DSHW-2024-005487

DRAFT FINAL
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South

March 2024
Environmental Remediation
Tooele Army Depot, Utah and Defense Depot Ogden, Utah
Contract No. W9124J-21-D-0006

U.S. Army Environmental Command Tooele Army Depot

DRAFT FINAL
Annual Groundwater Monitoring Report
Tooele Army Depot South
March 2024
Environmental Remediation
Tooele Army Depot, Utah and Defense Depot Ogden, Utah
Contract No. W9124J-21-D-0006
Prepared For:
U.S. Army Mission and Installation Contracting Command (MICC)
Fort Sam Houston (FSH), U.S. Army Environmental Command (USAEC), and Tooele Army Depot (TEAD)
Prepared By:
Brice Engineering, LLC
362 Pierpont Avenue
Salt Lake City, Utah 84101
801-948-9319 PH
www.BriceEng.com

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TABLE OF CONTENTS
ACRONYMS AND ABBREVIATIONS ...................................................................................................... III
1.0 INTRODUCTION ....................................................................................................................... 1
1.1 Report Organization ............................................................................................................ 1
1.2 Regulatory Framework ....................................................................................................... 1
1.3 LTM Site Descriptions ......................................................................................................... 2
1.3.1 SWMUs 1 and 25 .................................................................................................... 2
1.3.2 SWMU 13 ............................................................................................................... 4
1.3.3 SWMU 26 ............................................................................................................... 5
2.0 FIELD ACTIVITIES ...................................................................................................................... 7
2.1 Well Gauging, Inspection, and Groundwater Sampling ...................................................... 7
2.2 Sample Handling and Analysis ............................................................................................ 8
2.3 Waste Management ........................................................................................................... 8
3.0 SWMUS 1 AND 25 MONITORING RESULTS AND DISSCUSSION ................................................ 11
3.1 Groundwater Elevations ................................................................................................... 11
3.2 Analytical Results and Discussion ..................................................................................... 11
3.3 Concentration Trend Analysis ........................................................................................... 12
4.0 SWMU 13 MONITORING RESULTS AND DISSCUSSION ............................................................ 15
4.1 Groundwater Elevations ................................................................................................... 15
4.2 Analytical Results and Discussion ..................................................................................... 15
4.3 Concentration Trend Analysis ........................................................................................... 15
5.0 SWMU 26 MONITORING RESULTS AND DISSCUSSION ............................................................ 17
5.1 Groundwater Elevations ................................................................................................... 17
5.2 Analytical Results and Discussion ..................................................................................... 17
5.3 Concentration Trend Analysis ........................................................................................... 17
6.0 CONCLUSIONS AND RECOMMENDATIONS ............................................................................. 19
6.1 SWMUs 1 and 25 ............................................................................................................... 19
6.2 SWMU 13 .......................................................................................................................... 19
6.3 SWMU 26 .......................................................................................................................... 19
7.0 REFERENCES .......................................................................................................................... 21

TABLE OF CONTENTS (CONTINUED)
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Environmental Remediation Tooele Army Depot, Utah and Defense Depot Ogden, Utah
TABLES
Table 1 Summary of the LTM Program for SWMU 1
Table 2 Summary of the LTM Program for SWMU 25
Table 3 Summary of the LTM Program for SWMU 13
Table 4 Summary of the LTM Program for SWMU 26
Table 5 Summary of Groundwater Samples Collected
Table 6 SWMUs 1 and 25 Groundwater Elevation Data
Table 7 SWMUs 1 and 25 Groundwater Analytical Results
Table 8 SWMU 13 Groundwater Elevation Data
Table 9 SWMU 13 Groundwater Analytical Results
Table 10 SWMU 26 Groundwater Elevation Data
Table 11 SWMU 26 Groundwater Analytical Results
FIGURES
Figure 1 TEAD-S Overview Map
Figure 2 SWMUs 1 and 25 Potentiometric Surface Map
Figure 3 SWMUs 1 and 25 Groundwater Analyte Detections
Figure 4 SWMU 13 Potentiometric Surface Map
Figure 5 SWMU 13 Groundwater Analyte Detections
Figure 6 SWMU 26 Potentiometric Surface Map
Figure 7 SWMU 26 Groundwater Analyte Detections
APPENDICES
Appendix A SWMU 1 and 25, 13, and 26 Concentration Trend Plots
Appendix B Well Inspection Forms
Appendix C Field Sampling Forms
Appendix D Waste Documentation
Appendix E Quality Control Summary Report
Appendix F Laboratory Analytical Data Reports

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ACRONYMS AND ABBREVIATIONS
µg/L micrograms per liter
µg/L/yr micrograms per liter per year
amsl above mean sea level
AOC area of concern
bgs below ground surface
Brice Brice Engineering, LLC
CAMDS Chemical Agent Munitions Disposal System
CMI Corrective Measures Implementation
CMS Corrective Measures Study
COPC contaminant of potential concern
CTC carbon tetrachloride
DCA dichloroethane
DEHP bis(2-ethylhexyl)phthalate
DoD U.S. Department of Defense
EMAX EMAX Laboratories, Inc.
EPA U.S. Environmental Protection Agency
FSH Fort Sam Houston
ft/ft feet per foot
g/cm3 grams per cubic centimeter
IDF Individual Disposal Feature
LCS laboratory control sample
LNAPL light non-aqueous phase liquid
LTM long-term monitoring
MCL Maximum Contaminant Level
mg/L milligrams per liter
MICC U.S. Army Mission and Installation Contracting Command
MS matrix spike
MSD matrix spike duplicate
PAL Project Action Limit
PCE tetrachloroethene
Plexus Plexus Scientific Corporation
QA quality assurance
QC quality control
QCSR Quality Control Summary Report
QSM Quality Systems Manual for Environmental Laboratories, Version 5.3
RCRA Resource Conservation and Recovery Act
RFI RCRA Facility Investigation
RSL Regional Screening Level
Rust Rust Environment and Infrastructure
ACRONYMS AND ABBREVIATIONS (CONTINUED)
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SVOC semi-volatile organic compound
SWMU Solid Waste Management Unit
Synectics Environmental Synectics, Inc.
TCE trichloroethene
TDS total dissolved solids
TEAD Tooele Army Depot
TEAD-S Tooele Army Depot South
TPH-DRO total petroleum hydrocarbons – diesel range organics
UAC Utah Administrative Code
UDEQ Utah Department of Environmental Quality
UFP-QAPP Uniform Federal Policy-Quality Assurance Project Plan
USAEC U.S. Army Environmental Command
VOC volatile organic compound

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1.0 INTRODUCTION
Tooele Army Depot South (TEAD-S) is located in Tooele County, Utah, approximately 35 miles southwest
of Salt Lake City (Figure 1). The facility, previously known as the Deseret Chemical Depot, encompasses
19,364 acres in the northern portion of Rush Valley. Brice Engineering, LLC (Brice) has been contracted
under U.S. Army Mission and Installation Contracting Command (MICC) Contract Number W9124J-21-D-
0006 to conduct periodic groundwater sampling and analysis at the Solid Waste Management Units
(SWMUs) with groundwater long-term monitoring (LTM) requirements. This report covers the activities
and results of the May 2023 annual monitoring event at these SWMUs. Monitoring was conducted in
accordance with the current Uniform Federal Policy – Quality Assurance Project Plan (UFP-QAPP) for
TEAD-S groundwater sites, which was finalized in October 2021 (Brice 2021) as well as the Groundwater
Management Plan, Revision 2 (Parsons 2019).
Designed and built in the early 1940s, TEAD-S has been used since that time for the storage, renovation,
and disposal of many types of chemical weapons and material. Operations related to the disposal of the
chemical weapons stockpile at TEAD-S began in 1996 and concluded in January 2012. The primary mission
of TEAD-S for the storage and demilitarization of chemical warfare agents has been completed, and
facilities at the installation related to demilitarization have been or are being closed. Historical activities
at TEAD-S have resulted in soil and groundwater impacts throughout the facility, which are managed
under multiple areas of concern (AOCs) and SWMUs.
Based on the results of the 2022 groundwater monitoring event, the groundwater at SWMU 2 met the
non-degradation requirements outlined in Utah Administrative Code (UAC) R315-101 and was removed
from the LTM program (Brice 2023). Currently, LTM for groundwater is required at four SWMUs (1, 13,
25, and 26).
1.1 Report Organization
Information on the regulatory framework and descriptions of LTM sites sampled during the 2023 annual
monitoring event are discussed in the remainder of Section 1. Section 2 discusses the field activities that
were completed at the LTM sites in 2023. Sections 3, 4, and 5 discuss the monitoring results for SWMUs 1
and 25, 13, and 26, respectively. Section 6 summarizes the future monitoring program, and Section 7 lists
references cited in the report.
1.2 Regulatory Framework
TEAD-S operates under a Resource Conservation and Recovery Act (RCRA) Part B Hazardous Waste
Storage Permit (U.S. Environmental Protection Agency [EPA] ID UT5210090002; Utah Department of
Environmental Quality [UDEQ] 1993) originally issued by the Executive Secretary of the Utah Solid and
Hazardous Waste Control Board in 1993 and renewed in 2004 and 2015. This permit requires TEAD-S to
perform corrective action investigations for all SWMUs and other corrective action sites identified in the
permit. As outlined in Module V of the permit, RCRA corrective action is composed of three distinct
phases: RCRA Facility Investigation (RFI), Corrective Measures Study (CMS), and Corrective Measures
Implementation (CMI). Upon successful completion of CMI, sites may be granted site closure with LTM
requirements. TEAD-S has several SWMUs and AOCs currently in the RFI, CMS, and CMI steps of the RCRA
corrective action process, as described in Appendices A and B of Module V of the permit. Module VI of
the permit discusses post-closure care requirements.

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At present, the four SWMUs with groundwater LTM requirements are in the following stages:
• SWMU 1 – in CMI with LTM for groundwater
• SWMU 13 – site closed with LTM for groundwater
• SWMU 25 – in CMI with LTM for groundwater
• SWMU 26 – site closed with LTM for groundwater
The site backgrounds and LTM requirements for SWMUs 1, 13, 25, and 26 are presented in Section 1.3.
Project Action Limits (PALs) have been established for each LTM SWMU; however, the PALs are not
uniform across TEAD-S because the background groundwater quality varies significantly across the
installation, ranging from Class IA pristine groundwater (total dissolved solids [TDS] less than
500 milligrams per liter [mg/L]) to Class IV saline groundwater (TDS greater than 10,000 mg/L). At a
minimum, all groundwater is subject to non-degradation requirements. The State of Utah Risk-Based
Closure Standards (UAC R315-101) require resource protection and prohibit any further degradation of
groundwater quality from existing conditions or from background. The non-degradation requirement is
considered by UDEQ to be applicable to Army remedial activities associated with groundwater under the
corrective action permit for TEAD-S, and therefore is applicable to all TEAD-S LTM SWMUs. SWMUs with
higher background water quality are subject to more stringent standards. Based on background
groundwater quality, two categories of PALs for the LTM SWMUs have been established:
• For SWMUs with Class I or II groundwater, the PALs are the most stringent of either the EPA
tapwater Regional Screening Levels (RSLs) (based on a cancer risk of 1E-06 or a target hazard
quotient of 1.0) or the EPA Maximum Contaminant Levels (MCLs). SWMU 26 is included in
this category.
• For SWMUs with Class III or IV groundwater, the PALs are EPA MCLs; however, if an MCL does
not exist for a compound, the PAL is the EPA tapwater RSL (based on a cancer risk of 1E-06 or a
target hazard quotient of 1.0). SWMUs 1 and 25 are included in this category.
Although SWMU 13 has Class III or IV groundwater, the more conservative Class I and II PALs have
historically been used for SWMU 13. For consistency with historical practices, the more conservative
values have been applied to SWMU13 in this report and the UFP-QAPP (Brice 2021). The appropriate PALs
for each SWMU are listed in analytical results tables.
1.3 LTM Site Descriptions
Site histories and the LTM requirements for each of the SWMUs sampled during 2023 are discussed in the
following sections. Boundaries for SWMUs with and without LTM requirements are shown on Figure 1.
1.3.1 SWMUs 1 and 25
SWMUs 1 and 25 are adjacent SWMUs in the southern portion of TEAD-S (Figure 2). Due to their proximity
and similar characteristics, they are discussed jointly throughout this report. SWMU 1 occupies
approximately 373 acres along the southeastern boundary of the TEAD-S facility, while SWMU 25 occupies
approximately 1,293 acres to the west of SWMU 1. The two SWMUs are separated by a thin “buffer zone”
area. SWMU 1, known as the Eastern Demilitarization Area/Disposal Pit Site, was used from the 1940s to
the 1970s for the destruction and disposal of conventional and chemical munitions. Disposal pits were
created in support of these activities, and SWMU 1 contains numerous remnant disposal pits as a result.
At SWMU 25, a variety of demilitarization and disposal activities were conducted from 1945 to 1978. The
western portion of the SWMU 25 includes numerous clusters of explosion craters, with each cluster

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encompassing approximately 3 to 4 acres. To the east, SWMU 25 has numerous burning and disposal
trenches where scrap metal from incendiary cluster bombs was burned. Finally, the north-central portion
of SWMU 25 formerly contained scrap munitions placed in shallow trenches in two windrows. The
windrows once contained ash and incendiary waste from past open burning activities; however, the waste
piles and ash were removed during a surface stabilization project conducted from 2012 to 2015
(CB&I 2016).
As a result of the historical activities, elevated concentrations of volatile organic compounds (VOCs) and
metals have been detected in soil and groundwater at multiple locations throughout SWMUs 1 and 25.
The most widely observed contaminants include carbon tetrachloride (CTC), chloroform, other
chlorinated solvents, and hexavalent chromium.
In total, five mappable groundwater plumes have been identified: the Mustard Mountain, Northern, and
Southern plumes at SWMU 1; and the Eastern and Western plumes at SWMU 25 (Figure 3). A Phase II RFI
Addendum was completed for SWMUs 1 and 25 between 2015 and 2017 that evaluated the nature and
extent of these plumes and the subsurface hydrogeologic environment (Parsons 2018a). The investigation
determined that the contaminant plumes pose no risk to potential receptors or deeper potable
groundwater resources; however, the plumes are spatially associated with former disposal pits containing
uncharacterized buried waste that will remain in place. Given this environment, LTM is required for
SWMUs 1 and 25 based on the requirements of the TEAD-S RCRA Part B permit and the principle of non-
degradation because the buried waste has the potential to degrade groundwater. Based on the results of
the Phase II RFI Addendum, an LTM program was developed for SWMUs 1 and 25 and presented in the
Groundwater Management Plan (Parsons 2019).The main components of the LTM program (e.g., specific
wells, specific plumes, and analyte lists) and future planned remedies and land use for SWMUs 1 and 25
were agreed upon during a series of project planning meetings held between the Army and UDEQ over
the course of the Phase II RFI Addendum fieldwork.
The main objectives of the LTM program for groundwater at SWMUs 1 and 25 were identified as follows:
• Characterize the extent to which contaminant source areas continue to release contaminants
into groundwater.
• Document the vertical migration of contaminants in groundwater toward deeper
hydrostratigraphic units.
• Document horizontal migration of contaminants to validate the conceptual model of vapor
diffusive transport, in compliance with the non-degradation provision of state and federal laws.
• Document the requirements of the principle of non-degradation (UAC R315-101-3).
• Document, if any, hexavalent chromium impacts to groundwater near Individual Disposal
Feature (IDF) 1-152.
To meet these objectives, the monitoring program at SWMUs 1 and 25 consists of sampling and gauging
at 20 wells and gauging only at an additional 19 wells. LTM locations and analytes are summarized in
Table 1 for SWMU 1 and Table 2 for SWMU 25. Monitoring locations for both SWMUs are shown on
Figures 2 and 3. All five mapped plumes at SWMUs 1 and 25 exhibit similar shapes and characteristics.
Due to these similarities, the Northern Plume in SWMU 1 is not designated for monitoring in the
Groundwater Management Plan (Parsons 2019) because monitoring at the remaining four plumes
provides sufficient information to identify potential changes that would impact the Northern plume. At
the four plumes that are monitored, one or more shallow source area wells are sampled to monitor source
conditions, one deep source area well is monitored to assess vertical migration, and one downgradient
well is monitored to assess lateral migration. Additional wells are monitored along the installation

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boundary to monitor possible off-site migration. The primary contaminants being monitored at SWMUs 1
and 25 are VOCs. As of 2023, DEHP will no longer be analyzed at SWMUs 1 and 25. The 2022 event included
one-time analysis of total and dissolved DEHP. Total DEHP was only detected in two wells, and
concentrations were below PALs. Dissolved DEHP was not detected at any locations. Based on these
results and the site-use history of SWMUs 1 and 25, DEHP is not considered a contaminant of concern for
the SWMUs and no additional monitoring of DEHP is recommended (Brice 2023).
As noted above, one of the objectives of LTM at SWMUs 1 and 25 is to document whether hexavalent
chromium impacts are present in groundwater near IDF 1-152. The LTM program for SWMU 1 includes
sampling of a proposed well downgradient of IDF 1-152 that has not yet been installed (Table 1).
Installation of this well will occur in conjunction with CMI phase at SWMU 1, which is planned for 2025.
When installed, the well will be sampled annually, and the results will be used to document hexavalent
chromium impacts near IDF 1-152.
The initial period of required LTM at SWMUs 1 and 25 is 5 years. After 5 years of monitoring, data will be
evaluated to determine if contaminant concentrations are increasing systematically in source area wells,
or if vertical or horizontal migration of contaminant plumes is indicated. Following the 2026 monitoring
event, a determination will be made as to whether the LTM program should be modified, left unchanged,
or terminated.
1.3.2 SWMU 13
SWMU 13 encompasses the Chemical Agent Munitions Disposal System (CAMDS) Facility, which began
operations in 1979 and was demolished in 2012. The demilitarization facility is contained within a 10-acre
fenced site and was constructed for the research and development of methods for demilitarizing lethal
chemical munitions (such as nerve, blister, and mustard agents) and the treatment of wastes from this
demilitarization process. Most materials and munitions tested and demilitarized at the CAMDS facility
were disposed of by incineration. Three aboveground diesel fuel oil tanks were located within the western
perimeter of CAMDS. In 1978, approximately 500 gallons of fuel leaked from these tanks to the ground
surface. Between 1980 and 1985, an underground diesel fuel leak also reportedly occurred in the vicinity
of the tanks. The line leak went undetected for an extended period, and it is estimated that up to
38,000 gallons of fuel may have leaked (Rust Environment and Infrastructure [Rust] 1997). SWMU 13 also
includes three unlined lagoons known as the Northwest Wastewater Lagoons that were installed in 1991
and received sanitary sewer discharge from the CAMDS facility. The lagoons were investigated during a
Phase II RFI for potential environmental impacts; however, significant impacts to soil or groundwater were
not observed (Rust 1997). Collectively, SWMU 13 now includes all releases to groundwater and the fuel
release to soil. Other waste management units in the area were addressed during CAMDS closure.
Surface topography at SWMU 13 and adjacent SWMU 30 slopes gently to the southwest with ground
surface elevations ranging from approximately 5,072 to 5,039 feet above mean sea level (amsl). SWMU
13 is near the valley center and within 15 feet of the elevation of Faust Creek. To the east of the site, the
ground abruptly rises about 25 feet. The area west and northwest of SWMU 13 flooded when Faust Creek
discharge was high because the stream is dammed by the railroad embankments meeting in the
northwest part of TEAD-S. It is possible that the historical flooding of Faust Creek could result in waste
mobilization.
To address groundwater impacts associated with the fuel tanks at SWMU 13, a light non-aqueous phase
liquid (LNAPL) recovery system with interceptor trenches was installed in 2017 during the CMI stage of
the project, and associated LTM requirements were also established at that time (Parsons 2018c).
However, only three 55-gallon drums (approximately 165 gallons) of product were recovered by the

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system during the 2018 reporting period (Plexus Scientific Corporation [Plexus] 2019). Due to the low
recovery rate, a request for an Alternative Remedy Strategy consisting of LTM and land use controls was
submitted by TEAD and granted by UDEQ in 2019 on the basis of Technical Impracticality (TEAD 2019;
UDEQ 2019).
The LTM program specified under the Alternative Remedy Strategy consists of annual groundwater
sampling and well gauging for a minimum of 5 years. This monitoring includes sampling and gauging at
four wells and gauging only at an additional 16 wells. LTM locations and analytes for SWMU 13 are
presented in Table 3 and shown on Figures 4 and 5. The wells are sampled for total petroleum
hydrocarbons – diesel range organics (TPH-DRO) and VOCs. If any of these four wells contain free product,
samples are not collected. The first round of monitoring was conducted in 2018, but LTM was not
conducted in 2019 or 2020 due to contracting issues and COVID-19 travel restrictions. In 2021, LTM
resumed and will continue through at least 2024. By the end of 2024, a more extensive sampling event is
required to update the plume map for SWMU 13 to support future decision making. During this event,
groundwater samples will be collected from eight additional wells. Following this event, an evaluation will
be made as to whether the LTM program should continue unchanged, be modified, or be terminated.
1.3.3 SWMU 26
SWMU 26 consists of a former landfill that operated from 1956 to 1994 and occupies approximately
44 acres in the northeastern portion of the TEAD-S facility. SWMU 26 is divided into Eastern and Western
areas that are separated by an access road. The Eastern Area covers approximately 30 total acres with
buried waste located under approximately 14 acres. The Western Area consists of approximately 11 total
acres and has buried waste within four separate areas that encompass approximately 2 acres. The
complete contents of the landfill are unknown; however, waste disposed at a section of the landfill in the
1990s was observed to include solid waste, paper, and building debris. Historical documents indicate
munitions materials were also disposed of in the landfill (Plexus 2020a).
In 2016, SWMU 26 underwent an RFI Addendum (Plexus 2017), and groundwater was investigated for
potential VOC and semi-volatile organic compound (SVOC) impacts. Unacceptable risks to groundwater
were identified in the Eastern Area, and 1,1,1-trichloroethane, 1,1-dichloroethane (DCA), and DEHP were
identified as contaminants of potential concern (COPCs) for the site. Following the supplemental RFI, a
CMS (Plexus 2018) was conducted, which recommended implementation of land use controls and
installation of an engineered geosynthetic clay liner cap over the landfill. Installation of the cap was
completed between July 2019 and June 2020 (Plexus 2020a, 2020b). A new downgradient monitoring
well, S-150-20, was also installed during the CMI stage as recommended by the supplemental RFI.
A mappable groundwater plume has not been identified at SWMU 26; however, an LTM program was
established due to the presence of COPCs to evaluate groundwater conditions downgradient of the buried
waste and determine the effectiveness of the landfill cover at preventing additional groundwater
degradation. The LTM program requires annual water level monitoring and groundwater sampling for a
minimum period of 5 years. This monitoring includes sampling and gauging at three wells and gauging
only at an additional eight wells. The wells are sampled for VOCs. LTM locations and analytes for SWMU 26
are presented in Table 4 and shown on Figures 6 and 7. The first round of LTM was completed during the
July 2021 sampling event, and monitoring will continue through 2025, at which time an evaluation will be
made as to whether the LTM program should continue unchanged, be modified, or be terminated.

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2.0 FIELD ACTIVITIES
2.1 Well Gauging, Inspection, and Groundwater Sampling
Field activities completed during the 2023 annual monitoring event at TEAD-S included well gauging,
inspection, and groundwater sampling at SWMUs 1, 13, 25, and 26. Activities were completed following
procedures specified in the Groundwater Management Plan (Parsons 2019) and the UFP-QAPP (Brice
2021). Wells designated for water level monitoring (Tables 1 through 4) were gauged between 1 and
2 May 2023. Water levels and well depths were measured to the nearest 0.01-foot using an electronic
water level indicator at SWMUs 1, 25, and 26 and an oil-water interface probe at SWMU 13. LNAPL was
not detected at any of the SWMU 13 monitoring wells. The water level indicator and oil-water interface
probe were decontaminated prior to use and between monitoring well locations. In conjunction with
gauging, monitoring wells were inspected to identify any issues requiring maintenance. Inspection
summaries are included in Appendix B.
Water level measurements collected from wells with high TDS require correction to be usable for
potentiometric surface development. TDS values at SWMUs 1, 13, and 25 are greater than 3,000 mg/L
(Class III or IV groundwater quality), and water levels in those SWMUs were adjusted to the freshwater
head equivalent to account for salinity using Equation 1 shown below and per the Groundwater
Management Plan (Parsons 2019).
Equation 1: ℎ𝑓𝑓=�ℎ𝜌𝜌𝜌𝜌𝑓𝑓�−�𝜌𝜌−𝜌𝜌𝑓𝑓𝜌𝜌𝑓𝑓𝑧𝑧�
Where: ℎ𝑓𝑓 = freshwater equivalent head (feet amsl) ℎ = measured groundwater elevation (feet amsl) 𝜌𝜌 = measured groundwater density (grams per cubic centimeter [g/cm3]) 𝜌𝜌𝑓𝑓 = density of freshwater (1 g/cm3)
z = well screen bottom (feet amsl)
The measured groundwater density was derived by adding the mass of TDS [in g/cm3] for each well to the
density value of freshwater (𝜌𝜌𝑓𝑓), assumed to be 1 g/cm3. TDS concentrations were taken from Table 2.8
of the Groundwater Management Plan (Parsons 2019). For wells without established TDS concentrations,
data from the nearest well with data were used.
Groundwater sampling was conducted between 3 and 17 May 2023 at all wells designated for sampling
in SWMUs 1, 13, 25, and 26 (Tables 1 through 4). All wells were sampled using low-flow sampling
techniques. SWMUs 1, 13, and 25 were sampled using a non-dedicated submersible pump and dedicated
tubing, while SWMU 26 was sampled using a non-dedicated bladder pump (due to greater well depths)
and dedicated tubing. The submersible and bladder pumps were decontaminated prior to use and
between well locations. Field parameters were monitored for stability during purging using a field water
quality meter that was calibrated daily prior to use. Monitored parameters included temperature, pH,
oxidation-reduction potential, conductivity, turbidity, and dissolved oxygen.

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A summary of sampling at each SWMU is as follows:
• SWMU 1 – Monitoring wells S-70-90, S-71-90, S-93-92, S-127-15, S-128-15, S-129-15, S-135-16,
S-136-16, S-137-16, and S-138-16 were sampled for VOCs (EPA Method 8260C)
• SWMU 25 – Monitoring wells S-67-90, S-68-90, S-95-92, S-97-92, S-120-08, S-121-08, S-139-17,
S-140-17, S-141-17, and S-142-17 were sampled for VOCs (EPA Method 8260C)
• SWMU 13 – Monitoring wells S-55-90, S-78-91, S-91-91, and S13-CAM-DW1 were sampled for
TPH-DRO (EPA Method 8015D) and VOCs (EPA Method 8260C)
• SWMU 26 – Monitoring wells S-38-90, S-40-90, and S-150-20 were sampled for VOCs
(EPA Method 8260C)
Quality control (QC) samples including field duplicates, equipment blanks, and trip blanks were also
collected during the groundwater monitoring event. A comprehensive summary of all wells sampled for
the event, the field sample IDs, and the date and time of sampling is presented in Table 5, and field
sampling sheets are included in Appendix C. A total of 27 primary groundwater samples, four field
duplicate groundwater samples, four trip blanks, and two equipment blanks were collected and analyzed
in support of project activities.
2.2 Sample Handling and Analysis
Samples were collected using laboratory-provided containers labeled with indelible ink. After collection,
sample containers were placed in a resealable plastic bag and stored in iced coolers. Trip blanks were
included in each cooler containing samples for volatile organic analysis. The coolers were sealed with
shipping tape and custody seals and transported to the project laboratory by overnight courier under
chain-of-custody procedures. The samples were maintained within the EPA SW-846 sample preservation
requirement of less than 6 degrees Celsius during handling, storage, and transport to the lab. Samples
were sent via air courier to EMAX Laboratories, Inc. (EMAX) in Torrance, CA for analysis. Copies of the
chain-of-custody and cooler receipt records for this event are included with the analytical data reports in
Appendix F.
Quality assurance (QA)/QC procedures implemented for this sampling event included collection of trip
blank, equipment blank, and field duplicate samples. Analytical laboratory QC is also required to meet
specific QA/QC requirements for sample receipt and hold time; matrix spike (MS)/matrix spike duplicate
(MSD) recovery; laboratory control samples (LCSs); method blanks; and relative percent differences,
surrogate recoveries, instrument calibration, and internal standards. All control requirements and limits
are documented in the TEAD-S UFP-QAPP (Brice 2021) and the U.S. Department of Defense (DoD) Quality
Systems Manual for Environmental Laboratories, Version 5.3 (QSM; DoD 2019a). Environmental Synectics,
Inc. (Synectics) performed a Stage 2B validation on all data and an EPA Stage 4 validation on 10 percent
of the data (DoD 2019b). Additionally, Synectics performed a senior review of the validation to confirm
compliance with the UFP-QAPP and the QSM. Based on the review of the laboratory data, the analytical
data are deemed acceptable and usable with any qualifications noted in the Quality Control Summary
Report (QCSR) included in Appendix E. The QCSR contains detailed data validation information for the
sampling event, and the Synectics data validation reports are included as attachments. The full laboratory
reports with chain-of custody documentation are provided in Appendix F.
2.3 Waste Management
Investigation derived waste generated during field activities consisted of purge and decontamination
water. Based on historical results, purge water from wells in the TEAD-S LTM program is typically

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classifiable as non-hazardous waste; however, hazardous contaminant concentrations are present locally.
Specifically, S-139-17 is known to have potentially hazardous concentrations of CTC. Purge water is
containerized in labeled 5-gallon buckets during sample collection to facilitate waste management, with
each bucket containing water from one to three wells. Water from wells with concentrations determined
to be hazardous is then transferred to a DOT-approved 55-gallon drum for off-site disposal. The buckets
and drums are stored within secondary containment in a secure warehouse at TEAD-S and inspected
weekly until all hazardous waste has been properly disposed.
During the 2023 annual event, the concentration of CTC from S-139-17 was determined to be hazardous
(RCRA waste code D022: Chloroform). On 2 August 2023, approximately 1.5 gallons of purge water from
S-139-17 was transported from TEAD-S by Clean Harbors Environmental Services, Inc. to the Clean Harbors
Aragonite incineration facility (manifest 018383012FLE) and disposed of as hazardous waste. All other
waste was disposed of as non-hazardous at the TEAD-S wastewater treatment plant on 3 July 2023 with
installation approval. Waste documentation, including the waste manifest form, disposal confirmation,
waste disposal recommendation letter, and approval of non-hazardous waste disposal at TEAD-S are
included in Appendix D.

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3.0 SWMUs 1 AND 25 MONITORING RESULTS AND DISSCUSSION
3.1 Groundwater Elevations
Groundwater elevations are highest on the western side of SWMU 25 and show a decrease toward the
eastern side of SWMU 1; however, flow directions and gradients are not uniform across the SWMUs,
which is consistent with the suspected stratigraphic isolation of water-bearing units in the area (Parsons
2018a). On the western side of SWMU 25, groundwater flow is toward the east-southeast with a
horizontal hydraulic gradient of approximately 0.0010 feet per foot (ft/ft) between S-P3-90 and S-95-92.
Groundwater on the northeastern side of SWMU 25 flows radially away from S-100-92 toward the south
and east; however, the flow direction on the southeastern side of SWMU 25 is ambiguous due to shallow
hydraulic gradients and an apparent groundwater mound near S-95-92. At SWMU 1, groundwater flow is
generally to the east-northeast with a horizontal hydraulic gradient of approximately 0.0037 ft/ft between
S-5-82 and S-128-15. The area surrounding S-128-15 appears to be a groundwater depression, although
data east of the well are limited. Overall, the groundwater flow directions during the 2023 monitoring
event were consistent with those observed during the Phase II RFI Addendum (Parsons 2018a) and the
2022 monitoring event (Brice 2023). Measured and calculated freshwater equivalent groundwater
elevations at SWMUs 1 and 25 for the 2023 annual monitoring event are presented in Table 6.
Potentiometric contours based on the calculated freshwater equivalent groundwater elevations from the
2023 event are shown on Figure 2.
Vertically, hydraulic gradients at both SWMU 1 and SWMU 25 were observed to be uniformly upward.
Within SWMU 1, the vertical hydraulic gradient was approximately 0.085 ft/ft at S-135-16/S-136-16 and
approximately 0.052 ft/ft at S-137-16/S-138-16. Within SWMU 25, the vertical hydraulic gradient was
approximately 0.0036 ft/ft at S-139-17/S-140-17 and approximately 0.034 ft/ft at S-120-08/S-142-17.
Vertical gradients were previously evaluated for three of these well pairs during the Phase II RFI
Addendum (Parsons 2018a). Gradients based on 2017 water level measurements at S-137-16/S-138-16,
S-135-16/S-136-16, and S-139-17/S-140-167 were both upward and similar magnitude to those during the
2023 annual event.
At present, it is unclear whether the vertical gradient at S-135-16/S-136-16 varies significantly over time,
or if the gradient calculated during the Phase II RFI Addendum is the result of an erroneous water level
measurement or a well development issue. In 2017, the depth to water measurement at S-136-16 was
10.43 feet lower than the 2023 measurement; however, the recorded measurements from S-135-16 were
similar between 2017 and 2023. It is possible the 2017 water level measurement at S-136-16 is erroneous
(misread by 10 feet) or water levels within the well had not equilibrated following installation of the well
in November 2016 due to low aquifer permeability or incomplete well development. Continued
monitoring will help demonstrate whether the vertical gradient at S-135-16/S-136-16 is stable or variable.
3.2 Analytical Results and Discussion
Compounds with PAL exceedances during the 2023 event include CTC (five wells), chloroform (two wells),
and tetrachloroethene (PCE) (one well). All exceedances occurred in known plume source areas. Results
for the six wells sampled along the base boundary south of SWMUs 1 and 25 were all non-detect,
indicating contamination is not migrating off-site. Analytical results for SWMUs 1 and 25 during the 2023
annual monitoring event are summarized in Table 7. Results for detected analytes are shown on Figure 3.

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At SWMU 1, the only PAL exceedances were on the eastern side of the SWMU within the Mustard
Mountain plume source area. Chloroform was detected in shallow source area well S-127-15 with a
concentration of 130 µg/L. Chloroform was not detected above the PAL in the other Mustard Mountain
source area wells S-135-16 (shallow) and S-136-16 (deep); however, CTC exceeded the PAL in both wells
with concentrations of 19.0 µg/L and 29.0 µg/L, respectively. When compared with 2022 results, the CTC
result from S-135-16 has increased and the CTC result from S-136-16 has decreased.
The deep source area well (S-136-16) having a higher CTC concentration than the shallow well (S-135-16)
is inconsistent with the grab groundwater samples and previous sampling conducted at the wells during
the SWMUs 1 and 25 Phase II RFI Addendum (Parsons 2018a). During that investigation, grab
(Hydropunch) samples collected from the location had CTC concentrations of 240 µg/L at 178 feet below
ground surface (bgs), 83 µg/L at 201 feet bgs, and 0.27 µg/L at 236 feet bgs. Groundwater in this area
occurs in thin, laterally discontinuous silty sand, poorly graded sand, sandy clay, and clayey sand layers
separated by clay; and the grab samples are thought to reflect in-situ concentrations in different layers.
S-135-16 is screened across the shallowest grab sample depth with a screen interval from 175.5 to 185.5
feet bgs while S-136-16 is screened just below the deepest grab sample depth with a screen interval from
236 to 246 feet bgs. When the wells were sampled in 2017, however, the CTC concentration in S-135-16
was 0.52 µg/L while the result from S-136-16 was non-detect. The low concentrations were attributed to
“flushing” during well development and sampling, which does not allow time for back-diffusion of
contaminants from low-conductivity intervals of the aquifer into the sandy layers. The CTC detections in
2023, which are similar to 2022, suggest back-diffusion is occurring to at least some extent between the
annual sampling events and corroborate the upward vertical gradient observed during 2022 and 2023.
The highest levels of contamination occurred on the eastern side of SWMU 25 in the Eastern plume. At
S-139-17, concentrations of CTC (29,000 micrograms per liter [µg/L]), chloroform ( 690 µg/L), and PCE
(24.0 µg/L) were greater than the PALs and were the highest of all analytes detected during the 2023
monitoring event. However, results from the other Eastern Plume wells indicate that significant vertical
or lateral contamination migration from the source area has not occurred. In S-140-17, which is a deep
source area well paired with S-139-17, CTC was the only detected analyte greater than the PAL with a
concentration of 18 µg/L. At S-141-17, which is located approximately 350 feet downgradient of S-139-
17, all compounds were non-detect. The concentration of CTC in shallow source area well S-120-08 was
also greater than the PAL with a result of 350 µg/L. This well is located within the Western Plume source
area; however, no other compounds greater than the PALs were detected in S-142-17, which is a deep
well paired with S-120-08, or S-121-08, which is located approximately 100 feet downgradient of S-120-
08.
The results from the 2023 sampling event suggest that lateral and downward contaminant migration from
the plume source areas is not occurring, which is consistent with the slow vapor diffusive transport
indicated by the conceptual site model.
3.3 Concentration Trend Analysis
A concentration trend analysis for SWMUs 1 and 25 cannot yet be conducted due to insufficient data.
Some wells in the LTM program for the SWMUs have been sampled at irregular intervals dating back to
at least the late 1990s; however, recent data are sparse. Prior to the current sampling event, the SWMUs
were most recently sampled during the Phase II RFI Addendum in 2017.
For the trend analysis, only data from the Phase II RFI Addendum onward will be used. Many of the wells
in the LTM program were installed between 2015 and 2017, and many older historical results do not meet
current data requirements (e.g., method detection limits exceed PALs). Therefore, the year 2015 has been

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selected as a cutoff for the data used for trend analysis. Trend analysis for SWMUs 1 and 25 will be
completed after the LTM wells have been sampled five times since 2015. Results from the assessment will
be used to characterize the extent to which contaminant source areas continue to release contaminants
into groundwater and to document whether non-degradation requirements are being achieved. Although
concentration trend analysis is not yet possible, plots showing chloroform and CTC concentrations over
time for select wells are presented in Appendix A.

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4.0 SWMU 13 MONITORING RESULTS AND DISSCUSSION
4.1 Groundwater Elevations
Groundwater elevations in 2023 were observed to be lower than the 2022 elevations, in the majority of
wells but a clear trend throughout all wells was not observed. The direction of groundwater flow in the
northern and eastern portions of SWMU 13 was toward the west-southwest, while flow in the
southwestern portion of SWMU 13 is less uniform in direction but is generally toward the south and
southeast. The horizontal hydraulic gradient in the northern and eastern portions of SWMU 13 is steeper
than in the southwest, with a value of approximately 0.0113 ft/ft between S-55-90 and S-29-88 in 2023,
while the hydraulic gradient in the southwest was approximately 0.0011 ft/ft between S-84-91 and S-91-
91. The latter gradient is comparable to the 2022 observations, but the gradient between 2-55-90 and S-
29-88 almost doubled in 2023. This change is explained by a 2.61 foot increase in groundwater elevation
in well S-55-90 between 2022 and 2023. LNAPL was not detected in any wells during the event.
Additionally, during the 2023 event, monitoring wells S-86-91 and S-87-91 were dry. Measured and
calculated freshwater equivalent groundwater elevations at SWMU 13 for the 2023 annual monitoring
event are presented in Table 8. Potentiometric contours based on the 2023 freshwater equivalent
groundwater elevations are shown on Figure 4.
4.2 Analytical Results and Discussion
Only TCE concentrations exceeded PALs during the 2023 event. TCE exceeded the PAL (0.49 µg/L) in well
S-78-91 with a concentration of 0.50 J µg/L, which is a decrease from the 2022 concentration of 1.1 µg/L.
The concentration of Chloroform in S-55-90 was non-detect at 1.0 U µg/L, which is greater than the PAL
(0.22 µg/L) due to a detection of chloroform in the associated equipment blank. Additionally, detections
of DCA were observed below the PAL of 2.8 µg/L in two wells, S-91-91 and S13-CAM-DW1, at
concentrations of 0.18 J µg/L and 0.12 J µg/L, respectively. Analytical results for SWMU 13 during the 2023
annual monitoring event are summarized in Table 9. Results for detected analytes are shown on Figure 5.
Results from the 2023 monitoring event suggest impacts to groundwater at SMWU 13 are minor.
Insufficient data are available for a long-term trend assessment; however, the 2023 results are
comparable to the results from 2022. Continued annual monitoring will be performed to develop a more
thorough understanding of concentration trends at SWMU 13.
4.3 Concentration Trend Analysis
A concentration trend analysis for SWMU 13 cannot yet be conducted due to insufficient data. Some wells
in the LTM program for SWMU 13 have been sampled at irregular intervals dating back to at least the late
1990s; however, recent data at SWMU 13 are sparse. Prior to the current sampling event, SWMU 13 was
most recently sampled in 2017, though most wells in the LTM program were not sampled. The year 2014
has been selected as a cutoff for the data used for trend analysis because recent concentration trends are
more useful than historical trends for site management decisions, there was a gap in sampling prior to
2014, and many historical results do not meet current data requirements (e.g., method detection limits
exceed PALs). Trend analysis for SWMU 13 will be completed after the LTM wells have been sampled five
times since 2014. Although concentration trend analysis is not yet possible, plots showing chloroform and
TCE concentrations over time for select wells are presented in Appendix A.

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5.0 SWMU 26 MONITORING RESULTS AND DISSCUSSION
5.1 Groundwater Elevations
From 2022 to 2023, groundwater elevations at SWMU 26 decreased in all wells, with an average decrease
of 1.74 feet. This decrease is similar to the average decrease of 1.6 feet that was observed between the
2021 and 2022 events. SWMU 26 is located near Ophir Creek, which acts as a groundwater recharge area
and results in relatively low TDS concentrations at SWMU 26 compared to the other LTM SWMUs. The
lower groundwater elevations in 2023 may reflect annual or seasonal differences in streamflow and
recharge at Ophir Creek. The TDS concentrations at SWMU 26 are sufficiently low that density correction
is not required. Measured groundwater elevations at SWMU 26 for the 2023 annual monitoring event are
presented in Table 10. Potentiometric contours based on the measured groundwater elevations are
shown on Figure 6.
The observed direction of groundwater flow within the SWMU 26 boundary is generally to the east-
southeast. Flow direction is less uniform east of the SWMU 26 boundary with a localized area of northerly
groundwater flow in the vicinity of S-150-20. The horizontal hydraulic gradient within the SWMU 26
boundary was approximately 0.0019 ft/ft between wells S-37-90 and S-40-90. The horizontal hydraulic
gradient was notably steeper in the easternmost portion of the SWMU 26 monitoring area, with a value
of approximately 0.018 ft/ft between wells S-122-08 and S-41-90. Although groundwater elevations have
decreased at SWMU 26, the hydraulic gradients and flow directions are comparable to 2022.
5.2 Analytical Results and Discussion
Two compounds, chloroform and bromodichloromethane, had concentrations greater than the PALs
during the 2023 event. Chloroform concentrations exceeded the PAL (0.22 µg/L) in S-38-90 (0.25 J µg/L),
S-40-90 (1.0 µg/L), and S-150-20 (0.54 J µg/L). The results were comparable to the values in 2022.
Groundwater analytical results for SWMU 26 during the 2023 annual monitoring event are summarized
in Table 11. Results for detected analytes are shown on Figure 7.
The analytical result for bromodichloromethane was greater than the PAL (0.13 µg/L) in S-150-20 with a
concentration of 0.22 J µg/L, which is comparable to the result from 2022 (0.19 J µg/L). During the 2016
RFI Addendum for SWMU 26, bromodichloromethane was detected in wells S-37-90 and S-39-90 at
concentrations of 0.39 µg/L and 0.32 µg/L, respectively (Plexus 2017). Other analytes detected included
DCA and 1,1-dichloroethene in S-40-90 and dibromochloromethane in S-150-20. The analytical results for
these compounds were less than the PALs.
5.3 Concentration Trend Analysis
A concentration trend analysis for SWMU 26 could not be conducted due to insufficient data. Some wells
in the LTM program for SWMU 26 have been sampled at irregular intervals dating back to at least the late
1990s; however, recent data at SWMU 26 are sparse. Prior to the current sampling event, SWMU 26 was
most recently sampled in 2016. The year 2015 has been selected as a cutoff for the data used for trend
analysis because recent concentration trends are more useful than historical trends for site management
decisions, there was a gap in sampling prior to 2015, and many historical results do not meet current data
requirements (e.g., method detection limits exceed PALs). Trend analysis for SWMU 26 will be completed
after the LTM wells have been sampled five times since 2015. Although concentration trend analysis is
not yet possible, plots showing chloroform and bromodichloromethane concentrations over time for
select wells are presented in Appendix A.

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6.0 CONCLUSIONS AND RECOMMENDATIONS
6.1 SWMUs 1 and 25
Three compounds (CTC, chloroform and PCE) exceeded the PALs during the 2023 event. LTM at SWMUs
1 and 25 was initiated in 2022 and will continue annually until at least five monitoring events have been
completed (i.e., 2026). Results from the 2023 monitoring event indicate that lateral migration is not
occurring at the SWMU 1 and 25 plumes, and contamination is not migrating beyond the installation
boundary. The results also indicate downward vertical migration of contaminants at SWMUs 1 and 25 is
generally minimal due to clay-rich lithology and upward vertical hydraulic gradients; however, CTC
concentrations in the Mustard Mountain plume source area were higher in the deep monitoring well than
the shallow monitoring well, which was unexpected based on historical sample results from the Phase II
RFI Addendum (Parsons 2018a). The monitoring wells may be out of equilibrium with the aquifer or there
are additional sand intervals present that were not sampled in 2016 (Parsons 2018a). Continued
monitoring will help assess whether downward contaminant migration is occurring at the Mustard
Mountain plume and will also demonstrate if groundwater quality in the plume source areas is continuing
to degrade.
6.2 SWMU 13
TCE was the only compound exceeding the PAL at SWMU 13 during the 2023 monitoring event. This year,
the detection limit for chloroform was greater than the PAL, so despite a non-detect result, it cannot be
concluded whether it is above or below the PAL. Insufficient data are available for long-term trend
assessment; however, the 2023 results are comparable to the results from 2022. A more thorough
understanding of concentration trends at SWMU 13 will be developed as additional data are collected.
Annual monitoring at SWMU 13 will continue through at least 2024. Monitoring locations and analytes
for the next sampling event will follow the LTM program outlined in the Alternative Remedy Strategy. In
2024, a more extensive sampling event is scheduled to occur to update the plume map for SWMU 13 and
to support future decision making. The need for continued monitoring will be evaluated following the
2024 sampling event.
During the 2023 event, monitoring wells S-86-91 and S-87-91 were dry; therefore, no elevation data was
collected. It is recommended that monitoring wells S-92-91, S-105-93, and S-106-93 be added to the LTM
program for SWMU 13 for annual groundwater elevation gauging. These wells are located to the
northwest of the SWMU 13 boundary and will provide additional constraint on groundwater flow
directions in the northern portion of SWMU 13. It is also recommended that these wells are added to the
forthcoming revision to the Groundwater Management Plan.
6.3 SWMU 26
Two compounds, chloroform and bromodichloromethane, exceeded the PALs during the 2023 event.
Chloroform concentrations were greater than the PAL in the three wells sampled and had analytical
results comparable to 2022. The concentration of bromodichloromethane was greater than the PAL in
monitoring well S-150-20. Overall, the 2023 results are comparable to the 2022 results. Annual monitoring
at SWMU 26 will continue through at least 2025. Monitoring locations and analytes for the next sampling
event will remain unchanged from those presented in Table 4. The need for continued monitoring will be
evaluated following the 2025 sampling event.

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7.0 REFERENCES
Brice Engineering, LLC (Brice). 2021. Final Uniform Federal Policy – Quality Assurance Project Plan,
Tooele Army Depot South, Utah. October.
Brice Engineering, LLC (Brice). 2023. 2022 Annual Groundwater Monitoring Report Tooele Army Depot
South, Utah. January.
CB&I. 2016. Site‐Specific Final Report for Surface Stabilization at Tooele Army Depot‐South, SWMU 1
& 25. February.
Gilbert, Richard O. 1987. Statistical Methods for Environmental Pollution Monitoring. Van Nostrand
Reinhold: New York, NY.
Helsel. D.R., and R.M. Hirsch. 2002. Statistical methods in water resources: U.S. Geological Survey
Techniques of Water‐Resources Investigations, book 4, chap. A3, 524 p.
Kemron. 2016. Site Specific Final Report, Interim Remedial Action, Solid Waste Management Unit
(SWMU) 2, Tooele Army Depot ‐ South Area, Stockton, Utah.
Parsons. 2016. Final Long‐Term Monitoring of SWMU 2, SWMU 5, HWMU 31 and Implementation of the
Hydrogeologic Assessment and Recommendations Report Work Plan. Tooele Army Depot-South,
Tooele County, Utah. February.
Parsons. 2018a. Phase II Addendum Resource Conservation Recovery Act (RCRA) Facility Investigation
Report for Solid Waste Management Unit (SWMU) 1 and SWMU 25, Tooele Army Depot South
Area (TEAD-S). September.
Parsons. 2018b. 2017 Long‐Term Monitoring of SWMU 2 and SWMU 5 Annual Report. February.
Parsons. 2018c. Corrective Measures Implementation Completion Report for Solid Waste Management
Unit 13, Tooele Army Depot – South, Tooele County, Utah. May.
Parsons. 2019. Final Groundwater Management Plan, Revision Two. Tooele Army Depot – South, Tooele
County, Utah. June.
Plexus Scientific Corporation (Plexus), 2017. RCRA Facility Investigation Addendum, Solid Waste
Management Unit 26, Tooele Army Depot – South, Utah. July.
Plexus. 2018. Corrective Measures Study Work Plan / Report / Statement of Basis, Solid Waste
Management Unit 26, Tooele Army Depot – South, Utah. March.
Plexus. 2019. Annual Operation, Maintenance, and Monitoring Report, Solid Waste Management Unit
13, Tooele Army Depot – South, Tooele, Utah. February.
Plexus. 2020a. Corrective Measures Implementation Completion Report, Solid Waste Management
Unit 26 West (Areas A through D), Tooele Army Depot – South, Tooele County, Utah. April.
Plexus. 2020b. Corrective Measures Implementation Completion Report, Solid Waste Management
Unit 26 Areas E‐J, Tooele Army Depot – South, Tooele County, Utah. July.
Rust Environment and Infrastructure (Rust). 1997. Tooele Army Depot‐South Area, Revised Final Phase II
RCRA Facility Investigation Report Known Releases SWMUs 13 and 17. April.

2023 Annual Groundwater Monitoring Report, Tooele Army Depot South 22
Environmental Remediation Tooele Army Depot, Utah and Defense Depot Ogden, Utah
Tooele Army Depot (TEAD). 2019. Request for an Alternative Remedy Strategy at Solid Waste
Management Unit 13, Tooele Army Depot South Area. June.
U.S. Department of Defense (DoD). 2019a. Quality Systems Manual for Environmental Laboratories,
Version 5.3. January.
DoD. 2019b. General Data Validation Guidelines, Revision 1. November.
U.S. Environmental Protection Agency (EPA). 2009. Statistical Analysis of Groundwater Monitoring Data
at RCRA Facilities. Unified Guidance, EPA 530/R-09-007, March 2009.
Utah Department of Environmental Quality (UDEQ). 1993. Deseret Chemical Depot RCRA Part B
Hazardous Waste Storage Permit. Reissued 2015.
UDEQ. 2019. Letter from Ty L. Howard/UDEQ to Nicholas Montgomery/TEAD RE: Request for Alternative
Remedy Strategy Solid Waste Management Unit (SWMU) 13, Tooele Army Depot South. EPA ID
UT52100900002. 13 August.

TABLES

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Table 1
Summary of the LTM Program for SWMU 1
2023 Annual Monitoring Event
MONITORING
POINT ID LOCATION MONITORING
TYPE/PURPOSE FREQUENCY1,2 ANALYTES AND METHODS3 COMMENTS
S-70-90 Buffer Zone Installation Perimeter Annually VOCs / 8260C
S-71-90 Buffer Zone Installation Perimeter Annually VOCs / 8260C
S-93-92 Buffer Zone Installation Perimeter Annually VOCs / 8260C
S-127-15 SWMU 1 - Mustard Mountain Plume Source Area Annually VOCs / 8260C
S-128-15 SWMU 1 - Mustard Mountain Plume Lateral Migration Annually VOCs / 8260C
S-129-15 SWMU 1 - Southern Plume Lateral Migration Annually VOCs / 8260C
S-135-16 SWMU 1 - Mustard Mountain Plume Source Area Annually VOCs / 8260C Shallow, Co-located with S‑136-16
S-136-16 SWMU 1 - Mustard Mountain Plume Vertical Migration Annually VOCs / 8260C Deep, Co-located with S‑135‑16
S-137-16 SWMU 1 - Southern Plume Source Area Annually VOCs / 8260C Shallow, Co-located with S‑138‑16
S-138-16 SWMU 1 - Southern Plume Vertical Migration Annually VOCs / 8260C Deep, Co-located with S‑137‑16
Proposed Well – ID to
be established SWMU 1 IDF-1-152 Annually VOCs / 8260C, Total and Hexavalent
Chromium / 7199
To be located immediately downgradient of
IDF 1-152
S-4-82 Buffer Zone Water Level Only Annually N/A
S-5-82 Buffer Zone Water Level Only Annually N/A
S-69-90 Buffer Zone Water Level Only Annually N/A
S-96-92 SWMU 1 Water Level Only Annually N/A
S-125-15 SWMU 1 Water Level Only Annually N/A
S-126-15 SWMU 1 Water Level Only Annually N/A
Water Level Monitoring Wells
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
1 Sampling and well gauging to be conducted in May when groundwater levels are typically high.
2 LTM will be conducted for a minimum of 5 years beginning in 2022 and continue through 2026. At the end of the 5-year period, a determination will also be made as to whether the LTM program should be
modified, left unchanged, or terminated.
Groundwater Sampling and Water Level Monitoring Wells
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Table 2
Summary of the LTM Program for SWMU 25
2023 Annual Monitoring Event
MONITORING
POINT ID LOCATION MONITORING TYPE/PURPOSE FREQUENCY1,2 ANALYTES AND METHODS3 COMMENTS
S-67-90 Buffer Zone Installation Perimeter Annually VOCs / 8260C
S-68-90 Buffer Zone Installation Perimeter Annually VOCs / 8260C
S-95-92 Buffer Zone Installation Perimeter Annually VOCs / 8260C
S-97-92 Buffer Zone Installation Perimeter Annually VOCs / 8260C
S-120-08 SWMU 25 - Western Plume Source Area Annually VOCs / 8260C Shallow, Co-located with S-142-17
S-121-08 SWMU 25 - Western Plume Lateral Migration Annually VOCs / 8260C
S-139-17 SWMU 25 - Eastern Plume Source Area Annually VOCs / 8260C Shallow, Co-located with S‑140‑17
S-140-17 SWMU 25 - Eastern Plume Vertical Migration Annually VOCs / 8260C Deep, Co-located with S-139-17
S-141-17 SWMU 25 - Eastern Plume Lateral Migration Annually VOCs / 8260C
S-142-17 SWMU 25 - Western Plume Vertical Migration Annually VOCs / 8260C Deep, Co-located with S-120-08
S-6-82 SWMU 25 Water Level Only Annually N/A
S-7-82 SWMU 25 Water Level Only Annually N/A
S-18-88 SWMU 25 Water Level Only Annually N/A
S-19-88 SWMU 25 Water Level Only Annually N/A
S-64-90 SWMU 25 Water Level Only Annually N/A
S-65-90 SWMU 25 Water Level Only Annually N/A
S-66-90 SWMU 25 Water Level Only Annually N/A
S-98-92 SWMU 25 Water Level Only Annually N/A
S-99-92 SWMU 25 Water Level Only Annually N/A
S-100-92 SWMU 25 Water Level Only Annually N/A
S-101-92 SWMU 25 Water Level Only Annually N/A
S-102-92 SWMU 25 Water Level Only Annually N/A
S-P3-90 SWMU 25 Water Level Only Annually N/A
Groundwater Sampling and Water Level Monitoring Wells
Water Level Monitoring Wells
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
1 Sampling and well gauging to be conducted in May when groundwater levels are typically high.
2 LTM will be conducted for a minimum of 5 years beginning in 2022 and continue through 2026. At the end of the 5-year period, a determination will also be made as to whether the LTM
program should be modified, left unchanged, or terminated.
3 One-time analysis of DEHP was completed during the 2022 monitoring event. The need for continued analysis of DEHP is discussed in Section 7.1.
Page 1 of 1

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Table 3
Summary of the LTM Program for SWMU 13
2023 Annual Monitoring Event
MONITORING
POINT ID MONITORING PURPOSE FREQUENCY1,2 ANALYTES AND
METHODS COMMENTS
VOCs / 8260C
TPH-DRO / 8015D
VOCs / 8260C
TPH-DRO / 8015D
VOCs / 8260C
TPH-DRO / 8015D
VOCs / 8260C
TPH-DRO / 8015D
S-1-82 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-25-88 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-26-88 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-29-88 Groundwater Flow Direction,
LNAPL presence/thickness Annually N/A Gauged concurrently with sampling
event
S-30-88 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-54-90 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-55-90 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-56-90 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-58-90 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-59-90 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-76-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-78-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-81-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-82-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-83-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-84-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-86-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
Groundwater Monitoring Wells
S-55-90 Lateral Plume Migration Monitoring Annually Not sampled if LNAPL is present
S-91-91 Lateral Plume Migration Monitoring Annually Not sampled if LNAPL is present
S-78-91 Lateral Plume Migration Monitoring Annually Not sampled if LNAPL is present
Water Level Monitoring Wells
S13-CAM-DW1 Vertical Plume Migration
Monitoring Annually Not sampled if LNAPL is present
Page 1 of 2
Table 3
Summary of the LTM Program for SWMU 13
2023 Annual Monitoring Event
MONITORING
POINT ID MONITORING PURPOSE FREQUENCY1,2 ANALYTES AND
METHODS COMMENTS
S-87-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S-91-91 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
S13-CAM-DW1 Groundwater Flow Direction,
LNAPL Presence/Thickness Annually N/A Gauged concurrently with sampling
event
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
1 Sampling and well gauging to be conducted in May when groundwater levels are typically high.
2 LTM will be conducted for a minimum of 5 years. The first round of monitoring was conducted in 2018, but LTM was not conducted in
2019 or 2020. LTM resumed in 2021 and continue through 2024. A one-time sampling event including additional wells will be
completed in 2024 in conjunction with the fifth LTM event. Following the fifth LTM event, a determination will be made as to whether
the LTM program should be modified, left unchanged, or terminated.
Page 2 of 2
Table 4
Summary of the LTM Program for SWMU 26
2023 Annual Monitoring Event
MONITORING
POINT ID MONITORING PURPOSE FREQUENCY1,2 ANALYTES
AND METHODS COMMENTS
S-38-90 Source Area/Downgradient Monitoring Annually VOCs / 8260C N/A
S-40-90 Source Area/Downgradient Monitoring Annually VOCs / 8260C N/A
S-150-20 Downgradient Monitoring Annually VOCs / 8260C N/A
S-35-90 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-37-90 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-38-90 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-39-90 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-40-90 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-41-90 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-118-08 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-122-08 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-124-13 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
S-150-20 Groundwater Flow Direction Annually N/A Gauged concurrently with
sampling event
Groundwater Sampling
Water Level Monitoring Wells
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
1 Groundwater sampling and well gauging to be conducted in May when groundwater levels are typically high.
2 LTM will be conducted for a minimum of 5 years beginning in 2021 and continue through 2025. At the end of the 5-year period, a
determination will also be made as to whether the LTM program should be modified, left unchanged, or terminated.
Page 1 of 1

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Table 5
Summary of Groundwater Samples Collected
2023 Annual Monitoring Event
WELL ID FIELD SAMPLE ID SAMPLING DATE AND TIME
S-70-90 S-70-90-052023 05/04/2023 11:10
S-71-90 S-71-90-052023 05/04/2023 13:05
S-93-92 S-93-92-052023 05/05/2023 10:05
S-127-15 S-127-15-052023 05/10/2023 14:25
S-128-15 S-128-15-052023 05/09/2023 14:20
S-129-15 S-129-15-052023 05/05/2023 13:05
S-135-16-052023 05/10/2023 13:05
S-135-16-052023D (Field Duplicate)05/10/2023 13:10
S-136-16 S-136-16-052023 05/11/2023 12:40
S-137-16 S-137-16-052023 05/08/2023 13:50
S-138-16 S-138-16-052023 05/08/2023 16:20
S-67-90 S-67-90-052023 05/03/2023 12:05
S-68-90 S-68-90-052023 05/04/2023 10:15
S-95-92 S-95-92-052023 05/03/2023 14:20
S-97-92 S-97-92-052023 05/05/2023 11:37
S-120-08 S-120-08-052023 05/12/2023 10:05
S-121-08 S-121-08-052023 05/09/2023 12:40
S-139-17-052023 05/12/2023 11:40
S-139-17-052023D (Field Duplicate)05/12/2023 11:45
S-140-17 S-140-17-052023 05/11/2023 10:40
S-141-17 S-141-17-052023 05/08/2023 10:50
S-142-17 S-142-17-052023 05/09/2023 11:35
S-55-90 S-55-90-052023 05/16/2023 9:15
S-78-91 S-78-91-052023 05/16/2023 11:05
S-91-91-052023 05/15/2023 13:30
S-91-91-052023D (Field Duplicate)05/15/2023 13:30
S13-CAM-DW1 S13-CAM-DW1-052023 05/15/2023 11:35
S-38-90 S-38-90-052023 05/17/2023 10:05
S-40-90-052023 05/17/2023 11:50
S-40-90-052023D (Field Duplicate)05/17/2023 11:55
S-150-20 S-150-20-052023 05/17/2023 11:05
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
SWMU 1
S-135-16
S-139-17
S-40-90
S-91-91
SWMU 25
SWMU 13
SWMU 26
Page 1 of 1

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Table 6
SWMUs 1 and 25 Groundwater Elevation Data
2023 Annual Monitoring Event
LOCATION SWMU
DATE
MEASURED
MEASURING
POINT
ELEVATION
(feet amsl)
MEASURED DEPTH
TO WATER
(feet below
measuring point)
MEASURED TOTAL
WELL DEPTH
(feet below
measuring point)
MEASURED
GROUNDWATER
ELEVATION
(feet amsl)
CORRECTED
GROUNDWATER
ELEVATION
(feet amsl)
WELL USED FOR
TDS CORRECTION
S-4-82 Buffer 05/02/2023 5070.34 57.44 86.52 5012.90 5013.15 S-71-90
S-5-82 Buffer 05/02/2023 5054.22 37.93 58.80 5016.29 5016.45 S-5-82
S-6-82 25 05/02/2023 5043.08 21.29 37.36 5021.79 5021.85 S-22-88
S-7-82 25 05/02/2023 5052.19 33.60 54.21 5018.59 5019.17 S-64-90
S-18-88 25 05/02/2023 5041.43 23.03 39.14 5018.40 5018.58 S-68-90
S-19-88 25 05/02/2023 5063.53 38.98 39.38 5024.55 5024.55 S-22-88
S-64-90 25 05/02/2023 5048.73 26.45 37.40 5022.28 5022.59 S-64-90
S-65-90 25 05/02/2023 5041.47 21.06 28.82 5020.41 5020.63 S-64-90
S-66-90 25 05/02/2023 5062.14 40.84 96.82 5021.30 5022.03 S-101-92
S-67-90 Buffer 05/02/2023 5042.13 22.53 38.44 5019.60 5019.95 S-67-90
S-68-90 Buffer 05/02/2023 5062.44 44.32 64.40 5018.12 5018.34 S-68-90
S-69-90 Buffer 05/02/2023 5107.71 100.07 125.54 5007.64 5007.75 S-96-92
S-70-90 Buffer 05/02/2023 5064.19 47.67 52.22 5016.52 5016.56 S-70-90
S-71-90 Buffer 05/02/2023 5059.49 40.65 66.82 5018.84 5019.07 S-71-90
S-93-92 Buffer 05/02/2023 5076.45 66.12 153.87 5010.33 5010.73 S-93-92
S-95-92 Buffer 05/02/2023 5049.81 31.05 130.35 5018.76 5019.51 S-95-92
S-96-92 1 05/02/2023 5075.26 67.40 117.01 5007.86 5008.08 S-96-92
S-97-92 Buffer 05/02/2023 5090.30 73.19 85.34 5017.11 5017.26 S-97-92
S-98-92 25 05/02/2023 5052.65 29.97 41.61 5022.68 5023.01 S-64-90
S-99-92 25 05/02/2023 5052.72 34.34 40.90 5018.38 5018.48 S-99-92
S-100-92 25 05/02/2023 5080.67 56.95 76.89 5023.72 5024.00 S-102-92
S-101-92 25 05/02/2023 5063.10 44.54 52.78 5018.56 5018.67 S-101-92
S-102-92 25 05/02/2023 5057.55 38.95 46.31 5018.60 5018.70 S-102-92
S-120-08 25 05/02/2023 5053.47 35.33 68.79 5018.14 5018.81 S-120-08
S-121-08 25 05/02/2023 5053.89 35.92 55.39 5017.97 5018.36 S-121-08
S-125-15 1 05/02/2023 5080.67 63.94 72.05 5016.73 5016.83 S-97-92
S-126-15 1 05/02/2023 5075.71 58.88 66.84 5016.83 5016.93 S-97-92
S-127-15 1 05/02/2023 5083.54 76.78 117.51 5006.76 5006.94 S-127-15
S-128-15 1 05/02/2023 5075.82 69.79 107.55 5006.03 5006.21 S-128-15
S-129-15 1 05/02/2023 5064.40 52.18 108.25 5012.22 5012.51 S-129-15
S-135-16 1 05/02/2023 5131.92 123.35 187.72 5008.57 5008.84 S-135-16
S-136-16 1 05/02/2023 5131.94 118.27 249.40 5013.67 5014.22 S-136-16
S-137-16 1 05/02/2023 5067.75 57.73 128.34 5010.02 5010.40 S-137-16
S-138-16 1 05/02/2023 5067.79 54.56 197.70 5013.23 5014.00 S-138-16
S-139-17 25 05/02/2023 5072.39 54.99 62.38 5017.40 5017.43 S-139-17
S-140-17 25 05/02/2023 5072.38 55.00 200.33 5017.38 5017.95 S-140-17
S-141-17 25 05/02/2023 5078.86 61.52 77.70 5017.34 5017.47 S-141-17
S-142-17 25 05/02/2023 5053.62 33.40 212.40 5020.22 5023.80 S-142-17
S-P3-90 25 05/02/2023 5044.72 15.83 16.30 5028.89 5028.89 S-22-88
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
Page 1 of 1

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Table 7
SWMUs 1 and 25 Groundwater Analytical Results
2023 Annual Monitoring Event
S-67-90 S-68-90 S-70-90 S-71-90 S-93-92 S-95-92 S-97-92 S-120-08 S-121-08 S-127-15 S-128-15
S-67-90-052023 S-68-90-052023 S-70-90-052023 S-71-90-052023 S-93-92-052023 S-95-92-052023 S-97-92-052023
S-120-08-
052023
S-121-08-
052023
S-127-15-
052023
S-128-15-
052023
5/3/2023 5/4/2023 5/4/2023 5/4/2023 5/5/2023 5/3/2023 5/5/2023 5/12/2023 5/9/2023 5/10/2023 5/9/2023
25 25 1 1 1 25 25 25 25 1 1
VOCs PAL
(µg/L)PAL REFERENCE
1,1,1,2-Tetrachloroethane 0.57 EPA Tap Water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1,1-Trichloroethane 200 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1,2,2-Tetrachloroethane 0.076 EPA Tap Water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1,2-Trichloroethane 5 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1-Dichloroethane 2.8 EPA Tap Water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1-Dichloroethene 7 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1-Dichloropropene NS NS 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2,3-Trichlorobenzene 7 EPA Tap Water RSL 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
1,2,3-Trichloropropane 0.00075 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
1,2,4-Trichlorobenzene 70 EPA MCL 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
1,2-Dibromo-3-chloropropane 0.2 EPA MCL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
1,2-Dibromoethane (EDB) 0.05 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2-Dichlorobenzene 600 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2-Dichloroethane 5 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2-Dichloropropane 5 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,3-Dichlorobenzene NS NS 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,3-Dichloropropane 370 EPA Tap Water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,4-Dichlorobenzene 75 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,4-Dioxane NS NS 50.0 UJ 50.0 UJ 50.0 UJ 50.0 UJ 50.0 UJ 50.0 UJ 50.0 UJ 50.0 U 50.0 U 50.0 U 50.0 U
2,2-Dichloropropane NS NS 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
2-Butanone (MEK) 5,600 EPA Tap Water RSL 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
2-Chlorotoluene 240 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
2-Hexanone 38 EPA Tap Water RSL 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 U 10.0 U 10.0 U 10.0 U
4-Chlorotoluene 250 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
4-Methyl-2-pentanone (MIBK) NS NS 5.00 UJ 5.00 UJ 5.00 UJ 5.00 UJ 5.00 UJ 5.00 UJ 5.00 UJ 5.00 U 5.00 U 5.00 U 5.00 U
Acetone 14,000 EPA Tap Water RSL 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
Benzene 5 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.100 J
Bromobenzene 62 EPA Tap Water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Bromochloromethane 83 EPA Tap Water RSL 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Bromodichloromethane 80 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Bromoform 80 EPA MCL 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Bromomethane 7.5 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Carbon disulfide 810 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Carbon tetrachloride 5 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 350 3.00 0.200 U 0.200 U
Chlorobenzene 100 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Chloroethane 21,000 EPA Tap Water RSL 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 U
Chloroform 80 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 49.0 1.60 130 12.0
Chloromethane 190 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
cis-1,2-Dichloroethene 70 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
cis-1,3-Dichloropropene NS NS 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Cumene 450 EPA Tap Water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Dibromochloromethane 80 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Dibromomethane 8.3 EPA Tap water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Dichlorodifluoromethane 200 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Ethylbenzene 700 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
m,p-Xylene NS NS 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Methyl tert-butyl ether (MTBE)14 EPA Tap Water RSL 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Methylene chloride 5 EPA MCL 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 U 1.00 U 0.690 J 1.00 U
Location:
Sample ID:
Sampling Date:
SWMU:
Page 1 of 4
Table 7
SWMUs 1 and 25 Groundwater Analytical Results
2023 Annual Monitoring Event
S-67-90 S-68-90 S-70-90 S-71-90 S-93-92 S-95-92 S-97-92 S-120-08 S-121-08 S-127-15 S-128-15
S-67-90-052023 S-68-90-052023 S-70-90-052023 S-71-90-052023 S-93-92-052023 S-95-92-052023 S-97-92-052023
S-120-08-
052023
S-121-08-
052023
S-127-15-
052023
S-128-15-
052023
5/3/2023 5/4/2023 5/4/2023 5/4/2023 5/5/2023 5/3/2023 5/5/2023 5/12/2023 5/9/2023 5/10/2023 5/9/2023
25 25 1 1 1 25 25 25 25 1 1
VOCs PAL
(µg/L)PAL REFERENCE
Location:
Sample ID:
Sampling Date:
SWMU:
n-Butylbenzene 1,000 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
n-Propylbenzene 6,60 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
o-Xylene 190 EPA Tap Water RSL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
p-Cymene NS NS 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
sec-Butylbenzene 2,000 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Styrene 100 EPA MCL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U
tert-Butylbenzene 690 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Tetrachloroethene (PCE)5 EPA MCL 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.680 J 0.300 U 0.300 U 0.300 U
Toluene 1,000 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
trans-1,2-Dichloroethene 100 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
trans-1,3-Dichloropropene NS NS 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Trichloroethene (TCE)5 EPA MCL 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Trichlorofluoromethane 5,200 EPA Tap Water RSL 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Vinyl chloride 2 EPA MCL 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
Detected results appear in bold font.
Detections that exceed the PAL appear in red bold font.
J - The reported result is an estimated value.
J+ - The analyte is considered an estimated value with a possible high-bias due to a QC deviation.
J- - The analyte is considered an estimated value with a possible low-bias due to a QC deviation.
U - Not detected; the compound/analyte was analyzed for, but not detected above the limit of detection
unless otherwise noted.
UJ - The analyte was not detected; however, the result is estimated because of discrepancies in meeting
certain analyte-specific QC criteria.
Page 2 of 4
Table 7
SWMUs 1 and 25 Groundwater Analytical Results
2023 Annual Monitoring Event
VOCs PAL
(µg/L)PAL REFERENCE
1,1,1,2-Tetrachloroethane 0.57 EPA Tap Water RSL
1,1,1-Trichloroethane 200 EPA MCL
1,1,2,2-Tetrachloroethane 0.076 EPA Tap Water RSL
1,1,2-Trichloroethane 5 EPA MCL
1,1-Dichloroethane 2.8 EPA Tap Water RSL
1,1-Dichloroethene 7 EPA MCL
1,1-Dichloropropene NS NS
1,2,3-Trichlorobenzene 7 EPA Tap Water RSL
1,2,3-Trichloropropane 0.00075 EPA Tap Water RSL
1,2,4-Trichlorobenzene 70 EPA MCL
1,2-Dibromo-3-chloropropane 0.2 EPA MCL
1,2-Dibromoethane (EDB) 0.05 EPA MCL
1,2-Dichlorobenzene 600 EPA MCL
1,2-Dichloroethane 5 EPA MCL
1,2-Dichloropropane 5 EPA MCL
1,3-Dichlorobenzene NS NS
1,3-Dichloropropane 370 EPA Tap Water RSL
1,4-Dichlorobenzene 75 EPA MCL
1,4-Dioxane NS NS
2,2-Dichloropropane NS NS
2-Butanone (MEK) 5,600 EPA Tap Water RSL
2-Chlorotoluene 240 EPA Tap Water RSL
2-Hexanone 38 EPA Tap Water RSL
4-Chlorotoluene 250 EPA Tap Water RSL
4-Methyl-2-pentanone (MIBK) NS NS
Acetone 14,000 EPA Tap Water RSL
Benzene 5 EPA MCL
Bromobenzene 62 EPA Tap Water RSL
Bromochloromethane 83 EPA Tap Water RSL
Bromodichloromethane 80 EPA MCL
Bromoform 80 EPA MCL
Bromomethane 7.5 EPA Tap Water RSL
Carbon disulfide 810 EPA Tap Water RSL
Carbon tetrachloride 5 EPA MCL
Chlorobenzene 100 EPA MCL
Chloroethane 21,000 EPA Tap Water RSL
Chloroform 80 EPA MCL
Chloromethane 190 EPA Tap Water RSL
cis-1,2-Dichloroethene 70 EPA MCL
cis-1,3-Dichloropropene NS NS
Cumene 450 EPA Tap Water RSL
Dibromochloromethane 80 EPA MCL
Dibromomethane 8.3 EPA Tap water RSL
Dichlorodifluoromethane 200 EPA Tap Water RSL
Ethylbenzene 700 EPA MCL
m,p-Xylene NS NS
Methyl tert-butyl ether (MTBE)14 EPA Tap Water RSL
Methylene chloride 5 EPA MCL
Location:
Sample ID:
Sampling Date:
SWMU:
S-129-15 S-136-16 S-137-16 S-138-16 S-140-17 S-141-17 S-142-17
S-129-15-
052023
S-135-16-
052023
S-135-16-05-
2023 (FD)
S-136-16-
052023
S-137-16-
052023
S-138-16-
052023
S-139-17-
052023
S-139-17-05-
2023 (FD)
S-140-17-
052023
S-141-17-
052023
S-142-17-
052023
5/5/2023 5/10/2023 5/10/2023 5/11/2023 5/8/2023 5/8/2023 5/12/2023 5/12/2023 5/11/2023 5/8/2023 5/9/2023
1 1 1 1 1 1 25 25 25 25 25
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.400 J 0.380 J 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
50.0 UJ 50.0 U 50.0 U 50.0 U 50.0 UJ 50.0 UJ 50.0 U 50.0 U 50.0 U 50.0 UJ 50.0 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
10.0 UJ 10.0 U 10.0 U 10.0 U 10.0 UJ 10.0 UJ 10.0 U 10.0 U 10.0 U 10.0 UJ 10.0 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
5.00 UJ 5.00 U 5.00 U 5.00 U 5.00 UJ 5.00 UJ 5.00 U 5.00 U 5.00 U 5.00 UJ 5.00 U
10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.330 J 0.330 J 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.280 J 0.500 UJ 1.70 J 1.80 J 0.500 U 0.500 UJ 0.290 J
0.200 UJ 18.0 19.0 29.0 0.200 UJ 0.200 UJ 29000 28000 18.0 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 U
0.200 UJ 1.40 1.40 15.0 0.200 UJ 0.200 UJ 680 690 2.50 0.200 UJ 0.200 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U
1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 UJ 4.30 J 4.20 J 1.00 U 1.00 UJ 1.00 U
S-139-17S-135-16
Page 3 of 4
Table 7
SWMUs 1 and 25 Groundwater Analytical Results
2023 Annual Monitoring Event
VOCs PAL
(µg/L)PAL REFERENCE
Location:
Sample ID:
Sampling Date:
SWMU:
n-Butylbenzene 1,000 EPA Tap Water RSL
n-Propylbenzene 6,60 EPA Tap Water RSL
o-Xylene 190 EPA Tap Water RSL
p-Cymene NS NS
sec-Butylbenzene 2,000 EPA Tap Water RSL
Styrene 100 EPA MCL
tert-Butylbenzene 690 EPA Tap Water RSL
Tetrachloroethene (PCE)5 EPA MCL
Toluene 1,000 EPA MCL
trans-1,2-Dichloroethene 100 EPA MCL
trans-1,3-Dichloropropene NS NS
Trichloroethene (TCE)5 EPA MCL
Trichlorofluoromethane 5,200 EPA Tap Water RSL
Vinyl chloride 2 EPA MCL
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
Detected results appear in bold font.
Detections that exceed the PAL appear in red bold font.
J - The reported result is an estimated value.
J+ - The analyte is considered an estimated value with a possible high-bias due to a QC deviation.
J- - The analyte is considered an estimated value with a possible low-bias due to a QC deviation.
U - Not detected; the compound/analyte was analyzed for, but not detected above the limit of detection
unless otherwise noted.
UJ - The analyte was not detected; however, the result is estimated because of discrepancies in meeting
certain analyte-specific QC criteria.
S-129-15 S-136-16 S-137-16 S-138-16 S-140-17 S-141-17 S-142-17
S-129-15-
052023
S-135-16-
052023
S-135-16-05-
2023 (FD)
S-136-16-
052023
S-137-16-
052023
S-138-16-
052023
S-139-17-
052023
S-139-17-05-
2023 (FD)
S-140-17-
052023
S-141-17-
052023
S-142-17-
052023
5/5/2023 5/10/2023 5/10/2023 5/11/2023 5/8/2023 5/8/2023 5/12/2023 5/12/2023 5/11/2023 5/8/2023 5/9/2023
1 1 1 1 1 1 25 25 25 25 25
S-139-17S-135-16
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 24.0 J 24.0 J 0.190 J 0.300 UJ 0.300 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.120 J 0.110 J 0.200 U 0.200 UJ 0.200 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 4.50 J 4.60 J 0.200 U 0.200 UJ 0.200 U
0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U
0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U
Page 4 of 4
Table 8
SWMU 13 Groundwater Elevation Data
2023 Annual Monitoring Event
LOCATION DATE 
MEASURED
MEASURING POINT 
ELEVATION
(feet amsl)
MEASURED DEPTH 
TO WATER
(feet below 
measuring point)
MEASURED TOTAL 
WELL DEPTH
(feet below 
measuring point)
MEASURED 
GROUNDWATER 
ELEVATION  
(feet amsl)
CORRECTED 
GROUNDWATER 
ELEVATION  
(feet amsl)
WELL USED FOR TDS 
CORRECTION
S‐1‐82 5/1/2023 5039.69 10.53 22.45 5029.16 5029.26 S‐91‐91
S‐25‐88 5/1/2023 5046.18 16.57 21.98 5029.61 5029.64 S‐76‐91
S‐26‐88 5/1/2023 5046.38 16.58 23.25 5029.80 5029.83 S‐76‐91
S‐29‐88 5/1/2023 5042.79 14.46 20.33 5028.33 5028.38 S‐91‐91
S‐30‐88 5/1/2023 5041.66 12.13 20.10 5029.53 5029.60 S‐91‐91
S‐54‐90 5/1/2023 5053.93 20.08 30.58 5033.85 5034.23 S‐56‐90
S‐55‐90 5/1/2023 5045.67 11.33 20.97 5034.34 5034.69 S‐56‐90
S‐56‐90 5/1/2023 5056.00 22.69 51.05 5033.31 5034.33 S‐56‐90
S‐58‐90 5/1/2023 5039.87 9.94 14.15 5029.93 5029.97 S‐91‐91
S‐59‐90 5/1/2023 5038.99 9.22 17.88 5029.77 5029.84 S‐91‐91
S‐76‐91 5/1/2023 5042.86 13.16 25.40 5029.70 5029.76 S‐76‐91
S‐78‐91 5/1/2023 5042.33 12.58 24.90 5029.75 5029.85 S‐78‐91
S‐81‐91 5/1/2023 5044.85 15.21 25.40 5029.64 5029.69 S‐76‐91
S‐82‐91 5/1/2023 5044.36 14.74 25.65 5029.62 5029.67 S‐76‐91
S‐83‐91 5/1/2023 5042.00 12.64 25.45 5029.36 5029.47 S‐91‐91
S‐84‐91 5/1/2023 5040.25 10.38 28.19 5029.87 5030.02 S‐91‐91
S‐86‐91 5/1/2023 5049.84 Dry 17.85 Dry Dry ‐‐
S‐87‐91 5/1/2023 5048.16 Dry 17.85 Dry Dry ‐‐
S‐91‐91 5/1/2023 5040.57 11.21 25.93 5029.36 5029.49 S‐91‐91
S13‐CAM‐DW1 5/1/2023 5044.75 15.18 61.70 5029.57 5029.80 S‐76‐91
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
Page 1 of 1

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Table 9
SWMU 13 Groundwater Analytical Results
2023 Annual Monitoring Event
S13‐CAM‐DW1 S‐55‐90 S‐78‐91
S13‐CAM‐DW1‐052023 S‐55‐90‐052023 S‐78‐91‐052023 S‐91‐91‐052023 S‐91‐91‐05‐2023 (FD)
5/15/2023 5/16/2023 5/16/2023 5/15/2023 5/15/2023
VOCs PAL 
(µg/L)PAL REFERENCE
1,1,1,2‐Tetrachloroethane 0.57 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1,1‐Trichloroethane 200 EPA MCL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1,2,2‐Tetrachloroethane 0.076 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1,2‐Trichloroethane 0.28 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1‐Dichloroethane 2.8 EPA Tapwater RSL 0.120 J 0.200 U 0.200 U 0.180 J 0.170 J
1,1‐Dichloroethene 7 EPA MCL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,1‐Dichloropropene NS NS 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2,3‐Trichlorobenzene 7 EPA Tapwater RSL 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
1,2,3‐Trichloropropane 0.00075 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
1,2,4‐Trichlorobenzene 1.2 EPA Tapwater RSL 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
1,2‐Dibromo‐3‐chloropropane 0.00033 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
1,2‐Dibromoethane (EDB) 0.0075 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2‐Dichlorobenzene 300 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2‐Dichloroethane 0.17 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,2‐Dichloropropane 0.85 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,3‐Dichlorobenzene NS NS 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,3‐Dichloropropane 370 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,4‐Dichlorobenzene 0.48 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
1,4‐Dioxane NS NS 50.0 UJ 50.0 U 50.0 U 50.0 U 50.0 U
2,2‐Dichloropropane NS NS 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
2‐Butanone (MEK) 5,600 EPA Tapwater RSL 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
2‐Chlorotoluene 240 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
2‐Hexanone 38 EPA Tapwater RSL 10.0 UJ 10.0 U 10.0 U 10.0 U 10.0 U
4‐Chlorotoluene 250 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
4‐Methyl‐2‐pentanone (MIBK) NS NS 5.00 UJ 5.00 U 5.00 U 5.00 U 5.00 U
Acetone 14,000 EPA Tapwater RSL 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
Benzene 0.46 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Bromobenzene 62 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Bromochloromethane 83 EPA Tapwater RSL 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Bromodichloromethane 0.13 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Bromoform 3.3 EPA Tapwater RSL 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Bromomethane 7.5 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Carbon disulfide 810 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Carbon tetrachloride 0.46 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Chlorobenzene 78 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Chloroethane 21,000 EPA Tapwater RSL 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 U
Chloroform 0.22 EPA Tapwater RSL 0.200 UJ 1.00 U 0.200 U 0.200 U 0.200 U
Chloromethane 190 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
cis‐1,2‐Dichloroethene 36 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
cis‐1,3‐Dichloropropene NS NS 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Isopropylbenzene (Cumene) 450 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Dibromochloromethane 0.87 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Dibromomethane 8.3 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
Dichlorodifluoromethane 200 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Ethylbenzene 1.5 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
m,p‐Xylene 190 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Methyl tert‐butyl ether (MTBE) 14 EPA Tapwater RSL 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Methylene chloride 5 EPA MCL 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 U
n‐Butylbenzene 1,000 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
n‐Propylbenzene 660 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
o‐Xylene 190 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
p‐Cymene (p‐Isopropyltoluene) NS NS 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
sec‐Butylbenzene 2,000 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Styrene 100 EPA MCL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
tert‐Butylbenzene 690 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Tetrachloroethene (PCE) 5 EPA MCL 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Toluene 1,000 EPA MCL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
trans‐1,2‐Dichloroethene 68 EPA Tapwater RSL 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U
trans‐1,3‐Dichloropropene NS NS 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Trichloroethene (TCE) 0.49 EPA Tapwater RSL 0.200 UJ 0.200 U 0.500 J 0.200 U 0.200 U
Trichlorofluoromethane 5,200 EPA Tapwater RSL 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U
Vinyl chloride 0.019 EPA Tapwater RSL 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U
Location:
Sample ID:
Sampling Date:
S‐91‐91
Page 1 of 2
Table 9
SWMU 13 Groundwater Analytical Results
2023 Annual Monitoring Event
S13‐CAM‐DW1 S‐55‐90 S‐78‐91
S13‐CAM‐DW1‐052023 S‐55‐90‐052023 S‐78‐91‐052023 S‐91‐91‐052023 S‐91‐91‐05‐2023 (FD)
5/15/2023 5/16/2023 5/16/2023 5/15/2023 5/15/2023
VOCs PAL 
(µg/L)PAL REFERENCE
Location:
Sample ID:
Sampling Date:
S‐91‐91
Petroleum Hydrocarbons PAL
TPH‐DRO 10,000
Utah Tier 1 
Screening Level 220 U 220 U 220 U 200 U 210 U
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
Detected results appear in bold font.
Detections that exceed the PAL appear in red bold font.
Yellow highlighted cells indicate non‐detections where the limit of quantitation exceeds the PAL
J ‐ The reported result is an estimated value.
U ‐ Not detected; the compound/analyte was analyzed for, but not detected above the limit of detection unless otherwise noted.
UJ ‐ The analyte was not detected; however, the result is estimated because of discrepancies in meeting certain analyte‐specific QC criteria.
Page 2 of 2
Table 10
SWMU 26 Groundwater Elevation Data
2023 Annual Monitoring Event
LOCATION DATE
MEASURED
MEASURING POINT
ELEVATION
(feet amsl)
MEASURED DEPTH TO
WATER
(feet below measuring
point)
MEASURED TOTAL
WELL DEPTH
(feet below measuring
point)
MEASURED
GROUNDWATER
ELEVATION
(feet amsl)
S-35-90 5/1/2023 5373.49 263.50 279.34 5109.99
S-37-90 5/1/2023 5312.72 199.01 226.57 5113.71
S-38-90 5/1/2023 5323.14 212.95 233.59 5110.19
S-39-90 5/1/2023 5336.91 226.90 257.43 5110.01
S-40-90 5/1/2023 5354.55 247.30 271.85 5107.25
S-41-90 5/1/2023 5382.09 282.49 309 5099.60
S-118-08 5/1/2023 5361.38 254.40 297.65 5106.98
S-122-08 5/1/2023 5379.01 272.13 310.97 5106.88
S-124-13 5/1/2023 5357.33 250.74 259.44 5106.59
S-150-20 5/1/2023 5355.34 246.08 303.4 5109.26
Notes:
For definitions, refer to the Acronyms and Abbreviations section.
Page 1 of 1

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Table 11
SWMU 26 Analytical Results
2023 Annual Monitoring Event
S-38-90 S-150-20
S-38-90-052023 S-40-90-052023 S-40-90-05-2023 (FD)S-150-20-052023
5/17/2023 5/17/2023 5/17/2023 5/17/2023
VOCs PAL
(µg/L)PAL REFERENCE
1,1,1,2-Tetrachloroethane 0.57 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,1,1-Trichloroethane 200 EPA MCL 0.200 U 0.200 U 0.200 U 0.200 U
1,1,2,2-Tetrachloroethane 0.076 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,1,2-Trichloroethane 0.28 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,1-Dichloroethane 2.8 EPA Tapwater RSL 0.200 U 0.630 J 0.660 J 0.200 U
1,1-Dichloroethene 7 EPA MCL 0.200 U 1.50 1.40 0.200 U
1,1-Dichloropropene NS NS 0.200 U 0.200 U 0.200 U 0.200 U
1,2,3-Trichlorobenzene 7 EPA Tapwater RSL 0.300 U 0.300 U 0.300 U 0.300 U
1,2,3-Trichloropropane 0.00075 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
1,2,4-Trichlorobenzene 1.2 EPA Tapwater RSL 0.300 U 0.300 U 0.300 U 0.300 U
1,2-Dibromo-3-chloropropane 0.00033 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
1,2-Dibromoethane (EDB)0.0075 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,2-Dichlorobenzene 300 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,2-Dichloroethane 0.17 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,2-Dichloropropane 0.85 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,3-Dichlorobenzene NS NS 0.200 U 0.200 U 0.200 U 0.200 U
1,3-Dichloropropane 370 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,4-Dichlorobenzene 0.48 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
1,4-Dioxane NS NS 50.0 U 50.0 U 50.0 U 50.0 U
2,2-Dichloropropane NS NS 0.500 U 0.500 U 0.500 U 0.500 U
2-Butanone (MEK)5,600 EPA Tapwater RSL 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
2-Chlorotoluene 240 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
2-Hexanone 38 EPA Tapwater RSL 10.0 U 10.0 U 10.0 U 10.0 U
4-Chlorotoluene 250 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
4-Methyl-2-pentanone (MIBK)NS NS 5.00 U 5.00 U 5.00 U 5.00 U
Acetone 14,000 EPA Tapwater RSL 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
Benzene 0.46 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
Bromobenzene 62 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
Bromochloromethane 83 EPA Tapwater RSL 0.300 U 0.300 U 0.300 U 0.300 U
Bromodichloromethane 0.13 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.220 J
Bromoform 3.3 EPA Tapwater RSL 0.300 U 0.300 U 0.300 U 0.300 U
Bromomethane 7.5 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
Carbon disulfide 810 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
Carbon tetrachloride 0.46 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
Chlorobenzene 78 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
Chloroethane 21,000 EPA Tapwater RSL 1.00 U 1.00 U 1.00 U 1.00 U
Chloroform 0.22 EPA Tapwater RSL 0.250 J 1.00 1.00 0.540 J
Chloromethane 190 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
cis-1,2-Dichloroethene 36 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
cis-1,3-Dichloropropene NS NS 0.200 U 0.200 U 0.200 U 0.200 U
Isopropylbenzene (Cumene)450 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
Dibromochloromethane 0.87 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.160 J
Dibromomethane 8.3 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
Dichlorodifluoromethane 200 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
Ethylbenzene 1.5 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
m,p-Xylene 190 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
Methyl tert-butyl ether (MTBE)14 EPA Tapwater RSL 0.300 U 0.300 U 0.300 U 0.300 U
Methylene chloride 5 EPA MCL 1.00 U 1.00 U 1.00 U 1.00 U
n-Butylbenzene 1,000 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
n-Propylbenzene 660 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
o-Xylene 190 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
p-Cymene (p-Isopropyltoluene) NS NS 0.500 U 0.500 U 0.500 U 0.500 U
sec-Butylbenzene 2,000 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
Styrene 100 EPA MCL 0.500 U 0.500 U 0.500 U 0.500 U
tert-Butylbenzene 690 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
Tetrachloroethene (PCE)5 EPA MCL 0.300 U 0.300 U 0.300 U 0.300 U
Toluene 1,000 EPA MCL 0.200 U 0.200 U 0.200 U 0.200 U
trans-1,2-Dichloroethene 68 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
trans-1,3-Dichloropropene NS NS 0.500 U 0.500 U 0.500 U 0.500 U
Trichloroethene (TCE)0.49 EPA Tapwater RSL 0.200 U 0.200 U 0.200 U 0.200 U
Trichlorofluoromethane 5,200 EPA Tapwater RSL 0.500 U 0.500 U 0.500 U 0.500 U
Vinyl chloride 0.019 EPA Tapwater RSL 0.300 U 0.300 U 0.300 U 0.300 U
S-40-90Location:
Sample ID:
Sampling Date:
Notes:
Detected results appear in bold font.
Detections that exceed the PAL appear in red bold font.
J - The reported result is an estimated value.
U - Not detected; the compound/analyte was analyzed for, but not detected above the limit of detection unless otherwise noted.
Page 1 of 1

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FIGURES

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Service Layer Credits: Source: Esri, Maxar, Earthstar
Geographics, and the GIS User Community
TOOELE ARMY DEPOT SOUTH
SWMU 9
SWMU 34
HWMU 31
SWMU 23 SWMU 8
SWMU 36
SWMU 36
SWMU 3
SWMU 9
SWMU 30
SWMU 13
SWMU 11
SWMU 2 SWMU 22
SWMU 21
SWMU 29
SWMU 37
SWMU 27
SWMU 26
SWMU 32 SWMU 14
SWMU 15
SWMU 17
SWMU 19
SWMU 33
SWMU 20
SWMU 9
SWMU 5
SWMU 28
SWMU 25
BUFFER
ZONE
SWMU 1
1 INCH
1
A.C.
DRAWN:P.M.:
PROJECT No.:FIGURE:DATE:
Legend
SWMU Boundary With LTM
SWMU Boundary Without LTM
Tooele Army Depot South Boundary
770114 2/1/2024
O.C.
p
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
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m
x
d
3,000 0 3,000 6,0001,500
Feet
2023 ANNUAL GROUNDWATER MONITORING
REPORT TOOELE ARMY DEPOT SOUTH
TOOELE, UTAH
TEAD-S OVERVIEW MAP
Abbreviations
TEAD-S Toole Army Depot South
Notes
1. For conceptual purposes only. All locations are approximate.
2. Map produced using ESRI ArcMap v. 10.7.
References
1. Basemap source: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO,
USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,
Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and
the GIS User Community.
UTAH
TOOELE ARMY DEPOT SOUTH

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!U
!U !U
!U!U
!U!U
!U
!U
!U
!U
!U
!U
!U !U !U!U
!U
!U
!U
!U
!U
!U
!U
!U
!U
!U!U
!U!U
!U!U
!U!U
!U
!U
!U
!U
!U
SEE FIGURES 4 AND 5SEE FIGURES 4 AND 5
SWMU 9
SWMU 34
SWMU 31
SWMU 23
SWMU 8
SWMU 36
SWMU 36
SWMU 9
SWMU 30
SWMU 13
SWMU 9
SWMU 5
SWMU 25
BUFFER ZONE
SWMU 1
5028
5027
5 0 2 6
5 0 2 5
5 0 2 4
5023
5022
5021
5020
5018 5
0
1
7
5
0
1
6
5
0
1
5
5
0
1
4
5
0
1
3
5
0
1
2
5
0
1
1
5
0
1
0
5
0
0
9
5 0 1 9
5
0
1
9
5
0
0
8
5023
5 0 1 7
5 0 1 9
1 INCH
2
A.C.
DRAWN:P.M.:
PROJECT No.:FIGURE:DATE:
Legend
!U Monitoring Well
Groundwater Flow Direction
SWMU Boundary With LTM
SWMU Boundary Without LTM
Tooele Army Depot South Boundary
770114 3/21/2024
O.C.
p
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
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P
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T
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.
m
x
d
1,500 0 1,500 3,000750
Feet
2023 ANNUAL GROUNDWATER MONITORING REPORT
TOOELE ARMY DEPOT SOUTH
TOOELE, UTAH
SWMUS 1 AND 25 POTENTIOMETRIC SURFACE MAP
KEY MAPKEY MAP
FIGURE EXTENTFIGURE EXTENT
5028.15
Abbreviations
amsl above mean sea level
ft feet
LTM Long-Term Monitoring
SWMU Solid Waste Management Unit
Notes
1. Groundwater elevations and contours based on measurements collected in May
2023 during the annual monitoring event and corrected to account for
groundwater density variations between wells.
2. Groundwater elevations referenced to North American Vertical Datum of 1988.
3. For conceptual purposes only. All locations are approximate.
4. Map produced using ESRI ArcMap v. 10.7.
References
1. Basemap source: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO,
USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,
Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and
the GIS User Community.
Corrected Groundwater Elevation (ft amsl)

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!U
!U !U
!U!U
!U!U
!U
!U
!U
!U
!U
!U
!U !U !U!U
!U
!U
!U
!U
!U
!U
!U
!U
!U
!U!U
!U!U
!U!U
!U!U
!U!U
!U
!U
!U
!U
SEE FIGURES 6 AND 7SEE FIGURES 6 AND 7
S-141-17
No Analytes
Detected
S-138-16
No Analytes
Detected
SWMU 9
SWMU 34
SWMU 31
SWMU 23 SWMU 8
SWMU 36
SWMU 36
SWMU 9
SWMU 30
SWMU 13
SWMU 9
SWMU 5
SWMU 25
BUFFER ZONE
SWMU 1
S-120-08
S-127-15
S-135-16
S-139-17
S-67-90
No Analytes
Detected S-68-90
No Analytes
Detected
S-70-90
No Analytes
Detected S-71-90
No Analytes
Detected
S-93-92
No Analytes
Detected
S-129-15
No Analytes
Detected
S-97-92
No Analytes
Detected
S-95-92
No Analytes
Detected
S-142-17
S-140-17
S-137-16
S-136-16
S-128-15
S-121-08
WESTERN PLUME
EASTERN
PLUME NORTHERN
PLUME
SOUTHERN
PLUME
MUSTARD MOUNTAIN PLUME
1 INCH
3
A.C.
DRAWN:P.M.:
PROJECT No.:FIGURE:DATE:
Legend
!U Monitoring Well
!U Monitoring Well (Not Sampled)
Approximate Plume Contour
SWMU Boundary With LTM
SWMU Boundary Without LTM
Tooele Army Depot South Boundary
770114 3/21/2024
O.C.
p
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
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Feet
2023 ANNUAL GROUNDWATER MONITORING REPORT
TOOELE ARMY DEPOT SOUTH
TOOELE, UTAH
SWMUS 1 AND 25 GROUNDWATER ANALYTE
DETECTIONS
KEY MAPKEY MAP
FIGURE EXTENTFIGURE EXTENT
Analyte Concentration
Carbon tetrachloride 3.0
Chloroform 1.6
S-121-08
Analyte Concentration
Carbon tetrachloride 350
Chloroform 49.0
Tetrachloroethene (PCE)0.68 J
S-120-08
Analyte Concentration
Carbon disulfide 0.29 J
S-142-17
Analyte Concentration
Carbon tetrachloride 18
Chloroform 2.5
Tetrachloroethene (PCE)0.19 J
S-140-17
Analyte Concentration
1,1-Dichloroethene 0.4 J / 0.38 J
Benzene 0.33 J / 0.33 J
Carbon disulfide 1.7 J / 1.8 J
Carbon tetrachloride 29000 / 28000
Chloroform 680 / 690
Methylene chloride 4.3 J / 4.2 J
Tetrachloroethene (PCE)24.0 J / 24.0 J
trans-1,2-Dichloroethene 0.12 J / 0.11 J
Trichloroethene (TCE)4.5 J / 4.6 J
S-139-17
Analyte Concentration
Carbon tetrachloride 18.0 / 19.0
Chloroform 1.4 / 1.4
S-135-16
Analyte Concentration
Carbon tetrachloride 29.0
Chloroform 15.0
S-136-16
Analyte Concentration
Methylene chloride 0.69 J
Chloroform 130
S-127-15
Analyte Concentration
Benzene 0.1
Chloroform 12.0
S-128-15
Analyte Concentration
Carbon disulfide 0.28
S-137-16
Abbreviations
g/L micrograms per liter
LTM Long-Term Monitoring
PAL Project Action Limit
SWMU Solid Waste Management Unit
Notes
1. Plume contours are for general reference only and correspond to maximum
extent of CTC, TCE, and/or chloroform above PALs during the RFI Addendum
Parsons 2018a). The Mustard Mountain contour has been generalized to
encompass multiple partially overlapping contours.
2. For conceptual purposes only. All locations are approximate.
3. Map produced using ESRI ArcMap v. 10.7.
Chemistry Notes
1. Only detections are shown. If result is not displayed analyte was not detected.
2. All results measured in g/L.
3. Detected results appear in bold font.
4. Results above PAL appear in red/bold font.
5. ## / ## = normal sample result / field duplicate result.
6. J = The reported result is an estimated value.
References
1. Basemap source: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO,
USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,
Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and
the GIS User Community.

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SWMU 30
SWMU 13S-27-88
S-CAM-1
S-CAM-2
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S-29-88
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5029.26
5029.64 5029.83
5028.38
5029.6
5034.23
5034.69
5034.33
5029.97
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Legend
Corrected Groundwater Elevation (ft amsl)
!U Monitoring Well
!U Monitoring Well (Not Gauged)
Groundwater Flow Direction
SWMU Boundary With LTM
SWMU Boundary Without LTM
Tooele Army Depot South Boundary
770114 2/1/2024
O.C.
p
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
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x
d
250 0 250 500125
Feet
2023 ANNUAL GROUNDWATER MONITORING REPORT
TOOELE ARMY DEPOT SOUTH
TOOELE, UTAH
SWMU 13 POTENTIOMETRIC SURFACE MAP
KEY MAPKEY MAP
FIGURE EXTENTFIGURE EXTENT
5027.76
Abbreviations
amsl above mean sea level
ft feet
LTM Long-Term Monitoring
SWMU Solid Waste Management Unit
Notes
1. Groundwater elevations and contours based on measurements collected in May
2023 during the annual monitoring event and corrected to account for
groundwater density variations between wells.
2. Groundwater elevations referenced to North American Vertical Datum of 1988.
3. For conceptual purposes only. All locations are approximate.
4. Map produced using ESRI ArcMap v. 10.7.
References
1. Basemap source: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO,
USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,
Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and
the GIS User Community.
DRY

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SWMU 30
SWMU 13S-27-88
S-1-82
S-105-93
S-106-93
S-25-88 S-26-88
S-29-88
S-30-88
S-54-90
S-55-90
NO ANALYTES
DETECTED
S-56-90
S-58-90
S-59-90
S-76-91
S-78-91
S-81-91
S-82-91
S-83-91
S-84-91
S-86-91
S-87-91
S-91-91
S-92-91
S13-CAM-DW1
S-CAM-1
S-CAM-2
S-133-16
1 INCH
5
A.C.
DRAWN:P.M.:
PROJECT No.:FIGURE:DATE:
Legend
!U Monitoring Well
!U Monitoring Well (Not Sampled)
SWMU Boundary With LTM
SWMU Boundary Without LTM
Tooele Army Depot South Boundary
770114 3/18/2024
O.C.
p
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
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m
x
d
250 0 250 500125
Feet
2023 ANNUAL GROUNDWATER MONITORING
REPORT TOOELE ARMY DEPOT SOUTH
TOOELE, UTAH
SWMU 13 GROUNDWATER ANALYTE DETECTIONS
KEY MAPKEY MAP
FIGURE EXTENTFIGURE EXTENT
Analyte Concentration
1,1-Dichloroethane 0.12 J
S13-CAM-DW1
Analyte Concentration
Trichloroethene 0.5 J
S-78-91
Analyte Concentration
1,1-Dichloroethane 0.18 J / 0.17 J
S-91-91
Abbreviations
g/L micrograms per liter
LTM Long-Term Monitoring
PAL Project Action Limit
SWMU Solid Waste Management Unit
Notes
1. For conceptual purposes only. All locations are approximate.
2. Map produced using ESRI ArcMap v. 10.7.
Chemistry Notes
1. Only detections are shown. If result is not displayed analyte was not detected.
2. All results measured in g/L.
3. Detected results appear in bold font.
4. Results above PAL appear in red/bold font.
5. ## / ## = normal sample result / field duplicate result.
6. J = The reported result is an estimated value.
References
1. Basemap source: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO,
USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,
Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and
the GIS User Community.

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!U
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SWMU 14
SWMU 27
S-35-90
S-37-90
S-38-90
S-39-90
S-40-90
S-41-90
S-118-08 S-122-08
S-124-13
S-150-20
5109.99
5113.71
5110.19
5110.01
5107.25
5099.60
5106.98 5106.88
5106.59
5109.26
5 1 1 2 .5
5101.5
5103.55105.5
5106.5
5109.5
5 1 1 1 .5
5 1 1 0 .5
5 1 0 7 .55108.5
SWMU 26
1 INCH
6
A.C.
DRAWN:P.M.:
PROJECT No.:FIGURE:DATE:
Legend
Measured Groundwater Elevation (ft amsl)
!U Monitoring Well
Groundwater Flow Direction
SWMU Boundary With LTM
SWMU Boundary Without LTM
Tooele Army Depot South Boundary
770114 2/1/2024
O.C.
p
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
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m
x
d
400 0 400 800200
Feet
2023 ANNUAL GROUNDWATER MONITORING REPORT
TOOELE ARMY DEPOT SOUTH
TOOELE, UTAH
SWMU 26 POTENTIOMETRIC SURFACE MAP
KEY MAPKEY MAP
FIGURE EXTENTFIGURE EXTENT
5110.27
Abbreviations
amsl above mean sea level
ft feet
LTM Long-Term Monitoring
SWMU Solid Waste Management Unit
Notes
1.Groundwater elevations and contours based on measurements collected in May
2023 during the monitoring annual event.
2.Groundwater elevations referenced to North American Vertical Datum of 1988.
3.For conceptual purposes only. All locations are approximate.
4.Map produced using ESRI ArcMap v. 10.7.
References
1. Basemap source: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO,
USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,
Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and
the GIS User Community.

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!U
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!USWMU 27
S-35-90
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S-38-90
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S-40-90
S-41-90
S-118-08
S-122-08
S-124-13
S-150-20
SWMU 26
1 INCH
7
A.C.
DRAWN:P.M.:
PROJECT No.:FIGURE:DATE:
Legend
!U Monitoring Well
!U Monitoring Well (Not Sampled)
SWMU Boundary With LTM
SWMU Boundary Without LTM
Tooele Army Depot South Boundary
770114 2/1/2024
O.C.
p
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
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400 0 400 800200
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2023 ANNUAL GROUNDWATER MONITORING REPORT
TOOELE ARMY DEPOT SOUTH
TOOELE, UTAH
SWMU 26 GROUNDWATER ANALYTE DETECTIONS
KEY MAPKEY MAP
FIGURE EXTENTFIGURE EXTENT
Analyte Concentration
Chloroform 0.25 J
S-38-90
Analyte Concentration
1,1‐Dichloroethane 0.63 J / 0.66 J
1,1‐Dichloroethene 1.5 / 1.4
Chloroform 1.0 / 1.0
S-40-90
Analyte Concentration
Bromodichloromethane 0.22 J
Chloroform 0.54 J
Dibromochloromethane 0.16 J
S-150-20
Abbreviations
µg/L micrograms per liter
LTM Long-Term Monitoring
PAL Project Action Limit
SWMU Solid Waste Management Unit
Notes
1.For conceptual purposes only. All locations are approximate.
2.Map produced using ESRI ArcMap v. 10.7.
Chemistry Notes
1.Only detections are shown. If result is not displayed analytes were not detected.
2.All results measured in µg/L.
3.Detected results appear in bold font.
4.Results above PAL appear in red/bold font.
5.## / ## = normal sample result / field duplicate result.
6.J = The reported result is an estimated value.
References
1. Basemap source: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO,
USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,
Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and
the GIS User Community.

This page intentionally blank 

APPENDIX A
CONCENTRATION TREND PLOTS

This page intentionally blank
SWMUs 1 and 25 Chloroform Concentration Plots
S-67-90
: i --,--.---.-------
::::. 0 -
--<D ~
E .... 0 .E 'SI" -
0 ....
.Q
..c:.
{.) 0
N -
0 - C D 0 0
I I I
2015 2017 2019 2021 2023
Year
S-70-90
0 -.------co
::::. 0 -a, <O
~
E .... 0 .E 'SI"
0 ....
.Q
..c:.
{.) 0
N
0
2015 2017 2019 2021
Year
Notes : µg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
0 0
2023
S-68-90
----:------:-----
::J' 0 -
--<D ~
E .... 0 .E 'SI" -
0 ....
.Q
..c:.
{.) 0
N -
0 -0 ::> 0 0
I I I
2015 2017 2019 2021 2023
Year
S-71-90
0 -.-------co
::::. 0 -a, <O
~
E .... 0 .E 'SI"
0 ....
.Q
..c:.
{.) 0
N
0 0 0
2015 2017 2019 2021 2023
Year
SWMUs 1 and 25 Chloroform Concentration Plots
S-93-92
: i --,--.---.-------
::::. 0 -
--<D ~
E .... 0 .E 'SI" -
0 ....
.Q
..c:.
{.) 0
N -
O -< D 0 0
I I I
2015 2017 2019 2021 2023
Year
S-97-92
0 -.------co
::::. 0 -a, <O
~
E .... 0 .E 'SI"
0 ....
.Q
..c:.
{.) 0
N
0
2015 2017 2019 2021
Year
Notes : µg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
0 0
2023
S-95-92
----:------:-----
::J' 0 -
--<D ~
E .... 0 .E 'SI" -
0 ....
.Q
..c:.
{.) 0
N -
0 -0 ::> 0 0
I I I
2015 2017 2019 2021 2023
Year
S-120-08
0 -.-------co
::::. 0 -a, <O
~
E • .... 0 .E 'SI"
0 ....
.Q
..c:.
{.) 0
N
•
0
2015 2017 2019 2021 2023
Year
SWMUs 1 and 25 Chloroform Concentration Plots
S-121-08
: i --,--.---.-------
::::. 0 -
--<D ~
E .... 0 .E 'SI" -
0 ....
.Q
..c:.
{.) 0
N -
0 - C D • •
I I I
2015 2017 2019 2021 2023
::::.
0
0 -C"')
0
LO -N
--0 0) 0 -
~N
E o
.._ LO -
0 ..... e
.Q 8 -..c:. .....
Year
S-128-15
•
{.) :-----:------~-----
0
LO
0 -
• •
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
S-127-15
0
0 -<D
0 ::::. 0
LO --0) • ~ 0
0
E 'SI"
.... 0 ' .E 0 -0 C"') ....
.Q 0 ..c:. 0 -
{.) N
0
0 ---r ---~--..... :-----
0 -
I I I
2015 2017 2019 2021
Year
S-129-15
0 -.-------co
::::. 0 C') <D
~
E .... 0 .E 'SI"
0 ....
.Q
..c:.
{.) 0
N
0
2015 2017 2019 2021
Year
• •
---
2023
0 0
2023
SWMUs 1 and 25 Chloroform Concentration Plots
S-135-16
: i --,--.---.-------
::::. 0 -
--<D ~
E
.... 0 .E 'SI" -e
.Q
..c:.
{.) ~ -
0 -::, • •
I I I
2015 2017 2019 2021 2023
Year
S-137-16
0 -.------co
::::. 0 -a, <O
~
E .... 0 .E 'SI"
0 ....
.Q
..c:.
{.) 0
C'\I
0
2015 2017 2019 2021
Year
Notes : µg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
0 0
2023
S-136-16
----:------:-----
::J' 0 -
--<D ~
E .... 0 .E 'SI" -
0 ....
.Q
..c:.
{.) 0
C'\I -•
•
0 -::,
I I I
2015 2017 2019 2021 2023
Year
S-138-16
0 -.-------co
::::. 0 -a, <O
~
E .... 0 .E 'SI"
0 ....
.Q
..c:.
{.) 0
C'\I
0 0 0
2015 2017 2019 2021 2023
Year
SWMUs 1 and 25 Chloroform Concentration Plots
J --0)
0
0
N .....
-
::::l 0 -o-E a:, ....
.E g -e <.D
.Q 0 .c O -{.) ..,.
0
0 -N
S-139-17
• •
•
, __ -__ , ___________ -
0 -
I I I
2015 2017 2019 2021 2023
Year
S-141-17
0 -.------a:,
J 0 -a, <.D
~
E .... 0 .E ..,.
0 ....
.Q
.c
{.) 0
N
0
2015 2017 2019 2021
Year
Notes : µg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
0 0
2023
S-140-17
::J' 0 -
--<.D ~
E .... 0 .E ..,. -
0 ....
.Q
.c
{.) 0
N -
0 -::,
I I I
2015 2017 2019 2021
Year
S-142-17
0 -.-------a:,
J 0 -a, <.D
~
E .... 0 .E ..,.
0 ....
.Q
.c
{.) 0
N
0
2015 2017 2019 2021
Year
• •
2023
0 0
2023
SWMUs 1 and 25 Carbon Tetrachloride Concentration Plots
S-67-90
<O -
J ,_ - -
--:--• __ ,:_ ______ -
---0)
~ s:t -
(_)
I-
(_)
N -
0 -0 0 0
I I I
2015 2017 2019 2021 2023
Year
S-70-90
<O -
J :-----:--:--7 -------
---0)
~ s:t -
(_)
I-
(_)
N -
0 - (
0 0 0
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter, CTC = Carbon Tetrachloride
Dashed line is the PAL.
Hollow points indicate non-detect results
S-68-90
<O -
J ,_ - -----·----~-----
---0)
~s:t
(_)
I-
(_)
N -
0 -0 :> 0 0
I I I
2015 2017 2019 2021 2023
Year
S-71-90
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~ s:t -
(_)
I-
(_)
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( :> 0 0
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2015 2017 2019 2021 2023
Year
SWMUs 1 and 25 Carbon Tetrachloride Concentration Plots
S-93-92
<O -
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--:--• __ ,:_ ______ -
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~ s:t -
(_)
I-
(_)
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0 -C 0 0 0
I I I
2015 2017 2019 2021 2023
Year
S-97-92
<O -
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~ s:t -
(_)
I-
(_)
N -
o _ C 0 0 0
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter, CTC = Carbon Tetrachloride
Dashed line is the PAL.
Hollow points indicate non-detect results
S-95-92
<O -
J ,_ - -----·----~-----
---0)
~s:t
(_)
I-
(_)
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0 -0 :> 0 0
I I I
2015 2017 2019 2021 2023
Year
S-120-08
0
0
LO
0
0 -s:t
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0) 0 -
~(")
(_)
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0 -(_) N •
0
0 -..... •
0 -, __ ---------------
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2015 2017 2019 2021 2023
Year
SWMUs 1 and 25 Carbon Tetrachloride Concentration Plots
S-121-08
<O -
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~ s:t -
(_)
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N -
•
0 -
I I I
2015 2017 2019 2021 2023
Year
S-128-15
<O -
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~ s:t -
(_)
I-
(_)
N -
0 -( ::> 0 0
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter, CTC = Carbon Tetrachloride
Dashed line is the PAL.
Hollow points indicate non-detect results
S-127-15
<O -
J ,_ - -----·----~-----
---0)
~s:t
(_)
I-
(_)
N -
0 -• 0 0
I I I
2015 2017 2019 2021 2023
Year
S-129-15
<O -
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~ s:t -
(_)
I-
(_)
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0 -
( 0 0
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
SWMUs 1 and 25 Carbon Tetrachloride Concentration Plots
g -
0 -J N
---0)
~~
(_)
I-
(_) 0 -
LO-;---
0 -
S-135-16
•
•
I I I
2015 2017 2019 2021 2023
Year
S-137-16
<O -
J :-----:--:--7 -------
---0)
~ 'SI" -
(_)
I-
(_)
N -
0 -::> 0 0
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter, CTC = Carbon Tetrachloride
Dashed line is the PAL.
Hollow points indicate non-detect results
S-136-16
0 -co
0 -<O
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~o -(_) 'SI"
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I I I I I
2015 2017 2019 2021 2023
Year
S-138-16
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(_)
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(_)
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0 -0 0
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2015 2017 2019 2021 2023
Year
SWMUs 1 and 25 Carbon Tetrachloride Concentration Plots
0
0
0 -0 st
0
0
0 -
-0 ...JC') ---0)
::::l 0
-0 (_) 0 -
I-~
(_)
0
0
0 -0 .....
S-139-17
•
•
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0 -;-----;------~-----
I I I
2015 2017 2019 2021 2023
Year
S-141-17
<O -
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~ st -
(_)
I-
(_)
N -
0 -D • 0
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter, CTC = Carbon Tetrachloride
Dashed line is the PAL.
Hollow points indicate non-detect results
S-140-17
0 -C')
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~ LO .....
(_)
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I I I
2015 2017 2019 2021 2023
Year
S-142-17
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2015 2017 2019 2021 2023
Year
0

2

4

6
S13-CAM-DW1
Year
Ch
l
o
r
o
f
o
r
m

(
mg/
L
)
2014 2016 2018 2020 2022 2024
SWMU 13 Chloroform Concentration Plots
Notes: mg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
0

2

4

6
S-55-90
Year
Ch
l
o
r
o
f
o
r
m

(
mg/
L
)
2014 2016 2018 2020 2022 2024
0

2

4

6
S-78-91
Year
Ch
l
o
r
o
f
o
r
m

(
mg/
L
)
2014 2016 2018 2020 2022 2024
0

2

4

6
S-91-91
Year
Ch
l
o
r
o
f
o
r
m

(
mg/
L
)
2014 2016 2018 2020 2022 2024
SWMU 13 TCE Concentration Plots
:::::. --0)
~
w
(.)
I-
S13-CAM-DW1
<O -
s:t -
N -
i----.----
0 -0, 0 0
I I I
2014 2016 2018 2020 2022 2024
Year
S-78-91
<O -
. '
N -
·• . ' -....
0 -
I I I I I I I I I I I
2014 2016 2018 2020 2022 2024
Year
Notes : µg/L = micrograms per liter, TCE = trichloroethane
Dashed line is the PAL.
Hollow points indicate non-detect results
S-55-90
<O -
:::::. --0)
~ s:t -
w
(.)
I-
N -
2014 2016 2018 2020 2022 2024
Year
S-91-91
<O -
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w
(.)
I-
N -
,------·--
0 -Q 0 0 0
I I I I I I I I I I I
2014 2016 2018 2020 2022 2024
Year
SWMU 26 Bromodichloromethane Concentration Plots
S-38-90
::::. <O -
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~
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C: N -0
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0 -,---0 --,-- - -----0-:~ ~
I I I I
2015 2017 2019 2021 2023
::::. <O -
~
C: g s:t -
I!! -C:
Q) u
§ N -
(.)
Year
S-150-20
0 -;---
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
::::. ---0)
~
C:
0 :;:::.
I!! -C:
Q) u
C:
0
(.)
S-40-90
<O -
s:t -
N -
0 -,--~()-----------0-:~ ~
I I I I
2015 2017 2019 2021 2023
Year
SWMU 26 Chloroform Concentration Plots
<O -::::.
1
E ""'" -....
.E e
.Q
..c:.
{.) N -
S-38-90
I I I I I I I I
2015 2017 2019 2021 2023
<O -::::.
1
E ""'" -....
.E e
.Q
..c:.
{.) N -
0 -
Year
S-150-20
,_ --__ , ____ _. ____ . __ ._ ._
I I I I I I I I I I
2015 2017 2019 2021 2023
Year
Notes : µg/L = micrograms per liter
Dashed line is the PAL.
Hollow points indicate non-detect results
<O -::::.
1
E ""'" -....
.E e
.Q
..c:.
{.) N -
S-40-90
• : . . .
o ---r -,-------------r -1
I I I I I I I
2015 2017 2019 2021 2023
Year

APPENDIX B
WELL INSPECTION FORMS

This page intentionally blank
2023 TEAD Well Inventory
Well ID: S-1-82
Date Time Observed
20230501 12:26
Depth To Water (FT BTOC):
10.53
Total Depth (FT BTOC):
22.45
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-4-82
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
Date Time Observed
20230502 10:59
Depth To Water (FT BTOC):
57.44
Total Depth (FT BTOC):
86.52
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
General Notes:
Note minor issues and
maintenance during meetings
Well Photos
2023 TEAD Well Inventory
Well ID: S-5-82
Date Time Observed
20230502 10:46
Depth To Water (FT BTOC):
37.93
Total Depth (FT BTOC):
58.8
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-6-82
Date Time Observed
20230502 13:17
Depth To Water (FT BTOC):
21.29
Total Depth (FT BTOC):
37.36
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-7-82
Date Time Observed
20230502 13:48
Depth To Water (FT BTOC):
33.6
Total Depth (FT BTOC):
54.21
Casing Diameter (INCHES):
5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Faded
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-18-88
Date Time Observed
20230502 10:11
Depth To Water (FT BTOC):
23.03
Total Depth (FT BTOC):
39.14
Casing Diameter (INCHES):
7.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-19-88
Date Time Observed
20230502 09:54
Depth To Water (FT BTOC):
38.98
Total Depth (FT BTOC):
39.38
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-25-88
Date Time Observed
20230501 14:46
Depth To Water (FT BTOC):
16.57
Total Depth (FT BTOC):
21.98
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-26-88
Date Time Observed
20230501 14:39
Depth To Water (FT BTOC):
16.58
Total Depth (FT BTOC):
23.25
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-29-88
Date Time Observed
20230501 13:38
Depth To Water (FT BTOC):
14.46
Total Depth (FT BTOC):
20.33
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-30-88
Date Time Observed
20230501 13:01
Depth To Water (FT BTOC):
12.13
Total Depth (FT BTOC):
20.1
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-35-90
Date Time Observed
20230501 08:58
Depth To Water (FT BTOC):
263.5
Total Depth (FT BTOC):
279.34
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Starting to
fade
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-37-90
Date Time Observed
20230501 09:49
Depth To Water (FT BTOC):
199.01
Total Depth (FT BTOC):
226.57
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-38-90
Date Time Observed
20230501 10:01
Depth To Water (FT BTOC):
212.95
Total Depth (FT BTOC):
233.59
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-39-90
Date Time Observed
20230501 10:14
Depth To Water (FT BTOC):
226.9
Total Depth (FT BTOC):
257.43
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-40-90
Date Time Observed
20230501 10:26
Depth To Water (FT BTOC):
247.3
Total Depth (FT BTOC):
271.85
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-41-90
Date Time Observed
20230501 10:48
Depth To Water (FT BTOC):
282.49
Total Depth (FT BTOC):
309
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-54-90
Date Time Observed
20230501 14:07
Depth To Water (FT BTOC):
20.08
Total Depth (FT BTOC):
30.58
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Paint peeling
id fading
Well Completion/Bollard Condition:
OK:
General Notes:
Solid bottom for td
Well Photos
2023 TEAD Well Inventory
Well ID: S-55-90
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Starting to fade
Well Completion/Bollard Condition:
Minor Issue (describe in notes):Pad cracked still
solid needs to be re caulked
Date Time Observed
20230501 14:30
Depth To Water (FT BTOC):
11.33
Total Depth (FT BTOC):
20.97
Casing Diameter (INCHES):
7.5
Well Casing Material:
PVC
General Notes:
Note minor issues and
maintenance during meetings
Well Photos
2023 TEAD Well Inventory
Well ID: S-56-90
Date Time Observed
20230501 14:24
Depth To Water (FT BTOC):
22.69
Total Depth (FT BTOC):
51.05
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-58-90
Date Time Observed
20230501 12:08
Depth To Water (FT BTOC):
9.94
Total Depth (FT BTOC):
14.15
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-59-90
Date Time Observed
20230501 12:15
Depth To Water (FT BTOC):
9.22
Total Depth (FT BTOC):
17.88
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-64-90
Date Time Observed
20230502 13:38
Depth To Water (FT BTOC):
26.45
Total Depth (FT BTOC):
37.4
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-65-90
Date Time Observed
20230502 13:26
Depth To Water (FT BTOC):
21.06
Total Depth (FT BTOC):
28.82
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-66-90
Date Time Observed
20230502 13:56
Depth To Water (FT BTOC):
40.84
Total Depth (FT BTOC):
96.82
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Faded
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-67-90
Date Time Observed
20230502 10:01
Depth To Water (FT BTOC):
22.53
Total Depth (FT BTOC):
38.44
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
Minor Issue (describe in notes):Pad cracked still
solid needs to be caulked
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-68-90
Date Time Observed
20230502 10:30
Depth To Water (FT BTOC):
44.32
Total Depth (FT BTOC):
64.4
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-69-90
Date Time Observed
20230502 09:17
Depth To Water (FT BTOC):
100.07
Total Depth (FT BTOC):
125.54
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Replaced gw lock with n4 new lock
Well Photos
2023 TEAD Well Inventory
Well ID: S-70-90
Date Time Observed
20230502 10:40
Depth To Water (FT BTOC):
47.67
Total Depth (FT BTOC):
52.22
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-71-90
Date Time Observed
20230502 10:52
Depth To Water (FT BTOC):
40.65
Total Depth (FT BTOC):
66.82
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-76-91
Date Time Observed
20230501 13:22
Depth To Water (FT BTOC):
13.16
Total Depth (FT BTOC):
25.4
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-78-91
Date Time Observed
20230501 13:08
Depth To Water (FT BTOC):
12.58
Total Depth (FT BTOC):
24.9
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
Minor Issue (describe in notes):Pad cracked still
solid needs to be caulked
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-81-91
Date Time Observed
20230501 13:16
Depth To Water (FT BTOC):
15.21
Total Depth (FT BTOC):
25.4
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-82-91
Date Time Observed
20230501 15:13
Depth To Water (FT BTOC):
14.74
Total Depth (FT BTOC):
25.65
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Slight hydrocarbon odor when the well was opened. Product was not detected.
Well Photos
2023 TEAD Well Inventory
Well ID: S-83-91
Date Time Observed
20230501 13:31
Depth To Water (FT BTOC):
12.64
Total Depth (FT BTOC):
25.45
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-84-91
Date Time Observed
20230501 12:01
Depth To Water (FT BTOC):
10.38
Total Depth (FT BTOC):
28.19
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-86-91
Date Time Observed
20230501 13:50
Depth To Water (FT BTOC):
0
Total Depth (FT BTOC):
18.71
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well dry
Well Photos
2023 TEAD Well Inventory
Well ID: S-87-91
Date Time Observed
20230501 14:17
Depth To Water (FT BTOC):
0
Total Depth (FT BTOC):
17.85
Casing Diameter (INCHES):
4.2
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Dry
Well Photos
2023 TEAD Well Inventory
Well ID: S-91-91
Date Time Observed
20230501 12:52
Depth To Water (FT BTOC):
11.21
Total Depth (FT BTOC):
25.93
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
Minor Issue (describe in notes):Pad cracked still
solid but needs to be caulked
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-93-92
Date Time Observed
20230502 11:06
Depth To Water (FT BTOC):
66.12
Total Depth (FT BTOC):
153.87
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-95-92
Date Time Observed
20230502 10:20
Depth To Water (FT BTOC):
31.05
Total Depth (FT BTOC):
130.35
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-96-92
Date Time Observed
20230502 12:34
Depth To Water (FT BTOC):
67.4
Total Depth (FT BTOC):
117.01
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-97-92
Date Time Observed
20230502 11:16
Depth To Water (FT BTOC):
73.19
Total Depth (FT BTOC):
85.34
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-98-92
Date Time Observed
20230502 09:35
Depth To Water (FT BTOC):
29.97
Total Depth (FT BTOC):
41.61
Casing Diameter (INCHES):
7.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Fading
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-99-92
Date Time Observed
20230502 14:30
Depth To Water (FT BTOC):
34.34
Total Depth (FT BTOC):
40.9
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-100-92
Date Time Observed
20230502 14:05
Depth To Water (FT BTOC):
56.95
Total Depth (FT BTOC):
76.89
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-101-92
Date Time Observed
20230502 14:20
Depth To Water (FT BTOC):
44.54
Total Depth (FT BTOC):
52.78
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-102-92
Date Time Observed
20230502 14:14
Depth To Water (FT BTOC):
38.95
Total Depth (FT BTOC):
46.31
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-118-08
Date Time Observed
20230501 09:25
Depth To Water (FT BTOC):
254.4
Total Depth (FT BTOC):
297.65
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-120-08
Date Time Observed
20230502 15:19
Depth To Water (FT BTOC):
35.33
Total Depth (FT BTOC):
68.79
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-121-08
Date Time Observed
20230502 15:02
Depth To Water (FT BTOC):
35.92
Total Depth (FT BTOC):
55.39
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-122-08
Date Time Observed
20230501 09:12
Depth To Water (FT BTOC):
272.13
Total Depth (FT BTOC):
310.97
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-124-13
Date Time Observed
20230501 10:37
Depth To Water (FT BTOC):
250.74
Total Depth (FT BTOC):
259.44
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-125-15
Well Lock Condition:
OK:
Well Lid Condition:
Minor Issue (describe in notes):Does not close all
the way, well cap has lock
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
Date Time Observed
20230502 11:34
Depth To Water (FT BTOC):
63.94
Total Depth (FT BTOC):
72.05
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
General Notes:
Note minor issues and
maintenance during meetings
Well Photos
2023 TEAD Well Inventory
Well ID: S-126-16
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
Date Time Observed
20230502 11:26
Depth To Water (FT BTOC):
58.88
Total Depth (FT BTOC):
66.84
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
General Notes:
Well id is s-126-15 not s-126-16
Note minor issues and
maintenance during meetings Well Photos
2023 TEAD Well Inventory
Well ID: S-127-15
Date Time Observed
20230502 12:04
Depth To Water (FT BTOC):
76.78
Total Depth (FT BTOC):
117.51
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-128-15
Date Time Observed
20230502 12:11
Depth To Water (FT BTOC):
69.79
Total Depth (FT BTOC):
107.55
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-129-15
Date Time Observed
20230502 11:42
Depth To Water (FT BTOC):
52.18
Total Depth (FT BTOC):
108.25
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-135-16
Date Time Observed
20230502 12:19
Depth To Water (FT BTOC):
123.35
Total Depth (FT BTOC):
187.72
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-136-16
Date Time Observed
20230502 12:24
Depth To Water (FT BTOC):
118.27
Total Depth (FT BTOC):
249.4
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-137-16
Date Time Observed
20230502 11:48
Depth To Water (FT BTOC):
57.73
Total Depth (FT BTOC):
128.34
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-138-16
Date Time Observed
20230502 11:54
Depth To Water (FT BTOC):
54.56
Total Depth (FT BTOC):
197.7
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-139-17
Date Time Observed
20230502 15:10
Depth To Water (FT BTOC):
54.99
Total Depth (FT BTOC):
62.38
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Peeling
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-140-17
Date Time Observed
20230502 14:52
Depth To Water (FT BTOC):
55
Total Depth (FT BTOC):
200.33
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Peeling off
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-141-17
Date Time Observed
20230502 14:45
Depth To Water (FT BTOC):
61.52
Total Depth (FT BTOC):
77.7
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-142-17
Date Time Observed
20230502 14:35
Depth To Water (FT BTOC):
33.4
Total Depth (FT BTOC):
212.4
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
Minor Issue (describe in notes):Peeling off
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-150-20
Date Time Observed
20230501 10:57
Depth To Water (FT BTOC):
246.08
Total Depth (FT BTOC):
303.4
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S13-CAM-DW1
Date Time Observed
20230501 14:59
Depth To Water (FT BTOC):
15.18
Total Depth (FT BTOC):
61.7
Casing Diameter (INCHES):
4.5
Well Casing Material:
PVC
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
General Notes:
Well Photos
2023 TEAD Well Inventory
Well ID: S-P3-90
Well Lock Condition:
OK:
Well Lid Condition:
OK:
Well Cap Condition:
OK:
Stencil ID Condition:
OK:
Well Completion/Bollard Condition:
OK:
Date Time Observed
20230502 09:45
Depth To Water (FT BTOC):
15.83
Total Depth (FT BTOC):
16.3
Casing Diameter (INCHES):
2.25
Well Casing Material:
PVC
General Notes:
Just pvc casing
note issue during next meeting
Well Photos

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APPENDIX C
FIELD SAMPLING FORMS

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Calibration Forms

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Well Water Quality Reports

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2023 Sampling Forms

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Low-Flow Test Report:
Test Date / Time: 5/3/2023 10:37:14 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-67-90
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 26 ft (bgs)
Total Depth: 38.44 ft
Initial Depth to Water: 22.51 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 33.5 ft
Estimated Total Volume Pumped:
20 liter
Flow Cell Volume: 130 ml
Final Flow Rate: 200 ml/min
Final Draw Down: 0.39 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Could not lower pump speed to lower flow rate due to default controller settings, called manufacturer to fix issue with
next wells. All parameters stable at time of sampling, last 3 DO readings had measurements below 0.1 mg/L.
Weather Conditions:
65 hazy
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/3/2023
10:37 AM
00:00 6.59 pH 18.20 °C 25,740 µS/cm 4.50 mg/L 143.04 NTU 192.8 mV 22.51 ft 200.00 ml/min
5/3/2023
10:40 AM
03:00 7.12 pH 12.95 °C 28,161 µS/cm 0.56 mg/L 355.89 NTU 183.1 mV 22.80 ft 200.00 ml/min
5/3/2023
10:43 AM 06:00 7.14 pH 12.56 °C 28,422 µS/cm 0.37 mg/L 253.87 NTU 180.4 mV 22.85 ft 200.00 ml/min
5/3/2023
10:46 AM 09:00 7.16 pH 12.05 °C 28,440 µS/cm 0.31 mg/L 250.20 NTU 178.7 mV 22.90 ft 200.00 ml/min
5/3/2023
10:49 AM 12:00 7.16 pH 12.13 °C 28,552 µS/cm 0.27 mg/L 345.88 NTU 177.5 mV 22.90 ft 200.00 ml/min
5/3/2023
10:52 AM 15:00 7.17 pH 12.14 °C 28,548 µS/cm 0.19 mg/L 358.41 NTU 176.8 mV 22.90 ft 200.00 ml/min
5/3/2023
10:55 AM 18:00 7.17 pH 12.10 °C 28,500 µS/cm 0.16 mg/L 377.80 NTU 176.3 mV 22.90 ft 200.00 ml/min
5/3/2023
10:58 AM 21:00 7.18 pH 12.01 °C 28,502 µS/cm 0.15 mg/L 306.65 NTU 175.5 mV 22.90 ft 200.00 ml/min
5/3/2023
11:01 AM
24:00 7.18 pH 12.01 °C 28,487 µS/cm 0.16 mg/L 240.74 NTU 174.8 mV 22.90 ft 200.00 ml/min
5/3/2023
11:04 AM
27:00 7.18 pH 11.87 °C 28,529 µS/cm 0.15 mg/L 196.52 NTU 174.0 mV 22.90 ft 200.00 ml/min
5/3/2023
11:07 AM
30:00 7.18 pH 11.87 °C 28,544 µS/cm 0.13 mg/L 156.08 NTU 173.3 mV 22.90 ft 200.00 ml/min
5/3/2023
11:10 AM
33:00 7.18 pH 12.05 °C 28,573 µS/cm 0.12 mg/L 126.25 NTU 172.5 mV 22.90 ft 200.00 ml/min
5/3/2023
11:13 AM
36:00 7.18 pH 12.14 °C 28,560 µS/cm 0.23 mg/L 94.30 NTU 172.6 mV 22.90 ft 200.00 ml/min
5/3/2023
11:16 AM 39:00 7.18 pH 12.03 °C 28,552 µS/cm 0.17 mg/L 70.77 NTU 172.3 mV 22.90 ft 200.00 ml/min
5/3/2023
11:19 AM 42:00 7.18 pH 12.09 °C 28,583 µS/cm 0.15 mg/L 51.62 NTU 171.5 mV 22.90 ft 200.00 ml/min
5/3/2023
11:22 AM 45:00 7.18 pH 12.03 °C 28,618 µS/cm 0.12 mg/L 50.47 NTU 170.5 mV 22.90 ft 200.00 ml/min
5/3/2023
11:25 AM 48:00 7.18 pH 12.02 °C 28,666 µS/cm 0.12 mg/L 42.05 NTU 169.7 mV 22.90 ft 200.00 ml/min
5/3/2023
11:28 AM 51:00 7.19 pH 11.91 °C 28,575 µS/cm 0.10 mg/L 32.60 NTU 169.1 mV 22.90 ft 200.00 ml/min
5/3/2023
11:31 AM 54:00 7.19 pH 12.03 °C 28,666 µS/cm 0.11 mg/L 27.54 NTU 168.3 mV 22.90 ft 200.00 ml/min
5/3/2023
11:34 AM
57:00 7.19 pH 12.06 °C 28,644 µS/cm 0.09 mg/L 22.08 NTU 167.5 mV 22.90 ft 200.00 ml/min
5/3/2023
11:37 AM
01:00:00 7.19 pH 12.03 °C 28,633 µS/cm 0.08 mg/L 17.99 NTU 166.8 mV 22.90 ft 200.00 ml/min
5/3/2023
11:40 AM
01:03:00 7.19 pH 11.87 °C 28,669 µS/cm 0.11 mg/L 13.62 NTU 166.1 mV 22.90 ft 200.00 ml/min
5/3/2023
11:43 AM
01:06:00 7.19 pH 11.79 °C 28,657 µS/cm 0.09 mg/L 11.70 NTU 165.5 mV 22.90 ft 200.00 ml/min
5/3/2023
11:46 AM
01:09:00 7.19 pH 11.89 °C 28,643 µS/cm 0.07 mg/L 11.92 NTU 164.9 mV 22.90 ft 200.00 ml/min
5/3/2023
11:49 AM
01:12:00 7.19 pH 11.97 °C 28,685 µS/cm 0.08 mg/L 13.32 NTU 164.3 mV 22.90 ft 200.00 ml/min
5/3/2023
11:52 AM
01:15:00 7.19 pH 11.70 °C 28,717 µS/cm 0.06 mg/L 10.72 NTU 163.6 mV 22.90 ft 200.00 ml/min
5/3/2023
11:55 AM
01:18:00 7.19 pH 11.85 °C 28,736 µS/cm 0.07 mg/L 12.37 NTU 162.9 mV 22.90 ft 200.00 ml/min
5/3/2023
11:58 AM
01:21:00 7.19 pH 11.84 °C 28,740 µS/cm 0.08 mg/L 11.77 NTU 162.3 mV 22.90 ft 200.00 ml/min
5/3/2023
12:01 PM 01:24:00 7.19 pH 12.05 °C 28,712 µS/cm 0.06 mg/L 8.94 NTU 161.8 mV 22.90 ft 200.00 ml/min
Samples
Sample ID: Description:
S-67-90-052023 Sample time of 1205, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/4/2023 9:34:08 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-68-90
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 52.5 ft (bgs)
Total Depth: 64.4 ft
Initial Depth to Water: 44.2 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 60 ft
Estimated Total Volume Pumped:
3600 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 100 ml/min
Final Draw Down: 0.54 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
68 clear
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/4/2023 9:34
AM
00:00 6.92 pH 15.14 °C 14,208 µS/cm 5.86 mg/L 54.04 NTU 232.7 mV 44.20 ft 100.00 ml/min
5/4/2023 9:37
AM
03:00 7.51 pH 14.39 °C 14,524 µS/cm 2.78 mg/L 16.86 NTU 216.6 mV 44.50 ft 100.00 ml/min
5/4/2023 9:40
AM 06:00 7.53 pH 14.42 °C 14,526 µS/cm 2.75 mg/L 16.58 NTU 208.9 mV 44.52 ft 100.00 ml/min
5/4/2023 9:43
AM 09:00 7.54 pH 14.28 °C 14,536 µS/cm 2.70 mg/L 16.81 NTU 197.4 mV 44.55 ft 100.00 ml/min
5/4/2023 9:46
AM 12:00 7.54 pH 14.30 °C 14,552 µS/cm 2.64 mg/L 15.82 NTU 184.9 mV 44.58 ft 100.00 ml/min
5/4/2023 9:49
AM 15:00 7.54 pH 14.37 °C 14,557 µS/cm 2.58 mg/L 15.67 NTU 170.5 mV 44.62 ft 100.00 ml/min
5/4/2023 9:52
AM 18:00 7.55 pH 14.30 °C 14,565 µS/cm 2.55 mg/L 15.79 NTU 158.7 mV 44.64 ft 100.00 ml/min
5/4/2023 9:55
AM 21:00 7.55 pH 14.39 °C 14,591 µS/cm 2.55 mg/L 15.07 NTU 148.7 mV 44.66 ft 100.00 ml/min
5/4/2023 9:58
AM
24:00 7.56 pH 14.39 °C 14,533 µS/cm 2.54 mg/L 14.90 NTU 140.9 mV 44.68 ft 100.00 ml/min
5/4/2023
10:01 AM
27:00 7.56 pH 14.52 °C 14,592 µS/cm 2.59 mg/L 14.29 NTU 133.5 mV 44.70 ft 100.00 ml/min
5/4/2023
10:04 AM
30:00 7.56 pH 14.61 °C 14,587 µS/cm 2.62 mg/L 15.19 NTU 126.6 mV 44.72 ft 100.00 ml/min
5/4/2023
10:07 AM
33:00 7.57 pH 14.95 °C 14,577 µS/cm 2.65 mg/L 14.42 NTU 122.0 mV 44.73 ft 100.00 ml/min
5/4/2023
10:10 AM
36:00 7.57 pH 15.05 °C 14,584 µS/cm 2.66 mg/L 15.27 NTU 117.7 mV 44.74 ft 100.00 ml/min
Samples
Sample ID: Description:
S-68-90 Sample time of 1015, MS/MSD, 9 Sample containers. VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/4/2023 10:53:59 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-70-90
Well Diameter: 4.5 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 40 ft (bgs)
Total Depth: 52.22 ft
Initial Depth to Water: 47.58 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined Pump
Intake From TOC: 50 ft
Estimated Total Volume Pumped:
1500 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 100 ml/min Final
Draw Down: 0.24 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
72 pc
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/4/2023
10:53 AM
00:00 7.33 pH 17.11 °C 13,458 µS/cm 7.54 mg/L 3.84 NTU 175.0 mV 47.58 ft 100.00 ml/min
5/4/2023
10:56 AM
03:00 7.30 pH 16.52 °C 13,685 µS/cm 7.72 mg/L 1.65 NTU 166.4 mV 47.77 ft 100.00 ml/min
5/4/2023
10:59 AM 06:00 7.30 pH 16.27 °C 13,686 µS/cm 7.72 mg/L 0.73 NTU 155.9 mV 47.78 ft 100.00 ml/min
5/4/2023
11:02 AM 09:00 7.31 pH 15.73 °C 13,661 µS/cm 7.79 mg/L 1.55 NTU 150.3 mV 47.80 ft 100.00 ml/min
5/4/2023
11:05 AM 12:00 7.31 pH 15.47 °C 13,710 µS/cm 7.82 mg/L 0.68 NTU 152.1 mV 47.81 ft 100.00 ml/min
5/4/2023
11:08 AM 15:00 7.31 pH 15.66 °C 13,707 µS/cm 7.79 mg/L 0.60 NTU 148.6 mV 47.82 ft 100.00 ml/min
Samples
Sample ID: Description:
S-70-90 Sample time 1110, MS/MSD, 9 sample containers VOCs 8260,
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/4/2023 11:56:57 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-71-90
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 58 ft (bgs)
Total Depth: 66.82 ft
Initial Depth to Water: 40.4 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 64.8 ft
Estimated Total Volume Pumped:
6300 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 100 ml/min
Final Draw Down: 3.03 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Hard to maintain consistent flow rate below 100/ml/min. Tried to lower to 80 ml/min and it was difficult to
maintain a consistent flow rate which was causing parameter fluctuation (mainly temperature). After sampling
this well we called and talked to pump manufacturer, they recommend to increase pump speed a few settings
higher and use a clamp to squish the tubing to reduce to the desired flow rate.
Weather Conditions:
74 pc
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/4/2023
11:56 AM
00:00 7.54 pH 18.23 °C 10,829 µS/cm 4.79 mg/L 691.14 NTU 181.1 mV 40.40 ft 100.00 ml/min
5/4/2023
11:59 AM
03:00 7.58 pH 16.33 °C 11,364 µS/cm 4.29 mg/L 488.02 NTU 174.1 mV 40.83 ft 100.00 ml/min
5/4/2023
12:02 PM 06:00 7.58 pH 16.87 °C 11,416 µS/cm 4.32 mg/L 413.54 NTU 163.3 mV 40.92 ft 100.00 ml/min
5/4/2023
12:05 PM 09:00 7.59 pH 16.46 °C 11,348 µS/cm 4.30 mg/L 415.04 NTU 151.7 mV 41.01 ft 100.00 ml/min
5/4/2023
12:08 PM 12:00 7.59 pH 16.93 °C 11,457 µS/cm 4.35 mg/L 344.08 NTU 136.8 mV 41.08 ft 100.00 ml/min
5/4/2023
12:11 PM 15:00 7.60 pH 16.69 °C 11,335 µS/cm 4.24 mg/L 325.74 NTU 123.2 mV 41.17 ft 100.00 ml/min
5/4/2023
12:14 PM 18:00 7.60 pH 16.82 °C 11,438 µS/cm 4.30 mg/L 268.29 NTU 110.4 mV 41.25 ft 100.00 ml/min
5/4/2023
12:17 PM 21:00 7.61 pH 15.75 °C 11,293 µS/cm 4.21 mg/L 254.89 NTU 97.6 mV 41.36 ft 100.00 ml/min
5/4/2023
12:20 PM
24:00 7.61 pH 15.63 °C 11,359 µS/cm 4.18 mg/L 184.47 NTU 88.3 mV 41.48 ft 100.00 ml/min
5/4/2023
12:23 PM
27:00 7.60 pH 16.03 °C 11,410 µS/cm 4.21 mg/L 145.59 NTU 84.5 mV 41.58 ft 100.00 ml/min
5/4/2023
12:26 PM
30:00 7.61 pH 15.85 °C 11,356 µS/cm 4.54 mg/L 119.81 NTU 87.6 mV 41.68 ft 100.00 ml/min
5/4/2023
12:29 PM
33:00 7.60 pH 16.44 °C 11,364 µS/cm 4.29 mg/L 86.98 NTU 83.1 mV 41.77 ft 100.00 ml/min
5/4/2023
12:32 PM
36:00 7.61 pH 15.59 °C 11,319 µS/cm 4.24 mg/L 76.20 NTU 80.8 mV 41.84 ft 100.00 ml/min
5/4/2023
12:35 PM 39:00 7.60 pH 15.64 °C 11,369 µS/cm 4.24 mg/L 59.67 NTU 79.0 mV 41.94 ft 100.00 ml/min
5/4/2023
12:38 PM 42:00 7.61 pH 15.48 °C 11,356 µS/cm 4.21 mg/L 56.56 NTU 77.3 mV 42.02 ft 100.00 ml/min
5/4/2023
12:41 PM 45:00 7.61 pH 15.41 °C 11,366 µS/cm 4.20 mg/L 50.67 NTU 75.5 mV 42.10 ft 100.00 ml/min
5/4/2023
12:44 PM 48:00 7.61 pH 15.40 °C 11,374 µS/cm 4.20 mg/L 43.41 NTU 73.4 mV 42.15 ft 100.00 ml/min
5/4/2023
12:47 PM 51:00 7.61 pH 15.43 °C 11,369 µS/cm 4.19 mg/L 40.15 NTU 71.7 mV 42.21 ft 100.00 ml/min
5/4/2023
12:50 PM 54:00 7.60 pH 15.50 °C 11,389 µS/cm 4.21 mg/L 36.35 NTU 70.3 mV 42.26 ft 100.00 ml/min
5/4/2023
12:53 PM
57:00 7.61 pH 15.44 °C 11,358 µS/cm 4.18 mg/L 29.75 NTU 68.8 mV 42.31 ft 100.00 ml/min
5/4/2023
12:56 PM
01:00:00 7.61 pH 15.17 °C 11,371 µS/cm 4.19 mg/L 29.30 NTU 68.1 mV 42.37 ft 100.00 ml/min
5/4/2023
12:59 PM
01:03:00 7.61 pH 15.09 °C 11,381 µS/cm 4.19 mg/L 27.27 NTU 67.7 mV 43.43 ft 100.00 ml/min
Samples
Sample ID: Description:
S-71-90 Sample time 1305, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/5/2023 9:36:31 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-93-92
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 15 ft
Top of Screen: 136 ft (bgs)
Total Depth: 153.87 ft
Initial Depth to Water: 64.4 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 146 ft
Estimated Total Volume Pumped:
2293.333 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 80 ml/min
Final Draw Down: 1.32 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
50 cloudy
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/5/2023 9:36
AM 00:00 7.28 pH 11.76 °C
5,701.4
µS/cm 4.42 mg/L 4.55 NTU 234.2 mV 64.40 ft 100.00 ml/min
5/5/2023 9:37
AM 01:07 7.54 pH 11.67 °C
5,765.3
µS/cm 2.64 mg/L 1.41 NTU 231.0 mV 64.40 ft 100.00 ml/min
5/5/2023 9:40
AM 04:07 7.66 pH 11.36 °C
5,792.6
µS/cm 1.80 mg/L 2.21 NTU 223.0 mV 65.07 ft 100.00 ml/min
5/5/2023 9:43
AM 06:44 7.68 pH 11.22 °C
5,806.1
µS/cm 1.57 mg/L 1.10 NTU 219.7 mV 66.17 ft 100.00 ml/min
5/5/2023 9:46
AM 09:44 7.68 pH 11.17 °C
5,814.1
µS/cm 1.48 mg/L 0.61 NTU 217.8 mV 65.28 ft 100.00 ml/min
5/5/2023 9:49
AM 12:44 7.69 pH 11.13 °C
5,817.0
µS/cm 1.40 mg/L 0.43 NTU 215.3 mV 65.40 ft 100.00 ml/min
5/5/2023 9:52
AM 15:44 7.69 pH 11.15 °C
5,823.1
µS/cm 1.35 mg/L 0.32 NTU 213.1 mV 65.51 ft 80.00 ml/min
5/5/2023 9:55
AM
18:44 7.69 pH 11.16 °C
5,815.4
µS/cm
1.31 mg/L 0.42 NTU 210.4 mV 65.58 ft 80.00 ml/min
5/5/2023 9:58
AM
21:44 7.69 pH 11.09 °C 5,818.7
µS/cm
1.30 mg/L 0.30 NTU 207.5 mV 65.65 ft 80.00 ml/min
5/5/2023
10:01 AM
24:44 7.69 pH 11.06 °C 5,823.8
µS/cm
1.30 mg/L 0.24 NTU 204.6 mV 65.72 ft 80.00 ml/min
Samples
Sample ID: Description:
S-93-92-052023 Sample time of 1005, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/3/2023 1:20:29 PM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-95-92
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 15 ft
Top of Screen: 103 ft (bgs)
Total Depth: 130.35 ft
Initial Depth to Water: 30.14 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined Pump
Intake From TOC: 118 ft
Estimated Total Volume Pumped:
8220 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 100 ml/min
Final Draw Down: 3.12 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Hard to maintain consistent flowrate below 100/ml/min at time of purging, which was causing parameter
fluctuation (mainly temperature).
Weather Conditions:
75 clear
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/3/2023 1:20
PM
00:00 7.38 pH 31.85 °C 3.77 µS/cm 6.04 mg/L 1.57 NTU 150.5 mV 30.14 ft 200.00 ml/min
5/3/2023 1:23
PM
03:00 7.64 pH 16.31 °C
9,775.0
µS/cm
2.29 mg/L 182.77 NTU 140.7 mV 30.61 ft 200.00 ml/min
5/3/2023 1:26
PM 06:00 7.70 pH 15.50 °C
9,959.6
µS/cm 1.07 mg/L 370.85 NTU 105.4 mV 30.85 ft 200.00 ml/min
5/3/2023 1:29
PM 09:00 7.72 pH 15.57 °C 10,004 µS/cm 0.86 mg/L 237.95 NTU 84.6 mV 31.05 ft 160.00 ml/min
5/3/2023 1:32
PM 12:00 7.72 pH 16.14 °C
9,999.4
µS/cm 0.78 mg/L 193.08 NTU 69.5 mV 31.21 ft 160.00 ml/min
5/3/2023 1:35
PM 15:00 7.74 pH 16.17 °C 10,018 µS/cm 0.74 mg/L 165.06 NTU 59.0 mV 31.37 ft 160.00 ml/min
5/3/2023 1:38
PM 18:00 7.75 pH 16.15 °C 10,022 µS/cm 0.71 mg/L 149.94 NTU 53.1 mV 31.51 ft 140.00 ml/min
5/3/2023 1:41
PM 21:00 7.75 pH 16.27 °C 10,034 µS/cm 0.71 mg/L 133.91 NTU 43.2 mV 31.64 ft 140.00 ml/min
5/3/2023 1:44
PM
24:00 7.76 pH 16.53 °C 10,055 µS/cm 0.71 mg/L 122.82 NTU 41.1 mV 31.76 ft 140.00 ml/min
5/3/2023 1:47
PM
27:00 7.75 pH 17.23 °C 10,087 µS/cm 0.72 mg/L 123.46 NTU 37.8 mV 31.86 ft 140.00 ml/min
5/3/2023 1:50
PM
30:00 7.75 pH 17.85 °C 10,074 µS/cm 0.74 mg/L 121.15 NTU 33.5 mV 31.94 ft 120.00 ml/min
5/3/2023 1:53
PM
33:00 7.78 pH 15.85 °C 10,011 µS/cm 0.65 mg/L 110.12 NTU 21.0 mV 32.15 ft 120.00 ml/min
5/3/2023 1:56
PM
36:00 7.78 pH 16.38 °C 10,060 µS/cm 0.63 mg/L 92.52 NTU 16.2 mV 32.27 ft 120.00 ml/min
5/3/2023 1:59
PM 39:00 7.77 pH 16.99 °C 10,055 µS/cm 0.59 mg/L 92.97 NTU 13.1 mV 32.38 ft 120.00 ml/min
5/3/2023 2:02
PM 42:00 7.77 pH 17.19 °C
9,966.8
µS/cm 0.61 mg/L 101.42 NTU 10.1 mV 32.47 ft 120.00 ml/min
5/3/2023 2:05
PM 45:00 7.79 pH 16.10 °C 10,004 µS/cm 0.56 mg/L 99.22 NTU 1.6 mV 32.63 ft 100.00 ml/min
5/3/2023 2:08
PM 48:00 7.79 pH 16.36 °C 10,067 µS/cm 0.54 mg/L 111.86 NTU -2.1 mV 32.78 ft 100.00 ml/min
5/3/2023 2:11
PM 51:00 7.79 pH 16.84 °C 10,077 µS/cm 0.49 mg/L 123.67 NTU -5.7 mV 32.90 ft 100.00 ml/min
5/3/2023 2:14
PM 54:00 7.80 pH 16.40 °C
9,971.7
µS/cm 0.47 mg/L 138.64 NTU -11.2 mV 33.03 ft 100.00 ml/min
5/3/2023 2:17
PM
57:00 7.79 pH 16.42 °C 10,038 µS/cm 0.46 mg/L 136.30 NTU -16.6 mV 33.16 ft 100.00 ml/min
5/3/2023 2:20
PM
01:00:00 7.79 pH 16.64 °C
9,964.4
µS/cm
0.47 mg/L 150.23 NTU -15.7 mV 33.26 ft 100.00 ml/min
Samples
Sample ID: Description:
S-95-92-052023 Sample time of 1420, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/5/2023 11:00:40 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-97-92
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 73 ft (bgs)
Total Depth: 85.34 ft
Initial Depth to Water: 73.1 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 80.5 ft
Estimated Total Volume Pumped:
3130 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 80 ml/min
Final Draw Down: 0.71 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
50 cloudy
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/5/2023
11:00 AM
00:00 7.17 pH 12.43 °C 17,360 µS/cm 6.82 mg/L 0.46 NTU 221.4 mV 73.10 ft 100.00 ml/min
5/5/2023
11:01 AM
01:18 7.17 pH 12.49 °C 17,405 µS/cm 6.73 mg/L 0.38 NTU 221.5 mV 100.00 ml/min
5/5/2023
11:04 AM 04:18 7.19 pH 12.15 °C 17,449 µS/cm 6.65 mg/L 0.27 NTU 215.1 mV 73.58 ft 100.00 ml/min
5/5/2023
11:07 AM 07:18 7.19 pH 12.53 °C 17,512 µS/cm 6.68 mg/L 0.23 NTU 203.3 mV 73.62 ft 100.00 ml/min
5/5/2023
11:10 AM 10:18 7.20 pH 12.36 °C 17,472 µS/cm 6.66 mg/L 0.29 NTU 191.9 mV 73.67 ft 100.00 ml/min
5/5/2023
11:13 AM 13:18 7.20 pH 12.27 °C 17,466 µS/cm 6.68 mg/L 0.27 NTU 182.5 mV 73.70 ft 100.00 ml/min
5/5/2023
11:16 AM 16:18 7.21 pH 12.16 °C 17,451 µS/cm 6.70 mg/L 0.23 NTU 173.5 mV 73.73 ft 100.00 ml/min
5/5/2023
11:19 AM 19:18 7.21 pH 12.16 °C 17,456 µS/cm 6.73 mg/L 0.23 NTU 165.8 mV 73.76 ft 80.00 ml/min
5/5/2023
11:22 AM
22:18 7.21 pH 12.65 °C 17,515 µS/cm 6.79 mg/L 0.26 NTU 162.0 mV 73.77 ft 80.00 ml/min
5/5/2023
11:25 AM
25:18 7.21 pH 12.93 °C 17,442 µS/cm 6.75 mg/L 0.27 NTU 155.0 mV 73.79 ft 80.00 ml/min
5/5/2023
11:28 AM
28:18 7.22 pH 13.00 °C 17,364 µS/cm 6.70 mg/L 0.27 NTU 148.0 mV 73.80 ft 80.00 ml/min
5/5/2023
11:31 AM
31:18 7.22 pH 12.90 °C 17,380 µS/cm 6.73 mg/L 0.26 NTU 142.7 mV 73.80 ft 80.00 ml/min
5/5/2023
11:34 AM
34:18 7.22 pH 13.02 °C 17,377 µS/cm 6.75 mg/L 0.32 NTU 138.4 mV 73.81 ft 80.00 ml/min
Samples
Sample ID: Description:
S-97-92-052023 Sample time 1137, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/12/2023 9:14:13 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-120-08
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 20 ft
Top of Screen: 47 ft (bgs)
Total Depth: 68.79 ft
Initial Depth to Water: 35.26 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 59.5 ft
Estimated Total Volume Pumped:
2400 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 0.23 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Partly cloudy, 50 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/12/2023
9:14 AM
00:00 6.98 pH 14.07 °C 25,849 µS/cm 6.04 mg/L 25.34 NTU 246.9 mV 35.26 ft 50.00 ml/min
5/12/2023
9:17 AM
03:00 7.21 pH 13.48 °C 28,560 µS/cm 4.51 mg/L 115.57 NTU 234.7 mV 35.48 ft 50.00 ml/min
5/12/2023
9:20 AM 06:00 7.11 pH 13.99 °C 29,068 µS/cm 2.92 mg/L 129.80 NTU 233.7 mV 35.48 ft 50.00 ml/min
5/12/2023
9:23 AM 09:00 7.11 pH 14.28 °C 29,149 µS/cm 2.61 mg/L 91.59 NTU 229.7 mV 35.48 ft 50.00 ml/min
5/12/2023
9:26 AM 12:00 7.11 pH 14.46 °C 29,211 µS/cm 2.66 mg/L 70.63 NTU 220.6 mV 35.48 ft 50.00 ml/min
5/12/2023
9:29 AM 15:00 7.11 pH 14.62 °C 29,265 µS/cm 2.70 mg/L 59.22 NTU 206.5 mV 35.48 ft 50.00 ml/min
5/12/2023
9:32 AM 18:00 7.11 pH 14.85 °C 29,334 µS/cm 2.70 mg/L 51.45 NTU 190.7 mV 35.48 ft 50.00 ml/min
5/12/2023
9:35 AM 21:00 7.11 pH 15.20 °C 29,402 µS/cm 2.69 mg/L 47.22 NTU 178.1 mV 35.48 ft 50.00 ml/min
5/12/2023
9:38 AM
24:00 7.10 pH 15.57 °C 29,365 µS/cm 2.64 mg/L 43.58 NTU 165.2 mV 35.48 ft 50.00 ml/min
5/12/2023
9:41 AM
27:00 7.11 pH 15.51 °C 29,265 µS/cm 2.65 mg/L 36.37 NTU 156.5 mV 35.48 ft 50.00 ml/min
5/12/2023
9:44 AM
30:00 7.11 pH 15.33 °C 29,248 µS/cm 2.63 mg/L 31.34 NTU 147.9 mV 35.48 ft 50.00 ml/min
5/12/2023
9:47 AM
33:00 7.11 pH 15.25 °C 29,262 µS/cm 2.52 mg/L 33.65 NTU 138.5 mV 35.49 ft 50.00 ml/min
5/12/2023
9:50 AM
36:00 7.11 pH 15.36 °C 29,315 µS/cm 2.43 mg/L 33.21 NTU 131.2 mV 35.49 ft 50.00 ml/min
5/12/2023
9:53 AM 39:00 7.10 pH 15.58 °C 29,327 µS/cm 2.38 mg/L 32.88 NTU 125.8 mV 35.49 ft 50.00 ml/min
5/12/2023
9:56 AM 42:00 7.10 pH 15.80 °C 29,297 µS/cm 2.35 mg/L 30.26 NTU 120.9 mV 35.49 ft 50.00 ml/min
5/12/2023
9:59 AM 45:00 7.10 pH 15.92 °C 29,248 µS/cm 2.31 mg/L 27.98 NTU 116.6 mV 35.49 ft 50.00 ml/min
5/12/2023
10:02 AM 48:00 7.09 pH 16.16 °C 29,325 µS/cm 2.29 mg/L 27.62 NTU 113.2 mV 35.49 ft 50.00 ml/min
Samples
Sample ID: Description:
S-120-08-052023 Sample time 1005, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/9/2023 12:20:32 PM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-121-08
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 20 ft
Top of Screen: 33 ft (bgs)
Total Depth: 55.39 ft
Initial Depth to Water: 35.9 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined Pump
Intake From TOC: 45.5 ft
Estimated Total Volume Pumped:
900 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 0.15 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Breezy, sunny, 57 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/9/2023
12:20 PM
00:00 7.17 pH 16.40 °C 26,476 µS/cm 6.89 mg/L 8.48 NTU -21.5 mV 35.90 ft 50.00 ml/min
5/9/2023
12:23 PM
03:00 7.16 pH 15.96 °C 27,358 µS/cm 6.02 mg/L 30.25 NTU 11.7 mV 36.07 ft 50.00 ml/min
5/9/2023
12:26 PM 06:00 7.16 pH 16.35 °C 27,551 µS/cm 5.98 mg/L 12.71 NTU 18.9 mV 36.08 ft 50.00 ml/min
5/9/2023
12:29 PM 09:00 7.16 pH 16.83 °C 27,618 µS/cm 5.91 mg/L 8.27 NTU 23.5 mV 36.05 ft 50.00 ml/min
5/9/2023
12:32 PM 12:00 7.16 pH 17.13 °C 27,505 µS/cm 5.75 mg/L 5.84 NTU 30.6 mV 36.05 ft 50.00 ml/min
5/9/2023
12:35 PM 15:00 7.16 pH 17.17 °C 27,540 µS/cm 5.72 mg/L 4.81 NTU 34.9 mV 36.05 ft 50.00 ml/min
5/9/2023
12:38 PM 18:00 7.16 pH 17.33 °C 27,502 µS/cm 5.62 mg/L 4.22 NTU 38.8 mV 36.05 ft 50.00 ml/min
Samples
Sample ID: Description:
S-121-08-052023 Sample time 1240, MS/MSD, 9 sample containers
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/10/2023 1:52:54 PM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-127-15
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 105 ft (bgs)
Total Depth: 117.51 ft
Initial Depth to Water: 76.33 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined Pump
Intake From TOC: 112.5 ft
Estimated Total Volume Pumped:
1500 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 0.94 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Cloudy, windy, 55 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/10/2023
1:52 PM
00:00 7.50 pH 15.91 °C 5,841.7
µS/cm
4.45 mg/L 36.33 NTU 43.6 mV 76.33 ft 50.00 ml/min
5/10/2023
1:55 PM
03:00 7.38 pH 15.57 °C
6,008.9
µS/cm
2.05 mg/L 17.38 NTU 48.7 mV 76.82 ft 50.00 ml/min
5/10/2023
1:58 PM 06:00 7.37 pH 15.80 °C
6,030.0
µS/cm 1.72 mg/L 11.85 NTU 49.8 mV 76.90 ft 50.00 ml/min
5/10/2023
2:01 PM 09:00 7.38 pH 15.79 °C
6,023.6
µS/cm 1.65 mg/L 8.37 NTU 53.9 mV 76.95 ft 50.00 ml/min
5/10/2023
2:04 PM 12:00 7.38 pH 15.63 °C
6,023.4
µS/cm 1.68 mg/L 6.76 NTU 57.4 mV 76.99 ft 50.00 ml/min
5/10/2023
2:07 PM 15:00 7.39 pH 15.46 °C
6,024.8
µS/cm 1.73 mg/L 5.59 NTU 60.1 mV 77.04 ft 50.00 ml/min
5/10/2023
2:10 PM 18:00 7.39 pH 15.41 °C
6,034.4
µS/cm 1.80 mg/L 4.37 NTU 62.3 mV 77.10 ft 50.00 ml/min
5/10/2023
2:13 PM 21:00 7.39 pH 15.46 °C
6,034.7
µS/cm 1.85 mg/L 3.96 NTU 64.0 mV 77.14 ft 50.00 ml/min
5/10/2023
2:16 PM
24:00 7.39 pH 15.52 °C
6,039.1
µS/cm
1.88 mg/L 3.60 NTU 64.3 mV 77.19 ft 50.00 ml/min
5/10/2023
2:19 PM
27:00 7.39 pH 15.61 °C 6,038.8
µS/cm
1.88 mg/L 2.90 NTU 63.3 mV 77.23 ft 50.00 ml/min
5/10/2023
2:22 PM
30:00 7.39 pH 15.71 °C 6,039.4
µS/cm
1.87 mg/L 2.87 NTU 61.9 mV 77.27 ft 50.00 ml/min
Samples
Sample ID: Description:
S-127-15-052023 Sample time 1425, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/9/2023 1:51:38 PM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-128-15
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 95 ft (BGS)
Total Depth: 107.55 ft
Initial Depth to Water: 69.43 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined Pump
Intake From TOC: 102.5 ft
Estimated Total Volume Pumped:
1350 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 0.85 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
60 F, breezy, sunny
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/9/2023 1:51
PM
00:00 7.45 pH 18.76 °C 5,952.0
µS/cm
5.38 mg/L 3.30 NTU 19.9 mV 69.43 ft 50.00 ml/min
5/9/2023 1:54
PM
03:00 7.42 pH 18.74 °C
6,004.8
µS/cm
4.75 mg/L 0.69 NTU 11.7 mV 69.90 ft 50.00 ml/min
5/9/2023 1:57
PM 06:00 7.42 pH 18.55 °C
6,001.0
µS/cm 4.51 mg/L 0.66 NTU 5.2 mV 69.97 ft 50.00 ml/min
5/9/2023 2:00
PM 09:00 7.42 pH 18.81 °C
6,011.1
µS/cm 4.08 mg/L 0.59 NTU 3.2 mV 70.02 ft 50.00 ml/min
5/9/2023 2:03
PM 12:00 7.42 pH 19.08 °C
6,026.1
µS/cm 3.92 mg/L 0.66 NTU 0.5 mV 70.07 ft 50.00 ml/min
5/9/2023 2:06
PM 15:00 7.43 pH 18.95 °C
6,002.1
µS/cm 3.93 mg/L 0.66 NTU -0.9 mV 70.12 ft 50.00 ml/min
5/9/2023 2:09
PM 18:00 7.43 pH 19.14 °C
6,038.8
µS/cm 3.59 mg/L 0.64 NTU -2.3 mV 70.16 ft 50.00 ml/min
5/9/2023 2:12
PM 21:00 7.43 pH 19.37 °C
6,023.1
µS/cm 3.46 mg/L 0.59 NTU -2.1 mV 70.21 ft 50.00 ml/min
5/9/2023 2:15
PM
24:00 7.43 pH 19.12 °C
6,012.0
µS/cm
3.50 mg/L 0.60 NTU -2.9 mV 70.24 ft 50.00 ml/min
5/9/2023 2:18
PM
27:00 7.43 pH 19.36 °C 6,035.4
µS/cm
3.19 mg/L 0.68 NTU -3.6 mV 70.28 ft 50.00 ml/min
Samples
Sample ID: Description:
S-128-15 Sample time 1420, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/5/2023 12:30:32 PM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-129-15
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 96 ft (bgs)
Total Depth: 108.25 ft
Initial Depth to Water: 51.66 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 103.5 ft
Estimated Total Volume Pumped:
2880 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 80 ml/min
Final Draw Down: 1.29 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
54 pc
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/5/2023
12:30 PM 00:00 7.57 pH 14.98 °C
6,587.5
µS/cm 4.27 mg/L 3.88 NTU -159.2 mV 51.66 ft 100.00 ml/min
5/5/2023
12:33 PM 03:00 7.71 pH 14.25 °C
6,993.3
µS/cm 1.26 mg/L 65.01 NTU -152.0 mV 52.16 ft 100.00 ml/min
5/5/2023
12:36 PM 06:00 7.74 pH 14.52 °C
7,012.8
µS/cm 0.98 mg/L 32.13 NTU -139.5 mV 52.29 ft 100.00 ml/min
5/5/2023
12:39 PM 09:00 7.76 pH 14.16 °C
7,004.2
µS/cm 1.02 mg/L 21.38 NTU -131.5 mV 52.39 ft 100.00 ml/min
5/5/2023
12:42 PM 12:00 7.76 pH 14.29 °C
7,042.5
µS/cm 1.10 mg/L 20.94 NTU -127.2 mV 52.47 ft 80.00 ml/min
5/5/2023
12:45 PM 15:00 7.76 pH 14.44 °C
7,025.2
µS/cm 1.15 mg/L 18.16 NTU -124.6 mV 52.55 ft 80.00 ml/min
5/5/2023
12:48 PM 18:00 7.76 pH 14.42 °C
7,013.8
µS/cm 1.16 mg/L 15.67 NTU -123.3 mV 52.62 ft 80.00 ml/min
5/5/2023
12:51 PM
21:00 7.75 pH 14.65 °C
7,075.6
µS/cm
1.17 mg/L 13.48 NTU -123.2 mV 52.70 ft 80.00 ml/min
5/5/2023
12:54 PM
24:00 7.75 pH 15.22 °C 7,031.9
µS/cm
1.12 mg/L 11.62 NTU -123.3 mV 52.77 ft 80.00 ml/min
5/5/2023
12:57 PM
27:00 7.75 pH 14.73 °C 7,036.4
µS/cm
1.09 mg/L 9.77 NTU -124.7 mV 52.84 ft 80.00 ml/min
5/5/2023 1:00
PM
30:00 7.75 pH 14.72 °C 7,004.1
µS/cm
1.06 mg/L 7.48 NTU -125.6 mV 52.90 ft 80.00 ml/min
5/5/2023 1:03
PM
33:00 7.75 pH 14.85 °C 7,009.3
µS/cm
1.06 mg/L 7.06 NTU -125.2 mV 52.95 ft 80.00 ml/min
Samples
Sample ID: Description:
S-129-15 Sample time 1305, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/10/2023 9:39:32 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-135-16
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 175.5 ft (bgs)
Total Depth: 187.72 ft
Initial Depth to Water: 121.11 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 207.5 ft
Estimated Total Volume Pumped:
4800 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 6.09 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Pump stopped pumping around 11:11, had to pull pump and tubing got disconnected from pump during purge. Reattach tubing and
restarted purge on a new form. No sample associated with this form see next form.
Weather Conditions:
Windy, cloudy, 50 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/10/2023
9:39 AM
00:00 6.99 pH 13.37 °C 4,808.7
µS/cm
5.57 mg/L 17.25 NTU 184.5 mV 121.11 ft 50.00 ml/min
5/10/2023
9:42 AM
03:00 7.41 pH 13.26 °C
4,897.6
µS/cm
3.59 mg/L 535.63 NTU 45.4 mV 123.77 ft 50.00 ml/min
5/10/2023
9:45 AM 06:00 7.60 pH 13.46 °C
4,896.0
µS/cm 2.75 mg/L 888.87 NTU -6.4 mV 123.97 ft 50.00 ml/min
5/10/2023
9:48 AM 09:00 7.65 pH 13.54 °C
4,889.8
µS/cm 1.80 mg/L 1,341.3 NTU -25.2 mV 124.18 ft 50.00 ml/min
5/10/2023
9:51 AM 12:00 7.68 pH 13.62 °C
4,885.7
µS/cm 1.78 mg/L 1,328.7 NTU -29.8 mV 124.33 ft 50.00 ml/min
5/10/2023
9:54 AM 15:00 7.68 pH 13.71 °C
4,888.8
µS/cm 1.83 mg/L 1,234.0 NTU -30.0 mV 124.57 ft 50.00 ml/min
5/10/2023
9:57 AM 18:00 7.67 pH 13.94 °C
4,896.4
µS/cm 1.88 mg/L 1,089.1 NTU -26.5 mV 124.74 ft 50.00 ml/min
5/10/2023
10:00 AM 21:00 7.69 pH 14.27 °C
4,893.4
µS/cm 1.92 mg/L 1,001.2 NTU -31.1 mV 124.90 ft 50.00 ml/min
5/10/2023
10:03 AM
24:00 7.69 pH 14.47 °C
4,887.2
µS/cm
1.96 mg/L 872.55 NTU -22.8 mV 125.06 ft 50.00 ml/min
5/10/2023
10:06 AM
27:00 7.69 pH 14.69 °C 4,890.5
µS/cm
2.02 mg/L 803.71 NTU -24.5 mV 125.19 ft 50.00 ml/min
5/10/2023
10:09 AM
30:00 7.68 pH 14.97 °C 4,897.5
µS/cm
2.08 mg/L 720.37 NTU -19.0 mV 125.33 ft 50.00 ml/min
5/10/2023
10:12 AM
33:00 7.68 pH 15.34 °C 4,898.8
µS/cm
2.10 mg/L 613.77 NTU -17.8 mV 125.46 ft 50.00 ml/min
5/10/2023
10:15 AM
36:00 7.67 pH 15.63 °C 4,894.9
µS/cm
2.11 mg/L 553.11 NTU -24.4 mV 125.58 ft 50.00 ml/min
5/10/2023
10:18 AM 39:00 7.68 pH 15.86 °C
4,886.5
µS/cm 2.10 mg/L 505.31 NTU -31.6 mV 125.70 ft 50.00 ml/min
5/10/2023
10:21 AM 42:00 7.67 pH 16.05 °C
4,897.2
µS/cm 2.11 mg/L 414.34 NTU -32.7 mV 125.83 ft 50.00 ml/min
5/10/2023
10:24 AM 45:00 7.66 pH 16.35 °C
4,899.3
µS/cm 2.09 mg/L 335.92 NTU -34.5 mV 125.95 ft 50.00 ml/min
5/10/2023
10:27 AM 48:00 7.66 pH 16.61 °C
4,891.3
µS/cm 2.07 mg/L 275.80 NTU -37.4 mV 126.06 ft 50.00 ml/min
5/10/2023
10:30 AM 51:00 7.66 pH 16.80 °C
4,897.3
µS/cm 2.05 mg/L 232.21 NTU -39.4 mV 126.17 ft 50.00 ml/min
5/10/2023
10:33 AM 54:00 7.66 pH 17.01 °C
4,886.4
µS/cm 2.01 mg/L 199.70 NTU -42.3 mV 126.28 ft 50.00 ml/min
5/10/2023
10:36 AM
57:00 7.66 pH 16.81 °C
4,855.8
µS/cm
1.99 mg/L 149.35 NTU -44.7 mV 126.39 ft 50.00 ml/min
5/10/2023
10:39 AM
01:00:00 7.67 pH 16.06 °C
4,850.2
µS/cm
1.99 mg/L 126.19 NTU -46.0 mV 126.48 ft 50.00 ml/min
5/10/2023
10:42 AM
01:03:00 7.67 pH 15.64 °C 4,857.8
µS/cm
1.91 mg/L 106.82 NTU -47.0 mV 126.58 ft 50.00 ml/min
5/10/2023
10:45 AM
01:06:00 7.67 pH 15.36 °C 4,862.0
µS/cm
1.88 mg/L 93.60 NTU -48.2 mV 126.67 ft 50.00 ml/min
5/10/2023
10:48 AM
01:09:00 7.68 pH 15.17 °C 4,865.7
µS/cm
1.85 mg/L 81.87 NTU -48.9 mV 126.76 ft 50.00 ml/min
5/10/2023
10:51 AM
01:12:00 7.68 pH 15.06 °C 4,866.2
µS/cm
1.82 mg/L 69.67 NTU -49.8 mV 126.86 ft 50.00 ml/min
5/10/2023
10:54 AM
01:15:00 7.68 pH 14.94 °C 4,867.5
µS/cm
1.79 mg/L 58.89 NTU -50.2 mV 126.93 ft 50.00 ml/min
5/10/2023
10:57 AM
01:18:00 7.68 pH 14.86 °C 4,871.0
µS/cm
1.77 mg/L 54.60 NTU -50.4 mV 126.99 ft 50.00 ml/min
5/10/2023
11:00 AM
01:21:00 7.67 pH 14.86 °C
4,876.6
µS/cm
1.75 mg/L 47.29 NTU -50.4 mV 127.05 ft 50.00 ml/min
5/10/2023
11:03 AM 01:24:00 7.67 pH 14.91 °C
4,877.5
µS/cm 1.74 mg/L 37.77 NTU -50.3 mV 127.11 ft 50.00 ml/min
5/10/2023
11:06 AM 01:27:00 7.67 pH 15.05 °C
4,886.3
µS/cm 1.75 mg/L 33.56 NTU -49.0 mV 127.14 ft 50.00 ml/min
5/10/2023
11:09 AM 01:30:00 7.66 pH 15.27 °C
4,886.1
µS/cm 1.73 mg/L 33.40 NTU -49.5 mV 127.16 ft 50.00 ml/min
5/10/2023
11:12 AM 01:33:00 7.65 pH 15.69 °C
4,909.5
µS/cm 1.78 mg/L 27.70 NTU -46.4 mV 127.18 ft 50.00 ml/min
5/10/2023
11:15 AM 01:36:00 7.64 pH 16.38 °C
4,926.0
µS/cm 1.76 mg/L 27.82 NTU -44.1 mV 127.20 ft 50.00 ml/min
5/10/2023
11:18 AM 01:39:00 7.78 pH 17.36 °C 2.41 µS/cm 7.99 mg/L 0.40 NTU 4.8 mV
5/10/2023
11:21 AM
01:42:00 8.01 pH 18.39 °C 2.12 µS/cm 7.87 mg/L 0.51 NTU 16.1 mV
5/10/2023
11:24 AM
01:45:00 8.21 pH 19.67 °C 1.85 µS/cm 7.76 mg/L 0.50 NTU 17.7 mV
5/10/2023
11:27 AM
01:48:00 8.32 pH 20.95 °C 1.58 µS/cm 7.62 mg/L 0.61 NTU 19.0 mV
Samples
Sample ID: Description:
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/10/2023 11:45:41 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-135-16
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 175.5 ft (bgs)
Total Depth: 187.72 ft
Initial Depth to Water: 124.41 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 207.5 ft
Estimated Total Volume Pumped:
5250 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 4.79 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
50s mostly cloudy windy
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/10/2023
11:45 AM
00:00 7.45 pH 18.72 °C 4,598.3
µS/cm
4.83 mg/L 118.75 NTU 60.3 mV 124.41 ft 100.00 ml/min
5/10/2023
11:48 AM
03:00 7.54 pH 16.78 °C
4,829.2
µS/cm
2.71 mg/L 545.11 NTU -22.8 mV 127.10 ft 100.00 ml/min
5/10/2023
11:51 AM 06:00 7.68 pH 16.10 °C
4,830.6
µS/cm 1.67 mg/L 1,197.7 NTU -72.4 mV 127.40 ft 100.00 ml/min
5/10/2023
11:54 AM 09:00 7.73 pH 15.81 °C
4,864.6
µS/cm 1.46 mg/L 1,253.0 NTU -82.0 mV 127.72 ft 100.00 ml/min
5/10/2023
11:57 AM 12:00 7.74 pH 15.87 °C
4,863.4
µS/cm 1.35 mg/L 1,246.6 NTU -85.1 mV 128.03 ft 100.00 ml/min
5/10/2023
12:00 PM 15:00 7.74 pH 15.61 °C
4,856.7
µS/cm 1.27 mg/L 1,094.2 NTU -85.3 mV 128.29 ft 100.00 ml/min
5/10/2023
12:03 PM 18:00 7.74 pH 15.50 °C
4,869.5
µS/cm 1.24 mg/L 934.55 NTU -84.6 mV 128.57 ft 100.00 ml/min
5/10/2023
12:06 PM 21:00 7.72 pH 15.99 °C
4,920.2
µS/cm 1.24 mg/L 728.34 NTU -83.0 mV 128.80 ft 100.00 ml/min
5/10/2023
12:09 PM
24:00 7.71 pH 16.49 °C
4,890.6
µS/cm
1.19 mg/L 566.98 NTU -81.5 mV 129.01 ft 100.00 ml/min
5/10/2023
12:12 PM
27:00 7.70 pH 16.61 °C 4,896.4
µS/cm
1.24 mg/L 392.97 NTU -76.6 mV 129.07 ft 50.00 ml/min
5/10/2023
12:15 PM
30:00 7.69 pH 17.09 °C 4,926.0
µS/cm
1.35 mg/L 333.62 NTU -72.1 mV 129.09 ft 50.00 ml/min
5/10/2023
12:18 PM
33:00 7.68 pH 17.69 °C 4,930.9
µS/cm
1.35 mg/L 310.28 NTU -68.0 mV 129.09 ft 50.00 ml/min
5/10/2023
12:21 PM
36:00 7.68 pH 17.98 °C 4,894.2
µS/cm
1.32 mg/L 273.03 NTU -72.3 mV 129.10 ft 50.00 ml/min
5/10/2023
12:24 PM 39:00 7.68 pH 17.70 °C
4,866.9
µS/cm 1.31 mg/L 245.71 NTU -73.1 mV 129.11 ft 50.00 ml/min
5/10/2023
12:27 PM 42:00 7.68 pH 17.32 °C
4,868.7
µS/cm 1.32 mg/L 226.05 NTU -71.9 mV 129.13 ft 50.00 ml/min
5/10/2023
12:30 PM 45:00 7.68 pH 17.14 °C
4,872.5
µS/cm 1.33 mg/L 207.08 NTU -71.1 mV 129.15 ft 50.00 ml/min
5/10/2023
12:33 PM 48:00 7.67 pH 17.16 °C
4,884.9
µS/cm 1.35 mg/L 179.59 NTU -69.1 mV 129.18 ft 50.00 ml/min
5/10/2023
12:36 PM 51:00 7.66 pH 17.28 °C
4,886.7
µS/cm 1.35 mg/L 163.96 NTU -67.5 mV 129.19 ft 50.00 ml/min
5/10/2023
12:39 PM 54:00 7.66 pH 17.43 °C
4,891.2
µS/cm 1.36 mg/L 151.30 NTU -66.5 mV 129.19 ft 50.00 ml/min
5/10/2023
12:42 PM
57:00 7.65 pH 17.60 °C
4,894.2
µS/cm
1.36 mg/L 140.22 NTU -66.3 mV 129.19 ft 50.00 ml/min
5/10/2023
12:45 PM
01:00:00 7.65 pH 17.65 °C
4,875.5
µS/cm
1.33 mg/L 130.86 NTU -67.1 mV 129.19 ft 50.00 ml/min
5/10/2023
12:48 PM
01:03:00 7.65 pH 17.48 °C 4,882.0
µS/cm
1.33 mg/L 120.84 NTU -66.4 mV 129.19 ft 50.00 ml/min
5/10/2023
12:51 PM
01:06:00 7.64 pH 17.73 °C 4,902.0
µS/cm
1.31 mg/L 110.89 NTU -65.1 mV 129.19 ft 50.00 ml/min
5/10/2023
12:54 PM
01:09:00 7.64 pH 17.67 °C 4,876.7
µS/cm
1.28 mg/L 103.58 NTU -66.9 mV 129.20 ft 50.00 ml/min
5/10/2023
12:57 PM
01:12:00 7.64 pH 17.53 °C 4,870.3
µS/cm
1.26 mg/L 95.36 NTU -66.9 mV 129.20 ft 50.00 ml/min
5/10/2023
1:00 PM
01:15:00 7.64 pH 17.31 °C 4,874.3
µS/cm
1.25 mg/L 92.57 NTU -67.0 mV 129.20 ft 50.00 ml/min
5/10/2023
1:03 PM
01:18:00 7.64 pH 17.43 °C 4,889.1
µS/cm
1.23 mg/L 89.33 NTU -66.8 mV 129.20 ft 50.00 ml/min
Samples
Sample ID: Description:
S-135-16-052023 Sample time 1305, 3 sample containers, VOCs 8260
S-135-16-05-2023D Duplicate of S-137-16-052023, time of 1310m 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/11/2023 11:41:39 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-136-16
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 236 ft (bgs)
Total Depth: 249.4 ft
Initial Depth to Water: 113.33 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 243.5 ft
Estimated Total Volume Pumped:
3840 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 7.44 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Windy, sunny, 58 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/11/2023
11:41 AM
00:00 7.46 pH 16.15 °C 5,019.0
µS/cm
3.58 mg/L 2.45 NTU 142.4 mV 113.33 ft 100.00 ml/min
5/11/2023
11:44 AM
03:00 7.47 pH 16.39 °C
5,101.4
µS/cm
2.81 mg/L 0.63 NTU 127.1 mV 116.28 ft 100.00 ml/min
5/11/2023
11:47 AM 06:00 7.48 pH 16.36 °C
5,097.6
µS/cm 2.18 mg/L 0.71 NTU 117.5 mV 116.67 ft 100.00 ml/min
5/11/2023
11:50 AM 09:00 7.49 pH 16.39 °C
5,097.2
µS/cm 2.09 mg/L 1.03 NTU 112.0 mV 117.20 ft 100.00 ml/min
5/11/2023
11:53 AM 12:00 7.50 pH 16.55 °C
5,098.0
µS/cm 2.11 mg/L 1.20 NTU 104.4 mV 117.50 ft 80.00 ml/min
5/11/2023
11:56 AM 15:00 7.51 pH 16.69 °C
5,112.9
µS/cm 2.14 mg/L 13.04 NTU 96.3 mV 117.78 ft 80.00 ml/min
5/11/2023
11:59 AM 18:00 7.52 pH 16.79 °C
5,105.7
µS/cm 2.17 mg/L 58.77 NTU 86.6 mV 118.13 ft 80.00 ml/min
5/11/2023
12:02 PM 21:00 7.52 pH 16.94 °C
5,114.2
µS/cm 2.23 mg/L 145.02 NTU 79.9 mV 118.48 ft 80.00 ml/min
5/11/2023
12:05 PM
24:00 7.53 pH 17.13 °C
5,115.1
µS/cm
2.21 mg/L 300.02 NTU 75.1 mV 118.77 ft 80.00 ml/min
5/11/2023
12:08 PM
27:00 7.54 pH 17.25 °C 5,104.5
µS/cm
2.12 mg/L 378.07 NTU 70.9 mV 119.11 ft 80.00 ml/min
5/11/2023
12:11 PM
30:00 7.54 pH 17.26 °C 5,122.1
µS/cm
2.09 mg/L 427.78 NTU 69.4 mV 119.37 ft 50.00 ml/min
5/11/2023
12:14 PM
33:00 7.54 pH 17.62 °C 5,138.2
µS/cm
2.12 mg/L 394.04 NTU 79.6 mV 119.60 ft 50.00 ml/min
5/11/2023
12:17 PM
36:00 7.53 pH 18.10 °C 5,151.0
µS/cm
2.14 mg/L 406.46 NTU 87.6 mV 119.79 ft 50.00 ml/min
5/11/2023
12:20 PM 39:00 7.53 pH 18.53 °C
5,148.1
µS/cm 2.14 mg/L 406.67 NTU 94.1 mV 119.98 ft 50.00 ml/min
5/11/2023
12:23 PM 42:00 7.54 pH 18.84 °C
5,135.4
µS/cm 2.13 mg/L 401.86 NTU 90.7 mV 120.16 ft 50.00 ml/min
5/11/2023
12:26 PM 45:00 7.54 pH 18.98 °C
5,133.3
µS/cm 2.16 mg/L 379.34 NTU 89.4 mV 120.32 ft 50.00 ml/min
5/11/2023
12:29 PM 48:00 7.53 pH 19.21 °C
5,143.1
µS/cm 2.21 mg/L 359.66 NTU 99.4 mV 120.48 ft 50.00 ml/min
5/11/2023
12:32 PM 51:00 7.53 pH 19.45 °C
5,140.0
µS/cm 2.20 mg/L 344.91 NTU 104.7 mV 120.63 ft 50.00 ml/min
5/11/2023
12:35 PM 54:00 7.52 pH 19.66 °C
5,143.8
µS/cm 2.24 mg/L 339.85 NTU 109.3 mV 120.77 ft 50.00 ml/min
Samples
Sample ID: Description:
S-136-16-052023 Sample time of 1240, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/8/2023 11:57:12 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-137-16
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 116 ft (bgs)
Total Depth: 128.34 ft
Initial Depth to Water: 55.24 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 72.5 ft
Estimated Total Volume Pumped:
5634.167 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 7.32 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Partly cloudy, 70 F, breezy
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/8/2023
11:57 AM
00:00 7.58 pH 17.21 °C 7,314.8
µS/cm
2.93 mg/L 5.14 NTU -88.6 mV 55.24 ft 60.00 ml/min
5/8/2023
12:00 PM
03:00 7.65 pH 16.82 °C
7,428.3
µS/cm
2.13 mg/L 263.12 NTU -106.4 mV 57.13 ft 60.00 ml/min
5/8/2023
12:03 PM 06:00 7.72 pH 15.95 °C
7,516.1
µS/cm 0.96 mg/L 2,566.2 NTU -83.5 mV 57.51 ft 60.00 ml/min
5/8/2023
12:06 PM 09:00 7.72 pH 15.95 °C
7,521.7
µS/cm 0.75 mg/L 1,965.7 NTU -80.5 mV 57.81 ft 60.00 ml/min
5/8/2023
12:09 PM 12:00 7.71 pH 16.02 °C
7,548.0
µS/cm 0.84 mg/L 1,488.5 NTU -77.0 mV 58.10 ft 60.00 ml/min
5/8/2023
12:12 PM 15:00 7.70 pH 16.60 °C
7,608.6
µS/cm 0.98 mg/L 1,266.8 NTU -78.3 mV 58.30 ft 60.00 ml/min
5/8/2023
12:15 PM 18:00 7.68 pH 17.54 °C
7,674.6
µS/cm 1.10 mg/L 802.41 NTU -72.5 mV 58.51 ft 60.00 ml/min
5/8/2023
12:18 PM 21:00 7.66 pH 18.87 °C
7,710.0
µS/cm 1.07 mg/L 884.65 NTU -70.6 mV 58.70 ft 60.00 ml/min
5/8/2023
12:21 PM
24:00 7.67 pH 18.40 °C
7,526.6
µS/cm
1.03 mg/L 791.40 NTU -82.5 mV 58.91 ft 50.00 ml/min
5/8/2023
12:24 PM
27:00 7.68 pH 18.31 °C 7,540.8
µS/cm
1.11 mg/L 592.61 NTU -79.7 mV 59.07 ft 50.00 ml/min
5/8/2023
12:27 PM
30:00 7.67 pH 18.48 °C 7,599.0
µS/cm
1.27 mg/L 471.97 NTU -70.2 mV 59.23 ft 50.00 ml/min
5/8/2023
12:30 PM
33:00 7.65 pH 19.31 °C 7,636.6
µS/cm
1.26 mg/L 457.58 NTU -67.5 mV 59.39 ft 50.00 ml/min
5/8/2023
12:33 PM
36:00 7.66 pH 19.13 °C 7,572.8
µS/cm
1.26 mg/L 404.82 NTU -75.2 mV 59.53 ft 50.00 ml/min
5/8/2023
12:36 PM 39:00 7.65 pH 19.62 °C
7,620.5
µS/cm 1.34 mg/L 364.63 NTU -72.8 mV 59.68 ft 50.00 ml/min
5/8/2023
12:39 PM 42:00 7.64 pH 20.29 °C
7,635.6
µS/cm 1.31 mg/L 297.00 NTU -69.5 mV 59.82 ft 50.00 ml/min
5/8/2023
12:42 PM 44:53 7.63 pH 20.93 °C
7,656.7
µS/cm 1.35 mg/L 300.28 NTU -69.1 mV 59.97 ft 50.00 ml/min
5/8/2023
12:45 PM 47:53 7.61 pH 21.49 °C
7,615.5
µS/cm 1.30 mg/L 263.98 NTU -65.5 mV 60.10 ft 50.00 ml/min
5/8/2023
12:48 PM 50:53 7.62 pH 21.63 °C
7,626.1
µS/cm 1.33 mg/L 206.04 NTU -72.7 mV 60.22 ft 50.00 ml/min
5/8/2023
12:51 PM 53:53 7.60 pH 22.25 °C
7,672.6
µS/cm 1.35 mg/L 178.20 NTU -75.0 mV 60.32 ft 50.00 ml/min
5/8/2023
12:54 PM
56:53 7.58 pH 23.05 °C
7,688.5
µS/cm
1.36 mg/L 164.57 NTU -77.8 mV 60.46 ft 50.00 ml/min
5/8/2023
12:57 PM
59:53 7.62 pH 24.43 °C
7,633.2
µS/cm
6.37 mg/L 486.77 NTU -84.6 mV 60.62 ft 50.00 ml/min
5/8/2023 1:00
PM
01:02:53 7.60 pH 23.64 °C 7,593.3
µS/cm
1.94 mg/L 214.04 NTU -89.9 mV 60.82 ft 50.00 ml/min
5/8/2023 1:03
PM
01:05:53 7.60 pH 22.36 °C 7,560.3
µS/cm
1.67 mg/L 135.27 NTU -93.7 mV 60.97 ft 50.00 ml/min
5/8/2023 1:06
PM
01:08:53 7.60 pH 22.13 °C 7,602.5
µS/cm
1.42 mg/L 112.26 NTU -89.1 mV 61.15 ft 50.00 ml/min
5/8/2023 1:09
PM
01:11:53 7.59 pH 22.84 °C 7,651.0
µS/cm
1.38 mg/L 84.98 NTU -87.8 mV 61.29 ft 50.00 ml/min
5/8/2023 1:12
PM
01:14:53 7.58 pH 23.61 °C 7,671.7
µS/cm
1.35 mg/L 134.80 NTU -92.2 mV 61.41 ft 50.00 ml/min
5/8/2023 1:15
PM
01:17:53 7.57 pH 24.20 °C 7,652.9
µS/cm
1.28 mg/L 71.27 NTU -89.0 mV 61.53 ft 50.00 ml/min
5/8/2023 1:18
PM
01:20:53 7.57 pH 23.29 °C
7,584.0
µS/cm
1.30 mg/L 58.53 NTU -81.2 mV 61.64 ft 50.00 ml/min
5/8/2023 1:21
PM 01:23:53 7.59 pH 21.74 °C
7,573.5
µS/cm 1.36 mg/L 60.44 NTU -88.0 mV 61.75 ft 50.00 ml/min
5/8/2023 1:24
PM 01:26:53 7.59 pH 22.46 °C
7,615.5
µS/cm 1.14 mg/L 53.58 NTU -93.4 mV 61.87 ft 50.00 ml/min
5/8/2023 1:27
PM 01:29:53 7.58 pH 23.12 °C
7,641.7
µS/cm 1.11 mg/L 52.52 NTU -91.9 mV 61.96 ft 50.00 ml/min
5/8/2023 1:30
PM 01:32:53 7.58 pH 23.02 °C
7,600.0
µS/cm 1.09 mg/L 46.06 NTU -93.4 mV 62.07 ft 50.00 ml/min
5/8/2023 1:33
PM 01:35:53 7.59 pH 21.65 °C
7,559.3
µS/cm 1.16 mg/L 44.66 NTU -90.6 mV 62.18 ft 50.00 ml/min
5/8/2023 1:36
PM 01:38:53 7.60 pH 22.19 °C
7,612.1
µS/cm 1.07 mg/L 40.17 NTU -95.5 mV 62.28 ft 50.00 ml/min
5/8/2023 1:39
PM
01:41:53 7.58 pH 22.95 °C
7,644.5
µS/cm
1.04 mg/L 37.47 NTU -95.6 mV 62.38 ft 50.00 ml/min
5/8/2023 1:42
PM
01:44:53 7.58 pH 23.63 °C
7,651.2
µS/cm
1.01 mg/L 36.34 NTU -95.7 mV 62.47 ft 50.00 ml/min
5/8/2023 1:45
PM
01:47:53 7.57 pH 24.18 °C 7,650.5
µS/cm
0.98 mg/L 37.16 NTU -94.3 mV 62.56 ft 50.00 ml/min
Samples
Sample ID: Description:
S-137-16-052023 Sample time 1350, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/8/2023 2:20:07 PM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-138-16
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 185 ft (bgs)
Total Depth: 197.7 ft
Initial Depth to Water: 49.73 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined Pump
Intake From TOC: 192.5 ft
Estimated Total Volume Pumped:
6006 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 8.29 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Partly cloudy, windy, 70 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/8/2023 2:20
PM
00:00 7.57 pH 20.19 °C 5,678.6
µS/cm
2.55 mg/L 6.95 NTU -65.6 mV 49.73 ft 60.00 ml/min
5/8/2023 2:20
PM
00:44 7.57 pH 20.06 °C
5,765.2
µS/cm
2.28 mg/L 1.51 NTU -63.8 mV 51.28 ft 60.00 ml/min
5/8/2023 2:23
PM 03:44 7.56 pH 21.10 °C
5,868.8
µS/cm 2.44 mg/L 1.39 NTU -58.5 mV 51.53 ft 60.00 ml/min
5/8/2023 2:26
PM 06:44 7.59 pH 20.24 °C
5,799.4
µS/cm 2.47 mg/L 2.31 NTU -71.8 mV 51.75 ft 60.00 ml/min
5/8/2023 2:30
PM 10:06 7.60 pH 20.86 °C
5,873.6
µS/cm 2.30 mg/L 6.90 NTU -72.3 mV 51.96 ft 50.00 ml/min
5/8/2023 2:33
PM 13:06 7.60 pH 21.85 °C
5,910.3
µS/cm 2.36 mg/L 14.20 NTU -69.7 mV 52.17 ft 50.00 ml/min
5/8/2023 2:36
PM 16:06 7.62 pH 22.80 °C
5,929.1
µS/cm 2.38 mg/L 30.52 NTU -70.0 mV 52.32 ft 50.00 ml/min
5/8/2023 2:39
PM 19:06 7.64 pH 23.34 °C
5,892.7
µS/cm 2.31 mg/L 36.05 NTU -85.3 mV 52.49 ft 50.00 ml/min
5/8/2023 2:42
PM
22:06 7.62 pH 23.16 °C
5,882.3
µS/cm
2.28 mg/L 35.34 NTU -77.8 mV 52.68 ft 50.00 ml/min
5/8/2023 2:45
PM
25:06 7.63 pH 22.98 °C 5,883.9
µS/cm
2.29 mg/L 35.04 NTU -75.7 mV 52.87 ft 50.00 ml/min
5/8/2023 2:48
PM
28:06 7.68 pH 23.47 °C 5,892.8
µS/cm
2.24 mg/L 37.23 NTU -86.9 mV 53.05 ft 50.00 ml/min
5/8/2023 2:51
PM
31:06 7.68 pH 23.42 °C 5,882.7
µS/cm
2.20 mg/L 43.48 NTU -83.7 mV 53.25 ft 50.00 ml/min
5/8/2023 2:54
PM
34:06 7.68 pH 23.33 °C 5,893.0
µS/cm
2.17 mg/L 48.02 NTU -82.6 mV 53.43 ft 50.00 ml/min
5/8/2023 2:57
PM 37:06 7.68 pH 23.38 °C
5,888.9
µS/cm 2.14 mg/L 66.30 NTU -74.9 mV 53.61 ft 50.00 ml/min
5/8/2023 3:00
PM 40:06 7.70 pH 23.42 °C
5,893.9
µS/cm 2.07 mg/L 321.17 NTU -74.0 mV 53.81 ft 50.00 ml/min
5/8/2023 3:03
PM 43:06 7.70 pH 23.44 °C
5,889.2
µS/cm 1.99 mg/L 300.17 NTU -77.5 mV 53.93 ft 50.00 ml/min
5/8/2023 3:06
PM 46:06 7.70 pH 22.89 °C
5,876.2
µS/cm 2.01 mg/L 352.66 NTU -70.4 mV 54.11 ft 50.00 ml/min
5/8/2023 3:09
PM 49:06 7.71 pH 22.45 °C
5,881.2
µS/cm 1.97 mg/L 569.16 NTU -73.4 mV 54.30 ft 50.00 ml/min
5/8/2023 3:12
PM 52:06 7.61 pH 22.16 °C
5,811.8
µS/cm 5.88 mg/L 1,246.9 NTU -49.0 mV 54.59 ft 50.00 ml/min
5/8/2023 3:15
PM
55:06 7.71 pH 21.43 °C
5,793.1
µS/cm
2.02 mg/L 528.76 NTU -76.2 mV 54.84 ft 50.00 ml/min
5/8/2023 3:18
PM
58:06 7.74 pH 19.50 °C
5,838.5
µS/cm
2.11 mg/L 260.41 NTU -83.8 mV 55.08 ft 50.00 ml/min
5/8/2023 3:21
PM
01:01:06 7.72 pH 20.11 °C 5,898.7
µS/cm
2.06 mg/L 156.53 NTU -79.2 mV 55.24 ft 50.00 ml/min
5/8/2023 3:24
PM
01:04:06 7.71 pH 20.93 °C 5,924.6
µS/cm
2.00 mg/L 163.64 NTU -73.6 mV 55.39 ft 50.00 ml/min
5/8/2023 3:27
PM
01:07:06 7.71 pH 21.57 °C 5,920.5
µS/cm
1.93 mg/L 91.91 NTU -70.9 mV 55.55 ft 50.00 ml/min
5/8/2023 3:30
PM
01:10:06 7.71 pH 22.04 °C 5,923.0
µS/cm
1.91 mg/L 114.88 NTU -72.5 mV 55.72 ft 50.00 ml/min
5/8/2023 3:33
PM
01:13:06 7.70 pH 22.42 °C 5,919.4
µS/cm
1.85 mg/L 124.69 NTU -73.7 mV 55.89 ft 50.00 ml/min
5/8/2023 3:36
PM
01:16:06 7.70 pH 22.78 °C 5,926.6
µS/cm
1.81 mg/L 115.44 NTU -77.1 mV 56.02 ft 50.00 ml/min
5/8/2023 3:39
PM
01:19:06 7.71 pH 22.98 °C
5,901.4
µS/cm
1.78 mg/L 95.20 NTU -92.5 mV 56.17 ft 50.00 ml/min
5/8/2023 3:42
PM 01:22:06 7.71 pH 21.89 °C
5,873.2
µS/cm 1.83 mg/L 89.58 NTU -81.6 mV 56.34 ft 50.00 ml/min
5/8/2023 3:45
PM 01:25:06 7.72 pH 20.88 °C
5,876.0
µS/cm 1.78 mg/L 94.76 NTU -88.0 mV 56.50 ft 50.00 ml/min
5/8/2023 3:48
PM 01:28:06 7.72 pH 21.37 °C
5,903.4
µS/cm 1.76 mg/L 72.40 NTU -87.8 mV 56.66 ft 50.00 ml/min
5/8/2023 3:51
PM 01:31:06 7.71 pH 21.85 °C
5,913.0
µS/cm 1.74 mg/L 61.34 NTU -83.7 mV 56.80 ft 50.00 ml/min
5/8/2023 3:54
PM 01:34:06 7.71 pH 22.07 °C
5,883.2
µS/cm 1.69 mg/L 64.04 NTU -97.3 mV 56.95 ft 50.00 ml/min
5/8/2023 3:57
PM 01:37:06 7.71 pH 21.47 °C
5,882.9
µS/cm 1.71 mg/L 51.66 NTU -91.4 mV 57.10 ft 50.00 ml/min
5/8/2023 4:00
PM
01:40:06 7.71 pH 21.46 °C
5,890.1
µS/cm
1.68 mg/L 45.08 NTU -98.3 mV 57.24 ft 50.00 ml/min
5/8/2023 4:03
PM
01:43:06 7.72 pH 21.62 °C
5,890.6
µS/cm
1.66 mg/L 39.51 NTU -100.1 mV 57.40 ft 50.00 ml/min
5/8/2023 4:06
PM
01:46:06 7.71 pH 21.85 °C 5,903.8
µS/cm
1.66 mg/L 36.23 NTU -97.3 mV 57.55 ft 50.00 ml/min
5/8/2023 4:09
PM
01:49:06 7.71 pH 21.95 °C 5,882.3
µS/cm
1.63 mg/L 41.27 NTU -89.7 mV 57.72 ft 50.00 ml/min
5/8/2023 4:12
PM
01:52:06 7.71 pH 21.49 °C 5,853.1
µS/cm
1.65 mg/L 215.68 NTU -86.9 mV 57.86 ft 50.00 ml/min
5/8/2023 4:15
PM
01:55:06 7.72 pH 20.64 °C 5,863.3
µS/cm
1.69 mg/L 151.73 NTU -88.9 mV 58.02 ft 50.00 ml/min
5/8/2023 4:18
PM
01:58:06 7.72 pH 20.59 °C 5,899.9
µS/cm
1.66 mg/L 129.31 NTU -95.3 mV 58.15 ft 50.00 ml/min
Samples
Sample ID: Description:
S-138-16 Sample time of 1620, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/12/2023 10:41:45 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-139-17
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 50 ft (bgs)
Total Depth: 62.38 ft
Initial Depth to Water: 54.81 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 59 ft
Estimated Total Volume Pumped:
2730.833 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 1.2 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Windy, partly cloudy, 50 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/12/2023
10:41 AM
00:00 7.27 pH 17.50 °C 10,623 µS/cm 3.06 mg/L 6,274.6 NTU 128.0 mV 54.81 ft 50.00 ml/min
5/12/2023
10:44 AM
03:00 7.23 pH 16.74 °C 10,631 µS/cm 3.29 mg/L 1,931.3 NTU 98.4 mV 55.34 ft 50.00 ml/min
5/12/2023
10:47 AM 06:00 7.19 pH 16.65 °C 10,714 µS/cm 1.71 mg/L 1,124.9 NTU 84.7 mV 55.38 ft 50.00 ml/min
5/12/2023
10:50 AM 09:00 7.18 pH 16.83 °C 10,673 µS/cm 1.84 mg/L 946.99 NTU 79.6 mV 55.43 ft 50.00 ml/min
5/12/2023
10:53 AM 12:00 7.18 pH 16.80 °C 10,617 µS/cm 1.94 mg/L 72.3 mV 55.48 ft 50.00 ml/min
5/12/2023
10:54 AM 12:37 7.17 pH 16.79 °C 10,619 µS/cm 1.95 mg/L 764.93 NTU 71.7 mV 50.00 ml/min
5/12/2023
10:57 AM 15:37 7.17 pH 16.57 °C 10,581 µS/cm 1.99 mg/L 615.19 NTU 67.9 mV 55.52 ft 50.00 ml/min
5/12/2023
11:00 AM 18:37 7.17 pH 16.46 °C 10,576 µS/cm 2.05 mg/L 478.45 NTU 66.9 mV 55.57 ft 50.00 ml/min
5/12/2023
11:03 AM
21:37 7.21 pH 15.90 °C 10,437 µS/cm 4.88 mg/L 397.02 NTU 69.7 mV 55.62 ft 50.00 ml/min
5/12/2023
11:06 AM
24:37 7.17 pH 15.80 °C 10,465 µS/cm 2.74 mg/L 238.67 NTU 66.9 mV 55.67 ft 50.00 ml/min
5/12/2023
11:09 AM
27:37 7.16 pH 15.87 °C 10,421 µS/cm 2.69 mg/L 193.27 NTU 66.9 mV 55.71 ft 50.00 ml/min
5/12/2023
11:12 AM
30:37 7.15 pH 15.83 °C 10,416 µS/cm 2.64 mg/L 152.92 NTU 66.8 mV 55.74 ft 50.00 ml/min
5/12/2023
11:15 AM
33:37 7.15 pH 15.85 °C 10,399 µS/cm 2.57 mg/L 125.01 NTU 66.7 mV 55.78 ft 50.00 ml/min
5/12/2023
11:18 AM 36:37 7.15 pH 15.65 °C 10,374 µS/cm 2.50 mg/L 99.35 NTU 66.2 mV 55.81 ft 50.00 ml/min
5/12/2023
11:21 AM 39:37 7.15 pH 15.48 °C 10,371 µS/cm 2.44 mg/L 84.44 NTU 65.5 mV 55.84 ft 50.00 ml/min
5/12/2023
11:24 AM 42:37 7.16 pH 15.37 °C 10,364 µS/cm 2.38 mg/L 82.43 NTU 64.4 mV 55.88 ft 50.00 ml/min
5/12/2023
11:27 AM 45:37 7.16 pH 15.37 °C 10,364 µS/cm 2.31 mg/L 70.94 NTU 63.2 mV 55.91 ft 50.00 ml/min
5/12/2023
11:30 AM 48:37 7.16 pH 15.32 °C 10,351 µS/cm 2.24 mg/L 63.47 NTU 62.1 mV 55.95 ft 50.00 ml/min
5/12/2023
11:33 AM 51:37 7.16 pH 15.25 °C 10,357 µS/cm 2.18 mg/L 60.61 NTU 61.1 mV 55.98 ft 50.00 ml/min
5/12/2023
11:36 AM
54:37 7.16 pH 15.27 °C 10,360 µS/cm 2.12 mg/L 57.76 NTU 60.1 mV 56.01 ft 50.00 ml/min
Samples
Sample ID: Description:
S-136-17-052023 Sample time 1140, 3 sample containers, VOCs 8260
S-139-17-05-2023D Duplicate, sample time of 1145, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/11/2023 9:38:07 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-140-17
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 195 ft
Total Depth: 200.33 ft
Initial Depth to Water: 54.34 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined Pump
Intake From TOC: 197.5 ft
Estimated Total Volume Pumped:
4740 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 80 ml/min
Final Draw Down: 1.51 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Sunny, windy, 50 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/11/2023
9:38 AM
00:00 7.00 pH 13.27 °C 6,912.4
µS/cm
7.51 mg/L 3.46 NTU 238.2 mV 54.34 ft 100.00 ml/min
5/11/2023
9:41 AM
03:00 7.19 pH 12.80 °C
7,237.4
µS/cm
3.33 mg/L 1.09 NTU 198.8 mV 55.30 ft 100.00 ml/min
5/11/2023
9:44 AM 06:00 7.25 pH 12.62 °C
7,253.4
µS/cm 2.57 mg/L 0.97 NTU 186.9 mV 55.44 ft 100.00 ml/min
5/11/2023
9:47 AM 09:00 7.27 pH 12.65 °C
7,268.3
µS/cm 2.06 mg/L 52.21 NTU 173.7 mV 55.54 ft 100.00 ml/min
5/11/2023
9:50 AM 12:00 7.28 pH 12.73 °C
7,278.4
µS/cm 1.79 mg/L 63.45 NTU 160.8 mV 55.62 ft 100.00 ml/min
5/11/2023
9:53 AM 15:00 7.29 pH 12.75 °C
7,277.0
µS/cm 1.68 mg/L 123.54 NTU 142.8 mV 55.68 ft 100.00 ml/min
5/11/2023
9:56 AM 18:00 7.30 pH 12.85 °C
7,275.0
µS/cm 1.59 mg/L 151.91 NTU 110.2 mV 55.73 ft 100.00 ml/min
5/11/2023
9:59 AM 21:00 7.31 pH 13.05 °C
7,269.9
µS/cm 1.50 mg/L 168.00 NTU 89.3 mV 55.78 ft 100.00 ml/min
5/11/2023
10:02 AM
24:00 7.32 pH 13.33 °C
7,260.4
µS/cm
1.45 mg/L 180.13 NTU 75.6 mV 55.80 ft 100.00 ml/min
5/11/2023
10:05 AM
27:00 7.33 pH 13.42 °C 7,246.3
µS/cm
1.38 mg/L 192.97 NTU 66.7 mV 55.83 ft 100.00 ml/min
5/11/2023
10:08 AM
30:00 7.33 pH 13.40 °C 7,255.4
µS/cm
1.33 mg/L 201.79 NTU 59.3 mV 55.86 ft 100.00 ml/min
5/11/2023
10:11 AM
33:00 7.35 pH 13.58 °C 7,261.1
µS/cm
1.29 mg/L 227.15 NTU 52.9 mV 55.84 ft 80.00 ml/min
5/11/2023
10:14 AM
36:00 7.35 pH 13.91 °C 7,229.2
µS/cm
1.26 mg/L 244.92 NTU 47.5 mV 55.84 ft 80.00 ml/min
5/11/2023
10:17 AM 39:00 7.36 pH 13.58 °C
7,235.2
µS/cm 1.24 mg/L 245.15 NTU 42.5 mV 55.85 ft 80.00 ml/min
5/11/2023
10:20 AM 42:00 7.37 pH 13.83 °C
7,239.1
µS/cm 1.22 mg/L 280.31 NTU 39.5 mV 55.85 ft 80.00 ml/min
5/11/2023
10:23 AM 45:00 7.37 pH 14.10 °C
7,225.5
µS/cm 1.19 mg/L 298.94 NTU 34.4 mV 55.85 ft 80.00 ml/min
5/11/2023
10:26 AM 48:00 7.37 pH 14.34 °C
7,212.8
µS/cm 1.15 mg/L 304.87 NTU 30.9 mV 55.85 ft 80.00 ml/min
5/11/2023
10:29 AM 51:00 7.39 pH 13.99 °C
7,199.8
µS/cm 1.14 mg/L 316.77 NTU 27.3 mV 55.85 ft 80.00 ml/min
Samples
Sample ID: Description:
S-149-17-052923 Sample time 1030, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/8/2023 10:08:26 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-141-17
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 65 ft (bgs)
Total Depth: 77.7 ft
Initial Depth to Water: 60.8 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 72.5 ft
Estimated Total Volume Pumped:
2523 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 60 ml/min
Final Draw Down: 3.09 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
60, clear
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/8/2023
10:08 AM
00:00 6.96 pH 15.44 °C 10,685 µS/cm 5.22 mg/L 2,116.3 NTU 204.1 mV 60.80 ft 80.00 ml/min
5/8/2023
10:11 AM
03:00 7.27 pH 14.91 °C 11,136 µS/cm 2.38 mg/L 1,180.5 NTU 203.4 mV 62.05 ft 80.00 ml/min
5/8/2023
10:14 AM 06:00 7.28 pH 15.46 °C 11,192 µS/cm 2.49 mg/L 852.36 NTU 196.6 mV 62.63 ft 80.00 ml/min
5/8/2023
10:17 AM 09:00 7.32 pH 15.65 °C 11,167 µS/cm 2.36 mg/L 703.11 NTU 186.8 mV 62.78 ft 60.00 ml/min
5/8/2023
10:20 AM 12:00 7.33 pH 15.09 °C 11,140 µS/cm 2.20 mg/L 623.60 NTU 165.6 mV 62.94 ft 60.00 ml/min
5/8/2023
10:23 AM 15:00 7.32 pH 15.29 °C 11,173 µS/cm 2.05 mg/L 503.12 NTU 158.3 mV 63.10 ft 60.00 ml/min
5/8/2023
10:26 AM 18:00 7.33 pH 15.78 °C 11,147 µS/cm 1.91 mg/L 415.15 NTU 123.7 mV 63.21 ft 60.00 ml/min
5/8/2023
10:29 AM 21:03 7.32 pH 15.58 °C 11,129 µS/cm 1.66 mg/L 373.44 NTU 86.2 mV 63.39 ft 60.00 ml/min
5/8/2023
10:32 AM
24:03 7.31 pH 15.92 °C 11,113 µS/cm 1.55 mg/L 346.06 NTU 94.5 mV 63.52 ft 60.00 ml/min
5/8/2023
10:35 AM
27:03 7.32 pH 16.21 °C 11,091 µS/cm 1.46 mg/L 296.78 NTU 87.2 mV 63.62 ft 60.00 ml/min
5/8/2023
10:38 AM
30:03 7.33 pH 16.32 °C 11,063 µS/cm 1.39 mg/L 317.95 NTU 72.7 mV 63.72 ft 60.00 ml/min
5/8/2023
10:41 AM
33:03 7.34 pH 16.54 °C 11,038 µS/cm 1.31 mg/L 275.90 NTU 62.1 mV 63.79 ft 60.00 ml/min
5/8/2023
10:44 AM
36:03 7.34 pH 16.71 °C 11,021 µS/cm 1.27 mg/L 278.10 NTU 56.2 mV 63.85 ft 60.00 ml/min
5/8/2023
10:47 AM 39:03 7.34 pH 16.84 °C 10,995 µS/cm 1.25 mg/L 272.13 NTU 52.7 mV 63.89 ft 60.00 ml/min
Samples
Sample ID: Description:
S-141-17-052023 Sample time10:50, 3 sample, containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/9/2023 9:55:41 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-142-17
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 200 ft (bgs)
Total Depth: 212.4 ft
Initial Depth to Water: 30.59 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 207.5 ft
Estimated Total Volume Pumped:
4750.833 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 50 ml/min
Final Draw Down: 3.37 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
48 F, windy, partly cloudy
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/9/2023 9:55
AM 00:00 7.43 pH 13.68 °C
1,981.9
µS/cm 4.81 mg/L 5.10 NTU -139.6 mV 30.59 ft 50.00 ml/min
5/9/2023 9:58
AM 03:00 7.61 pH 13.43 °C
2,242.2
µS/cm 3.00 mg/L 3.83 NTU -189.0 mV 33.38 ft 50.00 ml/min
5/9/2023
10:01 AM 06:00 7.63 pH 13.48 °C
2,698.6
µS/cm 2.34 mg/L 4.06 NTU -199.3 mV 33.47 ft 50.00 ml/min
5/9/2023
10:02 AM 06:36 7.63 pH 13.50 °C
2,893.1
µS/cm 2.31 mg/L 3.67 NTU -200.6 mV 33.47 ft 50.00 ml/min
5/9/2023
10:05 AM 09:36 7.62 pH 13.59 °C
3,726.7
µS/cm 1.97 mg/L 3.39 NTU -213.0 mV 33.62 ft 50.00 ml/min
5/9/2023
10:08 AM 12:36 7.62 pH 13.83 °C
4,392.5
µS/cm 1.43 mg/L 3.40 NTU -222.4 mV 33.70 ft 50.00 ml/min
5/9/2023
10:11 AM 15:36 7.60 pH 14.03 °C
5,710.7
µS/cm 1.17 mg/L 2.82 NTU -227.9 mV 33.78 ft 50.00 ml/min
5/9/2023
10:14 AM
18:36 7.60 pH 14.22 °C
7,387.6
µS/cm
0.98 mg/L 2.19 NTU -233.4 mV 33.83 ft 50.00 ml/min
5/9/2023
10:17 AM
21:36 7.60 pH 14.37 °C 8,607.2
µS/cm
0.75 mg/L 2.00 NTU -239.6 mV 33.87 ft 50.00 ml/min
5/9/2023
10:18 AM
23:01 7.59 pH 14.31 °C 9,080.5
µS/cm
0.66 mg/L 1.87 NTU -243.6 mV 33.88 ft 50.00 ml/min
5/9/2023
10:21 AM
26:01 7.60 pH 14.42 °C 9,884.9
µS/cm
0.54 mg/L 1.80 NTU -251.7 mV 33.90 ft 50.00 ml/min
5/9/2023
10:24 AM
29:01 7.60 pH 14.50 °C 10,535 µS/cm 0.48 mg/L 4.49 NTU -259.3 mV 33.91 ft 50.00 ml/min
5/9/2023
10:27 AM
32:01 7.61 pH 14.67 °C 11,036 µS/cm 0.43 mg/L 15.75 NTU -263.1 mV 33.92 ft 50.00 ml/min
5/9/2023
10:30 AM 35:01 7.62 pH 14.76 °C 11,425 µS/cm 0.40 mg/L 30.40 NTU -263.0 mV 33.93 ft 50.00 ml/min
5/9/2023
10:33 AM 38:01 7.63 pH 14.81 °C 11,752 µS/cm 0.42 mg/L 41.31 NTU -259.8 mV 33.93 ft 50.00 ml/min
5/9/2023
10:36 AM 41:01 7.63 pH 15.04 °C 11,985 µS/cm 0.45 mg/L 49.95 NTU -254.7 mV 33.94 ft 50.00 ml/min
5/9/2023
10:39 AM 44:01 7.65 pH 14.91 °C 12,151 µS/cm 0.50 mg/L 55.13 NTU -247.1 mV 33.94 ft 50.00 ml/min
5/9/2023
10:42 AM 47:01 7.67 pH 14.79 °C 12,282 µS/cm 0.58 mg/L 59.12 NTU -238.0 mV 33.94 ft 50.00 ml/min
5/9/2023
10:45 AM 50:01 7.69 pH 14.59 °C 12,383 µS/cm 0.69 mg/L 59.06 NTU -227.9 mV 33.95 ft 50.00 ml/min
5/9/2023
10:48 AM
53:01 7.69 pH 14.55 °C 12,461 µS/cm 0.79 mg/L 59.33 NTU -215.0 mV 33.95 ft 50.00 ml/min
5/9/2023
10:51 AM
56:01 7.70 pH 14.64 °C 12,533 µS/cm 0.93 mg/L 56.23 NTU -202.8 mV 33.95 ft 50.00 ml/min
5/9/2023
10:54 AM
59:01 7.71 pH 14.83 °C 12,620 µS/cm 1.25 mg/L 57.85 NTU -191.2 mV 33.95 ft 50.00 ml/min
5/9/2023
10:57 AM
01:02:01 7.71 pH 15.21 °C 12,702 µS/cm 1.42 mg/L 54.52 NTU -181.5 mV 33.96 ft 50.00 ml/min
5/9/2023
11:00 AM
01:05:01 7.71 pH 15.50 °C 12,752 µS/cm 1.49 mg/L 49.77 NTU -173.0 mV 33.96 ft 50.00 ml/min
5/9/2023
11:03 AM
01:08:01 7.69 pH 15.37 °C 12,772 µS/cm 1.46 mg/L 49.08 NTU -164.7 mV 33.96 ft 50.00 ml/min
5/9/2023
11:06 AM
01:11:01 7.70 pH 15.39 °C 12,820 µS/cm 1.51 mg/L 47.51 NTU -158.2 mV 33.96 ft 50.00 ml/min
5/9/2023
11:09 AM
01:14:01 7.70 pH 15.47 °C 12,873 µS/cm 1.56 mg/L 39.64 NTU -152.1 mV 33.96 ft 50.00 ml/min
5/9/2023
11:12 AM
01:17:01 7.70 pH 15.63 °C 12,916 µS/cm 1.67 mg/L 35.42 NTU -147.0 mV 33.96 ft 50.00 ml/min
5/9/2023
11:15 AM 01:20:01 7.69 pH 15.89 °C 12,970 µS/cm 1.73 mg/L 35.98 NTU -142.2 mV 33.96 ft 50.00 ml/min
5/9/2023
11:18 AM 01:23:01 7.69 pH 16.20 °C 13,019 µS/cm 1.73 mg/L 32.55 NTU -138.0 mV 33.96 ft 50.00 ml/min
5/9/2023
11:21 AM 01:26:01 7.68 pH 16.23 °C 13,034 µS/cm 1.72 mg/L 32.23 NTU -134.5 mV 33.96 ft 50.00 ml/min
5/9/2023
11:24 AM 01:29:01 7.69 pH 16.36 °C 13,072 µS/cm 1.72 mg/L 27.73 NTU -129.5 mV 33.96 ft 50.00 ml/min
5/9/2023
11:27 AM 01:32:01 7.69 pH 16.41 °C 13,102 µS/cm 1.73 mg/L 26.38 NTU -128.6 mV 33.96 ft 50.00 ml/min
5/9/2023
11:30 AM 01:35:01 7.68 pH 16.25 °C 13,145 µS/cm 1.74 mg/L 25.62 NTU -122.0 mV 33.96 ft 50.00 ml/min
Samples
Sample ID: Description:
S-142-17-052023 Sample time 1135, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/15/2023 10:09:06 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S13-CAM-DW1
Well Diameter: 2 in
Casing Type: PVC
Screen Length: 5 ft
Top of Screen: 54 ft (bgs)
Total Depth: 61.7 ft
Initial Depth to Water: 15.08 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 59 ft
Estimated Total Volume Pumped:
12300 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 150 ml/min
Final Draw Down: 0.12 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Sunny, 60 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/15/2023
10:09 AM
00:00 7.19 pH 16.75 °C 19,894 µS/cm 5.44 mg/L 40.33 NTU 244.1 mV 15.08 ft 100.00 ml/min
5/15/2023
10:12 AM
03:00 7.26 pH 15.71 °C 20,917 µS/cm 1.48 mg/L 7,589.9 NTU 229.7 mV 15.18 ft 100.00 ml/min
5/15/2023
10:15 AM 06:00 7.25 pH 15.42 °C 20,887 µS/cm 0.83 mg/L 4,621.9 NTU 225.7 mV 15.20 ft 150.00 ml/min
5/15/2023
10:18 AM 09:00 7.25 pH 15.37 °C 20,933 µS/cm 0.65 mg/L 2,005.9 NTU 197.0 mV 15.20 ft 150.00 ml/min
5/15/2023
10:21 AM 12:00 7.26 pH 15.09 °C 20,963 µS/cm 0.58 mg/L 1,503.9 NTU 174.9 mV 15.20 ft 150.00 ml/min
5/15/2023
10:24 AM 15:00 7.27 pH 15.06 °C 21,062 µS/cm 0.52 mg/L 1,225.3 NTU 161.2 mV 15.20 ft 150.00 ml/min
5/15/2023
10:27 AM 18:00 7.27 pH 15.16 °C 21,060 µS/cm 0.46 mg/L 1,081.2 NTU 157.2 mV 15.20 ft 150.00 ml/min
5/15/2023
10:30 AM 21:00 7.28 pH 15.24 °C 20,976 µS/cm 0.43 mg/L 1,045.3 NTU 152.3 mV 15.20 ft 150.00 ml/min
5/15/2023
10:33 AM
24:00 7.28 pH 15.09 °C 21,026 µS/cm 0.38 mg/L 779.73 NTU 145.4 mV 15.20 ft 150.00 ml/min
5/15/2023
10:36 AM
27:00 7.28 pH 15.19 °C 21,087 µS/cm 0.35 mg/L 1,101.8 NTU 139.2 mV 15.20 ft 150.00 ml/min
5/15/2023
10:39 AM
30:00 7.27 pH 15.19 °C 21,098 µS/cm 0.31 mg/L 1,417.6 NTU 139.4 mV 15.20 ft 150.00 ml/min
5/15/2023
10:42 AM
33:00 7.27 pH 15.06 °C 21,158 µS/cm 0.29 mg/L 1,829.5 NTU 144.6 mV 15.20 ft 150.00 ml/min
5/15/2023
10:45 AM
36:00 7.27 pH 15.19 °C 21,052 µS/cm 0.28 mg/L 2,507.2 NTU 149.6 mV 15.20 ft 150.00 ml/min
5/15/2023
10:48 AM 39:00 7.27 pH 15.23 °C 21,041 µS/cm 0.27 mg/L 3,377.3 NTU 153.7 mV 15.20 ft 150.00 ml/min
5/15/2023
10:51 AM 42:00 7.27 pH 15.30 °C 21,297 µS/cm 0.26 mg/L 3,456.5 NTU 156.9 mV 15.20 ft 150.00 ml/min
5/15/2023
10:54 AM 45:00 7.26 pH 15.41 °C 21,177 µS/cm 0.26 mg/L 2,578.1 NTU 136.4 mV 15.20 ft 150.00 ml/min
5/15/2023
10:57 AM 48:00 7.26 pH 15.45 °C 21,147 µS/cm 0.25 mg/L 1,475.6 NTU 104.1 mV 15.20 ft 150.00 ml/min
5/15/2023
11:00 AM 51:00 7.26 pH 15.39 °C 21,205 µS/cm 0.24 mg/L 1,046.1 NTU 93.0 mV 15.20 ft 150.00 ml/min
5/15/2023
11:03 AM 54:00 7.26 pH 15.38 °C 21,076 µS/cm 0.23 mg/L 750.60 NTU 84.6 mV 15.20 ft 150.00 ml/min
5/15/2023
11:06 AM
57:00 7.26 pH 15.18 °C 21,386 µS/cm 0.23 mg/L 1,343.9 NTU 82.4 mV 15.20 ft 150.00 ml/min
5/15/2023
11:09 AM
01:00:00 7.26 pH 15.17 °C 21,526 µS/cm 0.22 mg/L 827.23 NTU 78.2 mV 15.20 ft 150.00 ml/min
5/15/2023
11:12 AM
01:03:00 7.26 pH 15.16 °C 21,595 µS/cm 0.21 mg/L 1,089.0 NTU 76.6 mV 15.20 ft 150.00 ml/min
5/15/2023
11:15 AM
01:06:00 7.26 pH 15.36 °C 21,647 µS/cm 0.21 mg/L 1,658.5 NTU 81.5 mV 15.20 ft 150.00 ml/min
5/15/2023
11:18 AM
01:09:00 7.26 pH 15.50 °C 21,673 µS/cm 0.22 mg/L 2,026.3 NTU 85.1 mV 15.20 ft 150.00 ml/min
5/15/2023
11:21 AM
01:12:00 7.26 pH 15.06 °C 21,665 µS/cm 0.20 mg/L 1,470.0 NTU 84.0 mV 15.20 ft 150.00 ml/min
5/15/2023
11:24 AM
01:15:00 7.26 pH 15.16 °C 21,798 µS/cm 0.17 mg/L 2,316.9 NTU 84.4 mV 15.20 ft 150.00 ml/min
5/15/2023
11:27 AM
01:18:00 7.26 pH 15.10 °C 21,691 µS/cm 0.15 mg/L 2,770.7 NTU 90.8 mV 15.20 ft 150.00 ml/min
5/15/2023
11:30 AM
01:21:00 7.25 pH 15.26 °C 21,791 µS/cm 0.15 mg/L 2,807.1 NTU 94.0 mV 15.20 ft 150.00 ml/min
5/15/2023
11:33 AM 01:24:00 7.25 pH 15.27 °C 21,696 µS/cm 0.14 mg/L 2,571.4 NTU 95.9 mV 15.20 ft 150.00 ml/min
Samples
Sample ID: Description:
S13-CAM-DW1-052023 With MS/MSD, sample time 1135, 15 sample containers, VOCs 8260 and TPH-DRO 8015D
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/16/2023 8:43:32 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-55-90
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 8 ft bgs
Total Depth: 20.97 ft
Initial Depth to Water: 11.52 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 15.5 ft
Estimated Total Volume Pumped:
4800 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 160 ml/min
Final Draw Down: 0.05 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
58 some clouds
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/16/2023
8:43 AM
00:00 7.14 pH 14.78 °C 10,654 µS/cm 7.61 mg/L 12.62 NTU 187.6 mV 11.52 ft 160.00 ml/min
5/16/2023
8:46 AM
03:00 7.29 pH 13.00 °C 11,276 µS/cm 5.29 mg/L 1.54 NTU 181.4 mV 11.56 ft 160.00 ml/min
5/16/2023
8:49 AM 06:00 7.29 pH 12.83 °C 11,256 µS/cm 5.31 mg/L 1.68 NTU 155.3 mV 11.57 ft 160.00 ml/min
5/16/2023
8:52 AM 09:00 7.29 pH 12.85 °C 11,077 µS/cm 5.54 mg/L 1.60 NTU 139.4 mV 11.57 ft 160.00 ml/min
5/16/2023
8:55 AM 12:00 7.28 pH 12.86 °C 10,894 µS/cm 5.77 mg/L 1.49 NTU 130.8 mV 11.57 ft 160.00 ml/min
5/16/2023
8:58 AM 15:00 7.27 pH 12.86 °C 10,762 µS/cm 5.88 mg/L 1.76 NTU 122.9 mV 11.57 ft 160.00 ml/min
5/16/2023
9:01 AM 18:00 7.27 pH 12.89 °C 10,670 µS/cm 5.97 mg/L 1.98 NTU 116.4 mV 11.57 ft 160.00 ml/min
5/16/2023
9:04 AM 21:00 7.27 pH 12.88 °C 10,581 µS/cm 6.04 mg/L 2.90 NTU 109.8 mV 11.57 ft 160.00 ml/min
5/16/2023
9:07 AM
24:00 7.27 pH 12.84 °C 10,498 µS/cm 6.07 mg/L 3.52 NTU 104.5 mV 11.57 ft 160.00 ml/min
5/16/2023
9:10 AM
27:00 7.27 pH 12.89 °C 10,410 µS/cm 6.14 mg/L 4.36 NTU 98.2 mV 11.57 ft 160.00 ml/min
5/16/2023
9:13 AM
30:00 7.27 pH 12.93 °C 10,326 µS/cm 6.17 mg/L 6.73 NTU 95.9 mV 11.57 ft 160.00 ml/min
Samples
Sample ID: Description:
S-55-90-052023 Sample time 1915 5 sample containers, VOCs 8250, TPH-DRO 8015
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/16/2023 10:18:21 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-78-91
Well Diameter: 4 in
Casing Type: PVD
Screen Length: 15 ft
Top of Screen: 7.7 ft bgs
Total Depth: 24.9 ft
Initial Depth to Water: 12.53 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 18.9 ft
Estimated Total Volume Pumped:
7200 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 160 ml/min
Final Draw Down: 0.02 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
65 clear
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/16/2023
10:18 AM
00:00 7.31 pH 18.16 °C 8,622.4
µS/cm
2.95 mg/L 8.01 NTU 149.2 mV 12.53 ft 160.00 ml/min
5/16/2023
10:21 AM
03:00 7.31 pH 14.20 °C
9,205.8
µS/cm
0.62 mg/L 3.51 NTU 118.7 mV 12.55 ft 160.00 ml/min
5/16/2023
10:24 AM 06:00 7.31 pH 13.72 °C
9,377.0
µS/cm 0.45 mg/L 2.70 NTU 98.9 mV 12.55 ft 160.00 ml/min
5/16/2023
10:27 AM 09:00 7.31 pH 13.47 °C
9,468.3
µS/cm 0.36 mg/L 2.48 NTU 87.7 mV 12.55 ft 160.00 ml/min
5/16/2023
10:30 AM 12:00 7.31 pH 13.55 °C
9,513.5
µS/cm 0.29 mg/L 2.58 NTU 80.1 mV 12.55 ft 160.00 ml/min
5/16/2023
10:33 AM 15:00 7.32 pH 13.56 °C
9,545.9
µS/cm 0.24 mg/L 2.14 NTU 74.2 mV 12.55 ft 160.00 ml/min
5/16/2023
10:36 AM 18:00 7.32 pH 13.62 °C
9,594.5
µS/cm 0.21 mg/L 2.24 NTU 68.0 mV 12.55 ft 160.00 ml/min
5/16/2023
10:39 AM 21:00 7.33 pH 13.56 °C
9,604.6
µS/cm 0.18 mg/L 1.60 NTU 62.3 mV 12.55 ft 160.00 ml/min
5/16/2023
10:42 AM
24:00 7.33 pH 13.73 °C
9,639.9
µS/cm
0.16 mg/L 1.45 NTU 58.0 mV 12.55 ft 160.00 ml/min
5/16/2023
10:45 AM
27:00 7.33 pH 13.76 °C 9,687.2
µS/cm
0.15 mg/L 1.66 NTU 54.6 mV 12.55 ft 160.00 ml/min
5/16/2023
10:48 AM
30:00 7.33 pH 13.69 °C 9,700.7
µS/cm
0.13 mg/L 1.48 NTU 52.0 mV 12.55 ft 160.00 ml/min
5/16/2023
10:51 AM
33:00 7.34 pH 13.51 °C 9,741.7
µS/cm
0.12 mg/L 1.31 NTU 49.3 mV 12.55 ft 160.00 ml/min
5/16/2023
10:54 AM
36:00 7.34 pH 13.92 °C 9,790.3
µS/cm
0.11 mg/L 1.37 NTU 46.5 mV 12.55 ft 160.00 ml/min
5/16/2023
10:57 AM 39:00 7.34 pH 14.01 °C
9,797.0
µS/cm 0.10 mg/L 1.30 NTU 44.1 mV 12.55 ft 160.00 ml/min
5/16/2023
11:00 AM 42:00 7.34 pH 14.07 °C
9,836.0
µS/cm 0.10 mg/L 1.06 NTU 41.8 mV 12.55 ft 160.00 ml/min
5/16/2023
11:03 AM 45:00 7.34 pH 14.05 °C
9,861.2
µS/cm 0.09 mg/L 1.11 NTU 40.0 mV 12.55 ft 160.00 ml/min
Samples
Sample ID: Description:
S-78-91-052023 Sample time 1105, 5 sample containers, VOCs 8250, TPH-DRO 8015
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/15/2023 1:02:32 PM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-91-91
Well Diameter: 4.5 in
Casing Type: PVC
Screen Length: 20 ft
Top of Screen: 3.7 ft (bgs)
Total Depth: 25.93 ft
Initial Depth to Water: 11.18 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 18.2 ft
Estimated Total Volume Pumped:
3840 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 160 ml/min
Final Draw Down: 0.03 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Sunny, clear, 70 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/15/2023
1:02 PM
00:00 7.16 pH 17.75 °C 16,214 µS/cm 3.16 mg/L 16.09 NTU 179.7 mV 11.18 ft 160.00 ml/min
5/15/2023
1:05 PM
03:00 7.09 pH 15.20 °C 17,419 µS/cm 0.57 mg/L 0.58 NTU 174.7 mV 11.20 ft 160.00 ml/min
5/15/2023
1:08 PM 06:00 7.09 pH 15.06 °C 17,676 µS/cm 0.42 mg/L 0.57 NTU 158.9 mV 11.21 ft 160.00 ml/min
5/15/2023
1:11 PM 09:00 7.10 pH 14.94 °C 17,641 µS/cm 0.35 mg/L 0.53 NTU 145.0 mV 11.21 ft 160.00 ml/min
5/15/2023
1:14 PM 12:00 7.11 pH 14.84 °C 17,550 µS/cm 0.32 mg/L 0.64 NTU 135.1 mV 11.21 ft 160.00 ml/min
5/15/2023
1:17 PM 15:00 7.11 pH 14.98 °C 17,541 µS/cm 0.31 mg/L 0.52 NTU 127.6 mV 11.21 ft 160.00 ml/min
5/15/2023
1:20 PM 18:00 7.12 pH 15.09 °C 17,524 µS/cm 0.31 mg/L 0.47 NTU 121.7 mV 11.21 ft 160.00 ml/min
5/15/2023
1:23 PM 21:00 7.12 pH 15.10 °C 17,474 µS/cm 0.31 mg/L 0.50 NTU 117.1 mV 11.21 ft 160.00 ml/min
5/15/2023
1:26 PM
24:00 7.13 pH 15.00 °C 17,418 µS/cm 0.30 mg/L 0.48 NTU 112.3 mV 11.21 ft 160.00 ml/min
Samples
Sample ID: Description:
S-91-91-052023 Sample time 1330, 5 sample containers, VOCs 8250, TPH-DRO 8015
S-91-91-05-2023D Duplicate Sample time 1335, 5 sample containers, VOCs 8250, TPH-DRO 8015
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/17/2023 9:30:37 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-38-90
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 20 ft
Top of Screen: 210.50 ft (bgs)
Total Depth: 233.59 ft
Initial Depth to Water: 213.27 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 232 ft
Estimated Total Volume Pumped:
6540 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 200 ml/min
Final Draw Down: 0.09 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Sunny, clear, 62 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/17/2023
9:30 AM
00:00 7.51 pH 14.47 °C 1,607.8
µS/cm
8.49 mg/L 0.67 NTU 209.1 mV 213.27 ft 200.00 ml/min
5/17/2023
9:33 AM
03:00 7.85 pH 13.30 °C
1,594.4
µS/cm
8.88 mg/L 0.29 NTU 208.3 mV 213.34 ft 200.00 ml/min
5/17/2023
9:36 AM 06:00 7.63 pH 13.05 °C
1,609.2
µS/cm 8.89 mg/L 0.38 NTU 209.7 mV 213.35 ft 200.00 ml/min
5/17/2023
9:39 AM 09:00 7.45 pH 12.98 °C
1,607.4
µS/cm 9.12 mg/L 10.30 NTU 204.4 mV 213.36 ft 200.00 ml/min
5/17/2023
9:42 AM 12:00 7.54 pH 12.87 °C
1,684.8
µS/cm 9.73 mg/L 12.25 NTU 113.9 mV 213.36 ft 200.00 ml/min
5/17/2023
9:45 AM 14:33 7.61 pH 12.73 °C
1,688.9
µS/cm 10.04 mg/L 0.98 NTU 89.8 mV 213.36 ft 200.00 ml/min
5/17/2023
9:48 AM 17:42 7.63 pH 12.74 °C
1,677.2
µS/cm 10.10 mg/L 0.64 NTU 90.4 mV 213.36 ft 200.00 ml/min
5/17/2023
9:51 AM 20:42 7.65 pH 12.71 °C
1,641.2
µS/cm 10.25 mg/L 5.11 NTU 101.3 mV 213.36 ft 200.00 ml/min
5/17/2023
9:54 AM
23:42 7.65 pH 12.75 °C
1,616.0
µS/cm
10.21 mg/L 22.82 NTU 110.7 mV 213.36 ft 200.00 ml/min
5/17/2023
9:57 AM
26:42 7.64 pH 12.72 °C 1,595.2
µS/cm
10.02 mg/L 56.47 NTU 117.4 mV 213.36 ft 200.00 ml/min
5/17/2023
10:00 AM
29:42 7.64 pH 12.77 °C 1,582.6
µS/cm
10.15 mg/L 163.42 NTU 117.3 mV 213.36 ft 200.00 ml/min
5/17/2023
10:03 AM
32:42 7.64 pH 12.75 °C 1,587.9
µS/cm
10.19 mg/L 0.37 NTU 119.9 mV 213.36 ft 200.00 ml/min
Samples
Sample ID: Description:
S-38-90-052023 Sample time 1005, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/17/2023 11:29:54 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-40-90
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 20 ft
Top of Screen: 251 ft (bgs)
Total Depth: 271.85 ft
Initial Depth to Water: 247.71 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 270 ft
Estimated Total Volume Pumped:
3600 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 200 ml/min
Final Draw Down: 0.14 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Sunny, clear, 70 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/17/2023
11:29 AM
00:00 7.74 pH 16.13 °C 896.32 µS/cm 8.16 mg/L 1.80 NTU 109.2 mV 247.71 ft 200.00 ml/min
5/17/2023
11:32 AM
03:00 7.36 pH 14.72 °C 907.86 µS/cm 7.99 mg/L 1.43 NTU 123.1 mV 247.85 ft 200.00 ml/min
5/17/2023
11:35 AM 06:00 7.33 pH 14.47 °C 907.30 µS/cm 7.69 mg/L 0.31 NTU 126.9 mV 247.85 ft 200.00 ml/min
5/17/2023
11:38 AM 09:00 7.42 pH 14.32 °C 904.82 µS/cm 7.98 mg/L 2.48 NTU 127.3 mV 247.85 ft 200.00 ml/min
5/17/2023
11:41 AM 12:00 7.54 pH 14.08 °C 906.78 µS/cm 8.86 mg/L 4.72 NTU 127.3 mV 247.85 ft 200.00 ml/min
5/17/2023
11:44 AM 15:00 7.58 pH 13.78 °C 910.34 µS/cm 9.35 mg/L 0.67 NTU 128.3 mV 247.85 ft 200.00 ml/min
5/17/2023
11:47 AM 18:00 7.59 pH 14.06 °C 912.79 µS/cm 9.51 mg/L 0.60 NTU 129.3 mV 247.85 ft 200.00 ml/min
Samples
Sample ID: Description:
S-40-90-052023 Sample time 1150, 3 sample containers, VOCs 8260
S-40-90-95-2923D Duplicate sample, sample time 1155, 3 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.
Low-Flow Test Report:
Test Date / Time: 5/17/2023 10:28:36 AM
Project: TEAD-S
Operator Name: CMH/SC
Location Name: S-150-20
Well Diameter: 4 in
Casing Type: PVC
Screen Length: 10 ft
Top of Screen: 291 ft (bgs)
Total Depth: 303.4 ft
Initial Depth to Water: 246.44 ft
Pump Type: GEOSUB
Tubing Type: Teflon lined
Pump Intake From TOC: 302 ft
Estimated Total Volume Pumped:
6600 ml
Flow Cell Volume: 130 ml
Final Flow Rate: 200 ml/min
Final Draw Down: 0.11 ft
Instrument Used: Aqua TROLL 500
Serial Number: 844514
Test Notes:
Weather Conditions:
Sunny, clear, 65 F
Low-Flow Readings:
Date Time Elapsed Time pH Temperature Specific
Conductivity
RDO
Concentration
Turbidity ORP Depth to
Water
Flow
+/- 0.1 +/- 3 %+/- 3 %+/- 10 %+/- 10 %+/- 10 +/- 0.3
5/17/2023
10:28 AM
00:00 7.85 pH 14.49 °C 2,247.1
µS/cm
8.44 mg/L 0.74 NTU 162.1 mV 246.44 ft 200.00 ml/min
5/17/2023
10:31 AM
03:00 7.78 pH 13.90 °C
2,288.7
µS/cm
8.76 mg/L 0.38 NTU 166.8 mV 246.55 ft 200.00 ml/min
5/17/2023
10:34 AM 06:00 7.62 pH 13.79 °C
2,333.5
µS/cm 8.68 mg/L 0.36 NTU 171.3 mV 246.55 ft 200.00 ml/min
5/17/2023
10:37 AM 09:00 7.49 pH 13.70 °C
2,343.0
µS/cm 8.62 mg/L 5.25 NTU 175.5 mV 246.55 ft 200.00 ml/min
5/17/2023
10:40 AM 12:00 7.06 pH 13.59 °C
2,379.6
µS/cm 7.43 mg/L 228.37 NTU -16.1 mV 246.55 ft 200.00 ml/min
5/17/2023
10:43 AM 15:00 6.99 pH 13.44 °C
2,269.3
µS/cm 7.86 mg/L 94.46 NTU -16.2 mV 246.55 ft 200.00 ml/min
5/17/2023
10:46 AM 18:00 7.24 pH 13.46 °C
2,205.3
µS/cm 8.57 mg/L 7.81 NTU -4.5 mV 246.55 ft 200.00 ml/min
5/17/2023
10:49 AM 21:00 7.33 pH 13.50 °C
2,194.3
µS/cm 8.81 mg/L 1.38 NTU 22.6 mV 246.55 ft 200.00 ml/min
5/17/2023
10:52 AM
24:00 7.35 pH 13.34 °C
2,184.1
µS/cm
8.89 mg/L 1.70 NTU 45.7 mV 246.55 ft 200.00 ml/min
5/17/2023
10:55 AM
27:00 7.35 pH 13.44 °C 2,181.7
µS/cm
8.95 mg/L 3.73 NTU 55.0 mV 246.55 ft 200.00 ml/min
5/17/2023
10:58 AM
30:00 7.35 pH 13.31 °C 2,185.1
µS/cm
9.02 mg/L 7.30 NTU 59.3 mV 246.55 ft 200.00 ml/min
5/17/2023
11:01 AM
33:00 7.35 pH 13.29 °C 2,184.3
µS/cm
9.13 mg/L 0.40 NTU 62.5 mV 246.55 ft 200.00 ml/min
Samples
Sample ID: Description:
S-150-20-052023 With MS/MSD, sample time of 1105, 9 sample containers, VOCs 8260
Created using VuSitu from In-Situ, Inc.

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APPENDIX D
WASTE DOCUMENTATION

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Brice Engineering, LLC

Salt Lake City Office
362 Pierpont Avenue
Salt Lake City, Utah 84101
801-948-9319 PH
www.BriceEng.com

Page 1 of 2
June 15, 2023
Tooele Army Depot-South Area
Attn: Troy Johnson
JMTE-GME-ENV, Bldg 5119
1 Tooele Army Depot
Tooele, UT 84074-5000
Subject: Results and Recommendations for Waste Disposal of Purge and Decontamination Water for
Multiple Sites at Tooele Army Depot-South
Dear Mr. Johnson:
Investigation-derived waste (IDW) in the form of well purge water and decontamination water was
generated during the May 2023 annual sampling event at Tooele Army Depot-South (TEAD-S) Solid
Waste Management Units (SWMUs) 1/25, 13, and 26. This letter provides a summary of the analytical
results for each SWMU and recommendations for waste disposal.

Liquid IDW generated during the annual sampling event in May 2023 was containerized separately
based on the SWMU in which it was generated and is currently stored in a common location at a secured
TEAD-S warehouse. In total, approximately 44 gallons of IDW were generated at SWMUs 1/25, 7 gallons,
13 gallons at SWMU 13, and 6 gallons at SWMU 26.

Recommendations for waste disposal are based on direct comparison of the analytical sample results
from May 2023 event to the United States Environmental Protection Agency regulatory levels for
hazardous waste. Unvalidated maximum detected concentrations from the May 2023 samples are
presented in Table 1 for each SWMU along with applicable regulatory levels. Carbon tetrachloride
exceeded the regulatory levels at well S-139-17 at SWMU25, no other compounds exceeded regulatory
levels in any SWMU. The waste is known to be predominately water; therefore, generator’s reasonable
knowledge was used to exclude the characteristics of ignitability, reactivity and corrosivity.

The liquid IDW generated at monitoring well S-139-17 at SWMU 25 exceeded the regulatory levels for
carbon tetrachloride and is considered hazardous waste. The approximately 2 gallons of liquid IDW
from monitoring well S-139-17 will be manifested and transported to be disposed of offsite at a
permitted facility.

It is recommended that the remaining liquid IDW generated during the 2023 annual sampling event be
disposed of based on the environmental sample results, and as such, be considered as non-hazardous. It
is recommended that the IDW be poured into a manhole marked “sewer” along Montgomery Road that
is upstream of the water treatment facility at TEAD-S or at an alternative onsite location provided by
TEAD-S. This recommended disposition for liquid IDW drums is pending TEAD-S approval. Please provide
comment or direction to carry out the recommended disposal actions.

Brice Engineering, LLC
Subject: Results and Recommendations for Waste Disposal of Purge and Decontamination Water for Multiple
Sites at Tooele Army Depot-South

Page 2 of 2
Please feel free to contact me with any questions or concerns.

Sincerely,

Andrew Castor
Project Manager
Brice Engineering, LLC
312-835-0965
[e-mail]
CC:
Tyson Erickson/TEAD
Michael Bowlby/USAEC
Steve Richard/USAEC

Table 1 - Data Summary for May 2022 Sampling Event
SWMU 1/252 SWMU 25
(S-139-17)SWMU 13 SWMU 26
Volatile Organic Compounds
1,1-Dichloroethene D029 µg/L 700 0.20 U 0.40 J 0.18 J 1.5
1,2-Dichloroethane D028 µg/L 500 0.20 U 0.20 U 0.20 U 0.20 U
1,4-Dichlorobenzene D027 µg/L 7,500 0.20 U 0.20 U 0.20 U 0.20 U
2-Butanone (MEK)D035 µg/L 200,000 10 U 10 U 10 U 10 U
Benzene D018 µg/L 500 0.10 J 0.33 J 0.20 U 0.20 U
Carbon tetrachloride D019 µg/L 500 350 29,000 0.20 U 0.20 U
Chlorobenzene D021 µg/L 100,000 0.20 U 0.20 U 0.20 U 0.20 U
Chloroform D022 µg/L 6,000 130 690 0.37 J 1.00
Tetrachloroethene (PCE)D039 µg/L 700 0.68 J 24.0 0.30 U 0.30 U
Trichloroethene (TCE)D040 µg/L 500 0.20 U 4.60 0.50 J 0.20 U
Vinyl chloride D043 µg/L 200 0.30 U 0.30 U 0.30 U 0.30 U
Notes:
1. Regulatory levels are the maximum Toxicity Characteristic Leaching Procedure levels specified in Table 1 of 40 CFR §261.24.
2. Excluding analytical results for S-139-17
J – The reported result is an estimated value.
U - Not detected; the compound/analyte was analyzed for, but not detected above the limit of detection unless otherwise noted.
Regulatory Level1UnitsCompound
Hazardous
Waste
Number
Maximum Concentration Detected in May 2023
Samples

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1
James Haydock
From:Johnson, D Troy CIV USARMY JMC (USA) <[e-mail]>
Sent:Wednesday, June 21, 2023 2:07 PM
To:Andrew Castor; Erickson, Tyson B CIV USARMY JMC (USA)
Cc:Bowlby, Michael A CIV USARMY IMCOM (USA); Richard, Stephen F CIV USARMY
IMCOM (USA); Chris Holt; Bentley, Kristyl CIV USARMY JMC (USA); Perkins, Shane R CIV
USARMY JMC (USA)
Subject:RE: TEAD-S IDW Purge Water Disposal 2023
Attachments:TEAD-S_IDW_Recommendations_20230615.pdf
Follow Up Flag:Follow up
Flag Status:Completed
Andy,

Tyson and I have reviewed the proposal and are good with the
recommendaƟons. We will work with Shane Perkins the TEAD RCRA Waste
Program Manger to follow RCRA compliance and upload the waste into the TEAD
operaƟng record. We will coordinate the waste profile and manifesƟng with
Shane.

D. Troy Johnson
Tooele Army Depot
Environmental RestoraƟon, Cultural Resource and Natural Resource Manager
1 Tooele Army Depot
Tooele, UT 84074
[phone]
[e-mail]

-----Original Message-----
From: Andrew Castor <[e-mail]>
Sent: Thursday, June 15, 2023 9:38 AM
To: Johnson, D Troy CIV USARMY JMC (USA) <[e-mail]>;
Erickson, Tyson B CIV USARMY JMC (USA) <[e-mail]>
Cc: Bowlby, Michael A CIV USARMY IMCOM (USA)
<[e-mail]>; Richard, Stephen F CIV USARMY IMCOM (USA)
<[e-mail]>; Chris Holt <[e-mail]>
Subject: [Non-DoD Source] TEAD-S IDW Purge Water Disposal 2023

Troy,

AƩached is a leƩer recommending disposal of the TEAD-S sampling purge
water IDW for SWMUs 1, 13, 25, and 26. Please reach out to me with any
quesƟons or concerns.

2

Thanks,

Andy

Andrew Castor, PG

Project Manager

[e-mail]

312-835-0965 CELL

362 Pierpont Ave

Salt Lake City, Utah 84101

UTD981552177
Grantsville, UT 84029
11600 North Aptus Road
Certificate of Disposal / Treatment - Storage and Transfer Run Date: 1/17/2024
Manifested To Site:Aragonite, UT Facility
EPA ID/Prov ID:
Generator ID Manifest No.Generation Date Received Date
TE335290 018383012FLE 8/2/2023 8/4/2023
Date:
Title:
the verification that this information is true, accurate, and complete.
personally verify truth and accuracy, I certify as the company official having supervisory responsibility for the persons who, acting under my direct instructions, made
that the information contained in or accompanying this document is true, accurate, and complete. As to the identified section(s) of this document for which I cannot
Under civil and criminal penalties of law for the making of submission of false or fraudulent statements or representations (18 U.S.C. 1001 and 15 U.S.C. 2615), I certify
Clean Harbors and subsequently shipped to another licensed facility has been or shall be identified as being generated by Clean Harbors in accordance with 40CFR 264.71(c).
The above described waste, received at the Clean Harbors facility listed above pursuant to the manifest(s) listed above, has/will be treated and/or disposed of by Clean
Harbors, or another licensed facility approved by Clean Harbors, in accordance with applicable federal, state and provincial laws and regulations. Any waste received by
Signed:1/17/2024
For waste imported/exported to/from Canada the waste has/will be disposed or recycled according to the Canadian export and import of hazardous waste or hazardous
recyclable material regulation as published in the Canadian Gazette Part II, vol 139, No 11, SOR/2005-149 May 17, 2005
Director Facility Applications

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APPENDIX E
QUALITY CONTROL SUMMARY REPORT

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Appendix E – Quality Control Summary Report E-i
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
TABLE OF CONTENTS
ACRONYMS AND ABBREVIATIONS ..................................................................................................E-III
1.0 INTRODUCTION ..................................................................................................................E-1
2.0 DATA VERIFICATION, DATA QUALITY REVIEW, AND QUALIFICATION ....................................E-1
3.0 CHEMICAL DATA QUALITY REVIEW ......................................................................................E-3
3.1 Analytical Sample and Field Quality Control Sample Summary ...................................... E-4
3.2 Sample Handling and Chain-of-Custody .......................................................................... E-4
3.3 Sample Preservation and Holding Time Compliance ....................................................... E-4
3.4 Blanks ............................................................................................................................... E-4
3.4.1 Method Blanks .................................................................................................... E-4
3.4.2 Trip Blanks ........................................................................................................... E-5
3.4.3 Equipment Blanks ............................................................................................... E-5
3.5 Laboratory Control Samples ............................................................................................ E-5
3.6 Matrix Spike Samples and Duplicates .............................................................................. E-5
3.7 Surrogates ........................................................................................................................ E-6
3.8 Field Duplicate Precision .................................................................................................. E-6
3.9 Additional Quality Control Discrepancies ........................................................................ E-6
4.0 COMPLETENESS ..................................................................................................................E-7
5.0 OVERALL DATA QUALITY AND USABILITY ASSESSMENT ........................................................E-7
6.0 REFERENCES .......................................................................................................................E-8
TABLES
Table E-1 Data Qualifiers .............................................................................................................. E-3
Table E-2 Qualified Results Summary ........................................................................................... E-9
ATTACHMENTS
Attachment E-1 Sample Summary
Attachment E-2 Data Summary Table
Attachment E-3 Field Duplicate Precision Report
Attachment E-4 Data Validation Reports

Appendix E – Quality Control Summary Report E-ii
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah

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Appendix E – Quality Control Summary Report E-iii
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
ACRONYMS AND ABBREVIATIONS
°C degrees Celsius
% percent
%R percent recovery
µg/L micrograms per liter
Brice Brice Engineering, LLC
CoC chain-of-custody
CCV continuing calibration verification
DL detection limit
DoD Department of Defense
DQO data quality objective
DRO diesel range organics
EB equipment blank
EMAX EMAX Laboratories, Inc.
EPA U.S. Environmental Protection Agency
FD field duplicate
IC initial calibration
ICV initial calibration verification
LCL lower control limit
LCS laboratory control sample
LCSD laboratory control sample duplicate
LOD limit of detection
LOQ limit of quantitation
MB method blank
MCL maximum contaminant level
mm millimeter
MPC measurement performance criteria
MS matrix spike
MSD matrix spike duplicate
PAL project action level
QA quality assurance
QC quality control
QCSR quality control summary report
QSM Quality Systems Manual
RPD relative percent difference
RRF relative response factor
SDG sample delivery group
SOP standard operating procedure
TB trip blank
TPH total petroleum hydrocarbons
VOC volatile organic compound
Appendix E – Quality Control Summary Report E-iv
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah

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Appendix E – Quality Control Summary Report E-1
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
1.0 INTRODUCTION
This quality assurance (QA)/quality control (QC) report summarizes the evaluation of laboratory data
collected during 2023 Annual Groundwater Monitoring sampling event. These data have been reviewed
to evaluate compliance with QA/QC criteria based on data quality objectives (DQOs) specified in the
approved Final Uniform Federal Policy - Quality Assurance Project Plan (QAPP), Tooele Army Depot –
South, Utah (Brice 2021), hereafter referred to as the QAPP.
This quality control summary report (QCSR) includes the report narrative; a sample summary, including
all samples collected and submitted to the laboratory for the associated sample delivery group (SDG) in
Attachment E-1; complete analytical results presented in crosstab format in Attachment E-2; evaluation
of field duplicates (FD) relative percent differences (RPDs) in Attachment E-3; and data validation reports
in Attachment E-4.
2.0 DATA VERIFICATION, DATA QUALITY REVIEW, AND
QUALIFICATION
EMAX Laboratories, Inc. (EMAX) in Torrance, CA was the primary laboratory for this project. EMAX holds
current State of Utah certification under the National Environmental Laboratories Accreditation
Conference and Department of Defense (DoD) Environmental Laboratory Accreditation Program
certifications for all requested analyses, and chemical analyses for all parameters were performed in
accordance with the DoD Quality Systems Manual (QSM) for Environmental Laboratories, Version 5.3
(DoD 2019a). Samples were prepared and analyzed in accordance with analytical methods specified in
Test Methods for Evaluating Solid Waste SW-846 (U.S. Environmental Protection Agency [EPA] 2022) and
laboratory standard operating procedures (SOPs).
The data quality review and assessment were performed by an experienced QA chemist at Synectics in
Sacramento, CA who is independent of the analytical laboratory. This evaluation included a review of the
analytical data including lab and field QC sample results, field and laboratory documentation, and Stage 4
data submittals. At a minimum, the level of review is at Stage 2B, with a minimum of 10 percent of the
samples for the project reviewed at Stage 4. Groundwater analytical results were compared to project
action limits (PALs), which were defined as the EPA maximum contaminant level (MCL); the EPA tap water
regional screening levels (RSL) (EPA 2021); and State of Utah Leaking Underground Storage Tanks Tier 1
screening levels for total petroleum hydrocarbons (TPH) as diesel range organics (DRO).
All project data were reviewed on an analytical-batch basis by assessing QC samples and associated field
sample results. Data quality review and usability assessment were performed using the QC criteria defined
in the QAPP (Brice 2021); DoD QSM (DoD 2019a); DoD General Data Validation Guidelines (DoD 2019b);
Test Methods for Evaluating Solid Waste SW-846 (EPA 2022); and the laboratory SOPs, in that order.
The following information was reviewed as part of the data quality review and assessment:
• Case narrative review, laboratory flagging review, and other analytical method-specific criteria
• Sample handling and chain-of-custody (CoC)
• Sample preservation and holding time compliance
• Field QC samples, including trip blanks (TBs), equipment blanks (EBs), and FDs

Appendix E – Quality Control Summary Report E-2
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
• Laboratory reporting limits, including limits of detection (LODs) and limits of quantitation (LOQs)
• Method blanks (MBs)
• Laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) recoveries
• Surrogate spike recoveries
• Matrix spike (MS) and matrix spike duplicate (MSD) recoveries
• Precision, including relative percent difference (RPD) values for duplicate analyses
• Sample dilution and reanalysis summary, where applicable
• Initial/continuing calibration verifications and instrument sensitivity summary
• Internal standards performance (gas chromatography/mass spectrometry [GC/MS]), and
retention time summary
• Instrument performance check summary
• Sequence and preparation logs
• Raw data – including recalculations and chromatogram review
The data quality review and assessment identified results requiring qualification and potential effects on
data usability based on the measurement performance criteria (MPC) defined in the QAPP. The following
MPC were used for this data quality review and assessment:
• Precision is a measure of the reproducibility of measurements, which can be used to verify
laboratory procedures, determine matrix effect, or sample homogeneity. Precision was
measured by the RPD between LCS and LCSDs, MS and MSDs, or primary and FD results.
• Accuracy is a measure of the correctness or closeness to the true value. Accuracy was evaluated
by reviewing the following elements: calibrations, surrogates, LCS, LCSD, MS, MSD, MBs, relative
response factors and relative standard deviations, tune criteria, second column confirmations,
and internal standards.
• Representativeness is a measure of the degree to which the samples reflect the site
characteristics. Representativeness was measured by reviewing sampling design, sampling
procedures, sample documentation, holding times, and preservations.
• Completeness is a measure of the amount of valid data obtained compared to the amount that
was expected to be obtained under correct, normal conditions. For completeness requirements,
valid results were all results not rejected and determined to be usable in the context of the
DQOs. Completeness was evaluated for each analytical method for a particular sampling event
with respect to each DQO or end data use. The completeness goal is 100 percent (%) for this
project.
• Comparability is a measure of the confidence with which one data set can be compared to
another. The following were reviewed to ensure comparability: use of standard methods for
sampling and analysis, reporting in standard units, operating instruments within calibrated
ranges, and using standard and comprehensive reporting formats.
• Sensitivity is the ability of an analytical method or instrument to discriminate between
measurement responses representing different concentrations. This capability is established
during the planning phase to meet the DQOs. It is important that calibration requirements, DLs,
and project-specific LODs and LOQs presented in the QAPP are achieved and that target analytes
can be detected at concentrations necessary to support the DQOs. In addition, sample results

Appendix E – Quality Control Summary Report E-3
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
are compared to method blank and field blank results to identify potential effects of laboratory
background and field procedures on sensitivity.
The qualifiers listed in Table 1 were applied to the analytical data set, as appropriate.
Table E-1 Data Qualifiers
QUALIFIER DESCRIPTION
U
The analyte was analyzed for, but not detected, or the analyte was detected in the sample at a
concentration less than or equal to five times (10 times for common laboratory contaminants) the blank
concentration.
J
The analyte was positively identified, and the quantitation is an estimation because of discrepancies in
meeting certain analyte-specific QC criteria. Or the analyte was positively identified, but the associated
concentration is estimated above the DL and below the LOQ.
J+ The analyte is considered an estimated value with a possible high bias due to a QC deviation.
J- The analyte is considered an estimated value with a possible low bias due to a QC deviation.
UJ The analyte was not detected; however, the result is estimated because of discrepancies in meeting
certain analyte-specific QC criteria.
X
The sample results were affected by serious deficiencies in the ability to analyze the sample and to meet
published method and project QC criteria. The presence or absence of the analyte cannot be
substantiated by the data provided. Acceptance or rejection of the data should be decided by the project
team, but exclusion of the data is recommended.
Notes:
For definitions, refer to the Acronyms and Abbreviations section.

