frmulwn!er .l!}is(;!Ja,1J" ll'.rrnil GmtmGifJ!lref l'~m;iiofmg l!Me: 2.25.07 lRevision: 2 Quu~ty PWGlJlnnCe Plrul {QAJ?) A 'lI1l' AtCJBUMlJEru1f' ] Wlfll!!'ifJE l¥!lE§A l!1llW\.1JllIJTh![ lW!lfLIL lFlllFJLlID JID&'Jl'A W/fI1J)llWr§DI&1f lll'OllR CJlW)iUNIlll 'WA1flElW. !)esClipQIDil of S!lI!lplilig 1i!Ve.li: ;r'" Q,),(d~; A ),\Cc.\:e /cb(oc,J ~ Lnclltioi! (well name) 'nNtJ -lfR • Ii' $.hi)p.l~r; 'C ; •• ' 00. •• , Name iliid iliiiials :G"W Puge40of41 Date /lull Time for Purging '1-:< f. 0 r l!IId Sampling (if diffel"eut) '. ------------- 'f, -: ": • '.1' ..•. ,/".';.'.,.)'}'".' Welll!'t!rging Bq!!ipUgeti; iipili'iip (If _bailer· W~l1;~;;~p (if other dUlil DeMet) Slllnpliiig Event f.A,o,.f.[I~ AI it'..!, k~I?";~, pH Buffer 7.0 7. 0 Specific COildllcl<mce '1 'I [} ... wdi w~tetjiItiP. (aiig)---:-o-~~-e ... '.;. " ;:', ..... , ~{;il:i!\\~/it»~e._\-.. -"·;".. -"-';~';+;,±-."". '",' . .c. .. ..,.o...~",-" ... ' pH .7·15), TellljJerl'!'W' ,. r7 . ~s, .. ~ell~~~~~J);~:k.~):,··; e; 3 '. _ ~. " '. .,1.,. , ,,:.,~7.·. ",.,:-;' •. t', "'. '-'-----¥«dOK ~ntial (Elt),~. _____ _ Turbidity D Tilllfl: . ....-....-......,-_ Gal. Purg~, ___ -:; ____ rii,iie:~ ___ Gar .. Pl1rged~......".£-__ Conauttance. ______ -".L.. __ Conductlllice, ____ ....".,o:;.. _____ _ p~------~~--------pH ______ ~~-------------- Temllerotu~r·""------_----Tempe· urc, _________ . __ _ )l.!l Oil Potentini (Eh). ____ _ .eUOJl Potentia! (Bh) _________ _ ' .. C·'·· --.' . ( ItI,J..ill -GmHu~Wllle? IIli5clJ~~g(-! FC!"mit Oml.!il.dwllle! J1fuiiftorr,ng nele: n 17.06 Rev;nicll: I Quvlily p.JlSumw.:e Plnn (Qfol') Tt!!'oirlify_====== ___ _ Turbiclily_-=========-__ _ PuQlJ;1im; Rille Calculation Plow Rm:e (IQJ). ill gpm. S/60: "''----106>---__ 1£'ill1e·.~o evacllute two cllSmg voimnes (2V) T:2\"Q-N il.) , N'li1ilber of Clliliilg volUines evilcl!!i!ed (if o'tliertitali [,1/0),--' '-' __ ~N"-L/L(j:L-_____ _ Iff well cVilcuatOd [0 <lryness. !lumber of gali01i~ eviii:"a't~jJ'l'iS" __ -"""'IL//.;,!}I:-______ _ Name of Certified Anaiyticlll Labor.tory if bUIJifllah'Energy Laiisi_' '_-',,,""',I'LI13[;,'--__ -- If a preservative is' Used, S ' ify.T e and 1'1'<', , YP."".". Quantity .If PreServative: Min -Ul"6mullwflter Disclwilie 1il'ermli GWVJl!lwllre; Mmilito!ing Qtmlliy AsS5YllnOO Plag (QM') ) Date: 2.Z5.W/ .litevisioR: 2 l?agellOof4! A'lI1I'ACill!MIllj:N1fB VI'JlHJl['l!'lli: P.A lIJlMI\lllllJM M1IlLlL l!i1l1li:iLllD IlJ)A'll'A W/lI[J)1P'J[§IJllEl!t1!' JIi'iGlll!. Gll!.ilJll[JNllJ) '!'if &'li'1E~ DescripJiOl1 of Samplilig Ever,l: 31"'" Q,>.CbC+; C' A) ,",erA.;. /(1-1 loc,de Localioll (well 00100) '-nJ,v -,J; e. .. 'I' $,Mip'.ikri '. ,.", Name riiid ihltials :G"W Dale and Time for II'ruging 9· 2 ,. O<i j Illid Slimplli1g (if diffeIrent} ___ -__ _ :.: . !::., . . . . ':! '''':'11 .. ·'-'...,-"-$11Y I Well Purging Equip 'fIJ~eil!: 'Liiul~P OJ{ _bader *~ii~inip (if other illni'! )Jennet) Gr<AnJ.\o ~ SampJiagEvent !IlIw\vl~ "';~t~c/c.>:lo';~, pH Buffer 7.0 7 .0 Deplh 10 Water Before h~gin ... g-,-/V",-,-I4-__ -:-_ (:asiliig1l1iiii~jje ( Temr~!:'!~·~ ; .. ::7,2:'.4 (, , . . ~e4~l(t~.i4(1t,ii¥~~)':7'. ,'*:.(-"' .... ;<-;&+-7-· ----RtidOJ[ ~ential(Eh),~. _________ --- Turbidity C2. 0 Time:._,.,..-..,,-_ Gal. Pumtid'--__ --"v'" TiDie:,_---GnI .. Purge4'--"..L--- .:. CoUduclllllce. _____ ,_---:?"'-__ COllductnuce. ____ -:?""'-_____ _ pH~ ____ ~~ __________ ___ Temp~mU!~·~ ___________________ _ Tempe . ure. _____________ _ y.e OJ[ Potentiill (Eb) ______ _ .eUOl[ Poieiltial (Eb) _______ _ .: ': Co: .. .... ( !Vlm -Gr4PJffidwntel .fi)jSG~mrge P.0rmit (1rOi.Hlliv.~~~ jv,{omturing D~Ie; n 17.(),s Revision: I Q;mlliy Aum!mrree PIM (QA.P) Page 41 of 4~ 'Fm'llidity __ ======-__ _ Trn:lIiriily __ __=======-__ _ I'llil1,UOOg Rate Calcmatiou Piow fulte (IQJ), iii gpm, S/@= "'--~..-.Jb ___ _ Tim,,',!o eVV.!:ilnte two casing vollU11eS (2V) T =2V/Q= ""A Nijmbe~ of caslilg voluilli\'s eVilclJliled'(ifdtlied hali ("jo)_'-,-, ___ M--:V'-'/:!"'-______ _ If weI! evacllnt~d to iltyness, Dum.ber af g~!iOlib evlli:u,~!~iI,.::,,"-,' __ --"',v,::<>':;,(),L-______ _ N=e of Certified Annlyticnl Laboratory if bJ,~f'tllii~ Eil~i:gy Laiis,-' '_"'_' ~'A"'I:L/£iA'___ __ -- If a preservative is' Used. ,!' Sp¢ify,'I'yP,~~d , Quantily <if l>!'CSelviitive: Mill -G.mmllilllmter D~sclI!lIge Penalt umum:J\,I',fl:tei 1\~m~cormg Di>!e: 2.25.07 Revision: 2 Qtwlity A6u~lI!m;e Plml (Qf~) 111 'll"H' AICJHIlMlJER1'Jl' n WlHilI'Ii'IE ~A iij~Ii\Rll!lillMi MlIILIL lFiilii:IT.11JJ I!J)A'J['A W([]ll1"JK§HIE"JI' Hi'l[J)llR 1G~1[JJ1UNJj)) WA'li'lElif. DescriplBon of Samplirng Bvelit: y'" Q'hQ.df~· A l.'tceJe. /rb (oc,J C il'age40of41 Localioil (wiili nili.ne) "TI;IA! -{; i2.. ·"'~t:~i~~idiliiii~ls :Gin"", HQil;,l"r ~a~ P.IMer Dute nrlfJ Time for lPllfgillg q. 22· 01 &/ill Sa~l1plillg (if different) . Well PllKging filqll i'/':irJkoc 'Litiitj"ioi _~i;il~~' ''WJit~p (if oilier ibun Bennet) 6-roAnj.\'o~ Sampling Event Q, \9'f~rI~ ",;}oJ cI ~Ior: ~c ". '. pHBliffer 7.0 7. 0 Specific COllducl<mce 9 U~ Depth 10 Water Before PlI~ging_",6A4-,-,-,-___ C'ms~rili ,Viilllirnle ,..----;" 1~~±i±~~~;~~~W~~~~~~~~~4·;.;· Ht:~:ift; ~ .... , " ...... ~o~itilC{iw~e ' ') '. ([., 1 ., : PI/' , .. : ~ii '5, y:s Tem~;~W~w,:., :,)~·ql· . p.et1o~ptii.\ill~iir~jj)· .. : . iff b 1Inb;~i~ ". ;D'~O Cond1lCtance. ____ --""'7''''--- pl,--------;:7"'------- Te!l!peral~)'_ ""--__ ---: ______ _ Ill: PGten£ial (Ell), ______ _ . . , '.' ;;' , ,1":" RedOJ( ~tentiial (Eh)--,--_____ _ Conductflllce, ____ -;?''''''-_____ _ pH, ______ ~~------------- Te~1e' re __________ _ !tililOlt Pd!im'iai (llil), _______ _ C·,: .. . ' ; .... ( rv.rill-lIlOllEatI'JfltBl Di5f:;1~rge PeJwt OrmUuJI?J&Gf I~8!lii:miP.g Quality AnmDlloo Plru; (QAi') T1!t-bidilJf~=====-__ _ Flow Rille (Q). in gpm, Slft!}= =,---b_-__ ( Pall" 41 of tiE 1rurllidily~---========-__ _ Time' \:0 eVDcllllle ftwo cflBing vollll1lllS (2V) T=2WQ= ________ __ Nilinbe/i' of cusL-tg volunie's evucua!ed (if otlieitiullI two},_' ___ --:-_______ _ If well cvncl1~ to dryness, Dumber of galimis evticuiite'd"', ___________ _ Name of Certified Analytical Lahorawry if oiill;i:Tjfli~ Eti'ci;'gy Loiis,_' '_' _"",'ICL;:",A~ ___ _ ~ J 4r O'fS-O ' If a preservative is' ~8ed, Sp~ify, TYI1~ 1lI,ld Q~antity ofp¢sel'vative: .35678222. Interrlatlonal urallluflI 122958p lll 12-23-2009 ( Min -OrooMWIlWY Discharge P""fill! GrOlill!iWllkllr M<IllilIJtiDll D-dte: 2,25,07 l!evisicn: 2 QIlHlliy A<GUfSilCe Plim (QAP) A'll'll'ACmffilWlr] Wl.mJ'Jl'lE jl~A IlmAllJl!lIJM MIDLL lF1I1lWlI WA'Jl'A ,01lt.II(§lBli!m]['J1i'@)Jr.GIlW1UNIll>WAmill DeSC!'ip!ilJ'.Hlf S~iI1fi!ilig Event: y O,';ck ';. A) ,'tc "J~ /cb loc,A p Pilge 40 of 41 "",$iW!p'li~r, ,,' i: .,~ , Location (well ru;JOO) jJ"J,v -7 R N2Ul'e iifui imrnils :r;;,w H, '{.'L~. ~ "" P./Mer Date and Time for Purging 9 -al-J oo~ Il!Kl SsilipJing (jf Iliff~nl),_' '_' -"'Y""(:.t!lrF--__ _ " _ ...... ~ .. :.."., ". ,", '-" ·~~.th ~':}··~-v";:· We!! Purging EqruplJkd:':Lpi,i/;p or _biiiier :~~U;~mp (if other IilIlD Dellllet) Gr","J.\of, Sa.'IIpling Event Q ",~\<c I~ AI ; j,@,/ Chl~,; J, ,~'Xf'Wf!.!i~iWpt~d,W §.ap.!PJ.Wg'~V~l!h'" W: '! " ' " pH Buffer 7.0 '7 0 pI;t~jf(ep~,9;'~~',:,t~,: ~,:p,;; ,',:;':' '~q > ' SpetiflC Cond.clafce q ~ g 'l,IMlfOS(cl.l1 }"YJ(.'\<J!~~~;;~~;,~~~!.~.:;'J:;/ 'i'i"" ,,,, > Depth !.o ~ater Before Fu~ginlgg_,,,,,,,::::::::~--;:-. Cmsj);it';~liijl~ =~#~¥'~~::f~~';'i " Tem~~,~.'~4_2:;!.J : ' ~e49~.r.q~!lli(~ir:':3: d'G , .. _-::r:~. ,~., ... "' •. , .' 't,'. -, :'t.! ,. '" TurlJidity Cl ~ U . " ~""ox I)' !fential (Ehi,~, _____ _ Time;, __ ~_OaI, ~~'----""7"-'fime:,_~~~ Oal,Pur!led,_~L....._ . "--.' ."' CouiluctililCe, ______ 7-"" __ _ Cond~mn~: ____ ~~----- P'U-____ ~~----pH, ___ ""7"c--_____ _ Tempernb'9-:....._~------T~ ure:--.:... _______ _ K Potential (i!Ji) ~ilX Potential (Bh), ______ _ , , ," ; ' .. ' C·: .. -, -. " ~' ,'; , " / 8/15 :' 4356782224 IlllernalionalufalllUIll MiU -&m.<!1<lwater Disclwrg!' &i'mit Grow;dwa~ MO!llilliillg «""'iiy ABBl.il'lIlEe F16n (QAP) Il»ie: !1.l7.fAS l'.eVWID'l: I Ttlrllillity-..:===== __ -.:. .... . :.:) 12:30.52 p III How RllW (Q), irl p. 'Jl'irrie to flirliCli,~te (t;-iO cMSing vil!uqws {2V) 8160= =, __ ~(;.,.,_-----,,-,-'~" T=~ZV{Q": p:;:.:.).". #rff-" ,'; '''' " "; .. ' .. 12-23-2009 9 /15 " .,'. 4356782224 International uranjum ( PAm -GruluOOlWllIieir D;,e-!!Ilfgte i1'mIiit iG;ro~oowarer Mi>llilcring QooIiljl A!lSMr_e lP'l&!l (QM') ,.J AJI"H'AtCJH1l!4!!Ef\1'jf 1J. WlIlJ:i!'mE Mlil'SA WJ!,.Nl!W MlllUL 12:31 :40 p.m. 12-23-2009 ( \.: iFJl.IEW JIlJA'l!'A ~1!lJ~Imi~Jlt GllWiUMll WA'll'EM. lOe~ooJ!wfS~DlIlglB'I'e1ili!: 3f Q"Qd::"C' A).tCAie. UID(or:Je ",.,.;,ii". i ',_ = . ,_ , , '-"1;JW,,~~1!ff(.'~;:;~· '.t:(i", ~ ~ < _L • , {<' ~'" I ~ - Looaiioll{welH'Ii_J. ':aNA! -81Z. ~tiuj~~'HllIitials :Gnn<r Uo!I;J.t i ~~ P./Mer D~ 8.1llllE'iille fQr lPiitgil!g ~.)J () J ~d$~l®g (if difful!ellt} , ," Welll'~figlBqiji~'~i~\nt\J;~t"~~~~~:~SJti~;(if(i~!h~pelU1~) -&;~~.w~~­ ~!i@tJJ'I'eii! ~~~I~r !~N;A'd,I~~I~r;~{",.;)i~~¥f,i4,~~\Il!1U~~,~~.Jl1jP~'1ifl;1if;¥i'iM",E)·, '" pHBuifer7~O ". 7.D . " .. "i ' .• ~."" ~,'~~-"", .. .";-'. <,,-,~' 10 115 ( :'; " '--' 4356782224 International uranium 12:32:37 p.m. 12-23-2009 c' '" MlIl-I{ilr@ru;dw~rer )!Ji§c~m:g!l I"©rl!!lit ar"iIDd.' Mooitomg QinAiii)' A8sl!mi1ceFlia@[(lJL!') ( " lJiitre: !UUlli JRewisioo: I " .. . ;. ~~~~~,~~,='~"=""="'~~~~ ", ,,<' .. 'Vol_ofWml!'!u.rgel1~!li1l1!'II!\lJMb!fJ,:I!Ii!I!'~4filf"·"ilii!l~'·~iil'·:!!1\~!1!!",.I!!. !_---' ____ -,---_~ . ':'; .. , :-';:~~.,~~~t.~i'<:~;.-,. '''''-.' 1'm!!I!1im!g b'e ClIIClBWiim ." . Flow lRllle {(D, ilm p, S1iW~ ..{, NuJiiber ofClilimg vo~e~~(jf.:~~1WCi)c;c¥l4'i\2,·'''';'·''''''''''-c=''''''''·''"'''''''''''''''''"' :'::"'---,,-,-,", J[fweli OlVOOll!~h1 <ky~~'8"lIil!l!lbiiJ[~1,g~Ji~~1~~ ."', : j'E, 1, , -; -... :).i:~-'· 11 /15 '\ i:' 4356782224 International uranium MilD -[l;roo]m/!!lII!lioi'1lJlisclmrige hmiit iGroMR<lwarer MrunilOring QW!lily ArulllllmO lP'l~~ (QAP} 12:33:25 p.m. 12-23-2009 , 'e· rnIIll!liS--=~!illC-.l±!ll~~~~ P./Mer " ~">~' -.. -, D1D!e ~1j!lI'l7inne f-qt~ging q .~.QC{ ~U\dlii~[l~ing (if diff¢;rellt)'--_"';£.V.£A-__ _ ,', ~,,~-'--. . . Well~@~Eqili~~Ut~;~~t~""~#~~':lt'~;;1f?\lier!lm~pernlet) . ck,,~d~o~' S~J1iill1friiJEve..'11 ?, \~::tt'-cl~8 ;h·<h /c~H!' ..... ~J{~£!!~.~Pl~{l1§,~Jl,~P~"lI~~iil:;VS.>,lS pH JIlMffer 7,0 7.0 . <..OC'", ", -"." - , ' .. , .. "l) 12/15 4356782224 International uranium 12:34:21 p.m. 12-23-2009 JilliII-~lVa1ef Jl)l.ct"lfg~ l"<rOllit 6rro!R1J<l'!lVa~ Molliloril>g Q>iaBity AIlslHOOlOO PA"" (QAI,,) ( ... "-,. Flow JbIe (Q), in gjlliil. . SJ6I)= '" .• ; ·-b . . '. :3:~'~~~f~~f'~~~;~~~~:·> '~~' _.,' _ '. -. -.'. . 'll'j~~.~~WJ!e OlvO) Il~ 1I1l!!!iJl1l!i (2V) ' .• <.<': i.jT.;~:~'l(ft:·t'i;W';;;tVIA'<'L .• "j··;;·, '. ,. Nuilmber of cMitIg lIiil?i~~~'V!i4~~~:(~'i1~':I\lii&!1'i\'!t." '"j, ,·.·FYi {'\. ,.', ; .. ' .-~. ; '.-",. J!f"..,11 evIICWUed,!O ~S8, ii_ben: Iif.·~:~i!i!l~':~~~,~ N_ of Oirlilled .1\..1 iIlI!yflcsll L!Ii~l!!~l)':if,~ "' '-' -"" .. ,-,,,.-" ~-',i'--:-i-\' :-."~~:~:'fn;;-;;. ·~;-7·.1!':i!_"~-' '-, ~, --_.-- 13 /15 . 1 4356782224 International uranium (~', ' , , llJim -Gro_wni .... /!JIisd!argo ll"millIi, IlroWi!dWilieF l\1l",;iloriog QooIWy A1m~roore l!'lrul (QM') 12-23-2009 C: '" tilt nliher!lm> .!Jennet) &r"",J.r~ ~ .> -,' co;:. -" .. SllIlIP!!!ItEvem 9;\"d$l~ ,I'< ;~~01!~I,or;~;, , ,_,~i\ffJ[~~!tIl!I~j~~~!4~~~V¢,lit;ri"~,M~;ri'" pHBuffec7.1I" ., ,,,,,, 7,0 ""_,,",,,"' S~IDcC~~~~~~~ __ u~~~~'1 ',' 'm· :,.. . " ~ Con~mn~, ______ -,~~ ________ _ Po!e!ltial riili¥-.; 11: ,', ~""' __ , ~-:--:--~~-, 14/15 ...... '. 4356782224 International uranium ( .... : W -Gr~W1lt.l" IDliocl!ll!gelI'<!r1!l!i! lIJrouOOlwilicl Mooiromll Qldily Ali __ e Flab (QAlP') Flow JlblIe {tID, iii gpm. 8100 = '" '~" ." ,,,; if:" 12:36:05 p_m_ r;. I . NiL'HlIlM ofcil8iJ1g l!61~~!~~~(~;Il~~~~\lW~rf""~t~if, .. :,,,,, .. ;.,,,,,.=~~,,,-, "'c" "cc'''-, .. '''· .. ·cc· ::;;c,.cc-_ 1m' 11'",,11 e1i;w!l.!e<lIIIlIIIrY!ll" •• llruml~,jr'~['iii~\!ii~~·:~J)jj~~ 12-23-2009 15/15 -", -. '.--~~ . ..: Mil! -GrnmOOlw&wf Di8CI!ru'g€l jp""'Jili! ililllm<iJw.re. Mooi!orlog QIl!ilitJl Ailsormllre ll'J!~!1 (Q.!lll') A'lfil'A<CJ1lIMllli:N'Jr 1 WiIlHillll'lE l.¥lIE§A ~~1llIJM JMillU Jii'mJLllJJ llM'1l'A 'W(j])~JR[J)i'--l!w.!'.1ij'@1~ G~(j])llIDJIDi 'WA'1l'lim. De~fIJlofS~.llruiglBve~!: 3'''' QII,(hn"C A) ,'±C«k, Ichlor,Je Wca!irnn{welhn&me)'l1blN -(11 "<I.!;,~~~tt11&i~~a~~~ :i;'"ntr 1/1;"~ '~"': P./Mer D&£e aoo Time for 1!Wginlg q, 22,0 1 rotlll.!l~.I.lJillg (if £DitifeWlI!} . WelD l1'tIyginlg lE!qiliJ,!iu~,"~~~i' ·'IDi!!~;r;'f.~lt'~JlI (if oiber., fhuOIjffienne€) (k",~jfo~' S .... p!illgEveni ((),wA.rl~ oJ ;}'~\cJc~I":~,, :, --:.'; pI.J:J$iilffer7.0 7,0 . " .'.'--.",.-.. .', -, ... -, . ". ,:"---" .. -. : .. ~o)(~' J{entiial (EIJ)"i-,; ____ -- COndui.:!ance'-__ --:r ____ _ ~------~~-------pH~ ____ -7~ ____________ __ Thmpel1!!u:r--________ _ 1'emp,e' !!re<...." _________ _ Ol! lP'oloo!iaD (I!lIII)_._,, ____ _ ~ill!(jJt Pmential(lilll),_' __ ---- Co, .. ~ • j " ' ---.' " \.' ',' .. j -.... / " Mlil-lflf®lWmwa!er lfJid8i-ge ll'e.!ii!!il {1ronmwmW M01!i!O!'nng Q>J!!lilJl ABsI!i:ili!cell'I.D (QA...1i') ]Dille: H.n®6 RevifliojR: ! 1!'~iiliiti1i6y:,:,' _-=-===== __ _ Pru!!ping lfuIte CalcUillatioll . -'T'-' Jclillw ~ate (Q), ill gJ!llll. S/OO", ='----9,,--~ NIl81Jlber of cllilimg voluiilii'seviiciJiliierll(ilf'ljiliBfHl/i'iif tWo),,,,P_'c..' ,""-"_-'-; _______ _ JIf well evaclIn!Cd 10 dryness. number oj g.mnto~ 'eir.re1li14fiJ",)lillM"" 'c..c..~ __ --_"-'. __ _ o Co!l!lllents A';,:'~ 00 ~~~ t~ -;00 . 'lAc,," ~~I ;ht ~ ~tir P..I",,, r,r'ts:t r \hf~G -'r~r sh, ... fl, <'L.,,). IOd2-,J:;A",'~'7 Iv! ~r 12 M_!Le . , :: j?,,'"t' ,..(\~ .. A wt IDly . I..~.Q :,14,. !,ff 1N£,< )G\.IY\?k::jj;b HIt' SF"tle:-Itz! !)W If?:> ',' ;-;--, c Drf,,~.-t'-is TNA/~ ~ Mil! -Gro"lllIlwaler ]Di;.cl1arge Il'ernmit Groundwater Mooilllring Qullli!)l ASSWlll!'lCB 1I'11J!1 (QAlI') lFJIm,1llJ De1lCKiil!i()J!lllfS!!ijliP;i;B:i~;:~~J~=~::~~:;~td::Z:~i-__ ~ lLoJ;l!tioil (wei! Iijiiiiie)e.-" 'J£..J/t.<' (_-r"'--I-___ _ Date Sijo1 Time for Jl'!Irgilig , !!lid S~pling (if djfJllmott2.:kU1L __ _ ;;-,-.. '-.-: __ "o:--:o,-~;:,--<:: ~ ___ -,;: __ . ,;" .. ,,+{i(-~,).'i-\':,~t1!f.i,·~-'-· - Well lI'un'ging 1ilqtdplli~ "~~i'Ii/J Of »ail;;rw~jl)lmi~iP (if o(l!er,tbnn Bennel) ___ _ SampliliglElVllill#J..k k. tl4(''''~ "1'~~1~~,U)~!®i\tw;i1t~~P!i!ig)fjye.jlJ ' •.. ' .. " Speeific Conductance 1'1 ff ". ".', ., ---. l" ~-- " ,.' ConiJticti!n.~~"", ___ 7""-__ _ ConduclanCv-"'''' ___ 7'''''-____ _ _ 0)( Potential (JEIlL _____ _ . ' ( \ . d -il:JwmJidlwa!el Di6cbll!:ge Jrnllillt o:Jromrilw2iB J.\{lIOOilllli!Jg i(!ooJ!ity Atlsmance ll'lon (QAll') (. ll'~ge41 of4H ~ ; ~),o evacuate !two caaillg voll!llles (2V) t,;:tifiQic,.'.' ....' ~ .. ' Nili!llbeE of casitlg vobilli&eviibUiitCdlikd!llei'lhiin tWo):"; ~. llf well evaclllIU;d to drYlless, number of g~lio~eva-ci!~~)iW." > ------------= '.\ ,.' , Name of Certified Aualytical LabonrtOiy iJ'OIit~lf\f~ai\tIi~ilY lLaiid '. ,,:,! .. ,~ .. , ".". MilH -GroVlndiwaler Di,cllll~ge ]P@rmit IGrov..rul\lUll!e[ Moiiiiitoring Qua~!JI Assrutranoo ll'lfill (Q.iIl:') J[l~ie: 2,25,07 )1',.evi8iol'l: 2 AI'll1I'AiC1IJIl\nlIElW Jl 'lJ!llIllllJI'JE ~.A 1UJlt.1%.NlllUlM1l\4!lIJL,L JFJiIJi:/LIDJ JIl)A\. 'ir Al([})~IfliID:Jll}1JJJil'(j))llt @llt([})1IIDJlDJ 'W A 'll'lEJlt lDescripiRoJlilof §ampiimg Bvent; S ~';'7 • diM 1 cf.tk;/;. () f JLocatioJl (welKiiiriiiir B to? 2.' ,\!r~l{gi~~j;)~t~t 1i~A~"t£?tS lit"/J"",, Date 8n!l'i Time for JPurgmg &il.d Sampling (if different) Cj.;;I., -d { " ,. . ..... ', ' .~ - -- • _ "-i' (:-~-~~-_-J. 'd"-~'~ L·.;~~_:." -."-.". <:' ~~:!!;_:",·Y!~~~t.:~i~::ii.{;&~r:: ,:" WelllPMll\Il1IgEilblp lUstiilf: ::.Jlilill'ifj or LHiiill~r .!Mi;,Il;l!tiBjtp (if lliher.ibHIl Bermet)'--__ _ Snm!JliljgEveili#f".( k. t!dQO'( .. 1'~¥!\~~»'l~~P.t¢.~~j1I'~,*,Plwg.)tl.Ji~!l.t&7, / "., ),' pH Bilffer 7.o,~=+1",,{jC<..---::-7~-'-c' . K-'tl"~~~t\~~~~:';:;;H& ~:::::i;~,;;,;:''';''';';' .. , ~~Sf~'"l·:!\~~~J~R~~~~::~[A~~~1.:~:_2:._;:t: ~:~,~~\~ ~H+'~~·-.'>'A:'-! -~~--. Speeific Cllndt)clance 1~ 8' 'fi .. ·.,....,, ____ GaI •. PUtged'-------,,_=__ COlld"ctall~.>,,_~_7""--__ _ Conducla!1Cu.,>"=-__ ---,,.-::;.. ____ _ p.~----~~~-------- Te.mperarn,,-. ______ -""""' __ _ R oJ(PorentlaB {Eh), ______ _ Riiliox P iii!ilil(EII) ______ _ C'":" ." ; . ~.' " " ~' ,"; " / C \ .. MOO -I!:lJi'GBwate. Jl)jsc!Jnrge ll'omllit {Jrorul!lwareo lYnoilltoring QwOOly MS""I';l"" 1!'!fl!] (QM) c 1Il'at~; H. na6 Jitevisiom; I VOlilili6 of Wllter Purged Vilhan Field If'an'llilW!ers are MI'i~surea{===='~"=====:- Jtllll'w Rate (Q), in gpm, . 8/00= ---=-==== .'. " . :-.' .. --;, Time'ro e'(fac!late (£wo "Ilsil!g volumes (2V) T=2V/o.'" , ...... '. .'.-. .', NWilber of cailing voliliililiileviililiiated(ii'6i1ler fMil t\riio)c:::';"C::::"'-'-'-_""-~~=' ~' 2' '''''.c.'' .c.' -'-'-' "-"--'- If well evacuated to dryness, number lif g~I!;,~~ 6vlibii1i~~!!:"iCL.:..' -~'---7"-~~~--'-:'':''\'-' "-_ ~-<-.. ~ If 11 preservative ifilliei!;' ~!ftyr:~W~tIJe: .•.... ''\ . "-J "A:.'-" Mill -iGrotlndWlliOi" i))i'c!lllill" lPermit iGroundwater OOl>iJitormg lQ1!aiity Ausl!l"llnoo li'J1lIl (QM) ',': ! A'll"lI'AICllillWlii:N'l!' n WlHIJI'J!'1E JMllil§A ~ RAiIllLlL 1FJIIEl!.JjJ) lIM'l!'A "([))~1Bllli;~rro~ G~([))1UNIDJ WA'J!'1E~ li)erreripliomt of S1J!IIpliUIIglBveml!: .3 Gkm «..I}//bt, "c/dltde () f 1oclItHon (wellllilriW) ka 3",~~l~dj;;i[1iil~ 1A~dU li//,~).t?,., 12,,,,,, Date anrl Time for IPurging Mil SaI1!lpling (if different) q j:J. ' () l' . Well P'lJIl"gil!g lElqlliplIiie.f '~~poKgliaii~/'W~H;~~p (if oilier Iliun BeMet)' ___ _ . Sampiiiigl!:lVe!ltA:'1,,'( k cit/oJ: PEl?Y;W\\ll~~P.I~4)'1§,¥",p!ilIgE.vel1tA;e2 ,--~ -'". , . . -'. -, . pIjJ~.~r1,9;~:::::;iA~: 1·;;" Specific Conductllllce ,19K JDepll! 10 WaleI' lBefore lPil<'ging,--l.<=-:~.L-.,.,. C~a.iijiE~folijme c Temp!'ratu.!". 16. '( L/ !,:--.---, -.-,' .• ',-.,-! "', . Red\lX F.'ti~il!i~1 (jr :1$ j ,. " >'.' ;., ",' .. , '., ",,', -":0':.;-'- Rf1(iOlC ~eDtiial V'''I _______ -\- ThIbldity /10, b Time:'...,-. ___ Oal. Purged, ___ -= Tim.,,·~---GnI.ll'ilrged,----=- Comluctan.""",~ __ ---:?",'--__ _ Com:!lllctano.N,,'""'= __ ---;,.""'-____ _ P'~------~~--------pH~ ______ ~~~ ______ ___ Tempm&tr-___ -:--_-""'-=-__ R "Potential (Eh), _____ _ ." \.' '.' , , ., ~/ , MiJ!-Groil!OOW8te't ][JiscolllCge Il'\;rlll1lil G-rO!llIllWBilW l\IioJlil:Orillg Qillility ASSO!J'B.1!"" Pion (QAl!') '- ][Jate: H.i7.116 Revision: I Voiwne of Water Purged WIlen JflieldP~lmnelers are Mensured[==========-- TIme to evacuate awo vusing volumes (2V) T=2VJQ ' Number of clllIwg voluimis eVMlliatiJd (If'dther thali tWo)_" ' ___ -:---"'------=--_____ _ If weD evacllilted to dryness, number of gaUorts tlvacliiite;dc:." ,--' ___ -,,>_~~=___..:.;_'_', --'--_ Name of Certified Analytical Laboratory if Olhei'tlilfu'M&igy Labs,",' c..' ,--' ......,----=======:::::.. ___ " ' __ Irk stle 0'r 126'1 r r', ; """,' ", ' , If n preservative is'liBed, SjreI:ify;1'yp9"t'd , , Quantity itfP.j'e8ervative: I "; ! ! , , , , MilD -fudl"nlilWllier lLlisc!tal'ge JPell!llit Grouwarer MoJJDilorilig Qilaliijl Assmaoce Pla~ (QAJP) A'lIT1MClfllMlEN'J!' JI 'IJ!I1HIJfJrlE ~A ~NiIIDlMI lMJillL,l1 lOescrnplioll ofsrunp::!~~:~~l@~~~w·~t!r~~!tJr~~ f Location (weifilu>JjL }tj m ....' 'ji!j~f~jt~ti~l{ ~:M~/a(j~;;~M ii/I'd Date ami Time for Ji'mgimlg ~ IOnd ~iWlplilig (if different) c;. p ,of' , Well Pu~gJaql!ib \iiJd?~iJ~~'oi"~~ji¥;II:~~~r~;'(if o~erthai!nel!ilet) /141;' ~;., 1":"/ Sampling18voot;f,;t"k t '.' t/tkl(!~ ' .. " ,1i:~¥~~~}J.j§~WP.t~;ii1.,§l$IlFll!l"<lllYe.p.t;:;¥" ';;,.1,' -- --."." -. --' -.--' ." .. " .. '. . ", -. - pHilliiffer7.o. ""r-tJ Specific Collductance 1'1 f( -'-!" ',.'.". " •••••••• v" .• -: .. ~:,.". Tellll'el'll!'~:::...---__ ::;"..~-- II ox Poten!ial (Eh) ______ _ ,: ... - COndluctanc:e:::,..".... __ --o,...<::~ ___ _ (:: .. , ; . ~.' " ( MiJ!l-Glfl>lllJldWiller lDijsc~arge ~t llrouwlivlBlei" Molliroril!g Qom!lty ABsoralilooFlIl!l (QAlP') Jl'!®IlingRate Calcillation lDiIlte; HJ 7.m; 1ireviiliOl'; I Time·~. "vacua!e liwo cmsi1lg VO!Ulj1eS (2V) 1':,2V!Q ;." =., . ". NwnbeE of Ca8wg voluiiii&evacuatold(ifJffie{iltiilitWo)'" ~ If well eVllClllIted to dryne.s, Dumber of gaiitJ~~vatilii'i1i~>ii" ? -------------=r,. Name of Certified Analytical Laboratoi'jl ifO~elfTn\ililE:li'@:gy LabS >:; i-, ;~, . , . -,--,; '-,-,-.. If a preileivativeiS'\ili~il;' Sp:;:!)lIY:ryp,,,,~~ '" QUaatitY IIfPf&IltVatlve: .' .. -'; OctoberlNovember Sampling Event Mill -iGBIil~iMiIw~Ii€i' J)J>fucl1lJrg<J hm!l! illmM4iWBielr Mow!!).!!,,!> Q!!aHiI)! J\..llStJII"ilIlOO lP'lail (QAP) mA!CJJlll\4lIli:mr n WlRll!'l!'IE lV_A W&Wlill1l\6! MlllLlL lD .. re: 2.25.1)7 P",visfloN': 2 lFlilElLll» ll»A'lI'A W@wmlHllElE1' Jli'®Jl1€.1Gll1€.~1Ul\1IDI Wf~'l!'IEl1€. !lesmi.ll<UOfJil of Sammpirumg E1IeIiI1: Iftt t;1&uri)rM~4,F cMet;{e JLoo~liiln (weiR B!ilili6) . -rwN ~ l"'~;~tl~~d i~iti~fi·¥ ..... ~ Date and TiMe fo..rPmgilDg ,It? .g2t. tJ r~i1ld SI.l~plii1g (if cliffeA"elli)" . WeliPrugiing EquiP lri:eJJl;pri~P 41r ··Uiaii~;;p~i\i~~~p (if oilier Ilwi DeMel) (-?VttJG-.> S!lIIIplOiig l!lve!i,,,-+I;!.lI.Jj>fa .. Ie!f.'~-""' ___ "-ll':r7"'J'i%~!!;@~Ii!~~,~.§,~l.t'jJlil'g·;I:lY~ilt, ...... 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Jff weB evacuated to dt'Ylless, number <>f galions "Vacu~t¥JI",·;,--' __ -'--_____ ~'----_ Name of Certified Analytical Laboraroryif OlJl~f'.i'Ji\ih;Efigi:gy LabsL' ::"''::'';'-::::::' :' =~.ci~--,-- y If Ii preservative IS ililed, Spet;i!'YTyp~"1ld Quantity of~cilefVative: ;--".l- MulD -(;rollL'Ml_er /DIisclmrW" lPI-_it i1lro!!iiruWlliIW lMiOOlHI\l);il'!g I(!!i!pUiiy A!Jswram:re Ji>loo ~4l!') A'1r1l.'A([;ilIllMllEI\l'lIJ! 'W<1Hll!'ll'IE /MIlE§A lUlR\&NJllIJlW lMllllL]L Descri!Wioo [if s_,:.~~!~rMCJ1L_:m({]ffi\JIDJ WArD. . Wcalooli (weiBij~®l8J T!Nd~ 2;'!!i~~'i~~~iti~f;..14dIU lilY, "/ ~~N tktfflt DlIrelill1!ll'l'J!'in!~furlPruJ!'gii'lg /1·2 -0 j IJllildsiA!Wp]i!IJg(iff~l!\\li'lt) .. ', .:' , . ": '-,' '----"'--':--:_/"'~',';(--:·>:·Y-··· ~. WelD Plii;gil!g lEl'lljgii~;ij~':~fjit'1!tp~;,~~~!,j~Jfttg~; (if Oliier.i!ialU J.!leooei) ~ml6j SSfJiipiiilgBvent )llfJ . ".", ..,~M\\i\%~JJi§.J~!~,~~P,~ip~'l®~rt~';'··;;i':;::,.· '.;, JIlHJijiiit"0ft"l.@._.".",../.~.-,,<tJ--:-. =_.= . .,.,.,-.. :7 ... ..,.." ,-,.", ,-; ;#J=(.~?31t) tf1, '8' &:e~ 7' .. Rooox PoUm!iui (E!I)-~'-J-._~ __ 1:+"~.J'r, !!/,h,':"'''',;' .\; 'p~\., ';',.,',' .. ' .62 "/G,;>fJ ±~liljjir ., fee..' '---,--,-..c-~:i-->::::...!<' nimbi! Pdtenliiii (Eh).....£-<~~ __ ~ __ ." , ." , Mlill! -([lID_water Dioor~a!ge 1Perll1l1!lt Dilfe: 1 U 7.tJii R,,,rjSID!1I: I GlOwml!warer M6lllt!tI~g Q~alilJl ft.JlSmBIlCe lI'lrui (QIllP'.) Pag€) ~·I "r 4I! 1)~idR~ ________ Thrij~ity,; .• ··~ " i:' NUIllliJer of cBsmg v<lliifd&iieviiCiii!i~dtif~il\er'ihiimlWo)",;;"", ;,==--"-"7'""-'-----'--"--- IDf 'Well eVllclJl)lted to dryness, !lilmiJei"'ofl;l~l,iii& l>V~~~t'1i~'f~""';""'" ,-"",'-,-' '-"-__ --'--~_-'--'-'_'__'_ Nome of Certified Annlyliooi Lah!ll1lkitYifiJiil.;f:ttijll!~~iwLail&L·· ,""i23-",,-",=-'-=~~_. '-"/'.:..' "~. ' .. ".' . y " : .. -, .. ' ~ MiHH -1i];@muilW!1iO!' lLliM;ullr/l'll jp~il1l!il ilJimo.OOWaieJr MOll1!imiig l(ltmIitJl .iI»&1eUOO li'lIlllil (1Qil1l') A'll"JI'A<CJlIl!I1lJERflr .ll mHlll'll'JE lM1IE§A l!JliIl&.NlI!UlMl JMllrK..lL Thlte: 2.25.11Yl iRevisiuml: 2 J)escrUjlOOm {If SllmmAi=~::;-'Jl'~%~~~:nR«J)lURJ1l)J VifAJrJEJR LocaliM(weJl'~&m] '1hN~ 3;'li;~I'Jl~fit{",de;'j1J1'J+N ~ff1t Daleoo!ll'ii'ill1efl)lll'mgiID!g 1(201 lIIrui~!>i~J!Pling(ifdliffumilit} '&A '"'' , :" ,,' Weil H'Qlig JE'llm~:frkl~'~t~~'~;j~~~~;h'I~Ihii~;~if Oili~rl!iUIi~ei!!lel)/;rumf '6J SaW!IP!iiD~ lE!voot ,A41p4 ", '" ' ~%l\~$!li§~Jrj!!lt~j!l.~*~~~wgilE.,Vf~t:.", "I' ':i, '. ' ""i, '\,' ; "12 : ,-. .'. ' .. \ .. ". " .. ~. :'; " ~" .. ' " .' Mill-lGra_wnl<:!" 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WN' f ..e .. !iX-I JB;iiffer 7.0 1 0 if'Jl!J~~#.1;~;,,~~·;;! ~.·;lI:4. :,;',;<':" "', Specific COlJd"C,lDce .111 uMft.J'oS(~iI1 i .::rrf"t,ip.~~~:';:;i;:",;;;ld~':?"~"r"'" ' ',-. 'j-' 'I'tlrbjdity _________ _ 1'e!ilperatwJ~ __ --:_"",, ___ _ otential (Eh)'--__ =-__ --~ (':" " , ... ~. "_. 1\ .. ~' ',' , , " ~, r\11ill-lGlOOmwarer Disc!tarll"lP'er~i Date: H.l7.06 JRevisEmn: I OroUi1!llWll~ l1ifooifOrilig Q~. ilBsmllce IPloo (QA!!') 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(QiPill') l.lAiI!lLlL G1lt(jJ)1IJl\JIDl 'W &:J!'U "', !, . , RIllI!lii POteiitjii! '(EI!)~2~·of-1<"---_"""';:- iI!1iI!I-Gm_wo!erDisc~"rgeJhrimit J!)&!e: H.l7.1/6 W..eVi6ion: I fuouwlW!l~ lMi!fllitorilng IJi'Yll!i\jl AilSI!I"SIiOO li'Il!'ill (QAJI'} . Flow lRate (Q!), ill gJPlil. ~ 8/00= ~'" .. ' .. • .'" .. -" ;" y,-",--":,:",-~,,\.(\j' , .• J!f well 6Vacuated (0 iIrylres., numberlif!l~I!.9~MV3.C~",~~~}I"";;.~+:,;.,,,· "'-'-"'--~-'-'-__ .:..' .c-. .:..' '!.C'':'''_ Nome Ilf Certified AnalytioailL. abtJlri!ll)t.l'if~@~,!,\],IOC~ . ~ .. 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" .. \.. :.; ., . ~, 2/11 ,',: 4356782224 International uranium ( Mil! -lGroi!il1dlWl!iet DiBoll""!!,, i1'§'0l!li! Gi1JDlkfllehwooiwlim!g Qwlliy fo"B~P!ml (QAll') " '._ l:!S):,):;:~_\ :". i.'_;'~/\ __ ~, J!')'OI!i!iPi~'J!tate'Calcilliiii°1!i '-"L--' IDoIll: U.H7.iMi liIevi.iOlil: 1 12:12:31 p_m. 12-22-2009 3/11 ( '" ". ~, '-.,.-,;,-i\' -'-." 10\6\\ l)(.p1J..", " .. r!>!:' FT Mi!O -liJrolilln<!!Wllne.r HJl;g~W" Jl'0Iiii!M1 ~W8!eE llilO>il!i!()Ili.,g Qw!illily AsSM..'IlltCfO lP'lilYil (QlAll') _;'i .. ' :. . " /' . HJlllle an!ll Time fur Jl>u!rgUIi!g ]1-L\ .~ oq IIllid S~njw,g (if!lliffeJ[ellt},_kM~)'-"ll-,--;, __ _ Well li"tlrg8iJg lBfJ1iJil~ :1tt~:'iS&~~p~i '. 'kiJ(;;;!j:w~!~ft; {if (lillerJilmllJaerutGi) {.1litm! 'fir SlliIII\'jiJialg lBvemJl ;r;f/r4. '. ..' .. n,~¥fI~~iji~~lltt~~~,~~1jI)I111i~~lt!Y¢JjPi'~":. pHJlll~7.1!).----;: .. ;;-, ... ,-LL.,-=,-,,<a,--:: .. :cc-.• ",-" .= ... ="" . ', pI}:l-:=-,-,:,-:~~~:--....:...:.:::.....l....C..-'--- R d'otlln!iilB (Eh)----¥-I ...... I{{W6ft Pd~litiiii (Eb), __ -:-o;:"---c_""'::", lurb ~L ,--.: '. , .,' ,> ... ;; . { ": \. '.; .j I l\IlJl!-tG~water]j)is!:!Ja~ge~IDilit JlJl&!e: H.I1.@6 1l:GvnGiwID<: I C:-roll!ill!~ l\OOnitThfMlg Qmiliiy ft.JlsMrI.ll1OOPian (Q-AJ1') Page 4B 1If4l1 Th-rbilBilj( ____________ Mi!2l'~(~ V!li1Vl1OO IlfWIl!er lP'!!rged WlielillFielil!Pmr~rB ~roM~~~;oo,_--!:' k:c..b"'-_____ .,- 1l'J!!!JwiuiRi!!e c~I~IiIi~ :: ~e {~ ilIlgpm.,fo , '.', ~ .. ' - .', , , ~.\' .,-., NiIIIllliler of Cllililig voluiiiil8eVi1clifliwri tiflillief!itfJ'n'two), .. i?..c"c.." =",-,,v"'/'-!,'ll'-r-_-'-_-'-=_ «well elll!lll1lll~d 1:0 dryness, l1i1mberof gilii~rii. ~\rii~1J;i#?~,,"'ii,,"C ,,"'",,"-'""~--,-____ ,-,..c..c_ Name of Certified AlIlI!yticai lLab()p1lotyifQ.t4~r:W«~~~f4ilvt'aii~' )/.'\ •. """" . " .,.,-, .' -<,-. .. Mi@ -C __ m!llwBi<e;" iiJ~.C!!Il!19" li'mml G-rlmrulW8ier MOl1lilMilg QuoliiY AS9M,"llCe lP'l!lll! (QP,Jp) AnAteJ!lIllAllEN'lf'R 'li&i1lillI'll'1E l1AllEL\\.4. l[i~~ lMIll1L.lL . . . ~ IDJA'Jr~»jC»lW~Jb.~.,.ro;,!~. IGIIRI1J)l@JlD!WUU DereripillWlll of §!IIIJJ!,llnig 1!W©1I!':'-f.1'ilJJ~,..1ot",,,,,'h/t""-44f'-.... Cf1,4."l'.fdj~ .. ""d,""fi"-______ ---,,----:- WcalilJlR(welnniliit,j] -rWN n'ili;t~l~JiiJt~f;~M4"J "'AI /lJ.rff/t Date a!I!!liTiOile Ifor JllMrgiJJg -IJ-1..\-at( aliI< §;iflillplilJ/l (if o1iff~llt), ol,lkr ' ',e, . ' .. ' '. . Welfi ~g Jf1qilfi~'tiT~'.(~~;~~'~·'~iill~;f:'!t~Jitjt;(if Ol1!:ertliUnl'f]~WleI).6Iufti '6J' . SllIIilpiingJil""IJ' ;JItf.4 "" ... "" .~Mi\lW~Yj~.~\i\!lijM:ijJP).ip$;JB"Vf!l!tif!¥!.'il'; 1,7 R;.,,' DiUvlfter'7Al 1= () .. ",' . ~4.i~·~~~~~~0; ' .. '-.,. "'-;-. ,. , ;':p;II'" ... Tempe'~ .. , _____ ~W!..:..u:.L-.._ 'i'eJll'jj'! :' R Olt Potentia! (il\l) __ L-"lJ.:~'ls,--~_ l'tcll\'lll POt;fuliiii (Ell)_·-,-I-\..:.:t-,-7_~_--">. ___ '!urb ~. £::~::::;~~k:,==---_..:..-TII-( b _J.. Cl5~ .' ,::...--- ,,' ., MfiiIII-IGi®wmIlW&!e!" JilJiscI!m1jelI't'l!1mmi! Date: H.R7.4l\J ReViisioll: I llioullil1* Mo1Ditormg Q~ AnS!lf1lJtre ll'im (1QIlP) ll'age 41 of 4R Th«bi!li!y ~ Midliy,'" .,------- .. -. "" , P,''''pil1ri Rilte CUlCfllmlioll , ,-'. - '-". NUlmbe~ of casmg voil.iililiSilV"jiifni"i\ted(ll"6iffiif~~niWtl)",·~".c:::~,-. '-" Ce' ~-"-~ __ ,",,",_'--"-'-'-~ if weU evoollated to dryness, IllI!l!!lilOi'of MMii~eihitWit.y~",1,,,,i'~' =-C=~~-'-__ -'---'-_ NIIlOO of Certified Aoalylical LaiKlx~roi'.Vifi:ii4~fT!lltJ\¥«~k~y.Jtli.jj~"-·,, -"'"~,~",.,:...o,-.-, •. ,,,, _~'-..-. '_"_".,-,,-,-.' "'. . .'.: ~ '.' If a presenflrtive iSCilii~ii; ~i!ft\il~rvftlivk !-'. ~: . /Wi1B -([JrouiMll!lIfllier 1/Jii'c!';!l'g<>P .. -mil ([Jrownl4ilWlliO!>J M€liIIilllring <Qulilll)l A&&!lKmce lP'!ml (1QI<'lll') LiI'lr'JI'lMC1!I!lM!lEN'li' n WYm'1l'JE J.MlIUlLil ~ OOH..lL DescriptilMl Of£ijiW1fi:!::~'1l'WJrff~':Jreqp[IDJl.!D WM'1l'Ellt lLAWsiiol!(weiHnnB) .. T~)A) 16 "'i!!J_tlf~~it6~Yi",w~"J~diJI tJ,d. lI>lI!eaOOJ'l!'!iillJefQrll'w.Nil!g Il·,:;>,-d[ IlWlIS~IiiJllllig{ifdi~l!lt} ,'" , "." we!n lPm'giilg lB~iii~:ijii&\~h~;~;'~I~:{,~'itW~;(if otlner @J1lIl~eooet) 6tM1t/J Sa!ll1(JliRig BVMi ;1Ii~4 ',.. ,n'$gl\~f!i}§~~l~",§ijW~~i1!$'!I1.~~)it'i "',i.;;;" ',;: pHJiiliifferUj,--"" .. ,.".,-L,-~'---,~~~ " .: . ,- '. -T.~ • ,,' , llfMIH -l1Ji:ll>wliJlilWllrer Dlsc!i'[ge iPl:rniil IJrowlll!iilll~ lYAGllitoring Qtoj)~ A8sMrrutee ~ (QAJ!') '. "" ."., . a preservative is"iilicij; Sp!llliIY/~i'P!H!~~, . Q~titY ljf}'feseflilitive: . -;-~' Il&iII -G'a"fkrilwaiiJ;' )j)J",cl1!~'1>" J!l\>wJJlil Or,;;~.ruIWIli@!1lMI!l!JiiI!Jffug I(!,,~liity A6~!lrIl">Ge Jl>la!Ji (QlA11') AH1MC1llI!WIlWlr 11 W!IlHlll'll'lE ~Jl, 1f.lmIllN1llDJMI MILl!. lfIow: 2,25.W Revi.ffiEl::2 W!!IEJLID) llllA'll'4 )Vj1j1lJ1il?]1~~,t@)~ dill&.lDJ1UMD 'I!IJ Jl, 'lI'D DetlCuEf!J!illlil ([IfS~~lilig:!E1i~: flftrtAtif~d, ' , S,&/iif ' ' " ';1/J wmliolil (welninilii~)17AlAf. /1 0' "'f·~~~~'=~Ji.~~Jf;~ 1Mit' ,oJ. ~r'Ji MtIt ' Dale IlIilIii 'film for lI'«II!gillg 11·2.' Q 'l oolil S~g (iff liIifferellt) , ",' .', , " " '. ' Weli JPDJRgOmg ~ii~1it~~l,~t~~[""~Uii;i)':~JllJ~1~if oilier ¢Blum jineMet) /:itull! 'iiJ ' SllWipftUODg lflvern< lJ!/f4 ,,' .. " "~~;f~t~~Ul~t!~jt~ijR1,~$P~Wg)~V~~'" 11"::"TW;-(,,{." i( JlH lBlill'fe,' '1.0 L. ar.l!iN~lt~~;~~~f,~~~;~,~,7Jf.~4c;!~\;~¥~:,,;,::·;,~ ." " --'--;- " i ~. - , .. ', . i .. ' -, ( '.' , , " ~." ... ',' .. ' Mi~ -lGlrillilll!ll!Jllll!el JIliIJclmrge Pertllilli! JIJI!lte: H.l7.1l\$ ](eviIlioJl: I llg/lllJl!i!wm..r Mollir.oring Qi~.llliiy JiBsWlfanoo 1l'lfAil (QAiP') 'l[oiUl-"me@fWIlIeKPm-gedlTifJJen FieRd l!'~!"I!ille!eIrll ai'e Me~~lIi"ed,--_~<-..!.I ..... ,,,,C,,-____ _ .) ",'. ";"'- • ,i -.; .-~ N@iIIlilerofc3sillgvOIlliiii&eitJiCMied{lfljilief,IMiI"tWil)1:':0C'!."i,,--,,-, ,,"," '..:.:c.,,-:-_"---'-_-'--'-~ lffwell eVIIClIIated to dryneoo, nnmbel'of g~ijii~ l:l{la"~~~~.1!'ii"":'"-,, ",".'., '-"-'_"'--'-__ -'--'-'_ . '~'! .... . ::t·'· . -,--, ---. -' '-~. -' . If 11 priiHeryative ~'iiliiill; S1,"'itY;'!YJl'f1!Wi. ,.' 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TeD1~l'lI!\l¢, j /,2 :$" .... ~~;i;'~l~~\i"~~l!2~k .' -'" te/.ilj1ei'at!tfe;,;·····"'··::..'· ----'~-'------ R OK Potential (illi) __ ..c...,..... __ _ " ~' :'; ., / MiiIII-GJiOOl'illlVI!!!el )L)JiSlJ~ru:ge lPe.rlWit {Jromo1W&~ Momtormg Q~llIity AusOlI1Iilre1l'l1M (QAJ!» ~idilllY. ________ _ .. ,;-,_ ·,"i.' VOIWTille ofWnlel' !"urged Wilen lField PIII[IJIiI!Ctel'1l ni:e Me'@l!He&!_~' ... ~{2~===~-:-__ ... :.... // . ".' .. :. -".,'. -;,-.. ""-"';'\'."': If well evacooted to dryness, Dumber of.,glil!ilIiS eviicil1i(ilj!",:i'."oo,": ",. cc· .""----"'''-.. ..;..-'._. ___ -'-'=_ Name of Certified Analytical Laboratm:Yifq~lt\f:rllill11ft~§y LiiM!i<j',-;';':':::' ::::::=.c. :..c,J' \:.. •. ~~' If a preservative ~flisea, ci.flrr~W~aii~~: ' llIIilB -(lroOllOOlwater lOi,clill>~ l!'OOT~n! OroMOOWBteIi M!lAHl!l!ring QuaUiiJl AeelJi'lliiCe ii'ililtl «(1M') A 'lf1l'.&C1HIlMllEtW II WUlHIll'll'lE ~ 1l.iJIMM1m R&IJ1I,IL DeSCKi~oo~ms~:!~~r}l~~~~:f~lIDJJ~! Wc~tnon (wilnniJiJ_] 'B'a 2'\!ii~~'1~Ji~iii~:'·~~'~;;e. , '/;. .. 1D1llie lim!l TIilJJIenfor JP'lln"l!Jimlg IWlI $lJlIiill'lil!lg (if di!feJreBlt) J1j. ;r7."ho/ ' '. -:",.., -. if l/'·~.\);1':·~t:/:---~:;.ji>----'-::, f.;:-)1;~>;h,~ttiW!J,~~~i'.1f:·;···'-·: Well ~g Eqrujp>1Uliillll: Jilililp OF .){iiil~eli; W;~'i;lifiinirnp (if ()~~r l»IaiR B.ruie~) ___ _ sa)liiPiing'lEVeil',,-:.-f;li,,-,"+,m'!i'~u,.~. ,~" --;-.,....,~...."...".. ,!Pt~ip~~~UL~Wjil~~;~;~.pJi"~J!.J.'!!Jl!i,i",.:" "i:: ' Il'l'l! Biiffu,. 7.®,_-=..,tL.7--~(}'---=oc-::-= ?l!!M~~~~~;n;~~;.:;;.:~~~,a·;:;:;,;i::;/'!"'.':~ i "i spooifie COlldlichinre" .1f 8' allvm:OS[G~i;fw:~~~~W~~;~{:',;:!\;~{':~{~::!,~~it":';,\j",, Telllpera)J'~ "~ ____ :-"';:-_---:-__ _ OK Potentia! {lElil) ___ ~ __ _ " PiltOOtiiil(E!i) __ ---=...,..... __ _ C"'" ... ~ .' " \,' '.' . , ., ~/ :::::--.' MU!l-([lmiIDi!liwaler Di5CilB!l!!' ll'ilii'OOt l1rou!llrl!~ M6llitorlilg Qlyi!liqr A'BQiC~ncell'lw {Q.4ll'} -.>..- ' ... ~ Flow Rate (Q), ill 811m. Date: U.17.1Mi lReVJiBio!i: I - -~ :. ']['fu:lEf~oClW!:rulate aW<I "osing vollll!Ws (2V) 8/60= '--__ -===~ 'f=!JlVlQ=:···· . ~'. Nilililber <If casing volilliits evlW\ialed (iIf'litl!1!I'thiiil (Wti)t.;·':..:; ':..:' -'--.!':=.==--_-'--'.c....:'=c...c... ][f well evacuatCd to dryness, n_ber ofglijio$ ei'ia8jj1iI#1~!;:'.'~!'..;·:":· .~=='--___ -'---='-- j.~ . -'; .~ .... Mm -Groooliilnl>lre;-Jll~'.l!BJi)le POJ'um! IGmuruiW!lWir Mo;-,i!oring D!JI0: 2.2SJJ7 JRevisiOb!: 2 QumHJiy Ass!If(oore Jl'la~ (IQ!A!!') A'll''II'ACJ.!lIM!EN'1l' u WY1HIll'lriE ~A 1IIJR\&!\iliiI1M 00!lU Degc.m'OfSn~I:~:!~'II'tfe~1U~~~J'12t! WcIl!HolD (well~l iJieif .. 1 d·j;~'~~~~Ji~Mif~·~d'·>~ek. .' Dale a~!II Tim~ for li'nrging ~!M! Slii!'»plIioog {if !IIifferellt} LIl· Z 0/. '81 f !( :-./ ,.'.:;\~) .: .. / ;':.{;.:----. :,.:::: :~:;r" -·:):t~~~;i:tfd~j~rt'·· '-. Weil ~ 1I:1quip 1[JOOiJJ:~!uiiip IlJr _UiliiUeJt '. W,~,I!p~~nIlP (iff other 1I1HnlJillellmlet)--c-__ _ ~."!. ... . Sa!llllJ)JiilgBvelllt t!il!id[ .. .... R[e,~~;~~A~i§~JlI.i\i;!J~~~Wj1'i9&'lJhrgl1t"".,,",,, *"" JIlEIJ!i!ffe,. U) 1. () Spooific Condltft~ce 1fr! '-." .. R 0]( PotentiaD {Eb),--_~,<-__ ", .",.,- .' MNiJ-GillllOO1lllwater JDiscbm,ge P!lA1i1!!l1 GrllUruil'l1lWf MOnitolWg QrualiIY Assmnre pjM (QIlli') 'WJI'I)idlily _______ _ Flow llWe (Q), Bill p. S(OO" "'. __ ~ _ _'__'._.~ .. l'iilfle'tc 6'11iACiliale ~o CBSfi!lg Wlliill6B (2V) 1'=·2V'iQ ';""",- 'f : y If a preservative iliisea, d::frtllf.iVhliJ~: . , , Mi!~ -!:ilroW!<llWllre, Dw.cln",1¥'ll'",..O\ 6rotQomw~iIlr MooilOO'iJiIg IQmlliljl AMQIl"IlIIG" ll'i1ill1l (!(PM) A'lI''lI'ACJlllllhllEN.iI' n W1HI!l'lI'iE l¥llE§A WANlllUM MlllLlL [l1!ie; 2,25.@7 JRevisionl: 2 J1i'iiIEJ1ID) lIlJilI71'ilI if~rniHlJ~1@).\Ji!W)~ ~1lIDJllJ) !,t'1fjEM ~;r;:r&~_~~;$i~1.1 Ji)!1Ie fl!llll 'Jriilie fo. ll'uDrgiJlllg ~ruiI~!iliIpEi!lg (if Ii!ift'flKellt) M· 2,7:'"'& r'" , WeIR hnPg lE!qH!~il6ie~~\~b~p~i 'kKW/!:~li~~~~; c;r o\herl!Ja~ Bewet) &;~;dLk . SllIiiJliiiRjglHve!lt tlffrrlt.:.. ., .. ,r~$M.I·~~.Uj§~fii~~;l~,.~~/1!iR'ilitflt,lY¢!W:"Ij{1: '"." =~Z;( ~i';=~~:!;::' ' .. - - --,-; ;~~~_ Oal. x>urgcliI!_~,.L._ "--, , • ,,-r 0 'J:I,... __ ~~-"---...:....c .. ,,,".;.,",,' ~""-+;:: 'pH Teljlperailile.'3'''''<'·::'' -..C;.....:.....::s,..----~- .It OJ[ Potenlial (Eb), __ ~", __ _ Itt "'". Potelitii1l"(Eh), ___ ~~ __ _ «: .. . " i ,-",,' .-' .' ~. ',; .. . , / J . , WJiII! -IGKollmwaw lIlisooll[ge P",mit 6romwarerMollitooog Date: H.17.!Mi lIleviuiof" I Qoolity AIlsnJrlll100 lPllln (QA.1i') 'll'wbillin.y. ________ _ J'l!lIII!ing Rate CalciJIaliOIi '; , " ,,~ .. Flow Rale (Q), in gpi.'J['itHJ~'t<! ~Vai::MaIe two cosOng VQ!un,tes {2V~ S/6f}~ ='--_~--'---'-'--' "~ ''f;';.2'V1Q;,;'''' ' ' "',', .. '. -, - --. , --'0" ~'--~ '.' ,-,',;,~".\ ¥.:;,~'--,", . If well evacuated to dryness, Illlmherofgill!illiB e';aCil~~.~\.i'""",i "-',;...' '--'-""--'_-'-__ -'--"'..;'''.''--_ Name of Cel1ified Analyticnl LaboKlltoiyif{lili';f~!~~gyL!lii~,'" .. _·,-",;..;,,_, -c;;'C-",-,--".' ,'-,:_'-,-_ . -.'-. If II preservative ji'1iBea, ~ftiW~l'Vatl,fu: MilD -/]roillIMllwn1!er Ji}jsdmlli&' li'MiIli! IGrO~ilIl'wllll'.J" ruIoli1ljwrnilg Qullility Ass~ruucelPloo (QAl!') A'Jl'Jl'M:!Jl!!lli1!!ElW ] WUl!IDl'lI'lE lWilWA 1I.J1M,.l\Jll\IJ.M MILIL JJi'.iIDU) 1IllA'1l'4 »,9JllRl)trn~WlRl.IGl~([)UNlID w &'lI'lE~ J!)escripeiorru of Saiim;piiiigJBveM!: 1VYfrt4L~G . lWcIitioo(weli~). TvJN QW~~I~di~itiiJ~1iW U~!j~~,J tJtd Date alllol 'ri9llfle fllf Il'mgil!g II ~t.\ -oq al1ld 5l~plil1g (if different) t/' IN .' "! . WeI! 'U~g EIJlU!~:i!1~?!£~~~oLJjffii~~'jfj}l~:~~ {if olhertHluiR BeMet)6IUIvi 'tiJ Sampling lElvernt ;f!i"lrai;, . 1P'~}!;i\Ml~Jf~~.11!!jl;t,j!!.~~Il'ilJ~~I~5T\!lJ:HI1 K, " =.,:...., jtt~. "'~;~!~:~~:::::'" Turbi~ity.~--,-______ _ -.... , - --""', .. !"",~.-.,.,--' .. ' _. " ("''' ," i ..... " ~. :.; " -' . -',' '-, -'. Mil! -G,llUDllwl1let lIlisdmrgeiI'eriii!i1 Q3r0uOOWIlWi Mollitorfug Qwill\JI ABsllnnceJ!>Joo (QA!i') Vo!DJl!'JiB of 'Water Purged When Field Pa[lliIJeters ai'6 Melllll!fGd~_---,q,-"b"--____ _ .; •• :.-, "0>", 'Eime.ro ilvooUlllte awn casing vnllJl!IDs (2V) T=2VJQ="'!f. " " ,,', Nmnber nf calling vol"~ilevacWlti:!I!(il'dtlieilliiiiil tWo)-,-"--""~' --'-'-'-'-.--.c-, _____ .:-.:-_ Jfwell evoo~ 10 dryness, number of galiOll~ e\la:diii~lI15"i'i,-, ''-''_~=--______ _ Nmme of Certified Analytical Lnboraloryif q!hii'ilf~"E~gy vi\is,-'-:'''"",'' _' =''-'' __ -'-o----'-'-'~ ". y .. '., If a preservative is'iliad; Specify:fYJ.l!f,1md.,. , ", Quantity tifP\iSetVative: '" -:-'-'-'-'. '" Mill-Grobf>illw~Rrei' j))~""!!a'H" 1?emlil I[Jrmm;!\IlI8w M"niroring QuaHiIY AU&!1lfOl!ce ll'!u;! (1QIA.1J') AR1MClHlll4!!EN1l' II ViflliIljD llAIlE§A [lJUNJrtu.M MJJJLlL J!i'JlJEI[,lIDlID&1l'& W«1l#§J1mEIE'EIDollR«illlRjI]lliJRilID 'W~'lliEllR 1!>escriJlltiO!ll of SMiplllmigJavm!: 1ft. fItuiiiJ'":(14'ifa& @ dtMlttiie lLo!;lliiOii (weJ!iniiiOO]7j.IN -11"'ii~'!~UJ jfuit~I{~~'lUeL,~f Dllie ~H111 TiiTli!e for lPiirgmg ZlillllSiifillplillg (if lIirrerellt). If; , 21/'//1'/ Well Jl'mgfug I!lq!in~ 1uie&;~if~~i .Jila~/~~';f~f{~~ (Of ollaer Iilaua BeMG0b:ttf/J&) fi:; iff" It ,," ",', ., ",', "'" A nil Saoilpii!iglEiVeiili ~/h ," """',, ,Ji>f~~f~~A~!~~~~l#~,i~,~~~~~illg'~'/ll!it,'i;(Vl, pH llIiiffilw 7.o'~c:=J.17,~ ""()--c:"='c=-".,-,Plg;~jtt~h11~~~;;·::,±~;Id,,;~,f;';;:'~'?;""""""~ , Specific Conilllci:m~e ,1ft IlMlJ[OS{\li)/1 ";ii!l!r~Ml~s.~:\~::f~1~7:;~:':;'~":'''''i';;'''", ,,' ", _~ __ , Gal.,purged~~,..,.,~,_ R OJ! Potellltian(i3h),--~_~ __ _ lr~ " • poteiltilil(lElh) __ ~~ __ _ ~ - C";.' " i ' .. ' .' 0, f :', \ " ....... ' .. ' J W -(l,oillllil!lwnOOr DklclJ&ige lP'.atIillit Orouwl!WIli.,r Moruooring IQiilllity A6ilw!lIIoo 1l'lm~ (QAli') 'fuWidilY. _______ _ l'tImallilig Rate Calc!!latioo Jf1iII>W Rate (Q), in fWIlI. S/oo= "''--__ ~'''''. =' --'.,_. ',-," ',,-" ------Nu9BibDf I>f calling voltlili&evliCtiilliid(ltdilierthan 'w,iI};.."'_'''',-''----'-'-:-______ , '-,"'~" '_ JJfweli evacuated to drynes., illil1Ilber I>fog;ljioti evDPufi~~"':f''''', ,c,,' ~"-_----~ ___ "_"_-"."" ''-- NI!IJI" ofCertffied Annlytical Laboratoty:if,p4,~!jfli!ili'~4~y Laii~ . " .,~ '"-.,:!-.. , . •• , 0"". If a preseB;Vlltive is'iiseil, S.l!~H.YJ)Q1~~~, "", ", QlIili1iityof~f."tive:· Miin -GttulW!ld!iIN(Olif lJi'sclll~rge JPB.l1imt I[lwoool!~,m"", l\4l!liiliiWIimg Qmliij!' Aug1O!"1mOO 1Pb (QAP) iilnA<C~l! WlHIIl'll'JE lMW§A llmANlIfUll.6I IVAI!.. . . ,~IT» ll»iiI~UU{[D~)fcimnE.'·.ru;.}Jltl .. '.lh1,.' i13l ..•• !lR ... ~. 1G~([J)lfIDllID WA 'If.mm . Jl)es~ of S!il1!lnJll11Dig E1IollIili: 1J!1l1f/A!ff... i$(J!/r{ti4G . , lLucatRoo (we!Oin~m) 1"WN ~ 2/2.. "!I!t"I&~i&~r~14Ii; 1M,. ',i· ~tLN tJtd . ;'-' --" ',: ','", ' . Dale oo!il 'l!'limme for J!'Mrgililg lllMl ~li~linJg (if !iliffe~tl.~ __ ...,..... __ _ Wela ll'ilJgil1g ~ilib'i6~;;~~~'~f'~~~ir'~fJ1j'~'~; (if o!l,teI~on ]!Beooet) 6/ir;,! '6s S1llilJiifOODglE1looi /1//1,4 .".,. ,rg~i(~~~JJi~~1Jjl»tWiilt~~lWwJ1Jy@ji.F"'·!{"'· . . """ jII-Hl1iffer 7.0,-. -::-:;:--LL.,.,-'-. .><:()---".=.,. ,,,.,.., .. ,,-;:. "-,..,, ,,',. :, \\ RedDx Potential (E1i) ____ -'.;: ~: .' . , . .-' .. ' li!li!l-I!]rollllidwnle;r Di8c!Jarge1E'~Eilllllit G:wwdlwaieff Morulxlriog QIIllli1,v JlJlBWifsiWIOJP1M {QAP} VoiWlmJlle of Wale!" Pru:gOO! Villren lField JI>~I'!Il!'Ietem are ~~dL...." _______ --,- ,.;,: .. . ;'." ~~!eca~lJim1i~1I . ',. }.: -,. "-', ~::~(~liigpmm·fo, ']['~'~51Y:li~~~!eawo OIDSillg1l0!llI!lOO (2'11) ,<I' =: 2V/Qi ",,">"', ' '" "," ;" • .: -'. _"'~ _i~·L_,.~i".r,j,·~·W-· . lff \IIIell eVI!Cl!ated (0 Ikynens. Il!.lllillbID;<ofg~llqIiB ~\fo!Cu.~!l1ili",r'.t;,;':,';c':"""'='--~---' __ -'-"'-'-'-_ Name oeCertified Arutly!iiclliLnl:loraloilrifll>ih, " . ,-," '';''--'.1 " .. ',-", .. ., ',. ---; MiruJ -!Jro.mnl'''B"" Jl>iHcIIR!{le ll'elli1>iC IGIDWJOi!iJ'/,1/FA" l\1kl.'Diiu¥ioj; lQooIiily A9S~I"Il!tOO ll'iIllll (QAW) ~jjM;~~;m;; Descrijliiillli lUi ,S!Jru~flilliJ!lig1B1Iiiiliii:~lfJUrm~~H(:!1, lLIlcaliOiI ('!IlIiilftim~_r1tJAf-. '} r Welllll"!%pg illl]li!il&"'H: ,J,"': "'XfpriMiiiloo IIJr,_lilalifilr ,,& .. ","." @!arm ~e~eI;) 6i'Ud m S81U1jiIDiU$)EVOOl,,;t/!,.,.: :c",f,J,%'!f,iMl"" "', ... !<.. . ....,.,..",--~,--",...."', '. "R~t~~~~J~~j\l~~ijl!,.~~P,li,~~(1l!;Vi1iiF":'P;;' . "" ,i, pIir ~iiffeK 7.0,..,.-. -:: .. ,,,,," .. -,-:L.~,.l£O.,--::= . .,...,,,, .. = Templll'",o. .... ~. ____ ~......,.. __ • R OJ{ Potential (Eb) )j'{~(jii: Poren!iiil {Eh) _____ .......;:,'<::- .. ' .' ~ -:: . JVJJR! -IliiEIIUOOWil!er IDiru;1!~[ge IP\ermit o.tourullw!llM Mollir:om.g QiillIi.y A!;sWQl1lle Plan (QAJi') Page4hf41 Noomiler of Clluimg vlllillii&ei;ifufulled tiftiillef~aili'iWo)",'\"",':'"" ="'-'---"-c _____ "-"-'-_ lff well 6vacIlIated to dtyileJl8, niwber'of g~jii;lIlb '(!lifaal.1~~If~:.''''"'''''': "c.. "oc; ~_"::~=-'-"-'-' __ -,,-"--,--,--_ . If a preservative ij'iiBea; . S~\lI1ifjr,!Yll!f~ .... QiiiUiilw~fPfOOetVlttive: '." Mil! -Orom1MlwBIlli' Diwlo"'15e lPbimlmil G,"@OOJ!W~!I>T Moiilillrimg Qu&Hi!y foJl&lIra..re Jl'JJ!liJ (QM) -.1,-- .' .",:$j.l!1~t~r: " .. y.. . . '--'..JQ<I<J/....::....:.,ws. __ N!Ilniiii iilllil iiilitiliisLl!.~!:lL,~:f£!!:;~_1= Date llI!liI 'fOille fur JPmgiJrng anlil51ilWipBiiig (if dilfel\;llli) /O·g 8: ~? 'Well ll'vlrgilmg lEllJll!i~ 'uie;f ;'~hlIniioJr __ Uliiii~;"WJI!~~p (if otheR' ~a";l~el!llet>' G{lJfP:> SllIiiJ!ilOOlg]FlVClIi! ;1tM, 1f~ri0'lf~"!!l{ji~!.~~}~.~~11!I'!i.i!WijV~lli .tf!Jl:. lNN"./ pIll l!lli.lffel' 7,0 "1'.-0 !,g'~~~h1;~;~;;:';.;,;,~,~~~c«;;)";;;:.,,; .. '. ' Splllllfic CondIRcffiilce.?,?f ullffl:OS(cill .; 'lg~,ti:~~~Wll;:;;.'i:::::;·';"~::::;b;i";'''A' IDcpll! to Water Before h~giilg IlII!/- .-/- "",' " .-; , Rtliloi, Poien!iai (Ell) _______ _ , IZb:7 d· : " C':" " i " ' --.. " l' ',' , , " ./ iVlliIII-<1:lrol!oownte< IDillchlllll" l!"erm1t 43roilll!llwBter Mo!lllMng Date; H.17.116 !it€lvisioll; I QlillHlly AaSI!fallOO1!\1!l1!1 (lAP) I Thriliiribii:)l: ________ _ Flow llWe (IQ), in gpm. 13/00= '" '~--__ c:...:..._ ~----- 'lfw'iJi!!lty.:...' _-.C-'.. ______ _ 'Ji.'ima·~ 61/1lCl!UIe two casing voll!lllell (2V) T"'iVlQ··.. ' ... '.".", " .. - If II preservative iIJ"liliea. Sp'~ify Type and QuaIJ.titYQf~C;tV~iive: 4356782224 International uranium Mill-GIDWl!!!"",ior JllIj~ JPiel:mmil . IGm&m<lW!liOf MQl!iroring iQlnGtily A!9!!11ll!re11'f>m (QAP) ~" : - -"-,,-, v-.~rnmOf~:~~:~~~:;~~Cf!1~ ~alil)l!I ('ftldr~~~r·rINN -S" (t 10:35:35 a.m. 12-23-2009 ( DlOIe: 2.25.W ~evi!li.l1i: 2 ii'age 40 ~t'..t H F', 2/11 '.' 4356782224 International uranium ( Mill-GKfi_W>liPJ DiscOOrgel1'\;-fIii1!i! lGrooorl1~ MOOil!)lriflg QMly Aoo_Pla!i (Q.IlJl') ( ~td~~li~~"~'~H~." ..... 12-23-2009 VIlIuieIllfWaie!'lI'mgOOlWkIDJ)iI~i!llPlli'\l~ererm ~~'!ir~J \ ," ' "" Jt>_iif~v3;;~kmI!i ""'i-~;t,,\~11/!;\". ..~)i;~;~!t;,~,,; ". "-. .yo ;-, ]Flow Rare (Q). ira gj(Im. SJIID = '" -+'~~f64i.~~,'¥!:' '",f;:~ ":",",.-' B4 3/11 .-.... MiHH -iG-1i'RIJ!Mi1wlIler 1ll>iscl!flr@ll Jl>@JWJi1 l[1m~i1!iIwiI~ l\AfoJJillrttwihlg lJ!!!l!d~jf AIlmnli'al!C<l ~iil (QiM) &'11ll'&C11lIIMllENlI' ] WII1HIll'll'1E lMIlimA 1lm1hlWll1:MlM/L,lL D=rll!Hioo of&i!t~P!~~~e!~NTf~~.:l!t@1LJ1\jlID 'WAtU~ .' WcaidOiR (welH~&iIW]~lAIAf ~ , Ie '·').f~~'~J~~i~t{";;;IIoIl1,' J~~ Iftert IDalte IMiIIII 'Ji'iirme for lP'ruirgDJJilg . . (if dliffl![~JIlt},,--~_-;, __ _ (if ol!il~r &lID! ~eMel)6Iitmf 'tis -'~.". '. ' .. --. 'Weln ll'Eii'giJllg ElqDllb [r;:~?l~u~@ S~ijiDg It!Ve!il~'-I.M~.W.CL%'I'.~,,,,,,,,. '"-. -=,......,,,. ,,,,, .. -,.,'-. ",.. ,,~,tl<!"!%j!Mi~itlttt~i~~,~~!!1i!J$i1tN~'itY,!;,,;:, .. pH lHifir 7.1!l'_~/.~' ~L-,--::::.,.-:-;, .,.,-", .. -;-O"'~' , ~, , Redox Potenllili (Eh)'--___ "'<-~ Q,~?i , . ' ruoo -Ifjrmlilldlwator Jilliscl!.rge jp'!)KI1llli! frlOU!idIr~ lMiioiliro,rmg Qidl\ll AooP.Hr~RC<lll'laD (QAJl'} ------------tMi\j~lY:', ,,' ,',,~ . "::.' ":--', '. '-. ~R!ite Cabll&lioll :;: ~ (~ irmgPl1!.~ , '," ,~~i{\j~~~~~a~@ cooirmg VOIU~eS{2"Y NoombtlK of casmg voliii~eWC'iiiitii!l·({j:iiiilei'ih~n'tWo};" y" ' " .. , -'. -----'--'--' .. " .. "." J!f well evaclla~ to m'Yl1ess, nilmool'of g~iJ1i@l:\irill\~~~a",ii"",·, '",,".co".c.' ""---'_-'-__ ""--'--"'-- Name of CeIlified AlInlytiCoilLabIJK"lotjlil',~,~i\.bt.iW~~ijpr,·lLaii!i"'}/f.,\, ----------~....""" .. ".,,, ,--"-ry,:,.77'.,,.,-~,.------=, .. " 4356782224 International uranIum Mil! -[lro1L'Mlw.'er DiscBrllr1l" fumil Grom!I!IlI!!iEf MOllliroring Q..nily As._ FIll" (QlM) 10:37:42 a.m. 12-23-2009 4/11 c !kiIe: 2.25.W lRewi.i.,,::2 " 4356782224 International uranium c Mi!II-Itlr<llIllll!ilWllWl" l!lit;eIiorge~ ~~jjm!OK~ ~I.v ./lBsilfllllOO P/om (1IlJlH? 10:38:49 a.m. I " ~ 'i,'ii~-/};: ..... . TiD.«ilidi!y, ~ '» •. ~iIiJ;L,:),i.~ .. " VoliMlIOO «IfW_ ~ 'WII511, Fi~ld ~~8 ruil~~~~ ,,~.,\ '- ,._·~·:!o;~1:;;\';~{;~~'::;~'~J.t;·::~.;.~~t :.4.~.;i. ;.~,:[\,{~,:-.:i:rl·~<~~~~~· :::.'~) ·.~·:~~~!9,'Jih'<!:'·'· lP'oo!r!!ilIil:1fI,~te CIiIc@lmijoli . . . -' , . " " .-. < Jl1low ][We {~ in I!JIIlil. Wdl@= --------~~~~~~~~~~~~7"~'·~"~f~,· '[2,:"swe t q 12-23-2009 5111 , . ." ';' ',., , Mir! -1k"ilR!l!!WI>ier mumrgeJPellfmt iGrown<ilwBWlr Mmmn!JWing Ql!oUJ!jf AusI!I(arn:" 1l'imil! ((liM') A 1]' AICJll!!¥I!lffiJ'1 n WI!JlIJJI1l'JE ~4IlrjJM.l~illl!JlM! lWITLlL JFilJElLIID lIDA'1l'p!. Jl.!'j1J)_Jb'!Jij:W,y~JlR GJlRI1})1lJM]l 'W A'1l'IE~ DewripiHIIfIII of §:Mtmpiillig 18'!1ennl: 1V'I1Jr4t. if?iillJlAd.u . . lLooaIHoiU(well®iJWlelTklA( ~ 8'&"'ti~~$tl~i;;l.i;lK.14ddt; 1M.,") ~~'" tJ,ffIt Dll!U!4J'Jl1imeforll'MrgilBg II, ;r.d? _&@iJ[Ji~Oig(ifd!iffeat} .'" ." ' Well PMIJiOg Bqji!i;:i&~~';)a;~~olt '~~~;i!WA~t~~;(if Oil,'eR'!fri.UUJf>emei)~tUtJi In Samjjlni~B'!Iei!i ./Iltlrr.J .' ,,~\i;g~~~!Ii~¥~~~~iiJ.t~'i#.lPAi,,~),f}it!lI!~>'·',~';": . ' .. ;,' IPHlBliiffur7.@,---:.7.:' •. ,-,L.7-"-'-tJ",--"", ... ".,,... = .... _, ·1 .;:. Telhpll,illtl11,1h ".J'i: :3//, ' . ~~q;':;iii~i!ti)~*;7. " .. " Turbidity. fJ L{ " • -, -! - -.-~. ,~ ___ Gru .. Piifged,--_· ...,'-",._ . ~ \ 'pIl!'-.·' -'-c:,-.:.;...,,,...,=-"""":-----:-'--'.,.-- Redox Potentia! (Bb)'--___ ~ __ .' .' _ -([j~Wl!ter DiSG~ll!:ge ll'€!'mmit OrouOOl_lVlo1litori!llg QliliIily .I\llSUEfBncB li'llIl! (QlAli') If a prese1=Vlltive ia-cffiiiill; Sp~ify,1'Yll~1!wL ...... . QilairtitYi\fP~fifvative: --"- 4356782224 International uranium Mm -Gti®ILMllJ/lili"l iDJisc!imrge 1!'emnmi& . G!lliDIwaren-l\1lolliim"iog QuaH'ltJl A!lSiY.!OOi:'e ll'ItlJ! (QlW) .,--' c , .. .-., .. ':. ·7w;j·;1····· 10:39:50 a.m. 12-23-2009 6111 ,., .. "" ·L"~ " . "' 4356782224 International uranium I . 1Mlil! -~;WlmlWI DliclJargePlililIfi (lrowOlld~~ ~~P!mi(QM') Flow ~(Q), ~gpm. Sf 00", ( 10:40:59 a.m. 12-23-2009 7/11 ,_.