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HomeMy WebLinkAboutDAQ-2024-005153 1 DAQC-160-24 Site ID 10119 (B5) MEMORANDUM TO: FILE – CHEVRON PRODUCTS COMPANY THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: February 21, 2024 SUBJECT: Chevron Products Company (Chevron), Major, NSPS, Title V, MACT, Davis County – FRS # UT00000049001100003 INSPECTION TYPE: State Electronic Data Report (SEDR) Review REVIEW DATE: February 21, 2024 SOURCE LOCATION: North Salt Lake/Davis County SOURCE CONTACT: Tony Pollock – 801-539-7162 APPLICABLE REGULATIONS: Approval Order (AO) dated 8/24/2022 – DAQE-AN101190106-22 SOURCE REVIEW EVALUATION: With the exception of sources that only monitor for opacity, quarterly report memoranda will only address the findings of the quarterly report. Approval Order and Title V permit conditions addressing continuous emission monitoring requirements will be addressed in Chevron’s relative accuracy performance specification test review memorandum. SEDR REVIEW: Fourth Quarter 2023 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation Boiler #7 2208 NOx 100% 11/06/23 08/16/23 FCC Regenerator Vent Opacity 0.00 30 % - 6min Boiler #7 2208 O2 100% 11/06/23 08/16/23 FCC Regenerator Vent Opacity 0.00 20 % - 3hrRA FCC Regenerator Vent 2208 Opacity 100% FCC Regenerator Vent SO2 0.00 50 ppm - 7dRA 1 8 2 2 Fourth Quarter 2023 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation FCC Regenerator Vent 2208 CO 97% 11/06/23 08/14/23 FCC Regenerator Vent SO2 0.00 25 ppm - 365dRA FCC Regenerator Vent 2208 NOx 97% 11/06/23 08/14/23 FCC Regenerator Vent NOx 0.00 106 ppm - 7dRA FCC Regenerator Vent 2208 SO2 97% 11/06/23 08/14/23 FCC Regenerator Vent NOx 0.00 80 ppm - 7dRA FCC Regenerator Vent 2208 CO2 97% 11/06/23 08/14/23 FCC Regenerator Vent CO 1.00 500 ppm - hour FCC Regenerator Vent 2208 O2 97% 11/06/23 08/14/23 Flare #1 H2S 0.00 162 ppm - 3hrRA Flare #1 2208 H2S 98% 11/08/23 09/21/20 Flare #2 H2S 0.00 162 ppm - 3hrRA Flare #1 2208 TRS 97% 11/08/23 Flare #3 H2S 0.00 162 ppm - 3hrRA Flare #2 2208 H2S 94% 11/08/23 09/22/20 Fuel Gas Mix Point H2S 0.00 162 ppm - 3hrRA Flare #2 2208 TRS 98% 11/09/23 Fuel Gas Mix Point H2S 0.00 60 ppm - 365dRA Flare #3 2208 H2S 99% 11/06/23 08/24/23 SRU Tailgas Incinerator 1 SO2 44.00 250 ppm - 12hrRA Flare #3 2208 TRS 100% 11/06/23 SRU Tailgas Incinerator 2 SO2 31.00 250 ppm - 12hrRA Fuel Gas Mix Point 2208 H2S 98% 11/07/23 08/25/23 SRU Tailgas Incinerator 1 2208 SO2 94% 10/09/23 08/15/23 SRU Tailgas Incinerator 1 2208 O2 91% 10/09/23 08/15/23 SRU Tailgas Incinerator 2 2208 SO2 97% 10/09/23 08/21/23 SRU Tailgas Incinerator 2 2208 O2 97% 10/09/23 08/21/23 Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit FCC Regenerator Vent Opacity 0 0 0 0 0 30 % - 6min FCC Regenerator Vent Opacity 0 0 0 0 0 20 % - 3hrRA FCC Regenerator Vent SO2 0 0 0 0 0 50 ppm - 7dRA FCC Regenerator Vent SO2 0 0 0 0 0 25 ppm - 365dRA FCC Regenerator Vent NOx 0 0 0 0 0 106 ppm - 7dRA 3 Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit FCC Regenerator Vent NOx 0 0 0 0 0 80 ppm - 7dRA FCC Regenerator Vent CO 0 0 1 0 0 500 ppm - hour Flare #1 H2S 0 0 0 0 0 162 ppm - 3hrRA Flare #2 H2S 0 0 0 0 0 162 ppm - 3hrRA Flare #3 H2S 0 0 0 0 0 162 ppm - 3hrRA Fuel Gas Mix Point H2S 0 0 0 0 0 162 ppm - 3hrRA Fuel Gas Mix Point H2S 0 0 0 0 0 60 ppm - 365dRA SRU Tailgas Incinerator 1 SO2 18 0 44 0 0 250 ppm - 12hrRA SRU Tailgas Incinerator 2 SO2 0 0 31 0 0 250 ppm - 12hrRA CMS Performance Summary - Hourly Summary Point Source Channel Monitor Malfunction Non-monitor Malfunction QA Calibrations Other Known Causes Unknown Causes Boiler #7 NOx 0 0 0 1 0 Boiler #7 O2 0 0 0 1 0 FCC Regenerator Vent Opacity 0 0 0 2 0 FCC Regenerator Vent CO 25 0 30 6 0 FCC Regenerator Vent NOx 25 0 30 6 0 FCC Regenerator Vent SO2 25 0 30 6 0 FCC Regenerator Vent CO2 25 0 30 6 0 FCC Regenerator Vent O2 25 0 30 6 0 Flare #1 H2S 31 0 23 2 0 Flare #1 TRS 63 0 6 1 0 Flare #2 H2S 66 4 34 34 0 Flare #2 TRS 0 4 5 33 0 Flare #3 H2S 0 0 23 2 0 Flare #3 TRS 0 0 0 2 0 Fuel Gas Mix Point H2S 0 0 47 2 0 SRU Tailgas Incinerator 1 SO2 56 0 24 59 0 SRU Tailgas Incinerator 1 O2 27 0 103 59 0 SRU Tailgas Incinerator 2 SO2 32 0 23 1 0 SRU Tailgas Incinerator 2 O2 32 0 23 1 0 4 Type Code 280 (COMS Attenuator Filters) Procedure 3 Point Source & Location Attenuator I.D. Attenuator Certification Date Certified Attenuator Opacity OPLR, SECR, or PLCF, Corrected Opacity Value Range Low, Mid, & High Certification 1-year or 5- year FCC Regenerator Vent - Flue Gas DHT200 / 14108330 2/21/23 12.90 0.90 22 Low 1 Year FCC Regenerator Vent - Flue Gas DHT200 / 14108330 2/21/23 24.60 0.90 39.83 Mid 1 Year FCC Regenerator Vent - Flue Gas DHT200 / 14108330 2/21/23 36.80 0.90 56.33 High 1 Year Type Code 281 (Procedure 3 - COMS Filter Audit Calibration Error) Point Source Location Audit Date Opacity Monitor Response (Average of 5) Mean Difference Calibration Error (≤ 3%) Low Mid High FCC Regenerator Vent Flue Gas Duct 10/25/23 7 0.780 1.398 FCC Regenerator Vent Flue Gas Duct 10/25/23 7 0.400 0.657 FCC Regenerator Vent Flue Gas Duct 10/25/23 7 -0.890 1.052 Pollutant Concentration Exceeded Span of CEM Monitor Outage During Point Source Operation Alternate Sampling CEM Modifications 34 Hours 1128 Hours 0 Hours 0 Events SOURCE INSPECTION SUMMARY EVALUATION: Chevron maintains its CEMS as required in R307-170 and 40 CFR 60.13. CURRENT