Qualification was not required in the following circumstances:
• Surrogate or MS recoveries were outside QC limits, and dilution of the sample resulted in
surrogate or spike dilution to a level beyond quantitation.
• MS recoveries were outside QC limits, and the spiked concentration was less than four times
that of the parent sample.
• An analyte was detected in the associated blank, but there was no detection in the associated
sample.
• MS/MSD or LCS/LCSD recoveries exceeded upper control limits and there was no detection in
the sample(s).
3.0 CHEMICAL DATA QUALITY REVIEW
The data verification and QCSR were performed to assess the overall quality and usability of the data
collected to support sampling activities for the 2023 Annual Groundwater Monitoring sampling event.
Complete details for the review and evaluation of field samples and associated QC samples are included
in this QCSR. During the data quality review, analytical results or recoveries that fell outside acceptance
criteria were identified and qualifiers were applied to the results, where appropriate, in accordance with
the project QAPP. Qualified results are considered estimated, and whenever possible, direction of
potential bias was assigned and effects on usability are discussed.

Appendix E – Quality Control Summary Report E-4
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
3.1 Analytical Sample and Field Quality Control Sample Summary
A total of 27 primary groundwater samples, four FD groundwater samples, four TBs, and two EBs were
collected and analyzed in support of project activities. The sample summary table in Attachment E-1
includes all field samples submitted to the analytical laboratory.
The overall project-required frequency of one FD for every 10 or fewer primary samples was met.
Five MS/MSDs were collected and submitted to the laboratory at the project-required frequency of one
set for every 20 or fewer project samples (5%).
EBs were collected at the proper frequency of one EB for every 20 primary samples, for each solid waste
management unit.
TBs were included in each cooler containing samples for volatile organic analysis (e.g., SW8260C).
3.2 Sample Handling and Chain-of-Custody
CoC forms and laboratory case narratives were reviewed to assess sample handling procedures that may
affect the integrity of the samples and quality of the resulting data. Copies of CoCs and cooler receipt
forms are included in the final laboratory report. Samples were required to be maintained at 0 to 6
degrees Celsius (°C) following collection, during storage, and upon receipt at the laboratory.
Samples were packed with frozen gel packs in accordance with the Brice packaging and shipping SOP, BE-
SOP-03 Labeling, Packaging, and Shipping Samples. Samples were shipped to EMAX in Torrance, CA via
FedEx. All sample coolers containing groundwater samples were received with temperature blank and
ambient cooler temperatures between 0 and 6°C.
3.3 Sample Preservation and Holding Time Compliance
The samples were extracted and/or analyzed within the recommended holding times and were properly
preserved for the analytical procedures used for this project.
All of the VOC sample containers for sample S13-CAM-DW1-052023 contained bubbles greater than
6 millimeters (mm) in diameter. The laboratory used the vial with the smallest bubble for the SW8260C
analysis. The detected and non-detect VOC results for sample S13-CAM-DW1-052023 were qualified J-
and UJ, respectively for estimated potential low bias.
3.4 Blanks
The following sections describe the results of the review and assessment of data for each analytical
method. QC parameters met project MPCs and DoD QSM v.5.3 criteria except where noted.
3.4.1 Method Blanks
An MB was included with each preparatory batch of 20 or fewer samples, as required. MB detections are
indicative of laboratory cross-contamination.
No target analytes were detected in the MBs.

Appendix E – Quality Control Summary Report E-5
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
3.4.2 Trip Blanks
A TB was included with each cooler containing volatile samples, as required. TB detections are indicative
of shipment and storage cross-contamination.
No target analytes were detected in the TBs.
3.4.3 Equipment Blanks
EBs were collected and submitted at the project-required frequency of one EB per 20 or fewer samples
collected using non-dedicated sampling equipment. EBs are reviewed to assess potential cross-
contamination between samples when non-dedicated sampling equipment is used.
The following analytes were detected greater than the detection limit in an EB and had associated project
sample detections less than 5 or 10 times (common laboratory contaminants) the blank concentration:
23E081: SW8260C analyte chloroform was detected in the EB and the following result was qualified U as
not detected: S-138-16-052023. VOCs analytes acetone and toluene were detected in the EB. However,
these analytes were not detected in the associated samples and no data qualifiers were applied to the
data for these analytes.
23E133: SW8260C analyte chloroform was detected in the EB and the following result was qualified U as
not detected: S-55-90-052023.
3.5 Laboratory Control Samples
An LCS or LCS/LCSD pair was included with each preparatory batch, as required. LCS and LCSD %R and
LCS/LCSD RPD were compared to the project MPC. All LCS/LCSD recoveries were within control limits and
LCS/LCSD precision was within the RPD limit.
3.6 Matrix Spike Samples and Duplicates
A project-specific MS/MSD sample was collected and submitted at the project-required frequency of one
MS/MSD per 20 or fewer samples. MS and MSD samples were prepared and analyzed for each laboratory
batch. However, in some instances the laboratory selected a sample from another client to perform the
MS/MSD on, and did not report the results of the MS/MSD.
MS/MSD recoveries and MS/MSD RPD were compared to project MPCs and met acceptance criteria, with
the following exceptions:
23E081: SW8260C analyte styrene recovered less than the lower control limit in the MS/MSD performed
on parent sample S-68-90-052023. The associated non-detect styrene result was qualified UJ for
estimated potential low bias.
23E081: SW8260C analyte styrene recovered less than the lower control limit in the MS/MSD performed
on parent sample S-70-90-052023. The associated non-detect styrene result was qualified UJ for
estimated potential low bias.
23E120: SW8260C analyte styrene recovered less than the lower control limit in the MS/MSD performed
on parent sample S-121-08-052023. The associated non-detect styrene result was qualified UJ for
estimated potential low bias.

Appendix E – Quality Control Summary Report E-6
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
3.7 Surrogates
Surrogates were included with all laboratory QC and field samples, as required. Surrogate recoveries were
reviewed and compared to project MPC. The majority of the surrogate recoveries were within control
limits for laboratory QC and field samples, with the following exceptions:
22E276: SW8260C surrogate dibromofluoromethane was recovered greater than the upper control limit
in samples S-139-17-052023 and S-139-17-052023D. The associated detected 1,1-dichloroethene,
benzene, carbon disulfide, methylene chloride, tetrachloroethene, trans-1,2-dichloroethene, and
trichloroethene results were qualified J+ due to estimated potential high bias.
3.8 Field Duplicate Precision
FD precision was evaluated by calculating the RPD between the parent sample result and the FD result
when both results were above the LOQ, and when one result fell between the LOD and the LOQ.
Acceptance criteria were less than 30% for water results.
Four FD samples were submitted and analyzed for 27 primary groundwater samples. Various FD pairs
were analyzed by methods SW8015D and SW8260C and all RPDs met acceptance criteria.
Attachment E-3 summarizes the field duplicate detections that were included in precision evaluations.
3.9 Additional Quality Control Discrepancies
Additional discrepancies not noted in the previous sections of this report that resulted in data qualification
are discussed here.
23E081: The closing continuing calibration verification (CCV) standard was analyzed outside of the 12-
hour analytical window. All of the associated detected and non-detected results in samples S-67-90-
052023, S-68-90-052023, S-70-90-052023, S-71-90-052023, S-93-92-052023, S-95-92-052023, S-97-92-
052023, S-129-15-052023, S-137-16-052023, S-138-16-052023, S-141-17-052023, SWMU-1/25-EB-
052023, and TB-20230503-1/25 were qualified J and UJ for indeterminate bias.
23E081: Acetone and 2-butanone had low relative response factors (RRFs) in the initial calibration (IC),
initial calibration verification (ICV) standard, and the opening and closing CCV standards. The associated
detected and non-detected results in samples S-67-90-052023, S-68-90-052023, S-70-90-052023, S-71-
90-052023, S-93-92-052023, S-95-92-052023, S-97-92-052023, S-129-15-052023, S-137-16-052023, S-
138-16-052023, S-141-17-052023, SWMU-1/25-EB-052023, and TB-20230503-1/25 were qualified J and
UJ for indeterminate bias.
23E120: Acetone and 2-butanone had low RRFs in the IC, ICV standard, and the opening and closing CCV
standards. The associated non-detected results in samples S-120-08-052023, S-121-08-052023, S-127-15-
052023, S-128-15-052023, S-135-16-052023, S-135-16-052023D, S-136-16-052023, S-139-17-052023, S-
139-17-05-2023D, S-140-17-052023, S-142-17-052023, and TB-20230509-1/25 were qualified UJ for
indeterminate bias.
23E133: Acetone and 2-butanone had low RRFs in the IC, ICV standard, and the opening and closing CCV
standards. The associated non-detected results in samples S13-CAM-DW1-052023, S-55-90-052023, S-78-
91-052023, S-91-91-052023, S-91-91-052023D, SWMU-13-EB-052023, and TB-20230515-13 were
qualified UJ for indeterminate bias.

Appendix E – Quality Control Summary Report E-7
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
23E133: Acetone and 2-butanone had low RRFs in the IC, ICV standard, and the opening and closing CCV
standards. The associated non-detected results in samples S-38-90-052023, S-40-90-052023, S-40-90-
052023D, S-150-20-052023, and TB-20230517-26 were qualified UJ for indeterminate bias.
4.0 COMPLETENESS
Completeness is a measure of the amount of valid data obtained compared with the amount that was
expected to be obtained under correct, normal conditions. For completeness requirements, valid results
are all results not rejected and determined to be usable in the context of project DQOs.
Completeness was evaluated using the formula below. The goal for completeness was 90% for all
methods and matrices. % 𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶 = 100 𝑥𝑥 (𝑉𝑉𝐶𝐶 )
Where: V = number of measurements judged valid
n = total number of measurements
No results were rejected and all results were considered usable. The overall project completeness for this
event is 100%.
5.0 OVERALL DATA QUALITY AND USABILITY ASSESSMENT
The overall quality of the project data was acceptable and completeness goals were met. Qualified data
are considered acceptable for use, with the limitations discussed within this QA/QC report regarding the
qualifiers applied to the results.
Table 2 includes all qualified results and reasons for qualification.
The following QC issues required qualification:
• Closing CCV analyzed greater than the 12-hour window
• EB contamination
• IC, ICV, and CCV RRF exceedances
• MS/MSD recovery failures
• MS/MSD RPD exceedances
• Bubbles greater than 6 mm in sample containers
• Surrogate recovery failures

Appendix E – Quality Control Summary Report E-8
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
6.0 REFERENCES
Brice Engineering. 2021. Final Uniform Federal Policy – Quality Assurance Project Plan Tooele Army
Depot South, Utah. October.
Department of Defense (DoD). 2019a. Quality Systems Manual for Environmental Laboratories,
Version 5.3. May.
DoD. 2019b. General Data Validation Guidelines. November.
DoD. 2020a. Data Validation Guidelines Module 1: Data Validation Procedure for Organic Analysis by
GC/MS. May.
U.S. Environmental Protection Agency (EPA). 2022. Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods, EPA publication SW-846, Third Edition, Final Updates I (1993), II
(1995), IIA (1994), IIB (1995), III (1997), IIIA (1999), IIIB (2005), IV (2008), V (2015), VI (2018), and
VII (2022).
EPA. 2021. Regional Screening Levels. Tables as of May 2021. Available at
https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables. Accessed on August 19,
2021.

Appendix E – Quality Control Summary Report E-9
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-38-90-052023 23E135 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-38-90-052023 23E135 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-40-90-052023 23E135 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-40-90-052023 23E135 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-40-90-05-2023D 23E135 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-40-90-05-2023D 23E135 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-55-90-052023 23E133 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-55-90-052023 23E133 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-55-90-052023 23E133 GW SW8260C Chloroform µg/L 1.0 U EB<LOQ
S-67-90-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-10
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-67-90-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-67-90-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-67-90-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-11
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-67-90-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-67-90-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-12
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-67-90-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-68-90-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-13
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-68-90-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-68-90-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock

Appendix E – Quality Control Summary Report E-14
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-68-90-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock, MS<LCL,
MSD<LCL
S-68-90-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-68-90-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock

Appendix E – Quality Control Summary Report E-15
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-70-90-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-70-90-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-70-90-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-16
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-70-90-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock, MS<LCL,
MSD<LCL
S-70-90-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-17
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-70-90-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-70-90-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-18
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-71-90-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-71-90-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-71-90-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-19
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-71-90-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-71-90-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-78-91-052023 23E133 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-78-91-052023 23E133 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-91-91-052023 23E133 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-91-91-052023 23E133 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF

Appendix E – Quality Control Summary Report E-20
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-91-91-05-2023D 23E133 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-91-91-05-2023D 23E133 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-93-92-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-93-92-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-21
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-93-92-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-93-92-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-22
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-93-92-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-93-92-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock

Appendix E – Quality Control Summary Report E-23
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-95-92-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-95-92-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-95-92-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-24
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-95-92-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-25
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-95-92-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-95-92-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-26
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-97-92-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-97-92-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-97-92-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-27
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-97-92-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-97-92-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-120-08-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-120-08-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-121-08-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-121-08-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF

Appendix E – Quality Control Summary Report E-28
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-121-08-052023 23E120 GW SW8260C Styrene µg/L 0.50 UJ MS<LCL, MSD<LCL
S-127-15-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-127-15-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-128-15-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-128-15-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-129-15-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-29
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-129-15-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-129-15-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-129-15-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-30
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-129-15-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-129-15-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-135-16-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-135-16-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-135-16-05-2023D 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF

Appendix E – Quality Control Summary Report E-31
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-135-16-05-2023D 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-136-16-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-136-16-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-137-16-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-32
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-137-16-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-137-16-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-137-16-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.28 J >12HRClock
S-137-16-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-33
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-137-16-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-137-16-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-34
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-138-16-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-138-16-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-138-16-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-35
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-138-16-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock, EB<LOQ
S-138-16-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-36
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-138-16-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-138-16-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-139-17-052023 23E120 GW SW8260C 1,1-Dichloroethene µg/L 0.40 J+ Sur>UCL
S-139-17-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-139-17-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-139-17-052023 23E120 GW SW8260C Benzene µg/L 0.33 J+ Sur>UCL
S-139-17-052023 23E120 GW SW8260C Carbon disulfide µg/L 1.7 J+ Sur>UCL
S-139-17-052023 23E120 GW SW8260C Methylene chloride µg/L 4.3 J+ Sur>UCL
S-139-17-052023 23E120 GW SW8260C Tetrachloroethene (PCE) µg/L 24 J+ Sur>UCL
S-139-17-052023 23E120 GW SW8260C trans-1,2-Dichloroethene µg/L 0.12 J+ Sur>UCL
S-139-17-052023 23E120 GW SW8260C Trichloroethene (TCE) µg/L 4.5 J+ Sur>UCL
S-139-17-05-2023D 23E120 GW SW8260C 1,1-Dichloroethene µg/L 0.38 J+ Sur>UCL
S-139-17-05-2023D 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-139-17-05-2023D 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-139-17-05-2023D 23E120 GW SW8260C Benzene µg/L 0.33 J+ Sur>UCL
S-139-17-05-2023D 23E120 GW SW8260C Carbon disulfide µg/L 1.8 J+ Sur>UCL
S-139-17-05-2023D 23E120 GW SW8260C Methylene chloride µg/L 4.2 J+ Sur>UCL
S-139-17-05-2023D 23E120 GW SW8260C Tetrachloroethene (PCE) µg/L 24 J+ Sur>UCL

Appendix E – Quality Control Summary Report E-37
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-139-17-05-2023D 23E120 GW SW8260C trans-1,2-Dichloroethene µg/L 0.11 J+ Sur>UCL
S-139-17-05-2023D 23E120 GW SW8260C Trichloroethene (TCE) µg/L 4.6 J+ Sur>UCL
S-140-17-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-140-17-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-141-17-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-38
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-141-17-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-141-17-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
S-141-17-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock

Appendix E – Quality Control Summary Report E-39
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S-141-17-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
S-141-17-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
S-142-17-052023 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-142-17-052023 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-150-20-052023 23E135 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
S-150-20-052023 23E135 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF

Appendix E – Quality Control Summary Report E-40
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S13-CAM-DW1-052023 23E133 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,1-Dichloroethane µg/L 0.12 J- Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 1,4-Dioxane µg/L 50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ Pres, IC RRF, ICV RRF,
CCV RRF
S13-CAM-DW1-052023 23E133 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 2-Hexanone µg/L 10 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ Pres

Appendix E – Quality Control Summary Report E-41
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S13-CAM-DW1-052023 23E133 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Acetone µg/L 10 UJ Pres, IC RRF, ICV RRF,
CCV RRF
S13-CAM-DW1-052023 23E133 GW SW8260C Benzene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Bromobenzene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Bromochloromethane µg/L 0.30 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Bromodichloromethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Bromoform µg/L 0.30 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Bromomethane µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Carbon disulfide µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Chlorobenzene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Chloroethane µg/L 1.0 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Chloroform µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Chloromethane µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Cumene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Dibromochloromethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Dibromomethane µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Ethylbenzene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C m,p-Xylene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Methylene chloride µg/L 1.0 UJ Pres

Appendix E – Quality Control Summary Report E-42
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
S13-CAM-DW1-052023 23E133 GW SW8260C n-Butylbenzene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C n-Propylbenzene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C o-Xylene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Styrene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Toluene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ Pres
S13-CAM-DW1-052023 23E133 GW SW8260C Vinyl chloride µg/L 0.30 UJ Pres
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock

Appendix E – Quality Control Summary Report E-43
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
SWMU-1/25-EB-052023 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Acetone µg/L 5.8 J >12HRClock, IC RRF,
ICV RRF, CCV RRF
SWMU-1/25-EB-052023 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-44
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
SWMU-1/25-EB-052023 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Chloroform µg/L 0.18 J >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Toluene µg/L 0.11 J >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-45
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
SWMU-1/25-EB-052023 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
SWMU-1/25-EB-052023 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
SWMU-13-EB-052023 23E133 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
SWMU-13-EB-052023 23E133 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
TB-20230503-1/25 23E081 GW SW8260C 1,1,1,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,1,1-Trichloroethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,1,2,2-Tetrachloroethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,1,2-Trichloroethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,1-Dichloroethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,1-Dichloroethene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,1-Dichloropropene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2,3-Trichlorobenzene µg/L 0.30 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2,3-Trichloropropane µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2,4-Trichlorobenzene µg/L 0.30 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2-Dibromo-3-
chloropropane µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2-Dibromoethane (EDB) µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2-Dichlorobenzene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2-Dichloroethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,2-Dichloropropane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,3-Dichlorobenzene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,3-Dichloropropane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 1,4-Dichlorobenzene µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-46
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
TB-20230503-1/25 23E081 GW SW8260C 1,4-Dioxane µg/L 50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 2,2-Dichloropropane µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
TB-20230503-1/25 23E081 GW SW8260C 2-Chlorotoluene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 2-Hexanone µg/L 10 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 4-Chlorotoluene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C 4-Methyl-2-pentanone
(MIBK) µg/L 5.0 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Acetone µg/L 10 UJ >12HRClock, IC RRF,
ICV RRF, CCV RRF
TB-20230503-1/25 23E081 GW SW8260C Benzene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Bromobenzene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Bromochloromethane µg/L 0.30 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Bromodichloromethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Bromoform µg/L 0.30 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Bromomethane µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Carbon disulfide µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Carbon Tetrachloride µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Chlorobenzene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Chloroethane µg/L 1.0 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Chloroform µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Chloromethane µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C cis-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C cis-1,3-Dichloropropene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Cumene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Dibromochloromethane µg/L 0.20 UJ >12HRClock

Appendix E – Quality Control Summary Report E-47
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
TB-20230503-1/25 23E081 GW SW8260C Dibromomethane µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Dichlorodifluoromethane µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Ethylbenzene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C m,p-Xylene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Methyl tert-butyl ether
(MTBE) µg/L 0.30 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Methylene chloride µg/L 1.0 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C n-Butylbenzene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C n-Propylbenzene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C o-Xylene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C p-Cymene (p-
Isopropyltoluene) µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C sec-Butylbenzene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Styrene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C tert-Butylbenzene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Tetrachloroethene (PCE) µg/L 0.30 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Toluene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C trans-1,2-Dichloroethene µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C trans-1,3-
Dichloropropene µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Trichloroethene (TCE) µg/L 0.20 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Trichlorofluoromethane µg/L 0.50 UJ >12HRClock
TB-20230503-1/25 23E081 GW SW8260C Vinyl chloride µg/L 0.30 UJ >12HRClock
TB-20230509-1/25 23E120 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
TB-20230509-1/25 23E120 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
TB-20230515-13 23E133 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF

Appendix E – Quality Control Summary Report E-48
2023 Annual Groundwater Monitoring Event Quality Control Summary Report
Tooele Army Depot South, Utah
Table E-2 Qualified Results Summary

SAMPLE IDENTIFICATION SDG MATRIX METHOD ANALYTE UNITS FINAL
RESULT
DATA
REVIEW
QUALIFIER
REASON FOR
QUALIFICATION
TB-20230515-13 23E133 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
TB-20230517-26 23E135 GW SW8260C 2-Butanone (MEK) µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
TB-20230517-26 23E135 GW SW8260C Acetone µg/L 10 UJ IC RRF, ICV RRF, CCV
RRF
Notes:
For definitions, refer to Acronyms and Abbreviations section.:
>12HRClock – closing CCV standard analyzed outside of the 12-hour window
CCV RRF – CCV standard relative response factor less than the lower control limit
EB<LOQ – equipment blank concentration less than the limit of quantitation
IC RRF – initial calibration relative response factor less than the lower control limit
ICV RRF – initial calibration verification standard relative response factor less than the lower control limit

MS<LCL – matrix spike recovery less than the lower control limit
MSD<LCL – matrix spike duplicate recovery less than the lower control limit
Pres – sample container contained a bubble greater 6 mm
Sur>UCL – surrogate recovery greater than the upper control limit

ATTACHMENT E-1
SAMPLE SUMMARY

This page intentionally blank
Field Sample ID Location Begin
Depth
End
Depth Matrix Sample Type Sample Method Sampling Date Lab SDG
TPH-Diesel Range
Organics (SW8015D)
VOCs
(SW8260C)
S-120-08-052023 S-120-08 46 66 GW N HY 5/12/2023 EMXT 23E120 X
S-121-08-052023 S-121-08 32.5 52.5 GW N, MS/MSD HY 5/9/2023 EMXT 23E120 X
S-127-15-052023 S-127-15 0 0 GW N HY 5/10/2023 EMXT 23E120 X
S-128-15-052023 S-128-15 0 0 GW N HY 5/9/2023 EMXT 23E120 X
S-129-15-052023 S-129-15 0 0 GW N HY 5/5/2023 EMXT 23E081 X
S-135-16-052023 S-135-16 0 0 GW N HY 5/10/2023 EMXT 23E120 X
S-135-16-05-2023D S-135-16 0 0 GW FD HY 5/10/2023 EMXT 23E120 X
S-136-16-052023 S-136-16 0 0 GW N HY 5/11/2023 EMXT 23E120 X
S-137-16-052023 S-137-16 0 0 GW N HY 5/8/2023 EMXT 23E081 X
S-138-16-052023 S-138-16 0 0 GW N HY 5/8/2023 EMXT 23E081 X
S-139-17-052023 S-139-17 0 0 GW N HY 5/12/2023 EMXT 23E120 X
S-139-17-05-2023D S-139-17 0 0 GW FD HY 5/12/2023 EMXT 23E120 X
S13-CAM-DW1-052023 S13-CAM-DW1 0 0 GW N, MS/MSD HY 5/15/2023 EMXT 23E133 X X
S-140-17-052023 S-140-17 0 0 GW N HY 5/11/2023 EMXT 23E120 X
S-141-17-052023 S-141-17 0 0 GW N HY 5/8/2023 EMXT 23E081 X
S-142-17-052023 S-142-17 0 0 GW N HY 5/9/2023 EMXT 23E120 X
S-150-20-052023 S-150-20 0 0 GW N, MS/MSD HY 5/17/2023 EMXT 23E135 X
S-38-90-052023 S-38-90 210.5 230.5 GW N HY 5/17/2023 EMXT 23E135 X
S-40-90-052023 S-40-90 251 271 GW N HY 5/17/2023 EMXT 23E135 X
S-40-90-05-2023D S-40-90 251 271 GW FD HY 5/17/2023 EMXT 23E135 X
S-55-90-052023 S-55-90 8 18 GW N HY 5/16/2023 EMXT 23E133 X X
S-67-90-052023 S-67-90 26 36 GW N HY 5/3/2023 EMXT 23E081 X
S-68-90-052023 S-68-90 52.5 62.5 GW N,MS/MSD HY 5/4/2023 EMXT 23E081 X
S-70-90-052023 S-70-90 40 50 GW N, MS/MSD HY 5/4/2023 EMXT 23E081 X
S-71-90-052023 S-71-90 58 68 GW N HY 5/4/2023 EMXT 23E081 X
S-78-91-052023 S-78-91 13.8 28.8 GW N HY 5/16/2023 EMXT 23E133 X X
S-91-91-052023 S-91-91 0 0 GW N HY 5/15/2023 EMXT 23E133 X X
S-91-91-05-2023D S-91-91 0 0 GW FD HY 5/15/2023 EMXT 23E133 X X
S-93-92-052023 S-93-92 136 151.5 GW N HY 5/5/2023 EMXT 23E081 X
S-95-92-052023 S-95-92 102.5 128 GW N HY 5/3/2023 EMXT 23E081 X
S-97-92-052023 S-97-92 72.5 83 GW N HY 5/5/2023 EMXT 23E081 X
SWMU-1/25-EB-052023 FIELDQC 0 0 WQ EB HY 5/3/2023 EMXT 23E081 X
Page 1 of 2
Sample Summary
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
Field Sample ID Location Begin
Depth
End
Depth Matrix Sample Type Sample Method Sampling Date Lab SDG
TPH-Diesel Range
Organics (SW8015D)
VOCs
(SW8260C)
SWMU-13-EB-052023 FIELDQC 0 0 WQ EB HY 5/15/2023 EMXT 23E133 X X
TB-20230503-1/25 FIELDQC 0 0 WQ TB --5/3/2023 EMXT 23E081 X
TB-20230509-1/25 FIELDQC 0 0 WQ TB --5/9/2023 EMXT 23E120 X
TB-20230515-13 FIELDQC 0 0 WQ TB --5/15/2023 EMXT 23E133 X
TB-20230517-26 FIELDQC 0 0 WQ TB --5/17/2023 EMXT 23E135 X
Notes:
EB – equipment blank
EMXT – EMAX Laboratories, Inc.
FD – field duplicate
GW – groundwater
HY – HydraSleeve®
ID – identification
MS – matrix spike
MSD – matrix spike duplicate
N – normal sample
QC – quality control
SDG – sample delivery group
TB – trip blank
TPH – total petroleum hydrocarbons
VOCs – volatile organic compounds
WQ – water quality control
Page 2 of 2
Sample Summary
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah

ATTACHMENT E-2
DATA SUMMARY TABLE

This page intentionally blank
S-120-08 S-121-08 S-127-15 S-128-15 S-129-15 S-136-16 S-137-16 S-138-16
S-120-08-052023 S-121-08-052023 S-127-15-052023 S-128-15-052023 S-129-15-052023 S-135-16-052023 S-135-16-05-2023D S-136-16-052023 S-137-16-052023 S-138-16-052023
5/12/2023 10:05:00 AM 5/9/2023 12:40:00 PM 5/10/2023 2:25:00 PM 5/9/2023 2:20:00 PM 5/5/2023 1:05:00 PM 5/10/2023 1:05:00 PM 5/10/2023 1:10:00 PM 5/11/2023 12:40:00 PM 5/8/2023 1:50:00 PM 5/8/2023 4:20:00 PM
N N N N N N FD N N N
Total Petroleum Hydrocarbons (µg/L)Matrix Screening Limit Type1 PAL
TPH-DRO GW UT LUST Tier 1 10,000 NA NA NA NA NA NA NA NA NA NA
VOC (µg/L)Matrix Screening Limit Type1 PAL
1,1,1,2-Tetrachloroethane GW EPA Tapwater RSL 0.57 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,1,1-Trichloroethane GW EPA MCL 200 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,1,2,2-Tetrachloroethane GW EPA Tapwater RSL 0.076 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,1,2-Trichloroethane GW EPA Tapwater RSL 0.28 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,1-Dichloroethane GW EPA Tapwater RSL 2.8 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,1-Dichloroethene GW EPA MCL 7 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,1-Dichloropropene GW NS NS 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,2,3-Trichlorobenzene GW EPA Tapwater RSL 7 0.300 U 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ
1,2,3-Trichloropropane GW EPA Tapwater RSL 0.00075 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
1,2,4-Trichlorobenzene GW EPA Tapwater RSL 1.2 0.300 U 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ
1,2-Dibromo-3-chloropropane GW EPA Tapwater RSL 0.00033 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
1,2-Dibromoethane (EDB)GW EPA Tapwater RSL 0.0075 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,2-Dichlorobenzene GW EPA Tapwater RSL 300 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,2-Dichloroethane GW EPA Tapwater RSL 0.17 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,2-Dichloropropane GW EPA Tapwater RSL 0.85 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,3-Dichlorobenzene GW NS NS 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,3-Dichloropropane GW EPA Tapwater RSL 370 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,4-Dichlorobenzene GW EPA Tapwater RSL 0.48 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
1,4-Dioxane GW EPA Tapwater RSL 0.46 50.0 U 50.0 U 50.0 U 50.0 U 50.0 UJ 50.0 U 50.0 U 50.0 U 50.0 UJ 50.0 UJ
2,2-Dichloropropane GW NS NS 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
2-Butanone (MEK)GW EPA Tapwater RSL 5600 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
2-Chlorotoluene GW EPA Tapwater RSL 240 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
2-Hexanone GW EPA Tapwater RSL 38 10.0 U 10.0 U 10.0 U 10.0 U 10.0 UJ 10.0 U 10.0 U 10.0 U 10.0 UJ 10.0 UJ
4-Chlorotoluene GW EPA Tapwater RSL 250 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
4-Methyl-2-pentanone (MIBK)GW NS NS 5.00 U 5.00 U 5.00 U 5.00 U 5.00 UJ 5.00 U 5.00 U 5.00 U 5.00 UJ 5.00 UJ
Acetone GW EPA Tapwater RSL 14,000 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
Benzene GW EPA Tapwater RSL 0.46 0.200 U 0.200 U 0.200 U 0.100 J 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Bromobenzene GW EPA Tapwater RSL 62 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Bromochloromethane GW EPA Tapwater RSL 83 0.300 U 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ
Bromodichloromethane GW EPA Tapwater RSL 0.13 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Bromoform GW EPA Tapwater RSL 3.3 0.300 U 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ
Bromomethane GW EPA Tapwater RSL 7.5 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
Carbon disulfide GW EPA Tapwater RSL 810 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.280 J 0.500 UJ
Carbon Tetrachloride GW EPA Tapwater RSL 0.46 350 3.00 0.200 U 0.200 U 0.200 UJ 18.0 19.0 29.0 0.200 UJ 0.200 UJ
Chlorobenzene GW EPA Tapwater RSL 78 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Chloroethane GW EPA Tapwater RSL 21,000 1.00 U 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 UJ
Chloroform GW EPA Tapwater RSL 0.22 49.0 1.60 130 12.0 0.200 UJ 1.40 1.40 15.0 0.200 UJ 0.200 UJ
Sample ID:
Location:
Sample Date:
S-135-16
Sample Type:
Page 1 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
S-120-08 S-121-08 S-127-15 S-128-15 S-129-15 S-136-16 S-137-16 S-138-16
S-120-08-052023 S-121-08-052023 S-127-15-052023 S-128-15-052023 S-129-15-052023 S-135-16-052023 S-135-16-05-2023D S-136-16-052023 S-137-16-052023 S-138-16-052023
5/12/2023 10:05:00 AM 5/9/2023 12:40:00 PM 5/10/2023 2:25:00 PM 5/9/2023 2:20:00 PM 5/5/2023 1:05:00 PM 5/10/2023 1:05:00 PM 5/10/2023 1:10:00 PM 5/11/2023 12:40:00 PM 5/8/2023 1:50:00 PM 5/8/2023 4:20:00 PM
N N N N N N FD N N N
Sample ID:
Location:
Sample Date:
S-135-16
Sample Type:
Chloromethane GW EPA Tapwater RSL 190 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
cis-1,2-Dichloroethene GW EPA Tapwater RSL 36 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
cis-1,3-Dichloropropene GW NS NS 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Cumene GW EPA Tapwater RSL 45 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Dibromochloromethane GW EPA Tapwater RSL 0.87 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Dibromomethane GW EPA Tapwater RSL 8.3 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Dichlorodifluoromethane GW EPA Tapwater RSL 200 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
Ethylbenzene GW EPA Tapwater RSL 1.5 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
m,p-Xylene GW EPA Tapwater RSL 190 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
Methyl tert-butyl ether (MTBE)GW EPA Tapwater RSL 14 0.300 U 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ
Methylene chloride GW EPA MCL 5 1.00 U 1.00 U 0.690 J 1.00 U 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 UJ
n-Butylbenzene GW EPA Tapwater RSL 1,000 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
n-Propylbenzene GW EPA Tapwater RSL 660 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
o-Xylene GW EPA Tapwater RSL 190 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
p-Cymene (p-Isopropyltoluene)GW NS NS 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
sec-Butylbenzene GW EPA Tapwater RSL 2,000 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
Styrene GW EPA MCL 100 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
tert-Butylbenzene GW EPA Tapwater RSL 690 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
Tetrachloroethene (PCE)GW EPA MCL 5 0.680 J 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ
Toluene GW EPA MCL 100 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
trans-1,2-Dichloroethene GW EPA Tapwater RSL 68 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
trans-1,3-Dichloropropene GW NS NS 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
Trichloroethene (TCE)GW EPA Tapwater RSL 0.49 0.200 U 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ
Trichlorofluoromethane GW EPA Tapwater RSL 5,200 0.500 U 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ
Vinyl chloride GW EPA Tapwater RSL 0.019 0.300 U 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ
EB – equipment blank
GW – groundwater
N – normal
NS – not specified
PAL – project action limit
QC – quality control
TB – trip blank
2PAL is the most stringent of the EPA MCL or the May 2021 EPA tap water RSLs (based on a cancer risk of 1E-06 or a target quotient of 1.0)
Detected results appear in bold font
Notes:
1State of Utah LUST Tier 1 screening level
Highlighted cells indicate detections that exceed the selected screening level.
µg/L – micrograms per liter
EPA – U.S. Environmental Protection Agency
FD – field duplicate
J – The reported result is an estimated value.
J- – The analyte is considered an estimated value with a possible low-bias due to a QC deviation.
MCL – maximum contaminant level
U – Not detected; the compound/analyte was analyzed for, but not detected above the Limit of Detection (LOD) unless otherwise noted
UJ – The analyte was not detected; however, the result is estimated because of discrepancies in meeting certain analyte-specific QC criteria.
VOC – volatile organic compounds
Page 2 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
Total Petroleum Hydrocarbons (µg/L)Matrix Screening Limit Type1 PAL
TPH-DRO GW UT LUST Tier 1 10,000
VOC (µg/L)Matrix Screening Limit Type1 PAL
1,1,1,2-Tetrachloroethane GW EPA Tapwater RSL 0.57
1,1,1-Trichloroethane GW EPA MCL 200
1,1,2,2-Tetrachloroethane GW EPA Tapwater RSL 0.076
1,1,2-Trichloroethane GW EPA Tapwater RSL 0.28
1,1-Dichloroethane GW EPA Tapwater RSL 2.8
1,1-Dichloroethene GW EPA MCL 7
1,1-Dichloropropene GW NS NS
1,2,3-Trichlorobenzene GW EPA Tapwater RSL 7
1,2,3-Trichloropropane GW EPA Tapwater RSL 0.00075
1,2,4-Trichlorobenzene GW EPA Tapwater RSL 1.2
1,2-Dibromo-3-chloropropane GW EPA Tapwater RSL 0.00033
1,2-Dibromoethane (EDB)GW EPA Tapwater RSL 0.0075
1,2-Dichlorobenzene GW EPA Tapwater RSL 300
1,2-Dichloroethane GW EPA Tapwater RSL 0.17
1,2-Dichloropropane GW EPA Tapwater RSL 0.85
1,3-Dichlorobenzene GW NS NS
1,3-Dichloropropane GW EPA Tapwater RSL 370
1,4-Dichlorobenzene GW EPA Tapwater RSL 0.48
1,4-Dioxane GW EPA Tapwater RSL 0.46
2,2-Dichloropropane GW NS NS
2-Butanone (MEK)GW EPA Tapwater RSL 5600
2-Chlorotoluene GW EPA Tapwater RSL 240
2-Hexanone GW EPA Tapwater RSL 38
4-Chlorotoluene GW EPA Tapwater RSL 250
4-Methyl-2-pentanone (MIBK)GW NS NS
Acetone GW EPA Tapwater RSL 14,000
Benzene GW EPA Tapwater RSL 0.46
Bromobenzene GW EPA Tapwater RSL 62
Bromochloromethane GW EPA Tapwater RSL 83
Bromodichloromethane GW EPA Tapwater RSL 0.13
Bromoform GW EPA Tapwater RSL 3.3
Bromomethane GW EPA Tapwater RSL 7.5
Carbon disulfide GW EPA Tapwater RSL 810
Carbon Tetrachloride GW EPA Tapwater RSL 0.46
Chlorobenzene GW EPA Tapwater RSL 78
Chloroethane GW EPA Tapwater RSL 21,000
Chloroform GW EPA Tapwater RSL 0.22
Sample ID:
Location:
Sample Date:
Sample Type:
S13-CAM-DW1 S-140-17 S-141-17 S-142-17 S-150-20 S-38-90
S-139-17-052023 S-139-17-05-2023D S13-CAM-DW1-052023 S-140-17-052023 S-141-17-052023 S-142-17-052023 S-150-20-052023 S-38-90-052023 S-40-90-052023 S-40-90-05-2023D
5/12/2023 11:40:00 AM 5/12/2023 11:45:00 AM 5/15/2023 11:35:00 AM 5/11/2023 10:40:00 AM 5/8/2023 10:50:00 AM 5/9/2023 11:35:00 AM 5/17/2023 11:05:00 AM 5/17/2023 10:05:00 AM 5/17/2023 11:50:00 AM 5/17/2023 11:55:00 AM
N FD N N N N N N N FD
NA NA 220 U NA NA NA NA NA NA NA
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.120 J 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.630 J 0.660 J
0.400 J+0.380 J+0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 1.50 1.40
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U 0.300 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U 0.300 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
50.0 U 50.0 U 50.0 UJ 50.0 U 50.0 UJ 50.0 U 50.0 U 50.0 U 50.0 U 50.0 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
10.0 U 10.0 U 10.0 UJ 10.0 U 10.0 UJ 10.0 U 10.0 U 10.0 U 10.0 U 10.0 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
5.00 U 5.00 U 5.00 UJ 5.00 U 5.00 UJ 5.00 U 5.00 U 5.00 U 5.00 U 5.00 U
10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.330 J+0.330 J+0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U 0.300 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.220 J 0.200 U 0.200 U 0.200 U
0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U 0.300 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
1.70 J+1.80 J+0.500 UJ 0.500 U 0.500 UJ 0.290 J 0.500 U 0.500 U 0.500 U 0.500 U
29000 28000 0.200 UJ 18.0 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
1.00 U 1.00 U 1.00 UJ 1.00 U 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U
680 690 0.200 UJ 2.50 0.200 UJ 0.200 U 0.540 J 0.250 J 1.00 1.00
S-139-17 S-40-90
Page 3 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
Sample ID:
Location:
Sample Date:
Sample Type:
Chloromethane GW EPA Tapwater RSL 190
cis-1,2-Dichloroethene GW EPA Tapwater RSL 36
cis-1,3-Dichloropropene GW NS NS
Cumene GW EPA Tapwater RSL 45
Dibromochloromethane GW EPA Tapwater RSL 0.87
Dibromomethane GW EPA Tapwater RSL 8.3
Dichlorodifluoromethane GW EPA Tapwater RSL 200
Ethylbenzene GW EPA Tapwater RSL 1.5
m,p-Xylene GW EPA Tapwater RSL 190
Methyl tert-butyl ether (MTBE)GW EPA Tapwater RSL 14
Methylene chloride GW EPA MCL 5
n-Butylbenzene GW EPA Tapwater RSL 1,000
n-Propylbenzene GW EPA Tapwater RSL 660
o-Xylene GW EPA Tapwater RSL 190
p-Cymene (p-Isopropyltoluene)GW NS NS
sec-Butylbenzene GW EPA Tapwater RSL 2,000
Styrene GW EPA MCL 100
tert-Butylbenzene GW EPA Tapwater RSL 690
Tetrachloroethene (PCE)GW EPA MCL 5
Toluene GW EPA MCL 100
trans-1,2-Dichloroethene GW EPA Tapwater RSL 68
trans-1,3-Dichloropropene GW NS NS
Trichloroethene (TCE)GW EPA Tapwater RSL 0.49
Trichlorofluoromethane GW EPA Tapwater RSL 5,200
Vinyl chloride GW EPA Tapwater RSL 0.019
EB – equipment blank
GW – groundwater
N – normal
NS – not specified
PAL – project action limit
QC – quality control
TB – trip blank
2PAL is the most stringent of the EPA MCL or the May 2021 EPA tap water RSLs (based on a cancer risk of 1E-06 or a target quotient of 1.0)
Detected results appear in bold font
Notes:
1State of Utah LUST Tier 1 screening level
Highlighted cells indicate detections that exceed the selected screening level.
µg/L – micrograms per liter
EPA – U.S. Environmental Protection Agency
FD – field duplicate
J – The reported result is an estimated value.
J- – The analyte is considered an estimated value with a possible low-bias due to a QC deviation.
MCL – maximum contaminant level
U – Not detected; the compound/analyte was analyzed for, but not detected above the Limit of Detection (LOD) unless otherwise noted
UJ – The analyte was not detected; however, the result is estimated because of discrepancies in meeting certain analyte-specific QC criteria.
VOC – volatile organic compounds
S13-CAM-DW1 S-140-17 S-141-17 S-142-17 S-150-20 S-38-90
S-139-17-052023 S-139-17-05-2023D S13-CAM-DW1-052023 S-140-17-052023 S-141-17-052023 S-142-17-052023 S-150-20-052023 S-38-90-052023 S-40-90-052023 S-40-90-05-2023D
5/12/2023 11:40:00 AM 5/12/2023 11:45:00 AM 5/15/2023 11:35:00 AM 5/11/2023 10:40:00 AM 5/8/2023 10:50:00 AM 5/9/2023 11:35:00 AM 5/17/2023 11:05:00 AM 5/17/2023 10:05:00 AM 5/17/2023 11:50:00 AM 5/17/2023 11:55:00 AM
N FD N N N N N N N FD
S-139-17 S-40-90
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.160 J 0.200 U 0.200 U 0.200 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U 0.300 U
4.30 J+4.20 J+1.00 UJ 1.00 U 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 U 1.00 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
24.0 J+24.0 J+0.300 UJ 0.190 J 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U 0.300 U
0.200 U 0.200 U 0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.120 J+0.110 J+0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
4.50 J+4.60 J+0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 U 0.200 U
0.500 U 0.500 U 0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 U 0.500 U
0.300 U 0.300 U 0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 U 0.300 U
Page 4 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
Total Petroleum Hydrocarbons (µg/L)Matrix Screening Limit Type1 PAL
TPH-DRO GW UT LUST Tier 1 10,000
VOC (µg/L)Matrix Screening Limit Type1 PAL
1,1,1,2-Tetrachloroethane GW EPA Tapwater RSL 0.57
1,1,1-Trichloroethane GW EPA MCL 200
1,1,2,2-Tetrachloroethane GW EPA Tapwater RSL 0.076
1,1,2-Trichloroethane GW EPA Tapwater RSL 0.28
1,1-Dichloroethane GW EPA Tapwater RSL 2.8
1,1-Dichloroethene GW EPA MCL 7
1,1-Dichloropropene GW NS NS
1,2,3-Trichlorobenzene GW EPA Tapwater RSL 7
1,2,3-Trichloropropane GW EPA Tapwater RSL 0.00075
1,2,4-Trichlorobenzene GW EPA Tapwater RSL 1.2
1,2-Dibromo-3-chloropropane GW EPA Tapwater RSL 0.00033
1,2-Dibromoethane (EDB)GW EPA Tapwater RSL 0.0075
1,2-Dichlorobenzene GW EPA Tapwater RSL 300
1,2-Dichloroethane GW EPA Tapwater RSL 0.17
1,2-Dichloropropane GW EPA Tapwater RSL 0.85
1,3-Dichlorobenzene GW NS NS
1,3-Dichloropropane GW EPA Tapwater RSL 370
1,4-Dichlorobenzene GW EPA Tapwater RSL 0.48
1,4-Dioxane GW EPA Tapwater RSL 0.46
2,2-Dichloropropane GW NS NS
2-Butanone (MEK)GW EPA Tapwater RSL 5600
2-Chlorotoluene GW EPA Tapwater RSL 240
2-Hexanone GW EPA Tapwater RSL 38
4-Chlorotoluene GW EPA Tapwater RSL 250
4-Methyl-2-pentanone (MIBK)GW NS NS
Acetone GW EPA Tapwater RSL 14,000
Benzene GW EPA Tapwater RSL 0.46
Bromobenzene GW EPA Tapwater RSL 62
Bromochloromethane GW EPA Tapwater RSL 83
Bromodichloromethane GW EPA Tapwater RSL 0.13
Bromoform GW EPA Tapwater RSL 3.3
Bromomethane GW EPA Tapwater RSL 7.5
Carbon disulfide GW EPA Tapwater RSL 810
Carbon Tetrachloride GW EPA Tapwater RSL 0.46
Chlorobenzene GW EPA Tapwater RSL 78
Chloroethane GW EPA Tapwater RSL 21,000
Chloroform GW EPA Tapwater RSL 0.22
Sample ID:
Location:
Sample Date:
Sample Type:
S-55-90 S-67-90 S-68-90 S-70-90 S-71-90 S-78-91 S-93-92 S-95-92 S-97-92
S-55-90-052023 S-67-90-052023 S-68-90-052023 S-70-90-052023 S-71-90-052023 S-78-91-052023 S-91-91-052023 S-91-91-05-2023D S-93-92-052023 S-95-92-052023 S-97-92-052023
5/16/2023 9:15:00 AM 5/3/2023 12:05:00 PM 5/4/2023 10:15:00 AM 5/4/2023 11:10:00 AM 5/4/2023 1:05:00 PM 5/16/2023 11:05:00 AM 5/15/2023 1:30:00 PM 5/15/2023 1:35:00 PM 5/5/2023 10:05:00 AM 5/3/2023 2:20:00 PM 5/5/2023 11:37:00 AM
N N N N N N N FD N N N
220 U NA NA NA NA 220 U 200 U 210 U NA NA NA
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.180 J 0.170 J 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.300 U 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.300 U 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
50.0 U 50.0 UJ 50.0 UJ 50.0 UJ 50.0 UJ 50.0 U 50.0 U 50.0 U 50.0 UJ 50.0 UJ 50.0 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
10.0 U 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 U 10.0 U 10.0 U 10.0 UJ 10.0 UJ 10.0 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
5.00 U 5.00 UJ 5.00 UJ 5.00 UJ 5.00 UJ 5.00 U 5.00 U 5.00 U 5.00 UJ 5.00 UJ 5.00 UJ
10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.300 U 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.300 U 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
1.00 U 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 UJ 1.00 UJ
1.00 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
S-91-91
Page 5 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
Sample ID:
Location:
Sample Date:
Sample Type:
Chloromethane GW EPA Tapwater RSL 190
cis-1,2-Dichloroethene GW EPA Tapwater RSL 36
cis-1,3-Dichloropropene GW NS NS
Cumene GW EPA Tapwater RSL 45
Dibromochloromethane GW EPA Tapwater RSL 0.87
Dibromomethane GW EPA Tapwater RSL 8.3
Dichlorodifluoromethane GW EPA Tapwater RSL 200
Ethylbenzene GW EPA Tapwater RSL 1.5
m,p-Xylene GW EPA Tapwater RSL 190
Methyl tert-butyl ether (MTBE)GW EPA Tapwater RSL 14
Methylene chloride GW EPA MCL 5
n-Butylbenzene GW EPA Tapwater RSL 1,000
n-Propylbenzene GW EPA Tapwater RSL 660
o-Xylene GW EPA Tapwater RSL 190
p-Cymene (p-Isopropyltoluene)GW NS NS
sec-Butylbenzene GW EPA Tapwater RSL 2,000
Styrene GW EPA MCL 100
tert-Butylbenzene GW EPA Tapwater RSL 690
Tetrachloroethene (PCE)GW EPA MCL 5
Toluene GW EPA MCL 100
trans-1,2-Dichloroethene GW EPA Tapwater RSL 68
trans-1,3-Dichloropropene GW NS NS
Trichloroethene (TCE)GW EPA Tapwater RSL 0.49
Trichlorofluoromethane GW EPA Tapwater RSL 5,200
Vinyl chloride GW EPA Tapwater RSL 0.019
EB – equipment blank
GW – groundwater
N – normal
NS – not specified
PAL – project action limit
QC – quality control
TB – trip blank
2PAL is the most stringent of the EPA MCL or the May 2021 EPA tap water RSLs (based on a cancer risk of 1E-06 or a target quotient of 1.0)
Detected results appear in bold font
Notes:
1State of Utah LUST Tier 1 screening level
Highlighted cells indicate detections that exceed the selected screening level.
µg/L – micrograms per liter
EPA – U.S. Environmental Protection Agency
FD – field duplicate
J – The reported result is an estimated value.
J- – The analyte is considered an estimated value with a possible low-bias due to a QC deviation.
MCL – maximum contaminant level
U – Not detected; the compound/analyte was analyzed for, but not detected above the Limit of Detection (LOD) unless otherwise noted
UJ – The analyte was not detected; however, the result is estimated because of discrepancies in meeting certain analyte-specific QC criteria.
VOC – volatile organic compounds
S-55-90 S-67-90 S-68-90 S-70-90 S-71-90 S-78-91 S-93-92 S-95-92 S-97-92
S-55-90-052023 S-67-90-052023 S-68-90-052023 S-70-90-052023 S-71-90-052023 S-78-91-052023 S-91-91-052023 S-91-91-05-2023D S-93-92-052023 S-95-92-052023 S-97-92-052023
5/16/2023 9:15:00 AM 5/3/2023 12:05:00 PM 5/4/2023 10:15:00 AM 5/4/2023 11:10:00 AM 5/4/2023 1:05:00 PM 5/16/2023 11:05:00 AM 5/15/2023 1:30:00 PM 5/15/2023 1:35:00 PM 5/5/2023 10:05:00 AM 5/3/2023 2:20:00 PM 5/5/2023 11:37:00 AM
N N N N N N N FD N N N
S-91-91
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.300 U 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 UJ
1.00 U 1.00 UJ 1.00 UJ 1.00 UJ 1.00 UJ 1.00 U 1.00 U 1.00 U 1.00 UJ 1.00 UJ 1.00 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.300 U 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.200 U 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.200 U 0.200 UJ 0.200 UJ 0.200 UJ 0.200 UJ 0.500 J 0.200 U 0.200 U 0.200 UJ 0.200 UJ 0.200 UJ
0.500 U 0.500 UJ 0.500 UJ 0.500 UJ 0.500 UJ 0.500 U 0.500 U 0.500 U 0.500 UJ 0.500 UJ 0.500 UJ
0.300 U 0.300 UJ 0.300 UJ 0.300 UJ 0.300 UJ 0.300 U 0.300 U 0.300 U 0.300 UJ 0.300 UJ 0.300 UJ
Page 6 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
Total Petroleum Hydrocarbons (µg/L)Matrix Screening Limit Type1 PAL
TPH-DRO GW UT LUST Tier 1 10,000
VOC (µg/L)Matrix Screening Limit Type1 PAL
1,1,1,2-Tetrachloroethane GW EPA Tapwater RSL 0.57
1,1,1-Trichloroethane GW EPA MCL 200
1,1,2,2-Tetrachloroethane GW EPA Tapwater RSL 0.076
1,1,2-Trichloroethane GW EPA Tapwater RSL 0.28
1,1-Dichloroethane GW EPA Tapwater RSL 2.8
1,1-Dichloroethene GW EPA MCL 7
1,1-Dichloropropene GW NS NS
1,2,3-Trichlorobenzene GW EPA Tapwater RSL 7
1,2,3-Trichloropropane GW EPA Tapwater RSL 0.00075
1,2,4-Trichlorobenzene GW EPA Tapwater RSL 1.2
1,2-Dibromo-3-chloropropane GW EPA Tapwater RSL 0.00033
1,2-Dibromoethane (EDB)GW EPA Tapwater RSL 0.0075
1,2-Dichlorobenzene GW EPA Tapwater RSL 300
1,2-Dichloroethane GW EPA Tapwater RSL 0.17
1,2-Dichloropropane GW EPA Tapwater RSL 0.85
1,3-Dichlorobenzene GW NS NS
1,3-Dichloropropane GW EPA Tapwater RSL 370
1,4-Dichlorobenzene GW EPA Tapwater RSL 0.48
1,4-Dioxane GW EPA Tapwater RSL 0.46
2,2-Dichloropropane GW NS NS
2-Butanone (MEK)GW EPA Tapwater RSL 5600
2-Chlorotoluene GW EPA Tapwater RSL 240
2-Hexanone GW EPA Tapwater RSL 38
4-Chlorotoluene GW EPA Tapwater RSL 250
4-Methyl-2-pentanone (MIBK)GW NS NS
Acetone GW EPA Tapwater RSL 14,000
Benzene GW EPA Tapwater RSL 0.46
Bromobenzene GW EPA Tapwater RSL 62
Bromochloromethane GW EPA Tapwater RSL 83
Bromodichloromethane GW EPA Tapwater RSL 0.13
Bromoform GW EPA Tapwater RSL 3.3
Bromomethane GW EPA Tapwater RSL 7.5
Carbon disulfide GW EPA Tapwater RSL 810
Carbon Tetrachloride GW EPA Tapwater RSL 0.46
Chlorobenzene GW EPA Tapwater RSL 78
Chloroethane GW EPA Tapwater RSL 21,000
Chloroform GW EPA Tapwater RSL 0.22
Sample ID:
Location:
Sample Date:
Sample Type:
Equipment Blank Equipment Blank Trip Blank Trip Blank Trip Blank Trip Blank
SWMU-1/25-EB-052023 SWMU-13-EB-052023 TB-20230503-1/25 TB-20230509-1/25 TB-20230515-13 TB-20230517-26
5/3/2023 9:15:00 AM 5/15/2023 9:00:00 AM 5/3/2023 7:30:00 AM 5/9/2023 7:30:00 AM 5/15/2023 7:30:00 AM 5/17/2023 7:30:00 AM
EB EB TB TB TB TB
NA 200 U NA NA NA NA
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
50.0 UJ 50.0 U 50.0 UJ 50.0 U 50.0 U 50.0 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
10.0 UJ 10.0 U 10.0 UJ 10.0 U 10.0 U 10.0 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
5.00 UJ 5.00 U 5.00 UJ 5.00 U 5.00 U 5.00 U
5.80 J 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ 10.0 UJ
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
1.00 UJ 1.00 U 1.00 UJ 1.00 U 1.00 U 1.00 U
0.180 J 0.170 J 0.200 UJ 0.200 U 0.200 U 0.200 U
Page 7 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
Sample ID:
Location:
Sample Date:
Sample Type:
Chloromethane GW EPA Tapwater RSL 190
cis-1,2-Dichloroethene GW EPA Tapwater RSL 36
cis-1,3-Dichloropropene GW NS NS
Cumene GW EPA Tapwater RSL 45
Dibromochloromethane GW EPA Tapwater RSL 0.87
Dibromomethane GW EPA Tapwater RSL 8.3
Dichlorodifluoromethane GW EPA Tapwater RSL 200
Ethylbenzene GW EPA Tapwater RSL 1.5
m,p-Xylene GW EPA Tapwater RSL 190
Methyl tert-butyl ether (MTBE)GW EPA Tapwater RSL 14
Methylene chloride GW EPA MCL 5
n-Butylbenzene GW EPA Tapwater RSL 1,000
n-Propylbenzene GW EPA Tapwater RSL 660
o-Xylene GW EPA Tapwater RSL 190
p-Cymene (p-Isopropyltoluene)GW NS NS
sec-Butylbenzene GW EPA Tapwater RSL 2,000
Styrene GW EPA MCL 100
tert-Butylbenzene GW EPA Tapwater RSL 690
Tetrachloroethene (PCE)GW EPA MCL 5
Toluene GW EPA MCL 100
trans-1,2-Dichloroethene GW EPA Tapwater RSL 68
trans-1,3-Dichloropropene GW NS NS
Trichloroethene (TCE)GW EPA Tapwater RSL 0.49
Trichlorofluoromethane GW EPA Tapwater RSL 5,200
Vinyl chloride GW EPA Tapwater RSL 0.019
EB – equipment blank
GW – groundwater
N – normal
NS – not specified
PAL – project action limit
QC – quality control
TB – trip blank
2PAL is the most stringent of the EPA MCL or the May 2021 EPA tap water RSLs (based on a cancer risk of 1E-06 or a target quotient of 1.0)
Detected results appear in bold font
Notes:
1State of Utah LUST Tier 1 screening level
Highlighted cells indicate detections that exceed the selected screening level.
µg/L – micrograms per liter
EPA – U.S. Environmental Protection Agency
FD – field duplicate
J – The reported result is an estimated value.
J- – The analyte is considered an estimated value with a possible low-bias due to a QC deviation.
MCL – maximum contaminant level
U – Not detected; the compound/analyte was analyzed for, but not detected above the Limit of Detection (LOD) unless otherwise noted
UJ – The analyte was not detected; however, the result is estimated because of discrepancies in meeting certain analyte-specific QC criteria.
VOC – volatile organic compounds
Equipment Blank Equipment Blank Trip Blank Trip Blank Trip Blank Trip Blank
SWMU-1/25-EB-052023 SWMU-13-EB-052023 TB-20230503-1/25 TB-20230509-1/25 TB-20230515-13 TB-20230517-26
5/3/2023 9:15:00 AM 5/15/2023 9:00:00 AM 5/3/2023 7:30:00 AM 5/9/2023 7:30:00 AM 5/15/2023 7:30:00 AM 5/17/2023 7:30:00 AM
EB EB TB TB TB TB
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U
1.00 UJ 1.00 U 1.00 UJ 1.00 U 1.00 U 1.00 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U
0.110 J 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.200 UJ 0.200 U 0.200 UJ 0.200 U 0.200 U 0.200 U
0.500 UJ 0.500 U 0.500 UJ 0.500 U 0.500 U 0.500 U
0.300 UJ 0.300 U 0.300 UJ 0.300 U 0.300 U 0.300 U
Page 8 of 8
Data Summary Table
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
ATTACHMENT E-3
FIELD DUPLICATE PRECISION REPORT
This page intentionally blank
S-135-16-052023 S-139-17-052023 S-91-91-052023 S-40-90-052023
23E120-06 23E120-09 23E133-04 23E135-04
5/10/2023 5/12/2023 5/15/2023 5/17/2023
Primary Primary Primary Primary
SW8015D Units Result Result RPD (%)Result Result RPD (%)Result Result RPD (%)Result Result RPD (%)
TPH-DRO µg/L ------------200 U 210 U NC ------
SW8260C
1,1,1,2-Tetrachloroethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,1,1-Trichloroethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,1,2,2-Tetrachloroethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,1,2-Trichloroethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,1-Dichloroethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.18 J 0.17 J NC 0.63 J 0.66 J NC
1,1-Dichloroethene µg/L 0.20 U 0.20 U NC 0.40 J 0.38 J NC 0.20 U 0.20 U NC 1.5 1.4 6.90
1,1-Dichloropropene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,2,3-Trichlorobenzene µg/L 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC
1,2,3-Trichloropropane µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
1,2,4-Trichlorobenzene µg/L 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC
1,2-Dibromo-3-chloropropane µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
1,2-Dibromoethane (EDB)µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,2-Dichlorobenzene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,2-Dichloroethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,2-Dichloropropane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,3-Dichlorobenzene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,3-Dichloropropane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,4-Dichlorobenzene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
1,4-Dioxane µg/L 50 U 50 U NC 50 U 50 U NC 50 U 50 U NC 50 U 50 U NC
2,2-Dichloropropane µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
2-Butanone (MEK)µg/L 10 UJ 10 UJ NC 10 UJ 10 UJ NC 10 UJ 10 UJ NC 10 UJ 10 UJ NC
2-Chlorotoluene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
2-Hexanone µg/L 10 U 10 U NC 10 U 10 U NC 10 U 10 U NC 10 U 10 U NC
4-Chlorotoluene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
4-Methyl-2-pentanone (MIBK) µg/L 5.0 U 5.0 U NC 5.0 U 5.0 U NC 5.0 U 5.0 U NC 5.0 U 5.0 U NC
Acetone µg/L 10 UJ 10 UJ NC 10 UJ 10 UJ NC 10 UJ 10 UJ NC 10 UJ 10 UJ NC
Benzene µg/L 0.20 U 0.20 U NC 0.33 J 0.33 J NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Bromobenzene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Bromochloromethane µg/L 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC
Bromodichloromethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Bromoform µg/L 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC
Bromomethane µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
Carbon disulfide µg/L 0.50 U 0.50 U NC 1.7 J 1.8 J NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
Carbon Tetrachloride µg/L 18 19 5.41 29000 28000 3.51 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Chlorobenzene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Chloroethane µg/L 1.0 U 1.0 U NC 1.0 U 1.0 U NC 1.0 U 1.0 U NC 1.0 U 1.0 U NC
Chloroform µg/L 1.4 1.4 0.00 680 690 1.46 0.20 U 0.20 U NC 1.0 1.0 0.00
Chloromethane µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
cis-1,2-Dichloroethene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
cis-1,3-Dichloropropene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Cumene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Dibromochloromethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Dibromomethane µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Dichlorodifluoromethane µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
Ethylbenzene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
m,p-Xylene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
S-40-90Location
23E120-08 23E133-03
Field Sample ID S-135-16-05-2023D S-139-17-05-2023D S-91-91-05-2023D
S-135-16 S-139-17
5/17/2023
Field QC Field Duplicate Field Duplicate Field Duplicate Field Duplicate
Sample Date 5/10/2023 5/12/2023 5/15/2023
23E135-03Lab Sample ID 23E120-05
S-40-90-05-2023D
S-91-91
Page 1 of 2
Field Duplicate Precision Report
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah
S-135-16-052023 S-139-17-052023 S-91-91-052023 S-40-90-052023
23E120-06 23E120-09 23E133-04 23E135-04
5/10/2023 5/12/2023 5/15/2023 5/17/2023
Primary Primary Primary Primary
S-40-90Location
23E120-08 23E133-03
Field Sample ID S-135-16-05-2023D S-139-17-05-2023D S-91-91-05-2023D
S-135-16 S-139-17
5/17/2023
Field QC Field Duplicate Field Duplicate Field Duplicate Field Duplicate
Sample Date 5/10/2023 5/12/2023 5/15/2023
23E135-03Lab Sample ID 23E120-05
S-40-90-05-2023D
S-91-91
Methyl tert-butyl ether (MTBE) µg/L 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC
Methylene chloride µg/L 1.0 U 1.0 U NC 4.3 J 4.2 J NC 1.0 U 1.0 U NC 1.0 U 1.0 U NC
n-Butylbenzene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
n-Propylbenzene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
o-Xylene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
p-Cymene (p-Isopropyltoluene) µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
sec-Butylbenzene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
Styrene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
tert-Butylbenzene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
Tetrachloroethene (PCE)µg/L 0.30 U 0.30 U NC 24 J 24 J NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC
Toluene µg/L 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
trans-1,2-Dichloroethene µg/L 0.20 U 0.20 U NC 0.12 J 0.11 J NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
trans-1,3-Dichloropropene µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
Trichloroethene (TCE)µg/L 0.20 U 0.20 U NC 4.5 J 4.6 J NC 0.20 U 0.20 U NC 0.20 U 0.20 U NC
Trichlorofluoromethane µg/L 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC 0.50 U 0.50 U NC
Vinyl chloride µg/L 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC 0.30 U 0.30 U NC
Notes:
Bolded result indicates a detection.
Shaded cells identify any compounds that were above the acceptable RPD limit.
J - Detected, Estimated
UJ - Compound was not detected and reporting limit is estimated
U - Compound
Page 2 of 2
Field Duplicate Precision Report
2023 Annual Groundwater Monitoring Report
Tooele Army Depot South, Utah

ATTACHMENT E-4
DATA VALIDATION REPORTS

This page intentionally blank
Data Validation Report for 23E081
SDG:
Facility:
Guidance Document:
Event:
Data Review Contractor:
Data Review Level:
23E081
USAEC, TEAD-S
FINAL Uniform Federal Policy - Quality Assurance Project Plan Tooele Army
Depot South, Utah, October 2021
TEAD-S 2023 Annual Monitoring Groundwater
Synectics, Sacramento, CA
S4VEM
Project Manager:
Date Submitted:
Andrew Castor
August 07, 2023
Primary Data Reviewer:Kathryn Cantone, Data Review Chemist
Field Sample ID Lab Sample ID Matrix Type/Type Code SW
8
2
6
0
C
S-129-15-052023 23E081-01 Water Field Sample/N X
S-137-16-052023 23E081-02 Water Field Sample/N X
S-138-16-052023 23E081-03 Water Field Sample/N X
S-141-17-052023 23E081-04 Water Field Sample/N X
S-67-90-052023 23E081-05 Water Field Sample/N X
S-68-90-052023 23E081-06 Water Field Sample/N X
S-70-90-052023 23E081-07 Water Field Sample/N X
S-71-90-052023 23E081-08 Water Field Sample/N X
S-93-92-052023 23E081-09 Water Field Sample/N X
S-95-92-052023 23E081-10 Water Field Sample/N X
S-97-92-052023 23E081-11 Water Field Sample/N X
SWMU-1/25-EB-052023 23E081-12 Water Equipment Blank/EB X
TB-20230503-1/25 23E081-13 Water Trip Blank/TB X
Second Reviewer:Evin McKinney, Senior Scientist
Contract Laboratory(ies):EMAX Laboratories, Inc., Torrance, CA
Prime Contractor:Brice Environmental Services Corporation, Salt Lake City, UT (BRSS)
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Data Validation Report for 23E081
This report assesses the analytical data quality associated with the analyses listed on the preceding cover
page at S4VEM data validation level. This assessment has been made through a combination of automated
data review (ADR) and supplemental manual review, the details of which are described below. The approach
taken in the review of this data set is consistent with the requirements contained in the FINAL Uniform Federal
Policy - Quality Assurance Project Plan Tooele Army Depot South, Utah, October 2021 and the additional
guidance documents incorporated by reference to the extent possible. Where definitive guidance is not
provided, results have been evaluated in a conservative manner using professional judgment.
Sample collection was managed and directed by Brice Environmental Services Corporation, Salt Lake City, UT
(BRSS); analyses were performed by EMAX Laboratories, Inc., Torrance, CA and were reported under sample
delivery group (SDG) 23E081. Data have been evaluated electronically based on electronic data deliverables
(EDDs) provided by the laboratory, and hard copy data summary forms have also been reviewed during this
effort and compared to the automated review output by the reviewers whose signatures appear on the
following page. Findings based on the automated data submission and manual data verification processes are
detailed in the ADR narrative and throughout this report.
All quality control (QC) elements associated with this SDG have been reviewed by a project chemist in
accordance with the requirements defined for the project. This review is documented in the attached Data
Review Checklists. The QC elements listed below were supported by the electronic deliverable and were
evaluated using ADR processes.
Results of the ADR process were subsequently reviewed and updated as applicable by the data review
chemists identified on the signature page. Quality control elements that were not included in the electronic
deliverable were reviewed manually and findings are documented within this report. Summaries of findings
and associated qualified results are documented throughout this report.
A total of 806 results (100.00%) out of the 806 results (sample and field QC samples) reported are qualified
based on review and 0 results (0.00%) have been rejected or deemed a serious deficiency (X qualifier). Trace
values, defined as results that are qualified as estimated because they fall between the detection limit and the
reporting limit/limit of quantitation, are not counted as qualified results in the above count. The qualified
results are detailed throughout this report and discussed in the narrative below, where appropriate.
Continuing Calibration Verification
Equipment Blank
Lab Blank
LCS Recovery
LCS RPD
MS Recovery
MS RPD
Prep Hold Time
Surrogate
Test Hold Time
Trip Blank
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Data Validation Report for 23E081
Samples 23E081-01 and 02 underwent S4VEM and the remaining samples S2BVEM.
The laboratory noted that corrections on the sample labels were not dated. The samples were logged
according to the CoC
Analytical Method Data Reviewer Comment
SW8260C The laboratory noted the following:
The Minimum Response Factor for all analytes were within method recommended
response factors with the exception of Acetone and 2-Butanone.
The MS/MSD recoveries were outside QC limits.
Narrative Comments
Reviewed by Kathryn Cantone, Data Review Chemist, Synectics,
Sacramento, CA
July 18, 2023
Reviewed by Evin McKinney, Senior Scientist, Synectics,
Sacramento, CA
August 07, 2023
As the First Reviewer, I certify that I have performed a data review process in accordance with the
requirements of the project guidance document, and have compared the electronic data to the laboratory's
hard copy report and have verified the consistency of the reported sample results and method quality control
data between the two deliverables.
As the Second Reviewer, I certify that I have performed a quality assurance review of the report generated
by the First Reviewer.
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Data Validation Report for 23E081
Quality Control Outliers for test method SW8260C, Continuing Calibration Verification RRF
Compliance requirements for satisfactory continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
CV067D2613 ()2-Butanone (MEK)0.0130 > 0.1 > 0.1 rf J/UJ V3
CV067D2613 ()Acetone 0.0440 > 0.1 > 0.1 rf J/UJ V3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Continuing Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-129-15-052023
23E081-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-129-15-052023
23E081-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-95-92-052023
23E081-10 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
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Data Validation Report for 23E081
Qualified Results associated with the Continuing Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-95-92-052023
23E081-10 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB Acetone 20 5.8 J 5.8 J ug/l G1/G3/TR/V3/V5
/Z6
TB-20230503-1/25
23E081-13 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
TB-20230503-1/25
23E081-13 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E081
Quality Control Outliers for test method SW8260C, Ending Continuing Calibration Verification
Compliance requirements for satisfactory closing continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
EV067D2613 (EV)2-Butanone (MEK)0.0130 < 0.1 < 0.1 rf J/UJ V5
EV067D2613 (EV)Acetone 0.0430 < 0.1 < 0.1 rf J/UJ V5
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Ending Continuing Calibration Verification for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-129-15-052023
23E081-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-129-15-052023
23E081-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-95-92-052023
23E081-10 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
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Data Validation Report for 23E081
Qualified Results associated with the Ending Continuing Calibration Verification for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-95-92-052023
23E081-10 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB Acetone 20 5.8 J 5.8 J ug/l G1/G3/TR/V3/V5
/Z6
TB-20230503-1/25
23E081-13 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
TB-20230503-1/25
23E081-13 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E081
Quality Control Outliers for test method SW8260C, Equipment Blank
The purpose of equipment blanks is to determine the existence and magnitude of cross-contamination problems resulting from the process
during sampling. Reported results were evaluated to determine compliance with the required acceptance criteria. Summary forms were
evaluated and compared to electronic data deliverables. Findings of this review, and contaminants found in equipment blanks are listed
below along with any associated qualified results.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
SWMU-1/25-EB-052023 (EB)Acetone 5.80 < 5 < 20 ug/l U/None*V
SWMU-1/25-EB-052023 (EB)Chloroform 0.180 < 0.1 < 1 ug/l U/None*V
SWMU-1/25-EB-052023 (EB)Toluene 0.110 < 0.1 < 1 ug/l U/None*V
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
*Blank flags displayed in the above table identify qualification of the sample result when it is less than or equal to the LOQ/RL. Sample
results above the LOD or LOQ will be qualified based on the validation guidance assigned in the project setup.
Qualified Results associated with the Equipment Blank for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-138-16-052023
23E081-03 N Chloroform 1.0 0.14 J 0.20 UJ ug/l V/Z6
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E081
Quality Control Outliers for test method SW8260C, Initial Calibration RRF
Compliance requirements for satisfactory initial calibration are established to ensure that the instrument is capable of producing acceptable
qualitative and quantitative data. Initial calibration is performed to verify and evaluate instrument performance prior to sample analysis.
Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
CAL 04/26/23 Inst 67 ()2-Butanone (MEK)0.0130 > 0.1 > 0.1 rf J/UJ G1
ICAL 04/26/23 Inst 67 ()Acetone 0.0400 > 0.1 > 0.1 rf J/UJ G1
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-129-15-052023
23E081-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-129-15-052023
23E081-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-95-92-052023
23E081-10 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
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Data Validation Report for 23E081
Qualified Results associated with the Initial Calibration RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-95-92-052023
23E081-10 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB Acetone 20 5.8 J 5.8 J ug/l G1/G3/TR/V3/V5
/Z6
TB-20230503-1/25
23E081-13 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
TB-20230503-1/25
23E081-13 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E081
Quality Control Outliers for test method SW8260C, Initial Calibration Verification RRF
Compliance requirements for satisfactory initial calibration verifications are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Initil calibration verification is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
ICV:RDC593 ()2-Butanone (MEK)0.0120 < 0.1 < 0.1 tf J/UJ G3
ICV:RDC593 ()Acetone 0.0360 < 0.1 < 0.1 rf J/UJ G3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-129-15-052023
23E081-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-129-15-052023
23E081-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-137-16-052023
23E081-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-138-16-052023
23E081-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-141-17-052023
23E081-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-67-90-052023
23E081-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-68-90-052023
23E081-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-70-90-052023
23E081-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-71-90-052023
23E081-08 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-93-92-052023
23E081-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-95-92-052023
23E081-10 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
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Data Validation Report for 23E081
Qualified Results associated with the Initial Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-95-92-052023
23E081-10 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
S-97-92-052023
23E081-11 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB Acetone 20 5.8 J 5.8 J ug/l G1/G3/TR/V3/V5
/Z6
TB-20230503-1/25
23E081-13 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
TB-20230503-1/25
23E081-13 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/Z6
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E081
Quality Control Outliers for test method SW8260C, MS Recovery
Data for matrix spikes/matrix spike duplicates (MS/MSD) are generated to determine long-term precision and accuracy of the analytical
method on various matrices and to demonstrate acceptable compound recovery by the laboratory at the time of sample analysis. These
data alone cannot be used to evaluate the precision and accuracy of individual samples. However, when exercising professional judgment,
MS/MSD data can be used in conjunction with other available QC information. Reported results were evaluated to determine compliance
with the required acceptance criteria, and summary forms were evaluated and compared to electronic data deliverables. Findings of this
review, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
S-68-90-052023 (MS)Styrene 37.0 78 - 123 10 - 123 percent J/UJ M
S-68-90-052023 (SD)Styrene 39.0 78 - 123 10 - 123 percent J/UJ M
S-70-90-052023 (MS)Styrene 30.0 78 - 123 10 - 123 percent J/UJ M
S-70-90-052023 (SD)Styrene 26.0 78 - 123 10 - 123 percent J/UJ M
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the MS Recovery for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-68-90-052023
23E081-06 N Styrene 1.0 0.50 U 0.50 UJ ug/l M/Z6
S-70-90-052023
23E081-07 N Styrene 1.0 0.50 U 0.50 UJ ug/l M/Z6
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-129-15-052023
23E081-01 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-129-15-052023
23E081-01 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-129-15-052023
23E081-01 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-129-15-052023
23E081-01 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-129-15-052023
23E081-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-129-15-052023
23E081-01 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-129-15-052023
23E081-01 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-129-15-052023
23E081-01 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-129-15-052023
23E081-01 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-129-15-052023
23E081-01 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-129-15-052023
23E081-01 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-129-15-052023
23E081-01 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-129-15-052023
23E081-01 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-129-15-052023
23E081-01 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-129-15-052023
23E081-01 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-137-16-052023
23E081-02 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-137-16-052023
23E081-02 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-137-16-052023
23E081-02 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-137-16-052023
23E081-02 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-137-16-052023
23E081-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-137-16-052023
23E081-02 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-137-16-052023
23E081-02 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-137-16-052023
23E081-02 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N Carbon disulfide 1.0 0.28 J 0.28 J ug/l TR/Z6
S-137-16-052023
23E081-02 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-137-16-052023
23E081-02 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-137-16-052023
23E081-02 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-137-16-052023
23E081-02 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-137-16-052023
23E081-02 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-137-16-052023
23E081-02 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-137-16-052023
23E081-02 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-137-16-052023
23E081-02 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-138-16-052023
23E081-03 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-138-16-052023
23E081-03 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-138-16-052023
23E081-03 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-138-16-052023
23E081-03 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-138-16-052023
23E081-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-138-16-052023
23E081-03 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-138-16-052023
23E081-03 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-138-16-052023
23E081-03 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-138-16-052023
23E081-03 N Chloroform 1.0 0.14 J 0.20 UJ ug/l V/Z6
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August 07, 2023 Page 19 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-138-16-052023
23E081-03 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-138-16-052023
23E081-03 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-138-16-052023
23E081-03 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-138-16-052023
23E081-03 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-138-16-052023
23E081-03 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-138-16-052023
23E081-03 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
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August 07, 2023 Page 20 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-141-17-052023
23E081-04 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-141-17-052023
23E081-04 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-141-17-052023
23E081-04 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-141-17-052023
23E081-04 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-141-17-052023
23E081-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-141-17-052023
23E081-04 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 21 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-141-17-052023
23E081-04 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-141-17-052023
23E081-04 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-141-17-052023
23E081-04 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-141-17-052023
23E081-04 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-141-17-052023
23E081-04 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 22 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-141-17-052023
23E081-04 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-141-17-052023
23E081-04 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-141-17-052023
23E081-04 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-67-90-052023
23E081-05 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
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ENV.ADR
August 07, 2023 Page 23 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-67-90-052023
23E081-05 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-67-90-052023
23E081-05 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-67-90-052023
23E081-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-67-90-052023
23E081-05 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-67-90-052023
23E081-05 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-67-90-052023
23E081-05 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-67-90-052023
23E081-05 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-67-90-052023
23E081-05 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 24 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-67-90-052023
23E081-05 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-67-90-052023
23E081-05 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-67-90-052023
23E081-05 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-67-90-052023
23E081-05 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
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August 07, 2023 Page 25 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-68-90-052023
23E081-06 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-68-90-052023
23E081-06 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-68-90-052023
23E081-06 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-68-90-052023
23E081-06 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-68-90-052023
23E081-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-68-90-052023
23E081-06 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-68-90-052023
23E081-06 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-68-90-052023
23E081-06 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-68-90-052023
23E081-06 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 26 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-68-90-052023
23E081-06 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-68-90-052023
23E081-06 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-68-90-052023
23E081-06 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Styrene 1.0 0.50 U 0.50 UJ ug/l M/Z6
S-68-90-052023
23E081-06 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-68-90-052023
23E081-06 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-68-90-052023
23E081-06 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-68-90-052023
23E081-06 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
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August 07, 2023 Page 27 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-70-90-052023
23E081-07 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-70-90-052023
23E081-07 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-70-90-052023
23E081-07 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-70-90-052023
23E081-07 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-70-90-052023
23E081-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-70-90-052023
23E081-07 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-70-90-052023
23E081-07 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-70-90-052023
23E081-07 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 28 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-70-90-052023
23E081-07 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-70-90-052023
23E081-07 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-70-90-052023
23E081-07 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-70-90-052023
23E081-07 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N Styrene 1.0 0.50 U 0.50 UJ ug/l M/Z6
S-70-90-052023
23E081-07 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-70-90-052023
23E081-07 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 29 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-70-90-052023
23E081-07 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-70-90-052023
23E081-07 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-70-90-052023
23E081-07 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-71-90-052023
23E081-08 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-71-90-052023
23E081-08 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-71-90-052023
23E081-08 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 30 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-71-90-052023
23E081-08 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-71-90-052023
23E081-08 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-71-90-052023
23E081-08 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-71-90-052023
23E081-08 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-71-90-052023
23E081-08 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-71-90-052023
23E081-08 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-71-90-052023
23E081-08 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-71-90-052023
23E081-08 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
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ENV.ADR
August 07, 2023 Page 31 of 46
Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-71-90-052023
23E081-08 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-71-90-052023
23E081-08 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-71-90-052023
23E081-08 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-71-90-052023
23E081-08 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-93-92-052023
23E081-09 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-93-92-052023
23E081-09 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-93-92-052023
23E081-09 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-93-92-052023
23E081-09 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-93-92-052023
23E081-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-93-92-052023
23E081-09 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-93-92-052023
23E081-09 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-93-92-052023
23E081-09 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-93-92-052023
23E081-09 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-93-92-052023
23E081-09 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-93-92-052023
23E081-09 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-93-92-052023
23E081-09 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-93-92-052023
23E081-09 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-93-92-052023
23E081-09 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-93-92-052023
23E081-09 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-95-92-052023
23E081-10 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-95-92-052023
23E081-10 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-95-92-052023
23E081-10 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-95-92-052023
23E081-10 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-95-92-052023
23E081-10 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-95-92-052023
23E081-10 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-95-92-052023
23E081-10 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-95-92-052023
23E081-10 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
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ENV.ADR
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-95-92-052023
23E081-10 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-95-92-052023
23E081-10 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-95-92-052023
23E081-10 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-95-92-052023
23E081-10 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-95-92-052023
23E081-10 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-95-92-052023
23E081-10 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-95-92-052023
23E081-10 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
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ENV.ADR
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-97-92-052023
23E081-11 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
S-97-92-052023
23E081-11 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-97-92-052023
23E081-11 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N 2-Hexanone 20 10 U 10 UJ ug/l Z6
S-97-92-052023
23E081-11 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
S-97-92-052023
23E081-11 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
S-97-92-052023
23E081-11 N Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
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ENV.ADR
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-97-92-052023
23E081-11 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
S-97-92-052023
23E081-11 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
S-97-92-052023
23E081-11 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
S-97-92-052023
23E081-11 N Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
S-97-92-052023
23E081-11 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
S-97-92-052023
23E081-11 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-97-92-052023
23E081-11 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
S-97-92-052023
23E081-11 N Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
S-97-92-052023
23E081-11 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
S-97-92-052023
23E081-11 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
SWMU-1/25-EB-052023
23E081-12 EB 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
SWMU-1/25-EB-052023
23E081-12 EB 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 2-Hexanone 20 10 U 10 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Acetone 20 5.8 J 5.8 J ug/l G1/G3/TR/V3
/V5/Z6
SWMU-1/25-EB-052023
23E081-12 EB Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Chloroform 1.0 0.18 J 0.18 J ug/l TR/Z6
SWMU-1/25-EB-052023
23E081-12 EB Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
SWMU-1/25-EB-052023
23E081-12 EB Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Toluene 1.0 0.11 J 0.11 J ug/l TR/Z6
SWMU-1/25-EB-052023
23E081-12 EB trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
SWMU-1/25-EB-052023
23E081-12 EB Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,1-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
TB-20230503-1/25
23E081-13 TB 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 1,4-Dioxane 100 50 U 50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
TB-20230503-1/25
23E081-13 TB 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 2-Hexanone 20 10 U 10 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5/
Z6
TB-20230503-1/25
23E081-13 TB Benzene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Bromobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Bromoform 1.0 0.30 U 0.30 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Bromomethane 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Chloroethane 2.0 1.0 U 1.0 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Chloroform 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Chloromethane 1.0 0.50 U 0.50 UJ ug/l Z6
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Data Validation Report for 23E081
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
TB-20230503-1/25
23E081-13 TB cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Cumene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Dibromomethane 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Methylene chloride 2.0 1.0 U 1.0 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB o-Xylene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Styrene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Toluene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l Z6
TB-20230503-1/25
23E081-13 TB Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l Z6
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOQ) based on the sample concentration.
In instances where no LOD is provided, results are reported down to the LOQ.
Trace values are not included in the qualified results table unless additional reason codes are associated.
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Data Validation Report for 23E081
Reason Code Definitions
Code Definition
G1 Initial Calibration RRF
G3 ICV RRF
M MS Recovery
TR Trace Level Detect
V Equipment Blank
V3 CCV RRF
V5 Ending Continuing Calibration Verification
Z6 Sample or the associated closing CCV was analyzed past the 12-hour time period from Tune or opening CCV
Flag Code and Definitions
Flag Definition
J Estimated Value
N The analysis indicates the presence of an analyte for which there was presumptive evidence to make a tentative identification.
NJ
The analyte has been tentatively identified or presumptively as present
and the associated numerical value was the estimated concentration in
the sample.
R The data are rejected due to deficiencies in meeting QC criteria and may not be used for decision making.
U Undetected: The analyte was analyzed for, but not detected.
UJ The analyte was not detected; however, the result is estimated due to discrepancies in meeting certain analyte-specific quality
control criteria.
X Result may require rejection; PDT attention required
Bias
-The result may be biased low
+The result may be biased high
Note - The bias field is a separate field; however, it is an integral part of the final flag (qualifier) on the sample result
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Data Validation Report for 23E081
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Were there discrepancies between the COC and the
samples received?•
Were there discrepancies between the COC and the
sample labels?•See narrative comments.
Were samples relinquished properly on the COC?•
Were all samples properly preserved?•
Were sampling dates/times, date and time of laboratory
receipt of samples, and sample conditions upon receipt
at the laboratory (including preservation, pH, and
temperature) documented?
•
Were sample results reported with percent moisture
correction if required?•
Were analytical methods performed and analysis dates
present?•
Were all requested target analytes reported?•
Were QAPP specified Project Quantitation Limit Goals
achieved? (The laboratory LOQ is compared to the
QAPP Project Quantitation Goal)
•Various compounds are reported non-detects at
levels (LOQs) greater than the project PQGs.
Were holding times met?•
Were trip blanks analyzed at the proper frequency and in
control?•
Were field blanks analyzed at the proper frequency and
in control?•
Were equipment blanks analyzed at the proper frequency
and in control?•See QC outliers.
Was a method blank prepared and analyzed with each
batch?•
Were target analytes in the method blank less than DL?•
Was an LCS/LCSD pair prepared and analyzed with each
batch?•
Were LCS/LCSD recoveries within project acceptance
limits?•
Was the LCS/LCSD RPD within project acceptance
limits?•
Was a MS/MSD pair prepared with each batch?•
Were MS/MSD recoveries within project acceptance
limits?•See QC outliers.
Was the MS/MSD RPD within project acceptance limits?•
If ISM was used for sample collection, were laboratory
triplicates analyzed and within project acceptance limits?•
Were surrogate recoveries within project acceptance
limits?•
Were field replicates (duplicates, triplicates, etc.)
analyzed at the proper frequency and in control?•
Were reported sample concentrations within calibration
range?•
Was the GC/MS system properly tuned based on method
criteria?•
Was instrument tuning completed every 12 hours during
sample analysis?•
Ending CCV outside of 12 hr window.
Associated samples were qualified J/UJ with Z6
reason code
Was the Calibration within project acceptance criteria?•See QC outliers
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Data Validation Report for 23E081
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Was a ICV performed after each ICAL prior to sample
analysis and within project acceptance criteria?•See QC outliers
Were CCVs run at the required frequency and within
project acceptance criteria?•See QC outliers
Were internal standard retention times and area criteria
within project acceptance criteria?•
Were internal standards spiked for every sample,
standard, and QC sample?•
Were instrument run logs present and filled out
appropriately?•
Were sample preparation sheets present and filled out
appropriately?•
Were certificates of standard traceability and
documentation of standard solution preparation provided?•
Were recalculation of QC Elements and Sample Results
performed?•
Were Relative Retention Times (RRTs) within ± 0.06
RRT units and updated with the latest daily CCV?•
Were chromatograms checked for peak integration?
(10% of automated integration and 100% of manual
integrations)
•
Were chromatograms checked for correct baseline/peak
integration and possible interferences?•
Were qualitative ion mass present?•
Have all Laboratory Case Narrative comments/findings
been addressed in the data review process?•
Were DoD QSM corrective actions followed if deviations
were noted?•
ICAL/ICV/CCV/ECV and 12 hr tune window out
of control and samples not re-analyzed or
addition ECV's were not analyzed.
Were any data recommended for exclusion in the data
validation process?•
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SDG #: 23E081 Date: 7/17/2023
Lab: Emax Laboratories, Inc Page: 1 of 1
Client: Brice Engineering, LLC Validated by: JT
Matrix: Water Second Review by: KMC
Tune ID: REC286.D
Recalculated Ion Ratio: 177:176
Reported Ratio: 6.5%p. 148
Relative Abundance (Ion Ratio) = Response of Target Mass × 100%
Response of Reference Mass
Target Mass Response = 1932 p. 148
Reference Mass Response = 29715 p. 148
Calculated Ratio = 6.5%Match
Comments:
S4VEM
INSTRUMENT PERFORMANCE CHECK / TUNE
VOCs - SW8260B
CALCULATIONS
Inst Perf
SDG #: 23E081 Date: 7/17/2023
Lab: Emax Laboratories, Inc Page: 1 of 1
Client: Brice Engineering, LLC Validated by: JT
Matrix: Water Second Review by: KMC
RRF Standard ID: RDC592
Analyte: Chloromethane
Calibration Level: 5
Reported Calibration RRF: 0.515 p. 88
RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
Analyte Response = 575122 p. 109
ISTD Response = 2232342 p. 109 ISTD: 1,4-Difluorobenzene
Analyte Conc. = 5.00 p. 109
ISTD Conc. = 10.0 p. 109
Calculated RRF = 0.515 Match
Calibration ID: ICAL 04/26/2023 08:46
Analyte: Chloromethane
Reported Average RRF: 0.53 p. 88
Reported %RSD: 9.57%p. 88
%RSD = Standard Deviation × 100%
Average RRF
RF Lvl 1: 0.594 RF Lvl 6: 0.567
RF Lvl 2: 0.462 RF Lvl 7: 0.492
RF Lvl 3: 0.592 RF Lvl 8: 0.483
RF Lvl 4: 0.536 RF Lvl 9:
RF Lvl 5: 0.515 RF Lvl 10:
Standard Deviation = 0.050
Calculated Average RRF = 0.53 Match
Calculated %RSD = 9.52% Match
Comments:
S4VEM
INITIAL CALIBRATION
VOCs - SW8260B
CALCULATIONS
ICAL
SDG #: 23E081 Date: 7/17/2023
Lab: Emax Laboratories, Inc Page: 1 of 1
Client: Brice Engineering, LLC Validated by: JT
Matrix: Water Second Review by: KMC
%D = 100% × ( CV RRF - Avg RRF ) / Avg RRF RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
ICV ID: IV067D2601
Analyte: Carbon tetrachloride
ISTD: 1,4-Difluorobenzene
Reported ICV RRF: 0.324 p. 138
Reported %D: 3.0%p. 138
Analyte Response = 765503 p. 142
ISTD Response = 2362609 p. 141
Analyte Conc. = 10.0 p. 142
ISTD Conc. = 10.0 p. 141
Mean RRF (ICAL) = 0.3340 p. 138
Calculated ICV RRF =0.324 Match
Calculated %D = -3.0%Match
CCV ID: CV067D2613
Analyte: Vinyl chloride
ISTD: 1,4-Difluorobenzene
Reported CCV RRF: 0.515 p. 152
Reported %D: -9.6%p. 152
Analyte Response = 1138083 p. 155
ISTD Response = 2211620 p. 155
Analyte Conc. = 10.0 p. 155
ISTD Conc. = 10.0 p. 155
Mean RRF (ICAL) = 0.470 p. 152
Calculated CCV RRF =0.515 Match
Calculated %D = 9.5% Match
Comments:
S4VEM
INITIAL / CONTINUING CALIBRATION VERIFICATION
VOCs - SW8260B
CALCULATIONS
ICV-CCV
SURROGATE SPIKES/SYSTEM MONITORING COMPOUNDS
SDG #: 23E081 Date: 7/17/2023
Lab: Emax Laboratories, Inc Page: 1 of 1
Client: Brice Engineering, LLC Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: S-129-15-052023 / 23E081-01
Compound ID: 4-Bromofluorobenzene
Reported %Recovery: 113.5%p. 11
% Recovery = Conc. Surr. In Sample × 100%
Conc. Surr. Spiked
Conc. In Sample = 11.4 p. 11
Surr. Spike Conc. = 10.0 p. 11
Calculated %Recovery = 113.5%Match
Sample ID: S-137-16-052023 / 23E081-02
Compound ID: Dibromofluoromethane
Reported %Recovery: 106.6%p. 15
% Recovery = Conc. Surr. In Sample × 100%
Conc. Surr. Spiked
Conc. In Sample = 10.7 p. 15
Surr. Spike Conc. = 10.0 p. 15
Calculated %Recovery = 106.6%Match
Comments:
CALCULATIONS
S4VEM
VOCs - SW8260B
Surr
GC/MS VALIDATION WORKSHEET - MATRIX SPIKES/DUPLICATES
SDG #: 23E081 Date: 7/17/2023
Lab: Emax Laboratories, Inc Page: 1 of 1
Client: Brice Engineering, LLC Validated by: JT
Second Review by: KMC
CALCULATIONS
Parent Sample ID: S-68-90-05202 Parent Sample ID: S-68-90-05202
Compound ID: Toluene Compound ID: S-68-90-05202
Recovery: 95%p.57 RPD: 4%p.57
% Recovery = Conc. MS - Conc. Unspiked Sample X 100 RPD = |MS Conc. - MSD Conc.| X 100
MS Spike Conc.(MS Conc. + MSD Conc.)/2
Conc. MS = 9.53 p.57 MS Conc. = 9.53 p.57
Unspiked Samp. = 0.0 p.57 MSD Conc. = 9.20 p.57
MS Spike Conc. = 10.0 p.57
RPD = 4%
% Recovery = 95%Matches Matches
Comments:
Mtrx Spk
SDG #: 23E081 Date: 7/17/2023
Lab: Emax Laboratories, Inc Page: 1 of 1
Client: Brice Engineering, LLC Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: V067E14L
Analyte: cis-1,2-Dichloroethene
Reported %Recovery: 106%p. 56
%Recovery = Conc. LCS × 100%
LCS Spike Conc.
Conc. LCS = 10.6 p. 56
LCS Spike Conc. = 10.0 p. 56
Calculated %Recovery = 106% Match
Sample ID: V067E14L / V067E14C
Analyte: Methylene Chloride
Reported RPD: 1%p. 56
RPD = | LCS Conc. - LCSD Conc.| × 100%
(LCS Conc. + LCSD Conc.)/2
LCS Conc. = 9.70 p. 56
LCSD Conc. = 9.60 p. 56
Calculated RPD = 1% Match
Comments:
S4VEM
VOCs - SW8260B
LABORATORY CONTROL SAMPLES
CALCULATIONS
LCS
SDG #: 23E081 Date: 7/17/2023
Lab: Emax Laboratories, Inc Page: 1 of 1
Client: Brice Engineering, LLC Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: V067E14L*
Compound ID: Carbon Tetrachloride
Reported Result: 10.6 p. 56
Conc. In Sample = Analyte Resp. × Conc. of IS × Final Volume × Dilution Factor
IS Resp. Average RRF Initial Amount
Analyte Response = 702017 p. 63
IS Response = 1972534 p. 62 IS: 1,4-Difluorobenzene
IS Conc. = 10.0 p. 62
Average RRF = 0.3340 p. 88
Final Volume (mL) = 25.0 p. 56
Initial Amount (mL) = 25.0 p. 56
Dilution Factor = 1 p. 56
Conc. In Sample = 10.7 Match
Sample ID: S-137-16-052023 / 23E081-02
Compound ID: Carbon Disulfide
Reported Result: 0.28 J p. 14
Conc. In Sample = Analyte Resp. × Conc. of IS × Final Volume × Dilution Factor
IS Resp. Average RRF Initial Amount
Analyte Response = 69547 p. 15
IS Response = 2178620 p. 15 IS: 1,4-Difluorobenzene
IS Conc. = 10.0 p. 15
Average RRF = 1.144 p. 88
Final Volume (mL) = 25 p.14
Initial Amount (mL) = 25 p.14
Dilution Factor = 1 p. 14
Conc. In Sample = 0.28 Match
Comments: *Recalculations were done on the LCS sample because sample #1 was ND.
S4VEM
VOCs - SW8260B
SAMPLE RESULT VERIFICATION
CALCULATIONS
Rslt Ver
Data Validation Report for 23E120
SDG:
Facility:
Guidance Document:
Event:
Data Review Contractor:
Data Review Level:
23E120
USAEC, TEAD-S
FINAL Uniform Federal Policy - Quality Assurance Project Plan Tooele Army
Depot South, Utah, October 2021
TEAD-S 2023 Annual Monitoring Groundwater
Synectics, Sacramento, CA
S4VEM
Project Manager:
Date Submitted:
Andrew Castor
August 07, 2023
Primary Data Reviewer:Kathryn Cantone, Data Review Chemist
Field Sample ID Lab Sample ID Matrix Type/Type Code SW
8
2
6
0
C
S-120-08-052023 23E120-01 Water Field Sample/N X
S-120-08-052023 23E120-01I Water Field Sample/N X
S-121-08-052023 23E120-02 Water Field Sample/N X
S-127-15-052023 23E120-03 Water Field Sample/N X
S-127-15-052023 23E120-03I Water Field Sample/N X
S-128-15-052023 23E120-04 Water Field Sample/N X
S-135-16-052023 23E120-06 Water Field Sample/N X
S-135-16-05-2023D 23E120-05 Water Field Duplicate/FD X
S-136-16-052023 23E120-07 Water Field Sample/N X
S-139-17-052023 23E120-09 Water Field Sample/N X
S-139-17-052023 23E120-09I Water Field Sample/N X
S-139-17-05-2023D 23E120-08 Water Field Duplicate/FD X
S-139-17-05-2023D 23E120-08I Water Field Duplicate/FD X
S-140-17-052023 23E120-10N Water Field Sample/N X
S-142-17-052023 23E120-11N Water Field Sample/N X
TB-20230509-1/25 23E120-12 Water Trip Blank/TB X
Second Reviewer:Evin McKinney, Senior Scientist
Contract Laboratory(ies):EMAX Laboratories, Inc., Torrance, CA
Prime Contractor:Brice Environmental Services Corporation, Salt Lake City, UT (BRSS)
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Data Validation Report for 23E120
This report assesses the analytical data quality associated with the analyses listed on the preceding cover
page at S4VEM data validation level. This assessment has been made through a combination of automated
data review (ADR) and supplemental manual review, the details of which are described below. The approach
taken in the review of this data set is consistent with the requirements contained in the FINAL Uniform Federal
Policy - Quality Assurance Project Plan Tooele Army Depot South, Utah, October 2021 and the additional
guidance documents incorporated by reference to the extent possible. Where definitive guidance is not
provided, results have been evaluated in a conservative manner using professional judgment.
Sample collection was managed and directed by Brice Environmental Services Corporation, Salt Lake City, UT
(BRSS); analyses were performed by EMAX Laboratories, Inc., Torrance, CA and were reported under sample
delivery group (SDG) 23E120. Data have been evaluated electronically based on electronic data deliverables
(EDDs) provided by the laboratory, and hard copy data summary forms have also been reviewed during this
effort and compared to the automated review output by the reviewers whose signatures appear on the
following page. Findings based on the automated data submission and manual data verification processes are
detailed in the ADR narrative and throughout this report.
All quality control (QC) elements associated with this SDG have been reviewed by a project chemist in
accordance with the requirements defined for the project. This review is documented in the attached Data
Review Checklists. The QC elements listed below were supported by the electronic deliverable and were
evaluated using ADR processes.
Results of the ADR process were subsequently reviewed and updated as applicable by the data review
chemists identified on the signature page. Quality control elements that were not included in the electronic
deliverable were reviewed manually and findings are documented within this report. Summaries of findings
and associated qualified results are documented throughout this report.
A total of 39 results (5.24%) out of the 744 results (sample and field QC samples) reported are qualified
based on review and 0 results (0.00%) have been rejected or deemed a serious deficiency (X qualifier). Trace
values, defined as results that are qualified as estimated because they fall between the detection limit and the
reporting limit/limit of quantitation, are not counted as qualified results in the above count. The qualified
results are detailed throughout this report and discussed in the narrative below, where appropriate.
Continuing Calibration Verification
Field Duplicate RPD
Lab Blank
LCS Recovery
LCS RPD
MS Recovery
MS RPD
Prep Hold Time
Surrogate
Test Hold Time
Trip Blank
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Data Validation Report for 23E120
Samples 23E120-01 and 02 underwent S4VEM and the remaining samples S2BVEM.
The laboratory noted that corrections on the sample labels were not dated. The samples were logged
according to the CoC
Analytical Method Data Reviewer Comment
SW8260C The laboratory noted the following:
The Minimum Response Factor for all analytes were within method recommended
response factors with the exception of Acetone and 2-Butanone.
The MS/MSD recoveries were outside QC limits.
Narrative Comments
Reviewed by Kathryn Cantone, Data Review Chemist, Synectics,
Sacramento, CA
July 21, 2023
Reviewed by Evin McKinney, Senior Scientist, Synectics,
Sacramento, CA
August 07, 2023
As the First Reviewer, I certify that I have performed a data review process in accordance with the
requirements of the project guidance document, and have compared the electronic data to the laboratory's
hard copy report and have verified the consistency of the reported sample results and method quality control
data between the two deliverables.
As the Second Reviewer, I certify that I have performed a quality assurance review of the report generated
by the First Reviewer.
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Data Validation Report for 23E120
Quality Control Outliers for test method SW8260C, Continuing Calibration Verification RRF
Compliance requirements for satisfactory continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
CV067D2617 ()2-Butanone (MEK)0.0140 > 0.1 > 0.1 rf J/UJ V3
CV067D2617 ()Acetone 0.0440 > 0.1 > 0.1 rf J/UJ V3
ICV067D2616 ()2-Butanone (MEK)0.0140 > 0.1 > 0.1 rf J/UJ V3
ICV067D2616 ()Acetone 0.0450 > 0.1 > 0.1 rf J/UJ V3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Continuing Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-120-08-052023
23E120-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-120-08-052023
23E120-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
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Data Validation Report for 23E120
Qualified Results associated with the Continuing Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-140-17-052023
23E120-10N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-140-17-052023
23E120-10N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E120
Quality Control Outliers for test method SW8260C, Ending Continuing Calibration Verification
Compliance requirements for satisfactory closing continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
EV067D2616 (EV)2-Butanone (MEK)0.0140 < 0.1 < 0.1 rf J/UJ V5
EV067D2616 (EV)Acetone 0.0430 < 0.1 < 0.1 rf J/UJ V5
EV067D2617 (EV)2-Butanone (MEK)0.0140 < 0.1 < 0.1 rf J/UJ V5
EV067D2617 (EV)Acetone 0.0450 < 0.1 < 0.1 rf J/UJ V5
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Ending Continuing Calibration Verification for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-120-08-052023
23E120-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-120-08-052023
23E120-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
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Data Validation Report for 23E120
Qualified Results associated with the Ending Continuing Calibration Verification for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-140-17-052023
23E120-10N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-140-17-052023
23E120-10N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E120
Quality Control Outliers for test method SW8260C, Initial Calibration RRF
Compliance requirements for satisfactory initial calibration are established to ensure that the instrument is capable of producing acceptable
qualitative and quantitative data. Initial calibration is performed to verify and evaluate instrument performance prior to sample analysis.
Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
CAL 04/26/23 Inst 67 ()2-Butanone (MEK)0.0130 > 0.1 > 0.1 rf J/UJ G1
CAL 04/26/23 Inst 67 ()Acetone 0.0400 > 0.1 > 0.1 rf J/UJ G1
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-120-08-052023
23E120-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-120-08-052023
23E120-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-140-17-052023
23E120-10N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
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Data Validation Report for 23E120
Qualified Results associated with the Initial Calibration RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-140-17-052023
23E120-10N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E120
Quality Control Outliers for test method SW8260C, Initial Calibration Verification RRF
Compliance requirements for satisfactory initial calibration verifications are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Initil calibration verification is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
IV067D2601 ()2-Butanone (MEK)0.0120 < 0.1 < 0.1 rf J/UJ G3
IV067D2601 ()Acetone 0.0360 < 0.1 < 0.1 rf J/UJ G3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-120-08-052023
23E120-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-120-08-052023
23E120-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-140-17-052023
23E120-10N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
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Data Validation Report for 23E120
Qualified Results associated with the Initial Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-140-17-052023
23E120-10N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E120
Quality Control Outliers for test method SW8260C, MS Recovery
Data for matrix spikes/matrix spike duplicates (MS/MSD) are generated to determine long-term precision and accuracy of the analytical
method on various matrices and to demonstrate acceptable compound recovery by the laboratory at the time of sample analysis. These
data alone cannot be used to evaluate the precision and accuracy of individual samples. However, when exercising professional judgment,
MS/MSD data can be used in conjunction with other available QC information. Reported results were evaluated to determine compliance
with the required acceptance criteria, and summary forms were evaluated and compared to electronic data deliverables. Findings of this
review, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
S-121-08-052023 (MS)Styrene 48.0 78 - 123 10 - 123 percent J/UJ M
S-121-08-052023 (SD)Styrene 44.0 78 - 123 10 - 123 percent J/UJ M
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the MS Recovery for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-121-08-052023
23E120-02 N Styrene 1.0 0.50 U 0.50 UJ ug/l M
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E120
Quality Control Outliers for test method SW8260C, Surrogate
Method performance for individual samples is demonstrated through spiking activities. All samples are spiked with surrogate compounds
prior to sample preparation. The sample itself may produce effects due to such factors as interferences and high concentrations of analytes.
Summary forms were evaluated and compared to electronic data deliverables. Surrogate results that were outside of the acceptance
criteria are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
S-139-17-052023 (N)Dibromofluoromet
hane 127 80 - 119 10 - 119 percent J/None I
S-139-17-05-2023D (FD)Dibromofluoromet
hane 124 80 - 119 10 - 119 percent J/None I
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Surrogate for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-139-17-052023
23E120-09 N 1,1-Dichloroethene 1.0 0.40 J 0.40 J +ug/l I/TR
S-139-17-052023
23E120-09 N Benzene 1.0 0.33 J 0.33 J +ug/l I/TR
S-139-17-052023
23E120-09 N Carbon disulfide 1.0 1.7 1.7 J +ug/l I
S-139-17-052023
23E120-09 N Methylene chloride 2.0 4.3 4.3 J +ug/l I
S-139-17-052023
23E120-09 N Tetrachloroethene (PCE)1.0 24 24 J +ug/l I
S-139-17-052023
23E120-09 N trans-1,2-Dichloroethene 1.0 0.12 J 0.12 J +ug/l I/TR
S-139-17-052023
23E120-09 N Trichloroethene (TCE)1.0 4.5 4.5 J +ug/l I
S-139-17-05-2023D
23E120-08 FD 1,1-Dichloroethene 1.0 0.38 J 0.38 J +ug/l I/TR
S-139-17-05-2023D
23E120-08 FD Benzene 1.0 0.33 J 0.33 J +ug/l I/TR
S-139-17-05-2023D
23E120-08 FD Carbon disulfide 1.0 1.8 1.8 J +ug/l I
S-139-17-05-2023D
23E120-08 FD Methylene chloride 2.0 4.2 4.2 J +ug/l I
S-139-17-05-2023D
23E120-08 FD Tetrachloroethene (PCE)1.0 24 24 J +ug/l I
S-139-17-05-2023D
23E120-08 FD trans-1,2-Dichloroethene 1.0 0.11 J 0.11 J +ug/l I/TR
S-139-17-05-2023D
23E120-08 FD Trichloroethene (TCE)1.0 4.6 4.6 J +ug/l I
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E120
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-120-08-052023
23E120-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-120-08-052023
23E120-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-121-08-052023
23E120-02 N Styrene 1.0 0.50 U 0.50 UJ ug/l M
S-127-15-052023
23E120-03 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-127-15-052023
23E120-03 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-128-15-052023
23E120-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-052023
23E120-06 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-135-16-05-2023D
23E120-05 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-136-16-052023
23E120-07 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N 1,1-Dichloroethene 1.0 0.40 J 0.40 J +ug/l I/TR
S-139-17-052023
23E120-09 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-052023
23E120-09 N Benzene 1.0 0.33 J 0.33 J +ug/l I/TR
S-139-17-052023
23E120-09 N Carbon disulfide 1.0 1.7 1.7 J +ug/l I
S-139-17-052023
23E120-09 N Methylene chloride 2.0 4.3 4.3 J +ug/l I
S-139-17-052023
23E120-09 N Tetrachloroethene (PCE)1.0 24 24 J +ug/l I
S-139-17-052023
23E120-09 N trans-1,2-Dichloroethene 1.0 0.12 J 0.12 J +ug/l I/TR
S-139-17-052023
23E120-09 N Trichloroethene (TCE)1.0 4.5 4.5 J +ug/l I
S-139-17-05-2023D
23E120-08 FD 1,1-Dichloroethene 1.0 0.38 J 0.38 J +ug/l I/TR
S-139-17-05-2023D
23E120-08 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
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Data Validation Report for 23E120
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-139-17-05-2023D
23E120-08 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-139-17-05-2023D
23E120-08 FD Benzene 1.0 0.33 J 0.33 J +ug/l I/TR
S-139-17-05-2023D
23E120-08 FD Carbon disulfide 1.0 1.8 1.8 J +ug/l I
S-139-17-05-2023D
23E120-08 FD Methylene chloride 2.0 4.2 4.2 J +ug/l I
S-139-17-05-2023D
23E120-08 FD Tetrachloroethene (PCE)1.0 24 24 J +ug/l I
S-139-17-05-2023D
23E120-08 FD trans-1,2-Dichloroethene 1.0 0.11 J 0.11 J +ug/l I/TR
S-139-17-05-2023D
23E120-08 FD Trichloroethene (TCE)1.0 4.6 4.6 J +ug/l I
S-140-17-052023
23E120-10N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-140-17-052023
23E120-10N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-142-17-052023
23E120-11N N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230509-1/25
23E120-12 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOQ) based on the sample concentration.
In instances where no LOD is provided, results are reported down to the LOQ.
Trace values are not included in the qualified results table unless additional reason codes are associated.
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Data Validation Report for 23E120
Reason Code Definitions
Code Definition
G1 Initial Calibration RRF
G3 ICV RRF
I Surrogate recovery outside project limits.
M MS Recovery
TR Trace Level Detect
V3 CCV RRF
V5 Ending Continuing Calibration Verification
Flag Code and Definitions
Flag Definition
J Estimated Value
N The analysis indicates the presence of an analyte for which there was presumptive evidence to make a tentative identification.
NJ
The analyte has been tentatively identified or presumptively as present
and the associated numerical value was the estimated concentration in
the sample.
R The data are rejected due to deficiencies in meeting QC criteria and may not be used for decision making.
U Undetected: The analyte was analyzed for, but not detected.
UJ The analyte was not detected; however, the result is estimated due to discrepancies in meeting certain analyte-specific quality
control criteria.
X Result may require rejection; PDT attention required
Bias
-The result may be biased low
+The result may be biased high
Note - The bias field is a separate field; however, it is an integral part of the final flag (qualifier) on the sample result
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Data Validation Report for 23E120
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Were there discrepancies between the COC and the
samples received?•
Were there discrepancies between the COC and the
sample labels?•See narrative comment
Were samples relinquished properly on the COC?•
Were all samples properly preserved?•
Were sampling dates/times, date and time of laboratory
receipt of samples, and sample conditions upon receipt
at the laboratory (including preservation, pH, and
temperature) documented?
•
Were sample results reported with percent moisture
correction if required?•
Were analytical methods performed and analysis dates
present?•
Were all requested target analytes reported?•
Were QAPP specified Project Quantitation Limit Goals
achieved? (The laboratory LOQ is compared to the
QAPP Project Quantitation Goal)
•
Various compounds are reported with detection
(s) and non-detect(s) at levels (LOQs) greater
than the project PQGs.
Were holding times met?•
Were trip blanks analyzed at the proper frequency and in
control?•
Were field blanks analyzed at the proper frequency and
in control?•
Were equipment blanks analyzed at the proper frequency
and in control?•
Was a method blank prepared and analyzed with each
batch?•
Were target analytes in the method blank less than DL?•
Was an LCS/LCSD pair prepared and analyzed with each
batch?•
Were LCS/LCSD recoveries within project acceptance
limits?•
Was the LCS/LCSD RPD within project acceptance
limits?•
Was a MS/MSD pair prepared with each batch?•1 of 2 batches prepared with a project MS/MSD.
Were MS/MSD recoveries within project acceptance
limits?•See QC outliers.
Was the MS/MSD RPD within project acceptance limits?•
If ISM was used for sample collection, were laboratory
triplicates analyzed and within project acceptance limits?•
Were surrogate recoveries within project acceptance
limits?•
See QC outliers. Laboratory used in-house QC
limits for review purposes. QC within laboratory
limits but out of control for client control limits.
Were field replicates (duplicates, triplicates, etc.)
analyzed at the proper frequency and in control?•
Were reported sample concentrations within calibration
range?•
Was the GC/MS system properly tuned based on method
criteria?•
Was instrument tuning completed every 12 hours during
sample analysis?•
Was the Calibration within project acceptance criteria?•See QC outliers
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Data Validation Report for 23E120
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Was a ICV performed after each ICAL prior to sample
analysis and within project acceptance criteria?•See QC outliers
Were CCVs run at the required frequency and within
project acceptance criteria?•See QC outliers
Were internal standard retention times and area criteria
within project acceptance criteria?•
Were internal standards spiked for every sample,
standard, and QC sample?•
Were instrument run logs present and filled out
appropriately?•
Were sample preparation sheets present and filled out
appropriately?•
Were certificates of standard traceability and
documentation of standard solution preparation provided?•
Were recalculation of QC Elements and Sample Results
performed?•
Were Relative Retention Times (RRTs) within ± 0.06
RRT units and updated with the latest daily CCV?•
Were chromatograms checked for peak integration?
(10% of automated integration and 100% of manual
integrations)
•
Were chromatograms checked for correct baseline/peak
integration and possible interferences?•
Were qualitative ion mass present?•
Have all Laboratory Case Narrative comments/findings
been addressed in the data review process?•
Were DoD QSM corrective actions followed if deviations
were noted?•Response factor/surrogates out of control and
samples not re-extracted/re-analyzed.
Were any data recommended for exclusion in the data
validation process?•
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SDG #: 23E120 Date: 7/20/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Batch
Tune ID: REC379
Recalculated Ion Ratio: 175:174
Reported Ratio: 7.1% p. 195
Relative Abundance (Ion Ratio) = Response of Target Mass × 100%
Response of Reference Mass
Target Mass Response = 2456 p. 195
Reference Mass Response = 34731 p. 195
Calculated Ratio = 7.1%Match
Comments:
S4VEM
INSTRUMENT PERFORMANCE CHECK / TUNE
VOCs - SW8260B
CALCULATIONS
Inst Perf
SDG #: 23E120 Date: 7/20/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
RRF Standard ID: RDC592
Analyte: Chloroform ReCalc
Calibration Level: 5
Reported Calibration RRF: 0.483 p. 135
RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
Analyte Response = 539436 p. 156
ISTD Response = 2232342 p. 156 ISTD: 1,4-Difluorobenzene
Analyte Conc. = 10.0 p. 156
ISTD Conc. = 10.0 p. 156
Calculated RRF = 0.242 Match
Calibration ID: ICAL 4/26/23 8:46
Analyte: Chloroform
Reported Average RRF: 0.495 p. 135
Reported %RSD: 3.69% p. 135
%RSD = Standard Deviation × 100%
Average RRF
RF Lvl 1: 0.460 RF Lvl 6: 0.487 p. 135
RF Lvl 2: 0.491 RF Lvl 7: 0.514
RF Lvl 3: 0.496 RF Lvl 8: 0.510
RF Lvl 4: 0.526 RF Lvl 9: 0.496
RF Lvl 5: 0.483 RF Lvl 10: 0.489
Standard Deviation = 0.018
Calculated Average RRF = 0.495 Match
Calculated %RSD = 3.71%Match
Comments:
S4VEM
INITIAL CALIBRATION
VOCs - SW8260B
CALCULATIONS
ICAL
SDG #: 23E120 Date: 7/20/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
%D = 100% × ( CV RRF - Avg RRF ) / Avg RRF RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
ICV ID: IV067D2601
Analyte: Carbon Tetrachloride
ISTD: 1,4-Difluorobenzene
Reported ICV RRF: 0.324 p. 185
Reported %D: 3.0%p. 185
Analyte Response = 765503 p. 189
ISTD Response = 2362609 p. 188
Analyte Conc. = 10.0 p. 189
ISTD Conc. = 10.0 p. 188
Mean RRF (ICAL) = 0.334 p. 185
Calculated ICV RRF =0.324 Match
Calculated %D = -3.0%Match
CCV ID: CV067D2616
Analyte: Methylene chloride
ISTD: 1,4-Difluorobenzene
Reported CCV RRF: 0.457 p. 199
Reported %D: 1.7% p. 199
Analyte Response = 1072827 p. 202
ISTD Response = 2348490 p. 202
Analyte Conc. = 10.0 p. 202
ISTD Conc. = 10.0 p. 202
Mean RRF (ICAL) = 0.465 p. 199
Calculated CCV RRF =0.457 Match
Calculated %D = -1.8%Match
Comments:
S4VEM
INITIAL / CONTINUING CALIBRATION VERIFICATION
VOCs - SW8260B
CALCULATIONS
ICV-CCV
SURROGATE SPIKES/SYSTEM MONITORING COMPOUNDS
SDG #: 23E120 Date: 7/20/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: KMC
Matrix: Water Second Review by: KMC
Sample ID: S-120-08-052023 / 23E120-01
Compound ID: 1,2-Dichloroethane-d4
Reported %Recovery: 106.4% p. 12
% Recovery = Conc. Surr. In Sample × 100%
Conc. Surr. Spiked
Conc. In Sample = 10.64 p. 12
Surr. Spike Conc. = 10.00 p. 12
Calculated %Recovery = 106.4% Match
Sample ID: S-121-08-052023 / 23E120-02
Compound ID: 1,2-Dichloroethane-d4
Reported %Recovery: 106.1% p. 21
% Recovery = Conc. Surr. In Sample × 100%
Conc. Surr. Spiked
CALCULATIONS
S4VEM
VOCs - SW8260B
Surr
GC/MS VALIDATION WORKSHEET - MATRIX SPIKES/DUPLICATES
SDG #: 23E120 Date: #######
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Parent Sample ID: S-121-08-052023 / 23E120-02 Parent Sample ID: S-121-08-052023 / 23E120-02
Compound ID: Carbon Tetrachloride Compound ID: Carbon Tetrachloride
Recovery: 111%p. 103 RPD: 1%p. 103
% Recovery = Conc. MS - Conc. Unspiked Sample X 100 RPD = |MS Conc. - MSD Conc.| X 100
MS Spike Conc.(MS Conc. + MSD Conc.)/2
Conc. MS = 14.1 p. 103 MS Conc. = 14.1 p. 103
Unspiked Samp. = 3.0 p. 103 MSD Conc. = 13.9 p. 103
MS Spike Conc. = 10.0 p. 103
RPD = 1%Match
% Recovery = 111%Match
Comments:
Mtrx Spk
SDG #: 23E120 Date: 7/20/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: KMC
Matrix: Water Second Review by: KMC
Sample ID: V067E17L
Analyte: Trichloroethene
Reported %Recovery: 102% p. 100
%Recovery = Conc. LCS × 100%
LCS Spike Conc.
Conc. LCS = 10.20 p. 100
LCS Spike Conc. = 10 p. 100
Calculated %Recovery = 102% Match
Sample ID: V067E17L / V067E17C
Analyte: Trichloroethene
Reported RPD: 0 p. 100
RPD = | LCS Conc. - LCSD Conc.| × 100%
(LCS Conc. + LCSD Conc.)/2
LCS Conc. = 10.20 p. 100
LCSD Conc. = 10.20 p. 100
Calculated RPD = 0% Match
Comments:
S4VEM
VOCs - SW8260B
LABORATORY CONTROL SAMPLES
CALCULATIONS
LCS
SDG #: 23E120 Date: 7/20/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: S-120-08-052023 / 23E120-01
Compound ID: Tetrachloroethene
Reported Result: 0.68 p. 10
Conc. In Sample = Analyte Resp. × Conc. of IS × Final Volume × Dilution Factor
IS Resp. Average RRF Initial Amount
Analyte Response = 38194 p. 12
IS Response = 1591171 p. 12 IS: CHLOROBENZENE-D5
IS Conc. = 10.0 p. 12
Average RRF = 0.353 p. 135
Final Volume (mL) = 25.0 p. 10
Initial Amount (mL) = 25.00 p. 10
Dilution Factor = 1 p. 10
Conc. In Sample = 0.68 Match
Sample ID: S-121-08-052023 / 23E120-02
Compound ID: Carbon Tetrachloride
Reported Result: 3.0 p. 20
Conc. In Sample = Analyte Resp. × Conc. of IS × Final Volume × Dilution Factor
IS Resp. Average RRF Initial Amount
Analyte Response = 225278 p. 21
IS Response = 2247666 p. 21 IS: 1,4-Difluorobenzene
IS Conc. = 10.0 p. 21
Average RRF = 0.334 p. 135
Final Volume (mL) = 25 p. 20
Initial Amount (mL) = 25 p. 20
Dilution Factor = 1 p. 20
S4VEM
VOCs - SW8260B
SAMPLE RESULT VERIFICATION
CALCULATIONS
Rslt Ver
Data Validation Report for 23E133
SDG:
Facility:
Guidance Document:
Event:
Data Review Contractor:
Data Review Level:
23E133
USAEC, TEAD-S
FINAL Uniform Federal Policy - Quality Assurance Project Plan Tooele Army
Depot South, Utah, October 2021
TEAD-S 2023 Annual Monitoring Groundwater
Synectics, Sacramento, CA
S4VEM
Project Manager:
Date Submitted:
Andrew Castor
August 07, 2023
Primary Data Reviewer:Kathryn Cantone, Data Review Chemist
Field Sample ID Lab Sample ID Matrix Type/Type Code SW
8
0
1
5
D
SW
8
2
6
0
C
S13-CAM-DW1-052023 23E133-05 Water Field Sample/N X X
S-55-90-052023 23E133-01 Water Field Sample/N X X
S-78-91-052023 23E133-02 Water Field Sample/N X X
S-91-91-052023 23E133-04 Water Field Sample/N X X
S-91-91-05-2023D 23E133-03 Water Field Duplicate/FD X X
SWMU-13-EB-052023 23E133-06 Water Equipment Blank/EB X X
TB-20230515-13 23E133-07 Water Trip Blank/TB X
Second Reviewer:Evin McKinney, Senior Scientist
Contract Laboratory(ies):EMAX Laboratories, Inc., Torrance, CA
Prime Contractor:Brice Environmental Services Corporation, Salt Lake City, UT (BRSS)
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Data Validation Report for 23E133
This report assesses the analytical data quality associated with the analyses listed on the preceding cover
page at S4VEM data validation level. This assessment has been made through a combination of automated
data review (ADR) and supplemental manual review, the details of which are described below. The approach
taken in the review of this data set is consistent with the requirements contained in the FINAL Uniform Federal
Policy - Quality Assurance Project Plan Tooele Army Depot South, Utah, October 2021 and the additional
guidance documents incorporated by reference to the extent possible. Where definitive guidance is not
provided, results have been evaluated in a conservative manner using professional judgment.
Sample collection was managed and directed by Brice Environmental Services Corporation, Salt Lake City, UT
(BRSS); analyses were performed by EMAX Laboratories, Inc., Torrance, CA and were reported under sample
delivery group (SDG) 23E133. Data have been evaluated electronically based on electronic data deliverables
(EDDs) provided by the laboratory, and hard copy data summary forms have also been reviewed during this
effort and compared to the automated review output by the reviewers whose signatures appear on the
following page. Findings based on the automated data submission and manual data verification processes are
detailed in the ADR narrative and throughout this report.
All quality control (QC) elements associated with this SDG have been reviewed by a project chemist in
accordance with the requirements defined for the project. This review is documented in the attached Data
Review Checklists. The QC elements listed below were supported by the electronic deliverable and were
evaluated using ADR processes.
Results of the ADR process were subsequently reviewed and updated as applicable by the data review
chemists identified on the signature page. Quality control elements that were not included in the electronic
deliverable were reviewed manually and findings are documented within this report. Summaries of findings
and associated qualified results are documented throughout this report.
A total of 75 results (17.05%) out of the 440 results (sample and field QC samples) reported are qualified
based on review and 0 results (0.00%) have been rejected or deemed a serious deficiency (X qualifier). Trace
values, defined as results that are qualified as estimated because they fall between the detection limit and the
reporting limit/limit of quantitation, are not counted as qualified results in the above count. The qualified
results are detailed throughout this report and discussed in the narrative below, where appropriate.
Continuing Calibration Verification
Equipment Blank
Field Duplicate RPD
Lab Blank
LCS Recovery
LCS RPD
MS Recovery
MS RPD
Prep Hold Time
Surrogate
Test Hold Time
Trip Blank
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Data Validation Report for 23E133
Samples 23E133-01 underwent S4VEM and the remaining samples S2BVEM.
The laboratory noted that corrections on the sample labels were not dated. The samples were logged
according to the CoC.
Analytical Method Data Reviewer Comment
SW8015D No additional comments; see Checklist for detail.
SW8260C The laboratory noted that the Minimum Response Factor for all analytes were within
method recommended response factors with the exception of Acetone and 2-Butanone. In
addition, sample analyzed with headspace greater than 6mm.
Narrative Comments
Reviewed by Kathryn Cantone, Data Review Chemist, Synectics,
Sacramento, CA
July 24, 2023
Reviewed by Evin McKinney, Senior Scientist, Synectics,
Sacramento, CA
August 07, 2023
As the First Reviewer, I certify that I have performed a data review process in accordance with the
requirements of the project guidance document, and have compared the electronic data to the laboratory's
hard copy report and have verified the consistency of the reported sample results and method quality control
data between the two deliverables.
As the Second Reviewer, I certify that I have performed a quality assurance review of the report generated
by the First Reviewer.
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Data Validation Report for 23E133
Quality Control Outliers for test method SW8260C, Continuing Calibration Verification RRF
Compliance requirements for satisfactory continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
CV006E1507 ()2-Butanone (MEK)0.0580 > 0.1 > 0.1 rf J/UJ V3
CV006E1507 ()Acetone 0.0350 > 0.1 > 0.1 rf J/UJ V3
CV006E1S06 ()2-Butanone (MEK)0.0600 > 0.1 > 0.1 rf J/UJ V3
CV006E1S06 ()Acetone 0.0350 > 0.1 > 0.1 rf J/UJ V3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Continuing Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S13-CAM-DW1-052023
23E133-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S13-CAM-DW1-052023
23E133-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S-55-90-052023
23E133-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-55-90-052023
23E133-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E133
Quality Control Outliers for test method SW8260C, Ending Continuing Calibration Verification
Compliance requirements for satisfactory closing continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
EV006E1506 (EV)2-Butanone (MEK)0.0740 < 0.1 < 0.1 rf J/UJ V5
EV006E1506 (EV)Acetone 0.0450 < 0.1 < 0.1 rf J/UJ V5
EV006E1507 (EV)2-Butanone (MEK)0.0580 < 0.1 < 0.1 rf J/UJ V5
EV006E1507 (EV)Acetone 0.0360 < 0.1 < 0.1 rf J/UJ V5
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Ending Continuing Calibration Verification for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S13-CAM-DW1-052023
23E133-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S13-CAM-DW1-052023
23E133-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S-55-90-052023
23E133-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-55-90-052023
23E133-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E133
Quality Control Outliers for test method SW8260C, Equipment Blank
The purpose of equipment blanks is to determine the existence and magnitude of cross-contamination problems resulting from the process
during sampling. Reported results were evaluated to determine compliance with the required acceptance criteria. Summary forms were
evaluated and compared to electronic data deliverables. Findings of this review, and contaminants found in equipment blanks are listed
below along with any associated qualified results.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
SWMU-13-EB-052023 (EB)Chloroform 0.170 < 0.1 < 1 ug/l U/None*V
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
*Blank flags displayed in the above table identify qualification of the sample result when it is less than or equal to the LOQ/RL. Sample
results above the LOD or LOQ will be qualified based on the validation guidance assigned in the project setup.
Qualified Results associated with the Equipment Blank for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-55-90-052023
23E133-01 N Chloroform 1.0 0.37 J 1.0 U ug/l V
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E133
Quality Control Outliers for test method SW8260C, Initial Calibration RRF
Compliance requirements for satisfactory initial calibration are established to ensure that the instrument is capable of producing acceptable
qualitative and quantitative data. Initial calibration is performed to verify and evaluate instrument performance prior to sample analysis.
Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
ICAL 5/15/23 inst. 06 ()2-Butanone (MEK)0.0600 > 0.1 > 0.1 rf J/UJ G1
ICAL 5/15/23 inst. 06 ()Acetone 0.0400 > 0.1 > 0.1 rf J/UJ G1
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S13-CAM-DW1-052023
23E133-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S13-CAM-DW1-052023
23E133-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S-55-90-052023
23E133-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-55-90-052023
23E133-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E133
Quality Control Outliers for test method SW8260C, Initial Calibration Verification RRF
Compliance requirements for satisfactory initial calibration verifications are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Initil calibration verification is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
IV006E1502 ()2-Butanone (MEK)0.0570 < 0.1 < 0.1 rf J/UJ G3
IV006E1502 ()Acetone 0.0330 < 0.1 < 0.1 rf J/UJ G3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S13-CAM-DW1-052023
23E133-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S13-CAM-DW1-052023
23E133-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/P/V3/V5
S-55-90-052023
23E133-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-55-90-052023
23E133-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E133
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S13-CAM-DW1-052023
23E133-05 N 1,1,1,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,1,1-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,1,2,2-Tetrachloroethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,1,2-Trichloroethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,1-Dichloroethane 1.0 0.12 J 0.12 J -ug/l TR/P
S13-CAM-DW1-052023
23E133-05 N 1,1-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,1-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2,3-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2,3-Trichloropropane 2.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2,4-Trichlorobenzene 1.0 0.30 U 0.30 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2-Dibromo-3-
chloropropane 2.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2-Dibromoethane (EDB)1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2-Dichloroethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,2-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,3-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,3-Dichloropropane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,4-Dichlorobenzene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 1,4-Dioxane 100 50 U 50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 2,2-Dichloropropane 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/P/V3/
V5
S13-CAM-DW1-052023
23E133-05 N 2-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 2-Hexanone 20 10 U 10 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 4-Chlorotoluene 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N 4-Methyl-2-pentanone
(MIBK)10 5.0 U 5.0 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Acetone 20 10 U 10 UJ ug/l G1/G3/P/V3/
V5
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Data Validation Report for 23E133
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S13-CAM-DW1-052023
23E133-05 N Benzene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Bromobenzene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Bromochloromethane 1.0 0.30 U 0.30 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Bromodichloromethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Bromoform 1.0 0.30 U 0.30 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Bromomethane 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Carbon disulfide 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Carbon Tetrachloride 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Chlorobenzene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Chloroethane 2.0 1.0 U 1.0 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Chloroform 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Chloromethane 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N cis-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N cis-1,3-Dichloropropene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Cumene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Dibromochloromethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Dibromomethane 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Dichlorodifluoromethane 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Ethylbenzene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N m,p-Xylene 2.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Methyl tert-butyl ether
(MTBE)1.0 0.30 U 0.30 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Methylene chloride 2.0 1.0 U 1.0 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N n-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N n-Propylbenzene 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N o-Xylene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N p-Cymene (p-
Isopropyltoluene)1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N sec-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l P
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Data Validation Report for 23E133
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S13-CAM-DW1-052023
23E133-05 N Styrene 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N tert-Butylbenzene 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Tetrachloroethene (PCE)1.0 0.30 U 0.30 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Toluene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N trans-1,2-Dichloroethene 1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N trans-1,3-Dichloropropene 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Trichloroethene (TCE)1.0 0.20 U 0.20 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Trichlorofluoromethane 1.0 0.50 U 0.50 UJ ug/l P
S13-CAM-DW1-052023
23E133-05 N Vinyl chloride 1.0 0.30 U 0.30 UJ ug/l P
S-55-90-052023
23E133-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-55-90-052023
23E133-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-55-90-052023
23E133-01 N Chloroform 1.0 0.37 J 1.0 U ug/l V
S-78-91-052023
23E133-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-78-91-052023
23E133-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-052023
23E133-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-91-91-05-2023D
23E133-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
SWMU-13-EB-052023
23E133-06 EB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230515-13
23E133-07 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOQ) based on the sample concentration.
In instances where no LOD is provided, results are reported down to the LOQ.
Trace values are not included in the qualified results table unless additional reason codes are associated.
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Data Validation Report for 23E133
Reason Code Definitions
Code Definition
G1 Initial Calibration RRF
G3 ICV RRF
P Sample preservation/collection requirement not met.
TR Trace Level Detect
V Equipment Blank
V3 CCV RRF
V5 Ending Continuing Calibration Verification
Flag Code and Definitions
Flag Definition
J Estimated Value
N The analysis indicates the presence of an analyte for which there was presumptive evidence to make a tentative identification.
NJ
The analyte has been tentatively identified or presumptively as present
and the associated numerical value was the estimated concentration in
the sample.
R The data are rejected due to deficiencies in meeting QC criteria and may not be used for decision making.
U Undetected: The analyte was analyzed for, but not detected.
UJ The analyte was not detected; however, the result is estimated due to discrepancies in meeting certain analyte-specific quality
control criteria.
X Result may require rejection; PDT attention required
Bias
-The result may be biased low
+The result may be biased high
Note - The bias field is a separate field; however, it is an integral part of the final flag (qualifier) on the sample result
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Data Validation Report for 23E133
Review Questions
Method: SW8015D (Nonhalogenated Organics using GC/FID)
Review Questions Yes No NA Comment
Did Chain-of-Custody information agree with laboratory
report and EDD for requested field samples and tests?•
Were samples preserved properly and received in good
condition?•
Were holding times met?•
Were sample receipt temperatures met?•
Were QAPP specified PQLs achieved?•
Were all QAPP-specified target analytes reported?•
Was the Calibration with acceptance criteria?•
Check and recalculate the response factors and average
response factors for a least one target compound.•
Check and recalculate the %RSD for one of more target
compounds. Verify that the recalculated values agree
with the laboratory reported values.
•
Was a second source verification analyzed after the ICAL
and all analytes within criteria?•
Were CCVs ran at the required frequency and within
acceptance criteria?•
Check and recalculate the continuing calibration
verification for at least one target analyte.•
Was a method blank prepared and analyzed with each
batch?•
Were target analytes detected in the method blank above
the MDL?•
Were target analytes reported in the field blank analyses
above the MDL?•Equipment Blank
If a field duplicate was analyzed, were the RPDs within
QAPP acceptance limits?•
Was an LCS/LCSD pair prepared and analyzed with each
batch?•
Were the LCS/LCSD recoveries within QAPP acceptance
limits?•
Were the LCS/LCSD RPDs within QAPP acceptance
limits?•
Was the duplicate RPD within QAPP acceptance limits?•
Was a MS/MSD pair prepared with each batch?•
Were MS/MSD recoveries and RPD within QAPP
acceptance limits?•
Were surrogate recoveries within QAPP acceptance
limits?•
Were reported sample concentrations within calibration
range?•
Have all Laboratory Case Narrative comments/findings
been addressed in the data review process?•
Were instrument run logs present and filled out
appropriately?•
Were sample preparation sheets present and filled out
appropriately?•
Check and recalculate the at least one target analyte for
a given sample and verify that recalculated values agree
with the laboatory reported values.
•
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Data Validation Report for 23E133
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Were there discrepancies between the COC and the
samples received?•
Were there discrepancies between the COC and the
sample labels?•
Were samples relinquished properly on the COC?•
Were all samples properly preserved?•
Sample #5 had a bubble greater than 6mm. The
laboratory used a sample vial with the smallest
bubble first. Results were qualified J/UJ with P
reason code.
Were sampling dates/times, date and time of laboratory
receipt of samples, and sample conditions upon receipt
at the laboratory (including preservation, pH, and
temperature) documented?
•
Were sample results reported with percent moisture
correction if required?•
Were analytical methods performed and analysis dates
present?•
Were all requested target analytes reported?•
Were QAPP specified Project Quantitation Limit Goals
achieved? (The laboratory LOQ is compared to the
QAPP Project Quantitation Goal)
•
Various compounds are reported with detection
(s) and non-detect(s) at levels (LOQs) greater
than the project PQGs.
Were holding times met?•
Were trip blanks analyzed at the proper frequency and in
control?•
Were field blanks analyzed at the proper frequency and
in control?•
Were equipment blanks analyzed at the proper frequency
and in control?•See QC outliers. Equipment blank.
Was a method blank prepared and analyzed with each
batch?•
Were target analytes in the method blank less than DL?•
Was an LCS/LCSD pair prepared and analyzed with each
batch?•
Were LCS/LCSD recoveries within project acceptance
limits?•
Was the LCS/LCSD RPD within project acceptance
limits?•
Was a MS/MSD pair prepared with each batch?•1 of 2 batches prepared with a project MS/MSD.
Were MS/MSD recoveries within project acceptance
limits?•
Was the MS/MSD RPD within project acceptance limits?•
If ISM was used for sample collection, were laboratory
triplicates analyzed and within project acceptance limits?•
Were surrogate recoveries within project acceptance
limits?•
Were field replicates (duplicates, triplicates, etc.)
analyzed at the proper frequency and in control?•
Were reported sample concentrations within calibration
range?•
Was the GC/MS system properly tuned based on method
criteria?•
Was instrument tuning completed every 12 hours during
sample analysis?•
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Data Validation Report for 23E133
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Was the Calibration within project acceptance criteria?•See QC outliers
Was a ICV performed after each ICAL prior to sample
analysis and within project acceptance criteria?•See QC outliers
Were CCVs run at the required frequency and within
project acceptance criteria?•See QC outliers
Were internal standard retention times and area criteria
within project acceptance criteria?•
Were internal standards spiked for every sample,
standard, and QC sample?•
Were instrument run logs present and filled out
appropriately?•
Were sample preparation sheets present and filled out
appropriately?•
Were certificates of standard traceability and
documentation of standard solution preparation provided?•
Were recalculation of QC Elements and Sample Results
performed?•
Were Relative Retention Times (RRTs) within ± 0.06
RRT units and updated with the latest daily CCV?•
Were chromatograms checked for peak integration?
(10% of automated integration and 100% of manual
integrations)
•
Were chromatograms checked for correct baseline/peak
integration and possible interferences?•
Were qualitative ion mass present?•
Have all Laboratory Case Narrative comments/findings
been addressed in the data review process?•
Were DoD QSM corrective actions followed if deviations
were noted?•Response factor out of control and samples not
re-analyzed/re-extracted.
Were any data recommended for exclusion in the data
validation process?•
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GC VALIDATION WORKSHEET - INITIAL CALIBRATION
SDG #: 23E133 Date: 7/24/23
Lab: EMAX Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Sample ID: LB16044A 02/17/23 05:47 Calibration ID: ICAL 02/17/2023
Compound ID: C10-C24 Compound ID: C10-C24
Reported RF: 25875 p. 298 Reported %RSD: 7.2%p. 298
Mean RF: 24916.6 p. 298
RF = Compound Area %RSD = Standard Deviation X 100
Compound Conc. Average RF
p. 298
Compound Area = 25874558 p. 304 RF Level 1 = 24620 RF Level 6 = 25682
Compound Conc. = 1000 p. 304 RF Level 2 = 22018 RF Level 7 = 25046
RF Level 3 = 23517
RF = 25875 Match RF Level 4 = 27659
RF Level 5 = 25875
Standard Deviation = 1802.34
Average RF = 24917 Match
%RSD = 7.2%Match
S4VEM
Comments:
Tooele SDG 23E133_8015_recalc Feb-00
GC VALIDATION WORKSHEET - CONTINUING CALIBRATION
EPA Level III / IV AFCEE Level I / 2 NEESA Level C / D
SDG #: 23E133 Date: 7/24/23
Lab: EMAX Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Sample ID: IDSD5B16002 ICV ID: IDSD5B16002
Compound ID: DIESEL(C10-C24) Compound ID: DIESEL(C10-C24)
Reported Conc: 535.16 p. 309 Reported %D: 7%p. 308
ICV Conc. = Compound Area %D = (True Value - Reported Value)/(True Value) X 100%
Mean RF Mean RF
Compound Area = 13334387.0 p. 309 True Value = 500 p. 308
Mean RF = 24916.619 p. 309 Reported Value = 535.16 p. 308
ICV Conc = 535.16 Match %D = -7%Match
%D Indicating Bias = 0.1
Comments:
Tooele SDG 23E133_8015_recalc Feb-00
GC VALIDATION WORKSHEET - SURROGATE SPIKES
EPA Level III / IV AFCEE Level I / 2 NEESA Level C / D
SDG #: 23E133 Date: 7/24/23
Lab: EMAX Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Sample ID: S-55-90-052023 / 23E133-01
Compound ID: Bromobenzene
Reported Recovery: 85%p. 275
% Recovery = Conc. Surr. In Sample X 100
Conc. Surr. Spiked
Conc. In Sample = 931 p. 275
Surr. Spike Conc. = 1100 p. 275
% Recovery = 85%Match
Comments:
Tooele SDG 23E133_8015_recalc Feb-00
GC VALIDATION WORKSHEET - MATRIX SPIKES/DUPLICATES
EPA Level III / IV AFCEE Level I / 2 NEESA Level C / D
SDG #: 23E133 Date: 7/24/23
Lab: EMAX Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Sample ID: S13-CAM-DWI-052023MS Sample ID: S13-CAM-DWI-052023MS / SI3-CAM-DW1
Compound ID: C10-C24 Compound ID: C10-C24
Recovery: 98%p. 290 RPD: 5%p. 290
% Recovery = Conc. MS - Conc. Unspiked Sample X 100
MS Spike Conc. RPD = |MS Conc. - MSD Conc.| X 100
(MS Conc. + MSD Conc.)/2
Conc. MS = 5430 p. 290
Unspiked Samp. = 0 p. 290 MS Conc. = 5430 p. 290
MS Spike Conc. = 5550 p. 290 MSD Conc. = 5690.0 p. 290
% Recovery = 98%Match RPD = 5%Match
Comments:
Tooele SDG 23E133_8015_recalc Feb-00
GC VALIDATION WORKSHEET - LABORATORY CONTROL SAMPLES
EPA Level III / IV AFCEE Level I / 2 NEESA Level C / D
SDG #: 23E133 Date: 7/24/23
Lab: EMAX Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Sample ID: DSE026WL Sample ID: DSE026WL / DSE026WC
Compound ID: C10-C24 Compound ID: C10-C24
Recovery: 101%p. 289 RPD: 1%p. 289
% Recovery = Conc. LCS X 100 RPD = |LCS Conc. - LCSD Conc.| X 100
LCS Spike Conc. (LCS Conc. + LCSD Conc.)/2
Conc. LCS = 5070 p. 289 LCS Conc. = 5070 p. 289
LCS Spike Conc. = 5000 p. 289 LCSD Conc. = 5120 p. 289
% Recovery = 101%Match RPD = 1%Match
Comments:
Tooele SDG 23E133_8015_recalc Feb-00
GC VALIDATION WORKSHEET
TARGET COMPOUND QUANTITATION
EPA Level III / IV AFCEE Level I / 2 NEESA Level C / D
SDG #: 23E133 Date: 7/24/23
Lab: EMAX Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Sample ID: DSE026WL
Compound ID: C10-C24
Reported Result: 5070 p. 289 240.808 ppm raw
Conc. In Sample = Area Cmpd. In Sample X Final Volume X Dilution Factor ) X (1000mg/g)
(Average RF) X (Initial Amount) X (% Solids) X (1000ml/kg)
Units
Area Sample = 12632694 Area p. 293
Average RF = 24916.6 p. 298
Final Volume = 1000 mL p. 323
Initial Amount = 1000 ml p. 323
Dilution Factor = 1 NA p. 289
Percent Solids= 100%%Liquid sample
Conc. In Sample = 5070 Match
Comments: Recalculations were done on the LCS because the project sample result was ND.
Tooele SDG 23E133_8015_recalc Feb-00
SDG #: 23E133 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Batch
Tune ID: REW407
Recalculated Ion Ratio: 175:174
Reported Ratio: 7.3% p. 141
Relative Abundance (Ion Ratio) = Response of Target Mass × 100%
Response of Reference Mass
Target Mass Response = 13296 p. 141
Reference Mass Response = 182323 p. 141
Calculated Ratio = 7.3%Match
Comments:
S4VEM
INSTRUMENT PERFORMANCE CHECK / TUNE
VOC SW8260
CALCULATIONS
Inst Perf
SDG #: 23E133 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
RRF Standard ID: REW252
Analyte: Chloroform ReCalc
Calibration Level: 5
Reported Calibration RRF: 0.639 p. 79
RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
Analyte Response = 1137254 p. 100
ISTD Response = 3557639 p. 100 ISTD: 1,4-Difluorobenzene
Analyte Conc. = 5.0 p. 100
ISTD Conc. = 10.0 p. 100
Calculated RRF = 0.639 Match
Calibration ID: ICAL 5/15/23 13:47
Analyte: Chloroform
Reported Average RRF: 0.603 p. 79
Reported %RSD: 6.29% p. 79
%RSD = Standard Deviation × 100%
Average RRF
RF Lvl 1: 0.613 RF Lvl 6: 0.536
RF Lvl 2: 0.584 RF Lvl 7: 0.598
RF Lvl 3: 0.599 RF Lvl 8: 0.610
RF Lvl 4: 0.636 RF Lvl 9: 0.556
RF Lvl 5: 0.639 RF Lvl 10: 0.660
Standard Deviation = 0.038
Calculated Average RRF = 0.603 Match
Calculated %RSD = 6.27%Match
Comments:
S4VEM
INITIAL CALIBRATION
VOC SW8260
CALCULATIONS
ICAL
SDG #: 23E133 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
%D = 100% × ( CV RRF - Avg RRF ) / Avg RRF RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
ICV ID: IV006E1502
Analyte: Carbon Tetrachloride
ISTD: 1,4-Difluorobenzene
Reported ICV RRF: 0.405 p. 131
Reported %D: 2.8%p. 131
Analyte Response = 1685341 p. 135
ISTD Response = 4163900 p. 134
Analyte Conc. = 10.0 p. 135
ISTD Conc. = 10.0 p. 134
Mean RRF (ICAL) = 0.394 p. 131
Calculated ICV RRF =0.405 Match
Calculated %D = 2.8%Match
CCV ID: CV006E1S06
Analyte: Methylene chloride
ISTD: 1,4-Difluorobenzene
Reported CCV RRF: 0.417 p. 145
Reported %D: -6.4% p. 145
Analyte Response = 1858921 p. 148
ISTD Response = 4453053 p. 148
Analyte Conc. = 10.0 p. 148
ISTD Conc. = 10.0 p. 148
Mean RRF (ICAL) = 0.392 p. 145
Calculated CCV RRF =0.417 Match
Calculated %D = 6.5%Match
Comments:
S4VEM
INITIAL / CONTINUING CALIBRATION VERIFICATION
VOC SW8260
CALCULATIONS
ICV-CCV
SURROGATE SPIKES/SYSTEM MONITORING COMPOUNDS
SDG #: 23E133 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: S-55-90-052023 / 23E133-01
Compound ID: 1,2-Dichloroethane-d4
Reported %Recovery: 101.0% p. 12
% Recovery = Conc. Surr. In Sample × 100%
Conc. Surr. Spiked
Conc. In Sample = 10.10 p. 12
Surr. Spike Conc. = 10.00 p. 12
Calculated %Recovery = 101.0% Match
Comments:
CALCULATIONS
S4VEM
VOC SW8260
Surr
GC/MS VALIDATION WORKSHEET - MATRIX SPIKES/DUPLICATES
SDG #: 23E133 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Parent Sample ID: S13-CAM-DW1-052023 / 23E133-05 Parent Sample ID: S13-CAM-DW1-052023 / 23E133-05
Compound ID: Carbon Tetrachloride Compound ID: Carbon Tetrachloride
Recovery: 84%p. 45 RPD: 2%p. 45
% Recovery = Conc. MS - Conc. Unspiked Sample X 100 RPD = |MS Conc. - MSD Conc.| X 100
MS Spike Conc.(MS Conc. + MSD Conc.)/2
Conc. MS = 8.44 p. 45 MS Conc. = 8.44 p. 45
Unspiked Samp. = 0.0 p. 45 MSD Conc. = 8.25 p. 45
MS Spike Conc. = 10.0 p. 45
RPD = 2%Match
% Recovery = 84%Match
Comments:
Mtrx Spk
SDG #: 23E133 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: V006E19L
Analyte: Trichloroethene
Reported %Recovery: 101% p. 42
%Recovery = Conc. LCS × 100%
LCS Spike Conc.
Conc. LCS = 10.1 p. 42
LCS Spike Conc. = 10 p. 42
Calculated %Recovery = 101% Match
Sample ID: V006E19L / V006E19C
Analyte: Trichloroethene
Reported RPD: 0 p. 42
RPD = | LCS Conc. - LCSD Conc.| × 100%
(LCS Conc. + LCSD Conc.)/2
LCS Conc. = 10.10 p. 42
LCSD Conc. = 10.10 p. 42
Calculated RPD = 0% Match
Comments:
S4VEM
VOC SW8260
LABORATORY CONTROL SAMPLES
CALCULATIONS
LCS
SDG #: 23E133 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: S-55-90-052023 / 23E133-01
Compound ID: Chloroform
Reported Result: 0.37 p. 11
Conc. In Sample = Analyte Resp. × Conc. of IS × Final Volume × Dilution Factor
IS Resp. Average RRF Initial Amount
Analyte Response = 92697 p. 12
IS Response = 4126343 p. 12 IS: 1,4-DIFLUOROBENZENE
IS Conc. = 10.0 p. 12
Average RRF = 0.603 p. 79
Final Volume (mL) = 25 p. 11
Initial Amount (mL) = 25 p. 11
Dilution Factor = 1 p. 11
Conc. In Sample = 0.37 Match
Comments:
S4VEM
VOC SW8260
SAMPLE RESULT VERIFICATION
CALCULATIONS
Rslt Ver
Data Validation Report for 23E135
SDG:
Facility:
Guidance Document:
Event:
Data Review Contractor:
Data Review Level:
23E135
USAEC, TEAD-S
FINAL Uniform Federal Policy - Quality Assurance Project Plan Tooele Army
Depot South, Utah, October 2021
TEAD-S 2023 Annual Monitoring Groundwater
Synectics, Sacramento, CA
S4VEM
Project Manager:
Date Submitted:
Andrew Castor
August 07, 2023
Primary Data Reviewer:Kathryn Cantone, Data Review Chemist
Field Sample ID Lab Sample ID Matrix Type/Type Code SW
8
2
6
0
C
S-150-20-052023 23E135-01 Water Field Sample/N X
S-38-90-052023 23E135-02 Water Field Sample/N X
S-40-90-052023 23E135-04 Water Field Sample/N X
S-40-90-05-2023D 23E135-03 Water Field Duplicate/FD X
TB-20230517-26 23E135-05 Water Trip Blank/TB X
Second Reviewer:Kathryn Cantone, Senior Scientist
Contract Laboratory(ies):EMAX Laboratories, Inc., Torrance, CA
Prime Contractor:Brice Environmental Services Corporation, Salt Lake City, UT (BRSS)
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Data Validation Report for 23E135
This report assesses the analytical data quality associated with the analyses listed on the preceding cover
page at S4VEM data validation level. This assessment has been made through a combination of automated
data review (ADR) and supplemental manual review, the details of which are described below. The approach
taken in the review of this data set is consistent with the requirements contained in the FINAL Uniform Federal
Policy - Quality Assurance Project Plan Tooele Army Depot South, Utah, October 2021 and the additional
guidance documents incorporated by reference to the extent possible. Where definitive guidance is not
provided, results have been evaluated in a conservative manner using professional judgment.
Sample collection was managed and directed by Brice Environmental Services Corporation, Salt Lake City, UT
(BRSS); analyses were performed by EMAX Laboratories, Inc., Torrance, CA and were reported under sample
delivery group (SDG) 23E135. Data have been evaluated electronically based on electronic data deliverables
(EDDs) provided by the laboratory, and hard copy data summary forms have also been reviewed during this
effort and compared to the automated review output by the reviewers whose signatures appear on the
following page. Findings based on the automated data submission and manual data verification processes are
detailed in the ADR narrative and throughout this report.
All quality control (QC) elements associated with this SDG have been reviewed by a project chemist in
accordance with the requirements defined for the project. This review is documented in the attached Data
Review Checklists. The QC elements listed below were supported by the electronic deliverable and were
evaluated using ADR processes.
Results of the ADR process were subsequently reviewed and updated as applicable by the data review
chemists identified on the signature page. Quality control elements that were not included in the electronic
deliverable were reviewed manually and findings are documented within this report. Summaries of findings
and associated qualified results are documented throughout this report.
A total of 10 results (3.23%) out of the 310 results (sample and field QC samples) reported are qualified
based on review and 0 results (0.00%) have been rejected or deemed a serious deficiency (X qualifier). Trace
values, defined as results that are qualified as estimated because they fall between the detection limit and the
reporting limit/limit of quantitation, are not counted as qualified results in the above count. The qualified
results are detailed throughout this report and discussed in the narrative below, where appropriate.
Continuing Calibration Verification
Field Duplicate RPD
Lab Blank
LCS Recovery
LCS RPD
MS Recovery
MS RPD
Prep Hold Time
Surrogate
Test Hold Time
Trip Blank
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Data Validation Report for 23E135
Samples 23E0135-01 underwent S4VEM and the remaining samples S2BVEM.
The laboratory noted that corrections on the sample labels were not dated. The samples were logged
according to the CoC.
Analytical Method Data Reviewer Comment
SW8260C The laboratory noted that the Minimum Response Factor for all analytes were within
method recommended response factors with the exception of Acetone and 2-Butanone.
Narrative Comments
Reviewed by Kathryn Cantone, Data Review Chemist, Synectics,
Sacramento, CA
July 24, 2023
Reviewed by Kathryn Cantone, Senior Scientist, Synectics,
Sacramento, CA
August 07, 2023
As the First Reviewer, I certify that I have performed a data review process in accordance with the
requirements of the project guidance document, and have compared the electronic data to the laboratory's
hard copy report and have verified the consistency of the reported sample results and method quality control
data between the two deliverables.
As the Second Reviewer, I certify that I have performed a quality assurance review of the report generated
by the First Reviewer.
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Data Validation Report for 23E135
Quality Control Outliers for test method SW8260C, Continuing Calibration Verification RRF
Compliance requirements for satisfactory continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
CV006E1504 ()2-Butanone (MEK)0.0540 > 0.1 > 0.1 rf J/UJ V3
CV006E1504 ()Acetone 0.0330 > 0.1 > 0.1 rf J/UJ V3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Continuing Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-150-20-052023
23E135-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-150-20-052023
23E135-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E135
Quality Control Outliers for test method SW8260C, Ending Continuing Calibration Verification
Compliance requirements for satisfactory closing continuing calibration are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Continuing calibration is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
EV006E1504 (EV)2-Butanone (MEK)0.0630 < 0.1 < 0.1 rf J/UJ V5
EV006E1504 (EV)Acetone 0.0380 < 0.1 < 0.1 rf J/UJ V5
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Ending Continuing Calibration Verification for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-150-20-052023
23E135-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-150-20-052023
23E135-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E135
Quality Control Outliers for test method SW8260C, Initial Calibration RRF
Compliance requirements for satisfactory initial calibration are established to ensure that the instrument is capable of producing acceptable
qualitative and quantitative data. Initial calibration is performed to verify and evaluate instrument performance prior to sample analysis.
Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
ICAL 5/15/23 inst. 06 ()2-Butanone (MEK)0.0600 > 0.1 > 0.1 rf J/UJ G1
ICAL 5/15/23 inst. 06 ()Acetone 0.0400 > 0.1 > 0.1 rf J/UJ G1
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-150-20-052023
23E135-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-150-20-052023
23E135-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E135
Quality Control Outliers for test method SW8260C, Initial Calibration Verification RRF
Compliance requirements for satisfactory initial calibration verifications are established to ensure that the instrument is capable of producing
acceptable qualitative and quantitative data. Initil calibration verification is performed to verify and evaluate instrument performance during
sample analysis. Summary forms were evaluated against project acceptance criteria, and any associated qualified results, are listed below.
Sample ID/
Lab Sample ID Analyte Result
Warning
Limits
Control
Limits Units Qualifier
Reason
Code Comment
IV006E1502 ()2-Butanone (MEK)0.0570 < 0.1 < 0.1 rf J/UJ G3
IV006E1502 ()Acetone 0.0330 < 0.1 < 0.1 rf J/UJ G3
IV006E1502 ()Acetone 0.0570 < 0.1 < 0.1 rf J/UJ G3
Where two qualifiers are listed, such as 'J/UJ', the first applies to positive results, and the second to non-detect results.
Upper and Lower Warning and Control Limits are abbreviated UWL, LWL, UCL, and LCL in the Comment field.
Qualified Results associated with the Initial Calibration Verification RRF for SW8260C
FieldSample ID Type Analyte LOQ Lab Result Qualified
Result Bias Units Reason
S-150-20-052023
23E135-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-150-20-052023
23E135-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOD) or (LOQ) based on the sample concentration and the validation guidance.
In instances where no LOD is provided, results are reported down to the LOQ.
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Data Validation Report for 23E135
Table of All Qualified Results
Test Method: SW8260C Extraction Method: SW5030B
FieldSample ID /
LabSample ID Type Analyte LOQ Lab Result Qualified Result Bias Units Reason
S-150-20-052023
23E135-01 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-150-20-052023
23E135-01 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-38-90-052023
23E135-02 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-052023
23E135-04 N Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
S-40-90-05-2023D
23E135-03 FD Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB 2-Butanone (MEK)20 10 U 10 UJ ug/l G1/G3/V3/V5
TB-20230517-26
23E135-05 TB Acetone 20 10 U 10 UJ ug/l G1/G3/V3/V5
Analytes not found in project samples are reported as not detected at the limit of detection (LOD) unless blank contamination occurs and
then the sample may be reported as not detected at the (LOQ) based on the sample concentration.
In instances where no LOD is provided, results are reported down to the LOQ.
Trace values are not included in the qualified results table unless additional reason codes are associated.
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Data Validation Report for 23E135
Reason Code Definitions
Code Definition
G1 Initial Calibration RRF
G3 ICV RRF
TR Trace Level Detect
V3 CCV RRF
V5 Ending Continuing Calibration Verification
Flag Code and Definitions
Flag Definition
J Estimated Value
N The analysis indicates the presence of an analyte for which there was presumptive evidence to make a tentative identification.
NJ
The analyte has been tentatively identified or presumptively as present
and the associated numerical value was the estimated concentration in
the sample.
R The data are rejected due to deficiencies in meeting QC criteria and may not be used for decision making.
U Undetected: The analyte was analyzed for, but not detected.
UJ The analyte was not detected; however, the result is estimated due to discrepancies in meeting certain analyte-specific quality
control criteria.
X Result may require rejection; PDT attention required
Bias
-The result may be biased low
+The result may be biased high
Note - The bias field is a separate field; however, it is an integral part of the final flag (qualifier) on the sample result
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Data Validation Report for 23E135
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Were there discrepancies between the COC and the
samples received?•
Were there discrepancies between the COC and the
sample labels?•
Were samples relinquished properly on the COC?•
Were all samples properly preserved?•
Were sampling dates/times, date and time of laboratory
receipt of samples, and sample conditions upon receipt
at the laboratory (including preservation, pH, and
temperature) documented?
•
Were sample results reported with percent moisture
correction if required?•
Were analytical methods performed and analysis dates
present?•
Were all requested target analytes reported?•
Were QAPP specified Project Quantitation Limit Goals
achieved? (The laboratory LOQ is compared to the
QAPP Project Quantitation Goal)
•
Various compounds are reported with detection
(s) and non-detect(s) at levels (LOQs) greater
than the project PQGs.
Were holding times met?•
Were trip blanks analyzed at the proper frequency and in
control?•
Were field blanks analyzed at the proper frequency and
in control?•
Were equipment blanks analyzed at the proper frequency
and in control?•
Was a method blank prepared and analyzed with each
batch?•
Were target analytes in the method blank less than DL?•
Was an LCS/LCSD pair prepared and analyzed with each
batch?•
Were LCS/LCSD recoveries within project acceptance
limits?•
Was the LCS/LCSD RPD within project acceptance
limits?•
Was a MS/MSD pair prepared with each batch?•
Were MS/MSD recoveries within project acceptance
limits?•
Was the MS/MSD RPD within project acceptance limits?•
If ISM was used for sample collection, were laboratory
triplicates analyzed and within project acceptance limits?•
Were surrogate recoveries within project acceptance
limits?•
Were field replicates (duplicates, triplicates, etc.)
analyzed at the proper frequency and in control?•
Were reported sample concentrations within calibration
range?•
Was the GC/MS system properly tuned based on method
criteria?•
Was instrument tuning completed every 12 hours during
sample analysis?•
Was the Calibration within project acceptance criteria?•See QC outliers
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-.000000
ENV.ADR
August 07, 2023 Page 10 of 11
Data Validation Report for 23E135
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Was a ICV performed after each ICAL prior to sample
analysis and within project acceptance criteria?•See QC outliers
Were CCVs run at the required frequency and within
project acceptance criteria?•See QC outliers
Were internal standard retention times and area criteria
within project acceptance criteria?•
Were internal standards spiked for every sample,
standard, and QC sample?•
Were instrument run logs present and filled out
appropriately?•
Were sample preparation sheets present and filled out
appropriately?•
Were certificates of standard traceability and
documentation of standard solution preparation provided?•
Were recalculation of QC Elements and Sample Results
performed?•
Were Relative Retention Times (RRTs) within ± 0.06
RRT units and updated with the latest daily CCV?•
Were chromatograms checked for peak integration?
(10% of automated integration and 100% of manual
integrations)
•
Were chromatograms checked for correct baseline/peak
integration and possible interferences?•
Were qualitative ion mass present?•
Have all Laboratory Case Narrative comments/findings
been addressed in the data review process?•
Were DoD QSM corrective actions followed if deviations
were noted?•Response factors out of control and samples not
re-extracted/re-analyzed.
Were any data recommended for exclusion in the data
validation process?•
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-.000000
ENV.ADR
August 07, 2023 Page 11 of 11
SDG #: 23E135 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Batch
Tune ID: REW341
Recalculated Ion Ratio: 175:174
Reported Ratio: 6.9% p. 119
Relative Abundance (Ion Ratio) = Response of Target Mass × 100%
Response of Reference Mass
Target Mass Response = 5003 p. 119
Reference Mass Response = 72040 p. 119
Calculated Ratio = 6.9%Match
Comments:
S4VEM
INSTRUMENT PERFORMANCE CHECK / TUNE
SW 8260 VOC
CALCULATIONS
Inst Perf
SDG #: 23E135 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
RRF Standard ID: REW252
Analyte: Chloroform ReCalc
Calibration Level: 5
Reported Calibration RRF: 0.639 p. 57
RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
Analyte Response = 1137254 p. 78
ISTD Response = 3557639 p. 78 ISTD: 1,4-Difluorobenzene
Analyte Conc. = 5.0 p. 78
ISTD Conc. = 10.0 p. 78
Calculated RRF = 0.639 Match
Calibration ID: ICAL 5/15/23 13:47
Analyte: Chloroform
Reported Average RRF: 0.603 p. 57
Reported %RSD: 6.29% p. 57
%RSD = Standard Deviation × 100%
Average RRF
RF Lvl 1: 0.613 RF Lvl 6: 0.536
RF Lvl 2: 0.584 RF Lvl 7: 0.598
RF Lvl 3: 0.599 RF Lvl 8: 0.610
RF Lvl 4: 0.636 RF Lvl 9: 0.556
RF Lvl 5: 0.639 RF Lvl 10: 0.660
Standard Deviation = 0.038
Calculated Average RRF = 0.603 Match
Calculated %RSD = 6.27%Match
Comments:
S4VEM
INITIAL CALIBRATION
SW 8260 VOC
CALCULATIONS
ICAL
SDG #: 23E135 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
%D = 100% × ( CV RRF - Avg RRF ) / Avg RRF RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
ICV ID: IV006E1502
Analyte: Carbon Tetrachloride
ISTD: 1,4-Difluorobenzene
Reported ICV RRF: 0.405 p. 109
Reported %D: 2.8%p. 109
Analyte Response = 1685341 p. 113
ISTD Response = 4163900 p. 112
Analyte Conc. = 10.0 p. 113
ISTD Conc. = 10.0 p. 112
Mean RRF (ICAL) = 0.394 p. 109
Calculated ICV RRF =0.405 Match
Calculated %D = 2.8%Match
CCV ID: CV006E1504
Analyte: Methylene chloride
ISTD: 1,4-Difluorobenzene
Reported CCV RRF: 0.397 p. 123
Reported %D: 1.3% p. 123
Analyte Response = 1797401 p. 126
ISTD Response = 4523242 p. 126
Analyte Conc. = 10.0 p. 126
ISTD Conc. = 10.0 p. 126
Mean RRF (ICAL) = 0.392 p. 123
Calculated CCV RRF =0.397 Match
Calculated %D = 1.4%Match
Comments:
S4VEM
INITIAL / CONTINUING CALIBRATION VERIFICATION
SW 8260 VOC
CALCULATIONS
ICV-CCV
SURROGATE SPIKES/SYSTEM MONITORING COMPOUNDS
SDG #: 23E135 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: S-150-20-052023 / 23E135-01
Compound ID: 1,2-Dichloroethane-d4
Reported %Recovery: 97.2% p. 10
% Recovery = Conc. Surr. In Sample × 100%
Conc. Surr. Spiked
Conc. In Sample = 9.72 p. 10
Surr. Spike Conc. = 10.00 p. 10
Calculated %Recovery = 97.2% Match
Comments:
CALCULATIONS
S4VEM
SW 8260 VOC
Surr
GC/MS VALIDATION WORKSHEET - MATRIX SPIKES/DUPLICATES
SDG #: 23E135 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Second Review by: KMC
CALCULATIONS
Parent Sample ID: S-150-20-052023 / 23E135-01 Parent Sample ID: S-150-20-052023 / 23E135-01
Compound ID: Carbon Tetrachloride Compound ID: Carbon Tetrachloride
Recovery: 93%p. 35 RPD: 3%p. 35
% Recovery = Conc. MS - Conc. Unspiked Sample X 100 RPD = |MS Conc. - MSD Conc.| X 100
MS Spike Conc.(MS Conc. + MSD Conc.)/2
Conc. MS = 9.29 p. 35 MS Conc. = 9.29 p. 35
Unspiked Samp. = 0.0 p. 35 MSD Conc. = 9.59 p. 35
MS Spike Conc. = 10.0 p. 35
RPD = 3%Match
% Recovery = 93%Match
Comments:
Mtrx Spk
SDG #: 23E135 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: V006E16L
Analyte: Trichloroethene
Reported %Recovery: 102% p. 34
%Recovery = Conc. LCS × 100%
LCS Spike Conc.
Conc. LCS = 10.2 p. 34
LCS Spike Conc. = 10 p. 34
Calculated %Recovery = 102% Match
Sample ID: V006E16L / V006E16C
Analyte: Trichloroethene
Reported RPD: 1 p. 34
RPD = | LCS Conc. - LCSD Conc.| × 100%
(LCS Conc. + LCSD Conc.)/2
LCS Conc. = 10.20 p. 34
LCSD Conc. = 10.10 p. 34
Calculated RPD = 1% Match
Comments:
S4VEM
SW 8260 VOC
LABORATORY CONTROL SAMPLES
CALCULATIONS
LCS
SDG #: 23E135 Date: 7/24/2023
Lab: Emax Page: 1 of 1
Client: Brice Engineering Validated by: JT
Matrix: Water Second Review by: KMC
Sample ID: S-150-20-052023 / 23E135-01
Compound ID: Bromodichloromethane
Reported Result: 0.22 p. 9
Conc. In Sample = Analyte Resp. × Conc. of IS × Final Volume × Dilution Factor
IS Resp. Average RRF Initial Amount
Analyte Response = 39275 p. 10
IS Response = 4262091 p. 10 IS: 1,4-DIFLUOROBENZENE
IS Conc. = 10.0 p. 10
Average RRF = 0.421 p. 57
Final Volume (mL) = 25 p. 9
Initial Amount (mL) = 25 p. 9
Dilution Factor = 1 p. 9
Conc. In Sample = 0.22 Match
Comments:
S4VEM
SW 8260 VOC
SAMPLE RESULT VERIFICATION
CALCULATIONS
Rslt Ver

