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Home My WebLink AboutDAQ-2024-0047271 DAQC-058-24 Site ID 10096 (B5) MEMORANDUM TO: CEM FILE – SUNNYSIDE COGENERATION ASSOCIATES THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: January 18, 2024 SUBJECT: Source: Unit 1 – Fluidized Bed Combustion Boiler Contact: Rusty Netz – 435-888-4476x107 Location: East Carbon, Carbon County, UT Test Contractor: Montrose Air Quality Services FRS ID#: UT00000049000700030 Permit/AO#: Title V operating permit 700030005 dated March 8, 2023 Subject: Review of RA/PST Report dated June 8, 2023 On June 23, 2023, Utah Division of Air Quality (DAQ) received a Relative Accuracy/Performance Specification Test (RA/PST) report for the Sunnyside Unit 1 in East Carbon, Utah. Testing was performed on May 16, 2023, to determine the relative accuracy of the O2, CO2, NOX, and SO2 monitoring systems. The DAQ-calculated test results are: RA/PST EVALUATION: Unit No. 1 NSPS RATA - Test Date - May 16, 2023 Primary Channel Manufacturer Serial No. Units CEM Value RM Value Relative Accuracy Status SO2 Eco Chem - MC3 425 ppm 89.12 93.94 3.0% Passed lbs/MMBtu 0.19 0.20 3.3% Passed lbs/hr 125.71 144.98 4.6% Passed CO2 % 12.76 14.00 9.4% Passed NOx Eco Chem - MC3 425 ppm 102.08 109.02 6.9% Passed lbs/MMBtu 0.16 0.17 7.2% Passed O2 Eco Chem - MC3 425 % 5.02 5.54 11.3% Passed Volumetric Flow Rate scfm 178656.7 172488.0 4.1% Passed Stack Test Deviation Report There were no deviations observed during testing. Calibration gases were in date and met performance specifications. DEVIATIONS: No deviations were noted in this report. 1 8 2 2 CONCLUSION: Sunnyside Cogeneration Associates operates the continuous emissions monitor (CEM) systems on the unit 1 stack to measure O2, CO2, NOX, and SO2 emissions. The CEM was audited by the DAQ and found to meet quality assurance requirements found in 40 CFR Part 60, Appendix B, Performance Specification 1, and R307-170, Continuous Emission Monitoring System Program. Quarterly cylinder gas audits and an annual relative accuracy test audit were conducted in accordance with the procedures outlined in UAC R307-170. RECOMMENDATION: The Sunnyside Cogeneration Associates Unit 1 CEM system was operating as required in R307-170 and 40 CFR 60.13 at the time of this evaluation. HPV: No. ATTACHMENTS: RATA Review Spreadsheets. Sunnyside Cogeneration Associates P.O. Box 159 . Sunnyside, Utah 84539 ' (435) 888-4476 . Fax (435) 888-2538 June 8,2023 Rob Leishman Division of Air Quality 195 North 1950 West Sdt Lake City, Utah 841l6 Re: Sunnyside Cogeneration Associates (SCA) Relative Accuracy Test Audit (RATA) CO Compliance Tests Title V Permit Number # 700030004 Dear Mr. Leishman: The following reports summarize the results from the CEM RATA and CO compliance tests conducted at the SCA facility on May 16,2023. The results are used to determine compliance with the facility's Air permit. The testing procedures adhered to all applicable EPA Methods, Division Policies, Utatr Air Conservation Rules, and methods approved by the Executive Secretary. I acknowledge under penalties of law that all information contained in the year 2023, CEM RATA and CO test reports, to the best of my knowledge, is tnrthful and accurate, and is a complete record of all monitoring related events which occurred during the compliance tests. Ifyou have any questions or if further clarification is needed, please contact Rusty Netz or myself at (435) 888-447 6. Thank You,w Gerald Hascall Agent for Sunnyside Cogeneration Associates Rusty Netz Plant File Cc: source Test Report for 2023 RATA Testing 2C,23 Relative Accuracy Test Audits and Compliance Testing Unit EU# 1 Sunnyside Cogeneration Associates Sunnyside, Utah Prepared For: Sunnyside Cogeneration Associates 1 Power Plant Road Sunnyside, Utah 84539 i I Prepared BY: Montrose Air QualitY Services, LLC 990 West 43rd Avenue Denver, Colorado 80211 For Submission To: Utah Division of Air QualitY 195 North 1950 West Salt Lake CitY, UT 84116 Document Number: GPO43AS-O25822-RT-133O Test Date: MaY 15, 2023 r--1.1r,'a; TTftT-i'=^\ it. "i t..1..'-.-..,-. '; , t'.',, .. t ,;t.' .'-i{i --j:-;-:-::"-;;^:*'* *''-1, l-t-:-";r;;"'* - I il Jtlrr a?2ir23 ii I ----)iL-_ STA€ffi, fo{lrohl*vt{t1} Mlo' Review and Ceftification All work, calculations, and other activities and tasks performed and presented in this document were carried out by nie or under my direction and supervision. I hereby certify that, to the best of my knowledge, Montrose operated in conformance with the requirements of the Montrose Quality Management System and ASTM D7O36-O4 during this test project. Signature: Name: June 6,2023 Cheyney Guymon Project Manager Date: Title: I have reviewed, technically and editorially, details, calculations, results, conclusions, and other appropriate written materials contained herein. I hereby certify that, to the best of my knowledge, the presented material is authentic, accurate, and conforms to the requirements of the Montrose Quality Management system and ASTM D7O36-O4. Signature: Name: June 6,2023 QA/QC SpecialistMatthew Parks GP043AS-02 5822-RT- 1 3 30 Page 2 ot 174 Table of Contents Paqe 1.0 2.0 3.0 4.0 5.0 Section Introduction.,,.... """"""' 5 1.1 Summary of Test Program """' 5 1.2 KeyPersonnel..'. """"""'8 Plant and Sampling Location Descriptions..'.,... """'10 2.L Process Description, Operation, and Control Equipment "" ""'10 2.2 Flue Gas Sampling Locations """"""'10 2.3 Operating Conditions and Process Data """10 2.4 CEMS DescriPtion ""' 11 Sampling and Analytical Procedures..'.... """"""11 3.1 Test Methods.... """"""11 3.1.1 EPA Method 2.'..... """""11 3.L.2 EPA Method 4...... """""13 3.1.4 EPA Methods 3A, 6C, 7E, and 10 .'.. """'15 3.2 Process Test Methods."..'.'...' """'17 Test Discussion and Results. """"""'L7 4.1 Field Test Deviations and Exceptions.' """""'17 4.2 Presentation of Results"..".'.'. """'i """""'L7 Internal QA/QC Activities """' 18 5.1 QA/QC Audits """'18 5.2 QA/QC Discussion. """18 5.3 Quality Statement """'18 List of Appendices Field Data and Calculations......" """19 A.1 Sampling Location """"""2O A.2 RATA Results.... """""'22 A.2 .1 Unit 1 .......... """"23 A.3 Unit l Field Data """'34 A.3.1 Flow Data.. "'''""'35 A.3.2 Instrumental Test Method Data ""62 A.4 Example Calculations... """'76 Facility Process Data........ """85 8.1 Unit 1 " "" '86 Quality Assurance/Quality Control """'LO7 C.1 Units and Abbreviations'..... "' 108 GP043AS-025822-RT- 1330 Page 3 ot t74 l C.2 Manual Test Method QA/QC Data ........ .......116 C.3 Instrumental Test Method QA/QC Data..'..... .......127 C.4 Calibration Gas Certificates......... .,..........L62 C.5 Accreditation Information/Certiflcations ..........17L List of Tables Table 1-1 Summary of Test Program.... ."..... 5 Table 1-2 Summary of MTA Results - Sunnyside Unit 1.,..... .......7 Table 1-3 Summary of Emission Limits .'.......... B Tdble 1-4 Test Personnel and Observers .'......'...9 Table 2-1 Sampling Locations .........'..10 Table}-Z CEMS Information ...........11 List of Figures Figure 3-1 EPA Method 2 Sampling Train....... ...............12 Figure 3-2 EPA Method 4 Sampling Train.... .............t4 Figure 3-3 EPA Methods 3A, 6C, 7E, and 10 Sampling Train .......'..."..16 GP043AS-025822-RT- 1 330 Page 4 ot L74 1 .0 I ntrod uctio n 1.1 Summary of Test Program Sunnyside Cogeneration Associates contracted Montrose Air Quality Services' LLC (Monirose) to perform a testing program at Sunnyside Power Plant located near Sunnyside, Utah. Testing was conducted in accordance with the testing requirements of Utah Department of Environmental Quality (UDEQ) Operating Permit 700030002 and (as applicable) 40 CFR Parts 60 and 75. The specific objectives were to: . Perform annual Relative Accuracy Test Audits (RATAs) on the Continuous Emission Monitoring Systems (CEMS) installed on Unit EU#1 o Perform annual carbon monoxide (CO) compliance testing on the exhaust stack of Unit EU#1 . Conduct the test program with a focus on safety Montrose performed the tests to measure the emission parameters listed in Table 1-1' Table 1-1 SummarY of Test Program To simplify this report, a list of Units and Abbreviations is included in Appendix C'1' Throughout this report, chemical nomenclature, acronyms, and reporting units are not defined. Please refer to the list for specific details' GP043AS-025822- RT- I 330 Page 5 ot 174 This report presents the test results and supporting data, descriptions Of the testing procedures, descriptions of the facility and sampling locations, and a summary of the quality assurance procedures used by Montrose. The average emission test results are summarized and compared to their respective performance specifications in Table 1-2, Detailed results for individual test runs and all supporting data can be found in the appendices. The testing was conducted by the Montrose personnel listed in Table 1-3. The tests were conducted according to the test plan (protocol) that was submitted to and approved by UDEQ. GP043AS-025822-RT-1330 Page 6 of 174 Table 1-2 Summary of RATA Results - Sunnyside Unit 1 April 18, 2023 App. B Sect, 2.3.1.2 Annual: < 7.5olo of RM Carbon Dioxide (COz) Annual: S 7.5olo of RM Annual: < 7.5olo of RMApp. B Sect. 2.3.1.2 App. B Sect. 2.3.1.2 < 20.0olo of RM Sulfur Dioxide (SOz) Annual: S 7.5olo of RMApp. B Sect, 2.3.1.2 S 20.0olo of RM S 20.0olo of RM Nitrogen Oxides (NO, as NOz) < 20.0olo of RM Part75 Nitrogen Oxides (NO, as NOz) App. B Sect. 2.3.1.2 < 20.07o of RM GP043AS-025822-RT- 1 330 Page 7 ol t74 l i I The applicable permit limits are presented in Table 1-3. Table 1-3 Summary of Emission Limits ii !,,2 Key Personnel A list of project pafticipants is included below: Facility Information Source Location: Project Contact: Role: Company: Telephone: Email: Agency Information Regulatory Agency: Agency Contact: Telephone: Email: Sunnyside Cogeneration Associates Sunnyside Power Plant 1 Power Plant Road Sunnyside, UT 84539 Rusty Netz Environmental Advisor Sunnyside Cogeneration Associates (435) 888-4476 xLoT rusnetz@hotmail.com Utah Department of Air Quality Rob Leishman (801) s36-4438 Rleishman@utah.gov Testing Company Information Testing Firm: Montrose Air Quality Services, LLC Contact: Craig Kormylo Title: District Manager Telephone: (303) 495-3936 Email: CKormylo@montrose-env.com 1i ,Iil il GP043AS-025822-RT- 1 330 Page 8 of 174 Test personnel and observers are summarized in Table 1-4. Table 1-4 Test Personnel and Observers Project Manager Qualified Individual' (QI) Trailer operator Cheyney Guyman Sample train oPerator Sample train operator Calculations and report preparationMatthew Parks Test Coordinator GP043AS-025822-RT- 1 330 Page 9 ot 774 2,A Plant and sampling Location Descriptions I 2.7. Frocess Description, Operation, and Control Equipment The Sunnyside Cogeneration Facility is a steam-electric generating power plant located in Sunnyside, Carbon County, Utah. The plant consists.of a circulating fluidized bed (CFB) combustion boiler designaied EU #1, an emergency backup diesel-fired PUmF, diesel storage tanks, coal handling equipment, ash handling equipment and limestone handling equipment. EU #t has a rating of ZbO mmBtu/hrand isequipped with limestone injection and a baghouse for control of emissions. The EU #1 is fueled by coal refuse from the Sunnyside and Star point Refuse piles. The flylbottom ash generated from the coal combustion is disposed of in an on-site landflll or used for beneficial applications. 2.2 Flue Gas Sampling Locations Information regarding the sampling locations is presented in Table 2-1. Tabte 2-1 Sampling Locations Unit EU#1 Sample location(s) were verified in the field to conform to EPA Method 1' See Appendix A.1 for more information. 2.3 Operating Conditions and Process Data Emission tests were performed while the source/units and air pollution control devices were operating at the conditions required by the relevant performance specifications. The units were tested when operating within the load levels reguired by 40 CFR Part 75' plant personnel were responsible for establishing the test conditions and collecting all applicable unit-operating data. The process data that was provided is presented in Appendix B. Data collected includes the following parameters: Unit Load (MW) Relevant CEMS Parameters a a GP043AS-025822-RT- 1 330 Page 10 of 174 2"4. CEMS DescriPtion Information regarding the monitoring systems is presented in Table 2-2' Table 2-2 CEMS Information 3,0 Sampling and Analytical Procedures 3.1 Test Methods The test methods forthis test program have been presented in Table 1-1. Additional information regarding specific applications or modifications to standard procedures is presented below. 3.1.1 EpA Methad 2, Determination of Gas Velocity and Volumetric Flow Rate (TYPe S Pitot Tube) EPA Method 2 is used to measure the gas velocity using an s-type pitot tube connected to a pressure measurement device, and to measure the gas temperature using a calibrated thermocouple connected to a thermocouple indicator. Typically, Type S (Stausscheibe) pitot tubes conforming to the geometric specifications in the test method are used, along with an inclined manometer. The measurements are made at traverse points specified by EPA Method 1. The molecularweight of the gas stream is determined from independent measurements of Oz, COz, and moisture. The stack gas volumetric flow rate is calculated using the measured average velocity head, the area of the duct at the measurement plane, the measured average temperature, the measured duct static pressure, the molecular weight of the gas stream, and the measured moisture' pertinent information regarding the performance of the method is presented below: . Method Options: r, S-type pitot tube coefficient is 0.84 e Method ExcePtions: None The typical sampling system is detailed in Figure 3-1' 417243 Unit EU#1 GP043AS-025822-RT- 1 330 Page 7t ot 174 FIGURE 3-1 US EPA METHOD 2 SAMPLING TRAIN GP043AS-025822-RT- 1 330 Page 12 of 174 3.1.2 EPA Method 4 Deterniination of Moisture Content in Stack Gas EpA Method 4 is a manual, non-isokinetic method used to measure the moisture content of gas streams. Gas is sampled at a constant sampling rate through a probe and impinger train, Moisture is removed using a series of pre-weighed impingers containing methodology- specific liquids and silica gel immersed in an ice water bath. The impingers are weighed after each run to determine the percent moisture. pertinent information regarding the performance of the method is presented below: . Method Options: o None . Method Exceptions: c., None The typical sampling system is detailed in Figure 3-2. GP043AS-025822-RT- 1 330 Page L3 of 174 Figure 3-2 EPA Method 4 SamPling Train SATT,PIE LINE (dailtailtb). VACUUM*- LhrE THERIiOCOT.,PtES$l BY-PASSVALVE(rla+,a) VACUUMGAUGE VALvE Iddaalut) MANOEIER ----o GP043AS-025822-RT- 1 330 Page 14 ot L74 3.1.4 EPA Methods 3A, 6C, 7E, and IO Determination of Oxygen, Car.bon Dioxide, Sulfur Dioxide, Nitrogen Oxides, and Carlron Morroxide Concentrations in Ernissions from Statiorrary Sources (l nstrumental Analyzer Procedures) Concentrations of Oz,COz, SOz, NOx, and CO are measured simultaneously using EPA Methods 3A, 6C, 7E, and 10, which are instrumental test methods. Conditioned gas is sent to a series of analyzers to measure the gaseous emission concentrations, The performance requirements of the method must be met to validate the data' Pertinent information regarding the performance of the method is presented below: o Sampling is performed using a dilution probe o A nondispersive infrared analyzer is used to measure COz o An ultraviolet absorption analyzer is used to measure SOz c, A chemiluminescent analyzer is used to measure NOx o A gas filter correlation nondispersive infrared analyzer is used to measure co c-, NO and NOz are measured separately and summed to report NOx emissions c, Gas stratification testing is peformed across a grid of 12 points determined using EPA Method 1 in accordance with 40 cFR Paft 60, Appendix B, PS2 58.1,3.2 and 40 CFR Part 75, Appendix A, $6.5.6.1. Stratification testing is performed for two minutes per traverse point in accordance with 40 cFR Part 75, Appendix A, $6.5.6.1(c). If diluent and pollutant concentrations are within 5o/o of their mean concentrations, subsequent gas RATA testing is performed at a single point in the stack as allowed by 40 cFR Part60, Appendix B, PS2 58.1.3.2 and 40 CFR Part 75, Appendix A 56.5.6.3(b). If diluent and pollutant concentrations are within lOo/o of their mean concentrations, RATA testing is performed at three points located 0.4 meter, 1.0 meter and 2.0 meters from the stack wall, as required by 40 cFR Part 60, Appendix B, PS2 58.1.3.2 and 40 CFR Part 75, Appendix A, $6.5.6.1(a). The typical sampling system is detailed in Figure 3-3. GP043AS-02582 2-RT- 1 330 Page 15 of 174 Figure 3-3 EPA Methods 3A, 6C, 7E, and 1O Sampling Train , qANAYZER GP043AS-02582 2-RT- 1 330 Page 16 of t74 ) 3,2 Process Test Methods The test plan did not require that process samples be collected during this test program; therefore, no process sample data are presented in this test report. 4,A Test Discussion and Results 4,L Field Test Deviations and Exceptions No deviations or exceptions from the test plan or test methods were identified by the project manager during this test program. 4.2 Presentation of Results The average results are compared to the applicable performance specifications and permit limits in Tables l-Z and 1-3. Emissions are reported in units consistent with those in the applicable performance specifications. Additional information is included in the appendices as presented in the Table of Contents' GP043AS-025822-RT- 1 330 Page L7 ot 774 l 5,0 Internal QA/QC Activities 5.1 QA/QC Audits The meter boxes and sampling trains used during sampling performed within the requirements of their respective methods. All post-test leak checks, minimum metered volumes, and minimum sample durations met the applicable QA/QC criteria, except where noted in Section 5.2, EPA Method 3A, 6C, 7E, and 10 calibration audits were all within the measurement system performance specifications for the calibration drift checks, system calibration bias checks, and calibration error checks, except where noted in Section 5.2. The NOz to NO converter efficiency check of the analyzer was conducted per the procedures in EPA Method 7E, Section 8.2.4. The conversion efficiency met the criteria, except where noted in Section 5.2. 5.2 QA/QC Discussion All QA/QC criteria were met during this test program. 5.3 Quality Statement Montrose is qualified to conduct this test program and has established a quality management system that led to accreditation with ASTM Standard D7036-04 (Standard Practice for Competence of Air Emission Testing Bodies). Montrose participates in annual functional assessments for conformance with D7036-04 which are conducted by the American Association for Laboratory Accreditation (A2l-A). All testing peformed by Montrose is supervised on site by at least one Qualified Individual (QI) as defined in D7036-04 Section 8.3.2. Data quality objectives for estimating measurement uncertainty within the documented limits in the test methods are met by using approved test protocols for each project as defined in D7036-04 Sections 7.2.t and 12.10. Additional quality assurance information is included in the report appendices. The content of this report is modeled after the EPA Emission Measurement Center Guideline Document (GD-043). GP043AS-025822-RT- 1330 Page 18 of 174 l l i i I Appendix A Field Data and Calculations lr l Page 19 of 174GP043AS-025822-RT- 1330 I I Appendix A,1 Sampling Location rl I l GP043AS-025822-RT- 1 330 Page 20 ot 174 Sunnyside Sampling Location Pollutant Stratification Test Points oH ^1 Stack Cross Section (A-A) Unlt Diameter (D) Upstream Distance (A) Downstream Distance (B) 1 101" >'t7'(2D) >67',(8D) Sample Point Distances trom Stack Wall Traverse Poini 1 4.4" Traverse Point 2 14.8" Traverse Point 3 29.9" Volumetric Flow Rate Sample Points +++ + + +++ 7211 . 