RECOMMENDATIONS: All deviations appear to be a result of breakdown or process related problems that do not warrant issuing a violation. Chevron was in compliance during this reporting period. No further enforcement actions should be taken. Chevron’s NSPS monitoring system meets the performance standards of 40 CFR 60, Appendix B Performance Specifications. HIGH PRIORITY VIOLATOR (HPV): No RECOMMENDATION FOR NEXT INSPECTION: Check DAS for daily zero and span drift. Check the QC program to ensure that monitor drift is being tracked and that the source can identify excessive drift. ATTACHMENTS: Excel spreadsheet review Chevron Troy Tortorich Chevron Products Company Refinery Manager Salt Lake Refinery 685 South Chevron Way North Salt Lake, Utah 84054 Tel 801 539 7200 January 29, 2024 CERTIFIED MAIL RETURN RECEIPT #7018 0680 0001 4890 0321 Mr. Bryce Bird, Director Division of Air Quality Utah Department of Environmental Quality 4th QUARTER 2023 CEM REPORT - State Electronic Data Report (SEDR) Dear Mr. Bird, Chevron Products Company Salt Lake Refinery submits the Quarterly Report in ASCII Electronic Format for the 4th quarter of 2023. This is in accordance with UACR 307-170 and applicable 40 CFR 60 subparts A, J, and Ja requirements. This report contains data on the following monitoring systems: " Boiler 7 NOx.O2CEM " FCC regenerator opacity COMS " FCC regenerator CO, C02 NOx, SO2, and 0' CEM " Fuel Gas H25 CEM " Flare I H2S, TRS CEM " Flare 2 H25, TRS CEM " Flare 3 H25, TRS CEM " SRU ISO2 and O2CEM " SRU2SO2andO2CEM As per the EPA response letter attached, the approved alternative test method to the relative accuracy test for H2S CEMS has been used at Flare I and Flare 2. If you have any questions regarding the CEM Report, please contact Tony Pollock at 801-539-7162 or dltf chevron.com. I certifi under penalty of law that all information contained in the report is truthful and accurate and is a complete record of all monitoring related events which occurred during the 4th quarter of 2023. Sincerely, -VI Troy 1'ortorich Ms. Serena Yau Chevron Salt Lake Refinery 685 South Chevron Way North Salt Lake, Utah 84054 Dear Ms. Yau: I am writing in response to your letter to EPA Region 8, dated October 27, 2020, in which you seek an alternative test method for use on Flare1 and Flare 2 at Chevron’s Salt Lake Refinery (Salt Lake) located in Salt Lake City, Davis County, Utah. It is our understanding that this facility is subject to 40 CFR part 60, Subpart Ja, Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or Modification Commenced After May 14, 2007 (Subpart Ja). The Office of Air Quality Planning and Standards (OAQPS), as the delegated authority, must make the determination on any major alternatives to test methods and procedures required under 40 CFR parts 59, 60, 61, 63 and 65. Your proposed test method alternatives and our approval decisions are discussed below. According to the information provided, Flare 1 and Flare 2 at Salt Lake are subject to section 60.107a(a)(2) of Subpart Ja, which requires that a hydrogen sulfide (H2S) continuous monitoring system (CEMS) be used to comply with the emission limits found in section 60.103a(h) of Subpart Ja. Section 60.107a(a)(2) of Subpart Ja also requires an H2S CEMS be installed, operated and maintained according to 40 CFR part 60, appendix B, Performance Specification 7 (PS-7), and the use of Method 11, 15, or 15A of Appendix A-5 to 40 CFR part 60 or Method 16 of Appendix A-6 to 40 CFR part 60 for conducting the relative accuracy test. Following section 60.107a(a)(2), you are required to comply with the applicable quality assurance procedures in Appendix F to 40 CFR part 60, specifically Procedure 1 (40 CFR 60, Appendix F), which requires the annual relative accuracy test of each H2S CEMS. Based on the information you provided, Flare 1 and Flare 2 are both equipped with a flare vapor recovery (FVR) system. These FVR systems employ a water seal to prevent flaring, unless there is sufficient pressure on the seal for flare gas to break through. The vapors that do not break through the water seal are compressed and recovered. The FVR system prevents flaring the vast majority of the time. The H2S CEMS are located downstream of these water seals which means that when these water seals are intact, which is typical, there is no flare gas being sampled by the H2S CEMS. This intermittent flaring makes conducting a relative accuracy test on an H2S CEMS on Flare 1 and Flare 2 difficult. As a result of the difficulty associated with conducting a relative 1/12/2021 2 accuracy test on these H2S CEMSs, you seek to use the alternative relative accuracy procedure provided in section 16.2 of 40 CFR part 60, Appendix B, Performance Specification 2 (PS-2) and referenced as an alternative to the relative accuracy test in sections 60.107a(e)(1)(ii) and (2)(ii) of Subpart Ja. The alternative procedure requested allows for the completion of the alternative relative accuracy procedures found in section 16.0 of PS-2 in lieu of the relative accuracy test procedures for an H2S CEMS specified in PS-7. We have reviewed your request and the associated rule language and recognize that it can be difficult to perform relative accuracy tests of the H2S CEMSs installed on these units that do not consistently combust flare gas. Based on the information contained in your request