APPENDIX F
LABORATORY ANALYTICAL DATA REPORTS

This page intentionally blank
LABORATO RIES. INC.
3051 Fujita Street
Torrance, CA90505
Tet;(310}-618-8889
Date: 06-01-2023
EMAX Batch No.: 23E135
Attn: Travis Gouveia
Brice
3800 Centerpoint Dr. Suite 8223
Anchorage. fJJ( 99503
Subject: Laboratory Report
Project: TEAD-S
Enclosed is the Laboratory report for samples received on 05/18/23.
The data reported relate only to samples listed below :
Sample ID Control # Col Date Matrix
......... ......................
S-150·20-052023 E135-01 05/17/23 WATER
S-38·90-052023 E135-02 05/17/23 WATER
5-40-90-05·20230 E135-03 05/17/23 WATER
S-40-90·052023 E135·04 05/17/23 WATER
TB·20230517·26 E135-05 05/17/23 WATER
S·150·20·052023MS E135-01M 05/17/23 WATER
S·150·20-052023MSD E135'01S 05/17/23 WATER
The results are summarized on the following pages.
Please feel free to call if you have any questions concerning
these results.
Caspar J. Pang
Laboratory Director
Analysis
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
This report is confidential and intended solely for the use of the individual or
entity to whom it is addressed. This report shall not be reproduced except in full
or without the written approval of EMAX.
EMAX certifies that results included in this report meets all TNI & DOD requirements
unless noted in the Case Narrative.
NELAP Accredited Certificate Number CA002912022·24
ANAB Accredited DoD ELAP and ISO/IEC 17025 Certificate Number L2278 Testing
California ELAP Accredited Certificate Number 2672
REPORT ID: 23E135 Page 1 of 454
CHAIN-OF-CUSTODY RECORD Brice Engineering, Salt Lake City, UT
Andrew Castor [phone]
362 W. Pierpont Ave
SLC, UT 84101
COC # 770113-
20230517_2
Page 1/1 '2.Q~I?~ 11
Project Name: USAEC, TEAD·S Laboratory: EMAX Laboratories, Inc., Torrance, CA Event: TEAD-S 2023 Annual Monitoring
Project Number: 770113
WBS Code:
Comments:
"'C
SW8015D (A) = TPH-Diesel Range Organics 0 .c ....
QI
::i
....
III
QI I-
iii
U
~
iii I: «
I§Y~rj;·r::§AP~§~gg~&rlQ~~IMQQltqr:ir1~§f()~fu~w~(~r.i<
Samp
SamplelD Matrix Date Time Init.
1 S-150-20-052023 WG 5/1712023 1105 CMH/SC
2 S-38-90-052023 WG 5/1712023 1005 CMH/SC
3 S-40-90-05-2023D WG 5/17/2023 1155 CMH/SC
4 S-40-90-052023 WG 5/17/2023 1150 CMH/SC
5 TB-20230517-26 WQ 5/1712023 730 CMH/SC
Turnaround Time: Standard
Relinquished by: (Signature)
Date 0/I-::J-j20 ).. 3
J~C~
TIme 1"') 10
Received by: (Signature)
POC: Raman Singh (310)-618-8889 ext 119 Groundwater
Ship to: 3051 Fujita Street Torrance, CA 90505
Code Matrix
lNG·.·. Ground Water
WQ/ Water Quality Control Matrix II)
U
0 « > ~ , Code Container/Preservative
0 u
La 0 12t 2x 1 L Amber glass bottle with Teflon lined cap. Cool
0 <0
N 0' to 6'C; protected from light 00 00
S s 1</~17
3x VOA, 40 mL Clear glass vial with Teflon lined septa,
rJl rJl HCLlo pH < 2, Cool 0' to 6'C
~f 31
••••••••
< H i············· •...• < Y
Sample Depth (ft bgs)
Location ID Type Top -Bottom Cooler Comments
X S-150-20 N1/MS1/SD1 0.00 0.00 3
X S-38-90 N1 210.50 230.50 3
X S-40-90 N1 251.00 271.00 3
X S-40-90 N1 251.00 271.00 3
X TripBlank TB1 0.00 0.00 3
T aYIt':
Date OS/ISI(Z}
@2"/r.'1
cr;-(). z..
Shipping Date:
Master_COC.xlsx
TIme O'l:~~
Received by Laboratory: (Signature, Date, Time) & c itio
--
I
I
I
REPORT ID: 23E135 Page 2 of 454
REFERENCE: EMAX-SM02 Rev. 12
SAMPLE RECEIPT FORM 1
Type of Deli ve,y Airbill / Tracking Number ECN Ot~~I~~
It! Fedex D UPS D GSa D Others 111-11 Cl111'11 tJ Recipient .IIHI.It.1n€t 1olir-~Jt1vj
D EMAX Courier D Client DelivelY Date b.>/101Z1; Time "P(~7S ,.,
COC INSPECTION ,
Ill, Client Name tJ Client PM/FC IA'Sampler Name ~ampling DatelTime ~amplelD ¢Matrix
r6 Address riTel #IFax # D Courier Sil,'llature AnalysIs Required Preservative (if any) ~TAT
Safety Issues (if any) , D High concentrations expected D From Superfund Site D Rad screening required
Note:
PACKAGING INSPECTION
Container ~Cooler D Box D Other
Condition (otrQ(,tIOV\ 11 Custody Sea I D Intact D Damaged
Packaging 1(M;M: -0.2 rz( Bubble Pack D Styrofoam D Popcorn D Sufficient D
Temperatures I;4"'Cooler 11.·1/'.1 "c D Cooler 2 ---°c DCooler3 ---°c D Cooler 4 ---"c D Cooler 5 ---"c
(Cool. ::;6"C but not frozen) D Cooler 6 "c D Cooler 7 ___ "c . D Cooler 8 °c D Cooler 9 "c D Cooler 10 "c
8SIN 2"l10Sl1lO~ R-SIN 2101fDOtl7
---------
Thermometer: e-slN D-SIN
Comments: D Temperature is out of range. PM was informed IMMEDIATELY.
Note:
DISCREP ANCIES
LabSamplelD LabSampleContaineriD Code ClientSample LabellD I Information Corrective Action
I? ).0 lIIO f2J -L ----/
~ /
~ /
,.../ /
./' /
./' /
/' /
/' /'
/ iA /'
/" t-lyi5IJ..-. ) ~ Eft-'5/1417:-
0 "H holdin p g tilne re q uirelnent for water salTI p les is 15 mins. Water sam les for p p H anal y sis are received 1:fe v~d 15 minutes from sam y lin p g tiIne. -
NOTES/OBSERVA T10NS:
SAMPLE MATRIX IS DRINKING WATER" DYES Il1'NO
LEGEND: 0 Continue to next page.
Code Description-Sample Management
DI Analysis is not indicaled in ____ _
D2 Analysis mismatch COC vs label
D3 Sample ID mismatch COC vs label
D4 Sample ID is not indicated in ___ _
DS Container -[Improper] [leaking] [broken]
D6 DatelTime is not indicated In
D7 DatelTime mismatch COC vs label
D8 Sample listed in COC is nol receIved
D9 Sample received is not liSled in COC
,b; 0) No initial$n corrections III COCIB
W Contamer count mismatch cae vs received
REVIEWS:
Code Description-Sample Management
Dl3 Out of Holding Time
DI4 Bubble is >6mm
DIS No trip blank in cooler
DI6 Preservation not indicated in ____ _
D 17 Preservation mismatch COC vs label
D18 Insufficient chemical preservative
DI9 Insufficient Sample
D20 No filtration info for dissolved analysis
D1 I No sample for moisture detennination
022 ------------------------------------
D23
---------------IF'~I---------
Code Description-Sample Management
RI Proceed as indicated in¥COC 0 Label
f
R2 Refer to anached instruction
RJ Cancel the analysis
R4 Use vial with smallest bubble firsl
RS Log-in with latest sampling dale and timeT I min
R6 Ad jusl pH as necessal)'
R7 Filter and preserved as necessary
RS ______________________________________ ___
R9 -----------------------------------
RIO -----------------------------------
RII -----------------------------------
R12 -----------------------------------
REPORT ID: 23E135 Page 3 of 454
REPORTING CONVENTIONS
DATA QUALIFIERS:
Lab Qualifier AFCEE Qualifier Description
J F Indicates that the analyte is positively identified and the result is less
than LOQ/RL but greater than LOD/MDLlDL.
N Indicates presumptive evidence of a compound.
B B Indicates that the analyte is found in the associated method blank
as well as in the sample at above QC level.
E J Indicates that the result is above the maximum calibration range or
estimated value.
* * Out of QC limit.
Note: The above qualifiers are used to flag the results unless the project requires a different
set of qualification criteria.
ACRONYMS AND ABBREVIATIONS:
CRDL Contract Required Detection Limit
RL Reporting Limit
MRL Method Reporting Limit
MDL Method Detection Limit
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
DO Diluted out
DATES
The date and time information for leaching and preparation reflect the beginning date and time of the
procedure unless the method, protocol, or project specifically requires otherwise.
REPORT ID: 23E135 Page 4 of 454
LABORATORY REPORT FOR
BRICE
TEAD-S
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
SDG#: 23E135
REPORT ID: 23E135 Page 5 of 454
Client : BRICE
Project: TEAD-S
SDG 23E135
CASE NARRATIVE
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
A total of five(5) water samples were received on 05/18/23 to be analyzed for
Volatile Organics by GC/MS in accordance with Method SW5030B/8260C and project
specific requirements.
Holding Time
Samples were analyzed within the prescribed holding time.
Instrument Performance and Calibration
Instrument tune check was performed prior to calibration. Result was within
acceptance criteria. Multi-calibration points were generated to establish
initial calibration (ICAL). ICAL was verified using secondary source (ICV).
Continuing calibration (CCV) was carried out at a frequency required by the
project. All calibration requirements were satisfied. Note that" Minimum
Response Factor" for all analytes were within method recommended response
factors with the exception of Acetone and 2-Butanone. However, percent
recoveries for all target analytes were within 70-130% on all calibration
points. Refer to calibration summary forms of I CAL , ICV and CCV for details.
Method Blank
Method blank was prepared and analyzed at the frequency required by the project.
For this SDG, one (1) method blank was analyzed. V006E16B -result was compliant
to project requirement. Refer to sample result summary form for details.
Lab Control Sample
Lab control sample was prepared and analyzed at a frequency required by the
project. For this SDG, one (1) set of LCS/LCD was analyzed. V006E16L/V006E16C
were within LCS limits. Refer to LCS summary form for details.
Matrix QC Sample
Matrix spike sample was prepared and analyzed at a frequency required by the
project. For this SDG, one (1) set of MS/MSD was analyzed. 23E135-01M/23E135-01S
-all analytes were within MS QC limits. Refer to Matrix QC summary form for
details.
Surrogate
Surrogates were added on QC and field samples. All surrogate recoveries were
within QC limits. Refer to sample result summary forms for details.
Sample Analysis
Samples were analyzed according to prescribed analytical procedures. Results
were evaluated in accordance to project requirements. For this SDG, all quality
control requirements were met.
REPORT ID: 23E135 Page 6 of 454
Client
Project
Client
Sample ID
LCS1W
LCD1W
MBLK1W
BRICE
TEAD-S
TB-20230517-26
S-150-20-052023
S-38··90-052023
S-40-90-05-2023D
S-40·90-052023
S-150-20-052023MS
S-150-20-052023MSD
FN Filename
% Moist Percent Moisture
Laboratory Dilution %
Sample ID Factor Moist
V006E16L NA
V006E16C NA
V006E16B NA
23E135-05 NA
23E135-01 NA
23E135-02 NA
23E135-03 NA
23E135-04 NA
23E135-01M 1 NA
23E135-01S 1 NA
LAB CHRONICLE
VOLATILE ORGANICS BY GC/MS
WATER
Analysis Extraction
DateTime DateTime
---------
05/19/2307:06 05/19/2307:06
05/19/2307:32 05/19/2307:32
05/19/2308:24 05/19/2308:24
05/19/2311: 52 05/19/2311: 52
05/19/2312:18 05/19/2312:18
05/19/2312:44 05/19/2312:44
05/19/2313: 11 05/19/2313:11
05/19/2313: 37 05/19/2313: 37
05/19/2315:21 05/19/2315:21
05/19/2315:47 05/19/2315:47
Sample
Data FN
REW343
REW344
REW346
REW354
REW355
REW356
REW357
REW358
REW362
REW363
SDG NO. 23E135
Instrument ID 06
Calibration Prep.
Data FN Batch Notes
----------------
REW253 V006E16 Lab Control Sample (LCS)
REW253 V006E16 LCS Duplicate
REW253 V006E16 Method Blank
REW253 V006E16 Field Sample
REW253 V006E16 Field Sample
REW253 V006E16 Field Sample
REW253 V006E16 Field Sample
REW253 V006E16 Field Sample
REW253 V006E16 Matrix Spike Sample (MS)
REW253 V006E16 MS Duplicate (MSD)
REPORT ID: 23E135 Page 7 of 454
SAMPLE RESULTS
REPORT ID: 23E135 Page 8 of 454
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E135
S-150-20-052023
23E135-01
REW355
Ext Btch ID: V006E16
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
l,l,l,2-Tetrachloroethane
lillI-Trichloroethane
l,l,2,2-Tetrachloroethane
1, 1, 2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
l,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
l,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
l,3-Dichlorobenzene
1,3-Dichloropropane
l,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-l,2-Dichloroethene
cis-l,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-l,2-Dichloroethene
Trans-l,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1,2,3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
l,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/17/23 11:05
Date Received: 05/18/23
Date Extracted: 05/19/23 12:18
Date Analyzed: 05/19/23 12:18
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
--------------------------------------------
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.25 0.50
ND 1.0 0.15 0.30
ND 2.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
0.22J 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.50 1.0
0.54J 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
0.16J 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 o.n 0.50
ND 10 2.5 5.0
ND 2.0 0.50 1.0
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.11 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 100 25 50
RESULT SPK _AMT %RECOVERY QC LIMIT
--------------------------------------------
9.72 10.0 97 70-130
10.2 10.0 102 70-130
10.4 10.0 104 70-130
10.3 10.0 103 70-130
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E135 Page 9 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW355.D
Acq On 19 May 2023 12:18 pm
Sample 23E135-01
Misc 25mL
(QT Reviewed)
Vial: 15
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 13:01 2023 Quant Results File: V006E15.RES
/
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Quant Method
Title
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.09 114 4262091 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 15.54 117 3578694 10.00 ug/l 0.00
73) 1,2-DICHLOROBENZENE-D4 19.42 152 1328944 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 1417504 10.30 ug/l 0.00
Spiked Amount 10.000 Recovery = 103.00%
41) l,2-Dichloroethane-d4 9.22 65 930667 9.72 ug/l ~ 0.00
Spiked Amount 10.000 Recovery = 97.20%
54) Toluene-d8 12.92 98 4821422 10.37 ug/l ....... 0.00
Spiked Amount 10.000 Recovery = 103.70%
76) 4-Bromofluorobenzene 17.55 95 1531629 10.18 uglY 0.00
Spiked Amount 10.000 Recovery = 101.80%
./
Target Compounds Qvalue
30) Chloroform 7.60 83 138837 //~: ;~ ug/l 97
48) Bromodichloromethane 11.48 83 39275 ug/l 74
62) Dibromochloromethane 14.55 129 17146 0.16 ug/l 93
/
.{ /'
(#) = qualifier out of range (m) = manual integration
REW355.D V006E15.M Fri May 19 13:01:31 2023 Page 1
REPORT ID: 23E135 Page 10 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW355.D
Aeq On 19 May 2023 12:18 pm
Vial: 15
Operator: LYamas
Sample 23E135-01 Inst 06
Mise 25mL Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 13:01 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
lA.bundance I I
, 440000011
4200000 ,
40000001
3800000j
I
36000001
3400000
3200000
30000001
I
28000001
26000001
I
i
24000001
22000001
i
20000001
i
18000001
1
i
16000001
1
1400000i
I
12000001
I
1000000!
800000i
;
600000 1 ,
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
(J)
oi c:
'" -'" a;
E e
TIC: REW355.D
(RTE Integrator)
l3
ill
aJ
~ w
[IJ o
0::
9
I
U
° =>
'5
E e
.0 o
, , I
~~: fi:1 g ~ II ~ € ~ I E Q) I
l
eE II
400000i 0 I II 'i ° °E il I
, i I' ~ 1
1
1
1
, j. !Il I
I :c ill II II E 'i ° I, ill o I II I. e II .5 II I ,
i 200~Ll-.-r-.--'l,i"uoe;l~':;' :<,~--:-, :::;:1 ::::;~=:;:::; :::;:, =';=;::1 :::;:=;=; =;::; "!'/:J~,! l,,;:, =i,;::!,.':i,L::;:_, =i,!~L::;::, ::::;:,~, ':';::' , ::::;:!::::-;:::, :!-j'-,:;~::::-;:::, ::;::1 =;,o~-:;=, :;:, 1,J U::::rl ::;::;:=LJ~L::::::Ir-=;::::,~ ~;!-I ~';=, =;1=;::' ':;:'~=;:,=;=, T
[Time--> 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00
REW355.D V006E15.M Fri May 19 13:01:32 2023 Page 2
REPORT ID: 23E135 Page 11 of 454
\!\bundance
I
Rem
47
Scan 368 (7.575 min): REW253.D (-)
8S
I Ohrr~~~~~~~~TIn~~~~~~~1~5,~91~:~~15~11~"~"~1,~,,~,1~~3~"~1'
mlz--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190
!Abundance Scan 369 (7.597 min): REW355.D
I e
RaWo
~/z-->
~bundance
! I
I I
I
I
m/z-->
#30
Chloroform
Coneen: 0.54 ug/l
RT: 7.60 min Sean# 369
Delta R.T. 0.02 min
Lab File: REW355.D
Aeq: 19 May 2023 12:18 pm
Tgt Ion: 83 Resp: 138837
Ion Ratio Lower Upper
83 100
85 66.9 38.7 98.7
47 26.5 0.0 53.2
bundance Ion 83.00 (82.70 to 83.70): REW355lj
Ion 85.00 (84.70 to 85.70): REW355.~
30000 Ion 47.00 (46.70 to 47.70): REW355'
1
25000 ?60 I
20000
,~, I
15000
10000
5000
o
ime--> 7.20 7.40 7.60 7.80
~bundance
I
•
Scan 644 (11.461 min): REW253.D (-)
ar
., #48
Bromodiehloromethane
Coneen: 0.22 ug/l
Rem!
I 47
0~~~~~~.¥~~~rr~~~~~~~~~~r2rOr7~
rn/z--> 40 60 80 100 120 140 160 180 200 ~bun~d~an~c~e--~~~~--~S~ca~n~6~4=5~(1~1~.4~7=5=m~in~)~:R~E~W~35~5~.D~~~~==--~
. I 8t3
I
44
RaWo~
I
O~I ~~~fo~~~i~~~~~~~~~~~~'~I~~~~
m/z-->
Abundance'
Subl
50!
80 100 120 140 160 180 200
Scan 645 (11.475 min): REW355.D (-)
8~
I
i O~~~~~~~~~~~~Jh~~~~'1 I I '" I 1""
mlz--> 60 80 100 120 160 180 200
RT: 11.48 min Sean# 645
Delta R.T. 0.01 min
Lab File: REW355.D
Aeq: 19 May 2023 12:18 pm
Tgt
Ion
83
85
Ion: 83
Ratio
100
83.1
Resp:
Lower
32.9
39275
Upper
92.9
bundance Ion 83.00 (82.70 to 83.70): REW355.q
12000jlon 85.00 (84.70 to 85.70): REW355.Q
1 I 11.48 .
10000 (\
It' 8000 1/ \\\'
6000 I. I,
I' I'
/1 \\ II \ \
1/ \1
jl \
Ij '\ l , I\! ~'\
4000
1
2000
o
ime--> 11 .30 11.40 11.50 11.60
REW355.D V006E15.M Fri May 19 13:01:33 2023 Page 3
REPORT ID: 23E135 Page 12 of 454
Abundance . I
I Re",!
0 1 35
Iz-->
V\bundance
I I t
RaWo
Scan 881 (14.537 min): REW253.D (-)
1 9
129
htz--> 0 40 60 80 100 120 140 160 180 200 Fbund~an~c~e--~~~~~s~c~an-=88~2~(~147.~55~1~m~1i~f~~:~R~E~W~3~5~5.~D~(_7)~~-=~--~
I I
sU~01 44
#62
Dibromochloromethane
Concen: 0.16 ug/l
RT: 14.55 min Scan# 882
Delta R.T. 0.01 min
Lab File: REW355.D
Acq: 19 May 2023 12:18 pm
Tgt
Ion
129
127
Ion:129
Ratio
100
70.1
Resp:
Lower
46.0
17146
Upper
106.0
bundancelon 129.00 (128.70 to 129.70): REW36
Ion 127.00 (126.70 to 127.70): REW3~
6000 14.55
5000
4000
i
[l1E:-_->
I I 98
LI,II,J'"I"""", 10:. .!/..,J ,,,~
40 60 80 100 120 140 160 180 200 __ ~im~.e--> 14.4514.5014.5514.6014.65 J
REW355.D V006E15.M Fri May 19 13:01:33 2023 Page 4
REPORT ID: 23E135 Page 13 of 454
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E135
S-38-90-052023
23E135-02
REW356
Ext Btch ID: V006E16
Calib. Ref.: REW253
PARAMETER(S)
-----------------------------
1,1/1/2-Tetrachloroethane
l,l,I-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
l,l,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1, 2, 4-Trichlorobenzene
l,2-Dibromo-3-chloropropane
1/2-Dichlorobenzene
l,2-Dichloroethane
l,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
l,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-l,2-Dichloroethene
cis-l,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1.2-Dibromoethane
l,2,3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
l,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/17/23 10:05
Date Received: 05/18/23
Date Extracted: 05/19/23 12:44
Date Analyzed: 05/19/23 12:44
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
-------------------------------------------
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.25 0.50
ND 1.0 0.15 0.30
ND 2.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.50 1.0
0.25J 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.21 0.50
ND 10 2.5 5.0
ND 2.0 0.50 1.0
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.11 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 100 25 50
RESULT SPK AMT %RECOVERY QC LIMIT
--------------------------------------------
9.73 10.0 97 70-130
10.1 10.0 101 70-130
10.4 10.0 104 70-130
10.5 10.0 105 70-130
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E135 Page 14 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW356.D
Acq On 19 May 2023 12:44 pm
Sample 23E135-02
Misc 25mL
(QT Reviewed)
Vial: 16
Operator: LYamas
Inst 06
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 19 13:16 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
10.09
15.54
19.42
114 4373748
117 3708267
152 1367735
8.10 111 1481948
Recovery
9.22 65 955533
Recovery
12.92 98 5007380
Recovery
17.55 95 1568949
Recovery
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.49 ug/l
= 104.90%
9.73 ug/lr-·
= 97.30%
10.40 ug/l --
= 104.00%
10.13 ug/X
= 101.30%
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Qvalue Target Compounds
30) Chloroform 7.60 83 65397 0.25 ug/l 93
/
(#) = qualifier out of range (m) = manual integration
REW356.D V006E15.M Fri May 19 13:17:03 2023 Page 1
REPORT ID: 23E135 Page 15 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW356.D
Aeq On 19 May 2023 12:44 pm
Sample 23E135-02
Mise 25mL
Vial: 16
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 13:16 2023 Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Initial Calibration
Abund"ance
4600000j
44000001
42000001
40000001
i
38000001
3600000i
34000001
j
32000001
3000000j ,
28000001
2600000j
I
24000001
. I
i 22000001
I
2000000j
i
18000001
1600000;
14 000001
1200000j
10000001
I
8000001
6000001
I
4000001 ;
200000:
01..,--,-,
Time-->
:;;0
f-'" o·
E
~
£
U)
oi c:
'" .c:
1i)
E
2 o =>
'5
E
~
is
I 0; II
I I II
i 1'1 'L' !I !~\ 11\ v ~ ~~
, I ' I' 'I ' 'I
2.00 4.00 6.00 8.00
TIC: REW356.D
,
u]
Z
~ m o
~ o
::::J
...J
U. o ....
" II
" il
II
II ii
Ii
'I II 1\
II _J \..
-; ,
10.00
, I
12.00
I
I
!
I'
1\ ,"" , I
14.00
REW356.D V006E15.M Fri May 19 13:17:04 2023
I I
16.00
U)
oi
ai
N
E
2 g
'5
E
2 m
"
I '
18.00
c;
uJ
Z
ill
~
ill m o
~ g
I o
5
N.
I
20.00
Page 2
REPORT ID: 23E135 Page 16 of 454
('.bundance
ReOO
47
Scan 368 (7.575 min): REW253.D (-)
st3
O~~~~~~~~~~rrrr~~TITI~~~~~~~~~
im/z--> 30 40 50 60 70 80 90 1 00 110 120 130 140 150 160 170 180 190
('.bundance Scan 369 (7.595 min): REW356.D
8r
I
! i 94 119128 a ~TT'l"ilflilll!1Jli,Yr'f'h*fli'I'IlTI'flri'Nf-,l,'.-M' 'hI! i"f i~i ''', ,rrj'r1', I'to-j! i TO. ,hi I TT. ,nc. 'TTi I", .TT. ,T . ., ~, .en. ICT, CT: i CT •• rrl ! rei i rei i TTi i TT. '~i i i
m/z--> 30 40 50 60 70 80 90 100 110120 130 140 150 i 60 170 180 190
Abundance Scan 369 (7.595 min): REW356.D (-) I 8~
su~oj
47
I 118128 I O~~~ffIThti~~~+&~~~~TIn~~crrr~~~~~~
rn/z--> 30 40 50 60 70 80
#30
Chloroform
Concen: 0.25 ug/l
RT: 7.60 min Scan# 369
Delta R.T. 0.02 min
Lab File: REW356.D
Acq: 19 May 2023 12:44 pm
Tgt Ion: 83 Resp: 65397
Ion Ratio Lower Upper
83 100
85 69.8 38.7 98.7
47 34.3 0.0 53.2
bundance Ion 83.00 (82.70 to 83.70): REW356.Q
Ion 85.00 (84.70 to 85.70): REW356.Q
15000 Ion 47.00 (46.70 to 47.70): REW356.Q
I
7.60 !
1\
10000 ! \
I t'\ 5000
1 ~ J ~-c~. i
"" I;'" I"" I' I" ,;, " ITT'
ime--> 7.40 7.50 7.60 7.70 7.80
REW356.D V006E15.M Fri May 19 13:17:05 2023 Page 3
REPORT ID: 23E135 Page 17 of 454
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
23E135
S-40-90-05-2023D
23E135-03
Lab File ID: REW357
Ext Btch ID: V006E16
Calib. Ref.: REW253
PARAMETER(S)
~~----------------------------
1,1, 1, 2-Tetrachloroethane
lil,I-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
l,l-Dichloropropene
l,2,3-Trichloropropane
1, 2, 4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
l,2-Dichloropropane
l,3-Dichlorobenzene
1,3-Dichloropropane
l,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-l,2-Dichloroethene
cis-l,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-l,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1,2,3-Trichlorobenzene
1/4-Dioxane
SURROGATE PARAMETER(S)
----------- ------- ------------
1/2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/17/23 11:55
Date Received: 05/18/23
Date Extracted: 05/19/23 13:11
Date Analyzed: 05/19/23 13:11
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
--------------------------------------------
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
0.66J 1.0 0.10 0.20
1.4 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.25 0.50
ND 1.0 0.15 0.30
ND 2.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.50 1.0
1.0 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.21 0.50
ND 10 2.5 5.0
ND 2.0 0.50 1.0
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.11 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 100 25 50
RESULT SPK AMT %RECOVERY QC LIMIT
--------------------------------------------
9.96 10.0 100 70-130
10.2 10.0 102 70-130
10.5 10.0 105 70-130
10.1 10.0 101 70-130
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E135 Page 18 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW357.D
Acq On 19 May 2023 1:11 pm
Sample 23E135-03
Misc 25mL
(QT Reviewed)
Vial: 17
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 13:35 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15 ~
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.09 114 4281733 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 15.54 117 3614076 10.00 ug/l 0.00
73) l,2-DICHLOROBENZENE-D4 19.42 152 1321829 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 1399400 10.12 ug/l 0.00
Spiked Amount 10.000 Recovery == 101.20%
41 ) l,2-Dichloroethane-d4 9.22 65 957515 9.96 ug/l 0.00
Spiked Amount 10.000 Recovery == 9r.b0%
54) Toluene-d8 12.92 98 4917799 10.48 ug/l~ 0.00
Spiked Amount 10.000 Recovery == 104.80%
76) 4-Bromofluorobenzene 17.55 95 1519470 10.16 ug/r 0.00
Spiked Amount 10.000 Recovery == 10~60%
Target Compounds Qvalue
12) l,l-Dichloroethene 3.66 61 334418
.k
1.42 ug/l 97
24) l,l-Dichloroethane 5.75 63 173613 0.66 ug/l 97
30) Chloroform 7.60 83 261387 /1.01 ug/l 97
(#) == qualifier out of range (m) = manual integration
REW357.D V006E15.M Fri May 19 13:35:49 2023 Page 1
REPORT ID: 23E135 Page 19 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW357.D
Aeq On 19 May 2023 1:11 pm
Vial: 17
Operator: LYamas
Sample 23E135-03
Mise 25mL
MS Integration Params: RTE.P
Quant Time: May 19 13:35 2023
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
.. Response via
/\bundance
Tue May 16 12:41:48 2023
Initial Calibration
I
44000001
J
4200000j
I
4000000j
3800000)
I
36000001
I
3400000j
i
32000001
i
30000001
2800000j
I
26000001
24000001
2200000;
2000000j
18000001
1600000)
1
1
14000001
1
I
1200000j
i
1000000j ::;;;
1--
800000 1 ~ 1--0" ::;;; ~
1 w ~
I ~ g ~ I
1 ~ ~ 0 1\
(f)
f c:
'" .c:
ill e o :c o
is
N.
TIC: REW357,O
w'
rn
N z w ro o cr o
::J
-' LL
15 ".
Ii
II
II
'I
,I
~f
uJ z
W
N
Z w
13 cr
S
I o
'<t'
o
uJ z w
~
~ o cr
S
I o
15
N.
II I I I
I II I I[ I
6000001 \ {j ~ E I
" 9 ~ ~ iii u.Q 4000001 II 9 G I
, II !
200000 1 II h 1\ i !! !~\ I
j I~~~J L~L ___ JU~
II 1\ I ! III I
I, II II i I L __ -!II Ii I ! [ I
I, II 'I ! '
'I 'I II I I
Ilil. II~il I ,I ,,\ I Ii I
JLJ !~~~~~~ L '----.JLJ~ O'-r~ , I . , , , I ' , , ! I ' , , , I '
2.00 4.00 6.00 8.00 Time-->
~"'I
10.00 12.00
\ I Iii i ! i
14.00 16.00
, I' "I"" I '
18.00 20.00
REW357.D V006E15.M Fri May 19 13:35:50 2023 Page 2
REPORT ID: 23E135 Page 20 of 454
~bundance
I
Scan 181 (3.656 min): REW253.D (-)
6
96
Rem!
I ! i I
J I ,~,;", '~(','" "IIJ" I ,:~, I\\'! 'I" "i"" I ,1 !'\'" ,W', I"" I~" I"" I" 1i~, ,
~/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
Abundance Scan 181 (3.656 min): REW357.D
I '
Ra~
6
96
44
#12
l,l-Diehloroethene
Coneen: 1.42 ug/l
RT: 3.66 min Sean# 181
Delta R.T. 0.00 min
Lab File: REW357.D
Aeq: 19 May 2023 1:11 pm
Tgt Ion: 61 Resp: 334418
Ion Ratio Lower Upper
61 100
96 68.0 35.1 95.1
63 31. 9 1.6 61. 6
bundance Ion 61.00 (60.70 to 61.70): REW357.
Ion 96.00 (95.70 to 96.70): REW357.
Ion 63.00 (62.70 to 63.70): REW357.
161 175 60000 128
! O~~~~TI¥Wh~Th~~fthorrnn~ITTITIT~~n,'~'~lInl'~II~'IT'rrlln'I~II~II
/J1/z--> 30
~bundance
I
Sub I
50
6
96
O~tin~~~~~~rrn~~~~~~~~~~~~ITD~
Iz--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
IA.bundance Scan 281 (5.751 min): REW253.D (-)
i
r Remj
1 I
I Ii I II 83
! 0 1" I' '~YI' '~;I'~?' 1IIIIi"\:',, 1,1,1, 'I" ~~'" ~I1,1", F,~ ,11~?,1,19" 'I,W?I"
m/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160
fAbundance Scan 281 (5.752 min): REW357.D
63
Ra~1
I 44
J .3~ ,I J
["T1/Z-->
iA.bundance
, I
Sub I
50!
30 40 50
55 ,II J 71
83
JL 9~ 112 121
I I i I
60 70 80 90 100 110 120 130
Scan 281 (5.752 min): REW357.D (-)
6f
•
I
In/z-->
Oi" I'~~' I' '~';'I"" '1111" I'~~' I~I~", I" ~~" ";1~,:~,1,,, I"" I"" 1""1"
30 40 50 60 70 80 90 100 110 120 130 140 150 160
40000
20000
o~~~~~~~~
ime--> 3.40 3.60 3.80 4.00 4.20
#24
l,l-Diehloroethane
Coneen: 0.66 ug/l
RT: 5.75 min Sean# 281
Delta R.T. 0.00 min
Lab File: REW357.D
Aeq: 19 May 2023 1:11 pm
Tgt Ion: 63 Resp: 173613
Ion Ratio Lower Upper
63 100
65 30.5 1.4 61.4
83 15.2 0.0 43.0
~bundance Ion 63.00 (62.70 to 63.70): REW357.g
40000 Ion 65.00 (64.70 to 65.70): REW357.q
Ion 83.00 (82.70 to 83.70): REW357.Q
30000
200001
I
10000
5.75
~\
I \
I \ i \ Ji;~~
O~~~~~~~~~
Irime--> 5.40 5.60 5.80 6.00
REW357.D V006E15.M Fri May 19 13:35:51 2023 Page 3
REPORT ID: 23E135 Page 21 of 454
II\bundance
I I
Scan 368 (7.575 min): REW253.D (-) #30
00 Chloroform
, I
Rem
47
i
i 0 I
95105 118 128 155165 193
TTTTT""I''''I''''I'''','
mlz--> 30 70 80 90 100 110 120 130 140 150 1 60 170 180 190
Abundance Scan 369 (7.597 min): REW357D
8~
i , I
! i
Ra ~I, 1 ,~,~,'IJI' '~:;," " ,\~, , 1 ,1,1,11 ?,1, I' , ! 1 ~ ;,1?, " I' " 'I' . , 'I " , , I' , " I' , , . I' , , , 1 " , , 1 '
~/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190
rbundance Scan 369 (7.597 min): REW357D (-)
! I 8
Sub
50
47
Coneen: 1.01 ug/l
RT: 7.60 min Sean# 369
Delta R.T. 0.02 min
Lab File: REW357.D
Aeq: 19 May 2023 1:11 pm
Tgt Ion: 83 Resp: 261387
Ion Ratio Lower Upper
83 100
85 65.2 38.7 98.7
47 23.6 0.0 53.2
bundance Ion 83.00 (82.70 to 83.70): REW357.Q
Ion 85.00 (84.70 to 85.70): REW357.~
60000 Ion 47.00 (46.70 to 47.70): REW357.Q
50000 7.60
40000
REW357.D V006E15.M Fri May 19 13:35:52 2023 Page 4
REPORT ID: 23E135 Page 22 of 454
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E135
S-40-90-052023
23E135-04
REW358
Ext Btch ID: V006E16
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
l,l,2-Trichloroethane
1,1-Dichloroethane
l,l-Dichloroethene
l,l-Dichloropropene
l,2 t 3-Trichloropropane
1,2,4-Trichlorobenzene
l,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
l,2-Dichloroethane
1,2-Dichloropropane
l,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2 /2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Brornochlorornethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-l,2-Dichloroethene
cis-l,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-l,2-Dichloroethene
Trans-l,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1,2,3-Trichlorobenzene
1,4 -Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/17/23
Date Received: 05/18/23
Date Extracted: 05/19/23
Date Analyzed: 05/19/23
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ
11:50
13: 37
13: 37
DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
--------------------------------------------
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
0.63J 1.0 0.10
1.5 1.0 0.10
ND 1.0 0.10
ND 2.0 0.25
ND 1.0 0.15
ND 2.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 20 5.0
ND l.0 0.25
ND 20 5.0
ND l.0 0.25
ND 20 5.0
ND l.0 0.10
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.25
ND l.0 0.25
ND l.0 0.10
ND l.0 0.10
ND 2.0 0.50
l.0 l.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND l.0 0.10
ND l.0 0.10
ND l.0 0.10
ND l.0 0.25
ND l.0 0.10
ND l.0 0.10
ND 2.0 0.21
ND 10 2.5
ND 2.0 0.50
ND l.0 0.15
ND l.0 0.25
ND 1.0 0.25
ND l.0 0.10
ND l.0 0.25
ND l.0 0.25
ND l.0 0.25
ND l.0 0.25
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND l.0 0.11
ND l.0 0.10
ND 1.0 0.15
ND 100 25
RESULT SPK _AMT %RECOVERY
---------------------------------
9.63 10.0 96
10.4 10.0 104
10.5 10.0 105
10.1 10.0 101
Final Volume : 25ml
Analyzed by : LYamas
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.50
0.30
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.50
10
0.50
10
0.50
10
0.20
0.20
0.30
0.20
0.30
0.50
0.50
0.20
0.20
l.0
0.20
0.50
0.20
0.20
0.20
0.20
0.50
0.20
0.20
0.50
5.0
l.0
0.30
0.50
0.50
0.20
0.50
0.50
0.50
0.50
0.30
0.20
0.20
0.50
0.20
0.50
0.30
0.20
0.30
50
QC LIMIT
-----------
70-130
70-130
70-130
70-130
relative to sample result significant figures.
REPORT ID: 23E135 Page 23 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW358.D
Acq On 19 May 2023 1:37 pm
Sample 23E135-04
Misc 25mL
(QT Reviewed)
Vial: 18
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 14:01 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.09 114 4378503 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 15.54 117 3647970 10.00 ug/l 0.00
73) l,2-DICHLOROBENZENE-D4 19.42 152 1336969 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 1422226 10.06 ug/l 0.00
Spiked Amount 10.000 Recovery = 100.60%
41) l,2-Dichloroethane-d4 9.22 65 947278 9.63 ug/l .----G. 00
Spiked Amount 10.000 Recovery = 96.30% ...---. 54) Toluene-d8 12.92 98 4964514 10.48 ug/l 0.00
Spiked Amount 10.000 Recovery 104.80%
76) 4-Bromofluorobenzene 17.55 95 1570446 10.38 ug/K' 0.00
Spiked Amount 10.000 Recovery = 103.80%
Target Compounds Qvalue
12) l,l-Dichloroethene 3.66 61 364695 .~.51 ug/l 95
24) l,l-Dichloroethane 5.75 63 168773 /.63 ug/l 95
30) Chloroform 7.58 83 264996 1.00 ug/l 96
~ " "" 0""-
(#) = qualifier out of range (m) = manual integration
REW358.D V006E15.M Fri May 19 14:02:04 2023 Page 1
REPORT ID: 23E135 Page 24 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW358.D
Aeq On 19 May 2023 1:37 pm
Vial: 18
Operator: LYamas
Sample 23E135-04 Inst 06
Mise 25mL Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 14:01 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
f-bundance
I 4600000i
1
! 4400000j
i 4200000!
1
4000000!
I
38000001
3600000!
i
34000001
I
32000001
30000001
2800000j
I
26000001
2400000]
2200000j
1
20000001
i
1800000/
I
1600000j
j
14000001
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
(f)
~.
III
~ e g
TIC: REW358.D
(f)
~R
(RTE Integrator)
3' w z
~ w ro o
0:: o
...J
I o o
N.
'§
E e ~ I ~ i ~ ~ .n o ~. ~ II Iii
i ~ ~ li'il' /, 800000 :,: Q). II .c tL :;;; " i ~~. ~ II
12000001
10000001
: 9 ~ ~ ,I 600000j ij ~ Er I I'
4000001 I ~ 6 II I
20000°1 I~"l_~~ Jl_-, l JLI~
i Oll .---.-.-'~, <I~' ::;:, ~,-.', :;:1 ::::,;:::::;=, :::;:, ='~I :::;:,=;=, ::;::, ~'~I ~, ::::;,~:;:, ==1-'1 ::;::, :::;:, =;=, 'r, =;:I:=';=:' ~::::;:::=;=I ::::;,=;=, ::;::, !"~I :;:, ::::'=~, :::1;:::;::' ~~, ,;=, ::;:1 =;:::, :;::, =:=;:;:
fTime--> 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00
REW358.D V006E15.M Fri May 19 14:02:05 2023 Page 2
REPORT ID: 23E135 Page 25 of 454
~bundance
I I
ReOO
Scan 181 (3.656 min): REW253D (-)
61
96
#12
1,1-Dichloroethene
Concen: 1.51 ug/l
RT: 3.66 min Scan# 181
Delta R.T. 0.00 min
Lab File: REW358.D
Acq: 19 May 2023 1:37 pm
I 315 47 75 84 it 117 132 179 I O~~~Hrr~~~nTI~~~~~nn~ITrrnnTIT~nn~~nTn
rn/z--> 30
fA,bundance
40 50 60 70 80 90 1 00 110 120 130 140 150 160 170 180 190
Scan 181 (3.656 min): REW358.D
61
I I
i RaWoi
; I 44
I 35,,1 O!,.-L.I. "
im/z--> 30 40 50
Abundance
: I
96
I
1170 82 J 1105 121 133 184
6~
Scan 181 (3.656 min): REW358D H
I
96
Tgt Ion: 61 Resp: 36469
Ion Ratio Lower Upper
61 100
96 62.6 35.1 95.1
63 35.7 1.6 61. 6
Abundance Ion 61.00 (60.70 to 61.70): REW358.0
80000 Ion 96.00 (95.70 to 96.70): REW358.Q
Ion 63.00 (62.70 to 63.70): REW358.Q
60000 3.00 I
40000
I
i
i
I
I ~/z-->
~
I 20000 )11 \ :
_,_ 1 ! '7' 133 , of: , , ' .A, , " , c; I
90 100 110 120 130 140 150 160 170 180 190 Irime--> 3.40 3.60 3.80 4.00 4.2~
Abundance ~can 281 (5.751 min): REW253D (-)
ReOO
#24
1,1-Dichloroethane
Concen: 0.63 ug/l
5
RT: 5.75 min Scan# 281
Delta R.T. 0.00 min
Lab File: REW358.D
Acq: 19 May 2023 1:37 pm
I
I
m/z--> 30 40 50
fAbundance
, I
RaWoi
1
60 70 80 90 100 11 0 120 130
Scan 281 (5.752 min): REW358.D r ,
I
i ,
i 44 I '
I I Ii, 8,3 98
140 150 160
I 35, 55, I i 70 II , I 115 0', , I' ,1:'1'1,:'1"" I r. I', Ilk. , I' , , , , . , , , I '+t+j-M-. , , I ' , , . I ' , . , , ' . , , I' , , . I ' .
m/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160
fl bund ""', t~n 28' (5.752 min), REW358.D (-)
Sub' I 501
I
'm/z-->
I i I It 83 98
0 1, , I ,~~, , ,~~, I~'~' , liil,I, , I~~' , 1,1;1", I' , , 1'1' , , , I : ~,~ , , , , , I' , , , I' , , , ! ' , , , I' ,
30 40 50 60 70 80 90 1 00 11 0 120 130 140 150 160
Tgt Ion: 63 Resp: 168773
Ion Ratio Lower Upper
63 100
65 34.8 1.4 61.4
83 14.5 0.0 43.0
bundance Ion 63.00 (62.70 to 6370) REW35s~C
40000;lon 65.00 (64.70 to 65.70) REW358.C
lion 83.00 (82.70 to 83.70): REW358C
I
10000
5.75
II I \ ;\
/ '\ \ ,hL
30000
20000
ime--> 5.60 5.80 6.00
REW358.D V006E15.M Fri May 19 14:02:06 2023 Page 3
REPORT ID: 23E135 Page 26 of 454
Abund-an-c-e--------,S~c-a-n-=-36-=-c8~(=7~.5=75=--mc-inc-):-=R:-:::E:::-c-W25-3.-D-(-)--~---
I ~
Rem!
47
Ohn~~~~ffrtttn~~~rrrrrrnttnTIn~~~1rr5rr5rr1TI65~~~1m9~3~-
Iz--> 30
~bundance
! I
. Ra~1
I
37 0:. ,
~~-->_~30 40 50 60
Abundance
!
I
Sub
50
47
94 119
I' ; I 'I' II. i I ! i , '. i i r: iii i ! ' 'I Ii i I Iii! I '
70 80 90 100 11 0 120 130 140 150 160 170 180 190
5~t36B (7.575 m'o), REW35BD (-)
b~-> o 1""1""1''''1''''1''''1'
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190
#30
Chloroform
Concen: 1.00 ug/l
RT: 7.58 min Scan# 368
Delta R.T. 0.00 min
Lab File: REW358.D
Acq: 19 May 2023 1:37 pm
Tgt Ion: 83 Resp: 264996
Ion Ratio Lower Upper
83 100
85 65.6 38.7 98.7
47 25.8 0.0 53.2
bundance Ion 83.00 (82.70 to 83.70): REW358.q
Ion 85.00 (84.70 to 85.70): REW358.q
Ion 47.00 (46.70 to 47.70): REW358.u
60000 i
40000
20000
ime-->
t
7.58
\
r\\ I~ !C'\ I
'I bl~=:!" ,---;:1
7.40 7.60 7.80 i
REW358.D V006E15.M Fri May 19 14:02:07 2023 Page 4
REPORT ID: 23E135 Page 27 of 454
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E135
TB-20230517-26
23E135-05
REW354
Ext Btch ID: V006E16
Calib. Ref.: REW253
PARAMETER (S)
------------------------------
I/I ,l/2-Tetrachloroethane
l,l,I-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
l,l-Dichloropropene
1, 2, 3-Trichloropropane
1, 2, 4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1/2-Dichlorobenzene
1,2-Dichloroethane
l,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
l,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Brornodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-l,2-Dichloroethene
cis-l,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1, 2, 3-Trichlorobenzene
l,4-Dioxane
SURROGATE PARAMETER (5)
------------------------------
l,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/17/23 07:30
Date Received: 05/18/23
Date Extracted: 05/19/23 11:52
Date Analyzed: 05/19/23 11:52
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
--------------------------------------------
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.25
ND 1.0 0.15
ND 2.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.50
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.21
ND 10 2.5
ND 2.0 0.50
ND 1.0 0.15
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.11
ND 1.0 0.10
ND 1.0 0.15
ND 100 25
RESULT SPK AMT %RECOVERY
---------------------------------
9.61 10.0 96
10.3 10.0 103
10.5 10.0 105
10.1 10.0 101
Final Volume : 25ml
Analyzed by : LYamas
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.50
0.30
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.50
10
0.50
10
0.50
10
0.20
0.20
0.30
0.20
0.30
0.50
0.50
0.20
0.20
1.0
0.20
0.50
0.20
0.20
0.20
0.20
0.50
0.20
0.20
0.50
5.0
1.0
0.30
0.50
0.50
0.20
0.50
0.50
0.50
0.50
0.30
0.20
0.20
0.50
0.20
0.50
0.30
0.20
0.30
50
QC LIMIT
-----------
70-130
70-130
70-130
70-130
relative to sample result significant figures.
REPORT ID: 23E135 Page 28 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW354.D
Acq On 19 May 2023 11:52 am
Sample 23E135-05
Misc 25mL
Vial: 14
Operator: LYamas
Inst 06
~ Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 12:17 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.09 114 4475901 10.00 ug/l 0.00
53 ) CHLOROBENZENE-D5 15.54 117 3778943 10.00 ug/l 0.00
73) 1,2-DICHLOROBENZENE-D4 19.42 152 1388370 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 1454902 10.06 ug/l 0.00
Spiked Amount 10.000 Recovery = 100.60%
41) l,2-Dichloroethane-d4 9.22 65 966557 9.61 ug/l 0.00
Spiked Amount 10.000 Recovery = 96.'fO%
54) Toluene-d8 12.92 98 5128491 10.45 ug/l ./ 0.00
Spiked Amount 10.000 Recovery = 104.50%
76) 4-Bromofluorobenzene 17.55 95 1620296 10.31 ug/) 0.00
Spiked Amount 10.000 Recovery = 103.10%
Target Compounds Qvalue
17) Methylene chloride 4.39 49 25860 0.15 ug/l 95
(#) = qualifier out of range (m) = manual integration
REW354.D V006E15.M Fri May 19 12:17:19 2023 Page 1
REPORT ID: 23E135 Page 29 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW354.D
Aeq On 19 May 2023 11:52 am
Vial: 14
Operator: LYamas
Sample 23E135-05 Inst 06
Mise 25mL Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 12:17 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
iAbundance
48000001
4600000j
,
44000001
I 4200000~
I
40000001
38000001
36000001
3400000!
32000001
30000001
2800000i
26000001
I
i 2400000,
I
2200000i ,
I
20000001
I
18000001 ,
16000001
14000001
j
1200000j
10000001
8000001
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
(f) .,-
~
E e g
'5
E e n o
(f)
..£
1
'" 1,1 e o :c o
(5
N_
TIC: REW354.D
Ii
I
; I I
~-
z
W
N
Z
W rn o
(Y g
I o
c3 w z w
~ w rn o
(Y g
I o
i5
N_
600000j
400000; ~ II" !li,I,!, ,1111,:i I"';': ,,:',,! , £.,~ ,ill 1,;1,' "il,'"
I ;2 Ii II ! i I! II Ii II
200000j J\ II jiU l\ 1\ Il .1\ II II
0 1 ,j~, I' ,'" ~~"" I"" I" ,L, ,','\.., ~~ 1'L-JGLu\ L-'-'--'~"'-~-'---'--,-.-----''-r-r-,---,--,---,-,--,-,--;=;:=,-r-~ ,," I , I ' I , , I' I I ' I , , I , I I
Time--> ___ ----=-2.~0"'_0 __ -,-4.:.:::0",_0 __ ~6,-".0~0 __ ~8,-".0~0 __ -,-,1 0"-'-.0:::0'---_..:.:12::::..0""0'---_-'-14-.c.O:::O'--_"-'16::::..0::.:0"--_"-'18::::..0::.:0"--_=20::::..0=..:0,,-----
REW354.D V006E15.M Fri May 19 12:17:20 2023 Page 2
REPORT ID: 23E135 Page 30 of 454
rU~::1 S~r (4~9 m;,) REW~3D (-)
I 49 I 84
I I I I Ii
I 0 1
" I '~'~III 1,1 11 1, , "I ?,~' I " III ,111 1, ,~TI1P,~ I' ,1,W" ':I~1", I' ,1,1?, , "I' , ,1,W", I
mlz--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
iA,bundance Scan 216 (4.390 min): REW354.D
Iz-->
Abundance
. I
Sub I
414
I
84
113
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
Scan 216 (4.390 min): REW354.D (-)
67
I
84
#17
Methylene chloride
Concen: 0.15 ug/l
RT: 4.39 min Scan# 216
Delta R.T. 0.00 min
Lab File: REW354.D
Acq: 19 May 2023 11:52 am
Tgt Ion: 49 Resp: 25860
Ion Ratio Lower Upper
49 100
84 80.6 57.4 117.4
86 56.3 25.5 85.5
bundance Ion 49.00 (48.70 to 49.70): REW354.
Ion 84.00 (83.70 to 84.70): REW354.
Ion 86.00 (85.70 to 86.70): REW354.
5000
4.39
4000
3000
001
O~I~~~~~~~~~I~~~~~~~~~nT~~~~
rn{~-~_~-,3=-=0_4,-=0---=5=-=0---=6=-=0---,7_c:O---=8=-=0---=9c:=0.--,-1 0"-'0=----:.-11c...:O=---:c12=0'--'-13=-:0'--'-14-'-'0'---'-'15'--'0'---1-'--6c..c0_1c..c7--cO_--'-'-"imc:..ce.=...-_->_4'-'-.1-,--0,--,4=.2=0_4-".~30=-----4,-,-.4,-=0,----,-,4=.5~0--,-,~
REW354.D V006E15.M Fri May 19 12:17:21 2023 Page 3
REPORT ID: 23E135 Page 31 of 454
QC SUMMARIES
REPORT ID: 23E135 Page 32 of 454
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
Ext Btch ID:
Calib. Ref.:
PARAMETER(S)
BRICE
TEAD-S
23E135
MBLK1W
V006E16B
REW346
V006E16
REW253
------------------------------
l,l,l,2-Tetrachloroethane
1 /1,I-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
l,l-Dichloroethane
l,l-Dichloroethene
l,l-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
l,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
l,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Brornomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-l,2-Dichloroethene
cis-l,3-Dichloropropene
Dibrornochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-l,2-Dichloroethene
Trans-l,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
l,2-Dibromoethane
l,2,3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Brornofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/19/23 08:24
Date Received: 05/19/23
Date Extracted: 05/19/23 08:24
Date Analyzed: 05/19/23 08:24
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
--------------------------------------------
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.25
ND 1.0 0.15
ND 2.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.50
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.21
ND 10 2.5
ND 2.0 0.50
ND 1.0 0.15
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.11
ND 1.0 0.10
ND 1.0 0.15
ND 100 25
RESULT SPK_AMT %RECOVERY
----------- ----------------------
9.74 10.0 97
10.5 10.0 105
10.4 10.0 104
10.1 10.0 101
Final Volume : 25ml
Analyzed by : LYamas
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.50
0.30
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.50
10
0.50
10
0.50
10
0.20
0.20
0.30
0.20
0.30
0.50
0.50
0.20
0.20
1.0
0.20
0.50
0.20
0.20
0.20
0.20
0.50
0.20
0.20
0.50
5.0
1.0
0.30
0.50
0.50
0.20
0.50
0.50
0.50
0.50
0.30
0.20
0.20
0.50
0.20
0.50
0.30
0.20
0.30
50
QC LIMIT
-----------
70-130
70-130
70-130
70-130
relative to sample result significant figures.
REPORT ID: 23E135 Page 33 of 454
EMAX QUALITY CONTROL DATA
LAB CONTROL SAMPLE ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E135
METHOD SW5030B/8260C
=============== =========================~=======================================================================================
MATRIX WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID MBLK1W LCS1W LCD1W
LAB SAMPLE ID V006E16B V006E16L V006E16C
LAB FILE ID REW346 REW343 REW344
DATE PREPARED OS/19/23 08:24 OS/19/23 07:06 05/19/23 07:32
DATE ANALYZED OS/19/23 08:24 OS/19/23 07:06 05/19/23 07:32
PREP BATCH V006E16 V006E16 V006E16
CALIBRATION REF: REW2S3 REW253 REW253
ACCESSION:
MBResult SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%) (%) (%)
------------------------------------------------------------------------------------------------------
1,1,lt 2 - Tetrachloroethane ND 10.0 10.4 104 10.0 10.3 103 1 78-124 20
I,l, I-Trichloroethane ND 10.0 10.8 108 10.0 9.62 96 12 74-131 20
1, 1, 2,2-Tetrachloroethane ND 10.0 10.9 109 10.0 10.6 106 3 71-121 20
1,1,2-Trichloroethane ND 10.0 10.4 104 10.0 10.1 101 3 80-119 20
l,l-Dichloroethane ND 10.0 10.S lOS 10.0 10.3 103 2 77-125 20
1,1-Dichloroethene ND 10.0 10.5 105 10.0 10.3 103 2 71-131 20
1,1-Dichloropropene ND 10.0 10.2 102 10.0 10.0 100 2 79-125 20
l,2,3-Trichloropropane ND 10.0 9.92 99 10.0 9.85 99 1 73-122 20
l,2,4-Trichlorobenzene ND 10.0 10.0 100 10.0 10.0 100 0 69-130 20
1,2-Dibromo-3-chloropropane ND 10.0 9.43 94 10.0 8.95 90 5 62-128 20
1,2-Dichlorobenzene ND 10.0 10.7 107 10.0 10.5 lOS 2 80-119 20
1,2-Dichloroethane ND 10.0 10.0 100 10.0 9.92 99 1 73-128 20
l,2-Dichloropropane ND 10.0 10.8 108 10.0 10.5 105 3 78-122 20
l,3-Dichlorobenzene ND 10.0 10.5 105 10.0 10.6 106 1 80-119 20
1,3-Dichloropropane ND 10.0 10.9 109 10.0 10.6 106 3 80-119 20
1,4-Dichlorobenzene ND 10.0 10.6 106 10.0 10.6 106 0 79-118 20
2,2-Dichloropropane ND 10.0 11.1 111 10.0 10.8 108 3 60-139 20
2-Butanone (MEK) ND SO.O S1. 3 103 50.0 50.5 101 2 56-143 20
2-Chlorotoluene ND 10.0 10.6 106 10.0 10.6 106 0 79-122 20
2-Hexanone ND 50.0 50.8 102 50.0 50.6 101 0 57-139 20
4-Chlorotoluene ND 10.0 10.5 105 10.0 10.4 104 1 78-122 20
Acetone ND 50.0 48.9 98 SO.O 48.7 97 0 39-160 20
Benzene ND 10.0 10.5 lOS 10.0 10.4 104 1 79-120 20
Bromobenzene ND 10.0 10.4 104 10.0 10.2 102 2 80-120 20
Bromochloromethane ND 10.0 10.1 101 10.0 9.97 100 1 78-123 20
Bromodichloromethane ND 10.0 10.1 101 10.0 9.83 98 3 79-125 20
Bromoform ND 10.0 9.88 99 10.0 9.80 98 1 66-130 20
Bromomethane ND 10.0 9.76 98 10.0 9.88 99 1 53-141 20
Carbon Disulfide ND 10.0 8.58 86 10.0 9.74 97 13 64-133 20
Carbon Tetrachloride ND 10.0 10.7 107 10.0 10.3 103 4 72-136 20
Chlorobenzene ND 10.0 10.8 108 10.0 10.7 107 1 82-118 20
Chloroethane ND 10.0 9.54 9S 10.0 9.61 96 1 60-138 20
Chloroform ND 10.0 10.3 103 10.0 10.1 101 2 79-124 20
Chloromethane ND 10.0 10.1 101 10.0 10.2 102 1 50-139 20
cis-l,2-Dichloroethene ND 10.0 10.5 105 10.0 10.2 102 3 78-123 20
cis-l,3-Dichloropropene ND 10.0 10.5 105 10.0 10.3 103 2 75-124 20
Dibromochloromethane ND 10.0 10.2 102 10.0 10.1 101 1 74-126 20
Dibromomethane ND 10.0 10.1 101 10.0 9.74 97 4 79-123 20
Dichlorodifluoromethane ND 10.0 9.20 92 10.0 9.43 94 2 32-152 20
Ethylbenzene ND 10.0 10.7 107 10.0 10.6 106 1 79-121 20
Isopropylbenzene ND 10.0 10.6 106 10.0 10.6 106 0 72-131 20
m,p-Xylene ND 20.0 21. 9 110 20.0 21.6 108 1 80-121 20
4-Methyl-2-Pentanone ND 50.0 S2.1 104 50.0 51. 0 102 2 67-130 20
Methylene Chloride ND 10.0 10.4 104 10.0 10.3 103 1 74-124 20
Methyl tert-butyl ether (MTBE) ND 10.0 10.3 103 10.0 10.1 101 2 71-124 20
n-Butylbenzene ND 10.0 10.5 lOS 10.0 10.7 107 2 75-128 20
n-Propylbenzene ND 10.0 10.8 108 10.0 10.7 107 1 76-126 20
o-Xylene ND 10.0 10.6 106 10.0 10.6 106 0 78-122 20
p-Isopropyltoluene ND 10.0 10.4 104 10.0 10.5 105 1 77-127 20
Sec-Butylbenzene ND 10.0 10.7 107 10.0 10.5 105 2 77-126 20
Styrene ND 10.0 10.6 106 10.0 10.S 105 1 78-123 20
Tert-Butylbenzene ND 10.0 10.5 105 10.0 10.S 105 0 78-124 20
Tetrachloroethene ND 10.0 10.9 109 10.0 10.7 107 2 74-129 20
Toluene ND 10.0 11. 0 110 10.0 10.9 109 1 80-121 20
Trans-l,2-Dichloroethene ND 10.0 10.5 105 10.0 10.4 104 1 75-124 20
Trans-l!3-Dichloropropene ND 10.0 10.5 105 10.0 10.4 104 1 73-127 20
Trichloroethene ND 10.0 10.2 102 10.0 10.1 101 1 79-123 20
Trichlorofluoromethane ND 10.0 9.34 93 10.0 9.44 94 1 65-141 20
Vinyl Chloride ND 10.0 9.60 96 10.0 9.87 99 3 58-137 20
1,2-Dibromoethane ND 10.0 10.3 103 10.0 10.2 102 1 77-121 20
l,2,3-Trichlorobenzene ND 10.0 9.90 99 10.0 10.0 100 1 69-129 20
l,4-Dioxane ND 200 179 90 200 173 87 3 S9-139 20
SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCDRec QCLimit
SURROGATE PARAMETERS (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%)
---------------------------------------------------------------------------
1,2-Dichloroethane-d4 10.0 9.61 96 10.0 9.56 96 70-130
4-Bromofluorobenzene 10.0 9.97 100 10.0 10.2 102 70-130
Toluene-d8 10.0 10.4 104 10.0 10.4 104 70-130
Dibromofluoromethane 10.0 10.1 101 10.0 10.3 103 70-130
ME: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
REPORT ID: 23E135 Page 34 of 454
EMAX QUALITY CONTROL DATA
MS/MSD ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E135
METHOD SW5030B/8260C
=============== =================================================================================================================
MATRIX WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID S-150-20-052023 S-150-20-052023MS S-150-20-052023MSD
LAB SAMPLE ID 23E135-01 23E135-01M 23E135-01S
LAB FILE ID REW355 REW362 REW363
DATE PREPARED 05/19/23 12:18 05/19/23 15:21 05/19/23 15: 47
DATE ANALYZED 05/19/23 12:18 05/19/23 15:21 05/19/23 15:47
PREP BATCH V006E16 V006E16 V006E16
CALIBRATION REF: REW253 REW253 REW253
ACCESSION:
PSResult SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/L) (%) (Ug/L) (ug/L) (%) (%) (%) (%)
------------------------------------------------------------------------------------------------------
l,l,l,2-Tetrachloroethane ND 10.0 10.1 101 10.0 10.4 104 3 78-124 20
lil,I-Trichloroethane ND 10.0 9.31 93 10.0 9.59 96 3 74-131 20
1,1,2,2-Tetrachloroethane ND 10.0 10.6 106 10.0 10.8 108 2 71-121 20
l,I,2-Trichloroethane ND 10.0 10.0 100 10.0 10.3 103 3 80-119 20
1,1-Dichloroethane ND 10.0 10.4 104 10.0 10.8 108 4 77-125 20
1,1-Dichloroethene ND 10.0 10.1 101 10.0 10.4 104 3 71-131 20
1,1-Dichloropropene ND 10.0 9.84 98 10.0 10.2 102 4 79-125 20
1,2,3-Trichloropropane ND 10.0 9.52 95 10.0 9.92 99 4 73-122 20
1, 2, 4-Trichlorobenzene ND 10.0 9.52 95 10.0 9.92 99 4 69-130 20
1,2-Dibromo-3-chloropropane ND 10.0 9.06 91 10.0 9.45 95 4 62-128 20
l,2-Dichlorobenzene ND 10.0 10.3 103 10.0 10.4 104 1 80-119 20
l,2-Dichloroethane ND 10.0 10.1 101 10.0 10.6 106 5 73-128 20
1,2-Dichloropropane ND 10.0 10.6 106 10.0 11.0 110 4 78-122 20
l,3-Dichlorobenzene ND 10.0 10.1 101 10.0 10.3 103 2 80-119 20
1,3-Dichloropropane ND 10.0 10.6 106 10.0 10.9 109 3 80 -119 20
1,4-Dichlorobenzene ND 10.0 10.1 101 10.0 10.6 106 5 79-118 20
2,2-Dichloropropane ND 10.0 9.71 97 10.0 10.1 101 4 60-139 20
2 -Butanone (MEK) ND 50.0 49.5 99 50.0 51. 0 102 3 56-143 20
2-Chlorotoluene ND 10.0 9.45 95 10.0 10.4 104 10 79-122 20
2-Hexanone ND 50.0 49.2 98 50.0 50.6 101 3 57-139 20
4-Chlorotoluene ND 10.0 10.9 109 10.0 10.1 101 8 78-122 20
Acetone ND 50.0 43.4 87 50.0 44.4 89 2 39-160 20
Benzene ND 10.0 10.4 104 10.0 10.8 108 4 79-120 20
Bromobenzene ND 10.0 10.0 100 10.0 10.3 103 3 80-120 20
Bromochloromethane ND 10.0 9.95 100 10.0 10.5 105 5 78-123 20
Bromodichloromethane 0.219J 10.0 10.2 100 10.0 10.4 102 2 79-125 20
Bromoform ND 10.0 9.15 92 10.0 9.47 95 3 66-130 20
Bromomethane ND 10.0 11. 4 114 10.0 10.2 102 11 53-141 20
Carbon Disulfide ND 10.0 12.2 122 10.0 10.9 109 11 64-133 20
Carbon Tetrachloride ND 10.0 9.29 93 10.0 9.59 96 3 72-136 20
Chlorobenzene ND 10.0 10.5 105 10.0 10.7 107 2 82-118 20
Chloroethane ND 10.0 11.6 116 10.0 10.7 107 8 60-138 20
Chloroform 0.540J 10.0 10.7 102 10.0 11.2 107 5 79-124 20
Chloromethane ND 10.0 12.2 122 10.0 11.1 111 9 50-139 20
cis-l,2-Dichloroethene ND 10.0 10.5 105 10.0 10.7 107 2 78-123 20
cis-l,3-Dichloropropene ND 10.0 10.0 100 10.0 10.6 106 6 75-124 20
Dibromochloromethane 0.162J 10.0 10.1 99 10.0 10.6 104 5 74-126 20
Dibromomethane ND 10.0 10.1 101 10.0 10.7 107 6 79-123 20
Dichlorodifluoromethane ND 10.0 11. 8 118 10.0 10.7 107 10 32-152 20
Ethylbenzene ND 10.0 10.2 102 10.0 10.6 106 4 79-121 20
Isopropylbenzene ND 10.0 10.1 101 10.0 10.5 105 4 72-131 20
m,p-Xhlene ND 20.0 20.8 104 20.0 21.6 108 4 80-121 20
4-Met yl-2-Pentanone ND 50.0 50.6 101 50.0 53.3 107 5 67-130 20
Methylene Chloride ND 10.0 10.3 103 10.0 10.7 107 4 74-124 20
Methyl tert-butyl ether (MTBE) ND 10.0 10.1 101 10.0 10.7 107 6 71-124 20
n-Butylbenzene ND 10.0 9.94 99 10.0 10.3 103 4 75-128 20
n-Propylbenzene ND 10.0 10.1 101 10.0 10.3 103 2 76-126 20
o-Xylene ND 10.0 10.3 103 10.0 10.6 106 3 78-122 20
p-Isopropyltoluene ND 10.0 9.82 98 10.0 10.1 101 3 77-127 20
Sec-Butylbenzene ND 10.0 9.93 99 10.0 10.1 101 2 77-126 20
Styrene ND 10.0 8.54 85 10.0 9.10 91 6 78-123 20
Tert-Butylbenzene ND 10.0 10.0 100 10.0 10.1 101 1 78-124 20
Tetrachloroethene ND 10.0 10.1 101 10.0 10.5 105 4 74-129 20
Toluene ND 10.0 10.7 107 10.0 11. 0 110 3 80-121 20
Trans-l,2-Dichloroethene ND 10.0 10.3 103 10.0 10.7 107 4 75-124 20
Trans-l,3-Dichloropropene ND 10.0 9.81 98 10.0 10.4 104 6 73-127 20
Trichloroethene ND 10.0 9.85 99 10.0 10.2 102 3 79-123 20
Trichlorofluoromethane ND 10.0 10.9 109 10.0 9.75 98 11 65-141 20
Vinyl Chloride ND 10.0 10.5 105 10.0 9.63 96 9 58-137 20
1,2-Dibromoethane ND 10.0 10.0 100 10.0 10.6 106 6 77-121 20
1, 2, 3-Trichlorobenzene ND 10.0 9.61 96 10.0 10.3 103 7 69-129 20
1.4-Dioxane ND 200 181 91 200 198 99 9 59-139 20
SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec QCLimit
SURROGATE PARAMETERS (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%)
--------------------------------------------------------------------------
1,2-Dichloroethane-d4 10.0 10.1 101 10.0 10.2 102 70-130
4-Bromofluorobenzene 10.0 10.0 100 10.0 9.91 99 70-130
Toluene-d8 10.0 10.4 104 10.0 10.4 104 70-130
Dibromofluoromethane 10.0 10.3 103 10.0 10.4 104 70-130
PS: Parent Sample MS: Matrix Spike MSD: Matrix Spike Duplicate
REPORT ID: 23E135 Page 35 of 454
QC DATA
REPORT ID: 23E135 Page 36 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW346.D
Acq On 19 May 2023 8:24 am
Sample V006E16B
Misc 25mL
(QT Reviewed)
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 19 9:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration ~
V006E15
Internal Standards R.T. Qlon Response Conc units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.08 114 4723109 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 15.54 117 3991940 10.00 ug/l 0.00
73) 1,2-DICHLOROBENZENE-D4 19.42 152 1481012 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 1533196 10.05 ug/l 0.00
Spiked Amount 10.000 Recovery = 100.~
41) 1,2-Dichloroethane-d4 9.23 65 1032881 9.74 ug/l 0.01
Spiked Amount 10.000 Recovery = 97.40%
54) Toluene-d8 12.91 98 5371926 10.36 ug/~ 0.00
Spiked Amount 10.000 Recovery = 103.60%
76) 4-Bromofluorobenzene 17.55 95 1759397 10.49 uglY 0.00
Spiked Amount 10.000 Recovery = 104.9'0%
./
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REW346.D V006E15.M Fri May 19 09:54:13 2023 Page 1
REPORT ID: 23E135 Page 37 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW346.D
Aeq On 19 May 2023 8:24 am
Vial: 6
Operator: LYamas
Sample V006E16B Inst 06
Mise 25mL Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 19 9:07 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
~bundance
, 50000001
4800000j
I
46000001
I
44000001
!
4200000j
4000000 1
3800000
3600000
I
34000001
3200000
3000000
!
28000001
I
26000001
2400000
2200000
!
20000001
18000001
16000001
j
14000001
!
!
12000001
!
1
10000001
8000001
6000001
I
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
(RTE Integrator)
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW346.D
I'
II
Ii
11 ~
! I,
~ I
~
I o a:
9
I o o
N.
I I
I I I I
I , I
4000001
2000001
I L I lull I I
I rL lu ILJL\~JU ~-OLl~~,4J'~I~'~'~' ~'~~~'~~'~I~; ~,~,~,~;~, T'~'~'~I~'~'~'~'~I~'='~;~~'~! T'~'~'~'~I~'~~'~I='~~~' ~I~'~' ~'~'~I i
ITime--> 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 --------~=---~~----~=---~~----~=----===--~~~--~~--~==~~===-----~
REW346.D V006E15.M Fri May 19 09:54:14 2023 Page 2
REPORT ID: 23E135 Page 38 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW343.D
Acq On 19 May 2023 7:06 am
Sample V006E16L
Vial: 3
Operator: LYamas
lnst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 7:28 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
Last Update
Response via
DataAcq Meth V006E15 ,,-
Internal Standards
1) l,4-DlFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DlCHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.09 114
15.54 117
19.42 152
8.10 111
9.22 65
12.92 98
17.55 95
1. 71
1.95
2.05
2.52
2.60
2.64
2.90
3.40
3.47
3.49
3.66
3.82
4.20
4.10
4.39
4.39
4.64
4.70
4.91
5.61
5.84
5.77
6.55
6.82
7.07
7.20
7.60
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
4578750
3880881
1521733
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
1493913 10.10 ug/l 0.00
Recovery = 101.00%
987797 9 . 61 ug / 1 .~ 0 . 00
Recovery = 96.1~
5248371 10.41 ug/l 0.00
Recovery = 104.~0%
1716714 9.97 ug/l 0.00
Recovery = 99.70%
1684688
2055439
1894352
1585511
1136026
2825597
2193947
568965
1218320
841020
2651957
1282283
121939
2760187
1858687
5167251
1077128
2551371
1825312
4850453
1432017
2953693
4081084
1404176
1683757
1797994
2843794
/
9.20 ug/l
10.13 ug/l
9.60 ug/l
9.76 ug/l
9.54 ug/l
10.43 ug/l
9.34 ug/l
49.30 ug/l
9.59 ug/l
48.92 ug/l
10.51 ug/l
250.18 ug/l
9.86 ug/l
9.98 ug/l
10.37 ug/l
8.58 ug/l
51.85 ug/l
10.31 ug/l
10.52 ug/l
10.73 ug/l
10.24 ug/l
10.46 ug/l
10.91 ug/l
51. 28 ug/l
11.06 ug/l
10.50 ug/l
10.30 ug/l
Qvalue
98
99
99
99
98
98
99
99
100
97
98
100
96
99
94
100
100
100
100
99
100
100
97
96
99
100
99
(#) = qualifier out of range (m) = manual integration
REW343.D V006E15.M Fri May 19 09:54:24 2023 Page 1
REPORT ID: 23E135 Page 39 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW343.D
Acq On 19 May 2023 7:06 am
Sample V006E16L
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 7:28 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit Qvalue
32 ) Bromochloromethane 7.95 130 881931 10.08 ug/l 98
33) Tetrahydrofuran 8.08 42 147935 9.60 ug/l 97
35 ) 1,1, I-Trichloroethane 8.49 97 2481553 10.81 ug/l 93
36 ) Cyclohexane 8.48 84 2578044 10.77 ug/l 98
38) l,l-Dichloropropene 8.85 110 772803 10.22 ug/l 99
39) Carbon tetrachloride 9.02 119 1925167 10.67 ug/l 97
40) tert-Amyl methyl ether (TA 9.20 73 2927096 9.92 ug/l 99
42) l,2-Dichloroethane 9.42 62 1288747 10.03 ug/l 100
43) Benzene 9.40 78 6507692 10.49 ug/l 99
44) Trichloroethene 10.67 130 1687849 10.15 ug/l 98
45 ) Methylcyclohexane 10.75 83 2791204 10.87 ug/l 97
46 ) l,2-Dichloropropane 11.02 63 1561093 10.82 ug/l 96
47) l,4-Dioxane 11.57 88 111922~1 79.22 ug/l 94
48 ) Bromodichloromethane 11. 46 83 1949112 10.10 ug/l 99
49) Dibromomethane 11.54 93 752115 10.14 ug/l 98
50 ) 2-Chloroethyl vinyl ether 12.15 63 92694 7.47 ug/l 94
51) 4-Methyl-2-pentanone 12.21 43 3438559 52.06 ug/l 99
52 ) cis-1,3-Dichloropropene 12.51 75 2381992 10.47 ug/l 98
55 ) Toluene 13.06 91 6989036 11.03 ug/l 99
56) Ethyl methacrylate 13.49 69 1196801 10.61 ug/l 100
57) trans-1,3-Dichloropropene 13.43 75 1721067 10.48 ug/l 100
58 ) l,l,2-Trichloroethane 13.69 97 941115 10.35 ug/l 97
59 ) 2-Hexanone 13.77 43 2300743 50.81 ug/l 98
60 ) l,3-Dichloropropane 14.14 76 1774010 10.91 ug/l 99
61) Tetrachloroethene 14.19 164 1512040 10.89 ug/l 99
62) Dibromochloromethane 14.55 129 1175428 10.22 ug/l 99
64) l,2-Dibromoethane 14.88 107 916368 10.30 ug/l 98
65) 1-Chlorohexane 15.23 91 2932778 11. 04 ug/l 100
66 ) Chlorobenzene 15.60 112 4410809 10.82 ug/l 99
67 ) 1, 1, l,2-Tetrachloroethane 15.69 131 1482169 10.45 ug/l 100
68) Ethylbenzene 15.71 91 8165986 10.67 ug/l 98
69) m-Xylene & p-Xylene 15.84 91 12245132 21.92 ug/l 99
70 ) o-Xylene 16.56 91 6026016 10.57 ug/l 98
71) Styrene 16.64 104 4614526 10.64 ug/l 99
72) Isopropylbenzene 17.17 105 7711417 10.56 ug/l 99
74) Bromoform 17.17 173 551962 9.88 ug/l 98
75) l,l,2,2-Tetrachloroethane 17.46 83 1094209 10.90 ug/l 98
77 ) 1, 2, 3-Trichloropropane 17.67 110 255056 9.92 ug/l 100
78) trans-1,4-Dichloro-2-buten 17.77 53 249314 9.54 ug/l 97
79) n-Propylbenzene 17.77 91 9847291 10.81 ug/l 99
"
80) Bromobenzene 17.81 156 1638906 10.42 ug/l , 99
(#) = qualifier out of range (m) = manual integration
REW343.D V006E15.M Fri May 19 09:54:25 2023 Page 2
REPORT ID: 23E135 Page 40 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW343.D
Aeq On 19 May 2023 7:06 am
Sample V006E16L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 7:28 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) l,3,5-Trimethylbenzene 17.98 105 6208995 10.54 ug/l 99
82) 2-Chlorotoluene 17.99 91 6208550 10.58 ug/l 98
83) 4-Chlorotoluene 18.06 91 4857464 10.47 ug/l 97
84) tert-Butylbenzene 18.43 134 1488221 10.52 ug/l 100
85) l,2,4-Trimethylbenzene 18.47 105 5990470 10.29 ug/l 100
86) see-Butylbenzene 18.68 105 8720427 10.65 ug/l 100
87) p-Isopropyltoluene 18.83 119 6675176 10.44 ug/l 100
88) l,3-Diehlorobenzene 18.94 146 3136555 10.54 ug/l 99
89 ) 1, 2, 3-Trimethylbenzene 19.02 105 5481931 10.38 ug/l 99
90) l,4-Diehlorobenzene 19.06 146 3157411 10.59 ug/l 100
91 ) n-Butylbenzene 19.28 91 6369885 10.52 ug/l 100
92) l,2-Diehlorobenzene 19.46 146 2655866 10.71 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.22 157 151243 9.43 ug/l 95
94) It 2, 4-Triehlorobenzene 21.05 180 1633793 10.04 ug/l 100
95) Hexaehlorobutadiene 21.18 225 1041981 10.40 ug/l 99
96) Naphthalene 21.33 128 2362961 9.94 ug/l 100
97) l,2,3-Triehlorobenzene 21.57 180 1237769 9.90 ug/l 97
(#) = qualifier out of range (m) = manual integration
REW343.D V006E15.M Fri May 19 09:54:25 2023 Page 3
REPORT ID: 23E135 Page 41 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW343.D
Acq On 19 May 2023 7:06 am
Sample V006E16L
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Vial: 3
Operator: LYamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 19 7:28 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
~bundance
~ I ; 1.35e+071
I
1.3e+07{
I
125e+071
i 1.2e+07j
!
1.15e+071
I
1.1e+07j
1.05e+07j
1e+07
9500000
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW343.D
:::;: .,:
of co
'" ~ a.
«I
:::;: ....,
0
'"
~ .,:
of co
il p
~ ....,
",-
"
:::;:
...::
~ ,
1" I I!'
HI
~ I
)
:::;: ....,-
t
I I?
~ (I)
>-ON ~c c>lil.21
~e ~~ _0
:::;: ....,."
.,: "'+;" c:O') <If :j c:
~
§. a.
e '" .Q
~
0
E
~ I "'-. , !
W~
I , I I It
20.00
REW343.D V006E15.M Fri May 19 09:54:28 2023 Page 4
REPORT ID: 23E135 Page 42 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW344.D
Acq On 19 May 2023 7:32 am
Sample V006E16C
Vial: 4
Operator: LYamas
Inst 06
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 7:55 2023
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Quant Results File: V006E15.RES
(RTE Integrator)
~
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
8.10
9.22
12.92
17.55
1. 70
1. 93
2.05
2.53
2.60
2.64
2.90
3.40
3.47
3.51
3.66
3.82
4.20
4.10
4.39
4.39
4.64
4.70
4.91
5.61
5.84
5.77
6.55
6.82
7.07
7.20
7.60
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
4574420
3839325
1501839
10.00 ug/l
10.00 ug/l
10.00 ug/l
1523688 10.31
Recovery =
982242 9.56
Recovery =
5168371 10.37
Recovery =
1736412 10.21
Recovery =
ug/l
103.10%
ug/l
95(60%
ug/J:-
103.70%
ugtJ:
102.10%
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1725484
2070565
1946265
1603764
1143189
2773927
2214471
9.43 ug/l
10.22 ug/l
9.87 ug/l
9.88 ug/l
9.61 ug/l
Qvalue
97
99
97
98
97
581171
1203598
836378
2597452
1205833
113972
2725485
1842841
5861859
1093966
2497540
1794721
4795062
1467638
2904093
3956924
1382820
1636046
1740138
2785692
10.25 ug/l
9.44 ug/l
50.40 ug/l
9.49 ug/l
48.69 ug/l
10.30 ug/l
235.49 ug/l
9.22 ug/l
9.86 ug/l
10.29 ug/l
9.74 ug/l
52.71 ug/l
10.11 ug/l
10.36 ug/l
10.61 ug/l
10.50 ug/l
10.30 ug/l
10.59 ug/l
50.55 ug/l
10.76 ug/l
10.17 ug/l
10.10 ug/l
100
100
97
99
98
98
99
96
98
95
100
98
100
99
99
99
99
97
96
99
99
99
(#) = qualifier out of range (m) = manual integration
REW344.D V006E15.M Fri May 19 09:54:38 2023 Page 1
REPORT ID: 23E135 Page 43 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW344.D
Acq On 19 May 2023 7:32 am
Sample V006E16C
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 7:55 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,1,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95
8.08
8.49
8.48
8.85
9.02
9.20
9.42
9.40
10.67
10.75
11.03
11.58
11.46
11.54
12.15
12.20
12.51
13.06
13.49
13.44
13.69
13.77
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.67
17.77
17.77
17.81
130 872157
42 147769
97 2205579
84 2539582
110 757146
119 1864578
73 2883465
62 1273505
78 6419193
130 1673453
83 2699855
63 1520571
88 107823
83 1895035
93 721523
63 94593
43 3365045
75 2335280
91 6828164
69 1164582
75 1686256
97 910802
43 2267042
76 1703069
164 1464746
129 1153971
107 901577
91 2901838
112 4328129
131 1445824
91 8032210
91 11957805
91 5977475
104 4513532
105 7623242
173 540281
83 1051906
110 250057
53 244821
91 9639558
156 1579737
(#) = qualifier out of range (m) = manual integration
9.97 ug/l
9.60 ug/l
9.62 ug/l
10.62 ug/l
10.02 ug/l
10.34 ug/l
9.78 ug/l
9.92 ug/l
10.36 ug/l
10.07 ug/l
10.52 ug/l
10.54 ug/l
172.82 ug/l
9.83 ug/l
9.74 ug/l
7.63 ug/l
50.99 ug/l
10.27 ug/l
10.89 ug/l
10.43 ug/l
10.38 ug/l
10.13 ug/l
50.60 ug/l
10.59 ug/l
10.66 ug/l
10.14 ug/l
10.25 ug/l
11.04 ug/l
10.73 ug/l
10.30 ug/l
10.61 ug/l
21.64 ug/l
10.60 ug/l
10.52 ug/l
10.55 ug/l
9.80 ug/l
10.61 ug/l
9.-85 ug/l
9.50. ug/l
10.72 ug/l
10.17 ug/l
Qvalue
98
96
99
95
98
97
99
100
99
99
97
96
92
100
99
98
99
99
100
100
97
99
98
99
99
99
99
99
100
99
98
99
98
99
99
98
98
99
94
100
99
REW344.D V006E15.M Fri May 19 09:54:39 2023 Page 2
REPORT ID: 23E135 Page 44 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW344.D
Aeq On 19 May 2023 7:32 am
Sample V006E16C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 7:55 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81 ) 1, 3, 5-Trimethylbenzene 17.98 105 6072335 10.44 ug/l 100
82) 2-Chlorotoluene 17.99 91 , 6149280 10.62 ug/l 98
83) 4-Chlorotoluene 18.06 91 4781971 10.45 ug/l 98
84) tert-Butylbenzene 18.43 134 1465078 10.50 ug/l 99
85) l,2,4-Trimethylbenzene 18.47 105 5898771 10.27 ug/l 99
86) see-Butylbenzene 18.68 105 8515188 10.54 ug/l 100
87) p-Isopropyltoluene 18.84 119 6617868 10.49 ug/l 100
88) l,3-Diehlorobenzene 18.94 146 3101088 10.56 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.02 105 5368823 10.30 ug/l 99
90) l,4-Diehlorobenzene 19.06 146 3115082 10.58 ug/l 99
91) n-Butylbenzene 19.28 91 6392180 10.70 ug/l 99
92) l,2-Diehlorobenzene 19.45 146 2573920 10.51 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.22 157 141595 8.95 ug/l 96
94) l,2,4-Triehlorobenzene 21.05 180 1609002 10.02 ug/l 100
95) Hexaehlorobutadiene 21.18 225 1018940 10.30 ug/l 98
96) Naphthalene 21.33 128 2316090 9.87 ug/l 100
97) l,2,3-Triehlorobenzene 21.57 180 1239547 10.04 ug/l 100
(#) = qualifier out of range (m) = manual integration
REW344.D V006E15.M Fri May 19 09:54:39 2023 Page 3
REPORT ID: 23E135 Page 45 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW344.D
Acq On 19 May 2023 7:32 am
Sample V006E16C
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Vial: 4
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 7:55 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
. Response via
Abundance
1.3e+07j
1.25e+07
1.2e+07,
I 1.15e+07i
I
1.1e+071
1.05e+071
I
1e+071
I
9500000j
!
90000001
85000001
80000001
75000001
1
70000001
65000001
60000001
!
5500000 1
5000000
!
4500000j
4000000j
35000001
3000000
2500000
Time-->
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW344.D
~
~ u
~
1i
II
:;;; ill
1-' :ill-' <Jil-lil c: ., (0-:
~ i
.<:: e
0 :c
'Y
0 , :EI
U
::E r:
~
I
I
::E >-: .,
c:
'" 'So
~
IL .,-
c:
~
REW344.D V006E15.M Fri May 19 09:54:42 2023 Page 4
REPORT ID: 23E135 Page 46 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW362.D
Acq On 19 May 2023 3:21 pm
Sample 23E135-01M
Misc 25mL
(QT Reviewed)
Vial: 22
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 15:43 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.09 114 4297046 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 15.54 117 3690536 10.00 ug/l 0.00
73) l,2-DICHLOROBENZENE-D4 19.42 152 1475135 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 1433369 10.33 ug/l 0.00
Spiked Amount 10.000 Recovery = 103.30%
41 ) l,2-Dichloroethane-d4 9.22 65 975666 10.11 ug/l 0.00
Spiked Amount 10.000 Recovery = 101 (10%
54) Toluene-d8 12.92 98 4971822 10.37 ug/l~ 0.00
Spiked Amount 10.000 Recovery = 103.70%
76 ) 4-Bromofluorobenzene 17.55 95 1673530 10.02 uglY 0.00
Spiked Amount 10.000 Recovery = 100.20%
-""
Target Compounds Qvalue
2) Dichlorodifluoromethane 1. 69 85 2027675 11.80 ug/l 98
3) Chloromethane 1. 93 50 2319898 12.19 ug/l 100
4) Vinyl chloride 2.05 62 1952639 /10.54 ug/l 99
5) Bromomethane 2.52 94 1734396 11. 37 ug/l 99
6) Chloroethane 2.60 64 1301762 11.65 ug/l 98
7) Dichlorofluoromethane 2.64 67 2638652 10.38 ug/l 100
8) Trichlorofluoromethane 2.87 101 2404336 10.91 ug/l 100
9) Acrolein 3.40 56 476281 43.97 ug/l 96
10) l,l,2-Trichloro-1,2,2-trif 3.47 151 1113494 9.34 ug/l 99
11) Acetone 3.49 43 705308 43.43 ug/l 95
12) 1,1-Dichloroethene 3.66 61 2384087 10.06 ug/l 99
13) tert-Butyl alcohol 3.80 59 1139203 236.84 ug/l 99
15 ) Methyl acetate 4.18 74 111251 9.58 ug/l 94
16 ) Iodomethane 4.10 142 2541583 9.79 ug/l 100
17) Methylene chloride 4.39 49 1726243 10.26 ug/l 95
18) Carbon disulfide 4.37 76 6917716 12.24 ug/l 100
19 ) Acrylonitrile 4.64 53 1018534 52.25 ug/l 100
20) tert-Butyl methyl ether (M 4.68 73 2355983 10.15 ug/l 99
21 ) trans-1,2-Dichloroethene 4.89 96 1683282 10.34 ug/l 100
22 ) Isopropyl ether (DIPE) 5.61 45 4498656 10.60 ug/l 99
23) Vinyl acetate 5.84 43 1427995 10.88 ug/l 100
24) 1,1-Dichloroethane 5.75 63 2762456 10.43 ug/l 99
26) tert-Butyl ethyl ether (ET 6.53 59 3497734 9.96 ug/l 99
27) 2-Butanone 6.82 43 1271388 49.47 ug/l 98
28) 2,2-Dichloropropane 7.07 77 1386971 9.71 ug/l 99
29) cis-1,2-Dichloroethene 7.20 96 1685500 10.49 ug/l 99
30) Chloroform 7.58 83 2784221 10.74 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW362.D V006E15.M Fri May 19 15:46:26 2023 Page 1
REPORT ID: 23E135 Page 47 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW362.D
Acq On 19 May 2023 3:21 pm
Sample 23E135-01M
Misc 25mL
(QT Reviewed)
Vial: 22
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 15:43 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit Qvalue
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95
8.08
8.49
8.48
8.84
9.02
9.19
9.41
9.40
10.66
10.75
11.02
11.57
11.46
11.54
12.20
12.20
12.51
13.06
13.49
13.43
13.69
13.77
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.65
17.77
17.76
17.81
130 817267
42 138454
97 2004972
84 2653964
110 698235
119 1572414
73 2703682
62 1212969
78 6067663
130 1536296
83 2683899
63 1437593
88 105970
83 1846249
93 704316
63 3258
43 3139347
75 2140957
91 6430445
69 1065609
75 1531481
97 866784
43 2117456
76 1630961
164 1338540
129 1103443
107 848876
91 2578273
112 4060826
131 1363105
91 7443677
91 11066132
91 5563082
104 3521489
105 7037291
173 495797
83 1027826
110 237391
53 218495
91 8957589
156 1526012
(#.) = qualifier out of range (m) = manual integration
REW362.D V006E15.M Fri May 19 15:46:27 2023
9.95 ug/l
9.58 ug/l
9.31 ug/l
11.82 ug/l
9.84 ug/l
9.29 ug/l
9.77 ug/l
10.06 ug/l
10.42 ug/l
9.85 ug/l
11.14 ug/l
10.61 ug/l
180.81 ug/l
10.20 ug/l
10.12 ug/l
0.28 ug/l #
50.64 ug/l
10.02 ug/l
10.67 ug/l
9.93 ug/l
9.81 ug/l
10.03 ug/l
49.17 ug/l
10.55 ug/l
10.13 ug/l
10.09 ug/l
10.04 ug/l
10.20 ug/l
10.48 ug/l
10.11 ug/l
10.23 ug/l
20.83 ug/l
10.26 ug/l
8.54 ug/l
10.13 ug/l
9.15 ug/l
10.56 ug/l
9.52 ug/l
8.63 ug/l
10.15 ug/l
10.00 ug/l
Page 2
100
98
98
94
99
99
99
99
99
99
96
97
95
99
97
1
99
99
99
99
100
96
100
99
99
99
98
99
100
100
98
99
98
99
99
99
96
99
95
99
100
REPORT ID: 23E135 Page 48 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW362.D
Aeq On 19 May 2023 3:21 pm
Sample 23E135-01M
Mise 25mL
(QT Reviewed)
Vial: 22
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 15:43 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) l,3,5-Trimethylbenzene 17.98 105 5570526 9.75 ug/l 100
82 ) 2-Chlorotoluene 17.99 91 5373222 9.45 ug/l 93
83) 4-Chlorotoluene 18.06 91 4882987 10.86 ug/l 96
84) tert-Butylbenzene 18.43 134 1376452 10.04 ug/l 98
85) l,2,4-Trimethylbenzene 18.47 105 5086596 9.02 ug/l 99
86) see-Butylbenzene 18.68 105 7880837 9.93 ug/l 100
87) p-Isopropyltoluene 18.84 119 6083349 9.82 ug/l 99
88) l,3-Diehlorobenzene 18.94 146 2905714 10.08 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.02 105 5004417 9.77 ug/l 100
90 ) l,4-Diehlorobenzene 19.06 146 2908104 10.06 ug/l 100
91) n-Butylbenzene 19.28 91 5833909 9.94 ug/l 99
92) l,2-Diehlorobenzene 19.45 146 2471202 10.28 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.22 157 140894 9.06 ug/l 94
94) l,2,4-Triehlorobenzene 21.05 180 1501767 9.52 ug/l 99
95) Hexaehlorobutadiene 21.18 225 958301 9.87 ug/l 99
96) Naphthalene 21.33 128 2186270 9.49 ug/l 99
97 ) 1, 2, 3-Triehlorobenzene 21.57 180 1165797 9.61 ug/l 100
(#) = qualifier out of range (m) = manual integration
REW362.D V006E15.M Fri May 19 15:46:27 2023 Page 3
REPORT ID: 23E135 Page 49 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW362.D
Aeq On 19 May 2023 3:21 pm
Sample 23E13S-01M
Mise 2SmL
Vial: 22
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 15:43 2023 Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Abu-ndance
! 1.25e+07j
;
1.2e+07i
I 1.15e+071
!
1.1e+07i
I 1.05e+07i
1
1e+07j
95000001
1
9000000j
85000001
I
8000000j
7500000j
!
70000001
i
65000001 ;
1
6000000j
55000001
I
5000000j
,,5000001
4000000j
1
35000001
3000000j
I
2500000
2000000
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW362.D
Time~--~>~~_~~2~.~00~~~4.~00~~~6.~0~0~~~8~.0~0~~1~0~.0~O~ 12.00 14.00
REW362.D V006E15.M Fri May 19 15:46:29 2023
~
I I
16.00
I,'
I
I
I ~
II
I "
, I
18.00
:;;:
r:
of a e
Q. e o :c
" '" 6
E e
.0
(5
N.
a. ro
, II'
I I
J_I L
ill 1~
20.00
Page 4
REPORT ID: 23E135 Page 50 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW363.D Vial: 23
Operator: LYamas Acq On 19 May 2023 3:47 pm
Sample 23E135-01S
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 19 16:09 2023
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023 Last Update
Response via
DataAcq Meth
Initial Calibration ~
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.09
15.54
19.42
8.10
9.22
12.92
17.55
1. 69
1. 93
2.05
2.52
2.60
2.64
2.90
3.40
3.47
3.49
3.66
3.80
4.18
4.10
4.39
4.39
4.64
4.68
4.89
5.60
5.84
5.75
6.53
6.82
7.07
7.20
7.58
114 4234988
117 3667173
152 1484406
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
111
65
98
95
85
59
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
1423962 10.41 ug/l 0.00
Recovery ==
966175 10.16 ~~'? 0.00
Recovery == 101. 60%
4959167 10.41
Recovery
1664448 9.91
ug/I-
104.10%
ugn
0.00
0.00
Recovery == 99.10%
1809808
2082391
1757953
1536458
1173186
2730109
2117520
465970
1117374
709465
2430616
1244587
108476
2561519
1777190
6055372
1051235
2457738
1715322
4667860
1296157
2819497
3878162
1291381
1426205
1699860
2851351
10.69 ug/l
11.10 ug/l
9.63 ug/l
10.22 ug/l
10.65 ug/l
10.89 ug/l
9.75 ug/l
43.65 ug/l
9.51 ug/l
44.38 ug/l
10.41 ug/l
262.54 ug/l
9.48 ug/l
10.01 ug/l
10.72 ug/l
10.87 ug/l
54.72 ug/l
10.74 ug/l
10.69 ug/l
11.16 ug/l
10.02 ug/l
10.80 ug/l
11.21 ug/l
50.99 ug/l
10.13 ug/l
10.73 ug/l
11.16 ug/l
Qvalue
97
100
98
99
100
100
100
96
96
97
98
100
96
99
95
100
98
99
100
99
100
100
96
97
99
100
99
(#) = qualifier out of range (m) = manual integration
REW363.D V006E15.M Fri May 19 16:13:05 2023 Page 1
REPORT ID: 23E135 Page 51 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW363.D
Acq On 19 May 2023 3:47 pm
Sample 23E135-01S
Misc 25mL
(QT Reviewed)
Vial: 23
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 16:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-l,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95
8.08
8.49
8.48
8.85
9.01
9.19
9.41
9.40
10.66
10.75
11.02
11.57
11.46
11.54
12.18
12.20
12.51
13.06
13.49
13.43
13.68
13.77
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.67
17.77
17.77
17.81
130 850701
42 147986
97 2035054
84 2457010
110 716662
119 1600862
73 2764849
62 1257944
78 6180787
130 1572908
83 2569440
63 1463952
88 114447
83 1861142
93 730479
63 2352
43 3257329
75 2229964
91 6576352
69 1130848
75 1612690
97 884836
43 2164634
76 1677548
164 1380347
129 1149290
107 886522
91 2645382
112 4137964
131 1387363
91 7676546
91 11385627
91 5698787
104 3730070
105 7242014
173 516108
83 1054440
110 248960
53 230649
91 9160270
156 1574193
(#) -qualifier out of range (m) = manual integration
REW363.D V006E15.M Fri May 19 16:13:06 2023
10.51 ug/l
10.39 ug/l
9.59 ug/l
11.10 ug/l
10.25 ug/l
9.59 ug/l
10.13 ug/l
10.59 ug/l
10.77 ug/l
10.23 ug/l
10.82 ug/l
10.97 ug/l
/98.13 ug/l
.. 10.43 ug/l
10.65 ug/l
0.20 ug/l #
53.32 ug/l
10.59 ug/l
10.98 ug/l
10.61 ug/l
10.39 ug/l
10.30 ug/l
50.59 ug/l
10.92 ug/l
10.52 ug/l
10.58 ug/l
10.55 ug/l
10.53 ug/l
10.74 ug/l
10.35 ug/l
10.62 ug/l
21.57 ug/l
10.58 ug/l
9.10 ug/l
10.50 ug/l
9.47 ug/l
10.77 ug/l
9.92 ug/l
9.05 ug/l
10.31 ug/l
10.26 ug/l
Page 2
99
95
96
96
99
97
99
100
100
98
96
97
98
98
97
36
98
99
99
98
98
96
100
98
100
99
99
99
100
98
98
99
98
99
100
100
98
95
94
100
99
REPORT ID: 23E135 Page 52 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW363.D
Aeq On 19 May 2023 3:47 pm
Sample 23E135-01S
Mise 25mL
(QT Reviewed)
Vial: 23
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 16:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) 1, 3, 5-Trimethylbenzene 17.98 105 5785623 10.07 ug/l 100
82) 2-Chlorotoluene 17.99 91 5957185 10.41 ug/l 98
83) 4-Chlorotoluene 18.06 91 4589444 10.14 ug/l 98
84) tert-Butylbenzene 18.43 134 1399362 10.14 ug/l 99
85) l,2,4-Trimethylbenzene 18.47 105 5366546 9.45 ug/l 100
86) see-Butylbenzene 18.68 105 8073683 10.11 ug/l 100
87) p-Isopropyltoluene 18.83 119 6310238 10.12 ug/l 99
88) l,3-Diehlorobenzene 18.94 146 2997676 10.33 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.02 105 5206906 10.10 ug/l 99
90 ) l,4-Diehlorobenzene 19.06 146 3073744 10.56 ug/l 100
91) n-Butylbenzene 19.28 91 6079369 10.29 ug/l 99
92) l,2-Diehlorobenzene 19.44 146 2520354 10.42 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.22 157 147864 9.45 ug/l 96
94) 1, 2, 4-Triehlorobenzene 21.05 180 1575349 9.92 ug/l 100
95) Hexaehlorobutadiene 21.18 225 1004989 10.28 ug/l 99
96) Naphthalene 21.33 128 2362247 10.19 ug/l 100
97) 1, 2, 3-Triehlorobenzene 21.57 180 1256102 10.29 ug/l 100
(#) ~ qualifier out of range (m) = manual integration
REW363.D V006E15.M Fri May 19 16:13:06 2023 Page 3
REPORT ID: 23E135 Page 53 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW363.D
Aeq On 19 May 2023 3:47 pm
Sample 23E135-01S
Mise 25mL
Vial: 23
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 16:09 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
I
1.25e+071
I 1.2e+07]
I
, 115e+07j
I
1.1e+071
, I
105e+071
I
1e+071 I ;
9500000j
90000001
I
85000001
8000000!
7500000j
I 7000000:
I
6500000 ~
1 6000000
5500000
1
5000000 1
!
4500000 1
j
4000000 J
j
3500000 I
I
3000000 I
I
2500000 j
2000000
I 1500000 i ,
1000000 ,
500000 I
!
i
0 I
Time--> 2.00
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW363.D
(RTE Integrator)
4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00
REW363.D V006E15.M Fri May 19 16:13:08 2023 Page 4
REPORT ID: 23E135 Page 54 of 454
INITIAL CALIBRATIONS
REPORT ID: 23E135 Page 55 of 454
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : [MAX Laboratories. Inc.
Lab Code : [MAX
Lab File 10: REW247
Instrument 10: 06
Project : ICAL
SDG No : ICAL
BFB Injection Date: 05/15/23
BFB Injection Time: 13:21
I I % RELATIVE I
I mle I ION ABUNDANCE CRITERIA ABUNDANCE I
I I I
I 50 I 15 -40% of mass 95 16.093 I
I 75 I 30 -60% of mass 95 I 42.626 I
I 95 I Base Peak. 100% relative abundance _____ 1 100.000 I
I 96 I 5 -9% of mass 95 I 6.843 I
I 173 I Less than 2% of mass 174 I 0.000(0)1 I
I 174 I Greater than 50% of mass 95 I 72.842 I
I 175 I 5 -9% of mass 174 I 5.667(7.7B)1 I
I 176 I 95 -101% % of mass 174 I 72.635(99.72)1 I
I 177 I 5 -9% % of mass 176 I 4.251(5.B5)2 I
I_I I I
I-Value is % mass 174 2-Value is % mass 176
This check applies to the following Calibration Standards:
I EPA I LAB I LAB I DATE I TIME
I SAMPLE NO. I SAMPLE 10 I FILE 10 I ANALYZED I ANALYZED
1=====1====1===1 1===
1IVSTDO.3 IV006E151 1REW248 I 05/15123 I 13:47
2IVSTDO.5 IV006E152 1REW249 I 05/15/23 I 14:13
31VSTD1 IV006E153 1REW250 I 05115/23 I 14:39
41 VSTD2 I V006E154 I REW251 I 05115/23 I 15: 05
51VSTD5 IV006E155 1REW252 I 05/15/23 I 15:31
61VSTDI0 IV006E156 1REW253 I 05/15/23 I 15:57
71VSTD20 IV006E157 1REW254 I 05/15123 I 16:23
BIVSTD30 IV006E158 1REW255 I 05/15/23 I 16:49
91 VSTD50 I V006E159 I REW256 I 05/15/23 I 17: 15
10lVSTD100 IV006E1510 1REW257 I 05/15123 I 17:41
I I I I 1 __ _
REPORT ID: 23E135 Page 56 of 454
Instrument 10 :06 Beginning DateTime :05/15/23 13:47 SDlke Unlts :PPB Ie File :REW253
Column Spec : RTX~2. 2 10 : O. 25MM Ending DateTime . 5/15/23 17:41 HPChem Method:V 6E15
13:4Z 14·i3 14:3~ 15'0§ 15:3I 1d¥ 16:23 16J~ 17j~ 171~! M lOX Parameters REW248 REW2~ REW250 REWi51 REW252 REW253 REW~ REW255 REW256 REW257 Av_RRF %_RSD Av_Rt_M
1 1.4-DIFLUOROBENZENE 1 1 1 1 1 1 1 1 1 1 1 0 lo.0~i ~ Dl~hlorodifluoromethane ...... 8.361 8.394 8.402 8.448 0.390 0.384 g.416 ~.3~ 8.442 0.400 7.72 1.6
4 Ch oromefhane 8.384 .396 .406 .451 .415 0.451 R·446 .472 .41 .512 8.443 9.53 1.1
5 ~~~~~hg~de 8:~ 8:~S~ °8:~; 8:3gI 08:3, iO:3~§ 0:3~~ 1:3~~ :~31 0:
4
11
2
9 0:~~1 ,9:1§ ~:g R ~ Chlorlroet®ne .252 8.218 .263 .255 .2 7 .261 0.~60 .273 0.242 0.2 1.26 .16 2.5 g
g
Dich orofluoromethane 0.532 .567 0.571 8.637 8.651 .53~~. 02 .613 8·5~ 8. .59 '1 2. 1
5
TriChllQrofluoromethane 0.484 0.510 0.514 .530 .552 .49 . 83 .~29.4 .5 .~13 6.2 2. 7 Acro em. ...... ...... 8.023 0.028 8.027 .02 .026 . 26 ~.o 4 0.06 . 25 8. ~. 5 11 l,l
t
2.Trlchloro.1,2,2.trifluoroethane 0.313 0.281 .274 0.2~6 .2~ .240 .267 . 79 .24~ 0.~7 . 77 7. .
25 1
132 f~i.8~~hloroethehone . 0:495 '0:509 R:gjr 8:g7~ R:g 91 8:gij~ 8:g~ :g~ :g~7 8:&3f 8:IO~~ 1b1 :8 ~a tert.B~tyl alco 1 .•.••••..•.. 0.009 0.011 0.011 .010 0.012 .012 0.011 0.013 . 11 11'~~ ~. 10 1~ ~~~~~l~~!i~te :::::: :::::: 'g:o~i 'g:~' 'g:"6 'ii:02~ ":~25 ":~26 '0:02~ '8':'30 8: ~9 1: ~:18 11~ c~g~~~d~~~hlfQdride .?:~~ .?:~~~ 0:42
537j 0:448 o:raQ RJ10 8:39~ LM RJ~5 o:iIl 8}~ :47 1:19
5 ~6 ~~YlgBnii~~~elh~l ( '0:039 '0:042 O:~~~ 81:1111 ~1:~~ 3:~~ ~:ij~o 18:~~ 81:~~ 81:3~~ 81:~~i5 1~:il7 1: 8 ert· utyl metL'J ether MTBE) 8.4M 0.514 0.484 .5 0 .578 0'H7 0.571 .580 .~34 .623. 9. 4. ~9 ~~ Irans'l'~'Dichloroethene .3 0.363 0.368 .4 5 .401 8. 3 0.37g 0.391 8. 54 .422 O. 7 6. 4. 5 2~ V
sopropy ether (DIPE) 0.9 1 0.911 0.966 1.0 .04
9
, 91 1.00 1.017 . 25 1.082 8.9 6. 3 5. 9 inyl.acetate ............ 0.288 8.290 8.30 0.95 0.30 0.314 0.296 8.346 .305 6.~ 5.~1
25
5
~~ ~~~~~i~t~r::~~;":ther (ElBE) .~:j~~ 'I?:~~~ '08-:j~~ ·o:~~~ '8':~~9 .~:~~ .~:~ .~:~~ .~:~~~ ·0:~8~.? l:g~9 9:&g ~:~g~
. Butanone 8.060 .o~g .Q~ 0.060 .ggf 0.g52 0.063 8·g~1 o.~aa 0.06 .Q~Q 7.25 U31~ ~ E~t~:~~~~~~~~~~~ene 8:~~~ :1 8:m 8:!U g:~~ h~ 8:~~1 8:~~ h~& g:!tS :~ ~:~~ P~~7
5 ~~ '~~~~~rg~~~~e '0:i92 '0:iS5 '0:i77 'Q:2ii~ 'g:i97 '0:i7i 'g:i94 'ii:i~6 'O:i~'i 'g:2i3 ~:~~~ g:92 9:~ij~~1
34 Df6~~~~6~~~thane 'Oji3 '0:29i 'Oji5 0:~8 oj~~ 8j~~ d~ij 8:mO § 8°j ~ 8j1~ d23 1H§ ~: ~ ~56 l,111.Trichloroethane 0.515 0.483 0.489 0.508 0.549 0.424 8.463 0.5 .4 8 .5691.501 8.581' 27 Cye Qhexqne ...... 0.449 0.499 0.555 0.641 0.470 .494 O. 9 0.526 ...... .~23 11.51 .4742 ~~ ~~~~~~~!~~~yg;~~:ne 'g~!~9 '~'~i~~ 'Q~m'" 'g~i~ 'Q~it1 .~~~ '80~mi67 'g~i~12 .~.~!~~ 'I'~i~§ :~~~ ~:~~ :R2~~
40 tert·Amvl meth~l ether (TAME) ~.652 .593 0.5 8.676 0.681 8.586. 0.66 .618 .722 .644 7.31 j002 421 11,2.Dichlloroet ane·d4 .207 .201 0.2 7 .2~5 0.242 .211 8. 28 0.21 .217 .264 .225 8.16 .2158 43 .2-D1Ch oroet ane .267 0.269 0.262 0.2 6 0.~9 0.25 .217 0.29 0.267 .317 .281 6.90 .4144 4 Benzene .378 1.i28 1.349 1.4 7 1.4 1.22 1.3 i 1.37 1.249 ... ... 1.3ti 5.9, .3ti6
444 TMrichlloroethene 0.367 O. 34 8.359 0.378 O. 8.32 0.3 8.375 0.339 0.404 0.3 6.5 10.6 1 5 ethy cyclohexane ...... O. 90 .545 8.~82 O. .495 0.~1 .562 0.538 O.~ZO 0.5 11.2 10.7 5
20 1~ U:8~g~!~~opropane . ?:~~? . ?:~~? .. ' ?:~?~ 0:o2~ P\ oj81 ~: II 8:361 R:291 ~:Oo~ R:~ I IF 1l:R~
48 Bromodi chloromethane 0.429 8.449 t.428 0.222 O. ~~4 O. 3~7 . ~o 0.218 O. ga6 .459 U~l 6. ~ 1d615
49Dibromomethane 0.154 .152 .154 8.170 0.168 0.1~7 .166 8.170 8.155 .184 ~.lH 7.09 11.539i 50 2-Chloroethyl vinyl ether ......... ,.. .021 .030 0.027 8.0ij 8.027 .028 .027 0.032 .07 11.5512.154 5514.Methyl.2.pentanone 0.129 0.117 0.131 .159 0.165.1 .159 .155 0.145 0.150 .1 11.0512.209 52 ~iS'l~'Dichloropropene 0.455 0.472 0.462 0.533 0.528 0.45 0.514 0.518 0.479 0.553 .497 7.27 12.5129 ~ T~T~ne~~ijENE'D5 1.30~ 1.18~1 1.~5~ 1.41' 1.430 1.268 1.30a 1.23~ 1.17' ..... ~ 1.29~ 7'M
O l~:~r§1 55 Toluene 1.652 1.61 1. 9~ 1. 781 1.774 1.484 1.667 1.692 1.34W······ 1.633 8. 13.0567 56 Ethyl methacrylate ...... 8.25 O. 5 0.301 0.301 0.262 0.308 0.307 0.2 0.336 R.291 9. 13.4893
57 trans-l.~·Dichloropropene 0.410 .38 0.~9 ~.439 1.443 8'm 8.446 0.441 0.41 8.481 0.423 7.~2 1~.4~~
5 ~~ ~:~e~a~~ghloroethane .?:~~ .?:~~~ ~O:lij~ :~~~ :~~a 8:~ O:~~ ~O:~r~ 8:~1~ 0:~~3 g:~l1 ~:0~7 13:~764
60 1.3'Dic~10ro~ropane 0.397 8.397 .41R .~~ .4~~ .~ 8.432 .429 o.~~ 0.481 .41~ 6.3 14.1~5~ g~ ;nrach g,oe he~ 0.~2 .323 .350 8'304 '~09 8· 6 .36g .~~ 0'2 8.4 1 '~~6 ~.3 14.1~7 ~ ~:~!a~~~~~~n!ane '~:~3~ '8?:~~~ '0:~i5 '8':210 '0:231' '~':~~i '8?:~1i '8':239 '~:2i~ '8':~~~ 88:~g 9:~& ~2:ij9~~i6
5 l-Chlorohexane 0.657 .621 0.707 .737 0.74 .631 .700 .715 0.653 .683 .~5 ~.27 15.~2 6 Chlorobenzene 1.063 O.~~~ 1.Q~3 1.1~1 1.12 .959 1.06~ 1.073 8·~7 ...... 1. ~O 6.§1 15.60 ~ ~t~t~~1~~~achloroethane ~:ij~ ~:933 ~:9§~ ~:r1g ~:g~ 1:1~j ~:§~3 ~:~~7~ .. : .. ~ .?:~~? ~: 7~ a:7~ 1~:~6§~
2 ~6 ~:XY1~~ & p·Xylene 1:11~ l:taI 1:16r 1:~15 1:5~' l:~~~ 1:~ 1:4 :::::: :::::: 1:1~9 5:~g 1!:~~9 ~~ 1~~~"gA~~~~2ENE'D4 1:~~~ l:~ l:~~~ ~:oll 1:~~ l:&&f 1:as1 l:a r ·~:?~i :::::i l:aaf ~:~6 l§:lr~,
74 Bromoform 0.364 ~.~3 0.337 8.366 0.380 0.326 8·3~0 ~.389 0.352 0.424 0'U7 8.02 17.17~i 751.1.2.2.Tetrachloroethane 0.573 . 58 0.654 .694 0.717 0.597 .62 .678 0.615 0.720 0.60 7.6617·nm 764.Bromofluorobenzene 1.170 . 17 1.155 1.193 1.2~ 1.092 1.18 .054 1.020 1.242 1.1 2 7.4917. 77 1.2.3-Trichloropropane --.---0.167 0.172 0.175 0.17 O.l~l 0.172 0.173 0.155 0.184 0.19 6.04 17. 78 trans.1
1
4.Dichloro.2.butene ............ 0.171 &.174 &.16 0.1 g 0.177 2.17~ 0.164 0.192 0.172 ~.85 17.77R1 ~6 G~~~g~n~~~~ene ~:6~I ~5:§~~ 8:~g~ 1:8~ 1:I6~ 8:3 0 I:~~2 1:6~1 '0:945 'i:i47 I:i~ 6:~0 1~:~9~ 81 1.3 5-Trimethylbenzene 4.041 .741 3.925 4.164 4.167 3.4~2 ~.80 3.707 ............ 3. 72 6.52 17.~779 82 2-Cnlorotoluene 33 .. ~27 .600 ~.739 4.173 4.214 3.5 9 .~9 3.840 ............ 3. ~ 6.44 17. 9~8 ~ 4.Chlorotoluene 918 .144 3.216 3.287 2.77 . 73 3.033 ............ 3. 5.83 18. 57 85 tert·Butylbenzene 1.0Q~ g:89~ 'a12 1·R15 1·8 5 0.81 O. 12 0.928 0.803 0.989 g. 2 8.15 1§. 3 2 8~ ~~:3~i~lmeth lbenzene ~"9a 5:~~8 ~)i~ 4i:9~ ~:11~ H3 ~:m ~:~3~ :::::: :::::: 5:~1 ~:6~~ 18:41~11
871)·Is0p.r e 4:5~~ 4'H! 4.152 .565 4.42 3.7 4.125 3.1 ............ 4.201 7. 11' 88 1.3-D1C ne 2.19 1. 1.959 .108 2.0 1.76 1.14 1. 1.715 ...... 1.955 7. 1. 385 ~9 1.2,3·T t y enzene 3.62 3. 3.456 3.7D 3. 3.080 3. 3.35 ............ 3.471 6.31 1 . 163 o 1.4·Dic obenzene 2.0~0 1.913 1.931 2.11 2.10 1.782 1.~ 2.000 1.749 ...... 1.960 6.691. 553 1 n·Butylbenzene 4.46 3.833 3.911 4.2 4.258 3.533 3. 3.680 ............ 3.978 7.801. 759
92 l,2-Dlchlorobenzene 1.7 7 1.599 1'885 1.818 1.759 1.478 1. 52 1.666 1.~5 1.421 1.630 8.54 1 .4460
93 1.2-Dlbromo-3-chloropropane 0.116 0.100 O. 7 0'118 0.111 8.090 0.10~ 0.1~ 8· 8 0.118 o.lH ~.34 20.219
941,2.4.Trichloro!)enzene 1.301 1.063 L 82 1.13 1.126 .948 Li8 1.03 . 27 1.0~ 1.06 .9321.0 3 95 Hexachlorobutadlene ...... 0.674 0.70 0.71 0.786 0.604 O. 6 0.6 0.544 0.6 0.6 .3521.1 96 NaDhthalene ...... 1.546 1.479 1. 5 1.60 1.417 1. 6 1.613 1.456 1.57 1.5 5.9721.32 I 97 l.2.3'~::=Obenzene = 0.788 0.821 ~I 0.95 0.746 O. 56 0.8111 0.730 0.840 0.822 7.4521.579
j~~~rRSDIO~nLt9 ""lJUU~x_%RSD: 15.9
Use Least Square Linear R~ression with weighting factor of inverse concentration for comps with % RSD > 15
Resp Ratio ~ xo + xl * Amt Ratio -7---~~
IDX Parameter xO xl CCF V 3
11 Acetone 0.00748 0.03560 0.9975 1/ n r'Z
REPORT ID: 23E135 Page 57 of 454
Instr'urnent ID : 06 Beginning OateTime :05/15/23 13:47
Splke Unlts :PPB IC File :REW253
Col!mn SPec_:RTX582.2 10 :0~25MM Ending DateTime : 5/15/23 11:41
HPChem Method :V006E15
13:4~ 14:ij 14:3~ 15:0~ 15:31 15:57 16:~3 16:~~ 17]~ 1'?~~
M IDX Parameters REW248 REW249 REW250 REW251 REW252 REW253 REW254 REW255 REW256 REW257 AvORec % RSO Av Rt M
:==: === =======
1 1.4·0IFLUOROBENZENE 1 1 1 1 1 1 1 1 1 1 1 0 10.0855 2 01chlorodifluoromethane ...... 90 98 100 112 98 96 104 91 110 6 7.72 1.6928 3 Chloromethane 87 89 92 102 112 102 101 107 95 116 7.6 9.53 1.9294
4 Vinyl chloride 109 90 103 108 114 101 96 99 9833 97 7 98'.1197 22.'50380190
5 Bromomethane 97 86 95 99 112 101 100 105 112 6.1 6 Chloroethane 97 84 101 98 110 100 100 105 9943 112 5.7 8.16 2.5986
7 Oichlorofluoromethane 9940 96 96 108 110 91 102 104 109 6.5 67.'2590 22.'86738691
8 Trichlorofluoromethane .......... ~ 100 103 108 97 94 103 90 110 4'79
5 9 Acrolein 92 112 108 88 104 104 96 104 8.86 3.3964
10 1.lL2·Trichloro·1.2.2·trifluoroethane 113 101 99 103 104 87 96 101 9891 107 5.9 7.94 3.4483 5 11 Acel;one 74 112 110 84 103 99 104 15 3 18 81 3 4881 12 1.1·Dichloroethene 90 92 96 105 108 91 102 106 96 115 '7 8:21 3:6558 25 13 tert·Butyl alcohol ...... ...... 82 100 100 91 109 109 100 118 8 10.70 3.8130 14 Acetonitrile '" ............................................. " .... ...... 0.000 0.00 0.0000
15 Methyl acetate ...... ...... 115 111 96 85 93 96 93 111 9.3 11.30 4.1850
16 Iodomethane .... ~? .... ~~ 99 107 106 8970 100 102 92 109 4.8 6.30 4.1169 17 MethYlene chloride 110 112 103 96 98 88 105 7.7 9.47 4.3946 18 CarbOn disulfide ...... ...... 8497 101 110 96 100 98 89 108 4 9 6 70 4 3684 5 19 Acrylonitrile 8487 93 104 111 91 111 109 100 116 9:6 10:70 4:6408
20 tert·Butyl methyl ether (MTBE) 95 90 104 107 9941 106 107 99 115 7.8 9.58 4.6869 21 trans·1.2·0ichloroethene 96 96 97 107 106 100 103 93 111 5.4 6.64 4.8965 ~~ ~~~~1°~~!t~i~er (DIPE) ... ~?? .... ~~ §~ 18~ 18Y §9 181 18~ §~ llg ~:~ ~:~~ g:~~
24 1.1·0ichloroethane 98 93 99 107 106 89 100 102 93 110 5.4 6.83 5.7516 25252.Butanol ...... ...... .. .................................. "'''' 0.000 0.00 0.0000
26 tert·Butyl ethyl ether (ETBE) 94 97 9903 113 105 90 102 102 94 110 6.45 7.69 6.5334 5 27 2·Butanone 100 100 100 107 87 105 102 97 110 7.25 6.8310
28 2.2,Oichloropropane 106 98 105 110 108 94 98 101 9864 91 6.1 7.69 7.0742 29 cls·1.2·0ichloroethene 98 91 9995 110 106 90 101 103 112 6.5 7.69 7.1957 30 Chloroform 102 97 105 106 89 99 101 92 109 4.7 6.29 7.5750
5 ~~ ~~~k~~rg~~~~ ... ioi .... 97 .... 93 ... i07 ... i03 9
82
0 ... ioi ... i03 .... 95 ... iii o. g~g g:9~ 9: 3g~g
33 Tetrahydrofuran .-----------.---_. 118 94 97 97 94 109 8.8 11.27 8.0750
34 Dibromofluoromethane 97 90 9988 102 109 96 102 96 95 115 5.7 7.49 8.0990 351.111.Trichloroethane 103 96 101 110 85 92 107 95 114 6.7 8.58 8.4927 36 Cyc ohexane ...... 86 95 106 123 90 94 105 101 8.6 11.51 8.4742 372.2.4.Trimethylpentane ...... ...... ...... ...... ...... .. ...................... 0.000 0.00 0.0000
38 1.1·0ichloropropene 95 96 9998 110044 105 8970 101 104 94 112 5.3 6.60 8.8471 39 Carbon tetrachloride 101 102 105 98 103 92 111 4.9 6.68 9.0172
40 tert·Amvl methyl ether (TAME) 101 8992 91 105 106 91 103 1049 9661 11127 6.1 7.31 9.2002 41 1.2·Dichloroethane·d4 92 96 104 108 97 101 97 6.3 8.16 9.2158 42 1.2·0ichloroethane 95 96 93 105 105 91 102 103 95 113 5.8 6.90 9.4144 43 Benzene 102 98 100 108 108 91 101 102 92 4.4 5.93 9.3976
44 Trichloroethene 101 92 99 104 106 90 100 103 93 111 5.1 6.58 10.6631 45 Methylcyclohexane ...... 87 97 104 116 88 92 100 96 119 8.7 11.2310.7445
461.2'Dichloropropane 107 98 97 103 101 89 100 103 92 110 4.7 6.21 11.0227 20471.4.0ioxane ...... ...... ...... 111 99 82 97 99 93 118 286 1184 11 5689
48 Bromodichloromethane 102 107 102 105 101 87 97 99 92 109 4:9 6:64 11:4615 49 Dibromomethane 95 94 95 105 104 91 102 105 96 114 5.9 7.09 11.5393 502.Chloroethyl vinyl ether ...... ...... 78 111 100 93 100 104 100 119 7.9 11.5512.1543
5514.Methvl.2.pentanone 90 81 91 110 115 92 110 108 101 104 9.4 11.0512.2091
52 cis·1A~·Dichloropropene 92 95 93 107 106 92 103 104 96 111 6.51 7.27 12.5129 53 CHLORuoENZENE·05 1 1 1 1 1 1 1 1 1 1 0 15.5374 54 Toluene·d8 101 91 105 109 110 9918 101 95 91 ...... 5.6 7.1312.9154 55 Toluene 101 99 103 109 109 102 104 82 ...... 6.3 8.6213.0567
56 Ethyl methacrylate ...... 89 88 103 103 90 106 105 99 115 7 6 9 34 13 4893 57 trans·1.3·Dichloropropene 97 90 93 104 105 91 105 104 97 114 6:4 7:62 13:4345
5 g~ ~:Ae~a~~~hloroethane ... ~?? .... ~~ ~ 18~ 18~ H~ 183 18~ §~ 18~ ~:~ ~:3~ l~:~~
60 1.3·Dichloropropane 95 95 10908 107 105 91 103 102 94 110 5.5 6.36 14.1355 61 Tetrachloroethene 96 90 107 107 91 101 103 93 112 5.9 7.39 14.1874 62 Oibromochloromethane 100 98 95 103 104 90 103 103 95 111 4.7 6.12 14.5379 632.Ethyl.1.butanol ............................................................ 0.000 0.00 0.0000
64 1.2·01bromoethane 101 91 94 105 103 9920 105 104 96 111 5.9 7.06 14.8793 65 l·Chlorohexane 96 91 103 108 108 102 104 95 100 5.2 6.27 15.2259 66 Chlorobenzene 101 95 100 110 107 91 101 102 92 4.9 6.31 15.6024
67 1L1.1~~·Tetrachloroethane 96 96 98 108 104 8899 101 101 95 112 5.4 6.91 15.6932 68 El;p'yloenzene 110043 98 101 107 106 100 96 4.1 5.72 15.7095 2 69 m·~lene & p·Xylene 98 104 111 109 92 100 84 ...... ...... 6.8 8.9615.8360 70o.Xylene 100 99 99 107 106 9890 100 100 ...... ...... 3.4 5.46 16.5678 71 Styrene 101 99 99 109 106 102 102 92 ...... 4.4 5.9916.6337
72 Isopropylbenzene 103 98 1011 108 105 88 99 96 4.61 6.2017.1731
73 1.2·D!CHLOROBENZENE·D4 1 931 1 1 1 1 1 1 1 0 19.4187 74 Bromoform 9
8
9
7
92 100 104 89 106 106 96 116 6.2 8.04 17.1743
75 1.1.2.2·Tetrachloroethane 100 99 105 109 9690 105 103 93 109 6.1 7.66 17.4508 76 4·Bromofluorobenzene 103 90 102 105 110 100 93 90 110 6.2 7.49 17.5494
77 1.2.3· Trichloropropane ...... 99 102 104 102 89 102 102 92 109 4 5 6 04 17 6648 78 trans.1
1
4.0iChloro.2.butene ...... ...... 99 101 98 87 103 102 95 112 4:7 6:85 17:7701
79 n·Propy benzene 104 100 104 111 1109 891 98 83 7.1 9.51 17.7702 80 Bromobenzene 103 96 97 105 107 101 102 91 111 5.5 6.90 17.8091
81 1.3
L
5·Trimethylbenzene 104 97 101 108 108 89 98 96 5.2 6.52 17.9779 822.Cnlorotoluene 101 93 97 108 109 91 101 100 ...... ...... 4.8 6.44 17.9908
83 4·Chlorotoluene 105 96 19038 106 105 89 98 100 ...... ...... 4.6 5.83 18.0557
84 tert·Butylbenzene 109 96 109 108 B9 98 100 B6 106 6.5 8.15 18.4322
85 1.2,4·Tnmethylbenzene 108 101 101 105 105 88 98 94 5.1 6.65 18.4711 86 sec·Butylbenzene 108 19091 102 111 107 8989 9988 84 ...... ...... 7.4 9.561B.6788 87 p·Isopr9Dyltoluene 109 99 109 105 91 ...... ...... 5.8 7.45 18.8346
88 1.3·Dichlorobenzene 109 96 100 108 107 90 100 101 88 ...... 5.7 7.5418.9385
89 1.2.3· Trimethylbenzene 105 99 100 108 106 89 9B 96 4.8 6.31 19.0163 90 1.4·0ichlorobenzene 105 98 99 108 108 91 101 102 89 ...... 5.3 6.69 19.0553 91 n·Butylbenzene 112 96 98 107 107 89 99 93 ...... 6.3 7.80 19.2759
92 1.2·01chlorobenzene 110 9B 102 112 108 91 101 102 90 87 6.8 8.54 19.4460
93 1.2·0ibromo·3·chloropropane 110 95 92 103 106 86 104 101 93 112 7 8.34 20.2209
94 1.2.4·Trichlorobenzene 122 99 94 106 105 89 101 97 87 101 7 9.93 21.0543 95 Hexachlorobutadiene ...... 102 106 111 112 92 101 96 83 97 7.2 9.35 21.1840 96 Naphthalene ...... 99 95 105 106 91 107 103 93 101 5 5.9721.3268
97 1.2.3·Trichlorobenzene ...... 96 100 109 110 91 104 99 89 102 5.8 7.45 2l.5749 __ -1_-----------_.1_-__________________________________ 1_-'
REPORT ID: 23E135 Page 58 of 454
Compound List Report 06
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title METHOD 8260
Last Update Tue May 16 12:41:48 2023
Response via Initial Calibration
Total Cpnds 97
PK# Compound Name QIon Exp_RT Rel_RT Cal #Qual A/H ID
--------------------------------------------------------------------------
1 I l,4-DIFLUOROBENZENE 114 10.08 1. 000 A 1 A B
2 T Dichlorodifluoromethane 85 1. 69 0.168 A 1 A B
3 T Chloromethane 50 1. 93 0.191 A 1 A B
4 T Vinyl chloride 62 2.05 0.203 A 1 A B
5 T Bromomethane 94 2.50 0.248 A 1 A B
6 T Chloroethane 64 2.60 0.258 A 1 A B
7 T Dichlorofluoromethane 67 2.64 0.262 A 1 A B
8 T Trichlorofluoromethane 101 2.88 0.285 A 1 A B
9 T Acrolein 56 3.40 0.338 A 1 A B
10 T 1, 1, 2-Trichloro-1,2,2-trifluor 151 3.45 0.342 A/ 1 A B
11 T Acetone 43 3.49 0.346 L 1 A B
12 T l,l-Dichloroethene 61 /3.66 0.362 A 2 A B
13 T tert-Butyl alcohol 59 3.80 0.377 A 1 A B
14 T Acetonitrile 41 0.00 0.000 A 2 A B
15 T Methyl acetate 74 4.18 0.414 A 1 A B
16 T Iodomethane 142 4.12 0.408 A 1 A B
17 T Methylene chloride 49 4.39 0.435 A 2 A B
18 T Carbon disulfide 76 4.37 0.433 A 1 A B
19 T Acrylonitrile 53 4.64 0.460 A 2 A B
20 T tert-Butyl methyl ether (MTBE) 73 4.68 0.464 A 1 A B
21 T trans-1,2-Dichloroethene 96 / 4.89 0.485 A 1 A B
22 T Isopropyl ether (DIPE) 45 5.60 0.556 A 1 A B
23 T Vinyl acetate 43 5.84 0.579 A 1 A B
24 T 1,1-Dichloroethane 63 5.75 0.570 A 2 A B
25 T 2-Butanol 45 ~.36 0.631 A 1 A B
26 T tert-Butyl ethyl ether (ETBE) 59 6.53 0.647 A 1 A B
27 T 2-Butanone 43 6.82 0.676 A 1 A B
28 T 2,2-Dichloropropane 77 7.07 0.701 A 2 A B
29 T cis-1,2-Dichloroethene 96 7.20 0.714 A 1 A B
30 T Chloroform 83 /7.57 0.751 A 2 A B
31 T tert-Amyl alcohol 59 8.49 0.842 A 1 A B
32 T Bromochloromethane 130 7.95 0.789 A 1 A B
33 T Tetrahydrofuran 42 ,.' 8.08 0.801 A 2 A B
34 S Dibromofluoromethane 111 8.10 0.803 A 1 A B
35 T l,l,l-Trichloroethane 97 8.49 0.842 A 2 A B
36 T Cyclohexane 84 8.47 0.840 A 1 A B
37 T 2,2,4-Trimethylpentane 57 8.46 0.839 A 1 A B
38 T 1,1-Dichloropropene 110 8.85 0.878 A 1 A B
39 T Carbon tetrachloride 119 9.02 0.894 A 1 A B
40 T tert-Amyl methyl ether (TAME) 73 9.20 0.912 A 2 A B
41 S 1,2-Dichloroethane-d4 65 9.22 0.914 A 1 A B
42 T 1,2-Dichloroethane 62 ./ 9.41 0.933 A 1 A B
43 T Benzene 78 r/ 9.40 0.932 A 2 A B
44 T Trichloroethene 130 10 :67 1.058 A 3 A B
45 T Methylcyclohexane 83 10.75 1. 066 A 2 A B
46 T 1,2-Dichloropropane 63 11.02 1. 093 A 1 A B
47 T l,4-Dioxane 88 11. 58 1.148 A 1 A B
48 T Bromodichloromethane 83 11.46 1.136 A 1 A B
49 T Dibromomethane 93 11.54 1.144 A 2 A B
50 T 2-Chloroethyl vinyl ether 63 12.15 1. 205 A 1 A B
51 T 4-Methyl-2-pentanone 43 12.20 1.210 A 3 A B
52 T cis-1,3-Dichloropropene 75 12.51 1. 241 A 3 A B
,5f..A 51\1i~'3 REPORT ID: 23E135 Page 59 of 454
53 I
54 S
55 T
56 T
57 T
58 T
59 T
60 T
61 T
62 T
63 T
64 T
65 T
66 T
67 T
68 T
69 T
70 T
71 T
72 T
73 I
74 T
75 T
76 S
77 T
78 T
79 T
80 T
81 T
82 T
83 T
84 T
85 T
86 T
87 T
88 T
89 T
90 T
91 T
92 T
93 T
94 T
95 T
96 T
97 T
Cal A =
#Qual =
A/H
ID R
CHLOROBENZENE-D5
Toluene-d8
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
2-Ethyl-1-butanol
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
l,2-DICHLOROBENZENE-D4
Bromoform
1, 1, 2,2-Tetrachloroethane
4-Bromofluorobenzene
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-butene
n-Propylbenzene
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
l,2,4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
l,3-Dichlorobenzene
1, 2, 3-Trimethylbenzene
l,4-Dichlorobenzene
n-Butylbenzene
l,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
l,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
1, 2, 3-Trichlorobenzene
117 15.54
98 12.91
91 13.04
69 13.49
75 /13.43
97 13.69
43
76
164
129
43
107
91
112
131
91
91
91 I
13.77
14.13
14.19
14.54
0.00
14.87
15.23
15.60
15.69
15.71
15.84
16.56
104) 16.63
105 )17.17
152 19.42
173 17.17
83 17.45
95 17.55
110 17.67
53 17.77
91 17.77
156 17.81
105 ,17.98
91/, 17.99
91./18.06
134 18.43
105 118.47
105 18.68
119 18.83
146 18.94
105 19.02
146 1 19 .05
91 ·19.28
146 19.44
157' 20.22
180 21.05
225' 21.18
12g 21.33
180 21.57
1.000
0.831
0.840
0.868
0.865
0.881
0.886
0.910
0.913
0.936
0.000
0.957
0.980
1. 004
1.010
1.011
1.019
1. 066
1. 070
1.105
1.000
0.884
0.898
0.904
0.910
0.915
0.915
0.917
0.926
0.926
0.930
0.949
0.951
0.962
0.970
0.975
0.979
0.981
0.993
1. 001
1.041
1.084
1.091
1. 098
1.111
Average L = Linear LO = Linear w/origin Q = Quad QO
number of qualifiers
Area or Height
R.T. B = R.T. & Q Q = Qvalue L = Largest A = All
V006E15.M Tue May 16 13:04:22 2023
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
2
1
1
1
1
2
1
1
3
1
3
1
1
1
1
1
1
1
2
3
1
2
1
2
1
1
2
1
2
1
1
1
1
1
2
2
2
2
2
1
1
2
2
1
2
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
= Quad w/origin
REPORT ID: 23E135 Page 60 of 454
BFB
Data File D:\HPCHEM\1\DATA\23E15\REW247.D Vial: 1
Acq On 15 May 2023 1:21 pm Operator: LYamas
Sample BFB06E11 Inst 06
Misc T/CHK Multiplr: 1.00
MS Integration Params: RTE.P
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
I
Title : METHOD 8260
bundance
600000
500000
400000
300000
200000
ime->
bundance
100000
80000
60000
40000
20000
16.00
50
TIC: REW247.D
16.50 17.00 17.50 18.00
Average of 17.524 to 17.549 min.: REW247.D (-)
95
75
174
la-> Oho~~~~~~~~~~~~T¥~~~~rn~~~~~Tr~~~~~~~~
AutoFind: Scans 1111, 1112, 1113; Background Corrected with Scan 1101
I Target I ReI. to I Lower I Upper I ReI. .-~ Raw I Result
Mass Mass Limit% Limit% Abn% Abn Pass/Fail I
----------------------------------------------------------------------
50 95 15 40 16.1 ,. 17574 PASS
75 95 30 60 42.6, 46548 PASS
95 95 100 100 100.0 109200 PASS
96 95 5 9 6.81' 7473 PASS
173 174 0.00 2 0.0 0 PASS
174 95 50 100 72.81' 79544 PASS
175 174 5 9 7.8/ 6188 PASS
176 174 95 101 99.7/ 79317 PASS
177 176 5 9 5.9 4642 PASS
REW247.D V006E15.M
;(; [A.
Tue May 16 10: 57: 33 2023 7$1(1!(ft3
REPORT ID: 23E135 Page 61 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW248.D Vial: 2
Operator: Acq On 15 May 2023 1:47 pm
Sample V006E151
LYamas
06
Misc 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
32) Bromochloromethane
35) 1 f 1,1-Trichloroethane
R.T. Qlon Response Conc Units Dev(Min)
10.09
15.54
19.42
114 4047991
117 3493918
152 1340035
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111
9.22 65
12.92 98
17.55 95
1.93
2.05
2.50
2.60
2.64
2.87
3.45
3.51
3.66
3.82 ./
4.18
4.10
4.41
4.37
4.64
4.68
4.91
5.61
5.84
5.75
50
62
94
64
67
101
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
6. 55 ~
6.86
7.09
7.20
7.58
7.95
8.50
/96
83
130
97
37993 0.29 ug/l 0.00
Recovery 2.90%
25143 0.28 ug/l 0.00
Recovery 2.80%
137203 0.30 ug/l 0.00
Recovery = 3.00%
47036 0.31 ug/l 0.00
Recovery = 3.10%
46653
56805
41603
30604
64666
58741
38048
69384
60113
30499
6329
70848
75417
126770
23974
54839
44211
120328
45884
73765
92956
36323
42723
44374
74424
23360
62496
0.26 ug/l
0.33 ug/l
0.29 ug/l
0.29 ug/l
0.27 ug/l
0.28 ug/l
0.34 ug/l
2.12 ug/l
0.27 ug/l
6.73 ug/l
0.58 ug/l
0.29 ug/l
0.48 ug/l
0.24 ug/l
1. 31 ug/l
0.25 ug/l
0.29 ug/l
0.30 ug/l
0.37 ug/l
0.30 ug/l
0.28 ug/l
1. 50 ug/l
0.32 ug/l
0.29 ug/l
0.30 ug/l
0.30 ug/l
0.31 ug/l
Qvalue
73
86
77
76
87
85
87
90
93
78
85
92
95
100
93
56
94
97
96
94
97
98
87
95
94
84
97
(#) = qualifier out of range (m) = manual integration
REW248. D V006E15.M Tue May 16 13: 02: 58 20233 LA.... 5/ n/1J Page 1
REPORT ID: 23E135 Page 62 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW248.D
Acq On 15 May 2023 1:47 pm
Sample V006E151
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,1,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
81) 1,3,5-Trimethylbenzene
82) 2-Chlorotoluene
83) 4-Chlorotoluene
84) tert-Butylbenzene
(#) = qualifier out of range (m)
8.48
8.85
9.01
9.22
9.42
9.40
10.66
10.75
11.02
11.55
11.46
11.54
12.18
12.23
12.51
13.06
13.50
13.44
13.68
13.81
14.14
14.19
14.54
14.89
15.23
15.60
15.69
15.71
15.84
16.58
16.64
17.17
17.19
17.46
17.98
17.77
17.81
17.98
17.99
18.06
18.43
84
110
119
73
62
~78
130
83
63
88
83
93
63
43
75
91
69
75
97
43
76
164
129
107
91
<'112
131
/ 91
/ 91
j 91
104
105
173
83
53
91
156
(105
t 91
91
134
51372
18908
48271
79148
32408
167389
44625
50570
40949
1752
52122
18674
4676
78180
55272
173194
29549
43010
26008
51677
41641
35848
30880
24282
68849
111434
36902
212708
313345
154546
118095
203195
14638
23049
8829
250260
42648
162438
156058
128102
40580
0.24 ug/l
0.28 ug/l
0.30 ug/l
0.30 ug/l
0.29 ug/l
0.31 ug/l
0.30 ug/l
0.22 ug/l
0.32 ug/l
3.17 ug/l
0.31 ug/l
0.28 ug/l
0.43 ug/l
1. 34 ug/l
0.27 ug/l
0.30 ug/l
0.29 ug/l
0.29 ug/l
0.32 ug/l
1. 27 ug/l
0.28 ug/l
0.29 ug/l
0.30 ug/l
0.30 ug/l
0.29 ug/l
0.30 ug/l
0.29 ug/l
0.31 ug/l
0.62 ug/l
0.30 ug/l
0.30 ug/l
0.31 ug/l
0.30 ug/l
0.26 ug/l
0.38 ug/l
0.31 ug/l
0.31 ug/l
0.31 ug/l
0.30 ug/l
0.31 ug/l
0.33 ug/l
Qvalue
89
90
95
92
94
98
94
84
89
99
82
92
60
94
92
99
77
90
92
94
81
94
92
97
98
98
98
99
99
96
96
97
97
81
80
97
91
96
98
97
97
REW248.D V006E15.M Tue May
= manual integration 4 tA-----
16 13,02,59 2023 57 1111-3 Page 2
I
REPORT ID: 23E135 Page 63 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW248.D
Aeq On 15 May 2023 1:47 pm
Sample V006E151
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
85) 1,2,4-Trimethylbenzene 18.47 105 166371 0.32 ug/l 96
86) see-Butylbenzene 18.68 105 233104 0.32 ug/l 99
87) p-Isopropyltoluene 18.84 119 184307 0.33 ug/l 99
88) 1,3-Diehlorobenzene 18.94 146 86000 0.33 ug/l 98
89) 1, 2, 3-Trimethylbenzene 19.02 1105 146005 0.31 ug/l 99
90) 1,4-Diehlorobenzene 19.06 146 82833 0.32 ug/l 98
£' 91) n-Butylbenzene 19.28 91 178346 0.33 ug/l 98
92) 1,2-Diehlorobenzene 19.45 /146 71851 0.33 ug/l 99
93) 1,2-Dibromo-3-ehloropropan 20.21 157 4652 0.33 ug/l 86
94) 1,2,4-Triehlorobenzene 21. 05 /180 52284 0.36 ug/l 97
95) Hexaehlorobutadiene 21.18 -225 34006 0.39 ug/l 93
96 ) Naphthalene 21. 33 128 92025 0.44 ug/l 99
97) 1,2,3-Triehlorobenzene 21.59 ,180 42699 0.39 ug/l 96
j
(#) = qualifier out of range (m) = manual integration
REW248.D V006E15.M Tue May 16 13:02:59 2023 Page 3
REPORT ID: 23E135 Page 64 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW248.D
Aeq On 15 May 2023 1:47 pm
Sample V006E151
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
40000001
I
I
3800000j
3600000
34000001
32000001
!
3000000j
I
2800000
26000001
24000001
2200000
I
2000000j
I
1800000j
1600000j
1
1400000 1
1200000
800000
600000
400000
200000.
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW248.D
O~~~~~~~~~~~I~~~~~~~I~'~' ~~~~~'~I ~'~~~~~~~~-'~I~~~
Tlme-·~->~ ___ =2.~00~_~4:!:..0~0~_~6~.0~0~_~8~.0~0~_~10~.~OO~_~12:::.:.0~O~_1,--4~.0~0~---,1,-",6~.0-,,-0_~1~8.-,,-00~_~20::.:.0~0,,--__
REW248.D V006E15.M Tue May 16 13:03:02 2023 Page 4
REPORT ID: 23E135 Page 65 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW249.D
Acq On 15 May 2023 2:13 pm
Sample V006E152
Vial: 3
Operator: LYamas
06
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:04 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
8.10 111
9.22 65
12.92 98
17.55 95
1. 69 85
1.93 50
2.05 62
2.50 94
2.60 64
2.64 67
2.88 101
3.40 56
3.45 151
3.49 43
3.66 '(""61
3.82 59
4.18 74
4.14 142
4.39 49
4.37 76
4.64 53
4.70 73
4.89 <96
5.60 45
5.86 43
5.75 ( 63
6.55 59
6.84 43
7.07 77
7.20 j 96
7.57 83
3991932
3506540
1340560
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
58080 0.45 ug/l 0.00
Recovery = 4.50%
40049 0.45 ug/l 0.00
Recovery = 4.50%
206877 0.45 ug/l 0.00
Recovery = 4.50%
68150 0.45 ug/l 0.00
Recovery = 4.50%
71993
79008
77579
60590
43450
113245
101798
19750
56017
82686
101676
45579
4266
119639
105307
236333
41767
102541
72355
181807
40037
114614
158528
59971
65518
67618
116649
0.45 ug/l
0.45 ug/l
0.45 ug/l
0.43 ug/l
0.42 ug/l
0.48 ug/l
0.50 ug/l
1. 96 ug/l
0.51 ug/l
3.13 ug/l
0.46 ug/l
10.20 ug/l
0.40 ug/l
0.50 ug/l
0.67 ug/l
0.45 ug/l
2.31 ug/l
0.48 ug/l
0.48 ug/l
0.46 ug/l
0.33 ug/l
0.47 ug/l
0.49 ug/l
2.51 ug/l
0.49 ug/l
0.45 ug/l
0.48 ug/l
Qvalue
93
80
85
89
78
99
94
84
98
96
99
57
50
98
96
99
92
98
95
99
71
97
95
96
87
99
95
(#) = qualifier out of range (m) = manual integration6«
REW249.D V006E15.M Tue May 16 13: 05: 10 2023 .5 /(7(~S Page 1
REPORT ID: 23E135 Page 66 of 454
Ql1antitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW249.D
Aeq On 15 May 2023 2:13 pm
Sample V006E152
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 3
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:04 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAeq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
32) Bromoehloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) eis-1,3-Diehloropropene
55} Toluene
56} Ethyl methacrylate
57} trans-1,3-Dichloropropene
58} l,l,2-Trichloroethane
59) 2-Hexanone
60} l,3-Dichloropropane
61) Tetrachloroethene
62} Dibromochloromethane
64) l,2-Dibromoethane
65} 1-Chlorohexane
66} Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68} Ethylbenzene
69} m-Xylene & p-Xylene
70) o-Xylene
71} Styrene
72} Isopropylbenzene
74} Bromoform
75} l,l,2,2-Tetrachloroethane
77} l,2,3-Trichloropropane
78} trans-1,4-Dichloro-2-buten
79} n-Propylbenzene
80} Bromobenzene
7.95 130
8.12 42
8.50 97
8.48 84
8.86 110
9.01 119
9.20 73
9.42 62
9.40 78
10.67 130
10.73 83
11. 03 ./ 63
11. 59 88
11.46 83
11.54
12.15
12.23
12.51
13.06
13.50
13.43
13.68
13.78
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.72 / 91
15.84 91
16.58 ,/ 91
16.64 /104
f' 93
63
43
75
91
69
75
97
43
76
164
129
107
_ 91
112
131
17.17
17.17
17.46
17.65
17.69
105
173
83
110
53
17.77 /91
17.81 156
36968
11750
96364
89534
31778
80038
118294
53663
265102
66697
97775
61812
8070
89660
30343
8118
117192
94153
282723
45202
66643
40504
69294
69552
56658
50848
36465
108915
174498
61121
338859
493729
253909
194325
323919
22995
44101
11186
2614
400979
66286
0.48 ug/l
0.87 ug/l
0.48 ug/l
0.43 ug/l
0.48 ug/l
0.51 ug/l
0.46 ug/l
0.48 ug/l
0.49 ug/l
0.46 ug/l
0.44 ug/l
0.49 ug/l
14.82 ug/l
0.53 ug/l
0.47 ug/l
0.75 ug/l
2.04 ug/l
0.47 ug/l
0.49 ug/l
0.44 ug/l
0.45 ug/l
0.49 ug/l
1.69 ug/l
0.47 ug/l
0.45 ug/l
0.49 ug/l
0.45 ug/l
0.45 ug/l
0.47 ug/l
0.48 ug/l
0.49 ug/l
0.98 ug/l
0.49 ug/l
0.50 ug/l
0.49 ug/l
0.47 ug/l
0.50 ug/l
0.49 ug/l
0.11 ug/l
0.50 ug/l
0.48 ug/l
(#) = qualifier out of range (m) = manual integration ~~
Qvalue
99
65
95
90
99
94
92
98
98
94
89
98
99
99
91
74
95
94
98
95
93
98
98
92
96
96
95
97
99
99
99
99
100
99
99
94
98
71
88
98
94
REW249.D V006E15.M Tue May 16 13:05:11 2023 ~/(7(~3 Page 2
REPORT ID: 23E135 Page 67 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW249.D
Acq On 15 May 2023 2:13 pm
Sample V006E152
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT ReVleWed)
Vial: 3
Operator: LYamas
06 lnst
Multiplr: 1. 00
Quant Time: May 16 13:04 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) 1,3,5-Trimethylbenzene 17.98 t'105 250725
82) 2-Chlorotoluene 17.99 _ 91 241328
83) 4-Chlorotoluene 18.06 . 91 195576
84) tert-Butylbenzene 18.43 134 59862
85) 1,2,4-Trimethylbenzene 18.47 ..-105 259543
86) sec-Butylbenzene 18,.68 /105 363821
87) p-lsopropyltoluene 18.83 119 279358
88) l,3-Diehlorobenzene 18.94 ~146 126305
89) l,2,3-Trimethylbenzene 19.02 ' 105 231114
~ 90) 1,4-Dichlorobenzene 19.05 146 128248
'< 91 ) n-Butylbenzene 19.28 91 256912
92) l,2-Dichlorobenzene 19.44 146 107158 r 93) l,2-Dibromo-3-ehloropropan 20.22 157 6706
94) l,2,4-Triehlorobenzene 21. 05 .... 180 71234
95) Hexaehlorobutadiene 21.18 225 45167
96) Naphthalene 21. 33 128 103639
97) 1,2,3-Triehlorobenzene 21.59 ./180 52797
(#) = qualifier out of
REW249.D V006E15.M
range (m) = manual integration
Tue May 16 13:05:11 2023
0.48 ug/l 98
0.47 ug/l 99
0.48 ug/l 94
0.48 ug/l 99
0.51 ug/l 97
0.50 ug/l 98
0.50 ug/l 99
0.48 ug/l 96
0.50 ug/l 97
0.49 ug/l 97
0.48 ug/l 97
0.49 ug/l 94
0.47 ug/l 90
0.50 ug/l 98
0.51 ug/l 99
0.49 ug/l 98
0.48 ug/l 93
Page 3
REPORT ID: 23E135 Page 68 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E1S\REW249.D
Aeq On lS May 2023 2:13 pm
Sample V006E1S2
Mise O.Sppb 8260/2.Sppb KET-AA/12.Sppb TBA
Vial: 3
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:04 2023 Quant Results File: V006E1S.RE
Method
Title
Last Update
. Response via
Abundance
i 4000000j
38000001
!
i
36000001
I
3400000J
I
3200000
J
1
3000000,
1
2800000j
l
2600000j
i ,
I
2400000j
1
22000001
2000000j
I
1800000)
I
i
16000001
1
i
14000001
J
I
1200000j
I
1000000j
Tlme-->
I '
2.00
D:\HPCHEM\1\METHODS\V006E1S.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW249.D
I ' , i ! I
4.00
!
6.00 8.00 10.00 12.00 14.00 16.00
I
18.00 20.00
REW249.D V006E1S.M Tue May 16 13:0S:14 2023 Page 4
REPORT ID: 23E135 Page 69 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Ar~ On 15 May 2023 2:39 pm
Sample V006E153
Misc 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
Quant Time: May 16 13:05 2023
Vial: 4
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1 /2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
8.10 111
9.22 65
12.92 98
17.55 95
1. 69
1. 93
2.05
2.50
2.60
2.64
2.87
3.40
3.47
3.49
3.66
3.82
4.20
4.12
4.39
4.37
4.64
4.70
4.89
5.61
5.86
5.75
6.53
6.84
7.07
7.20
7.58
85
50
62
94
64
67
101
56
151
43
_ 61
59
74
142
49
76
53
73
,/ 96
45
43
/63
59
43
77
96
83
3815846
3307080
1289255
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
120247 0.98 ug/l 0.00
Recovery = 9.80%
82904 0.97 ug/l 0.00
Recovery = 9.70%
449340 1.05 ug/l 0.00
Recovery = 10.50%
148893 1.02 ug/l 0.00
Recovery = 10.20%
150383
154743
169831
128679
100169
218071
196026
43352
104512
87099
202582
86580
11781
228491
165142
488158
73042
184704
140384
368437
109860
231943
290176
103199
133173
136259
228566
0.99 ug/l
0.92 ug/l
1.03 ug/l
0.95 ug/l
1. 01 ug/l
0.97 ug/l
1.00 ug/l
4.51 ug/l
0.99 ug/l
3.72 ug/l
0.96 ug/l
20.27 ug/l
1.14 ug/l
0.99 ug/l
1.11 ug/l
0.97 ug/l
4.22 ug/l
0.90 ug/l
0.97 ug/l
0.98 ug/l
0.94 ug/l
0.99 ug/l
0.93 ug/l
4.52 ug/l
1.05 ug/l
0.95 ug/l
0.99 ug/l
Qvalue
77
89
93
98
92
100
96
81
95
87
99
77
70
100
98
99
98
91
98
98
90
99
99
98
92
96
98
(#) = qualifier out of range (m) = manual integration ~
REW250.D V006E15.M Tue May 16 13,06,00 2023 ~1i~~ Page 1
REPORT ID: 23E135 Page 70 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Acq On 15 May ?o/.~ 2:39 pm
Sample V006E153
Misc 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 4
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:05 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
81) l,3,5-Trimethylbenzene
82) 2-Chlorotoluene
7.95
8.49
8.48
8.85
9.02
9.20
9.41
9.40
10.67
10.73
11.02
11.46
11. 54
12.18
12.21
12.51
13.06
13.50
13.43
13.69
13.79
14.14
14.19
14.54
14.89
15.23
15.60
15.69
15.72
15.84
16.58
16.64
17.17
130
97
84
110
119
73
62
78
130
83
63
83
93
63
43
75
91
69
.c 75
97
43
76
164
129
107
r 91
112
131
r 91
~ 91
_91
104
,-105
17 . 17'--173
17.45 83
17.67 110
17.77"-' 53
17 . 77 -91
17.81 156
17.98 105
17.99 91
67470
186594
190247
62753
147951
222528
100158
514761
137045
207804
116884
163388
58609
8101
249272
176356
558925
84657
130233
76769
170644
135650
118695
92534
71083
233909
348259
118094
658042
987378
483001
365555
631717
43475
84314
22134
22010
800134
128714
505985
482053
0.92 ug/l
0.98 ug/l
0.95 ug/l
1. 00 ug/l
0.98 ug/l
0.91 ug/l
0.94 ug/l
1. 00 ug/l
0.99 ug/l
0.97 ug/l
0.97 ug/l
1. 02 ug/l
0.95 ug/l
0.78 ug/l
4.53 ug/l
0.93 ug/l
1.04 ug/l
0.88 ug/l
0.93 ug/l
0.99 ug/l
4.42 ug/l
0.98 ug/l
1.00 ug/l
0.94 ug/l
0.94 ug/l
1. 03 ug/l
1.00 ug/l
0.98 ug/l
1.01 ug/l
2.07 ug/l
0.99 ug/l
0.99 ug/l
1.02 ug/l
0.92 ug/l
0.99 ug/l
1.02 ug/l
0.99 ug/l
1.04 ug/l
0.97 ug/l
1.01 ug/l
0.97 ug/l
Qvalue
93
97
98
96
99
96
99
98
97
96
98
93
97
72
97
98
97
95
97
93
89
99
99
98
100
100
99
95
100
100
99
100
99
99
93
80
86
99
96
97
100
(#) = qualifier out of range (m) = manual integration :;V' )
REW2S0oD V006E1SoM Tue May 1613,06,01 2023 jlnr~)page 2
REPORT ID: 23E135 Page 71 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Aeq On 15 May 2023 2:39 pm
Sample V006E153
Mise 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(Q'l' H.evleWeCl)
Vial: 4
Operator: LYamas
Inst 06
Multiplr: 1. 00
Quant Time: May 16 13:05 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
83) 4-Chlorotoluene 18.06 91 405372 1. 03 ug/l 97
84) tert-Butylbenzene 18.43 <134 117555 0.98 ug/l 86
85) 1, 2, 4-Trimethylbenzene 18.47 105 498497 1. 01 ug/l 96
86) see-Butylbenzene 18.68 105 708889 1. 02 ug/l 99
87) p-Isopropyltoluene 18.83 119 535337 0.99 ug/l 97
88) l,3-Diehlorobenzene 18.94 146 252530 1. 00 ug/l 99
89) l,2,3-Trimethylbenzene 19.02 105 445557 1. 00 ug/l 98
90 ) l,4-Diehlorobenzene 19.06 146 248895 0.98 ug/l 100
91 ) n-Butylbenzene 19.28 91 504196 0.98 ug/l 99
92) l,2-Diehlorobenzene 19.44 146 213399 1. 02 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.21 157 12515 0.92 ug/l 98
94) 1, 2, 4-Triehlorobenzene 21. 05 180 129155 0.94 ug/l 98
95) Hexaehlorobutadiene 21.18 225 90244 1. 06 ug/l 96
96 ) Naphthalene 21. 33 128 190668 0.95 ug/l 97
97 ) l,2,3-Triehlorobenzene 21.57 180 105899 1. 00 ug/l 98
~ j]":" 11 ( 1-~
------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
REW250.D V006E15.M Tue May 16 13:06:01 2023 Page 3
REPORT ID: 23E135 Page 72 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Aeq On 15 May 2023 2:39 pm
Sample V006E153
Mise 1ppb 8260/5ppb KET-AA/25ppb TBA
Vial: 4
Operator: T.Yamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:05 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
('-bundance
I 40000001
I 38000001 , I
36000001
34000001
I
32000001
I
I
i
30000001
I
2800000j
1
2600000
2400000
1
i
22000001
I
2000000)
\
I
18000001
i600000
1400000]
1200000!
1000000]
!
800000
600000
400000
200000
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW250.D
8"
u'J z
I a:
9
I o
::;;:
1--
1 I ! Ii!
fIirl1e--~> ___ -----'2=:.. 0:::..:O=--_~4..:.: . .:::00=--_~6.=-=O-=-O __ .::8.:=.O:.::cO __ -,-1 0=.~OO=---_-,-12=.-=-OO=---_....:.14-'.:.-=-OO=---_....:.1-=-
6
. .=OO-=---_-,1-,-8.=O-=-O _--=2",-O.=O~O_
REW250.D V006E15.M Tue May 16 13:06:03 2023 Page 4
REPORT ID: 23E135 Page 73 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW251.D Vial: 5
Operator: Acq On 15 May 2023 3:05 pm
Sample V006E154
LYamas
06
Misc 2ppb 8260/10ppb KET-AA/50ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1} l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. Qlon Response Cone Units Dev(Min}
10.09
15.54
19.42
114 3845602
117 3365890
152 1298844
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111
9.22 65
12.92 98
17.55 95
85
50
62
94
64
67
101
56
151
43
1. 70
1. 93
2.05
2.51
2.60
2.64
2.88
3.40
3.45
3.49
3.66
3.82
4.20
4.12
4.39
4.37
4.64
4.68
4.91
./ 61
59
74
5. 60 ~
5.84
5.75 /
6.55
6.84
7.07
7.20 /
7.58
142
49
76
53
73
96
45
43
63
59
43
77
96
83
252349 2.03 ug/l 0.00
Recovery = 20.30%
180555 2.09 ug/l 0.00
Recovery = 20.90%
953811 2.18 ug/l 0.00
Recovery = 21.80%
309988 2.11 ug/l 0.00
Recovery = 21.10%
309277
346662
357869
269797
196082
490068
407376
109073
220328
189733
442969
220896
23332
496686
338399
1025563
180342
431042
311592
806286
222879
509818
707656
230218
282038
316271
489316
2.01 ug/l
2.03 ug/l
2.16 ug/l
1.98 ug/l
1.96 ug/l
2.15 ug/l
2.07 ug/l
11.25 ug/l
2.07 ug/l
11.17 ug/l
2.09 ug/l
51.31 ug/l
2.25 ug/l
2.14 ug/l
2.25 ug/l
2.03 ug/l
10.34 ug/l
2.07 ug/l
2.14 ug/l
2.12 ug/l
1. 90 ug/l
2.15 ug/l
2.25 ug/l
10.01 ug/l
2.21 ug/l
2.20 ug/l
2.11 ug/l
Qvalue
88
93
98
91
91
100
99
97
99
95
98
89
99
98
97
99
93
97
96
99
94
98
98
98
98
95
98
(#) = qualifier out of range (m) = manual integration 1;'r~3 Page 1 REW251.D V006E15.M Tue May 16 13:06:54 2023
REPORT ID: 23E135 Page 74 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW251.D
Acq On 15 May 2023 3:05 pm
Sample V006E154
Misc 2ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 5
Operator: LYamas
06
1.00
Inst
Multiplr:
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l /1-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1 /2-Diehloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodiehloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetraehloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95 130
8.08 42
8.50 97
8.46 84
8.85 110
9.02 119
9.20 73
9.42 62
9.40 78
10.67 130
10.75/83
11.03 /63
11.58 88
11.46 <83
11. 54 93
12.16 63
12.21 43
12.51 -75
13.06 91
13.49 69
13.43 ,/75
13.69 97
13.78 43
14.14 76
14.19 164
14.54129
14.89 107
15.23 r 91
15.60 112
15. 69 ~131
15.71 ,,91
15.84 . 91
./
16. 56 ~ 91
16.64 104
17.17 ..1:.05
17.17 -173
17.46 83
17.67 110
17.77 t' 53
17.77'" 91
17.81 156
157707
30822
390985
427109
131446
314816
520054
227805
1120908
290397
447568
249801
23328
340037
130658
22711
612168
410238
1199073
202519
295589
165943
415196
301971
257857
204679
161860
496386
775106
266450
1420621
2144800
1060204
819395
1374288
95130
180340
45447
45309
1718255
282700
2.15 ug/l
2.38 ug/l
2.03 ug/l
2.12 ug/l
2.07 ug/l
2.08 ug/l
2.10 ug/l
2.11 ug/l
2.15 ug/l
2.08 ug/l
2.08 ug/l
2.06 ug/l
44.48 ug/l
2.10 ug/l
2.10 ug/l
2.18 ug/l
11.03 ug/l
2.15 ug/l
2.18 ug/l
2.07 ug/l
2.08 ug/l
2.11 ug/l
10.57 ug/l
2.14 ug/l
2.14 ug/l
2.05 ug/l
2.10 ug/l
2.15 ug/l
2.19 ug/l
2.17 ug/l
2.14 ug/l
4.43 ug/l
2.14 ug/l
2.18 ug/l
2.17 ug/l
1.99 ug/l
2.10 ug/l
2.07 ug/l
2.03 ug/l
2.21 ug/l
2.10 ug/l
Qvalue
97
97
99
95
99
96
97
99
100
98
99
100
89
96
98
99
99
96
99
97
99
96
97
100
98
97
98
100
99
100
100
99
99
98
99
98
95
89
84
100
99
(#) = qualifier out of range (m) = manual integration ~V'
REW251.D V006E15.M Tue May 16 13:06:54 2023 5/(1(13 Page 2
I REPORT ID: 23E135 Page 75 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW251.D
Aeq On 15 May 2023 3:05 pm
Sample V006E154
Mise 2ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 5
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
81) 1, 3, 5-Trimethylbenzene 17.98 /105 1081651 2.15 ug/l
82) 2-Chlorotoluene 17.99 /" 91 1084144 2.16 ug/l
83) 4-Chlorotoluene 18.06 ./ 91 835324 2.11 ug/l
84) tert-Butylbenzene 18.43 < 134 263746 2.19 ug/l
85) l,2,4-Trimethylbenzene 18.47 105 1041492 2.10 ug/l
86) see-Butylbenzene 18.68 ; 105 1555759 2.23 ug/l
87) p-Isopropyltoluene 18.83 119 1185955 2.17 ug/l
88) l,3-Diehlorobenzene 18.94 ,£ 146 547698 2.16 ug/l
89) 1, 2, 3-Trimethylbenzene 19.02 105 975483 2.16 ug/l ,
90) 1,4-Diehlorobenzene 19.06/ 146 549441 2.16 ug/l
91) n-Butylbenzene 19.28 / 91 1102336 2.13 ug/l
92) l,2-Diehlorobenzene 19.44 .146 472239 2.23 ug/l
93) l,2-Dibromo-3-ehloropropan 20.22 157 27927 2.04 ug/l
94) l,2,4-Triehlorobenzene 21. 05 ' 180 294202 2.12 ug/l
95) Hexaehlorobutadiene 21.18 225 189957 2.22 ug/l
96) Naphthalene 21. 33 128 427345 2.11 ug/l
97) 1, 2, 3-Triehlorobenzene 21.57 1 180 233695 2.19 ug/l
Qvalue
100
99
98
97
99
100
99
99
100
99
100
98
100
98
99
99
97
:f; L0l1!~)
----------------------------------------------------------------i;Ji------
(#) = qualifier out of range (m) = manual integration
REW251.D V006E15.M Tue May 16 13:06:55 2023 Page 3
REPORT ID: 23E135 Page 76 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW251.D
Aeq On 15 May 2023 3:05 pm
Sample V006E154
Mise 2ppb 8260/10ppb KET-AA/50ppb TBA
Vial: 5
Operator: LYamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
. 40000001
3800000
3600000j
34000001
I
32000001
I
3000000 1
1
i
28000001
!
)
26000001
24000001
!
i
22000001
20000001
!
1800000j
i
i
1600000j
1
14000001
!
12000001
10000001
I
8000001
Time-->
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW251.D
w z
W
N
Z
W
~ cr
3
"-is
.f_
I
eo II
, II· -I
II
I
I ! i j! i
20.00
REW251.D V006E15.M Tue May 16 13:06:57 2023
REPORT ID: 23E135 Page 77 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW252.D
Acq On 15 May 2023 3:31 pm
Sample V006E155
Misc 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1. 00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. Qlon Response Conc units Dev(Min)
10.09
15.54
19.42
114 3557639
117 3124358
152 1193635
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111 627878 5.46 ug/l 0.00
Recovery = 54.60%
9.22 65 430359 5.39 ug/l 0.00
Recovery = 53.90%
12.92 98 2234443 5.51 ug/l 0.00
Recovery 55.10%
17.55 95 744773 5.51 ug/l 0.00
1. 70
1. 93
2.05
2.51
2.60
2.64
2.88
3.40
3.45
3.49
3.66
3.82
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.60
5.84
5.75
6.53
6.82
7.07
7.20
7.57 ,/
85
50
62
94
64
67
101
56
151
43
61
,-59
74
142
49
76
53
73
"-/96
45
43
/ 63
59
43
77
96
83
Recovery = 55.10%
796604
879650
873841
706180
511095
1158528
982617
237790
514631
382605
1062657
494012
46077
1138504
716059
2565521
440342
1029047
712459
1855853
547149
1168676
1527679
568785
642335
704825
1137254
5.60
5.58
5.70
5.59
5.52
5.50
5.39
26.52
5.22
27.53
5.42
124.05
4.79
5.30
5.14
5.48
27.28
5.35
5.29
5.28
5.04
5.33
5.26
26.73
5.43
5.30
5.30
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
96
97
100
98
99
98
97
99
98
96
99
98
91
100
100
100
96
98
100
100
99
99
98
100
99
99
99
(#) = qualifier out of range (m) = manual integration
REW252.D V006E15.M Tue May 16 13:07:37 2023
REPORT ID: 23E135 Page 78 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW252.D
Acq On 15 May 2023 3:31 pm
Sample V006E155
Misc 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 6
Operator: LYamas
06 lnst
Multiplr: 1. 00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) lsopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-l,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95 130
8.08 42
8.49 97
8.48 84
8.84 110
9.02 119
9.20 73
9.41 62
9.40 78
10.66 130
10.75 83
11. 02 63
11.57 ./88
11.46 83
11. 54 93
12.15 63
12.20 43
12.51 ~75
13.06 91
13.49 69
13.43 ("'75
13.68 97
13.77 43
14.14 76
14.19 164
14.54 129
14.88 107
15.23 r-91
15.60 112
15.69 131
15.71/91
15.84 /' 91
16.56 91
16.63 /104
17.17 ~105
17.17 173
17.45 83
17.67 110
17.77 ~ 53
17.771/ 91
17.81 156
351232
56072
977399
1139498
308915
736609
1211378
525480
2604416
682258
1152076
565345
48188
753932
298845
48293
1464122
939617
2771973
470500
691724
376308
996069
685068
597664
483367
369034
1160888
1757717
594316
3250428
4893955
2431264
1844683
3101156
226869
427730
103231
101048
3934894
657815
5.16 ug/l
4.68 ug/l
5.48 ug/l
6.13 ug/l
5.26 ug/l
5.25 ug/l
5.29 ug/l
5.26 ug/l
5.40 ug/l
5.28 ug/l
5.77 ug/l
5.04 ug/l
99.31 ug/l
5.03 ug/l
5.19 ug/l
5.01 ug/l
28.53 ug/l
5.31 ug/l
5.43 ug/l
5.18 ug/l
5.23 ug/l
5.14 ug/l
27.32 ug/l
5.23 ug/l
5.34 ug/l
5.22 ug/l
5.15 ug/l
5.43 ug/l
5.36 ug/l
5.20 ug/l
5.28 ug/l
10.88 ug/l
5.30 ug/l
5.28 ug/l
5.28 ug/l
5.18 ug/l
5.43 ug/l
5.12 ug/l
4.93 ug/l
5.51 ug/l
5.33 ug/l
Qvalue
98
97
93
99
98
98
100
100
99
100
99
99
99
99
98
93
99
98
100
98
100
98
96
98
99
99
96
99
99
99
99
100
99
99
100
99
97
98
95
100
100
(#) = qualifier out of range (m) = manual integration. 2
REW2S2.D V006E1S.M Tue May 16 13,07,38 2023 j3\\/('"]"J Page 2
REPORT ID: 23E135 Page 79 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW252.D
Arq On 15 May ?0?3 3:31 pm
Sample V006E155
Mise 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 6
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) 1,3,5-Trimethylbenzene 17.98,105 2487149 5.38 ug/l 99
82) 2-Chlorotoluene 17.99 91 2515191 5.46 ug/l 100
83) 4-Chlorotoluene 18.06 91 1914290 5.26 ug/l 99
84) tert-Butylbenzene 18.43 ,./ ~34 599863 5.41 ug/l 100
85) 1,2,4-Trimethylbenzene 18.47 105 2394715 5.25 ug/l 100
86 ) see-Butylbenzene 18.68 . 105 3451091 5.37 ug/l 100
87) p-Isopropyltoluene 18.83 119 2645019 5.28 ug/l 100
88) 1,3-Diehlorobenzen~ 18.94 ,146 1246913 5.34 ug/l 99
89 ) 1,2,3-Trimethylbenzene 19.02 105 2200836 5.31 ug/l 99
90 ) 1,4-Diehlorobenzene 19.06 ~146 1258042 5.38 ug/l 100
91) n-Butylbenzene 19.28' 91 2541174 5.35 ug/l 99
92) 1,2-Diehlorobenzene 19.44 146 1049666 5.40 ug/l 98
93) 1,2-Dibromo-3-ehloropropan 20.22 157 66500 5.29 ug/l 96
94) 1,2,4-Triehlorobenzene 21.05,-180 671805 5.26 ug/l 99
95) Hexaehlorobutadiene 21.18 225 439549 5.59 ug/l 99
96) Naphthalene 21.33 128 990988 5.32 ug/l 100
97) 1,2,3-Triehlorobenzene 21. 57,.,-180 540371 5.51 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW252.D V006E15.M Tue May 16 13:07:38 2023 Page 3
REPORT ID: 23E135 Page 80 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW252.D
Aeq On 15 May 2023 3:31 pm
Sample V006E155
Mise 5ppb 8260/25ppb KET-AA/125ppb TBA
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
V\bundance
, 54000001
52000001
50000001
4800000
1
1
4600000
44000001
42000001
I
40000001
!
3800000 1
3600000
3400000
3200000
3000000
I
28000001
I
26000001
24000001
2200000\
20000001
18000001
16000001
14roml
1200000
1
10000001
I
8000001
!
6000001
, 4000001
i 200000i J,
Time-->
, I
2.00
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW252.D
c.
'"
, I ! t I ! t j I Ii! f I I , I ' I I I I I , I I I ' I I I I I
8.00 10.00 12.00 14.00 16.00 18.00 20.00
REW252.D V006E15.M Tue May 16 13:07:41 2023 Page 4
REPORT ID: 23E135 Page 81 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW253.D Vial: 7
Operator: LYamas Acq On 15 May 2023 3:57 pm
Sample V006E156 Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.08 114
15.54 117
19.42 152
4201521
3710147
1432830
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111 1305027 9.62 ug/l 0.00
Recovery = 96.20%
9.22 65 915332 9.70 ug/l 0.00
Recovery = 97.00%
12.91 98 4706069 9.77 ug/l 0.00
Recovery = 97.70%
17.55 95 1565323 9.65 ug/l 0.00
1.69
1. 93
2.05
2.50 .,-
2.60 .
2.64
2.88
3.40
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.60
5.84
5.75
6.53
6.82
7.07
7.20
7.57
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
/96
45
43
t' 63
59
43
77
96
83
Recovery = 96.50%
1637617
1893638
1837298
1509839
1095198
2252461
2093398
454999
1010215
666083
2114930
1062191
94827
2277481
1429985
5329386
868979
2128776
1439653
3744955
1237880
2315425
3082964
1087224
1313299
1422036
2252579
9.75
10.17
10.14
10.13
10.02
9.06
9.72
42.96
8.67
41. 86
9.13
225.85
8.35
8.97
8.69
9.64
45.59
9.38
9.04
9.03
9.65
8.94
8.98
43.27
9.40
9.05
8.89
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
(#) = qualifier out of range (m) = manual integration
REW253. D V006E15. M Tue May 16 13: 08: 16 2023 Pt]l1rfl..3 Page 1
REPORT ID: 23E135 Page 82 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW253.D
Acq On 15 May 2023 3:57 pm
Sample V006E156
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 7
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95 130
8.08 " 42
8.49 ./ 97
8.48 84
8.85 110
9.02 119
9.20 73
9.41 I 62
9.40 / 78
10.67 130
10.75 83
11.02 ,,63
11. 58 88
11.46 83
11.54 93
12.15 63
12.20 43
12.51 75
13.04 91
13.49 69
13.43 75
13.69 97
13.77 43
14.13 76
14.19 164
14.54 129
14.87 107
15.23 ,91
15.60 112
15.69 131
15.71 c 91
15.84 ,91
16.56 -c-91
16.63 104
17.17 ,105
17 .17 F 173
17.45 83
17.67 110
17.77 53
17.77; 91
17.81 156
717797
119640
1783219
1973667
623075
1444891
2461779
1073573
5159975
1378480
2080780
1178744
94023
1543161
615764
106234
2784136
1916555
5505571
973573
1428058
753664
1852964
1419194
1209020
989254
767432
2341526
3556694
1205259
6503421
9801704
4856684
3730318
6172080
467221
854710
216138
215277
7793304
1317692
8.94 ug/l
8.46 ug/l
8.47 ug/l
8.99 ug/l
8.98 ug/l
8.73 ug/l
9.09 ug/l
9.11 ug/l
9.06 ug/l
9.04 ug/l
8.83 ug/l
8.90 ug/l
164.07 ug/l
8.72 ug/l
9.05 ug/l
9.33 ug/l
45.93 ug/l
9.18 ug/l
9.09 ug/l
9.02 ug/l
9.10 ug/l
8.67 ug/l
42.80 ug/l
9.13 ug/l
9.11 ug/l
9.00 ug/l
9.03 ug/l
9.22 ug/l
9.13 ug/l
8.89 ug/l
8.89 ug/l
18.35 ug/l
8.91 ug/l
9.00 ug/l
8.84 ug/l
8.88 ug/l
9.04 ug/l
8.92 ug/l
8.75 ug/l
9.09 ug/l
8.89 ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
(#) = qualifier out of range (m) = manual integration ~
REW253.D V006E15.M Tue May 16 13,08,16 2023 :!J 411.1(ll;b page 2
REPORT ID: 23E135 Page 83 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW253.D
Aeq On 15 May 2023 3:57 pm
Sample V006E156
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 7
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
81 ) 1, 3, 5-Trimethylbenzene 17.98 105 4918141 8.86 ug/l
82) 2-Chlorotoluene 17.99 (' 91 5027165 9.10 ug/l
83) 4-Chlorotoluene 18.06 -91 3879282 8.88 ug/l
84) tert-Butylbenzene 18.43 134 1183975 8.89 ug/l
85) 1,2,4-Trimethylbenzene 18.47 , 105 4798479 8.76 ug/l
86) see-Butylbenzene 18.68 -105 6881508 8.93 ug/l
87) p-Isopropyltoluene 18.83 119 5369847 8.92 ug/l
88) 1,3-Diehlorobenzene 18.94 146 2533563 9.04 ug/l
"' 89) 1,2,3-Trimethylbenzene 19.02 105 4412429 8.87 ug/l
90 ) l,4-Diehlorobenzene 19.05 146 2552753 9.09 ug/l .,-
91) n-Butylbenzene 19.28 91 5062110 8.88 ug/l
92) l,2-Diehlorobenzene 19.44 146 2117371 9.07 ug/l
93) l,2-Dibromo-3-ehloropropan 20.22 /157 129657 8.59 ug/l
94) l,2,4-Triehlorobenzene 21.05 180 1358872 8.87 ug/l
95) Hexaehlorobutadiene 21.18 /225 866034 9.18 ug/l
96 ) Naphthalene 21. 33 1 128 2030259 9.07 ug/l
97) 1,2,3-Triehlorobenzene 21.57 180 1069362 9.08 ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
(#) -: -~~~i;:~i~~ -~~; -~~ -~~~~~ -(~) -: -~~~~~i -;:~;~~~~;;:~~ 2 fJ· r1 +iUJ_ ------
REW253.D V006E15.M Tue May 16 13:08:17 2023 Page 3
REPORT ID: 23E135 Page 84 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW253.D
Aeq On 15 May 2023 3:57 pm
Sample V006E156
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 16 13:07 2023
Vial: 7
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
. Response via
(\bundance,
, I
[1.05e+071
, I
l 1e+071
, 950000°1
90000001
85000001
i
80000001
75000001
70000001
6500000:
;
60000001
5500000j
50000001
I
4500000j
I
4000000j
!
3500000j
3000000)
i
i
25000001
I
20000001
I
1500000j
I
1000000;
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW253.D
REW253.D V006E15.M Tue May 16 13:08:19 2023
::;:
..:
oj
" (l)
>.
;;;:
I-"
::;: ..:
i
::;: ..:
oj
" il .,.
I-"
Q)
(J)
REPORT ID: 23E135 Page 85 of 454
Quantitation Report l QT ReVleWeO)
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Acq On 15 May 2023 4:23 pm
Sample V006E157
Misc 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09
15.54
19.42
8.10
9.22
12.92
17.55
1.69
1. 93
2.03
2.50
2.60
2.64
2.88
3.40
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.60
5.84
5.75
6.53
6.82
7.07
7.20
7.58
114 3805963
117 3335114
152 1311803
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
111
65
98
95
85
50
62
94
64
67
101
56
151
43
._ 61
59
74
142
49
76
53
73
~ 96
45
43
.; 63
59
43
77
/ 96
83
2512790 20.44
Recovery =
1738666 20.34
Recovery =
8724991 20.15
Recovery =
2958120 19.92
Recovery =
ug/l
204.40%
ug/l
203.40%
ug/l
201.50%
ug/l
199.20%
0.00
0.00
0.00
0.00
2921912
3396093
3132768
2709922
1982072
4585668
3678797
19.20 ug/l
20.14 ug/l
19.10 ug/l
20.06 ug/l
20.02 ug/l
20.36 ug/l
18.85 ug/l
Qvalue
98
99
99
997420
2035596
1428238
4268621
2231395
189654
4590105
2880790
9982938
1890831
4347038
2882493
7614910
2341893
4696843
6337537
2414970
2500134
2882047
4553063
103.97 ug/l
19.28 ug/l
102.76 ug/l
20.34 ug/l
523.76 ug/l
18.45 ug/l
19.96 ug/l
19.33 ug/l
19.94 ug/l
109.51 ug/l
21.14 ug/l
19.99 ug/l
20.26 ug/l
20.15 ug/l
20.02 ug/l
20.38 ug/l
106.10 ug/l
19.76 ug/l
20.24 ug/l
19.83 ug/l
100
99
99
99
99
99
99
100
100
94
100
99
100
100
99
100
100
98
100
99
99
98
99
100
(#) = qualifier out of range (m) = manual integration ~
REW2S4.D V006E1S.M Tue May 16 13,09,41 2023 ~)1{1';' Page 1
REPORT ID: 23E135 Page 86 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Acq On 15 May 2023 4:23 pm
Sample V006E157
Mise 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
32)
33)
35 )
36)
38)
39)
40)
42)
43)
44)
45 )
46 )
47)
48 )
49 )
50 )
51)
52)
55)
56)
57)
58)
59)
60)
61)
62 )
64)
65)
66 )
67 )
68)
69)
70)
71 )
72)
74)
75)
77)
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
1, 1, 1-Trichloroethane
Cyclohexane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
1,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-l,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
l-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2{2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.95 130
8.08 42
8.49 97
8.48 84
8.84 110
9.02 119
9.19 73
9.41 ,...62
9.40 '78
10.66 130
10.75 ·83
11.02 .r 63
11.57 88
11.46 ~ 83
11.54 93
12.15 c 63
12.20 43
12.51,75
13.06 91
13.49 69
13.43/,75
13.69 97
13.76 43
14.14 76
14.19 164
14.54 129
14.88 107
15.23 ' 91
15.60 112
15.69 131
15.71 ~ 91
15.84 -91
16.56 / 91
16.63 104
17.17 105
17 .17' 173
17.45 83
17.67 110
17.77 (' 53
17.77 I 91
17.81 156
1475341
250681
3524529
3763298
1267735
2927444
5052902
2182458
10376562
2763783
3944545
2397108
201018
3122921
1266634
203434
6052783
3910725
11116636
2052777
2975981
1557067
4205982
2883225
2403571
2033554
1604682
4668396
7105690
2464349
13161388
19160742
9770567
7629916
12396822
1022322
1816745
451376
463887
15431615
2727836
20.28 ug/l
19.58 ug/l
18.47 ug/l
18.92 ug/l
20.17 ug/l
19.52 ug/l
20.61 ug/l
20.43 ug/l
20.12 ug/l
20.00 ug/l
18.48 ug/l
19.98 ug/l
387.24 ug/l
19.47 ug/l
20.55 ug/l
19.73 ug/l
110.24 ug/l
20.67 ug/l
20.42 ug/l
21. 17 ug/l
21.09 ug/l
19.94 ug/l
108.08 ug/l
20.64 ug/l
20.14 ug/l
20.58 ug/l
21.00 ug/l
20.44 ug/l
20.29 ug/l
20.22 ug/l
20.02 ug/l
39.91 ug/l
19.94 ug/l
20.48 ug/l
19.76 ug/l
21. 22 ug/l
20.99 ug/l
20.36 ug/l
20.60 ug/l
19.65 ug/l
20.11 ug/l
Qvalue
99
98
95
98
99
98
99
100
100
99
98
99
99
99
99
95
100
99
99
98
100
100
99
98
100
98
99
100
100
99
99
97
99
100
100
99
98
98
98
99
99
(#) = qualifier out of range (m) = manual integration~V\ b
REW254 . D V006E15. M Tue l\1ay 16 13: 09: 42 2023 5 J\ 1 {I'l/ Page 2
REPORT ID: 23E135 Page 87 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Aeq On 15 May 2023 4:23 pm
Sample V006E157
Mise 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
81 ) 1/3,5-Trimethylbenzene 17.98.---105 9968910 19.63 ug/l
82) 2-Chlorotoluene 17.99 , 91 10215393 20.19 ug/l
83) 4-Chlorotoluene 18.06 <,91 7798700 19.50 ug/l
84) tert-Butylbenzene 18.43 134 2391915 19.62 ug/l
85) 1/2,4-Trimethylbenzene 18.47 105 9805084 19.55 ug/l
86 ) see-Butylbenzene 18.68 j .. 05 13766972 19.50 ug/l
87 ) p-Isopropyltoluene 18.83 119 10821876 19.64 ug/l
c 88) l,3-Diehlorobenzene 18.94 J.46 5113416 19.94 ug/l
89 ) 1, 2, 3-Trimethylbenzene 19.02 105 8888768 19.52 ug/l
90 ) l,4-Diehlorobenzene 19.06
,-).46 5201666 20.23 ug/l
91) n-Butylbenzene 19.28 91 10313816 19.76 ug/l
92) l,2-Diehlorobenzene 19.44 /146 4335220 20.27 ug/l
93) l,2-Dibromo-3-ehloropropan 20.22 157 284745 20.60 ug/l
94) 1,2,4-Triehlorobenzene 21.05 /180 2832572 20.19 ug/l
95) Hexaehlorobutadiene 21.18 225 1738172 20.13 ug/l
96) Naphthalene 21.33 128 4372122 21.34 ug/l
97) l,2,3-Triehlorobenzene 21.57 180 2246376 20.83 ug/l
<'
Qvalue
99
99
99
100
100
99
100
99
99
99
99
100
97
99
99
100
99
(#) = qualifier out of range (rn) = manual integration L-, LA (ru~
REW254.D V006E15.M Tue May 16 13:09:42 2023 /31\1r-Page 3
REPORT ID: 23E135 Page 88 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Aeq On 15 May 2023 4:23 pm
Vial: 8
Operator: LYamas
06 Sample V006E157
Mise 20ppb 8260/100ppb KET-AA/500ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Initial Calibration
Abundance
. 2.2e+071
1
I
2.1e+07j
I
2e+07j
I 1.ge+07i
I
1.8e+07j
i
1.7e+071
1.6e+07j
I
1.5e+07j
1.4e+07j
i
13e+071
j
1.2e+07i
j
1.1e+07j
1
1e+071
90000001
I
8000000j
I
70000001
i
60000001
I
50000001
\
40000001
i
3000000
2000000,
I
10000001
i
1
Time-->
"'j 1 ' ! i ! ! ,i !!, \ j! i j
2.00 4.00 6.00 8.00
TIC: REW254.D
I I I
1111, U~I~
I \ ! I I iii! i ! j iii! i j , i
10.00 12.00 14.00 16.00 18.00 20.00
REW254.D V006E15.M Tue May 16 13:09:45 2023
REPORT ID: 23E135 Page 89 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Acq On 15 May 2023 4:49 pm
Sample V006E158
Misc 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-l,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
3921302
3465018
1341861
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10
9.22
12.92
17.55
1. 69
1. 93
2.03
2.50
2.60
2.64
2.88
3.38
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.61
5.84
5.75
6.53
6.82
7.07
7.20
7.58
111 3634116 28.70 ug/l
287.00%
ug/l
291.20%
ug/l
286.20%
ug/l
279.50%
0.00
Recovery =
65 2564386 29.12
Recovery =
98 12878257 28.62
Recovery =
95 4244847 27.95
85
50
62
94
64
67
101
56
151
43
,61
59
74
142
49
76
53
73
96
45
43
/ 63
59
43
77
.I 96
83
Recovery =
4891634
5557372
5007371
4404636
3210647
7215715
6228298
1502567
3276445
2113275
6858996
3457939
305143
7257916
4500683
15184788
2867160
6818622
4600854
11963153
3690369
7437328
9825947
3614309
3949709
4550514
7175664
31. 20 ug/l
31. 99 ug/l
29.62 ug/l
31. 65 ug/l
31. 48 ug/l
31.09 ug/l
30.97 ug/l
152.02 ug/l
30.13 ug/l
148.75 ug/l
31. 73 ug/l
787.78 ug/l
28.80 ug/l
30.63 ug/l
29.31 ug/l
29.44 ug/l
161.17 ug/l
32.19 ug/l
30.97 ug/l
30.89 ug/l
30.81 ug/l
30.76 ug/l
30.67 ug/l
154.12 ug/l
30.29 ug/l
31.02 ug/l
30.34 ug/l
0.00
0.00
0.00
Qvalue
98
99
99
100
99
99
99
99
99
100
100
98
98
100
99
99
99
100
100
99
98
99
97
100
98
99
99
(#) = qualifier out of range (m) = manual integration
REW255.D V006E15.M Tue May 16 13:10:29 2023
REPORT ID: 23E135 Page 90 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Acq On 15 May 2023 4:49 pm
Sample V006E158
Misc 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P .
Vial: 9
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32)
33)
35}
36)
38)
39 )
40 }
42}
43)
44)
45)
46}
47}
48}
49}
50}
51}
52}
55}
56}
57}
58}
59 }
60}
61}
62}
64}
65}
66)
67)
68}
69 }
70}
71 }
72)
74)
75)
77)
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
1,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.95
8.06
8.49
8.48
8.84
9.01
9.19
9.41
9.40
10.66
10.75
11.02
11.57
11. 46
11.54
12.15
12.20
12.51
13.06
13.49
13.43
13.68
13.76
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.67
17.77,
17.77/
17.81
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
.--75
91
69
,-75
97
43
76
164
129
107
91
1'12
131
91
f 91
./
<' 91
104
-l05
(173
83
110
53
91
156
2310038
394090
6283300
6455052
2022903
4763085
7867379
3415413
16219166
4406334
6608062
3818779
318386
4919745
2003246
331940
9101129
6089701
17592168
3187653
4588683
2442488
6168161
4454405
3828935
3158179
2480976
7435969
11153144
3847809
19761702
25013531
15220079
11835660
18786463
1566079
2731255
698230
707821
19892507
4229917
(#) = qualifier out of range (m) = manual integration
REW255.D V006E15.M Tue May 16 13:10:30 2023
30.81
29.87
31. 97
31.49
31. 23
30.83
31.14
31. 04
30.52
30.95
30.05
30.89
595.29
29.78
31. 55
31. 24
160.89
31.24
31.10
31. 64
31. 29
30.10
152.56
30.69
30.88
30.76
31.25
31. 34
30.65
30.38
28.93
50.15
29.90
30.57
28.82
31.78
30.85
30.78
30.73
24.77
30.49
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
99
96
95
98
100
97
99
99
99
99
98
99
97
99
99
100
100
100
100
99
99
99
99
98
100
98
99
99
100
100
96
82
99
100
98
99
99
96
100
90
99
REPORT ID: 23E135 Page 91 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Aeq On 15 May 2023 4:49 pm
Sample V006E158
Mise 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81 ) l,3,5-Trimethylbenzene 17.98 ./105 14922785 28.72 ug/l 98
82) 2-Chlorotoluene 17.99 91 15459982 29.88 ug/l 98
83) 4-Chlorotoluene 18.06 91 12209255 29.85 ug/l 98
84) tert-Butylbenzene 18.43 134 3736809 29.97 ug/l 99
85 ) l,2,4-Trimethylbenzene 18.47 ,...105 14519987 28.30 ug/l 96
86) see-Butylbenzene 18.68 -1.05 18106820 25.08 ug/l 91
87 ) p-Isopropyltoluene 18.83 119 15422290 27.36 ug/l 95
88 ) l,3-Diehlorobenzene 18.94 ( 146 7982969 30.43 ug/l 99
89 ) l,2,3-Trimethylbenzene 19.02 /105 13383406 28.73 ug/l 98
90 ) l,4-Diehlorobenzene 19.06 146 8051976 30.61 ug/l 99
91 ) n-Butylbenzene 19.28 91 14814754 27.75 ug/l 94
92) l,2-Diehlorobenzene 19.44 ...-146 6707148 30.67 ug/l 100
93) l,2-Dibromo-3-ehloropropan 20.22 157 428089 30.27 ug/l 99
94) l,2,4-Triehlorobenzene 21.05 180 4159006 28.98 ug/l 99
95) Hexaehlorobutadiene 21.18 225 2553506 28.90 ug/l 100
96 ) Naphthalene 21.33 128 6492779 30.98 ug/l 98
97) 1, 2, 3-Triehlorobenzene 21.57 L 180 3266204 29.61 ug/l 100
J 1(' '1,3 ---------------------------------------------------------~ --t.-{-t-1 ~ -------
(#) = qualifier out of range (m) = manual integration 7
REW255.D V006E15.M Tue May 16 13:10:30 2023 Page 3
REPORT ID: 23E135 Page 92 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Aeq On 15 May 2023 4:49 pm
Sample V006E158
Mise 30ppb 8260/150ppb KET-AA/750ppb TBA
Vial: 9
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
i
i
3.2e+071
I
3e+071
2.8e+07
2.6e+07
1
I
2.4e+071
2.2e+071
i
I
I
2e+071
j
1.8e+07j
I , I
! 1.6e+071
:
1.4e+07:
I
1.2e+071
I ,.<{)7:
8000000 1
6000000,
I
40000001
I
I
2000000:
::!E
1--
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW255.D
II! , , I
! I
O~~~~~~~~~'~~~~~~~~~~~~~~~~~~I~~~~~~~~~~~I~~~
2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00
REW255.D V006E15.M Tue May 16 13:10:33 2023
REPORT ID: 23E135 Page 93 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW256.D Vial: 10
Operator: LYamas Acq On 15 May 2023 5:15 pm
Sample V006E159 Inst 06
Misc 50ppb 8260/250ppb KET-AA/1250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-l,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-l,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.09 114
15.54 117
19.42 152
4263582
3777879
1535124
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10
9.22
12.92
17.55
1. 69
1. 93
2.03
2.50
2.60
2.64
2.88
3.38
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.61
5.84
5.75
6.53
6.82
7.07
7.20
7.58
111 6545706 47.54 ug/l
475.40%
ug/l
482.10%
ug/l
453.10%
ug/l
450.60%
0.00
Recovery =
65 4616405 48.21
Recovery =
98 22230538 45.31
Recovery =
95 7830293 45.06
85
50
62
94
64
67
101
56
151
43
61
r 59
74
142
49
76
53
73
./ 96
45
43
/63
59
43
77
96
83
Recovery =
7733964
8922030
7627846
7062744
5155646
11900765
9887642
2562915
5251202
3510834
11224678
5951536
541252
11818617
7349390
24921334
4845338
11383845
7547333
19723543
6307546
12274712
16381044
6167866
6140601
7464245
11846328
45.36 ug/l
47.24 ug/l
41.50 ug/l
46.68 ug/l
46.49 ug/l
47.16 ug/l
45.22 ug/l
238.49 ug/l
44.41 ug/l
228.71 ug/l
47.75 ug/l
1247.02 ug/l
46.99 ug/l
45.87 ug/l
44.02 ug/l
44.45 ug/l
250.50 ug/l
49.42 ug/l
46.73 ug/l
46.85 ug/l
48.44 ug/l
46.70 ug/l
47.03 ug/l
241.89 ug/l
43.31 ug/l
46.80 ug/l
46.06 ug/l
0.00
0.00
0.00
Qvalue
98
99
99
99
99
99
98
100
100
98
100
98
100
99
99
99
100
99
100
99
98
99
98
99
98
100
99
(#) = qualifier out of range (m) = manual integration c!-,l/'-'
~1\'" "} Page 1 REW256.D V006E15.M Tue May 16 13:11:29 2023
REPORT ID: 23E135 Page 94 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW256.D
Acq On 15 May 2023 5:15 pm
Sample V006E159
Mise 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Vial: 10
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAeq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32)
33)
35)
36)
38)
39)
40)
42)
43)
44)
45 )
46 )
47)
48)
49 )
50)
51 )
52)
55)
56)
57)
58)
59 )
60 )
61)
62)
64)
65)
66)
67)
68)
69)
70)
71 )
72)
74)
75)
77 )
78)
80)
81 )
Bromochloromethane
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
1,2-Dichloroethane
Benzene
Triehloroethene
Methylcyclohexane
1,2-Dichloropropane
1,4-Dioxane
Bromodiehloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
eis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetraehloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1 t 4-Diehloro-2-buten
Bromobenzene
1, 3, 5-Trimethylbenzene
7.95
8.08
8.49
8.48
8.84
9.02
9.19
9.41
9.40
10.66
10.75
11.02
11.57
11.46
11.54
12.15
12.20
12.51
13.06
13.49
13.43
13.69
13.76
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.67
17.77
17.81
17.98
130
42
97
84
110
119
73
.... 62
.r 78
130
, 83
/63
88
83
93
r 63
43
75
('"91
(. 69
<' 75
97
43
76
164
129
107
r 91
112
131
91
r
,/ 91
/' 91
"
1'04
105
,173
83
110
/ 53
156
" 105
3859644
684090
10183653
11210701
3313953
7708860
13165338
5690365
26628035
7228001
11475475
6211205
541704
8232455
3302777
569290
15478142
10218511
25317320
5443221
7777128
4105137
10599260
7416716
6302927
5285497
4128272
12325846
18269286
6537120
257p0219
30116380
22658539
19434222
24830260
2702109
4720460
1188632
1261746
7250408
20220424
47.35 ug/l
47.69 ug/l
47.65 ug/l
50.30 ug/l
47.06 ug/l
45.89 ug/l
47.93 ug/l
47.56 ug/l
46.09 ug/l
46.69 ug/l
47.99 ug/l
46.21 ug/l
931.53 ug/l
45.82 ug/l
47.84 ug/l
49.28 ug/l
251.65 ug/l
48.22 ug/l
41.05 ug/l
49.55 ug/l
48.65 ug/l
46.40 ug/l
240.44 ug/l
46.87 ug/l
46.62 ug/l
47.22 ug/l
47.69 ug/l
47.64 ug/l
46.05 ug/l
47.35 ug/l
34.59 ug/l
55.38 ug/l
40.83 ug/l
46.04 ug/l
34.93 ug/l
47.94 ug/l
46.60 ug/l
45.81 ug/l
47.88 ug/l
45.68 ug/l
34.02 ug/l
Qvalue
99
96
93
98
100
99
98
98
99
98
98
99
100
99
99
98
100
99
89
98
98
99
98
97
100
97
99
99
99
100
80
62
90
97
87
99
98
98
99
99
82
(#)-:-~~~ii~i~~-~~~-~~-~~~;~-(~)-:-~~~~~i-i~~~;~~~i~~--S~----------------
REW256.D V006E15.M Tue May 16 13:11:30 2023 ~"1\~5 Page 2
REPORT ID: 23E135 Page 95 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW256.D
Aeq On 15 May 2023 5:15 pm
Sample V006E159
Mise 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Vial: 10
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
82) 2-Chlorotoluene 17.99 91 21740358 36.72 ug/l 87
83) 4-Chlorotoluene 18.06 ' 91 16944542 36.21 ug/l 84
84) tert-Butylbenzene 18.43 134 6164808 43.21 ug/l 99
85) l,2,4-Trimethylbenzene 18.47 105 19279917 32.84 ug/l 76 < 86) see-Butylbenzene 18.68 -105 21586862 26.13 ug/l 71
87) p-Isopropyltoluene 18.83 119 19749938 30.63 ug/l 79
88) l,3-Diehlorobenzene 18.94 '146 13161002 43.85 ug/l 98
89) 1, 2, 3-Trimethylbenzene 19.02 /105 18258743 34.26 ug/l 83
90) l,4-Diehlorobenzene 19.06 ,146 13423176 44.61 ug/l 97
91) n-Butylbenzene 19.28 91 18739437 30.68 ug/l 76
92) l,2-Dichlorobenzene 19.45 /146 11245927 44.94 ug/l 100
93) l,2-Dibromo-3-ehloropropan 20.22 157 754989 46.67 ug/l 98
94) l,2,4-Trichlorobenzene 21.05 180 7119063 43.36 ug/l 99
95) Hexachlorobutadiene 21.18 225 4177934 41.34 ug/l 100
96) Naphthalene 21.33 128 11176192 46.61 ug/l 99
97) l,2,3-Triehlorobenzene 21. 57 ' 180 5601044 44.39 ug/l 99
? ~1 (1 (1-:? -----~-----------~~--------------~-----~--------------~---------J-~------
(#) = qualifier out of range (m) = manual integration
REW256.D V006E15.M Tue May 16 13:11:30 2023 Page 3
REPORT ID: 23E135 Page 96 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW256.D
Acq On 15 May 2023 5:15 pm
Vial: 10
Operator: LYamas
Inst 06 Sample V006E159
Mise 50ppb 8260/250ppb KET-AA/1250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
i
5e+07\
4.8e+071
4.6e+071
1 4.4e+07:
4.2e+071
,
4e+071
3.8e+071
I
3.6e+071
3.4e+071
!
I
3.2e+07j
j
3e+071
I
2.8e+07)
2.6e+071
j
2.4e+07i
i
i
2.2e+071
1
iii
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW256.D
REW256.D V006E15.M
(RTE Integrator)
Page 4
REPORT ID: 23E135 Page 97 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW257.D
Acq On 15 May 2023 5:41 pm
Sample V006E1510
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.08 114 3587043 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 15.54 117 3209065 10.00 ug/l 0.00
73) l,2-DICHLOROBENZENE-D4 19.42 152 1275389 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 13378109 115.48 ug/l 0.00
Spiked Amount 10.000 Recovery = 1154.80%
41 ) l,2-Dichloroethane-d4 9.22 65 9453558 117.34 ug/l 0.00
Spiked Amount 10.000 Recovery = 1173.40%
54) Toluene-d8 12.91 98 31763488 76.22 ug/l 0.00
Spiked Amount 10.000 Recovery = 762.20%
76) 4-Bromofluorobenzene 17.55 95 15843554 109.74 ug/l 0.00
Spiked Amount 10.000 Recovery = 1097.40%
Target Compounds Qvalue
2) Dichlorodifluoromethane 1. 69 85 15852376 110.52 ug/l 98
3) Chloromethane 1. 93 50 18349244 115.47 ug/l 99
4) Vinyl chloride 2.01 62 15070553 97.47 ug/l 100
5) Bromomethane 2.50 94 14232063 111. 80 ug/l 100
6) Chloroethane 2.58 64 10419491 111.69 ug/l 100
7) Dichlorofluoromethane 2.62 67 23260568 109.57 ug/l 98
8) Trichlorofluoromethane 2.88 101 20235886 110.00 ug/l 99
9) Acrolein 3.38 56 4729127 523.06 ug/l 98
10) l,l,2-Trichloro-1,2,2-trif 3.45 151 10662452 107.17 ug/l 99
11) Acetone 3.49 43 6686156 521.12 ug/l 99
12) l,l-Dichloroethene 3.66 ' 61 22634545 114.45 ug/l 100
13) tert-Butyl alcohol 3.82 59 11761351 2929.13 ug/l 98
15) Methyl acetate 4.18 74 1083296 111. 79 ug/l 88
16) Iodomethane 4.12 142 23646572 109.09 ug/l 99
17) Methylene chloride 4.43 49 14750185 105.01 ug/l 100
18) Carbon disulfide 4.37 76 51162848 108.45 ug/l 97
19) Acrylonitrile 4.64 53 9397943 577.50 ug/l 100
20) tert-Butyl methyl ether (M 4.68 73 22345119 115.30 ug/l 100
21 ) trans-1,2-Dichloroethene 4.89 <' 96 15130990 111. 35 ug/l 100
22) Isopropyl ether (DIPE) 5.60 45 38821959 109.60 ug/l 98
23) Vinyl acetate 5.83 43 12421220 113.38 ug/l 98
24) l,l-Dichloroethane 5.75 " 63 24388561 110.28 ug/l 99
26) tert-Butyl ethyl ether (ET 6.53 59 32287682 110.18 ug/l 97
27) 2-Butanone 6.82 43 11785652 549.39 ug/l 99
28) 2,2-Dichloropropane 7.07 77 10887030 91.28 ug/l 97
29) cis-1,2-Dichloroethene 7.18 j 96 14996745 111.76 ug/l 100
30) Chloroform 7.57 83 23685553 109.47 ug/l 99
(#) = qualifier out of range (m) = manual integration 3,lA--( ~ Page 1 ~ 11v'-"
REW257.D V006E15.M Tue May 16 13:12:39 2023
REPORT ID: 23E135 Page 98 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW257.D
Acq On 15 May 2023 5:41 pm
Sample V006E1510
Misc 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: LYamas
06
1.00
Inst
Multiplr:
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32)
33)
35 )
36)
38)
39)
40 )
42 )
43 )
44)
45 )
46)
47)
48 )
49)
50 )
51)
52 )
55 )
56 )
57 )
58)
59 )
60 )
61)
62 )
64)
65)
66 )
67)
70)
71 )
72)
74)
75)
77)
78)
80)
81)
82)
83)
Bromochloromethane
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
1,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1,1, 1, 2-Tetrachloroethane
a-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
1,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
Bromobenzene
1,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
7.95
8.08
8.49
8.48
8.84
9.02
9.20
9.41
9.40
10.67
10.75
11.02
11.56
11. 46
11.54
12.15
12.20
12.51
13.04
13.49
13.43
13.69
13.77
14.13
14.19
14.54
14.87
15.23
15.60
15.69
16.56
16.64
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
'" 75
91
69
./ 75
97
43
76
164
129
107
91
112
131
, 91
104
17.17 1105
17.17 /173
17.46 83
17.67 110
17.77 53
17.81 156
17.98/105
17.99 91
18.22 91
7634153
1324328
20413861
23518150
6653730
15628519
25893131
11365083
40300728
14506722
24020327
12382542
1157460
16470371
6591393
1145481
26984608
19845427
33180219
10783432
15448853
8164134
19657270
14803633
12870055
10589428
8198474
21928281
26918289
13164312
30228683
27988312
31869976
5413530
9181142
2341835
2443783
14628874
25384132
26915833
60232
111.32 ug/l
109.73 ug/l
113.53 ug/l
125.43 ug/l
112.31 ug/l
110.57 ug/l
112.04 ug/l
112.91 ug/l
82.91 ug/l
111.38 ug/l
119.41 ug/l
109.50 ug/l
2365.79 ug/l
108.97 ug/l
113.49 ug/l
117.85 ug/l
521.47 ug/l
111.30 ug/l
63.33 ug/l
115.57 ug/l
113.76 ug/l
108.63 ug/l
524.96 ug/l
110.14 ug/l
112.06 ug/l
111.37 ug/l
111.50 ug/l
99.78 ug/l
79.87 ug/l
112.24 ug/l
64.12 ug/l
78.06 ug/l
52.78 ug/l
115.59 ug/l
109.10 ug/l
108.63 ug/l
111.62 ug/l
110.93 ug/l
51. 40 ug/l
54.72 ug/l
0.15 ug/l
Qvalue
100
93
99
97
100
98
98
99
85
99
98
99
98
99
99
96
94
98
71
99
99
99
94
97
99
97
99
91
77
100
60
68
56
99
99
98
98
99
60
48
87
(#) = qualifier out of range (m) = manual integration ~VL
REW257. D V006E15.M Tue May 16 13,12,40 2023 ~~ jr1 {n? Page 2
REPORT ID: 23E135 Page 99 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW257.D
Aeq On 15 May 2023 5:41 pm
Sample V006E1510
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
84) tert-Butylbenzene 18.43 ~134 12616522 106.44 ug/l
85) l,2,4-Trimethylbenzene 18.30 105 319789 0.66 ug/l
86) see-Butylbenzene 18.47 ~105 23894510 34.82 ug/l
88) l,3-Diehlorobenzene 18.94 '146 19689309 78.97 ug/l
89) 1, 2, 3-Trimethylbenzene 19.02 , 105 23282917 52.59 ug/l
90) l,4-Diehlorobenzene 19.07 .,146 19778680 79.12 ug/l
92) l,2-Diehlorobenzene 19.46 r 146 18117521 87.15 ug/l
93) l,2-Dibromo-3-ehloropropan 20.22 157 1508957 112.27 ug/l
94) l,2,4-Triehlorobenzene 21.05 180 13807083 101.23 ug/l
95) Hexaehlorobutadiene 21.18 / 225 8140789 96.95 ug/l
96) Naphthalene 21.33...--128 20074354 100.77 ug/l
97) l,2,3-Triehlorobenzene 21.57 180 10713848 102.20 ug/l
Qvalue
93
61
38
77
58
76
82
98
99
99
96
99
(#) = qualifier out of range (m) = manual integration
REW257. D V006E15.M Tue May 16 13: 12: 40 2023 h IA { .., Page 3 ~1\1'1r~ REPORT ID: 23E135 Page 100 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW257.D
Acq On 15 May 2023 5:41 pm
Sample V006E1510
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
Vial: 11
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
f-bundancej
! I
! 8.5e+07j
.,+07 1
7.5e+071
I
7e+07 1
6.5e+07 I
j
I
I
6e+07
1
!
5.5e+07 I
1
I
5e+07 I
j
I
4.5e+07 j
1
4e+071
3~~71
3e+071
1
i
2.5e+071'
2e+07 I
1.5e+07
1e+07
5000000
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW257.D
REW257.D V006E15.M Tue May 16 13:12:43 2023
REPORT ID: 23E135 Page 101 of 454
SECOND SOURCE
VERIFICATION
REPORT ID: 23E135 Page 102 of 454
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORM/IHCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratories, Inc.
Lab Code : EMAX
Lab File 10: REW261
Instrument 10: 06
Project : ICAL
SOG No : lCAL
BFB Injection Date: 05/16/23
BFB Injection Time: 11:11
I I % RELATIVE
I mle I ION ABUNDANCE CRITERIA ABUNDANCE
I 1================
I 50 I 15 . 40% of mass 95 16.428
I 75 I 30 . 60% of mass 95 I 42.584
I 95 I Base Peak, 100% relative abundance _____ 1 100.000
I 96 I 5 . 9% of mass 95 I 6.057
I 173 I Less than 2% of mass 174 I 0.000(0)1
I 174 I Greater than 50% of mass 95 I 73.102
I 175 I 5 . 9% of mass 174 I 5.425(7.42)1
I 176 I 95 . 101% % of mass 174 I 70.934(97.03)1
I 177 I 5 . 9% % of mass 176 I 4.437(6.26)2 I_I 1 ___ _
I-Value is % mass 174 2·Value is % mass 176
This check applies to the following Calibration Standards:
I EPA I LAB I LAB I DATE I TIME I
I SAMPLE NO. I SAMPLE ID I FILE ID I ANALYZED I ANALYZED I
1=====1====1===1 I I
11VST010 I IVOO6E1502 1REW262 I 05/16/23 I 12:17 I
I I I I I I
REPORT ID: 23E135 Page 103 of 454
CONTINUE_CALIBRATION -CALIBRATION VERIFICATION
Instrument 10 :06 IC Beginning DateTime :05/15/23 13:47 Spike Amount :10 PPB
Column Spec :RTX502.2 10 :0.25MM IC Ending DateTime :05/15/23 17:41
HPChem Method :VOO6E15 Date_Time :05/16/23 12:17 CCICV File :REW262 IC File :REW253
1M WAlI'arameters \.\.~onl\.\. .. _D \;\;_Kesp[{;('lOO"IAVMrl\.l.~ ~I~ \.o-"u OF ~o~l"o_\.or
1 l,4-DIFLUOROBENZENE 10.000 0 4163900 1 1 10.0B6 10.085 0 2Dlchlorodifluoromethane 9.5n -4.2 15946590.383 0.400 1.690 1.693 7.72 3 Chloromethane 10.075 0.7 18585520.4460.443 1.927 1.929 9.53 4 Vinyl chloride 9.883 -1.2 1773793 0.426 0.431 2.045 2.038 9.17 5 Bromomethane 9.987 -0.1 1475861 0.354 0.355 2.499 2.502 8.19 6 Chloroethane 10.009 0.1 1083934 0.260 0.260 2.598 2.599 8.16
7 Dichlorofluoromethane 10.285 2.9 2534516 0.609 0.592 2.638 2.638 7.59 8 Trichlorofluoromethane 9.404 -6.0 2008246 0.482 0.513 2.875 2.8n 6.20 5 9 Acrolein 48.753 -2.5 511684 0.025 0.025 3.405 3.396 8.86
10 1.1.2-Trichloro-1.2.2-trifluoroethane 9.854 -1.5 1137993 0.273 0.2n 3.447 3.448 7.94 5 11 Acetone 43.498 -13.0 684437 0.033 0.040 3.489 3.488 18.81 0.0075 0.0356
12 1.1·Dichloroethene 10.420 4.2 2392205 0.575 0.551 3.656 3.656 8.21 25 13 tert-Butyl alcohol 224.905 -10.0 1048289 0.010 0.011 3.824 3.813 10.70
14 Acetonitrile 15 Methyl acetate 16 Iodoiilethane 17 Methylene chloride 18 CarbOn disulfide 5 19 Acrylonitrile 20 tert-8utyl methYl ether (MTSE) 21 trans-1.2-Dichloroethene 22 Isopropyl ether (DIPE)
23 ViDYl acetate 24 1.1-Dichloroethane 25 25 2-Butanol 26 tert-Butyl ethyl ether (ETSE)
5 27 2-Butanone 28 2,2-Dichlonopropane 29 cls·1.2-Dichloroethene 30 Chloroform 5 31 tert-Amyl alcohol 32 Bromochloromethane 33 Tetrahydrofuran 34 Dibromofluoromethane 35 1.111-Trichloroethane 36 Cyc ohexane 37 2.2.4-Trimethylpentane 38 1.1-Dichloropropene 39 Carbon tetrachloride 40 tert-Amyl methyl ether (TAME)
41 1.2-Dichloroethane-d4 42 1.2-Dichloroethane 43 Benzene 44 Trichloroethene 45 Methylcyclohexane
46 1.2-Dichloropropane 20 47 1.4-Dioxane 48 Bromodichloromethane 49 Dibromomethane 50 2-Chloroethyl vinyl ether
5 51 4-MethYl-2-~ntanone 52 cis-1h~-Dichloropropene 53 CHLORuoENZENE-D5 54 Toluene-dB 55 Toluene 56 Ethyl methacrylate 57 trans-1.3-Dichloropropene
58 1.1.2-Trichloroethane
5 59 2 -Hexanone 60 1.3-Dichloropropane 61 Tetrachloroethene 62 Dibromochloromethane
632-EtbYl-1-butanol 64 1.2-Dlbromoethane
65 1-Chlorohexane 66 Chlorobenzene 67 1.1.162-Tetrachloroethane
68 EthYl enzene 2 69 m-Xvlene & p-Xylene
70 o-XYlene 71 Styrene 72 Isopropylbenzene 73 1.2-DICHLOROBENZENE-D4 74 Bromoform 75 1.1.2.2-Tetrachloroethane 76 4-Bromofluorobenzene n 1.2.3-Trichloropropane 78 trans-114-Dichloro-2-butene 79 n-Propy benzene
80 Bromobenzene 81 1.3L 5-Trimethylbenzene
82 2-Cnlorotoluene 83 4-Chlorotoluene 84 tert-Butylbenzene 85 1.2.4-Trlmethylbenzene 86 sec-Butyl benzene 87 p-IsQP.ropyltoluene 88 1.3-Dichlorobenzene
89 1.2.3-Trimethylbenzene 90 1.4-Dichlorobenzene 91 n-Butylbenzene
92 1.2-Dlchlorobenzene 93 1.2-Dibromo-3-chloropropane 94 1.2.4-Trichlorobenzene
95 Hexachlorobutadiene 96 Naphthalene
97 1.2.3-Trichlorobenzene
9.224 -7.8 103764 0.025 0.027 4.201 4.185 11.30
10.035 0.4 2524963 8:g~ 0.604 4.117 4.117 6.30
9.636 -3.6 1571212 0.392 4.390 4.395 9.47
11.908 19.1 6520813 1.566 1.315 4.369 4.368 18:~8 49.826 -0.3 941239 8:~g 0.045 4.641 4.641
9.717 -2.8 2185973 8:~g 4.704 4.687 9.58
10.2~1 2.8 1621838 0.389 4.914 ~:ro~ 6.64
10.0 1 0.9 4149215 0.996 0.988 5.605 6.43
9.727 -2.7 1237019 0.297 0.305 5.836 5.838 6.20
10.184 1.8 2614330 0.628 0.617 5.n3 5.752 6.83
9.870 -1.3 3357243 0.806 0.817 6.549 6.533 7.69
47.475 -5.0 1182225 0.057 0.060 6.821 ~:~1 7.25
10.761 7.6 1489974 0.358 0.333 7.093 7.69
10.164 1.6 1583162 0.380 0.374 7.198 7.196 7.69
9.874 -1.3 2479991 0.596 0.603 7.596 7.575 6.29
9.698 -3.0 771973 0.185 0.191 87 .. 950783 87 .. 905725 161.'2747 8.736 -12.6 122381 0.029 0.034 9.962 -0.4 1339712 0.322 0.323 8.099 8.099 7.49
9.559 -4.4 1995063 0.479 0.501 8.489 8.493 8.58 10.182 1.8 2216130 0.532 0.523 8.476 8.474 11.51
9.950 -0.5 684285 0.164 0.165 8.853 8.847 6.60 10.272 2.7 1685341 0.405 0.394 9.021 9.017 6.68 9.709 -2.9 2604562 0.626 0.644 9.203 9.200 7.31
99.'676410 _-32.'94 913150 0.219 0.225 9.216 9.216 8.16 1122894 0.270 0.281 9.424 9.414 6.90 10.190 1.9 5749673 1.381 1.355 9.398 9.398 5.93 10.078 0.8 1523705 0.366 0.363 10.670 10.663 6.58 10.906 9.1 25465530.6120.561 10.748 10.745 11.23 9.982 -0.2 1310301 0.315 0.315 11.021 11.023 6.21
174.464 -12.8 99083 0.001 0.001 11.566 11.569 11.84 9.708 -2.9 17032200.409 0.421 11.462 11.462 6.64 9.607 -3.9 647747 0.156 0.162 11.540 11.539 7.09 9.011 -9.9 101667 0.024 0.027 12.150 12.154 11.55 48.910 -2.2 2937939 0.141 0.144 12.202 12.209 11.05 10.148 1.5 2100341 0.504 0.497 12.513 12.513 7.27
10.000 0 3625488 1 1 15.538 15.537 0 10.498 5.0 4942467 1.363 1.299 12.916 12.915 7.13 10.521 5.2 62277251.7181.63313.05913.057 8.62 9.518 -4.8 1003286 0.277 0.291 13.487 13.489 9.34 9.998 -0.0 1533970 0.423 0.423 13.435 13.434 7.62 9.311 -6.9 790536 0.218 0.234 13.695 13.689 6.47 47.476 ·5.0 2008417 0.111 0.117 13.772 13.770 9.00 9.661 -3.4 14670980.405 0.419 14.136 14.135 6.36 10.361 3.6 1344362 0.371 0.358 14.188 14.187 7.39 9.617 -3.8 10330570.285 0.296 14.538 14.538 6.12
9.772 -2.3 8118090.2240.22914.87614.879
10.663 6.6 2647411 0.730 0.685 15.226 15.226 10.274 2.7 3911993 1.079 1.050 15.603 15.602 9.958 -0.4 1319527 0.364 0.365 15.694 15.693 10.251 2.5 73261232.0211.97115.70715.710 21.084 5.4 11002997 1.517 1.439 15.836 15.836 10.103 1.0 5380834 1.484 1.469 16.563 16.568
10.117 1.24 ~L09~79n84 1.130 1.117 16.628 16.634
18:aa3 2'a 1.9211.88~ Km 1~:U~
9.569 -4.3 0.351 0.367 17.173 17.174 9.987 -0.1 902086 0.659 0.660 17.446 17.451 10.376 3.8 1607771 1.175 1.132 17.550 17.549
9.337 -6.6 216034 0.158 0.169 17.667 17.665 9.507 -4.9 2233950.1630.172 17.771 17.770
10.850 8.5 888.9926 6.494 5.985 17.771 17.770 10.233 2.3 1 1 1.058 1.034 17.809 17.809 10.508 5.1 55 4.0693.872 17.978 17.978
10.684 6.8 5 4.120 3.856 17.991 17.991 10.410 4.1 434 3.1733.048 18.056 18.056 10.516 5.2 1337846 0.977 0.929 18.433 18.432 10.364 3.6 5424992 3.963 3.824 18.472 18.471 10.660 6.6 78513815.7365.381 18.679 18.679 10.637 6.4 6116783 4.468 4.201 18.835 18.835
10.497 5.0 2809205 2.052 1.955 18.939 18.938 10.194 1.9 4844060 3.539 3.471 19.017 19.016
10.345 3.5 2775669 2.028 1.960 19.056 19.055 10.958 9.6 5967378 4.359 3.978 19.276 19.276 10.155 1.5 2265912 1.655 1.630 19.445 19.446 8.960 -10.4 129253 0.094 0.105 20.224 20.221
10.336 3.4 1513149 1.105 1.069 21.055 21.054
11.128 11.3 10029120.733 0.658 21.184 21.184 9.920 ·0.8 2120891 1.549 1.562 21.327 21.327 10.276 2.8 1156229 0.845 0.822 21.574 21.575
7.06 6.27 6.31 6.91 5.72 8.96 5.46
5.99 6.28
8.04 7.66 7.49 6.04 6.85 9.51 6.90 6.52
6.44
5.83 8.15
6.65 9.56 7.45 7.54 6.31
6.69 7.80
8.54 8.34 9.93
9.35 5.97
7.45
0.9975
Sp'i1<e1IJi1O"'un"'l:'='"""OtNo""mffim""an-l-rMQffiinru"'nl:...---A'1I"1IMr-----I ----------------------------
REPORT ID: 23E135 Page 104 of 454
BFB
Data File D:\HPCHEM\1\DATA\23E16\REW261.D Vial: 1
Acq On 16 May 2023 11:11 am Operator: LYamas
Sample BFB06E12 Inst 06
Misc T/CHK Multiplr: 1.00
MS Integration Params: RTE.P
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title : METHOD 8260
f'\blJfOWffij, TIC: REW261.D
600000
500000
400000
300000
I 200000
I I 100000
0
!rime--> 16.00 16.50 17.00 d50 18~00 18~50 19.00
I
~bundance Average of 17.523 to 17.549 min.: REW261.D (-)
95
120000
100000 174
80000
60000 75
40000
20000 50
37
44 .1 I ~11 6~ .11 It 81 8~ l~ 128 135 141 0 ,II III 104109 117 I
rn/z--> 3D 4'0 50 6'0 70 8'0 90 100 110 120 130 140 150 160 170 180
AutoFind: Scans 1111, 1112, 1113; Background Corrected with Scan 1106
I Target I ReI. to I L~w~r
Mass Mass Llmlt%
50
75
95
96
173
174
175
176
177
95
95
95
95
174
95
174
174
176
REW261.D V006E15.M
15
30
100
5
0.00
50
5
95
5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
ReI.
Abn%
16.4
42.6
100.0
6.1
0.0
73.1
7.4
97.0
6.3
Raw
Abn
21160
54849
128803
7802
o
94157
6988
91365
5715
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 23E135 Page 105 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Dich1orodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M 1,1,2-Trichloro-1,2 /2-trifl
11 T,M Acetone
12 C,T,M 1,1-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M 1,1-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2 /2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T/M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M 1 ,1,1-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M 1 /1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
Amount Calc.
10.000 10.000
10.000 9.577
10.000 10.075
10.000 9.883
10.000 9.987
10.000 10.009
10.000 10.285
10.000 9.404
50.000 48.753
10.000 9.854
50.000 43.498
10.000 10.420
250.000 224.905
-1.000 0.000
10.000 9.224
10.000 10.035
10.000 9.636
10.000 11.908
50.000 49.826
10.000 9.717
10.000 10.281
10.000 10.091
10.000 9.727
10.000 10.184
250.000 0.000
10.000 9.870
50.000 47.475
10.000 10.761
10.000 10.164
10.000 9.874
50.000 0.000
10.000 9.698
10.000 8.736
10.000 9.962
10.000 9.559
10.000 10.182
10.000 0.000
10.000 9.950
10.000 10.272
10.000 9.709
10.000 9.764
%Dev Area% Dev(min)
0.0
4.2
-0.7
1.2
0.1
-0.1
-2.9
6.0
2.5
1.5
13.0
-4.2
10.0
0.0
7.8
-0.4
3.6
-19.1
0.3
2.8
-2.8
-0.9
2.7
-1.8
100.0#
1.3
5.0
-7.6
-1.6
i.3
100.0#
3.0
12.6
0.4
4.4
-1. 8
100.0#
0.5
-2.7
2.9
2.4
99
97
98
97
98
99
113
96
112
113
102
113
99
o
109
111
110
122
108
103
113
111
100
113
o
109
109
113
111
110
o
108
102
103
112
112
o
110
117
106
100
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.02
0.00
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.02
0.00
0.02
0.00
0.02
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
(#) = Out of Range
REW262.D V006E15.M Tue May l6 13: Ol: 04 2023 71/rJ~ Page 1
REPORT ID: 23E135 Page 106 of 454
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 1,2-Dichloroethane 10.000 9.610 3.9 105 0.01
T,M Benzene 10.000 10.190 -1. 9 111 0.00
T,M Trichloroethene 10.000 10.078 -0.8 111 0.00
T,M Methylcyclohexane 10.000 10.906 -9.1 122 0.00
C,T,M 1,2-Dichloropropane 10.000 9.982 0.2 111 0.00
T,M 1,4-Dioxane 200.000 174.464 12.8 105 -0.01
T,M Bromodichloromethane 10.000 9.708 2.9 110 0.00
T,M Dibromomethane 10.000 9.607 3.9 105 0.00
T,M 2-Chloroethyl vinyl ether 10.000 9.011 9.9 96 0.00
T,M 4-Methyl-2-pentanone 50.000 48.910 2.2 106 0.00
T,M cis-1,3-Dichloropropene 10.000 10.148 -1. 5 110 0.00
I CHLOROBENZENE-D5 10.000 10.000 0.0 98 0.00
S Toluene-d8 10.000 10.498 -5.0 105 0.00
C,T,M Toluene 10.000 10.521 -5.2 113 0.01
T,M Ethyl methacrylate 10.000 9.518 4.8 103 0.00
T,M trans-1,3-Dichloropropene 10.000 9.998 0.0 107 0.00
T,M 1,1,2-Trichloroethane 10.000 9.311 6.9 105 0.00
T,M 2-Hexanone 50.000 47.476 5.0 108 0.00
T,M 1,3-Dichloropropane 10.000 9.661 3.4 103 0.00
T,M Tetrachloroethene 10.000 10.361 -3.6 111 0.00
T,M Dibromochloromethane 10.000 9.617 3.8 104 0.00
T,M 2-Ethyl-1-butanol -1.000 0.000 0.0 0 0.00
T,M 1,2-Dibromoethane 10.000 9.772 2.3 106 0.00
T,M 1-Chlorohexane 10.000 10.663 -6.6 113 0.00
P, T,M Chlorobenzene 10.000 10.274 -2.7 110 0.00
T,M 1,1,1,2-Tetrachloroethane 10.000 9.958 0.4 109 0.00
C,T,M Ethylbenzene 10.000 10.251 -2.5 113 0.00
T,M m-Xylene & p-Xylene 20.000 21.084 -5.4 112 0.00
T,M o-Xylene 10.000 10.103 -1. 0 111 0.00
T,M Styrene 10.000 10.117 -1. 2 110 0.00
T,M Isopropylbenzene 10.000 10.224 -2.2 113 0.00
I 1,2-DICHLOROBENZENE-D4 10.000 10.000 0.0 96 0.00
P,T,M Bromoform 10.000 9.569 4.3 103 0.00
P,T,M 1, 1, 2, 2-Tetrachloroethane 10.000 9.987 0.1 106 0.00
S 4-Bromofluorobenzene 10.000 10.376 -3.8 103 0.00
T,M 1, 2, 3-Trichloropropane 10.000 9.337 6.6 100 0.00
T,M trans-1,4-Dichloro-2-butene 10.000 9.507 4.9 104 0.00
T,M n-Propylbenzene 10.000 10.850 -8.5 114 0.00
T,M Bromobenzene 10.000 10.233 -2.3 110 0.00
(#) = Out of Range
REW262.D V006E15.M Tue May 16 13:01:04 2023 3>fI\1 \ v 6
Page 2
REPORT ID: 23E135 Page 107 of 454
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 1, 3, 5-Trimethylbenzene 10.000 10.508 -5.1 113 0.00
T,M 2-Chlorotoluene 10.000 10.684 -6.8 112 0.00
T,M 4-Chlorotoluene 10.000 10.410 -4.1 112 0.00
T,M tert-Butylbenzene 10.000 10.516 -5.2 113 0.00
T,M 11 2 ,4-Trimethylbenzene 10.000 10.364 -3.6 113 0.00
T,M sec-Butylbenzene 10.000 10.660 -6.6 114 0.00
T,M p-Isopropyltoluene 10.000 10.637 -6.4 114 0.00
T,M 1,3-Dichlorobenzene 10.000 10.497 -5.0 111 0.00
T,M l,2,3-Trimethylbenzene 10.000 10.194 -1. 9 110 0.00
T,M l,4-Dichlorobenzene 10.000 10.345 -3.5 109 0.00
T,M n-Butylbenzene 10.000 10.958 -9.6 118 0.00
T,M l,2-Dichlorobenzene 10.000 10.155 -1. 5 107 0.00
T,M l,2-Dibromo-3-chloropropane 10.000 8.960 10.4 100 0.00
T,M l,2,4-Trichlorobenzene 10.000 10.336 -3.4 111 0.00
T,M Hexachlorobutadiene 10.000 11.128 -11.3 116 0.00
T,M Naphthalene 10.000 9.920 0.8 104 0.00
T,M l,2,3-Trichlorobenzene 10.000 10.276 -2.8 108 0.00
_________________________________________________________ ~~_~lJ{~? _____ _
(#) = Out of Range
REW262.D V006E15.M
SPCC's out = a CCC's out = a
Tue May 16 13:01:05 2023 Page 3
REPORT ID: 23E135 Page 108 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I 1 /4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P/T/M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M 1 /1 /2-Trichloro-1 /2,2-trifl
11 T,M Acetone
12 C,T,M 1 /1-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1 /2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P/T/M 1 /1-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2 /2-Dichloropropane
29 T,M cis-1 /2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M lil,I-Trichloroethane
36 T,M Cyclohexane
37 T,M 2 /2 /4-Trimethylpentane
38 T,M 1 /1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
AvgRF CCRF
1. 000 1. 000
0.400 0.383
0.443/ 0.446
0.431 0.426
0.355 0.354
0.260 0.260
0.592 0.609
0.513 0.482
0.025 0.025
0.277 0.273
0.040 ""0.033
0.551 0.575
0.011 0.010
0.000 0.000
0.027 0.025
0.604 0.606
0.392 0.377
1. 315 1. 566
0.045 0.045
0.540 0.525
0.379 0.389
0.988 0.996
0.305 0.297
0.617 ,/' 0.628
0.000 0.010
0.817 0.806
0.060 ---0.057
0.333 0.358
0.374 0.380
0.603 0.596
0.000 0.001
0.191 0.185
0.034 0.029
0.323 0.322
0.501 0.479
0.523 0.532
0.000 0.025
0.165 0.164
0.394 0.405
0.644 0.626
0.225 0.219
(#) = Out of Range
REW262.D V006E1S.M Tue May 16 13:01:09 2023
%Dev Area% Dev(min)
0.0
4.3
-0.7
1.2
0.3
0.0
-2.9
6.0
0.0
1.4
17.5
-4.4
9.1
0.0
7.4
-0.3
3.8
-19.1
0.0
2.8
-2.6
-0.8
2.6
-1. 8
0.0
1.3
5.0
-7.5
-1.6
1.2
0.0
3.1
14.7
0.3
4.4
-1. 7
0.0
0.6
-2.8
2.8
2.7
99
97
98
97
98
99
113
96
112
113
102
113
99
0#
109
III
110
122
108
103
113
III
100
113
0#
109
109
113
III
110
0#
108
102
103
112
112
0#
110
117
106
100
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.02
0.00
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.02
0.00
0.02
0.00
'0.02
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
REPORT ID: 23E135 Page 109 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M 1,2-Dichloroethane
43 T,M Benzene
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M 1,2-Dichloropropane
47 T,M 1,4-Dioxane
48 T,M Bromodichloromethane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I
54 S
CHLOROBENZENE-D5
Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M 1, 1, 2-Trichloroethane
59 T,M 2-Hexanone
60 T,M 1,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 2-Ethyl-l-butanol
64 T,M 1,2-Dibromoethane
65 T,M 1-Chlorohexane
66 P, T,M Chlorobenzene
67 T,M 1, 1, 1, 2-Tetrachloroethane
68 C,T/M Ethylbenzene
69 T,M m-Xylene & p-Xylene
70 T,M o-Xylene
71 T,M Styrene
72 T,M Isopropylbenzene
73 I 1,2-DICHLOROBENZENE-D4
74 P,T,M Bromoform
75 P,T,M 1, 1, 2 1 2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1 1 2 1 3-Trichloropropane
78 T,M trans-1 1 4-Dichloro-2-butene
79 T,M n-Propylbenzene
80 T,M Bromobenzene
AvgRF
0.281
1.355
0.363
0.561
0.315
0.001
0.421
0.162
0.027
0.144
0.497
CCRF
0.270
1. 381
0.366
0.612
0.315
0.001
0.409
0.156
0.024
0.141
0.504
1. 000 1. 000
1.299 1.363
1. 633 1. 718
0.291 0.277
0.423 0.423
0.234 0.218
0.117 0.111
0.419 0.405
0.358 0.371
0.296 0.285
0.000 0.000
0.229 0.224
0.685 0.730
1.050....--1.079
0.365 0.364
1.971 2.021
1.439 1.517
1.469 1.484
1.117 1.130
1.882 1.924
1.000
0.367
0.660
1.132
0.169
0.172
5.985
1.034
1.000
<'" 0.351
0.659
4.. .175
0.158
0.163
6.494
1. 058
(#) = Out of Range
REW262.D V006E15.M Tue May 16 13:01:11 2023
%Dev Area% Dev(min)
3.9
-1. 9
-0.8
-9.1
0.0
0.0
2.9
3.7
11.1
2.1
-1. 4
105
111
111
122
111
105
110
105
96
106
110
0.0 98
-4.9 105
-5.2 113
4.8 103
0.0 107
6.8 105
5.1 108
3.3 103
-3.6 111
3.7 104
0.0 0#
2.2 106
-6.6 113
-2.8 110
0.3 109
-2.5 113
-5.4 112
-1. 0 111
-1.2 110
-2.2 113
0.0
4.4
0.2
-3.8
6.5
5.2
-8.5
-2.3
96
103
106
103
100
104
114
110
0.01
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
~jn (1-3 Page 2
I REPORT ID: 23E135 Page 110 of 454
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D Vial: 2
Operator: Aeq On 16 May 2023 12:17 pm
Sample IV006E1502
LYamas
06
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M l,3,5-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.856
T,M 4-Chlorotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M l,2,4-Trimethylbenzene 3.824
T,M see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
T,M l,3-Diehlorobenzene 1.955
T,M l,2,3-Trimethylbenzene 3.471
T,M l,4-Diehlorobenzene 1.960
T,M n-Butylbenzene 3.978
T,M l,2-Diehlorobenzene 1. 630
T,M l,2-Dibromo-3-ehloropropane 0.105
T,M 1, 2, 4-Triehlorobenzene 1.069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1.562
T,M l,2,3-Triehlorobenzene 0.822
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
4.069 -5.1 113 0.00
4.120 -6.8 112 0.00
3.173 -4.1 112 0.00
0.977 -5.2 113 0.00
3.963 -3.6 113 0.00
5.736 -6.6 114 0.00
4.468 -6.4 114 0.00
2.052 -5.0 111 0.00
3.539 -2.0 110 0.00
2.028 -3.5 109 0.00
4.359 -9.6 118 0.00
1. 655 -1. 5 107 0.00
0.094 10.5 100 0.00
1.105 -3.4 111 0.00
0.733 -11.4 116 0.00
1.549 0.8 104 0.00
0.845 -2.8 108 0.00
<5 v, 5/(7('13
----~------------------------------=----~--------------------------------~
(#) = Out of Range
REW262.D V006E15.M
SPCC's out = 0 CCC's out = 0
Tue May 16 13:01:12 2023 Page 3
REPORT ID: 23E135 Page 111 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 12:44 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.09 114 4163900 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 15.54 117 3625488 10.00 ug/l 0.00
73) l,2-DICHLOROBENZENE-D4 19.42 152 1368873 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 8.10 111 1339712 9.96 ug/l 0.00
Spiked Amount 10.000 Recovery = 99.60%
41) l,2-Dichloroethane-d4 9.22 65 913150 9.76 ug/l 0.00
Spiked Amount 10.000 Recovery = 97.60%
54) Toluene-d8 12.92 98 4942467 10.50 ug/l 0.00
Spiked Amount 10.000 Recovery = 105.00%
76) 4-Bromofluorobenzene 17.55 95 1607771 10.38 ug/l 0.00
Spiked Amount 10.000 Recovery = 103.80%
Target Compounds Qvalue
2) Dichlorodifluoromethane 1. 69 85 1594659 9.58 ug/l 98
3) Chloromethane 1. 93 50 1858552 10.08 ug/l 98
4) Vinyl chloride 2.05 62 1773793 9.88 ug/l 98
5) Bromomethane 2.50 94 1475861 9.99 ug/l 100
6} Chloroethane 2.60 64 1083934 10.01 ug/l 99
7) Dichlorofluoromethane 2.64 67 2534516 10.28 ug/l 100
8} Trichlorofluoromethane 2.87 101 2008246 9.40 ug/l 98
9} Acrolein 3.40 56 511684 48.75 ug/l 99
10 } l,l,2-Trichloro-1,2,2-trif 3.45 151 1137993 9.85 ug/l 99
11} Acetone 3.49 43 684437 43.50 ug/l 98
12} l,l-Dichloroethene 3.66 /61 2392205 10.42 ug/l 99
13) tert-Butyl alcohol 3.82 59 1048289 224.90 ug/l 100
15) Methyl acetate 4.20 74 103764 9.22 ug/l 99
16} Iodomethane 4.12 142 2524963 10.03 ug/l 99
17} Methylene chloride 4.39 49 1571212 9.64 ug/l 99
18) Carbon disulfide 4.37 76 6520813 11.91 ug/l 100
19) Acrylonitrile 4.64 53 941239 49.83 ug/l 98
20 } tert-Butyl methyl ether (M 4.70 73 2185973 9.72 ug/l 98
21) trans-1,2-Dichloroethene 4.91 (96 1621838 10.28 ug/l 100
22) Isopropyl ether (DIPE) 5.61 45 4149215 10.09 ug/l 100
23} Vinyl acetate 5.84 43 1237019 9.73 ug/l 98
24} l,l-Dichloroethane 5.77 63 2614330 10.18 ug/l 99
(' 26) tert-Butyl ethyl ether {ET 6.55 59 3357243 9.87 ug/l 98
27 } 2-Butanone 6.82 43 1182225 47.47 ug/l 97
28 } 2,2-Dichloropropane 7.09 77 1489974 10.76 ug/l 99
29} cis-1,2-Dichloroethene 7.20 96 1583162 10.16 ug/l 100
30} Chloroform 7.60 /83 2479991 9.87 ug/l 100
(#) = qualifier out of range (m) = manual integration 5
REW262.D V006E1S.M Tue May 16 13,01,20 2023 . ~\1\V~ Page 1
REPORT ID: 23E135 Page 112 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 12:44 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32)
33)
35 )
36)
38)
39 )
40 )
42 )
43)
44)
45 )
46)
47)
48 )
49 )
50)
51 )
52)
55)
56)
57)
58)
59 )
60)
61 )
62)
64)
65)
66)
67)
68)
69)
70)
71)
72)
74)
75)
77 )
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
l,l,l-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
l,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-l,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
l-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.95
8.08
8.49
8.48
8.85
9.02
9.20
9.42
9.40
10.67
10.75
11.02
11.57
11.46
11.54
12.15
12.20
12.51
13.06
13.49
13.43
13.69
13.77
14.14
14.19
14.54
14.88
15.23
15.60
15.69
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
75 ..-91
69
/' 75
, 97
43
76
164
129
107
# 91
112
131
91
91
91
15.71 ./
15.84 ,/
16.56 j
16.63
17.17
104
" 105
17.17
17.45
17.67
17.77
17.77
17.81
J
173
./ 83
110
53
91
156
771973
122381
1995063
2216130
684285
1685341
2604562
1122894
5749673
1523705
2546553
1310301
99083
1703220
647747
101667
2937939
2100341
6227725
1003286
1533970
790536
2008417
1467098
1344362
1033057
811809
2647411
3911993
1319527
7326123
11002997
5380834
4097984
6974011
480992
902086
216034
223395
8889926
1448441
9.70 ug/l
8.74 ug/l
9.56 ug/l
10.18 ug/l
9.95 ug/l
10.27 ug/l
9.71 ug/l
9.61 ug/l
10.19 ug/l
10.08 ug/l
10.91 ug/l
9.98 ug/l
174.46 ug/l
9.71 ug/l
9.61 ug/l
9.01 ug/l
48.91 ug/l
10.15 ug/l
10.52 ug/l
9.52 ug/l
10.00 ug/l
9.31 ug/l
47.48 ug/l
9.66 ug/l
10.36 ug/l
9.62 ug/l
9.77 ug/l
10.66 ug/l
10.27 ug/l
9.96 ug/l
10.25 ug/l
21.08 ug/l
10.10 ug/l
10.12 ug/l
10.22 ug/l
9.57 ug/l
9.99 ug/l
9.34 ug/l
9.51 ug/l
10.85 ug/l
10.23 ug/l
Qvalue
100
97
100
90
99
97
99
99
100
99
98
99
94
99
98
99
99
99
100
100
98
99
99
98
99
100
100
100
100
100
99
99
100
99
99
99
98
100
97
100
99
---------------------------------------------------------;:--------------
(#) = qualif.ier out of range (m) = manual integration :;'~1(~1
REW262.D V006E15.M Tue May 16 13:01:21 2023 2J It Page 2
REPORT ID: 23E135 Page 113 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 12:44 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
81) l,3,5-Trimethylbenzene 17.98 105 5569834 10.51 ug/l
82) 2-Chlorotoluene 17.99 91 5640189 10.68 ug/l
83) 4-Chlorotoluene 18.06 91 4343425 10.41 ug/l
84) tert-Butylbenzene 18.43 134 1337846 10.52 ug/l
85) 1,2,4-Trimethylbenzene 18.47 105 5424992 10.36 ug/l
86) see-Butylbenzene 18.68 105 7851381 10.66 ug/l
87) p-Isopropyltoluene 18.83 119 6116783 10.64 ug/l
88) 1,3-Diehlorobenzene 18.94 146 2809205 10.50 ug/l
89) 1,2,3-Trimethylbenzene 19.02 105 4844060 10.19 ug/l
90) 1,4-Diehlorobenzene 19.06 146 2775669 10.35 ug/l
91) n-Butylbenzene 19.28 91 5967378 10.96 ug/l
92) 1,2-Dichlorobenzene 19.45 146 2265912 10.16 ug/l
93) 1,2-Dibromo-3-chloropropan 20.22 157 129253 8.96 ug/l
94) 1, 2, 4-Trichlorobenzene 21. 05 180 1513149 10.34 ug/l
95 ) Hexachlorobutadiene 21.18 225 1002912 11.13 ug/l
96 ) Naphthalene 21.33 128 2120891 9.92 ug/l
97 ) 1,2,3-Trichlorobenzene 21.57 180 1156229 10.28 ug/l
Qvalue
99
99
99
99
99
100
100
99
100
99
99
100
95
99
99
100
98
REPORT ID: 23E135 Page 114 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Aeq On 16 May 2023 12:17 pm
Sample IV006E1502
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 16 12:44 2023
TBA
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
(RTE Integrator)
Last Update
Response via
fA.bundance
I 1.2e+07j
! 1.15e+07i ; I
1.1e+071
1.05e+071
1e+07!
I
95000001
i
90000001
85000001
8000000
75000001
I
70000001
6500000
6000000
55000001
i
50000001
I
4500000i
I
40000001
i
3500000 1
i
30000001
i
2500000
2000000
15000001
!
10000001
500000j
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW262.D
t-o
Q)
C.
III
~ime~--~> ______ ~2~.~00~ __ ~4.~00~ __ ~6~.0~0 ____ ~8~.0~0~ __ ~10~.~00~ __ ~1~2.~00~ __ ~1~4.~00~ __ ~1~6~.0~0 __ ~1~8~.0~0 __ ~2~0~.0~0 ____ ~
REW262.D V006E15.M Tue May 16 13:01:24 2023 Page 4
REPORT ID: 23E135 Page 115 of 454
DAILY CALIBRATIONS
REPORT ID: 23E135 Page 116 of 454
1
2
3
4
5
6
7
8
9
10
11
12
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratories, Inc.
Lab Code : EMAX
Project : TEAD-S
SDG No : 23E135
BFB Injection Date: 05/19/23
BFB Injection Time: 06:15
Lab File ID: REW341
Instrument ID: 06
m/e
50
75
95
96
173
174
175
176
177
ION ABUNDANCE CRITERIA
~~ = ~g~ ~~ ~:~~ ~~----------------------
Base Peak, 100% relatlve abundance ____ _
~e~s 9~h~~ ;~s~f 9~~a~s~s,-,1~7~4<_~~_::_----~~~~~~~~~~-
~r=a~~roih~~s~0~7~f mass 95 ____________ _
~5_ -9~0~%O~ ~~S~ai~6174-----------------
I-value 18 % mass 174 2-value 18 % mass 176
o RELATIVE
ABUNDANCE
17.000
42.173
100.000
6.740
0.000(0)1
72.809
5.056(6.94)1
69.591(95.58)1
4.569(6.57)2
This check applies to the following samples, Lab QCs and Standards:
I EPA
LAB LAB DATE TIME
SAMPLE NO. SAMPLE ID FILE ID ANALYZED ANALYZED
====================== ================ ============ ========== ==========
VSTD10 CV006E1504 REW342 05/19/23 06 40
LCSIW V006E16L REW343 05/19/23 07 06
LCDIW V006E16C REW344 05/19/23 07 32
MBLKIW V006E16B REW346 05/19/23 08 24
TB-20230517-26 23E135-05 REW354 05/19/23 11 52
S-150-20-052023 23E135-01 REW355 05/19/23 12 18
S-38-90-052023 23E135-02 REW356 05/19/23 12 44
S-40-90-05-2023D 23E135-03 REW357 05/19/23 13 11
S-40-90-052023 23E135-04 REW358 05/19/23 13 37
S-150-20-052023MS 23E135-01M REW362 05/19/23 15 21
S-150-20-052023MSD 23E135-01S REW363 05/19/23 15 47
VSTDI0 EV006E1504 REW366 05/19/23 17 06
REPORT ID: 23E135 Page 117 of 454
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name: EMAX Laboratories, Inc.
Lab Code: EMAX
Lab File ID: REW253
Instrument ID: 06
1,4 DIFLUOROBENZENE
I
INTERNAL STANDARD (IS)
Area # RT #
1
2
3
4
5
6
7
8
9
10
11
12
========================
I 0~P~~U~I~i~
LOWER LIMIT
4201521
8403042
2100761
Area #
10.08
10.25
9.913
RT #
======================== =============== ==============
VSTD10 4523242
LCS1W 4578750
LCD1W 4574420
MBLK1W 4723109
TB-20230517-26 4475901
S-150-20-052023 4262091
S-38-90-052023 4373748
S-40-90-05-2023D 4281733
S-40-90-052023 4378503
S-150-20-052023MS 4297046
S-150-20-052023MSD 4234988
VSTD10 4150024
Area Upper Limit = +100% of leAL Midpoint IS Area
Area Lower Limit = -50% of ICAL Midpoint IS Area
10.09
10.09
10.09
10.08
10.09
10.09
10.09
10.09
10.09
10.09
10.09
10.09
CHLOROBENZENE-D5
Area # RT #
3710147
7420294
1855074
Area #
===============
3796294
3880881
3839325
3991940
3778943
3578694
3708267
3614076
3647970
3690536
3667173
3622748
15.54
15.71
15.37
RT #
==============
15.54
15.54
15.54
15.54
15.54
15.54
15.54
15.54
15.54
15.54
15.54
15.54
Retention Time (RT) Upper Limit +10 seconds of leAL Midpoint IS RT
Retention Time(RT) Lower Limit = -10 seconds of ICAL Midpoint IS RT
Project: TEAD-S
SDG No: 23E135
Date Analyzed: 05/15/23
Time Analyzed: 15:57
1432830
2865660
716415
Area #
19.42
19.59
19.25
RT #
=============== ==============
1426922 19.43
1521733 19.42
1501839 19.42
1481012 19.42
1388370 19.42
1328944 19.42
1367735 19.42
1321829 19.42
1336969 19.42
1475135 19.42
1484406 19.42
1425571 19.42
REPORT ID: 23E135 Page 118 of 454
BFB
Data File D:\HPCHEM\1\DATA\23E19\REW341.D
Acq On 19 May 2023 6:15 am
Sample BFB06E16
Misc T/CHK
MS Integration Params: RTE.P
Vial: 1
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title : METHOD 8260
Abundance , I
500000
400000
300000
200000
100000
rrime-->
f-bundance
100000
80000
60000
40000
16.00
20000 50
TIC: REW341.D
11
i! ;
16.50 17.00 17.50 18.00
75
Average of 17.537 to 17.563 min.: REW341.D (-)
95
19.00
174
80 90 100 110 120 130 140 150 160 170 180 190 200 210
AutoFind: Scans 1112, 1113, 1114; Background Corrected with Scan 1107
I Target I ReI. to I L~w~r
Mass Mass Llmlt%
50
75
95
96
173
174
175
176
177
95
95
95
95
174
95
174
174
176
15
30
100
5
0.00
50
5
95
5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
ReI.
Abn%
17.0
42.2/
100.0
6.7
0.0/
72.8
6.9/
95.6;-
6.6
REW341.D V006E15.M Fri May 19 09;54;53 2023
Raw
Abn
16820
41728
98944
6669
o
72040
5003
68856
4521
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 23E135 Page 119 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Acq On 19 May 2023 6:40 am
Sample CV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration ~
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
1 -~----~~~=~~;~~;;;~~~~~~~----------~~~--~~~~~~-------~~~--~~~---~~~~---
2 T,M Dichlorodifluoromethane 10.000 9.365 6.3 103 0.02
3 P/T/M Chloromethane 10.000 10.205 -2.1 108 0.02
4 C,T,M Vinyl chloride 10.000 9.442~ 5.6 100 0.00
5 T,M Bromomethane 10.000 9.511 4.9 101 0.02
6 T,M Chloroethane 10.000 9.472 5.3 102 0.02
7 T,M Dichlorofluoromethane 10.000 10.477 -4.8 125 0.02
8 T,M Trichlorofluoromethane 10.000 9.434 5.7 105 0.02
9 T,M Acrolein 50.000 43.303 13.4 109 0.00
10 T,M 1,1,2-Trichloro-1,2,2-trifl 10.000 9.561 4.4 119 0.02
11 T,M Acetone 50.000 43.780 12.4 112 0.02
12 C,T,M 1,1-Dichloroethene 10.000 10.346 -3.5 122 0.00
13 T,M tert-Butyl alcohol 250.000 213.678 ~ 14.5 102 0.02
14 T,M Acetonitrile -1.000 0.000 0.0 0 0.00
15 T,M Methyl acetate 10.000 8.677 13.2 112 0.02
16 T,M Iodomethane 10.000 9.842 1.6 118 -0.02
17 T,M Methylene chloride 10.000 10.148 -1.5 126 0.00
18 T,M Carbon disulfide 10.000 10.161 -1.6 113 0.02
19 T,M Acrylonitrile 50.000 47.524 5.0 112 0.00
20 T,M tert-Butyl methyl ether (MT 10.000 9.509 4.9 109 0.02
21 T,M trans-1 /2-Dichloroethene 10.000 10.453 -4.5 124 0.02
22 T,M Isopropyl ether (DIPE) 10.000 10.374 -3.7 124 0.00
23 T,M Vinyl acetate 10.000 9.818 1.8 110 0.02
24 P/T/M 1 /1-Dichloroethane 10.000 10.404 -4.0 125 0.02
25 T,M 2-Butanol 250.000 0.000 100.0# 0 0.00
26 T,M tert-Butyl ethyl ether (ETB 10.000 10.137 -1.4 121 0.02
27 T,M 2-Butanone 50.000 44.973 10.1 112 0.02
28 T,M 2,2-Dichloropropane 10.000 11.288 -12.9 129 0.00
29 T,M cis-1 /2-Dichloroethene 10.000 10.384 -3.8 124 0.00
30 C,T,M Chloroform 10.000 10.246 ~ -2.5 124 0.02
31 T,M tert-Amyl alcohol 50.000 0.000 100.0# 0 0.00
32 T,M Bromochloromethane 10.000 9.718 2.8 117 0.00
33 T,M Tetrahydrofuran 10.000 8.692 13.1 111 0.00
34 S Dibromofluoromethane 10.000 10.173 -1.7 114 0.00
35 T,M 1 /1 /1-Trichloroethane 10.000 9.787 2.1 124 0.01
36 T,M Cyclohexane 10.000 11.183 -11.8 134 0.00
37 T,M 2 /2,4-Trimethylpentane 10.000 0.000 100.0# 0 0.01
38 T,M 1 /1-Dichloropropene 10.000 10.345 -3.5 124 0.00
39 T,M Carbon tetrachloride 10.000 10.561 -5.6 130 0.00
40 T,M tert-Amyl methyl ether (TAM 10.000 9.277 7.2 110 0.00
41 S 1,2-Dichloroethane-d4 10.000 9.331 6.7 104 0.01
(#) = Out of Range
REW342.D V006E15.M Fri May 19 09:55:09 2023 Page 1
REPORT ID: 23E135 Page 120 of 454
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Acq On 19 May 2023 6:40 am
Sample CV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M l,2-Dichloroethane 10.000 9.696 3.0 115 0.01
T,M Benzene 10.000 10.404 -4.0 124 0.00
T,M Trichloroethene 10.000 10.229 -2.3 122 0.00
T,M Methylcyclohexane 10.000 10.630 -6.3 130 0.00
C,T,M l,2-Dichloropropane 10.000 10.480 /" -4.8 127 0.00
T,M l,4-Dioxane 200.000 172.571 13.7 113 0.00
T,M Bromodichloromethane 10.000 9.799 2.0 121 0.00
T,M Dibromomethane 10.000 9.606 3.9 114 0.00
T,M 2-Chloroethyl vinyl ether 10.000 7.158 28.4# 83 0.01
T,M 4-Methyl-2-pentanone 50.000 46.387 7.2 109 0.01
T,M cis-1,3-Dichloropropene 10.000 10.254 -2.5 120 0.01
I CHLOROBENZENE-D5 10.000 10.000 0.0 102 0.00
S Toluene-d8 10.000 10.298 -3.0 108 0.00
C,T,M Toluene 10.000 11.078 ~ -10.8 125 0.01
T,M Ethyl methacrylate 10.000 9.812 1.9 111 0.00
T,M trans-1,3-Dichloropropene 10.000 10.297 -3.0 116 0.00
T,M l,l,2-Trichloroethane 10.000 10.114 -1.1 119 0.00
T,M 2-Hexanone 50.000 45.220 9.6 108 0.00
T,M l,3-Dichloropropane 10.000 10.376 -3.8 116 0.00
T,M Tetrachloroethene 10.000 10.972 -9.7 123 0.00
T,M Dibromochloromethane 10.000 9.988 0.1 114 0.01
T,M 2-Ethyl-1-butanol -1.000 0.000 0.0 0 0.00
T,M l,2-Dibromoethane 10.000 9.821 1.8 111 0.01
T,M 1-Chlorohexane 10.000 11.241 -12.4 125 0.00
P, T,M Chlorobenzene 10.000 10.769 -7.7 121 0.00
T,M l,l,l,2-Tetrachloroethane 10.000 10.367 -3.7 119 0.00
C,T,M Ethylbenzene 10.000 10.857r/ -8.6 125 0.01
T,M m-Xylene & p-Xylene 20.000 22.121 -10.6 123 0.01
T,M o-Xylene 10.000 10.643 -6.4 122 0.00
T,M Styrene 10.000 10.556 -5.6 120 0.01
T,M Isopropylbenzene 10.000 10.803 -8.0 125 0.00
I 1,2-DICHLOROBENZENE-D4 10.000 10.000 0.0 100 0.01
P,T,M Bromoform 10.000 9.806 1.9 110 0.00
P,T,M l,l,2,2-Tetrachloroethane 10.000 10.563 -5.6 116 0.01
S 4-Bromofluorobenzene 10.000 10.330 -3.3 107 0.00
T,M 1, 2, 3-Trichloropropane 10.000 9.800 2.0 109 0.00
T,M trans-1,4-Dichloro-2-butene 10.000 9.287 7.1 106 0.00
T,M n-Propylbenzene 10.000 11. 421 -14.2 125 0.00
T,M Bromobenzene 10.000 10.646 -6.5 119 0.00
(#) = Out of Range
REW342.D V006E15.M Fri May 19 09:55:10 2023 Page 2
REPORT ID: 23E135 Page 121 of 454
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Acq On 19 May 2023 6:40 am
Sample CV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
TIM 1 /3 /5-Trimethylbenzene 10.000 10.961 "\ -9.6 123 0.00
TIM 2-Chlorotoluene 10.000 10.907 -9.1 119 0.00
TIM 4-Chlorotoluene 10.000 11.188 -11. 9 125 0.00
TIM tert-Butylbenzene 10.000 11.150 -11. 5 125 0.00
TIM 1 /2 /4-Trimethylbenzene 10.000 10.739 -7.4 122 0.00
T,M sec-Butylbenzene 10.000 11.292 -12.9 126 0.00
TIM p-Isopropyltoluene 10.000 11.215 -12.1 125 0.00
TIM 1 /3-Dichlorobenzene 10.000 10.955 -9.6 121 0.00
T,M 1 /2 /3-Trimethylbenzene 10.000 10.711 -7.1 120 0.00
T,M 1 /4-Dichlorobenzene 10.000 10.904 -9.0 119 0.00
T,M n-Butylbenzene 10.000 11.272 -12.7 126 0.00
T,M 1 ,2-Dichlorobenzene 10.000 10.893 -8.9 120 0.01
T,M 1 /2-Dibromo-3-chloropropane 10.000 8.633 13.7 100 0.00
T,M 1 /2 /4-Trichlorobenzene 10.000 10.048 -0.5 113 0.00
T,M Hexachlorobutadiene 10.000 11.171 -11. 7 121 0.00
T,M Naphthalene 10.000 9.526 4.7 105 0.00
T,M 1 /2 /3-Trichlorobenzene 10.000 9.678 3.2 106 0.01
(#) = Out of Range
REW342.D V006E15.M
SPCC's out = 0 CCC's out = 0
Fri May 19 09:55:11 2023 Page 3
REPORT ID: 23E135 Page 122 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Acq On 19 May 2023 6:40 am
Sample CV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M 1,1,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C/T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-l,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P/T,M 1,1-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichtoropropane
29 T,M cis-l,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M 1,1, I-Trichloroethane
36 T,M Cyclohexane
37 T,M 2{2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S lt2-Dichloroethane-d4
AvgRF
1. 000
0.400
0.443
0.431
0.355
0.260
0.592
0.513
0.025
0.277
0.040
0.551
0.011
0.000
0.027
0.604
0.392
1.315
0.045
0.540
0.379
0.988
0.305
0.617
0.000
0.817
o .<J6 0
0.333
0.374
0.603
0.000
0.191
0.034
0.323
0.501
0.523
0.000
0.165
0.394
0.644
0.225
50% Max. R.T. Dev 0.16min
200%
CCRF
1.000
0.374
,/1 0.452
.0.407
0.338
0.246
0.620
0.484
0.022
0.265
0.033
0.570
0.010
0.000
0.023
0.595
0.397
1.336
0.043
0.514
0.396
1.024
0.300
../ 0.641
0.009
0.828
0.054
0.375
0.388
0.618
0.001
0.186
0.029
0.329
0.491
0.585
0.026
0.171
0.416
0.598
0.210
%Dev Area% Dev(min)
0.0
6.5
-2.0
5.6
4.8
5.4
-4.7
5.7
12.0
4.3
17.5
-3.4
9.1
0.0
14.8
1.5
-1. 3
-1. 6
4.4
4.8
-4.5
-3.6
1.6
-3.9
0.0
-1.3
10.0
-12.6
-3.7
-2.5
0.0
2.6
14.7
-1. 9
2.0
-11.9
0.0
-3.6
-5.6
7.1
6.7
108
103
108
100
101
102
125
105
109
119
112
122
102
0#
112
118
126
113
112
109
124
124
110
125
0#
121
112
129
124
124
0#
117
111
114
124
134
0#
124
130
110
104
0.00
0.02
0.02
0.00
0.02
0.02
0.02
0.02
0.00
0.02
0.02
0.00
0.02
0.00
0.02
-0.02
0.00
0.02
0.00
0.02
0.02
0.00
0.02
0.02
0.00
0.02
0.02
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.01
(#) -Out of Range
REW342.D V006E15.M Fri May 19 09:55:15 2023 Page 1
REPORT ID: 23E135 Page 123 of 454
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Acq On 19 May 2023 6:40 am
Sample CV006E1504
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
TIM 1 1 2-Dichloroethane 0.281
TIM Benzene 1.355
TIM Trichloroethene 0.363
TIM Methylcyclohexane 0.561
CITIM 1,2-Diehloropropane 0.315
T,M 1,4-Dioxane 0.001
T,M Bromodiehloromethane 0.421
TIM Dibromomethane 0.162
TIM 2-Chloroethyl vinyl ether 0.027
T,M 4-Methyl-2-pentanone 0.144
TIM eis-1,3-Dichloropropene 0.497
I CHLOROBENZENE-D5 1.000
S Toluene-d8 1.299
CITIM Toluene 1.633
TIM Ethyl methacrylate 0.291
TIM trans-l,3-Diehloropropene 0.423
TIM 1,l,2-Trichloroethane 0.234
TIM 2-Hexanone 0.117
TIM 1,3-Dichloropropane 0.419
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
0.272 3.2 115 0.01
1.410 -4.1 124 0.00
0.371 -2.2 122 0.00
0.596 -6.2 130 0.00
0.330 -4.8 127 0.00
0.001 0.0 113 0.00
0.413 1.9 121 0.00
0.156 3.7 114 0.00
0.019 29.6# 83 0.01
/.134 6.9 109 0.01
0.510 -2.6 120 0.01
1.000 0.0 102 0.00
1.337 -2.9 108 0.00
1.809 -10.8 125 0.01
0.285 2.1 111 0.00
0.436 -3.1 116 0.00
0.237 -1. 3 119 0.00
0.106 9.4 108 0.00
0.435 -3.8 116 0.00
TIM Tetrachloroethene 0.358 / 0.393 -9.8 123 0.00
TIM Dibromochloromethane 0.296/' 0.296 0.0 114 0.01
TIM 2-Ethyl-1-butanol 0.000 0.000 0.0 0# 0.00
TIM 1,2-Dibromoethane 0.229 0.225 1.7 111 0.01
TIM 1-Chlorohexane 0.685 0.770 -12.4 125 0.00
PI T,M Chlorobenzene 1.050 1.131 -7.7 121 0.00
T,M 1{1,1,2-Tetrachloroethane 0.365 0.379 -3.8 119 0.00
CIT{M Ethylbenzene 1.971 2.140 -8.6 125 0.01
TIM m-Xylene & p-Xylene 1.439 1.592 -10.6 123 0.01
TIM o-Xylene 1.469 1.564 -6.5 122 0.00
TIM Styrene 1.117 1.179 -5.6 120 0.01
TIM Isopropylbenzene 1.882 2.033 -8.0 125 0.00
I 1{2-DICHLOROBENZENE-D4 1. 000 1.000 0.0 100 0.01
P,T,M Bromoform 0.367 0.360 1.9 110 0.00
PITIM 1{1 1 2,2-Tetrachloroethane 0.660 0.697 -5.6 116 0.01
S 4-Bromofluorobenzene 1.132 1.169 -3.3 107 0.00
TIM 11 21 3-Trichloropropane 0.169 0.166 1.8 109 0.00
TIM trans-1{4-Diehloro-2-butene 0.172 0.159 7.5 106 0.00
TIM n-Propylbenzene 5.985 6.836 -14.2 125 0.00
TIM Bromobenzene 1.034 1.101 -6.5 119 0.00
(#) = Out of Range
REW342.D V006E15.M Fri May 19 09:55:17 2023 Page 2
REPORT ID: 23E135 Page 124 of 454
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Aeq On 19 May 2023 6:40 am
Sample CV006E1504
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1 /3 /5-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.856
T,M 4-Chlorotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M l,2,4-Trimethylbenzene 3.824
T,M see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
T,M 1 /3-Diehlorobenzene 1. 955
T,M 1, 2, 3-Trimethylbenzene 3.471
T,M l,4-Diehlorobenzene 1.960
T,M n-Butylbenzene 3.978
T,M l,2-Diehlorobenzene 1. 630
T,M l,2-Dibromo-3-ehloropropane 0.105
T,M l,2,4-Triehlorobenzene 1.069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1.562
T,M 1, 2, 3-Triehlorobenzene 0.822
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
4.244 -9.6 123 0.00
4.206 -9.1 119 0.00
3.410 -11. 9 125 0.00
1. 036 -11. 5 125 0.00
4.106 -7.4 122 0.00
6.076 -12.9 126 0.00
4.711 -12.1 125 0.00
2.142 -9.6 121 0.00
3.718 -7.1 120 0.00
2.137 -9.0 119 0.00
4.484 -12.7 126 0.00
1. 776 -9.0 120 0.01
0.091 13.3 100 0.00
1.075 -0.6 113 0.00
0.735 -11.7 121 0.00
1.488 4.7 105 0.00
0.796 3.2 106 0.01
(#) = Out of Range
REW342.D V006E15.M
sPcc's out = 0 CCC's out = 0
Fri May 19 09:55:18 2023 Page 3
REPORT ID: 23E135 Page 125 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Acq On 19 May 2023 6:40 am
Sample CV006E1504
Vial: 2
Operator: LYarnas
Inst 06
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 7:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile·
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.43 152
8.10
9.23
12.91
17.55
1.71
1.95
2.05
2.52
2.62
2.66
2.90
3.40
3.47
3.51
3.66
3.82
4.20
4.10
4.39
4.39
4.64
4.70
4.91
5.60
5.86
5.77
6.55
6.84
7.07
7.20
7.60
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
4523242 ~ 10.00 ug/l
3796294~ 10.00 ug/l
1426922v/ 10.00 ug/l
1486109 10.17
Recovery =
947939 9.33
Recovery =
5076782 10.30
Recovery =
1668571 10.33
Recovery =
ug/l
101.70%
ug/l
93.30%
ug/l
103.00%
ug/l
103.30%
0.00
0.00
0.01
0.00
0.01
0.00
0.00
1693824
2045016
1840962
1526858
1114252
2804840
2188349
9.36 ug/l
10.21 ug/l
9.44 ug/l
9.51 ug/l
9.47 ug/l
10.48 ug/l
9.43 ug/l
43.30 ug/l
9.56 ug/l
43.78 ug/l
10.35 ug/l
213.68 ug/l
8.68 ug/l
9.84 ug/l
10.15 ug/l
Qvalue
98
100
98
100
97
99
493701
1199478
748053
2580195
1081911
106027
2690351
1797401
6044223
975232
2323737
1791256
4633890
1356360
2901317
3745567
1216567
1697775
1756990
2795456
10.16 ug/l
47.52 ug/l
9.51 ug/l
10.45 ug/l
10.37 ug/l
9.82 ug/l
10.40 ug/l
10.14 ug/l
44.97 ug/l
11.29 ug/l
10.38 ug/l
10.25 ug/l
100
98
99
97
98
100
95
100
95
99
99
99
99
99
98
100
98
98
100
99
98
(#) = qualifier out of range (m) = manual integration
REW342.D V006E15.M Fri May 19 09:55:26 2023 Page 1
REPORT ID: 23E135 Page 126 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Acq On 19 May 2023 6:40 am
Sample CV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 7:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32)
33)
35)
36)
38)
39)
40)
42)
43)
44)
45)
46)
47)
48)
49)
50 )
51 )
52)
55 )
56 )
57)
58)
59 )
60)
61)
62)
64)
65)
66)
67 )
68)
69)
70)
71)
72 )
74)
75)
77)
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
1,1, I-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
l,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
l,l,2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.95
8.08
8.50
8.48
8.85
9.02
9.20
9.42
9.40
10.67
10.75
11.02
11.58
11.46
11.54
12.16
12.21
12.53
13.06
13.49
13.43
13.69
13.77
14.14
14.19
14.55
14.89
15.23
15.60
15.69
15.72
15.85
16.56
16.64
17.17
17.17
17.46
17.67
17.77
17.77
17.81
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
840356
132279
2219121
2644101
772859
1882208
2703532
1230675
6377372
1679985
2696292
1494436
106466
1867628
703534
87737
3026880
2305610
6865984
1083107
1654212
899203
2003141
1649905
1490753
1123456
854266
2922472
4293552
1438443
8124653
12087939
5935799
4477403
7716275
513778
994557
236381
227487
9754837
1570810
(#) = qualifier out of range (m) = manual integration
9.72 ug/l
8.69 ug/l
9.79 ug/l
11.18 ug/l
10.34 ug/l
10.56 ug/l
9.28 ug/l
9.70 ug/l
10.40 ug/l
10.23 ug/l
10.63 ug/l
10.48 ug/l
172.57 ug/l
9.80 ug/l
9.61 ug/l
7.16 ug/l
46.39 ug/l
10.25 ug/l
11.08 ug/l
9.81 ug/l
10.30 ug/l
10.11 ug/l
45.22 ug/l
10.38 ug/l
10.97 ug/l
9.99 ug/l
9.82 ug/l
11.24 ug/l
10.77 ug/l
10.37 ug/l
10.86 ug/l
22.12 ug/l
10.64 ug/l
10.56 ug/l
10.80 ug/l
9.81 ug/l
10.56 ug/l
9.80 ug/l
9.29 ug/l
11.42 ug/l
10.65 ug/l
Qvalue
98
92
100
95
98
98
99
100
100
99
97
98
98
98
100
98
99
98
100
99
97
98
98
98
99
99
99
99
99
99
98
98
98
99
99
98
99
100
96
99
100
REW342.D V006E15.M Fri May 19 09:55:26 2023 Page 2
REPORT ID: 23E135 Page 127 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Aeq On 19 May 2023 6:40 am
Sample CV006E1504
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 7:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) 1,3,5-Trimethylbenzene 17.98 105 6056063 10.96 ug/l 100
82) 2-Chlorotoluene 17.99 91 6001868 10.91 ug/l 98
83) 4-Chlorotoluene 18.06 91 4866139 11.19 ug/l 98
84) tert-Butylbenzene 18.43 134 1478594 11.15 ug/l 90
85) 1,2,4-Trimethylbenzene 18.47 105 5859650 10.74 ug/l 100
86) see-Butylbenzene 18.68 105 8669775 11. 29 ug/l 100
87) p-Isopropyltoluene 18.83 119 6722406 11. 22 ug/l 99
88) 1,3-Diehlorobenzene 18.94 146 3056077 10.96 ug/l 98
89) 1, 2, 3-Trimethylbenzene 19.02 105 5305611 10.71 ug/l 100
90) 1,4-Diehlorobenzene 19.05 146 3049752 10.90 ug/l 99
91 ) n-Butylbenzene 19.28 91 6398374 11.27 ug/l 99
92) 1,2-Diehlorobenzene 19.46 146 2533550 10.89 ug/l 98
93) 1,2-Dibromo-3-ehloropropan 20.22 157 129822 8.63 ug/l 97
94) 1,2,4-Triehlorobenzene 21. 05 180 1533418 10.05 ug/l 99
95) Hexaehlorobutadiene 21.18 225 1049435 11.17 ug/l 98
96) Naphthalene 21.33 128 2123063 9.53 ug/l 99
97) 1,2,3-Triehlorobenzene 21.59 180 1135136 9.68 ug/l 98
(#) = qualifier out of range (m) = manual integration
REW342.D V006E15.M Fri May 19 09:55:27 2023 Page 3
REPORT ID: 23E135 Page 128 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW342.D
Aeq On 19 May 2023 6:40 am
Sample CV006E1504
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 19 7:02 2023
TBA
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
li\-bLlndance
· 1.35e+071
I
1.3e+071
· I
i 1.25e+07j
· I
1.2e+07i
· i i 1.15e+071
· 1.1e+071
1.05e+07j
i 1e+071
95000001
90000001
i
85000001
I
8000000J
i
75000001
,
70000001
!
65000001
6000000j
55000001
t
50000001
j
4500000'
1
4000000j
I
35000001
30000001
I
25000001
20000001
1
15000001
l
10000001
500000;
Time-->
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW342.D
REW342.D V006E15.M Fri May 19 09:55:29 2023
20.00
Page 4
REPORT ID: 23E135 Page 129 of 454
Evaluate Continuing Calibration Report.
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Acq On 19 May 2023 5:06 pm
Sample EV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
(RTE Integrator)
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M l,l,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M l,l-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M 1, 1, 1-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
Amount Calc.
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.742
11.879
10.295
11.222
11.396
10.830
10.106
48.333
9.085
50.000 50.945
10.000 10.242
250.000 245.680
-1.000 0.000
10.000 10.102
10.000 10.098
10.000 10.853
10.000 10.762
50.000 53.429
10.000 10.521
10.000 10.710
10.000 11.341
10.000 11.083
10.000 10.999
250.000 0.000
10.000 11.181
50.000 52.346
10.000 10.198
10.000 10.939
10.000 10.683
50.000 0.000
10.000 10.569
10.000 9.923
10.000 10.549
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.492
11.011
0.000
9.949
9.423
10.124
10.071
(#) = Out of Range
REW366.D V006E15.M Fri May 19 17:32:14 2023
%Dev Area%Dev(min)
0.0
-7.4
-18.8
-2.9
-12.2
-14.0
-8.3
-1.1
3.3
9.1
-1.9
-2.4
1.7
0.0
-1. 0
-1. 0
-8.5
-7.6
-6.9
-5.2
-7.1
-13.4
-10.8
-10.0
100.0#
-11.8
-4.7
-2.0
-9.4
-6.8
100.0#
-5.7
0.8
-5.5
5.1
-10.1
100.0#
0.5
5.8
-1. 2
-0.7
99
109
115
100
109
112
118
103
111
104
118
111
107
o
119
111
123
110
116
111
117
124
113
122
o
123
119
107
119
119
o
117
116
108
111
121
o
109
107
110
103
0.00
0.00
0.00
0.00
0.02
0.00
0.00
0.02
0.00
0.02
0.02
0.00
0.02
0.00
0.02
-0.02
0.00
0.02
0.00
0.02
0.02
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.00
0.02
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
Page 1
REPORT ID: 23E135 Page 130 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Acq On 19 May 2023 5:06 pm
Sample EV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M l,2-Dichloroethane
43 T,M Benzene
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M l,2-Dichloropropane
47 T,M l,4-Dioxane
48 T,M Bromodichloromethane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M l,l,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M l,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 2-Ethyl-1-butanol
64 T,M l,2-Dibromoethane
65 T,M 1-Chlorohexane
66 P, T,M Chlorobenzene
67 T,M l,l,l,2-Tetrachloroethane
68 C,T,M Ethylbenzene
69 T,M m-Xylene & p-Xylene
70 T,M o-Xylene
71 T,M Styrene
72 T,M Isopropylbenzene
73 I l,2-DICHLOROBENZENE-D4
74 P,T,M Bromoform
75 P,T,M l,l,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M l,2,3-Trichloropropane
78 T,M trans-1,4-Dichloro-2-butene
79 T,M n-Propylbenzene
80 T,M Bromobenzene
Amount Calc.
10.000 10.456
10.000 10.871
10.000 10.405
10.000 10.980
10.000 11.299
200.000 175.026
10.000 10.397
10.000 10.316
10.000 8.063
50.000 54.231
10.000 10.845
10.000 10.000
10.000 10.396
10.000 11.054
10.000 10.425
10.000 10.383
10.000 10.315
50.000 51.999
10.000 10.647
10.000 10.394
10.000 10.168
-1.000 0.000
10.000 10.407
10.000 10.546
10.000 10.869
10.000 10.710
10.000 10.710
20.000 21.977
10.000 10.745
10.000 10.628
10.000 10.579
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.564
10.672
10.025
10.075
9.025
10.798
10.532
(#) = Out of Range
REW366.D V006E15.M Fri May 19 17:32:15 2023
%Dev Area% Dev(min)
-4.6
-8.7
-4.0
-9.8
-13.0
12.5
-4.0
-3.2
19.4
-8.5
-8.5
113
118
114
123
125
105
118
113
85
117
117
0.0 98
-4.0 104
-10.5 119
-4.3 113
-3.8 111
-3.1 116
-4.0 119
-6.5 114
-3.9 111
-1. 7 110
0.0 a
-4.1 113
-5.5 112
-8.7 116
-7.1 118
-7.1 118
-9.9 117
-7.4 118
-6.3 115
-5.8 117
0.0
4.4
-6.7
-0.3
-0.7
9.7
-8.0
-5.3
99
107
117
103
112
103
118
118
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Page 2
REPORT ID: 23E135 Page 131 of 454
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Acq On 19 May 2023 5:06 pm
Sample EV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev{min)
T,M 1,3,5-Trimethylbenzene 10.000 10.466 -4.7 117 0.00
T,M 2-Chlorotoluene 10.000 10.780 -7.8 118 0.00
T,M 4-Chlorotoluene 10.000 10.652 -6.5 119 0.00
T,M tert-Butylbenzene 10.000 10.405 -4.0 116 0.00
T,M l,2,4-Trimethylbenzene 10.000 10.504 -5.0 119 0.00
T,M sec-Butylbenzene 10.000 10.468 -4.7 117 0.00
T,M p-Isopropyltoluene 10.000 10.452 -4.5 117 0.00
T,M 1 /3-Dichlorobenzene 10.000 10.696 -7.0 118 0.00
T,M 1 /2,3-Trimethylbenzene 10.000 10.548 -5.5 118 0.00
T,M 1,4-Dichlorobenzene 10.000 10.738 -7.4 118 0.00
T,M n-Butylbenzene 10.000 10.796 -8.0 121 0.00
T,M l,2-Dichlorobenzene 10.000 10.666 -6.7 117 0.00
T,M l,2-Dibromo-3-chloropropane 10.000 9.387 6.1 109 0.00
T,M 1 /2,4-Trichlorobenzene 10.000 10.435 -4.4 117 0.00
T,M Hexachlorobutadiene 10.000 10.708 -7.1 116 0.00
T,M Naphthalene 10.000 10.395 -3.9 114 0.00
T,M 1, 2, 3-Trichlorobenzene 10.000 10.442 -4.4 114 0.00
(#) = Out of Range
REW366.D V006E15.M
SPCC's out = 0 CCC's out = 0
Fri May 19 17:32:15 2023 Page 3
REPORT ID: 23E135 Page 132 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Acq On 19 May 2023 5:06 pm
Sample EV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M l,l,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M l,l-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
AvgRF
1. 000
0.400
0.443
0.431
0.355
0.260
0.592
0.513
0.025
0.277
0.040
0.551
0.011
0.000
0.027
0.604
0.392
1.315
0.045
0.540
0.379
0.988
0.305
0.617
0.000
0.817
0.060
0.333
0.374
0.603
0.000
0.191
0.034
0.323
0.501
0.523
0.000
0.165
0.394
0.644
0.225
50% Max. R.T. Dev 0.16min
200%
CCRF
1.000
0.430
0.526
0.444
0.398
0.296
0.641
0.518
0.024
0.252
0.038
0.565
0.011
0.000
0.027
0.610
0.425
1.415
0.048
0.568
0.406
1.120
0.339
0.678
0.011
0.913
0.063
0.339
0.409
0.644
0.001
0.202
0.033
0.341
0.476
0.576
0.027
0.164
0.371
0.652
0.226
%Dev Area% Dev(min)
0.0
-7.5
-18.7
-3.0
-12.1
-13.8
-8.3
-1. 0
4.0
9.0
5.0
-2.5
0.0
0.0
0.0
-1. 0
-8.4
-7.6
-6.7
-5.2
-7.1
-13.4
-11.1
-9.9
0.0
-11.8
-5.0
-1. 8
-9.4
-6.8
0.0
-5.8
2.9
-5.6
5.0
-10.1
0.0
0.6
5.8
-1. 2
-0.4
99
109
115
100
109
112
118
103
111
104
118
111
107
0#
119
111
123
110
116
111
117
124
113
122
0#
123
119
107
119
119
0#
117
116
108
111
121
0#
109
107
110
103
0.00
0.00
0.00
0.00
0.02
0.00
0.00
0.02
0.00
0.02
0.02
0.00
0.02
0.00
0.02
-0.02
0.00
0.02
0.00
0.02
0.02
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.00
0.02
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
(#) = Out of Range
REW366.D V006E15.M Fri May 19 17:32:19 2023 Page 1
REPORT ID: 23E135 Page 133 of 454
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Acq On 19 May 2023 5:06 pm
Sample EV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 TIM 1 /2-Dichloroethane
43 TIM Benzene
44 TIM Trichloroethene
45 TIM Methylcyclohexane
46 C/T/M 1 /2-Dichloropropane
47 TIM 1/4-Dioxane
48 TIM Bromodichloromethane
49 TIM Dibromomethane
50 TIM 2-Chloroethyl vinyl ether
51 TIM 4-Methyl-2-pentanone
52 TIM cis-1 /3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C/T/M Toluene
56 TIM Ethyl methacrylate
57 TIM trans-1 /3-Dichloropropene
58 TIM 1 /1 /2-Trichloroethane
59 TIM 2-Hexanone
60 TIM 1 /3-Dichloropropane
61 TIM Tetrachloroethene
62 TIM Dibromochloromethane
63 TIM 2-Ethyl-1-butanol
64 TIM 1 /2-Dibromoethane
65 TIM 1-Chlorohexane
66 PI TIM Chlorobenzene
67 TIM 111/ 11 2-Tetrachloroethane
68 C/T/M Ethylbenzene
69 TIM m-Xylene & p-Xylene
70 TIM o-Xylene
71 TIM Styrene
72 TIM Isopropylbenzene
73 I 1 /2-DICHLOROBENZENE-D4
74 P,T/M Bromoform
75 P/T,M 1 /1 /2 /2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1 /2 /3-Trichloropropane
78 T,M trans-1,4-Dichloro-2-butene
79 T,M n-Propylbenzene
80 T,M Bromobenzene
AvgRF
0.281
1.355
0.363
0.561
0.315
0.001
0.421
0.162
0.027
0.144
0.497
1.000
1. 299
1. 633
0.291
0.423
0.234
0.117
0.419
0.358
0.296
0.000
0.229
0.685
1.050
0.365
1.971
1.439
1.469
1.117
1.882
1.000
0.367
0.660
1.132
0.169
0.172
5.985
1.034
CCRF
0.293
1.473
0.378
0.616
0.356
0.001
0.438
0.167
0.022
0.156
0.539
1. 000
1.350
1.805
0.303
0.439
0.242
0.121
0.446
0.372
0.301
0.000
0.238
0.722
1.141
0.391
2.111
1.582
1.579
1.187
1.990
1.000
0.351
0.704
1.135
0.170
0.155
6.463
1.089
(#) = Out of Range
REW366.D V006E15.M Fri May 19 17:32:21 2023
%Dev Area% Dev(min)
-4.3 113
-8.7 118
-4.1 114
-9.8 123
-13.0 125
0.0 105
-4.0 118
-3.1 113
18.5 85
-8.3 117
-8.5 117
0.0 98
-3.9 104
-10.5 119
-4.1 113
-3.8 111
-3.4 116
-3.4 119
-6.4 114
-3.9 111
-1. 7 110
0.0 0#
-3.9 113
-5.4 112
-8.7 116
-7.1 118
-7.1 118
-9.9 117
-7.5 118
-6.3 115
-5.7 117
0.0 99
4.4 107
-6.7 117
-0.3 103
-0.6 112
9.9 103
-8.0 118
-5.3 118
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Page 2
REPORT ID: 23E135 Page 134 of 454
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
hcq On 19 May ~O/'1 5:06 pm
Sample EV006E1S04
Mise 10ppb 8260/S0ppb KET-AA/2S0ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E1S.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1,3,S-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.8S6
T,M 4-Chlbrotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M 1, 2, 4-Trimethylbenzene 3.824
T,M see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
T,M 1,3-Diehlorobenzene 1.955
T,M 1, 2, 3-Trimethylbenzene 3.471
T,M l,4-Diehlorobenzene 1.960
T,M n-Butylbenzene 3.978
T,M l,2-Diehlorobenzene 1.630
T,M l,2-Dibromo-3-ehloropropane 0.10S
T,M 1,2,4-Triehlorobenzene 1.069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1.S62
T,M 1, 2, 3-Triehlorobenzene 0.822
SO% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
4.0S2 -4.6 117 0.00
4.1S7 -7.8 118 0.00
3.247 -6.S 119 0.00
0.967 -4.1 116 0.00
4.017 -S.O 119 0.00
5.632 -4.7 117 0.00
4.391 -4.S 117 0.00
2.091 -7.0 118 0.00
3.662 -S.S 118 0.00
2.10S -7.4 118 0.00
4.29S -8.0 121 0.00
1.739 -6.7 117 0.00
0.099 S.7 109 0.00
1.116 -4.4 117 0.00
0.70S -7.1 116 0.00
1.624 -4.0 114 0.00
0.858 -4.4 114 0.00
(#) = Out of Range
REW366.D V006E15.M
SPCC's out = a CCC's out = a
Fri May 19 17:32:22 2023 Page 3
REPORT ID: 23E135 Page 135 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Acq On 19 May 2023 5:06 pm
Sample EV006E1504
Vial: 26
Operator: LYamas
Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 17:30 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
8.10
9.22
12.92
17.55
1. 70
1. 93
2.05
2.53
2.60
2.64
2.90
3.40
3.47
3.51
3.65
3.82
4.20
4.09
4.39
4.39
4.64
4.70
4.91
5.60
5.83
5.77
6.53
6.82
7.07
7.20
7.59
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
4150024 ~ 10.00 ug/l
3622748 ~ 10.00 ug/l
1425571 10.00 ug/l
1413960 10.55
Recovery =
938733 10.07
Recovery
4890856 10.40
Recovery =
1617802 10.03
Recovery =
ug/l
105.50%
ug/l
100.70%
ug/l
104.00%
ug/l
100.30%
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1782665
2183869
1841598
1652869
1230034
2659912
2150788
10.74 ug/l
11.88 ug/l
10.29 ug/l
11.22 ug/l
11.40 ug/l
10.83 ug/l
10.11 ug/l
48.33 ug/l
Qvalue
97
99
98
505585
1045740
792135
2343420
1141307
113256
2532521
1763694
5873740
1005'937
2358850
1683750
4647651
1404824
2814244
3790517
1299175
1407297
1698278
2674181
9.09 ug/l
50.95 ug/l
10.24 ug/l
245.68 ug/l
10.10 ug/l
10.10 ug/l
10.85 ug/l
10.76 ug/l
53.43 ug/l
10.52 ug/l
10.71 ug/l
11.34 ug/l
11.08 ug/l
11.00 ug/l
11.18 ug/l
52.35 ug/l
10.20 ug/l
10.94 ug/l
10.68 ug/l
100
99
99
99
99
100
96
98
100
92
100
95
99
99
99
100
99
100
100
97
97
99
99
99
(#) = qualifier out of range (m) = manual integration
REW366.D V006E15.M Fri May 19 17:32:29 2023 Page 1
REPORT ID: 23E135 Page 136 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Acq On 19 May 2023 5:06 pm
Sample EV006E1504
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 17:30 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95
8.10
8.50
8.48
8.85
9.02
9.20
9.42
9.40
10.67
10.75
11.02
11.58
11.46
11.54
12.15
12.20
12.51
13.06
13.49
13.44
13.69
13.77
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.67
17.77
17.77
17.81
130 838566
42 138555
97 1974639
84 2388676
110 681981
119 1540876
73 2706782
62 1217697
78 6113665
130 1567933
83 2555413
63 1478165
88 99071
83 1818059
93 693196
63 90674
43 3246717
75 2237121
91 6538301
69 1098133
75 1591809
97 875157
43 2198126
76 1615500
164 1347621
129 1091478
107 863884
91 2616303
112 4135281
131 1417981
91 7648505
91 11460436
91 5718669
104 4301560
105 7211015
173 500644
83 1003860
110 242786
53 220862
91 9213784
156 1552456
(#) = qualifier out of range (m) = manual integration
10.57 ug/l
9.92 ug/l
9.49 ug/l
11.01 ug/l
9.95 ug/l
9.42 ug/l
10.12 ug/l
10.46 ug/l
10.87 ug/l
10.40 ug/l
10.98 ug/l
11.30 ug/l
175.03 ug/l
10.40 ug/l
10.32 ug/l
8.06 ug/l
54.23 ug/l
10.84 ug/l
11.05 ug/l
10.43 ug/l
10.38 ug/l
10.32 ug/l
52.00 ug/l
10.65 ug/l
10.39 ug/l
10.17 ug/l
10.41 ug/l
10.55 ug/l
10.87 ug/l
10.71 ug/l
10.71 ug/l
21.98 ug/l
10.75 ug/l
10.63 ug/l
10.58 ug/l
9.56 ug/l
10.67 ug/l
10.08 ug/l
9.02 ug/l
10.80 ug/l
10.53 ug/l
Qvalue
98
96
99
95
98
98
99
99
100
99
98
97
95
100
99
96
98
98
100
98
99
97
100
99
99
98
99
100
100
99
98
100
99
99
100
100
98
96
91
100
99
REW366.D V006E15.M Fri May 19 17:32:29 2023 Page 2
REPORT ID: 23E135 Page 137 of 454
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Aeq On 19 May 2023 5:06 pm
Sample EV006E1504
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 19 17:30 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81 ) 1, 3, 5-Trimethylbenzene 17.98 105 5777097 10.47 ug/l 100
82) 2-Chlorotoluene 17.99 91 5926759 10.78 ug/l 100
83) 4-Chlorotoluene 18.06 91 4628517 10.65 ug/l 98
84) tert-Butylbenzene 18.43 134 1378496 10.40 ug/l 98
85) l,2,4-Trimethylbenzene 18.47 105 5725895 10.50 ug/l 99
86) see-Butylbenzene 18.68 105 8029127 10.47 ug/l 100
87) p-Isopropyltoluene 18.84 119 6259043 10.45 ug/l 99
88) l,3-Dichlorobenzene 18.94 146 2980995 10.70 ug/l 99
89) l,2,3-Trimethylbenzene 19.02 105 5220029 10.55 ug/l 100
90) l,4-Dichlorobenzene 19.06 146 3000422 10.74 ug/l 99
91) n-Butylbenzene 19.28 91 6122662 10.80 ug/l 99
92) l,2-Dichlorobenzene 19.45 146 2478409 10.67 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.22 157 141015 9.39 ug/l 95
94) l,2,4-Triehlorobenzene 21.06 180 1590954 10.44 ug/l 100
95) Hexachlorobutadiene 21.18 225 1004980 10.71 ug/l 98
96 ) Naphthalene 21.33 128 2314478 10.39 ug/l 99
97) 1, 2, 3-Trichlorobenzene 21.57 180 1223602 10.44 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW366.D V006E15.M Fri May 19 17:32:30 2023 Page 3
REPORT ID: 23E135 Page 138 of 454
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E19\REW366.D
Aeq On 19 May 2023 5:06 pm
Sample EV006E1504
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
26
LYamas
06
1. 00
Quant Time: May 19 17:30 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
! 125e+07j
I 1.2e+07j
i I i 1.15e+07·
i 1.1e+07
I 1
! 10~::::111
9500000
i 9000000;
1
85000001
j,.1
8000000
7500000
7000000
6500000
6000000
I
55000001
i 50000001
i
45000001
4000000'
i 35000001
3000000
rTime-->
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
I
6.00
, I
8.00
TIC: REW366.D
, I ' , I , I I , ,
10.00 12.00
J
:;!
f-
o
I c'
I ~ ,
I I ' , I I I ' I , , I I I , , I '
14.00 16.00 18.00 20.00
REW366.D V006E15.M Fri May 19 17:32:32 2023
, , I It
Page 4
REPORT ID: 23E135 Page 139 of 454
· ANALYTICAL LOGS
REPORT ID: 23E135 Page 140 of 454
Page 70
ANALYSIS LOG FOR VOLATILES
d JI
Start Date: 5. (Ir;l~ Cl 5-ml Purge Cl lO-ml Purge r1 25-ml Purge Book#: A06-019 ,
Sample &e Matrix Instrument No. 06 i
Data Sample Prep
FileName Lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
ID Arww pH CI, S A ( PJ <2 < Snnm n,,1) WrA~ 'refI DATE r;t I,h ~ i
01 ~E.VJ'24.q BFBObEI\ i\l/A 111/.4 MIA I.~:~ ICALID VOtlloEI5
,
02 o\K V DO"'!;I?I 'll.t.lI, OilS" I Q.'?l lS 't\" STANDARDS
03 4:1 t'iA" ~S 11-S NAME 10
Amount Cone,
'/... IuS" •• '4" loll (ml!!lI
04 5t> ~ 0.1 lI.lC'" I r; l, (Sot_ 5'1,. "t"~0 1-0 I " ~ DCC !!II4l .... -I., -o'l.
05 Ifl 4-0.1-I 'l. l'" ,0 DCC iUob S~k41-l'\i -o~ sili'lfl
06 S"l. '5" Os" 1.S"" I) a.1 \1S DCC IETAA l&vl-4t> .A'L.a/ 1JN.
07 S1 t.. II tj tl> i'i> 2.S0 DCC4c:ltiJ... 1 ~ VI-4, _ ~C;-41 U'P
08 5"4-'1 l-tl> a.o -':60 1;0<-BFB rt<. -61 I 'fi)
~ 09 !"~ 'l' l S-.
.~ L'O -'4~ , ~ ~ IS" \0 C\'So IS/SURR, r.~ iU-Q~ .It
ri 10 t;1. 't IS' I i ~ 3.$b l2.S"O ICV/LCS ~'::; ~'.;.!k O? ,'i!'M I ~ ,
:::t 11 fj1 lo .J: If\V ,V ,V
Il~1I bot> lSl»1lIb ICV/LCS tu.f> II '2-5'-li\ ; sa.1!l-h J 10
12 ~ ~ltUSE'
I-
ICV ILCS l£ei/fI &'O-4'l .. O?l-0 ~ s 'Ull
< 13 ~ Itt tJSF ICV/LCS~, &VI"<I\:/-,"-Cl:!I 15' !;b.
~ 14 ,V
"'0 lV 0 o "E:lS'O [ l,',Gt. heA&.. li:sti Data File Folder 'l~l"5 ~ 15
....
Lorn Syringe Le·t # -
~ 16 / pH strip Hn-ol1l4-tb
17 V Chlorine strip -o1...ar-OS""-64
18 L Methanol -01.. -0 l-li'.-
19 ./ NaHS04 ... -01-or -Ir
20 / ,
Reagent Water
21 ,/;' Sand
22 ./ 1\: SS, e~,~. 4Mtl. Electronic Data Archival Location Date
23 ./ HPCHEM_VOA/TOO6 r;tlhl~
24 /' 1~:5-lt.o,k£T:-AA Comments:
25 ./
26 /'
27 ./
28 /
29 ./ Analyzed By: L/I.'(
30 Ut't 'S ( lin (2-] Date Disposed:S'll!t:ll~ Disposed By: LPN
REPORT ID: 23E135 Page 141 of 454
""l
Page 71
ANALYSIS LOG FOR VOLATILES
SOP ~MAX-8260 Rev.No.!Q deMAX-8260C Rev. No.! Cl EMAX-8Z60SIM Rev.No.! Cl EMAX-M8Z60SIM Rev.No. 2 Cl EMAX-TCPSIM Rev.No. ~ Cl EMAX-624 Rev.No. § Cl EMAX-624.1 Rev.No. 2
Start Date: 5" l \b h.) Cl S-mL Purge Cl 10-mL Purge iI 2S-mL Purge Book#' A06-079
.: ......... _ ................................................
Matrix Instrument No. 06 Sample Data Sample
Prep Lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
File Name Amount S 10 pH CI, "t I t7(').3 <2 < 50 om DATE
01 rtevJUo( ~ re ()~El1. (C, \\ ICALID VGotoElt;
02 J.-,,,..L \NO obE.l'6" 61 \l..~l ,., STANDARDS
NAME 10
Amount Cone.
03 / (ull (m.tU
04 DCC
05 / DCC
06 DCC
07 V DCC
08 / BFB S~l~4:I-'1';"O I I lib
D:I 09 / IS/SURR. $i toO -0'1. I ~ tilt -0 .... l> I' ICV/LCS ~ ~t::t ~ .... 10 ,
n UiI
::x:: 11 / ICVILCS me. I-2,.r:; -c>1 S" mt').St>
.-12 / ICV /LCS te'O\4 I:!.v I-"t-l-lj~-61 '3 'U'O
, ; 13 1/ ICV/LCS lAdd. .1" 1 .... +I-bS' ,,,~
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en 15 / LOT #I Syringe Lot #I
~ 16 / pH strip NS V -01-04 -{( ..
17 / Chlorine strip J.--o1~Oj--oS'-64
•
18 / Methanol
19 / NaHSO.
20 / Reagent w.ater
21 / Sand .
22 / Electronic Data Archival Location Date
23 / HPCHEM_ VOA/TOO6 1:;( I ~ /'JJ
24 / Comments:
25 V
26 /
27 /
28 /
29 / Analyzed By: I.!tt
"-!..Pi" Stls.{'2.,? Date Disposed: ;-(1 !J2-~ Disposed By: LA 'I 30
REPORT ID: 23E135 Page 142 of 454
~ '.-1'-,..- ,..-~. ,~ ~. ~ '-' .-.-..... ,.... .." ".. ' .. " i""""---=::t ~ ~jl!l!l!l!!l!!l!!,!/I!!!!I!I!I!I/I,lII!IIIIII!I________ --Page 75
ANALYSIS LOG FOR VOLATILES
SOP J EMAX-8260 Rev.No. 10 "EMAX-8260C Rev. No.! D EMAX-8260SIM Rev.No.! D EMAX-M8260SIM Rev.No. Q D EMAX-TCPSIM Rev.No.:f D EMAX-624 Rev.No. § D EMAX-624.1 Rev.No. Q
Start Date: :r( ('r (2.3 D S-ml Purge D 10-ml Purge Ii7 2S-ml Purge Book #: A06-079
Matrix Instrument No. 06 Sample Data Sample
Prep Lab Sample ID DF W Notes INITIAL CALIBRATION REFERENCE
File Name Amount S ID pH CI,
51lsJ'2.-3> <2 < Scorn DATE
01 ~evJ341 8FB6'EI(, ~ .. \t) ICAllD V OObElS'
02 4-1.. CVo~H;LC;-04-STANDARDS
dc~ NAME ID
Amount Cone.
03 \{O otp'E::l('" L (~I melL
04 44-C. C~1.. ~II'V-~~I_Q ~ \ ! ./ DCC E:leu lL-~t-.-dl-
05 4-S" \2-lNS~ DCC8"'l,("b S V\-,\:1-'l8-c3 5
06 4(., voc"gtc,~ 2.5I'Y\L DCC ICC'""tA J.-Sv I-4: 1--01--01 'f
07 411 2$-11+--02-tJ I l t\ .f" ..; DCC.(.c..M $VI-4.I-iS"-o) 1
08 4S ~ -Q~~ ~ J, j ./ BFB '\1.-ClI ) . ,tlIh1fJ
txJ 09 4 C\ 1:?'E-ll q -0 l:l:. t'l,S""WI.L ?~ .,j J IS/SURR. et"t-Ol S-f » ./ ICV/LCS~ isVl-4'l. _n-'"!::t'1.. I -I 10 '0\) I -04-1: otS"lM\...-SV V ("') I
:::r: 11 1'5"1 -~I-M.f\'\\'-tj"O .,j .; ICV/lCS~ ISvl-·H-'J-!!I-(j I -:r
~ 12 C)')... J/ -O'J:.. \ DW'L 2..S ,; ..; ICV /LCSlc..€1AA SVl-4:z.-0'l -t>3 -("' f
0 13 S3 1.-:kll1--o'1:L \ 0 WlL 'IS v' .,f ICV/LCS~~ &"I-4I-~~r03 S-/ .,..
rr1 14 ~A-L?t:.\ ~S-O~ 1SML \ l~ V ..; Data File Folder 2~E:l~
~ 15 C:j~ \ -01 ./ ./ LOT II Syringe Lot II
~ 16 % \ -o?-V ../ pH strip \{C2.l oi;O t-{SV--{j 1-o4-{h
17 '5<\ -~~ / / Chlorine strip l.?'HOlS I J. -(J L,.f)f -0 f" -cA ..
18 5<S ,J/ -cA v' / Methanol
19 1'jQ 1--'lJEH.4.--L~ ./ -/ NaHSO,
20 ~~ I -\4-V ,) Reagent Water l2-W ~ -1...1.r004
21 tu\ J,--\,\ v ,/ Sand
22 1Dl. 1?,et3t? 4llk J ./ Electronic Data Archival Locatien Date
23 ~~ J.., -OIS V ./ HPCHEM VOA/TOO6 r;/lqh~
24 IA-2.~£"tl4-u /Lf v ./ Comments:
25 ~5 J.; -\.\S Iv \V V ./
26 \.V tp~ ~V (\{)c.,FI~Il4-I q',oro
27 --"
28 ~
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30 <... A\{ S" ( \ if I (.,~ Date Disposed: SI t 1 {7/?' Disposed By: ~ REPORT ID: 23E135 Page 143 of 454
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I Page 75
STANDARDS LOG FOR VOLATILES
Book No: SVl-35
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REPORT ID: 23E135 Page 145 of 454
I
,~ Page 16
~ STANDARDS LOG FOR VOLATILES , ,
I Book No: SVl-36
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.,~ Page 20
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Ii STANDARDS LOG FOR VOLATILES
t"·:· ['0:
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I ,-Page 31
; STANDARDS LOG FOR VOLATILES
I Book No: SVl-36
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Page 66
STANDARDS LOG FOR VOLATILES
I Book No: SVl-36
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SV1-36-66,-01
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Page 68
STANDARDS LOG FOR VOLATILES
Book No: SVl-36
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SV 1-36-68-01
W\-,,0-OI..l-01 «'2..ftlO mt4ttWlilC 1.. 000 ppM 1WML $0 P,W! Name ~ZbO (Zf;)
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STANDARDS LOG FOR VOLATILES
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I Page 29
STANDARDS LOG FOR VOLATILES
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Book No: SVl-37
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REPORT ID: 23E135 Page 187 of 454
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Book No: SVl-37
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REPORT ID: 23E135 Page 188 of 454
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Book No: SVl-37
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REPORT ID: 23E135 Page 189 of 454
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Book No: SVl-37
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REPORT ID: 23E135 Page 190 of 454
r Page 34
STANDARDS LOG FOR VOLATILES
Book No: SVl-37
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REPORT ID: 23E135 Page 191 of 454
I Page 35
STANDARDS LOG FOR VOLATILES ,..~
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REPORT ID: 23E135 Page 192 of 454
I Page 36
STANDARDS LOG FOR VOLATILES
Book No: SVl-37
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REPORT ID: 23E135 Page 193 of 454
RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Gravimetric Certificate
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
• ISO 11034A .... edKed
R&fer&otW ,.,.bt~ldl PfoducQr
CQl'tific..lt& ;32220l
~ .. " ~ rACC'RED'IT'EDl
IsonEC 17025 Accredited
Testing lab3riltofy
CQrtifloto f 3222.02
Catalog No. : 556476 Lot No.: A0155119 6 VI-3D -64-00
Description: Custom 1.2.3-Trichloropropane-c.I5 Standard
Custom 1.2.3-Trichloropropane-d5 Standard 1,OOOll9/mL, P& T Methanol,
1mLlampui
Container Size: 2 mL Pkg Amt: > 1 mL ~~--------------------------------Expiration Date: November 30, 2022 Storage: O°C or colder
CERTIFIED VALUES
-. Compound' .. . - -
.---cGrav. Cont. - .
(weight/volume)
Expanded tlncertainty - - -
1,2,3-Trichloropropane-d5
CAS # 203578-27-2 (Lot PR-14307)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
."·:;~;t. 1-";j<~4
La':'e Klbe -Mix Technician Date Mixed: 15-Nov-2019
1,000.0 Ilg/mL
Balance: 1127510105
(95% C.L.; K=2)
+/-10.0737
+/-56.6693
+/-57.9677
Gravimetric
Unstressed
Stressed
Manufactured under Restek's ISO 9001 :2008
Registered Quality System
Certificate #FM 80397
Page 1 of2
REPORT ID: 23E135 Page 194 of 454
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/jJECD,
GC/MS, LC/MS, RI, and/or melting point.
• Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
Purity of isomeric compounds is reported as the sum of the isomers.
Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k U;ralJim.etric + U~om.ogeneity + U;torage stability + U;hipping stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
..-:-._.
label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
1DoC or colder (Refrigerate) <40°C ~ 40°C up to 7 days
DOC or colder (Freezer) < 25°C <:: 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
• Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
• Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
Page 2 of 2
REPORT ID: 23E135 Page 195 of 454
/' ;;:., RESTEK0 CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30224
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PlUOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0146953
Description : Toluene-d8 Standard
Toluene-dB 20001.lg/mL, P& T Methanol, 1 mUampul
Container Size: 2 mL ------------------Pkg Amt: > 1 mL -----------------Expiration Date: March 31, 2024 Storage: O°C or colder
~ ..
Ii'C'CREDIT'iD)
ISO 11034 Aeuedfted
Ref@TtoceMJtel!ilf'foductr
CMifICJteU22.2.01
'",~ a
IsonEC 17025 Accredited
resting Labor.lory
(Qrti1iate i3222.02
CERTIFIED VALUES
Compound
Toluene-d8
CAS # 2037-26-5
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
(Lot PR-30245)
Grav. Conc.
(weight/volume)
2,018.0 flg/mL
Expanded Uncertainty
(95% C.l.; K=2)
+/-11.8428
+/-113.1587
+/-115.8060
Gravimetric
Unstressed
Stressed
REPORT ID: 23E135 Page 196 of 454
Column:
105m x 0.53mm x 3.01lm
Rtx-502.2 «at.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ SOC/min. (hold 5 min.)
Inj. Temp:
200"C
Oet. Temp:
250"C
Oet. Type:
FID
M"YJ1'f W:";r
Maggie Wang -operations-"'r-eC-hn-'C-ian-'
~*' ~ -P.a;.1O'
Jennifer Pollino -Operations Tech·ARM QC
o 5 10 15
Minu1es
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 12-Mar-2019
Date Passed: 18-Mar-2019
Balance: 1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E135 Page 197 of 454
General Certified Reference Material Notes
Expiration Notes:
• Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
• Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
• Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/IJECD,
GC/MS, LC/MS, RI, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty. storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Uiravi-rnetric + U~omooeneit:y + U;t:oraoe stability + U;hippino stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
1Q°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
O°C or colder (Freezer) < 25°C ~ 25°C up to 7 days
• Separate (not combined) uncertainty values for graVimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product. when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampUl until the material is completely
dissolved.
REPORT ID: 23E135 Page 198 of 454
125 Ma rket Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Tel [phone]
Fax [phone]
www.AccuStandard.com
Catalog No: M-502C-04
Description: Volatile Organic Compounds
Lot: 218041438-01
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Component
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichloropropane
1,1-Dichloropropene
cis-1 ,3-Dichloropropene "
trans-l ,3-Dichloropropene "
Hexachlorobutadiene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
Trichloroethylene
1,2,3-Trichloropropane
.• Weight compensated to 100% purity.
H 47,8% cis isomer, 46,1% trans isomer
CAS#
96-12-8
106-93-4
107-06-2
78-87-5
142-28-9
563-58-6
10061-01-5
10061-02-6
87-68-3
630-20-6
79-34-5
19-00-5
79-01-6
96-18-4
5 V \~ ,0 ~o{-.."' l b
Date Certified: Jun 18,2020
Expiration: Jun 18, 2023
Sample Size: 1 mL
Components: 14
Storage Condition: Refrig (0-5 ·C)
Certified Reference Material
Purily % Prepared
Concentration'
(GC/MS) (!lg/mL)
95.8 2088'
99.9 2002
99.8 2001
99.5 2002
96.7 2069'
99.9 2001
93.9 2036'
93.9 1964'
98.0 2002
98.9 2001
96.0 2086'
98.6 2001
100.0 2002
97.5 2052'
Certified Analyte
Concentration'
(!lg/mL)
2000
2000
1997
1992
2001
1999
1912
1844
1962
1979
2003
1973
2002
2001
A product with a suffix (-1A. -26. etc. or -01, -02. etc.) on its lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 822-275872-11
, Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen using approximately a 95% confidence level.
Labels and certificates follow U.S. Conventions in reporting numerical values: A comma (.) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal place marker.
The information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Certified By:
Larry Decker, Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/lEe 17025 and certified to ISO 9001 :2015 QR-QRGIlNO-OOl
Rev. 5/18
REPORT ID: 23E135 Page 199 of 454
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers ANAB Certificate Number AR-1463
ISO/l EC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories ANAB Certificate Number AT-1339
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations Certificate Number 3774
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square rool of the total
variance of the uncertainty of the components using the following formula: lIa = II -+ 11(111)" + 11(1 ) -+ (II(R l) -his
formula represents uncertainty components from the mass, volume, short-term tability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims mllst hp. made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 200 of 454
·.);( .. Agilent ... Certificate of Analysis
Product Name: Haloalkanes Standard
Product Number: DWM-540-1 Lot Issue Date: 23-Dec-2019
Lot Number: 0006507491 Expiration Date: 31-Jan-2023
Description:
This analytical reference material (RM) was manufactured and verified in accordance with an ISO 9001 registered quality system,
and analyte concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the
95% confidence level for each analyte, determined gravimetrically, is listed below.
Analyte
bromochloromethane
bromodichloromethane
bromoform
bromomethane
carbon tetrachloride
chloroethane
chloroform
chloromethane
dibromochloromethane
1,2-dibromo-3-chloropropane
1 ,2-dibromoethane
dibromomethane
dichlorodifluoromethane
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethene
cis-1,2-dichloroethene
~
ACCREDITED
'8"ri!
REfERENCE MATEmAL
PROOUCER
ISO 17034 Cert No.
AR-1936
CAS# Analyte Lot
000074-97-5 RMOOO09
000075-27-4 RM12585
000075-25-2 RM07516
000074-83-9 RMOO064
000056-23-5 RM07576
000075-00-3 RMOO065
000067-66-3 RM13988
000074-87-3 RM12571
000124-48-1 RM13909
000096-12-8 RM11663
000106-93-4 RMOO018
000074-95-3 RM12878
000075-71-8 RM05289
000075-34-3 RM13775
000107-06-2 RM04655
000075-35-4 RM12062
000156-59-2 RM12063
RM was produced in accordance with TUV USA Inc registered ISO
9001 Quality Management System. Cert # 5610018560026
Page: 1 of 3
www.agilent.com/quality/
CSD-QA-015.1
Concentration ± Uncertainty
200.9 ± 1.0 iJg/mL
200.9 ± 1.0 iJg/mL
201.0 ± 1.0 iJg/mL
200.2 ± 1.0 IJg/mL
201.0 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.4 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 1J9/mL
200.9 ± 1.0 iJg/mL
200.8 ± 1.0 iJg/mL
200.8 ± 1.0 IJg/mL
200.6 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
201.0 ± 1.0 1J9/mL
200.9 ± 1.0 1J9/mL
~
ACCREDITED
1¥I'".ith&
TESTING l ABORATORV
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E135 Page 201 of 454
Certificate of Analysis
Product Number: DWM-540-1 Lot Number:
trans-1,2-dichloroethene 000156-60-5 RM07565
1,2-dichloropropane 000078-87-5 RM12821
1,3-dichloropropane 000142-28-9 RM09825
2,2-dichloropropane 000594-20-7 RM12927
1,1-dichloropropene 000563-58-6 RM15884
cis-1,3-dichloropropene 010061-01-5 RM12891
trans-1,3-dichloropropene 010061-02-6 RM12254
hexachlorobutadiene 000087-68-3 RM09157
methylene chloride 000075-09-2 RM11650
1,1,1,2-tetrachloroethane 000630-20-6 RM12632
1,1,2,2-tetrachloroethane 000079-34-5 NT00390
tetrach loroethene 000127-18-4 RM06491
1 ,1 , i-trichloroethane 000071-55-6 RMOO027
1,1,2-trichloroethane 000079-00-5 RM01175
lrichloroethene 000079-01-6 f-{MOOO29
trichlorofluoromethane 000075-69-4 RMOO017
1,2,3-trichloropropane 000096-18-4 RM09131
vinyl chloride 000075-01-4 RM05458
Matrix: methanol (methyl alcohol)
Storage Conditions: Store Frozen (-25° to -10°C).
Traceability:
0006507491
201.0 ± 1.0 IJg/mL
200.9 ± 1.01Jg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.7 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.6 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
201.0 ± 1.0 IJg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
~
ACCREDITED
-~-__ Wib.i§
A€F"EAENC£ MATERIAL
PRODUCER
ISO 17034 Cert No.
AR-1936
R~v1 v"as produced in accordance with TUV USA Inc registered iSO
9001 Quality Management System. Cert # 5610018560026
Page: 2 of 3
www.agilent.comfquaiityi
CSD-QA-015.1
~
ACCREOITED
--_._-LliiiGW&&
n,STlNG I ABORJ\TORY
ISO 17025 Cert
No. AT-1937
REPORT ID: 23E135 Page 202 of 454
•• : e' A "I .. }:~~.. gl ent ... Certificate of Analysis
Product Number: DWM-540-1 Lot Number: 0006507491
Homogeneity:
This RM was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is no minimum sub-sample
Intended Use:
This RM is intended for the preparation of working reference samples for use in routine laboratory analyses, calibration of
instruments, validation of analytical methods, assessments of measurement methods, and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above, provided the RM is handled and stored in accordance
with the instructions given in this certificate. This certification is nullified if the RM is damaged, contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
ACCREDITED -REFERENCE MA.TERIAL
PROOUCER
ISO 17034 Cert No.
AR-1936
RM was produced in accordance with TUV USA Inc registered ISO
9001 Quality Management System. Cert # 56100 18560026
Page: 3 of 3
www.agilent.comlqualityl
CSD-QA-015.i
Sample lot approver:
~Qo.lA2fORIO
Monica Bourgeois
QMS Representative
~
ACCREDITED
w"iin'(f
TESTING lABORATORY
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E135 Page 203 of 454
~ ~ .... RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30003
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description : VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,OOO~g/mL, P&T Methanol, 1mLlampui
Container Size: 2 mL ---------------------PkgAmt: ___ > __ 1_m_L __________ ___
Expiration Date: September 30, 2024 Storage: O°C or colder
~.
(ACC'REDIT"'iOI
ISO 11034 Aa:redfted.
Refer~ MltQllal Pfoducer
(QI1ifiQtQ Om.01
~.
(ACCiED".T]iiJ
ISOnEC 17021i Accredited
Testing ubofarory
Certif\ate-#322202
CERTIFIED VALUES
Compound
I-Bromo-4-fluorobenzene (BFB)
CAS # 460-00-4 (Lot 2040 1 KO)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Grav. Conc.
(weight/volume)
5,030.0 Ilg/mL
Expanded Uncertainty
(95% C.L.; K=2)
+/-29.5189
+/-'282.0557
+/-288.6541
Gravimetric
Unstressed
Stressed
REPORT ID: 23E135 Page 204 of 454
Column:
105m x 0.S3mm x 3.0~m
Rtx·502.2 (oat.#1091O)
Carrier Gas:
hydrogen-constant pressure 11,0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ 8'C/min. (hold 5 min.)
Inj. Temp:
200'C
Oet. Temp:
250'C
Oet. Type:
FID
Walker Workman -Operations Technician I
o 5 10 15 20 25 30
Minutes
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 27·Jun-2019
Date Passed: 0 I·Jul·20 19
Balance: 1128342314
Manufactured under Restek's ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E135 Page 205 of 454
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/IJECD,
GC/MS, LC/MS, RI, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetriC uncertainty, homogeneity between-ampUl uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Uiral1imetric + U~omoge71eity + U;torage stabiHty + U;hipping stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
• Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) <60°C ~ 60°C up to 7 days
10°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
O°C or colder (Freezer) <25°C ~ 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetriC uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampUl until the material is completely
dissolved.
REPORT ID: 23E135 Page 206 of 454
I Page 37
STANDARDS LOG FOR VOLATILES
Book No: SVl-37
I Parent ID Parent Standard Name Cone. Aliquot Final Cone.
tN1 /'?{) -u1-~", ( ~~;'''-LnL \.A-t 1-<W"'-o~ ~vt ~I?P"'"
Standard ID SVl-37-37-01
Name Tt,/ ~S (r;>A .. 2--)
[1,"\.1-~ /' / \ I Final Volume 'l-_v...,c
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-/ Prep. Date t{ i:JJ-./ pi
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Exp. Date
Prepared By oAl
/' \r;I-'
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Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-37-37-02
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.\,r A\ n C~.} ~ LlI'Y" Wi Ii" l \ 1/ 1'1 I Name rS/~f-(r,,··cd
Final Volume 2..o.--t-
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Exp. Date "j 2.')---( ~
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1("" -1,~ -\1. .... -(4 V ~ ~ A n \-7v(<..-1r~ i~ 1X'O' I Standard ID
Name
1/ z.~-~-01" 'vui: Lr-u c,~ ·~o \~ 1--
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Final Volume
MeOH Solvent ID
Prep. Date ---I---' ----I Exp. Date
Prepared By
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I ~ ~a.r J-\j ~
REPORT ID: 23E135 Page 207 of 454
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STANDARDS LOG FOR VOLATILES
Parent ID Parent Standard Name Cone. Aliquot Final Cone.
4v1 .... ?#-tv ...{~ fU;o T~ """,0-0 V"" 4 0 /-va ~f"'1
1. -Ii -(Lf N0~ o;;i{f-~ .c ! I
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Book No: SVl-37
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Book No: SVl-37
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STANDARDS LOG FOR VOLATILES
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1 STANDARDS lOG FOR VOLATilES
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Book No: SVl-39
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Book No: SVl-39
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Book No: SVl-39
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I Page 33 ,
STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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Page 69
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STANDARDS LOG FOR VOLATILES
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STANDARDS lOG FOR VOlATilES
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REPORT ID: 23E135 Page 376 of 454
Page 78
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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Page 2
STANDARDS LOG FOR VOLATILES
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REPORT ID: 23E135 Page 378 of 454
Page 85
STANDARDS lOG FOR VOlATilES
Book No: SVl-41
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REPORT ID: 23E135 Page 379 of 454
Page 76
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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REPORT ID: 23E135 Page 380 of 454
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REPORT ID: 23E135 Page 381 of 454
Page 68
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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REPORT ID: 23E135 Page 382 of 454
Page 73
STANDARDS lOG FOR VOLATILES
Book No: SV1-41
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REPORT ID: 23E135 Page 383 of 454
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Book No: SVl-41
Standard ID SV1-41-25-01
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REPORT ID: 23E135 Page 384 of 454
Page 3
STANDARDS LOG FOR VOLATILES
Book No: SVl-42
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-42-03-01
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REPORT ID: 23E135 Page 385 of 454
Page 65
STANDARDS lOG FOR VOlATILES
Book No: SVl-41
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REPORT ID: 23E135 Page 386 of 454
CPI
Date manufactured: 5/5/2022
Original issue date: 5/5/2022
Catalog No.: Lot No.: Storage:
Z-G34 481102 :S -10 oc
-020200-04
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
PIT Methanol
Expiration
Date:
4-May-2027
Carbon Disulfide Solution, 5,000 mg/L, 1 ml
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, m!!IL
carbon disulfide 75-15-0 99.9 200.24.1P 5044 ± 250
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS.' It may aslo be used for various US EPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for .
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-O:OI8ln(x+31) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E135 Page 387 of 454
Certificate of Analysis Page 2 of 2
Catalog No.: Z-034-020200-04 Lot No.: 481102 Expiration Date: 5/4/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-011. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc= ...fL,u;2 where U; are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 4-May-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Paul Johnson
Quality Control Supervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 388 of 454
CPI
INTERNATIONAL
Date manufactured: 11/16/2022
Original issue date: 11/16/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
Z-034 492307 ::::: -10 oc PIT Methanol
Expiration
Date:
20-Nov-2025 Vinyl Acetate Solution, 2,500 mg/L, 1 mL
-020232-10
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mt!IL
vinyl acetate 108-05-4 99.9 232.7.1P 2496 ± 160
•Not a ctrtified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCJMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCJMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y"3·202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E135 Page 389 of 454
Certificate of Analysis Page 2 of 2
Catalog No.: Z-034-020232-10 Lot No.: 492307 Expiration Date: 11120/2025
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-011. This is consistent with the intended use ofthis CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc = ~Iui 2 where ui are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 20-Nov-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association ofLaboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist II
Certified By:
Dominique Lindner
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 390 of 454
Trusled ;\tlswt:r:;
Product Name: VOC Gas Standard
Product Number: DWM-544-1
Reference Material Certificate
Product Information Sheet
Storage Conditions: Store Frozen (-25° to -1 0°C).
chloroethane 2006 ± 10 ~g/ml
chloromethane 2009 ± 10 ~glml
dichlorodifluoromethane 2009 ± 10 ~g/ml
trichlorofluorometl:l~ne-2008 ± 10 ~g/mL
vinyl chloride 2010 ± 10 ~g/ml
Matrix: methanol (methyl alcohol)
Description:
ISO 17034
Lot Number: 0006685354
Lot Issue Date: 13-Jun-2022
Expiration Date: 31-Jul-2025
000075-00-3 RM00065
.000074"87-3 RM12571
000075-71-8 RM05289
0.00075-69-4 RM00017
000075-01-4 RM05458
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Traceability:.
The balances used for these measurements are calibrated with weights traceable to NI~3T in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delayfor the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Page: 1 of 2
CSD-QA-015.1 ISO 17025
REPORT ID: 23E135 Page 391 of 454
Agilent
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
~~~F!!_;~~~i~~!!i;i0:'!:~ii!~.~~~~; :~~::~:~'-;!
ACCAlZOITE:;;:D
·-··~-~-----···-
ru:F{:IIf:NCt.MI\"TI:fiiJ\l.
f.lllOUUCf.H
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV/SUD registered ISO
9001:2015 Quality Management System. Cert# 951215321
Page: 2 of 2
www.agllent.com/quality/
CSD-QA-015. 1
Sample lot approver:
/t:\(2
U(( ti '2 0 0 LA<f1? {)_u_c)_
Monica Bour·geois
Qi\115 R{:"!presentativr~
ISO 17025
REPORT ID: 23E135 Page 392 of 454
CPI~
lNTERNATIONAL
Date manufactured: 4/14/2022
Original issue date: 4/14/2022
Catalog No.: Lot No.: Storage:
Z-G34 479712 ::;-lO"C
-126047-01
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
6VI -6o-O/-oo
Certificate of Anal • SIS Date Received:
Page 1 of 5 Rev 0
Solvent:
Pff Methanol
Expiration
Date:
16-0ct-2023
Description:
Custom Volatiles Mix, 73-6047, Various
Concentrations, 1 mL
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mi!/L
2-nitropropane 79-46-9 97.7 219.7.1P 2003 ± 110
ally I chloride 107-05-1 98.9 227.1.2P 1995 ± 120
benzene 71-43-2 99.99 146.1.9P 2003 ± 110
bromobenzene 108-86-1 100 147.7.1P 2000 ± 140
bromochloromethane 74-97-5 99.7 148.1.3P 2008 ± 110
bromodich1oromethane 75-27-4 98.7 149.1.11P 1996 ± 110
bromoform 75-25-2 99.3 150.7.2P 1995 ± 110
n-buty !benzene 104-51-8 99.2 151.7.3.2P 1984 ± 110
sec-butylbenzene 135-98-8 99.5 152.1.2.1P 2007 ± 110
tert-buty1benzene 98-06-6 99.9 153.29.1P 2004 ± 110
carbon tetrachloride 56-23-5 100 154.9.1P 2005 ± 110
chlorobenzene 108-90-7 99.9 155.29.1P 2008 ± 110
2-chloroethanol 107-07-3 98.5 217.1.2.1P · 2006 ± 120
chloroform 67-66-3 99.8 156.7.1P 1998 ± 110
chloroprene 126-99-8 98.9 315.5.22P 1982 ± 140
2-ch1orotoluene 95-49-8 99.5 157.7.1P 2014 ± 110
4-chlorotoluene 106-43-4 99.9 158.9.3P 2015 ± 110
REPORT ID: 23E135 Page 393 of 454
Certificate of Analysis Page 2 of 5
Catalog No.: Z-034-126047-01
cis-! ,2-dichloroethy lene
dibromochloromethane
1,2-dibromo-3-chloropropane
I ,2--dibromoethane
dibromomethane
1 ,2-dichlorobenzene
I ,3--dichlorobenzene
1,4-dichlorobenzene
cis-! ,4--dichloro-2-butene
trans-! ,4-dichloro-2-butene
I, 1-dichloroethane
I ,2-dichloroethane
I, 1-dichloroethylene
trans-! ,2-dichloroethylene
dichlorofluoromethane (Freon 21)
I ,2-dichloropropane
I ,3-dichloropropane
2,2-dichloropropane
I, 1-dichloropropylene
cis-! ,3-dichloropropylene
trans-! ,3-dichloropropy Jene
I ,4-dioxane
ethyl ether
ethyl methacrylate
ethylbenzene
Manufactured By:
Brian Stokes
Production Chemist I
LotNo.: 479712
156-59-2 98.5
124-48-1 98.6
96-12-8 98.6
106-93-4 99.9
74-95-3 99.8
95-50-1 99.8
541-73-1 99.8
106-46-7 99.9
1476-11-5 96.2
110-57-6 98
75-34-3 98.1
107-06-2 99.9
75-35-4 99.98
156-60-5 99.7
75-43-4 98
78-87-5 99.7
142-28-9 100
594-20-7 99
563-58-6 99
10061-01-5 99.5
10061-02-6 99
123-91-1 99.93
60-29-7 99.8
97-63-2 99.5
100-41-4 100
Certified By:
Tyler Sherman
Quality Control Chemist I
Expiration Date: 10/16/2023
!66.1.7.1P 2000 ± 110
159.1.8.1P 2001±110
160.7.2.3P 1999 ± 110
161.9.1P 2002 ± 110
162.1.2P 2012 ± 120
43.7.1P 2006 ± 110
44.1.2P 2008 ± 110
45.29.1P 2030 ± 110
209.1.4.1P 1966 ± 110
20!.1.17P 1996 ± 110
!63.247.3.2P 1985 ± 120
!64.!58.1P 2001 ± !10
165.1.4P 2001 ± 110
167.9.!P 2000 ± 110
986.5.4P 1960 ± 140
168.8.l.IP 1994 ± !20
169.7.3P 2034 :1:140
170.158.1.1P 1999 ± 120
171.1 58.2.3P 1999 ± 120
172.7.6.1P 2003 :1: 110
173.7.11P 2002 :1: 110
223.1.4P 39940 ±2000
226.9.1P 1993 :1: 110
216.7.1P 2037 :1: 110
174.7.1P 2001 :1: 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 394 of 454
Certificate of Analysis Page 3 of 5
Catalog No.: Z-034-126047-01
hexachlorobutadiene
iodomethane
isobutyl alcohol
isopropylbenzene
4-isopropyholuene
methyl acrylonitrile
methyl methacrylate
methyl acrylate
methylene chloride
naphthalene
nitrobenzene
propionitrile
n-propylbenzene
styrene
I, I, I ,2-tetrachloroethane
I, 1,2,2-tetrachloroethane
tetrachloroethylene
tetrahydrofuran (THF)
toluene
1 ,2,3-trichlorobenzene
1,2,4-trichlorobenzene
1, 1,1-trichloroethane
1,1 ,2-trichloroethane
trichloroethylene
1 ,2,3-trichloropropane
Manufactured By:
Brian Stokes
Production Chemist I
LotNo.: 479712
87-68-3 98
74-88-4 99.9
78-83-1 100
98-82-8 98.9
99-87-6 99.9
126-98-7 98
80-62-6 99.8
96-33-3 99.9
75-09-2 99.99
91-20-3 99.8
98-95-3 100
107-12-0 99.8
103-65-1 99.7
100-42-5 99.5
630-20-6 99.8
79-34-5 99.6
127-18-4 100
109-99-9 99.99
108-88-3 100
87-61-6 99.8
120-82-1 99.6
71-55-6 99.6
79-00-5 99.6
79-01-6 98.1
96-18-4 99.5
Certified By:
Tyler Sherman
Quality Control Chemist I
Expiration Date: 10/16/2023
47.158.3.1P 2003 ± 120
203.29.2P 2000 ± 110
220.7.2P 39730 ± 2000
176.9.1P 1998 ± 120
177.9.3P 1998 ± 110
212.286.1.1P 19960 ± 1100
231.7.3P 2016 ± 120
349.1.1P 2015 ± 120
178.271.1P 2010 ± 110
26.9.1P 1996 ± 110
94.7.1P 1985 ± 110
218.7.3P 19900 ± 1000
179.7.2.2P 1999 ± 110
180.9.4P 2001 ± 110
181.7.2.9P 2005 ± 110
182.1.3P 2001 ± 120
183.1.2P 2001 ± 110
299.271.2P 2006 ± 110
184.48.1P 2003 ± 110
185.1.2P 1996 ± 110
54.29.1P 1992 ± 110
187.247.1.3P 1995 ± 110
195.7.1.6P 2001 ± 110
188.29.1P 1998 ± 120
189.1.3P 2009 ± 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 395 of 454
Certificate of Analysis Page 4 of 5
Catalog No.: Z-G34-126047-0l Lot No.: 479712 Expiration Date: 10/16/2023
I, I ,2-trichloro-1 ,2,2-trifluoroethane (Freon 113) 76-13-1 99 270.158.3P 1996 ± 120
1 ,2,4-trimethylbenzene 95-63-6 98.7 190.7.1P 1974 ± 110
1 ,3,5-trimethylbenzene 108-67-8 99.5 191.7.1P 1962 ± 110
m-xylene 108-38-3 99.7 193.7.1.2P 2001 ± 110
o-xylene 95-47-6 99 192.29.3P 2004 ± 120
p-xylene 106-42-3 99.9 194.7.1P 1998 ± 110
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+3l) + 0.1157) + 636.54y·3·202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. L S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
'JYler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 396 of 454
Certificate of Analysis Page 5 of 5
Catalog No.: Z-034-126047-01 Lot No.: 479712 Expiration Date: 10116/2023
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Instituie of Standards and Teclmology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc =the combined uncertainty Uc = ...f"Lu;2 where U; are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 16-0ct-2023
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 397 of 454
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: OGAD-001
Description: Oxygenate Gasoline Additive Standard
Lot: 222011266
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Component
MtBE
EtBE
Isopropyl ether
TAME
t-Butanol
Signal Word: Danger
CAS#
1634-04-4
637-92-3
108-20-3
994-05-8
75-65-0
Date Certified: Jan 19, 2022
Expiration: Jan 19, 2025
Sample Size: 1 mL
Components: 5
Storage Condition: Refrig (0-5 °C)
Certified Reference Material • ~""'~-
AR·1463
Purity%
Tel [phone]
Fax [phone]
www.AccuStandard.com
Certified Analyte
Concentration•
(iJg/mL)
1997
2002
2010
1983
9965
This Certified Reference Material was verified 1~·-a~an®..\iit~ ISO/IEC 17025
A product with a suffix (-1A. -2B, etc. oP01;.:..02, ete;)'~jjtii!'fot number has had Its expiration date extended and is identical to the same lot number without the ~uffix.
• All weights are traceable through Nt~T, Te~t Nq;~s84i2S9871·17
' Certified Analyte Concentration = Pii.tJ!Y: x Prep~~d Concentration.
The Uncertainty associated wiili'!Jiii'ce·~tiii~ifliidrii:~ntratlon reported on this certificate is :t2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard devlatiQn equal to ll!a 'pi>sl!ive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 Is chosen usiri~:.l!pproxii'ii_iitely a 95% confidence level.
Labels and Cl11'\l!IQI1tes follow.V.~, CoOYenUons In reporting numerical values: A comma (,)Is used to separate units of one-thousand or greater. A period (.)Is used as
a decimal p'ia'c-&htlilter-· .,_, .. · ·· · ·
The lnforrriati~il jln this ~rilfit:ate may not be reproduced wHhout the express permission of the manufacturer. Sea reverse side for additional information
Hazard lnform~ii: p]ijj!~~ fui~r to the SDS for Information regarding the hazards associated with using this material.
This product was:J!ti\~ared according to In-house procedures and Is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, JSOJIEC 17025 and certified to ISO 9001:2015 OR-QRGJIN0-001
Rev. 7/20
REPORT ID: 23E135 Page 398 of 454
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the. front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product Is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u8 = .f(u(V))2 + (u(m))2 + (u(JV))2 + (u{R0))2 This
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 Is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 399 of 454
~PI
INTERNATIONAl.
Date manufactured: 8/24/2022
Original issue date: 8/24/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
(707)545-790 1 Fax
Certificate of Anal sis Date Received:
Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-G34 492308 ::::-10 oc
Date:
23 -Aug-2027 2-Chloroethyl Vinyl Ether Solution, 2,000 mg/L, l mL
Pff Methanol
-020145-02
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound
CAS No. Purity(%) Neat Material Lot No. Concentration, mi!'IL
2-chloroethylvinyl ether
110-75-8 99.8 145.1.5P 2010 :1: 110
•Nota certified volue
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various US EPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+3l) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E135 Page 400 of 454
Certificate of Analysis
s v t--38~o~-n./
Page 2 of 2
Catalog No.: Z-034-020145-02 Lot No.: 492308 Expiration Date: 8/23/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=Iru.,: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, U 0 =the combined uncertainty Uc = --JL,llt 2 where lit are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Aug-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By: Certified By: Released By:
h-b C0U S~M~
Sanquetta Coakley Dominique Lindner Susan Mathews
Production Chemist I Quality Control Chemist I Quality Control Team Lead
REPORT ID: 23E135 Page 401 of 454
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-8010R-1-04-10X
Description: 1-Chlorohexane
Lot: 221031011
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Signal Word: Danger
Component
1-Chlorohexane
This Certified Reference Material was verified ~~:W~an~;~ ISO/IEC 17025
Date Certified: Mar 3, 2021
Expiration: Mar 3, 2031
Sample Size: 1 mL
Components: 1
Storage Condition: Ambient (>5 oc)
Certified Reference Material
Tel [phone]
Fax [phone]
www.AccuStandard.com
A product with a suffix (-1A, -28, etc. 0r ~~1;~. ~t~¥6,iH(~itot number has had Its expiration data extended and Is ldantlcel to the same lot number without the suffix.
• All weights are traceable through NISJ; Te-~t l'!q; ~s4i2s9B7H 7
. ' Certified Analyte Concentration " Pofitii¥ Prep~~d Concentration.
The Uncertainty associated wli!i ~'certlfliid' ®hcimtration reported on this certificate Is :1:2.4%. This value is the combined expanded uncertainty and represents an
estimated standard devlattOj(equal to.the paiiiilve square root of the total variation of tha uncertainty of components. A normal distribution Is assumed and a coverage
factor of Ko:2 Is chosen usti\iJ,approxfni!liety a 95% confidence level.
Labels and Ciirtlfltates follow,iJ.:a, Cliiwentions In reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period(.) Is used as
a decimal piii'ilii mai-l!eJ; ·.· .· ... ·.· .. . .
The lnformalioiJ,'on thiS..~)'tlfi!;l!la may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard lnform~ii6:n; Pt~ilse refer to the SOS for Information regarding the hazards associated with using this material.
This product was''pi:ilpared according to In-house procedures and Is guaranteed to ba homogeneous.
Certified By:
Larry Oecl<er, Organic QC Manager
Page 1 of 1 • Rev. 1
For use In routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001:2015 OA·OAG/INCHl01
Rev. 7/20
REPORT ID: 23E135 Page 402 of 454
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated dally using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the. front of this certificate. Class A glassware
is used in the manufacture and quality control of ail standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on !tm label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .{(u(V))l + (u(m))2 + (u(IV))2 + (u(RO))l I his
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 403 of 454
CPI
INTERNATI.ONAL
Date manufactured: 6/24/2022
Original issue date: 6/24/2022
Catalog No.: Lot No.: Storage:
Z-034 484154 :::-10 oc
-020869-08
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 2 Rev 0
Solvent:
Prr Methanol
Expiration
Date:
23-Jun-2027
Description:
1,2,3-Trimethylbenzene Solution, 2,500 mg!L, l mL
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography ( GC) or gas chromatograph/mass spectrometry ( GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, m!!IL
1 ,2,3-trimethylbenzene
526-73-8 92.7 869.8.4.1P 2536 ± 140
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various US EPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled% change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y'3202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -1 0 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E135 Page 404 of 454
Certificate of Analysis
~vt'"~og--L8
Page 2 of 2
Catalog No.: Z-034-020869-08 Lot No.: 484154 Expiration Date: 6/23/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty uc = -YI.U; 2 where u; are the individual
uncertainty components for characterization, transportation, homogeneity, andshelflife.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Jun-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 405 of 454
CPI
INTERNATIONAL
Date manufactured: I 0115/2020
Original issue date: I 0/15/2020
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • Date Received:
SIS Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-034 426643 S -1 0 Degrees
c
Pff Methanol
Date: 14-0ct-2025 t-Butyl Alcohol Solution, 50,000 mg!L, l mL
-020511-06
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mi!IL
2-methyl-2-propanol 75-65-0 99.8 511.7.1P 49900 ± 2500
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E135 Page 406 of 454
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020232-10 Lot No.: 476834 Expiration Date: 3/6/2025
(95% confidence) values listed are detennined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is detennined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perfonn daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
continued by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc = ..JL,U; 2 where ui are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short tenn and long tenn testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Mar-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 407 of 454
CERTIFIED REFERENCE MAT~~~-~~~---. ·-··-·--·~.so~· ~
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30006
Certificate of Analysis
-·"· ·. ,,.
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0183812
Description : VOA Calibration Mix #1
VOA Calibration Mix #1 5,0001-Jg/mL, P& T Methanoi/Water(90:1 0),
1mL/ampul
Container Size : 2 mL ------------------Pkg Amt: > 1 mL -----------------
Expiration Date : July 31, 2025 Storage: ooc or colder
---------------------Ship: Ambient
~Motorl>lfrodUcil'
Ca:tifi<atU321l.OI
CERTIFIED VALUES
,,~, .Gray, C.o.nc. . . ! ·"· E.xpan~e_d Uncertainty -·
·. (weight/volume) (95% C.L.; K=2)
Acetone 5,031.8 Jlg/mL +I-29.2555 Jlg/mL Gravimetric
CAS# 67-64-1 (Lot SHBN366!) +I-303.5928 )lg!mL Unstressed
Purity 99% +I-304.3136 JlglmL Stressed
2 2-Butanone (MEK) 5,041.0 )lglmL +I-29.3088 )lg!mL Gravimetric
CAS# 78-93-3 (Lot SHBN2844) +I-304.1459 )lg/mL Unstressed
Purity 99% +I-304.8680 )lg/mL Stressed
3 4-Methyl-2-pentanone (MIBK) 5,041.5 Jlg/mL +/-29.3117 )lg/mL Gravimetric
CAS# 108-10-1 (Lot SHBN3601) +I-304.1760 )lg/mL Unstressed
Purity 99% +I-304.8982 Jlg/mL Stressed
4 2-Hexanone 5,026.8 )lglmL +I-29.2264 JlglmL Gravimetric
CAS# 591-78-6 (Lot MKCM4072) +I-303.2911 )lg/mL Unstressed
Purity 99% +I-304.0112 )lg/mL Stressed
Solvent: P &T Methanol/Water (90: I 0)
CAS# 67-56-117732-18-5
Purity 99%
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E135 Page 408 of 454
Cok.!~!l=
105m x O.S3m,; x 3.01lm
Rtx·S02.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240'C
fl rC/min. (hold 5 min.)
lnj. Temp:·
200"C
Det. Temp:
2SO'C
DeL Type;.
FlO
Brlttany Federinko-Openrtlons Tech I
Clara WinciJe -Operation5 T..ehnician I
01-Aug-2020 rev.
0 5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 07-Apr-2022
Date Passed: 11-Apr-2022
Balance: B251644995
Manufactured under Reatek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2of3
REPORT ID: 23E135 Page 409 of 454
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-603-M-5X
Description: Acrolein & Acrylonitrile
Lot: 223021463
Solvent: Methanol (90%)
Date Certified: Feb 21, 2023
Expiration: Jun 21, 2023
Sample Size: 1 ml
Components: 2
Tel [phone]
Fax [phone]
www.AccuStandard.com
Water (10%) Storage Condition: Freeze (<-10 °C)
Hazards: Refer to SDS for complete safety information
Component
Acrolein
Acrylonitrile
Signal Word: Danger
CAS#
107-02-8
107-13-1
Certified Reference Material
Purity'%
86.1
99.8
Pr!)pared
Concentration'
/ml
58 0S·
50.10
This Certified Reference Material was verified in accor\i!J'nce with ISbJIEC 17025 (AT-1339) and ISO 17034 (AR-1463)
• Weight compensated to 100% purity. \-~-~·. : : ... \· .. :_\·.
Certified Analyte
Concentration'
/ml
5001
5000
A product with a suffix (-1A, -28, etc. or ;01,.-02;'~\Q;) on:l.~t!·lot number has had Its expiration date extended and Is Identical to the same lot number without the suffix.
' Certified Analyte Concentration = Plifi!y ~'Prapar~lcbri'centratlon.
The Uncertainty associated with the.~jtlfled co.~centratlon reported on this certificate Is ±2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard deviation equal to.l~e posll!v~.· square root of tha total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen using 'iJpproxlriiately a)!5% confidence level.
'All weights are traceabl!lltliough Nl!lT, ·T~~t No. 664/291344·16 & 684/292805-19
' Purity/Identity determined by one or {nora of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and.c~&lfic!iltes follo~{:i:J.i;;.{:<lii~entions
In reporting numerical values: A comma(,) is used to separate units of one-thousand or greater. A period(.) Is used as
a decimal pi~~~ marker. ' . ·.
The lnformaiion on this certincate may not be reproduced without tha express permission of the manufacturer. See reverse side for additional information
Hazard lnformatl()n;.PI.~aserafer to the SDS for Information regarding the hazards associated with using this material.
This product was .. p(epared according to in-house procedures and Is guaranteed to be homogeneous .
. ~:··.'
Certified By:
Page 1 of 1
For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001:2015 OR·ORG/IN0·001
Rev. 7120
REPORT ID: 23E135 Page 410 of 454
1. Quality Standards:
ISO 17034:2016-General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u0 = .f(u(V))l + (u(m))Z + (u(IV))2 + (u{R0))2 I his
formula represents uncertainty components from the mass, volume, short-term stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 411 of 454
CPI~
Date manufactured: 10/4/2022
Original issue date: 10/4/2022
Catalog No.: Lot No.: Storage:
Z-034 489953 :s; -10 oc
-020354-09
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 2
Solvent:
P/T Methanol
Expiration
Date:
3-0ct-2027
Description:
2-Butanol Solution, 50000 mg/L, 1 ml
Rev 0
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, m!!/L
2-butanol 78-92-2 99.8 354.7.JP 50000 ± 2600
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y"3
'
202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E135 Page 412 of 454
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-08S-10X
Description: Cyclohexane
Lot: 219101390
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Signal Word: Danger
Component
Cyclohexane
.->..._
This Certified Reference Material was verified,~:'
CAS#
110-82-7
Date Certified: Oct 25, 2019
Expiration: Oct 25, 2029
Sample Size: 1 ml
Components: 1
Storage Condition: Ambient (>5 °C)
Certified Reference Material
"'"l.'g.:t::--
AR-1463
Tel (203)786·529Q
Fax [phone]
www.AccuStandard.com
A product with e suffix (·1A, -2B, etc. 91!~~~. t number has had Its expiration date extended and Is identical to the same lot number without the suffix.
'All weights are traceable through N~:r~st Np;,664 'a'9s71-17
.
' Certified Analyte Concentration = PW~Y •. ~ Pref.#~d Conceniratlon.
The Uncertainty associated,,~,iftJh
r
r
c
J
'
f
f
i
~
~
~
:
~
i
\
t
e
n
t
r
a
t
i
o
n

report.ed on this certificate Is ±2.4%. This· value Is the combined expanded uncertainty and represents an
estimated standard deviatlil\i;equal to.;f,l)e posi!lve square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 is chosen U~JW:,!'Pproxl\il~el
y
a 95% confidence level.
Labels and.~l·l!f.if;.J'It
e
s

folloW:U$; . .9,#\'~~ntions In reporting numerical values: A comma(,) is used to separate units of one-thousand or greater. A period(.) is used as
a decimal Pf~iili'malkv~. . '.)•f.::i'"".
The fnforma{i~}hl~\iii\
{
~
i
i
l
r
.
t
l
l
j
!
J
.
e

may not be reproduced without the express permission of the manufacturer. See reverse side for additional informalion
Hazard lnform~!!im.l;'f)~~
~
·
'
i
'
l
\
i
~
r

to the SOS for Information regarding the hazards associated with using this material.
This product wa\i~~ared according to in-house procedures and Is guaranteed to be homogeneous.
Certl«ed By:
Larry Decker, Organic QC Manager
Page 1 of 1 -Rev. 1
For use In routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOnEC 17025 and certified to ISO 9001:2015
OR·OR<li1N<J.001
Rev. 7120
REPORT ID: 23E135 Page 413 of 454
1. Quality Standards:
ISO 17034:2016-General Requirements tor the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
s-VI-?Jg---01-n
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side.-This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an 180/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used In the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .f(u(V)F Of (u(m)F + (u(IV))2 + (u(RO))l fhis
formula represents uncertainty components from the mass, volume, short-term ~ability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 414 of 454
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-09S-12.5X
Description: Methylcyclohexane
Lot: 222081 023
Solvent: Methanol
Date Certified: Aug 2, 2022
Expiration: Aug 2, 2032
Sample Size: 1 mL
Components: 1
Tel [phone]
Fax [phone]
www.AccuStandard.com
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 •c)
Signal Word: Danger
Component CAS#
Methyicyciohexane 108-87-2
This Certified Reference Material was verified in acco.rdance with ISO/IEC 17025
Certified Reference Material
Purity%
(GC/FID)
100.0
prepared
Conce!ltr.atlon•
··NstmLt
2538
Certified Analyte
Concentration'
(lJQ/ml)
2538
A product with a suffix (-1A, -28, etc. or -01, -02, etc.) on Its lot number has had Its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test NO. 684/289871-17
1 Certified Analyte Concentration= Purity xPrepared Concentration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen usln·g approximately a 95% confidence level.
Labels and certificates follow U.S. Conventions in reporting numerical values: A comma(,) is used to separate units of one-thousand or greater. A period(.) is used as
a decimal place marker.
The information on this· certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information: Please refer to the SDS for information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001:2015 OR·ORG/IN0·001
Rev. 7/20
REPORT ID: 23E135 Page 415 of 454
1. Quality Standards:
ISO 17034:2016-General Requirements for the Competence of
Reference Material Producers
ISO/I EC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u3 = .f(u(V))2 + (u(m))2 + (u(IV))2 + (u(R0))2 This
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 416 of 454
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
~V\-~q-(0··04
CERTIFICATE OF ANALYSIS
Catalog No: S-6524-0.25X
Description: Methyl acetate
Lot: 222031 007
Solvent: Methanol
Date Certified: Mar 2, 2022
Expiration: Mar 2, 2032
Sample Size: 1 mL
Components: 1
Hazards: Refer to SOS for complete safety information Storage Condition: Ambient (>5 oc)
Signal Word: Danger
Component CAS#
Methyl acetate 79-20-9
This Certified Reference Material was verified in accordance with ISO/IEC 17025
Certified Reference Material
Purity%
(GC/MS)
100.0
Pr~pared
Concentl'atlon•
. <llglmL)
Certified Analyte
Concentration'
(!Jg/ml)
2520
A product with a suffix (·1A, -28, etc. or ·01, -02, etc.)on lis lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 684/289871-17
' Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty associated. With the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen using approximately a 95% confidence level.
Labels and certificates follow,u:s. Con~entions in reporting numerical values: A comma(.) is used to separate units of one-thousand or greater. A period·(.) is used as
a decimal place marker.
The information. on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information; Please refer to the SDS for information regarding the hazards associated with using this materiaL
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic QC Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001 :2015 OR-ORG/INO·OOl
Rev. 7120
REPORT ID: 23E135 Page 417 of 454
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001:2015-Quality Management System-Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u8 = .f(u(V))2 + (u(m))2 + (u(IY))2 + (u(R0))2 This
formula represents uncertainty components from the mass, volume, short-term ~ability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 418 of 454
~ .... RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: (814)353·1309
www.restek.com
Catalog No. : 30003
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description : VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,000~g/ml, P&T Methanol, 1mllampul
Container Size : 2 ml ------------------Pkg Amt: > 1 ml ------------------
Expiration Date : September 30, 2024 Storage: ooc or colder
@;
(A"CC'ieolTi"DJ
ISO i7034·A....,dKed
Refereoc.o ~~~10111 f'roctucar
Certfftclto t~222.0l
... :::,\ '·l···
0
ISOnEC 17025 Acc:rediled
Toi!l~g l>borarory
Certifiote 13222.02
CERTIFIED VALUES
1-Bromo-4-fluorobcnzcne (BFI:l)
CAS# 460-00-4 (Lot 2040 I KO)
Purity 99%
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
Grav. Cone.
(weight/volume)
5,030.0 ~g/mL
Expanded Uncertainty
(95% C.L.; K=2)
+!-29.5189
+I-'282.0557
+/-288.6541
j.tg/mL
J.lg/mL
j.tg/mL
Gravimetric
Unstressed
Stressed
REPORT ID: 23E135 Page 419 of 454
Column:
105m x 0.53mm x 3.0~rn
Rtx·502.2 (cat.l/10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ 8'C/min.(hold 5 min.)
lnj. Temp:
200'C
Oet. Temp:
lSO'C
Oet. Type:
FlO
Walker Workman-Operations technician I
10 15
Minules
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Dale Mixed: 27-Jun-2019
Dale Passed: 01-Jul-2019
Balance: 1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E135 Page 420 of 454
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/(JECD,
GC/MS, LC/MS, Rl, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
Purity of isomeric compounds is reported as the sum of the isomers.
Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Ufiravimetric + U~omogenetty + u;tora 9 e stabHity + u;,;1111 tn9 stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product If it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
10°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
ooc or colder (Freezer) < 25°C ~ 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
• Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
REPORT ID: 23E135 Page 421 of 454
CPI
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
<;v \-~'3 --ol(-o s
Date Received: Date manufactured: 7/13/2022
Original issue date: 7/13/2022 Certificate of Analysis Page 1 of 2 Rev 0
Catalog No.: Lot No.: Storage:
Z-G34 484785
-122455-05
Certified Values:
Solvent:
PIT Methanol
Expiration
Date:
12-Jul-2027
Description:
Method 8260 Internal Standard Mix, 3-30, 2,500
mg/L, I ml
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mi!/L
chlorobenzene-d5 3114-55-4 99.5 128.120.1P 2504 ± 130
I ,2-dichlorobenzene-d, 2199-69-1 99.7 247.29.3P 2514 ± 130
I ,4-difluorobenzene 540-36-3 99.3 129.158.1.2P 2523 ± 140
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled% change per day can be calculated using the following:
%Change= (-0.0 18ln(x+31) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
REPORT ID: 23E135 Page 422 of 454
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-122455-05 Lot No.: 484785 Expiration Date: 7/12/2027
Method of Preparation:
All weights arc traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimctriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
arc checked daily in accordance to in house procedure 02-LB-G-002. Balances arc calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty u 0 = '/'f.u;2 where u; are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 12-Jul-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E135 Page 423 of 454
~ ....
RESTEK
11 0 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30240
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic plus
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0192204
Description : 8260A Surrogate Mix
8260A Surrogate Mix 2,5001Jg/mL, P&T Methanol, 1mUampul
Container Size : 2 mL ~~--------------
Pkg Amt: > 1 mL --~~-----------
Expiration Date: December 31, 2027 Storage: o•c or colder
Ship: Ambient
CERTIFIED VALUES
Expanded
· Elution Compound CAS# Lot# Punty Grav. Cone. Unce11ainty *
Order (weight/volume) (gS% C.L.; K=2)
Dibromofluoromethane 1868-53-7 022013 99% 2,517.6 J.Lg/mL +I-141.4279
2 1 ,2-Dichloroethane-d4 17060-07-0 PR-32845 99% 2,507.6 J.Lg/mL +I-140.8661
3 Toluene-d8 2037-26-5 I-27008 99% 2,511.4 J.Lg/mL +I-141.0796
4 1-Bromo-4-fiuorobenzene (BFB) 460-00-4 184975 99% 2,517.8 J.Lg/mL +I-141.4391
* Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
01-Nov-2022 rev. 1 of3
REPORT ID: 23E135 Page 424 of 454
Column:
105m x 0.53mm x 3.01'm
Rtx-502.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240'C
@ B"C/min. (hold 5 min.)
lnj. Temp:
200'C
Det. Temp:
250"C
Det. Type:
FlO
Split Vent:
40ml/min
lnj.Vol
11'1
f. .. i'
r;}/*jJ/.. 1~"14Jr~·
Daniel Wasson • Operations Tech I
Christie Mills· Operations Tech II· ARM QC
01-Nov-2022 rev.
0
Quality Confirmation Test
l
5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
____ _i:IC®Pla.D~ For .QRtimal results in your lab, conditioos.should.be.adJustedJor your
specific instrument, method, and application.
Date Mixed: 02-Dec-2022 Balance Serial#
Date Passed: 06-Dec-2022
1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2 of 3
REPORT ID: 23E135 Page 425 of 454
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
• Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
• Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/!JECD,
GC/MS, LC/MS, Rl, and/or melting point.
• Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombtned uncertatnty = k 2 2 2 ' 2
Ugravtmetric + Uhomog<m.,;ty + Ustorag11 stabtltty + Ushtpptng stabtltty
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
• The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
• Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
• Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2ml ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev. 3of3
REPORT ID: 23E135 Page 426 of 454
Certificate of Analysis
Product Name: Carbon Disulfide Standard
Product Number: EPA-1012-1
Lot Issue Date: 21-Sep-2020
Lot Number: 0006557585
Expiration Date: 30-Sep-2024
Description:
This analytical reference material (RMI was manufactured and verified in accordance with an ISO 9001 registered quality system and analyte
concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each
analyte, determined gravimetrically, is listed below.
Analyte
carbon disulfide
Matrix: methanol (methyl alcoholl
Storage Conditions: Store Frozen (-25° to -10°C).
Traceability:
CAS#
000075-15-0
Analyte lot
RM08158
Concentration ± Uncertainty
5023 ± 251Jg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3, ISO 9001, ISO 17025,
and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are calibrated against a NIST traceable
thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This AM was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is no minimum sub-sample size required.
lnten ded Use:
This AM is intended for the preparation of working reference samples for use in routine laboratory analyses, calibration of instruments, validation of
analytical methods, assessments of measurement methods. and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at zo•c to 25•c immediately after opening the container and should be processed without delay for
the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above. provided the AM is handled and stored in accordance with the
instructions given in this certificate. This certification is nullified if the AM is damaged. contaminated. or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate. Agilent will notify the purchaser.
~
ACCAEOIT£0
REFCAEHC£ MAlfR~L
PfiOOUCE.R
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with TUV USA Inc registered ISO 9001 Quality
Management System. Cert # 56 100 18560026
Page: 1 of 1
www.agilent.com/quality/
CSO-OA-015.1
Sample lot approver:
~oo.wgzORA
Monica Bourgeois
QMS Representative
TEsnNotAIIOAATORV
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E135 Page 427 of 454
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: c; /1"1 11-1-___
by TUV USA to ISO 9001:2015
~·--.. _________ C_e_ri_if_ic_a_te_o_f_A_n_a_ly~..,..s_is_ .. ____ R_e_v _o _ Page
Catalog No.: Lot No.: Storage:
s -10 oc 3200-G34 480677
-120016-03
Compound
bromomethane
chloromethane
chloroethane
dichlorodifluoromethane
vinvl chloride
trich lorotluoromethane
Solvent: Exp. Date:
PIT Methanol 1 1/8/2026
CAS No Purity{%)
74-83-9 99.5
74-87-3 99.7
75-00-3 99.94
75-71-8 99
75-01-4 99
75-69-4 99
Description:
ISO 17034-Method 8260 Gases,
2.000 m2/L. 2 x 0.6 mL
Compound Lot No Concentration, m2:/L
139.158.1.11' 2025 ± 7.36 mg/L
140.158.3P 2013 ± 7.32 mg/L
141.2.31' 1979 ± 6.93 mg/L
142.158.5!' 2026 or 21.46 mg/L
143.158.5.21' 20 II ± 21.3 mg/L
l44.l.3P 1998 ± 13.43 mg/L
Second Source standards are prepared according to NELAC requirements.
Certified Bv:
Samuel Garrett All weights are traceable through N. I. S, T. Test No. 822/264157-00.
Concentration (correct for ouritv) and uncertaintv (95% confidence) values
REPORT ID: 23E135 Page 428 of 454
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
Sv\-~~-\o -0)
CERTIFICATE OF ANALYSIS
Catalog No: APP-9-211-20X
Description: Vinyl acetate
Lot: 222111294
Solvent: Methanol
Date Certified: Nov 21, 2022
Expiration: May 21, 2023
Sample Size: 1 ml
Components: 1
Hazards: Refer to SDS for complete safety information Storage Condition: Freeze (<-1 0 °C)
Signal Word: Danger
Component
CAS#
Vinyl acetate
108-05-4
: -·:~.
Certified Reference Material
Purity'%
100.0
P,r~pared
Coneertt@.tl9n•
_,.,> .. ''trot_,
:p:-.,~,,
.. ·"""·<·:.,
Certified Analyte
Concentration'
/mL
2006
This Certified Reference Material was verifietFlirl!ccor~~~-\vith
150/IEC 17025 (AT-1339) and ISO 17034 (AR-1463)
A product with a suffix (·1A, ·2B, etc. or -01.,. -O~}~ta.) pnJi$ii~t? number has had its expiration data extended and is Identical to the same lot number wtthout the suffix.
, Certified Analyte Concentration = P~fW:,tfi'E;pa~~ll~~ritration. . . .
The Uncertainty associated with the;:ti~):tified cq~~ntratioh reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal i('ji.fill. positiv~;squarEi root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K"2 Is chosen uslr)g~pp(oxim~t(iiy~'~$#o confidence level. ·
'All weights are traceabiEd!ii'o~gh N)~r.·r~'s\ No. 684/291344-18 & 684/292805-19
' Purity/Identity determined:ii~ one o{f'iiore of ihe following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels an~:t~:r\\iJ¢.~~)0s follovi'\]:~;,,p(>;i~entlons In reporting numerical values: A comma (,)is used to separate units of one-thousand or greater. A period(.) is used as
a decimal P!~%~ m~~~t;,. ' ·
The informatii;lfi:pn this. :Certificate may not be reproduced without the express permission Of the manufacturer. See reverse side for additional information
Hazard lnforma~QillPi~ase 'tater to the SDS for Information regarding the hazards associated with using this material.
This product wa~.~fepared according loin-house proc·adures and is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic ac Manager
Page 1 of 1
For use in routine labotatory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001:2015 OR·ORGIJN()-001
Rev. 7120
REPORT ID: 23E135 Page 429 of 454
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u8 = .f(u(V))2 + (u(m))2 + (u(IV))l + (u(RO))l I his
formula represents uncertainty components from the mass, volume, short-term !ftability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and limit of liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 430 of 454
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 575702
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0191824
Description : Custom Revised 8260 Megamix
Container Size :
Expiration Date :
Custom Revised 8260 Megamix 2,000-40,000f.]g/ml, P& T Methanol,
1mllampul
2 ml Pkg Amt: _>_1_m_L ______ _
November 30, 2025 Storage: ooc or colder
Ship; Ambient
~··.
(AC'CRi:ti ITioJ
ISO 17034 Ac.:redftcd
P:efP.f~Ma1t>ri61F'foducf!"
C'-rtifu::ate tlllJ.Ol
~',
{Af£Reori"]P'J
ISO/lEC 11 02S Aocr-.dited
TQStlngUbor>torY
(o?l'ttflcl19 U2ll02
CERTIFIED VALUES
Dichlorofluoromethane (CFC-21) 75-43-4 12841600 99% 2,000.0 11glmL +/-69.1292
2 Diethyl ether (ethyl ether) 60-29-7 SHBP5008 99% 2,011.0 11g/mL +/-69.5094
3 I, 1,2-Trichlorotrifluoroethane (CFC-113) 76-13-1 00016133 99% 2,008.0 11glmL +I-69.4057
4 I, 1-dichloroethene 75-35-4 SHBG8609V 99% 2,001.6 f.lg/mL +!-69.9029
5 Iodomethane (methyl iodide) 74-88-4 RD220125 99% 2,007.5 11glmL +I-69.3884
6 Allyl chloride ( 3-cbloropropene) 107-05-1 RP220405A 99% 2,011.0 !lglmL +I-69.5094
7 Methylene cbloride(dichloromcthane) 75~09-2 SHBP1417 99% 2,001.6 f.lglmL +I-69.9056
8 trans-! ,2-Dichloroethene 156-60-5 MKBH9850V 99% 2,001.7 f.lglmL +I-69.9064
9 1, 1-Dichloroethane 75-34-3 760200 99% 2,001.1 f.lglmL +I-69.8864
10 Chlciroprcnc (2-cbloro-1 ,3-butadiene) 126-99-8 220712JLM 99% 2;014.0 ftglmL +I-69.6131
11 Propionitrile 107-12-0 BCCF4J67 99% 20,009.5 11glmL +I-691.5748
12 2,2-Dichloropropane 594-20-7 RD220812 99% 2,004.3 flglmL +I-70.0110
13 cis-1,2-Dichloroethcne 156-59-2 MKCP7830 99% 2,014.0 11g/mL +1-70.3516
14 Methacrylonitrile 126-98-7 1012014 99% 20,031.5 jlglmL +I-692.3351
15 Methyl acrylate 96-33-3 SHBG66J6V 99% 2,007.0 f.LglmL +I-69.3711
16 Isobutanol (2-Methyl-1-propanol) 78-83-1 SHBP7066 99% 40,013.5 11glmL +I-1,382.9594
01-Nov-2022 rev.
~-RESTEK 1 of 5
REPORT ID: 23E135 Page 431 of 454
17 chloroform 67-66-J SHBN8469 99% 2,002.3 ttg/mL +/-69.9291
18 Bromochloromethane 74-97-5 00008541 99% 2,011.9 ttg/mL +/-70.2782
19 Tetrahydrofuran 109-99-9 SHBP0039 99% 2,005.0 ttg/mL +/-69.3020
20 1,1, !-trichloroethane 71-55-6 RD220613 98% 2,001.2 ttg/mL +/-69.8893
21 l, 1-Dichloropropene 563-58-6 220617JLM 99% 2,014.0 ttg/mL +/-70.3498
22 carbon tetrachloride 56-23-5 SHBL8097 99% 2,000.1 ttg/mL +/-69.8514
23 1 ,2-Dichloroethane 107-06-2 MKCN9758 99% 2,001.6 ttg/mL +/-69.9056
24 Benzene 71-43-2 MKCQ2104 99% 2,010.5 ttg/mL +/-70.2293
25 2-Chloroethanol 107-07-3 RD220606A 99% 2,002.5 ttg/mL +/-69.2156
26 Trichloroetheoe 79-01-6 SHBN3720 99% 2,001.6 jlg/mL +/-69.9047
27 1 ,2-Dichloropropane 78-87-5 BCBR0882V 99% 2,001.8 ttg/mL +/-69.9125
28 Methyl methacrylate 80-62-6 MKCQ2755 99% 2,007.5 f!g/mL +/-69.3884
29 bromodichloromethane 75-27-4 MKCF8470 99% 2,001.7 ttg/mL +/-69.9082
30 I ,4-Dioxane 123-91-1 SHBP8653 99% 40,041.0 f!g/mL +/-1,383.9099
31 2-Nitropropanc 79-46-9 BCCB9352 97% 2,003.5 ttg/mL +/-69.2514
32 Dibromomethane 74-95-3 I 0233302 99% 2,013.0 r•g/mL +/-70.3149
33 cis-1 ,3-Dichloropropene." -... 10061-01-5 RD22031! 99% 2,001.9 ttg/mL +/-69.9152
34 Toluene 108-88-3 ED097-US 99% 2,011.4 f!g/mL +/-70.2608
35 Ethyl methacrylate 97-63-2 MKCN6206 97% 2,004.0 f!g/mL +/-69.2681
36 trans-! ,3-Dichloropropene 10061-02-6 RD220816 99% 2,000.5 ttg/mL +/-69.8671
37 1, I ,2-Trichloroethane 79-00-5 FGBOJ 99% 2,001.9 jlg/mL +!-69.9134
38 1 ,3-Dichloropropane 142-28-9 BCCB98!7 99% 2,011.1 jlg/mL +/-70.2485
39 Tetrachlorocthene 127-18-4 SHBJ7422 99% 2,001.2 f!g/mL +/-69.8890
40 dibromochloromcthane 124-48-l MKCM8659 99% 2,002.2 ttg/mL +/-69.9256
41 I ,2-Dibromoethane (EDB) 106-93-4 BCCF5058 99% 2,006.0 jlg/mL +/-70:0704
42 Chlorobenzene 108-90-7 SHBN6640 99% 2,000.1 ttg/mL +1-69,8506
43 1 ,l, I ,2-Tetrachloroethane 630-20-6 GCOI 99% 2,009.8 ~•g/mL +/-70.2031
44 Ethylbenzene 100-4!-4 094632L2JG 99% 2,016.4 ~g/mL +/-70.4337
45 m-Xylene 108-38-3 SHBN6673 98% 2,012.6 ttg/mL +I-70.3019
46 p-Xylene 106-42-3 10234437 99% 2,009.1 ttg/mL +/-70.1787
47 o-Xylene 95-47-6 SHBN5105 98% 2,010.1 f!g/mL +/-70.2!63
48 Styrene 100-42-5 MKCQ3390 99% 2,012.6 jlg/mL +/-70.3027
49 Isopropylbenzene (cumene) 98-82-8 Z20D022 99% 2,009.3 p.g/mL +/-70.1874
50 bromofonn 75-25-2 MKCR0680 99% 2,000.8 ftg/mL +/-69.8750
51 cis-1,4-Dichloro-2-butene 1476-11-5 RD220907 97% 2,000.0 ttg/mL +/-69.1290
52 I, 1 ,2,2-Tetrachloroethane 79-34-5 OXACF +/-69.9466
01-Nov-2022 rev. ·---· RESTEK 2 of5
REPORT ID: 23E135 Page 432 of 454
53 I ,2,3-Trichloropropane 96-18-4 332900 99% 2,010.3 [!g/mL +I-70.2206
54 ~·ans-I ,4-dichloro-2-butene 110-57-6 RD220921 RSR 94% I ,999.9 ftg/mL +I-69.1240
55 n-Propylbenzenc I 03-65-1 MKCN1126 99% 2,009.1 [!glmL +I-70.1804
56 Bromo benzene 108-86-1 WXBC5147V 99% 2,012.5 )lg/mL +I-70.2992
57 1 ,3,5-Trimethylbenzene I 08-67-8 BCCF4166 99% 2,010.8 )lglmL +I-70.2381
58 2-Chlorotolucne 95-49-8 MKCF5243 99% 2,007.5 )lg/mL +I-70.1228
59 4-Chlorotoluene 106-43-4 MKCC8496 99% 2,012.4 [lg/mL +I-70.2957
60 tert-Butylbenzene 98-06-6 STBJJ937 99% 2,009.0 jJ.ghnL +I-70.1769
61 I ,2,4-Trimcthylbenzenc 95-63-6 WXBC9428V. 98% 2,004.8 ftg/mL +I-70.0297
62 sec-Butylbcnzcne 135-98-8 MKCP2266 99% 2,009.2 ftg/mL +/w 70.1839
63 p-lsopropy I toluene (p-Cymcne) 99-87-6 MKCR6143 99% 2,007.6 ftg/mL +I-70.1280
64 I ,3-Dichlorobcnzene 541-73-1 BCCD5315 99% 2,000. 7 )lglmL +/-69.8715
65 1 ,4-Dichlorobenzene I 06-46-7 MKBS4401V 99% 2,002.0 jtg/mL +I-69.9195
66 n-Butylbcnzene 104-51-8 09804AE 99% 2,006.9 [!g/mL +i-70.1036
67 I ,2-Dichlorobenzene 95-50-1 SHBN3835 99% 2,001.2 ftg/mL +/-69.8898
68 1 ,2-Dibromo-3-chloropropanc 96-12-8 HBMVB 97% 2,006.3 [!g/mL +I-70.0843
69 Nitrobenzene 98-95-3 10224044 99% 2,004.0 [!g/mL +I-69.2674
70 I ,2,4-Trichlorobcnzene 120-82-1 SHBM0526 99% 2,009.7 jJ.g/mL +/-70.1996
71 Hcxachlorobutadiene 87-68-3 X05J 99% 2,007.4 )lg/mL +!-70.1210
---~··--
72 Naphthalene 91-20-3 MKCH02J9 99'Yo 2,001.5 )lglmL +/-69.9132
73 I ,2,3-Trichlorobcnzene 87-61-6 MKBX7627V 99% 2,015.7 [lg/mL +/-70.4092
• Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
-~-
01-Nov-2022 rev. RESTEK 3 of 5
REPORT ID: 23E135 Page 433 of 454
Column:
60m x 0.2Smm x 1.4~m
Rtx-502.2 (e<it.#10916)
Canier Gas:
helium·constant pressure 30 psi
Temp. Program:
40'C [hold 6 min.) to 240'C
@ 6'C/min. [hold 10 min.)
lnj. Temp:
zoo•c
Det. Temp:
250'(
Det. Type:
MSD
Split Vent:
20.0 ml/min.
lnj. Vol
1~1
Cathleen Soltis -Mix Technician
Jennijer Pollino. Operations T ~h lll· ARM QC
01-Nov-2022 rev.
Dale Min<l:
Quality Confirmation Test
i
"16,17 29.30 • .:31 ..:t5,4.6
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
18-Nov-2022 Balance Serial # B251644995
Dale Passed: 05-Dee-2022
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
4 of 5
REPORT ID: 23E135 Page 434 of 454
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are detenmined by one or more of the following techniques: GC/FID, HPLC, GC/f.JECD,
GC/MS, LC/MS, Rl, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
Purity of isomeric compounds is reported as the sum of the isomers.
Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombtned uncerta<nty = k U~rauimetrtc + U~omogene;ty + u;torag" sta/JiJity + u;htpptng stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product. when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL am puis. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
-~.
01-Nov-2022 rev. RESTEK 5 of 5
REPORT ID: 23E135 Page 435 of 454
~ .... llESTEK CERTIFIED REFERENCE MATERIAL
11 0 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: (814}353-1309
www.restek.com
Catalog No. : 30465
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0164741
Description : California Oxygenates Mixture #1
California Oxygenates Mixture #1 2000-100001Jg/mL, P& T Methanol,
1mllampul
Container Size : 2 mL
~~--------------
PkgAmt: ___ >~1~m~L~-----------
Expiration Date : September 30, 2025 Storage: ooc or colder
Ship: Ambient
~;,
(ACCREDIT"'@)
ISO 11034 ActtedKed
R(l(erencq. AUtQJ1•1 F'loducQf
(Mffic.l!G-tJlllO\
.. ..
@ftE~tT]ru
ISOAEC 1702l; Acctedited
1iatlno l>boutory
Cortiliote • 3222.02
CERTIFIED VALUES
tert-Butano1 (TBA)
CAS# 75-65-0 (Lot SHBLS806)
Purity 99%
2 Methyl-tert-buty1 ether ( MTBE)
CAS # 1634-04-4 (Lot SHBL0822)
Purity 99%
3 Diisopropyl ether ( DIPE )
CAS# 108-20-3 (Lot SHBH1927V)
Purity 99%
4 Ethy1-tert-buty1 ether (ETBE)
CAS# 637-92-3 (Lot MKCM3774)
Purity 99%
5 tert-Amyl methyl ether (TAME)
CAS# 994-05-8 (Lot HMBG774SV)
Purity 99%
-.;-, •'i+ · .Grq_v.· COJ)C.-.~-· .c _,_ •
,.. ': , (weight/volume)
10,033.6 l!g/mL
2,000.0 llg/mL
2,006.0 f!g/mL
2,017.6 j!g/mL
2,009.2 J.tglmL
"' ,_. ~.f.l!!lande.d .UnceA"tainty_-. ~ ... l .. .L. . •·· ,.,~;~,;;.:.} ::.··
(95% C.L.; K=2)
+I-58.7489 1-lg/mL Gravimetric
+!-214.9330 llg/mL Unstressed
+I-221.1750 J.LglmL Stressed
+I-11.7371 1-lg/mL Gravimetric
+I-42.8500 llg/mL Unstressed
+1-44.0940 ).lg/mL Stressed
+I-11.7723 ).lg/mL Gravimetric
+I-42.9785 llg/mL Unstressed
+I-44.2263 1-lg/mL Stressed
+/-11.8404 ).lg/mL Gravimetric
+I-43.2270 1-1glmL Unstressed
+I-44.4820 llglmL Stressed
+I-II. 7911 J.LglmL Gravimetric
+I-43.0471 J,tg/mL Unstressed
+I-44.2968 fjg/mL Stressed
01-Aug-2020 rev.
1 of 3
REPORT ID: 23E135 Page 436 of 454
Solvent: P&T Methanol
CAS# 67-56-l
Purity 99%
Column:
105m x 0.53mm x 3.0~m
Rtx-502.2 (cat.Ul0910)
Carrier Gas:
hydrogen·constant pressure 11.0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ 8'C/min. (hold 5 min.)
lnj. Temp:
zoo·c
Det. Temp:
250'C
Det. Type:
FlO
Walker Workman· Operations Te-chnician I
~~~it~L .....
.Ju•l\,.. Alben..on • Op4r•llon• Tech-ARM OC
'~·-·
01-Aug-2020 rev.
5 10 15 20
Minutes
This chromatogram represents a general set of testing conditions chosen for product
F~c:c::ept:=mr.B. For optimal results in your lab; conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 24-Sep-2020
Date Passed: 27-Sep-2020
Balance: !128360905
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2 of3
REPORT ID: 23E135 Page 437 of 454
125 Market Street
New Haven. CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-601C-10X
Description: 2-Chloroethylvinyl ether
Lot: 218061690-01
Date Certified: Jul 15, 2020
Expiration: Jul 15, 2023
Sample Size: 1 ml
Components: 1
Tel [phone]
Fax [phone]
www.AccuStandard.com
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Storage Condition: Freeze (<-10 •c)
Signal Word: Danger
Component
CAS#
2-Chloroethylviny\ ether
110-75-8
Certified Reference Material
Purity%
(GC/MS)
100.0
~J~pared
concentrMIQn'
<y9Yn1q
2006·
Certified Analyte
Concentration'
(j.!g/ml)
2006
A product with a suffix (·1A, -28, etc. qr~~p\":}'o2. number has had Its expiration date extended and Is Identical to the same lot number without the suffix.
'All weights are traceable through Nis'T: T~st No;,822-275872-11
'Certified Analyte Concentration=~;;';.;\ Pre.~~,l~d Concentration.
The Uncertainty assoclateq;W\tW@B' . '· :.'})\'bentratlon reported on this certificate Is ±2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard deviat@:t'equal t~,t)le positive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2.1s chosen , .. , .. , roxiiJi!jtely a 95% confidence level.
Labels and,pe:f\.i foil .:,::C?P~Ventions in reporting numerical values: A comma (,) Is used to separate units of one-thousand or greater. A period(.) Is used as
a decimal ·... ,,:,;.•"'
The informait()):j)pn t~J:;:\¢\lttJflil.!!te may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard lnfomt'' ... ,, .. ~~·x:··. ·· iefer to the SDS for Information regarding the hazards associated with using this material.
ared according to In-house procedures and Is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1
For use In routine laboratory analysis.
AccuStandard is accredited to ISO 17034, 150/IEC 17025 and certified to ISO 9001:2015
OR-ORGnN0·001
Rev. 7/20
REPORT ID: 23E135 Page 438 of 454
1. Quality Standards:
ISO 17034:2016-General Requirements for the Competence of
Reference Material Producers ANAB Certificate Number AR-1463
180/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories ANAB Certificate Number AT-1339
ISO 9001:2015-Quality Management System-Requirements
Eagle Registrations Certificate Number 3774
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u11 = .f(u(V)Jl 1-(u(m))! + (u(lV))2 + (u(RO))ll his
formula represents uncertainty components from the mass, volume, short-term stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E135 Page 439 of 454
Product Name: 1-Chlorohexane Standard
Product Number: EPA-1208-1
Storage Conditions: Store at Room Temperature (15° to 30°C).
Matrix: methanol (methyl alcohol)
Description:
Lot Number:
Lot Issue Date:
Expiration Date:
0006668972
1 0-Mar-2022
30-Apr-2025
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 1 of 2
CSO-OA·D15.1
REPORT ID: 23E135 Page 440 of 454
' . -. .. . ...... A "I
ISO 17034 ···:..:_··· 91 ent . .. . . . .
· Trusted Answers
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
,:> ~-.....,.._ .... -:;.,~'"<-"."«~'3'i.\'V."'•'>VJI." V~-""A\ ~-. "'..,.,""-.,.....,,,.,Yio..,'-'"w·"-'" -.... .,v.._,._._-..,..,.,':t..,...,._ • ._,,,.,.._ .... ~,,.._ •. ,.,,,.~., "''""'"''~"'''~~··"}" .. .,,.,"._._ ... .,, .... .,._ .... ._.,, .... "";.,;•, '• ,.,._,._,,,'\.._._.,.,.,•,, ,._._.._._ •. ~,,.,.._,~,._,._._,._,"., .... ,._._.,.h-.,'·'o'Y'J."'~'.\Vb\,.~<h .. "o'~"'"'•''''•'•" '"''""''"9'"-'·~ .._ .. ~''§:
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A.CCR£,.DITEO
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV/SUD registered lSD 9001:2015
Quality Management System. Curt# 951215321
Page: 2 of2
www.agilentcom/quality/
CSD-QA-015.1
Sample lot approver:
~001AZfOW
Monica Bourgeois
QMS Representative
~
A C 0 R f:·D IT 6 D
ISO 17025 Cert
No. AT-1937
REPORT ID: 23E135 Page 441 of 454
Scientific
SIMPLE SOLUTIO~S FQR AOVAHCtO SCIENCE
Chromanex, 14271 Jeffey Rd #223, Irvine, CA 92620 [phone], Fax [phone]
Date manufactured: 10/15/2020
Original issue date: 10/15/2020 Certificate of Analysis DateReceived:
Catalog No.: Lot No.: Storage: Solvent: Expiration Description:
Date:
3200-44 453887 :::; -10 °C PIT Methanol 14-0ct-202 5 1,2,3-Trimethylbenzene Solution,
2500 mg/L, 1 mL
Certified Values:
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM
has been confirmed by ga.s chromatography (GC) or gas chromatograph/mass spectrometry
(GC/MS) using an internally developed method against an independent source. The uncertainty
value is calculated for a 95% confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ma/L
1,2,3-trimethylbenzene 526-73-8 95.2 869.3.19P 2515 ± 9.27
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control
standard for Chromatography Equipment such as GC, GC/MS, HPLC,and HPLC/MS. It may aslo be used for
various USEPA, NIOSH, and ASTM methods.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and
uncertainty (95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements: s -10 °C
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal
ampule. Once opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated
REPORT ID: 23E135 Page 442 of 454
Certificate of Analysis
Catalog No.: 3200-44 Lot No.: 453887 Expiration Date: 10/14/2025
using NIST traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department
of Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology
(NIST). Balances are checked daily in accordance to in house procedure 02-LB-004. Balances are calibrated
annually by an ISOIIEC 17025:2005 and ISO Guide 34:2009 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance
with internal procedure 02-QS-1 0. This is consistent with the intended use of this CRM. The homogeneity of this
product has been confirmed by procedures consistent with ISO!IEC qulde 17025:2005 and ISO qulde 34:2009.
Hazardous information:
Refer to MSDS
Calculation of Uncertainty
The following equations are used to calculate the value of the expanded uncertainty: U=ku c: U=Expanded
Uncertainty, k= the coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc= "2,u1
2
where u 1 are the individual uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified
value. These tests include the effect of temperature and packaging on the product. This standard is guaranteed
until the following date: 14-0ct-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO
17034:2016 Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American
Association of Laboratory Accreditation (A2LA).
Manufactured By: Certified By: Released By:
L. ~
Melissa Workoff Claire Desrochers Susan Mathews
\
REPORT ID: 23E135 Page 443 of 454
~' IRESTEK® CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30470
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
lot No.: A0162335
Description : tert-Butanol Standard
tert-Butanol Std 50,0001Jg/ml, P&T Methanol, 1 mL/ampul
Container Size : 2 ml
-------------------------------------
Pkg Amt: > 1 ml -----~~-------------
Expiration Date : July 31, 2023
----~----------------------
Storage: o•c or colder
a
ISO ·11034 Awedited
Re4'erw...e ~.~t~l~l Plodum
C~rlffiato "32ll0l
·.·.·.\ ..
" h::·
.:
(i'CC'ReE>ttj§'DJ
·ISOAEC 17025 Accredited
Totting L>boratcry
((!rtifiate f32~02
CERTIFIED VALUES
Compound . -
teti-Butanol (TBA)
CAS# 75-65-0 (Lot SHBL5806)
Purity 99%
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
Grav.Conc.
(weight/volume)
50,008.0 J.lg/mL
Expanded Uncertainty
.. (95% C.L.; K:::2) .. -· ·· -

