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DRC-2009-006365 - 0901a0688014d819
State of Utah GARY R.HERBERT I Governor fiREG BELL Lieutenant Governor h?_c..- .:)Lcq -cokS(i-s3^ Department of Environmental Quality Arranda Smith E\eiuttve Director Dr\'ISrON OF RADIATION CONTROL Dane L. Fmerfrock Director 'e. ^/f '^ November 17,2009 CERTIFIED MAIL (Return Receipt Requested) Mr, David C Frydenlund Vice President and General Counsel Denison Mines (USA) Corp. (DUSA) 1050 Sevenieenth St. Suite 950 Denver. Colorado. 80265 Subject: DUSA 1" Quarter, 2009 (June I, 2009). Groundwater Monitoring Report: Notice of Violation and Compliance Order, Docket No. UGW09-06 Dear Mr. Frydenlund: The enclosed Notice of Violation and Compliance Order ("NOV/CO") is based on Division of Radiation Control (DRC) findings from the review of the DUSA, 1" Quarter 2009 Groundwater Monitoring Report for the White Mesa Uranium Mill facility near Blanding, Utah. Please give this order your immediate attention. A written response is required within 30 calendar days after receipt of this NOTICE. This order is fully enforceable unless appealed in writing within 30 days, as described in the ^^Notice" section of this NOV/CO. Any response or written answer to this NOV/CO should be addressed to Dane L. Finerfrock, Co-Executive Secretary, Utah Water Quality Board, 168 North 1950 West, P.O. Box 144850, Salt Lake City, Utah 84114-4850. UTAH WATER QUALITY BOARD Dane L. Finerfrock Co-Execulive Secretary "Enclosure; Notice of Violation and Order, Docket No. UGW09-06 168 Nortli 1050 West • SaU Lake City. UT Mailing Address- P.O. Bo^ I446.S0 • SaU Uke Citv, (IT Ml 14-4850 TcJfphone (801) 536-4250 • Fax (SOI i 533^097 • T.D.D. (801) S.16-4414 PrinLeil on lOO'.t recycled paper UTAH WATER QUALITY BOARD IN THE MATTER OF Denison Mines (USA) Corp. 1050 SEVENTEENTH ST. SUITE 950 DENVER, COLORADO, 80265 DOCKET NUMBER UGW09-06 NOTICE OF VIOLATION AND COMPLIANCE ORDER A. STATUTORY AUTHORITY This NOTICE OF VIOLATION and COMPLIANCE ORDER (NOV/CO) is issued to Denison Mines (USA) Corporation (hereinafter DUSA) facility, by the UTAH WATER QUALFTY BOARD (hereinafter the BOARD) under the Utah Water Quality Act, Utah Code Ann. §§ 19-5-101 to 19-5-123 (the ACT), including sections 19-5-104, 19-5-106, 19-5-111 and 19-5- 115. This NOV/CO is also issued in accordance with the Utah Administrative Procedures Act, Utah Code Ann. §§ 63G4-101 to 63G-4-601. The BOARD has authorized the Co-Executive Secretary of the Board (Co-Executive Secretary) to issue such NOTICES AND ORDERS in accordance with §19-5-106(8) ofthe Utah Code. B. APPLICABLE STATUTORY AND REGULATORY PROVISIONS i. DUSA was issued Ground Water Quality Discharge Pennit No. UGW370004 (hereinafter Permit) on March 8, 2005, and was last modified on March 17, 2008. 2. l.E.Ua) ofthe Permit requires that "...all sampling shall be conducted to ensure collection ofthe representative samples, and reliabUity and validity of groundwater monitoring data. All groundwater sampling shall be conducted in accordance with the currently approved Groundwater Monitoring Quality Assurance Plan." 3. Part I.F. 1 of the Pennit requires that "...the Permittee shall submit quarterly monitoring reports of field and laboratory analyses of all well monitoring and samples described in Parts I.E.I, l.E.2, iE.3,1.E.5, and I.E.7 of this Pennit for E.xecutive Secretary review and approval. Reports shall be submitted according to the following schedule: Table 6. Groundwater Monitoring Reporting Schedule Quarter . First Second Third Fourth Period Januarv - March April - June July - September October - December Due Date June J September I Decemlyer I March I 4. Part n.A of the Permit requires thai ".. .Samples taken in compUance with the monitoring requirements eslablished under Pan 1 shall be representative ofthe monitored activity. " 5. The DUSA Quality Assurance Plan (hereinafter DUSA QAP) was originally dated November 17, 2006, (Revision 1.0); and was approved by the Co-Executive Secretary on November 17, 2009 Docket No. UGW09-06 Page 1 December 1, 2006. The DUSA QAP was last levised by DUSA on November 18, 2008 (Revision. 