on the intermittent flare gas flows, we approve the use of the alternative testing approach found in section 16.0 of PS-2, which allows cylinder gases to be used as an alternative to the relative accuracy test for H2S CEMSs, with the following caveats for each test: • This alternative test method is only approved for use on the two H2S CEMSs installed on Flare 1 and Flare 2 at Chevron’s Salt Lake Refinery. • The alternative relative accuracy procedures approved herein are an alternative to the relative accuracy test required by PS-7 and Procedure 1. • When conducting the alternative relative accuracy test, you must follow the procedures for performing the alternative relative accuracy test described in section 16.2 of PS-2 and meet the criteria specified in section 16.3 of PS-2. • The gas quality for the cylinder gases used to conduct the alternative relative accuracy tests must meet the Protocol Gas requirements defined in section 16.2.4 of PS-2, to an accuracy of at least 3 percent, or the cylinder gas material must be vendor certified as traceable to a NIST standard at 3 percent accuracy if Protocol Gases are not available at the concentration necessary for the alternative relative accuracy test. • The alternative relative accuracy procedures must be performed periodically as defined in section 60.107a(a)(1)(v) of Subpart Ja. • A copy of this approval letter must be included in the report detailing the results of the alternative relative accuracy procedures. If you have any questions regarding this determination, please contact Kim Garnett at 919-541- 1158 or garnett.kim@epa.go v. Sincerely, Steffan M. Johnson, Leader Measurement Technology Group STEFFAN JOHNSON Digitally signed by STEFFAN JOHNSON Date: 2021.01.12 08:43:07 -05'00' 3 cc: Rachel Agnew, Chevron (rachelagnew@chevron.com) Kim Garnett, EPA/OAQPS/AQAD (garnett.kim@epa.gov) Jeremy Marsigli, Utah DEQ (jmarsigli@utah.gov) Laurie Ostrand, EPA R8 (ostrand.laurie@epa.gov) Brenda Shine, EPA/OAQPS/SPPD (shine.brenda@epa.gov) Chevron Refinery EER 4Q2023 Point Source Information Late Expired Cal. Gas Valid Cal. Gas Days Yes No 1 Type Code 100 (Company Information)Type Code Company Manager Company Name AIRS # Phone Number Environmental Contact 1 100 Troy Tortorich 01100003 (801) 539-7162 Tony Pollock 1 100 0 0 0 0 1 Type Code 110 (Point Source Identification)Type Code Point Source Quarter 1 - 4 Year Point Source Operating Hrs. in Quarter 1 110 4 2023 2208 1 110 4 2023 2208 1 110 4 2023 2208 1 110 4 2023 2208 1 110 4 2023 2208 1 110 4 2023 2208 1 110 4 2023 2208 1 110 4 2023 2208 1 110 0 0 0 1 Type Code 200 (Monitor Identification)Type Code Point Source Channel Manufacturer Model No. Monitor SN Low Span High Span Installation Date Monitor Location 1 200 NOx Ametek Western Research9900 ZE-9900-10941-1 0 500 8/17/2018 F11007 1 200 O2 Ametek Western Research9900 ZE-9900-10941-1 0 21 8/17/2018 F11007 1 200 CO Siemens Ultramat 6 J6-783 0 1000 4/16/2020 K3223 1 200 CO2 Siemens Ultramat 6/Oxymat 6J7-447 0 25 4/16/2020 K3223 1 200 NOx Ametek Western Research9900 ZW-9900-S1334-10 200 4/16/2020 K3223 1 200 O2 Siemens Ultramat 6/Oxymat 6J7-447 0 10 4/16/2020 K3223 1 200 Opacity Sick/Maihak DHT200 0 100 10/5/2013 K3223 1 200 SO2 Siemens Ultramat 6E J6-783 0 200 4/16/2020 K3223 1 200 H2S Siemens Maxum Edition II #300194969000100 300 2/3/2010 V75220 1 200 TRS Atom FGA-100 140011 0 250000 11/5/2015 V75220 1 200 H2S Siemens Maxum Edition II #300194969000200 300 11/5/2010 V75120 1 200 TRS Atom FGA-100 140012 0 250000 11/4/2015 V75120 1 200 H2S Siemens Maxum Edition II #3001946900020 0 300 11/6/2019 D35014 1 200 TRS Atom FGA-100 18002 0 250000 11/6/2019 D35014 1 200 H2S Siemens Maxum Edition II #300195363800100 300 12/6/2009 V-113 1 200 O2 Ametek Ametek 9900 ZW-9900-S1332-10 21 9/1/2021 F-6550 1 200 SO2 Ametek Ametek 9900 ZW-9900-S1332-10 500 9/1/2021 F-6550 1 200 O2 Ametek Ametek 9000 AV9000WM-10235-1A0 21 12/16/2010 F-68250 1 200 SO2 Ametek Ametek 9000 AV9000WM-10235-1A0 500 12/16/2010 F-68250 1 200 0 0 0 0 0 0 1/0/1900 0 1 Type Code310 (Excess Emissions) SUMMARY REPORT Type Code Channel Total Hours of Excess Emissions Excess Emissions - % of Total Operating Hours RC 701 Hours - start up/Shutdown RC 702 Hours- Control Equipment Problems RC 703 Hours - Process Problems RC 704, 706, 707 Hours -Other Known Causes RC 705 Hours - Unknown Causes Emission Limitation Emission Limitation Units Emission Limitation Averaging Period 1 TRUE 310 Opacity 0 0.00% 0 0 0 0 0 30 % 6min 1 TRUE 310 Opacity 0 0.00% 0 0 0 0 0 20 % 3hrRA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 50 ppm 7dRA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 25 ppm 365dRA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 106 ppm 7dRA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 80 ppm 7dRA 1 TRUE 310 CO 1 0.05% 0 0 1 0 0 500 ppm hour 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 162 ppm 3hrRA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 162 ppm 3hrRA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 162 ppm 3hrRA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 162 ppm 3hrRA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 60 ppm 365dRA 1 TRUE 310 SO2 62 2.81% 18 0 44 0 0 250 ppm 12hrRA 1 TRUE 310 SO2 31 1.40% 0 0 31 0 0 250 ppm 12hrRA 1 310 0 0 0 0 0 0 0 0 0 Point Source SRU Tailgas Incinerator 2 0 SRU Tailgas Incinerator 2 Boiler #7 FCC Regenerator Vent Flare #1 Flare #2 Flare #3 Fuel Gas Mix Point SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 0 SRU Tailgas Incinerator 1 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Fuel Gas Mix Point Fuel Gas Mix Point Flare #2 Flare #3 Flare #3 Fuel Gas Mix Point SRU Tailgas Incinerator 1 Chevron Products Co. 0 Boiler #7 Boiler #7 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Flare #1 Flare #1 Flare #2 FCC Regenerator Vent FCC Regenerator Vent Flare #1 Flare #2 Flare #3 FCC Regenerator Vent FCC Regenerator Vent SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 0 Chevron Refinery EER 4Q2023 1 Type Code 300 (CMS Performance Summary) Type Code Channel Point Source Operating Hours Downtime - % of Total Operating Hours Total CMS Downtime RC 721 Hours - Monitor Malfunction RC 722 Hours - Non-monitor Malfunction RC 723 Hours - QA Calibrations RC 724 Hours - Other Known Causes RC 725 Hours - Unknown Causes 1 TRUE 300 NOx 2208 0.05% 1 0 0 0 1 0 1 TRUE 300 O2 2208 0.05% 1 0 0 0 1 0 1 TRUE 300 Opacity 2208 0.10% 2.2 0 0 0 2.2 0 1 TRUE 300 CO 2208 2.77% 61.25 25.25 0 29.75 6.25 0 1 TRUE 300 NOx 2208 2.77% 61.25 25.25 0 29.75 6.25 0 1 TRUE 300 SO2 2208 2.77% 61.25 25.25 0 29.75 6.25 0 1 TRUE 300 CO2 2208 2.77% 61.25 25.25 0 29.75 6.25 0 1 TRUE 300 O2 2208 2.77% 61.25 25.25 0 29.75 6.25 0 1 TRUE 300 H2S 2208 2.48% 54.75 30.5 0 22.75 1.5 0 1 TRUE 300 TRS 2208 3.16% 69.75 62.5 0 6 1.25 0 1 TRUE 300 H2S 2208 6.22% 137.25 66.25 3.5 34 33.5 0 1 TRUE 300 TRS 2208 1.90% 42 0 3.5 5.25 33.25 0 1 TRUE 300 H2S 2208 1.10% 24.25 0 0 22.75 1.5 0 1 TRUE 300 TRS 2208 0.07% 1.5 0 0 0 1.5 0 1 TRUE 300 H2S 2208 2.21% 48.75 0 0 46.75 2 0 1 TRUE 300 SO2 2208 6.27% 138.5 56.25 0 23.75 58.5 0 1 TRUE 300 O2 2208 8.57% 189.25 27 0 103 59.25 0 1 TRUE 300 SO2 2208 2.52% 55.75 31.75 0 23 1 0 1 TRUE 300 O2 2208 2.52% 55.75 31.75 0 23 1 0 1 300 0 0 0 0 0 0 1 Type Code 250 (Performance Specification RATA Results) Type Code Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units of Measurement CEM Value Reference Method Value Relative accuracy Pass/ Fail 1 365 Days 250 NOx 08/16/23 08/16/22 12 ppm 0.074 0.075 2.25% P 1 365 Days 250 O2 08/16/23 08/16/22 12 0 4.826 4.828 0.33% P 1 325 Days 250 SO2 08/14/23 09/23/22 12 ppm 16.9 15.667 9.07% P 1 326 Days 250 NOx 08/14/23 09/22/22 12 ppm 41.532 42.389 3.51% P 1 326 Days 250 CO 08/14/23 09/22/22 12 ppm 26.918 26.433 2.06% P 1 326 Days 250 CO2 08/14/23 09/22/22 12 ppm 17.28 16.978 1.93% P 1 326 Days 250 O2 08/14/23 09/22/22 12 0 2.12 2.12 1.31% P 1 0 Days 250 H2S 09/21/20 09/21/20 12 ppm 8.9 5.81 3.30% P 1 0 Days 250 H2S 09/22/20 09/22/20 12 ppm 8.29 5.39 2.93% P 1 373 Days 250 H2S 08/24/23 08/16/22 12 ppm 0 2.26 1.60% P 1 374 Days 250 H2S 08/25/23 08/16/22 12 ppm 0.04 1.95 1.25% P 1 364 Days 250 SO2 08/15/23 08/16/22 12 ppm 107.369 114.978 7.91% P 1 364 Days 250 SO2 08/15/23 08/16/22 12 lb./hr. 1.743 1.992 3.10% P 1 364 Days 250 O2 08/15/23 08/16/22 12 0 4.084 4.133 5.00% P 1 334 Days 250 SO2 08/21/23 09/21/22 12 ppm 132.091 135.895 5.82% P 1 334 Days 250 SO2 08/21/23 09/21/22 12 lb./hr. 3.251 3.407 10.41% P 1 334 Days 250 O2 08/21/23 09/21/22 12 0 7.17 7.844 3.00% P 1 0 Days 250 0 01/00/00 01/00/00 0 0 0 0 0.00% 0 1 Type Code 260 (CGA Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units of Measurement CEM Value Cylinder Value Precision %Pass/ Fail Range - High or Low 1 Valid Cal. Gas 260 NOx 11/06/23 1 AAL073503 08/02/29 EPA Traceability Protocol (Sept. 1997)ppm 135.4 137.6 -167.00% P Low 1 Valid Cal. Gas 260 NOx 11/06/23 2 CC97975 10/29/26 EPA Traceability Protocol (Sept. 1997)ppm 272.4 276.1 -132.00% P High 1 Valid Cal. Gas 260 O2 11/06/23 1 XC014765 05/01/26 EPA Traceability Protocol (Sept. 1997)ppm 5.1 5.1 34.00% P High 1 Valid Cal. Gas 260 O2 11/06/23 2 CC506900 05/22/26 EPA Traceability Protocol (Sept. 1997)ppm 8.1 8.1 -45.00% P High 1 Valid Cal. Gas 260 CO 11/06/23 1 CC92361 04/27/28 EPA Traceability Protocol (Sept. 1997)ppm 249.1 249 -240.00% P Low 1 Valid Cal. Gas 260 CO 11/06/23 2 ALM011670 02/26/27 EPA Traceability Protocol (Sept. 1997)ppm 545.5 546.6 -120.00% P High 1 Valid Cal. Gas 260 CO2 11/06/23 1 CC232281 02/24/28 EPA Traceability Protocol (Sept. 1997)ppm 6.5 6.6 -105.00% P Low 1 Valid Cal. Gas 260 CO2 11/06/23 2 CC487479 03/02/28 EPA Traceability Protocol (Sept. 1997)ppm 13.9 14 -40.00% P High 1 Valid Cal. Gas 260 NOx 11/06/23 1 CC320573 01/03/31 EPA Traceability Protocol (Sept. 1997)ppm 55.5 55.8 -47.00% P Low 1 Valid Cal. Gas 260 NOx 11/06/23 2 CC262317 10/15/26 EPA Traceability Protocol (Sept. 1997)ppm 111 111.1 -9.00% P High 1 Valid Cal. Gas 260 O2 11/06/23 1 EB0109000 08/17/26 EPA Traceability Protocol (Sept. 1997)% 5 5 0.00% P Low 1 Valid Cal. Gas 260 O2 11/06/23 2 CC504376 03/01/27 EPA Traceability Protocol (Sept. 1997)% 8.1 8 50.00% P High 1 Valid Cal. Gas 260 SO2 11/06/23 1 CC733445 08/22/30 EPA Traceability Protocol (Sept. 1997)ppm 55.9 55.08 145.00% P Low 1 Valid Cal. Gas 260 SO2 11/06/23 2 SG914942BAL 08/02/29 EPA Traceability Protocol (Sept. 1997)ppm 112.1 110.1 184.00% P High 1 Valid Cal. Gas 260 H2S 11/08/23 1 CC102694 10/12/24 EPA PROTOCOL II GASppm 67.3 68.99 -245.00% P Low 1 Valid Cal. Gas 260 H2S 11/8/23 2 ALM035540 10/14/24 EPA PROTOCOL II GASppm 145 157 -8 P High 1 Valid Cal. Gas 260 TRS 11/8/23 1 CC97784 12/16/24 EPA PROTOCOL II GASppm 12,276 12,526 -2 P Low 1 Valid Cal. Gas 260 TRS 11/8/23 