-.,.,. ','- .... , .. -.~. 't; . 4356782224 International uranium MilD -G-ro~OOIW1l",,' Ji}D~il!"Jl'milil (Jr",.mliwo1.e;r Mol!UilX~h1g ~rJ/ All.",,,,,,,,, J!'lfu. (QA!1') 10:42:04 a.m. 12-23-2009 8/11 ( 4356782224 International uranium l\iI! -ItlmWiIllWOOlr IDil;"~Jl'emmii (lro_~~!!pmg QtlllIi!y MsPJli1l!!OO 1'100 (Q.Iili') villn_ iIIfW.!i!£el' J!'inJlged Wilelll FieR~ Ji'1il~!ml ,,' r," ... ~iJ~jEl~~~~ol' ,',):~", ;rt4\', f 1F1@\!I'~' (Q), i!U gpillil, 10:43:09 a.m. 12-23-2009 .,q. ..... ~ !' .... Sfalll= =-.8~~~~~'}#;: ..•. < .. . ' 0· .. , 9/11 ,:., 1\&.11-([Jro!ll!ll!warer lll!iool!Jlj,Wl' JPorr!lii ffioi!lllliiwaieJi M();um'lllg Qwlliiljl Ail8ID!lanre if'!ml {QAP} A'H'l1'LM:!i!I!lM!IlW'H' n ViIllHlll'1l'lE~'&' 1II1R1J}.RJlllliM l¥lIIU • • .' ~Uu;;U.1J)) Jlj)A1l'~»tJl~.~!lt@!)iWilk«JJlIIDlJjJ) Wi' AI 'H'lEm . ]}e§Cl'lJ~Ri)1D m Sammj;mlom!g E1Imt._/.JJJJ..w... .. N~""'""'-""I'($r. -+644:tJ"f/tL?!., 'I,A"11t..,¢""-----_---,-..,---,-:;- lL!JcIlliOIO (wellDi8>LNAI-1/ 1 'l!i~II~J1~i~i~~1fo,titI'j 14.· .. · Jil'4N ~d. . ~ -. ~ flA.lflJ-. rr~ Jl)llte mlll'Ji.'ime [i1r hrgillg /I. g. a r liIlJl!ll S~lPliJag {if diffell"elillt} . " , ..;, , .' 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'., . : ,. ~ . , Mlln -([lro~~t~tl/l!lier Disclla,~ lPL"Iro!'ilit iGr"lJoollImW M!lliillI<Nrixlg IIJlI&lilj< ji.S6~m!!re ll'11an (QJll!') lDeIlcl1ipru!OOiIof S'I iiimr~liDi.ii lE1iiiliit:_.J!I.'J:/Y,~~A lLIic&!ioo (well ~)._·---,f--,-\N,-,=N<-l""","""""' __ weil'Cia' of!;ierllRllII1lJ$GMet)bn;t?i nJ '. , S·~"',nM,'''' Evooi .M" ,%, ,~'" ", ' lP'tfj:viiiiteljlii;!~"";jg"!!:·IiSamiiJi,Eilnt.7:',·INII ",' i,' =''ll'" ".'''' '4-;...t.;'!f"'':"'\-~~== ;'" "-"'~iwfJ~N~.i'~~1J~~~T'r.W.-;;,~,~·,.;,,-r .. ,,~~,·)f''''''Ji~.,. ' pl1ii:l~@ifeE 'l.il,., "{ () ~,. 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BLt TWAJ 13 ";'".: .' .. , '. ,\ ~ l '·· . , " j '.' -' Miil! -I!]WIW~VJllter Jllloo!l§~ge lP\eliLlilt iliiropl!ll!W!lier MooiiOKflng QIIl'Ji\j! ABimro!!OO 1!'1oo (QA!!') RJi&!e: IU7.Ql6 ~1fiBioFC I ~bidn~ ~ fil~ii~~l~'\~."~ 'V61~f!IJI(liJlfW!lierPi!rgefll~' ,,-,j&J~ i, I bS/" ' -".\';" .;,,';!.: .\' ... :" •. CJ, ':l ,.'~~' . t -,,".:. :.~-J'.-t, _ ~:\ ~y..-'~~~.,:t' ': _.' -" -.J '~J.:~~'~:~?~:~,.\"" PMwmgRllie Cal!l!!!!!~iillii . - - ".'. ":~. ~ .' . :::~-:f::'~:t~:':·l-~_~l~~J,~;l{!;:.':., _ . ::~{~ i!w~~~',,~, _" ".". "~,;~~~r~~~~,~~~n~:~~:v;,I.~~8~2~,, -, -:' Nmilier <If "./liiig viiliiiit~!i:iWJfi!~)i!OO'i'(jii~ti!'fu'!~~iitWo))?if,\.,."", -::-., ", . 'i -' ,. " "",.:>,.-. -;".--! ;':-:':~;;~'.' '·:~'::::·::<.f<-. ri.·--. -_ "" -. fr;;[ 'fn~h 1~~~ \'~'- . 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NDlillbeK of c8smg "oY"iWseiticii~(ilf~ilii!i'iljliintWil},-"i~; .""-,,'-="'-""--, ____ -'-=-'--_ !If well evacua~d [0 drYlle8&.llil!lIlberlifg@,iiri~'Si)'''E~~i~~S'!I'''';''''''''''''~'--___ --..c ___ ,-,-,--_ ,.' . . : : ' y If a preservative itfiiBeti,· Sj.1\l£Jfy,'!)e~!m,t., ...... . QIiil\ttiW ~f$elVlitive: .-:-,.' " MiDH -I!1;;;)U!lIllw.1!fIi( }j))iscbm~ ])'em! (lm_wal!fli( M!>!!lltniii!lg !(!®!!IiilJl A9SUJrILf!re ll'lll.1 (Q!!l!') ATIA~.ll 'lJ!Il1IJJf.lI' ~A 1Il1R\A~lIIDllil OOillLlL ., .... ~lillN.IDJIDJ!l\lt?lf~Q. ,.\:m;~l& iGlIR([J)fUNlj)) Vif !l\'J!'Ell!. DescDiipalllDlilllflf SSI!IlIJPIIUilllg JEv@lIl: ~4t!lJ!jda . L0080011(weln~r'1\"I;J \1 R'j"'i~"~M~t~fs~ ~j1rtM fdjqd- Ji)/JIe an!Il'I Ti~e lior li"nlrgilllg ll-L\ .0'\ mm!ll s!il\Iipllnng (if cIIiffeKeilt), N/I\' ,.. " ... : , . Weln J!>MtWiDg lflfJlO!l~hl~t;~~~~o~' ""~:;~i~)t~1t; (if Oiller!fitOOl)mGnnGo6'tUru! 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F , MilI-lGi~wa[~")JJIis~!>arg@lI\eEmit Jri!!1e: H.17.!Mi 1liwiDi~iil: 1 (lrouwliwatet Mooirorililg QlllilllY A88Qlran"ePI~~ (QAli") P~ge 4hf 4!K Tuwidi!Y. _________ 1ruff~~~i~"' "~ 'VoilillOOlifWaierlPllrgelil 'ilIhe!!.J!1ielo1lPai"!lmerers are~l!I'iJdc--_______ _ ".' . . ,., '., :'.j- 1r~'fi4J' c;yru::1iIl1e dWII casillg lIol!IJ!Ws (2V) '" ", 'It' =iVi~i:"'.""\·"'"'I!./(-A :: "" "',; :' Nwnbof of casillg lIo1llltd£ii evacilllatoo (lJItlilil!rWI'u tWo),,,,,",,," "'-' -",,-,-,N:c::' -f-'(,.:;]4,---,-__ .:..:..c....:-_ If welievaclJIJlted to dryness, I!itmilet·ofglilj'l,ri~;§va~\!~~~",if',c;.'" ';..0; -'-''-)' (I!,!:!<,L/L:JIt-=--'--__ ....:--'-_ ~ ,-, . Nmme of Certified Annlyliollll JLal'DKI!ID~l'jf Q~i~ If a preservative iSiilicii; Sp'~ify; 'Th'1l,~,J!"~". , ,", QIiIlirtit1 IIfPf<j'Servative: .-,; .... MiIII-I[lro"E<.liIw~rer DDi!C-!J~~g;: JPi!,Ji!1~jt i(JroMll<llJll!ll@" .l¥I!lmJiaomg J!j)~!e: 2.2J5Jl7 1Revisio!l: 2 QI!llHiIjl ilmS!l'fb1ilre li'lrui (Qifl!E') AHACl!llMilEN1!' 1l WlHill'll'm: MIE§A ~Nl!lDM OOHI1JL . . .' ~lID lIDA'll'4»~Mg}·~J!W1iil([DllmlllnWA'll'1EL1t . DescrnpinalllofS!ia1il,!illurulgli:.l'll@oot: ~da JLocafiHolll (w8Ifi"iin~!1i@) '1lA f{J-~4'-'-.l.lq.J.II{l..""""'·'--'·· ,.>f.j!i'Ni:-'~~,4,~"':~t~~~""'J"'[~-i!t-~~~-;/-Irt,-1tdt-·(-,,,,,-. "-/1.-. ~-".'-, '$--"'.-' ~-.. -:-1~ ~a IDfl!e !l!fi<l Tinl!le for 1!"wJrglJilg JI. 2 . a 1 moo :ll?!ii1PH~nJg (if diffem3nt). . ..... . ...... . :--;;. \ ',:: .'".. , . , Weln1P'MtgDilgEtn!l~ij~!!~p~~'~:1i~~~0~~i~i~;~f OI!!er~UUl~elllie!)6Iunl m Sa~lgOlgJE!vel1l AIt'W.4. .... ' " ' .. R~~~\\l~\lli.i!lt~I~,~~Xi#lfJj,v~t'i·:;E';:" pHl!lijiffeK7.11 1-() speciijCCOlld~P.~~.tl,~r ~~~~~ ..... ' GIiI •. Wrged 0,.,----. . '. L-.-,.... ""'.' ~- ". \.-'- .. ,-'\'. RedoK Potentia! (Eb)c-' ___ -'\. __ {2fNScJ-L . TwA/-II , .... . ' Mil!! -«JwlUlIillwa!er IDiBclmrga l!'<O!Iot [Me; H.l7.@Ii iReviDio!l!: R OJrouillllW!l!et l.Vfuwtom.g ~y .Il!J!mmloo JPjWi (QILli',) ----------'" _____ Thilil~!Y.' .~ ...... 'fimeiro ~WlcWlnte tW@lls8mgwlUlil6B (2V) . 1" ",'2V/Q'::""'«, .... .• , :"" NmtlIer of casilllg vol!li~li'e\rilt'i.ia'ted(ii:ti~'WuiliitWo)-"-,,,''''··;;''-'' ~,--~_---,;",---_,----,,--,,-_ . ;. lffwell evacwated 101 dryness, numbo!"of g~li~~~\\y.at!l*(~~,,!,,'["""\"-"" "'-'-'''-'-_-____ '----'-_ N_e of Certified Ann!ytiold LnboraIOfjrifOih~fli#uJi'iil:~trilY.;t;ajjli ·'''It',·, " ., ,. , '" -- ' .. -." .• ""!"--'-.. : c •• :_.-;: -_ Tab C 1.200 600 o 1.200 F~' ---- o Monitoring Wel(MW) • Piezometer • 50 .. • Spring S:'f>rqe<UllUC-001·01-001 Denison M",HIGISlmapdoo;$l20091223Nb'ateMapJ1\lld LoooIl!1 • Surface Water • Chloroform MrN o Nitrate MrN --Nitrate Concentration (mgfl) --Grouna.vater Elevation Contours 10Ft - - -Groundwater Elevation Contours 5ft Source(s): Aerilll -utah GIS Portal website: Weils -HGC. Inc.. May 2008 report. Figure 3 Nitrate Concentrations with Groundwater Elevations , ~ • 1,200 600 0 1,200 /i """"'!;_~",,,,"Iii _____ ! Feet S:Ip,,,,ecu.IIUC·OO1-01-001 J.ogO!!!! o Monilomg wen • Surface Water • Piezometer • Chloroform MW • Seep 0 ".Urate MW • _ --Olloride Concentration (mg.1..) --Groundwater Elevation Contours 10Ft - - -Groundwater Elevation Contours 5ft Source(s): Aerial -Utah GIS Portal website; Wells -HGC, Inc., May 2006 report. Figure 4 Chloride Concentrations with Groundwater Elevations TabD Q) E .-I-- '-Q) > 0 ....... -c. Q) > E Q) .c ....I • '-.1'"' Q) ...., ""-'" to S ~ I ~ Z I-- 600Z /1/n 600Z/1/n 600Z/1/01 600Z/1/6 600Z/1/8 600 Z/1/L 600Z/1 /9 600Z/1/S 600Z/1/P 600Z/1/E 600Z/1/Z - ~ , - ~ -~ ~ - ~ - - ~ - - - - - 0000000000 OLl)OLl)OLl)OLl)OLl) OJ E .-l- I- OJ > 0 --c. OJ > E OJ ..c ...J • I-,t' OJ ...., -to S N I ~ Z I- 600l/1/lT 600l/1/n 600l/1/01 600l/1/6 600l/1/8 600l/1/L 600l/1/9 600l/1/S 600l/1/v 600l/1/E 600l/1/l - - - - - - - - 000 000 000 000 o LI'l 0 LI'l 0 LI'l .-t .-t N N QJ E 0- I- ~ QJ > 0 --a. QJ > E QJ ..c ~ 0 ~ .t' QJ +'" -ro S M I ~ Z I- 600l /T/lT 600l/T/n 600l/T/OT 600l/T/6 600l/T/8 600l/T/L 600l/T/9 600l/T/S 600l/T/v 600l/T/'t 600l/T/l - - - - - - - - I 4 000 0 0 0 o Lf) 0 Lf) 0 Lf) o 0 .-t .-t N N m m m m m m OJ E 0-t-... OJ > 0 --c. OJ > E OJ ..c -oJ • ... ,t' OJ +" -to S ~ I ~ Z t- - 600l/T/lT ~ ~ 600l/T/n 600l/T/OT 600l/T/6 600l/T/8 600l/T/L 600l/T/9 600l/T/S 600l/T/P 600l/T/E 600l/T/l - - - - - 000000000 000000000 . . . . . . . . . mo::tLl)lOr-.OOO"lO..-t mmmmmmmo::to::t QJ E 0-I- 10.. QJ > 0 --a. QJ > E QJ ..c ~ 0 10.. .t' QJ ...., -to S Ln I ~ Z I- 600Z/8/ZT - 600 Z/1/ZT 600Z/17z/n - 600Z/LT/n - 600Z/01/n - 600z/£/n - 600z/a/01 600Z/0Z/01 600Z/£1/01 - 600Z/9/01 - 600Z/6Z/6 600Z/ZZ/6 600Z/51/6 - 600Z/8/6 - 600Z/1/6 - 600Z/ 5Z/8 -t-t-t-t--+-+-"~~-i Lf"l0Lf"l0Lf"l0Lf"l0 o::;tLf"lLf"lI.OI.Or--r--oo . . . . . . . . 00000000 r--r--r--r--r--r--r--r-- QJ E 0-t-... QJ > 0 --a. QJ > E QJ ..c ....I 0 ... . t' QJ +'" -fa S U) I ~ Z t- 600 Z/1/Z1 600 Z/1/n 600Z/1/01 600Z/1/6 600Z/1/8 ~ -\ \ - - - ~ 0000000000 r--OOO'lO..-tNM<:t U"l lC) . . . . . . . . . . -..,JCJ"Il/1.j::>WNI-> 00000000 . . . . . . . . 00000000 00000000 8/25/2009 I-9/1/2009 I-9/8/2009 I-9/15/2009 ~ I-9/22/2009 I-9/29/2009 I-10/6/2009 I-10/13/2009 I-10/20/2009 I-10/27/2009 I-11/3/2009 ~ I-11/10/2009 I-11/17/2009 I-11/24/2009 I-12/1/2009 ~ I I I I [12/8/2009 """'i Z ~ I 00 :E OJ _ r+ ;::rtD . "'" C'" 3 -c - ~ tD < tD -o < tD "'" """'i -0 3 tD 0) E 0- I- r- 0) > 0 --C-O) > E 0) ..c ...J 0 r-.t' 0) +" -ttl S en I -=::t Z I- - 600Z/8/11 - 600Z/1/11 - 600Z/17z/n - 600Z/L1/n - 600Z/01/n - 600z/£/n 600Z/LZ/01 600Z/0Z/01 - 600z/n/01 600Z/9/01 600Z/6Z/6 - 600Z/ZZ/6 - 600Z/S1/6 - 600Z/8/6 600Z/1/6 600Z/SZ/8 0000000000 \DI'OOcnO..-tN("'I')o:::tLl) . . . . . . . . . . o:::to:::to:::to:::tLl)LI)LI)LI)LI)LI) \D\D\D\D\D\D\D\D\D\D Q) E 0-.... ~ Q) > 0 --Q) C. > E Q) ....I .c ~ • Q) ...., '+-...., -ttJ S 0 ~ I ~ Z .... 600l /1/l1 600l /1/11 600l /1/01 600l /1/6 600l /1/8 - - - ~ ~ - 00000000 \.OooONo::t\.OooO . . . . . . . . .-t.-tNNNNNM 0000000000000000 OJ E .-~ ~ OJ > 0 --OJ Q. > E OJ ....I ..c ~ • OJ . t' .... -to S 'l""I 'l""I I ~ Z ~ 600Z/1/l1 600Z/1/n - ~ \ ~ -\ ~ ~ 00000000 N<:t\DOOON<:t\D . . . . . . . . 0000.-1.-1.-1.-1 r--r--r--r--r--r--r--r-- QJ E 0-.... ... QJ > 0 -QJ > QJ ....I ... QJ .... ta S N ~ I ~ Z .... -a. E ..c 0 .... ..... - 600Z/T/ZI 600Z/T/n - 00000000 OLl)OLl)OLl)OLl) . . . . . . . . 1'1'00000'\0'\00 MMMMMM<:t<:t ClJ E .-.... ~ ClJ > 0 --ClJ Q, > E ClJ ...J ..c ~ • ClJ . t' ...., -to S M ~ I -=::t Z .... 600Z/1/l1 600 Z/1 /n - -, Lf)OLf)OLf)OLf)OLf)O O'lOO..-t..-tNNMM<:t . . . . . . . . . . \Di'i'i'i'i'i'i'i'i' <:t<:t<:t<:t<:t<:t<:t<:t<:t<:t cv E .-I- ~ cv > 0 -cv > cv ....I ~ cv ...., to S ~ ~ I ~ Z I- -a. E ..c • . t' - 600Z/1/11 600Z/1/n o 0 0 0 0 0 0 00 (J) 0 .-t N M <:t NNMMMMM \D \D \D \D \D \D \D OJ E .-l- i- OJ > 0 -OJ > OJ ....I i- OJ ...., ta S a.n 'l""'f I ~ Z I- -C. E ..c • . t' - 600l/1/l1 600l/1/n - - 0000000000 0000000000 . . . . . . . . . . 1..0000N<:t1..0000N<:t r--r--OO 0000 0000 cn cncn OJ E .-~ i.. OJ > 0 -OJ > OJ ....I i- OJ oIJ to S \D ~ I ~ Z ~ -a. E .c • ,t' - 600l/1/Z1 600l/1/n - OLl)OLl)OLl)OLl)O OO..-t..-tNNMM<:t . . . . . . . . . cncncncncncncncncn <:t<:t<:t<:t<:t<:t<:t<:t<:t Q) E 0-.... ~ Q) > a -Q) > Q) ..... ~ Q) +" to S I' ~ I ~ Z .... -c. E .c • ,t' - 600l/1/lT 600l/1/n - - o 0 0 0 000 .-t N ('\") o::t LI) 1.0 r-- LI) LI) LI) LI) LI) LI) LI) ('\") ('\") ('\") ('\") ('\") ('\") ('\") OJ E .-I- ~ OJ > 0 -OJ > OJ ....I ~ OJ .., to S 00 ~ I ~ Z I- 600l/1/lT -C. E .c • . t' - 600l/1/n - - 00000000 00000000 . . . . . . . . ClJ E .-I- ~ ClJ > 0 -ClJ > ClJ ....I ~ ClJ ...., to S en t""'t I III:t Z I- -Co E ..c • . t' - 600l/1/n 600l/1/n - - 00000000000 m<:tL.{')\.OI'-OOO'lO..-tNm . . . . . . . . . . . <:t<:t<:t<:t<:t<:t<:tL.{')L.{')L.{')L.{') L.{')L.{')L.{')L.{')L.{')L.{')L.{')L.{')L.{')L.{')L.{') Tab E Water Levels and Data over Time White Mesa Mill· Well TN4·1 Total or lVlcaslIring Le nglh j\llcaslIl'ed Tolal Total Water Land Point Of Deplh to Deplh to Depth Elevation Surface Elevation Riser Dale Of Waler Waler Of (WL) (LSD) (MP) (L) Monitoring (blw.MP) (blw.LSD) Well 5.646.96 5,648,09 1.1 3 11 2.5 5,577.74 2/6/2009 47,7 1 46,58 5.577.35 7121 12009 48,10 46,97 5.577.62 912 112009 47,83 46,70 5,578.46 10/2812009 46,99 45,86 5,579,95 12/1412009 45.50 44.37 Water Levels and Data over Time Whil e Mesa Mill -Well TN4-2 Total 0 1' Measuring Length Measured Total Total Water Land Point Of Depth to Depth to Depth Elevation Surface Elevation Riser Date Of Water Water Of (WL) (LSD) (MP) (L) l'vlonitoring (blw.MP) (blw.LSD) Well 5,625.75 5,626.69 0.94 95 5,610.13 2/612009 15.32 14.38 5.609.39 7/2 112009 16.06 15.12 5.608.49 9/2112009 16.96 16.02 5.605.84 11 1212009 19.61 18.67 5.605.33 12/1412009 20.12 19.18 Water Levels and Data over Tilli e White Mesa Mill -Well TN4-3 TOlalor Mensllring Lenglh l'vicaslired TOlal Tolal Wale,' Land Point Of Deplh to Deplh 10 Deplh Elevation Surface Elevation niseI' Dale Of Waler Waler Of (WL) (LSD) (MP) (L) l\t[onitoring (blw.MP) (blw.LSD) Well 5.633.64 5.634.50 0.86 11 0 5.594.72 2/6/2009 30.73 29.87 5.593.32 7/2 112009 32.13 3 1.27 5.593.29 9/2 112009 32.16 3 1.30 5.593.55 1012812009 3 1.90 3 1.04 5.594.07 12/1412009 3 1.38 30.52 Water Levels and Data over Time W hite Mesa Mill -Well TN4-4 TOlalor l\1casliring Lenglh lVlcasllrcd Tolal TOlal Waler Land Point Of Deplh to Deplh to Depth Elevation Surface Elevat ion Riser Dale Of Waler \-Vater Of (WL) (LSD) (MI') (L) iVlonitoring (bl\\'.MI') (bl\\'.LSD) Well 5.64 1.04 5.64 1.87 0.83 136 5.585.05 2/612009 40.40 39.57 5.587.84 712 112009 37.61 36.78 5.588.60 912112009 36.85 36.02 5.589.45 1012812009 36.00 35.17 5.589.39 12114/2009 36.06 35.23 Water Levels and Data over Time White Mesa Mill -Well TN4-S Total or Measuring Length 1\1easured Total Total \-Vater Land Point Of Depth to Depth to Depth Elevation Surface Elevation Riser Date Of Water Water Of (WL) (LSD) (MP) (L) Monitoring (blw.MP) (blw.LSD) Wen 5,653.70 5,655.18 1.48 155 5,554.70 812512009 70.75 69.27 5,554.78 912 112009 70.67 69.19 5,554.8 1 11110/2009 70.64 69.16 5,554.89 1211 412009 70.56 69.08 Water Levels and Data over Time White Mesa Mill -Well TN4-6 Total 0 1" Measuring Length McaslII'ed Total Total "Vatel" Land Point 01' Depth to Depth to Depth Ele"ation Surface Elevation Riser Date or \-Vater Water 01' (WL) (LSD) (MP) (L) iVlonitorillg (blw.MP) (blw.LSD) Well 5.663,03 5.664,94 1.9 1 135 5.550 03 8125/2 009 75.42 73.5 1 5.549,97 912212009 75.48 73.57 5.550.12 I 1/312 009 75.33 73.42 5.550.43 1211412009 75.02 73.11 Water Levels and Data over Time W hite Mesa Mill -Well TN4-7 Total or l\1easliring Lenglh l\1casul'cd Total Total ',Vatcl" Land Point Of Depth to Depth to Depth Elevation Surface Elevation Riser Date Of Water Water Of (WL) (LSD) (M P) (L) Monitoring (blw.MP) (blw.LSD) Well 5,647.39 5,649.26 1.87 120 5,528.75 812512009 96.70 94.83 5,534.53 912 112009 90.92 89.05 5.535.0 I 11 /1012009 90.44 88.57 5,535.15 12114/2009 90.30 88.43 ""ater Levels and Data over Time White Mesa M ill -Well TN4-8 Total or Measuring Length MCaSUI"ed Total Total Water Land Point Of Depth to De pth to Depth Elevation Surface Elevation Riser Date Of Water Water Of (WL) (LSD) (MP) (L) Monitoring (blw.MP) (blw.LSD) Well 5.649.35 5.651.48 2.13 160 5.562.98 812512009 62.47 60.34 5.563.07 9/2 112009 62.38 60.25 5.563.06 11 /312009 62.39 60.26 5.577.35 12/14/2009 48.10 45 .97 Water Levels and Data over T ime White Mesa Mill -Well TN4-9 Total or iVlcas uring Length Measured Total Total 'Vater Land Point Of Depth to Dept h to Depth Elevation Surrace Elevation Riser Date Of Water Water Of (WL) (LSD) (MP) (L) Mo nitoring (blll'.MP) (blll'.LSD) Well 5,645,68 5,647.45 1.77 102.5 5,560,05 8/2512009 65.40 63,63 5.560,12 9/2212009 65.33 63.56 5.560,27 1111012009 65,18 63.4 1 5.560.53 12114/2009 64,92 63,15 Water Levels and Dala over Time While Mesa M ill -Well TN4-10 TOlalor Measuring Lenglh Measured Tolal Tolal WaleI' Land Point Of Deplh 10 Deplh 10 Depth Elevati on Surface Elevation Riser Dale Of \Va ler Waler Of (WL) (LSD) (M P) (L) IVlollitol"ing (blw.MP) (blw.LSD) Well 5.664.63 5.666.98 2.35 107.5 5,542.65 812512009 82.80 80.45 5.542.87 9122/2009 82.58 80.23 5.543.08 I 1110/2009 82.37 80.02 5.543.37 1211412009 82.08 79.73 '~'ater Levels and Data over T im e White Mesa Mill -Well TN4-11 Tolal or Measuring Lenglh Measured Tolal Tolal WaleI' La nd Point or Deplh 10 Deplh 10 Deplh Elevation Surface Elevation Riser Dale or \Vater WaleI' or (WL) (LSD) (MP) (L) Monitoring (blw.MP) (blw.LSD) Well 5,683,16 5,684,53 1.3 7 147.5 5,553,92 I 1/3/2009 71.53 70,16 5.554,80 12/1412009 70,65 69,28 'ValeI' Levels and Data over Time White Mesa M ill -Well TN4-12 TOlalor Measuring Lenglh Measured Tolal Tolal WaleI' Land Point Of Deplh 10 Deplh 10 Deplh Elevation Surface Elevation Riser Dale Of \Va ter Wale,' Of (WL) (LSD) (M P) (L) Monitoring (blw.MP) (blw.LSD) Well 5.667.03 5.668.24 1.21 11 5 5.585.54 1 11312009 39.9 1 38.70 5.586.07 1211412009 39.38 38.17 Water Levels and Data over Time Whit e Mesa M ill -Well TN4-13 Total or Measuring Length Measured Total Total Water Land Point or Depth to Depth to Depth Ele"ation Surface Elevation Riser Date or Water Water or (WL) (LSD) (MP) (L) Monitoring (bl ll'.MP) (bill'. LSD) Well 5.633.04 5.634.32 1.28 120 5.578.08 I 1/3/2 009 47.37 46.09 5.578.35 12/1412009 47.10 45.82 Water Levels and Data over Time White Mesa Mill · Well TN4·14 Total or lVleaslIl'in g Length 1\1casul'cd Total Total Water Land Point Of Depth to Depth to Depth Elevation Surface Eleva tion Rise.' Date Of Water 'Vater Of (WL) (LSD) (MP) (L) Monitoring (blw.MP) (blw.LS D) Well 5,647.80 5,649.53 1.73 135 5.562.10 I 1/4/2009 63.35 6 1.62 5.562.43 12/1412009 63.02 6 1.29 Water Levels and Data over Ti me White Mesa Mill -Well TN4-15 Total 0 1' lVleasuring Length lVleasurcd Total Total Water Land Point Of Depth to Depth to Depth Ele vation Surface Eleva tion Riser Date Of Water Water Of (WL) (LSD) (MP) (L) lVlonitoring (blw.MP) (blw.LSD) Well 5.675.0 1 5.676.49 1.48 155 5.543.08 I 1/1012009 82.37 80.89 5.532.99 12114/2009 92.46 90.98 Water Levels and Data over Time White Mesa Mill -Well TN4-16 TOlalor lVlcasuI"ing Lenglh lVlcaslIred Tolal Tolal 'Vater Land Point Of Deplh 10 Deplh 10 Deplh Elevation Surface Elevation Ri ser Dale Of Waler \Vat er Of (WL) (LSD) (MP) (L) lVloniloring (blw.MP) (blw.LSD) Well 5.65 1.07 5.652.70 1.63 100 5,576.09 1 1/4/2009 49.36 47.73 5.576.31 1211 412009 49.14 47.5 1 VI'ater Levels and Data over Tim e White Mesa Mill -Well TN4-17 Total or Measuring Length l\'lcasurcd Total Total \·VatCl" Land Point Of Depth to Depth to Depth Elevation Sur'face Elevation Riser Date Of Water Water Of (WL) (LSD) (MP) (L) Monitoring (blw.MP) (blw.LSD) Well 5,639.73 5,641.55 1.82 100 5,589.86 I 1/4/2009 35.59 33.77 5,590.17 1211412009 35.28 33.46 Water Levels and Data over Time White Mesa Mill -Well TN4-18 TOlalor rvteaslIring Lenglh Measured Tolal Tolal Waler Land Point Of Deplh 10 Deplh 10 Deplh Elevation SUI'race Elevation Ri ser Dale Of Waler Waler Of (WL) (LSD) (I\1P) (L) Monitoring (blw.MP) (blw.LSD) Wen 5.643.95 5.645.45 1.50 100 5.566.85 111212009 58.60 57.10 5.580.14 12114/2009 45.31 43.81 Water Levels and Data over Tim e Whi te Mesa M ill -Well TN4-19 TOlal 0 1' Measuring Lenglh Measured Tolal Total Waler Land Point Of Deplh to Deplh 10 Deplh Elevation Surra ce Elevation Riser Dale Of Waler Waler Of (WL) (LSD) (MP) (L) 1\1onitoring (blw.MP) (blw.LSD) Well 5.659.59 5,66 1.36 1.77 11 0 5,570.26 111212009 55.19 53.42 5,570.79 12114/2009 54.66 52.89 Tab F February Sampling Event ------------------------------------------~ ENERG Y LASORA TORIES, INC. '2393 Sail Creek Highway (8260 1) • P.o. Box 3258 ' Casper. WY 82602 Toll Free 888.235 0515 ' 307.2350515 • Fax 307.234. f/J39 ' casper@eflergylab.com · wwweflergylab.com II1U()/U11()flJr5 February II, 2009 Denison Mines (USA) Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C09020370 Project Name: Initial Nitrate ANALYTICAL SU MMARY REPORT -_.----_.---------------------------------------- Energy Laboratories, Inc, received the following 7 samples for Denison Mines (USA) Corp on 2110/2009 for analysis. Sam pte 10 Ctlent Sample 10 Collect Date Receive Oate Matrix Teat C09020370-001 TWN-l 02/06/09 12:25 0211 0/09 Aqueous Nitrogen, Nitrate + Nitrite C09020370-002 TWN·2 02/06/09 13:20 0211 0/09 Aqueous Same As Above --._----------.. --.---... _----_ ... C09020370·003 TWN·3 02/06/0912:3702110109 Aqueous Same As Above C09020370·004 TWN·4 02/06/09 10:20 0211 0109 Aqueous Same As Above C09020370-005 TWN-60 02/06/0908:45 02110109 Aqueous Same As Above C09020370-006 TWN-63 02/06/09 08:30 0211 0/09 Aqueous Same As Above -------- C09020370-007 Temp Blank 02110/09 Aqueous Temperature As appropriate, any exceptions or problems with the analyses are noted In the Laboratory Analytical Report, the ONOC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approvad By: &~ uJJ ~ l ,,"'!??JaU ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' P'Q Box 3258 • Casper, WY 82602 _!!:~!!:~~~ Toll Free 888.235.0515 • 307.235.0515 • Fa)( 307.234.1639 • casper@energylab.com · wWIY.energylab.com I AIU )n.~1 TOIUE S LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Initial Nitrate Lab 10: C09020370-001 Client Sample 10: TWN-1 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen. Nitrate+Nitrito as N 0.7 mg/l Lab 10: C09020370-002 Client Sample 10: TWN -2 Matrix: Aqueous Analyse8 Rosult Units MAJOR IONS Nitrogen. Nltrate+Nitrite 8S N 25.4 mg/l Lab 10: C09020370-003 Client Sample 10: TWN-3 Matrix: Aqueous Analyaes Result Units MAJOR IONS Nitrogen, Nltrate+Nltrite as N 23.6 mg/l Lab 10: C09020370-004 Client Sample 10: TWN-4 Matrix: Aqueous Analy888 Result Units MAJOR IONS Nitrogen, Nitrste+Nitrite as N 1.0 mg/l QUallners Qualifiers ---- 0 Quallnerl 0 Quallflera RL 0.1 RL 0.2 MCL! QCL Report Date: 02/11/09 Collection Date: 02/06/0912:25 DateRecelved: 02/10/09 Method Analy.IB Date J By E353.2 02l11/09 10:59 /1al Collection Date: 02/06109 13:20 OateRecelved: 02/10109 MCll QCL Method Anal),.ls Date I By E353.2 0211110911 :09/191 Collection Date: 02/06/09 12:37 OateRecelved: 02/10109 ------------. MCLI RL QCl Method Analysl. Date J By 0.2 E353.2 02/11/0911:12/j91 Collection Date: 02106/09 10:20 DateRacelvad: 02110/09 MCLI RL QCL Method Analysis Date I By 0.1 E353.2 02/111091 1:14/j81 ----------------------------------Report Rl ~ Analyte reporting limit. Definitions: aCl -Quality coniroi limit. D • RL lnCl'eased due 10 sample matrix interference. MeL -Maximum contaminant level. NO -Not deteded at the reporting limit. ENERG Y LABORATORIES, INC. • 2393 Sail Creek Highway (82601) • Po. Box 3258 • Casper. WY 82602 tg .. "'iIt{!fiI Toll Fre8 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· IYlmenergylab.com L/tIl{)IM I ()/Urs LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Inilial Nitrate Lab 10: C09020370-005 Client Sample 10: TWN-60 Matrix: Aqueous Analyses Result --------------- MAJOR IONS Nitrogen, Nilrate ... Nitrlte as N ND Lab 10: C09020370-006 Client Sample 10: TWN-63 Matrix: Aqueous Units -.-~~.---- mg/l Analy.as Result Units QualUisrs Rl 0.1 Quallflo", Rl Report Date: 02/11/09 Collection Date: 02/06/0908:45 OateRecelved: 02/10109 MCU QCl MCL! Method Analysis Date I By E353.2 0211110911:17 /jal Collection Date: 02106/0908:30 DateRecelved: 02/10/09 QCL Method Analysl, Oate I 8y ----------------------------_ .. _ .... _---- MAJOR IONS Nitrogen. Nitrate+Nitrite as N ND mg/l Lab 10: C09020370-007 Client Sample 10: Temp Blank Matrix; Aqueous Analyses ReBult Units 0.1 Qualifiers RL E353.2 02/1 1/0911:191)01 Collection Date: Not Provided DateRecelved: 02/10109 MCU QCL Method Analys's Date I By -----------_.-.. ---.------. ---_._-- PHYSICAL PROPERTIES Temperature Report Oef[nltlons: RL -Analyte reporting limit. QeL -Quality control limit. 2 ·c E170.1 02/10/0909:251 sdw ----------.--_._------_._- MeL -Maximum contaminantievel. NO -Not detected at the reporting limit. -.-.---------------------------------------~ ENERGY LABORATORIES, INC .• 2393 Sail Creek Hi9hway (82601)' Po. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com · WWI.energylab.com lAunU/"OIU~ \ QA/QC Summary Report Client: Denison Mines (USA) Corp Project: Initial Nilrale Analyt. M.lhod: E353.2 Sam pl. 10: MBLK·1 Nitrogen. Nilrste+Nltrile as N Sam pl. 10: LCS·2 Nitrogen, Nltrate+Nilrite 8S N Sampl.IO: C09020370-o01AMS Nitrogen, Nitrale+Nilrite as N Sampl.'O: C09020370-o01AMSO Nitrogen, Nitrate+Nitrile 88 N Result Units Molhod Blank ND mg/l Laboratory Control Sample 2.25 mglL Sample Matrix Spike 2.83 mglL Sample Matri)( Spike Duplicate 2.91 mg/l Report Date: 02/11/09 Work Order: C09020370 RL %REC l ow limit High Limit RPD RPDUmlt Qual Balch: R11~58~ Run: TECHNICON_090211A 02/11109 10:07 0.03 Run : TECHNICON_090211A 02/11/0910:09 0.10 90 90 110 Run : TECHNICON_090211A 02/11/09 11 :02 0.1 0 108 90 110 Run: TECHNICON_090211A 02111 /0911 :0~ 0.10 112 90 110 2.8 10 S ---------------------------- Qualifiers: Rl -Analyte reporting limit. NO -Not detected at the reporting limit. S • Spike recovery outside of advisory limits. \,iustoay PLEASE PRINT-Provide as much information as Dossible. Company Name: Project Name, PWS, Permit, Etc_ Sample Origin EPA/State Compliance: Dlj\I~DI\.. M;A~.s ~,/"J N/Ir~ State: ft<..-J Yes 0 No 0 - Report Mail Ad~~sB~ gO, . Contact Name: Phone/Fax: Email: Sampler: (Please Print) ~i. A .. L.... tff g-tfS-// i2'(.a¥I ~/M€£ 6 'f ~ z. 2'?-1 f-j:;;"e£ II: 8 PV/A . Invoice Address: I I ~.ice Contact & Phone : Purchase Order: QuotelBoHIe Order: I <:"' ..... ,-I./av ; I:> --r:; L1' Special Report/Fonnats -Ell must be notified &W.i.\I1, \'7@[]@ 1Ml3®!lD~ Contact ELI prior to Shipped by: prior to sample submittal for the following; o i!; R RUSH sample submittal 1/L'l'_A--Fl !!m cn..r:::. I=' for charges and Cooler rO(5): ~>~51 0 ~ scheduling -See fi/~n~ -(I) 0:>.. S~(f.)'" W U Instruction Page " '" ~ J: DDW DA2LA o<~~ -c RecelptTemp c..> c: Comments; U .. cnl.Q " ::2. DC D GSA D EDD/EDT{Electrooic Data) oCD .... aJl « E' ~ 0..$ c: I-'" D POTWIWWTP Fonnat: lD~tOO l-e: S on~ EIV~I~ « '5 os No D State; D LEVEL IV o..~-~ I-~E<Ig, W 0; Custody Seal C!J J N D Other: D NELAC till >l W E ~ CI) 5 H BcttJcsI CD Coolers B C Z Intact (f) N SAMPLE IDENTIFICAnON Collection Collection MATRIX Signature @N (Name, Location. Interval, etc.) Date TIme Match , /' -r1lM./-I 2. -f:,. ()&f i J25'() J -iN / ~ 1WN' z. a,/"o4 IJ32~ I-w / /' ~ 3TWA}_ 3 ':z. .1> . ()q 1.2.17 I-w / ./ Q • -rIAl AI -L.{ 2,·6 ·IJ&J JD2IJ I-w / ./ l '-rWN-{,(; /l..,./Yf l ~gi{S i-w / /' ~ • 77AIA/-.I.. ? 2-f:,-rfl IlJgzl> I-W / / ~ 7 ~ ~O .1< f.,,~ j,( ~ , r -~ ! (it! 9 fX){).31.~ '0 I"'" Custody ~ ... "" by 'P!..: Oat"" .... /d.JtJ I /.. """"'J!./ Recer.oed by (~): Oatem ,."" Signature: VA../ "4/~' !l.-"I.-Record •• '..,....,..,byl ..... )' u"",, /-Received by (print): DateJ me: AaMe: MUST be Signed I~~d/~ ,0., OatefT"'" '2.~ ~ -Samole Disposal: Return to C~ent: Lab Disposal: . ~//J~;q 9 ' , In certain circumstances, s;:mples submitted to Energy laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as naice of this possibility. All sul:Kontract data will be clearty notated on your analytical report. VISit our web site at www.energylab.com for additional information, dOW'nloadable fee schedule, forms. and links. Energy Laboratories Inc Workorder Receipt Checklist Denison Mines (USA) Corp Login completed by: Edith McPike Reviewed by: Reviewed Date: Shipping container/cooler in good condition? Custody seals Intact on shIpping container/cooler? Custody seals Inlact on sample botUes? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers Intact? Sufficient sample volume for IndIcated test? All samples received withIn holding time? ContalnerfTemp Blank temperature: Water· VOA vials have zero headspace? Water -pH acceptable upon receIpt? Contact and Correclive AcUon Comments: None Ve. Ii! Ves Ii! Ves 0 Ves Ii! Ves Ii! Ves Ii! Ves Ii! Ves Ii! Ves Ii! Ve. Ii! Ye·O Yes Ii! C09020370 Date and Time Received: 211012009 9:25 AM Received by: pb No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier name: Next Day Air Not Present 0 Not Present 0 Not Pre.ent Ii! No VOA vIals submitted 0' Not Appllcabte 0 l ,-1!:::or,J;;aU ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway(82801j ' po. Box 3258 . Casper. WY 82802 _!!~!!~~~.!' Toll Free 888235.0515 • 301.235.0515 • Fax 301.234.1639 . casper@energylab.com · wWI1<energylab,com , AIIOUATORlF5 CLIENT: Denison Mines (USA) Corp Date: II-Feb-09 Project: Inillal Nitrate CASE NARRATIVE Sample Delivery Group: C09020370 ORIGINAL SAMPLE SUBMITTAL(S) All original sample submittals have been returned with the data package, SAMPLE TEMPERATURE COMPLIANCE: 4"C (±2"C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered Immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900,0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters, Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in relurnlng the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated, ATRAZINE. SIMAZINE AND PCB ANALYSIS USING EPA 505 Data for Atrazlne and Simazine are reported from EPA 525.2. not from EPA 505. Data reported by ELI using EPA method 505 reflects the results for seven individual Aroclors. When the results for all seven are ND (not detected). the sample meets EPA compliance criteria for PCB moniloring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so. ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated wilhin the Laboratory Analylical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories. Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillette, Wf eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SD eli·t -Energy Laboratories, Inc. -College Station. TX CERTIFICATIONS: USEPA: WfOOOO2; FL-DOH NELAC: E87641; California: 02118CA Oregon: Wf200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES. INC. -CASPER.Wf certifies that certain method seleetions contained in this report meet requiremenls as set forth by the above eccrediting authorilles. Some results requested by the etient may not be covered under these certifications. All analysis data to be submitled for regulatory enforcement should be certified In the sample state of origin. Please verify ELI's certification coverage by viSiting www.energylab.com ELI appreciates the opportunity to provide you with this analytical service . For additional information and services visit our web page W\vw.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT --------_. __ . __ .. _ .. 4356782224 International uralllulH 1228 13 P 111 12-22-2009 ENERGY LABORATORIES, WC .• 2393 Sail Creek Highway (82601)' po. Box 3258 • Caspar, WY 82602 TOIl Free 888.235.0515 • 301.2{ '15' Fax 301.234.1639 • caspar@energylab.co( 1Vwenergylab.com February 12, 2009 Denison Mines (USA) Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C09020365 Project Name: Chloride Exploration ANALYTICAL SUMMARY REPORT Energy Laboratories. Inc. received the following 7 samples for Denison Mines (USA) Corp on 2110/2009 for analysis. Sample 10 Client Sample 10 Coliect Date Rece iva Date Matrix Test C09020365-001 TWN-1 02106/09 12:50 02/10109 Aqueous E300.0 Anions C09020365-002 TWN-2 02/06/09 13:2002/10/09 Aqueous Same As Above C09020365-003 TWN-3 02/06/09 12:3702/10109 Aqueous Same As Above C09020365-004 TWN-4 02/06/09 10:20 02/10109 Aqueous Same As Above C09020365-005 TWN-60 02/06/0908:45 02/10109 Aqueous Same As Above C09020365-006 TWN-63 02/06/0908:30 02/10109 Aqueous Sa me As Above C09020365-007 Temp Blank 02/10109 Aqueous Temperature As appropriate. any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QAJQC Summary Report, or the Case NarraUve. If you have any questions regarding these tests results, please call. Report Approved By: 24/37 435678222t1 International uranIUm 12 28 23 P III 12-22-2009 25/37 ENERGY LABORATORIES, f!'Jp .• 2393 Salt Creek Highway (82601) • Po. Box 32511. • Casper, WY 82602 Toll Free 888.235.0515 • 3072! '15' Fax 307234.1639 • casper@energylab.CO( . ,Y/.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines (USA) Corp Site Name: Chloride Exploration Lab 10: C09020365-{)01 Client Sample to: TWN-1 Matrix: Aqueous Analyses MAJOR tONS Chloride Lab 10: C09020365-002 Client Sample ID: TWN-2 Matrix: Aqueous Analyses MAJOR IONS Chloride LablD: C09020365-{)03 Client Sample ID: TWN-3 Matrix: Aqueous Analyses MAJOR tONS Chloride LablD: C09020365-004 Client Sample ID: TWN-4 Matrix: Aqueous Analyses MAJOR IONS Chloride Report Rl . Analyle reporting limit. Definitions: Qel -Quality control limit. Result 19 Result 29 Result 96 Result 13 Units mg/l Units mgll Units mgll Units mg/l Report Date: 02/12/09 Collection Date: 02/06/09 12:50 DateReceived: 02/10109 MeLt Qualifiers Rl Qel Method Analysis Date J By E300.0 0211 110920:05/1)1 Collection Date: 02/06/09 13:20 DateRecelved: 02/10109 MeLt Qualifiers Rl Qel Method Analysis Date I By E300.0 02/11/0920:52 /1)1 Collection Date: 02/06/09 12:37 DateReceived: 02/10109 MeLt Qualifiers Rl Qel Method Analysis Date I By E300.0 02111/09 21 :07 Iljl Collection Date: 02/06/09 10:20 DateReceived: 02/10109 MeL! Qualifiers Rl Qel Method Analysis Date I By E300.0 02111109 21 :22 11)1 Mel -Maximum contaminant level. ND -Not detected at the reporting limit. <35678222< Inler national uranium 12 28 34 P rn 12-22-2009 26 /37 ENERGY LABORATORIES, INC .• 2393 Sal! Creek Highway(82601)' PO Box 3f"} . C,7Sper, WY82602 Toll Free 888.235.0515 • 3072( ,15 , Fax 307234.1639 • casper@energylab.co( ll'wenergylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines (USA) Corp Site Name: Chloride Exploration Report Date: 02112109 Lab 10: C09020365-005 Collection Date: 0210610908:45 Client Sample 10: TWN-60 Date Received: 02110109 Matrix: Aqueous MCL! Analyses Result Units Qualifiers RL QCL Method Analysis Oate I By MAJOR IONS Chloride Lab 10: C09020365-006 Client Sample 10: TWN-63 Matrix: Aqueous Analyses MAJOR IONS Chloride Lab 10 : C09020365-007 Client Sample 10: Temp Blank Matrix: Aqueous Analyses PHYSICAL PROPERTIES Temperatura Report RL -Analyte reporting limit. Definitions: aCL -Quality control limit. ND mg/L Result Units ND mg/L Result Units 3.0 ·C E300.0 02/1 1109 21 :38 Iljl Collection Date: 02106109 08:30 DateReceived: 02110109 MCL! Qualifiers RL QCL Method Analysis Date IBy E300.0 02/11109 21 :53/1jl Collection Date: Not Provided DateReceived: 02110109 MCL! Qualifiers RL QCL Method Analysis Date I By E170.1 02/10109 09:25 1 pb Mel · Maximum contaminant level. NO -Not detected at the reporting limit. 4356782224 InternatIonal uranium 12_28 44 P J1l 12-22-2009 27 /37 ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' po. Box 325R • Casper, WI' 82602 Toll Free 888.235.0515 • 301.2.{ ;15' Fax 301.234.1639 • casper@energylab.co{ ", .. energyI8b.com Client: Denison Mines (USA) Corp Project: Chloride Exploration Analylo Method: E300.0 Sample 10: LCS Chloride SamplolO: MBLK Chloride Sample 10: C09020365-001AMS Chloride Sample 10; C09020365-001AMSD Chloride Qualifiers: RL -Analyte reporting limit. QAlQC Summary Report Result Units l aboratory Control Sample 9.61 mg/L Method Blank NO mg/L Sample Matrix Spike 70.2 mgIL Sample MatriX Spike Duplicate 71.0 mg/L RL 1.0 0.02 1.0 1.0 Report Date: 02112109 Work Order: C09020365 %REC Low Limit High limit RPD RPDLimit Qual Batch: R1 14625 Run: IC1-C_090211A 02111/0914:42 96 90 110 Run: IC1·C_090211A 02111/0914:57 Run: tC1-G_090211A 02111/0920:21 104 90 110 Run: IC1-G_090211A 02/11109 20:36 105 gO 110 1.1 20 ND -Not detected at the reporting limit. PLEASE PRINT-Provide as much information as possible. , Ct:u:!:!Eany N:une: ~ Project Name, PWS. Permit, Etc. Sample Origin EPA/State Compliance: . 1 I), ~ 1J1'''''A\ dt,.?,;iy;: 5.. ,/-State:_~ Yes 0 NoD - Report Mat.d=':'~....,..,. S-Of con?! Name: /J ' Phone/Fax: Email: ;mPler: (P1ea~se Print) --tl I ,;j?I .. .J. -t4-$':!SJ/ K-ya" fA-1M€!( 6"'H'-Z2ZI M"fd_ II. _~ Invoice Address: ~ Inv'K'" Contact & Phone: Purchase Order: QuoteiBonle Orer: ~ '='a-E -' )-Wio ---r A lr ~ 'f-K 727.1 Special Report/Formats -ELI must be notified &!lW.'ill,'\7@[]@ rnlrn®(J[J~ Contact ELI poor to . s~~p .. ;" '" prior to sample submittal for the following· 0 -R RUSH sampl e subm,ttal ~/7' -/ I . i!? (D en ~ for charges and Coolor ID{s): ~ >;g 151 0 ~ scheduling -See ~~~ ~ UJ t:. U Instruction Page ekJ o -(I) I '0 R , T Dow D A2LA 0 ":0 gJ () § Comments: m p' .mp -.. (/)!ffil « 0 -'2 0 C o GSA 0 EOO/EDT(Electronic Da'a) ~ §l;.Ei c I-ro J _._, D ,8 .... "'0 I-C S 00''71 POTWNVWTP Fonnat: E.!£5:I'j!! <{ 5 ~ No o State: D LEVEL IV ~ ~I ~ I ~ UJ ';ij Cos'od, Sea' 0 : D Other: 0 NELAC '.' (J) >1 ,~' ~ § H Bott'es' B® ~ ~ Coolers f--"S-A-M-P-LE-,D-E-N-T-,F-,-C-AT-,-O-N----.-C-O-liecti-'-on-.,-c-ol-'e-ct-io-n+-M-A-T-R-IX---1 -..t ::a::,"", Q N {Name, Location, Interval. etc.} Date Time \j Match GJN '-fC,vlJ-/ 2.,6·tJr I/ZSO I-tV / -/ I~ 'J1..JN-7 J 11326 iI-v.; / / -I-t----- '-TfAJ/II,3 I V'37 /-VJ / / 1; __ _ '-rVJN-t.f \ IIOW "-W II L I"'! '-rIAJN'blJ 1 1J!f'l~ /-w IL ~ 6 77AlN ,1c3 :2-t ·o1 108'30 /-vJ '/ L I~ ~ 7 ' I!: ~ ''/,P/I\</J o/!Ja ... 11 1 '_~ ~ 9 'f ~ • I ~ I Custody I~:shed by rJ~:l ~.., 0j.;~; :'/;-:;,0 I~aturet! L Received by (prim): OatelTime: SlglUllu.re: Record 'Relitqu!SheCl bY1pcinl): Date! Ime: I~ignatur.: ecelllcd by (prinl): OalclTlme: Signature""------ M~ST be ,.,~. """Y' DatolTi ... , ~e, Signed Sample Dispo,al: RetumtoCI;enl: LabD;,oosal: "R;:;;;;:;;;;/I-4('/ .-9-/£1-/.77 9.;;7S--.. In certain circumstances, samples submitted to Energy l aboratories. Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibiJity. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information, downloadable fee schedule, forms, and links. ~ '" '" '" ~ '" N N N ~ '! ~ § ~ " ~ ~ N N '" '" N '0 3 N .:., N ~ o <0 ~ ;:0 ~ 4356782224 International urallium Energy Laboratories Inc Workorder Receipt Checklist Denison Mines (USA) Corp 12:29 14 p_rrr 12-22-2009 ( I I~illll~II~111I1 C09020365 Login completed by: Kimberly Humiston Date and Time Received: 2/10/20099:25 AM Reviewed by: Received by: pb Reviewed Date: Carrier name: Next Day Air Shipping container/cooler in good condition? Yes 0" No 0 Not Present 0 Custody seals intact on shipping container/cooler? Yes 0" No 0 Not Present 0 Custody seals intact on sample bottles? Yes 0 No 0 Not Present 0' Chain of custody present? Yes 0' No 0 Chain of custody signed when relinquished and received? Yes 0" No 0 Chain of custody agrees with sample labels? Yes 0' No 0 Samples in proper containe r/bottle? Yes 0' No 0 Sample containers intact? Yes III No 0 Sufficient sample volume for indicated test? Yes 0" No 0 AU samples received within holding time? Yes 0 No 0 ContainerfTemp Blank temperature: 3°e On Ice Water -VOA vials have zero headspace? Yes 0 No 0 No VOA vials submitted I{/ Water -pH acceptable upon receipt? Yes 0" No 0 Not Applicable 0 29 /37 ---------~.~~.~~~-~----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------_.----------------- Contact and Corrective Action Comments: None 435678222-1 InternatlollaluramUJII 12_29_2-1 p.1lI 12-22-2009 ENERG Y LA BORA TORIES, INC .• 2393 Sail Creek Highway (8260 I) • Po. Box 3258 • Casper, WY 82602 Toll Free 888.23~0515 • 307.2( '15 ' Fax 307.234.1639 • casper@energylab.co( 'wwenergylab.com CLIENT: Denison Mines (USA) Corp Project: Chloride Exploration Sample Delivery Group: C09020365 ORIGINAL SAMPLE SUBMITIAL(S) All original sample submittals have been return ed with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4"C (±2"C) , Date: 12-Feb-09 CASE NARRATIVE 30/37 Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shaU be considered acceptable if there is evidence that the chilling process has begun . GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be vIewed as Inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in retuming the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIL/SOLID SAMPLES Al l samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS USING EPA 505 Data for Atrazine and Simazine are reported from EPA 525.2, not from EPA 505. Data reported by ELI using EPA method 505 reflects the results for seven individual Aroclors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillette, WY eli-h - Energy Laboratories, Inc. -Hele na, MT eli-r -Energy Laboratories, Inc. -Rapid City, SD eli-t - Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: US EPA: WY00002; FL-DOH NELAC: E87641; California: 02118CA Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The resuits of this Analytical Report relate only to the items submitted for analYSis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meel requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify ELI 's certification coverage by visiting W\\W.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page lNINW.energylab.com. THI S IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT cNcRG r LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • P.O Box 3258 • Casper, WY 82602 Toll Free 888.2350515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com' wwv/.energylab.com L/lUC)ful/Omrf February 25, 2009 Denison Mines (USA) Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C09020752 Project Name: Nitrate ANALYTICAL SUMMARY REPORT Energy Laboratories, Inc. received the following 3 samples for Denison Mines (USA) Corp on 2/20/2009 for analysis. Sample 10 Client Sample 10 Collect Date Receive Date Matrix re.t C09020752·001 Piez 1 02/1 9/09 08:48 02/20109 Aqueous Nitrogen, Nitrate + Nitrite C09020752·002 Piez 2 02/19/09 08:20 02/20/09 Aqueous Same As Above C09020752·003 Piez 3 02/19/0907:35 02/20/09 Aqueous Same As Above As eppropriate, any exceptions or problems with the analyses are noted In the Laboratory Analytical Report, the QAJQC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' P.O, Box 3258 . Casper, WY 82602 Toll Free 888,235.0515 • 30Z235.0515 • Fax 30Z234, 1639 • casper@energylab.com · lV,menergylab,com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (U SA) Co rp Nilrale Lab 10: C09020752-001 Client Sample 10: Piez 1 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nil rste+Nitrile as N 6.8 mgiL Lab 10: C09020752-002 Client Sample 10: Piez 2 Matrix: Aqueous -------- Analyses MAJOR IONS Nitrogen, Nitrale+Nitrite as N Lab 10: C09020752-003 Client Samplo 10: Piez 3 Matrix: Aqueous Analyses ---.------ MAJOR IONS Nitrogen, Nitrate+Nltrite as N Report RL -Analyte reporting limit. Definitions: ael -Quality control limit. Result Units 0.5 mg/L Result Units 0,7 mgiL 0-RL inCfsased due to sample matrix Interference. Qualifiers RL D 0.2 Qualifiers RL 0,1 Qualifiers RL 0.1 MCU aCL Report Date: 02/25/09 Collection Date: 02/19/0908:48 OateRecolved: 02/20109 Method Analysis Datel By E353.2 02125/0913:581 jal Collection O.t.: 02/19/0908:20 OateRocoivod: 02/20109 -.-- MCU aCL Melhod Analysis Oalol By E353.2 02/25/09 14:01 Iial Collection Date: 02/19/09 07:35 OateReceived: 02/20109 MCU aCL Method Analysis Date I By E353.2 02/25/0914 :111 jal Mel· Maximum contaminant level. NO - Not detected at the reporting limit. ENERG r LA BORA TORIES, INC .• 2393 Sail Creek Highway (82601) • P.o. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 307235.0515 • Fax 307234.1639 • casper@energylab.com· wwwenergylab.com I AUOUAI ()I/It '> Client: Denison Mines (USA) Corp ProJect: Nilrale Analyte Method: E353.2 Sample 10: MBLK·1 Nitrogen , Nllrate+Nilrlte as N Sample 10: LCS·2 Nitrogen, Nltrate+NUrlte as N Sample 10: C09020752·002AMS Nitrogen. Nltrate;.Nilrlte as N Sampla 10: C09020752·002AMSO Nitrogen, Nltrate+NHrlte as N Quallflero: RL -Analyte reporting limit. QAlQC Summary Report Result Units Method Blank ND mgiL Laboratory Control Sample 2.42 mg/L Sample Matrix Spike 2.32 m9/L Sample Matrix Spike Duplicate 2.35 mg/L Report Date: 02/25/09 Work Ordor: C09020752 RL %REC Low Limit High Limit RPO RPOLlmlt Qual Batch: R115175 Run: TECHNICON_090225A 02/25/09 13:04 0.03 Run: TECHNICON_090225A 02125/0913:07 0.10 94 90 110 Run: TECHNICON_090225A 02/25/09 14:03 0.10 90 90 110 Run: TECHNICON_090225A 02/25/0914:06 0.10 92 90 110 1.3 10 ND • Not detected at the reporting limit. L 4Ft !(.'~~ I uRf[ " Chain of Custody and Analytical Request Record Page _1_ 01_1_ r~.,c r-"," ,. ,.... UYtUt:: ell::' IJIU\.II IIIIVIIIIClLlYI .... S P~~IUIO;:. COO1~e: Project Name, PWS, Perm~, Etc. Sample Origin EPNState Compliance: < \ ~t'A'\ ;",," 1'\11.'", u /t/;l .f ~ State: ~ Yes 0 No 0 Report Mail Address ~(:dl~~&<IG;O;¥S-I/ Cii::~NaplY 1~6f?-P~;~ax2Z~} Email: S~:~ (~::;=- Invoice Address: InVOIce Contact & Phone: Purchase Order: QuoteiBottle Order: 5~~~ 3~~ Special Report/Formats -ELI must be notified &G!JLi.ill, '\7@[]@ ill~®I!D~ Contact Ell prior to . :;;;;:;:r 11 prior to sample submittal for the following : 0 Ii; R RUSH sample submittal r --t! a:::l en.c !='" for charges and C~er lO(s): ~>;gOi Cl ~ scheduling-See .--, C)/ ~~~ ~ W C. Instruction Page'S! 81 o DW 0 A2LA 8~'l5~ 13 § U Comments: Rea>~T~P _ .. u)ICJ1 « 0 0 C o GSA 0 EDD/EDT(Electronic Data) ~ ~ <= I-ro O "' ..... '" 0 I-c: 5 On ~ POTWIWWTP Fonnat: "'e ",:;:riii « :; ")'::y -.. 1 N O 0 c..~ a; 1 ,\ ..... ( os / a State: LEVEL IV ~ !ij<CI:;r 1'1 W Oi Custody Sea' ry i N o Other: 0 NELAC en >1 W E H Bonles! .. ~r:-.., I ...... (j) 0 Coolers ~ ~~~~~~~~~~~-, __ ~~~ __ ~~~+-_____ j~ Z In~a [£fN SAMPLE IDENTIFICATION Collection Collection MATRIX 1 '" Signature / (Name, Locabon, Interval, etc) Date Time M.re. y N 'Ji~7 :;;·wor ('if~g J-w I"" I~ 2 V'I~:C 2-J-'(j'M IMIO I-W (\ I~ : .vi ~?: -3 12· IQo '1 1 01c3S /-vJ I,) ir----- ~ 6 ~ 7 ~ 8 ~ o 9 % I~ '0 l~h9a2a7.s-? I custOdy "'\"""1,"""" "'t'1Y' I O .. etrme, /fdtJ <7-,rol ) I """""" '" t ..... ), DmeJT1me, S~ "", R d JcY .. ~ (j!}-/",~J2. 2 ·/f·f)" /<G, -V....A-.-M~~rbe "0/1 .... _"'1 .... ' D3l.rnme, () S'gnaI'ro, """''''''''npnn/)' ""om""" Slgna/~" Signed Sample Disposal: Return to Client: Lab Disoosal: I P,q:;,,_c;~ _'L~"";;;' q,z,-) C "" --, ~ In certain circumstances. samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report VISit our web site at www.energylab.comforadditionalinformation.dOlNnloaciable fee schedule, forms, and liTi<.s. Energy Laboratories Inc Workorder Receipt Checklist ~lllliil~ Denison Mines (USA) Corp Login completed by: Edith McPike Reviewed by: Reviewed Date: Shipping container/cooler In good condition? Custody seals Intact on shipping container/cooler? Custody seals Intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample Jabels? Samples In proper container/bottle? Sample containers Intact? Sufficient sample volume for Indicated test? All samples received within holding time? ContalnerfTemp Blank temperature : Waler -VOA vials have Z8ro headspace? Waler -pH acceptable upon receipt? Contact and Corrective Action Comments: None Ye'lil Ves iii Ves 0 Ve'lil Ves iii Ves iii Ves iii Ves iii Ve'lil Ve'liI Ves 0 Ves iii C09020752 Date and Time Received: 2/20/2009 9:30 AM Received by: pb No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier name: Next Day Air Not Present 0 Not Present D Not Present iii No VOA vials submitted 0 Not Applicable 0 ENERGYLABORATORIE5, INC. -2393Sal(Creek Highway(8260I)-Po. Box3258 • Casper, WY82602 ,g~If({g~ lOll Free 888.2350515 • 30123505/5 • Fax 301234.1639 • casper@energylab.com · IYlVwenergylab.com lAliOU/l/C J/U/; \ CLIENT: Project: Denison Mines (USA) Corp Nilrate Sample Delivery Group: C09020752 ORIGINAL SAMPLE SUBMITTAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4'C (t2'C) Date: 2S-Feb-09 CASE NARRATIVE Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable If there Is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is Intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in relurning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS USING EPA 505 Data for Atrazine and Simazine are reported from EPA 525.2, not from EPA 505. Data reported by ELI using EPA method 505 reflects the results for seven individual Aroclors. When the results for all seven are NO (not detectad), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize Its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS ell-b -Energy Laboratorlas, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillatte, WY eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SO eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: US EPA: WY00002; FL-DOH NELAC: E87641; California: 02118CA Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained In this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certlncatlons. All analysis data to be submitted for regulatory enforcement should be certified In the sample state of origin. Please verity ELI's certification coverage by visiting www.