4.0) and was approved by the Co-Executive Secretary on March 30, 2009. Changes in QAP Revision 4.0 were minor and do not alter any findings set out below. 6. Section 4.3.1 ofthe DUSA QAP, states that "Trip blanks will be used to assess contamination introduced into the sample containers by volatile organic compounds ("VOCs") through diffusion during sample transport and storage." 7. Section 6.2.2 of the DUSA QAP, requires that all quarterly and semi-annual groundwater monitoring shall include collection of the following field parameters before sample collection: "... depth to groundwater, pH, temperature, specific conductance, redox potential (Eh) and turbidity in the manner specified in paragraph 6.2.7f d) {v)...". 8. Section 6.2.7(d)(v) of the DUSA QAP, requires that DUSA: "Take measurements of field parameters (pH, specific conductance, temperature, redox potential and turbidity) during well purging, using the Field Parameter Meter and turbidity measuring instrument. These maasurements will be recorded on the Field Data Worksheet. Purging is completed after two casing volumes have been removed and the field parameters pH, temperature, specific conductance, redox potential (Eh) and turbidity have stabilized to within 10% over at least two consecutive measurements. The groundwater in the weli should recover lo within at least 90% ofthe measured groundwater static surface before .sampling. In addition, turbidity measurement in the water should be<5 NTU prior to sampling (DTG WeU Development 6.7, page 6-48) unless the well is characterized by water that has a higher turbidity. Aflow-cell needs to be used for field parameters. Ifthe well is purgedto dryness or is purged such that fidl recovery exceeds two hours, the well should be sampled as soon as a sufficient volumc of groundwater is available to fill sample containers (DTG, Well Purging, 7.2.4, page 7-9r 9. Section 9.1.3 ofthe DUSA QAP, requires, in part, that "Trip blanks, and equipment rinsate samples will he compared with original sample results...." C. FINDINGS OF FACT 1. Denison Mines (USA) Corporation (hereinafter DUSA) facility receives and processes natural uranium-bearing ores and certain specified alternate feed materials, and possesses byproduct material in the form of uranium waste tailings and other uranium byproduct waste generated by the licensee's milling operations. This facility is located approximately 6 miles south of Bianding, Utah on a tract of land in Sections 28, 29, 32, and 33, Township 37 South, Range 22 Easl, Salt Lake Baseline and Meridian, San Juan County, Utah. 2. DUSA submitted a report tilled "While Mesa Uranium Mill Groundwater Monitoring Report l*^^ Quarter (January - March)" to the Utah Division of Radiation Control (hereafter DRC) dated June 1, 2009 (hereinafter l" Quarter, 2009 Report). 3. The DUSA I^* Quarter, 2009 Report was received al the DRC by its respective due date (June 1,2009). November 17.2009 Docket No. UGW09-06 Page 2 4. The DRC conducted a review of the 1" Quarter, 2009 Report to determine compliance with State Rules and Regulations and terms ofthe Permit. 5. Contrary to the requirements of Part l.E.l(a) ofthe Permit and Section 6.2.7(d)(v) ofthe DUSA QAP, DUSA failed to allow turbidity to stabilize within 10% with at least 2 samples collected before collecting groundwater samples in 17 wells during the February and March monitoring events, as shown in the table below. Groundwater Monitoring Event ]" Qir, 2009 ]"Q[r, 2009 l"Qtr,2009 ]" Qlr, 2009 l"Qtr,2009 r'Qtr,2009 1" Qlr, 2009 1" Qtr, 2009 1" Qlr. 2009 1" Qlr. 2009 1" Qir, 2009 r'Qir. 2009 1" Qtr. 2009 1" Qtr, 2009 ["Qtr. 2009 1" Qtr. 2009 March. 