2 EB0140133 9/21/25 EPA PROTOCOL II GASppm 26,156 27,571 -5 P High 1 Valid Cal. Gas 260 H2S 11/8/23 1 ALM040013 6/30/24 EPA PROTOCOL II GASppm 66 70 -5 P Low 1 Valid Cal. Gas 260 H2S 11/8/23 2 CC192822 6/9/26 EPA PROTOCOL II GASppm 147 159 -7 P High 1 Valid Cal. Gas 260 TRS 11/9/23 1 CC66003 12/26/24 EPA PROTOCOL II GASppm 12,392 12,533 -1 P Low 1 Valid Cal. Gas 260 TRS 11/9/23 2 EB0140133 9/21/25 EPA PROTOCOL II GASppm 27,446 27,571 0 P High 1 Valid Cal. Gas 260 H2S 11/6/23 1 ALM042146 5/28/26 EPA PROTOCOL II GASppm 67 70 -5 P Low 1 Valid Cal. Gas 260 H2S 11/6/23 2 CC192822 5/28/26 EPA PROTOCOL II GASppm 146 157 -7 P High 1 Valid Cal. Gas 260 TRS 11/6/23 1 CC231302 4/26/25 EPA PROTOCOL II GASppm 2,434 2,491 -2 P Low 1 Valid Cal. Gas 260 TRS 11/6/23 2 CC260070 12/17/24 EPA PROTOCOL II GASppm 5,493 5,553 -1 P High 1 Valid Cal. Gas 260 H2S 11/7/23 1 ALM032841 3/8/24 EPA Traceability Protocol (Sept. 1997)ppm 68 70 -3 P Low 1 Valid Cal. Gas 260 H2S 11/7/23 2 CC47722 3/9/24 EPA Traceability Protocol (Sept. 1997)ppm 156 162 -4 P High 1 Valid Cal. Gas 260 O2 10/9/23 1 ALM054666 4/26/27 EPA Traceability Protocol (Sept. 1997)ppm 5 5 -1 P Low 1 Valid Cal. Gas 260 O2 10/9/23 2 EB0089076 8/7/28 EPA Traceability Protocol (Sept. 1997)ppm 8 8 -2 P High 1 Valid Cal. Gas 260 SO2 10/9/23 1 CC107467 8/29/30 EPA Traceability Protocol (Sept. 1997)ppm 130 126 3 P Low 1 Valid Cal. Gas 260 SO2 10/9/23 2 EB0134129 11/22/29 EPA Traceability Protocol (Sept. 1997)ppm 252 252 0 P High 1 Valid Cal. Gas 260 O2 10/9/23 1 ALM054666 5/31/30 EPA Traceability Protocol (Sept. 1997)ppm 5 5 0 P Low 1 Valid Cal. Gas 260 O2 10/9/23 2 CC741651 8/23/29 EPA Traceability Protocol (Sept. 1997)ppm 8 8 0 P High 1 Valid Cal. Gas 260 SO2 10/9/23 1 CC356043 11/1/27 EPA Traceability Protocol (Sept. 1997)ppm 134 123 9 P Low 1 Valid Cal. Gas 260 SO2 10/9/23 2 ALM047181 2/1/27 EPA Traceability Protocol (Sept. 1997)ppm 247 250 -1 P High 1 260 0 1/0/00 0 0 1/0/00 0 0 0 0 0 0 0 1 Type Code 270 (Linearity Test Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units of Measurement CEM Value Cylinder Value Precision %Pass/ Fail Range - High or Low 1 270 0 01/00/00 0 0 01/00/00 0 0 0 0 0.00% 0 0 Point Source Point Source Point Source Point Source FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Flare #1 Flare #1 Flare #1 Flare #2 SRU Tailgas Incinerator 2 FCC Regenerator Vent Flare #1 Flare #2 Flare #3 Fuel Gas Mix Point Boiler #7 Boiler #7 SRU Tailgas Incinerator 2 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Boiler #7 Boiler #7 FCC Regenerator Vent Flare #3 Flare #1 Flare #1 Flare #2 Flare #2 Flare #3 Fuel Gas Mix Point SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 0 Boiler #7 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Boiler #7 0 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 0 Flare #3 Flare #3 Fuel Gas Mix Point Fuel Gas Mix Point SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 Boiler #7 Boiler #7 Flare #3 Flare #3 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Flare #2 Flare #2 Flare #2 Flare #1 0 Chevron Refinery EER 4Q2023 1 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code Channel Start Date Start Time End Date End Time Hours 1 34 210 H2S 11/13/23 15:31 11/13/23 15:31 0.00 1 34 210 H2S 11/13/23 15:43 11/13/23 15:43 0.00 1 68 210 H2S 10/12/23 2:43 10/12/23 2:46 0.05 1 TRUE 210 H2S 10/12/23 3:21 10/12/23 3:28 0.12 1 210 H2S 10/12/23 13:53 10/12/23 13:58 0.08 1 210 H2S 10/12/23 14:09 10/12/23 14:13 0.07 1 210 H2S 10/12/23 14:20 10/12/23 14:36 0.27 1 210 H2S 10/12/23 15:43 10/12/23 15:50 0.12 1 210 H2S 10/18/23 14:17 10/18/23 14:43 0.43 1 210 H2S 11/13/23 15:23 11/13/23 15:31 0.13 1 210 H2S 11/13/23 15:34 11/13/23 15:38 0.07 1 210 H2S 11/13/23 15:41 11/13/23 15:46 0.08 1 210 H2S 11/28/23 10:04 11/28/23 10:08 0.07 1 210 H2S 11/28/23 10:23 11/28/23 10:46 0.38 1 210 H2S 12/17/23 23:17 12/17/23 23:21 0.07 1 210 H2S 12/17/23 23:40 12/17/23 23:59 0.32 1 210 H2S 12/25/23 3:19 12/25/23 3:28 0.15 1 210 H2S 11/13/23 13:30 11/13/23 14:57 1.45 1 210 SO2 11/14/23 10:15 11/14/23 10:59 0.73 1 210 SO2 11/16/23 4:52 11/16/23 4:55 0.05 1 210 SO2 11/16/23 5:00 11/16/23 5:06 0.10 1 210 SO2 11/16/23 5:07 11/16/23 5:46 0.65 1 210 SO2 11/16/23 6:58 11/16/23 7:02 0.07 1 210 SO2 11/16/23 8:16 11/16/23 15:55 7.65 1 210 SO2 11/21/23 2:53 11/21/23 3:12 0.32 1 210 SO2 11/21/23 3:27 11/21/23 4:05 0.63 1 210 SO2 11/21/23 4:36 11/21/23 5:04 0.47 1 210 SO2 11/21/23 12:15 11/21/23 12:30 0.25 1 210 SO2 11/21/23 12:41 11/21/23 12:56 0.25 1 210 SO2 11/21/23 13:20 11/21/23 14:20 1.00 1 210 SO2 11/21/23 23:38 11/21/23 23:49 0.18 1 210 SO2 11/21/23 23:51 11/21/23 23:55 0.07 1 210 SO2 11/21/23 23:57 11/22/23 0:01 0.07 1 210 SO2 11/22/23 0:04 11/22/23 0:12 0.13 1 210 SO2 11/22/23 0:13 11/22/23 0:37 0.40 1 210 SO2 11/22/23 0:39 11/22/23 0:46 0.12 1 210 SO2 11/22/23 1:17 11/22/23 1:29 0.20 1 210 SO2 11/22/23 1:33 11/22/23 1:36 0.05 1 210 SO2 11/22/23 1:40 11/22/23 1:45 0.08 1 210 SO2 11/22/23 1:46 11/22/23 2:09 0.38 1 210 SO2 11/22/23 2:13 11/22/23 5:46 3.55 1 210 SO2 11/22/23 12:06 11/22/23 21:58 9.87 1 210 SO2 11/22/23 22:24 11/22/23 22:28 0.07 1 210 SO2 11/22/23 22:32 11/22/23 22:46 0.23 1 210 SO2 10/16/23 16:48 10/16/23 16:58 0.17 1 210 SO2 10/20/23 11:37 10/20/23 11:40 0.05 1 210 SO2 10/29/23 12:07 10/29/23 12:12 0.08 1 210 SO2 10/29/23 16:58 10/29/23 17:01 0.05 1 210 SO2 11/13/23 15:22 11/13/23 16:01 0.65 