-
+/-292.8078
+1-1,071.2377
+/-1,102.3483
J.lg/niL
J.lglmL
j.lg/mL
Gravimetric
Unstressed
Stressed
14-May-2020 rev. 1 of 3
REPORT ID: 23E135 Page 444 of 454
Column:
105m x 0.53mm .x 3.0~m
Rtx-502.2 (c,t.Nl0910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ s·cjmin. (hold 5 min.)
lnj. Temp:
2oo·c
Det. Temp:
25o·c
Det. Type:
FID
\~ J.i-3/ywo-<~'--'l(r:\ ~~
Kyll1.1 S\rublo-Opqratlon5 Technlelrm I
14-May-2020 rev.
10 15 20 25
Mlnllles
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 07-Jul-2020
Date Passed: 09-Jul-2020
Balance: 1127510105
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
/
(
2 of3
REPORT ID: 23E135 Page 445 of 454
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
by TUV USA to ISO 9001:2015
Catalog No.: Lot No.:
sci ntlffc
It uri Q2-crf)
4~t ·-7 r{-u~ -r·--I ·1
Certificate of Analysis
Solvent: Exp. Date:
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: -------
Rev 0 Page
Description:
034-3200 480682
Storage:
::; -10 oc P/TMeOH:Water 9:1 4/28/2027 Ketones Solution, 2500 mg/L, 1 ml ISO 17034
-121020-I 7
Certified Bv:
Compound
acetone
2-butanone (MEK)
4-methvl-2-oentanone (MIBK)
2-hexanone
Melissa Workoff
CAS No
67-64-1
78-93-3
108-10-1
591-78-6
Purity(%) Compound Lot No Concentration, mi!!L
99.6 I 96.271.4P 2498 ± 53.47 mg!L
99.9 197.1.2P 2498 ± 53.51 mg/L
99.88 198.421.1.21' 2500 ± 54.02 mg/L
100 199.7.3P 2501 ± 53.58 mg!L
All weights are traceable through N. I. S. T. Test No. 822/264157-00.
Concentration (correct for ouritv) and uncertaintv (95% confidence) values
REPORT ID: 23E135 Page 446 of 454
Trusted A11swers
Reference Material Certificate
Product Information Sheet
Product Name: Acrolein and Acrylonitrile Standard
Product Number: AMN-623-1
Storage Conditions: Store Frozen (-25• to -lD"C).
acrylonitrile 2009 ± 10 IJg/mL
Matrix: methanol (methyl alcohol)
Description:
ISO 17034
Lot Number: 0006728532
Lot Issue Date: 14-Feb-2023
Expiration Date: 30-Jun-2023
000107-13-1 RM20527
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material (RM) standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above. Purity values are taken from approved vendor raw material certificates.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference (RM) standard was unitized according to an in-house procedure and is guaranteed to be homogeneous.
There is no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference (RM) standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard (RM) is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 1 of 2
CSD-QA-015.1 ISO 17025
REPORT ID: 23E135 Page 447 of 454
. . . .
••••
0 A ·1 ............... g1 ent . . .
Trusted Answers
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~~I/Qllllii8J!.!_I!
ACCREDITED
REFERENCE MATERIAL
PRODUCER
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUVISUO registered ISO
9001:2015 Quality Management System. Cert# 951215321
Page: 2 of2
www.agilent.com/quality/
CSD-QA-015.1
Sample lot approver:
~ooM~QW
Monica Bourgeois
QMS Representative
ISO 17025
REPORT ID: 23E135 Page 448 of 454
~:~
(i\%jiEDIT:!EJ
Reference Materials Producer
Cart #2495.01
SPEXertificate®
Certificate of Reference Material
Catalog Number: S-1015 Lot No. CP200701 009
Cyclohexane Ship Date: August 6, 2021
Methanol (Purge & Trap Grade) Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quali~y
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed m
USEPA, ASTM and other methods relevant to the certified properties listed below. ·
Certified Compounds:
Compound
Cyclohexane
~
110-82-7
•-Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 1-19/mL
Purity
99.5%
Certifiedt
10181-Jg/ml
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepa~e the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6, 2021 Certifying Officer: .sn.e..INJ.O..........._ ~­
shanhon Macieira, Operations Manager
Page 1 of2
REPORT ID: 23E135 Page 449 of 454
Report of Cert~fication
Catalog Number: S-1 015
Description: Cyclohexane
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200701009
Ship Date: August 6, 2021
Expiration Date: August 5, 2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems-Requirements
-ISO/IEC 17025: General requirements for the competence of testing
and calibration laboratories
-ISO 17034: General requirements for the competence of reference
material producers
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials-Contents of certificates and
!abies
Storage Requirements:
-!SO Guide 35: Refernece Materials -General and Statistical
principals for certification
-Guide to the Expression of Uncertainty in Measurement, 2008
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions. (18°C to 27'C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5~L with a 25~L ga::; tight syrir.go. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
Ail analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked ancl
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used In all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-be
ttle. variation,-is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
-X= x ± U where X=certified value, U=expanded uncertainty, x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
-uc =combined standard uncertainty obtained by combining the individual compound standard uncertainty components u1. where Uc=.JrUi•
Legal Notice:
SPEX CertiPrep Certified Reference Materials a no not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.l'i>
Your Science Is Our Passion."'
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Page 2 of7
i
Rev: / j
r REPORT ID: 23E135 Page 450 of 454
R~r
~ SPEXertificate®
Reference Materials Producer
Cert #2495.01
Certificate of Reference Material
Catalog Number: S-3893 Lot No. CP200615008
Description: Methyl acetate
Matrix: Methanol (Purge & Trap Grade) Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
US EPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Methyl acetate
CAS#
79-20-9
* -Isomer ratios (when applicable} are an uncertified parameter.
Final Solution Verification:
Labeled
1000 ~g/ml
Purity
99.5%
Certified!
985 ~g/ml
Uncertainty
± 34 ~g/ml
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20, 2022 Certifying Officer: 3~V>--~
Shannon Macieira, Operations Manager
Page 1 of 2
© 20211 Spex, an AB,sl.Y'Scienti~company.
REPORT ID: 23E135 Page 451 of 454
Report of Cert{(ication
Catalog Number: S-3893
Description: Methyl acetate
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200615008
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
·ISO 9001: Quality management systems-Requirements
• ISO/IEC 17025: General requirements for the competence of testing
and calibration laboratories
-ISO 17034: General requirements for the competence of reference
material producers
• ISO Guide 30: Reference Materials • Selected terms and definitions
-ISO Guide 31: Reference Materials-Contents of certificates and
lables
Storage Requirements:
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
• Guide to the Expression of Uncertainty in Measurement, 2008
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditlons (18•c to 27.C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE Is calculated from the SHIPPED DATE using our stability data and
Is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance Is acceptable. The minimum recommended
amount that should be removed from this vial is 5~L with a 25~L gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sal.es support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity In accordance with our.intemal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
ttle variation, Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
-X= x ± U where X=certified value, U=expanded uncertainty, x=property value
-U = kuc where k=2 is the coverage factor at the 95% confidence level
-uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components u1, where uc="ru,•
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep. ~
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
REPORT ID: 23E135 Page 452 of 454
~! SPEXertificate®
(A"C'£ReotTii)J
Reference Materials Producer
Cart #2495.01
Certificate of Reference Material
Catalog Number: S-2470 Lot No. EN191227005
Methylcyclohexane
Methanol (Purge & Trap Grade) Ship Date: August 6, 2021
Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography .instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Methylcyclohexane
CAS#
108-87-2
*-Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 iJglmL
Purity
99%
Certifiedt
1018 j..Jg/ml
Uncertainty
± 36 j..Jg/ml
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered With Atlantic
Scale, and traceable tb NISTand NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6, 2021 Certifying Officer: .Sbw.o,___ ~--­
Shannon Macieira, Operations Manager
Page 1 of 2
REPORT ID: 23E135 Page 453 of 454
··.:
Report of Cert~(ication
Catalog Number: S-2470 Lot No. EN191227005
Description: Methylcyclohexane
Matrix: Methanol (Purge & Trap Grade) Ship Date: August 6, 2021
Expiration Date: August 5, 2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISO/IEC 17025: General requirements for the competence of testing
-ISO Guide 35: Refernece Materials-General and Statistical
principals for certification
and calibration laboratories -Guide to the Expression of Uncertainty in Measurement, 2008
-ISO 17034: General requirements for the competence of reference
material producers
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18"C to 27"C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5pl with a 25pl gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly ciC;aned prior to use. Dilutions should be performed only with Class (
A volumetric glassware.
Material Source: .
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Veridor
identifications are proprietary, however sources of all materials used iri the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at crmsa![e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all prep·arations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-be
ttle variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
• X= x ± U where X=certified value, U=expanded uncertainty, x=property value
-U = kuc where k=2 is the coverage factor at the 95% confidence level
-uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components u1. where uc=viw2
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, pr otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.l'j>
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Page 2 of 2
Rev: 0
REPORT ID: 23E135 Page 454 of 454
LA B 0 RAT 0 R I e S. INC.
3051 Fqjita Street
Torrance, CA90505
T eI;(31 0)-61 g..,SS89
Date: 06·01·2023
EMAX Batch No.: 23E081
Attn: Travis Gouveia
Brice
3800 Centerpoint Dr. Suite 8223
Anchorage. AA. 99503
Subject: Laboratory Report
Project: TEAD·S
Enclosed is the Laboratory report for samples received on 05/10/23.
The data reported relate only to samples listed below :
Sample 10 Control # Col Date Matrix
.. .. .. .. .. ~ ...... .................... --..........
S· 129· 15·052023 E081·01 05/05/23 WATER
S· 137· 16·052023 E08l-02 05/08/23 WATER
S·138·16· 052023 E081·03 05/08/23 WATER
S·141· 17· 052023 E081'04 05/08/23 WATER
S·67·90·052023 E081'05 05/03/23 WATER
S·68·90·052023 E081·06 05/04/23 WATER
S·70·90·052023 E081·07 05/04123 WATER
S·71·90·052023 E081'08 05/04/23 WATER
S·93·92·052023 E081·09 05/05/23 WATER
S·95·92·052023 E081-l0 05/03/23 WATER
S·97·92·052023 E081-l1 05/05/23 WATER
SWMU·1/25·EB·052023 E081·12 05/03/23 WATER
TS· 20230503· 1/25 E081·13 05/03/23 WATER
S·68·90·052023MS E081·06M 05/04/23 WATER
S·68·90·052023MSD E081·06S 05/04/23 WATER
S·70·90·052023MS E08l-07M 05/04/23 WATER
S·70·90·052023MSD E081·07S 05/04/23 WATER
The results are summarized on the following pages.
Please feel free to call if you have any questions concerning
these resul
.... :I.d.~f vL-
Caspar J. Pang
Laboratory Director
Analysis
VOCS BY 8260C
VOCS 8Y 8260C
VOCS BY 8260C
VOCS 8Y 8260C
VOCS 8Y 8260C
VOCS 8Y 8260C
VOCS 8Y 8260C
VOCS 8Y 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
This report is confidential and intended solely for the use of the individual or
entity to whom it is addressed. This report shall not be reproduced except in full
or without the written approval of EMAX.
EMAX certifies that results included in this report meets all TNI & DOD requirements
unless noted in the Case Narrative.
NELAP Accredited Certificate Number CA002912022·24
ANAB Accredited DoD ELAP and ISO/IEC 17025 Certificate Number L2278 Testing
California ELAP Accredited Certificate Number 2672
REPORT ID: 23E081 Page 1 of 489
CHAIN·OF·CUSTODY RECORD Brice Engineering, Salt Lake City, UT
Andrew Castor [phone]
COC # 770113·20230509
Page 1/1
2jC (1)\
362 W. Pierpont Ave
SLC, UT 84101
Project Name: USAEC, TEAD-S Laboratory: EMAX Laboratories, Inc., Torrance, CA
Project Number: 770113 POC: Raman Singh (310)-618-8889 ext 119
WBS Code: Ship to: 3051 Fujita Street Torrance, CA 90505
Comments: Code Matrix
SW8015D (A) = TPH-Diesel Range Organics (J) ····Wa .. Ground Water ()
-;;
~ WCl. Water Quality Control Matrix QI ~ I-0 Code Container/Preservative iii 0 ()
.!:! '"C L() 0
21 2x 1 L Amber glass bottle with Teflon lined cap, Cool >.0 .... (0
0 N 0' to 6°C; protected from light -..c: 00 00 IV ... S s h) 3x VOA, 40 mL Clear glass vial with Teflon lined septa, I: QI <::i (f) (f) HCLto pH < 2, Cool 0' to 6'C
~"~Ht:tgAP-§iQ?3~RdQ~IMdl1if9; .• JGW:;:1 .. LL ii •••••••••• ?H) ••• 121: !J1. li>i>
Sample ID Matrix Date Time
1 S-129-15-052023 WG 5/5/2023 1305
2 S-137 -16-052023 WG 5/8/2023 1350
3 S-138-16-052023 WG 5/8/2023 1620
4 S-141-17 -052023 WG 5/8/2023 1050
5 S-67 -90-052023 WG 5/3/2023 1205
6 S-68-90-052023 WG 5/4/2023 1015
7 S-70-90-052023 WG 514/2023 1110
8 S-71-90-052023 WG 514/2023 1305
9 S-93-92-052023 WG 5/5/2023 1005
10 S-95-92-052023 WG 5/3/2023 1420
11 S-97 -92-052023 WG 5/5/2023 1137
12 SW MU-1/25-EB-052023 WQ 5/3/2023 915
13 TB-20230503-1/25 WQ 5/3/2023 730
Turnaround Time: Standard
Relinquished by: (Signature)~~ 14 (rJ
Date ];
Time &'0':::>
Received by: (Signature) .,.:":;,.,;!'.
Master_COC.xlsx ~:I
Samp
Sample Depth (ft bgs)
Init. Location ID Type Top -Bottom
CMH/SC X S-129-15 N1 0.00 0.00
CMH/SC X S-137-16 N1 0.00 0.00
CMH/SC X S-138-16 N1 0.00 0.00
CMH/SC X S-141-17 N1 0.00 0.00
CMH/SC X S-67-90 N1 26.00 36.00
CMH/SC X S-68-90 N1/MS1/SD1 52.50 62.50
CMH/SC X S-70-90 N1/MS1/SD1 40.00 50.00
CMH/SC X S-71-90 N1 58.00 68,00
CMH/SC X S-93-92 N1 136.00 151.50
CMH/SC X S-95-92 N1 102.50 128.00
CMH/SC X S-97-92 N1 72.50 83.00
CMH/SC X FIELDQC TB1 0.00 0.00
CMH/SC X FIELDQC EB1 0.00 0.00
-------
I. r;1(.~
UC" ~.i]
'kJ,A,1;U'''}.;) c.$7 ,(~f:>!U" w<-~2 0
Date. 'S~4 -,2'3
Time (000
Shipping Date: <j~9-' ~3
Received by Laboratory: (Signature, Date, Time) & conditio
11
Event: TEAD-S 2023 Annual Monitoring
Groundwater
..... . ... ....
.....
I
I
Cooler Comments I
1
1
1
1
1
1 MS/MSD-total of 9 containers
1 MS/MSD-total of 9 containers
1
1
1
1
1
1
f-eC.6.Je6 Jc,~.
.A'.~'I' /""7' /.....-c,,"t'l-,'/' "'"-
6'5110/1 '5
-71/~
q ,:sS-
REPORT ID: 23E081 Page 2 of 489
REFERENCE: EMAX-SM02 Rev. 12
SAMPLE RECEIPT FORM 1
Type of DelivelY Airbill/ Tracking Number ECN1.3 j; C '0 I
~edex D UPS D GSO D Olhers 77~o ~nl.{\) t;BC Recipient j"'\F\\f ,0\ '?I \j fYi",
D EMAX Courier D Client DelivelY Date uStl'" 23, Timeq :sS-
COC INSPECTION
~:ientName ~ Client PM/FC ~ampler Name ~~mpling DatelTime ~ampleID '~Matrix
ddress ~I#/Fax# D ourier Signature ~Analysis Required ~reservative (if any) 'TAT
Safety Issues (ifany) , D Igh concentrations expected D From Superfund Site D Rad screening required
Note:
PACKAGING INSPECTION
Container ~ooler D Box DOther
C;ondition lotrewOV\ ~ustOdY Seal D Intact D Damaged
Packaging {Ii\(;tut: -o· 2 ,~ubble Pack j D Styrofoam DPopcom D Sufficient 'l\ k1 c..~
Temperatures ~Cooler I v61"~"c D Cooler 2 ---"c DCooler3 ---°c D Cooler 4 ---"c D Cooler 5 ---"c
(Cool, :S6 °C but not frozen) D Cooler 6 "c D Cooler 7 "c D Cooler 8 °c D Cooler 9 "c D Cooler 10 ___ "C
Thermometer: ~IN 21.10Sl/IO!'J B -SIN 2 \01(potl7 ------
C-SIN D-SIN
Comments: D Temperature is ou of range. PM was informed IMMEDlA TEL Y.
Note:
DISCREPANCIES
LabSamplelD LabSampleContainerID Code ClientSample Label ID / Information Corrective Action
10 141-nlO 'fd.
/'
~ /
~ /
/ /'
/ /
/ /
/' /'
./ /'
/'" /'
/' A , /' «
~ .' ~/J Ie}] A-' to, L ' tA-t5h It-~
o pH holding time requirement for water samples is 15 mins. Water samples for pH analysis are received be/ond 15 minutes from sampling time. , I
NOTES/OBSERVATIONS:
SAMPLE MATRIX IS DRINKING WATER? DYES ~NO
LEGEND:
Code Description-Sample Management
Dl Analysis is not indicated in ____ _
D2 Analysis mismatch COC vs label
D3 Sample ID mismatch COC vs label
D4 Sample ID is not indicated in ___ _
DS Container -[improper] [leaking] [broken]
D6 DatelTime is not indicated in ___ _
D7 DatelTime mismatch COC vs label
D8 Sample listed in COC is not received
D9 Sample received is not listed in cac
~o initial~m corrections in cac~~
Dll Container count mismatch COC vs received
1)12 Container size mismatch cae vs received
REVIEWS:
Code Description-Sample Management
DB aut of Holding Time
Dl4 Bubble is >6mm
DIS No trip blank in cooler
D16 Preservation not indicated in ____ _
D17 Preservation mismatch cac vs label
DI8 Insufficient chemical preservative
DI9 Insufficient Sample
D20 No filtration info for dissolved analysis
D21 No sample for moisture determination
D22 __________________________________ __
D23 __________________________________ __
D24 ____________________ ~~------~----
Sample Labeling J:~~~-l\..A..ji.4.dlp,A;::""-"
Date~\u·~~~2-~~~~~
SRF --=--%'c-F--
Date __ -="---j~
EMAX Laboratories. Inc. 3051 Fujita SI., Torrance, CA 90505
o Continue to next page.
Code Description-Sample Management
Rl Proceed as indicated in )6..COC 0 Label
R2 Refer to attached instruction
R3 Cancel the analysis
R4 Use vial with smaIlest bubble first
RS Log-in with latest sampling date and time~ I min
R6 Adjust pH as necessary
R7 Filter and preserved as necessary
RS ________________________________ ___
R9 ________________________________ _
RIO ________________________________ _
RII -----------------------------------RI2 ________________________________ ___
REPORT ID: 23E081 Page 3 of 489
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REPORT ID: 23E081 Page 4 of 489
REPORTING CONVENTIONS
DATA QUALIFIERS:
Lab Qualifier AFCEE Qualifier Description
J F Indicates that the analyte is positively identified and the result is less
than LOQ/RL but greater than LOD/MDLlDL.
N Indicates presumptive evidence of a compound.
B B Indicates that the analyte is found in the associated method blank
as well as in the sample at above QC level.
E J Indicates that the result is above the maximum calibration range or
estimated value.
* * Out of QC limit.
Note: The above qualifiers are used to flag the results unless the project requires a different
set of qualification criteria.
ACRONYMS AND ABBREVIATIONS:
CRDL Contract Required Detection Limit
RL Reporting Limit
MRL Method Reporting Limit
MOL Method Detection Limit
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
DO Diluted out
DATES
The date and time information for leaching and preparation reflect the beginning date and time of the
procedure unless the method, protocol, or project specifically requires otherwise.
REPORT ID: 23E081 Page 5 of 489
LABORATORY REPORT FOR
BRICE
TEAD-S
METHOD SW5030B/8260C
VOLATilE ORGANiCS BY GC/MS
SDG#: 23E081
REPORT ID: 23E081 Page 6 of 489
Client : BRICE
Project: TEAD-S
SDG 23E081
CASE NARRATIVE
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
A total of thirteen(13) water samples were received on 05/10/23 to be
analyzed for Volatile Organics by GC/MS in accordance with Method
SW5030B/8260C and project specific requirements.
Holding Time
Samples were analyzed within the prescribed holding time.
Instrument Performance and Calibration
Instrument tune check was performed prior to calibration. Result was within
acceptance criteria. Multi-calibration points were generated to establish
initial calibration (ICAL). ICAL was verified using secondary source (ICV).
Continuing calibration (CCV) was carried out at a frequency required by the
project. All calibration requirements were satisfied. Note that" Minimum
Response Factor" for all analytes were within method recommended response
factors with the exception of Acetone and 2-Butanone. However, percent
recoveries for all target analytes were within 70-130% on all calibration
points. Refer to calibration summary forms of ICAL, ICV and CCV for details.
Method Blank
Method blank was prepared and analyzed at the frequency required by the
project. For this SDG, one(l) method blank was analyzed. V067E14B -result
was compliant to project requirement. Refer to sample result summary form
for details.
Lab Control Sample
Lab control sample was prepared and analyzed at a frequency required by the
project. For this SDG, one(l) set of LCS/LCD was analyzed. V067E14L/V067E14C
were within LCS limits. Refer to LCS summary form for details.
Matrix QC Sample
Matrix spike sample was prepared and analyzed at a frequency required by the
project. For this SDG, two(2) sets of MS/MSD (23E081-06M/23E081-06S) and
(23E081-07M/23E081-07S) were analyzed. All analytes were within project QC
limits except for Styrene (unstable in acidic matrix) was not within MS/MSD
QC limits. Presence of matrix interference was suspected. Refer to Matrix QC
summary forms for details.
Surrogate
Surrogates were added on QC and field samples. All surrogate recoveries were
within QC limits. Refer to sample result summary forms for details.
Sample Analysis
Samples were analyzed according to prescribed analytical procedures. Results
were evaluated in accordance to project requirements. For this SDG, all
quality control requirements were met with the exception of those that were
discussed within the associated QC parameter.
REPORT ID: 23E081 Page 7 of 489
LAB CHRONICLE
VOLATILE ORGANICS BY GC/MS
Client : BRICE SOG NO. : 23EOBI
Project : TEAD·S Instrument ID : 67
WATER
Client Laboratory Dilution % Analysis Extraction Sample Cal ibration Prep.
Sample ID Sample ID Factor Moist DateTime DateTime Data FN Data FN Batch Notes
.. ~ .............. ............. . ............. . ........................
LCSIW V067E14L 1 NA 05/12/2307: 10 0511212307:10 REC288 RDC593 V067E14 Lab Control Sample (LCS)
LCDIW V067EI4C 1 NA 05112/2307:36 05112/2307: 36 REC2B9 RDC593 V067E14 LCS Duplicate
MBLKIW V067E14B 1 NA 05/12/2308:27 05112/2308: 27 REC291 RDC593 V067E14 Method 8lank
TB· 20230503· 1/25 23E081-13 1 NA 05/12/2308: 53 05112/2308: 53 REC292 RDC593 V067E14 Field Sample
SWMU-1/25·EB-052023 23E081-12 1 NA 05112/2309:18 05112/2309: 18 REC293 RDC593 V067E14 Field Sample
S·68·90·052023 23E081-06 1 NA 05112/2309:44 05112/2309:44 REC294 RDC593 V067E14 Field Sample
S-70-90·052023 23E081·07 1 NA 05112/2310: 10 05112/2310: 10 REC295 ROC593 V067E14 Field Sample
S·67-90-052023 23EOBI-05 1 NA 05112/2310: 35 05/12/2310: 35 REC296 RDC593 V067E14 Field Sample
S·95·92-052023 23E081-10 1 NA 05112/2311 : 01 05/12/2311:01 REC297 RDC593 V067E14 Field Sample
S-71-90·052023 23E081·08 1 NA 05112/2311:26 05112/2311: 26 REC298 RDC593 V067E14 Field Sample
S·129-15·052023 23E081-01 1 NA 05112/2311: 52 05112/2311: 52 REC299 RDC593 V067E14 Field Sample
S-93-92·052023 23E081·09 1 NA 05/12/2312: 18 0511212312:18 REC300 RDC593 V067E14 Field Sample
S·97·92·052023 23E081-11 1 NA 05/12/2312:43 05/12/2312: 43 REC301 RDC593 V067E14 Field Sample
S-137-16-052023 23E081·02 1 NA 05112/2313: 09 05112/2313: 09 REC302 RDC593 V067E14 Field Sample
S· 138· 16·052023 23E081·03 1 NA 05/12/2313: 35 0511212313: 35 REC303 RDC593 V067E14 Field Sample
S-141-17-052023 23E081-04 1 NA 05112/2314: 01 05/12/2314: 01 REC304 RDC593 V067E14 Field Sample
S·68·90·052023MS 23E081·06M 1 NA 05112/2314: 26 05112/2314: 26 REC305 RDC593 V067E14 Matrix Spike Sample (MS)
S·68·90·052023MSD 23E081-06S 1 NA 05/12/2314:52 05112/2314: 52 REC306 RDC593 V067E14 MS Duplicate (MSD)
S-70-90·052023MS 23E081·07M 1 NA 05112/2315: 18 05/12/2315:18 REC307 RDC593 V067E14 Matrix Spike Sample (MS)
S·70·90·052023MSD 23E081·07S 1 NA 05/12/2315:44 05/12/2315:44 REC308 RDC593 V067E14 MS Dupl icate (MSD)
FN -Filename
% Moist· Percent Moisture
REPORT ID: 23E081 Page 8 of 489
SAMPLE RESULTS
REPORT ID: 23E081 Page 9 of 489
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/05123 13: 05
Project TEAD-S Date Received: 05/10123
Batch No. 23E081 Date Extracted: 05/12/23 11: 52
Sample ID S-129-15-052023 Date Analyzed: 05/12/23 11: 52
Lab Samp ID 23E081-01 Dilution Factor: 1
Lab File ID REC299 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/U (ug/U (ug/U (ug/U
... _a. _______ . ___ ..... __ .... ·· ... _-_ ..... .. -------------------. -----------
1. 1. 1. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1.1.2.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane NO 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene NO 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide NO 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform NO 1.0 0.10 0.20
Chloromethane NO 1.0 0.25 0.50
cis-1.2-0ichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Oibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISOpro~YlbenZene NO 1.0 0.10 0.20
m.~-x~ ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene NO 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene NO 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene NO 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2-Dibromoethane NO 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
--_.-----------------------------_ ... ----_.-_._---_. ----_ ... ---.--------_.
1.2-Dichloroethane-d4 10.5 10.0 105 70-130
4 -Bromofl uorobenzene 11.3 10.0 113 70-130
Toluene-d8 10.9 10.0 109 70-130
Oibromofluoromethane 10.7 10.0 107 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b1 : VLu Analyzed by : VLu
Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 10 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC299.D
Acq On 12 May 2023 11:52 am
Sample 23E081-01
Misc 25mL .~.
(QT Reviewed)
Vial: 14
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:18 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) 1,4-DIFLUOROBENZENE 10.15 114 2253215 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1583027 10.00 ug/l 0.00
74) 1,2-DICHLOROBENZENE-D4 19.49 152 413332 10.00 ug/l 0.00
~System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 572041 10.65 ug/l 0.02
Spiked Amount 10.000 Recovery 106.50%
43 ) 1,2-Dichloroethane-d4 9.31 65 428552 10.45 ug/l .--0.02
Spiked Amount 10.000 Recovery 104.50%
56 ) Toluene-d8 12.97 98 2398894 10.90 ug/l /"' 0.00
Spiked Amount 10.000 Recovery 109.00%
77) 4-Bromofluorobenzene 17.60 95 633614 11.35 ugly 0.00
Spiked Amount 10.000 Recovery 113.50%
/
" . Target Compounds 0/ Qvalue
19 ) Carbon disulfide 4.53 76 26929 0.10 ug/l 100
(#) = qualifier out of range (m) = manual integration
REC299.D V067D26.M Mon May 15 08:18:57 2023 Page 1
REPORT ID: 23E081 Page 11 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC299.D
Aeq On 12 May 2023 11:52 am
Sample 23E081-01
Mise 25mL
Vial: 14
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:18 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
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Initial Calibration
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N
Z w ro
0
0::
0 -' :r:
(,)
0 "' .
Ii il Ii
o L~,~00~3=, O~O ~c4~,"00--;"75~,"bo~'~6~,-OO~7-,T'00~-8,,-Lb!0"" " ·-r-rg."bOh:i-'1~0-.l-: 0-h0-'1-'1~: 0-0~1-'2~: 0,.0r-1-'3~: 0-0"1-;-4-: 0"6~1-;-5-,O-0~1L6-: 0-0~1-'7-'-, O~O '1-;-8-, 0-0-1-'-9-. 0-0 -2-0 .-00-21-. O-O~ Jime-->
-----------------------------------
REC299.D V067D26.M Mon May 15 08:18:58 2023 Page 2
REPORT ID: 23E081 Page 12 of 489
Abundance
I
I RefOj
Scan 145 (4:497 min): RUC593JJT-)
7(3
49
84
44 i
I I I I i 188
! o~·-,-. ~, --'--'-;I~r ii' Iii I ~2 , , ' , ' ,6,4, ,,(,0, 'I: ~,9, ,I! I , ' , I ' , , , I .
'm/z--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ~bundance Scan 146 (4.527 min): REG
[ I T
Ra~1 44
I 49 67 84
Im/z __ > ~~~35~' -'-4hb~",~C,'5~,+~r+b~' "5-'15~' -'-"6b~' '~6-r15r+1~, 7"b~' ~rl~h,--~+'~15+1 ~, '-'-9"b~' 9--'15~
40
~undance Scan 146 (4.527 min): R
, I
I
Sub I
501
76
I
84 49
~~~-"~3-'5~'~4b"~4'5~+'50~-'5r5~6'b~~~~~+rl-,-p~,n~90'~
67
I #19
Carbon disulfide
Concen: 0.10 ug/l
RT: 4.53 min Scan# 146
Delta R.T. 0.03 min
Lab File: REC299.D
Acq: 12 May 2023 11:52 am
Tgt
Ion
76
78
Ion: 76 Resp: 26929
Upper
i
4000j
I
3000
2000
1
!
1000 1
I
Ratio Lower
100
9.1 6.3 1l. 7
of--~,.~';:::;"::~-~-~""-~'''''' -r-"--,-r~, -.--, -, .--
ime--> 4.40 4.50 4.60 4.70
REC299.D V067D26.M Mon May 15 08:19:00 2023 Page 3
REPORT ID: 23E081 Page 13 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/08/23 13:50
Project TOO-S Date Received: 05/10/23
Batch No. 23E081 Date Extracted: 05/12/23 13:09
Sample ID S-137-16-052023 Date Analyzed: 05/12/23 13:09
Lab Samp ID 23E081-02 Dilution Factor: 1
Lab File ID REC302 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument 10: 67
RESULTS LOQ OL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/L) (ug/U -_ ...... -........................... _ ......... .. ...... _ .......... .................... ..................... .....................
1. 1. 1.2-Tetrachloroethane NO 1.0 0.10 0.20
1.1. I-Trichloroethane NO 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane NO 1.0 0.10 0.20
1.1.2-Trichloroethane NO 1.0 0.10 0.20
1.1-0ichloroethane NO 1.0 0.10 0.20
1.1-0ichloroethene NO 1.0 0.10 0.20
1.1-0ichloropropene NO 1.0 0.10 0.20
1. 2. 3-Trichlorogropane NO 2.0 0.25 0.50
1.2.4-Trichloro enzene NO 1.0 0.15 0.30
1.2-0ibromo-3-chloropropane NO 2.0 0.25 0.50
1.2-0ichlorobenzene NO 1.0 0.10 0.20
1.2-0ichloroethane NO 1.0 0.10 0.20
1.2-0ichlorogropane NO 1.0 0.10 0.20
1.3-0ichloro enzene NO 1.0 0.10 0.20
1.3-0ichlorogro pane NO 1.0 0.10 0.20
1.4-0ichloro enzene NO 1.0 0.10 0.20
2.2-0ichloro~ro~ane NO 1.0 0.25 0.50
2-Butanone ( EK NO 20 5.0 10
2-Chlorotoluene NO 1.0 0.25 0.50
2-Hexanone NO 20 5.0 10
4-Chlorotoluene NO 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene NO 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane NO 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide 0.28J 1.0 0.25 0.50
Carbon Tetrachloride NO 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform NO 1.0 0.10 0.20
Chloromethane NO 1.0 0.25 0.50
cis-1.2-0ichloroethene NO 1.0 0.10 0.20
CiS-1.3-0ichloro~ropene NO 1.0 0.10 0.20
Oibromochloromet ane NO 1.0 0.10 0.20
Oibromomethane NO 1.0 0.10 0.20
Oichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISOpro~Ylbenzene NO 1.0 0.10 0.20
mtxf: ene NO 2.0 0.21 0.50
4-et yl-2-Pentanone NO 10 2.5 5.0
Methylene Chloride NO 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) NO 1.0 0.15 0.30
n-Butylbenzene NO 1.0 0.25 0.50
n-Propylbenzene NO 1.0 0.25 0.50
o-Xylene NO 1.0 0.10 0.20
~-Isopro~bltoluene NO 1.0 0.25 0.50
ec-Buty enzene NO 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert-Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene NO 1.0 0.15 0.30
Toluene NO 1.0 0.10 0.20
Trans-1.2-0ichloroethene NO 1.0 0.10 0.20
Trans-1.3-0ichloropropene NO 1.0 0.25 0.50
Trichloroethene NO 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2-0ibromoethane NO 1.0 0.10 0.20
1.2.3-Trichlorobenzene NO 1.0 0.15 0.30
1.4-0ioxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
_ ........................................... -.... .................... .......... a_ ...... • .. ....... -_ .... -_ .. _ .. _------
1.2-0ichloroethane-d4 10.7 10.0 107 70-130
4-Bromofluorobenzene 11.0 10.0 110 70-130
Toluene-d8 10.9 10.0 109 70-130
Oibromofluoromethane 10.7 10.0 107 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 14 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC302.D
Acq On 12 May 2023 1:09 pm
Sample 23E081-02
Misc 25mL
(QT Reviewed)
Vial: 17
Operator: VLu
Inst 67
Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 15 8:20 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1 t 4-DIFLUOROBENZENE 10.15 114 2178620 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1546348 10.00 ug/l 0.00
74) 1 t 2-DICHLOROBENZENE-D4 19.49 152 417334 10.00 ug/l 0.00
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 553491 10.66 ug/l 0.02
Spiked Amount 10.000 Recovery 106.60%
43 ) 1 t 2-Dichloroethane-d4 9.30 65 424676 10.71 ug/l ~ 0.02
Spiked Amount 10.000 Recovery 107.10%
56) Toluene-d8 12.97 98 2351636 10.94 ug/l/' 0.00
Spiked Amount 10.000 Recovery 109.40%
~ 77 ) 4-Bromofluorobenzene 17.60 95 619945 11.00 uglY 0.00
Spiked Amount 10.000 Recovery 110.00%
I' /
:~Target Compounds Qvalue
7) Chloroethane 2.72 64 13411 0.20 ug/l 75
19 ) Carbon disulfide 4.53 76 69547 0.28 ug/l 98
/'
(#) = qualifier out of range (m) = manual integration
REC302.D V067D26.M Mon May 15 08:20:24 2023 Page 1
REPORT ID: 23E081 Page 15 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC302.D
Aeq On 12 May 2023 1:09 pm
Sample 23E081-02
Mise 25mL
Vial: 17
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:20 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via r' bundance
9000000;
1.5000001
! I
Booooooi
7500000fi
I
70000001
I
65000001
6000000i
I
5500000,
i 5000000i
45000001
I
4000000:
I
35000001 '
3000000\
25000001
20000001
15000001
1000000
1
5000001
!
::;;
,..:
oi c:
'" ~ e
0 :c u
!
::;; ,..:
oi
"0
!E
" ~
c:
0 -e
'" u
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC30Z.D
en w ro z "0
w .,
N c:
Z Q)
w " ~ CD
0
0::
0
:::J
...J u.
is "1 en * '" " c:
'" ~ £
Q) c: E '" e ~ 0
" e
'5 .Q
E .c: u e 9 .0
is ~
\,
on a
W
Z
W
N z en W
CD oi
0 c:
0:: Q)
N 0 c:
...J '" I .0
U e
0
" 0:
0
E e
CD ....
" a
W
Z w
N z
W
CD
0
0::
0
...J
I u
is
c't
: \ /l o~. Ii',1 ,1\ li\)\ '1' 'I III, .. ,1\ , ".....-".'., ,"~ ,. ,
2.00 3.00 4.00 5.00 6.bo 7.00 B.OO 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 1B.00 19.0020.0021.00 ifime-->
REC302.D V067D26.M Mon May 15 08:20:25 2023 Page 2
REPORT ID: 23E081 Page 16 of 489
414
I
I
Ra'5bi
49
~/z--> 0'. 35 P'l40~4"5~ 50
Abundance
I
Sub i
50 1
102
160 1'05 '{[(j"
,
i o Ln'll ~~4h-19 h-. ~I' ~. ,IT, I~. ++1 i++II~, '~1~7~15~B'0~· B''l15''l'~9' 'o'l' ~9~15'~' ~1 O'~O~· 1~'O' 5~' ~11~0~· ~, I
m/z--> 35 40 45 50 55 60 65 70 1
~bunaance ----~-~Scan 145 (4.49TiTIln): RDC593TIT-J
I ~
I ,
i
i
I
I
RefOJ
, 49
J ... ,-. ~,,-cl .~4,4-.. T-i1+1 ~I'-f~c,=2"" ~, ~, ,,' I~. "~-j-4,,,~77'T~0'" '''''71+51-rJ[7~~B:'-10~' -r-Bif-T~.B5+[ r+~~~'9"'0~' "9-'15~'
:m/z--> 30 35 40 45 50 55 60 65
Abu ndance -SCan141614r:5271TlIn1:m=c::m2:u-------'--'----j
44
#7
Chloroethane
Concen: 0.20 ug/l
RT: 2.72 min Scan# 52
Delta R.T. 0.02 min
Lab File: REC302.D
Acq: 12 May 2023 1:09 pm
Tgt Ion: 64 Resp: 13411
Ion Ratio Lower Upper
64 100
49 14.0 0.0 57.1
bundance ono4.00-To37010-64-:7D):REC302.D!
lion 49.00 (4B.70 to 49.70): REC302.D 1
2500 1
1
'
2.72
20001
1500
1
1000
1
I
5001 I ! \
01, ! I V \ --
ime--> 2.50 2.60 2.70 2.802.90 3.00-'
#19
Carbon disulfide
Concen: 0.28 ug/l
RT: 4.53 min Scan# 146
Delta R.T. 0.03 min
Lab File: REC302.D
Acq: 12 May 2023 1:09 pm
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
8.3 6.3
69547
Upper
11. 7
bu~r0n76-:-00l75:70l070.70YREC302.D
lion 7B.00 (77.70 to 7B.70): REC302.D
I
140001
120001
I
100001
BOOO;
REC302.D V067D26.M Mon May 15 08:20:26 2023 Page 3
REPORT ID: 23E081 Page 17 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/08/23 16:20
Project TEAD-S Date Received: 05110123
Batch No. 23E081 Date Extracted: 05/12/23 13:35
Sample ID S-138-16-052023 Date Analyzed: 05/12/23 13:35
Lab Samp ID 23E081-03 Dilution Factor: 1
Lab File ID REC303 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/L) (ug/U
... _--_ ............. -----_ ..... __ ..... ." ... _-........ .............. ................ ....................
1.1. 1. 2-Tetrachl oroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1.1.2.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Ch 1 oroethane ND 2.0 0.50 1.0
Chloroform 0.14J 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m.wxf; ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4 -Di oxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPKJ#f %RECOVERY QC LIMIT
......................................... ------.--""""-" .. ." ........... -.. .................... ---.... _--_ .. -
1.2-Dichloroethane-d4 10.5 10.0 105 70-130
4-Bromofluorobenzene 11.2 10.0 112 70-130
Toluene-d8 10.8 10.0 108 70-130
Dibromofluoromethane 10.8 10.0 108 70-130
Notes: Sample Amount : 25ml Final Volume : 25ml
Prepared b1 : VLu Analyzed by : VLu
Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 18 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC303.D
Acq On 12 May 2023 1:35 pm
Sample 23E081-03
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:21 2023
~
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M
Last Update
Response via
DataAcq Meth
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Vial: 18
Operator: VLu
Inst 67
Mul tiplr: 1. 00
Quant Results File: V067D26.RES
(RTE Integrator)
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2154178 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1546551 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 404558 10.00 ug/l 0.00
System Monitoring Compounds
:...., 36) Dibromofluoromethane 8.21 111 554889 10.81 ug/l 0.02
Spiked Amount 10.000 Recovery 108.10%
43 ) l,2-Dichloroethane-d4 9.31 65 412767 10.53 ug/l ~0.02
Spiked Amount 10.000 Recovery 105.3 %
56 ) Toluene-d8 12.97 98 2312738 10.75 ug/l ~O.OO
Spiked Amount 10.000 Recovery 107.50%
-77 ) 4-Bromofluorobenzene 17.60 95 610625 11.17 ug/lL:: 0.00
Spiked Amount 10.000 Recovery 111.70%
~ Target Compounds Qvalue
19) Carbon disulfide 4.53 76 28940 0.12 ug/l 97
32) Chloroform 7.71 83 15159 /0.14 ug/l 93
(#) = qualifier out of range (m) = manual integration
REC303.D V067D26.M Mon May 15 08:21:06 2023 Page 1
REPORT ID: 23E081 Page 19 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC303.D
Aeq On 12 May 2023 1:35 pm
Sample 23E081-03
Mise 25mL
Vial: 18
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:21 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via : Initial Calibration
Abundance--~-------~----------···----TK:::REC30TD---------·-----~··-·
9000000:
85000001
80000001
i
If\
750000011 Ii
7000000!
5000000
4500000i
4000000
I
3500000i
1
I
30000001
2500000
2000000:
i
15000001
1000000,
500000:
,
CI)
oi c:
'" ,5
" E
::;: e
f-' 0 ::;: " oi 0=
"C f-' 0
'" c.5 E ::; g e '" .0 'C .E is c:
0 e -e .9
'" "" <.) <.)
..;
0
ui
CI) uJ ro z z "% w W N N. c: Z CI) z " w oi W " en en 0 c:
0 f-0 " IY N
IY 0 c:
0 " ...J .0 ::::J I e ...J <.) 0 U-" is 0=
CI) ..... 0
..j E
"% e
cP
c: .... '" ,5
" e
0 :c
0
9
N.
..j
0
uJ z w
N
Z w
cP
0
IY
0
...J
I
<.)
is
~
II
Time--> °2.0~3~4})Q 5.00 6.00 7.00 8.00 9.00 1O:~011 :0012:00 1~:~0 14:00 15:00 '~6.00 17:0018.00 19.0020.00 21.00
REC303.D V067D26.M Mon May 15 08:21:07 2023 Page 2
REPORT ID: 23E081 Page 20 of 489
,
-------------SCan14oT4~'r97rnr(1):~D-C59~PT)--~--I
I
#19
Carbon disulfide
Concen: 0.12 ug/l
RT: 4.53 min Scan# 146
Delta R.T. 0.03 min
I Lab File: REC303.D
Acq: 12 May 2023 1:35 pm
! O~-__,_,__~i
im/z--> 30 35 40
lA.bundance
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
28940
Upper
Ra~i
I
ol--
m/z--> 30
Abundance
Sub.
7.8 6.3 11. 7
bundanGelOr176~01l17570to 76:70): REC303.D
lion 78.00 (77.70 to 78.70): REC303.D ,
60001 4.53
I
5000i
40001
3000]
50i 2000:
, L, ,~ ,'-'-, ~. -,j41-,-~ ~'c-r, ~,--.-.-,-,,,, ,-,-, c-r,-,jy--,-,-,-, !~' -,-",+' ch-r8'O~' c-r8+.18~'5+i ""'g'O-'-' c-,-, ''''9'5~' 1O:t=1 ;::::,;:::;,:::;:,~(~/:;:::, ;::::, :::;:\:'::;\ ,=;:,="-::;:::'--:;:::/\--;:::;' ",::.:::;' =:;:
m/z--> 30 35 40 45 50 55 60 65 70 75 ime--> 4.40 4.50 4.60 4.70
RefO
----------'------------------'-----------------------
Scan 363 (7.683 min): RD'C593.D (-) 8,
I
i!
120
#32
Chloroform
Concen: 0.14 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC303.D
Acq: 12 May 2023 1:35 pm
, 110
. 'i I 1 Tgt Ion: 83 Resp: 15159 120 130
Ra~i
1 I I
: I i I III O~'r-'-'; .L,-I' .,..,-r-~, ,,' -.-r-r, -,-;, '~""" ,.1..,l,!-,''--' ~,--;-, ~. '-r-rT"~-'--'-'-'--'--'-
m/z--> 30 40 50 60 70 80 gO 100 110 120 ' 130 r.-~i:':bucc:n:-:id=an=-=cc=-e-------,...S=ca=n,...3"..64T7.712 min): REC303. -
I 83
Sub.
50·
47
40
O,"--'-~-T"
,IT\/z--> 30 40 50
Ion Ratio Lower Upper
83 100
85 63.1 39.4 99.4
47 23.6 0.0 56.0
bundanceTon--83~-0\82~70-fo-8'3: 70):-REC303'o
40001ion 85.00 (84.70 to 85.70): REC303.D
lion 47.00 (46.70 to 47.70): REC303.D
3500
1' 3000 1 7.71
I
2500:
2000 1
I
15001
°LCC:":_.:c:.:.._
7.60 7.70 7.80
-----~.--
REC303.D V067D26.M Mon May 15 08:21:08 2023 Page 3
REPORT ID: 23E081 Page 21 of 489
METHOD SW5030B/B260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/0B123 10:50
Project TEAD-S Date Received: 05/10123
Batch No. 23EOB1 Date Extracted: 05/12/23 14:01
Sample ID S-141·17-052023 Date Analyzed: 05/12/23 14:01
Lab Samp ID 23E081-04 Dilution Factor: 1
Lab File ID REC304 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOO DL LOD
PARAMETER(S) (ug/L) (ug/l) (ug/L) (ug/L)
-------.......... _ ............ _ ......... ........... _ .. . ............ _ ... ..... a ........ . ...............
l,l,l,2-Tetrachloroethane ND 1.0 0.10 0.20
1,1, I-Trichloroethane ND 1.0 0.10 0.20
l,l,2,2-Tetrachloroethane ND 1.0 0.10 0.20
l,l,2·Trichloroethane ND 1.0 0.10 0.20
l,l·Dichloroethane ND 1.0 0.10 0.20
l,l·Dichloroethene ND 1.0 0.10 0.20
l,l·Dichloropropene ND 1.0 0.10 0.20
l,2,3'Trichlorggropane ND 2.0 0.25 0.50
l,2,4-Trichloro enzene ND 1.0 0.15 0.30
l,2-Dibromo·3·chloropropane ND 2.0 0.25 0.50
l,2·Dichlorobenzene ND 1.0 0.10 0.20
l,2·Dichloroethane ND 1.0 0.10 0.20
l,2.Dichlorogro pane ND 1.0 0.10 0.20
l,3·Dichloro enzene ND 1.0 0.10 0.20
l,3-Dichlorogro pane ND 1.0 0.10 0.20
l,4·Dichloro enzene ND 1.0 0.10 0.20
2,2'Dichloro~ro~ane ND 1.0 0.25 0.50
2·Butanone ( EK ND 20 5.0 10
2·Chlorotoluene ND 1.0 0.25 0.50
2· Hexanone ND 20 5.0 10
4·Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis·1,2·Dichloroethene ND 1.0 0.10 0.20
CiS'l,3.Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~YlbenZene ND 1.0 0.10 0.20
m,~.x~ ene ND 2.0 0.21 0.50
4· et yl·2·Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Met~l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n·Bu ylbenzene ND 1.0 0.25 0.50
n·Propylbenzene ND 1.0 0.25 0.50
o·Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert·Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans·1,2·Dichloroethene ND 1.0 0.10 0.20
Trans·1,3·Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
l,2·Dibromoethane ND 1.0 0.10 0.20
l,2,3·Trichlorobenzene ND 1.0 0.15 0.30
1,4· Di oxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
....................... _ .......... -....... -.. ___ .a_._ ... _ -_ .... _--_.----_._._----------_ .. --
l,2·Dichloroethane-d4 10.6 10.0 106 70·130
4·Bromofluorobenzene 11.2 10.0 112 70·130
Toluene·d8 11.0 10.0 110 70-130
Dibromofluoromethane 10.8 10.0 108 70·130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 22 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC304.D
Acq On 12 May 2023 2:01 pm
Sample 23E081-04
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:21 2023
Vial: 19
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.15 114 2187995 10.00 ug/l 0.02
55) CHLOROBENZENE-D5 15.60 117 1558341 10.00 ug/l 0.00
74) 1,2-DICHLOROBENZENE-D4 19.49 152 408427 10.00 ug/l 0.00
L
: System Monitoring Compounds
36 ) Dibromofluoromethane 8.21 111 561455 10.77 ug/l 0.02
Spiked Amount 10.000 Recovery 107.70%
43) l,2-Dichloroethane-d4 9.30 65 422595 10.61 ug/l ~0.02
Spiked Amount 10.000 Recovery 106. %
56) Toluene-d8 12.97 98 2382171 10.99 ug/l /0.00
Spiked Amount 10.000 Recovery 109.90%
77) 4-Bromofluorobenzene 17.60 95 619108 11.22 ug/7' 0.00
Spiked Amount 10.000 Recovery 112.20%
/ i:" ./
:Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC304.D V067D26.M Mon May 15 08:21:34 2023 Page 1
REPORT ID: 23E081 Page 23 of 489
,
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC304.D
Aeq On 12 May 2023 2:01 pm
Sample 23E081-04
Mise 25mL
Vial: 19
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:21 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
(RTE Integrator)
r
bundance Trc .... :c-l"R'>l'E--rC...,3C1\"04A.'"'D---------~~ ~-----------
8500000
I
! 80000001
!
i
i 75000001
7000000i
6500000
6000000
1
I
5500000] ,
I
5000000: ,
45000001 I
40000001'
I
i
i
3500000: '
I!
I I
30000001 •
25000001 I
I
I
20000001
; i
1500000j
1
I
1000000:
5000001
(/) ". c:
III
£
" E e
0
:::J
'5
E e .c
Ci
II
on
(/) a
ui .,; uJ
% z z w w c: N
N " Z Z :::J W
W 0 OJ
OJ I-0 0 a:: a:: 0 0 ...J
:::> I
...J u.. t)
Ci
(/) ": ...
% c:
III ~
§
:c
0
9
"!
!i
, " ol,~~~~~=r= /1 i\
i[ II n " " :\ II
... a
uJ
Z
(/) W .; N
c: Z
" w
N OJ c: 0 " .c a:: e 0
0 ...J
:::J I
'" t) 0
E 9 e "! OJ
.,J-
iTime--> 2.00 3.00 4.00 5.00 6.60 7.60 8.b
16 9.00 10:0011:0012:00 13:00 14:00 '15:00 16:001io018:00 19.00 20.00 21.00
~ ~--------------------------- - --------
REC304.D V067D26.M Mon May 15 08:21:35 2023 Page 2
REPORT ID: 23E081 Page 24 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/03/23' 12:05
Project TEAD-S Date Received: 05110123
Batch No. 23E081 Date Extracted: 05/12/23 10:35
Sample ID S-67-90-052023 Date Analyzed: 05/12/23 10:35
Lab Samp ID 23E081-05 Dilution Factor: 1
Lab File ID REC296 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER (S) (ug/L) (ug/L) (ug/l) (ug/L)
.... __ ....... --_ ....... _-_ ................. ............ _---.. ... ---_ ...... ........ " ........ -.. ...................
1. 1. 1.2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2 -Dibromo-3-chl oropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
8romobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
8romodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
IsoprO~Ylbenzene ND 1.0 0.10 0.20
m'~/h ene ND 2.0 0.21 0.50
4-t yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methtl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~&ltoluene ND 1.0 0.25 0.50
ec-8uty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1. 2. 3-Trichlorobenzene ND 1.0 0.15 0.30
l.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
.... _ .................................. _--_ .... .. .. _ .......... _-.................. . -_ ...... -.... .......... _-_ .. _-
1.2-Dichloroethane-d4 10.8 10.0 108 70-130
4-Bromofluorobenzene 11.0 10.0 110 70-130
Toluene-d8 10.8 10.0 108 70-130
Di bromofl uoromethane 10.9 10.0 109 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b1' : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 25 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC296.D
Acq On 12 May 2023 10:35 am
Sample 23E081-05
Misc 25mL
(QT Reviewed)
Vial: 11
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:17 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26 ~
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2320138 10.00 ug/l 0.02
55) CHLOROBENZENE-D5 15.60 117 1668037 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 457213 10.00 ug/l 0.00
System Monitoring Compounds
-. 36) Dibromofluoromethane 8.21 111 600386 10.86 ug/l 0.02
Spiked Amount 10.000 Recovery 108.60%
fj~ 43) l,2-Dichloroethane-d4 9.31 65 455158 10.78 ug/l 0.02
Spiked Amount 10.000 Recovery 107. B'tf%
56) Toluene-d8 12.97 98 2512154 10.83 ug/l ---0.00
, Spiked Amount 10.000 Recovery 108.30%
77) 4-Bromofluorobenzene 17.61 95 678096 10.98 ug/l/ 0.00
Spiked Amount 10.000 Recovery 109.80%
Target Compounds ../" Qvalue
(#) = qualifier out of range (m) = manual integration
REC296.D V067D26.M Mon May 15 08:17:25 2023 Page 1
REPORT ID: 23E081 Page 26 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC296.D
Aeq On 12 May 2023 10:35 am
Sample 23E081-05
Mise 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:17 2023
Vial: 11
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Initial Calibration
~bundance
t 9000000
TIC: REC296.D
I
8500000,
8000000j
i
7500000f\
70000001
I
65000001
I
6000000j
I
I
5500000)
50000001
I
4500000;
i
40000001
35000001
3000000j •
! I
25000001 •
I;
I'
i i ..
2000000'
1500000
10000001 I
500000;
I , i ( o~ ""7, .j
rrime--> 2.00 3.00 4.00 5.00 6.00
REC296.D V067D26.M
(f)
.; c co .r::. .,
E e
0
::l <= 0
E e
.0
i5
!1
/1
1\
7.06 's.bo
(f) on
0 00 w '" ui ~ z 0 z c UJ W UJ Q) N Z N ::l Z Z "0 UJ (f) UJ
UJ f-CD .; N
CD 0 c Z
0 c:: Q) UJ
N CD c:: 0 c 0 0 ...J Q)
::::J ::r: .0 c::
...J u e 0
"-0 ...J
i5 ::l ::r: <= u * 0 i5 (f) E
'" e <';
"0 CD
" ... c: co ~ e
0 :c .!O!
0
<';
I' I: ;i
!\ ij
Ii II Ii
1/\111\, i' ," ,1:(", !' ";' ~\ I"~ -"J; "I'/·"""""~'~'-~
9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
Mon May 15 08:17:26 2023 Page 2
REPORT ID: 23E081 Page 27 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/04/23 10: 15
Project TEAD-S Date Received: 05/10/23
Batch No. 23E081 Date Extracted: 05/12/23 09: 44
Sample 10 S-68-90-052023 Date Analyzed: 05/12/23 09:44
Lab Samp 10 23E081-06 Dilution Factor: 1
Lab File 10 REC294 Matrix: WATER
Ext Btch 10 V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/L) (ug/L) (ug/l)
.... ---_ .... -.... _-... _ ... -_ ....... ....... __ ....... _ ... -._ .. _ .. -... ---_ ....... . -...... _----
1. 1. 1. 2-Tetrachl oroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachl oroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~YlbenZene ND 1.0 0.10 0.20
m.wx~ ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Meth{l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert-Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1. 2. 3-Trichlorobenzene ND 1.0 0.15 0.30
1.4 -Di oxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
............ -----_ ... --....... --_ .. __ . . ............... ....... -......... ....... _ .......... .-..... _--_ .
1.2-Dichloroethane-d4 10.2 10.0 102 70-130
4-Bromofluorobenzene 11.2 10.0 112 70-130
Toluene-d8 10.8 10.0 108 70-130
Dibromofluoromethane 10.5 10.0 105 70-130
Notes: Sample Amount : 25ml Final Volume : 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 28 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC294.D Vial: 9
Operator: VLu Acq On 12 May 2023 9:44 am
Sample 23E081-06
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:16 2023
Inst 67
Multiplr: 1.00
~. Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
"System Monitoring Compounds
( 36) Dibromofluoromethane
Iv Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
'", Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
. Target Compounds
10.15
15.60
19.49
8.21
9.31
12.97
17.60
114 2248656
117 1589229
152 417832
III 565206
Recovery
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.02
0.00
0.00
10.55 ug/l 0.02
105.50%
65 415434 10.15 ug/l ~ 0.02
101.'50%
ug/l /0.00
108.20%
ug/l/ 0.00
111.9.0%
Recovery
98 2391020 10.82
Recovery
95 631781 11.19
Recovery
Qvalue
(#) = qualifier out of range (m) = manual integration
REC294.D V067D26.M Mon May 15 08:16:38 2023 Page 1
REPORT ID: 23E081 Page 29 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC294.D
Aeq On 12 May 2023 9:44 am
Sample 23E081-06
Mise 2SmL
MS Integration Params: RTE.P
Quant Time: May 15 8:16 2023
Vial: 9
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
~bundance ------------~T~IC-.c-:~R'ECN~
I
1
8000000j
,
75000001
7000000"
6500000i
I
60000001
I
I
5500000 1
5000000;
,
I
4500000;
40000001
I
35000001
3000000
25000001
I
2000000i
I
1500000:
1000000:
en
oi c:
'" ~
E e
0
" "" 0
E e .c
0
ori
w z w
N
Z w m a
0:: a
en 0
oj uJ
d: z w c: N " Z " w "0 m f-a
0:: a
...J
::J
...J
"-
:r:
(.)
i5
*-en ...
"0
'" c:
'" £;
" e
.Q
.<::
0 0
"'-Ii II
5000001 I ,i I[
I ! 1:,1 1\ I! I \ "' • II I' Ii
...
0
uJ
Z w en N oi z c:
" w
N m c: a " .c 0:: e a
0 ...J
" :r:
"" (.) 0 i5 E e "'-m ...
t ! II f\ 'I J\ 1',: ii
i '. I!'\ 11\ ,1'1 i '\ ,'\ ',i, 0' ,\~ .. , ,~.~,~, ~~~~~~~~-~~~. ~~~~~~~~~~~~~~~~~~~~~~~~-
ifime--> 2.00 3.00 4.00 5.00 6_00 7.00 8.00'9_00 10.0011:00 12:00 13:0014:00 15:00 16:00 17:0018:0019:0020.0021:00
REC294.D V067D26.M Mon May 15 08:16:39 2023 Page 2
REPORT ID: 23E081 Page 30 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/04/23 11:10
Project TEAD·S Date Received: 05110123
Batch No. 23E081 Date Extracted: 05112/23 10: 10
Sample ID S·70·90·052023 Date Analyzed: 05/12/23 10: 10
Lab Samp ID 23E081·07 Dilution Factor: 1
Lab File ID REC295 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOO DL LOD
PARAMETER (S) (ug/L) (ug/l) (ug/l) (ug/l)
____ a. __ .......... ·· ..• _ •. ••··· -....... _ .. ----_._._--.. _.-._---. .......... -_ ...
1,1,1,2·Tetrachloroethane ND 1.0 0.10 0.20
1,1,1·Trichloroethane NO 1.0 0.10 0.20
1,1,2,2·Tetrachloroethane NO 1.0 0.10 0.20
1,1,2·Trichloroethane NO 1.0 0.10 0.20
1,1·Dichloroethane NO 1.0 0.10 0.20
1,1·Dichloroethene NO 1.0 0.10 0.20
1,1·Dichloropropene ND 1.0 0.10 0.20
1,2,3'Trichlorocropane ND 2.0 0.25 0.50
1,2,4·Trichloro enzene ND 1.0 0.15 0.30
1,2·Dibromo·3·chloropropane ND 2.0 0.25 0.50
1,2·Dichlorobenzene ND 1.0 0.10 0.20
1,2·Dichloroethane NO 1.0 0.10 0.20
1,2.Dichlorocropane NO 1.0 0.10 0.20
1,3·0ichloro enzene NO 1.0 0.10 0.20
1,3.Dichlorocropane NO 1.0 0.10 0.20
1,4·Dichloro enzene NO 1.0 0.10 0.20
2,2'Dichloro~ro~ane NO 1.0 0.25 0.50
2·Butanone ( EK NO 20 5.0 10
2·Chlorotoluene ND 1.0 0.25 0.50
2· Hexanone ND 20 5.0 10
4·Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene NO 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride NO 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis·1,2·Dichloroethene ND 1.0 0.10 0.20
CiS'1,3'Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane NO 1.0 0.10 0.20
Dibromomethane NO 1.0 0.10 0.20
Dichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISOpro~Ylbenzene NO 1.0 0.10 0.20
m,w~ ene ND 2.0 0.21 0.50
4· et yl·2·Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methtl tert·butyl ether (MTBE) NO 1.0 0.15 0.30
n·Bu ylbenzene NO 1.0 0.25 0.50
n·Propylbenzene ND 1.0 0.25 0.50
o'Xylene NO 1.0 0.10 0.20
~'Isopro~bltoluene NO 1.0 0.25 0.50
ec·Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert·Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene NO 1.0 0.15 0.30
Toluene NO 1.0 0.10 0.20
Trans·1,2·Dichloroethene ND 1.0 0.10 0.20
Trans· 1 ,3·Dichloropropene NO 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1,2·0ibromoethane NO 1.0 0.10 0.20
1,2,3·Trichlorobenzene ND 1.0 0.15 0.30
1,4·0ioxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT __ .. a_._ .. __ .. __________ .. _______ _ ___ a ____ .. _ -----.-----____ a ______ -------_ ... -
1,2·Dichloroethane·d4 10.2 10.0 102 70·130
4·Bromofluorobenzene 11.2 10.0 112 70·130
Toluene·d8 10.9 10.0 109 70·130
Dibromofluoromethane 10.6 10.0 106 70·130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 31 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC295.D
Acq On 12 May 2023 10:10 am
Sample 23E081-07
Misc 25mL
(QT Reviewed)
Vial: 10
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:16 2023 Qu~~sults File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2269522 10.00 ug/l 0.02
55) CHLOROBENZENE-D5 15.60 117 1616394 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 423946 10.00 ug/l 0.00
System Monitoring Compounds
, 36) Dibromofluoromethane 8.21 111 571226 10.56 ug/l 0.02
i\ Spiked Amount 10.000 Recovery 105.60%
43) l,2-Dichloroethane-d4 9.31 65 421255 10.20 ug/l..--0.02
Spiked Amount 10.000 Recovery 102.00%
56 ) Toluene-d8 12.97 98 2455219 10.92 uglY 0.00
,
" Spiked Amount 10.000 Recovery 109.20%
77 ) 4-Bromofluorobenzene 17.60 95 642945 11.23 ug~ 0.00
Spiked Amount 10.000 Recovery 112.30%
/
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC295.D V067D26.M Mon May 15 08:17:02 2023 Page 1
REPORT ID: 23E081 Page 32 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC295.D
Aeq On 12 May 2023 10:10 am
Sample 23E081-07
Mise 25mL
Vial: 10
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:16 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update wed Apr 26 14:33:42 2023
Response via : Initial Calibration Abundance -------~--------TIC:RB:;290.0----------------------------------------
8000000j
I ,
7500000;
7000000! ,
(\
1\
6500000: !
i i
60000001 i
i!
550000011
i ,
5000000, ,
45000001 !
i I , I' , 4000000
1
i
!
3500000i
30000001
i:
2500000i
2000000;
I
!
1500000) .
1000000;
500000: '
on en 0 .; uJ
ill "0 Z " Z '" W 0
W c: N uJ .,
Z N " Z Z (5 w en w w .... CD .,-N CD 0 c: Z 0 0:: ., w
0:: 0 N CD
0 -' c: 0 I .,
::J .0 0::
-' U e 0 "-0 -' is " I
"': '5 u
en E ~ of en e c: " CD .,
"0 ..;. ti '" c: E ., e ti 0
" e '5 .Q
E .<= e .!l
0 ,g ~ 0
1\ 1:\ i\ ii il .j !\ III I, i 1\ l\ 1 \ 1\ Jl. :'\ [rim~--> 0 ~~. 3.00 __ 4.bo _---'5_.0--=0_· _6_00--=0_7_00_0_8_00_0 __ 9,---00_' 0_1--,-00_'0-,-011 :00 12~00 13:0014~0015:00 ;'.,--6-'---:0~0--;-1-+7~:0--;-0-',1'-'---80"'O--;-o.=-1-r;9~:--;-OO--,'-_r-£~~00~Q-'---___ -2.1--;-00-0-
REC295.D V067D26.M Mon May 15 08:17:03 2023 Page 2
REPORT ID: 23E081 Page 33 of 489
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/04123 13:05
Project TEAD-S Date Received: 05/10/23
8atch No. 23E081 Date Extracted: 05/12/23 11:26
Sample ID S-71-90-052023 Date Analyzed: 05/12/23 11:26
Lab Samp ID 23E081-08 Dilution Factor: 1
Lab File ID REC298 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PAR.Al-1ETER(S) (ug/L) (ug/L) (ug/L) (ug/L) ----_._-_ ... _-_ ................... . ..... -....... ....... __ ..... •••• a ......... _.--........
1. 1. 1. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m.wx~ ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4 -Di oxane ND 100 25 50
SURROGATE PAR.Al-1ETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
. __ ........ -............ _-_ ..... --_ .. . -.... __ ....... ----_ .. _----------_ ..... . __ .a._·_·_
1.2-Dichloroethane-d4 10.4 10.0 104 70-130
4-Bromofluorobenzene 11.3 10.0 113 70-130
Toluene-d8 10.9 10.0 109 70-130
Dibromofluoromethane 10.7 10.0 107 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 34 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC298.D
Acq On 1? Mny /.023 11:26 am
Sample 23E081-08
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:18 2023
Vial: 13
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2274035 10.00 ug/l 0.01
55) CHLOROBENZENE-D5 15.60 117 1606209 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 419409 10.00 ug/l 0.00
System Monitoring Compounds
".
~-~' 36 ) Dibromofluoromethane 8.21 111 577371 10.65 ug/l 0.01
l\' Spiked Amount 10.000 Recovery 106.50%
43) l,2-Dichloroethane-d4 9.30 65 431286 10.42 ug/l ~ 0.01
Spiked Amount 10.000 Recovery 104. %
56 ) Toluene-d8 12.97 98 2430354 10.88 ug/l /,0.00
Spiked Amount 10.000 Recovery 108.80%
77) 4-Bromofluorobenzene 17.60 95 638953 11.28 ug/l/ 0.00
Spiked Amount 10.000 Recovery 112 :JD%
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC298.D V067D26.M Mon May 15 08:18:13 2023 Page 1
REPORT ID: 23E081 Page 35 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC298.D
Aeq On 12 May 2023 11:26 am
Sample 23E081-08
Mise 25mL
Vial: 13
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:18 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via : Initial Calibration
rA-bundance-------·---·--------------~rc:HEc29KD-
8000000
7500000
70000001
ri
650000011
I!
1 ' Ii
6000000 !
I
5500000j i
5000000
1 ;
I
4500000j
40000001
I
3500000;
3000000]
25000001 •
i
2000000·
I
15000001 .
~ I
1000000; i
500000] :
en .,;
ui "C
Q, z c: W " N " Z (5
W f0-
al
0 a::
0
::::>
-' u.
is
en ..t.
oi en
c: " to "C £ Q, " c: E to e ~ 0
" e 'is .S!
E .t::
U e 9 £!
0 "!
Ii
j\ ii jl\
(RTE Integrator)
on
0 w
Z " W 0
N W Z Z W
al en w
N 0 oi z a:: c: w 0 " N al -' c: 0 :I: " a:: U .c 0 § -'
" I
'is u
is E "'. e
al ..t
0 1 , I J\ 1\ ! ~ I I
ifime--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.0010:0011:00 12:00 13:00 14:00 15.0016.0017.0018.00 19.0020.00 21.00
REC298.D V067D26.M Mon May 15 08:18:14 2023 Page 2
REPORT ID: 23E081 Page 36 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/05123 10:05
Project TEAD-S Date Received: 05110123
Batch No. 23E081 Date Extracted: 05/12/23 12:18
Sample ID S-93-92-052023 Date Analyzed: 05/12/23 12:18
Lab Samp ID 23E081-09 Dilution Factor: 1
Lab File ID REC300 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOO DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/L) (ug/L)
........... __ ..... _ ... --.................. . .................. .................... ................... ..................
1. 1. 1. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2·Tetrachl oroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m.~-x~ ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Meth{l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
................................................ ...----.... _ .. -.-................ .................. ... _--------
1.2-Dichloroethane-d4 10.5 10.0 105 70-130
4-Bromofluorobenzene 11.3 10.0 113 70-130
Toluene-d8 10.9 10.0 109 70-130
Dibromofluoromethane 10.7 10.0 107 70-130
Notes: Sampl e Amount : 25ml Final Vol ume : 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 37 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC300.D
Acq On 12 May 2023 12:18 pm
Sample 23E081-09
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:19 2023
Vial: 15
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.15 114 2180398 10.00 ug/l 0.01
55 ) CHLOROBENZENE-D5 15.60 117 1545804 10.00 ug/l 0.00
74) 1,2-DICHLOROBENZENE-D4 19.49 152 403791 10.00 ug/l 0.00
1 System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 555073 10.68 ug/l 0.01
Spiked Amount 10.000 Recovery 106.80%
1'·' 43 ) 1,2-Dichloroethane-d4 9.30 65 415514 10.47 U9/l~.01
Spiked Amount 10.000 Recovery 104. 0%
56) Toluene-d8 12.97 98 2349052 10.93 ug/l ~ 0.00
Spiked Amount 10.000 Recovery 109.30%
77 ) 4-Bromofluorobenzene 17.60 95 614516 11.27 uglY 0.00
Spiked Amount 10.000 Recovery 11~70%
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC300.D V067D26.M Mon May 15 08:19:27 2023 Page 1
REPORT ID: 23E081 Page 38 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC300.D
Aeq On 12 May 2023 12:18 pm
Sample 23E081-09
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
15
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: May 15 8:19 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
f-bundance '----------------...1"T7IC"'-:7R""E7'C""'30n.D
I I , I
I
80000001
I
7500000;
i 7000000f\1
65000001 !
II
1 i
60000001
5500000)
5000000! '
i
I
45000001
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! '
3500000!
3000000 1
I
2500000:
i
2000000j
1500000 1
1000000;
i!
rJl
oi
I e o
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E e .c
is
rJl
ui a;
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N " Z " "0 W co f-
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is "',
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500000: [' II
.0
0
W
Z w
N
Z w co
0 a::
0
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, ;1 I'"
I I", 1'1 II
I " 1\ ,I Ii I,'l
rJl
oi c:
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0
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CO
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Time--> 2.00 3.00 4.00 5.00 6.00 7.00 '8.00 9.00' 10:00 11:00 12:00 13:00 1(0015:00 16:00 17:0018:00 19.0020.0021.00
---~
REC300.D V067D26.M Mon May 15 08:19:28 2023 Page 2
REPORT ID: 23E081 Page 39 of 489
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/03123 14:20
Project TEAD-S Date Received: 05/10123
Batch No. 23EOB1 Date Extracted: 05/12/23 11:01
Sample ID S-95-92-052023 Date Analyzed: 05/12/23 11:01
Lab Sa!]!p ID 23E081-10 Dilution Factor: 1
Lab File ID REC297 Matrix: WATER
Ext Btch ID V067E14 % Moi sture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARl>METER(S) (ug/L) (ug/L) (ug/L) (ug/L)
. _--_ ... ----_ .... ----_ ....... _ .... ---_.-... _ .. ---_ .......... ................ ........ -.....
1. 1. 1. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1.2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorggropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m.~-X~ ene ND 2.0 0.21 0.50
4-et Yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methil tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1. 4 -Di oxane ND 100 25 50
SURROGATE PARl>METER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
.......................................... ...... ---......... ................ . ---_ ....... .. --_ ...........
1.2-Dichloroethane-d4 10.3 10.0 103 70-130
4-Bromofluorobenzene 11.2 10.0 112 70-130
Toluene-dB 10.9 10.0 109 70-130
Dibromofluoromethane 10.6 10.0 106 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b1' : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 40 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC297.D
Acq On 12 May 2023 11:01 am
Sample 23E081-10
Misc 25mL
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 12
Operator: VLu
Inst 67
Mul tiplr: 1. 00
Quant Time: May 15 8: 17 2023 ___ ~ Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2249275 10.00 ug/l 0.01
55) CHLOROBENZENE-D5 15.60 117 1594253 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 419648 10.00 ug/l 0.00
,~'System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 568033 10.60 ug/l 0.01
Spiked Amount 10.000 Recovery 106.00%
43 ) l,2-Dichloroethane-d4 9.30 65 420931 10.28 ug/l 0.01
Spiked Amount 10.000 Recovery 102 ::so%
56 ) Toluene-d8 12.97 98 2421582 10.92 U 9 /12o"% 0.00
(' Spiked Amount 10.000 Recovery 109. 0%
T 77) 4-Bromofluorobenzene 17.60 95 633399 11.17 ugly 0.00
j Spiked Amount 10.000 Recovery 111.70%
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC297.D V067D26.M Mon May 15 08:17:48 2023 Page 1
REPORT ID: 23E081 Page 41 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC297.D
Aeq On 12 May 2023 11:01 am
Sample 23E081-10
Mise 25mL
Vial: 12
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:17 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
~bundance
8000000j
I
75000001
I
7000000]
h
i \
6500000 [
6000000j
5500000j
I
5000000j
I'
!
4500000[ ,
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40000001.
1
1 i 3500000i :
I
30000001
i
I I
i
2500000:
! :
2000000,
1500000i
1000000;
500000i
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
~rc:REC297.D
(J)
o:i w z
W
N
Z
W
J;
c:
Q)
::l
-0
0-tIl
0 a:
0
::::J
...J
U.
is
(J) "'. ,i (J)
c: '" III -0
== .,
Q) c: E III e a; 0
::l e -= .2 0
E .J:;
" e is -" ~. is
d '. Ii
j:
II
.n
0
uJ z w
N
Z w (J) tIl
0 ,;
a: c:
Q) 0 N -' c:
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tIl ...
'" 0
uJ
Z
W
N z w
tIl
0 a:
0
...J
I
U
is
"'-
,! i\ Ii "
ifime--> O~:o~.OO "74 .00 5.00 6.00 7.00 8.b~ 9.ob! 10:66 11~06 12:001~~~0 14~00 '15~OO '~6:Q()_17_:0_6 _18~00_19:00 20.00 21.00
REC297.D V067D26.M Mon May 15 08:17:49 2023 Page 2
REPORT ID: 23E081 Page 42 of 489
METHOD SWS030B/B260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected 05/05123 11: 37
Project TEAD-S Date Received 05110123
Batch No. 23EOB1 Date Extracted 05/12/23 12: 43
Sample ID S-97·92·052023 Date Analyzed 05112123 12:43
Lab Samp ID 23EOB1-11 Dilution Factor 1
Lab File ID REC301 Matrix WATER
Ext Btch ID V067E14 % Moisture NA
Calib. Ref. RDC593 Instrument ID 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/l) (ug/L)
........ __ .-----_ .......... _--_._----------------_.-..... _--_ .. ----._ ... _-
1.1. 1. 2·Tetrachl oroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2·Tetrachl oroethane ND 1.0 0.10 0.20
1.1.2·Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorggropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo·3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3·Dichloro enzene ND 1.0 0.10 0.20
1.3.Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2·Chlorotoluene ND 1.0 0.25 0.50
2· Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis·1.2·Dichloroethene ND 1.0 0.10 0.20
CiS'1.3'Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m.wx~ ene ND 2.0 0.21 0.50
4-et yl·2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n·Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4·Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
.-._-------------_._-_._------... _.-._---. __ ._._--_. ----.... ---------_ ....
1.2-Dichloroethane-d4 10.4 10.0 104 70-130
4 -Bromofl uorobenzene 11.1 10.0 111 70-130
Toluene·dB 10.9 10.0 109 70-130
Dibromofluoromethane 10.6 10.0 106 70·130
Notes: Sample Amount : 25ml Final Volume : 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 43 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC301.D
Acq On 12 May 2023 12:43 pm
Sample 23E081-11
Misc 25mL
(QT Reviewed)
Vial: 16
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:19 2023 ~ Quant Results File: V067D26. RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2252915 10.00 ug/l 0.01
55 ) CHLOROBENZENE-D5 15.60 117 1590411 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 425725 10.00 ug/l 0.00
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 567479 10.57 ug/l 0.01
Spiked Amount 10.000 Recovery 105.70%
43) l,2-Dichloroethane-d4 9.30 65 425768 10.38 ug/l 0.01
Spiked Amount 10.000 Recovery 103.8'6"%
56) Toluene-d8 12.97 98 2416529 10.93 ug/l ~ 0.00
" Spiked Amount 10.000 Recovery 109.3'0% '<
;. 77 ) 4-Bromofluorobenzene 17.60 95 636870 11.08 ugly 0.00
L Spiked Amount 10.000 Recovery 110F.80%
[,Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC301.D V067D26.M Mon May 15 08:19:48 2023 Page 1
REPORT ID: 23E081 Page 44 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC301.D
Aeq On 12 May 2023 12:43 pm
Sample 23E081-11
Mise 25mL
Vial: 16
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:19 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via : Initial Calibration
A6i.indanc:e---~-~--~~----~--~ ----TIC:REC3lJ1.D
I
8000000j
I
7500000:
i
70000001
h
6500000: .
60000001
5500000
: 5000000j
I
! I
4500000; :
40000001
!
3500000i' i
!
3000000 ,
2500000 '
2000000
I
I
I
1500000:
1000000
500000:
en
ai c:
'" ~ E e
0
::J
'" 0
E e
.0
i5
en
-<i
'i'
Q) c
'" £;
Q) e sa
"" " i5
~
u.i z
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0:
0
::::l
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.... -
,i
Ii
en .,;
"% c
Q)
::J
0
I-
(RTE Integrator)
.n
0
W -<i z 0 UJ W N
Z Z
W W
'" en N
0 <li z
0: c: w
0 Q) '" N 0 ...J c:
I Q) 0:
U .0 0 e ...J
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O:-c : ,----------
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.bo 9.00 10:00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REC301.D V067D26.M Mon May 15 08:19:49 2023 Page 2
REPORT ID: 23E081 Page 45 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/03123 09: 15
Project TEAD-S Date Received: 05/10/23
Batch No. 23E081 Date Extracted: 05/12123 09: 18
Sample ID SWMU-1/25-EB-052023 Date Analyzed: 05/12123 09: 18
Lab Samp ID 23E081-12 Dilution Factor: 1
Lab File ID REC293 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/L) (ug/l)
___ .a .. ____ ..... _. ____ .......... __ .......... _. ........ _-----. .. _---_ .... ...... __ .....
1.1.1.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2.2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone 5.8J 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Ch 1 orobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform 0.18J 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m,~-xh ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene O.llJ 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4 -Di oxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT _ .... _a_ ...... __ ..... _._ .. _____ .. __ ____ a_at_a. •••• a .. ____ .. ------------_ .... --_ ....
1.2-Dichloroethane-d4 9.96 10.0 100 70-130
4-Bromofluorobenzene 10.9 10.0 109 70-130
Toluene-d8 10.7 10.0 107 70-130
Dibromofluoromethane 10.3 10.0 103 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 46 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC293.D
Acq On 12 May 2023 9:18 am
Sample 23E081-12
Mise 25mL
(QT Reviewed)
Vial: 8
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:15 2023 ~ht Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2189072 10.00 ug/l 0.01
55 ) CHLOROBENZENE-D5 15.60 117 1531394 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 398608 10.00 ug/l 0.00
System Monitoring Compounds
36 ) Dibromofluoromethane 8.21 111 537782 10.31 ug/l 0.01
Spiked Amount 10.000 Recovery 103.10%
43) l,2-Dichloroethane-d4 9.30 65 396939 9.96 ug/l ""-0.01
Spiked Amount 10.000 Recovery 99.60%
56 ) Toluene-d8 12.97 98 2284670 10.73 ug/l /' 0.00
Spiked Amount 10.000 Recovery 107.30%
77 ) 4-Bromofluorobenzene 17.60 95 584319 10.85 uglY 0.00
Spiked Amount 10.000 Recovery 108.50%
r
]Target Compounds ./ Qvalue
13) Acetone 3.61 43 51024 ~.81 ug/l 91
32) Chloroform 7.70 83 19668 /0.18 ug/l 95
57) Toluene 13.12 91 29665 0.11 ug/l 99
/
(#) = qualifier out of range (m) = manual integration
REC293.D V067D26.M Mon May 15 08:16:00 2023 Page 1
REPORT ID: 23E081 Page 47 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC293.D
Aeq On 12 May 2023 9:18 am
Sample 23E081-12
Mise 25mL
Vial: 8
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:15 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
2200000i
i
j
21000001
I
20000001
j
19000001
:1
1800000:[11
ii'
ii'
170000011
1600000ji
15000001
14000001
1300000
I 1200000i
I! ii 11000001 ' ,
i
1000000i
i
9000001
800000!
700000!
600000 1
500000i ,
1,
I'
400000j'
i i
300000; !
I
200000: ,
1000001
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC:REC21J3.D
en
oj
c:
til
! e o
'" 1 .c
i5
w z
~ z
W
aJ o a: o
::::>
...J
"-
is
..t.
i:
11
II
I:
I'
!\
[I
II
II
I[
II
II
['I,
III, Ii ~ I.~' cJ ii i ,,' e '\1 eo
o Ii ii :I~
I " 'II i~ is I, 1\ i I 1\
on o
W z
W
N
Z
W
aJ o a: g
I
U
!i il
oj o
W z
W
N
Z
W
aJ o a: o
...J
i3
is
N.
il Ii Ii Ii
0: :"~---,-, ~_\ ,'" ~ Il, j \~ L ... , -, ,r", , j\, T ,~ '. • ' ,._ i\~ Ji~~'_-_~'f',,~~_,,-____ ,
:rime--> 2.00 3.00 4.00 5.00 6li07.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00
REC293.D V067D26.M Mon May 15 08:16:01 2023 Page 2
REPORT ID: 23E081 Page 48 of 489
ADunaance-----~-~----S-can 94\3374m1nfl~[YG593~[J(T-----~---, # 13
, i Acetone
101
I , I Re~i i
I, 5,8 85 I'I
I I ' iii ! I
151
I
I Concen: 5.81 ug/l
I
RT: 3.61 min Scan# 95
Delta R.T. 0.04 min
I! I Lab File: REC293. D
" I Acq: 12 May 2023 9:18
i ,
II 167 I
am
i '. 6,6 i ~ 116 132
rn/z--> °3~4~115b'~~o70Z~~~'10~ '110~~0 130' 140
~unaance-Scan 95 (3.615 min): REC293.D
1ro1601T0~" i Tgt
Ion
43
58
Ion: 43 Resp:
Ratio Lower
100
51024
Upper
I
Ra'5{)i
I 58
I i II 78 94
[,I, 66 I I
iii,
29.6 4.9 64.9
f.bundancelon--;jr3~{r0l4270T043:70Tl~EC293:O
10000jlOn 58.00 (57.70 to 58.70): REC293.D,
I 3.61
8000: 1\
i ! \ , in/z--> O~O 40 5~ '1'60 I' 7'0' '8~" 9'0 100 110 '120' 130 140 150 '1£30 170
Abundance------SCa.I19513.615 min): REGzroTI (_) ---~---4
43
58
~bundance
i I
I II Re~j I
or: ~~4~J~4~~TI ~15~~~~74~,HI~'TI ~~~~,,~~142~0~~11 ~~aoo!0 ./0 50~oa" ;i~';~~O¥;I~~~Jgi 110 ,~o ' '30
44
I : I
, LI ill:
1
I':,i l : 0 ;-i ~If---+'I",~~~~~--,--c~-,--,J~,J-. C"-. ~~~~~,,~,~'~-.-r-r~--,--
)"/z--> 3'0 40 50 60 70 80 90 106 110 120 130
Fbundance, Scan 363 (7.697 m~): REC2!""'....-.-------I
47
6000i
4000i
2000i
#32
Chloroform
Concen: 0.18 ug/l
RT: 7.70 min Scan# 363
Delta R.T. 0.01 min
Lab File: REC293.D
Acq: 12 May 2023 9:18 am
Tgt
Ion
83
85
47
Ion: 83 Resp:
Ratio Lower
100
63.7
26.6
39.4
0.0
19668
Upper
99.4
56.0
bundancelOrll3~.01JTffZ.70-Toff370TREC293.D
lion 85.00 (84.70 to 85.70): REC293.D
5000jlon 47.00 (46.70 to 47.70): REC293.D
4000i
I
30001
!
I
2000i
1000 i
7.70
I ;-
I
i 40 Iii ! I !L
mlz __ >_0--,-3l--,--0===4='o=-__ ,J_':'~-=-0-=--=-=--'6~'o~-=--=--=-'7-=-'0-=-' -=--=-"8_0-=-~~~9-=-0-=--=--=-1~'_0=O-=-~-=-1-=-10-=-' -=--=-1-=-2=6-=--=--=-1-'--3_0--"-im_e ___ >_0_L_~, _7_.6_0~ -DO 7.80
REC293.D V067D26.M Mon May 15 08:16:02 2023 Page 3
REPORT ID: 23E081 Page 49 of 489
rbunaance, -'-------Scan 734 (13.10~RIJC593TIT-f
i 91
I I I iii ; I
! i I
! RefO] !I
If
I 65
I
Ra~1 'I
1! 2~7
0~r~'~'-'L,~,',-i5cn, TTTl~Yl' 14' i++: ITTTTTCTTTTTT~1T"~~3"""CTTT'---rpTTTTTTTTTTTT1TT'~~1~n'I'i'n1 ~
r
tn/Z--> 3,0 40 50 60 70 s'o 9'0 1'601101201301'401'50160 Ho 180 190200210 '
bundance Scan 734 (13.118 min): REC293. I 91
I
I Sub!
I' 50!
I
i j 39 51 6,5
II' ii" Ii, i o T'~'TT' *'TT, 1', CTTTrrTT'r+'+rt-n-CTTT'''T'",,-A-oTTTTTTTT'"TTT'lTTTrrTTlTTTTTrrrTfTT.n.=
,m/z--> 30 40 50 60 70
207
#57
Toluene
Concen: 0.11 ug/l
RT: 13.12 min Scan# 734
Delta R.T. 0.01 min
Lab File: REC293.D
Acq: 12 May 2023 9:18 am
Tgt
Ion
91
92
Ion: 91
Ratio
100
63.8
Resp:
Lower
32.9
29665
Upper
92.9
bundancelon 91·01J19a:70tQY1.70y-REC293:D
j
'IOn 92.00 (91.70 to 92.70): REC293.D,
10000 13.12 ,
1 \
soo01
i i
\
6000
4000
"
,I II Ii
2000
1
' j \\~,
o ! \
i I ~ --!~r-~'r'--;
ime--> 13.0013.0513.1013.1513.20
REC293.D V067D26.M Mon May 15 08:16:03 2023 Page 4
REPORT ID: 23E081 Page 50 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/03123 07:30
Project Too-S Date Received: 05/10/23
Batch No_ 23E081 Date Extracted: 05/12/23 08:53
Sample ID TB-20230503-1/25 Date Analyzed: 05/12/23 08:53
Lab Samp ID 23E081-13 Dilution Factor: 1
Lab File ID REC292 Matrix: WATER
Ext Btch ID V067E14 % Moisture: NA
Calib_ Ref_ RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/L) (ug/L) (ug/l)
--_ ........ -... _ ... _--...... _--------_._ .. _ .. ---------_.-.-...... _ .. _ ... .. _ .. _ ..... _--
1.1.1.2-Tetrachloroethane ND 1.0 0_10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m.WXf; ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Meth{l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene NO 1.0 0.25 0.50
Trichloroethene NO 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2-0ibromoethane NO 1.0 0.10 0.20
1.2.3-Trichlorobenzene NO 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK fIlo1T %RECOVERY QC LIMIT -_ ......... _ ............... -_ .... _ ..... --_._-_ ...... -_._-_ .. __ ... . .... _ .......... ----_ ........
1.2-Dichloroethane-d4 9.56 10.0 96 70-130
4-Bromofluorobenzene 11.2 10.0 112 70-130
Toluene-d8 11.0 10.0 110 70-130
Dibromofluoromethane 10.1 10.0 101 70-130
Notes: Sample Amount : 25ml Final Volume : 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 51 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC292.D
Acq On 12 May 2023 8:53 am
Sample 23E081-13
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:15 2023
Vial: 7
Operator: VLu
Inst 67
Multiplr: 1.00
~ant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.15 114 2288364 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1564372 10.00 ug/l 0.00
74) 1,2-DICHLOROBENZENE-D4 19.49 152 397292 10.00 ug/l 0.00
System Monitoring Compounds
36 ) Dibromofluoromethane 8.21 III 551091 10.10 ug/l 0.02
{-Spiked Amount 10.000 Recovery 101.00%
43 ) 1,2-Dichloroethane-d4 9.31 65 398043 9.56 ug/l ~.02
Spiked Amount 10.000 Recovery 95.60%
56) Toluene-d8 12.97 98 2400179 11.03 ug/l /0.00
\": Spiked Amount 10.000 Recovery 110 y,o%
T 77) 4-Bromofluorobenzene 17.61 95 598870 11.16 ug/ 0.00
Spiked Amount 10.000 Recovery 111.60%
r~ ,/
~<Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC292.D V067D26.M Mon May 15 08:15:24 2023 Page 1
REPORT ID: 23E081 Page 52 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC292.D
Aeq On 12 May 2023 8:53 am
Sample 23E081-13
Mise 25mL
Vial: 7
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:15 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
8000000!
7500000
7000000i
1
Ii
650000011
II
, I
6000000: ,
I
I:
55000001 '
5000000:
:
1
45000001,
I
I
I
1
4000000:
i
35000001 : I!
3000000!
I
2500000) .
, I
!
2000000:
1500000'
i i
: I
10000001
I
500000:
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RECZ92JJ
en
ai ui ~ z
W t:
N Ql
:0 Z '0 w f-eo
0 a:
0
::J
...J
"-0
~.
en
oj en
t: ~ III ~ £
Ql t: E III
Ie £
0 Ql
:0 Ie '" .2 0
E .<:::
0 Ie is ,g N. 0
.n a
ill z
W
N
Z w eo en 0 oj a: t:
0 Ql
...J N
I t:
Ql U .c
Ie
0
:0
'" 0
E
Ie eo ...
~ a
ill z w
N
Z w eo
0 a:
0
--' I
U
0
N.
O-~'~'T=~~''''''''--' -----;-~-_ _,_L~~_C+---'-,'-,---r~~~--r'--'--,-.--r---r~.,,'-;-_~~-_---c_---
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11:00 12:00 13:0014:00 15.00 16:00 17.00 18.00 19.0020.00 21.00
REC292.D V067D26.M Mon May 15 08:15:25 2023 Page 2
REPORT ID: 23E081 Page 53 of 489
QC SUMMARIES
REPORT ID: 23E081 Page 54 of 489
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/12/23 08:27
Project TEAD·S Date Received: 05/12/23
Batch No. 23E081 Date Extracted: 05/12/23 08:27
Sample ID MBLK1W Date Analyzed: 05/12/23 08:27
Lab Samp ID V067E14B Dilution Factor: 1
Lab File ID REC291 Matrix: WATER
Ext Btch ID V067E14 % MOisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOO DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/l) (ug/l)
............ _---_ ...... _--.----_ ... __ .. ... _--.. _--_ .. __ ·"_a ••• •• .... -........ ..-.........
1. 1. 1. 2·Tetrachloroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2·Tetrachl oroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1·Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3.Trichlorgcropane ND 2.0 0.25 0.50
1.2.4·Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo·3·chloropropane ND 2.0 0.25 0.50
1.2·Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2.Dichlorogropane ND 1.0 0.10 0.20
1.3·Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4·Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2·Chlorotoluene ND 1.0 0.25 0.50
2·Hexanone ND 20 5.0 10
4·Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS'1.3'Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m,~,xh ene ND 2.0 0.21 0.50
4· et yl·2·Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert·butyl ether (MTBE) ND 1.0 0.15 0.30
n·Butylbenzene ND 1.0 0.25 0.50
n· Propyl benzene ND 1.0 0.25 0.50
o·Xylene ND 1.0 0.10 0.20
~'Isopro~bltoluene ND 1.0 0.25 0.50
ec·Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans·1.2·Dichloroethene ND 1.0 0.10 0.20
Trans-1.3·Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2·Dibromoethane ND 1.0 0.10 0.20
1.2.3·Trichlorobenzene ND 1.0 0.15 0.30
1.4·Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
..... a ...... __ • _____ ..... __ • _______ .. _ .... _---_ .... ___ .a.a. ___ ... --........ -.-----" ... _ ..
1.2·Dichloroethane·d4 10.0 10.0 100 70·130
4-Bromofluorobenzene 11.0 10.0 110 70·130
Toluene·d8 10.8 10.0 108 70·130
Dibromofluoromethane 10.3 10.0 103 70·130
Notes: Sample Amount : 25ml Final Volume : 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E081 Page 55 of 489
EMAX QUALITY CONTROL OATA
LAB CONTROL S.AMPLE ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23EOB1
METHOD SWS030B/B260C
MATRIX : WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
S.AMPLE ID : MBLK1W LCS1W LCDlW
LAB S.AMPLE ID : V067E14B V067E14L V067E14C
LAB FILE ID : REC291 REC288 REC2B9
DATE PREPARED : 05/12/23 OB:27 05/12/23 07:10 05/12/23 07: 36
DATE ANALYZED : 05112123 OB:27 05/12/23 07:10 05/12/23 07:36
PREP BATCH : V067E14 V067E14 V067E14
CALIBRATION REF: RDC593 RDC593 RDC593
ACCESSION:
MBResult SpikeAmt LCSResult LCSRec SpikeAmt LCOResult LCDRec RPD QCLimit MaxRPD
PAR.AMETERS (ug/l) (ug/l) (ug/l) (%l (ug/l) (ug/l) (%l (%l (%l (%)
------------.. ----_ .. _.---_._.-... __ a •• ·_· .......... ....... __ ...... ...... __ .............. .. .......... --_ .. _----
1,1,1,2-Tetrachloroethane NO 10.0 11.2 112 10.0 11.3 113 1 7B-124 20
1,1,1-Trichloroethane NO 10.0 10.B lOB 10.0 10.B lOB 0 74-131 20
1,1,2,2-Tetrachloroethane NO 10.0 10.B lOB 10.0 11.0 110 2 71-121 20
1,1,2-Trichloroethane NO 10.0 10.B lOB 10.0 11.0 110 2 BO-119 20
1,1-Dichloroethane NO 10.0 10.5 105 10.0 10.5 105 0 77-125 20
1,1-Dichloroethene NO 10.0 10.B lOB 10.0 10.4 104 4 71-131 20
1,1-Dichloropropene NO 10.0 9.76 9B 10.0 9.B6 99 1 79-125 20
1,2,3-Trichlorogropane NO 10.0 10.3 103 10.0 10.7 107 4 73-122 20
1,2,4-Trichloro enzene NO 10.0 10.6 106 10.0 10.6 106 0 69-130 20
1,2-Dibromo-3-chloropropane NO 10.0 9.64 96 10.0 9.93 99 3 62-12B 20
1,2-Dichlorobenzene NO 10.0 10.3 103 10.0 10.4 104 1 BO-119 20
1,2-Dichloroethane NO 10.0 9.99 100 10.0 10.2 102 2 73-12B 20
1,2-Dichlorggropane NO 10.0 10.5 105 10.0 10.5 105 0 7B-122 20
1,3-Dichloro enzene NO 10.0 10.3 103 10.0 10.4 104 1 BO-119 20
1,3-Dichlorogropane NO 10.0 10.5 105 10.0 10.B lOB 3 BO-119 20
1,4-Dichloro enzene NO 10.0 10.4 104 10.0 10.4 104 0 79-11B 20
2,2-DiChlOrO~rO~ane NO 10.0 11.5 115 10.0 11.4 114 1 60-139 20
2-Butanone ( EK NO 50.0 53.B lOB 50.0 51.4 103 5 56-143 20
2-Chlorotoluene NO 10.0 10.4 104 10.0 10.6 106 2 79-122 20
2-Hexanone NO 50.0 50.2 100 50.0 50.B 102 1 57-139 20
4-Chlorotoluene NO 10.0 10.3 103 10.0 10.1 101 2 7B-122 20
Acetone NO 50.0 56.1 112 50.0 54.6 109 3 39-160 20
Benzene NO 10.0 10.4 104 10.0 10.5 105 1 79-120 20
Bromobenzene NO 10.0 10.B lOB 10.0 10.7 107 1 BO-120 20
Bromochloromethane NO 10.0 10.5 105 10.0 10.5 105 0 7B-123 20
Bromodichloromethane NO 10.0 10.5 105 10.0 10.5 105 0 79-125 20
Bromoform NO 10.0 9.91 99 10.0 9.94 99 0 66-130 20
Bromomethane NO 10.0 12.1 121 10.0 11.2 112 B 53-141 20
Carbon Disulfide NO 10.0 12.2 122 10.0 11.4 114 7 64-133 20
Carbon Tetrachloride NO 10.0 10.6 106 10.0 10.6 106 0 72-136 20
Chlorobenzene NO 10.0 10.5 105 10.0 10.5 105 0 B2-11B 20
Chloroethane NO 10.0 11.9 119 10.0 10.9 109 9 60-138 20
Chloroform NO 10.0 10.7 107 10.0 10.7 107 0 79-124 20
Chloromethane NO 10.0 10.5 105 10.0 9.61 96 9 50-139 20
cis-1,2-Dichloroethene NO 10.0 10.6 106 10.0 10.6 106 0 7B-123 20
CiS-1,3-DiChlOro~rOpene NO 10.0 10.4 104 10.0 10.5 105 1 75-124 20
Dibromochloromet ane NO 10.0 10.4 104 10.0 10.5 105 1 74-126 20
Dibromomethane NO 10.0 10.1 101 10.0 10.2 102 1 79-123 20
Dichlorodifluoromethane NO 10.0 11.7 117 10.0 11.0 110 6 32-152 20
Ethyl benzene NO 10.0 10.B lOB 10.0 10.B lOB 0 79-121 20
ISOpro~Ylbenzene NO 10.0 11.0 110 10.0 11.1 111 1 72-131 20
m,wxf; ene NO 20.0 21.9 110 20.0 21.9 110 0 BO-121 20
4-et yl-2-Pentanone NO 50.0 4B.4 97 50.0 4B.4 97 0 67-130 20
Methylene Chloride NO 10.0 9.70 97 10.0 9.60 96 1 74-124 20
Meth{l tert-butyl ether (MTBEl NO 10.0 10.4 104 10.0 10.5 105 1 71-124 20
n-Bu ylbenzene NO 10.0 10.7 107 10.0 10.6 106 1 75-12B 20
n-Propylbenzene NO 10.0 11.2 112 10.0 11.2 112 0 76-126 20
o-Xylene NO 10.0 11.1 111 10.0 11.1 111 0 7B-122 20
~-Isopro~bltoluene NO 10.0 11.2 112 10.0 10.9 109 3 77-127 20
ec-Buty enzene NO 10.0 11.5 115 10.0 11.4 114 1 77-126 20
Styrene NO 10.0 9.42 94 10.0 9.71 97 3 7B-123 20
Tert-Butylbenzene NO 10.0 11.2 112 10.0 11.2 112 0 7B-124 20
Tetrachloroethene NO 10.0 10.B lOB 10.0 10.B lOB 0 74-129 20
Toluene NO 10.0 10.7 107 10.0 10.B lOB 1 BO-121 20
Trans-1,2-Dichloroethene NO 10.0 10.3 103 10.0 10.3 103 0 75-124 20
Trans-1,3-Dichloropropene NO 10.0 10.4 104 10.0 10.6 106 2 73-127 20
Trichloroethene NO 10.0 9.95 100 10.0 10.0 100 1 79-123 20
Trichlorofluoromethane NO 10.0 12.6 126 10.0 11.3 113 11 65-141 20
Vinyl Chloride NO 10.0 11.4 114 10.0 10.6 106 7 5B-137 20
1,2-Dibromoethane NO 10.0 10.4 104 10.0 10.7 107 3 77-121 20
1,2,3-Trichlorobenzene NO 10.0 10.4 104 10.0 10.5 105 1 69-129 20
1.4 -Di oxane NO 200 200 100 200 201 101 0 59-139 20
SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCDRec QCLimit
SURROGATE PAR.AMETERS (ug/Ll (ug/Ll (%l (ug/Ll (ug/l) (%l (%l
. __ ........... _ .. ---_ ............ _ .... ---".---_ .. ---.-..... -....... "._. . ............ ._ .. a .. ____ •
1,2-Dichloroethane-d4 10.0 10.5 105 10.0 10.5 105 70-130
4-Bromofluorobenzene 10.0 10.4 104 10.0 10.5 105 70-130
Toluene-dB 10.0 10.B lOB 10.0 11.0 110 70-130
Dibromofluoromethane 10.0 10.B lOB 10.0 10.B lOB 70-130
MB: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
REPORT ID: 23E081 Page 56 of 489
EMAX QUALITY CONTROL DATA
MS/MSD ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E081
METHOD SWS030B/8260C
MATRIX : WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID : S-68-90-052023 S-68-90-052023MS S-68-90-052023MSD
LAB SAMPLE ID : 23E081-06 23E081-06M 23EOB1-06S
LAB FILE ID : REC294 REC305 REC306
DATE PREPARED : 05/12/23 09:44 05/12/23 14:26 05/12/23 14:52
DATE ANALYZED : 05/12/23 09:44 05/12/23 14:26 05/12/23 14:52
PREP BATCH : V067E14 V067E14 V067E14
CALIBRATION REF: RDC593 RDC593 RDC593
ACCESSION:
PSResult SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/L) (%l (ug/L) (ug/L) (%l (%) (%l (%)
~ .......................................................... ......... __ . .. .. -.. -.... ...... __ ... --. ......... _-.. -....... _--... _ .... __ .... . .............
1.1.1.2-Tetrachloroethane ND 10.0 9.96 100 10.0 9.84 9B 1 78-124 20
1. 1. I-Trichloroethane ND 10.0 9.84 98 10.0 9.29 93 6 74-131 20
1. 1. 2. 2-Tetrachloroethane ND 10.0 9.79 98 10.0 10.0 100 2 71-121 20
1.1.2-Trichloroethane ND 10.0 10.3 103 10.0 10.5 105 2 80-119 20
1.1-Dichloroethane ND 10.0 9.87 99 10.0 9.60 96 3 77-125 20
1.1-Dichloroethene ND 10.0 9.03 90 10.0 8.68 87 4 71-131 20
1.1-Dichloropropene ND 10.0 9.38 94 10.0 8.76 88 7 79-125 20
1.2.3-Trichlorogropane ND 10.0 9.53 95 10.0 9.80 98 3 73-122 20
1.2.4-Trichloro enzene ND 10.0 9.72 97 10.0 10.1 101 4 69-130 20
1.2-Dibromo-3-chloropropane ND 10.0 9.01 90 10.0 9.40 94 4 62-128 20
1.2-Dichlorobenzene ND 10.0 9.46 95 10.0 9.39 94 1 80-119 20
1.2-Dichloroethane NO 10.0 10.6 106 10.0 10.6 106 0 73-128 20
1.2-Dichlorogro pane ND 10.0 10.2 102 10.0 10.3 103 1 78-122 20
1.3-Dichloro enzene NO 10.0 9.32 93 10.0 9.16 92 2 80-119 20
1.3-Dichlorogropane ND 10.0 10.1 101 10.0 10.2 102 1 80-119 20
1.4-0ichloro enzene NO 10.0 9.11 91 10.0 9.02 90 1 79-118 20
2.2-Dichloro~ro~ane ND 10.0 8.76 88 10.0 8.38 84 4 60-139 20
2-Butanone ( EK ND 50.0 48.9 98 50.0 52.0 104 6 56-143 20
2-Chlorotoluene ND 10.0 8.97 90 10.0 8.64 86 4 79-122 20
2-Hexanone ND 50.0 49.9 100 50.0 52.0 104 4 57-139 20
4-Chlorotoluene ND 10.0 8.53 85 10.0 8.31 83 3 78-122 20
Acetone ND 50.0 47.5 95 50.0 50.2 100 6 39-160 20
Benzene ND 10.0 10.1 101 10.0 9.70 97 4 79-120 20
Bromobenzene ND 10.0 9.52 95 10.0 9.42 94 1 80-120 20
Bromochloromethane ND 10.0 10.0 100 10.0 10.1 101 1 78-123 20
Bromodichloromethane ND 10.0 10.2 102 10.0 10.1 101 1 79-125 20
Bromoform ND 10.0 9.40 94 10.0 9.65 97 3 66-130 20
Bromomethane ND 10.0 9.93 99 10.0 10.3 103 4 53-141 20
Carbon Disulfide ND 10.0 11. 7 117 10.0 11.7 117 0 64-133 20
Carbon Tetrachloride ND 10.0 9.72 97 10.0 8.99 90 8 72-136 20
Chlorobenzene ND 10.0 9.79 98 10.0 9.58 96 2 82-118 20
Chloroethane NO 10.0 11.6 116 10.0 12.1 121 4 60-138 20
Chloroform ND 10.0 10.3 103 10.0 10.0 100 3 79-124 20
Chloromethane ND 10.0 8.91 89 10.0 8.99 90 1 50-139 20
cis-1.2-Dichloroethene ND 10.0 9.81 98 10.0 9.59 96 2 78-123 20
CiS-1.3-Dichloro~ropene ND 10.0 10.2 102 10.0 10.2 102 0 75-124 20
Dibromochloromet ane ND 10.0 9.93 99 10.0 9.98 100 1 74-126 20
Dibromomethane ND 10.0 10.0 100 10.0 10.1 101 1 79-123 20
Dichlorodifluoromethane ND 10.0 8.67 87 10.0 9.05 91 4 32-152 20
Ethyl benzene ND 10.0 9.52 95 10.0 9.11 91 4 79-121 20
ISOpro~Ylbenzene ND 10.0 9.25 93 10.0 8.87 89 4 72-131 20
mtXF; ene ND 20.0 19.3 97 20.0 18.6 93 4 80-121 20
4-et yl-2-Pentanone ND 50.0 50.4 101 50.0 52.2 104 4 67-130 20
Methylene Chloride ND 10.0 9.20 92 10.0 9.25 93 1 74-124 20
Meth{l tert-butyl ether (MTBEl ND 10.0 10.4 104 10.0 10.8 108 4 71-124 20
n-Bu ylbenzene NO 10.0 8.60 86 10.0 8.27 83 4 75-128 20
n-Propylbenzene ND 10.0 9.02 90 10.0 8.57 86 5 76-126 20
o-Xylene ND 10.0 10.1 101 10.0 9.80 98 3 78-122 20
~-Isopro~bltoluene ND 10.0 8.82 88 10.0 8.48 85 4 77-127 20
ec-Buty enzene ND 10.0 9.26 93 10.0 8.74 87 6 77-126 20
Styrene ND 10.0 3.70 37* 10.0 3.85 39* 4 78-123 20
Tert-8utylbenzene ND 10.0 9.29 93 10.0 8.85 89 5 78-124 20
Tetrachloroethene ND 10.0 9.43 94 10.0 8.84 88 6 74-129 20
Toluene ND 10.0 9.53 95 10.0 9.20 92 4 80-121 20
Trans-1.2-Dichloroethene ND 10.0 9.11 91 10.0 8.77 88 4 75-124 20
Trans-1.3-0ichloropropene ND 10.0 9.94 99 10.0 9.99 100 1 73-127 20
Trichloroethene ND 10.0 9.87 99 10.0 9.46 95 4 79-123 20
T ri ch 1 orofl uoromethane ND 10.0 11.8 118 10.0 12.2 122 3 65-141 20
Vinyl Chloride ND 10.0 10.8 108 10.0 11.1 111 3 58-137 20
1.2-Dibromoethane NO 10.0 10.0 100 10.0 10.0 100 0 77-121 20
1.2.3-Trichlorobenzene ND 10.0 9.51 95 10.0 10.3 103 8 69-129 20
1.4 -Di oxane ND 200 199 100 200 207 104 4 59-139 20
SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec QCLimit
SURROGATE PARAMETERS (ug/Ll (ug/L) (%) (ug/L) (ug/L) (%l (%l
.... _--_.-........ __ ...... __ ................ . ----_ ...... .---_ ..... _ .. _--... --_ ........... .. .. _ ...........
1.2-Dichloroethane-d4 10.0 11.0 110 10.0 11.1 111 70-130
4-Bromofluorobenzene 10.0 9.93 99 10.0 9.90 99 70-130
Toluene-d8 10.0 10.5 105 10.0 10.4 104 70-130
Dibromofluoromethane 10.0 10.9 109 10.0 11.1 111 70-130
PS: Parent Sample MS: Matrix Spike MSD: Matrix Spike Duplicate
* Out of QC Limit
REPORT ID: 23E081 Page 57 of 489
EMAX QUALITY CONTROL DATA
MS/MSD ANALYSIS
CLIENT BRICE
PROJECT TEAD·S
BATCH NO. 23EOB1
METHOD SW5030B/B260C
MATRIX : WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE 10 : S· 70·90·052023 S·70·90·052023MS S·70·90·052023MSD
LAB SAMPLE 10 : 23EOB1·07 23E081·0lM 23E081·07S
LAB FILE 10 : REC295 REC307 REC308
DATE PREPARED : 05112/23 10:10 05/12/23 15:18 05/12123 15:44
DATE ANALYZED : 05/12/23 10:10 05/12/23 15:18 05112123 15:44
PREP BATCH : V067E14 V067E14 V067E14
CALIBRATION REF: RDC593 RDC593 RDC593
ACCESSION:
PSResult SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec RPD QCLimit MaxRPD
PARAMETERS (ug/l) (ug/l) (ug/l) (%) (ug/l) (ug/L) (%) (%) (%) (%)
. __ ................. ------_ ...... _ .. ......... _ .. .. .......... ......... -_ ... _.-.... _ ... _ .. _-----..-_ .. -...... . .... _ ........
1.1.1.2·Tetrachloroethane ND 10.0 10.3 103 10.0 9.64 96 7 78·124 20
1.1.1·Trichloroethane ND 10.0 10.3 103 10.0 9.33 93 10 74·131 20
1. 1. 2.2·Tetrachloroethane ND 10.0 10.2 102 10.0 10.0 100 2 71·121 20
1. 1. 2·Trichloroethane ND 10.0 10.5 105 10.0 10.1 101 4 80·119 20
1.1·Dichloroethane ND 10.0 10.5 105 10.0 9.43 94 11 77·125 20
1.1·0ichloroethene ND 10.0 9.46 95 10.0 8.41 84 12 71·131 20
1.1,Oichloropropene ND 10.0 9.74 97 10.0 8.71 87 11 79·125 20
1.2.3.TriChlorogropane NO 10.0 10.1 101 10.0 9.71 97 4 73·122 20
1.2.4·Trichloro enzene ND 10.0 10.3 103 10.0 9.65 97 7 69·130 20
1.2·Dibromo·3·chloropropane ND 10.0 9.90 99 10.0 9.72 97 2 62·128 20
1.2·Dichlorobenzene ND 10.0 9.87 99 10.0 9.35 94 5 80·119 20
1.2,Oichloroethane ND 10.0 11.0 110 10.0 10.2 102 8 73·128 20
1.2.OiChlOrO~Opane ND 10.0 10.8 108 10.0 9.92 99 8 78·122 20
1.3·Dichloro nzene ND 10.0 9.51 95 10.0 8.90 89 7 80·119 20
1.3.DiChlorogropane NO 10.0 10.4 104 10.0 9.92 99 5 80·119 20
1.4·Dichloro enzene ND 10.0 9.49 95 10.0 8.95 90 6 79·118 20
2.2.OiChlOrO~rO~ane ND 10.0 9.10 91 10.0 8.17 82 11 60·139 20
2·8utanone ( EK ND 50.0 52.0 104 50.0 49.9 100 4 56·143 20
2·Chlorotoluene ND 10.0 9.30 93 10.0 8.49 85 9 79·122 20
2· Hexanone ND 50.0 52.3 105 50.0 50.8 102 3 57·139 20
4·Chlorotoluene ND 10.0 9.05 91 10.0 8.45 85 7 78·122 20
Acetone ND 50.0 51.8 104 50.0 48.4 97 7 39·160 20
Benzene ND 10.0 10.5 105 10.0 9.45 95 11 79·120 20
Bromobenzene ND 10.0 9.92 99 10.0 9.41 94 5 80·120 20
Bromochloromethane ND 10.0 10.5 105 10.0 9.81 98 7 78·123 20
Bromodi chloromethane ND 10.0 10.6 106 10.0 9.91 99 7 79·125 20
Bromoform ND 10.0 9.80 98 10.0 9.65 97 2 66·130 20
Bromomethane ND 10.0 10.8 108 10.0 10.0 100 8 53·141 20
Carbon Disulfide NO 10.0 11.9 119 10.0 11.5 115 3 64·133 20
Carbon Tetrachloride ND 10.0 10.2 102 10.0 9.14 91 11 72·136 20
Chlorobenzene ND 10.0 10.2 102 10.0 9.38 94 8 82·118 20
Chloroethane ND 10.0 12.8 128 10.0 11.7 117 9 60·138 20
Chloroform ND 10.0 10.7 107 10.0 9.75 98 9 79·124 20
Chloromethane ND 10.0 9.32 93 10.0 9.03 90 3 50·139 20
cis·1.2·Dichloroethene NO 10.0 10.2 102 10.0 9.33 93 9 78·123 20
CiS'1.3'Dichloro~ropene ND 10.0 10.6 106 10.0 9.72 97 9 75·124 20
Oibromochloromet ane ND 10.0 10.2 102 10.0 9.71 97 5 74·126 20
Dibromomethane ND 10.0 10.3 103 10.0 9.77 98 5 79·123 20
Dichlorodifluoromethane ND 10.0 9.40 94 10.0 8.30 83 12 32·152 20
Ethyl benzene NO 10.0 9.84 98 10.0 9.02 90 9 79·121 20
IsoprO~YlbenZene ND 10.0 9.61 96 10.0 8.91 89 8 72·131 20
m.wxf; ene NO 20.0 19.8 99 20.0 18.3 92 8 80·121 20
4· et yl·2·Pentanone NO 50.0 53.1 106 50.0 50.0 100 6 67·130 20
Methylene Chloride ND 10.0 9.69 97 10.0 8.79 88 10 74·124 20
Methyl tert·butyl ether (MTBE) ND 10.0 11.0 110 10.0 10.4 104 6 71·124 20
n· Butyl benzene ND 10.0 9.19 92 10.0 8.28 83 10 75·128 20
n·Propylbenzene ND 10.0 9.45 95 10.0 8.71 87 8 76·126 20
o·Xylene ND 10.0 10.4 104 10.0 9.59 96 8 78·122 20
~.Isopro~bltoluene ND 10.0 9.39 94 10.0 8.56 86 9 77·127 20
ec·Buty enzene ND 10.0 9.66 97 10.0 8.94 89 8 77·126 20
Styrene ND 10.0 3.01 30* 10.0 2.57 26* 16 78·123 20
Tert·Butylbenzene ND 10.0 9.69 97 10.0 8.88 89 9 78·124 20
Tetrachloroethene ND 10.0 9.77 98 10.0 8.76 88 11 74·129 20
Toluene ND 10.0 9.88 99 10.0 9.07 91 9 80·121 20
Trans·1.2·Dichloroethene ND 10.0 9.72 97 10.0 8.69 87 11 75·124 20
Trans·1.3·Dichloropropene ND 10.0 10.3 103 10.0 9.72 97 6 73·127 20
T ri c h 1 oroethene ND 10.0 10.3 103 10.0 9.31 93 10 79·123 20
Trichlorofluoromethane ND 10.0 12.4 124 10.0 12.0 120 3 65·141 20
Vinyl Chloride ND 10.0 11.6 116 10.0 10.9 109 6 58·137 20
1.2·Dibromoethane NO 10.0 10.3 103 10.0 9.83 98 5 77·121 20
1.2.3·Trichlorobenzene ND 10.0 10.3 103 10.0 10.2 102 1 69·129 20
l,4·Dioxane ND 200 207 104 200 201 101 3 59·139 20
SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec QCLimit
SURROGATE PARAMETERS (ug/l) (ug/L) (%) (ug/L) (ug/l) (%) (%)
-........ -_ .......... -_ ....... ---...... _-----........... ........ -_ .... ..--_ ....... .. ..... -..... -... -...........
1.2·Dichloroethane·d4 10.0 11.1 111 10.0 10.9 109 70·130
4·Bromofluorobenzene 10.0 10.0 100 10.0 10.1 101 70·130
Toluene·d8 10.0 10.5 105 10.0 10.5 105 70·130
Dibromofluoromethane 10.0 11.1 111 10.0 10.9 109 70·130
PS: Parent Sample MS: Matrix Spike MSD: Matrix Spike Duplicate
* Out of QC Limit
REPORT ID: 23E081 Page 58 of 489
QC DATA
REPORT ID: 23E081 Page 59 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC291.D
Acq On 12 May 2023 8:27 am
Sample V067E14B
Misc 25mL
(QT Reviewed)
Vial: 6
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 12 12:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration ~
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.15 114 2368690 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1664623 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 430496 10.00 ug/l 0.00
~System Monitoring Compounds
36 ) Dibromofluoromethane 8.21 111 581453 10.30 ug/l 0.02
Spiked Amount 10.000 Recovery 103?%
43 ) l,2-Dichloroethane-d4 9.31 65 432771 10.04 ug/" 0.02
Spiked Amount 10.000 Recovery 100 .4~
56) Toluene-d8 12.97 98 2490625 10.76 ug/l 0.00
Spiked Amount 10.000 Recovery 107.60%
77 ) 4-Bromofluorobenzene 17.60 95 638591 10.98 uglY 0.00
Spiked Amount 10.000 Recovery 109.80%
/
'" Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC291.D V067D26.M Mon May 15 08:09:51 2023 Page 1
REPORT ID: 23E081 Page 60 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC291.D
Aeq On 12 May 2023 8:27 am
Sample V067E14B
Mise 25mL
Vial: 6
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 12 12:29 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
rbundancei
I 75000001
I I
i
70000001
6500000
I
I 6000000j , I
I
j
5500000:
I
!i
5000000i.
II
4500000; !
4000000
35000001
)
300000011
I'
I'
I
2500000j
I
2000000j
15000001 i
1000000!
500000:
j I
j \
: \
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC291.D
'" 05
w % z c: w " N :0
Z (5
W I-eo
0
Il:
0
::;)
....I u..
15
..t.
'" oi '" c ~ to % ;5
" c E '" e ~ 0
:0 e 0= 0 0
E 1"
0 ~ j5
j5 «;
.n
0
W z w
N z
W eo
0
Il:
0
....I
I
U
Ii
Ii I
'" oi c:
" N c:
" .0 e
0
:0
0= 0
E e eo ..t
1\ II i \,--------J\ J' II 11
]1 /\ )1
~
0
W
Z w
N
Z
W eo
0
Il:
0
....I
I
U
15 «;
Irime--> 02:00 ' 3.00' 4.00 5.00 6.00 7.bo a.bb i 'i i ' I' 'i' I" I' , f' I I" I I I' . , : i :' 'i
9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00
REC291.D V067D26.M Mon May 15 08:09:52 2023 Page 2
REPORT ID: 23E081 Page 61 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC288.D
Acq On 12 May 20/.3 7:10 am
Sample V067E14L
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:13 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023 ~
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev{Min)
1) 1/4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1/2-DICHLOROBENZENE-D4
) System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) 1/2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
~. Spiked Amount 10.000
" 77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1/1/2-Trichloro-1/2/2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1/2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l/l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2/2-Dichloropropane
31) cis-1/2-Dichloroethene
32) Chloroform
10.15 114
15.60 117
19.49 152
8.21
9.30
12.97
17.60
1. 88
2.16
2.28
2.66
2.72
2.76
2.99
3.53
3.59
3.61
3.78
3.94
4.25
4.31
4.53
4.54
4.78
4.82
5.05
5.71
5.90
5.96
6.65
6.94
7.23
7.33
7.71
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
1972534
1423507
430893
10.00 ug/l
10.00 ug/l
10.00 ug/l
507770 10.80
Recovery
377895 10.53
Recovery =
2144936 10.84
Recovery
606598 10.42
Recovery
ug/l
108.00%
ug/l~
105.30%
ug/ I./'
108.40%
uglY
10;;.20%
0.02
0.00
0.00
0.02
0.02
0.00
0.00
Qvalue
704520
1099721
1052443
692878
720030
1227832
851127
187803
473292
443552
1170219
490562
925394
276274
2748609
889219
525137
983100
770685
2329530
1267557
775052
1534947
141697
908694
750516
1048413
11.70 ug/l
10.52 ug/l
11.36 ug/l
12.13 ug/l
11.86 ug/l
10.70 ug/l
12.57 ug/l
40.65 ug/l
10.72 ug/l
56.07 ug/l
10.81 ug/l
225.72 ug/l
9.77 ug/l
10.74 ug/l
12.18 ug/l
9.70 ug/l
50.60 ug/l
10.43 ug/l
10.32 ug/l
10.69 ug/l
10.48 ug/l
11. 21 ug/l
10.27 ug/l
53.85 ug/l
11.52 ug/l
10.60 ug/l
10.73 ug/l
99
98
99
100
99
100
100
97
99
99
99
100
98
99
100
99
97
100
100
100
100
100
99
96
99
99
99
(#) = qualifier out of range (m) = manual integration
REC288.D V067D26.M Mon May 15 08:13:30 2023 Page 1
REPORT ID: 23E081 Page 62 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC288.D
Acq On 12 May 2023 7:10 am
Sample V067E14L
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:13 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) 1,1,1-Trichloroethane
40) 1,1-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) 1,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) 1,2-Dichloropropane
49) Bromodichloromethane
50) 1,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) 1,1,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.17
8.57
8.60
8.94
9.11
9.26
9.48
9.51
10.74
10.82
11.09
11.53
11.63
11.61
12.21
12.26
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.26
14.61
14.96
15.28
15.68
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
302881
79895
1225789
878559
329378
702017
240135
2747159
462373
647854
1355503
623498
674028
46051
240676
18800
1404901
872766
2719162
595976
350506
326016
889593
623059
542485
345837
279228
1163679
1518512
475650
3064247
4502298
2157108
1402563
2795040
151457
319029
81928
78606
3509407
477780
(#) = qualifier out of range (m) = manual integration
REC288.D V067D26.M Mon May 15 08:13:31 2023
10.54 ug/l
9.36 ug/l
11.13 ug/l
10.77 ug/l
9.76 ug/l
10.65 ug/l
10.32 ug/l
10.43 ug/l
9.99 ug/l
9.95 ug/l
11.04 ug/l
10.50 ug/l
10.49 ug/l
199.70 ug/l
10.10 ug/l
1.76 ug/l
48.43 ug/l
10.43 ug/l
10.74 ug/l
10.44 ug/l
8.48 ug/l
10.84 ug/l
50.19 ug/l
10.51 ug/l
10.80 ug/l
10.37 ug/l
10.44 ug/l
10.75 ug/l
10.52 ug/l
11.23 ug/l
10.76 ug/l
21.86 ug/l
11.11 ug/l
9.42 ug/l
11.01 ug/l
9.91 ug/l
10.80 ug/l
,)-0.31 ug/l
9.51 ug/l
11.20 ug/l
10.83 ug/l
Qvalue
98
96
98
98
99
99
99
100
99
99
99
98
99
99
98
79
98
100
100
89
100
97
100
99
99
100
99
99
99
100
100
99
100
98
100
99
100
97
96
99
100
Page 2
REPORT ID: 23E081 Page 63 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC288.D
Aeq On 12 May 2023 7:10 am
Sample V067E14L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:13 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) l,3,5-Trimethylbenzene 18.04 105 2149215 11.00 ug/l
83) 2-Chlorotoluene 18.06 91 2106316 10.43 ug/l
84) 4-Chlorotoluene 18.12 91 1705570 10.28 ug/l
85) tert-Butylbenzene 18.48 134 483869 11. 23 ug/l ,', 86) 1, 2, 4-Trimethylbenzene 18.52 105 1995738 11.01 ug/l
~~: 87) see-Butylbenzene 18.74 105 2983262 11.52 ug/l
,;.! 88) p-Isopropyltoluene 18.90 119 2267684 11.15 ug/l
89) l,3-Diehlorobenzene 19.01 146 913051 10.34 ug/l
90 ) l,4-Diehlorobenzene 19.12 146 895530 10.42 ug/l
':..-;, 91 ) n-Butylbenzene 19.34 91 2069734 10.69 ug/l
-92) l,2-Diehlorobenzene 19.52 146 718926 10.34 ug/l
93) l,2-Dibromo-3-ehloropropan 20.31 157 29286 9.64 ug/l
94) l,2,4-Triehlorobenzene 21.17 180 310683 10.60 ug/l
95) Hexaehlorobutadiene 21. 29 225 265744 10.77 ug/l
96) Naphthalene 21.45 128 345224 9.20 ug/l
97) l,2,3-Triehlorobenzene 21.70 180 208202 10.41 ug/l
(#) = qualifier out of range (m) = manual integration
REC288.D V067D26.M Mon May 15 08:13:31 2023
Qvalue
100
95
93
96
100
100
99
100
99
99
99
100
99
100
99
100
Page 3
REPORT ID: 23E081 Page 64 of 489
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI2\REC288.D Vial: 3
Aeq On 12 May 2023 7:10 am
Sample V067E14L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Operator:
Inst
Multiplr:
VLu
67
1. 00
Quant Time: May 15 8:13 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
~bundance
I 75000001
I I
I I . !
70000001
I
6500000;
if:
r I:
1\
6000000:
I
I
55000001
I
,
5000000j
4500000: '
i
40000001
I
J ,
i
35000001
I
II
ji
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC288.0
REC288.D V067D26.M Mon May 15 08:13:34 2023 Page 4
REPORT ID: 23E081 Page 65 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC289.D
Acq On 12 May 2023 7:36 am
Sample V067E14C
Vial: 4
Operator: VLu
Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:13 2023
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Quant Results File: V067D26.RES
(RTE Integrator)
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.15 114
15.60 117
19.49 152
8.21
9.30
12.97
17.60
1. 88
2.16
2.26
2.68
2.72
2.78
2.98
3.53
3.59
3.61
3.78
3.92
4.25
4.31
4.53
4.54
4.77
4.82
5.05
5.71
5.90
5.96
6.64
6.94
7.23
7.33
7.71
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
2068294
1493633
455653
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
534456 10.84
Recovery
394694 10.49
Recovery =
2281200 10.98
Recovery :;:
643250 10.45
Recovery
693543
1053330
1026481
672638
696040
1281416
804897
186552
494915
452809
1178693
523279
971127
265232
2703586
922130
544092
1041061
808926
2430858
1336337
781202
1615142
141814
941145
789588
1099763
10.99
9.61
10.57
11. 23
10.94
10.65
11.33
38.51
10.69
54.59
10.38
229.63
9.77
9.84
11.42
9.60
50.00
10.54
10.34
10.64
10.54
10.78
10.31
51.40
11.38
10.63
10.74
ug/l
108.40%
0.01
ug/l 0.01
104.40%
uglY 0.00
109.80%
ug/V
104.50%
0.00
/
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
97
99
100
97
100
99
99
99
99
98
100
99
99
100
99
98
99
100
100
99
99
100
87
99
99
99
(#) = qualifier out of range (m) = manual integration
REC289.D V067D26.M Mon May 15 08:13:49 2023 Page 1
REPORT ID: 23E081 Page 66 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC289.D
Acq On 12 May 2023 7:36 am
Sample V067E14C
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:13 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) l,l,l-Trichloroethane
r 40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
-47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.16
8.59
8.59
8.94
9.11
9.26
9.48
9.49
10.74
10.82
11.09
11.52
11.63
11.61
12.21
12.26
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.26
14.61
14.94
15.28
15.67
15.76
15.78
15.91
16.62
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
316243
79261
1157870
920183
349110
736095
252062
2896502
492856
683035
1285126
654220
709806
48557
253979
19765
1470776
922902
2855672
634043
388295
348279
943981
669593
570425
368229
299965
1210630
1594428
500624
3219980
4723175
2269766
1516674
2966370
160621
344094
89571
81924
3694499
501546
(#) = qualifier out of range (m) = manual integration
REC289.D V067D26.M Mon May 15 08:13:50 2023
10.49 ug/l
8.86 ug/l
10.02 ug/l
10.75 ug/l
9.86 ug/l
10.65 ug/l
10.33 ug/l
10.49 ug/l
10.16 ug/l
10.01 ug/l
9.98 ug/l
10.51 ug/l
10.53 ug/l
200.82 ug/l
10.16 ug/l
1.77 ug/l
48.35 ug/l
10.51 ug/l
10.75 ug/l
10.59 ug/l
8.96 ug/l
11.04 ug/l
50.75 ug/l
10.77 ug/l
10.82 ug/l
10.52 ug/l
10.69 ug/l
10.66 ug/l
10.53 ug/l
11. 26 ug/l
10.78 ug/l
21.85 ug/l
11.14 ug/l
9.71 ug/l
11.14 ug/l
9.94 ug/l
11.01 ug/l
~.65 ug/l
, 9.37 ug/l
11.15 ug/l
10.75 ug/l
Qvalue
99
97
97
98
100
99
96
100
99
99
99
98
99
98
97
83
98
99
99
94
98
98
100
99
99
100
98
99
98
99
100
100
100
99
99
98
100
100
98
100
99
Page 2
REPORT ID: 23E081 Page 67 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC289.D
Aeq On 12 May 2023 7:36 am
Sample V067E14C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:13 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
82) 1, 3, 5-Trimethylbenzene 18.03 105 2271464 10.99 ug/l 99
83) 2-Chlorotoluene 18.06 91 2260237 10.58 ug/l 95
84) 4-Chlorotoluene 18.11 91 1777149 10.13 ug/l 93
85 ) tert-Butylbenzene 18.48 134 512281 11.25 ug/l 95
86 ) 1,2,4-Trimethylbenzene 18.52 105 2074026 10.82 ug/l 99
87) see-Butylbenzene 18.74 105 3118462 11.39 ug/l 100
88) p-Isopropyltoluene 18.89 119 2345509 10.91 ug/l 99
89 ) 1,3-Diehlorobenzene 19.01 146 972109 10.41 ug/l 99
90) 1,4-Diehlorobenzene 19.12 146 946007 10.41 ug/l 99
91) n-Butylbenzene 19.34 91 2160248 10.55 ug/l 100
92) 1,2-Diehlorobenzene 19.52 146 763009 10.38 ug/l 100
93) 1,2-Dibromo-3-ehloropropan 20.31 157 31900 9.93 ug/l 100
94) 1,2,4-Triehlorobenzene 21.15 180 327416 10.57 ug/l 99
95) Hexaehlorobutadiene 21.29 225 274335 10.51 ug/l 100
96) Naphthalene 21.45 128 371362 9.36 ug/l 99
97) 1, 2, 3-Trichlorobenzene 21.69 180 221408 10.47 ug/l 98
(#) = qualifier out of range (m) = manual integration
REC289.D V067D26.M Mon May 15 08:13:50 2023 Page 3
REPORT ID: 23E081 Page 68 of 489
Quantitation Report
Data File
Aeq On
Sample
D:\HPCHEM\I\DATA\23EI2\REC289.D
12 May 2023 7:36 am
V067E14C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
Quant Time: May 15 8:13 2023 Quant Results File:
Method
Title
Last Update
Response via
Abundance.
7000000j
!
6500000,
i
6000000j\
II
i l
55000001!
I':
5000000i
i
4500000:
40000001
j
ji
35000001 !
i 30000001 i
i i
) !
5000001
I
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
----rrC:REC289.D
REC289.D V067D26.M Mon May 15 08:13:53 2023
4
VLu
67
1. 00
V067D26.RES
Cll c:
~ e
"-e o
:E o
ci>
6
E e
£! a
~
Page 4
REPORT ID: 23E081 Page 69 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC305.D Vial: 20
Operator: VLu Acq On 12 May 2023 2:26 pm
Sample 23E081-06M
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:21 2023
Inst 67
Mul tiplr: 1. 00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
(RTE Integrator)
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
!.Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.15
15.60
19.49
8.21
9.30
12.97
17.60
1. 88
2.16
2.28
2.68
2.72
2.78
2.99
3.53
3.59
3.61
3.78
3.92
4.25
4.31
4.53
4.54
4.77
4.82
5.05
5.71
5.90
5.96
6.65
6.92
7.23
7.33
7.71
114 2085257
117 1568156
152 509933
111 543063
Recovery
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.93
0.01
0.00
0.00
0.01
65 417837 11.01
ug/l
109.30%
ug/lr
110.10%
ug/l r
104.60%
ugly
0.01
Recovery
98 2281566 10.46 0.00
Recovery
95 683617 9.93 0.00
Recovery 99.30%
85 551897
50 984338
62 1062164
94 599721
64 746285
67 1398371
101 847999
56 113367
151 449052
43 397473
61 1034175
59 601052
142 968064
43 247688
76 2785363
49 890933
53 532383
73 1036776
96 718853
45 2454825
63 1261942
43 546937
59 1599043
72 136017
77 730898
96 734298
83 1058473
./
Qvalue
8.67 ug/l 99
8.91 ug/l 96
10.85 ug/l 100
9.93 ug/l 99
11.63 ug/l 98
11.53 ug/l 100
11.84 ug/l 99
23.21 ug/l 98
9.62 ug/l 100
47.53 ug/l 99
9.03 ug/l 99
261.61 ug/l 100
9.66 ug/l 99
9.11 ug/l 99
11.67 ug/l 100
9.20 ug/l 100
48.53 ug/l 99
10.41 ug/l 99
9.11 ug/l 100
10.65 ug/l 99
9.87 ug/l 99
7.49 ug/l 100
10.12 ug/l 100
48.90 ug/l 92
8.76 ug/l 100
9.81 ug/l 100
10.25 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC305.D V067D26.M Mon May 15 08:21:57 2023 Page 1
REPORT ID: 23E081 Page 70 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC305.D
Acq On 12 May 2023 2:26 pm
Sample 23E081-06M
r!Jisc 25mL
(QT Reviewed)
Vial: 20
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:21 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
j 37) Cyclohexane
-38) l,l,l-Trichloroethane
c 40) l,l-Dichloropropene
~ 41) Carbon tetrachloride
., 42) tert -Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
82) l,3,5-Trimethylbenzene
8.08
8.15
8.57
8.59
8.94
9.11
9.26
9.48
9.49
10.74
10.82
11.09
11.53
11.61
11.61
12.24
12.58
13.12
13.50
13.53
13.75
13.80
14.20
14.24
14.61
14.94
15.28
15.66
15.75
15.76
15.89
16.62
16.70
17.24
17.24
17.50
17.72
17.82
17.82
17.87
18.03
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
105
305296
90377
1275264
848892
334965
677318
260845
2800834
520238
678939
1458757
640994
692382
48550
251949
1544195
902471
2658370
624813
374613
340517
975028
661982
521579
364880
295586
1090390
1556423
464604
2986926
4374281
2152334
606755
2586066
170014
342366
89686
95144
3343160
497354
1994233
(#) = qualifier out of range (m) = manual integration
REC305.D V067D26.M Mon May 15 08:21:58 2023
10.05 ug/l
10.02 ug/l
10.95 ug/l
9.84 ug/l
9.38 ug/l
9.72 ug/l
10.61 ug/l
10.06 ug/l
10.64 ug/l
9.87 ug/l
11.24 ug/l
10.21 ug/l
10.19 ug/l
199.16 ug/l
10.00 ug/l
50.36 ug/l
10.20 ug/l
9.53 ug/l
9.94 ug/l
8.23 ug/l
10.28 ug/l
49.93 ug/l
10.14 ug/l
9.43 ug/l
9.93 ug/l
10.03 ug/l
9.14 ug/l
9.79 ug/l
9.96 ug/l
9.52 ug/l
19.28 ug/l
10.06 ug/l
~. 70 ug/l
. 9.25 ug/l
9.40 ug/l
9.79 ug/l
9.53 ug/l
9.73 ug/l
9.02 ug/l
9.52 ug/l
8.62 ug/l
Qvalue
100
98
97
98
100
99
99
100
100
100
99
98
99
95
98
97
100
100
92
98
97
98
98
99
100
98
100
99
100
100
100
100
85
99
99
100
97
100
100
100
100
Page 2
REPORT ID: 23E081 Page 71 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC305.D
Acq On 12 May 2023 2:26 pm
Sample 23E081-06M
Mise 25mL
(QT Reviewed)
Vial: 20
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:21 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
83) 2-Chlorotoluene 18.04 91 '2143122 8.97 ug/l
84) 4-Chlorotoluene 18.12 91 1674157 8.53 ug/l
85) tert-Butylbenzene 18.48 134 473415 9.29 ug/l
86) l,2,4-Trimethylbenzene 18.52 105 1460145 6.81 ug/l
87) see-Butylbenzene 18.73 105 2836319 9.26 ug/l
88) p-Isopropyltoluene 18.89 119 2122821 8.82 ug/l
89) l,3-Diehlorobenzene 19.01 146 973925 9.32 ug/l
90) l,4-Diehlorobenzene 19.12 146 926149 9.11 ug/l
91 ) n-Butylbenzene 19.34 91 1971012 8.60 ug/l
,
" 92) l,2-Diehlorobenzene 19.52 146 778247 9.46 ug/l
-93) l,2-Dibromo-3-ehloropropan 20.31 157 32381 9.01 ug/l
I 94) l,2,4-Triehlorobenzene 21.15 180 336910 9.72 ug/l
1-, 95 ) Hexaehlorobutadiene 21.29 225 263334 9.02 ug/l
~-96) Naphthalene ug/l L 21.43 128 370387 8.34
97) l,2,3-Triehlorobenzene 21.69 180 225060 9.51 ug/l
(#) = qualifier out of range (m) = manual integration
REC305.D V067D26.M Mon May 15 08:21:58 2023
Qvalue
95
93
87
96
99
99
100
99
100
99
97
100
98
100
99
Page 3
REPORT ID: 23E081 Page 72 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC30S.D
Aeq On 12 May 2023 2:26 pm
Sample 23E081-06M
Mise 2SmL
Vial:
Operator:
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: May IS 8:21 2023 Quant Results File:
Method
Title
Last Update
Response via
~bundance---------
80000001
75000001
I
70000000,
II
Ii
I' , I'~ ! 6500000 ,-,t-
Iii
;~
,E
6000000ie Ig
I !E II~ 55000001~
i'f
j:
i I
50000001 I
! :
11
4500000:
i:
4000000j
!
3500000 [
i
3000000j
25000001
20000001
1500000 1
1000000j
500000;
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC31l5.D
REC30S.D V067D26.M Mon May IS 08:22:01 2023
20
VLu
67
l. 00
V067D26.RES
~
I-'"
oi c:
'" a. e a. e o
~
6
E e
.0
is
N_
Page 4
REPORT ID: 23E081 Page 73 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC306.D Vial: 21
Operator: VLu Acq On 12 May 2023 2:52 pm
Sample 23E081-06S
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:22 2023
Inst 67
Mul tiplr: 1. 00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Last Update
Response via
DataAcq Meth V067D26 ~
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
-36) DibromofluoromethClnc
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.15
15.60
19.49
8.21
9.30
12.97
17.60
1. 87
2.18
2.28
2.68
2.72
2.80
2.98
3.53
3.59
3.61
3.78
3.92
4.25
4.31
4.53
4.54
4.78
4.82
5.05
5.71
5.90
5.96
6.65
6.92
7.23
7.33
7.70
114 2048523
117 1547600
152 504431
111 541320
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
11.09 ug/l 0.01
Recovery 110.90%
65 413278 11.09 ug/l 0.01
Recovery
98 2237755 10.40
110.~
ug/l ........----0.00
104.00%
ug/l/ 0.00
Recovery
95 674382 9.90
Recovery
85 566037
50 976063
62 1066567
94 612222
64 761335
67 1312348
101 857026
56 114974
99P'{)%
Qvalue
9.05 ug/l 99
8.99 ug/l 94
11.09 ug/l 100
10.32 ug/l 99
12.08 ug/l 99
11.01 ug/l 100
12.18 ug/l 99
23.96 ug/l 99
9.08 ug/l 99
50.16 ug/l 99
8.68 ug/l 99
151 416342
43 412096
61 976663
59 579208 256.63 ug/l 99
142 925621
43 245527
76 2740153
49 880190
53 533074
73 1055823
96 679532
45 2433604
63 1205420
43 552806
59 1601447
72 142215
77 686395
96 705433
83 1017926
9.41 ug/l 99
9.19 ug/l 98
11.69 ug/l 99
9.25 ug/l 100
49.46 ug/l 98
10.79 ug/l 99
8.77 ug/l 100
10.75 ug/l 99
9.60 ug/l 99
7.70 ug/l 100
10.32 ug/l 99
52.04 ug/l 92
8.38 ug/l 99
9.59 ug/l 99
10.04 ug/l 100
(#) = qualifier out of range (m) = manual integration
REC306.D V067D26.M Mon May 15 08:22:25 2023 Page 1
REPORT ID: 23E081 Page 74 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC306.D
Acq On 12 May 2023 2:52 pm
Sample 23E081-06S
Misc 25mL
(QT Reviewed)
Vial: 21
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:22 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
.~·~esponse via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) 1,1,1-Trichloroethane
40) 1,1-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) 1,2-Dichloroethane
( 46) Trichloroethene
47) Methylcyclohexane
I 48) 1,2-Dichloropropane
;~ 49) Bromodichloromethane
r 50) 1,4-Dioxane
51) Dibromomethane
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) 1,1,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
82) 1,3,5-Trimethylbenzene
8.08
8.15
8.57
8.59
8.94
9.11
9.26
9.48
9.49
10.74
10.82
11.09
11.53
11.61
11.61
12.24
12.58
13.12
13.50
13.53
13.75
13.80
14.20
14.26
14.61
14.94
15.28
15.66
15.76
15.76
15.89
16.62
16.70
17.24
17.24
17.52
17.72
17.82
17.82
17.87
18.03
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
105
302625
85412
1255384
787405
307188
615720
260164
2653681
511135
639179
1464347
635322
672459
49692
249626
1573185
887334
2530723
620090
378670
341655
1001537
656000
482543
362153
291649
1005254
1503834
452979
2818243
4171717
2069372
623536
2448579
172625
346442
91179
95719
3141964
486830
1905658
(#) = qualifier out of range (m) = manual integration
REC306.D V067D26.M Mon May 15 08:22:26 2023
10.14 ug/l
9.64 ug/l
10.97 ug/l
9.29 ug/l
8.76 ug/l
8.99 ug/l
10.77 ug/l
9.70 ug/l
10.64 ug/l
9.46 ug/l
11.49 ug/l
10.30 ug/l
10.07 ug/l
207.50 ug/l
10.08 ug/l
52.22 ug/l
10.21 ug/l
9.20 ug/l
9.99 ug/l
8.43 ug/l
10.45 ug/l
51.97 ug/l
10.18 ug/l
8.84 ug/l
9.98 ug/l
10.03 ug/l
8.54 ug/l
9.58 ug/l
9.84 ug/l
9.11 ug/l
18.63 ug/l
9.80 ug/l
~85 ug/l
B.87 ug/l
9.65 ug/l
10.01 ug/l
9.80 ug/l
9.89 ug/l
8.57 ug/l
9.42 ug/l
8.33 ug/l
Qvalue
99
96
98
98
100
100
99
99
99
100
99
99
99
99
99
98
100
99
95
98
97
98
99
99
99
99
100
99
100
99
100
99
85
100
100
99
98
99
100
99
99
Page 2
REPORT ID: 23E081 Page 75 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC306.D
Aeq On 12 May 2023 2:52 pm
Sample 23E081-06S
Mise 25mL
(QT Reviewed)
Vial: 21
Operator: VLu
Inst 67
Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 15 8:22 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
83) 2-Chlorotoluene 18.04 91 2042170 8.64 ug/l
84) 4-Chlorotoluene 18.12 91 1613881 8.31 ug/l
c' 85 ) tert-Butylbenzene 18.48 134 446337 8.85 ug/l i.-
£'.\ 86 ) 1, 2, 4-Trimethylbenzene 18.52 105 1418321 6.69 ug/l
h_ 87) see-Butylbenzene 18.73 105 2648761 8.74 ug/l
88) p-Isopropyltoluene 18.89 119 2017336 8.48 ug/l
t, 89 ) 1,3-Diehlorobenzene 19.01 146 946704 9.16 ug/l
90) 1,4-Diehlorobenzene 19.12 146 906721 9.02 ug/l
91) n-Butylbenzene 19.34 91 1874530 8.27 ug/l
92) 1,2-Diehlorobenzene 19.52 146 764567 9.39 ug/l
93) 1,2-Dibromo-3-ehloropropan 20.31 157 33419 9.40 ug/l
94) 1, 2, 4-Triehlorobenzene 21.15 180 345050 10.06 ug/l
95) Hexaehlorobutadiene 21. 29 225 248256 8.59 ug/l
96) Naphthalene 21. 43 128 402667 9.17 ug/l
97) 1,2,3-Triehlorobenzene 21.70 180 241083 10.30 ug/l
(#) = qualifier out of range (m) = manual integration
REC306.D V067D26.M Mon May 15 08:22:26 2023
Qvalue
95
93
89
97
99
100
98
99
99
100
98
99
98
98
99
Page 3
REPORT ID: 23E081 Page 76 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC306.D
Aeq On 12 May 2023 2:52 pm
Sample 23E081-06S
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
21
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: May 15 8:22 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
AlJundance--
80000001
I
75000001
r
r~
Ir-: 7000000L~
f-
11
6500000i~
i§
1~ 60000001~ Ii
5500000]
I I
5000000j!
4500000 1 i
4000000: '
i
3500000i
: !
30000001
!
2500000<
2000000;
1500000!
!
1000000i
500000;
Time-->
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC30o.o-
REC306.D V067D26.M Mon May 15 08:22:29 2023
~
~
oj
C
ell
C.
~ e o
{j
1
E e
.0
is
N.
Page 4
REPORT ID: 23E081 Page 77 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC307.D
Acq On 12 May 2023 3:18 pm
Sample 23E081-07M
Misc 25mL
(QT Reviewed)
Vial: 22
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023 ~
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
iTarget Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene J
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.15
15.60
19.49
8.21
9.31
12.97
17.60
1. 88
2.16
2.28
2.68
2.72
2.78
2.98
3.53
3.59
3.61
3.78
3.92
4.25
4.31
4.53
4.54
4.78
4.82
5.05
5.71
5.90
5.96
6.65
6.92
7.23
7.33
7.71
114 1985715
117 1506756
152 484613
111 526164
Recovery
10.00 ug/l
10.00 ug/l
10.00 ug/l
11.12 ug/l
111.20%
65 400824 11.09 ug/l
110~
ug/l~
104.80%
Recovery
98 2195179 10.48
Recovery
95 656544 10.03
Recovery
ugly
10 7 0%
0.02
0.00
0.00
0.02
0.02
0.00
0.00
Qvalue
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
569996
981141
1082082
619818
783055
1401934
847981
109430
452036
412609
1031676
603441
974718
240932
2703399
893817
525645
1046330
730374
2457527
1275533
330997
1586727
137870
722372
728550
1052143
9.40 ug/l
9.32 ug/l
11.61 ug/l
10.78 ug/l
12.82 ug/l
12.13 ug/l
12.44 ug/l
23.53 ug/l
10.17 ug/l
51.81 ug/l
9.46 ug/l
275.82 ug/l
10.22 ug/l
9.31 ug/l
11.90 ug/l
9.69 ug/l
50.31 ug/l
11.03 ug/l
9.72 ug/l
11.20 ug/l
10.48 ug/l
4.76 ug/l
10.55 ug/l
52.05 ug/l
9.10 ug/l
10.22 ug/l
10.70 ug/l
100
94
100
99
98
100
98
99
100
100
99
100
99
100
100
100
100
100
100
99
100
99
99
90
99
99
99
(#) = qualifier out of range (m) = manual integration
REC307.D V067D26.M Mon May 15 08:25:28 2023 Page 1
REPORT ID: 23E081 Page 78 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC307.D
Acq On 12 May 2023 3:18 pm
Sample 23E081-07M
Mise 25mL
(QT Reviewed)
Vial: 22
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. Qlon Response Conc Unit Qvalue
33)
34)
37)
i: 38)
". 40)
41 )
, 42)
44)
45)
46)
47)
48 )
49)
50 )
51 )
52)
53)
54)
57 )
58 )
59)
60 )
61)
62)
63)
64)
65 )
66 )
67 )
68 )
69 )
70 )
71 )
72)
73)
75)
76 )
78 )
79)
80)
81 )
Bromochloromethane
Tetrahydrofuran
Cyclohexane
l,l,l-Trichloroethane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-l,3-Dichloropropene
Toluene
trans-l,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
l-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
1,2,3-Trichloropropane
trans-l,4-Diehloro-2-buten
n-Propylbenzene
Bromobenzene
8.08
8.15
8.59
8.60
8.94
9.12
9.26
9.48
9.50
10.74
10.82
11.09
11.53
11.61
11.61
12.24
12.24
12.58
13.12
13.50
13.53
13.75
13.81
14.20
14.26
14.61
14.95
15.28
15.66
15.76
15.78
15.89
16.63
16.70
17.24
17.24
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
304804
84018
1273791
847562
330947
674087
261123
2776518
510188
676517
1462687
643619
685075
47985
246224
10.53
9.78
11.48
10.32
9.74
10.15
11.15
10.48
10.95
10.32
11.84
10.77
10.59
206.71
10.26
1127 0.10
1549698 53.07
896633 10.64
2647669 9.88
619366 10.25
372726 8.52
334213 10.50
981681 52.32
652399 10.40
519402 9.77
361064 10.22
291992 10.32
1090497 9.52
1557902 10.19
460169 10.26
2966328 9.84
4307999 19.76
2132977 10.38
474509 ..-----3.01
2582882 9.61
168508 9.80
339713 10.22
90005 10.07
94196 10.13
3329652 9.45
492360 9.92
(#) = qualifier out of range (m) = manual integration
REC307.D V067D26.M Mon May 15 08:25:28 2023
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l #
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
99
98
98
98
99
99
98
100
99
99
99
100
98
97
99
1
97
99
99
95
98
98
99
98
99
99
99
100
99
100
99
100
100
85
100
99
100
98
98
100
100
Page,2
REPORT ID: 23E081 Page 79 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC307.D
Aeq On 12 May 2023 3:18 pm
Sample 23E081-07M
Mise 25mL
(QT Reviewed)
Vial: 22
Operator: VLu
Inst 67
Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1, 3, 5-Trimethylbenzene 18.03 105 1996733 9.09 ug/l
83) 2-Chlorotoluene 18.04 91 2112376 9.30 ug/l
84) 4-Chlorotoluene 18.12 91 1687910 9.05 ug/l
85 ) tert-Butylbenzene 18.48 134 469193 9.69 ug/l
86 ) l,2,4-Trimethylbenzene 18.52 105 1477111 7.25 ug/l
87) see-Butylbenzene 18.73 105 2811457 9.66 ug/l
88) p-Isopropyltoluene 18.89 119 2147016 9.39 ug/l
89) l,3-Diehlorobenzene 19.01 146 944419 9.51 ug/l
90) l,4-Diehlorobenzene 19.12 146 916657 9.49 ug/l
91 ) n-Butylbenzene 19.34 91 2001182 9.19 ug/l
92) l,2-Diehlorobenzene 19.52 146 771460 9.87 ug/l
~-93) l,2-Dibromo-3-ehloropropan 20.31 157 33813 9.90 ug/l
" 94) 1, 2, 4-Triehlorobenzene 21.15 180 339217 10.29 ug/l
~~ 95) Hexaehlorobutadiene 21. 29 225 259535 9.35 ug/l
96) Naphthalene 21.43 128 388153 9.20 ug/l
97) 1, 2, 3-Triehlorobenzene 21.70 180 231500 10.29 ug/l
(#) = qualifier out of range (m) = manual integration
REC307.D V067D26.M Mon May 15 08:25:29 2023
Qvalue
100
95
94
88
95
99
99
100
100
99
99
100
99
98
100
99
Page 3
REPORT ID: 23E081 Page 80 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC307.D
Aeq On 12 May 2023 3:18 pm
Sample 23E081-07M
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023 Quant Results File:
Method
Title
Last Update
Response via
Abundance
i 1
! 80000001
7500000!
!
7000000j"!
6500000] :
1
II
i~.
, 6000000 i 't
'C 1£ I~ 10
55000001J
1'5 !~ , .c
'" 5000000Ji:15
I
45000001
I
4000000; .
i
3500000; ,
3000000)
!
25000001 i
2000000]
1500000;
I
1000000:
500000:
Time-->
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC307JJ
(RTE Integrator)
REC307.D V067D26.M Mon May 15 08:25:31 2023
22
VLu
67
1. 00
V067D26.RES
:;; ,.:
'" c ro
Cl.
Ie
Cl.
Ie o
~
,},
6
E
Ie
.0
9
"!
Page 4
REPORT ID: 23E081 Page 81 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC308.D Vial: 23
Operator: VLu Acq On 12 May 2023 3:44 pm
Sample 23E081-07S
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023
Inst 67
Mul tiplr: 1. 00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
~ 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-l,2-Dichloroethene
32) Chloroform
10.15
15.60
19.49
8.21
9.30
12.97
17.60
1. 88
2.16
2.28
2.68
2.72
2.78
2.99
3.53
3.59
3.61
3.78
3.92
4.25
4.31
4.53
4.54
4.77
4.82
5.05
5.71
5.90
5.96
6.64
6.94
7.23
7.33
7.71
114 2122993
117 1579908
152 501699
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
553812 10.95
Recovery
419634 10.86
Recovery
2309386 10.51
Recovery
683851 10.09
Recovery
537943
1015520
1082729
615889
764135
1350588
876551
114398
431758
411903
979768
583663
944329
244296
2790230
866902
535342
1059405
697875
2438050
1227587
300647
1588955
141415
693712
711356
1025121
8.30
9.03
10.86
10.02
11.70
10.93
12.03
23.01
9.09
48.38
8.41
249.53
9.26
8.83
11.49
8.79
47.93
10.45
8.69
10.39
9.43
4.04
9.88
49.93
8.17
9.33
9.75
ug/l 0.01
109.~
ug/l 0.01
108.60%
ug /1 ,..A o. 00
10;}.10%
ug7l 0.00
100.90%
/ Qvalue
ug/l 100
ug/l 95
ug/l 99
ug/l 100
ug/l 99
ug/l 100
ug/l 99
ug/l 86
ug/l 100
ug/l 99
ug/l 98
ug/l 100
ug/l 98
ug/l 100
ug/l 100
ug/l 99
ug/l 98
ug/l 100
ug/l 99
ug/l 100
ug/l 99
ug/l 99
ug/l 100
ug/l 89
ug/l 99
ug/l 99
ug/l 100
(#) = qualifier out of range (m) = manual integration
REC308.D V067D26.M Mon May 15 08:25:56 2023 Page 1
REPORT ID: 23E081 Page 82 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC308.D
Acq On 1/' M~y 2023 3:44 pm
Sample 23E081-07S
Misc 25mL
(QT Reviewed)
Vial: 23
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit Qvalue
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) l,l,l-Trichloroethane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
L 50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.15
8.59
8.60
8.94
9.11
9.26
9.48
9.49
10.74
10.82
11.09
11.52
11.61
11.61
12.24
12.24
12.58
13.12
13.50
13.53
13.75
13.80
14.20
14.26
14.61
14.94
15.28
15.67
15.76
15.78
15.91
16.62
16.70
17.24
17.24
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
303628
91155
1281165
819880
316664
648938
260458
2677527
505692
652469
1480959
633825
685978
49832
250742
1158
1562157
875763
2548758
615539
368333
336519
998576
652429
488380
359726
291887
1035022
1503127
453154
2849121
4178122
2067263
423867
2509080
171657
344316
89902
95713
3177307
483300
(#) = qualifier out of range (m) = manual integration
REC308.D V067D26.M Mon May 15 08:25:57 2023
9.81 ug/l
9.92 ug/l
10.80 ug/l
9.33 ug/l
8.71 ug/l
9.14 ug/l
10.40 ug/l
9.45 ug/l
10.16 ug/l
9.31 ug/l
11.21 ug/l
9.92 ug/l
9.91 ug/l
200.78 ug/l
9.77 ug/l
0.10 ug/l #
50.04 ug/l
9.72 ug/l
9.07 ug/l
9.72 ug/l
8.03 ug/l
10.08 ug/l
50.76 ug/l
9.92 ug/l
8.76 ug/l
9.71 ug/l
9.83 ug/l
8.61 ug/l
9.38 ug/l
9.64 ug/l
9.02 ug/l
18.28 ug/l
9.59 ug/l
.A .57 ug/l
8.91 ug/l
9.65 ug/l
10.01 ug/l
9.71 ug/l
9.94 ug/l
8.71 ug/l
9.41 ug/l
98
98
98
99
99
100
100
100
99
99
99
99
99
99
98
1
96
99
100
94
99
98
98
98
100
100
99
99
99
100
100
100
99
78
100
99
99
95
99
100
99
Page 2
REPORT ID: 23E081 Page 83 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC308.D
Aeq On 12 May 2023 3:44 pm
Sample 23E081-07S
Mise 25mL
(QT Reviewed)
Vial: 23
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
82) 1, 3, 5-Trimethylbenzene 18.03 105 1909524 8.39 ug/l 100
83) 2-Chlorotoluene 18.06 91 1995201 8.49 ug/l 95
84) 4-Chlorotoluene 18.11 91 1632388 8.45 ug/l 93
85 ) tert-Butylbenzene 18.48 134 445400 8.88 ug/l 88
-86) 1, 2, 4-Trimethylbenzene 18.52 105 1386453 6.57 ug/l 95
87) see-Butylbenzene 18.74 105 2693971 8.94 ug/l 99
88 ) p-Isopropyltoluene 18.89 119 2026697 8.56 ug/l 100
89) 1,3-Diehlorobenzene 19.01 146 915051 8.90 ug/l 99
90 ) 1,4-Diehlorobenzene 19.12 146 895525 8.95 ug/l 99
(' 91 ) n-Butylbenzene 19.34 91 1865710 8.28 ug/l 99
92) 1,2-Diehlorobenzene 19.52 146 756712 9.35 ug/l 99
93) 1,2-Dibromo-3-ehloropropan 20.31 157 34392 9.72 ug/l 97
i" 94) 1, 2, 4-Triehlorobenzene 21.15 180 329178 9.65 ug/l 99
95 ) Hexaehlorobutadiene 21.29 225 251252 8.74 ug/l 99
96) Naphthalene 21.45 128 393466 9.01 ug/l 99
97) 1, 2, 3-Triehlorobenzene 21.69 180 238195 10.23 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC308.D V067D26.M Mon May 15 08:25:57 2023 Page 3
REPORT ID: 23E081 Page 84 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC308.D
Aeq On 12 May 2023 3:44 pm
Sample 23E081-07S
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
23
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: May 15 8:25 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
,A.I)unaa-nce--~---------------~rc:REC31JKD
8000000:
75000001
7000000 r\
I! I!
6500000:
'::< ,>t.
'~
6000000;~
!~
~
5500000 ~
i
5000000 !
I
I
! [
I
4500000:
4000000·
i'
! !
350000011
I!
3000000! I
2500000]
2000000: ,
I
15000001
I
10000001
I
500000i
(RTE Integrator)
REC308.D V067D26.M Mon May 15 08:25:59 2023
::< ,..:
Qj
c:
'" e-o. e o
il
M
6
E e
.0
is
<';
Page 4
REPORT ID: 23E081 Page 85 of 489
INITIAL CALIBRATIONS
REPORT ID: 23E081 Page 86 of 489
Lab Name :
Lab Code :
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
EMAX Laboratories, Inc. Project ICAL
EMAX SDG No lCAL
Lab File ID: ROC587 BFB Injection Date: 04/26/23
Instrument ID: 67 BFB Injection Time: 08:20
I I I % RELATIVE
I m/ e I ION ABUNDANCE CRITERIA I ABUNDANCE I
1=====1========================================1================1
I 50 I 15 -40% of mass 95 I 20.379 I
I 75 I 30 -60% of mass 95 I 45.113 I
I 95 I Base Peak, 100% relative abundance ____ 1 100.000 I
I 96 I 5 -9% of mass 95 I 6 .378 I
I 173 I Less than 2% of mass 174 I 0.000(0)1 I
I 174 I Greater than 50% of mass 95 i 76.492 I
I 175 I 5 -9% of mass 174 I 5.532(7.23)1 I
I 176 I 95 -101% % of mass 174 I 76.007(99.37)1 I
I 177 I 5 -9% % of mass 176 I 4.717(6.21)2 I
1 __ 1 I I
I-Value is % mass 174 2-Value is % mass 176
This check applies to the following Calibration Standards:
I EPA LAB I LAB I DATE TIME
I SAMPLE NO. I SAMPLE ID I FILE ID I ANALYZED I ANALYZED I
1====================1================1============1==========1==========1
1IVSTDO.3 IV067D261 IROC588 I 04/26/23 I 08:46 I
2IVSTDO.5 IV067D262 IROC589 I 04/26/23 I 09:11 I
31VSTD1 IV067D263 IROC590 I 04/26/23 I 09:37 I
41VSTD2 IV067D264 IROC591 I 04/26/23 I 10:03 I
51VSTD5 IV067D265 IROC592 I 04/26/23 I 10:28 I
61VSTD10 IV067D266 IROC593 I 04/26/23 I 10: 54 I
71VSTD20 IV067D267 IROC594 I 04/26/23 I 11: 19 I
81VSTD30 IV067D268 IROC595 I 04/26/23 I 11:45 I
91VSTD100 IV067D2610 IROC597 I 04/26/23 I 12:36 I
1olVSTD50 IV067D2611 IROC600 104/26/23 I 13:53 I
111VSTD10 I IV067D2601 IROC603 I 04/26/23 I 15:39 I
I I I I I I
REPORT ID: 23E081 Page 87 of 489
Instrument ID :67
Rpqinninq nntpTimp '04/?h/?' OR,4h
Spike Units :PPB
IC File :RDC593
M IDX Parameters
==::;:==== =====================================
1 1,4-DIFLUOROBENZENE
2 Dichlorodifluoromethane
3 Dichlorotetrafluoroethane
4 Chloromethane
5 Vinyl chloride
6 Bromomethane
7 Chloroethane
8 Dichlorofluoromethane
9 Trichlorofluoromethane
10 sec-Propyl alcohol
5 11 Acrolein
12 1,1,2-Trichloro-1,2,2-trifluoroethane
5 13 Acetone
14 1,1-Dichloroethene
25 15 tert-Butyl alcohol
16 Iodomethane
17 Methyl acetate
10 18 Acetonitrile
19 Carbon disulfide
20 Methylene chloride
5 21 Acrylonitrile
22 tert-Butyl methyl ether (MTBE)
23 trans-1,2-Dichloroethene
24 Isopropyl ether (DIPE)
25 1,1-Dichloroethane
26 'iinyl acetate
25 27 2-Butanol
28 tert-Butyl ethyl ether (ETBE)
5 29 2-Butanone
30 2,2-Dichloropropane
31 cis-l,2-Dichloroethene
32 Chloroform
33 Bromochloromethane
34 Tetrahydrofuran
5 35 tert-Amyl alcohol
36 Dibromofluoromethane
37 Cyclohexane
38 1,1,1-Trichloroethane
39 2,2,4-Trimethylpentane
40 1,1-Dichloropropene
41 Carbon tetrachloride
42 tert-Amyl methyl ether (TAME)
43 1,2-Dichloroethane-d4
44 Benzene
45 1,2-Dichloroethane
46 Trichloroethene
47 Methylcyclohexane
48 1,2-Dichloropropane
49 Bromodichloromethane
20 50 1,4-Dioxane
51 Dibromomethane
52 2-Chloroethyl vinyl ether
5 53 4-Methyl-2-pentanone
54 cis-1,3-Dichloropropene
55 CHLOROBENZENE-D5
56 Toluene-d8
57 Toluene
58 trans-1,3-Dichloropropene
59 Ethyl methacrylate
60 1,1,2-Trichloroethane
5 61 2-Hexanone
62 1,3-Dichloropropane
63 Tetrachloroethene
64 Dibromochloromethane
65 1,2-Dibromoethane
66 1-Chlorohexane
67 Chlorobenzene
68 1,1,1,2-Tetrachloroethane
69 Ethylbenzene
2 70 m-Xylene & p-Xylene
71 o-Xylene
72 Styrene
73 Isopropylbenzene
74 1,2-DICHLOROBENZENE-D4
75 Bromoform
76 1,1,2,2-Tetrachloroethane
77 4-Bromofluorobenzene
78 1,2,3-Trichloropropane
79 trans-l,4-Dichloro-2-butene
80 n-Propylbenzene
81 Bromobenzene
82 1,3,5-Trimethylbenzene
83 2-Chlorotoluene
84 4-Chlorotoluene
85 tert-Butylbenzene
86 1,2,4-Trimethylbenzene
87 sec-Butylbenzene
88 p-Isopropyltoluene
89 1,3-Dichlorobenzene
90 1,4-Dichlorobenzene
91 n-Butylbenzene
92 1,2-Dichlorobenzene
93 1,2-Dibromo-3-chloropropane
94 1,2,4-Trichlorobenzene
95 Hexachlorobutadiene
96 Naphthalene
97 1,2,3-Trichlorobenzene
~ Sp~ke Amount -Nomlnal Amount * M
Ave_%RSD 6.8 Max_%RSD 14.7
.3 .5 1
08:46 09:11 09:37
RDC588 RDC589 RDC590
====== ====== ======
1 1 1
0.289 0.303 0.337
------------------
0.594 0.462 0.592
0.414 0.445 0.504
0.262 0.271 0.299
0.269 0.290 0.334
0.529 0.597 0.610
0.307 0.323 0.369
------------------
------0.027 0.024
0.209 0.228 0.232
------------------
0.4% 0.543 0.566
0.010 0.011 0.011
0.411 0.456 0.462
0.132 0.134 0.125
------------------
1. 034 1.022 1.131
------0.560 0.495
------0.043 0.050
0.421 0.457 0.478
0.345 0.378 0.380
0.969 1. 082 1.102
0.552 0.621 0.614
------------0.288
------------------
0.678 0.747 0.785
------------0.012
0.374 0.415 0.403
0.308 0.354 0.361
0.460 0.491 0.496
0.127 0.132 0.150
------------0.044
------------------
0.191 0.218 0.252
0.457 0.492 0.585
0.366 0.414 0.419
------1.255 1.594
0.149 0.166 0.171
0.276 0.327 0.337
0.098 0.108 0.114
0.158 0.177 0.189
1.213 1. 314 1.353
0.210 0.232 0.239
0.291 0.315 0.331
------0.533 0.622
0.249 0.290 0.301
0.282 0.312 0.330
------------0.001
------0.103 0.117
------------------
0.130 0.125 0.138
0.343 0.405 0.407
1 1 1
1.157 1.355 1.480
1.625 1.838 1. 833
0.318 0.364 0.385
------------0.247
0.179 0.197 0.214
0.113 0.104 0.115
0.363 0.407 0.407
0.317 0.351 0.352
0.200 0.219 0.222
0.151 0.176 0.185
0.649 0.721 0.728
0.899 0.997 1.030
0.258 0.294 0.287
1.768 1.953 1. 998
1.318 1.458 1.452
1.187 1.328 1. 360
0.876 0.993 1. 008
1.493 1.716 1.752
1 1 1
------0.326 0.315
0.611 0.672 0.690
1.274 1. 363 1.413
0.167 0.170 0.193
------------0.170
6.542 7.385 7.316
0.939 1.021 1.035
4.064 4.511 4.454
4.683 5.130 5.156
3.559 3.704 3.617
0.886 0.957 0.991
3.769 4.122 4.108
5.371 5.722 5.873
3.985 4.404 4.489
1. 979 2.008 2.003
1. 836 1.997 1. 941
------3.875 4.012
1. 575 1.575 1.591
------------0.056
0.575 0.585 0.580
0.484 0.469 0.504
0.924 0.731 0.723
0.458 0.409 0.397
---------
2 5 10 20
10:03 10:28 10: 54 11:19
RDC591 RDC592 RDC593 RDC594
====== ====== ====== ======
1 1 1 1
0.302 0.289 0.326 0.292
------------------------
0.536 0.515 0.567 0.492
0.487 0.475 0.531 0.458
0.287 0.286 0.324 0.293
0.314 0.301 0.341 0.306
0.618 0.574 0.580 0.598
0.363 0.337 0.381 0.344
------------------------
0.023 0.020 0.025 0.022
0.235 0.215 0.222 0.231
0.051 0.044 0.039 0.035
0.576 0.562 0.543 0.585
0.011 0.011 0.011 0.011
0.485 0.491 0.493 0.511
0.120 0.119 0.142 0.125
------------------------
1.122 1.137 1.287 1.195
0.507 0.444 0.435 0.444
0.057 0.051 0.054 0.052
0.500 0.475 0.481 0.485
0.393 0.369 0.375 0.393
1.154 1. 078 1. 098 1.151
0.645 0.598 0.604 0.632
0.334 0.344 0.385 0.340
------------------------
0.835 0.777 0.735 0.757
0.013 0.013 0.014 0.013
0.431 0.402 0.394 0.413
0.372 0.352 0.357 0.377
0.526 0.483 0.487 0.514
0.153 0.145 0.147 0.151
0.046 0.043 0.044 0.040
0.008 0.008 0.010 0.009
0.233 0.238 0.252 0.248
0.545 0.548 0.614 0.578
0.437 0.406 0.412 0.435
1.471 1.442 1.619 1.453
0.181 0.169 0.170 0.179
0.351 0.328 0.337 0.358
0.124 0.116 0.122 0.123
0.183 0.181 0.192 0.184
1.401 1. 304 1.319 1.403
0.253 0.235 0.236 0.240
0.348 0.325 0.328 0.346
0.577 0.591 0.688 0.635
0.320 0.294 0.298 0.316
0.331 0.319 0.325 0.342
0.001 0.001 0.001 0.001
0.128 0.119 0.120 0.125
0.049 0.049 0.051 0.054
0.159 0.144 0.152 0.148
0.433 0.421 0.428 0.453
1 1 1 1
1.370 1. 393 1.467 1.460
1.904 1.762 1.777 1.876
0.417 0.397 0.409 0.427
0.281 0.273 0.290 0.299
0.228 0.211 0.211 0.218
0.132 0.121 0.129 0.125
0.443 0.410 0.416 0.427
0.375 0.338 0.348 0.372
0.241 0.233 0.238 0.247
0.202 0.188 0.192 0.195
0.789 0.748 0.767 0.824
1. 067 0.992 1.003 1.065
0.308 0.289 0.295 0.316
2.098 1. 958 1. 989 2.131
1.539 1.435 1.466 1.564
1.438 1. 347 1.375 1.478
1. 070 1.016 1.054 1.141
1. 891 1. 774 1. 799 1.939
1 1 1 1
0.361 0.334 0.351 0.364
0.738 0.674 0.687 0.687
1.303 1.319 1.377 1.358
0.196 0.186 0.189 0.186
0.188 0.185 0.192 0.198
7.668 7.244 7.217 7.832
1.063 1. 000 0.988 1.057
4.741 4.464 4.463 4.855
4.784 4.428 4.427 4.755
4.300 3.895 3.908 4.214
1. 040 0.966 0.963 1.078
4.428 4.125 4.155 4.517
6.375 6.009 6.038 6.594
4.936 4.697 4.780 5.279
2.121 1.980 2.010 2.158
2.064 1.924 1.944 2.099
4.503 4.421 4.552 5.041
1.686 1.555 1. 586 1.688
0.070 0.071 0.071 0.072
0.652 0.663 0.691 0.781
0.626 0.583 0.580 0.676
0.786 0.809 0.875 0.934
0.449 0.439 0.464 0.512
------------
30
11:45
RDC595
======
1
0.301
------
0.483
0.442
0.295
0.310
0.597
0.343
------
0.024
0.229
0.038
0.561
0.012
0.515
0.135
------
1.192
0.444
0.057
0.505
0.392
1.156
0.638
0.363
------
0.771
0.014
0.409
0.378
0.510
0.154
0.044
0.010
0.252
0.585
0.430
1.474
0.179
0.355
0.128
0.190
1.400
0.245
0.346
0.651
0.318
0.350
0.001
0.129
0.059
0.163
0.464
1
1.445
1. 849
0.441
0.316
0.224
0.138
0.444
0.365
0.253
0.202
0.810
1. 062
0.314
2.105
1. 508
1. 452
1.139
1.898
1
0.376
0.715
1. 341
0.191
0.205
7.438
1. 051
4.638
4.575
4.141
1. 038
4.346
6.237
5.034
2.125
2.081
4.818
1.663
0.078
0.773
0.633
1. 001
0.523
Column Spec :RTX502.2 ID :0.25MM
Ending DateTime :04/26/23 13:53
H~~hem Method :voG?D2G
50 100
13:53 12:36
RDC600 RDC597 AV_RRF %_RSD Av_Rt_M
====== ===:::::== ====== ====== =======
1 1 1 0 10.1420
0.291 0.322 0.305 5.66 1.8533
------------0.000 0.00 0.0000
------------0.530 9.57 2.1166
------ ------0.470 8.00 2.2371
0.286 0.293 0.290 5.68 2.6806
0.303 0.309 0.308 6.63 2.6967
0.566 0.549 0.582 4.77 2.7910
0.325 0.342 0.343 6.58 2.9577
------------0.000 0.00 0.0000
0.022 0.024 0.023 8.06 3.5109
0.219 0.217 0.224 3.75 3.5771
0.035 0.038 0.040 14.65 3.5907
0.530 0.529 0.549 4.80 3.7632
0.011 0.013 0.011 6.45 3.9126
0.489 0.491 0.480 6.34 4.2302
0.121 0.151 0.130 8.01 4.2814
------------0.000 0.00 0.0000
1.096 1.227 1.144 7.27 4.4991
0.423 0.430 0.465 9.90 4.5253
0.052 0.059 0.053 8.95 4.7543
0.471 0.504 0.478 5.25 4.7986
0.379 0.381 0.378 3.80 5.0251
1.137 1.123 1.105 5.08 5.6929
0.617 0.610 0.613 4.26 5.8769
0.346 0.403 0.350 9.85 5.9369
------------0.000 0.00 0.0000
0.741 0.749 0.757 5.33 6.6309
0.013 0.015 0.013 6.91 6.9104
0.392 0.367 0.400 4.81 7.1993
0.364 0.368 0.359 5.58 7.3059
0.496 0.489 0.495 3.69 7.6858
0.145 0.152 0.146 6.20 8.0526
0.040 0.045 0.043 4.96 8.1378
0.009 ------0.009 9.29 8.1653
0.242 0.256 0.238 8.45 8.1943
0.558 0.623 0.559 9.25 8.5654
0.414 0.404 0.414 4.92 8.5786
1.384 1.572 1.474 7.68 8.7399
0.174 0.174 0.171 5.48 8.9249
0.338 0.336 0.334 6.91 9.1017
0.120 0.126 0.118 7.89 9.2478
0.176 0.190 0.182 5.46 9.2902
1.347 1.294 1.335 4.46 9.4684
0.225 0.230 0.235 5.01 9.4874
0.335 0.335 0.330 5.21 10.7235
0.619 0.685 0.622 8.11 10.8098
0.310 0.313 0.301 7.04 11.0845
0.333 0.336 0.326 5.74 11.5199
0.001 0.001 0.001 6.36 11.6116
0.119 0.127 0.121 6.59 11.6005
0.055 0.062 0.054 9.00 12.1959
0.147 0.164 0.147 9.02 12.2461
0.440 0.449 0.424 8.11 12.5689
1 1 1 0 15.6023
1.393 1. 384 1.390 6.69 12.9723
1. 769 1.550 1. 778 6.30 13 .1081
0.415 0.436 0.401 9.38 13.4866
0.291 0.323 0.290 8.35 13.5203
0.208 0.223 0.211 6.90 13.7467
0.126 0.142 0.125 9.36 13.8095
0.408 0.438 0.416 5.77 14.1879
0.355 0.355 0.353 4.74 14.2434
0.239 0.252 0.234 7.11 14.6014
0.186 0.202 0.188 8.26 14.9462
0.790 0.779 0.761 6.75 15.2721
1.028 0.998 1.014 4.93 15.6622
0.307 0.307 0.298 5.81 15.7499
2.000 ------2.000 5.46 15.7630
1.284 ------1.447 6.45 15.8946
1.395 1.281 1.364 6.33 16.6251
1. 099 1. 061 1.046 7.51 16.6952
1. 789 ------1. 783 7.40 17.2275
1 1 1 0 19.4889
0.363 0.404 0.355 7.64 17.2389
0.668 0.717 0.686 5.07 17.5062
1.340 1.419 1.351 3.39 17.6041
0.175 0.194 0.184 5.75 17.7166
0.192 0.205 0.192 5.86 17.8215
6.774 ------7.269 5.54 17.8135
1. 033 1.054 1.024 3.78 17.8671
4.620 ------4.534 4.94 18.0278
4.864 4.061 4.686 7.12 18.0453
3.790 3.358 3.849 7.90 18.1140
1. 052 1. 026 1.000 5.78 18.4807
4.283 ------4.206 5.24 18.5246
5.853 ------6.008 6.06 18.7308
4.862 ------4.718 8.13 18.8899
2.095 2.012 2.049 3.31 19.0009
2.056 1. 995 1.994 4.18 19.1237
4.717 ------4.492 8.74 19.3429
1.626 1. 590 1.613 3.04 19.5181
0.070 0.077 0.071 9.29 20.2926
0.756 0.744 0.680 11.99 21.1561
0.606 0.565 0.573 11.91 21. 2861
0.913 1.011 0.871 11.97 21. 4337
0.487 0.503 0.464 9.14 21. 6879
-------------------
REPORT ID: 23E081 Page 88 of 489
I
Instrument ID :67
Beginning DateTime :04/26/23 08:46
Spike Units :PPB
IC File :RDC593
M IDX Parameters
=:::===== =====================================
1 1,4-DIFLUOROBENZENE
2 Dichlorodifluoromethane
3 Dich1orotetrafluoroethane
4 Chloromethane
5 Vinyl chloride
6 Bromomethane
7 Chloroethane
8 Dichlorofluoromethane
9 Trichlorofluoromethane
10 sec-Propyl alcohol
5 11 Acrolein
12 1,1,2-Trichloro-l,2,2-trifluoroethane
5 13 Acetone
14 1,1-Dichloroethene
25 15 tert-Butyl alcohol
16 Iodomethane
17 Methyl acetate
10 18 Acetonitrile
19 Carbon disulfide
20 Methylene chloride
5 21 Acrylonitrile
22 tert-Buty1 methyl ether (MTBE)
23 trans-l,2-Dichloroethene
24 Isopropyl ether (DIPE)
25 1,1-Dichloroethane
26 Vinyl acetate
25 27 2-Butanol
28 tert-Butyl ethyl ether (ETBE)
5 29 2-Butanone
30 2,2-Dichloropropane
31 cis-1,2-Dichloroethene
32 Chloroform
33 Bromochloromethane
34 Tetrahydrofuran
5 35 tert-Amyl alcohol
36 Dibromofluoromethane
37 Cyclohexane
38 1,1,1-Trichloroethane
39 2,2,4-Trimethylpentane
40 1,1-Dichloropropene
41 Carbon tetrachloride
42 tert-Amyl methyl ether (TAME)
43 1,2-Dichloroethane-d4
44 Benzene
45 1,2-Dichloroethane
46 Trichloroethene
47 Methylcyclohexane
48 1,2-Dichloropropane
49 Bromodichloromethane
20 50 1,4-Dioxane
51 Dibromomethane
52 2-Chloroethyl vinyl ether
5 53 4-Methyl-2-pentanone
54 cis-1,3-Dichloropropene
55 CHLOROBENZENE-D5
56 Toluene-d8
57 Toluene
58 trans-l,3-Dichloropropene
59 Ethyl methacrylate
60 1,1,2-Trichloroethane
5 61 2-Hexanone
62 1,3-Dichloropropane
63 Tetrachloroethene
64 Dibromochloromethane
65 1,2-Dibromoethane
66 1-Chlorohexane
67 Chlorobenzene
68 1,1,1,2-Tetrachloroethane
69 Ethylbenzene
2 70 m-Xylene & p-Xylene
71 o-Xylene
72 Styrene
73 Isopropylbenzene
74 1,2-DICHLOROBENZENE-D4
75 Bromoform
76 1,1,2,2-Tetrachloroethane
77 4-Bromofluorobenzene
78 1,2,3-Trichloropropane
79 trans-1,4-Dichloro-2-butene
80 n-Propylbenzene
81 Bromobenzene
82 1,3,5-Trimethylbenzene
83 2-Chlorotoluene
84 4-Chlorotoluene
85 tert-Butylbenzene
86 1,2,4-Trimethylbenzene
87 sec-Butylbenzene
88 p-Isopropyltoluene
89 1,3-Dichlorobenzene
90 1,4-Dichlorobenzene
91 n-Butylbenzene
92 1,2-Dichlorobenzene
93 1,2-Dibromo-3-chloropropane
94 1,2,4-Trichlorobenzene
95 Hexachlorobutadiene
96 Naphthalene
97 1,2,3-Trichlorobenzene
INITIAL_CALIBRATION -RELATIVE_RESPONSE_FACTOR(%REC)
.3 .5 1 2 5 10 20 30
08:46 09:11 09:37 10:03 10:28 10:54 11:19 11:45
RDC588 RDC589 RDC590 RDC591 RDC592 RDC593 RDC594 RDC595
====== ====== ====== ====== ====== ====== ====== ======
1 1 1 1 1 1 1 1
95 99 110 99 95 107 96 99
------------------------------------------------
112 87 112 101 97 107 93 91
88 95 107 104 101 113 97 94
90 93 103 99 99 112 101 102
87 94 108 102 98 111 99 101
91 103 105 106 99 100 103 103
90 94 108 106 98 111 100 100
------ ------
------------------------------------
------117 104 100 87 109 96 104
93 102 104 105 96 99 103 102
------------------128 110 98 88 95
90 99 103 105 102 99 107 105
91 96 99 96 97 99 99 109
86 95 96 101 102 103 106 107
102 103 96 92 92 109 96 104
------------------ ------------------------------
90 89 99 98 99 112 104 104
------120 106 109 95 94 95 95
------81 94 108 96 102 98 108
88 96 100 105 99 101 101 106
91 100 101 104 98 99 104 104
88 98 100 104 98 99 104 105
90 101 100 105 98 99 103 104
------------82 95 98 110 97 104
------------------------------------------------
90 99 104 110 103 97 100 102
------------92 100 100 108 100 108
94 104 101 108 100 98 103 102
86 99 101 104 98 99 105 105
93 99 100 106 98 98 104 103
87 90 103 105 99 101 103 105
------------102 107 100 102 93 102
------------------89 89 111 100 111
80 92 106 98 100 106 104 106
82 88 105 97 98 110 103 105
88 100 101 106 98 100 105 104
------85 108 100 98 110 99 100
87 97 100 106 99 99 105 105
83 98 101 105 98 101 107 106
83 92 97 105 98 103 104 108
87 97 104 101 99 105 101 104
91 98 101 105 98 99 105 105
89 99 102 108 100 100 102 104
88 95 100 105 98 99 105 105
------86 100 93 95 111 102 105
83 96 100 106 98 99 105 106
87 96 101 102 98 100 105 107
------------93 98 91 100 100 107
------85 97 106 98 99 103 107
------------------91 91 94 100 109
88 85 94 108 98 103 101 111
81 96 96 102 99 101 107 109
1 1 1 1 1 1 1 1
83 97 106 99 100 106 105 104
91 103 103 107 99 100 106 104
79 91 96 104 99 102 106 110
------------85 97 94 100 103 109
85 93 101 108 100 100 103 106
90 83 92 106 97 103 100 110
87 98 98 106 99 100 103 107
90 99 100 106 96 99 105 103
85 94 95 103 100 102 106 108
80 94 98 107 100 102 104 107
85 95 96 104 98 101 108 106
89 98 102 105 98 99 105 105
87 99 96 103 97 99 106 105
88 98 100 105 98 99 107 105
91 101 100 106 99 101 108 104
87 97 100 105 99 101 108 106
84 95 % 102 97 101 109 109
84 96 98 106 99 101 109 106
1 1 1 1 1 1 1 1
------92 89 102 94 99 103 106
89 98 101 108 98 100 100 104
94 101 105 96 98 102 101 99
91 92 105 107 101 103 101 104
------------89 98 96 100 103 107
90 102 101 105 100 99 108 102
92 100 101 104 98 96 103 103
90 99 98 105 98 98 107 102
100 109 110 102 94 94 101 98
92 96 94 112 101 102 109 108
89 96 99 104 97 96 108 104
90 98 98 105 98 99 107 103
89 95 98 106 100 100 110 104
84 93 95 105 100 101 112 107
97 98 98 104 97 98 105 104
92 100 97 104 96 97 105 104
------86 89 100 98 101 112 107
98 98 99 105 96 98 105 103
------------79 99 100 100 101 110
85 86 85 96 98 102 115 114
84 82 88 109 102 101 118 110
106 84 83 90 93 100 107 115
99 88 86 97 95 100 110 113
Column Spec :RTX502.2 ID :0.25MM
Ending DateTime :04/26/23 13:53
HPChem Method :V067D26
50 100
13:53 12:36
RDC600 RDC597 AvDRec %_RSD AV_Rt_M
====== ====== ====== ====== =======
1 1 1 0 10.1420
95 106 4.5 5.66 1.8533
------------0.000 0.00 0.0000
------------7.9 9.57 2.1166
------------6.3 8.00 2.2371
99 101 3.9 5.68 2.6806
98 100 4.5 6.63 2.6967
97 94 3.8 4.77 2.7910
95 100 4.8 6.58 2.9577
------------0.000 0.00 0.0000
96 104 6.8 8.06 3.5109
98 97 3.3 3.75 3.5771
88 95 10.7 14.65 3.5907
97 96 3.8 4.80 3.7632
102 115 3.6 6.45 3.9126
102 102 4.7 6.34 4.2302
93 116 6.5 8.01 4.2814
------------0.000 0.00 0.0000
96 107 5.7 7.27 4.4991
91 92 8.1 9.90 4.5253
98 111 6.7 8.95 4.7543
99 105 3.6 5.25 4.7986
100 101 2.5 3.80 5.0251
103 102 3.5 5.08 5.6929
101 100 2.9 4.26 5.8769
99 115 7.1 9.85 5.9369
------------0.000 0.00 0.0000
98 99 3.6 5.33 6.6309
100 115 4.8 6.91 6.9104
98 92 3.6 4.81 7.1993
101 103 3.6 5.58 7.3059
100 99 2.7 3.69 7.6858
99 104 4.5 6.20 8.0526
93 105 4.1 4.96 8.1378
100 ------7.4 9.29 8.1653
102 108 6.1 8.45 8.1943
100 111 6.9 9.25 8.5654
100 98 3.2 4.92 8.5786
94 107 5.5 7.68 8.7399
102 102 3.6 5.48 8.9249
101 101 4.3 6.91 9.1017
102 107 6 7.89 9.2478
97 104 4 5.46 9.2902
101 97 3.4 4.46 9.4684
96 98 3.4 5.01 9.4874
102 102 3.7 5.21 10.7235
100 110 o.~ 8.11 10.8098
103 104 4.8 7.04 11. 0845
102 103 4 5.74 11.5199
99 111 0 6.36 11.6116
98 105 4.8 6.59 11.6005
102 115 7.1 9.00 12.1959
100 112 6.9 9.02 12.2461
104 106 5.7 8.11 12.5689
1 1 1 0 15.6023
100 100 4.3 6.69 12.9723
99 87 4.6 6.30 13 .1081
103 109 7 9.38 13 .4866
100 111 5.9 8.35 13.5203
99 106 4.8 6.90 13.7467
101 114 7.1 9.36 13.8095
98 105 4.2 5.77 14.1879
101 101 3.3 4.74 14.2434
102 108 5.5 7.11 14.6014
99 107 5.7 8.26 14.9462
104 102 5.1 6.75 15.2721
101 98 3.6 4.93 15.6622
103 103 4.3 5.81 15.7499
100 ------3.7 5.46 15.7630
89 ------4.7 6.45 15.8946
102 94 4.7 6.33 16.6251
105 101 5.5 7.51 16.6952
100 ------5 7.40 17.2275
1 1 1 0 19.4889
102 114 5.9 7.64 17.2389
97 105 3.5 5.07 17.5062
99 105 2.6 3.39 17.6041
95 105 4.7 5.75 17.7166
100 107 4.2 5.86 17.8215
93 ------4 5.54 17.8135
101 103 2.9 3.78 17.8671
102 ------3.5 4.94 18.0278
104 87 5.4 7.12 18.0453
98 87 6.3 7.90 18.1140
105 103 4.7 5.78 18.4807
102 ------4 5.24 18.5246
97 ------4.5 6.06 18.7308
103 ------6.1 8.13 18.8899
102 98 3 3.31 19.0009
103 100 3.3 4.18 19.1237
105 ------6.5 8.74 19.3429
101 99 2.6 3.04 19.5181
99 108 5.5 9.29 20.2926
111 109 10.1 11. 99 21.1561
106 99 9.4 11. 91 21. 2861
105 116 10 11. 97 21. 4337
105 108 7.3 9.14 21. 6879
----------------------------------------, F L""'L-~ J.... 60 <=---
SlA-~II /d-~ REPORT ID: 23E081 Page 89 of 489
Method
Title
Last Update
Response via
Total Cpnds
Compound List Report 67
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration ~
97
PK# Compound Name QIon Exp_RT Rel_RT Cal #Qual A/H ID
1 I
2 T
3 T
4 T
5 T
6 T
7 T
8 T
9 T
10 T
11 T
12 T
13 T
14 T
15 T
16 T
f7 T
]:8 T
19 T
2@ T
21 T
22 T
23 T
24 T
25' T
26 T
27 T
2,8 T
2,9 T
30 T
31 T
)2 T
13 T
14 T
3)5 T
1~ S
3'1 T
.... " c. 3~ T
39 T
4@ T
41' T
42' T
4~ S
~4 T
45 T
.¥6 T
47 T
48 T
49 T
50 T
th T
~2 T
S3 T
3C
1,4-DIFLUOROBENZENE
Dichlorodifluoromethane
Dichlorotetrafluoroethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Dichlorofluoromethane
Trichlorofluoromethane
see-Propyl alcohol
Acrolein
1,1,2-Trichloro-1,2,2-trifluor
Acetone
1,1-Dichloroethene
tert-Butyl alcohol
Iodomethane
Methyl acetate
Acetonitrile
Carbon disulfide
Methylene chloride
Acrylonitrile
tert-Butyl methyl ether (MTBE)
trans-1,2-Dichloroethene
Isopropyl ether (DIPE)
1,1-Dichloroethane
Vinyl acetate
2-Butanol
tert-Butyl ethyl ether (ETBE)
2-Butanone
2,2-Dichloropropane
cis-1,2-Dichloroethene
Chloroform
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Dibromofluoromethane
Cyclohexane
l,l,l-Trichloroethane
2,2,4-Trimethylpentane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TAME)
1,2-Dichloroethane-d4
Benzene
1,2-Dichloroethane
Trichloroethene
Methyl eye 1 ohexane
1,2-Dichloropropane
Bromodichloromethane
1,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
114 10.14
85 1. 86
85 ' 0.00
50 2.12
62 2.24
94 r 2.68
64 2.70
67 2.78
101 2.Q6
45 0.00
56 3.50
151 3.57
43 / 3.57,
61 r 3.76
59 3.90
142 4.22
43 4.28
41 4.32
76 4.50
49 4.51
53 4.75
73 4.79
96 5.02
45 5.70
63 5.87
43 5.93
45 6.44
59 6.63
72 6.91
77 7.20
96~ 7.30
83 7.68
130 8.05
42 8.13
59 8.16
111 8.19
84 8.56
97 8.57
57 8.73
110 8.92
119 9.10
87 9.23
65/ 9.29
78-9.47
62 9.48
130 10.72
83 10.81
63 .11. 09
83 11. 51
88· 11. 61
93 11. 60
63( 12.20
43 12.24
1.000
0.183
0.000
0.209
0.221
0.264
0.266
0.274
0.292
0.000
0.345
0.353
0.353
0.371
0.385
0.416
0.422
0.426
0.444
0.445
0.468
0.472
0.496
0.562
0.579
0.585
0.635
0.654
0.681
0.710
0.720
0.758
0.794
0.802
0.805
0.808
0.844
0.846
0.862
0.880
0.898
0.911
0.916
0.934
0.935
1.058
1.066
1.094
1.135
1.146
1.144
1. 203
1.208
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
1
1
2
1
1
1
1
1
1
1
1
1
1
2
1
1
1
1
1
2
2
1
1
1
2
1
1
1
1
2
1
2
1
2
1
1
1
2
1
1
1
1
1
2
1
3
2
1
1
1
2
1
3
A
A
A
PI.
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
: 0~ : ~\\
B
B
B
B
B
B
B
B
B
B
B REPORT ID: 23E081 Page 90 of 489
~4 T
~t
:5~ I
56 S
!i:~ T
~~ T
~~ T ":,;,..:11\ '~O T
'%'4 T :-., ~:
'602 T
>.~; it
'6'3 T
t~ T
'~;5 T
"66 T
;67 P, M
'68 T
~9 T
'70 T
'~1 T
:!7'2 T
,,~ T
~=+~
.~~ I
W;:s
'.~~
"iij;Jj
~ l'g ito
:~i
~;2
'~3
S4
'85
86
87 88
89
§,o
9)1
~~
.<';. ", 9,,:§, r,;
g~
fJ.!j
'ge
.&,-~
T
T
S
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
T
cis-1,3-Dichloropropene
CHLOROBENZENE-D5
Toluene-d8
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
l,2-DICHLOROBENZENE-D4
Bromoform
1, 1, 2, 2-Tetrachloroethane
4-Bromofluorobenzene
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-butene
n-Propylbenzene
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
l,2,4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
l,3-Dichlorobenzene
l,4-Dichlorobenzene
n-Butylbenzene
l,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
l,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
1, 2, 3-Trichlorobenzene
75 12.56
117
98
91
75
69
97
43
76
164
129
107
15.60
12.97
13.10
13.48
13.51
13.75
13.80
14.18
14.24
14.59
14.94
15.27
15.66
15.75
91 .
112
131
91
91
91
r 15 .76
/'15.89
/16.62
104
105
16.70
17.22
152 19.49
173 17.24
83 17.50
95 17.60
110 17.72
53 17.82
91 17.81
156. 17.87
105 18.03
91' 18.04
91 18.12
134 18.48
105 '18.52
105 18.73
119 18.89
146 18.99
146',19.12
91 19.34
146/ 19.52
157 20.29
180 r 21.15
225 21.29
128/ 21.43
180 21.68
1.239
1.000
0.831
0.840
0.864
0.866
0.881
0.885
0.909
0.913
0.935
0.958
0.978
1. 004
1.009
1.010
1.019
1.066
1.070
1.104
1. 000
0.885
0.898
0.903
0.909
0.914
0.914
0.917
0.925
0.926
0.930
0.948
0.951
0.961
0.969
0.975
0.981
0.992
1.001
1.041
1.085
1.092
1.100
1.112
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
3
2
1
1
1
1
2
1
1
3
1
1
1
1
1
1
1
1
2
3
1
2
1
2
1
1
2
1
2
1
1
1
1
1
2
2
2
2
1
1
2
2
1
2
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
~al A = Average L = Linear LO = Linear w/origin Q Quad QO Quad w/origin
*Qual = number of qualifiers
c A/H = Area or Height
ID R R.T. B = R.T. & Q Q = Qvalue L = Largest A = All
~-------------------------------------------------------------------------
E: V067D26.M Thu Apr 27 08:26:36 2023
REPORT ID: 23E081 Page 91 of 489
BFB
Data File D:\HPCHEM\1\DATA\23D26\RDC587.D Vial: 1
Acq On 26 Apr 2023 8:20 am Operator: VLu
Sample BFB67D24 Inst 67
Misc T/CHK Mul tiplr: l. 00
MS Integration Params: RTE.P
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title : METHOD 8260B
bundance
50000]
40000
30000
20000
10000
0
ime->
bun dance
450001
40000 1
350001 174
I
30000
25000
75
20000
15000
10000 50
5000
!TI/z-->
AutoFind: Scans 1042, 1043, 1044; Background Corrected with Scan 1036
I Target I ReI. to I L~w~r
Mass Mass Llmlt%
50 95 15
75 95 30
95 95 100
96 95 5
173 174 0.00
174 95 50
175 174 5
176 174 95
177 176 5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
ReI.
Abn%
20.4i
45.1
100.0
6.4
0.0
76.5
7.2
99.4
6.2/
Raw
Abn
9409
20829
46171
2945
0
35317
2554
35093
2178
RDC587.D V067D26.M Thu Apr 27 08: 24: 18 2023's ~ \ \l ~=$
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 23E081 Page 92 of 489
-; :
;~,~
~~: :l
Quantitation Report (QT Reviewed)
;;,Data File D: \HPCHEM\l \ DATA \23D26\RDC588. D Vial: 2
VLu
67
1. 00
':Acq On 26 Apr 2023 8: 46 am Operator:
;t;Sample V067D261
HMisc O. 3ppb 8260/1.5ppb KET-AA/7. 5ppb TBA
:; MS Integration Params: RTE. P
Inst
Multiplr:
Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.RES
,',
5Quant Method
".~ Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
'.~. Last Update
jResponse via
~;])ataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
iInternal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
~~:~ System Monitoring Compounds
:'~ 36) Dibromofluoromethane
if Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
~ 56) Toluene-d8
f Spiked Amount 10.000
,. 77) 4-Bromofluorobenzene
.~ Spiked Amount 10.000
.j' ,~~
::;;Target Compounds
2)
4)
5)
6)
7)
8)
9)
" 11)
'" 12)
13)
14)
15)
16)
17)
19)
20)
I 21)
22)
; 23)
24)
25)
26 )
28 )
30 )
31)
32)
33)
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Dichlorofluoromethane
Trichlorofluoromethane
Acrolein
l,l,2-Trichloro-1,2,2-trif
Acetone
l,l-Dichloroethene
tert-Butyl alcohol
Iodomethane
Methyl acetate
Carbon disulfide
Methylene chloride
Acrylonitrile
tert-Butyl methyl ether (M
trans-1,2-Dichloroethene
Isopropyl ether (DIPE)
l,l-Dichloroethane
Vinyl acetate
tert-Butyl ethyl ether (ET
2,2-Dichloropropane
cis-1,2-Dichloroethene
Chloroform
Bromochl orome thane
R.T. QIon Response Cone Units Dev(Min)
10.15
15.60
19.49
114 2335620
117 1655304
152 455925
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
8.19 111
9.29 65
12.97 98
17.60 95
1. 84
2.12
2.24
2.66
2.70
2.78
2.96
3.53
3.59
3.59
3.76
3.94
4.23
4.29
4.51
4.53
4.76
4.82
5.04
5.70
5.87
5.96
6.64
7.20
7.30
7.70
8.05
85
50
62
94
64
67
101
56
151
43
r 61
59
142
43
76
49
53
73
/ 96
45
63
/ 43
59
77
/ 96
83
130
13397 0.24 ug/l 0.00
Recovery = 2.40%
11097 0.26 ug/l 0.00
Recovery 2.60%
57477 0.25 ug/l 0.00
Recovery = 2.50%
17424 0.28 ug/l 0.00
Recovery 2.80%
20225
41629
29000
18339
18846
37094
21506
10713
14677
39443
34754
17577
28821
9241
72443
41193
15166
29519
24163
67892
38650
17879
47475
26237
21598
32200
8931
0.28 ug/l
0.34 ug/l
0.26 ug/l
0.27 ug/l
0.26 ug/l
0.27 ug/l
0.27 ug/l
1.96 ug/l
0.28 ug/l
4.21 ug/l
0.27 ug/l
6.83 ug/l
0.26 ug/l
0.30 ug/l
0.27 ug/l
0.38 ug/l
1. 23 ug/l
0.26 ug/l
0.27 ug/l
0.26 ug/l
0.27 ug/l
0.22 ug/l
0.27 ug/l
0.28 ug/l
0.26 ug/l
0.28 ug/l
0.26 ug/l
Qvalue
82
99
94
97
89
94
95
74
99
84
98
93
99
76
93
98
94
97
96
95
98
88
94
93
97
97
95
(#) = qualifier out of range (m) = manual integration
RDC588.D V067D26.M Thu Apr 27 08:28:45 2023 Page 1
REPORT ID: 23E081 Page 93 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC588.D
;Acq On 26 Apr 2023 8:46 am
'Sample V067D261
:Misc 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
. Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.RES
• <
, Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. Qlon Response Cone Unit
37)
38)
39)
<: 40)
. -. 41)
¥, 42)
v 44)
45)
46)
( 47)
T 48)
~:~ 49)
} 51)
53)
54)
57)
58)
59)
60)
61)
62)
63)
64)
'" 65)
66)
67)
68)
69)
70)
71)
72)
73)
75)
76)
78)
80)
81)
82)
83)
84)
85)
Cyclohexane
1,1,1-Trichloroethane
2,2,4-Trimethylpentane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
1,2-Dichloroethane
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
Bromodichloromethane
Dibromomethane
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
lsopropylbenzene
Bromoform
1,1,2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
n-Propylbenzene
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
8.57
8.59
8.75
8.92
9.10
9.25
9.46
9.49
10.74
10.81
11.09
11.53
11.61
12.26
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.24
14.61
14.96
15.28
15.67
15.75
15.76
15.89
16.62
16.70
17.24
17.24
17.52
17.72
17.82
17.87
18.03
18.06
18.11
18.48
84
97
57
110
119
87
78
,(62
130
83
63
83
93
43
<' 75
91
75
69
97
43
76
164
129
107
/ 91
112
131
91
91
91
104
,lOS
173
83
110
/ 91
156
105
91
91
134
32024
25659
75999
10406
19343
6877
85012
14687
20389
34825
17436
19792
6472
45464
24011
80678
15769
10281
8865
28089
18017
15745
9912
7510
32243
44659
12818
87805
130855
58934
43482
74119
3625
8352
2278
89478
12848
55583
64048
48676
12112
0.25
0.27
0.22
0.26
0.25
0.25
0.27
0.27
0.26
0.24
0.25
0.26
0.23
1.32
0.24
0.27
0.24
0.21
0.25
1.36
0.26
0.27
0.26
0.24
0.26
0.27
0.26
0.27
0.55
0.26
0.25
0.25
0.22
0.27
0.27
0.27
0.28
0.27
0.30
0.28
0.27
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l'
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
(#) = qualifier out of range (m) = manual integration (~,~ ~1\\~<~
RDC588.D V067D26.M Thu Apr 27 08:28:46 2023 ~ v-~
Qvalue
95
92
95
96
96
94
99
92
97
99
95
96
95
95
99
99
98
89
97
96
97
95
99
96
99
100
99
99
97
100
98
100
99
99
97
99
99
96
94
96
98
Page 2
REPORT ID: 23E081 Page 94 of 489
Quantitation Report
pata File D:\HPCHEM\1\DATA\23D26\RDC588.D
Aeq On 26 Apr 2023 8:46 am
Sample V067D261
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(,2T Reviewed)
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
86) 1,2,4-Trimethylbenzene 18.52 < 105 51545 0.27 ug/l 98
87) see-Butylbenzene 18.74< 105 73459 0.27 ug/l 97
~.", 88) p-Isopropyltoluene 18.89 119 54505 0.25 ug/l 100
~, 89) 1,3-Diehlorobenzene 19.01 I 146 27068 0.29 ug/l 97
;.. 90) 1,4-Diehlorobenzene 19.12, 146 25111 0.28 ug/l 98
91) n-Butylbenzene 19.34 91 48023 0.23 ug/l 99
92) 1,2-Diehlorobenzene 19.52' 146 21549 0.29 ug/l 93
94) 1,2,4-Triehlorobenzene 21.17 180 7864 0.25 ug/l 96
95) Hexaehlorobutadiene 21.29( 225 6626 0.25 ug/l 90
96) Naphthalene 21.45 128 12638 0.32 ug/l 94
97) 1,2,3-Triehlorobenzene 21.69 180 6259 0.30 ug/l 91
____________________________________________________ ~_~ __ ~t~l~? _______ _
(#) = qualifier out of range (m) = manual integration
RDC588.D V067D26.M Thu Apr 27 08:28:46 2023 Page 3
REPORT ID: 23E081 Page 95 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC588.D
Aeq On 26 Apr 2023 8:46 am
Sample V067D261
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.REE
I
Method
Title
Last Update
Response via
1500000
700000
I
600000
500000
::t. .,.....
Dt.i
i Il!l
100000 I ,
ffime-->
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
w
~ w m o a:: o
::I
...J
U.
15 ....
TIC: RDC588.D
(RTE Integrator)
t
iii z
~ z w m
~ o
...J :r: u
15
~
RDC588.D V067D26.M Thu Apr 27 08:28:48 2023 S;:\\\:J--3 Page 4
REPORT ID: 23E081 Page 96 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D Vial: 3
Operator: Acq On 26 Apr 2023 9:11 am
Sample V067D262
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
Inst
Multiplr:
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
[
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
ISystem Monitoring Compounds
f 36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
LTarget Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
R.T. QIon Response Conc Units Dev(Min)
10.15
15.60
19.49
114 2227413
117 1566290
152 442714
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
8.19 111
9.29 65
12.97 98
17.60 95
1.85 85
50
62
94
64
67
101
56
151
43
61
r 59
142
43
76
49
53
73
2.11
2.23
2.70
2.70
2.78
2.96
3.50
3.57
3.59
3.76
3.92
4.23
4.29
4.50
4.53
4.76
4.80
5.02
5.70
5.89
5.94
6.63
7.22
7.30.-
7.68
8.06
r 96
r
45
63
43
59
77
96
83
130
24319 0.46 ug/l 0.00
Recovery 4.60%
19733 0.49 ug/l 0.00
Recovery = 4.90%
106080 0.49 ug/l 0.00
Recovery = 4.90%
30173 0.50 ug/l 0.00
Recovery = 5.00%
33781
51404
49591
30209
32273
66478
35978
14963
25430
35528
60455
29446
50749
14966
113808
62407
24082
50908
42089
120531
69125
29960
83176
46261
39371
54720
14741
Qvalue
0.50 ug/l 91
0.44 ug/l 90
0.47 ug/l 96
0.47 ug/l 97
0.47 ug/l 96
0.51 ug/l 94
0.47 ug/l 95
2.87 ug/l 84
0.51 ug/l 97
3.98 ug/l 100
0.49 ug/l 97
12.00 ug/l 94
0.47 ug/l 100
0.52 ug/l 82
0.45 ug/l 96
0.60 ug/l 98
2.05 ug/l 96
0.48 ug/l 100
0.50 ug/l 97
0.49 ug/l 98
0.51 ug/l 97
0.38 ug/l 89
0.49 ug/l 96
0.52 ug/l 96
0.49 ug/l 99
0.50 ug/l 99
0.45 ug/l 98
(#) = qualifier out of range (m) = manual integration~~
RDC589.D V067D26.M Thu Apr 27 08:30:53 2023 z>f\\)-~ Page 1
REPORT ID: 23E081 Page 97 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D
Acq On 26 Apr 2023 9:11 am
Sample V067D262
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 3
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
37) Cyclohexane
38) 1,1,1-Trichloroethane
39) 2,2,4-Trimethylpentane
40) 1,1-Dichloropropene
41) Carbon tetrachloride
j 42) tert-Amyl methyl ether (TA
fv 44) Benzene
45) 1,2-Dichloroethane
46) Trichloroethene
C 47) Methylcyclohexane
1 48) 1,2-Dichloropropane
L 49) Bromodichloromethane
R 51) Dibromomethane
1: 52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
; 64) Dibromochloromethane
" 65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
;-71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) 1,1,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
82) 1,3,5-Trimethylbenzene
83) 2-Chlorotoluene
8.57 84
8.59 97
8.73 57
8.92 110
9.11 119
9.25 87
9.47 78
9.49 62
10.72 130
10.81 83
11.09 63
11. 53 83
11.61 93
12.20 63
12.26 43
12.58 ,75
13.10 91
13.50 / 75
13.53 69
13.75 97
13.82 43
14.20 76
14.24 164
14.61 129
14.94 107
15.28 (' 91
15.66 112
15.75 131
15.76 I 91
15.89 91
16.63/ 91
16.70 1 104
17.22/105
17.24 173
17.52 83
17.72 110
17.82 53
17.82 / 91
17.87 156
18.03 105
18.04 91
54806
46110
139816
18491
36416
11985
146337
25883
35103
59356
32267
34723
11502
4422
69830
45133
143921
28471
17886
15452
40870
31869
27504
17157
13776
56478
78079
23063
152914
228317
104022
77793
134425
7206
14875
3753
2970
163482
22606
99844
113562
(#) = qualifier out of range (m) = manual integration
0.44 ug/l
0.50 ug/l
0.43 ug/l
0.49 ug/l
0.49 ug/l
0.46 ug/l
0.49 ug/l
0.50 ug/l
0.48 ug/l
0.43 ug/l
0.48 ug/l
0.48 ug/l
0.43 ug/l
0.37 ug/l
2.13 ug/l
0.48 ug/l
0.52 ug/l
0.45 ug/l
0.39 ug/l
0.47 ug/l
2.10 ug/l
0.49 ug/l
0.50 ug/l
0.47 ug/l
0.47 ug/l
0.47 ug/l
0.49 ug/l
0.49 ug/l
0.49 ug/l
1.01 ug/l
0.49 ug/l
0.47 ug/l
0.48 ug/l
0.46 ug/l
0.49 ug/l
0.46 ug/l
0.35 ug/l
0.51 ug/l
0.50 ug/l
0.50 ug/l
0.55 ug/l
RDC589.D V067D26.M Thu Apr 27 08:30:54 2023 .-51,/\
Qvalue
96
91
98
96
100
98
99
100
98
98
100
89
92
80
96
98
98
93
93
99
97
100
95
100
98
97
100
97
99
97
100
100
99
95
96
89
97
99
99
97
93
REPORT ID: 23E081 Page 98 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D
Aeq On 26 Apr 2023 9:11 am
Sample V067D262
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 3
Operator: VLu
67
1. 00
Inst
Multiplr:
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
84) 4-Chlorotoluene 18.12 91 81996 0.48 ug/l
85) tert-Butylbenzene 18.48 134 21178 0.48 ug/l 1: 86) 1, 2, 4-Trimethylbenzene 18.52 ·105 91244 0.49 ug/l
l~ 87) see-Butylbenzene 18.73 ' 105 126668 0.48 ug/l
E 88 ) p-Isopropyltoluene 18.89 119 97475 0.47 ug/l
y 89) l,3-Diehlorobenzene 19.01 I 146 44443 0.49 ug/l
1\ 90) l,4-Diehlorobenzene 19.12 ' 146 44214 0.50 ug/l
91) n-Butylbenzene 19.34 , 91 85784 0.43 ug/l
92) l,2-Diehlorobenzene 19.52/146 34862 0.49 ug/l
93) l,2-Dibromo-3-ehloropropan 20.29 157 816 0.26 ug/l
94) l,2,4-Triehlorobenzene 21.15 ( 180 12950 0.43 ug/l
95) Hexaehlorobutadiene 21. 29'/ 225 10387 0.41 ug/l
96) Naphthalene 21.43 128 16181 0.42 ug/l
97) 1, 2, 3-Triehlorobenzene 21. 70 1 180 9061 0.44 ug/l
1 L.,
r
Qvalue
95
97
98
99
100
99
97
99
93
82
97
94
100
98
e::,1/'-~
, ----------------------------------------------------------,5 J-\ l ~ --------
(#) = qualifier out of range (m) = manual integration
RDC589.D V067D26.M Thu Apr 27 08:30:54 2023 Page 3
REPORT ID: 23E081 Page 99 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D
Aeq On 26 Apr 2023 9:11 am
Sample V067D262
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
Vial: 3
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
rOO"da"""
'. 1800000
1700000
1 .. vV'JVV;
1
1100000
1000000
900000
600000 I
500000 :::;;
~ .,
c:
til :::;; ~ ~:::;; e
0 w..,:
:::;;:::;; " m'
~ ~ ~~l'! il ~ ~';:'~ ~"-lti! I~~ IPf I!i e , : ." c: ~t: ~ g s-
Time->
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC589.D
:::;;
:::;; ..,:
~ :::;; ~ :::;; :::;;~ ~ :::;; W ~. I-
I-~ m ~ ~ ~:s ~ .~ ~:::;; i:::;;· :::;;.
I-~c» c: G)..,: ... t-: ~. w-: ~ ~~i p~l·r·' a..a. 1 ~ ~ s fiJli i~! 5 ~3;i Ii ~ s2 .,
i~1 ,st;: l ':E IS: 256 iI ~i I~ ~ i I ~ g § ~ Jii.el
" l~1 ' '? IE . tHO, ~e gap m
I-'" !!! ;;~ ~~~~ ~ t: ~ Q(! S N DI:l 0 1 UJ 'l"""i5~
N ~
~
t w z
~ w m o
0::
9
J:
U
6
<'i.
:::;; ..,:
oj
c:
til ~
0-e
.9 .<: u ..; .;
E e
fl
0
<'i.
~.:::;;. c, 1-.
&1 ~.9 r;-!i 'C ~3
RDC589.D V067D26.M Thu Apr 27 08:30:56 2023 :5 fA !51\~ Page 4 REPORT ID: 23E081 Page 100 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D Vial: 4
Operator: VLu Acq On 26 Apr 2023 9:37 am
Sample V067D263 Inst 67
Misc 1.0ppb 8260/5.0ppb KET-AA/25ppb TBA Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
~:\System Monitoring Compounds
c 36) Dibromofluoromethane
h Spiked Amount 10.000
; 43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.14
15.60
19.49
114 2165460
117 1543098
152 445946
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.19 111
9.29 65
12.97 98
17.60 95
1. 86
2.12
2.24
2.68
2.70
2.78
2.96
3.53
3.57
3.59
3.76
3.92
4.23
4.28
4.50
4.53
4.76
4.80
5.02
5.70
5.87
5.94
6.63
6.91
7.19
7.32
7.68
85
50
62
94
64
67
101
56
151
43
61
" 59
142
43
76
49
53
73
~ 96
45
63
43
59
72
77
96
83
54583 1.06 ug/l 0.00
Recovery 10.60%
40915 1.04 ug/l 0.00
Recovery = 10.40%
228415 1.06 ug/l 0.00
Recovery = 10.60%
63033 1.05 ug/l 0.00
Recovery 10.50%
72942
128259
109031
65421
72220
132052
79994
25534
50264
68593
122498
58923
100106
27114
245001
107106
53961
103608
82345
238584
132990
69379
169919
12761
87281
78216
107361
1.10 ug/l
1.12 ug/l
1. 07 ug/l
1.04 ug/l
1. 08 ug/l
1.05 ug/l
1.08 ug/l
5.03 ug/l
1.04 ug/l
7.90 ug/l
1.03 ug/l
24.70 ug/l
0.96 ug/l
0.96 ug/l
0.99 ug/l
1.06 ug/l
4.74 ug/l
1.00 ug/l
1.00 ug/l
1.00 ug/l
1. 00 ug/l
0.91 ug/l
1.04 ug/l
4.42 ug/l
1.01 ug/l
1.01 ug/l
1. 00 ug/l
Qvalue
98
99
98
99
98
100
99
76
96
92
97
96
99
80
96
97
96
100
99
98
98
96
93
94
99
99
99
(#) = qualifier out of range (m) = manual integration
RDC590.D V067D26.M Thu Apr 27 08:31:58 2023 Page 1
REPORT ID: 23E081 Page 101 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D
Acq On 26 Apr 2023 9:37 am
Sample V067D263
Misc 1.0ppb 8260/5.0ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 4
Operator: VLu
Inst 67
Mul tiplr: 1. 00
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. Qlon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
35) tert-Amyl alcohol
37) Cyclohexane
38) l,l,l-Trichloroethane
39) 2,2,4-Trimethylpentane
r 40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
C 44) Benzene
1 45) l,2-Dichloroethane
L 46) Trichloroethene
R 47) Methylcyclohexane
[ 48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
8.05 130
8.15 42
8.19 59
8.56 84
8.57 97
8.73 57
8.92 110
9.10 119
9.26 87
9.47 78
9.48 62
10.72 130
10.81 ""83
11.09 <63
11. 53 83
11. 63 88
11.60 93
12.20/ 63
12.26 43
12.56 '75
13.10 91
13.48 / 75
13.53 69
13.75 97
13.82 43
14.19 76
14.24 164
14.59 129
14.94 107
15.27 ./ 91
15.66 112
15.75 131
15.76 I 91
15.89"! 91
16.63 ! 91
16.70 "104
17.22 L 105
17.24 173
17.50 83
17.72 110
17.82 53
32534
9554
6893
126581
90742
345233
36932
72949
24618
292880
51845
71634
134599
65194
71354
4728
25401
9267
149689
88207
282853
59430
38066
32973
88412
62834
54376
34282
28530
112325
158902
44258
308361
448159
209853
155588
270299
14063
30760
8591
7599
1.03 ug/l
1.02 ug/l
3.64 ug/l
1.05 ug/l
1.01 ug/l
1.08 ug/l
1.00 ug/l
1.01 ug/l
0.96 ug/l
1.01 ug/l
1.02 ug/l
1.00 ug/l
1.00 ug/l
1.00 ug/l
1.01 ug/l
18.68 ug/l
0.97 ug/l
0.79 ug/l
4.70 ug/l
0.96 ug/l
1.03 ug/l
0.96 ug/l
0.85 ug/l
1.01 ug/l
4.60 ug/l
0.98 ug/l
1.00 ug/l
0.95 ug/l
0.98 ug/l
0.96 ug/l
1.02 ug/l
0.96 ug/l
1.00 ug/l
2.01 ug/l
1.00 ug/l
0.96 ug/l
0.98 ug/l
0.89 ug/l
1.01 ug/l
1.04 ug/l
0.89 ug/l
(#) = qualifier out of range (m) = manual integration S l/'--.
RDC590.D V067D26.M Thu Apr 27 08:31:58 2023 r:5 i \{'L5
Qvalue
96
80
90
95
99
99
98
99
92
100
100
98
99
100
99
100
98
96
98
98
100
89
93
95
97
99
99
99
98
99
98
100
99
99
100
99
99
99
99
100
86
Page 2
REPORT ID: 23E081 Page 102 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D
Aeq On 26 Apr 2023 9:37 am
Sample V067D263
~ise 1.0ppb 8260/5.0ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 4
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.RES
Quant Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
DataAeq Meth V067D26
Compound R.T. Qlon Response Cone Unit Qvalue
-------------------------------------------------------------------------
80 ) n-Propylbenzene 17.81 91 326257 1.01 ug/l 99
81) Bromobenzene 17.87 156 46166 1.01 ug/l 98
r 82) 1,3,5-Trimethylbenzene 18.03 105 198631 0.98 ug/l 100
~ 83) 2-Chlorotoluene 18.04 , 91 229944 1.10 ug/l 93
Q 84) 4-Chlorotoluene 18.12 91 161309 0.94 ug/l 95 v' t\l~ 85) tert-Butylbenzene 18.48 134 44204 0.99 ug/l 99
i\! 86 ) 1,2,4-Trimethylbenzene 18.52 (105 183193 0.98 ug/l 100
87) see-Butylbenzene 18.73 I 105 261892 0.98 ug/l 99
88) p-Isopropyltoluene 18.89 I 119 200168 0.95 ug/l 99
89 ) 1,3-Diehlorobenzene 19.01 I 146 89318 0.98 ug/l 100
90) l,4-Diehlorobenzene 19.12 146 86575 0.97 ug/l 98
91) n-Butylbenzene 19.34 91 178907 0.89 ug/l 98
92) 1,2-Diehlorobenzene 19.52 r 146 70938 0.99 ug/l 96
93) 1,2-Dibromo-3-ehloropropan 20.29 157 2514 0.80 ug/l 93
94) 1,2,4-Triehlorobenzene 21.15 ( 180 25885 0.85 ug/l 97
95) Hexaehlorobutadiene 21. 29 / 225 22460 0.88 ug/l 95
96) Naphthalene 21.43 128 32258 0.83 ug/l 98
97) 1,2,3-Triehlorobenzene 21.70 180 17709 0.86 ug/l 97
------------------------------------------------------~-~--~-[~~~-~---
(#) = qualifier out of range (m) = manual integration
RDC590.D V067D26.M Thu Apr 27 08:31:59 2023 Page 3
REPORT ID: 23E081 Page 103 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D
Aeq On 26 Apr 2023 9:37 am
Sample V067D263
Mise 1.0ppb 8260/5.0ppb KET-AA/25ppb TBA
Vial: 4
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.REE
Method
Title
Last Update
Response via
lAbundance
i
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC590.D
. i
I
1500000
1000000
600000
500000
I
ITime-->
RDC590.D V067D26.M
w z
~ z w
CD o ex: o
:3 u.
~
, 14.00 15.00 16.00 1ioo 18.00 19.0020.00 21.00 .
Thu Apr 27 08:32:01 2023 Page 4
REPORT ID: 23E081 Page 104 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Acq On 26 Apr 2023 10:03 am
Sample V067D264
Vial: 5
Operator: VLu
Inst 67
Misc 2.0ppb 8260/10ppb KET-AA/50ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26:M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
( Spiked Amount 10.000
1 77) 4-Bromofluorobenzene
1: Spiked Amount 10.000
LTarget Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.14 114
15.60 117
19.49 152
8.19 111
9.29 65
12.97 98
17.60 95
1. 86
2.12
2.24
2.68
2.70
2.80
2.96
3.53
3.57
3.59
3.78
3.92
4.22
4.28
4.50
4.53
4.76
4.80
5.02
5.70
5.89
5.94
6.63
6.92
7.20
I 7.30'
7.68
85
50
62
94
64
67
101
56
151
43
/ 61
59
142
43
76
49
53
73
J 96
45
/ 63
43
59
72
77
96
83
2105743
1502963
449730
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
98047 1.95 ug/l 0.00
Recovery 19.50%
77116 2.01 ug/l 0.00
Recovery = 20.10%
411745 1.97 ug/l 0.00
Recovery = 19.70%
117188 1.93 ug/l 0.00
Recovery = 19.30%
127055
225572
205221
120888
132059
260115
152680
48781
98835
108039
242569
111785
204141
50333
472352
213342
119092
210680
165599
486135
271457
140810
351718
28390
181594
156574
221325
1. 98
2.08
1. 98
2.04
2.12
2.11
9.89
2.10
12.79
2.10
48.18
2.02
1. 83
1. 96
2.18
10.75
2.09
2.08
2.09
2.10
1. 91
2.21
10.11
2.16
2.07
2.12
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
98
99
99
98
100
99
97
94
100
100
99
97
98
100
100
100
98
99
100
96
99
98
95
87
98
99
99
(#) = qualifier out of range (m) = manual integration
RDC591.D V067D26.M Thu Apr 27 08:32:25 2023 Page 1
REPORT ID: 23E081 Page 105 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Acq On 26 Apr 2023 10:03 am
Sample V067D264
Misc 2.0ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 5
Operator: VLu
67
1.00
Inst
Multiplr:
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
33)
34)
[ 35)
l 37)
~ 38)
l' 39)
1" 40)
41)
42)
( 44)
45)
46)
47)
48)
49)
50 )
51)
52)
53)
54)
57)
. 58)
59)
60 )
61)
62)
63)
64)
65)
66)
67)
68)
69)
70)
71)
72)
73)
75)
76)
78)
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
1, 1, I-Trichloroethane
2, 2, 4-Trimethylpentane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
1,2-Dichloroethane
Trichloroethene
Methyl eye 1 ohexane
1,2-Dichloropropane
Bromodichloromethane
1,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
l-Chlorohexane
Chlorobenzene
1,1,1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
l,l,2,2-Tetrachloroethane
1,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05
8.14
8.21
8.56
8.57
8.74
8.93
9.10
9.26
9.47
9.50
10.72
10.81
11.09
11.53
11. 61
11.60
12.20
12.24
12.56
13.10
13.48
13.53
13.75
13.81
14.19
14.24
14.61
14.95
15.27
15.66
15.75
15.76
15.89
16.63
16.70
17.22
17.24
17.50
17.71
17.82
130
42
59
84
97
57
110
119
87
178
/ 62
130
, 83
63
83
, 88
93
63
< 43
75 r 91
-<75
69
97
43
76
164
129
107
j 91
112
131
< 91
, 91
91
'104
( 105
173
83
110
53
64637
19208
16323
229502
184205
619597
76048
147654
52122
589844
106518
146439
242950
134863
139314
9698
53812
20667
334369
182560
572373
125397
84467
68471
198605
133186
112716
72390
60683
237227
320768
92684
630650
925386
432325
321717
568372
32449
66389
17674
16903
(#) = qualifier out of range (m) = manual integration
RDC591.D V067D26.M Thu Apr 27 08:32:26 2023
2.11
2.11
8.86
1.95
2.11
2.00
2.11
2.10
2.10
2.10
2.16
2.11
1.85
2.13
2.03
39.40
2.11
1. 81
10.80
2.04
2.14
2.08
1.94
2.16
10.61
2.13
2.13
2.06
2.15
2.08
2.10
2.07
2.10
4.25
2.11
2.05
2.12
2.03
2.15
2.13
1. 96
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
98
94
91
100
90
99
99
99
98
100
99
98
98
97
98
"I"" .LVV
99
100
99
98
100
98
98
99
98
98
99
99
99
100
99
99
100
99
100
99
99
96
99
95
96
Page 2
REPORT ID: 23E081 Page 106 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Acq On 26 Apr 2023 10:03 am
Sample V067D264
Mise 2.0ppb 8260/10ppb KET-AA/50ppb
MS Integration Params: RTE.P
Vial: 5
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
80 ) n-Propylbenzene 17.81 r 91 689742 2.11 ug/l
81) Bromobenzene 17.87 156 95587 2.08 ug/l
I 82) l,3,5-Trimethylbenzene 18.03 105 426450 2.09 ug/l
83) 2-Chlorotoluene 18.04 < 91 430326 2.04 ug/l
84) 4-Chlorotoluene 18.12 I 91 386777 2.23 ug/l
85) tert-Butylbenzene 18.48 ( 134 93541 2.08 ug/l
86) l,2,4-Trimethylbenzene 18.52 105 398293 2.11 ug/l
87) see-Butylbenzene 18.73 105 573386 2.12 ug/l
88) p-Isopropyltoluene 18.89 ( 119 443939 2.09 ug/l
89) l,3-Diehlorobenzene 19.01 146 190807 2.07 ug/l
90) l,4-Diehlorobenzene 19.12 J 146 185667 2.07 ug/l
L 91) n-Butylbenzene 19.34 ( 91 405021 2.00 ug/l
f 92) l,2-Diehlorobenzene 19.52 146 151625 2.09 ug/l
"'-93) l,2-Dibromo-3-ehloropropan 20.29 157 6264 1. 98 ug/l
94) l,2,4-Triehlorobenzene 21.16-180 58642 1.92 ug/l
95) Hexaehlorobutadiene 21.29 225 56308 2.19 ug/l
96) Naphthalene 21.43 128 70658 1.80 ug/l
97) 1, 2, 3-Triehlorobenzene 21. 68 180 40382 1.93 ug/l
Qvalue
99
99
99
99
98
98
98
100
99
100
99
99
98
97
99
98
98
98
-------_______________________________________________ ~~jJ~~-----
(#) = qualifier out of range (m) = manual integration
RDC591.D V067D26.M Thu Apr 27 08:32:26 2023 Page 3
REPORT ID: 23E081 Page 107 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Acq On 26 Apr 2023 10:03 am
Vial: 5
Operator: VLu
Inst 67 Sample V067D264
Mise 2.0ppb 8260/10ppb KET-AA/50ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration IArCbu~ndLa~nc~e~1 ~~~~~~~~~~==~~~~~Tmlc~:nR~DC~5~9~1.~D-----------------------------~
117000001
11600000]
i
1500000
1400000
·1 1300000
1200000
1100000
1000000 1
900000
RDC591.D V067D26.M
u.i z
~
W
<D
lE o
:::l
..J
U.
is
-I:
Thu Apr 27 08:32:28 2023
.n c
ui z
Page 4
REPORT ID: 23E081 Page 108 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D Vial: 6
Operator: VLu Acq On 26 Apr 2023 10:28 am
Sample V067D265 Inst 67
Misc 5.0ppb 8260/25ppb KET-AA/125ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
I:System Monitoring Compounds
c 36) Dibromofluoromethane
fv Spiked Amount 10.000
~ 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
(. 13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. Qlon Response Conc Units Dev(Min)
10.14 114
15.60 117
19.49 152
2232342
1629177
496816
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.20 111 265381 4.99 ug/l 0.00
Recovery 49.90%
9.29 65 201837 4.97 ug/l 0.00
Recovery = 49.70%
12.97 98 1134923 5.01 ug/l 0.00
Recovery 50.10%
17.60 95 327706 4.88 ug/l 0.00
1. 86 85
50
62
94
64
67
101
56
151
43
r 61
59
142
43
76
49
53
73
2.12
2.24
2.68
2.70
2.80
2.96
3.53
3.57
3.59
3.76
3.92
4.24
4.28
4.50
4.53
4.76
4.79
5.02
5.70
5.89
5.94
6.63
6.91
7.19
7.30 !
7.68
I 96
45
/63
43
59
72
77
96
83
Recovery = 48.80%
323009
575122
530190
319552
336515
640659
376145
113929
240021
247925
627145
299297
547870
133105
1269320
495774
283291
529888
411364
1203044
667038
383539
867211
71377
448254
393098
539436
Qvalue
4.74 ug/l 98
4.86 ug/l 100
5.06 ug/l 100
4.94 ug/l 99
4.90 ug/l 98
4.93 ug/l 100
4.91 ug/l 100
21.79 ug/l 100
4.80 ug/l 100
27.69 ug/l 96
5.12 ug/l 98
121.69 ug/l 99
5.11 ug/l 100
4.57 ug/l 98
4.97 ug/l 100
4.78 ug/l 99
24.12 ug/l 98
4.97 ug/l 100
4.87 ug/l 100
4.88 ug/l 100
4.88 ug/l 99
4.90 ug/l 99
5.13 ug/l 96
23.97 ug/l 99
5.02 ug/l 99
4.90 ug/l 99
4.88 ug/l 100
. (#) = qualifier out of range (m) = manual integration
RDC592.D V067D26.M Thu Apr 27 08:32:45 2023 Page 1
REPORT ID: 23E081 Page 109 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D
Acq On 26 Apr 2023 10:28 am
Sample V067D265
Misc 5.0ppb 8260/25ppb KET-AA/125ppb
MS Integration Params: RTE.P
Vial: 6
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
35) tert-Amyl alcohol
37) Cyclohexane
38) l,l,l-Trichloroethane
39) 2,2,4-Trimethylpentane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
C 44) Benzene
1 45) l,2-Dichloroethane
L 46) Trichloroethene
I; 47) Methylcyclohexane
[ 48) l,2-Dichloropropane
49) Bromodichloromethane
50} l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
'>. 64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
8.06
8.14
8.17
8.56
8.58
8.74
8.93
9.10
9.25
9.47
9.48
10.72
10.81
11. 07
11.51
11. 61
11. 60
12.20
12.24
12.56
13.10
13.48
13.51
13.75
13.81
14.19
14.24
14.59
14.95
15.27
15.66
15.75
15.76
15.90
16.63
16.68
17.22
17.24
17.50
17.71
17.81
130
42
59
84
97
57
110
119
87
78
62
130
83
! 63
83
88
93
( 63
43
( 75
91
! 75
69
97
43
76
164
129
107
! 91
112
).31
91
! 91
91
104
j105
173
83
110
53
162043
48432
44226
612119
453099
1609428
188486
365906
129860
1454988
261960
362467
659224
328340
356310
23795
132280
54685
802473
470301
1435460
323737
222743
172210
492127
334013
275720
189463
152829
609170
808219
235202
1595161
2337833
1097629
827293
1445405
82959
167400
46132
46026
4.98 ug/l
5.01 ug/l
22.66 ug/l
4.91 ug/l
4.91 ug/l
4.89 ug/l
4.93 ug/l
4.90 ug/l
4.93 ug/l
4.88 ug/l
5.00 ug/l
4.92 ug/l
4.75 ug/l
4.89 ug/l
4.90 ug/l
91.18 ug/l
4.90 ug/l
4.52 ug/l
24.44 ug/l
4.96 ug/l
4.95 ug/l
4.96 ug/l
4.71 ug/l
5.00 ug/l
24.26 ug/l
4.93 ug/l
4.80 ug/l
4.96 ug/l
4.99 ug/l
4.92 ug/l
4.89 ug/l
4.85 ug/l
4.90 ug/l
9.92 ug/l
4.94 ug/l
4.86 ug/l
4.97 ug/l
4.71 ug/l
4.91 ug/l
5.03 ug/l
4.83 ug/l
Qvalue
99
99
100
100
99
100
99
99
98
100
100
99
100
99
100
90
99
98
100
98
100
98
98
98
100
100
98
100
100
100
99
99
99
100
100
99
100
99
100
99
94
(#) ~ qualifier out of range (m) ~ manual integration
RDC592.D V067D26.M Thu Apr 27 08:32:45 2023 SLA-f) Page 2
S\U~~ REPORT ID: 23E081 Page 110 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D
Aeq On 26 Apr 2023 10:28 am
Sample V067D265
Mise 5.0ppb 8260/25ppb KET-AA/125ppb
MS Integration Params: RTE.P
Vial: 6
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.RES
Quant Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
DataAeq Meth V067D26
Compound R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
80 ) n-Propylbenzene 17.81 r 91 1799590 4.98 ug/l 100
81) Bromobenzene 17.87 156 248380 4.88 ug/l 98
-,. 82) 1, 3, 5-Trimethylbenzene 18.03 < 105 1108860 4.92 ug/l 99
l' 83) 2-Chlorotoluene 18.04 91 1099892 4.72 ug/l 94
E.: 84) 4-Chlorotoluene 18.10 91 967525 5.06 ug/l 98
I J\~ 85) tert-Butylbenzene 18.48 ,134 239885 4.83 ug/l 99
;'Y 86) 1, 2, 4-Trimethylbenzene 18.53 105 1024778 4.90 ug/l 99
87) see-Butylbenzene 18.73 105 1492598 5.00 ug/l 100
88) p-Isopropyltoluene 18.89 ,119 1166660 4.98 ug/l 100
89) 1,3-Diehlorobenzene 18.99 J 146 491864 4.83 ug/l 100
90) 1,4-Diehlorobenzene 19.12 , 146 477927 4.82 ug/l 100
91) n-Butylbenzene 19.34 j 91 1098148 4.92 ug/l 100
92) 1,2-Diehlorobenzene 19.52 146 386200 4.82 ug/l 99
93) 1,2-Dibromo-3-ehloropropan 20.29 157 17524 5.00 ug/l 98
94) 1, 2, 4-Trichlorobenzene 21.16 180 164702 4.88 ug/l 99
95) Hexachlorobutadiene 21. 29 f25 144741 5.09 ug/l 99
96) Naphthalene 21. 43 128 201031 4.65 ug/l 100
97) 1, 2, 3-Trichlorobenzene 21.68 180 109128 4.73 ug/l 99
(#) = qualifier out of range (m) = manual integration
RDC592.D V067D26.M Thu Apr 27 08:32:46 2023 Page 3
REPORT ID: 23E081 Page 111 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D
Aeq On 26 Apr 2023 10:28 am
Sample V067D265
Mise 5.0ppb 8260/25ppb KET-AA/125ppb TBA
Vial: 6
Operator: VLu
67
1. 00
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.REE
Method
Title
Last Update
Response via
Fbundance
I 2700000
I
i 2600000 !
I
2500000
I
24000001
2300000
2200000
I
2100000
2000000
19000001
1800000
1700000
16000001
15000001
I
1400000
1300000
1200000
1100000
1000000
900000
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
ill z
~ w
II] o a: o
::J
...J
U. c
.0:
TIC: RDC592.D
RDC592.D V067D26.M Thu Apr 27 08:32:48 2023 Page 4
REPORT ID: 23E081 Page 112 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D
Acq On 26 Apr 2023 10:54 am
Sample V067D266
Vial: 7
Operator: VLu
Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
L
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
ASystem Monitoring Compounds
S 36) Dibromofluoromethane
;, Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.14 114
15.60 117
19.49 152
8.19 111
9.29 65
12.97 98
17.60 95
l. 86 85
2.12 50
62
94
64
67
101
56
151
43
/ 61
59
2.24
2.68
2.70
2.78
2.96
3.50
3.57
3.57
3.76
3.90
4.22
4.28
4.50
4.51
4.75
4.79
5.02 .(
5.70
5.87 J
5.93
6.63
6.91
7.20
7.30
7.68
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
2183075
1594928
498004
549869
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.57
0.00
0.00
0.00
0.00
Recovery =
ug/l
105.70%
ug/l
105.40%
ug/l
105.50%
ug/l
101.90%
418568 10.54 0.00
Recovery =
2339248 10.55 0.00
Recovery
685510 10.19 0.00
Recovery =
712543
1236990
1159967
706231
745429
1266643
831517
270299
484755
427094
1184682
597511
1075340
310956
2808995
949826
587834
1049753
818734
2396278
1318860
840033
1604908
148687
859400
778617
1064245
Qvalue
10.69 ug/l 100
10.69 ug/l 100
11.32 ug/l 100
11.17 ug/l 100
11.10 ug/l 100
9.97 ug/l 100
11.09 ug/l 100
52.87 ug/l 100
9.92 ug/l 100
48.78 ug/l 100
9.89 ug/l 100
248.42 ug/l 100
10.25 ug/l 100
10.93 ug/l 100
11.24 ug/l 100
9.36 ug/l 100
51.18 ug/l 100
10.07 ug/l 100
9.91 ug/l 100
9.93 ug/l 100
9.86 ug/l 100
10.98 ug/l 100
9.71 ug/l 100
51.06 ug/l 100
9.84 ug/l 100
9.93 ug/l 100
9.85 ug/l 100
(#) = qualifier out of range (m) = manual integration ~
RDC593.D V067D26.M Thu Apr 27 08,33,49 2023 ~;(~1'L3 Page 1
REPORT ID: 23E081 Page 113 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D
Acq On 26 Apr 2023 10:54 am
Sample V067D266
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 7
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. Qlon Response Conc Unit
33)
34)
35 )
37)
38 )
39 )
40)
41)
42)
(. 44)
'1 45)
L 46)
1< 47)
[; 48)
49)
50 )
51)
52)
53)
54)
57)
58)
59)
60 )
61 )
62)
63)
64)
65)
-66)
67 )
68 )
69)
70 )
71 )
72)
73)
75 )
76 )
78 )
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
1, 1, 1-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
l-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
l,l,2,2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05 130
8.14 42
8.16 59
8.56 84
8.57 97
8.73 57
8.92 110
9.10 119
9.23 87
9.47 178
9.48 '62
10.72 130
10.81 83
11. 09 63
11. 51 83
11. 61 88
11.60 93
12.20 63
12.24 43
12.56 '75
13.10 91
13.48 r75
13.51 69
13.75 97
13.80 43
14.18 76
14.24 164
14.59 129
14.94 107
15.27 1 91
15.66 112
15.75 131
15.76 ,91
15.89 91
16.62 / 91
16.70 104
17.22 ,lOS
17.24 173
17.50 83
17.72 110
17.82 53
320097
96277
105930
1341207
899465
3535233
370134
736778
265518
2879652
514964
715886
1502560
651346
708435
51291
262963
112087
1657314
934047
2834055
651825
463192
336276
1031522
664005
554751
379176
305749
1222980
1599480
469971
3172145
4676325
2193821
1681115
2868834
174720
342287
93970
95577
(#) = qualifier out of range (m) = manual integration
RDC593.D V067D26.M Thu Apr 27 08:33:49 2023
10.06
10.19
55.49
11.00
9.96
10.99
9.91
10.10
10.31
9.88
10.06
9.94
11.06
9.91
9.96
200.97
9.97
9.48
51.62
10.08
9.99
10.19
10.01
9.98
51.94
10.00
9.86
10.14
10.20
10.08
9.89
9.90
9.94
20.26
10.08
10.08
10.09
9.89
10.02
10.23
10.00
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
.. ~ /1 u':::!! .l-
ug/I
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Page 2
REPORT ID: 23E081 Page 114 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D
.Aeq On 26 Apr 2023 10:54 am
Sample V067D266
Mise 10ppb 8260/50ppb KET-AA/250ppb
1\18 Integration Params: RTE.P
Vial: 7
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RE8
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHOD8\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
80) n-Propylbenzene 17.81 91 3593925 9.93 ug/l
81 ) Bromobenzene 17.87 156 491974 9.65 ug/l
L 82) 1, 3, 5-Trimethylbenzene 18.03 105 2222578 9.84 ug/l
p 83) 2-Chlorotoluene 18.04 91 2204705 9.45 ug/l
;3 84) 4-Chlorotoluene 18.12 f 91 1946005 10.15 ug/l
IV 85) tert-Butylbenzene
c
ug/l 18.48 134 479676 9.64
!v' 86) l,2,4-Trimethylbenzene 18.52 105 2069453 9.88 ug/l
87) sec-Butylbenzene 18.73 105 3007044 10.05 ug/l
88 ) p-Isopropyltoluene 18.89 119 2380420 10.13 ug/l
89) l,3-Dichlorobenzene 18.99-146 1001061 9.81 ug/l
90) l,4-Dichlorobenzene 19.12, 146 968291 9.75 ug/l
91) n-Butylbenzene 19.34 91 2267089 10.13 ug/l
92) l,2-Dichlorobenzene 19.52 ! 146 789707 9.83 ug/l
93) l,2-Dibromo-3-chloropropan 20.29 157 35281 10.05 ug/l
94) l,2,4-Trichlorobenzene 21.15 I 180 344293 10.17 ug/l
95) Hexachlorobutadiene 21.29 225 288629 10.12 ug/l
96) Naphthalene 21.43 128 435685 10.05 ug/l
97) l,2,3-Trichlorobenzene 21.68 (; 180 231081 10.00 ug/l
:v'.
(#) = qualifier out of range (m) = manual integration
RDC593.D V067D26.M Thu Apr 27 08:33:50 2023
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Page 3
REPORT ID: 23E081 Page 115 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D
Aeq On 26 Apr 2023 10:54 am
Sample V067D266
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Vial: 7
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RE~
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration ~~=bu~n~dcan~re~~~~~=-~~==~~=-~~~~~~~TI~C~:~RD~C~5~9~3~.D~----------------------------~~
I 5400000
5200000
5000000
4800000
4600000
4400000
4200000
4000000
1
I
3800000
3600000
34000001
3200000j
3000000
2800000
2600000
2400000
22000001
20000001
1800000
RDC593.D V067D26.M Thu Apr 27 08:33:52 2023
REPORT ID: 23E081 Page 116 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC594.D Vial: 8
Operator: VLu Aeq On 26 Apr 2023 11:19 am
Sample V067D267 Inst 67
Mise 20ppb 8260/100ppb KET-AA/500ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev{Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
" System Monitoring Compounds
36) Dibromofluoromethane
I\ Spiked Amount 10.000
~ 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
C Spiked Amount 10.000
! 77) 4-Bromofluorobenzene
I Spiked Amount 10.000
R.
[Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
~ 14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
'-17) Methyl acetate
19) Carbon disulfide
J. 20) Methylene chloride
[.", 21) Acrylonitrile
, 22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.14
15.60
19.49
8.19
9.29
12.97
17.60
1. 85
2.11
2.23
2.68
2.70
2.80
2.96
3.50
3.57
3.59
3.76
3.90
4.23
4.28
4.50
4.53
4.75
4.79
5.02
5.68
5.87
5.93
6.63
6.91
7.20
7.30
7.68
114 2313292
117 1689543
152 523893
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
111
65
98
95
85
50
62
94
64
67
101
56
151
43
r 61
59
142
43
76
49
53
73
196
45
! 63
43
59
72
77
96
83
1148734 20.84 0.00
Recovery =
ug/l
208.40%
ug/l
202.60%
ug/l
210.10%
ug/l
201.10%
853012 20.26 0.00
Recovery
4934750 21.01 0.00
Recovery =
1422777 20.11 0.00
Recovery =
1349241
2274278
2118533
1356019
1413782
2765237
1593419
515978
1067186
811827
2706128
1259256
2365395
576730
5526915
2055047
1195133
2242473
1816916
5323252
2922672
1575021
3503474
301216
1910593
1742739
2376038
Qvalue
19.11 ug/l 99
18.55 ug/l 100
19.50 ug/l 100
20.24 ug/l 99
19.86 ug/l 98
20.55 ug/l 99
20.06 ug/l 99
95.23 ug/l 100
20.61 ug/l 99
87.50 ug/l 99
21.31 ug/l 98
494.08 ug/l 99
21.28 ug/l 99
19.12 ug/l 100
20.88 ug/l 100
19.12 ug/l 100
98.20 ug/l 100
20.29 ug/l 99
20.76 ug/l 99
20.82 ug/l 100
20.61 ug/l 100
19.43 ug/l 100
19.99 ug/l 100
97.61 ug/l 97
20.65 ug/l 99
20.98 ug/l 99
20.74 ug/l 99
(#) = qualifier out of range (m) = manual integration
RDC594.D V067D26.M Thu Apr 27 08:34:09 2023
3l~ 6\\\~ ~
Page 1
REPORT ID: 23E081 Page 117 of 489
Quantitation Report (QT Reviewed)
IJata File D: \HPCHEM\l \ DATA \23D2 6\RDC594 . D
Acq On 26 Apr 2023 11:19 am
Sample V067D267
Misc 20ppb 8260/100ppb KET-AA/500ppb
Ms Integration Params: RTE.P
Vial: 8
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33 )
34)
[ 35)
.4 37)
c 38)
['I 39)
Iv 40)
41)
42)
44)
45)
46)
47)
48)
49)
50 )
51)
52)
53)
54)
c 57)
J' 58)
>-59)
[>! 60)
. 61)
62)
63)
64)
65)
66)
67)
68)
69)
70 )
71)
72)
73)
75)
76)
78 )
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
1,1, I-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
1, 1, 2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2,2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05
8.14
8.15
8.56
8.57
8.74
8.93
9.10
9.25
9.47
9.48
10.72
10.81
11.07
11.51
11.60
1l. 60
12.18
12.24
12.56
13.10
13.48
13.51
13.75
13.81
14.19
14.24
14.59
14.95
15.27
15.66
15.75
15.76
15.89
16.63
16.68
17.22
17.24
17.50
17.71
17.82
130
42
59
84
97
57
110
119
87
I 78
62
130
83
63
83
88
93
63
43
l75
91
/ 75
. 69
97
43
76
164
129
107
i 91
112
131
~ 91
91
j 91
104
1105
( 173
83
110
53
697000
185899
203143
2671945
2013800
6723209
828786
1657531
569911
6491897
1111966
1601328
2938343
1461235
1580433
108441
579013
251741
3426179
2093936
6338070
1444510
1011489
736682
2115268
1441919
1256190
835856
659432
2784692
3599689
1069107
7200244
10566797
4992901
3854309
6551016
381403
720121
194394
207693
20.67 ug/l
18.58 ug/l
100.43 ug/l
20.68 ug/l
21.04 ug/l
19.72 ug/l
20.93 ug/l
21.43 ug/l
20.89 ug/l
21.02 ug/l
20.49 ug/l
20.98 ug/l
20.41 ug/l
20.98 ug/l
20.96 ug/l
400.99 ug/l
20.71 ug/l
20.10 ug/l
100.71 ug/l
21.33 ug/l
21.10 ug/l
2l. 32 ug/l
20.63 ug/l
20.64 ug/l
100.54 ug/l
20.50 ug/l
21.07 ug/l
21.11 ug/l
20.78 ug/l
21.67 ug/l
21.01 ug/l
21.26 ug/l
21.31 ug/l
43.22 ug/l
21.66 ug/l
21.82 ug/l
21.74 ug/l
20.52 ug/l
20.04 ug/l
20.11 ug/l
20.66 ug/l
(#) = qualifier out of range (m) = manual integration c VL-
RDC594.D V067D26.M Thu Apr 27 08:34:10 2023 ~
SI \{L ~
Qvalue
99
94
99
100
99
100
99
99
97
99
100
100
100
100
98
98
100
100
100
99
100
98
99
98
99
98
99
100
100
100
100
99
99
99
99
100
100
99
100
98
98
Page 2
REPORT ID: 23E081 Page 118 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC594.D
Acq On 26 Apr 2023 11:19 am
Sample V067D267
Mise 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
J.Jast Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
80) n-Propylbenzene 17.81 " 91 8206377 21. 55 ug/l
81) Bromobenzene 17.87 156 1107300 20.64 ug/l
82) l,3,5-Trimethylbenzene 18.03 105 5086762 21.41 ug/l
83) 2-Chlorotoluene 18.04 " 91 4981921 20.29 ug/l
84) 4-Chlorotoluene 18.12 91 4415406 21.90 ug/l
85 ) tert-Butylbenzene 18.48 ,134 1129382 21. 57 ug/l
86) l,2,4-Trimethylbenzene 18.52 105 4732673 21.48 ug/l
87) see-Butylbenzene 18.73 105 6908786 21.95 ug/l
88) p-Isopropyltoluene 18.89 /119 5531220 22.38 ug/l
1" 89) l,3-Diehlorobenzene 18.99 146 2260739 21. 06 ug/l
'1 90) l,4-Diehlorobenzene 19.12 ' 146 2199429 21. 06 ug/l , 91) n-Butylbenzene 19.34 91 5282308 22.44 ug/l ,-
R 92) l,2-Diehlorobenzene 19.52 146 1768829 20.93 ug/l
L 93) l,2-Dibromo-3-ehloropropan 20.29 157 75666 20.48 ug/l
94) l,2,4-Triehlorobenzene 21.15 < 180 818087 22.96 ug/l
95) Hexaehlorobutadiene 21. 29 225 708811 23.63 ug/l
96) Naphthalene 21.43 128 979015 21.46 ug/l
97) 1, 2, 3-Triehlorobenzene 21. 68 i 180 536519 22.06 ug/l
(#) = qualifier out of range (m) = manual integration ~~
RDC594.D V067D26.M Thu Apr 27 08:34:10 2023 5\\1~~
Qvalue
99
100
100
99
99
97
99
99
99
100
100
99
100
100
99
98
99
99
Page 3
REPORT ID: 23E081 Page 119 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC594.D
Aeq On 26 Apr 2023 11:19 am
Sample V067D267
Mise 20ppb 8260/100ppb KET-AA/500ppb TBA
Vial: 8
Operator: VLu
67
1. 00
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.REE
Method
Title
Last Update
Response via
r-~~;+'1ff
I 1.2e+071
I I 1.15e+07
1.1e+07
1.05e+07
1e+07
9500000
90000001
I
85000001
8000000
7500000 1
I
7000000
6500000
I
6000000i
i
55000001
5000000
4500000
4000000
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC594.D
(RTE Integrator)
RDC594.D V067D26.M Thu Apr 27 08:34:12 2023 Page 4
REPORT ID: 23E081 Page 120 of 489
Quantitation Report (QT Re"\ iewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D Vial: 9
Operator: VLu Acq On 26 Apr 2023 11:45 am
Sample V067D268 Inst 67
Misc 30ppb 8260/150ppb KET-AA/750ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
L
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-DS
74) 1,2-DICHLOROBENZENE-D4
TSystem Monitoring Compounds
;: 36) Dibromofluoromethane
j\ Spiked Amount 10 . 000
1 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
;-11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.14
15.60
19.49
8.19
9.29
12.97
17.60
1. 85
2.11
2.23
2.68
2.70
2.80
2.96
3.50
3.57
3.59
3.76
3.90
4.22
4.28
4.50
4.53
4.75
4.79
5.02
5.68
5.87
5.93
6.62
6.91
7.20
7.30
7.68
114 2178360
117 1613031
152 510627
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
111
65
98
95
85
50
62
94
64
67
101
56
151
43
( 61
59
142
43
76
49
53
73
, 96
45
/ 63
43
59
72
77
) 96
83
1646989 31.72 0.00
Recovery =
ug/l
317.20%
ug/l
312.50%
ug/l
311.80%
ug/l
297.80%
1238869 31.25 0.00
Recovery =
6993234 31.18 0.00
Recovery =
2054117 29.78 0.00
Recovery
1966056
3153506
2890583
1925272
2027647
3904639
2240764
798481
1498839
1240607
3664538
1891497
3367607
880577
7792094
2903974
1854931
3302559
2563175
7557565
4168222
2369936
5036871
469313
2670319
2469928
3332128
Qvalue
29.57 ug/l 99
27.32 ug/l 100
28.26 ug/l 99
30.52 ug/l 99
30.25 ug/l 98
30.81 ug/l 100
29.96 ug/l 100
156.51 ug/l 100
30.74 ug/l 100
142.00 ug/l 98
30.64 ug/l 100
788.11 ug/l 98
32.18 ug/l 98
31.01 ug/l 99
31.26 ug/l 100
28.69 ug/l 99
161.85 ug/l 100
31.74 ug/l 100
31.09 ug/l 100
31.40 ug/l 100
31.22 ug/l 100
31.05 ug/l 100
30.53 ug/l 99
161.50 ug/l 99
30.65 ug/l 99
31.58 ug/l 100
30.89 ug/l 99
(#) = qualifier out of range (m) = manual integration
RDC595.D V067D26.M Thu Apr 27 08:34:21 2023 Page 1
REPORT ID: 23E081 Page 121 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D
Acq On 26 Apr 2023 11:45 am
Sample V067D268
Misc 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
T.Jast Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33)
34)
35)
37)
38)
39)
40)
41)
42)
C 44)
] 45)
T 46)
F 47)
:c 48)
49)
50 )
51)
52)
53)
54)
57)
58 )
59)
60 )
61)
62)
63)
64)
65)
66)
.' 67)
68 )
69)
70 )
71)
72)
73)
75)
76)
78 )
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
1,1, I-Trichloroethane
2, 2, 4-Trimethylpentane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
1,2-Dichloroethane
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
Bromodichloromethane
1,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1,1,1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
1,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05
8.14
8.15
8.56
8.57
8.73
8.92
9.10
9.25
9.47
9.48
10.72
10.81
11.09
11.51
11.60
11. 60
12.20
12.24
12.56
13.10
13.48
13.51
13.75
13.80
14.18
14.24
14.59
14.94
15.27
15.66
15.75
15.76
15.89
16.62
16.70
17.22
17.24
17.50
17.72
17.82
130
42
59
84
97
57
110
119
87
78
62
130
183
63
83
88
93
{ 63
43
75
91
75
69
97
43
76
164
129
107
, 91
112
131
f 91
91
J 91
104
1105
173
83
110
53
1007709
284645
313446
3825113
2810323
9633568
1172883
2322163
838377
9151930
1602518
2261945
4255080
2081141
2286362
163153
843449
382549
5341866
3029966
8947797
2135172
1530549
1085630
3333993
2147241
1765847
1224191
979895
3918902
5140043
1518853
10184577
14593964
7024641
5513181
9182931
576063
1094854
292464
313590
31.74 ug/l
30.20 ug/l
164.56 ug/l
31.44 ug/l
31.18 ug/l
30.00 ug/l
31.46 ug/l
31.89 ug/l
32.64 ug/l
31. 48 ug/l
31. 36 ug/l
31. 47 ug/l
31. 39 ug/l
31.73 ug/l
32.21 ug/l
640.67 ug/l
32.04 ug/l
32.44 ug/l
166.75 ug/l
32.78 ug/l
31.19 ug/l
33.01 ug/l
32.70 ug/l
31.86 ug/l
165.99 ug/l
31.98 ug/l
31.02 ug/l
32.38 ug/l
32.34 ug/l
31.94 ug/l
31.42 ug/l
31.64 ug/l
31.57 ug/l
62.52 ug/l
31.92 ug/l
32.69 ug/l
31. 92 ug/l
31. 80 ug/l
31. 26 ug/l
31.04 ug/l
32.01 ug/l
(#) = qualifier out of range (m) = manual integration ~~~
RDC595.D V067D26.M Thu Apr 27 08:34:22 2023 ~~\\(~~
Qvalue
99
94
100
100
99
100
99
99
99
100
100
99
100
100
99
98
99
100
100
100
99
97
98
99
99
98
99
100
100
100
100
100
99
97
99
100
99
99
100
97
100
Page 2
REPORT ID: 23E081 Page 122 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D
Aeq On 26 Apr 2023 11:45 am
Sample V067D268
Mise 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
DataAeq Meth V067D26
Compound R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
80) n-Propylbenzene 17.81 c 91 11394667 30.70 ug/l 99
81) Bromobenzene 17.87 156 1609943 30.79 ug/l 100
"" 82) l,3,5-Trimethylbenzene 18.03 105 7105446 30.69 ug/l 99
r 83 ) 2-Chlorotoluene 18.04 ~ 91 7008404 29.29 ug/l 99
84) 4-Chlorotoluene 18.12 ( 91 6344012 32.28 ug/l 99
85) tert-Butylbenzene 18.48 134 1589453 31.14 ug/l 98
86) l,2,4-Trimethylbenzene 18.52 '105 6658044 31.00 ug/l 98
87) see-Butylbenzene 18.73 (105 9554084 31.14 ug/l 98
88) p-Isopropyltoluene 18.89 119 7711282 32.01 ug/l 99
89) l,3-Diehlorobenzene 18.99 )146 3255873 31.12 ug/l 100
90) l,4-Diehlorobenzene 19.12 146 3187777 31. 31 ug/l 99
91) n-Butylbenzene 19.34 91 7380811 32.18 ug/l 98
92) l,2-Diehlorobenzene 19.52 ( 146 2547568 30.92 ug/l 100
r 93) l,2-Dibromo-3-ehloropropan 20.29 157 119028 33.06 ug/l 98 L
94) l,2,4-Triehlorobenzene 21.15 (180 1184390 34.11 ug/l 100
95) Hexaehlorobutadiene 21.29 225 970237 33.18 ug/l 98
96) Naphthalene 21.43 128 1533466 34.49 ug/l 99
97) l,2,3-Triehlorobenzene 21.68 e180 801158 33.80 ug/l 99
L·
_______________________________________________________ ~_~~~-l[b:~-----
(#) = qualifier out of range (m) = manual integration
RDC595.D V067D26.M Thu Apr 27 08:34:22 2023 Page 3
REPORT ID: 23E081 Page 123 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D
Acq On 26 Apr 2023 11:45 am
Sample V067D268
Mise 30ppb 8260/150ppb KET-AA/750ppb TBA
Vial: 9
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
\Abundance
I I
1 I
I 1.7e+07:
, I
1.6e+07
1.5e+07
I
I
I
1.4e+07i
I
1.3e+07i
I
1.2e+07 i
1.1e+07
I
1e+07i
9000000 j
I
8000000i
i
70000001
6000000
50000001
I
400000011:.. ~
~~ . 3000000i~ ~ ~ 1-. I
o e
1~!5 Q) 'eI
::l 0
2000000 ~I ~
~~ ,
C I-
10000001
Time-->
~ \ i~\V1
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC595.D
:.
I-
U
RDC595.D V067D26.M Thu Apr 27 08:34:25 2023
REPORT ID: 23E081 Page 124 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D
Acq On 26 Apr 2023 1:53 pm
Sample V067D2611
Mise 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Vial: 14
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
fI 77) 4-Bromofluorobenzene
Spiked Amount 10.000
S=Target Compounds
2) Dichlorodifluoromethane
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
, 20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
34) Tetrahydrofuran
10.15
15.60
19.49
8.19
9.29
12.97
17.60
1. 85
2.70
2.70
2.80
2.96
3.50
3.59
3.59
3.78
3.90
4.23
4.28
4.50
4.53
4.76
4.80
5.02
5.70
5.89
5.94
6.63
6.91
7.20
7.32
7.68
8.06
8.14
114 2392742
117 1760980
152 535606
10.00 ug/l
10.00 ug/l
10.00 ug/l
111 2900655 50.87
Recovery =
65 2104879 48.34
Recovery =
98 12268379 50.10
Recovery =
95 3588641 49.60
Recovery
ug/l
508.70%
ug/l
483.40%
ug/l
501.00%
ug/l
496.00%
0.01
0.00
0.00
0.00
0.00
0.00
0.00
85
94
64
67
3482982
3420011
3620627
6775580
3884595
1292085
2623613
2081854
6346190
3367195
5851047
1447824
47.69
49.36
49.18
48.67
47.28
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
101
56
151
43
{ 61
59
142
43
76
49
53
73
; 96
45
63
43
59
72
77
196
83
130
42
13112496
5056338
3092098
5630027
4528322
13606758
7375748
4141325
8861822
775201
4693342
4357690
5939377
1732301
476829
230.56
48.99
216.94
48.31
1277.27
50.90
46.41
47.89
45.48
245.62
49.26
50.01
51.46
50.30
49.39
48.90
242.86
49.04
50.72
50.13
49.68
46.06
100
99
100
100
99
100
99
99
96
99
99
100
100
100
100
99
100
100
100
100
97
99
100
99
99
94
(#) = qualifier out of range (m) = manual integration
RDC600.D VQ67D26.M Thu Apr 27 08,37,00 2023 ~~l \ I 'L ~ Page 1 REPORT ID: 23E081 Page 125 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D
Acq On 26 Apr 2023 1:53 pm
Sample V067D2611
Misc 50ppb 8260/250ppb KET-AA/1250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
14
VLu
67
1. 00
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
35)
37 )
, 38)
i 39)
F: 40)
!V 41)
IV 42)
44)
45)
( 46)
47)
48)
49)
50)
51)
52)
53)
54)
57)
58)
59)
60 )
61)
[/ 62)
i' 63)
64)
65)
66)
67)
68)
69)
70 )
71)
72)
73)
75)
76 )
78)
79)
80)
81)
tert-Amyl alcohol
Cyclohexane
l,l,l-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
l,l,2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
8.15
8.57
8.57
8.75
8.92
9.10
9.25
9.48
9.49
10.72
10.81
11. 09
11.53
11.61
11.60
12.20
12.24
12.58
13.12
13.48
13.53
13.75
13.81
14.19
14.24
14.61
14.94
15.28
15.66
15.75
15.76
15.89
16.63
16.70
17.24
17.24
17.50
17.72
17.82
17.82 i
17.87
59
84
97
57
110
119
87
78
62
130
r 83
63
83
I 88
93
63
43
,I 75
91
175
69
97
43
76
164
129
107
91
112
131
t 91
91
91
104
'105
'173
83
110
53
91
156
521022
6677876
4947182
16559234
2087343
4043984
1437900
16117401
2697568
4011128
7403990
3714716
3987435
276573
1420546
652397
8786100
5267135
15579106
3657886
2565646
1828281
5525737
3591323
3125407
2107093
1637939
6957530
9052252
2704600
17606821
22616967
12282406
9676272
15752982
970937
1788706
467469
513667
18141805
2767400
249.02
49.97
49.97
46.95
50.97
50.55
50.96
50.46
48.07
50.80
49.73
51.57
51.13
988.74
49.13
50.36
249.69
51.87
49.75
51.80
50.20
49.15
252.00
48.99
50.30
51.05
49.51
51.95
50.69
51.61
49.99
88.76
51.13
52.55
50.16
51.10
48.69
47.31
49.99
46.60
50.45
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
(#) = qualifier out of range (m) = manual integration ~ ,
RDC600. D V067D26.M Thu Apr 27 08: 37: 01 2023 ~ Sl\r 1-~
Qvalue
99
100
100
100
100
99
98
100
100
100
99
99
98
100
99
99
99
98
94
98
99
98
99
99
99
100
99
99
100
97
87
98
99
98
99
100
97
100
94
100
Page 2
REPORT ID: 23E081 Page 126 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D
Aeq On 26 Apr 2023 1:53 pm
Sample V067D2611
Mise 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Vial: 14
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1,3,5-Trimethylbenzene 18.03 ~ 105 12371593 50.94 ug/l
83) 2-Chlorotoluene 18.04 ( 91 13026026 51.90 ug/l , 84) 4-Chlorotoluene 18.12 91 10149438 49.24 ug/l (
85) tert-Butylbenzene 18.48 134 2817710 52.63 ug/l
86) 1,2,4-Trimethylbenzene 18.52 105 11469914 50.92 ug/l ( 87) see-Butylbenzene 18.73 / 105 15675796 48.71 ug/l
88) p-Isopropyltoluene 18.89 119 13021893 51.53 ug/l
89) 1,3-Diehlorobenzene 19.01 '146 5611243 51.13 ug/l
90) 1,4-Diehlorobenzene 19.12 ! 146 5505209 51.55 ug/l
91) n-Butylbenzene 19.34 91 12631058 52.49 ug/l
92) 1,2-Diehlorobenzene 19.52 r 146 4353984 50.38 ug/l
I 93) 1,2-Dibromo-3-ehloropropan 20.29 157 186296 49.33 ug/l
1", 94) 1, 2, 4-Triehlorobenzene 21.15 180 2024051 55.57 ug/l
r-95) Hexaehlorobutadiene 21.29 (225 1623597 52.93 ug/l
96) Naphthalene 21.43 128 2445901 52.44 ug/l
97) 1,2,3-Triehlorobenzene 21.70 /180 1303865 52.45 ug/l
(#) = qualifier out of range (m) = manual integration
RDC600.D V067D26.M Thu Apr 27 08:37:01 2023
Qvalue
97
97
91
97
96
95
97
99
100
96
99
100
99
99
100
99
Page 3
REPORT ID: 23E081 Page 127 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D
Acq On 26 Apr 2023 1:53 pm
Sample V067D2611
Mise 50ppb 8260/250ppb KET-AA/1250ppb TBA
Vial: 14
Operator: VLu
67
1. 00
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration "fA.=bu~n-;Cda=n~ce~=-=--"':'=~~~=-=-:=-=-:==-~==~~=--=--:T,:r.IC""'-:""R"""DC7"l6""'O,..-O . ....-D-------------~~---~--~
I 2.ge+07
I 2.Se+07
2.7e+07
2.6e+07
I
2.5e+07j
2.4e+07
2.3e+07
2.2e+07
2.1e+07
2e+07
1.ge+07
1.Se+07
1.7e+071
I
1.6e+07
1.5e+07
1.4e+07
1.3e+07
1.2e+07
1.1e+07i
I
1e+07
9000000
SOOOOOO
RDC600.D V067D26.M Thu Apr 27 08:37:03 2023 Page 4
REPORT ID: 23E081 Page 128 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D
Acq On 26 Apr 2023 12:36 pm
Sample V067D2610
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
11
VLu
67
1. 00
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
l'Bystem Monitoring Compounds
~ 36) Dibromofluoromethane
r,· Spiked Amount 10.000
t 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
-12) l,l,2-Trichloro-1,2,2-trif
F 13) Acetone
", 14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
34) Tetrahydrofuran
R.T. QIon Response Conc Units Dev(Min)
10.14 114
15.60 117
19.49 152
2218346
1621442
489219
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.19 111 5687718 107.58 ug/l 0.00
Recovery = 1075.80%
9.29 65 4209713 104.28 ug/l 0.00
Recovery = 1042.80%
12.97 98 22439298 . 99.53 ug/l 0.00
Recovery 995.30%
17.60 95 6943214 105.07 ug/l 0.00
1. 86
2.68
2.68
2.80
2.94
3.50
3.57
3.59
3.78
3.90
4.23
4.28
4.50
4.53
4.75
4.79
5.02
5.70
5.87
5.93
6.63
6.91
7.20
7.30
7.70
8.05
8.14
85
94
64
67
101
56
151
43
J 61
59
142
43
76
49
53
73
J 96
45
/' 63
43
59
72
77
i 96
83
130
42
Recovery = 1050.70%
7148921
6506436
6864386
12173030
7579620
2623298
4822505
4217193
11726310
7026050
10893696
3341481
27227003
9529711
6558753
11171836
8448775
24916021
13532297
8936706
16624327
1630275
8130641
8166691
10841613
3381083
1004639
105.59 ug/l
101.29 ug/l
100.57 ug/l
94.32 ug/l
99.51 ug/l
504.91 ug/l
97.12 ug/l
474.00 ug/l
96.29 ug/l
2874.69 ug/l
102.22 ug/l
115.54 ug/l
107.26 ug/l
92.46 ug/l
561.96 ug/l
105.43 ug/l
100.65 ug/l
101.64 ug/l
99.53 ug/l
114.96 ug/l
98.94 ug/l
550.90 ug/l
91.64 ug/l
102.53 ug/l
98.70 ug/l
104.58 ug/l
104.68 ug/l
Qvalue
100
100
100
100
99
100
100
99
99
96
98
100
100
99
99
100
99
99
100
100
98
92
99
100
100
100
93
(#) = qualifier out of range (m) = manual integration
RDC597.D V067D26.M Thu Apr 27 08:35:30 2023 Page 1
REPORT ID: 23E081 Page 129 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D
Acq On 26 Apr 2023 12:36 pm
Sample V067D2610
Misc 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: VLu
67
1. 00
Inst
Multiplr:
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
37)
38)
39)
40 )
41)
42)
44)
45)
46)
" 47)
.c 48)
J 49)
J< 50)
n 51)
52)
53)
54)
57)
58)
59)
60 )
61)
62)
63)
64)
65)
66)
67)
68 )
71)
72)
75)
76 )
78)
79)
81 )
83)
84)
85)
89)
90 )
Cyclohexane
1, 1, 1-Trichloroethane
2, 2, 4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromornethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochlorornethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
o-Xylene
Styrene
Bromoform
l,l,2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
Bromobenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
l,3-Dichlorobenzene
l,4-Dichlorobenzene
8.57
8.59
8.76
8.92
9.10
9.25
9.48
9.49
10.72
10.81
11.09
11.53
11.61
11.60
12.20
12.24
12.58
13.12
13.48
13.53
13.75
13.80
14.18
14.24
14.61
14.94
15.28
15.66
15.76
16.62
16.70
17.24
17.52
17.72
17.82
17.87
18.06
18.12
18.48
19.01
19.12
84
97
57
110
119
87
; 78
62
130
83
63
83
88
93
63
43
-< 75
91
/ 75
69
97
43
76
164
129
,107
91
112
131
E 91
104
1173
83
110
53
156
i 91
/ 91
I 134
i 146
146
i
13820806
8960822
34879949
3870800
7447609
2804930
28710378
5092236
7430308
15200565
6950021
7452403
573456
2824566
1377114
18223250
9970305
25126652
7074433
5240131
3614516
11535362
7101247
5759426
4087295
3269981
12634172
16183907
4980490
20770066
17202235
1974484
3507231
950690
1000722
5155221
19868173
16426557
5019910
9843138
9759302
111.54
97.63
106.67
101.94
100.42
107.22
96.96
97.87
101.50
110.11
104.07
103.08
2211.26
105.36
114.67
558.60
105.90
87.15
108.81
111. 36
105.53
571. 33
105.21
100.66
107.55
107.35
102.45
98.42
103.22
93.90
101. 46
113.77
104.53
105.33
106.62
102.89
86.66
87.25
102.65
98.19
100.05
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
100
100
99
99
98
98
100
99
99
98
99
100
99
100
98
98
89
95
96
99
96
99
99
99
100
98
98
100
93
99
99
99
97
99
100
95
83
95
97
98
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration ~~
RDC597.D V067D26.M Thu Apr 27 08:35:31 2023 ~(\I~~ Page 2
REPORT ID: 23E081 Page 130 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D
Aeq On 26 Apr 2023 12:36 pm
Sample V067D2610
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: VLu
67
1. 00
Inst
Multiplr:
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
92) l,2-Diehlorobenzene 19.52 ( 146 7780726 98.57 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.29 /157 377536 109.45 ug/l 99
r 94) l,2,4-Triehlorobenzene 21.15 180 3637705 109.35 ug/l 100 L ,. 95) Hexachlorobutadiene 21.29 225 2764705 98.68 ug/l 99 l-
e: 96) Naphthalene 21. 43 I 128 4947529 116.14 ug/l 100 ,-
fV 97) l,2,3-Trichlorobenzene 21.69 180 2462569 108.45 ug/l 99
t,;
(#) = qualifier out of range (m) = manual integration
RDC597.D V067D26.M Thu Apr 27 08:35:31 2023 Page 3
REPORT ID: 23E081 Page 131 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D
Aeq On 26 Apr 2023 12:36 pm
Sample V067D2610
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
Vial: 11
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
~bundance
i I
! I
4.6e+07j
I
4.4e+07j
4.2e+07j
I
4e+07j
I
3.8e+071
3.6e+07
3.4e+07
3.2e+07
3e+07
2.8e+07j
I
2.6e+07j
2.4e+07
2.2e+07
2e+07
1.8e+07
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC597.D
(RTE Integrator)
RDC597.D V067D26.M Thu Apr 27 08:35:33 2023 Page 4
REPORT ID: 23E081 Page 132 of 489
SECOND SOURCE
VERIFICATION
REPORT ID: 23E081 Page 133 of 489
CONTINUE_CALIBRATION -CALIBRATION VERIFICATION
Instrument ID :67
IC Beginning DateTime :04/26/23 08:46
SpIke Amount :10 PPB
CC/CV File :RDC603
IC File :RDC593
M lOX Parameters
======= =====================================
1 1,4-DIFLUOROBENZENE
2 Dichlorodifluoromethane
3 Dichlorotetrafluoroethane
4 Chloromethane
5 vinyl chloride
6 Bromomethane
7 Chloroethane
8 Dichlorofluoromethane
9 Trichlorof1uoromethane
10 sec-Propyl alcohol
5 11 Acrolein
12 1,1,2-Trichloro-1,2,2-trifluoroethane
5 13 Acetone
14 1,1-Dichloroethene
25 15 tert-Butyl alcohol
16 Iodomethane
17 Methyl acetate
10 18 Acetonitrile
19 Carbon disulfide
20 Methylene chloride
5 21 Acrylonitrile
22 tert-Butyl methyl ether (MTBE)
23 trans-1,2-Dichloroethene
24 Isopropyl ether (DIPE)
25 1,1-Dichloroethane
26 Vinyl acetate
25 27 2-Butanol
28 tert-Butyl ethyl ether (ETBE)
5 29 2-Butanone
30 2,2-Dichloropropane
31 cis-1,2-Dichloroethene
32 Chloroform
33 Bromochloromethane
34 Tetrahydrofuran
5 35 tert-Amyl alcohol
36 Dibromofluoromethane
37 Cyclohexane
38 1,1,1-Trichloroethane
39 2,2,4-Trimethylpentane
40 1,1-Dichloropropene
41 Carbon tetrachloride
42 tert-Amyl methyl ether (TAME)
43 1,2-Dichloroethane-d4
44 Benzene
45 1,2-Dichloroethane
46 Trichloroethene
47 Methylcyclohexane
48 1,2-Dichloropropane
49 Bromodichloromethane
20 50 1,4-0ioxane
51 Dibromomethane
52 2-Chloroethyl vinyl ether
5 53 4-Methyl-2-pentanone
54 cis-1,3-Dichloropropene
55 CHLOROBENZENE-D5
56 Toluene-d8
57 Toluene
58 trans-1,3-Dichloropropene
59 Ethyl methacrylate
60 1,1,2-Trichloroethane
5 61 2-Hexanone
62 1,3-Dichloropropane
63 Tetrachloroethene
64 Dibromochloromethane
65 1,2-Dibromoethane
66 1-Chlorohexane
67 Chlorobenzene
68 1,l,l,2-Tetrachloroethane
69 Ethylbenzene
2 70 m-XYlene & p-Xylene
71 o-Xylene
72 Styrene
73 Isopropylbenzene
74 1,2-DICHLOROBENZENE-D4
75 Bromoform
76 l,l,2,2-Tetrachloroethane
77 4-Bromofluorobenzene
78 1,2,3-Trichloropropane
79 trans-1,4-Dichloro-2-butene
80 n-Propylbenzene
81 Bromobenzene
82 1,3,5-Trimethylbenzene
83 2-Chlorotoluene
84 4-Chlorotoluene
85 tert-Butylbenzene
86 1,2,4-Trimethylbenzene
87 sec-Butylbenzene
88 p-Isopropyltoluene
89 1,3-Dichlorobenzene
90 1,4-Dichlorobenzene
91 n-Butylbenzene
92 1,2-Dichlorobenzene
93 1,2-Dibromo-3-chloropropane
94 1,2,4-Trichlorobenzene
95 Hexachlorobutadiene
96 Naphthalene
97 1,2,3-Trichlorobenzene
Sp1ke Amount -Nom1nal Amount * M
CC_Con CC%_D CC_Resp CCRRF AvRRF CC_Rtm AvRtm
======= ===== ======== ===== ===== ===::;;:::;;::;: ======
10.000 0 2362609 1 1 10.137 10.142
8.355 -16.5 602546 0.255 0.305 1.859 1.853
8.364 -16.4 1047257 0.443 0.530 2.120 2.117
9.567 -4.3 1061415 0.449 0.470 2.241 2.237
9.077 -9.2 621052 0.263 0.290 2.682 2.681
10.613 6.1 771458 0.327 0.308 2.703 2.697
10.848 8.5 1491252 0.631 0.582 2.803 2.791
10.313 3.1 836620 0.354 0.343 2.964 2.958
9.140 -8.6 483393 0.205 0.224 3.573 3.577
44.470 -11.1 421380 0.036 0.040 3.594 3.591
9.052 -9.5 1174074 0.497 0.549 3.757 3.763
216.581 -13.4 563773 0.010 0.011 3.900 3.913
10.097 1.0 1146131 0.485 0.480 4.234 4.230
8.939 -10.6 275356 0.117 0.130 4.278 4.281
10.350 3.5 2798378 1.184 1.144 4.497 4.499
8.697 -13.0 954677 0.404 0.465 4.512 4.525
45.742 -8.5 568595 0.048 0.053 4.745 4.754
9.221 -7.8 1040725 0.440 0.478 4.789 4.799
9.400 -6.0 840464 0.356 0.378 5.023 5.025
9.775 -2.3 2552049 1.080 1.105 5.681 5.693
9.681 -3.2 1401840 0.593 0.613 5.871 5.877
10.136 1.4 839174 0.355 0.350 5.929 5.937
9.090 -9.1 1626697 0.689 0.757 6.616 6.631
45.054 -9.9 142000 0.012 0.013 6.893 6.910
9.558 -4.4 903274 0.382 0.400 7.200 7.199
9.232 -7.7 783244 0.332 0.359 7.302 7.306
9.530 -4.7 1114949 0.472 0.495 7.682 7.686
8.969 -10.3 308840 0.131 0.146 8.048 8.053
9.330 -6.7 95373 0.040 0.043 8.135 8.138
46.906 -6.2 96904 0.008 0.009 8.150 8.165
10.498 5.0 591137 0.250 0.238 8.179 8.194
10.251 2.5 1352848 0.573 0.559 8.559 8.565
9.746 -2.5 952763 0.403 0.414 8.574 8.579
10.788 7.9 3756893 1.590 1.474 8.734 8.740
9.439 -5.6 381740 0.162 0.171 8.924 8.925
9.691 -3.1 765503 0.324 0.334 9.100 9.102
9.323 -6.8 259776 0.110 0.118 9.231 9.248
10.029 0.3 431239 0.183 0.182 9.290 9.290
9.614 -3.9 3032099 1. 283 1.335 9.465 9.468
9.344 -6.6 517837 0.219 0.235 9.479 9.487
9.596 -4.0 748188 0.317 0.330 10.722 10.724
10.454 4,5 1537065 0.651 0.622 10.809 10.810
9.531 -4.7 677918 0.287 0.301 11.087 11.085
9.267 -7.3 713603 0.302 0.326 11.525 11.520
173.816 -13 .1 48008 0.001 0.001 11.598 11.612
8.782 -12.2 250739 0.106 0.121 11.598 11.601
48.815 -2.4 1696055 0.144 0.147 12.241 12.246
9.616 -3.8 964227 0.408 0.424 12.563 12.569
10.000 0 1712570 1 1 15.602 15.602
10.697 7.0 2547480 1. 488 1.390 12.972 12.972
9.536 -4.6 2904335 1.696 1. 778 13.103 13.108
9.730 -2.7 668253 0.390 0.401 13.483 13.487
9.324 -6.8 463423 0.271 0.290 13.527 13.520
8.998 -10.0 325542 0.190 0.211 13.746 13.747
47.546 -4.9 1013935 0.118 0.125 13.804 13.809
9.058 -9.4 645730 0.377 0.416 14.184 14.188
9.568 -4.3 578274 0.338 0.353 14.243 14.243
9.061 -9.4 363699 0.212 0.234 14.608 14.601
8.877 -11. 2 285612 0.167 0.188 14.944 14.946
9.686 -3.1 1261704 0.737 0.761 15.280 15.272
9.380 -6.2 1629224 0.951 1.014 15.660 15.662
9.299 -7.0 473934 0.277 0.298 15.748 15.750
9.563 -4.4 3275548 1.913 2.000 15.762 15.763
19.853 -0.7 4920075 1.436 1.447 15.894 15.895
9.931 -0.7 2320095 1.355 1.364 16.625 16.625
9.810 -1.9 1756894 1. 026 1.046 16.698 16.695
9.372 -6.3 2862494 1.671 1. 783 17.238 17.228
10.000 0 534462 1 1 19.488 19.489
9.036 -9.6 171323 0.321 0.355 17.238 17.239
8.778 -12.2 321780 0.602 0.686 17.501 17.506
10.308 3.1 744145 1.392 1. 351 17.603 17.604
8.447 -15.5 83296 0.156 0.184 17.720 17.717
10.273 2.7 105347 0.197 0.192 17.823 17.822
9.704 -3.0 3769938 7.054 7.269 17.823 17.813
8.980 -10.2 491529 0.920 1.024 17.866 17.867
9.433 -5.7 2286111 4.277 4.534 18.027 18.028
9.262 -7.4 2320026 4.341 4.686 18.042 18.045
8.731 -12.7 1795993 3.360 3.849 18.115 18.114
9.693 -3.1 517870 0.969 1.000 18.480 18.481
9.659 -3.4 2171469 4.063 4.206 18.524 18.525
9.872 -1. 3 3170170 5.932 6.008 18.729 18.731
9.764 -2.4 2462340 4.607 4.718 18.889 18.890
9.192 -8.1 1006744 1. 884 2.049 19.006 19.001
9.047 -9.5 964079 1.804 1.994 19.123 19.124
9.963 -0.4 2392370 4.476 4.492 19.342 19.343
8.973 -10.3 773778 1.448 1.613 19.517 19.518
8.725 -12.7 32882 0.062 0.071 20.306 20.293
10.354 3.5 376327 0.704 0.680 21.154 21.156 I 9.625 -3.8 294610 0.551 0.573 21.285 21. 286
9.051 -9.5 421247 0.788 0.871 21.432 21. 434
9.959 -0.4 247062 0.462 0.464 21.695 21.688
--.-----------. ---
Column Spec :RTX502.2 ID :0.25MM
IC Ending DateTime :04/26/23 13:53
HPChem Method :V067D26
Date_Time :04/26/23 15:39
%_RSD cO_XO Co_Xl Co_X2 co_Cor
-----======= ======= ======= ======
0
5.66
9.57
8.00
5.68
6.63
4.77
6.58
3.75
14.65
4.80
6.45
6.34
8.01
7.27
9.90
8.95
5.25
3.80
5.08
4.26
9.85
5.33
6.91
4.81
5.58
3.69
6.20
4.96
9.29
8.45
9.25
4.92
7.68
5.48
6.91
7.89
5.46
4.46
5.01
5.21
8.11
7.04
5.74
6.36
6.59
9.02
8.11
0
6.69
6.30
9.38
8.35
6.90
9.36
5.77
4.74
7.11
8.26
6.75
4.93
5.81
5.46
6.45
6.33
7.51
7.40
0
7.64
5.07
3.39
5.75
5.86
5.54
3.78
4.94
7.12
7.90
5.78
5.24
6.06
8.13
3.31
4.18
8.74
3.04
9.29
11.99
11.91
11.97
9.14
--------------------
REPORT ID: 23E081 Page 134 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Acq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
Mul tiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
25 P,T,M l,l-Dichloroethane
2€i T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
~9 T,M 2-Butanone
30 T,M 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
~3 T,M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
37 T,M Cyclohexane
~8 T,M l,l,l-Trichloroethane
39 T,M 2,2,4-Trimethylpentane
4Q T,M l,l-Dichloropropene
41 T,M Carbon tetrachloride
Amount Calc.
10.000 10.000
10.000 8.356
-1.000 0.000
10.000 8.364
10.000 9.567
10.000 9.078
10.000 10.613
10.000 10.849
10.000 10.313
-1.000 0.000
50.000 0.000
10.000 9.141
50.000 44.470
10.000 9.052
250.000 216.582
10.000 10.098
10.000 8.940
-1.000 0.000
10.000 10.351
10.000 8.697
50.000 45.743
10.000 9.221
10.000 9.401
10.000 9.775
10.000 9.681
10.000 10.136
-1.000 0.000
10.000 9.090
50.000 45.054
10.000 9.559
10.000 9.233
10.000 9.531
10.000 8.969
10.000 9.331
50.000 46.906
10.000 10.499
10.000 10.252
10.000 9.747
10.000 10.788
10.000 9.440
10.000 9.692
%Dev Area% Dev(min)
0.0
16.4
0.0
16.4
4.3
9.2
-6.1
-8.5
-3.1
0.0
100.0#
8.6
11.1
9.5
13.4
-1. 0
10.6
0.0
-3.5
13.0
8.5
7.8
6.0
2.2
3.2
-1. 4
0.0
9.1
9.9
4.4
7.7
4.7
10.3
6.7
6.2
-5.0
-2.5
2.5
-7.9
5.6
3.1
108
85
o
85
92
88
103
118
101
o
o
100
99
99
94
107
89
o
100
101
97
99
103
107
106
100
o
101
96
105
101
105
96
99
91
108
101
106
106
103
104
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.00
-3.50#
0.00
0.02
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
~,~------------------------------------------------------------------------
::~\#) = Out of Range
~RDC603.D V067D26.M Thu Apr 27 08: 37: 21 2023 3 L.A-5" { \ (2.-3 Page 1
REPORT ID: 23E081 Page 135 of 489
Evaluate Continuing Calibration Report
) ,~, Data File D: \HPCHEM\l \ DATA \23D26\RDC603. D
., Acq On 26 Apr 2023 3: 39 pm
'\ '. :' \:' Sample IV067D2601
,; j Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
. -MS Integration Params: RTE. P
Vial: 17
Operator: VLu
Inst 67
Mul tiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Min. RRF
"1 '" Max. RRF Dev
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
, --------------------------------------------------------------------------
4<2 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
4iJ: T,M Benzene
45 T,M l,2-Dichloroethane
~~ T,M Trichloroethene
47 T,M Methylcyclohexane
~B C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
50 T,M l,4-Dioxane
51 T,M Dibromomethane
52 T,M 2-Chloroethyl vinyl ether
53 T,M 4-Methyl-2-pentanone
$4 T,M cis-1,3-Dichloropropene
5S I CHLOROBENZENE-D5
56 S Toluene-dB
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
5g T,M Ethyl methacrylate eo T,M l,l,2-Trichloroethane
~j T,M 2-Hexanone
9~ T,M l,3-Dichloropropane
6J T,M Tetrachloroethene
~4' T,M Dibromochloromethane
&5 T,M l,2-Dibromoethane
66 T,M 1-Chlorohexane
67 P,M Chlorobenzene
68 T,M l,l,l,2-Tetrachloroethane
69 C,T,M Ethylbenzene
~O T,M m-Xylene & p-Xylene
jl T,M o-Xylene
72 T,M Styrene
'3 T,M Isopropylbenzene
~4 I l,2-DICHLOROBENZENE-D4
15 P,T,M Bromoform
~@ P,T,M l,l,2,2-Tetrachloroethane
~1 S 4-Bromofluorobenzene
"flfl T, M 1,2,3 -Trichloropropane
f~ T,M trans-l,4-Dichloro-2-butene
~O T,M n-Propylbenzene ;:.. .;..-
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.324
10.030
9.615
9.345
9.597
10.455
9.531
9.268
173.816
8.782
0.000
48.815
9.617
10.000
10.698
9.537
9.731
9.324
8.998
47.547
9.058
9.569
9.061
8.878
9.687
9.380
9.300
9.564
19.854
9.931
9.811
9.373
10.000
9.036
8.778
10.308
8.447
10.274
9.704
6.8
-0.3
3.8
6.5
4.0
-4.6
4.7
7.3
13.1
12.2
100.0#
2.4
3.8
0.0
-7.0
4.6
2.7
6.8
10.0
4.9
9.4
4.3
9.4
11.2
3.1
6.2
7.0
4.4
0.7
0.7
1.9
6.3
0.0
9.6
12.2
-3.1
15.5
-2.7
3.0
98
103
105
101
105
102
104
101
94
95
o
102
103
107
109
102
103
100
97
98
97
104
96
93
103
102
101
103
105
106
105
100
107
98
94
109
89
110
105
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
-0.01
0.00
-12.20#
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
~~------------------------------------------------------------------------
6Z#) = Out of Range
CRDC603.D V067D26.M
t
Thu Apr 27 08: 37 :22 2023 ~?\\ ( 1--~ Page 2
REPORT ID: 23E081 Page 136 of 489
t
l.f
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Acq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
Multiplr: 1. 00
Method
't4; Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
'J") Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
"~J Compound Amount Calc. %Dev Area% Dev(min)
81 T,M . Bromobenzene 10.000 8.980 10.2 100 0.00
.82 T,M l,3,5-Trimethylbenzene 10.000 9.433 5.7 103 0.00
83 T,M 2-Chlorotoluene 10.000 9.263 7.4 105 0.00
84 T,M 4-Chlorotoluene 10.000 8.731 12.7 92 0.00
~85 T,M tert-Butylbenzene 10.000 9.693 3.1 108 0.00
'86 T,M l,2,4-Trimethylbenzene 10.000 9.660 3.4 105 0.00
R7 T,M sec-Butylbenzene 10.000 9.873 1.3 105 0.00
'88 T,M p-Isopropyltoluene 10.000 9.764 2.4 103 0.00
89 T,M l,3-Dichlorobenzene 10.000 9.192 8.1 101 0.01
-SO T,M l,4-Dichlorobenzene 10.000 9.047 9.5 100 0.00
'9~ T,M n-Butylbenzene 10.000 9.964 0.4 106 0.00
BQ T,M l,2-Dichlorobenzene 10.000 8.973 10.3 98 0.00
'93 T,M l,2-Dibromo-3-chloropropane 10.000 8.726 12.7 93 0.01
:9~ T,M l,2,4-Trichlorobenzene 10.000 10.355 -3.6 109 0.00
8.5 T,M Hexachlorobutadiene 10.000 9.625 3.8 102 0.00
:9Ei T,M Naphthalene 10.000 9.051 9.5 97 0.00
97 T,M 1, 2, 3-Trichlorobenzene 10.000 9.959 0.4 107 0.01
3
E
:...... ~ tA-r--'j \ [ ; ~~ L S
~-----------------------------------------------------------------------
.:( #) = Out of Range
:RDC603.D V067D26.M
SPCC's out = 0 CCC's out = 0
Thu Apr 27 08:37:22 2023 Page 3
REPORT ID: 23E081 Page 137 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
_'r~ Acq On 26 Apr 2023 3: 39 pm
Sample IV067D2601
.. , ," Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
[--------------------------------------------------------------------------
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
A P, T, M Chloromethane
: 5 C, T, M Vinyl chloride
:,6 T, M Bromomethane
:7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-l,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
2f T,M Acrylonitrile
2~ T,M tert-Butyl methyl ether (MT
2~ T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
2~ P,T,M l,l-Dichloroethane
2~ T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
29 T,M 2-Butanone
Jo T,M 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
32 C,T/M Chloroform
33 T,M Bromochloromethane
14 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
::l6 S Dibromofluoromethane
::l1 T,M Cyclohexane
~~ T,M l,l,l-Trichloroethane
19 T,M 2,2,4-Trimethylpentane
4~ T,M l,l-Dichloropropene
~F T,M Carbon tetrachloride
1.000 1.000
0.305 0.255
0.000 0.000
0.530(" 0.443
0.470 0.449
0.290 0.263
0.308 0.327
0.582 0.631
0.343 0.354
0.000 0.000
0.023 0.000
0.224 0.205
0.040 .0.036
0.549 0.497
0.011 0.010
0.480 0.485
0.130 0.117
0.000 0.000
1.144 1.184
0.465 0.404
0.053 0.048
0.478 0.440
0.378 0.356
1.105 1.080
0.613 / 0.593
0.350 0.355
0.000 0.000
0.757 0.689
0.013 r 0.012
0.400 0.382
0.359 0.332
0.495 0.472
0.146 0.131
0.043 0.040
0.009 0.008
0.238 0.250
0.559 0.573
0.414 0.403
1. 474 1. 590
0.171 0.162
0.334 0.324
0.0
16.4
0.0
16.4
4.5
9.3
-6.2
-8.4
-3.2
0.0
100.0#
8.5
10.0
9.5
9.1
-1. 0
10.0
0.0
-3.5
13.1
9.4
7.9
5.8
2.3
3.3
-1. 4
0.0
9.0
7.7
4.5
7.5
4.6
10.3
7.0
11.1
-5.0
-2.5
2.7
-7.9
5.3
3.0
108
85
0#
85
92
88
103
118
101
0#
0#
100
99
99
94
107
89
0#
100
101
97
99
103
107
106
100
0#
101
96
105
101
105
96
99
91
108
101
106
106
103
104
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.00
-3.50#
0.00
0.02
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
;~------------------------------------------------------------------------
L~#) = Out of Range
<~'RDC603 . D V067D26. M Thu Apr 27 08:37:27 2023 ~t,I/L~ Page 1
REPORT ID: 23E081 Page 138 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Acq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
67
1. 00
Inst
Multiplr:
-" _.1.': Method
L Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
'{:o Response via
.3"; Min. RRF
Max. RRF Dev
Compound
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
AvgRF
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min) J •. ___________________ ~ _____________________________________________________ _
4,2 T,M tert-Amyl methyl ether (TAM 0.118 0.110
43 S l,2-Dichloroethane-d4 0.182 0.183
44 T,M Benzene 1. 335 1.283
45 T,M l,2-Dichloroethane 0.235 0.219
!46 T,M Trichloroethene 0.330 0.317
47 T,M Methylcyclohexane 0.622 0.651
48 C,T,M l,2-Dichloropropane 0.301 0.287
49 T,M Bromodichloromethane 0.326 0.302
-SO T,M l,4-Dioxane 0.001 0.001
5:1 T,M Dibromomethane 0.121 0.106
5'2 T,M 2-Chloroethyl vinyl ether 0.054 0.000
.$3 T,M 4-Methyl-2-pentanone 0.147 <,0.144
154 T,M cis-1,3-Dichloropropene 0.424 0.408
:; },
E~5 I CHLOROBENZENE-D5 1.000 1.000
-5,6 S Toluene-d8 1. 390 1.488
5-7 C,T,M Toluene 1.778 1.696
58 T,M trans-1,3-Dichloropropene 0.401 0.390
~§ T,M Ethyl methacrylate 0.290 0.271
60 T,M l,l,2-Trichloroethane 0.211 0.190
~1 T,M 2-Hexanone 0.125 / 0.118
52 T,M l,3-Dichloropropane 0.416 0.377
63 T,M Tetrachloroethene 0.353 0.338
64 T,M Dibromochloromethane 0.234 0.212
65 T,M l,2-Dibromoethane 0.188 0.167
66 T,M 1-Chlorohexane 0.761 0.737
&7 P,M Chlorobenzene 1.014 0.951 ea T,M 1, 1, l,2-Tetrachloroethane 0.298 /' 0.277
~)9 C,T,M Ethylbenzene 2.000 1.913
7:0 T,M m-Xylene & p-Xylene 1.447 1.436 ;H T,M o-Xylene 1. 364 1.355
72 T,M Styrene 1.046 1.026
"7'~
Sf
T,M Isopropylbenzene 1. 783 1.671
'"b4 I l,2-DICHLOROBENZENE-D4 1.000 1.000
'$§ P,T,M Bromoform 0.355 ( 0.321
~6 P,T,M l,l,2,2-Tetrachloroethane 0.686 / 0.602
.fj,7 S 4-Bromofluorobenzene 1. 351 1. 392
18 T,M l,2,3-Trichloropropane 0.184 0.156
~9 T,M trans-1,4-Dichloro-2-butene 0.192 0.197
S:o T,M n-Propylbenzene 7.269 7.054
':" (#) = Out of Range
6RDC603.D V067D26.M Thu Apr 27 08:37:30 2023
6.8 98 0.00
-0.5 103 0.00
3.9 105 0.00
6.8 101 0.00
3.9 105 0.00
-4.7 102 0.00
4.7 104 0.00
7.4 101 0.01
0.0 94 -0.01
12.4 95 0.00
100.0# 0# -12.20#
2.0 102 0.00
3.8 103 0.00
0.0 107 0.00
-7.1 109 0.00
4.6 102 0.00
2.7 103 0.00
6.6 100 0.01
10.0 97 0.00
5.6 98 0.00
9.4 97 0.00
4.2 104 0.00
9.4 96 0.01
11.2 93 0.00
3.2 103 0.01
6.2 102 0.00
7.0 101 0.00
4.3 103 0.00
0.8 105 0.00
0.7 106 0.00
1.9 105 0.00
6.3 100 0.01
0.0 107 0.00
9.6 98 0.00
12.2 94 0.00
-3.0 109 0.00
15.2 89 0.00
-2.6 110 0.00
3.0 105 0.01
Page 2
REPORT ID: 23E081 Page 139 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Aeq On 26 Apr 2023 3:39 pm
Vial: 17
Operator: VLu
Sample IV067D2601 Inst 67
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
'f::} Title
'$~\ Last Update
1($ Response via
,~,;
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000
20%
Min. ReI. Area
Max. ReI. Area
50%
200%
Max. R.T. Dev 0.16min
Compound AvgRF CCRF %Dev Area% Dev(min)
81 T,M
'B2 T,M
,83 T,M
'84 T,M :g(j:) T,M
13'6 T,M
"8:7 T,M
'8-8 T,M
89 T,M
'9'b T,M
94. T,M
"S@ T,M
'93 T,M
'94 T,M
'95 T,M
'96 T,M
97 T,M
''8'£3
85;
;;, t;
Bromobenzene
1 ,3 ,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1 ,2 ,4-Trimethylbenzene
see-Butylbenzene
p-Isopropyltoluene
1 ,3-Diehlorobenzene
1 ,4-Diehlorobenzene
n-Butylbenzene
1 ,2-Diehlorobenzene
1 ,2-Dibromo-3-ehloropropane
1 ,2 ,4-Triehlorobenzene
Hexaehlorobutadiene
Naphthalene
1 ,2 ,3-Triehlorobenzene
1.024
4.534
4.686
3.849
1.000
4.206
6.008
4.718
2.049
1.994
4.492
1.613
0.071
0.680
0.573
0.871
0.464
0.920
4.277
4.341
3.360
0.969
4.063
5.932
4.607
1.884
1.804
4.476
1. 448
0.062
0.704
0.551
0.788
0.462
10.2
5.7
7.4
12.7
3.1
3.4
1.3
2.4
8.1
9.5
0.4
10.2
12.7
-3.5
3.8
9.S
0.4
100 0.00
103 0.00
105 0.00
92 0.00
108 0.00
105 0.00
105 0.00
103 0.00
101 0.01
100 0.00
106 0.00
98 0.00
93 0.01
109 0.00
102 0.00
97 0.00
107 0.01
~} ~ t~ 51J (2-~~----------------------------------------------------~ ---~-----------
01#) = Out of Range
0RDC603.D V067D26.M
SPCC's out = 0 CCC's out = 0
Thu Apr 27 08:37:32 2023 Page 3
REPORT ID: 23E081 Page 140 of 489
Quantitation Report (QT Reviewed)
;' Data File D: \HPCHEM\l \DATA\23D26\RDC603.D Vial: 17
Operator: VLu .' A~q On 26 Apr 2023 3: 39 pm
":Sample IV067D2601 Inst 67
rMisc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
,~ MS Integration Params: RTE. P
, Quant Time: Apr 26 16:09 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
,Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
, 1) 1,4-DIFLUOROBENZENE
" 55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
'J'System Monitoring Compounds
;;~ 36) Dibromofluoromethane
I Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
[Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
/ 12) 1,1,2-Trichloro-1,2,2-trif
,,~. 13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
10.14
15.60
19.49
8.18
9.29
12.97
17.60
1. 86
2.12
2.24
2.68
2.70
2.80
2.96
3.57
3.59
3.76
3.90
4.23
4.28
4.50
4.51
4.75
4.79
5.02
5.68
5.87
5.93
6.62
6.89
7.20
7.30 ,7
7.68
8.05
114 2362609
117 1712570
152 534462
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
111
65
98
95
85
50
62
94
64
67
101
151
43
(' 61
59
142
43
76
49
53
73
/ 96
45
~ 63
43
59
72
77
96
83
130
591137 10.50
Recovery
431239 10.03
Recovery =
2547480 10.70
Recovery =
744145 10.31
Recovery =
602546
1047257
1061415
621052
771458
1491252
836620
483393
421380
1174074
563773
1146131
275356
2798378
954677
568595
1040725
840464
2552049
1401840
839174
1626697
142000
903274
783244
1114949
308840
8.36
8.36
9.57
9.08
10.61
10.85
10.31
9.14
44.47
9.05
216.58
10.10
8.94
10.35
8.70
45.74
9.22
9.40
9.78
9.68
10.14
9.09
45.05
9.56
9.23
9.53
8.97
ug/l -0.01
105.00%
ug/l 0.00
100.30%
ug/l 0.00
107.00%
ug/l 0.00
103.10%
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
99
99
100
99
98
99
100
100
98
98
100
100
99
100
100
99
100
99
100
100
98
100
98
99
99
99
99
(#) = qualifier out of range (m) = manual integration ~ f/..--.
RDC603.D V067D26.M Thu Apr 27 08:37:39 2023 5(\l~3 Page 1
REPORT ID: 23E081 Page 141 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Acq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 16:09 2023 Quant Results File: V067D26.RES
. Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
I..Jast Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. Qlon Response Cone Unit
34) Tetrahydrofuran
35) tert-Amyl alcohol
37) Cyclohexane
38) l,l,l-Trichloroethane
39) 2,2,4-Trimethylpentane
40) l,l-Dichloropropene
l 41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
~ 45) l,2-Dichloroethane
1 46) Trichloroethene
I 47) Methylcyclohexane
R 48) l,2-Dichloropropane
L 49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
! 67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.14 42
8.15 59
8.56 84
8.57 97
8.73 57
8.92 110
9.10 119
9.23 87
9.46 78
/ 9.48 62
/'
10.72 130
10.81 83
1l. 09 63
1l. 53 <: 83
1l. 60 88
11. 60 93
12.24 43
12.56 ,-75
13.10 91
13.48 75
13.53 ( 69
13.75 97
13.80 43
14.18 76
14.24 164
14.61 129
14.94/107
15.28 / 91
15.66 112
15.75 r 131
15.76" 91
15.89 I 91
16.62 I 91
16.70 I 104
17.24 /105
17. 24 ~ 73
17.50 83
17.72 110
17.82 53
(' 17.82 { 91
17.87 156
95373
96904
1352848
952763
3756893
381740
765503
259776
3032099
517837
748188
1537065
677918
713603
48008
250739
1696055
964227
2904335
668253
463423
325542
1013935
645730
578274
363699
285612
1261704
1629224
473934
3275548
4920075
2320095
1756894
2862494
171323
321780
83296
105347
3769938
491529
9.33 ug/l
46.91 ug/l
10.25 ug/l
9.75 ug/l
10.79 ug/l
9.44 ug/l
9.69 ug/l
9.32 ug/l
9.61 ug/l
9.34 ug/l
9.60 ug/l
10.45 ug/l
9.53 ug/l
9.27 ug/l
173.82 ug/l
8.78 ug/l
48.81 ug/l
9.62 ug/l
9.54 ug/l
9.73 ug/l
9.32 ug/l
9.00 ug/l
47.55 ug/l
9.06 ug/l
9.57 ug/l
9.06 ug/l
8.88 ug/l
9.69 ug/l
9.38 ug/l
9.30 ug/l
9.56 ug/l
19.85 ug/l
9.93 ug/l
9.81 ug/l
9.37 ug/l
9.04 ug/l
8.78 ug/l
8.45 ug/l
10.27 ug/l
9.70 ug/l
8.98 ug/l
Qvalue
97
100
100
100
100
99
100
98
100
100
100
100
99
99
100
99
98
99
100
99
99
99
100
98
99
98
99
99
100
99
100
99
100
100
100
98
100
99
100
100
100
. (#) = qualifier out of range (m) = manual integration ~ ~.
RDC603.D V067D26.M Thu Apr 27 08:37:39 2023 5' (\11-3 Page 2
REPORT ID: 23E081 Page 142 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Aeq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 16:09 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1, 3, 5-Trimethylbenzene 18.03 r 105 2286111 9.43 ug/l
83) 2-Chlorotoluene 18.04 < 91 2320026 9.26 ug/l
L 84) 4-Chlorotoluene 18.11 91 1795993 8.73 ug/l
;. 85) tert-Butylbenzene 18.48 " 134 517870 9.69 ug/l
~. 86) 1, 2, 4-Trimethylbenzene 18.52 , 105 2171469 9.66 ug/l
IV 87) see-Butylbenzene 18.73· 105 3170170 9.87 ug/l
r'" 88) p-Isopropyltoluene 18.89 I 119 2462340 9.76 ug/l
89) 1,3-Diehlorobenzene 19.011146 1006744 9.19 ug/l
90 ) 1,4-Diehlorobenzene 19.12'146 964079 9.05 ug/l
91) n-Butylbenzene 19.34 91 2392370 9.96 ug/l
92) 1,2-Diehlorobenzene 19.52 I 146 773778 8.97 ug/l
93) 1,2-Dibromo-3-ehloropropan 20.31 157 32882 8.73 ug/l
94) 1,2,4-Triehlorobenzene 21.15 I 180 376327 10.35 ug/l
95) Hexaehlorobutadiene 21. 29 225 294610 9.63 ug/l
96) Naphthalene 21.43 128 421247 9.05 ug/l
97) 1, 2, 3-Trichlorobenzene 21.69~ 180 247062 9.96 ug/l
Qvalue
100
94
94
97
100
100
100
99
100
100
100
97
99
99
99
99
. C~ --------------------------------------------------------~---------------51\t~~ .. (#) = qualifier out of range (m) = manual integration
RDC603.D V067D26.M Thu Apr 27 08:37:40 2023 Page 3
REPORT ID: 23E081 Page 143 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Aeq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: Apr 26 16:09 2023
Vial: 17
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Results File: V067D26.REE
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Initial Calibration
r
bundance
: 7500000
TIC: RDC603.D
I
7000000j
I
65000°°1
000000°1
5500000
5000000
4500000 1
4000000
tQme--> 2.00 3.00 4.005.00 6.00 7.bo 8.bo' 9. 0 10.00 11.00 12:0013.00 14.00 15.00 16.00 17.00 18:00 19:00 20.00 21~00
RDC603.D V067D26.M Thu Apr 27 08,37,42 2023 ?5!\I1-~ Page 4
REPORT ID: 23E081 Page 144 of 489
DAILY CALIBRATIONS
REPORT ID: 23E081 Page 145 of 489
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BRQMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratories, Inc.
Lab Code : EMAX
Lab File ID: REC286
Instrument ID: 67
Project : TEAD·5
SDG No : 23E081
BFB Injection Date: 05/12/23
BFB Injection Time: 06:12
I I % RELATIVE I
I mle I ION ABUNDANCE CRITERIA ABUNDANCE I
1=1 I
I 50 I 15 -40% of mass 95 20.545 I
I 75 I 30 -60% of mass 95 I 46.286 I
I 95 I Base Peak, 100% relative abundance __ 1 100.000 I
I 96 I 5 -9% of mass 95 I 6.697 I
I 173 I Less than 2% of mass 174 I 0.000(0)1 I
I 174 I Greater than 50% of mass 95 I 68.580 I
I 175 I 5 -9% of mass 174 I 5.182(7.56)1 I
I 176 I 95 -101% % of mass 174 168.594(100.02)1 I
I 177 I 5 -9% % of mass 176 I 4.460(6.5)2 I
I_I I I
I-Value is % mass 174 2-Value is % mass 176
This check applies to the following samples, Lab QCs and Standards:
I EPA I LAB I LAB DATE I TIME I
I 5AMPLE NO. I 5AMPLE ID I FILE ID ANALYZED I ANALYZED I
1======1====1======1===
11V5TDI0 ICV067D2613 IREC287 05/12/23 I 06:45
21 LC51W I V067E14L I REC288 05/12123 I 07: 10
31 LCDIW I V067E14C I REC289 05112123 I 07: 36
41MBLK1W IV067E14B IREC291 05/12/23 I 08:27
5ITB-20230503-1/25 I 23E081-13 IREC292 05/12123 I 08:53
615WMU-1/25-EB-052023 I 23E081-12 IREC293 05/12/23 I 09:18
7IS-68-90-052023 I 23E081-06 IREC294 05/12/23 I 09:44
815-70-90-052023 I 23E081-07 IREC295 05/12/23 I 10:10
915-67-90-052023 I 23E081-05 IREC296 05/12/23 I 10:35
1015-95-92-052023 I 23E081-10 IREC297 05/12/23 I 11:01
1115-71-90-052023 1 23E081-08 !REC298 05/12/23 I 11:26
1215-129-15-052023 I 23E081-01 IREC299 05/12/23 I 11:52
1315-93-92-052023 I 23E081-09 IREC300 I 05/12/23 I 12:18
1415-97-92-052023 123E081-11 IREC301 I 05/12/23 I 12:43
1515-137-16-052023 123E081-02 IREC302 I 05/12/23 I 13:09
1615-138-16-052023 123E081-03 IREC303 I 05/12/23 I 13:35
1715-141-17-052023 I 23E081-04 IREC304 I 05/12/23 I 14:01
1815-68-90-052023M5 I 23E081-06M IREC305 I 05/12/23 I 14:26
19 I 5-68-90-052023M5D I 23E081-06S IREC306 I 05/12/23 I 14:52
20 I 5-70-90-052023MS I 23E081-0lM IREC307 I 05/12/23 I 15:18
21IS-70-90-052023M5D I 23E081-075 IREC308 I 05/12/23 I 15:44
221V5TDI0 I EV067D2613 IREC314 I 05/12/23 I 18:18
I I I I 1 __ _
REPORT ID: 23E081 Page 146 of 489
FORM 8
VOLATILE INTERNAL STANDARD MEA AND RETENTION TIME SUMMAAY
Lab Name: EMAX Laboratories. Inc.
Lab Code: EMAX
Lab File ID: RDC593
Instrument ID: 67
Project: TEAD·S
SDG No: 23E081
Date Analyzed: 04/26/23
Time Analyzed: 10:54
I INTERNAL STANDARD (IS) 1.4·DIFLUDR08ENZENE I CHLOR08ENZENE-D5 I 1.2·DICHLOROBENZENE-D4 I
I Area #1 RT#I Area #1 RT#I Area #1 RT#I
1====== I I I I I I
I 12 HOUR STD 2183075 I 10. 14 I 1594928 I 15. 60 498004 I 19.49 I
I UPPER LIMIT 4366150 I 10.31 I 3189856 I 15.77 996008 I 19.66 I
I LOWER LIMIT 1091538 I 9.973 I 797464 I 15.43 249002 I 19.32 I
1======= =====1====1====1==== ====1====1
I Area #1 RT#I Area #1 RT# Area #1 RT#I
I I I I I I
11 VSTD10 2211620 I 10.15 I 15912B3 I 15.60 479790 I 19.49 I
21 LCS1W 1972534 I 10.15 I 1423507 I 15.60 430893 I 19.49 I
31 LCD1W 2068294 I 10.15 I 1493633 I 15.60 455653 I 19.49 I
41 MBLK1W 2368690 I 10.15 I 1664623 I 15.60 430496 I 19.49 I
5ITB·20230503-1/25 2288364 I 10.15 I 1564372 I 15.60 397292 I 19.49 I
6ISWMU-1/25·EB-052023 2189072 I 10.15 I 1531394 I 15.60 398608 I 19.49 I
7IS-68-90-052023 2248656 I 10.15 I 1589229 I 15.60 417832 I 19.49 I
8IS-70-90-052023 2269522 I 10.15 I 1616394 I 15.60 423946 19.49 I
9IS-67-90-052023 232013B I 10.15 I 1668037 I 15.60 457213 19.49
10IS-95-92-052023 2249275 I 10.15 I 1594253 I 15.60 419648 19.49
11IS-71-90·052023 2274035 I 10.15 I 1606209 I 15.60 I 419409 19.49
12IS-129-15-052023 2253215 I 10.15 I 1583027 I 15.60 I 413332 19.49
13IS·93·92·052023 2180398 I 10.15 I 1545804 I 15.60 I 403791 19.49
14IS-97·92-052023 2252915 I 10.15 I 1590411 I 15.60 I 425725 19.49
15IS-137·16·052023 2178620 I 10.15 I 1546348 I 15.60 I 417334 19.49
16IS-138·16·052023 2154178 I 10.15 I 1546551 I 15.60 I 404558 19.49
17IS-141·17·052023 2187995 I 10.15 I 1558341 I 15.60 I 408427 19.49
18IS-68-90-052023MS 2085257 I 10.15 I 1568156 I 15.60 I 509933 19.49
19I5-68-90-052023MSD 2048523 I 10.15 I 1547600 I 15.60 I 504431 19.49
20 I S-70-90·052023MS 1985715 I 10.15 I 1506756 I 15.60 I 484613 I 19.49
21 I S-70-90·052023MSD 2122993 I 10.15 I 157990B I 15.60 I 501699 I 19.49
22 I VSTD10 2102126 I 10.15 I 1537164 I 15.60 I 485155 I 19.49
1 ____________ 1 ____ 1 _____ 1 ____ 1 _____ 1 ___ _
Area Upper Limit = +100% of ICAL Midpoint IS Area
Area Lower Limit = ·50% of ICAL Midpoint IS Area
Retention Time(RT) Upper Limit = +10 seconds of ICAL Midpoint IS RT
Retention Time(RT) Lower Limit = -10 seconds of ICAL Midpoint IS RT
REPORT ID: 23E081 Page 147 of 489
BFB
Data File D:\HPCHEM\1\DATA\23E12\REC286.D Vial: 1
Acq On 12 May 2023 6:12 am Operator: VLu
Sample BFB67E14
Misc T/CHK
~~:rnst : 67
Multiplr: 1.00
MS Integration Params: RTE.P
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title : METHOD 8260B
.~bundance
50000,
I
400001
I
I
300001
20000
ime-->
f'\bU~ 95 1
40000
35000
i
300001
25000'
20000!
I
15000j
1
10000j 50
176
75
5000; I 68 ! ! ' '
I I, 57 62 1·1 ' I 81 88 I' ~ 40 45 III ,II I III" II iii I '
JTl/Z--> ~O 35 4'0415 \b 5151 616 '6'5 170 'jlJ '8'd '859b9~' 100 1051'10 1151'20 125130 135140 1451~0 155160 1~65170 175 H301~85
AutoFind: Scans 1041, 1042, 1043; Background Corrected with Scan 1036
I Target I ReI. to I Lower I Mass Mass Limit% I Upper I
Limit%
ReI.
Abn%
Raw
Abn I Result I
Pass/Fail
----------------------------------------------------------------------
50 95 15 40 20.5 rA 8900 PASS
75 95 30 60 46.3/ 20051 PASS
95 95 100 100 100.0 43320 PASS
96 95 5 9 6.7 2901 PASS
173 174 0.00 2 0.0/ 0 PASS
174 95 50 100 68.6; 29709 PASS
175 174 5 9 7.6 / 2245 PASS
176 174 95 101 ./ 100.0 / 29715 PASS
177 176 5 9 6.5 i 1932 PASS
REC286.D V067D26.M Mon May 15 08:14:02 2023
REPORT ID: 23E081 Page 148 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC287.D
Acq On 12 May 2023 6:45 am
Sample CV067D2613
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000
20%
Min. Rel. Area
Max. Rel. Area
50%
200%
~ Max. R.T. Dev 0.16min
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M 1,1,2-Trichloro-1,2,2-trifl
13 T,M Acetone
Amount Calc.
10.000 10.000
10.000 11.461
-1.000 0.000
10.000 9.725
10.000 10.959 ./
10.000 11.647
10.000 11.620
10.000 11.110
10.000 11.628
-1.000 0.000
50.000 40.595
10.000 10.868
50.000 55.237
%Dev Area% Dev(min)
0.0
-14.6
0.0
2.8
-9.6
-16.5
-16.2
-11.1
-16.3
0.0
18.8
-8.7
-10.5
101
109
o
92
98
106
106
113
106
0.01
0.02
0.00
0.04
0.02
0.00
0.02
0.00
0.02
0.00
0.03
0.02
0.02
14 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
10.000 10.887 / -8.9
o
78
111
115
112
95
109
0.02
0.02
0.01
0.01
0.01
0.03
0.03
0.02
0.01
0.01
0.00
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
25 P,T,M 1,1-Dichloroethane
26 T,M Vinyl acetate
27 T,M 2-Butanol
18 T,M tert-Butyl ethyl ether (ETB
29 T,M 2-Butanone
30 T,M 2,2-Dichloropropane
II T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
33 T,M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
37 T,M Cyclohexane
~8 T,M 1,1,1-Trichloroethane
~9 T,M 2,2,4-Trimethylpentane
40 T,M 1,1-Dichloropropene
41 T,M Carbon tetrachloride
250.000 233.585
10.000 10.997
10.000 10.653
-1.000 0.000
10.000 11.069
10.000 10.054
50.000 49.592
10.000 10.629
10.000 10.794
10.000 11.061
10.000 10.887
10.000 11.080
-1.000 0.000
10.000 10.351
50.000 50.361
10.000 11.902
10.000 10.860
10.000 11.087
10.000 10.523
10.000 8.677
50.000 0.000
10.000 10.852
10.000 11.364
10.000 11.106
10.000 0.000
10.000 10.037
10.000 10.917
(#) = Out of Range
<REC287.D V067D26.M Mon May 15 08:14:18 2023
6.6
-10.0
-6.5
0.0
-10.7
-0.5
0.8
-6.3
-7.9
-10.6
-8.9
-10.8
0.0
-3.5
-0.7
-19.0
-8.6
/ -10.9
. -5.2
13.2
100.0#
-8.5
-13.6
-11.1
100.0#
-0.4
-9.2
99
o
100
109
98
107
110
113
112
102
o
108
100
123
111
114
106
86
o
104
105
113
o
103
110
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.02
-8.16#
0.00
0.01
0.01
-8.73#
0.00
0.01
Page 1
REPORT ID: 23E081 Page 149 of 489
Evaluate Continuing Calibration Report
~. (, Data File D:\HPCHEM\1\DATA\23E12\REC287.D Vial: 2
Acq On 12 May 2023 6:45 am Operator: VLu
Sample CV067D2613 Inst 67
--\ Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1. 00 -,
-\ ~ .. MS Integration
Method
Title
Last Update
Response via
Params: RTE.P
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 TIM tert-Amyl methyl ether (TAM
43 S 1 /2-Dichloroethane-d4
44 TIM Benzene
45 T,M l,2-Dichloroethane
4~ T,M Trichloroethene
47 T,M Methylcyclohexane
4'8 C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
50 T,M l,4-Dioxane
51 T,M Dibromomethane
52 T,M 2-Chloroethyl vinyl ether
53 T,M 4-Methyl-2-pentanone
54 T,M cis-l,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-l,3-Dichloropropene
59 T,M Ethyl methacrylate
60 T,M l,l,2-Trichloroethane
61 T,M 2-Hexanone
6~ T,M 1 /3-Dichloropropane
63 T,M Tetrachloroethene
64 T,M Dibromochloromethane
65 T,M l,2-Dibromoethane
68 T,M l-Chlorohexane
61 P,M Chlorobenzene
68 T,M l,l,l,2-Tetrachloroethane
69 C,T,M Ethylbenzene
70 T,M m-Xylene & p-Xylene
71 T,M o-Xylene
72 T,M Styrene
~3 T,M Isopropylbenzene
?4 I l,2-DICHLOROBENZENE-D4
75 P,T,M Bromoform
'6 P,T,M 1,1,2,2-Tetrachloroethane
VV S 4-Bromofluorobenzene
V8 T,M 1,2,3-Trichloropropane
~9 T,M trans-l,4-Dichloro-2-butene
SO T,M n-Propylbenzene
Amount Calc.
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.433
10.390
10.729
10.167
10.287
11.193
10.487
10.698
196.060
10.128
2.062
46.786
10.605
10.000 10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.941
11.025
10.568
8.602
10.721
48.429
10.434
11.066
10.198
10.267
10.863
10.665
11.471
10.977
22.445
11.340
9.738
11.384
10.000
9.738
10.679
10.447
10.199
10.075
11.539
3t#) = Out of Range
~~EC287.D V067D26.M Mon May 15 08:14:18 2023
%Dev Area% Dev(min)
/
-4.3
-3.9
-7.3
-1. 7
-2.9
-11.9
-4.9
-7.0
2.0
-1.3
79.4#
6.4
-6.1
102
100
110
102
105
103
107
109
99
103
22
92
107
0.0 100
-9.4
-10.3
/ -5.7
14.0
-7.2
3.1
-4.3
-10.7
-2.0
-2.7
-8.6
-6.6
-14.7
-9.8
-12.2
-13.4
2.6
-13.8
0.0
2.6
-6.8
-4.5
-2.0
-0.7
-15.4
103
110
103
86
107
93
104
112
100
100
107
108
116
110
111
112
96
113
96
95
103
99
96
97
112
0.03
0.00
0.01
0.01
0.01
0.02
0.00
0.01
0.00
0.02
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.02
0.00
0.00
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.02
0.01
0.00
0.00
0.00
0.01
Page 2
REPORT ID: 23E081 Page 150 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC287.D
Acq On 12 May 2021 n:4S am
Vial: 2
Operator: VLu
Sample CV067D2613 Inst 67
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
-je Title
:: ;« Last Update
'; Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
.,;j ~:.; Min. RRF
~~ /,0 Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
81 T,M Bromobenzene 10.000 10.846 -8.5
82 T,M 1 /3,5-Trimethylbenzene 10.000 11.309 -13.1
83 T,M 2-Chlorotoluene 10.000 10.620 -6.2
84 T,M 4-Chlorotoluene 10.000 10.536 -5.4
85 T,M tert-Butylbenzene 10.000 11.677 -16.8
86 T,M 1, 2, 4-Trimethylbenzene 10.000 11.193 -11.9
"87 T,M sec-Butylbenzene 10.000 11.955 -19.6
88 T,M p-Isopropyltoluene 10.000 11.525 -15.3
89 T,M 1 /3-Dichlorobenzene 10.000 10.787 -7.9
90 T,M 1 /4-Dichlorobenzene 10.000 10.702 -7.0
9'1 T,M n-Butylbenzene 10.000 11.069 -10.7
92 T,M 1,2-Dichlorobenzene 10.000 10.622 -6.2
93 T,M 1,2-Dibromo-3-chloropropane 10.000 9.661 3.4
94 T,M 1, 2, 4-Trichlorobenzene 10.000 10.871 -8.7
95 T,M Hexachlorobutadiene 10.000 11.477 -14.8
·n·'-T, fJI Naphthalene 10.000 8.958 10.4 :;;10
97 T,M 1,2,3-Trichlorobenzene 10.000 10.051 -0.5
B~
,.
¥
t~~
~
(#) = Out of Range
REC287.D V067D26.M
SPCC's out = 0 CCC's out = 0
Mon May 15 08:14:19 2023
108 0.00
111 0.02
108 0.01
100 0.00
117 0.00
109 0.00
115 0.01
110 0.01
106 0.01
106 0.00
105 0.00
104 0.00
93 0.01
103 0.01
109 0.00
86 0.01
97 0.01
Page 3
REPORT ID: 23E081 Page 151 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC287.D
Acq On 12 May 2023 6:45 am
Sample CV067D2613
,~, Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
2] T,M Acrylonitrile
2z T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
2~ P,T,M l,l-Dichloroethane
2g T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
29 T,M 2-Butanone
30 T,M 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
33 T,M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
37 T,M Cyclohexane
38 T,M l,l,l-Trichloroethane
j~ T,M 2,2,4-Trimethylpentane
40 T,M l,l-Dichloropropene
41 T,M Carbon tetrachloride
AvgRF CCRF
1.000 1.000
0.305 0.350
0.000 0.000
0.530/0.515
0.470 0.515
0.290 0.337
0.308 0.357
0.582 0.646
0.343 0.399
0.000 0.000
0.023 0.019
0.224 0.243
0.040 0.044
0.549 0.598
0.011 0.010
0.480
0.130
0.000
1.144
0.465
0.053
0.478
0.378
1.105
0.613
0.350
0.000
0.757
0.013
0.400
0.359
0.495
0.146
0.043
0.009
0.238
0.559
0.414
1.474
0.171
0.334
0.528
0.139
0.000
1.267
0.467
0.052
0.508
0.408
1.222
/"0.667
0.388
0.000
0.784
0.013
0.476
0.390
0.549
0.153
0.038
0.000
0.259
0.635
0.459
0.000
0.172
0.365
%Dev Area% Dev(min)
0.0
-14.8
0.0
2.8
-9.6
-16.2
-15.9
-11.0
-16.3
0.0
17.4
-8.5
-10.0
-8.9
9.1
-10.0
-6.9
0.0
-10.8
-0.4
1.9
-6.3
-7.9
-10.6
-8.8
-10.9
0.0
-3.6
0.0
-19.0
-8.6
-10.9
-4.8
11. 6
100.0#
-8.8
-13.6
-10.9
100.0#
-0.6
-9.3
101
109
0#
92
98
106
106
113
106
0#
78
III
115
112
95
109
99
0#
100
109
98
107
110
113
112
102
0#
108
100
123
III
114
106
86
0#
104
105
113
0#
103
110
0.01
0.02
0.00
0.04
0.02
0.00
0.02
0.00
0.02
0.00
0.03
0.02
0.02
0.02
0.02
0.01
0.01
0.01
0.03
0.03
0.02
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.02
-8.16#
0.00
0.01
0.01
-8.73#
0.00
0.01
2'---------------------------------------------_______ ----_______________ _
2~#) = Out of Range
2~EC287.D V067D26.M Mon May 15 08:14:22 2023 Page 1
REPORT ID: 23E081 Page 152 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC287.D
Acq On 12 May 2023 6:45 am
Sample CV067D2613
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1. 00
.:':
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. ReI. Area
~~. Max. RRF Dev 20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M tert-Amyl methyl ether (TAM
43 S 1,2-Dichloroethane-d4
Zf4 T,M Benzene
45 T,M 1,2-Dichloroethane
46 T,M Trichloroethene
47 T,M Methylcyclohexane
48 C,T,M 1,2-Dichloropropane
49 T,M Bromodichloromethane
50 T,M 1,4-Dioxane
5'1 T, M Dibromomethane
5~ T,M 2-Chloroethyl vinyl ether
5:3 T,M 4-Methyl-2-pentanone
54 T,M cis-1,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
59 T,M Ethyl methacrylate eo T,M 1,1,2-Trichloroethane
61 T,M 2-Hexanone
62 T,M 1,3-Dichloropropane
63 T,M Tetrachloroethene
64 T,M Dibromochloromethane
65 T,M 1,2-Dibromoethane
66 T,M 1-Chlorohexane
'7 P,M Chlorobenzene
~8 T,M 1,1,1,2-Tetrachloroethane
69 C,T,M Ethylbenzene
~a T,M m-Xylene & p-Xylene
11 T,M o-Xylene
'72 T,M Styrene
73 T,M Isopropylbenzene
~4 I 1,2-DICHLOROBENZENE-D4
19 P/T,M Bromoform
'6 P,T,M 1,1,2,2-Tetrachloroethane
~~ S 4-Bromofluorobenzene
~8 T,M 1, 2, 3-Trichloropropane
~9 T,M trans-1,4-Dichloro-2-butene
~O T,M n-Propylbenzene
?
AvgRF
0.118
0.182
1. 335
0.235
0.330
0.622
0.301
0.326
0.001
0.121
0.054
0.147
0.424
1.000
CCRF
0.123
0.189
1.432
0.238
0.339
0.697
0.316
0.349
0.001
0.122
0.011
0.138
0.450
1.000
1.390 1.521
1.778 1.960
0.401 0.424
0.290 0.250
0.211 0.226
0.125 0.121
0.416 0.434
0.353 0.390
0.234 0.239
0.188 0.193
0.761 0.826
1. 014 /" 1. 082
0.298 0.341
2.000 2.195
1. 447 1. 624
1.364 1.547
1.046 1.018
1.783 2.030
1.000 1.000
0.355/ 0.345
0.686/ 0.732
1.351 1.411
0.184 0.188
0.192 0.193
7.269 8.387
%Dev Area% Dev(min)
-4.2
-3.8
-7.3
-1. 3
-2.7
-12.1
-5.0
-7.1
0.0
-0.8
79.6#
6.1
-6.1
0.0
-9.4
-10.2
-5.7
13.8
-7.1
3.2
-4.3
-10.5
-2.1
-2.7
-8.5
-6.7
-14.4
-9.7
-12.2
-13.4
2.7
-13.9
0.0
2.8
-6.7
-4.4
-2.2
-0.5
-15.4
102
100
110
102
105
103
107
109
99
103
22#
92
107
100
103
110
103
86
107
93
104
112
100
100
107
108
116
110
111
112
96
113
96
95
103
99
96
97
112
0.03
0.00
0.01
0.01
0.01
0.02
0.00
0.01
0.00
0.02
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.02
0.00
0.00
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.02
0.01
0.00
0.00
0.00
0.01
~-------------------------------------------------------------------------
(#) = Out of Range
bREC287.D V067D26.M Mon May 15 08:14:25 2023 Page 2
REPORT ID: 23E081 Page 153 of 489
Evaluate Continuing Calibration Report
;. Data File D:\HPCHEM\1\DATA\23E12\REC287.D
<\i ,~'
:~ Aeq On 12 May 2023 6:45 am
Sample CV067D2613
Vial: 2
Operator: VLu
Inst 67
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
--,::'} -'> ,'" Last Update
;:.f .
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
81
82
83
84
,~?
86
87
88
~9
~Q
91
,92
93
94
95
96
97
c}
I ~~ _
8.:-
B~-
8-~
"'--" '-'
';:;r.::
Response via
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
20% Max. ReI. Area
Compound
Bromobenzene
l,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
l,2,4-Trimethylbenzene
see-Butylbenzene
p-Isopropyltoluene
l,3-Diehlorobenzene
l,4-Diehlorobenzene
n-Butylbenzene
l,2-Diehlorobenzene
l,2-Dibromo-3-ehloropropane
1, 2, 4-Triehlorobenzene
Hexaehlorobutadiene
Naphthalene
l,2,3-Triehlorobenzene
AvgRF
1.024
4.534
4.686
3.849
1.000
4.206
6.008
4.718
2.049
1.994
4.492
1.613
0.071
0.680
0.573
0.871
0.464
50% Max. R.T. Dev 0.16min
200%
CCRF
1.111
5.128
4.977
4.055
1.167
4.708
7.183
5.438
2.210
2.134
4.973
1.714
0.068
0.739
0.657
0.780
0.467
%Dev Area% Dev(min)
-8.5 108 0.00
-13.1 111 0.02
-6.2 108 0.01
-5.4 100 0.00
-16.7 117 0.00
-11.9 109 0.00
-19.6 115 0.01
-15.3 110 0.01
-7.9 106 0.01
-7.0 106 0.00
-10.7 105 0.00
-6.3 104 0.00
4.2 93 0.01
-8.7 103 0.01
-14.7 109 0.00
10.4 86 0.01
-0.6 97 0.01
(#) = Out of Range
REC287.D V067D26.M
SPCC's out = a CCC's out = 0
Mon May 15 08:14:25 2023 Page 3
REPORT ID: 23E081 Page 154 of 489
Quantitation Report (QT Reviewed)
c"Data File D:\HPCHEM\1\DATA\23E12\REC287.D Vial: 2
Operator: VLu Acq On 12 May 2023 6:45 am
Sample CV067D2613 Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
:c Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.15
15.60
19.49
8.19
9.29
12.97
17.60
1. 88
'") 1C
.£. • ..1..U
2.26
2.68
2.72
2.78
2.98
3.53
3.59
3.59
3.78
3.92
4.23
4.29
4.53
4.54
4.76
4.80
5.04
5.70
5.89
5.94
6.65
6.92
7.22
7.32
7.70
114 2211620 I"
117 1591283/
152 479790./
III 572000
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.85
0.01
0.00
0.00
0.00
Recovery
ug/l
108.50%
ug/l
103.90%
ug/l
109.40%
ug/l
104.50%
65 418169 10.39 0.00
Recovery
98 2420822 10.94 0.00
Recovery
95 677038 10.45 0.00
Recovery
85 773638
50 1139832
62 1138083
94 745920
64 790646
67 1429609
101 882992
56 210275
151 538008
43 489954
61 1321865
59 569175
142 1168479
43 307152
76 2801395
49 1033153
53 577044
73 1122924
96 903376
45 2703229
63 1475684
43 858688
59 1733971
72 148580
77 1052850
96 862413
83 1214125
Qvalue
11.46 ug/l 100
9.73 ug/l 95
10.96 ug/l 99
11.65 ug/l 100
11.62 ug/l 98
11.11 ug/l 100
11.63 ug/l 100
40.59 ug/l 99
10.87 ug/l 100
55.24 ug/l 99
10.89 ug/l 99
233.58 ug/l 100
11.00 ug/l 99
10.65 ug/l 99
11.07 ug/l 99
10.05 ug/l 99
49.59 ug/l 100
10.63 ug/l 99
10.79 ug/l 99
11.06 ug/l 100
10.89 ug/l 99
11.08 ug/l 99
10.35 ug/l 100
50.36 ug/l 91
11.90 ug/l 99
10.86 ug/l 99
11.09 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC287.D V067D26.M Mon May 15 08:14:30 2023 Page 1
REPORT ID: 23E081 Page 155 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC287.D
Acq On 12 May 2023 6:45 am
Sample CV067D2613
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
i' 38) l,l,l-Trichloroethane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,I,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.06
8.15
8.57
8.59
8.92
9.11
9.26
9.48
9.49
10.74
10.82
11.09
11.53
11.61
11.61
12.20
12.24
12.58
13.12
13.50
13.53
13.75
13.80
14.20
14.26
14.61
14.94
15.28
15.68
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
339185
83027
1403769
1016239
379967
807165
272113
3167241
527406
750763
1540510
698247
771104
50691
270688
24690
1521661
995368
3119597
674331
397256
360374
959598
691152
621384
380353
306914
1314641
1721242
543163
3493528
5168352
2461501
1620395
3230485
165748
351422
90281
92744
4024213
532927
(#) = qualifier out of range (m) = manual integration
REC287.D V067D26.M Mon May 15 08:14:31 2023
10.52 ug/l
8.68 ug/l
11.36 ug/l
11.11 ug/l
10.04 ug/l
10.92 ug/l
10.43 ug/l
10.73 ug/l
10.17 ug/l
10.29 ug/l
11.19 ug/l
10.49 ug/l
10.70 ug/l
196.06 ug/l
10.13 ug/l
2.06 ug/l
46.79 ug/l
10.60 ug/l
11.02 ug/l
10.57 ug/l
8.60 ug/l
10.72 ug/l
48.43 ug/l
10.43 ug/l
11.07 ug/l
10.20 ug/l
10.27 ug/l
10.86 ug/l
10.67 ug/l
11.47 ug/l
10.98 ug/l
22.45 ug/l
11.34 ug/l
9.74 ug/l
11.38 ug/l
9.74 ug/l
10.68 ug/l
10.20 ug/l
10.08 ug/l
11.54 ug/l
10.85 ug/l
Qvalue
99
97
97
98
99
99
98
100
99
99
99
97
99
98
99
86
98
97
99
92
100
98
99
99
99
99
99
100
99
100
100
100
100
99
100
99
100
99
98
100
99
Page 2
REPORT ID: 23E081 Page 156 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC287.D
Aeq On 12 May 2023 6:45 am
Sample CV067D2613
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) l,3,5-Trimethylbenzene 18.04 105 2460420 11.31 ug/l
83) 2-Chlorotoluene 18.06 91 2387904 10.62 ug/l
84) 4-Chlorotoluene 18.12 91 1945531 10.54 ug/l
85 ) tert-Butylbenzene 18.48 134 560034 11.68 ug/l
86) 1, 2, 4-Trimethylbenzene 18.52 105 2258730 11.19 ug/l
87) sec-Butylbenzene 18.74 105 3446193 11.96 ug/l
88) p-Isopropyltoluene 18.90 119 2609100 11.53 ug/l
89) l,3-Dichlorobenzene 19.01 146 1060524 10.79 ug/l
90) l,4-Dichlorobenzene 19.12 146 1023713 10.70 ug/l
r 91 ) n-Butylbenzene 19.34 91 2385911 11.07 ug/l
92) l,2-Dichlorobenzene 19.52 146 822251 10.62 ug/l
~-93) l,2-Dibromo-3-ehloropropan 20.31 157 32683 9.66 ug/l
~> ~ 94) l,2,4-Triehlorobenzene 21.17 180 354694 10.87 ug/l
95 ) Hexaehlorobutadiene 21. 29 225 315363 11.48 ug/l
96) Naphthalene 21.45 128 374264 8.96 ug/l
97) 1, 2, 3-Trichlorobenzene 21.69 180 223838 10.05 ug/l
(#) = qualifier out of range (m) = manual integration
REC287.D V067D26.M Mon May 15 08:14:31 2023
Qvalue
99
94
93
96
99
100
99
99
99
99
100
99
99
100
99
98
Page 3
REPORT ID: 23E081 Page 157 of 489
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI2\REC287.D Vial: 2
Aeq On 12 May 2023 6:45 am
Sample CV067D2613
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Operator:
Inst
Multiplr:
VLu
67
1. 00
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
~bundance -----------------------~--------~T~IC~:~R~E~C~~28~7~.~D.------------------------
75000001
I
i
7000000:
65000001
i
ii
I:
600000011
Ii II
5500000!
i
50000001
I
!
45000001 0
40000001
!
3500000,
30000001,
1'-I~ ,e: om
i£ 2500000i~ ie
Ii
j e 2000000,~
10
i [ ::;;
I t
1500000: ~ 11
1000000j 0 i g
!: ~ J~
'II ~ 500000!
f
Time-->
REC287.D V067D26.M Mon May 15 08:14:33 2023
'" c
~ x
Eo
::;: ,..:
.,; c
[
~ e o
{3
'" 6
E e
.0
is
N_
Page 4
REPORT ID: 23E081 Page 158 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Acq On 12 May 2023 6:18 pm
Sample EV067D2613
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 29
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023 Last Update
Response via Multiple Level Calibration ,~
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2 ,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
25 P,T,M l,l-Dichloroethane
26 T,M Vinyl acetate
27 T,M 2-Butanol
28' T,M tert-Butyl ethyl ether (ETB
29 T,M 2-Butanone
30 T,M 2,2-Dichloropropane
3t T,M cis-1,2-Dichloroethene
12 C,T,M Chloroform
3], T,M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
17 T,M Cyclohexane
~8 T,M l,l,l-Trichloroethane
39 T,M 2,2,4-Trimethylpentane
40 T,M l,l-Dichloropropene
41 T,M Carbon tetrachloride
Amount Calc.
10.000 10.000
10.000 9.197
-l.000 0.000
10.000 8.046
10.000 9.717
10.000 9.967
10.000 10.292
10.000 10.246
10.000 10.798
-l.000 0.000
50.000 38.626
10.000 10.547
50.000 54.068
10.000 9.554
250.000 222.529
10.000
10.000
-1.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
-1.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
9.369
9.527
0.000
12.303
9.155
48.020
9.791
9.646
9.988
9.794
9.446
0.000
9.659
50.065
10.303
9.944
10.208
9.938
8.675
0.000
10.656
10.121
9.988
0.000
9.741
9.990
{#) = Out of Range
2REC314.D V067D26.M Mon May 15 08:14:49 2023
%Dev Area% Dev(min)
0.0
8.0
0.0
19.5
2.8
0.3
-2.9
-2.5
-8.0
0.0
22.7#
-5.5
-8.1
4.5
1l. 0
6.3
4.7
0.0
-23.0#
8.5
4.0
2.1
3.5
0.1
2.1
5.5
0.0
3.4
-0.1
-3.0
0.6
-2.1
0.6
13.2
100.0#
-6.6
-l.2
0.1
100.0#
2.6
0.1
96
83
o
72
83
86
89
99
94
o
70
102
107
93
86
88
84
o
105
94
90
94
94
97
96
83
o
96
94
101
96
100
95
82
o
97
89
97
o
95
95
0.01
0.02
0.00
0.06
0.04
0.00
0.02
0.00
0.02
0.00
0.03
0.02
0.04
0.04
0.04
0.03
0.03
0.03
0.03
0.04
0.03
0.03
0.03
0.03
0.04
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.04
-8.16#
0.01
0.03
0.03
-8.73#
0.01
0.01
Page 1
REPORT ID: 23E081 Page 159 of 489
Evaluate Continuing Calibration Report
,. Data File D: \HPCHEM\l \ DATA \23E12\REC314. D
1" Acq On 12 May 2023 6:18 pm
Sample EV067D2613
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial: 29
Operator: VLu
Inst 67
Multiplr: 1.00
j Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
44 T,M Benzene
45 T,M l,2-Dichloroethane
46 T,M Trichloroethene
47 T,M Methylcyclohexane
48 C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
50 T,M l,4-Dioxane
51 T,M Dibromomethane
52 T,M 2-Chloroethyl vinyl ether
53 T,M 4-Methyl-2-pentanone
54 T,M cis-1,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
5~ T,M Ethyl methacrylate
60 T,M l,l,2-Trichloroethane
61 T,M 2-Hexanone
G2 T,M l,3-Dichloropropane
6~ T,M Tetrachloroethene
64 T,M Dibromochloromethane
65 T,M l,2-Dibromoethane
66 T,M 1-Chlorohexane
67 P,M Chlorobenzene
68 T,M l,l,l,2-Tetrachloroethane
69 C,T,M Ethylbenzene
~O T,M m-Xylene & p-Xylene
71 T,M o-Xylene
72 T,M Styrene
73 T,M Isopropylbenzene
~4 I l,2-DICHLOROBENZENE-D4
75 P,T,M Bromoform
~6 P,T,M l,l,2,2-Tetrachloroethane
?7 S 4-Bromofluorobenzene
~8 T,M l,2,3-Trichloropropane
~8 T,M trans-1,4-Dichloro-2-butene
@O T,M n-Propylbenzene
Amount Calc.
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
9.764
10.283
9.947
9.903
10.009
10.513
9.999
10.043
196.738
9.767
3.187
47.512
9.719
10.000 10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.660
10.093
9.516
8.493
9.949
48.586
9.859
9.997
9.793
9.686
9.861
10.104
10.353
10.123
20.331
10.244
9.354
10.480
10.000
8.896
9.592
10.052
9.737
8.328
9.968
%Dev Area% Dev(min)
2.4
-2.8
0.5
1.0
-0.1
-5.1
0.0
-0.4
1.6
2.3
68.1#
5.0
2.8
0.0
-6.6
-0.9
4.8
15.1
0.5
2.8
1.4
0.0
2.1
3.1
1.4
-1. 0
-3.5
-1. 2
-1. 7
-2.4
6.5
-4.8
0.0
11. 0
4.1
-0.5
2.6
16.7
0.3
91
94
97
95
97
92
97
97
94
94
32
89
93
96
97
97
90
82
96
90
95
98
93
91
94
98
101
98
97
98
89
100
97
88
93
96
93
81
98
0.03
0.01
0.03
0.03
0.01
0.02
0.01
0.03
0.01
0.02
0.02
0.01
0.01
0.00
0.02
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.02
0.01
0.00
0.00
0.00
0.01
~~------------------------------------------------------------------------
6~#) = Out of Range
REC314.D V067D26.M Mon May 15 08:14:49 2023 Page 2
REPORT ID: 23E081 Page 160 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
A~q On 12 May 2023 6:1R pm
Sample EV067D2613
Vial: 29
Operator: VLu
Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
Title
t .{ Last Update
'} ~;
r Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
'", Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
"
Compound Amount Calc. %Dev Area% Dev(min)
81 T,M Bromobenzene 10.000 9.954 0.5
82 T,M l,3,5-Trimethylbenzene 10.000 10.046 -0.5
83 T,M 2-Chlorotoluene 10.000 9.914 0.9
84 T,M 4-Chlorotoluene 10.000 9.728 2.7
85 T,M tert-Butylbenzene 10.000 10.110 -1.1
86 T,M l,2,4-Trimethylbenzene 10.000 10.103 -1. 0
87 T,M sec-Butylbenzene f' 10.000 10.293 -2.9
88 T,M p-Isopropyltoluene 10.000 10.323 -3.2
89 T,M l,3-Dichlorobenzene 10.000 10.104 -1. 0
~6 T,M l,4-Dichlorobenzene 10.000 9.995 0.1
Q;l T,M n-Butylbenzene 10.000 10.014 -0.1
$~ T,M l,2-Dichlorobenzene 10.000 10.076 -0.8
93 T,M l,2-Dibromo-3-chloropropane 10.000 9.042 ~4 T,M l,2,4-Trichlorobenzene 10.000 10.058
9.6
-0.6
95 T,M Hexachlorobutadiene 10.000 11.146 -11.5
96 ", T, tJI Naphthalene 10.000 8.373 16.3
97 T,M 1, 2, 3-Trichlorobenzene 10.000 9.663 3.4
" ~~.
~
~(#) = Out of Range
"REC314.D V067D26.M
SPCC's out = 0 CCC's out = 0
Mon May 15 08:14:50 2023
101 0.00
99 0.02
102 0.01
93 0.00
102 0.00
100 0.00
100 0.01
99 0.00
100 0.01
100 0.00
96 0.00
100 0.00
88 0.01
96 0.02
107 0.00
81 0.01
94 0.01
Page 3
REPORT ID: 23E081 Page 161 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Acq On 12 May 2023 6: 18 pm
Sample EV067D2613
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 29
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
··4 P, T, M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
, 8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
2@ T,M Methylene chloride
2i T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
25 P,T,M l,l-Dichloroethane
26 T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
29 T,M 2-Butanone
30 T,M 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
12 C/T,M Chloroform
33 T,M Bromochloromethane
A4 T,M Tetrahydrofuran
15 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
37 T,M Cyclohexane
~g T,M l,l,l-Trichloroethane
39 T,M 2,2,4-Trimethylpentane
4@ T,M l,l-Dichloropropene
4~ T,M Carbon tetrachloride
AvgRF
1.000
0.305
0.000
0.530
0.470
0.290
0.308
0.582
0.343
0.000
0.023
0.224
0.040
0.549
0.011
0.480
0.130
0.000
1.144
0.465
0.053
0.478
0.378
1.105
0.613
0.350
0.000
0.757
0.013
0.400
0.359
0.495
0.146
0.043
0.009
0.238
0.559
0.414
1.474
0.171
0.334
50% Max. R.T. Dev 0.16min
200%
CCRF
1.000
0.281
0.000
0.426
0.456
0.289
0.317
0.596
0.371
0.000
0.018
0.236
0.043
0.524
0.010
0.450
0.124
0.000
1. 408
0.425
0.051
0.468
0.365
1.104
0.600
0.331
0.000
0.732
0.013
0.412
0.357
0.505
0.145
0.038
0.000
0.254
0.565
0.413
0.000
0.167
0.334
%Dev Area% Dev(min)
0.0
7.9
0.0
19.6
3.0
0.3
-2.9
-2.4
-8.2
0.0
21.7#
-5.4
-7.5
4.6
9.1
6.2
4.6
0.0
-23.1#
8.6
3.8
2.1
3.4
0.1
2.1
5.4
0.0
3.3
0.0
-3.0
0.6
-2.0
0.7
11.6
100.0#
-6.7
-1.1
0.2
100.0#
2.3
0.0
96
83
0#
72
83
86
89
99
94
0#
70
102
107
93
86
88
84
0#
105
94
90
94
94
97
96
83
0#
96
94
101
96
100
95
82
0#
97
89
97
0#
95
95
0.01
0.02
0.00
0.06
0.04
0.00
0.02
0.00
0.02
0.00
0.03
0.02
0.04
0.04
0.04
0.03
0.03
0.03
0.03
0.04
0.03
0.03
0.03
0.03
0.04
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.04
-8.16#
0.01
0.03
0.03
-8.73#
0.01
0.01
4,~-------------------------------------------------------________________ _
2~#) = Out of Range
2&EC314.D V067D26.M Mon May 15 08:14:53 2023 Page 1
REPORT ID: 23E081 Page 162 of 489
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Acq On 12 May 2023 6:18 pm
Sample EV067D2613
Misc 10ppb 8260/50ppb KET-AA/250ppb
3. MS Integration Params: RTE.P
TBA
Vial: 29
Operator: VLu
Inst 67
Multiplr: 1.00
"j:c' Method
~ ~,
,:. / Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
.; ,;, Last Update
,,; Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
42 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
44 T,M Benzene
45 T,M l,2-Dichloroethane
46 T,M Trichloroethene
~7 T,M Methylcyclohexane
~8 C,T,M l,2-Dichloropropane
~~ T,M Bromodichloromethane
~O T,M l,4-Dioxane
~l T,M Dibromomethane
p2 T,M 2-Chloroethyl vinyl ether
5~ T,M 4-Methyl-2-pentanone
54 T,M cis-1,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
59 T,M Ethyl methacrylate
Go T,M l,l,2-Trichloroethane
61 T,M 2-Hexanone
62 T,M l,3-Dichloropropane
63 T,M Tetrachloroethene
64 T,M Dibromochloromethane
~5 T,M l,2-Dibromoethane
~~ T,M 1-Chlorohexane
~9 P,M Chlorobenzene
B8 T,M l,l,l,2-Tetrachloroethane
6,9 C, T, M Ethylbenzene
~d T,M m-Xylene & p-Xylene
~1 T,M o-Xylene
72 T,M Styrene
~~ T,M Isopropylbenzene
~~ I l,2-DICHLOROBENZENE-D4
7-5 P, T, M Bromoform
'6 P,T,M l,l,2,2-Tetrachloroethane
~7 S 4-Bromofluorobenzene
78 T,M l,2,3-Trichloropropane
99 T,M trans-1,4-Dichloro-2-butene
~O T,M n-Propylbenzene
AvgRF
0.118
0.182
1. 335
0.235
0.330
0.622
0.301
0.326
0.001
0.121
0.054
0.147
0.424
1.000
1.390
1.778
0.401
0.290
0.211
0.125
0.416
0.353
0.234
0.188
0.761
1.014
0.298
2.000
1.447
1.364
1.046
1.783
1.000
0.355
0.686
1.351
0.184
0.192
7.269
50% Max. R.T. Dev 0.16min
200%
CCRF
0.115
0.187
1.328
0.232
0.330
0.654
0.301
0.327
0.001
0.118
0.017
0.140
0.412
1.000
1.482
1.795
0.382
0.246
0.210
0.121
0.410
0.353
0.230
0.182
0.750
1.025
0.308
2.025
1.471
1.397
0.978
1.869
1.000
0.316
0.658
1.358
0.180
0.160
7.245
%Dev Area% Dev(min)
2.5
-2.7
0.5
1.3
0.0
-5.1
0.0
-0.3
0.0
2.5
68.5#
4.8
2.8
0.0
-6.6
-1. 0
4.7
15.2
0.5
3.2
1.4
0.0
1.7
3.2
1.4
-1.1
-3.4
-1.2
-1. 7
-2.4
6.5
-4.8
91
94
97
95
97
92
97
97
94
94
32#
89
93
96
97
97
90
82
96
90
95
98
93
91
94
98
101
98
97
98
89
100
0.0 97
11. 0 88
4.1 93
-0.5 96
2.2 93
16.7 81
0.3 98
0.03
0.01
0.03
0.03
0.01
0.02
0.01
0.03
0.01
0.02
0.02
0.01
0.01
0.00
0.02
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.02
0.01
0.00
0.00
0.00
0.01
~-------------------------------------------------------------------------
~1#) = Out of Range
SREC314.D V067D26.M Mon May 15 08:14:55 2023 Page 2
REPORT ID: 23E081 Page 163 of 489
~1'Q
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Aeq On 12 May 2023 6:18 pm
Sample EV067D2613
Vial: 29
Operator: VLu
Inst 67
[ Mise 10ppb 8260/50ppb KET-AA/250ppb ;z:, ~, TBA Multiplr: 1.00
./
t31
~2
8;3
.of·,_:
84
85
" 86
87
88
89
90
91
92
93
~4
~5
96
97
6~
;::'::
;:,.-;~ --a ~;.
,~. "
tJ ~
'''i
.-, 7.'
V . ..1
8::
2·
~
~
MS Integration Params: RTE.P
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M Bromobenzene 1.024
T,M 1, 3, 5-Trimethylbenzene 4.534
T,M 2-Chlorotoluene 4.686
T,M 4-Chlorotoluene 3.849
T,M tert-Butylbenzene 1.000
T,M 1, 2, 4-Trimethylbenzene 4.206
T,M see-Butylbenzene 6.008
T,M p-Isopropyltoluene 4.718
T,M l,3-Diehlorobenzene 2.049
T,M l,4-Diehlorobenzene 1.994
T,M n-Butylbenzene 4.492
T,M l,2-Diehlorobenzene 1.613
T,M l,2-Dibromo-3-chloropropane 0.071
T,M 1, 2, 4-Triehlorobenzene 0.680
T,M Hexaehlorobutadiene 0.573
T, ~·1 Naphthalene 0.871
T,M 1, 2, 3-Triehlorobenzene 0.464
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
1.019 0.5 101 0.00
4.555 -0.5 99 0.02
4.646 0.9 102 0.01
3.744 2.7 93 0.00
1.011 -1.1 102 0.00
4.249 -1. 0 100 0.00
6.184 -2.9 100 0.01
4.871 -3.2 99 0.00
2.070 -1. 0 100 0.01
1.993 0.1 100 0.00
4.499 -0.2 96 0.00
1.626 -0.8 100 0.00
0.064 9.9 88 0.01
0.684 -0.6 96 0.02
0.638 -11.3 107 0.00
0.729 1603 81 0.01
0.448 3.4 94 0.01
(#) = Out of Range
'REC314.D V067D26.M
SPCC's out = 0 CCC's out = 0
Mon May 15 08:14:56 2023 Page 3
REPORT ID: 23E081 Page 164 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Acq On 12 May 2023 6:18 pm
c' Sample EV067D2613
Vial: 29
Operator: VLu
Inst 67
. Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
,MS Integration Params: RTE.P
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
C. Spiked Amount 10.000
'[ 77) 4-Bromofluorobenzene
Spiked Amount 10.000
. : Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.15
15.60
19.49
8.21
9.30
12.99
17.60
1. 87
2.18
2.28
2.68
2.72
2.78
2.98
3.53
3.59
3.61
3.80
3.94
4.25
4.31
4.53
4.56
4.78
4.82
5.05
5.72
5.91
5.96
6.66
6.94
7.23
7.33
7.71
114
117
152
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
2102126 /'
1537164 /
485155 /
533835
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.66
0.01
0.00
0.00
0.01
Recovery
ug/l
106.60%
ug/l
102.80%
ug/l
106.60%
ug/l
100.50%
393393 10.28
Recovery
2278415 10.66
Recovery
658733 10.05
Recovery
590055
896388
959158
606742
665627
1253123
779321
190169
496294
455838
1102534
515390
946120
261091
2959405
894202
531092
983138
767306
2320034
1261793
695843
1537930
140395
866256
750555
1062581
9.20 ug/l
8.05 ug/l
9.72 ug/l
9.97 ug/l
10.29 ug/l
10.25 ug/l
10.80 ug/l
38.63 ug/l
10.55 ug/l
54.07 ug/l
9.55 ug/l
222.53 ug/l
9.37 ug/l
9.53 ug/l
12.30 ug/l
9.16 ug/l
48.02 ug/l
9.79 ug/l
9.65 ug/l
9.99 ug/l
9.79 ug/l
9.45 ug/l
9.66 ug/l
50.06 ug/l
10.30 ug/l
9.94 ug/l
10.21 ug/l
0.01
0.02
0.00
Qvalue
99
92
100
99
97
100
99
99
100
99
99
99
99
100
100
100
99
100
100
99
100
100
100
93
99
100
99
(#) = qualifier out of range (m) = manual integration
REC314.D V067D26.M Mon May 15 08:15:02 2023 Page 1
REPORT ID: 23E081 Page 165 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Acq On 12 May 2023 6:18 pm
Sample EV067D2613
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 29
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
L 37) Cyclohexane
A 38) 1,1,1-Trichloroethane
S 40) 1,1-Dichloropropene
~ 41) Carbon tetrachloride
Iv 42) tert -Amyl methyl ether (TA
44) Benzene
45) 1,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) 1,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.18
8.59
8.60
8.94
9.11
9.26
9.49
9.51
10.74
10.82
11.10
11.54
11.63
11.61
12.21
12.26
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.26
14.61
14.96
15.28
15.68
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
304460
78894
1188319
868680
350498
702098
242038
2790930
488284
694311
1375216
632766
688038
48348
248100
36265
1468775
867051
2758880
586553
378868
323055
929969
630871
542260
352806
279689
1152875
1575184
473551
3112018
4522339
2147981
1503621
2873010
153112
319173
87153
77519
3515148
494593
(#) = qualifier out of range (m) = manual integration
REC314.D V067D26.M Mon May 15 08:15:03 2023
9.94 ug/l
8.68 ug/l
10.12 ug/l
9.99 ug/l
9.74 ug/l
9.99 ug/l
9.76 ug/l
9.95 ug/l
9.90 ug/l
10.01 ug/l
10.51 ug/l
10.00 ug/l
10.04 ug/l
196.74 ug/l
9.77 ug/l
3.19 ug/l
47.51 ug/l
9.72 ug/l
10.09 ug/l
9.52 ug/l
8.49 ug/l
9.95 ug/l
48.59 ug/l
9.86 ug/l
10.00 ug/l
9.79 ug/l
9.69 ug/l
9.86 ug/l
10.10 ug/l
10.35 ug/l
10.12 ug/l
20.33 ug/l
10.24 ug/l
9.35 ug/l
10.48 ug/l
8.90 ug/l
9.59 ug/l
9.74 ug/l
8.33 ug/l
9.97 ug/l
9.95 ug/l
Qvalue
99
99
98
98
98
99
97
100
100
99
99
99
98
98
98
89
99
99
99
96
98
98
99
98
99
99
99
99
99
99
100
100
99
99
99
100
100
98
95
100
99
Page 2
REPORT ID: 23E081 Page 166 of 489
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Acq On 12 May 2023 6:18 pm
Sample EV067D2613
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 29
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1,3,5-Trimethylbenzene 18.04 105 2209923 10.05 ug/l
83) 2-Chlorotoluene 18.06 91 2254018 9.91 ug/l
84) 4-Chlorotoluene 18.12 91 1816393 9.73 ug/l
85) tert-Butylbenzene 18.48 134 490311 10.11 ug/l
86) 1,2,4-Trimethylbenzene 18.52 105 2061547 10.10 ug/l
87) see-Butylbenzene 18.74 105 3000110 10.29 ug/l
88 ) p-Isopropyltoluene 18.89 119 2362979 10.32 ug/l
89) 1,3-Diehlorobenzene 19.01 146 1004474 10.10 ug/l
90 ) 1,4-Diehlorobenzene 19.12 146 966791 9.99 ug/l
91 ) n-Butylbenzene 19.34 91 2182478 10.01 ug/l
92) 1,2-Diehlorobenzene 19.52 146 788742 10.08 ug/l
L 93) 1,2-Dibromo-3-ehloropropan 20.31 157 30930 9.04 ug/l
94) 1,2,4-Triehlorobenzene 21.17 180 331828 10.06 ug/l
r 95) Hexaehlorobutadiene 21.29 225 309673 11.15 ug/l
96) Naphthalene 21. 45 128 353724 8.37 ug/l
97) 1,2,3-Trichlorobenzene 21.70 180 217591 9.66 ug/l
(#) = qualifier out of range (m) = manual integration
REC314.D V067D26.M Mon May 15 08:15:03 2023
Qvalue
100
95
93
97
99
100
99
99
99
99
100
99
99
98
99
100
Page 3
REPORT ID: 23E081 Page 167 of 489
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E12\REC314.D
Aeq On 12 May 2023 6:18 pm
Sample EV067D2613
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 29
Operator:
Inst
Multiplr:
VLu
67
1. 00
Quant Time: May 15 8:14 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
~bundance ~~~~~~~~--~~~~~~~T'nIC~:~R~E~C~3~1"4n.Dn-~~~~~~
, 75000001
7000000i
!
6500000fi
I
!
6000000i
1
55000001
I
)i
5000000j
I
I
45000001
4000000' :
I:
35000001 i
(:i<.
''''. l:g
3000000 1
2500000ll
its
:0
10000001
,
500000'
0'
2.00
REC314.D V067D26.M Mon May 15 08:15:05 2023
~ ,..:
oj c:
'" 0. e
0. e o
~
M
6
E e
'" is
N.
Page 4
REPORT ID: 23E081 Page 168 of 489
· ANALYTICAL LOGS
REPORT ID: 23E081 Page 169 of 489
Page 24
ANALYSIS LOG FOR VOLATILES
SOP [i(EMAX-8260 Rev.No.!!! Iirl'MAX-8260C Rev. No.! 0 EMAX-8260SIM Rev.No.! 0 EMAX-M8260SIM RE!V.No.Q 0 EMAX-TCPSIM Rev.No. ~ 0 EMAX-624 Rev.No. § 0 EMAX-624.1 Rev.No. !
Start Date: 4/1." Il...., o S-mL Purge 0 lO-mL Purge I!'" 2S-mL Purge Book#' A67-081 ----_ .. _ .......... -•.............................. .. '. ~~ .
l~) Matrix Instrument No. 67 Sample Data Sample
Prep lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
10 File Name Amount 5
lAAL.)
pH CI,
<2 < 5DDm DATE lot /1'-/21
01 1"1>C,~1 &fflJr, 1 D24 A/PJ iliA INA AlA '21t..0 1b..I'.AA "T&A ftJ:l-f) ICAllD V 04:,1 Du"
02 n VOh1&llu I IhnID,t(' D.l L.C 1. ("Mit STANDARDS
Sq 1-.. o,o,lo.)'{ b,t' NAME 10 f Amount Cone. 03 2.(" 11,(" (01) (m"'U
04 '10 ~ ", 0·\ 1/1., \.0 ('.0 t\ DCC J}j.~
1">1/\-'""-Tl-11., ... .. 'I'b '!lA"" .141.-01-n ::r 1A"1I
05 'II 4 '" 0.1./1.0 1..0 /0 1\1> DCC 41UiJ -q,-~ n. .j 'tn''''''"
06 ql.. , IIX n .. ' t'.D t~ la, DCC ~!:.
-11-~ '''--(1) ~" -~I-1'\-2.n
07 ql " .' 1,01,.0 10 0 «b DccTM-'1Vof -&.11.-D'1-0 '1./1\» /t'z..n
08 14 1 2.0 /10 -z.,0 100 ~O BFB -""'-110.01 I c;D
D:I 09 It, II ... ~.O II, ~O I~ 1)b IS/SURR, ·U : 4\:~r-~J..
I 1..c;"V
" ~\"II J>
"I 1m ll:SJ,.) ICV/lCS~~ -"il-"t<"-O\
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"iV
... -I.foo Dl.";D·l.. <"'tIG
12 18 ~I.Nc\E. ICV/lCS ~ -"'-.. ,,-~ I '2A1>
-'H -i.i-O'\ , ~ c.:.
13 "'tt J. Icv/lc"1J..1':;r""
_1.I'l._~ -01
~
'Z-<""1>
c:r v _ L.t'!oo -"'D1. "' ~ 14 (,00 \/111.11)1-" " ",1('.011, c;"'O 20 12.~nl\)., Data File Folder 23DU,
'0 15 Dt ~:l:N<'E.
I
lOT II Syringe lot II ~
C' 16 01. J.... pH strip M.W-O~-01.-Ol-~ C'" 0\ '1." 01.11)2100 I \() 0 2.<:bnlll. 17 ~ h., 1('14 Chlorine strip -0'-02.-\(_1
" 18 ·,_, __ w, Methanol -{)2,·OI-l'l
19 ----NaHSO. -Ol-tH-Ol.
20 ---r--.... Reagent Water i RW~ -'11.-{)/)!.f 'V -D~-Ol-0(",
21 ,.;>
Sand
22 ---~ Electronic Data Archival location Date
23 ----HPCHEM_VOA/T067 if #1.1/1.'"
24 ~ Comments: £16 hllWl'U'l tttHt!i.Mt
25 /' A-~ 12M, Cb.., g a.tj.il I I~a· 11. '" IS!)
26 ,/
~ ~ ~lfd 1 lU.h~
27 ' ......... t tlilt ~.II~ ~ aU:Dl,-,itl. Z,-dLAN..
28 o Refer to sample weight log
29 Analyzed By: \I\..
30 , .... _--=----\Il q l1."lll __ Date Disposed: ..... q/'l."'I1U Disposed By: Vl... REPORT ID: 23E081 Page 170 of 489
Page 39
ANALYSIS LOG FOR VOLATILES
SOP mMAX-S260 Rev.No.10 I3"EMAX-S260C Rev. No.! 0 EMAX-S260SIM Rev.No.! 0 EMAX-MS260SIM Rev.No. Q 0 EMAX-TCPSIM Rev.No. ~ 0 EMAX-624 Rev.No. § 0 EMAX-624.1 Rev.No.!
Start Date: t:;" /11.1 L" o 5-mL Purge 0 10-mL Purge cr 25-mL Purge Book#' A67-081
Matrix Instrument No. 67 Sample Data Sample
Prep Lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
File Name Amount S ID pH CI, lJ,IU'/z,-., <2 <S m DATE
01 1lU .. l.i t.. lI,'F-& j." E 14 ." , D"'',I L ICALID V 0/'11> z,{:)
02 ,,1 (, VO t.11)"2,1'0 f) '"
STANDARDS
~i VO"" Ellil , NAME 10
Amount Cone.
03 (ul mell
04 rI'I c... .. DCC J1~ <;'''-'" \. '.y. -0 I ~ ....
_ IH_ "'1.-0"1-
05 410 R. :t.N<,E. DCC UIiJU -41.~~-O' j I
06 q, Vf>b'l E14~ ... 1,C'itlL DCC f?A\ .. 41-,q·iJ,\ ,
07 ((2. 1 .. ;i!Di'I-I?' 1.0 / /' In, -00&" -b4-'L' DCC c.~ ... '-Il'l..-fil -0 I I
08 q} -I'l. ,. /' / BFB .. LiI-1.b-D1 I I 0/)4"'0/
III 09 t(14 .. () It; /' / IS/SURR. ··lft ·4'H12. ~ 11.i"\.
l>
ICV/LCSi!,..~
.. &( t-oz.,"",i
~ -I 10 er, -l>1 ./ ./ .. ill. -U'\ .0'\ n
:::t 11 life.. • D\ / /' ICV /LCS '?>1AI1J -~t-",-OI l;"
12 'I, -10 .. /' ,...
ICV/LCS 6iK .. LfI-1"-~ I ~
<: 13 ~i o. 6g ~ ,... ,... ICV/LCS CS1. '~ .. 41-"1'-0) I I
0' tit! .. () I ~ /
~. 14 .. /' Data File Folder ·l~E'l..
.~ 15 ;(1) .. 011 J,... / /' LOT # Syringe Lot #
~ 16 bl -19-( .. / /' pH strip ~/.1.lC""O M W -0, -01vL (' -I -17 oL -()1. / / Chlorine strip 1. " '7"~ () \ P.> I -01, .Ill, -tn·"
"" / -L.. 18 C~ -n ".. ,... Methanol -0 ~-(}I-I e;
19 61.{ -1'lLJ /' / NaHSO.
i
20 O~ -bL.M /' /' Reagent Water Rw~ -1.1..-00'-1
21 Db -() foe, ,. /' / Sand
22 01 II -(JiM ,...
/ Electronic Data Archival Location Date
23 bY i.--tJH ... , ..... ~-/" /' HPCHEM_VOA/T067
24 M 2. IN~E. Comments:
25 10 'L,,~oq4 -04 1-(",l 1,0 /' /' 'i8-60\"0 0, -II
26 /I -01 /" ,...
27 11. ! .• 01.. r ,...
28 ., ~ ..... -0) ' .... '" ..-/ o Refer to sample weight log
29 14 ~\ID'''l Pl."l? iV·.lf AnalY2ed By: \(t..
30 I( I , I\ot l,.valu.CA.t .. ((A Date Disposed: t:;" L \ ~ I. 1:.:} Disposed By: VL
110 L 1. I
'1 tl .,. N<'~ REPORT ID: 23E081 Page 171 of 489
en

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REPORT ID: 23E081 Page 172 of 489
I Page 75
STANDARDS LOG FOR VOLATILES
Book No: SVl-35
I Parent ID Parent Standard Name Co.:;~j,.., AIi~1t Final ~f~ , ,
~ -to -o-:}-\ ~ 'TLt.-VO I. ~' ~ (1St) 2£V . >'\. '?'-
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Name IcEr~#C~V
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MeOH Solvent ID ~1,.4--oo4-'fl-c --/ I Prep. Date (2-/~ /?;;l
Exp. Date mf~l/7-r -------------I Prepared By Sf)
Comments: ----------I
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Parent ID Parent Standard Name CO~1;U1 Aliq~~oL Final~~h Standard ID SVl-3S-7S-02
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<7'11\ ~ 1j0 -Cuj -ICf M..R.~,I -AQ hd--L ,v,tA.,(-o«~ t;O, OOO~/111
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Name tvI~v,A ·1tu17Je. .
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Comments:
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"""",,'.~.m~,,~, ______________ _
REPORT ID: 23E081 Page 173 of 489
I
,~ Page 16
~ STANDARDS LOG FOR VOLATILES , ,
I Book No: SVl-36
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-36-16-01
I t:;" \ _?:).> O!J. ~ \/1.-vJA T ;1"1 ~y >OOOMI-"I IOO,~ ~O--'>-lM
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Prep. Date ~ itt.!).j
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Prep. Date 3 Itt. /).\
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REPORT ID: 23E081 Page 174 of 489
I
.,~ Page 20
/
Ii STANDARDS LOG FOR VOLATILES
t"·:· ['0:
I Book No: SVl-36
Parent ID Parent Standard Name Concnf>i'\ Aliquot"A. Final CRBh Standard ID SVl-36-20-01
I G\ 'A'\ -l ';V --11,\ 'f )~ 0 C_ 1--.) J0 1 / S,-S ~/l'1C >-~ f AF" 1>""; V 2(1'-0 Name
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-------. MeOH Solvent 10 SUI I Itro-.rl{ --r;7P-c :>
I ~ Prep. Date '~/IA( LA v:> , .
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('''\ -')Ir -9"'\-I ;r ~ /A;~--<:J r-ii\<n 7J("O, ,t '1y-1iJ Ou Name tr' (f"') \It-, -tv--r .un I' 1.-1
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I -~ (WI iJ+ -Cc~"lL1'-&-( (} --MeOH Solvent 10
~ Prep. Date (),dd1I'~
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1?ul od 11 .Of) REPORT ID: 23E081 Page 175 of 489
I ,-Page 31
; STANDARDS LOG FOR VOLATILES
I Book No: SVl-36
Parent 10 Parent Standard Name Conc.;!>"", Aliq u9t1... Final fbW,c. Standard 10
I (No. -f,,..-,-,"6 -! X V':Jfr-iYA<t/.. ~\ ~\ c'OV ?~-t)
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Name
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I • VI.-'-(/{'1lt, REPORT ID: 23E081 Page 176 of 489
I
Page 66
STANDARDS LOG FOR VOLATILES
I Book No: SVl-36
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SV1-36-66,-01
4111 /')C-II £11 Gv,> }..'O <ill ! ~Vl tW'\-Il ,,~~ liP')
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~ ---------~ Comments:
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/
"-eN CI/' I dU I J-\ -REPORT ID: 23E081 Page 177 of 489
Page 68
STANDARDS LOG FOR VOLATILES
Book No: SVl-36
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I STANDARDS LOG FOR VOLATILES
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,!, -30-ii-ILl ~2(PbA S ':> ~ J. ~
Name :rSI<S
Final Volume IO~1..
~ -----") I
MeOH Solvent 10 S"IN IA· () Dtl -t ') -n
Prep. Date "In-In.1
Exp. Date 1. J.£.I n.!.
~
-----I Prepared By VL
Syringe ID:
~
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VL iif/z. ILl
Parent ID Parent Standard Name Cone. Aliquot Final Cone.
SV1-~'·/H.-1I Yl~o 7\ 2f/)OIPI'h UDANl 5"0 pp ..... I Standard ID SVl-37-35-03
Name ISg~
J... -30",11-14 'l'Z(,OA S~ J-t.. '-I Final Volume 10 r'hL
MeOH Solvent 10 ~W1A-OD~·l ~-~
Prep. Date If 12l/li -------Exp. Date ~/1.1/27..
,/ Prepared By \It
.--.--Syringe ID:
~
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REPORT ID: 23E081 Page 220 of 489
I Page 36
STANDARDS LOG FOR VOLATILES
Book No: SVl-37
I Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-37-36-01
~'''1-3f-OI--1f ~2(pc "L> 2f;(;o 121m um-'-'$"0 DlP"I Name IS/5S
I J, .. ;0-11-~t.I '?'lI9DA C; s ~ J.. I ' ..... Final Volume IOrnL
MeOH Solvent 10 SWIA-oOti-ll-tA ----........ " ./ I
P~ep. Date "/Z illl
Exp. Date ~J2i!Z.Z.
Prepared By VL
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Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-37-36-02
I <,.V \ -",O-02-0t. '\IDA 11AM'li\ c~od 1f1; v: t;'oO{) lJOt'VI IODML ~()pP"'1
II I
Name "Bt=-8
Final Volume 10 WlL -~ MeOH Solvent 10 ~WIA • boll-Lt;"· 0) -----Prep. Date q 1l.I/z..l ...... t'\ Exp. Date 1. /J. l/ 2. 1-
..-----V Prepared By VL --~ Syringe ID:
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Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-37-36-03
$\11-50-Ol.-(}1... VIJA ~nl\'v( lMOd mi\t S~"Oo,OI"'\ 100",,1-50DPM Name BF8 a I . I
, Final Volume 10 il\L. ----MeOH Solvent 10 C;WlA -D{)tt· ,'\--~ ----... Prep. Date ifjZI!2-1
/ Exp. Date 3/LI/'lL .------~ Prepared By VL
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REPORT ID: 23E081 Page 221 of 489
RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Gravimetric Certificate
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
• ISO 11034A .... edKed
R&fer&otW ,.,.bt~ldl PfoducQr
CQl'tific..lt& ;32220l
~ .. " ~ rACC'RED'IT'EDl
IsonEC 17025 Accredited
Testing lab3riltofy
CQrtifloto f 3222.02
Catalog No. : 556476 Lot No.: A0155119 6 VI-3D -64-00
Description: Custom 1.2.3-Trichloropropane-c.I5 Standard
Custom 1.2.3-Trichloropropane-d5 Standard 1,OOOll9/mL, P& T Methanol,
1mLlampui
Container Size: 2 mL Pkg Amt: > 1 mL ~~--------------------------------Expiration Date: November 30, 2022 Storage: O°C or colder
CERTIFIED VALUES
-. Compound' .. . - -
.---cGrav. Cont. - .
(weight/volume)
Expanded tlncertainty - - -
1,2,3-Trichloropropane-d5
CAS # 203578-27-2 (Lot PR-14307)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
."·:;~;t. 1-";j<~4
La':'e Klbe -Mix Technician Date Mixed: 15-Nov-2019
1,000.0 Ilg/mL
Balance: 1127510105
(95% C.L.; K=2)
+/-10.0737
+/-56.6693
+/-57.9677
Gravimetric
Unstressed
Stressed
Manufactured under Restek's ISO 9001 :2008
Registered Quality System
Certificate #FM 80397
Page 1 of2
REPORT ID: 23E081 Page 222 of 489
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/jJECD,
GC/MS, LC/MS, RI, and/or melting point.
• Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
Purity of isomeric compounds is reported as the sum of the isomers.
Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k U;ralJim.etric + U~om.ogeneity + U;torage stability + U;hipping stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
..-:-._.
label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
1DoC or colder (Refrigerate) <40°C ~ 40°C up to 7 days
DOC or colder (Freezer) < 25°C <:: 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
• Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
• Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
Page 2 of 2
REPORT ID: 23E081 Page 223 of 489
/' ;;:., RESTEK0 CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30224
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PlUOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0146953
Description : Toluene-d8 Standard
Toluene-dB 20001.lg/mL, P& T Methanol, 1 mUampul
Container Size: 2 mL ------------------Pkg Amt: > 1 mL -----------------Expiration Date: March 31, 2024 Storage: O°C or colder
~ ..
Ii'C'CREDIT'iD)
ISO 11034 Aeuedfted
Ref@TtoceMJtel!ilf'foductr
CMifICJteU22.2.01
'",~ a
IsonEC 17025 Accredited
resting Labor.lory
(Qrti1iate i3222.02
CERTIFIED VALUES
Compound
Toluene-d8
CAS # 2037-26-5
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
(Lot PR-30245)
Grav. Conc.
(weight/volume)
2,018.0 flg/mL
Expanded Uncertainty
(95% C.l.; K=2)
+/-11.8428
+/-113.1587
+/-115.8060
Gravimetric
Unstressed
Stressed
REPORT ID: 23E081 Page 224 of 489
Column:
105m x 0.53mm x 3.01lm
Rtx-502.2 «at.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ SOC/min. (hold 5 min.)
Inj. Temp:
200"C
Oet. Temp:
250"C
Oet. Type:
FID
M"YJ1'f W:";r
Maggie Wang -operations-"'r-eC-hn-'C-ian-'
~*' ~ -P.a;.1O'
Jennifer Pollino -Operations Tech·ARM QC
o 5 10 15
Minu1es
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 12-Mar-2019
Date Passed: 18-Mar-2019
Balance: 1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E081 Page 225 of 489
General Certified Reference Material Notes
Expiration Notes:
• Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
• Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
• Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/IJECD,
GC/MS, LC/MS, RI, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty. storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Uiravi-rnetric + U~omooeneit:y + U;t:oraoe stability + U;hippino stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
1Q°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
O°C or colder (Freezer) < 25°C ~ 25°C up to 7 days
• Separate (not combined) uncertainty values for graVimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product. when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampUl until the material is completely
dissolved.
REPORT ID: 23E081 Page 226 of 489
125 Ma rket Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Tel [phone]
Fax [phone]
www.AccuStandard.com
Catalog No: M-502C-04
Description: Volatile Organic Compounds
Lot: 218041438-01
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Component
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichloropropane
1,1-Dichloropropene
cis-1 ,3-Dichloropropene "
trans-l ,3-Dichloropropene "
Hexachlorobutadiene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
Trichloroethylene
1,2,3-Trichloropropane
.• Weight compensated to 100% purity.
H 47,8% cis isomer, 46,1% trans isomer
CAS#
96-12-8
106-93-4
107-06-2
78-87-5
142-28-9
563-58-6
10061-01-5
10061-02-6
87-68-3
630-20-6
79-34-5
19-00-5
79-01-6
96-18-4
5 V \~ ,0 ~o{-.."' l b
Date Certified: Jun 18,2020
Expiration: Jun 18, 2023
Sample Size: 1 mL
Components: 14
Storage Condition: Refrig (0-5 ·C)
Certified Reference Material
Purily % Prepared
Concentration'
(GC/MS) (!lg/mL)
95.8 2088'
99.9 2002
99.8 2001
99.5 2002
96.7 2069'
99.9 2001
93.9 2036'
93.9 1964'
98.0 2002
98.9 2001
96.0 2086'
98.6 2001
100.0 2002
97.5 2052'
Certified Analyte
Concentration'
(!lg/mL)
2000
2000
1997
1992
2001
1999
1912
1844
1962
1979
2003
1973
2002
2001
A product with a suffix (-1A. -26. etc. or -01, -02. etc.) on its lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 822-275872-11
, Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen using approximately a 95% confidence level.
Labels and certificates follow U.S. Conventions in reporting numerical values: A comma (.) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal place marker.
The information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Certified By:
Larry Decker, Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/lEe 17025 and certified to ISO 9001 :2015 QR-QRGIlNO-OOl
Rev. 5/18
REPORT ID: 23E081 Page 227 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers ANAB Certificate Number AR-1463
ISO/l EC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories ANAB Certificate Number AT-1339
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations Certificate Number 3774
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square rool of the total
variance of the uncertainty of the components using the following formula: lIa = II -+ 11(111)" + 11(1 ) -+ (II(R l) -his
formula represents uncertainty components from the mass, volume, short-term tability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims mllst hp. made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 228 of 489
·.);( .. Agilent ... Certificate of Analysis
Product Name: Haloalkanes Standard
Product Number: DWM-540-1 Lot Issue Date: 23-Dec-2019
Lot Number: 0006507491 Expiration Date: 31-Jan-2023
Description:
This analytical reference material (RM) was manufactured and verified in accordance with an ISO 9001 registered quality system,
and analyte concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the
95% confidence level for each analyte, determined gravimetrically, is listed below.
Analyte
bromochloromethane
bromodichloromethane
bromoform
bromomethane
carbon tetrachloride
chloroethane
chloroform
chloromethane
dibromochloromethane
1,2-dibromo-3-chloropropane
1 ,2-dibromoethane
dibromomethane
dichlorodifluoromethane
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethene
cis-1,2-dichloroethene
~
ACCREDITED
'8"ri!
REfERENCE MATEmAL
PROOUCER
ISO 17034 Cert No.
AR-1936
CAS# Analyte Lot
000074-97-5 RMOOO09
000075-27-4 RM12585
000075-25-2 RM07516
000074-83-9 RMOO064
000056-23-5 RM07576
000075-00-3 RMOO065
000067-66-3 RM13988
000074-87-3 RM12571
000124-48-1 RM13909
000096-12-8 RM11663
000106-93-4 RMOO018
000074-95-3 RM12878
000075-71-8 RM05289
000075-34-3 RM13775
000107-06-2 RM04655
000075-35-4 RM12062
000156-59-2 RM12063
RM was produced in accordance with TUV USA Inc registered ISO
9001 Quality Management System. Cert # 5610018560026
Page: 1 of 3
www.agilent.com/quality/
CSD-QA-015.1
Concentration ± Uncertainty
200.9 ± 1.0 iJg/mL
200.9 ± 1.0 iJg/mL
201.0 ± 1.0 iJg/mL
200.2 ± 1.0 IJg/mL
201.0 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.4 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 1J9/mL
200.9 ± 1.0 iJg/mL
200.8 ± 1.0 iJg/mL
200.8 ± 1.0 IJg/mL
200.6 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
201.0 ± 1.0 1J9/mL
200.9 ± 1.0 1J9/mL
~
ACCREDITED
1¥I'".ith&
TESTING l ABORATORV
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E081 Page 229 of 489
Certificate of Analysis
Product Number: DWM-540-1 Lot Number:
trans-1,2-dichloroethene 000156-60-5 RM07565
1,2-dichloropropane 000078-87-5 RM12821
1,3-dichloropropane 000142-28-9 RM09825
2,2-dichloropropane 000594-20-7 RM12927
1,1-dichloropropene 000563-58-6 RM15884
cis-1,3-dichloropropene 010061-01-5 RM12891
trans-1,3-dichloropropene 010061-02-6 RM12254
hexachlorobutadiene 000087-68-3 RM09157
methylene chloride 000075-09-2 RM11650
1,1,1,2-tetrachloroethane 000630-20-6 RM12632
1,1,2,2-tetrachloroethane 000079-34-5 NT00390
tetrach loroethene 000127-18-4 RM06491
1 ,1 , i-trichloroethane 000071-55-6 RMOO027
1,1,2-trichloroethane 000079-00-5 RM01175
lrichloroethene 000079-01-6 f-{MOOO29
trichlorofluoromethane 000075-69-4 RMOO017
1,2,3-trichloropropane 000096-18-4 RM09131
vinyl chloride 000075-01-4 RM05458
Matrix: methanol (methyl alcohol)
Storage Conditions: Store Frozen (-25° to -10°C).
Traceability:
0006507491
201.0 ± 1.0 IJg/mL
200.9 ± 1.01Jg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.7 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.6 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
201.0 ± 1.0 IJg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
~
ACCREDITED
-~-__ Wib.i§
A€F"EAENC£ MATERIAL
PRODUCER
ISO 17034 Cert No.
AR-1936
R~v1 v"as produced in accordance with TUV USA Inc registered iSO
9001 Quality Management System. Cert # 5610018560026
Page: 2 of 3
www.agilent.comfquaiityi
CSD-QA-015.1
~
ACCREOITED
--_._-LliiiGW&&
n,STlNG I ABORJ\TORY
ISO 17025 Cert
No. AT-1937
REPORT ID: 23E081 Page 230 of 489
•• : e' A "I .. }:~~.. gl ent ... Certificate of Analysis
Product Number: DWM-540-1 Lot Number: 0006507491
Homogeneity:
This RM was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is no minimum sub-sample
Intended Use:
This RM is intended for the preparation of working reference samples for use in routine laboratory analyses, calibration of
instruments, validation of analytical methods, assessments of measurement methods, and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above, provided the RM is handled and stored in accordance
with the instructions given in this certificate. This certification is nullified if the RM is damaged, contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
ACCREDITED -REFERENCE MA.TERIAL
PROOUCER
ISO 17034 Cert No.
AR-1936
RM was produced in accordance with TUV USA Inc registered ISO
9001 Quality Management System. Cert # 56100 18560026
Page: 3 of 3
www.agilent.comlqualityl
CSD-QA-015.i
Sample lot approver:
~Qo.lA2fORIO
Monica Bourgeois
QMS Representative
~
ACCREDITED
w"iin'(f
TESTING lABORATORY
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E081 Page 231 of 489
~ ~ .... RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30003
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description : VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,OOO~g/mL, P&T Methanol, 1mLlampui
Container Size: 2 mL ---------------------PkgAmt: ___ > __ 1_m_L __________ ___
Expiration Date: September 30, 2024 Storage: O°C or colder
~.
(ACC'REDIT"'iOI
ISO 11034 Aa:redfted.
Refer~ MltQllal Pfoducer
(QI1ifiQtQ Om.01
~.
(ACCiED".T]iiJ
ISOnEC 17021i Accredited
Testing ubofarory
Certif\ate-#322202
CERTIFIED VALUES
Compound
I-Bromo-4-fluorobenzene (BFB)
CAS # 460-00-4 (Lot 2040 1 KO)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Grav. Conc.
(weight/volume)
5,030.0 Ilg/mL
Expanded Uncertainty
(95% C.L.; K=2)
+/-29.5189
+/-'282.0557
+/-288.6541
Gravimetric
Unstressed
Stressed
REPORT ID: 23E081 Page 232 of 489
Column:
105m x 0.S3mm x 3.0~m
Rtx·502.2 (oat.#1091O)
Carrier Gas:
hydrogen-constant pressure 11,0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ 8'C/min. (hold 5 min.)
Inj. Temp:
200'C
Oet. Temp:
250'C
Oet. Type:
FID
Walker Workman -Operations Technician I
o 5 10 15 20 25 30
Minutes
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 27·Jun-2019
Date Passed: 0 I·Jul·20 19
Balance: 1128342314
Manufactured under Restek's ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E081 Page 233 of 489
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/IJECD,
GC/MS, LC/MS, RI, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetriC uncertainty, homogeneity between-ampUl uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Uiral1imetric + U~omoge71eity + U;torage stabiHty + U;hipping stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
• Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) <60°C ~ 60°C up to 7 days
10°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
O°C or colder (Freezer) <25°C ~ 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetriC uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampUl until the material is completely
dissolved.
REPORT ID: 23E081 Page 234 of 489
I Page 37
STANDARDS LOG FOR VOLATILES
Book No: SVl-37
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REPORT ID: 23E081 Page 235 of 489
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Book No: SVl-37
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REPORT ID: 23E081 Page 236 of 489
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Page 39
Book No: SVl-37
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REPORT ID: 23E081 Page 237 of 489
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Page 40
Book No: SVl-37
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REPORT ID: 23E081 Page 238 of 489
STANDARDS lOG FOR VOLATilES
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Book No: SVl-37
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REPORT ID: 23E081 Page 239 of 489
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Page 42
Book No: SVl-37
Standard ID
Name
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Comments:
Standard ID
Name
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Prep. Date
Exp. Date
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Comments:
Standard ID
Name
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Prep. Date
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REPORT ID: 23E081 Page 240 of 489
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Page 43
Book No: SVl-37
Standard ID
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Prep, Date
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Comments:
Standard ID
Name
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REPORT ID: 23E081 Page 241 of 489
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Page 44
Book No: SVl-37
Standard 10 SVl-37-44-0l
Name ¥XX -Jdt G 1.-(;)
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Name
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Comments:
REPORT ID: 23E081 Page 242 of 489
,-
,7 STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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Page 84
STANDARDS LOG FOR VOLATILES
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Page 16
STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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Page 44
STANDARDS LOG FOR VOLATILES
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Book No: SVl-39
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Book No: SVl-39
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STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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Page 66
STANDARDS LOG FOR VOLATILES
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Page 67
STANDARDS lOG FOR VOlATilES
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Page 69
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Page 72
STANDARDS lOG FOR VOlATilES
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Book No: SVl-39
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Page 77
STANDARDS lOG FOR VOLATILES
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Book No: SVl-42
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Page 8S
STANDARDS lOG FOR VOLATILES
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Page 83
STANDARDS LOG FOR VOLATILES
Book No: 5Vl-41
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STANDARDS LOG FOR VOLATILES
Book No: SV1·42
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Page 76
STANDARDS LOG FOR VOLATilES
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Page 86
STANDARDS LOG FOR VOLATILES
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Book No: SVl-41
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Page 3
STANDARDS lOG FOR VOLATILES
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REPORT ID: 23E081 Page 411 of 489
Page 65
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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REPORT ID: 23E081 Page 412 of 489
Page 73
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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REPORT ID: 23E081 Page 413 of 489
Page 68
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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REPORT ID: 23E081 Page 414 of 489
,,{:PI
INTERNATIONAL
Date manufactured: 5/5/2022
Original issue date: 5/5/2022
Catalog No.: Lot No.: Storage:
Z-G34 481165 ::; -10 °C
-126047-01
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 5
Solvent:
prr Methanol
Expiration
Date:
6-Nov-2023
Description:
Custom Volatiles Mix, 73-6047, Various
Concentrations, 1 mL
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!lL
2-nitropropane 79-46-9 97.7 219.7.lP 1998 ± 110
allyl chloride 107-05-1 98.9 227.1.2P 1991 ± 120
benzene 71-43-2 99.99 146.1.9P 2003 ± 110
bromobenzene 108-86-1 100 147.7.IP 1999 ± 140
bromochloromethane 74-97-5 99.7 148.1.3P 2008 ± 110
bromodichloromethane 75-27-4 98.7 149.1.11P 1996 ± 110
bromoform 75-25-2 99.3 150.7.2P 1995 ± 110
n-buty Ibenzene 104-51-8 99.2 151.7.3.2P 1997 ± 110
sec-butylbenzene 135-98-8 99.5 152.1.2.lP 1999 ± 110
tert-butylbenzene 98-06-6 99.9 153.29.lP 1999 ± 110
carbon tetrachloride 56-23-5 100 154.9.IP 2005 ± 110
chlorobenzene 108-90-7 99.9 155.29.1P 2008 ± 110
2-chloroethanol 107-07-3 98.5 217.1.2.lP 2006 ± 120
chloroform 67-66-3 99.8 156.7.lP 1998 ± 110
chloroprene 126-99-8 98.9 315.5.22P 1982 ± 140
2-chlorotoluene 95-49-8 99.5 157.7.lP 2014 ± 110
4-chlorotoluene 106-43-4 99.9 158.9.3P 2015 ± 110
REPORT ID: 23E081 Page 415 of 489
Certificate of Analysis Page 2 of 5
Catalog No.: Z~G34~126047~Ol
cis-I,2-dichloroethylene
dibromochloromethane
1 ,2-dibromo-3-chloropropane
1,2-dibromoethane
dibromomethane
1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
cis-l,4-dichloro-2-butene
trans-I,4-dichloro-2-butene
I,I-dichloroethane
1,2-dichloroethane
I,I-dichloroethylene
trans-I,2-dichloroethylene
dichlorofluoromethanc (Freon 21)
1,2-dichloropropane
1,3-dichloropropane
2,2-dichloropropane
1,I-dichloropropylene
cis-I,3-dichloropropylene
trans-I,3-dichloropropylene
1 A-dioxane
ethyl ether
ethyl methacrylate
ethylbenzene
Manufactured By:
Bradley Richter
Production Chemist I
Lot No.: 481165
156-59-2 98.5
124-48-1 98.6
96-12-8 98.6
106-93-4 99.9
74-95-3 99.8
95-50-1 99.8
541-73-1 99.8
106-46-7 99.9
1476-11-5 98
110-57-6 98
75-34-3 98.1
107-06-2 99.9
75-35-4 99.98
156-60-5 99.7
75-43-4 98
78-87-5 99.7
142-28-9 100
594-20-7 99
563-58-6 99
10061-01-5 99.5
10061-02-6 99
123-91-1 99.93
60-29-7 99.8
97-63-2 99.5
100-41-4 100
Certified By:
Paul Johnson
Quality Control Supervisor
Expiration Date: 11/6/2023
166.1.7.1P 2000 ± 110
159.1.8.1P 2001 ± 110
160.7.2.3P 1996 ± 110
161.9.1P 1999 ± 110
162.1.2P 2012 ± 120
43.7.1P 2006 ± 110
44.1.2P 2008 ± 110
45.29.1P 2030 ± 110
209.1.5P 2003 ± 110
201.1.l7.IP 1996 ± 110
1 63.247.3.2P 1985 ± 120
164.158.1P 1999 ± 110
165.1.4P 2001 ± 110
167.9.IP 2000 ± 110
986.5.4P 1960 ± 140
168.8.IP 2002 ± 120
169.7.3P 2001 ± 140
170.l58.I.IP 1999 ± 120
I 71.158.2.4P 1998 ± 120
1 72.7.6.1 P 2001 ± 110
173.7.IIP 1988 ± 110
223.1.4P 39980 ± 2000
226.9.1P 1998 ± 110
216.7.IP 1993 ± 110
174.7.1P 2001 ± 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 416 of 489
Certificate of Analysis Page 3 of 5
Catalog No.: Z-G34-126047-01
hexachlorobutadiene
iodomcthane
isobutyl alcohol
isopropylbenzene
4-isopropyltoluene
methyl acrylonitrile
methyl methacrylate
methyl acrylate
methylene chloride
naphthalene
nitrobenzene
propionitrile
n-propylbcnzene
styrene
1,1,I,2-tetrachloroethane
1,1,2,2-tetrachloroethane
tetrachloroethylene
tetrahydrofuran (THF)
toluene
1,2,3-trichlorobenzene
1,2,4-trichlorobenzene
I,I,I-trichloroethane
1,I,2-trichloroethane
trichloroethylene
1,2,3-trichloropropane
Manufactured By:
Bradley Richter
Production Chemist I
Lot No.: 481165
87·68·3 98
74-88-4 99.9
78-83-1 100
98-82-8 99.9
99-87-6 99.9
126-98-7 98
80-62-6 99.8
96-33-3 98.5
75-09-2 99.99
91-20-3 99.8
98-95-3 100
107-12·0 99.8
103-65-1 99.7
100-42-5 99.5
630-20-6 99.8
79-34-5 99.4
127-18-4 100
109-99-9 99.99
108-88-3 100
87-61-6 99.8
120-82-1 99.6
71-55-6 99.6
79-00-5 99.6
79-01-6 100
96-18-4 99.5
Certified By:
Paul Johnson
Quality Control Supervisor
Expiration Date: 1116/2023
47.1 58.3.1P 2003 ± 120
203.29.2P 2000 ± 110
220.7.2P 40000 ± 2000
176.9.3P 2004 ± 110
I 77.9.3P 1988 ± 110
212.286.1.1P 20010 ± 1100
231.7.3P 2018 ± 120
349.7.IP 1999 ± 110
178.271.1P 2010 ± 110
26.9.IP 2020 ± 110
94.7.1P 1985 ± 110
218.7.3P 20000 ± 1000
179.7.2.2P 1998 ± 110
180.9.4P 2001 ± 110
181.7.2.9P 1997 ± 110
182.8.2P 1998 ± 120
183.1.2P 2001 ± 110
299.271.2P 2006 ± 110
I 84.48.lP 2003 ± 110
185.1.2P 1999 ± 110
54.29.lP 1987 ± 110
187.247.1.3P 1995 ± 110
195.7.1.6P 1999 ± 110
188.29.2P 2016 ± 110
I 89.1.3P 2001 ± 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 417 of 489
i>
Certificate of Analysis Page 4 of 5
Catalog No.: Z-G34-126047-01 Lot No.: 481165 Expiration Date: 1116/2023
1,1 ,2-trichloro-1 ,2,2-trifluoroethane (Freon 113) 76-\3.1 99 270.1 58.3P 1996 ± 120
1,2,4-trimethylbenzene 95-63-6 98.7 190.7.IP 1999 ± 110
1,3,5-trimethylbenzene 108-67-8 99.5 191.7.lP 2001 ± 110
m-xylene 108-38-3 99.7 193.7.1.2P 2001 ± 110
o-xylene 95-47-6 99 192.29.3P 1998 ± 120
p-xylene 106-42-3 99.9 194.7.IP 1999 ± 110
*Not 8 certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.0181n(x+31) + 0.1157) + 636.54i3.
202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Paul Johnson
Quality Control Supervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 418 of 489
Certificate of Analysis Page 5 of 5
Catalog No.: Z-G34-126047-01 Lot No.: 481165 Expiration Date: 1116/2023
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Ue = the combined uncertainty Ue = ~LUj2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Nov-2023
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Paul Johnson
Quality Control Supervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 419 of 489
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
CERTIFICATE OF ANALYSIS
Catalog No: OGAD-001
Description: Oxygenate Gasoline Additive Standard
Lot: 222011266
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Component
MtBE
EtBE
Isopropyl ether
TAME
t-Butanol
Signal Word: Danger
This Certified Reference Material was verified hi accordance with ISOIIEC 17025
CAS #
1634-04-4
637-92-3
108-20-3
994-05-8
75-65-0
Date Certified: Jan 19, 2022
Expiration: Jan 19, 2025
Sample Size: 1 mL
Components: 5
Storage Condition: Refrig (0-5 ·e)
Certified Reference Material
Purity % Prepared Certified Analyte
(GC/MS)
Conceritration' Concentration'
(H9linq (f./g/mL)
1997
2002
2010
1983
9965
A product with a suffix (-1A, -2B, etc. or -01, -02, etc.) on lis lot number has had Its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 684/289871-17
1 Certified Analyte Concentration" Purity x Prepared Concentration.
The Uncertainty associated with Ihe certlfledcoricentration reported on this certificate is ±2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square rool of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor' of K"2 Is chosen uslng,llPproxlniately a 95% confidence level.
Labels and certlijcates follow't;I,l)' Cohventlons in reporting numerical values: A comma (,) Is used to separate units of one-thousand or greater. A period (.) Is used as
a decimal place rharker. "
The Information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard Information: Pli~ase refer to the SOS for Information regarding the hazards associated with using this material.
This product was prepared according to In-house procedures and Is guaranteed to be homogeneous.
Certified By: ~ Larry Decker. Organic QC MBnager--------
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 QA·OAG/INO·OOl
Rev. 7120
REPORT ID: 23E081 Page 420 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the, front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: Us = .I(u(V»)2 + (u(m»2 + (u(IV»)2 + (u(Rb»2 I his
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 Is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 421 of 489
~PI
INTERNATIONAL
Date manufactured: 8/24/2022
Original issue date: 8/24/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • Date Received:
SIS Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-G34 492308 ::: -10°C
Date:
23-Aug-2027 2-Chloroethyl Vinyl Ether Solution, 2,000 mgIL, 1 mL
PIT Methanol
-020145-02
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (OC) or gas chromatograph/mass spectrometry (OC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
2-chlorocthylvinyl ether 110-75-8 99.8 145.I.SP 2010 ± 110
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCfMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N.!. S. T. Test No. 8221264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E081 Page 422 of 489
Certificate of Analysis
S¥("-38~o~~n./
Page 2 of 2
Catalog No.: Z-G34-020145-02 Lot No.: 492308 Expiration Date: 8/23/2027
(95% confidence) values listed are detennined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is detennined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perfonn daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025 :20 17 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
con finned by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kue : u==Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k==2, Ue == the combined uncertainty Ue == '\1L,U;2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short tenn and long tenn testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Aug-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Sanquetta Coakley
Production Chemist I
Certified By:
Dominique Lindner
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 423 of 489
125 Market Street
New Haven, CT 06513
USA
Catalog No: M-8010R-1-04-10X
Description: 1-Chlorohexane
Lot: 221031011
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Component
1-Chlorohexane
This Certified Reference Material was verified In accordance with ISO/IEC 17025
CAS#
544-10-5
Date Certified: Mar 3,2021
Expiration: Mar 3,2031
Sample Size: 1 mL
Components: 1
Storage Condition: Ambient (>5 'C)
Certified Reference Material
Purity % PrElpared Certified Analyte
Concentration' Concentration'
(GC/MS) (f.'g/mL) (f.'g/mL)
99.0 2020 2000
A product with a suffix (-1A, -2B, etc. or -01,-02, etc.) on,Us lot number has had Us expiration date extended and is identical to the same lot number without the suffix.
2 All weights are traceable through NIST, Test No. 684/289871-17
, Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty assoclatedwlththecertilied concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation ,equal to the po'sitive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen usln,9"approxlmately a 95% confidence level.
Labels and certificates follow,\;i.S, Conventions in reporting numerical values: A comma (,) Is used to separate units of one-thousand or greater. A period (.) Is used as
a deCimal place marker. '
The Information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information: Please refer to the SDS for Information regarding the hazards associated with using this material.
This product watprepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
~--q?--6---.­C----L-"?
---'~'.'~--.~-.--...... --.-~.-~-.-.-------.~.----Larry Decker, Organic.:: ac Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEe 1'7025 and certified to ISO 900'1:2015 QR-ORGfINO-OOl
Aov.7/20
REPORT ID: 23E081 Page 424 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification andlor
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: un = his
formula represents uncertainty components from the mass, volume, short-term lability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k:=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 425 of 489
CPI
INTERNATIONAL
Date manufactured: 6/24/2022
Original issue date: 6/24/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
Z-G34 484154 :S.1O °C PIT Methanol
Expiration
Date:
23-Jun-2027 1,2,3-Trimethylbenzene Solution, 2,500 mg/L, I mL
-020869-08
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
1,2,3-trimethylbenzene 526-73-8 92.7 869.8.4.lP 2536 ± 140
·Not a certified va1ue
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y'3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. 1. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E081 Page 426 of 489
Certificate of Analysis
bVlr~Og--l8
Page 2 of 2
Catalog No.: Z-G34-020869-08 Lot No.: 484154 Expiration Date: 6123/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty U c = ~IUj 2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Jun-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
Jared BaH
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 427 of 489
CPI
INTERNATIONAL
Date manufactured: 10/15/2020
Original issue date: 10/15/2020
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • Date Received:
SIS Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-G34 426643 :5 -10 Degrees
C
Pff Methanol
Date:
14-0ct-2025 t-Butyl Alcohol Solution, 50,000 mgIL, 1 mL
-020511-06
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
2-methyl-2-propanol 75-65-0 99.8 511.7.lP 49900 ±2500
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and A8TM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following;
% Change == (-0.018In(x+31) + 0.1157) + 636.54y'3.202
where x == boiling point of the most volatile analyte in the mix (degrees K)
y == boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E081 Page 428 of 489
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020232-1 0 Lot No.: 476834 Expiration Date: 3/6/2025
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02.QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOllEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty U c = --Jr,Uj2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Mar-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 429 of 489
/'" ~ ....
RESTEK CERTIFIED REFERENCE M~T~_RIA~ _____ "" __ . ~~
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30006
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative detennination of the analyte(s) listed.
Lot No.: A0183812
Description : VOA Calibration Mix #1
VOA Calibration Mix #1 5,000l1g/mL, P&T MethanollWater(90:10),
1mUampui
Container Size : 2 mL Pkg Amt: > 1 mL -------------------------------------------Expiration Date: July 31, 2025 Storage: DoC or colder
-----------------------Ship: Ambient
w...-MoI .... frodiKor
CodIfict«> tl2J.'l.Ol
C E R TI FIE 0 V A L U E S
, . Compound , ,Grav. C.onc. " E.xpanded Uncertainty _
• (weight/volume) (95% C.L.; K=2)
Acetone 5,031.8 Ilg/mL +/-29.2555 Ilg/mL Gravimetric
CAS# 67-64-1 (Lot SHBN3661 ) +/-303.5928 Ilg/mL Unstressed
Purity 99% +/-304.3136 Ilg/mL Stressed
2 2-Butanone (MEK) 5,041.0 !J.g/mL +/-29.3088 Ilg/mL Gravimetric
CAS # 78-93-3 (Lot SHBN2844) +1-304.1459 Ilg/mL Unstressed
Purity 99% +/-304.8680 Ilg /mL Stressed
3 4-Methyl-2-pentanone (MIBK) 5,041.5 Ilg/mL +1-29.3117 Ilg/mL Gravimetric
CAS# 108-10-1 (Lot SHBN3601) +/-304.1760 Ilg/mL Unstressed
Purity 99% +/-304.8982 Ilg/mL Stressed
4 2-Hexanone 5,026.8 Ilg/mL +1-29.2264 Ilg/mL Gravimetric
CAS# 591-78-6 (Lot MKCM4072) +1-303.2911 Ilg/mL Unstressed
Purity 99% +/-304.0112 Ilg/mL Stressed
Solvent: P&T MethanollWater (90: 10)
CAS # 67-56-117732-18-5
Purity 99%
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E081 Page 430 of 489
COhl~l1:
105m" O.S3mm x 3.0~m
Rtx-S02.2 (cat.#10910,
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
4O'C (hold 2 min., to l40'C
"rC/min. (hold 5 min.,
Inj. Temp:·
2OO'C
Bet. Temp:
250'C
BrttIany Federlnko -Operations Tech I
01-Aug-2020 rev.
o 5 10 15
Minutes
20 25 so
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific Instrument, method, and application.
Date MIxed: 07-Apr-2022
Date Passed: 1I-Apr-2022
Balance: B2S 1644995
Manufactured under Reatek'IISO 9001:2015
Registered Quality System
Certificate #FM 80397
2of3
REPORT ID: 23E081 Page 431 of 489
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-603-M-5X
Description: Acrolein & Acrylonitrile
Lot: 223021463
Date Certified: Feb 21,2023
Expiration: Jun 21, 2023
Sample Size: 1 mL
Components: 2
Tel [phone]
Fax [phone]
www.AccuStandard.com
Solvent: Methanol (90%)
Water (10%) Storage Condition: Freeze «-10°C)
Hazards: Refer to SDS for complete safety information
Certified Reference Material
Component
Acrolein
Acrylonitrile
Signal Word: Danger
CAS#
107-02-8
107-13-1
Purity' %
This Certified Reference Material was verified in accordance with ISO/IEC 17025 (AT-1339) and ISO 17034 (AR-1463)
• Weight compensated to 100% purity.
Prepared Certified Analyte
Concentration' Concentration'
(f1g/ml) (Mg/mL)
5808' '
5010
5001
5000
A product with a suffix (-lA, -2B, etc. or ,01, -02, eto.) on.its lot number has had Its expiration date extended and Is identical to the same lot number without the suffix.
, Certified Analyte Concentration = Purity x Prepared Concentration,
The Uncertainty associated with the certified concentration reported on this certificate Is ±2.4%, This value Is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components, A normal distribution is assumed and a coverage
factor of K=2 Is chosen using approximately a 95% confidence level.
'All weights are traceablethrough NIST,Test No. 684/291344-18 & 684/292805-19
, Purity/Identity determined by one or more of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and. certificates follow U.S. Conventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal place marker.
The Information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information.: Please refer to the SOS for Information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous,
Certified By:
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 QR-ORG/INO-OO1
Rev. 7/20
REPORT ID: 23E081 Page 432 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: un = U 1/ 111 1/ Ii his
formula represents uncertainty components from the mass, volume, short-term tability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 433 of 489
CPI"~
INTERNATIONAL
Date manufactured: 10/4/2022
Original issue date: 10/4/2022
Catalog No.: Lot No.: Storage:
Z-G34 489953 S -10°C
-020354-09
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 2
Solvent:
PIT Methanol
Expiration
Date:
3-0ct-2027
Description:
2-Butanol Solution, 50000 mg/L, 1 ml
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (aC) or gas chromatograph/mass spectrometry (aC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mf!fL
2-butanol 78-92-2 99.8 354.7.1P 50000 ± 2600
·Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.0181n(x+31) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point ofthe solvent (degrees K)
This model assumes the container is stored at _10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. 1. S. T. Test No. 822/264157-00. Concentration (correctfor purity) and uncertainty
REPORT ID: 23E081 Page 434 of 489
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020354-09 Lot No.: 489953 Expiration Date: 10/3/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025 :20 17 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025 :20 17 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, U c = the combined uncertainty U c = '/''Lu j
2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 3-0ct-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 435 of 489
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-08S-10X
Description: Cyclohexane
Lot: 219101390
Solvent: Methanol
Date Certified: Oct 25, 2019
Expiration: Oct 25, 2029
Sample Size: 1 mL
Components: 1
Tel [phone]Q
Fax [phone]
www.AccuStandard.com
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 DC)
Signal Word: Danger
Component CAS #
Cyclohexane 110-82-7
.' ",".'
":·h:~.
This Certified Reference Material was verified'\n'a~COrda~~Q'viith ISOIIEC 17025
Certified Reference Material
... r~-.r.'~:,'n .. ,
AR-1463
Purity %
(GG/MS)
100.0
Prllpared
ConcentrAtjon'
(~Mbl)
Certified Analyte
Concentration'
(j.Jg/mL)
2002
A product with a suffix (-1A, -2B, etc. Qr -01 ,:-02,eigyl)n1t~'lot number has had its expiration date extended and Is identical to the same lot number without the suffix.
'All weights are traceable through NIST, T~st Np,68412~9871-17
, Certified Analyte Concentration = Purity x prep'a!tid Concentration.
The Uncertainty associated wlth@i c';:rili:f~c;!:¢Srj(:entration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviatiQ!l~qu:al to !be pokHive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 is chosen usinli:approxtm~tely a 95% confidence level.
labels andcerlificates folloW\.J,S, c;onventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater, A period (.) is used as
a decimal place marker.' .,'.
The informatl~nAn th\~:·¢iirti(iq?te may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Informatloo.,J?Jease refer to the 50S for information regarding the hazards associated with using this material.
This product wa!f:~r!ipared according to in-house procedures and Is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic OC Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 OR-ORGIINCJ.OOl
Rs .... 7/20
REPORT ID: 23E081 Page 436 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
S-Vl-b~-o1-n
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua == .I(u(Y»2 + (u(m»)2 + (u(ly»)2 + (u(RO»)2 I his
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and limit of liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 437 of 489
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
S\I\-~y .. 'O-OI..
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-09S-12.5X
Description: Methylcyclohexane
Lot: 222081023
Solvent: Methanol
Date Certified: Aug 2, 2022
Expiration: Aug 2, 2032
Sample Size: 1 mL
Components: 1
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 ·C)
Signal Word: Danger
Component CAS#
Methylcyclohexane 108-87-2
This Certified Reference Material was verilied in accordance with ISOIIEC 17025
Certified Reference Material
Purity %
(GC/FID)
100.0
~tepared
Concentration'
J!19 /mL l
2538
Certified Analyte
Concentration'
(Hg/mL)
2538
A product with a suffix (-1A. -2B. etc. or -01, -02, etc.) 60 Its lot number has had Its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 684/289871-17
, Certified Analyte Concentration" Purity xPrepaied Concentration.
The Uncertainty associated' with lhe certified concentration reported on this certificate is ±2.4'10. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen uslngapproxlrl1ately a 95% confidence level.
Labels and certificates follow U.S" Conventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal place marker,. .
The information.on this'certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard Information: PI~ase iefer to the SDS for information regarding the hazards associated with using this material.
This product was pr~pared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 QR·ORGilNO·OO1
Rev. 7/20
REPORT ID: 23E081 Page 438 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is deSigned for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .f(u(Y»)2 + (uCm»)! + (uClv))2 + (u(RO»)2 This
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. legal Notice and Limit of liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 439 of 489
125 Marke1 Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
~ V\--?q -lo·~04
CERTIFICATE OF ANALYSIS
Catalog No: S-6524-0.25X
Description: Methyl acetate
Lot: 222031007
Solvent: Methanol
Date Certified: Mar 2, 2022
Expiration: Mar 2, 2032
Sample Size: 1 mL
Components: 1
Hazards: Refer to SOS for complete safety information Storage Condition: Ambient (>5 ·C)
Signal Word: Danger
Component CAS #
Methyl acetate 79-20-9
This Certified Reference Material was verified in accordance with ISOIIEC 17025
Certified Reference Material
Purity %
(GC/MS)
100.0
Prepared
Conceritratl.on'
··(WJIn'lL)
Certified Analyte
Concentration'
(fl9 /mL)
2520
A product with a suffix (-1A, -28, etc. Of -01, -02, etc.) on Us lot number has had its expiration date extended and is identical to the same lot number without the suffix.
, All weights are traceable through NIST, Test No. 6841289871-17
\ Certified Analyte Concentration = PUrity x Prepared Concentration.
The Uncertainty associated. With the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to :the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen uslngapproxtrnately a 95% confidence level.
Labels and certificates folloW\.i.s.Conventions in reporting numerical values: A comma (.) is use'd to separate units of one-thousand or greater. A period·(.) is used as
a decimal place marker. ..
The information.()n this eaitlfi.cate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information; Please refer to the SDS for information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic ac Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/lEe 17025 and certified to ISO 9001 :2015 QR·ORGlINO·OO1
Rev. 7120
.J
REPORT ID: 23E081 Page 440 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = ./{u(V»2 + {u(m))2 + {u(JV))2 + {u(RO»2 This
formula represents uncertainty components from the mass, volume, short-term dtability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and LImit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 441 of 489
CPI
INTERNATIONAL
Date manufactured: 3/2/2022
Original issue date: 3/212022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Analysis
Solvent:
Date Received:
Page 1 of 2 Rev 0
Description:
Z-G34 476834 :S -10 °C PIT Methanol
Expiration
Date:
6-Mar-2025 Vinyl Acetate Solution, 2,500 mg/L, 1 mL
-020232-10
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (OC) or gas chromatograph/mass spectrometry (OCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mf!/L
vinyl acetate 108-05-4 99.9 232.7.lP 2500 ± 160
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54i3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at _10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N.!. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E081 Page 442 of 489
S'VI-3~~o~"'lq
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020232-10 Lot No.: 476834 Expiration Date: 3/6/2025
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIlEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-Oll. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u==ku c : u==Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty U c == ~I,u; 2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Mar-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 443 of 489
REPORT ID: 23E081 Page 444 of 489
,(> f)
.o~~:~ .. Agilent
" a '1-
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~~~-~~';;;,." .. . ..... :':
-";,.;'/"~) ..... hH:n;:;;, ... ~-~hi.s-YJ'~>;,;"'N:',U;';'''),I';#'h';.7N;.r;~J',F;;;';";J''':''PI';;;;;:,/,,·j.f';JjJ/i;-;>;X;/J;~>N''''''''';~·;''~J'';~>},:;U""J./.P.J').r/h'):r;./J-;/;;'"J;;".N;;:";#;;;"'N~"'-";;;n~jj;~·>; .. ;.,;,,~;'"';:U~;JJ-I';"'N.I;,;;.,..;,;..",-;;;/;. ... ,.~:.,,,,;;';,>;,-,;,,';;':';;.iJ-,~:
~~~.~J!,~~~~;ii-;,~;:~';i~!ii;iiil:I;::'.I.:?')!'!
ACCA[;DITED .. ~,., .. -,-~.-.---~-
r\l:rrfll~NC" MArUUAl,
i>UOl)UCf.H
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV/SUD registered ISO
9001 :2015 Quality Management System. Cert# 951215321
Page: 2 of 2
www.agilent.com/quality/
CSD-QA-015.1
Sample lot approver:
~C('f1)~Ul
Monica Bourgeois
01\115 Representative
ISO 17025
REPORT ID: 23E081 Page 445 of 489
CPI
Date manufactured: 515/2022
Original issue date: 515/2022
Catalog No.: Lot No.: Storage:
Z-G34 481102 :S -10°C
-020200-04
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
PIT Methanol
Expiration
Date:
4-May-2027 Carbon Disulfide Solution, 5,000 mg/L, 1 ml
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ID!!fL
carbon disulfide 75-15-0 99.9 200.24.IP 5044 ± 250
·Not a certitied value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCIMS. It may aslo be used for various US EPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for·
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at _10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 8221264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E081 Page 446 of 489
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020200-04 Lot No.: 481102 Expiration Date: 5/412027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty Uc = --JIuj
2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 4-May-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Paul Johnson
Quality Control SUpervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 447 of 489
/ ~ ....
RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30631
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0183952
~MoIOIIiI"")dUc"
CoilIIIat.t32l201
IS05C 1702$ Aoaediled
Tos\iIlg~atory
~132Wl2
Description : tert-Amyl Alcohol Standard SVt-3~-D)'-f]
Tert-Amyl Alcohol 10, OOOjJg/mL, P& T Methanol, 1 mLiampul
Container Size: 2 mL ~~---------------Expiration Date: April 30, 2027 ------------------
Compound
tert-Amyl alcohol
CAS # 75-85-4 (Lot STBB I 898V)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Pkg Amt: > 1 mL ----~-----------Storage: O·G or colder
Ship: Ambient
CERTIFIED VALUES
-
Grav. Conc.
(weight/volume)
10,010.0 flg/mL
Expanded Uncertainty
(95% C.L.; K=2)
+1-92.6344
+1-226.1085
+1-232.0226
flg/mL
flg /mL
flg/mL
Gravimetric
Unstressed
Stressed
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E081 Page 448 of 489
Column:
105m x 0.53mm x 3.01lm
Rtx·502.2 (cat.#10910)
CanierGas:
hydrogen-constant pressure 11.0 psi.
Temp, Program:
4O'C (hQld 2 min.) to 24O'C
@ S·C/mln. (hold 5 min.)
Inl. Temp:
200'C
DeL Temp:
25O'C
Det. Type:
FlO
Whitney Bennett· Operation Tech I
Christie MUIs • Operations Technician n
o 1-Aug-;!020 rev.
o 5 10 15
Minutes
20 25 so
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 12·Apr·2022
Date Passed: 13-Apr.2011
Balance: 1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality Syelem
Certificate #I'M 80397
20f3
REPORT ID: 23E081 Page 449 of 489
125 Market Street
New Haven. CT 06513
USA ~ AccuStandard®
~ -?]'t '.'-61.-\ -r:3-
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-04S-1OX
Description: Isooctane
Lot: 221031139
Solvent: Methanol
Date Certified: Mar 11, 2021
Expiration: Mar 11, 2031
Sample Size: 1 mL
Components: 1
Tel [phone]
Fax [phone]
www.AccuStandard.com
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 ·C)
~~~ Certified Reference Material
Signal Word: Danger
Component CAS # Purity % Prepared Certified Analyte
Concentration' Concentration'
(GC/MS) (lJglmL) (fJg/mL)
Isooctane 540-84-1 99.4 2001 1989
2-)2) ~_ 'f'(\'~~ ~
.D '}leo 'It ( 1-..,... O')J
A product with a suffix (-1A. -2B. etc. or -01. -02. etc.) on Its lot number has had Its expiration date extended and Is Identical to the same lot number without the suffix.
2 All weights ere traceable through NIST. Test No. 684/289871-17
, Certified Analyte Concentration" Purity. x Prepared Concentration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2,4'10. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to t/)e positive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 Is chosen uSi.tig approximately a 95% confidence level.
Labels and certificates follow·U.S.COnventions In reporting numerical values: A comma (.) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal pJaclimark~r;
The Information. on this'certlflcate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard InformatJon: Please refer to the SOS for Information regarding the hazards associated with using this material.
This product was prepared according to In-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Daoker, Organlo ac Manager
Page 1 of 1 For use In routine laboratory analysiS.
AccuStandard is accredited to ISO 17034, iSOIlEe 17025 and certified to ISO 9001 :2015 QR·ORGlINO·OOI
Rev. 7/20
REPORT ID: 23E081 Page 450 of 489
/ ~" RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30003
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description: VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,000~g/mL, P&T Methanol, 1mLlampui
Container Size: 2 mL ~~--------------Pkg Amt: > 1 mL ----~-----------Expiration Date: September 30, 2024 Storage: O°C or colder
~ •..... \ .. ;.
~"
f@EDlT]o)
ISO tlIl34·At<redHed.
R&fQreotQ ~tQlIOlI PtoducClr
CQl1ifla.IQ'~22l.0~
d
IsonEC 17025 Ac .. edlted
ToItlI'l911borarory
Cor1iliot .. 32l2.02
CERTIFIED VALUES
'. Compound
I-Bromo-4-fluorobenzene (BFB)
CAS # 460-00-4 (Lot 20401 KO)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Grav. Cone.
(weight/volume)
5,030.0 I!gfmL
Expanded Uncertainty
(95% C.L.; K:;;:2)
+f-29.5189
+/-'282.0557
+f-288.6541
I!gfmL
J.lgfmL
J.lgfmL
Gravimetric
Unstressed
Stressed
REPORT ID: 23E081 Page 451 of 489
Column:
105m x 0.53mm x 3.0~m
Rtx·S02.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ SOC/min. (hold 5 min.)
Inj. Temp:
200"C
Oet. Temp:
250"C
Oet. Type:
flO
Walker Workman· OperatJons Technician I
5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 27·Jun·2019
Date Passed: 01.Jul-2019
Balance: 1128342314
Manufactured under Restek'$ ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E081 Page 452 of 489
cpr
INTERNATIONAL
Date manufactured: 7/1312022
Original issue date: 7113/2022
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Analysis Date Received:
Page 1 of 2 Rev 0
Catalog No.: Lot No.: Storage: Solvent: Expiration
Date:
12-Jul-2027
Description:
Z-G34 484785
-122455-05
Certified Values:
prr Methanol Method 8260 Internal Standard Mix, 3·30,2,500
rng/L, 1 ml
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mg/L
chlorobenzene-d5 3114-55-4 99.5 128.120.1P 2504 :J: 130
1,2-dichlorobenzene-d. 2199-69-1 99.7 247. 29.3P 2514 ± 130
1,4-difluorobenzene 540-36-3 99.3 129.158.1.2P 2523 ± 140
'Not. certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change"" (-0.018ln(x+31) + 0.1157) + 636.54i3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °c and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
REPORT ID: 23E081 Page 453 of 489
Certificate of Analysis
)\11--:,ff-01-((,
Page 2 of 2
Catalog No.: Z-G34-122455-05 Lot No.: 484785 Expiration Date: 7/12/2027
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are detennined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is detennined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consfstent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kue : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, U e = the combined uncertainty U e = -iI,u/ where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability ofthis product is based upon rigorous short tenn and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 12-Jul-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E081 Page 454 of 489
~ ..
RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30240
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic plus
sv I ~J~ ~ 10-\1-
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative andlor quantitative determination of the analyte(s) listed.
Lot No.: A0192204
Description : 8260A Surrogate Mix
8260A Surrogate Mix 2,500f-lg/mL, P&T Methanol, 1mUampui
Container Size : 2 mL --------------------PkgAmt: __ >_1 __ m_L __________ __
Expiration Date: December 31,2027 Storage: O°C or colder
Ship: Ambient
CERTIFIED VALUES
Expanded
. Elution - _ Compound CAS # Lot # Purity Grav. Cone. Uncertainty *
Order . (weight/volume) (95% C.L., K=2)
Dibromofluoromethane 1868-53-7 022013 99% 2,517.6 IlglmL +/-141.4279
2 1,2-Dichloroethane-d4 17060-07-0 PR-32845 99% 2,507.6 Ilg/mL +/-140.8661
3 Toluene-d8 2037-26-5 1-27008 99% 2,511.4 IlglmL +/-141.0796
4 I-Bromo-4-iluorobenzene (BFB) 460-00-4 184975 99% 2,517.8 Ilg/mL +/-141.4391
* Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
.-..
01-Nov-2022 rev. RESTEK 10f3
REPORT ID: 23E081 Page 455 of 489
Column:
105m x O.53mm x 3.0~m
Rtx·502.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 pSi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ SOC/min. (hold 5 min.)
Inj. Temp:
2oo"c
Det. Temp:
250"C
Det. Type:
FlO
Split Vent:
40ml/min
Inj. Vol
1111
f;~d t{ltt(.
Daniel Wasson· Operations Tech I
Chrislie Mills· Operations Tech II· ARM QC
01-Nov-2022 rev.
o
Quality Confirmation Test
5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
_____ acG.m)l<lJJce.~or .QJilimal results in your.1ah.-cooditions..shouJdbaadjusted for your
specific instrument, method, and application.
Date Mixed: 02-Doc-2022 Balance Serial #
Date Passed: 06-Doo-2022
1128342314
Manufactured under Restek's ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
2013
REPORT ID: 23E081 Page 456 of 489
~ .....
RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 575702
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0191824
Description: Custom Revised 8260 Megamix
Custom Revised 8260 Megamix 2,000 -40,000~g/mL, P& T Methanol,
1mUampul
Container Size : 2 mL ~~---------------
Pkg Amt: _>_1.:...:..:.m:;;L~ ____ _
Expiration Date: November 30,2025 Storage: O°C or colder
Ship: Ambient
D
15011134,....._'"
~MReNlPicduceJ
C~J.J22lhI
CERTIFIED VALUES
--'--" _c.. .• ' -" __ • -... ' . ._'_ " ~.' ,;.~. • " Expanded
Elution Compound CAS # . Lot # Purity Grav. Cone. Uncertainly'
Order
I I (weight/volume) (95% C.L.; K=2)
Dichlorofluoromethane (CFC-21) 75-43-4 12841600 99% 2,000.0 !1g/mL +/-69.1292
2 Dielhyl cther (ethyl ether) 60-29-7 SHBP5008 99% 2,011.0 !1g/mL +/-69.5094
3 1,1 ,2-Trichlorotrifluoroethane (CFC-113) 76-13-1 00016133 99% 2,008.0 !1g/mL +/-69.4057
4 I,I-dichloroethene 75-35-4 SHBG8609V 99% 2,001.6 !1g /mL +/-69.9029
5 Iodomethane (methyl iodide) 74-88-4 RD220125 99% 2,007.5 !1g/mL +/-69.3884
6 Allyl chloride ( 3-chloropropene ) 107-05-1 RP220405A 99% 2,011.0 I1g/mL +/-69.5094
7 Methylene chloride (dichloromethanc) 75-09-2 SHBPI417 99% 2,001.6 flg/mL +1-69.9056
8 trans-I,2-Dichloroethene 156-60-5 MKBH9850V 99% 2,001.7 flg/mL +1-69.9064
9 I,I-Dichloroethane 75-34-3 760200 99% 2,001.1 flg /mL +/-69.8864
10 Chloroprene (2-chloro-1 ,3-butadiene) 126-99-8 220712JLM 99% 2,014.0 I1g /mL +/-69.6131
11 Propionitrile 107-12-0 BCCF4167 99% 20,009.5 !1g/mL +1-691.5748
12 2,2-Dichloropropane 594-20-7 RD220812 99% 2,004.3 I1g/mL +/-70.0110
13 cis-I,2-Dichloroethene 156-59-2 MKCP7830 99% 2,014.0 flg/mL +/-70.3516
14 Methacrylonitrile 126-98-7 1012014 99% 20,031.5 l1g!mL +/-692.3351
15 Methyl acrylate 96-33-3 SHBG66l6V 99% 2,007.0 flg/mL +/-69.3711
16 Isobutanol (2-Methyl-l-propanol) 78-83-1 SHBP7066 99% 40,013.5 flg!mL +/-1,382.9594
.,..--."..,
01-Nov-2022 rev. RESTEK 1of5
REPORT ID: 23E081 Page 457 of 489
17 chloroform
18 Bromochloromethane
19 Tetrahydrofuran
20 1,1, I-trichloroethane
21 I,I-Dichloropropene
22 carbon tetrachloride
23 1,2-Dichloroethane
24 Benzene
25 2-Ch1oroethanol
26 Trichloroethene
27 1,2-Dichloropropane
28 Methyl methacrylate
29 bromodich1oromethane
30 1,4-Dioxane
31 2-Nitropropane
32 Dibromomethane
33 cis-I ,3-Dichloropro~ ..• '.'
34 Toluene
35 Ethyl methacrylate
36 trans-I,3-Dichloropropene
37 I, I ,2-Trichloroethane
38 1,3-Dichloropropane
39 Tetrachloroethene
40 dibrornochloromethane
41 1,2-Dibromoethane (EDB)
42 ChIorobenzene
43 1.1 , 1 ,2-Tetrachloroethane
44 Ethylbenzcne
45 rn-Xylene
46 p-Xylene
47 o-Xylene
48 Styrene
49 Isopropylbenzene (curnene)
50 bromoform
51 cis-l ,4-Dichloro-2-butene
52 1,1,2,2-Tetrachloroethane
o 1-Nov-2022 rev.
67-66-3 SHBN8469
74-97-5 00008541
109-99-9 SHBP0039
71-55-6 RD220613
563-58-6 220617JLM
56-23-5 SHBL8097
107-06-2 MKCN9758
71-43-2 MKCQ2104
107-07-3 RD220606A
79-01-6 SHBN3720
78-87-5 BCBR0882V
80-62-6 MKCQ2755
75-27-4 MKCF8470
123-91-1 SHBP8653
79-46-9 BCCB9352
74-95-3 10233302
10061-01-5 RD220311
108-88-3 ED097-US
97-63-2 MKCN6206
10061-02-6 RD220816
79-00-5 FGBOI
142-28-9 BCCB9817
127-18-4 SHBJ7422
124-48-1 MKCM8659
106-93-4 BCCF5058
108-90-7 SHBN6640
630-20-6 GCOI
100-41-4 094632L21G
108-38-3 SHBN6673
106-42-3 10234437
95-47-6 SHBN5105
100-42-5 MKCQ3390
98-82-8 Z20D022
75-25-2 MKCR0680
1476-11-5 RD220907
79-34-5 OXACF
99% 2,002.3 IlglmL
99% 2,011.9 IlglmL
99% 2,005.0 IlglmL
98% 2,001.2 IlglmL
99% 2,014.0 Ilg/mL
99% 2,000.1 IlglmL
99% 2,001.6 IlglmL
99% 2,010.5 IlglmL
99% 2,002.5 IlglmL
99% 2,001.6 IlglmL
99% 2,001.8 Ilg/mL
99% 2,007.5 IlglmL
99% 2,001.7 IlglmL
99% 40,041.0 IlglmL
97% 2,003.5 IlglmL
99% 2,013.0 Ilg/mL
99% 2,001.9 IlglmL
99% 2,011.4 IlglmL
97% 2,004.0 IlglmL
·99% 2,000.5 IlglmL
99% 2,001.9 IlglmL
99% 2,011.1 IlglmL
99% 2,001.2 IlglmL
99% 2,002.2 IlglmL
99% 2,006.0 IlglmL
99% 2,000.1 IlglmL
99% 2,009.8 IlglmL
99% 2,016.4 IlglmL
98% 2,012.6 IlglmL
99% 2,009.1 Ilg/mL
98% 2,010.1 IlglmL
99% 2,012.6 IlglmL
99% 2,009.3 IlglmL
99% 2,000.8 1lg/mL
97% 2,000.0 IlglmL
99% 2,002.8 IlglmL
+/-69.9291
+/-70.2782
+/-69.3020
+/-69.8893
+/-70.3498
+/-69.8514
+/-69.9056
+/-70.2293
+/-69.2156
+/-69.9047
+/-69.9125
+/-69.3884
+/-69.9082
+/-1,383;9099
+1-69.2514
+/-70.3149
+/-69.9152
+/-70.2608·
+/-69.26.8l .. • •.
+/-. 69.86ii\
+/-70.2485
+/-69.8890
+/-69.9256
+/-70;0704
+/-69.8506
+/-70.2031
+/-70.4337
+/-70.3019
+/-70.1787
+/-70.2163
+/-70.3027
+/-70.1874
+/-69.8750
+/-69.1290
+/-69.9466
2of5
REPORT ID: 23E081 Page 458 of 489
53 1,2,3-Trichloropropane 96-18-4 332900 99% 2,010.3 !!g/mL +/-70.2206
54 trans-l ,4-dichloro-2-butene 110-57-6 RD220921 RSR 94% 1,999.9 !!g/mL +/-69.1240
55 n-Propylbenzene 103-65-1 MKCNll26 99% 2,009.1 !!g/mL +/-70.1804
56 Bromobenzene 108-86-1 WXBCS147V 99% 2,012.S Ilg/mL +/-70.2992
57 1,3,5-Trimethylbenzene 108-67-8 BCCF4166 99% 2,010.8 !!g/mL +/-70.2381
58 2-Chlorotolucne 9S-49-8 MKCFS243 99% 2,007.S Ilg/mL +/-70.1228
59 4-Chlorotoluene 106-43-4 MKCC8496 99% 2,012.4 !!g/mL +/-70.2957
60 tert-Butylbenzene 98-06-6 STBJl937 99% 2,009.0 !!g/mL +1-70.1769
61 1,2,4-Trimethylbenzene 95-63-6 WXBC9428V 98% 2,004.8 !!g/mL +1-70.0297
62 sec-Butylbenzene 135-98-8 MKCP2266 99% 2,009.2 !!g/mL +/-70.1839
63 p-Isopropyitoluene (p-Cymene) 99-87-6 MKCR6143 99% 2,007.6 !!g/mL +1-70.1280
64 1,3-Dichlorobenzene 541-73-1 BCCD5315 99% 2,000.7 !!g/mL +/-69.8715
65 I A-Dichlorobenzene 106-46-7 MKBS4401V 99% 2,002.0 !!g/mL +/-69.9195
66 n-Butylbenzene 104-51-8 09804AE 99% 2,006.9 !!g/mL +1-70.1036
67 1,2-Dichlorobenzene 95-50-1 SHBN3835 99% 2,001.2 !!g/mL +1-69.8898
68 1,2-Dibromo-3-chloropropane 96-12-8 HBMVB 97% 2,006.3 !!g/mL +1-70.0843
69 Nitrobenzene 98-9S-3 10224044 99% 2,004.0 !!g/mL +1-69.2674
70 1,2,4-Trichlorobenzene 120-82-1 SHBM0526 99% 2,009.7 !!g/mL +1-70.1996
71 Hexachlorobutadiene 87-68-3 X05J 99% 2,007.4 f.1g/mL +1-70.1210
72 Naphthalene 91-20-3 MKCH0219 99% 2,001.5 !!g/mL +1-69.9132
73 1,2,3-Trichlorobenzene 87-61-6 MKBX7627V 99% 2,015.7 !!glmL +1-70.4092
.. Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
01-Nov-2022 rev.
3 of 5
REPORT ID: 23E081 Page 459 of 489
Column:
60m x O.2Smm x L4"",
Rtx-S02.2 (cat.#10916)
Carrier Gas:
hellum-constant pressure 30 psi
Temp. Program:
4O"C (hold 6 min.) to 240"C
@ 6"C/mln. (hold 10 min.)
Inj. Temp:
200'C
Det. Temp:
2S0'C
Det. Type:
MSO
Split Vent:
20.0 ml/min.
Inj. Vol
1111
Cathleen Soltis -Mix Technlcl ....
JennIlerPoIIino • Operations Tech III· ARM QC
01-Nov-2022 rev.
Quality Confirmation Test
I '16"17 29.30.31 45.46
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: l8-Nov-2022 Balance Serial #
Date Passed: 05-Dee-2022
B251644995
Manufactured under Restek's ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
40f5
REPORT ID: 23E081 Page 460 of 489
~ ....
IlESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30465
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative andlor quantitative determination of the analyte(s) listed.
Lot No.: A0164741
Description : California Oxygenates Mixture #1
California Oxygenates Mixture #1 2000-10000IJg/mL, P& T Methanol,
1mUampui
Container Size: 2 mL ------------------Pkg Amt: > 1 mL -----------------Expiration Date: September 30, 2025 Storage: O°C or colder
Ship: Ambient
~:,
fA'§iEDIT"iDl
180110)4 _edited
ReforEil<4 MolO1I.ll'Iod.,,,
CMifK;at& .3222.0\
. " "~'~'" , a
ISOAEC 17025 Aocrodilod
Testing Ub"ntoty
Cerlifiote #3222.02
CERTIFIED VALUES
. r l!l"i ~-:G(C\v.,CO"lc. ,-. • .. '
.. , (weight/volume)
", ... ~.E.lUland(lJI Unce,rtainty< _ " , ... k\,~,"! _ .
(95% C.L.; K=2)
tert-Butanol (TBA) 10,033.6 J.lg/mL +/-58.7489 Jlg/mL Gravimetric
CAS # 75-65-0 (Lot SHBL5806) +/-214.9330 Jlg/mL Unstressed
Purity 99% +1-221.1750 Jlg/mL Stressed
2 Methyl-tert-butyl ether ( MTBE ) 2,000.0 Jlg/mL +/-11.7371 Jlg/mL Gravimetric
CAS# 1634-04-4 (Lot SHBL0822) +/-42.8500 Jlg/mL Unstressed
Purity 99% +/-44.0940 Jlg/mL Stressed
3 Diisopropyl ether ( DIPE ) 2,006.0 Jlg/mL +/-11.7723 Jlg/mL Gravimetric
CAS # 108-20-3 (Lot SHBHI927V) +/-42.9785 Jlg/mL Unstressed
Purity 99% +/-44.2263 Jlg/mL Stressed
4 Ethyl-tert-butyl ether (ETBE) 2,017.6 Jlg/mL +/-11.8404 Jlg/mL Gravimetric
CAS# 637-92-3 (Lot MKCM3774) +/-43.2270 Jlg/mL Unstressed
Purity 99% +/-44.4820 Jlg/mL Stressed
5 lert-Amyl methyl ether (TAME) 2,009.2 Jlg/mL +1-11.7911 Jlg/mL Gravimetric
CAS# 994-05-8 (Lot HMBG7745V) +/-43.0471 Jlg/mL Unstressed
Purity 99% +/-44.2968 Jlg/mL Stressed
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E081 Page 461 of 489
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Column:
105m x 0.S3mm x 3.0~m
Rlx-502.2 (cal.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi,
Temp. Program:
40'C (hold 2 min.) 10 240'C
@S'C/min. (hold 5 min.)
inj. Temp:
200'C
Det. Temp:
250'C
Oet. Type:
FID
WalkerWornman· Operations Technician I
£~~_ ,1--.~ .<:::}}V~1((QI-.:iQ'C--....
,JUIiI1I,". Alba,u;on .Oporallonll Tueh.ARM QC
'~~.-'
01-Aug-2020 rev.
5 10 15 20
Minutes
This chromatogram represents a general set of testing conditions chosen for product
Fl(:r~flrtrmr.fl. Fnr nrtim<11 results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 24-Sep-2020
Date Passed: 27-Scp-2020
Balance: 1128360905
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2 of 3
REPORT ID: 23E081 Page 462 of 489
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
CERTIFICATE OF ANALYSIS
Catalog No: M-601 C-1 OX
Description: 2-Chloroethylvinyl ether
Lot: 218061690-01
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
~~~
Signal Word: Danger
Date Certified: Jul 15, 2020
Expiration: Jul 15, 2023
Sample Size: 1 mL
Components: 1
Storage Condition: Freeze «·10 ·C)
Certified Reference Material
Component CAS# Purity % Prepared Certified Analyte
Concentration' Concentration'
(GC/MS) (H9/mL) (flg/mL )
2-Chloroethylvinyl ether 110-75-8 100.0 2006 2006
A product with a suffix (-1A, -2B, etc. or -01, -02, etc.) on its lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 822-275872-11
, Certified Analyte Concentralion = Purity x Prepared Concentration.
The Uncertainty associated with the certifle'd concentration reported on this certificate is ±2,4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components, A normal distribution Is assumed and a coverage
factor of K=2 I,s chosen using approximately a 95% confidence level.
Labels and certificates folioV/U.S, Conventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater, A period (.) is used as
a decimal plaqe marker., , .
The information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Inform!itlon:.Pie~se refer to the SOS for information regarding the hazards associated with using this material.
This product wa~:p;~pared according to in-house procedures and is guaranteed to be homogeneolls.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEe 17025 and certified to ISO 9001 :2015 QR·ORGnNO·OOl
Rev. 7120
REPORT ID: 23E081 Page 463 of 489
.j
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers ANAB Certificate Number AR-1463
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories ANAB Certificate Number AT-1339
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations Certificate Number 3774
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory, Please refer to the NIST test number listed on the front of this certificate, Class A glassware
is used in the manufacture and quality control of all standards, Good Laboratory Practices have been used throughout
the preparation of this Standard,
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on Ule face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ti" = .r(Ii('!fFI-(u(mlY I (u(1V))2 F (u(RO»)2 I his
formula represents uncertainty components from the mass, volume, short-term stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery,
REPORT ID: 23E081 Page 464 of 489
Product Name: l-Chlorohexane Standard
Product Number: EPA-1208-1
Storage Conditions: Store at Room Temperature (ISO to 30°e).
Lot Number:
Lot Issue Date:
Expiration Date:
CERTIFIED VALUES
0006668972
10-Mar-2022
30-Apr-202S
Component Name Concentration Expanded Uncertainty CAS# Analyte Lot
t ~ Q • S '. No("'~ "?
Matrix: methanol (methyl alcohol)
Description:
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 1 of 2
CSO·QA·015.1
REPORT ID: 23E081 Page 465 of 489
ISO 17034 .. '~~:~:' .. Agilent
,* ~ ".
• TI ,Jslt:d /\I1~:\Vf~!~)
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~~ ...... x.. :.> .... ...-; ..... ~;o.., «<-;0; .. « ";V,>;«'';>; 'l"!;""'" «s:~ ~ .... -.;.... "I>'\: ..:«.,;.. o;.->-",<'\. \. ... ~ ..... .;:,.;;.x .. • ..... ·;> • ..;..-... •• .. ~ .................. -:-.-..; .. -.; ... .,;~ .. >; .... ,«,-o; .. .;o;.,; ..... .:: .... -..... r,-;>(-;> .... ~.:..< .'-"::' •• ;'o; ...... ~. • ........ ~ ........ , ..... ~. .. .............. ~ .... ;o ................. v ............... ;x. ..................................................... " ........... ;-.; ""::'1'
x«·;.X«-:-.""= .. NX*m»:-:·:::.;·.; ....... :·.·.·:.:·:-'.«·:·:.;.:%,~;.o)~o,;'::t.';.;·:.:·:-: .. • .•• ~.;~x·~: ... .;.;.;.>' ... .;·x .. .;.;·:·.y.«.;<-:·x .... ~_-..::. ............... : .... .;:( .. .,.~ .... :.; ... :*:,.:.;.; ... o:!.~ .. x.;·~~~w..:.;.;« ... :':·:·:·:~: .. .;.:,.:.-: ..... ,;-; .. .: ..... :.:.' ... :.;.;.; .. ' .. .;:>:..: ••• -;:~.~:::.;.: ............ :.: ................ ' ............... .: ........... : ............. : .... ', •••• '.: •• -:.; ............. ;. .............. .
~
ACCREOITED
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV ISUD registered ISO 9001 :2015
Quality Management System. Curt# 951215321
Page: 2 of 2
www.agilent.com/quality/
CSD·0A·015.1
Sample lot approvlr:
~QQM~QN6J
Monica Bourgeois
QMS Representative
~
ACCRf;DITEP
ISO 17025 Cert
No. AT-1937
REPORT ID: 23E081 Page 466 of 489
Scientific
SIMPLE SVlUl10NS FOR ADVAHGlV SCIENCE
Chromanex, 14271 Jeffey Rd #223, Irvine, CA 92620 [phone], Fax [phone] ._----------
Date manufactured: 10/15/2020
Original issue date: 10/15/2020 Certificate of Analysis Date Received:
Catalog No.: Lot No.: Storage: Solvent: Expiration Description:
3200-44 453887 PIT Methanol
Date:
14-0ct-2025 1 ,2,3-Trimethylbenzene Solution,
2500 mg/L, 1 mL
Certified Values:
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM
has been confirmed by g2,S chromatography (GC) or gas chromatograph/mass spectrometry
(GC/MS) using an internally developed method against an independent source. The uncertainty
value is calculated for a 95% confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, maIL
1,2,3-trimethylbenzene 526-73-8 95,2 869,3.19P 2515 ± 9.27
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control
standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It mayaslo be used for
various USEPA, NIOSH, and ASTM methods.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and
uncertainty (95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements: ::; -10°C
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal
ampule. Once opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards, All Glassware is calibrated
REPORT ID: 23E081 Page 467 of 489
Certificate of Analysis
Catalog No.: 3200-44 Lot No.: 453887 Expiration Date: 10/14/2025
using NIST traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department
of Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology
(NIST). Balances are checked daily in accordance to in house procedure 02-LB-004. Balances are calibrated
annually by an ISOIIEC 17025:2005 and ISO Guide 34:2009 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance
with internal procedure 02-0S-1 O. This is consistent with the intended use of this CRM. The homogeneity of this
product has been confirmed by procedures consistent with ISOIIEC qulde 17025:2005 and ISO Qulde 34:2009.
Hazardous information:
Refer to MSDS
Calculation of Uncertainty
The following equations are used to calculate the value of the expanded uncertainty: U=ku c: U=Expanded
Uncertainty, k= the coverage factor at the 95% confidence level, k=2, U c = the combined uncertainty uc = ..Jru l
2
where uj are the individual uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified
value. These tests include the effect of temperature and packaging on the product. This standard is guaranteed
until the following date: 14-0ct-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO
17034:2016 Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American
Association of Laboratory Accreditation (A2LA).
Manufactured By: Certified By: Released By:
Melissa Workoff Claire Desrochers Susan Mathews
REPORT ID: 23E081 Page 468 of 489
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30470
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative andlor quantitative determination of the analyte(s) listed.
Lot No.: A0162335
Description: tert-Butanol Standard
tert-Butanol Std 50.000IJg/mL. P&T Methanol. 1 mLiampul
Container Size: 2 mL
----------------------------
Pkg Amt: > 1 mL --.;..;.;.~----
Expiration Date: July 31. 2023 Storage: DOC or colder
-------------------------------
','; .. '-: .. M\ ....
Ij\C'CRED1T101
ISO t1~)4 Aa:redHed
R*r«lCe M~t~i~ PfoducQr
C9ftifiatQ Ulll.()l
d
·Isonec 17025 AOCfedited
Testing l>bOr'tory
C.rtifiGto fl222.02
CERTIFIED VALUES
Compound
tert-Butanol (TBA)
CAS # 75-65-0
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
(Lot SHBL5806)
Grav. Cone.
(weight/volume)
50,008.0 I!g/mL
Expanded Uncertainty
(95% C.L.; K=2)
+/-292.8078
+/-1,071.2377
+/-1,102.3483
Gravimetric
Unstressed
Stressed
14-May-2020 rev. 1 of 3
REPORT ID: 23E081 Page 469 of 489
Column:
105m x 0.53mm x 3.0~m
Rtx-502.2 (cat.#1091O)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ S'C/min. (hold 5 min.)
Inj, Temp:
200'C
Det. Temp:
250'C
Oet. Type:
FID
\I)'tfi-I ,~~~
Kyllo Strublq • Opero.tlonll Teohnlcltln ,
14-May-2020 rev.
10 15 20 25
fA tnutes
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 07-Jul-2020
Date Passed: 09-Jul-2020
Balance: 1127510105
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
/
i
20f3
REPORT ID: 23E081 Page 470 of 489
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
by TUV USA to ISO 9001:2015
Catalog No.: Lot No.:
scientific
(1 (uri Q 2 .. eft)
~~I .-'7 f-u1 F--l:r
Certificate of Analysis
Solvent: Exp. Date:
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: -------
Rev 0 Page
Description:
034-3200 480682
Storage:
:S -10°C PIT MeOH:Water 9:1 4/2812027 Ketones Solution, 2500 mglL, 1 ml ISO 17034
-12 \020-17
Compound
acetone
2-butanone (MEK)
4-methvl-2-oentanone (MIBK)
2-hexanone
Certified By:
Melissa Workoff
CAS No
67-64-1
78-93-3
108-10-1
591-78-6
Purity (%) Compound Lot No Concentration, mlllL
99.6 1 96.271.4P 2498 ± 53.47 mg/L
99.9 197.1.2P 2498 ± 53.51 mg/L
99.88 198.421.1.2P 2500 ± 54.02 mg/L
100 199.7.3P 2501 ± 53.58 mg/L
All weights are traceable through N. 1. S. T. Test No. 8221264157-00.
Concentration (correct for Duritv) and uncertainty (95% confidence) values
REPORT ID: 23E081 Page 471 of 489
· . ,
" ••• 0 A -I
•• a .... :.".. gl ent .. . . ~
Trusted Allswers
Reference Material Certificate
Product Information Sheet
Product Name: Acrolein and Acrylonitrile Standard
Product Number: AMN-623-1
Storage Conditions: Store Frozen (_25° to -1 DoC).
acrylonitrile 2009 ± 101.19/mL
Matrix: methanol (methyl alcohol)
Description:
ISO 17034
Lot Number: 0006728532
Lot Issue Date: 14-Feb-2023
Expiration Date: 30-Jun-2023
000107-13-1 RM20527
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material (RM) standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically. is listed above. Purity values are taken from approved vendor raw material certificates.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST SpeCial Publication 1088.
Homogeneity:
This analytical reference (RM) standard was unitized according to an in-house procedure and is guaranteed to be homogeneous.
There is no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference (RM) standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard (RM) is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 10f2
CSD-QA-015.1 ISO 17025
REPORT ID: 23E081 Page 472 of 489
. . . .
•••• e A -I ... :e.:.... gl ent . . .
Trusted Answers
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
REFER!:NCE MATERIAL
PRODUCER
ISO 17034 Cert
No. AR·1936
RM was produced in accordance with the TUV/SUD registered ISO
9001 :2015 Quality Management System. Cert# 951215321
Page: 2of2
www.agilant.com/quality/
CSD-QA·015.1
Sample lot approver:
~QOMgzoW
Monica Bourgeois
QMS Representative
ISO 17025
REPORT ID: 23E081 Page 473 of 489
~;
~;.
fi\«TI. DIT'TIB
SPEXerti/icate@
Certificate of Reference Material Reference Materials Producer
Cart #2495.01
Catalog Number: S-1015
Cyclohexane
Lot No. CP200701009
Ship Date: August 6, 2021
Methanol (Purge & Trap Grade) Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quali~y
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed In
USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Cyclohexane
CAS #
110-82-7
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 IJg/mL
Purity
99.5%
Certifiedt
1018 IJg/mL
Uncertainty
± 36IJg /mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepar~ the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6, 2021 Certifying Officer: ,3\u)..~"l---~-.,..
Shannon Macieira, Operations Manager
Page 1 of 2
REPORT ID: 23E081 Page 474 of 489
Report of Certification
Catalog Number: S-1015
Description: Cyclohexane
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200701009
Ship Date: August 6,2021
Expiration Date: August 5,2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS) and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the following standards:
-ISO 9001: Quality management systems. Requirements
-ISO/IEC 17025: General requirements for the competence of testing
• ISO Guide 35: Refernece Materials· General and Statistical
principals for certification and calibration laboratories • Guide to the Expression of Uncertainty in Measurement, 2008 ·ISO 17034: General requirements for the competence of reference
material producers
• EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition • ISO Guide 30: Reference Materials· Selected terms and definitions
-ISO Guide 31: Reference Materials· Contents of certificates and
lables
Storage Requirements:
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18°C to 2rC). Note: Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended amount that should be removed from this vial is 5fJL with a 25fJL ga~ tight syrir.go. All solutions should be thoroughly mixed, by shaking, prior to use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362·98 Appendix X2. Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure 4300·HOMOGEN·1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo tile variation, Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as: -