3 2 ! Stack Cross Section (A-A) Sample Point Distances from Stack Wall TraveBe Point I 3.3 Traverse Point 2 10.6 Traverse Point 3 19.6 Traverse Point 4 32.6 Unit Diameter (D) Upstream Distance (A) Downstream Distance (B) 1 101" >17', (2D) >67',(8D) GP043AS-025822- RT- 1 330 Page 27 ot L74 Appendix A.2 RATA Results I I I ,l Appendix A.2,1 Unit 1 GP043AS-025822-RT- 1330 Page 23 ot t74 Montrose Air Quality Services, 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet LLC. Monitor: Flow - P63 scfhCompany: Sunnyside Source: EU #1 Dale: 511612023 Reference Method Run # (scfh)*1 167559 2 168855 3 176375 4 174030 5 166542 6 167794 7 174516 8 175389 I 185425 10 176609 Relative Method (scfh) 179695 179217 17937',| 178865 178647 178584 176993 178926 179348 177955 Diff -12137.00 -10362.00 -2996.00 -4835.00 -12105.00 -10790.00 -2477.00 -3537.00 6077.00 -1346.00 Diff. Sqd. 147306769 107371044 8976016 23377225 14653'1025 116424100 61 35529 12510369 36929929 18117 16 Ave 173948.33 178656.22 -4707.89 * Not used in calculations Standard Deviation 5707.33 ConfidenceCoefficient 4387.03 Relative Accuracy 5.23 (of RM Test Data) o,,o GP043AS-025822- RT- 1 330 Page 24 ot L74 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Company: Sunnyside Monitor: 02 o/o Source: EU #1 Dale: 511612023 Reference Relative Method Method Run # dv(%) dv(%) Abs. Diff Diff. Sqd.*1 5.7 5.0 0.7297 0.5324 2 5.5 5.0 0.5491 0.3016 3 5.7 5.0 0.6880 0-4734 4 5.7 5.0 0.6802 0.4627 5 5.4 5.0 0A209 0.1772 6 5.5 5.0 0.4615 0.2130 7 5.5 5.1 0.4056 0.1645 I 5.5 5.1 0.4348 0.1890 9 5.5 5.0 0.5133 0.2635 10 5.4 5.0 0.4369 0.1908 Ave 5.55 5.02 0.53 StandardDeviation 0.109 ConfidenceCoefficient 0.084 Absolute Difference 0.53 % (of RM Test Data) GP043AS-02 5822- RT- 1 330 Page 25 ot t74 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Company: Sunnyside Source: EU #1 Dale: 511612023 Monitor:co2 o/o Standard Deviation Confidence Coefficient Reference Method Run # (Yo) 1 13.9 2 14.1 3 14.0 4 14.0*5 13.9 6 14.2 7 14.1 8 14.1 I 14.0 10 14.1 0.11 0.08 AbsoluteDifference 1.28 (of RM Test Data) Relative Method (Yo) 12.8 12.8 12.8 12.8 12.8 12.8 12.7 12.7 12.7 12.8 Abs. Diff 1.06437 1.25889 1.24179 1.16533 1.10624 1.35327 1.38917 1.36184 1.34806 1.33254 Diff. Sqd. 1.13289 1.58480 't.54205 1.35800 1.22377 1.83135 1.92980 1.85461 1.81726 1.77567 Ave 14.O5 12.77 1.28 otto GP043AS-025822- RT- 1330 Page 26 of t74 Montrose Air Quality Services, LLG. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Company: Sunnyside Source: EU #1 Dale: 511612023 Monitor: CO2 lbs/hr Run # 1 2 3 4 5 o 7 *8 o 10 Reference Method (lbs/hr) 143907.0 149673.4 151658.5 149822.9 142938.5 149295.5 152257.2 156430.7 156550.6 1 53657.1 Relative Method (lbs/hr) 143912.00 143770.40 143666.'10 142942.60 142946.70 142638.00 141284.80 142779.10 143035.30 142802.50 Abs. Diff 4.99361 5903.01651 7992.35865 6880.31027 8.23906 6657.52143 10972.41674 13651.63677 13515.31089 10854.63848 Diff. Sqd. 25 34845604 63877797 47338669 68 44322592 1 20393929 1 863671 86 1 82663629 117823176 Ave 149973.42 142999.82 6976.53 Standard Deviation 4653.19 Confidence Coefficient 3576.75 Relative Accuracy 7.04 (of Reference Method) % GP043AS-025822-RT- 1 330 Page 27 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheel Company: Sunnyside Source: EU #1 Dale: 511612023 Monitor:NOx ppm Reference Method Run # (ppm) 1 97.67*2 97.29 3 98.45 4 98.78 5 99.34 6 99.51 7 98.75 8 98.30 I 96.70 10 95.47 0.56 0.43 Abs. Diff 3.42591967 6.10547184 4.1 5062595 3.92429475 2.9581936 3.092229 4.24630727 4.30353511 4.50392758 4.13177851 Relative Method (ppm) 101.10 103.40 102.60 102.70 102.30 102.60 103.00 102.60 101.20 99.60 Diff. Sqd. 1 1.73693 37.27679 17.2277 15.40009 8.750909 9.56188 18.03113 18.52041 20.28536 17.07159 Ave 98.11 101.97 3.86 15.18 * Not used in calculations Standard Deviation Confidence Coefficient Relative Accuracy (of RM Test Data) 4.37 otto GP043AS-025822-RT- 1 330 Page 28 of L74 Montrose Air QualitY Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA ShEEt Company: Sunnyside Source: EU #1 Dale: 511612023 " Not used in calculations Standard Deviation 0.0021 Confidence Coefficient 0.0016 Reference Relative Method Method Run # (lb/mmbtu) (lb/mmbtu) Abs. Diff Diff. Sqd' 1 0.168 0.155 0.01342 0.0002 2 0.165 0.159 0.00645 0.0000 3 0.168 0.157 0.01078 0.0001 4 0.169 0.157 0.01226 0.0002*5 0171 0.157 0.01439 0.0002 6 0.169 0.157 0.01168 0.0001 7 0.167 0.158 0.00940 0.0001 8 0.1 67 0. 1 58 0.00895 0.0001 I 0.1 65 0. 1 56 0.00894 0.0001 10 0.162 0.152 0.00987 0.0001 Monitor: NOx lb/mmbtu Relative Accuracy 7.08 (of RM Test Data) Ave 0.17 0.16 0.01 o/o GP043AS-025822-RT- 1 330 Page 29 ot L74 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Company: Sunnyside Source: EU #1 Dale: 511612023 Standard Deviation Confidence Coefficient Monitor: Nox lbs/hr Run # 1 2 3 4 5 6 7 *8 o 10 Reference Method (lbs/hr) 105.8 108.1 111.0 110.6 106.6 109.6 111.4 114.1 112.5 108.3 Relative Method (lbs/hr) 101.10 103.40 102.60 102.70 102.30 102.60 103.00 102.60 't01.20 99.60 Abs. Diff 4.71308 4.70865 8.37759 7.90008 4.27360 6.95324 8.38431 11.52903 11.26713 8.73520 Diff. Sqd. 22 22 70 62 18 48 70 133 127 76 Ave 109.31 102.06 7.26 2.32 1.79 Relative Accuracy (of Reference Method) 8.27 % GP043AS-025822-RT- 1330 Page 30 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Company: SunnYside Source: EU #1 Date 511612023 Monitor:so2 ppmvw Reference Method Run # (ppmvw) I 79.22*2 81.12 3 81.34 4 83.53 5 86.83 6 82.73 7 84.36 I 80.02 I 89.40 10 90.43 Relative Method (ppmvw) 83.80 88.20 80.40 88.80 92.00 88.20 84.80 85.40 93.40 97.50 Abs. Diff 4.5774137 7.0797976 0.9438150 5.2656791 5.1708273 5.4706528 0.4358945 5.3834342 3.9968589 7.071 1800 Diff. Sqd. 20.95272 50.1 2353 0.890787 27.72738 26.73746 29.92804 0.1 90004 28.98136 't5.97488 50.00159 Ave 84.21 88.26 4.26 22.38 * Not used in calculations Standard Deviation Confidence Coefficient 2.19 1.68 Relative Accuracy 7.05 (of RM Test Data) otto GP043AS-025822- RT- 1 330 Page 31 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Monitor:so2Company: Sunnyside Source: EU #1 Dale: 511612023 Reference Method Run # (lb/hr) 1 119.32 2 125.32*3 127.48 4 130.04 5 129.51 6 126.63 7 132.29 I 129.16 I 144.57 10 142.67 Relative Method (lb/hr) 118.20 124.50 1 13.00 125.10 130.10 124.50 119.70 120.60 131.70 137.10 Abs. Diff 1 .1 '19878 0.81551 1 14.48251 4.939114 0.594862 2.128534 12.59156 8.564117 12.86838 5.566294 Diff. Sqd. 1.254127 0.665058 209.7432 24.39484 0.353861 4.530655 158.5473 73.3441 165.5953 30.98363 Ave 131.06 125.72 5.47 - Not used in calculations Standard Deviation Confidence Coefficient 4.88 3.75 Relative Accuracy 7.03 (of RM Test Data) otto GP043AS-025822-RT- 1 330 Page 32 ot L74 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Company: Sunnyside Monitor: SO2 lbs/mmbtu Source: EU #1 Dale: 511612023 Reference Relative Method Method Run # (lb/mmbtu) (lb/mmbtu) Abs. Diff Diff Sqd' 1 0.190 0.179 0.01092 0.0001 2 0.192 0.189 0.00278 0.0000*3 0.193 0.171 0.02173 0.0005 4 0.199 0.189 0.01001 0.0001 5 0.208 0.197 0.01127 0.0001 6 0.1 95 0.1 88 0.00697 0.0000 7 0.199 0.181 0.01782 0.0003 8 0.189 0.183 0.00594 0.0000 9 0.212 0.200 0.01202 0.0001 10 0.213 0.208 0.00517 0.0000 Ave 0.20 0.19 0.01 " Not used in calculations Standard Deviation O.OO5 Relative Accuracy 6.35 % Confidence Coefficient 0.003 (of RM Test Data) GP043AS-025822-RT- 1330 Page 33 of 174 I Appendix A.3 Unit 1 Field Data GP043AS-025822-RT- r 330 Page 34 of 174 l l i Lll i I Appendix A.3.1 Flow Data I I Iil i Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocity Sheet Sunnyside EU #1 (0823-0836) #1 511612023 AP Sqrt AP Ts (in. H2O) (in. H2O) oF 1 1.3 1.14 303 2 1.7 1.30 303 3 1 .8 1.34 303 Wall Effects 1 4 1 .2 1 .'t0 302 0 101 in 5 1.7 1.30 303 A 55.64 ft2 6 1.8 1.34 303 Cp O.84OO 6-8 7 1.2 1.10 302 Pg -0.1 in. H2O I 1.6 1 26 303 Po", 23.9 in. Hg 9 1.7 1.30 303 Ps 2i.89 in. Hg 10 1.3 1.14 302 Mw(wet) 30.7816 lb/lb-mole 1'l 1.6 1.26 303 Bws 0.10't 12 1.7 1.30 303 Vs = 90.8008 ft./sec Qs gta = 1.OO53E+07 scf/hr Qs eto = ,l.6ZSS8E+OS scf/min DSCFH = 9.0381E+06 average = 1.550 1.2416 302.75 0F RUN #1 : g.O731E+06 DSCFH 762.75 0R 1.OO92E+07 SCFH GP043AS-025822-RT- 1 330 Page 36 ot L74 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (0858-0906) #2 5t16t2023 1 2 3 4 5 6 7 I 9 10 11 12 AP (in. H2O) 1.2 1.7 1.8 't.3 1.7 1.7 1.3 1.6 1.8 1.4 1.6 1.8 Sqrt AP (in. H2O) 1.10 1.30 1.34 1.14 1.30 1.30 1.14 1.26 1.34 1.18 1.26 1.34 Ts OF 303 304 304 304 304 304 304 304 304 303 304 304 303.83 0F 763.83 0R Wall Effects 0 A cp Ps Pt"t P3 Mw(wet) Bws Vs= Qs "ta = Qs "ro = DSCFH = I 101 55.64 0.8400 -0.1 23.9 23.89 30.7816 0.1 01 91.6337 ',l.0131E+07 1.688558+05 9.1 081 E+06 in ft2 6-B in. H2O in. Hg in. Hg lb/lb-mole fUsec scf/hr scf/min average = 1.575 1.2521 RUN#2: 9.3061E+06 DSCFH 1.0357E+07 SCFH GP043AS-025822-RT- 1 330 Page37 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (0948-0957) #3 5t16t2023 AP Sqrt AP Ts (in. H2O) (in. H2O) oF 1 1.2 1.10 305 2 1.7 1 .30 306 3 1.8 1.34 306 Wall Effects 1 4 1.3 1.14 305 5 1.7 1.30 305 6 1.8 1.34 306 7 1.3 1.14 305 I 1.7 1 .30 305 9 1.8 1.34 305 10 1.2 1.10 304 11 1.6 1.26 305 12 1.8 1.34 305 0 101 in A 55.64 fl2 Cp O.84OO 6-8 Ps -0.1 in. H2O Pur, 23.9 in. Hg Ps 23.89 in. Hg Mw(wet) 28.1232 lb/lb-mole Bws 0.1019 Vs = 95.8815 fUsec Qs "to = 1.0582E+07 scf/hr Qs "ta = 1.76375E+05 scf/min DSCFH = 9.5041E+06 average = 1.575 1.2512 305.17 0F RUN #3: g.441OE+06 DSCFH 765.17 0R 1.0512E+07 SCFH GP043AS-025822-RT- 1 330 Page 38 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (r023-1 031 ) #4 5t16t2023 AP Sqrt AP Ts (in. H2O) (in. H2O) oF 1 1.2 1.10 305 2 1.7 1.30 305 3 1.8 1.34 306 Wall Effects 1 4 1.2 1.10 305 0 101 in 5 1.6 1.26 306 A 55.64 ft2 6 1.8 1.34 305 CP 0.8400 6-8 7 1.2 1.10 305 Ps -0.1 in H2O I 1.6 1.26 3OO Pb", 23.9 in. Hg g 1.7 '1 .30 305 P" 23.89 in. Hg 10 1 .3 1.14 305 Mw(wet) 28-1232 lb/lb-mole 11 1.6 1.26 306 Bws 0.1019 12 1.7 1.30 305 Vs = 94.6274 fUsec Qs sa = 1.0442E+07 scf/hr QS sro = 1.74030E+05 scf/min DSCFH = 9.3778E+06 average = 1.533 1.2347 305.33 0F RUN #[: 9.1645E+06 DSCFH 765.33 0R 1.0217E+07 SCFH GP043AS-025822-RT- 1 330 Page 39 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (1 057-1 1 07) #5 5t't612023 AP Sort AP Ts (in. H2O) (in. H2O) oF 1 1.2 1.10 305 2 1.6 1.26 306 3 1.8 1.34 306 WallEffects 1 4 1.3 1.14 305 5 1.6 1.26 306 6 1.7 1.30 305 7 1.3 1.14 305 8 1.6 1.26 306 I 1.7 1.30 306 10 1 .3 1 .14 305 11 1.6 1.26 305 12 1.7 1.30 306 0 101 in A s5.64 ft2 Cp O.84OO 6-8 Pg -0.1 in. H2O Pu", 23.9 in. Hg Ps 23.89 in. Hg Mw(wet) 30.7522 lb/lb-mole Bws 01042 Vs = 90.5753 fUsec Qs "ta = 9.9925E+OO scf/hr Qs "ra = 1.66542E+05 scf/min DSCFH = 8.9513E+06 average = 1.533 1.2357 305.50 0F RUN #5: 8.gg4gE+06 DSCFH 765.50 0R 1.OO3oE+07 SCFH GP043AS-025822-RT- 1 330 Page 40 ot t74 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84663 801-794-2951 Velocitv Sheet Sunnyside EU #1 (1131-11411 #6 5t16t2023 AP Sort AP Ts (in. H2O) (in. H2O) oF 1 1.3 1.14 305 2 1.7 1.30 306 3 1.8 1.34 306 Wall Effects 1 4 1.3 1.14 306 5 1.7 1.30 306 6 1.8 1.34 306 7 1.3 1 .14 306 8 1.6 1.26 307 I 1.7 1.30 306 10 1.2 1.10 306 11 1.6 1.26 306 12 1.7 1.30 306 $ 101 in A 5s.64 ft2 Cp 0.8400 6-8 Pe -0.1 in. H2O Po", 23.9 in. Hg P" 23.89 in. Hg Mw(wet) 30.7522 lb/lb-mole Bws 0.1042 Vs = 91.3162 ft/sec Cls *a = 1.OO68E+07 scf/hr Qs "ra = 1.67794E+05 scf/min DSCFH = 9.0186E+06 average = 1.558 1.2454 306.00 0F RUN #6: 9.2207E+06 DSCFH 766.00 oR 1.0269E+07 SCFH GP043AS-025822-RT- 1330 Page 41 of t74 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (1215-12261 #7 5t1612023 AP Sort AP Ts (in. H2O) (in. H2O) oF 1 1.3 1.14 306 2 1.7 1.30 306 3 '1.8 1.34 306 Wa[ Effects 1 4 1.3 1.14 306 5 1.6 1.26 306 6 1.8 1.34 306 7 1.2 1.10 306 8 1.6 1.26 307 I 1.7 1.30 307 10 1.2 ',t.10 306 11 1.6 1.26 307 12 1.7 1.30 307 0 101 in A 55.64 ft2 Ce O.84OO 6-8 Ps -O.f in. H2O Po", 20.2 in. Hg P" 26.j9 in. Hg Mw(wet) 30.8028 lb/lb-mole Bws 0.1001 Vs = 86.6722 fUsec Qs aro = 1.0471E+07 scf/hr Qs sro = 1.745168+05 scf/min DSCFH = 9.4228E+06 average = 1.542 1.2394 306.33 0F RUN #7: 9.4464E+06 DSCFH 766.33 0R 1.O4g7E+07 SCFH GP043AS-025822-RT- 1 330 Page 42 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside (r250-1301 ) #8 5t16t2023 I 2 J 4 5 6 7 8 I 10 11 12 AP (in. H2O) 1.2 '1.6 1.8 1.3 1.7 1.8 1.3 1.7 1.7 1.2 1.6 1.8 Sqrt AP (in. H2O) 1.10 1.26 1.34 1.14 1.30 1.34 1.14 1.30 1.30 't.10 1.26 1.34 Ts OF 306 307 307 306 306 307 306 307 307 306 307 307 306.58 0F 766.58 0R Wall Effects 0 A cp Ps Pur Ps Mw(wet) Bws Vs= QS sta = Qs ato = DSCFH = 1 101 55.64 0.8400 -0.1 26.2 26.19 30.8028 0.1 001 87 _1343 1.0523E+07 1.75389E+05 9.4700E+06 tn ft2 6-B in. H2O in. Hg in. Hg lb/lb-mole fUsec scf/hr scf/min average = 'l .558 1-2448 RUN #8: 9.7242E+06 DSCFH 1.O824E+07 SCFH GP043AS-025822- RT- 1 330 Page 43 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (1324-13341 5t16t2023 AP Sort AP Ts (in. H2O) (in. H2O) oF 1 1.3 1.14 305 2 1.7 1.30 305 3 1.7 1.30 305 WallEffects I 4 1.3 1.14 305 5 1.7 1.30 305 6 1.8 1.34 306 7 1.4 1.'t8 305 I 1.7 1.30 305 I 1.7 1.30 305 10 1 .3 1.14 304 11 1.6 1 26 305 12 1.8 1.34 305 0 101 in A 55.64 f12 Cp O.84OO 6-8 Ps -0.1 in. H2A Po", 26.2 in. Hg P" 26.19 in. Hg Mw(wet) 28.1104 lb/lb-mole Bws 0.1031 Vs = 91.9300 fUsec Qs "to = 1.1126E+07 scf/hr Qs "ra = 1.8542SE+0S scf/min DSCFH = 9.9785E+06 average = 1.583 1.2559 3O5.OO 0F RUN #9: 9.7412E+06 DSCFH 765.00 0R 1.0861E+07 SCFH GP043AS-02 5822-RT- 1 330 Page 44 of 174 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (1400-141 I ) #10 5t16t2023 1 2 4 5 6 7 8 o 10 11 12 Ts OF 305 305 305 304 305 305 305 305 305 304 305 305 AP (in. H2O) 1.3 1.7 1.8 1.3 1.6 1.7 1.3 1.7 1.8 1.3 1.7 1.7 Sqrt A P (in. H2O) 1.14 1.30 1.34 1.14 1.26 1.30 1.14 1.30 1.34 1.14 1.30 1.30 Wall Effects 0 A cp Ps Po"t P" Mw(wet) Bws Vs= QS sro = Qs "ro = DSGFH = 1 101 55.64 0.8400 -0.1 ,20 23.89 28.1104 0.1 031 95.9667 1.0597E+07 1.76609E+05 9.5040E+06 n ft2 6-B in. H2O in. Hg in. Hg lb/lb-mole ft/sec scf/hr scf/min average =1.575 1.2523 304.83 764.83 oF 0R RUN #10: 9.5040E+06 DSCFH 1.0597E+07 SCFH GP043AS-025822-RT- 1 330 Page 45 of 174 s@l 1v. 2 V.so 3 V^e 4 V*s"" 5v* 6 Bws TEST RESULTS Description Units Valug Volume of Gas Sampled by Dry Gas Meter dcf 43.9610 Dry Gas Volume at Standard Conditions dscf 35.6600 Volume of Gas per Minule @ Dry Condtions dscf/min 0.5943 Volume of Water Vapor in the Gas Sample scf 4.0057 Total Moisture Collected in lmpingers and Silica ( g 85.1 Waler Vapor in the Gas Stream, Proportion by Volume 0.1010 GP043AS-025822-RT- 1 330 EPA Method 4 RUN #1 Pagelof 3 Page 46 of t74 1 2 3 4 e 6 Svmbol Bws TEST RESULTS Description Units @ Volume of Gas Sampled by Dry Gas Meter dcf 44'1410 Dry Gas Volume at Siandard Conditions dscf 35 7044 Volume of Gas per Minute @ Dry Condtions dscf/min 0 5951 Volume of Water Vapor in the Gas Sample scf 4'0527 Total Moisture Collected in lmpingers and Silica ( g 86 1 Water Vapor in the Gas Stream, Proportion by Volume 0 101 I GP043AS-025822-RT- 1330 EPA Method 4 RUN #2 Page2of 3 Page 47 of 174 1 2 J 4 E 6 Svmbol Bws TEST RESULTS Description Units !!!g'e Volume of Gas Sampled by Dry Gas Meter dcf 44.6580 Dry Gas Volume at Standard Conditions dscf 35.6391 Volume of Gas per Minule @ Dry Condtions dscf/min 0.5940 Volume of Water Vapor in the Gas Sample scf 4.1469 Total Moisture Collected in lmpingers and Silica ( g 88.1 Water Vapor in the Gas Stream, Proportion by Volume 01042 GP043AS-025822-RT- 1330 EPA Method 4 RUN #3 Page3of3 Page 48 of 174 I 2 3 4 5 6 s@l Bws TEST RESULTS Description Units Value Volume of Gas Sampled by Dry Gas Meter dcf 45'3580 Dry Gas Volume at Standard Conditions dscf 36 0184 Volume of Gas per Minute @ Dry Condtions dscf/min 0 6003 Volume of Water Vapor in the Gas Sample scf 4 0057 Total Moisture Collected in lmpingers and Silica ( g 85 1 Water Vapor in the Gas Stream, Proportion by Volume 0 '1001 GP043AS-025822-RT- 1330 EPA Method4 RUN#4 Pagelof 2 Page 49 ol 174 Svmbol 1V. 2 V,*o 3Vm 4 V*s"" 5v" 6 Bws TEST RESULTS Descriotion Units yglCg Volume of Gas Sampled by Dry Gas Meter dcf 44.3140 Dry Gas Volume at Standard Conditions dscf 35.2658 Volume of Gas per Minute @ Dry Condtions dscf/min 0.5878 Volume oI Water Vapor in the Gas Sample scf 4.0527 Total Moisture Collected in lmpingers and Silica ( g 86.1 Water Vapor in the Gas Stream, Proportion by Volume 0.1031 GP043AS-025822-RT-1330 EPA Method 4 RUN #5 Page2of2 Page 50 of 174 MONTROSE AIR QUALTTY SERVTCES, LLC' 6823 South 3600 Wcst Spanish Fodq UT 84660 CVclonlc FIow Determinrtion n nxo.EJx{n*{ ^-nys,* - tlugldil EU + I Pftot ftbc D,,b S//efs - Brr.Prur. (W ?3'1O , PitotTubee laltial: ^- ( -n_T Pitot Tuber Port: A - f,- O*rr*fu r*.r"-v(r fu'f ' sbdcPr:Gs& (ruq ?N srrcklxmcarhu /6/' GP043AS-025822-RT- 1 330 4 Page 51 of 174 EPAmoftod ZllC Datatheet ffiolh 63f, g7a IIEltk AE / dtt Lrtr Soaav Slc lo T.!(- |t"2? ldlhr:So^^,.i S;Jc, . UT hlaraEh''srlrfl*2 3. tlo lffi s4^-L ndatcE ,tr/-be?,rO D trl:<.t |[E.D:c-A Ll*13.7 rbCot.hlE n,(q !rt 3 urrTlE lqr Irlhr rJ7 ffi;ilmFH!l:4.1 ulc.tl*OE b ,/ tGD tolrt r.alfrt fD urb ry4 rrp ,o{1.2 -a 3o6 t,2 -3 306 t.tr a-,16-f l.J -2 30tr ,? -5 3aL t.u 3-'bg 3 -,30.r .:7 -5 30r .( Li-l ltc.r .-( -J 30S .-h -o 9o{LT ]o5.3 l"e'l t{nl 9 Irf ttra ,af : brlLr at, leEnPlld:-o,l 'brtldldtt*{ Tl T. ilm mrltrltt rn t-nr$ |I$-Ot -l 3o!,z -a sa6 t.? -5 30( t.g a-,tot ) -3 Jo(l,G .' -3 9o.s t,v t-l !}5r 2 -a 50c .E uJ 30y .) 1-l 305 1.3 -J 3oi6 .b -?3at so5,t.431 Totrl lnrrfE (0.o) ml lr.rlt lool A.trlp lo.ml Irt{49 (ofiml Rcvie*ad: fmJl-CPM- Page 52 of t74GP043AS-025822-RT- 1 330 EPA Me(trod 2filC Datasheet rdlCfrl o?s (: ?D]fitr&AL ltt ) [aC 5urr.r.r Jidt *g- tE -? LGIIllr:S-v-, , SiJe- UT EutEtftirrrtFlIl:e.3.q O barGt:-\#o- L [n;tse XL-Dea/to L oa}S-L rillDt -H DO&13.7 l-0fildr*o.rLl tf,r I 5 IrrtTll:Egz tEft .tl o't Ittkrr.3tf&Ot .o. I '6Idlrldl*t/ T'.n!! tdn tr..lT.q flt Utbqf, Fttd I-t 305 .4. -f,309 l.c e5 30C l.vt-f 3os .3 -l 30("t.c -3 30f t.7 3-t 3os-,.3 -1 s6 1,6 -3 30.C t." t{- |%,5 i.3 -)305 t.c-3 30c t.-? t7 .bss I r3t Tot l aEr.!! 10.0) Ary{Ae lo.fuo, r: r'. \. \ I GP043AS-025822-RT- 1 330 acrr lo,0l frtqr tlrol RarlGsred: FPl, CPM Page 53 ofTTT EPA Ioftod 2ZC Oattlrreet Eu OISI e) Lc 5 u^^.tt criltaD - E}--r-__ l.Fll*lcprrrlrf|,|[ k / Jt") UftJ!$ r, n"ut S iJL::iT EE bl'A sfq.T--:.lc - e<.J.1O ,tm lqlrt:D:YL-8?am!hE:[{rh L-AhrOfirro.8\ ria t rtIID bP-E! F[&thrr:l1t€[ bnt*ldci.r& Dirrr htr ltrttl.n, m rtbdu., rllot Tot l AtrF-....E ri.: ,.ir ., i GP043AS-025822-RT- 1 330 loJ, to.o0ol O.o) @.mt (oo) (ooml Artt,.? (omf tlrTt 10!l Ra,Br.e [frpr ZtnL EPA Method 4 Datasheet XF, oourrmrlrt lmpln3Cr lmdr8lr lmplilrr lmplryrr lmplnEEr { lmplnjar lmplryu lmptglr lmplrE:r lmplElrr Auarr!: totrl (0.0) . (0.000) fot.l (0.0m) ArCrrtic (0.0) GP043AS-025822-RT- 1330 PuBs,:IgJ lzs. "ot' EPA Method 4 Dataeheet {r-ilr !mplrECt !mpixpr lmplrfrr ]mPllrltr Irnpln3.rl lmphBCl lmCr[cr lrnCnlrr tnp|nicr lmplnt.ra AEnt! Tonl(o.o) (0.oo0l AErrlG Total lo.ol {o.w} GP043AS-025822-RT- 1 330 Paqf-$qpJ.l24., Company:Run Number: I Sampling Locaton:;fuf Date: f- 16'e 9 MONTROSE AIR QUALITY SERYICES, LLC. 6823 South 3600 West Spanish Fork, UT 84660 Moisture Data (EPA Method 4) Moisture Collmted Impinger 1 Impinger 2 Implnger 3 Impinger 4 Initial Weight 7oq. t Lsa.t CrH.r 7cl l.g 75',t,8 Weight Gain e -g g g Final Weight 1LlLl.1 1rz.t rotal Gain (vw) BS.b , GP043AS-025822-RT- 1330 Page 57 of 774 MONTROSE AIR QUALTTY SERVTCES, LLC. 6E23 South 3600 West Spanish Forlq UT 84660 Moisture Data (EPA Method 4) compony: Sg art,. S:Je Run Numbu", J Snmpling Locafion: 5*a aL o"t", f- I /: ) 3 Moisture Collectcd Inidal Weight FinalWetght Weight Gain rmpinger t 7-lLI 711 ,L' _ s Impinger 2 Impinger 3 rmpinger 4 7aC.