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional Information and services visit our web page www.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT July Sampling Event ENERG Y LABORATORIES, INC. ·2393 Sail Creek HighlVay (82601) • Po. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 . casper@energylab.com. IVWlY.energylab.com tAl/OlutTORIES July 30, 2009 Denison Mines (USA) Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C09070693 Project Name: Nitrate ANALYTICAL SUMMARY REPORT Energy Laboratories, Inc. received the following 8 samples for Denison Mines (USA) Corp on 7/1712009 for analysis. -~ . Sample 10 Client Sample 10 Collect Date Receive Date Matrix Test C09070693·001 MW·18 07114/0908:1207/17/09 Aqueous Nitrogen, Nitrate + Nitrite C09070693·002 MW·19 07114/0910:2607/17/09 Aqueous Same As Above C09070693·003 Piez·1 07/14/0909:2507/17/09 Aqueous Same As Above C09070693·004 Piez·2 07/14/0909:4507/17/09 Aqueous Same As Above C09070693·005 Piez·3 07/14/0910:1007/17/09 Aqueous Same As Above C09070693·006 Piez-4 07/14/0908:07 07117/09 Aqueous Same As Above C09070693·007 Piez-5 07/14/0908:52 07117/09 Aqueous Same As Above C09070693·008 Temp Blank 07/14/0910:1007/17/09 Aqueous Temperature As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report. the QA/QC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: ._-- ENERGY LABORATORIES, INC. ·2393 Sail Creek Highway(8260I). p.D. Box 3258 . Casper, W'r'82602 ToII Free888.235.0515 ·307.235.0515· Fax 307.234.1639 • casper@energylab.com .wlYlv.energylab.com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Nitrate Lab 10: C09070693·001 Client Sample 10: MW-18 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nilrale+Nitrite as N ND mg/L Lab 10: C09070693·002 Client Sample 10: MW·19 Matrix: Aqueous Analyses Result Units -.. -, -- MAJOR IONS Nitrogen. Nilrale+Nitrite as N 2.2 mg/L Lab 10: C09070693-003 Client Sample 10 : Piez-1 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nitrale+Nilrile as N 6.6 mg/L Lab 10: C09070693-004 Client Sample 10: Piez-2 Matrix: Aqueous ------~------------------ Analyses MAJOR IONS Nitrogen. Nilrate+Nilrite as N Report RL -Analyte reporting limit. Definitions: QCl. Quality control limit. Result Units 0.5 mgfL Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.2 Qualifiers RL 0.1 Report Date: 07/30109 Collection Date: 0711410908:12 DateReceived: 07/17109 MCU QCL Method Analysis Date I By MCU QCL MCU QCL MCU E353.2 07/22/09 13:261 i_I Collection Date : 0711410910:26 DateReceived: 07117109 Method Analysis Date I By E353.2 0712210913:311 i.1 Collection Date: 0711410909:25 DateReceived: 07117109 Method Analysis Date I By E353.2 07122/09 13:331 i_I Collection Date: 07/14109 09:45 DateReceived: 07117109 QCL Method Analysis Date I By E353.2 0712210913:36 J jal MCl . Maximum contaminant level. NO . Not detected at the reporting limit. ENERGY LABORATORIES, INC. ·2393 Salt Creek Highway (82601) • P.O Box 3258 . Casper. WY 82602 Toll Free 888.2350515 • 307.2350515 • Fax 307.234.1639 • casper@energylab.com • WlYW.energylab.com LABORA TORY ANALYTICAL REPORT Client: Site Name: Lab 10: Denison Mines (USA) Corp Nitrate C09070693-005 Client Sample 10: Piez-3 Matrix: Aqueous Analyses Result Units Qualifiers RL MCU Report Date: 07/30109 Collection Date: 07/14/09 10:10 DateReceived: 07/17/09 QCL Method Analysis Date I By --------~--------- MAJOR IONS Nitrogen, Nitrate+Nilrile as N Lab 10: C09070693-006 Client Sample 10: Piez-4 Matrix: Aqueous Analyses MAJOR IONS Nitrogen, Nilrate+Nitrite as N Lab 10: C09070693-007 Client Sample 10: Piez-5 Matrix: Aqueous Analyses MAJOR IONS Nitrogen, Nitrate+Nitrile as N Lab 10: C09070693·008 Client Sample 10: Temp Blank Matrix: Aqueous ~~-- Analyses PHYSICAL PROPERTIES Temperature Report Definitions: Rl -Analyte reporting limit. Qel-Quality conlrollimit. 0.8 mg/l Result Units 1.8 mg/L Result Un its mg/L Result Units 2.0 'C 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL E353.2 07/22/09 13:461 jal Collection Date: 07114/0908:07 DateReceived: 07/17/09 MCU QCL Method Analysis Dat8 I By MCU 07122109 13:48 / i,1 Collection Date: 07/14/0908:52 DateReceived: 07/17109 QCL Method Analysis Date I By MCU E353.2 07l22/09 13:51/ial Collection Date: 07/14/091 0:10 DateRecelved: 0711 7109 Qel Method Analysis Date I By Et70.1 07/17/09 09: 15 I sec Mel ~ Maximum contaminant level. NO -Not detected at the reporting limit. ENERGYLABORATORIE5, INC .• 23935allCreekHighway(82601j .p.D. Box 3258 . Casper, WY82602 Toll Free 8882350515 • 307.2350515 • Fax 307.234.1639 • casper@energylab.com • wlmenergylab.com Client: Denison Mines (USA) Corp Project: Nitrate I Analyte Method: E353.2 Sample 10: MBLK·l Nitrogen, Nitrate+Nilrite as N Sample 10: LCS·2 Nitrogen. Nitrate +Nilrite as N Sample 10: C09070693'{)04AMS Nitrogen, Nilrate+Nitrite as N Sample 10: C09070693'{)04AMSO Nitrogen, Nilrate+Nitrite as N Qualifiers: Rl . Analyte reporting limit. QA/QC Summary Report Result Units Method Blank NO mglL Laboratory Control Sample 2:47 mg/L Sample Matrix Spike 2.39 mglL Sample Matrix Spike Duplicate 2.47 mg/L Report Date: 07130109 Work Order: C09070693 RL %REC Low Limit High Limit RPD RPDUmit Qual Run: TECHNICON_090722A 0.03 Run: TECHNICON_090722A 0.10 99 90 110 Run: TECHNICON_090722A 0.10 96 90 110 Run: TECHNICON_090722A 0.10 100 90 110 3.3 NO -Not detected at the reporting limit. Batch: R1 21253 07122109 12:43 07/22/09 12:46 07/22109 13:38 07/22/0913:41 10 _.-_It' PLEASE PRINT-Provide as much Information as possible. company~ Project Name, PWS, Permrt, Etc. Sample Origin EPA/State Compliance: JY1. ' • .,..; }Jj:;YAk State: /Jo:/ Yes 0 No 0 ( , )<JJ ;\.,J Report Mail Addre~o . r:!,r-y. yO'i' Contact Name: Phone/Fax: Email: Sampler: (Please Print) ~~,4 P ... IMif bff UZ.} --£",rJ! J a/'~ /. BI"'''(''A 'A~ 1<;YS-1I Invoice Address: J Invoice Contact & Phone: Purchase Order: QuotelBottre Order: /SA, ,f' C;""--'<- Special ReportlFonnats -ELI must be notified &ll!J&!b \'7@O@ ill~@I1!J~ Contact ELI prior to ~(illA UPS ~!O prior to sample submittal for the following: 0 l;; R RUSH sample submittal for charges and Cooler 10(s): eCDcn..l::: [ O;0Il+-:g>~Ot 0 scheduling -See -cnc7l ~ UJ Instruction Page E!:"Ut ~ :r: '0 U Dow DA2LA o""~,,, <.) c: Comments: Recel~p 0c ~ .. 1J51 ::> DGSA D EOO/EOT(Electronic Data) oi!:.-« e ~ >-.!!:! 5 ~ '" orV-,p on~ DpOTWNNVTP c: 5 Fonnat ..8~~I:g :; D State: D LEVEL IV ECi.= <ii « >--t~\O-{'\'*' ,{'Or Y No ~E«lg UJ n; ~"" CuBrody Seal f!! ,N D Other: D NELAC ~ >1 ~ UJ E H ye< Botti .. ' @:;r ~ CI) 0 Coolers B Z ~ Intact G)" SAMPLE IDENTIFICATION Collection Collection MATRtX Signature (Name, Location, Interval, etc.) Date Time Match Y N , 'tfJ/G liltv-/ 'i I f'I~' 07 X o ZS('2. 1-vJ ,~ 2 M 1/11 -10/ / I01..~ / I 3 Rl~ -I ()1J5" > I 1:= , vl'n .... 1, \ flt'l> I, , \" 5 i/~ -") ) 1010 ) Iv 6 "t ..... L / otto 1 ( ~ 7 "t1--5 y.-yY .QCj &Sl /-<0 1')( ~ , , ~ 0 ':6.. '~ '0 1"'f'lf){01!£J' /1 . custody R~""JZ;. by (""'(4;,. 0"76 17 jOl(S J~otu~ Received by (prinI): atemme: Signature: ","If\.. R-'1'1f"f(" 7 -t1 Record RelinqulSh6d by (print): Oate/T1me: /' signature: Received by (print): Oatefnme: Signature: MUST be .". Signed Sample Disposal: Return to Client: Lab Disposal: I no,.":! ~y L:;-lOrG"'~ ;:efT7!/7IcR cr /~7?~- This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. anaIYSi~ted. VISit our web site at www.energylab.com for additional information, downloadable fee schedule, forms, and links. Energy Laboratories Inc Workorder Receipt Checklist illlllllll~lllll~ Denison Mines (USA) Corp C09070693 Login completed by: Edith McPike Date and Time Rece ived: 7/17/20099:15 AM Reviewed by: Received by: al Reviewed Date: Carrier name: Next Day Air Shipping containerfcooler in good condition? Custody seals intact on shipping conlainerlcooler? Custody seals inlact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? ContainerlTemp Blank temperature: Water -VOA vials have zero headspace? Water· pH acceptable upon receipt? Contact and Corrective Action Comments: None Yes Ii! Yes Ii! Yes 0 Yes Ii! Yes Ii! Yes Ii! Yes Ii! Yes Ii! Yes Ii! Yes Ii! Yes 0 Yes Ii! No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Not Present 0 Not Present 0 Not Present 0" No VOA vials submitted 0' Nol Applicable 0 ENERGY LABORATORIES, INC. ·2393 Sail Creek Highway (82601). Po. Box 3258 . Casper. WY82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.C()m • wWlY.energylab.C()m CLIENT: Denison Mines (USA) Corp Date: 30·Ju/-09 Project: Nitrate CASE NARRATIVE Sample Delivery Group: C09070693 ORIGINAL SAMPLE SUBMITIAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4°C (±20C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYStS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLlD SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZtNE, SIMAZtNE AND PCB ANALYSIS USING EPA 505 Data for Atrazine and Simazine are reported from EPA 525.2, not from EPA 505. Data reported by ELI using EPA method 505 reflects the results for seven individual Aroclors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYStS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qual ified contract laboratories for thi s selVice. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, tnc. -Gillette, WY eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SO eli-t -Energy Laboratories, Inc. -College Station , TX CERTIFICATIONS: USEPA: WY00002, Radiochemical WY00937; FL-DOH NELAC: E87641, Radiochemical E871017; California: 02118CA; Oregon: WY200001 ; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities . Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify ELI's certification coverage by visiting WINW .energylab.com ELI appreciates the opportunity to provide you with this analytical selVice. For additional information and services visit our web page WINW.energylab.com. THIS IS THE FtNAL PAGE OF THE LABORATORY ANALYTICAL REPORT --.. _-------- ENERGY LABORATORIES, INC. ·2393 Salt Creek Highway (82601) • Po. Box 3258 • Casper. WY 82602 Toll Free 888.235.0515 • 301235.0515 • Fax 301234.1639 • casper@energylab.com . wWlv.energylab.com ANALYTICAL SUMMARY REPORT August 03. 2009 Denison Mines (USA) Corp 6425 S Hwy 191 Btanding. UT 84511 Workorder No.: C09070903 Project Name: Nitrate Energy Laboratories. Inc. received the following 8 samples for Denison Mines (USA) Corp on 7/23/2009 for analysis. Sample 10 Client Sample 10 Coliect Date Receive Oate Matrix Test C09070903·001 TWN·1 07/21/0913:2307/23/09 Aqueous Nitrogen, Nitrate + Nitrite C09070903·002 TWN·2 07/21/0913:3407/23/09 Aqueous Same As Above C09070903·003 TWN·3 07/21/0913:55 07/23/09 Aqueous Same As Above C09070903·004 TWN·4 07/2110913:4307/23/09 Aqueous Same As Above C09070903·005 TWN·60 07/21/0909:30 07/23/09 Aqueous Same As Above C09070903·006 TWN·63 07/21/0909:48 07/23/09 Aqueous Same As Above C09070903·007 TWN·64 07/21 /0911 :4507/23/09 Aqueous Same As Above C09070903·008 TWN·65 07/2110913:43 07/23/09 Aqueous Same As Above As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the ONQC Summary Report. or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: ENERG Y LABORATORIES, INC. ·2393 Sail Creek Highway (82601) . p.o. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com . WWlv.energylab.com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Nitrate Lab 10: C09070903·001 Client Sample 10 : TWN-1 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen. Nitrate+Nitrile as N 0.4 mg/L Lab 10 : C09070903-002 Client Sample 10: TWN-2 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nilrate+Nitrile as N 25.0 mglL Lab 10 : C09070903-003 Client Sample 10: TWN-3 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nitrate+Nilrile as N 25.3 mglL Lab 10: C09070903-004 Client Sample 10: TWN-4 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nitrate+Nitrite as N 0.5 mglL Report RL -Analyte reporting limit. Definitions: eeL -Quality controllimil. o . RL increased due to sample matrix interference. Qualifiers Rl 0.1 Qualifiers Rl D 0.3 Qualifiers RL D 0.3 Qualifiers Rl 0.1 Report Date: 08/03/09 Collection Date: 07/2 110913:23 DateRece ived: 07/23/09 MCLJ eCl Mothod Analysis Date I By MCLJ eCl MCLJ E353.2 07/24/09 11 :23 1 jal Collection Date: 07/21/09 13:34 DateReceived: 07/23/09 Method Analysis Date I By E353.2 07/24/09 11:25 1 ial Collection Date: 07/21 /09 13:55 DateRecelved: 07/23/09 eCl Mothod Analysis Date f By MCLJ E353.2 07/31/09 14:36 1 ial Collection Date: 07/21/0913:43 DateReceived: 07/23/09 OCL Method Analysis Date I By E353.2 07/3110914:391 ial MeL -Maximum contaminant level. NO . Not detected at the reporting limit. ENERGYLABORATORIES, INC .• 2393 Sail Creek Highway (82601) .p.o. 8ox3258 • Casper. WY82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com • wwwenergylab.com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Nilrate Lab 10: C09070903-005 Client Sample 10: TWN-60 Matrix: Aqueous Analyses MAJOR IONS Nitrogen. Nitrate+Nitrile as N Lab 10: C09070903-006 Client Sample 10: TWN-63 Matrix: Aqueous Analyses MAJOR IONS Nitrogen, Nitrate+Nitrite as N Lab 10: C09070903-007 Client Sample 10: TWN-64 Matrix: Aqueous Analyses MAJOR IONS Nitrogen, Nitrale+Nitrite as N Lab 10: C09070903-008 Client Sample 10: TWN-65 Matrix: Aqueous Analyses MAJOR IONS Nitrogen. Nitrale+Nitrite as N Report Definitions: RL . Analyte reporting limit. QCL -Quality controllimil. Result Units NO mg/L Result Units NO mglL Result Units ND mg/L Result Units 0.5 mg/l Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 MCW Report Date: 08/03/09 Collection Date: 07 /2 1/0909:30 DateRecelved: 07/23/09 QCL Method Analysis Oato I By MCW E353.2 07131/0914:41/ ial Collection Date: 07/21 /0909:48 DateRecelved: 07/23/09 QCL Melhod Analysis Date I By E353.2 07/31/09 14:44 / ial Collection Date: 07/21/09 11 :45 DateRecelved: 07123/09 MCW Qel Method Analysis Date I By E353.2 07/31/0914:54/ ial Collection Date: 07/21/0913:43 DateRecelved: 07/23/09 MCW QCL Melhod Analysis Dale I By E353.2 07/31/0914:56 / jat Mel · Ma ximum contaminant level. NO . Not detected at the reporting limit. ENERGY LABORATORIES, INC. ·2393 Sail Creek Highway (82601) • PO Box 3258 • Casper, WY82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 . casper@energylab.com • wWI"energylab.com QAfQC Summary Report Client: Denison Mines (USA) Corp Report Dale: 08103109 Project: Nitrate Work Order: C09070903 Analyte Result Units RL %REC Low Limit High Limit RPO RPOLimlt Qual Method: E353.2 Balch: R121364 Sample 10: MBLK·1 Method Blank Run: TECHNICON_090724A 0712410910:13 Nitrogen, Nitrate+Nitrile as N NO mg/L 0.03 Sample 10; LCS-2 Laboratory Control Sample Run: TECHNICON_090724A 0712410910:15 Nitrogen, Nitrale+Niuite as N 2.53 mg/L 0.10 101 90 110 Sample 10: C09070793-002CMS Sample Matrix Spike Run: TECHNICON_090724A 07124/09 11 :08 Nitrogen. Nitrate+Nitrile as N 2.74 mg/l 0.10 110 gO 110 Sample to: C09070793-002CMSO Sample Matrix Spike Duplicate Run: TECHNICON_090724A 07/24/09 11 : 10 Nitrogen, Nitrate+Nilrite as N 2.71 m9/L 0.10 108 90 110 1.1 10 Method: E353.2 Batch: R121744 Sample 10: MBLK-l Method Blank Run: TECHNICON_090731A 0713110914:29 Nitrogen, Nitrate+Nitrite as N NO mg/L 0.03 Sample 10: LCS-2 Laboratory Control Sample Run: TECHNICON_090731A 0713110914:31 Nitrogen, Nitrate+NitIite as N 2.57 mglL 0.10 103 90 110 Sample 10: C09070903-004AMS Sample Matrix Spike Run: TECHNICON_090731A 07131/0914:46 Nitrogen, Nitrate+Nitrite as N 2.55 mg/L 0.10 102 90 110 Sample 10: C09070903-004AMS Sample Matrix Spike Run: TECHNICON_090731A 07/3110914:49 Nitrogen, Nitrate+Nitrite as N 2.58 mg/L 0.10 104 90 110 Sample 10: C09071061-002CMSO Sample Matrix Spike Duplicate Run: TECHNICON_090731A 07/31/09 15:24 Nitrogen, Nilrale+Nilrite as N 2.21 mglL 0.10 103 90 110 2.7 10 Qualifiers: RL -Analyie reporting limit. NO -Not detected al the reporting limit. AI ,I'l;!' ~>i"'I~'~'I."1 ,rI Chain of Custody and Analytical Request Record pagei Of + n~me: c \ )PfliSoN rrll.:r~j Report Mail A~~O:~ M 12L .. J Ide; IJ:( <i5'I5/1 Invoice Address: -7 'T _<;t:l ... ~ Special ReporVFormats -ELI must be notified prior to sample submittal for the following: Dow DGSA D POTWIWINTP D State: ___ _ D Other: ___ _ SAMPLE IDENTIFICATION DA2LA D EOO/EOT(Eleclrooic Dala) Format: D LEVEL'::-IV-,----- D NELAC (Name, Location, Interval, etc.) Date I' Time PLEASE PRINT-Provide as much information as Project Name, PWS, Permit, Etc. £~TL £:meUkeL Pho~;~22LI Invoidi Contact & Phone: o ~ film ",..c. ~>;gOI °Cii CI) as ~ ~~U5~ 0..:'8 '" ~ . '~'ffi, o :RQ) c: .... ::0-.-0 ~~~ritl Ea~Q5 ~ E":'g> ~ >1 IUI.II. TRllC j ~ 3", &llM.\l1, Y1@O@ ill~®(!JJ~@,@) o ~ w t:. I '0 () § « e f: ~ « .= w 'iii W E (/) 0 z = Origin State: tA.r Email: Yes 0 No 0 Sam pier: (Please Print) k_Jf! J2~g Purchase Order: = Orr/sr: Contact ELI prior to Shl~"1i R I RUSH sample submittal I---;.'S'JS LJ"tt1:'.:-' ----I for charges and COOler 10(5): scheduling -See U Instruction Page Comments: RltUI:;f °c On Ice: 5 ~ H I cu,;ro;;;. Seal @ N Bottl"1 B 0 Coolers ~ Intact (l) N 1 Signature 6. N Match V 'TIN"', I 172(,(11 11)1"S It-vJ 1"1 1 1 1 1 1 1 1 1 1 1 I~ ~T~~~i. I / I r3~1 '!-w f~1 I I I I I I I I 1ll-.. _·-····· ~ ~ ~-rN"'-~ r 13/~W ___ ! I$SJ~ I ) 1 1\~m~1111 1 1 11111 1 (~D'dillll I 1'T!AIN:6tf 1--( Ifiq5: I/-w rtl 11-,1-[-1 I I I I '1 -I~ l:i£~-k~S;. ~'-_v 1 1~~J3lf3~-W IXI I I I I I I I I I I I~ll---~ '0 1\,)"'--I h I I I I I I I I I I I'" Received by (print): DatelTrme: signature: -6 1 Record Received by (print): Oatemme: Signature: ~~=!_~e~--------------------~-----------t~~~~'---~~~7-:JS~-Y~~~? Sample Disposal: Return to Client: ____ _ .' r / In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysiSA'equested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information, downloadable fee schedule, forms, and links. Energy Laboratories Inc Workorder Receipt Checklist Denison Mines (USA) Corp Login completed by: Corinne Wagner Reviewed by: Reviewed Date: Shipping containerfcooter in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/boll Ie? Sample containers intact? Sufficient sample volume for indicated test? All samples received with in holding time? ContainerfTemp Blank temperature: Water· VOA vials have zero headspace? Water · pH acceptable upon receipt? Contact and Corrective Action Comments: None Ves 0 Ves 0 Ves D Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 2'C On Ice Ves D Ves 0 C09070903 Date and Time Received: 7/23/20099:30 AM Received by: al No D No D No D No D No D No D No D No D No D No D No D No D Carrier name: Next Day Air Not Present 0 Not Present 0 Not Present 0" No VOA vials submitted 0 Nol Applicable D ENERGY LABORA rORIES, INC. ·2393 Sail Creek Highway (82601) . Po. Box 3258 . Casper, WY 82602 roll Free 888.235.0515 . 307235.0515 . Fax 307234.1639 . casper@energylab.com . lvom energylab. com CLIENT: Project: Denison Mines (USA) Corp Nitrate Sample Delivery Group: C09070903 ORIGINAL SAMPLE SUBMITIAL(S) All original sample submitlals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4°C (±2°C) Date: 03-Aug-09 CASE NARRATIVE Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS USING EPA 505 Data for Atrazine and Simazine are reported from EPA 525.2, not from EPA 505. Data reported by ELI using EPA method 505 reflects the results for seven individual Aroclors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring . SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gilletle, WY eli-h -Energy Laboratories, Inc. -Helena. MT eli-r -Energy Laboratories, Inc. -Rapid City, SD eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: USEPA: WY00002, Radiochemical WY00937; FL-DOH NELAC: E87641 , Radiochemical E871 017; California: 02118CA; Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER.wy certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitled for regulatory enforcement should be certified in the sample state of origin. Please verify ELI's certification coverage by visiting www.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional infonnation and services visit our web page www.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT ENERGY LABORATORIES, INC. ·2393 Sail Creek Highway (82601)· p.o. Box 3258 . Casper. WY 82602 Toll Free 888.235.0515 • 307235.0515 • Fax 307234.1639 • casper@energylab.com . """"energylab.com ANALYTICAL SUMMARY REPORT July 30. 2009 Denison Mines (USA) Corp 6425 S Hwy 191 Blanding. UT 84511 Workorder No.: C09070691 Project Name: Chloride Energy Laboratories. Inc. received the following 7 samples for Denison Mines (USA) Corp on 7/1712009 for analysis. Sample 10 Client Sample 10 Collect Date Receive Oate Matrix Test C09070691-001 MW 18 07/14/0908:1207/17/09 Aqueous E300.0 Anions C09070691-002 MW 19 07114/0910:26 07/17109 Aqueous Same As Above C09070691-003 Piez-1 07114/0909:25 07/17/09 Aqueous Same As Above C09070691-004 Piez-2 07/14/0909:4507/17/09 Aqueous Same As Above C09070691-005 Piez-3 07/14/0910:1007/17109 Aqueous Same As Above C09070691-006 Piez-4 07/14/0908:07 07117109 Aqueous Same As Above ----- C09070691-007 Piez-5 07/14/0908:52 07/17109 Aqueous Same As Above As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, th e QA/QC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: ~fl4 Steven E. Carlston Technical Director ENERG Y LABORATORIES, INC. ·2393 Salt Creek Highway (82601) • P.O Box 3258 . Casper, WI' 82602 Toll Free 888.235.0515 • 307235.0515 • Fax 307234.1639 • casper@energylab.com · wwwenergylab.com LASORA TORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Chloride Lab 10: C09070691·001 Client Sample 10 : MW 18 Matrix: Analyses MAJOR IONS Chloride Lab 10: Aqueous ---- C09070691·002 Client Sample 10: MW 19 Matrix: Aqueous Analyses ------- MAJOR IONS Chloride Lab 10: C09070691 ·003 Client Sample 10: Piez·1 Matrix: Analyses MAJOR IONS Chloride Lab 10: Aqueous C09070691·004 Client Sample 10: Piez·2 Matrix: Aqueous Analyses ------- MAJOR IONS Chloride Report Rl . Analyle reporting limit. Definitions: aCL· Quality control limit. Result Units 51 mg/L Result Units 24 mg/L Result Units 60 mg/L Result Units 7 mg/L Qualifiers RL Qualifiers RL Qualifiers RL Qualifiers RL Report Date: 07/30109 Collection Date: 07/14/0908:12 DateReceived: 07/17/09 MCU QCL Method Analysis Date I By E300.0 07l21/0923:16/1jl Collection Date: 07/14/0910:26 DateRecelved: 07/17109 MCU eeL Method Analysis Date I By E300.0 07/2110923:31 I ljl Collection Date: 07/14/0909:25 DateRecelved: 07/17109 MCU QCL Method Analysis Date I By E300.0 07121/0923:47 I Ijl Collection Date: 07/14/0909:45 DateRecelved: 07/17109 MCU QCL Method Analysis Date I By E300.0 07/22/09 00:02 I Ijl MeL · Maximum contaminant level. ND -Not deleded at the reporting limit. ENERG Y LASORA TORIES, INC .• 2393 Sail Creek Highway (82601) . Po. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234. 1639 • casper@energylab.com . ww .. energylab.com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Chloride Lab ID: C09070691-005 Client Sample ID: Piez·3 Matrix: . ____ A_q_ue.::.ou.::.s~ __ _ Analyses MAJOR IONS Chloride Lab ID: C09070691-006 Client Sample ID: Piez-4 Matrix.: _______ A.::queo~u.::.s~ __ Ana lyses MAJOR IONS Chloride Lab ID: C09070691-007 Client Sample ID: Piez·5 Result Units 12 mg/L Result Units 46 mg/L Matrix: Aqueous .~~~~~~ ------------ Analyses MAJOR IONS Chloride Report Definitions: RL . Analyte reporting limit. ael . Quality control limit. Result Units t8 mg/L Qualifiers RL Qualifiers RL Qualifiers RL MCU Report Date: 07/30109 Collection Date: 07/14/0910:10 DateReceived: 07/17/09 QCL Method Analysis Date I By .~------ E300.0 07122/09 01 :04 1 Iii Collection Date: 07/14/0908:07 DateReceived: 07/17/09 MCU QCL Method Analysis Date I By E300.0 0712210901 :50 /Iii Collection Date: 07/14/0908:52 DateReceived: 07/17/09 MCU QCL Method Analysis Date I By E300.0 07/2210902:051 Iii MeL· Maximum contaminant level. NO . Not detected at the reporting limit. ENERG Y LABORATORIES, INC. ·2393 Sail Creek Highway (82601) . P.o. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 3072350515 . Fax 307234.1639 • casper@energylab.com · WWlY.energylab.com QA/QC Summary Report Client: Denison Mines (USA) Corp Report Date: 07/30109 Project: Chloride Work Order: C09070691 .-! A""lyte Result Units RL %REC Low Limit High Limit RPO RPDLimit Qual I Method: E300.0 Balch: R1 21271 Sample 10: LCS Laboratory Control Sample Run: IC1-C_090721A 07/21/09 16:50 Chloride 9.49 mg/L 1.0 95 90 110 Sample 10: MBLK Method Blank Run: IC1-C_090721A 0712 1/0917:21 Chloride NO mg/L 0.04 Sample 10: C09070650-001AMS Sample Matrix Spike Run: IC1-C_090721A 07/21/0921 :28 Chloride 73.5 mg/L 1.0 133 90 110 S Sample 10: C09070650~01AMSO Sample Matrix Spike Duplicate Run: IC1-C_090721A 07/2110921 :43 Chloride 73.7 mg/L 1.0 134 90 110 0.3 20 S Sample 10: C09070691~05AMS Sample Matrix Spike Run: IC1-C_090721A 07/22/0901:19 Chloride 62.7 mg/L 1.0 103 90 110 Sample 10: C09070691~05AMSO Sample Matrix Spike Duplicate Run: IC1-C_090721A 07/22/09 01 :34 Chloride 62.7 mg/L 1.0 103 90 110 0.1 20 Qualifiers: RL . Analyte reporting limit. NO -Not detected at the reporting limit. 5 -Spike recovery outside of advisory limits. I /1{.( )"'~l/( 1/,'1, '> Chain of Custody and Analytical Request Record page_I_oIL PLEASE PRINT-Provide as much Information as I "Yd"Y~ ~!.NI~CN «l,Ne Project Name, PWS~Permit, Etc. "ti,e Origin State: ~,---Yes 0 1,}"",dll'-'t::. No 0 Report Mail .~ .._--/t. friJr c,a .-J~ ~~ ;2~:me:tZk/ p;;~?z/ Email: Sampler: (Please Print) . a· t..J/X. /J/ </'{~I/ /<'/".I .. "" D Invoice Address: f Invoiae Contact & Phone: ~ Order: ~ Order: <;r. "S. Special Report/Formats -ELI must be notified prior to sample submittal for the following: Contact Ell prior to RUSH sample submittal for charges and scheduling -See Instruction Page Shipped by: DDW o GSA o POTWNlJlNTP DA2LA o EDD/EDT(Electronic Oata) o ~ t?m(l)~ ~>;gOI scn~ i;' C::!:(}j; (I) o<'j5 ~ ~ ".(/)1·2 o & ~IDI ... »$ c:: U Q VQv"\~ "'fI' ,.,-n", ::J ·c Comments: o State: ___ _ o Other: ___ _ Fonnat:.::-;-___ _ o LEVEL IV o NELAC QI~ co 0 .D Q)~r= Ea.. .... ~ ~ E<CI& z'" ., en >1 ~\"i,{:v'- 1 '= ~ N ~ ""e-t--~ W v \ n ~~:~ B(0' SAMPLE IDENTIFICATION Collection MATRIX ~ I I I I I I I I I Z I ~'{\ ;,;::u"' ~ N (Name, Location, Interval, etc.) Date ~ Match (DN MW/K _~7I'for ~~/211-v0IXI I I I I I I I I I I I ~dK-.Jv/l I~ 2 (vi &Ii / '1 I) , 1 }(l2~ 1 J 1)( 1 1 1 1 1 1 1 1 1 1 1 I r~ I: ~::-~ I ) I~~ ~ I~ 11111111111 I ~ '6 nffe -tf 1 / lagn 1 ( 1 x liii 1 1 1 1 1 1 1 1 I~ 7 ~,,~ -5' 17'-1'/,01 It7tS.2I/~vJ I')L 8 , 10 VI ;>~" s '" I~ 1~'&O/t.Jt..9/ I Custody jt'ls' -...-,,(,",,), Record Received by (print): DatelTime: Signature: MUST be ...--:? Signed Sam (e Dis osal: Return to Client: Lab Dis osal: In certain circumstances. samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the ;:;;SiS requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energyJab.comfor additional information, downloadable fee schedule. forms, and links. Energy Laboratories Inc Workorder Receipt Checklist Denison Mines (USA) Corp Login completed by: Edith McPike Reviewed by: Reviewed Date: Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample boHles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? ConlainerfTemp Blank temperature: Waler· VOA vials have zero heads pace? Water -pH acceptable upon receipt? Contact and Corrective Action Comments: None Ves III Ves III Ves 0 Ves III Ves III Ves III Ves III Ves III Ves III Ves III Ves 0 Ves III C09070691 Date and Time Received: 7/17/20099:15 AM Received by: al No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier name: Next Day Air Not Present 0 Not Present D Not Present 0 No VOA vials submitted 0" Not Applicable 0 ENERGYLABORATORIE5, INC .• 2393 Sail Creek Highway (82601) . Po. Box3258 • Casper, WY82602 liJll Free 888.2350515 . 307235.0515 • Fax 307234.1639 • casper@energylab.com . www.energylab.com CLIENT: Project: Denison Mines (USA) Corp Chloride Sample Delivery Group: C09070691 ORIGINAL SAMPLE SUBMITTAL(S) All original sample submit1als have been returned with the data pa ckage. SAMPLE TEMPERATURE COMPLIANCE: 4'C (±2'C) Date: 30-Ju/-09 CASE NARRATIVE Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gros s beta is intended as a drinking water method for low TDS waters . Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the labora tory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE. SIMAZINE AND PCB ANALYSIS USING EPA 505 Data for Atrazine and Simazine are reported from EPA 525.2. not from EPA 505. Data reported by ELI using EPA melhod 505 reflects the resu lts for seven individual Aroclors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so. ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories. Inc. -Billings. MT eli-g -Energy Laboratories , Inc. -Gillette, WY eli-h -Energy Laboratories , Inc. -Helena, MT eli-r -Energy Laboratories. Inc. -Rapid City. SD eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: USEPA: WY00002. Radiochemical WY00937; FL-DOH NELAC: E87641. Radiochemical E871017; California: 02118CA; Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES. INC. -CASPER.WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these ce rtificat ions. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify ELI's certification coverage by visiting WVoNI.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page ww...v.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT August Sampling Event ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (8260 I) . P.O Box 3258 . Casper. W'r' 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com • www.energylab.com ANALYTICAL SUMMARY REPORT AU9uSt31,2009 Denison Mines (USA) Corp 6425 S Hwy 191 Blandin9, UT 84511 Workorder No.: C09081076 Project Name: Nitrate Initial Energy Labora tories, Inc. re ceived the following 6 samples for Denison Mines (USA) Corp on 8/2 8/2009 for analysis. Sample 10 Client Sample 10 Collect Date Receive Oate Matrix Te.t C09081076-001 TWN-5 08/27/0906:40 08/2 8/09 Aqueous Nitrogen, Nitrate + Nitrite C09081076·002 TWN-6 08/27/0906:57 08/2 8/09 Aqueous Same As Above C09081076-003 TWN-7 08/27/0906:25 08/28/09 Aqueous Same As Above C09081076-004 TWN-8 08/27/0907:06 08/2 8/09 Aqueous Same As Above C09081076-005 TWN-9 08/27/0907:27 08/2 8/09 Aqueous Same As Above C09081076-006 TWN-10 08/27/0907:1508/28/09 Aqueous Same As Above As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: ENERGY LABORATORIES, INC. ·2393 SalfCreek Highway (82601). PO Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@ener9ylab.com . wmv.energylab.com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Nitrate Initial lab 10: e09081076·001 Client Sample 10: TWN·5 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nitrate+Nitrite as N 0.22 mgll lab 10: e09081076·002 Client Sample 10: TWN·6 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen , Nitrate+Nitrite as N 3.2 mgll lab 10: e09081 076·003 Client Sample 10: TWN·7 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nilrale+Nilrite as N NO mg/l Lab 10: e09081076-004 Client Sample 10: TWN-8 Matrix: Aqueous Analyses Result Units MAJOR tONS Nitrogen, Nitrale+Nilrile as N NO mg/L Report RL • Analyte reporting limit. Definitions: QCL . Quality control limit. Qualifiers Rl 0.10 Qualifiers Rl 0.10 Qualifiers Rl 0.10 Qualifiers Rl 0.10 Report Date: 08131 109 Collection Date: 0812710906:40 DateReceived: 08128109 MCU QCl Method Analysis Date I By MCU E353.2 08131109 11 :331 i_I Collection Date: 08/2710906:57 DateRecelved: 08/28109 Qel Method Analysis Date I By MCU E353.2 08131/O9 11:35 1 i_I Collection Date: 08127/0906:25 DateReceived: 08128109 Qel Method Analysis Data I By MCU E353.2 0813,/09,,:38 I i_1 Collection Date: 08/2710907:06 DateRecelved: 08/28109 ael Method Analysis Date I By E353.2 08/31109 11 :40 I ja! Me l -Maximum contaminant level. ND - Not detected at the reporting limit. ENERG YLABORA TORIE5, INC .• 2393 Sail CreekHighway(82801j .P,o. 8ox3258 • Casper. WY82802 liJII Free 888.235.0515 • 307.235.0515 • Fax 307.234.1839 • casper@energylab.com . wwwenergylab.com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Nitrate Initial Lab 10: C09081 076-005 Client Sample 10: TWN-9 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nitrale+Nilrite as N 9.3 mg/L Lab 10: C09081076-006 Client Sample 10: TWN-10 Matrix: Aqueous Analyses Result Units MAJOR IONS Nitrogen, Nitrate+Nitrite as N 1.1 mg/L Report RL -Analyte reporting limit. Definitions: ael -Quality conlrol limit. Qualifiers RL 0.15 Qualifiers RL 0.10 MCU Report Date: 08/31/09 Collection Date: 08/2710907:27 DateReceived: 08/28/09 ael Method Analysis Date I By MCU E353.2 08/31109 11 :50 1 ial Collection Date: 08/2710907:15 DateRecelved: 08/28/09 QeL Method Analysis Date I By E353.2 08/31/0911:53 /ial MeL -Maximum contaminant level. NO -Not detected at the reporting limit. ENERGY LABORATORIES, INC. ·2393 Sah Creek Highway (82601) • po. Box 3258 . Casper. WY82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com . ww,"energylab.com Client: Denison Mines (USA) Corp Project: Nitrate Initial Analyte Method: E353.2 Sample 10 : MBlK·1 Nitrogen, Nitrate+Nitrile as N Sample 10: LCS-2 Nitrogen, Nitrate+Nitrite as N Sample 10: C09081076-004AMS Nitrogen, Nilrate+Nitrite as N Sample 10: C090S1076·004AMSO Nitrogen. Nitrate+Nitrite as N Qualifiers: RL -An aJyte reporting limit. oAloe Summary Report Result Units Method Blank NO mglL Laboratory Control Sample 2.5 mglL Sample Matrix Spike 2.1 mglL Sample Matrix Spike Duplicate 2.2 mg/L Report Date: 08/31/09 Work Order: C09081076 Rl %REC Low limit High limit RPD RPDlimit Qual Batch: R123095 Run: TECHNICON_090B31A 0813110909:30 0.03 Run: TECHNICON_090B31A 0813110909:33 0.10 102 90 110 Run: TECHNICON_090B31A 08131/09 11:43 0.10 107 90 110 Run: TECHNICON_090B3 1A 08131109 11:45 0.10 l OB 90 11 0 NO -Not detected at the reporting limit. IUird Chain of Custody and Analytical Request Record Page -.L-. of L . 'erR_at-p·UlIi' ,,"~ .. , ,Uf I\J i~1-l {VI ,"",vt<:S Report Mail AO~:SJ. G~ G;01 t2.L._.J~ u..T 'js'lS-// Invoice / Q Special Report/Formats: Dow D POTWNVWTP D State: ___ _ D Other: ___ _ D EOO/EOT(Eleclron;c D.,.) Format: . .".,. ___ _ D LEVEL IV D NELAC PI ~.6.C::'" PRINT (Provide as much information as Dossible.l Project Name. PWS, Perm;t, Etc. Sample Origin nee NPlrlJk_ _Lv·,t,J State I 6 Yes 0 No 0 Email: 7,Z~:ameD~l/ Ph;;;. 72 Z ( Sampler: (Please Prinl) 12t<...! 12J._ / e Order: Order: Contact ELI prior to IppCl y RUSH sample submittal ~ (J. for charges and Cooler ID(s" scheduling -See /) • Instruction Page ( '.1, t7A Comments: I ReceiptTcmp L.{ 'c I 0, Ice: [ji N ~Jb,U,L~:,~ If 'n'm l ~HO I /-{/J l'il I I I I I I I I I I I I~ I 2 T~f\I --t:, 1-I . 1 iJh,C;1-1 J I~ I I~ I:;:~~i I () I ~~f I ) I{I I II II I I II I I il------I I: iZz:,3 ... --1 ~.A.o7 1 W,} I /-~ I~I I I I 11 1 I I I II 3i 1 7 ~- I:, i I I 11 111 1 111 1 11 I L~I I Custody Received by (print): DatefTime: Signa Record Received by (print): Oolamme: Signature: MUSTbe,~ ____________________ ~ __________ ~~~~~~ __ ~~ ________ ~~~~~~~ a lme'~ Signed Sample Disoosal: Return to Client: Lab DisDosal: 'IYiJ~ In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in ord er to complete the analysis r~~ This serves as notice of th is possibility. All sub-contract data will be clearly notated on your analytical report. T~' Visit our web site at www.energylab.com for additional information. downloadable fee schedule, forms, and links. Energy Laboratories Inc Workorder Receipt Checklist 1111111111~lill Denison Mines (USA) Corp C09081 076 Login compleled by: Kimberly Humiston Date and Time Received: 8/28/2009 9:30 AM Reviewed by: Received by: al Reviewed Date: Carrier name: Next Day Air Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? ContainerfTemp Blank temperature: Water -VOA vials have zero headspace? Water· pH acceptable upon receipt? Contact and Corrective Action Comments: None Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Not Present 0 Not Present 0 Not Present 0 No VOA vials submitted 0" Not Applicable 0 ENERGY LABORATORIES, INC. ·2393 Salt Creek Highway (82601) • PO Box 3258 . Casper. WI' 82602 TOil Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com . wwwenergylab.com CLIENT: Project: Denison Mines (USA) Corp Nitrate Initial Sample Delivery Group: C09081076 ORIGINAL SAMPLE SUBMITTAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4'C (±2'C) Date: 31-Aug-09 CASE NARRATIVE Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recomm ended delay between end of exposure to beginning of counting should not exceed 8 days . SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB data reported by ELI reflects th e resu lts for seven individual Arociors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratori es will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories. Inc. -Gillette, WY eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SO eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: USEPA: WY00002. Radiochemical WY00937; FL-DOH NELAC: E87641. Radiochemical E871017: California: 02118CA; Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The resulls of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES. INC. -CASPER,WY certifies that certain method selections contained in this report meet requiremenls as set forth by the above accrediling authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify Ell's certification coverage by visiting WVo/IN.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page www.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT 1\356782224 Inl ellia liona l urani um 12 29 1\'1 P m 12~22-2009 ENERG Y LABORATORIE$, INC •• 2393 $all Creek Highway (8260 I) • P.D. 80, .1258 • Casper, WY 82602 Toll Free 888.235.0515 .: ?35.0515 · Fax 307.234.1639 • casper@energyl( 'm • www.energylab.com , . ANALYTICAL SUMMARY REPORT September 04.2009 Denison Mines (USA) Corp 6425 S Hwy 191 Btanding. UT 84511 Workorder No.: C09081078 Project Name: Chloride Inv. Initial Energy Laboratories. Inc. received the following 6 samples for Denison Mines (USA) Corp on 8/28/2009 for analysis. Sample 10 Client Sample 10 Collect Date Receive Date Matrix Test C09081078-001 TWN-5 08/27/0906:40 08/28/09 Aqueous Chloride C09081078-002 TWN-6 08/27/0906:57 08/28/09 Aqueous Same As Above C09081078-003 TWN-7 08/27/0906:25 08/28/09 Aqueous Same As Above C09081078-004 TWN-8 08/27/0907:06 08/28/09 Aqueous Same As Above C09081078-005 TWN-9 08/27/0907:27 08/28/09 Aqueous Same As Above C09081078-006 TWN-10 08/27/0907:1508/28/09 Aqueous Same As Above As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QAJQC Summary Report. or the Case Narrative. If you have any questions regarding Ihese tests results, please call. Report Approved By: Stephanie D_ Waldrop Reporting Supervisor 31 /37 4356782224 Inter natrona I ur allIum 12 29·55 P ttl 12-22-2009 ENERli Y LABORATORIES, INC •• 2393 SaH Creek Higillvay (826'01) • Po. E!P< 3258 • Casper, WY 82602 Toll Free 888.235.0515 • ( '°35.0515 ' Fax 301.234.1639 • casper@energyZ ·,m· www.energylab,com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Chloride Inv. Initial Lab 10: C09081078-001 Client Sample 10 : TWN-s Matrix: Analyses MAJOR iONS Chloride Lab 10: Aqueous C09081078-002 Client Sample ID: TWN-6 Matri x: Analyses MAJOR IONS Chloride Lab 10: Client Sample 10: Matrix: Analyses MAJOR IONS Chloride Lab 10: Client Sample 10: Matrix: Ana lyses MAJOR IONS Chloride Aqueous C09081078-003 TWN-7 Aqueous C09081 078-004 TWN-8 Aqueous Report RL -Analyte reporting limit. Definitions: OCL -Quality control limil. Result Units 42 mg/L Result Units 32 mg/L Rosult Units 4 mg/L Result Units 11 mg/L Qualifiers RL Qualifiers RL Qualifiers RL Qualifiers RL Report Date: 09104109 Collection Date: 0812710906:40 DateReceived: 08128109 MCU Qel Method Analysis Date I By MCU A4500-CI B 09/04/0913:47 1 lal Collection Date: 0812710906:57 DateReceived: 08128109 QCL Method Analysis Date I By A4500-CI 8 09/04109 13:49 / ial Collection Date: 08127109 06:25 DateReceived: 08128109 MCU QCL Mothod Analysis Date I By A4500,CI B 09/04/09 13:51 1 ial Collection Date: 08127109 07:06 OateRecelved: 08128109 MCU QCL Method Analysis Date f By A4500-CIB 09/04/09 13:53 1 ial MeL -Maximum contaminanllevel. NO -Not detected at the reporting hmit. 32 /37 Internatronal uranrum 12 30:06 pill 12-22-2009 ENERGYLABORATORjES, INC .• 2393SahCreekHignway(82601j ·P.O lJp.3258 • Casper, WY82602 7011 Free 888.235.0515 • ! '35.0515· Fax 307.234.1939 • casper@energyi( "" • WWlY.energylab.com LABORATORY ANALYTICAL REPORT Client: Site Name: Denison Mines (USA) Corp Chloride Inv. Initial Lab 10: C09081 078-005 Client Sample 10: TWN-9 Matrix: Analyses MAJOR IONS Chloride Lab 10: Aqueous C09081078-006 Client Sample 10: TWN-10 Matrix: Analyses MAJOR IONS Chloride Aqueous Report Rl -Analyte reporting limit. Definitions: QCl -Quality control limit. Result Units 169 mg/L Result Units 19 mglL Qualifiers RL Qualifiers RL MCU Report Date: 09/04/09 Collection Date: 08/2710907:27 DateReceived: 08/28/09 QCl Method Analysis Date I By MCU A4500·CI B 09/04/09 13:55 1 ial Collection Date: 08127/09 07:15 DateReceived: 08128/09 QCl Method Analysis Date I By A4500·CI B 09/04/09 13:58 1 ial MCL -Maximum contaminant level. NO -Not detecled althe reporting limit. 33/37 4356782224 Illlelllallollal UlalllUIlI 12.30 15 P_IIL 12-22-2009 ENERGYLABORATORIE5, INC .• 2393 Salt CreekHighway(82601j .P.D. EfJw 3258 • Caspsr, WY82602 Toll Free 888.235.0515 • I "35.0515' Fax 301.234.1639 • casper@energy{ )m' www.energylab.com 34 /37 Client: Denison Mi nes (USA) Corp Project: Chloride Inv. Initial Analyte Method: A4S00·CI B Sample 10 : MBLK9·090904B Chloride Sample 10: COgOB1078~OO5AMS Chloride Sample ID: LCS3S·090904B Chloride Sample ID: C09081078·00SAMSD Chloride Qualifiers: RL - Analyte reporting limit. QAlQC Summary Report Result Units Method Blank ND mglL Sample Matrix Spike 523 mglL Laboratory Control Sample 3S00 mglL Sample Matrix Spike Duplicate 523 mgfL Report Date: 09/04/09 Work Order: C09081078 RL %REC Low Limit High Limit Run: TITRATION_090904C 0.4 Run: TITRATION_090904C 1.0 100 90 110 Run: TITRATION_090904C 1.0 99 90 110 Run: TITRATlON_090904C 1.0 100 90 110 ND -Not detected at the reporting limit. RPD RPOUmit Qual Balch: 090904B·CL·TTR·W 09/04/09 13:45 09/04/0914:02 09/04/09 14:04 09/04/09 14:15 0 10 ju#i$ Rtrl.ulkfi_Ul/&" Chain of Custody and Analytical Request Record PLEASE PRINT (Provide as much information as possible.l Page ---1-of -i- Project Name. PWS, Permit, EtC.. I Sample Origin I ihICJf'~ Jr-/V ;7",,;),;) State u.r \ fS~AI;ScW ()t1,;,6 ,,~ No D Yes D Report Mail Add,(!;O. 6cP)G g-() if ,g(ti",d,:.w, /lor fr'i£lt Name: f\ ~ ~ tJl'Y/~ h n /2ZZ.( . e Address~: I [ovole . .,....(. inVOice I.,.;omact & Ph one: --~> .""'-" Special Report/Formats: ~ &~&I.!" 't7@D® [M~®QD~"ii'rn@) D ow D POTVVIWWTP D State: ___ _ D Other: ___ _ D EOO/EOT(Electronic Dala) Format:.-::-:-___ _ D LEVEL IV D NELAC Cl w ~O (1):5 c a:l~OI :v --> (5 >-(5 11!",¥,l:Jl~ 0S:'5~C> ~«CJ)I.Q ~ o ..... all c:: •• Q) c::--iii l!iro .2 0 ~~Iro ' 3 Q).=ws: ~ Z"'5...<t:[ClCl ~. ~ ~I ~ '" SAMPLE IDENTIFICATION Collection Collection MATRIX ~ (Name, Location, Interval, etc.) Date Time 7uJ1J-£ I,rZt-U1IMttO 1 \-w IY I ' IIA.JrV -~ 1-. / 'liJ£S'1 I J 1'1 I 3 --t1A.JAJ' -"1 J j 1-6£16 L l Ii -. -------------I' . -1- 0 e:- LL ;:: I '0 U c => « ~ 1= '" c :; « l- LL 'E LL '" (J) '0 c '" U5 ~o,,'~,~,: (Pleail Print) a~;,/ UL Email: Purchase Order: , Order: I" R u s H Contact ELI prior to Shipped by: RUSH sample submittal J-,,,L,,u,1 ~+-__ -I for charges and scheduling -See ~ Instruction Page ~+ -. R 'P Temp VI °c Comments: On 1C1l': Y N Cu"ody S"I t OIIBoI~ N On Cooler N' [nt:lcl Y N Signature y Match ~ '" '" C> ~ '" " " " ~ i! §. § §. c 0: = c " -prvAl ~ 8. 2 . 5 -tlf\J;..) _ q .. -__ -. 6 .. 1O~+--}-I~ ,. n _ /11-1.1 r ~ -I ~ '''' j ::; 6 7fA1/J-j{)_lk7.7 -o3JLl1'/,S" I J.--uJ Ii 7 ~ '0 . 8 9 1--1-I 1- 10 _1 __ I , " I Custody Rellnquis f ROCl!ivod by (print): Record RecfliVft(l by (print): 1f!(B~\ ~ ~ Si!lnilluro: 0 ~ Sign (0 Jl ure: MUST be TJ;grJ();;t qij~~Z;--?-:::.d-~ Signed Sample Disposal: Return to Client: lab DisDosal: ' ·v1;r':;~-5 In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the anaIYSiS/~ This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energyJab.com for additional information, downloadable fee schedule, forms, and links. OJ ~ 435678222.01 InlemallollCiI UICjIllUIll r ( . Energy Laboratories Inc Workorder Receipt Checklist 12.30A6p III 12-22-2009 Denison Mines (USA) Corp C09081078 Login com pleted by: Kimberly Humiston Date and Time Received: 8/28/20099:30 AM Reviewed by: Received by: al Reviewed Date: Carrier name: Next Day Air Shipping container/cooler in good conditio n? Yes 0' Custody seals inlact on shipping container/cooler? Yes 0' Custody seals intact on sample bollles? Yes D Chain of custody present? Yes 0 Chain of custody signed when relinquished and received? Yes 0 Chain of cuslody agrees with sample labe ls? Yes 0 Samples in proper container/bottle? Yes 0 Sample containers intact? Yes 0 Sufficient sample volume for indicated test? Yes 0 All samples received within holding lime? Yes 0' ContaineriTemp Blank temperature: 44C On Ice Water -VOA vials have zero headspace? Water -pH acceptable upon receipt? Contact and Corrective Action Comments: None Yes D Yes 0 No D No D No D No D NoD No D No D No D No D No D No D No D Not Present 0 Not Present 0 Not Present 0" No VOA vials submitted 0 Not Applicable 0 36 /37 4356782224 International uralllUOI 12: 30:55 P_IlL 12-22-2009 ENERGY LABORATORII;5, INC .• 2393 Salt Creek Highway (82801) • P.O 8"V 3258 • Casper, WY 82602 Toll Free 88fi2350515 • ( ?350515' Fax 301.234.1839 • casper@energy{ Jm • www.energylab.com , . . . CLIENT: Project: Denison Mines (USA) Corp Chloride Inv. Initial Sample Delivery Group: C09081078 ORIGINAL SAMPLE SUBMITTAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4°C (±2°C) Date: 04·Sep·09 CASE NARRATIVE 37/37 Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable wa ters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE. SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB da ta reported by ELI reflects the results for seven individual Aroclors. When the results for all seven are NO (not detected). the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. ClRANCI I LAClORATORY LOCATIONS e1i~b ~ Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillette, WY eli-h -Energy Laboratories, Inc. -Helena, MT eli·r· Energy Laboratories, Inc .. Rapid City, SO eli-! - Energy Laboratories, Inc .