X

=

x

:l: U where X=certified value, U=expanded uncertainty, x=property value
-

U

=

kuc where k=2 is the coverage factor at the 95% confidence level
• Uc :: combined standard uncertainty obtained by combining the individual compound standard uncertainty components Ui, where uc::,Jrul' Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified Individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.\'P
Your Science is Our Passion.®
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax 1·732·603-9647
Page 2 of?
I
Rev: J
r
,./
REPORT ID: 23E081 Page 475 of 489
SR~}~·
ce~) ~ SPEXerti/icate®
Reference Materials Producer
Cert #2495.01
Certificate of Reference Material
Catalog Number: S-3893 Lot No. CP200615008
Description: Methyl acetate
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Matrix: Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
Methyl acetate
CAS #
79-20-9
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 ~g/mL
Purity
99.5%
Certifiedt
985 ~g/mL
Uncertainty
± 34 ~g/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20, 2022 Certifying Officer: .3~ ~
Shannon Macieira, Operations Manager
Page 1 of2
© 2021 ISpex, an A~Y)cienti~ company.
REPORT ID: 23E081 Page 476 of 489
Report of Cert~fication
Catalog Number: S-3893
Description: Methyl acetate
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200615008
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISO/IEC 17025: General requirements for the competence of testing
and calibration laboratories
-ISO 17034: General requirements for the competence of reference
material producers
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
-Guide to the Expression of Uncertainty In Measurement, 2008
-EURACHEMICITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
-NISTTechnlcal Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18DC to 27DC). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
Is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5J.lL with a 25J.lL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertlPrep from pre-qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025. ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final. packaged material have been analyzed to prove homogeneity In accordance with our intemal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity. as expressed as maximum between-bo
ttle variation. Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X = x ± U where X=certified value. U=expanded uncertainty. x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
-Uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components Ui. where Uc=v'rUI 2
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic. drug. or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever. whether based on breech of
warranty, alleged negligence. or otherwise. with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any inCidental, special. or consequential damages.
SPEX CertiPrep.1'j>
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
REPORT ID: 23E081 Page 477 of 489
U' SPEXerti/icate®
(jj'C'&e DdAA)
Reference Materials Producer
Cart #2495.01
Certificate of Reference Material Chemical Testing
Cerl #2495.02
Catalog Number: S-2470 Lot No. EN 191227005
Methylcyclohexane
Ship Date: August 6, 2021
Methanol (Purge & Trap Grade) Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Methylcyclohexane
CAS #
108-87-2
* -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 J,Jg/mL
Purity
99%
Certifiedt
1018 J,Jg/mL
Uncertainty
± 36 J,Jg/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6,2021 Certifying Officer: 3\<u:;...~v.vo"'J--. N\.l?Y'Sl-----
Shannon Macieira, Operations Manager
Page 1 of 2
REPORT ID: 23E081 Page 478 of 489
Report of Cert~fication
Catalog Number: 8-2470
Description: Methylcyclohexane
Matrix: Methanol (Purge & Trap Grade)
Lot No, EN191227005
Ship Date: August 6,2021
Expiration Date: August 5, 2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
• ISOIIEC 17025: General requirements for the competence of testing
and calibration laboratories
• ISO Guide 35: Refernece Materials· General and Statistical
principals for certification
-ISO 17034: General requirements for the competence of reference
material producers
-Guide to the Expression of Uncertainty in Measurement, 2008
• EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
• ISO Guide 30: Reference Materials· Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18°C to 27'C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5pL with a 25pL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cl(;aned prior to use. Dilutions should be performed only with Class (
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre·qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at crmsa![e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300·HOMOGEN·1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
tile variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X '" x ± U where X=certified value, U=<expanded uncertainty, x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
• Uc '" combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI. where uc="l:UI'
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind Whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.fP
Your SCience is Our Passion.'"
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Page 2 of 2
Rev: 0
REPORT ID: 23E081 Page 479 of 489
SRf3?r eel! SPEXerti/icate®
Reference Materials Producer
Cert #2495.01
Certificate of Reference Material
Catalog Number: S-615 Lot No. CP200928022
Description: 2-Butanol
Ship Date: June 20, 2022 Matrix: Expiration Date: June 19, 2025
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
2-Butanol
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
100 0 l-lg/mL
Purity
100%
Certifiedt
100 0 l-lg/mL
Uncertainty
± 35 I-Ig/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound( s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any Significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20, 2022 Certifying Officer: 3~ ~-.
Shannon Macieira, Operations Manager
Page 1 of 2
© 2021 I Spex, an A~WScienti~ company.
REPORT ID: 23E081 Page 480 of 489
,j
Report of Certification
Catalog Number: 8-615
Description: 2-Butanol
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200928022
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISOIIEC 17025: General requirements for the competence of testing
and calibration laboratories
• ISO 17034: General requirements for the competence of reference
material producers
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
-Guide to the Expression of Uncertainty in Measurement, 2008
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement· Third Edition
-NISTTechnical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product In ambient conditions (18°C to 27°C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
Is applicable only if the product Is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5IJL with a 25\JL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
Identifications are proprietary, however sources of al\ materials used In the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
tile variation, Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
-

X

=

x

± U where X=certified value, U=expanded uncertainty, x=property value
-

U

'" kuc where k=2 is the coverage factor at the 95% confidence level
-Uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI. where Uc="rUi'
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
Individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any Incidental, special, or consequential damages.
SPEX CertiPrep. ,
Your Science is Our Passion.'"
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
REPORT ID: 23E081 Page 481 of 489
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: I) It' 11.1.
by TUV USA to ISO 9001:2015 Certificate of Analysis Rev 0 Page
Catalog No.: lot No.: Storage:
:5 -10°C 3200-034 480677
-120016-03
Compound
bromomethane
chloromethane
chloroethane
dichlorodifluoromethane
vinvl chloride
trichlorofluoromethane
Solvent: Exp. Date:
PIT Methanol 11/8/2026
CAS No Purity (%)
74-83-9 99.5
74-87-3 99.7
75-00-3 99.94
75-71-S 99
75-01-4 99
75-69-4 99
Description:
ISO 17034 -Method 8260 Gases,
2.000 ml!lL_ 2 x 0.6 mL
Compound lot No Concentration, mll/L
139.15S.1.1P 2025 ± 7.36 mg/L
140.1 58.3P 2013 ± 7.32 mg/L
141.2.3P 1979 ± 6.93 mg/L
142.158.5P 2026 ± 21.46 mW!-
143.15S.5.2P 2011 ± 21.3 mg/L
144.1.3P 1998 ± 13.43 mW!-
Second Source standards are prepared according to NELAC requirements.
Certified By:
Samuel Garrett All weights are traceable through N.r. S. T. Test No. 822/264157-00.
Concentration (correct for Duritv) and uncertainty (95% confidence) values
REPORT ID: 23E081 Page 482 of 489
.;.";.
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
SV\-'?~-, 0 -0,
CERTIFICATE OF ANALYSIS
Catalog No: APP·9·211·20X
Description: Vinyl acetate
Lot: 222111294
Solvent: Methanol
Date Certified: Nov 21, 2022
Expiration: May 21,2023
Sample Size: 1 mL
Components: 1
Hazards: Refer to SOS for complete safety information Storage Condition: Freeze «.10 ·C)
Signal Word: Danger
Component CAS#
Vinyl acetate 108·05·4
Certified Reference Material
AR·1463
Purity' %
100.0
Prepared
Concentration"
QH9/fuq
This Certified Reference Material was verified 10 accordance with ISOIIEC 17025 (AT·1339) and ISO 17034 (AR·1463)
Certified Analyte
Concentration'
(jJg/mL)
2006
A product with a suffix (·IA, ·2B, etc. or -01, ·02,e\c.) on .il$.lot number has had its expiration date extended and is Identical to the same lot number wnhout the suffix.
, Certified Analyte Concentration = Purity ·x Prepa;ed Conc~ntration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen using approximateiy a 95% confidence level.
'All weights are traceable through NIST, Test No. 684/291344·18 & 684/292805-19
, Puritylldentity determined by one or more of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and·certlftcates follow U:S. Conventions in reporting numerical values: A comma (,) is use·d to separate units of one-thousand or greater. A period (.) is used as
a decimal pl~ee marker •.
The information on this .. certlficate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information: Please refer to the SDS for information regarding the hazards associated with using this material.
This product was.prepared according to in·house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEe 17025 and certified to ISO 9001 :2015 QR·ORG/INO·OO1
Rav.7/20
REPORT ID: 23E081 Page 483 of 489
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product Is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .!(u(V»)2 + (u(m»)2 + (u(IV»)2 + (u(RO))Z I his
formula represents uncertainty components from the mass, volume, short-term !ltability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E081 Page 484 of 489
Certificate of Analvsis
Product Name: Carbon Disulfide Standard
Product Number: EPA·1012·' Lot Issue Date: 2' ·Sep·2020
Lot Number: 0006557585 Expiration Date: 30·Sep·2024
Description:
This analytical reference material (RM) was manufactured and verified in accordance with an ISO 9001 registered quality system and analyte
concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each
analyte, determined gravimetrically, is listed below.
Analyte
carbon disulfide
Matrix: methanol (methyl alcohol)
Storage Conditions: Store Frozen (.25° to ., DOC).
Traceability:
CAS#
000075· 15·0
Analyte lot
RM08158
Concentration ± Uncertainty
5023 ± 25 Ilg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSl Z540.3, ISO 9001, ISO 17025,
and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are calibrated against a NIST traceable
thermometer in accordance with NIST Special Publication 108B.
Homogeneity:
This RM was unitized according to an in· house procedure and is guaranteed to be homogeneous. There is no minimum sub·sample size required.
Intended Use:
This RM is intended for the preparation of working reference samples for use in routine laboratory analyses. calibration of instruments. validation of
analytical methods, assessments of measurement methods. and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20·C to 25·C immediately after opening the container and should be processed without delay for
the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above, provided the RM is handled and stored in accordance with the
instructions given in this certificate. This certification is nullified if the RM is damaged. contaminated. or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
ACCREOITED
"Uti..,
RE"FEIlE'NCf: Ml\TE'RIAL
PRODUCER
ISO 17034 Cert
No. AR·1936
RM was produced in accordance with TUV USA Inc registered ISO 9001 Ouality
Management System. Cert # 56 100 18560026
Page: 1 of 1
www.agilent.com/quality/
CSO·OM15.1
Sample lot approver:
G0tPO QAASZ Ow
MOllica Bourgeois
QMS Representative
~
ACCREDITED
;.MN@
TESTING lABorV.TORV
ISO 17025 Cert
No. AT·1937
2.SD Smith ~.;treet North Kingstown, Hhode Island 028Ei2 www.agikmtcorn/quality
REPORT ID: 23E081 Page 485 of 489
SPEXerti/icate@
Certificate of Reference Material
Catalog Number: 8-260 Lot No. CP200804006
Description: tert-Amyl alcohol
Ship Date: June 20, 2022 Matrix: Expiration Date: June 19, 2025
This SPEXOrganics@ Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
tert-Amyl alcohol
SVI-3&-o1-o2
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 l-Ig/mL
Purity
99%
Certifiedt
1018l-1g/mL
Uncertainty
± 361J9/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20,2022 Certifying Officer: .3~ ~
Shannon Macieira, Operations Manager
Page 1 of 2
© 2021 I Spex, an ARftw)cienti~ comp.ny.
REPORT ID: 23E081 Page 486 of 489
Report of Cert~fication
Catalog Number: S-260 Lot No. CP200804006
Description: tert-Amyl alcohol
Matrix: Methanol (Purge & Trap Grade) Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISOIIEC 17025: General requirements for the competence of testing
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
and calibration laboratories -Guide to the Expression of Uncertainty in Measurement, 2008
-ISO 17034: General requirements for the competence of reference
material producers
-EURACHEMICITAC Guide: Qualifying Uncertainty in Analytical
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once It arrives in your laboratory, please store this product in ambient conditions (18°C to 27°C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5iJL with a 25iJL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by 5PEX CertiPrep from pre-qualifled vendors as per ISO guidelines. Vendor
Identifications are proprietary, however sources of all materials used In the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used In all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and A5TM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our intemal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
ttle variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X = x ± U where X=certlfied vaiue, U=expanded uncertainty, x=property value
- U :;: kuc where k:;:2 is the coverage factor at the 95% confidence level
-Uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI. where uc="ruf
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained In appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any InCidental, speCial, or consequential damages.
SPEX CertiPrep. fj)
Your Science is Our Passion."'
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Rev:
REPORT ID: 23E081 Page 487 of 489
s~~~' SPEXerti/icate®
~
Reference Materials Producer
Cert #2495.01
Certificate of Reference Ma teria 1
~d}' ~<~~ A .
" "I.. .. Chemical Testing
Cert #2495.02
Catalog Number: S-3730 Lot No. EN190716008
Description:
Ship Date: July 13, 2022 Matrix: Expiration Date: July 12, 2025
This SPEXOrganlcs® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
2,2,4-Trimethylpentane
Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
2,2,4-Trimethylpentane
~
540-84-1
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labgled
1000 IJg/mL
Purity
99%
Certifiedt
1000 IJg/mL
Uncertainty
± 35IJg/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: July 13, 2022 Certifying Officer: 3~ ~.
Shannon Macieira, Operations Manager
Page 1 of 2
<P 2021 I Spex, an A~~cientit2 company.
REPORT ID: 23E081 Page 488 of 489
Report of Certification
Catalog Number: 5-3730
Description:
Matrix:
2,2,4-Trimethylpentane
Methanol (Purge & Trap Grade)
Lot No. EN190716008
Ship Date: July 13. 2022
Expiration Date: July 12. 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISOIIEC 17025: General requirements for the competence of testing
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
and calibration laboratories -Guide to the Expression of Uncertainty in Measurement, 2008
-ISO 17034: General requirements for the competence of reference
material producers
-EURACHEMICITAC Guide: Qualifying Uncertainty in Analytical
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives In your laboratory, please store this product in ambient conditions (18°C to 27°C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE Is calculated from the SHIPPED DATE using our stability data and
is applicable only If the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial Is 5jJL with a 25jJL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come In contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
Identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrlcs have been used In all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity In accordance with our intemal procedure
4300-HOMOGEN-1A. This Is consistent with the Intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
tile variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X: as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X = x ± U where X=certified value, U=expanded uncertainty, x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
-Uo = combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI, where UC=.JrUI2
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained In appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep. 1>
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone] (I)
"-~ ... ,~--/
Page 2 of2
Rev: 0
REPORT ID: 23E081 Page 489 of 489