(g Totat Gain (vw) 86 't , 693. I bo.q,_ -t1,7- _ g [o?.{- s 1s8.< _ GP043AS-025822-RT- 1330 Page 58 of 174 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West Spanish Fork, UT 84660 Moisture Data (EPA Method 4) compauy: 5 o-nnys i) e - samolins Loca6on: Slq" L 3Run Number: Date:e- U -t3 Impinger 1 Impinger 2 Impinger 3 Impinger 4 Initial Weight 7',lll.l 713. A e 2l.o ,_ 2l'1. ( Molsture Collecte.d Flnal Weight 797 6 t-t t ,{ 6 tg -'/ %+J$\ lLtl'b Totar Gain (vw) Weight Gain -8 -g B Effit , GP043AS-025822-RT- 1330 Page 59 of 174 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West Spanish Fork, UI84660 Moisture Data (EPA Method 4) rber: q sampring t*rar , .frcb Gu *l) orr,., .S//(/fS/' Initial Weight Moisture Collected FiDaI Weight Impinger 1 Impinger 2 Impinger 3 Implnger 4 -71rO,c L1.,5.L -bo4j .96.c '7 - 7^{ Aot o Weight Gain -g _g g g fu,= ._r 74 7.3 Total Galn (Vw) GP043AS-025822-RT-1330 Page 60 of 174 MONTROSE AIR QUALITY SERVTCES, LLC. 6823 South 3600 \trest SpanishFor{q UT 8ffi0 Run Number:t) (EPA Method 4) Inifial r#eight 10n,7 6(2,7 6/7. t 6ffiq Impinger I Implnger 2 Impinger3 Impinger4 Moisture Collected - <rf 6"1 .{ Weight Gain g e I g ff7,"1 ,Total Gain (Vw) GP043AS-025822-RT- 1 3 30 Page 61 of 174 Appendix A.3.2 fnstrumental Test Method Data MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unit EU # l 05t16t23 Stratification Date and Time 5116123 7:46 5116/23 7:47 5116123 7:48 5116123 7:49 5116123 7:50 5116123 7:51 5116123 7:52 5116123 7:53 5116123 7:54 5116123 7:55 5116123 7:56 5116/23 7:57 51161237:58 5116123 7:59 5116123 8:00 5116123 8:01 5116123 8:02 5116123 8:03 5116123 8:04 5116123 8:05 5116123 8:06 5116123 8:07 5116123 8:08 5116123 8:09 5116123 8:10 5116123 8:11 5116123 8:12 NO, (ppm) 101 .9 102.2 111 .7 1'1 1.0 109.9 104.7 1 09.1 105.7 '109.5 1 09.1 107.7 '106.6 106.9 108.0 108.9 110.8 110.9 109.4 107.8 109.9 108.7 107.8 97.8 99.6 125.2 107.2 111.0 co (ppm) 20.2 20.3 20.3 20.2 20.1 20.2 20.2 20.0 20.3 20.1 20.0 20.0 19.8 19.7 19.7 '19.9 19.9 20.1 19.8 19.9 19.8 20.5 914 53.9 21.3 20.5 206 s02 (ppm) 98.9 83.4 74.8 76.2 76.6 84.9 86.4 78.7 77.9 86.2 79.9 75.9 79.0 77.7 68.1 71.2 69.6 75.1 69.1 66.5 74.5 75.7 212.4 59.8 60.3 81.9 69.2 Oz t%) 5.5 5.7 5.8 5.8 5.7 56 6.1 5.7 5.7 5.6 5.7 5.7 5.7 6.4 5.8 5.7 5.8 5.6 5.6 5.7 6.3 5.6 5.2 6.0 5.8 EE 5.7 COz tJ6) 14.0 '13.9 13.8 138 13.9 14.0 12.7 13.9 13.9 13.9 13.9 13.8 13.9 12.2 13.8 13.8 137 13.9 't4.0 13I 12.3 13.9 14.2 13.5 13.7 13.9 13.9 Avg Avg Avg 106 9 107.6 109.6 Avg 1 08.1 Total Avg 108 0 GP043AS-025822-RT-1 330 Page 63 of 174 $Ndo\t \oG, )c' loCL o9 9 u ' l \ o q : q q q oo @ @ o @ s @ t s N qN q \ o s a q q a -N O r r N @ r - N N- N N N N F N N N o\ c ? . ! q q u ? @ q q so o s s 6 0 0 s 6 :\ . ! - o q @ a 9 o q q $o o n o $ o o o t N- N N N N N N N N oo o o o o o 6 0 ! EE E E E E E E E E EE E E E E E E E E DO O O O O O O O ! oa o o- o o - o o o a o !! o o o o o o ! o - - 4 6 0 - - o o o EE E E E E E E E E EE E E E E E E E E EE E E E E E E E E EE E E E E E E E E €9 _ o 9 9 e _ o 4 ! ! 99 ! e e e e e e ! ON 6 O O T O - O S NO 6 @ O @ O O S N O @ @ O O O @ 9 N N Vn N N O @ s O O @ @ O O O T o S N O n @O N O - @ N @ $ - @ O N N @ - O N $ F @@ @ @ N @ @ O @ @ N @ - N N O O N N O r: r : l - : : : t oo o o o o 9q o o q q q q q o oo o o o o o o o o N@ O F N N N { N N Ot s N O N O @ O O - Or N O @ S @ @ N o -t I : . ! - - - c ! . ! oo o o o o o o o o -N O S O @ N @ O O ** * * * + * * t I cc c c L EE E E d E E E I ) vv 9 C oo o o o o o o o A a@ @ a a @ a a a 3 cc q c 9 9 . ? t q \ oo N o o @ N o t N -N N O N N O N ! 3 rN O { O @ N @ O O +* + * + + + + s F c< * lr r f f f r r l c Eg t E t E t t g a vv J E NN N N N N - oo o o o o o o o l 6@ @ A A @ @ A A 3 d6 o o o o o o o o oo o o o o o o o o oo o o o o o o oo o o o o o o o6 0 6 0 b 9. 9 . 9 9 . 9 . 9 9 . q 9 9 oE a o a a o o o ! ;i - : - - i ' 3 ' EE E E E E E E E E oo o o o o d o o o oo o o o o o o o o N- o o @ \ 9 q s g OF r O @ N I O O O N@ @ @ @ @ @ @ 6 0 -N O S 6 @ N @ O O +* * * * + + * * r cc c c c c c c c * lS f f , 5 t f f f c ET E E E C V E X . .v . v J E NN N N N N N N N - oo o o o o o o o ! @@ @ @ @ @ a @ 4 3 = A A' G . 6 6 ' F 6 ' 6 ' A t* & & t & * U & r cc c c c c c c c + f3 5 r ) ) a ) a c Ed E E E E X E T 2 oo o o o o o o o : oo o o o o o o o 9 €n ; N o s o o o @ o N o qe ? NN @ @ o o @ @ @ r i aL \ u o o o o o o o o o o o6 l :' : : " .a 6 ? 6 6 S 6 ' 6 ' 6 a3 9 l + + + + * * * * *: i3 5 s s s s 5 5 5 5 5 : =o t u t d d d d t d ) CO v v v v v E o_ x x x x x x x x x - o oo o o o o o o o x zz z z z z z z z z EE E E E E E E oo o o o o o o oo o o o o o o c! f . J \ . ? . ! r : c ? c NF 6 @ t o@ @ o o @ @ @ !D O D E E O O O E EE E E E E E E E E oo o o o o o o o o oo o o o o oD E a ! b E o t o EE E E E E E E E E oo o o o o o o o o oo o o o o o o o o 9u 2 c ? q @ o @ - s o @@ O - F - O O @ @ oo r r r - F - o o -d O t O @ N @ o o +t * + t * * + + - cc c c c c c c c * tf f f l S t r f t r c Gt t x E s u E u ? xx x x x x x x x - oo o o o o o o o x zz z z z z z z 2 9 . -N O 3 O @ N @ O O T N O t O @ N @ O O ** * * t * * * + - * * + + + + + * + - cc c c c c c c c * s c g c c * ll l f l l l r l c J f , 3 f , J l f r j c EE E T E E E T T ? X T E E E E g E E . 9i 9 9 9 9 9 9 9 6 88 8 8 8 8 8 8 8 8 -N O S O @ N @ O O F N O n O @ N @ O O ** * * + + * + * = * + + * r * * * * F cc c c c * . - . c c $ fS l t f l l j f c f > f f l l l r r c EE E C E E T T E 2 E E E E E E E E E ? , x x x x x x x x x - oo o o o o o o o x oo o o o o o o o x 66 ( l O O O 6 c - r l - ) < , r zz z z z z z z z 9 9s s 9 g E o . g . s O 9s . 0 . 0 . 0 9 . 9 . { r d , s p s 9 s s 9 g ! p !) oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o LE T L E T E E E T EE E E T E T T T E E b E E E E E E E E oo o o o o o o o o o o o o oo o o o o o o o o o o o o o d d o o o o o o o o o o o o o aa o @ o o a a 6 b o a o a a a oo o o c o o o c o o o o o o 6 0 6 0 0 6 6 0 0 0 0 0 0 0 0 Eo : o E . 5 E - 6 ; - E -6 - 6 E 5 - 6 5 5 - 6 5 - 6 . E b' a b b E o A E OI E D I E D E O E EO O O E ! O E D E !E E I E E O D ' D EE E E E E E E E E EE E E E E E E E E E E E E E E E E E E oo o o o o o o o o o o o o o o o o o d o o o o o o o o o o oo o o o o o o o o o o o o o o o o o o o o o d o o o o o o r. ! @ q q < . \ q N c q @o o o @ N o o o Q @o o o o o o @ o u rN o S 6 @ N @ O O +* * $ * * * + + - cc c * lt t f > f f f J c EE T E E E g d T ? , NN N N N N N N N - oo o o o o o o o A aa @ a @ @ @ a @ Y a =a a e 6 6 ' c a 6 6 ++ t t * * s t * - cc c c c c c c c * fl l r f 5 f f : c gE E E T E E T T ? oo o o o o o o o : OO O O O O O O O 9 @N @ O 6 - N N @ S ai 6 i o i c i c t : o i o i N a ; OO O - - - O O O O -N O $ O @ N @ O O *$ e * + * * + + - cc c c c c c c c * 3J > l f l f l l C ug E E e e d t s _ - xx x x oo o o o o o o o x rN O t O @ N @ O O e N O S O @ N @ O O +* t + + * + + + r + * t + * + * t * r qs g E E s g s s : E E s E E s E g s l E& T E G E G E E . ? E E T V E E d E 8 . 1 OO O O O O O O O : N N N N N N N N N - 56 6 5 6 6 - 6 5 Q Q o q q o q o o o x o@ @ @ @ @ @ @ a a 3 €€ € € € € € € € € 60 6 6 60 0 ! o o o o a o !! € ! e € g - o ! € q: o q q q r r 6 o o@ e o @ o F s N @ OO r - O O F e r O oo o o o o o o o o o o o o o o o o o o oo o o o o o o o o o o o o o o o o o o oo o o 83 8 8 8 3 3 3 8 8 3 8 3 3 3 8 3 3 8 8 oo s o o o o o o G o o G 6 G 6 0 0 0 6 bE . b o - - o E . EE E - 6 . 5 5 o n . 6 o }B B ; 3 ' } B ; ; ;; ; ; ] ; 3 ; ' ; EE E E E E E E E E EE E E E E E E E E oo o o o o o o o o o o o o o o o o o o oo o o o o o o o o o o o o o o o o o o oc' )Fd.NN@IANoarf )$oo(J EE oo eEE0ce.2Eu0o€ e ; oO l a( ! u E@ = o6 f .* E Fc i ; FO3o o $F. dotn\ooo)ocorf ) ra ilFd. r\N@t)Noaro<foo(9 i €€ € € € € € € € € !4 e 9 9 - o € 4 4 4 O< D O O O N F @ - Nd i d i ^ i a i r i N c i d t s oF o N o o o o o 6 oo @ @ o N N S O @ 66 - 6 N o N @ @ o <9 O t < i o 6 o o ;d d < 6 6 N @ O o rr l t t t t t ! s fr t f J f f f l L vG E E E U E E S ^ . i NN N N N - oo o o o o o o o x o( . ) o o o o o o o S TE E E E O O E ! E oo o o o o o o o o uo o o o o o o o o oo o o o o o o o o EL T E E T E E E t r oo o o o o o o o o oo o o o o 60 a o o o .a . a . Q . q . q . g . g .9 . 9 .q EO O O O a D O O O ;i i ! ; ; ! i ; ; ss s s s s s s s s r- E o o o ! E o o oo o o o o 60 0 0 0 0 0 0 @ Q Ft s E E E E E E E t r oo o o o o o o o Q oo o o o o o o o o o@ a a o o 66 6 G O O -a - 6 5 " 6 . 6 - 6 E 5 E E r; i i ' ; ; ' ; . ss s s s s s S s s ;N 6 n 6 @ N @ O O ** * * * * * + + = EE E g E g E E E : eg e d _ e e _ d _ e e _ a NN N N N - oo o o o o o o o x oo o o o o o o o u *E i - o r : q o g o o r o ? >N 6 . o o o t n o o s t '. ". . = a 6 6 t 6 ' a c 6 ' 6 4 >g 9 l * + * * * + + * + = iS g s s s s s s s s s E 2_ 6 G e E E E T E E d P , a6 - o- ' r u N N N N - o oo o o o o o o o S EE I O O E E E E O oo o o o o b i ) d o o o o o o o oo o o o o o o o 9 TE E I E E E E E E oo o o o o oo d o o o o o o o ao a a a 6 6C G 6 0 0 EE 5 5 5 E E 6 E E ss s s s s s s s s bE E I O O O E O E dr o o o o o o o o o i, d o o o o o o o o oo o o o o @ o o o 88 8 8 3 8 8 8 3 8 aa 6 a o a d d 6 6 c o G 6 o , o 6E - 6 5 - 6 - 6 E 5 . 6 5 .O O E O O E D D E ss s s s s s s s s oT O O O N - r O - Fi s r i a i r + + i t 66 N @ O e *+ + * * + * + * 5 cc r c c * ti E E E e E E s : i Nd N N N N N N N : - oo o o o o o o o A oo o o o o o o o i j t! D D ! O ! ! O O ss s s s s s * s s ;d 6 < 6 0 N O O O ** + + * * * + + E cc c c c * EE E T E E T E V ' NN N N N Y oo o o o o o o o x oo ( J o o o o o ( ) S 6E E O O O ! E ! O ss s s s s s s s s 3* 5 9, R ? . 9 q q c ? 9 r 9 t o c- < * 6 6 0 6 0 0 0 6 0 0 .; 8 5 .. ': .. a a 6 ' e 6 ' 6 ' c 6 ' A a >. 9 q * + * + + + + * * - EE g s s s i E i = s s E =6 d u E x t t E t t - a c 6- g- - N N N N N - o oo o o o o o o o g N6 t s t s S O O O O l ri r i r i o r i . r i r i r r r i o O@ @ O 6 N F F @ F .i 6i 6 i 6 i . i . i .i 6i . i 6 i NO O @ N @ ci d i c i a i d r a i c i c i r i ;t u 6 + 6 6 N 6 0 0 +* * + * + + * + 5 cc c c t * EE & E g E C E E . ' NN N N N - oo o o o o o o o S aEIoE"9IEUooo MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unil EU #1 05t16123 Run #1 Rata Date and Time 5116123 8:23 5116123 8:24 5116123 8:25 5116t23 8'.26 5116123 8:27 5116123 8:28 5116123 8:29 5116123 8:30 5116123 8:31 5116123 8:32 5116123 8:33 5116123 8:34 5116123 8:35 5116123 8:36 5116123 8:37 5116123 8:38 5/16/23 8:39 5116123 8:40 5116123 8:41 5116123 8:42 5116123 8:43 Average : NO, (opm) 105.0 104.5 104.7 110.2 112.1 1 10.5 '108.4 106.6 107.3 111.8 107.5 106.4 105.7 112.5 111.2 107.2 119.2 1 13.3 99.9 103.4 109.4 108.4 co (ppm) 20.2 20.3 20.1 20.3 20.2 20.1 20.2 20.2 20.1 20.3 200 20.0 't9.9 19.9 19.7 89.0 35.1 20.3 19.8 19.9 19.8 24.1 so2 (ppm) 79.5 73.4 72.8 62.1 65.9 76.3 76.0 83.2 83.3 75.7 90.4 87.3 90.6 80.0 81.9 154.4 61.0 88.7 98.3 83.6 82.3 83.2 Oz tYe) 5.6 5.6 5.7 5.7 5.7 5.7 5.6 5.6 5.6 5.8 5.5 5.6 5.6 5.7 5.7 5.5 6.0 5.5 5.4 5.6 5.7 5.6 COz Itr) 13.8 't3.8 13.7 13.7 13.7 13.7 13.7 13.7 13.7 13.6 13.8 13.7 13.7 13.7 13.6 13.8 13.4 13.7 13.9 13.7 13.6 13.7 GP043AS-025822-RT- 1 330 Page 66 of L74 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unit EU #'l 05t16123 Run #2 Rata Date and Time 5116123 8:58 5/'16/23 8:59 5/16/23 9:00 5116123 9:01 5116123 9:02 5116123 9:03 5116123 9:04 5116123 9:05 5116123 9:06 5116123 9:07 5116123 9:08 5116123 9:09 5116123 9:10 5116123 9:11 5116123 9:12 5116123 9"13 5116123 9:14 5116123 9:15 5t16123 9:16 5t16123 9:17 5116123 9:18 Average:109.9 23.8 NO, (pom) 110.8 '108.5 109.0 113.4 109.5 108.8 108.6 108.8 111.5 1 10.5 104.4 1 10.0 121.0 102.1 115.1 115.3 107.7 108.9 110.1 110.3 103.6 co (ppm) 19.7 19.7 19.8 19.7 19.5 19.6 19.4 19.4 19.4 19.5 88.9 34.4 20.5 20.1 20.4 20.2 19.8 19.9 20.0 20.2 20.1 82.9 84.2 75.2 75.0 79.8 79.8 84.3 82.2 75.8 95.7 200.5 68.2 92.2 81.8 59.8 70.5 71.4 74.6 83.6 95.4 87.7 85.7 13.7 13.8 13.6 13.7 13.7 13.7 13.7 13.7 13.6 13.7 14.0 13.4 13.9 '13.9 13.6 13.8 13.8 13.7 13.8 13.9 13.8 13.7 SO2 Oz COz (ppm) tb lft) 5.5 5.5 5.6 5.6 5.5 5.7 5.7 5.6 5.7 5.6 5.2 6.0 5.4 5.5 5.8 5.6 5.6 5.7 5.6 5.5 5.6 5.6 GP043AS-025822-RT-1330 Page 67 of 174 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant: Sunnyside Source : Unit EU #1 Dale: 05116123 Run : Run #3 Rata Date and Time 5116123 9:48 5116123 9:49 5116123 9:50 5116123 9:51 5116123 9:52 5116123 9:53 5116123 9:54 5116123 9:55 5116123 9:56 5116123 9:57 5116123 9:58 5116123 9:59 511612310:00 5116123 1O:O1 5116123 10:02 5116123 10:03 5116123 10:04 5116123 1O:05 511612310:06 5116123 10:07 5116123 10:08 Average : NO, (ppm) 108.3 110.5 114.0 111.2 110.8 1'10.9 111.0 110.2 109.4 115.8 113.5 112.4 111.5 111.2 110.7 109.9 109.6 109.3 106.0 107.8 101 .9 1 10.3 co (ppm) 19.8 19.6 19.9 19.8 20.0 20.0 20.1 20.2 20.0 20.3 20.2 20.2 20.0 19.9 20.0 19.9 20.0 19.8 19.6 19.8 88.7 23.2 so2 (ppm) 85.5 80.6 66.1 71.2 73.9 77.3 72.7 77.6 68.2 69.1 68.3 68.1 81.7 83.2 75.6 82.1 76.8 93.7 93.0 96.6 216.2 84.7 Oz t%) 5.5 5.6 5.7 5.6 5.6 5.6 5.6 5.5 5.7 5.7 5.6 5.7 5.6 5.6 5.6 5.5 5.6 5.5 5.5 5.5 5.1 56 COz tft) 14.0 13.9 13.8 13.9 13.9 13.8 13.9 14.0 13.8 13.8 13.8 13.8 13.8 13.9 13.8 13.9 13.8 13.9 13.9 13.9 14.2 13.9 GP043AS-025822-RT- 1 330 Page 68 of 174 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant : Sunnyside Source : Unit EU #1 Date: 05116123 Run : Run #4 Rata Date and Time 511612310:23 511612310:24 5116123 10:25 511612310:26 5116123 10:27 511612310:28 511612310:29 511612310:30 5t1612310:3'l 5t16123 10:32 5116123 10:33 5116123 10:34 5t16123 1O:35 5t16123 10:36 5116123 10:37 5116123 10:38 5116123 10:39 5116123 10:4Q 5116123 10:41 5116123 10:42 5116123 10:43 Average : NO' (ppm) 133.3 112.4 110.8 110.'1 109.6 107.0 110.7 107.8 106.5 111.0 1 13.5 111 .3 't 1 1.0 109.6 '108.1 106.4 118.4 115.1 101.5 104.6 112.0 11 1.0 co (ppm) 18.2 19.8 20.0 19.9 20.0 20.0 20.0 19.9 19.8 19.9 19.9 20.0 20.3 20.3 20.0 87.4 38.3 20.8 20.2 20.5 20.4 24.1 so2 (ppm) 59.7 75.8 71.3 80.4 86.8 78.2 76.8 90.0 90.6 84.7 91.8 81.5 83.5 85.3 79.1 181.4 66.9 98.5 106.9 80.7 83.9 87.3 Oz tb) 5.6 5.6 5.6 5.6 5.5 5.6 5.6 5.5 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.4 5.9 5.5 5.4 5.6 5.6 56 COz t%) 13.7 13.8 13.7 13.8 13.9 13.8 13.8 13.9 13.8 13.8 13.8 13.7 13.8 13.8 13.7 13.9 13.5 13.8 14.0 13.8 '13.8 13.8 GP043AS-025822-RT- 1 330 Page 69 of 174 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant : Sunnyside Source : Unit EU #1 Date:. 05116123 Run : Run #5 Rata Date and Time 511612310:57 511612310:58 511612310:59 511612311:00 511612311:01 511612311:02 5116123 11 03 511612311:04 5116123 11:05 5116123 11:06 5116123 11:O7 511612311 08 5116123 11:09 5116123 1'l 10 5116123 11:11 511612311 12 5116123 11 13 511612311:14 511612311:15 511612311:16 511612311:17 NO, (ppm) 118.0 115.8 112.4 109.8 107.4 112.2 114 .8 109.2 1 10.0 117.8 100.7 106.8 120.0 103.0 112.9 115.7 113.9 113.0 111.3 112.2 111.2 20.9 20.6 20.6 20.5 20.2 19.8 19.9 19.8 19.8 20.2 81.7 33.0 20.7 20.5 20.8 20.3 20.5 20.2 20.3 20.3 19.8 23.8 68.0 79.3 89.5 96.9 88.5 83.3 97.8 9s.5 85.5 87.1 206.s 70.5 89.8 109.5 73.6 74.1 81.6 82.3 88.1 85.1 82.1 91.2 Oz t%) 5.5 5.4 5.5 5.3 5.3 5.5 5.4 5.3 5.5 5.4 4.9 5.7 5.3 5.2 5.5 5.5 5.5 5.4 5.4 5.4 4.2 5.3 COz t%) 13.7 13.8 13.7 't3.9 13.9 13.7 13.9 13.9 13.7 13.9 14.3 13.6 13.9 14.1 13.8 13.8 13.9 13.9 13.9 13.9 10.2 13.7 co so2 (ppm) (ppm) Average: 111.8 GP043AS-025822-RT- 1 330 Page 70 of t74 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant : Sunnyside Source : Unit EU #'1 Date:. 05116123 Run : Run #6 Rata Date and Time 511612311:31 5116123 11:32 511612311:33 5116D311:34 511612311:35 511612311:36 511612311:37 511612311:38 511612311:39 511612311:40 5t1612311:41 511612311 42 5t1612311:43 511612311:44 511612311:45 511612311:46 511612311:47 511612311:48 511612311:49 511612311:50 511612311:51 Average : NO, (ppm) 110.9 112.4 115.4 113.3 112.4 1 1't.6 109.9 104.5 '104.6 123.4 104.4 109.8 1 15.6 108.8 111 .5 111.5 113.4 1 15.0 115.5 't13.5 111.9 111.9 co (pom) 20.8 20.8 20.9 20.6 20.6 20.6 20.7 80.9 46.7 21.2 20.7 21.1 20.8 20.6 20.6 20.4 20.6 20.5 20.5 20.5 20.7 24.8 so2 (ppm) 85.9 79.2 80.7 79.7 75.0 101.0 95.1 197.3 66.5 77.2 107.2 73.9 80.7 74.2 86.8 75.1 80.8 70.5 79.5 72.3 82.4 86.7 Oz t%) 5.3 5.5 5.4 5.4 5.5 5.2 5.2 5.0 5.7 5.4 5.3 5.4 5.4 5.4 5.3 5.5 5.4 5.5 5.4 5.4 5.4 5.4 Coz t&) 13.9 13.8 14.0 13.9 13.9 14.1 14.1 14.3 13.7 14.0 14.2 14.0 14.0 14.0 14.1 13.9 14.0 13.9 14.0 14.0 14.0 14.0 GP043AS-025822-RT- 1 330 Page 7t of t74 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unit EU #1 05116t23 Run #7 Rata Date and Time 511612312:15 511612312:16 511612312:17 511612312:18 511612312:19 511612312:20 511612312:21 5116123 12:22 5116123 12:23 5116123 12:24 5116123 12:25 511612312:26 511612312:27 511612312:28 511612312:29 511612312:30 5116123 12:31 51161231232 511612312:33 511612312:34 511612312:35 NO, iopm) 108.4 107.0 109.0 110.9 109.8 111.3 110.6 '109.5 109.5 108.1 107.'l 112.0 1 1'1.9 110.5 110.9 112.2 112.4 113.2 114.2 113.8 109.9 co (pom) 20.9 20.9 21.0 21.0 20.9 21.0 21.1 20.6 20.6 20.5 20.5 20.5 20.2 20.0 20.1 19.9 19.8 19.7 19.7 19.8 19.9 20.4 so2 (ppm) 82.1 88.7 85.5 78.2 65.7 74.3 71.9 77.6 83.6 90.1 97.0 96.8 99.4 98.4 102.7 90.8 88.3 86.3 88.6 99.5 107.9 88.3 Oz tb) 5.3 5.4 5.4 5.4 5.6 5.4 5.5 5.4 5.3 5.3 5.3 5.4 5.4 5.4 5.3 5.4 5.5 5.5 5.5 5.4 5.3 54 Coz t&) 14.1 14.0 14.0 14.0 13.8 14.0 13.9 13.9 14.0 14.0 14.0 14.0 13.9 14.0 14.0 13.9 13.9 13.9 13.8 14.0 14.0 13.9Average : 110.6 GP043AS-025822-RT- 1 330 Page 72 of 774 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unit EU #1 05t16t23 Run #8 Rata Date and Time 5116123 12:50 511612312:51 511612312:52 511612312:53 511612312:54 511612312:55 5t16t2312"56 5116123 12:57 511612312:58 511612312:59 5/16/23 13:00 511612313:01 511612313:02 511612313:03 5116123 13:04 5t16t23 13:05 511612313:06 511612313:07 511612313:08 5/16/23 13:09 511612313:10 Average: NO, (pom) 112.2 112.9 111.9 113.1 1 13.6 115.2 112.0 111.5 111.6 't 10.3 109.9 109.9 110.0 105.3 105.9 106.5 108.0 107.3 104.2 106.0 1 15.8 110.1 co (ppm) 19.7 19.7 19.8 19.5 19.7 19.7 19.9 20.0 20.1 20.2 20.0 20.3 20.6 20.6 20.8 20.6 20.6 20.7 78.4 38.6 20.7 23.8 so2 (ppm) 91.3 90.1 83.0 94.8 83.5 87.0 80.7 74.6 75.0 73.1 77.2 72.2 75.9 83.8 71.3 76.7 75.7 75.7 166.9 62.8 93.4 84.0 Oz t%) 5.4 5.4 5.5 5.4 5.4 5.4 5.5 5.5 5.4 5.5 5.5 5.5 5.4 5.4 5.4 5.4 5-4 5.4 5.1 5.8 5.3 54 COz tft) 13.9 14.0 13.9 13.9 13.9 13.9 13.8 13.8 13.9 13.8 13.8 13.8 13.8 13.9 13.8 13.8 13.9 13.8 14.0 '13.5 13.9 13.8 GP043AS-025822-RT- 1 330 Page 73 of L74 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unit EU #1 05t16t23 Run #9 Rata Date and Time 5116123 13:24 511612313:25 511612313:26 511612313:27 511612313:28 5116123 13:29 511612313:30 5116123 13:31 511612313:32 5116/2313:33 5116123 13:34 5116123 13:35 51161231336 511612313:37 5/16/2313:38 511612313:39 511612313:40 511612313:41 511612313:42 5116123 13:43 511612313:44 Average : COz t%) 5.43 13.72 5.42 13.72 5.51 13.64 5.55 13.60 5.55 13.62 5.53 13.61 5.46 13.67 5.39 13.74 5.42 13.69 5.34 13.77 5.43 13.68 5.53 13.63 5.44 ',t3.67 5.42 13.69 4.97 14.05 5.77 13.41 5.48 13.65 5.23 13.91 5.40 13.73 5.36 13.73 5.29 13.84 NO, (pom) 109.38 108.26 108.81 1 09.1 5 110.04 1 11.58 111 .72 't09.49 107.53 106.25 106.25 107.32 108.77 109.13 101.48 105.09 121.40 102.67 '109.54 107.69 105.41 20.05 19.96 19.74 19.92 19.80 19.93 20.11 20.09 20.04 20.12 19.93 19.93 19.83 19.80 77.61 39.05 22.14 21.50 20.17 19.98 19.82 90.07 90.82 89.93 85.30 82.84 82.59 86.26 91.14 85.3'l 92.71 85.46 84.99 88.22 97.10 177.70 66.83 97.91 '109.55 91.52 99.29 100.32 94.1 CO SO2 Oz (pom) (oom) Un 't08.4 23.8 13.75.4 GP043AS-025822-RT- 1 330 Page 74 of 174 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant : Sunnyside Source : Unit EU #1 Date: 05/16/23 Run : Run #10 Rata Date and Time 5116123 14:O0 5116123 14:01 511612314:02 5116123 14:03 5116123 14:04 5116123 14:05 511612314:06 511612314:07 511612314:08 511612314:09 5116123 14:10 5116123 14:11 511612314:12 5116123 14:13 5116123'14:14 511612314:15 511612314:16 5116123 14:17 5116123 14:18 51161231419 511612314:20 Average: NO, (ppm) 108.6 107.0 107.6 107.7 107.3 107.4 107.5 105.0 105.2 101.4 124.6 107.4 '105.0 1 06.1 105.5 104.5 103.2 103.9 105.6 107.0 108.5 106.9 co (pom) 19.5 19.3 19.3 19.1 19.2 19.2 19.4 19.2 86.0 55.0 22.0 19.6 19.7 20.0 20.2 19.9 '19.9 20..0 19.7 2o.o 19.9 24.6 s02 (opm) 88.5 87.8 94.4 98.0 92.5 88.7 93.6 100.7 229.6 75.5 79.7 102.0 81.9 79.6 86.2 99.4 89.9 82.3 84.1 80.4 83.3 95.1 Oz t%) 5.4 5.4 5.3 5.3 5.4 5.4 5.3 5.3 4.9 5.8 5.6 5.2 5.4 5.4 5.3 5.3 5.3 5.4 5.4 5.4 5.4 5.3 COz tb) 13.7 13.7 13.8 13.7 13.7 13.7 13.8 13.8 14.1 13.4 13.6 13.9 '13.8 13.7 13.8 13.9 13.8 13.8 13.7 't3.7 13.7 13.8 GP043AS-025822-RT- 1330 Page 75 ol L74 I il il Appendix A.4 Example Calculations rl i I l i sunnyside cogen EUl slL6l2023 Run #1 Samplc calculations EPA Method 2: Determination ot Stack Gas velGity and volumetric Flow Rat€ (40 CFR Parr 60, Appendlx A-11 Variable Value )eflnltlon Unit of Measurem€nt D.101.0 ;tack Diameter inches 55.638 )ross-Sectional Area of the Stack ft2 P.