• College Station, TX CERTIFICATIONS: USEPA: WY00002, Radiochemical WY00937; FL·DOH NELAC: E87641 , Radiochemical E871017; California: 02118CA; Oregon: WY200001; Utah: 3072350515; Vir9inia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin . Please verify ELI's certification coverage by visiting www.energylab.com ELI appreCiates the opportunity to provide you with this analytical service. For additional information and services visit our web page wvvw.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT September Sampling Event ENERG Y LASORA TORIES, INC .• 2393 Sail Creek Highway (8260 1) . P.o. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 ' casper@energylab.com' www.energylab,com October 06, 2009 Denison Mines USA Corp 64255 Hwy 191 Blanding, UT 84511 Workorder No.: C09090891 ANALYTICAL SUMMARY REPORT Project Name: 3rd Quarter Nitrate and Chloride En ergy Laboratories, Inc. received the following 27 samples for Denison Mines USA Corp on 9/23/2009 for analysis. Sample 10 Client Sample 10 Collect Date Receive Date Matrix Te.t C09090891 -001 TWN-1R 09/2 1/0907:5009/23/09 Aqueous Chloride Nitrogen, Nitrate + Nitrite C09090891-002 TWN-2R 09/21/0908:5709/23/09 Aqueous Same As Above C09090891 -003 TWN-3R 09/21/0909:4709/23/09 Aqueous Same As Above C09090891-004 TWN-4R 09/2 1/0910:44 09/23/09 Aqueous Same As Above C09090891-005 TWN-5R 09/21/0914:12 09/23/09 Aqueous Same As Above C09090891·006 TWN·6R 09/22/09 09:50 09/23/09 Aqueous Same As Above C09090891·007 TWN· 7R 09/21/0913:2009/23/09 Aqueous Same As Above C09090891·008 TWN-8R 09/21/0915:1009/23/09 Aqueous Same As Above C09090891·009 TWN-9R 09/22/09 07:43 09/23/09 Aqueous Same As Above C09090891·010 TWN·10R 09/22/0908:51 09/23/09 Aqueous Same As Above C09090891·011 TWN·1 09/22/09 14: 12 09/23/09 Aqueous Same As Above C09090891·012 TWN·2 09/22/09 13:56 09/23/09 Aqueous Same As Above C09090891 -013 TWN-3 09/22/0914:01 09/23/09 Aqueous Same As Above C09090891·014 TWN-4 09/22/0914:0609/23/09 Aqueous Same As Above C09090891-015 TWN-5 09/22/09 13:44 09/23/09 Aqu eous Same As Above C09090891·016 TWN·6 09/22/0913:2 1 09/23109 Aqueous Same As Above C09090891·017 TWN·7 09/22/09 13:49 09/23/09 Aqueous Same As Above C09090891·018 TWN·8 09/22/09 13: 17 09/23/09 Aqueous Same As Above C09090891·019 TWN·9 09/22109 13:34 09/23/09 Aqueous Same As Above C09090B91·020 TWN·10 09/22109 13:2B 09/23/09 Aqueous Same As Above C09090B91-021 Piez 1 09/22/09 11 :10 09/2 3/09 Aqueous Same As Above C09090B91·022 Piez 2 09/22/09 11 :50 09/23/09 Aqueous Same As Above C09090B91·023 Piez 3 09/22/0912:05 09/23/09 Aqueous Same As Above C09090B91-024 WLPU 09/22/0910:5509/23/09 Aqueous Same As Above ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' po. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com · wwwenergylab.com ANALYTICAL SUMMARY REPORT C09090891 -025 TWN-50 09/22/0913:21 09/2 3/09 Aqueous Same As Above C09090891-025 TWN-O 09/22/09 08:20 09/23/09 Aqueous Same As Above C09090891-027 Temp Blank 09/2 3/09 Aqueous Temperature As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QAJQC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • P.o. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301235.0515 • Fax 301234.1639 • casper@energylab.com · wWlv.energylab.com LABORATORY ANALYTICAl REPORT Client: Denison Mines USA Corp Site Name: 3rd Quarter Nitrate and Chloride Lab to: C09090S91-001 Client 5amptelD: TWN-1R Matrix: Aqueous Analyses Result Units MAJOR tONS Chloride Nitrogen , Nitrate+Nitrite as N Lab to: C09090S91 -002 Client Sample 10: TWN-2R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen. Nilrale+Nilrite as N Lab 10 : C09090S91-003 Client Sample 10: TWN-3R Matrix: Aqueous Analyses MAJOR tONS Chloride Nitrogen, Nitrale+Nilrite as N Lab to: C09090S91-004 Client Sample 10: TWN-4R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrale+Nilrite as N Report RL -Analyte reporting limit. Definitions: QCL -Quality controllimil. ND ND Result NO NO Result 1 NO Result 2 NO mglL m9/L Units mg/L mg/L Units mg/l mg/L Units mg/L mg/L Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 1 0.1 Qualifiers RL 1 0.1 Report Date: 10/06/09 Collection Date: 09/21/0907:50 DateRecelved: 09/23/09 MCLJ QCL Method Analysis Date I By A4500-CI B 10/02/0914:07 1 i.1 E353.2 10/05/0913:181 i.1 Collection Date: 09/21/090S:57 DateRecelved: 09/23/09 MCLJ QCL Method Analysis Date I By A4500·CI B 10/0210914:151 i.1 E353.2 10/05/09 13:20 1 i.1 Collection Oato: 09/21/0909:47 OateRecelved: 09/23/09 MCLJ QCL Method Analysis Date I By A4500·CI B 10/02/0914:19 1 i.1 E353.2 10/05/09 13:23 I i.1 Collection Date: 09121/0910:44 DateReceived: 09/23/09 MCLJ QCL Method Analysis Date I By A4500-CI B 10/0210914:23 1 i.1 E353.2 10/05/0913:25 1 i.1 MCL -Maximum contaminant lever. ND -Not detected at th e reporting limit. ENERG r LABORATORIES, INC .• 2393 Salt Creek Highway (82601) • Po. Box 3258 . Casper, wr 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com . WWlv.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 3rd Quarter Nitrate and Chloride Lab 10: C09090891-005 Client Sample 10: TWN-5R Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nilrate+Nitrile as N Lab 10: C09090891-006 Client Sample 10: TWN-6R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nilrite as N Lab 10 : C09090891-007 Client Sample 10: TWN-7R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrale+Nilrite as N Lab 10: C09090891-008 Client Sample 10: TWN·8R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nilrite as N Report RL . Analyte reporting limit. Definitions: OCl· Quality control limit. 2 ND Result ND ND Result ND Result ND m91L mg/L Units mg/L mglL Units m91L m91L Units mglL mg/L Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 MCU Report Date: 10106/09 Collection Date: 09/2 1/0914:12 OateReceived: 09/23/09 aCl Method Analysis Oate I By MCU aCL A4500·CI B E353.2 10102109 15:35 I ial 10105109 13:35 I ial Collection Date: 09/22109 09:50 OateRecelved: 09123/09 Method Analysis Date ( By A4500-CI B 10102/0915:38 I ial E353.2 1010510913:38 Iial Collection Date: 0912110913:20 Date Received: 09123/09 MCU aCL Method Analysis Date I By A4500·CI B 10102/09 15:41 I ial E353.2 1010510913:40/jal Collection Date: 09/2110915:10 OateRecelved: 09/23/09 MCU aCL Method Analysis Date I By A4500·CI B 10102/09 15:44 I ial E353.2 10105109 13:43 I ial MCl . Maximum contaminant level. NO • Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • po. Box 3258 . Casper, WY 82602 Toll Free 888.2350515 • 307235.0515 • Fax 307234.1639 . casper@energylab.com· wlYW.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 3rd Quarter Nitrate and Chloride Lab 10: C09090S91-009 Client Sample 10: TWN-9R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nltrite as N Lab 10: C09090S91-010 Client Sample 10: TWN-10R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nilrate+NUrite as N lab 10: C09090891.011 Client Sample 10: TWN-1 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C09090S91·012 Client Sample 10: TWN·2 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL . Analyte reporting limit. Definitions: aCl. Quality control limit. Result NO NO Result NO NO Result 19 0.4 Result 17 22.6 Units mg/L mg/L Units mg/L mg/L Units mg/L mg/L Units mg/L mg/L o . Rl increased due to sample matrix interference. Report Date: tO/06/09 Collection Date: 09/22/0907:43 OateRecelved: 09/23/09 MCU Qualifiers RL QCL Method Analysis Oato IBy A4500·CIB 10/02/09 15:59 1 iol 0.1 E353.2 10/05/0913:45 1 iol Collection Date: 09/22/09 OS :5 1 DateRecelved: 09/23/09 MCU Qualifiers RL QCL Method Analysis Date I By A4500·CI B 10/02/09 16:02 1 iol 0.1 E353.2 10/05/09 13:551 iol Collection Date: 09/22/0914:12 DateRecelved: 09/23/09 MCU Qualifiers RL QCL Method Analysis Date I By A4500·CI B 10/02/09 16: 15 1 iol 0.1 E353.2 10/05/0913:57/ iol Collection Date: 09122/09 13:56 Date Received: 09/23/09 MCU Qualifiers RL QCL Method Analysis Date I By A4500·CI B 10/02/09 16: 16 1 iol D 0.3 E353.2 10/05/09 14:00/ jol MCl • Maximum contaminant level. NO . Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393SaIfCreekHighway(82601j' p.D. Box 3258 • Casper, WY82602 ToIIFree888.235.0515· 301.235.0515 • Fax 301.234.1639 ' casper@energylab.com ·wWlv.energylab.com LABORATORY ANALYTICAL REPORT Client: Oenison Mines USA Corp Site Name: 3rd Quarter Nitrate and Chtoride Lab 10: C09090891-013 Client Sample 10: TWN-3 Matrix: Analyses MAJOR IONS Chloride Aq ueous Nitrogen. Nilrate+Nitrile as N Lab 10: C09090891-014 Client Sample 10: TWN-4 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrile as N Lab 10: C09090891-015 Client Sample 10: TWN-5 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrile as N Lab 10: C09090891-016 Client Sample 10: TWN-6 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen. Nitrate+Nitrite as N Report RL -Analyte reporting limit. Definitions: QeL -Quality control limit Result Units 99 mg/L 27.1 mglL Result Units 13 mg/L 0.4 mglL Result Units 45 mg/L 0.5 mg/L Result Units 23 mg/L 1.6 mglL o . RL increased due to sample matrix interference. Qualifiers o Qualifiers Qualifiers Qualifiers RL 1 0.3 RL 0.1 RL 0.1 RL 1 0.1 MCU Report Date: 10/06/09 Collection Date: 09/22/09 14:01 DateReceived: 09/23/09 QCL Method Analysis Date I By A4500·CI B 1010210916:271 ial E353 .2 10105109 14:021 ial Collection Date: 09/22/09 14:06 OateRecelved: 09/23/09 MCU QCL Method Analysis Date J By A4500·CIB 10102109 16:37 1 ial E353.2 10105109 14:051 ial Collection Date: 09/22/0 9 13:44 DateRecelved: 09/23/09 MCU QCL Method Analysis Date I By A4500·CI B 1010510913:351 ial E353.2 1010510914:15 11al Collection Date: 09/2210913:21 DateRecelved: 09/23/09 MCU QCL Method Analysis Date' By A4500·CI B 10/05/0913:381 ial E353.2 10/05/0914:17 /jal MeL -Maximum contaminant level. NO . Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' p.o. Box 3258 . Casper. W'f82602 Toll Free 888.235.0515 • 3072350515 • Fax 307234.1639 • casper@energylab.cam • www.energylab.cam LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 3rd Quarter Nitrate and Chloride Lab 10: C09090891·0 17 Client Sample 10: TWN·7 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrale+Nilrite as N Lab 10: C09090891-018 Client Sample 10: TWN-8 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrlle as N lab 10: C09090B91-019 Client Sample 10: TWN-9 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrile as N Lab 10: C09090891-020 Client Sample 10: TWN-l0 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nilrate+Nitrite as N Report Rl . Analyte reporting limit. Definitions: QCl· Quality control tim it. Result 7 NO Result 12 NO Result 201 8.9 Result 35 1.6 Units mgll mg/l Units mgll mg/L Units mgll mg/l Units mg/l m9/l Report Date: 10106/09 Collection Date: 09/22/09 13:49 DateRecelved: 09/23/09 MCU Qualifiers Rl QCl Method Analysis Date' By A4500·CI B 10/05/0913:41 /ial 0.1 E353.2 10/05/0914:20 1 ial Collection Date: 09/22/09 13:17 OateReceived: 09/23/09 MCU Qualifiers Rl QCl Method Analysis Date I By A4500-CI B 10/05109 13:451 ial 0.1 E353.2 10105/09 14:221 ial Collection Date: 09/22/09 13:34 DateRecelved: 09/23/09 MCU Qualifiers Rl QCl Method Analysis Date I By 1 A4500-CI B 10/05/0914:01 1 ial 0.2 E353.2 10/05/09 14:25 /1al Collection Date: 09122109 13:28 OateReceived: 09/23/09 MCU QualifiofS Rl QCl Method Analysis Date I By A4500-CI B 10/05/0914:091 ial 0.1 E353.2 10/05/0914:32/1al MCl . Maximum contaminant level. NO . Not detected at the reporting limit. ENERG Y LABORATORIES, INC .• 2393 SaIl Creek Highway (82601) • P.D Box 3258 . Casper, WY 82602 Toll Free 888.2350515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com · ww",energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 3rd Quarter Nitrate and Chloride Lab 10: C09090B91·021 Client Sample 10: Piez 1 Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nilrile as N Lab 10: C09090B91·022 Client Sample ID: Piez 2 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrile as N Lab ID: C09090891·023 Client Sample ID: Piez 3 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen. Nilrate+Nitrite as N Lab ID: C09090B91·024 Client Sample ID: WLPU Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nit(ale+Nitrite as N Report Rl -Analyte reporting limit. Definitions: QCl -Quality control limit. 78 7.3 Result 17 0.5 Result 24 0.9 Result 5 NO mg/L mg/L Units mg/L mg/L Units mg/L mg/L Units mg/L mgll. Qualifiers RL 0.2 Qualifiers RL 0.1 Qualifiers RL 1 0.1 Qualifiers RL 0.1 MCU Report Date: 10106/09 Collection Date: 09/22/0911:10 DateRecelved: 09/23/09 QCL Mothod Analysis Date I By A4S00·CIB 10/0S/0914:1411al E3S3.2 10/05/09 14:35 1 lal Collection Date: 09/22/09 11 :50 DateRecelved: 09/23/09 MCU QCL Method Analysis Oate I By A4500·CI B 10/0S/09 14:26 /1al E353.2 10/05/09 14:37/1al Collection Date: 09/22/09 12:05 DateRecelved: 09/23/09 MCU QCL Method AnalysIs Date I By A4500·CI B 10105/0914:41/1al E353.2 10/05/09 14:40 /1al Collection Date: 09/22/09 10:55 OateRecelved: 09/23/09 MCU QCL Method Analysis Date I By A4500·CIB 10/05/09 14:54 /1al E353.2 10/05/09 14:42/1al MCl -Maximum contaminant level. NO -Not detected at the (eporting limit. ENERGY LABORATORIES, INC .• 2393 Sal/Creek Highway (82601)' p.o. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com· 'VMI(energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 3rd Quarter Nitrate and Chloride Lab 10: C09090891-025 Client Sample 10: TWN·6D Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nitrale+Nitrite as N Lab 10: C09090891-026 Client Sample 10: TWN-O Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nilrate+Nitrile as N Lab 10: C09090891-027 Client Sample 10: Temp Blank Matrix: Aqueous Analyses PHYSICAL PROPERTIES Temperature Report Definitions: RL . Analyte reporting limit. eel -Quality control limil. Result Units 22 1.6 Result 2 ND mglL mg/L Units mg/L mg/L Result Units 4.0 ·C Qualifiers RL 0.1 Quallfiars RL O. I Qualifiers RL MCLJ Report Date: tO/06/09 Coliection Date: 09/22/0913:21 OateRecelved: 09/23/09 Qel Method Analysis Date I By A4500-CI B E353.2 10/05/09 14:57/ ial 10/05/09 14:52/ ial Coliectlon Oate: 09/22/09 08:20 DateRecelved: 09/23/09 MCLJ QCL MCLJ Method Analysis Date I By A4500-CI B 10/05/09 15:02 /Ial E353.2 10/05/09 14:55/ ial Collection Date: Not Provided OateRecelved: 09/23/09 QCL Method Analysis Date I By E170. I 09/23/0914:30/ kbh Mel -Maximum contaminant level. NO -Not detected at the reporting limit ENERG Y LABORATORIES, INC .• 2393 Salt Creek Highway (82601) • P.o. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com • IYlYW.energylab.com QAlQC Summary Report Client: Denison Mines USA Corp Project: 3rd Quarter Nitrate and Chloride Analyte Method: A4500·CI B Sample 10: MBLK9·091002A Chloride Sample 10: C09090875·002AMS Chloride Sample 10: C09090875-002AMSO Chloride Sample 10: LCS35-091002A Chloride Sample 10: C09090981·014BMS Chloride Sample 10: C09090981·014BMSO Chloride Method: A4500·CI B Sample 10: MBLK9·091005A Chloride Sample 10: C09090891-022BMS Chloride Sample 10: C09090891-022BMSO Chloride Sample 10: lCS35·09100SA Chloride Qualifiers: RL . Analyle reporting limit. Count Result Un its Method Blank NO mg/L Sample Matrix Spike 34.7 mg/L Sample Matrix Spike Duplicate 34.0 mg/L laboratory Control Sample 3540 mg/L Sample Matrix Spike 96.2 mglL Sample Matrix Spike Duplicate 91.9 mglL Method Blank NO mg/L Sample Matrix Spike 99.8 mg/L Sample Matrix Spike Duplicate 99.8 mg/L Laboratory Control Sample 3780 mg/L Report Date: 10/06/09 Work Order: C09090891 RL %REC low limit High Limit Run: TITRATION_091002A 0.4 Run: TITRATION_091002A 1.0 96 90 110 Run: TITRATlON_091002A 1.0 94 90 110 Run: TITRATION_091002A 1.0 100 90 110 Run: TlTRATION_091002A 1.0 108 90 110 Run: TlTRATION_091002A 1.0 104 90 110 Ru n: TITRATION_091005C 0.4 Run: TITRATION_091005C 1.0 94 90 110 Ru n: TITRATION_091005C 1.0 94 90 110 Run: TITRATION_091005C 1.0 107 90 110 NO . Not detected at the re porting limit. RPD RPOLimit Qual Batch: 091002A·CL·TTR·W 10/02/0910:58 2 4.5 10/0210911:40 10102/09 11 :41 10 10102/09 15:08 10/02/0917:08 10102109 17:08 10 Batch: 091005A·CL·TTR·W 10105/09 12:38 10/05/09 14:37 10/05/09 14:37 0 10 10/05/0916:10 ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' p.D. Box 3258 • Casper, WY 82602 Toll Free 888.2350515 • 307.2350515 • Fax 307.234.1639 • casper@energylab.com· wlYlY.energylab.com QAlQC Summary Report Client: Denison Mines USA Corp Report Date: 10106/09 Project: 3rd Quarter Nitrate and Chloride Work Order: C09090891 Analyte Count Result Units RL %IREC Low Limit High Limit RPO RPDLimit Qual Method: E353.2 Balch: R124617 Sample 10: MBLK-1 Melhod Blank Run: TECHNICON_09100SA 10/0S/09 11 :08 Nitrogen, Nilrale+Ni\rite as N ND mg/L 0.03 Sample 10: LCS·2 Laboratory Control Sample Run: TECHNICON_09100SA 10/oS/o911:10 Nitrogen, Nitrale+Nilrite as N 2.S7 mg/l 0.10 103 90 110 Sample 10: C09090891-004AMS Sample Matrix Spike Run: TECHNICON_09100SA 10/0S/09 13:28 Nitrogen, Nitrate+Nitrite as N 2.13 mg/L 0.10 103 90 11 0 Sample 10: C09090891'()04AMSO Sample Matrix Spike Duplicate Run: TECHNICON_09100SA 10/0S/09 13:30 Nitrogen. Nilrate+Nitrite as N 2.16 mg/L 0.10 lOS 90 11 0 1.4 10 Sample 10: C09090891-014AMS Sample Matrix Spike Run: TECHNICON_09100SA 10/0S/09 14:07 Nitrogen, Nilrate+Nitrite as N 2.47 mg/L 0.10 102 90 110 Sample 10: C09090891-014AMSO Sample Matrix Spike Duplicate Run: TE CHNICON_09100SA 10/0S/0914:10 Nitrogen. Nitrate+Nitrite as N 2.46 mg/L 0.10 101 90 110 0.4 10 Sample 10: C09090891'()24AMS Sample Matrix Spike Run: TECHNICON_09100SA 10/0S/09 14:4S Nitrogen. Nitrate+Nilrite as N 2.01 mg/L 0.10 100 90 110 Sample 10: C09090a91·024AMSO Sample Matrix Spike Duplicate Run: TECHNICON_09100SA 10/05/0914:47 Nitrogen . Nitrate+Nilrite as N 1.99 mg/l 0.10 100 90 110 10 Qualifiers: RL -Analyte reporting timit. NO -Not detected at the reporting limit. lAW&? .~m"it·u·UD' Chain of Custody and Analytical Request Record Page~of :3, I :u~. J{L.~~_ t<'rJ/S&. Report Mail-~YY"D gpJ)(, «09 P AJ/J""', d.J 1.1..7 >r'l .C: J I Invoice Address: . -¥-I ('~r.. ,NVl Special Report/Formats: Dow o EOO/EOT(Elect,onK: Data) D POTWNVWTP D State: ___ _ D Other: ___ _ Format:-::-;-___ _ o LEVEL IV o NELAC PLEASE PRINT IPrnvirt" as much informalion as Dossiblli , PWS, Permit, Etc. I Sample Origin i <S .... J OLlCdU'(..f-Nf.lvoJe.j ch/Ml.;ft,_ State iJ.T Yes 0 No 0 Contact Name: Email: Sampler: (Please Print) a., A' !la.1.v.,., b 1;!' -c2Z/ Invorce Con-tacf & Phone: -~ :s: Cl ~ '" ~O~£ .... cCD=OI~ ,->o>'rn ~CJ)~~~ 03:== co C) u <.(~I.Q ~ O .. Q:;~I.§ .... a>-co ~~I~ I ::J (1)-= a:; 5: ~\7~D@ ~@:@)QD~ ~ 0 <{ w t::. I '0 0 c " « e I-'" l-E « " >- L-1ttf1d! ., Jf -un..;rld::.e Order: ~ Order: • Contact ELI prior to RUSH sample submittal R for charges and scheculing -See c..\',C'V" Instruction Page ROCoiPt~P Comments: U °c On Ice: N Zti.<X:laro ~ > I -.::! ';-1 en • ~ ~ ~~ w E W '" (f) '0 C '" 5 Custody Seal D~ On Bortle On Cooler SAMPLE IDENTIFICATION (Name, Location, Interval, etc.) 7WtJ-I R '-rIAl N -1 R.. . 311,.,)1\I_:~ 12.. '-rw/<J-4iL , ±lbl'" -l; R 6 TwN ,urn r1.. ----- 711r-JN-ll • ThW ___ ~Jl.. '1WN,QR f'oliection Collection MATRIX ~ ~ Date TIme iq·ll.()1 IM:'>n 12-w 1>:lx 1·2101 112.8:51-1 1.><1 X 1·21 ·D1 16q41 I ( Ix l'x ·ll ·[)Q IID4'~' I \ 1)(1 X /.2.1-01 1/111'1 I J I xJx 1l2·01 1 DqS-O I I 1')(.1')( nl·01 113:2fl I I 1),1)( 1~(L'LiJ5JlL_ I l_ 1)<. r-x . n ·C1J I O~3 I I I X Iy 10-'i-wtJ -10 l ~'nO'fI6i6$" I ~-~ Ir Ix I Custody R~"ed by (p ' Roc.;"", by (pm'), Ui H Intact SIgnature Match loJ] >ltgni:lIuro. Record Recoived by (print): DatcfTime: Sign-ature: ~: MUSTbe~ ______________________________ -,~~~~~ __ ~~ ________ ~~~~~~~ Sig ned Sample DisDosal: Return 10 Client: Lab DisDosal: __ I "]:2., \\)C{ \ ~~) .03;; ;., /<~ In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete Ih;-;'n~[YSiS~~?' This serves as notice of this possibility. All 5ub-contract data will be clearly notated on your analytical report. / C . Visit our web site at www.energylab.com for additional information. downloadable fee schedule, forms, and links. • Chain of Custody and Analytical Request Record page~of~ temM&UHi"i ' PI FA~F PRINT Ip,.nvirl~ as much 111. ,'Jame: D W;s,o'/ rVI ;,JeS i Projectaje, PWS, Permit, Etc. ,3 r (J'Afl,l-TW A"~+',"k ,j (hlortl'd!, Report Mail Address: 0-C; P"O. a~ 00 , {l,JfNl/I.;"" {A"1 ~K Invoice Address: J C '3".,. Contact Name: I T2.t>N ILL" liwoil:e Contact & Phone: ,S,J 1A......t IIUllt:!IrdA: 0T1f uz/ Special Report/Formats: :;: ~\7@O@ rn~®QD~~@) Dow D EOO/EOTIElectron;c Data) D POTWNVWTP D State: ___ _ D Other: ___ _ Format:.-::-:-___ _ D LEVEL IV D NELAC '" ~ ~o U)£ ~CJ;gol Cii ._> 0 >-1tj ~(J)~~~ o~:= ~ C) u«~I.Q~ '0 .. Q; cce:l.!; .... Q)-'-.~ Cl.ct1 00 t:~rcU ' ::JQ).~Q)~ Z_!_«_'_~_,,,,~ ~~ 1 SAMPLE IDENTIFICATION Collection Collection MATRIX "'.::s; (Name. Location. Interval, etc.) Date Time <.. ThW-1 I1Z2-()9 l /'ill 12-w Ix I X I 'jVVN -J.. 11 ?l-b1 1 b5 (" I / 1 X 1)< 1J--rfAlN' _~ Iq hrft'I14o( I ( I X I X I >ll~IN' L.j ~ II rflJ I 4 () (" I X Ix I as ;=-0 « W t:. I "0 U e: " <{ e I-'" l-e: <{ :; f-w 'E w '" (/J "0 e: 2 (f) , I 'II-',e Origin State: fA-r Yes 0 ce. No 0 Email: Sampler: (Please Print) [GoLOO/L If , Order: Quote/Bottle Order: .. Contact ELI prior to RUSH sample submittal Iw·' \ ,V\C R for charges and scheduling -See Instruction Page C-\: f\\t U Comments: On Ice: S H Custody Se.' ~ On Bottle N On Cooler Intact y Signature y Match .ql I'WN--t[_ Iq·zz·of 1/334 I / 1'>'-1)(1 I I I I I I I I I I I~ lO TWN/{{) 11·zz:OJ ll3.28' I:<-w I-t lx l 1 I I I I 1 I 1 I ~ I Custody () :) s""',,.c Record 51,,,,,,., (print): Received by (print): ,~, Ua!e/ilme: sTgnalure:- MUSTbe,~ ____________ _ Signed S'!lllplel I~~ Return to Client: Lab cn~~\m \'-\?D~ In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analYp~ est ....... This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. VISit our web site at www.energylab.com for additional information. downloadable fee schedule. forms. and links. - IgliiWl «cm.kt.fielrlli' Chain of Custody and Analytical Request Record PI I=.II.~'" PRINT (Provide as much information as nn .. ;h'o \ Page __ of __ "'""',))::/ISCN (lI) iNp:, I ~o;J7;L::peN;::k i rj,/u,;{e I ::a7:leO~y Yes 0 No 0 Report Mail Address: &rv;< ?5t71 ~'~nL" fAr ?/'I5// Invoice . I .SA :t Name: I ~"'''' D,J~ tn ~??J Ilnv~-ContacT& Phone: ~ ... , Special ReporVFormats: ;;: ~~~ ~@:@){!!)~~® Dow D EOO/EOT(Electronic Data) D POTWIWWTP D State: ___ _ D Other: ___ _ Fonmat:.-::-:-___ _ D LEVEL IV D NELAC o -~Otf)£ ~co~Ol Q) ._> 0 >-ro 19 .. ,..00 cu:> C"'"'jJs en:>-o~'5 ~ 0'1 U -«:cnl.Q ~ '0 .... mlc:; .... 8.75525 ~~I1ii ' 20..«\0'10 ~ E ~[ ~ '" ,-en ... :J ",.= 0;;;: ~ v .....;::: SAMPLE IDENTIFICATION Collection Coliection "'Tn,v -'I:' (Name, Location, Interval, etc.) Date Time i),'n I I qz2'-o1 1 ~I/IO I ;2'w I X It< o ~ w t:. I '0 U § « E' I-'" I-E « ,= w 12 W '" (fJ -g '" iii Email: Sampler: (Please Print) 1 ~t1t'W If t-'urcnase Order: QuotelBottle Order: , .. R u s H Contact ELI prior to RUSH sample submittal h~~~~'---1 for charges and scheduling -See /' l ' Instruction Page U ,f 1'\ + Comments: I Receipt TG("p y 'c " Y ;N OooBo'. ~([) On Cooler Y N Intact N ISlgnature Y N Match ~ t U:~I f1 ( 1 ~lil l TflfT1TI r --1~1 ~:!~.-t ~~~1f I R~r Ifl.L k IQI-I 1 1 ·1 1 1 1 1 1 li I I 7 ,,~~ _h\('QlIVC.tO(:bcw,.;.J ,~ I .. I<7mo ?nJ\'(. • 10 PI iCustody ReceivecI by (pnnt): Oau~mme: S~n-atur;: R eco rd Received by (print): DatclTime: Signature: ~~STbe~ ____________________________________________________ ~~.,~,,~,.~y~.~,~,,~~~,------~~~------------~~~~.~,.~~~~~~-r- Signed Sam Ie Dis osat Return toelient: Lab Dis osal: . . In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information, downloadable fee schedule, forms, and links. Energy Laboratories Inc Workorder Receipt Checklist Den ison Mines USA Corp Login completed by: Halley Ackerman Reviewed by: Reviewed Date: Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper conlainer/bottle? Sample containers inlact? Sufficient sample volume for indicated lest? All samples received within holding time? ContainerfTemp Blank temperature: Water· VOA vials have zero headspace? Water -pH acceptable upon receipt? Contact and Corrective Action Comments: None Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 Yes 0 C09090891 Date and Time Received: 9/23/20092:30 PM Received by: al No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier name: Hand Del Not Present D Not Present 0 Not Present 0' No VOA vials submitted [{I Not Applicable 0 ENERGY LABORATORIES, INC. 02393 Sail Creek Highway(82601) 0 PD. Box 3258 0 Casper. WY82602 ToIiFree888.235.0515 0 307.235.0515 0 Fax 307.234.1639 0 casper@energylab.com o'VlYW.energylab.com CLIENT: Denison Mines USA Corp Dale: 06·0ct·09 Project: 3rd Quarter Nitrale and Chloride CASE NARRATIVE Sample Delivery Group: C09090S91 ORIGINAL SAMPLE SUBMITIAL(S) All original sample submittals have been relumed wilh Ihe dala package. SAMPLE TEMPERATURE COMPLIANCE: 4"C (±2"C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be con sidered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Melhod 900.0 for gross alpha and gross bela is inlended as a drinking waler melhod for low TDS walers. Dala provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS Dala for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB dala reported by ELI refiecls Ihe resulls for seven individual Aroclors. When Ihe results for all seven are NO (nol delecled), Ihe sample meels EPA compliance crileria for PCB moniloring. SUBCONTRACTING ANALYSIS Subconlracling of sample analyses 10 an oulside laboralory may be required. If so, ENERGY LABORATORIES will ulilize ils branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboralory Analylical Report. BRANCH LABORATORY LOCATIONS eli·b • Energy Laboratories, Inc. -Billings, MT eli·g . Energy Laboralories, Inc. -Gillette, WY eli·h -Energy Laboralories, Inc .• Helena, MT eli·r· Energy Laboralories, Inc .. Rapid City, SO eli·1 • Energy Laboralories, Inc .. College Slalion, TX CERTIFICATIONS: USEPA: WY00002, Radiochemical WY00937; FL-DOH NELAC: ES7641, Radiochemical E871017; California: 0211SCA; Oregon: WY200001; Ulah: 3072350515; Virginia: 00057; Washinglon: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC .• CASPER,WY certifies Ihal certain melhod selections conlained in Ihis report meel requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify Ell's certification coverage by visiting IN'Y'M'.energylab,com Ell appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page lNWW.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT October/November Sampli ng Event ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • p. 0. Box 3258 . Casper. WY 82602 , Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com • www.energylab.com ANALYTICAL SUMMARY REPORT November 11 . 2009 Denison Mines USA Corp 6425 S Hwy 191 Blanding. UT 84511 Workorder No.: C09110253 Project Name: 4th Quarter Nitrate and Chloride Energy Laboratories. Inc. received the following 25 samples for Denison Mines USA Corp on 1116/2009 for analysis. Sample ID Client Sample tD Collect Oate Receive Date Matrix Test C091 10253·001 TWN 3R 1110210909:54 11/06/09 Aqueous Chloride Nitrogen. Nitrate + Nitrite C09110253·002 TWN 3 11/02/0914:0011106/09 Aqueous Same As Above C09110253·003 TWN 2R 11102/09 11 :05 11106109 Aqueous Same As Above ----------------------C09110253·004 TWN 2 11/02/09 11 :34 11/06/09 Aqueous Same As Above C09110253·005 TWN 19R 11/02/09 13:20 11106109 C09110253·006 TWN 19 11/02/09 13:42 11106109 Same As Above C09110253·007 TWN 1aR 11102/0915:0011106/09 Aqueous Same As Above -=C""'0.,..91,-1:c:0..,25cc3:-.0ccOc:8,-TWN=::.,-1""'8------11/02/09 15:33 11106109 Aqueous Same As Above C0911 0253·009 TWN 11 R 11/03/09 08:20 11106109 Aqueous Same As Above C09110253·010 TWN 11 11/03/09 08:53 11106109 Aqueous Same As Above ----~ ~ -~---------------------------------------------------------C091 10253~011 TWN 12R 11 /03/0909:47 11106109 Aqueous Same As Above C09110253~012 TWN 12 11103/09 10:30 11106/09 Aqueous Same As Above --------. C09110253~013 TWN 8R 11103/0913:1011106/09 Aqueous Same As Above C09110253·014 TWN 8 11103/0913:4511106/09 Aqueous Same As Above ---------------------------------------------------C09110253~015 TWN 6R 11/03/0914:35 11/06/09 Aqueous C09110253~016 TWN 6 11/03/0915:0211/06/09 Aqueous C09110253·017 TWN 16R 11104/0907:47 11 /06/09 Aqueous ---------. C09110253·018 TWN 16 11104/0908:15 11106/09 Aqueous C09110253~019 TWN 17R 11104/0908:58 11106/09 Aqueous C09110253~020 TWN 17 11104/0909:24 11 /06/09 Aqueous C0911 0253~021 TWN 0 11104/09 09:24 11 /06/09 Aqueous Same As Above Same As Above Same As Above Same As Above Same As Above Same As Above Same As Above -----------------------C0911 0253~022 TWN 13R 11 /04/09 12:43 11106109 Aqueous Same As Above C09110253~023 TWN 13 11/04/09 13:11 11106/09 Aqueous Same As Above ENERGY LASORA TORIES, INC .• 2393 Sail Creek Highway (82601) • p.o. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylsb.com · wwwenergylab.com ANALYTICAL SUMMARY REPORT C091 10253·024 TWN 14R C091 10253·025 TWN 14 11/04/0913:57 11/06109 11/04109 14:27 11/06109 Aqueous Same As Above -------Aqueous Same As Above As appropriate. any exceptions or probtems with the anatyses are noted in the Laboratory Analytical Report. the QAlQC Summary Report. or the Case Narrative. If you have any questions regarding these tests resu lts , please call. Report Approved By: ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • p.o. Box 3258 • Casper, WY 82602 Toll Free 888235.0515 • 307235.0515 • Fax 307234.1639 • casper@energylab.com • lYIYIY.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate and Chloride Lab 10: C09110253·001 Client Sample 10: TWN3R Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride 3 mg/l Nitrogen, Nitrate+Nitrile as N NO mglL Lab 10 : C09110253·002 Client Sample 10: TWN3 Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride 106 mg/L Nitrogen, Nitrale+Nilrite as N 29.0 mg/L Lab 10 : C09110253·003 Client Sample 10: TWN2R Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride NO mglL Nitrogen, Nitrate+Nitrile as N NO mglL Lab 10: C09110253·004 Client Sample 10 : TWN 2 Matrix: Aqueous Qualifiers RL 0.1 Qualifiers RL 1 0 0.3 Qualifiers RL 0.1 Report Date: 11111/09 Coliection Date: 11102/09 09:54 DateRecelved: 11/06/09 MCU QCL Method Analysis Date I By A4500·CI B 11109109 10:14 /1, E353.2 1110910910:541 i_I Collection Date: 11 /02/09 14 :00 OateRecelved: 11/06/09 MCU QCL Method Analysis Date I By A4500·CI B 11109109 10:18 II, E353.2 1110910911:11 Ii_I Collection Date: 11102109 11 :05 Date Received: 11106/09 MCU QCL Method Analysis Date I By A450(),CI B 1110910910:21 11, E353.2 1110910910:59 1 i_I Coliection Date: 11/02/09 11:34 DateReceived: 11 /06/09 -------------------------------- MCU Analyses Result Units Qualifiers RL QCL Method Analysis Oate I By --------------------------------_ .• _._---_. MAJOR IONS Chloride Nitrogen, Nilrate+Nilrite as N Report RL • Analyte reporting limit. Definitions: QCl • Quality control limit. 55 mglL 20.8 mglL o . RL increased due to sample matrix interference. A4500·CI B 1110910910:2711, 0.2 E353.2 11109109 11 :02 1 i_I MCL -Maximum contaminant level. NO • Not detected at the reporting limit. ENERG r LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • p. 0. Box 3258 • Casper, W'( 82602 Toll Free 888235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· ww .. energylab.com LABORA TORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate and Chloride Lab 10: C09110253-005 Client Sample 10 : TWN 19R Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nilrale+Nitrite as N Lab 10: C09110253-006 Client Sample to: TWN 19 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrale+Nitrite as N Lab 10: C09110253-007 Client Sample 10: TWN 18R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrile as N Lab 10: C09110253-008 Client Sample 10: TWN 18 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report RL . Analyte reporting limit. Definitions: QCL . Quality control limit. 2 ND Result 125 7.4 Result 1 ND Result 57 1.3 mg/L mg/L Units mg/l mg/L Units mgfL mg/L Units mg/L mg/L Qualifiers RL 0.1 Qualifiers RL 1 0.2 ._----- Qualifiers RL 0.1 Qualifiers RL 0.1 MCU Report Date: 11111109 Collection Date: t 1/02/0913:20 DateRecelved: 11 /06/09 eel Method Analysis Dale I By A4500-CIB 11109/0910:30 Ilr E353.2 11109/09 11 :04 !jal Collection Date: 11102/09 13:42 DateRecelved: 11106/09 MCU QCL Method Analysis Datal By A4500-CIB 11109/0910:32/1r E353.2 11/09/0911:16/ial Collection Date: 11102109 15:00 DateReceived: 11/06/09 MCU QCL Method Analysis Date I By A4500·CIB 11109/0910:46/1r E353.2 11/09/09 11:19 /ial Collection Date: 11102/09 15:33 DateReceived: 11/06/09 -.---~--- MCU QCL Method Analysis Date I By A4500·CIB 11/09/0910:49 /1r E353.2 11109/0911:211 ial MCl . Maximum contaminant level. ND -Not detected at the reporting limit. ENERGY LABORATORIES, INC •• 2393 Sail Creek Highway (8260l}' p.D. Box 3258 . Casper, WY82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com · wWIY.snergylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate and Chloride Lab 10: C09110253-009 Client Sample 10: TWN 11 R Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nilrate-+Nilrite as N Lab 10: C09110253-010 Client Sample 10: TWN 11 Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nilrate+Nitrite as N Lab 10: C091 10253·011 Client Sample 10: TWN 12R Matrix: Aqueous Analyses Result Units NO NO mg/l mg/L Result Units 74 1.3 mg/L mg/l Result Units Qualifiers Qualifiers Qualifiers Rl 1 0.1 Rl 1 0.1 RL Report Date: 11/11109 Collection Date: 11/03/0908:20 DateRecelved: 11/06/09 MCU QCl Method Analysis Date I By A4500·CI B 11/09/0910:56 /1, E353.2 11/09/09 11 :24 I i.1 Collection Date: 11 /03/0908:53 DateRecelved: 11 /06/09 MCU QCl Method Analysis Date I By A4500-CI B 11109/09 11: 11 II, E353.2 11109/09 11 :26 I i.1 Collection Date: 11103/09 09:47 DateRecelved: 11106/09 MCU eel Method Analysis Date I By ----------------~------_. ---------.----------~ MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C091 10253·012 Client Sample 10: TWN 12 Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nilrate+Nitrite as N Report Rl . Analyte reporting limit. Deflnltions: ael . Quality control limit. NO NO mg/l mg/L Result Units 109 mg/l 0.5 mg/l 0.1 Qualifiers Rl 0.1 A4500-CI B 11109/09 11: 14 II, E353.2 11109/09 11 :34 I i.1 Collection Date: 11103/09 10:30 DateReceived: 11106/09 MCU Qel Method Analysis Oate I By A450G-CI B 11/09/09 11 :1611, E353.2 11109/09 11 :36 1 i.1 Mel -Maximum contaminant level. NO· Not detected at the reporting limit ENERG Y LABORATORIES, INC .• 2393 Sa/l Creek Highway (82601) • p.o. Box 3258 • Casper. wr 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com • WlYlY.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate and Chloride Lab 10: C09110253-01 3 Client Sample 10: TWN BR Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nitrate+Nitrile as N Lab 10: C09110253·014 Client Sample 10: TWN B Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nitrate+Nilrite as N Lab lD: C09110253·015 Client Sample 10: TWN6R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C09110253·016 Client Sample 10: TWN 6 Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nitrate+Nitrite as N Report RL . Analyte reporting limit. Definitions : ael · Quality control limit. Result Units 3 NO mg/L mg/L Result Units 12 NO Result NO NO mg/l mgfL Units mg/l mg/L Result Units 21 1.4 mg/l mg/l Qualifiers Rl 0.1 Qualifiers Rl 0.1 ~~- Qualifiers Rl 1 0.1 Qualifiers RL 0.1 Report Date: 11/11 /09 Collection Date: 11 /03/0913:10 DateRecelved: 11106/09 MCU QCl Melhod Analysis Date I By MCU A4500-CI B 11 /09/09 11:18 /1, E353.2 11 /09/09 11 :39 1 ial Collection Date: 11103109 13:45 DateReceived: 11106/09 QCl Melhod Analysis Date I By MCU QCl A4500·CI B E353.2 11109/09 11 :21 I lr 11 /09/09 11 :41 I ial Collection Date: 11103/09 14:35 DateRecelved: 11106/09 Method Analysis Date/ By A4500·CI B 11 /0910911 :2511, E353.2 11/09109 11 :44 1 ial Collection Date: 11/03/09 15:02 DateReceived: 11 /06/09 MCU Qel Method Analysis Date I By A4500·CI B 11109/09 11 :27 I I, E353.2 11/09/09 11 :54 1 ial Mel · Maximum contaminant level. NO . Not detected at the reporting limit. ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • P.D. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· WlYW.onergyJab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate and Chloride Lab 10: C091 10253-017 Client Sample 10: TWN 16R Matrix: Aqueous Analy ses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nitrile as N Lab 10: C09110253-018 Client Sample 10: TWN16 Matrix: Aqueous Analyses MAJOR tONS Chloride Nitrogen, Nilrate+Nitrite as N Lab to: C09110253-019 Client Sample 10: TWN 17R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrale+Nilrite as N Lab ID: C09110253-020 Client Sample 10: TWN 17 Matrix: Aqueous Analyses -. -~ --- MAJOR IONS Chloride Nitrogen, Nitrale+Nitrite as N Report RL -Analyte reporting limit. Definitions: ael . Quality control limit. 1 NO Result 39 1.0 Result NO Result 152 6.7 mg/L mg/L Units mg/L mg/L Units mg/l mg/l Units mg/L mg/L Qualifiers Qualifiers Qualifiers Qualifiers Rl 1 0.1 Rl 1 0.1 Rl 0.1 RL 0.2 Report Date: 11 /11 /09 Collection Date: 11104109 07:4 7 DateRecelved: 11106/09 MCU QCl Meth od Analysis Date/ By A4500·CI B 11 /09/09 11 :34 II, E353.2 11109/09 1 t :561 iol Collection Date: 11104/09 08: 15 OateReceived: 11106/09 MCU QCl Method Analysis Date I By A4500·CI B 11109/09 11 :37 II, E353.2 11109/09 11 :591 iol Collection Date: 11/04/0908:58 DateReceived: 11106/09 --~------. MCU QCl Method Analysis Date I By A4500-CI B 11109/09 11 :39/1, E353.2 11109/0912:01 I iol Collection Date: 11104/09 09:24 DateRecelved: 11106/09 MCU QCL Method Analysis Date I By A4500-CI B 11109/09 11 :41 /I, E353.2 11109/09 12:041 iol Mel -Maximum contaminant level. NO • Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 Salt Creek Highway (82601) • Po. Box 3258 . Casper, WY 82602 ToIIFree888.235.0515 • 301.235.0515 • Fax 301.234.1639' casper@energylab.rom·wwwenergy/ab.rom LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 41h Quarter Nitrate and Chloride Lab ID: C09110253-021 Client Sample tD: TWN 0 Matrix: Aqueous Report Date: 11111109 Collection Date: 11104/09 09:24 DateReceived: 11106/09 -------------------------- Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C09110253-022 Client Sample ID: TWN 13R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nilrate+Nitrite as N Lab ID: C09 110253-023 Client Sample ID: TWN 13 Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen, Nitrale+Niirile as N LabtD: C091 10253-024 Client Sample ID: TWN 14R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report Rl-Analyte reporting limit. Defi nitions: eCl-Quality control limit. Result Units 187 6.7 Result 1 NO mg/l mg/l Units mg/L mg/L Result Units 83 0.5 Result NO NO mg/L mg/l Units mg/l mg/l Qualifiers Qualifiers Qualifiers Qualifiers Rl 1 0.2 Rl 0.1 Rl 0.1 Rl 0.1 MCU QCl Method Analysis Date I By MCU QCl A4500-CI B 11109/09 11 :4311r E353.2 11109/0912:14 /i_1 Collection Date: 11/04/09 12:43 OateRecelved: 11/06/09 Method Analysis Date I By A4500·CI B 11109/0911:5111r E353.2 11/09/09 12:16/i_1 Coilection Date: 11104/09 13: 11 DateReceived: 11106/09 MCU QCl Method Analysis Date I By A4500·CI B 11109/09 11 :54 IIr E353.2 11109/09 12: 191 i_I Collection Date: 11/04/09 13:57 DateReceived: 11106/09 MCU QeL Method Analysis Dale I By A4500·CI B 11109/09 11 :5611r E353.2 11109/0 9 12:21 1 i_I MCl -Maximum contaminant level. NO -Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' Po. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com · WlVW.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate and Chloride Lab 10: C09 11 025 3-025 Client Sample 10: TWN 14 Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report Rl . Analyte reporting limit. Definitions: Qe l -Quality control limit. 32 3.4 mg/L mg/l Qualitrers RL 1 0.2 MCU Report Date: 1111 1109 Collection Date: 11 10410914:27 OateReceived: 11106109 QCl Method Analysis Date I By A4500-CI B 11/09/09 11 :59 Ilr E353.2 11109/09 12:24 I j_1 MeL -Maximum contaminant level. NO - Not detected at the reporting limit. ENERGY LABORATORIES, INC •• 2393 Salt Creek Highway (82601) • p.o. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 . casper@energylab.com· www.energylab.com QA/QC Summary Report Client: Denison Mines USA Corp Report Date: 11/11/09 Project: 4th Quarter Nitrate and Chtoride Work Order: C09110253 Analyte Result Units Rl %REC Low Limit High limit RPO RPOLimlt Qual Method: A4500·CI B Batch: 091109·Cl ·TIR·W Sample 10: MBlK9'()91109 Method Blank Run: TITRATION_091109A 11109/09 08:38 Chloride ND mg/L 0.4 Sample 10: C09110083'()01AMS Sample Matrix Spike Run: TITRATION_091109A 11/09/0909:42 Chloride 5030 mg/L 1.0 101 90 11 0 Sample 10: C09110083·001AMSO Sample Matrix Spike Duplicate Run: TITRATION_0911 09A 11109/09 09:45 Chloride 4960 mg/l 1.0 99 90 110 1.4 10 Sample 10: C09110253'()06BMS Sample Matrix Spike Run: TITRATION_091109A 11109109 10:35 Chloride 300 mg/L 1.0 99 90 110 Sample 10: C09110253·006BMSO Sample Matrix Spike Duplicate Run: TITRATION_091109A 11 /09/09 10:36 Chloride 302 mg/l 1.0 100 90 110 0.6 10 Sample 10: lCS35'()91109 Laboratory Control Sample Run: TITRATION_091109A 11 /09/09 10:39 Chloride 3600 mg/L 1.0 102 90 110 Sample 10: C09110253·016BMS Sample Matrix Spike Run: TITRATION_091109A 11 /09/0911 :31 Chloride 105 mg/L 1.0 95 90 110 Sample 10: C09110253·016BMSD Sample Matrix Spike Duplicate Run: TITRATION_091109A 11109109 11 :32 Chloride 108 mg/l 1.0 98 90 110 2.5 10 Sample 10: C09110266·001AMS Sample Matrix Spike Run: TlTRATION_091109A 11 /09/09 12:09 Chloride 52.1 mg/l 1.0 96 90 110 Sample 10: C09110266·001AMSD Sample Matrix Spike Duplicate Run: TlTRATION_091109A 11 /09/0912:10 Chloride 51 .2 mg/l 1.0 94 90 110 1.7 10 ----------- Qualifiers: Rl· Analyte reporting limit. NO · Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 SaIl Creek Highway (82601) • PO. Box 3258 • Casper. WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· wwwenergylab.com QA/aC Summary Report Client: Denison Mines USA Corp Project: 4th Quarter Nitrale and Chloride Analyte Result Units Method: E353.2 Sample 10: MBLK·1 Method Blank Nitrogen , Nilrate+Nilrile as N NO mg/L Sample 10: LCs·2 Laboratory Control Sample Nitrogen, Nitrale+Nitrile as N 2.50 mg/L Sample 10: C09110253·005AMs Sample Matrix Spike Nitrogen, Nitrate+Nitrite as N 1.93 mg/l Sample to: C09110253·005AMSO Sample Matrix Spike Duplicate Nitrogen, Nitrale+Nitrile as N 1.94 mgfL Sample 10: C09110253·015AMS Sample Matrix Spike Nitrogen, Nitrate+Nilrite as N 1.99 mg/L Sample 10: C09110253-ll15AMSO Sample Matrix Spike Duplicate Nitrogen. Nitrale+Nilri1e as N 2.03 mg/L Sample 10: C09110253·024AMS Sample Matrix Spike Nitrogen, Nitrate+Nitrite as N 2.16 mg/L Sample 10: C09110253·024AMSD Sample Matrix Spike Duplicate Nitrogen , Nilrate+Nitrite as N 2.37 mg/L Qualifiers: RL -Analyte reporting limit. S -Spike recovery outside of advisory limits. RL %REC 0.Q3 0.10 97 0.10 94 0.10 95 0.10 100 0.10 101 0.10 107 0.10 117 Report Date: 11111/09 Work Order: C09110253 Low Limit High Limit RPO RPDLimit Qual Balch: RI262tO Run: TECHNICON_091109A 11109/0910:49 Run: TECHNICON_091 t 09A 11109/09 to:51 90 110 Run: TECHNICON_091109A 11/09/09 tl:07 90 110 Run: TECHNICON_091109A 11/09/09 11 :09 90 110 0.5 10 Run: TECHNICON_091109A 11109/09 11:47 90 110 Run: TECHNICON_091109A 11 /09/09 11:49 90 110 2 10 Run: TECHNICON_0911 09A 11/09/0912:27 90 110 Run: TECHNICON_0911 09A 11109/09 12:29 90 110 6.4 10 5 NO -Not detected at the reporting limit. Chain of Custody and Analytical Request Record Page ~ of ~ , «Ci!@!!t't'U·UY*. PLEASE PRINT Provide as much Information as ossible. IRm~~Y ' Project Name, PWS, Permit, Etc, Sam pte Origin EPA/State Compliance: <-I'" 6.~ iU :\"'";~ • c.h \c>r;J.~ State l).-\-Yes 0 No 0 Dcn\~o~ M', (\ e-:::, Report Mait Address: PO BD)( P-:,I .. "'):", 0.. ,u. t 801\ Contact Name: Phone/Fax: Email: Sampler: (Please Print) lMr.' \ R~WI 'P..\"",<r' L\:.5 '-71! xu,\ hMnu HoI\:.k'(t Invoice Address: Invoice Contact & Phone: ~ Order: ~ Order: ~<. So.t'1~ Special Report/Formats: 15 ~ I ~ '\7~1JS OO~®QD~~[Q) ~O Vl~ ~[I)~OI Cii .. Contact ELI prior to I ~n~ed b' RUSH sample submittal \-Q.<i~ for charges and Dow D EOO/EOT(Electronic Dala) Format: "fj>a ~1; cU)'U! U'l ~ 0:>= ~ OJ u>ooc: '-« 001",'-1 '" o ~ e ... iti2c:-;:: ~a..rooD 0 ~ UJ t:. R scheduling -See ~\ Instruction Page D POT'NNVWTP I '0 RecaiptTemp () e Comments: D State: ___ _ D Other: ___ _ D LEVEL''C"IVc----- D NELAC 1:~I1ij , ::J Q).!: Q) s: Z 0.. .,::(] :ira E >1 '" en ~ SAMPLE IDENTIFICATION Collection MATRIX () Location. Interval, etc.} Time TWA) '3> R. I 11-2-oq I OqSL\ I ~-W 1')( I)' I' aWN 3 I \\-.?-Q'l, l-llIOc)=ri-w 1')( I)' ':rvJtJ :L R 1 \\-.;1.-011 I lI0S Ig.-v) I)' 1)< 'TwA! ~ I \\-~-00, I i 1:1,4 I ~-w Ix l:x i 'T~tJ \q R I II-d.-0'\ I !:,:lD b.-w 12, I'" 6 lvJtJ J1 I \1-;2.-D~ I 1~tG-I d--W llil- :J U '2. « e I-ro l-e « " On Ice: >-5 UJ " UJ ro H I On So!t1e (/) '0 e On Cooler ro iii Intact Signature Match () 7 1WN \1S R 111·;;1..-0,\ I ISOD I&.-w I" 1)< I I I I I I I I I I I~ rs -rWN lZ ~U:~-0'\ j \ 5::':' I ~-W I X I X I ~ 9 "i\..:lIJ \1 R III-::'-Oq I ()8~() Id-.-W 1')( 1)( I I I I I I I I I I I~ l°TWN \\ 11I-3-CY\l olSS3 Id.-W IxlX I I I I I I I I I I I~ I Custody HeceiV9(l Dy (print): u atOlI imc: ~lQnalure: Record Received by (print); Dalo/Time: Signature: °c 0 N -- Y N <:XlN ~N 0N MUSTbe~--------------------------------hc~~~~ __ ~~ ________ ~~~ ____ ~ Signed Sam Ie DisDosal: Return to Client Lab Disposal: ry: ~ ___ --- ee- In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested . This serves as notice of this possibility. All sUb-contract data will be clearly notated on your analytical report. VISit our web site at www.energylab.com for additional information, downloadable fee schedule, forms. and links. Chain of Custody and Analytical Request Record page .d.-of ~, '"!{((~Y ~ PLEASE PRINT (Provide as much information as Dossible.) Company Name: M~t)~ Project Name, PWS , Permit, Etc. N;tr~tc. a Sample Origin EPN State Compliance: D-c";!>CI\ 4Th ()1AAlh.-~ c,hlor:ac: State: t-\-r Yes 0 No 0 Report Mail Address: pO Bc)( 80'1 Contact Name: Phone/Fax: Email: Sampler: (Please Print) B\""Ait'\, u.t lS''1!>1\ R~AA ?",'~-cr 1..\3S b/g~, -,-:;.~"" l~o ll:a"1 Invoice Address: Invoice Contact & Phone: Pu rchase Order: Quote/Bottle Order: S"'I'IIc, 's"IY\<" Special Report/Formats: :;: ~17@!l© OO~®GD~~@ .. Contact ELI pri or to S~bc.'( , 0 RUSH sample submittal . ~O(f)~ ~ for charges and Cooter 10(5): ~co;gOI :v 0 « R scheduling -See ~~ i --> 0 >-1i; W t:. Instruction Page ficncnm3:; D OW D EOO/EDT(Electronic Data) c '" ~ I o~l5 ~ C'l "C Receipt Temp D POTWIWWTP Fonmat: U <= Comments: ~ « U)'ffi, ~ " U D State: D LEVEL IV 0 .. CL; c '§ « e 1-°c '-~ro.QO I-'" I-<= D Other: D NELAC ~~I-" ' ~ « :; On Ice: (j)N ~ Q).