1 210 SO2 11/15/23 13:43 11/15/23 13:49 0.10 1 210 SO2 11/16/23 1:58 11/16/23 2:02 0.07 1 210 SO2 11/21/23 4:19 11/21/23 4:27 0.13 1 210 SO2 11/21/23 7:22 11/21/23 7:42 0.33 1 210 SO2 11/21/23 8:09 11/21/23 8:39 0.50 1 210 SO2 11/21/23 8:44 11/21/23 8:51 0.12 1 210 SO2 11/26/23 23:12 11/26/23 23:16 0.07 1 210 SO2 12/12/23 19:29 12/12/23 19:32 0.05 1 210 0 1/0/00 0:00 1/0/00 0:00 1 1 Yes 1 33.78 TC 220 Hours 1127.95 TC 220 Hours 0.00 TC 230 Hours 0.00 Events 0.00 Hours 0.00 Events 0.00 0.00 1 1127.95 TC 300 Hours 0.00 TRUE None Reported None Reported None Reported None Reported None Reported None Reported Point Source Yes Flare #2 Flare #2 Type Code 550 (Changes in Operation in Control Equipment When CEM Data Not Available) Type Code 500 (Boiler Operating Days w/o 18 Hours of Data) Type Code 450 (Data Excluded) Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code 220 (Monitor Outage During Point Source Operation) Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) Type Code 240 (CEM Modifications) Type Code 530 (Excess Emissions During Emergency Conditions) Flare #2 Flare #2 Flare #2 Flare #2 Flare #3 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #1 Flare #1 Flare #2 Flare #2 Flare #2 Flare #2 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 0 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 Chevron Refinery EER 4Q2023 Relative Accuracy Overview Point Source Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units Measured CEM Value Reference Method Value Relative Accuracy Pass/ Fail Boiler #7 NOx 08/16/23 08/16/22 12 ppm 0.074 0.08 2.25% P Boiler #7 O2 08/16/23 08/16/22 12 4.826 4.83 0.33% P FCC Regenerator Vent SO2 08/14/23 09/23/22 12 ppm 16.9 15.67 9.07% P FCC Regenerator Vent NOx 08/14/23 09/22/22 12 ppm 41.532 42.39 3.51% P FCC Regenerator Vent CO 08/14/23 09/22/22 12 ppm 26.918 26.43 2.06% P FCC Regenerator Vent CO2 08/14/23 09/22/22 12 ppm 17.28 16.98 1.93% P FCC Regenerator Vent O2 08/14/23 09/22/22 12 2.12 2.12 1.31% P Flare #1 H2S 09/21/20 09/21/20 12 ppm 8.9 5.81 3.30% P Flare #2 H2S 09/22/20 09/22/20 12 ppm 8.29 5.39 2.93% P Flare #3 H2S 08/24/23 08/16/22 12 ppm 0 2.26 1.60% P Fuel Gas Mix Point H2S 08/25/23 08/16/22 12 ppm 0.04 1.95 1.25% P SRU Tailgas Incinerator 1 SO2 08/15/23 08/16/22 12 ppm 107.369 114.98 7.91% P SRU Tailgas Incinerator 1 SO2 08/15/23 08/16/22 12 lb./hr. 1.743 1.99 3.10% P SRU Tailgas Incinerator 1 O2 08/15/23 08/16/22 12 4.084 4.13 5.00% P SRU Tailgas Incinerator 2 SO2 08/21/23 09/21/22 12 ppm 132.091 135.90 5.82% P SRU Tailgas Incinerator 2 SO2 08/21/23 09/21/22 12 lb./hr. 3.251 3.41 10.41% P SRU Tailgas Incinerator 2 O2 08/21/23 09/21/22 12 7.17 7.84 3.00% P * NSPS CGA Fourth 2023 Audit Gas Ranges Audit Gas Ranges AP1 Low AP2 Low AP1 High AP2 High Boiler #7 NOx 11/6/23 500 137.6 100 to 150 Boiler #7 NOx 11/6/23 500 276.1 250 to 300 Boiler #7 O2 11/6/23 21 5.1 4 to 6 Boiler #7 O2 11/6/23 21 8.1 8 to 12 FCC Regenerator Vent CO 11/6/23 1000 249 200 to 300 FCC Regenerator Vent CO 11/6/23 1000 546.6 500 to 600 FCC Regenerator Vent CO2 11/6/23 25 6.6 5 to 8 FCC Regenerator Vent CO2 11/6/23 25 14 10 to 14 FCC Regenerator Vent NOx 11/6/23 200 55.8 40 to 60 FCC Regenerator Vent NOx 11/6/23 200 111.1 100 to 120 FCC Regenerator Vent O2 11/6/23 10 5 4 to 6 FCC Regenerator Vent O2 11/6/23 10 8 8 to 12 FCC Regenerator Vent SO2 11/6/23 200 55.08 40 to 60 FCC Regenerator Vent SO2 11/6/23 200 110.1 100 to 120 Flare #1 H2S 11/8/23 300 68.99 60 to 90 Flare #1 H2S 11/8/23 300 156.9 150 to 180 Flare #1 TRS 11/8/23 250000 12526 50000 to 75000 Flare #1 TRS 11/8/23 250000 27571 125000 to 150000 Flare #2 H2S 11/8/23 300 69.7 60 to 90 Flare #2 H2S 11/8/23 300 158.8 150 to 180 Flare #2 TRS 11/9/23 250000 12533 50000 to 75000 Flare #2 TRS 11/9/23 250000 27571 125000 to 150000 Flare #3 H2S 11/6/23 300 70.46 60 to 90 Flare #3 H2S 11/6/23 300 157.1 150 to 180 Flare #3 TRS 11/6/23 250000 2491 50000 to 75000 Flare #3 TRS 11/6/23 250000 5553 125000 to 150000 Fuel Gas Mix Point H2S 11/7/23 300 70.36 60 to 90 Fuel Gas Mix Point H2S 11/7/23 300 161.6 150 to 180 SRU Tailgas Incinerator 1 O2 10/9/23 21 5.09 4 to 6 SRU Tailgas Incinerator 1 O2 10/9/23 21 8.05 8 to 12 SRU Tailgas Incinerator 1 SO2 10/9/23 500 125.7 100 to 150 SRU Tailgas Incinerator 1 SO2 10/9/23 500 251.6 250 to 300 SRU Tailgas Incinerator 2 O2 10/9/23 21 5.04 4 to 6 SRU Tailgas Incinerator 2 O2 10/9/23 21 7.97 8 to 12 SRU Tailgas Incinerator 2 SO2 10/9/23 500 123.2 100 to 150 SRU Tailgas Incinerator 2 SO2 10/9/23 500 249.5 250 to 300 * Type Code 280 (COMS Attenuator Filters) Procedure 3 Point Source Location Attenuator I.D. Attenuator Certification Date Certified Attenuator Opacity OPLR, SECR, or PLCF, Corrected Opacity Value Range Low, Mid, & High Certification 1-year or 5-year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 2/21/23 13 0.8996 22 Low 1 Year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 2/21/23 25 0.8996 39.83 Mid 1 Year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 2/21/23 37 0.8996 56.33 High 1 Year * Opacity Monitor Response (Average of 5) Low Range Mid Range High Range FCC Regenerator Vent Flue Gas Duct 10/25/23 7 0.780 0.002 0.006 1.398 FCC Regenerator Vent Flue Gas Duct 10/25/23 7 0.400 0.004 0.003 0.657 FCC Regenerator Vent Flue Gas Duct 10/25/23 7 -0.890 0.006 0.002 1.052 Point Source Location Audit Date Mean Difference Standard Deviation Confidence