This page intentionally blank

LABORATO RIES. IN C.
S05i Fuida Street
Torrance, CA90505
Tel; (3i0}-6i8-8889
Date: 06-01-2023
EMAX Batch No.: 23E120
Attn: Travis Gouveia
Brice
3800 Centerpoint Dr. Suite 8223
Anchorage. P¥.. 99503
Subject: laboratory Report
Project: TEAO-S
Enclosed is the laboratory report for samples received on 05/16/23.
The data reported relate only to samples listed below :
Sample ID Control # Col Date Matrix
........... . ......................
S-120-08-052023 E120-01 05/12123 WATER
5-121-08-052023 E120-02 05/09123 WATER
S-127-15-052023 El20-03 05110123 WATER
S-128-15-052023 El20-04 05/09/23 WATER
5-135-16-05-20230 El20-05 05/10/23 WATER
S-135-16-052023 E120-06 05/10/23 WATER
5-136-16-052023 E120-07 05/11/23 WATER
5-139-17-05-20230 El20-08 05/12/23 WATER
5-139-17-052023 El20-09 05/12123 WATER
S-140-17-052023 El20-10 05/11/23 WATER
5-142-17-052023 El20-11 05/09/23 WATER
TB-20230509-1/25 El20-12 05/09/23 WATER
5-121-08-052023M5 E120-02M 05/09/23 WATER
5-121-08-052023M50 E120-025 05/09/23 WATER
The results are summarized on the following pages.
Please feel free to call if you have any questions concerning
these results.
Analysis
VOCS BY 8260C
VOC5 BY 8260C
VOC5 BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOC5 BY 8260C
VOC5 BY 8260C
VOC5 8Y 8260C
VOC5 8Y 8260C
VOC5 BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOC5 BY 8260C
This report is confidential and ntended solely for the use of the individual or
entity to whom it is addressed. This report shall not be reproduced except in full
or without the written approval of EMAX.
EMAX certifies that results included in this report meets all TNI & DOD requirements
unless noted in the Case Narrative.
NElAP Accredited Certificate Number CA002912022-24
ANAB Accredited DoD ElAP and I50/IEC 17025 Certificate Number l2278 Testing
California ElAP Accredited Certificate Number 2672
REPORT ID: 23E120 Page 1 of 560
CHAIN·OF·CUSTODY RECORD
Project Name: USAEC, TEAD-S
Project Number: 770113
WBS Code:
Comments:
SW8015D (A) = TPH-Diesel Range Organics
Brice Engineering, Salt Lake City, UT
Andrew Castor [phone]
COC # 770113·20230515
Page 1/1 362 W. Pierpont Ave
SLC, UT 84101
Laboratory: EMAX Laboratories, Inc., Torrance, CA
POC: Raman Singh (310)-618-8889 ext 119
Ship to: 3051 Fujita Street Torrance, CA 90505
Code Matrix "0
0 VVG Ground Water J: ....
GI WQ Water Quality Control Matrix :i III
.... ()
III ~ GI ~ I-~ , Code Container/Preservative jij 0 () u L() 0
21 2x 1 L Amber glass bottle with Teflon lined cap. Cool :g, 0 (0
N 0' to 6°C; protected from light jij <Xl <Xl
I: S S .l1> 3x VOA, 40 mL Clear glass vial with Teflon lined septa. « (f) (f) HCLto pH < 2. Cool 0' to 6'C
1Q~lto 11
Event: TEAO-S 2023 Annual Monitoring I
Groundwater I
i
§Y~&(:'1'gAI:);§?p?~Abdy~IM'!"~~X,y,~AL:L2;U~>i ............. )( 21 31 In \......... ./? <\ ....•••.••• < .....................
Sample 10 Matrix Oate Time
1 S-120-08-052023 WG 5/12/2023 1005
2 S-121-08-052023 WG 5/9/2023 1240
3 S-127 -15-052023 WG 5/10/2023 1425
4 S-128-15-052023 WG 5/9/2023 1420
5 S-135-16-05-20230 WG 5/10/2023 1310
6 S-135-16-052023 WG 5/10/2023 1305
7 . S-136-16-052023 WG 5/11/2023 1240
8 S-139-17 -05-20230 WG 5/12/2023 1145
9 S-139-17 -052023 WG 5/12/2023 1140
10 S-140-17 -052023 WG 5/11/2023 1040
11 S-142-17 -052023 WG 5/9/2023 1135
12 TB-20230509-1/25 WQ 5/9/2023 730
Turnaround Time: Standard
Relinquished by: (Signature) /,,'1/12.:5 IbI, C_t!'!f!3.:::::-.----
Date 5//5', ",':.>
Time (?'l.")C::> 7
Received by: (Signature)
Master_COC.xlsx
Samp
Sample Oepth (ft bgs)
Init. Location 10 Type Top -Bottom
CMH/SC X S-120-08 N1 46.00 66.00
CMH/SC X S-121-08 N1/MS1/SD1 32.50 52.50
CMH/SC X S-127-15 N1 0.00 0.00
CMH/SC X S-128-15 N1 0.00 0.00
CMH/SC X S-135-16 N1 0.00 0.00
CMH/SC X S-135-16 N1 0.00 0.00
CMH/SC X S-136-16 N1 0.00 0.00
CMH/SC X S-139-17 N1 0.00 0.00
CMH/SC X S-139-17 N1 0.00 0.00
CMH/SC X S-140-17 N1 0.00 0.00
CMH/SC X S-142-17 N1 0.00 0.00
CMH/SC X TripBlank TB1 0.00 0.00
f.t/;·,\1". 0;;".1 ~X : (5,;0~f ... I'G )
Date ~)-I :) -1.. .:J
Time irOQ -'::::::/
Shipping Date: 0-6-13
Received by Laboratory: (Signature, Date, Time) & conditio
Cooler Comments
1
1 9 containers
1
1
1
1
1
1
1
1
1
1
..
Of: -0. z.
f2.eotIVltA~ ~---fr-
1s-/';tJ,J·
OIf;Lf~
REPORT ID: 23E120 Page 2 of 560
REFERENCE: EMAX-SM02 Rev. 12
SAMPLE RECEIPT FORM 1
/ Type' of DelivelY Airbilll Tracking Number ECN ~~ 1::110
cY Fedex o UPS o GSa o Others 11 ZIlJ'5l117~V'l55 Recipient I..l OOC 'Ij YJe. -l0li .r-~mt&
o EMAX Courier 0 Client Delivery Date fr/ICI/n Time 61:l/S-
$=OC INSPECTION ,
~lientName '~ient PM/FC .ef Sampler Name O""Sampling DateiTime 2mPleID. efMatrix
Address el #/ Fax # o Courier Signature ~nalYSis Required Preservative (ifany) Irl'AT
Safety Issues (ifany) , o High concentrations expected o From Superfund Site ORad screening required
Note:
PACKAGING INSPECTION
Container ~.cooler o Box o Other
C;ondition (OHQGt\Ov) . Custody Sea I o Intact o Damaged
Packaging {fA(;tUt: -O· 2 ~ Bubble Pack o Styrofoam o Popcorn o Sufficient 0
Temperatures ¢ Cooler I ,·ql~·1. "c o Cooler 2 ---"c o Cooler 3 ---"c o Cooler 4 ---"c o Cooler 5 ---"c
(Cool, ::::6 nc but not frozen) o Cooler 6 "c 0 Cooler 7 "c o Cooler 8 °c o Cooler 9 {Ie o Cooler 10 "c
A.S/N27.10Sl1lOe ~S/N 2101(g(}tl7
---------
Thermometer: C-S/N D-S/N
Comments: o Temperature is out of range. PM was informed IMM DIATELY.
Note:
D ISCREP ANCIES
LabSampleID LabSampleContainerlD Code ClientSample Label ID / Information Corrective Action
2,w,6t If,&,t.f, ",I21~Z ~I PIO f'!1
---/ ----/
~ /
~ /
/ /
/ ~ /
../ /
/' /
/ J J. /
-t.-'J/lf.& ';;;l3 £. tt-,sl II hi':
o pH holdmg tune requIrement for water samples IS 15 mms. Water samples fOl pH analYSIS ale lecelved beyond 15 mmutes from samphng tune.
NOTES/OBSERVATIONS:
SAMPLE MATRIX IS DRINKING WATER" 0 YES
LEGEND:
Code Description-Sample Management
01 Analysis is not indicated in ____ _
02 Analysis mismatch COC vs label
03 Sample ID mismatch cac vs label
D4 Sample lD is not indicated in ___ _
OS Container ·[improper) [leaking) [broken)
06 DatelTime is not indicated in ___ _
07 DatelTime mismatch cac vs label
D8 Sample listed in cac is not received
DVsamPle received is not listed in cac
(0,10 No initialeOn corrections in cac~
'bl Container count mIsmatch coe vs recel ved
REVIEWS:
Date __ ~~ ____ ~--
Code Description-Sample Management
013 aut of Holding Time
014 Bubble is >6mm
DIS No trip blank in cooler
016 Preservation not indicated in ____ _
D 17 Preservation mismatch cac vs label
018 Insufficient chemical preservative
019 Insufficient Sample
020 No filtration info for dissolved analysis
D21 No sample for moisture detennination
022 ____________________________________ __
D23
--------------------~~------------
D24
--------------------~~----_f------
SRF
----"'=
Date
EMAX Laboratories. Inc. 3051 Fujita Sr, Torrance, CA 90505
o Continue to next page.
Code Description·Sample Management
RI Proceed as indicated in OO:OC 0 Label
I
R2 Refer to attached instruction
R3 Cancel the analysis
R4 Use vial with smallest bubble first
R5 Log-in with latest sampli~g date and time+ I min
R6 Adjust pH as necessary
R7 Filter and preserved as necessary
R8 ______________________________ ___
R9 ______________________________ ___
RIO __________________________________ ___
Rll -----------------------------------
R12 -----------------------------------
REPORT ID: 23E120 Page 3 of 560
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REPORT ID: 23E120 Page 4 of 560
REPORTING CONVENTIONS
DATA QUALIFIERS:
Lab Qualifier AFCEE Qualifier Description
J F Indicates that the analyte is positively identified and the result is less
than LOQ/RL but greater than LOD/MDLlDL.
N Indicates presumptive evidence of a compound.
B B Indicates that the analyte is found in the associated method blank
as well as in the sample at above QC level.
E J Indicates that the result is above the maximum calibration range or
estimated value.
* * Out of QC limit.
Note: The above qualifiers are used to flag the results unless the project requires a different
set of qualification criteria.
ACRONYMS AND ABBREVIATIONS:
CRDL Contract Required Detection Limit
RL Reporting Limit
MRL Method Reporting Limit
MOL Method Detection Limit
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
DO Diluted out
DATES
The date and time information for leaching and preparation reflect the beginning date and time of the
procedure unless the method, protocol, or project specifically requires otherwise.
REPORT ID: 23E120 Page 5 of 560
LABORATORY REPORT FOR
BRICE
TEAD-S
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
SDG#: 23E120
REPORT ID: 23E120 Page 6 of 560
Client : BRICE
Project: TEAD-S
SDG 23E120
CASE NARRATIVE
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
A total of twelve (12) water samples were received on 05/16/23 to be analyzed for
Volatile Organics by GC/MS in accordance with Method SW5030B/8260C and project
specific requirements.
Holding Time
Samples were analyzed within the prescribed holding time.
Instrument Performance and Calibration
Instrument tune check was performed prior to calibration. Result was within
acceptance criteria. Multi-calibration points were generated to establish initial
calibration (ICAL). ICAL was verified using secondary source (ICV). Continuing
calibration (CCV) was carried out at a frequency required by the project. All
calibration requirements were satisfied. Note that" Minimum Response Factor" for all
analytes were within method recommended response factors with the exception of
Acetone and 2-Butanone. However, percent recoveries for all target analytes were
within 70-130% on all calibration points. Refer to calibration summary forms of
ICAL, ICV and CCV for details.
Method Blank
Method blank was prepared and analyzed at the frequency required by the project. For
this SDG, two(2) method blanks were analyzed. V067E17B and V067E18B were compliant
to project requirement. Refer to sample result summary forms for details.
Lab Control Sample
Lab control sample was prepared and analyzed at a frequency required by the project.
For this SDG, two (2) sets of LCS/LCD were analyzed. V067E17L/V067E17C and
V067E18L/V067E18C were within LCS limits. Refer to LCS summary forms for details.
Matrix QC Sample
Matrix spike sample was prepared and analyzed at a frequency required by the
project. For this SDG, one (1) set of MS/MSD was analyzed and the following was
noted: 23E120-02M/23E120-02S -Percent recovery for Styrene(unstable in acidic
matrix) was not within MS/MSD QC limits. Presence of matrix interference was
suspected. The rest of the analytes were in control. Refer to Matrix QC summary form
for details.
Surrogate
Surrogates were added on QC and field samples. All surrogate recoveries were within
QC limits. Refer to sample result summary forms for details.
Sample Analysis
Samples were analyzed according to prescribed analytical procedures. Results were
evaluated in accordance to project requirements. For this SDG, all quality control
requirements were met with the exception of those that were discussed within the
associated QC parameter. One analyte was manually integrated in samples E120-08 and
-09. Hence, the original chromatogram was retained and corrected chromatogram was
initialed and dated. The secondary reviewer concurred with the manual integration.
REPORT ID: 23E120 Page 7 of 560
LAB CHRONICLE
VOLATILE ORGANICS BY GC/MS
Client : BRICE SDG NO. : 23E120
Project : TOO·S Instrument ID : 67
WATER
Client Laboratory Dilution % Analysis Extraction Sample Calibration Prep.
Sample ID Sample ID Factor Moist DateTime DateTime Data FN Data FN Batch Notes
............. ...... --.......... .. ........ -........... .......................................
LCS1W V067E17L 1 NA 05/17/2307: 33 05/17/2307: 33 REC381 RDC593 V067El7 Lab Control Sample (LCS)
LCD1W V067El7C 1 NA 05/17/2307: 59 05/17/2307:59 REC382 RDC593 V067E17 LCS Duplicate
MBLK1W V067E17B 1 NA 05/17/2308: 50 05/17/2308:50 REC384 RDC593 V067E17 Method Blank
TB-20230509-1/25 23E120-12 1 NA 05/17/2311: 24 05/17/2311:24 REC390 RDC593 V067E17 Field Sample
S·121·08-052023 23E120·02 1 NA 05/17/2311: 49 05/17/2311:49 REC391 RDC593 V067E17 Field Sample
S-120-08·052023 23E120-01 1 NA 05/17/2312:15 05/17/2312:15 REC392 RDC593 V067E17 Field Sample
S-127·15-052023 23E120·03 1 NA 05/17/2312: 41 05/17/2312:41 REC393 RDC593 V067E17 Field Sample
S·128·15·052023 23E120-04 1 NA 05/17/2313: 06 05/17/2313:06 REC394 RDC593 V067E17 Field Sample
S-135-16·05-2023D 23E120·05 1 NA 05117 12313: 32 05/17/2313:32 REC395 RDC593 V067E17 Field Sample
S·135-16-052023 23E120·06 1 NA 05/17/2313:58 05/17/2313:58 REC396 RDC593 V067E17 Field Sample
S-136-16·052023 23E120·07 1 NA 05/17/2314: 23 05/17/2314: 23 REC397 RDC593 V067E17 Field Sample
S·139·17-05·2023D 23E120·08 1 NA 05/17/2314: 49 05/17/2314:49 REC398 RDC593 V067E17 Field Sample
S ·139·17 ·052023 23E120-09 1 NA 05/17/2315:15 05/17/2315:15 REC399 RDC593 V067E17 Field Sample
S-121-08-052023MS 23E120·02M 1 NA 05/17/2316:32 05/1712316:32 REC402 RDC593 V067E17 Matrix Spike Sample (MS)
S·121·08-052023MSD 23E120-02S 1 NA 05/17/2316:58 05/17/2316:58 REC403 RDC593 V067E17 MS Duplicate (MSD)
LCS2W V067E18L 1 NA 05/18/2307:34 05/18/2307: 34 REC410 RDC593 V067E18 Lab Control Sample (LCS)
LCD2W V067E1BC 1 NA 05/18/2307: 59 05/18/2307: 59 REC411 RDC593 V067E18 LCS Duplicate
MBLK2W V067E18B 1 NA 05/18/2308: 50 05/1812308:50 REC413 RDC593 V067E18 Method Bl ank
S·120·08-052023 i 23El20-01I 10 NA 05/18/2315:41 05118/2315: 41 REC429 RDC593 V067E18 Diluted Sample
S-127-15·052023 23E120·03I 5 NA 05/18/2316: 07 05118/2316: 07 REC430 RDC593 V067E18 Diluted Sample
S-140·17·052023 23El20-10N 1 NA 05/18/2316:33 05/18/2316:33 REC431 RDC593 V067E18 Field Sample
S·142-17·052023 23E120·11N 1 NA 05/18/2316: 58 05/1812316:58 REC432 RDC593 V067E18 Field Sample
S-139-17-05-2023D 23E120-08I 500 NA 05/18/2317: 24 05/18/2317: 24 REC433 RDC593 V067E18 Diluted Sample
S·139·17-052023 23E120-09I 500 NA 05/18/2317:50 05/1812317:50 REC434 RDC593 V067E18 Diluted Sample
FN . Filename
% Moist -Percent Moisture
REPORT ID: 23E120 Page 8 of 560
SAMPLE RESULTS
REPORT ID: 23E120 Page 9 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client
Project
Batch No.
Sa!llPle ID
Lab Samp ID
Lab File ID
Ext Btch ID
Calib. Ref.
BRICE
TEAD-S
Date Collected: 05/12/23 10:05
Date Recei ved: 05/16/23
Date Extracted: 05/17/23 12:15 # 05/18/23 15:41
Date Analyzed: 05/17/23 12:15 # 05/18/23 15:41
Dilution Factor: 1 # 10
PAAAMETER(S)
23E120
S-120·08-052023
E120-01 ~20-01I REC392 EC429
V067E17 067E18
RDC593 C593
1.1. 1. 2-Tetrachl oroethane
1. 1. I-Trichloroethane
1.1.2.2-Tetrachloroethane
1.1.2-Trichloroethane
1.1-Dichloroethane
1.1-Dichloroethene
1.1-Dichloropropene
1. 2. 3-Trichloropropane
1. 2. 4-Trichlorobenzene
1.2-Dibromo-3-chloropropane
1.2-Dichlorobenzene
1.2-Dichloroethane
1.2-Dichloropropane
1.3-Dichlorobenzene
1.3-Dichloropropane
1.4-Dichlorobenzene
2.2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide # Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1.2-Dichloroethene
cis-1.3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethyl benzene
Isopropyl benzene
m.p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butyl benzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1.2-Dichloroethene
Trans-1.3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1.2-Dibromoethane
1.2.3-Trichlorobenzene
1.4-Dioxane
SURROGATE PAAAMETER(S)
RESULTS
(ug/U
a ••••••••••
ND
ND
ND
ND ND
ND ND
ND
ND ND
ND
ND ND
ND ND
ND ND
ND
ND ND
ND ND
ND
ND
ND
ND
ND
ND
ND
350
ND
ND 49
ND
ND
ND
ND ND
ND
ND
ND
ND
ND
ND
ND
ND
ND ND
ND
ND
ND
ND
0.68J
ND
ND
ND ND
ND
ND
ND
ND
ND
RESULT
1.2-Dichloroethane-d4 10.6
4-Bromofluorobenzene 10.7
Toluene-d8 10.7
Dibromofluoromethane 11.0
i 1.2-Dichloroethane-d4 104
4-Bromofluorobenzene 109
Toluene-d8 109
Di bromofl uoromethane 108
Matrix: WATER
% Moisture: NA
Instrument ID: 67 # 67
LOQ
(ug/U
...... a ...... __ _
1.0
1.0
1.0
1.0
1.0
1.0
1.0 2.0
1.0 2.0
1.0 1.0
1.0 1.0
1.0 1.0 1.0
20
1.0
20
1.0
20
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
2.0
1.0
1.0
1.0
1.0 1.0
1.0 1.0
1.0 1.0
2.0 10
2.0
1.0
1.0 1.0
1.0
1.0
1.0 1.0
1.0
1.0
1.0
1.0 1.0
1.0
1.0
1.0
1.0
1.0
100
SPK_AMT
10.0
10.0
10.0
10.0
100
100
100
100
DL
(ug/U
... --....... .
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.25
0.15
0.25
0.10
0.10
0.10
0.10
0.10
0.10
0.25
5.0
0.25
5.0
0.25
5.0
0.10
0.10
0.15
0.10
0.15
0.25
0.25
1.0
0.10
0.50
0.10
0.25
0.10
0.10
0.10
0.10
0.25
0.10
0.10
0.21
2.5
0.50
0.15
0.25
0.25
0.10 0.25
0.25
0.25
0.25 0.15
0.10
0.10
0.25
0.10
0.25
0.11
0.10
0.15
25
%RECOVERY .. __ ............ .
106
107
107
110
104
109 109
108
# Result(s) associated as marked on the header
Notes: Sample Amount 25ml Final Volume: 25ml
Prepared by VLu Analyzed by : VLu
# Sample Amount 2.5ml Final Volume : 25ml
LOD
(ug/L)
0.20
0.20 0.20 0.20
0.20
0.20
0.20
0.50
0.30
0.50 0.20
0.20
0.20 0.20
0.20
0.20
0.50
10
0.50
10
0.50
10
0.20
0.20
0.30
0.20
0.30
0.50 0.50
2.0
0.20
1.0
0.20
0.50
0.20
0.20
0.20
0.20
0.50
0.20
0.20 0.50
5.0
1.0
0.30
0.50
0.50 0.20
0.50
0.50
0.50 0.50
0.30
0.20 0.20
0.50
0.20
0.50
0.30
0.20
0.30
50
QC LIMIT
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70·130
# Prepared by VLu Analyzed by : VLu
Detection limits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 10 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05112/23 10:05
Project TEAD·S Date Received: 05/16/23
Batch No. 23El20 Date Extracted: 05/17/23 12:15
Sample ID S·120·08·052023 Date Analyzed: 05/17/23 12:15
Lab Samp ID 23El20·01 Dilution Factor: 1
Lab File ID REC392 Matrix: WATER
Ext Btch ID V067El7 % Moisture: NA
Calib. Ref. RDC593 Instrument 10: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/l) (ug/l)
.............. __ ................................ . .................. ................... ................. _ .. ...................
1. 1. 1.2·Tetrachloroethane NO 1.0 0.10 0.20
1. 1. l·Trichloroethane NO 1.0 0.10 0.20
1. 1. 2. 2·Tetrachloroethane NO 1.0 0.10 0.20
1.1.2·Trichloroethane NO 1.0 0.10 0.20
1.1·Dichloroethane NO 1.0 0.10 0.20
1.1·Dichloroethene NO 1.0 0.10 0.20
1.1·Dichloropropene NO 1.0 0.10 0.20
1. 2. 3.Trichlorggropane NO 2.0 0.25 0.50
1.2.4·Trichloro enzene NO 1.0 0.15 0.30
1.2·Dibromo·3·chloropropane NO 2.0 0.25 0.50
1.2·Dichlorobenzene NO 1.0 0.10 0.20
1.2·Dichloroethane NO 1.0 0.10 0.20
1.2.Dichlorogropane NO 1.0 0.10 0.20
1.3·Dichloro enzene NO 1.0 0.10 0.20
1.3.Dichlorogropane NO 1.0 0.10 0.20
1.4·Dichloro enzene NO 1.0 0.10 0.20
2.2'Dichloro~ro~ane NO 1.0 0.25 0.50
2·Butanone ( EK NO 20 5.0 10
2·Chlorotoluene NO 1.0 0.25 0.50
2·Hexanone NO 20 5.0 10
4·Chlorotoluene NO 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene NO 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane NO 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide NO 1.0 0.25 0.50
Carbon Tetrachloride 360E 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform 49 1.0 0.10 0.20
Chloromethane NO 1.0 0.25 0.50
cis-1.2-Dichloroethene NO 1.0 0.10 0.20
CiS.1.3-DichloroRropene NO 1.0 0.10 0.20
Dibromochloromet ane NO 1.0 0.10 0.20
Dibromomethane NO 1.0 0.10 0.20
Dichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISOprO~YlbenZene NO 1.0 0.10 0.20
m,wxF; ene NO 2.0 0.21 0.50
4-et yl-2-Pentanone NO 10 2.5 5.0
Methylene Chloride NO 2.0 0.50 1.0
Met~l tert-butyl ether (MTBE) NO 1.0 0.15 0.30
n-Bu ylbenzene NO 1.0 0.25 0.50
n· Propyl benzene NO 1.0 0.25 0.50
o-Xylene NO 1.0 0.10 0.20
~-Isopro~bltoluene NO 1.0 0.25 0.50
ec·Buty enzene NO 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert-Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene 0.68J 1.0 0.15 0.30
Toluene NO 1.0 0.10 0.20
Trans·1.2-Dichloroethene NO 1.0 0.10 0.20
Trans-1.3·Dichloropropene NO 1.0 0.25 0.50
Trichloroethene NO 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2-Dibromoethane NO 1.0 0.10 0.20
1.2.3-Trichlorobenzene NO 1.0 0.15 0.30
1.4·Dioxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
..................................................... . ............. __ .. -_ ............. -.. ----...... -.... .... _--_ .......
1.2-Dichloroethane-d4 10.6 10.0 106 70·130
4·Bromofluorobenzene 10.7 10.0 107 70-130
Toluene-d8 10.7 10.0 107 70-130
Dibromofluoromethane 11.0 10.0 110 70·130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 11 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC392.D
Acq On 17 May 2023 12:15 pm
Sample 23E120-01
Mise 25mL
(QT Reviewed)
Vial: 14
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:30 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.15 114 2202235 10.00 ug/l 0.01
55 ) CHLOROBENZENE-D5 15.60 117 1591171 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 441560 10.00 ug/l 0.00
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 577928 11.01 ug/l 0.01
Spiked Amount 10.000 Recovery 110.10%
43) 1 r 2-Dichloroethane-d4 9.30 65 426458 10.64 ug/l~ 0.01
Spiked Amount 10.000 Recovery 106:~
56 ) Toluene-d8 12.97 98 2372535 10.72 ug/l 0.00
Spiked Amount 10.000 Recovery 107.20%
77 ) 4-Bromofluorobenzene 17.62 95 639603 10.72 ug/k 0.01
Spiked Amount 10.000 Recovery 107.20%
./
Target Compounds Qvalue
19 ) Carbon disulfide 4.54 76 25755 0.10 ug/l 94
32) Chloroform 7.71 83 5352425 .,,-49.08 ug/l 96
41 ) Carbon tetrachloride 9.11 119 26632823 361.74 ug/l E. 100
63) Tetrachloroethene 14.26 164 38194 / 0.68 ug/l 98
/
(#) = qualifier out of range (m) = manual integration
REC392.D V067D26.M Thu May 18 08:30:16 2023 Page 1
REPORT ID: 23E120 Page 12 of 560
i
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC392.D
Aeq On 17 May 2023 12:15 pm
Sample 23E120-01
Mise 25mL
Vial: 14
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:30 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
1.7e+07;
1.6e+07'
1.5e+07;
1.4e+07'
1.3e+07:
1.2e+07!
1.1e+07 i
!
i 1e+07,
9000000 ,
I
I
8000000!
7000000
60000001
5000000
4000000,
3000000
i ,
2000000i
i 1
1000000:
::;:
"'" oi
'0 -= "5
<J)
'5
c
0 -e
'" (,)
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
(RTE Integrator)
Trc:REG392IJ~ ------~-----------~~ -~
::;:
"'" .n c.5 ui 0 g z W
11
w z (/) .E N (/) W oi Ie z
W ai N e:
0 OJ % z <I> :c w N
(,) (/) (/) 0 OJ e: a:: e: <I> oi '..f " 0 .0
e: !9 0 " a:: ~ '" ,<I> :J '0 ::;: 0 £; Ie: -' f--' " " I'" u. >-: I '" E "" 15 (,) 0 :m " E Ie ", c
0 !
:E Q) Ie
" '0 ~ OJ
'" il: " 0 10 Ie E P-o e :c ii .0 i ~ 0
Ii is t if f-i:
I
..f
0 w z w
N
Z w
OJ
0 a::
0
-' I
(,)
0
'"
Time--> 0~O~TM3.00 4.00 5.00 6.00 7.00 8.00 9.60\10:6'011:00 12:00 13:0014:0~ 15:0016~0017.00 18.0019.0020.0021,00
REC392.D V067D26.M Thu May 18 08:30:17 2023 Page 2
REPORT ID: 23E120 Page 13 of 560
Re~:
#19
Carbon disulfide
Concen: 0.10 ug/l
RT: 4.54 min Scan# 147
Delta R.T. 0.04 min
Lab File: REC392.D
4
1
9 II, 84
44 I ~2 64 70 i I 179 i 88
Acq: 17 May 2023 12:15 pm
ri,/z--> ~b35 40' 45 5'0 5'5 6'0 . 65 ' 70 7'5' 8'0 -8i-'-15-h+~90~~9~1~~ i,
Abundance ---Scail147 (4.541 rilIn):REG3M.D
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
25755
Upper
Ra~
i
oi
mlz--> 30
Abundance
Subi
50!
!
7p
44 I
40
I 49
:i5 1./5 5~ 55 W .5 7rb~7-'i5+" -'c-r,80~8+~,1I~~9CTb~S5-
Scan 147 (4.541 min): RFC3-92TIT-}-
7'6
49
11.0 6.3 11. 7
bUrldance 10r176lY017570T07B:7U):REC392.D
5000:lon 78.00 (77.70 to 78.70): REC392.D
4.54
40001
3000,
1000
I ~ r
i 40' " " , I. i O'-r~'n ii, . I I I I o~-, --I -.-l~'_, ,-, "~"'-I '~--~;--;'r-'-
[l1_/z_--,,-__ ~-=3c::.'o_3=_='5 ___ ...:.4_=__b __ 4.:.::'5,--'_'-=--5b ___ ~-=5c:::15,_'_'6=-:b ___ -=6-=-5---'7-=b'----'-715=--'---=8~b_8=_=:5 ___ _=91_=__o___=9=_=15_Jc:.:ic.:.m:::.e_--> ___ 4_.4Q._4.59 __ 4_.6Q __ ilQ..._~80
~bundance
Re~1
I
I 47
Scan 363 (7.683 min): RDC'593.D (-)
83
I
!
#32
Chloroform
Concen: 49.08 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC392.D
i, 55 ': Acq: 17 May 2023 12:15 pm
m/z--> ~b----40" '"~aL 60 7'0
74
80
ill • ~-1~0~0~~11'--0~+~2+-2~~~-i Tgt
,Abundance' ' 'SCa'i1364 (7.712 min): RE'C39T.D 130 I,! Io
8
n
3 8~
Ion: 83 Resp: 5352425
Ratio Lower Upper
100
Ra~
47 ! , ; i
i i
41 'I' I ' " 70 I i 120 0~ __ ~~~I~~5~8~~~~~H,:,~1~88~~~~~~~~, ~~'~I~'
m/z--> 30 40 50 '6'0 7'0 8'0 9'0" 100'" 110' 120 130
Abundance Scan 364 (7.712 min): REC31l2'-r.D"("-)---'-'-'=--'--'-=-=--....:.::'-=--j
Sub
50
47
83
85
47
65.5
25.8
39.4
0.0
99.4
56.0
bundance lon--83-:-0-01ffT.TO f683. 7Ur -REC392.D
:Ion 85.00 (84.70 to 85.70): REC392.D
lion 47.00 (46.70 to 47.70): REC392.D
12000001
1000000i 7.71
I
8000001
600000!
400000'
200000
o
ime--> 7.40 7.60 7.80 8.00 8.20
REC392.D V067D26.M Thu May 18 08:30:18 2023 Page 3
REPORT ID: 23E120 Page 14 of 560
~bundance , #41
I
RefOl
Ra~
47
! !
II
Ii
47 82 II III
O __ ,, ___ ,~_40~T'-r-c~~5,u8,~6~5 ,-rt72~-,,--i1-+1 +,--9,"1~.,-~--,-~~yllT'1~~3~-,r-~
i
m/z--> 30' 4b 50 ~O 7b' 8b" 9b'
I '100 110 1~0 130
llfbundance Scan460 (9.114 niin): REC392]JT-)"~----'-=-=------'-=--=----{
sU~OI
47
Carbon tetrachloride
Concen: 361.74 ug/l
RT: 9.11 min Scan# 460
Delta R.T. 0.01 min
Lab File: REC392.D
Acq: 17 May 2023 12:15 pm
Tgt Ion:119 Resp:26632823
Ion Ratio Lower Upper
119 100
117 103.0 73.4 133.4
-"'buCC:nCCid-=Cancccc=eT::lo=n'--1Hf.OO (118.70 to 11970'-:-REC392
lion 117.00 (116.70 to 117.70): REC392
5000000j
9.,11
,1
I
4000000;
3000000:
2000000i
82 i ! 1 10000001 ) \
i I, \\
i ! : i 123 OLc~1~1~1~--,--+5,8'r-' ,-;6:c:;5-,--,-7~2~--,-+-1 HI,~9T~1 ~~~--,--r.--,J,' +-, l,l-,~,,~~ 01=1 ;::::;::::::::::::;::::;::::::'<'::;:~:::;::-~--:~~"-~~~,=:: ~~_~ __ 40 __ 5_0 __ 6_bc __ 7_b __ 8b __ 9_b __ 1_00 __ 1_1 __ 0 _1_2_0 __ 13_' 0_-,--i_me--> __ 8--,.8-,--0 __ 9_.0()_~_~20 __ ~:40
RefO!
0 1
m/z-->
~bundance
I
i Ra~1
129
94
I
47
59
I
'I , I,
i I
5b (30
70 82 i i 117! I ,,----~~'"'~~~,-,-j, :+,1",", TT', 11 1
" " , "I,"" ,
40
47
70 80 90 100 110 120 130 140
Scan 812 (14.257 mm): REC39T.D
129
94
166 #63
Tetrachloroethene
Concen: 0.68 ug/l
RT: 14.26 min Scan# 812
Delta R.T. 0.01 min
Lab File: REC392.D
:1 I Acq: 17 May 2023 12:15 pm
T I
38194 150' 160 I~ I Tgt Ion: 164 Resp: ~ Ion Ratio Lower Upper
196 ! 164 100
i 166 130.6 97.7 157.7
129 88.6 56.9 116.9
131 83.7 52.5 112.5
i I
iii
59 ! I 82 i'
bundancelon 104.UD\1o3JO-1O--ro.'GOr REC392
lion 166.00 (165.70 to 166.70): REC392
lion 129.00 (128.70 to 129.70): REC392
:Ion 131.00 (130.70 to 131.70): REC392
20000' Ol __ ~ __ ~--. ___ ~,~'I n-'T-!!i~'~--,-
m/z--> 40 50 60 70 80 90 100 110 120 130 140 150 160 170
A5uncfance---~--. Scan 812114.257 min): REC392.0 (-)
Sub'
50
O~
[Il/z--> 40
47
59
50 60
129
94
82
II
70 80 90
15000i ,
,~4.26
/
10000
i
! \
5000: I \
i / \ ol--~--~--=;:~c~c,--
ime--> 14.10 14:20 14.30
REC392.D V067D26.M Thu May 18 08:30:18 2023 Page 4
REPORT ID: 23E120 Page 15 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/12/23 10:05
Project TEAD-S Date Recei ved: 05/16/23
Batch No. 23E120 Date Extracted: 05/18/23 15:41
Sa!llPle 10 S-120-08-052023 Date Analyzed: 05/18/23 15:41
Lab Samp 10 23E120-01I Dilution Factor: 10
Lab File 10 REC429 Matrix: WATER
Ext Btch 10 V067E18 t Moisture: NA
Calib. Ref. RDC593 Instrument 10: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/L) (ug/l)
-.................. _--.......... _-_.--... __ a ... •• .... ........ a __ ....... ... _.a_ .......... . .. __ .............
1. 1. 1. 2-Tetrachloroethane ND 10 1.0 2.0
1.1.1-Trichloroethane ND 10 1.0 2.0
1. 1. 2. 2-Tetrachloroethane ND 10 1.0 2.0
1.1.2-Trichloroethane ND 10 1.0 2.0
1.1-Dichloroethane ND 10 1.0 2.0
1.1·Dichloroethene ND 10 1.0 2.0
1.1-Dichloropropene ND 10 1.0 2.0
1. 2. 3-Trichlorogropane ND 20 2.5 5.0
1.2.4-Trichloro enzene ND 10 1.5 3.0
1.2-Dibromo-3-chloropropane ND 20 2.5 5.0
1.2-Dichlorobenzene ND 10 1.0 2.0
1.2-Dichloroethane ND 10 1.0 2.0
1.2-Dichlorogropane ND 10 1.0 2.0
1.3-Dichloro enzene ND 10 1.0 2.0
1.3-Dichlorogropane ND 10 1.0 2.0
1.4-Dichloro enzene ND 10 1.0 2.0
2.2'Dichloro~ro~ane ND 10 2.5 5.0
2-Butanone ( EK ND 200 50 100
2-Chlorotoluene ND 10 2.5 5.0
2-Hexanone ND 200 50 100
4-Chlorotoluene ND 10 2.5 5.0
Acetone ND 200 50 100
Benzene ND 10 1.0 2.0
Bromobenzene ND 10 1.0 2.0
Bromochloromethane ND 10 1.5 3.0
Bromodichloromethane ND 10 1.0 2.0
Bromoform ND 10 1.5 3.0
Bromomethane ND 10 2.5 5.0
Carbon Disulfide ND 10 2.5 5.0
Carbon Tetrachloride 350 10 1.0 2.0
Chlorobenzene ND 10 1.0 2.0
Chloroethane ND 20 5.0 10
Chloroform 48 10 1.0 2.0
Chloromethane ND 10 2.5 5.0
cis-1.2·Dichloroethene ND 10 1.0 2.0
C1S-1.3-Dichloro~ropene ND 10 1.0 2.0
Dibromochloromet ane ND 10 1.0 2.0
D1bromomethane ND 10 1.0 2.0
Dichlorodifluoromethane ND 10 2.5 5.0
Ethyl benzene ND 10 1.0 2.0
ISOpro~Ylbenzene ND 10 1.0 2.0
m.w~ ene ND 20 2.1 5.0
4-et yl-2-Pentanone ND 100 25 50
Methylene Chloride ND 20 5.0 10
Meth1l tert-butyl ether (MTBE) ND 10 1.5 3.0
n-Bu ylbenzene ND 10 2.5 5.0
n-Propylbenzene ND 10 2.5 5.0
o-Xylene ND 10 1.0 2.0
~-Isopro~bltoluene ND 10 2.5 5.0
ec-Buty enzene ND 10 2.5 5.0
Styrene ND 10 2.5 5.0
Tert-Butylbenzene ND 10 2.5 5.0
Tetrachloroethene ND 10 1.5 3.0
Toluene ND 10 1.0 2.0
Trans-1.2-Dichloroethene ND 10 1.0 2.0
Trans·1.3-Dichloropropene ND 10 2.5 5.0
Trichloroethene ND 10 1.0 2.0
Trichlorofluoromethane ND 10 2.5 5.0
Vinyl Chloride ND 10 1.1 3.0
1.2·Dibromoethane ND 10 1.0 2.0
1. 2. 3-Trichlorobenzene ND 10 1.5 3.0
1.4-Dioxane ND 1000 250 500
SURROGATE PARAMETER(S) RESULT SPK AMT tRECOVERY QC LIMIT
....... _ ........... _ ......... -.................. ....... __ ...... -................. -............... _-...... __ ._-_ ..
1.2·Dichloroethane-d4 104 100 104 70-130
4-Bromofluorobenzene 109 100 109 70-130
Toluene-d8 109 100 109 70-130
Dibromofluoromethane 108 100 108 70-130
Notes: Sample Amount : 2.5ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 16 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC429.D
Aeq On 18 May 2023 3:41 pm
Sample 23E120-01I lOX
Mise 2.5mL
(QT Reviewed)
Vial: 22
Operator: VLu
Inst 67
Multiplr: l.00
MS Integration Params: RTE.P
Quant Time: May 19 8:23 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) 1,4-DIFLUOROBENZENE 10.15 114 2314638 10.00 ug/l 0.01
55) CHLOROBENZENE-D5 15.60 117 1638965 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 445086 10.00 ug/l 0.00
iSystem Monitoring Compounds
36) Dibromofluoromethane 8.21 111 593495 10.76 ug/l 0.01
Spiked Amount 10.000 Recovery 107.60%
43) 1,2-Dichloroethane-d4 9.30 65 438334 10.41 ug/l 0.01
Spiked Amount 10.000 Recovery 104.10%
56) Toluene-d8 12.97 98 2476130 10.87 ug/l 0.00
Spiked Amount 10.000 Recovery 108.70%
77) 4-Bromofluorobenzene 17.62 95 655379 10.90 ug/l 0.01
Spiked Amount 10.000 Recovery 109.00%
~Target Compounds Qvalue
32) Chloroform 7.71 83 554496 /' 4.84 ug/l 96
41 ) Carbon tetrachloride 9.11 119 2736833 35.37 ug/l 100
/
(#) = qualifier out of range (m) = manual integration
REC429.D V067D26.M Fri May 19 08:23:25 2023 Page 1
REPORT ID: 23E120 Page 17 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC429.D
Aeq On 18 May 2023 3:41 pm
Sample 23E120-01I lOX
Mise 2.5mL
Vial: 22
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 8:23 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
80000001
7500000,
6500000' !
i:
I ; i
I 6000000! I
5500000: .
! 5000000,
4500000: -
40000001 .
3500000:
3000000
2500000:
2000000
1500000
1000000
500000'
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TJC:REC429.D
::;: ..: en
oi w .., z -c W 0
:E N
0 Z
~ W
In
0
.,; .., .,
c:
Q)
" 0
f-
c: a:
0 0 € => <II ...J
() "-
is
en .....
oi c:
<II ~
::;: E e ..: 0
<5 " 0= g 0
E
~ e .c
0 is
:E
()
en
!~ ~~
:i 1) e
'0 Tfi :\~~
.~
i'(
on
0
W z w
N z w
In en
0 oi a: c:
0 Q)
N ...J c: I Q)
U .c e
0
" 0= 0
E e
In ....
..j
0
W
Z w
N
Z
W
In
0 a:
0
...J
I
U
is
N.
,'T, :
o-,-~-=c~-;_~_ __~~_ ___ ~ _____ _
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.0021.00
REC429.D V067D26.M Fri May 19 08:23:26 2023 Page 2
REPORT ID: 23E120 Page 18 of 560
j
RefO!
Ra'5{)i
I
47
55
47
,
74 ,i;'i , ,~~O~~
6'0 7'0 8b 9b 100 110 120 130
Scan 364 (7.711 min): REc-4Z9-:~
83 !
O,-~~-~~~~, ''-'-!' I~~' ~2,~~-tL~~-1 ~~~..,.1, ~_,_~~, ~ m/z-~> 3'0 40 50 60 7'0 80 ' 90 100 110 120 130
f.\bundance Scan 364 (7.711 min): REC429.D (-)
~
Sub
50,
RefO
47
70
70
47
i I
I I
i I I
I
I
! Ji
8'0
82
I
I' I
90 100
Ii , I II
! [, I I!
0~1 ~~, ,42
'm/z--> 40
59 70 II i : ~23
50 6'0 70 80 90 100 110 120 130
A6lindance--" '---Scan'4@\9':"mmTri):REC'4Z9:0------
47
o~~·
m/z--> 40 50
iA-bundance'
Sub'
50:
m/z-->
47
41
40 50
1H
82
I,
! i
59 65 72 [ i ~c-c' ~~,,~~~.,..+i~. "-12L,..3~~
60 70 80 90 100 110 120 130
Scan 460\9:114 min): REC429TIT-) 1F
82
58 65 72
60 70 80 ""-90"---_10'-" 0
i
#32
Chloroform
Concen: 4.84 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC429.D
Acq: 18 May 2023 3:41 pm
Tgt Ion: 83 Resp: 554496
Ion
83
85
47
1000001
I
!
800001
600001
#41
Ratio Lower Upper
100
64.9 39.4 99.4
25.9 0.0 56.0
7.71
Carbon tetrachloride
Concen: 35.37 ug/l
RT: 9.11 min Scan# 460
Delta R.T. 0.01 min
Lab File: REC429.D
Acq: 18 May 2023 3:41 pm
Tgt
Ion
119
117
Ion:119 Resp: 2736833
Ratio Lower Upper
100
103.7 73.4 133.4
rbundcinceJOrlTf9-:00 (1T8-:70-f6 119:70): REC429
lion 117.00 (116.70 to 117.70): REC429
500000: 9.,11
400000:
300000
) \
\,---
200000:
100000'
REC429.D V067D26.M Fri May 19 08:23:27 2023 Page 3
REPORT ID: 23E120 Page 19 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client : BRICE Date Collected: 05/09123 12:40
Project : TEAD-S Date Received: 05/16/23
Batch No_ 23E120 Date Extracted: 05/17/23 11:49
Sample ID ; S-121-08-052023 Date Analyzed: 05/17/23 11:49
Lab Sa!!1P ID: 23E120-02 Dilution Factor: 1
Lab File ID: REC391 Matrix: WATER
Ext Btch ID: V067E17 % Moisture: NA
Calib_ Ref.: RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/L> (ug/L> (ug/L>
a. _______ ...... __ ... _ ...... __ ._. __ .. .. __ a .. • ... _ .... ....... a ....... __ ..... -........... ..............
1.1.1.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorggropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride 3.0 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform 1.6 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
I sopro~y 1 benzene ND 1.0 0.10 0.20
m.~-x~ ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-l.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1. 2. 3-Trichlorobenzene ND 1.0 0.15 0.30
1,4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
.................................................... ................... .. ............... -.................... .. __ ..............
1.2-Dichloroethane-d4 10.6 10.0 106 70-130
4-Bromofluorobenzene 10.8 10.0 108 70-130
Toluene-d8 10.7 10.0 107 70-130
Dibromofluoromethane 10.8 10.0 108 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 20 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC391.D
Acq On 17 May 2023 11:49 am
Sample 23E120-02
Misc 25mL
(QT Reviewed)
Vial: 13
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:29 2023 ~~uant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.15 114 2247666 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1619845 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 444549 10.00 ug/l 0.00
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 577971 10.79 ug/l 0.02
Spiked Amount 10.000 Recovery 107.90%
43) l,2-Dichloroethane-d4 9.31 65 433916 10.61 ug/y--0.02
Spiked Amount 10.000 Recovery 106.10%
56) Toluene-d8 12.97 98 2409464 10.70 ug/l /0.00
Spiked Amount 10.000 Recovery 107.00%
77) 4-Bromofluorobenzene 17.60 95 650315 10.83 ug/V 0.00
Spiked Amount 10.000 Recovery 108.30%
/
Target Compounds Qvalue
32) Chloroform 7.70 83 177680 1. 60 ug/l 97
41 ) Carbon tetrachloride 9.12 119 225278 /' 3.00 ug/l 98
(#) = qualifier out of range (m) = manual integration
REC391.D V067D26.M Thu May 18 08:29:43 2023 Page 1
REPORT ID: 23E120 Page 21 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC391.D
Aeq On 17 May 2023 11:49 am
Sample 23E120-02
Mise 25mL
Vial: 13
Operator: VLu
Inst 67
Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 18 8:29 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance -.
8500000:
8000000,
7500000
;;
7000000 :
6500000i .
i i , ,
6000000:
Ii
5500000! •
j
5000000:
4500000,
4000000i ,
3500000
3000000i .
i
2500000
2000000
1500000
1000000'
500000
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
-.---~. ~rc:REC3-9T.U-----------·---
.,.;
(f) 0
ai uJ ui ~ z z w w C N
N " Z
Z :J W 0 W I-
CD
CD 0
0 0::
0:: 0
0 ...J
J: ::J
...J U
u.
is
"'. (f)
oi (f)
C ..,:
'" :i9 ~ ." I-C E .",
e ~
0 'C" ::;;: :J .Qe ...: <;: .co 0 ~ U E g e ~ .c
.E 0 c:<". e 0.--e 0 '" :c u u
(f)
oi
C
" N
C
" .c e
0
:J
<;:
0
E e
CD
'"
.f
0
uJ
Z
W
N z w
CD
0
0::
0
...J
J:
U q
"!
!ime-->
Ol.-~ /\;\ /\J\
2.00 3.00 4.00 5.00 6.00 7.60 8.00 9.0010.00 11:00 12.0013:00 14:00 15:00 6.00 17.00 18:00 19.0020:0021.00
REC391.D V067D26.M Thu May 18 08:29:44 2023 Page 2
REPORT ID: 23E120 Page 22 of 560
~bundance
Re~,
47
I
42 i 55
Scai13031T.6~TmlilfRDC593lTB
8i3
I
i i I! , I i:
, 74 ii' O~·;LJ+~ I I .l,.c,..,--.-.~
m/z--> 30 40 50 60 70 80 9'0 1 OO~; 10
Abundance -----Scan 3631T.6-9a min): REC39T.D
83
!
II
! :
47
120
120 130
----;
II
. O~ 44'00 iii/ 7~, lilli, I .~~'~~:rl~~O~~~
.m/z--> 30 50 60 70 8'0 90 100 110 120 do AbundanC:Cce=---~-.....::..c=--"S"':c~a='n 363 (7.698 min): REC39T.Dl:·~) -"-'-------"' ......... -=j
Subi
50:
~3
Ii
II
! I
i I
#32
Chloroform
Concen: 1.60 ug/l
RT: 7.70 min Scan# 363
Delta R.T. 0.02 min
Lab File: REC391.D
Acq: 17 May 2023 11:49 am
Tgt Ion: 83 Resp: 177680
Ion Ratio Lower Upper
83 100
85 66.4 39.4 99.4
47 25.9 0.0 56.0
5undancelon -ff3:'OO-(8270to 8370): REC391.D
lion 85.00 (84.70 to 85.70): REC391.D
lion 47.00 (46.70 to 47.70): REC391.D
400001
20000;
i
100001
I
I ..
7.70
O;~-.,..:..::.~~~~ 70 i,i i 1~O ,I
;m/z--> 30 ___ 6 .... 0 __ ' .... 70::..· ___ 8 .... '0 __ ' '.--.90::..'_..:.1 .... 0,0::..' _1 ... 1 .... 0_..:.1-:c20"--....."130 tfime-->
0k::--:-,----r-m-!~ -~-~~~~~~~=---
7.50 7.60 7.70 7.80 7.90 8.00
~bundance
Re~i I
m/z-->
Abundance
47
47
Scan 460 (9'TOO min): RUC59TD (-)
i 1
i i
82
! i
: i
I I! '
82
40 58 70 I iii 123
I 0'-.1 ~~-.L~~~~~~.,..-r~-.-,-+I-i.· +-.,..-,.....~~~~~.L,.I J,' IT, ~~
#41
Carbon tetrachloride
Concen: 3.00 ug/l
RT: 9.12 min Scan# 460
, De 1 taR. T . 0 . 02 mi n
Lab File: REC391.D
Acq: 17 May 2023 11:49 am
Tgt Ion:119 Resp:
Ion Ratio Lower
119 100
225278
Upper
117 105.6 73.4 133.4
bundancelorf11Kcro-(n8~70-lo1 1970YREC391
50000ilon 117.00 (116.70 to 117.70): REC391
I
400001
Im/z __ > 40 50 60 70 80 90 100 110 120 130 ~'<:bC'Cun::c:d=a=nc=e---'---~ -Scan 460 (9:1T6f11lnyREC31T1.DT-f·-"-"""-------------".'""'-
Sub'
50
0
m/z-->
41
40
47
58
50 60
REC391.D V067D26.M
72
7'0
117 30000
82
I , i ,23 I
80 90 100 110 120
Thu May 18 08:29:45 2023 Page 3
REPORT ID: 23E120 Page 23 of 560
METHOD SWS030B/B260C
VOLATILE ORGANICS BY GC/MS
Client
Project
Batch No.
Sample ID
Lab Samp ID
Lab File ID
Ext Btch ID
Cal ib. Ref.
BRICE
TEAD·S
Date Collected: 05/10/23 14:25
Date Received: 05/16/23
Date Extracted: 05/17/23 12:41 # 05/18/23 16:07
Date Analyzed: 05/17/23 12:41 # 05/18/23 16:07
Dilution Factor: 1 # 5
PARAMETER(S)
23E120
S-127-15-052023
E120-03 B20-031 REC393 EC430
V067E17 067E1B
RDC593 C593
1. 1. 1. 2-Tetrachloroethane
1. 1. I-Trichloroethane
1. 1. 2. 2-Tetrachloroethane
1.1.2-Trichloroethane
1.1-Dichloroethane
1.1-Dichloroethene
1.1-Dichloropropene
1.2.3-Trichloropropane
1.2.4-Trichlorobenzene
1.2-Dibromo-3-chloropropane
1.2-Dichlorobenzene
1.2-Dichloroethane
1.2-Dichloropropane
1.3-Dichlorobenzene
1.3-Dichloropropane
1.4-Dichlorobenzene
2.2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Ch 1 oroethane # Chloroform
Chloromethane
cis-1.2-Dichloroethene
cis-1.3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethyl benzene
Isopropyl benzene
m.p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butyl benzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1.2-Dichloroethene
Trans-1.3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1.2-Dibromoethane
1.2.3-Trichlorobenzene
1.4 -Di oxane
SURROGATE PARAMETER(S)
RESULTS
(ug/L)
ND
ND
ND
ND ND
ND ND ND
ND ND
ND
ND
ND
ND
ND
ND
ND ND
ND
ND
ND
ND
ND
ND
ND
ND ND
ND
ND
ND ND ND
130
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.69J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
RESULT
1.2-Dichloroethane-d4 10.3
4-Bromofluorobenzene 10.9
Toluene-d8 10.9
Dibromofluoromethane 10.7
i 1.2-Dichloroethane-d4 51.5
4-Bromofluorobenzene 54.7
Toluene-d8 53.9
Dibromofluoromethane 52.9
Matrix: WATER
% Moisture: NA
Instrument ID: 67 # 67
LOO
(ug/l)
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
20
1.0
20
1.0
20
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
10
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
100
SPK AMT
10.0
10.0
10.0
10.0
50.0
50.0
50.0
50.0
DL
(ug/l)
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.25
0.15
0.25
0.10
0.10
0.10
0.10
0.10
0.10
0.25
5.0
0.25
5.0
0.25
5.0
0.10
0.10
0.15
0.10
0.15
Q.2~ u.2::l
0.10
0.10
0.50
0.50
0.25
0.10
0.10
0.10
0.10
0.25
0.10
0.10
0.21
2.5
0.50
0.15
0.25
0.25
0.10
0.25
0.25
0.25
0.25
0.15
0.10
0.10
0.25
0.10
0.25
0.11
0.10
0.15
25
%RECOVERY
~ a ................ ..
103
109
109
107
103
109
108
106
# Result(s) associated as marked on the header
Notes: Sample Amount 25ml Final Volume: 25ml
Prepared by VLu Analyzed by : VLu
# Sample Amount 5.0ml Final Volume: 25ml
LOD
(ug/l) -_ ...... -.... -
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.50 0.30
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.50
10
0.50
10
0.50
10
0.20
0.20
0.30
0.20
0.30
0.50
0.50
0.20
0.20
1.0
1.0
0.50
0.20
0.20
0.20
0.20
0.50
0.20
0.20
0.50
5.0
1.0
0.30
0.50
0.50
0.20
0.50
0.50
0.50
0.50
0.30 0.20
0.20 0.50
0.20 0.50 0.30
0.20 0.30
50
QC LIMIT
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
# Prepared by VLu Analyzed by : VLu
Detection limits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 24 of 560
METHOD SWS030B/B260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/10123 14:25
Project Too-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/17/23 12:41
Sample ID S-127-15-052023 Date Analyzed: 05/17/23 12:41
Lab Samp ID 23E120-03 Dilution Factor: 1
Lab File ID REC393 Matrix: WATER
Ext Btch ID V067E17 % Moisture: NA
Calib. Ref. ROC593 Instrument ID: 67
RESULTS LOO DL LOD
PARAMETER(S) (ug/l) (ug/L) (ug/l) (ug/l)
aa ......... ____ ........................... ...... a .......... • .. .. · .. _a .......... ................ ................
1.1.1.2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. 1-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane NO 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform 130E 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISoprO~Ylbenzene ND 1.0 0.10 0.20
m.WXf: ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride 0.69J 2.0 0.50 1.0
Methil tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1. 2. 3-Trichlorobenzene ND 1.0 0.15 0.30
l,4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
................................ -...... _ ....... ... -_ ........ _ . .................. ---_ .. -._ .... -.. ........ __ .... -
1.2-Dichloroethane-d4 10.3 10.0 103 70-130
4-Bromofluorobenzene 10.9 10.0 109 70-130
Toluene-dB 10.9 10.0 109 70-130
Dibromofluoromethane 10.7 10.0 107 70-130
Notes: Sample Amount : 25ml Final Volume : 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 25 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC393.D
Acq On 17 May 20'23 12:41 pm
Sample 23E12G-G3
Misc 25mL
(QT Reviewed)
Vial: 15
Operator: VLu
Inst 67
Multiplr: 1.00'
MS Integration Params: RTE.P
Quant Time: May 18 8:30' 20'23 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 826GB
Wed Apr 26 14:33:42 20'23
Initial Calibration ~
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10'.15 114 2220'549 10'.0'0' ug/l 0'.01
55 ) CHLOROBENZENE-D5 15.60' 117 15820'83 10'.0'0 ug/l 0'.00'
74) l,2-DICHLOROBENZENE-D4 19.50' 152 43120'3 10'.0'0' ug/l 0.01
---
"System Monitoring Compounds
36) Dibromofluoromethane 8.21 III 567594 10'.73 ug/l 0'.01
Spiked Amount 10'.0'0'0' Recovery 107.30%
43) l,2-Dichloroethane-d4 9.30' 65 415369 10'.28 ug/l.-0.0'1
Spiked Amount 10'.0'0'0' Recovery 10'2.80%
56 ) Toluene-d8 12.97 98 239160'3 10'.87 ug/l /"' 0'.0'0'
Spiked Amount 10'.0'0'0' Recovery 10'8.70'%
77 ) 4-Bromofluorobenzene 17.60' 95 63320'9 10'.87 uglY 0'.0'0'
Spiked Amount 10'.0'0'0' Recovery 10'8.70'%
/'
Target Compounds Qvalue
20') Methylene chloride 4.54 49 710'51 0'.69 ug/l 98
32) Chloroform 7.71 83 14245767 --l3J-.56 ug/l E.. 97
(#) = qualifier out of range (m) = manual integration
REC393.D V067D26.M Thu May 18 0'8:30':44 20'23 Page 1
REPORT ID: 23E120 Page 26 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC393.D
Aeq On 17 May 2023 12:41 pm
Sample 23E120-03
Mise 25mL
Vial: 15
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:30 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
Abundance------~~-----------------Trc:HEG39J:D-----~----------------------
8500000
8000000!
7500000 1
70000001',
!
6500000;
60000001
i
:
I_
1_
5500000: •
5000000,
4500000,
4000000:
i
, I
3500000
3000000
2500000 •
2000000, ,
15000001
1000000
500000
(f)
oj
c: co
~
E e
0 ::>
'" 0
E e
.0
i5
\ :"\
.n a
ui (f) W .,; z z "9 w w " N N c: Z Z " w W ::> CD (f) CD (5 0 oj 0 f-a:: c: a:: 0 " 0 ...J N
:::l :c c: .,
...J () .0 w-e 15 0
..to ::>
(f) '" 0
'" E ~ e
c: CD
co ..t
~ e
0 :c
" i5
N.
'" a
W
Z w
N z
W
CD
0 a::
0
...J :c
()
15
N.
Time--> 0~o;~3.00--OC4.00 5.00 6.00 7.00 '8:~~ 9.0010:0011~00 12.00 13:00 14.00 15.00 16.0017.00 18.00 19.0020.0021.00
REC393.D V067D26.M Thu May 18 08:30:45 2023 Page 2
REPORT ID: 23E120 Page 27 of 560
Abundance--------Scan 146-(4.51TmJrij:RDC593TIT0
76
i
I
i
84
44
#20
Methylene chloride
Concen: 0.69 ug/l
RT: 4.54 min Scan# 147
Delta R.T. 0.03 min
Lab File: REC393.D
Acq: 17 May 2023 12:41 pm
I 01--~i-r--r
/n/z--> 3'0 3'5
i ! iii ~2 , ! ' , , ~~ ~~ 70, I J,9 ~ ~ ~ $ ® ~ ro ~ 00
Scan 147 r4.541 min): REC393.D
Tgt Ion: 49 Resp: 71051
f,bundance
! Ra~1
I
i
44
419
!
84
i
, 40', . i II 76 , I II 8,,8
, O~~~~~-!:!! 'I ! 'I i 'I "i'iil "1""1' 'I
~~ W ~ ~ ~_~ ~ W ~ ro ~ 00 ~ 00 ~
Abundance Scan 147 (4.541 min): R.-'cEC'""3"'9"'3'-r.D'--r._ c'----=-c-~--=-"-----I
'i9
84
Sub!
Ion Ratio Lower Upper
49 100
84 69.4 41.7 101.7
86 45.6 15.7 75.7
bundance on 9-:-01l\'n),m1O-49~70TREC39TD
lion 84.00 (83.70 to 84.70): REC393.D
lion 86.00 (85.70 to 86.70): REC393.D
15000j 4.54 :,
i l
10000 1
1 50: i 5000:
I i 41' I 76i,!',',. , 0 1 I ,~ If:
11/
;m/z--> _ ~~~_3_5~_-=-"4~bc-\-h_~4~!5~' _1+1~~_b+I~:5:;!5,---'~~_6-'-'_0'-_"-'~6.';!5:'~' _7'-b~' :~7..C-15+_~_'''8:b::..C-8:5~~''9'-'.0~''--:9'-5::-----,--,,--im--,e,-----_>_----,-4.=3:0'~:::;::4 .. ::;::40;:::;' :::;:4";::~:;:::50;::::;::;:::4.60 __ ~4.Z~·4.80
Abundance
i Re~:
I
47
'Scan 363 (7.6!f3 min): RD'C593.D (-)
8i3 I #32
I Chloroform
I
I Concen: 129.56 ug/l
i! RT: 7.71 min Scan# 364
I i I De 1 taR. T . 0 . 03 mi n
I Lab File: REC393.D
55 I, i Acq: 17 May 2023 12 :41 pm
0'
m/z-->
Abundance
,; Iii 74 ,! I ~120 i
40 45''o--,--,-"'r-r6~'o~' 'c-r"T7--Tb-T' +-C-~8'bP11 ,-'-r'-r, 9-'-b'" ~'1 0~0~-'-1'1 oo--r-r, , 120 . 130 Tgt Ion: 83 Resp:14245767
Ra~,
47
! 1
0,--1 ~~4+1~ii-Lil!
m/z--> 40 ' '5b'
r.-lA.C:bu~nCJd=an=-=cC=-e---C.
!
Sub
50
47
Scan 364 (7.712 min): REC393.D Ion Ratio Lower Upper
8~ 83 100
85 65.5 39.4 99.4
47 25.9 0.0 56.0
bundancelOn-ff:r.nO-(ff27{ftoff370r-REC393D
3500000110n 85.00 (84.70 to 85.70): REC393.D
lion 47.00 (46.70 to 47.70): REC393.D
i I
, i ' 3000000 i
5:0 ,~!~, 8'01 I ,ll"9b,,9::,4c,-,--10'" 0'~"1'-10~1"+~+~~~4 130 25000001
Scan 364 (7.712 min): REC393.D (-) I
7.71
8,3 2000000)
1500000,
1000000;
500000:
REC393.D V067D26.M Thu May 18 08:30:46 2023 Page 3
REPORT ID: 23E120 Page 28 of 560
METHOD SWS030B/B260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/10123 14: 25
Project TEAD-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/18123 16: 07
Sample 10 S-127-15-052023 Date Analyzed: 05/18/23 16:07
Lab Samp 10 23E120-031 Dilution Factor: 5
Lab File 10 REC430 Matrix: WATER
Ext Btch ID V067E18 % Moisture: NA
Calib. Ref. RDC593 Instrument 10: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/L) (ug/L)
.a ....... __ ..... _ ..••• ___ ... ____ ---_ .. _ .. --_. .. -_ .. a ........... ........... a ...... .. .. __ .--_ ....
1.1.1.2-Tetrachloroethane ND 5.0 0.50 1.0
1. 1. I-Trichloroethane ND 5.0 0.50 1.0
1. 1. 2. 2-Tetrachloroethane ND 5.0 0.50 1.0
1.1.2-Trichloroethane ND 5.0 0.50 1.0
1.1-Dichloroethane ND 5.0 0.50 1.0
1.1-Dichloroethene ND 5.0 0.50 1.0
1.1-Dichloropropene ND 5.0 0.50 1.0
1.2.3-Trichlorogropane ND 10 1.2 2.5
1.2.4-Trichloro enzene ND 5.0 0.75 1.5
1.2-Dibromo-3-chloropropane ND 10 1.2 2.5
1.2-Dichlorobenzene ND 5.0 0.50 1.0
1.2-Dichloroethane ND 5.0 0.50 1.0
1.2-Dichlorogropane ND 5.0 0.50 1.0
1.3-Dichloro enzene ND 5.0 0.50 1.0
1.3-Dichlorogropane ND 5.0 0.50 1.0
1.4-Dichloro enzene ND 5.0 0.50 1.0
2.2-Dichloro~ro~ane ND 5.0 1.2 2.5
2-Butanone ( EK ND 100 25 50
2-Chlorotoluene ND 5.0 1.2 2.5
2-Hexanone ND 100 25 50
4-Chlorotoluene ND 5.0 1.2 2.5
Acetone ND 100 25 50
Benzene ND 5.0 0.50 1.0
Bromobenzene ND 5.0 0.50 1.0
Bromochloromethane ND 5.0 0.75 1.5
Bromodichloromethane ND 5.0 0.50 1.0
Bromoform ND 5.0 0.75 1.5
Bromomethane ND 5.0 1.2 2.5
Carbon Disulfide ND 5.0 1.2 2.5
Carbon Tetrachloride ND 5.0 0.50 1.0
Chlorobenzene ND 5.0 0.50 1.0
Chloroethane ND 10 2.5 5.0
Chloroform 130 5.0 0.50 1.0
Chloromethane ND 5.0 1.2 2.5
cis-1.2-Dichloroethene ND 5.0 0.50 1.0
CiS-1.3-Dichloro~ropene ND 5.0 0.50 1.0
Dibromochloromet ane ND 5.0 0.50 1.0
Dibromomethane NO 5.0 0.50 1.0
Dichlorodifluoromethane NO 5.0 1.2 2.5
Ethyl benzene NO 5.0 0.50 1.0
ISOprovylbenZene ND 5.0 0.50 1.0
m.~-~ ene NO 10 1.0 2.5
4-et yl-2-Pentanone NO 50 12 25
Methylene Chloride ND 10 2.5 5.0
Methtl tert-butyl ether (MTBE) NO 5.0 0.75 1.5
n-Bu ylbenzene NO 5.0 1.2 2.5
n-Propylbenzene NO 5.0 1.2 2.5
o-Xylene NO 5.0 0.50 1.0
~-IsoproVbltoluene NO 5.0 1.2 2.5
ec-Buty enzene NO 5.0 1.2 2.5
Styrene NO 5.0 1.2 2.5
Tert-Butylbenzene NO 5.0 1.2 2.5
Tetrachloroethene NO 5.0 0.75 1.5
Toluene NO 5.0 0.50 1.0
Trans-1.2-Dichloroethene NO 5.0 0.50 1.0
Trans-1.3-Dichloropropene NO 5.0 1.2 2.5
Trichloroethene ND 5.0 0.50 1.0
Trichlorofluoromethane NO 5.0 1.2 2.5
Vinyl Chloride NO 5.0 0.55 1.5
1.2-Dibromoethane NO 5.0 0.50 1.0
1. 2. 3-Trichlorobenzene NO 5.0 0.75 1.5
l,4-Dioxane NO 500 120 250
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
.................... -.................... __ .. --.. _ ........ _--...... _-..... __ .. -_ ............. ...... __ ......
1.2-Dichloroethane-d4 51.5 50.0 103 70-130
4-Bromofluorobenzene 54.7 50.0 109 70-130
Toluene-d8 53.9 50.0 108 70-130
Dibromofluoromethane 52.9 50.0 106 70-130
Notes: Sample Amount : 5.0ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 29 of 560
Quantitat-ion Report
Data File D:\HPCHEM\1\DATA\23E18\REC430.D
Aeq On 18 May 2023 4:07 pm
Sample 23E120-03I 5X
Mise 5.0mL
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 23
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Time: May 19 8:25 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
~.
D:\HPCHEM\1\METHODS\V067D26.M (RTE
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Integrator)
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2256707 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1595081 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 427025 10.00 ug/l 0.00
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 568687 10.57 ug/l 0.02
Spiked Amount 10.000 Recovery 105.70%
43 ) l,2-Dichloroethane-d4 9.31 65 423111 10.30 ug/l ~0.02
Spiked Amount 10.000 Recovery 103.09J-
56 ) Toluene-d8 12.97 98 2392739 10.79 ug/l 0.00
Spiked Amount 10.000 Recovery 107.90%
77 ) 4-Bromofluorobenzene 17.60 95 631524 10.95 uglY 0.00
Spiked Amount 10.000 Recovery 109.50%
/
.. Target Compounds Qvalue
32) Chloroform 7.71 83 2865482 7 4 ug/l 96
(#) = qualifier out of range (m) = manual integration
REC430.D V067D26.M Fri May 19 08:25:44 2023 Page 1
REPORT ID: 23E120 Page 30 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC430.D
Aeq On 18 May 2023 4:07 pm
Sample 23E120-03I 5X
Mise 5.0mL
Vial: 23
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 8:25 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
85000001
!
8000000'
i
7500000]
7000000,
!
6500000)
!
6000000:
55000001
i
50000001
4500000'
4000000:
3500000 1
3000000j
2500000
2000000
1500000:
1000000:
500000
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC:REC430.D
w (f)
<Xi z J: W
N c Z '" ::;: W ::>
'" "0 ....-0 f-
U a: g 0
::J .g ...J
e u..
0 0 :c (f) "'. u ",' (f)
c v '" "C ;5 " '" c E .. e ~ 0 ::> e <= .Q 0
E .<:
0 e 0 .0 N. 0
",-0
ill z w
N
Z w
'" (f)
0 .,; a: c
0 '" ...J N c I '" U .0 e
0 ::> <= 0
E e
'" '"
v
0
ill
Z w
N z
W
'" 0 a:
0
...J
I
U
0
N.
o ------~
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11:0012:00 13:00 14:0015.00 16.00 17.00 18.0019.0020.0021.00
REC430.D V067D26.M Fri May 19 08:25:45 2023 Page 2
REPORT ID: 23E120 Page 31 of 560
Re®i
!
47
I ,
, ,I
; ,
II
#32
Chloroform
Concen: 25.64 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC430.D
Acq: 18 May 2023 4:07 pm
,55 II I ,i, 74 I I 120 I O~'I :", ""', ,II'" ",~', ,'" I
m/z--> 30 ~~~_~O 70 80 90 100 _110~~~ 13~
Abliildance--Scan 364 (T.Tf3Il1In):-RE<ITOTI ~
~
Tgt Ion: 83 Resp: 2865482
Ion Ratio Lower Upper
83 100
Ra~,
47
i
I!
i i , :
: [
i I o 41 II i: 58 70 ,1,1 I 118 124
mlz--> 3t-b~' '-'-'-'4'O~-,Lp5+-'o~'; '~6-T:O-'-'--'-'-7rbr-r-T~8T'o+" -p, T'-r-9"b~T1~60~' ·~1"1-'0-.--r+dt-0'-'-'-'1-'3~0
\A.bundance Scan 364\T.713IT11n}:REC430:D (-)
~3
Sub,
m/z-->
50
1
I
47 !
i 0~,41 ~li!+,~~58~~7TO~~~u,~,I~I~~_~~~~~1t-18h,1~2~~
30 40 50 6'0 7'0 8'0 g'O 106 1 i 6 120 130
85 65.1 39.4 99.4
I 47 26.2 0.0 56.0
~celOi1lIT'CRf\8Z.70T01l3:7DT REG43000'
7000001l0n 85.00 (84.70 to 85.70): REC430D
. lion 47.00 (46.70 to 47.70): REC430.D
600000!
500000i
!
400000!
300000 1
i
200000j
1000001
I
7.71
O~~ "~. "'"---
ime--> ~o 7.60 7.80 8.00 8.20
REC430.D V067D26.M Fri May 19 08:25:46 2023 Page 3
REPORT ID: 23E120 Page 32 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client : BRICE Date Collected: 05/09/23 14:20
Project : TEAD-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/17/23 13:06
Sa!DPle ID : S -128 -15 -052023 Date Analyzed: 05/17/23 13:06
Lab Samp ID: 23E120-04 Dilution Factor: 1
Lab File ID: REC394 Matrix: WATER
Ext Btch ID: V067E17 % Moisture: NA
Calib. Ref.: RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/l) (ug/l) (ug/L)
6 ~ 6 a .... _ .......... _ .. _ ..... __ • __ • _ ...... _ .. . .. _._--_ .. ..... _--_.-.. ................. -...... _--_ .....
1.1.1.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene 0.10J 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Ch 1 oroethane ND 2.0 0.50 1.0
Chloroform 12 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m,~-Xf: ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1. 2. 3-Trichlorobenzene ND 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
... _--_ ......... __ .... ---........ _-_. __ .. ........... _ .. -..... a ........ _ . .............. -_ ... __ .....
1.2-Dichloroethane-d4 10.3 10.0 103 70-130
4-Bromofluorobenzene 11.1 10.0 111 70-130
Toluene-d8 10.9 10.0 109 70-130
Dibromofluoromethane 10.7 10.0 107 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b1' : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 33 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC394.D
Acq On 17 May 2023 1:06 pm
Sample 23E120-04
Misc 25mL
(QT Reviewed)
Vial: 16
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:31 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M URTE Integrator)
METHOD 8260B ~
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) 1,4-DIFLUOROBENZENE 10.15 114 2147899 10.00 ug/l 0.01
55) CHLOROBENZENE-D5 15.60 117 1518659 10.00 ug/l 0.00
74) 1,2-DICHLOROBENZENE-D4 19.50 152 409762 10.00 ug/l 0.02
I System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 547712 10.70 ug/l 0.02
Spiked Amount 10.000 Recovery 107.00%
43 ) 1,2-Dichloroethane-d4 9.30 65 400854 10.26 ug/l r~ 0.02
Spiked Amount 10.000 Recovery 102.60%
56 ) Toluene-d8 12.99 98 2308177 10.93 ug/l/' 0.02
Spiked Amount 10.000 Recovery 109.30%
77 ) 4-Bromofluorobenzene 17.60 95 611663 11.05 ug/~ 0.00
Spiked Amount 10.000 Recovery 110.50%
.,/
Target Compounds Qvalue
32 ) Chloroform 7.71 83 1300459 12.23 ug/l 96
44) Benzene 9.48 78 29751 .--0.10 ug/l 96
,/
(#) = qualifier out of range (m) = manual integration
REC394.D V067D26.M Thu May 18 08:31:20 2023 Page 1
REPORT ID: 23E120 Page 34 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC394.D
Aeq On 17 May 2023 1:06 pm
Sample 23E120-04
Mise 2SmL
Vial: 16
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:31 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
:1
85000001
8000000
7500000;
70000001,
6500000 1
I
i
6000000]
5500000
5000000:
4500000: •
4000000'
3500000
3000000
2500000
2000000j
1500000
1000000,
500000
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Trc:REG394.D
C/l ::;: oi ...: co
c5 '" £; g Q)
E
.E e e 0
0 :l
:c '5 u E e ,g
0
;'1
on o
W z w
~ w co o
~ o
...J
I
U
C/l
oi co
Q)
N co
Q) .c e o
:l
1 co .,c
..¢ o
W z
W
N
Z
W
<D o
~ o
...J
I
U
is
N.
O'-~::--.~--.---.-~, ~, ,----
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.0010.0011:00 12.0013:0014.0015.00 16:00 17.00 18.00 19.0020.00 21.00
REC394.D V067D26.M Thu May 18 08:31:21 2023 Page 2
REPORT ID: 23E120 Page 35 of 560
-----,
i
I
I
47
42 55 74' 120 ,
#32
Chloroform
Concen: 12.23 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC394.D
Acq: 17 May 2023 1:06 pm
m/z--> ~~~7f-1i~b~.l-'6b 7b'4-~~8bi" \b 100 , i----,--,....,.~~r-~ iTt
110 120 130 i 9 Ion: 83 Resp: 1300459
Abuildance------------scil.n3Q4l'T.71T mm): REC394.D
I ~3
!
Ra'5b;
Sub I
50
1
47
118
, -----r-'-~_-,~, ~,
110 120 130
! Ion
83
85
47
Ratio
100
65.0
25.7
Lower Upper
39.4 99.4
0.0 56.0
bundancelon 83~OO-\827GlO83~70T"REC394:D
'Ion 85.00 (84.70 to 85.70): REC394.D
300000:lon 47.00 (46.70 to 47.70): REC394.D
250000:
200000'
150000'
1
100000j
i
500001
7.71
Scan 485 (9.465 mm): RDC59:r.D (-)
78 l #44
i
RefOi
I
52 I 39 62, I
, 4R I" 56 i " 74 !!
O-c--------, ' ~,'i U~T-~, ,"," , ' , II' I '
m/z--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95
Abundance-------Scan 48OT9-:48nrnlnyR'EC3'94.o--
78
44
51
39 .:, 65 74 Ii
98
I'
100 105
I I, II, I
I O~"T ~~~~! H-i '~'''' '~TTI ,',1!, I~, h-, TTTl' !-,~, +,' ,~! i+1 :'-'~' ~'T', ~'TTI 'TTT"~~~~
m/z--> 30 35 40 45 50 55 60 65 70 75 80 85 90 '9'5' 100 105
Abundance Scan-2f80(9:48\J1Ti1nfRE'G:l94:DT-}
Sub i
50!
i
O!
:m/z--> 30
39
44
35 40 45
51
' ' , i"
50 55
65
60 65
78
I 74 i
70~'~ :~o 85 9'0 9'5 100 1~
I
Benzene
Concen: 0.10 ug/l
RT: 9.48 min Scan# 485
Delta R.T. 0.02 min
Lab File: REC394.D
Acq: 17 May 2023 1:06 pm
Tgt Ion: 78 Resp: 29751
Ion Ratio Lower Upper
78 100
77 25.6 0.0 53.5
52 16.5 0.0 47.6
I bundancelon 7KO-0,\7770Tcl7K7n):HEC39'4.D
lion 77.00 (76.70 to 77.70): REC394.D
8000!IOn 52.00 (51.70 to 52.70): REC394.D
9.48
6000·
4000:
2000:
~
o ~ ,:::;:::::::::::;::::::::=::;:::::
ime--> 9.30 9.40 9.50 9.60
REC394.D V067D26.M Thu May 18 08:31:22 2023 Page 3
REPORT ID: 23E120 Page 36 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/10/23 13: 10
Project TEAD-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/17/23 13:32
Sa!DPle ID S-135-16·05-2023D Date Analyzed: 05/17/23 13:32
Lab Samp ID 23E120-05 Dilution Factor: 1
Lab File ID REC395 Matrix: WATER
Ext Btch ID V067E17 % Moisture: NA
Calib. Ref. RDC593 Instrument 10: 67
RESULTS LOQ OL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/L) (ug/L)
_. __ a •• ______ •••• _. ___________ ---_ .. ---_. ... _-._ .. -. ____ a. _____ ____ a ____ .. _
1. 1. 1. 2-Tetrachl oroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane NO 1.0 0.10 0.20
1.1.2.2-Tetrachloroethane NO 1.0 0.10 0.20
1. 1. 2·Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane NO 1.0 0.10 0.20
1.2-Dichlorogropane NO 1.0 0.10 0.20
1.3-Dichloro enzene NO 1.0 0.10 0.20
1.3-0ichlorogropane NO 1.0 0.10 0.20
1.4-0ichloro enzene ND 1.0 0.10 0.20
2.2'Oichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride 19 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform 1.4 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-0ichloroethene ND 1.0 0.10 0.20
CiS'1.3-0ichloro~ropene NO 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Oichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOpro~Ylbenzene ND 1.0 0.10 0.20
m.~-~ ene NO 2.0 0.21 0.50
4· et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride NO 2.0 0.50 1.0
Methtl tert·butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~&ltoluene ND 1.0 0.25 0.50
ec-Buty enzene NO 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-0ichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene NO 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
l,4-Dioxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
•• ____ a ... ____ ....... _ •• __________ ----------------._ ...... -____ a_Me_a • .--_ ......... -
1.2-0ichloroethane-d4 10.4 10.0 104 70-130
4-Bromofluorobenzene 10.8 10.0 108 70-130
Toluene·d8 10.8 10.0 108 70-130
Dibromofluoromethane 10.6 10.0 106 70·130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b1 : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 37 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC395.D
Acq On 17 May 2023 1:32 pm
Sample 23E120-05
Misc 25mL
(QT Reviewed)
Vial: 17
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:31 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.15 114 2156555 10.00 ug/l 0.02
55) CHLOROBENZENE-D5 15.60 117 1534996 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.50 152 414548 10.00 ug/l 0.02
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 545523 10.61 ug/l 0.02
Spiked Amount 10.000 Recovery 106.10%
43) l,2-Dichloroethane-d4 9.31 65 406518 10.36 ug/l~ 0.02
Spiked Amount 10.000 Recovery 103.60%
56 ) Toluene-d8 12.99 98 2307441 10.81 ug/l~ 0.02
Spiked Amount 10.000 Recovery 108.~O%
77 ) 4-Bromofluorobenzene 17.62 95 602754 10.76 ugJa:' 0.02
Spiked Amount 10.000 Recovery 1~60%
Target Compounds Qvalue
19 ) Carbon disulfide 4.53 76 38685 0.16 ug/l 97
32) Chloroform 7.71 83 154827 ~1.45 ug/l 95
41 ) Carbon tetrachloride 9.12 119 1354136 ' 18.78 ug/l 100
./
(#) = qualifier out of range (m) = manual integration
REC395.D V067D26.M Thu May 18 08:31:59 2023 Page 1
REPORT ID: 23E120 Page 38 of 560
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI7\REC39S.D
Aeq On 17 May 2023 1:32 pm
Sample 23E120-0S
Mise 2SmL
Vial: 17
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:31 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration Abundance---------------------------------TIC:REGJ90.U------------------
8000000
7500000
,
7000000{
6500000:
] i
6000000i
5500000; :
i
5000000i
4500000,
,
4000000i
3500000] ,
3000000 .
",-
,
2500000'
2000000
1500000
::;;
~
1000000' <li
" <;: :;
'" 'is
C
(f) 0
w-oo uJ
z ~ z " L.LJ L.LJ
N 0 N C Z uJ z .,
(f) L.LJ " L.LJ Z ro (5 ro <li L.LJ I-a C a " N
::;; a:: a:: N z
1--a a C L.LJ -' " ro <li :::> I .c a -' e " u.. U a:: ." 0
0 15 " a
(f) :c ..I: <= -' ,,-l;l<n_ 0 I E U C "'" e '" ~"9 15 £ ro N. " c" .... E OC
.c'" e ~ 0 ::;; " Ue
~ <= 0 0 :c c5 E 0 g e is .c ,\~~ .E is e
0
500000 €
'" U
0 :c
U
Time-->
o
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.0010:00 11.0012:00 13.00 14.00 15:00 16:0017:00 18.00 19.0020.00 21.00
REC39S.D V067D26.M Thu May 18 08:32:00 2023 Page 2
REPORT ID: 23E120 Page 39 of 560
49
#19
Carbon disulfide
Concen: 0.16 ug/l
RT: 4.53 min Scan# 146
Delta R.T. 0.03 min
Lab File: REC395.D
84
44 i I
Acq: 17 May 2023 1:32 pm
O~.-~,---~~~~-r'+~-. " 64, 70 ! .. j79r--~TI~' .-rTTTC
m/z--> 35 40 45 5'0 55 60 65 70 75 80 85 90 9'5
Abunaance----~ --Scan 'I46l432Tmin):RE;390:0
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
38685
Upper
7.6
44
40 49 84 67
Oil I I
im/z--> ~T'3T5~"4b~-T4'5~+-r50+--C' '5T'15~6"b~T6"'5+' "7"''0 i5' 8'0 85 90 "9'5'
fA.bundance ---Scan 146 (4.52TmInYl~EC395.D (-)
7,6
Sub
50:
f
I
10.3 6.3 11. 7
bundanceron 7El.OU(75.70-f670.70): REC395,O
lion 78.00 (77.70 to 78.70): REC395.D
80001
i 4.53
7000
1
60001
!
50001 , ,
4000 1
3000j
2000i
1000; , 49 84 ! ~
Ol-n I I 617 ii, I oi;:::;:::;:=;=;==:";::::;,::;=;=::;:::,:::;::::;=;:c~, ~:;:::;:::;'::::;::
rn/z-->
Abundance
RefO
~3"5~4T'0~' ·--n-4
Tb'· ,,-t-5"bh--c-"5'5" ~'T6T'0TT'6'15,.j, " ~7lrro ~7'15h-+-"8b" "+-8,--i15~9'b~' ,. "9'5~' tnme--> 4Ao' 4.50' 4.60 . 4.70 4.80
Scai1303\T.6'83 min): RDC593.D (-)
~3
47 i i
I #32
Chloroform
! ,
I
120 i
Concen: 1.45 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC395.D
Acq: 17 May 2023 1:32 pm
01 4~ii! 5!5 74 ,i,l i
'm/z--> 3'0 40 50 6070 '8'0 9'0 100' 110 1~0' 130 I Tgt Ion: 83 Resp: 154827
Abundance--~---~-~-~~Scan 364 (7.712 mln):'REC395:D
. 83
!
47
i 40. i I, , " , . II i I !. , . ,'" 118
Ion Ratio Lower Upper
83 100
85 64.3 39.4 99.4
47 24.9 0.0 56.0
roo bundance .. lorl --8:r.O-0-(8T.7UloET70): -REC395.D
:Ion 85.00 (84.70 to 85.70): REC395,O
35000Jon 47.00 (46.70 to 47.70): REC395,O
7.71 m/z--> ~rJO,.-+-,-+"-t50~~6-0~r-r-;70~~8To+,+,-.,-L,--9'--0 --'-"1TOO~~1""1nO~+1T20~'13o
lA.buna~mce ---=--:C-~Scan 364 (7.712 min): REC3'9"'5':-;.D~(-~) --'-'-=-------=-==-=--------'-=-=-1
300001
250001
20000)
Sub'
50
47
83
15000
I
i 10000j
5000
m/z--> ~O-:~---·~5~O~==6=-0~~~'7--=-'o~:-=-8~0"-,-,"-..4-,90~'~~10~0-~~1~1'0~~+;-:hO~~13~0 ,~ime--> 0:7~6~'7.~;-:;.70 ~{8~~~i~Q 8.00
REC395.D V067D26.M Thu May 18 08:32:01 2023 Page 3
REPORT ID: 23E120 Page 40 of 560
RefOj
I
47
0 , 42
i ~--+-'-----'~'~: -,
m/z--> 30 40 50
lA.bundance·
, !
82
59 70 , I
60 7'0 ~~ 100" 110 '
Scan 460 (9.1T5ITITnJ: REC395.0
1 1
I
• i F3
i I .
120
19
1 i ! I
i:
Ra~j
47 82 l
I i I
'41 58 70 Iii ~23
m/z--> ~~~~~~40 50 60' 7'0 8'0' i I 9'0 100 110120' 130
Abundance ... -~ ·------s-can 460 (9.115 mlilfREC395.D~'-----.c........~
i
Sub!
50i
! 41
I 0, ,
'I'!z--> 3'0 40
47
i
i 58 ,
5'0 6'0
1 "l
82
!
I I
70 II
7'0 '8b I do 100 110
#41
Carbon tetrachloride
Concen: 18.78 uq/l
RT: 9.12 min Scan# 460
Delta R.T. 0.02 min
Lab File: REC395.D
Acq: 17 May 2023 1:32 pm
Tgt Ion:119 Resp: 1354136
Ion Ratio Lower Upper
119 100
117 103.2 73.4 133.4
buiidiiiicelon119.00~{n8.70 10 119.70): REC395
lion 117.00 (116.70 to 117.70): REC395
2500001
200000)
1500001
1000001
REC395.D V067D26.M Thu May 18 08:32:02 2023 Page 4
REPORT ID: 23E120 Page 41 of 560
METHOD SWS030B/B260C
VOLATILE ORGANICS BY GC/MS
Client : BRICE Date Collected: 05/10123 13: 05
Project : TEAD-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/17/23 13:5B
Sample ID ; S-135-16-052023 Date Analyzed: 05/17/23 13:5B
Lab Samp 10: 23E120-06 Dilution Factor: 1
Lab File 10: REC396 Matrix: WATER
Ext Btch 10: V067E17 % Moisture: NA
Calib. Ref.: RDC593 Instrument 10: 67
RESULTS LOQ OL LOD
PARAMETER{S) (ug/L) (ug/L) (ug/L) (ug/L)
----_ .. _----------.. -------------_ .. ---_.------.-_ .. _-.-_. __ .---. . -_ ... _._ .... -
1. 1. 1.2-Tetrachloroethane NO 1.0 0.10 0.20
1. 1. I-Trichloroethane NO 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane NO 1.0 0.10 0.20
1.1.2-Trichloroethane NO 1.0 0.10 0.20
1.1-0ichloroethane NO 1.0 0.10 0.20
1.1-0ichloroethene NO 1.0 0.10 0.20
1.1-0ichloropropene NO 1.0 0.10 0.20
1.2.3-Trichlorogropane NO 2.0 0.25 0.50
1.2.4-Trichloro enzene NO 1.0 0.15 0.30
1.2-0ibromo·3-chloropropane NO 2.0 0.25 0.50
1.2-0ichlorobenzene NO 1.0 0.10 0.20
1.2-0ichloroethane NO 1.0 0.10 0.20
1.2-0ichlorogropane NO 1.0 0.10 0.20
1.3-0ichloro enzene NO 1.0 0.10 0.20
1.3-0ichlorogropane NO 1.0 0.10 0.20
1.4-0ichloro enzene NO 1.0 0.10 0.20
2.2-0ichloro~ro~ane NO 1.0 0.25 0.50
2-Butanone ( EK NO 20 5.0 10
2-Chlorotoluene NO 1.0 0.25 0.50
2-Hexanone NO 20 5.0 10
4-Chlorotoluene NO 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene NO 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane NO 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride 1B 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform 1.4 1.0 0.10 0.20
Chloromethane NO 1.0 0.25 0.50
cis-1.2-0ichloroethene NO 1.0 0.10 0.20
CiS-1.3-0ichloro~ropene NO 1.0 0.10 0.20
Oibromochloromet ane NO 1.0 0.10 0.20
Oibromomethane NO 1.0 0.10 0.20
Oichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISoprO~Ylbenzene NO 1.0 0.10 0.20
m.wxf: ene NO 2.0 0.21 0.50
4-et yl-2-Pentanone NO 10 2.5 5.0
Methylene Chloride NO 2.0 0.50 1.0
Meth{l tert-butyl ether (MTBE) NO 1.0 0.15 0.30
n-Bu ylbenzene NO 1.0 0.25 0.50
n-Propylbenzene NO 1.0 0.25 0.50
o-Xylene NO 1.0 0.10 0.20
~-Isopro~bltoluene NO 1.0 0.25 0.50
ec-Buty enzene NO 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert-Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene NO 1.0 0.15 0.30
Toluene NO 1.0 0.10 0.20
Trans-1.2-0ichloroethene NO 1.0 0.10 0.20
Trans-1.3-0ichloropropene NO 1.0 0.25 0.50
Trichloroethene NO 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2-0ibromoethane NO 1.0 0.10 0.20
1.2.3-Trichlorobenzene NO 1.0 0.15 0.30
1,4-0ioxane NO 100 25 50
SURROGATE PARAMETER{S) RESULT SPK_AMT %RECOVERY QC LIMIT
.. -.. __ .................... -.. __ .. -_. . _._._-----. _---_ .. _.-. ...... --_ .. -. ---_ ........
1.2-0ichloroethane-d4 10.4 10.0 104 70-130
4-Bromofluorobenzene 10.7 10.0 107 70-130
Toluene-dB 10.9 10.0 109 70-130
01bromofluoromethane 10.7 10.0 107 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 42 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC396.D
Acq On 17 May 2023 1:58 pm
Sample 23E120-06
Misc 25mL
(QT Reviewed)
Vial: 18
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:32 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2188184 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1556215 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.50 152 421617 10.00 ug/l 0.02
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 560194 10.74 ug/l 0.02
Spiked Amount 10.000 Recovery 107.40%
43 ) l,2-Dichloroethane-d4 9.31 65 414413 10.41 ug/l ~0.02
Spiked Amount 10.000 Recovery 104.10%
56) Toluene-d8 12.99 98 2359011 10.90 ug/l ,'---0.02
Spiked Amount 10.000 Recovery 109.00%
77 ) 4-Bromofluorobenzene 17.62 95 610781 10.73 ug//Y 0.02
Spiked Amount 10.000 Recovery 107.30%
/"
'Target Compounds Qvalue
19 ) Carbon disulfide 4.53 76 41130 0.16 ug/l 97
32) Chloroform 7.71 83 152765 1. 41 ug/l 97
41 ) Carbon tetrachloride 9.12 119 1345392 '~18.39 ug/l 99
/'
(#) = qualifier out of range (m) = manual integration
REC396.D V067D26.M Thu May 18 08:32:29 2023 Page 1
REPORT ID: 23E120 Page 43 of 560
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI7\REC396.D
Aeq On 17 May 2023 1:58 pm
Sample 23E120-06
Mise 25mL
Vial: 18
Operator: VLu
Inst 67
Multiplr: l.00
MS Integration Params: RTE.P
Quant Time: May 18 8:32 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
8000000;
75000001
7000000
6500000;
6000000; ,
5500000!
5000000
I
!
4500000i
i
! !
400000011
'i
3500000
3000000
2500000:
2000000:
1500000;
1000000
500000;
::;:
>-'
oj
" <.: :;
'" '0
c
0
€
III
()
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
T1C:RtC3-g-~
(/)
ui .,;
z ~ UJ c N Q) Z :J
UJ "0 '" f-0
0:
0
:::>
...J
U-
0
..I:.
!!
on
0
W z
UJ
N
Z
UJ (/)
'" .,;
0 c
Q) 0: N
0 c
...J Q) .c I e () 0
:J
<;:
0
E e
'" .0-
.¢
0
W z
UJ
N
Z
UJ
'" 0
0:
0
...J ::c
()
0
N.
!\ 1\!1 i\
.' '\ i\i~\ J\ . \ .. ii, .. \ " ........ . O~ \~
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
----~------------
REC396.D V067D26.M Thu May 18 08:32:30 2023 Page 2
REPORT ID: 23E120 Page 44 of 560
Scan 145 (4.49Tminfl~rrC593:rrr-r---------------'1 #19
76
I !:., Carbon disulfide
RefO i
49
84
44
o i--r'Fn,-"'I-" , '1: 152~ 64 7,0 ~~,=,.9 -,-,h-'-' ,8c8~~~~
m/z--> 30 35 40 4'5" 50 5'5 60 6'5 70 75 80 '85 'g'O' 9'5
!
lAbundance---SCanl46-(4.52TmTnfHEC396.D
76 i
44
40 49 84
47 ! 67
0' , '~ , l,i~'Tn~, '
m/z--> 30--35'-404'5-5'0 '5'5 60' 85 ' 7'6' i5 'ab 85 90 95
Abundance--SCanl46l4.52TmlnfHEC3-90~DT-)
, I 76
I
Sub I
50]
O~,
:m/z--> 30 35 4'0
lAbunaance
RefO:
1
Ra'5{)j
47
47
44 49
I 47 :
, " I I
4'5 5'0 5'5
, i
: I , I
1 I , ,
I I
40 0L.-i' ,
m/z--> 30 40 50 60 708090 100
lAbundance-Scan 36'4(T.Tf3-rmnj:HEC3-96J)'T-)
~
120
110 120 130 -..:.=-~
118
120 130
Concen: 0.16 ug/l
RT: 4.53 min Scan# 146
Delta R.T. 0.03 min
Lab File: REC396.D
Acq: 17 May 2023 1:58 pm
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
41130
Upper
10.0 6.3 11. 7
bundance lOrl761RnT57UlO7670YREC39o.D'
lion 78.00 (77.70 to 78.70): REC396.D
8000;
6000!
I
40001
I
20001
#32
Chloroform
4.53
Concen: 1.41 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC396.D
Acq: 17 May 2023 1:58 pm
Tgt
Ion
83
85
47
Ion: 83 Resp:
Ratio Lower
100
66.0
26.3
39.4
0.0
152765
Upper
99.4
56.0
bundancelon 83.0-01S-Z70-fo-s370r REC39'6. 0
lion 85.00 (84.70 to 85.70): REC396.D
35000jlon 47.00 (46.70 to 47.70): REC396.D
I
30000!
25000:
I
20000:
15000
7.71
Sub
50
47
i \ 5000 1
: ! li 10000
~Z--? __ ~o:-'40' i':_~0,--~60 ~~io-' 80
111 __ '_90==_1.90_' _' _11Q~_1+~8~20-~130 irll.e--> __ O~-i-:50~;&~_~3.Qj.13~~I9Q~ 8,9.0.
REC396.D V067D26.M Thu May 18 08:32:31 2023 Page 3
REPORT ID: 23E120 Page 45 of 560
Abundance-'---~-----Scan 46U19.100 min): RDCo9J.IJT-)---
1
Re~
47 82 : I
: !
#41
Carbon tetrachloride
Concen: 18.39 ug/l
RT: 9.12 min Scan# 460
Delta R.T. 0.02 min
Lab File: REC396.D
Acq: 17 May 2023 1:58 pm
i 1123 I 1~1301, Tgt Ion:119 Resp: 1345392
Ratio Lower Upper
100
Ra~i
47 82
! I , 41 I I 58 70 I i ~ o-;------c---.------,--,----r~----,--,-~~i, I ! i 'I I
,m/z--> 30 40 50 60 70 80 90 100 110
~bundance--~---'~--Scan 4'00\9.115 min): REG39KDT-f--
Sub,
50
47 82
j i
i i
, , , ,
i i
! !
ii'
: i I
I I I
I 11~3
I~
120 130
1H
i ;
70 ~-+'~~~~~~-.,.llLL.J~~_3~_ '70 ab gb 100 110 120 130
, Ion
I 119
117 104.0 73.4 133.4
bundance 10rl1191ml'\l1f.70101T9:70r -RECJ96
lIon 117.00 (116.70 to 117.70): REC396
250000i
200000:
150000i i
1000001 II
i
500001
I / \
" . Or---;----;=;= --;~~~-T~~~:-='-~-
ime--> 8.80 9.00 9.20 9.40
REC396.D V067D26.M Thu May 18 08:32:31 2023 Page 4
REPORT ID: 23E120 Page 46 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client : BRICE Date Collected: 05/11/23 12: 40
Project : TEAD-S Date Received: 05/16123
Batch No. 23E120 Date Extracted: 05/17123 14:23
Sample ID ; S-136-16-052023 Date Analyzed: 05/17123 14:23
Lab Samp ID: 23E120-07 Dilution Factor: 1
Lab File 10: REC397 Matrix: WATER
Ext Btch ID: V067E17 % Moisture: NA
Calib. Ref.: RDC593 Instrument 10: 67
RESULTS LOQ DL LOD
PAAAMETER(S) (ug/l) (ug/l) (ug/L) (ug/l) -----_ .......... _-_ .......... -..... _--_ .. -.... -........ .............. -...... _ .......... ..............
1. 1. 1.2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorggropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride 29 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform 15 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprOvylbenZene ND 1.0 0.10 0.20
m,~-xh ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Met~l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-IsoproV&ltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PAAAMETER(S) RESULT SPK AMT %RECOVERY QCLIMIT
................................................. ................... ................... ................... .... -Oo ...... • ......
1.2-Dichloroethane-d4 10.4 10.0 104 70-130
4-Bromofluorobenzene 10.8 10.0 108 70-130
Toluene-d8 10.7 10.0 107 70-130
Dibromofluoromethane 10.8 10.0 108 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 47 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC397.D
Acq On 17 May 2023 2:23 pm
Sample 23E120-07
Misc 25mL
(QT Reviewed)
Vial: 19
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:32 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023 Last Update
Response via
DataAcq Meth
Initial Calibration , _____ ~
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.15 114 2148055 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1541581 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.50 152 420226 10.00 ug/l 0.02
~System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 553619 10.81 ug/l 0.02
Spiked Amount 10.000 Recovery 108.10%
43) l,2-Dichloroethane-d4 9.31 65 408325 10.45 ug/l~ 0.02
Spiked Amount 10.000 Recovery 104.50%
56) Toluene-d8 12.99 98 2293393 10.70 ug/l~ 0.02
Spiked Amount 10.000 Recovery 107./00%
77) 4-Bromofluorobenzene 17.62 95 611556 10.77 ug11 0.02
Spiked Amount 10.000 Recovery 1 7 .70%
, Target Compounds Qvalue
7) Chloroethane 2.72 64 22705 0.34 ug/l 84
19 ) Carbon disulfide 4.54 76 42469 0.17 ug/l 96
20) Methylene chloride 4.54 49 17689 0.18 ug/l 95
32) Chloroform 7.71 83 1648464 ....... 15.50 ug/l 97
41 ) Carbon tetrachloride 9.12 119 2100375 /9.25 ug/l 99
63) Tetrachloroethene 14.26 164 6480 0.12 ug/l 92
(#) = qualifier out of range (m) = manual integration
REC397.D V067D26.M Thu May 18 08:33:10 2023 Page 1
REPORT ID: 23E120 Page 48 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC397.D
Aeq On 17 May 2023 2:23 pm
Vial: 19
Operator: VLu
Sample 23E120-07 Inst 67
Mise 2SmL Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:32 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance ------~
8500000;
i
80000001
7500000'
7000000:
6500000;
60000001
I
5500000
5000000
4500000
4000000J
35000001
3000000
2500000
2000000:
,
1500000; .
1000000
500000
::,;
,..: .;
c:
'" :;
" e
0
1:
U
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration --- ----------~---~~----~-------IIC:-REC3-9t])------~---------
::,;
,..: en
r.5 oj
§ c
'" :; .E " ::,; e E
Ii 0 e 1: 0 ~ U :J
~ '" 0
E
c e
.Ill .c
"C 0 .e!
f
" ii
::,; ,..:
.;
"C ." 0
1:
0 ~
c:
0 ~ u:g .,
c:
'" ~ \e ;.2
• .<:;
,0
'i'~
'''{
,~
i:
Iii z w
N
Z
W
'" 0 ex:
0
::J
...J
"-is
*
.,; o
oJ z
W
N
Z
W
'" o ex: o
...J
I
U
en .; c
" ~
" .c
§
:J
15
E e
'" "
c5
oJ z
W
N
Z
W
'" o ex: o
...J
I
U
is
"'-
o :.--2c~,cc -=~~,..,-,-..,..,-~-;-;--~-ri--'-,-Lc'o-r-ri--f.,...,--r-,'-,-,.-,-,.~----,-,~-,--'--'-'r-~~-;-;--~~.,..----r
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.0010.0011 ~OO 12~00 13.00 14:0015.0016.00 17.0018.0019.00 20.00 21.00
REC397.D V067D26.M Thu May 18 08:33:12 2023 Page 2
REPORT ID: 23E120 Page 49 of 560
RefO
94
49 i:
, I 11 6,9
#7
Chloroethane
Concen: 0.34 ug/l
RT: 2.72 min Scan# 52
Delta R.T. 0.02 min
Lab File: REC397.D
Acq: 17 May 2023 2:23 pm
• 44 . i 591 i U 81 87 102
m/z--> 0 ~~40" 45~OT55 60 '6:5 7'07'5' ~o 8'5 9'0 95 100 165 110
Abundanre-~-~~----~---~SCar15212720-mTnT1~~C3WJ)----~-~ .--~,
Tgt
Ion
64
49
Ion: 64 Resp:
Ratio Lower
100
22705
Upper
44
64
49 78 94
18.7 0.0 57.1
fburidimceIOn-64.0-0163.70f064.70): REC397.D
! 500010n 49.00 (48.70 to 49.70). REC397.D
2.72
m/z--> 0~35 40 4'5 50 515 60 ~i~ 70 7'5 80 85 90 915 160 105 110
4000:
Abundance Scan 52 (2.720 mtn): RECJ97TI\T--
Sub
50
49
64 !
i ;
3000:
2000·
1000·
,rn_/z_--_> __ ~_ 35' 40 4'5" 5'0 515 6b Il!~' 7'0 715 '8'0' 815 SO ~~5 1~6 ... 0_'1 ... 0 .... 5--"1_"'10 ____ ' --1' .... im"'e __ ---'>---"Oi2 .50 2.~~;;;~2-.80-;.9-~:
Abundance
RefO
40
Scan 145 (4.497 mtn~TIC09'TIJ (-)
7f'
49
44 49
OJ-! __
m/z--> 3'0 35 40 45 50 55 60 '65 io 75 80
Scan 147 (4.542 mtn): REC397.D (-)
76
Abundance
Sub
50 49
84
84
,
#19
Carbon disulfide
Concen: 0.17 ug/l
RT: 4.54 min Scan# 147
Delta R.T. 0.04 min
Lab File: REC397.D
Acq: 17 May 2023 2:23 pm
Tgt
Ion
76
78
Ion: 76
Ratio
100
10.3
Resp:
Lower
6.3
42469
Upper
11. 7
Abundance, Ion 76~OOlT5:70To76:TOYREC39TD
I ilon 78.00 (77.70 to 78.70): REC397.D
8~ 00 4 8000 4.54
I
4000
84
I
2000i
0-
m/z--> 30
44
35 40 45 5ci-5-5-"0~---65 iO -~ 75 80-'5---90 __ 95 _ ~;m'c:>_ 0 _4"'0_ 4.50 4.60 4.70 4.80
REC397.D V067D26.M Thu May 18 08:33:12 2023 Page 3
REPORT ID: 23E120 Page 50 of 560
:t\bunaance -
i
Re~
Ra~; ,
O~.",
)"/z--> 30 35
Abundance
Sub;
50
40
i' ,
40
S-caill40{4-:-5'r2 min): RO~o~r3:0T-J_u~-,---~! #20 7p ,
Methylene chloride I
49
44 49
, ,
II" I l'i'i'I;~
45 50 55 60 65 70 75 80
Scan 147 (4.542 min): REC31T7:DT-}
7p
49
84
84
i ~'5 '9'0 . 9'5
84
Concen: 0.18 ug/l
RT: 4.54 min Scan# 147
Delta R.T. 0.03 min
Lab File: REC397.D
Acq: 17 May 2023 2:23 pm
Tgt
Ion
49
84
86
Ion: 49 Resp:
Ratio Lower
100
66.5 41.7
43.7 15.7
17689
Upper
101.7
75.7
, bundance 10rf49-:-m)l48'.70T04'9-:TOYREC397. O!
5000110n 84.00 (83.70 to 84.70): REC397.D
lion 86.00 (85.70 to 86.70): REC397.0
40001
i
30001
2000i
1000,
4.54
o 40 i , i, ! i, i Ot=,=:.=.~_~~ -----------__ u
,m/z--> 3'O-354b~5 5'0' 5'5 60 65 ~10758b 8'5 90 95 ime--> 4.40 4.50 4.60 4.70
Abundance
I
42
47
55
74 120
#32
Chloroform
Concen: 15.50 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC397.D
Acq: 17 May 2023 2:23 pm
OL-
m/z--> 3'0 40 50 60 7'0 80 90 100 110 120 130 Tgt Ion: 83 Resp: 1648464
Abundance
Ra~
47
-~--Scan 364 (7. 713 min): REC39~7;.;.D:...--"-.:.-"-------"'-=-------'= Ion Ratio Lower Upper
~
i
! i
: i
83 100
85 65.8 39.4 99.4
47 26.0 0.0 56.0
i
r-bi.inaancelon 83.00-(8270 t() 8370}: REC397.0
400000,Ion 85.00 (84.70 to 85.70): REC397.0
lion 47.00 (46.70 to 47.70): REC397.D
0 '--,' _, 41 70 i 118
m/z--> 30 40 50 60 ' '70 8V
I
9'0 100 ~1-10~~120--130
350000i
300000: 7.71
A6Lindance -------scarl"3-64lT.713rT1ii1}:REC3'9T.DT-f
Sub
50i
47
83
,
250000;
200000
150000 '
100000 i
50000:
O!-'
m/z--> 30
41
40
~__-~____'_"" ,~_~~.c-~ . 70 _~~1~18 k 0;_------'--,
50 __ ---"6-,.-0 __ -----'--'70=-----=8~0 _9 ... 0 ____ ----"'10-,.-0 110 120,_ 130 ime--> 7 .4Q.._L~ __ J.80~~8.00-8.20
REC397.D V067D26.M Thu May 18 08:33:12 2023 Page 4
REPORT ID: 23E120 Page 51 of 560
Abundance
Re~J
47 82
42 59 70 O~-----r---,-.~~~~-~~~~,~-:--~.~, ~,~,~T ;! i ~----r----'----'----'
m/z--> 40 50 60 70 80 90 100
, i 123
I
' I; ,
110 120 130
Abundance----------Scan 461>\9-:116 min): RECJ9T.D
117
! '
i i
1
47
i 1
82 !
Ii, ,I,
I 41 58 65 72 I I ' I ~ 23 i 0 ,--I ~-'-;--'-,-+'~~'-'c' ,-'-;::~O-, ;-r-,--,--r', : :', I' I ' I ' I
;m/z--> 4'0 50 60 70 80 90 100 110 120 130
Abundance Scan 460 (9.116 min): REC3gT.IrF)c-'-'-=---~~-
i
i
Sub:
50 J
! ;m/z-->
Abundance
Re~:
Ra!;b
01
m/z--> 30
f.bundance
Sub
50
47
47
44
59
82
58 70 Ii
6'0 7'0
I I Ii I ' , I
80 90 100 110
Scan 812 (14.243 minTRDCo93-:Dl-)
129
129
94
82
iii' ·~~,~,~,~~h,~I~,~,~,~, ~~t!~,~~~~~'h:
40 50 60 70 80 90 100 110 120 130 140 150 160 170
'-----SCan812 (14.259 m/nf"REC397.D (-)
1Q6
129
94
47
59 82
#41
Carbon tetrachloride
Concen: 29.25 ug/l
RT: 9.12 min Scan# 460
Delta R.T. 0.02 min
Lab File: REC397.D
Acq: 17 May 2023 2:23 pm
Tgt Ion:119 Resp: 2100375
Ion Ratio Lower Upper
119 100
117 102.7 73.4 133.4
bundanceion1T9-:()011lS.7()-to n970r REC397
lion 117.00 (116.70 to 117.70): REC397
400000i
I
I
300000!
#63
Tetrachloroethene
Concen: 0.12 ug/l
RT: 14.26 min Scan# 812
Delta R.T. 0.02 min
Lab File: REC397.D
Acq: 17 May 2023 2:23 pm
Tgt Ion:164 Resp: 6480
i Ion Ratio Lower Upper
164 100
166 143.4 97.7 157.7
129 82.2 56.9 116.9
131 79.0 52.5 112.5
, bundancelon 164.()0116'37UlO164.7U):REC397
5000jlon 166.00 (165.70 to 166.70): REC397
lion 129.00 (128.70 to 129.70): REC397
ilon 131.00 (130.70 to 131.70): REC397
4000,
3000i
:14.26
2000
1000
0, ~~T-~-' O~=-=, \
rnj~==,:-,_}()_,±O 50 60 70 8'0 90 100 110 120 130 140 150 160 170 ___ trl!ne--,,-_1~~15_ 14.20 14.25 14.30 14.35
REC397.D V067D26.M Thu May 18 08:33:13 2023 Page 5
REPORT ID: 23E120 Page 52 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05112/23 11: 45
Project TEAD·S Date Received: 05/16/23
Batch No. 23El20 Date Extracted: 05/17/23 14:49 $ 05/18/23 17:24
Sample ID S·139·17·05·2023D Date Analyzed: 05/17/23 14:49 05/18/23 17:24
Lab Samp ID El20·08 120.081 Dilution Factor: 1 # 500
Lab File ID REC398 C433 Matrix: WATER
Ext Btch ID V067E17 067E18 .t Moisture: NA
Calib. Ref. RDC593 C593 Instrument 10: 67 # 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/L) (ug/L) ._--_ ..... _--_ ....... -..... -_ ......... . ..... _--_ .... ....... -.... ----.............. _--._---_ ...... -
1. 1. 1.2·Tetrachloroethane NO 1.0 0.10 0.20
1. 1. l·Trichloroethane NO 1.0 0.10 0.20
1.1.2.2·Tetrachloroethane NO 1.0 0.10 0.20
1.1.2·Trichloroethane NO 1.0 0.10 0.20
1.1-Dichloroethane NO 1.0 0.10 0.20
1.1-Dichloroethene 0.38J 1.0 0.10 0.20
1.1·Dichloropropene NO 1.0 0.10 0.20
1. 2. 3-Trichlorggropane NO 2.0 0.25 0.50
1.2.4·Trichloro enzene NO 1.0 0.15 0.30
1.2-Dibromo-3·chloropropane NO 2.0 0.25 0.50
1.2-Dichlorobenzene NO 1.0 0.10 0.20
1.2-Dichloroethane NO 1.0 0.10 0.20
1.2-Dichlorogropane NO 1.0 0.10 0.20
1.3-Dichloro enzene NO 1.0 0.10 0.20
1.3.Dichlorogropane NO 1.0 0.10 0.20
1.4·Dichloro enzene NO 1.0 0.10 0.20
2.2'Dichloro~ro~ane NO 1.0 0.25 0.50
2·Butanone ( EK NO 20 5.0 10
2·Chlorotoluene NO 1.0 0.25 0.50
2· Hexanone NO 20 5.0 10
4·Chlorotoluene NO 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene 0.33J 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane NO 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide 1.8 1.0 0.25 0.50
# Carbon Tetrachloride 28000 500 50 100
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
# Chloroform 690 500 50 100
Chloromethane NO 1.0 0.25 0.50
cis·1.2·Dichloroethene NO 1.0 0.10 0.20
CiS-1.3'Dichloro~ropene NO 1.0 0.10 0.20
Dibromochloromet ane NO 1.0 0.10 0.20
Dibromomethane NO 1.0 0.10 0.20
Dichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISOprO~Ylbenzene NO 1.0 0.10 0.20
m.~.x?; ene NO 2.0 0.21 0.50
4· et yl·2·Pentanone NO 10 2.5 5.0
Methylene Chloride 4.2 2.0 0.50 1.0
Methyl tert·butyl ether (MTBE) NO 1.0 0.15 0.30
n·Butylbenzene NO 1.0 0.25 0.50
n·Propylbenzene NO 1.0 0.25 0.50
o·Xylene NO 1.0 0.10 0.20
~'Isopro~bltoluene NO 1.0 0.25 0.50
ec·Buty enzene NO 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert-Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene 24 1.0 0.15 0.30
Toluene NO 1.0 0.10 0.20
Trans-1.2·Dichloroethene O.l1J 1.0 0.10 0.20
Trans·1.3-Dichloropropene NO 1.0 0.25 0.50
Trichloroethene 4.6 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2·Dibromoethane NO 1.0 0.10 0.20
1.2.3·Trichlorobenzene NO 1.0 0.15 0.30
1.4·Dioxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT .tRECOVERY QC LIMIT .-_ .... ----_ .... __ ....... _--_ .... __ ..... .... -......... _ .. .. ..... -........ _-............ -.... -----_ ...... _-
1.2-Dichloroethane·d4 8.48 10.0 85 70-130
4-Bromofluorobenzene 10.3 10.0 103 70·130
Toluene·dB 10.4 10.0 104 70·130
Dibromofluoromethane 12.4 10.0 124 70·130 i 1.2·Dichloroethane·d4 5240 5000 105 70·130
4· Bromofl uorobenzene 5460 5000 109 70-130
Toluene·d8 5420 5000 108 70·130
Dibromofluoromethane 5350 5000 107 70·130
# Result(s) associated as marked on the header
Notes: Sample Amount 25ml Final Volume: 25ml
Prepared by VLu Analyzed by : VLu $ Sample Amount 0.050ml Final Volume: 25ml
Prepared b, VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 53 of 560
METHOD SWS030B/B260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/12/23 11:45
Project TEAD·S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/17123 14: 49
Sa!DPle 10 ; S·139·17·05·2023D Date Analyzed: 05/17/23 14:49
Lab Samp 10: 23E120·08 Dilution Factor: 1
Lab File 10: REC398 Matrix: WATER
Ext Btch 10: V067E17 % Moisture: NA
Calib. Ref.: RDC593 Instrument 10: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/l) (ug/L)
---------------_ .......... _ ...... ........ _-----_ .. --.. _ ..... ---_ ......... ....... __ ........
1. 1. 1. 2·Tetrachloroethane NO 1.0 0.10 0.20
1.1.1·Trichloroethane NO 1.0 0.10 0.20
1.1.2.2·Tetrachloroethane NO 1.0 0.10 0.20
1.1.2·Trichloroethane NO 1.0 0.10 0.20
1.1·Dichloroethane NO 1.0 0.10 0.20
1.1·Dichloroethene 0.38J 1.0 0.10 0.20
1.1·Dichloropropene NO 1.0 0.10 0.20
1. 2. 3.Trichlorogropane NO 2.0 0.25 0.50
1.2.4·Trichloro enzene NO 1.0 0.15 0.30
1.2·Dibromo·3·chloropropane NO 2.0 0.25 0.50
1.2·Dichlorobenzene NO 1.0 0.10 0.20
1.2·Dichloroethane NO 1.0 0.10 0.20
1.2.Dichlorogropane NO 1.0 0.10 0.20
1.3·Dichloro enzene NO 1.0 0.10 0.20
1.3.Dichlorogropane NO 1.0 0.10 0.20
1.4·Dichloro enzene NO 1.0 0.10 0.20
2.2.Dichlorogro~ane NO 1.0 0.25 0.50
2·Butanone ( EK NO 20 5.0 10
2·Chlorotoluene NO 1.0 0.25 0.50
2· Hexanone NO 20 5.0 10
4·Chlorotoluene NO 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene 0.33J 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane NO 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide 1.8 1.0 0.25 0.50
Carbon Tetrachloride 2200E 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform 540E 1.0 0.10 0.20
Chloromethane NO 1.0 0.25 0.50
cis·1.2·Dichloroethene NO 1.0 0.10 0.20
Cis.1.3.Dichloro~ropene NO 1.0 0.10 0.20
Dibromochloromet ane NO 1.0 0.10 0.20
Dibromomethane NO 1.0 0.10 0.20
Dichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISOpro~Ylbenzene NO 1.0 0.10 0.20
m.g-XF; ene NO 2.0 0.21 0.50
4· et yl·2·Pentanone NO 10 2.5 5.0
Methylene Chloride 4.2 2.0 0.50 1.0
Methyl tert·butyl ether (MTBE) NO 1.0 0.15 0.30
n·Butylbenzene NO 1.0 0.25 0.50
n·Propylbenzene NO 1.0 0.25 0.50
o·Xylene NO 1.0 0.10 0.20
~.Isopro~~ltoluene NO 1.0 0.25 0.50
ec·Buty enzene NO 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert·Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene 24 1.0 0.15 0.30
Toluene NO 1.0 0.10 0.20
Trans·1.2·Dichloroethene O.l1J 1.0 0.10 0.20
Trans· 1. 3·Dichloropropene NO 1.0 0.25 0.50
Trichloroethene 4.6 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2·Dibromoethane NO 1.0 0.10 0.20
1. 2. 3·Trichlorobenzene NO 1.0 0.15 0.30
1.4·Dioxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
•• __ a .. _____ ......... •• ... • .... ••• .. • .... .. ...... __ ..... -_ .. _--_.-. ---_ .......... .............
1.2·Dichloroethane·d4 8.48 10.0 85 70·130
4·Bromofluorobenzene 10.3 10.0 103 70·130
Toluene·d8 10.4 10.0 104 70·130
Dibromofluoromethane 12.4 10.0 124 70·130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b1' : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 54 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC398.D
Acq On 17 May 2023 2:49 pm
Sample 23E120-08
Misc 25mL
(QT Reviewed)
Vial: 20
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:37 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration ~
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.18 114 1991449 10.00 ug/l 0.04
55) CHLOROBENZENE-D5 15.62 117 1582960 10.00 ug/l 0.01
74) l,2-DICHLOROBENZENE-D4 19.50 152 468657 10.00 ug/l 0.01
System Monitoring Compounds
36) Dibromofluoromethane 8.22 111 587112 12.37 ug/l 0.03
Spiked Amount 10.000 Recovery 123.70%
43) l,2-Dichloroethane-d4 9.38 65 307319 8.48 ug/l ~ 0.09
Spiked Amount 10.000 Recovery 84.80%
56) Toluene-d8 12.99 98 2286250 10.39 ug/l/ 0.02
Spiked Amount 10.000 Recovery 103.9~%
77) 4-Bromofluorobenzene 17.62 95 654176 10.33 ug/l/ 0.01
Spiked Amount 10.000 Recovery 103.30%
/
:-Target Compounds Qvalue
14) l,l-Dichloroethene 3.82 61 42034 0.38 ug/l 98
.-r'
19) Carbon disulfide 4.56 76 399743 ,.-1.75 ug/l 98
20) Methylene chloride 4.56 49 388958 c-4.20 ug/l 98
23) trans-1,2-Dichloroethene 5.07 96 8339 --0.11 ug/l 100
32) Chloroform 7.71 83 53235672 539.87 ug/l E 85
37) Cyclohexane 8.65 84 109210 ,,-0.98 ug/l 96
41 ) Carbon tetrachloride 9.36 119 144487382m 2170.21 ug/l£
44) Benzene 9.54 78 88534 /' 0.33 ug/l 98
46 ) Trichloroethene 10.75 130 300080 :-?57 ug/l 97
47 ) Methylcyclohexane 10.85 83 63145 . 0.51 ug/l 90
63) Tetrachloroethene 14.26 164 1330323 ~~3 .82 ug/l 98
(#) = qualifier out of range (m) = manual integration
REC398.D V067D26.M Thu May 18 08:37:35 2023 Page 1
REPORT ID: 23E120 Page 55 of 560
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI7\REC398.D Vial: 20
Aeq On 17 May 2023 2:49 pm
Sample 23E120-08
Mise 25mL
Operator:
Inst
Multiplr:
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: May 18 8:37 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Ab~~e~rcw --
3.6e+07-
3.4e+071
3.2e+07:
3e+07j
2.Be+07'
2.6e+07 1
2.4e+07t
!
.
2.2e+07:
2e+07:
1.Be+07
I 1.6e+07J
I
: 1.4e+07!
1.2e+07!
1e+07
BOOOOOO
::;; ...: 60000001
c.5 .,; c
Q) :;
Q) e 4000000'
~
0
2000000 9
::;;
Ii
t8:
~
" .1Il
"C .e
i
::;;
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Trc:R~98TI
'!
W z w
::;;
>-:
Q) '" c
'" 0 rn .,;
>-: N rn z ~ W z C e w Q)
'" .,; w i c c CD
'" '" ::. 0 ~ :;
'" i-: 0:: I e E ::;; 0
0 e ...: l~ ::::l
...J £ 0 .,; !~ u.
" is is "" c .C I 0 '" Q) .,;.. N. ! E x ~ '" e "" .;, .0 0
c is "0 f-ijj '" g: u ::;;
0 N
rn :c N c
.,; 0 z '" W .0
~ g: CD e
Q) 0 0 c I-" '" 0:: "" " 0 0
0 ...J E
l-I e u CD ..;.
O.·~~··-· ------~~-·c~· '~' '.
-.i
0 w z w
N z
W
CD
0
0::
0
...J
I u
is
N.
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 B.OO 9.00 10:00 11.00 12:00 13.00 14.00 15.00 16.00 17.00 1B.00 19.0020.0021.00
------------------------------------_. --------
REC398.D V067D26.M Thu May 18 08:37:36 2023 Page 2
REPORT ID: 23E120 Page 56 of 560
Abundance
RefOi
45 Ii OL~~. _,':~LY-r 'I iii, I I 70 :,5~ , i I
m/z--> 30 35 40 45 50 55 60 65 70 75 80 85 90
Abundance Scan 105 (3.B19 min): REC3'98:D
44 ~1
Ra~t)'
I
40
i I 8
#14
l,l-Dichloroethene
Concen: 0.38 ug/l
96 RT: 3.82 min Scan# 105
Delta R.T. 0.06 min
Lab File: REC398.D
! Acq: 17 May 2023 2 :49 pm
1 1100
"I' I,
95 100 105 !
I
96
Tgt Ion: 61 Resp: 42034
Ion Ratio Lower Upper
61 100
96 61.4 33.2 93.2
63 32.6 3.7 63.7
bundanceI0i101.OU100-:7UlOOT.70}:-REC398~Di
8000ilon 96.00 (95.70 to 96.70): REC398.0
ilon 63.00 (62.70 to 63.70): REC398.0
7000'
I i; 7 O~:--T11-'--~---:--'---+-t-I' , i ' ': I , r' I I 'I,~---r'~rt-,--~~
mlz--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 6000:
5000;
3.82
Abu-naance------~-Scan 105 (3.8T9I'nrn}:REC:mB:n-(=,
Sub'
50: I 96
I
,
4000 1
3000]
2000i
i ; I 10001
47 I
I i I
I
40 1/
if'
, , 82,' ,
'i II' ' 01::;' :;=/;::;::;:::;::;=;::;:::;::;:::;
rn1z--> °n/~t!'4'5 .",,-5'0=--5.::..:' '5=------6c....:b,---' ~' 6c...:'5~'~7--=b-----,-7-=c15~' '~8i-=-0~1 -=8~15=--9.::..:b,---' ~' 9=-c!5,---' --,-1'.::..:00,-' --'-10c....:'5=------J'--Cimc:..:e.::.--~->_~t;~~__=3:.:...:.6=_=_0 3.70 3.80~3~.9_0 _,!:OQ 4.,!Q
Scan 140(4,497 min): ROC59TO (-)
7F
I
RefO· I
49
84
, i 44
i i 88
Im/z __ > ~jo~'~' ~35-'~40' ~5' I ~'o52 55 60 6~5 ~~, 75 I ~:'o ~15 90
Abundance Scan 148 (4.556 mll'fREC39KD~"
Ra~:
44
41 o '-"T'-"-~'-----~T '
m/z--> 30 35 40 45
Abundance
Sub'
50
49
76 ,
6467 ::,' i I" I
50 55 60 65 70 75 80
Scan 148T4.556 min): REC39B.D (-)
4:9
76
84
88
8'S g'O 95
84
#19
Carbon disulfide
Concen: 1.75 ug/l
RT: 4.56 min Scan# 148
Delta R.T. 0.06 min
Lab File: REC398.D
Acq: 17 May 2023 2:49 pm
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
9.7 6.3
399743
Upper
11. 7
bundanceJo616-:-0017570107K70i:REC39B.0-
50000ilon 78.00 (77.70 to 78.70): REC398.0
4.56
40000:
300001
I
I 20000
10000.
4144 :88 I ~O-~3-5-40+~5-j~Q_5~i5~' ',',6'0 ,6:56~i~ !~ ~~ 80 ___ hQ5+~.4_.~~-0~9~5~ ~ime--> 0~--~-4~60-m/z--> 4.80
REC398.D V067D26.M Thu May 18 08:37:36 2023 Page 3
REPORT ID: 23E120 Page 57 of 560
49
#20
Methylene chloride
Concen: 4.20 ug/l
RT: 4.56 min Scan# 148
Delta R.T. 0.04 min
Lab File: REC398.D
Acq: 17 May 2023 2:49 pm
Tgt Ion: 49 Resp: 388958
76
I
84
Ion Ratio Lower Upper
49 100
84 73.0 41.7 101.7
86 46.6 15.7 75.7
bundancelon-2rg~{ro-r48:71JlO49~70r-REC39KO
lion 84.00 (83.70 to 84.70): REC398.D
80000i'on 86.00 (85.70 to 86.70): REC398.D
« I~
o ~:~, ~-T~' ~t-+4,1-+-H,--,-1i-+i ~i f+' i ~-,--~-,-c-r-,-r-<6~4T'6~7-;-TT~,,+i +h-rc-,+I !-tl i+i t-T, -"-'1 ,~,' ~ ~~ ~ ~ ~"~' ~"~' ~ ~ ~ ~ ~ ~ 00 ~
!
4.56
Abundance -SCaI1148 (4.556 mtn): REC39~
! 4~
Sub
50,
76
84
I
;
i
40000 i
I
I
20000:
41 44 ~iO--3s-~4'O' 45 : i 5,J 6467 , 188 i /-
55 60' 65 'io , i , I Ol~ __ T_~-=~="~'::::'-: __
715 8'0 85 909'5 ' ime--> 4.20 4.40 4.60 4.80 5.00 m/z--> .-'--'------'--------------------
Abundance
RefO;
Scan 181 (5.023 mtn): R0C593-:-0----r-r----
61
I
I
,
i i ! '
96
i ! !100 47 iii 67 O~----· ~,,', I' I" I I I Iii',.,
m/z--> 30 35 4'0 45 50 55 60 65 70 75 80 85 90 95 100 105
Abuilili:lnce Scan 183 (5.067 mtn): REC3""'98".""'D-----
44
61
I
96
40
76
o '. ' m/z--> 3b3540 4550 5!5 6'oh---c6"5~7'-0---'75-r1 ~8'-0~8~5~9Tb-"'T95+' '-'-1-'-OO~105
'I #23
trans-1,2-Dichloroethene
Concen: 0.11 ug/l
RT: 5.07 min Scan# 183
Delta R.T. 0.04 min
Lab File: REC398.D
Acq: 17 May 2023 2:49 pm
Tgt
Ion
96
98
Ion: 96
Ratio
100
63.1
Resp:
Lower
32.9
8339
Upper
92.9
bundancelon 96-:-00-\9'5:7{no-9-6~70rREC39KO
lion 98.00 (97.70 to 98.70): REC398.D
5.07
2000;
Abundance ---~~-Scan 1~(o.06TITifi1J:REC-J9KO\T u_________ 1500:
61
Sub' 50,
96
, "
1000;
5001
I
I
• 40 ,. ' i
f11/Z-->_~Q-j5_40-45-:5'0-' 5'5 6o"6570-75~8o~85'90-9S--10~]Q~ ~irn~~ 0~·.:i~~'5.0Q~~~05~~~1(L5j~_ 5.20
REC398.D V067D26.M Thu May 18 08:37:37 2023 Page 4
REPORT ID: 23E120 Page 58 of 560
RefO;
47
Ra'5bi
;i!
oL 41 ilil.
mlz--> 30 40 50
Abundance-
Sub:
50; 47
Scan 363 (7.683 min): RDC593'TIT-)
8
1
3
I
, i
: i
i i
! :
iii 58 65 70 77 Iii' 1 94
I i'· ! i I I' " I'
60 70 80 90 100 110
Scan 364 (T.712ITilnfREC3g8]r~
~,
i;
II
l I
II
118 124 \'~ '~
120 130
#32
Chloroform
Coneen: 539.87 ug/l
RT: 7.71 min Sean# 364
Delta R.T. 0.03 min
Lab File: REC398.D
Aeq: 17 May 2023 2:49 pm
Tgt Ion: 83 Resp:53235672
Ion Ratio Lower Upper
83 100
85 81.3 39.4 99.4
47 34.5 0.0 56.0
bundance lon-8T.OO-(8-Z-:7OTo83. 70r-REC398~D
lion 85.00 (84.70 to 85.70): REC398.D
8000000110n 47.00 (46.70 to 47.70): REC398.D
I 7.71
60000001 ' '
II 'II
i I' };
40000001
2000000i
1, i' oj 41 58 65 70 77 1111,1 94 118 124 I o~ j/ .~
I m/z--> ~b '4'0 ~~50~~6'b~' c-r-c7--rb-r-r~8r1b-"+,+L,-9Tb~' ~. ~1"6~0~~11"-0~,r-r+1'+~""-0-'--'--"-130 tnme--> 7.40 7.60 7.80 8.00 8.20
~bundance ,
,
RefOi
41
SCan 423 (8.559 min): RDC593.D (-)
56
i 84
97
69
i63 O~-_-c>..Ulr 51,,1:, I:' ,I 77"
m/z--> 30 40 50 60 7'08'0 90 100
117
1 .123
~-----,------r-
110 120 130.
Abundance Scan 428 (8.647 min): REC39~8~.D~----, 5P
84
41 I
69
51 ' 77 r
'm/z--> 0~-4'o i 5060 70 8/' ~90~'~' -1~0~0' 110 120
Abundan~--'" -----Scan428 (8.647 min): REC39KO----r-r------------4
. 56
Sub
50
41
84
69
#37
Cyelohexane
Coneen: 0.98 ug/l
RT: 8.65 min Scan# 428
Delta R.T. 0.09 min
Lab File: REC398.D
Acq: 17 May 2023 2:49 pm
Tgt Ion: 84 Resp: 109210
Ion Ratio Lower Upper
84 100
69 34.7 6.8 66.8
bundancelon-84.00\8-:f.70"1OE47U):REC39KD
lion 69.00 (68.70 to 69.70): REC398.D
10000' 8.65
8000i
60001
4000'
2000i
m_l_z-~ ___ ~~()_~ __ 4~ _=~1~-6-0~'~+7-'-~0~77-8~D _ ~ _'~O _-'-10 --120 ',0 lm,--,-~.30 i40 ~.50 -".60-8.7~-•.• 0 .:90
REC398.D V067D26.M Thu May 18 08:37:37 2023 Page 5
REPORT ID: 23E120 Page 59 of 560
~bundance
RefOi
#41
Carbon tetrachloride
Coneen: 2170.21 ug/l m
RT: 9.36 min Sean# 477
Delta R.T. 0.26 min
Lab File: REC398.D
47 82 Aeq: 17 May 2023 2:49 pm
59, !!
,m/z--> 0'~-4o'-~-E?o-~-'80~r100120140 '160180200220240 'T Tgt Ion:119 Resp:144487382
Abu-ndance -'----~~--Scan 477 (9.363 min): RECJ9'8~ ------i Ion Ratio Lower Upper
Ra~j
I
o·
47
m/z--> 40 60 80
Aouridance
82
47
AtJunaance
I
RefOj
52
39
1119 119 100
II
:1 117 91.7 73.4 133.4
100 120 140 160 180 200 220 240
-S-can-477\9.3-o3-minJ:t~EC3-9a:O~(=f--~--
11[7
5000000·
\ 4000000: i
3000000:' ~
2000000j
1000000j ) : __
~ime--> O~~~~~bO-' -9.;-0 -9.'~_0--_~ 9_.6_0_, '
#44
Benzene
Coneen: 0.33 ug/l
RT: 9.54 min Sean# 489
Delta R.T. 0.07 min
Lab File: REC398.D
Aeq: 17 May 2023 2:49 pm
i Tgt Ion: 78 Resp: 88534 200 220 ~2IO I
o~
m/z--> 40
~bundance
Ra~j
! Ii
,47 8~ 1:1
0'----c_.,J~~<?..JJJ~9_;_4~~L:ii.L., 134
'1
203 219 233
m/z--> 40 60 80 100 120 140 160 180 200 220
Aburidance-----------Scan 489\9338 min): R1EC-39'8~-----
240
Sub
50
51
39'1
78
120
OL~JLI _6~2_"""'I_:_____O-T~~_+__~_r13-i-'-6~~_,__r_T"
m/z--> 40 60 80 100 120 140 -------,-'--------.. ~---'-=--160
203 219 235
---'--1~
180 200 220 240
Ion Ratio Lower Upper
78 100
77 24.5 0.0 53.5
52 17.1 0.0 47.6
bundancelon nf.UO~(7770~t678~70rREC398.D
30000jlon 77.00 (76.70 to 77.70): REC398.D
!Ion 52.00 (51.70 to 52.70): REC398.D
I
250001
i 9.54
20000:
15000:
10000
5000:
, /
o~ ~-:/ "~~-~-----~~-
ime--> 9.40 9.50 9.60 9.70
REC398.D V067D26.M Thu May 18 08:37:37 2023 Page 6
REPORT ID: 23E120 Page 60 of 560
RefO: 60
,
i' i;
Ra~l 60
47 117
130
II
#46
Trichloroethene
Concen: 4.57 ug/l
RT: 10.75 min Scan# 572
Delta R.T. 0.03 min
Lab File: REC398.D
Acq: 17 May 2023 2:49 pm
Tgt Ion:130 Resp: 300080
Ion Ratio Lower Upper
130 100
132 94.8 65.3 125.3
95 98.0 71.1 131.1
I 97 63.6 40.3 100.3
r bundancelOn-1JO~()P2970l0l3070fREC398
lion 132.00 (131.70 to 132.70): REC398
120000',lon 95.00 (94.70 to 95.70): REC398.D
. lion 97.00 (96.70 to 97.70): REC398.D
m/z--> ~o 4:
1
50 u6b~_6\6°~-8:_2-_'90'~ 100--110-,cd6~'1io~40-' 100000
~bLlrid~mce ------'-Scan572T11J.751lTlIn): REC3'9KDT-}--
80000:
Sub!
50:
m/z-->
Ra~:
Sub
50
47
50
41
41
41
60
66 72
60 70
69
55
70
69
95
I ,
82 II!:,:
80 9'0 ' 100 110
98
I 98
'I Ii
" " ,ij'
98
130 ~i
130 140 '
#47
Methylcyclohexane
Concen: 0.51 ug/l
RT: 10.85 min Scan# 579
Delta R.T. 0.04 min
Lab File: REC398.D
Acq: 17 May 2023 2:49 pm
Tgt Ion: 83 Resp: 63145
Ion Ratio Lower Upper
83 100
55 80.0 57.8 117.8
98 44.0 22.9 82.9
bundance on -3:"OO'\'827()tolf370f'REC39a,D
14000jlon 55.00 (54.70 to 55.70): REC398,D
lion 98.00 (97.70 to 98.70): REC398.D
12000:
10.85
10000:
8000]
6000
4000:
2000:
m/z-->
,i 130 , ~~, .
030 -n;_t=~o_ ~u60 _ ;io'-Tu'90 ':100~!~6, __ 1~0 '1,4Qnn~ime~_~_0_t=~iQ.§~-c~~~~Q~~Q~-11.00
REC398.D V067D26.M Thu May 18 08:37:38 2023 Page 7
REPORT ID: 23E120 Page 61 of 560
Abundance -------Scan-8T2T14.243 min): RDG59TD,-)
166
129 I'
RefO i 94 i! i:
!! I' I
41,7 59 82 II I : : i II
, oLr'~~ '!, ,7,0 I i I I /1 i I 1,117" ili,i , " ,k I "
,m/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
Abundance --~------S-can 81T(14.258-mIn):REG3-g8~D
166
129
I
I'
94 ! I
:! i 47
I
59 82 Ii': I
, , , 70 ' , 119! ! , : I I
,m/z--> ~O~40---:?c> 60 70 8'~' 90: ~~60 110 1201~~~1401$0 H~O I~+O
Abundance ----Scan 812l14-:258 min): RE~T:)
Sub
50:
129
166
m/z-->
47 'I' iii ~~4b~. :-:s-"8:+1~--'-'--'-90+1' 1+h-6~0~1";O ~~~ Jo 140 150160
1 !~o
#63
Tetrachloroethene
Concen: 23.82 ug/l
RT: 14.26 min Scan# 812
Delta R.T. 0.01 min
Lab File: REC398.D
Acq: 17 May 2023 2:49 pm
Tgt Ion:164 Resp: 1330323
Ion Ratio Lower Upper
164 100
166 126.7 97.7 157.7
129 84.1 56.9 116.9
131 80.9 52.5 112.5
bundance 0i1104.01r(1o:f:TOToT64.70YREG398
lion 166.00 (165.70 to 166.70): REC398
8000001l0n 129.00 (128.70 to 129.70): REC398
ilon 131.00 (130.70 to 131.70): REC398
700000!
6000001 ,
500000!
14.26
400000i
300000' /\
200000' J,' ii ',\\, ! ,! \\
1000001 I \
I \\
O~I ______ _ ____ '---__ _
'----T------,..--~---,-----r--, , ,--
ime--> 14.20 14.40 14.60
REC398.D V067D26.M Thu May 18 08:37:38 2023 Page 8
REPORT ID: 23E120 Page 62 of 560
Quantitation Report (Qedit)
Data File D:\HPCHEM\I\DATA\23EI7\REC398.D
Acq On 17 May 2023 2:49 pm
Sample 23E120-08
Mise 2SmL
Vial: 20
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:34 2023 Quant Results File: temp. res
Method
Title
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
'A~! b~u-n1d~a-l'lce-. ----------~
! e+u7]
80000001
6000000:
4000000:
2000000 1
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Ion 1~(lT870 to 119. 70YREC3~8~-~---­
Ion 117.00 (116.70 to 117.70): REC398.D
9.36
r~====--t , \
OLi ~~~-r-T-~~-'-'c-r-~-~~~+-,_~-4--~~-,--,~ -,--,~~~--,;=:;=::;:=;:==;=T
Time--> 8.00 8.~0 8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80
Abundance Scan 477 (9.363 min): REC398.D
6000000' 117
4000000:
82 i I
2000000: 47 ' I !
10.00 10.20
j I i I : II
: 39 i. 58 70 If 91 102110 i i "24 136 187 203 219 235 254
m/z--> °30-4T05060~7o'-'-"8b+i 1-+! 1~9rrO~1-'60~1~1~0-,'1"'2.y0~·-13'" 0"';-"14-'-' 0~'~'1~5~0-1"6-0"-'-17nO~1~80~1-9~0~200 210 220 230 240 250 260
'Abundance -----~-------Scan 460 (9.10U min): RDC593JJ (-)
6000000:
4000000'
2000000
m/z-->
OT1 ~~_47"
3'0 40 50
59 70 82 117
60 70 8'0 9b 100 110 120
(41) Carbon tetrachloride (T,M)
9.36min 1968.14ug/l
response 131034224
Ion Exp% Act%
119.00 100 100
117.00 103.40 101.14
0.00 0.00 0.00
0.00 0.00 0.00
TIC: REC398.D
--------------
REC398.D V067D26.M Thu May 18 08:34:11 2023
210 220 230 240 250 260
REPORT ID: 23E120 Page 63 of 560
Quantitation Report (Qedit)
Data File D:\HPCHEM\1\DATA\23E17\REC398.D
Aeq On 17 May 2023 2:49 pm
Sample 23E120-08
Mise 25mL
Vial: 20
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:34 2023 Quant Results File: temp.res
Method
Title
Last Update
Response via
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
(RTE Integrator)
---------.IC:Oon;c-Tf9lJU1HS7Ol()'119. 70): REC398~.~D--~--~-----~~---~~
Ion 117.00 (116.70 to 117.70): REC398.D
80000001
i
60000001
4000000
2000000 1
9.36
~ I \
i 0 ,---: ---'--~~~-'~I~-r--r~~--'--'-~-l-! -,-,-~, -4{-~-~I'-'-~-''-'-1 l~---+-"=;::::::;:=;=;==;=;I=r='i='T=rl ~----r~"c--'--~_~
ITime--> 8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20
)l\bundance Scan 477 (9.363 min): REC398.D
I 60000001 1 H
II,
i '
, 40000001
82
2000000 47
; 39 5~ 70 i I 91 102110 II ~24 136 187 203 219 235 254
1m/z--> 03'0' 4b-"~50~,u6r-rb-r, "~7-'0~8~b+-li ,+1 ,';9b-;-' ~, ~10;-;i 0~1-;-10;:.,l-1cY2c,r;0'~1~3~0:':;-;:-14"0~' "'1~50~' ~1~6~0~1~7~0~18"6':'='1C,90~' 20C) 210220 230 240-250-260
Abundance Scan 460 (9.100 minfHD-c593.D (-)
, 60000001
4000000
2000000 1
; 47 59 70
°3() 40~T 50 '60' jb 82
'm/z-->
(41) Carbon tetrachloride (T,M)
9.36min 2170.21ug/l m
response 144487382
Ion Exp% Act%
119.00 100 100
117.00 103.40 91.72
0.00 0.00 0.00
0.00 0.00 0.00
117
TIC: REC398.D
o incorrect Retentk>n Time
o Incorrect Baseline
g' incorrect Integration o Other __ ~ ____ _
,/ /L t-. '--' . T I
J i . f\ j -~i(1;\\Vff
-------,/I--,hL.---------~-------------~-~----~~~---
l
REC398.D V067D26.M Thu May 18 08:34:14 2023
REPORT ID: 23E120 Page 64 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05112/23 11: 45
Project TEAD-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/18/23 17:24
Sample 10 S-139·17-05-2023D Date Analyzed: 05/18/23 17:24
Lab Samp 10 23E120-081 Dilution Factor: 500
Lab File 10 REC433 Matrix: WATER
Ext Btch 10 V067E18 % Moisture: NA
Calib. Ref. ROC593 Instrument 10: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/L) (ug/L)
__ ... a· ...... _ ....... • ..... ____ • .. ···· ._._-----_ .. -------_ .. _. _._ .. __ ..... _-....... ---_ ....
1.1.1.2-Tetrachloroethane NO 500 50 100
1. 1. I-Trichloroethane NO 500 50 100
1. 1. 2. 2·Tetrachloroethane NO 500 50 100
1.1.2·Trichloroethane NO 500 50 100
1.1-Dichloroethane NO 500 50 100
1.1-Dichloroethene NO 500 50 100
1.1-Dichloropropene NO 500 50 100
1. 2. 3.Trichlorggropane ND 1000 120 250
1.2.4-Trichloro enzene ND 500 75 150
1. 2-Dibromo· 3· chloropropane ND 1000 120 250
1.2·Dichlorobenzene ND 500 50 100
1.2-Dichloroethane ND 500 50 100
1.2-Dichlorogropane ND 500 50 100
1.3-Dichloro enzene ND 500 50 100
1.3-Dichlorogropane NO 500 50 100
1.4-Dichloro enzene ND 500 50 100
2.2-Dichloro~ro~ane ND 500 120 250
2-Butanone ( EK ND 10000 2500 5000
2-Chlorotoluene ND 500 120 250
2-Hexanone ND 10000 2500 5000
4-Chlorotoluene ND 500 120 250
Acetone ND 10000 2500 5000
Benzene NO 500 50 100
Bromobenzene ND 500 50 100
Bromochloromethane ND 500 75 150
Bromodichloromethane ND 500 50 100
Bromoform ND 500 75 150
Bromomethane ND 500 120 250
Carbon Disulfide ND 500 120 250
Carbon Tetrachloride 28000 500 50 100
Chlorobenzene ND 500 50 100
Chloroethane ND 1000 250 500
Chloroform 690 500 50 100
Chloromethane ND 500 120 250
cis-1.2-Dichloroethene ND 500 50 100
CiS'1.3-Dichloro~ropene NO 500 50 100
Dibromochloromet ane ND 500 50 100
Dibromomethane ND 500 50 100
Dichlorodifluoromethane ND 500 120 250
Ethyl benzene ND 500 50 100
ISOprO~Ylbenzene ND 500 50 100
m,~-xh ene ND 1000 100 250
4-et yl·2-Pentanone ND 5000 1200 2500
Methylene Chloride ND 1000 250 500
Methtl tert-butyl ether (MTBE) ND 500 75 150
n·Bu ylbenzene ND 500 120 250
n·Propylbenzene ND 500 120 250
o·Xylene ND 500 50 100
~-Isopro~bltoluene ND 500 120 250
ec·Buty enzene NO 500 120 250
Styrene ND 500 120 250
Tert-Butylbenzene ND 500 120 250
Tetrachloroethene ND 500 75 150
Toluene ND 500 50 100
Trans-1.2-Dichloroethene ND 500 50 100
Trans-1.3·Dichloropropene ND 500 120 250
Trichloroethene ND 500 50 100
Trichlorofluoromethane ND 500 120 250
Vinyl Chloride ND 500 55 150
1.2-Dibromoethane NO 500 50 100
1.2.3-Trichlorobenzene ND 500 75 150
1,4·Dioxane ND 50000 12000 25000
SURROGATE PARAMETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
.. __ ........ _ ............... -.-.......... -...... .. --_ ........ _--. ...... -..... _--._--.-.. _----_ .... _ ........ --
1.2·Dichloroethane·d4 5240 5000 105 70-130
4-Bromofluorobenzene 5460 5000 109 70·130
Toluene-d8 5420 5000 108 70·130
Dibromofluoromethane 5350 5000 107 70-130
Notes: Sample Amount : 0.050ml Final Volume: 25ml
Prepared b1' : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 65 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC433.D
Acq On 18 May 2023 5:24 pm
Sample 23E120-08I 500X
Misc 50uL
(QT Reviewed)
Vial: 26
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 8:20 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.15 114 2306651 10.00 ug/l 0.01
55) CHLOROBENZENE-D5 15.60 117 1635729 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 445818 10.00 ug/l 0.00
; System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 588044 10.70 ug/l 0.01
Spiked Amount 10.000 Recovery 107.00%
43) l,2-Dichloroethane-d4 9.30 65 439588 10.47 ug/l 0.01
Spiked Amount 10.000 Recovery 104. 70%
56 ) Toluene-d8 12.99 98 2464793 10.84 ug/l .-/" 0.02
Spiked Amount 10.000 Recovery 108.40%
77 ) 4-Bromofluorobenzene 17.62 95 657411 10.92 ug/l"'-0.01
Spiked Amount 10.000 Recovery 109.20%
Target Compounds ,,/ Qvalue
32) Chloroform 7.71 83 156700 ,r--1. 37 ug/l 96
41) Carbon tetrachloride 9.11 119 4361821 56.56 ug/l 100
/
(#) = qualifier out of range (m) = manual integration
REC433.D V067D26.M Fri May 19 08:20:37 2023 Page 1
REPORT ID: 23E120 Page 66 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC433.D
Aeq On 18 May 2023 5:24 pm
Sample 23E120-08I 500X
Mise 50uL
Vial: 26
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 8:20 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via : Initial Calibration
Abundance--~------------------------~------~-----~~-lrC:REC~r3-3-.-D-- -----------
8000000:
.
I
7500000i
I
70000001
65000001.
6000000 1
5500000:
5000000: :
4500000,
4000000i
i
I
35000001
I
..
! i
3000000, .
2500000
I
~ , . ,
2000000;
1500000.
1000000
500000'
(/)
oj
c:
'" £;
" E
~ ::;; " "" ..: 0
c.5 E
§ e .c
.E is
e
0 :;:
u
, :j
::;; r-:
Q)
"C ." 0
{3
~
c:
0 -e
'" u (/)
ui .,;
~ z w c: N " Z " W (;
OJ I-
0
~
0 => -' "-15
'":
!:I~
1!"9
'" c:
'" til
',
1£
:\~
1..:-
.n
0
uJ z w
N
Z
W
OJ (/)
0 oj
~ c:
0 Q)
N
-' c:
I Q) .c u e
0
" "" 0
E e
OJ ...
" 0
uJ
Z
W
N
Z
W
OJ
0
~
0
-' I u
15
~
:fime-->
0: ,--:-I' /\ j \. , , ," I' , . , ! . , "ii' . 'i' , .' i \ . ,
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00
REC433.D V067D26.M Fri May 19 08:20:38 2023 Page 2
REPORT ID: 23E120 Page 67 of 560
Abi,indance
:
--------S-can3-6317:683 mm): RD-C5H3-:Dl=)---~--------,
83 i #32
47
i I Chloroform
Concen: 1.37 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC433.D
Acq: 18 May 2023 5:24 pm
Tgt Ion: 83 Resp: 156700
Ra~;
47
I : i ~/z--> ~~r~:,:-,--l--I ,y: !--'-+~:0-'-~~6-'--0~"---'70~~8''o+'-! i-f-L! ;,-'-1 ;--91"0 ~'~1'TOO~~1r-r10'T 1 ~~o' 130
Abundance ----Scan 364 (7-:Tf2111ln): REC433'TI (-)
Sub,
50i
I
83
i i i i
I!
47 I i
1, i I
!m/z-->
40 II i i I 118 ~~O~-4-0-~~+'-i~+-'-b~~6b~~7'b~.,---,8b~14'1~! ~9'b~r-1~0~0~'T1'10~~1rl2~0~'T1~30
Abundance Scan 460 (9.100 min): RD'C5lIT.DT-) in
I!
, i
: 1
47 82 II:
I 0~~~:~~~59~~7~0~~1+1+,~,~~~~~~1~!~~2~,3~~.
'm/z--> 40 506b 70 8'0 90 100 11'0 ' 120
' I'i 11CW Abundance Scan 46019.115 mm): REC"43""'3".D---------
Ra~
Im/z __ >
lA.bundance
47
41
1171
6'0" 7'0' 80 9'0 100' 110 '120
Scan 460 (9.115 mm): REC433.D (-) in
I
I
I
Ion Ratio Lower Upper
83 100
85 65.5 39.4 99.4
47 26.4 0.0 56.0
bundancel()f1ff:r.OO-(82~70to83~70J:-REC433.D
40000ilon 85.00 (84.70 to 85.70): REC433.D
:Ion 47.00 (46.70 to 47.70): REC433.D
35000;
30000:
,
25000:
20000'
15000:
I
10000:
I
50001
7.71
1/ ,
0 1 ):~
ime--> 7.50 7.60 7.70 7.80~7.9()·8.&6
#41
Carbon tetrachloride
Concen: 56.56 ug/l
RT: 9.11 min Scan# 460
Delta R.T. 0.01 min
Lab File: REC433.D
Acq: 18 May 2023 5:24 pm
Tgt Ion:119 Resp: 4361821
Ion Ratio Lower Upper
119 100
117 103.3 73.4 133.4
bundancelonTf9-:DOTlTff.70-{o -n9.70):REC433
ilon 117.00 (116.70 to 117.70): REC433
8000001
I
600000j
I 400000
I
I
/\
I i Sub
50,
47 82
200000i i \
\
I J 0.--~~4~1 ~~~~~~~~~L--~~~~ _~_: -L-i 1~23~ 0 ~:=~ ____ ~~-_-:-:-::~.--
m/z--> 40 50 60 70 80 90 100 _1_1.::..0 __ 1c:2=-=0_--.:1-=-30-=--.J.:if..c.im_e=----_> __ --=8c:.:.8'-=--0 9.00 9.20
REC433.D V067D26.M Fri May 19 08:20:39 2023
9040
Page 3
REPORT ID: 23E120 Page 68 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05112/23 11: 40
Project TEAD-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/17/23 15:15 # 05/18/23 17:50
Sa!IIPle ID S-139-17-052023 Date Analyzed: 05/17/23 15:15 05/1B/23 17:50
Lab Sal!lP ID E120-09 120-091 Dilution Factor: 1 # 500
Lab File ID REC399 EC434 Matrix: WATER
Ext Btch ID V067E17 067E18 % Moisture: NA
Calib. Ref. RDC593 C593 Instrument ID: 67 # 67
RESULTS LOO DL LOD
PARAMETER(S} (ug/L) (ug/L) (ug/L> (ug/L>
....... _ ........... __ ... ---.... _-_ .. _---_ ..... -.. _---.. _-_ .......... ............. _ ... ............. _-
1. 1. 1. 2·Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1.2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene 0.40J 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorggropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone NO 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene 0.33J 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide 1.7 1.0 0.25 0.50
# Carbon Tetrachloride 29000 500 50 100
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
# Chloroform 680 500 50 100
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~YlbenZene ND 1.0 0.10 0.20
mtxf: ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride 4.3 2.0 0.50 1.0
Met~l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene 24 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene 0.12J 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene 4.5 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1. 2. 3-Trichlorobenzene ND 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
............ -.... _--------.... -..... _-_. ---_ .. -._--------.-----------_ .. _------.-_ .. _--
1.2-Dichloroethane-d4 8.82 10.0 88 70-130
4-Bromofluorobenzene 10.3 10.0 103 70-130
Toluene-d8 10.6 10.0 106 70-130
Dibromofluoromethane 12.7 10.0 127 70-130 i 1.2-Dichloroethane-d4 5150 5000 103 70-130
4-Bromofluorobenzene 5450 5000 109 70-130
Toluene-d8 5460 5000 109 70-130
Dibromofluoromethane 5280 5000 106 70-130
# Result(s} associated as marked on the header
Notes: Sample Amount 25ml Final Volume: 25ml
Prepared by VLu Analyzed by : VLu
# Sample Amount 0.050ml Final Volume: 25ml 11 Prepared by VLu Analyzed by : VLu
Detection limits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 69 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/12/23 11: 40
Project TEAD-S Date Received: 05/16123
Batch No. 23E120 Date Extracted: 05/17/23 15: 15
Sample ID S-139-17-052023 Date Analyzed: 05/17/23 15: 15
Lab Samp ID 23E120-09 Dilution Factor: 1
Lab File ID REC399 Matrix: WATER
Ext Btch ID V067E17 % Moisture: NA
Calib. Ref. RDC593 Instrument 10: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/L) (ug/L) (ug/L)
--. __ ... __ ........................ _ .. __ .. _ .. ----............. . ................ .. .................
1,1 , 1 ,2-Tetrachl oroethane NO 1.0 0.10 0.20
1,1 ,I-Trichloroethane NO 1.0 0.10 0.20
1,1,2,2-Tetrachloroethane NO 1.0 0.10 0.20
1,1,2-Trichloroethane NO 1.0 0.10 0.20
1,1-Dichloroethane NO 1.0 0.10 0.20
1,1-Dichloroethene 0.40J 1.0 0.10 0.20
1,1-Dichloropropene NO 1.0 0.10 0.20
1,2,3-Trichlorogropane NO 2.0 0.25 0.50
1,2,4-Trichloro enzene NO 1.0 0.15 0.30
1,2-Dibromo-3-chloropropane NO 2.0 0.25 0.50
1,2-Dichlorobenzene NO 1.0 0.10 0.20
1,2-Dichloroethane NO 1.0 0.10 0.20
1,2-Dichlorogropane NO 1.0 0.10 0.20
1,3-Dichloro enzene NO 1.0 0.10 0.20
1,3-Dichlorogropane NO 1.0 0.10 0.20
1,4-Dichloro enzene NO 1.0 0.10 0.20
2,2-Dichloro~ro~ane NO 1.0 0.25 0.50
2-Butanone ( EK NO 20 5.0 10
2-Chlorotoluene NO 1.0 0.25 0.50
2-Hexanone NO 20 5.0 10
4-Chlorotoluene NO 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene 0.33J 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane NO 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide 1.7 1.0 0.25 0.50
Carbon Tetrachloride 2200E 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform 560E 1.0 0.10 0.20
Chloromethane NO 1.0 0.25 0.50
cis-1,2-Dichloroethene NO 1.0 0.10 0.20
CiS-1,3-Dichloro~ropene NO 1.0 0.10 0.20
Dibromochloromet ane NO 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISoprO~Ylbenzene ND 1.0 0.10 0.20
m,wxf: ene NO 2.0 0.21 0.50
4-et yl-2-Pentanone NO 10 2.5 5.0
Methylene Chloride 4.3 2.0 0.50 1.0
Meth{l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene NO 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene 24 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1,2-Dichloroethene 0.12J 1.0 0.10 0.20
Trans-I , 3-Dichloropropene NO 1.0 0.25 0.50
Trichloroethene 4.5 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1,2-Dibromoethane ND 1.0 0.10 0.20
1,2,3-Trichlorobenzene NO 1.0 0.15 0.30
1.4 -Di oxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
................................................... ................... ...... -.......... . _ .. __ .-.. _ ... .... __ ...........
1,2-Dichloroethane-d4 8.82 10.0 8B 70-130
4-Bromofluorobenzene 10.3 10.0 103 70-130
Toluene-d8 10.6 10.0 106 70-130
Dibromofluoromethane 12.7 10.0 127 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b1' : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 70 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC399.D
Acq On 17 May 2023 3:15 pm
Sample 23E120-09
Misc 25mL
(QT Reviewed)
Vial: 21
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.18 114 1890818 10.00 ug/l 0.04
55) CHLOROBENZENE-D5 15.62 117 1497413 10.00 ug/l 0.02
74) 1,2-DICHLOROBENZENE-D4 19.50 152 450628 10.00 ug/l 0.02
.\System Moni toring Compounds
, ~ 36) Dibromofluoromethane 8.22 111 574272 12.74 ug/l 0.03
Spiked Amount 10.000 Recovery 127.40%
43) 1,2-Dichloroethane-d4 9.38 65 303586 8.82 ug/l---0.09
Spiked Amount 10.000 Recovery 88.20%
56 ) Toluene-d8 12.99 98 2209132 10.61 ug/l /' 0.02
Spiked Amount 10.000 Recovery 106.10%
77 ) 4-Bromofluorobenzene 17.62 95 629518 10.34 ug/l ___ 0.02
Spiked Amount 10.000 Recovery 103.40%
/'
. Target Compounds Qvalue
14) 1,1-Dichloroethene 3.80 61 41562 0.40 ug/l 98
.",. 19 ) Carbon disulfide 4.54 76 371174 1. 72 ug/l 100
20) Methylene chloride 4.56 49 380587 A.33 ug/l 99
23) trans-1,2-Dichloroethene 5.07 96 8655 .---0-. 12 ug/l 90
32J Chloroform 7.71 83 52667035 ~62. 53 ug/l e 85
37) Cyclohexane 8.65 84 103340 0.98 ug/l 96
41) Carbon tetrachloride 9.35 119 141182986m 2~33.43 ug/l£
44) Benzene 9.54 78 82873 ~ 0.33 ug/l 97
46 ) Trichloroethene 10.75 130 280978 ?50 ug/l 97
47) Methylcyclohexane 10.85 83 61397 0.52 ug/l 88
63) Tetrachloroethene 14.26 164 1271624 /24.07 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC399.D V067D26.M Thu May 18 08:35:54 2023 Page 1
REPORT ID: 23E120 Page 71 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC399.D Vial: 21
Aeq On 17 May 2023 3:15 pm
Sample 23E120-09
Mise 25mL
Operator:
Inst
Multiplr:
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: May 18 8:35 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
3.8e+07·
3.6e+07·
3.4e+07i
3.2e+07·
3e+07·
2.8e+07!
2.6e+07i
I
2.4e+07!
2.2e+07·
2e+07·
1.8e+07:
1.6e+07:
1.4e+07 i
1.2e+07
1e+07
8000000"
6000000:
4000000
2000000
:2
~
c.5
oj
" .,
~ e
0 :c
" i:'?
:2
1-0
:2 .,
" Ii .,
£ I .,
e
0 :c
.>1 .19 0 "t! 0:; f '" " ~
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIc:REG391r.D
w z
UJ
N if) Z oj UJ :2 " CD if) '" 6. 0 + <Xi £ ex: f-oi " .,
f-: 0 I " E :2 ::J " e ~ ,.,
-' ., '" 0 oj '., "-:;;
:;; N 0 I (5
0= " '" " f-0 ., * E x ., CD e .c
.0 0
is 13 ~ >-
0 :2
(RTE Integrator)
:2
~
oj
" on ., 0 if)
£ W oj ., " e z .,
0 UJ N :c N " " z .,
UJ .0 ~ e CD 0 Q) 0 f-:;; ex: 0= 0 0
-' E
I e
0 CD
"
0; i \.J\ ---~;'-", " ,'~. , , ' __ ---y---~_~ __ . __ ~ __
.;f
0
W z
UJ
N z
UJ
CD
0 ex:
0
-' I
0
0
0:;
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.009.00 10.00 11.00 12.00 13:00 14.00 15:00 16.00 17.00 18:00 19.0020.0021.00
REC399.D V067D26.M Thu May 18 08:35:55 2023 Page 2
REPORT ID: 23E120 Page 72 of 560
lI'I6tiridance
RefO
o
m/z--> 35 Abundance-
Ra~:
j
Sub:
50i
40
44
Sca.nl1r3\3758 min): RDC593.D Fi---
611
I
!
96
96
96
#14
l,l-Dichloroethene
Concen: 0.40 ug/l
RT: 3.80 min Scan# 104
Delta R.T. 0.04 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
Tgt Ion: 61 Resp: 41562
Ion Ratio Lower Upper
61 100
96 61. 2 33.2 93.2
63 32.7 3.7 63.7
r'-Olindanceron 61 :D'a\oO~7a to 61.70): REC399.D
8000110n 96.00 (95.70 to 96.70): REC399.D
lion 63.00 (62.70 to 63.70): REC399.D
7000!
60001
5000i
4000:
3.80
40
3000 1
2000:
I I 10001
47 II 1100 :m/Z-=?_~_~'5 .. 4'0 ;ffiLI -n51~ci ~55~+-+~!0+11 !~; 6"b'" '~7"b~7-"5~8"'o~8'TTI5~' ~9"0~' "'9,'+5 c+I1,.j6-'o~1TT6-n5~ ~ime--> O-=:;=~~; -;~~~;~;O 4.00 4.10
Abundance
i RefOi
44
scan 145 (4.497 min): RDC593.D (-)
76
49
84
O~ .. -.~ .. -_~ __ • ~r1c-++1 f-h..J=.p2=.-. T"T~. I 64 70 ,! LV,9=" ..---r+-,-l-,,88~~~.
m/z--> 30 35 4'0 45 50 55 60 65 70 75 80 85 9'0 95
.Abundance Scan 147 (4.542 mlllyREC:r99"'.'"'D-----.-":~-"""-"""---j
4~
76 84
Ra~,
44
o 41 64 67 .~~;7-r-9~+"_~~ __ --
m/z--> 30 35' 40 45 50 55 60 . 6'5 '7'0 75 8'0 85 9'0' 9'5
88
A5und~ance---~-----Scan-147 (4.542 min): REC399~D (-)
49
#19
Carbon disulfide
Concen: 1.72 ug/l
RT: 4.54 min Scan# 147
Delta R.T. 0.04 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
Tgt
Ion
76
78
Ion: 76 Resp:
30000j
Ratio Lower
100
9.2 6.3
371174
Upper
11. 7
Sub
50
76
84
1 I 20000
10000
o 41 44, 64 67 79 88 l 0------=-·--
m/z--> 30 35--'~4s50 55 60 65' . 70 75 ~85--rOO9s ime--> ..... 4.40--4.60
- -------------------~----------- --------4.80
REC399.D V067D26.M Thu May 18 08:35:56 2023 Page 3
REPORT ID: 23E120 Page 73 of 560
Re~ 49
44
i o~i ~~~~-r~1 )2, i' i ,64 7? i , 179
h,/z--> 35 40 45 50 55 60 65 70 75 80
hc'ALCbuC:::n:-:>d~an=-=c:-:Ce~ Scan 148\43517 min): RECJ91HJ
Ra~
Sub i
50,
Abundance
Re~
49
i
76
76
Scan 181 (5.023 min): RD-C-593.D (-)
~1
I
,j
#20
Methylene chloride
Concen: 4.33 ug/l
RT: 4.56 min Scan# 148
Delta R.T. 0.05 min
84 Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
, ! 88
I
85
84
84
96
I i Tgt Ion: 49 Resp: 380587 ~-'-~i
90 95 Ion Ratio Lower Upper
49 100
84 72.8 41.7 101.7
86 45.8 15.7 75.7
, bundaricelon-49-'-00T4KTOT64970):REC399.D
'Ion 84.00 (83.70 to 84.70): REC399.D
800001l0n 86.00 (85.70 to 86.70): REC399.D
i
60000:
I
40000i
200001
4.56
4.60 4.80 5.00
#23
trans-1 t 2-Dichloroethene
Concen: 0.12 ug/l
RT: 5.07 min Scan# 183
Delta R.T. 0.04 min
i Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
o 4 7 iii 67 i ! ,100
m/z--> 310-35--4045~ 50 55 60' 6'5 '70 7'5 80 8'5'90 Tgt
Ion
96
98
Ion: 96 Resp: 8655
Upper Aoundance-----Scan 183 (5.068 mTrifREC-:399~
Ra~
Sub·
50
40
4~ 6,1
76
95 100 105
96
96
Ratio Lower
100
55.0 32.9 92.9
ps;buridancelo-ri-9KOO (95.70 to9670):REC399.D I :ion 98.00 (97.70 to 98.70): REC399.D
2000' 5.07
1000]
5001
I
I OL~~-~--:---: -=~~ __ ~-~ __ ,_
'8'5 __ 99_' '_95_10~_H)_5_JrlrnEl~~> 4.904.955.005.055.10 5.15 5.20 m/z-->
0----.-, , ,.' i 'T,'
30 35 40 45 50 55 60 65 70 75 80
REC399.D V067D26.M Thu May 18 08:35:56 2023 Page 4
REPORT ID: 23E120 Page 74 of 560
Re~!
47
55
O,-:-~. ~~r~jc-c4L~~~~~!,~,--L.~~. ~I ~, .~.~.~,~. ~'~--,--r+-i-c---~
m/z--> 30 40 50 60 70 80 90 100 110
Abunaance ------. ~---Scan3041T.Tf3 mlrirREC3~r9~--'--'-=~=
Ra~ 47
,
0,,-41 ii,
m/z--> 30
Abundance
Sub'
50 47
83
1
: I
120
. I
120 130
#32
Chloroform
Concen: 562.53 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
bundance TOrll33~OO(8Z70l08370J~REC399~D~
lion 85.00 (84.70 to 85.70): REC399.D
8000000jlOn 47.00 (46.70 to 47.70): REC399.D
7.71
6000000:
4000000:
20000001
I
i 41 :i !II 58 70
I
II,i i 120 I I 01-..-~-"---Oll~~~~"~~~~T~~~'+~~~~ in/z--~ 3'o=--------'~
I
I . I ' , I ' I ~
40 50 60 70 80 90 100 110 .-'"--_~ __ -=-=._--".:,-_--'-"~: ..... ~~:.:~ __ ~_ r+_1:2=.0~_~ .... 13~6'---l.:tr .... im:."e __ --_> __ ~~_''..'...:7.~O-7.60 7.80 8.00 8.20
Abundance
41
Re~; I
Scan .l2'3l83'59 min): RDC59:f.'D~( -~) ~~------,
5:6
84
97
69
63 117
51 i' II' 77 ,I, 1.1
mlz--> O~o'--~' ~4L,0 c.,---~5~0~' 60 70 8'0 90 ·,L1;.L0~0~~-~J...Y'.=-~~ i 123
.. ! I,
110 120 ~ Abundance Scan 428llf.Q4ffminfHEC399.D
~6
84
41
Ra~
69
m/z-->
Ol--~I.'
30 40
51 ,
50 60 7'0 80 90 100 .---"".'"-----
#37
Cyclohexane
Concen: 0.98 ug/l
RT: 8.65 min Scan# 428
Delta R.T. 0.09 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
Tgt Ion: 84 Resp: 103340
Ion Ratio Lower Upper
84 100
69 34.5 6.8 66.8
6000!
4000·
2000
REC399.D V067D26.M Thu May 18 08:35:56 2023 Page 5
REPORT ID: 23E120 Page 75 of 560
Abundance
RefO'
47 82
#41
Carbon tetrachloride
Concen: 2233.43 ug/l m
RT: 9.35 min Scan# 476
Delta R.T. 0.25 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
200 220 . 240J Tgt
, Ion
Ion:119 Resp:141182986
Ratio Lower Upper
100
47 82
I:
i i OL--,--r~~5",,8 2-~T~;! 93. ~04 1~~28140. ,187201
m/z--> 40 6'0 80 100 120 140 160 180 . 200
lA.bundance Scan 476 (9.349 min): REC399.D (-
i 111 9
!I
Sub
50
47 82 ,[
I
219 235
220 240
185 203 219 235
ibundance
RefO
52
39 63 o~--,-L~~
m/z --> 40' 6'0
Abundance
Ra~.
47
180 . 200 '220 240
-------Scan 485 (9.465 min): RDC593.D (-)
78
!
;:' 98
:,ij'l
80 100 120 140 160 180
SCan489\9.539 min): REC3mnJ
11[7
;i
82
200 220 240
58 70 'I. 136 182 219 233 0, .~~~~~~~~~
! 119
117 93.3 73.4 133.4
rbundancelO-n-1T9:'0.-01111l.70 16-n9-. 70): REC399
!Ion 117.00 (116.70 to 117.70): REC399
70000001 935 , .
6000000:
j
5000000!
i
4000000j
3000000i
20000001 I
10000001 )
o t:::'--=-'-----
ime--> 8.80 9.00 9.20 9.40 9.60
#44
Benzene
Concen: 0.33 ug/l
RT: 9.54 min Scan# 489
Delta R.T. 0.07 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
Tgt Ion: 78 Resp: 82873
Ion Ratio Lower Upper
78 100
77 25.4 0.0 53.5
52 17.1 0.0 47.6
, bundance on78:-00-(7TT0l078'JOYR'EC399'.D
25000
:ion 77.00 (76.70 to 77.70): REC399.D
:Ion 52.00 (51.70 to 52.70): REC399.D
9.54
m/z--> 40 60 80 100 120 140 160 180 200 220 240 c.;.A~bu=--n~d~an-c-e-'-=-----------~Scan 489 (9.539 min): REC-:r9'9~.;';D--;:(-~)~=------='"--------=-"-"--I 200001
150001
Sub
50.
O·
62
78
120
100001
5000
136
182. ___ 2_~9_~3.3. I O'-~c---~_C-.'L
m/z--> 40 60 80 100 120 140 1§Q. _.!130 __ ?Q.Q?20 __ ~~QJrli!l~--;:' 9.40 9.50
REC399.D V067D26.M Thu May 18 08:35:57 2023
9.60 9.70
Page 6
REPORT ID: 23E120 Page 76 of 560
RefOi 60 , i i' ,
I :
i 47 I 1"
I 83' 'I' I"~ l' 36
! 41 53' 66 72 ,!i,'I",1
! OT-~'---,--"""i_,----.-W-'--t------r-i~l r--'-~~ I I·" p----.--.-rt'I';-wJ 14'-,--,--,c-r-o
mlz--> 30 40 50 60 70 80 90 '106 116 120 130 140 Abundance---~-----~SCai15T2lTIf.752 min): REG391DJ
9P 130
! i , I
I ! I
II i
ii,
II I
47 I i 1 7 ' I' ,
Ra~; 60
#46
Trichloroethene
Concen: 4.50 uq/l
RT: 10.75 min Scan# 572
Delta R.T. 0.03 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
Tgt Ion:130 Resp: 280978
Ion Ratio Lower Upper
130 100
132 94.3 65.3 125.3
95 99.1 71.1 131.1
97 63.5 40.3 100.3
bundance ori13-o:m)Tf2970 to T3-0. 70YREC399
120000Jion 132.00 (131.70 to 132.70): REC399
lion 95.00 (94.70 to 95.70): REC399.D
lion 97.00 (96.70 to 97.70): REC399.D
1000001 Or-~, ,~~0!Lr~ ii,! 66 72 8,2, III: i]23 c+i+1i-\' ~--o-6,--c-c~
'm/z--> 30 40 50 6b I 7b" 8'0 9'0 166' _1 'ri-1;..0-,T1~20=--~1~30=--~1-=-:40=---j Abundance~-----~---Scan 572(10:752 min): REC399.D (-) 10.75 80000i , 95
I
Sub,
50! 60
i I
: j
i 47 i : !
1 41! , '1 i 66 72 83 ; i i i I
: I
"i ~6 0t---~-T-,----,--Jl---'i'----;-n~~~,--,-, ~--'-, ->41 i~-,-,L\l-., 1" ~-,,-
30 40 50 60 70 80 90 100 110 120 130 140
~bundance
! I
!
!
RefO:
,
o
m/z--> 3'0
Scan 577 (10.809 mInYRU1:'593Il (-)
55 8
1
3
,
41 98
,
,
69 I
I: I' i,i l 47,1k, 63 ,iii 7711 91 ,I, 130
,
: 1,
'\ 1" Ii
Jt',
., '\
600001
40000j
20000:
' ,
ime-->
l \
0; =_.,!=c_=-_'::~c
10.60 10.70 10.80 10.90
#47
Methylcyclohexane
Concen: 0.52 ug/l
11,00
RT: 10.85 min Scan# 579
Delta R.T. 0.05 min
Lab File: REC399.D
Acq: 17 May 2023 3:15 pm
Tgt Ion: 83 Resp: 61397
Abundance
40 50 60 7'08'090' 100 110 '120 130 140
Scan o79TfIDf54 min): REC'391f.'"'D-----'----1 Ion Ratio Lower Upper
83 111
55
98
, Ra~:
41
47 69
130136
m/z--> 0~4;~C;~" to' 80
11
:, 90 '~'Oo' 110120~14O-
Abundance Scan 579 (1 O~mlnrHEG3991JT-) ,
, 83
Sub'
50 41
55
O---"-~,,-,,-~,~' 4,-,
,
70
98
I ,
132
83 100
55 77.4 57.8 117.8
98 42.6 22.9 82.9
'F! -bu----lon-83~OO(82:7016-83:70):REC399.D nfJllliOl lon 55.00 (54.70 to 55.70): REC399.D
I lion 98.00 (97.70 to 98.70): REC399.D
12000 1
10000 1
80001
6000:
i
4000j
2000
o'-~
10.85
,-----~--~----------------.----"-
m/z--> 30 40 50 60 70 80 90 100 110 120 130 140 ime--> 10.60 10.80 11.00
-~-----~~~------------
REC399.D V067D26.M Thu May 18 08:35:57 2023 Page 7
REPORT ID: 23E120 Page 77 of 560
Abundance Scan 812 (14.243 min): RDC59J.~-~-n #63
1~ Tetraehloroethene
129 i! I Cone en : 24.07 ug/l
II RT: 14.26 min Sean# 812
! i I De 1 taR. T . 0 . 02 mi n
:,',1' i Lab File: REC399.D
Aeq: 17 May 2023 3:15
94
pm
RefOi
47
82 59
m/z--> ~;O-40-50~60 i~ 801-.-9'0 ~ i~60 1101~O~13~ 1fo" 150 160+i
i '"'"1'7""'0~~' r Tgt Ion: 164 Resp: 1271624
~bundance-'-~~----Scan812lT4.258mln):RECJg9.D I Ion Ratio Lower Upper
47
59
82
129
1~6 I i~: ig~.4 97.7 157.7
94
I
I,
i I II
! Ii,
II I!: Ii '", iii
129 84.9 56.9 116.9
1131 80.8 52.5 112.5
bu-ndancelon T64.00 \16'3.70 toT64.70):REC399
800000110n 166.00 (165.70 to 166.70): REC399
;Ion 129.00 (128.70 to 129.70): REC399
700000jlon 131.00 (130.70 to 131.70): REC399 ill! ! i'
o ,6674 I, ", 117,111, 11'1
,m/z--> 3h-b~4~0h-, "'50"60'70 8'0 90"100 110 120 13J,0'r'~14TT'0~'~15TTI0~16T'0-+Y+1f()' 600000,
Abundance--'~---Scan 812 (14.2'08 min): REC399.D (-)
I
Sub!
501 I
129
47
500000j
400000]
14.;26
'(-;
300000 I W~\:
200000 i f \\)
1000001 1"
0 1 ------~~ -
\-n/z-->
~~---. I----.----,-~-r________r'~-"~-,,
ime-->~~_1_4._1~0 14.20 14.30 14.40 14.50
REC399.D V067D26.M Thu May 18 08:35:58 2023 Page 8
REPORT ID: 23E120 Page 78 of 560
Quantitation Report (Qedit)
Data File D:\HPCHEM\1\DATA\23E17\REC399.D
Aeq On 17 May 2023 3:15 pm
Sample 23E120-09
Mise 25mL
Vial: 21
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:35 2023 Quant Results File: temp. res
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
80000001
i
6000000;
40000001
i
2000000'
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
IA.bundance Scan 442 (8.852 min): REC399.D
5000
44 83
2d
~ ~ !
Im/z __ > ~~~35'-'--c40~-+~~!5~~5"b~ ~5-+,~+-i ~6-'--b~' ~6~5~'~0 75 81~~5 ' 9'0 95100r105~~ 11 O~1151 ~:O 125 130
Abundance~-~--Scan 46\)\9:100 min): RDCo93-:D (-)
117
5000;
47 82
m/z-->
42 59 70 i • 86 O~ ~ ... -~ ..... -.. -.~~~-.~--... .~~~~ ,~~~ 1~l.,+~~~~~~~~·"'C '~"'--~~-'~_~_'~T ____ '
30 35 40 45 50 55 6'0 05 7'0 75 80 85 90 95 100105110115120125130
TIC: REC399.D
(41) Carbon tetrachloride (T,M)
8.85min 0.01ug/l
response 324
Ion Exp% Act%
119.00 100 100
117,00 103.40 40634806.48#
0.00 0.00 0.00
0.00 0.00 0.00
------.--~--.. ~.-.---~
REC399.D V067D26.M Thu May 18 08:35:23 2023
REPORT ID: 23E120 Page 79 of 560
Quantitation Report (Qedit)
Data File D:\HPCHEM\1\DATA\23E17\REC399.D
Aeq On 17 May 2023 3:15 pm
Sample 23E120-09
Mise 25mL
Vial: 21
Operator: VLu
Inst 67
Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 18 8:35 2023 Quant Results File: temp.res
Method
Title
Last Update
Response via
~bundaitce 1e+071
BOOOOOO;
I
60000001
I
I
4000000;
2000000;
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Ion 119.00TlT8.70 to 119.70TREC-3-g-g:rr-
Ion 117.00 (116.70 to 117.70): REC399.D
rrime--> 8.00 B.20
~bundance
, 60000001
I
4000000!
2000000i
0 1
47 82
I
II
Scan 476 (9.349 min): REC399.D
117
II
, I
39 : I~ 58 7
1
0 II i 91 102 i I ~~4 136 187 203 219 235
m/z--> 30 ~bundance
6000000'
40 50 6'0' 70 8b
l
.. 90 160 110 120 130 140 150 ' 160 170 180'T190 200 210'
T
220 -'230 240
--------.S""c=a;;O-n "'46""O"{'9:fQO min): RDC59-3-:D (-) -~-----,,-----------
4000000
2000000;
I
I
47 59 70 0'
'm/z--> 3b 4'0
• I
7'0 50 60
82 117
TiC: REC399.D
(41) Carbon tetrachloride (T,M)
9.35min 2233.43ug/l m ~'noorrect Reientlol1 Time o incorrect Baseline
response 141182986 o Incorrect Integration
Ion Exp% Act%
o Other _____ ~~
119.00 100 100 Initlals~~ _~/'~ I t L
117.00 103.40 93.25
0.00 0.00 0.00
0.00 0.00 0.00
REC399.D V067D26.M Thu May 18 08:35:37 2023
REPORT ID: 23E120 Page 80 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/12123 11:40
Project TEAD-S Date Received: 05/16/23
Batch No. 23E120 Date Extracted: 05/18/23 17:50
Sample ID S-139-17-052023 Date Analyzed: 05/18/23 17:50
Lab Samp ID 23E120-09I Dilution Factor: 500
Lab File ID REC434 Matrix: WATER
Ext Btch ID V067E18 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOO DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/l) (ug/L)
~ .......................................................... .................... . ................. ................ . .................
1. 1. 1. 2-Tetrachl oroethane ND 500 50 100
1. 1. I-Trichloroethane ND 500 50 100
1. 1. 2. 2-Tetrachloroethane ND 500 50 100
1.1.2-Trichloroethane ND 500 50 100
1.1-Dichloroethane ND 500 50 100
1.1-Dichloroethene ND 500 50 100
1.1-Dichloropropene ND 500 50 100
1. 2. 3-Trichlorogropane ND 1000 120 250
1.2.4-Trichloro enzene ND 500 75 150
1.2-Dibromo-3-chloropropane ND 1000 120 250
1.2-Dichlorobenzene ND 500 50 100
1.2-Dichloroethane ND 500 50 100
1.2-Dichlorogropane ND 500 50 100
1.3-Dichloro enzene ND 500 50 100
1.3-Dichlorogropane ND 500 50 100
1.4-Dichloro enzene ND 500 50 100
2.2-Dichloro~ro~ane ND 500 120 250
2-Butanone ( EK ND 10000 2500 5000
2-Chlorotoluene ND 500 120 250
2-Hexanone ND 10000 2500 5000
4-Chlorotoluene ND 500 120 250
Acetone ND 10000 2500 5000
Benzene ND 500 50 100
Bromobenzene ND 500 50 100
Bromochloromethane ND 500 75 150
Bromodichloromethane ND 500 50 100
Bromoform ND 500 75 150
Bromomethane ND 500 120 250
Carbon Disulfide ND 500 120 250
Carbon Tetrachloride 29000 500 50 100
Chlorobenzene ND 500 50 100
Chloroethane ND 1000 250 500
Chloroform 680 500 50 100
Chloromethane ND 500 120 250
cis-1.2-Dichloroethene ND 500 50 100
CiS-1.3-Dichloro~ropene ND 500 50 100
Dibromochloromet ane ND 500 50 100
Dibromomethane ND 500 50 100
Di ch 1 orodi fl uoromethane ND 500 120 250
Ethyl benzene ND 500 50 100
ISOprO~YlbenZene ND 500 50 100
m,~-xh ene ND 1000 100 250
4-et Yl-2-Pentanone ND 5000 1200 2500
Methylene Chloride ND 1000 250 500
Met~l tert-butyl ether (MTBE) ND 500 75 150
n-Bu ylbenzene ND 500 120 250
n-Propylbenzene ND 500 120 250
o-Xylene ND 500 50 100
~-Isopro~bltoluene ND 500 120 250
ec-Buty enzene ND 500 120 250
Styrene ND 500 120 250
Tert-Butylbenzene ND 500 120 250
Tetrachloroethene ND 500 75 150
Toluene ND 500 50 100
Trans-1.2-Dichloroethene ND 500 50 100
Trans-1.3-Dichloropropene ND 500 120 250
Trichloroethene ND 500 50 100
Trichlorofluoromethane ND 500 120 250
Vinyl Chloride ND 500 55 150
1.2-Dibromoethane ND 500 50 100
1.2.3-Trichlorobenzene ND 500 75 150
l,4-Dioxane ND 50000 12000 25000
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
........................................... ... ---......... -----. __ .. -. ........ _--_ ..... ---_ ... "_."
1.2-Dichloroethane-d4 5150 5000 103 70-130
4-Bromofluorobenzene 5450 5000 109 70-130
Toluene-d8 5460 5000 109 70-130
Dibromofluoromethane 5280 5000 106 70-130
Notes: Sample Amount : 0.050ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 81 of 560
Quantitat'.on Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC434.D
Acq On 18 May 2023 5:50 pm
Sample 23E120-09I 500X
Misc 50uL
MS Integration Params: RTE.P
Quant Time: May 19 8:19 2023
Vial: 27
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.15 114 2285051 10.00 ug/l 0.01
55 ) CHLOROBENZENE-D5 15.60 117 1604883 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.50 152 430883 10.00 ug/l 0.01
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 574920 10.56 ug/l 0.01
Spiked Amount 10.000 Recovery 105.60~
43 ) l,2-Dichloroethane-d4 9.30 65 428481 10.30 ug/l ( 0.01
Spiked Amount 10.000 Recovery 103.00%
56) Toluene-d8 12.99 98 2436981 10.92 ug/l ,-/" 0.02
Spiked Amount 10.000 Recovery 109.20%
77) 4-Bromofluorobenzene 17.62 95 634798 10.91 ugly 0.01
Spiked Amount 10.000 Recovery 109.10%
/
j Target Compounds Qvalue
32) Chloroform 7.71 83 153415 1. 36 ug/l 97
41 ) Carbon tetrachloride 9.11 119 4360727 57.08 ug/l 100
(#) = qualifier out of range (m) = manual integration
REC434.D V067D26.M Fri May 19 08:19:41 2023 Page 1
REPORT ID: 23E120 Page 82 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC434.D
Aeq On 18 May 2023 5:50 pm
Sample 23E120-09I 500X
Mise 50uL
Vial: 27
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 8:19 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
A511ndanc~~-
8000000'
7500000·
I
7000000j
i
6500000
60000001
5500000,
i
5000000]
4500000;
4000000: '
,
, I
3500000; ,
3000000
2500000
2000000;
1500000
1000000, '
500000
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration rrG:REC43"'4"".O...-------~~~--------~~----~ ~
:2 ..:
ci
"0 ." 0 :c
" ..
.:"
2
c:
0 -e .. .,; U
en a
W 05 W
z "% z w w c: N N
Z Q) Z ::> W w (5 <D en <D t-o ci 0 0:: c:
0:: 0 Q)
0 N -' c: :::l I Q)
-' U .0 u.. e c 0
* ::>
en ilcn 'is
E ci c: il[:g-e .. <D .s:: qd> ... Q) dffi E e II~ 0 )I~ :2 ::> <= ..: 0
c5 E ; !'5
g e 1:0
.0 !N .g ;s ii~ e
0
:E
U
II!:
-i a
W z w
N
Z
W m
0
0::
0
...J
I
U c
N.
Time-->
0 1 .\~ f\ !,\ ! VI, !(
2.00 3.00 4.00 5.00 6.00 7.00 S.OO 9.00' 10:0011:00 12:00 13:0014.00 15:00 16:00 17:00 18.00 19.0020.00 21.00
REC434.D V067D26.M Fri May 19 08:19:42 2023 Page 2
REPORT ID: 23E120 Page 83 of 560
lIi.bundance
I i , !
I
Renal
I
I
I
II
42 55 i I
, , 74 I' i I
47
120 O~ il-,-+1_-;.I'i I '111',i., I
m/z·-> 30 40 50 60 70 80 90 100' , 110 ' ,
tl5undance---~ ~--~Scan 364(7J1TmInf~EC434.IT ---'--'-~----=-==-=------'~
IT~
120 130
, 83
I
'
I,' I,
Raw-', Ii
:JU II
1 47 II
I
ii
40 , i, I I o~~,~t--., li!1 ,I,ll
fn/z--> 30 40 50 60' '7'0 '8'0' , '90 ' ,. 100 110
Abundance:-'-----'-=--~-"'Scan 364 (7.712 min): REC4:r4.D (-)
118
120' 130
83
#32
Chloroform
Concen: 1.36 ug/l
RT: 7.71 min Scan# 364
Delta R.T. 0.03 min
Lab File: REC434.D
Acq: 18 May 2023 5:50 pm
Tgt Ion: 83 Resp: 153415
Ion Ratio Lower Upper
83 100
85 65.6 39.4 99.4
47 25.8 0.0 56.0
bundance on l3'1JU1ff2.70-to-8-TIOYREC434~D­
lion 85.00 (84.70 to 85.70): REC434.D
35000jlOn 47.00 (46.70 to 47.70): REC434.D
I
300001 7.71 I
25000i
20000:
Sub I
50!
: I
i! i
I I 10000:
15000:
II 5000
1
I Iii, JII 118 oi _~Xn __ .'::::~~~
47
/n/z-->_ ~j-b~' ---r-r'4"'o,.,...,..,.l.,.c'5j-b~--'-'6'o"'~~'7"'o~' """"8'o...j.''+'Y'-'-9'-0'" ~, '" 1"O"0"''''-'-1'-10''--rl1ri~~Oi "1To ime--> ' 7.50 7_.~_oi._70 ___ 7._80_~!~_.9~' 0~8-.0~0
Abundance SCai146lJ(9.100 min): RD'C59'3:'D (-)
1H
! !
47 8
1
2 i i :
, II i i
o 41 i, 58 70 Ii! 112 3
"--r-,-4-;'0~~5''o' ~-+6"rO~,..,-j7'o"""· ~8'-0++-'''9''0~T''1''O-0 ~1r-,1"0~' ...J.120 m/z-->
Abundance
Sub'
50
---'.---.,S""can 4'60 (9.114 mlllYREC434.D (-)
11~
47 82
130
#41
pm
Ion:119 Resp: 4360727
Ratio Lower Upper
100
103.5 73.4 133.4
Dunaancelon119.00(118.70to 119.70): REC434
:Ion 117.00 (116.70 to 117.70): REC434
800000:
600000' ,
400000!
\
I
I o~, 42, 5,8 65 72
i, , J 200000
/ , ' 123 01.L . '''---
12~ 130 ime--> 8.80 '9.00' 9.20 100
--------------
9.40 ,m/z--> 40 50 '6'0' 70
'---------110
REC434.D V067D26.M Fri May 19 08:19:43 2023 Page 3
REPORT ID: 23E120 Page 84 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected 05/11/23 10:40
Project TEAD-S Date Received 05116/23
Batch No. 23E120 Date Extracted 05118/23 16: 33
Sample ID S-140-17·052023 Date Analyzed 05118/23 16: 33
Lab Sa!!IP ID 23E120-10N Dilution Factor 1
Lab File ID REC431 Matrix WATER
Ext Btch ID V067E18 % Moisture NA
Calib. Ref. RDC593 Instrument ID 67
RESULTS LOQ DL LOD
PARftMETER(S) (ug/U (ug/L) (ug/U (ug/L)
~ .......................................................... .................. .. ................. ..................... ....................
l,l,l,2-Tetrachloroethane ND 1.0 0.10 0.20
1,1, I-Trichloroethane ND 1.0 0.10 0.20
l,l,2,2-Tetrachloroethane ND 1.0 0.10 0.20
l,l,2-Trichloroethane ND 1.0 0.10 0.20
l,l·Dichloroethane ND 1.0 0.10 0.20
l,l·Dichloroethene ND 1.0 0.10 0.20
l,l·Dichloropropene ND 1.0 0.10 0.20
l,2,3-Trichlorogropane ND 2.0 0.25 0.50
l,2,4-Trichloro enzene ND 1.0 0.15 0.30
l,2·Dibromo-3·chloropropane ND 2.0 0.25 0.50
l,2-Dichlorobenzene ND 1.0 0.10 0.20
l,2-Dichloroethane ND 1.0 0.10 0.20
l,2-Dichlorogro pane ND 1.0 0.10 0.20
l,3·Dichloro enzene ND 1.0 0.10 0.20
l,3.Dichlorogro pane ND 1.0 0.10 0.20
l,4-Dichloro enzene ND 1.0 0.10 0.20
2,2-Dichloro~ro~ane ND 1.0 0.25 0.50
2·Butanone ( EK ND 20 5.0 10
2·Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride 18 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform 2.5 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis·1,2-Dichloroethene ND 1.0 0.10 0.20
CiS'l,3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m,wx~ ene ND 2.0 0.21 0.50
4· et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Meth1l tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n·Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene 0.19J 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1,2·Dichloroethene ND 1.0 0.10 0.20
Trans-1,3·Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
l,2·Dibromoethane ND 1.0 0.10 0.20
l,2,3-Trichlorobenzene ND 1.0 0.15 0.30
1.4· Di oxane ND 100 25 50
SURROGATE PARftMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
...................................................... ............. __ .. ................... ................... ...................
I, 2 -Di ch 1 oroethane· d4 10.3 10.0 103 70-130
4-Bromofluorobenzene 11.1 10.0 111 70-130
Toluene·d8 10.8 10.0 108 70·130
Dibromofluoromethane 10.6 10.0 106 70·130
Notes: Sample Amount : 25ml Final Volume : 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 85 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC431.D
Acq On 18 May 2023 4:33 pm
Sample 23E120-10N
Misc 25mL
(QT Reviewed)
Vial: 24
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 8:22 2023
r~
Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2273932 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1615341 10.00 ug/l 0.00
74) 1,2-DICHLOROBENZENE-D4 19.49 152 434654 10.00 ug/l 0.00
System Monitoring Compounds
36) Dibromofluoromethane 8.21 III 576231 10.63 ug/l 0.02
Spiked Amount 10.000 Recovery 106.3QJv-
43 ) 1,2-Dichloroethane-d4 9.30 65 424879 10.27 ug/l ' 0.02
Spiked Amount 10.000 Recovery 102 r %
56 ) Toluene-d8 12.97 98 2433889 10.84 ug/ 0.00
Spiked Amount 10.000 Recovery 108/% .-, 77 ) 4-Bromofluorobenzene 17.60 95 652995 11.12 ug/ 0.00 -
Spiked Amount 10.000 Recovery 111,/20%
./
i Target Compounds Qvalue
19) Carbon disulfide 4.53 76 31580 0.12 ug/l 96
32) Chloroform 7.71 83 285447 /2.54 ug/l 96
41 ) Carbon tetrachloride 9.11 119 1347776 Yn.73 ug/l 100
63) Tetrachloroethene 14.24 164 10612 0.19 ug/l 98
/
(#) = qualifier out of range (m) = manual integration
REC431.D V067D26.M Fri May 19 08:22:31 2023 Page 1
REPORT ID: 23E120 Page 86 of 560
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI8\REC431.D Vial: 24
Aeq On 18 May 2023 4:33 pm
Sample 23E120-10N
Mise 2SmL
Operator:
Inst
Multiplr:
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: May 19 8:22 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
8000000
7500000j
7000000j
n
i: , I
6500000: !
6000000
i
5500000: i
,
50000001
i
1
45000001
4000000
3500000:
30000001
2500000
2000000
1500000,
1000000;
500000
::;: ,..:
oj
"0
"" :;
<I)
'0
c:
0 -e
'" u
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TrC:REC431.D
(/)
ui z 05
'i' w
N
Z
W
<D
0
Q) c:
Q)
" (5
I-
0:
::;: 0
::J ,..: ...J
oj U.
"0 0 ·c .J..
(/) 9.
oj t: c
'" !!'9 .r:
Q) cQ)
E OC
0 -e~
::;: i5 8~ ,..: " "" 0 r.5 0 :c g E .2 e
.0 9 .E is \"!. e ii~ 9. .r: u
.,;
0
W z w
N z w
<D (/) 0
0: oj
0 c:
Q)
...J N
I c:
U Q) .c e
0
" "" 0
E e
<D
.J.
" 0
W z
W
N
Z
W
'" 0
0:
0
...J
I
U
~
Oc ----. '~-'----r--r' 'r~r-c-~-'~~--------
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 1 foo 1ioo 13.00 14:00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 Time-->
REC431.D V067D26.M Fri May 19 08:22:32 2023 Page 2
REPORT ID: 23E120 Page 87 of 560
~Du-ndance---~~------Scan---r40\4A97 min): RDCS~r3~D\-T~---------1 # 19 - , ro
i
RefOl
49
44 I
I ! Carbon disulfide
84
Coneen: 0.12 ug/l
RT: 4.53 min Sean# 146
Delta R.T. 0.03 min
Lab File: REC431.D
Aeq: 18 May 2023 4:33 pm
0_: ~-C-' " : ,p2 " 6,4, 70 T~_,l~c-,--H--,--r-;8+8-.--;-r~~
m/z--> 30 3'5 40 45 50 55 60 65 70 75 80 8'S 9'0' 95
)lI.bundance----SCanl46\4-:-52TminyREC431.D
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
31580
Upper
Ra!;b.
Sub:
50:
j
40
40 i
0\-,-. ' i 4b 30 35 rn /z -->
~bundance
47
42
44
44
' ,
45
55
7(3
49 67
49 67 ,
I I
50
Ii
6b 6'5
i I 7'5 55 70
Scan 36'3lT.o83 min): RDC!593.D (-)
83
I
I
74
84
84
120
7.5 6.3 11. 7
bundancelOn76.01)175:T0-to 76:TOYREC431.D
lion 78.00 (77.70 to 78.70): REC431.D
70001
6000:
5000;
4000:
i
3000!
2000 1
1000:
#32
Chloroform
4.53
Coneen: 2.54 ug/l
RT: 7.71 min Sean# 364
Delta R.T. 0.03 min
Lab File: REC431.D
Aeq: 18 May 2023 4:33 pm
m/z--> 30 40 50 Tgt Ion: 83 Resp: 285447
,lA.bundance
40 OL-------'-,
m/z--> 30 40
A6-unai3rice
47
50
47
I
i!
70 118 __ ~.~_-'-'-:c-'--_____ _ ...,-'-~~. ------~
60 70 80 90 100 110 120 130
-Scan3041TTrTmln):-RcC4:rm-(=)
8;3
Ion Ratio Lower Upper
83 100
85 65.1 39.4 99.4
47 25.6 0.0 56.0
buridancelarfllT01)lff270-fO-!fJ.TOr REC43TD
70000l'Ion 85.00 (84.70. to 85.70): REC431.D
,Ion 47.00 (46.70 to 47.70): REC431.D
600001
50000:
40000:
30000;
20000
I 10000
7.71
Ot-I ~ ______ 41~~ 70 118 I 0 / --~~-----
m_/z_--? __ l..o.... __ -4:Cl,_ 50 ~_"6_,O-=--=--=-,--j70-80+-4--~90~~ 100~' -11'" 0-~1~013o [ime-::> _ J.'~_7.607.70 7.8o-i908.o-0
REC431.D V067D26.M Fri May 19 08:22:32 2023 Page 3
REPORT ID: 23E120 Page 88 of 560
RefOi
47 82
i i , ,
I:
#41
Carbon tetrachloride
Concen: 17.73 ug/l
RT: 9.11 min Scan# 460
Delta R.T. 0.02 min
Lab File: REC431.D
Acq: 18 May 2023 4:33 pm
i 0~~4~2-,--,'~~-+59 70 ,~~~~~~~~, ~~~~~~
m/z--> 30 40 50 60 7'0 80 90 100 110 120 130 Tgt Ion:119 Resp: 1347776
Ion Ratio Lower Upper
119 100
lA.bundance--~Scan 460 (9.11 OffiinyREC43l:D
!
Ra'5bi
I
Sub:
50
oL.
m/z--> 30
41
40
47
47
,
!
i i
50
82
82
I I
70 I I
I I
7'0 80 9'0 100
58
110
j I
111
, I
i i
I I
i I
, I
, I
iJ23
120
"-r
130
---~----
, !
129 I!
I! [;
iii II
47 I II, '[ i
59 I: ! II
" 82 t' ',,', I! 'I, I I , ! i [: I' O~~_~,,_J~!O i ,I; , ~17 [I, " " ,4l.1-,-~
,m/z--> 40 50 60 70 80 90 100 110 120 130 140 150 160 170
RefOj 94
,
A5undance-~------Scan 811 (14.244 min): REC'f3T:D
166
129
94
44 : : ~
: ,:
59
82
m/z-->
117 103.8 73.4 133.4
bundancelonIT9-'-()0\I11f.70 -fo H97U):REC431
ilon 117.00 (116.70 to 117.70): REC431
250000j 9.,11 ,
i
200000j
,
\
150000j \ i
\ 1000001 \
ime--> 8.80 9.00 9.20
#63
Tetrachloroethene
9.40
Concen: 0.19 ug/l
RT: 14.24 min Scan# 811
Delta R.T. 0.00 min
Lab File: REC431.D
Acq: 18 May 2023 4:33 pm
Tgt Ion:164 Resp: 10612
-j Ion Ratio Lower Upper
164 100
166 125.7 97.7 157.7
129 84.2 56.9 116.9
131 82.0 52.5 112.5
bundancelOr1104Jra(r6:r.70-fof64~7()): REC431
:Ion 166.00 (165.70 to 166.70): REC431
6000ilon 129.00 (128.70 to 129.70): REC431
Ion 131.00 (130.70 to 131.70): REC431
4000
14.24
3000:
2000
REC431.D V067D26.M Fri May 19 08:22:33 2023 Page 4
REPORT ID: 23E120 Page 89 of 560
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/09/23 11: 35
Project TEAD-S Date Received: 05/16123
Batch No. 23E120 Date Extracted: 05118/23 16:58
Sample ID S-142-17-052023 Date Analyzed: 05118123 16: 58
Lab Sa!!1P ID 23El20-11N Dilution Factor: 1
Lab File ID REC432 Matrix: WATER
Ext Btch ID V067El8 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/L) (ug/U (ug/L) (ug/L)
..... _-_ ...... _--_ .......................... .. ............... ..... --........... ................. ........... __ .....
1.1.1.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachl oroethane ND 1.0 0.10 0.20
1.1.2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1. 2. 3-Trichlorogropane ND 2_0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0_10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0_20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0_15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide 0.29J 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0_25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
Cis-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISoprO~YlbenzeAe ND 1.0 0.10 0.20
m'W£f; ene ND 2_0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methtl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Bu ylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1. 2. 3-Trichlorobenzene ND 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK_AMT %RECOVERY QC LIMIT
............................. _ ................. --.............. __ .. ____ a ......... ------" ........ --------_ .. -
1.2-Dichloroethane-d4 10.7 10.0 107 70-130
4-Bromofluorobenzene 10.8 10.0 108 70-130
Toluene-d8 10.7 10.0 107 70-130
Dibromofluoromethane 10.8 10.0 108 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 90 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC432.D
Acq On 18 May 2023 4:58 pm
Sample 23E120-11N
Misc 25mL
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 25
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Time: May 19 8:22 2023 ~~ Quant Results File: V067D26.RES
Quant Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
DataAcq Meth V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1 t 4-DIFLUOROBENZENE 10.15 114 2277081 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1624955 10.00 ug/l 0.00
74) 1 t 2-DICHLOROBENZENE-D4 19.49 152 446034 10.00 ug/l 0.00
c\ System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 584843 10.78 ug/l 0.02
Spiked Amount 10.000 Recovery 107.80%
43 ) 1 t 2-Dichloroethane-d4 9.30 65 441505 10.65 ug/l ,/'ll.02
Spiked Amount 10.000 Recovery 106.50%
56) Toluene-d8 12.97 98 2421143 10.72 ug/l ...--0.00
Spiked Amount 10.000 Recovery 107.20%
77 ) 4-Bromofluorobenzene 17.62 95 648661 10.77 ug/V 0.02
Spiked Amount 10.000 Recovery 10/70%
Target Compounds Qvalue
19 ) Carbon disulfide 4.53 76 75552 O.~ ug/l 99
(#) = qualifier out of range (m) = manual integration
REC432.D V067D26.M Fri May 19 08:22:52 2023 Page 1
REPORT ID: 23E120 Page 91 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC432.D
Aeq On 18 May 2023 4:58 pm
Sample 23E120-11N
Mise 25mL
Vial: 25
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 19 8:22 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance .
;
8000000!
I
i
7500000,
7000000,
6500000i
60000001
i'
i i
Ii
5500000 1 I i
5000000'
4500000: '
4000000: '
3500000i
3000000
25000001 :
I
2000000
1500000·
1000000
500000:
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TrC:REC432~D-----------
.n
0
ui
(/) W oi z z ~ w
W N N e Z Z '" w
W ::l W
W (5 0 0 f0-0:: 0:: 0 0 -' => I
-' u.. U
is
(/) ":.
<Ii (/)
e " '" ~ .r=
Q; e E '" e .r=
0 Q;
::l § <= 0 ~ :c
" is .0 ~ is
(/)
<Ii e
'" N e
'" .0 e
0
::l <= 0
E e
W
..t
" 0
W
Z
W
N
Z w
CO
0
0:
0
-' I u
is
~
l\ I[
Time--> O~lb 3.00 4.00 5.00 6.00 7.008.b~' 9.0~:' 10:~o11:00 1i001~:OO 14:0015:0016:00 17.00 '18.00 19.0020.0021.00
REC432.D V067D26.M Fri May 19 08:22:53 2023 Page 2
REPORT ID: 23E120 Page 92 of 560
~bundance --SCanl40{4.497 min): RDTI59:r:Dl=)-------# 19
,
i
RefOi
,
i ! . 49
84
44
I ' 'i i 88
i Oj~-'-'-r-r, 'l,--r-+,-,-++c-r-+, R_2", "I~'~' n, ,-,-,-;64CTI~' ~7nl0..,-~,-i-i +-"7,9,--, ".,-, ,,' ,-+<' '-\'T~ ~~-> ~ ~ ~ ~ ~ ~ 00 ~ ro ~ 00 ~ 00 ~
Abundance Scan 146l4.527 min): REC432~.D..-=-:c-=-=--
7p
44
40 49 67 84
m/z--> ~b' 3'5' 4'0 ~ 4'5' 50 5'5 6'0' 6'5 7'0 75 80' ~15 90 9'5
Abundance-Scan 146l4.527 min): REC432.Dln-).-----~--1
Sub
50
76
Carbon disulfide
Concen: 0.29 ug/l
RT: 4.53 min Scan# 146
Delta R.T. 0.03 min
Lab File: REC432.D
Acq: 18 May 2023 4:58 pm
Tgt
Ion
76
78
Ion: 76 Resp:
Ratio Lower
100
9.3 6.3
75552
Upper
11. 7
bundancel0nf6]ro-(75.7(fto76~70):REC432.D
16000jlon 78.00 (77.70 to 78.70): REC432.D
:
14000:
12000J
10000!
8000i
6000!
i
4000:
4.53
49 I
2000
1
! I 44 67 I 84 L!m:c::/z=----_>_0-=-3b=-~' __ '_=3~c:c5~_'-"4_"0~~~4:'5~'_-:~1:0==5='5=' ==6='0=' :6:S=' ::7"'o==7='5:
h
'_ --=8:'0==8:'5:' ='-=9-=-'0_9=-:'5=--~ime--> 0 ~.30 4.40 4.50~ 4~~-~.~~ 4.80 4.90
REC432.D V067D26.M Fri May 19 08:22:54 2023 Page 3
REPORT ID: 23E120 Page 93 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client : BRICE Date Collected: 05/09/23 07:30
Project : TEAD-S Date Received: 05/16/23
Batch No. : 23E120 Date Extracted: 05/17/23 11: 24
Sample 10 : TB-20230509-1/25 Date Analyzed: 05/17/23 11: 24
Lab Samp 10: 23E120-12 Dilution Factor: 1
Lab File 10: REC390 Matrix: WATER
Ext Btch 10: V067E17 % Moisture: NA
Calib. Ref.: RDC593 Instrument 10: 67
RESULTS LOO OL LOD
PARAMETER(S} (ug/L) (ug/L) (ug/l) (ug/l)
.... _---........ _-_ ........... _-_ .......... .. .... _ .......... _ .. ...................... ...... " ..... " .... ....................
1. 1. 1.2-Tetrachloroethane NO 1.0 0.10 0.20
1.1. I-Trichloroethane NO 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane NO 1.0 0.10 0.20
1. 1. 2-Trichloroethane NO 1.0 0.10 0.20
1.1-0ichloroethane NO 1.0 0.10 0.20
1.1-0ichloroethene NO 1.0 0.10 0.20
1.1-0ichloropropene NO 1.0 0.10 0.20
1. 2. 3-Trichlorgcropane NO 2.0 0.25 0.50
1.2.4-Trichloro enzene NO 1.0 0.15 0.30
1.2-0ibromo·3-chloropropane NO 2.0 0.25 0.50
1.2-0ichlorobenzene NO 1.0 0.10 0.20
1.2-0ichloroethane NO 1.0 0.10 0.20
1.2-0ichlorogropane NO 1.0 0.10 0.20
1.3-0ichloro enzene NO 1.0 0.10 0.20
1.3-0ichlorogropane NO 1.0 0.10 0.20
1.4-0ichloro enzene NO 1.0 0.10 0.20
2.2-0ichloro~ro~ane NO 1.0 0.25 0.50
2-Butanone ( EK NO 20 5.0 10
2-Chlorotoluene NO 1.0 0.25 0.50
2-Hexanone NO 20 5.0 10
4-Chlorotoluene NO 1.0 0.25 0.50
Acetone NO 20 5.0 10
Benzene NO 1.0 0.10 0.20
Bromobenzene NO 1.0 0.10 0.20
Bromochloromethane NO 1.0 0.15 0.30
Bromodichloromethane NO 1.0 0.10 0.20
Bromoform NO 1.0 0.15 0.30
Bromomethane NO 1.0 0.25 0.50
Carbon Disulfide NO 1.0 0.25 0.50
Carbon Tetrachloride NO 1.0 0.10 0.20
Chlorobenzene NO 1.0 0.10 0.20
Chloroethane NO 2.0 0.50 1.0
Chloroform NO 1.0 0.10 0.20
Chloromethane NO 1.0 0.25 0.50
cis-1.2-0ichloroethene NO 1.0 0.10 0.20
CiS-1.3-0ichloro~ropene NO 1.0 0.10 0.20
Oibromochloromet ane NO 1.0 0.10 0.20
Oibromomethane NO 1.0 0.10 0.20
Oichlorodifluoromethane NO 1.0 0.25 0.50
Ethyl benzene NO 1.0 0.10 0.20
ISOprO~YlbenZene NO 1.0 0.10 0.20
mtxf: ene NO 2.0 0.21 0.50
4-et Yl-2-Pentanone NO 10 2.5 5.0
Methylene Chloride NO 2.0 0.50 1.0
Methtl tert-butyl ether (MTBE) NO 1.0 0.15 0.30
n-Bu ylbenzene NO 1.0 0.25 0.50
n-Propylbenzene NO 1.0 0.25 0.50
o-Xylene NO 1.0 0.10 0.20
~-Isopro~bltoluene NO 1.0 0.25 0.50
ec-Buty enzene NO 1.0 0.25 0.50
Styrene NO 1.0 0.25 0.50
Tert-Butylbenzene NO 1.0 0.25 0.50
Tetrachloroethene NO 1.0 0.15 0.30
Toluene NO 1.0 0.10 0.20
Trans-1.2-0ichloroethene NO 1.0 0.10 0.20
Trans-1.3·0ichloropropene NO 1.0 0.25 0.50
Trichloroethene NO 1.0 0.10 0.20
Trichlorofluoromethane NO 1.0 0.25 0.50
Vinyl Chloride NO 1.0 0.11 0.30
1.2-0ibromoethane NO 1.0 0.10 0.20
1.2.3-Trichlorobenzene NO 1.0 0.15 0.30
1.4 -Oi oxane NO 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
................ _ ................................... -................... .................... .... --............ -........ _ ...........
1.2-0ichloroethane-d4 10.0 10.0 100 70-130
4-Bromofluorobenzene 10.9 10.0 109 70-130
Toluene-d8 10_9 10.0 109 70-130
Oibromofluoromethane 10.5 10.0 105 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 94 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC390.D
Acq On 17 May 2023 11:24 am
Sample 23E120-12
Misc 25mL
(QT Reviewed)
Vial: 12
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14: 33: 42 2023 ~.
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2179707 10.00 ug/l 0.01
55 ) CHLOROBENZENE-D5 15.60 117 1525349 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 406102 10.00 ug/l 0.00
1,
System Monitoring Compounds
'~. 36) Dibromofluoromethane 8.21 111 547147 10.53 ug/l 0.01
Spiked Amount 10.000 Recovery 105.30%
43 ) l,2-Dichloroethane-d4 9.30 65 398114 10.04 ug/l~ 0.01
Spiked Amount 10.000 Recovery 100.40%
56 ) Toluene-d8 12.97 98 2315840 10.92 ug/~ 0.00
Spiked Amount 10.000 Recovery 109t O%
77 ) 4-Bromofluorobenzene 17.60 95 597547 10.89 ugj 0.00
Spiked Amount 10.000 Recovery 10§/.90%
. Target Compounds Qvalue
20) Methylene chloride 4.54 49 11050 0.11 ug/l 95
0/'
(#) = qualifier out of range (m) = manual integration
REC390.D V067D26.M Thu May 18 08:29:19 2023 Page 1
REPORT ID: 23E120 Page 95 of 560
Data File
Aeq On
Sample
Mise
Quantitation Report
D:\HPCHEM\I\DATA\23EI7\REC390.D
17 May 2023 11:24 am
23E120-12
25mL
Vial: 12
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:29 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
i
75000001
i :
7000000
65000001:
II
6000000; !
I
55000001
I
5000000·
4500000] °
4000000]
3500000
3000000
2500000
2000000
1500000, •
1000000
500000'
::;;
~ .,;
" 0C:
0
£
Q) c: ~ >-~ ::;;
D:\HPCHEM\I\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TlC:RE390.D
C/l
W «i
"% z w c: N Q) Z " W 0 C!l f-0 a:
0
::::l
...J u.
is
C/l
....
.,; C/l c: .j '" ,:; "% Q)
E c:
'" e ,:;
0 Q)
" e <= 0 52 E ti e Ci £! N. 0
(RTE Integrator)
.,.;
0
W z .j w 0 N W Z
W Z
C!l W
0 C/l N
a: .,; z
0 c: w
Q) C!l ...J N
I c: 0
U Q) a: .c 0 e ...J
0 I " U <= 0 is E N. e
C!l ...
Time--> O2 .00 <3.00 . 4.00 5.006.007.00 8.00 9.00 10.00 11.00 12.00 13:0014:00 15:00 16.00 17.00 18.00 19.0020.00 21.00
------------------~~--------~~-------------------- -----------------
REC390.D V067D26.M Thu May 18 08:29:20 2023 Page 2
REPORT ID: 23E120 Page 96 of 560
Re~i
-Scan-1,fHl:-5T2mIfl):RD-C59TD-Ff-------------1
7~ i
I I
49 I !
'84 I
Abundance
; '88 i
; , I I
I ",.~,..,,-,--1
859095i
i
49
i Ra~1 84
, 76 I
40
! I i
mlz--> ~o 3'5 4'0 415 5'0 55 SO 65' ib 715 80' 8'5 90 ~
Abundance SCanT47 (4.541 min): REC390-nT-;"::----=-==-----=-=-----':":-""---1
4,9
84
Sub
50,
i
I
I
76 i I
1 40 1 I O~ I I,:
5'5 6b
i I
7b 'I ' I
8
1
5
i I i, ,
!:J:1I.~lQ...~ 40 45 50 65 75 80 90 95 ----
#20
Methylene chloride
Concen: 0.11 ug/l
RT: 4.54 min Scan# 147
Delta R.T. 0.03 min
Lab File: REC390.D
Acq: 17 May 2023 11:24 am
Tgt Ion: 49 Resp: 11050
Ion
49
84
86
2500]
I
1
20001
1500J
Ratio
100
66.9
43.3
Lower Upper
41. 7 101.7
15.7 75.7
4.54
REC390.D V067D26.M Thu May 18 08:29:21 2023 Page 3
REPORT ID: 23E120 Page 97 of 560
QC SUMMARIES
REPORT ID: 23E120 Page 98 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Co 11 ected: 05/17/23 08: 50
Project TEAD-S Date Received: 05/17/23
Batch No. 23E120 Date Extracted: 05/17/23 08:50
Sample ID MBLK1W Date Analyzed: 05/17/23 08:50
Lab Samp ID V067E17B Dilution Factor: 1
Lab File ID REC384 Matrix: WATER
Ext Btch ID V067E17 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/l) (ug/l)
.. _-_ ......... _ ............................. ................. • ...... a __ .... __ -_ ......... __ .... ........ __ .....
1. 1. 1.2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane ND 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3·chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOpro~Ylbenzene ND 1.0 0.10 0.20
m'~-£f; ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~&ltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4 -Di oxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
.................. _-_ .......... __ .---_ .... .-----_.-.. -.. · __ .a.""· ____ a. __ ·· . -_._-_ .........
1.2-Dichloroethane-d4 10.0 10.0 100 70-130
4-Bromofluorobenzene 11.1 10.0 111 70-130
Toluene-d8 11.0 10.0 110 70-130
Dibromofluoromethane 10.5 10.0 105 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 99 of 560
EMAX QUALITY CONTROL DATA
LAB CONTROL S.AMPLE ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E120
METHOD SW5030B/8260C
MATRIX : WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
S.AMPLE ID : MBLK1W LCS1W LC01W
LAB S.AMPLE ID : V067E17B V067E17L V067E17C
LAB FILE ID : REC384 REC381 REC382
DATE PREPARED : 05117/23 08:50 05/17/23 07:33 05/17/23 07:59
DATE ANALYZED : 05117123 08:50 05/17/23 07:33 05/17123 07:59
PREP BATCH : V067E17 V067E17 V067E17
CALIBRATION REF: RDC593 RDC593 RDC593
ACCESSION:
MBResult SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCORec RPO QCLimit MaxRPO
PAR.AMETERS (ug/L) (ug/l) (ug/l) (%) (ug/l) (ug/l) (%) (%) (%) (%)
...... _-... __ ....... _ ........ _-...... _ ... _____ a ____ . _ .... -.. _ .. -................ ---_._ .. --_ ......... ..... -...... ___ a ... •• ..
1.1.1.2-Tetrachloroethane NO 10.0 11.7 117 10.0 11.7 117 0 78-124 20
1.1. I-Trichloroethane NO 10.0 10.7 107 10.0 10.9 109 2 74-131 20
1. 1. 2. 2-Tetrachloroethane NO 10.0 10.8 108 10.0 11.3 113 5 71-121 20
1. 1. 2-Trichloroethane NO 10.0 11.1 111 10.0 11.2 112 1 80-119 20
1.1-0ichloroethane NO 10.0 10.4 104 10.0 10.6 106 2 77-125 20
1.1-0ichloroethene NO 10.0 10.1 101 10.0 10.5 105 4 71-131 20
1.1-0ichloropropene NO 10.0 9.75 98 10.0 9.99 100 2 79-125 20
1.2.3-Trichlorogropane NO 10.0 10.5 105 10.0 11.1 111 6 73-122 20
1.2.4-Trichloro enzene NO 10.0 11.0 110 10.0 11.3 113 3 69-130 20
1.2-0ibromo-3-chloropropane NO 10.0 10.2 102 10.0 10.5 105 3 62-128 20
1.2 -Oi ch 1 orobenzene NO 10.0 10.5 105 10.0 10.6 106 1 80-119 20
1.2-0ichloroethane NO 10.0 10.1 101 10.0 10.3 103 2 73-128 20
1.2-0ichlorogropane NO 10.0 10.6 106 10.0 10.9 109 3 78-122 20
1.3-0ichloro enzene NO 10.0 10.6 106 10.0 10.7 107 1 80-119 20
1.3-0ichlorogropane NO 10.0 10.7 107 10.0 11.1 111 4 80-119 20
1.4-0ichloro enzene NO 10.0 10.5 105 10.0 10.7 107 2 79-118 20
2.2-0ichloro~ro~ane NO 10.0 11.5 115 10.0 11.4 114 1 60-139 20
2-Butanone ( EK NO 50.0 50.8 102 50.0 53.1 106 4 56-143 20
2-Chlorotoluene NO 10.0 10.4 104 10.0 10.6 106 2 79-122 20
2-Hexanone NO 50.0 48.9 98 50.0 52.2 104 7 57-139 20
4-Chlorotoluene NO 10.0 10.2 102 10.0 10.4 104 2 78-122 20
Acetone NO 50.0 54.6 109 50.0 57.4 115 5 39-160 20
Benzene NO 10.0 10.6 106 10.0 10.7 107 1 79-120 20
Bromobenzene NO 10.0 10.7 107 10.0 11.0 110 3 80-120 20
Bromochloromethane NO 10.0 10.5 105 10.0 10.7 107 2 78-123 20
Bromodichloromethane NO 10.0 10.6 106 10.0 10.9 109 3 79-125 20
Bromoform NO 10.0 9.85 99 10.0 10.1 101 3 66-130 20
Bromomethane NO 10.0 11.5 115 10.0 10.3 103 11 53-141 20
Carbon Disulfide NO 10.0 11.8 118 10.0 10.8 108 9 64-133 20
Carbon Tetrachloride NO 10.0 10.7 107 10.0 10.9 109 2 72-136 20
Chlorobenzene NO 10.0 10.8 108 10.0 10.7 107 1 82-118 20
Chloroethane NO 10.0 11.4 114 10.0 10.6 106 7 60-138 20
Chloroform NO 10.0 11.0 110 10.0 11.0 110 0 79-124 20
Chloromethane NO 10.0 9.80 98 10.0 8.63 86 13 50-139 20
cis-1.2-0ichloroethene NO 10.0 10.6 106 10.0 10.8 108 2 78-123 20
CiS-1.3-0ichloro~ropene NO 10.0 10.6 106 10.0 11.0 110 4 75-124 20
Oibromochloromet ane NO 10.0 10.7 107 10.0 10.8 108 1 74-126 20
Oibromomethane NO 10.0 10.4 104 10.0 10.6 106 2 79-123 20
Oichlorodifluoromethane NO 10.0 10.6 106 10.0 10.1 101 5 32-152 20
Ethyl benzene NO 10.0 11.0 110 10.0 11.0 110 0 79-121 20
ISOprO~Ylbenzene NO 10.0 11.3 113 10.0 11.5 115 2 72-131 20
m,~-xh ene NO 20.0 22.3 112 20.0 22.3 112 0 80-121 20
4-et Yl-2-Pentanone NO 50.0 46.8 94 50.0 50.2 100 7 67-130 20
Methylene Chloride NO 10.0 9.61 96 10.0 9.72 97 1 74-124 20
Meth{l tert-butyl ether (MTBE) NO 10.0 10.4 104 10.0 10.8 108 4 71-124 20
n-Bu ylbenzene NO 10.0 10.8 108 10.0 10.6 106 2 75-128 20
n-Propylbenzene NO 10.0 11.0 110 10.0 11.2 112 2 76-126 20
o-Xylene NO 10.0 11.3 113 10.0 11.4 114 1 78-122 20
~-Isopro~bltoluene NO 10.0 11.0 110 10.0 11.1 111 1 77-127 20
ec-Buty enzene NO 10.0 11.3 113 10.0 11.6 116 3 77-126 20
Styrene NO 10.0 9.93 99 10.0 10.2 102 3 78-123 20
Tert-Butylbenzene NO 10.0 11.3 113 10.0 11.3 113 0 78-124 20
Tetrachloroethene NO 10.0 10.8 108 10.0 10.8 108 0 74-129 20
Toluene NO 10.0 10.8 108 10.0 11.0 110 2 80-121 20
Trans-1.2-0ichloroethene NO 10.0 10.3 103 10.0 10.4 104 1 75-124 20
Trans-1.3-0ichloropropene NO 10.0 10.7 107 10.0 10.9 109 2 73-127 20
Trichloroethene NO 10.0 10.2 102 10.0 10.2 102 0 79-123 20
Trichlorofluoromethane NO 10.0 12.0 120 10.0 10.2 102 16 65-141 20
Vinyl Chloride NO 10.0 10.7 107 10.0 9.75 98 9 58-137 20
1.2-0ibromoethane NO 10.0 10.7 107 10.0 10.9 109 2 77-121 20
1. 2. 3-Trichlorobenzene NO 10.0 10.8 108 10.0 11.6 116 7 69-129 20
1.4 -Oi oxane NO 200 194 97 200 210 105 8 59-139 20
SpikeAmt LCSResult LCSRec SpikeAmt LCOResult LCDRec QCLimit
SURROGATE PAR.AMETERS (ug/l) (ug/L) (%) (ug/L) (ug/l) (%) (%)
........ a ........................................ • ..... __ ........ .............. . .... _-_ ... ... -........ . ........ __ ......
1.2-0ichloroethane-d4 10.0 10.3 103 10.0 10.6 106 70-130
4-Bromofluorobenzene 10.0 10.1 101 10.0 10.4 104 70-130
Toluene-d8 10.0 10.8 108 10.0 10.7 107 70-130
Oibromofluoromethane 10.0 10.8 108 10.0 11.0 110 70-130
MB: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
REPORT ID: 23E120 Page 100 of 560
METHOD SWS030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE Date Collected: 05/18123 08:50
Project TEAD-S Date Received: 05/18/23
Batch No. 23E120 Date Extracted: 05/18/23 08:50
Sample ID MBLK2W Date Analyzed: 05/18/23 08:50
Lab Samp ID V067E18B Dilution Factor: 1
Lab File ID REC413 Matrix: WATER
Ext Btch ID V067E18 % Moisture: NA
Calib. Ref. RDC593 Instrument ID: 67
RESULTS LOQ DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/l) (ug/L)
____ a _________________ •• ____ ·_ ___ .a .• ____ .----.. -._. _._-_. __ ._. -_ ... _-----
1.1.1.2-Tetrachloroethane ND 1.0 0.10 0.20
1.1. I-Trichloroethane ND 1.0 0.10 0.20
1. 1. 2. 2-Tetrachloroethane NO 1.0 0.10 0.20
1. 1. 2-Trichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethane ND 1.0 0.10 0.20
1.1-Dichloroethene ND 1.0 0.10 0.20
1.1-Dichloropropene ND 1.0 0.10 0.20
1.2.3-Trichlorogropane ND 2.0 0.25 0.50
1.2.4-Trichloro enzene ND 1.0 0.15 0.30
1.2-Dibromo-3-chloropropane ND 2.0 0.25 0.50
1.2-Dichlorobenzene ND 1.0 0.10 0.20
1.2-Dichloroethane ND 1.0 0.10 0.20
1.2-Dichlorogropane ND 1.0 0.10 0.20
1.3-Dichloro enzene ND 1.0 0.10 0.20
1.3-Dichlorogropane ND 1.0 0.10 0.20
1.4-Dichloro enzene ND 1.0 0.10 0.20
2.2-Dichloro~ro~ane ND 1.0 0.25 0.50
2-Butanone ( EK ND 20 5.0 10
2-Chlorotoluene ND 1.0 0.25 0.50
2-Hexanone ND 20 5.0 10
4-Chlorotoluene ND 1.0 0.25 0.50
Acetone ND 20 5.0 10
Benzene ND 1.0 0.10 0.20
Bromobenzene ND 1.0 0.10 0.20
Bromochloromethane ND 1.0 0.15 0.30
Bromodichloromethane ND 1.0 0.10 0.20
Bromoform ND 1.0 0.15 0.30
Bromomethane ND 1.0 0.25 0.50
Carbon Disulfide ND 1.0 0.25 0.50
Carbon Tetrachloride ND 1.0 0.10 0.20
Chlorobenzene ND 1.0 0.10 0.20
Chloroethane ND 2.0 0.50 1.0
Chloroform ND 1.0 0.10 0.20
Chloromethane ND 1.0 0.25 0.50
cis-1.2-Dichloroethene ND 1.0 0.10 0.20
CiS-1.3-Dichloro~ropene ND 1.0 0.10 0.20
Dibromochloromet ane ND 1.0 0.10 0.20
Dibromomethane ND 1.0 0.10 0.20
Dichlorodifluoromethane ND 1.0 0.25 0.50
Ethyl benzene ND 1.0 0.10 0.20
ISOprO~Ylbenzene ND 1.0 0.10 0.20
m,~-xh ene ND 2.0 0.21 0.50
4-et yl-2-Pentanone ND 10 2.5 5.0
Methylene Chloride ND 2.0 0.50 1.0
Methyl tert-butyl ether (MTBE) ND 1.0 0.15 0.30
n-Butylbenzene ND 1.0 0.25 0.50
n-Propylbenzene ND 1.0 0.25 0.50
o-Xylene ND 1.0 0.10 0.20
~-Isopro~bltoluene ND 1.0 0.25 0.50
ec-Buty enzene ND 1.0 0.25 0.50
Styrene ND 1.0 0.25 0.50
Tert-Butylbenzene ND 1.0 0.25 0.50
Tetrachloroethene ND 1.0 0.15 0.30
Toluene ND 1.0 0.10 0.20
Trans-1.2-Dichloroethene ND 1.0 0.10 0.20
Trans-1.3-Dichloropropene ND 1.0 0.25 0.50
Trichloroethene ND 1.0 0.10 0.20
Trichlorofluoromethane ND 1.0 0.25 0.50
Vinyl Chloride ND 1.0 0.11 0.30
1.2-Dibromoethane ND 1.0 0.10 0.20
1.2.3-Trichlorobenzene ND 1.0 0.15 0.30
1.4-Dioxane ND 100 25 50
SURROGATE PARAMETER(S) RESULT SPK AMT %RECOVERY QC LIMIT
._ ................... -----_.-----_ .... ---... _a ....... .... ---_._ . ._-----_._-
1.2-Dichloroethane-d4 10.0 10.0 100 70-130
4-Bromofluorobenzene 11.2 10.0 112 70-130
Toluene-d8 10.9 10.0 109 70-130
Dibromofluoromethane 10.5 10.0 105 70-130
Notes: Sample Amount : 25ml Final Volume: 25ml
Prepared b, : VLu Analyzed by : VLu Detection imits are reported relative to sample result significant figures.
REPORT ID: 23E120 Page 101 of 560
EMAXJlUALITY CONTROL DATA LAB C TROL SAMPLE ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E120
METHOD SWS030B/B260C
MATRIX : WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID : MBLK2W LCS2W LCD2W
LAB SAMPLE ID : V067E1BB V067E18L V067E18C
LAB FILE ID : REC413 REC410 REC411
DATE PREPARED : 05/18/23 08:50 05118/23 07: 34 05/18/23 07:59
DATE ANALYZED : 05/18/23 08:50 05/18/23 07:34 05/18/23 07:59
PREP BATCH : V067E18 V067E18 V067E18
CALIBRATION REF: RDC593 RDC593 RDC593
ACCESSION:
MBResult SpikeArnt LCSResult LCSRec SpikeArnt LCDResult LCDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/U (ug/L) (%) (ug/L) (ug/U (%) (%) (%) (%)
........................ _ ........................... ............. -.................... ................... ............... -_ ............ ................. .. ................
1.1.1.2-Tetrachloroethane ND 10.0 10.8 108 10.0 11.4 114 5 78-124 20
1. 1. I-Trichloroethane ND 10.0 10.3 103 10.0 10.7 107 4 74-131 20
1. 1. 2. 2-Tetrachloroethane ND 10.0 10.3 103 10.0 10.6 106 3 71-121 20
1.1.2-Trichloroethane ND 10.0 10.2 102 10.0 10.7 107 5 80-119 20
1.1-Dichloroethane ND 10.0 10.0 100 10.0 10.4 104 4 77-125 20
1.1-Dichloroethene ND 10.0 9.56 96 10.0 9.92 99 4 71-131 20
1.1-Dichloropropene ND 10.0 9.40 94 10.0 9.72 97 3 79-125 20
1.2.3-Trichlorocropane ND 10.0 9.88 99 10.0 10.1 101 2 73-122 20
1.2.4-Trichloro enzene NO 10.0 10.9 109 10.0 11.0 110 1 69-130 20
1.2 -Dibromo-3-chl oropropane ND 10.0 9.55 96 10.0 10.1 101 6 62-128 20
1.2-Dichlorobenzene ND 10.0 9.99 100 10.0 10.3 103 3 80-119 20
1.2-Dichloroethane ND 10.0 9.59 96 10.0 9.82 98 2 73-128 20
1.2-Dichlorocropane ND 10.0 10.1 101 10.0 10.5 105 4 78-122 20
1.3-Dichloro enzene NO 10.0 10.1 101 10.0 10.3 103 2 80-119 20
1.3-Dichlorocropane ND 10.0 9.99 100 10.0 10.5 105 5 80-119 20
1.4-Dichloro enzene ND 10.0 10.0 100 10.0 10.3 103 3 79-118 20
2.2-Dichloro~ro~ane ND 10.0 11.0 110 10.0 11.1 111 1 60-139 20
2-Butanone ( EK ND 50.0 49.6 99 50.0 49.7 99 0 56-143 20
2-Chlorotoluene ND 10.0 9.70 97 10.0 10.1 101 4 79-122 20
2-Hexanone ND 50.0 48_3 97 50.0 50.0 100 3 57-139 20
4-Chlorotoluene ND 10.0 10.3 103 10.0 10.5 105 2 78-122 20
Acetone ND 50.0 54.0 108 50.0 55.3 111 2 39-160 20
Benzene ND 10.0 10.1 101 10.0 10.4 104 3 79-120 20
Bromobenzene ND 10.0 10.1 101 10.0 10.5 105 4 80-120 20
Bromochloromethane ND 10.0 9.91 99 10.0 10.2 102 3 78-123 20
Bromodichloromethane ND 10.0 10.3 103 10.0 10.6 106 3 79-125 20
Bromoform ND 10.0 9.40 94 10.0 9.58 96 2 66-130 20
Bromomethane ND 10.0 9.32 93 10.0 9.04 90 3 53-141 20
Carbon Disulfide ND 10.0 10.2 102 10.0 9.75 98 5 64-133 20
Carbon Tetrachloride ND 10.0 10.1 101 10.0 10.5 105 4 72-136 20
Chlorobenzene ND 10.0 10.1 101 10.0 10.6 106 5 82-118 20
Chloroethane ND 10.0 9.50 95 10.0 9.28 93 2 60-138 20
Chloroform NO 10.0 10.4 104 10.0 10.7 107 3 79-124 20
Chloromethane ND 10.0 7.45 75 10.0 7.12 71 5 50-139 20
cis-1.2-Dichloroethene ND 10.0 10.1 101 10.0 10.4 104 3 78-123 20
CiS-1.3-Dichloro~ropene ND 10.0 10.0 100 10.0 10.4 104 4 75-124 20
Dibromochloromet ane ND 10.0 9.82 98 10.0 10.4 104 6 74-126 20
Dibromomethane NO 10.0 9.65 97 10.0 10.1 101 5 79-123 20
Dichlorodifluoromethane ND 10.0 9.73 97 10.0 9.13 91 6 32-152 20
Ethyl benzene ND 10.0 10.4 104 10.0 10.8 108 4 79-121 20
ISOprO~Ylbenzene ND 10.0 10.7 107 10.0 11.3 113 5 72-131 20
m,~-xh ene ND 20.0 21.1 106 20.0 22.2 111 5 80-121 20
4-et yl-2-Pentanone ND 50.0 46.8 94 50.0 48.4 97 3 67-130 20
Methylene Chloride ND 10.0 9.07 91 10.0 9.30 93 3 74-124 20
Met~l tert-butyl ether (MTBE) ND 10.0 9.87 99 10.0 10.1 101 2 71-124 20
n-Bu ylbenzene ND 10.0 10.6 106 10.0 10.8 108 2 75-128 20
n-Propylbenzene ND 10.0 10.7 107 10.0 11.0 110 3 76-126 20
o-Xylene ND 10.0 10.8 108 10.0 11.3 113 5 78-122 20
~-Isopro~bltoluene ND 10.0 10.9 109 10.0 11.0 110 1 77-127 20
ec-Buty enzene ND 10.0 11.2 112 10.0 11.4 114 2 77-126 20
Styrene ND 10.0 9.39 94 10.0 9.92 99 5 78-123 20
Tert-Butylbenzene ND 10.0 11.0 110 10.0 11.3 113 3 78-124 20
Tetrachloroethene ND 10.0 10.2 102 10.0 10.7 107 5 74-129 20
Toluene NO 10.0 10.3 103 10.0 10.9 109 6 80-121 20
Trans-1.2-Dichloroethene ND 10.0 9.83 98 10.0 10.0 100 2 75-124 20
Trans-1.3-Dichloropropene ND 10.0 9.93 99 10.0 10.4 104 5 73-127 20
Trichloroethene ND 10.0 9.68 97 10.0 9.94 99 3 79-123 20
Trichlorofluoromethane ND 10.0 9.29 93 10.0 8.83 88 5 65-141 20
Vinyl Chloride ND 10.0 8.78 88 10.0 8.48 85 3 58-137 20
1.2-Dibromoethane ND 10.0 9.91 99 10.0 10.3 103 4 77-121 20
1. 2. 3-Trichlorobenzene ND 10.0 10.8 108 10.0 11.1 111 3 69-129 20
1.4-Dioxane ND 200 190 95 200 187 94 2 59-139 20
SpikeArnt LCSResult LCSRec SpikeArnt LCDResult LCDRec QCLimit
SURROGATE PARAMETERS (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%)
..................................................... .. .............. .............. .. ............. .. ............. .. ..................
1.2-Dichloroethane-d4 10.0 10.3 103 10.0 10.3 103 70-130
4-Bromofluorobenzene 10.0 10.4 104 10.0 10.4 104 70-130
Toluene-d8 10.0 10.7 107 10.0 10.8 108 70-130
Dibromofluoromethane 10.0 10.8 108 10.0 10.9 109 70-130
MB: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
REPORT ID: 23E120 Page 102 of 560
EMAX QUALITY CONTROL DATA
MS/MSD AAALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO_ 23E120
METHOD SWS030B/8260C
MATRIX : WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID : S-121-08-052023 S-121-08-052023MS S-121-08-052023MSD
LAB SAMPLE ID : 23E120-02 23E120-02M 23E120-02S
LAB FILE ID : REC391 REC402 REC403
DATE PREPARED : 05/17/23 11:49 05/17/23 16:32 05/17123 16:58
DATE AAALYZED : 05/17/23 11:49 05/17/23 16:32 05/17/23 16:58
PREP BATCH : V067E17 V067E17 V067E17
CALIBRATION REF: RDC593 RDC593 RDC593
ACCESSION:
PSResult SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%) (%) (%)
----------.----_ ....................... ................ -........ a_ ..... .................... .. .......................... ....... a ..... .. ........... -
1. 1. 1. 2-Tetrachl oroethane NO 10.0 10.8 108 10.0 10.7 107 1 78-124 20
1. 1. I-Trichloroethane ND 10.0 10.9 109 10.0 10.7 107 2 74-131 20
1. 1.2. 2-Tetrachloroethane ND 10.0 10.7 107 10.0 10.7 107 0 71-121 20
1.1.2-Trichloroethane NO 10.0 11.1 111 10.0 11.4 114 3 80-119 20
1.1-Dichloroethane NO 10.0 10.7 107 10.0 10.6 106 1 77-125 20
1.1-Dichloroethene NO 10.0 9.71 97 10.0 9.79 98 1 71-131 20
1.1-Dichloropropene NO 10.0 10.2 102 10.0 10.1 101 1 79-125 20
1.2.3-Trichlorogropane NO 10.0 10.5 105 10.0 10.7 107 2 73-122 20
1.2.4-Trichloro enzene ND 10.0 10.9 109 10.0 10.7 107 2 69-130 20
1.2-Dibromo-3-chloropropane ND 10.0 10.8 108 10.0 11.0 110 2 62-128 20
1.2-Dichlorobenzene NO 10.0 10.1 101 10.0 9.96 100 1 80-119 20
1.2-Dichloroethane NO 10.0 11.6 116 10.0 11.9 119 3 73-128 20
1.2-Dichlorogropane NO 10.0 11.1 111 10.0 11.1 111 0 78-122 20
1.3-Dichloro enzene ND 10.0 9.95 100 10.0 9.49 95 5 80-119 20
1.3-Dichlorogropane NO 10.0 11.0 110 10.0 11.5 115 4 80-119 20
1.4-Dichloro enzene NO 10.0 9.89 99 10.0 9.45 95 5 79-118 20
2.2-Dichloro~ro~ane NO 10.0 10.3 103 10.0 10.0 100 3 60-139 20
2-Butanone ( EK NO 50.0 53.7 107 50.0 59.5 119 10 56-143 20
2-Chlorotoluene ND 10.0 9.01 90 10.0 8.65 87 4 79-122 20
2-Hexanone NO 50.0 54.9 110 50.0 60.9 122 10 57-139 20
4-Chlorotoluene ND 10.0 9.76 98 10.0 9.29 93 5 78-122 20
Acetone NO 50.0 50.3 101 50.0 55.9 112 11 39-160 20
Benzene NO 10.0 10.8 108 10.0 10.8 108 0 79-120 20
Bromobenzene NO 10.0 9.96 100 10.0 9.64 96 3 80-120 20
Bromochloromethane NO 10.0 10.8 108 10.0 11.1 111 3 78-123 20
Bromodichloromethane ND 10.0 11.3 113 10.0 11.3 113 0 79-125 20
Bromoform NO 10.0 10.2 102 10.0 10.4 104 2 66-130 20
Bromomethane ND 10.0 10.4 104 10.0 10.8 108 4 53-141 20
Carbon Disulfide NO 10.0 11.4 114 10.0 11.8 118 3 64-133 20
Carbon Tetrachloride 3.00 10.0 14.1 111 10.0 13.9 109 1 72-136 20
Chlorobenzene NO 10.0 10.6 106 10.0 10.4 104 2 82-118 20
Chloroethane ND 10.0 12.3 123 10.0 13.0 130 6 60-138 20
Chloroform 1.60 10.0 13.0 114 10.0 13.0 114 0 79-124 20
Chloromethane NO 10.0 9.22 92 10.0 9.47 95 3 50-139 20
cis-1.2-Dichloroethene NO 10.0 10.6 106 10.0 10.5 105 1 78-123 20
CiS-1.3-Dichloro~ropene NO 10.0 11.2 112 10.0 11.4 114 2 75-124 20
Dibromochloromet ane ND 10.0 10.8 108 10.0 11.1 111 3 74-126 20
Dibromomethane NO 10.0 10.9 109 10.0 11.2 112 3 79-123 20
Dichlorodifluoromethane ND 10.0 9.30 93 10.0 9.43 94 1 32-152 20
Ethyl benzene NO 10.0 10.4 104 10.0 10.1 101 3 79-121 20
ISOprO~Ylbenzene ND 10.0 10.2 102 10.0 9.99 100 2 72-131 20
m,~-xf: ene NO 20.0 21.2 106 20.0 20.5 103 3 80-121 20
4-et yl-2-Pentanone NO 50.0 56.9 114 50.0 61.5 123 8 67-130 20
Methylene Chloride ND 10.0 9.89 99 10.0 9.95 100 1 74-124 20
Meth{l tert-butyl ether (MTBE) NO 10.0 11.5 115 10.0 12.1 121 5 71-124 20
n-Bu ylbenzene ND 10.0 9.58 96 10.0 9.08 91 5 75-128 20
n-Propylbenzene NO 10.0 9.74 97 10.0 9.25 93 5 76-126 20
o-Xylene ND 10.0 10.9 109 10.0 10.8 108 1 78-122 20
~-Isopro~bltoluene NO 10.0 9.78 98 10.0 9.15 92 7 77-127 20
ec-Buty enzene NO 10.0 10.1 101 10.0 9.38 94 7 77-126 20
Styrene NO 10.0 4.77 48* 10.0 4.44 44* 7 78-123 20
Tert-Butylbenzene ND 10.0 9.94 99 10.0 9.47 95 5 78-124 20
Tetrachloroethene NO 10.0 10.3 103 10.0 9.93 99 4 74-129 20
Toluene NO 10.0 10.4 104 10.0 10.1 101 3 80-121 20
Trans-1.2-Dichloroethene NO 10.0 9.88 99 10.0 9.85 99 0 75-124 20
Trans-1.3-Dichloropropene NO 10.0 10.9 109 10.0 11.3 113 4 73-127 20
Trichloroethene NO 10.0 10.7 107 10.0 10.6 106 1 79-123 20
Trichlorofluoromethane ND 10.0 12.2 122 10.0 12.4 124 2 65-141 20
Vinyl Chloride NO 10.0 11.6 116 10.0 12.0 120 3 58-137 20
1.2-Dibromoethane ND 10.0 10.8 108 10.0 11.3 113 5 77-121 20
1. 2. 3-Trichlorobenzene NO 10.0 10.9 109 10.0 11.3 113 4 69-129 20
1.4-Dioxane NO 200 218 109 200 238 119 9 59-139 20
SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec QCLimit
SURROGATE PARAMETERS (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%)
....... -.................................. _-_ .... _._ .. __ ._ .. ... __ ......... ....... ----....... -...... ___ a ........ _ ..
1.2-Dichloroethane-d4 10.0 11.1 111 10.0 11.7 117 70-130
4-Bromofluorobenzene 10.0 9.77 98 10.0 9.59 96 70-130
Toluene-d8 10.0 10.4 104 10.0 10.4 104 70-130
Dibromofluoromethane 10.0 11.1 111 10.0 11.3 113 70-130
PS: Parent Sample MS: Matrix Spike MSD: Matrix Spike Duplicate
* Out of QC Limit
REPORT ID: 23E120 Page 103 of 560
QC DATA
REPORT ID: 23E120 Page 104 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC384.D
~cq On 17 May 2023 8:50 am
Sample V067E17B
Misc 25mL
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 6
Operator: VLu
Inst 67
Multiplr: 1.00
.. Quant Time: May 17 9: 55 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26 ~
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.15 114 2273441 10.00 ug/l 0.02
55 ) CHLOROBENZENE-D5 15.60 117 1592561 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 416893 10.00 ug/l 0.00
_.
System Monitoring Compounds
36) Dibromofluoromethane 8.21 111 566251 10.45 ug/l 0.02
;'" Spiked Amount 10.000 Recovery 104.50%
43 ) l,2-Dichloroethane-d4 9.31 65 414056 10.01 ug/l 0.02
Spiked Amount 10.000 Recovery 100.10%
56) Toluene-d8 12.99 98 2433034 10.99 ug/l ~ 0.02
Spiked Amount 10.000 Recovery 109.90%
r: 77) 4-Bromofluorobenzene 17.60 95 626408 11.12 ugly 0.00
Spiked Amount 10.000 Recovery 111'.20%
Target Compounds /' Qvalue "'
(#) = qualifier out of range (m) = manual integration
REC384.D V067D26.M Thu May 18 08:19:54 2023 Page 1
REPORT ID: 23E120 Page 105 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC384.D
Acq On 17 May 2023 8:50 am
Sample V067E17B
Mise 25mL
Vial: 6
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 17 9:55 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
7500000:
7000000i
6500000j
6000000i
55000001 :
5000000 !
45000001 .
i
40000001
j
3500000:
3000000:
i I
2500000,
i
!
2000000i
I
1500000
1000000,
5000001
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC384.D
(f)
ai
u.i 'C
" z c: W " N ::l z '0 w f-m
0 a::
0
::J
...J
U.
15
(f) "-oi (f)
c: ~-
'" 'C ~ " c:
'" e ,5
0 Q)
::l e '5 .Q
E .s::; u e 0 ,g ~ 0
<Ii
0
uJ
Z w
N
Z
W m
0 a::
0
...J
I
U
'i !\ I: i
(f)
oi c:
" N c:
" .0 e
0
::l
'" 0
E e m
"
'" 0
uJ
Z w
N z w m
0 a::
0
...J
I
U
15
~
0: , ' I ' i ~ . \ ,I \ " i ' " , :' ii ',e, , , ' '. -,,' '" I ii, I '
Time--> 2.00 3.00 4.00 5.006.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REC384.D V067D26.M Thu May 18 08:19:55 2023 Page 2
REPORT ID: 23E120 Page 106 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC381.D Vial: 3
Operator: VLu Acq On 17 May 2023 7:33 am
Sample V067E17L Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:20 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Last Update
Response via
DataAcq Meth V067D26 ,....----
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
~ 36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.15
15.60
19.49
8.21
9.31
12.99
17.60
1. 88
2.16
2.28
2.68
2.72
2.78
2.98
3.53
3.59
3.61
3.78
3.94
4.25
4.31
4.53
4.54
4.78
4.82
5.05
5.71
5.90
5.96
6.65
6.94
7.23
7.33
7.71
114 2239216
117 1612846
152 508177
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.02
0.00
0.00
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
574812 10.77 0.02
Recovery
ug/l
107.70%
ug/lr-
102.90%
ug/lr
107·530%
ugj~
101.00%
419150 10.29
Recovery
2412396 10.76
Recovery =
693129 10.10
Recovery
725423
1163396
1129179
748296
784497
1388943
925735
217417
537108
489954
1243647
544192
1045546
296355
3034647
999566
569525
1112928
870561
2615098
1432059
832091
1734925
151730
1030935
850406
1214635
10.61 ug/l
9.80 ug/l
10.74 ug/l
11.54 ug/l
11.39 ug/l
10.66 ug/l
12.04 ug/l
41.46 ug/l
10.72 ug/l
54.56 ug/l
10.12 ug/l
220.58 ug/l
9.72 ug/l
10.15 ug/l
11.84 ug/l
9.61 ug/l
48.34 ug/l
10.40 ug/l
10.27 ug/l
10.57 ug/l
10.43 ug/l
10.60 ug/l
10.23 ug/l
50.79 ug/l
11.51 ug/l
10.58 ug/l
10.95 ug/l
0.02
0.02
0.00
Qvalue
100
97
100
100
99
100
99
99
100
99
97
98
99
99
100
99
99
100
100
99
100
99
99
99
99
99
98
(#) = qualifier out of range (m) = manual integration
REC381.D V067D26.M Thu May 18 08:20:56 2023 Page 1
REPORT ID: 23E120 Page 107 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC381.D
Acq On 17 May 2023 7:33 am
Sample V067E17L
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:20 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33)
34)
37)
38)
40)
41 )
42)
44)
45 )
46 )
47)
" 48)
,-49)
r. 50)
51 )
52)
53)
54)
57)
58)
59)
60)
61)
62)
63)
64)
65)
66)
67)
68)
69 )
70)
71)
72)
73)
75)
76)
78)
79)
80)
81 )
Bromochloromethane
Tetrahydrofuran
Cyclohexane
l,l,l-Trichloroethane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
l,l,2,2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
8.08
8.17
8.59
8.60
8.94
9.12
9.26
9.50
9.51
10.74
10.83
11.10
11.54
11.63
11.61
12.21
12.26
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.26
14.61
14.96
15.28
15.68
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
344017
91704
1312257
995312
373732
801042
279675
3153667
530155
754733
1472209
716345
775552
50831
280397
20006
1541587
1008455
3111109
689805
414244
377204
982546
721589
617439
404990
324056
1308761
1762424
560937
3534470
5193749
2492398
1675187
3238869
177540
378143
98089
97340
4068100
554278
10.54
9.47
10.49
10.74
9.75
10.70
10.59
10.55
10.09
10.21
10.57
10.63
10.63
~4.18
.. 10.36
1. 65
46.81
10.61
10.85
10.67
8.85
11.07
48.92
10.75
10.85
10.71
10.70
10.67
10.77
11.69
10.96
22.25
11.33
9.93
11.26
9.85
10.85
10.46
9.98
11.01
10.65
(#) = qualifier out of range (m) = manual integration
REC381.D V067D26.M Thu May 18 08:20:57 2023
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
96
98
98
100
99
99
100
99
99
99
98
99
99
97
75
97
99
100
93
99
98
99
99
99
99
97
100
99
100
99
100
99
99
99
99
99
99
99
100
100
Page 2
REPORT ID: 23E120 Page 108 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC381.D
Aeq On 17 May 2023 7:33 am
Sample V067E17L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:20 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1, 3, 5-Trimethylbenzene 18.04 105 2467125 10.71 ug/l
83) 2-Chlorotoluene 18.06 91 2465873 10.35 ug/l
84) 4-Chlorotoluene 18.12 91 1992130 10.19 ug/l
85) tert-Butylbenzene 18.48 134 573081 11.28 ug/l
86) 1,2,4-Trimethylbenzene 18.53 105 2335303 10.93 ug/l
87) see-Butylbenzene 18.74 105 3457790 11.33 ug/l
88) p-Isopropyltoluene 18.89 119 2647937 11.04 ug/l
89) l,3-Diehlorobenzene 19.01 146 1099093 10.55 ug/l
90 ) 1,4-Diehlorobenzene 19.12 146 1066568 10.53 ug/l
91 ) n-Butylbenzene 19.34 91 2462759 10.79 ug/l
92) 1,2-Diehlorobenzene 19.52 146 861497 10.51 ug/l
93) 1,2-Dibromo-3-ehloropropan 20.31 157 36398 10.16 ug/l
94) 1, 2, 4-Triehlorobenzene 21.16 180 379970 11.00 ug/l
95) Hexaehlorobutadiene 21. 29 225 330370 11.35 ug/l
96) Naphthalene 21.45 128 420100 9.49 ug/l
97) 1, 2, 3-Triehlorobenzene 21.70 180 255510 10.83 ug/l
. (#) = qualifier out of range (m) = manual integration
REC381.D V067D26.M Thu May 18 08:20:57 2023
Qvalue
100
95
93
96
99
99
99
100
99
100
99
98
99
98
99
99
Page 3
REPORT ID: 23E120 Page 109 of 560
Data File
Aeq On
Sample
Quantitation Report
D:\HPCHEM\1\DATA\23E17\REC381.D
17 May 2023 7:33 am
V067E17L
Vial:
Operator:
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: May 18 8:20 2023 Quant Results File:
Method
Title
Last Update
Response via
Abundance
,
7500000;
, 70000001
I
i
6500000['
6000000i
I
5500000' 1.
50000001
45000001
4000000]
3500000; •
3000000;:;
!If. ,.,
c: 1~
ltl 2500000iE e o ,,E
i:g
1(5
2000000i~
1° ::;; ...:
1500000!· ~
::;; c:
i I-~ £
'~ ~
i' ~ e
1000000! i i ~
~ alE
110..: @.E ~ m:§
<$ ,~
500000
Time-->
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Trc:REG31f1.IT~ ~-~~~~---~---~
REC381.D V067D26.M Thu May 18 08:21:00 2023
3
VLu
67
l. 00
V067D26.RES
Page 4
REPORT ID: 23E120 Page 110 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC382.D
Acq On 17 May 2023 7:59 am
Sample V067E17C
Vial: 4
Operator: VLu
Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:21 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Last Update
Response via
DataAcq Meth V067D26 ~
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8·
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
: Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.15 114
15.60 117
19.49 152
8.21
9.30
12.99·
17.60
1. 88
2.16
2.28
2.68
2.72
2.78
2.98
3.53
3.59
3.61
3.78
3.92
4.25
4.31
4.53
4.54
4.77
4.82
5.05
5.71
5.91
5.96
6.64
6.94
7.23
7.33
7.71
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
2184518
1599354
497934
570651
Recovery
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
10.96 ug/l 0.01
109.60%
421119 10.59 ug/l 3.01
105.90% Recovery
2386542 10.73 ug/l 0.02
Recovery 107.30%
ug/l/ 0.00
104.()0%
699246 10.40
Recovery
671226
998559
1000519
649461
709094
1357504
767887
214237
529138
503040
1262411
565255
1028238
301054
2698724
986299
591667
1126664
856322
2629742
1417571
782465
1745322
154697
998200
846467
1190317
/~
10.07 ug/l
8.63 ug/l
9.75 ug/l
10.27 ug/l
10.55 ug/l
10.68 ug/l
10.24 ug/l
41.87 ug/l
10.82 ug/l
57.42 ug/l
10.53 ug/l
234.85 ug/l
9.80 ug/l
10.57 ug/l
10.80 ug/l
9.72 ug/l
51.48 ug/l
10.80 ug/l
10.36 ug/l
10.89 ug/l
10.59 ug/l
10.22 ug/l
10.55 ug/l
53.08 ug/l
11.42 ug/l
10.79 ug/l
11.00 ug/l
Qvalue
99
95
100
99
98
100
100
100
99
99
99
98
98
100
100
99
98
100
100
100
100
99
100
90
100
100
99
(#) = qualifier out of range (m) = manual integration
REC382.D V067D26.M Thu May 18 08:21:38 2023 Page 1
REPORT ID: 23E120 Page 111 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC382.D
Acq On 17 May 2023 7:59 am
Sample V067E17C
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:21 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) l,l,l-Trichloroethane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.16
8.59
8.60
8.94
9.11
9.26
9.49
9.51
10.74
10.82
11.10
11.54
11.63
11.61
12.21
12.26
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.26
14.61
14.96
15.28
15.67
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
341681 10.73 ug/l
93894 9.93 ug/l
1295494 10.62 ug/l
982767 10.87 ug/l
373365 9.99 ug/l
798600 10.93 ug/l
279303 10.84 ug/l
3121725 10.71 ug/l
528015 10.31 ug/l
731744 10.15 ug/l
1447410 10.65 ug/l
714466 10.86 ug/l
775400 10.89 ug/l
53619 ~09.96 ug/l
279649 10.59 ug/l
20963 1.77 ug/l
1613539 50.23 ug/l
1015768 10.96 ug/l
3120172 10.97 ug/l
701045 10.93 ug/l
437274 9.42 ug/l
379935 11.25 ug/l
1040390 52.24 ug/l
736458 11.06 ug/l
607468 10.76 ug/l
404188 10.78 ug/l
327160 10.89 ug/l
1311023 10.78 ug/l
1741918 10.74 ug/l
555618 11.67 ug/l
3513101 10.98 ug/l
5151218 22.26 ug/l
2494852 11.44 ug/l
1700410 10.17 ug/l
3273323 11.48 ug/l
178424 10.10 ug/l
386025 11.30 ug/l
101681 11.07 ug/l
99463 10.41 ug/l
4058388 11.21 ug/l
558762 10.96 ug/l
(#) = qualifier out of range (m) = manual integration
REC382.D V067D26.M Thu May 18 08:21:39 2023
Qvalue
100
97
97
98
99
100
98
100
100
99
99
99
99
98
99
81
98
100
100
93
98
99
99
99
99
99
99
100
99
100
100
100
99
98
100
98
100
99
98
100
100
Page 2
REPORT ID: 23E120 Page 112 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC382.D
Aeq On 17 May 2023 7:59 am
Sample V067E17C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:21 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
82) l,3,5-Trimethylbenzene 18.04 105 2480739 10.99 ug/l 100
83) 2-Chlorotoluene 18.06 91 2468766 10.58 ug/l 94
84) 4-Chlorotoluene 18.11 91 1996158 10.42 ug/l 93
85 ) tert-Butylbenzene 18.48 134 564894 11.35 ug/l 97
86 ) 1, 2, 4-Trimethylbenzene 18.52 105 2303177 11.00 ug/l 99
87 ) see-Butylbenzene 18.74 105 3460866 11.57 ug/l 100
88) p-Isopropyltoluene 18.89 119 2612252 11.12 ug/l 99
89 ) l,3-Diehlorobenzene 19.01 146 1092523 10.71 ug/l 99
90 ) l,4-Diehlorobenzene 19.12 146 1067020 10.75 ug/l 99
:.~. 91) n-Butylbenzene 19.34 91 2379726 10.64 ug/l 99
92) l,2-Diehlorobenzene 19.52 146 854486 10.64 ug/l 100
93) l,2-Dibromo-3-ehloropropan 20.31 157 36880 10.50 ug/l 97
-. 94) 1, 2, 4-Triehlorobenzene 21.15 180 382304 11.29 ug/l 100
95 ) Hexaehlorobutadiene 21.29 225 324366 11.37 ug/l 99
96) Naphthalene 21.45 128 436631 10.07 ug/l 98
97) l,2,3-Triehlorobenzene 21.69 180 267063 11.56 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC382.D V067D26.M Thu May 18 08:21:39 2023 Page 3
REPORT ID: 23E120 Page 113 of 560
Quantitation Report
Data File
Aeq On
Sample
D:\HPCHEM\I\DATA\23EI7\REC382.D
17 May 2023 7:59 am
V067E17C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
Quant Time: May 18 8:21 2023 Quant Results File:
Method
Title
Last Update
Response via
Abundance
7500000!
7000000·
i
6500000t:
:1
60000001
:1
"
5500000i! .,
i'
5000000,
i
4500000!
4000000j
3500000·
i:
3000000: .
i
!~-1ft-· 2500000i~
15 ,.,
'E
·2 o ," 2000000j:§ :e
'~ :2
'0 ..:
1500000: ~
. ~ 1>"1~ cr: ~ ~ §
1000000i i i ~g
J ~~ a;;. ~:C ~ CD~
500000!
Time-->
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RECJ82.D
.,
c: .,
i
REC382.D V067D26.M Thu May 18 08:21:42 2023
4
VLu
67
1. 00
V067D26.RES
::< ..:
<Ii c:
'" c. e c. e o
~
~ e
D o
~
Page 4
REPORT ID: 23E120 Page 114 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC413.D
Acq On 18 May 2023 8:50 am
Sample V067E18B
Misc 25mL
(QT Reviewed)
Vial: 6
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 9:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.17 114 2377971 10.00 ug/l 0.03
55) CHLOROBENZENE-D5 15.62 117 1665592 10.00 ug/l 0.02
74) 1,2-DICHLOROBENZENE-D4 19.50 152 429983 10.00 ug/l 0.02
System Monitoring Compounds
36 ) Dibromofluoromethane 8.22 111 594555 10.49 ug/l 0.03
Spiked Amount 10.000 Recovery 104.90%
ty 43) 1,2-Dichloroethane-d4 9.30 65 432993 10.01 ug/l_ 0.02
Spiked Amount 10.000 Recovery -100.10%
56) Toluene-d8 12.99 98 2528122 10.92 ug/l ~ 0.02
--Spiked Amount 10.000 Recovery 109.20% \
~
'j" 77) 4-Bromofluorobenzene 17.62 95 652455 11. 23 ug/~ 0.02 L
L Spiked Amount 10.000 Recovery 112.30%
t< /'
r'Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REC413.D V067D26.M Fri May 19 08:36:12 2023 Page 1
REPORT ID: 23E120 Page 115 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC413.D
Aeq On 18 May 2023 8:50 am
Sample V067E18B
Mise 25mL
Vial: 6
Operator: VLu
Inst 67
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 18 9:29 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
Abundance ----------------~TT"1I7'C7l: Rr->lE="C4 ... 1..,3~.D.-------~-~
I I
I ,
I 75000001
70000001
65000001l
ji
" j ~
6000000ji
i
5500000
5000000\ '
,I
!I ii
Ii
I 45000001;
40000001
3500000 •
3000000: :
I
I
1
2500000;
2000000i
1500000
1000000j •
I'
! :
500000;
(J)
oj
c:
til
~
E e
0
" '" 0
E e
.0
is
(J)
ai
~ on
u.i Cl
c: uJ z " z w " N 0 W
Z l-N
Z w w (J)
'" oj
0 '" c:
0:: 0 " 0:: N 0 0 c:
~ " ..J ..J .0
u. I e
i5 u 0
" .t. '5
E
(J) e
" '" " .t
Q,
c:
~
~
0
£
is
c.:..
" Cl
W z w
N
Z
W
'" 0
0::
0
-' I u
0
N.
ii
i\
Ol , " "'" ,I" " ' ','" """, " I', ,~----
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00
REC413.D V067D26.M Fri May 19 08:36:13 2023 Page 2
REPORT ID: 23E120 Page 116 of 560
Quantitasion Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC410.D Vial: 3
Operator: VLu Acq On 18 May 2023 7:34 am
Sample V067E18L Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 9:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Last Update
Response via
DataAcq Meth V067D26 ~
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
P:System Monitoring Compounds
-: 36) Dibromofluoromethane
;" Spiked Amount 10.000
G 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
C. Spiked Amount 10.000
1 77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.17
15.62
19.50
8.22
9.32
12.99
17.62
1. 88
2.18
2.28
2.70
2.72
2.80
3.00
3.53
3.61
3.61
3.80
3.94
4.26
4.32
4.54
4.56
4.79
4.83
5.07
5.73
5.92
5.97
6.67
6.95
7.24
7.35
7.73
114 2419935
117 1770486
152 546273
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.03
0.02
0.02
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
620272 10.76
Recovery
455575 10.34
Recovery
2633017 10.70
Recovery
768060 10.41
Recovery
ug/l
107.60%
ug/l
103 (4()%
ug/l.........--
107.00%
ug/X
10.--;;10%
0.03
0.03
0.02
0.02
718334
955113
997196
652812
707126
1440734
771635
255866
574243
523996
9.73 ug/l
7.45 ug/l
~.78 ug/l
9.32 ug/l
9.50 ug/l
10.23 ug/l
Qvalue
99
92
100
99
97
100
1269640
612274
1074504
296567
2818511
1019532
607664
1141369
900385
2725673
1485307
775813
1814762
160144
1062115
875400
1241083
9.29 ug/l
45.14 ug/l
10.60 ug/l
53.99 ug/l
9.56 ug/l
229.64 ug/l
9.24 ug/l
9.40 ug/l
10.18 ug/l
9.07 ug/l
47.73 ug/l
9.87 ug/l
9.83 ug/l
10.19 ug/l
10.01 ug/l
9.15 ug/l
9.90 ug/l
49.61 ug/l
10.97 ug/l
10.07 ug/l
10.36 ug/l
99
98
100
99
98
100
98
99
100
99
100
100
100
99
99
99
100
99
100
99
99
(#) = qualifier out of range (m) = manual integration
REC410.D V067D26.M Fri May 19 08:37:37 2023 Page 1
REPORT ID: 23E120 Page 117 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC410.D
Acq On 18 May 2023 7:34 am
Sample V067E18L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 9:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
33) Bromochloromethane
34) Tetrahydrofuran
r 37) Cyclohexane
38) l,l,l-Trichloroethane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
, 47) Methylcyclohexane
48) l,2-Dichloropropane
\ 49) Bromodichloromethane
i. 50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.09
8.18
8.60
8.62
8.95
9.13
9.28
9.49
9.51
10.75
10.82
11.10
11.54
11.63
11.63
12.21
12.26
12.59
13.13
13.51
13.54
13.76
13.82
14.20
14.26
14.62
14.96
15.30
15.68
15.76
15.78
15.91
16.64
16.71
17.24
17.25
17.52
17.72
17.82
17.82
17.88
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
349357
85902
1347628
1035945
389315
820552
284057
3255971
544338
773253
1516236
734735
812135
53746
282134
23736
1664138
1030939
3244176
704737
425148
379626
1065501
736179
636308
407489
329532
1381196
1807793
569306
3685116
5400610
2603867
1739264
3384203
182162
384173
99538
99678
4234524
567029
(#) = qualifier out of range (m) = manual integration
REC410.D V067D26.M Fri May 19 08:37:38 2023
9.91 ug/l
8.21 ug/l
9.97 ug/l
10.35 ug/l
9.40 ug/l
10.14 ug/l
9.95 ug/l
10.08 ug/l
9.59 ug/l
9.68 ug/l
10.07 ug/l
10.09 ug/l
10.30 ug/l
189.98 ug/l
9.65 ug/l
1.81 ug/l
46.76 ug/l
10.04 ug/l
10.30 ug/l
9.93 ug/l
8.27 ug/l
10.15 ug/l
48.33 ug/l
9.99 ug/l
10.18 ug/l
9.82 ug/l
9.91 ug/l
10.26 ug/l
10.07 ug/l
10.81 ug/l
10.41 ug/l
21.08 ug/l
10.78 ug/l
9.39 ug/l
10.72 ug/l
9.40 ug/l
10.25 ug/l
9.88 ug/l
9.51 ug/l
10.66 ug/l
10.14 ug/l
Qvalue
99
97
97
98
99
99
98
100
99
99
99
98
99
97
99
78
97
100
99
95
99
98
99
99
99
98
99
100
99
100
100
100
99
98
99
99
99
100
96
100
100
Page 2
REPORT ID: 23E120 Page 118 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC410.D
Aeq On 18 May 2023 7:34 am
Sample V067E18L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 9:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1,3,5-Trimethylbenzene 18.04 105 2590255 10.46 ug/l
83) 2-Chlorotoluene 18.06 91 2482817 9.70 ug/l , 84) 4-Chlorotoluene 18.12 91 2164292 10.29 ug/l .. -
..
85) tert-Butylbenzene 18.50 134 602654 11.04 ug/l
,. 86) 1, 2, 4-Trimethylbenzene 18.54 105 2427219 10.56 ug/l
1\ 87 ) see-Butylbenzene 18.74 105 3660939 11.15 ug/l
\:
l" 88) p-Isopropyltoluene 18.90 119 2819593 10.94 ug/l
89 ) 1,3-Diehlorobenzene 19.01 146 1127429 10.07 ug/l
90 ) l,4-Diehlorobenzene 19.12 146 1091264 10.02 ug/l
'." 91) n-Butylbenzene 19.34 91 2600669 10.60 ug/l
;1 92) 1,2-Diehlorobenzene 19.53 146 880938 9.99 ug/l 1
93) l,2-Dibromo-3-ehloropropan 20.31 157 36779 9.55 ug/l
94) 1, 2, 4-Triehlorobenzene 21.17 180 404014 10.88 ug/l
95) Hexaehlorobutadiene 21.30 225 354831 11.34 ug/l
96) Naphthalene 2l.45 128 433751 9.12 ug/l
97) 1,2,3-Triehlorobenzene 21.70 180 273807 10.80 ug/l
(#) = qualifier out of range (m) = manual integration
REC410.D V067D26.M Fri May 19 08:37:38 2023
Qvalue
100
94
94
96
99
99
100
100
99
99
99
98
99
99
99
98
Page 3
REPORT ID: 23E120 Page 119 of 560
Quantitation Report
Data File
Aeq On
Sample
D:\HPCHEM\1\DATA\23E18\REC410.D
18 May 2023 7:34 am
V067E18L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
Quant Time: May 18 9:35 2023 Quant Results File:
Method
Title
Last Update
Response via
(A.bundance
II t
i 7500000:
7000000j
i
650000011
Ii
11
6000000i!
II
5500000; I
I
5000000 1
i
i
4500000]
i
4000000i
Ii 3500000j~
Ie:
'to
300000011
," .5 ,." 2500000;~
iil liS i I
i'
2000000j :
15000001
500000 1
Time-->
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Trc:REC41 0.0
REC410.D V067D26.M Fri May 19 08:37:40 2023
3
VLu
67
1. 00
V067D26.RES
::i: ...:
oi c:
<Il
0. e
0. e o
~
'" ~ .c
is
~
Page 4
REPORT ID: 23E120 Page 120 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC411.D Vial: 4
Operator: VLu Acq On 18 May 2023 7:59 am
Sample V067E18C Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 9:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023 ~
Initial Calibration
L
V067D26
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
i'System Monitoring Compounds
36) Dibromofluoromethane
"~I Spiked Amount 10.000
~ 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
-12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. Qlon Response Conc Units Dev(Min)
10.17
15.62
19.50
8.22
9.32
12.99
17.62
1. 88
2.18
2.28
2.68
2.72
2.80
2.98
3.53
3.59
3.61
3.80
3.94
4.25
4.31
4.54
4.56
4.79
4.83
5.05
5.73
5.92
5.97
6.66
6.94
7.23
7.35
7.71
114 2384647
117 1720549
152 538153
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.03
0.02
0.02
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
619594 10.90 ug/l 0.03
Recovery 109.00%
447154 10.30 ug/l 0.03
103 .. ~
ug/l."..,-0.02
107.70%
ug/l/ 0.02
103.'50%
Recovery =
2575561 10.77
Recovery
752410 10.35
Recovery
/
664571
899975
948993
624506
680623
1438744
723270
245927
567995
528487
1298399
608819
1078513
255462
2661624
1030308
603049
1147179
905205
2755636
1519513
762619
1837173
158079
1062208
891944
1263015
9.13 ug/l
7.12 ug/l
8.48 ug/l
9.04 ug/l
9.28 ug/l
10.37 ug/l
8.83 ug/l
44.03 ug/l
10.64 ug/l
55.26 ug/l
9.92 ug/l
231.73 ug/l
9.41 ug/l
8.22 ug/l
9.75 ug/l
9.30 ug/l
48.07 ug/l
10.07 ug/l
10.03 ug/l
10.46 ug/l
10.40 ug/l
9.13 ug/l
10.17 ug/l
49.69 ug/l
11.14 ug/l
10.42 ug/l
10.70 ug/l
Qvalue
99
91
100
100
96
100
99
100
99
99
100
99
99
98
99
99
98
100
100
99
100
99
100
96
99
99
99
(#) = qualifier out of range (m) = manual integration
REC411.D V067D26.M Fri May 19 08:39:46 2023 Page 1
REPORT ID: 23E120 Page 121 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC411.D
Acq On 18 Mny 2023 7:S9 am
Sample V067E18C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operutor: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 9:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. Qlon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) 1,1,1-Trichloroethane
40) 1,1-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) 1,2-Dichloroethane
v 46) Trichloroethene
47) Methylcyclohexane
48) 1,2-Dichloropropane
!.: 49) Bromodichloromethane
50) 1,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) eis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) 1,2-Dibromoethane
-66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) 1,1,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.17
8.59
8.60
8.95
9.13
9.28
9.50
9.51
10.75
10.82
11.10
11.54
11.63
11.63
12.21
12.26
12.59
13.12
13.50
13.54
13.76
13.82
14.20
14.26
14.62
14.96
15.28
15.68
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.88
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
355949
95002
1074025
1055851
396842
839442
287788
3318327
549453
782508
1194099
757193
824580
52126
290497
24123
1695805
1051029
3321240
716854
441127
390114
1072155
749587
650587
419426
333881
1401651
1849799
584010
3722488
5523018
2656882
1784684
3454741
182949
390251
100676
99313
4318150
578191
(#) = qualifier out of range (m) = manual integration
REC411.D V067D26.M Fri May 19 08:39:47 2023
10.24 ug/l
9.21 ug/l
8.06 ug/l
10.70 ug/l
9.72 ug/l
10.53 ug/l
10.23 ug/l
10.43 ug/l
9.82 ug/l
9.94 ug/l
8.05 ug/l
10.55 ug/l
10.61 ug/l
186.98 ug/l
10.08 ug/l
1.87 ug/l
48.36 ug/l
10.39 ug/l
10.86 ug/l
10.39 ug/l
8.83 ug/l
10.73 ug/l
50.04 ug/l
10.47 ug/l
10.72 ug/l
10.40 ug/l
10.33 ug/l
10.71 ug/l
10.60 ug/l
11.41 ug/l
10.82 ug/l
22.18 ug/l
11.32 ug/l
9.92 ug/l
11.26 ug/l
9.58 ug/l
10.57 ug/l
10.14 ug/l
9.62 ug/l
11.04 ug/l
10.49 ug/l
Qvalue
100
97
97
99
99
99
98
100
100
99
99
99
98
99
99
76
98
98
100
92
100
98
98
99
99
99
99
100
100
100
99
100
99
99
100
99
100
97
96
100
99
Page 2
REPORT ID: 23E120 Page 122 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC411.D
Acq On 10 May 2023 7:59 Qm
Sample V067E18C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 9:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1,3,5-Trimethylbenzene 18.04 105 2630427 10.78 ug/l
83) 2-Chlorotoluene 18.06 91 2557507 10.14 ug/l
-84) 4-Chlorotoluene 18.12 91 2177481 10.51 ug/l
f.\ 85) tert-Butylbenzene 18.50 134 605878 11.26 ug/l
--86) 1,2,4-Trimethylbenzene 18.52 105 2445815 10.81 ug/l
Iv; 87) sec-Butylbenzene 18.74 105 3679601 11.38 ug/l
r'!~ 88) p-Isopropyltoluene 18.90 119 2805768 11.05 ug/l
89 ) 1,3-Dichlorobenzene 19.01 146 1140684 10.34 ug/l
90) 1,4-Dichlorobenzene 19.12 146 1103371 10.28 ug/l
91) n-Butylbenzene 19.34 91 2607253 10.78 ug/l
92) 1,2-Dichlorobenzene 19.53 146 898366 10.35 ug/l
93) 1,2-Dibromo-3-chloropropan 20.31 157 38290 10.09 ug/l
94) 1,2,4-Triehlorobenzene 21.17 180 402832 11.01 ug/l
95) Hexachlorobutadiene 21.29 225 356261 11.56 ug/l
96) Naphthalene 21.45 128 444340 9.48 ug/l
97) 1, 2, 3-Trichlorobenzene 21.70 180 276856 11.08 ug/l ..----
(#) = qualifier out of range (m) = manual integration
REC411.D V067D26.M Fri May 19 08:39:47 2023
Qvalue
100
94
93
97
99
99
99
99
100
100
100
95
99
98
99
100
Page 3
REPORT ID: 23E120 Page 123 of 560
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI8\REC411.D Vial: 4
Aeq On 18 May 2023 7:59 am
Sample V067E18C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Operator:
Inst
Multiplr:
VLu
67
1. 00
Quant Time: May 18 9:35 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
Abundance
i
75000001
I 70000001
65000000
\\
Ii
Ii
60000001 .
ii :!
55000001
5000000i
I
4500000J i , I
; i
4000000~
,
, 35000001
i~
i't.
i~
'co 3ooooo01~
Ie
to l.i iog
25000001.9
iii
Ii'?
2000000:
1500000:
5000001
o~~~~~
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Trc:RcC-41T1Y~~--~~-~~~~-"--,-~~ -
Time--> 2.00 3.00 4.00 5.00
REC411.D V067D26.M Fri May 19 08:39:49 2023 Page 4
REPORT ID: 23E120 Page 124 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC402.D Vial: 24
Operator: VLu Acq On 17 May 2023 4:32 pm
Sample 23E120-02M
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 18 8:48 2023
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
Last Update
Response via
DataAcq Meth V067D26 ~
Internal Standards
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
"Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-l,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.17
15.62
19.50
8.22
9.32
12.99
17.62
1. 88
2.18
2.28
2.68
2.72
2.80
3.00
3.53
3.61
3.61
3.80
3.94
4.26
4.31
4.54
4.56
4.79
4.83
5.07
5.73
5.92
5.97
6.66
6.94
7.25
7.35
7.71
114 2009830
117 1529105
152 504924
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.03
0.02
0.02
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
531023 11.09
Recovery
407432 11.14
Recovery
2201639 10.35
Recovery
666261 9.77
Recovery
ug/l
110.90%
ug/d-
111.40%
ug/l~
103.50%
ugfl
}J.70%
0.03
0.03
0.02
0.02
570628
982139
1091265
602430
760260
9.30 ug/l
9.22 ug/l
11.56 ug/l
10.35 ug/l
12.29 ug/l
12.65 ug/l
12.19 ug/l
30.67 ug/l
10.92 ug/l
50.28 ug/l
Qvalue
100
94
100
99
97
1478670
840910
144372
491268
405260
1071655
585315
1005575
282721
2613825
923172
544216
1104553
751348
2515446
1320065
637538
1659443
143997
828678
766123
1296191
9.71 ug/l
264.33 ug/l
10.41 ug/l
10.79 ug/l
11.37 ug/l
9.89 ug/l
51.47 ug/l
11.50 ug/l
9.88 ug/l
11.33 ug/l
10.72 ug/l
9.05 ug/l
10.90 ug/l
53.71 ug/l
10.31 ug/l
10.62 ug/l
13.02 ug/l
100
99
98
99
99
98
99
99
100
100
100
99
99
99
100
99
99
99
99
99
99
99
(#) = qualifier out of range (m) = manual integration
REC402.D V067D26.M Thu May 18 08:48:43 2023 Page 1
REPORT ID: 23E120 Page 125 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC402.D
Acq On 17 May 2023 4:32 pm
Sample 23E120-02M
Misc 25mL
(QT Reviewed)
Vial: 24
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:48 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
, 38) 1,1,1-Trichloroethane
~ 40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) 1,2-Dichloroethane
-46) Trichloroethene
.~ 47) Methylcyclohexane
48) 1,2-Dichloropropane
49) Bromodichloromethane
50) 1,4-Dioxane
51) Dibromomethane
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) 1,1,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
82) 1,3,5-Trimethylbenzene
8.09
8.17
8.59
8.60
8.96
9.13
9.28
9.50
9.51
10.75
10.83
11.10
11.54
11.63
11.63
12.26
12.59
13.13
13.50
13.54
13.76
13.82
14.20
14.26
14.62
14.96
15.28
15.68
15.76
15.78
15.91
16.64
16.71
17.24
17.25
17.52
17.72
17.82
17.82
17.88
18.04
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
105
316691
95543
1261089
906666
350580
949532
268913
2894428
547149
711937
1460329
671637
738775
51219
265098
1681271
953585
2820604
670423
423077
358350
1045905
701268
554539
385884
309235
1157629
1641098
490925
3178007
4685193
2274646
762318
2785006
183400
370129
97732
105833
3573902
515041
2137930
(#) = qualifier out of range (m) = manual integration
REC402.D V067D26.M Thu May 18 08:48:44 2023
10.81 ug/l
10.99 ug/l
11.23 ug/l
10.90 ug/l
10.19 ug/l
14.13 ug/l
11.35 ug/l
10.79 ug/l
11.61 ug/l
10.73 ug/l
11.68 ug/l
11.10 ug/l
11.28 ug/l
217.99 ug/l
10.91 ug/l
56.88 ug/l
11.18 ug/l
10.37 ug/l
10.93 ug/l
9.53 ug/l
11.09 ug/l
54.93 ug/l
11.02 ug/l
10.28 ug/l
10.77 ug/l
10.77 ug/l
9.95 ug/l
10.58 ug/l
10.79 ug/l
10.39 ug/l
21.17 ug/l
10.90 ug/l
___ 4.77 ug/l
10.21 ug/l
10.24 ug/l
10.69 ug/l
10.49 ug/l
10.93 ug/l
9.74 ug/l
9.96 ug/l
9.34 ug/l
Qvalue
100
95
97
98
98
99
98
100
100
99
99
98
99
98
100
97
99
99
97
99
99
99
98
99
100
100
100
99
99
99
100
100
85
100
99
100
100
97
100
99
100
Page 2
REPORT ID: 23E120 Page 126 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC402.D
Aeq On 17 May 2023 4:32 pm
Sample 23E120-02M
Mise 25mL
(QT Reviewed)
Vial: 24
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:48 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
83) 2-Chlorotoluene 18.06 91 2132973 9.01 ug/l 95
84) 4-Chlorotoluene 18.12 91 1897297 9.76 ug/l 95
85) tert-Butylbenzene 18.50 134 501551 9.94 ug/l 90
86) 1, 2, 4-Trimethylbenzene 18.54 105 1701174 8.01 ug/l 97
87) see-Butylbenzene 18.74 105 3055245 10.07 ug/l 100
88) p-Isopropyltoluene 18.91 119 2329232 9.78 ug/l 99
89) l,3-Diehlorobenzene 19.01 146 1029060 9.95 ug/l 99
90 ) l,4-Diehlorobenzene 19.14 146 996002 9.89 ug/l 99
91) n-Butylbenzene 19.34 91 2172502 9.58 ug/l 99
92) l,2-Diehlorobenzene 19.53 146 826314 10.14 ug/l 100
93) l,2-Dibromo-3-ehloropropan 20.31 157 38297 10.76 ug/l 95
94) l,2,4-Triehlorobenzene 21.17 180 375164 10.93 ug/l 99
95) Hexaehlorobutadiene 21.30 225 284591 9.84 ug/l 99
96) Naphthalene 21.45 128 424435 9.65 ug/l 100
97) l,2,3-Triehlorobenzene 21.70 180 255648 10.91 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC402.D V067D26.M Thu May 18 08:48:44 2023 Page 3
REPORT ID: 23E120 Page 127 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC402.D
Aeq On 17 May 2023 4:32 pm
Sample 23E120-02M
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: May 18 8:48 2023 Quant Results File:
Method
Title
Last Update
Response via
fA-bundance
85000001::;:
i~
Ie: 8000000i~ 1§
'5 ," '0: .:0
7500000ie i~
10 1'1
I
7000000
1
I
1 65000001
6000000i '
i
55000001 '
5000000
i i
4500000' !
4000000!
3500000; ,
!
3000000;
2500000!
i
I
i i 1
2000000]
15000001
1000000;
500000:
Time-->
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC402.D
Q)
e:
Q)
~
E
REC402.D V067D26.M Thu May 18 08:48:46 2023
24
VLu
67
1. 00
V067D26.RES
Page 4
REPORT ID: 23E120 Page 128 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC403.D Vial: 25
Operator: VLu Acq On 17 May 2023 4:58 pm
Sample 23E120-02S
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 18 8:49 2023
Inst 67
Multiplr: 1.00
Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26 .,,--
Internal Standards
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
"' System Monitoring Compounds
. 36) Dibromofluoromethane
Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.17 114
15.62 117
19.50 152
1931294
1475561
505645
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.03
0.02
0.02
8.22
9.32
12.99
17.62
1. 88
2.18
2.28
2.68
2.72
2.80
2.98
3.53
3.59
3.61
3.80
3.94
4.25
4.31
4.54
4.56
4.79
4.83
5.07
5.73
5.92
5.97
6.66
6.94
7.24
7.35
7.71
111 518610 11.27 0.03
Recovery
ug/l
112.70%
ug/l
116/.Bo%
ug/l r
103.90%
ug/V
65 410552 11.68 0.03
Recovery
98 2132484 10.39 0.02
Recovery
95 654850 9.59 0.02
Recovery 95.90%
85 555563
50 969248
62 1083868
94 602827
64 774286
67 1397640
101 822258
56 149915
151 457217
43 432930
61 1038126
59 627406
142 955840
43 294100
76 2609342
49 892730
53 567877
73 1114881
96 720121
45 2463585
63 1250215
43 648510
59 1659275
72 153220
77 773916
96 731210
83 1245037
Qvalue
9.42 ug/l 99
9.47 ug/l 93
11.95 ug/l 100
10.78 ug/l 100
13.03 ug/l 98
12.44 ug/l 100
12.40 ug/l 99
33.14 ug/l 92
10.58 ug/l 100
55.89 ug/l 99
9.79 ug/l 99
294.86 ug/l 99
10.30 ug/l 99
11.68 ug/l 99
11.81 ug/l 100
9.95 ug/l 100
55.89 ug/l 99
12.08 ug/l 100
9.85 ug/l 99
11.54 ug/l 99
10.56 ug/l 100
9.58 ug/l 100
11.34 ug/l 99
59.47 ug/l 100
10.02 ug/l 99
10.54 ug/l 99
13.02 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC403.D V067D26.M Thu May 18 08:49:09 2023 Page 1
REPORT ID: 23E120 Page 129 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC403.D
Acq On 17 May 2023 4:58 pm
Sample 23E120-02S
Mise 25mL
(QT Reviewed)
Vial: 25
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:49 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) l,l,l-Trichloroethane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
82) l,3,5-Trimethylbenzene
8.09
8.18
8.59
8.62
8.94
9.13
9.28
9.50
9.51
10.75
10.82
11.10
11.54
11.63
11.63
12.26
12.59
13.13
13.50
13.54
13.76
13.82
14.20
14.26
14.62
14.96
15.28
15.68
15.76
15.78
15.91
16.64
16.71
17.24
17.25
17.52
17.74
17.82
17.82
17.88
18.04
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
105
313364
92052
1253720
854086
333287
895046
269592
2774390
537985
674095
1455191
647291
712124
53781
260240
1747866
930795
2663197
667359
426763
354644
1118591
704311
517104
383080
312950
1084476
1553686
468463
2983204
4379708
2165205
685847
2628402
186531
372481
99696
105248
3399792
498943
2047063
(#) = qualifier out of range (m) = manual integration
REC403.D V067D26.M Thu May 18 08:49:09 2023
11.13 ug/l
11.02 ug/l
11.62 ug/l
10.69 ug/l
10.08 ug/l
13.86 ug/l
11.84 ug/l
10.76 ug/l
11.88 ug/l
10.58 ug/l
12.11 ug/l
11.13 ug/l
11.31 ug/l
238.20 ug/l
11.15 ug/l
61.54 ug/l
11.36 ug/l
10.15 ug/l
11.28 ug/l
9.97 ug/l
11.38 ug/l
60.88 ug/l
11.47 ug/l
9.93 ug/l
11.08 ug/l
11.29 ug/l
9.66 ug/l
10.38 ug/l
10.67 ug/l
10.11 ug/l
20.51 ug/l
10.76 ug/l
~.44 ug/l
9.99 ug/l
10.40 ug/l
10.74 ug/l
10.69 ug/l
10.85 ug/l
9.25 ug/l
9.64 ug/l
8.93 ug/l
Qvalue
99
97
97
97
100
99
97
99
100
99
99
98
99
98
97
97
99
100
95
98
98
99
97
99
100
98
99
100
100
100
100
100
84
100
99
100
99
100
100
99
99
Page 2
REPORT ID: 23E120 Page 130 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E17\REC403.D
Aeq On 17 May 2023 4:58 pm
Sample 23E120-02S
Mise 25mL
(QT Reviewed)
Vial: 25
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:49 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
83) 2-Chlorotoluene 18.06 91 2050337 8.65 ug/l 94
84) 4-Chlorotoluene 18.12 91 1807811 9.29 ug/l 94
85 ) tert-Butylbenzene 18.50 134 478704 9.47 ug/l 90
86) l,2,4-Trimethylbenzene 18.54 105 1584004 7.45 ug/l 97
87) see-Butylbenzene 18.74 105 2850386 9.38 ug/l 100
88) p-Isopropyltoluene 18.90 119 2181963 9.15 ug/l 100
89 ) l,3-Diehlorobenzene 19.01 146 982801 9.49 ug/l 99
90) l,4-Diehlorobenzene 19.12 146 952262 9.45 ug/l 99
91 ) n-Butylbenzene 19.34 91 2062902 9.08 ug/l 99
92) l,2-Diehlorobenzene 19.53 146 812876 9.96 ug/l 99
" 93) l,2-Dibromo-3-ehloropropan 20.31 157 39071 10.96 ug/l 98
94) 1, 2, 4-Triehlorobenzene 21.17 180 368295 10.71 ug/l 99
r", 95) Hexaehlorobutadiene 21. 30 225 266843 9.22 ug/l 99
96) Naphthalene 21.45 128 453173 10.29 ug/l 99
97) l,2,3-Triehlorobenzene 21.70 180 265531 11.31 ug/l 100
(#) = qualifier out of range (m) = manual integration
REC403.D V067D26.M Thu May 18 08:49:10 2023 Page 3
REPORT ID: 23E120 Page 131 of 560
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI7\REC403.D
Aeq On 17 May 2023 4:58 pm
Sample 23E120-02S
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
25
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: May 18 8:49 2023 Quant Results File: V067D26.RES
Method D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration Abundance---------------------~ ------~----~--~Trc:REC-40-3JJ-~~-----~--~ ---~-----------~-
8500000':2
'I-'"
i~
8000000ii
E 'e .0
!::I
:!E
7500000ie I~
15
II
70000001 i
6500000
6000000: :
5500000
j; , .
1
5000000!
4500000:
4000000i
3500000
3000000]
2500000·
2000000,
1500000
1000000:
:2
I-'"
gi
rn
Cl.
~ o
:E
" '" 6
E e
.0
is
c-:..
0------· -.----------~----'~_._--_~ __ --_. ~~~ __ ~.-·--~-~-c----~. ~ __ .____ -"-_-___ ~_-;~--~ ... _~ _~ __
Time--> 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REC403.D V067D26.M Thu May 18 08:49:12 2023 Page 4
REPORT ID: 23E120 Page 132 of 560
INITIAL CALIBRATIONS
REPORT ID: 23E120 Page 133 of 560
Lab Name
Lab Code
Lab File
:
:
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
EMAX Laboratories, Inc. Project lCAL
EMAX SDG No I CAL
ID: RDC587 BFB Injection Date: 04/26/23
Instrument ID: 67 BFB Injection Time: 08:20
1 1 % RELATIVE 1
1 m/ e 1 ION ABUNDANCE CRITERIA 1 ABUNDANCE 1
1=====1========================================1================1
1 50 1 15 -40% of mass 95 1 20.379 1
1 75 1 30 -60% of mass 95 1 45.113 1
1 95 1 Base Peak, 100% relative abundance __ 1 100.000 1
1 96 1 5 -9% of mass 95 1 6.378 1
1 173 1 Less than 2% of mass 174 1 0.000 (0)1 1
1 174 1 Greater than 50% of mass 95 1 76.492 1
1 175 1 5 -9% of mass 174 1 5.532(7.23)1 1
1 176 1 95 -101% % of mass 174 1 76.007(99.37)1 1
1 177 1 5 -9% % of mass 176 1 4.717(6.21)2 1
1 __ 1 1 1
1-Value is % mass 174 2-Value is % mass 176
This check applies to the following Calibration Standards:
EPA 1 LAB LAB 1 DATE 1 TIME 1
1 SAMPLE NO. 1 SAMPLE ID 1 FILE ID 1 ANALYZED 1 ANALYZED 1
1====================1================1============1==========1==========1
1IVSTDO.3 IV067D261 IRDC588 1 04/26/23 1 08:46 1
2IVSTDO.5 IV067D262 \RDC589 1 04/26/23 \ 09:11 \
31VSTD1 IV067D263 \RDC590 \ 04/26/23 1 09:37 1
41VSTD2 IV067D264 \RDC591 \ 04/26/231 10:03 \
51vSTD5 IV067D265 IRDC592 1 04/26/23 \ 10:28 \
6\VSTD10 IV067D266 IRDC593 \ 04/26/23 \ 10: 54 \
71VSTD20 IV067D267 IRDC594 \ 04/26/23 1 11: 19 \
8\VSTD30 IV067D268 IRDC595 \ 04/26/23 1 11:45 1
9\VSTD100 \V067D2610 \RDC597 \ 04/26/23 \ 12:36 \
1olVSTD50 \V067D2611 \ RDC600 1 04/26/23 \ 13: 53 \
1l\VSTD10 1 IV067D2601 \RDC603 104/26/23 \ 15:39 \
1 1 1 1 1 1
REPORT ID: 23E120 Page 134 of 560
Tnnrrumrnr Tn ~h7
Beginning DateTime :04/26/23 08:46
Spike Units :PPB
IC File :RDC593
M IDX Parameters
======= =====================================
1 1,4-DIFLUOROBENZENE
2 Dichlorodifluoromethane
3 Dichlorotetrafluoroethane
4 Chloromethane
5 Vinyl chloride
6 Bromomethane
7 Chloroethane
8 Dichlorofluoromethane
9 Trichlorofluoromethane
10 sec-Propyl alcohol
5 11 Acrolein
12 1,1,2-Trichloro-l,2,2-trifluoroethane
5 13 Acetone
14 1,1-Dichloroethene
25 15 tert-Butyl alcohol
16 Iodomethane
17 Methyl acetate
10 18 Acetonitrile
19 Carbon disulfide
20 Methylene chloride
5 21 Acrylonitrile
22 tert-Butyl methyl ether (MTBE)
23 trans-l,2-Dichloroethene
24 Isopropyl ether (DIPE)
25 1,1-Dichloroethane
26 Vinyl acetate
25 27 2-Butanol
28 tert-Butyl ethyl ether (ETBE)
5 29 2-Butanone
30 2,2-Dichloropropane
31 cis-l,2-Dichloroethene
32 Chloroform
33 Bromochloromethane
34 Tetrahydrofuran
5 35 tert-Amyl alcohol
36 Dibromofluoromethane
37 Cyclohexane
38 1,1,1-Trichloroethane
39 2,2,4-Trimethylpentane
40 1,1-Dichloropropene
41 Carbon tetrachloride
42 tert-Amyl methyl ether (TAME)
43 1,2-Dichloroethane-d4
44 Benzene
45 1,2-Dichloroethane
46 Trichloroethene
47 Methylcyclohexane
48 1,2-Dichloropropane
49 Bromodichloromethane
20 50 1,4-Dioxane
51 Dibromomethane
52 2-Chloroethyl vinyl ether
5 53 4-Methyl-2-pentanone
54 cis-l,3-Dichloropropene
55 CHLOROBENZENE-D5
56 Toluene-d8
57 Toluene
58 trans-1,3-Dichloropropene
59 Ethyl methacrylate
60 1,1,2-Trichloroethane
5 61 2-Hexanone
62 1,3-Dichloropropane
63 Tetrachloroethene
64 Dibromochloromethane
65 1,2-Dibromoethane
66 1-Chlorohexane
67 Chlorobenzene
68 1,1,1,2-Tetrachloroethane
69 Ethylbenzene
2 70 m-Xylene & p-Xylene
71 o-Xylene
72 Styrene
73 Isopropylbenzene
74 1,2-DICHLOROBENZENE-D4
75 Bromoform
76 1,1,2,2-Tetrachloroethane
77 4-Bromofluorobenzene
78 1,2,3-Trichloropropane
79 trans-1,4-Dichloro-2-butene
80 n-Propylbenzene
81 Bromobenzene
82 1,3,5-Trimethylbenzene
83 2-Chlorotoluene
84 4-Chlorotoluene
85 tert-Butylbenzene
86 1,2,4-Trimethylbenzene
87 sec-Butylbenzene
88 p-Isopropyltoluene
89 1,3-Dich1orobenzene
90 1,4-Dichlorobenzene
91 n-Butylbenzene
92 1,2-Dichlorobenzene
93 1,2-Dibromo-3-chloropropane
94 1,2,4-Trichlorobenzene
95 Hexachlorobutadiene
96 Naphthalene
97 1,2,3-Trichlorobenzene
~mount -Nom~nal Amount * M
Ave_%RSD 6.8 Max %RSD 14.7
.3 .5
08:46 09:11
RDC588 RDC589
====== ======
1 1
0.289 0.303
------------
0.594 0.462
0.414 0.445
0.262 0.271
0.269 0.290
0.529 0.597
0.307 0.323
------------
------0.027
0.209 0.228
------------
0.496 0.543
0.010 0.011
0.411 0.456
0.132 0.134
------------
1.034 1.022
------0.560
------0.043
0.421 0.457
0.345 0.378
0.969 1.082
0.552 0.621
------------
------------
0.678 0.747
------------
0.374 0.415
0.308 0.354
0.460 0.491
0.127 0.132
------------
------------
0.191 0.218
0.457 0.492
0.366 0.414
------1.255
0.149 0.166
0.276 0.327
0.098 0.108
0.158 0.177
1.213 1.314
0.210 0.232
0.291 0.315
------0.533
0.249 0.290
0.282 0.312
------------
------0.103
------------
0.130 0.125
0.343 0.405
1 1
1.157 1.355
1. 625 1.838
0.318 0.364
------------
0.179 0.197
0.113 0.104
0.363 0.407
0.317 0.351
0.200 0.219
0.151 0.176
0.649 0.721
0.899 0.997
0.258 0.294
1.768 1.953
1.318 l.458
1.187 1.328
0.876 0.993
1.493 1.716
1 1
------0.326
0.611 0.672
1.274 1. 363
0.167 0.170
------------
6.542 7.385
0.939 1.021
4.064 4.511
4.683 5.130
3.559 3.704
0.886 0.957
3.769 4.122
5.371 5.722
3.985 4.404
1. 979 2.008
1.836 1. 997
------3.875
1.575 1.575
------------
0.575 0.585
0.484 0.469
0.92410.731
0.458 0.409
------
1 2 5 10 20
09:37 10:03 10:28 10:54 11:19
RDC590 RDC591 RDC592 RDC593 RDC594
====== ====== ====== ====== ======
1 1 1 1 1
0.337 0.302 0.289 0.326 0.292
------------------------------
0.592 0.536 0.515 0.567 0.492
0.504 0.487 0.475 0.531 0.458
0.299 0.287 0.286 0.324 0.293
0.334 0.314 0.301 0.341 0.306
0.610 0.618 0.574 0.580 0.598
0.369 0.363 0.337 0.381 0.344
------------------------------
0.024 0.023 0.020 0.025 0.022
0.232 0.235 0.215 0.222 0.231
------0.051 0.044 0.039 0.035
0.566 0.576 0.562 0.543 0.585
0.011 0.011 0.011 0.011 0.011
0.462 0.485 0.491 0.493 0.511
0.125 0.120 0.119 0.142 0.125
------------------------------
1.131 1.122 1.137 1.287 1.195
0.495 0.507 0.444 0.435 0.444
0.050 0.057 0.051 0.054 0.052
0.478 0.500 0.475 0.481 0.485
0.380 0.393 0.369 0.375 0.393
1.102 1.154 1. 078 1. 098 1.151
0.614 0.645 0.598 0.604 0.632
0.288 0.334 0.344 0.385 0.340
------------------------------
0.785 0.835 0.777 0.735 0.757
0.012 0.013 0.013 0.014 0.013
0.403 0.431 0.402 0.394 0.413
0.361 0.372 0.352 0.357 0.377
0.496 0.526 0.483 0.487 0.514
0.150 0.153 0.145 0.147 0.151
0.044 0.046 0.043 0.044 0.040
------0.008 0.008 0.010 0.009
0.252 0.233 0.238 0.252 0.248
0.585 0.545 0.548 0.614 0.578
0.419 0.437 0.406 0.412 0.435
1. 594 1.471 1.442 1.619 1.453
0.171 0.181 0.169 0.170 0.179
0.337 0.351 0.328 0.337 0.358
0.114 0.124 0.116 0.122 0.123
0.189 0.183 0.181 0.192 0.184
1. 353 1.401 1. 304 1. 319 1. 403
0.239 0.253 0.235 0.236 0.240
0.331 0.348 0.325 0.328 0.346
0.622 0.577 0.591 0.688 0.635
0.301 0.320 0.294 0.298 0.316
0.330 0.331 0.319 0.325 0.342
0.001 0.001 0.001 0.001 0.001
0.117 0.128 0.119 0.120 0.125
------0.049 0.049 0.051 0.054
0.138 0.159 0.144 0.152 0.148
0.407 0.433 0.421 0.428 0.453
1 1 1 1 1
1.480 1.370 1.393 1.467 1.460
1.833 1.904 1.762 1.777 1.876
0.385 0.417 0.397 0.409 0.427
0.247 0.281 0.273 0.290 0.299
0.214 0.228 0.211 0.211 0.218
0.115 0.132 0.121 0.129 0.125
0.407 0.443 0.410 0.416 0.427
0.352 0.375 0.338 0.348 0.372
0.222 0.241 0.233 0.238 0.247
0.185 0.202 0.188 0.192 0.195
0.728 0.789 0.748 0.767 0.824
l. 030 1.067 0.992 1. 003 1.065
0.287 0.308 0.289 0.295 0.316
1.998 2.098 1.958 1.989 2.131
l.452 1.539 1.435 1.466 1.564
l.360 l.438 l.347 1.375 1.478
1.008 1.070 1.016 1.054 1.141
1.752 1.891 1.774 l. 799 1.939
1 1 1 1 1
0.315 0.361 0.334 0.351 0.364
0.690 0.738 0.674 0.687 0.687
1.413 1. 303 1.319 1. 377 1.358
0.193 0.196 0.186 0.189 0.186
0.170 0.188 0.185 0.192 0.198
7.316 7.668 7.244 7.217 7.832
1.035 1.063 1.000 0.988 1.057
4.454 4.741 4.464 4.463 4.855
5.156 4.784 4.428 4.427 4.755
3.617 4.300 3.895 3.908 4.214
0.991 1.040 0.966 0.963 1.078
4.108 4.428 4.125 4.155 4.517
5.873 6.375 6.009 6.038 6.594
4.489 4.936 4.697 4.780 5.279
2.003 2.121 1. 980 2.010 2.158
1.941 2.064 l. 924 1.944 2.099
4.012 4.503 4.421 4.552 5.041
1. 591 1.686 1.555 1. 586 1.688
0.056 0.070 0.071 0.071 0.072
0.580 0.652 0.663 0.691 0.781
0.504 0.626 0.583 0.580 0.676
0.723 0.786 0.809 0.875 0.934
0.397 0.449 0.439 0.464 0.512
---------------
30
11:45
RDC595
====::;:.=
1
0.301
------
0.483
0.442
0.295
0.310
0.597
0.343
------
0.024
0.229
0.038
0.561
0.012
0.515
0.135
------
1.192
0.444
0.057
0.505
0.392
1.156
0.638
0.363
------
0.771
0.014
0.409
0.378
0.510
0.154
0.044
0.010
0.252
0.585
0.430
1.474
0.179
0.355
0.128
0.190
1.400
0.245
0.346
0.651
0.318
0.350
0.001
0.129
0.059
0.163
0.464
1
1.445
1.849
0.441
0.316
0.224
0.138
0.444
0.365
0.253
0.202
0.810
1.062
0.314
2.105
1. 508
1.452
1.139
l. 898
1
0.376
0.715
1.341
0.191
0.205
7.438
1. 051
4.638
4.575
4.141
1. 038
4.346
6.237
5.034
2.125
2.081
4.818
l. 663
0.078
0.773
0.633
l. 001
0.523
---
Column Spec :RTX502.2 ID :0.25MM
Ewhng IJate'1'1me ; 04/2G/23 13.53
HPChem Method :V067D26
50 100
13: 53 12:36
RDC600 RDC597 AV_RRF %_RSD AV_Rt_M
====== ====== ====== ====== =======
1 1 1 0 10.1420
0.291 0.322 0.305 5.66 1.8533
------------0.000 0.00 0.0000
------------0.530 9.57 2.1166
------------0.470 8.00 2.2371
0.286 0.293 0.290 5.68 2.6806
0.303 0.309 0.308 6.63 2.6967
0.566 0.549 0.582 4.77 2.7910
0.325 0.342 0.343 6.58 2.9577
------------0.000 0.00 0.0000
0.022 0.024 0.023 8.06 3.5109
0.219 0.217 0.224 3.75 3.5771
0.035 0.038 0.040 14.65 3.5907
0.530 0.529 0.549 4.80 3.7632
0.011 0.013 0.011 6.45 3.9126
0.489 0.491 0.480 6.34 4.2302
0.121 0.151 0.130 8.01 4.2814
------------0.000 0.00 0.0000
1. 096 1.227 1.144 7.27 4.4991
0.423 0.430 0.465 9.90 4.5253
0.052 0.059 0.053 8.95 4.7543
0.471 0.504 0.478 5.25 4.7986
0.379 0.381 0.378 3.80 5.0251
1.137 1.123 1.105 5.08 5.6929
0.617 0.610 0.613 4.26 5.8769
0.346 0.403 0.350 9.85 5.9369
------------0.000 0.00 0.0000
0.741 0.749 0.757 5.33 6.6309
0.013 0.015 0.013 6.91 6.9104
0.392 0.367 0.400 4.81 7.1993
0.364 0.368 0.359 5.58 7.3059
0.496 0.489 0.495 3.69 7.6858
0.145 0.152 0.146 6.20 8.0526
0.040 0.045 0.043 4.96 8.1378
0.009 ------0.009 9.29 8.1653
0.242 0.256 0.238 8.45 8.1943
0.558 0.623 0.559 9.25 8.5654
0.414 0.404 0.414 4.92 8.5786
1.384 1.572 1.474 7.68 8.7399
0.174 0.174 0.171 5.48 8.9249
0.338 0.336 0.334 6.91 9.1017
0.120 0.126 0.118 7.89 9.2478
0.176 0.190 0.182 5.46 9.2902
1.347 1.294 1.335 4.46 9.4684
0.225 0.230 0.235 5.01 9.4874
0.335 0.335 0.330 5.21 10.7235
0.619 0.685 0.622 8.11 10.8098
0.310 0.313 0.301 7.04 11.0845
0.333 0.336 0.326 5.74 11. 5199
0.001 0.001 0.001 6.36 11.6116
0.119 0.127 0.121 6.59 11.6005
0.055 0.062 0.054 9.00 12.1959
0.147 0.164 0.147 9.02 12.2461
0.440 0.449 0.424 8.11 12.5689
1 1 1 0 15.6023
1. 393 l. 384 1.390 6.69 12.9723
1. 769 1.550 1.778 6.30 13.1081
0.415 0.436 0.401 9.38 13.4866
0.291 0.323 0.290 8.35 13.5203
0.208 0.223 0.211 6.90 13.7467
0.126 0.142 0.125 9.36 13.8095
0.408 0.438 0.416 5.77 14.1879
0.355 0.355 0.353 4.74 14.2434
0.239 0.252 0.234 7.11 14 .6014
0.186 0.202 0.188 8.26 14.9462
0.790 0.779 0.761 6.75 15.2721
l.028 0.998 1.014 4.93 15.6622
0.307 0.307 0.298 5.81 15.7499
2.000 ------2.000 5.46 15.7630
l.284 ------1.447 6.45 15.8946
1. 395 1.281 1.364 6.33 16.6251
l. 099 l.061 l.046 7.51 16.6952
1.789 ------1.783 7.40 17.2275
1 1 1 0 19.4889
0.363 0.404 0.355 7.64 17.2389
0.668 0.717 0.686 5.07 17.5062
1. 340 1.419 1.351 3.39 17.6041
0.175 0.194 0.184 5.75 17.7166
0.192 0.205 0.192 5.86 17.8215
6.774 ------7.269 5.54 17.8135
1.033 1.054 1.024 3.78 17.8671
4.620 ------4.534 4.94 18.0278
4.864 4.061 4.686 7.12 18.0453
3.790 3.358 3.849 7.90 18.1140
1. 052 1.026 1.000 5.78 18.4807
4.283 ------4.206 5.24 18.5246
5.853 ------6.008 6.06 18.7308
4.862 ------4.718 8.13 18.8899
2.095 2.012 2.049 3.31 19.0009
2.056 1.995 1.994 4.18 19.1237
4.717 ------4.492 8.74 19.3429
l.626 l.590 1.613 3.04 19.5181
0.070 0.077 0.071 9.29 20.2926
0.756 0.744 0.680 11.99 2l.1561
0.606 0.565 0.573 1l. 91 2l. 2861
0.913 1.011 0.871 11.97 21.4337
0.487 0.503 0.464 9.14 2l.6879
----------------
REPORT ID: 23E120 Page 135 of 560
Instrument ID :67
Beginning DateTime :04/26/23 08:46
Spike Units :PPB
IC File :RDC593
M lOX Parameters
======= =====================================
1 1,4-DIFLUOROBENZENE
2 Dichlorodifluoromethane
3 Dichlorotetrafluoroethane
4 Chloromethane
5 Vinyl chloride
6 Bromomethane
7 Chloroethane
8 Dichlorofluoromethane
9 Trichlorofluoromethane
10 sec-Propyl alcohol
5 11 Acrolein
12 1,1,2-Trichloro-1,2,2-trifluoroethane
5 13 Acetone
14 1,1-Dichloroethene
25 15 tert-Butyl alcohol
16 Iodomethane
17 Methyl acetate
10 18 Acetonitrile
19 Carbon disulfide
20 Methylene chloride
5 21 Acrylonitrile
22 tert-Butyl methyl ether (MTBE)
23 trans-l,2-Dichloroethene
24 Isopropyl ether (DIPE)
25 1,1-Dichloroethane
26 Vinyl acetate
25 27 2-Butanol
28 tert-Butyl ethyl ether (ETBE)
5 29 2-Butanone
30 2,2-Dichloropropane
31 cis-1,2-Dichloroethene
32 Chloroform
33 Bromochloromethane
34 Tetrahydrofuran
5 35 tert-Amyl alcohol
36 Dibromofluoromethane
37 Cyclohexane
38 1,1,1-Trichloroethane
39 2,2,4-Trimethylpentane
40 1,1-Dichloropropene
41 Carbon tetrachloride
42 tert-Amyl methyl ether (TAME)
43 1,2-Dichloroethane-d4
44 Benzene
45 1,2-Dichloroethane
46 Trichloroethene
47 Methylcyclohexane
48 1,2-Dichloropropane
49 Bromodichloromethane
20 50 l,4-Dioxane
51 Dibromomethane
52 2-Chloroethyl vinyl ether
5 53 4-Methyl-2-pentanone
54 cis-1,3-Dichloropropene
55 CHLOROBENZENE-D5
56 Toluene-d8
57 Toluene
58 trans-l,3-Dichloropropene
59 Ethyl methacrylate
60 1,1,2-Trichloroethane
5 61 2-Hexanone
62 1,3-Dichloropropane
63 Tetrachloroethene
64 Dibromochloromethane
65 1,2-Dibromoethane
66 1-Chlorohexane
67 Chlorobenzene
68 1,1,1,2-Tetrachloroethane
69 Ethylbenzene
2 70 m-Xylene & p-Xylene
71 o-Xylene
72 Styrene
73 Isopropylbenzene
74 1,2-DICHLOROBENZENE-D4
75 Bromoform
76 1,1,2,2-Tetrachloroethane
77 4-Bromofluorobenzene
78 1,2,3-Trichloropropane
79 trans-1,4-Dichloro-2-butene
80 n-Propylbenzene
81 Bromobenzene
82 1,3,5-Trimethylbenzene
83 2-Chlorotoluene
84 4-Chlorotoluene
85 tert-Butylbenzene
86 1,2,4-Trimethylbenzene
87 sec-Butylbenzene
88 p-Isopropyltoluene
89 1,3-Dichlorobenzene
90 1,4-Dichlorobenzene
91 n-Butylbenzene
92 1,2-Dichlorobenzene
93 1,2-Dibromo-3-chloropropane
94 1,2,4-Trichlorobenzene
95 Hexachlorobutadiene
96 Naphthalene
97 1,2,3-Trichlorobenzene
----
INITIAL_CALIBRATION -RELATIVE_RESPONSE_FACTOR(%REC)
.3 .5 1 2
08:46 09:11 09:37 10:03
RDC588 RDC589 RDC590 RDC591
====== ====== ====== ======
1 1 1 1
95 99 110 99
--------------«---------
112 87 112 101
88 95 107 104
90 93 103 99
87 94 108 102
91 103 105 106
90 94 108 106
------------------------
------117 104 100
93 102 104 105
------------------128
90 99 103 105
91 96 99 96
86 95 96 101
102 103 96 92
------------------------
90 89 99 98
------120 106 109
------81 94 108
88 96 100 105
91 100 101 104
88 98 100 104
90 101 100 105
------------82 95
------------------------
90 99 104 110
------------92 100
94 104 101 108
86 99 101 104
93 99 100 106
87 90 103 105
------------102 107
------------------89
80 92 106 98
82 88 105 97
88 100 101 106
------85 108 100
87 97 100 106
83 98 101 105
83 92 97 105
87 97 104 101
91 98 101 105
89 99 102 108
88 95 100 105
------86 100 93
83 96 100 106
87 96 101 102
------------93 98
------85 97 106
------------------91
88 85 94 108
81 96 96 102
1 1 1 1
83 97 106 99
91 103 103 107
79 91 96 104
------------85 97
85 93 101 108
90 83 92 106
87 98 98 106
90 99 100 106
85 94 95 103
80 94 98 107
85 95 96 104
89 98 102 105
87 99 96 103
88 98 100 105
91 101 100 106
87 97 100 105
84 95 96 102
84 96 98 106
1 1 1 1
------92 89 102
89 98 101 108
94 101 105 96
91 92 105 107
------------89 98
90 102 101 105
92 100 101 104
90 99 98 105
100 109 110 102
92 96 94 112
89 96 99 104
90 98 98 105
89 95 98 106
84 93 95 105
97 98 98 104
92 100 97 104
------86 89 100
98 98 99 105
------------79 99
85 86 85 96
84 82 88 109
106 84 83 90
__ 9_91 __ 8_8 86 97
------
5 10 20 30
10:28 10:54 11:19 11:45
RDC592 RDC593 RDC594 RDC595
====== ====== ====== ======
1 1 1 1
95 107 96 99
------------------------
97 107 93 91
101 113 97 94
99 112 101 102
98 111 99 101
99 100 103 103
98 111 100 100
------------------------
87 109 96 104
96 99 103 102
110 98 88 95
102 99 107 105
97 99 99 109
102 103 106 107
92 109 96 104
------------------------
99 112 104 104
95 94 95 95
96 102 98 108
99 101 101 106
98 99 104 104
98 99 104 105
98 99 103 104
98 110 97 104
------------------------
103 97 100 102
100 108 100 108
100 98 103 102
98 99 105 105
98 98 104 103
99 101 103 105
100 102 93 102
89 111 100 111
100 106 104 106
98 110 103 105
98 100 105 104
98 110 99 100
99 99 105 105
98 101 107 106
98 103 104 108
99 105 101 104
98 99 105 105
100 100 102 104
98 99 105 105
95 111 102 105
98 99 105 106
98 100 105 107
91 100 100 107
98 99 103 107
91 94 100 109
98 103 101 111
99 101 107 109
1 1 1 1
100 106 105 104
99 100 106 104
99 102 106 110
94 100 103 109
100 100 103 106
97 103 100 110
99 100 103 107
96 99 105 103
100 102 106 108
100 102 104 107
98 101 108 106
98 99 105 105
97 99 106 105
98 99 107 105
99 101 108 104
99 101 108 106
97 101 109 109
99 101 109 106
1 1 1 1
94 99 103 106
98 100 100 104
98 102 101 99
101 103 101 104
96 100 103 107
100 99 108 102
98 96 103 103
98 98 107 102
94 94 101 98
101 102 109 108
97 96 108 104
98 99 107 103
100 100 110 104
100 101 112 107
97 98 105 104
96 97 105 104
98 101 112 107
96 98 105 103
100 100 101 110
98 102 115 114
102 101 118 110
93 100 I 107 115
95 100 110 113
--------------F'L""L-"'i< J....6r7 C--
SlA-~I I P-5
Column Spec :RTX502.2 ID :0.25MM
Ending DateTime :04/26/23 13:53
HPChem Method :V067D26
50 100
13:53 12:36
RDC600 RDC597 AvDRec %_RSD Av_Rt_M
====== ====== ====== ====== =======
1 1 1 0 10.1420
95 106 4.5 5.66 1.8533
------------0.000 0.00 0.0000
------------7.9 9.57 2.1166
------ ------6.3 8.00 2.2371
99 101 3.9 5.68 2.6806
98 100 4.5 6.63 2.6967
97 94 3.8 4.77 2.7910
95 100 4.8 6.58 2.9577
------------0.000 0.00 0.0000
96 104 6.8 8.06 3.5109
98 97 3.3 3.75 3.5771
88 95 10.7 14.65 3.5907
97 96 3.8 4.80 3.7632
102 115 3.6 6.45 3.9126
102 102 4.7 6.34 4.2302
93 116 6.5 8.01 4.2814
------------0.000 0.00 0.0000
96 107 5.7 7.27 4.4991
91 92 8.1 9.90 4.5253
98 111 6.7 8.95 4.7543
99 105 3.6 5.25 4.7986
100 101 2.5 3.80 5.0251
103 102 3.5 5.08 5.6929
101 100 2.9 4.26 5.8769
99 115 7.1 9.85 5.9369
------------0.000 0.00 0.0000
98 99 3.6 5.33 6.6309
100 115 4.8 6.91 6.9104
98 92 3.6 4.81 7.1993
101 103 3.6 5.58 7.3059
100 99 2.7 3.69 7.6858
99 104 4.5 6.20 8.0526
93 105 4.1 4.96 8.1378
100 ------7.4 9.29 8.1653
102 108 6.1 8.45 8.1943
100 111 6.9 9.25 8.5654
100 98 3.2 4.92 8.5786
94 107 5.5 7.68 8.7399
102 102 3.6 5.48 8.9249
101 101 4.3 6.91 9.1017
102 107 6 7.89 9.2478
97 104 4 5.46 9.2902
101 97 3.4 4.46 9.4684
96 98 3.4 5.01 9.4874
102 102 3.7 5.21 10.7235
100 110 6.1 8.11 10.8098
103 104 4.8 7.04 11. 0845
102 103 4 5.74 11.5199
99 111 0 6.36 11.6116
98 105 4.8 6.59 11. 6005
102 115 7.1 9.00 12.1959
100 112 6.9 9.02 12.2461
104 106 5.7 8.11 12.5689
1 1 1 0 15.6023
100 100 4.3 6.69 12.9723
99 87 4.6 6.30 13.1081
103 109 7 9.38 13.4866
100 111 5.9 8.35 13.5203
99 106 4.8 6.90 13.7467
101 114 7.1 9.36 13.8095
98 105 4.2 5.77 14.1879
101 101 3.3 4.74 14.2434
102 108 5.5 7.11 14.6014
99 107 5.7 8.26 14.9462
104 102 5.1 6.75 15.2721
101 98 3.6 4.93 15.6622
103 103 4.3 5.81 15.7499
100 ------3.7 5.46 15.7630
89 ------4.7 6.45 15.8946
102 94 4.7 6.33 16.6251
105 101 5.5 7.51 16.6952
100 ------5 7.40 17.2275
1 1 1 0 19.4889
102 114 5.9 7.64 17.2389
97 105 3.5 5.07 17.5062
99 105 2.6 3.39 17.6041
95 105 4.7 5.75 17.7166
100 107 4.2 5.86 17.8215
93 ------4 5.54 17.8135
101 103 2.9 3.78 17.8671
102 ------3.5 4.94 18.0278
104 87 5.4 7.12 18.0453
98 87 6.3 7.90 18.1140
105 103 4.7 5.78 18.4807
102 ------4 5.24 18.5246
97 ------4.5 6.06 18.7308
103 ------6.1 8.13 18.8899
102 98 3 3.31 19.0009
103 100 3.3 4.18 19.1237
105 ------6.5 8.74 19.3429
101 99 2.6 3.04 19.5181
99 108 5.5 9.29 20.2926
III 109 10.1 1l.99 21.1561
106 99 9.4 11.91 21.2861
105 116 10 11.97 21. 4337
105 108 7.3 9.14 21. 6879
-------------------
REPORT ID: 23E120 Page 136 of 560
Method
Title
Last Update
Response via
Total Cpnds
Compound List Report 67
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration ~
97
PK# Compound Name QIon Exp_RT Rel_RT Cal #Qual A/H ID
1 I
2 T
3 T
4 T
5 T
6 T
7 T
8 T
9 T
10 T
11 T
12 T
13 T
14 T
15 T
16 T
1)7 T
18 T
19 T
20 T
21 T
22 T
23 T
24 T
25 T
26 T
27 T
28 T
29 T
30 T
31 T
32 T
3-3 T
14 T
3'5 T
3(? S
3~ T
3~ T
39 T
4@ T
41 T
4~' T
4)' S
44 T
45 T
~6 T
47 T
48 T
49 T
50 T
51 T
~2 T
S3 T
l,4-DIFLUOROBENZENE
Dichlorodifluoromethane
Dichlorotetrafluoroethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Dichlorofluoromethane
Trichlorofluoromethane
sec-Propyl alcohol
Acrolein
l,l,2-Trichloro-1,2,2-trifluor
Acetone
l,l-Dichloroethene
tert-Butyl alcohol
Iodomethane
Methyl acetate
Acetonitrile
Carbon disulfide
Methylene chloride
Acrylonitrile
tert-Butyl methyl ether (MTBE)
trans-1,2-Dichloroethene
Isopropyl ether (DIPE)
l,l-Dichloroethane
Vinyl acetate
2-Butanol
tert-Butyl ethyl ether (ETBE)
2-Butanone
2,2-Dichloropropane
cis-1,2-Dichloroethene
Chloroform
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Dibromofluoromethane
Cyclohexane
l,l,l-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TAME)
l,2-Dichloroethane-d4
Benzene
l,2-Dichloroethane
Trichloroethene
Methyl eye lohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
114
85
85 -
50
62 '
94 r
64
67
101
45
56
151
43 ./
61 ('
59
142
43
41
76
49
53
73
96
45
63
43
45
59
72
77
96
83
130
42
59
111
84
97
57
110
119
87
65'
78-
62
10.14
1.86
0.00
2.12
2.24
2.68
2.70
2.78
2.Q6
0.00
3.50
3.57
3.57-
3.76
3.90
4.22
4.28
4.32
4.50
4.51
4.75
4.79
5.02
5.70
5.87
5.93
6.44
6.63
6.91
7.20
7.30
7.68
8.05
8.13
8.16
8.19
8.56
8.57
8.73
8.92
9.10
9.23
9.29
9.47
9.48
10.72
10.81
130
83
63
83
88 '
93
63 (
43
.11.09
11.51
11.61
11.60
12.20
12.24
1.000
0.183
0.000
0.209
0.221
0.264
0.266
0.274
0.292
0.000
0.345
0.353
0.353
0.371
0.385
0.416
0.422
0.426
0.444
0.445
0.468
0.472
0.496
0.562
0.579
0.585
0.635
0.654
0.681
0.710
0.720
0.758
0.794
0.802
0.805
0.808
0.844
0.846
0.862
0.880
0.898
0.911
0.916
0.934
0.935
1. 058
1.066
1.094
1.135
1.146
1.144
1.203
1. 208
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
1
1
2
1
1
1
1
1
1
1
1
1
1
2
1
1
1
1
1
2
2
1
1
1
2
1
1
1
1
2
1
2
1
2
1
1
1
2
1
1
1
1
1
2
1
3
2
1
1
1
2
1
3
A
A
A,
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
~ /
B 0
: 6\\\
B
B
B
B
B
B
B
B
B
B
B REPORT ID: 23E120 Page 137 of 560
$4 T
~:~
:5~ I
5'6 S
:~:~ T
~~ T
1:;~ T ,t'b T
c' .-k 'til T =, ~; '6~ T
.: !F
'(;'3 T
~,5:l T
'6'5 T
':66 T
'67 P, M
'68 T
~9 T
90 T
~1 T
~2 T
') T
'?p~ I
~,~ T
'.17:~ T ~.~ S
~~ T
'~;9 T
'~'Q T
'~l T '~'2 T
'g3 T
l34 T
:85 T
86 T
87 T
fiB T
~~ T 90 T
9'1 T §'~ T
~'~ T
t$4 T
~5 T ~';.""t. 9~ T ~t T gc
,~,
cis-1,3-Dichloropropene
CHLOROBENZENE-D5
Toluene-d8
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
l,2-DICHLOROBENZENE-D4
Bromoform
l,l,2,2-Tetrachloroethane
4-Bromofluorobenzene
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-butene
n-Propylbenzene
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1, 2, 4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
l,3-Dichlorobenzene
l,4-Dichlorobenzene
n-Butylbenzene
l,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
l,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
1, 2, 3-Trichlorobenzene
75 12.56
117 15.60
98 12.97
91 13.10
75 13.48
69 13.51
97 13.75
43 13.80
76 14.18
164 14.24
129 14.59
107 14.94
91.15.27
112 15.66
131 15.75
91 r15.76
91,15.89
91 /16.62
104 16.70
105 17.22
152 19.49
173 17.24
83 17.50
95 17.60
110 17.72
53 17.82
91 17.81
l56_ 17.87
105 18.03
91' 18.04
91. 18.12
134 18.48
105 '18.52
105 18.73
119 18.89
146 18.99
146~. 19.12
91 19.34
146/ 19.52
157 20.29
180 r 21. 15
225 21.29
128/ 21.43
180 21.68
1.239
1. 000
0.831
0.840
0.864
0.866
0.881
0.885
0.909
0.913
0.935
0.958
0.978
1.004
1.009
1. 010
1.019
1.066
1.070
1.104
1.000
0.885
0.898
0.903
0.909
0.914
0.914
0.917
0.925
0.926
0.930
0.948
0.951
0.961
0.969
0.975
0.981
0.992
1.001
1.041
1.085
1.092
1.100
1.112
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
3
2
1
1
1
1
2
1
1
3
1
1
1
1
1
1
1
1
2
3
1
2
1
2
1
1
2
1
2
1
1
1
1
1
2
2
2
2
1
1
2
2
1
2
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
~al A = Average L = Linear LO = Linear w/origin Q = Quad QO = Quad w/origin
*Qual = number of qualifiers
[ A/H = Area or Height
ID R R.T. B = R.T. & Q Q = Qvalue L = Largest A = All
~-------------------------------------------------------------------------
g V067D26.M Thu Apr 27 08:26:36 2023
€{ ;
REPORT ID: 23E120 Page 138 of 560
BFB
Data File D:\HPCHEM\1\DATA\23D26\RDC587.D
Acq On 26 Apr 2023 8:20 am
Sample BFB67D24
Misc T/CHK
MS Integration Params: RTE.P
Vial: 1
Operator: VLu
67
1. 00
Inst
Multiplr:
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title : METHOD 8260B
rbUndanj
! 50000 1 ! I I I
Ion 90.00 (94.70 to 95.70): RDC587.D
I
, .
I
i 40000
30000
20000
10000
I
! O~~~~~~~~~~~~~~~~~,TI~~~~~~~~~~~~~~~~~
rrime->
rbundance
I
45000
40000
I
I
35000
300001
I 25000
20000
150001
10000
tn/z-->
174
75
AutoFind: Scans 1042, 1043, 1044; Background Corrected with Scan 1036
I Target I ReI. to I L~w~r
Mass Mass Llmlt%
50 95 15
75 95 30
95 95 100
96 95 5
173 174 0.00
174 95 50
175 174 5
176 174 95
177 176 5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
ReI.
Abn%
20.4i
45.1
100.0
6.4
0.0
76.5
7.2
99.4
6.2/
Raw
Abn
9409
20829
46171
2945
0
35317
2554
35093
2178
RDC587.D V067D26.M Thu Apr 27 08: 24: 18 2023's ~ \ \ l ~~
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 23E120 Page 139 of 560
Quantitation Report (QT Reviewed)
~' 'i
:4Data File D: \HPCHEM\l \DATA\23D26\RDC588.D Vial: 2
Operator: VLu ~.Acq On 26 Apr 2023 8 :46 am
Sample V067D261 Inst 67
Misc 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA Multiplr: l.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.RES
5Quant Method
:STitle
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
~.DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
~~Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
;:; System Monitoring Compounds
:~ 36) Dibromofluoromethane
~; Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
! Spiked Amount 10.000
"' 77) 4-Bromofluorobenzene
,~ y
Spiked Amount 10.000
j' .0.
~ITarget Compounds
2)
4)
5)
6)
7)
8)
9)
11)
12)
13)
14)
15)
16)
17)
19)
20)
1 21)
22)
~ . 23)
24)
25)
26)
28)
30 )
31)
32)
33)
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Dichlorofluoromethane
Trichlorofluoromethane
Acrolein
l,l,2-Trichloro-1,2,2-trif
Acetone
l,l-Dichloroethene
tert-Butyl alcohol
Iodomethane
Methyl acetate
Carbon disulfide
Methylene chloride
Acrylonitrile
tert-Butyl methyl ether (M
trans-1,2-Dichloroethene
Isopropyl ether (DIPE)
l,l-Dichloroethane
Vinyl acetate
tert-Butyl ethyl ether (ET
2,2-Dichloropropane
cis-1,2-Dichloroethene
Chloroform
Bromochloromethane
R.T. QIon Response Conc Units Dev(Min)
10.15
15.60
19.49
114 2335620
117 1655304
152 455925
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
8.19 111
9.29 65
12.97 98
17.60 95
1.84
2.12
2.24
2.66
2.70
2.78
2.96
3.53
3.59
3.59
3.76
3.94
4.23
4.29
4.51
4.53
4.76
4.82
5.04
5.70
5.87
5.96
6.64
7.20
7.30
7.70
8.05
85
50
62
94
64
67
101
56
151
43
'" 61 59
142
43
76
49
53
73
/ 96
45
63
43
59
77
/ 96
83
130
13397 0.24 ug/l 0.00
Recovery 2.40%
11097 0.26 ug/l 0.00
Recovery 2.60%
57477 0.25 ug/l 0.00
Recovery = 2.50%
17424 0.28 ug/l 0.00
Recovery = 2.80%
20225
41629
29000
18339
18846
37094
21506
10713
14677
39443
34754
17577
28821
9241
72443
41193
15166
29519
24163
67892
38650
17879
47475
26237
21598
32200
8931
0.28
0.34
0.26
0.27
0.26
0.27
0.27
l. 96
0.28
4.21
0.27
6.83
0.26
0.30
0.27
0.38
1.23
0.26
0.27
0.26
0.27
0.22
0.27
0.28
0.26
0.28
0.26
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
82
99
94
97
89
94
95
74
99
84
98
93
99
76
93
98
94
97
96
95
98
88
94
93
97
97
95
(#) = qualifier out of range (m) = manual integration
RDC588.D V067D26.M Thu Apr 27 08:28:45 2023 Page 1
REPORT ID: 23E120 Page 140 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC588.D
,;Acq On 26 Apr 2023 8:46 am
~Sample V067D261
:,Misc 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
(QT Reviewed)
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.RES
, ,
. Quant Method
Title
Last Update
Response via
'DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
37)
38 )
39)
" 40)
~ 41)
1: 42)
Iv 44)
45)
46)
( 47)
T 48)
I 49)
r 51)
53)
54)
57)
58)
59)
60 )
61)
62)
63)
;; 64)
1, 65)
66)
67)
68)
69)
70 )
71)
72)
73)
75)
76)
78)
80 )
81)
82)
83)
84)
85)
Cyclohexane
1, 1, 1-Trichloroethane
2, 2, 4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
Dibromomethane
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
l,2,3-Trichloropropane
n-Propylbenzene
Bromobenzene
1 1 3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
8.57
8.59
8.75
8.92
9.10
9.25
9.46
9.49
10.74
10.81
11.09
11.53
11.61
12.26
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.24
14.61
14.96
15.28
15.67
15.75
15.76
15.89
16.62
16.70
17.24
17.24
17.52
17.72
17.82
17.87
18.03
18.06
18.11
18.48
r
84
97
57
110
119
87
78
( 62
130
83
63
83
93
43
r 75
91
75
69
97
43
76
164
129
107
/ 91
112
131
91
91
91
104
,105
-173
83
110
r 91
156
105
91
91
134
32024
25659
75999
10406
19343
6877
85012
14687
20389
34825
17436
19792
6472
45464
24011
80678
15769
10281
8865
28089
18017
15745
9912
7510
32243
44659
12818
87805
130855
58934
43482
74119
3625
8352
2278
89478
12848
55583
64048
48676
12112
(#) = qualifier out of range (m) = manual integration
RDC588.D V067D26.M Thu Apr 27 08:28:46 2023
0.25
0.27
0.22
0.26
0.25
0.25
0.27
0.27
0.26
0.24
0.25
0.26
0.23
1.32
0.24
0.27
0.24
0.21
0.25
1.36
0.26
0.27
0.26
0.24
0.26
0.27
0.26
0.27
0.55
0.26
0.25
0.25
0.22
0.27
0.27
0.27
0.28
0.27
0.30
0.28
0.27
/' I/~
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
(~il\\~~
Qvalue
95
92
95
96
96
94
99
92
97
99
95
96
95
95
99
99
98
89
97
96
97
95
99
96
99
100
99
99
97
100
98
100
99
99
97
99
99
96
94
96
98
Page 2
REPORT ID: 23E120 Page 141 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC588.D
~eq On 26 Apr 2023 8:46 am
Sample V067D261
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
86 ) l,2,4-Trimethylbenzene 18.52 < 105 51545 0.27 ug/l 98
87) see-Butylbenzene 18.74< 105 73459 0.27 ug/l 97
_.H' 88) p-Isopropyltoluene 18.89 119 54505 0.25 ug/l 100
f-', 89) l,3-Diehlorobenzene 19.01 ! 146 27068 0.29 ug/l 97 ,
,:: 90) l,4-Diehlorobenzene 19.12. 146 25111 0.28 ug/l 98
91) n-Butylbenzene 19.34 91 48023 0.23 ug/l 99
92) l,2-Diehlorobenzene 19.52' 146 21549 0.29 ug/l 93
94) 1, 2, 4-Triehlorobenzene 21.17 180 7864 0.25 ug/l 96
95) Hexaehlorobutadiene 21.29{ 225 6626 0.25 ug/l 90
96) Naphthalene 21.45 128 12638 0.32 ug/l 94
97) l,2,3-Triehlorobenzene 21.69 180 6259 0.30 ug/l 91
____________________________________________________ ~_~ __ ~t~l~? _______ _
(#) = qualifier out of range (m) = manual integration
RDC588.D V067D26.M Thu Apr 27 08:28:46 2023 Page 3
REPORT ID: 23E120 Page 142 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC588.D
Aeq On 26 Apr 2023 8:46 am
Sample V067D261
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Pararns: RTE.P
Quant Time: Apr 27 8:28 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Re onse via
1900000
1800000
1400000
1300000
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
w z w
N Z w m
0
0::
0
::::I
..J
U.
0
.t.
RDC588.D V067D26.M Thu Apr 27 08:28:48 2023
.. c
W
Z w
N z w m
0
0::
0
..J
~ u
0
~
Page 4
REPORT ID: 23E120 Page 143 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D Vial: 3
Operator: Acq On 26 Apr 2023 9:11 am
Sample V067D262
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
Inst
Multiplr:
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
[System Monitoring Compounds
E 36) Dibromofluoromethane
Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
LTarget Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
R.T. QIon Response Cone Units Dev(Min)
10.15
15.60
19.49
114 2227413
117 1566290
152 442714
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
8.19 111
9.29 65
12.97 98
17.60 95
85
50
62
94
64
67
101
56
151
43
61
r 59
142
43
76
49
53
73
1. 85
2.11
2.23
2.70
2.70
2.78
2.96
3.50
3.57
3.59
3.76
3.92
4.23
4.29
4.50
4.53
4.76
4.80
5.02
5.70
5.89
5.94
6.63
7.22
7.30 -'
7.68
8.06
r 96
r
45
63
43
59
77
96
83
130
24319 0.46 ug/l 0.00
Recovery 4.60%
19733 0.49 ug/l 0.00
Recovery = 4.90%
106080 0.49 ug/l 0.00
Recovery = 4.90%
30173 0.50 ug/l 0.00
Recovery = 5.00%
33781
51404
49591
30209
32273
66478
35978
14963
25430
35528
60455
29446
50749
14966
113808
62407
24082
50908
42089
120531
69125
29960
83176
46261
39371
54720
14741
0.50 ug/l
0.44 ug/l
0.47 ug/l
0.47 ug/l
0.47 ug/l
0.51 ug/l
0.47 ug/l
2.87 ug/l
0.51 ug/l
3.98 ug/l
0.49 ug/l
12.00 ug/l
0.47 ug/l
0.52 ug/l
0.45 ug/l
0.60 ug/l
2.05 ug/l
0.48 ug/l
0.50 ug/l
0.49 ug/l
0.51 ug/l
0.38 ug/l
0.49 ug/l
0.52 ug/l
0.49 ug/l
0.50 ug/l
0.45 ug/l
Qvalue
91
90
96
97
96
94
95
84
97
100
97
94
100
82
96
98
96
100
97
98
97
89
96
96
99
99
98
(#) = qualifier out of range (m) = manual integration ~~
RDC589.D V067D26.M Thu Apr 27 08:30:53 2023 t>f\\~~ Page 1
REPORT ID: 23E120 Page 144 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D
Acq On 26 Apr 2023 9:11 am
Sample V067D262
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 3
Operator: VLu
67
1. 00
Inst
Multiplr:
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
37) Cyclohexane
38) l,l,l-Trichloroethane
39) 2,2,4-Trimethylpentane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
0t 44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
C 47) Methylcyclohexane
1 48) l,2-Dichloropropane
I 49) Bromodichloromethane