-0.10 ;lack Static Pressure in. H2O P.-0.01 ;tack Static Pressure in. Hg o/oCOz 137 loncntEtion of Carbon Dioxide Dry Volume Percent (%vd) %oz 56 )oncenfaton of Oxyqen Ory Volume Percent (%vd) Md 32.22 )ry Mol€cular weight of the Stack Gas lb/lb-mole 0.101 ;tack Gas Molsture Content (From EPA Method 4)o/o HQ t100 M,30.78 \ctual Mol6elar Weight of the Stack Gas lb/lb-mole Pu.,23.9 larometic Pressure in Hg Ps 23.A9 \bsolute Stack Prssure in Hq T 302 75 Werage Stack Temperature .F Tq:ut 763 \veEge Absolute Stack Temperalure Kp 85.49 Faclor (fusec) x v(((lbIb-molexin. HgxcRXin.Hro))) Cp 0.84 )itot Coefflcient Dimensionless AvgVAp 1.2416 Werage Square Root of Velocity Head Readings in H2O 90.8 \v€rage Stack Gas Velocity fusec T,.o 528 ;landard Absolule Temperature P,ro 29.92 ;tandard Absolute Pressure in. Hg o y Volumetric Flow Rate Corrected to Standard Conditions dscf/hr GP0434S-025822-RT- 1 330 Page77 of t74 Sunnyside Coten EUI slt6l2023 Run fl Sampl€ Calculations EPA Method 2: Determination ot Stack 6as veloclty and Volumetric Flow Rat€ (40 CFR Pan 60, Appendix a-11 ^. nloJ2|f nl7o7l24l^2 = 55.538 ft^2 \= Pcl136 = -0.1/13.6 = -0.01in. HB (0 44 x %COr) + {o.32 x o/oOr\ + (0.28 x %Nr) (0.44 x 13 7) + (0.32 x 5.6) + (0.28 x87.13) 32.22 lb/lb-mole Mdx(1-B*i)+ (18.0x8*) 32.22x(1 -O.1O1\ + (18.0x0101) 30.78 lb/lb-mole Pt., t Pg 239+(-001) 23.89 ln. Hg 460 + T, 460 +302.75 763 R Ke x Ce x AvgVAp x (Eq. 2-6) (P, x M.) 763 85.49x 0.84 x 12416x (8€-fi30:76- 90.8 rtlsec (Eq. 2-7) 3600x (1-8.,) x(V,) x(A)x (T.rdxP.) (Tr", , P".) 3600 x (1 - 0.101) x (90 8) x (55.64) x (528 x 23.89) (763 x 29.92) = 9.038E+05 dscf/h.lEq. 2-8) a= GP043AS-025822-RT- 1 330 Page 78 of t74 SunnYside Cogen EUl slt6l2023 Run s1 samPle calculatlons EpA Method 4: Determlnation of Moisture Conceotratlon in Slack Gases (40 CFR Part 60, Appendix A-31 , P-=P0.,+(AH/13.6) = 23 9 + (1 5/13.6) = 24.01 In. H8 Td.460+tm = 460 + 66.8333333333333 =527R V*(3rd,= KrxVk = 0.04706 x 85 1 = 4.O0 scf V-Gut= K4xYxV.xP- Gq. a'1) T. .'1764x1.009x43.961 x24.01 - = 35.56dsc, (Eq.a-i) B*,= V.crsrat V*ct*al + V.frat = 4.00 4 00 + 35.66 = o.rol (%/100) Eq.aa) variable Valoe Definltlon Unit of Measuremenl Po",23.9 Barometric Pressure in. Hg AH 1.50 )ressur€ OiffBrential across Oritice in. HrO 24.O1 \bsolute Pressuro at Gas Meter in.Hg t.66.83 'emDorature at Gas Meter .F T-\bsolute Temperature al Gas Meier "R K1 0.04706 lonversion Factor ftr/mI 85.1 /olume of Watsr Condensed 400 /olume ot Water Condensed scl K"17.64 lonstant 'R/in.Hg 1.0090 on Fador unitless 43.96 /olume of Stack Gas Collected dcf 35.66 iamDle Gas Volume dscf B*.o 101 itack Gas Moisture content o/ot'100 GP043AS-025822-RT- 1 330 Page79 of 174 Sunnyside Unit EU S1 slL6l2023 Run *1 Sampl€ Calculations EPA Method 3A: Determination of Oxygen and Carbon Dioxlde Con@ntratlons In Emissions from Stationary Sources (lnstrumental Analyzer Prcedurel (40 CFR Part 60, Appendix A-21 o, C..,= (C.,, - Co) x C.. (U- ' Uo) = (s.638-(0))x996 (s8-(0) = 5.7 o/"vd (Eq.7E-sb) co2 cr.,.(C.,8-CdxC." (c- - cd (Eq. 7E-5b) Varlable Value )effnition Unlt of Measurement oa C.,"5.6 Uerage Unadjusted Gas Concentration o,/ovd orQ 0.0 Wemge PE/Post Zero Gas Response o/oud o, C."'t0 0 ot Upscale Calibration Gas o/o oz C-9.8 Werage Pre/Post Upscale Gas Reponse %vd oz Cr*{verage Gas Concentration Adjusled for Bias ",ivd co, c",r 13.7 \verage Unadiusted Gas Concentration o/ovd cor Q 0.1 Average PrelPost Zefo Gas Response 6/.vd co, c-.26.9 loncentration o, Upscale Calibration Gas v. co, c.265 qveEge Pre/Post Upscsle Gas Reponse %ud co, cr*\verag€ Gas Concentration Adjusled ,or Bias %vd GP043AS-025822-RT- 1 330 Page 80 of 174 srnnyside Unit EU fl slt6l2023 Run f1 Sample Calculatlons EPAMethod6c: DetermlnatlonofSulturDiorldeEmisslonsrromStatlonarySources ( lnstrumental Analy.er Pr6edure, (/r0 cFR Part 50, Appendix a{) (Cr"r-Co)xC.. (C- - Co) (83.2-(0.25))x99.8 (e4.2 - (0.25)) = 88.1 ppmvw (Eq.7E-sb) ca= (c8_) (MW) (101 (385 3) = r.47E-O5 lblscl Erb/m6Bt!= (Cd) (FJ (10O) (COrolovd) = 0.47E-Os\ t1800) (100) (13.e) = 0.19 lb/mmBtu lEq.19-7) Variable value Deflnltion Unit ol Measurement c",s 83.2 qvemqe Unadiusted Gas Conentration ppmvd q 0.3 veraoe PB/lPosl Zero Gas Response ppmvd c-"99.8 )onentration of Upscale Calibralion Gas pPm 94.2 \veraqe Pre/Post Ups€le Gas Reponse ppmvd c*,88.1 ueEge Gas Concentration Adjusted for Bias ppmvd 64.06 ,rolecular Weiohl lbllb-moie 385.3 /olume ot One Pound of ldeal Gas at Standard Conditions scf/lb-mole F 1 800 : Faclor trom EPA Method 1 9 scf/mmBtu cd 1.47E-O5 )ollutant Concentration, Dry Basis pound/dry standard cubic foot CO, o/ovd 13.9 )O, ConentEtion dry volume percent Eru/-,a,0.19 :mission Rale pounds per million Eritish thermal units GP043AS-025822-RT-1330 Page B1 of 174 S0nnyside Unit EU fl slt6l2023 Run #1 Sample Calculations EPA Method 7E: Determinatlon ol Nitroten Oxid6 Emlssions trom Stationary Sources (lnstrumental Analyrer Procedure) (40 CFR Part 50, Appendir A-41 Cs.,=(C",s-Co)xC-. (c, - co) (1084-(0.4))x 160 (15e 45 - (0 4)) = 108.6 ppmw (Eq. 7E-5b) = 1.30E-05 lblsc, Er6/nh6ru= (Cd) (F.) (100) = 0.17|blmmBtu lEq.19-7) variable value )efinltlon c 108.4 Werage Unadjusted Gas Concenlration ppmvd co o.4 \verage Pre/Post Zero Gas Response ppmvd c-"160.0 )oncentratjon of Upscale Cslibration Gas ppm c.159.5 Verage Pe/Post Upscale Gas Reponse ppmvd c*,108.6 \verage Gas Concentration Adjusted for Bias ppmvd 46.01 ,!olecular WeiOht lbllb-mole 385.3 385.3 Volume of Ore Pound ol ldeal Gas at Standard Conditions scf/lb-mole F,1800 Factorfrom EPA Method 19 scf/mmBtu cd 1.30E-05 )ollulant Conc€ntration, Dry Basis pounds per standard cubic foot COr Tovd 't3I )O? Conentration dry volume percent F,,o.17 :mission Rate pounds per million British thermal units (COr%vd) (1.68E-01) (13.9) (100) GP043AS-025822-RT- 1 330 Page 82 of 174 Sunnyside Unit EU {l slt6l2023 Run t1 Sample Calculations EPA M€thod 10: Detetmlnation ot Carbon Monoxide Emlssions from Stationary Sourc€s (lnstrumental Analyzer Ptocedurel (40 CFn Part 60, Appendlx A-41 (C",r-Co)xC." (C.'Co) (24.1 - {o.2\\ x25.1 (25.2 - lo.2)) = 24.0 ppmvw (Eq.7E-sb) Ca= (Cs-) (MW) (101 (385 3) = r.74E-O5 lb/sct (cd) (FJ (100) (COr%vd) = o.02lb/mmBtu (Eq.19-7) varlable value )eftnltlon Unlt o, Measurement c","24.1 \vtrage Unsdjusted Gas Concsntration ppmvd q o.2 \veraqe Pre/Post Zero Gas Rgsponse ppmvd c."25.1 loncentration of Upscale Calibration Gas PPM c.25.2 \vsage Pre,/Posl Upsle Gas Reponse ppmvd c..,24.O \veEge Gas Conentration Adiusted for Bias ppmvd 28.01 l/lolecular Weioht lb/lb-mole 385.3 385.3 /olume ot One Pound of ldeal Gas at Standard Conditions scfllb-mole F.1 800 : Factor from EPA Melhod 19 scf/mmBtu cd 174E-06 ,ollutant Concentration, Dry Basis pounds per standard cubic foot CO2 o/ovd 13.9 lO, Concanlration dry volume percent Ep7..a,o.o2 :mission Rate pounds per million British thermal units GP043AS-025822-RT- 1 330 Page 83 of 174 sunnyslde Unit EU #1 slt6l2023 Relative Acoracy Test Audit Sample Calcolatlons NO, (lb/mmBtul Run S d2 I 3 4 6 7 I 9 10 11 0.165 0.'159 0.006 0.00004 0.'168 0.'157 0.011 0.00012 0 169 0.157 0.012 0.00015 0.169 0.157 0.167 0 158 0 167 0 158 0 165 0.156 o 162 0152 0.00014 0.@009 0.00008 0.00008 0.00010 0.012 0.009 0.009 0.009 o olo 0.o10 0.092 0.0084 o.ooo11 o.0(197 ala = 0.002 CC=(b.ogrs) Sd Average 0.167 0.157 Sum nla nla Sum2 ale nla (2.306) (0.002) = 0.002 RA= ldl+lcCl rioo) RM = 0.010 + 0 002 rlo0) 0 167 = 7.loA Varlables Id',0.00097 ium o, the Squared Oifferenes IIdJ.0.0084 Souare oI the Summsd Differences n lumber ol I e$ Runs sd o.m2 Standard Dsviation of Differences b.ors 2.&6 f-value ,rom PS2, Table 2-l CL 0.ot)z 2.57o Conidgnce (;oelflclent tdt 0.010 \bsolute Averaqe Difference tcct 0.m2 \bsolute Contidence Coetticient RM 0.167 \veraqe RM Value RA 7 10/"lelative A@umcy GP043AS-025822-RT- 1 330 Page 84 of 174 Appendix B Facility Process Data l GP043AS-025822-RT-1330 Page 85 of 174 Appendix 8.1 Unit I I l I l I Nb $F. .oN@oo Oo o o '- ra i i u i { , NN o eE E g i E F E E E s E E E E E E $ i E f i iE g l . o . E B T g g E g g E E g E E 3 S E ! E 93 3 ES E T F E ;c i ; j i d c c d o ' d d d o o d o d o d o dd c i r i NF O O O O OF F F . ? ip g E d s ss f p . * od o d o F o o 6 - o Q ea 1 . ! E . ! e d l q ' : e q q = = 88 S E i gr r I rE g I r r8 88 I E 88 E8 E 8 " " -- - - - - - +i - -E OE O I FF ni . i i F i d G. N o-Jt$lr JoiE4, CU ' !o 'r E :. Ul ;, ! :o o@ F F? O F o O - Gr C , QQ q e - q q o - il I i ci o i u; 6 G u, 6 6 rr td 8i i n ri t + ui T; T E f f fi f i fi f f ;f i fi f i Ef i fi fi ;f i ;f i ;H E * f i O O NF O O F T F h O I F t s F ! } O Nd F N d g N F E S t r g g d i oo o o - Q Q Q e Q q e q q e q q t \ q q .i ^l .t i .r i Gi Gi . r l .r l nl . \ i . r i 3 i N .{ N N N N R N N ;- - - i ? ? F ? ? F - Efi g €E O tt t Ii to= o -g dEE E Eg B E{ t > o6 ll nOt E 8E EO (E O Ea9E P uJ O r q i n Jl l $ ? -s N eg E n =. ! r qEc E + 5* g E J* E gp E E E g r I E p E t E E p E I r i E E rE r E - - d o? F G ? 6 { Q Q r t Q q d ? q q 9 e . ! q q o o oo o o - F =t E i s g N r d E g s E E E E r i n s E 5 HE s . $ ' * $i $ = S . - u s s s a gJ g g g ig gI i $S g U ' EE E E EE E I=EE $ E= $E E E E E E E E B B E B g E E E E E E E ., E sB $ s s * s g s $ s s B $ $ B B $ $ $ $ EE E E E E E E E E E E E E E EE I E E E ,zfo o?O- daoqU' J c ru f l "E=5 EH zJ ts ^ lbE3 8e oo . or L x^9= iD O- oe }EOE lt vE^<- FA o e NOo9o8 (. l{,i io s8 ON (, G' .T Eg E EE = E: o 5i t r s' E H$ c $ E E EE = HE 6 ;t r ij oEbdt I& s NIGl sfNo@@a,c, l |! (! . taE, lr lo6,f EO io E3 =l 'c o ;r:l o Eofi s .o = !, i ! o rt , Ino= ao .9 bEt E ET B (J i i ll tr O. c gE E( JEu fi 6 G , E ,l l l E + o8 $ rg t s I EE E $ 5E 3 (9 ,: L l E (r l , tg *H 1' Dq E9 H Ee = F E Ef l E F E E aE Eo a qE HE do . EE, B I I I $; n I I BB $ BB B N I F s E $ ES E I E F FF N N F N F ] ' ] . . : . . ci d ci c i c r o o o o d d c i G i G i d d d d d d d oo o o ni l * n R n n n E s s i l n i D n n 3 i $ * EE E E E E E t t 8 t I t t t t t I 8 8 tt t t I t t t ,g I $E $ $ $ s $ $ $ $ $ $ $ $ E $ s $ E $ $ EE EE E E E E B E E E E S S E S E E E S E E - rI = tt s .t , Eo- Nb $,- .oOl@0)c' l too- ot s * h -- d *d f i NN Iqoo EI $ E i l E E E E i i l i E E E i E E E e ii f ; ; " - E E E E g g E 9 E 9 E g EE 3 gg E E I E qq q E F F o' c r . r J c r d o od d o o d o d o c i o oo o oo o o fi f i t H Fo No b F Fr s$ g $ ** J OF o O F U ) N t Q ei s P i r t H F S EE E E i s E E B E E EE E E o . sI EE E E E $ E I E E E E E E E E E E E E E EE E I " Er $ E $ $ E $ 1 3 [ $ $ E E $ $ E $ 3 $ E$ E E ' . oN , o ? o - t r t Q ! E - q q - I q q + ul r i . r i d d td 5 i i i Ei i o 5 ! o E o r 6 o o F t s F F t s oo !Q h c l a q ! q q c! d d rr s d E E !t ! , n $s n EB il E E I I I bo5l=BlueaD2zl c, o 'o 'E '. E ;. ' : Q -[ o .! t : 1 . ! . ! t : oo F N ! t C t E6 0 0 F e oo o ( o N ( D dJ S P i S !toEe troq ll ll o= o .9 c, E6 . E Eg . B Eo > (J i i ll rt O" o gE (! O !l -8o9E g UJ O o n ll [ : i ur F - H + NN oE S gE E E .= g g ? EE T 3 r. E E S ES g E tt E NO ( ! r o N i o { D ! t ss d d i J g g s s oo o o c Q Q e q o c o o F q n I i i ; i n i .i . t i 6 i nl .i ci di ., i .i ti -- - - ? ? !E r r I E EI E E F E BE E E E E E E E E E B E E g E E E E E l IE E E E i ' ss s $ s $ s $ B $ $ $ B $ $ E E E E $ E EE EE E E EE E E l E E E E t s E EE E E E E HE = z-fo o? t0 r dD A6OJ E 8g c=5 ts F bo8EzJ F^ L t l , Eg 82 ao a- () o - x^2? oO - Oo - =- 3A ot s JO rv*s *$OJ o E NOoeo8 @FI gB oA r (, (o il h* oI ;- E H. E g HE d EE E E; o 5i a aE s fl e $ EE q. E so 5 8. E ? r- E' 5 Et o&G ct }t .\ lEN tr\dooo\OJcr loCL I-EBfioozzf co io {i E z6 I ,- o Egra = -i J oc f r II ls, 3 @ !c ,EE E Eo > od i ll l fJ r o gE .E ( : Ea9E e uJ O o i' ; [i l b . 1 uJ F o d -R c i oE S PE 5 il EE E * EE E E nt E -o)o $$E Ee *E e EE T H5 E H* g$ E s E E &E = fr E EE Eo - EBOL E E3 E Es E E $ E E S 5 E HT E g E Es gq E E E E ct d o d. i o c i ci c , ct d c , c i c i GJ o d c i d d c i oo o c , iE E E E E E TETT -F - t 8 8 t E S ' 8 t g t E 8 8 9 = S 9 : 9 P = P E Eg st s s s s s s s s s s s s s B s s s s s c" E s$ s $ s $ $ $ $ * $ $ * $ $ $ s s s $ $ EE E E E E E E E E E E E E E E E E E E E No vF.oolo)c' rod EE E I E g l E d s r E f i s $ H E l l E E En i [ * ' g E E E gE g } E ET I E Eg 9 ES P 3 3 Eg q E F F E; ; ; ; ; r ; e i ic d o o c t d d d c t c i d ci c i o ' " HH f i f ; oo EO O F ?- ti S E ! i ' * c{ GO t t s o cd d s S ;f ; E E B E I F i I E E t ; E F E f ; . i I a . ;$ f ; g . - . gE . E E . B . E . E gE gt E 8 E E E E EE E 9 EE E E . Ef ; ; i l 9 ; i H i l E i E f ; I E ; E H E i l . I E[ i B - - ii i g g s E s ' E g s g g s s 3s . E g i 3 es g s : boEsl!oal ,z2:) co Io ,J E l' , ,. ' Ot .o 3 3; ; 3 3 3 3 3; 3 ; 3 3 3 3 3f ; 3 rq 3 33 ; i nr o 6 F F F to ro t a a Q Q A q q c t q q ,: q d n ns 8 dr f s d s I' E E E E E E ff I ff I rQ . ! 9 . 1 q . ! \ q q C ES B R F [ 8 F R X 3 !q t q c r c . ! q c EP E B F $ 8 S B I ;E E i . oF 9. ! q . ? q e a d ? q q E8 8 B 8 B 8 T I E !o . q q q r t8 t 5 8 B o. q q ? Nd N N I E FF EEo . EEEE at f r il l l tn ) o -g c, Eu - E Eg 8 Eo > tJ dl l! tt O. E 8E tr o (! 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N Q co d d d d c c o d c c dd o' o' d d o ' d d ct c t . r a EE f f E E f r !I -F $ I= tt B E B B E E E B E E B E B E E S B E S ., E $$ B $ $ $ s g g s s s s s s s s s $ s s sE E E E S E E E T S E E E E S E E S S E Nb riNfoOto)c' loo Sa g 5 E E E e I E E E & E E E : E E E I EE : H * . 3: s 3 rs gg g g P s E E g E E E g E E E T ? q i E Eg ? f i E E = E E; ; E ; t ; t ; ; ; ir ; at ; r i 3 ci c c; c tt d o r t SI E F E E E E B f i E E ; ; E i ; E E i i fB ; ; . o " EE E j E i E E E ; E E B i t s E E E ; i gi E [ " o !! E E I E B E i ! ! 3 ! I E E E I ! E $ 3! E 3 o o TjEIDTTot,zlo }f i t i l . oo ;E 8 3 3 3 3 3 3 8 3 3 ; 3 3 3; S 3 3 ; fi Hf i fi fi BH f i fi fi i fi T fr }T f i ;} f r fi C'oz -= , ll l ;; r :' a oaoE,I ttoE" . EF€- i Ui l . q , Il io= troEuEB Ego6 ll uOr E o! =8b oO It uEo fi 6 It ] UJ F o G' 9 =cEE =E5- rt ll rr - E EE E E E E E E E E F E E F E E E E E E E EE E I - " sg $ E $ i $ s } $ $ $ E $ $ $ g $ $ i 3 $3 $ H . . IE E ; E E $ oraft ) llEq Gi , N (\ t NBc oEaE3 ba ,t E Et H Es EE E E s E g B E B B E E g E E B T E E E 'E $ g $ $ E B H H E H g f ; $ $ g $ g $ * H H ,zfa oQ3Hoq OJ E cRox o_ Ea F^ ,( AE3HE oo - (J O- =3 Bo * 3Eot Lvd^+r &BOJ (, E NOOP o& G'*I Ef t t- 9 (U N (r @fi E9 ,= < Z- z *E e B. E ? H5 E Et Ef l s $ f i E ge e sE AE E O L I4 t E f Er . = U' .F ri j o EE 6@Eo - Loo-oG. NEN $No$(r loo)o(L IB., Il lo6tzl EO !o ,' B io :' I-1 o EoT€r * !EOa t IuO= ! EO -9 ii Eg E Ea > (J i i ll nO.E€ eoCO to B 9E T UJ O r \ i u1 r t + UJ F T! oE a E- 9 t s ; EE E H Eg , l e ,: l * F ci ! t9- $H E E^ u hg *E * sE Bf f E E E EE = E€ A HE ii B LtU 6Et Iod. gq q g $ E r g s F E E F E g E * N S f l 8 eq H H F E o o o o o o o o o c i € r < t c j c i c j c i c t d d o' c i oo c l t ) $5 E T EI f rE I E ii ' SE ;rET E Hs EE E E E E E S S E E E E E B E E E E E E ,, E $$ E $ $ $ $ E $ $ $ $ $ $ $ $ s $ $ $ $ EE E E E EE E E E E E 5 E 5 5 5 5 E E E a\ at vr. .oIr )olG)oloo $! : E l i $ ; $ E t l i E E$ * [ o o si o oo o F? ri -r i 5 j dN B s r r I E E E 5 EE il & $ t ? E Eg 8 E hS S f i t x E - i i - - r r - - - FF - N ci c i c i c i o o ci d ci c i ci o ct c i d ci c t d o o ct cj d d t i Ob N t s Fr dd d i l *' .j o! 6 * ? ? dr B g U ' " J ?O O O T A O F G ? O G si d E r i EB N e B N 66 0 ? o o o ! o 6 0 0 0 F r F O 6 F i i A6 F R ? ? gg g g E g I gg E E g d d = s e I 5 ! P g5 g $ ' - -- ; c F ? ? ? ? ? a \ i (i r o N 0 c r t F id i l . i . \ i i ! , FF O o N O O qa q q r q q - q to n o l l ' o i 6 6 f eN 9 a Q q q { Y i i q q ui r t r t o i ( , u i r i o E | a N O O O O O F O C' E 3 O 7 N C ' C FI Q ' ! O F il i * il i * d !t 6 * * !i g S I 8! * E !i ! i !, Io5Etr Jo62zf ct o !o ,E .: . a .. 8 :: o ;' r ': o q. ! ! oo F hF o oN t o t t N o iF i N d i 8 ttoEA =i ) O '! t ul i o) o .9 oEt E EB S tJ ii ll rt (J r o 8Eeo oO E*Eo s H5 : ur o J- rr u l + UJ F F I OE ii 9E E : =6 g ] J EE E E EE g 3 .: l J l p oo ! o o i tt . O F ( r N r l ) ! r d l o l Q 3 ! r q N F (O o F F F ? Ei l * F * P H f i g $ g 3 E H f i [E $ E J 3 $ $S d E * * EE E r E E' S Es E B gE gE E ' E - E ' E ' g g E' E ' g E +6 6 6 o o o t o o - F o o ! F 6 l F o 5 ? FG o o F F dt I $ fi g$ sl i B S E 3 i l g Et g B t e 3e E s * ' gr iS ! s' g ! $$ s s Eg s r r Eg S g SE I E ' tt IE E E I E # EE Ot s O O F ? .i . i n qi c{ G | aQ r: Ea a a qq q q t : q c \ qq Qq a e .\ i G i . i N N ({ d d R N d N O N N N N N N C d -- - . ! hq S E E g E g B P H E E E ; i P ; E ? } 5 F= P9 9 = = 5 = = = = = = = = = = = = = E = o r *s s s g $ $ s $ g $ $ $ $ $ $ s $ B $ s SE E E E EI Et s E E E E t s E E E I E E E 2zo qQHHOE Ur J c xS-t=5 EEzJ F^ ,afEHg oI () o - HP oo - =- ie9g Lvt^rso E N! ,oe .E i 8B .e N C' @B Eg ru : €= Ef i E = E; o 6= t r h' E CD P : . e oE Eq g E ; E 9E € EE < 3 HE f ci . = ? s- _E ^E o_ E Eo&0t Ln {5 . NIN ri t\oroot tl ,o) rtCL 5l'gBBot2la' o .s E 3, O -. ^ ' I l' . o Egfi s 6E=. 1 oa !r 1l o3 o en t EE E Fg " va , " .. : 'E EE EO !oEa o 9E B II J O T nr $ E l! l - F i, Eg gE E $ EE f l 3 EE E u IJ I E = $H E ts ^ Hf i e = r ; cr r P : . a 6 E g gE * $E -\ tr to E HE EE Et = Bo0t Eq i { H - F E ET E E S S H S f i 5E E 9 E TI B S I X c, c , c , c , cr o o o O c, c i d d c , G i c i d d ci c t c i og o i si E E i E n B E= ES S E E E E I s ! E E E E = l l l E = l ., E E$ E $ $ $ $ $ $ g $ $ g $ g $ E $ $ $ g EE E I E E E EE E E E E S E S E E E E E (\ tE $NdF.Or0,0loo- D O O F t? t ti B i '* NO .f o l' o! rq r: o a s! I e e q Q. ! rr EE i = g g E E f l F 8 E E 9 = Ot s i t FF aj rr o ' g nc E E E g g E E g E E E 3 $ E S 9 E g 9 T 9 EE E H E E ;; ; 4 6 i c ; c ; o c , G t G t o o o oo d o o o dc i c i t i ,\ 6 - t F? 8! r E R i *' Hi i E oo O? ? N O i$ g i i 6N a l o F? .\ i ; - r i aN 6 0 ? o ci qa q q l q q r : q n q g E : ! 