Coefficient Calibration Error (≤ 3%) Type Code 281 (Procedure 3 - COMS Filter Audit Calibration Error) Point Source Channel Audit Date Low Span Audit Gas Used High Span Audit Gas Used Chevron Refinery EER 4Q2023 Monitoring Information TC 210, 230, & 240 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) H2S SO2 Grand Total (blank)0 0 Flare #1 0 0 Flare #2 2.4 2.4 Flare #3 1.45 1.45 SRU Tailgas Incinerator 1 27.57 27.57 SRU Tailgas Incinerator 2 2.37 2.37 Grand Total 0 3.85 29.93 33.78 * Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 240 (CEM Modifications) - 100 (All) * Count of Channel Column Labels Row Labels (blank) Grand Total (blank) (blank) Grand Total Chevron Refinery EER 4Q2023 Type Code 220 (Monitor Outage During Point Source Operation) - 600 (All) * Sum of Hours Column Labels Row Labels 724 723 721 722 Grand Total FCC Regenerator Vent Opacity Quarterly Audit 2.20 2.20 CO Quarterly Audit 4.50 4.50 Daily Validation 29.25 29.25 Routine checks found system had low flow, cleared any plugging. 1.75 1.75 Cleaned sample box and probe. Replaced ammonia scrubbers, filter and coalescing filter. 0.50 0.50 Cal Drift Due to sample system plugging 24.75 24.75 NOx Analyzer in fault. Repaired, calibrated and validated.0.50 0.50 CO2 Quarterly Audit 4.50 4.50 Daily Validation 29.25 29.25 Routine checks found system had low flow, cleared any plugging. 1.75 1.75 Cleaned sample box and probe. Replaced ammonia scrubbers, filter and coalescing filter. 0.50 0.50 Cal Drift Due to sample system plugging 24.75 24.75 NOx Analyzer in fault. Repaired, calibrated and validated.0.50 0.50 NOx Quarterly Audit 4.50 4.50 Daily Validation 29.25 29.25 Routine checks found system had low flow, cleared any plugging. 1.75 1.75 Cleaned sample box and probe. Replaced ammonia scrubbers, filter and coalescing filter. 0.50 0.50 Cal Drift Due to sample system plugging 24.75 24.75 NOx Analyzer in fault. Repaired, calibrated and validated.0.50 0.50 SO2 Quarterly Audit 4.50 4.50 Daily Validation 29.25 29.25 Routine checks found system had low flow, cleared any plugging. 1.75 1.75 Cleaned sample box and probe. Replaced ammonia scrubbers, filter and coalescing filter. 0.50 0.50 Cal Drift Due to sample system plugging 24.75 24.75 NOx Analyzer in fault. Repaired, calibrated and validated.0.50 0.50 O2 Quarterly Audit 4.50 4.50 Daily Validation 29.25 29.25 Routine checks found system had low flow, cleared any plugging. 1.75 1.75 Cleaned sample box and probe. Replaced ammonia scrubbers, filter and coalescing filter. 0.50 0.50 Cal Drift Due to sample system plugging 24.75 24.75 NOx Analyzer in fault. Repaired, calibrated and validated.0.50 0.50 Flare #1 H2S Quarterly Audit 1.50 1.50 Daily Validation 22.75 22.75 Loss of communication between analyzer and DCS. Restarted analyzer. Reran Validation 30.50 30.50 TRS Quarterly Audit 1.25 1.25 Loss of communication between analyzer and DCS. Restarted analyzer. Reran Validation 31.50 31.50 Analyzer cal drift, replaced excimer envelope and revalidated 0.75 0.75 Replaced filter, millivolts dropped which was fixed by replacing the excimer envelope. 6.00 6.00 Analyzer cal drift, replaced detector assembly. Recalibrated and validated. 2.25 2.25 Validation drift caused by communication error, reset system and reran validation.28.00 28.00 Flare #2 H2S Quarterly Audit 3.50 3.50 Daily Validation 28.75 28.75 Validation drift caused by carrier gas leaking out. Pressure checked system, bottle appeared to be leaking. Replaced H2 bottles. 35.25 35.25 Misc. Cal Drift 0.50 0.50 Sample drier not holding temperature. Replaced air heater in sample box. 5.25 5.25 CEMS fuse failed. Replaced fuse, rebooted analyzer and reenabled daily validation. 28.75 28.75 Analyzer offline for shared CGA 1.25 1.25 High value on H2S validation failed, placed analyzer in hold and adjusted Chromes on GC. Revalidated and passed. 30.50 30.50 Loss of power to CEMS which caused loss of signal. 3.50 3.50 Chevron Refinery EER 4Q2023 Sum of Hours Column Labels Row Labels 724 723 721 722 Grand Total TRS Sample drier not holding temperature. Replaced air heater in sample box. 5.25 5.25 CEMS fuse failed. Replaced fuse, rebooted analyzer and reenabled daily validation. 28.75 28.75 Analyzer offline for shared CGA 1.25 1.25 Loss of power to CEMS which caused loss of signal. 3.50 3.50 Attempted CGA, but had HMI issues. Had to try a CGA on the next day. 3.25 3.25 Flare #3 H2S Quarterly Audit 1.50 1.50 Daily Validation 22.75 22.75 TRS Quarterly Audit 1.50 1.50 Fuel Gas Mix Point H2S Quarterly Audit 2.00 2.00 Daily Validation 45.50 45.50 Calibrate/Revalidate 0.50 0.50 Analyzer had air leak. Turned off air briefly which caused down-time status to come in. 0.50 0.50 Air leak in the analyzer, which caused bottle to run out early. Replaced leaking fitting and put back in service. 0.25 0.25 SRU Tailgas Incinerator 1 SO2 Quarterly Audit 1.25 1.25 Daily Validation 22.00 22.00 Cal Drift Due to sample system plugging 29.50 29.50 Calibrate/Revalidate 0.50 0.50 Slight daily validation drift, adjusted SO2 zero and span. Calibrated then revalidated. 1.25 1.25 Daily validation drift on SO2 and O2. Recalibrated and revaildated. 