R 51) Dibromomethane
r 52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
" 65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
-71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
82) l,3,5-Trimethylbenzene
83) 2-Chlorotoluene
8.57 84
8.59 97
8.73 57
8.92 110
9.11 119
9.25 87
9.47 78
9.49 62
10.72 130
10.81 83
11. 09 63
11.53 83
11.61 93
12.20 63
12.26 43
12.58 r75
13.10 91
13.50 / 75
13.53 69
13.75 97
13.82 43
14.20 76
14.24 164
14.61 129
14.94 107
15.28 (' 91
15.66 112
15.75 131
15.76/ 91
15.89 91
I 16.63, 91
16.70/ 104
17.22 /' 105
17.24 173
17.52 83
17.72 110
17.82 53
17.82 / 91
17.87 156
18.03 105
18.04 91
54806
46110
139816
18491
36416
11985
146337
25883
35103
59356
32267
34723
11502
4422
69830
45133
143921
28471
17886
15452
40870
31869
27504
17157
13776
56478
78079
23063
152914
228317
104022
77793
134425
7206
14875
3753
2970
163482
22606
99844
113562
0.44 ug/l
0.50 ug/l
0.43 ug/l
0.49 ug/l
0.49 ug/l
0.46 ug/l
0.49 ug/l
0.50 ug/l
0.48 ug/l
0.43 ug/l
0.48 ug/l
0.48 ug/l
0.43 ug/l
0.37 ug/l
2.13 ug/l
0.48 ug/l
0.52 ug/l
0.45 ug/l
0.39 ug/l
0.47 ug/l
2.10 ug/l
0.49 ug/l
0.50 ug/l
0.47 ug/l
0.47 ug/l
0.47 ug/l
0.49 ug/l
0.49 ug/l
0.49 ug/l
1.01 ug/l
0.49 ug/l
0.47 ug/l
0.48 ug/l
0.46 ug/l
0.49 ug/l
0.46 ug/l
0.35 ug/l
0.51 ug/l
0.50 ug/l
0.50 ug/l
0.55 ug/l
Qvalue
96
91
98
96
100
98
99
100
98
98
100
89
92
80
96
98
98
93
93
99
97
100
95
100
98
97
100
97
99
97
100
100
99
95
96
89
97
99
99
97
93
(#) = qualifier out of range (m) = manual integration 'I\~~
RDC589.D V067D26.M Thu Apr 27 08:30:54 2023 3f/\ ~l \ . Page 2
REPORT ID: 23E120 Page 145 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D
Aeq On 26 Apr 2023 9:11 am
Sample V067D262
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 3
Operator: VLu
Inst 67
Multiplr: 1. 00
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. Qlon Response Cone Unit Qvalue
-------------------------------------------------------------------------
84) 4-Chlorotoluene 18.12 91 81996 0.48 ug/l 95
85) tert-Butylbenzene 18.48 134 21178 0.48 ug/l 97 , 86) l,2,4-Trimethylbenzene 18.52 ·105 91244 0.49 ug/l 98
r~ 87) see-Butylbenzene 18.73 ' 105 126668 0.48 ug/l 99
E 88) p-Isopropyltoluene 18.89 119 97475 0.47 ug/l 100
'Y 89) l,3-Diehlorobenzene 19.01,146 44443 0.49 ug/l 99
f. 90) l,4-Diehlorobenzene 19.12 ' 146 44214 0.50 ug/l 97
91) n-Butylbenzene 19.34 , 91 85784 0.43 ug/l 99
92) l,2-Diehlorobenzene 19.52 I 146 34862 0.49 ug/l 93
93) l,2-Dibromo-3-ehloropropan 20.29 157 816 0.26 ug/l 82
94) 1, 2, 4-Triehlorobenzene 21.15 ( 180 12950 0.43 ug/l 97
95) Hexaehlorobutadiene 21.29/ 225 10387 0.41 ug/l 94
96) Naphthalene 21.43 128 16181 0.42 ug/l 100
97) l,2,3-Triehlorobenzene 21. 70 1 180 9061 0.44 ug/l 98
~7/---
, --__ --__ --__ --___ --__ --_ ----------------------------------5 -L \ l ~ -~ ------
(#) = qualifier out of range (m) = manual integration
RDC589.D V067D26.M Thu Apr 27 08:30:54 2023 Page 3
REPORT ID: 23E120 Page 146 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC589.D
Acq On 26 Apr 2023 9:11 am
Sample V067D262
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
Vial: 3
Operator: VLu
67
1. 00
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: Apr 27 8:29 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
rbundanci
. 1800000
1700000
1600000
1500000
1400000
j
13000001
1200000
1100000
1000000
900000j
I
i
800000
700000
! ~
i ~
100000 I' !
Time-->
::;; ..:
:;:.
I-).:
Q) • ~
Q)
E ~ :::>
e
0
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
::;;
....: ::;; ill
1-;' ID
I-w-: ~ QJl.
0"; Ii;
~ .:
I a;
>-~
b :::> ~ ID
~ t:
!l
::;;
~ ~ 1 ~ ~~ I~I ~il
'" ao
ui z w
~
W
ID
~ o
:3 u.
~
TIC: RDC589.D
::;; ~ ::;;::;;. ::;;. :l' I-.-:ti ~ .~ ~::;; ~::;;. ~. ~" c: Q)t-= ~-..... -~~i !Oq-r · ~ en-: I!.~ c ~ fij --as i! .... >< i~ ~ Q.~I.c: -";Q) ~ .,;-~ ~fij~ l~ J Ii e OOB If I 10 B8B ci> {r . 1-6 E.!-o ~ ...: I"'" ~ e ~ <'t 1£ lE.;, ~·o,e
~ <Ill ~·u tIl~~a~ 0 c\t 0 ___
~
::;; ..: .,; c ~.::;;. '" Q. C, 1-. e I ~ ~
~ ~-~ ~e
6 1£ E . -6 e ~5 ,e
0
<'t ~z....-
RDC589.D V067D26.M Thu Apr 27 08:30:56 2023 :7 fA 51 \ ~ Page 4 REPORT ID: 23E120 Page 147 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D Vial: 4
Operator: VLu Acq On 26 Apr 2023 9:37 am
Sample V067D263 Inst 67
Misc 1.0ppb 8260/5.0ppb KET~AA/25ppb TBA Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
" L
Internal Standards
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
J'System Monitoring Compounds
c 36) Dibromofluoromethane
h Spiked Amount 10.000
r 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.14
15.60
19.49
114 2165460
117 1543098
152 445946
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.19 111
9.29 65
12.97 98
17.60 95
1. 86
2.12
2.24
2.68
2.70
2.78
2.96
3.53
3.57
3.59
3.76
3.92
4.23
4.28
4.50
4.53
4.76
4.80
5.02
5.70
5.87
5.94
6.63
6.91
7.19
7.32
7.68
85
50
62
94
64
67
101
56
151
43
61
~ 59
142
43
76
49
53
73
~ 96
45
63
43
59
72
77
96
83
54583 1.06 ug/l 0.00
Recovery 10.60%
40915 1.04 ug/l 0.00
Recovery = 10.40%
228415 1.06 ug/l 0.00
Recovery = 10.60%
63033 1.05 ug/l 0.00
Recovery = 10.50%
72942
128259
109031
65421
72220
132052
79994
25534
50264
68593
122498
58923
100106
27114
245001
107106
53961
103608
82345
238584
132990
69379
169919
12761
87281
78216
107361
1.10
1.12
1. 07
1. 04
1. 08
1. 05
1. 08
5.03
1. 04
7.90
1. 03
24.70
0.96
0.96
0.99
1. 06
4.74
1. 00
1. 00
1. 00
1. 00
0.91
1. 04
4.42
1. 01
1. 01
1. 00
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
98
99
98
99
98
100
99
76
96
92
97
96
99
80
96
97
96
100
99
98
98
96
93
94
99
99
99
(#) = qualifier out of range (m) = manual integration
RDC590.D V067D26.M Thu Apr 27 08:31:58 2023 Page 1
REPORT ID: 23E120 Page 148 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D
Acq On 26 Apr 2023 9:37 am
Sample V067D263
Misc 1.0ppb 8260/5.0ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 4
Operator: VLu
Inst 67
Multiplr: 1.00
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
35) tert-Amyl alcohol
37) Cyclohexane
38) 1,1,1-Trichloroethane
39) 2,2,4-Trimethylpentane
r 40) 1,1-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
'" 44) Benzene
1 45) 1,2-Dichloroethane
46) Trichloroethene
R 47) Methylcyclohexane
C 48) 1,2-Dichloropropane
49) Bromodichloromethane
50) 1,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) 1,1,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
8.05 130
8.15 42
8.19 59
8.56 84
8.57 97
8.73 57
8.92 110
9.10 119
9.26 87
9.47 78
9.48 62
10.72 130
10.81 '83
11.09 (63
11. 53 83
11. 63 88
11. 60 93
12.20/ 63
12.26 43
12.56 '" 75
13.10 91
13.48 / 75
13.53 69
13.75 97
13.82 43
14.19 76
14.24 164
14.59 129
14.94 107
15.27 .( 91
15.66 112
15.75 131
15.76 I 91
15.89! 91
16.63 ! 91
16.70 ~ 104
17.22 L 105
17.24 173
17.50 83
17.72 110
17.82 53
32534
9554
6893
126581
90742
345233
36932
72949
24618
292880
51845
71634
134599
65194
71354
4728
25401
9267
149689
88207
282853
59430
38066
32973
88412
62834
54376
34282
28530
112325
158902
44258
308361
448159
209853
155588
270299
14063
30760
8591
7599
1.03 ug/l
1.02 ug/l
3.64 ug/l
1.05 ug/l
1. 01 ug/l
1.08 ug/l
1. 00 ug/l
1.01 ug/l
0.96 ug/l
1.01 ug/l
1.02 ug/l
1. 00 ug/l
1.00 ug/l
1.00 ug/l
1.01 ug/l
18.68 ug/l
0.97 ug/l
0.79 ug/l
4.70 ug/l
0.96 ug/l
1.03 ug/l
0.96 ug/l
0.85 ug/l
1.01 ug/l
4.60 ug/l
0.98 ug/l
1.00 ug/l
0.95 ug/l
0.98 ug/l
0.96 ug/l
1.02 ug/l
0.96 ug/l
1.00 ug/l
2.01 ug/l
1.00 ug/l
0.96 ug/l
0.98 ug/l
0.89 ug/l
1.01 ug/l
1.04 ug/l
0.89 ug/l
(#) = qualifier out of range (m) = manual integration S ~
RDC590.D V067D26.M Thu Apr 27 08: 31: 58 2023 ':5 1 \{'L ~
Qvalue
96
80
90
95
99
99
98
99
92
100
100
98
99
100
99
100
98
96
98
98
100
89
93
95
97
99
99
99
98
99
98
100
99
99
100
99
99
99
99
100
86
Page 2
REPORT ID: 23E120 Page 149 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D
Aeq On 26 Apr 2023 9:37 am
Sample V067D263
Mise 1.0ppb 8260/5.0ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 4
Operator: VLu
Inst 67
Mul tiplr: 1. 00
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.RES
Quant Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
DataAeq Meth V067D26
Compound R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
80 ) n-Propylbenzene 17.81 91 326257 1.01 ug/l 99
81) Bromobenzene 17.87 156 46166 1.01 ug/l 98
)-82) 1,3,5-Trimethylbenzene 18.03 105 198631 0.98 ug/l 100 L
p 83) 2-Chlorotoluene 18.04 ( 91 229944 1.10 ug/l 93 ,-, 84) 4-Chlorotoluene ug/l -18.12 91 161309 0.94 95 ~-tv 85) tert-Butylbenzene 18.48 134 44204 0.99 ug/l 99
iIi 86) 1, 2, 4-Trimethylbenzene 18.52 (105 183193 0.98 ug/l 100
87) see-Butylbenzene 18.73 I 105 261892 0.98 ug/l 99
88 ) p-Isopropyltoluene 18.89 I 119 200168 0.95 ug/l 99
89) 1,3-Diehlorobenzene 19.01 I 146 89318 0.98 ug/l 100
90 ) 1,4-Diehlorobenzene 19.12 146 86575 0.97 ug/l 98
91) .n-Butylbenzene 19.34 91 178907 0.89 ug/l 98
92) 1,2-Diehlorobenzene 19.52 / 146 70938 0.99 ug/l 96
93) 1,2-Dibromo-3-ehloropropan 20.29/157 2514 0.80 ug/l 93
94) 1,2,4-Triehlorobenzene 21.15 180 25885 0.85 ug/l 97
95) Hexaehlorobutadiene 21. 29 I 225 22460 0.88 ug/l 95
96) Naphthalene 21. 43 128 32258 0.83 ug/l 98
97) 1,2,3-Triehlorobenzene 21.70 180 17709 0.86 ug/l 97
______________________________________________________ ~_~ __ J(_[~~~~ __ _
(#) = qualifier out of range (m) = manual integration
RDC590.D V067D26.M Thu Apr 27 08:31:59 2023 Page 3
REPORT ID: 23E120 Page 150 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC590.D
Aeq On 26 Apr 2023 9:37 am
Sample V067D263
Mise 1.0ppb 8260/5.0ppb KET-AA/25ppb TBA
Vial: 4
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 15:15 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
fA,bundance TIC: ROC590.0
. I
. i
i
I
I
I
I
I
!
1700000
1600000
1500000
I
1400000j
13000001
I
1200000
1100000
I
i
10000001
I
9000001
I
800000j
700000
600000
I
Irime-->
RDC590.D V067D26.M Thu Apr 27 08:32:01 2023 Page 4
REPORT ID: 23E120 Page 151 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Acq On 26 Apr 2023 10:03 am
Sample V067D264
Misc 2.0ppb 8260/10ppb KET-AA/50ppb
MS Integration Params: RTE.P
Vial: 5
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.14 114 2105743 10.00 ug/l 0.00
55) CHLOROBENZENE-D5 15.60 117 1502963 10.00 ug/l 0.00
74) l,2-DICHLOROBENZENE-D4 19.49 152 449730 10.00 ug/l 0.00
System Monitoring Compounds
36) Dibromofluoromethane 8.19 111 98047 1. 95 ug/l 0.00
Spiked Amount 10.000 Recovery = 19.50%
43) l,2-Dichloroethane-d4 9.29 65 77116 2.01 ug/l 0.00
Spiked Amount 10.000 Recovery = 20.10%
56) Toluene-d8 12.97 98 411745 1. 97 ug/l 0.00
( Spiked Amount 10.000 Recovery 19.70% .
1 77) 4-Bromofluorobenzene 17.60 95 117188 1. 93 ug/l 0.00
r Spiked Amount 10.000 Recovery = 19.30%
h
[Target Compounds Qvalue
2) Dichlorodifluoromethane 1. 86 85 127055 1. 98 ug/l 98
4) Chloromethane 2.12 50 225572 2.02 ug/l 99
5) Vinyl chloride 2.24 62 205221 2.08 ug/l 99
6) Bromomethane 2.68 94 120888 1. 98 ug/l 98
7) Chloroethane 2.70 64 132059 2.04 ug/l 100
8) Dichlorofluoromethane 2.80 67 260115 2.12 ug/l 99
9) Trichlorofluoromethane 2.96 101 152680 2.11 ug/l 97
11) Acrolein 3.53 56 48781 9.89 ug/l 94
12) l,l,2-Trichloro-1,2,2-trif 3.57 151 98835 2.10 ug/l 100
13) Acetone 3.59 43 108039 12.79 ug/l 100
14) l,l-Dichloroethene 3.78 ~ 61 242569 2.10 ug/l 99
15) tert-Butyl alcohol 3.92 59 111785 48.18 ug/l 97
16) Iodomethane 4.22 142 204141 2.02 ug/l 98
17) Methyl acetate 4.28 43 50333 1. 83 ug/l 100
19) Carbon disulfide 4.50 76 472352 1. 96 ug/l 100
20 ) Methylene chloride 4.53 49 213342 2.18 ug/l 100
21) Acrylonitrile 4.76 53 119092 10.75 ug/l 98
22) tert-Butyl methyl ether (M 4.80 73 210680 2.09 ug/l 99
23 ) trans-1,2-Dichloroethene 5.02 ) 96 165599 2.08 ug/l 100
24) Isopropyl ether (DIPE) 5.70 45 486135 2.09 ug/l 96
25) l,l-Dichloroethane 5.89 j 63 271457 2.10 ug/l 99
26) Vinyl acetate 5.94 43 140810 1. 91 ug/l 98
28 ) tert-Butyl ethyl ether (ET 6.63 59 351718 2.21 ug/l 95
29) 2-Butanone 6.92 72 28390 10.11 ug/l 87
30 ) 2,2-Dichloropropane 7.20 77 181594 2.16 ug/l 98
31 ) cis-1,2-Dichloroethene 7.30 1 96 156574 2.07 ug/l 99
32 ) Chloroform 7.68 83 221325 2.12 ug/l 99
(#) = qualifier out of range (m) = manual integration
RDC591.D V067D26.M Thu Apr 27 08:32:25 2023 ~s1\ ~3 Page 1
REPORT ID: 23E120 Page 152 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Acq On 26 Apr 2023 10:03 am
Sample V067D264
Misc 2.0ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
5
VLu
67
1. 00
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33)
34)
.L 35)
1 37)
;:.. 38)
1\ 39)
1" 40)
41)
42)
( 44)
45)
46)
47)
48)
49)
50)
51)
52)
53)
54)
57)
. 58)
59)
60)
61)
62)
63)
64)
65)
66)
67)
68)
69 )
70)
71)
72)
73)
75)
76)
78)
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
1, 1, I-Trichloroethane
2, 2, 4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-l,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
l-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05
8.14
8.21
8.56
8.57
8.74
8.93
9.10
9.26
9.47
9.50
10.72
10.81
11.09
11.53
11.61
11. 60
12.20
12.24
12.56
13.10
13.48
13.53
13.75
13.81
14.19
14.24
14.61
14.95
15.27
15.66
15.75
15.76
15.89
16.63
16.70
17.22
17.24
17.50
17.71
17.82
130
42
59
84
97
57
110
119
87
t 78
/ 62
130
., 83
63
83
88
93
63
, 43
75 r
91
..c75
69
97
43
76
164
129
107
J 91
112
131
< 91
. 91
91
'104
! 105
173
83
110
53
64637
19208
16323
229502
184205
619597
76048
147654
52122
589844
106518
146439
242950
134863
139314
9698
53812
20667
334369
182560
572373
125397
84467
68471
198605
133186
112716
72390
60683
237227
320768
92684
630650
925386
432325
321717
568372
32449
66389
17674
16903
(#) = qualifier out of range (m) = manual integration
RDC591.D V067D26.M Thu Apr 27 08:32:26 2023
2.11
2.11
8.86
1. 95
2.11
2.00
2.11
2.10
2.10
2.10
2.16
2.11
1. 85
2.13
2.03
39.40
2.11
1. 81
10.80
2.04
2.14
2.08
1.94
2.16
10.61
2.13
2.13
2.06
2.15
2.08
2.10
2.07
2.10
4.25
2.11
2.05
2.12
2.03
2.15
2.13
1. 96
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
98
94
91
100
90
99
99
99
98
100
99
98
98
97
98
100
99
100
99
98
100
98
98
99
98
98
99
99
99
100
99
99
100
99
100
99
99
96
99
95
96
Page 2
REPORT ID: 23E120 Page 153 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Aeq On 26 Apr 2023 10:03 am
Sample V067D264
Mise 2.0ppb 8260/10ppb KET-AA/50ppb
MS Integration Params: RTE.P
Vial: 5
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
80 ) n-Propylbenzene 17.81 r 91 689742 2.11 ug/l
81) Bromobenzene 17.87 156 95587 2.08 ug/l
, 82) l,3,5-Trimethylbenzene 18.03 105 426450 2.09 ug/l
83) 2-Chlorotoluene 18.04 , 91 430326 2.04 ug/l
84) 4-Chlorotoluene 18.12 ! 91 386777 2.23 ug/l
85) tert-Butylbenzene 18.48 ( 134 93541 2.08 ug/l
86) l,2,4-Trimethylbenzene 18.52 105 398293 2.11 ug/l
87) see-Butylbenzene 18.73 105 573386 2.12 ug/l
88 ) p-Isopropyltoluene 18.89 ( 119 443939 2.09 ug/l
89) l,3-Diehlorobenzene 19.01 146 190807 2.07 ug/l
90) l,4-Diehlorobenzene 19.12 I 146 185667 2.07 ug/l
.L 91) n-Butylbenzene 19.34 ( 91 405021 2.00 ug/l
C" 92) l,2-Diehlorobenzene 19.52 146 151625 2.09 ug/l j~
L 93) l,2-Dibromo-3-ehloropropan 20.29 157 6264 1. 98 ug/l
94) l,2,4-Triehlorobenzene 21. 16" 180 58642 1. 92 ug/l
95) Hexaehlorobutadiene 21.29 225 56308 2.19 ug/l
96) Naphthalene 21. 43 128 70658 1. 80 ug/l
97) l,2,3-Triehlorobenzene 21.68 180 40382 1. 93 ug/l
Qvalue
99
99
99
99
98
98
98
100
99
100
99
99
98
97
99
98
98
98
~" \r1.-?J ----------------------------------------------------------~~----~------
(#) = qualifier out of range (m) = manual integration
RDC591.D V067D26.M Thu Apr 27 08:32:26 2023 Page 3
REPORT ID: 23E120 Page 154 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC591.D
Aeq On 26 Apr 2023 10:03 am
Sample V067D264
Vial: 5
Operator: VLu
Inst 67
Mise 2.0ppb 8260/10ppb KET-AA/50ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 15:16 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
fbundance
!
1700000
1600000,
I
I 1500000
1400000
1300000
1
1200000 1
1100000
1000000
9000001
800000
700000
600000
500000
I ,
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
u.i z w
!:;!
w
~ a: o
3 u.
is
./:
TIC: RDC591.D
i3 w z
II
II II :;; II..: ioj , c
I.!! I~
'0-
0/1
RDC591.D V067D26.M Thu Apr 27 08:32:28 2023
~ w z
W
N
Z
W m
~ o
...J
J:
U
~
Page 4
REPORT ID: 23E120 Page 155 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D Vial: 6
Operator: VLu Acq On 26 Apr 2023 10:28 am
Sample V067D265 Inst 67
Misc 5.0ppb 8260/25ppb KET-AA/125ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
{:System Monitoring Compounds
~ 36) Dibromofluoromethane
IV Spiked Amount 10.000
~ 43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
, 11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
:~ 13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
R.T. QIon Response Cone Units Dev(Min)
10.14 114
15.60 117
19.49 152
2232342
1629177
496816
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.20 111 265381 4.99 ug/l 0.00
Recovery 49.90%
9.29 65 201837 4.97 ug/l 0.00
Recovery 49.70%
12.97 98 1134923 5.01 ug/l 0.00
Recovery = 50.10%
17.60 95 327706 4.88 ug/l 0.00
1.86
2.12
2.24
2.68
2.70
2.80
2.96
3.53
3.57
3.59
3.76
3.92
4.24
4.28
4.50
4.53
4.76
4.79
5.02
5.70
5.89
5.94
6.63
6.91
7.19
7.30
7.68
85
50
62
94
64
67
101
56
151
43
, 61
59
142
43
76
49
53
73
I 96
45
" 63
43
59
72
77
! 96
83
Recovery 48.80%
323009
575122
530190
319552
336515
640659
376145
113929
240021
247925
627145
299297
547870
133105
1269320
495774
283291
529888
411364
1203044
667038
383539
867211
71377
448254
393098
539436
4.74 ug/l
4.86 ug/l
5.06 ug/l
4.94 ug/l
4.90 ug/l
4.93 ug/l
4.91 ug/l
21.79 ug/l
4.80 ug/l
27.69 ug/l
5.12 ug/l
121.69 ug/l
5.11 ug/l
4.57 ug/l
4.97 ug/l
4.78 ug/l
24.12 ug/l
4.97 ug/l
4.87 ug/l
4.88 ug/l
4.88 ug/l
4.90 ug/l
5.13 ug/l
23.97 ug/l
5.02 ug/l
4.90 ug/l
4.88 ug/l
Qvalue
98
100
100
99
98
100
100
100
100
96
98
99
100
98
100
99
98
100
100
100
99
99
96
99
99
99
100
. (#) = qualifier out of range (m) = manual integration
RDC592.D V067D26.M Thu Apr 27 08:32:45 2023 Page 1
REPORT ID: 23E120 Page 156 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D
Acq On 26 Apr 2023 10:28 am
Sample V067D265
Misc 5.0ppb 8260/25ppb KET-AA/125ppb
MS Integration Params: RTE.P
Vial: 6
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
35) tert-Amyl alcohol
37) Cyclohexane
38) 1,1,1-Trichloroethane
39) 2,2,4-Trimethylpentane
40) 1,1-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
C 44) Benzene
1 45) 1,2-Dichloroethane
~ 46) Trichloroethene
[; 47) Methylcyclohexane
[ 48) 1,2-Dichloropropane
49) Bromodichloromethane
50) 1,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) 1,1,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
" 64) Dibromochloromethane
65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) 1,1,2,2-Tetrachloroethane
78) 1,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
8.06
8.14
8.17
8.56
8.58
8.74
8.93
9.10
9.25
9.47
9.48
10.72
10.81
11.07
11.51
11.61
11.60
12.20
12.24
12.56
13.10
13.48
13.51
13.75
13.81
14.19
14.24
14.59
14.95
15.27
15.66
15.75
15.76
15.90
16.63
16.68
17.22
17.24
17.50
17.71
17.81
130
42
59
84
97
57
110
119
87
78
62
130
83
! 63
83
88
93
( 63
43
/ 75
91
/75
69
97
43
76
164
129
107
/ 91
112
).31
91
~ 91
91
104
J105
173
83
110
53
162043
48432
44226
612119
453099
1609428
188486
365906
129860
1454988
261960
362467
659224
328340
356310
23795
132280
54685
802473
470301
1435460
323737
222743
172210
492127
334013
275720
189463
152829
609170
808219
235202
1595161
2337833
1097629
827293
1445405
82959
167400
46132
46026
(#) = qualifier out of range (m) = manual integration
RDC592.D V067D26.M Thu Apr 27 08:32:45 2023
4.98 ug/l
5.01 ug/l
22.66 ug/l
4.91 ug/l
4.91 ug/l
4.89 ug/l
4.93 ug/l
4.90 ug/l
4.93 ug/l
4.88 ug/l
5.00 ug/l
4.92 ug/l
4.75 ug/l
4.89 ug/l
4.90 ug/l
91.18 ug/l
4.90 ug/l
4.52 ug/l
24.44 ug/l
4.96 ug/l
4.95 ug/l
4.96 ug/l
4.71 ug/l
5.00 ug/l
24.26 ug/l
4.93 ug/l
4.80 ug/l
4.96 ug/l
4.99 ug/l
4.92 ug/l
4.89 ug/l
4.85 ug/l
4.90 ug/l
9.92 ug/l
4.94 ug/l
4.86 ug/l
4.97 ug/l
4.71 ug/l
4.91 ug/l
5.03 ug/l
4.83 ug/l
Qvalue
99
99
100
100
99
100
99
99
98
100
100
99
100
99
100
90
99
98
100
98
100
98
98
98
100
100
98
100
100
100
99
99
99
100
100
99
100
99
100
99
94
REPORT ID: 23E120 Page 157 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D
Aeq On 26 Apr 2023 10:28 am
Sample V067D265
Mise 5.0ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
6
VLu
67
1. 00
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.RES
Quant Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
Last Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
DataAeq Meth V067D26
Compound R.T. Qlon Response Cone Unit Qvalue
-------------------------------------------------------------------------
80 ) n-Propylbenzene 17.81 c 91 1799590 4.98 ug/l 100
81) Bromobenzene 17.87 156 248380 4.88 ug/l 98
". 82) l,3,5-Trimethylbenzene 18.03 < 105 1108860 4.92 ug/l 99
4':. 83) 2-Chlorotoluene 18.04 91 1099892 4.72 ug/l 94
E: 84) 4-Chlorotoluene 18.10 91 967525 5.06 ug/l 98
I IV: 85) tert-Butylbenzene 18.48 ·134 239885 4.83 ug/l 99
tv 86) 1, 2, 4-Trimethylbenzene 18.53 105 1024778 4.90 ug/l 99
87) see-Butylbenzene 18.73 105 1492598 5.00 ug/l 100
88) p-Isopropyltoluene 18.89 ,119 1166660 4.98 ug/l 100
89) l,3-Diehlorobenzene 18.99 I 146 491864 4.83 ug/l 100
90) l,4-Diehlorobenzene 19.12 ,146 477927 4.82 ug/l 100
91) n-Butylbenzene 19.34 I 91 1098148 4.92 ug/l 100
92) l,2-Dichlorobenzene 19.52 146 386200 4.82 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.29 157 17524 5.00 ug/l 98
94) 1, 2, 4-Trichlorobenzene 21.16 180 164702 4.88 ug/l 99
95) Hexachlorobutadiene 21. 29 ~25 144741 5.09 ug/l 99
96) Naphthalene 21.43 128 201031 4.65 ug/l 100
97) l,2,3-Trichlorobenzene 21.68 180 109128 4.73 ug/l 99
(#) = qualifier out of range (m) = manual integration
RDC592.D V067D26.M Thu Apr 27 08:32:46 2023 Page 3
REPORT ID: 23E120 Page 158 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC592.D
Aeq On 26 Apr 2023 10:28 am
Sample V067D265
Mise 5.0ppb 8260/25ppb KET-AA/125ppb TBA
Vial: 6
Operator: VLu
67
1. 00
Inst
Multiplr:
MS Integration Pararns: RTE.P
Quant Time: Apr 26 14:34 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
~bundance TIC: RDC592.D
I 27000001
i I
!
2600000
2500000
2400000
2~ooool
2200000
2100000
2000000
19000001
1800000
1700000
1600000
1500000
1400000
!
1300000i
1200000
1100000
1000000
900000
RDC592.D V067D26.M
ui z
~
W
£Xl o c: o
::::>
..J u.
is
..0:
Thu Apr 27 08:32:48 2023
~I
Page 4
REPORT ID: 23E120 Page 159 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D Vial: 7
Operator: VLu Acq On 26 Apr 2023 10:54 am
Sample V067D266 Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
ASystem Monitoring Compounds
S 36) Dibromofluoromethane
;'\ Spiked Amount 10.000
43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2)
4)
5)
6)
7)
8)
9)
11)
12)
" 13)
14)
15)
16)
17)
19)
20 )
21)
22)
23)
24)
25 )
26)
28)
29)
30 )
31)
32)
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Dichlorofluoromethane
Trichlorofluoromethane
Acrolein
1,1,2-Trichloro-1,2,2-trif
Acetone
1,1-Dichloroethene
tert-Butyl alcohol
Iodomethane
Methyl acetate
Carbon disulfide
Methylene chloride
Acrylonitrile
tert-Butyl methyl ether (M
trans-1,2-Dichloroethene
Isopropyl ether (DIPE)
1,1-Dichloroethane
Vinyl acetate
tert-Butyl ethyl ether (ET
2-Butanone
2,2-Dichloropropane
cis-1,2-Dichloroethene
Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.14
15.60
19.49
114 2183075
117 1594928
152 498004
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.19
9.29
12.97
17.60
1. 86
2.12
2.24
2.68
2.70
2.78
2.96
3.50
3.57
3.57
3.76
3.90
4.22
111
65
98
95
85
50
62
94
64
67
101
56
151
43
/ 61
59
142
4.28 43
4.50 76
4.51 49
4.75 53
4.79 73
5.02 .I 96
5.70 45
5.87 J 63
5.93 43
6.63 59
6.91 72
7.20 77
7.30/96
7.68 83
549869 10.57 0.00
Recovery =
ug/l
105.70%
ug/l
105.40%
ug/l
105.50%
ug/l
101.90%
418568 10.54
Recovery =
2339248 10.55
Recovery =
685510 10.19
Recovery =
712543
1236990
1159967
706231
745429
1266643
831517
270299
484755
427094
1184682
597511
1075340
310956
2808995
949826
587834
1049753
818734
2396278
1318860
840033
1604908
148687
859400
778617
1064245
10.69 ug/l
10.69 ug/l
11.32 ug/l
11.17 ug/l
11.10 ug/l
9.97 ug/l
11.09 ug/l
52.87 ug/l
9.92 ug/l
48.78 ug/l
9.89 ug/l
248.42 ug/l
10.25 ug/l
10.93 ug/l
11. 24 ug/l
9.36 ug/l
51.18 ug/l
10.07 ug/l
9.91 ug/l
9.93 ug/l
9.86 ug/l
10.98 ug/l
9.71 ug/l
51.06 ug/l
9.84 ug/l
9.93 ug/l
9.85 ug/l
0.00
0.00
0.00
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
(#) = qualifier out of range (m) = manual integration ~
RDC593.D VQ67D26.M Thu Apr 27 08.33,49 2023 ......--';(\ r'L:' Page 1
REPORT ID: 23E120 Page 160 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D
Acq On 26 Apr 2023 10:54 am
Sample V067D266
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 7
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33 )
34)
35)
37)
38)
39)
40)
41)
42 )
C 44)
°1 45)
.... 46)
1< 47)
C 48)
49)
50)
51)
52)
53)
54)
57)
58)
59)
60 )
61)
62)
63)
64)
65)
66)
67)
68 )
69)
70)
71)
72)
73)
75)
76 )
78 )
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
1,1,1-Trichloroethane
2,2,4-Trimethylpentane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
1,2-Dichloroethane
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
Bromodichloromethane
1,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1,1,1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2,2-Tetrachloroethane
1,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05
8.14
8.16
8.56
8.57
8.73
8.92
9.10
9.23
9.47
9.48
10.72
10.81
11.09
11.51
11.61
11.60
12.20
12.24
12.56
13.10
13.48
13.51
13.75
13.80
14.18
14.24
14.59
14.94
15.27 I
15.66
15.75
15.76
15.89
16.62
16.70
17.22
17.24
17.50
17.72
17.82
130
42
59
84
97
57
110
119
87
1 78
, 62
130
83
63
83
88
93
63
43
'75
91
t 75
69
97
43
76
164
129
107
91
112
131
, 91
91
I 91
104
,105
173
83
110
53
320097
96277
105930
1341207
899465
3535233
370134
736778
265518
2879652
514964
715886
1502560
651346
708435
51291
262963
112087
1657314
934047
2834055
651825
463192
336276
1031522
664005
554751
379176
305749
1222980
1599480
469971
3172145
4676325
2193821
1681115
2868834
174720
342287
93970
95577
(#) = qualifier out of range (m) = manual integration
RDC593.D V067D26.M Thu Apr 27 08:33:49 2023
10.06
10.19
55.49
11.00
9.96
10.99
9.91
10.10
10.31
9.88
10.06
9.94
11.06
9.91
9.96
200.97
9.97
9.48
51.62
10.08
9.99
10.19
10.01
9.98
51.94
10.00
9.86
10.14
10.20
10.08
9.89
9.90
9.94
20.26
10.08
10.08
10.09
9.89
10.02
10.23
10.00
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Page 2
REPORT ID: 23E120 Page 161 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D
.Aeq On 26 Apr 2023 10: 54 am
~ample V067D266
j'·;Jise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 7
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
80 ) n-Propylbenzene 17.81 91 3593925 9.93 ug/l
81) Bromobenzene 17.87 156 491974 9.65 ug/l
[ 82) l,3,5-Trimethylbenzene 18.03 105 2222578 9.84 ug/l
jl 83) 2-Chlorotoluene 18.04 91 2204705 9.45 ug/l
,S 84) 4-Chlorotoluene 18.12 f 91 1946005 10.15 ug/l
I\I 85) tert-Butylbenzene 18.48 134 479676 9.64 ug/l
!v' 86) l,2,4-Trimethylbenzene 18.52 105 2069453 9.88 ug/l
87) see-Butylbenzene 18.73 105 3007044 10.05 ug/l
88) p-Isopropyltoluene 18.89 ' 119 2380420 10.13 ug/l
89) l,3-Diehlorobenzene 18.99. 146 1001061 9.81 ug/l
90) l,4-Diehlorobenzene 19.12, 146 968291 9.75 ug/l
91) n-Butylbenzene 19.34 91 2267089 10.13 ug/l
92) l,2-Diehlorobenzene 19.52 1 146 789707 9.83 ug/l
93) l,2-Dibromo-3-ehloropropan 20.29 157 35281 10.05 ug/l
94) 1, 2, 4-Triehlorobenzene 21.15 I 180 344293 10.17 ug/l
95) Hexaehlorobutadiene 21. 29 225 288629 10.12 ug/l
96) Naphthalene 21.43 128 435685 10.05 ug/l
97) l,2,3-Triehlorobenzene 21.68 0 180 231081 10.00 ug/l
. (#) = qualifier out of range (m) ::;;: manual integration
RDC593.D V067D26.M Thu Apr 27 08:33:50 2023
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Page 3
REPORT ID: 23E120 Page 162 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC593.D
Aeq On 26 Apr 2023 10:54 am
Sample V067D266
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Vial: 7
Operator:
Inst
Multiplr:
VLu
67
1. 00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via rbundance
! 5400000j
i 5200000)
I I
50000001
j
I
48000001
4600000
4400000
4200000
4000000'J1
3800000
36000001
34000001
3200000j ,
30000001
!
2800000!
I
I
2600000
2400000
2200000
2000000
1800000
1
16000001
I
1400000i
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC593.D
(RTE Integrator)
RDC593.D V067D26.M Thu Apr 27 08:33:52 2023
REPORT ID: 23E120 Page 163 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC594.D Vial: 8
Operator: VLu Acq On 26 Apr 2023 11:19 urn
Sample V067D267 Inst 67
Misc 20ppb 8260/100ppb KET-AA/500ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
~ 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
~ 77) 4-Bromofluorobenzene
Spiked Amount 10.000
[Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-l,2,2-trif
13) Acetone
~ 14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
~ 21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-l,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.14
15.60
19.49
8.19
9.29
12.97
17.60
1.85
2.11
2.23
2.68
2.70
2.80
2.96
3.50
3.57
3.59
3.76
3.90
4.23
4.28
4.50
4.53
4.75
4.79
5.02
5.68
5.87
5.93
6.63
6.91
7.20
7.30
7.68
114 2313292
117 1689543
152 523893
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
III
65
98
95
85
50
62
94
64
67
101
56
151
43
,r 61
59
142
43
76
49
53
73
! 96
45
! 63
43
59
72
77
96
83
1148734 20.84 0.00
Recovery
ug/l
208.40%
ug/l
202.60%
ug/l
210.10%
ug/l
201.10%
853012 20.26
Recovery
4934750 21.01
Recovery =
1422777 20.11
Recovery
1349241
2274278
2118533
1356019
1413782
2765237
1593419
515978
1067186
811827
2706128
1259256
2365395
576730
5526915
2055047
1195133
2242473
1816916
5323252
2922672
1575021
3503474
301216
1910593
1742739
2376038
19.11 ug/l
18.55 ug/l
19.50 ug/l
20.24 ug/l
19.86 ug/l
20.55 ug/l
20.06 ug/l
95.23 ug/l
20.61 ug/l
87.50 ug/l
21.31 ug/l
494.08 ug/l
21.28 ug/l
19.12 ug/l
20.88 ug/l
19.12 ug/l
98.20 ug/l
20.29 ug/l
20.76 ug/l
20.82 ug/l
20.61 ug/l
19.43 ug/l
19.99 ug/l
97.61 ug/l
20.65 ug/l
20.98 ug/l
20.74 ug/l
0.00
0.00
0.00
Qvalue
99
100
100
99
98
99
99
100
99
99
98
99
99
100
100
100
100
99
99
100
100
100
100
97
99
99
99
(#) = qualifier out of range (m) = manual integration
RDC594.D V067D26.M Thu Apr 27 08:34:09 2023
311' 6\\'~ ~
Page 1
REPORT ID: 23E120 Page 164 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC594.D
Acq On 26 Apr 2023 11:19 am
Sample V067D267
r,Usc 20ppb 8260/100ppb KET-AA/500ppb
Ms Integration Params: RTE.P
Vial: 8
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
33)
34)
[ 35)
/0 37)
E:' 38)
[I 39)
I' 40)
41 )
42)
44)
45)
46)
47)
48)
49)
50 )
51)
52)
53)
54)
-57)
I' 58)
'-59)
['/ 60)
. 61)
62)
63)
64)
65 )
66 )
67)
68)
69)
70 )
71 )
72)
73)
75)
76)
78)
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
l,l,l-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
l,l,2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05
8.14
8.15
8.56
8.57
8.74
8.93
9.10
9.25
9.47
9.48
10.72
10.81
11.07
11.51
11.60
11.60
12.18
12.24
12.56
13.10
13.48
13.51
13.75
13.81
14.19
14.24
14.59
14.95
15.27
15.66
15.75
15.76
15.89
16.63
16.68
17.22
17.24
17.50
17.71
17.82
130
42
59
84
97
57
110
119
87
! 78
62
130
83
63
83
88
93
63
43
!75
91
L 75
69
97
43
76
164
129
107
( 91
112
131
< 91
91
J 91
104
1105
[ 173
83
110
53
697000
185899
203143
2671945
2013800
6723209
828786
1657531
569911
6491897
1111966
1601328
2938343
1461235
1580433
108441
579013
251741
3426179
2093936
6338070
1444510
1011489
736682
2115268
1441919
1256190
835856
659432
2784692
3599689
1069107
7200244
10566797
4992901
3854309
6551016
381403
720121
194394
207693
20.67 ug/l
18.58 ug/l
100.43 ug/l
20.68 ug/l
21.04 ug/l
19.72 ug/l
20.93 ug/l
21.43 ug/l
20.89 ug/l
21.02 ug/l
20.49 ug/l
20.98 ug/l
20.41 ug/l
20.98 ug/l
20.96 ug/l
400.99 ug/l
20.71 ug/l
20.10 ug/l
100.71 ug/l
21.33 ug/l
21.10 ug/l
21.32 ug/l
20.63 ug/l
20.64 ug/l
100.54 ug/l
20.50 ug/l
21.07 ug/l
21.11 ug/l
20.78 ug/l
21.67 ug/l
21.01 ug/l
21.26 ug/l
21.31 ug/l
43.22 ug/l
21.66 ug/l
21.82 ug/l
21.74 ug/l
20.52 ug/l
20.04 ug/l
20.11 ug/l
20.66 ug/l
(#) = qualifier out of range (m) = manual integration~ ~
RDC594.D V067D26.M Thu Apr 27 08:34:10 2023 ~
~\\{7-~
Qvalue
99
94
99
100
99
100
99
99
97
99
100
100
100
100
98
98
100
100
100
99
100
98
99
98
99
98
99
100
100
100
100
99
99
99
99
100
100
99
100
98
98
Page 2
REPORT ID: 23E120 Page 165 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC594.D
Aeq On 26 Apr 2023 11:19 am
Sample V067D267
Mise 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title METHOD 8260B
J.Jast Update Wed Apr 26 14:33:42 2023
Response via Initial Calibration
DataAeq Meth V067D26
Compound R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
80 ) n-Propylbenzene 17.81 I' 91 8206377 21.55 ug/l 99
81) Bromobenzene 17.87 156 1107300 20.64 ug/l 100
82) 1,3,5-Trimethylbenzene 18.03 105 5086762 21. 41 ug/l 100
83) 2-Chlorotoluene 18.04 " 91 4981921 20.29 ug/l 99
84) 4-Chlorotoluene 18.12 91 4415406 21.90 ug/l 99
85) tert-Butylbenzene 18.48 ,134 1129382 21.57 ug/l 97
86) 1,2,4-Trimethylbenzene 18.52 105 4732673 21.48 ug/l 99
87) see-Butylbenzene 18.73 105 6908786 21.95 ug/l 99
88) p-Isopropyltoluene 18.89 1 119 5531220 22.38 ug/l 99
\" 89) 1,3-Diehlorobenzene 18.99 146 2260739 21.06 ug/l 100
jl 90) 1,4-Diehlorobenzene 19.12 ' 146 2199429 21.06 ug/l 100
T 91) n-Butylbenzene 19.34 91 5282308 22.44 ug/l 99 1_
R 92) 1,2-Diehlorobenzene 19.52 146 1768829 20.93 ug/l 100
.~' , 93) ." ug/l L, 1,2-Dibromo-3-ehloropropan 20.29 157 75666 20.48 100
94) 1, 2, 4-Triehlorobenzene 21.15. 180 818087 22.96 ug/l 99
95) Hexaehlorobutadiene 21.29 225 708811 23.63 ug/l 98
96) Naphthalene 21.43 128 979015 21. 46 ug/l 99
97) 1,2,3-Triehlorobenzene 21.68 ' 180 536519 22.06 ug/l 99
(#) = qualifier out of range (m) = manual integration ~~
RDC594.D V067D26.M Thu Apr 27 08:34:10 2023 ~\\I~~ Page 3
REPORT ID: 23E120 Page 166 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC594.D
Aeq On 26 Apr 2023 11:19 am
Vial: 8
Operator: VLu
Inst 67 Sample V067D267
Mise 20ppb 8260/100ppb KET-AA/500ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Initial Calibration
~~~;+'lf7
I I 1.2e+07
,
: I i 1.15e+071
I lle+071
1.05e+071
1e+07j
95000001
90000001
8500000J
I
80000001
7500000j
7000000
6500000
60000001
j
5500000
5000000
4500000
i
4000000
:;: :;:
I-:": I-:":
~ ~
IV :;:.,
3500000 1 oI!i:;:~ -"'iD...=e i ~ Sil1uf.9 , ~ alii
3000000: ~ ~9
:::::::jlii 11 tl~!
1500000~! ~ i~ /1111\
2li>. .-215 b Ii ,I
,.9.q; 0.9 ~ ~ ~ Ii 1000000j~4> ~ ~ i~ !II \ :1
1\1-I ii I \ i fI ~ I \ Ii I ; i /I i I II
5000001\ [VI I': ill I i:\ 1\ 1\1 \ I! '\1' 'A' I' 1,1 i,l I J \ I ;1\1\ v \! V ill 0 1 v' jJ ,J ~
Time--> 2.00 3.00 4.00
RDC594.D V067D26.M
TIC: RDC594.D
Thu Apr 27 08:34:12 2023 Page 4
REPORT ID: 23E120 Page 167 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D
Acq On 26 Apr 2023 11:45 am
Sample V067D268
l'-1isc 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
L
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
"System Monitoring Compounds
:: 36) Dibromofluoromethane
r, Spiked Amount 10.000
1 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
-11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
i'. 13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.14
15.60
19.49
8.19
9.29
12.97
17.60
1.85
2.11
2.23
2.68
2.70
2.80
2.96
3.50
3.57
3.59
3.76
3.90
4.22
4.28
4.50
4.53
4.75
4.79
5.02
5.68
5.87
5.93
6.62
6.91
7.20
7.30
7.68
114 2178360
117 1613031
152 510627
10.00 ug/l
10.00 ug/l
10.00 ug/l
111
65
98
95
1646989 31.72
Recovery
1238869 31.25
Recovery =
6993234 31.18
Recovery =
2054117 29.78
Recovery =
ug/l
317.20%
ug/l
312.50%
ug/l
311.80%
ug/l
297.80%
0.00
0.00
0.00
0.00
0.00
0.00
0.00
85
50
62
94
64
67
1966056
3153506
2890583
1925272
2027647
3904639
2240764
29.57 ug/l
27.32 ug/l
28.26 ug/l
30.52 ug/l
30.25 ug/l
30.81 ug/l
29.96 ug/l
Qvalue
99
101
56
151
43
{ 61
59
142
43
76
49
53
73
, 96
45
.( 63
43
59
72
77
) 96
83
798481
1498839
1240607
3664538
1891497
3367607
880577
7792094
2903974
1854931
3302559
2563175
7557565
4168222
2369936
5036871
469313
2670319
2469928
3332128
156.51 ug/l
30.74 ug/l
142.00 ug/l
30.64 ug/l
788.11 ug/l
32.18 ug/l
31.01 ug/l
31.26 ug/l
28.69 ug/l
161.85 ug/l
31.74 ug/l
31.09 ug/l
31.40 ug/l
31.22 ug/l
31.05 ug/l
30.53 ug/l
161.50 ug/l
30.65 ug/l
31.58 ug/l
30.89 ug/l
100
99
99
98
100
100
100
100
98
100
98
98
99
100
99
100
100
100
100
100
100
99
99
99
100
99
(#) = qualifier out of range (m) = manual integration
RDC595.D V067D26.M Thu Apr 27 08:34:21 2023 Page 1
REPORT ID: 23E120 Page 168 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D
Aeq On 26 Apr 2023 11:45 am
Sample V067D268
Mise 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
IJast Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
33)
34)
35)
37)
38)
39 )
40 )
41)
42)
<: 44)
'1 45)
I 46)
F 47)
I: 48)
49)
50)
51)
52)
53)
54)
57)
58)
59 )
60)
61)
62)
63)
64)
65)
66)
67)
68)
69 )
70)
71)
72)
73)
75)
76)
78)
79)
Bromochloromethane
Tetrahydrofuran
tert-Amyl alcohol
Cyclohexane
1, 1, 1-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methyleyclohexane
l,2-Diehloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Diehloropropane
Tetrachloroethene
Dibromoehloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetraehloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
l,l,2,2-Tetraehloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
8.05
8.14
8.15
8.56
8.57
8.73
8.92
9.10
9.25
9.47
9.48
10.72
10.81
11.09
11.51
11.60
11. 60
12.20
12.24
12.56
13.10
13.48
13.51
13.75
13.80
14.18
14.24
14.59
14.94
15.27
15.66
15.75
15.76
15.89
16.62
16.70
17.22
17.24
17.50
17.72
17.82
130
42
59
84
97
57
110
119
87
78
62
130
! 83
63
83
88
93
{ 63
43
75
91
75
69
97
43
76
164
129
107
r 91
112
131
, 91
91
I 91
104
1105
173
83
110
53
1007709
284645
313446
3825113
2810323
9633568
1172883
2322163
838377
9151930
1602518
2261945
4255080
2081141
2286362
163153
843449
382549
5341866
3029966
8947797
2135172
1530549
1085630
3333993
2147241
1765847
1224191
979895
3918902
5140043
1518853
10184577
14593964
7024641
5513181
9182931
576063
1094854
292464
313590
31.74 ug/l
30.20 ug/l
164.56 ug/l
31.44 ug/l
31.18 ug/l
30.00 ug/l
31.46 ug/l
31.89 ug/l
32.64 ug/l
31.48 ug/l
31.36 ug/l
31. 47 ug/l
31.39 ug/l
31.73 ug/l
32.21 ug/l
640.67 ug/l
32.04 ug/l
32.44 ug/l
166.75 ug/l
32.78 ug/l
31.19 ug/l
33.01 ug/l
32.70 ug/l
31.86 ug/l
165.99 ug/l
31.98 ug/l
31.02 ug/l
32.38 ug/l
32.34 ug/l
31.94 ug/l
31.42 ug/l
31.64 ug/l
31.57 ug/l
62.52 ug/l
31. 92 ug/l
32.69 ug/l
31.92 ug/l
31.80 ug/l
31.26 ug/l
31. 04 ug/l
32.01 ug/l
(#) = qualifier out of range (m) = manual integration ~V~
RDC595.D V067D26.M Thu Apr 27 08:34:22 2023 ,75{\(~5
Qvalue
99
94
100
100
99
100
99
99
99
100
100
99
100
100
99
98
99
100
100
100
99
97
98
99
99
98
99
100
100
100
100
100
99
97
99
100
99
99
100
97
100
Page 2
REPORT ID: 23E120 Page 169 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D
Aeq On 26 Apr 2023 11:45 am
Sample V067D268
Mise 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
80 ) n-Propylbenzene 17.81 < 91 11394667 30.70 ug/l
81) Bromobenzene 17.87 156 1609943 30.79 ug/l
>" 82) l,3,5-Trimethylbenzene 18.03 105 7105446 30.69 ug/l
l' 83) 2-Chlorotoluene 18.04 ~ 91 7008404 29.29 ug/l
84) 4-Chlorotoluene 18.12 ( 91 6344012 32.28 ug/l
85) tert-Butylbenzene 18.48 134 1589453 31.14 ug/l
86) 1, 2, 4-Trimethylbenzene 18.52 1.05 6658044 31.00 ug/l
87) see-Butylbenzene 18.73 1105 9554084 31.14 ug/l
88) p-Isopropyltoluene 18.89 119 7711282 32.01 ug/l
89) l,3-Diehlorobenzene 18.99 ,146 3255873 31.12 ug/l
90) l,4-Diehlorobenzene 19.12 1 146 3187777 31.31 ug/l
91) n-Butylbenzene 19.34 91 7380811 32.18 ug/l
92) l,2-Diehlorobenzene 19.52 i 146 2547568 30.92 ug/l
r 93) l,2-Dibromo-3-ehloropropan 20.29 157 119028 33.06 ug/l L
94) 1, 2, 4-Triehlorobenzene 21.15 '180 1184390 34.11 ug/l
95) Hexaehlorobutadiene 21.29 225 970237 33.18 ug/l
96) Naphthalene 21.43 128 1533466 34.49 ug/l
97) l,2,3-Triehlorobenzene 21.68 '180 801158 33.80 ug/l
'"
L,
Qvalue
99
100
99
99
99
98
98
98
99
100
99
98
100
98
100
98
99
99
_______________________________________________________ ~_~~~-l[~~-----
(#) = qualifier out of range (m) = manual integration
RDC59S.D V067D26.M Thu Apr 27 08:34:22 2023 Page 3
REPORT ID: 23E120 Page 170 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC595.D
Acq On 26 Apr 2023 11:45 am
Sample V067D268
Mise 30ppb 8260/150ppb KET-AA/750ppb TBA
Vial: 9
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 26 14:35 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
~bundance
I 1.7e+07i
1.6e+07j
1.5e+07
1.4e+071
I
1.3e+07j
1.2e+07
1.1e+07 I
1e+07
9000000, ,
80000001
I
70000001
6000000) • •
I ...: ...:
I ~ ~
50000001 l i§j
I ~ I~~
; ~ooQ) D:2C
4000000j i N." ~';:'~
3000000
li% i: l.~I~Jjt~j
gl e;n 1\ I
2000000 II ~ d ~ i ~II\ II I,,:§~\ ~ i fl1!: 1,11\ /, II
10 i\~ 11/'" Iii J\ II
1 000000 i I, l!{\ liil!i\11
I ' I " 'I ,'1 1 '1 ' I,. I: i I \ \ i Ii \ i \ i I
IV, Ir~ ,: i Ii \ i \1 d \' I ! V '\J if ~ \ : V \j \1 \
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC595.D
0' ,v \j ,
:rime-> 2.00 3.00' 4.bo' 5.00
RDC595.D V067D26.M Thu Apr 27 08:34:25 2023 ~~ LA--~' Page 4 5 \ \( ~ ~ REPORT ID: 23E120 Page 171 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D Vial: 14
OpArntor: VLu Aeq On 26 Apr 2023 1:51 pm
Sample V067D2611 Inst 67
Mise 50ppb 8260/250ppb KET-AA/1250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
'I 77) 4-Bromofluorobenzene
Spiked Amount 10.000
=Target Compounds
2) Dichlorodifluoromethane
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
34) Tetrahydrofuran
10.15
15.60
19.49
8.19
9.29
12.97
17.60
1. 85
2.70
2.70
2.80
2.96
3.50
3.59
3.59
3.78
3.90
4.23
4.28
4.50
4.53
4.76
4.80
5.02
5.70
5.89
5.94
6.63
6.91
7.20
7.32
7.68
8.06
8.14
<
114 2392742
117 1760980
152 535606
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.00
111 2900655 50.87
Recovery =
65 2104879 48.34
Recovery
98 12268379 50.10
Recovery
95 3588641 49.60
85
94
64
67
101
56
151
43
( 61
59
142
43
76
49
53
73
196
45
63
43
59
72
77
)96
83
130
42
Recovery =
3482982
3420011
3620627
6775580
3884595
1292085
2623613
2081854
6346190
3367195
5851047
1447824
13112496
5056338
3092098
5630027
4528322
13606758
7375748
4141325
8861822
775201
4693342
4357690
5939377
1732301
476829
47.69
49.36
49.18
48.67
47.28
230.56
48.99
216.94
48.31
1277.27
50.90
46.41
47.89
45.48
245.62
49.26
50.01
51.46
50.30
49.39
48.90
242.86
49.04
50.72
50.13
49.68
46.06
ug/l
508.70%
ug/l
483.40%
ug/l
501.00%
ug/l
496.00%
0.00
0.00
0.00
0.00
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
100
99
100
100
99
100
99
99
96
99
99
100
100
100
100
99
100
100
100
100
97
99
100
99
99
94
(#) = qualifier out of range (m) = manual integration
RDC600.D V067D26.M Thu Apr 27 08,37,00 2023 ~ZS\ \1'2-5 Page 1
REPORT ID: 23E120 Page 172 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D
Acq On 26 Apr 2023 1:53 pm
Sample V067D2611
Misc 50ppb 8260/250ppb KET-AA/1250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
14
VLu
67
1. 00
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
35)
37)
;" 38)
r 39)
~: 40)
~,; 41)
IV. 42)
1/
44)
45)
46)
47)
48)
49)
50)
51)
52)
53)
54)
57)
58)
59)
60 )
61)
62)
63)
64)
65)
66)
67)
68)
69)
70)
71)
72)
73)
75)
76)
78)
79)
80 )
81 )
tert-Amyl alcohol
Cyclohexane
l,l,l-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
8.15
8.57
8.57
8.75
8.92
9.10
9.25
9.48
9.49
10.72
10.81
11.09
11.53
11.61
11.60
12.20
12.24
12.58
13.12
13.48
13.53
13.75
13.81
14.19
14.24
14.61
14.94
15.28
15.66
15.75
15.76
15.89
16.63
16.70
17.24
17.24
17.50
17.72
17.82
17.82 I
17.87
59
84
97
57
110
119
87
78
62
130
r 83
63
83
I 88
93
63
43
J 75
91
r75
69
97
43
76
164
129
107
, 91
112
131
f 91
91
91
104
'105
'173
83
110
53
91
156
521022
6677876
4947182
16559234
2087343
4043984
1437900
16117401
2697568
4011128
7403990
3714716
3987435
276573
1420546
652397
8786100
5267135
15579106
3657886
2565646
1828281
5525737
3591323
3125407
2107093
1637939
6957530
9052252
2704600
17606821
22616967
12282406
9676272
15752982
970937
1788706
467469
513667
18141805
2767400
249.02
49.97
49.97
46.95
50.97
50.55
50.96
50.46
48.07
50.80
49.73
51. 57
51.13
988.74
49.13
50.36
249.69
51.87
49.75
51.80
50.20
49.15
252.00
48.99
50.30
51.05
49.51
51.95
50.69
51.61
49.99
88.76
51.13
52.55
50.16
51.10
48.69
47.31
49.99
46.60
50.45
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
(#) = qualifier out of range (m) = manual integration ~
RDC600.D V067D26.M Thu Apr 27 08:37:01 2023 ~ S(\('2-.t>
Qvalue
99
100
100
100
100
99
98
100
100
100
99
99
98
100
99
99
99
99
98
94
98
99
98
99
99
99
100
99
99
100
97
87
98
99
98
99
100
97
100
94
100
Page 2
REPORT ID: 23E120 Page 173 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D
Aeq On 26 Apr 2023 1:53 pm
Sample V067D2611
Mise 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Vial: 14
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
82) 1, 3, 5-Trimethylbenzene 18.03 ~ 105 12371593 50.94 ug/l 97
83) 2-Chlorotoluene 18.04 r 91 13026026 51.90 ug/l 97
84) 4-Chlorotoluene 18.12 f 91 10149438 49.24 ug/l 91
85) tert-Butylbenzene 18.48 134 2817710 52.63 ug/l 97
86) 1, 2, 4-Trimethylbenzene 18.52 105 11469914 50.92 ug/l 96
87) see-Butylbenzene 18.73 J 105 15675796 48.71 ug/l 95
88) p-Isopropyltoluene 18.89 119 13021893 51.53 ug/l 97
89 ) 1,3-Diehlorobenzene 19.01 '146 5611243 51.13 ug/l 99
90) 1,4-Diehlorobenzene 19.12 ( 146 5505209 51.55 ug/l 100
91) n-Butylbenzene 19.34 91 12631058 52.49 ug/l 96
92) 1,2-Diehlorobenzene 19.52 ( 146 4353984 50.38 ug/l 99
I 93) 1,2-Dibromo-3-ehloropropan 20.29 157 186296 49.33 ug/l 100
}" 94) 1, 2, 4-Triehlorobenzene 21.15 180 2024051 55.57 ug/l 99
95) Hexaehlorobutadiene 21.29 ( 225 1623597 52.93 ug/l 99
96) Naphthalene 21.43 128 2445901 52.44 ug/l 100
97) 1,2,3-Triehlorobenzene 21. 70 /180 1303865 52.45 ug/l 99
(#) = qualifier out of range (m) = manual integration
RDC600.D V067D26.M Thu Apr 27 08:37:01 2023 Page 3
REPORT ID: 23E120 Page 174 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC600.D
Aeq On 26 Apr 2023 1:53 pm
Sample V067D2611
Mise 50ppb 8260/250ppb KET-AA/1250ppb TBA
Vial: 14
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:36 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
~bundance
2.ge+07j
I
2.8e+07
j
l
2.7e+07
2.6e+07j
2.5e+071
2.4e+07
2.3e+07
2.2e+07
I
2.1e+071
2e+07
1.ge+07
1.8e+07
1.7e+071
1.6e+071
I
1.5e+071
I
1.4e+071
1.3e+071
1.2e+071
j 1.1e+07
1e+07j
9000000 1
8000000
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDC600.D
:rime--> 2.00 ioo 4. 0 5.00 6.06 7.008.00 9.00 10.00 11:00 12.00 13:00 14~00 15.00 16:00 1ioo 18:00 19:0020.00 21.00
RDC600.D V067D26.M Thu Apr 27 08:37:03 2023 Page 4
REPORT ID: 23E120 Page 175 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D Vial: 11
Operator: VLu Acq On 26 Apr 2023 12:36 pm
Sample V067D2610 Inst 67
Misc 100ppb 8260/500ppb KET-AA/2500ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
T'
L
Internal Standards
1) 1,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1,2-DICHLOROBENZENE-D4
~"System Monitoring Compounds
~ 36) Dibromofluoromethane
r,· Spiked Amount 10.000
~ 43) 1,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
~, 12) 1,1,2-Trichloro-1,2,2-trif
£ 13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1,1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
34) Tetrahydrofuran
R.T. Qlon Response Conc Units Dev(Min)
10.14 114
15.60 117
19.49 152
2218346
1621442
489219
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.19 111 5687718 107.58 ug/l 0.00
Recovery = 1075.80%
9.29 65 4209713 104.28 ug/l 0.00
Recovery = 1042.80%
12.97 98 22439298 . 99.53 ug/l 0.00
Recovery = 995.30%
17.60 95 6943214 105.07 ug/l 0.00
1.86
2.68
2.68
2.80
2.94
3.50
3.57
3.59
3.78
3.90
4.23
4.28
4.50
4.53
4.75
4.79
5.02
5.70
5.87
5.93
6.63
6.91
7.20
7.30
7.70
8.05
8.14
85
94
64
67
101
56
151
43
J 61
59
142
43
76
49
53
73
196
45
/' 63
43
59
72
77
i 96
83
130
42
Recovery 1050.70%
7148921
6506436
6864386
12173030
7579620
2623298
4822505
4217193
11726310
7026050
10893696
3341481
27227003
9529711
6558753
11171836
8448775
24916021
13532297
8936706
16624327
1630275
8130641
8166691
10841613
3381083
1004639
105.59 ug/l
101.29 ug/l
100.57 ug/l
94.32 ug/l
99.51 ug/l
504.91 ug/l
97.12 ug/l
474.00 ug/l
96.29 ug/l
2874.69 ug/l
102.22 ug/l
115.54 ug/l
107.26 ug/l
92.46 ug/l
561.96 ug/l
105.43 ug/l
100.65 ug/l
101.64 ug/l
99.53 ug/l
114.96 ug/l
98.94 ug/l
550.90 ug/l
91. 64 ug/l
102.53 ug/l
98.70 ug/l
104.58 ug/l
104.68 ug/l
Qvalue
100
100
100
100
99
100
100
99
99
96
98
100
100
99
99
100
99
99
100
100
98
92
99
100
100
100
93
(#) = qualifier out of range (m) = manual integration
RDC597.D V067D26.M Thu Apr 27 08:35:30 2023 Page 1
REPORT ID: 23E120 Page 176 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D
Acq On 26 Apr 2023 12:36 pm
Sample V067D2610
Misc 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: VLu
67
1. 00
Inst
Multiplr:
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
37)
38)
39)
40 )
41)
42)
44)
45)
46)
47)
~ 48)
J 49)
1< 50)
L 51)
52)
53)
54)
57)
58)
59)
60)
61)
62)
63)
64)
65)
66)
67)
68)
71)
72)
75)
76 )
78)
79)
81)
83)
84)
85)
89)
90)
Cyclohexane
l,l,l-Trichloroethane
2,2,4-Trimethylpentane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
trans-1,3-Dichloropropene
Ethyl methacrylate
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
o-Xylene
Styrene
Bromoform
1, 1, 2, 2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
Bromobenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
l,3-Dichlorobenzene
l,4-Dichlorobenzene
8.57
8.59
8.76
8.92
9.10
9.25
9.48
9.49
10.72
10.81
11.09
11.53
11.61
11.60
12.20
12.24
12.58
13.12
13.48
13.53
13.75
13.80
14.18
14.24
14.61
14.94
15.28
15.66
15.76
16.62
16.70
17.24
17.52
17.72
17.82
17.87
18.06
18.12
18.48
19.01
19.12
84
97
57
110
119
87
~. 78
62
130
83
63
83
88
93
63
43
« 75
91
./ 75
69
97
43
76
164
129
,107
91
112
131
E 91
104
/173
83
110
53
156
I 91
! 91
I 134
,146
146
13820806
8960822
34879949
3870800
7447609
2804930
28710378
5092236
7430308
15200565
6950021
7452403
573456
2824566
1377114
18223250
9970305
25126652
7074433
5240131
3614516
11535362
7101247
5759426
4087295
3269981
12634172
16183907
4980490
20770066
17202235
1974484
3507231
950690
1000722
5155221
19868173
16426557
5019910
9843138
9759302
111.54
97.63
106.67
101.94
100.42
107.22
96.96
97.87
101. 50
110.11
104.07
103.08
2211. 26
105.36
114.67
558.60
105.90
87.15
108.81
111.36
105.53
571.33
105.21
100.66
107.55
107.35
102.45
98.42
103.22
93.90
101.46
113.77
104.53
105.33
106.62
102.89
86.66
87.25
102.65
98.19
100.05
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
(#) = qualifier out of range (m) = manual integration ~~
RDC597.D V067D26.M Thu Apr 27 08:35:31 2023 ~(\I2-~
Qvalue
100
100
100
99
99
98
98
100
99
99
98
99
100
99
100
98
98
89
95
96
99
96
99
99
99
100
98
98
100
93
99
99
99
97
99
100
95
83
95
97
98
Page 2
REPORT ID: 23E120 Page 177 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D
Acq On 26 Apr 2023 12:36 pm
Sample V067D2610
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: VLu
67
1. 00
Inst
Multiplr:
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
92) l,2-Diehlorobenzene 19.52 ( 146 7780726 98.57 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.29 ,157 377536 109.45 ug/l 99
94) l,2,4-Triehlorobenzene 21.15 180 3637705 109.35 ug/l 100
~ 95) Hexaehlorobutadiene 21.29 225 2764705 98.68 ug/l 99
~. 96) Naphthalene 21.43;128 4947529 116.14 ug/l 100
jV 97) l,2,3-Triehlorobenzene 21.69 180 2462569 108.45 ug/l 99
tv
(#) = qualifier out of range (m) = manual integration
RDC597.D V067D26.M Thu Apr 27 08:35:31 2023 Page 3
REPORT ID: 23E120 Page 178 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC597.D
Acq On 26 Apr 2023 12:36 pm
Sample V067D2610
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
Vial: 11
Operator: VLu
Inst 67
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Apr 27 8:35 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
~bundance
! I
4.6e+071
4.4e+07
4.2e+07
4e+07
3.8e+07
3.6e+07
3.4e+07
3.2e+07
3e+07
2.8e+07
2.6e+07
I
2.4e+07j
I 2.2e+071
i
2e+07j
1.8e+07
I
I
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: RDCS97.D
RDC597.D V067D26.M Thu Apr 27 08:35:33 2023 Page 4
REPORT ID: 23E120 Page 179 of 560
SECOND SOURCE
VERIFICATION
REPORT ID: 23E120 Page 180 of 560
CONTINUE_CALIBRATION -CALIBRATION VERIFICATION
Instrument ID :67
IC Beginning DateTime :04/26/23 08:46
SpIke Amount :10 PPB
CC/CV File :RDC603
IC File :RDC593
M IDX Parameters
======= =====================================
1 1,4-DIFLUOROBENZENE
2 Dichlorodifluoromethane
3 Dichlorotetrafluoroethane
4 Chloromethane
5 Vinyl chloride
6 Bromomethane
7 Chloroethane
8 Dichlorofluoromethane
9 Trichlorofluoromethane
10 sec-Propyl alcohol
5 11 Acrolein
12 1,1,2-Trichloro-1,2,2-trifluoroethane
5 13 Acetone
14 1,1-Dichloroethene
25 15 tert-Butyl alcohol
16 Iodomethane
17 Methyl acetate
10 18 Acetonitrile
19 Carbon disulfide
20 Methylene chloride
5 21 Acrylonitrile
22 tert-Butyl methyl ether (MTBE)
23 trans-1,2-Dichloroethene
24 Isopropyl ether (DIPE)
25 1,1-Dichloroethane
26 Vinyl acetate
25 27 2-Butanol
28 tert-Butyl ethyl ether (ETBE)
5 29 2-Butanone
30 2,2-Dichloropropane
31 cis-1,2-Dichloroethene
32 Chloroform
33 Bromochloromethane
34 Tetrahydrofuran
5 35 tert-Amyl alcohol
36 Dibromofluoromethane
37 Cyclohexane
38 1,1,1-Trichloroethane
39 2,2,4-Trimethylpentane
40 1,1-Dichloropropene
41 Carbon tetrachloride
42 tert-Amyl methyl ether (TAME)
43 1,2-Dichloroethane-d4
44 Benzene
45 1,2-Dichloroethane
46 Trichloroethene
47 Methylcyclohexane
48 1,2-Dichloropropane
49 Bromodichloromethane
20 50 1,4-Dioxane
51 Dibromomethane
52 2-Chloroethyl vinyl ether
5 53 4-Methyl-2-pentanone
54 cis-1,3-Dichloropropene
55 CHLOROBENZENE-D5
56 Toluene-d8
57 Toluene
58 trans-l,3-Dichloropropene
59 Ethyl methacrylate
60 1,1,2-Trichloroethane
5 61 2-Hexanone
62 1,3-Dichloropropane
63 Tetrachloroethene
64 Dibromochloromethane
65 1,2-Dibromoethane
66 1-Chlorohexane
67 Chlorobenzene
68 1,1,1,2-Tetrachloroethane
69 Ethylbenzene
2 70 m-Xylene & p-Xylene
71 o-Xylene
72 Styrene
73 Isopropylbenzene
74 1,2-DICHLOROBENZENE-D4
75 Bromoform
76 1, 1, 2, 2-Tetrachloroethane
77 4-Bromofluorobenzene
78 1,2,3-Trichloropropane
79 trans-l,4-Dichloro-2-butene
80 n-Propylbenzene
81 Bromobenzene
82 1,3,5-Trimethylbenzene
83 2-Chlorotoluene
84 4-Chlorotoluene
85 tert-Butylbenzene
86 1,2,4-Trimethylbenzene
87 sec-Butylbenzene
88 p-Isopropyltoluene
89 1,3-Dichlorobenzene
90 1,4-Dichlorobenzene
91 n-Butylbenzene
92 1,2-Dichlorobenzene
93 1,2-Dibromo-3-chloropropane
94 1,2,4-Trichlorobenzene
95 Hexachlorobutadiene
96 Naphthalene
97 1,2,3-Trichlorobenzene
-spike Amount -Nom1nal Amount • M
CC_Con CC%_D CC_Resp CCRRF AvRRF CC_Rtm AVRtm
======= ===== ======== ===== :::;;=:::;;== ====== ======
10.000 0 2362609 1 1 10.137 10.142
8.355 -16.5 602546 0.255 0.305 1.859 1. 853
8.364 -16.4 1047257 0.443 0.530 2.120 2.117
9.567 -4.3 1061415 0.449 0.470 2.241 2.237
9.077 -9.2 621052 0.263 0.290 2.682 2.681
10.613 6.1 771458 0.327 0.308 2.703 2.697
10.848 8.5 1491252 0.631 0.582 2.803 2.791
10.313 3.1 836620 0.354 0.343 2.964 2.958
9.140 -8.6 483393 0.205 0.224 3.573 3.577
44.470 -11.1 421380 0.036 0.040 3.594 3.591
9.052 -9.5 1174074 0.497 0.549 3.757 3.763
216.581 -13.4 563773 0.010 0.011 3.900 3.913
10.097 1.0 1146131 0.485 0.480 4.234 4.230
8.939 -10.6 275356 0.117 0.130 4.278 4.281
10.350 3.5 2798378 1.184 1.144 4.497 4.499
8.697 -l3.0 954677 0.404 0.465 4.512 4.525
45.742 -8.5 568595 0.048 0.053 4.745 4.754
9.221 -7.8 1040725 0.440 0.478 4.789 4.799
9.400 -6.0 840464 0.356 0.378 5.023 5.025
9.775 -2.3 2552049 1.080 1.105 5.681 5.693
9.681 -3.2 1401840 0.593 0.6l3 5.871 5.877
10.136 1.4 839174 0.355 0.350 5.929 5.937
9.090 -9.1 1626697 0.689 0.757 6.616 6.631
45.054 -9.9 142000 0.012 0.013 6.893 6.910
9.558 -4.4 903274 0.382 0.400 7.200 7.199
9.232 -7.7 783244 0.332 0.359 7.302 7.306
9.530 -4.7 1114949 0.472 0.495 7.682 7.686
8.969 -10.3 308840 0.131 0.146 8.048 8.053
9.330 -6.7 95373 0.040 0.043 8.l35 8.138
46.906 -6.2 96904 0.008 0.009 8.150 8.165
10.498 5.0 591137 0.250 0.238 8.179 8.194
10.251 2.5 1352848 0.573 0.559 8.559 8.565
9.746 -2.5 952763 0.403 0.414 8.574 8.579
10.788 7.9 3756893 1.590 1.474 8.734 8.740
9.439 -5.6 381740 0.162 0.171 8.924 8.925
9.691 -3.1 765503 0.324 0.334 9.100 9.102
9.323 -6.8 259776 0.110 0.118 9.231 9.248
10.029 0.3 431239 0.183 0.182 9.290 9.290
9.614 -3.9 3032099 1.283 1. 335 9.465 9.468
9.344 -6.6 517837 0.219 0.235 9.479 9.487
9.596 -4.0 748188 0.317 0.330 10.722 10.724
10.454 4.5 1537065 0.651 0.622 10.809 10.810
9.531 -4.7 677918 0.287 0.301 11.087 11.085
9.267 -7.3 713603 0.302 0.326 11.525 11. 520
173.816 -13.1 48008 0.001 0.001 11.598 11.612
8.782 -12.2 250739 0.106 0.121 11.598 11.601
48.815 -2.4 1696055 0.144 0.147 12.241 12.246
9.616 -3.8 964227 0.408 0.424 12.563 12.569
10.000 0 1712570 1 1 15.602 15.602
10.697 7.0 2547480 1.488 1.390 12.972 12.972
9.536 -4.6 2904335 1.696 1.778 l3 .103 l3 .108
9.730 -2.7 668253 0.390 0.401 13.483 13.487
9.324 -6.8 463423 0.271 0.290 l3.527 13.520
8.998 -10.0 325542 0.190 0.211 13.746 13.747
47.546 -4.9 1013935 0.118 0.125 13.804 l3.809
9.058 -9.4 645730 0.377 0.416 14.184 14.188
9.568 -4.3 578274 0.338 0.353 14.243 14.243
9.061 -9.4 363699 0.212 0.234 14.608 14.601
8.877 -11. 2 285612 0.167 0.188 14.944 14.946
9.686 -3.1 1261704 0.737 0.761 15.280 15.272
9.380 -6.2 1629224 0.951 1.014 15.660 15.662
9.299 -7.0 473934 0.277 0.298 15.748 15.750
9.563 -4.4 3275548 1. 913 2.000 15.762 15.763
19.853 -0.7 4920075 1.436 1.447 15.894 15.895
9.931 -0.7 2320095 1.355 1.364 16.625 16.625
9.810 -1. 9 1756894 1. 026 1. 046 16.698 16.695
9.372 -6.3 2862494 1.671 1.783 17.23B 17.228
10.000 0 534462 1 1 19.48B 19.489
9.036 -9.6 171323 0.321 0.355 17.238 17.239
8.778 -12.2 321780 0.602 0.686 17.501 17.506
10.308 3.1 744145 1.392 1.351 17.603 17.604
8.447 -15.5 83296 0.156 0.184 17.720 17.717
10.273 2.7 105347 0.197 0.192 17.823 17.B22
9.704 -3.0 3769938 7.054 7.269 17.B23 17.8l3
8.980 -10.2 491529 0.920 1.024 17.866 17.867
9.433 -5.7 2286111 4.277 4.534 18.027 18.028
9.262 -7.4 2320026 4.341 4.686 18.042 18.045
B.731 -12.7 1795993 3.360 3.B49 18.115 18.114
9.693 -3.1 517870 0.969 1. 000 18.480 18.481
9.659 -3.4 2171469 4.063 4.206 18.524 18.525
9.872 -1. 3 3170170 5.932 6.008 18.729 18.731
9.764 -2.4 2462340 4.607 4.718 1B.889 18.890
9.192 -8.1 1006744 1. 884 2.049 19.006 19.001
9.047 -9.5 964079 1.804 1.994 19.123 19.124
9.963 -0.4 2392370 4.476 4.492 19.342 19.343
8.973 -10.3 773778 1.448 1.613 19.517 19.518
8.725 -12.7 32882 0.062 0.071 20.306 20.293
10.354 3.5 376327 0.704 0.680 21.154 21.156
9.625 -3.B 294610 0.551 0.573 21. 285 21. 286
9.051 -9.5 421247 0.788 0.871 21.432 21.434
9.959 ~I 247062 0.462 0.464 21. 695 21.688
-------I------------------
Column Spec :RTX502.2 ID :0.25MM
IC_Ending DateTime :04/26/23 13:53
HPChem Method :V067D26
Date_Time :04/26/23 15:39
%_RSD cO_XO Co_Xl Co_X2 co_Cor
===== ======= ======= ======= ======
0
5.66
9.57
8.00
5.68
6.63
4.77
6.58
3.75
14.65
4.80
6.45
6.34
8.01
7.27
9.90
8.95
5.25
3.80
5.08
4.26
9.85
5.33
6.91
4.81
5.58
3.69
6.20
4.96
9.29
8.45
9.25
4.92
7.68
5.48
6.91
7.89
5.46
4.46
5.01
5.21
8.11
7.04
5.74
6.36
6.59
9.02
8.11
0
6.69
6.30
9.38
8.35
6.90
9.36
5.77
4.74
7.11
8.26
6.75
4.93
5.81
5.46
6.45
6.33
7.51
7.40
0
7.64
5.07
3.39
5.75
5.86
5.54
3.78
4.94
7.12
7.90
5.78
5.24
6.06
8.l3
3.31
4.1B
8.74
3.04
9.29
11.99
11.91
11.97
9.14
--------------------------------
REPORT ID: 23E120 Page 181 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Acq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M 1,1,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M I odome thane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
25 P,T,M 1,1-Dichloroethane
2~ T,M Vinyl acetate
27 T,M 2-Butanol
28' T, M tert -Butyl ethyl ether (ETB
~9 T,M 2-Butanone
30 TIM 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
~3 T,M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
37 T,M Cyclohexane
~8 T,M 1,1,1-Trichloroethane
39 T,M 2,2,4-Trimethylpentane
40 T,M 1,1-Dichloropropene
4] T,M Carbon tetrachloride
Amount Calc.
10.000 10.000
10.000 8.356
-1.000 0.000
10.000 8.364
10.000 9.567
10.000 9.078
10.000 10.613
10.000 10.849
10.000 10.313
-1.000 0.000
50.000 0.000
10.000 9.141
50.000 44.470
10.000 9.052
250.000 216.582
10.000 10.098
10.000 8.940
-1.000 0.000
10.000 10.351
10.000 8.697
50.000 45.743
10.000 9.221
10.000 9.401
10.000 9.775
10.000 9.681
10.000 10.136
-1.000 0.000
10.000 9.090
50.000 45.054
10.000 9.559
10.000 9.233
10.000 9.531
10.000 8.969
10.000 9.331
50.000 46.906
10.000 10.499
10.000 10.252
10.000 9.747
10.000 10.788
10.000 9.440
10.000 9.692
%Dev Area% Dev(min)
0.0
16.4
0.0
16.4
4.3
9.2
-6.1
-8.5
-3.1
0.0
100.0#
8.6
11.1
9.5
13.4
-1. 0
10.6
0.0
-3.5
13.0
8.5
7.8
6.0
2.2
3.2
-1.4
0.0
9.1
9.9
4.4
7.7
4.7
10.3
6.7
6.2
-5.0
-2.5
2.5
-7.9
5.6
3.1
108
85
o
85
92
88
103
118
101
o
o
100
99
99
94
107
89
o
100
101
97
99
103
107
106
100
o
101
96
105
101
105
96
99
91
108
101
106
106
103
104
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.00
-3.50#
0.00
0.02
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
~~---------------------------------~--------------------------------------
)~#) = Out of Range
~RDC603.D V067D26.M Thu Apr 27 08:37:21 2023 3LA-5{ \( 2-3 Page 1
REPORT ID: 23E120 Page 182 of 560
Evaluate Continuing Calibration Report
-:,-~' Data File D: \HPCHEM\l \DATA\23D26\RDC603.D
" Acq On 26 Apr 2023 3: 39 pm
.:~ ", ~" Sample IV067D2601
., 1 Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
, . MS Integration Params: RTE. P
Vial: 17
Operator: VLu
67
1. 00
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
j.
Last Update
Response via
~"' Min. RRF
~:r ;~. Max. RRF Dev
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
, --------------------------------------------------------------------------
42 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
44 T,M Benzene
45 T,M l,2-Dichloroethane
4b T,M Trichloroethene
47 T,M Methylcyclohexane
4£ C,T,M l,2-Dichloropropane
-~ 9 T, M Bromodichloromethane
50 T,M l,4-Dioxane
51 T,M Dibromomethane
52 T,M 2-Chloroethyl vinyl ether
53 T,M 4-Methyl-2-pentanone
$4 T,M cis-1,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
51 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
~9 T,M Ethyl methacrylate
60 T,M l,l,2-Trichloroethane
6i T,M 2-Hexanone
e~ T,M l,3-Dichloropropane
63 T,M Tetrachloroethene
641 T,M Dibromochloromethane
&5 T,M l,2-Dibromoethane
66 T,M 1-Chlorohexane
67 P,M Chlorobenzene
68 T,M l,l,l,2-Tetrachloroethane
69 C,T,M Ethylbenzene
10 T,M m-Xylene & p-Xylene
~1 T,M o-Xylene
72 T,M Styrene
1-3 T,M Isopropylbenzene
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
9.324
10.030
9.615
9.345
9.597
10.455
9.531
9.268
173.816
8.782
0.000
48.815
9.617
10.000
10.698
9.537
9.731
9.324
8.998
47.547
9.058
9.569
9.061
8.878
9.687
9.380
9.300
9.564
19.854
9.931
9.811
9.373
6.8
-0.3
3.8
6.5
4.0
-4.6
4.7
7.3
13.1
12.2
100.0#
2.4
3.8
0.0
-7.0
4.6
2.7
6.8
10.0
4.9
9.4
4.3
9.4
11.2
3.1
6.2
7.0
4.4
0.7
0.7
1.9
6.3
98
103
105
101
105
102
104
101
94
95
o
102
103
107
109
102
103
100
97
98
97
104
96
93
103
102
101
103
105
106
105
100
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
-0.01
0.00
-12.20#
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
~4 I l,2-DICHLOROBENZENE-D4 10.000 10.000 0.0 107 0.00
'5 P,T,M Bromoform 10.000 9.036 9.6 98 0.00
~@ P,T,M l,l,2,2-Tetrachloroethane 10.000 8.778 12.2 94 0.00
W~ S 4-Bromofluorobenzene 10.000 10.308 -3.1 109 0.00
'1f}-E} T,M l,2,3-Trichloropropane 10.000 8.447 15.5 89 0.00
1J}~-T, M trans-1, 4 -Dichloro-2 -butene 10.000 10.274 -2.7 110 0.00
~~ T,M n-Propylbenzene 10.000 9.704 3.0 105 0.01
'4------------------------------------------------------------------------
5{#) = Out of Range
GRDC603.D V067D26.M
~ ,-
Page 2
REPORT ID: 23E120 Page 183 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Acq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Misc 10ppb 8260/50ppb KET-AA/250ppb
{" MS Integration Params: RTE. P
TBA
Vial: 17
Operator: VLu
67
1. 00
Inst
Multiplr:
Method
;,:1' Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
'J~~ Last Update
Response via
1): Min. RRF
1'~) Max. RRF Dev
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc . %Dev Area% Dev(min)
81
82
83
84
'B5
"86
8.7
'8.8
89
BO
"91L
92
:98
9A
:$;5
~~tb
97
a
E
f-
"f.;
8
81.
8:;;
Sr
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
. Bromobenzene
l,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1, 2, 4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
l,3-Dichlorobenzene
l,4-Dichlorobenzene
n-Butylbenzene
l,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
l,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
1, 2, 3-Trichlorobenzene
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
8.980
9.433
9.263
8.731
9.693
9.660
9.873
9.764
9.192
9.047
9.964
8.973
8.726
10.355
9.625
9.051
9.959
10.2 100 0.00
5.7 103 0.00
7.4 105 0.00
12.7 92 0.00
3.1 108 0.00
3.4 105 0.00
1.3 105 0.00
2.4 103 0.00
8.1 101 0.01
9.5 100 0.00
0.4 106 0.00
10.3 98 0.00
12.7 93 0.01
-3.6 109 0.00
3.8 102 0.00
9.5 97 0.00
0.4 107 0.01
~... ~ fA-5"J \ [2.. S L ____________________________________________________________ ~ ________ _
.,(#) = Out of Range
;. 0
~RDC603.D V067D26.M
SPCC's out = 0 CCC's out = 0
Thu Apr 27 08:37:22 2023 Page 3
REPORT ID: 23E120 Page 184 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
':;; Acq On 26 Apr 2023 3: 39 pm
Sample IV067D2601
.: Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
67
1. 00
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
i.--------------------------------------------------------------------------
i
2
3
.;4;
:5
~'6
I 1,4-DIFLUOROBENZENE
T,M Dichlorodifluoromethane
T,M Dichlorotetrafluoroethane
P,T,M Chloromethane
C,T,M Vinyl chloride
T,M Bromomethane
~~ T,M Chloroethane
.. 8 T, M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M 1,1,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16
17
18
19
2@
2f
2:&
230
24
T,M Iodomethane
T,M Methyl acetate
T,M Acetonitrile
T,M Carbon disulfide
T,M Methylene chloride
T,M Acrylonitrile
T,M tert-Butyl methyl ether (MT
T,M trans-1,2-Dichloroethene
T,M Isopropyl ether (DIPE)
2~ P,T,M 1,1-Dichloroethane
27
28
19
:30
31
32
33
3-4
].5
36
1-1)
~@i
§g
40'
T,M Vinyl acetate
T,M 2-Butanol
T,M tert-Butyl ethyl ether (ETB
T,M 2-Butanone
T,M 2,2-Dichloropropane
T,M cis-1,2-Dichloroethene
C,T,M Chloroform
T,M Bromochloromethane
T,M Tetrahydrofuran
T,M tert-Amyl alcohol
S Dibromofluoromethane
T,M Cyclohexane
T,M 1,1,1-Trichloroethane
T,M 2,2,4-Trimethylpentane
T,M 1,1-Dichloropropene
T,M Carbon tetrachloride
1.000 1.000
0.305 0.255
0.000 0.000
0.5301" 0.443
0.470 0.449
0.290 0.263
0.308 0.327
0.582 0.631
0.343 0.354
0.000 0.000
0.023 0.000
0.224 0.205
0.040 .0.036
0.549 0.497
0.011 0.010
0.480 0.485
0.130 0.117
0.000 0.000
1.144 1.184
0.465 0.404
0.053 0.048
0.478 0.440
0.378 0.356
1.105 1. 080
0.613/ 0.593
0.350 0.355
0.000 0.000
0.757 0.689
0.013, 0.012
0.400 0.382
0.359 0.332
0.495 0.472
0.146 0.131
0.043 0.040
0.009 0.008
0.238 0.250
0.559 0.573
0.414 0.403
1.474 1.590
0.171 0.162
0.334 0.324
0.0
16.4
0.0
16.4
4.5
9.3
-6.2
-8.4
-3.2
0.0
100.0#
8.5
10.0
9.5
9.1
-1. 0
10.0
0.0
-3.5
13.1
9.4
7.9
5.8
2.3
3.3
-1.4
0.0
9.0
7.7
4.5
7.5
4.6
10.3
7.0
11.1
-5.0
-2.5
2.7
-7.9
5.3
3.0
108
85
0#
85
92
88
103
118
101
0#
0#
100
99
99
94
107
89
0#
100
101
97
99
103
107
106
100
0#
101
96
105
101
105
96
99
91
108
101
106
106
103
104
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.00
-3.50#
0.00
0.02
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
2~------------------------------------------------------------___________ _
2~#) = Out of Range
)~DC603.D V067D26.M Thu Apr 27 08:37:27 2023 :7 tA
5'1\ft~ Page 1
REPORT ID: 23E120 Page 185 of 560
" '('
-,;R, Evaluate Continuing Calibration Report
Data File D:\HPCHEM\I\DATA\23D26\RDC603.D
.~ , Acq On 26 Apr 2023 3:39 pm
3 Sample IV067D2601
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
67
1. 00
Inst
Multiplr:
. ' -~ . : Method
Title
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
J:~, Last Update
,'{1 Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
.j' ; Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
4;2 T,M tert-Amyl methyl ether (TAM
43 S 1,2-Dichloroethane-d4
44 T,M Benzene
45 T,M 1,2-Dichloroethane
~6 T,M Trichloroethene
47 T,M Methylcyclohexane
48 C,T,M 1,2-Dichloropropane
49 T,M Bromodichloromethane
50 T,M 1,4-Dioxane
~d T, M Dibromomethane
£12 T,M 2-Chloroethyl vinyl ether
S~ T,M 4-Methyl-2-pentanone
54 T,M cis-l,3-Dichloropropene
5~5 I CHLOROBENZENE-D5
-£.6 S Toluene-d8
f:r7 C, T, M Toluene
58 T,M trans-l,3-Dichloropropene
19 T,M Ethyl methacrylate
60 T,M 1,I,2-Trichloroethane
61 T,M 2-Hexanone
62 T,M l,3-Dichloropropane
63 T,M Tetrachloroethene
64 T,M Dibromochloromethane
65 T,M l,2-Dibromoethane
66 T,M 1-Chlorohexane
~7 P,M Chlorobenzene
&8 T,M l,l,l,2-Tetrachloroethane
~9 C,T,M Ethylbenzene
~g T,M m-Xylene & p-Xylene
?'?f T, M o-Xylene
72 T,M Styrene
~~ T,M Isopropylbenzene
~4 I l,2-DICHLOROBENZENE-D4
~~ P,T,M Bromoform
1>,'~ P, T, M I, I, 2,2 -Tetrachloroethane
~1 S 4-Bromofluorobenzene
~8 T,M l,2,3-Trichloropropane
~9 T,M trans-1,4-Dichloro-2-butene
~O T,M n-Propylbenzene
AvgRF
0.118
0.182
1.335
0.235
0.330
0.622
0.301
0.326
0.001
0.121
0.054
0.147
0.424
1.000
1.390
CCRF
0.110
0.183
1. 283
0.219
0.317
0.651
0.287
0.302
0.001
0.106
0.000
< 0 .144
0.408
1.000
1.488
1.696
0.390
0.271
0.190
1.778
0.401
0.290
0.211
0.125
0.416
0.353
0.234
0.188
0.761
1.014
0.298 7
/ 0.118
0.377
0.338
0.212
0.167
0.737
2.000
1.447
1.364
1.046
1.783
1.000
0.355
0.686
1.351
0.184
0.192
7.269
0.951
0.277
1.913
1.436
1. 355
1.026
1.671
1.000
! 0.321
/ 0.602
1. 392
0.156
0.197
7.054
%Dev Area% Dev(min)
6.8
-0.5
3.9
6.8
3.9
-4.7
4.7
7.4
0.0
12.4
100.0#
2.0
3.8
0.0
-7.1
4.6
2.7
6.6
10.0
5.6
9.4
4.2
9.4
11. 2
3.2
6.2
7.0
4.3
0.8
0.7
1.9
6.3
0.0
9.6
12.2
-3.0
15.2
-2.6
3.0
98
103
105
101
105
102
104
101
94
95
0#
102
103
107
109
102
103
100
97
98
97
104
96
93
103
102
101
103
105
106
105
100
107
98
94
109
89
110
105
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
-0.01
0.00
-12.20#
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.01
~-------------------------------------------------------------------------
~(#) = Out of Range
6RDC603.D V067D26.M Thu Apr 27 08:37:30 2023 Page 2
REPORT ID: 23E120 Page 186 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Aeq On 26 Apr 2023 3:39 pm
Vial: 17
Operator: VLu
Sample IV067D2601 Inst 67
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
7/j Title
·t~)' Last Update
~~(f;' Response via
'f.i.,
'f" ..
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000
20%
Min. ReI. Area
Max. ReI. Area
50%
200%
Max. R.T. Dev 0.16min
Compound AvgRF CCRF %Dev Area% Dev(min)
81
82
83
'84
a\!5
8"6
'2)7
l~:8
'89
9'fJ
9~
~9~
~93
'94
'95
'96
97
&\
;;::
.8-.
34.
8(tE
B.t:
-6<':
e8B
8S'
'1;:' (}
~'::
.9'~.
t,-
-'
£;r
(:'
,~.
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
T, M
Bromobenzene
l,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1, 2, 4-Trimethylbenzene
see-Butylbenzene
p-Isopropyltoluene
l,3-Diehlorobenzene
l,4-Diehlorobenzene
n-Butylbenzene
l,2-Diehlorobenzene
l,2-Dibromo-3-ehloropropane
l,2,4-Triehlorobenzene
Hexaehlorobutadiene
Naphthalene
l,2,3-Triehlorobenzene
1.024
4.534
4.686
3.849
1.000
4.206
6.008
4.718
2.049
1.994
4.492
1.613
0.071
0.680
0.573
0.871
0.464
0.920
4.277
4.341
3.360
0.969
4.063
5.932
4.607
1.884
1.804
4.476
1. 448
0.062
0.704
0.551
0.788
0.462
10.2 100
5.7 103
7.4 105
12.7 92
3.1 108
3.4 105
1. 3 105
2.4 103
8.1 101
9.5 100
0.4 106
10.2 98
12.7 93
-3.5 109
3.8 102
9.5 97
0.4 107
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.01
t, --_ -------___ --___ -___ -__ --__ --__ --_ ---_ -_ -_ ~ -~ _ 5-l LL ~ 3 -----------
C(#) = Out of Range
0RDC603.D V067D26.M
-,'.,..
SPcc's out = 0 CCC's out = 0
Thu Apr 27 08:37:32 2023 Page 3
REPORT ID: 23E120 Page 187 of 560
Quantitation Report (QT Reviewed)
tData File D:\HPCHEM\1\DATA\23D26\RDC603.D
'Acq On 26 Apr 2023 3:39 pm
i~':Sample IV067D2601
Vial: 17
Operator: VLu
Inst 67
:YMisc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
~MS Integration Params: RTE.P
, Quant Time: Apr 26 16: 09 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
~Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) l,4-DIFLUOROBENZENE
,. 55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
lSystem Monitoring Compounds
•• ~ 36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
lTarget Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
. 12) l,l,2-Trichloro-1,2,2-trif
, 13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
33) Bromochloromethane
10.14 114
15.60 117
19.49 152
8.18
9.29
12.97
17.60
1. 86
2.12
2.24
2.68
2.70
2.80
2.96
3.57
3.59
3.76
3.90
4.23
4.28
4.50
4.51
4.75
4.79
5.02
5.68
5.87
5.93
6.62
6.89
7.20
7.30 /'
7.68
8.05
111
65
98
95
85
50
62
94
64
67
101
151
43
(' 61
59
142
43
76
49
53
73
/ 96
45
t' 63
43
59
72
77
96
83
130
2362609
1712570
534462
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
591137 10.50
Recovery
431239 10.03
Recovery =
2547480 10.70
Recovery
744145 10.31
Recovery
602546
1047257
1061415
621052
771458
1491252
836620
483393
421380
1174074
563773
1146131
275356
2798378
954677
568595
1040725
840464
2552049
1401840
839174
1626697
142000
903274
783244
1114949
308840
8.36
8.36
9.57
9.08
10.61
10.85
10.31
9.14
44.47
9.05
216.58
10.10
8.94
10.35
8.70
45.74
9.22
9.40
9.78
9.68
10.14
9.09
45.05
9.56
9.23
9.53
8.97
ug/l -0.01
105.00%
ug/l 0.00
100.30%
ug/l 0.00
107.00%
ug/l 0.00
103.10%
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
99
99
100
99
98
99
100
100
98
98
100
100
99
100
100
99
100
99
100
100
98
100
98
99
99
99
99
(#) = qualifier out of range (m) = manual integration~~
RDC603.D V067D26.M Thu Apr 27 08:37:39 2023 ~ 5(\{b3 Page 1
REPORT ID: 23E120 Page 188 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Acq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 16:09 2023 Quant Results File: V067D26.RES
. Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
I...ast Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
34) Tetrahydrofuran
35) tert-Amyl alcohol
37) Cyclohexane
38) 1,l,l-Trichloroethane
39) 2,2,4-Trimethylpentane
40) 1,1-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
~ 45) 1,2-Dichloroethane
1 46) Trichloroethene
I 47) Methylcyclohexane
R 48) 1,2-Dichloropropane
L 49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) 1,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) l-Chlorohexane
67) Chlorobenzene
68) 1,1,1,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.14 42
8.15 59
8.56 84
8.57 97
8.73 57
8.92 110
9.10 119
9.23 87
9.46 78
/ 9.48 62
-' 10.72 130
10.81 83
1l. 09 63
1l.53 c 83
1l. 60 88
1l. 60 93
12.24 43
12.56 .. -75
13.10 91
13.48 75
13.53 ( 69
13.75 97
13.80 43
14.18 76
14.24 164
14.61 129
14.94 " 107
15.28/ 91
15.66 112
15.75 r 131
15.76" 91
15.89 I 91
16.62 I 91
16.70/104
17.24 /105
17. 24 ~ 73
17.50 83
17.72 110
17.82 53
17.82 ~ 91
17.87 156
95373
96904
1352848
952763
3756893
381740
765503
259776
3032099
517837
748188
1537065
677918
713603
48008
250739
1696055
964227
2904335
668253
463423
325542
1013935
645730
578274
363699
285612
1261704
1629224
473934
3275548
4920075
2320095
1756894
2862494
171323
321780
83296
105347
3769938
491529
9.33 ug/l
46.91 ug/l
10.25 ug/l
9.75 ug/l
10.79 ug/l
9.44 ug/l
9.69 ug/l
9.32 ug/l
9.61 ug/l
9.34 ug/l
9.60 ug/l
10.45 ug/l
9.53 ug/l
9.27 ug/l
173.82 ug/l
8.78 ug/l
48.81 ug/l
9.62 ug/l
9.54 ug/l
9.73 ug/l
9.32 ug/l
9.00 ug/l
47.55 ug/l
9.06 ug/l
9.57 ug/l
9.06 ug/l
8.88 ug/l
9.69 ug/l
9.38 ug/l
9.30 ug/l
9.56 ug/l
19.85 ug/l
9.93 ug/l
9.81 ug/l
9.37 ug/l
9.04 ug/l
8.78 ug/l
8.45 ug/l
10.27 ug/l
9.70 ug/l
8.98 ug/l
Qvalue
97
100
100
100
100
99
100
98
100
100
100
100
99
99
100
99
98
99
100
99
99
99
100
98
99
98
99
99
100
99
100
99
100
100
100
98
100
99
100
100
100
. (#) = qualifier out of range (m) = manual integration ~ ~
RDC603.D V067D26.M Thu Apr 2708:37:392023 5 {\I 1-3 Page 2
REPORT ID: 23E120 Page 189 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Aeq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 17
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: Apr 26 16:09 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) l,3,5-Trimethylbenzene 18.03 c 105 2286111 9.43 ug/l
83) 2-Chlorotoluene 18.04 , 91 2320026 9.26 ug/l r 84) 4-Chlorotoluene 18.11 91 1795993 8.73 ug/l
> 85) tert-Butylbenzene 18.48 !. 134 517870 9.69 ug/l 1-'
~. 86) 1, 2, 4-Trimethylbenzene 18.52,.105 2171469 9.66 ug/l
1\' 87) see-Butylbenzene 18.73" 105 3170170 9.87 ug/l
;\,' 88) p-Isopropyltoluene 18.89,119 2462340 9.76 ug/l
89) l,3-Diehlorobenzene 19.01 I 146 1006744 9.19 ug/l
90 ) l,4-Dichlorobenzene 19.12,146 964079 9.05 ug/l
91) n-Butylbenzene 19.34 91 2392370 9.96 ug/l
92) l,2-Diehlorobenzene 19.52 I 146 773778 8.97 ug/l
93) l,2-Dibromo-3-ehloropropan 20.31 157 32882 8.73 ug/l
94) 1, 2, 4-Triehlorobenzene 21.15 I 180 376327 10.35 ug/l
95) Hexachlorobutadiene 21.29 225 294610 9.63 ug/l
96) Naphthalene 21.43 128 421247 9.05 ug/l
97) 1,2,3-Triehlorobenzene 21.69~ 180 247062 9.96 ug/l
Qvalue
100
94
94
97
100
100
100
99
100
100
100
97
99
99
99
99
cV-'------------------------------------~------------~------~---------------
. (#) = qualifier out of range (m) = manual integration
RDC603.D V067D26.M Thu Apr 27 08:37:40 2023 51\i~~ Page 3
REPORT ID: 23E120 Page 190 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23D26\RDC603.D
Aeq On 26 Apr 2023 3:39 pm
Sample IV067D2601
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: Apr 26 16:09 2023
TBA
Vial: 17
Operator: VLu
Inst 67
Multiplr: 1. 00
Quant Results File: V067D26.RES
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Initial Calibration
Abundance
I
TIC: RDC503.D
7500000
1
!
7000000)
!
l
650000011
6000000 11
[rime--> 2. 0 3.00 4.00 5. 0 6.00 7.00 10~00 11:00 12.00 13:00 14.0015:0016~00 17.00 18:00 19:00 20:00 21.00
RDC603.D V067D26.M Thu Apr 27 08,37,42 2023 ? S'\\\1-?:' Page 4
REPORT ID: 23E120 Page 191 of 560
DAILY CALIBRATIONS
REPORT ID: 23E120 Page 192 of 560
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratories, Inc.
Lab Code : EMAX
Lab File 10: REC379
Instrument 10: 67
Project : TEAD-S
SDG No : 23E120
BFB Injection Date: 05/17/23
BFB Injection Time: 06:34
I I I % RELATIVE I
I mle I ION ABUNDANCE CRITERIA I ABUNDANCE I
1=1 I I
I 50 I 15 -40% of mass 95 I 20.388 I
I 75 I 30 -60% of mass 95 I 46.135 I
I 95 I Base Peak, 100% relative abundance __ 1 100.000 I
I 96 I 5 . 9% of mass 95 I 6.664 I
I 173 I Less than 2% of mass 174 I 0.000(0)1 I
I 174 I Greater than 50% of mass 95 I 73.009 I
I 175 I 5 -9% of mass 174 I 5.163(7.07)1 I
I 176 I 95 . 101% % of mass 174 I 70.715(96.86)1 I
I 177 I 5 . 9% % of mass 176 I 4.335(6.13)2 I
I_I I I
I-Value is % mass 174 2-Value is % mass 176
This check applies to the following samples, Lab QCs and Standards:
I EPA I LAB I LAB I DATE I TIME I
I SAMPLE NO. I SAMPLE 10 I FILE 10 I ANALYZED I ANALYZED I
1======1====1===1 1===
11VSTD10 ICV067D2616 IREC380 I 05/17/23 I 07:08
21 LCS1W IV067E17L IREC381 I 05117/23 I 07:33
31 LCD1W IV067E17C IREC382 I 05117123 I 07:59
41MBLK1W IV067E17B IREC384 I 05/17/23 I 08:50
51 TB -20230509 ·1/25 I 23E120 ·12 I REC390 I 05/17/23 I 11 : 24
6IS-121·08-052023 I 23E120·02 IREC391 I 05/17/23 I 11:49
7IS-120·08·052023 I 23E120-01 IREC392 I 05/17/23 I 12:15
81 S·127-15· 052023 I 23E120-03 IREC393 I 05/17/23 I 12:41
9IS·128-15-052023 I 23E120-04 IREC394 I 05/17/23 I 13:06
10IS-135·16-05-2023D I 23E120·05 IREC395 I 05/17/23 I 13:32
11IS-135·16·052023 I 23E120-06 IREC396 I 05/17/23 I 13:58
12 I S·136-16-052023 I 23E120-07 IREC397 I 05117/23 I 14:23
13IS-139-17-05-2023D I 23E120·08 IREC398 I 05/17/23 I 14:49
14IS-139-17·052023 I 23E120-09 IREC399 I 05/17/23 I 15:15
15IS·121-08-052023MS I 23E120-02M IREC402 I 05/17/23 I 16:32
16 I S-121-08-052023MSD I 23E120·02S IREC403 I 05/17/23 I 16:58
171VSTD10 I EV067D2616 IREC404 I 05/17/23 I 17:23
I I I I 1 __ _
REPORT ID: 23E120 Page 193 of 560
FORM 8
VOLATILE INTERNAL STANDARD MEA AND RETENTION TIME SUMMAAY
Lab Name: EMAX Laboratories, Inc.
Lab Code: EMAX
Lab File ID: RDC593
Instrument ID: 67
Project: TEAD-S
SDG No: 23E120
Date Analyzed: 04/26/23
Time Analyzed: 10:54
I INTERNAL STANDARD (IS) l,4-DIFLUOROBENZENE I CHLOR08ENZENE-D5 I l,2-DICHLOROBENZENE-D4 I
I Area #1 RT#I Area #1 RT#I Area #1 RT#I
I I I I I I I
I 12 HOUR STD 2183075 I 10.14 I 1594928 I 15.60 I 498004 I 19.49 I
I UPPER LIMIT 4366150 I 10.31 I 3189856 I 15. 77 I 996008 I 19.66 I
I LOWER LIMIT 1091538 I 9.973 I 797464 I 15.43 I 249002 I 19.32 I
1======= =====1====1====1====1====1====1
I Area #1 RT#I Area #1 RT#I Area #1 RT#I
I I I I I I I
11VSTD10 2348490 I 10.15 I 1695793 I 15.60 I 530607 I 19.49 I
21 LCS1W 2239216 I 10.15 I 1612846 I 15.60 I 508177 I 19.49 I
31 LCD1W 2184518 10.15 I 1599354 I 15.60 I 497934 I 19.49 I
41MBLK1W 2273441 10.15 I 1592561 I 15.60 I 416893 I 19.49 I
51 TB-20230509 -1/25 2179707 10. 15 I 1525349 I 15.60 I 406102 I 19.49 I
6IS-121-08-052023 2247666 10.15 I 1619845 15.60 I 444549 I 19.49 I
7IS-120-08-052023 2202235 10.15 I 1591171 15.60 I 441560 I 19.49 I
81 S -127 -15 -052023 2220549 10.15 I 1582083 15.60 I 431203 I 19.50 I
9IS-128-15-052023 2147899 10.15 I 1518659 15.60 I 409762 I 19.50 I
10IS-135-16-05-2023D 2156555 10.15 I 1534996 15.60 I 414548 I 19.50 I
11 I S-135-16-052023 2188184 10.15 I 1556215 15.60 I 421617 I 19.50 I
12 I S-136-16-052023 2148055 10.15 I 1541581 15.60 I 420226 I 19.50 I
13IS-139-17-05-2023D 1991449 10.18 I 1582960 15.62 I 468657 I 19.50 I
14IS-139-17-052023 1890818 10.18 I 1497413 15.62 I 450628 I 19.50 I
15 I S-121-08-052023MS 2009830 I 10.17 I 1529105 15.62 I 504924 I 19.50 I
16IS-121-08-052023MSD 1931294 I 10.17 I 1475561 15.62 I 505645 I 19.50 I
17IVSTD10 2151225 I 10.17 I 1564211 15.62 I 498006 I 19.50 I
I I I I I I
Area Upper Limit = +100% of ICAL Midpoint IS Area
Area Lower Limit = -50% of ICAL Midpoint IS Area
Retention Time(RT) Upper Limit = +10 seconds of ICAL Midpoint IS RT
Retention Time(RT) Lower Limit = -10 seconds of ICAL Midpoint IS RT
REPORT ID: 23E120 Page 194 of 560
BFB
Data File D:\HPCHEM\1\DATA\23E17\REC379.D Vial: 1
Acq On 17 May 2023 6:34 am Operator: VLu
Sample BFB67E17 Inst 67
Misc T/CHK Multiplr: 1.00
MS Integration Params: RTE.P
Method D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
Title : METHOD 8260B
~bu~~
I I
I 50000)
i I I I
!
400001
30000;
20000j
I
Abundance Average of 17.605 to 17.634 min.: REC379.D (-)
45000:
40000 1
350001
I
30000i
!
25000j
20000i
150001
10000,
5000:
95
75
50
68
174
, 39 45 56 61 141
h,/z--> 0 ~'O ~io_]'5+ ~b '''55++: !TT6tTci++! 6TT5~70~' +J-l-t+rtt-~-+h-rct+!-f+,cCTTnTTTT5TT1TTO~1"1~5'1;20 125130 1'35140 1451'50155160 1651701'75180185
AutoFind: Scans 1041, 1042, 1043i Background Corrected with Scan 1036
I
Target I ReI. to I Lower
Mass Mass Limit% I
Upper I
Limit%
ReI.
Abn%
Raw
Abn I
Result I
Pass/Fail
----------------------------------------------------------------------
50 95 15 40 / 20.4 / 9699 PASS
75 95 30 60 46.1 J 21947 PASS
95 95 100 100 100.0 47571 PASS
96 95 5 9 6.7 3170 PASS
173 174 0.00 2 0.0/ 0 PASS
174 95 50 100 73.0 34731 PASS
175 174 5 9 7.1 2456 PASS
176 174 95 101 96.9/ 33640 PASS
177 176 5 9 6.1 2062 PASS
REC379.D V067D26.M Thu May 18 08:22:22 2023
REPORT ID: 23E120 Page 195 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E17\REC380.D
Acq On 17 May 2023 7:08 am
Sample CV067D2616
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
,_ I 1,4 -DIFLUOROBENZENE
-T,M Dichlorodifluoromethane
~ T,M Dichlorotetrafluoroethane
: P,T,M Chloromethane
:) C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
i2 T,M 1,1,2-Trichloro-1,2,2-trifl
:.3 T,M Acetone
~4 C,T,M 1,1-Dichloroethene
~~ T,M tert-Butyl alcohol
n T,M Iodomethane
.~ T,M Methyl acetate
T,M Acetonitrile
"~T,M Carbon disulfide
~~. n T,M Methylene chloride
?? T,M Acrylonitrile
::;;~ T, M tert -Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
~5 P,T,M 1,1-Dichloroethane
~6 T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
~9 T,M 2-Butanone
10 T,M 2,2-Dichloropropane
11 T,M cis-1,2-Dichloroethene
?~ C,T,M Chloroform
~~ T,M Bromochloromethane
,~J;:; T,M Tetrahydrofuran
.-.: T,M tert-Amyl alcohol
~ S Dibromofluoromethane
~7 T,M Cyclohexane
j0 T,M 1,1,1-Trichloroethane
~~ T,M 2,2,4-Trimethylpentane
~0 T,M 1,1-Dichloropropene
;" iT, M Carbon tetrachloride
Amount Calc.
10.000 10.000
10.000 9.738
-1.000 0.000
10.000 8.684
10.000 9.949
10.000 10.853
10.000 10.980
10.000 10.763
10.000 11.016
-1.000 0.000
50.000 43.031
10.000 10.577
50.000 56.633
10.000 10.323
250.000 238.480
10.000 10.600
10.000 10.690
-1.000 0.000
10.000 11.631
10.000 9.832
50.000 50.286
10.000 10.997
10.000 10.486
10.000 10.835
10.000 10.624
10.000 10.826
-1. 000 0.000
10.000 10.593
50.000 51.481
10.000 11.582
10.000 10.815
10.000 10.991
10.000 10.754
10.000 9.912
50.000 0.000
10.000 11.220
10.000 10.810
10.000 10.805
10.000 0.000
10.000 9.731
10.000 10.672
%Dev Area% Dev(min)
0.0
2.6
0.0
13.2
~ 0.5
-8.5
-9.8
-7.6
-10.2
0.0
13.9
-5.8
-13.3
-3.2
./ 4.6
-6.0
-6.9
0.0
-16.3
1.7
-0.6
-10.0
-4.9
-8.4
-6.2
-8.3
0.0
-5.9
-3.0
-15.8
-8.1
/
-9.9
-7.5
0.9
100.0#
-12.2
-8.1
-8.0
100.0#
2.7
-6.7
108
98
o
87
95
105
106
116
107
o
88
115
125
112
103
111
105
o
111
113
106
118
114
117
116
106
o
117
108
127
117
120
115
105
o
114
106
117
o
106
114
0.01
0.02
0.00
0.05
0.02
-0.02
0.00
0.00
0.02
0.00
0.03
0.02
0.02
0.02
0.02
0.01
0.01
0.01
0.03
0.03
0.03
0.01
0.01
0.01
0.03
0.01
0.01
0.00
0.01
0.03
0.01
0.01
0.01
0.02
-8.16#
0.01
0.01
0.01
-8.73#
0.01
0.01
~-------------------------------------------------------------------------
~(#) = Out of Range
~REC380.D V067D26.M Thu May 18 08:23:38 2023 Page 1
REPORT ID: 23E120 Page 196 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E17\REC380.D
Acq On 17 May 2023 7:08 am
,;:;:, Sample CV067D2616
3,3 Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
j4 MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method .; r-)"
" Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
;ot~ Last Update
;~ ,;j Response via
,.n Min. RRF
Max. RRF Dev
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
42 T,M tert-Amyl methyl ether (TAM
13 S l,2-Dichloroethane-d4
'; 4 T, M Benzene
~5 T,M l,2-Dichloroethane
~§ T,M Trichloroethene
~7 T,M Methylcyclohexane
4@ C,T,M l,2-Dichloropropane
~g T,M Bromodichloromethane
SQ T,M l,4-Dioxane
~,;~ T, M Dibromomethane
S~ T,M 2-Chloroethyl vinyl ether
j,;) T,M 4-Methyl-2-pentanone
S~ T,M cis-1,3-Dichloropropene
SS I CHLOROBENZENE-D5
~6 S Toluene-d8
57 C,T,M Toluene
S8 T,M trans-1,3-Dichloropropene
59 T,M Ethyl methacrylate
10 T,M l,l,2-Trichloroethane
11 T,M 2-Hexanone
~2 T,M l,3-Dichloropropane
~~ T,M Tetrachloroethene
iH T, M Dibromochloromethane
~~ T,M l,2-Dibromoethane
~~ T,M 1-Chlorohexane
~~ P,M Chlorobenzene
~8 T,M l,l,l,2-Tetrachloroethane
;H3 C, T, M Ethylbenzene
1~ T,M m-Xylene & p-Xylene
~~ T,M o-Xylene
7:2 T,M Styrene
~3 T,M Isopropylbenzene
74 I l,2-DICHLOROBENZENE-D4
75 P,T,M Bromoform
76 P,T,M l,l,2,2-Tetrachloroethane
07 S 4-Bromofluorobenzene
~8 T,M 1,2,3-Trichloropropane
19 T,M trans-1,4-Dichloro-2-butene
RA T,M n-Propylbenzene
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.607
10.656
10.608
10.390
10.078
10.744
10.504
10.874
198.402
10.467
1.804
48.162
10.652
10.000
10.809
10.763
10.864
9.199
11.239
49.757
10.979
10.684
10.729
10.704
10.478
10.616
11.511
10.696
21.753
11.165
9.793
11.138
10.000
10.147
10.886
10.179
10.510
10.314
10.768
/
-6.1
-6.6
-6.1
-3.9
-0.8
-7.4
-5.0
-8.7
0.8
-4.7
82.0#
3.7
-6.5
0.0
-8.1
-7.6
-8.6
8.0
-12.4
0.5
-9.8
-6.8
-7.3
-7.0
-4.8
-6.2
-15.1
-7.0
-8.8
-11.6
2.1
-11.4
0.0
-1. 5
-8.9
-1. 8
-5.1
-3.1
-7.7
111
109
115
111
109
105
114
117
106
113
20
100
114
106
109
115
113
98
120
102
117
115
112
112
111
114
124
114
114
118
103
117
107
109
116
106
109
110
116
0.03
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.02
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.01
~~------------------------------------------------------------------------
'~'l#) = Out of Range
,;u~'EC380.D V067D26.M Thu May 18 08:23:38 2023 Page 2
REPORT ID: 23E120 Page 197 of 560
Evaluate Continuing Calibration Report
;.;,) .....
F -S:1
eft Data File D: \HPCHEM\l \ DATA \23E17\REC380. D
7". Acq On 17 May 2023 7:08 am
or,; Sample CV067D2616
Vial: 2
Operator: VLu
Inst 67
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
.~! Title
':), Last Update
oft 1 Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
r-::~ \:~
~f'~ Min. RRF
2, ;~ Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M Bromobenzene 10.000 10.607 -6.1
T,M 1, 3 , 5-Trimethylbenzene 10.000 10.562 -5.6
T,M 2-Chlorotoluene 10.000 10.071 -0.7
T,M 4-Chlorotoluene 10.000 10.091 -0.9
T,M tert-Butylbenzene 10.000 11.213 -12.1
T,M 1, 2, 4-Trimethylbenzene 10.000 10.801 -8.0
T,M sec-Butylbenzene 10.000 11.156 -11.6
T,M p-Isopropyltoluene 10.000 10.824 -8.2
T,M 1 /3-Dichlorobenzene 10.000 10.430 -4.3
T,M 1 /4-Dichlorobenzene 10.000 10.268 -2.7
T,M n-Butylbenzene 10.000 10.486 -4.9
T,M 1 /2-Dichlorobenzene 10.000 10.416 -4.2
T,M 1 /2-Dibromo-3-chloropropane 10.000 10.779 -7.8
:/ ~!: T,M 1 /2 /4-Trichlorobenzene 10.000 10.981 -9.8
T,M Hexachlorobutadiene 10.000 11.282 -12.8
T,M Naphthalene 10.000 9.312 6.9
T,M 1, 2, 3-Trichlorobenzene 10.000 10.561 -5.6
~ (#) = Out of Range
REC380.D V067D26.M
SPCC's out = 0 CCC's out = 0
Thu May 18 08:23:39 2023
117 0.00
114 0.01
114 0.01
106 0.00
124 0.00
116 0.00
118 0.01
114 0.01
113 0.01
112 0.00
110 0.00
113 0.00
114 0.01
115 0.01
119 0.00
99 0.01
113 0.01
Page 3
REPORT ID: 23E120 Page 198 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E17\REC380.D
Acq On 17 May 2023 7:08 am
::" Sample CV067D2616
"7 -:;
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
.;""
TBA
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
~3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
.: r~ C,T,M Vinyl chloride
() T,M Bromomethane
-7 T,M Chloroethane
8 T,M Dichlorofluoromethane
S T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-l,2,2-trifl
.:. '3 T, M Acetone
!4 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
2~ T,M trans-1,2-Dichloroethene
~1 T,M Isopropyl ether (DIPE)
~s P,T,M l,l-Dichloroethane
?~ T,M Vinyl acetate
::'~"j! T,M 2-Butanol
10 T,M tert-Butyl ethyl ether (ETB
}~ T,M 2-Butanone
~~ T,M 2,2-Dichloropropane
~i T,M cis-1,2-Dichloroethene
;2 C,T,M Chloroform
23 T,M Bromochloromethane
14 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
16 S Dibromofluoromethane
~7 T,M Cyclohexane
~g T,M 1, 1, 1-Trichloroethane
2) T,M 2,2,4-Trimethylpentane
2~ T,M l,l-Dichloropropene
~~ T,M Carbon tetrachloride
AvgRF CCRF
1. 000 1. 000
0.305 0.297
0.000 0.000
0.530 r 0.460
0.470 0.467
0.290 0.314
0.308 0.338
0.582 0.626
0.343 0.378
0.000 0.000
0.023 0.020
0.224 0.237
0.04p 0.045
0.549 0.567
0.011 0.011
0.480 0.509
0.130 0.139
0.000 0.000
1.144 1.331
0.465 0.457
0.053 0.053
0.478 0.525
0.378 0.397
1.105 1.197
0.613 /0.651
0.350 0.379
0.000 0.000
0.757 0.802
0.013 0.014
0.400 0.463
0.359 0.388
0.495 0.544
0.146 0.157
0.043 0.043
0.009 0.000
0.238 0.267
0.559 0.604
0.414 0.447
1.474 0.000
0.171 0.167
0.334 0.357
%Dev Area% Dev(min)
0.0
2.6
0.0
13.2
0.6
-8.3
-9.7
-7.6
-10.2
0.0
13.0
-5.8
-12.5
-3.3
0.0
-6.0
-6.9
0.0
-16.3
1.7
0.0
-9.8
-5.0
-8.3
-6.2
-8.3
0.0
-5.9
-7.7
-15.8
-8.1
-9.9
-7.5
0.0
100.0#
-12.2
-8.1
-8.0
100.0#
2.3
-6.9
108
98
0#
87
95
105
106
116
107
0#
88
115
125
112
103
111
105
0#
111
113
106
118
114
117
116
106
0#
117
108
127
117
120
115
105
0#
114
106
117
0#
106
114
0.01
0.02
0.00
0.05
0.02
-0.02
0.00
0.00
0.02
0.00
0.03
0.02
0.02
0.02
0.02
0.01
0.01
0.01
0.03
0.03
0.03
0.01
0.01
0.01
0.03
0.01
0.01
0.00
0.01
0.03
0.01
0.01
0.01
0.02
-8.16#
0.01
0.01
0.01
-8.73#
0.01
0.01
~4---------------------------------------------------------------------
:i '~#) = Out of Range
:?,f,lEC380.D V067D26.M Thu May 18 08:23:42 2023 Page 1
REPORT ID: 23E120 Page 199 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E17\REC380.D
~l Acq On 17 May 2023 7:08 am
Sample CV067D2616
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial: 2
Operator: VLu
67
1. 00
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
;;, Last Update
0, ,; Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
-.i(
,~' ,; Min. RRF 0.000 Min. ReI. Area
""~ ~-'-20% Max. ReI. Area
, '1
'\ Compound
<2 T,M tert-Amyl methyl ether (TAM
,~S l,2-Dichloroethane-d4
.'~, ~:~ T,M Benzene
~~ T,M l,2-Dichloroethane
16 T,M Trichloroethene
4~ T,M Methylcyclohexane
48 C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
SO T,M l,4-Dioxane
;~1 T, M Dibromomethane
'~;2 T, M 2 -Chloroethyl vinyl ether
\~3 T,M 4-Methyl-2-pentanone
j~ T,M cis-1,3-Dichloropropene
:~~,~;. I CHLOROBENZENE-D5
5~ S Toluene-d8
::;:j C, T, M Toluene
SS T,M trans-1,3-Dichloropropene
~h T,M Ethyl methacrylate
~0 T,M l,l,2-Trichloroethane
0t T,M 2-Hexanone
~2 T,M l,3-Dichloropropane
';3 T,M Tetrachloroethene
:\ 4 T, M Dibromochloromethane
~5 T,M l,2-Dibromoethane
56 T,M 1-Chlorohexane
57 P,M Chlorobenzene
~8 T,M l,l,l,2-Tetrachloroethane
G9 C,T,M Ethylbenzene
~O T,M m-Xylene & p-Xylene
71 T,M o-Xylene
'}2 T, M Styrene
7~ T,M Isopropylbenzene
,,' I 1,2 -DICHLOROBENZENE-D4
-'" P, T, M Bromoform
1~ P,T,M l,l,2,2-Tetrachloroethane
80 S 4-Bromofluorobenzene
~~ T,M 1, 2, 3-Trichloropropane
~~ T,M trans-1,4-Dichloro-2-butene
00 T,M n-Propylbenzene
AvgRF
0.118
0.182
1.335
0.235
0.330
0.622
0.301
0.326
0.001
0.121
0.054
0.147
0.424
1.000
1.390
1.778
0.401
0.290
0.211
0.125
0.416
0.353
0.234
0.188
0.761
1.014
0.298
2.000
1.447
1.364
1.046
1.783
1.000
0.355
0.686
1.351
0.184
0.192
7.269
50% Max. R.T. Dev 0.16min
200%
CCRF
0.125
0.194
1.416
0.244
0.333
0.669
0.316
0.354
0.001
0.126
0.010
0.142
0.452
1.000
1.503
1.914
0.436
0.267
0.237
0.124
0.457
0.377
0.251
0.201
0.797
1.077
/0.343
2.139
1.574
1.523
1.024
1.986
;.000
. 0.360
/0.747
1.375
0.194
0.198
7.827
%Dev Area% Dev(min)
-5.9
-6.6
-6.1
-3.8
-0.9
-7.6
-5.0
-8.6
0.0
-4.1
81.5#
3.4
-6.6
0.0
-8.1
-7.6
-8.7
7.9
-12.3
0.8
-9.9
-6.8
-7.3
-6.9
-4.7
-6.2
-15.1
-6.9
-8.8
-11.7
2.1
-11.4
0.0
-1. 4
-8.9
-1. 8
-5.4
-3.1
-7.7
111
109
115
111
109
105
114
117
106
113
20#
100
114
106
109
115
113
98
120
102
117
115
112
112
III
114
124
114
114
118
103
117
107
109
116
106
109
110
116
0.03
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.02
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.01
:~-------------------------------------------------------------------------
C(#) = Out of Range
"REC380.D V067D26.M Thu May 18 08:23:44 2023 Page 2
REPORT ID: 23E120 Page 200 of 560
Evaluate Continuing Calibration Report
~ry
7~ Data File D:\HPCHEM\1\DATA\23E17\REC380.D
~3 Aeq On 17 May 2023 7:08 am
Sample CV067D2616
Vial: 2
Operator: VLu
Inst 67 Ji Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
'~q
Method "7 .~~ Title ,~.~ (~
ijC:; Last Update
q; .::;, Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
\j~ ~
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
8 1 T ,
:~: 2 T ,
n 3 T \,~ ,
;. f~ 4 T ,
'C~ .~) T ,
-() ~ T ,
~ 7 T ,
r~ .) T \:} ,
r~ ,~; T ~ I
c~ , .-~ T , ~:! ,
:'";, '}; T ~,~ ;~ ,
i~ ~~ T ,
\~ 3 T ,
4 T ,
,)5 T ,
'~~:' 6 T ,
9 7 T ,
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1, 2, 4-Trimethylbenzene
see-Butylbenzene
p-Isopropyltoluene
l,3-Diehlorobenzene
l,4-Diehlorobenzene
n-Butylbenzene
l,2-Diehlorobenzene
l,2-Dibromo-3-ehloropropane
1, 2, 4-Triehlorobenzene
Hexaehlorobutadiene
Naphthalene
l,2,3-Triehlorobenzene
1.024
4.534
4.686
3.849
1.000
4.206
6.008
4.718
2.049
1.994
4.492
1.613
0.071
0.680
0.573
0.871
0.464
1.086
4.789
4.719
3.884
1.121
4.543
6.702
5.107
2.137
2.047
4.711
1.681
0.076
0.747
0.646
0.811
0.490
-6.1
-5.6
-0.7
-0.9
-12.1
-8.0
-11.6
-8.2
-4.3
-2.7
-4.9
-4.2
-7.0
-9.9
-12.7
6.9
-5.6
117 0.00
114 0.01
114 0.01
106 0.00
124 0.00
116 0.00
118 0.01
114 0.01
113 0.01
112 0.00
110 0.00
113 0.00
114 0.01
115 0.01
119 0.00
99 0.01
113 0.01
~~------------------------------------------------------------------------
?#) = Out of Range
i;'mC380.D V067D26.M
SPCC's out = 0 CCC's out = 0
Thu May 18 08:23:45 2023 Page 3
REPORT ID: 23E120 Page 201 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC380.D
Acq On 17 May 2023 7:08 am
Sample CV067D2616
Vial: 2
Operator: VLu
Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:22 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
/System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) l,2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
. Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.15 114
15.60 117
19.49 152
8.21
9.30
12.97
17.60
1. 88
2.16
2.26
2.66
2.70
2.78
2.98
3.53
3.59
3.59
3.78
3.92
4.23
4.29
4.53
4.54
4.77
4.80
5.04
5.71
5.90
5.94
6.63
6.92
7.23
7.32
7.70
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
2348490 ;
1695793/
530607
627989
Recovery
10.00 ug/l
10.00 ug/l
10.00 ug/l
11.22
455437 10.66
ug/l
112.20%
ug/l
106.60%
ug/l
108.10%
ug/l
101. 80%
Recovery
2548644 10.81
Recovery
729496 10.18
Recovery
0.01
0.00
0.00
0.01
0.01
0.00
0.00
698038
1080843
1097178
738075
793390
9.74 ug/l
8.68 ug/l
9.95 ug/l
10.85 ug/l
10.98 ug/l
10.76 ug/l
11.02 ug/l
43.03 ug/l
10.58 ug/l
56.63 ug/l
10.32 ug/l
Qvalue
99
94
100
100
98
1470705
888241
236686
555996
533424
1330891
617066
1195905
327304
3125660
1072827
621328
1233739
931883
2811858
1529156
890944
1884282
161284
1087896
911940
1278152
238.48 ug/l
10.60 ug/l
10.69 ug/l
11.63 ug/l
9.83 ug/l
50.29 ug/l
11.00 ug/l
10.49 ug/l
10.84 ug/l
10.62 ug/l
10.83 ug/l
10.59 ug/l
51.48 ug/l
11.58 ug/l
10.81 ug/l
10.99 ug/l
100
99
100
100
98
99
99
99
99
100
100
98
99
99
100
99
99
100
89
99
100
100
(#) = qualifier out of range (m) = manual integration
REC380.D V067D26.M Thu May 18 08:22:36 2023 Page 1
REPORT ID: 23E120 Page 202 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC380.D
Acq On 17 May 2023 7:08 am
Sample CV067D2616
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:22 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) l,l,l-Trichloroethane
40) l,l-Dichloropropene
~ 41) Carbon tetrachloride
;" 42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
~ 46) Trichloroethene
47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.06
8.15
8.57
8.59
8.94
9.11
9.26
9.48
9.49
10.74
10.82
11.09
11.53
11.61
11.61
12.20
12.24
12.58
13.12
13.50
13.53
13.75
13.80
14.20
14.26
14.61
14.96
15.28
15.67
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
368090
100710
1418004
1049860
391151
837914
293762
3325215
572339
780994
1570227
742625
832253
54471
297048
22941
1663356
1061624
3245705
738734
452711
402615
1050673
774988
639338
426435
340981
1351412
1825846
580856
3627635
5338049
2582773
1736587
3368472
190998
396172
102889
104996
4152963
576373
(#) = qualifier out of range (m) = manual integration
REC380.D V067D26.M Thu May 18 08:22:37 2023
10.75 ug/l
9.91 ug/l
10.81 ug/l
10.80 ug/l
9.73 ug/l
10.67 ug/l
10.61 ug/l
10.61 ug/l
10.39 ug/l
10.08 ug/l
10.74 ug/l
10.50 ug/l
10.87 ug/l
198.40 ug/l
10.47 ug/l
1.80 ug/l
48.16 ug/l
10.65 ug/l
10.76 ug/l
10.86 ug/l
9.20 ug/l
11.24 ug/l
49.76 ug/l
10.98 ug/l
10.68 ug/l
10.73 ug/l
10.70 ug/l
10.48 ug/l
10.62 ug/l
11.51 ug/l
10.70 ug/l
21.75 ug/l
11.16 ug/l
9.79 ug/l
11.14 ug/l
10.15 ug/l
10.89 ug/l
10.51 ug/l
10.31 ug/l
10.77 ug/l
10.61 ug/l
Qvalue
99
97
97
99
99
100
98
100
99
99
98
97
99
100
98
80
97
99
99
88
100
97
99
99
99
100
99
100
99
100
99
100
100
99
100
99
98
99
100
99
99
Page 2
REPORT ID: 23E120 Page 203 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC380.D
Aeq On 17 May 2023 7:08 am
Sample CV067D2616
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:22 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
82) l,3,5-Trimethylbenzene 18.04 105 2541194 10.56 ug/l 100
83) 2-Chlorotoluene 18.06 91 2504139 10.07 ug/l 95
84) 4-Chlorotoluene 18.12 91 2060649 10.09 ug/l 93
.'. 85 ) tert-Butylbenzene 18.48 134 594745 11.21 ug/l 94
86 ) l,2,4-Trimethylbenzene 18.52 105 2410559 10.80 ug/l 99
87) see-Butylbenzene 18.74 105 3556209 11.16 ug/l 100
88) p-Isopropyltoluene 18.90 119 2709900 10.82 ug/l 99
89 ) l,3-Diehlorobenzene 19.01 146 1134098 10.43 ug/l 99
90) l,4-Diehlorobenzene 19.12 146 1086301 10.27 ug/l 99
91) n-Butylbenzene 19.34 91 2499629 10.49 ug/l 99
92) l,2-Diehlorobenzene 19.52 146 891704 10.42 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.31 157 40325 10.78 ug/l 94
-94) l,2,4-Triehlorobenzene 21.17 180 396217 10.98 ug/l 99
95) Hexaehlorobutadiene 21.29 225 342828 11.28 ug/l 98
96) Naphthalene 21.45 128 430253 9.31 ug/l 99
97) 1,2,3-Triehlorobenzene 21.69 180 260114 10.56 ug/l 100
(#) = qualifier out of range (m) = manual integration
REC380.D V067D26.M Thu May 18 08:22:37 2023 Page 3
REPORT ID: 23E120 Page 204 of 560
Data File
Aeq On
Sample
Quantitation Report
D:\HPCHEM\1\DATA\23E17\REC380.D
17 May 2023 7:08 am
CV067D2616
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Vial:
Operator:
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: May 18 8:22 2023 Quant Results File:
Method
Title
Last Update
Response via
AbUndance --~----~-
i 7500000:
7000000:
6500000i'
Ii
1
1,
600000011
I
5500000i
I
r
!
50000001 .
4500000: •
,.
!:
:1
4000000) I
3500000;
30000001:::;
,.:
~ !~ 2500000!~
10 !~ 10
200000011
io
1500000,
1000000'
500000i
o~
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
iIC:REc:mo:u----
Time--> 2.00 3.00 4.00 5.00
REC380.D V067D26.M Thu May 18 08:22:39 2023
2
VLu
67
1. 00
V067D26.RES
Page 4
REPORT ID: 23E120 Page 205 of 560
Evaluate Continuing Calibration Report
8 Data File D:\HPCHEM\1\DATA\23E17\REC404.D
~, Acq On 17 May 2023 5:23 pm
J Sample EV067D2616
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial: 26
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023 ~ Last Update
Response via Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000
20%
Min. ReI. Area
Max. ReI. Area
50%
200%
Max. R.T. Dev 0.16min
, ;
Compound
,L I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
J T,M Dichlorotetrafluoroethane
~ P,T,M Chloromethane
:5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
'8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
~2 T,M l,l,2-Trichloro-1,2,2-trifl
T3 T,M Acetone
14 C,T,M l,l-Dichloroethene
lS T,M tert-Butyl alcohol
L,:; T, M Iodomethane
-L ::' T, M Methyl acetate
~Q T,M Acetonitrile
19 T,M Carbon disulfide
:;,:;J T, M Methylene chloride
2~ T,M Acrylonitrile
',:":; T,M tert-Butyl methyl ether (MT
~3 T,M trans-1,2-Dichloroethene
~4 T,M Isopropyl ether (DIPE)
)5 P,T,M l,l-Dichloroethane
26 T,M Vinyl acetate
27 T,M 2-Butanol
~8 T,M tert-Butyl ethyl ether (ETB
)9 T,M 2-Butanone
~O T,M 2,2-Dichloropropane
il T,M cis-1,2-Dichloroethene
1) C,T,M Chloroform
'~~ T,M Bromochloromethane
';, (: T, M Tetrahydrofuran
-;:t~ T,M tert-Amyl alcohol
~M S Dibromofluoromethane
-t: ~~ T f M Cyclohexane
~0 T,M 1 /1,l-Trichloroethane
,;~ it T, M 2,2,4 -Trimethylpentane
~j T,M l,l-Dichloropropene
:': 1 T, M Carbon tetrachloride
Amount Calc.
10.000 10.000
10.000 9.190
-1.000 0.000
10.000 8.417
10.000 10.023
10.000 10.225
10.000 10.689
10.000 10.465
10.000 10.933
-1.000 0.000
50.000 46.697
10.000 10.619
50.000 53.140
10.000 9.830
250.000 229.722
10.000 9.466
10.000 10.164
-1.000 0.000
10.000 11.579
10.000 9.175
50.000 49.601
10.000 10.168
10.000 9.758
10.000 10.341
10.000 9.985
10.000 9.792
-1.000 0.000
10.000 10.049
50.000 51.983
10.000 10.331
10.000 10.228
10.000 10.445
10.000 10.070
10.000 8.798
50.000 0.000
10.000 10.605
10.000 10.847
10.000 10.244
10.000 0.000
10.000 9.979
10.000 10.230
%Dev Area% Dev(min)
0.0
8.1
0.0
15.8
-0.2
-2.2
-6.9
-4.6
-9.3
0.0
6.6
-6.2
-6.3
1.7
8.1
5.3
-1. 6
0.0
-15.8
8.2
0.8
-1. 7
2.4
-3.4
0.2
2.1
0.0
-0.5
-4.0
-3.3
-2.3
-4.5
-0.7
12.0
100.0#
-6.1
-8.5
-2.4
100.0#
0.2
-2.3
99
85
o
78
87
90
95
103
97
o
87
105
107
98
91
91
92
o
101
97
96
100
97
103
100
88
o
102
100
103
101
105
99
85
o
99
97
101
o
99
100
0.03
0.03
0.00
0.07
0.05
0.00
0.03
0.03
0.03
0.00
0.03
0.02
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.05
0.05
0.04
0.04
0.03
0.04
0.04
0.04
0.03
0.03
0.04
0.04
0.03
0.04
0.03
-8.16#
0.03
0.03
0.03
-8.73#
0.03
0.03
--
~--------------------------------------------------------------------------
;(#) = Out of Range
:. REC4 04. D V067D26 . M Thu May 18 08:23:52 2023 Page 1
REPORT ID: 23E120 Page 206 of 560
Evaluate Continuing Calibration Report
;; i Data File D: \HPCHEM\l \ DATA \23E17\REC404.D
~~ Acq On 17 May 2023 S:~l pm
.-:; .~; ,," Sample EV067D2616
;~; Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
~1 MS Integration Params: RTE.P
~:§
Vial: 26
Operator: VLu
Inst 67
Multiplr: 1. 00
},F; Method
.~"J Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
-, "
,": 8 Last Update
..• ~. i~ Response via
~;q
:~t Min. RRF
Max. RRF Dev
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
42 T,M tert-Amyl methyl ether (TAM
~3 S 1,2-Dichloroethane-d4
All T,M Benzene
~S T,M l,2-Dichloroethane
A6 T,M Trichloroethene
"'": T, M Methylcyclohexane
~B C,T,M l,2-Dichloropropane
!i 1') T, M Bromodichloromethane
~Q T,M l,4-Dioxane
,~;,' T,M Dibromomethane
!~9 T,M 2 -Chloroethyl vinyl ether
;:;':i T,M 4-Methyl-2-pentanone
(ij T,M cis-1,3-Dichloropropene
f:5 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
~9 T,M Ethyl methacrylate
~O T,M l,l,2-Trichloroethane
~1 T,M 2-Hexanone
~~ T,M l,3-Dichloropropane
~~ T,M Tetrachloroethene
'TCf T, M Dibromochloromethane
~~ T,M l,2-Dibromoethane
~~ T,M 1-Chlorohexane
00 P,M Chlorobenzene
~~ T,M 1 /1,l,2-Tetrachloroethane
.:? ';-;. C,T 1M Ethylbenzene
~~ T,M m-Xylene & p-Xylene
~f T,M o-Xylene
'; 2 T, M Styrene
~3 T,M Isopropylbenzene
r::
74 I 1 /2-DICHLOROBENZENE-D4
75 P,T,M Bromoform
~6 P,T,M 1, 1, 2, 2-Tetrachloroethane
17 S 4-Bromofluorobenzene
f8 T,M 1, 2, 3-Trichloropropane
~~ T,M trans-1,4-Dichloro-2-butene
~~ T,M n-Propylbenzene
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.173
10.288
10.198
10.276
10.152
11.108
10.269
10.425
196.511
9.955
3.577
50.163
10.115
10.000
10.767
10.501
10.083
8.853
10.350
51.969
10.229
10.249
10.262
10.055
10.233
10.387
10.545
10.469
20.932
10.690
9.749
10.837
10.000
9.299
9.929
10.160
9.837
8.576
10.276
-1. 7
-2.9
-2.0
-2.8
-1. 5
-11.1
-2.7
-4.3
1.7
0.4
64.2#
-0.3
-1.2
0.0
-7.7
-5.0
-0.8
11. 5
-3.5
-3.9
-2.3
-2.5
-2.6
-0.5
-2.3
-3.9
-5.4
-4.7
-4.7
-6.9
2.5
-8.4
0.0
7.0
0.7
-1. 6
1.6
14.2
-2.8
97
96
102
101
101
99
102
103
96
98
37
96
99
98
100
103
97
87
102
98
100
102
99
97
100
103
104
103
101
104
95
105
100
94
99
100
96
86
104
0.04
0.03
0.03
0.03
0.03
0.02
0.02
0.03
0.02
0.03
0.02
0.02
0.03
0.02
0.02
0.03
0.03
0.03
0.02
0.02
0.02
0.02
0.03
0.02
0.03
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.02
0.02
q1 ____________________________________________________ --------------------
~~#) = Out of Range
~';;f(EC404.D V067D26.M Thu May 18 08:23:52 2023 Page 2
REPORT ID: 23E120 Page 207 of 560
Evaluate Continuing Calibration Report
\. -~-.
':XG Data File D: \HPCHEM\l \ DATA \23E1 7\REC404. D
bc\: ~".
7, Acq On 17 May 2023 5:23 pm
I'.:~
Vial: 26
Operator: VLu
,Sample EV067D2616 Inst 67
':;: Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
Title
Last Update
tj '. Response via
~~ "; ..
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
nfJ Min. RRF
::.;, '1~ Max. RRF Dev
i:? ~,
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
81 T,M Bromobenzene 10.000 10.131 -1.3 105 0.02
~:~ 2 T,M l,3,5-Trimethylbenzene 10.000 10.359 -3.6 105 0.02
tc:, T,M 2-Chlorotoluene 10.000 9.889 1.1 105 0.02
:';;4 T,M 4-Chlorotoluene 10.000 10.505 -5.1 103 0.02
;55 T,M tert-Butylbenzene 10.000 10.580 -5.8 110 0.02
?i 6 T,M l,2,4-Trimethylbenzene 10.000 10.423 -4.2 105 0.02
:37 T,M sec-Butylbenzene 10.000 10.582 -5.8 105 0.02
88 T,M p-Isopropyltoluene 10.000 10.633 -6.3 105 0.02
89 T,M l,3-Dichlorobenzene 10.000 10.393 -3.9 106 0.02
';0 T,M l,4-Dichlorobenzene 10.000 10.325 -3.2 106 0.02
'"~ 1 T,M n-Butylbenzene 10.000 10.427 -4.3 103 0.00 12 T,M l,2-Dichlorobenzene 10.000 10.461 -4.6 106 0.02 u: ~i T,M l,2-Dibromo-3-chloropropane 10.000 9.598 4.0 96 0.02
~) ~~ T,M 1, 2, 4-Trichlorobenzene 10.000 10.935 -9.4 108 0.02 _.' ';';
? ~~ T,M Hexachlorobutadiene 10.000 11.535 -15.4 114 0.02
~~~ r~~ T,M Naphthalene 10.000 9.830 1.7 98 0.02
~.i ry T,M 1, 2, 3-Trichlorobenzene 10.000 11.234 -12.3 112 0.03
'8J
'3 ~;
',i.~ ~:?
.~"
",: !
,.:.
:;'.
;: --------------------------------------------------------------------------
(#) = Out of Range
REC404.D V067D26.M
SPCC's out = 0 CCC's out = 0
Thu May 18 08:23:53 2023 Page 3
REPORT ID: 23E120 Page 208 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E17\REC404.D
Acq On 17 May 2023 5:23 pm
Sample EV067D2616
:;:;:: Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
0~ MS Integration Params: RTE.P
Vial: 26
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
)3 T,M Dichlorotetrafluoroethane
~~ P,T,M Chloromethane
':' C, T, M Vinyl chloride
~b T,M Bromomethane
3~ T,M Chloroethane
)8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
72 T,M 1,1,2-Trichloro-1,2,2-trifl
23 T,M Acetone
~4 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
2'~ T, M tert -Butyl methyl ether (MT
7~ T,M trans-1,2-Dichloroethene
:~ T,M Isopropyl ether (DIPE)
~~ P,T,M 1,1-Dichloroethane
'H T,M Vinyl acetate
:7 T,M 2-Butanol
:>\~ T,M tert-Butyl ethyl ether (ETB
)~ T,M 2-Butanone
20 T,M 2,2-Dichloropropane
~1 T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
-~ 3 T, M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
~,6 S Dibromofluoromethane
': 7 T, M Cyclohexane
~3 T,M 1,1,1-Trichloroethane
~~ T,M 2,2,4-Trimethylpentane
~~ T,M 1,1-Dichloropropene
• h T,M Carbon tetrachloride
AvgRF
1.000
0.305
0.000
0.530
0.470
0.290
0.308
0.582
0.343
0.000
0.023
0.224
0.040
0.549
0.011
0.480
0.130
0.000
1.144
0.465
0.053
0.478
0.378
1.105
0.613
0.350
0.000
0.757
0.013
0.400
0.359
0.495
0.146
0.043
0.009
0.238
0.559
0.414
1.474
0.171
0.334
50% Max. R.T. Dev 0.16min
200%
CCRF
1.000
0.280
0.000
0.446
0.471
0.296
0.329
0.609
0.375
0.000
0.022
0.238
0.043
0.540
0.010
0.455
0.133
0.000
1.325
0.426
0.052
0.486
0.369
1.143
0.612
0.343
0.000
0.761
0.014
0.413
0.367
0.517
0.147
0.038
0.000
0.253
0.606
0.424
0.000
0.171
0.342
%Dev Area% Dev(min)
0.0
8.2
0.0
15.8
-0.2
-2.1
-6.8
-4.6
-9.3
0.0
4.3
-6.2
-7.5
1.6
9.1
5.2
-2.3
0.0
-15.8
8.4
1.9
-1. 7
2.4
-3.4
0.2
2.0
0.0
-0.5
-7.7
-3.2
-2.2
-4.4
-0.7
11. 6
100.0#
-6.3
-8.4
-2.4
100.0#
0.0
-2.4
99
85
0#
78
87
90
95
103
97
0#
87
105
107
98
91
91
92
0#
101
97
96
100
97
103
100
88
0#
102
100
103
101
105
99
85
0#
99
97
101
0#
99
100
0.03
0.03
0.00
0.07
0.05
0.00
0.03
0.03
0.03
0.00
0.03
0.02
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.05
0.05
0.04
0.04
0.03
0.04
0.04
0.04
0.03
0.03
0.04
0.04
0.03
0.04
0.03
-8.16#
0.03
0.03
0.03
-8.73#
0.03
0.03
~~------------------------------------------------------------------------
: '':#) = Out of Range
t;EC404.D V067D26.M Thu May 18 08:23:56 2023 Page 1
REPORT ID: 23E120 Page 209 of 560
Evaluate Continuing Calibration Report
;~~' Data File D:\HPCHEM\1\DATA\23E17\REC404.D
]-Acq On 17 May 2023 5:23 pm
-~< Sample EV067D2616
': Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
A.:~ Response via
,~~, Min. RRF
-£.!_ ,.:.; Max. RRF Dev
Compound
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. Rel. Area
20% Max. Rel. Area
AvgRF
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
;--------------------------------------------------------------------------
'J:~ T,M tert-Amyl methyl ether (TAM
j3 S 1 /2-Dichloroethane-d4
~l?l T,M Benzene
45 T,M 1 /2-Dichloroethane
16 T,M Trichloroethene
47 T,M Methylcyclohexane
18 C/T/M 1 /2-Dichloropropane
~9 T,M Bromodichloromethane
~o T,M 1/4-Dioxane
~1 T,M Dibromomethane
SQ T,M 2-Chloroethyl vinyl ether
~)~~ T,M 4-Methyl-2-pentanone
~1 T,M cis-1 /3-Dichloropropene
:~ S I
5::; S
CHLOROBENZENE-D5
Toluene-d8
5::;1 C , T,M Toluene
53 T,M trans-1 /3-Dichloropropene
40 T,M Ethyl methacrylate
1~ T,M 1 /1 /2-Trichloroethane
~~ T,M 2-Hexanone
~~ T,M l,3-Dichloropropane
~3 T,M Tetrachloroethene
64 T,M Dibromochloromethane
65 T,M 1 /2-Dibromoethane
66 T,M 1-Chlorohexane
~7 P/M Chlorobenzene
ta T,M l,l /1,2-Tetrachloroethane
~9 C,T/M Ethylbenzene
~l~:') T, M m-Xylene & p-Xylene
~1 T,M o-Xylene
1:~ T,M Styrene
~~ T,M Isopropylbenzene
3~ I l,2-DICHLOROBENZENE-D4
7:) P, T,M Bromoform
~~ P,T/M l,l,2,2-Tetrachloroethane
~jl'! S 4-Bromofluorobenzene
G~ T,M 1 /2 /3-Trichloropropane
h9 T,M trans-1,4-Dichloro-2-butene
~O T,M n-Propylbenzene
0.118
0.182
l. 335
0.235
0.330
0.622
0.301
0.326
0.001
0.121
0.054
0.147
0.424
1.000
l. 390
1.778
0.401
0.290
0.211
0.125
0.416
0.353
0.234
0.188
0.761
1.014
0.298
2.000
1.447
1.364
1.046
1.783
1.000
0.355
0.686
1.351
0.184
0.192
7.269
0.120
0.187
1.361
0.241
0.335
0.691
0.309
0.340
0.001
0.120
0.019
0.148
0.429
1.000
l.497
1.867
0.404
0.257
0.219
0.129
0.426
0.362
0.241
0.189
0.778
1.053
0.314
2.094
1.514
1.458
1.019
1.933
1.000
0.330
0.681
1.372
0.181
0.165
7.469
-l. 7
-2.7
-l. 9
-2.6
-l. 5
-11.1
-2.7
-4.3
0.0
0.8
64.8#
-0.7
-l. 2
0.0
-7.7
-5.0
-0.7
1l.4
-3.8
-3.2
-2.4
-2.5
-3.0
-0.5
-2.2
-3.8
-5.4
-4.7
-4.6
-6.9
2.6
-8.4
0.0
7.0
0.7
-l. 6
l.6
14.1
-2.8
97
96
102
101
101
99
102
103
96
98
37#
96
99
98
100
103
97
87
102
98
100
102
99
97
100
103
104
103
101
104
95
105
100
94
99
100
96
86
104
0.04
0.03
0.03
0.03
0.03
0.02
0.02
0.03
0.02
0.03
0.02
0.02
0.03
0.02
0.02
0.03
0.03
0.03
0.02
0.02
0.02
0.02
0.03
0.02
0.03
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.00
0.02
0.02
~-------------------------------------------------------------------------
f (#) = Out of Range
~REC404.D V067D26.M Thu May 18 08:23:58 2023 Page 2
REPORT ID: 23E120 Page 210 of 560
Evaluate Continuing Calibration Report
I:, Data File D: \HPCHEM\l \DATA\23E17\REC404.D
..,.;~ \;
~~ Aeq On 17 May 2023 5:23 pm
Vial: 26
Operator: VLu
Inst 67 ;) Sample EV067D2616
5~ Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
~ MS Integration Params: RTE.P
Method ~~ ~~~
"U; Title
-p <.)
(~,: Last Update
Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000
20%
Min. Rel. Area
Max. Rel. Area
50%
200%
Max. R.T. Dev 0.16min
Compound AvgRF CCRF %Dev Area% Dev(min)
I:;' 1
;~~ 2
i1 3
c~ :1:: ~;
;~)
<':'
(; ~:"j
: "< / c
n ~;l
.. ~ ~:-:~
,"{ q
~~l ·'Cf
--::2 ,:.-:/
'::J 3
94
:) 5
9 6
9 7
,3
c,
0
~~ ., ., .~ :7-
';".~ .,
:1 ,.~
-' \ \.;":"
;-.. ,-
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
T ,
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
Bromobenzene
1,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1,2,4-Trimethylbenzene
see-Butylbenzene
p-Isopropyltoluene
1,3-Diehlorobenzene
1,4-Diehlorobenzene
n-Butylbenzene
1,2-Diehlorobenzene
1,2-Dibromo-3-ehloropropane
1,2,4-Triehlorobenzene
Hexaehlorobutadiene
Naphthalene
1,2,3-Triehlorobenzene
1.024
4.534
4.686
3.849
1.000
4.206
6.008
4.718
2.049
1.994
4.492
1. 613
0.071
0.680
0.573
0.871
0.464
1.038
4.697
4.634
4.043
1.058
4.384
6.358
5.017
2.130
2.059
4.684
1.688
0.068
0.744
0.661
0.856
0.521
-1. 4
-3.6
1.1
-5.0
~5.8
-4.2
-5.8
-6.3
-4.0
-3.3
-4.3
-4.6
4.2
-9.4
-15.4
1.7
-12.3
105 0.02
105 0.02
105 0.02
103 0.02
110 0.02
105 0.02
105 0.02
105 0.02
106 0.02
106 0.02
103 0.00
106 0.02
96 0.02
108 0.02
114 0.02
98 0.02
112 0.03
~G---------------------------------------------------------------------~-~
~!#) = Out of Range
¢pEC404.D V067D26.M
SPCC's out = 0 CCC's out = 0
Thu May 18 08:23:59 2023 Page 3
REPORT ID: 23E120 Page 211 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC404.D Vial: 26
Operator: VLu Acq On 17 May 2023 5:23 pm
Sample EV067D2616 Inst 67
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 18 8:23 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1 t 4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) 1 t 2-DICHLOROBENZENE-D4
; System Monitoring Compounds
36) Dibromofluoromethane
Spiked Amount 10.000
43) 1 t 2-Dichloroethane-d4
Spiked Amount 10.000
56) Toluene-d8
Spiked Amount 10.000
77) 4-Bromofluorobenzene
Spiked Amount 10.000
:Target Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) 1 t 1 t 2-Trichloro-1 t 2 t 2-trif
13) Acetone
14) 1 t 1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1 t 2-Dichloroethene
24) Isopropyl ether (DIPE)
25) 1 t 1-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2t2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.17
15.62
19.50
8.22
9.32
12.99
17.62
1. 88
2.18
2.28
2.68
2.72
2.81
2.99
3.53
3.59
3.61
3.80
3.94
4.26
4.32
4.54
4.56
4.79
4.83
5.07
5.73
5.92
5.97
6.66
6.94
7.24
7.35
7.71
114 2151225
117 1564211
152 498006/
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.03
0.02
0.02
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
543685 10.60
Recovery
402755 10.29
Recovery
2341882 10.77
Recovery
683406 10.16
Recovery
ug/l
106.00%
ug/l
102.90%
ug/l
107.70%
ug/l
101. 60%
0.03
0.03
0.02
0.02
603416
959585
1012478
636981
707481
9.19 ug/l
8.42 ug/l
10.02 ug/l
10.23 ug/l
10.69 ug/l
10.46 ug/l
10.93 ug/l
46.70 ug/l
10.62 ug/l
53.14 ug/l
Qvalue
99
93
100
100
98
1309784
807521
235280
511322
458479
1160919
544477
978297
285072
2850385
917017
561393
1044942
794320
2458190
1316398
738165
1637476
149178
888914
790001
1112556
9.83 ug/l
229.72 ug/l
9.47 ug/l
10.16 ug/l
11.58 ug/l
9.17 ug/l
49.60 ug/l
10.17 ug/l
9.76 ug/l
10.34 ug/l
9.98 ug/l
9.79 ug/l
10.05 ug/l
51.98 ug/l
10.33 ug/l
10.23 ug/l
10.44 ug/l
100
99
98
99
100
99
99
99
99
100
99
99
99
100
99
100
100
100
97
99
99
99
(#) = qualifier out of range (m) = manual integration
REC404.D V067D26.M Thu May 18 08:23:26 2023 Page 1
REPORT ID: 23E120 Page 212 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC404.D
,Z\cq On 17 May 2023 5: 23 pm
Sample EV067D2616
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:23 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
ljast Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
1 38) l,l,l-Trichloroethane
~ 40) l,l-Dichloropropene
~ 41) Carbon tetrachloride
1\ 42) tert -Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
r 46) Trichloroethene
~ 47) Methylcyclohexane
L 48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
-68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.09
8.17
8.59
8.60
8.95
9.13
9.28
9.50
9.51
10.75
10.82
11.10
11.54
11.63
11.63
12.21
12.26
12.59
13.13
13.51
13.54
13.76
13.82
14.20
14.26
14.62
14.96
15.30
15.68
15.76
15.78
15.91
16.64
16.71
17.24
17.25
17.52
17.72
17.84
17.82
17.88
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
315711
81879
1303272
911784
367452
735728
258072
2928313
518518
720669
1487060
665014
730864
49420
258800
41664
1586941
923418
2921026
632464
401877
341998
1012227
666043
565734
376196
295463
1217417
1647863
490837
3275066
4737843
2281121
1594634
3023142
164275
339138
90386
81937
3719713
516685
(#) = qualifier out of range (m) = manual integration
REC404.D V067D26.M Thu May 18 08:23:27 2023
10.07 ug/l
8.80 ug/l
10.85 ug/l
10.24 ug/l
9.98 ug/l
10.23 ug/l
10.17 ug/l
10.20 ug/l
10.28 ug/l
10.15 ug/l
11.11 ug/l
10.27 ug/l
10.42 ug/l
196.51 ug/l
9.96 ug/l
3.58 ug/l
50.16 ug/l
10.11 ug/l
10.50 ug/l
10.08 ug/l
8.85 ug/l
10.35 ug/l
51.97 ug/l
10.23 ug/l
10.25 ug/l
10.26 ug/l
10.06 ug/l
10.23 ug/l
10.39 ug/l
10.54 ug/l
10.47 ug/l
20.93 ug/l
10.69 ug/l
9.75 ug/l
10.84 ug/l
9.30 ug/l
9.93 ug/l
9.84 ug/l
8.58 ug/l
10.28 ug/l
10.13 ug/l
Qvalue
100
96
98
99
99
99
98
100
100
99
99
98
98
98
99
91
98
99
100
96
99
98
99
98
100
99
99
100
99
100
99
100
100
99
100
99
100
97
96
100
100
Page 2
REPORT ID: 23E120 Page 213 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E17\REC404.D
Aeq On 17 May 2023 5:23 pm
Sample EV067D2616
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 8:23 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1,3,5-Trimethylbenzene 18.04 105 2339294 10.36 ug/l
83) 2-Chlorotoluene 18.06 91 2307915 9.89 ug/l
84) 4-Chlorotoluene 18.13 91 2013463 10.51 ug/l
85) tert-Butylbenzene 18.50 134 526703 10.58 ug/l ,A
l'
86) l,2,4-Trimethylbenzene 18.54 105 2183119 10.42 ug/l
87) see-Butylbenzene 18.74 105 3166192 10.58 ug/l
88 ) p-Isopropyltoluene 18.90 119 2498479 10.63 ug/l
89) l,3-Diehlorobenzene 19.01 146 1060641 10.39 ug/l
90 ) l,4-Diehlorobenzene 19.14 146 1025189 10.33 ug/l
91) n-Butylbenzene 19.34 91 2332725 10.43 ug/l
92) l,2-Diehlorobenzene 19.53 146 840575 10.46 ug/l
93) l,2-Dibromo-3-ehloropropan 20.31 157 33703 9.60 ug/l
r
94) l,2,4-Triehlorobenzene 21.17 180 370300 10.93 ug/l
95) Hexaehlorobutadiene 21. 30 225 328990 11.54 ug/l
96) Naphthalene 21.45 128 426311 9.83 ug/l
97) l,2,3-Triehlorobenzene 21.71 180 259684 11.23 ug/l
(#) = qualifier out of range (m) = manual integration
REC404.D V067D26.M Thu May 18 08:23:27 2023
Qvalue
100
95
99
97
100
99
99
99
99
99
100
98
100
100
99
99
Page 3
REPORT ID: 23E120 Page 214 of 560
Data File
Aeq On
Sample
Quantitation Report
D:\HPCHEM\I\DATA\23EI7\REC404.D
17 May 2023 5:23 pm
EV067D2616
Vial:
Operator:
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: May 18 8:23 2023 Quant Results File:
Method
Title
Last Update
Response via
Abundance .
8000000 1
7500000:
7000000;
6500000;[
'i
!
6000000 1 ~ :1
5500000: I
5000000:
4500000:
i
i
4000000b,
ItT-:
'v i~
,0;
3500000i~
,~
o ." '5 :"8
3000000j~ to
Ie?
25000001 , i I
t I
2000000; t
1500000'
1000000:
500000:
D:\HPCHEM\I\METHODS\V067D26.M
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC:REG404.D
(RTE Integrator)
::;:
~
<Ii c:
" >, x
C.
'" " c:
" ~
E
26
VLu
67
1. 00
V067D26.RES
i'lf :'
U _1_) :,,;Vt~,_~!\~. _, ~,, __ . ~> ~~_
Time-->
REC404.D V067D26.M Thu May 18 08:23:29 2023 Page 4
REPORT ID: 23E120 Page 215 of 560
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratories. Inc.
Lab Code : EMAX
Lab File ID: REC408
Instrument ID: 67
Project : TEAD-S
SDG No : 23E120
BFB Injection Date: 05/18/23
BFB Injection Time: 06:35
I I % RELATIVE I
I mle I ION ABUNDANCE CRITERIA ABUNDANCE I
1=1 I
I 50 I 15 -40% of mass 95 19.089 I
I 75 I 30 -60% of mass 95 I 44.641 I
I 95 I Base Peak. 100% relative abundance __ 1 100.000 I
I 96 I 5 -9% of mass 95 I 6.430 I
I 173 I Less than 2% of mass 174 I 0.000(0)1 I
I 174 I Greater than 50% of mass 95 I 74.233 I
I 175 I 5 -9% of mass 174 I 5.354(7.21)1 I
I 176 I 95 -101% % of mass 174 I 72.686(97.92)1 I
I 177 I 5 -9% % of mass 176 I 4.334(5.96)2 I
I_I I I
I-Value is % mass 174 2-Value is % mass 176
This check applies to the following samples. Lab QCs and Standards:
I EPA I LAB I LAB I DATE I TIME I
I SAMPLE NO. I SAMPLE ID I FILE ID I ANALYZED I ANALYZED I
1======1====1===1 I I
11VSTDI0 ICV067D2617 IREC409 I 05/18/23 I 07:08 I
21 LCS2W IV067EI8L IREC410 I 05/18/23 I 07:34 I
31 LCD2W IV067E18C IREC411 I 05/18/23 I 07:59 I
4IMBLK2W IV067E18B IREC413 I 05/18/23 I 08:50 I
5IS-120-08-052023 123E120-011 IREC429 I 05/18/23 I 15:41 I
6IS-127-15-052023 I 23E120-031 IREC430 I 05/18/23 I 16:07 I
7IS-140-17-052023 I 23E120-10N IREC431 I 05/18/23 I 16:33 I
8IS-142-17-052023 123E120-11N IREC432 I 05/18/23 I 16:58 I
9IS-139-17-05-2023D I 23E120-081 IREC433 I 05/18/23 I 17:24 I
10IS-139-17-052023 I 23E120-091 IREC434 I 05/18/23 I 17:50 I
111VSTD10 I EV067D2617 IREC435 I 05/18/23 I 18:16 I
I I I I I I
REPORT ID: 23E120 Page 216 of 560
FORM 8
VOLATILE INTERNAL STANDARD MEA AND RETENTION TIME SUMMARY
Lab Name: EMAX Laboratories. Inc.
Lab Code: EMAX
Lab File ID: RDC593
Instrument ID: 67
I INTERNAL STANDARD (IS) 1.4·DIFLUOROBENZENE I
I Area # I
I I
I 12 HOUR STD 2183075 I
I UPPER LIMIT 4366150 I
I LOWER LIMIT 1091538 I
I I
I Area # I
I I
11VSTD10 2460462 I
21LCS2W 2419935 I
31 LCD2W 2384647 I
4IMBLK2W 2377971 I
515·120-08-052023 2314638 I
615-127·15-052023 2256707 I
715-140-17-052023 2273932 I
815-142-17-052023 2277081 I
9IS-139-17-05-2023D 2306651 I
1015-139-17-052023 2285051 I
lllVSTDlO 2240101 I
I I
Area Upper Limit = +100% of ICAL Midpoint IS Area
Area Lower Limit = -50% of ICAL Midpoint IS Area
RT #1
I
10.14 I
10.31 I
9.973 I
I
RT # I
I
10.17 I
10.17 I
10.17 I
10.17 I
10.15 I
10.15 I
10.15 I
10.15 I
10.15 I
10.15 I
10.15 I
I
CHLOROBENZENE-D5
Area # I
I
1594928 I
3189856 I
797464 I
I
Area # I
I
1774908 I
1770486 I
1720549 I
1665592 I
1638965 I
1595081 I
1615341 I
1624955 I
1635729 I
1604883 I
1651674 I
I
Retention Time(RT) Upper Limit = +10 seconds of ICAL Midpoint IS RT
Retention Time(RT) Lower Limit = -10 seconds of ICAL Midpoint IS RT
I
RT #1
I
15.60 I
15.77 I
15.43 I
I
RT # I
I
15.62 I
15.62 I
15.62 I
15.62 I
15.60 I
15.60 I
15.60 I
15.60 I
15.60 I
15.60 I
15.60 I
I
Project: TEAD·S
SDG No: 23£120
Date Analyzed: 04/26/23
Time Analyzed: 10:54
1.2-DICHLOROBENZENE·D4 I
Area # I RT #1
I I
498004 I 19.49 I
996008 I 19.66 I
249002 I 19.32 I
I I
Area # I RT # I
I I
542284 I 19.50 I
546273 I 19.50 I
538153 I 19.50 I
429983 I 19.50 I
445086 I 19.49 I
427025 I 19.49 I
434654 I 19.49 I
446034 I 19.49 I
445818 I 19.49 I
430883 I 19.50 I
529078 I 19.49 I
I I
REPORT ID: 23E120 Page 217 of 560
BFB
Data File D:\HPCHEM\1\DATA\23E18\REC408.D Vial: 1
Acq On 18 May 2023 6:35 am Operator: VLu
Sample BFB67E18 Inst 67
Misc T/CHK Multiplr: 1.00
MS Integration Params: RTE.P
Method D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
Title : METHOD 8260B
Abundance
60000i
40000'
30000'
. Ion 95.00 (94.7OlO9o.rO): REC408.D
~ 'I II I,
" il
j I
Ii , I
I ,,' II 200001,'
! i i ! i
100001 I I I ,
I i \ II
I
lrime-->
. ! \ O~~" " : i'T" iii iii I" I' I" I --)1 \ I ,I 1--r-r-~~'-I'-'------'--I--'----~-'-"7~-'-rr----'-'--------:--'-'"
15.80 16.00 16.20 16.40 16.60 16.8017.00 17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00 19.20 19.40
Abundance
i
50000;
i
400001
I
20000J
i
!
10000i 50
m/z-->
39 45 o~'o 35' 4'0 4'5 50
75
Average of 17.618 to 17.648 min.: REC408.D (-)
95
174
! i
AutoFind: Scans 1042, 1043, 1044; Background Corrected with Scan 1036
I Target I ReI. to I Lower
Mass I Mass Limit%
50 95 15
75 95 30
95 95 100
96 95 5
173 174 0.00
174 95 50
175 174 5
176 174 95
177 176 5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
ReI.
Abn%
19.1/ ,
44.61
100.0
6.4 I
0.0 /
74.2 I
7.2 /
97.9 !
6.0 II
REC408.D V067D26.M Fri May 19 08:40:13 2023
Raw
Abn
9773
22855
51197
3292
0
38005
2741
37213
2219
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 23E120 Page 218 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E18\REC409.D
Acq On 18 May 2023 7:08 am
Sample CV067D2617
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration ~
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
25 P,T,M l,l-Dichloroethane
26 T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
29 T,M 2-Butanone
30 T,M 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
33 T,M Bromochloromethane
~4 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
37 T,M Cyclohexane
38 T,M l,l,l-Trichloroethane
~9 T,M 2,2,4-Trimethylpentane
40 T,M l,l-Dichloropropene
41 T,M Carbon tetrachloride
Amount Calc.
10.000 10.000
10.000 9.879
-1.000 0.000
10.000 8.286 ~
10.000 9.541
10.000 10.106
10.000 10.354
10.000 10.867
10.000 10.238
-1.000 0.000
50.000 46.925
10.000 11.242
50.000 54.479
10.000 10.629 J
250.000 249.501
10.000 10.537
10.000 10.102
-1.000 0.000
10.000 10.732
10.000 9.675
50.000 48.876
10.000 10.373
10.000 10.591
10.000 10.589
10.000 10.715
10.000 10.030
-1.000 0.000
10.000 10.178
50.000 51.122
10.000 11.905
10.000 10.766
10.000 10.992
10.000 10.501 /
10.000 8.559
50.000 0.000
10.000 10.919
10.000 10.987
10.000 11.037
10.000 0.000
10.000 10.033
10.000 10.920
%Dev Area% Dev(min)
0.0
1.2
0.0
17.1
4.6
-1.1
-3.5
-8.7
-2.4
0.0
6.2
-12.4
-9.0
-6.3
0.2
-5.4
-1. 0
0.0
-7.3
3.2
2.2
-3.7
-5.9
-5.9
-7.1
-0.3
0.0
-1. 8
-2.2
-19.0
-7.7
-9.9
-5.0
14.4
100.0#
-9.2
-9.9
-10.4
100.0#
-0.3
-9.2
113
104
o
87
95
102
105
123
104
o
100
128
126
121
113
116
104
o
108
116
108
116
120
120
123
103
o
118
113
136
122
126
118
95
o
116
113
125
o
114
122
0.03
0.03
0.00
0.05
0.03
-0.01
0.03
0.00
0.03
0.00
0.03
0.02
0.04
0.04
0.02
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.01
0.03
0.03
0.01
0.01
0.03
0.03
0.03
0.03
0.03
0.02
-8.16#
0.01
0.03
0.03
-8.73#
0.01
0.03
~-------------------------------------------------------------------------
: (#) = Out of Range
;REC409.D V067D26.M Fri May 19 08:40:36 2023 Page 1
REPORT ID: 23E120 Page 219 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E18\REC409.D
Acq On 18 May 2023 7:08 am
Sample CV067D2617
.~,' Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
.I,. Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B ") 'i Last Update
:.' c' Response via
", .:-!
v~ ~ Min. RRF
Max. RRF Dev
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
42 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
44 T,M Benzene
45 T,M l,2-Dichloroethane
46 T,M Trichloroethene
47 T,M Methylcyclohexane
48 C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
5p T,M 1,4-Dioxane
51 T,M Dibromomethane
52 T,M 2-Chloroethyl vinyl ether
~j T,M 4-Methyl-2-pentanone
54 T,M cis-1,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
59 T,M Ethyl methacrylate
60 T,M l,l,2-Trichloroethane
61 T,M 2-Hexanone
62 T,M l,3-Dichloropropane
~3 T,M Tetrachloroethene
64 T,M Dibromochloromethane
65 T,M l,2-Dibromoethane
6~ T,M 1-Chlorohexane
g? P,M Chlorobenzene
68 T,M l,l,l,2-Tetrachloroethane
69 C,T,M Ethylbenzene
~Q T,M m-Xylene & p-Xylene
11 T,M o-Xylene
72 T,M Styrene
13 T,M Isopropylbenzene
)
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.213
10.281
10.667
10.058
10.148
10.713
10.392
10.701
193.444
9.974
1.642
46.322
10.596
10.000
10.852
10.987J
10.457
8.548
10.627
48.052
10.467
11.061
10.371
10.297
11.027
10.650
11.381
11.014
22.284 /
11.300
9.715
11.423
-2.1
-2.8
-6.7
-0.6
-l. 5
-7.1
-3.9
-7.0
3.3
0.3
83.6#
7.4
-6.0
0.0
-8.5
-9.9
-4.6
14.5
-6.3
3.9
-4.7
-10.6
-3.7
-3.0
-10.3
-6.5
-13.8
-10.1
-1l. 4
-13.0
2.9
-14.2
112
110
122
113
115
109
118
121
108
113
20
101
118
III
114
122
114
95
118
103
116
125
114
112
122
120
128
123
122
125
107
126
0.03
0.01
0.03
0.03
0.03
0.02
0.01
0.03
0.01
0.03
0.02
0.01
0.03
0.01
0.02
0.03
0.03
0.03
0.01
0.01
0.01
0.01
0.03
0.02
0.03
0.01
0.01
0.02
0.01
0.01
0.01
0.01
74 I l,2-DICHLOROBENZENE-D4 10.000 10.000 0.0 109 0.01
75 P,T,M Bromoform 10.000 9.802 2.0 108 0.02
76 P,T,M l,l,2,2-Tetrachloroethane 10.000 10.424 -4.2 113 0.01
77 S 4-Bromofluorobenzene 10.000 10.319 -3.2 110 0.01
78 T,M 1, 2, 3-Trichloropropane 10.000 10.278 -2.8 109 0.01
q§ T,M trans-1,4-Dichloro-2-butene 10.000 10.148 -1.5 110 0.02
80 T,M n-Propylbenzene 10.000 11.394 -13.9 125 0.01
~~------------------------------------------------------------------------
6~#) = Out of Range
6REC409.D V067D26.M
c;
Fri May 19 08:40:37 2023 Page 2
REPORT ID: 23E120 Page 220 of 560
Evaluate Continuing Calibration Report
-,0 Data File D: \HPCHEM\l \DATA\23E18\REC409.D Vial: 2
Operator: VLu :);) Acq On 18 May 2023 7: 08 am
'}, Sample CV067D2617 Inst 67
t' .
~
j'> --
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
r::: -j
\.... ,2.
82
f33
8·~~
t3 ::
::3 }
,c;:
2
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Mul tiplr: 1. 00
MS Integration Params: RTE.P
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Min. RRF
Max. RRF Dev
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M Bromobenzene 10.000 10.636 -6.4 120 0.01
T,M 1,3,5-Trimethylbenzene 10.000 11.031 -10.3 122 0.02
T,M 2-Chlorotoluene 10.000 10.142 -1.4 117 0.01
T,M 4-Chlorotoluene 10.000 9.618 3.8 103 0.01
T,M tert-Butylbenzene 10.000 11.619 -16.2 131 0.01
T,M 1, 2, 4-Trimethylbenzene 10.000 11.088 -10.9 122 0.01
T,M sec-Butylbenzene 10.000 11.837 -18.4 128 0.01
T,M p-Isopropyltoluene 10.000 11.480 -14.8 123 0.01
T,M 1,3-Dichlorobenzene 10.000 10.550 -5.5 117 0.01
T,M 1,4-Dichlorobenzene 10.000 10.408 -4.1 116 0.01
T,M n-Butylbenzene 10.000 11. 177 -11.8 120 0.02
T,M 1,2-Dichlorobenzene 10.000 10.583 -5.8 117 0.01
T,M 1,2-Dibromo-3-chloropropane 10.000 9.799 2.0 106 0.01
T,M 1, 2, 4-Trichlorobenzene 10.000 11.132 -11. 3 119 0.01
T,M Hexachlorobutadiene 10.000 12.112 -21.1# 130 0.01
T,M Naphthalene 10.000 9.155 8.5 99 0.01
T,M 1, 2, 3-Trichlorobenzene 10.000 10.552 -5.5 115 0.03
-(#) = Out of Range
REC409.D V067D26.M
SPCC's out = a CCC's out = a
Fri May 19 08:40:37 2023 Page 3
REPORT ID: 23E120 Page 221 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E18\REC409.D
Acq On 18 May 2023 7:08 am
Sample CV067D2617
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
.~~ MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
~~ T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
25 P,T,M l,l-Dichloroethane
2~ T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
29 T,M 2-Butanone
30 T,M 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
33 T,M Bromochloromethane
34 T,M Tetrahydrofuran
65 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
37 T,M Cyclohexane
38 T,M l,l,l-Trichloroethane
39 T,M 2,2,4-Trimethylpentane
40 T,M l,l-Dichloropropene
41 T,M Carbon tetrachloride
AvgRF CCRF
1.000 1.000
0.305 0.302
0.000 0.000
0.530/ 0.439
0.470 0.448
0.290 0.293
0.308 0.319
0.582 0.632
0.343 0.352
0.000 0.000
0.023 0.022
0.224 0.252
0.040 0.044
0.549 0.584
0.011 0.011
0.480 0.506
0.130 0.132
0.000 0.000
1.144 1. 228
0.465 0.450
0.053 0.051
0.478 0.496
0.378 0.401
1.105 1.170
0.613/ 0.657
0.350 0.351
0.000 0.000
0.757 0.771
0.013 0.014
0.400 0.476
0.359 0.387
0.495 0.544
0.146 0.153
0.043 0.037
0.009 0.000
0.238 0.260
0.559 0.614
0.414 0.457
1.474 0.000
0.171 0.172
0.334 0.365
%Dev Area% Dev(min)
0.0
1.0
0.0
17.2
4.7
-1. 0
-3.6
-8.6
-2.6
0.0
4.3
-12.5
-10.0
-6.4
0.0
-5.4
-1. 5
0.0
-7.3
3.2
3.8
-3.8
-6.1
-5.9
-7.2
-0.3
0.0
-1. 8
-7.7
-19.0
-7.8
-9.9
-4.8
14.0
100.0#
-9.2
-9.8
-10.4
100.0#
-0.6
-9.3
113
104
0#
87
95
102
105
123
104
0#
100
128
126
121
113
116
104
0#
108
116
108
116
120
120
123
103
0#
118
113
136
122
126
118
95
0#
116
113
125
0#
114
122
0.03
0.03
0.00
0.05
0.03
-0.01
0.03
0.00
0.03
0.00
0.03
0.02
0.04
0.04
0.02
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.01
0.03
0.03
0.01
0.01
0.03
0.03
0.03
0.03
0.03
0.02
-8.16#
0.01
0.03
0.03
-8.73#
0.01
0.03
~~---------------------------------------~--------------------------------
;: '.(#) = Out of Range
j~EC409.D V067D26.M Fri May 19 08:40:41 2023 Page 1
REPORT ID: 23E120 Page 222 of 560
Eva,i.uate Continuing Calibration Report
" Data File D:\HPCHEM\1\DATA\23E18\REC409.D
"" Acq On 18 May 2023 7: 08 am
Sample CV067D2617
~,' Misc 10ppb 8260/50ppb KET-AA/250ppb
;' MS Integration Params: RTE.P
TBA
Vial: 2
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
~;t Min. RRF
:1 Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
44 T,M Benzene
45 T,M l,2-Dichloroethane
46 T,M Trichloroethene
47 T,M Methylcyclohexane
48 C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
50 T,M l,4-Dioxane
51 T,M Dibromomethane
52 T,M 2-Chloroethyl vinyl ether
53 T,M 4-Methyl-2-pentanone
54 T,M cis-1,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
§9 T,M Ethyl methacrylate
60 T,M l,l,2-Trichloroethane
61 T,M 2-Hexanone
62 T,M l,3-Dichloropropane
6g T,M Tetrachloroethene
~4 T,M Dibromochloromethane
65 T,M l,2-Dibromoethane
66 T,M 1-Chlorohexane
67 P,M Chlorobenzene
68 T,M l,l,l,2-Tetrachloroethane
69 C,T,M Ethylbenzene
~O T,M m-Xylene & p-Xylene
71 T,M o-Xylene
72 T,M Styrene
73 T,M Isopropylbenzene
~4 I l,2-DICHLOROBENZENE-D4
75 P,T,M Bromoform
~6 P,T,M l,l,2,2-Tetrachloroethane
77 S 4-Bromofluorobenzene
~8 T,M l,2,3-Trichloropropane
~9 T,M trans-1,4-Dichloro-2-butene
80 T,M n-Propylbenzene
AvgRF
0.118
0.182
1.335
0.235
0.330
0.622
0.301
0.326
0.001
0.121
0.054
0.147
0.424
CCRF
0.120
0.187
1.424
0.236
0.335
0.667
0.313
0.349
0.001
0.121
0.009
0.136
0.450
1.000 1.000
1.390 1.509
1. 778 1. 954
0.401 0.419
0.290 0.248
0.211 0.224
0.125 0.120
0.416 0.436
0.353 0.390
0.234 0.243
0.188 0.193
0.761 0.839
1.014 1.080
0.298 ... 0.339
2.000 2.203
1.447 1.612
1. 364 1. 542
1.046 1.016
1.783 2.037
1.000
0.355
0.686
1. 351
0.184
0.192
7.269
1.000
I 0.348
'/0.715
1.394
0.190
0.195
8.282
%Dev Area% Dev(min)
-1. 7
-2.7
-6.7
-0.4
-1. 5
-7.2
-4.0
-7.1
0.0
0.0
83.3#
7.5
-6.1
0.0
-8.6
-9.9
-4.5
14.5
-6.2
4.0
-4.8
-10.5
-3.8
-2.7
-10.2
-6.5
-13.8
-10.1
-11.4
-13.0
2.9
-14.2
0.0
2.0
-4.2
-3.2
-3.3
-1. 6
-13.9
112
110
122
113
115
109
118
121
108
113
20#
101
118
111
114
122
114
95
118
103
116
125
114
112
122
120
128
123
122
125
107
126
109
108
113
110
109
110
125
0.03
0.01
0.03
0.03
0.03
0.02
0.01
0.03
0.01
0.03
0.02
0.01
0.03
0.01
0.02
0.03
0.03
0.03
0.01
0.01
0.01
0.01
0.03
0.02
0.03
0.01
0.01
0.02
0.01
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.01
0.02
0.01
64--------------------------------------______________ --------------------
6~#) = Out of Range
'5REC409.D V067D26.M Fri May 19 08:40:43 2023 Page 2
REPORT ID: 23E120 Page 223 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E18\REC409.D
Aeq On 18 May 2023 7:08 am
Vial: 2
Operator: VLu
; , Sample CV067D2617 Inst 67
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
',: Method
,:~, Title
l}( Last Update
i)! '} Response via
.~ ~~
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
~~~ Min. RRF
&';;; Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
81 T,M
82 T,M
83 T,M
B4 T,M
B5 T,M
86 T,M
87 T,M
88 T,M
89 T,M
SIb T,M
91 T,M
92 T,M
~S3 T,M
94 T,M
gS T,M
96 T,M
97 T,M
; o
Bromobenzene
1 /3 /5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1 /2 /4-Trimethylbenzene
see-Butylbenzene
p-Isopropyltoluene
1 /3-Diehlorobenzene
1 /4-Diehlorobenzene
n-Butylbenzene
1 /2-Diehlorobenzene
1 /2-Dibromo-3-ehloropropane
1 /2 /4-Triehlorobenzene
Hexaehlorobutadiene
Naphthalene
1, 2, 3-Triehlorobenzene
1.024
4.534
4.686
3.849
1. 000
4.206
6.008
4.718
2.049
1.994
4.492
1.613
0.071
0.680
0.573
0.871
0.464
1.089
5.002
4.753
3.702
1.161
4.664
7.112
5.416
2.162
2.075
5.021
1.707
0.069
0.757
0.694
0.797
0.490
-6.3
-10.3
-1.4
3.8
-16.1
-10.9
-18.4
-14.8
-5.5
-4.1
-11.8
-5.8
2.8
-11. 3
-21.1#
8.5
-5.6
~ (#) = Out of Range
REC409.D V067D26.M
sPCC's out = 0 CCC's out = 0
Fri May 19 08:40:44 2023
120
122
117
103
131
122
128
123
117
116
120
117
106
119
130
99
115
0.01
0.02
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.01
0.01
0.01
0.03
Page 3
REPORT ID: 23E120 Page 224 of 560
Quantitation Report (QT Reviewed)
{
. Data File D:\HPCHEM\1\DATA\23E18\REC409.D
;~cq On 18 May 2023 7:08 am
. ~ample CV067D2617
,'Mise 10ppb 8260/50ppb KET-AA/250ppb
~MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
TBA Multiplr: 1.00
0"Quant Time: May 18 9:36 2023 Quant Results File: V067D26.RES
.Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Internal Standards R.T. QIon Response Cone Units Dev(Min)
'-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 10.17 114 2460462 10.00 ug/l 0.03
55) CHLOROBENZENE-D5 15.62 117 1774908 . 10.00 ug/l 0.01
74) l,2-DICHLOROBENZENE-D4 19.50 152 542284/ 10.00 ug/l 0.01 , ..
'. j\System Monitoring Compounds
... B 36) Dibromofluoromethane 8.21 111 640249 10.92 ug/l 0.01
jV, Spiked Amount 10.000 Recovery 109.20%
fi 43)
.;-,
l,2-Dichloroethane-d4 9.30 65 460334 10.28 ug/l 0.01
Spiked Amount 10.000 Recovery 102.80%
56) Toluene-d8 12.99 98 2678145 10.85 ug/l 0.02
Spiked Amount 10.000 Recovery 108.50%
77 ) 4-Bromofluorobenzene 17.62 95 755847 10.32 ug/l 0.01
Spiked Amount 10.000 Recovery = 103.20%
Target Compounds Qvalue
2) Dichlorodifluoromethane 1. 88 85 741917 9.88 ug/l 100
4) Chloromethane 2.16 50 1080424 8.29 ug/l 96
5) Vinyl chloride 2.26 62 1102353 9.54 ug/l 99
6) Bromomethane 2.66 94 720068 10.11 ug/l 99
7) Chloroethane 2.72 64 783808 10.35 ug/l 98
8) Dichlorofluoromethane 2.79 67 1555636 10.87 ug/l 100
9) Trichlorofluoromethane 2.99 101 864880 10.24 ug/l 99
" ~, 11 ) Acrolein 3.53 56 270414 46.93 ug/l 99 ~~.,
~ 12) l,l,2-Trichloro-1,2,2-trif 3.59 151 619172 11.24 ug/l 99
13) Acetone 3.61 43 537600 54.48 ug/l 98
14) l,l-Dichloroethene 3.80 61 1435720 10.63 ug/l 98
15 ) tert-Butyl alcohol 3.92 59 676363 249.50 ug/l 99
16) Iodomethane 4.25 142 1245463 10.54 ug/l 95
17) Methyl acetate 4.31 43 324065 10.10 ug/l 98
19 ) Carbon disulfide 4.53 76 3021711 10.73 ug/l 100
20) Methylene chloride 4.54 49 1106026 9.68 ug/l 99
21) Acrylonitrile 4.77 53 632706 48.88 ug/l 100
22) tert-Butyl methyl ether (M 4.82 73 1219186 10.37 ug/l 99
23) trans-1,2-Dichloroethene 5.05 96 986064 10.59 ug/l 100
24) Isopropyl ether (DIPE) 5.71 45 2878973 10.59 ug/l 99
25 ) l,l-Dichloroethane 5.90 63 1615831 10.72 ug/l 100
26 ) Vinyl acetate 5.96 43 864738 10.03 ug/l 100
28 ) tert-Butyl ethyl ether (ET 6.65 59 1896827 10.18 ug/l 99
29 ) 2-Butanone 6.94 72 167798 51.12 ug/l 91
30) 2,2-Dichloropropane 7.23 77 1171594 11.91 ug/l 99
31 ) cis-1,2-Dichloroethene 7.33 96 951144 10.77 ug/l 100
32) Chloroform 7.71 83 1339140 10.99 ug/l 99
(#) = qualifier out of range (m) ; manual integration
REC409.D V067D26.M Fri May 19 08:40:49 2023 Page 1
REPORT ID: 23E120 Page 225 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\I\DATA\23EI8\REC409.D
Acq On 18 May 2023 7:08 am
Sample CV067D2617
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 9:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. Qlon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
37) Cyclohexane
38) l,l,l-Trichloroethane
40) l,l-Dichloropropene
41) Carbon tetrachloride
42) tert-Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
~ 46) Trichloroethene
~ 47) Methylcyclohexane
L 48) l,2-Dichloropropane
L': 49) Bromodichloromethane
[ 50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-l,3-Dichloropropene
59) Ethyl methacrylate
60) l,l,2-Trichloroethane
61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) 1,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-l,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.15
8.59
8.60
8.94
9.13
9.26
9.49
9.51
10.75
10.82
11.10
1l. 54
1l. 63
1l. 63
12.21
12.26
12.59
13.13
13.51
13.54
13.76
13.82
14.20
14.26
14.62
14.96
15.30
15.68
15.76
15.78
15.91
16.64
16.71
17.24
17.25
17.52
17.74
17.84
17.82
17.88
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
376548
91108
1509861
1123594
422515
898266
296329
3503236
580447
823932
1640279
769740
858065
55642
296571
21878
1676110
1106436
3467868
744232
440321
398434
1062002
773318
692784
431436
343336
1488565
1917030
601100
3909488
5723274
2736075
1803147
3615848
188555
387710
102833
105581
4491291
590695
(#) = qualifier out of range (m) = manual integration
REC409.D V067D26.M Fri May 19 08:40:50 2023
10.50 ug/l
8.56 ug/l
10.99 ug/l
11.04 ug/l
10.03 ug/l
10.92 ug/l
10.21 ug/l
10.67 ug/l
10.06 ug/l
10.15 ug/l
10.71 ug/l
10.39 ug/l
10.70 ug/l
193.44 ug/l
9.97 ug/l
1.64 ug/l
46.32 ug/l
10.60 ug/l
10.99 ug/l
10.46 ug/l
8.55 ug/l
10.63 ug/l
48.05 ug/l
10.47 ug/l
11.06 ug/l
10.37 ug/l
10.30 ug/l
11.03 ug/l
10.65 ug/l
11.38 ug/l
11.01 ug/l
22.28 ug/l
11.30 ug/l
9.72 ug/l
1l. 42 ug/l
9.80 ug/l
10.42 ug/l
10.28 ug/l
10.15 ug/l
11.39 ug/l
10.64 ug/l
Qvalue
98
96
97
99
100
100
98
100
99
99
99
98
99
98
97
72
97
99
100
93
100
98
99
98
98
100
100
100
99
100
100
100
100
99
100
99
99
99
99
99
100
Page 2
REPORT ID: 23E120 Page 226 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\I\DATA\23EI8\REC409.D
Aeq On 18 May 2023 7:08 am
Sample CV067D2617
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 18 9:36 2023 Quant Results File: V067D26.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\I\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
82) l,3,5-Trimethylbenzene 18.04 105 2712470 11.03 ug/l 99
83) 2-Chlorotoluene 18.06 91 2577366 10.14 ug/l 100
[ 84) 4-Chlorotoluene 18.13 91 2007331 9.62 ug/l 93
j\ 85 ) tert-Butylbenzene 18.50 134 629820 11.62 ug/l 95
r.:: ,_,J 86) l,2,4-Trimethylbenzene 18.54 105 2528964 11.09 ug/l 99
1\1:: 87) see-Butylbenzene 18.74 105 3856480 11.84 ug/l 99
f'/ 88) p-Isopropyltoluene 18.90 119 2937262 11. 48 ug/l 99
89) 1,3-Diehlorobenzene 19.01 146 1172343 10.55 ug/l 100
90) l,4-Diehlorobenzene 19.14 146 1125312 10.41 ug/l 100
91) n-Butylbenzene 19.36 91 2722975 11.18 ug/l 99
92) l,2-Diehlorobenzene 19.53 146 925941 10.58 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.31 157 37465 9.80 ug/l 99
94) l,2,4-Triehlorobenzene 21.17 180 410495 11.13 ug/l 98
95) Hexaehlorobutadiene 21.30 225 376142 12.11 ug/l 98
96) Naphthalene 21. 45 128 432332 9.16 ug/l 99
97) l,2,3-Triehlorobenzene 21.71 180 265606 10.55 ug/l 99
(#) = qualifier out of range (m) = manual integration
REC409.D V067D26.M Fri May 19 08:40:50 2023 Page 3
REPORT ID: 23E120 Page 227 of 560
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E18\REC409.D
Aeq On 18 May 2023 7:08 am
Sample CV067D2617
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator:
Inst
Multiplr:
VLu
67
1. 00
Quant Time: May 18 9:36 2023 Quant Results File: V067D26.RES
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M
METHOD 8260B
(RTE Integrator)
Last Update
Response via
;A.bundance
7500000
1
I
7000000]
!
6500000 I!
I! Ii ii
II
6000000j
Ii
Ii
5500000j:
I
i
50000001'
I
I,
II
4500000 ,
4000000! '
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC409.D
REC409.D V067D26.M Fri May 19 08:40:53 2023
::;;
~.
~1 NI c:,
Q,)" ~ ::;; eji
.l1!li ~:
"1'
Q) c:
I'
l{
i
II ! :1 ~~ ::;; ~
~ co oj i
c: Ii! Q) ~ Ii! c:
~II !
<'3 I' ,..!. !
i I:
$1'/ ~ill U'I' I 1I11 " ! '!ili llii'
IIII !I)' j,:~ 1,1
[illl!:
t
:1 1
illll!\ :)
,ii,
'iii:,
iii:
:r!i: II iii,
Page 4
REPORT ID: 23E120 Page 228 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E18\REC435.D
Acq On 18 May 2023 6:16 pm
Sample EV067D2617
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 28
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration ~
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
4 P,T,M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 TIM Acrolein
12 T,M 1,1,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 TIM Methyl acetate
18 TIM Acetonitrile
19 T,M Carbon disulfide
20 T,M Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 TIM trans-1,2-Dichloroethene
24 T,M Isopropyl ether (DIPE)
2S P,T,M l,l-Dichloroethane
26 T,M Vinyl acetate
27 T,M 2-Butanol
28 TIM tert-Butyl ethyl ether (ETB
29 TIM 2-Butanone
30 T,M 2,2-Dichloropropane
31 T,M cis-1,2-Dichloroethene
32 C,T,M Chloroform
33 T,M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
36 S Dibromofluoromethane
3~ T,M Cyclohexane
jg T,M 1,1,1-Trichloroethane
39 T,M 2,2,4-Trimethylpentane
40 T,M 1,1-Dichloropropene
41 T,M Carbon tetrachloride
Amount Calc.
10.000 10.000
10.000 9.155
-1.000 0.000
10.000 8.353
10.000 10.064
10.000 10.336
10.000 10.667
10.000 9.916
10.000 11.312
-1.000 0.000
50.000 40.651
10.000 10.175
50.000 55.598
10.000 9.157
250.000 236.637
10.000 9.167
10.000 10.313
-1.000 0.000
10.000 12.448
10.000 8.851
50.000 50.736
10.000 9.918
10.000 9.197
10.000 9.849
10.000 9.585
10.000 9.023
-1.000 0.000
10.000 9.667
50.000 53.329
10.000 9.770
10.000 9.764
10.000 9.971
10.000 10.030
10.000 9.470
50.000 0.000
10.000 10.618
10.000 10.756
10.000 9.640
10.000 0.000
10.000 9.416
10.000 9.710
%Dev Area% Dev(min)
0.0
8.5
0.0
16.5
-0.6
-3.4
-6.7
0.8
-13.1
0.0
18.7
-1. 8
-11.2
8.4
5.3
8.3
-3.1
0.0
-24.5#
11. 5
-1. 5
0.8
8.0
1.5
4.1
9.8
0.0
3.3
-6.7
2.3
2.4
0.3
-0.3
5.3
100.0#
-6.2
-7.6
3.6
100.0#
5.8
2.9
103
88
a
80
91
95
99
102
105
a
79
105
117
95
98
92
97
a
114
97
102
101
95
102
100
84
a
102
107
102
101
104
102
95
a
103
100
99
a
98
99
0.01
0.02
0.00
0.05
0.02
0.00
0.02
0.02
0.02
0.00
0.03
0.02
0.04
0.02
0.02
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.01
0.03
0.03
0.03
0.01
0.01
0.03
0.03
0.03
0.03
0.01
-8.16#
0.01
0.01
0.03
-8.73#
0.01
0.01
~~------------------------------------------------------------------------
~~#) = Out of Range
&EC435.D V067D26.M Fri May 19 08:41:14 2023 Page 1
REPORT ID: 23E120 Page 229 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E18\REC435.D
5 Acq On 18 May 2023 6:16 pm
Sample EV067D2617
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 28
Operator: VLu
Inst 67
Multiplr: 1.00
s Method
.• , Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
" Last Update
:J d Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
.:;b Min. RRF
~{.~. Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
44 T,M Benzene
45 T,M l,2-Dichloroethane
46 T,M Trichloroethene
47 T,M Methylcyclohexane
48 C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
50 T,M l,4-Dioxane
51 T,M Dibromomethane
52 T,M 2-Chloroethyl vinyl ether
5] T,M 4-Methyl-2-pentanone
54 T,M cis-1,3-Dichloropropene
55 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
S9 T,M Ethyl methacrylate
60 T,M l,l,2-Trichloroethane
61 T,M 2-Hexanone
g2 T,M l,3-Dichloropropane
63 T,M Tetrachloroethene
64 T,M Dibromochloromethane
05 T,M l,2-Dibromoethane
~6 T,M 1-Chlorohexane
67 P,M Chlorobenzene
58 T,M l,l,l,2-Tetrachloroethane
gg C,T,M Ethylbenzene
76 T,M m-Xylene & p-Xylene
71 T,M o-Xylene
72 T,M Styrene
i9 T,M Isopropylbenzene
j4 I l,2-DICHLOROBENZENE-D4
,~ P,T,M Bromoform
?~ P,T,M 1, 1, 2, 2-Tetrachloroethane
~7 S 4-Bromofluorobenzene
~8 T,M l,2,3-Trichloropropane
79 T,M trans-1,4-Dichloro-2-butene
80 T,M n-Propylbenzene
Amount Calc.
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.992
10.402
9.730
10.085
9.714
11.129
9.941
10.098
207.643
10.034
3.204
50.986
9.875
10.000
10.521
9.832
9.697
8.751
10.028
51.404
9.882
9.654
9.886
10.091
9.482
9.914
10.057
9.708
19.761
10.024
9.296
10.181
10.000
9.425
9.899
9.923
9.884
8.462
9.590
'(#) = Out of Range
6REC435.D V067D26.M Fri May 19 08:41:14 2023
f·
%Dev Area% Dev(min)
0.1
-4.0
2.7
-0.9
2.9
-11.3
0.6
-1. 0
-3.8
-0.3
68.0#
-2.0
1.3
0.0
-5.2
1.7
3.0
12.5
-0.3
-2.8
1.2
3.5
1.1
-0.9
5.2
0.9
-0.6
2.9
1.2
-0.2
7.0
-1. 8
0.0
5.7
1.0
0.8
1.2
15.4
4.1
99
101
101
103
100
103
103
104
106
103
35
101
101
104
103
102
99
91
104
102
102
101
101
102
97
104
105
101
101
103
96
105
106
101
105
103
103
90
103
0.03
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.01
Page 2
REPORT ID: 23E120 Page 230 of 560
Evaluate Continuing Calibration Report
, , Data File D:\HPCHEM\1\DATA\23E18\REC435.D Vial:
l0 Acq On 18 May 2023 6:16 pm Operator:
,,' ; Sample EV067D2617 Inst ! ";,
/ -"., Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: .', ..... , MS Integration Params: RTE.P : "
Method
'/0 Title
.t s Last Update
Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
28
VLu
67
1. 00
) Min. RRF
~-. Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
81 T,
82 T,
83 T,
84 T,
85 T,
86 T,
l37 T,
88 T,
89 T,
9b T,
91 T,
t",-02 T,
93 T,
94 T,
95 T,
96 T,
97 T,
[)
:-j .'
s:::
c-;,.";.
ot....t
8 ~~~.
,26
~,:7
t) d
E S~
c r~ _/ .......
~) ~I
:'j .
. ;)
.-',
C
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M
Bromobenzene
l,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
l,2,4-Trimethylbenzene
sec-Butylbenzene
p-Isopropyltoluene
l,3-Dichlorobenzene
l,4-Dichlorobenzene
n-Butylbenzene
l,2-Dichlorobenzene
l,2-Dibromo-3-chloropropane
1, 2, 4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
l,2,3-Trichlorobenzene
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.761
9.695
9.618
9.511
9.856
9.738
9.878
9.915
9.787
9.843
9.618
10.049
9.796
10.175
10.857
9.048
9.943
2.4
3.0
3.8
4.9
1.4
2.6
1.2
0.9
2.1
1.6
3.8
-0.5
2.0
-1. 8
-8.6
9.5
0.6
~(#) = Out of Range
'REC435.D V067D26.M
SPCC's out = 0 CCC's out = 0
Fri May 19 08:41:15 2023
108
105
108
100
109
105
104
104
106
107
101
109
104
106
114
96
106
0.00
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.00
0.01
0.01
Page 3
REPORT ID: 23E120 Page 231 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E18\REC435.D
Acq On 18 May 2023 6:16 pm
Sample EV067D2617
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 28
Operator: VLu
Inst 67
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
,1 I l,4-DIFLUOROBENZENE
.2 T,M Dichlorodifluoromethane
3 T,M Dichlorotetrafluoroethane
.·4 P, T, M Chloromethane
5 C,T,M Vinyl chloride
6 T,M Bromomethane
7 T,M Chloroethane
8 T,M Dichlorofluoromethane
9 T,M Trichlorofluoromethane
10 T,M sec-Propyl alcohol
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 TIM Methyl acetate
18 TIM Acetonitrile
19 T,M Carbon disulfide
20 TIM Methylene chloride
21 T,M Acrylonitrile
22 T,M tert-Butyl methyl ether (MT
23 T,M trans-1,2-Dichloroethene
24 TIM Isopropyl ether (DIPE)
25 P,T/M l,l-Dichloroethane
26 T,M Vinyl acetate
27 T,M 2-Butanol
28 T,M tert-Butyl ethyl ether (ETB
~~ T,M 2-Butanone
30 TIM 2,2-Dichloropropane
31 TIM cis-1 /2-Dichloroethene
32 C,T,M Chloroform
3~ T,M Bromochloromethane
34 T,M Tetrahydrofuran
35 T,M tert-Amyl alcohol
3~ S Dibromofluoromethane
J1 T,M Cyclohexane
~8 T,M l,l,l-Trichloroethane
~9 T,M 2 /2,4-Trimethylpentane
~b T,M l,l-Dichloropropene
41 T,M Carbon tetrachloride
AvgRF
1.000
0.305
0.000
0.530
0.470
0.290
0.308
0.582
0.343
0.000
0.023
0.224
0.040
0.549
0.011
0.480
0.130
0.000
1.144
0.465
0.053
0.478
0.378
1.105
0.613
0.350
0.000
0.757
0.013
0.400
0.359
0.495
0.146
0.043
0.009
0.238
0.559
0.414
1.474
0.171
0.334
50% Max. R.T. Dev 0.16min
200%
CCRF
1.000
0.279
0.000
0.443
0.473
0.299
0.328
0.577
0.388
0.000
0.019
0.228
0.045
0.503
0.010
0.440
0.134
0.000
1.424
0.411
0.053
0.474
0.348
1.088
0.587
0.316
0.000
0.732
0.014
0.391
0.351
0.494
0.146
0.041
0.000
0.253
0.601
0.399
0.000
0.161
0.325
%Dev Area% Dev(min)
0.0
8.5
0.0
16.4
-0.6
-3.1
-6.5
0.9
-13.1
0.0
17.4
-1. 8
-12.5
8.4
9.1
8.3
-3.1
0.0
-24.5#
11. 6
0.0
0.8
7.9
1.5
4.2
9.7
0.0
3.3
-7.7
2.3
2.2
0.2
0.0
4.7
100.0#
-6.3
-7.5
3.6
100.0#
5.8
2.7
103
88
0#
80
91
95
99
102
105
0#
79
105
117
95
98
92
97
0#
114
97
102
101
95
102
100
84
0#
102
107
102
101
104
102
95
0#
103
100
99
0#
98
99
0.01
0.02
0.00
0.05
0.02
0.00
0.02
0.02
0.02
0.00
0.03
0.02
0.04
0.02
0.02
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.03
0.01
0.03
0.03
0.03
0.01
0.01
0.03
0.03
0.03
0.03
0.01
-8.16#
0.01
0.01
0.03
-8.73#
0.01
0.01
~-------------------------------------------------------------------------
~ (#) = Out of Range
,REC435.D V067D26.M Fri May 19 08:41:18 2023 Page 1
REPORT ID: 23E120 Page 232 of 560
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\I\DATA\23EI8\REC435.D
Acq On 18 May 2023 6:16 pm
J( Sample EV067D2617
6.:L Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
5L MS Integration Params: RTE.P
:j. ';':~
<, ~
Vial: 28
Operator: VLu
Inst 67
Multiplr: 1.00
_~'.r Method
~ ,:. Title
36
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update .~ "/ Response via
.j t;:
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
3 :; Min. RRF ;1 :' 0.000 Min. ReI. Area
Max. RRF Dev ,.; 20% Max. ReI. Area
Compound
42 T,M tert-Amyl methyl ether (TAM
43 S l,2-Dichloroethane-d4
44 T,M Benzene
45 T,M 1,2-Dichloroethane
46 T,M Trichloroethene 47 T,M Methylcyclohexane
4B C,T,M l,2-Dichloropropane
49 T,M Bromodichloromethane
56 T,M 1,4-Dioxane
5i T,M Dibromomethane
~1 T,M 2-Chloroethyl vinyl ether
52 T,M 4-Methyl-2-pentanone
54 T,M cis-1,3-Dichloropropene
~5 I CHLOROBENZENE-D5
56 S Toluene-d8
57 C,T,M Toluene
58 T,M trans-1,3-Dichloropropene
59 T,M Ethyl methacrylate
GO T,M l,l,2-Trichloroethane
gl T,M 2-Hexanone
62 T,M l,3-Dichloropropane
63 T,M Tetrachloroethene
~4 T,M Dibromochloromethane
~~ T,M l,2-Dibromoethane
~6 T,M 1-Chlorohexane
~~ P,M Chlorobenzene
@8 T,M 1, 1, l,2-Tetrachloroethane
6~ C,T,M Ethylbenzene
~~ T,M m-Xylene & p-Xylene
~l iT, M o-Xylene
'72 T, M Styrene
73 T,M Isopropylbenzene
.... :;
74 I l,2-DICHLOROBENZENE-D4
75 P,T,M Bromoform
76 P,T,M l,l,2,2-Tetrachloroethane
~7 S 4-Bromofluorobenzene
18 T,M l,2,3-Trichloropropane
~9 T,M trans-1,4-Dichloro-2-butene
~0 T,M n-Propylbenzene
AvgRF
0.118
0.182
1. 335
0.235
0.330
0.622
0.301
0.326
0.001
0.121
0.054
0.147
0.424
1.000
1.390
1.778
0.401
0.290
0.211
0.125
0.416
0.353
0.234
0.188
0.761
1.014
0.298
2.000
1.447
1. 364
1.046
1.783
1.000
0.355
0.686
1. 351
0.184
0.192
7.269
50% Max. R.T. Dev 0.16min
200%
CCRF
0.118
0.189
1. 299
0.237
0.321
0.693
0.299
0.329
0.001
0.121
0.017
0.150
0.419
1. 000
1. 463
1.748
0.389
0.254
0.212
0.128
0.411
0.341
0.232
0.190
0.721
1.006
0.299
1.941
1.430
1.367
0.972
1.816
1.000
0.334
0.679
1.340
0.182
0.162
6.971
%Dev Area% Dev(min)
0.0
-3.8
2.7
-0.9
2.7
-11.4
0.7
-0.9
0.0
0.0
68.5#
-2.0
1.2
0.0
-5.3
1.7
3.0
12.4
-0.5
-2.4
1.2
3.4
0.9
-1.1
5.3
0.8
-0.3
2.9
1.2
-0.2
7.1
-1. 9
0.0
5.9
1.0
0.8
1.1
15.6
4.1
99
101
101
103
100
103
103
104
106
103
35#
101
101
104
103
102
99
91
104
102
102
101
101
102
97
104
105
101
101
103
96
105
106
101
105
103
103
90
103
0.03
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.00
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.02
0.01
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.01
~~------------------------------------------------------------------------
~i#) = Out of Range
13R.EC435.D V067D26.M Fri May 19 08:41:21 2023 Page 2
REPORT ID: 23E120 Page 233 of 560
Evaluate Continuing Calibration Report
L,I Data File D: \HPCHEM\l \DATA\23E18\REC435.D
,,) Aeq On 18 May 2023 6: 16 pm
Vial: 28
Operator: VLu
;;i1 Sample EV067D2617 Inst 67
,c' Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
Title
Last Update
f Response via
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Multiple Level Calibration
~.~~. Min. RRF
Ei (:; Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
~J--------------------------------------------------------------------------'. Cd
81
82
aB
§4
85
86
87
88
89
90
91
92
93
94
9§
96
97
81
82
83
8·4
BTf
g(
8
~~
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
T,M
Bromobenzene
1, 3 , 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1 /2 /4-Trimethylbenzene
see-Butylbenzene
p-Isopropyltoluene
1 /3-Diehlorobenzene
1 /4-Diehlorobenzene
n-Butylbenzene
1 /2-Diehlorobenzene
1 /2-Dibromo-3-chloropropane
1,2,4-Triehlorobenzene
Hexaehlorobutadiene
Naphthalene
1, 2, 3-Triehlorobenzene
1.024
4.534
4.686
3.849
1.000
4.206
6.008
4.718
2.049
1.994
4.492
1. 613
0.071
0.680
0.573
0.871
0.464
1.000
4.396
4.508
3.660
0.985
4.096
5.934
4.678
2.006
1.963
4.321
1.621
0.069
0.692
0.622
0.788
0.462
2.3 108
3.0 105
3.8 108
4.9 100
1. 5 109
2.6 105
1. 2 104
0.8 104
2.1 106
1. 6 107
3.8 101
-0.5 109
2.8 104
-1.8 106
-8.6 114
9.5 96
0.4 106
j (#) = Out of Range
REC435.D V067D26.M
spec's out = 0 CCC's out = 0
Fri May 19 08:41:22 2023
0.00
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.00
0.01
0.01
Page 3
REPORT ID: 23E120 Page 234 of 560
Quantication Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC435.D
;~,Acq On 18 May 2023 6: 16 pm
\ Sample EV067D2617
:,Misc 10ppb 8260/50ppb KET-AA/250ppb
~MS Integration Params: RTE.P
Vial: 28
Operator: VLu
Inst 67
TBA Multiplr: 1.00
?" Quan t Time: May 19 8 : 41 2023 Quant Results File: V067D26.RES
Quant Method
", Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
.Last Update
-'Response via
.,:DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
_ Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
55) CHLOROBENZENE-D5
74) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
,-~.: 36) Dibromofluoromethane
Spiked Amount 10.000
~~ 43) l,2-Dichloroethane-d4
Spiked Amount 10.000
" 56) Toluene-d8
Spiked Amount 10.000
,T 77) 4-Bromofluorobenzene
'1:. Spiked Amount 10.000
',rTarget Compounds
2) Dichlorodifluoromethane
4) Chloromethane
5) Vinyl chloride
6) Bromomethane
7) Chloroethane
8) Dichlorofluoromethane
9) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
i' 14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
~ 17) Methyl acetate
19) Carbon disulfide
20) Methylene chloride
21) Acrylonitrile
22) tert-Butyl methyl ether (M
23) trans-1,2-Dichloroethene
24) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
26) Vinyl acetate
28) tert-Butyl ethyl ether (ET
29) 2-Butanone
30) 2,2-Dichloropropane
31) cis-1,2-Dichloroethene
32) Chloroform
10.15 114
15.60 117
19.49 152
8.21
9.30
12.97
17.60
1. 88
2.16
2.26
2.68
2.72
2.80
2.98
3.53
3.59
3.61
3.78
3.92
4.25
4.31
4.53
4.54
4.77
4.82
5.05
5.71
5.90
5.96
6.65
6.92
7.23
7.33
7.71
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
76
49
53
73
96
45
63
43
59
72
77
96
83
2240101 ~ 10.00 ug/l
1651674 / 10.00 ug/l
529078 10.00 ug/l
566863 10.62
Recovery ==
424041 10.40
Recovery
2416206 10.52
Recovery ==
709146 9.92
Recovery ==
ug/l
106.20%
ug/l
104.00%
ug/l
105.20%
ug/l
99.20%
0.01
0.00
0.00
0.01
0.01
0.00
0.00
625960
991569
1058642
670458
735174
9.16 ug/l
8.35 ug/l
10.06 ug/l
10.34 ug/l
10.67 ug/l
Qvalue
99
93
1292379
87'0040
213280
510177
499508
1126124
584038
986568
301188
3190782
921199
597958
1061303
779614
2438009
1315988
708291
1640293
159365
875334
785376
1105996
9.92 ug/l
11.31 ug/l
40.65 ug/l
10.17 ug/l
55.60 ug/l
9.16 ug/l
236.64 ug/l
9.17 ug/l
10.31 ug/l
12.45 ug/l
8.85 ug/l
50.74 ug/l
9.92 ug/l
9.20 ug/l
9.85 ug/l
9.59 ug/l
9.02 ug/l
9.67 ug/l
53.33 ug/l
9.77 ug/l
9.76 ug/l
9.97 ug/l
100
99
99
99
99
99
100
100
98
99
98
99
100
99
100
100
99
98
100
100
100
62
99
99
100
(#) == qualifier out of range (m) == manual integration
REC435.D V067D26.M Fri May 19 08:41:27 2023 Page 1
REPORT ID: 23E120 Page 235 of 560
Quantitation~eport (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC435.D
Acq On 18 May 2023 6:16 pm
Sample EV067D2617
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 28
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 19 8:41 2023 Quant Results File: V067D26.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Last Update
Response via
DataAcq Meth
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Conc Unit
33) Bromochloromethane
34) Tetrahydrofuran
,~ 37) Cyclohexane
A 38) l,l,l-Trichloroethane
,~"
o 40) l,l-Dichloropropene
M 41) Carbon tetrachloride
Iv 42) tert -Amyl methyl ether (TA
44) Benzene
45) l,2-Dichloroethane
46) Trichloroethene
47) Methylcyclohexane
48) l,2-Dichloropropane
49) Bromodichloromethane
50) l,4-Dioxane
51) Dibromomethane
52) 2-Chloroethyl vinyl ether
53) 4-Methyl-2-pentanone
54) cis-1,3-Dichloropropene
57) Toluene
58) trans-1,3-Dichloropropene
I 59) Ethyl methacrylate
~ 60) l,l,2-Trichloroethane
~ 61) 2-Hexanone
62) l,3-Dichloropropane
63) Tetrachloroethene
64) Dibromochloromethane
65) l,2-Dibromoethane
66) 1-Chlorohexane
67) Chlorobenzene
68) l,l,l,2-Tetrachloroethane
69) Ethylbenzene
70) m-Xylene & p-Xylene
71) o-Xylene
72) Styrene
73) Isopropylbenzene
75) Bromoform
76) l,l,2,2-Tetrachloroethane
78) l,2,3-Trichloropropane
79) trans-1,4-Dichloro-2-buten
80) n-Propylbenzene
81) Bromobenzene
8.08
8.15
8.57
8.60
8.94
9.11
9.26
9.48
9.49
10.74
10.82
11.09
11.53
11.63
11.61
12.20
12.24
12.58
13.12
13.50
13.53
13.75
13.82
14.20
14.26
14.61
14.94
15.28
15.67
15.76
15.78
15.91
16.64
16.70
17.24
17.25
17.52
17.72
17.82
17.82
17.87
130
42
84
97
110
119
87
78
62
130
83
63
83
88
93
63
43
75
91
75
69
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
327462
91775
1345775
893487
361055
727190
263959
2909238
529913
718018
1551432
670383
737213
54377
271616
38855
1679637
938791
2887671
642260
419495
349870
1057210
679448
562663
382687
313095
1191173
1660769
494304
3206711
4722913
2258403
1605616
2998753
176886
359209
96481
85889
3688011
528900
(#) = qualifier out of range (m) = manual integration
REC435.D V067D26.M Fri May 19 08:41:27 2023
10.03 ug/l
9.47 ug/l
10.76 ug/l
9.64 ug/l
9.42 ug/l
9.71 ug/l
9.99 ug/l
9.73 ug/l
10.09 ug/l
9.71 ug/l
11.13 ug/l
9.94 ug/l
10.10 ug/l
207.64 ug/l
10.03 ug/l
3.20 ug/l
50.99 ug/l
9.87 ug/l
9.83 ug/l
9.70 ug/l
8.75 ug/l
10.03 ug/l
51.40 ug/l
9.88 ug/l
9.65 ug/l
9.89 ug/l
10.09 ug/l
9.48 ug/l
9.91 ug/l
10.06 ug/l
9.71 ug/l
19.76 ug/l
10.02 ug/l
9.30 ug/l
10.18 ug/l
9.42 ug/l
9.90 ug/l
9.88 ug/l
8.46 ug/l
9.59 ug/l
9.76 ug/l
Qvalue
99
97
97
99
98
100
99
99
99
99
99
98
98
98
100
85
97
99
100
96
98
100
99
98
99
99
98
100
99
100
100
100
99
100
100
100
100
98
99
100
99
Page 2
REPORT ID: 23E120 Page 236 of 560
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E18\REC435.D
Aeq On 18 May 2023 6:16 pm
Sample EV067D2617
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 28
Operator: VLu
Inst 67
TBA Multiplr: 1.00
Quant Time: May 19 8:41 2023 Quant Results File: V067D26.RES
Quant Method
'I'i tIe
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
V067D26
Compound R.T. QIon Response Cone Unit
82) 1, 3, 5-Trimethylbenzene 18.04 105 2325832 9.69 ug/l
83) 2-Chlorotoluene 18.06 91 2384831 9.62 ug/l
84) 4-Chlorotoluene 18.11 91 1936613 9.51 ug/l
85) tert-Butylbenzene 18.48 134 521266 9.86 ug/l
86) l,2,4-Trimethylbenzene 18.52 105 2167020 9.74 ug/l
87 ) sec-Butylbenzene 18.74 105 3139750 9.88 ug/l
88 ) p-Isopropyltoluene 18.90 119 2475072 9.91 ug/l
89) l,3-Dichlorobenzene 19.01 146 1061081 9.79 ug/l
90) l,4-Diehlorobenzene 19.12 146 1038357 9.84 ug/l
" 91 ) n-Butylbenzene 19.34 91 2286078 9.62 ug/l \.::::
'} 92) l,2-Diehlorobenzene 19.52 146 857839 10.05 ug/l
". 93) l,2-Dibromo-3-ehloropropan 20.31 157 36544 9.80 ug/l
f? 94) l,2,4-Triehlorobenzene 21.17 180 366079 10.18 ug/l
r.:: 95) Hexachlorobutadiene 21. 29 225 328965 10.86 ug/l
96) Naphthalene 21.45 128 416854 9.05 ug/l
97) l,2,3-Triehlorobenzene 21.69 180 244189 9.94 ug/l
(#) = qualifier out of range (m) = manual integration
REC435.D V067D26.M Fri May 19 08:41:27 2023
Qvalue
99
95
93
97
99
99
99
99
99
100
100
99
98
98
99
99
Page 3
REPORT ID: 23E120 Page 237 of 560
Quantitation Report
Data File D:\HPCHEM\I\DATA\23EI8\REC435.D Vial: 28
Aeq On 18 May 2023 6:16 pm
Sample EV067D2617
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Operator:
Inst
Multiplr:
VLu
67
1. 00
Quant Time: May 19 8:41 2023 Quant Results File: V067D26.RES
Method
Title
Last Update
Response via
~bundance
7500000:
70000001
i
i
6500000[1
!I
6000000;1
II
Ii
i!
5500000 1 :
Ii II
50000001!
Ii
" i;
45000001 ;
Ii
I;
!I
4000000: i
!i
3500000: :
i I II
! I
3000000j i
I::' It!: i~
ijg
2500000il
fg I!E i~ 20000001~
iqi
; !
1500000, :
" =!;;
'I]::
1000000, : I
0-J CP~
5000001
D:\HPCHEM\1\METHODS\V067D26.M (RTE Integrator)
METHOD 8260B
Wed Apr 26 14:33:42 2023
Initial Calibration
TIC: REC435.D
REC435.D V067D26.M Fri May 19 08:41:30 2023
::;: r-: .,;
c:
~
Q. e
~
E e .c
9
"!
Page 4
REPORT ID: 23E120 Page 238 of 560
· ANALYTICAL LOGS
REPORT ID: 23E120 Page 239 of 560
Page 24
ANALYSIS LOG FOR VOLATILES
SOP IifEMAX-8260 Rev.No.!!! fiil"'EMAX-8260C Rev. No.! 0 EMAX-8260SIM Rev.No.! 0 EMAX-M8260SIM Rev.No. Q 0 EMAX-TCPSIM Rev.No. ~ 0 EMAX-624 Rev.No. § 0 EMAX-624.1 Rev.No. !
Start Date: 4/1,,11,..., o 5-ml Purge 0 10-mL Purge [!(" 25-mL Purge Book#: A67-081
I l~) Matrix Instrument No. 67 Sample Data Sample
Prep Lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
File Name Amount S 10
(AL.)
pH CI,
<2 < 500m DATE 4 /1. to 11:"
01 llbC.'~' ~E&k1 DlLj JrJ& NA AlA AlA ICZ'l.r.o Ib.J·A4 1&A /}!~l-f) ICALID VOl.,Ou,
02 n V/)/"1Jl1.'" I D,D\/IM( ID.~ u: 1.("Mb STANDARDS
Sq ... o,o,ID.),( b., 2.e-11.(" NAME 10 f Amount Cone.
03 1-lui me/L
04 '10 -; " 0" /0., \.0 ("'.0 2" DCC (f];..~
-SV\-"'--0., ::: .. 'l"b11lK" _ 'n.·ol-D,\ ::r 1.-0
OS 'II 4 "" O.l.II.ll t.o /0 (71 DCC LtIUlJ -IH-.¥ 01.. oj ~/"z,ftI
06 4l. \' b.( /~.' t'.D t~ 12.\ DCC ~~ -11-~ "''1-(1) t.." -~-11'\-2.n
07 ql b .' 1,0/("0 10 n «l> DCCTM-'11.14 -1.f1.-D1.-U} 'a!:;»/I'I,;"
08 1Lt 1 2.0 110 '2-0 100 ~o BFB -I.tl-11t1-DI I <;1)
aI 09 '1~ II ., "J.O /I, ~O I~ 1~ IS/SURR.1~ -I.tl-"1:.-0). i 1.4iI"
-iil_ VI.-b1. ... 1.\""1>
~ 10 'tc,. ., t; -0 /JA I;"b 2.tn> 1m 1l:~J.) ICV/LCS:!t~ -"\-~J"i~A ~
~//'1A"!>
n -~n.--1.<;"1)
::x: 11 11 10 lolt:l 100 ~D 'l;(lOMit ICV/LCS?~
-~I-,,~-~
I[.~
....
~ -Iri.. D1.'; D-L. Ot;
12 18 R.I.N~E. ICV/LCS~ -'41-""'-~ i -z..n,
-~I-L1i'-tn 1 ~
<.: 13
"'"
J. ICV /LCsty::r"r
_I.n._~ -01
~
'2-M
c:.r -~ ... -.tn. "' ~ 14 (.00 \I 0 j, 11)1-" I, ,,1.,·011, <;1) 20 Il~nl\k Data File Folder 23D2.-"
c:::J 15 DI R:X.N<,r: LOT # Syringe Lot # ~
C" 16 /)1-J, pH strip MW-O-~-D"1_ Dl-~
C""
17 .; 0\ -:tV 0 1..101.100 I -\It t1J 1.(bnDI. It'.l4 Chlorine strip ·O'-o2.-\~-1
18 .. '""-"''''''''' Methanol -01.-Ol-l~
19 ---NaHSO. -Ol-tH-Ol..
20 -r--""'-Reagent Water 1 RW." -1.1.-nbU 'v -'" -01 -0 r-
21 -P Sand
22 ---~ Electronic Data Archival Location Date
23 ----HPCHEM_ VOA!T067 ~ 11.111.'"
24 ~ Comments: £*hllWl'uI ttM{llh1t
25 /'" A-~ ('/is, {.ba.. ~tuJ.d1 ::r~a-ll::'"', S~
26 /' ~; ~U~Q I IlLt-~
27 ':----~ lit e.1l.II~ ~ IUDlIt-d~, z,-"f.L.cN..
28 o Refer to sample weight log
29 Analyzed By: Vl-
30 .. --.. ------... ~.Yh.._'l11.ltI.l3_ Date Disposed:. . ~f"1.Jl'l.·} --------------Disposed By: \1....
REPORT ID: 23E120 Page 240 of 560
Page 42
ANALYSIS LOG FOR VOLATILES
SOP rt'EMAX-8260 Rev.No.1Q AX-8260C Rev. No.! 0 EMAX·8260SIM Rev.No.! 0 EMAX-M8260SIM Rev.No. Q 0 EMAX-TCPSIM Rev.No. ~ 0 EMAX·624 Rev.No.!! 0 EMAX-624.1 Rev.No.!
Start Date: ,II, 11.'" o S-mL Purge 0 lO-mL Purge iii'" 2S-ml Purge Book#' A67-081
Matrix Instrument No. 67 Sample Data Sample
Prep lab Sample ID DF W Notes INITIAL CALIBRATION REFERENCE
File Name Amount S ID pH CI,
41'1.,~121 <2 < Sppm DATE
01 'R.rL...,'1 '1 11. f M ... 1 E " /' iiI. '. 1,1.j ICAllD V()(ilDl-~
02 iO L \I 0 t.-l DU", U" .-STANDARDS
VOIo'EI1L NAME ID Amount Cone.
03 'i{\ , lull 1m ,Ill
04 n_ ~ c.
o&1.{.,0 <';'\1\-"(\-, lr -U I
~
,..
DCC 1/~.f.. lIrA _ ~I_ 1'1./ -11"1_
OS il. R...I "'~~ Dec 4id4 ·41-f\·I)l I
06 tl./ \lnl,,'J;. Ii P> l.(",L Dec fA/tt<. -~1-1q-flJ I
07 <l( '_"'1=-\/)'1.1-1, ." 1.0 ./ / DCC Ch -41..-fl 1-0 I I
~L, -Lil -l(,,-() I \1!11A7J1
,
08 . It " / ./ BFB ,
~ 09 n -let ,.. /"
""
IS/SURR. -1.11-4.Q..oL ( ItO
l>
lev /lCS ,,~~ • 'tl-~~"O\ }. -I 10 'i''ii -).,0 /" / n / -"IJ.-O " ...ffI.
:::t 11 i'1 t,EII1-b\ "" Icv/le~.uJ -41-~~-{)\ \" " /"
~ 12 tid 1..J,E. it.O -11-,.. ./ / IT~" bOlt; -0 4-1." ICV/lCS 6!ti ·41-1}-([l} I I <:
~\ -61.. ;' ICV/lCS lh, ... -LlI-log-o, I I
~ 13 ,-
~ 14 ttl. -() I '" ,-/' ID~ Data File Folder 1.'>E11
~
15 q" -()~ / / ("")( LOTU Syringe Lot #
16 '14 ~ l\l\ ;' / pH strip H£.tID~;O tI\'; V -O~ ... (r"--l <I-I ~ 17 1\ • fI~ "" Chlorine strip 1.,"'1,0 1& I .. ~.,,-B-d2.'~ /'
18 &tin -0(' / / Methanol .J., _ tll--ol • Itt
19 6i'1 -01
--
I" /' NaHSO,
20 li -{)S '"
/' / '1-« t~l(? 1 'j)~F-l"'t Reagent Water I2..W\~~1.-f)l)l.j
21 tttf -Oq .--
r / <;'0", m 1(? J (mAlYi lC) Sand
22 400 -10 / / ,to Electronic Data Archival Location Date I---
23 en - \ I
,.-
/ ai? HPeHEM_ VOA/T067
I
01 ~02.n r 24 I / Comments: I ,
25 b, '-' -02.. \ ~ , / /
26 I b4 ~v 0 b11) lin II" l'i1.'
27 i O( I I 1 \'tot IIValuat/..J
28 I l11n L 1... .I o Refer to sample weight log
29 .{... b"l "2..1:'" (,f. Analyzed By: VL
30 ~ Date Disposed: ~lli:02 Disposed By: Vl-
( -. llt/z) REPORT ID: 23E120 Page 241 of 560
Page 43
ANALYSIS LOG FOR VOLATILES
SOP mEMAX-8260 Rev.No.!Q Gt'f'MAX-8260C Rev. No.! 0 EMAX-8260SIM Rev.No.! 0 EMAX-M8260SIM Rev.No. Q 0 EMAX-TCPSIM Rev.No. ~ 0 EMAX-624 Rev.No. § 0 EMAX-624.1 Rev.No. 1
Start Date: t; /I <if J L,) 0 S-mL Purge 0 lO-mL Purge Iil" 2S-mL Purge Book #. A67-081 -----------
Matrix Instrument No. 67 Sample Data Sample
Prep"
File Name Lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
Amount S 10 pH Ci,
< 2 <5nom DATE 4/2('/n
01 IRE.tl.\Oi P.:IF-&t.IEI tc ~ ilL.d' ICALID v Ot,1l:>2.r.:.
02 01 L\iDI..1 D1.(,r1 ,-STANDARDS
03 10 \Ill ""1'£1 'il L. NAME 10
Amount Cone.
/' lull Imo/ll
04 1\ J.. c.. ,. DCC ~;:.~
sVI· ~\.''l-DI _ 4,. qi.!..-o') "(-
05 11-Jl..IN'£ DCC ~fLt.UI . 4l-1'(":·111 , II
06 I~ Vb~J1 J:.1<t b / 1XWlL DCC IbAS -LtI-l'l-CJ1. ,
07 IY T1'J ;' DCC CAL -4.1. ·1)\ -I) l , I
08 I( nEOi'4-01 , i.e .-,-i\l, -iln(""-O'~ltj BFB -41-'/".-1\ I I l:flr11Ab(
IX! 09 1ft, 1.'') ED 4' - 0 \
I ,-./ T .. -/l/}/,,·b4·l-0 IS/SURR" ~ 41-4 I{ ./)"1-¢ \Ub I » -I 10 Ii 2:~E.oeti -0\ L ., / TR •• 1lf)1". hLl-l-O Icv/LCSj!~~
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; STANDARDS LOG FOR VOLATILES
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Page 66
STANDARDS LOG FOR VOLATILES
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Page 68
STANDARDS LOG FOR VOLATILES
Book No: SVl-36
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SV 1-36-68-01
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Page 27
STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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Book No: SVl-37
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Book No: SVl-37
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Book No: SVl-37
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REPORT ID: 23E120 Page 289 of 560
r Page 34
STANDARDS LOG FOR VOLATILES
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REPORT ID: 23E120 Page 290 of 560
I Page 35
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REPORT ID: 23E120 Page 291 of 560
I Page 36
STANDARDS LOG FOR VOLATILES
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REPORT ID: 23E120 Page 292 of 560
RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Gravimetric Certificate
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
• ISO 11034A .... edKed
R&fer&otW ,.,.bt~ldl PfoducQr
CQl'tific..lt& ;32220l
~ .. " ~ rACC'RED'IT'EDl
IsonEC 17025 Accredited
Testing lab3riltofy
CQrtifloto f 3222.02
Catalog No. : 556476 Lot No.: A0155119 6 VI-3D -64-00
Description: Custom 1.2.3-Trichloropropane-c.I5 Standard
Custom 1.2.3-Trichloropropane-d5 Standard 1,OOOll9/mL, P& T Methanol,
1mLlampui
Container Size: 2 mL Pkg Amt: > 1 mL ~~--------------------------------Expiration Date: November 30, 2022 Storage: O°C or colder
CERTIFIED VALUES
-. Compound' .. . - -
.---cGrav. Cont. - .
(weight/volume)
Expanded tlncertainty - - -
1,2,3-Trichloropropane-d5
CAS # 203578-27-2 (Lot PR-14307)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
."·:;~;t. 1-";j<~4
La':'e Klbe -Mix Technician Date Mixed: 15-Nov-2019
1,000.0 Ilg/mL
Balance: 1127510105
(95% C.L.; K=2)
+/-10.0737
+/-56.6693
+/-57.9677
Gravimetric
Unstressed
Stressed
Manufactured under Restek's ISO 9001 :2008
Registered Quality System
Certificate #FM 80397
Page 1 of2
REPORT ID: 23E120 Page 293 of 560
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/jJECD,
GC/MS, LC/MS, RI, and/or melting point.
• Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
Purity of isomeric compounds is reported as the sum of the isomers.
Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k U;ralJim.etric + U~om.ogeneity + U;torage stability + U;hipping stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
..-:-._.
label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
1DoC or colder (Refrigerate) <40°C ~ 40°C up to 7 days
DOC or colder (Freezer) < 25°C <:: 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
• Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
• Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
Page 2 of 2
REPORT ID: 23E120 Page 294 of 560
/' ;;:., RESTEK0 CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30224
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PlUOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0146953
Description : Toluene-d8 Standard
Toluene-dB 20001.lg/mL, P& T Methanol, 1 mUampul
Container Size: 2 mL ------------------Pkg Amt: > 1 mL -----------------Expiration Date: March 31, 2024 Storage: O°C or colder
~ ..
Ii'C'CREDIT'iD)
ISO 11034 Aeuedfted
Ref@TtoceMJtel!ilf'foductr
CMifICJteU22.2.01
'",~ a
IsonEC 17025 Accredited
resting Labor.lory
(Qrti1iate i3222.02
CERTIFIED VALUES
Compound
Toluene-d8
CAS # 2037-26-5
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
(Lot PR-30245)
Grav. Conc.
(weight/volume)
2,018.0 flg/mL
Expanded Uncertainty
(95% C.l.; K=2)
+/-11.8428
+/-113.1587
+/-115.8060
Gravimetric
Unstressed
Stressed
REPORT ID: 23E120 Page 295 of 560
Column:
105m x 0.53mm x 3.01lm
Rtx-502.2 «at.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ SOC/min. (hold 5 min.)
Inj. Temp:
200"C
Oet. Temp:
250"C
Oet. Type:
FID
M"YJ1'f W:";r
Maggie Wang -operations-"'r-eC-hn-'C-ian-'
~*' ~ -P.a;.1O'
Jennifer Pollino -Operations Tech·ARM QC
o 5 10 15
Minu1es
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 12-Mar-2019
Date Passed: 18-Mar-2019
Balance: 1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E120 Page 296 of 560
General Certified Reference Material Notes
Expiration Notes:
• Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
• Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
• Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/IJECD,
GC/MS, LC/MS, RI, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty. storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Uiravi-rnetric + U~omooeneit:y + U;t:oraoe stability + U;hippino stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
1Q°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
O°C or colder (Freezer) < 25°C ~ 25°C up to 7 days
• Separate (not combined) uncertainty values for graVimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product. when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampUl until the material is completely
dissolved.
REPORT ID: 23E120 Page 297 of 560
125 Ma rket Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Tel [phone]
Fax [phone]
www.AccuStandard.com
Catalog No: M-502C-04
Description: Volatile Organic Compounds
Lot: 218041438-01
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Component
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichloropropane
1,1-Dichloropropene
cis-1 ,3-Dichloropropene "
trans-l ,3-Dichloropropene "
Hexachlorobutadiene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
Trichloroethylene
1,2,3-Trichloropropane
.• Weight compensated to 100% purity.
H 47,8% cis isomer, 46,1% trans isomer
CAS#
96-12-8
106-93-4
107-06-2
78-87-5
142-28-9
563-58-6
10061-01-5
10061-02-6
87-68-3
630-20-6
79-34-5
19-00-5
79-01-6
96-18-4
5 V \~ ,0 ~o{-.."' l b
Date Certified: Jun 18,2020
Expiration: Jun 18, 2023
Sample Size: 1 mL
Components: 14
Storage Condition: Refrig (0-5 ·C)
Certified Reference Material
Purily % Prepared
Concentration'
(GC/MS) (!lg/mL)
95.8 2088'
99.9 2002
99.8 2001
99.5 2002
96.7 2069'
99.9 2001
93.9 2036'
93.9 1964'
98.0 2002
98.9 2001
96.0 2086'
98.6 2001
100.0 2002
97.5 2052'
Certified Analyte
Concentration'
(!lg/mL)
2000
2000
1997
1992
2001
1999
1912
1844
1962
1979
2003
1973
2002
2001
A product with a suffix (-1A. -26. etc. or -01, -02. etc.) on its lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 822-275872-11
, Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen using approximately a 95% confidence level.
Labels and certificates follow U.S. Conventions in reporting numerical values: A comma (.) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal place marker.
The information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Certified By:
Larry Decker, Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/lEe 17025 and certified to ISO 9001 :2015 QR-QRGIlNO-OOl
Rev. 5/18
REPORT ID: 23E120 Page 298 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers ANAB Certificate Number AR-1463
ISO/l EC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories ANAB Certificate Number AT-1339
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations Certificate Number 3774
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square rool of the total
variance of the uncertainty of the components using the following formula: lIa = II -+ 11(111)" + 11(1 ) -+ (II(R l) -his
formula represents uncertainty components from the mass, volume, short-term tability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims mllst hp. made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 299 of 560
·.);( .. Agilent ... Certificate of Analysis
Product Name: Haloalkanes Standard
Product Number: DWM-540-1 Lot Issue Date: 23-Dec-2019
Lot Number: 0006507491 Expiration Date: 31-Jan-2023
Description:
This analytical reference material (RM) was manufactured and verified in accordance with an ISO 9001 registered quality system,
and analyte concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the
95% confidence level for each analyte, determined gravimetrically, is listed below.
Analyte
bromochloromethane
bromodichloromethane
bromoform
bromomethane
carbon tetrachloride
chloroethane
chloroform
chloromethane
dibromochloromethane
1,2-dibromo-3-chloropropane
1 ,2-dibromoethane
dibromomethane
dichlorodifluoromethane
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethene
cis-1,2-dichloroethene
~
ACCREDITED
'8"ri!
REfERENCE MATEmAL
PROOUCER
ISO 17034 Cert No.
AR-1936
CAS# Analyte Lot
000074-97-5 RMOOO09
000075-27-4 RM12585
000075-25-2 RM07516
000074-83-9 RMOO064
000056-23-5 RM07576
000075-00-3 RMOO065
000067-66-3 RM13988
000074-87-3 RM12571
000124-48-1 RM13909
000096-12-8 RM11663
000106-93-4 RMOO018
000074-95-3 RM12878
000075-71-8 RM05289
000075-34-3 RM13775
000107-06-2 RM04655
000075-35-4 RM12062
000156-59-2 RM12063
RM was produced in accordance with TUV USA Inc registered ISO
9001 Quality Management System. Cert # 5610018560026
Page: 1 of 3
www.agilent.com/quality/
CSD-QA-015.1
Concentration ± Uncertainty
200.9 ± 1.0 iJg/mL
200.9 ± 1.0 iJg/mL
201.0 ± 1.0 iJg/mL
200.2 ± 1.0 IJg/mL
201.0 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.4 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 1J9/mL
200.9 ± 1.0 iJg/mL
200.8 ± 1.0 iJg/mL
200.8 ± 1.0 IJg/mL
200.6 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
201.0 ± 1.0 1J9/mL
200.9 ± 1.0 1J9/mL
~
ACCREDITED
1¥I'".ith&
TESTING l ABORATORV
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E120 Page 300 of 560
Certificate of Analysis
Product Number: DWM-540-1 Lot Number:
trans-1,2-dichloroethene 000156-60-5 RM07565
1,2-dichloropropane 000078-87-5 RM12821
1,3-dichloropropane 000142-28-9 RM09825
2,2-dichloropropane 000594-20-7 RM12927
1,1-dichloropropene 000563-58-6 RM15884
cis-1,3-dichloropropene 010061-01-5 RM12891
trans-1,3-dichloropropene 010061-02-6 RM12254
hexachlorobutadiene 000087-68-3 RM09157
methylene chloride 000075-09-2 RM11650
1,1,1,2-tetrachloroethane 000630-20-6 RM12632
1,1,2,2-tetrachloroethane 000079-34-5 NT00390
tetrach loroethene 000127-18-4 RM06491
1 ,1 , i-trichloroethane 000071-55-6 RMOO027
1,1,2-trichloroethane 000079-00-5 RM01175
lrichloroethene 000079-01-6 f-{MOOO29
trichlorofluoromethane 000075-69-4 RMOO017
1,2,3-trichloropropane 000096-18-4 RM09131
vinyl chloride 000075-01-4 RM05458
Matrix: methanol (methyl alcohol)
Storage Conditions: Store Frozen (-25° to -10°C).
Traceability:
0006507491
201.0 ± 1.0 IJg/mL
200.9 ± 1.01Jg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.7 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.6 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.9 ± 1.0 IJg/mL
200.8 ± 1.0 IJg/mL
201.0 ± 1.0 IJg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
~
ACCREDITED
-~-__ Wib.i§
A€F"EAENC£ MATERIAL
PRODUCER
ISO 17034 Cert No.
AR-1936
R~v1 v"as produced in accordance with TUV USA Inc registered iSO
9001 Quality Management System. Cert # 5610018560026
Page: 2 of 3
www.agilent.comfquaiityi
CSD-QA-015.1
~
ACCREOITED
--_._-LliiiGW&&
n,STlNG I ABORJ\TORY
ISO 17025 Cert
No. AT-1937
REPORT ID: 23E120 Page 301 of 560
•• : e' A "I .. }:~~.. gl ent ... Certificate of Analysis
Product Number: DWM-540-1 Lot Number: 0006507491
Homogeneity:
This RM was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is no minimum sub-sample
Intended Use:
This RM is intended for the preparation of working reference samples for use in routine laboratory analyses, calibration of
instruments, validation of analytical methods, assessments of measurement methods, and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above, provided the RM is handled and stored in accordance
with the instructions given in this certificate. This certification is nullified if the RM is damaged, contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
ACCREDITED -REFERENCE MA.TERIAL
PROOUCER
ISO 17034 Cert No.
AR-1936
RM was produced in accordance with TUV USA Inc registered ISO
9001 Quality Management System. Cert # 56100 18560026
Page: 3 of 3
www.agilent.comlqualityl
CSD-QA-015.i
Sample lot approver:
~Qo.lA2fORIO
Monica Bourgeois
QMS Representative
~
ACCREDITED
w"iin'(f
TESTING lABORATORY
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E120 Page 302 of 560
~ ~ .... RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30003
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description : VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,OOO~g/mL, P&T Methanol, 1mLlampui
Container Size: 2 mL ---------------------PkgAmt: ___ > __ 1_m_L __________ ___
Expiration Date: September 30, 2024 Storage: O°C or colder
~.
(ACC'REDIT"'iOI
ISO 11034 Aa:redfted.
Refer~ MltQllal Pfoducer
(QI1ifiQtQ Om.01
~.
(ACCiED".T]iiJ
ISOnEC 17021i Accredited
Testing ubofarory
Certif\ate-#322202
CERTIFIED VALUES
Compound
I-Bromo-4-fluorobenzene (BFB)
CAS # 460-00-4 (Lot 2040 1 KO)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Grav. Conc.
(weight/volume)
5,030.0 Ilg/mL
Expanded Uncertainty
(95% C.L.; K=2)
+/-29.5189
+/-'282.0557
+/-288.6541
Gravimetric
Unstressed
Stressed
REPORT ID: 23E120 Page 303 of 560
Column:
105m x 0.S3mm x 3.0~m
Rtx·502.2 (oat.#1091O)
Carrier Gas:
hydrogen-constant pressure 11,0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ 8'C/min. (hold 5 min.)
Inj. Temp:
200'C
Oet. Temp:
250'C
Oet. Type:
FID
Walker Workman -Operations Technician I
o 5 10 15 20 25 30
Minutes
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 27·Jun-2019
Date Passed: 0 I·Jul·20 19
Balance: 1128342314
Manufactured under Restek's ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E120 Page 304 of 560
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/IJECD,
GC/MS, LC/MS, RI, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetriC uncertainty, homogeneity between-ampUl uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Uiral1imetric + U~omoge71eity + U;torage stabiHty + U;hipping stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
• Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) <60°C ~ 60°C up to 7 days
10°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
O°C or colder (Freezer) <25°C ~ 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetriC uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampUl until the material is completely
dissolved.
REPORT ID: 23E120 Page 305 of 560
I Page 37
STANDARDS LOG FOR VOLATILES
Book No: SVl-37
I Parent ID Parent Standard Name Cone. Aliquot Final Cone.
tN1 /'?{) -u1-~", ( ~~;'''-LnL \.A-t 1-<W"'-o~ ~vt ~I?P"'"
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REPORT ID: 23E120 Page 306 of 560
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Book No: SVl-37
Standard ID SVl-37-38-01
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Prep. Date cr/W/ p.;f
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Prep. Date ~J~/"Lf
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Name ~(M~
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REPORT ID: 23E120 Page 307 of 560
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Page 39
Book No: SVl-37
Standard ID SVl-37-39-01
Name ~;'Y) ~S;
Final Volume cR,fJv'\.it.-L
MeOH Solvent 10 16vI1It---1)\ \ '()I-o""~
Prep. Date iJ01 ;1';J-/ )//
Exp. Date r"'7I,l.::}-I,..-v-
Prepared By eO
Syringe ID:
Comments:
Standard ID SVl-37-39-02
Name ~ ~h'<G
Final Volume d,(,~
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Prep. Date I)lfi2-7H1A
Exp. Date o 1,1 L-;rI2---~
Prepared By [;JO
Syringe ID:
Comments:
Standard ID SVl-37-39-03
Name eM l{f')
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Prep. Date CCtt~f",
Exp. Date O{?{jc,/1 .... 2.--
Prepared By 0-0
Syringe ID: ~ ,-yl-e;k..-"l.<> .... >
V f)i .... 0{' ..-(1
Comments:
REPORT ID: 23E120 Page 308 of 560
I
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Book No: SVl-37
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Book No: SVl-37
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Book No: SVl-37
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Book No: SVl-39
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STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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Book No: SVl-39
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Book No: SVl-39
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Book No: SVl-39
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Book No: SVl-39
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Book No: SVl-39
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Book No: SVl-39
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Page 44
STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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STANDARDS lOG FOR VOlATilES
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STANDARDS lOG FOR VOlATilES
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STANDARDS LOG FOR VOLATILES
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Page 69
STANDARDS lOG FOR VOlATilES
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STANDARDS LOG FOR VOLATILES
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STANDARDS LOG FOR VOLATILES
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Page 72
STANDARDS lOG FOR VOlATilES
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Page 83
STANDARDS LOG FOR VOLATILES
Book No: 5Vl-41
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Page 2
STANDARDS LOG FOR VOLATILES
Book No: SV1·42
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REPORT ID: 23E120 Page 478 of 560
Page 76
STANDARDS LOG FOR VOLATilES
Book No: SVl-41
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Page 86
STANDARDS LOG FOR VOLATILES
Book No' SVl-41
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Page 3
STANDARDS lOG FOR VOLATILES
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Page 65
STANDARDS LOG FOR VOLATILES
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REPORT ID: 23E120 Page 483 of 560
Page 73
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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REPORT ID: 23E120 Page 484 of 560
Page 68
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
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REPORT ID: 23E120 Page 485 of 560
,,{:PI
INTERNATIONAL
Date manufactured: 5/5/2022
Original issue date: 5/5/2022
Catalog No.: Lot No.: Storage:
Z-G34 481165 ::; -10 °C
-126047-01
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 5
Solvent:
prr Methanol
Expiration
Date:
6-Nov-2023
Description:
Custom Volatiles Mix, 73-6047, Various
Concentrations, 1 mL
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!lL
2-nitropropane 79-46-9 97.7 219.7.lP 1998 ± 110
allyl chloride 107-05-1 98.9 227.1.2P 1991 ± 120
benzene 71-43-2 99.99 146.1.9P 2003 ± 110
bromobenzene 108-86-1 100 147.7.IP 1999 ± 140
bromochloromethane 74-97-5 99.7 148.1.3P 2008 ± 110
bromodichloromethane 75-27-4 98.7 149.1.11P 1996 ± 110
bromoform 75-25-2 99.3 150.7.2P 1995 ± 110
n-buty Ibenzene 104-51-8 99.2 151.7.3.2P 1997 ± 110
sec-butylbenzene 135-98-8 99.5 152.1.2.lP 1999 ± 110
tert-butylbenzene 98-06-6 99.9 153.29.lP 1999 ± 110
carbon tetrachloride 56-23-5 100 154.9.IP 2005 ± 110
chlorobenzene 108-90-7 99.9 155.29.1P 2008 ± 110
2-chloroethanol 107-07-3 98.5 217.1.2.lP 2006 ± 120
chloroform 67-66-3 99.8 156.7.lP 1998 ± 110
chloroprene 126-99-8 98.9 315.5.22P 1982 ± 140
2-chlorotoluene 95-49-8 99.5 157.7.lP 2014 ± 110
4-chlorotoluene 106-43-4 99.9 158.9.3P 2015 ± 110
REPORT ID: 23E120 Page 486 of 560
Certificate of Analysis Page 2 of 5
Catalog No.: Z~G34~126047~Ol
cis-I,2-dichloroethylene
dibromochloromethane
1 ,2-dibromo-3-chloropropane
1,2-dibromoethane
dibromomethane
1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
cis-l,4-dichloro-2-butene
trans-I,4-dichloro-2-butene
I,I-dichloroethane
1,2-dichloroethane
I,I-dichloroethylene
trans-I,2-dichloroethylene
dichlorofluoromethanc (Freon 21)
1,2-dichloropropane
1,3-dichloropropane
2,2-dichloropropane
1,I-dichloropropylene
cis-I,3-dichloropropylene
trans-I,3-dichloropropylene
1 A-dioxane
ethyl ether
ethyl methacrylate
ethylbenzene
Manufactured By:
Bradley Richter
Production Chemist I
Lot No.: 481165
156-59-2 98.5
124-48-1 98.6
96-12-8 98.6
106-93-4 99.9
74-95-3 99.8
95-50-1 99.8
541-73-1 99.8
106-46-7 99.9
1476-11-5 98
110-57-6 98
75-34-3 98.1
107-06-2 99.9
75-35-4 99.98
156-60-5 99.7
75-43-4 98
78-87-5 99.7
142-28-9 100
594-20-7 99
563-58-6 99
10061-01-5 99.5
10061-02-6 99
123-91-1 99.93
60-29-7 99.8
97-63-2 99.5
100-41-4 100
Certified By:
Paul Johnson
Quality Control Supervisor
Expiration Date: 11/6/2023
166.1.7.1P 2000 ± 110
159.1.8.1P 2001 ± 110
160.7.2.3P 1996 ± 110
161.9.1P 1999 ± 110
162.1.2P 2012 ± 120
43.7.1P 2006 ± 110
44.1.2P 2008 ± 110
45.29.1P 2030 ± 110
209.1.5P 2003 ± 110
201.1.l7.IP 1996 ± 110
1 63.247.3.2P 1985 ± 120
164.158.1P 1999 ± 110
165.1.4P 2001 ± 110
167.9.IP 2000 ± 110
986.5.4P 1960 ± 140
168.8.IP 2002 ± 120
169.7.3P 2001 ± 140
170.l58.I.IP 1999 ± 120
I 71.158.2.4P 1998 ± 120
1 72.7.6.1 P 2001 ± 110
173.7.IIP 1988 ± 110
223.1.4P 39980 ± 2000
226.9.1P 1998 ± 110
216.7.IP 1993 ± 110
174.7.1P 2001 ± 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 487 of 560
Certificate of Analysis Page 3 of 5
Catalog No.: Z-G34-126047-01
hexachlorobutadiene
iodomcthane
isobutyl alcohol
isopropylbenzene
4-isopropyltoluene
methyl acrylonitrile
methyl methacrylate
methyl acrylate
methylene chloride
naphthalene
nitrobenzene
propionitrile
n-propylbcnzene
styrene
1,1,I,2-tetrachloroethane
1,1,2,2-tetrachloroethane
tetrachloroethylene
tetrahydrofuran (THF)
toluene
1,2,3-trichlorobenzene
1,2,4-trichlorobenzene
I,I,I-trichloroethane
1,I,2-trichloroethane
trichloroethylene
1,2,3-trichloropropane
Manufactured By:
Bradley Richter
Production Chemist I
Lot No.: 481165
87·68·3 98
74-88-4 99.9
78-83-1 100
98-82-8 99.9
99-87-6 99.9
126-98-7 98
80-62-6 99.8
96-33-3 98.5
75-09-2 99.99
91-20-3 99.8
98-95-3 100
107-12·0 99.8
103-65-1 99.7
100-42-5 99.5
630-20-6 99.8
79-34-5 99.4
127-18-4 100
109-99-9 99.99
108-88-3 100
87-61-6 99.8
120-82-1 99.6
71-55-6 99.6
79-00-5 99.6
79-01-6 100
96-18-4 99.5
Certified By:
Paul Johnson
Quality Control Supervisor
Expiration Date: 1116/2023
47.1 58.3.1P 2003 ± 120
203.29.2P 2000 ± 110
220.7.2P 40000 ± 2000
176.9.3P 2004 ± 110
I 77.9.3P 1988 ± 110
212.286.1.1P 20010 ± 1100
231.7.3P 2018 ± 120
349.7.IP 1999 ± 110
178.271.1P 2010 ± 110
26.9.IP 2020 ± 110
94.7.1P 1985 ± 110
218.7.3P 20000 ± 1000
179.7.2.2P 1998 ± 110
180.9.4P 2001 ± 110
181.7.2.9P 1997 ± 110
182.8.2P 1998 ± 120
183.1.2P 2001 ± 110
299.271.2P 2006 ± 110
I 84.48.lP 2003 ± 110
185.1.2P 1999 ± 110
54.29.lP 1987 ± 110
187.247.1.3P 1995 ± 110
195.7.1.6P 1999 ± 110
188.29.2P 2016 ± 110
I 89.1.3P 2001 ± 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 488 of 560
i>
Certificate of Analysis Page 4 of 5
Catalog No.: Z-G34-126047-01 Lot No.: 481165 Expiration Date: 1116/2023
1,1 ,2-trichloro-1 ,2,2-trifluoroethane (Freon 113) 76-\3.1 99 270.1 58.3P 1996 ± 120
1,2,4-trimethylbenzene 95-63-6 98.7 190.7.IP 1999 ± 110
1,3,5-trimethylbenzene 108-67-8 99.5 191.7.lP 2001 ± 110
m-xylene 108-38-3 99.7 193.7.1.2P 2001 ± 110
o-xylene 95-47-6 99 192.29.3P 1998 ± 120
p-xylene 106-42-3 99.9 194.7.IP 1999 ± 110
*Not 8 certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.0181n(x+31) + 0.1157) + 636.54i3.
202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Paul Johnson
Quality Control Supervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 489 of 560
Certificate of Analysis Page 5 of 5
Catalog No.: Z-G34-126047-01 Lot No.: 481165 Expiration Date: 1116/2023
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Ue = the combined uncertainty Ue = ~LUj2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Nov-2023
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Paul Johnson
Quality Control Supervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 490 of 560
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
CERTIFICATE OF ANALYSIS
Catalog No: OGAD-001
Description: Oxygenate Gasoline Additive Standard
Lot: 222011266
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Component
MtBE
EtBE
Isopropyl ether
TAME
t-Butanol
Signal Word: Danger
This Certified Reference Material was verified hi accordance with ISOIIEC 17025
CAS #
1634-04-4
637-92-3
108-20-3
994-05-8
75-65-0
Date Certified: Jan 19, 2022
Expiration: Jan 19, 2025
Sample Size: 1 mL
Components: 5
Storage Condition: Refrig (0-5 ·e)
Certified Reference Material
Purity % Prepared Certified Analyte
(GC/MS)
Conceritration' Concentration'
(H9linq (f./g/mL)
1997
2002
2010
1983
9965
A product with a suffix (-1A, -2B, etc. or -01, -02, etc.) on lis lot number has had Its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 684/289871-17
1 Certified Analyte Concentration" Purity x Prepared Concentration.
The Uncertainty associated with Ihe certlfledcoricentration reported on this certificate is ±2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square rool of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor' of K"2 Is chosen uslng,llPproxlniately a 95% confidence level.
Labels and certlijcates follow't;I,l)' Cohventlons in reporting numerical values: A comma (,) Is used to separate units of one-thousand or greater. A period (.) Is used as
a decimal place rharker. "
The Information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard Information: Pli~ase refer to the SOS for Information regarding the hazards associated with using this material.
This product was prepared according to In-house procedures and Is guaranteed to be homogeneous.
Certified By: ~ Larry Decker. Organic QC MBnager--------
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 QA·OAG/INO·OOl
Rev. 7120
REPORT ID: 23E120 Page 491 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the, front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: Us = .I(u(V»)2 + (u(m»2 + (u(IV»)2 + (u(Rb»2 I his
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 Is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 492 of 560
~PI
INTERNATIONAL
Date manufactured: 8/24/2022
Original issue date: 8/24/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • Date Received:
SIS Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-G34 492308 ::: -10°C
Date:
23-Aug-2027 2-Chloroethyl Vinyl Ether Solution, 2,000 mgIL, 1 mL
PIT Methanol
-020145-02
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (OC) or gas chromatograph/mass spectrometry (OC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
2-chlorocthylvinyl ether 110-75-8 99.8 145.I.SP 2010 ± 110
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCfMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N.!. S. T. Test No. 8221264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E120 Page 493 of 560
Certificate of Analysis
S¥("-38~o~~n./
Page 2 of 2
Catalog No.: Z-G34-020145-02 Lot No.: 492308 Expiration Date: 8/23/2027
(95% confidence) values listed are detennined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is detennined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perfonn daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025 :20 17 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
con finned by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kue : u==Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k==2, Ue == the combined uncertainty Ue == '\1L,U;2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short tenn and long tenn testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Aug-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Sanquetta Coakley
Production Chemist I
Certified By:
Dominique Lindner
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 494 of 560
125 Market Street
New Haven, CT 06513
USA
Catalog No: M-8010R-1-04-10X
Description: 1-Chlorohexane
Lot: 221031011
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Component
1-Chlorohexane
This Certified Reference Material was verified In accordance with ISO/IEC 17025
CAS#
544-10-5
Date Certified: Mar 3,2021
Expiration: Mar 3,2031
Sample Size: 1 mL
Components: 1
Storage Condition: Ambient (>5 'C)
Certified Reference Material
Purity % PrElpared Certified Analyte
Concentration' Concentration'
(GC/MS) (f.'g/mL) (f.'g/mL)
99.0 2020 2000
A product with a suffix (-1A, -2B, etc. or -01,-02, etc.) on,Us lot number has had Us expiration date extended and is identical to the same lot number without the suffix.
2 All weights are traceable through NIST, Test No. 684/289871-17
, Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty assoclatedwlththecertilied concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation ,equal to the po'sitive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen usln,9"approxlmately a 95% confidence level.
Labels and certificates follow,\;i.S, Conventions in reporting numerical values: A comma (,) Is used to separate units of one-thousand or greater. A period (.) Is used as
a deCimal place marker. '
The Information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information: Please refer to the SDS for Information regarding the hazards associated with using this material.
This product watprepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
~--q?--6---.­C----L-"?
---'~'.'~--.~-.--...... --.-~.-~-.-.-------.~.----Larry Decker, Organic.:: ac Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEe 1'7025 and certified to ISO 900'1:2015 QR-ORGfINO-OOl
Aov.7/20
REPORT ID: 23E120 Page 495 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification andlor
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: un = his
formula represents uncertainty components from the mass, volume, short-term lability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k:=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 496 of 560
CPI
INTERNATIONAL
Date manufactured: 6/24/2022
Original issue date: 6/24/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
Z-G34 484154 :S.1O °C PIT Methanol
Expiration
Date:
23-Jun-2027 1,2,3-Trimethylbenzene Solution, 2,500 mg/L, I mL
-020869-08
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
1,2,3-trimethylbenzene 526-73-8 92.7 869.8.4.lP 2536 ± 140
·Not a certified va1ue
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y'3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. 1. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E120 Page 497 of 560
Certificate of Analysis
bVlr~Og--l8
Page 2 of 2
Catalog No.: Z-G34-020869-08 Lot No.: 484154 Expiration Date: 6123/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty U c = ~IUj 2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Jun-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
Jared BaH
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 498 of 560
CPI
INTERNATIONAL
Date manufactured: 10/15/2020
Original issue date: 10/15/2020
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • Date Received:
SIS Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-G34 426643 :5 -10 Degrees
C
Pff Methanol
Date:
14-0ct-2025 t-Butyl Alcohol Solution, 50,000 mgIL, 1 mL
-020511-06
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
2-methyl-2-propanol 75-65-0 99.8 511.7.lP 49900 ±2500
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and A8TM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following;
% Change == (-0.018In(x+31) + 0.1157) + 636.54y'3.202
where x == boiling point of the most volatile analyte in the mix (degrees K)
y == boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E120 Page 499 of 560
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020232-1 0 Lot No.: 476834 Expiration Date: 3/6/2025
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02.QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOllEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty U c = --Jr,Uj2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Mar-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 500 of 560
/'" ~ ....
RESTEK CERTIFIED REFERENCE M~T~_RIA~ _____ "" __ . ~~
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30006
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative detennination of the analyte(s) listed.
Lot No.: A0183812
Description : VOA Calibration Mix #1
VOA Calibration Mix #1 5,000l1g/mL, P&T MethanollWater(90:10),
1mUampui
Container Size : 2 mL Pkg Amt: > 1 mL -------------------------------------------Expiration Date: July 31, 2025 Storage: DoC or colder
-----------------------Ship: Ambient
w...-MoI .... frodiKor
CodIfict«> tl2J.'l.Ol
C E R TI FIE 0 V A L U E S
, . Compound , ,Grav. C.onc. " E.xpanded Uncertainty _
• (weight/volume) (95% C.L.; K=2)
Acetone 5,031.8 Ilg/mL +/-29.2555 Ilg/mL Gravimetric
CAS# 67-64-1 (Lot SHBN3661 ) +/-303.5928 Ilg/mL Unstressed
Purity 99% +/-304.3136 Ilg/mL Stressed
2 2-Butanone (MEK) 5,041.0 !J.g/mL +/-29.3088 Ilg/mL Gravimetric
CAS # 78-93-3 (Lot SHBN2844) +1-304.1459 Ilg/mL Unstressed
Purity 99% +/-304.8680 Ilg /mL Stressed
3 4-Methyl-2-pentanone (MIBK) 5,041.5 Ilg/mL +1-29.3117 Ilg/mL Gravimetric
CAS# 108-10-1 (Lot SHBN3601) +/-304.1760 Ilg/mL Unstressed
Purity 99% +/-304.8982 Ilg/mL Stressed
4 2-Hexanone 5,026.8 Ilg/mL +1-29.2264 Ilg/mL Gravimetric
CAS# 591-78-6 (Lot MKCM4072) +1-303.2911 Ilg/mL Unstressed
Purity 99% +/-304.0112 Ilg/mL Stressed
Solvent: P&T MethanollWater (90: 10)
CAS # 67-56-117732-18-5
Purity 99%
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E120 Page 501 of 560
COhl~l1:
105m" O.S3mm x 3.0~m
Rtx-S02.2 (cat.#10910,
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
4O'C (hold 2 min., to l40'C
"rC/min. (hold 5 min.,
Inj. Temp:·
2OO'C
Bet. Temp:
250'C
BrttIany Federlnko -Operations Tech I
01-Aug-2020 rev.
o 5 10 15
Minutes
20 25 so
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific Instrument, method, and application.
Date MIxed: 07-Apr-2022
Date Passed: 1I-Apr-2022
Balance: B2S 1644995
Manufactured under Reatek'IISO 9001:2015
Registered Quality System
Certificate #FM 80397
2of3
REPORT ID: 23E120 Page 502 of 560
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-603-M-5X
Description: Acrolein & Acrylonitrile
Lot: 223021463
Date Certified: Feb 21,2023
Expiration: Jun 21, 2023
Sample Size: 1 mL
Components: 2
Tel [phone]
Fax [phone]
www.AccuStandard.com
Solvent: Methanol (90%)
Water (10%) Storage Condition: Freeze «-10°C)
Hazards: Refer to SDS for complete safety information
Certified Reference Material
Component
Acrolein
Acrylonitrile
Signal Word: Danger
CAS#
107-02-8
107-13-1
Purity' %
This Certified Reference Material was verified in accordance with ISO/IEC 17025 (AT-1339) and ISO 17034 (AR-1463)
• Weight compensated to 100% purity.
Prepared Certified Analyte
Concentration' Concentration'
(f1g/ml) (Mg/mL)
5808' '
5010
5001
5000
A product with a suffix (-lA, -2B, etc. or ,01, -02, eto.) on.its lot number has had Its expiration date extended and Is identical to the same lot number without the suffix.
, Certified Analyte Concentration = Purity x Prepared Concentration,
The Uncertainty associated with the certified concentration reported on this certificate Is ±2.4%, This value Is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components, A normal distribution is assumed and a coverage
factor of K=2 Is chosen using approximately a 95% confidence level.
'All weights are traceablethrough NIST,Test No. 684/291344-18 & 684/292805-19
, Purity/Identity determined by one or more of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and. certificates follow U.S. Conventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal place marker.
The Information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information.: Please refer to the SOS for Information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous,
Certified By:
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 QR-ORG/INO-OO1
Rev. 7/20
REPORT ID: 23E120 Page 503 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: un = U 1/ 111 1/ Ii his
formula represents uncertainty components from the mass, volume, short-term tability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 504 of 560
CPI"~
INTERNATIONAL
Date manufactured: 10/4/2022
Original issue date: 10/4/2022
Catalog No.: Lot No.: Storage:
Z-G34 489953 S -10°C
-020354-09
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 2
Solvent:
PIT Methanol
Expiration
Date:
3-0ct-2027
Description:
2-Butanol Solution, 50000 mg/L, 1 ml
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (aC) or gas chromatograph/mass spectrometry (aC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mf!fL
2-butanol 78-92-2 99.8 354.7.1P 50000 ± 2600
·Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.0181n(x+31) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point ofthe solvent (degrees K)
This model assumes the container is stored at _10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. 1. S. T. Test No. 822/264157-00. Concentration (correctfor purity) and uncertainty
REPORT ID: 23E120 Page 505 of 560
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020354-09 Lot No.: 489953 Expiration Date: 10/3/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025 :20 17 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025 :20 17 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, U c = the combined uncertainty U c = '/''Lu j
2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 3-0ct-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 506 of 560
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-08S-10X
Description: Cyclohexane
Lot: 219101390
Solvent: Methanol
Date Certified: Oct 25, 2019
Expiration: Oct 25, 2029
Sample Size: 1 mL
Components: 1
Tel [phone]Q
Fax [phone]
www.AccuStandard.com
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 DC)
Signal Word: Danger
Component CAS #
Cyclohexane 110-82-7
.' ",".'
":·h:~.
This Certified Reference Material was verified'\n'a~COrda~~Q'viith ISOIIEC 17025
Certified Reference Material
... r~-.r.'~:,'n .. ,
AR-1463
Purity %
(GG/MS)
100.0
Prllpared
ConcentrAtjon'
(~Mbl)
Certified Analyte
Concentration'
(j.Jg/mL)
2002
A product with a suffix (-1A, -2B, etc. Qr -01 ,:-02,eigyl)n1t~'lot number has had its expiration date extended and Is identical to the same lot number without the suffix.
'All weights are traceable through NIST, T~st Np,68412~9871-17
, Certified Analyte Concentration = Purity x prep'a!tid Concentration.
The Uncertainty associated wlth@i c';:rili:f~c;!:¢Srj(:entration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviatiQ!l~qu:al to !be pokHive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 is chosen usinli:approxtm~tely a 95% confidence level.
labels andcerlificates folloW\.J,S, c;onventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater, A period (.) is used as
a decimal place marker.' .,'.
The informatl~nAn th\~:·¢iirti(iq?te may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Informatloo.,J?Jease refer to the 50S for information regarding the hazards associated with using this material.
This product wa!f:~r!ipared according to in-house procedures and Is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic OC Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 OR-ORGIINCJ.OOl
Rs .... 7/20
REPORT ID: 23E120 Page 507 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
S-Vl-b~-o1-n
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua == .I(u(Y»2 + (u(m»)2 + (u(ly»)2 + (u(RO»)2 I his
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and limit of liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 508 of 560
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
S\I\-~y .. 'O-OI..
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-09S-12.5X
Description: Methylcyclohexane
Lot: 222081023
Solvent: Methanol
Date Certified: Aug 2, 2022
Expiration: Aug 2, 2032
Sample Size: 1 mL
Components: 1
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 ·C)
Signal Word: Danger
Component CAS#
Methylcyclohexane 108-87-2
This Certified Reference Material was verilied in accordance with ISOIIEC 17025
Certified Reference Material
Purity %
(GC/FID)
100.0
~tepared
Concentration'
J!19 /mL l
2538
Certified Analyte
Concentration'
(Hg/mL)
2538
A product with a suffix (-1A. -2B. etc. or -01, -02, etc.) 60 Its lot number has had Its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 684/289871-17
, Certified Analyte Concentration" Purity xPrepaied Concentration.
The Uncertainty associated' with lhe certified concentration reported on this certificate is ±2.4'10. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen uslngapproxlrl1ately a 95% confidence level.
Labels and certificates follow U.S" Conventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal place marker,. .
The information.on this'certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard Information: PI~ase iefer to the SDS for information regarding the hazards associated with using this material.
This product was pr~pared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 QR·ORGilNO·OO1
Rev. 7/20
REPORT ID: 23E120 Page 509 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is deSigned for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .f(u(Y»)2 + (uCm»)! + (uClv))2 + (u(RO»)2 This
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. legal Notice and Limit of liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 510 of 560
125 Marke1 Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
~ V\--?q -lo·~04
CERTIFICATE OF ANALYSIS
Catalog No: S-6524-0.25X
Description: Methyl acetate
Lot: 222031007
Solvent: Methanol
Date Certified: Mar 2, 2022
Expiration: Mar 2, 2032
Sample Size: 1 mL
Components: 1
Hazards: Refer to SOS for complete safety information Storage Condition: Ambient (>5 ·C)
Signal Word: Danger
Component CAS #
Methyl acetate 79-20-9
This Certified Reference Material was verified in accordance with ISOIIEC 17025
Certified Reference Material
Purity %
(GC/MS)
100.0
Prepared
Conceritratl.on'
··(WJIn'lL)
Certified Analyte
Concentration'
(fl9 /mL)
2520
A product with a suffix (-1A, -28, etc. Of -01, -02, etc.) on Us lot number has had its expiration date extended and is identical to the same lot number without the suffix.
, All weights are traceable through NIST, Test No. 6841289871-17
\ Certified Analyte Concentration = PUrity x Prepared Concentration.
The Uncertainty associated. With the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to :the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen uslngapproxtrnately a 95% confidence level.
Labels and certificates folloW\.i.s.Conventions in reporting numerical values: A comma (.) is use'd to separate units of one-thousand or greater. A period·(.) is used as
a decimal place marker. ..
The information.()n this eaitlfi.cate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information; Please refer to the SDS for information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic ac Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/lEe 17025 and certified to ISO 9001 :2015 QR·ORGlINO·OO1
Rev. 7120
.J
REPORT ID: 23E120 Page 511 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = ./{u(V»2 + {u(m))2 + {u(JV))2 + {u(RO»2 This
formula represents uncertainty components from the mass, volume, short-term dtability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and LImit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 512 of 560
CPI
INTERNATIONAL
Date manufactured: 3/2/2022
Original issue date: 3/212022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Analysis
Solvent:
Date Received:
Page 1 of 2 Rev 0
Description:
Z-G34 476834 :S -10 °C PIT Methanol
Expiration
Date:
6-Mar-2025 Vinyl Acetate Solution, 2,500 mg/L, 1 mL
-020232-10
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (OC) or gas chromatograph/mass spectrometry (OCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mf!/L
vinyl acetate 108-05-4 99.9 232.7.lP 2500 ± 160
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54i3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at _10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N.!. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E120 Page 513 of 560
S'VI-3~~o~"'lq
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020232-10 Lot No.: 476834 Expiration Date: 3/6/2025
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIlEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-Oll. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u==ku c : u==Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty U c == ~I,u; 2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Mar-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 514 of 560
REPORT ID: 23E120 Page 515 of 560
,(> f)
.o~~:~ .. Agilent
" a '1-
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~~~-~~';;;,." .. . ..... :':
-";,.;'/"~) ..... hH:n;:;;, ... ~-~hi.s-YJ'~>;,;"'N:',U;';'''),I';#'h';.7N;.r;~J',F;;;';";J''':''PI';;;;;:,/,,·j.f';JjJ/i;-;>;X;/J;~>N''''''''';~·;''~J'';~>},:;U""J./.P.J').r/h'):r;./J-;/;;'"J;;".N;;:";#;;;"'N~"'-";;;n~jj;~·>; .. ;.,;,,~;'"';:U~;JJ-I';"'N.I;,;;.,..;,;..",-;;;/;. ... ,.~:.,,,,;;';,>;,-,;,,';;':';;.iJ-,~:
~~~.~J!,~~~~;ii-;,~;:~';i~!ii;iiil:I;::'.I.:?')!'!
ACCA[;DITED .. ~,., .. -,-~.-.---~-
r\l:rrfll~NC" MArUUAl,
i>UOl)UCf.H
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV/SUD registered ISO
9001 :2015 Quality Management System. Cert# 951215321
Page: 2 of 2
www.agilent.com/quality/
CSD-QA-015.1
Sample lot approver:
~C('f1)~Ul
Monica Bourgeois
01\115 Representative
ISO 17025
REPORT ID: 23E120 Page 516 of 560
CPI
Date manufactured: 515/2022
Original issue date: 515/2022
Catalog No.: Lot No.: Storage:
Z-G34 481102 :S -10°C
-020200-04
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
PIT Methanol
Expiration
Date:
4-May-2027 Carbon Disulfide Solution, 5,000 mg/L, 1 ml
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ID!!fL
carbon disulfide 75-15-0 99.9 200.24.IP 5044 ± 250
·Not a certitied value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCIMS. It may aslo be used for various US EPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for·
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at _10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 8221264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E120 Page 517 of 560
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020200-04 Lot No.: 481102 Expiration Date: 5/412027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty Uc = --JIuj
2 where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 4-May-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Paul Johnson
Quality Control SUpervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 518 of 560
/ ~ ....
RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30631
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0183952
~MoIOIIiI"")dUc"
CoilIIIat.t32l201
IS05C 1702$ Aoaediled
Tos\iIlg~atory
~132Wl2
Description : tert-Amyl Alcohol Standard SVt-3~-D)'-f]
Tert-Amyl Alcohol 10, OOOjJg/mL, P& T Methanol, 1 mLiampul
Container Size: 2 mL ~~---------------Expiration Date: April 30, 2027 ------------------
Compound
tert-Amyl alcohol
CAS # 75-85-4 (Lot STBB I 898V)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Pkg Amt: > 1 mL ----~-----------Storage: O·G or colder
Ship: Ambient
CERTIFIED VALUES
-
Grav. Conc.
(weight/volume)
10,010.0 flg/mL
Expanded Uncertainty
(95% C.L.; K=2)
+1-92.6344
+1-226.1085
+1-232.0226
flg/mL
flg /mL
flg/mL
Gravimetric
Unstressed
Stressed
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E120 Page 519 of 560
Column:
105m x 0.53mm x 3.01lm
Rtx·502.2 (cat.#10910)
CanierGas:
hydrogen-constant pressure 11.0 psi.
Temp, Program:
4O'C (hQld 2 min.) to 24O'C
@ S·C/mln. (hold 5 min.)
Inl. Temp:
200'C
DeL Temp:
25O'C
Det. Type:
FlO
Whitney Bennett· Operation Tech I
Christie MUIs • Operations Technician n
o 1-Aug-;!020 rev.
o 5 10 15
Minutes
20 25 so
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 12·Apr·2022
Date Passed: 13-Apr.2011
Balance: 1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality Syelem
Certificate #I'M 80397
20f3
REPORT ID: 23E120 Page 520 of 560
125 Market Street
New Haven. CT 06513
USA ~ AccuStandard®
~ -?]'t '.'-61.-\ -r:3-
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-04S-1OX
Description: Isooctane
Lot: 221031139
Solvent: Methanol
Date Certified: Mar 11, 2021
Expiration: Mar 11, 2031
Sample Size: 1 mL
Components: 1
Tel [phone]
Fax [phone]
www.AccuStandard.com
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 ·C)
~~~ Certified Reference Material
Signal Word: Danger
Component CAS # Purity % Prepared Certified Analyte
Concentration' Concentration'
(GC/MS) (lJglmL) (fJg/mL)
Isooctane 540-84-1 99.4 2001 1989
2-)2) ~_ 'f'(\'~~ ~
.D '}leo 'It ( 1-..,... O')J
A product with a suffix (-1A. -2B. etc. or -01. -02. etc.) on Its lot number has had Its expiration date extended and Is Identical to the same lot number without the suffix.
2 All weights ere traceable through NIST. Test No. 684/289871-17
, Certified Analyte Concentration" Purity. x Prepared Concentration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2,4'10. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to t/)e positive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 Is chosen uSi.tig approximately a 95% confidence level.
Labels and certificates follow·U.S.COnventions In reporting numerical values: A comma (.) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal pJaclimark~r;
The Information. on this'certlflcate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard InformatJon: Please refer to the SOS for Information regarding the hazards associated with using this material.
This product was prepared according to In-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Daoker, Organlo ac Manager
Page 1 of 1 For use In routine laboratory analysiS.
AccuStandard is accredited to ISO 17034, iSOIlEe 17025 and certified to ISO 9001 :2015 QR·ORGlINO·OOI
Rev. 7/20
REPORT ID: 23E120 Page 521 of 560
/ ~" RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30003
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description: VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,000~g/mL, P&T Methanol, 1mLlampui
Container Size: 2 mL ~~--------------Pkg Amt: > 1 mL ----~-----------Expiration Date: September 30, 2024 Storage: O°C or colder
~ •..... \ .. ;.
~"
f@EDlT]o)
ISO tlIl34·At<redHed.
R&fQreotQ ~tQlIOlI PtoducClr
CQl1ifla.IQ'~22l.0~
d
IsonEC 17025 Ac .. edlted
ToItlI'l911borarory
Cor1iliot .. 32l2.02
CERTIFIED VALUES
'. Compound
I-Bromo-4-fluorobenzene (BFB)
CAS # 460-00-4 (Lot 20401 KO)
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Grav. Cone.
(weight/volume)
5,030.0 I!gfmL
Expanded Uncertainty
(95% C.L.; K:;;:2)
+f-29.5189
+/-'282.0557
+f-288.6541
I!gfmL
J.lgfmL
J.lgfmL
Gravimetric
Unstressed
Stressed
REPORT ID: 23E120 Page 522 of 560
Column:
105m x 0.53mm x 3.0~m
Rtx·S02.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ SOC/min. (hold 5 min.)
Inj. Temp:
200"C
Oet. Temp:
250"C
Oet. Type:
flO
Walker Workman· OperatJons Technician I
5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 27·Jun·2019
Date Passed: 01.Jul-2019
Balance: 1128342314
Manufactured under Restek'$ ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E120 Page 523 of 560
cpr
INTERNATIONAL
Date manufactured: 7/1312022
Original issue date: 7113/2022
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Analysis Date Received:
Page 1 of 2 Rev 0
Catalog No.: Lot No.: Storage: Solvent: Expiration
Date:
12-Jul-2027
Description:
Z-G34 484785
-122455-05
Certified Values:
prr Methanol Method 8260 Internal Standard Mix, 3·30,2,500
rng/L, 1 ml
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mg/L
chlorobenzene-d5 3114-55-4 99.5 128.120.1P 2504 :J: 130
1,2-dichlorobenzene-d. 2199-69-1 99.7 247. 29.3P 2514 ± 130
1,4-difluorobenzene 540-36-3 99.3 129.158.1.2P 2523 ± 140
'Not. certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change"" (-0.018ln(x+31) + 0.1157) + 636.54i3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °c and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
REPORT ID: 23E120 Page 524 of 560
Certificate of Analysis
)\11--:,ff-01-((,
Page 2 of 2
Catalog No.: Z-G34-122455-05 Lot No.: 484785 Expiration Date: 7/12/2027
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are detennined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is detennined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consfstent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kue : u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, U e = the combined uncertainty U e = -iI,u/ where Uj are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability ofthis product is based upon rigorous short tenn and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 12-Jul-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E120 Page 525 of 560
~ ..
RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30240
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic plus
sv I ~J~ ~ 10-\1-
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative andlor quantitative determination of the analyte(s) listed.
Lot No.: A0192204
Description : 8260A Surrogate Mix
8260A Surrogate Mix 2,500f-lg/mL, P&T Methanol, 1mUampui
Container Size : 2 mL --------------------PkgAmt: __ >_1 __ m_L __________ __
Expiration Date: December 31,2027 Storage: O°C or colder
Ship: Ambient
CERTIFIED VALUES
Expanded
. Elution - _ Compound CAS # Lot # Purity Grav. Cone. Uncertainty *
Order . (weight/volume) (95% C.L., K=2)
Dibromofluoromethane 1868-53-7 022013 99% 2,517.6 IlglmL +/-141.4279
2 1,2-Dichloroethane-d4 17060-07-0 PR-32845 99% 2,507.6 Ilg/mL +/-140.8661
3 Toluene-d8 2037-26-5 1-27008 99% 2,511.4 IlglmL +/-141.0796
4 I-Bromo-4-iluorobenzene (BFB) 460-00-4 184975 99% 2,517.8 Ilg/mL +/-141.4391
* Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
.-..
01-Nov-2022 rev. RESTEK 10f3
REPORT ID: 23E120 Page 526 of 560
Column:
105m x O.53mm x 3.0~m
Rtx·502.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 pSi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ SOC/min. (hold 5 min.)
Inj. Temp:
2oo"c
Det. Temp:
250"C
Det. Type:
FlO
Split Vent:
40ml/min
Inj. Vol
1111
f;~d t{ltt(.
Daniel Wasson· Operations Tech I
Chrislie Mills· Operations Tech II· ARM QC
01-Nov-2022 rev.
o
Quality Confirmation Test
5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
_____ acG.m)l<lJJce.~or .QJilimal results in your.1ah.-cooditions..shouJdbaadjusted for your
specific instrument, method, and application.
Date Mixed: 02-Doc-2022 Balance Serial #
Date Passed: 06-Doo-2022
1128342314
Manufactured under Restek's ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
2013
REPORT ID: 23E120 Page 527 of 560
~ .....
RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 575702
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0191824
Description: Custom Revised 8260 Megamix
Custom Revised 8260 Megamix 2,000 -40,000~g/mL, P& T Methanol,
1mUampul
Container Size : 2 mL ~~---------------
Pkg Amt: _>_1.:...:..:.m:;;L~ ____ _
Expiration Date: November 30,2025 Storage: O°C or colder
Ship: Ambient
D
15011134,....._'"
~MReNlPicduceJ
C~J.J22lhI
CERTIFIED VALUES
--'--" _c.. .• ' -" __ • -... ' . ._'_ " ~.' ,;.~. • " Expanded
Elution Compound CAS # . Lot # Purity Grav. Cone. Uncertainly'
Order
I I (weight/volume) (95% C.L.; K=2)
Dichlorofluoromethane (CFC-21) 75-43-4 12841600 99% 2,000.0 !1g/mL +/-69.1292
2 Dielhyl cther (ethyl ether) 60-29-7 SHBP5008 99% 2,011.0 !1g/mL +/-69.5094
3 1,1 ,2-Trichlorotrifluoroethane (CFC-113) 76-13-1 00016133 99% 2,008.0 !1g/mL +/-69.4057
4 I,I-dichloroethene 75-35-4 SHBG8609V 99% 2,001.6 !1g /mL +/-69.9029
5 Iodomethane (methyl iodide) 74-88-4 RD220125 99% 2,007.5 !1g/mL +/-69.3884
6 Allyl chloride ( 3-chloropropene ) 107-05-1 RP220405A 99% 2,011.0 I1g/mL +/-69.5094
7 Methylene chloride (dichloromethanc) 75-09-2 SHBPI417 99% 2,001.6 flg/mL +1-69.9056
8 trans-I,2-Dichloroethene 156-60-5 MKBH9850V 99% 2,001.7 flg/mL +1-69.9064
9 I,I-Dichloroethane 75-34-3 760200 99% 2,001.1 flg /mL +/-69.8864
10 Chloroprene (2-chloro-1 ,3-butadiene) 126-99-8 220712JLM 99% 2,014.0 I1g /mL +/-69.6131
11 Propionitrile 107-12-0 BCCF4167 99% 20,009.5 !1g/mL +1-691.5748
12 2,2-Dichloropropane 594-20-7 RD220812 99% 2,004.3 I1g/mL +/-70.0110
13 cis-I,2-Dichloroethene 156-59-2 MKCP7830 99% 2,014.0 flg/mL +/-70.3516
14 Methacrylonitrile 126-98-7 1012014 99% 20,031.5 l1g!mL +/-692.3351
15 Methyl acrylate 96-33-3 SHBG66l6V 99% 2,007.0 flg/mL +/-69.3711
16 Isobutanol (2-Methyl-l-propanol) 78-83-1 SHBP7066 99% 40,013.5 flg!mL +/-1,382.9594
.,..--."..,
01-Nov-2022 rev. RESTEK 1of5
REPORT ID: 23E120 Page 528 of 560
17 chloroform
18 Bromochloromethane
19 Tetrahydrofuran
20 1,1, I-trichloroethane
21 I,I-Dichloropropene
22 carbon tetrachloride
23 1,2-Dichloroethane
24 Benzene
25 2-Ch1oroethanol
26 Trichloroethene
27 1,2-Dichloropropane
28 Methyl methacrylate
29 bromodich1oromethane
30 1,4-Dioxane
31 2-Nitropropane
32 Dibromomethane
33 cis-I ,3-Dichloropro~ ..• '.'
34 Toluene
35 Ethyl methacrylate
36 trans-I,3-Dichloropropene
37 I, I ,2-Trichloroethane
38 1,3-Dichloropropane
39 Tetrachloroethene
40 dibrornochloromethane
41 1,2-Dibromoethane (EDB)
42 ChIorobenzene
43 1.1 , 1 ,2-Tetrachloroethane
44 Ethylbenzcne
45 rn-Xylene
46 p-Xylene
47 o-Xylene
48 Styrene
49 Isopropylbenzene (curnene)
50 bromoform
51 cis-l ,4-Dichloro-2-butene
52 1,1,2,2-Tetrachloroethane
o 1-Nov-2022 rev.
67-66-3 SHBN8469
74-97-5 00008541
109-99-9 SHBP0039
71-55-6 RD220613
563-58-6 220617JLM
56-23-5 SHBL8097
107-06-2 MKCN9758
71-43-2 MKCQ2104
107-07-3 RD220606A
79-01-6 SHBN3720
78-87-5 BCBR0882V
80-62-6 MKCQ2755
75-27-4 MKCF8470
123-91-1 SHBP8653
79-46-9 BCCB9352
74-95-3 10233302
10061-01-5 RD220311
108-88-3 ED097-US
97-63-2 MKCN6206
10061-02-6 RD220816
79-00-5 FGBOI
142-28-9 BCCB9817
127-18-4 SHBJ7422
124-48-1 MKCM8659
106-93-4 BCCF5058
108-90-7 SHBN6640
630-20-6 GCOI
100-41-4 094632L21G
108-38-3 SHBN6673
106-42-3 10234437
95-47-6 SHBN5105
100-42-5 MKCQ3390
98-82-8 Z20D022
75-25-2 MKCR0680
1476-11-5 RD220907
79-34-5 OXACF
99% 2,002.3 IlglmL
99% 2,011.9 IlglmL
99% 2,005.0 IlglmL
98% 2,001.2 IlglmL
99% 2,014.0 Ilg/mL
99% 2,000.1 IlglmL
99% 2,001.6 IlglmL
99% 2,010.5 IlglmL
99% 2,002.5 IlglmL
99% 2,001.6 IlglmL
99% 2,001.8 Ilg/mL
99% 2,007.5 IlglmL
99% 2,001.7 IlglmL
99% 40,041.0 IlglmL
97% 2,003.5 IlglmL
99% 2,013.0 Ilg/mL
99% 2,001.9 IlglmL
99% 2,011.4 IlglmL
97% 2,004.0 IlglmL
·99% 2,000.5 IlglmL
99% 2,001.9 IlglmL
99% 2,011.1 IlglmL
99% 2,001.2 IlglmL
99% 2,002.2 IlglmL
99% 2,006.0 IlglmL
99% 2,000.1 IlglmL
99% 2,009.8 IlglmL
99% 2,016.4 IlglmL
98% 2,012.6 IlglmL
99% 2,009.1 Ilg/mL
98% 2,010.1 IlglmL
99% 2,012.6 IlglmL
99% 2,009.3 IlglmL
99% 2,000.8 1lg/mL
97% 2,000.0 IlglmL
99% 2,002.8 IlglmL
+/-69.9291
+/-70.2782
+/-69.3020
+/-69.8893
+/-70.3498
+/-69.8514
+/-69.9056
+/-70.2293
+/-69.2156
+/-69.9047
+/-69.9125
+/-69.3884
+/-69.9082
+/-1,383;9099
+1-69.2514
+/-70.3149
+/-69.9152
+/-70.2608·
+/-69.26.8l .. • •.
+/-. 69.86ii\
+/-70.2485
+/-69.8890
+/-69.9256
+/-70;0704
+/-69.8506
+/-70.2031
+/-70.4337
+/-70.3019
+/-70.1787
+/-70.2163
+/-70.3027
+/-70.1874
+/-69.8750
+/-69.1290
+/-69.9466
2of5
REPORT ID: 23E120 Page 529 of 560
53 1,2,3-Trichloropropane 96-18-4 332900 99% 2,010.3 !!g/mL +/-70.2206
54 trans-l ,4-dichloro-2-butene 110-57-6 RD220921 RSR 94% 1,999.9 !!g/mL +/-69.1240
55 n-Propylbenzene 103-65-1 MKCNll26 99% 2,009.1 !!g/mL +/-70.1804
56 Bromobenzene 108-86-1 WXBCS147V 99% 2,012.S Ilg/mL +/-70.2992
57 1,3,5-Trimethylbenzene 108-67-8 BCCF4166 99% 2,010.8 !!g/mL +/-70.2381
58 2-Chlorotolucne 9S-49-8 MKCFS243 99% 2,007.S Ilg/mL +/-70.1228
59 4-Chlorotoluene 106-43-4 MKCC8496 99% 2,012.4 !!g/mL +/-70.2957
60 tert-Butylbenzene 98-06-6 STBJl937 99% 2,009.0 !!g/mL +1-70.1769
61 1,2,4-Trimethylbenzene 95-63-6 WXBC9428V 98% 2,004.8 !!g/mL +1-70.0297
62 sec-Butylbenzene 135-98-8 MKCP2266 99% 2,009.2 !!g/mL +/-70.1839
63 p-Isopropyitoluene (p-Cymene) 99-87-6 MKCR6143 99% 2,007.6 !!g/mL +1-70.1280
64 1,3-Dichlorobenzene 541-73-1 BCCD5315 99% 2,000.7 !!g/mL +/-69.8715
65 I A-Dichlorobenzene 106-46-7 MKBS4401V 99% 2,002.0 !!g/mL +/-69.9195
66 n-Butylbenzene 104-51-8 09804AE 99% 2,006.9 !!g/mL +1-70.1036
67 1,2-Dichlorobenzene 95-50-1 SHBN3835 99% 2,001.2 !!g/mL +1-69.8898
68 1,2-Dibromo-3-chloropropane 96-12-8 HBMVB 97% 2,006.3 !!g/mL +1-70.0843
69 Nitrobenzene 98-9S-3 10224044 99% 2,004.0 !!g/mL +1-69.2674
70 1,2,4-Trichlorobenzene 120-82-1 SHBM0526 99% 2,009.7 !!g/mL +1-70.1996
71 Hexachlorobutadiene 87-68-3 X05J 99% 2,007.4 f.1g/mL +1-70.1210
72 Naphthalene 91-20-3 MKCH0219 99% 2,001.5 !!g/mL +1-69.9132
73 1,2,3-Trichlorobenzene 87-61-6 MKBX7627V 99% 2,015.7 !!glmL +1-70.4092
.. Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
01-Nov-2022 rev.
3 of 5
REPORT ID: 23E120 Page 530 of 560
Column:
60m x O.2Smm x L4"",
Rtx-S02.2 (cat.#10916)
Carrier Gas:
hellum-constant pressure 30 psi
Temp. Program:
4O"C (hold 6 min.) to 240"C
@ 6"C/mln. (hold 10 min.)
Inj. Temp:
200'C
Det. Temp:
2S0'C
Det. Type:
MSO
Split Vent:
20.0 ml/min.
Inj. Vol
1111
Cathleen Soltis -Mix Technlcl ....
JennIlerPoIIino • Operations Tech III· ARM QC
01-Nov-2022 rev.
Quality Confirmation Test
I '16"17 29.30.31 45.46
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: l8-Nov-2022 Balance Serial #
Date Passed: 05-Dee-2022
B251644995
Manufactured under Restek's ISO 9001 :2015
Registered Quality System
Certificate #FM 80397
40f5
REPORT ID: 23E120 Page 531 of 560
~ ....
IlESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30465
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative andlor quantitative determination of the analyte(s) listed.
Lot No.: A0164741
Description : California Oxygenates Mixture #1
California Oxygenates Mixture #1 2000-10000IJg/mL, P& T Methanol,
1mUampui
Container Size: 2 mL ------------------Pkg Amt: > 1 mL -----------------Expiration Date: September 30, 2025 Storage: O°C or colder
Ship: Ambient
~:,
fA'§iEDIT"iDl
180110)4 _edited
ReforEil<4 MolO1I.ll'Iod.,,,
CMifK;at& .3222.0\
. " "~'~'" , a
ISOAEC 17025 Aocrodilod
Testing Ub"ntoty
Cerlifiote #3222.02
CERTIFIED VALUES
. r l!l"i ~-:G(C\v.,CO"lc. ,-. • .. '
.. , (weight/volume)
", ... ~.E.lUland(lJI Unce,rtainty< _ " , ... k\,~,"! _ .
(95% C.L.; K=2)
tert-Butanol (TBA) 10,033.6 J.lg/mL +/-58.7489 Jlg/mL Gravimetric
CAS # 75-65-0 (Lot SHBL5806) +/-214.9330 Jlg/mL Unstressed
Purity 99% +1-221.1750 Jlg/mL Stressed
2 Methyl-tert-butyl ether ( MTBE ) 2,000.0 Jlg/mL +/-11.7371 Jlg/mL Gravimetric
CAS# 1634-04-4 (Lot SHBL0822) +/-42.8500 Jlg/mL Unstressed
Purity 99% +/-44.0940 Jlg/mL Stressed
3 Diisopropyl ether ( DIPE ) 2,006.0 Jlg/mL +/-11.7723 Jlg/mL Gravimetric
CAS # 108-20-3 (Lot SHBHI927V) +/-42.9785 Jlg/mL Unstressed
Purity 99% +/-44.2263 Jlg/mL Stressed
4 Ethyl-tert-butyl ether (ETBE) 2,017.6 Jlg/mL +/-11.8404 Jlg/mL Gravimetric
CAS# 637-92-3 (Lot MKCM3774) +/-43.2270 Jlg/mL Unstressed
Purity 99% +/-44.4820 Jlg/mL Stressed
5 lert-Amyl methyl ether (TAME) 2,009.2 Jlg/mL +1-11.7911 Jlg/mL Gravimetric
CAS# 994-05-8 (Lot HMBG7745V) +/-43.0471 Jlg/mL Unstressed
Purity 99% +/-44.2968 Jlg/mL Stressed
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E120 Page 532 of 560
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
Column:
105m x 0.S3mm x 3.0~m
Rlx-502.2 (cal.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi,
Temp. Program:
40'C (hold 2 min.) 10 240'C
@S'C/min. (hold 5 min.)
inj. Temp:
200'C
Det. Temp:
250'C
Oet. Type:
FID
WalkerWornman· Operations Technician I
£~~_ ,1--.~ .<:::}}V~1((QI-.:iQ'C--....
,JUIiI1I,". Alba,u;on .Oporallonll Tueh.ARM QC
'~~.-'
01-Aug-2020 rev.
5 10 15 20
Minutes
This chromatogram represents a general set of testing conditions chosen for product
Fl(:r~flrtrmr.fl. Fnr nrtim<11 results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 24-Sep-2020
Date Passed: 27-Scp-2020
Balance: 1128360905
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2 of 3
REPORT ID: 23E120 Page 533 of 560
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
CERTIFICATE OF ANALYSIS
Catalog No: M-601 C-1 OX
Description: 2-Chloroethylvinyl ether
Lot: 218061690-01
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
~~~
Signal Word: Danger
Date Certified: Jul 15, 2020
Expiration: Jul 15, 2023
Sample Size: 1 mL
Components: 1
Storage Condition: Freeze «·10 ·C)
Certified Reference Material
Component CAS# Purity % Prepared Certified Analyte
Concentration' Concentration'
(GC/MS) (H9/mL) (flg/mL )
2-Chloroethylvinyl ether 110-75-8 100.0 2006 2006
A product with a suffix (-1A, -2B, etc. or -01, -02, etc.) on its lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 822-275872-11
, Certified Analyte Concentralion = Purity x Prepared Concentration.
The Uncertainty associated with the certifle'd concentration reported on this certificate is ±2,4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components, A normal distribution Is assumed and a coverage
factor of K=2 I,s chosen using approximately a 95% confidence level.
Labels and certificates folioV/U.S, Conventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater, A period (.) is used as
a decimal plaqe marker., , .
The information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Inform!itlon:.Pie~se refer to the SOS for information regarding the hazards associated with using this material.
This product wa~:p;~pared according to in-house procedures and is guaranteed to be homogeneolls.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEe 17025 and certified to ISO 9001 :2015 QR·ORGnNO·OOl
Rev. 7120
REPORT ID: 23E120 Page 534 of 560
.j
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers ANAB Certificate Number AR-1463
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories ANAB Certificate Number AT-1339
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations Certificate Number 3774
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory, Please refer to the NIST test number listed on the front of this certificate, Class A glassware
is used in the manufacture and quality control of all standards, Good Laboratory Practices have been used throughout
the preparation of this Standard,
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on Ule face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ti" = .r(Ii('!fFI-(u(mlY I (u(1V))2 F (u(RO»)2 I his
formula represents uncertainty components from the mass, volume, short-term stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery,
REPORT ID: 23E120 Page 535 of 560
Product Name: l-Chlorohexane Standard
Product Number: EPA-1208-1
Storage Conditions: Store at Room Temperature (ISO to 30°e).
Lot Number:
Lot Issue Date:
Expiration Date:
CERTIFIED VALUES
0006668972
10-Mar-2022
30-Apr-202S
Component Name Concentration Expanded Uncertainty CAS# Analyte Lot
t ~ Q • S '. No("'~ "?
Matrix: methanol (methyl alcohol)
Description:
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 1 of 2
CSO·QA·015.1
REPORT ID: 23E120 Page 536 of 560
ISO 17034 .. '~~:~:' .. Agilent
,* ~ ".
• TI ,Jslt:d /\I1~:\Vf~!~)
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~~ ...... x.. :.> .... ...-; ..... ~;o.., «<-;0; .. « ";V,>;«'';>; 'l"!;""'" «s:~ ~ .... -.;.... "I>'\: ..:«.,;.. o;.->-",<'\. \. ... ~ ..... .;:,.;;.x .. • ..... ·;> • ..;..-... •• .. ~ .................. -:-.-..; .. -.; ... .,;~ .. >; .... ,«,-o; .. .;o;.,; ..... .:: .... -..... r,-;>(-;> .... ~.:..< .'-"::' •• ;'o; ...... ~. • ........ ~ ........ , ..... ~. .. .............. ~ .... ;o ................. v ............... ;x. ..................................................... " ........... ;-.; ""::'1'
x«·;.X«-:-.""= .. NX*m»:-:·:::.;·.; ....... :·.·.·:.:·:-'.«·:·:.;.:%,~;.o)~o,;'::t.';.;·:.:·:-: .. • .•• ~.;~x·~: ... .;.;.;.>' ... .;·x .. .;.;·:·.y.«.;<-:·x .... ~_-..::. ............... : .... .;:( .. .,.~ .... :.; ... :*:,.:.;.; ... o:!.~ .. x.;·~~~w..:.;.;« ... :':·:·:·:~: .. .;.:,.:.-: ..... ,;-; .. .: ..... :.:.' ... :.;.;.; .. ' .. .;:>:..: ••• -;:~.~:::.;.: ............ :.: ................ ' ............... .: ........... : ............. : .... ', •••• '.: •• -:.; ............. ;. .............. .
~
ACCREOITED
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV ISUD registered ISO 9001 :2015
Quality Management System. Curt# 951215321
Page: 2 of 2
www.agilent.com/quality/
CSD·0A·015.1
Sample lot approvlr:
~QQM~QN6J
Monica Bourgeois
QMS Representative
~
ACCRf;DITEP
ISO 17025 Cert
No. AT-1937
REPORT ID: 23E120 Page 537 of 560
Scientific
SIMPLE SVlUl10NS FOR ADVAHGlV SCIENCE
Chromanex, 14271 Jeffey Rd #223, Irvine, CA 92620 [phone], Fax [phone] ._----------
Date manufactured: 10/15/2020
Original issue date: 10/15/2020 Certificate of Analysis Date Received:
Catalog No.: Lot No.: Storage: Solvent: Expiration Description:
3200-44 453887 PIT Methanol
Date:
14-0ct-2025 1 ,2,3-Trimethylbenzene Solution,
2500 mg/L, 1 mL
Certified Values:
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM
has been confirmed by g2,S chromatography (GC) or gas chromatograph/mass spectrometry
(GC/MS) using an internally developed method against an independent source. The uncertainty
value is calculated for a 95% confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, maIL
1,2,3-trimethylbenzene 526-73-8 95,2 869,3.19P 2515 ± 9.27
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control
standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It mayaslo be used for
various USEPA, NIOSH, and ASTM methods.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and
uncertainty (95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements: ::; -10°C
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal
ampule. Once opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards, All Glassware is calibrated
REPORT ID: 23E120 Page 538 of 560
Certificate of Analysis
Catalog No.: 3200-44 Lot No.: 453887 Expiration Date: 10/14/2025
using NIST traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department
of Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology
(NIST). Balances are checked daily in accordance to in house procedure 02-LB-004. Balances are calibrated
annually by an ISOIIEC 17025:2005 and ISO Guide 34:2009 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance
with internal procedure 02-0S-1 O. This is consistent with the intended use of this CRM. The homogeneity of this
product has been confirmed by procedures consistent with ISOIIEC qulde 17025:2005 and ISO Qulde 34:2009.
Hazardous information:
Refer to MSDS
Calculation of Uncertainty
The following equations are used to calculate the value of the expanded uncertainty: U=ku c: U=Expanded
Uncertainty, k= the coverage factor at the 95% confidence level, k=2, U c = the combined uncertainty uc = ..Jru l
2
where uj are the individual uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified
value. These tests include the effect of temperature and packaging on the product. This standard is guaranteed
until the following date: 14-0ct-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO
17034:2016 Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American
Association of Laboratory Accreditation (A2LA).
Manufactured By: Certified By: Released By:
Melissa Workoff Claire Desrochers Susan Mathews
REPORT ID: 23E120 Page 539 of 560
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30470
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative andlor quantitative determination of the analyte(s) listed.
Lot No.: A0162335
Description: tert-Butanol Standard
tert-Butanol Std 50.000IJg/mL. P&T Methanol. 1 mLiampul
Container Size: 2 mL
----------------------------
Pkg Amt: > 1 mL --.;..;.;.~----
Expiration Date: July 31. 2023 Storage: DOC or colder
-------------------------------
','; .. '-: .. M\ ....
Ij\C'CRED1T101
ISO t1~)4 Aa:redHed
R*r«lCe M~t~i~ PfoducQr
C9ftifiatQ Ulll.()l
d
·Isonec 17025 AOCfedited
Testing l>bOr'tory
C.rtifiGto fl222.02
CERTIFIED VALUES
Compound
tert-Butanol (TBA)
CAS # 75-65-0
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
(Lot SHBL5806)
Grav. Cone.
(weight/volume)
50,008.0 I!g/mL
Expanded Uncertainty
(95% C.L.; K=2)
+/-292.8078
+/-1,071.2377
+/-1,102.3483
Gravimetric
Unstressed
Stressed
14-May-2020 rev. 1 of 3
REPORT ID: 23E120 Page 540 of 560
Column:
105m x 0.53mm x 3.0~m
Rtx-502.2 (cat.#1091O)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ S'C/min. (hold 5 min.)
Inj, Temp:
200'C
Det. Temp:
250'C
Oet. Type:
FID
\I)'tfi-I ,~~~
Kyllo Strublq • Opero.tlonll Teohnlcltln ,
14-May-2020 rev.
10 15 20 25
fA tnutes
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 07-Jul-2020
Date Passed: 09-Jul-2020
Balance: 1127510105
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
/
i
20f3
REPORT ID: 23E120 Page 541 of 560
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
by TUV USA to ISO 9001:2015
Catalog No.: Lot No.:
scientific
(1 (uri Q 2 .. eft)
~~I .-'7 f-u1 F--l:r
Certificate of Analysis
Solvent: Exp. Date:
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: -------
Rev 0 Page
Description:
034-3200 480682
Storage:
:S -10°C PIT MeOH:Water 9:1 4/2812027 Ketones Solution, 2500 mglL, 1 ml ISO 17034
-12 \020-17
Compound
acetone
2-butanone (MEK)
4-methvl-2-oentanone (MIBK)
2-hexanone
Certified By:
Melissa Workoff
CAS No
67-64-1
78-93-3
108-10-1
591-78-6
Purity (%) Compound Lot No Concentration, mlllL
99.6 1 96.271.4P 2498 ± 53.47 mg/L
99.9 197.1.2P 2498 ± 53.51 mg/L
99.88 198.421.1.2P 2500 ± 54.02 mg/L
100 199.7.3P 2501 ± 53.58 mg/L
All weights are traceable through N. 1. S. T. Test No. 8221264157-00.
Concentration (correct for Duritv) and uncertainty (95% confidence) values
REPORT ID: 23E120 Page 542 of 560
· . ,
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•• a .... :.".. gl ent .. . . ~
Trusted Allswers
Reference Material Certificate
Product Information Sheet
Product Name: Acrolein and Acrylonitrile Standard
Product Number: AMN-623-1
Storage Conditions: Store Frozen (_25° to -1 DoC).
acrylonitrile 2009 ± 101.19/mL
Matrix: methanol (methyl alcohol)
Description:
ISO 17034
Lot Number: 0006728532
Lot Issue Date: 14-Feb-2023
Expiration Date: 30-Jun-2023
000107-13-1 RM20527
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material (RM) standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically. is listed above. Purity values are taken from approved vendor raw material certificates.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST SpeCial Publication 1088.
Homogeneity:
This analytical reference (RM) standard was unitized according to an in-house procedure and is guaranteed to be homogeneous.
There is no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference (RM) standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard (RM) is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 10f2
CSD-QA-015.1 ISO 17025
REPORT ID: 23E120 Page 543 of 560
. . . .
•••• e A -I ... :e.:.... gl ent . . .
Trusted Answers
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
REFER!:NCE MATERIAL
PRODUCER
ISO 17034 Cert
No. AR·1936
RM was produced in accordance with the TUV/SUD registered ISO
9001 :2015 Quality Management System. Cert# 951215321
Page: 2of2
www.agilant.com/quality/
CSD-QA·015.1
Sample lot approver:
~QOMgzoW
Monica Bourgeois
QMS Representative
ISO 17025
REPORT ID: 23E120 Page 544 of 560
~;
~;.
fi\«TI. DIT'TIB
SPEXerti/icate@
Certificate of Reference Material Reference Materials Producer
Cart #2495.01
Catalog Number: S-1015
Cyclohexane
Lot No. CP200701009
Ship Date: August 6, 2021
Methanol (Purge & Trap Grade) Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quali~y
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed In
USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Cyclohexane
CAS #
110-82-7
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 IJg/mL
Purity
99.5%
Certifiedt
1018 IJg/mL
Uncertainty
± 36IJg /mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepar~ the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6, 2021 Certifying Officer: ,3\u)..~"l---~-.,..
Shannon Macieira, Operations Manager
Page 1 of 2
REPORT ID: 23E120 Page 545 of 560
Report of Certification
Catalog Number: S-1015
Description: Cyclohexane
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200701009
Ship Date: August 6,2021
Expiration Date: August 5,2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS) and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the following standards:
-ISO 9001: Quality management systems. Requirements
-ISO/IEC 17025: General requirements for the competence of testing
• ISO Guide 35: Refernece Materials· General and Statistical
principals for certification and calibration laboratories • Guide to the Expression of Uncertainty in Measurement, 2008 ·ISO 17034: General requirements for the competence of reference
material producers
• EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition • ISO Guide 30: Reference Materials· Selected terms and definitions
-ISO Guide 31: Reference Materials· Contents of certificates and
lables
Storage Requirements:
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18°C to 2rC). Note: Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended amount that should be removed from this vial is 5fJL with a 25fJL ga~ tight syrir.go. All solutions should be thoroughly mixed, by shaking, prior to use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362·98 Appendix X2. Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure 4300·HOMOGEN·1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo tile variation, Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as: -