2009 Well MW-] '" MW-3"' MW-3A'" MW-5"' MW-M '" MW-12'" MW-14'" MW-15 "•• MW-17"' MW-23"' MW-25 "' MW-27'" MW-28"' MW-29'" MW-30'" MW-31 '" MW-32 ''' Turbidity 1.08 @ 23.1 sallons 0.7 @ 4.95 gallons 0.15 @ 6.6 gallons 0.35 @ 26.4 gallons 0.85 @ 18.15 gallons 0.69 @I8.15 gallons 0.O4 @ 19.8 gallons 0.14 @ 26.4 gallons 0.1 @ 21.45 gallons 0.23 @ 14.85 gallons 0 @ 2805 gallons 0.13 @ 29.7 gallons 0 @ 26.4 gallons 2.14^' 19.8 gallons 0 @ 24.75 gallons 0.05 @ 24.75 gallons 6.29 ©31.35 gallons Turbidity 1.22 tg'33 gallons 0.21 @ 6.6 gallons 0.2 @ 8.25 gallons 0.19 (? 36.3 gallons 0.68 @ 36.3 gallons 1.17 Co) 24.75 gallons 0.06 @ 28.05 gallons 0.1 @ 36.3 gallons 0.13 ^' 36.3 gallons 0.45 @ 19.8 gallons 0.26 @ 36.3 gallons 0.07 @ 36.3 gallons 0.09 @ 36.3 gallons 3.12 28.05 gallons 0.25 36.3 gallons 0.25 @ 36.J gallons 4.68 @ 37.95 gallons % Difference I2.96'«- -70% 33.33% -45.71% -19.99Ct> 69.56% 49.99% -28.57% 30% 95.65% CO -46.15% CO 45.79'S 00 400% -25.59% Footnotes: 1) Data for this well was 2) Data for Ihis well was obtained from Tab B ofthe 1" Quaner 2009 Groundwater Monitoring Report obtained from Tab D of the 1" Quarter 2CK)9 Groundwater Moniioring Report 6. Contrary to the requirements of Part I.E. 1(a) of the Permit and Sections 6.2.2(a) and 6.2.7(d)(v) of the DUSA QAP, DUSA failed to measure for turbidity in wells MW-14 and MW-32 during the January, 2009 monitoring event. 7. Contrary to the requirements of Part l.E.l(a) ofthe Permit and Sections 6.2.2(a) and 6.2.7(d)(v) of the DUSA QAP, DUSA failed to measure for turbidity in wells MW-20 and MW-22 during the February, 2009 monitoring event. 8. Contrary to the requirements of Part I.E. 1(a) ofthe Permit and Section 6.2.7(d)(v) ofthe DUSA QAP, DUSA failed to evacuate two casing volumes before collecting groundwater samples in 13 wells during the January, February, and March moniioring events, as shown in the table below. Groundwater Monitoring Event 1" Qtr. 2009 P'Qir. 2009 1" Qlr. 2009 1" Qtr, 2009 r'Qir. 2009 1" Qtr. 2009 Monitoring Well MW-5"' Mw-ir" MW-17'" MW-18 ^" MW-19'" MW-22'" DUSA Calculated Two Casing Volumes 41.34 51.34 45.64 81.44 128.17 61.22 DUSA Calculated Purge Rate 0.33 gpm 0.33 gpm 0.33 gpm 0.33 gpm 0.33 gpm 0.33 gpm DUSA Calculated Time to Purge Two Casing Volumes (Minutes) 125 155 138 246 383 185 Reported Time WeU Purged (Minutes) 120 120 120 120 120 120 Total Gallons Purged Before Sample Collection 39.6 39.6 39.6 39.6 39.6 39.6 November 17,2009 Docket No. UGW09-06 Paae 3 1" Qtr, 2009 I" Qlr, 2009 J "Qtr. 2009 1" Qtr, 2009 r Qtr. 2009 January. 2009 March. 2009 MW-25"' MW-27"' MW-28"' MW-31 "•' MW-32"' MW-32'" MW-32 '•^' 49.92 56.50 41.55 77.86 71.54 71.88 72.22 0.33 gpm 0.33 gpm 0.33 gpm 0.33 gpm 0.33 gpm 0.33 gpm 0.33 gpm 151 171 125 235 216 217 218 120 120 120 120 120 120 120 39.6 39.6 39.6 39.6 39.6 39.6 39.6 Footnotes: 1) Data for this well was obtained from Tab B nfthe 1'^ Quaner2009 Groundwater Moniioring Report 2) Data for Ihis well was oblained from Tab C of the 1" Quarter 2009 Groundwater Monitoring Report 3) Data for this well was oblained from Tab D of the 1"^ Quarter 2009 Groundwater Monitoring Report 9. In the V Quarter, 2009 Report, DUSA disclosed that the March, 2009 Trip Blank was lost due to an analytical equipment enor. As a result, and contrary to the requirements of Part I.E. 1(a) of the Permit and Section 9.1.3 of the DUSA QAP, DUSA failed to provide any' comparison of any March, 2009 Trip Blank results to the original sample results. D. VIOLATIONS Based on the foregoing FINDINGS OF FACT, DUSA is in violation of the following: 1. Part I.E. 1(a) of the Permit and Sections 6.2.2(a) and 6.2.7(d)(v) of the DUSA QAP for failing to measure for turbidity in wells MW-14 and MW-32 during the January, 2009 monitoring event and wells MW-20 and MW-22 during the February, 2009 monitoring event. 