26.75 26.75 Analyzer offline during calibration of O2 0.50 0.50 Took system offline for CEM PLC upgrade. The O2 and SO2 analyzers were reading, but did not validate during the PLC upgrade because the signals that normally initiate the drift check were removed due to the PLC upgrade. In the future, Chevron will make its best efforts to have an alternative method of completing daily validations during extended maintenance periods, such as manually initiating and recording drift check validations. 56.75 56.75 O2 Quarterly Audit 2.50 2.50 Daily Validation 103.00 103.00 Misc. Cal Drift 0.50 0.50 Daily validation drift on SO2 and O2. Recalibrated and revaildated. 0.50 0.50 Took system offline for CEM PLC upgrade. The O2 and SO2 analyzers were reading, but did not validate during the PLC upgrade because the signals that normally initiate the drift check were removed due to the PLC upgrade. In the future, Chevron will make its best efforts to have an alternative method of completing daily validations during extended maintenance periods, such as manually initiating and recording drift check validations. 56.75 56.75 O2 drifted on validation. Recalibrated and revalidated 26.00 26.00 SRU Tailgas Incinerator 2 SO2 Quarterly Audit 1.00 1.00 Daily Validation 22.75 22.75 Validation drift caused by communication error, reset system and reran validation.31.75 31.75 Calibrate/Revalidate 0.25 0.25 O2 Quarterly Audit 1.00 1.00 Daily Validation 23.00 23.00 Validation drift caused by communication error, reset system and reran validation.31.75 31.75 Boiler #7 NOx Quarterly Audit 1.00 1.00 O2 Quarterly Audit 1.00 1.00 Grand Total 229.70 459.00 432.25 7.00 1127.95 Chevron Refinery EER 4Q2023 SO2 * SO2 Type Code 410 (SO2) - 6000 (All) SO2 * SO2 Count of Magnitude of Emissions Column Labels SO2 Row Labels 701 703 Grand Total SO2 SRU 1 shutdown and start up that was preplanned. This was for repairing a 600# steam line which required a unit shut down. The refinery does not have a history of emmissions associate with this cause. SO2 SRU Tailgas Incinerator 1 18 18 SO2 SRU1 trim air analyzer stopped reading. This caused high temperature alarms and high SO2 alarms which informed operations of abnormal conditions. The SRU1 unit shut down. Operations contacted analyzer team which repaired analyzer. Once repaired, operations safely brought the unit back on line. The refinery does not have an emissions history associated with this cause. SO2 SRU Tailgas Incinerator 1 44 44 SO2 SWS2 column had several flooding events. Column swings caused ammonia gas flow to SRU2 to swing as well. Trim air demand analyzer was unable to respond quickly enough causing incomplete combustion of acid gas. This led to process related SO2 exceedance. The refinery does not have a history of emmissions associated with this cause. SO2 SRU Tailgas Incinerator 2 7 7 SO2 Amine 2 regenerator OH pressure control valve was open due to an instrument issue. Once it was closed, an excess flow went to SRU 2, which couldn't handle the extra volume. SO2 was high until the operator added liquid oxygen to handle the extra volume. The refinery does not have a history of emmissions associated with this cause. SO2 SRU Tailgas Incinerator 2 12 12 SO2 SRU1 had the Trim air demand analyzer stop reading. This caused excess SO2 to build in the SRU1 unit which was diverted to the SRU2 to stabalize the process in SRU1. This caused an excess SO2 in the SRU2 unit. Operations followed procedures to stabalize the SRU1 unit and SRU2 unit. The refinery does not have a history of emissions associated with this cause. SO2 SRU Tailgas Incinerator 2 12 12 SO2 Grand Total 18 75 93 NOx d * NOx d Type Code 421 (Daily NOx Emissions) - 500 (All) NOx d * NOx d Count of Reason Code Column Labels NOx d Row Labels Grand Total NOx d Grand Total H2S/TRS * H2S/TRS Type Code 430 (H2S) - 6000 (All) H2S/TRS * H2S/TRS Count of Magnitude of Emissions Column Labels H2S/TRS Row Labels Grand Total H2S/TRS Grand Total Chevron Refinery EER 4Q2023 CO * CO Type Code 440 (CO) - 6000 (All) CO * CO Count of Magnitude of Emissions Column Labels CO Row Labels 703 Grand Total CO FCC Regenerator Vent CO While making adjustments to the unit, lowering feed and removing black wax to meet plan, the regen temperature cooled down which caused the CO to climb above the limit. The Unit Operator added HCO and ensured there was enough excess O2 to stabalize CO emmissions. 1 1 CO Grand Total 1 1 VOC/THC * VOC/THC Type Code 460 (VOC/THC) - 6000 (All) VOC/THC * VOC/THC Count of Magnitude of Emissions Column Labels VOC/THC Row Labels Grand Total VOC/THC Grand Total O2 * O2 Type Code 470 (TRS as O2) - 6000 (All) O2 * O2 Count of Magnitude of Emissions Column Labels O2 Row Labels Grand Total O2 Grand Total Chevron Refinery EER 4Q2023 Type Code 500 Before February 28, 2005 (Boiler Operating Days w/o 18 Hours of Data) After February 28, 2005 (90% Operating Hours For each 30 BOD) - 500 (All) * Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 510 (F-factor, Equations & Conversion Factors) - 500 (All) Count of F-factor Column Labels Row Labels Grand Total Grand Total * Type Code 520 (Minimum Data Not Obtained <22/30 BODs) - 500 (All) Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 530 (Excess Emissions During Emergency Conditions) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * Type Code 540 (Fuel Pre-treatment Credit SO2) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * TypeCode 550 (Changes in Operation in Control Equipment When CEM Data Not Available) - 500 (All) Column Labels Row Labels Grand Total Grand Total