9 I EE E p g g E E s r = E E g g g g qq q e q l s9 E t t t e O eG ! e- O ts a aO O t C q QE - - o - ; ; ; ; ; d a i - 6 i -' d 6, i t i ci ui d 5i 6 o .D o. D ro . o F F i Q e a I Q q q r: e \ o o d d d il d d ta E S fr d I s tf !, s !, !i ls s' !i Fr \ a o o o F l sg s P F p S ob N t ) F ' ) N t F dP R I i S R F F B bebAal lr JoiDzz= EO !o t: B=O :. ' r ,a EE4 E* ? It E=i ! C" O It ll l o3 € .9 dEt . E 5t E od ll n (J r E PE oo Oa r ,I ; H fi 6 I I ll . l : d ur F ; ll $B eg E A .= c r r u ) EE f ; E J. = E O - 5s g e It l l E '! 5 &. -C ) o t ii d s tF ? a o o o N o F i o O F U ? t q t Q q Q a qq c l q = E : E* . ; g s g $ f ; s s e 3 s E t e 3 i l 3 $ i l il E R R " " E EE - E EE E ' E ' E ' g E E F i E Ep p E E g E' E E ' E f; f; f ; tE ; i E i E I E $ i a B [ [ E f i e . 8] . f i 8 - ' s si i$ s s g g 9 = 3 s s 3 g 3 = s s 3 s= 3 $ EE E ; l i # Eg i i i i R I i 3 r * i r Rt fr * r i & i i EE E I E E - ! E H S t f l f r E f r f i g r $ 9 I * * t * 9 8 8 x 6 , ; - - ? 5 F= -: - - u' E *s s $ $ * s s $ $ $ $ $ s g E s $ $ $ $ EE E E E E E E E E E E E E E E E I U gE z.z. a) ) oA !l -daA- J E sg o- =5 EHzJ F^ ,- al t fsgs oo - () o - x^e3 ol L oo - =- =a ob JOLv t^tsOJ (, E NOo9 .E E Ef r E{ ! 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' ! N (\ t co oE K Et t s ? EE E 3 L -- E +5E g e sl t l E uE p OF F aa N E$ E E E E E E g s $ E g B g g E E $ E E EE E E E E E -E E$ $ $ E s E $ $ $ $ $ $ $ $ $ $ $ 8 8 $ EE EE E E E E E E E E E t s E E E EE E E 5 5 $E = =z.=u, oQ OIda oG l OJ c xE o- =5 hh== 5t s zJ F^ l- o<F>F$E83 oO - () A=- x^9e ol L oo . 3EAE J6Lvd^$HOJ o aE NOoeo8 rt*I #H Et s I =O la xo , (U : sE ti l .E E E' E ? H= E 5€ ED P : . il &' E $ EE F B E i F= Es E HE EE Er ttsE, $\ - -+ Nta\ l $r\ dorloH0,ol IEo- TEEul ct6tz. f EO ;o 'r EZA ;r t .I o T'o-fi a€a ot t l! 6, i .r ) = 6 odEE f i Eo > oa i ll rt () rHEEE - i rr r E t II J F E H eg f i s EE f , H EE g U x* E rt tP EBH EO 9 gE *s e =r = ? E5 E 5e H$ s g x E EE = E€ a sE HE d0 - BE t I t t r tr p r Bs 8 8 8 s r B I E ss I Eg * 8 E E F? F ? O f t F A d ? o' o ' c , d o o o c i Gi ci c t o Gi ct c t c t d o ' d d . i oo o t xR E N F & B E s B s s t B ' t e s $ c t E! ! 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E E q a I { U . a; . t t . * PF F F F E E PE P R P P E S tr P F F E E EE E F . tl tI a e e q Q q Q t o N t s o o F F o d q q r? s l q q = E fi E E ; s t s s E I i ! i E E n f i Es d f i g3 sf f ; $ * ' $+ $ $ + t ' $ $$ $ e e s *g $ $$ $ $ $ $S $ s -- - r - rE r E I E n EE ?6 o o O c l O O O rO E O O C l C , O O O O F F d 6 6 6 6 6 ti td * i ri 6 J d d { { i ' d ri rj !! ' q q q q c qq q t q ca a ! ul q ! ! ! 88 8 E S e E r E E 8 E E 8 f l 8 8 8 8 8 E OO N F c ! C C ' r o O Ed 5 ' c f d d g c .r t q l q a t q 88 8 E 8 8 8 ts t s E O O O G O O O A O O O O O O O O O a ai N N d N . t N ( at N f l N G. d l a l G| d a { na N N ?? ? ? ., . U EE H E i l U E E E E ? ; q E i P E I ? 3 f i a E - + + + + r + i i + ? t + + { { t u + t { i ., E s$ $ $ $ s s $ $ $ s s $ $ $ s $ $ $ $ $ EE E E E E E EE E E E E E S E E E E T I 2zfo o? aa r daoqAJ E ol l o5 o- =5 r- FEE 5t s zJ F^ t- a fi sHg geHE=- =Eob J6 lr vE^CI&bOr J o E N@OP (- ) fl f: EH ir B I s a eg E ' i r Eo . tBE. o+ t\ tt(I st\Ho\ooOJotoCL I.eEt6,2D ca o ;o 3ga6 13 EIfi g - €E ot , t! t r o= 6 .9 oEE f Eo > oi i ll rr () . E gE 6C 'Eu R 9E r ui O r J_ !r r $ + r. t J F ; N N@ oa R gB t s ; EE T S EE E B rt ! E ru . E iP f: $H OD fi Eg tU : ;- E Hg E YE A[ f E EE $ EE F E E AB = Ef E HE iE L ([ oEt ost R p E s I E 8s 5 E3 e8 r 5 N 8t t r 13 E Eg q $ FE - r - -. ! 6l - r Gl !. q - - - i r r r r . o o o o o g o o o o o o o o o o o o o d o oc l o i IE E ; E E f !! -l - . & EH S g H g E E E g e ; $ e ; e e i i ? R 6 Oy ! ? ! f !! ! ! ! ! f !r ! i ! * f t! ? aD F G o o o o r N d N * * R R R8 R 8 8 & &g S I I S I I .B D B B - t s A b - A A - D A U U B - - a EE E E EE E E E E E E E E E E E S T E E Appendix C Qual ity Assurance/Quality Control Appendix C.1 Units and Abbreviations I ilGP043AS-025822-RT- 1330 MI+?N,I+gP.H UNITS AND ABBREVIATIONS @Xo/o 02 corrected to X% oxygen (corrected for dilution air) lCCl absolute value of the confldence coefficient ldl absolute value of the mean differencesoC degrees CelsiusoF degrees FahrenheitoR degrees Rankine " HzO inches of water column 13.6 sPecific gravitY of mercury AH pressure drop across orifice meter, inches H2O AP velocity head of stack gas, inches H2O e total samPling time, minutes pg microgram Pa densitY of acetone, mg/ml P* density of water, 0.9982 g/ml or 0.002201 lb/ml acfm actual cubic feet of gas per minute at stack conditions An cross-sectional area ol nozzle,flz A" cross-section al area of stack, square feet (ft') Btu British thermal unit B*" proportion by volume of water vapor in gas stream Ca particulate matter concentration in stack gas, gr/acf Cnus average unadjusted gas concentration, ppmv Co,, measured concentration of calibration gas, ppmv cf or ft3 cubic feet cfm cubic feet Per minute cc". average gas concentration ad.lusted for bias, ppmv CM average of initial and final system bias check responses from upscale calibration gas, ppmv cm or mt cubic meters Cro actual concentration of the upscale calibration gas, ppmv C6 average of initial and final system bias check responses from low-level calibration gas, ppmv Cp pitot tube coefficient C. particulate matter concentration in stack gas, gr/dscf CS calibration sPan, % or PPmv Cs measured concentration of calibration gas' ppmv Cv manufactured certified concentration of calibration gas, ppmv D drift assessment, % of sPan dcf dry cubic feet dcm dry cubic meters Dn diameter of nozzle, inches D. diameter of stack, inches dscf dry standard cubic feet dscfm dry standard cubic feet per minute dscm dry standard cubic meters Fd F-factor, dscf/MMBtu of heat input fpm feet Per minute fps feet Per second ft feet ft2 square feet n nrr.gal gallons gr grains (7000 grains Per Pound)gr/dscf grains per dry standard cubic feet hr hour cP043AS-025822-RT-1 330 Page 109 of 174 6.i\ A*?N,I+P"p.H UNITS AND ABBREVIATIONS I percent of isokinetic samplingin inch k kilo or thousand (metric units, multiply by t03;K kelvin (temperature) K3 conversion factor 0.0154 gr/mg K4 conversion factor 0.002668 ((in. Hg)(ft"))/((mlX'R)) kg kilogram Kp pitot tube conslant (85.49 fUsec) kwscfh thousand wet standard cubic feet per hourI literslb/hr pounds per hourlb/MMBtu pounds per million Btulpm liters per minutem meter or milliM thousand (English units) or mega (million, metric units) mt cubic meters ma mass of residue of acetone after evaporation, mg Md molecular weight of stack gas; dry basis, lb/lb-mole meq milliequivalentmg milligram Mg megagram (106 grams)min minute ml or mL millilitermm millimeterMM million (English units)MMBtU/hr million Btu per hour mn total amount of particulate matter collected, mg mol mole mol. M. or MW molecular weight M" molecular weight of stack gas; wet basis, lb/lb-mole MW molecular weight or megawattn number of data pointsng nanogramnm nanometer Pu", barometric pressure, inches Hg pg picogram Ps stack static pressure, inches H2O P, barometric pressure of dry gas meter, inches Hg ppb parts per billionppbv parts per billion, by volumeppbvd parts pei billion by volume, dry basisppm parts per millionppmv parts per million, by volumeppmvd parts per million by volume, dry basisppmvw parts per million by volume, wel basisP, absolute stack gas pressure, inches Hg psi pounds per square inchpsia pounds per square inch absolutepsig pounds per square inch gauge P",o standard absolute pressure, 29.92 inches Hg Q, volumetric flow rate, actual conditions, acfm Q" volumetric flow rate, standard conditions, scfm Q,,o volumetric flow rate, dry standard conditions, dscfm R ideal gas constant 21 85 ((in. Hg) (fr3)y(("R) (tbmote)) GP043AS-025822-RT- 1330 Page 110 of 174 scfh scfm scm scmh sec 60 lt?N,I+gp.H SBtnrt SBi scf sf, sq. ft., or ft2 square feet std t T oszs T, Tm ton or t tph or tons/hr tons Per hour tpy or tons/yr tons Per Year UNITS AND ABBREVIATIONS post-run system bias check, % of span pre-run system bias check, % of sPan standard cubic feet standard cubic feet Per hour standard cubic feet Per minute standard cubic meters standard cubic meters Per hour second standard metric ton (1000 kg) t-value absolute average ambient temperature' oR (+459'67 for English) absolute average dry gas meter temperature, oR (+459'67 for English) ton = 2000 pounds Ts Tsto V va Vt. Vm(sto) Vr" v" V*"1"t0; Vwi(std) Vw"g("to) W wa Wirp [Vse absolute average stack gas meter temperature, oR (+459'67 for English) absolute temperature at standard conditions volt volume of acetone blank, ml volume of acetone used in wash, ml total volume H2O collected in impingers and silica gel, grams volume of gas sampled through dry gas meter, ftj volume of gas measured by the dry gas meter, corrected to standard conditions, dscf stack gas volume samPled, acf volume collected at stack conditions through nozzle, acf average stack gas velocity, feet per second volume of water vapor condensed, corrected to standard conditions, scf volume of water vapor in gas sampled from impingers, scf volume of water vapor in gas sampled from silica gel, scf watt weight of residue in acetone wash, mg total weight of impingers, grams total weight of silica gel, grams dry gas meter calibration factor, dimensionless GP043AS-025822-RT- 1330 Page tlt of t74 64\ lf?N,I+gp.H AAS ACDP ACE AD ADL AETB AS ASTM BACT BDL BHP BIF BLS CC CD CE CEM CEMS CERMS CET CFR CGA CHNOS CNCG CO coc COMS CPM CPMS CT CTM cTo CVAAS D" DE Dioxins DLL DNCG ECD EIT ELCD EMPC EPA EPRI ES ESP EU FCCU FGD FI FIA FID FPD FPM FTIR FTPB FTRB Furans GC ACRONYMS atomic absorption spectroscopy air contaminant discharge permit analyzer calibration error, percent of span absolute difference above detection limit Air Emissions Testing Body applicable standard (emission limit) American Society For Testing And Materials best achievable control technology below detection limit brake horsepower boiler and industrial furnace black liquor solids confidence coefficient calibration drift calibration error continuous emissions monitor continuous emissions monitoring system continuous emissions rate monitoring system calibration error test Code of Federal Regulations cylinder gas audit elemental analysis for determination of C, H, N, O, and S content in fuels concentrated non-condensable gas catalytic oxidizer chain of custody continuous opacity monitoring system condensible particulate matter continuous parameter monitoring system combustion turbine conditional test method catalytic thermal oxidizer cold vapor atomic absorption spectroscopy equivalent diameter destruction efficiency polychlorinated dibenzo-p-dioxins (pcdd's) detection level limited dilute non-condensable gas electron capture detector Engineer ln Training electoconductivity detector (hall detector) estimated maximum possible concentration US Environmental Protection Agency Electric Power Research lnstitute emission standard (applicable limit) electrostatic precipitator emission unit fluid catalytic cracking unit flue gas desulfurization flame ionization flame ionization analyzer flame ionization detector flame photometric detector filterable particulate matter Fourier-transform infrared spectroscopy field train proof blank field train recovery blank polychlorinated dibenzofurans (pcdf s) gas chromatography GP043AS-025822-RT- 1 330 Page ll2 of 774 6C f+?N,r+gp.H ACRONYMS GC/MS gas chromatography/mass spectroscopy GFMS graphite furnace atomic absorption spectroscopy GFC gas filter correlation GHG greenhouse gas HAP hazardous air PollutantHC hydrocarbons HHV higher heating value HPLC high performance liquid chromatography HRGC/HRMS high-resolution gas chromatography/high-resolution mass spectroscopy HRSG heat recovery steam generator lC ion chromatograPhy ICAP inductively-coupled argon plasmography ICPCR ion chromatography with a poslcolumn reactor ICP-MS inductively coupled plasma-mass spectroscopy lR infrared radiation ISO lnternational Standards Organization kW kilowatts LFG landfill gas LHV lower heating value LPG liquified petroleum gas MACT maximum achievable control technology MDI methylene diphyenyl diisocyanate MDL method detection limit MNOC maximum normal operating conditions MRL method reporting limit MS mass spectrometry NA not applicable or not available NCASI National Council For Air And Steam lmprovement NCG non-condensable gases ND not detected NDIR non-dispersive infrared NESHAP National Emissions Standards For Hazardous Air Pollutants NG natural gas NIOSH National lnstitute For Occupational Safety And Health NIST National lnstitute Of Standards And Technology NMC non-methane cutter NMOC non-methane organic compounds NMVOC non-methane volatile organic compounds NPD nitrogen phosphorus detector NSPS New Source Performance Standards OSHA Occupational Safety And Health Administration PAH polycyclic aromatic hydrocarbons PCB polychlorinated biphenyl compounds PCWP plywood and composite wood products PE Professional Engineer PFAS per- and polyfluoroalkyl substances (PFAS) Pl photoionization PID photoionization detector PM particulate matter PM.,o particulate matter less than '10 microns in aerodynamic diameter PMz s particulate matter less than 2.5 microns in aerodynamic diameter POM polycyclic organic matter PS performance sPecification PSD particle size distribution PSEL plant site emission limits PST performance specification test PTE permanent total enclosure PTM performance test method GP043AS-025822-RT- 1 330 Page 113 of t74 64\ *fgN,I+gLE ACRONYMS QA/QC quality assurance and quality control Ql Qualified lndividual QSTI Qualified Source Testing lndividual RA relative accuracyRAA relative accuracy auditRACT reasonably available control technologyRATA relative accuracy test auditRCTO rotary concentrator thermal oxidizerRICE stationary reciprocating internal combustion engineRM reference methodRTO regenerative thermal oxidizerSAM sulfuric acid mist SCD sulfur chemiluminescent deteclorSCR selective catalytic reduction systemSD standard deviation Semi-VOST semivolatile organic compounds sample trainSRM standard reference materialTAP toxic air pollutant TBD to be determinedTCA thermal conductivity analyzerTCD thermal conductivity detectorTGNENMOC total gaseous non-ethane non-methane organic compoundsTGNMOC total gaseous non-methane organic compoundsTGOC total gaseous organic compoundsTHC total hydrocarbonsTIC tentatively identified compoundTO thermal oxidizerTO toxic organic (as in EPA Method TO-15)TPM total particulate matterTSP total suspended particulate matterTTE temporary total enclosureULSD ultra-low sulfur dieselUV ultraviolet radiation rangeVE visible emissionsVOC - volatile organic compoundsVOST volatile organic sample trainWC water columnWWTP waste water treatment plant GP043AS-025822-RT- 1 330 Page tl4 of 174 60 lf?N,I+gp.I Ag silver As arsenic Ba barium Be beryllium C carbon Cd cadmium CdS cadmium sulfide CH2O formaldehyde CH3CHO acetaldehyde CH3OH methanol CHo methane C2H4O ethylene oxide C:Hu ethane CaH4O acrolein CsHoO propionaldehyde CsHu propane C6HsOH phenol CHEMICAL NOMENCLATURE Se Sor So. SO, TCDD TCDF TGOC THC TI TRS Zn selenium sulfur dioxide sulfur trioxide sulfur oxides tetrachlorodibenzodioxin tetrachlorodibenzof uran total gaseous organic concentration total hydrocarbons thallium total reduced sulfur compounds zinc Clz ClO2 chlorine dioxide CO carbon monoxide Co cobalt COz carbon dioxide Cr chromium Cu copper. EtO ethylene oxide EIOH ethyl alcohol (ethanol) H2 hydrogen HzO water llzO, hydrogen peroxide HzS hydrogen sulfide H2SO4 sulfuric acid HCI hydrogen chloride Hg mercury IPA isopropyl alcohol MDI methylene diphyenyl diisocyanate MeCl, methylene chloride MEK methyl ethyl ketone MeOH methanol Mn manganese N2 nitrogen NHa ammonia Ni nickel NO nitric oxide NOz nitrogen dioxide NO, nitrogen oxides 02 oxygen P phosphorus Pb lead PCDD polychlorinateddibenzo-p-dioxins PCDF polychlorinated dibenzofurans Sb antimony GP043AS-025822-RT- 1 330 Page 115 of 174 rl ll Appendix C.2 Manual Test Method QA I QC Data Montrose Air QualitY Services 6823 South 3600 West Spanish Fork, Utah &4660 (8011 7e+2e50 (801 ) 266-7 11 1 Meter Box Calibration Data Form (English Units) Date 1t312023 Average Yi 1.009 Orfice Manometer Setting AH 0.50 1.00 1.50 2.00 3.00 4.00 Barometric Pressure 25.4 Meter Box Number APEX XC-522-10 DGM No.351501 Average aH 1.717 Std Test Meter (Vs) Ft3 5 4.997 9.997 10.006 9.997 10.003 Dry Gas Meter Outlet (Td o)'F 77 76 76 77 80 80 81 81 80 81 81 82 Calibrated By Std Meter Y ATT 0.99497 lntet (Td i) "F 76 80 EO 84 83 88 87 88 88 90 90 91 Average [rd)'F 77.25 79.25 82.75 u.25 u.75 86.00 AH '1.758 1.729 1,700 1.710 1.726 1.678 Average AH 1.7',17 Dry Gas Meter (vd) Fts 4.947 4.95 9.954 9.952 9.945 9.939 Std Test Meter (Ts)'F 73 74 74 75 75 75 75 75 77 77 77 77 Time A Minutes 11.53 8.08 13.12 11.42 9.33 7.98 AH/13.6 0.04 0.07 0.11 0,15 o.22 o.29 Yi 1.01 1 1.010 1.009 1.A12 1.006 1.007 Average Yi 1.009 Std Test Meter Average Temp. 73.50 74.50 75.00 75.00 77.O0 77.00 GP043AS-025822-RT- 1330 Page tL7 ot 174 Montrose Air Qualig Services 6823 South 3600 West Spanish Fork, Utah &4ti60 (801) 7e+2e50 (801 ) 2A0-7 11 1 Sample Box Temperaturc Sensor Calibration Form Sample Box Number: AET lmpinger Boxes (Cal) Date:11312023 Calibrated By: CG Barometric Pressure: 25.4 Reference: ERTCO-1 OS-SNBS APEX #1A (XC522) APEX #2A(XC522-10) APEX #3A.(XC522-14) ES #1A (C-5000) Reference Point Number I 1 3 4 4 E 5 1 1 3 4 4 5 5 ,l 1 3 4 4 5 5 1 1 3 4 4 5 5 Sourco a (speciff) Probe on Probe off cPIU Oven on Oven off lmpinger lce lmpinger amb. Probe on Probe off CPM Oven on Oven off lmpinger ice lmpinger amb. Probe on Probe off CPM Oven on Oven off lmpinger ice lmpinger amb. Probe on Probe off CPM Oven on Oven off lrnpinger ice lmpingeramb. Reference Thermometer Temperature'F 240 55 57 241 58 40 51 249 56 55 244 57u 53 Thermocouple Potentiometer Temperature "F 241 s6 59 243 59 40 53 250 54 55 245 59 33 52 238 56 56 240 57 36 57 2M 53 56 242 59 37 55 Temperature Difference b % -0.14 -0.19 -0.39 4.19 -0.29 0.00 {.39 -0.14 0.39 0.00 -0.39 -0.14 0.20 0.19 4.29 0.00 -0.19 0.3e 0.14 0.00 0,00 0.00 0.00 -0.19 0,00 0.14 0.00 {.19 2Ai 56 55 241 59 36 57 244 53 55 243 59 37il a Type of calibration system used. b (rebrence temp. "F + 460) - (test thermometer temp. 'F + 460) reference temperature 'F + 4.60 GP043AS-025822-RT- 1 330 ' 100< 1.57o Page 118 of 174 Montrose Air Quality Serulces 6823 South 3600 West Spanish Fork, Uhh 84660 (Bol) 7e+2950 (801) 266-7111 Sample Box Temperature Sensor Calibration Form Sample Box Number: AET lmpinger Boxes (Cal) Date:11412023 Calibrated By: CG Barometrlc Pressure: 25.4 Reference: ERTCO-1 0S-SNBS a)6'-A b) c) d) e) 0 a) 6'- B b) c) d) e) 0 1'-C 8'- A lce Water HotWater Boiling Water Warm Oil Hot Oil Boiling Oil lce Water HotWater Boiling Water Warm Oil Hot Oil Boiling Oil lce Water HotWater Boiling Water Warm Oil Hot Oil Boiling Oil lce Water HotWater Boiling Water Warm Oil Hot Oil Boiling Oil Temperature DifGrence b % 0.00 0.16 0.15 0.28 0.25 0.11 0.00 -0.16 0.00 -0.14 -0.12 -0.22 0.20 0.16 4.29 4.14 0.12 0.22 0.00 -0.33 -0.15 -0.14 -0.25 -0.11 Reference Point Source a Number (sPecify) Reference Thermocouple Thermorneter Potentiometer Temperature oF Temperature oF 37 152 224 251 351 455 36 150 229 252 350 461 37 150 226 251 343 460 4',l 149 226 250 348 460 37 153 226 253 353 456 36 149 ?2s 251 349 459 38 151 224 250 u4 462 41 147 225 249 346 459 a) b) c) d) e) 0 a) b) c) d) e) 0 a Type of calibration system used. b (reference temp. oF + 460) - (test thermometer temp. oF '* 460) ' 100< 1-5% rebrence temperature oF + 460 GP043AS-025822-RT- 1330 Page 179 of 774 Pltot Tube Callbr.tlon Drta theet PrltEbrq Dhl.l AnC. fh(bltr fra&rhe T.pclD C.ID' lD: GtAaig+ncl Cdt[0on p.dffi uhe th. Dmdln of EFA ir.hod 2, S.rllon 10.1 E: H"'"" .nd Tubln! Dlmon.lmt D.tr ffi|t hrd rlaltcrlratbmh||{ s, mrt q. :._q@tr P!ar Pgr Prtr Paa! Pss Pgre Psts P.ls Pru PassO.fE Lltaahg h!.1 pdllq! fot dtr.mtratf & I E ^ DrCf lr.ltcalne ad ,o.lbo lor rLhrlnlno I th.n aiqhiltra z. t$embty lnbrcomponont Spaclng RequrDmordr Nt>e flI1 !n 75(l 0.370 (rD. e r.5)z@t Y r!.1 d1 i tfll 7 > OTBi , 800 OlhtTCctly S.b.c* TC onry Prr Paar Pa.a Otlb.tTC only e I -le :G'- +lo'l o_ a-lf <k +ltrl R. ,-1. .e-..ttr o.E A oa A o Et(n EAtfir (:t ILtZs-l l lm 3 f+ O Gll?.Sl ND D (0.tt7t < q< lL3751 0.t/l,(, P- ,lGD <P-<i6ftt 0_4rm o./t4O I Pe- Pr I ! 