= iii!: V >-S zCi.<CIg>o ;§ W '" Custody Seal E >1 W '" On Bonle Y N '" l-/... m "C On Cooler 0 N <f) -:t () <= '" :: =j iii H Intact QN SAMPLE IDENTIFICATION Collection Collection MATRIX Signature 0)N (Name. Location, Interval, etc.) Date Time Match , l~ R Oql..\7 ~-W ')( iWN 1\-3-0'1 '/.. I~ 2 TWN \~ \ \-3-0'\ \O~O :loW 'f. 'f. 1~('(~\\~15~ 3 TwN 'DR 111-3-M \3\0 ~-W Ix X t9 4 TWN SS 111-~~O'\ 13L\S ~-vJ X X ''fvJrJ oR. 1\-~-o'l 1~3S g.-'.JJ If'. y.. ~ 'T\NN b Ii-:'-0'\ I SOd... d.-v::> y.. 'f ~ 7 ~ b1\ Il-~-CY{ 0747 '1-\,\) I" '/.. ~ 8 TwN 1(" Il-l.\ -0'\ Dg\~ ::l -\,,0 ).. ). ~ 9 -rvJN I1R )\-'-1 -Oil o~g ~-W I" 'f. I~ "1INN 17 ll-'-I-Oq O~~l{ l-W I). 1-I"" Custody ~~~~;"~:\l:a.,.~. III:i;me tOSO -;j "::::""/;,,,1. "h~ Received by (pnn!): OatefT1me: Signature: Record Relinquished by (print): r OatefTime: Signature: V Received by (print): OatefTime: Signature: MUST be Signed 7r··~"·~:·7 1.0'818 m'16: 'N.s-O:>lgna ure;......, ...?-" Sample Disoosal: Return to Client Lab Disposal: \ l'b . Cleo.. ~ -- In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information, downloadable fee schedule. forms. and links. Chain of Custody and Analytical Request Record Page~of~ l AGORA TORIE5 y Name: Den',~n M"Tl~ Report Mail Address: \,,0 B,()X B \""11. ·no. I U.T goq ~4 51 \ Invoice Address: S<UVl(' Special Report/Formats: Dow D EOO/EOT(Electronic Data) D POTWNVWTP D State: ___ _ D Other: ___ _ Format:.-;:-;-___ _ D LEVEL IV D NELAC SAMPLE IUt:N ".,\,;A "UN __ ,, ____ .. (Name, Location, Interval, etc.) Date Time PI ~.6.~~ PRlI"-IT ID,.n\lil'lq: as much information as Project Name, PWS, Permit, EtC. 4Th Qv-o .. rt-(:., N:+ro..tc. ~ Gh lDf ;~c Contact Name: Phone/Fax: R'(f'" ?"" rYl V 435 b7(5 ;;Qd. \ Invoice & Phone : ~~C 15 -~ W©D© rn@:®(\IJ~~@) '" ~O~~ ..... OJa::l._ul Q) .£>0 >..10 ~UJ~~~ 8~~k~r -< ..... COI c: ~~~§a l' ~~I~;: --: ::J~<Ig>CI . \.. ZE >1 C '" A--en "...c J MATRIX o ~ UJ 1::. I '0 () § <{ e f--'" f--E <{ ~ UJ 'E UJ '" (/) -g '" en " "I-',e Origin State: i).-\-Yes 0 No 0 Email: Sampler: (Please Print) I""n V I-lo 1\ ),o."\.- Purchase Order: OlJntp/Rnttle Order: .. R u s H Contact Ell prior to RUSH sample submittal for charges and scheduling -See ~ Instruction Page Comments: m. L °c (i)N .1 On Bonk! Y N On Cooler C!> N Intact ~ N Signature tV' \.. Match \!......fI'\I ThJI'J c) I \\-'1-D'l I o'Q.,i I J. __ hlJ_'6Jy 1 -'--J 1 __ Ll J _L .. J .. 1 ~ 2 "'TVJN 1:3> R I \\-11,-0'1 \;:)'l.\~ :)-w y. ~ ~U'A \\D'l.-'S~ 1 3 TwtJ 1~ I\-tl-c'l \~\ I ~-~ 'f.. y., In?: I '~N \ L\. R \\ -L\ -0'\ \3'07 ::l-w ')( 'I. Ii- I: IwN \4 I JI-~-O~ 1 14~7 1 :L-W I ~ I ~I I I I I I I I I I I • I 7 '%: 8 ~ , I~ 10 ~ :::ilgnatur8: I Custody Record hffl~~~~--~~~~~ Signature -JAM«" 1AIIh4a Signature: ~eCeiVed bYTPnrli): I H:eceived oy (print): JateJTimc: signature: MUST bel--___ _ Sig ned Sample Disposal: Return to Clien\: . Labl "7L .'] __ ~ ~~ .-/ l \ ,(., d'\ "14<, ~7 I-- In certain circumstances. samples submitted to Energy Laboratories. Inc. may be subcontracted to other certified laboratories in order to complete the analysis ~ This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information, downloadable fee schedule. forms. and links. Energy Laboratories Inc Workorder Receipt Checklist Denison Mines USA Corp Login completed by: Halley Ackerman Reviewed by: Reviewed Date: Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seats intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper containerlbottle7 Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? ContainerfTemp Blank temperature: Water· VOA vials have zero headspace? Water· pH acceptable upon receipt? Contact and Corrective Action Comments: None Ves 0 Ves 0 Ves D Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves D Ves 0 C09110253 Date and Time Received: 11/6/20099:45 AM Received by: al No D No D No D No D No D No D No D No D No D No D No D No D Carrier name: FedEx Not Present D Not Present D Not Present 0' No VOA vials submitted 0' Not Applicable D ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' P.O. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com · wlYlv.energylab.com CLIENT: Denison Mines USA Corp Date: ll-Nov-09 Project: 4th Quarter Nitrate and Chtoride CASE NARRA rIVE Sampte Delivery Group: C09110253 ORtGtNAL SAMPLE SUBMITTAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4·C (±2·C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process ha s begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE. SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB data reported by ELI reflects the results for seven individual Aroclors . VVhen the results for all seven are NO (not detected). the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required . If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service . Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -GilieHe, WY eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SO eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: US EPA: WY00002, Rad iochemical WY00937; FL-DOH NELAC: E87641 , Radiochemical E871017; California: 02118CA; Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify ELI's certification coverage by visiting www.energylab.com ELI appreciates the opportunity to provide you with this analytical service . For additional information and services visit our web page www.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • p.o. Box 3258 . Casper. WY 82602 TOil Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· wlVIY.energylab.com ANALYTICAL SUMMARY REPORT November 04, 2009 Denison Mines USA Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C09101104 Project Name: 4th Quarter Nitrate & Chloride Energy Laboratories, Inc. received the following 8 samples for Denison Mines USA Corp on 10/29/2009 for analysis. Sample 10 Client Sample 10 Collect Date Receive Oate Matrix Test C09101104-001 UWLP 10/27/0909:10 10/29/09 Aqueous E300.0 Anions Nitrogen, Nitrate + Nitrite C09101104-002 Piez 1 10/27/0909:35 10/29/09 Aqueous Same As Above C09101104-003 Piez 2 10/27/0910:20 10/29/09 Aqueous Same As Above C09101104-004 Piez 3 10/27/0910:30 10/29/09 Aqueous Same As Above C09101104-005 TWN-1R 10/2 8/09 08:20 10/29/09 Aqueous Same As Above C09101104-006 TWN-1 10/28/09 13:20 10/2 9/09 Aqueous Same As Above C09101104-007 TWN-4R 10/28/0910:10 10/29/09 Aqueous Same As Above C09101104-008 TWN-4 10/28/0913:1010/29/09 Aqueous Same As Above As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: &:rrhl..!w, J), U)..o .hP Stephnie D. Waldrop 1 Reporting Supervisor ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • p.D. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· www.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate & Chloride Lab 10: C09101104-001 Client Sample 10 : UWLP Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen. Nitrate+Nitrite as N Lab 10: C09101104-002 Client Sample 10 : Piez 1 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen. Nitrate+Nitrile as N Lab 10: C09101104-003 Client Sample 10 : Piez 2 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C09101104-004 Client Sample 10: Piez 3 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report Rl . Analyte reporting limit. Definitions: QCl· Quality control limit. 3 NO Result 61 7.4 Result 7 0.6 Result 19 1.2 mg/L mg/L Units mgfL mg/L Units mgfl mglL Units mglL mg/l Qualifiers RL 0.1 Qualifiers RL 0.2 Qualifiers RL 0.1 Qualifier. RL 0.1 MCU Report Date: 11/04/09 Collection Date: 10/2710909:10 OateRecelved: 10/2 9/09 QCL Method Analysis Oate I By E300.0 E353.2 10/3110900:48 1 Iii 11102109 14:07 1 jal Collection Date: 10/27109 09 :35 OateRecelved: 10/29/09 MCU QCL Method Analysis Date / By E300.0 1013110901 :371 Iii E353.2 11102109 14:14 1 jal Collection Date: 10/2710910:20 DateRecelved: 10/29/09 MCU QCL Method Analysis Date I By E300.0 1013110901:53 1 Iii E353.2 11102/0914:17 / ial Collection Date: 10/27109 10:30 OateRecelved: 10/29/09 MCU QCL Method Analysis Dale I By E300.0 10131109 02:10 /Iil E353.2 11/02109 14:19 1 ial MCl . Maximum contaminant level. NO . Not detected at the reporting limit. ENERG Y LABORATORIES, INC .• 2393 SaU Creek Highway (82601) • P.O Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· wWlY.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate & Chloride Lab 10: C09101104·005 Client Sample 10: TWN-1 R Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrale+Nitrite as N Lab 10 : C091 011 04-006 Client Sample 10: TWN-1 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nilrate+Nilrite as N Lab 10: C091 011 04-007 Client Sample 10: TWN-4R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen. Nitrate+Nitrite as N Lab 10: C09101104-008 Client Sample 10 : TWN-4 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrale+Nitrile as N Report Rl -Analyte reporting limit. Definitions: QCl . Quality control limit. NO NO Result 18 0.5 Result NO NO Result 11 0.4 mglL mglL Units m9/L mg/L Units mg/L mg/L Units mg/L mg/l Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 MCU Report Date: 11104109 Collection Date: 1012810908:20 DateRecelved: 10129109 ael Method Analysis Date ' By MCU aCL MCU aCL MCU aCL E300.0 E353.2 10/31/0902:26 I Ijl 11/02/0914:22 1 jal Collection Date: 1012810913:20 DateRecelved: 10129109 Method Analysis Date I By E300.0 10/31 /0902:42 /1jl E353.2 11/02/09 14:241 jal Collection Date: 10/28109 10:10 DateReceived: 10129109 Method Analysis Dale I By E300.0 10/31 /09 02:59 I Ijl E353.2 11103/09 10:351 ial Collection Date: 1012810913:10 DateRecelved: 10/29109 Method Analysis Date I By E300.0 10/31109 03: 15 I ljl E353.2 11/03/09 10:38 /jal MCl -Maximum contaminant level. NO -Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 Sell Creek Highway (82601) • PO Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 307 235.0515 • Fax 307234.1639 • casper@energylab.com · wWIY.energylab.com QAlQC Summary Report Client: Denison Mines USA Corp Project: 4th Quarter Nitrate & Chloride Analyte Result Units Method: E300.0 Sample 10: LCS Laboratory Control Sample Chloride 9.74 mg/L Sample 10: MBLK Method Blank Chloride NO mg/L Sample 10: C09101104-001AMS Sample Matrix Spike Chloride 22.0 mg/L Sample 10: C09101104-001AMSO Sample Matrix Spike Duplicate Chloride 23.7 mg/L Sample 10: C09101121 -003AMS Sample Matrix Spike Chloride 21.6 mg/L Sample 10: C09101121-003AMSO Sample Matrix Spike Duplicate Chloride 22.3 mg/L Method: E353.2 Sample 10: MBLK-l Method Blank Nitrogen, Nilrate+Nitrite as N NO mg/L Sample 10: LCS-2 Laboratory Control Sample Nitrogen , Nitrate+Nitrite as N 2.50 mg/L Sample 10: C09101102-005HMS Sample Matrix Spike Nitrogen . Nitrate+Nitrite as N 1.81 mg/L Sample 10: C09101102-005HMSO Sample Matrix Spike Duplica te Nitrogen . Nitrate+Nitrite as N 1.85 mglL Sample 10: C091 011 04-006BMS Sample Matrix Spike Nitrogen. Nitrate+Nitrite as N 2.60 mg/L Sample 10: C09101104-006BMSO Sample Matrix Spike Duplicate Nitrogen. Nitrate+Nitrite as N 2.54 mg/L Qualifiers: RL . Analyte reporting limit. RL 1.0 0.04 1.0 1.0 1.0 1.0 0.03 0.10 0.10 0.10 0.10 0.10 Report Date: 11 /04109 Work Order: C09101104 %REC Low Lim it High limit RPD RPDlimit Qual Batch: R125839 Run: IC2-C_091029A 10/29/0920:36 97 90 110 Run: IC2-C_091029A 10/29/09 20:53 Run: IC2-C_091029A 10/31/0901 :04 95 80 120 Run: IC2-C_091029A 10/31 /0901:20 104 80 120 7.8 20 Run: IC2-C_091029A 10/31 /0905:10 98 80 120 Run: IC2-C_091029A 10/31 /0905:27 101 80 120 2.8 20 Balch: R125900 Run: TECHNICON_091102A 11/02/0910:57 Run: TECHNICON_091102A 11102/09 10:59 100 90 110 Run: TECHNICON_091102A 11 /02/0913:49 91 90 110 Run: TECHNICON_091102A 11102/09 13:52 93 90 110 2.2 10 Run: TECHNICON_091102A 11/02/09 14:27 107 90 110 Run: TECHNICON_091102A 11/0210914:29 104 90 110 2.3 10 NO -Not detected at the reporting limil. ENERG r LABORATORIES, INC •• 2393 Sail Creek Highway (82601) • P.o. Box 3258 . Casper, wr 82602 Toll Free 888.23!W515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com · WWlY.energylab.com QA/QC Summary Report Client: Denison Mines USA Corp Project: 41h Quarter Nilrale & Chloride Analyte Result Units Method: E353.2 Sample 10: MBLK·1 Method Blank Nitrogen, Nilrate+Nilrite as N NO mg/L Sample 10: LCS-2 Laboratory Control Sample Nitrogen. Nitrate+Nitrite as N 2.57 mg/L Sample 10: C09101127-001AMS Sample Matrix Spike Nitrogen, Nitrate+Nitrite as N 2.25 mglL Sample 10: C09101127·001AMSO Sample Matrix Spike Duplicate Nitrogen, Nilrate+Nitrite as N 2.26 mg/L Qualifiers: Rl-Analy1e reporting limit. RL 0.03 0.10 0.10 0.10 Report Date: 11/04/09 Work Order: C09101104 %REC Low limit High Limit RPO RPOLlmlt Qual Batch: R125947 Run: TECHNICON_091103A 1110310910:10 Run: TECHNICON_091103A 11103/0910:13 103 90 110 Run: TECHNICON_091103A 11103109 10:28 106 90 110 Run: TECHNICON_091103A 11103109 10:30 106 gO 110 0.4 10 NO -Not detected at the reporting limit. /i&lWj Chain of Custody and Analytical Request Record Page ---1-of +--,«"m.10k_kU. PI 1=4.!=i.F P~INT IPl"nvirl,,! as muctljnformation as possible.) y Name: 1),-AI;c,,»N (V\;N~5 i 7/l/t;i P)/;l;k-J chft,z;j& I ::;:Ieo;~;-Yes [SJ .... UIII~IIClII'-'t::. No 0 Report Mail At'OS. ~ 1>~r {l;J~M~ O.r ~'f SI/ Invoice I "s", .... ""- Special Report/Formats: Dow D EOO/EOT(Electronic Data) D POTWIWWTP Format:. ____ _ D State: ___ _ D Other: ___ _ D LEVEL IV D NELAC SAMPLE IDENTIFICATION I 7z:~epJM:hOnj;~ _ t??/ I Invoic~ Contact & Phone: c-~. :;: o -~o cn~ :!!oo;gOI Q; . _> 0 >-co ~(/)~rn~ o~~ ~ en U «(1)1.2 ~ '0 .. Q>~I.E ~ ~ro g o t:~I", ' ::J 0).: Cii 3: zC5..«lapo E >1 &G:!l&I1 ')1@[]@ ~~®Q!.J~~IID ~ ~ ~;:, (Name, Location. Int"rv-"1_etc.) , llbJLP ILb'l11JJJJ111~ 11. -W~)( --------I' Hit r ., rn'71,of 1 t1q~f l · t 1 ~ 3 ,'f? 2.. td-n·()f 102 . 7 )( I-~(..i~~o-"-t1·oif I 102D I \ 1.2<J X 0 w I U « I-l-« W w (f) Email: : (Pleas A Print) 112, .. , ~/ntw.fl Purchase Order: ~ Order: I" ;::-I R ~ '0 " ~ I tJ '" E :> ~ I 5 '" '0 " '" iii I H Contact Ell prior to RUSH sample submittal for charges and Cooler 10 s): scheduling -See V ,~ .' MJ'O. Instruction Page C . l : ( ..Q . ~om Comments: Recelp -that w;/I ~(, -..5 °c ~~~1~f. _ c:::::y s." N •. hi. drJv 7~ AIAaAA £, On 8cl1l1c Y @ On Cooler (j N Intact ~ N Signature r.;.. N Match \!J v " I~ 1:5~\1 ~%t 1 1~1 /1 111 1 11111 I I I leTVJN -4 yh'J'l-o'/ Il'sfo l.a'-w JS(I")( 9 10 I Custody Received by (print): DatelTime: Signature: Record Rcccivod by (pnnt): DatefTlme· Signature MUSTbe~ ______________________________ ~~~ Sig_ned Sample Disposal: Return to Clien t: Lab DiSDosal: ref....) \o1''A'CU:m \Lj 10 ~ ____ In certain circumstances. samples submitted to Energy Laboratories. Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information. downloadable fee schedule. forms. and links. Energy Laboratories Inc Workorder Receipt Checklist IIII~II Denison Mines USA Corp Login completed by: Diane Downing Reviewed by: Reviewed Date: Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper containerlboltle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? Containerrremp Blank temperature: Water· VOA vials have zero heads pace? Water· pH acceptable upon receipt? Contact and Corrective Action Comments: None Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 C09101104 Date and Time Received: 10/29/20092:10 PM Received by: al No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier name: Hand Del Not Present 0 Not Present 0 Not Present 0" No VOA vials submitted 0" Not Applicable 0 ENERG r LABORATORIES, INC. ·2393 Sail Creek Highway (82601) • Po. Box 3258 . Casper, wr 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com • ww .. energylab.com CLIENT: Denison Mines USA Corp Date: 04·Nov·09 Project: 4th Quarter Nitrate & Chloride CASE NARRATIVE Sample Delivery Group: C09101104 ORIGINAL SAMPLE SUBMITIAL(S) All original sample submittals have been retumed with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4'C (±2'C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after co llection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low lOS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recomme nded delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE. SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB data reported by Ell reflects the results for seven individual Aroclors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qu alified contract laboratori es for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories. Inc. -Billings. MT eli-g -Energy Laboratories. Inc. -Gillette. WY eli-h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City. SD eli-t -Energy Laboratories. Inc. -College Station. TX CERTIFICATIONS: USEPA: WY00002. Radiochemical WY00937: FL-DOH NELAC: E87641. Radiochemical E871017; California: 02118CA; Oregon: WY200001 : Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES. INC. -CASPER.WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regUlatory enforcement should be certified in the sample state of origin. Please ve rify ELI's certification coverage by visiting IN'INW.energylab.com ELI appreCiates the opportunity to provide you with this analytical service. For additional information and services visit our web page VoIWW.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT ENERGY LABORATORIES, INC .• 2393 SahCreek Highway (82601)' p.D. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 307.2350515 • Fax 307.234.1639 • casper@energylab.com· www.energylab.com November 18. 2009 Denison Mines USA Corp 6425 S Hwy 191 Blanding. UT 84511 Workorder No.: C09110461 ANALYTICAL SUMMARY REPORT Projecl Name: 4th Quarter Nilrate & Chloride Energy Laboratories, Inc. received the following 11 samples for Denison Mines USA Corp on 11/1212009 for analysis. Sample 10 Client Sample ID Collect Date Receive Date Matrix Test C09110461·001 TWN-01 11/10/0912:3511/12/09 Aqueous Chloride Nitrogen, Nitrate + Nitrite C09110461-002 TWN-15R 11/10/0908:25 11/12/09 Aqueous Same As Above C09110461-003 TWN-15 11/10/0908:5311/12/09 Aqueous Same As Above C09110461-004 TWN-10R 11/10/0910:1011/12/09 Aqueous Same As Above C091 10461-005 TWN-10 11/10/09 10:22 11112109 Aqueous Same As Above C09110461-006 TWN-9R 11/10/0911 :0511112/09 Aqueous Same As Above C091 10461-007 TWN-9 11/10/0912:0911/12/09 Aqueous Same As Above C09110461 -008 TWN-SR 11/10/09 12:45 11/12/09 Aqueous Same As Above C091 10461-009 TWN-S 11/10/0913:1911/12/09 Aqueous Same As Above C091 10461-010 TWN-7R 11110/0914:0011/12/09 Aqueous Same As Above C09110461-011 TWN-7 11110/0914:1311/12/09 Aqueous Same As Above As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report. or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: Stephnie D. Waldrop I Reporting Supervisor ._------ ENERGY LABORATORIES, INC .• 2393 SoH Creek Highway (82601)' p.o. Box 3258 • Casper. WY 82602 Toll Free 888.235.0515 • 307.2350515 • Fax 307.234.1639 • casper@energylab.com · ",ww.energylab.com LABORA TORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate & Chloride Lab 10 : C09110461-001 Client Sample 10: TWN -D1 Matrix: Analyses MAJOR IONS Chloride Aqueous ---- Nitrogen, Nitrate+Nitrite as N Lab 10: C09110461 -002 Client Sample 10: TWN-15R Matrix: Analyses MAJOR IONS Ch loride Aqueous Nitrogen, Nitrate+Nitrite as N Lab 10: C09110461 -003 Client Sample 10: TWN-15 Matrix: Analyses MAJOR IONS Chloride Aqueous Nitrogen , Nilrate+Nitrite as N Lab 10: C09 11 0461-004 Client Sample 10: TWN-10R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen , Nitrate+Nitrite as N Report Definitions: Rl . Analyte reporting limit. QCl· Quality control limit. Result Units NO NO mg/L mg/l Result Units 23 NO mg/L mg/l Result Units 78 1.1 Result NO NO mg/L mg/L Units mg/l mgll Qualifiers RL 0.1 Qualifiers RL 0.1 QualifIers RL 0.1 Qualifiers RL 0.1 Report Date: 11118/09 Collection Date: 11/101091 2:35 DateRecelved: 11 /12/09 MCU QCL Melhod Analysis Date I By A4500-CI B 11113/09 14:16/1, E353.2 11 /17/09 12:51 1 jal Collection Date: 11110109 08:25 Date Received: 11112109 --.. _----- MCU QCL Method Analysis cate J By A4500·CI B 11113/0914:18/1, E353.2 1111710912:53/jal Collection Date: 1111010908:53 DateReceived: 11112109 MCU QCL Method Analysis Date I By A4500-CI B 11113/0914:21 I I, E353.2 11117109 12:56 1 jal Collection Date: 11/1010910:10 DateReceived: 11112109 MCU QCL Method Analysis Date I By A4S00-CI B 11113/0914:2411, E353.2 11117109 12:58 1 jal MCl -Maximum contaminant level. NO · Not detected at the reporting limit. ENERGY LABORATORIES, INC •• 2393 Sal! Creek Highway (82601) • po. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com· www.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 41h Quarter Nilrale & Chloride Lab 10: C09110461·005 Client Sample 10: TWN·10 Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrale+Nitrite as N Lab 10: C09110461·006 Client Sample 10: TWN·9R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C09110461·007 Client Sample ID: TWN·9 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C09110461·008 Client Sample ID: TWN·5R Matrix: Aqueous Analyses --- MAJOR IONS Chloride Nitrogen , Nilrate+Nitrite as N Report Rl . Analyte reporting limit. Definitions: aCl . Quality control limit. 26 1.4 Result 1 ND Result 205 12.0 Result ND ND mg/l mg/L Units mg/L mg/L Units mg/L mg/L Units mg/L mg/l Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.2 Qualifiers RL 0.1 Report Date: 11118/09 Collection Date: 11 /1010910:22 DateReceived: 11112/09 MCU QCL Method Analysis Date I By A4500·CIB 1111 3/09 14:2711r E353.2 11117109 13:01 1 ial Collection Date: 11 /1010911 :05 DateReceived: 11 /12/09 MCU QCL Method Analysis Date I By A4500·CI B 11113/0914:30 /1r E353.2 1111710913:11 1 ial Collection Date: 11/10/0912:09 OateReceived: 11112/09 MCU QCL Method Analysis Date I By A4500·CI B 11113/09 14:33 /1r E353.2 1111710913:131ial Collection Date: 1111010912:45 DateReceived: 11112109 MCU QCL Method Analysis Date I By A4500·CI B 11113/0914:36 11r E353.2 1111710913:16 1ial Mel · Maximum contaminant level. NO . Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 Salt Creek Highwsy(82601J· p.D. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· www.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate & Chloride Lab 10: C09110461-009 Client Sample 10: TWN-5 Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nilrite as N Lab 10 : C09110461-010 Client Sample 10: TWN-7R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: COS110461-011 Client Sample 10: TWN-7 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report Definitions: RL . Analyte reporting limit. aeL· Quality control limit. 48 0.2 Result ND ND Result 7 0.1 mglL mglL Units mglL mglL Units mg/L mglL Qualifiers Qualifiers Qualifiers Rl 1 0.1 RL 1 0.1 Rl 0.1 MCU Report Date: 1111 8/09 Collection Date: 11/10109 13:19 OateRecelved: 11/12/09 QCl Method Analysis Date I By A4500-CIB 11113/0914:40 /1, E353.2 11117109 13: 181 jol Collection Date: 11/1010914:00 OateReceived: 11/12/09 MCU QCl Method Analysis Oate J By A4500-CI B 1111 310914:47 11, E353.2 11117109 13:21/ iol Collection Date: 1111010S 14:13 Date Received: 11112/09 MCU QCl Method Analysis Date I By A4500-CI B 11113/0S 14:49 /1, E353.2 1111710913:281 iol Mel -Maximum contamlnanllevel. NO -Not deteded allhe reporting limit. ENERG r LABORATORIES, INC .• 2393 Sah Creek Highway (8260 I) . Po. Box 3258 • Casper, WY 82602 Tolf Free 888.2350515 • 301.2350515 • Fax 301.234.1639 • casper@energylab.com· wwwenergylab.com QA/QC Summary Report Client: Denison Mines USA Corp Project: 4th Quarter Nitrate & Chloride Analyte Method: A4500·CI B Sample 10: MBLK9'()91113 Chloride Sample 10: C0911046t '()09AMS Chloride Sample 10: C09110461'()09AMSD Chloride Sample 10: LCS35·091113 Chloride Method: E353.2 Sample 10: MBLK-1 Nitrogen, Nitrale+Nitrite as N SamplelD: LCS·2 Nitrogen, Nitrate+Nitrite as N SamplelD: C09110461'()05BMS Nitrogen, Nitrale+Nitrite as N SamplelD: C09110461'()05BMSD Nitrogen, Nitrate+Nitrite as N SamplelD: C09110474'()04FMS Nitrogen, Nitrate+Nitrite as N SamplelD: C09110474'()04FMSD Nitrogen, Nitrate+Nitrite as N Qualifiers: RL . Analyte reporting limit. Result Units Method Blank ND mg/L Sample Matrix Spike 222 mg/L Sample Matrix Spike Duplicate 224 mg/L Laboratory Control Sample 3600 mg/L Method Blank ND mg/L Laboratory Control Sample 2.56 mg/L Sample Matrix Spike 3.93 mg/L Sample Matrix Spike Duplicate 3.90 mg/L Sample Matrix Spike 2.0S mg/L Sample Matrix Spike Duplicate 2.16 mg/l S . Spike recovery outside of advisory limits. Report Date: 1 t /t 6109 Work Order: C09110461 Rl %REC Low limit High Limit Run: TITRATION_OSII13B 0.4 Run: TITRATION_091 I 13B 1.0 99 SO 11O Run: TITRATION_OS1113B 1.0 10O SO 11O Run: TITRATlON_091 I 13B 1.0 102 90 11O Run: TECHNICON_091 117A 0.03 Run: TECHNICON_091 I 17A 0.10 102 90 11O Run: TECHNICON_091 I 17A 0.10 84 90 11O Run: TECHNICON_OSI I 17A 0.10 83 90 11O Run: TECHNICON_091 I 17A 0.10 104 SO 11O Run: TECHNICON_091 I 17A 0.10 108 90 11O NO . Not deteded at the reporting limit. RPD RPDLlmlt Qual Balch: 091113·CL·TIR-W 0.8 0.8 3.3 11113/09 14:04 t1/13/0914:43 11113/0S 14:44 10 11/13/0915:19 Batch: R I 26597 11/1710910:11 11/17/09 10: I 3 11/17/0S 13:03 S 11/17/0913:06 10 S I III 7/0S 13:4 I 11I17IOS 13:43 10 .Sii[!I:·U~Elfl{tC.'" PLEASE PRINT (Provide as much information as oossible.1 ----- Company Name: Project Name, PWS, Permit, Etc. Sample Origin EPA/State Compliance: De.!1·I~" M :f1(:~ 4'1"'1 Q~~r /IJ ,~(q..t(. ~ c.J, 10 r~J.{, State: U-f Yes 0 No 0 Report Mail Address: Po ~("'ol <60~ Contact Name: Phone/Fax: Email: Sampler: (Please Print) l?>lc...n6.;(~ l)..-\-1)45\\ R~"" p<l.\tI\~r 43'" (,,7't. ~\ -R~M P'J",(,r Invoice Address: Invoice Contact & Phone: Purchase Order: QuotelBonle Order: ~f1\(., SA.IY\~ Special Report/Formats: :;:: &W&I117@O@ ~~®(1I)~~[Q) .. Contact Ell prior to '"*' IV ! 0 RUSH sample submittal ~OCl)~ 2:" ~ ;::-R for charges and COOlOnD(S): I ~m;gal Q; 0 scheduling -See (Jh(/J'J J ·_>o>-cti « Dow D EOO/EOT(Electronic Data) 19 (I) (I) ro ~ :r P-UJ t:. Instruction Page , C '" '" I o~~ ~ en ~. "0 Receipt emp D POTWNVWTP ..., U e Comments: I Fonmat: u 10 .£ :J U d _<c (I) iiSl.:;.! f;t' -' « a I D State: D LEVEL IV o .. Q;c:.§ 0;...-ro °c ~ ~cti 00 I- D Other: D NELAC (' l-e C.:J'N ~I~' « :; On Ico: :::JC1I.=o:;.~ ..... S ZCi.<CI~O UJ 12 Custody Seal C E >1 UJ '" On Bottle '" (f) "0 en e On Cooler Y N !!l H Intact )~ en SAMPLE IDENTIFICATION Collection Collection MATRIX Signature (Name. Location, Interval, etc.) Date Time Match Y N , ~ )( ""1\NN-Di. \I-\O-uo. 1 ~~"S ~-W ><. taa\\~\ ! 2 3 4 5 ~ 6 ~ 7 ~ 8 ~ 0 9 I~ k;;:i " I"" i v, Custody i2:=b~rz): DateITlmo: lZ-M"0( Received by (print): Daterr1me: Signature: Il-Il-()(\ \\(\C\ Record Relin<Jjlshed by (print): Datemme: l ignatup : Received by (print): Daterrime: Signature: MUST be Signed Sample Disposal: Return to Client: Lab Disposal: ocellI y d~, ':, 'Y • ./ u·'·"''0'd/M tJ.'3 C '~~--=--, r:. requested This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information. downloadable fee schedule. forms. and links. I4~WI M@.k&'··4'1i' Chain of Custody and Analytical Request Record PLEASE PRINT IProvide as much information as possible.) page..:l-of 2 · :\...oUII ]5;:,SON W1.;.I1~~ Project Name, PWS, Permit, Etc. I Sample Origin L[1I-Clou N,.~ j J,~ State lAo(" Yes 0 No 0 Report Mail Mdress: A ~tJ'I /). cJ. ~ VI Contact Name: Phone/Fax: Email: Sampler: (Please Print) (IL/"", .:. t4f tlfSJ I ~ __ ~AI____ illS" 'ff 4M;s l'Ktc j)",L..- Invoice AddreSs: I c. ... ~.::.- lnvo~ Contact & Phone: I Purchase Order: ---""'" ........ Qud'te/Bottle Order: Special Report/Formats: f5 ~ I &ro&I1 'i:7@O@ IM~®Q!J~@) ~o (I)~ ~CO;gOI Qi o ~ w t::. I '0 (,) § <! Ie I" Contact ELI prior to RUSH sample submittal lor charges and scheduling -See Instrudion Page ":jt:~v I CooieTiO Sf: Dow rii>ci5 ;g-ro D EOO/EOT(Electronic Data) Co~2! ~;:: R (Jjr/~L :> '15 ro 0> Format: ~ <(J)I~I~ D LEVEL IV ~ ~'* g;§ o POTWIWWTP o State: ___ _ I--'" u Comments: ReeelptTemp {)-. 0 c o Other: ___ _ r-~~~ ______________ D __ ,N_E_LA ___ c __ -. ________ ~~_:_~_~_:_~_,f5_'~~:j I--E <! .= w 'E W '" (f) 1:1 On Ice: Y. N SAMPLE IDENTIFICATION Collection MATRIX~"":; (Name, Location, Interval, etc.) Time '" iii Custody Seal s o,So'O b(l On Cooler N Intact Y N Signature Y N Match H :r-1AW-I6'fL_ ,_IIJ.JO·~1 1 ~8'h£ IJ.-w 16'lx l I I I_I 1_1_1 Ll XL. ___b", ISJgl I' ( I~ 1 ( 1 ~~llllllll ll g 1 ~ ~11) \ ItwN-'fR. I 1 1'J/05' I J IXlx l I I I I I I I I I x F I 7wAf~ If' I 7 1'7,01 I t ~~ r~ I I I I I I I I I I ~t= 'Jl.JJI -/;e. 7 J2.l{b)( Y X I !rtuAl-S-I \ 1131'r I ) 1)£1)( I I I I I I I I I 1)( 177_/A/·,_zJL ._J) 1/400 I JXlx I I I I I I I I I 1')< I ThJAI~ r III·to·{ff I JIf/3 Ij-W 1")<1);( I I I I 1 I II I _J x I I~ I Custody /lblJ Reo •• "," by (.">11' D,J,I!T""'" S~n"ijiij' Record Rec8lved by (print): DatefTime: Signaturo: MUSTbe~ ____________________ ~ ________ -,~~~~~ __ ~~~ __ ~~~~ __ ~~~ S · ed 'Y' • 'A' C! <;13 /. .goa "':::~ Ig" Sample Disposal: Return toClien!: Lab Disoosol, r-f W V / / V ~ ././ In certain circumstances. samples submitted to Energy Laboratories. Inc. may be subcontracted to other certified laboratories in order to complete the analysis r-~ This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information, downloadable fee schedule. forms, and links. Energy Laboratories Inc Workorder Receipt Checklist 11111111111 I Denison Mines USA Corp Login completed by: Halley Ackerman Reviewed by: Reviewed Date: Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample boHles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? ContainerfTemp Blank temperature: Water -VOA vials have zero headspace? Water -pH acceptable upon receipt? Contact and Corrective Action Comments: None Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 2"C On Ice Ves 0 Ves 0 C09110461 Date and Time Received: 11/12/20099:30 AM Received by: al No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier name: FedEx Not Present D Not Present 0 Not Present 0' No VOA vials submitted 0' Nol Applicable 0 ENERG Y LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • Po. Box 3258 • Casper. WY 82602 Toll Free 888.23!;:O515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com · Wlmenergylab.com CLIENT: Denison Mines USA Corp Date: 18-Nov-09 Project: 4th Quarter Nitrate & Ch loride CASE NARRATIVE Sample Delivery Group: C091 10461 ORIGINAL SAMPLE SUBMITIAL(S) All original sample submittals have been returned with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4'C (±2'C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed B days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE. SIMAZINE AND PCB ANALYSIS Data for PCBs. Atrazine and Simazine are reported from EPA 525.2. PCB data reported by Ell renects the results for seven individual Aroclors. When the results for all seven are NO (not detected). the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so. ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories. Inc. -Billings, MT eli-g -Energy Laboratories. Inc. -Gillette. WY eli·h· Energy Laboratories, Inc .. Helena, MT eli-r -Energy Laboratories. Inc. -Rapid City. SO eli-t -Energy Laboratories. Inc. -College Station. TX CERTIFICATIONS: USEPA: WY00002. Radiochemical WY00937; FL-DOH NELAC: E87641 , Radiochemical E871017; California: 02118CA; Oregon: WY200001 ; Utah : 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The resulls of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES. INC. -CASPER.WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify Ell's certification coverage by visiting WWvV.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page www.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT ENEflG Y LABOflATOflIE5, INC .• 2393 Sail Creek Highway (8260 1) • Po. Box 3258 . Casper. WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com · www.energylab.com ANALYTICAL SUMMARY REPORT November 04.2009 Denison Mines USA Corp 6425 S Hwy 191 Blanding. UT 84511 Workorder No.: C09101104 Project Name: 4th Quarter Nitrate & Chloride Energy Laboratories. Inc. received the following 8 samples for Denison Mines USA Corp on 10/29/2009 for analysis. SamplelD Client Sample 10 Collect Date Receive Date Matrix Test C09101104-001 UWLP 10/27/0909:10 10/29/09 Aqueous E300.0 Anions Nitrogen. Nitrate + Nitrite C09101104-002 Piel1 10/27/0909:35 10/29/09 Aqueous Same As Above C09101104-003 Piel2 10/27/0910:20 10/29/09 Aqueous Same As Above C09101104-004 Piel3 10/27/0910:30 10/29/09 Aqueous Same As Above C09101104-005 TWN-1R 10/28/09 08:20 10/29/09 Aqueous Same As Above C09101104-006 TWN-1 10/28/09 13:20 10/29/09 Aqueous Same As Above C09101104-007 TWN-4R 10/28/0910:1010/29/09 Aqueous Same As Above C09101104-008 TWN-4 10/28/0913:10 10/29/09 Aqueous Same As Above As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QNQC Summary Report. or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: &~ho.M.R. u ) .. 0 be Stephnil!D:Waldrop I Reporting Supervisor ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' Po. Box 3258 . Casper, WY82602 Toll Free 888.235.0515 . 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· WWI.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate & Chtoride Lab ID: C09101104-001 Client Sample tD: UWLP Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nilrate+Nitrite as N Lab 10: C09101104-002 Client Sample ID : Piez 1 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrile as N Lab 10: C09101104-003 Client Sample ID: Piez 2 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab ID: C091 0 11 04-004 Client Sample ID: Piez 3 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Report Rl -Analyte reporting limit. Definitions: ael -Quality control limit. 3 NO Result 61 7.4 Result 7 0.6 Result 19 1.2 mg/L mg/L Units mg/L mg/L Units mg/L mg/L Units mg/L mg/L Qualifiers RL 0.1 Qualifiers RL 1 0.2 Quallflors RL 0.1 Qualifiers RL 0.1 MCU Report Date: 11104/09 Collection Date: 10/27109 09:10 DateRecelved: 10/29/09 QCL Method Analysis Datel By E300.0 E353.2 10/31/09 00:48 Ilil 11102/0914:07 1 iol Collection Date: 10/2710909:35 OateReceived: 10/2 9/09 MCU QCL Method Analysis Date I By E300.0 10/31/09 01 :37 I Iii E353.2 11102/0914:14 1 ial Collection Date: 10/27109 10:20 Date Received: 10/29/09 MCU QCL Method Analysis Date I By E300.0 10/3110901 :53 I Iii E353.2 11/02/0914:17 1 ial Collection Date: 10/2710910:30 DateRecelved: 10/29/09 MCU QCL Method Analysis Date I By E300.0 10/3 1/09 02:10 I Iii E353.2 11/02l09 14:19/jal Mel -Maximum contaminant level. ND -Not detected at the reporting limit. ENERGY LABORATORIES, INC .• 2393 Sah Creek Highway (82601)' p.D. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 307235.0515 • Fax 307234.1639 • casper@ener9ylab.com · wWlY.energylab.com LABORATORY ANALYTICAL REPORT Client: Denison Mines USA Corp Site Name: 4th Quarter Nitrate & Chloride Lab 10 : C091011 04-005 Client Sample 10 : TWN-1R Matrix: Aqueous Analyses Result Units MAJOR IONS Chloride Nitrogen, Nitrate+Nitrite as N Lab 10: C091 011 04-006 Client Sample 10: TWN-1 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen, Nilrate+Nilrite as N Lab 10: C091 011 04-007 Client Sample 10: TWN-4R Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen. Nitrale+Nitrile as N Lab 10: C09101104-008 Client Sample 10: TWN-4 Matrix: Aqueous Analyses MAJOR IONS Chloride Nitrogen. Nilrate+Nitrile as N Report RL . Analyte reporting limit. Definitions: QCL • Quality control limit. NO NO Result 18 0.5 Result NO NO Result 11 0.4 mglL mglL Units mg/L mg/L Units mglL mglL Units mg/L mg/L Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 Qualifiers RL 0.1 MCU Report Date: 11 /04/09 Collection Date: 10/28/09 08:20 DateRecelved: 10/29/09 QCL Method Analysis Date I By MCU QCL MCU QCL MCU QCL E300.0 E353.2 10/3110902:261 Iii 11/02/0914:22 /1al Collection Date: 10/28/09 13:2 0 DateRecelved: 10/29/09 Method Analysis Date I By E300.0 10/31/0902:42 /1il E353.2 11102/09 14:24 I ial Collection Date: 10/2 8/0910:10 OateRecelved: 10/29/09 Method Analysis Oate I By E300.0 10/31/09 02:59 I Iii E353.2 11/03/09 10:351 ial Collection Date: 10128/09 13:10 DateRecelved: 10/29/09 Method Analysis Date J By E300 .0 10/31109 03: 15 I Iii E353.2 11103/0910:381 ial MCL . Maximum contaminant level. NO . Not detected at the reporting limil. ENERG Y LASORA TORIES, INC .• 2393 Sail Creek Highway (82601) . P.o. Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234. 1639 • casper@energylab.com • IYlYlY.energylab.com QAlQC Summary Report Client: Denison Mines USA Corp Project: 4th Quarter Nitrate & Chloride Analyt. Result Unlt& Method: E300.0 Sampl e 10: LCS Laboratory Control Sample Chloride 9.74 m91L Sample 10: MBLK Method Blank Chloride ND mg/l Sampl e 10: C09101104·001AMS Sample Matrix Spike Chloride 22.0 mg/L Sampl e 10: C09101104·001AMSD Sample Matrix Spike Duplicate Chloride 23.7 mg/L Sample 10: C09101121·003AMS Sample Matrix Spike Chloride 21 .6 mg/L Sample 10: C09101121·003AMSD Sample MatriJl( Spike Duplicate Chloride 22.3 mg/L Method: E353.2 Sample 10: MBLK·1 Method Blank Nitrogen, Nitrate+Nitrile as N ND mg/L Sample 10: LCS·2 Laboratory Control Sample Nitrogen, Nitrate+Nitrite as N 2.50 mg/L Sample 10: C09101102·005HMS Sample Matrix Spike Nitrogen, Nitrate"'Nitrite as N 1.81 m9/L Sample 10: C09101102·005HMSD Sample Matrix Spike Duplicate Nitrogen, Nitrate+Nitrite as N 1.85 mg/L Sample 10: C09101104-006BMS Sample Matrix Spike Nitrogen, Nitrate+Nitrite as N 2.60 mg/L Sample 10: C09101104·006BMSD Sample Matrix Spike Duplicate Nitrogen, Nitrate+Nitri te as N 2.54 mg/L Qualifiers: RL -Analyte reporting limit. RL 1.0 0.04 1.0 1.0 1.0 1.0 0.03 0.10 0.10 0.10 0.10 0.1 0 Report Date: 11/04/09 Work Order: C09101104 %REC Low limit High Limit RPD RPOLImil Qual Batch: R125839 Run: IC2·C_091029A 10/29/0920:36 97 90 110 Run: IC2-C_091029A 10/29109 20: 53 Run: IC2-C_091029A 10/31/0901 :04 95 80 120 Run : IC2·C_091029A 1013 1/0901:20 104 80 120 7.8 20 Run: IC2-C_091029A 10/31/0905:10 98 80 120 Run: IC2-C_091029A 10131/0905:27 101 80 120 2.8 20 Batch: R125900 Run: TECHNICON_091102A 11/02/09 10: 5 7 Run: TECHNICON_091102A 11102/09 10:59 100 90 110 Run: TECHNICON_091102A 11/02109 13:49 91 90 110 Run: TECHNICON_091102A 11102/09 13:52 93 90 110 2.2 10 Run: TECHNICON_091102A 1110210914:27 107 90 110 Run: TECHNICON_091102A 11102109 14:29 104 90 110 2.3 10 NO -Not detected at the reporting limit. ENERG Y LABORATORIES, INC •• 2393 Sah Creek Highway (82601) • p.o. Box 3258 . Casper, WY 82602 Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@energylab.com· lYWIv.energylab.com QA/Qe Summary Report Client: Denison Mines USA Corp Project: 4th Quarter Nitrate & Chlorid e Analyte Result Units Method: E353.2 Sample 10: MBLK·l Method Blank Nitrogen, Nitrale+Nitrile as N NO mg/L Sample 10: LCS·2 Laboratory Control Sample Nitrogen, Nitrale+Nitrile as N 2.57 mg/L Sample 10: C09101127·001AMS Sample Matrix Spike Nitrogen, Nitrate+Nitrite as N 2.25 mglL Sample 10: C09101127·001AMSO Sample Matrix Spike Duplicate Nitrogen, Nitrate+Nitrile as N 2.26 mg/l Quallfler.: RL • Analyte reporting limit. RL 0.03 0.10 0.10 0.10 Report Date: 11 /04/09 Work Order: C09 101104 %REC Low limit High LImit RPO RPDUmit Qual Batch: R125947 Run: TECHNICON_091103A 11103109 10:10 Run: TECHNICON_091103A 1110310910:13 103 90 110 Run: TECHNICON_091103A 1110310910:28 106 90 110 Run: TECHNICON_091103A 11103109 10:30 106 90 110 0.4 10 NO • Not detected at the reporting limit. 14'+#(liW' Chain of Custody and Analytical Request Record mtn·"&k·lrUi, . .. . PLEASE PRINT Provide as much Informallon as ossible. Page ----I-of +- compan15;-I\IIS/)N iY1 ;",~S ~j~~7f::;'l PJ);1:kMk;ziJ6 :~a::le or~;..-"e Yes ~ No 0 Report Mail A~d~l/ ~ 'lrtJ1 Contact ~ame: /?1t{HiIAA 1.A.'1 g-lf,)/1 }2",,,, alMAd 61% -?'7-?1 Invoice I Iinvoicb Contact & Phone: rs""", €. C~U4A' Special Report/Formats: s: Li.\lk'l&I1 '\1@D@ ~~@(!JJ~@:@) Dow D EOO/EOT(Electronic Data) D POTWMlWTP D State: ___ _ D Other: ___ _ Fonnat:."..,. ___ _ D LEVEL IV D NELAC C) Qj ~O(l)..c:: :!!m;gol:;; ._> 0 >..10 ~(()~m~ O~'8 ~ en U «OOhQ ~ '0 .. C1~I.§ ~~I~~ § Q).=Q)~ Z-a«I~O E >1 '" <JJ SAMPLE IDENTIFICATION MATRIX (Name, Location, Interval, etc.) 1 "bJLP ~tJ'l1{)r l !JqfO 11-W IXIX' I' ~!; 'l ~~·i1.af I t11~~l l I ~ 3 =-;; i r d·n-Of lot ~ TY I' D;t.i.:~ ~b-iH)q I 1~30 I '" IXJ X >=" 0 « W t:. I '0 0 co :J <t e I-ro l-E <t :J >-w -e w ro (f) '0 co ro iii Email: .. R I:J 5 H . : (Pleasil Print) 1 121'~o.L M. L. "'() ~ Order: Contact ELI prior to RUSH sample submittal for charges and scheduling -See Instruction Page Comments: -tht..rt ",,;/1 ~(, ~t s,,11e1 ~'a ~~ ·Ju%. ~ --AIA.u.~_ :! Order: .~ I V~:::.':;';'S (7(,'< .... -1 cr, o °c On leo: (b N Custody Sea, 00 Bonle Y @ On Cooler ~ N Intact ~ N Signature r.,.. N Match \;.J '-"I~:li~~1 1~ ( =;" • ! l:jWni ~~~IWi£l l I I11111111 I m I I'TWtJ ~4 Yb'2~-o1lT~/([J:t-W=xrX] I I I I 1 __ L_nu ~ , I~ 10 I",JJ ~eceiV9Cl by (print): Signature: I Custody Record f-d~Y~~~.i..!#.~(jLI..~UfL.q:t!~~~::.Jl. ReceIVed by (pnnt): S.gnature: MUSTber-____________ _ R~b)'tabOr, _ _L~.--> ~Org'a:\rfi \ L( 10 ~ ____ 1":---.....1 Samole -' Return to Client: Lab I In certain circumstances, samples submitted to Energy Laboratories, Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information. downloadable fee schedule, forms. and links. Energy Laboratories Inc Workorder Receipt Checklist ~I"~I IIII Denison Mines USA Corp C091 011 04 Logi n completed by: Diane Downing Date and Time Received: 10/29/20092:10 PM Reviewed by: Received by: al Reviewed Date: Carrier name: Hand Del Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper containerlbottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? ConlainerfTemp Blank temperature: Waler· VOA vials have zero heads pace? Water· pH acceptable upon receipt? Contact and Corrective Action Comments: None Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 Ves 0 3·C On Ice Ves 0 Ves 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Not Present 0 Not Present 0 Not Present [21 No VOA vials submitted 0' Nol Applicable 0 ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601)' PO Box 3258 . Casper. WY82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com· Wlvw.energylab.com CLIENT: Denison Mines USA Corp Date: 04-Nov-09 Project: 4th Quarter Nitrate & Chloride CASE NARRATIVE Sample Delivery Group: C09101104 ORIGINAL SAMPLE SUBMITIAL(S) All original sample submittals have been retumed with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4'C (±2'C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low lOS waters. Data provided by thi s method for non potable waters should be viewed as inconsistent. RADON IN AIR ANALYSIS The desired exposure time is 48 hours (2 days). The time delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recom mended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLI D SAMPLES All samples reported on an as received basis unless otherwise indica ted. ATRAZINE, SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB data reported by ELI reflects the results for seven individual Arodors. When the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sample analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillette, WY eli·h • En ergy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc .. Rapid City, SO eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: USEPA: WY00002, Radiochemical WY00937; FL-DOH NELAC: E87641, Radiochemical E871017; Califomia: 02118CA; Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meet requirements as set forth by the above accred iting authorities. Some results requested by the dient may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin . Please verify ELI's certification coverage by visiting 'N"W\Y.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page w..vw.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT ENERGY LABORATORIES, INC .• 2393 Sail Creek Highway (82601) • P.O Box 3258 • Casper, WY 82602 Toll Free 888.235.0515 • 307235.0515 • Fax 307234.1639 . casper@energylab.com . wlYw.energylab.com ANALYTICAL SUMMARY REPORT October 21,2009 Denison Mines USA Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C09100620 Project Name: Frog Pond Energy Laboratories, Inc. received the following 1 sample for Denison Mines USA Corp on 10/15/2009 for analysis. Sample 10 Client Sample 10 Collecl Date Receive Date Matrix Test C09100620·001 Frog Pond 10/14/0908:52 10/15/09 Aqueous Nilrogen, Nitrate + Nitrite As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report. the QAlQC Summary Report, or the Case Narrative. If you have any questions regarding these tests results, please call. Report Approved By: ~~ ~ l()cl~ S ephanie D. Waldrop Reporting Supervisor ENERGY LABORATORIES, INC .• 2393 S.II Creek Highway(82601j • Po. Box 3258 • Casper, WY82602 ~ ~ Toll Free 888.235.0515 • 301235.0515 • Fax 301234.1639 • casper@energylab.com·www.energylab.com (AIlORATOtUC5 LABORATORY ANALYTICAL REPORT Client: Project: Lab 10: Denison Mines USA Corp Frog Pond C09100620-001 Client Sample 10: Frog Pond Analyses Result Units MAJOR IONS Nitrogen, Nitrate+Nitrite as N Report Definitions: Rl -Anaiyte reporting limit. QCL - Quality control lim it. ND m9/L Qualifiers Rl 0.1 Report Date: 10/21109 Collection Date: 10/14/0908:52 DateRecelved: 10/15/09 Matrix: Aqueous MCL! QCL Method Analysis Date I By E353.2 10/20/0915:541 ial MCl -Maximum contaminant level. NO -Not detected at the reporting limit. ENERG r LASORA TORIES, INC .• 2393 Sail Creek Highway (82601) • Po. Box 3258 . Casper. WY 82602 Toll Free 888.235.0515 • 307.235.0515 • Fax 307.234.1639 • casper@energylab.com . wWlv.energylab.com QAlQC Summary Report Client: Denison Mines USA Corp Project: Frog Pond Analyte Count Result Units Method: E353.2 Sample 10: MBLK-1 Nitrogen, Nitrate+Nitrite as N Sample 10: LCS·2 Nitrogen. Nitrale+Nilrite as N Sample 10: C09100600·0010MS Nitrogen. Nitrate+Nitrite as N SamplelD: C09100600·0010MSO Nitrogen, Nilrate+Nitrile as N Qualifiers: RL -Analyte reporting limit. Method Blank NO mg/L Laboratory Control Sample 2.44 mgfL Sample Matrix Spike 1.93 mgfL Sample Matrix Spike Duplicate 1.92 mgfL Report Date: 10/2 1/09 Work Order: C091 00620 RL '%REC low limit High Limit Run: TECHNICON_091020A 0.03 Run: TECHNICON_091020A 0.10 98 90 110 Run: TECHNICON_091020A 0.10 96 90 110 Run: TECHNICON_091020A 0.10 96 90 110 NO -Not detected at the reporting limit. RPD RPDlimit Qual 0.5 Balch: R125355 1012010912:51 10120109 12:54 10120/0915:44 10120109 15:46 10 .si~t:li"'tif'".U"''''.'' PLEASE PRINT (Provide as much information as possible.) Company Name: Project Name. PWS. Permit, Etc. Sample Origin EPA/State Compliance: D~.~o ..... yYl 'Xooo) (U s 1'1") (<> rp. f ro « I'~. State: iJ-!-.,.L-Yes D No D Report Mail Address: Contact'Name: Phone/Fax: Email: Sampler: (Please Print) f·o. B.." Yo, ·Ua:.;.dTIA'k. 'OF. "rJ-. zZ2.I J"~5"."rY-2Z2" U~1 .JTtdk:... S (,-,-J,..,.." U'/""L..... d"'-k.ed~,,.,~.....,_, .. -Invoice Address: Invoice Contact & Phone: Purchase Order: Quote/Bottle Order: -5 ........ _ -Sc.--c..- Special ReporVFormats: ;;: &GiJ&I1 'I7@O@ OO@:®I!iJ~~® .. Contact ELI prior to '~1!