2. Part l.E.l(a) of the Pennit and Section 6.2.7)(d)(v) ofthe DUSA QAP for failing to achieve stable turbidity conditions before collecting groundwater samples in 17 wells during the February and March, 2009 monitoring events. 3. Part I.E. 1 (a) of the Permit and Section 6.2.7(d)(v) of the DUSA QAP for failing to excavate two casing volumes before collecting groundwater samples in 13 wells during the Januar>', February, and March 2009 monitoring events. 4. Part l.E.Ua) ofthe Permit and Section 9.1.3 ofthe DUSA QAP for failing to provide any comparison of March, 2009 Trip Blank results to original sample results for multiple volatile organic compounds. E. ORDER In view of the foregoing FINDINGS, and pursuant to Utah Code Annotated Section 19-3-108, DUSA is hereby ordered to: 1. Immediately initiate all actions necessary to achieve compliance with all applicable provisions of the Utah Water Quality Act, Ground Water Quality Rules in the Utah Administrative Code, and the Permit (including but not limited to requirements ofthe DUSA QAP.) November 17.2009 Docket No. UGW09-06 Page 4 2. Submit a report to the Co-Executive Secretary within 30 days of receipt of this NOV and Order to include but not be limited to the following items: a. The root cause of the noncompliance, b. Corrective steps taken or to be taken to prevent re-occurrence of the noncompliance, c. Date when compliance was/or will be achieved. F. NOTICE Compliance with the provisions of this NOV/CO is mandatory. Under the Division's Penalty Criteria for Civil Settlement Negotiations, Utah Administrative Code § R317-1-8, DUSA's good faith efforts to comply with this Compliance Order may impact the monetary penalty that could apply in a settlement. Providing false information may subject DUSA to further civil penalties or criminal fines. UCA § 19-5-115 provides that a violation ofthe ACT or a related order maybe subject to a civil penalty of up to $10,000 per day of violation. Under certain circumstances of willfulness or gross negligence, violators may be fined up to $25,000 per day of violation. G. CONTESTING THIS NOV/CO This NOV/CO is effective immediately and shall become final unless contested in writing within thirty (30) days after the date this NOV/CO was signed. See Utah Administrative Code § R317-9- 3(3), Any further administrative proceedings in this case shall be conducted formally under Utah Code Ann. §§ 63G4-10I through 63G-4-601. To contest this NOV/CO, you must respond in writing and must comply with the requirements of the Administrative Rules of the Water Quality Board, found at Utah Administrative Code § R317- 9 and with the requirements ofthe Utah Administrative Procedures Act, including Utah Code Ann. § 63-G-4-201(3)(a) and (b). Those provisions of the Utah Administrative Procedures Act require, among other things, that you state your factual and legal reasons for disagreeing with the Notice of Violation or Compliance Order, and that you state the action that you would like the agency to take (e.g., withdrawing the NOV/CO). A response contesting this NOV/CO must be received by the Co-Executive Secretary within 30 calendar days of receipt of this NOV/CO. (Mailing address) (Address for by-hand or overnight delivery) Dane L. Finerfrock, Co-Execuiive Secretary Dane L. Finerfrock, Co-Executive Secretary Utah Water Quality Board Utah Water Quality Board 168 North 1950 West Utah DEQ Building 2, DRC 2"^^ Floor P.O. Box 144850 168 North 1950 West Sah Lake City, UT 84114-4850 Salt Lake City UT, 84114 November 17,2009 Docket No. IIGW09-06 Page 5 You will not be allowed to contest this NOV/CO in court or in any other forum if you do not first contest the NOV/CO as described above. Signed this // day of November, 2009 UTAH WATER QUALITY BOARD dl^^^r^ Dane L. Finerfrocl Co-ExeCUtive Setfetary November 17, 2009 Docket No. UGW09-06 Page 6