0.(825 o.&t00 GP043AS-025822-RT- 1330 Page tZO of 174 Pltot Tubc Gallbratlon Drfia Sheet t rohcror ( Dbitrl Aneh lind? lf t uillTrPr lD: C.brylD; C$rlton,iimd uhe !EPDc.&c d EPAlLlhd2,S.cibn iO'1 [" Hfo't"'"ntrndrubr*Dr'**"'[ Para Pa Par3 PeB Pa86 PaSt Pa!! P.3a Pilr P!!E Dara &l.lldttf lill lct[on t a.andilDg q .ild t, -"ME'ffi Dter lDdlc..hr lcl r-r- * T,r " Als.mbly lntrtcomponeil Splclng Requlrrment3 Oll&tTCqrly setb.d(Tc orry Pe88 Per Plla OfiratTC only Pcdorn:d Bp ApprbYod Bf 4LA -lF .a< +ltrl -lOP <o: +lG!z R. (-!F < B. : +5')0.0 B. a-r'<!i<+t-,t.3 o.7 t, aai.nr l+ 0-1251 FAtfro lr 0.Gtt25')o@51 D (0.i675. < D< 0.3751 0.370 P^ (1.05D. < Pr < 1,69r)o4000 Pr (i.05Dr < Pr < 1.5Q)o,/m 1P.-P.!t0.@5 oqm cP043AS-025822-RT- 1330 Page 12t of 174 Montrose Air Quality Seryices Certificate of Balance Ca labratlon Address: 5823 South 3600 West Clty/State/Zip: Spanish Fork, Utah 84560 Manufacturer: Model: SerlalNumber: ldentlflcatlon: Locatlon: Next callbratlon: Reference Weights Cal ld: Nominat Mass 1 20 50 100 200 Comments: Sartarius Analytlcal 8a110530705871 AET#1 SmallTrailer lndlcatlon 1 19.9998 49.9999 99.9997 199.9999 NominalMass 7 20 50 100 200 lndlcetlon Error 1 0.0000 19.9999 -1E-04 49.9999 -0.0001 99.9998 -0.0002 199.9998 -0.0002 Certmcate No.: 7lS-?;O22*l callb, Date: {4lzazl Technician; Cheyney Guymon 61412023 Error 0.0000 -0.0002 -0.0001 {.0003 -0.0001 Pertlnent lnformation: The artlfact described herein has been calibrated using sitandards traceble to N|ST. This is to certiff the data reported herein ls true and correct as the date calibrated. The Authorlzed Signature: procedure used to calibrate the artlfact meets the to meet MAQS Standards. GP0434S-025822-RT- 1330 Page 122 of t74 Montrose Air Quality Services Ccrtlflcate of Balance Calabratlon Address: 6823 South 3600 West City/State/Zip: Spanish Fork, Utah 84660 Manufacturer: Model: SerlalNumber: ldentificatlon: Location: Shimadzu Top Loader D4467L7AET #2439 AET #2 SmallTraller Certificate No.: 715-2022.*2 Calib, Date: Ll4l2A23 Techniclan: CheYneYGuymon Next Calibratlon: Reference Welghts Cal ld: NominalMass lndlcatlon 1 1.00 20 19.99 s0 49.98 100 99.93 2N L99.97 Comments: Pertinent tnformatlon : 6/412023 Error 0.00 -0.01 -0.02 -o.07 -0.03 NomlnalMass 1.01 20 50 100 200 lndlcatlon Error 0.99 -0.02 19.99 {.01 49.98 -0.02 99.96 -0.04 199.96 -0.04 The artifact described herein has been calibrated uslng standards traceble to NIST. This is to certify the data reported herein is true and correct as the date callbrated. The procedure used to calibrate the artifact meets the to meet MAQS Standards. Authorlzed Slgnature: GP043AS-025822-RT- 1330 Page 123 of L74 Address: Clty/Statc/zip: Manufaeturer: Model: Serlal Number: ldentlficadon: Locatlon: Next Gllbradon: Reference Welghts Cal ld: NominalMass 7 20 50 100 2@ Comments: Montrose Air Quality Services Certificate of Balance CalabraUon 6823 South 3600 West Spanish Fork, Utah 84650 OHAUS Top Loader 83s0103094 AET #5 Gooseneck CertificateNo.: US-2022*s Callb. Date: UAlZaZg Technlclan: Cheyney Guymon lndlcation 1 19.8 49.8 99.9 199.7 614/2023 Error 0 4.2 -o.2 -0.1 -0.3 NomlnalMass t 20 50 100 200 tndlcatlon Error 0.99 -0.01 19.8 -O.2 49.8 -o.2 100 0 t99.7 -0.3 Pertinent lnformation: The artlfact described herein has been calibrated using standards traceble to NIST. This is to certifo the data reported herein is true and correct as the date callbrated. The procedure used to calibrate the artlfact meets the requirements to meet MAes standards. Authorized Slgnature: GP0434S-025822-RT- 1 330 Page 724 of 774 Montrose Air Quality Services Certificate of Balance Calabration Address: 6823 South 3600 West Cttylstalelaipt Spanish Fork, Utah 84660 Manufacturer: Model: SerialNumber: !dentification: [ocation: NomlnalMass 1 20 50 100 2W Comments: OHAUS Analytical 8329s82358 AET #6 Gooseneck lndicatlon 7 19.9999 50 99.9997 199.9998 61412A23 Error 0.0000 -18-04 0 -0.0003 -0.0002 Certiftcate No.: 715-2022*6 calib, Date: ,-l4l2o23 Technician: Cheyney Guymon lndlcatlon Eror 1.0001 0.0001 20.000x 1E-04 50.0001 0.0001 99.9998 -0.0002 1e9.9996 -0.0004 Next Calibration: Reference Weights Cal ld: NominalMass 1 20 50 100 200 Pertinent lnformation: The artifact described herein has been calibrated using standards traceble to NIST. This is to certifo the data reported herein is true and correct as the date callbrated. The procedure used to calibrate the artlfact meets the requirements to meet MAQS Standards. Authorlzed Slgnature: GP043AS-025822-RT- 1330 Page t25 of 174 Montrose Air Quality Seruices Certificate of Balance Calabratlon Address: 5823 South 3600 West Cfty/State/Zip: Spanish Fork, Utah 84560 Manufasturer: Model: SerialNumber: ldeftlflcadon: Location: Sartarlus Analytical A200-5/3s120053 AET #7 Laboratory Certificate No.: 715-2022*7 Callb. Date: U4l2O23 Techniclan: Cheyney Guymon Next CallbraUon: Reference WelghB Ca! ld: NomlnalMass 1 zo 50 100 200 Comments: lndlcatlon 1.0001 19.9999 49.9998 99.9998 199.9999 6/412023 Error 0.0001 4.0001 -0.0002 -0.0002 -o,0001 Nominal Mass 7 20 50 100 2N lndlcatlon Eror 1 0.0000 19.9999 -0.0001 4g.ggg7 -0.0003 99.9997 -0.0003 199.9999 -0.0m1 Pertinent lnformatlon: The artiftct described herein has been calibrated using standards traceble to NIST. Thls is to certiff the data reported herein ls true and correct as the date calibrated. The Authorlzed Slgnature: procedure used to calibrate the artifact meets the gaquirements to meet MAes standards. GP0434S-025822-RT- 1330 Page t26 of 174 Appendix C,3 Instrumental Test Method QA/QC Data GPO43AS-025822-RT- 1 330 Page 127 of 774 Company Source Date Sample Gas Span Cylinder Value (ppm) 0 74.5 160 lnitial Bias Analyzer Response (ppm) 0.2 .t59.8 Analyzer Calibration Sunnyside Unit EU #'l 5t16t2023 NOx 160 Post-test #1 Bias Analyzer Response (ppm) 0.2 159.8 Post-test #2 Bias Analyzer Response (ppm) 0.2 159.8 Post-test #3 Bias Analyzer Response (ppm) 0.2 159.8 System Response (ppm) 0.4 160.4 System Response (ppm) 0.5 160.1 System Response (ppm) 0.6 161.3 Analyzer Response (ppm) 0.2 75.4 '159.8 System Response (ppm) 0.4 158.5 Absolute Difference (ppm) 0.2 0.9 0.2 System Bias (% of span) 0.13 0.81 System Bias (% of span) 0.13 0.37 System Bias (% of span) 0.19 0.19 System Bias (% of span) 0.25 0.94 Difference (% of span) 0.13 0.56 0.12 Drift (% of span) 0.00 I '19 Drift (% of span) 0.06 0.19 Drift (% of span) 0.06 0.75 GP043AS-025822-RT- 1 330 Page t28 of L74 Post-test #4 Bias Analyzer Response System Response Analyzer Response System Response (ppm) 0.2 159.8 Post-test #5 Bias (ppm) 0.2 159.8 Post-test #6 Bias (ppm) 0.2 159.8 Post-test #7 Bias (ppm) 0"2 159.8 Post-test #9 Bias (ppm) 0.2 159.8 (ppm) 0.7 16'l (ppm) 0.7 161 (ppm) 0.6 160.7 (ppm) 0.8 160.8 (ppm) 0.7 160.3 System Bias (% of span) 0.31 0.75 System Bias (% of span) 0.31 0.75 System Bias (% of span) 0.25 0.56 System Bias (% of span) 0.25 0.87 System Bias (% of span) 0.38 063 System Bias (% of span) 0.31 0.31 Drifl (% of span) 0.06 0.19 Drift (% of span) 0.00 0.00 Drift (% of span) 0.06 0.19 Drift (% of span) 0.00 0.31 Drift (% of span) 0.13 0.25 Drift (% of span) 0.06 0.31 Analyzer Response System Response Analyzer Response System Response (ppm) 0.2 159.8 Post-test #8 Bias Analyzer Response System Response (ppm) 0.6 161.2 Analyzer Response System Response GP043AS-025822-RT- 1330 Page 129 of t74 Post-test #10 Bias Analyzer Response System Response (ppm) 0.2 159.8 (ppm) 0.7 160.5 System Bias (% of span) 0.31 o44 System Bias (% of span) 0.13 99.88 Drift (% of span) 0.00 0.12 Drift (% of span) 0.44 100.31 Post-test #11 Bias Analyzer Response System Response (ppm) 0.2 159 8 (ppm) GP043AS-025822-RT- 1 330 Page 130 of 174 Company: Source: Date : Sample Gas : SPan : Cylinder Value (ppm) 0 25.1 49.6 lnitial Bias Analyzer Response (ppm) 0.'l 25.8 Analvzer Calibration Sunnyside Unit EU #1 5t16t2023 co 49.6 Post-test #1 Bias Analyzer Response (ppm) 0.1 25.8 Post-test #2 Bias Analyzer Response (PPm) 0.1 25.8 Post-test #3 Bias Analyzer Response (ppm) 0.1 25.8 System Response (ppm) 0.1 24.9 System Response (ppm) 0.1 25.1 System Response (ppm) 0.4 25 Analyzer Response (ppm) 0.1 25.8 49.7 Absolute Difference (ppm) 0.1 0.7 0.1 Difference (% of span) 0.20 1.41 0.20 Drift (% of span) 0.40 1.01 Drift (% of span) 0.00 0.40 Drifl (% of span) 0.60 0.20 System Response (ppm) 0.3 25.4 System Bias (% of span) 0.40 0.81 System Bias (% of span) 0.00 1.81 System Bias (% of span) 0.00 1.41 System Bias (% of span) 0.60 1.61 GP043AS-025822-RT- 1 3 30 Page 131 of 174 Post-test #4 Bias Analyzer Response (ppm) 0.1 25.8 Post-test #5 Bias Analyzer Response (ppm) 0.1 25.8 Post-test #6 Bias Analyzer Response (ppm) 0.1 25.8 Post-test #7 Bias Analyzer Response (ppm) 0.1 258 Post-test #8 Bias Analyzer Response (ppm) 0.'l 25.8 Post-test #9 Bias Analyzer Response (ppm) 0.1 25.8 System Response (ppm) 0.8 24.9 System Response (ppm) 0.2 24.9 System Response (ppm) 0.3 24.9 System Response (ppm) 0.1 25 System Response (ppm) 0.2 25.1 System Response (ppm) 0 24.6 System Bias (% of span) 1.41 1.81 System Bias (% of span) o.20 1.81 System Bias (% of span) 0.40 1.81 System Bias (% of span) 0.00 1.6't System Bias (% of span) 0.20 1.41 System Bias (% of span) o.20 2.42 Drift (% of span) 0.81 0.20 Drift (% of span) 1.21 0.00 Drift (% of span) o20 0.00 Drift (% of span) 0.40 0.20 Drifl (% of span) 0.20 0.20 Drift (% of span) 0.40 1.01 GP043AS-025822-RT- 1 330 Page L32 of 174 Post-test #10 Bias Analyzer Response System Response (ppm) 0.1 25.8 (ppm) 0.1 24.8 System Bias (% of span) 0.00 2.02 System Bias (% of span) 0.20 52.02 Drift (% of span) 0.20 0.40 Drift (% of span) 0.20 50.00 Post-test #11 Bias Analyzer Response System Response (ppm) 0.1 25.8 (ppm) GP043AS-025822-RT- 1 330 Page 133 of 174 Company Source Date Sample Gas Span Sunnyside Unit EU #1 5t16t2023 so2 240 Analvzer Calibration Cylinder Value (ppm) 0 99.8 240 lnitialBias Analyzer Response (ppm) 0.1 98 Post-test #1 Bias Analyzer Response (ppm) 0.1 98 Post-test #2 Bias Analyzer Response (ppm) 0.1 98 H@ Analyzer Response (ppm) 0.1 98 Analyzer Response (ppm) 0.1 98 238.3 System Response (ppm) 0.1 95.2 System Response (ppm) 0.4 93.1 System Response (ppm) 0.1 93.1 System Response (ppm) 0.4 93.4 Absolute Difference (ppm) 0.1 1.8 1.7 System Bias (% of span) 0.00 1.17 System Bias (% of span) 0.13 2.04 System Bias (% of span) 0.00 2,04 System Bias (% of span) 0.13 1.92 Difference (% of span) 0.04 0.75 0.71 Drift (% of span) 0.13 0.88 Drift (% of span) 0.13 0.00 Drift (% of span) 0.1 3 0.13 GP043AS-025822-RT- 1 330 Page t34 of 174 Post-test #4 Bias Analyzer Response (ppm) 0.1 98 Post-test #5 Bias Analyzer Response (ppm) 0.1 98 Post-test #6 Bias Analyzer Response (ppm) 0.1 98 Post-test #7 Bias Analyzer Response (ppm) 0.1 98 Post-test #8 Bias Analyzer Response (ppm) 0.1 98 System Response (ppm) 0.9 93.9 System Response (ppm) o.4 93.8 System Response (PPm) 0.8 93.5 System Response (ppm) 0.9 94.3 System Response (ppm) 1 94.1 System Bias (% of span) 0.33 1.71 System Bias (o/o of span) 0.13 1.75 System Bias (% of span) 0.29 1.88 System Bias (% of span) 0.33 1.54 System Bias (% of span) 0.38 1.63 System Bias (% of span) 0.71 1.54 Post-test #9 Bias Analyzer Response (ppm) 0.1 98 System Response (ppm) 1.8 94.3 Drift (% of span) 0.21 0.21 Drift (% of span) 0.21 0.04 Drift (% of span) 0.17 0.12 Drift (% of span) 0.04 0.33 Drift (% of span) 0.04 0.08 Drift (% of span) 0.33 0.08 GP043AS-025822-RT- 1 3 30 Page 135 of 174 Post-test #10 Bias Analyzer Response (ppm) 0.1 98 Post-test #l l Bias Analyzer Response (ppm) 0.1 98 System Response (ppm) 2.4 94.1 System Response (ppm) System Bias (% of span) 0.96 1.63 System Bias (% of span) 0.04 40.83 Drift (% of span) 0.25 0.08 Drift (% ofspan) 1.00 39.21 l l li il GP043AS-025822-RT- 1 330 Page 136 of 174 Company Source Date Sample Gas Span Analvzer Calibration Cylinder Value (ppm) 0 9.96 19.56 lnitial Bias Analyzer Response (ppm) 0 9.9 Post-test #1 Bias Analyzer Response (ppm) 0 9.9 Analyzer Response (ppm)' 0 9.9 19.5 System Response (ppm) 0 9.8 System Response (ppm) 0 9.8 Absolute Difference (ppm) 0.0 0.1 0.1 System Bias (% of span) 0.00 0.51 System Bias (% of span) 0.00 0.51 System Bias (% of span) 0.00 0.51 System Bias (% of span) 0.00 1.02 Sunnyside Unit EU #1 511612023 o2 19.56 Post-test #2 Bias Analyzer Response (ppm) 0 9.9 Post-test #3 Bias Analyzer Response (ppm) 0 9.9 System Response (ppm) 0 9.8 System Response (ppm) 0 9.7 Difference (% of span) 0.00 0.31 0.31 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.51 cP043AS-025822-RT- 1 330 Page 737 of t74 Post-test #4 Bias Analyzer Response (ppm) 0 9.9 Post-test #5 Bias Analyzer Response (ppm) 0 9.9 Post-test #6 Bias Analyzer Response (ppm) 0 9.9 Post-test #7 Bias Analyzer Response (ppm) 0 9.9 Post-test #8 Bias Analyzer Response (ppm) 0 9.9 Post-test #9 Bias Analyzer Response (ppm) 0 9.9 System Response (ppm) 0 9.8 System Response (ppm) 0 9.8 System Response (ppm) 0 9.8 System Response (ppm) 0 9.7 System Response (ppm) 0 9.8 System Response (ppm) 0 9.8 System Bias (% of span) 0.00 0.51 System Bias (% of span) 0.00 0.51 System Bias (% of span) 0.00 0.51 System Bias (% of span) 0.00 1.02 System Bias (% of span) 0.00 0.51 System Bias (% ofspan) 0.00 0.51 Drift (% of span) 0.00 0.51 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.51 Drift (% of span) 0.00 0.51 Drift (% of span) 0.00 0.00 GP043AS-025822-RT- 1 330 Page 138 of 174 Post-test #10 Bias Analyzer Response (ppm) 0 9.9 Post-test #11 Bias Analyzer Response (ppm) 0 9.9 System Response (ppm) 0 9.8 System Response (ppm) System Bias (% of span) 0.00 0.51 System Bias (% of span) 0.00 50.61 Drift (o/o of span) 0.00 0.00 Drift (% of span) 0.00 50.10 cP043AS-025822-RT- 1330 Page 139 of 174 Company Source Date Sample Gas Span Sunnyside Unit EU #1 5t16t2023 co2 26.85 Analvzer Calibration Cylinder Value (ppm) 0 11.68 26.85 lnitial Bias Analyzer Response (ppm) 0 26.9 Analyzer Response (ppm) 0 11.7 26.9 System Response (ppm) 0.1 26.8 Absolute Difference (ppm) 0.0 0.0 0.0 System Bias (% of span) 0.37 0.37 System Bias (o/o of span) 0.37 2.98 System Bias (% of span) 0.74 2.23 System Bias (% of span) 0.74 1.86 Post-test #1 Bias Analyzer Response (ppm) 0 26.9 Post-test #2 Bias Analyzer Response (ppm) 0 26.9 System Response (ppm) 0.1 26.1 System Response (ppm) 0.2 26.3 Difference (% of span) 0.00 0.07 0.19 Drift (% of span) 0.00 2.61 Drift (% of span) 0.37 0.74 Drift (% of span) 0.00 0.37 Post-test #3 Bias Analyzer Response (ppm) 0 26.9 System Response (ppm) 0.2 26.4 GP043AS-025822-RT- 1 3 30 Page L4O of 774 Post-test #4 Bias Analyzer Response (ppm) 0 26.9 Post-test #5 Bias Analyzer Response (ppm) 0 26.9 Post-test #6 Bias Analyzer Response (ppm) 0 26.9 System Response (ppm) 0.2 26.2 System Response (ppm) 0.2 26.3 System Response (ppm) 0.2 26.4 System Response (ppm) 0.2 26.4 System Response (ppm) 0.1 26.2 System Response (ppm) 0.1 26 System Bias (% of span) 0.74 2.61 System Bias (% of span) 0.74 2.23 System Bias (% of span) 0.74 1.86 System Bias (% of span) 0.74 1.86 System Bias (% of span) 0.37 2.61 System Bias (% of span) 0.37 3.35 Drift (% of span) 0.00 0.74 Drift (% of span) 0.00 0.37 Drift (% of span) 0.00 0.37 Drift (% of span) 0.00 0.00 Drift (% of span) 0.37 0.74 Drift (% of span) 0.00 0.74 Post-test #7 Bias Analyzer Response (ppm) 0 26.9 Post-test #8 Bias Analyzer Response (ppm) 0 26.9 Post-test #9 Bias Analyzer Response (ppm) 0 26.9 GP043AS-025822-RT- 1330 Page 141 of 174 Post-test #10 Bias Analyzer Response System Response(ppm) (ppm) a 0.2 26.9 26 Post-test #11 Bias System Response (ppm) System Bias (% of span) 0.74 3.35 System Bias (o/o of span) 0.00 1 00.1 I Drift (% of span) 0.37 0.00 Drift (% of span) 0.74 96.83 Analyzer Response (ppm) 0 26.9 1r l GP043AS-025822-RT- 1 330 Page L42 ot t74 D.t! and IM 5t16DO23 5t16DO2g 5/16/2023 6:59: 5/16/2023 8:501 NO,co s02 Oz CO: 5/15/2023 6:5E: 5/t6/2023 6:59: 5116D023 6:59: 0.2 49.5 . -0.1 0.o 0.0 0.2 49.4 0.1 0.0 0.0 0.1 19.1 0.2 0.0 0.0 0.'t 47.2 0.0 10.0 8.1 o.r 35.9 0.0 18.3 10.8 o.2 20.5 0.2 18.5 10.9 o.t 9.0 0.3 '18.5 10.8 0.'l 3.1 0.2 18.s 10.8 o.'l o.7 0.5 18.5 10.9 0.'t 0.1 0.4 19.0 '10.8 o.2 0.0 0.0 19.5 10.9 0.1 0.0 0.2 19.5 10.8o,rruo,gffiro.s 0.1 0.1 o.2 't9.5 10.8 0.1 0.1 0.1 19.5 10.8 o.r 0.1 0.1 19.5 10.5 0.1 2.2 0.2 7.9 2.O 0.1 12.8 0.2 0.5 0.2 0.1 27.7 0.2 0.0 0.1 0.1 39.4 0.3 0.0 0.0 0.2 45.9 0.1 0.0 0.1 0.1 48.7 0.3 0.0 0.0 o. r 49.2 0. 1 0.0 0.0 0.1 19.4 0.2 0.0 0.1 0.1 49.7 0.1 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20.0 19.9 19.9 19.9 19.9 19.9 19.9 19.9 19.9 19.9 19.9 19.9 19.9 19.9 1.3 co (ppm) 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 so2 (ppm) 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 voc (ppm) 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Oz t&) 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 COz tft) 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 GP043AS-025822-RT- 1 330 Page 161 of 174 Appendix C.4 Calibration Gas Certificates li il l ,t I i i l t-GP043AS-025822-RT- 1 330 Page 162 ot 174 r:,'j,tjt f.; i -jn;:,l :i ..I.: ?l::!1. t:i:' Docilumb.t: 5233/6 Undc Orr I Equlprncnt Inc- t700 3. ALnt d. Ettrct Lor Angolrr CA 9005t Tr!:323€u{15{Fu:714{l{G!e PGVP lD: E220ll2 CERTIFICATE OF ANAL lEPA PROTOCOL GA| Ctrb:cl(fult@n I]BEPI(GFROYO ut}I8t2tleilDutnl^lPl(rYPiotrcuTlttro0{ril ffi@D&j1a1mt2 Itrdattui&l?En Erfirrt ?tiCOtO,toEilS *dftlttr,r.llEDL1, Frdl:1oiJtflfiE. tclt,zlfirllfrElTl06q,fn&St-ao.r!*^l Cc SoCffiPrleanadttt tr..2@p.ts l{5ltl NlRlr'OTG |1O 7rt1*10.06!r olmtNn Ifli,/IOTBEE" IIO'E' DTEI@rtr Trli rJo.otl WAAMT CcSrcaion laformafun:Carfutba Datc:10lAOf2OD- Icna: 9O Montlu *ptrilotr Erate: 10nM20fi,0 naty&d.rrac.|!i.dEadlU!pfr.2Of2EP Tr.ab0lyMl,OcmnarEPA'.00IR.t2,Elt,rdnoProc.durcl.U.rrCnry.!oU!aAr-rdi.lolutryi.r.duEldt rf r bv.l ot conEdE s, ip.dnrr.ly ffr.r $[i r 6ra.rfa acbr k ' Z Do N.l U.. thb dt dld-f hratE b td tln 100 Pgtc. C@ llpora lif, b-n conECS borrgm B io.drtf d.d AnfulData.. (Frel!,rcglrfird,ez6o.1rlGrlffi) f . CryiltG GarDariorr.S El.rrEbtirnt: Trp.rqtEcr* RaS-dcrEaads,t: CI c.r0t doonaiffin: arl * h&rnErt tb.d: llorb l/l^{10 gX 2rcleawx Ail!,icd5rd: ltDR U.luu$offiqDlrlbn 10a1r?fi22 E 0 & 7Ot C3 a.ol coi3: tt, 7n, ar O G C,02 Com: tol& 0 C: C.6 E t.oa CcrG: G.ql lDI: f IrnTItAr-r: G-01 f C'ltpaa. Orytn R.Crr-Ldcmffrto.E lD* Cr0ldcoic.,ilrr: D.S* mlrratlrtrd! 8ilmouracEsrNTlE2qllil@A'r Arly{olfftIrd: hEmlric LdirtlfdcllEolr ldAfxtn 7 O R ar75 c: 9.Sl Cclic: 9L R. el71 & O C: 3.ltt Ccnc e.S 2t O C: 0.e67 R. 9tE, Ccnc e,5 UOX: I LBT-tA...t: 9.S l3 &rEl, CnffionrUiilihtf EqrollDn :IrrclrlLb: sRr,trtlrn$rilqlnd.rt: SRl, CoEnffir, UEtrhtt: SRf,l Erpfr&nDrl.: 4,0t0C:0Ccno:o tOZ,0c:0C.n3:0 L,0G:080Gorco llOI: * IrnTd^..ry: tt ir.ilsArri.ri: Trp.rqlnnrt }rruruToor@E, Conc.ntrdn, th.rihM 0Jr5 f rO-oao f Edntblo.b: 1tnQtaIA Tn .6bb: SRll l, 8]tPl.r, Crfilbl] NInX, t70701,UIEId[a 8Rll Catilrfiloa, UnE dntf gl7Ef , io.oaof 8RX Edrdon Otbi lllluE&2 C.rlld B, *,OR:0e0Ca.:o &020C:0G.io:o Z 0 C3 0 lt 0 Gcmlo lrOI: ll LnfdA..{: * fll}{cC m.H.mdo,ldJd bortDbbh. &rioth.