~iJJ. 0 RUSH sample submittal ~o '" I for charges and Cooler 10(5); Q; ~= r:-R c CO;gOI Ci> 0 « scheduling -See ( 1/1f~t1l-'B>~ ~ro w !::-Instruction Page Dow D EOO/EOT(Electronic Data) cU)Vi (/) ~ I o~= ~ C) "0 Receipt Temp D POTWNVWTP Format: u °oc U c Comments: _«U)lml:..;;;;: ::> U ~ D State: D LEVEL IV o ~ c <! e °c .... Q.i$ C'c f-ro ~a.mo o c D Other: D NELAC ~I~· f-:; On Ice: fJ/N ::Jd>.=Q)~ ~ <! .... S z~«laro W "E '-'~fJ E >1 W ro On Bottle Y N ro -\: (f) "0 en c On Coolor Y ro .z iii H Intact Y SAMPLE IDENTIFICATION Collection Collection MATRIX Signature N (Name. Location. Interval. etc.) Date Time Match , / F r","" P..........! 101,,,1,,, <; OflF;7.. I-W "'f)q /(j)&!){) 2 ~ ~ 3 t9 • 5 ~ , 16j 7 ~ • i8 , I~ 10 I~ Custody Relinquished by (print): O~je;:~ 'J'Y/P/ Received by (pnrt): OatolTime: Signature: -.u...:J T .... k-/D '/lJ'i I;!PI> Record Rellnq",,""" b~ o"emme ~~rur~ UJd Received by (pnnl): Datemme: Signature' MUST be .:J __ 'DI~I 0'\ I~O i Signed .:-r.-r \I.t ~ Lab Disposal: "'00"'00, 'CfJ1J'iifr,.,"".''If)rd.? / </: () 2-"9"' ure, SamDle DlsDosal Return to Chent In certain circumstances. samples submitted to Energy Laboratories. Inc. may be subcontracted to other certified laboratories in order to complete the analysis requested. This serves as notice of this possibility. All sub-contract data will be clearly notated on your analytical report. Visit our web site at www.energylab.com for additional information. downloadable fee schedule. forms. and links. Energy Laboratories Inc Workorder Receipt Checklist IIIIIIIIIIIIIII!! 1111111111 11111111111 Denison Mines USA Corp Login compleled by: Tabitha Edwards Reviewed by: Reviewed Date: Shipping container/cooler in good condition? Custody seals inlact on shipping container/cooler? Custody seals intact on sample bottles? Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers inlact? Sufficient sample volume for indicated test? All samples received within holding time? Containerrremp Blank temperature: Waler -VOA viats have zero headspace? Water -pH acceptable upon receipt? Contact and Corrective Action Comments: None Ves I{) Ves I{) Ves I{) Ves I{) Ves I{) Ves I{) Ves I{) Ves I{) Yes I{) Yes I{) Yes 0 Yes I{) C091 00620 Date and Time Received: 10115120092:02 PM Received by: em No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 No 0 Carrier name: Hand Del Not Present 0 Not Present 0 Not Present 0 No VOA vials submitted {{I Not Applicable 0 1#JJ..4il& ENERGY LABORATORIES, INC. ·2393 Sah Creek Highway (826(}f) • p.o. Box 3258 • Casper, WY 82602 ;n;;;~ Toll Free 888.235.0515 • 301.235.0515 • Fax 301.234.1639 • casper@ene'Yylab.com· l¥WI'<energy/ab.com , 1/" )/< 11, -,,'{, \ CLIENT: Denison Mines USA Corp Date: 21-0cl-09 Project: Frog Pond CASE NARRATIVE Sample Delivery Group: C091 00620 ORIGINAL SAMPLE SUBMITTAL(S) All original sample submittals have been retumed with the data package. SAMPLE TEMPERATURE COMPLIANCE: 4·C (±2·C) Temperature of samples received may not be considered properly preserved by accepted standards. Samples that are hand delivered immediately after collection shall be considered acceptable if there is evidence that the chilling process has begun. GROSS ALPHA ANALYSIS Method 900.0 for gross alpha and gross beta is intended as a drinking water method for low TDS waters. Data provided by this method for non potable waters should be viewed as inconsistent. RADON tN AIR ANALYStS The desired exposure time is 48 hours (2 days). The lime delay in returning the canister to the laboratory for processing should be as short as possible to avoid excessive decay. Maximum recommended delay between end of exposure to beginning of counting should not exceed 8 days. SOIUSOLID SAMPLES All samples reported on an as received basis unless otherwise indicated. ATRAZINE, SIMAZINE AND PCB ANALYSIS Data for PCBs, Atrazine and Simazine are reported from EPA 525.2. PCB data reported by ELI reflects the results for seven individual Aroclors. Vv'hen the results for all seven are NO (not detected), the sample meets EPA compliance criteria for PCB monitoring. SUBCONTRACTING ANALYSIS Subcontracting of sampte analyses to an outside laboratory may be required. If so, ENERGY LABORATORIES will utilize its branch laboratories or qualified contract laboratories for this service. Any such laboratories will be indicated within the Laboratory Analytical Report. BRANCH LABORATORY LOCATIONS eli-b -Energy Laboratories, Inc. -Billings, MT eli-g -Energy Laboratories, Inc. -Gillette, WY eli·h -Energy Laboratories, Inc. -Helena, MT eli-r -Energy Laboratories, Inc. -Rapid City, SD eli-t -Energy Laboratories, Inc. -College Station, TX CERTIFICATIONS: USEPA: WYOOOO2, Radiochemical WY00937; FL-DOH NELAC: E87641 , Radiochemical E871017; California: 02118CA; Oregon: WY200001; Utah: 3072350515; Virginia: 00057; Washington: C1903 ISO 17025 DISCLAIMER: The results of this Analytical Report relate only to the items submitted for analysis. ENERGY LABORATORIES, INC. -CASPER,WY certifies that certain method selections contained in this report meet requirements as set forth by the above accrediting authorities. Some results requested by the client may not be covered under these certifications. All analysis data to be submitted for regulatory enforcement should be certified in the sample state of origin. Please verify ELI's certification coverage by visiting WVMI.energylab.com ELI appreciates the opportunity to provide you with this analytical service. For additional information and services visit our web page www.energylab.com. THIS IS THE FINAL PAGE OF THE LABORATORY ANALYTICAL REPORT Tab G CSV Files to be sent via email by 1-4-10 Tab H TWN -1 Date Nitrate (mg/I) Chloride (mg/I) 2/6/2009 0.7 19 7/21/2009 0.4 17 9/21/2009 0.4 19 10/28/2009 0.5 18 TWN-2 Nitrate (mg/I) Chloride (mg/I) Date 2/6/2009 25.4 29 7/21/2009 25 25 9/21/2009 22.6 17 11/2/2009 20.8 55 TWN-3 Nitrate (mg/I) Chloride (mg/I) Date 2/6/2009 23.6 96 7/21/2009 25.3 96 9/21/2009 27.1 99 11/2/2009 29 106 TWN-4 Nitrate (rng/I) Chloride (rng/I) Date 2/6/2009 1 13 7/21/2009 0.05 12 9/21/2009 0.4 13 10/28/2009 0.4 11 TWN-5 Nitrate (mg/I) Date 8/25/2009 9/21/2009 11/10/2009 22 0.5 0.2 Chloride (mg/I) 42 45 48 TWN -6 Nitrate (mg/I) Date 8/25/2009 9/22/2009 11/3/2009 3.2 1.6 1.4 Chloride (m g/I) 32 13 21 TWN-7 Date 8/25/2009 9/21/2009 11/10/2009 Nitrate (mg/l) Ch loride (mg/l) ND 11 ND 7 0.1 7 TWN-8 Nitrate (rng/I) Chloride (rng/I) Date 8/25/2009 ND 11 9/21/2009 ND 12 11/10/2009 ND 12 TWN-9 Nitrate (rng/I) Date 8/25/2009 9/22/2009 11/10/2009 9.3 8.9 12 Chloride (rng/I) 169 201 205 TWN-lO Nitrate (mg/I) Date 8/25/2009 9/22/2009 11/10/2009 1.1 1.6 1.4 Chloride (mg/I) 19 35 26 TWN-11 Nitrate (mg/I) Chloride (mg/I) Date 11/3/2009 1.3 74 TWN -12 Nitrate (mg/I) Chloride (mg/I) Date 11/3/2009 0.5 109 TWN -13 Nitrate (mg/I) Ch loride (mg/I) Date 11/4/2009 0.5 83 TWN-14 Nitrate (mg/I) Chloride (mg/I) Date 11/4/2009 3.4 32 TWN -IS Nitrate (mg/I) Chloride (mg/I) Date 11/10/2009 1.1 78 TWN -16 Nitrate (mg/I) Chloride (mg/I) Date 11/4/2009 1 39 TWN -17 Nitrate (mg/I) Chloride (mg/I) Date 11/4/2009 6.7 152 TWN -18 Nitrate (mg/I) Chloride (mg/I) Date 11/2/2009 1.3 57 TWN-19 Nitrate (mg/I) Chloride (mg/I) Date 11/2/2009 7.4 125 Piezometer 1 Nitrate (m g/I) Chloride (mg/I) Date 2/19/2009 6.8 NA 7/14/2009 6.8 60 9/22/2009 7.3 78 10/27/2009 7.4 61 Piezometer 2 Nitrate (mg/I) Chloride (m g/I) Date 2/19/2009 0.5 NA 7/14/2009 0.5 7 9/22/2009 0.5 17 10/27/2009 0.6 7 Piezometer 3 Nitrate (mg/I) Chlori de (mg/I) Date 2/19/2009 0.7 NA 7/14/2009 0.8 12 9/22/2009 0.8 24 10/27/2009 1.2 19 Piezometer 4 Date 7/14/2009 Nitra te (mg/I) Chloride (m g/I) 1.8 46 Piezometer 5 Date 7/14/2009 Nitrate (mg/I) Chloride (mg/I) 0.7 18 MW-18 Date 7/14/2009 Nitrate (mg/I) ND Ch loride (mg/I) 51 MW-19 Date 7/14/2009 Nitrate (mg/I) 2.2 Chloride (mg/I) 24 Wil dlife Pond Date 9/22/2009 10/27/2009 Ni trate (mg/I) Chloride (mg/I) ND 5 ND 3 Frog Pond Date 10/14/2009 Nitrate (mg/I) ND Ch loride (mg/I) NA Tab I Nitrate Concentration Graphs TWN-l Nitrate Concentrations 0.8 0.7 I-----0.6 ---0.5 :::. 0.4 --.. E 0.3 0.2 I-- 0.1 0 T TWN-2 Nitrate Concent rations 30 25 20 c---- "-15 bO -i. 10 5 0 T TWN-3 Nitrate Concentrations 35 -.--- 30 r-._....;;=--...... ------+"""'=~~;::::::=...;--..-~ • 25 r----. • ~ 20 r-- E 15 r-- 10 5 +-- o +---.----r---.--~. ---.----,' ------, TWN-4 Nitrate Concentrations 1.2 1 0.8 " 0.6 OJ) E OA 0.2 0 TWN-S Nitrate Concentrations 25 20 ~ 15 E 10 5 TWN-7 Nitrate Concentrations 0.12 0.1 0.08 "-0.06 .. E 0.04 0.02 0 TWN-6 Nitrate Concentrations 3.5 3 2.5 <::. 2 .. E 1.5 1 0.5 0 8/1/2009 9/1/2009 10/1/2009 11/1/2009 1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 +--- 0.2 0.1 -1--- TWN-8 Nitrate Concentration Are Non-Detect o .. --~~--~--.---~--~~--~--~--~--+ TWN-9 Nitrate Concentrations 14 12 • 10 • • " 8 OJ) E 6 4 2 0 , '" '" '" '" 0 0 0 0 0 0 0 0 N N N N ------------.... .... .... .... ------------00 '" 0 .... .... .... TWN-IO Nitrate Concentrations 1.8 1.6 1.4 1.2 '-1 .. .s 0.8 0.6 0.4 0.2 0 --,-T -, en en en en 0 0 0 0 0 0 0 0 N N N N --------.... .... .... .... --------00 en 0 .... .... .... 1.4 1.2 1 0.8 0.6 0.4 0.2 0 TWN-11 Nitrate Concentration (mg/I) 11/3/2009 • ------ 0.6 0.5 0.4 TWN-12 Nitrate Concentration (mg/I) 11/3/2009 0.3 f---- 0.2 -1-- 0.1 -1-------- O L----------------- TWN-13 Nitrate Concentration (mg/I) 11/4/2009 90 ~------------------------------- 80 ~----------------------~·~------ 70 ~------------------------------- 60 ~------------------------------- 50 ~------------------------------- 40 +-------------------------------- 30 +-------------------------------- 20 +-------------------------------- 10 +-------------------------------- O L-------------------------------- 4 3.5 3 2.5 2 1.5 1 0.5 0 TWN-14 Nitrate Concentration (mg/I) 11/4/2009 -- 1.2 1 0.8 0 .6 0.4 0.2 0 TWN-1S Nitrate Concentration (mg/I) 11/10/2009 • -- 1.2 1 . 0.8 . 0.6 0.4 . TWN-16 Nitrate Concentration (mg/I) 11 /4/2009 0.2 -1----------------- 0 -1------------------- TWN-17 Nitrate Concentration (mg/I) 11/4/2009 8 7 6 5 +--- 4 +--- 3 +--- • 2 +--------------------- 1 +--- o L----------------__ 1.4 1.2 TWN-18 Nitrate Concentrattion 11/2/2009 • 1 f--- 0.8 0.6 0.4 f---------------- 0.2 .f------ o -'------------------ 8 7 6 5 4 3 2 1 .. 0 TWN-19 Nitrate Concentration (mg/I) 11/2/2009 • r 6'a 0 I-~ ~ ?' OJ 6'a 0 E ~ I-~ .-"'6-I- L. 6'a 0 OJ \ I-~ > ~ 0 ~ 6'a ~ V) 0 L. c:: ~ OJ 0 ..-.. ~ +-' .--OJ +-' .......... 6'a E to tlO v0 L. E -0 +-' ~ N c:: "'-'" OJ OJ 6'a .-U 0 0.. c:: ~ 0 ~ U 6'a OJ 0 ~ +-' to ? L. +-' 6'a .-0 Z -~ ~ ~ ~ 6'a 0 ~ ~ ~"':f'!r-.OC!~",: r-. r-. r-. lDlDlD r- ~~ 6'Q 0 1\ ~ ~ 'l' cu ~ 6'Q E 00 .-~ I- L. 6'Q 0 cu ~ > ~ 0 • ~ 6'Q N V) 0 L. C -~ cu e ...... ~ +'" .--cu +'" " 6'Q E to bD 0 L. E ~ e +'" ~ C N "'-" cu cu 6'Q U 0 .-~ Q. C l- e ~ u 6'Q cu 0 ~ +'" ~ to L. 6'Q +'" .-0 Z I-~ "f H 6'Q 0 ~ ? LI) 1..0 LI) LI) LI) 1..0 0 LI) 0 ~ 0 0 0 ~ , 6'Q 0 r-0 ~~ ~ '/' OJ 6'Q E r v~ .-"'6- l- I.. 6'Q 0 OJ r 0 > ~ 0 H 6'Q m V) 0 I.. t: r-0 OJ 0 ..-.. ~ +" .--OJ +" " 6'Q E ta tlO v~ I.. E r 0 +" ~ N t: ""-" OJ OJ 6'Q .-U 0 Q. t: r-0 0 ~ U 6'Q OJ 0 0 +" r- ta ~ I.. +" 6'Q .-0 z ~ 0 f 6'Q 0 0 ~ '<tNrlOOI..D'<tNO .. .... rl rl 0000 c 0 .-otooI ta ~ otooI C OJ u C 0 U OJ otooI ta ~ otooI .-Z ~ ~ OJ otooI OJ E 0 N OJ .-0.. .-... -......... tlO E ....... 0'\ 0 0 N ......... ~ It""""I ......... r-.. • N Lf) o o c: 0 .-+'" n:s s- +'" c: OJ u c: 0 U OJ +'" n:s s- +'" .-Z Ln s- OJ +'" OJ E 0 N OJ .-0. ----........ tlO E -C'\ 0 O N ........ ~ ~ ........ r-..... ~ ~ 00 ~ ~ ~ ~ M N rl 0 o 0 0 0 0 0 0 0 r c: 0 .-+" ~ ta :... 0 +" 0 c: N OJ " u ~ c: \""'I 0 " U r-... ~ ~ M OJ +" +" U ta OJ :... +" +" OJ .-0 Z I CO c: \""'I 0 I Z S ~ 00 <.D <::t N 0 o 0 0 0 ........ -........ tlO E ""-' c: 0 .-+"" CO '-+"" c: OJ u c: 0 U OJ +"" CO '-+"" .-Z 0'\ ~ I S ~ 0'\ 0 0 N ........ ~ ~ ........ ....... L.f) N • N L.f) M L.f) o o ~ u OJ ~ OJ C I C o Z ...-~ ,0 ao l E ~ __ I OJ S ~ ~~ o~ N ZN ........ '1J~ C o 0- ~ 0---O- S 00 o I..D o N o o ---. -......... aD E ....... OJ ...., u 0"\ ...., OJ co 0 ...., "-OJ I ~ ~ ...., ~ 0-0 z ~ I I "'C r::::: 0 r::::: 0 ~ 0 Z Q. aD 0 "-u. 00 1D o:::t C"J 0 000 0 Chloride Concentration Graphs TWN-l Chloride Concentrations 19.5 19 18.5 <:::. 18 bO E 17.5 17 16.5 16 TWN-2 Chloride Concentraions 60 -,-- 50 f--- 40 +----/ ~30 t~::~~==~~::/Z/==~ 20 -1-------. 10 +---------------------------------------- o +---,---,---,---,----r---r---r---,--~--~ TWN-3 Chloride Co ncentrations 108 106 104 102 " 100 .. E 98 96 94 92 90 T I --. TWN-4 Chloride Concentrations 13.5 13 12.5 "-12 "" E 11.5 11 10.5 10 TWN-S Chloride Concentrations 49 48 47 46 -=:. 4S .. 44 E 43 42 41 40 39 TWN-6 Chloride Concentrations 35 30 25 ~ 20 E 15 -1-- 10 +---------- 5 o +-----,----~ ----r---~ 8/1/2009 9/1/2009 10/1/2009 11/1/2009 ~ E 8 6 4 TWN-7 Chloride Co ncentratons 2 -t-- o +-~---.--~--~~---r--~--~~--~~ TWN-8 Chloride Concentrations 12.2 12 11.8 11.6 '-11.4 .. E 11.2 11 10.8 10.6 10.4 TWN-9 Chloride Concentrations 250 200 • • .. "-150 .. .s 100 50 0 ----, '" '" '" '" 0 0 0 0 0 0 0 0 N N N N --------.... .... .... .... --------00 '" 0 .... .... .... TWN-10 Chloride Concentrations 40 3S 30 2S '-20 .. .s lS 10 S 0 -----. -------r ----, '" '" '" '" 0 0 0 0 0 0 0 0 N N N N --------.... .... .... .... --------00 '" 0 .... .... .... TWN-11 Chloride Concentration (mg/I) 11/3/2009 80 70 ----+ 60 +---- 50 40 30 20 +--------- 10 +--- o L----------------------------------- 120 100 80 TWN-12 Chloride Concentration(mg/I) 11/3/2009 • 60 f--- 40 t---- 20 +-------------------------------- O L-------------------------------- 35 30 25 20 15 TWN-14 Chloride Concentration (mg/I) 11/4/2009 • 10 -j--- 5 o -'------- 90 80 70 60 l- SO 40 TWN-1S Chloride Concentration (mg/I) 11/10/2009 30 -1------ 20 10 +-------------------------------- o ~---------------------------------- 45 40 35 30 . 25 20 15 10 5 0 TWN-16 Chloride Concentration (mg/I) 11/4/2009 ---.- TWN-17 Chloride Concentration(mg/I) 11/4/2009 160 140 120 100 80 60 +------ 40 +------ 20 +------- • O L-------------------------------- 60 50 40 I- 30 20 10 0 TWN-18 Chloride Concentration (mg/I) 11/2/2009 --• TWN-19 Chloride Concentration (mg/I) 11/2/2009 140 120 .. 100 80 60 -\---- 40 -\------------ 20 -1--------------------- O L------------------ CU E 0-~ 100. cu > 0 ~ (/) c: 100. 0 CU 0-...., ...., CU to E 100. ...., 0 c: N CU CU U 0-c: C. 0 U CU "C 0- 100. 0 -.J: U ---.. -"-bO E "'-" I- I- o 0 0 0 0 0 o 00 U) o::t N rl CT\ 0 0 N -rl -0 rl CT\ 0 0 N -rl -CT\ CT\ 0 0 N -rl -00 CT\ 0 0 N -rl -'" 6'Q °0 --0 'f OJ 6'Q E v ~ .-I-"'6- L. 6'Q OJ V > ~ 0 ~ N V) 6'Q C V L. ~ 0 OJ ~ . -...... +J +J -OJ co "-6'Q E L. bD °0 +J E 0 c ~ N OJ -OJ U 6'Q .-C °0 0. 0 :--s u OJ 6'Q "C °0 .-~ L. 0 6'Q -..c v ~ U ~ 6'Q V ~ -? 0 LI) 0 LI) 0 N rl rl Q) 0 0 N ......... rl Q) ......... 0 E rl 0-I- '-Q) > Q) 0 0 0 N rt') V) ......... rl t: ......... '-Q) Q) 0 0-...... ...., ...., -Q) ta '-- E '-tlO ...., E 0 t: Q) N Q) "'-" 0 Q) U 0 N 0-t: ......... 0.. rl 0 ......... 00 U Q) -"'C 0-'-0 Q) -0 oJ: 0 N U ......... rl ......... r-- c 0 .-..... CO ~ ..... C QJ u ----C -......... 0 b.O U E QJ '-"" "C en .-~ 0 0 0 -N oJ: U ......... ~ ~ or-t ~ ......... QJ I' ..... QJ E 0 N QJ .-c.. o Lf) • o <::t o rI"l o N o .--t o r:: 0 .-...., fa ~ ...., r:: OJ u -r:: -........ 0 ao u E OJ ---"C 0'\ .-~ 0 0 0 -N .r::. U ........ ~ Ln ~ ~ ........ OJ I' ...., OJ E 0 N OJ .-0. o N • Lf) .-i o .-i Lf) o c 0 .-+'" to ~ +'" C 0) u C 0 U 0) "'C .-~ 0 -..c: u CO ~ I S ~ en 0 0 N ......... ~ ~ ......... I' +'" u 0) +'" 0) C I C 0 Z o 0 0 0 0 0 0 U) lI) <::t rf) N .-i c: e • . -+-' to l- +-' c: -. -QJ ......... u bO c: E e -u en QJ 0 "'C 0 .-N l-e ......... -~ .J: ~ U ......... en I" ~ I S ~ o ~ 0 ~ 0 ~ 0 M N N M M s:: e .-...., en 0 ta 0 l-N ...., -<""""i s:: -0 CU <""""i U ...-.. s:: ..... e '--u tlO E CU "'C "'"-" .-CU -l-e E -.-s:. I-U I- "'C cu s:: > e 0 en 0.. 0 0 N cu -<""""i ~ -.-en -"'C -.-S Attachment 5 Site Hydrogeology and Estimation of Groundwater Pore Velocities in the Perched Zone White Mesa Uranium Mill Site near Blanding, Utah (Hydro Geo Chem, 2009) Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 i TABLE OF CONTENTS 1. INTRODUCTION.............................................................................................................. 1 2. SITE HYDROGEOLOGY.................................................................................................. 3 2.1 Geologic Setting......................................................................................................3 2.2 Hydrogeologic Setting............................................................................................4 2.3 Perched Zone Hydrogeology..................................................................................5 2.3.1 Lithologic and Hydraulic Properties........................................................... 6 2.3.2 Perched Groundwater Flow...................................................................... 11 2.3.3 Saturated Thickness.................................................................................. 12 3. PERCHED GROUNDWATER PORE VELOCITIES..................................................... 15 3.1.1 Downgradient of the Tailings cells........................................................... 15 3.1.2 The Vicinity of the Tailings cells..............................................................16 3.1.3 The Northeastern Portion of the Site ........................................................ 17 4. SUMMARY...................................................................................................................... 21 5. REFERENCES ................................................................................................................. 27 6. LIMITATIONS STATEMENT........................................................................................ 29 TABLES 1 Peel Hydraulic Test Results 2 Results of July 2002 and June 2005 Hydraulic Tests 3 Estimated Hydraulic Conductivities and Perched Zone Pore Velocities 4 Estimated Perched Zone Hydraulic Properties Based on Analysis of Observation Wells Near MW-4 5 Estimated Perched Zone Hydraulic Properties Based on Analysis of Observation Wells Near TW4-19 6 Estimated Perched Zone Hydraulic Properties and Pore Velocities for TWN-Series Wells Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 ii TABLE OF CONTENTS (Continued) FIGURES 1 Site Plan and Perched Well Locations, White Mesa Well Site 2 Approximate Elevation of Top of Brushy Basin (Contours generated by Kriging) 3 Perched Water Levels, August 1990 4 Perched Water Levels, August 1994 5 Perched Water Levels, September 2002 6 Kriged December 2009 Water Levels, White Mesa Site 7 3rd Quarter, 2009 Chloroform Plume Showing Area Responding to First 7 Months of Long-Term Pumping, White Mesa Site 8 Portion of USGS Black Mesa 7.5’ Sheet Showing Approximate Location of Tailing Cells in Relation to Nearby Canyons and Ruin Spring 9 Perched Zone Saturated Thickness, December 2009, White Mesa Site 10 Depths to Perched Water, December 2009, White Mesa Site 11 Kriged December 2009 Water Level Map Showing Hypothetical Pathlines, White Mesa Site APPENDIX A Perched Nitrate Monitoring Well Hydraulic Tests, White Mesa Uranium Mill, October 2009 Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 1 1. INTRODUCTION This report provides a brief description of the hydrogeology of the White Mesa Uranium Mill Site, located south of Blanding, Utah, and focuses on the occurrence and flow of groundwater within the relatively shallow perched groundwater zone at the site. Based on available existing hydrogeologic information from the site, estimates of hydraulic gradients and intergranular rates of groundwater movement (interstitial or pore velocities) are provided. These estimates are then used to calculate average pore velocities for a hypothetical conservative solute (assuming no hydrodynamic dispersion) within 1) an area downgradient of the tailings cells, 2) beneath and immediately upgradient and crossgradient of the tailings cells, and 3) within the northeastern portion of the site. The results of hydraulic testing of the TWN-series wells, located in the northeastern portion of the site are provided in Appendix A and are used to calculate pore velocities in an area affected by elevated nitrate concentrations. Figure 1 shows the locations of these and other perched zone monitoring wells at the site. Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 2 Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 3 2. SITE HYDROGEOLOGY Titan, 1994 provides a detailed description of site hydrogeology based on information available at that time. A brief summary of site hydrogeology that is based primarily on Titan, 1994, but includes the results of more recent site investigations, is provided below. 2.1 Geologic Setting The White Mesa Uranium Mill site (the “Mill” or the “site”) is located within the Blanding Basin of the Colorado Plateau physiographic province. Typical of large portions of the Colorado Plateau province, the rocks underlying the site are relatively undeformed. The average elevation of the site is approximately 5,600 feet above mean sea level (ft amsl). The site is underlain by unconsolidated alluvium and indurated sedimentary rocks consisting primarily of sandstone and shale. The indurated rocks are relatively flat lying with dips generally less than 3º. The alluvial materials consist mostly of aeolian silts and fine-grained aeolian sands with a thickness varying from a few feet to as much as 25 to 30 feet across the site. The alluvium is underlain by the Dakota Sandstone and Burro Canyon Formation, which are sandstones having a total thickness ranging from approximately 100 to 140 feet. Beneath the Burro Canyon Formation lies the Morrison Formation, consisting, in descending order, of the Brushy Basin Member, the Westwater Canyon Member, the Recapture Member, and the Salt Wash Member. The Brushy Basin and Recapture Members of the Morrison Formation, classified as shales, are very fine-grained and have a very low permeability. The Brushy Basin Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 4 Member is primarily composed of bentonitic mudstones, siltstones, and claystones. The Westwater Canyon and Salt Wash Members also have a low average vertical permeability due to the presence of interbedded shales. Beneath the Morrison Formation lie the Summerville Formation, an argillaceous sandstone with interbedded shales, and the Entrada Sandstone. Beneath the Entrada lies the Navajo Sandstone. The Navajo and Entrada Sandstones constitute the primary aquifer in the area of the site. The Entrada and Navajo Sandstones are separated from the Burro Canyon Formation by approximately 1,000 to 1,100 feet of materials having a low average vertical permeability. Groundwater within this system is under artesian pressure in the vicinity of the site, is of generally good quality, and is used as a secondary source of water at the site. 2.2 Hydrogeologic Setting The site is located within a region that has a dry to arid continental climate, with an average annual precipitation of approximately 13.3 inches, and an average annual lake evaporation rate of approximately 47.6 inches. Recharge to aquifers occurs primarily along the mountain fronts (for example, the Henry, Abajo, and La Sal Mountains), and along the flanks of folds such as Comb Ridge Monocline. Although the water quality and productivity of the Navajo/Entrada aquifer are generally good, the depth of the aquifer (approximately 1,200 feet below land surface [ft bls]) makes access difficult. The Navajo/Entrada aquifer is capable of yielding significant quantities of water Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 5 to wells (hundreds of gallons per minute [gpm]). Water in wells completed across these units at the site rises approximately 800 feet above the base of the overlying Summerville Formation. Perched groundwater in the Dakota Sandstone and Burro Canyon Formation is used on a limited basis to the north (upgradient) of the site because it is more easily accessible. Water quality of the Dakota Sandstone and Burro Canyon Formation is generally poor due to high total dissolved solids (TDS) and is used primarily for stock watering and irrigation. The saturated thickness of the perched water zone generally increases to the north of the site, increasing the yield of the perched zone to wells installed north of the site. 2.3 Perched Zone Hydrogeology Perched groundwater beneath the site occurs primarily within the Burro Canyon Formation. Perched groundwater at the site has a generally low quality due to high total dissolved solids (TDS) in the range of approximately 1,100 to 7,900 milligrams per liter (mg/L), and is used primarily for stock watering and irrigation in the areas upgradient (north) of the site. Perched water is supported within the Burro Canyon Formation by the underlying, fine-grained Brushy Basin Member. Figure 2 is a contour map showing the approximate elevation of the contact of the Burro Canyon Formation with the Brushy Basin Member, which essentially forms the base of the perched water zone at the site. Wells and piezometers shown in Figures 1 and 2 consist of surveyed perched zone monitoring wells and piezometers that include temporary perched zone monitoring wells (TW4-and TWN-series wells). The TW4-series wells are associated with an area of elevated perched zone chloroform concentrations located east and Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 6 northeast (cross-gradient to upgradient) of the tailings cells. The TWN-series wells are associated with areas of elevated nitrate and chloride in the northeastern portion of the site, upgradient of the tailings cells. Contact elevations between the Burro Canyon Formation and Brushy Basin Member are based on perched monitoring well drilling and geophysical logs and surveyed land surface elevations. As indicated, the Burro Canyon/Brushy Basin contact (although irregular because it represents an erosional surface) generally dips to the south/southwest beneath the site. Figures 3 through 6 are perched groundwater elevation contour maps for the years 1990, 1994, 2002, and 2009, respectively. Based on the contoured water levels, groundwater within the perched zone flows generally south to southwest beneath the site. Beneath the tailings cells, perched groundwater flow is generally southwest to south-southwest. Perched groundwater flow will be discussed in more detail in Section 2.3.2. 2.3.1 Lithologic and Hydraulic Properties Although the Dakota Sandstone and Burro Canyon Formations are often described as a single unit due to their similarity, previous investigators at the site have distinguished between them. The Dakota Sandstone is a relatively-hard to hard, generally fine-to-medium grained sandstone cemented by kaolinite clays. The Dakota Sandstone locally contains discontinuous interbeds of siltstone, shale, and conglomeratic materials. Porosity is primarily intergranular. The underlying Burro Canyon Formation hosts most of the perched groundwater at the site. The Burro Canyon Formation is similar to the Dakota Sandstone but is generally more poorly sorted, Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 7 contains more conglomeratic materials, and becomes argillaceous near its contact with the underlying Brushy Basin Member. The permeabilities of the Dakota Sandstone and Burro Canyon Formation at the site are generally low. No significant joints or fractures within the Dakota Sandstone or Burro Canyon Formation have been documented in any wells or borings installed across the site (Knight Piésold, 1998). Any fractures observed in cores collected from site borings are typically cemented, showing no open space. 2.3.1.1 Dakota Based on samples collected during installation of wells MW-16 (no longer used) and MW-17, located immediately downgradient of the tailings cells, porosities of the Dakota Sandstone range from 13.4% to 26%, averaging 20%, and water saturations range from 3.7% to 27.2%, averaging 13.5%. The average volumetric water content is approximately 3%. The hydraulic conductivity of the Dakota Sandstone based on packer tests in borings installed at the site ranges from approximately 2.7 x 10-6 centimeters per second (cm/s) to 9.1 x 10-4 cm/s, with a geometric average of 3.9 x 10-5 cm/s. 2.3.1.2 Burro Canyon The average porosity of the Burro Canyon Formation is similar to that of the Dakota Sandstone. Based on samples collected from the Burro Canyon Formation at MW-16 (no longer Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 8 used), located immediately downgradient of tailings cell #3, porosity ranges from 2% to 29.1%, averaging 18.3%, and water saturations of unsaturated materials range from 0.6% to 77.2%, averaging 23.4%. Titan, 1994, reported that the hydraulic conductivity of the Burro Canyon Formation ranges from 1.9 x 10-7 to 1.6 x 10 -3 cm/s, with a geometric mean of 1.1 x 10-5 cm/s, based on the results of 12 pumping/recovery tests performed in monitoring wells and 30 packer tests performed in borings prior to 1994. Hydraulic testing of wells MW-01, MW-03, MW-05, MW-17, MW-18, MW-19, MW-20, and MW-22 during July, 2002, wells MW-23, MW-25, MW-27, MW-28, MW-29, MW-30, MW-31, MW-32, TW4-20, TW4-21, and TW4-22 during June, 2005, wells TW4-23, TW4-24, TW4-25 during November, 2007, and TWN-series wells in October, 2009 (Figure 1), yielded average perched zone hydraulic conductivities ranging from approximately 2 x 10-7 cm/s to 0.01 cm/s. Except for the values of 0.01 cm/s at TWN-16, the range of conductivities was similar to the range reported by previous investigators at the site (Hydro Geo Chem, Inc [HGC], 2002; HGC, 2005; HGC, 2007b). Downgradient (south to southwest) of the tailings cells, average perched zone conductivities based on tests at MW-3, MW-5, MW-17, MW-20, MW-22, and MW-25 ranged from approximately 4 x 10-7 to 1 x 10-4 cm/s Permeability estimates from these tests were based on pumping/recovery and slug tests analyzed using several different methodologies. 25 temporary perched zone monitoring wells (the TW4-series wells shown in Figure 1) have been installed at the site to investigate elevated concentrations of chloroform initially discovered at well MW-4 in 1999. The chloroform likely originated from two former leach Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 9 fields, one located north of TW4-18, and the other near TW4-19, that received both laboratory and lavatory wastes in the early years of Mill operation. Some of the coarser-grained and conglomeratic zones encountered within the perched zone during installation of these wells are believed to be partly continuous or at least associated with a relatively thin, relatively continuous zone of higher permeability (International Uranium [USA] Corporation [IUSA] and HGC, 2001). The higher permeability zone defined by these wells is generally located east to northeast of the tailings cells at the site, and is hydraulically cross-gradient to upgradient of the tailings cells with respect to perched groundwater flow. Based on analyses of pumping tests at MW-4 and drilling logs from nearby temporary wells, the hydraulic conductivity of this relatively thin coarser-grained zone was estimated to be as high as 2.5 x 10-3 cm/s. Relatively high conductivities measured at MW-11, located on the southeastern margin of the downgradient edge of tailings cell #3, and at MW-14, located on the downgradient edge of tailings cell #4, of 1.4 x 10-3 cm/s and 7.5 x 10-4 cm/s, respectively (UMETCO, 1993), may indicate that this zone extends beneath the southeastern margin of the cells. However, this zone of higher permeability within the perched water zone does not appear to exist downgradient (south-southwest) of the tailings cells. At depths beneath the perched water table, the zone is not evident in lithologic logs of temporary wells TW4-4 and TW4-6 (located east [cross-gradient] of cell #3, as shown in Figure 5), nor is it evident in wells MW-3, MW-5, MW-12, MW-15, MW-16, MW-17, MW-20, MW-21, or MW-22, located south to southwest (downgradient) of the tailings cells, based on the lithologic logs or hydraulic testing of the wells. The apparent absence of the zone south of TW4-4 and south-southwest of the tailings cells indicates that it “pinches out” (HGC, 2005). Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 10 To test the potential existence and continuity of this higher permeability zone, and to refine hydraulic parameter estimates, long term pumping of MW-4 and TW4-19 began in April 2003. MW-26 (TW4-15) was added to the pumping network in August 2003, and TW4-20 was added in August, 2005. These wells were selected for pumping because they were 1) located in areas of the perched zone having relatively high transmissivity, and could therefore sustain relatively high pumping rates, and 2) because the wells were also located in perched water having relatively high chloroform concentrations, which resulted in significant rates of chloroform mass removal. As such, the pumping has constituted an interim action to mitigate chloroform in the perched zone (HGC, 2004). Analysis of drawdown data collected from wells that responded measurably to pumping between the start of pumping (April 2003) and November 2003, indicated average hydraulic conductivities ranging from 4 x 10-5 to 5 x 10-4 cm/s in the area east to northeast of the tailings cells, assuming the perched zone is unconfined, and from 5 x 10-5 to 1 x 10-3 cm/s if the perched zone is considered semi-confined (HGC, 2004). Figure 7 shows the approximate area where detectable drawdowns were measured during the 7 months of pumping. This area is interpreted to coincide roughly with the zone of higher permeability. Wells located outside this zone that did not respond measurably to pumping are interpreted to be completed in lower permeability materials. Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 11 2.3.2 Perched Groundwater Flow Perched groundwater flow at the site has historically been to the south/southwest. As presented in Section 2.3, Figures 3 through 6 are perched groundwater elevation contour maps for the years 1990, 1994, 2002, and 2009, respectively. The 1990, 1994, and 2002 maps were hand contoured because of sparse data. As groundwater elevations indicate, the perched groundwater gradient changes from generally southwesterly in the western portion of the site, to generally southerly in the eastern portion of the site. The most significant changes between the 2002 and 2009 water levels result from pumping of wells MW-4, TW4-19, TW4-20, and MW-26. These wells are pumped to reduce chloroform mass in the perched zone east and northeast of the tailings cells. In general, perched groundwater elevations have not changed significantly at most of the MW-series site monitoring wells since installation, except in the vicinity of the wildlife ponds and the pumping wells. For example, relatively large increases in water levels occurred between 1994 and 2002 at MW-4 and MW-19, located in the east and northeast portions of the site, as shown by comparing Figures 4 and 5. These water level increases in the northeastern and eastern portions of the site are likely the result of seepage from wildlife ponds located near the piezometers shown in Figure 5, which were installed in 2001 for the purpose of investigating these changes. The increase in water levels in the northeastern portion of the site has resulted in a local steepening of groundwater gradients over portions of the site. Conversely, pumping of wells MW-4, TW4-19, TW4-20, and MW-26 has depressed the perched water table locally and reduced average hydraulic gradients to the south and southwest of these wells. Perched zone Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 12 hydraulic gradients currently range from a maximum of approximately 0.05 ft/ft east of tailings cell #2 to approximately 0.01 ft/ft downgradient of cell #3, between cell #3 and MW-20. Perched water discharges in springs and seeps along Westwater Creek Canyon and Cottonwood Canyon to the west-southwest of the site, and along Corral Canyon to the east of the site, where the Burro Canyon Formation outcrops. The discharge point located most directly downgradient of the tailings cells is Ruin Spring. This feature is located approximately 10,000 feet south-southwest of the tailings cells at the site and is depicted on the USGS 7.5-minute quad sheet for Black Mesa (Figure 8). 2.3.3 Saturated Thickness The saturated thickness of the perched zone as of the 3rd quarter of 2009 ranges from approximately 93 ft in the northeastern portion of the site to less than 6 ft in the southwest portion of the site (Figure 9), and depths to water range from approximately 15 ft in the northeastern portion of the site (adjacent to the wildlife ponds) to approximately 114 ft at the southwest margin of tailings cell #3 (Figure 10). The relatively large saturated thicknesses in the northeastern portion of the site are likely related to seepage from wildlife ponds located near the piezometers shown in Figure 10. Although sustainable yields of as much as 4 gpm have been achieved in wells intercepting the larger saturated thicknesses and higher permeability zones in the northeast portion of the site, perched zone well yields are typically low (<0.5 gpm) due to the generally Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 13 low permeability of the perched zone. Sufficient productivity can generally be obtained only in areas where the saturated thickness is greater, which is the primary reason that the perched zone has been used on a limited basis as a water supply to the north (upgradient) of the site, but not downgradient of the site. Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 14 Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 15 3. PERCHED GROUNDWATER PORE VELOCITIES Average rates of movement of a conservative solute in perched groundwater (equivalent to interstitial or pore velocities) have been calculated for the areas of the perched zone 1) downgradient of the tailings cells, 2) beneath and immediately upgradient and crossgradient of the tailings cells, and 3) within the northeastern portion of the site (HGC, 2005, and Appendix A). 3.1.1 Downgradient of the Tailings cells As discussed in Section 2.3.2, the nearest discharge point for perched water downgradient of the tailings cells is Ruin Spring. The average hydraulic gradient between the downgradient edge of tailings cell #3 and Ruin Spring is approximately 0.013 ft/ft assuming the following: 1) The surveyed elevation of Ruin Spring, based on the USGS topographic map for Black Mesa, is approximately 5,380 ft amsl. 2) The distance between the downgradient edge of tailings cell #3 and Ruin Spring is approximately 10,000 ft. 3) The average groundwater elevation at the downgradient edge of tailings cell #3 is approximately 5,511 ft amsl. The calculated rate of movement downgradient of the tailings cells was based on 1) an effective porosity of 0.18, 2) an average hydraulic gradient of 0.013 ft/ft, and 3) geometric averages of hydraulic conductivities estimated from hydraulic tests at wells located at the downgradient edge of the cells and south and southwest of the cells. The geometric averages were based on slug tests performed at MW-3, MW-5, MW-17, MW-20, MW-22, and MW-25 Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 16 (HGC, 2002; HGC, 2005), and pump tests performed by Peel Environmental (UMETCO, 1993) at MW-11, MW-12, MW-14, and MW-15, as summarized in Table 1. Two averages were calculated; one using conductivities estimated from HGC slug test data analyzed using the Bouwer-Rice solution (Bouwer and Rice, 1976) and the other using conductivities estimated from the same data using the KGS solution (Hyder, 1994), as summarized in Table 2. Included in each average were the results of the pump tests reported in UMETCO, 1993, for MW-11, MW- 12, MW-14, and MW-15. The geometric averages thus calculated were 2.3 x 10-5 and 4.3 x 10-5 cm/s. Assuming the average conductivity ranges from 2.3 x 10-5 to 4.3 x 10-5 cm/s (0.064 ft/day to 0.120 ft/day), the calculated average rate of movement ranges from 0.0047 ft/day to 0.0087 ft/day (or 1.7 ft/year to 3.2 ft/year). 3.1.2 The Vicinity of the Tailings cells Perched zone pore velocities beneath and immediately upgradient of the tailings cells were calculated in HGC, 2005, based on data from wells MW-23, MW-25, MW-27, MW-28, MW-29, MW-30, MW-31, MW-32, TW4-20, TW4-21, and TW4-22 (Table 3). Estimated hydraulic conductivities range from approximately 2 x 10-7 to 1 x 10-4 cm/s and yield a geometric average of approximately 3 x 10-5 cm/s or 31 ft/yr. Using hydraulic gradients in the vicinity of each well, the estimated conductivity at each well, and an effective porosity of 0.18, the estimated pore velocities ranged from 49.5 ft/year at TW4-21, to 0.010 ft/year at MW-23, and have a geometric average of approximately 4.5 ft/year. Hydraulic gradients in the vicinity of most of these wells have not changed significantly since 2005, nor have the estimated pore Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 17 velocities. The largest changes have occurred in wells located near pumping wells due to periodic changes in pumping rates. East of the tailings cells, within the area of the chloroform plume (Figure 7), perched zone pore velocities are calculated using hydraulic conductivities reported in HGC, 2004, as summarized in Tables 4 and 5. Wells TW4-5, TW4-9, and TW4-1 are on a line subparallel to the hydraulic gradient in that area. Using the (arithmetic) average hydraulic conductivity of 321 ft/yr for these wells (assuming unconfined conditions) a hydraulic gradient of 0.029 ft/ft, and an effective porosity of 0.18, the estimated pore velocity is 52 ft/yr. If semi-confined conditions are assumed (and that flow is primarily through only coarser-grained zones defined by drilling logs as discussed in HGC, 2004), an average hydraulic conductivity of 663 ft/yr is calculated, and the pore velocity is estimated as 110 ft/yr. The arithmetic average conductivity was used because the range for these three wells is within an order of magnitude. 3.1.3 The Northeastern Portion of the Site Perched zone pore velocities in the northeastern portion of the site are provided in Table 6 and Appendix A. The geometric average hydraulic conductivity of the TWN-series hydraulic tests is approximately 5.3 x 10-5 cm/s or 54 ft/yr. Using hydraulic gradients in the vicinity of each TWN-series well, the estimated conductivity at each well, and an effective porosity of 0.18, the calculated pore velocities range from 0.04 feet per year (ft/yr) at TWN-7 to 762 ft/yr at TWN-16, with a geometric average of approximately 7 ft/yr. The calculated pore velocity at TWN-16 is the highest of any perched zone well at the site due to the relatively high Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 18 conductivity of 0.01 cm/s estimated for the well. This suggests the presence of a relatively thin high permeability zone (or set of such zones) analogous to that inferred to exist east of the tailings cells near MW-4. Although none of the nearby wells appear to intercept such a zone, suggesting that it is likely not continuous additional data might reveal the continuity of such a zone. Appendix A also provides a discussion of nitrate distribution with respect to permeability and perched zone pore velocities in the northeastern portion of the site. Areas of elevated perched zone nitrate (> 5 mg/L) that exist northeast of and proximal to the Mill are referred to as Area 1 and Area 2 respectively (Figure 11). Average perched zone pore velocities along hypothetical pathlines oriented with the long axes of these areas of elevated nitrate concentrations are calculated as approximately 0.55 ft/yr to 7 ft/yr for Area 1 and 23 ft/yr for Area 2 using geometric averages of hydraulic conductivity estimates along the pathlines (Appendix A). These velocities are insufficient to transport nitrate from the upgradient to the downgradient portions of the two areas within the approximate 30 year operational time of the Mill, suggesting that 1) actual rates are faster than calculated using the geometric averages of the estimated hydraulic conductivities, 2) each nitrate area has resulted from more than one localized seepage area and/or one or more diffuse, distributed seepage areas located upgradient of the tailings cells, or 3) the nitrate distribution results from a combination of these factors. With regard to 2) above, more than one seepage area may have received water from the same source resulting in similar seepage chemistry at more than one areal location. Furthermore, some seepage areas may have existed prior to Mill construction, and contributed nitrate for decades prior to the existence of any source areas related to Mill operation. Another complicating factor Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 19 is that hydraulic gradients have changed over time over portions of the site. For example, hydraulic gradients have changed as a result of seepage from the wildlife ponds, and would be expected to have changed in response to any other sources of seepage present prior to Mill construction and operation. The higher the pore velocities, the fewer localized seepage areas are needed to distribute the nitrate detected in both Area 1 and Area 2. Higher pore velocities would result in spreading of nitrate from each potential source location over a larger area. Past and present pore velocities may be high enough to support minimal contributing seepage locations if 1) greater weight were given to the highest conductivity estimates when calculating the averages or 2) flow is primarily through one or more relatively thin, relatively continuous higher permeability zones similar to that inferred to exist in the vicinity of MW-4, located east of the tailings cells within an area of elevated chloroform (HGC, 2007a). Because the estimated hydraulic conductivities in Table 6 are averages over the entire saturated thicknesses at the estimation points, the conductivity of a relatively thin horizon or horizons through which most of the flow was occurring would be underestimated as would the effective pore velocity. The presence of higher permeability horizons within both Area 1 and Area 2 (by analogy with the area near MW-4) would allow greater spreading of perched zone nitrate within the 30 year operational time history of the Mill. Fewer localized seepage areas could then be called upon to yield the observed nitrate distributions. The high hydraulic conductivity estimated at TWN-16 indicates the possible existence of such a horizon within Area 1. Such a zone does not appear to be penetrated by other TWN-series wells near and within Area 1, suggesting that any Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 20 higher permeability zone penetrated by TWN-16 is not continuous over Area 1. However, additional data might reveal the presence of a zone analogous to that near MW-4 that could have transported nitrate over longer distances. Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 21 4. SUMMARY Perched groundwater at the site is hosted primarily by the Burro Canyon Formation, which consists of a relatively hard to hard, fine- to medium-grained sandstone containing siltstone, shale and conglomeratic materials. The Burro Canyon Formation is separated from the underlying regional Navajo/Entrada aquifer by approximately 1000 ft of Morrison Formation and Summerville Formation materials having a low average vertical permeability. The Brushy Basin Member of the Morrison Formation is a shale that immediately underlies the Burro Canyon Formation and forms the base of the perched water zone at the site. Based on hydraulic tests at perched zone monitoring wells, the hydraulic conductivity of the perched zone ranges from approximately 2 x 10-7 to 0.01 cm/s. Perched water flow is generally from northeast to southwest across the site. Beneath and downgradient of the tailings cells, on the west side of the site, perched water flow is south- southwest. On the eastern side of the site perched water flow is more southerly. Perched water generally has a low quality, with total dissolved solids ranging from approximately 1,100 to 7,900 mg/L, and is used primarily for stock watering and irrigation north (upgradient) of the site. Depths to perched water range from approximately 15 ft near the wildlife ponds in the northeastern portion of the site to approximately 114 ft at the southwestern margin of the tailings cells. Saturated thicknesses range from approximately 93 ft near the wildlife ponds to less than 6 ft in the southwest portion of the site, downgradient of the tailings cells. Although sustainable yields of as much as 4 gpm have been achieved in wells penetrating higher transmissivity zones, Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 22 well yields are typically low (< 0.5 gpm) due to the generally low permeability of the perched zone. In general, the highest permeabilities and well yields are in the area of the site immediately northeast and east (upgradient to crossgradient) of the tailings cells. A relatively continuous, higher permeability zone has been inferred to exist in this portion of the site which is associated with an area of elevated chloroform concentrations that most likely originated from two former leach fields that received both laboratory and lavatory wastes in the early years of Mill operation. Hydraulic tests at wells located in this area indicate hydraulic conductivities in the range of 10-3 to 10-4 cm/s. Using data from TW4-5, TW4-9, and TW4-1 (which form a north- south line approximately parallel to perched water flow east of the tailings cells) pore velocities are estimated to range from approximately 52 to 110 ft/yr in this area. Hydraulic conductivities in the northeastern portion of the site, upgradient of the tailings cells (within elevated nitrate Area 1), are generally in the intermediate range of values estimated for the site, although the highest conductivity estimated for the site (approximately 0.01 cm/s), and one of the lowest conductivities estimated for the site (approximately 4 x 10-7 cm/s) occur in this area. Hydraulic tests of TWN-series wells yield a geometric average of approximately 5.3 x 10-5 cm/s or 54 ft/yr. Calculated pore velocities range from approximately 0.04 to 762 ft/yr and have a geometric average pore velocity of approximately 7 ft/yr. Permeabilities beneath and immediately upgradient of the tailings cells are generally within the intermediate to low range of values estimated for the site. Hydraulic conductivity Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 23 estimates for wells MW-23, MW-25, MW-27, MW-28, MW-29, MW-30, MW-31, MW-32, TW4-20, TW4-21, and TW4-22 range from approximately 2 x 10-7 to 2 x 10-4 cm/s and yield a geometric average of approximately 3 x 10-5 cm/s or 31 ft/yr. Estimated pore velocities ranged from 0.010 ft/yr to 49.5 ft/yr and have a geometric average of approximately 4.5 ft/year. Permeabilities downgradient of the tailings cells are generally low. Combined with shallow hydraulic gradients, average calculated pore velocities downgradient of the tailings cells are among the lowest on site. Hydraulic tests at wells located at the downgradient edge of the cells, and south and southwest of the cells (MW-3, MW-5, MW-11, MW-12, MW-14, MW-15, MW-17, MW-20, MW-22, and MW-25), yielded geometric average hydraulic conductivities of 2.3 x 10-5 and 4.3 x 10-5 cm/s (23 ft/yr and 44 ft/yr, respectively) depending on the testing and analytical method. Assuming the average conductivity ranges from 2.3 x 10-5 to 4.3 x 10-5 cm/s, the calculated average pore velocity ranges from 1.7 ft/year to 3.2 ft/year. With regard to nitrate distribution (as discussed in Appendix A), within Area 1, a geometric average pore velocity along the indicated pathline of as high as 7 ft/yr is calculated, and in the western portion of Area 2, a geometric average pore velocity along the indicated pathline of 23 ft/yr is calculated (Figure 11). These velocities are insufficient to transport nitrate from the upgradient to the downgradient portions of either area within the approximate 30 year operational time of the Mill, suggesting that 1) actual pore velocities are higher than calculated using the geometric averages of the estimated hydraulic conductivities, 2) each nitrate area has resulted from more than one localized seepage areas and/or one or more diffuse, distributed seepage areas located upgradient of the tailings cells, or 3) the nitrate distribution results from a Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 24 combination of these factors. With regard to item 2) above, more than one seepage area may have received water from the same source resulting in similar seepage chemistry at more than one areal location. Furthermore, some seepage areas may have existed prior to Mill construction, and contributed nitrate for decades prior to the existence of any seepage areas related to Mill operation. The higher the pore velocities, the fewer localized seepage areas are needed to distribute the nitrate detected in both Area 1 and Area 2. Higher pore velocities would result in spreading of nitrate from each potential source location over a larger area. Past and present pore velocities may be high enough to support minimal contributing seepage locations if 1) greater weight were given to the highest conductivity estimates when calculating the averages or 2) flow is primarily through one or more relatively thin, relatively continuous higher permeability zones similar to that inferred to exist in the vicinity of MW-4, located east of the tailings cells within an area of elevated chloroform (HGC, 2007a). Because the estimated hydraulic conductivities in Table 6 are averages over the entire saturated thicknesses at the estimation points, the conductivity of a relatively thin horizon or horizons through which most of the flow was occurring would be underestimated as would the effective pore velocity. The presence of higher permeability horizons within both Area 1 and Area 2 (by analogy with the area near MW-4) would allow greater spreading of perched zone nitrate within the 30 year operational time history of the Mill. Fewer localized seepage areas could then be called upon to yield the observed nitrate distributions. The high hydraulic conductivity estimated at TWN-16 indicates the possible existence of such a horizon within Area 1. Such a zone does not Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 25 appear to be penetrated by other TWN-series wells near and within Area 1, suggesting that any higher permeability zone penetrated by TWN-16 is not continuous over Area 1. However, additional data might reveal the presence of a zone analogous to that near MW-4 that could have transported nitrate over longer distances. Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 26 Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 27 5. REFERENCES Bouwer, H. and R.C. Rice. 1976. A slug test method for determining hydraulic conductivity of unconfined aquifers with completely or partially penetrating wells. Water Resources Research, Vo. 12:3. Pp. 423-428. Hyder, Z., J.J. Butler, C.D. McElwee, and W. Liu. 1994. Slug tests in partially penetrating wells. Water Resources Research. Vol. 30:11. Pp. 2945-2957. Hydro Geo Chem, Inc. 2002. Hydraulic Testing at the White Mesa Uranium Mill Near Blanding, Utah During July, 2002. Submitted to International Uranium (USA) Corporation, Denver, Colorado. HGC. 2005. Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill, April Through June, 2005. Submitted to International Uranium (USA) Corporation, Denver, Colorado. HGC. 2007a. Preliminary Contamination Investigation Report. White Mesa Uranium Mill Site Near Blanding, Utah. November 20, 2007. HGC. 2007b. Draft Letter to Steven Landau, Denison Mines (USA) Corporation, Denver, Colorado. December 19, 2007. International Uranium (USA) Corporation and Hydro Geo Chem, Inc. 2001. Update to report “Investigation of Elevated Chloroform Concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah”. November 9, 2001. Knight-Piésold. 1998. Evaluation of Potential for Tailings Cell Discharge – White Mesa Mill. Attachment 5, Groundwater Information Report, White Mesa Uranium Mill, Blanding, Utah. Submitted to UDEQ. TITAN. 1994. Hydrogeological Evaluation of White Mesa Uranium Mill. Submitted to Energy Fuels Nuclear. UMETCO. 1993. Groundwater Study. White Mesa Facilities. Blanding, Utah. Prepared by UMETCO Minerals Corporation and Peel Environmental Services. Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 28 Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 29 6. LIMITATIONS STATEMENT The opinions and recommendations presented in this report are based upon the scope of services and information obtained through the performance of the services, as agreed upon by HGC and the party for whom this report was originally prepared. Results of any investigations, tests, or findings presented in this report apply solely to conditions existing at the time HGC’s investigative work was performed and are inherently based on and limited to the available data and the extent of the investigation activities. No representation, warranty, or guarantee, express or implied, is intended or given. HGC makes no representation as to the accuracy or completeness of any information provided by other parties not under contract to HGC to the extent that HGC relied upon that information. This report is expressly for the sole and exclusive use of the party for whom this report was originally prepared and for the particular purpose that it was intended. Reuse of this report, or any portion thereof, for other than its intended purpose, or if modified, or if used by third parties, shall be at the sole risk of the user. Site Hydrogeology & Est. GW Travel Times H:\718000\hydrpt09b\report\hydr122909 Final.doc December 29, 2009 30 TABLES TABLE 1 Peel Hydraulic Test Results1 Hydraulic Conductivity (cm/s) MW-11 1.4 x 10-3 MW-12 2.2 x 10-5 MW-14 7.5 x 10-4 MW-15 1.9 x 10-5 Notes: cm/s = centimeters per second 1 From UMETCO, 1993 Well H:\718000\hydrpt09b\report\Tables1and2.xls: Table 1 12/29/2009 TABLE 2 Results of July 2002 and June 2005 Hydraulic Tests2 Well KGS Bouwer-Rice MW-3 4.0 x 10-7 1.5 x 10-5 MW-5 3.5 x 10-6 2.4 x 10-5 MW-17 2.6 x 10-5 2.7 x 10-5 MW-20 --9.3 x 10-6 MW-22 1.0 x 10-6 7.9 x 10-6 MW-25 1.1 x 10-4 7.4 x 10-5 2.3 x 10-5 4.3 x 10-5 2From HGC, 2002; HGC, 2005 3From UMETCO, 1993 Permeability in Centimeters Per Second Geometric Average of above test results with Peel3 test results for MW-11, MW-12, MW-14, and MW-15. H:\718000\hydrpt09b\report\Tables1and2.xls: Table 2 12/29/2009 TABLE 3 Estimated Hydraulic Conductivities and Perched Zone Pore Velocities (cm/s) (ft/yr) MW-23 2.2 x 10-7 0.22 MW-25 1.1 x 10-4 112 MW-27 7.2 x 10-5 74 MW-28 1.8 x 10-6 1.8 MW-29 1.1 x 10-4 112 MW-30 8.1 x 10-5 83 MW-31 7.1 x 10-5 73 MW-32 2.9 x 10-5 29 TW4-20 5.6 x 10-5 57 TW4-21 1.9 x 10-4 c 194 TW4-22 1.2 x 10-4 123 Notes: a Average of estimates; value for MW-23 based on second test at MW-23. b Assumes effective porosity of 0.18 cEstimates from Bouwer-Rice method not included in average cm/s = Centimeters per second ft/ft = Feet per foot ft/yr = Feet per year 11.7 49.5 19.8 8.1 12.4 9.7 3.38 0.023 0.022 0.029 0.010 14.3 9.0 0.29 Pore Velocityb (ft/yr) Hydraulic Conductivitya Hydraulic Gradient 0.046 0.029 0.037 Well (ft/ft) 0.013 0.027 0.024 0.008 0.021 H:\718000\hydrpt09b\report\Table3.xls: Table3 12/29/2009 TABLE 4 Estimated Perched Zone Hydraulic Properties Based on Analysis of Observation Wells Near MW-4 Observation Well Theis Solution (Confined or Unconfined) Transmissivity (ft2/day) Storage Coefficient Water Bearing Zone Thickness (feet) Average Hydraulic Conductivity (ft/day) Average Hydraulic Conductivity (cm/sec) Unconfined 8.9 0.023 39 0.23 8.2x10-5 Confined 8.4 0.023 24 0.35 1.3x10-4 Unconfined 4.6 0.0065 39 0.12 4.3x10-5 Confined 3.8 0.0063 24 0.16 5.7x10-5 Unconfined 4.7 0.011 39 0.12 4.3x10-5 Confined 3.3 0.011 24 0.14 5.0x10-5 Unconfined 4.5 0.010 39 0.12 4.3x10-5 Confined 3.9 0.010 24 0.16 5.7x10-5 Unconfined 5.8 0.019 39 0.15 5.4x10-5 Confined 3.5 0.019 24 0.15 5.4x10-5 Unconfined 12.4 0.0029 39 0.32 1.1x10-4 Confined 9.1 0.0031 24 0.38 1.4x10-4 Notes: cm/sec = Centimeters per second ft/day = Feet per day ft 2 /day = Feet squared per day MW-4A (early time) TW4-1 TW4-2 TW4-7 TW4-8 MW-4A H:\718000\hydrpt09b\report\tables4and5.xls: Table 4 12/29/2009 TABLE 5 Estimated Perched Zone Hydraulic Properties Based on Analysis of Observation Wells Near TW4-19 Observation Well Theis Solution (Confined or Unconfined) Transmissivity (ft2/day) Storage Coefficient Water Bearing Zone Thickness (feet) Average Hydraulic Conductivity (ft/day) Average Hydraulic Conductivity (cm/sec) Unconfined 89 0.0043 67 1.3 4.6x10-4 Confined 87 0.0043 31 2.8 1.0x10-3 Unconfined 72 0.0043 67 1.1 3.9x10-4 Confined 71 0.0043 31 2.3 8.2x10-4 Unconfined 48 0.0077 67 0.72 2.6x10-4 Confined 46 0.0076 31 1.5 5.4x10-4 Unconfined 15 0.0037 67 0.22 7.9x10-5 Confined 12 0.0037 31 0.39 1.4x10-4 Unconfined 19 0.0036 67 0.28 1.0x10-4 Confined 18 0.0035 31 0.58 2.1x10-4 Unconfined 76 0.0046 67 1.1 3.9x10-4 Confined 74 0.0046 31 2.4 8.6x10-4 Unconfined 44 0.12 67 0.66 2.4x10-4 Confined 39 0.12 31 1.3 4.6x10-4 Notes: cm/sec = Centimeters per second ft/day = Feet per day ft 2 /day = Feet squared per day TW4-5 TW4-9 TW4-19 TW4-10 TW4-15 TW4-16 TW4-18 H:\718000\hydrpt09b\report\tables4and5.xls: Table 5 12/29/2009 TABLE 6 Estimated Perched Zone Hydraulic Properties and Pore Velocities for TWN-Series Wells Pathline Head Change Hydraulic Gradient Pore Velocity (cm/s) (ft/yr) (ft) (ft) ft/ft ft/yr TWN-1 1.70E-04 1.74E+02 220 13 5.91E-02 57.0 TWN-2 1.87E-05 1.91E+01 230 17 7.39E-02 7.85 TWN-3 8.77E-06 8.96E+00 300 13 4.33E-02 2.16 TWN-4 8.94E-04 9.14E+02 1050 10 9.52E-03 48.3 TWN-5 4.47E-04 4.57E+02 290 15 5.17E-02 131 TWN-6 1.74E-04 1.78E+02 440 10 2.27E-02 22.5 TWN-7 4.08E-07 4.17E-01 660 10 1.52E-02 0.04 TWN-8 1.13E-04 1.16E+02 550 13 2.36E-02 15.2 TWN-9 2.93E-05 2.99E+01 825 17 2.06E-02 3.42 TWN-10 3.07E-05 3.14E+01 660 5 7.58E-03 1.32 TWN-11 1.08E-04 1.11E+02 880 14 1.59E-02 9.8 TWN-12 7.87E-05 8.04E+01 550 22 4.00E-02 17.9 TWN-13 3.69E-06 3.77E+00 1050 4 3.81E-03 0.08 TWN-14 3.18E-06 3.25E+00 880 13 1.48E-02 0.27 TWN-15 3.68E-05 3.76E+01 990 14 1.41E-02 2.96 TWN-16 0.010336 1.06E+04 770 10 1.30E-02 762 TWN-17 4.96E-06 5.06E+00 1200 10 8.33E-03 0.23 TWN-18 1.70E-03 1.74E+03 300 10 3.33E-02 322 TWN-19 2.25E-05 2.30E+01 550 22 4.00E-02 23.2 Notes: aAverage of KGS and Bouwer-Rice estimates. Assumes effective porosity of 0.18 cm/s = Centimeters per second ft/ft = Feet per foot ft/yr = Feet per year Well Hydraulic Conductivitya H:\718000\hydrpt09b\report\Table6.xls: Table 6 12/29/2009 FIGURES HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE CELL NO. 2 CELL NO. 4A 3332 MW-21 3000 BOUNDARY PROPERTY SCALE IN FEET 0 CELL NO. 1 MILL SITE MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-16 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-32 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 MW-26 TW4-1 TW4-2 TW4-3 TW4-4 TW4-5 TW4-6 TW4-9 TW4-11 TW4-12 TW4-13 TW4-14 TW4-16 TW4-18 TW4-20 TW4-21 MW-04TW4-7 TW4-8 TW4-10 TW4-22 TW4-19 TW4-23 TW4-24 TW4-25 TWN-1 TWN-2 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 MW-20 PIEZ-1 perched monitoring well temporary perched monitoring well installed April, 2005 perched piezometer MW-31 temporary perched monitoring well perched monitoring well installed April, 2005 SITE PLAN AND PERCHED WELL LOCATIONS WHITE MESA SITE H:/718000/hydrpt09b/welloc.srf TW4-19 TW4-20 EXPLANATION temporary perched monitoring well installed May, 2007 TW4-23 wildlife pond SJS temporary perched nitrate monitoring well TWN-1 112/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE CELL NO. 2 CELL NO. 4A 3332 MW-21 3000 BOUNDARY PROPERTY SCALE IN FEET 0 CELL NO. 1 MILL SITE 5536 5492 5466 5491 5479 5494 5477 5473 5495 5470 5518 5511 5449 5470 5396 5483 5502 5499 5537 5515 5491 5508 5489 5515 5518 5534 5522 5536 5512 5532 5526 5536 5521 5517 5520 5506 5481 5497 55025509 5525 5521 5516 5552 5536 5558 5501 5477 MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-16 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-26 MW-32 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 5521 5522 5517 5544 5534 5542 5519 5507 5536 5545 5507 5552 5562 5543 5560 5518 5528 5525 5561 5536 5502 5555 TWN-1 TWN-2 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 MW-20 PIEZ-1 5449 5552 perched monitoring well showing elevation in feet amsl temporary perched monitoring well installed in 2005 showing elevation in feet amsl perched piezometer showing elevation in feet amsl 5512 MW-31 5489 temporary perched monitoring well showing elevation in feet amsl 5525 perched monitoring well installed in 2005 showing elevation in feet amsl APPROXIMATE ELEVATION OF TOP OF BRUSHY BASIN (Contours Generated by Kriging) H:/718000/hydrpt09b/bbel0909.srf EXPLANATION SJS temporary perched nitrate monitoring well showing elevation in feet amsl 5519 TWN-4 212/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 3332 3000 SCALE IN FEET 0 5582 5503 5471 5502 5521 5501 5494 5493 5498 5587 5604 5458 5450 5498 5507 5537 5576 5543 5512 5537 5547 5557 5557 5583 5550 5585 5537 5583 5578 5565 5586 5571 5524 5549 5559 5548 558455485561 5580 5574 5593 5614 5600 5542 5541 MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-26 MW-32 TW4-19 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 5551 5553 5554MW-04 5541 5569 5599 TW4-24 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 5603 5606 5585 5590 5559 5603 5583 5585 5614 5629 5587 5587 5584 5604 5606 5600 5607 5603 5607 TWN-1 TWN-2 MW-22 PIEZ-1 5450 5592 perched monitoring well showing elevation in feet amsl temporary perched monitoring well installed April, 2005 showing elevation in feet amsl perched piezometer showing elevation in feet amsl 5556 MW-31 5546 temporary perched monitoring well showing elevation in feet amsl 5573 perched monitoring well installed April, 2005 showing elevation in feet amsl KRIGED DECEMBER 2009 WATER LEVELS WHITE MESA SITE H:/718000/hydrpt09b/wl1209c.srf EXPLANATION temporary perched monitoring well installed May, 2007 showing elevation in feet amsl5541 SJS temporary perched nitrate monitoring well showing elevation in feet amsl TWN-4 5605 612/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 3332 3000 SCALE IN FEET 0 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 1700 3000 ND 2000 12 280 ND 910 1000 ND ND ND 850 ND ND 136600 13000 200 2300 NS NS NS NS NS MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-26 MW-32 TW4-19 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 1500 2000 NDMW-04 ND 1 ND MW-4 PIEZ-1 2000 NS perched monitoring well showing concentration in uG/l temporary perched monitoring well installed April, 2005 showing concentration in uG/l perched piezometer (not sampled) 1700 MW-32 ND temporary perched monitoring well showing concentration in uG/l 200 perched monitoring well installed April, 2005 showing concentration in uG/l 3rd QUARTER, 2009 CHLOROFORM PLUME SHOWING AREA RESPONDING TO FIRST 7 MONTHS OF LONG-TERM PUMPING WHITE MESA SITE H:/718000/nov09/chldwn2c.srf EXPLANATION NOTES: ND = not detected, NS = not sampled; temporary perched monitoring well installed May, 2007 showing concentration in uG/lND SJS approximate area of measurable drawdowns during the first 7 months of long term pumping 712/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 3332 3000 SCALE IN FEET 0 46 11 6 11 42 7 17 21 28 69 93 9 54 15 5 38 39 28 21 29 57 42 39 50 28 49 25 51 52 29 64 55 4 43 78 51 83 36 59 57 41 78 43 41 64 58 73 62 87 78 54 14 97 31 23 71 69 69 59 59 42 71 98 52 MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-26 MW-32 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 TWN-1 TWN-2 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 30 31 36MW-04 40TW4-19 MW-20 PIEZ-1 9 41 perched monitoring well showing saturated thickness in feet temporary perched monitoring well installed April, 2005 saturated thickness in feet perched piezometer showing saturated thickness in feet 25 MW-31 57 temporary perched monitoring well showing saturated thickness in feet 57 perched monitoring well installed April, 2005 showing saturated thickness in feet PERCHED ZONE SATURATED THICKNESS DECEMBER 2009 WHITE MESA SITE H:/718000/hydrpt09b/satthck09.srf EXPLANATION SJS temporary perched nitrate monitoring well showing saturated thickness in feet 87 TWN-4 912/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 3332 3000 SCALE IN FEET 0 66 110 83 107 90 109 104 107 77 71 51 82 67 114 115 76 51 78 103 77 70 62 68 49 64 56 71 54 56 59 38 49 89 76 65 77 5783 69 59 55 63 15 38 49 44 MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-26 MW-32 TW4-19 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 71 68 68MW-04 67 56 45 TW4-24 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 31 36 71 75 90 48 65 82 71 39 47 63 92 49 35 45 55 46 20 TWN-1 TWN-2 MW-22 PIEZ-1 67 63 perched monitoring well showing depth to water in feet temporary perched monitoring well installed April, 2005 showing depth to water in feet perched piezometer showing depth to water in feet 71 MW-31 70 temporary perched monitoring well showing depth to water in feet 55 perched monitoring well installed April, 2005 showing depth to water in feet DEPTHS TO PERCHED WATER DECEMBER 2009 WHITE MESA SITE H:/718000/hydrpt09b/dtw1209c.srf EXPLANATION temporary perched monitoring well installed May, 2007 showing depth to water in feet 67 SJS temporary perched nitrate monitoring well showing depth to water in feet TWN-4 36 1012/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 3332 3000 SCALE IN FEET 0 MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-26 MW-32 TW4-19 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 5582 5503 5471 5502 5521 5501 5494 5493 5498 5587 5604 5458 5450 5498 5507 5537 5576 5543 5512 5537 5547 5557 5557 5583 5550 5585 5537 5583 5578 5565 5586 5571 5524 5549 5559 5548 55845548 5561 5580 5574 5593 5614 5600 5542 5541 5553 5554MW-04 5541 5569 5599 TW4-24 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 5603 5606 5585 5590 5559 5603 5583 5585 5614 5629 5587 5587 5584 5604 5606 5600 5607 TWN-1 TWN-2 5603 5607 MW-20 PIEZ-1 5460 5593 perched monitoring well showing elevation in feet amsl temporary perched monitoring well installed April, 2005 showing elevation in feet amsl perched piezometer showing elevation in feet amsl 5556 MW-31 5546 temporary perched monitoring well showing elevation in feet amsl 5573 perched monitoring well installed April, 2005 showing elevation in feet amsl KRIGED DECEMBER 2009 WATER LEVEL MAP SHOWING HYPOTHETICAL PATHLINES WHITE MESA SITE H:/718000/hydtst09b/nitrpath2c.srf EXPLANATION temporary perched monitoring well installed May, 2007 showing elevation in feet amsl5540 SJS temporary perched nitrate monitoring well showing elevation in feet amsl 5601 TWN-1 pathlines for Areas 1 and 2 AREA 1 AREA 2 area with nitrate > 5 mg/L 11 area with chloroform > 70 ug/L 12/29/09 APPENDIX A PERCHED NITRATE MONITORING WELL HYDRAULIC TESTS WHITE MESA URANIUM MILL OCTOBER 2009 APPENDIX A PERCHED NITRATE MONITORING WELL HYDRAULIC TESTS WHITE MESA URANIUM MILL OCTOBER 2009 Prepared for: DENISON MINES (USA) CORP. 1050 17th Street, Suite 950 Denver, Colorado 80265 Prepared by: HYDRO GEO CHEM, INC. 51 West Wetmore, Suite 101 Tucson, Arizona 85705 (520) 293-1500 December 29, 2009 App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-i TABLE OF CONTENTS 1. INTRODUCTION............................................................................................................... 1 2. HYDRAULIC TESTING.................................................................................................... 3 2.1 Data Collection .......................................................................................................3 2.2 Data Analysis..........................................................................................................5 2.3 Results.....................................................................................................................8 3. ESTIMATED PERCHED WATER TRAVEL TIMES IN THE NORTHEASTERN PORTION OF THE SITE ................................................................ 11 4. DISCUSSION................................................................................................................... 15 5. CONCLUSIONS............................................................................................................... 19 6. REFERENCES ................................................................................................................. 23 7. LIMITATIONS................................................................................................................. 25 TABLES A.1 Parameters Used in Hydraulic Test Analyses A.2 Slug Test Results A.3 Estimated Perched Zone Pore Velocities FIGURES A.1 Site Plan and Perched Well Locations, White Mesa Site A.2 Kriged December 2009 Water Levels Showing Locations of Hydraulic Gradient Calculations, White Mesa Site A.3 Perched Zone Nitrate (mg/L), White Mesa Site A.4 Kriged December 2009 Water Level Map Showing Hypothetical Pathlines, White Mesa Site APPENDICES A.1 Background Corrections A.2 Slug Test Analysis Plots App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-ii App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-1 1. INTRODUCTION This report describes the hydraulic testing of 19 new temporary perched zone groundwater monitoring wells at the White Mesa Uranium Mill (the “Mill” or the “site”). The wells, designated TWN-1 through TWN-19 as shown in Figure A.1, were installed to better define the distribution of nitrate and chloride in the perched groundwater. All wells were completed in nominal 6 ¾ inch diameter boreholes using flush-thread, 4-inch diameter PVC casing and factory slotted screen. Wells TWN-11 through TWN-19 were the last round of TWN-series wells to be installed and development of these wells was completed during the week prior to the testing. Wells TWN-1 through TWN-10 were tested first to allow more time for water levels in the newest wells (TWN-11 through TWN-19) to stabilize. Hydraulic testing consisted of slug tests conducted between October 19 and October 26, 2009. Test data were analyzed to estimate perched zone hydraulic properties in the vicinity of each new well. Slug testing and analysis procedures were similar to those used in previous testing at the site during July 2002 and June, 2005 as described in Hydro Geo Chem, Inc. (HGC), 2002, and HGC, 2005. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-2 App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-3 2. HYDRAULIC TESTING HGC personnel conducted hydraulic tests between October 19 and October 26, 2009. The hydraulic tests consisted of slug tests performed in the same manner as described in HGC, 2002, and HGC, 2005. Hydraulic tests were performed at all TWN-series perched well installations and at existing well MW-24. The test results at MW-24 are described in a separate document. The purpose of the tests was to estimate hydraulic parameters (primarily hydraulic conductivity) in the vicinity of each new well. The same slugs and electric water level meter were used in both the current testing event and the June 2005 testing event. The submersible 0-30 pounds per square inch absolute (psia) Level Troll 500TM pressure transducers and data loggers used in the current tests were similar to those used in previous tests. 2.1 Data Collection Two slugs consisting of sealed, pea-gravel-filled, schedule-80 PVC pipe, one approximately 3 feet long, and one approximately 4 feet long, as described in HGC, 2002, were used for the tests. The 3-foot slug had a larger diameter and displaced approximately 0.75 gallons of water. The 4-foot slug had a smaller diameter and displaced approximately 0.47 gallons. Typically, the 3-foot, 0.75-gallon displacement slug was used. If a test using the 3-foot slug was slow due to low permeability conditions, a concurrent test could be started in the next well using the 4-foot, 0.47- gallon slug. Two Level-TrollJ data loggers were available to allow two wells to be tested simultaneously. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-4 In all cases, water level data were collected automatically using a Level-TrollJ data logger and by hand using the electric water level meter. Automatically logged data were collected at 5-second intervals except at TWN-16, where a 1-second interval was used. Hand-collected data were obtained more frequently in the first few minutes of each test when water levels were changing rapidly, then more slowly as the rate of water level change diminished. Prior to each test, the static water level in each well was measured by hand using the electric water level meter. The data logger was then lowered to a depth of approximately 8 to 10 feet below the static water level, and background pressure readings were collected for approximately 30 to 60 minutes prior to beginning a test. The purpose of collecting the background data was to allow correction of test data for any trends in water levels measured at the wells. Typically, 30 minutes of background readings were collected for TWN-1 through TWN-10, and 1 hour of background readings for TWN-11 through TWN-19. The longer interval was used for wells TWN-11 through TWN-19 because these were the most recently installed wells and there was a higher likelihood that water levels in these wells had not yet stabilized after installation and development. Wells TWN-1 through TWN-10 were also tested first to give the more recently installed wells more time to stabilize. Once background data were collected, the slug and electric water level meter sensor were then suspended in the well just above the static water level. Each test commenced by lowering the slug to a depth of approximately 2 feet below the static water level over a period of a few seconds and taking water level readings by hand as soon as possible afterwards. Upon completion, App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-5 equipment pulled from each well was rinsed with clean water prior to its use in the next test. Automatically logged data were checked, backed up on the hard drive of a personal computer, and e-mailed to HGC’s Tucson office daily for review and processing. 2.2 Data Analysis Data were analyzed using AqtesolvTM (HydroSOLVE, 2000), a computer program developed and marketed by HydroSOLVE, Inc. In preparing the automatically logged data for analysis, the total number of records was reduced. In general, all data collected in the first 50 seconds were retained, then every 2nd, then 3rd, then 4th, etc. record was retained for analysis. For example, if the first 10 records were retained (50 seconds of data at 5-second intervals), the next records to be retained would be the 12th, the 15th, the 19th, the 24th, etc. In general, the maximum measured rise in water levels was slightly below what would be expected considering the slug volume, the volume in the 4-inch-diameter casing, and the volume in the annular space between the casing and the 6 ¾-inch-diameter bore. Assuming a 30 percent effective porosity for the filter pack, the expected rise in water level is approximately 1 foot per gallon. The maximum expected rise for the 3-foot, 0.75-gallon slug is therefore about 0.75 feet, and for the 4-foot, 0.47-gallon slug, about 0.47 feet. If only the 4-inch diameter casing is considered, a maximum rise of approximately 1.12 ft is expected for the 0.75 gallon slug, and approximately 0.75 ft for the 0.47 gallon slug. Data were analyzed using two solution methods: the KGS unconfined method (Hyder et al., 1994) and the Bouwer-Rice unconfined method (Bouwer and Rice, 1976). When filter pack App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-6 porosities were required by the analytical method, a value of 30 percent was used. The saturated thickness was taken to be the difference between the static water level measured just prior to the test and the depth to the Brushy Basin contact as defined in the drilling logs (Table A.1). In cases where the static water level was below the top of the screened interval, the saturated thickness was also the effective screen length. In cases where the static water level was above the top of the screened interval, the partial penetration of the well was considered in the analysis. Background data were analyzed for any obvious trends and when detected were used to correct subsequent test readings. Background trends were used to correct data from wells TWN-2, TWN-9, TWN-10, TWN-11, and TWN-12. (Data from TWN-7 were corrected for barometric pressure changes as discussed below.) The method for background correction was to fit a linear or logarithmic function to the background data then use that function to correct the subsequent test readings. In all cases, the corrections were a small fraction of the total displacement created by the slugs. Plots of raw and corrected displacements for these wells are provided in Appendix A.1. Barometric pressure was recorded throughout each test using a BaroTrollTM pressure transducer and logger. In all cases, except at TWN-7, the test duration was short enough that the impact of changing barometric pressure could be ignored. The overnight test at TWN-7 required a correction for atmospheric pressure changes. Good agreement exists between hydraulic conductivity estimates made by different solution methods after correcting the data. The interpretation at TWN-7 is complicated by the extremely low hydraulic conductivity, the consequent small rate of change in App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-7 water levels during the test, and by the possibility that the relationship between changes in water level and changes in barometric pressure was not constant over the test. The behavior of water levels at TWN-7 in relation to changes in barometric pressure is consistent with the discussion in HGC, 2004. Water level changes in the perched wells are impacted by instantaneous transmission of barometric pressure changes down the well casings and delayed (lagged and attenuated) transmission of pressure changes to the water table at locations remote from the wells. The lag and attenuation at remote locations result from vertically downward propagation of pressure changes through the low permeability vadose materials. The KGS solution allows estimation of both specific storage and hydraulic conductivity, while the Bouwer-Rice solution allows estimation of only the hydraulic conductivity. The Bouwer- Rice solution is valid only for the straight-line portion of the data that results when the log of displacement is plotted against time, and is insensitive to both storage and the specified initial water level rise. Typically, only the later-time data are interpretable using Bouwer-Rice. The KGS solution generally allows a fit to both early and late time data, and is sensitive to storage and the specified initial water level rise. Both solutions were used for comparison. Automatically logged and hand-collected data were analyzed separately using both solution methods. The hand-collected data, therefore, served as an independent data set and a check on the accuracy of the automatically logged data. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-8 2.3 Results The results of the analyses are provided in Table A.2 and Appendix A.2. Appendix A.2 contains plots generated by AqtesolveJ that show the quality of fit between measured and simulated results, and reproduce the parameters used in each solution. Estimates of hydraulic conductivity range from 3.6 x 10-7 centimeters per second (cm/s) at TWN-7 to 0.0142 cm/s at TWN-16. The value of 0.0142 cm/s estimated using the KGS solution for the test at TWN-16 is higher than any value previously estimated for the perched zone. Except for the hydraulic conductivity estimate at TWN-16, values are within the range previously measured at the site. In general, the agreement between hydraulic conductivities estimated from the KGS and Bouwer-Rice solutions is good, and values agree within a factor of 2 except at TWN-4, where the estimates differed by a factor of about 63, and at TWN-16, where the estimates differed by a factor of 2.2. The agreement between estimates obtained from automatically logged and hand-collected data is also good. In all but three cases, the estimates based on automatically logged and hand-collected data using the KGS solution are within a factor of 2, and in the other three cases are within a factor of 3. Estimates obtained from automatically logged and hand-collected data using the Bouwer-Rice solution are also close: identical or within a factor of 2 in all cases except at TWN-13, where the estimates differ by a factor of 3. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-9 Specific storage estimates of 0.1 obtained at TWN-10 and TWN-13 using KGS are anomalously high. These estimates suggest that these tests were impacted by near-well storage effects not encountered at other wells. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-10 App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-11 3. ESTIMATED PERCHED WATER TRAVEL TIMES IN THE NORTHEASTERN PORTION OF THE SITE Average perched groundwater travel times in the vicinity of the TWN-series wells are estimated based on the hydraulic conductivity estimates obtained from the wells and hydraulic gradients calculated from site water levels. This method is identical to that presented in HGC, 2005. Because the hydraulic conductivity estimates represent values vertically averaged over the measured saturated thicknesses of the wells, the calculated travel times also represent values averaged over the saturated thicknesses. Except for the high hydraulic conductivity of 0.0142 cm/s estimated for TWN-16 using the KGS solution, hydraulic conductivity estimates from the new wells are within the range previously reported for the site. Perched zone hydraulic conductivities at the site are generally highest in the area northeast and east (upgradient to crossgradient) of Tailings Cell #2. Figure A.2 is a contour map of December, 2009 perched water level data. This map was generated by gridding the raw data using ordinary linear kriging with a linear variogram. The general direction of perched water flow inferred from the water level contours is to the south-southwest. Flow is complicated immediately northeast of the Mill site by the groundwater mound associated with the wildlife ponds. Perched water flow at many of the new installations located immediately north of the ponds is to the north-northwest, and a broad region of relatively flat hydraulic gradient exists to the northwest of the ponds. The highest measured water level was at TWN-12, the most northern of the newly installed TWN-series wells. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-12 Table A.3 provides the average perched water pore (interstitial) velocities in the vicinities of the new wells based on hydraulic conductivity estimates and hydraulic gradients calculated from water levels shown on Figure A.2. Hydraulic conductivities shown in Table A.3 are averages of KGS and Bouwer-Rice estimates shown in Table A.2. An effective porosity of 18 percent was used in the calculations. The heavy green lines in Figure A.2 indicate the positions and lengths over which the perched zone hydraulic gradients were calculated. The method of calculation is substantially the same as described in HGC, 2005. As indicated, the calculated pore velocities range from 0.04 feet per year (ft/yr) at TWN-7 to 762 ft/yr at TWN-16. Calculated velocities at TWN-1, TWN-4, TWN-5, TWN-6, TWN-8, TWN-12, TWN-16, TWN-18, and TWN-19 are greater than 10 ft/yr; velocities at TWN-2, TWN-3, TWN-8, TWN-9, TWN-10, TWN-11, and TWN-15 are between 1 and 10 ft/yr; and velocities at TWN-7, TWN-13, TWN-14, and TWN-17 are less than 1 ft/yr. Figure A.3 is a map posting nitrate concentrations obtained from samples of perched zone wells that shows the approximate areas where nitrate concentrations exceed 5 mg/L. These areas are hereafter referred to as areas of elevated nitrate. Figure A.4 is a water level contour map showing these same areas. The northeastern area of elevated nitrate is referred to as Area 1, and the central area as Area 2..Area 1 consists of two sub-areas, the northernmost associated with TWN-17 and TWN-19, and the other associated with TWN-9 and PIEZ-1. Areas 1 and 2 are separated by a groundwater mound associated with the wildlife ponds. Areas 1 and 2 are generally elongated in the northeast-southwest direction, roughly parallel to the perched hydraulic gradient. The eastern portion App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-13 of the central area contains a lobe (or spur) that is elongated in the north-south to south-southeast direction. Average perched groundwater pore velocities are calculated for two hypothetical pathlines through elevated nitrate Areas 1 and 2. These pathlines are shown in Figure A.4. The northeastern pathline (from TWN-17 to TWN-9) is associated with Area 1 (northeast of the wildlife ponds) and the central pathline (from TWN-2 to MW-11) is associated with Area 2 (west and southwest of the wildlife ponds). These pathlines, although subparallel to the long axes of portions of the two areas, are considered hypothetical because they are not always parallel to the current hydraulic gradient. The average hydraulic gradient along the Area 1 pathline is approximately 0.012 ft/ft, and along the Area 2 pathline, 0.025 ft/ft. The geometric mean hydraulic conductivity along the Area 1 pathline (based on estimates at TWN-9, TWN-14, and TWN-17) is approximately 8 ft/yr, and along the Area 2 pathline (based on estimates at TWN-2, TW4-24, and MW-11), approximately 165 ft/yr. Assuming a porosity of 18 percent, average pore water velocities of 0.55 ft/yr for the Area 1 pathline and 23 ft/yr for the Area 2 pathline are calculated. A larger velocity of approximately 7 ft/yr is calculated for the Area 1 pathline if the hydraulic conductivity for nearby well TWN-16 is substituted for that of TWN-17 (which yields a geometric mean hydraulic conductivity [based on estimates at TWN-9, TWN-14, and TWN-16] of approximately 100 ft/yr). App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-14 App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-15 4. DISCUSSION Perched water pore (interstitial) velocities in the vicinities of the new wells are calculated (using averages of KGS and Bouwer-Rice hydraulic conductivity estimates) to range from approximately 0.04 ft/yr at TWN-7 to 762 ft/yr at TWN-16. Calculated average velocities along the two hypothetical pathlines shown in Figure A.4 are 0.55 ft/yr to 7 ft/yr for nitrate Area 1 and 23 ft/yr for nitrate Area 2. Calculated velocities are insufficient to move nitrate from the upgradient to the downgradient portions of either area during the approximately 30 years of site operation. This suggests that 1) actual velocities are higher than calculated using the geometric averages of the estimated hydraulic conductivities, 2) each nitrate area has resulted from more than one localized seepage area and/or one or more diffuse, distributed seepage areas located upgradient of the tailings cells, or 3) the nitrate distribution results from a combination of these factors. With regard to item 2) above, more than one seepage area may have received water from the same source resulting in similar seepage chemistry at more than one areal location. Furthermore, some seepage areas may have existed prior to Mill construction, and contributed nitrate for decades prior to the existence of any seepage areas related to Mill operation. Hydraulic gradients have changed as a result of seepage from the wildlife ponds, and would be expected to have changed in response to any other sources of seepage present prior to Mill construction and operation. The higher the pore velocities, the fewer seepage areas are needed to distribute the nitrate detected in both Area 1 and Area 2. Higher pore velocities would result in spreading of nitrate from each potential source location over a larger area. Past and present pore velocities may be high enough App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-16 to support minimal contributing seepage locations if 1) greater weight were given to the highest conductivity estimates when calculating the averages or 2) flow is primarily through one or more relatively thin, relatively continuous higher permeability zones similar to that inferred to exist in the vicinity of MW-4, located east of the tailings cells within an area of elevated chloroform (HGC, 2007). Because the estimated hydraulic conductivities in Table A.2 are averages over the entire saturated thicknesses at the estimation points, the conductivity of a relatively thin horizon or horizons through which most of the flow was occurring would be underestimated as would the effective pore velocity. For example, if nearly all the flow were occurring within a horizon with a thickness that was only 10 percent of the total saturated thickness, then the conductivity of that horizon could be nearly 10 times as high as the average estimated over the entire saturated thickness, and the effective pore velocity nearly 10 times higher than estimated using the vertically averaged conductivity. Based on hydraulic test data and drilling logs at or near MW-4, the conductivity of a relatively thin, relatively continuous higher permeability zone penetrated by MW-4 was estimated to be as much as 5 to 10 times higher than the vertically averaged conductivity estimates (HGC, 2007). The presence of higher permeability horizons within both Area 1 and Area 2 (by analogy with the area near MW-4) would allow greater spreading of perched zone nitrate within the 30 year operational time history of the Mill. Fewer localized seepage areas could then be called upon to yield the observed nitrate distributions. The high hydraulic conductivity estimated at TWN-16 indicates the possible existence of such a horizon within Area 1. Such a zone does not appear to be penetrated by other TWN-series wells near and within Area 1, suggesting that any higher permeability zone penetrated by TWN-16 is not continuous over Area 1. However, additional data might reveal the App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-17 presence of a zone analogous to that near MW-4 that could have transported nitrate over longer distances. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-18 App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-19 5. CONCLUSIONS Hydraulic conductivity estimates based on slug tests at the new wells range from 3.6 x 10-7 cm/s at TWN-7 to 0.014 cm/s at TWN-16. The value of 0.014 cm/s, based on the test conducted at TWN-16 and obtained using the KGS solution, is higher than any previously reported value for the perched zone. The average of the KGS and Brouwer-Rice results at TWN-16 was 0.01 cm/s. Except for estimates obtained at TWN-16, the range of hydraulic conductivities estimated for the new wells is within the range of perched zone values previously reported for the site. Perched zone hydraulic conductivities at the site are generally highest in the area northeast to east (upgradient to crossgradient) of Tailings Cell #2. Perched water pore (interstitial) velocities in the vicinities of the new wells are calculated to range from 0.04 feet per year (ft/yr) at TWN-7 to 762 ft/yr at TWN-16. Calculated velocities at TWN-1, TWN-4, TWN-5, TWN-6, TWN-8, TWN-12, TWN-16, TWN-18, and TWN-19 are greater than 10 ft/yr; velocities at TWN-2, TWN-3, TWN-8, TWN-9, TWN-10, TWN-11, and TWN-15 are between 1 and 10 ft/yr; and velocities at TWN-7, TWN-13, TWN-14, and TWN-17 are less than 1 ft/yr. Areas of elevated perched zone nitrate that exist northeast of and proximal to the Mill are referred to as Area 1 and Area 2 respectively. Average perched zone pore velocities along hypothetical pathlines oriented with the long axes of these areas of elevated nitrate concentrations are calculated as approximately 0.55 ft/yr to 7 ft/yr for Area 1 and 23 ft/yr for Area 2 using geometric App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-20 averages of hydraulic conductivity estimates along the pathlines. These velocities are insufficient to transport nitrate from the upgradient to the downgradient portions of either area within the approximate 30 year operational time of the Mill, suggesting that 1) actual pore velocities are higher than calculated using the geometric averages of the estimated hydraulic conductivities, 2) each nitrate area has resulted from more than one localized seepage area and/or one or more diffuse, distributed seepage areas located upgradient of the tailings cells, or 3) the nitrate distribution results from a combination of these factors. With regard to item 2) above, more than one seepage area may have received water from the same source resulting in similar seepage chemistry at more than one areal location. Furthermore, some seepage areas may have existed prior to Mill construction, and contributed nitrate for decades prior to the existence of any seepage areas related to Mill operation. Hydraulic gradients have changed as a result of seepage from the wildlife ponds, and would be expected to have changed in response to any other sources of seepage present prior to Mill construction and operation. The presence of higher permeability horizons within both Area 1 and Area 2 (by analogy with the area near MW-4) would allow greater spreading of perched zone nitrate within the 30 year operational time history of the Mill. Fewer localized seepage areas could then be called upon to yield the observed nitrate distributions. The high hydraulic conductivity estimated at TWN-16 indicates the possible existence of such a horizon within Area 1. Such a zone does not appear to be penetrated by other TWN-series wells near and within Area 1, suggesting that any higher permeability zone penetrated by TWN-16 is not continuous over Area 1. However, additional data might reveal the App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-21 presence of a zone analogous to that near MW-4 that could have transported nitrate over longer distances. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-22 App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-23 6. REFERENCES Bouwer, H. and R.C. Rice. 1976. A Slug-Test method for Determining Hydraulic Conductivity of Unconfined Aquifers with Completely or Partially Penetrating Wells. Water Resources Research, Vol. 12, No. 3, Pp. 423-428. Hyder, Z., J.J. Butler, Jr., C.D. McElwee, and W. Liu. 1994. Slug Tests in Partially Penetrating Wells. Water Resources Research, Vol. 30, No. 11, Pp. 2945-2957. Hydro Geo Chem, Inc. 2002. Hydraulic Testing at the White Mesa Uranium Mill Near Blanding, Utah During July 2002. August 22, 2002. Hydro Geo Chem, Inc. 2004. Final Report. Long Term Pumping at MW-4, TW4-10, and TW4- 15. White Mesa Uranium Mill Near Blanding, Utah. May 26, 2004. Hydro Geo Chem, Inc. 2005. Perched Monitoring Well Installation and Testing at the White Mesa Uranium Mill, April Through June 2005. August 3, 2005. Hydro Geo Chem, Inc. 2007. Preliminary Contamination Investigation Report. White Mesa Uranium Mill Site Near Blanding, Utah. November 20, 2007. HydroSolve, Inc. 2000. AQTESOLV for Windows. User=s Guide. International Uranium (USA) Corporation and Hydro Geo Chem. 2001. Update to report “Investigation of Elevated Chloroform Concentrations in Perched Groundwater at the White Mesa Uranium Mill Near Blanding, Utah”. November 9, 2001. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-24 App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-25 7. LIMITATIONS The opinions and recommendations presented in this report are based upon the scope of services and information obtained through the performance of the services, as agreed upon by HGC and the party for whom this report was originally prepared. Results of any investigations, tests, or findings presented in this report apply solely to conditions existing at the time HGC=s investigative work was performed and are inherently based on and limited to the available data and the extent of the investigation activities. No representation, warranty, or guarantee, express or implied, is intended or given. HGC makes no representation as to the accuracy or completeness of any information provided by other parties not under contract to HGC to the extent that HGC relied upon that information. This report is expressly for the sole and exclusive use of the party for whom this report was originally prepared and for the particular purpose that it was intended. Reuse of this report, or any portion thereof, for other than its intended purpose, or if modified, or if used by third parties, shall be at the sole risk of the user. App A: Perched Nitrate Monitoring Well Hydraulic Tests H:\718000\hydrpt09b\report\App A-TWN hydraulic tests 122909 Final.doc December 29, 2009 A-26 TABLES TABLE A.1 Parameters Used in Hydraulic Test Analyses Depth to Depth to Depth to Top Depth to Base Saturated Thickness Well Brushy Basin Water of Screen of Screen Above Brushy Basin (ft) (ft) (ft) (ft) (ft) TWN-1 102 48 55.0 105.0 54.0 TWN-2 92 18 15.0 95.0 74.0 TWN-3 92 32 45.0 95.0 60.0 TWN-4 123 37 45.0 125.0 85.5 TWN-5 147 70 80.0 150.0 77.0 TWN-6 127 75 60.0 130.0 52.0 TWN-7 102 91 25.0 105.0 11.0 TWN-8 142 62 75.5 145.5 80.0 TWN-9 94 65 47.0 97.0 29.0 TWN-10 102 82 55.0 105.0 20.0 TWN-11 140 72 62.0 142.0 68.0 TWN-12 107 40 30.0 110.0 67.0 TWN-13 115 47 46.0 116.0 68.0 TWN-14 120 63 53.0 123.0 57.0 TWN-15 150 92 85.0 155.0 58.0 TWN-16 90 49 43.0 93.0 41.0 TWN-17 104 35 24.0 104.0 69.0 TWN-18 142 59 55.0 145.0 83.0 TWN-19 105 55 56.0 106.0 50.0 Note: ft = feet H:\718000\hydrpt09b\report\App A Tables.xls: Table A.1 12/29/2009 TABLE A.2 Slug Test Results Bouwer-Rice Bouwer-Rice Test Saturated Thickness K (cm/s) Ss (1/ft) K (cm/s) K (cm/s) Ss (1/ft) K (cm/s) TWN-1 54 1.70E-04 2.22E-03 NI 1.97E-04 1.25E-03 1.36E-04 TWN-2 74 1.49E-05 3.20E-04 2.25E-05 2.04E-05 1.16E-04 2.73E-05 TWN-3 60 8.56E-06 8.73E-06 8.97E-06 7.75E-06 1.53E-05 8.89E-06 TWN-4 85 1.76E-03 3.43E-04 2.79E-05 1.25E-03 1.84E-06 NI TWN-5 77 4.88E-04 3.88E-07 4.06E-04 4.88E-04 3.88E-07 3.70E-04 TWN-6 79 1.74E-04 2.22E-03 NI 3.50E-04 2.22E-12 3.36E-04 TWN-7 11 3.57E-07 2.22E-03 4.59E-07 3.57E-07 2.21E-03 NI TWN-8 80 1.51E-04 3.66E-04 7.55E-05 4.73E-04 1.41E-06 2.48E-04 TWN-9 29 2.99E-05 6.92E-03 2.86E-05 6.02E-05 5.59E-03 7.93E-05 TWN-10 20 3.83E-05 0.1 2.31E-05 8.71E-05 8.12E-03 1.10E-04 TWN-11 68 1.18E-04 1.08E-05 9.83E-05 9.34E-05 7.18E-05 9.78E-05 TWN-12 67 8.05E-05 4.65E-05 7.69E-05 1.28E-04 1.27E-07 7.39E-05 TWN-13 68 2.62E-06 0.1 4.77E-06 2.09E-06 0.1 6.93E-06 TWN-14 57 3.61E-06 6.39E-03 2.74E-06 3.98E-06 3.17E-03 7.93E-06 TWN-15 58 4.75E-05 1.04E-03 2.61E-05 5.86E-05 3.49E-04 6.42E-05 TWN-16 41 0.0142 8.02E-04 6.47E-03 NI NI NI TWN-17 69 3.73E-06 0.033 6.18E-06 1.41E-06 0.061 1.96E-06 TWN-18 83 2.27E-03 2.44E-06 1.14E-03 2.67E-03 2.22E-12 NI TWN-19 50 2.69E-05 2.49E-03 1.81E-05 3.83E-05 3.34E-03 NI Notes: Bouwer-Rice = Unconfined Bouwer-Rice solution method in Aqtesolv™ cm/s = Centimeters per second ft = Feet K = hydraulic conductivity KGS = Unconfined KGS solution method in Aqtesolv™ Ss= specific storage NI= Not interpretable . Automatically Logged Data Hand Collected Data KGS KGS H:\718000\hydrpt09b\report\App A Tables.xls: Table A.2 12/29/2009 TABLE A.3 Estimated Hydraulic Conductivities and Perched Zone Pore Velocities Pathline Head Change Hydraulic Gradient Pore Velocity (cm/s) (ft/yr) (ft) (ft) ft/ft ft/yr TWN-1 1.70E-04 1.74E+02 220 13 5.91E-02 57.0 TWN-2 1.87E-05 1.91E+01 230 17 7.39E-02 7.85 TWN-3 8.77E-06 8.96E+00 300 13 4.33E-02 2.16 TWN-4 8.94E-04 9.14E+02 1050 10 9.52E-03 48.3 TWN-5 4.47E-04 4.57E+02 290 15 5.17E-02 131 TWN-6 1.74E-04 1.78E+02 440 10 2.27E-02 22.5 TWN-7 4.08E-07 4.17E-01 660 10 1.52E-02 0.04 TWN-8 1.13E-04 1.16E+02 550 13 2.36E-02 15.2 TWN-9 2.93E-05 2.99E+01 825 17 2.06E-02 3.42 TWN-10 3.07E-05 3.14E+01 660 5 7.58E-03 1.32 TWN-11 1.08E-04 1.11E+02 880 14 1.59E-02 9.8 TWN-12 7.87E-05 8.04E+01 550 22 4.00E-02 17.9 TWN-13 3.69E-06 3.77E+00 1050 4 3.81E-03 0.08 TWN-14 3.18E-06 3.25E+00 880 13 1.48E-02 0.27 TWN-15 3.68E-05 3.76E+01 990 14 1.41E-02 2.96 TWN-16 0.010336 1.06E+04 770 10 1.30E-02 762 TWN-17 4.96E-06 5.06E+00 1200 10 8.33E-03 0.23 TWN-18 1.70E-03 1.74E+03 300 10 3.33E-02 322 TWN-19 2.25E-05 2.30E+01 550 22 4.00E-02 23.2 Notes: aAverage of KGS and Bouwer-Rice estimates. Assumes effective porosity of 0.18 cm/s = Centimeters per second ft/ft = Feet per foot ft/yr = Feet per year Well Hydraulic Conductivitya H:\718000\hydtst09\report\Tables.xls: Table A.3 12/29/2009 FIGURES HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE CELL NO. 2 CELL NO. 4A 3332 MW-21 3000 BOUNDARY PROPERTY SCALE IN FEET 0 CELL NO. 1 MILL SITE MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-16 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-32 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 MW-26 TW4-1 TW4-2 TW4-3 TW4-4 TW4-5 TW4-6 TW4-9 TW4-11 TW4-12 TW4-13 TW4-14 TW4-16 TW4-18 TW4-20 TW4-21 MW-04TW4-7 TW4-8 TW4-10 TW4-22 TW4-19 TW4-23 TW4-24 TW4-25 TWN-1 TWN-2 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 MW-20 PIEZ-1 perched monitoring well temporary perched monitoring well installed April, 2005 perched piezometer MW-31 temporary perched monitoring well perched monitoring well installed April, 2005 SITE PLAN AND PERCHED WELL LOCATIONS WHITE MESA SITE H:/718000/hydrpt09b/TWNloc.srf TW4-19 TW4-20 EXPLANATION temporary perched monitoring well installed May, 2007 TW4-23 wildlife pond SJS temporary perched nitrate monitoring well TWN-1 A.112/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 3332 3000 SCALE IN FEET 0 5582 5503 5471 5502 5521 5501 5494 5493 5498 5587 5604 5458 5450 5498 5507 5537 5576 5543 5512 5537 5547 5557 5557 5583 5550 5585 5537 5583 5578 5565 5586 5571 5524 5549 5559 5548 558455485561 5580 5574 5593 5614 5600 5542 5541 MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-28 MW-29 MW-30 MW-31 MW-26 MW-32 TW4-19 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 5551 5553 5554MW-04 5541 5569 5599 TW4-24 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-11 TWN-12 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 5603 5606 5585 5590 5559 5603 5583 5585 5614 5629 5587 5587 5584 5604 5606 5600 5607 5603 5607 TWN-1 TWN-2 MW-22 PIEZ-1 5450 5592 perched monitoring well showing elevation in feet amsl temporary perched monitoring well installed April, 2005 showing elevation in feet amsl perched piezometer showing elevation in feet amsl 5556 MW-31 5546 temporary perched monitoring well showing elevation in feet amsl 5573 perched monitoring well installed April, 2005 showing elevation in feet amsl KRIGED DECEMBER 2009 WATER LEVELS SHOWING LOCATIONS OF HYDRAULIC GRADIENT CALCULATIONS WHITE MESA SITE H:/718000/hydrrpt09b/wlq4pathc.srf EXPLANATION temporary perched monitoring well installed May, 2007 showing elevation in feet amsl5541 SJS temporary perched nitrate monitoring well showing elevation in feet amsl TWN-4 5605 pathline for gradient calculations A.212/29/09 HYDRO GEO CHEM, INC.APPROVED DATE REFERENCE FIGURE 3332 3000 SCALE IN FEET 0 0.08 0.03 1.5 0.08 0.03 0.11 0.05 0.16 0.7 0.03 2.5 4.9 3.6 0.03 0.1 0.1 0.3 5.7 0.2 0.05 15 23 0.05 7.5 6.5 2.5 10 7.9 2.2 2.5 12 7.3 2.4 3.7 1.6 9.6 5.23.2 5.1 8.3 21 6.8 0.5 0.8 1.8 0.7 21 29 0.5 0.2 1.4 0.1 0.01 12 1.4 0.5 3.4 1.1 1 6.7 1.3 7.4 MW-01 MW-02 MW-03 MW-05 MW-11 MW-12 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-22 MW-23 MW-24 MW-25 MW-27 MW-26 MW-28 MW-29 MW-30 MW-31 MW-32 TW4-19 PIEZ-1 PIEZ-2 PIEZ-3 PIEZ-4 PIEZ-5 TWN-2 TWN-3 TWN-4 TWN-5 TWN-6 TWN-7 TWN-8 TWN-9 TWN-10 TWN-13 TWN-14 TWN-15 TWN-16 TWN-17 TWN-18 TWN-19 3.7 5.7 0.05MW-04 0.05 31 15 TW4-24 TWN-18 TWN-1 TWN-11 TWN-12 0.4 1.3 0.5 MW-4 PIEZ-1 5.7 NS perched monitoring well showing concentration in mg/L temporary perched monitoring well installed April, 2005 showing concentration in mg/L perched piezometer (not sampled) 7.5 MW-32 0.05 temporary perched monitoring well showing concentration in mg/L 5.1 perched monitoring well installed April, 2005 showing concentration in mg/L PERCHED ZONE NITRATE (mg/L) WHITE MESA SITE H:/718000/hydrpt09b/no3postc.srf EXPLANATION temporary perched monitoring well installed May, 2007 showing concentration in mg/LND SJS AREA 1 AREA 2 temporary perched nitrate monitoring well showing concentration in mg/L TWN-1 0.4 area with nitrate > 5 mg/L A.312/29/09 APPENDIX A.1 BACKGROUND CORRECTIONS H:\718000\hydtst09\report\AppendixA\TWN-2 correction.xls: graph Chart 1 TWN-2 Raw and Corrected Displacements 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0 5 10 15 20 25 30 35 40 45 50 55 60 65 Time (minutes) Di s p l a c e m e n t ( f t ) raw corrected H:\718000\hydtst09\report\AppendixA\TWN-9 correction.xls: graph Chart 1 TWN-9 Raw and Corrected Displacements 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 Time (minutes) Di s p l a c e m e n t ( f t ) raw corrected H:\718000\hydtst09\report\AppendixA\TWN-10 correction.xls: graph Chart 1 TWN-10 Raw and Corrected Displacements 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 Time (minutes) Di s p l a c e m e n t ( f t ) raw corrected H:\718000\hydtst09\report\AppendixA\TWN-11 correction.xls: graph Chart 1 TWN-11 Raw and Corrected Displacements 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0 5 10 15 20 25 30 35 Tme (minutes) Di s p l a c e m e n t ( f t ) raw corrected H:\718000\hydtst09\report\AppendixA\TWN-12 correction.xls: graph Chart 1 TWN-12 Raw and Corrected Displacements 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0 5 10 15 20 25 30 35 40 45 50 55 Time (minutes) Di s p l a c e m e n t ( f t ) raw corrected APPENDIX A.2 SLUG TEST ANALYSIS PLOTS 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn1\twn1.aqt Date: 11/12/09 Time: 11:44:37 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-1 AQUIFER DATA Saturated Thickness: 54. ft WELL DATA (twn1) Initial Displacement: 0.75 ft Static Water Column Height: 54. ft Total Well Penetration Depth: 54. ft Screen Length: 47. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0001702 cm/sec Ss = 0.002215 ft-1 Kz/Kr = 0.1 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn1\twn1h.aqt Date: 11/12/09 Time: 11:45:12 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-1 AQUIFER DATA Saturated Thickness: 54. ft WELL DATA (twn1) Initial Displacement: 0.75 ft Static Water Column Height: 54. ft Total Well Penetration Depth: 54. ft Screen Length: 47. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0001971 cm/sec Ss = 0.001247 ft-1 Kz/Kr = 0.1 0. 6. 12. 18. 24. 30. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn1\twn1hbr.aqt Date: 11/12/09 Time: 11:45:27 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-1 AQUIFER DATA Saturated Thickness: 54. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn1) Initial Displacement: 0.75 ft Static Water Column Height: 54. ft Total Well Penetration Depth: 54. ft Screen Length: 47. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.0001364 cm/sec y0 = 0.1976 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn2\twn2c.aqt Date: 11/12/09 Time: 11:48:04 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-2 AQUIFER DATA Saturated Thickness: 74. ft WELL DATA (twn2) Initial Displacement: 0.5 ft Static Water Column Height: 74. ft Total Well Penetration Depth: 74. ft Screen Length: 74. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 1.499E-5 cm/sec Ss = 0.0003201 ft-1 Kz/Kr = 0.1 0. 12. 24. 36. 48. 60. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn2\twn2cbr.aqt Date: 11/12/09 Time: 11:48:21 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-2 AQUIFER DATA Saturated Thickness: 74. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn2) Initial Displacement: 0.5 ft Static Water Column Height: 74. ft Total Well Penetration Depth: 74. ft Screen Length: 74. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 2.253E-5 cm/sec y0 = 0.3764 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn2\twn2h.aqt Date: 11/12/09 Time: 11:48:41 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-2 AQUIFER DATA Saturated Thickness: 74. ft WELL DATA (twn2) Initial Displacement: 0.5 ft Static Water Column Height: 74. ft Total Well Penetration Depth: 74. ft Screen Length: 74. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 2.04E-5 cm/sec Ss = 0.0001156 ft-1 Kz/Kr = 0.1 0. 14. 28. 42. 56. 70. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn2\twn2hbr.aqt Date: 11/12/09 Time: 11:49:04 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-2 AQUIFER DATA Saturated Thickness: 74. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn2) Initial Displacement: 0.5 ft Static Water Column Height: 74. ft Total Well Penetration Depth: 74. ft Screen Length: 74. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 2.729E-5 cm/sec y0 = 0.4075 ft 0.01 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn3\twn3.aqt Date: 11/12/09 Time: 11:49:43 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-3 AQUIFER DATA Saturated Thickness: 60. ft WELL DATA (twn3) Initial Displacement: 1. ft Static Water Column Height: 60. ft Total Well Penetration Depth: 60. ft Screen Length: 47. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 8.563E-6 cm/sec Ss = 8.731E-6 ft-1 Kz/Kr = 0.1 0. 40. 80. 120. 160. 200. 0.1 1. 10. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn3\twn3br.aqt Date: 11/12/09 Time: 11:49:59 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-3 AQUIFER DATA Saturated Thickness: 60. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn3) Initial Displacement: 1. ft Static Water Column Height: 60. ft Total Well Penetration Depth: 60. ft Screen Length: 47. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 8.967E-6 cm/sec y0 = 0.8239 ft 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn3\twn3h.aqt Date: 11/12/09 Time: 11:50:20 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-3 AQUIFER DATA Saturated Thickness: 60. ft WELL DATA (twn3) Initial Displacement: 1. ft Static Water Column Height: 60. ft Total Well Penetration Depth: 60. ft Screen Length: 47. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 7.75E-6 cm/sec Ss = 1.527E-5 ft-1 Kz/Kr = 0.1 0. 40. 80. 120. 160. 200. 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn3\twn3hbr.aqt Date: 11/12/09 Time: 11:50:34 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-3 AQUIFER DATA Saturated Thickness: 60. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn3) Initial Displacement: 1. ft Static Water Column Height: 60. ft Total Well Penetration Depth: 60. ft Screen Length: 47. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 8.898E-6 cm/sec y0 = 0.8239 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn4\twn4.aqt Date: 11/12/09 Time: 11:51:06 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-4 AQUIFER DATA Saturated Thickness: 85. ft WELL DATA (twn4) Initial Displacement: 1. ft Static Water Column Height: 85. ft Total Well Penetration Depth: 85. ft Screen Length: 77. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.001763 cm/sec Ss = 0.000343 ft-1 Kz/Kr = 0.1023 0. 4. 8. 12. 16. 20. 0.001 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn4\twn4br.aqt Date: 11/12/09 Time: 11:51:20 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-4 AQUIFER DATA Saturated Thickness: 85. ft Anisotropy Ratio (Kz/Kr): 0.1023 WELL DATA (twn4) Initial Displacement: 1. ft Static Water Column Height: 85. ft Total Well Penetration Depth: 85. ft Screen Length: 77. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 2.794E-5 cm/sec y0 = 0.01803 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn4\twn4h.aqt Date: 11/12/09 Time: 11:51:39 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-4 AQUIFER DATA Saturated Thickness: 85. ft WELL DATA (twn4) Initial Displacement: 1. ft Static Water Column Height: 85. ft Total Well Penetration Depth: 85. ft Screen Length: 77. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.001257 cm/sec Ss = 1.844E-6 ft-1 Kz/Kr = 0.1023 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn5\twn5.aqt Date: 11/12/09 Time: 11:52:23 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-5 AQUIFER DATA Saturated Thickness: 77. ft WELL DATA (twn5) Initial Displacement: 0.75 ft Static Water Column Height: 77. ft Total Well Penetration Depth: 77. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0004878 cm/sec Ss = 3.884E-7 ft-1 Kz/Kr = 0.1 0. 4. 8. 12. 16. 20. 0.001 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn5\twn5br.aqt Date: 11/12/09 Time: 11:52:51 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-5 AQUIFER DATA Saturated Thickness: 77. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn5) Initial Displacement: 0.75 ft Static Water Column Height: 77. ft Total Well Penetration Depth: 77. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.0004057 cm/sec y0 = 0.6545 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn5\twn5h.aqt Date: 11/12/09 Time: 11:53:06 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-5 AQUIFER DATA Saturated Thickness: 77. ft WELL DATA (twn5) Initial Displacement: 0.75 ft Static Water Column Height: 77. ft Total Well Penetration Depth: 77. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0004878 cm/sec Ss = 3.884E-7 ft-1 Kz/Kr = 0.1 0. 2. 4. 6. 8. 10. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn5\twn5hbr.aqt Date: 11/12/09 Time: 11:53:20 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-5 AQUIFER DATA Saturated Thickness: 77. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn5) Initial Displacement: 0.75 ft Static Water Column Height: 77. ft Total Well Penetration Depth: 77. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.00037 cm/sec y0 = 0.57 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn6\twn6.aqt Date: 11/12/09 Time: 11:53:41 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-6 AQUIFER DATA Saturated Thickness: 52. ft WELL DATA (twn6) Initial Displacement: 0.65 ft Static Water Column Height: 52. ft Total Well Penetration Depth: 52. ft Screen Length: 52. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft Gravel Pack Porosity: 0.3 SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0001743 cm/sec Ss = 0.002215 ft-1 Kz/Kr = 0.1 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn6\twn6h.aqt Date: 11/12/09 Time: 11:53:56 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-6 AQUIFER DATA Saturated Thickness: 52. ft WELL DATA (twn6) Initial Displacement: 0.65 ft Static Water Column Height: 52. ft Total Well Penetration Depth: 52. ft Screen Length: 52. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft Gravel Pack Porosity: 0.3 SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0003495 cm/sec Ss = 2.215E-12 ft-1 Kz/Kr = 0.1 0. 2. 4. 6. 8. 10. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn6\twn6hbr.aqt Date: 11/12/09 Time: 11:54:07 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-6 AQUIFER DATA Saturated Thickness: 52. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn6) Initial Displacement: 0.65 ft Static Water Column Height: 52. ft Total Well Penetration Depth: 52. ft Screen Length: 52. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft Gravel Pack Porosity: 0.3 SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.0003358 cm/sec y0 = 0.328 ft 0.01 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn7\twn7c.aqt Date: 11/12/09 Time: 11:55:24 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-7 AQUIFER DATA Saturated Thickness: 11. ft WELL DATA (twn7) Initial Displacement: 0.5 ft Static Water Column Height: 11. ft Total Well Penetration Depth: 11. ft Screen Length: 11. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 3.573E-7 cm/sec Ss = 0.002215 ft-1 Kz/Kr = 0.1 0. 120. 240. 360. 480. 600. 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn7\twn7cbr.aqt Date: 11/12/09 Time: 11:55:37 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-7 AQUIFER DATA Saturated Thickness: 11. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn7) Initial Displacement: 0.5 ft Static Water Column Height: 11. ft Total Well Penetration Depth: 11. ft Screen Length: 11. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 4.595E-7 cm/sec y0 = 0.4324 ft 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn7\twn7hc.aqt Date: 11/12/09 Time: 11:56:10 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-7 AQUIFER DATA Saturated Thickness: 11. ft WELL DATA (twn7) Initial Displacement: 0.5 ft Static Water Column Height: 11. ft Total Well Penetration Depth: 11. ft Screen Length: 11. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 3.573E-7 cm/sec Ss = 0.002215 ft-1 Kz/Kr = 0.1 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn8\twn8.aqt Date: 11/12/09 Time: 11:57:13 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-8 AQUIFER DATA Saturated Thickness: 80. ft WELL DATA (twn8) Initial Displacement: 0.75 ft Static Water Column Height: 80. ft Total Well Penetration Depth: 80. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0001506 cm/sec Ss = 0.0003657 ft-1 Kz/Kr = 0.1 0. 4. 8. 12. 16. 20. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn8\twn8br.aqt Date: 11/12/09 Time: 11:57:25 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-8 AQUIFER DATA Saturated Thickness: 80. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn8) Initial Displacement: 0.75 ft Static Water Column Height: 80. ft Total Well Penetration Depth: 80. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 7.55E-5 cm/sec y0 = 0.1367 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn8\twn8h.aqt Date: 11/12/09 Time: 11:59:32 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-8 AQUIFER DATA Saturated Thickness: 80. ft WELL DATA (twn8) Initial Displacement: 0.75 ft Static Water Column Height: 80. ft Total Well Penetration Depth: 80. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0004733 cm/sec Ss = 1.413E-6 ft-1 Kz/Kr = 0.1 0. 4. 8. 12. 16. 20. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn8\twn8hbr.aqt Date: 11/12/09 Time: 11:59:47 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-8 AQUIFER DATA Saturated Thickness: 80. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn8) Initial Displacement: 0.75 ft Static Water Column Height: 80. ft Total Well Penetration Depth: 80. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.0002484 cm/sec y0 = 0.3132 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn9\twn9c.aqt Date: 11/12/09 Time: 12:00:39 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-9 AQUIFER DATA Saturated Thickness: 29. ft WELL DATA (twn9) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 29. ft Screen Length: 29. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 2.989E-5 cm/sec Ss = 0.006923 ft-1 Kz/Kr = 0.1 0. 16. 32. 48. 64. 80. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn9\twn9cbr.aqt Date: 11/12/09 Time: 12:00:55 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-9 AQUIFER DATA Saturated Thickness: 29. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn9) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 29. ft Screen Length: 29. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 2.855E-5 cm/sec y0 = 0.1721 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn9\twn9h.aqt Date: 11/12/09 Time: 12:01:11 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-9 AQUIFER DATA Saturated Thickness: 29. ft WELL DATA (twn9) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 29. ft Screen Length: 29. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 6.017E-5 cm/sec Ss = 0.005586 ft-1 Kz/Kr = 0.1 0. 8. 16. 24. 32. 40. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn9\twn9hbr.aqt Date: 11/12/09 Time: 12:01:24 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-9 AQUIFER DATA Saturated Thickness: 29. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn9) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 29. ft Screen Length: 29. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 7.932E-5 cm/sec y0 = 0.2376 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn10\twn10c.aqt Date: 11/12/09 Time: 12:06:05 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-10 AQUIFER DATA Saturated Thickness: 20. ft WELL DATA (twn10) Initial Displacement: 0.5 ft Static Water Column Height: 20. ft Total Well Penetration Depth: 20. ft Screen Length: 20. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 3.827E-5 cm/sec Ss = 0.1 ft-1 Kz/Kr = 0.1 0. 16. 32. 48. 64. 80. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn10\twn10cbr.aqt Date: 11/12/09 Time: 12:06:20 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-10 AQUIFER DATA Saturated Thickness: 20. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn10) Initial Displacement: 0.5 ft Static Water Column Height: 20. ft Total Well Penetration Depth: 20. ft Screen Length: 20. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 2.306E-5 cm/sec y0 = 0.07868 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn10\twn10h.aqt Date: 11/12/09 Time: 12:07:32 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-10 AQUIFER DATA Saturated Thickness: 20. ft WELL DATA (twn10) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 20. ft Screen Length: 20. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 8.702E-5 cm/sec Ss = 0.008127 ft-1 Kz/Kr = 0.1 0. 8. 16. 24. 32. 40. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn10\twn10hbr.aqt Date: 11/12/09 Time: 12:07:45 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-10 AQUIFER DATA Saturated Thickness: 20. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn10) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 20. ft Screen Length: 20. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.0001096 cm/sec y0 = 0.2488 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn11\twn11c.aqt Date: 11/12/09 Time: 12:08:09 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-11 AQUIFER DATA Saturated Thickness: 68. ft WELL DATA (twn11) Initial Displacement: 0.5 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0001182 cm/sec Ss = 1.079E-5 ft-1 Kz/Kr = 0.1 0. 6. 12. 18. 24. 30. 0.001 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn11\twn11cbr.aqt Date: 11/12/09 Time: 12:09:01 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-11 AQUIFER DATA Saturated Thickness: 68. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn11) Initial Displacement: 0.5 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 9.833E-5 cm/sec y0 = 0.3944 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn11\twn11h.aqt Date: 11/12/09 Time: 12:09:16 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-11 AQUIFER DATA Saturated Thickness: 68. ft WELL DATA (twn11) Initial Displacement: 0.5 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 9.344E-5 cm/sec Ss = 7.177E-5 ft-1 Kz/Kr = 0.1 0. 4. 8. 12. 16. 20. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn11\twn11hbr.aqt Date: 11/12/09 Time: 12:09:29 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-11 AQUIFER DATA Saturated Thickness: 68. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn11) Initial Displacement: 0.5 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 9.784E-5 cm/sec y0 = 0.3597 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn12\twn12c.aqt Date: 11/12/09 Time: 12:10:10 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-12 AQUIFER DATA Saturated Thickness: 67. ft WELL DATA (twn12) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 67. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 8.054E-5 cm/sec Ss = 4.65E-5 ft-1 Kz/Kr = 0.1 0. 12. 24. 36. 48. 60. 1.0E-4 0.001 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn12\twn12cbr.aqt Date: 11/12/09 Time: 12:10:26 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-12 AQUIFER DATA Saturated Thickness: 67. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn12) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 67. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 7.691E-5 cm/sec y0 = 0.3766 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn12\twn12h.aqt Date: 11/12/09 Time: 12:10:38 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-12 AQUIFER DATA Saturated Thickness: 67. ft WELL DATA (twn12) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 67. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.0001284 cm/sec Ss = 1.271E-7 ft-1 Kz/Kr = 0.1 0. 6. 12. 18. 24. 30. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn12\twn12hbr.aqt Date: 11/12/09 Time: 12:10:59 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-12 AQUIFER DATA Saturated Thickness: 67. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn12) Initial Displacement: 0.5 ft Static Water Column Height: 29. ft Total Well Penetration Depth: 67. ft Screen Length: 67. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 7.387E-5 cm/sec y0 = 0.3766 ft 0.01 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn13\twn13.aqt Date: 11/12/09 Time: 12:11:20 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-13 AQUIFER DATA Saturated Thickness: 68. ft WELL DATA (twn13) Initial Displacement: 0.75 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 2.619E-6 cm/sec Ss = 0.1 ft-1 Kz/Kr = 0.1 0. 60. 120. 180. 240. 300. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn13\twn13br.aqt Date: 11/12/09 Time: 12:11:32 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-13 AQUIFER DATA Saturated Thickness: 68. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn13) Initial Displacement: 0.75 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 4.766E-6 cm/sec y0 = 0.1367 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn13\twn13h.aqt Date: 11/12/09 Time: 12:11:46 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-13 AQUIFER DATA Saturated Thickness: 68. ft WELL DATA (twn13) Initial Displacement: 0.75 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 2.093E-6 cm/sec Ss = 0.1 ft-1 Kz/Kr = 0.1 0. 12. 24. 36. 48. 60. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn13\twn13hbr.aqt Date: 11/12/09 Time: 12:11:58 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-13 AQUIFER DATA Saturated Thickness: 68. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn13) Initial Displacement: 0.75 ft Static Water Column Height: 68. ft Total Well Penetration Depth: 68. ft Screen Length: 68. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 6.93E-6 cm/sec y0 = 0.1888 ft 0.01 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn14\twn14.aqt Date: 11/12/09 Time: 12:12:31 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-14 AQUIFER DATA Saturated Thickness: 57. ft WELL DATA (twn14) Initial Displacement: 0.75 ft Static Water Column Height: 57. ft Total Well Penetration Depth: 57. ft Screen Length: 57. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 3.611E-6 cm/sec Ss = 0.006392 ft-1 Kz/Kr = 0.1 0. 60. 120. 180. 240. 300. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn14\twn14br.aqt Date: 11/12/09 Time: 12:13:10 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-14 AQUIFER DATA Saturated Thickness: 57. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn14) Initial Displacement: 0.75 ft Static Water Column Height: 57. ft Total Well Penetration Depth: 57. ft Screen Length: 57. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 2.741E-6 cm/sec y0 = 0.1137 ft 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn14\twn14h.aqt Date: 11/12/09 Time: 12:13:23 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-14 AQUIFER DATA Saturated Thickness: 57. ft WELL DATA (twn14) Initial Displacement: 0.75 ft Static Water Column Height: 57. ft Total Well Penetration Depth: 57. ft Screen Length: 57. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 3.976E-6 cm/sec Ss = 0.003166 ft-1 Kz/Kr = 0.1 0. 12. 24. 36. 48. 60. 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn14\twn14hbr.aqt Date: 11/12/09 Time: 12:13:39 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-14 AQUIFER DATA Saturated Thickness: 57. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn14) Initial Displacement: 0.75 ft Static Water Column Height: 57. ft Total Well Penetration Depth: 57. ft Screen Length: 57. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 7.933E-6 cm/sec y0 = 0.3766 ft 0.01 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn15\twn15.aqt Date: 11/12/09 Time: 12:13:55 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-15 AQUIFER DATA Saturated Thickness: 58. ft WELL DATA (twn15) Initial Displacement: 0.5 ft Static Water Column Height: 58. ft Total Well Penetration Depth: 58. ft Screen Length: 58. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 4.751E-5 cm/sec Ss = 0.001037 ft-1 Kz/Kr = 0.1 0. 12. 24. 36. 48. 60. 0.001 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn15\twn15br.aqt Date: 11/12/09 Time: 12:14:07 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-15 AQUIFER DATA Saturated Thickness: 58. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn15) Initial Displacement: 0.5 ft Static Water Column Height: 58. ft Total Well Penetration Depth: 58. ft Screen Length: 58. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 2.611E-5 cm/sec y0 = 0.1137 ft 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn15\twn15h.aqt Date: 11/12/09 Time: 12:14:19 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-15 AQUIFER DATA Saturated Thickness: 58. ft WELL DATA (twn15) Initial Displacement: 0.5 ft Static Water Column Height: 58. ft Total Well Penetration Depth: 58. ft Screen Length: 58. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 5.857E-5 cm/sec Ss = 0.0003488 ft-1 Kz/Kr = 0.1 0. 6. 12. 18. 24. 30. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn15\twn15hbr.aqt Date: 11/12/09 Time: 12:14:30 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-15 AQUIFER DATA Saturated Thickness: 58. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn15) Initial Displacement: 0.5 ft Static Water Column Height: 58. ft Total Well Penetration Depth: 58. ft Screen Length: 58. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 6.422E-5 cm/sec y0 = 0.2857 ft 0.01 0.1 1. 10. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn16\twn16.aqt Date: 11/12/09 Time: 12:15:01 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-16 AQUIFER DATA Saturated Thickness: 41. ft WELL DATA (twn16) Initial Displacement: 1. ft Static Water Column Height: 41. ft Total Well Penetration Depth: 41. ft Screen Length: 41. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.01416 cm/sec Ss = 0.0008019 ft-1 Kz/Kr = 0.1 0. 0.1 0.2 0.3 0.4 0.5 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn16\twn16br.aqt Date: 11/12/09 Time: 12:15:12 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-16 AQUIFER DATA Saturated Thickness: 41. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn16) Initial Displacement: 1. ft Static Water Column Height: 41. ft Total Well Penetration Depth: 41. ft Screen Length: 41. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.006472 cm/sec y0 = 0.2167 ft 0.01 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn17\twn17.aqt Date: 11/12/09 Time: 12:15:34 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-17 AQUIFER DATA Saturated Thickness: 69. ft WELL DATA (twn17) Initial Displacement: 0.5 ft Static Water Column Height: 69. ft Total Well Penetration Depth: 69. ft Screen Length: 69. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 3.725E-6 cm/sec Ss = 0.03315 ft-1 Kz/Kr = 0.1 0. 40. 80. 120. 160. 200. 0.001 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn17\twn17br.aqt Date: 11/12/09 Time: 12:16:05 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-17 AQUIFER DATA Saturated Thickness: 69. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn17) Initial Displacement: 0.5 ft Static Water Column Height: 69. ft Total Well Penetration Depth: 69. ft Screen Length: 69. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 6.181E-6 cm/sec y0 = 0.07176 ft 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn17\twn17h.aqt Date: 11/12/09 Time: 12:16:32 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-17 AQUIFER DATA Saturated Thickness: 69. ft WELL DATA (twn17) Initial Displacement: 0.5 ft Static Water Column Height: 69. ft Total Well Penetration Depth: 69. ft Screen Length: 69. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 1.416E-6 cm/sec Ss = 0.06122 ft-1 Kz/Kr = 0.1 0. 30. 60. 90. 120. 150. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn17\twn17hbr.aqt Date: 11/12/09 Time: 12:17:19 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-17 AQUIFER DATA Saturated Thickness: 69. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn17) Initial Displacement: 0.5 ft Static Water Column Height: 69. ft Total Well Penetration Depth: 69. ft Screen Length: 69. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 1.955E-6 cm/sec y0 = 0.08239 ft 0.01 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn18\twn18.aqt Date: 11/12/09 Time: 12:18:02 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-18 AQUIFER DATA Saturated Thickness: 83. ft WELL DATA (twn18) Initial Displacement: 0.75 ft Static Water Column Height: 83. ft Total Well Penetration Depth: 83. ft Screen Length: 83. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.002267 cm/sec Ss = 2.442E-6 ft-1 Kz/Kr = 0.1 0. 1. 2. 3. 4. 5. 0.001 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn18\twn18br.aqt Date: 11/12/09 Time: 12:18:21 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-18 AQUIFER DATA Saturated Thickness: 83. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn18) Initial Displacement: 0.75 ft Static Water Column Height: 83. ft Total Well Penetration Depth: 83. ft Screen Length: 83. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 0.001136 cm/sec y0 = 0.3597 ft 0.1 1. 10. 100. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn18\twn18h.aqt Date: 11/12/09 Time: 12:18:34 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-18 AQUIFER DATA Saturated Thickness: 83. ft WELL DATA (twn18) Initial Displacement: 0.75 ft Static Water Column Height: 83. ft Total Well Penetration Depth: 83. ft Screen Length: 83. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 0.00267 cm/sec Ss = 2.215E-12 ft-1 Kz/Kr = 0.1 0.01 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn19\twn19.aqt Date: 11/12/09 Time: 12:18:57 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-19 AQUIFER DATA Saturated Thickness: 50. ft WELL DATA (twn19) Initial Displacement: 0.5 ft Static Water Column Height: 50. ft Total Well Penetration Depth: 50. ft Screen Length: 50. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 2.685E-5 cm/sec Ss = 0.002493 ft-1 Kz/Kr = 0.1 0. 16. 32. 48. 64. 80. 0.01 0.1 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn19\twn19br.aqt Date: 11/12/09 Time: 12:19:27 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-19 AQUIFER DATA Saturated Thickness: 50. ft Anisotropy Ratio (Kz/Kr): 0.1 WELL DATA (twn19) Initial Displacement: 0.5 ft Static Water Column Height: 50. ft Total Well Penetration Depth: 50. ft Screen Length: 50. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: Bouwer-Rice K = 1.811E-5 cm/sec y0 = 0.1367 ft 0.1 1. 10. 100. 1000. 0. 0.2 0.4 0.6 0.8 1. Time (min) Di s p l a c e m e n t ( f t ) WELL TEST ANALYSIS Data Set: H:\718000\hydtst09\twn19\twn19h.aqt Date: 11/12/09 Time: 12:19:40 PROJECT INFORMATION Company: HGC Client: Denison Test Well: TWN-19 AQUIFER DATA Saturated Thickness: 50. ft WELL DATA (twn19) Initial Displacement: 0.5 ft Static Water Column Height: 50. ft Total Well Penetration Depth: 50. ft Screen Length: 50. ft Casing Radius: 0.167 ft Well Radius: 0.28 ft SOLUTION Aquifer Model: Unconfined Solution Method: KGS Model Kr = 3.832E-5 cm/sec Ss = 0.00335 ft-1 Kz/Kr = 0.1 Attachment 6: Calculation to Evaluate Potential Tailings Cell Source Assume:  Nitrate Concentration in Tailings Solution = 290 mg/L  Nitrate Concentration in un-impacted Groundwater = 1 mg/L  Average Plume Concentration = 30 mg/L Mixing Equation: Ct*Vt + Cg*Vg = Cm*Vm (eq 1) Where: Ct = Concentration of nitrate in tailings solutions Vt = Volume of tailings solutions Cg = Concentration of nitrate in unimpacted groundwater Vg = Volume of unimpacted groundwater Cm = Concentration of nitrate in mixture Vm = Volume of mixture Another Equation: Vt + Vg = Vm (eq 2) Substituting eq2 in eq1: Ct*Vt + Cg*Vg = Cm*( Vt + Vg) (eq 3) Substitute Nitrate Concentrations in eq3 290*Vt + 1*Vg = 30*( Vt + Vg) 290*Vt + 1*Vg = 30*Vt + 30*Vg 260*Vt = 29*Vg Vt = 29/260*Vg = 0.11* Vg The volume of tailings solution would have to be eleven percent of the volume of unimpacted groundwater in the mixture. Attachment 6 Calculation to Evaluate Potential Tailings Cell Source