|p.olbrdnrplbnnr4m&mnmrrysEe.rndonrblh3rrtruiyolthrl[oalrr lrfur.lbibrnyn4nThffiof odh.tirJthtauldrt[rthgtmrryr.ot!:Hurnonbaltlrrb.tqilon,ldrhlollh.rr. lnEmntrhdllh.bllyof ]S.,.GrtEquFrnllnhc.,.rlrgaf of thc E ot t\G ftSfIndoo oldpd Mn ood t! [. ..Lblbhrd tr prE fi&g rdt ttfuillqt 10,24rr0!0 cclo7?,1 6.01 '.0.96 ta Bdmcr C.rton dbdd. Oryg.n Nlt'qon r 0.05 '6t 0.04% hoSpuEZ Cut GP043AS-025822-RT- 1330 Page 163 of L74 LInd. Grl & Equtpment trrc, 5700 S. Ahrcdr Strrt Lor Angohl CAe0OSt T.l! 323-5tt5.2t54 Frr:71{€12{G!9 PGVF tD: Fingtz Docf{umbcn 520!Sa gWryar ry e {ANALY'nN ispe pffi 1021,20!0 DTM$EG' {1.0E ta te.56 tt Brlrncr Crrton dlorldc Orygon l{ltogen t 0.05 r r 0.0a tt Cubrur&Orbl4ft fuD IGEPIG PNO\,o UTHS '2TTS NDI'EIRruPKWY PBrtO UTtrt800{t!t ereartrirD Et $Ailda.,,,d.tuttur.rr't44m Eir$nt RNtCDiZ(IeiE{S A*nqFDt.4'0ry.!/0z!r,t FtD,f,'lotutu,. l,,tt,/n,',..trc'nut Q,tlargfit Ait As COA5roc,ffirfitl0,[ tnlyof,f 2O@Elg l6(tia ccrlificelion lafonntion: wn Detr,:1ofuno22 Tetm:96 Monttrs *pwon Dab: lOtlLlEO3o nta crtr,, E Ertftd EilOrE b rh. 2Oi2 Epr Tr-ort.t, protot Doqrlri tlpA{0ol+l2lEil.u''oain'y.lbtnt;-,t-".a-+r-d;ryti:*:ffi-i'i.[1+fd;r;tD",&E-rfiilHfrffifatlyffigrffr.,@.dr'.bt/taoo.d O(,2rslratrrnb..lrcorfuutlleyfrn lRarqrhnlrrgc{f.l. &!rrgolrlrrbrm E'ttcbdtrCIOAhhrfrun. Aaalytical Daa:l.@ oErtr,.m. W, ZEZ.D Grl|, Cr6b3 *0.) Cattsr.idd. R.SraECm.3t*n: fZ* mi.dconclffoi: ttrS'x llttll,trutUaad: Atlthtr&Godl t!.lb VlAt1o 8/N 20c1g4liyt( NDIR f,rtorcrtntd: Typ.rCy0nlr* oxlgrcqrTfolo Conomhlm I una[trfy: l42o f :ro,c! fEffiarDrb: Olnlrat8c,Tr.c..!- b: SRir trnmpStrcytnd.r* NTRMT]vA I C,inrc SRi, Cmrffioo , Urrorlhtf tg!.f , rr,o$fSil E pfilon D.bi Vlll?!&ttl,.d ,{uhott C.lS?.tbr 10//o4,tfr'2 z; O & larf C: fi.0E c,rnc: lttTk, 112f 2. 0 c: lt.O CflE: ttffZ 0 c: tt,!e * [Zt ConE: ltt6 UOf,: f IinTxtAEf 11't * 2. eryr]rt Oryfr i.q-bdColrrtllcr 2o1t C.r0n dconc.rffion: l95a f Itrtl.tE,lt U.ed: 8Llrr,i O,lrnd t€ gr{ 7IB202IrAAOOCA,Ar:Wc.ludtod: hrt,r!rytta lrdUu$ori C.ltsrlonZ Io(,,/,&E Z 0 l! 2o.0 C: IO.5T coac lgsoR: 2ort * 0 C: tg.sC cooc: IO.5"TZ 0 C: IDSC & ZOrf cclc3 tg56llol: r hrtt.rL..ta tg-B t trtf:rl fy CotDllll{bn rUrurtitr Erphtoroat :Tr.rru.5: SRrr rrB.,npb*rcyl,J.rl 8Rf, Courtr,lrurEtl$a SRltEryilarDO: crtlldEy *0R:GC:OCcm:O X: O 2: 0 C: O Com:oZ 0 G: 0 l: o OcGO uil: * IET..ttaarr: f 20,30 t3 roJIt r fl011202! 8Rt{ 2a53r, 7l8t, I FfiIzgtl 20.0!r r ro.ozrt3 QtwaPl Intb?rndlon Bnbhld l:rh h.r !..n lrtDrul dyotl' rquatt by$rrio- ffif#HH#ffiffiffiffiHffi#Hffiffi; ProSpcc EZ Ccrt n6lrnortlndtd: fprtqAforffiT GP043AS-025822-RT-1 330 Page 164 ot 174 E-ffi;ry Docilumber: 533912' Llnde Gas & Equipment lnc. 57OO S. Alameda Street Los Angeles C490058 Tel:323-585.2154 Fax: 714,342.6689 PGVP lD: F22023 TIFICATE OF ANALYSB /EPA PROTOCOL GAS Custofrct & Order Inlormation . . LGEPKG PROJO UT HS 1211S INOU$TRIAL PKWY PRovo ur !16064136, Cd,lificele lssu?nca Data : 02 On023 Lhde Ordet Numbr 72344367 Prrl A/umDar Nl CD27E.AS Cuslory PO Numbo,: 80351658 Fit Oat.: O2n3f2023 Lot Numbcc 70086303406 CylindarSlyto&Oulet:AS CGA580 Cylindar Pressure and Volume:2OOO pcig 160 fi3 ts C,Concentration Expiration Date: Cylrnder Nurnb,or:''r 0210812031 cc4sT252 NIST Trsceable ExpanCed Uncertainty 26.8s % Balance Carbon dioxide Nitrogen t 0.06 % C e r tiftc ati o n I nfo r m ati o n :C e ttific atio n D ale : O2l 08 12O23 Ierm: 96 Months Explntion Date : 0210812031 This cylindrr was mdif€d 8@ding to th€ 2012 EPA TEE€bility Proto@I, Documonl #EPA-600/R-12531, using Prsadure G1. Un@rlainty lbov€ is lxp.e8sed aa absoluto axprnded uneirint al ! level ol csfidehfi ol lpproximately 96% wlth a @verEgo ,ac1s k = 2, Do Nol Use thls Slandard ll PEssurs ls loss than 100 PSIG. I Anabrtcal DatA: (R=Raloann stondatd' z=zetu Gas' c=Gas candidat4 1 - CompoBnl: ' Csrbon dloxldc Rglcruncc Stendard: Type / C)/indEr #; Raq@slad Con@ntrslion: C6rllllsd ConEntrallon: lnsln{nsnl Used' AnaMrcalMethodl Last Mullipoint Calibralion: Flftt Anrlysli D.t : 2i... 0. R:.25.01 R: 25.0,1 Z: o Z: 0 C: 26.06 UO$i: 'A Anatfzed By 27 0/r ' 26,a5 6/,' Hdiba VIA{10 S/N 20C194WK NDIR o'il2712023 GMIS / OT0011171 25.01 ,'6 10.05 % 1110912025 C: ZS A7 C: 2637 R: 25.03 C-c!lc; 26.85 Conc: 26.85 Conc: 26.84 Con6nlratbn / Un6rtainty: ExDlEtioo DaL: Tncablc lo; SRM # / Ssmple # / Crinder #: RGM / N/A / CC193512 SRM ConEnfetion / Uncortalnly: 26.S'oh I f0.05./r SRM ExtiEtion Dst€: O5t1Sl20A Cortifed 8y Mrln TGrl Ar.ry: 26.85 % ol thc u6o otthe inlomadon containod horeln exeed the leg ertablished tor proyiding sucfi inforrolon. Page 1 ol 1 ProSpec EZ Ceil S.cond Amly8iD D.ta: Drtc Z:OP'OC:0Conc:O R:OZiOC:0Conc:O Zz0C:OR:0Conc:O UOM: % MctnTestAsas)r: % GP043AS-025822-RT- 1 330 Page 165 of 174 ;:;,APNNilR Pmxelr 5700 Sadr Alarocda Srct Las Argclcq CA 9005t Tcl: (323! 5t5-21t4 Fa(714) s,{2{5t9 POVPID. FZN17 , CERTIFICATE OF,4ATALY;ST^S / EPA PROT'OCOL G,4S It Qtmrut a {ru l{or;don: Doci{umber 00Ol I 15G} AMERICAN EiIVIROMEMTAL 6823 S 3600 W SPANISHFORK UT 8466G Prulr Oder l,ttabq: 92316671 Clrlanrlr P. O, Ntotfl,r: O Cwta*rRt$ntw llrrmbr: FtllM: Gl12t?o1t MNEbt Nl SOCttE As lttNt',':: 7lre7tctts CylMcrglctltu: AS @ASOO C\l&rhsnltbt: 2(D0pd9 l4Ocu,lt.Cer$ltt Conccnfrotbn: Eeiration Datc: fl2gl2025 Gyllnder Number . Ccl020gl NIST Trsceeble Analytlcal Uncotulnty: 99.E ppm SULFURDOXIDE ,1% B.bnce NIIROGEiI Ctr{doa l$otntdon: @tt fu,ttoitt Dete: 81i2912017 Term: 96 Months Expl1E/'6n Dab: 6t29t2o25 Thleqdlxlerrval onincdseg{lngtotie20'l2EPATracoabilityProtocol,Document#EPA€@/R-12/531,BlngPmcadupGl. DoNd Usc thlr $rndard if Plg$up lr lesg thrn .l00 PSIG. AarfficelDato: f . GorFon nh 8lf,FuniiqD€ ltrClcdCffimfrn: C.r{fild Concanlrdon: lr*urrnl (lrct Anrlythrl ftl.lhod trrnrllDoilcs{!{o.r Ftr^rdrtb D.tr- (R!n€6nen6 SbrrCrrd, Z--Z.o @1 C,€,as Uaffi) 9ippm S.8pp.n HORIBA, 14A61 0, 62@s5101 1 IIDIR d6t2o17 Dra: AEEtzOl1 Rdt r|oSt ndardTt .: l{TRfa R!4. 6ti CyldGr*. SAlffi] Br. &d CsG e5.17 ppmRd.SldTrrulbSRlrr: 1&fl@ SRilSrrprcf: 1?gt@tf SRll Cy'lndtl|: Z t Z UOI: o 5.1 0 F9{n t z: C: e5.2 0 s.8 ColE: Cooc: s.qp s.7lE C: s.9 Cz gg.7 9.2 0 s.9 D.b: upmlf C: 09.s Cotr: 90.709C: S.9 Corr: 6.?e9R: 85.3 Cooc: B.IS& e5.1 LUT- S.EEB @.gl8pDm u.. d lta lrlbririlial stffi irrln ar.ed hc frG rd.Hlftad 'bf proyi.frg srdl Hocrdbar Andfzed bI "*'T',#*il/ GP043AS-025822-RT- I 330 Page 166 of 174 Qnorut& fu lr{ordo* ATIIERI CAN E]WIROTI,ENTAL 8823 S 36m W SPAr,,llSH FORK UT E1600' Ptualr Odcr ltuabr: E7e12212 Cwtonpr P. O. Naa,}r,r: EPA ORDER Cuslqa? R4lerare l,lt nbr : Pnrrlr 5700 Sodr Alarncda StrECr Los A4cles, CA 9005t Tcl: (323) st5-21t4 Fu:(714) 542{689 FGVPID: frn017 Flflh* 17run7 Pa.ltu: U8O!I4F s Lallab: tmTBE Llltu$yhtfubt: AS CGAIIO LYabhwttYolut* Zffip19'l.Ocrr.ftCcrlSbd Conuttubn: CaWal$ondon: Oefiificr,flot 0cie: 3l1li2O17 Ierm: 96 Monthg ExphnonDab: A1fiN25 Thb cyllrder was oeilllied acording to the 2012 EPA Tnceabllity Probcol, Document *EPASO0/R-121531 , rrslng Proccdurs Gt. Do Not l,Jge thlr Stended lf P]lsrun l8 bs3 than 1m PSIG. AaeffiUlDaa: 1ftfr6rs6$.rrdtd,b2.m*,O'Gaacrnahb, l. Co.tfil.lt grlXrRl,IrIDE Raqaodcdtcadtaht 2/oPldn C]didco.rrilo.t zlloppm lrfrrrrrrt Urc t(,RlBA, V!A61O, 5@:l55l0ll AillYllcd llbtEt ilIR Ldrffdpohtc.Edrt 2n7ta17 Analyzed by: R.ll{rrs'bndrrdTt?e Gfals R.r.8l4 Ctlilrhl: OC3olB R{.8ts CqE 5cl.tpprn R.L sd Tr.o-lebaRila: 16rrs8rrS@Ll: oa+t6 SRtrr Cllndrrt: FFAU tcordAdFlrD!h:D.b: sAlZglT G: A0 CqE: ?eefi R W Co.rc 6.11 I..nIotL..r: T._*f. Rl5GZOc: 2iF 2i & Zz IDI: E of tlE intunaio.tconhLd h..ah mdirboaatubtt(, for D.ovtdhe &€trhb7nrdm' ceilinedbY: ffi-l- Docilumbec 0fi1o{.721 CERTIFICATE OF.ATYAL}"ITS / EPA PROTOCOL GAS Bglration Dete: Cyllnder Numben ltno25 ccr50890 NIST Trecaablo Analytica I Uncsrtainty: r 0.5 962ry0 ppm SULFUR DIOXIDE Bebnce NITROGEN GP043AS-025822-RT- 1330 Page 167 of 174 ,it?i|lt! nu: '.!(ffJ .neI! t.G lJlii. -' DocNumb.r: 45397a Llnde Gar t Equlpment lnc. 5700 S. Alrmcdr ltrrol Lor Angoh CA 90058 Trh 323{85{154 F.I:71.3{i4266E0 PBVP 1O.F220Z2 CERTTFICATE OF ANALYSIS /EPA PROTOCOL GA.g Castoaa * Odoltfondot ICEPTG PROVIOUT H6 12'|l I I{DUaTRTAL P|(WYpttol/C' UT 04s,4136 For Refcrence C e rtiJicat io n Info r m ilio n :@dlflcatlon Da1a;Og12nO22 lerm.. 96 Months Ex plnt/orr Delta : O5l12f2O3O Ttftcrlndtrra.catUi.d.lEdtrgbth!20l2EP TracbltyProlod,Osarm.{r€P^{@rR-12/s!1.rlhgPoordurct, lrEblnty.bo.lrpnocdrrrbotut rg.rd.duEtshtyrte lorrldanthnoolapprcoondyeSf d$!Eovngohcb.t-Z Oo NoturoOrb Stnfid-f *runbhnnm tOO pstci. - - AnalyticalData.' Frnetryresbn6r(,&zrrccrt,rcrffi, r. colEFoorrt llltlc.{rh R.|bmEEnrth: Tn rcy0ndGrf: W td,aDd.:Wt?lAta, Lhdor#lt nbrzlGle0a pr,luimDc t{t}to7CrE{a citutw?Or*m0'r',J&141 tDt:O*zilNu2 rd,lt r6.f, TUlCOillt71O C)dr,*r S0- t ArH' Al CGA GCo Clffior Pltr,,,'r..t d [4m: &0 pr[ iloil, Gl,,tstcE7iam S.9 Dplrlro't p?ir 01n6tzE, 1C8& ' aa-I-20 ' FFO!o 9e.75 p9m / rr.5 DFl! oltz,/,oin Raqurbd Corloflfrilor C.r{adCo,rnfa{ot: kpfunqrt Urad: Andylhd Mltbd: L..t liulthdrl Crlhlor: ?5 PPn 7l.5p9m Ih.mD EbEron azl-Ls S/N t606{607 chqniumh.a€ne utawa Coneil[t(,t , Unarltmy: Estrilon O.b: rmrht b: SRMf/Srnpallcllndril: BRM CorEft.lbo,UisLlilf Silr Etdr.rbn O.b: Ctmld By Aa.td 2. 0 & S.e C: 71-7 corc 7t,, Ri 96, Z O e ilS Cmc ?,tt Z o c: 7tl.O R: 06.9 caac 71.9 lroll: PPm lonT.rt^!.tE lai pFD 05n2ti1030 sAt8128 l{itrlc oxldc l,lltrogen ProSpcc EZ Ccrt EfEIEHffi.E e O i: 90.9 Ct 1a-a coic 7a.a R: 95.9 Z: O Gt 71.5 Conc 71.5 Z 0 Ct 7a.6 R: gl Cms 7/15 UOX: pr XmTE!4!.r!z l1l Drfir ]]fE trrton conl8lrd lEh tt$ b-.r |x!9rt!d d,ur rtqlEl by qdlfid lr$arb ettrh Llrda Gc e Equ[mnt lnc. Wilh E bcla! th.t th. kil.fbn t prt rutrrh ri: lrtb dtr 9al!49 "1dl+ "!lpl# ara b Eid3ro b ,|e .rarr ot th. ipadlc rrdfu prrurm4 s ,rdr m'rimr|yor nponairdbn c U tto UUg-of rr rr A m fcnrrlon lti.,ry D,rpa._Th3hfordoibonbdruftrh.l5dttbnrtBttrt!ny_u!.otltthrmtmtaurotolnffnndd*oa-tl.uiL, lnmmtrhrltrhotcu'u t*roce.ecqlernai'riii..'lffior., ta tn ot h. lntuf,n lbn onffnd huoh acccd ll!-l!G dlab&lEd h. pryldhe rudr ttrorr*trr GP043AS-025822-RT- 1 330 Page 168 of 174 : ; i:€ii i t' :i .i; .ti i;l; Italfu ar ptopt noe pdrt'w DocNumber: t107578 Prexalr Dlrtrlbutlon, lnc. 5700 S. Ahmeda St oct 1o Angoler CA 00058 Tel:32368$2154 Frr 714{42{E89 PGVP lDr Ftloll CERTIFICATE OF ANALYSIS / EPA PROTOCOL GA'1 Cuooter & Ottct ltttonulton PNAXAR PKg PROVO UI TIS 121t S INOUSTRIA, PlorY PROI/O Ur EaCGt138 For Refereace Onty: C e rtifrc ado n I nfo rmatio n : R.qu.dad Cr.rllEtm: C.rlifi.dMtlbn: HurBaU!.d: ArCydc.l U6$.n: Lrt litdtpo,i{ Calbotlon: NOx 101 ppm Certillcation Date : 01 I 1 9 2021 Icrm; 96 Months Ex p I ntl on D ate : M I 19 t2ON Irlt qdrr,as€rttLd rd}E rotE 2ol2EpATrEbiIryPllbd,oGtMtrEPA{eR-12/531, udig_ProedurD Gl. tlm'lslrtylbopbqFBltda.bcolutratgsndod ufiriin$ er afmr d s1r*no-ol gpfrcotnigy CEX wi0l e;urwleo iaaorf ' Z. Oo ncf tha fir Strli.btd It PtlBuE is 16! [[n lm PglG. AtulyticglDgla: (F'netuoGs'ilde'd'z'zmcrt'Gc"c'e",, 1, @dl9orr,,fr tltl3odtlc Ralbrtrttrarr.d: TtF/Cylndti: C.rffIcto butac, t cDt 04l1sl/,0,21 Arrr& Or*/ rtlrrDef; 7 1848906 Prr rvrrr$cr Nl Nol80Eds Fn Odc:O.,l05lilglt Ld l,lut rbar 700661@t05 cyfirdr sv. t ad3n As cs^ e60 CttodctPt M$d yduD:2O0opalg 1a0fis GMIS ' DTq)t3552 25t ppm rt ppm 05r07/2028 t665b / a3{-ril clLo173o. 2€.e ppmr11,1 Pem 05109,2020 leo ppm teo pprn ltElm Ea.tron 12ls/N ol28Gl(ff6 Orqira!dn!m olficr2g,t1 CmatEtm, Un6tfdniY: EQhrdo D.lr: fr.st bLlo: SRMt/ssmC.t/Cyfndrl: SRU Concenrdion (mbrri& ult)/ 2t o Rr 256 G: t6OJ Cat: 160 & 268 Z O Cr 1G03 Co.tr l!(l Z 0 C: !a).5 l: * Gonc: '16l tto* ppm LtnTEtAur: 160 PPrr Amty4.rBy Catfled 8y hbnEton mtahrd tsrh hra bsil pEp.rld Bl ylr rsqHt tsy qudf.d dprrb wtlHn Fteir Dt*hrtbo. hc. lrifG tr bcim ihrt the lnf(mfo l! .grt ttlhlo tha llf{iB of tha snalytol irnmtsr6oiUnOrlth!t3iEffitdngtntanyuiotuefrbrhat6nfaursrdsCsntorerrriirottpw. lnnoGmldEtliclisb&tycrPndrObn$diclr,lnc,dtdr{dlottrare o( hE Hoflrdm 6ddrd hslh axE d tE fro ostilshod tot ProYldil€ ltrdl lnbmaton. E yxsr,vl vvry, Cyllndar Number 04t'3,nox, sA3252 Nltrlc oxlde Nitrogen ProSpec EZ Cert E}filfl+ffJeLE SRM EplElion Oota: !.@dd Antlyrl. O.t!: Ott o,4l?er''Xnl Z o R: 256 c: 160,e Cffi: 160 R: 28 Zi 0 C: 160.8 Cilcr l0O zt 0 c; 150.7 E zfi Gmcl toll: ppm LDT!d^E Y: llo PPm GP043AS-025822-RT- 1 330 Page 168 of 174 i,'l:rL'r ffi C o,llbb l. twr1Eo D da : 1 2l z2tazz Lhdc Ordor Number 7ZZ9110! Pln NuDDer Nt COZsME-AS Cudonor Po Numb.r 8029?il3 Llnde Gas & Equlpment lnc. 5700 S. Alameda Streel Los Angclas CA 90058 Tel: 323.585-2154 Far: 714{026689 PGYP lD:FZ2OX| Fit Data:1U1UNAI. Lrl N urnbo r : 7 00862141 Oz Cy'ln&t Styto &Oq(ot AS CGA gSO Cylin*r Pfr$m ud Votunto: 2OOO WIO 147 lt3 DocNumber: 530554 Cusrom., &. Otdcr Inlontatio n LGEPKG PROVO UT HS 12tI S INDUSTRIAL PI(WY PROVO UT 8460&8136 Analvtical Data: 1. Compo,ruC ProSpec EZ Cert ffi Certi/icuion Information: certificaaon Date:1212112022 rerm.. 96 Months Expintion Date: 1212112030 Thls crindsr ms otlifEd 8@ding lo ths 2012 EPA TErabirty Pmlool, Dodmont tEpl€00ft-12,/531, usirg pDedurs Gl uncsdalntv ab(unelbintv al a levolof mfid.nca ot apprcxnntatv os% *itir-i"w.ag" i.crc i'= ,. D;i;iu;; d;il;drd n 'EUE is rE* t "n roo psrllis o'Q6sd !s absoluto orpandsd Certifi ed Concentratio n Cylinder Number: 12/21t2030 cc167112 Expanded Uncertalnty 25.1 ppm Balance Carbon monoxide Nltrogan t 0.1 ppm (R=Rslorcnu Standud, }izamOas, C=casCudldat ) Carbon moMlda Rcqussled Con@lBtioft 25 ppm C€rtlfod Cononlration: 2S.t ppm lnstrumrrt Used:Hodbs VIA{i0 S/N 57067S015 AnaMjcd Mothod: NDIR Llsl Murupotnt Calibtalon: lZljSlZOZ2 Fht Amlyrlt ZO R 24:0 ZtO UOU: ppm Amltrz€d By RrirmncoStendard: Typs/Cylhdor#: Conentration / Umrl,Elnty: Explntbn Date: fnc.rbl.to; SRilJ/Sampto,/Cylndor#: SR, Cmcsntrefpn / Unertainv: SRM ErpiElion OEb: C€rtifled By GMIS / OT0o08ri88 25.02 ppm rO.04 ppm 0s/1912030 sRM 26354 / 5&E-34 / FFl 0866 24.512 ppm I r0.O2e ppm ua7m29 R: 25 Z:o C: 25 C: 25 Conq C: 25 Conc: R: 24.9 Conc f,[n T..lArrry:26.1 ppm 1 25.1 25.1 2s.1 Z:0R;gC;OConc:O R:OZi9C:OConG:O z:0c:0R:OConc;o Uolli ppm lltm T.rlALy: ppm 4,4 a\,\) otlhoGeofhelnfomalion6nl.t*dl".i""i&i'trri,i**-riiii-JJ-iorp.riaingir;ltffiffi.'-'-"crolli'uaar' lnmsvenlsh.lltholial pas6 1of ,t CERTIFICATE OF ANALYSiS, GP043AS-025822-RT- 1 330 Page 169 of 774 LAaryM@ DocNumber: t0o023 Pnr.ir Dbtrlbrdon, lnc- 5700 S. Alemedr Stust Lc Angclco CA 90058 Tcl: t2!{E5-2164 Fer: ?l{{{2{6t3 PtG\lP lD: FZ2,,aO &nus&th*rlttu;tfua AilEBrcA'{ ENVIR(IIEXTAL 8&I1S@W SPANEH FORK UT IIgt.ItO4 w@t,,rnr@lfu(,lntrfrlJ Pr.rtd- rtu$finaiE, ftrr&z0or Nl cOSortF,As e,ir'6,otrr'Pcrt//ilitu - CERTIFICATE OF ANALYSIS / EPA PROTIOCOL G..{,S Flmj@t121&n t lr*r$.,:7uE!e$@ Clririlrsort r OAt A8 . CGA!50 Qf/I/fur,Damaxl ltt Tr.'20XPP.O t/olE ProSpcc EZ Cul ffi C en lfi catb n I nfonnn io n :@rblfiatbn DaE,:O2llUinzO lerm: 96 Monihe Exfllt,fot, Dde: OA1ED028 THr.Ullndswrc{nrdEdho iDOE2012 EPATTeTU$y PrltEl, DoarndnlEPr'6@rR-1$St, uthe Prudra Gl. Do flol UBt rb SirnLdtftrubb..trn16 PSIG AnolVtiCalDota: flreborpsrdrd,z'7so*,c"azicarraaal 1. C'qFpirrt cilonmond.a n burc.Strd-{. lt,Elgygn }. GISTCC?'6788 Roqu.tbdcotEnfrttq|: So,Dm Concenf.lbnrlrrrtthnl ga2PPmroill* C.iIHcorrrltdqr ilg.8fm EloidimDrb: olmt&E T'rG..bLb: Sila,ltmplilGylhdor* 8il tt79c,&{45, FF2atB 8R$ CorErntnhn, Umaratry. 9l.O PPMT.O/.o PPi, sRMturrlbrlr.h oltatwn C.dnrd E ;d;tr;rEy.d-drnmplt 6tii-iffi;i*.i;morfuirop..tbtir-E;.korrmirarryorrifnradrrpnrbrh.nllBXtydlrruEorlhoifimuionfrrltrvptpos-Tlr. otlho ffi.nalimcorll)rld ltooln arcd tlr br eleuhlndlrptuddif ructt lfonneilm. 0a1Em28 DT00t6Et0 Cr3: 40.8 Conc; 49.7 Cam: /10.7 z, o &tr:! cz n: fi.z i4, 0 c: Z 0 C: 40.7 R: UOf: pprn sRU E9lrilarD.h LcqtdAnrlylb OrE o.ll *, U i: o C: O Cnng: ii l;oz:0G:0Coneo &,0C:0R30Conc:O UOX: pp,n IrnTa.tAr.Y: PFll GP043AS-025822-RT- 1330 Page L7O ot t74 Appendix C.5 Accred itation Information/ Ceftifications \ir\ ioNt.oCt r tooor' ) rf ) dIFd.c!N@1r ' )Nov, rnsfoC) ' (9 tJ . l '- J (f ) I oz&; FZz:o; =:6 @NoC\ TC\ I lf ,ozokt(LxUJ l. Loulko oEooo:=ooI (Lo-vu.Eg) (l ,$F. (Y )NoN(a lr )oLJ laat ) l!ou,ko \s o.sL ru P a6 E tr E -u ' .e P i pE E -L.E L a r , ? E D E s o. = o EE S EE ; It s 'E 5 S E3 t OG , S c^ gE E E fi 3 ; E O. d E G o F S ( r ) .E . E Es ;a s B *H .> . : t{ h EE #o - :g E * E€ E iI E8 (9 sl aQ . ,E El Er 6 oi v. 2 O = ?- - - fJ s gE E Z EE E E ; g et F EO Y A FB C ) U' coEfooco-Co zoFUIJo-=oolrouJFIlrFt!!o $Ndo(Y )T\ doOlo(L FJ l J Lr a I CZ&; FZ z3c;E: € @(\ to(\ tNorf )o2oEE, (Lxt! lJ -oEI Lo oEo.ho=ogI tI - Lo--(, 'u -ao.. 8 ]- COolo(\ l (Y )or( )oin3al , 9, l!oulko \$ ia € tr t , s ar r+ - .g E .e oE . EE P ? E D =A ar t - Y - v . - a EE $ ET E of o oL E AE E E3 s 3E E PE E EE H 83 H 8E o rE 8j F2 .. ; .l . = 6 EE =v LL .9 tt r (r r st ; :t Ei fi HI 8g 6 ;l EE E ?I EE E T s. Z = = ?- LgE g z EE s t :o = := EA 3 E F( J CoEf(,oCo-Co llII zo-FUJJo-=oC) lrolr JFI]LFtUJo o(' ) coHFdAIN@l. r ! f{o@f4sloo- (9 This is the Last Page of This Document If you have any questions, please contact one of the following individuals by email or phone. Name: Craig Kormylo Title: District Manager Region: USA - Stack - Great Plains - Operations Email : CKormylo@montrose-env.com Phone: (303) 495-3936 Name: Glen Capra Title: Vice President Region: USA - Stack Email : GCapra@montrose-env.com Phone: (5L2) 772-6450 GP043AS-025822-RT- 1330 Page t74 of t74 Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Reference Methods 2, 3A, 6C, 7E, 10, & 19 Source Information Company Name Sunnyside Cogen. Company Contact:Rusty Netz Contact Phone No.435-888-4476 Stack Designation:Unit No. 1 Test & Review Dates Test Date:5/16/2023 Review Date: 1/18/2024 Observer:Not Observed Reviewer:Rob Leishman Emission Limits Emission Rates SO2 NOX CO SO2 NOX CO lbs./MMBtu 0.4200 0.2500 0.0850 0.200 0.167 0.022 lbs./hr. 462.0 144.52 ppm 207.9 96.20 93.608 23.773 %O2 Correction as a whole # Test Information Stack I.D. inches As ft^2 Y Dl H @ Cp Pbar Pq (static) Ps Stack Pressure 101.00 55.638 1.0090 1.717 0.84 23.90 -0.1 23.892647 Contractor Information Contact:Andrew Bruning Contracting Company: Montrose Air Quality Services Address: 990 W 43rd Avenue, Denver, CO 80211 Phone No.: 303-810-2168 Project No.: 1800 Division of Air Quality Instrumental Reference Methods - Gaseous Measurements Round Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc dscf/MMBtu wscf/MMBtu scf/MMBtu Diluent F factor used O2 CO2 Anthracite 2 Bituminous 2 Lignite Natural Propane Butane 10100 COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Wet CEM Correct For O2 CO2 Interference w/CO Yes Yes Yes Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Company Sunnyside Cogen. Point Source Unit No. 1 Test Date 5/16/23 Start Time End Time Run CO2 % CO2 lb/hr Flow SCFM NOx PPMDV SO2 PPMDV Power MW NOx MMBtu O2 % SO2 lb/hr SO2 lb/MMBtu Headers Here Headers Here 8:23 8:44 1 12.8 143912 179695.8 101.1 83.8 58 0.155 5 118.2 0.179 8:58 9:19 2 12.8 143770.4 179217.8 103.4 88.2 58.6 0.158 5 124.5 0.189 9:48 10:09 3 12.8 143666.1 179371.7 102.3 80.4 58.6 0.157 5 113 0.171 10:23 10:44 4 12.8 142942.8 178865.2 102.7 88.8 58.7 0.157 5 125.1 0.189 10:57 11:18 5 12.8 142948.7 178647.6 102.3 92 58.8 0.157 5 130.1 0.197 11:31 11:52 6 12.8 142638 178584.9 102.6 88.2 58.7 0.157 5 124.5 0.179 12:15 12:36 7 12.7 141284.8 176993.1 103 84.8 58.6 0.158 5.1 119.7 0.181 12:50 13:11 8 12.7 142779.1 178926.8 102.8 85.4 58.6 0.158 5.1 120.5 0.183 13:24 13:45 9 12.7 143035.3 179348 101.2 93.4 58.5 0.156 5 131.7 0.2 14:00 14:21 10 12.8 142802.5 177955.1 99.6 97.5 58.5 0.152 5 137.1 0.208 11 12 13 14 15 16 Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 SO2 Analyzer:Serial No.: CO2 Analyzer:Serial No.: Acquisition System:Serial No.: Acquisition System: Serial No.: Equivalent Emission Limit:207.94 0.42 462.00 Test Date SO2 Dry SO2 Dry SO2 Test Date % CO2 Dry 5/16/2023 RM CEMS Diff RM CEMS Diff RM CEMS Diff 5/16/2023 RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. Run# Start Time End Time %c %c 1 8:23 8:44 Y 88.2 83.8 4.36 Y 0.1903 0.179 0.011 Y 135.98 118.2 17.8 1 8:23 8:44 Y 13.9 12.8 1.06 2 8:58 9:19 Y 91.9 88.2 3.65 Y 0.1967 0.189 0.008 Y 142.72 124.5 18.2 2 8:58 9:19 Y 14.0 12.8 1.17 3 9:48 10:09 90.6 80.4 0.1927 0.171 140.42 113 3 9:48 10:09 Y 14.1 12.8 1.27 4 10:23 10:44 Y 93.0 88.8 4.19 Y 0.1988 0.189 0.010 Y 142.17 125.1 17.1 4 10:23 10:44 Y 14.0 12.8 1.19 5 10:57 11:18 Y 97.0 92 4.96 Y 0.2089 0.197 0.012 Y 148.12 130.1 18.0 5 10:57 11:18 Y 13.9 12.8 1.09 6 11:31 11:52 Y 92.4 88.2 4.15 Y 0.1953 0.179 0.016 Y 142.04 124.5 17.5 6 11:31 11:52 Y 14.1 12.8 1.34 7 12:15 12:36 Y 93.8 84.8 8.99 Y 0.1998 0.181 0.019 Y 144.37 119.7 24.7 7 12:15 12:36 Y 14.0 12.7 1.34 8 12:50 13:11 Y 88.9 85.4 3.48 Y 0.1897 0.183 0.007 Y 138.72 120.5 18.2 8 12:50 13:11 Y 14.0 12.7 1.32 9 13:24 13:45 Y 99.7 93.4 6.29 Y 0.2123 0.2 0.012 Y 154.73 131.7 23.0 9 13:24 13:45 Y 14.0 12.7 1.35 10 14:00 14:21 Y 100.8 97.5 3.28 Y 0.2126 0.208 0.005 Y 155.95 137.1 18.9 10 14:00 14:21 14.2 12.8 11 11 12 12 13 13 14 14 15 15 16 16 Average = 93.9 89.12 4.82 0.201 0.189 0.011 145.0 125.711 19.267 Average = 14.000 12.760 1.234 Sd Standard Deviation = 1.81 Sd Standard Deviation = 0.004 Sd Standard Deviation = 2.677 Sd Standard Deviation = 0.11 Confidence Coefficient = 1.39 Confidence Coefficient = 0.003 Confidence Coefficient = 2.1 Confidence Coefficient = 0.086 RA - Relative Accuracy = RA RA RA - Relative Accuracy =9.42% n = 9 9 9 n = 9 or RA of 1%1.24% t0.975 = 2.306 2.306 2.306 t0.975 = 2.306 E.L. Relative Accuracy = 45% 2.98% 48% 3.33% 31% 4.62% a For steam generators;b Average of three samples;9 c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems 13.2 Relative accuracy Performance Specification. The RA of the CEMSS must be not greater than 20 percent when RM is used in the denominator of Eq. 2-6 (average emissions during test are greater than 50 percent of the emission standard)or 10 percent when the applicable emission standard is used in the denominator of Eq. 2-6 (average emissions during test are less than 50 percent of the emission standard). Up dated January 17, 2006 40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems 13.2 CEMS Relative Accuracy Perfromance Specification. The RA of the CEMS must be no grater than 20 percent of the mean value of the reference method (RM) data. 1 percent O2 or CO2. The results are also acceptable if the absolute value of the difference between the mean RM value and the mean CEMS value is less than or equal to 1.0 percent O2 (or CO2). Up dated September 14, 2016 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Eco Chem - MC3 163 Ac t i v a t e R u n ? PassedPassedPassedPassed Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Division of Air Quality Relative Accuracy Test Audit of Sunnyside Cogen. Unit No. 1 NOX Analyzer:Serial No.: O2 Analyzer:Serial No.: Acquisition System:Serial No.: Acquisition System: Serial No.: Equivalent Emission Limit:0.25 Date NOx Dry NOx Dry NOx Test Date % O2 Dry 5/16/2023 RM CEMS Diff RM CEMS Diff RM CEMS Diff 9/30/2014 RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. Run# Start Time End Time %c %c 1 8:23 8:44 Y 108.7 101.1 7.6 Y 0.169 0.155 0.014 120.44 1 8:23 8:44 Y 5.7 5 0.691 2 8:58 9:19 Y 109.6 103.4 6.2 Y 0.169 0.158 0.011 122.39 2 8:58 9:19 Y 5.7 5 0.691 3 9:48 10:09 Y 109.7 102.3 7.4 Y 0.168 0.157 0.011 122.11 3 9:48 10:09 5.7 5 4 10:23 10:44 Y 109.0 102.7 6.3 Y 0.168 0.157 0.011 119.79 4 10:23 10:44 Y 5.7 5 0.721 5 10:57 11:18 110.9 102.3 0.172 0.157 121.76 5 10:57 11:18 Y 5.4 5 0.387 6 11:31 11:52 Y 111.1 102.6 8.5 Y 0.169 0.157 0.012 122.84 6 11:31 11:52 Y 5.5 5 0.488 7 12:15 12:36 Y 109.8 103 6.8 Y 0.168 0.158 0.010 121.43 7 12:15 12:36 Y 5.5 5.1 0.416 8 12:50 13:11 Y 109.2 102.8 6.4 Y 0.168 0.158 0.010 122.49 8 12:50 13:11 Y 5.5 5.1 0.416 9 13:24 13:45 Y 107.8 101.2 6.6 Y 0.165 0.156 0.009 120.24 9 13:24 13:45 Y 5.5 5 0.488 10 14:00 14:21 Y 106.4 99.6 6.8 Y 0.161 0.152 0.009 118.35 10 14:00 14:21 Y 5.4 5 0.387 11 11 12 12 13 13 14 14 15 15 16 16 Average = 109.0 102.1 6.940 0.17 0.156 0.011 Average = 5.540 5.020 0.520 Sd Standard Deviation = 0.74 Sd Standard Deviation = 0.002 Sd Standard Deviation = Sd Standard Deviation = 0.14 Confidence Coefficient = 0.572 Confidence Coefficient = 0.001 Confidence Coefficient = Confidence Coefficient = 0.108 RA - Relative Accuracy =6.90%Relative Accuracy =7.20%Relative Accuracy = RA - Relative Accuracy =11.33% n = 9 9 0 n = 9 or RA of 1%0.52% t0.975 = 2.306 t0.975 = 2.306 t0.975 = t0.975 = 2.306 E.L. Relative Accuracy = EMRA 67% EMRA a For steam generators;b Average of three samples; c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems 4. Performance and Equipment Specifications 4.3 Relative accuracy. The RA of the CEMSS shall be no grater than 20 percent of the mean value of the RM test data in terms of the units of the emission standard or 10 percent of the applicable standard, whichever is greater For SO2 emission standards between 0.30 and 0.20 lbs./MMBtu use 15 Percent of the applicable standard; For SO2 emission standards below 0.20 lbs./MMBtu use 20 Percent of the emission standard; 40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems 12. Calculate the arithmetic difference between the RM and the CEMSS output for each run. The average of the nine (of more) data sets constitute the RA. 13.2 Relative accuracy. The RA of the CEMSS must be no grater than 1 percent O2 or CO2. 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 163Eco Chem - MC3 Eco Chem - MC3 163 Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? PassedPassedPassed Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Division of Air Quality Relative Accuracy Test Audit of Sunnyside Cogen. Unit No. 1 CO Analyzer:Serial No.: Acquisition System: Acquisition System: Serial No.: Equivalent Emission Limit:96.20 0.085 Date CO Dry CO Dry CO 5/16/2023 RM CEMS Diff RM CEMS Diff RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. 1 8:23 8:44 24.05 0.023 16.23 2 8:58 9:19 23.89 0.022 16.24 3 9:48 10:09 23.23 0.022 15.75 4 10:23 10:44 24.22 0.023 16.20 5 10:57 11:18 23.97 0.023 16.02 6 11:31 11:52 25.00 0.023 16.82 7 12:15 12:36 20.49 0.019 13.80 8 12:50 13:11 23.84 0.022 16.28 9 13:24 13:45 24.04 0.022 16.32 10 14:00 14:21 25.00 0.023 16.92 11 12 13 14 15 16 Average = Sd Standard Deviation = Confidence Coefficient = RA - Relative Accuracy = n = 0 0 0 t0.975 = E.L. Relative Accuracy = a For steam generators;b Average of three samples; c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 4 For Carbon Monoxide (CO) Continuous Emission Monitoring Systems applicable emission standard is used to calculate RA. 40 CFR 60 Performance Specification 4A For Carbon Monoxide (CO) Continuous Emission Monitoring Systems 13.2 Relative accuracy. The RA of the CEMSS must be no greater than 10 percent when the average RM value is used to calculate RA, 5 percent when the applicable emission standard is used to calculate RA, or within 5 ppmv when the RA is calculated as the absolute average difference between the RM and CEMSS plus the 2.5 percent confidence coefficient. 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 13.2 Relative accuracy. The RA of the CEMSS must be no grater than 10 percent when the average of the RM value is used to calculate RA or 5 percent when the Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Dry Volumetric Flow dscfh Run Date Start Time End Time RM CEM Diff 1 5/16/23 8:23 8:44 9,280,828.92 2 5/16/23 8:58 9:19 9,349,942.00 3 5/16/23 9:48 10:09 9,323,256.91 4 5/16/23 10:23 10:44 9,199,963.77 5 5/16/23 10:57 11:18 9,192,080.11 6 5/16/23 11:31 11:52 9,255,185.44 7 5/16/23 12:15 12:36 9,262,111.54 8 5/16/23 12:50 13:11 9,390,953.37 9 5/16/23 13:24 13:45 9,338,992.47 10 5/16/23 14:00 14:21 9,311,782.46 11 5/16/23 12 5/16/23 13 5/16/23 14 5/16/23 15 5/16/23 16 5/16/23 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Dry Volumetric Flow dscfm Run Date Start Time End Time RM CEM Diff 1 5/16/23 8:23 8:44 154,680.48 2 5/16/23 8:58 9:19 155,832.37 3 5/16/23 9:48 10:09 155,387.62 4 5/16/23 10:23 10:44 153,332.73 5 5/16/23 10:57 11:18 153,201.34 6 5/16/23 11:31 11:52 154,253.09 7 5/16/23 12:15 12:36 154,368.53 8 5/16/23 12:50 13:11 156,515.89 9 5/16/23 13:24 13:45 155,649.87 10 5/16/23 14:00 14:21 155,196.37 11 5/16/23 12 5/16/23 13 5/16/23 14 5/16/23 15 5/16/23 16 5/16/23 Average = Standard Deviation Sunnyside Cogen. Unit No. 1 En t e r Us e En t e r Us e Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Actual Volumetric Flow acfm Run Date Start Time End Time RM CEM Diff 1 5/16/23 8:23 8:44 311,327.99 2 5/16/23 8:58 9:19 314,098.77 3 5/16/23 9:48 10:09 314,098.77 4 5/16/23 10:23 10:44 310,026.06 5 5/16/23 10:57 11:18 310,626.95 6 5/16/23 11:31 11:52 312,963.75 7 5/16/23 12:15 12:36 310,860.63 8 5/16/23 12:50 13:11 315,267.16 9 5/16/23 13:24 13:45 315,500.84 10 5/16/23 14:00 14:21 314,499.36 11 5/16/23 12 5/16/23 13 5/16/23 14 5/16/23 15 5/16/23 16 5/16/23 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = WET VOLUMETRIC FLOW wscfh Run Date Start Time End Time RM CEM Diff 1 5/16/23 8:23 8:44 10,326,503.35 2 5/16/23 8:58 9:19 10,403,403.42 3 5/16/23 9:48 10:09 10,385,726.75 4 5/16/23 10:23 10:44 10,248,383.24 5 5/16/23 10:57 11:18 10,265,563.83 6 5/16/23 11:31 11:52 10,336,038.83 7 5/16/23 12:15 12:36 10,262,561.37 8 5/16/23 12:50 13:11 10,405,320.09 9 5/16/23 13:24 13:45 10,433,450.34 10 5/16/23 14:00 14:21 10,403,051.54 11 5/16/23 12 5/16/23 13 5/16/23 En t e r Us e En t e r Us e Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 14 5/16/23 15 5/16/23 16 5/16/23 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Wet Volumetric Flow wscfm Run Date Start Time End Time RM CEM Diff 1 5/16/23 8:23 8:44 172,108.39 179695.8 2 5/16/23 8:58 9:19 Y 173,390.06 179217.8 (5,827.74) 3 5/16/23 9:48 10:09 Y 173,095.45 179371.7 (6,276.25) 4 5/16/23 10:23 10:44 Y 170,806.39 178865.2 (8,058.81) 5 5/16/23 10:57 11:18 Y 171,092.73 178647.6 (7,554.87) 6 5/16/23 11:31 11:52 Y 172,267.31 178584.9 (6,317.59) 7 5/16/23 12:15 12:36 Y 171,042.69 176993.1 (5,950.41) 8 5/16/23 12:50 13:11 Y 173,422.00 178926.8 (5,504.80) 9 5/16/23 13:24 13:45 Y 173,890.84 179348 (5,457.16) 10 5/16/23 14:00 14:21 Y 173,384.19 177955.1 (4,570.91) 11 5/16/23 12 5/16/23 13 5/16/23 14 5/16/23 15 5/16/23 16 5/16/23 Average = 172,487.96 178,656.69 6,168.73 Standard Deviation 1,072 Confidence Coefficient = 824 RA - Relative Accuracy =1 4.1% n = 9 t0.975 =2.306 En t e r Us e Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Test Overview NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Point Source Unit No. 1 Contact Phone No.Rusty Netz Stack Designation:Unit No. 1 Project No.:0 Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12 Test Date 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 Start Time 8:23 8:58 9:48 10:23 10:57 11:31 12:15 12:50 13:24 14:00 Stop Time 8:44 9:19 10:09 10:44 11:18 11:52 12:36 13:11 13:45 14:21 Run Time 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 Stack I.D. (inches)101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 As ft^2 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 Cp (Pitot Tube Coefficient)0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 Yd Meter Y Factor (unit less)1.0090 1.0090 1.0090 1.0090 1.0090 1.0090 1.0090 1.0090 1.0090 1.0090 1.0090 1.0090 Pbar Barometric Pressure ("Hg)23.90 23.90 23.90 23.90 23.90 23.90 23.90 23.90 23.90 23.90 23.90 23.90 Pq (Static Pressure)-0.10 -0.10 -0.10 -0.10 -0.10 -0.10 -0.10 -0.10 -0.10 -0.10 -0.10 -0.10 Ps (Pressure of the Stack)23.89 23.89 23.89 23.89 23.89 23.89 23.89 23.89 23.89 23.89 23.89 23.89 Ts Stack Temp Avg. oF 302.70 303.80 305.10 305.30 305.50 306.00 306.30 306.50 305.00 304.80 Tm Meter Temperature oF 66.00 66.00 68.00 68.00 75.00 75.00 78.00 78.00 77.00 77.00 CO2 (carbon dioxide)13.86 13.97 14.07 13.99 13.89 14.14 14.04 14.02 14.05 14.18 O2 (oxygen)5.69 5.69 5.72 5.72 5.39 5.49 5.52 5.52 5.49 5.39 Md Molecular Weight Dry 30.44 30.46 30.48 30.47 30.44 30.48 30.47 30.46 30.47 30.48 #VALUE!#VALUE! Ms Molecular Weight Wet 29.18 29.20 29.20 29.19 29.14 29.17 29.25 29.25 29.16 29.17 #VALUE!#VALUE! N2 (nitrogen)80.45 80.34 80.21 80.29 80.73 80.37 80.44 80.47 80.47 80.44 #VALUE!#VALUE! Vm Sample Volume (cf)43.96 43.96 44.14 44.14 44.66 44.66 45.36 45.36 44.31 44.31 0.00 0.00 Vm std Standard Volume (dscf)35.55 35.55 35.56 35.56 35.51 35.51 35.86 35.86 35.10 35.10 Vlc Moisture (g)85.10 85.10 86.10 86.10 88.10 88.10 82.30 82.30 87.40 87.40 Vwstd Moisture Volume (scf)4.01 4.01 4.05 4.05 4.15 4.15 3.87 3.87 4.11 4.11 Bws Moisture Content (%100)10.13%10.13%10.23%10.23%10.46%10.46%9.75%9.75%10.49%10.49% S Bws (saturation moisture)99.90%99.90%99.90%99.90%99.90%99.90%99.90%99.90%99.90%99.90% AvgSqrtDlp √∆P 1.242 1.252 1.251 1.235 1.236 1.245 1.238 1.256 1.256 1.252 Vs. Gas Velocity (ft./sec)93.26 94.09 94.09 92.87 93.05 93.75 93.12 94.44 94.51 94.21 Qa (stack actual flow rate) acfm 311,328 314,099 314,099 310,026 310,627 312,964 310,861 315,267 315,501 314,499 Qs (stack std. flow rate) dscfm 154,680 155,832 155,388 153,333 153,201 154,253 154,369 156,516 155,650 155,196 #VALUE!#VALUE! Qsd (stack std. flow rate) dscfh 9,280,829 9,349,942 9,323,257 9,199,964 9,192,080 9,255,185 9,262,112 9,390,953 9,338,992 9,311,782 Qw (stack flow rate) wscfm 10,326,503 10,403,403 10,385,727 10,248,383 10,265,564 10,336,039 10,262,561 10,405,320 10,433,450 10,403,052 Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Test Overview NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Point Source Unit No. 1 Contact Phone No.Rusty Netz Stack Designation:Unit No. 1 Project No.:0 Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12 Test Date 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 5/16/2023 Heat Input - BTU/hr. F factor - scf/MMBtu 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 Fuel Analysis - ft3/min 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 Fuel Flow - ft3/min 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Heat Input - BTU/hr.0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SO2 Concentrations Uncorrected 83.20 85.70 84.70 87.30 91.20 86.70 88.30 84.00 94.10 95.10 Dry Corrected 88.16 91.85 90.63 92.99 96.96 92.35 93.79 88.88 99.69 100.78 Wet Corrected NOx Concentrations Uncorrected 108.40 109.90 110.30 110.00 111.80 111.90 110.60 110.10 108.40 106.90 Dry Corrected 108.65 109.59 109.65 109.01 110.89 111.11 109.76 109.20 107.79 106.40 Wet Corrected CO Concentrations Uncorrected 24.10 23.80 23.20 24.10 23.80 24.80 20.40 23.80 23.80 24.60 Dry Corrected 24.05 23.89 23.23 24.22 23.97 25.00 20.49 23.84 24.04 25.00 Wet Corrected CO2 Concentrations Uncorrected 13.70 13.70 13.90 13.80 13.70 14.00 13.90 13.80 13.70 13.80 Dry Corrected 13.86 13.97 14.07 13.99 13.89 14.14 14.04 14.02 14.05 14.18 Wet Corrected O2 Concentrations Uncorrected 5.60 5.60 5.60 5.60 5.30 5.40 5.40 5.40 5.40 5.30 Dry Corrected 5.69 5.69 5.72 5.72 5.39 5.49 5.52 5.52 5.49 5.39 Wet Corrected Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 Average Emission Dry SO2 NOX CO lbs./MMBtu 0.200 0.167 0.022 Average % concentration lbs./hr.144.52 CO2 O2 ppm or % 93.61 109.21 23.77 14.02 5.56 Run 1 Enter O2 or CO2 Dry SO2 NOX CO CO2 O2 CO2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.90E-01 1.69E-01 2.27E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.465E-05 1.298E-05 1.748E-06 lbs./hr.135.98 120.44 16.23 13.86 5.69 ppm or %88.16 108.65 24.05 13.70 5.60 Run 2 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.97E-01 1.69E-01 2.24E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.526E-05 1.309E-05 1.737E-06 lbs./hr.142.72 122.39 16.24 13.97 5.69 ppm or %91.85 109.59 23.89 13.70 5.60 Raw Value Run 3 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.93E-01 1.68E-01 2.16E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.506E-05 1.310E-05 1.689E-06 lbs./hr.140.42 122.11 15.75 14.07 5.72 ppm or %90.63 109.65 23.23 13.90 5.60 Raw Value Run 4 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.99E-01 1.68E-01 2.27E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.545E-05 1.302E-05 1.761E-06 lbs./hr.142.17 119.79 16.20 13.99 5.72 ppm or %92.99 109.01 24.22 13.80 5.60 Raw Value Run 5 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)2.09E-01 1.72E-01 2.26E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.611E-05 1.325E-05 1.743E-06 lbs./hr.148.12 121.7582 16.02 13.89 5.39 ppm or %96.96 110.89 23.97 13.70 5.30 Raw Value Corrected For Cal. Drift Raw Value Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift O2 CO2 Clear lbs./MMBTU Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 O2 CO2 Clear lbs./MMBTU Run 6 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.95E-01 1.69E-01 2.31E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.535E-05 1.327E-05 1.818E-06 lbs./hr.142.04 122.8362 16.82 14.14 5.49 ppm or %92.35 111.11 25.00 14.00 5.40 Raw Value Run 7 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)2.00E-01 1.68E-01 1.91E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.559E-05 1.311E-05 1.489E-06 lbs./hr.144.37 121.43 13.80 14.04 5.52 ppm or %93.79 109.76 20.49 13.90 5.40 Raw Value Run 8 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.90E-01 1.68E-01 2.23E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.477E-05 1.304E-05 1.733E-06 lbs./hr.138.72 122.49 16.28 14.02 5.52 ppm or %88.88 109.20 23.84 13.80 5.40 Raw Value Run 9 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)2.12E-01 1.65E-01 2.24E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.657E-05 1.287E-05 1.748E-06 lbs./hr.154.73 120.24 16.32 14.05 5.49 ppm or %99.69 107.79 24.04 13.70 5.40 Raw Value Run 10 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)2.13E-01 1.61E-01 2.31E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.675E-05 1.271E-05 1.818E-06 lbs./hr.155.95 118.35 16.92 14.18 5.39 ppm or %100.78 106.40 25.00 13.80 5.30 Raw Value Run 11 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Sunnyside Cogen RATA RM 1, 2, 3A, 6C, 7E, 10, & 19 (Tested 5-16-2023) Calibration Error Test Test Date May 16, 2023 O2 CS - Cal. Span 19.56 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.00% Passed Cal. Mid-level 9.96 9.90 0.06 0.31% Passed Cal. High-level 19.56 19.50 0.06 0.31% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of CS - Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.92% 100% of Cal. Span High-level 100.00% Test Date May 16, 2023 CO2 CS - Cal. Span 26.85 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.000% Passed Cal. Mid-level 11.68 11.70 0.02 0.074% Passed Cal. High-level 26.85 26.90 0.05 0.186% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 43.50% 100% of Cal. Span High-level 100.00% Test Date May 16, 2023 SO2 CS - Cal. Span 240.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.10 0.10 0.042% Passed Cal. Mid-level 99.80 98.00 1.80 0.750% Passed Cal. High-level 240.00 238.30 1.70 0.708% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 41.58% 100% of Cal. Span High-level 100.00% Test Date May 16, 2023 NOx CS - Cal. Span 160.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.20 0.20 0.125% Passed Cal. Mid-level 74.50 75.40 0.90 0.563% Passed Cal. High-level 160.00 159.80 0.20 0.125% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 46.56% 100% of Cal. Span High-level 100.00% Test Date May 16, 2023 CO CS - Cal. Span 49.60 96.2 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.10 0.10 0.202% Passed Cal. Mid-level 25.10 25.80 0.70 1.411% Passed Cal. High-level 49.60 49.70 0.10 0.202% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.60% 100% of Cal. Span High-level 100.00%