X

=

x

:l: U where X=certified value, U=expanded uncertainty, x=property value
-

U

=

kuc where k=2 is the coverage factor at the 95% confidence level
• Uc :: combined standard uncertainty obtained by combining the individual compound standard uncertainty components Ui, where uc::,Jrul' Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified Individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.\'P
Your Science is Our Passion.®
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax 1·732·603-9647
Page 2 of?
I
Rev: J
r
,./
REPORT ID: 23E120 Page 546 of 560
SR~}~·
ce~) ~ SPEXerti/icate®
Reference Materials Producer
Cert #2495.01
Certificate of Reference Material
Catalog Number: S-3893 Lot No. CP200615008
Description: Methyl acetate
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Matrix: Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
Methyl acetate
CAS #
79-20-9
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 ~g/mL
Purity
99.5%
Certifiedt
985 ~g/mL
Uncertainty
± 34 ~g/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20, 2022 Certifying Officer: .3~ ~
Shannon Macieira, Operations Manager
Page 1 of2
© 2021 ISpex, an A~Y)cienti~ company.
REPORT ID: 23E120 Page 547 of 560
Report of Cert~fication
Catalog Number: S-3893
Description: Methyl acetate
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200615008
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISO/IEC 17025: General requirements for the competence of testing
and calibration laboratories
-ISO 17034: General requirements for the competence of reference
material producers
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
-Guide to the Expression of Uncertainty In Measurement, 2008
-EURACHEMICITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
-NISTTechnlcal Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18DC to 27DC). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
Is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5J.lL with a 25J.lL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertlPrep from pre-qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025. ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final. packaged material have been analyzed to prove homogeneity In accordance with our intemal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity. as expressed as maximum between-bo
ttle variation. Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X = x ± U where X=certified value. U=expanded uncertainty. x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
-Uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components Ui. where Uc=v'rUI 2
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic. drug. or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever. whether based on breech of
warranty, alleged negligence. or otherwise. with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any inCidental, special. or consequential damages.
SPEX CertiPrep.1'j>
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
REPORT ID: 23E120 Page 548 of 560
U' SPEXerti/icate®
(jj'C'&e DdAA)
Reference Materials Producer
Cart #2495.01
Certificate of Reference Material Chemical Testing
Cerl #2495.02
Catalog Number: S-2470 Lot No. EN 191227005
Methylcyclohexane
Ship Date: August 6, 2021
Methanol (Purge & Trap Grade) Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Methylcyclohexane
CAS #
108-87-2
* -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 J,Jg/mL
Purity
99%
Certifiedt
1018 J,Jg/mL
Uncertainty
± 36 J,Jg/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6,2021 Certifying Officer: 3\<u:;...~v.vo"'J--. N\.l?Y'Sl-----
Shannon Macieira, Operations Manager
Page 1 of 2
REPORT ID: 23E120 Page 549 of 560
Report of Cert~fication
Catalog Number: 8-2470
Description: Methylcyclohexane
Matrix: Methanol (Purge & Trap Grade)
Lot No, EN191227005
Ship Date: August 6,2021
Expiration Date: August 5, 2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
• ISOIIEC 17025: General requirements for the competence of testing
and calibration laboratories
• ISO Guide 35: Refernece Materials· General and Statistical
principals for certification
-ISO 17034: General requirements for the competence of reference
material producers
-Guide to the Expression of Uncertainty in Measurement, 2008
• EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
• ISO Guide 30: Reference Materials· Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18°C to 27'C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5pL with a 25pL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cl(;aned prior to use. Dilutions should be performed only with Class (
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre·qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at crmsa![e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300·HOMOGEN·1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
tile variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X '" x ± U where X=certified value, U=<expanded uncertainty, x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
• Uc '" combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI. where uc="l:UI'
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind Whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.fP
Your SCience is Our Passion.'"
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Page 2 of 2
Rev: 0
REPORT ID: 23E120 Page 550 of 560
SRf3?r eel! SPEXerti/icate®
Reference Materials Producer
Cert #2495.01
Certificate of Reference Material
Catalog Number: S-615 Lot No. CP200928022
Description: 2-Butanol
Ship Date: June 20, 2022 Matrix: Expiration Date: June 19, 2025
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
2-Butanol
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
100 0 l-lg/mL
Purity
100%
Certifiedt
100 0 l-lg/mL
Uncertainty
± 35 I-Ig/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound( s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any Significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20, 2022 Certifying Officer: 3~ ~-.
Shannon Macieira, Operations Manager
Page 1 of 2
© 2021 I Spex, an A~WScienti~ company.
REPORT ID: 23E120 Page 551 of 560
,j
Report of Certification
Catalog Number: 8-615
Description: 2-Butanol
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200928022
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISOIIEC 17025: General requirements for the competence of testing
and calibration laboratories
• ISO 17034: General requirements for the competence of reference
material producers
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
-Guide to the Expression of Uncertainty in Measurement, 2008
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement· Third Edition
-NISTTechnical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product In ambient conditions (18°C to 27°C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
Is applicable only if the product Is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5IJL with a 25\JL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
Identifications are proprietary, however sources of al\ materials used In the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
tile variation, Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
-

X

=

x

± U where X=certified value, U=expanded uncertainty, x=property value
-

U

'" kuc where k=2 is the coverage factor at the 95% confidence level
-Uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI. where Uc="rUi'
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
Individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any Incidental, special, or consequential damages.
SPEX CertiPrep. ,
Your Science is Our Passion.'"
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
REPORT ID: 23E120 Page 552 of 560
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: I) It' 11.1.
by TUV USA to ISO 9001:2015 Certificate of Analysis Rev 0 Page
Catalog No.: lot No.: Storage:
:5 -10°C 3200-034 480677
-120016-03
Compound
bromomethane
chloromethane
chloroethane
dichlorodifluoromethane
vinvl chloride
trichlorofluoromethane
Solvent: Exp. Date:
PIT Methanol 11/8/2026
CAS No Purity (%)
74-83-9 99.5
74-87-3 99.7
75-00-3 99.94
75-71-S 99
75-01-4 99
75-69-4 99
Description:
ISO 17034 -Method 8260 Gases,
2.000 ml!lL_ 2 x 0.6 mL
Compound lot No Concentration, mll/L
139.15S.1.1P 2025 ± 7.36 mg/L
140.1 58.3P 2013 ± 7.32 mg/L
141.2.3P 1979 ± 6.93 mg/L
142.158.5P 2026 ± 21.46 mW!-
143.15S.5.2P 2011 ± 21.3 mg/L
144.1.3P 1998 ± 13.43 mW!-
Second Source standards are prepared according to NELAC requirements.
Certified By:
Samuel Garrett All weights are traceable through N.r. S. T. Test No. 822/264157-00.
Concentration (correct for Duritv) and uncertainty (95% confidence) values
REPORT ID: 23E120 Page 553 of 560
.;.";.
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
SV\-'?~-, 0 -0,
CERTIFICATE OF ANALYSIS
Catalog No: APP·9·211·20X
Description: Vinyl acetate
Lot: 222111294
Solvent: Methanol
Date Certified: Nov 21, 2022
Expiration: May 21,2023
Sample Size: 1 mL
Components: 1
Hazards: Refer to SOS for complete safety information Storage Condition: Freeze «.10 ·C)
Signal Word: Danger
Component CAS#
Vinyl acetate 108·05·4
Certified Reference Material
AR·1463
Purity' %
100.0
Prepared
Concentration"
QH9/fuq
This Certified Reference Material was verified 10 accordance with ISOIIEC 17025 (AT·1339) and ISO 17034 (AR·1463)
Certified Analyte
Concentration'
(jJg/mL)
2006
A product with a suffix (·IA, ·2B, etc. or -01, ·02,e\c.) on .il$.lot number has had its expiration date extended and is Identical to the same lot number wnhout the suffix.
, Certified Analyte Concentration = Purity ·x Prepa;ed Conc~ntration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen using approximateiy a 95% confidence level.
'All weights are traceable through NIST, Test No. 684/291344·18 & 684/292805-19
, Puritylldentity determined by one or more of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and·certlftcates follow U:S. Conventions in reporting numerical values: A comma (,) is use·d to separate units of one-thousand or greater. A period (.) is used as
a decimal pl~ee marker •.
The information on this .. certlficate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information: Please refer to the SDS for information regarding the hazards associated with using this material.
This product was.prepared according to in·house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEe 17025 and certified to ISO 9001 :2015 QR·ORG/INO·OO1
Rav.7/20
REPORT ID: 23E120 Page 554 of 560
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISOIIEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISOIIEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product Is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .!(u(V»)2 + (u(m»)2 + (u(IV»)2 + (u(RO))Z I his
formula represents uncertainty components from the mass, volume, short-term !ltability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E120 Page 555 of 560
Certificate of Analvsis
Product Name: Carbon Disulfide Standard
Product Number: EPA·1012·' Lot Issue Date: 2' ·Sep·2020
Lot Number: 0006557585 Expiration Date: 30·Sep·2024
Description:
This analytical reference material (RM) was manufactured and verified in accordance with an ISO 9001 registered quality system and analyte
concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each
analyte, determined gravimetrically, is listed below.
Analyte
carbon disulfide
Matrix: methanol (methyl alcohol)
Storage Conditions: Store Frozen (.25° to ., DOC).
Traceability:
CAS#
000075· 15·0
Analyte lot
RM08158
Concentration ± Uncertainty
5023 ± 25 Ilg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSl Z540.3, ISO 9001, ISO 17025,
and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are calibrated against a NIST traceable
thermometer in accordance with NIST Special Publication 108B.
Homogeneity:
This RM was unitized according to an in· house procedure and is guaranteed to be homogeneous. There is no minimum sub·sample size required.
Intended Use:
This RM is intended for the preparation of working reference samples for use in routine laboratory analyses. calibration of instruments. validation of
analytical methods, assessments of measurement methods. and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20·C to 25·C immediately after opening the container and should be processed without delay for
the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above, provided the RM is handled and stored in accordance with the
instructions given in this certificate. This certification is nullified if the RM is damaged. contaminated. or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
ACCREOITED
"Uti..,
RE"FEIlE'NCf: Ml\TE'RIAL
PRODUCER
ISO 17034 Cert
No. AR·1936
RM was produced in accordance with TUV USA Inc registered ISO 9001 Ouality
Management System. Cert # 56 100 18560026
Page: 1 of 1
www.agilent.com/quality/
CSO·OM15.1
Sample lot approver:
G0tPO QAASZ Ow
MOllica Bourgeois
QMS Representative
~
ACCREDITED
;.MN@
TESTING lABorV.TORV
ISO 17025 Cert
No. AT·1937
2.SD Smith ~.;treet North Kingstown, Hhode Island 028Ei2 www.agikmtcorn/quality
REPORT ID: 23E120 Page 556 of 560
SPEXerti/icate@
Certificate of Reference Material
Catalog Number: 8-260 Lot No. CP200804006
Description: tert-Amyl alcohol
Ship Date: June 20, 2022 Matrix: Expiration Date: June 19, 2025
This SPEXOrganics@ Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
tert-Amyl alcohol
SVI-3&-o1-o2
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 l-Ig/mL
Purity
99%
Certifiedt
1018l-1g/mL
Uncertainty
± 361J9/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20,2022 Certifying Officer: .3~ ~
Shannon Macieira, Operations Manager
Page 1 of 2
© 2021 I Spex, an ARftw)cienti~ comp.ny.
REPORT ID: 23E120 Page 557 of 560
Report of Cert~fication
Catalog Number: S-260 Lot No. CP200804006
Description: tert-Amyl alcohol
Matrix: Methanol (Purge & Trap Grade) Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISOIIEC 17025: General requirements for the competence of testing
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
and calibration laboratories -Guide to the Expression of Uncertainty in Measurement, 2008
-ISO 17034: General requirements for the competence of reference
material producers
-EURACHEMICITAC Guide: Qualifying Uncertainty in Analytical
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once It arrives in your laboratory, please store this product in ambient conditions (18°C to 27°C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5iJL with a 25iJL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by 5PEX CertiPrep from pre-qualifled vendors as per ISO guidelines. Vendor
Identifications are proprietary, however sources of all materials used In the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used In all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and A5TM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our intemal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
ttle variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X = x ± U where X=certlfied vaiue, U=expanded uncertainty, x=property value
- U :;: kuc where k:;:2 is the coverage factor at the 95% confidence level
-Uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI. where uc="ruf
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained In appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any InCidental, speCial, or consequential damages.
SPEX CertiPrep. fj)
Your Science is Our Passion."'
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Rev:
REPORT ID: 23E120 Page 558 of 560
s~~~' SPEXerti/icate®
~
Reference Materials Producer
Cert #2495.01
Certificate of Reference Ma teria 1
~d}' ~<~~ A .
" "I.. .. Chemical Testing
Cert #2495.02
Catalog Number: S-3730 Lot No. EN190716008
Description:
Ship Date: July 13, 2022 Matrix: Expiration Date: July 12, 2025
This SPEXOrganlcs® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
2,2,4-Trimethylpentane
Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
2,2,4-Trimethylpentane
~
540-84-1
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labgled
1000 IJg/mL
Purity
99%
Certifiedt
1000 IJg/mL
Uncertainty
± 35IJg/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: July 13, 2022 Certifying Officer: 3~ ~.
Shannon Macieira, Operations Manager
Page 1 of 2
<P 2021 I Spex, an A~~cientit2 company.
REPORT ID: 23E120 Page 559 of 560
Report of Certification
Catalog Number: 5-3730
Description:
Matrix:
2,2,4-Trimethylpentane
Methanol (Purge & Trap Grade)
Lot No. EN190716008
Ship Date: July 13. 2022
Expiration Date: July 12. 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISOIIEC 17025: General requirements for the competence of testing
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
and calibration laboratories -Guide to the Expression of Uncertainty in Measurement, 2008
-ISO 17034: General requirements for the competence of reference
material producers
-EURACHEMICITAC Guide: Qualifying Uncertainty in Analytical
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives In your laboratory, please store this product in ambient conditions (18°C to 27°C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE Is calculated from the SHIPPED DATE using our stability data and
is applicable only If the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial Is 5jJL with a 25jJL gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come In contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
Identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrlcs have been used In all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity In accordance with our intemal procedure
4300-HOMOGEN-1A. This Is consistent with the Intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
tile variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X: as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
- X = x ± U where X=certified value, U=expanded uncertainty, x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
-Uo = combined standard uncertainty obtained by combining the individual compound standard uncertainty components UI, where UC=.JrUI2
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained In appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep. 1>
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone] (I)
"-~ ... ,~--/
Page 2 of2
Rev: 0
REPORT ID: 23E120 Page 560 of 560
LABORA-TO RIES. INC.
3051 Fujita Street
Torrance. CA 90505
Tel; (31 O}-61.:&-8889
Date: 06-08-2023
EMAX Batch N9 _ : 23E133
Attn: Travis Gouveia
Brice
3800 Centerpoi nt Dr. Sui te 8223
Anchorage. I«. 99503
SUbject: Laboratory Report
PrOject: TEAO-S
Enclosed is the Laboratory report for samples received on 05/18/23_
The data reported relate only to samples 1 i sted below :
Sample ID Control # Col Date Matrix
.......... .........................
S-55-90-052023 E133-01 05/16/23 WATER
S-76-91-052023 E133-02 05116123 WATER
S-91-91-05-2023O E133-03 05/15123 WATER
S-91-91-052023 E133-04 05/15123 WATER
S13-CAA-DW1-052023 E133-05 05/15/23 WATER
SWMU-13-EB-052023 E133-06 05115123 WATER
TB-20230515-13 E133-07 05/15/23 WATER
S13-CAA-DW1-052023MS E133-05M 05115/23 WATER
S13-CAA-DW1-052023MSD E133-05S 05/15/23 WATER
The results are summarized on the following pages.
Please feel free to call if you have any questions concerning
these resul ts.
Sincerely yours.
o.~ __ F.IK._C{>
ca~p~~ -Jl Pang
Laboratory Di rector
AnalysiS
VOCS BY 8260C
TPH-DRO
VOCS BY 8260C
TPH-DRO
VOCS BY 8260C
TPH-DRO
VOCS BY 8260C
TPH-DRO
VOCS BY 8260C
TPH-DRO
VOCS BY 8260C
TPH-DRO
VOCS BY 8260C
VOCS BY 8260C
TPH-DRO
VOCS BY 8260C
TPH-DRO
This report is confidential and intended solely for the use of the individual or
entity to whom it is addressed. This report shall not be reproduced except in full
or without the written approval of EMAX.
EMAX certifies that results included in this report meets all TNI & DOD requirements
unless noted in the Case Narrative.
NE~ Accredited Certificate Number CA002912022-24
ANAB Accredited DoD ELAP and lSO/IEC 17025 Certificate Number L2278 Testing
California ELAP Accredited Certificate Number 2672
REPORT ID: 23E133 Page 1 of 345
CHAIN-OF-CUSTODY RECORD Brice Engineering, Salt Lake City, UT
Andrew Castor [phone]
COC # 770113-20230517
Page 1/1 '1 ~Et"~ 362 W. Pierpont Ave
SLC, UT 84101
Project Name: USAEC, TEAD-S Laboratory: EMAX Laboratories, Inc., Torrance, CA
Project Number: 770113 POC: Raman Singh (310)-618-8889 ext 119
WBSCode: Ship to: 3051 Fujita Street Torrance, CA 90505
Comments:
"C
Code Matrix
SW8015D (A); TPH·Diesel Range Organics 0 WG Ground Water ..c
11 WQ Water Quality Control Matrix
ALL VOC VOA Viles are located in Cooler #1, 1 L ambers are located in ::i f/J
... 0
cooler #1 or #2. (/) g GI ~ I-0 Code Container/Preservative iii Q 0 u I.() 0 2x 1 L Amber glass bottle with Teflon lined cap, Cool ~ .-CC 21 0 N O' to e'c; protected from light iii CO CO
C $ $ 31 3x VOA, 40 mL Clear glass vial with Teflon lined septa,
<C en en HClIo pH < 2, Cool O· to e'c
";§~~~;!~~p.~tq~;~ti~~fft()h~9~'~~~(6~!J:&~~~r"
" >,'
21 31 " ,
Samp
Sample Depth (ft bgs)
Sample 10 Matrix Date Time Init. Location 10 Type Top -Bottom
1 S-55-90-052023 WG 5/16/2023 915 CMH/SC X X S-55-90 N1 8.00 18.00
2 S-78-91-052023 WG 5/16/2023 1105 CMH/SC X X S-78-91 N1 13.80 28.80
3 S-91-91-05-20230 WG 5/15/2023 1335 CMH/SC X X S-91-91 F01 0.00 0.00
4 S-91-91-052023 WG 5/15/2023 1330 CMH/SC X X S-91-91 N1 0.00 0.00
5 S 13-CAM-OW 1-052023 WG 5/15/2023 1135 CMH/SC X X S13-CAM-OW1 N1/MS1/SD1 0.00 0.00
6 SW MU-13-EB-052023 WQ 5/15/2023 900 CMH/SC X X FIELOQC EB2 0.00 0.00
7 TB-20230515-13 WQ 5/15/2023 730 CMH/SC X TripBlank TB1 0.00 0.00
Turnaround Time: Standard
11
Event: TEAO-S 2023 Annual Monitoring
Groundwater
Cooler Comments
1/2
1/2
1/2
1/2
1
1
1
~tleived; /1_---12 ~~
0'1;09
~::!n~;i;~(Signature) C(~/? {j,(j-~-
Time ~ ..?
Received by; (Signature)
R-~ 11~L{,s&cl by: (S'15""'fuG ).::::;:::;?-O
Date '5-/l-23
Time \1..\':)0
~
Z.O/I.f(,
7" 1/1. ~
Cif:-O.2.
Master_Coe.xlsx ~7 Shipping Date: c::::;--1 -'2..3
Received by Laboratory: (Signature, Da~, Jme) & conditio REPORT ID: 23E133 Page 2 of 345
Type' of Delivety
ifFedex o UPS o GSO o Others
o EMAX Courier. 0 Client Delivery
",-
<;:OC INSPECTION ,
. r1 Client N~me ~ Client PM/FC
riAddress riTel # / Fax #
Airbill / Tracking NUlnber
&AOH1U f[ : 11217~11101 S-
~ Sampler Name ~ampliilg Datelfime
o Courier Signature Analysis Required
REFERENCE: EMAX-SM02 Rev. 12
SAMPLE RECEIPT FORM 1
ECN 2~!;./H
Recipient J 0 rei Vlt'lt) Jo I iJ -AAmllJ
Date o~/lVJn; Time D":~~
~ampleID p'Matrix
Preservative (if any) ~TAT
Safety Issues (ifany) .F o High concentrations expected o From Superfund Site ORad screening required
Not~:
...•.
PACKAGING INSPECTION
Container ~Cooler o Box o Other
C;ondition cottQGtlOV\ I?f Custody Seal o Intact o Damaged
Packaging {(A(JOt: -0.2 It5 Bubble Pack o Styrofoam o Popcorn o Sufficient 0
Temperatures o Cooler I ---°c 7cooler 2 Z.0U-'IJ "c e(Cooler3 2.1/,.'1 "C o Cooler 4 ___ tlC o Cooler 5 ---"c
(Cool, 'S6 °C but not frozen) 0COOler6 "c Otooler7 "c, o Cooler 8 °c o Cooler 9 "c o Cooler 10 "c
Thermometer: A -'SIN 21105 l1foe . B -SIN 2101(001)7
---------
e-slN D-SIN ----
Comments: o Temperature is out of range. PM was informed IMMEDIATELY.
Note:
DISCREPANCIES
LabSampleID LabSampleContaineriD . Code ClientSample Label ID / Information Corrective Action
.~ ZI,Ztl PILI P-l.\
q 2~ 010 ~
""' .. /' ----/'
~ /
~ /
" ~ /'
V /
/"" ;/
.,/"" /
../" A /
~ ~~/f/:' I~ '---!d\ d\l\k",
0 ~H holdin p g timere q uirement for water sam les is 15 mins. p Watet· sam les for p p H anal sis are received be ondlJ 5 iTiinutes from sam y y lin p g time. \ '.
NOTES/OBSERVATIONS:
SAMPLE MATRIX IS DRINKING WATER? 0 YES I!1'NO
LEGEND:
Code Description-Sample Management
DI Analysis is not indicated in ___ _
D2 Analysis mismatch COC vs label
D3 Sample ID mismatch COC vs label
D4 Sample ID is not indicated in ___ _
DS Container -[improper] [leaking] [broken]
D6 DatelTime is not indicated in ___ _
D7 Datelfime mismatch COC vs label
D8 Sample listed in COC is not received
~\ Sample received is not listed in COC
~ No initialBn corrections in COo1\abel)
D11 Container count mismatch COC vs re~
Code Description-Sample Management
D13 Out of Holding Time
(014) Bubble is >6mm
~ No trip blank in cooler
DI6 Preservation not indicated in ___ _
D 17 Preservation mismatch COC vs label
DI8 Insufficient chemical preservative
D 19 Insufficient Sample
D20 No filtration info for dissolved analysis
D21 No sample for moisture detennination
D22 ________________________________ __
D23 ____________________ ~------------
~ SRF
Date
EMAX Laboratories, Inc. 3051 Fujita SI., Torrance, CA 90505
o Continue to next page.
Code Description-Sample Management
RI Proceed as indicated in I'( cae 0 Label
R2 Refer to attached instruJi~n
R3 Cancel the analysis
R4 Use vial with smallest bubble first
R5 Log-in with latest sampli~g date and time+ I min
R6 Adjust pH as necessary
R7 Filter and preserved as necessary
R8· -----------------------------------R9 ______________________ ~ ________ _
RIO -----------------------------------
RII -----------------------------------RI2 ________________________________ ___
REPORT ID: 23E133 Page 3 of 345
;
... IG.IN ··i:NP.HA (B01 t_ .• · 1151 RIS .. OLT
8. ICE> GINEERING LLC· i
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; EMAx LABORATORIES, tNt
: 3051 FUJITA ST \' .
TORRANCE CA $0505 61a..~BB9 REF: 770113
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## MASTER ## .
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'JHU -•. MAY 10:30A
M~ORITl OVER~IGHT
REPORT ID: 23E133 Page 4 of 345
ORIGIN ID:NPHA [phone]
¢$ISHOLT
BRICE ENGINEERING LLC
362PlERtlONT AVE
SALT LAKE CITY, UT 84101
UNIlEPSTATES US
TO. RAMAN SINGH
EMAX LABORATORIES, INC
.. 30lt FUJITA ST
_t.uu""lnCE CA 90505
REF 770113
, 30f3
I~~:I 7721 7671 2649
M$tr# 7721 7671 1816 I 0201 I
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SHIP DATE: 17MAY23
ACTWGT: 50.00 LB
CAD: 1t146747111NET4610
DIMS: 25x13x14IN
BILL SENDER
~~
Express
[E]i
THU ·18 MAY 10:30A
PRIORITY OVERNIGHT
90505
CA-US LAX
REPORT ID: 23E133 Page 5 of 345
REPORTING CONVENTIONS
DATA QUALIFIERS:
Lab Qualifier AFCEE Qualifier Description
J F Indicates that the analyte is positively identified and the result is less
than LOQ/RL but greater than LOD/MDLlDL.
N Indicates presumptive evidence of a compound.
B B Indicates that the analyte is found in the associated method blank
as well as in the sample at above QC level.
E J Indicates that the result is above the maximum calibration range or
estimated value.
* * Out of QC limit.
Note: The above qualifiers are used to flag the results unless the project requires a different
set of qualification criteria.
ACRONYMS AND ABBREVIATIONS:
CRDL Contract Required Detection Limit
RL Reporting Limit
MRL Method Reporting Limit
MOL Method Detection Limit
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
DO Diluted out
DATES
The date and time information for leaching and preparation reflect the beginning date and time of the
procedure unless the method, protocol, or project specifically requires otherwise.
REPORT ID: 23E133 Page 6 of 345
LABORATORY REPORT FOR
BRICE
TEAD-S
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
SDG#: 23E133
REPORT ID: 23E133 Page 7 of 345
Client : BRICE
Project: TEAD-S
SDG 23E133
CASE NARRATIVE
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
A total of seven(7) water samples were received on 05/18/23 to be analyzed for
Volatile Organics by GC/MS in accordance with Method SW5030B/8260C and project
specific requirements.
Holding Time
Samples were analyzed within the prescribed holding time.
Instrument Performance and Calibration
Instrument tune check was performed prior to calibration. Result was within
acceptance criteria. Multi-calibration points were generated to establish
initial calibration (ICAL). ICAL was verified using secondary source (ICV).
Continuing calibration (CCV) was carried out at a frequency required by the
project. All calibration requirements were satisfied. Note that" Minimum
Response Factor" for all analytes were within method recommended response
factors with the exception of Acetone and 2-Butanone. However, percent
recoveries for all target analytes were within 70-130% on all calibration
points. Refer to calibration summary forms of ICAL, ICV and CCV for details.
Method Blank
Method blank was prepared and analyzed at the frequency required by the project.
For this SDG, two(2) method blanks were analyzed. V006E19B and V006E20B were
compliant to project requirement. Refer to sample result summary forms for
details.
Lab Control Sample
Lab control sample was prepared and analyzed at a frequency required by the
project. For this SDG, two (2) sets of LCS/LCD were analyzed. V006E19L/V006E19C
and V006E20L/V006E20C were within LCS limits. Refer to LCS summary forms for
details.
Matrix QC Sample
Matrix spike sample was prepared and analyzed at a frequency required by the
project. For this SDG, one(l) set of MS/MSD was analyzed. 23E133-05M/23E133-05S
-all analytes were within MS QC limits. Refer to Matrix QC summary form for
details.
Surrogate
Surrogates were added on QC and field samples. All surrogate recoveries were
within QC limits. Refer to sample result summary forms for details.
Sample Analysis
Samples were analyzed according to prescribed analytical procedures. Results
were evaluated in accordance to project requirements. For this SDG, all quality
control requirements were met.
REPORT ID: 23E133 Page 8 of 345
Client
Project
Client
Sample ID
---------
LCS1W
LCD1W
MBLK1W
BRICE
TEAD-S
S-55-90-052023
S-78-91-052023
S-91-91-05-2023D
S-91-91-052023
TB-20230515-13
SWMU-13-EB-052023
LCS2W
LCD2W
MBLK2W
S13-CAM-DW1-052023
S13-CAM-DW1-052023MS
S13-CAM-DW1-052023MSD
FN -Filename
... Moist -Percent Moisture
Laboratory Dilution ...
Sample ID Factor Moist
---------
V006E19L 1 NA
V006E19C 1 NA
V006E19B 1 NA
23E133-01 1 NA
23E133-02 1 NA
23E133-03 1 NA
23E133-04 1 NA
23E133-07 1 NA
23E133-06 1 NA
V006E20L 1 NA
V006E20C 1 NA
V006E20B 1 NA
23E133-05 1 NA
23E133-05M 1 NA
23E133-05S 1 NA
LAB CHRONICLE
VOLATILE ORGANICS BY GC/MS
WATER
Analysis Extraction
DateTime DateTime
--------------------------
OS/23/2309:07 OS/23/2309:07
OS/23/2309:33 OS/23/2309:33
OS/23/2310:25 OS/23/2310:25
OS/23/2315:36 OS/23/2315:36
OS/23/2316:02 OS/23/2316:02
OS/23/2316:28 OS/23/2316:28
OS/23/2316:54 OS/23/2316:54
OS/23/2318:12 OS/23/2318:12
OS/23/2318:38 OS/23/2318:38
OS/24/2307:57 OS/24/2307:57
OS/24/2308:23 OS/24/2308:23
OS/24/2309:15 OS/24/2309:15
OS/24/2310:59 OS/24/2310:59
OS/24/2313: 09 OS/24/2313: 09
OS/24/2313: 35 OS/24/2313: 35
Sample
Data FN
REW409
REW410
REW412
REW424
REW425
REW426
REW427
REW430
REW431
REW435
~REW436
Rll!.l438
REW442
REW447
REW448
SDG NO. 23E133
Instrument ID 06
Calibration Prep.
Data FN Batch Notes
REW253 V006E19 Lab Control Sample (LCS)
REW253 V006E19 LCS Duplicate
REW253 V006E19 Method Blank
REW253 V006E19 Field Sample
REW253 V006E19 Field Sample
REW253 V006E19 Field Sample
REW253 V006E19 Field Sample
REW253 V006E19 Field Sample
REW253 V006E19 Field Sample
REW253 V006E20 Lab Control Sample (LCS)
REW253 V006E20 LCS Duplicate
REW253 V006E20 Method Blank
REW253 V006E20 Field Sample
REW253 V006E20 Matrix Spike Sample (MS)
REW253 V006E20 MS Duplicate (MSD)
REPORT ID: 23E133 Page 9 of 345
SAMPLE RESULTS
REPORT ID: 23E133 Page 10 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E133
S-55-90-052023
23E133-01
REW424
Ext Btch ID: V006E19
Calib. Ref.: REW253
PARAMETER{S)
------------------------------
1,1, 1, 2-Tetrachloroethane
1,1,1-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichlorop ro1ane
2-Butanone {MEK
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
~t~;~~~~~~~~~~~~h~~~ene
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl
n-Butylbenzene
ether (MTBE)
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
l,2-Dibromoethane
l,2,3-Trichlorobenzene
l,4-Dioxane
SURROGATE PARAMETER (S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/16/23 09:15
Date Received: 05/18/23
Date Extracted: OS/23/23 15:36
Date Analyzed: OS/23/23 15:36
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
--------------------------------------------
NO 1.0 0.10
NO 1.0 0.10
NO 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.25
NO 1.0 0.15
NO 2.0 0.25
NO 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 20 5.0
NO 1.0 0.25
NO 20 5.0
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.50
0.37J 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.21
ND 10 2.5
ND 2.0 0.50
NO 1.0 0.15
NO 1.0 0.25
NO 1.0 0.25
NO 1.0 0.10
ND 1.0 0.25
NO 1.0 0.25
ND 1.0 0.25
NO 1.0 0.25
NO 1.0 0.15
NO 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.11
NO 1.0 0.10
ND 1.0 0.15
ND 100 25
RESULT SPK_AMT %RECOVERY
---------------------------------
10.1 10.0 101
10.4 10.0 104
10.3 10.0 103
10.4 10.0 104
Final Volume : 25ml
Analyzed by : LYamas
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.50
0.30
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.50
10
0.50
10
0.50
10
0.20
0.20
0.30
0.20
0.30
0.50
0.50
0.20
0.20
1.0
0.20
0.50
0.20
0.20
0.20
0.20
0.50
0.20
0.20
0.50
5.0
1.0
0.30
0.50
0.50
0.20
0.50
0.50
0.50
0.50
0.30
0.20
0.20
0.50
0.20
0.50
0.30
0.20
0.30
50
QC LIMIT
-----------
70-130
70-130
70-130
70-130
relative to sample result significant figures.
REPORT ID: 23E133 Page 11 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW424.D
Acq On 23 May 2023 3:36 pm
Sample 23E133-01
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 18
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 16:01 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023 ~
Initial Calibration ,
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.10 114 4126343 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 3555270 10.00 ug/l 0.01
73) l,2-DICHLOROBENZENE-D4 19.43 152 1323293 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1379977 10.35 ug/l 0.02
Spiked Amount 10.000 Recovery = 103.50%
41) l,2-Dichloroethane-d4 9.23 65 936410 10.10 ug/l 0.01
Spiked Amount 10.000 Recovery = 101 ((fO%
54) Toluene-d8 12.93 98 4768347 10.33 ug/J..---0.01
Spiked Amount 10.000 Recovery = 103.30%
76) 4-Bromofluorobenzene 17.56 95 1558689 10.41 ugX 0.01
Spiked Amount 10.000 Recovery = 104.10%
./
Target Compounds Qvalue
17) Methylene chloride 4.39 49 40115 0.25 ug/l 96
30) Chloroform 7.60 83 92697 0.37 ug/l 96
,..--
(#) = qualifier out of range (m) = manual integration
REW424.D V006E15.M Tue May 23 16:01:55 2023 Page 1
REPORT ID: 23E133 Page 12 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW424.D
Aeq On 23 May 2023 3:36 pm
Sample 23E133-01
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial: 18
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 23 16:01 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
! 44000001
4200000)
4000000j
I
38000001
3600000
3400000
3200000
3000000
2800000
2600000
2400000
! 2200000
2000000
1800000
1600000
1400000
1200000
1000000
800000
600000
400000
1 200000
! 0
ttime-->
I
1
I
I
I
1 I
1
1
I I I
I
I I
1
I
1 I
I -
2.00
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW424.D
w· z w
~ w
ttl
0
0:
0
::J --' u.
i5 ....
,
(J)
Q).
e:
'" .c: a; (J) E " e 1:J 0
'" ::>
'l'i e:
'" E .<:
~ a; e a 0
:E .2
0
N.
:::;; r:
Q) :::;; 1:J .'" f--' .Q 0 .r:
0 E" Q) e: 0
.ll1 e >-.r: .Q a; .c:
:::;; ()
AJ\..... '"-
I I I I
4.00 6.00 8.00 10.00 12.00
'---.
I
14.00
(RTE Integrator)
~.
z w
~
III
0 ct
0 --' I
()
I
(J)
0'-c
Q)
~
.l'l e g
'l'i
E e
O? ....
LL
I I
16.00 18.00
--' J:
()
~H
A
I
20.00
REW424.D V006E15.M Tue May 23 16:01:56 2023
I
Page 2
REPORT ID: 23E133 Page 13 of 345
V'\bundance
, I
Rem
I
i
m/z-->
bundance
Ra~:
I
S"'r'6 (4.389 miol' REW253. D H
84
50 60 70 80 90 100 110 120 130 140 150 160 170
r Scan 216 (4,390 min): REW424,D
84
67 76 II
0 ', ,I,' ' ,II 94, 113
1,-,-,-..J1j1ft1jJftl+lcY+J,t"J., Wh~TI-rAY+tn'rF'lTT"T'T",r"'T""ri""r'l'-rr'l
mlz--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
~ -,-----, ,~----,,---.------.-"~--~---
Abundance Scan 216 (4,390 min): REW424.D (-)
, I 4'
Sub I
50
1
84
I 41
o lrrnTTt'rr-n-'t'WnY-nTtn--rrlYJ-tT+h-T'rYt-tTTTrrnTTT,nTTI""! ' , , , I ' , , 'I '" I ' , , , I
I
Ra'!toi
1,1
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
Scan 368 (7,575 min): REW253,D (-)
83
94 105 118 135 161
, Oh~ TTTf't'f,'¥f't'f'n, Yff1fnLfth-rrYft'focrt-n-TTT"<TJTr-rtTITTTnI '-~I iii I Ii, Iii iii I Iii iii iii i ! i
Im/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190
Abu'ndance Scan 369 (7,597 min): REW424.D H
I 8r
I, i
I
Sub I
50:
I II
105 118 135 161
i 0 I' 'I' I'" ,1'1 "''Trrr.P'T'T''''1hT1l'' "I" "1""1'
#17
Methylene chloride
Concen: 0.25 ug/l
RT: 4.39 min Scan# 216
Delta R.T. 0.00 min
Lab File: REW424.D
Acq: 23 May 2023 3:36 pm
Tgt Ion: 49 Resp: 40115
Ion Ratio Lower Upper
49 100
84 83.2 57.4 117.4
86 52.9 25.5 85.5
bundance Ion 49,00 (48,70 to 49,70): REW4-24,Q
lion 84,00 (83,70 to 84,70) REW424,q
8000 Ion 86,00 (85,70 to 86,70): REW424,~
i 4,39
6000 A
2000
//\ IA r \\
I
o I
1'"'''1', I
4.20 4,30 4.40 4.50 4,60 4,70_J ime-->
#30
Chloroform
Concen: 0.37 ug/l
RT: 7.60 min Scan# 369
Delta R.T. 0.02 min
Lab File: REW424.D
Acq: 23 May 2023 3:36 pm
Tgt Ion: 83 Resp: 92697
Ion Ratio Lower Upper
83 100
85 67.1 38.7 98.7
47 28.3 0.0 53.2
bundance Ion 83.00 (82.70 to 83.7"0): R-EW424.a
lion 85,00 (84,70 to 85,70): REW424,q
Ion 47.00 (46,70 to 47.70): REW424w
20000
1
15000
10000 1
5000
Im/z --> 30 40 50 60 70 80 90 1 00 11 0 120 130 140 150 160 170.-,-1-,--80,-1'-..C9--,-0~--,-,-,i,-,-mc=-e-_->~~--,--7,--,.4~0 --,-,7 .~50=----7,--,-,=-:60,,---,7,-,-, 7:..::0'----'-7~, 8=0~ ___ --i
REW424.D V006E15.M Tue May 23 16:01:56 2023 Page 3
REPORT ID: 23E133 Page 14 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E133
S-78-91-052023
23E133-02
REW425
Ext Btch ID: V006E19
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
1, 1, l,2-Tetrachloroethane
1,1, I-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1, 2, 4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dich1oroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloroprofane
2-Butanone (MEK
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xhlene
4-Met yl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1,2,3-Trichlorobenzene
l,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/16/23 11:05
Date Received: 05/18/23
Date Extracted: OS/23/23 16:02
Date Analyzed: OS/23/23 16:02
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
----------- ---------------------------------
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.25 0.50
ND 1.0 0.15 0.30
ND 2.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.50 1.0
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.21 0.50
ND 10 2.5 5.0
ND 2.0 0.50 1.0
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
0.50J 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 o .ll 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 100 25 50
RESULT SPK_AMT %RECOVERY QC LIMIT
--------------------------------------------
10.3 10.0 103 70-130
9.82 10.0 98 70-130
10.2 10.0 102 70-130
10.5 10.0 105 70-130
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E133 Page 15 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW425.D
Acq On 23 May 2023 4:02 pm
Sample 23E133-02
Misc 25mL
(QT Reviewed)
Vial: 19
Operator: LYamas
Inst 06
Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 23 16:27 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.10 114 3915841 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 3378542 10.00 ug/l 0.01
73) 1,2-DICHLOROBENZENE-D4 19.43 152 1335551 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1324396 10.47 ug/l 0.02
Spiked Amount 10.000 Recovery 104.70%
41 ) l,2-Dichloroethane-d4 9.23 65 909767 10.34 ug/l 0.01
Spiked Amount 10.000 Recovery 103. 0%
54) Toluene-d8 12.93 98 4496728 10.25 ug/l r 0.01
Spiked Amount 10.000 Recovery = 102.50%
76) 4-Bromofluorobenzene 17.56 95 1483977 9.82 ug/V 0.01
Spiked Amount 10.000 Recovery = 9~20%
Target Compounds Qvalue
17) Methylene chloride 4.41 49 41246 0.27 ug/l 99
44) Trichloroethene 10.68 130 71248 0.50 ug/l 97
(#) = qualifier out of range (m) = manual integration
REW425.D V006E15.M Tue May 23 16:27:58 2023 Page 1
REPORT ID: 23E133 Page 16 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW425.D
Aeq On 23 May 2023 4:02 pm
Sample 23E133-02
Mise 25mL
MS Integration Params: RTE.P
Quant Time: May 23 16:27 2023
Vial: 19
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RE
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title METHOD 8260
Last Update Tue May 16 12:41:48 2023
Response via Initial Calibration
~l\bL-m---;ld-an-,c~e---------------~---=TC-::ICc-:=R=E:-CWC-:4-=-25=-.=0----------------1
! !
95000001
1
90000001
I
85000001
!
1
80000001
!
i
!
75000001
j
7000000 1
1
6500000i
I
60000001
! ,
5500000;
50000001
!
4500000;
I
40000001
I
35000001
30000001
25000001
j
20000001
w' z
W
~J
Z
W
Q) o cr g
-' u.
(5
"".
[J)
a:i
d;
c
" :J
(5
f-
c1
ill z
~
1ll o cr g
I
l)
Ii ~ ~
1\ jg ~-il
II ~ d; II Ii ~ ~ I:
1500000] •. i 1 i c I I
c;
ill z
W
N
Z
W
Q) o cr g
I o
is
c<,
10000001 i 0 ~ i I I I
. 500oot~,_._yl.lO;:I-O:::;::::':;=' ::..,JL,-;=, ::;=_1 c-::;i::::;:=;==;'=F1 T', "T,=F, T', ~~-";=. ~ J~:;=, T' =C=1r=r~\--r=r, =r, =0;,==;=0, 'T, c""LJ~1 'T, =i'=~l""'-I=r-,J ~~, =;=, =;,=;c=, T', =;C,=;C,
,Time--> 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 . _____ ._ ... __ . __ --==-=-__ -=~_~~ __ ~_=___....c...c~ __ -=c..=-=--_--'-'~_--'-~_=___.c.=_=_=_. _ _==_:.:.c=__,, ___ ._
REW425.D V006E15.M Tue May 23 16:27:59 2023 Page 2
REPORT ID: 23E133 Page 17 of 345
bundance
Ra~
0
Sub
50
I 0 [
tn!3:::?
f-bundance
Rem
o
~->
~bundance
!
I Ra~
30 40
30 40
44
50 60
4
50 60
Scan 216 (4.389 min): REW253.D (-)
7
, , '
70 80 90 100 110 120 130 140 150 160 170
Scan 217 (4.411 min): REW425.D (-)
84
76
70 80 90 100 110 120 130 140 150 160 170
Scan 583 (10.669 min): REW253.D (-)
'p T
60
[,I 70
60
60
~~ 1,[1051 207
I I I ,.,-'I""T''''I''''
80 100 120 140 160 180 200
Scan 584 (10.683 min): REW425.D
95 1 0
l,z--> 0 L,,-Y4-lJ!01f--4U-,-J,ll6jll.,0 ,-l,--,---r8-'-0'-r-r--,-llJU1 01-0'---'--'-'-,1"2-'-0 --,-Lj-I+-14-'-0r-r-"1---r6.,0 --.-r-r-18-'-O-'--'-"2"0"0--'--'-'-
fA-bundance Scan 584 (10.683 min): REW425.D (-)
95 1 0
Sub
50 60
#17
Methylene chloride
Concen: 0.27 ug/l
RT: 4.41 min Scan# 217
Delta R.T. 0~02 min
Lab File: REW425.D
Acq: 23 May 2023 4:02 pm
Tgt Ion: 49 Resp: 41246
Ion Ratio Lower Upper
49 100
84 87.0 57.4 117.4
86 56.7 25.5 85.5
bundance Ion 49.00 (48.70 to 49.70): REW425.
8000 Ion 84.00 (83.70 to 84.70): REW425.
Ion 86.00 (85.70 to 86.70): REW425'1
6000 4.41 !
4000
2000
#44
Trichloroethene
Concen: 0.50 ug/l
RT: 10.68 min Scan# 584
Delta R.T. 0.01 min
Lab File: REW425.D
I
I
Acq: 23 May 2023 4:02 pm
Tgt
Ion
130
132
95
97
Ion:130
Ratio
100
97.5
102.6
63.1
Resp:
Lower
69.7
67.9
35.8
71248
Upper
129.7
127.9
95.8
bundancelon 130.00 (129.70 to 130.70): REW4
Ion 132.00 (131.70 to 132.70): REW4
30000 Ion 95.00 (94.70 to 95.70): REW425.
Ion 97.00 (96.70 to 97.70): REW425.
25000
10.68
20000
15000
10000
5000
REW425.D V006E15.M Tue May 23 16:28:00 2023 Page 3
REPORT ID: 23E133 Page 18 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
23E133
S-91-91-05-2023D
23E133 -03
Lab File ID: REW426
Ext Btch ID: V006E19
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1, 2, 4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl
n-Butylbenzene
ether (MTBE)
n-Propylbenzene
a-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
vinyl Chloride
1,2-Dibromoethane
1,2,3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Date Collected:
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Matrix:
% Moisture:
Instrument ID:
RESULTS LOQ
(ug/L) (ug/L)
----------------------
ND 1.0
ND 1.0
ND 1.0
ND 1.0
0.17J 1.0
ND 1.0
ND 1.0
ND 2.0
ND 1.0
ND 2.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 20
ND 1.0
ND 20
ND 1.0
ND 20
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 2.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 2.0
ND 10
ND 2.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 100
RESULT SPK_AMT
----------- -----------
10.5 10.0
9.94 10. O.
10.1 10.0
10.5 10.0
05/15/23 13: 35
05/18/23
OS/23/23 16:28
OS/23/23 16:28
1
WATER
NA
06
DL
(ug/L)
LOD
(ug/L)
----------- -----------
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.25 0.50
0.15 0.30
0.25 0.50
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.25 0.50
5.0 10
0.25 0.50
5.0 10
0.25 0.50
5.0 10
0.10 0.20
0.10 0.20
0.15 0.30
0.10 0.20
0.15 0.30
0.25 0.50
0.25 0.50
0.10 0.20
0.10 0.20
0.50 1.0
0.10 0.20
0.25 0.50
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.25 0.50
0.10 0.20
0.10 0.20
0.21 0.50
2.5 5.0
0.50 1.0
0.15 0.30
0.25 0.50
0.25 0.50
0.10 0.20
0.25 0.50
0.25 0.50
0.25 0.50
0.25 0.50
0.15 0.30
0.10 0.20
0.10 0.20
0.25 0.50
0.10 0.20
0.25 0.50
0.11 0.30
0.10 0.20
0.15 0.30
25 50
%RECOVERY QC LIMIT
----------- -----------
105 70-130
99 70-130
101 70-130
105 70-130
==================================================================================
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E133 Page 19 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW426.D
Acq On 23 May 2023 4:28 pm
Sample 23E133-03
Misc 2SmL
(QT Reviewed)
Vial: 20
Operator: LYamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 23 17:16 2023 ~Quant Results File: V006E1S.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E1S.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E1S
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.10 114 3678794 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 3245586 10.00 ug/l 0.01
73) l,2-DICHLOROBENZENE-D4 19.43 152 1272897 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1246993 10.50 ug/l 0.02
Spiked Amount 10.000 Recovery = 105.00%
41) l,2-Dichloroethane-d4 9.24 65 868084 10.51 ug/l 0.03
Spiked Amount 10.000 Recovery = 105.16%
54) Toluene-d8 12.93 98 4269977 10.13 ug/l..,..,..-0.01
Spiked Amount 10.000 Recovery = 101. 30%
76 ) 4-Bromofluorobenzene 17.56 95 1432032 9.94 ug/l/ 0.01
Spiked Amount 10.000 Recovery = 99;fi 0%
Target Compounds Qvalue
17) Methylene chloride 4.41 49 34249 0.24 ug/l 97
24) l,l-Dichloroethane S.77 63 38374 0.17 ug/l 93
/
(#) = qualifier out of range (m) = manual integration
REW426.D V006E15.M Tue May 23 17:17:14 2023 Page 1
REPORT ID: 23E133 Page 20 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW426.D
Aeq On 23 May 2023 4:28 pm
Sample 23E133-03
Mise 25mL
MS Integration Params: RTE.P
Quant Time: May 23 17:16 2023
Vial: 20
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
!Abundance
, 95000001
9000000
8500000
8000000
7500000
7000000
I
!
I
6500000
6000000 1
1
5500000
5000000
I
I
4500000
4000000
3500000
j 3000000 I
1
1 i
I 2500000
I
j 2000000
1
i
1500000 I 1
I
!
! i 1000000
I oo~ ~
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW426.D
w· z
W
N z w
fD a
~ a
:J
-' LL
(5 ..,..
CJ) .,-
<: CJ) til .c ~ 1il
E .,
e <:
'" 0 .c
::;; ::;; ::l ..,
t-: t-' '5 e E 0 a: e :c
-& <Ii .0 ~. c: is 'C III 0 .c :c ~ " ., 0 c: :c .,
>. ,>1
.c 9 ..,
::;;
~ w z
;;;. w
0 ~ w w CJ) co
a5 z a "0 w ~ cb ~ 9 <: ., w CJ) I ::l fD <Ii 0 ~ a <: ~ et: I';l a -' <:
I J!l 0 e
0 ::l -= 0
E e
fD ..,.
U
I I I I I I I I T ITime-.~->~ ____ ~2~.0~0~ __ ~4~.0~0 __ ~6~.0~0~ __ ~8~.0~0~ __ 1~O~.0~0 __ ~1~2.~00~ __ ~14~.O~O~ __ 1~6~.O~O __ ~1~8.~OO~ __ 2~O~.O~O~ __ ~
REW426.D V006E15.M Tue May 23 17:17:16 2023 Page 2
REPORT ID: 23E133 Page 21 of 345
---------------=----=-:-=-:-:---===----:-:--=-:-==-=-:::c-:-:------------, ~bundance Scan 216 (4.389 min): REW253.D (-)
I Rew 49 7
84
64 O~~.rr~~rrn~~~~rrnTrrnnnT~n.~nn~~Trr~
Iz--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
iAbundance Scan 217 (4.409 min): REW426.D
• Ra% 84
O~~~~~~~~~~hn~~~~~~~~~~~
Iz--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
bundance Scan 217 (4.409 min): REW426.D (-)
Sub
50
76
8
I O~~~~~rrnn+~~~hn~~~~~~~'~"~I'~"~'I~'~"'1
hl/z--> 90 100 110 120 130 140 150 160 170
bundance
Rem
4
Scan 281 (5.751 min): REW253.D (-)
6
140
I 0 ,
156
150 160
mlz--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 ~bundance ~can 282 (5.771 min): REW426.D (-)
i
Sub
50
hl/z-->
#17
Methylene chloride
Coneen: 0.24 ug/l
RT: 4.41 min Sean# 217
Delta R.T. 0.02 min
Lab File: REW426.D
Aeq: 23 May 2023 4:28 pm
Tgt Ion: 49 Resp: 34249
Ion Ratio Lower Upper
49 100
84 87.6 57.4 117.4
86 61. 7 25.5 85.5
bundance Ion 49.00 (48.70 to 49.70): REW426.
Ion 84.00 (83.70 to 84.70): REW426.
6000 Ion 86.00 (85.70 to 86.70): REW426.
5000 4.41
#24
l,l-Diehloroethane
Coneen: 0.17 ug/l
RT: 5.77 min Sean# 282
Delta R.T. 0.02 min
Lab File: REW426.D
Aeq: 23 May 2023 4:28 pm
Tgt Ion: 63 Resp: 38374
Ion Ratio Lower Upper
63 100
65 32.8 1.4 61. 4
83 19.9 0.0 43.0
bundance Ion 63.00 (62.70 to 63.70): REW426.Q
8000
Ion 65.00 (64.70 to 65.70): REW426'j
Ion 83.00 (82.70 to 83.70): REW426.
5.77
6000 I
4000 I
2000
REW426.D V006E15.M Tue May 23 17:17:17 2023 Page 3
REPORT ID: 23E133 Page 22 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E133
S-91-91-052023
23E133-04
REW427
Ext Btch ID: V006E19
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
1, 1, 1, 2-Tetrachloroethane
l,l,I-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
1,l,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1 /2-Dichloroethene
cis-l,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-xr;lene
4-Met yl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-ISOprO~Yltoluene
Sec-Buty benzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-l,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
l,2-Dibromoethane
l,2,3-Trichlorobenzene
l,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: 05/15/23 13:30
Date Received: 05/18/23
Date Extracted: OS/23/23 16:54
Date Analyzed: OS/23/23 16:54
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
--------------------------------------------
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
0.18J 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.25
ND 1.0 0.15
ND 2.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.25
ND 20 5.0
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.15
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.50
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.10
ND 2.0 0.21
ND 10 2.5
ND 2.0 0.50
ND 1.0 0.15
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.25
ND 1.0 0.15
ND 1.0 0.10
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.10
ND 1.0 0.25
ND 1.0 0.11
ND 1.0 0.10
ND 1.0 0.15
ND 100 25
RESULT SPK_AMT %RECOVERY
---------------------------------
10.5 10.0 105
9.99 10.0 100
10.2 10.0 102
10.5 10.0 105
Final Volume : 25ml
Analyzed by : LYamas
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.50
0.30
0.50
0.20
0.20
0.20
0.20
0.20
0.20
0.50
10
0.50
10
0.50
10
0.20
0.20
0.30
0.20
0.30
0.50
0.50
0.20
0.20
1.0
0.20
0.50
0.20
0.20
0.20
0.20
0.50
0.20
0.20
0.50
5.0
1.0
0.30
0.50
0.50
0.20
0.50
0.50
0.50
0.50
0.30
0.20
0.20
0.50
0.20
0.50
0.30
0.20
0.30
50
QC LIMIT
-----------
70-130
70-130
70-130
70-130
relative to sample result significant figures.
REPORT ID: 23E133 Page 23 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW427.D
Acq On 23 May 2023 4:54 pm
Sample 23E133-04
Misc 25mL /(
(QT Reviewed)
Vial: 21
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 23 17:20 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.10 114 3812793 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 3328624 10.00 ug/l 0.01
73) 1,2-DICHLOROBENZENE-D4 19.43 152 1300113 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1292438 10.50 ug/l 0.02
Spiked Amount 10.000 Recovery = 105.00%
41) l,2-Dichloroethane-d4 9.23 65 901473 10.53 ug/l ~0.01
Spiked Amount 10.000 Recovery = 105.30%
54) Toluene-d8 12.93 98 4398638 10.18 ug/l /' 0.01
Spiked Amount 10.000 Recovery = 101.80%
76 ) 4-Bromofluorobenzene 17.56 95 1470628 9.99 ugly 0.01
Spiked Amount 10.000 Recovery = 99.90%
./
Target Compounds Qvalue
17) Methylene chloride 4.41 49 38281 0.26 ug/l 88
24) 1,1-Dichloroethane 5.77 63 41706 0.18 ug/l 87
/
(#) = qualifier out of range (m) = manual integration
REW427.D V006E15.M Tue May 23 17:20:41 2023 Page 1
REPORT ID: 23E133 Page 24 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW427.D
Aeq On 23 May 2023 4:54 pm
Vial: 21
Operator: LYamas
Sample 23E133-04 Inst 06
Mise 25mL Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 23 17:20 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
fi\bundance
9500000
i 9000000
I
85000001
I
i 8000000j
I
7500000 1
70000001
I
6500000 1
6000000
55000001
I
1
50000001
45000001
i
40000001
I
35000001
I
30000001
2500000
20000001
I
15000001
10000001
5000001
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW427.D
uI z
W
N
Z w m a a:: a
::J
---' u.
9 "'.
(f)
of c: (f) '" :g .c: ..,
E d> e c:
'" 0 ~ :;; " '5 e t-" E .Q n: e .c:
of .n 5 c: is '" N. .c: ..,
e 0 :c .2
9
§
z w It; ~ 0
ill w
(f) m z a ex; w a:: a: ~ a
c: W ..J ., m (f) I
" a (lr 0 ~ a:: c: is ., a ~ N. ..J
I 1l 0 e
0
" '8 E e m
.,f
i I'-,
! ol~,~~hr~=J~ '~~~~~rT~~~~~rT~FT~~~FT~~~r*~~~F¥~Fr~~~ 1 ,I I I ' ,
1 I 1 1 I I I I 1 I 1 I I 1 I I 1 I I 1 I I I I 1
lTime--> 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00
REW427.D V006E15.M Tue May 23 17:20:42 2023 Page 2
REPORT ID: 23E133 Page 25 of 345
Abundance
i I Scan 216 (4.389 min): REW253.D (-)
76
I #17
Reroj
I
49 84
97105 118 131 148 170 I 0 ~ TTT3rr5iTTt-rn'rrrTTT1>TTTTfLfTrl+h-rTi-i-rTTTTnTrTTn-T'lITTTrTTTTT'TTI I I I iii Iii)
!m/z--> 30 70 80 90 100 110 120 130 140 150 160 170
rb-undance.
i I
I Ra~bi
!
r -----_.,
Scan 217 (4.410 min): REW427.D
84
165
I 0 'n-r..-rt'f1f1fLtYl't'W'h'rrt'WfLrrt'f-/-WI+r'1-+'n-TTrrTTTTTTrIT-r'-,CTTTTlI-r· '" 'TT. 1'-' 'fT' TT' I ",J.,-', '" I Tn' • "'1
(m/z--> __ ._3,,-0,--4-,,0,--5,-,0,--6,-,0--=,7-=0---=8,,:,:0~9-'C0~1 0,-,0,:-:-11,-::0=-=1c-=2"70-:-=1,=3-=0--c1-:-4_0~_1c.c5-,-0-,1-,,-6-,,-0 -,1-'..7,,-0--1
Abundance Scan 217 (4.410 min): REW427.D (-)
, I 4f
Sub I I
5°1 4,0
84
Ii
165
(mjz-->
o 'n-r..-rt'I-+Y+Ylll!,l",JJ,-,l,-ljljl/L..H+r4lI+r'1-rrT~CTTTTTTrIT-r-rCTTTTl,-r. n-n I ' ,i, 'I "
_.:=.30=---...:..40=----=-=---=-==---'-=--_-=-='----''-=---'-1 O=O=--:..11'-'0'-'-12~0~13iU_'!0_1~_ 160 170
Abundance Scan 281 (5.751 min): REW253.D (-)
i
Reooi I
j I
1 '
J., .. ~;, .. ~;, .99. JI,"1'~. ,D .. , .. :I~ ... \" .. )2.~ ~n., .'.9~,.
Im/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160
IAbundance Scan 282 (5.773 min): REW427,O
i 4r 63
Ra'&b
I
36 I .55 I
o " I i ~/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 ,--.--;-----''-'------'-''---=-=----'-=-=--'-=~===-==~~'==~~-:::--:~~'-''--'-''-''--'.-=-=-_1
f\bundance Scan 282 (5.773 min): REW427.D (-) ,
I ,
Subl
50: I
Ii
, II 83 i 39 , 53 ,1;1" 76 100 123131
0 1 III 1,,1 I 111.1 .lii1111 i. I if I II,I i III, 'i ~ I I ( Iii I I i~ I I ill i ! r iii Iii i l...,-rT'l"TTTTT',-n .. -T'rTTT", f iii j
im/z-::-? 30 40 50 60 70 80 90 100 110 120 130 140 150 160
Methylene chloride
Concen: 0.26 ug/l
RT: 4.41 min Scan# 217
Delta R.T. 0.02 min
Lab File: REW427.D
Acq: 23 May 2023 4:54 pm
Tgt Ion: 49 Resp: 38281
Ion Ratio Lower Upper
49 100
84 75.0 57.4 117.4
86 47.7 25.5 85.5
bundance Ion 49.00 (48.70 to 49.70): REvV427.Q
Ion 84.00 (83.70 to 84.70): REW427q
Ion 86.00 (85.70 to 86.70): REW427.~
6000 I
4.41 I
11\ .
4000 ~OOI jf\" i b~r J \~'. );1\1''., i o ~_'C_L., __ . i
[ 111 , I I "I' I j-,,-r'T--'--' I
ime--> 4.20 4.30 4.40 4.50 4.60 4.70
#24
1,1-Dichloroethane
Concen: 0.18 ug/l
RT: 5.77 min Scan# 282
Delta R.T. 0.02 min
Lab File: REW427.D
Acq: 23 May 2023 4:54 pm
Tgt Ion: 63 Resp: 41706
Ion Ratio Lower Upper
63 100
65 37.2 1.4 61. 4
83 20.7 0.0 43.0
bundance Ion 63.00 (62.70 to 63.70): REW427.Q
lion 65.00 (64.70 to 65.70): REW427.d
Ion 83.00 (82.70 to 83.70): REW427.Q
8000 !
6000 I
REW427.D V006E15.M Tue May 23 17:20:42 2023 Page 3
REPORT ID: 23E133 Page 26 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
23E133
S13-CAM-DW1-052023
23E133-05
Lab File ID: REW442
Ext Btch ID: V006E20
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
1, 1, 1,2-Tetrachloroethane
1, 1, 1-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloroprofane
2-Butanone (MEK
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Oibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl
n-Butylbenzene
ether (MTBE)
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-l,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1,2,3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Date Collected: 05/15/23 11:35
Date Received: 05/18/23
Date Extracted: OS/24/23 10:59
Date Analyzed: OS/24/23 10:59
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
----------- ----------- ----------- -----------
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
0.12J 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.25 0.50
ND 1.0 0.15 0.30
ND 2.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.50 1.0
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
NO 1.0 0.10 0.20
NO 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
NO 1.0 0.10 0.20
NO 1.0 0.10 0.20
NO 2.0 0.21 0.50
NO 10 2.5 5.0
ND 2.0 0.50 1.0
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
NO 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.11 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 100 25 50
RESULT SPK_AMT %RECOVERY QC LIMIT
----------- ---------------------------------
10.2 10.0 102 70-130
9.84 10.0 98 70-130
10.2 10.0 102 70-130
10.2 10.0 102 70-130
==================================================================================
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E133 Page 27 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW442.D
Acq On 24 May 2023 10:59 am
Sample 23E133-05
Misc 25mL
(QT Reviewed)
Vial: 10
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 11:28 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.10 114 4940168 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 4302652 10.00 ug/l 0.01
73) 1,2-DICHLOROBENZENE-D4 19.43 152 1671023 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1619575 10.15 ug/l 0.02
Spiked Amount 10.000 Recovery :::: 101.50%
41) l,2-Dichloroethane-d4 9.23 65 1126781 10.16 ug/l /~ 0.01
Spiked Amount 10.000 Recovery :::: 101. 6(0%
54) Toluene-d8 12.93 98 5686161 10.18 ug/l 0.01
Spiked Amount 10.000 Recovery 101.80%
76) 4-Bromofluorobenzene 17.56 95 1861398 9.84 ug/ 0.01
Spiked Amount 10.000 Recovery :::: 98. 0%
Target Compounds Qvalue
24) 1,1-Dichloroethane 5.77 63 35707 0.12 ug/l 75
(#) = qualifier out of range (m) :::: manual integration
REW442.D V006E15.M Wed May 24 11:28:58 2023 Page 1
REPORT ID: 23E133 Page 28 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW442.D
Aeq On 24 May 2023 10:59 am
Sample 23E133-05
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
10
LYamas
06
l. 00
MS Integration Params: RTE.P
Quant Time: May 24 11:28 2023 Quant Results File: V006E15.RE
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title METHOD 8260
Last Update Tue May 16 12:41:48 2023
Response via Initial Calibration
~\b-u-n~da-n~ce~------TIC REW4-:-42::-,c:::-O----------------
i
95000001
!
j
9000000]
i
85000001
!
!
80000001
i
7500000j
1
'10000001
65000001
I
60000001
i
I
5500000 1
I
50000001
45000001 ,
40000001
[
35000001
3000000j
i
2500000;
I
20000001
1500000i !
10000001
I
i
5000001
I
OL-r-,
iTime-->
I
iI
!I
'i
II Ii
II
II
II
II
'I
II
II
II
I' II ,I
I!
II
,[
II
II II
II II~\
I!ill!!~i
2,00 4,00
REW442.D V006E15.M
:;,
f-C n:
oi c
'" .c
" e
0 :c
0
9
I
6,00
I
(J)
<1)
" '" ~ e o
:J
'6
E e .n
is
w'
Z
W
N
Z
W co
0
~
0
::::l
...J
LL
0 .t,
(J)
cO
D
'" c g;
(5
f-
Wed May 24 11:29:00 2023
,,' 0 w z
«)' w
0 N
W z
W Z co w 0 N ~ z w 0
ro --'
0 I
cr: 0
9 0
(J) N, I oi 0 c
Q)
~
Q) .n e
0
:J
'6
E e co .t
Page 2
REPORT ID: 23E133 Page 29 of 345
REW442.D V006E15.M Wed May 24 11:29:01 2023 Page 3
REPORT ID: 23E133 Page 30 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
23E133
SWMU-l3-EB-052023
23E133-06
Lab File ID: REW431
Ext Btch ID: V006E19
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
1, 1, 1,2-Tetrachloroethane
I, I, I-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
l,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
ciS-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1, 2, 3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Date Collected: 05/15/23 09:00
Date Received: 05/18/23
Date Extracted: OS/23/23 18:38
Date Analyzed: OS/23/23 18:38
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
----------- ---------------------------------
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.25 0.50
ND 1.0 0.15 0.30
ND 2.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.50 1.0
0.17J 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.21 0.50
ND 10 2.5 5.0
ND 2.0 0.50 1.0
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.11 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 100 25 50
RESULT SPK_AMT %RECOVERY QC LIMIT
--------------------------------------------
10.2 10.0 102 70-130
10.4 10.0 104 70-130
10.3 10.0 103 70-130
10.6 10.0 106 70-130
==================================================================================
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E133 Page 31 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW431.D
Acq On 23 May 2023 6:38 pm
Sample 23E133-06
Misc 25mL
(QT Reviewed)
Vial: 25
Operator: LYamas
Inst 06
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 24 9:06 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 10.10 114 3947190 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 3390039 10.00 ug/l 0.01
73) l,2-DICHLOROBENZENE-D4 19.43 152 1265594 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1357564 10.65 ug/l 0.02
Spiked Amount 10.000 Recovery == 106.50%
41 ) l,2-Dichloroethane-d4 9.23 65 904125 10.20 ug/l 0.01
Spiked Amount 10.000 Recovery == 102.00%
54) Toluene-d8 12.93 98 4543606 10.32 ug/l.-/ 0.01
Spiked Amount 10.000 Recovery == 103.20%
76 ) 4-Bromofluorobenzene 17.56 95 1490982 10.41 uglY 0.01
Spiked Amount 10.000 Recovery == 104 10%
Target Compounds Qvalue
11 ) Acetone 3.51 43 86395 3.46 ug/l 99
13) tert-Butyl alcohol 3.84 59 19937 4.51 ug/l 98
17) Methylene chloride 4.39 49 56702 0.37 ug/l 93
30) Chloroform 7.60 83 40622 0.17 ug/l 89
(#) == qualifier out of range (m) == manual integration
REW431.D V006E15.M Wed May 24 09:06:43 2023 Page 1
REPORT ID: 23E133 Page 32 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW431.D
Aeq On 23 May 2023 6:38 pm
Sample 23E133-06
Mise 25mL
Vial: 25
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 9:06 2023 Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
,
i,rbundance
4200000
,
i
4000000
1
3800000j
i
3600000j
1
34000001
3200000j
i
3000000
2800000
26000001
I
2400000j
I
22000001
I
20000001
I
1800oo0j
i
!
16000001
1400000 1
1200000
10000001
!
j
8000001
i
6000001
400000j
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW431.D
UI z w
N z w
In
0
0::
0
:::l -' LL
~R
Ii
II
(I)
",-
1j c:
til
£;
'" (/) E e "<t-
o "d; " '5 c:
til
E £;
ii '" e
(5 .Q
.c:
0
(5
N_
::;;
::;; .-: ~~ ~
~-'t;: :;;
o 0 1--~8 £ <5
2m Q) g ~-ai <~ :t ~
0 ~ '" :c j!l :;; (J
200000 ~ ~ '"--,." 0
iTime--> 2.00 4.00 6.00 8.00 10.00 12.00
~
14.00
REW431.D V006E15.M Wed May 24 09:06:44 2023
8
uJ z
W
N
Z w
In
0
0::
0 -' I
(J
i
,
(I)
cD c::
re c:
JIl 0 5
" '5
E e
In ..
.,f o
uJ z w
~
W
In o
0:: o -' I
(J
~
~~ ~,~
16.00 18.00 20~00
Page 2
REPORT ID: 23E133 Page 33 of 345
bundance Scan 173 (3.488 min): REW253.D (-)
4
Re !tID
I
58
I 176 190200 ~/Z--> 0 40 60 80 100 120 140 160 1JO I I ~60 I
~bund·~a-nc-e--~~~=---~S~ca-n~1=74~(3~.5=09~m~in~):=R~E~W~4~31~.D~---==-~~~
r
Ra-wo
O .........,.-JlliI""¥'-I"'filI-ll'J'llP"f"'\~ J ~~IIiII".",~tll"""~I~'O, ", "..: ~~,1,,3'?I~,4~ .. J.,~P .!, ~1" I , 1Uf-U1 (1 iii r Ii r I i,. ii" I i i i { Ii, I mlz-->
Abundance
Sub
50
ibundance
I Re~
40
r
60 80 100 120 140 160 180 200
Scan 174 (3.509 min): REW431.D (-)
Scan 188 (3.802 min): REW253.D (-)
60 70 80 90 100 11 0 120 130 140 150
Scan 190 (3.845 min): REW431.D
I! 1'1 I "1' I
Iz--> 30 40 50 60 70 80 90 100 11 0 120 130 140 150
bundance
Sub
50
Iz-->
I 47
Scan 190 (3.845 min): REW431.D (-)
5
79
#11
Acetone
Concen: 3.46 ug/l
RT: 3.51 min Scan# 174
Delta R.T. 0.02 min
Lab File: REW431.D
Acq: 23 May 2023 6:38 pm
Tgt
Ion
43
58
Ion: 43
Ratio
100
29.7
Resp:
Lower
0.1
86395
Upper
60.1
bundance Ion 43.00 (42.70 to 43.70): REW431
30000 Ion 58.00 (57.70 to 58.70): REW431
3.51
A \
25000
20000
10000
5000
ime-->
#13
tert-Butyl alcohol
Concen: 4.51 ug/l
RT: 3.84 min Scan# 190
Delta R.T. 0.04 min
Lab File: REW431.D
Acq: 23 May 2023 6:38 pm
Tgt
Ion
59
57
Ion: 59
Ratio
100
9.3
Resp:
Lower
0.0
19937
Upper
38.6
bundance Ion 59.00 (58.70 to 59.70): REw4311
3000 Ion 57.00 (56.70 to 57.70): REW431'~I'
3.84
2500 I
ime-->
REW431.D V006E15.M Wed May 24 09:06:44 2023 Page 3
REPORT ID: 23E133 Page 34 of 345
Abundance Scan 216 (4.389 min): REW253.D-(~)~--------------l
, Rem 7r
#17
I 49 II 84
: I I' oi, 'I ?'~II' 1 ,111/ ' "I ?,~, I " III' III' '~:I ~?~~~r~T"I' , ,1,~O III
Im/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170._
~bundance Scan 216 (4.390 min): REW43TD
· I f
I i 84
RaWo]
I I I 76 i
Methylene chloride
Concen: 0.37 ug/l
RT: 4.39 min Scan# 216
Delta R.T. 0.00 min
Lab File: REW431.D
Acq: 23 May 2023 6:38 pm
Tgt Ion: 49 Resp: 56702
Ion Ratio Lower Upper
49 100
84 79.8 57.4 117.4
86 51. 9 25.5 85.5
f\bUndance Ion 49.00 (48.70 to 49.70): REW431~q
Ion 84.00 (83.70 to 84.70): REW431.q
10000 Ion 86.00 (85.70 to 86.70): REW431.q I 36 'Ui i55 6,7 i !. 94 111 128 141 fnf~--_>_~~3_' '0_' ,_114_~~_50_111i,1:6S '_'17_I
'O_! I_I~'O_III :9_! 'a_I '~'T_O~_' 1_1~0_1_2~_'1\j~C1'~~=;~_1_'~_O'_'1'lC 8000 1 4i~9
,lAbundance Scan 216 (4.390 min): REW43·1.D H I 1/\
,
T 6000 II :, ~\\
84 '/ '\
I I 1 11[, \\
SUb50 11
II' 1 4000 1 1,/ \ r\
Jli \V\~\ : I I I ill '-\ \ i
I 2000; U \~ I J,~T,,,I~j~l,,I,"I,,~,T, 1'~ ~~1""n""'T'P"" ob& I ,~~(''(C~
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 ifime--> 4.20 4.30 4.40 4.50 4.60 4.70 -.J i [m/z-->
~bun-dance Scan 368 (7.575 min): REW253.D (-) ~I ' RJ 8~
,i II I
: i 47 1\ i
i I I I 67 II ~
I 01, I' '~'~IIII" \1 1 ~4,'MT~~' I:R511 ~,l~rTTT""I1~,~,1~711 'I" ,1~~T
[rnk:::~..~.'L1Q.."'®"" 60 7Q.. 80 90 100 11 0 120130 1491~ 60 170180 190
'lAbundance Scan 369 (7.596 min): REW431.D
• i 4~ 8~ !
#30
Chloroform
Concen: 0.17 ug/l
RT: 7.60 min Scan# 369
Delta R.T. 0.02 min
Lab File: REW431.D
Acq: 23 May 2023 6:38 pm
Tgt Ion: 83 Resp: 40622
Ion Ratio Lower Upper
83 100
85 75.9 38.7 98.7
: !, I I I
· Rawoj Ii I II i~bu-n~da-n-c-e-lo-n-8-3-.0-0-(8-2-.7-0-to-8-3-.7-0-):-R-EW~43To
1 I' 'I '00 85,00 (84 7010 85 70) REW 431 ,0
47 31. 6 0.0 53.2
I 0 I , I ' ,I""llli"11111,,r, I'" n:, ,I ),1,1, ,;,4" , , , I ' , :,f: "P''' I ,"~,~" I' , , , I' "I' 10000 '00 47,00 (467:~: 47.70). REW 431G
/r'/z--> 30 40 50 60 70 80 90 100 110 120 130 149_15_0 .155Q_17_0_1 =.;80=...1-,-,9,-,-0_-1 8000 ~, i
ilAbundance sca~r369 (7.596 min): REW431.D (-) I \
6000 \,
1 ' /"\ \ SU~oj II 40001 !/ \ \ ,
I 47 2000J . II (\ \\ I
I I ; \, \\
01 ~O ~~~ 1 ,~t~~ ~:~~1119b ;'bO ;'j 0 :,~~ ;'~o ;10 ;'~o ;'tkl;'jo ;'Jo ;',\0 , , I' ImH 0~60 ~'tV;.
REW431.D V006E15.M Wed May 24 09:06:45 2023 Page 4
REPORT ID: 23E133 Page 35 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
BRICE
TEAD-S
Client
Project
Batch No.
Sample ID :
Lab Samp ID:
Lab File ID:
23E133
TB-20230515-13
23E133-07
REW430
Ext Btch ID: V006E19
Calib. Ref.: REW253
PARAMETER(S)
------------------------------
1, 1, l,2-Tetrachloroethane
1,1,1-Trichloroethane
l,l,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
l,l-Dichloroethene
l,l-Dichloropropene
1, 2, 3-Trichloropropane
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
l,2-Dichlorobenzene
1,2-Dichloroethane
l,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-DiChloroprofane
2-Butanone (MEK
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Brornomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-l,2-Dichloroethene
ciS-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-l,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1, 2, 3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER(S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Date Collected:
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Matrix:
% Moisture:
Instrument ID:
RESULTS LOQ
(ug/L) (ug/L)
----------------------
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 2.0
ND 1.0
ND 2.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 20
ND 1.0
ND 20
ND 1.0
ND 20
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 2.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 2.0
ND 10
ND 2.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 1.0
ND 100
RESULT SPK_AMT
----------------------
10.0 10.0
10.3 10.0
10.2 10.0
10.3 10.0
05/15/23 07:30
05/18/23
OS/23/23 18:12
OS/23/23 18:12
1
WATER
NA
06
DL
(ug/L)
LaD
(ug/L)
----------------------
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.25 0.50
0.15 0.30
0.25 0.50
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.25 0.50
5.0 10
0.25 0.50
5.0 10
0.25 0.50
5.0 10
0.10 0.20
0.10 0.20
0.15 0.30
0.10 0.20
0.15 0.30
0.25 0.50
0.25 0.50
0.10 0.20
0.10 0.20
0.50 1.0
0.10 0.20
0.25 0.50
0.10 0.20
0.10 0.20
0.10 0.20
0.10 0.20
0.25 0.50
0.10 0.20
0.10 0.20
0.21 0.50
2.5 5.0
0.50 1.0
0.15 0.30
0.25 0.50
0.25 0.50
0.10 0.20
0.25 0.50
0.25 0.50
0.25 0.50
0.25 0.50
0.15 0.30
0.10 0.20
0.10 0.20
0.25 0.50
0.10 0.20
0.25 0.50
0.11 0.30
0.10 0.20
0.15 0.30
25 50
%-RECOVERY QC LIMIT
----------------------
100 70-130
103 70-130
102 70-130
103 70-130
==================================================================================
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E133 Page 36 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW430.D
Acq On 23 May 2023 6: 12 pm ~.
Sample 23E133-07
Misc 25mL
(QT Reviewed)
Vial: 24
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 9:04 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.10 114 4065134 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 3532734 10.00 ug/l 0.01
73) 1,2-DICHLOROBENZENE-D4 19.43 152 1291764 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1358692 10.35 ug/l 0.02
Spiked Amount 10.000 Recovery = 103.50Yr
41 ) 1,2-Dichloroethane-d4 9.23 65 913819 10.01 ug/l 0.01
Spiked Amount 10.000 Recovery = 100.1~
54) Toluene-d8 12.93 98 4700776 10.25 ug/l 0.01 .
Spiked Amount 10.000 Recovery = 102. JO%
76) 4-Bromofluorobenzene 17.56 95 1511718 10.34 ug/l 0.01
Spiked Amount 10.000 Recovery = 10:;40%
Target Compounds Qvalue
17) Methylene chloride 4.41 49 61155 0.38 ug/l 89
(#) = qualifier out of range (m) = manual integration
REW430.D V006E15.M Wed May 24 09:04:30 2023 Page 1
REPORT ID: 23E133 Page 37 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW430.D
Aeq On 23 May 2023 6:12 pm
Sample 23E133-07
Mise 2SmL
Vial: 24
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 9:04 2023 Quant Results File: V006E1S.RE
Method
Title
Last Update
_~ Response via
fAbundance
14~ool
. 40000001
i
38000001
3600000j
34000001
3200000
3000000
2800000
26000001
24000001
22000001
20000001
I
18000001
16000001
1400000
1200000
I
10000001
I
800000j
6000001
I
400000
D:\HPCHEM\1\METHODS\V006E1S.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW430,D
li"i"
i
~ o
3 u.
~-
(RTE Integrator)
~-
m
~ ro o
9
I o
.,f o
u'J z w
!?!
ill o oc
9
I o
is N_
REW430.D V006E1S.M Wed May 24 09:04:32 2023 Page 2
REPORT ID: 23E133 Page 38 of 345
~bundance
j
ReOO
0
Iz-->
bundance
I
RaWo
30
49
40 50 60
40
Scan 216 (4.389 min): REW253.D (-)
7
70 80 90 100 110 120 130 140 150 160 170 180 190
Scan 217 (4.411 min): REW430.D
84
94 121 170 191
i O'n-rrrt't"IWt'li'WtY"P/+I't'ff,'H'Pt'I't'HYrhl ,'h'II'" 'TT' 'TTI'TT' .TT· In', 'TTl' , :,..n'Tn'TT'T~: ' , , , I " 'I"" '" ' " I
im/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190
~bundance Scan 217 (4.411 min): REW430.D (-)
I 4 ~
Sub
50
Iz-->
#17
Methylene chloride
Concen: 0.38 ug/l
RT: 4.41 min Scan# 217
Delta R. T. O-.OT-m.in--
Lab File: REW430.D
Acq: 23 May 2023 6:12 pm
Tgt Ion: 49 Resp: 61155
Ion Ratio Lower Upper
49 100
84 76.4 57.4 117.4
86 47.9 25.5 85.5
bundance Ion 49.00 (48.70 to 49.70): REW430.
jlOn 84.00 (83.70 to 84.70): REW430.q
12000 Ion 86.00 (85.70 to 86.70): REW430.~
10000 4.41 I
ime--> 4.20 4.40 4.60 4.80
REW430.D V006E15.M Wed May 24 09:04:33 2023 Page 3
REPORT ID: 23E133 Page 39 of 345
QC SUMMARIES
REPORT ID: 23E133 Page 40 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client
Project
Batch No.
Sample ID .
Lab Samp ID:
Lab File ID:
Ext Btch ID:
Calib. Ref.:
PARAMETER(S)
BRICE
TEAD-S
23E133
MBLK1W
V006E19B
REW412
V006E19
REW253
------------------------------
1, 1, 1,2-Tetrachloroethane
1, 1, 1-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1, 2, 3-Trichloropropane
l,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
l,3-Dichlorobenzene
1,3-Dichloropropane
l,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Ch1oroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xylene
4-Methyl-2-Pentanone
Methylene Chloride
Methyl tert-butyl
n-Butylbenzene
ether (MTBE)
n-Propylbenzene
o-Xylene
p-Isopropyltoluene
Sec-Butylbenzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-l,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1, 2, 3-Trichlorobenzene
1,4-Dioxane
SURROGATE PARAMETER (S)
----------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Date Collected: OS/23/23 10:25
Date Received: OS/23/23
Date Extracted: OS/23/23 10:25
Date Analyzed: OS/23/23 10:25
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL
(ug/L) (ug/L) (ug/L)
LOD
(ug/L)
---------------------- ----------------------
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.25 0.50
ND 1.0 0.15 0.30
ND 2.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.25 0.50
ND 20 5.0 10
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.50 1.0
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 2.0 0.21 0.50
ND 10 2.5 5.0
ND 2.0 0.50 1.0
ND 1.0 0.15 0.30
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.25 0.50
ND 1.0 0.15 0.30
ND 1.0 0.10 0.20
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.10 0.20
ND 1.0 0.25 0.50
ND 1.0 0.11 0.30
ND 1.0 0.10 0.20
ND 1.0 0.15 0.30
ND 100 25 50
RESULT SPK_AMT %RECOVERY QC LIMIT
----------- ---------------------------------
9.57 10.0 96 70-130
10.1 10.0 101 70-130
10.6 10.0 106 70-130
10.0 10.0 100 70-130
==================================================================================
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E133 Page 41 of 345
EMAX QUALITY CONTROL DATA
LAB CONTROL SAMPLE ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E133
METHOD SW5030B/8260C
=============== =================================================================================================================
MATRIX WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID MBLK1W LCS1W LCD1W
LAB SAMPLE ID V006E19B V006E19L V006E19C
LAB FILE ID REW412 REW409 REW410
DATE PREPARED OS/23/23 10:25 OS/23/23 09:07 OS/23/23 09:33
DATE ANALYZED OS/23/23 10:25 OS/23/23 09:07 OS/23/23 09:33
PREP BATCH V006E19 V006E19 V006E19
CALIBRATION REF: REW253 REW253 REW253
ACCESSION:
MBResult SpikeAmt LCSResult LCSRee SpikeAmt LCDResult LCDRee RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%) (%) (%)
----------------------------------------------------------------------------------------------
1,1,1,2-Tetraehloroethane ND 10.0 9.24 92 10.0 9.38 94 2 78-124 20
1,1,1-Triehloroethane ND 10.0 8.95 90 10.0 8.90 89 1 74-l31 20
1, 1,2, 2-Tetrachloroethane ND 10.0 9.98 100 10.0 10.1 101 1 71-121 20
1,1,2-Triehloroethane ND 10.0 9.68 97 10.0 9.59 96 1 80-119 20
1,1-Diehloroethane ND 10.0 10.1 101 10.0 10.3 103 2 77-125 20
1,1-Diehloroethene ND 10.0 10.1 101 10.0 10.1 101 0 71-131 20
1,1-Dichloropropene ND 10.0 10.3 103 10.0 10.2 102 1 79-125 20
1,2,3-Trichlorobrop ane ND 10.0 9.53 95 10.0 9.80 98 3 73-122 20
l,2,4-Trichloro enzene ND 10.0 9.92 99 10.0 9.75 98 2 69-l30 20
1,2-Dibromo-3-chloropropane ND 10.0 9.23 92 10.0 8.72 87 6 62-128 20
1,2-Dichlorobenzene ND 10.0 10.5 105 10.0 10.6 106 1 80-119 20
1,2-Dichloroethane ND 10.0 10.4 104 10.0 10.4 104 0 73-128 20
1,2-Dichloropropane ND 10.0 10.5 105 10.0 10.4 104 1 78-122 20
1,3-Diehlorobenzene ND 10.0 10.5 105 10.0 10.5 105 0 80-119 20
1,3-Dichlorobrop ane ND 10.0 10.4 104 10.0 10.1 101 3 80-119 20
1,4-Dichloro enzene ND 10.0 10.4 104 10.0 10.4 104 0 79-118 20
2,2-Dichloroprofane ND 10.0 10.3 103 10.0 10.3 103 0 60-l39 20
2-Butanone (MEK ND 50.0 54.1 108 50.0 51. 9 104 4 56-143 20
2-Chlorotoluene ND 10.0 9.87 99 10.0 9.79 98 1 79-122 20
2-Hexanone ND 50.0 52.5 105 50.0 51.8 104 1 57-l39 20
4-Chlorotoluene ND 10.0 11.0 110 10.0 11.2 112 2 78-122 20
Acetone ND 50.0 50.1 100 50.0 49.9 100 0 39-160 20
Benzene ND 10.0 10.2 102 10.0 10.2 102 0 79-120 20
Bromobenzene ND 10.0 9.93 99 10.0 10.0 100 1 80-120 20
Bromochloromethane ND 10.0 10.0 100 10.0 9.98 100 0 78-123 20
Bromodichloromethane ND 10.0 9.56 96 10.0 9.61 96 1 79-125 20
Bromoform ND 10.0 9.44 94 10.0 9.52 95 1 66-130 20
Bromomethane ND 10.0 9.47 95 10.0 9.00 90 5 53-141 20
Carbon Disulfide ND 10.0 9.87 99 10.0 9.23 92 7 64-133 20
Carbon Tetrachloride ND 10.0 9.50 95 10.0 9.53 95 0 72-136 20
Chlorobenzene ND 10.0 10.3 103 10.0 10.4 104 1 82-118 20
Chloroethane ND 10.0 9.69 97 10.0 9.10 91 6 60-138 20
Chloroform ND 10.0 9.78 98 10.0 9.77 98 0 79-124 20
Chloromethane ND 10.0 10.3 103 10.0 10.0 100 3 50-139 20
cis-1,2-Dichloroethene ND 10.0 10.2 102 10.0 10.2 102 0 78-123 20
cis-1,3-Diehloropropene ND 10.0 10.1 101 10.0 10.1 101 0 75-124 20
Dibromoehloromethane ND 10.0 9.86 99 10.0 9.62 96 2 74-126 20
Dibromomethane ND 10.0 9.83 98 10.0 9.82 98 0 79-123 20
Dichlorodifluoromethane ND 10.0 10.9 109 10.0 10.6 106 3 32-152 20
Ethylbenzene ND 10.0 9.86 99 10.0 9.98 100 1 79-121 20
Isopropylbenzene ND 10.0 9.81 98 10.0 9.91 99 1 72-131 20
m,p-Xhlene ND 20.0 20.0 100 20.0 20.4 102 2 80-121 20
4-Met yl-2-Pentanone ND 50.0 56.0 112 50.0 54.2 108 3 67-130 20
Methylene Chloride ND 10.0 10.5 105 10.0 10.5 105 0 74-124 20
Methyl tert-butyl ether (MTBE) ND 10.0 10.1 101 10.0 10.1 101 0 71-124 20
n-Butylbenzene ND 10.0 10.1 101 10.0 10.2 102 1 75-128 20
n-Propylbenzene ND 10.0 9.78 98 10.0 9.98 100 2 76-126 20
o-Xylene ND 10.0 9.63 96 10.0 9.74 97 1 78-122 20
p-ISOpro~Yltoluene ND 10.0 9.89 99 10.0 9.86 99 0 77-127 20
Sec-Buty benzene ND 10.0 9.61 96 10.0 9.65 97 0 77-126 20
Styrene ND 10.0 9.98 100 10.0 10.1 101 1 78-123 20
Tert-Butylbenzene ND 10.0 9.44 94 10.0 9.78 98 4 78-124 20
Tetrachloroethene ND 10.0 9.71 97 10.0 9.94 99 2 74-129 20
Toluene ND 10.0 10.2 102 10.0 10.3 103 1 80-121 20
Trans-1,2-Dichloroethene ND 10.0 10.1 101 10.0 10.1 101 0 75-124 20
Trans-l,3-Dichloropropene ND 10.0 9.98 100 10.0 9.89 99 1 73-127 20
Trichloroethene ND 10.0 10.1 101 10.0 10.1 101 0 79-123 20
Trichlorofluoromethane ND 10.0 9.32 93 10.0 8.66 87 7 65-141 20
Vinyl Chloride ND 10.0 9.20 92 10.0 8.89 89 3 58-137 20
1,2-Dibromoethane ND 10.0 9.83 98 10.0 10.1 101 3 77-121 20
l,2,3-Trichlorobenzene ND 10.0 10.0 100 10.0 9.81 98 2 69-129 20
1,4-Dioxane ND 200 193 97 200 181 91 6 59-139 20
SpikeAmt LCSResult LCSRee SpikeAmt LCDResult LCDRec QCLimit
SURROGATE PARAMETERS (ug/L) (ug/L) (%) (ug/L) (ug/L) (") (%)
---------------------------------------------------------------------------
1,2-Dichloroethane-d4 10.0 9.87 99 10.0 9.83 98 70-130
4-Bromofluorobenzene 10.0 10.3 103 10.0 10.2 102 70-130
Toluene-d8 10.0 10.2 102 10.0 10.2 102 70-130
Dibromofluoromethane 10.0 10.2 102 10.0 9.88 99 70-130
ME: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
REPORT ID: 23E133 Page 42 of 345
METHOD SW5030B/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE
Project TEAD-S
Batch No. 23E133
Sample ID MBLK2W
Lab Samp ID: V006E20B
Lab File ID: REW438
Ext Btch ID: V006E20
Calib. Ref. : REW253
PARAMETER(S)
------------------------------
1,1, 1, 2-Tetrachloroethane
l,l,I-Trichloroethane
1, 1, 2, 2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichloropropane
1, 2, 4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
m,p-Xhlene
4-Met yl-2-Pentanone
Methylene Chloride
Methyl tert-butyl ether (MTBE)
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-ISOprO~Yltoluene
Sec-Buty benzene
Styrene
Tert-Butylbenzene
Tetrachloroethene
Toluene
Trans-1,2-Dichloroethene
Trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Chloride
1,2-Dibromoethane
1,2,3-Trichlorobenzene
l,4-Dioxane
SURROGATE PARAMETER (S)
------------------------------
1,2-Dichloroethane-d4
4-Bromofluorobenzene
Toluene-d8
Dibromofluoromethane
Notes:
Sample Amount : 25ml
Prepared by : LYamas
Detection limits are reported
Date Collected: OS/24/23 09:15
Date Received: OS/24/23
Date Extracted: OS/24/23 09:15
Date Analyzed: OS/24/23 09:15
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 06
RESULTS LOQ DL LOD
(ug/L) (ug/L) (ug/L) (ug/L)
---------------------- ----------------------
ND l.0 0.10 0.20
ND l.0 0.10 . 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND 2.0 0.25 0.50
ND l.0 0.15 0.30
ND 2.0 0.25 0.50
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.25 0.50
ND 20 5.0 10
ND l.0 0.25 0.50
ND 20 5.0 10
ND l.0 0.25 0.50
ND 20 5.0 10
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.15 0.30
ND l.0 0.10 0.20
ND l.0 0.15 0.30
ND l.0 0.25 0.50
ND l.0 0.25 0.50
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND 2.0 0.50 l.0
ND l.0 0.10 0.20
ND l.0 0.25 0.50
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.25 0.50
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND 2.0 0.21 0.50
ND 10 2.5 5.0
ND 2.0 0.50 l.0
ND l.0 0.15 0.30
ND l.0 0.25 0.50
ND l.0 0.25 0.50
ND l.0 0.10 0.20
ND l.0 0.25 0.50
ND l.0 0.25 0.50
ND l.0 0.25 0.50
ND l.0 0.25 0.50
ND l.0 0.15 0.30
ND l.0 0.10 0.20
ND l.0 0.10 0.20
ND l.0 0.25 0.50
ND l.0 0.10 0.20
ND l.0 0.25 0.50
ND l.0 0.11 0.30
ND l.0 0.10 0.20
ND l.0 0.15 0.30
ND 100 25 50
RESULT SPK_AMT %RECOVERY QC LIMIT
--------------------------------------------
9.61 10.0 96 70-130
10.1 10.0 101 70-130
10.3 10.0 103 70-130
10.0 10.0 100 70-130
Final Volume : 25ml
Analyzed by : LYamas
relative to sample result significant figures.
REPORT ID: 23E133 Page 43 of 345
EMAX QUALITY CONTROL DATA
LAB CONTROL SAMPLE ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E133
METHOD SW5030B/8260C
=============== =================================================================================================================
MATRIX WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID MBLK2W LCS2W LCD2W
LAB SAMPLE ID V006E20B V006E20L V006E20C
LAB FILE ID REW438 REW435 REW436
DATE PREPARED OS/24/23 09:15 OS/24/23 07:57 OS/24/23 08:23
DATE ANALYZED OS/24/23 09:15 OS/24/23 07:57 OS/24/23 08:23
PREP BATCH V006E20 V006E20 V006E20
CALIBRATION REF: REW253 REW253 REW253
ACCESSION:
MEResult SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%) (%) (%)
----------------------------------------------------------------------------------------------
1, 1, 1, 2-Tetrachloroethane ND 10.0 9.73 97 10.0 9.37 94 4 78-124 20
1,1, I-Trichloroethane ND 10.0 10.1 101 10.0 8.81 88 14 74-131 20
1, 1, 2, 2-Tetrachloroethane ND 10.0 10.3 103 10.0 9.81 98 5 71-121 20
1,1,2-Trichloroethane ND 10.0 9.84 98 10.0 9.56 96 3 80-ll9 20
1,1-Dichloroethane ND 10.0 10.4 104 10.0 9.94 99 5 77-125 20
1,1-Dichloroethene ND 10.0 10.2 102 10.0 9.72 97 5 71-131 20
1,1-Dichloropropene ND 10.0 10.6 106 10.0 10.1 101 5 79-125 20
1,2,3-Trichloropropane ND 10.0 10.0 100 10.0 9.53 95 5 73-122 20
1,2,4-Trichlorobenzene ND 10.0 9.64 96 10.0 9.61 96 0 69-130 20
1,2-Dibromo-3-chloropropane ND 10.0 9.37 94 10.0 8.78 88 7 62-128 20
l,2-Dichlorobenzene ND 10.0 10.9 109 10.0 10.4 104 5 80-ll9 20
1,2-Dichloroethane ND 10.0 10.6 106 10.0 10.3 103 3 73-128 20
1,2-Dichloropropane ND 10.0 10.6 106 10.0 10.2 102 4 78-122 20
1,3-Dichlorobenzene ND 10.0 10.7 107 10.0 10.3 103 4 80-ll9 20
1,3-Dichloropropane ND 10.0 10.6 106 10.0 10.2 102 4 80-ll9 20
1,4-Dichlorobenzene ND 10.0 10.7 107 10.0 10.3 103 4 79-ll8 20
2,2-Dichloropropane ND 10.0 10.6 106 10.0 10.2 102 4 60-139 20
2-Butanone (MEK) ND 50.0 52.5 105 50.0 50.1 100 5 56-143 20
2-Chlorotoluene ND 10.0 9.78 98 10.0 9.80 98 0 79-122 20
2-Hexanone ND 50.0 53.1 106 50.0 50.5 101 5 57-139 20
4-Chlorotoluene ND 10.0 11. 3 ll3 10.0 10.7 107 5 78-122 20
Acetone ND 50.0 49.6 99 50.0 49.3 99 1 39-160 20
Benzene ND 10.0 10.4 104 10.0 9.99 100 4 79-120 20
Bromobenzene ND 10.0 10.2 102 10.0 9.76 98 4 80-120 20
Bromochloromethane ND 10.0 10.2 102 10.0 9.68 97 5 78-123 20
Bromodichloromethane ND 10.0 10.0 100 10.0 9.47 95 5 79-125 20
Bromoform ND 10.0 9.82 98 10.0 9.24 92 6 66-130 20
Bromomethane ND 10.0 8.98 90 10.0 9.64 96 7 53-141 20
Carbon Disulfide ND 10.0 9.61 96 10.0 8.79 88 9 64-133 20
Carbon Tetrachloride ND 10.0 9.85 99 10.0 9.47 95 4 72-136 20
Chlorobenzene ND 10.0 10.8 108 10.0 10.5 105 3 82-ll8 20
Chloroethane ND 10.0 8.99 90 10.0 9.53 95 6 60-138 20
Chloroform ND 10.0 10.1 101 10.0 9.70 97 4 79-124 20
Chloromethane ND 10.0 10.2 102 10.0 10.8 108 6 50-139 20
cis-1,2-Dichloroethene ND 10.0 10.5 105 10.0 9.92 99 6 78-123 20
cis-1,3-Dichloropropene ND 10.0 10.3 103 10.0 9.99 100 3 75-124 20
Dibromochloromethane ND 10.0 10.3 103 10.0 9.75 98 5 74-126 20
Dibromomethane ND 10.0 9.97 100 10.0 9.75 98 2 79-123 20
Dichlorodifluoromethane ND 10.0 10.6 106 10.0 11.1 III 5 32-152 20
Ethylbenzene ND 10.0 10.1 101 10.0 9.83 98 3 79-121 20
Isopropylbenzene ND 10.0 9.79 98 10.0 9.68 97 1 72-131 20
m,p-Xylene ND 20.0 20.7 104 20.0 19.8 99 4 80-121 20
4-Methyl-2-Pentanone ND 50.0 55.1 llO 50.0 52.1 104 6 67-130 20
Methylene Chloride ND 10.0 10.6 106 10.0 10.3 103 3 74-124 20
Methyl tert-butyl ether (MTBE) ND 10.0 10.1 101 10.0 9.76 98 3 71-124 20
n-Butylbenzene ND 10.0 9.32 93 10.0 9.94 99 6 75-128 20
n-Propylbenzene ND 10.0 9.79 98 10.0 9.71 97 1 76-126 20
o-Xylene ND 10.0 9.91 99 10.0 9.58 96 3 78-122 20
p-Isopropyltoluene ND 10.0 9.43 94 10.0 9.93 99 5 77-127 20
Sec-Butylbenzene ND 10.0 8.98 90 10.0 9.52 95 6 77-126 20
Styrene ND 10.0 10.3 103 10.0 9.92 99 4 78-123 20
Tert-Butylbenzene ND 10.0 9.35 94 10.0 9.25 93 1 78-124 20
Tetrachloroethene ND 10.0 10.2 102 10.0 9.66 97 5 74-129 20
Toluene ND 10.0 10.7 107 10.0 10.2 102 5 80-121 20
Trans-1,2-Dichloroethene ND 10.0 10.3 103 10.0 9.89 99 4 75-124 20
Trans-1,3-Dichloropropene ND 10.0 10.5 105 10.0 9.94 99 5 73-127 20
Trichloroethene ND 10.0 10.4 104 10.0 10.0 100 4 79-123 20
Trichlorofluoromethane ND 10.0 8.83 88 10.0 9.51 95 7 65-141 20
Vinyl Chloride ND 10.0 8.96 90 10.0 9.51 95 6 58-137 20
1,2-Dibromoethane ND 10.0 10.4 104 10.0 9.78 98 6 77-121 20
1, 2, 3-Trichlorobenzene ND 10.0 9.57 96 10.0 9.60 96 0 69-129 20
1,4-Dioxane ND 200 192 96 200 187 94 3 59-139 20
SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCDRec QCLimit
SURROGATE PARAMETERS (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%)
--------------------------------------------------------------------------
1,2-Dichloroethane-d4 10.0 9.76 98 10.0 9.92 99 70-130
4-Bromofluorobenzene 10.0 10.1 101 10.0 9.93 99 70-130
Toluene-d8 10.0 10.4 104 10.0 10.3 103 70-130
Dibromofluoromethane 10.0 9.99 100 10.0 9.94 99 70-130
ME: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
REPORT ID: 23E133 Page 44 of 345
EMAX QUALITY CONTROL DATA
MS/MSD ANALYSIS
CLIENT BRICE
PROJECT TEAD-S
BATCH NO. 23E133
METHOD SW5030B/8260C
====:::::========== =================================================================================================================
MATRIX WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID S13-CAM-DW1-052023 S13-CAM-DW1-052023MS S13-CAM-DWI-052023MSD
LAB SAMPLE ID 23E133-05 23E133-05M 23E133-05S
LAB FILE ID REW442 REW447 REW448
DATE PREPARED OS/24/23 10:59 OS/24/23 13:09 OS/24/23 13:35
DATE ANALYZED OS/24/23 10:59 OS/24/23 13: 09 OS/24/23 13 :35
PREP BATCH V006E20 V006E20 V006E20
CALIBRATION REF: REW253 REW253 REW253
ACCESSION:
PSResult SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%) (%) (%)
------------------------------------------------------------------------------------------------------
1, 1, l,2-Tetrachloroethane ND 10.0 9.06 91 10.0 8.98 90 1 78-124 20
1,1,1-Trichloroethane ND 10.0 7.80 78 10.0 7.73 77 1 74-131 20
1,1,2,2-Tetrachloroethane ND 10.0 9.99 100 10.0 9.62 96 4 71-121 20
1,1,2-Trichloroethane ND 10.0 9.35 94 10.0 9.19 92 2 80-119 20
1,1-Dichloroethane o .1l7J 10.0 9.52 94 10.0 9.43 93 1 77-125 20
1,1-Dichloroethene NO 10.0 9.17 92 10.0 9.18 92 0 71-131 20
1,1-Dichloropropene ND 10.0 8.66 87 10.0 8.62 86 0 79-125 20
1,2,3-Trichloropropane ND 10.0 9.24 92 10.0 8.67 87 6 73-122 20
1, 2, 4-Trichlorobenzene NO 10.0 9.04 90 10.0 8.76 88 3 69-130 20
1,2-Dibromo-3-chloropropane ND 10.0 8.74 87 10.0 8.40 84 4 62-128 20
1,2-Dichlorobenzene ND 10.0 9.28 93 10.0 8.97 90 3 80-119 20
1,2-Dichloroethane ND 10.0 9.27 93 10.0 9.11 91 2 73-128 20
1,2-Dichloropr opane ND 10.0 9.72 97 10.0 9.63 96 1 78-122 20
1,3-Dichlorobenzene ND 10.0 9.05 91 10.0 8.82 88 3 80-119 20
1,3-Dichloropropane ND 10.0 9.71 97 10.0 9.42 94 3 80-119 20
1,4-Dichlorobenzene ND 10.0 9.04 90 10.0 8.73 87 3 79-118 20
2,2-Dichloropropane ND 10.0 8.74 87 10.0 8.70 87 0 60-139 20
2-Butanone (MEK) NO 50.0 48.3 97 50.0 49.9 100 3 56-143 20
2-Chlorotoluene ND 10.0 8.41 84 10.0 8.27 83 2 79-122 20
2-Hexanone ND 50.0 48.5 97 50.0 51. 5 103 6 57-139 20
4-Chlorotoluene ND 10.0 9.42 94 10.0 9.14 91 3 78-122 20
Acetone ND 50.0 42.9 86 50.0 45.3 91 5 39-160 20
Benzene ND 10.0 9.47 95 10.0 9.29 93 2 79-120 20
Bromobenzene ND 10.0 8.87 89 10.0 8.71 87 2 80-120 20
Bromochloromethane ND 10.0 9.37 94 10.0 9.23 92 2 78-123 20
Bromodichloromethane ND 10.0 9.01 90 10.0 8.90 89 1 79-125 20
Bromoform ND 10.0 8.46 85 10.0 8.32 83 2 66-130 20
Bromomethane ND 10.0 9.68 97 10.0 10.5 105 8 53-l41 20
Carbon Disulfide ND 10.0 9.43 94 10.0 8.71 87 8 64-133 20
Carbon Tetrachloride ND 10.0 8.44 84 10.0 8.25 83 2 72-136 20
Chlorobenzene ND 10.0 9.27 93 10.0 9.17 92 1 82-118 20
Chloroethane ND 10.0 9.55 96 10.0 10.4 104 9 60-138 20
Chloroform ND 10.0 9.08 91 10.0 9.06 91 0 79-124 20
Chloromethane ND 10.0 10.8 108 10.0 12.0 120 11 50-139 20
cis-1,2-Dichloroethene ND 10.0 9.42 94 10.0 9.27 93 2 78-123 20
cis-1,3-Dichloropropene ND 10.0 9.56 96 10.0 9.36 94 2 75-124 20
Dibromochloromethane ND 10.0 9.02 90 10.0 8.97 90 1 74-126 20
Dibromomethane ND 10.0 9.49 95 10.0 9.26 93 2 79-123 20
Dichlorodifluoromethane ND 10.0 9.51 95 10.0 10.5 105 10 32-152 20
Ethylbenzene ND 10.0 8.96 90 10.0 8.96 90 0 79-121 20
Isopropylbenzene ND 10.0 8.82 88 10.0 8.78 88 0 72-131 20
m,p-Xylene ND 20.0 18.6 93 20.0 18.3 92 2 80-121 20
4-Methyl-2-Pentanone ND 50.0 51. 9 104 50.0 54.1 108 4 67-130 20
Methylene Chloride ND 10.0 9.45 95 10.0 9.30 93 2 74-124 20
Methyl tert-butyl ether (MTBE) ND 10.0 9.92 99 10.0 9.81 98 1 71-124 20
n-Butylbenzene ND 10.0 8.88 89 10.0 8.59 86 3 75-128 20
n-Propylbenzene NO 10.0 8.84 88 10.0 8.67 87 2 76-126 20
o-Xylene ND 10.0 9.09 91 10.0 9.05 91 0 78-122 20
p-IsoproPbltoluene NO 10.0 8.62 86 10.0 8.42 84 2 77-127 20
See-Butyl enzene ND 10.0 8.68 87 10.0 8.42 84 3 77-126 20
Styrene ND 10.0 9.08 91 10.0 8.85 89 3 78-123 20
Tert-Butylbenzene ND 10.0 8.65 87 10.0 8.37 84 3 78-124 20
Tetrachloroethene ND 10.0 8.68 87 10.0 8.70 87 0 74-129 20
Toluene ND 10.0 9.38 94 10.0 9.28 93 1 80-121 20
Trans-1,2-Dichloroethene ND 10.0 9.32 93 10.0 9.13 91 2 75-124 20
Trans-1,3-Dichloropropene ND 10.0 9.24 92 10.0 9.09 91 2 73-127 20
Trichloroethene ND 10.0 8.94 89 10.0 8.76 88 2 79-123 20
Trichlorofluoromethane ND 10.0 8.69 87 10.0 9.53 95 9 65-141 20
Vinyl Chloride ND 10.0 9.19 92 10.0 10.5 105 13 58-137 20
1,2-Dibromoethane ND 10.0 9.32 93 10.0 9.35 94 0 77-121 20
1,2,3-Trichlorobenzene ND 10.0 9.31 93 10.0 8.95 90 4 69-129 20
1,4-Dioxane ND 200 185 93 200 186 93 1 59-139 20
SpikeAmt MSResult MSRec SpikeAmt MSDResult MSDRec QCLimit
SURROGATE PARAMETERS (ug/L) (ug/L) (%) (ug/L) (ug/L) (%) (%)
---------------------------------------------------------------------------
1,2-Dichloroethane-d4 10.0 10.2 102 10.0 10.2 102 70-130
4-Bromofluorobenzene 10.0 9.82 98 10.0 9.76 98 70-130
Toluene-d8 10.0 10.1 101 10.0 10.2 102 70-130
Dibromofluoromethane 10.0 10.3 103 10.0 10.4 104 70 -130
PS: parent Sample MS: Matrix Spike MSD: Matrix Spike Duplicate
REPORT ID: 23E133 Page 45 of 345
QC DATA
REPORT ID: 23E133 Page 46 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW412.D
Acq On 23 May 2023 10:25 am
Sample V006E19B
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 23 10:51 2023
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Vial: 6
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RES
(RTE Integrator)
~'
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 10.10 114 4319466 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 3587206 10.00 ug/l 0.01
73) 1,2-DICHLOROBENZENE-D4 19.43 152 1352000 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1399687 10.03 ug/l 0.02
Spiked Amount 10.000 Recovery = 100.30%
41) 1,2-Dichloroethane-d4 9.23 65 928154 9.57 ug/l , __ 0.01
Spiked Amount 10.000 Recovery = 95.70%
54) Toluene-d8 12.93 98 4922414 10.57 ug/l,/? 0.01
Spiked Amount 10.000 Recovery = 105.~
76 ) 4-Bromofluorobenzene 17.56 95 1548685 10.12 ug/l, 0.01
Spiked Amount 10.000 Recovery = 101.20%
Target Compounds / Qvalue
17) Methylene chloride 4.41 49 46824 0.28 ug/l 91
(#) = qualifier out of range (m) = manual integration
REW412.D V006E15.M Tue May 23 10:51:49 2023 Page 1
REPORT ID: 23E133 Page 47 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW412.D
Aeq On 23 May 2023 10:25 am
Sample V006E19B
Mise 25mL
MS Integration Params: RTE.P
Quant Time: May 23 10:51 2023
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Initial Calibration
V\bundance TIC: REW412.D
4400000
4200000
4000000
i 3800000
I
I 3600000 i
3400000J I
1 !
32000001 ,
I I
i
I 3000000
i
i 2800000 1
I
I
I 2600000
!
I 2400000
I
I
2200000
j 2000000
I
i 1800000 !
i I
i 1600000
I 1400000
i
i 1200000
I
1000000
I I 8000001 :;;:
! ...: i
I ~ ! 600000 '§
i i :E
" Q)
I
c:
400000 OJ >.
~
I
:;;:
200000 L-D i
I
~ime--> 0
2.00 4.00 6.00
REW412.D V006E15.M
ilf
Z
W
N z w
ID a
0:: a
::J -' LL
~~
(J)
of c: .,
£
Q)
E (J) e ~ g Q) 0:: C 0 '" E .c:
.§ 'Q) e is .Q
.c: ~
N.
II
\.... '-
8.00 10~00 12~00 14~00
Tue May 23 10:51:50 2023
i3 w z
~ z w
ID a
0:: a -' :r:
(.)
16~00
(J)
eli c: ~
2l e
0 :::J
1i
E e
~
I
!
18~00
a -' :r:
(.)
9
N.
I
A L~
20~00 I
Page 2
REPORT ID: 23E133 Page 48 of 345
~b":~O:1 SOl6 (4389 mioJ REW253D (-I
I oL~~lrJ ... r";'~~ 1?~, .'.1~ .1 ,11n, .. 1~_ .. , . 'To .. ~
~ 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
~bundance Scan 217 (4.411 min): REW412.D
414
II 84
RaWo
I O"n-rTTt'Pfft'I'IT,'ft'r-w'f'Pt'I"Prt-tTr'Pl'+rI+ri--rrnCTT+TTTTTTTTl Iii I Iii iii iii I I T iii i~l
~/z-->_ 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170
IAbundance Scan 217 (4.411 min): REW412.D(-) ,
Sub
50
4
84
#17
Methylene chloride
Concen: 0.28 ug/l
RT: 4.41 min Scan# 217
Delta R.T. 0.02 min
Lab File: REW412.D
Acq: 23 May 2023 10:25 am
Tgt Ion: 49 Resp: 46824
Ion Ratio Lower Upper
49 100
84 79.6 57.4 117.4
86 48.7 25.5 85.5
~---;----:--=-=c::--c-=-c=-=-~~~.-"-. bundance Ion 49.00 (48.70 to 49.70): REW412.Q
10000 Ion 84.00 (83.70 to 84.70): REW412.d
Ion 86.00 (85.70 to 86.70): REW412.d
i
8000 4.41
6000
4000
2000
ime-->
1\;;<+ ~ NVy-c, i o / x'. • M.-'~i.._L~~ ,-, . i
, , , I ' " I rr-rrr"''l"TT''lTT, I
4.20 4.30 4.40 4.50 4.60 4.ZQ~8iL~
REW412.D V006E15.M Tue May 23 10:51:52 2023 Page 3
REPORT ID: 23E133 Page 49 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW409.D Vial: 3
Operator: LYamas Acq On 23 May 2023 9:07 am
Sample V006E19L Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 23 9:32 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.10
15.55
19.43
8.12
9.23
12.93
17.56
1. 71
1. 95
2.05
2.52
2.62
2.66
2.90
3.40
3.47
3.51
3.65
3.82
4.20
4.09
4.41
4.39
4.66
4.70
4.91
5.62
5.86
5.77
6.55
6.84
7.09
7.22
7.60
114 4621716
117 4019517
152 1554477
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
1522560 10.20 ug/l 0.02
Recovery = 102.00%
1024337 9.87 ug/l ~ 0.01
Recovery = 98.70%
5315179 10.18 ug/l 0.01
Recovery = 101. 80%
ug/)/ 0.01
102.80%
1808863 10.28
Recovery =
2005451
2118061
1831940
1552586
1164470
2876802
2208875
571831
1154634
867703
2563809
1394732
124925
2743193
1892113
5999814
1145530
2529728
1759985
4860371
1585860
2885398
3808478
1494375
1582897
1765577
2726793
10.85 ug/l
10.34 ug/l
9.20 ug/l
9.47 ug/l
9.69 ug/l
10.52 ug/l
9.32 ug/l
49.09 ug/l
9.01 ug/l
50.07 ug/l
10.06 ug/l
269.59 ug/l
10.01 ug/l
9.82 ug/l
10.45 ug/l
9.87 ug/l
54.63 ug/l
10.13 ug/l
10.05 ug/l
10.65 ug/l
11.23 ug/l
10.13 ug/l
10.09 ug/l
54.07 ug/l
10.30 ug/l
10.21 ug/l
9.78 ug/l
Qvalue
98
99
99
97
98
100
99
95
99
98
97
100
95
99
95
99
99
100
99
98
100
99
99
98
99
100
99
(#) = qualifier out of range (m) = manual integration
REW409.D V006E15.M Tue May 23 10:52:04 2023 Page 1
REPORT ID: 23E133 Page 50 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW409.D
Acq On 23 May 2023 9:07 am
Sample V006E19L
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 9:32 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit Qvalue
32)
33)
35)
36)
38)
39)
40)
42)
43)
44)
45)
46)
47)
48)
49)
50)
51 )
52 )
55)
56)
57)
58)
59)
60)
61 )
62)
64)
65)
66)
67)
68)
69)
70)
71 )
72)
74)
75)
77)
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
l,l,l-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
l,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1,l,2,2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.97
8.10
8.50
8.49
8.87
9.03
9.22
9.42
9.41
10.67
10.76
11.03
11.58
11.48
11.55
12.16
12.22
12.53
13.07
13.50
13.45
13.69
13.79
14.15
14.20
14.55
14.89
15.24
15.62
15.71
15.72
15.85
16.58
16.64
17.19
17.19
17.46
17.67
17.77
17.77
17.82
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
884390
151681
2073807
2469996
783922
1730223
2895923
1346811
6364336
1699312
2687865
1530726
121432
1862509 .r~
735344
154090
3731461
2325270
6702723
1188733
1697808
911234
2462543
1748695
1396400
1174622
905071
2776682
4354314
1357250
7809903
11544661
5687696
4482948
7420457
538975
1024037
250374
224304
9096396
1596278
(#) = qualifier out of range (m) = manual integration
REW409.D V006E15.M Tue May 23 10:52:04 2023
10.01
9.75
8.95
10.22
10.27
9.50
9.73
10.38
10.16
10.13
10.37
10.51
192.64
9.56
9.83
12.30
55.97
10.12
10.21
10.17
9.98
9.68
52.50
10.39
9.71
9.86
9.83
10.09
10.31
9.24
9.86
19.95
9.63
9.98
9.81
9.44
9.98
9.53
8.41
9.78
9.93
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Page 2
98
96
99
95
100
98
99
100
100
98
97
96
94
99
99
94
98
98
100
97
98
98
99
100
99
100
98
100
100
99
99
99
98
99
99
99
99
99
94
99
100
REPORT ID: 23E133 Page 51 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW409.D
Aeq On 23 May 2023 9:07 am
Sample V006E19L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 9:32 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) l,3,5-Trimethylbenzene 17.99 105 5910880 9.82 ug/l 99
82) 2-Chlorotoluene 18.00 91 5914488 9.87 ug/l 99
83) 4-Chlorotoluene 18.07 91 5213820 11. 00 ug/l 100
84) tert-Butylbenzene 18.43 134 1363682 9.44 ug/l 93
85) l,2,4-Trimethylbenzene 18.47 105 5847299 9.84 ug/l 99
86) see-Butylbenzene 18.69 105 8037965 9.61 ug/l 99
87) p-Isopropyltoluene 18.85 119 6460296 9.89 ug/l 99
88) l,3-Diehlorobenzene 18.95 146 3184173 10.48 ug/l 99
89 ) 1, 2, 3-Trimethylbenzene 19.03 105 5565837 10.31 ug/l 100
90 ) l,4-Diehlorobenzene 19.07 146 3157858 10.36 ug/l 100
91) n-Butylbenzene 19.29 91 6226190 10.07 ug/l 99
92) l,2-Diehlorobenzene 19.46 146 2656934 10.49 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.22 157 151247 9.23 ug/l 94
94) l,2,4-Triehlorobenzene 21.07 180 1649859 9.92 ug/l 99
95 ) Hexaehlorobutadiene 21.20 225 1106936 10.82 ug/l 99
96 ) Naphthalene 21.34 128 2445118 10.07 ug/l 99
97 ) 1, 2, 3-Triehlorobenzene 21.59 180 1278876 10.01 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW409.D V006E15.M Tue May 23 10:52:05 2023 Page 3
REPORT ID: 23E133 Page 52 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW409.D
Aeq On 23 May 2023 9:07 am
Sample V006E19L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial: 3
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 23 9:32 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
V',bundance
: j
I j
i 1.35e+07~
1 1 I
I 1.3e+07
I
i 1.25e+07
i 1.2e+07j
: ;'5 07 1 . 1.1.e+
1
1.1e+07 I
1.05e+07 j
1e+07 1
9500000 I
1 I
9000000
1
8500000 I
J 8000000
7500000
1
7000000 1
6500000 I
i
6000000 1
5500000
1
5000000 I
4500000 I
4000000 ~
3500000 I
3000000
2500000
2000000
1500000
1000000
l5000~
Ime--> 2.00
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW409.D
I I
4.00 6.00 8.00 10.00 12.00 14.00
;;;: r: g
Q)
~ a.
"" Q) c
.!!!
~
E
I
lii
i ill
I :;;;
1--i l N I ~
~
~
16.00 18.00 20.00
REW409.D V006E15.M Tue May 23 10:52:08 2023
I
Page 4
REPORT ID: 23E133 Page 53 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW410.D Vial: 4
Operator: LYamas Acq On 23 May 2023 9:33 am
Sample V006E19C Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 23 9:58 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.~(RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.10
15.55
19.43
8.12
9.23
12.93
17.56
1. 71
1. 95
2.05
2.52
2.62
2.66
2.90
3.40
3.49
3.51
3.66
3.82
4.20
4.10
4.41
4.39
4.64
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
114 4593862
117 3956960
152 1535139
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
1466331 9.88 ug/l 0.02
Recovery = 98.80%
1013944 9.83 ug/l <" 0.01
Recovery =
5224819 10.17
Recovery =
98.30%
ug/l./" 0.01
101 ;.70%
1770572 10.19 ugn 0.01
Recovery = 1~. 90%
1951206
2035114
1761297
1466556
1087135
2879475
2040480
565179
1147039
859397
2565567
1326748
119121
2653647
1885292
5577691
1117010
2509047
1758845
4784230
1472750
2903615
3948205
1424966
1566184
1746889
2707127
10.62 ug/l
10.00 ug/l
8.89 ug/l
9.00 ug/l
9.10 ug/l
10.59 ug/l
8.66 ug/l
48.81 ug/l
9.00 ug/l
49.88 ug/l
10.13 ug/l
258.00 ug/l
9.60 ug/l
9.56 ug/l
10.48 ug/l
9.23 ug/l
53.60 ug/l
10.11 ug/l
10.11 ug/l
10.55 ug/l
10.50 ug/l
10.25 ug/l
10.52 ug/l
51.87 ug/l
10.25 ug/l
10.17 ug/l
9.77 ug/l
Qvalue
97
99
98
99
97
99
100
94
99
96
98
99
94
98
94
100
99
100
99
98
100
99
97
96
99
100
99
(#) = qualifier out of range (m) = manual integration
REW410.D V006E15.M Tue May 23 10:52:18 2023 Page 1
REPORT ID: 23E133 Page 54 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW410.D
Acq On 23 May 2023 9:33 am
Sample V006E19C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 9:58 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
32)
33)
35)
36 )
38 )
39)
40)
42 )
43)
44)
45 )
46 )
47)
48 )
49)
50)
51 )
52)
55)
56)
57)
58)
59)
60)
61)
62)
64)
65)
66)
67)
68)
69)
70)
71 )
72)
74)
75)
77)
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
1, 1, 1-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
l,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.97
8.10
8.50
8.48
8.86
9.03
9.22
9.42
9.41
10.68
10.76
11.03
11. 58
11.47
11.55
12.16
12.21
12.53
13.07
13.50
13.45
13.71
13.78
14.15
14.20
14.55
14.89
15.24
15.61
15.71
15.72
15.85
16.58
16.64
17.19
17.19
17.46
17.67
17.77
17.77
17.82
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
876587
158604
2050382
2026843
775418
1725494
2869634
1337162
6354830
1689083
2578437
1500621
113581
1861040
730295
153960
3592520
2307183
6667943
1155933
1656333
888829
2391976
1677747
1408313
1128056
912589
2783354
4322849
1356526
7784098
11628108
5661378
4466622
7377016
536683
1018952
254226
227302
9166837
1591945
9.98
10.26
8.90
8.44
10.22
9.53
9.70
10.37
10.21
10.13
10.01
10.36
/181. 27
.. 9.61
9.82
12.37
54.21
10.10
10.32
10.05
9.89
9.59
51. 81
10.12
9.94
9.62
10.07
10.27
10.40
9.38
9.98
20.42
9.74
10.10
9.91
9.52
10.06
9.80
8.63
9.98
10.03
(#) = qualifier out of range (m) = manual integration
REW410.D V006E15.M Tue May 23 10:52:19 2023
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Page 2
98
97
99
98
99
98
100
98
100
98
97
96
98
99
99
97
98
99
100
96
100
98
98
99
99
98
99
99
99
100
99
99
98
99
100
99
99
96
94
99
99
REPORT ID: 23E133 Page 55 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW410.D
Aeq On 23 May 2023 9:33 am
Sample V006E19C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 9:58 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) 1, 3, 5-Trimethylbenzene 17.99 105 5883841 9.90 ug/l 100
82) 2-Chlorotoluene 18.00 91 5798037 9.79 ug/l 92
83) 4-Chlorotoluene 18.07 91 5223824 11.16 ug/l 95
84) tert-Butylbenzene 18.43 134 1395682 9.78 ug/l 96
85) l,2,4-Trimethylbenzene 18.48 105 5769697 9.83 ug/l 99
86 ) see-Butylbenzene 18.69 105 7969678 9.65 ug/l 100
87 ) p-Isopropyltoluene 18.85 119 6356242 9.86 ug/l 100
88) l,3-Diehlorobenzene 18.95 146 3158292 10.52 ug/l 99
89 ) l,2,3-Trimethylbenzene 19.03 105 5569160 10.45 ug/l 99
90) l,4-Diehlorobenzene 19.07 146 3116641 10.36 ug/l 99
91) n-Butylbenzene 19.29 91 6216613 10.18 ug/l 99
92) l,2-Diehlorobenzene 19.46 146 2654101 10.61 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.24 157 141103 8.72 ug/l 99
94) l,2,4-Triehlorobenzene 21.07 180 1601460 9.75 ug/l 99
95) Hexaehlorobutadiene 21. 20 225 1053018 10.42 ug/l 99
96) Naphthalene 21.34 128 2393311 9.98 ug/l 99
97 ) 1, 2, 3-Triehlorobenzene 21.59 180 1237831 9.81 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW410.D V006E15.M Tue May 23 10:52:19 2023 Page 3
REPORT ID: 23E133 Page 56 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW410.D
Aeq On 23 May 2023 9:33 am
Sample V006E19C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 23 9:58 2023
TBA
Vial: 4
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
f,bundance
!
; 1.35e+07
!
1.3e+07
1.25e+07
1.2e+07
1.15e+07
1.1e+07
1.05e+07
1e+07
9500000
9000000
8500000
3500000
2500000
2000000
1500000
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW410.D
REW410.D V006E15.M Tue May 23 10:52:22 2023
:;;:
r: :g
"" ~ ,g
I
:;;; 1-:
'" t
~ ::;:. >.
U5
Page 4
REPORT ID: 23E133 Page 57 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW438.D
Acq On 24 May 2023 9:15 am
Sample V006E20B
Misc 25mL
(QT Reviewed)
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 9:44 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15 ~ ..
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1/4-DIFLUOROBENZENE 10.10 114 5049583 10.00 ug/l 0.01
53) CHLOROBENZENE-D5 15.55 117 4221155 10.00 ug/l 0.01
73) 1,2-DICHLOROBENZENE-D4 19.43 152 1588869 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 8.12 111 1635354 10.03 ug/l 0.02
Spiked Amount 10.000 Recovery = 100.30%
41) 1,2-Dichloroethane-d4 9.23 65 1090114 9.61 ug/l 0.01
Spiked Amount 10.000 Recovery = %':10%
54) Toluene-d8 12.93 98 5666956 10.34 ug/l~ 0.01
Spiked Amount 10.000 Recovery = 103.40%
76) 4-Bromofluorobenzene 17.56 95 1813089 10.08 ug£l 0.01
Spiked Amount 10.000 Recovery = 1ifo.80%
(,/
Target Compounds Qvalue
17) Methylene chloride 4.41 49 26007 0.13 ug/l 95
(#) = qualifier out of range (m) = manual integration
REW438.D V006E15.M Wed May 24 09:48:20 2023 Page 1
REPORT ID: 23E133 Page 58 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW438.D
Aeq On 24 May 2023 9:15 am
Sample V006E20B
Mise 25mL
MS Integration Params: RTE.P
Quant Time: May 24 9:44 2023
Vial: 6
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
5200000
50000001
4800000
4600000
!
44000001
I
42000001
I
4000000j
3800000j
3600000
3400000
1
3200000j
i
3000000j
!
2800000:
i
2600000 I!
2400000
2200000)
2000000j
I
1800000j
16000001
I
14000001
12000001
10000001
i
Tue May 16 12:41:48 2023
Initial Calibration
Cf)
.i
" to
~
~ o
'" '5
E
~
is
TIC: REW438.D
us z w
~
~ rr o
:::J
..J
LL
~.
800000j .:g
6000001 i
" Q)
4000001 J I
20000:1-,1 ,,--,1, ~,k::c;;::~;::::::';::::'~'-;:::~';=;';=::';::=I;::=';::=;::=' ~;::::;=~iu;=, rd, ~,L;=)~! L;=-_;=, ;=, ;=, 1r='~;:=;';=Ir=;=;=r!.,L--'=1I:=;,~-----1~I~,J:=::;,~1 '=;:1=;:'::::;':=;:':::::;:'::::;::1 : ~ime--> 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 .~!
REW438.D V006E15.M Wed May 24 09:48:21 2023 Page 2
REPORT ID: 23E133 Page 59 of 345
~bundance
I
Rem
Ra~
49
Scan 216 (4.389 min): REW253.D (-)
7
84
84
o~~~~~~~~~~~~~~~~~~~~~
Iz--> 30
bundance
Sub
50
Iz-->
76
37
#17
Methylene chloride
Concen: 0.13 ug/l
RT: 4.41 min Scan# 217
Delta R.T. 0.02 min
Lab File: REW438.D
Acq: 24 May 2023 9:15 am
Tgt Ion: 49 Resp: 26007
Ion Ratio Lower Upper
49 100
84 83.6 57.4 117.4
86 49.9 25.5 85.5
bundance Ion 49.00 (48.70 to 49.70): REW438.
Ion 84.00 (83.70 to 84.70): REW438.
Ion 86.00 (85.70 to 86.70): REW438.
5000
4.41
REW438.D V006E15.M Wed May 24 09:48:23 2023 Page 3
REPORT ID: 23E133 Page 60 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW435.D
Acq On 24 May 2023 7:57 am
Sample V006E20L
Vial: 3
Operator: LYamas
Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 8:19 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15 ~
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.10 114
15.55 117
19.43 152
8.12
9.23
12.93
17.56
1. 71
1. 95
2.05
2.52
2.62
2.66
2.90
3.40
3.49
3.51
3.66
3.82
4.20
4.10
4.41
4.39
4.66
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
4400175
3703345
1447023
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
1420069 9.99
Recovery =
964435 9.76
Recovery =
5007719 10.41
Recovery =
1654843 10.10
Recovery =
1868745
1989345
1698773
1402001
1029348
2752057
1992651
538384
1106898
818718
2468244
1280004
109438
2625420
1832784
5558599
1096784
2410038
1725077
4628966
1469866
2831271
3828019
1382641
1545087
1727833
2684755
10.62
10.21
8.96
8.98
8.99
10.57
8.83
48.54
9.07
49.59
10.17
259.87
9.21
9.87
10.64
9.61
54.94
10.14
10.35
10.65
10.94
10.44
10.65
52.54
10.56
10.50
10.12
ug/l 0.02
99.90%
ug/l r 0.01
97.60%
ug/l,r-0.01
104.10%
ug?J. 0.01
101.00%
./
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
97
98
98
99
96
100
100
97
99
98
97
100
97
99
93
99
98
100
100
99
100
99
97
98
99
100
99
(#) = qualifier out of range (m) = manual integration
REW435.D V006E15.M Wed May 24 09:48:35 2023 Page 1
REPORT ID: 23E133 Page 61 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\~ATA\23E24\REW435.D
Acq On 24 May 2023 7:57 am
Sample V006E20L
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 8:19 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32)
33)
35 )
36)
38)
39)
40)
42 )
43 )
44 )
45 )
46 )
47)
48 )
49)
50 )
51)
52)
55 )
56 )
57 )
58 )
59)
60)
61)
62 )
64)
65)
66 )
67)
68 )
69 )
70 )
71)
72)
74)
75)
77)
78)
79 )
80)
Bromochloromethane
Tetrahydrofuran
1, 1, 1-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
l,4-Dioxane
Bromodichloromethane
D ibromome thane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.97
8.10
8.51
8.49
8.86
9.03
9.22
9.44
9.41
10.68
10.76
11.03
11. 59
11.47
11.55
12.16
12.21
12.53
13.07
13.50
13.45
13.71
13.78
14.15
14.20
14.55
14.89
15.24
15.61
15.71
15.72
15.85
16.58
16.64
17.19
17.19
17.46
17.67
17.77
17.77
17.82
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
83
110
53
91
156
857414
145180
2216988
2251879
768059
1708138
2753437
1314148
6196426
1665674
2233991
1473502
115100
1862268
710384
143437
3495327
2255397
6441874
1123298
1643582
853854
2292653
1644095
1346264
1133299
879101
2513576
4207459
1316331
7366722
11018465
5392172
4255791
6823079
521903
983486
245118
214663
8475067
1521375
(#) = qualifier out of range (m) = manual integration
10.19 ug/l
9.81 ug/l
10.05 ug/l
9.79 ug/l
10.57 ug/l
9.85 ug/l
9.71 ug/l
10.64 ug/l
10.39 ug/l
10.43 ug/l
9.05 ug/l
10.62 ug/l
~91. 78 ug/l
10.04 ug/l
9.97 ug/l
12.03 ug/l
55.06 ug/l
10.31 ug/l
10.65 ug/l
10.43 ug/l
10.49 ug/l
9.84 ug/l
53.06 ug/l
10.60 ug/l
10.16 ug/l
10.33 ug/l
10.36 ug/l
9.91 ug/l
10.82 ug/l
9.73 ug/l
10.09 ug/l
20.67 ug/l
9.91 ug/l
10.29 ug/l
9.79 ug/l
9.82 ug/l
10.30 ug/l
10.02 ug/l
8.64 ug/l
9.79 ug/l
10.17 ug/l
Qvalue
97
95
93
95
97
97
100
99
100
99
95
96
98
100
99
96
98
99
100
100
98
96
98
97
99
99
99
100
100
99
98
99
97
99
100
99
100
94
94
99
99
REW435.D V006E15.M Wed May 24 09:48:36 2023 Page 2
REPORT ID: 23E133 Page 62 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW435.D
Aeq On 24 May 2023 7:57 am
Sample V006E20L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 8:19 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) 1, 3, 5-Trimethylbenzene 17.99 105 5435978 9.70 ug/l 99
82) 2-Chlorotoluene 18.00 91 5459003 9.78 ug/l 97
83) 4-Chlorotoluene 18.07 91 5003748 11.34 ug/l 99
84) tert-Butylbenzene 18.43 134 1257540 9.35 ug/l 96
85) 1,2,4-Trimethylbenzene 18.48 105 5388563 9.74 ug/l 98
86) see-Butylbenzene 18.69 105 6992181 8.98 ug/l 100
87) p-Isopropyltoluene 18.85 119 5732538 9.43 ug/l 100
88) 1,3-Diehlorobenzene 18.95 146 3021153 10.68 ug/l 99
89) 1,2,3-Trimethylbenzene 19.03 105 5158475 10.27 ug/l 100
90 ) 1,4-Diehlorobenzene 19.07 146 3047873 10.75 ug/l 100
91 ) n-Butylbenzene 19.29 91 5365480 9.32 ug/l 100
92) 1,2-Diehlorobenzene 19.46 146 2560007 10.85 ug/l 98
93) 1,2-Dibromo-3-ehloropropan 20.22 157 142877 9.37 ug/l 92
94) 1,2,4-Triehlorobenzene 21.07 180 1491844 9.64 ug/l 99
95 ) Hexaehlorobutadiene 21.20 225 863161 9.06 ug/l 97
96) Naphthalene 21.34 128 2273060 10.06 ug/l 99
97) 1,2,3-Triehlorobenzene 21.59 180 1137903 9.57 ug/l 97
(#) = qualifier out of range (m) = manual integration
REW435.D V006E15.M Wed May 24 09:48:36 2023 Page 3
REPORT ID: 23E133 Page 63 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW435.D
Aeq On 24 May 2023 7:57 am
Sample V006E20L
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 24 8:19 2023
TBA
Vial: 3
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
iAhundance
! 1.25e+07
!
i 1.2e+07 ,
i
i i 1.15e+07
1 i 1.1e+07 ,
i
: 1.05e+07
1e+07
9500000
6500000
4500000
4000000
3500000
3000000
2500000
2000000
1500000
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW435.D
REW435.D V006E15.M Wed May 24 09:48:39 2023 Page 4
REPORT ID: 23E133 Page 64 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW436.D
Acq On 24 May 2023 8:23 am
Sample V006E20C
Vial: 4
Operator:. LYamas
Inst : 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 8:45 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE
METHOD 8260
Integrator)
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.10 114
15.55 117
19.43 152
8.12
9.23
12.93
17.56
1.71
1. 95
2.05
2.52
2.62
2.66
2.90
3.40
3.49
3.51
3.66
3.82
4.20
4.10
4.41
4.39
4.64
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
4521999
3849030
1509437
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
1451508 9.94
Recovery =
ug/l
99.40%
0.02
1007755 9.92 ug/l~·
99.20%
0.01
Recovery =
5126812 10.26
Recovery =
ug/l/
102.60%
0.01
1697447 9.93 ugp{ 0.01
Recovery = 7.30 %
2001497
2162954
1854172
1546629
1120219
2732428
2204393
548604
1112656
836732
2424496
1259688
113767
2601013
1820642
5228173
1059649
2384305
1694487
4589870
1562352
2771504
3786346
1356036
1527830
1678706
2644977
11.07 ug/l
10.80 ug/l
9.51 ug/l
9.64 ug/l
9.53 ug/l
10.21 ug/l
9.51 ug/l
48.13 ug/l
8.87 ug/l
49.30 ug/l
9.72 ug/l
248.86 ug/l
9.31 ug/l
9.52 ug/l
10.28 ug/l
8.79 ug/l
51. 65 ug/l
9.76 ug/l
9.89 ug/l
10.28 ug/l
11.31 ug/l
9.94 ug/l
10.25 ug/l
50.14 ug/l
10.16 ug/l
9.92 ug/l
9.70 ug/l
Qvalue
97
100
97
99
100
99
100
96
97
98
98
99
95
100
93
99
99
100
100
99
99
100
96
97
99
100
99
(#) = qualifier out of range (m) = manual integration
REW436.D V006E15.M Wed May 24 09:48:50 2023 Page 1
REPORT ID: 23E133 Page 65 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW436.D
Acq On 24 May 2023 8:23 am
Sample V006E20C
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 8:45 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit Qvalue
32 ) Bromochloromethane 7.97 130 836637 9.68 ug/l 99
33 ) Tetrahydrofuran 8.10 42 135317 8.89 ug/l 97
35 ) l,l,l-Trichloroethane 8.51 97 1997576 8.81 ug/l 99
36) Cyclohexane 8.49 84 2346506 9.93 ug/l 95
38) l,l-Dichloropropene 8.87 110 752183 10.07 ug/l 96
39) Carbon tetrachloride 9.03 119 1687352 9.47 ug/l 97
40) tert-Amyl methyl ether (TA 9.20 73 2721345 9.34 ug/l 100
42 ) l,2-Dichloroethane 9.42 62 1307888 10.31 ug/l 100
43 ) Benzene 9.41 78 6123519 9.99 ug/l 99
44) Trichloroethene 10.68 130 1645993 10.02 ug/l 98
45 ) Methylcyclohexane 10.76 83 2585168 10.19 ug/l 96
46) l,2-Dichloropropane 11.03 63 1455069 10.21 ug/l 96
47) l,4-Dioxane 11. 59 88 115516 /87.29 ug/l 95
48) Bromodichloromethane 11.47 83 1803814 9.47 ug/l 99
49) Dibromomethane 11.55 93 713541 9.75 ug/l 98
50) 2-Chloroethyl vinyl ether 12.16 63 136865 11.17 ug/l 98
51) 4-Methyl-2-pentanone 12.21 43 3396952 52.07 ug/l 97
52 ) cis-1,3-Dichloropropene 12.53 75 2246507 9.99 ug/l 98
55 ) Toluene 13.06 91 6402500 10.19 ug/l 100
56 ) Ethyl methacrylate 13.50 69 1096280 9.80 ug/l 99
57) trans-1,3-Dichloropropene 13.45 75 1619769 9.94 ug/l 98
58) l,l,2-Trichloroethane 13.69 97 861310 9.56 ug/l 97
59) 2-Hexanone 13.78 43 2266221 50.46 ug/l 100
60 ) l,3-Dichloropropane 14.15 76 1640206 10.17 ug/l 99
61) Tetrachloroethene 14.20 164 1331239 9.66 ug/l 99
62) Dibromochloromethane 14.55 129 1111892 9.75 ug/l 100
64) l,2-Dibromoethane 14.89 107 862161 9.78 ug/l 98
65) 1-Chlorohexane 15.24 91 2628805 9.97 ug/l 99
66) Chlorobenzene 15.62 112 4229565 10.46 ug/l 100
67 ) 1, 1, l,2-Tetrachloroethane 15.71 131 1318236 9.37 ug/l 100
68) Ethylbenzene 15.72 91 7455994 9.83 ug/l 98
69) m-Xylene & p-Xylene 15.85 91 10959540 19.78 ug/l 99
70) o-Xylene 16.58 91 5417521 9.58 ug/l 98
71 ) Styrene 16.64 104 4267767 9.92 ug/l 99
72 ) Isopropylbenzene 17.19 105 7011499 9.68 ug/l 100
74) Bromoform 17.19 173 512053 9.24 ug/l 100
75) 1, 1, 2, 2-Tetrachloroethane 17.46 83 977155 9.81 ug/l 99
77) l,2,3-Trichloropropane 17.67 110 243248 9.53 ug/l 99
78) trans-1,4-Dichloro-2-buten 17.77 53 221551 8.55 ug/l 91
79) n-Propylbenzene 17.77 91 8775750 9.71 ug/l 99
80) Bromobenzene 17.82 156 1523408 9.76 ug/l 99
--------------------------------------------------------------------~----
(# ) = qualifier out of range (m) = manual integration
REW436.D V006E15.M Wed May 24 09:48:51 2023 Page 2
REPORT ID: 23E133 Page 66 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW436.D
Aeq On 24 May 2023 8:23 am
Sample V006E20C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 4
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 8:45 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81) 1, 3, 5-Trimethylbenzene 17.99 105 5601549 9.58 ug/l 100
82) 2-Chlorotoluene 18.00 91 5705596 9.80 ug/l 99
83) 4-Chlorotoluene 18.07 91 4925494 10.71 ug/l 99
84) tert-Butylbenzene 18.43 134 1297349 9.25 ug/l 93
85) l,2,4-Trimethylbenzene 18.48 105 5463153 9.46 ug/l 99
86 ) see-Butylbenzene 18.68 105 7734352 9.52 ug/l 100
87 ) p-Isopropyltoluene 18.85 119 6296872 9.93 ug/l 99
88 } l,3-Dichlorobenzene 18.95 146 3046516 10.32 ug/l 99
89 } 1, 2, 3-Trimethylbenzene 19.02 105 5349238 10.21 ug/l 100
90 ) l,4-Diehlorobenzene 19.07 146 3059632 10.34 ug/l 100
91 ) n-Butylbenzene 19.29 91 5967312 9.94 ug/l 99
92) l,2-Diehlorobenzene 19.46 146 2563486 10.42 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.22 157 139590 8.78 ug/l 91
94) l,2,4-Trichlorobenzene 21.07 180 1551884 9.61 ug/l 100
95) Hexaehlorobutadiene 21. 20 225 1046439 10.53 ug/l 98
96) Naphthalene 21. 34 128 2286758 9.70 ug/l 99
97) l,2,3-Triehlorobenzene 21.59 180 1191375 9.60 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW436.D V006E15.M Wed May 24 09:48:52 2023 Page 3
REPORT ID: 23E133 Page 67 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW436.D
Aeq On 24 May 2023 8:23 am
Sample V006E20C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 24 8:45 2023
TBA
Vial: 4
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
~bundance
1 1
I
! 1.
9000000
8500000
8000000
7500000
7000000
6500000'
6000000
11~nn'~nnl
! I 1 UlJUIJlJU 1
!
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW436.D
[~e_--_> _______ -=~ ____ ~~ __ ~~ __ ~== ____ ~= ___ .~~ __ ~~~ __ ~=-__ -=~ __ -=~~ __ ~
REW436.D V006E15.M Wed May 24 09:48:54 2023 Page 4
REPORT ID: 23E133 Page 68 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW447.D Vial: 15
Operator: LYamas Acq On 24 May 2023 1:09 pm
Sample 23E133-05M
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 24 13:32 2023
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260 .
Tue May 16 12:41:48 2023 ~ Last Update
Response via
DataAcq Meth
Initial Calibration
V006E15
Internal Standards
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. Qlon Response Cone Units Dev(Min)
10.10
15.55
19.43
8.12
9.23
12.93
17.56
1. 71
1. 95
2.05
2.52
2.62
2.66
2.90
3.40
3.49
3.51
3.66
3.82
4.20
4.10
4.41
4.39
4.64
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
114 5086518
117 4529672
152 1828508
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
1685733 10.26 ug/l 0.02
Recovery = 102.6090-
1163981 10.19 ug/l 0.01
101('90%
ug/l _.c:. 0.01
100.9090-
Recovery =
5934905 10.09
Recovery =
2032947 9.82 ug/)( 0.01
Recovery = 98.2090-
1935200
2425748
2014859
1746631
1262926
2831649
2265680
550658
1082270
824690
2571152
1489191
117085
2526870
1881259
6309228
1171090
2724790
1796467
5062101
1707983
2987044
4227066
1469215
1478941
1792814
2787224
/'
9.51 ug/l
10.76 ug/l
~.19 ug/l
9.68 ug/l
9.55 ug/l
9.41 ug/l
8.69 ug/l
42.95 ug/l
7.67 ug/l
42.87 ug/l
9.17 ug/l
261. 55 ug/l
8.52 ug/l
8.22 ug/l
9.45 ug/l
9.43 ug/l
50.75 ug/l
9.92 ug/l
9.32 ug/l
10.08 ug/l
10.99 ug/l
9.52 ug/l
10.17 ug/l
48.30 ug/l
8.74 ug/l
9.42 ug/l
9.08 ug/l
Qvalue
97
99
97
99
99
99
99
92
99
96
98
100
93
98
96
99
99
100
99
98
99
100
97
98
99
99
99
(#) = qualifier out of range (m) = manual integration
REW447.D V006E15.M Wed May 24 13:35:21 2023 Page 1
REPORT ID: 23E133 Page 69 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW447.D
Acq On 24 May 2023 1:09 pm
Sample 23E133-05M
Misc 25mL
(QT Reviewed)
Vial: 15
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 13:32 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
32) Bromochloromethane
33) Tetrahydrofuran
35) I /1 /1-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-l,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-l,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) l-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1 /2,2-Tetrachloroethane
77) 1 /2,3-Trichloropropane
78) trans-l,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.97
8.10
8.50
8.49
8.85
9.03
9.22
9.42
9.41
10.67
10.76
11.03
11.58
11.47
11.55
12.21
12.21
12.53
13.06
13.50
13.45
13.69
13.77
14.15
14.20
14.55
14.89
15.24
15.62
15.71
15.72
15.85
16.58
16.64
17.19
17.19
17.46
17.67
17.77
17.77
17.82
130 911225
42 164628
97 1989388
84 1874688
110 727221
119 1692363
73 3090764
62 1323558
78 6527642
130 1651008
83 2165486
63 1558415
88 128052
83 1931012
93 781482
63 4850
43 3807608
75 2417213
91 6936592
69 1315952
75 1771333
97 991803
43 2561313
76 1842816
164 1407614
129 1211094
107 967733
91 2741837
112 4410719
131 1499445
91 7997397
91 12158101
91 6049723
104 4595619
105 7518122
173 568082
83 1205398
110 285690
53 277751
91 9672181
156 1676219
(#) = qualifier out of range (m) = manual integration
REW447.D V006E15.M Wed May 24 13:35:22 2023
9.37 ug/l
9.62 ug/l
7.80 ug/l
7.05 ug/l
8.66 ug/l
8.44 ug/l
9.43 ug/l
9.27 ug/l
9.47 ug/l
8.94 ug/l
7.59 ug/l
9.72 ug/l
184.58 ug/l
9.01 ug/l
9.49 ug/l
0.35 ug/l #
51.89 ug/l
9.56 ug/l
9.38 ug/l
9.99 ug/l
9.24 ug/l
9.35 ug/l
48.46 ug/l
9.71 ug/l
8.68 ug/l
9.02 ug/l
9.32 ug/l
8.84 ug/l
9.27 ug/l
9.06 ug/l
8.96 ug/l
18.65 ug/l
9.09 ug/l
9.08 ug/l
8.82 ug/l
8.46 ug/l
9.99 ug/l
9.24 ug/l
8.85 ug/l
8.84 ug/l
8.87 ug/l
Page 2
99
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96
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99
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99
97
96
97
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99
1
99
99
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98
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98
98
98
99
98
98
100
100
100
99
100
99
99
99
99
98
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96
99
99
REPORT ID: 23E133 Page 70 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW447.D
Aeq On 24 May 2023 1:09 pm
Sample 23E133-05M
Mise 25mL
(QT Reviewed)
Vial: 15
Operator: LYamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 24 13:32 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81 ) 1,3,5-Trimethylbenzene 17.99 105 6179591 8.73 ug/l 99
82 ) 2-Chlorotoluene 18.00 91 5929451 8.41 ug/l 99
83) 4-Chlorotoluene 18.07 91 5247418 9.42 ug/l 99
84) tert-Butylbenzene 18.43 134 1469103 8.65 ug/l 93
85) 1, 2, 4-Trimethylbenzene 18.47 105 6057899 8.66 ug/l 99
86) see-Butylbenzene 18.68 105 8538974 8.68 ug/l 99
87) p-Isopropyltoluene 18.85 119 6623181 8.62 ug/l 100
88) 1,3-Diehlorobenzene 18.95 146 3234987 9.05 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.03 105 5605055 8.83 ug/l 99
90 ) 1,4-Diehlorobenzene 19.07 146 3240158 9.04 ug/l 99
91) n-Butylbenzene 19.29 91 6462267 8.88 ug/l 99
92) 1,2-Diehlorobenzene 19.46 146 2764448 9.28 ug/l 100
93) 1,2-Dibromo-3-ehloropropan 20.22 157 168338 8.74 ug/l 98
94) 1,2,4-Triehlorobenzene 21. 07 180 1768052 9.04 ug/l 100
95 ) Hexaehlorobutadiene 21. 20 225 1069743 8.89 ug/l 98
96 ) Naphthalene 21. 34 128 2739297 9.59 ug/l 100
97 ) 1, 2, 3-Triehlorobenzene 21. 59 180 1398968 9.31 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW447.D V006E15.M Wed May 24 13:35:22 2023 Page 3
REPORT ID: 23E133 Page 71 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW447.D Vial: 15
Aeq On 24 May 2023 1:09 pm
Sample 23E133-05M
Mise 25mL
Operator:
Inst
Multiplr:
LYamas
06
1. 00
MS Integration Params: RTE.P
Quant Time: May 24 13:32 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
it\bundance
i !
: 1.4e+07 1
i 1.3e+071
1.2e+07
I
1.1e+071
I
1e+07i
I
9000000
8000000
I
7000000
6000000j
I
50000001
4000000
3000000
2000000
1000000
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW447.D
REW447.D V006E15.M Wed May 24 13:35:24 2023 Page 4
REPORT ID: 23E133 Page 72 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW448.D Vial: 16
Operator: LYamas Acq On 24 May 2023 1:35 pm
Sample 23E133-05S
Misc 25mL
MS Integration Params: RTE.P
Quant Time: May 24 14:21 2023
Inst 06
Multiplr: 1.00
Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
Last Update
Response via
DataAcq Meth V006E15 ~
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.10
15.55
19.43
8.12
9.23
12.93
17.56
1. 71
1. 95
2.05
2.52
2.62
2.66
2.89
3.40
3.49
3.51
3.66
3.82
4.20
4.10
4.41
4.39
4.64
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
114 4998432
117 4460938
152 1828365
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
1671675 10.36
Recovery =
1144640 10.20
Recovery =
5885772 10.16
Recovery =
2019135 9.76
Recovery =
2100766 ~0.51
2661163 / ~2.02
2264268 / 10.51
187043'0
1350935
2793396
2442938
567508
1045607
854290
2530588
1462837
135514
2485015
1820432
5724818
1203447
2649724
1729293
4871891
1807974
2904614
3838469
1492132
1446004
1732802
2730464
10.54
10.39
9.44
9.53
45.04
7.54
45.33
9.18
261.44
10.04
8.23
9.30
8.71
53.07
9.81
9.13
9.87
11.84
9.43
9.40
49.92
8.70
9.27
9.06
ug/l 0.02
103.60%
ug/l.,,--0.01
102.00%
ug/l/-. 0.01
101 ~JO%
ug/.r 0.01
9060 %
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
97
98
97
98
98
99
100
99
100
96
99
100
92
98
95
99
99
100
100
98
100
100
99
98
99
100
100
(#) = qualifier out of range (m) = manual integration
REW448.D V006E15.M Wed May 24 14:25:28 2023 Page 1
REPORT ID: 23E133 Page 73 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW448.D
Acq On 24 May 2023 1:35 pm
Sample 23E133-05S
Misc 25mL
(QT Reviewed)
Vial: 16
Operator: LYamas
Inst 06
Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 24 14:21 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit Qvalue
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1{3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1{2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,1,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1{1,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.97
8.10
8.50
8.49
8.87
9.03
9.22
9.42
9.41
10.68
10.76
11.03
11.58
11.47
11.55
12.23
12.21
12.53
13.07
13.50
13.45
13.69
13.79
14.15
14.20
14.55
14.89
15.24
15.62
15.71
15.72
15.85
16.58
16.64
17.19
17.19
17.46
17.67
17.77
17.77
17.82
130 882136
42 154824
97 1935595
84 2335519
110 711537
119 1624760
73 3003065
62 1277852
78 6292841
130 1589603
83 2588403
63 1517013
88 126489
83 1874587
93 749276
63 4832
43 3898683
75 2324755
91 6760658
69 1307413
75 1716840
97 960496
43 2679399
76 1759962
164 1389187
129 1185702
107 955338
91 2652541
112 4295991
131 1463945
91 7882513
91 11780668
91 5930427
104 4408768
105 7372205
173 558671
83 1160333
110 267954
53 272384
91 9490058
156 1647030
(#) = qualifier out of range (m) = manual integration
REW448.D V006E15.M Wed May 24 14:25:28 2023
9.23 ug/l
9.21 ug/l
7.73 ug/l
8.94 ug/l
8.62 ug/l
8.25 ug/l
9.33 ug/l
9.11 ug/l
9.29 ug/l
8.76 ug/l
9.23 ug/l
9.63 ug/l
185.54 ug/l
8.90 ug/l
9.26 ug/l
0.36 ug/l #
54.07 ug/l
9.36 ug/l
9.28 ug/l
10.08 ug/l
9.09 ug/l
9.19 ug/l
51.47 ug/l
9.42 ug/l
8.70 ug/l
8.97 ug/l
9.35 ug/l
8.68 ug/l
9.17 ug/l
8.98 ug/l
8.96 ug/l
18.35 ug/l
9.05 ug/l
8.85 ug/l
8.78 ug/l
8.32 ug/l
9.62 ug/l
8.67 ug/l
8.68 ug/l
8.67 ug/l
8.71 ug/l
Page 2
99
94
96
95
99
98
99
99
100
99
96
95
96
98
99
1
99
98
99
99
99
98
100
99
99
99
99
100
100
99
99
100
100
100
100
99
99
100
91
99
100
REPORT ID: 23E133 Page 74 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW448.D
Aeq On 24 May 2023 1:35 pm
Sample 23E133-05S
Mise 25mL
(QT Reviewed)
Vial: 16
Operator: LYamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 24 14:21 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) l,3,5-Trimethylbenzene 17.99 105 5997765 8.47 ug/l 99
82) 2-Chlorotoluene 18.00 91 5828798 8.27 ug/l 99
83) 4-Chlorotoluene 18.07 91 5095855 9.14 ug/l 100
84) tert-Butylbenzene 18.43 134 1422147 8.37 ug/l 93
85) l,2,4-Trimethylbenzene 18.47 105 5869077 8.39 ug/l 99
86) see-Butylbenzene 18.68 105 8285521 8.42 ug/l 100
87) p-Isopropyltoluene 18.85 119 6470406 8.42 ug/l 99
88) l,3-Diehlorobenzene 18.95 146 3154421 8.82 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.02 105 5474090 8.62 ug/l 99
90) l,4-Diehlorobenzene 19.07 146 3129541 8.73 ug/l 99
91 ) n-Butylbenzene 19.29 91 6248518 8.59 ug/l 98
92) l,2-Diehlorobenzene 19.46 146 2673502 8.97 ug/l 100
93) l,2-Dibromo-3-ehloropropan 20.22 157 161924 8.40 ug/l 96
94) l,2,4-Triehlorobenzene 21. 07 180 1712924 8.76 ug/l 100
95) Hexaehlorobutadiene 21. 20 225 1038952 8.63 ug/l 99
96 ) Naphthalene 21. 34 128 2690954 9.42 ug/l 99
97) 1, 2, 3-Triehlorobenzene 21. 59 180 1344607 8.95 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW448.D V006E15.M Wed May 24 14:25:29 2023 Page 3
REPORT ID: 23E133 Page 75 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW448.D
Aeq On 24 May 2023 1:35 pm
Sample 23E133-05S
Mise 25mL
MS Integration Params: RTE.P
Quant Time: May 24 14:21 2023
Vial: 16
Operator:
Inst
Multiplr:
LYamas
06
1. 00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Initial Calibration
fA,bundance i 1.4e+07
TIC: REW448.D
j
1.3e+071
1.2e+07j
I
1.1e+071
I
1e+071
i
I
90000001
!
8000000
7000000
6000000
50000001
4000000
3000000
2000000
1000000
I 0 , , ,',
rfime-->
:;; 1-:
REW448.D V006E15.M
, , , I '
10.00
, I '
12.00
, I
14.00
, I
16.00
, I '
18.00 20~OO ' , , I I
Wed May 24 14:25:31 2023 Page 4
REPORT ID: 23E133 Page 76 of 345
INITIAL CALIBRATIONS
REPORT ID: 23E133 Page 77 of 345
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratories. Inc.
Lab Code : EMAX
Lab File ID: REW247
Instrument 10: 06
Project : ICAL
SDG No : ICAL
BFB Injection Date: 05/15/23
BFB Injection Time: 13:21
I I % RELATIVE I
I mle I ION ABUNDANCE CRITERIA ABUNDANCE I
I I I
I 50 I 15 . 40% of mass 95 16.093 I
I 75 I 30 . 60% of mass 95 I 42.626 I
I 95 I Base Peak. 100% relative abundance __ 1 100.000 I
I 96 I 5 . 9% of mass 95 I 6.B43 I
I 173 I Less than 2% of mass 174 I 0.000(0)1 I
I 174 I Greater than 50% of mass 95 I 72.B42 I
I 175 I 5 . 9% of mass 174 I 5.667(7.78)1 I
I 176 I 95 . 101% % of mass 174 I 72.635(99.72)1 I
I 177 I 5 . 9% % of mass 176 I 4.251(5.85)2 I
I_I I I
l·Value is % mass 174 2·Value is % mass 176
This check applies to the following Calibration Standards:
I EPA I LAB I LAB I DATE I TIME I
I SAMPLE NO. I SM-1PLE ID I FILE ID I ANALYZED I ANALYZED I
1=====1====1===1 I I
1IVSTDO.3 IV006E151 IREW248 I 05/15/23 I 13:47 I
2IVSTDO.5 IV006El52 IREW249 I 05/15/23 I 14:13 I
31VSTD1 IVOO6E153 1REW250 I 05/15123 I 14:39 I
41 VSTD2 I V006El54 I REW251 I 05/15/23 I 15: 05 I
51VSTD5 IV006E155 IREW252 I 05/15/23 I 15:31 I
61VSTD10 IV006E156 IREW253 I 05/15/23 I 15:57 I
71VSTD20 IV006E157 IREW254 I 05/15/23 I 16:23 I
81VSTD30 IV006E158 1REW255 I 05/15/23 I 16:49 I
91 VSTD50 I V006El59 I REW256 I 05/15/23 I 17: 15 I
10 I VSTD100 IV006E1510 IREW257 I 05/15/23 I 17:41 I
I I I I I I
REPORT ID: 23E133 Page 78 of 345
Instru~ent ID :06 Beglnnlng Datelime :00/10/23 13:47 SDlke Unlts :PPB Ie File :REW253
M lOX Parameters
1.4'DIFLU~ENZENE Dlrhlorodi uoromethane Ch oromefhane Vinyl ch oride Br~momethane Ch oroet~ne Dichl~ro }V0romethane Trich oro uoromethane Acro~ein 1.lt ·Trichloro·1.2.2·trifluoroethane Ace one 1.1'Dichl~roytheny tert-Buty a coho
l~ IViI. acetate thane 17 e ene chloride
5 ~~ car~ disulfide Acrt onit,ile
ter 'B~t2 ~et~Yl et~er (MTBE) trans-. ·D1Ch oroet ene ~~ Qsopropyl ether (DIPE) inyl aCytate 1.1·Dich oroethane
25 ~~ 2· Butanol tert-Butyl ethyl ether (ETBE)
5 ~~ 2·Butanone 2.2'Di~hloro~ropane Clf·1. -Dich oroethene d~ Ch oroform tert.Am-rl alcohol ~ Bromoch oromethane Tetrahydrofuran Di~romofluoromethane
I
1. 11-Trichloroethane Cyc ohexane 2. 2. 4·Trimethyl pentane 1.1-Dichloropr~pene Carbon tytrach ~ride Iert.~ methf; et~r (TAME) .2·Dic loroet ane-1. 2· Dichloroethane Benzene Trichloroethene
20H
Methnlcf;clohexane 1.2-ic loropropane l,4·Dioxane Bromodichloromethane Di~romomethane 2· hlor~ethYl vinyl ether
'H
4-Meth3 .2.~yntanone Cis-1OS·Dic oropropene CHLOR ENZENE·D5 Toluene·d8 Toluyne Ethy metha~rf;late ~~ tran~-1.3.D1C loropropene 1.1. -Trichloroethane 'ij 2·Hexanone 1.3'Dichloro~ropane Tetrachloroe hene Dibro~chloromethane 2·Ethy -I-butanol
I~ 1.2.Dlbrgmoethane l·fhloro exane rh oro~enzene t1.16 -Tetrachloroethane
2 ~~ E ~l enzene m-~lene & p-Xylene g' yene tyrene 72 1~~~DygA(~~~lENE.D4 ~~ 8ry~f~rm ~~ 1 ... -Tetrachloroethane 4· Bromofl uorobenzene
I 1.2.3'Trichlor~propane tr~ns-114-DiCh oro-2·butene n· rogy benzene Bromo enzene l'~h~'TrimethYlbenzene 2· oroto 1 uene
i 4.Chlorot~luene tert·Buty benzyne 1.2.4-Trlmethy benzene sec.ButYlbynzyne ~'Isop.ro~y to uene 'i·D1Ch orobenzene 1 .. 3-Trimethylbenzene 1. -Dirhlorobenzene Ii n·Buty ~ynzene 1.2·D1C oro~enzyne 1.2-Di~romo. -c~ oropropane 1.2.4-richloro enzene Hexachl~robutadiene §~ Na~htha ene 1 .. 3-Trichlorobenzene
~I'! "Ii:. !'-lUll" _ = ,Noml na I III1KlUm; ,!:!< Max %RSD: 15.9
J~a~
1
pra o:~~ 0.5 2 0.484
0.313
0.495
0.583
0.239 ~. ~ :~91
0.607
o:bg~ ~.3~2 U1~
0.192
0.313 0.515
0.156 q9~ t~~~ O. 67
0.337 .... __ ..
0.429 0.154 ... _ ......
0.129 0.455 1 1.~O~ 1. 5
0.41g 0.24 ...........
0.~7 O. 2 O. 95
0.2~2 ~.~ 7 0: 5~ h~s 1.474 1.127 1.931
~:~~ 1.17 ...........
...........
6.225
1.i1 4: ~ II 4. 8 ~.7 8 d~
H2
4.4 g 1.77
HoY
&!~ Je~~g r&g~ JQ~~~ 15:5~ REW253 ~~~ = =
1 1 1 1 1 jm ~J6g ~.394 ~.4~2 j:U~ 0.~9q .406 .41
.339 ~:~i ~:N ~:4~7 ~:M .3~7 g:~~1 .31 d~ dYb rm 0.6~7 f'! .~3~ 0.5~i .5~2 p~ .~23 O.~ :~~~ jJ~~ 0.281 . 74 ~:g~6 .03~ 0:8~r .0 ~ 0.509 .~97 oJ~5 .5 O. 9 .011 .11 .012
8·0~1 p~o 0.026 p~~ ~'r 0.599 .p · 6 t~~ · O~ 1:2~ :~g .340 · 7 ~:~~ .11
0.042 ~:2 8:g~ 8·05g 8:~~~ 8.514 .57 .363 0.3ra .4 5 1:g2~ o. 3 .911 o.~; P90 hd a:~~g 0.574 ~:60 .663 hg7 O. 17
8.794 0.76R ~:g2~ ~:8~ p~ ~:~~ j~g o.~ 0.~g7
8:35'
8:j9g J~ ~.32 ~J~ .37~ .599 ~:6~g . 39 .53 0.59
0.185 0.177 ~.20~ rj~ ~.171 r94 .g4 j5~ .028 .033
0.291 0.315 · 2 .~11 .330
~.483 ~.489 0:~g5 0.54 . 24 :a~~ .449 .499 0.641 0.470
0.1 89 8:~ij 0.17§ 8.174 ~'m ~.167 ~.4 1
P96
.414 O:~~~ Jor 1m L~~ ~:~2 j~~ £:219 l~jH 1.2~~ 1. § I!~ 0:4 8:5~5 I:~~r 1!11 8.310 O. .306 · 25 ~j~i · 15 ........... .. ........ .~2 .0~1 ·R01 ~.449 0.428 · 2 8:~~ o:B · 19 .152 8J~ .178 .1~ ........... .03 ~.02i d5§ 0.117 0.1~1 .15 O. 65 .13
0.47f 0.4 f .53r 0.52~ 0.4\ :il 1.18~ 1.~59 1.417 1.4,0 1.2~ 1.~1 1. 9~ 1.7S1 1.74 U62 1. 7
~. 5 8:3~ p~§ 0.~1 O. O~ o:~~ 1241 ~:~~ ~:233 .2 2 f2~ .. .......... 0.103 :12~ ~.126
8·r 0.41 .449 Ji O:~~ .432
. 23 8J~0 .~83 oJsg . 90 · 04 O. 67
I~I! 8j1; £.240 ~.236 rg7 ra1 .737 tm .6 1 .70 1.0~3 d~g J~9 o:~g~ o.§? I~~~ t~~~
1.1
h9~ 1.~9g h~~
tas US~ 1. 75
1. IiI tg~ 1.4~
hli
1.1 1.91 1.9 r 1.859
1 ~:~~9 ~:~§~ ~:~~ 8j~ U~I i, 1J;~ 1.12~ bH 0.17 I~ 8Jh ............ g.17~ H~ 0.1~ ~.982 .23 6.5 i:~8 1.0 lijl .92~ t!~~ g:§25 pr~ !~ ~.894 3.7ll
Pg, rm g.89~ 4:1~ II .737 f~ .49~ If i: S~ .42 p~ 1. ri~~ 2.g t~~ rr5 h .08
1 I .1 5 r~~3 r§r1 d~ 4.25 Ii I PO~ d~~ pr1 8~ii 1.1 oJ~~ d~ 0.7 1 U~~ Ha~ 1.6 bl~ o.g 6 0.7 0.90
16j~ REW255 = 1 n~i ~:6~~ O:~,~
8.036 O:~~~
~.g26 n~1 ~.049 .580 0.391 1.017 0.~14 O. 32
~:Ir ~. 6 . 7 O. 10
U~~ U~
0.172 0.40~ 0.66 0.218 0.29 1.37 0.37~ ~~I~i ~:o~g
0.15~ 0.51 1.2~~ 1.6 0.307 0.441 nr~ Ug~ 0.3
~.23S l:~h O. 70 h~ 1.4 1.19
1.8 r
0.~8~ h~~ 2.17 III 3. ~ 5: ~
l607
'm r'
p~ 1m q:Y 6 .g 3 ~:61r 0.81
Col urnn Spec : RTX5~2. 2 lO : 0 25MM ending DateTime ;. 5/15/23 17:41 HPChem Method :Vu 6E15
~~~~ &~ Av RRF % RSD Av Rt M = = --"'---=-- -
1 1 O:a2g 7.7~ l~~~i 0.~6~ ~:r~ ~. 1 1.53 .~ o~ .431 ·F 11 ~:54~ :~!~ · 9 .16 ~: ~ p~ 2. 1 O:~~ .~ 3 2. 79 j' 6
· 5 3.
8:0~~ :o~~ .77 IlL r In 0.~11 .6 1 .013 .11 1 .7~ · ~O
1 :~ .OO~ 8·02~ Q30 it .55 . 59 0: oI
d~~ h~! O. 92 · 7 1. 15 18:~~ I III r~ ~. 48 4. 08 .6 .~ 4. 9
O:~~ if g:25
4. ~ .925 5.
.29g .rs I~~~ .57 0.680 O. 17 ~:f3 O. ~O 0.7~ 0.90g o.~ qS4 !~ 7. ~ n§j~ b5g H~ ~. 7 0.55 ~:6gS ~~1~ S·2 7.5751 .0 °r~ q~~ 0.21, 1U7 7. 5
~j,~ 14~ 8:~~~ i~ 7.4~ 0.56 1~:1
'iO ~.1~5 l:l~~ ~. g : 1H 0:~1~ 8:;
.7 2 :31 . ~~ h~~ .2~ Us .2 .37 6~~1~ 9:~§7 ~:3i !I ~.404 11J 1~. 631
oj 1 :~~ h:oW 8:~~r 6.2
8·gg1 11. :l~g ~: g9 ~:1~~ 6. IU~15 d~ 1i:gS 11.5 93
8J4~ :~ 12.1543 11.05 12.20~1 0.471 0.551 7.27 IU1 71 7.1g 1.177 Ip~~~ a:r~ o.L ~:~ I~ ~j17 0.4 3 7. 2 1 .4~~ .2~
1m
~. 7 Ir~70 0.112 .1 3 .00 q~ .461 ~j~ 1 .1~;~
dgij J~~ k~ 79 O. 80 9:~g ~.21j ~:~~ j~ 1R:~9~~ :~7 .68~ i~ 15. 2
o:~~l '.!ill . 6 0.410 l:a~9 J~ 1 .8~6~
l:11' 1 .~ 78 1.029 1 . 3 7 ~:~~ do lhri, Q.3r~ ~.421 8i B:l~3i U~ d~~ b~~ 7. ~ 7. 0.15 ~J~ U~ p4
B:r648 0.1 .~l 17.7781 17.77 2 0.945 1.147 B:~97~ I~ 6:~
il! 0.803 0.989 11 · 24 .6~ 1 . 711
~. 1
I
1 . 7 1 . 1.715 1:9~S ~~ 1 t ~~~~~ H6~ 1.749
a:4~~ rT 1.421 h1 ~.327 p~ rgg~ i: 3 .08 21.1~ 0.6 · 5 d~ 1.M d~2 5. 7 ~U7 0.730 O. 0 7.45
-------------------------
Use Least Square Linear R~ression with weighting factor of inverse concentration for comps with % RSD > 15
Resp_Ratio = xo + xl * Amt_Ratio -~ (j'-
lOX Parameter xO xl CCF c/ f 3 11 Acetone 0.00748 0.03560 0.9975 !f/ n /2
REPORT ID: 23E133 Page 79 of 345
Instrument 10 :06 Beginning OateTime :05/15/23 13:47 Splke Unlts :PPB Ie File :REW253
M lOX Parameters =
5 !
1.4'DIFLUOR~ENZENE 01 Vhlorodi uoromethane Ch oromethane Vinyl chloride Bromomethane Chloroethane Oichlorofluoromethane Trichlorofluoromethane Acrolein 10 l,li 2.Trichloro.1,2,2.trifluoroethane
2: U
Ace one l,l·0ichloroethene tert·Butyl alcohol Acetonitrile 15 Methyl acetate 16 Iodomethane 17 MethYlene cfloride
5 ~8 CarbOn disu fide
Acr{lOnitri e ter .But2l mett\Yl ether (MTBE) 21 trans·1, ·Dichloroethene ~ Isopropyl ether (DIPE) VilJ.Yl acetate 24 l,l,Oichloroethane
2: ~9 2·8utanol tert·Butyl ethyl ether (ETBE) 2·8utanone 28 2.2'Dichloro~ropane 29 cls·1,2·0ich oroethene
5 ~Y Chloroform tert.~l alcohol ~ 8romoch oromethane Tetrahyc!rofuran
I Oibromofluoromethane l,li 1.Trichloroethane Cyc ohexane 2,2,4·Trimethylpentane l,l,Oichloropropene Carbon tetrachloride
1Y tert.~l met~l ether (TJlME) l,2,Oic loroet ane·d4 42 l,2·Dichloroethane 43 Benzene rs Trichloroethene Met~lchrlohexane
20 * 1,2' ic loropropane l,4·0ioxane Bromodichloromethane Dibromomethane 50 2·Chloroethyl vinyl ether 5 51 4.Met~1.2.~ntanone 52 CiS.1(Ji(OiC loropropene ~ CHLOR ENZENE·05 Toluene·d8
~9 Toluene Ethyl methacrhlate trans ·1, 3· Oi c loropropene 58 1,1,2· Trichloroethane 559 2·Hexanone 60 l,3.Oichloro~ropane 61 Tetrachloroe hene
I Oi b~hl oromethane 2·Etbl' ·l·butanol l,2·01bromoethane l·Chlorohexane Chlorobenzene 1i 1,162.Tetrachloroethane
2 ~8 E ~~ enz~ne m· ene p'Xylene o,XYlene
71 Styrene
H IsOPro~Rl benzene 1,2·01 LOROBENZENE·D4
Bromof~rm 1,1,2, ·Tetrachloroethane
i 4· 8romofluorobenzene l,2,3·Trichloropropane trans· 1i 4.0iChl oro·2·butene n.progy benzene Bromo enzene I, 3 ~ 5· Trimethyl benzene
~ 2·C lorotoluene 4.Chlorot~luene
i tert·Buty benzene 1,2,4· Trlmethyl benzene sec·8utyl benzene
fi ~. Isopro~Yltoluene ,3·0ich orobenzene l,2,3·TrimethYlbenzene l,4·0ichlorobenzene
I n· Butyl brozene l,2·01Ch orobenzene 1,2 ·Oi bromo· 3· chl oropropane l,2,4·Trichlorobenzene Hexachlorobutadiene Na~hthalene 97 I, ,3· Trichlorobenzene
&~ ~!~ 14:3~ REW250
======= = = 1 1 1 ........ 90 9B B7 89 92 109 ~ 103 97 95 97 101
~ 96 96 99 100 ........ ............ 92 113 101 ~ ............ .........
90 92 96 ......... ......... 82 .......... .......... .........
.......... ........... 115 97 99 99 ........... ........... 110 ......... .......... 97 87 ~~ 84 84 90 96 97
100 92 98 ........... ............ 94 98 93 99 .......... ........... .. .. __ ...
94 18~ 93 100 90
~8i 98 105 91 ~~ 97 ......... .......... .......... ..
101 97 93 ........ ........... ..........
97 90 98 103 ~ 98 ............ 95 .......... ........ .. .........
95 96 99 101 102 98 101 92 91 92 89 96 95 96 93 102 98 100 101 92 99 ......... 87 97 107 98 97 ........ ......... .. ........
102 107 102 95 94 95 ........... ........... 78 90 81 91 92 95 93 1 1 1 101 91 105 101 ~ 103 .......... ~ 97 90 106 99 99 ....... ......... 88 95 95 98 96 90 100 100 98 95 .......... ......... ........ -
101 91 94
96 91 103 101 95 100
96 96 98 103 98 101 104 98 104
100 ij 99 101 99 103 101 1 1 99 93 92 87 100 99 103 90 102 ............ 99 102 ........... .........
19a 104 100 103 96 97 104 97 101 101 93 97 105 96 103 109 96 98 108 101 101 108 101 13~ 109 99 109 96 180 105 99 193 105 ~~ 112 98 110 98 102 110 95 92 122 99 94 .......... 102 106 ........... 99 95 ...... _ .... 96 100
----
~g~ ~3~ ~~~ 16:~~ J&i~ 52 REW254 55 = ==== = = = 1 1 1 9~ 1 100 m 18~ 104 102 101 107 108 114 101 96 99 99 112 101 100 105 98 110 100 100 105 108 110 91 13~ 104
10~ 188 97 103 11 1 8 88 104 104
103 104 ~ 96 101 112 110 103 18~ 105 108 91 102 100 100 91 109 109 ............ ......... ......... ........ ........
111 96 85 93 96 107 106 §9 100 102 112 103 96 98 101 110 96 100 98 104 111 91 111 109 104 107 94 106 107 107 106 91 100 103
106 106 90 101 103 95 18~ 97 101 103 107 89 100 102 ............ .. .......... ......... ... -_ ....
113 105 90 102 102 100 107 87 105 102 110 10~ 94 1~ 101 110 10 90 103 105 106 89 101 ........... ........... . ......... .........
107 103 90 102 103 118 94 82 97 97 102 109 96 102 96 101 110 ~8 92 107 106 123 94 105 ......... ......... _ ..... ........ ..........
104 105 90 101 104 104 105 87 98 103 105 109 91 103 104 104 97 101 97 105
II
91 102 103 108 91 101 102 104 1 6 90 100 103 104 116 88 92 100
103 101 89 100 103
111 99 82 ~~ ~ 105 101 87 105 104 91 102 105
111 100 93 100 104 110 115 92 110 108 107 106 92 103 104 1 1 1 1 1 109 110 98 101 95
109 1~9 91 182 104
103 13 90 1 6 105 104 105 91 105 104 106 103 87 100 100 105 109 85 108 102 107 105 91 183 102 107 107 ~b 1 1 103 103 104 103 103 .. ......... ......... ........... ........... ...........
105 103 90 105 104
108 108 ~~ 102 104 110 107 101 102 108 104 89 101 101 107 106 89 100 96 111 109 92 100 84 107 106 89 100 18~ 109 106 §g 1~ 108 105 96 1 1 1 10~ 1 100 104 89 106 105 109 90 105 103
105 110 96 100 93 104 102 89 102 102 101 98 87 103 1~ 111 110 91 98 105 107 89 101 102 108 108 89 9B 96 108 109 91 101 108 106 105 89 98 10
109 108 H 98 132 IY~ 105 98 107 ~H ~ 109 105 89
18H 107 90 133 T 106 89 1 ~ 108 108 91 101
107 107 89 99 18~ 112 108 ~ 181 103 106 106 105 89 101 97
111 112 92 101 96 105 106 91 107 103 109 110 91 104 99
Column Spec : RTX502. 2 10 : O. 251+1 Ending OateTime :05/15/23 17:41 HPChern Method :V006E15
&~~ &~~ AvORec t RSD Av Rt M ==== ==== ====== ======= 1 1 1 0 10.085~ 91 110 6 7.72 1.692 95 116 7.6 9.53 1.9294 83 97 7 9.17 UI 93 112 6.1 8.19 93 112 5.7 8.16 94 IY8 6.5 7.~9 2.6381 90 4.9 g. 0 2.8769
96 104 7 .86 3.3964 89 107 1B 7.94 3.4483 91 104 18.81 3.4881 96 115 7 8.21 u~ro 100 118 0.003 1~.70 .. ......... ......... 1 :gg H2R8 93 111 9.3 92 109 4.8 6.30 4.1; 88 105 7.7 9.47 4.3 89 108 4.9 1U8 4.3 100 116 9'1 ua~ 99 115 7. 9.58 93 111 5. 6.~ 4.8965
94 110 5.2 6. 5.6049
97 113 4.4 6.20 §:~~ 93 110 0.803 6.83 .. ......... ....... 0.00 0.0000
94 110 6.4 7.69 um 97 110 5 7.25
86 91 6.1 7.69 7.0742 94 112 6.5 7.~ 7.1957 92 109 4.7 6. 9 7.5750 ............ .. ......... 0.000 2.00 0.0000
95 112 5.3 ~:gs~ 94 109 8.8 11:~~ 95 115 r 7.4§ U~~ 95 114 .7 8.5 101 o.oOa 11.51 . ......... 0.00 i:~~~ 94 112 5.3 6.60 92 111 4.9 6.68 96 112 6.1 7.31 9.2002
96 117 6.3 8.16 9.2158 95 113 5.8 6.90 9.4144 92 4.4 5.93 9.3976
93 111 5.1 6.58 l~:m~ 96 119 8.7 11.23 92 113 4.7 6.21 11.0227
93 11 28.6 11.84 ttl 92 109 4.9 6.64 96 114 5.9 7.~ 100 119 7.9 11.5 101 104 9.4 11.05 12.2091
96 111 6.5 7.2~ 12.5129 1 1 1 15.5374 91 5.6 7.13 12'1 82 ......... 6.3 8.62 13.0 7 99 115 7.6 9.34 B:434g 97 114 6.4 7.62 93 109 4.7 ~.47 13.6890
~X 10~ 7.5 r 13.n04 11 5.5 6. 6 14.1355 93 11 5.9 7. 9 14.1874 95 111 4.7 a. 2 14.5379 ......... ......... 0.000 .00 0.0000 96 lbb 5.~ 7.06 14.8793
~~ h 6.27 IH~~a 6.31 95 112 ~.4 6.91 15.6932 ......... ......... .1 5.72 lU~8 ........... ....... 'O. 6.8 8.96
.. 'O ... 'O-~.4 5.46 16.5678
92 .4 5.99 16.6337 ......... .. -....... 4.6 6.28 lUm 1 1 1 96 116 P 8.04 17.1743 93 109 .1 7.66 17.4508
~~ 110 6.2 7.49 17.~ 109 4.5 6.04
B:n81 95 112 4.7 6.85 7.1 9.51 17.n 2 91 111 5.5 6.9~ B:~~ ........... ........... 5.2 6.5 .......... ....... 4.8 6.44 17.9908 4.6 5.yg 18.~~7 86 106 6.5 8. 5 II: ~M 5.1 6.6~ ......... .......... 7.4 9.5 5.8 7.45 18.8346
88 5.7 7.54 1~.93B5 4.8 6.31 19:~~ 89 5.3 6.69 6.3 7.~ 19.~9 ~g 87 6.8 8. ~6: 2ag 112 7 8.34
87 101 7 9.93 ~um 83 97 7.2 9.35
§§ 101 5 5.97 102 5.8 7.45
--------------------
REPORT ID: 23E133 Page 80 of 345
Compound List Report 06
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title METHOD 8260
Last Update Tue May 16 12:41:48 2023
Response via Initial Calibration
Total Cpnds 97
PK# Compound Name Qlon Exp_RT Rel_RT Cal #Qual A/H ID
--------------------------------------------------------------------------
1 I 1,4-DIFLUOROBENZENE 114 10.08 1.000 A 1 A B
2 T Dichlorodifluoromethane 85 1. 69 0.168 A 1 A B
3 T Chloromethane 50 1. 93 0.191 A 1 A B
4 T Vinyl chloride 62 2.05 0.203 A 1 A B
5 T Bromomethane 94 2.50 0.248 A 1 A B
6 T Chloroethane 64 2.60 0.258 A 1 A B
7 T Dichlorofluoromethane 67 2.64 0.262 A 1 A B
8 T Trichlorofluoromethane 101 2.88 0.285 A 1 A B
9 T Acrolein 56 3.40 0.338 A 1 A B
10 T 1,1,2-Trichloro-1,2,2-trifluor 151 3.45 0.342 A/ 1 A B
11 T Acetone 43 3.49 0.346 L 1 A B
12 T 1,1-Dichloroethene 61 /"3.66 0.362 A 2 A B
13 T tert-Butyl alcohol 59 3.80 0.377 A 1 A B
14 T Acetonitrile 41 0.00 0.000 A 2 A B
15 T Methyl acetate 74 4.18 0.414 A 1 A B
16 T Iodomethane 142 4.12 0.408 A 1 A B
17 T Methylene chloride 49 4.39 0.435 A 2 A B
18 T Carbon disulfide 76 4.37 0.433 A 1 A B
19 T Acrylonitrile 53 4.64 0.460 A 2 A B
20 T tert-Butyl methyl ether (MTBE) 73 4.68 0.464 A 1 A B
21 T trans-1,2-Dichloroethene 96 / 4.89 0.485 A 1 A B
22 T Isopropyl ether (DIPE) 45 5.60 0.556 A 1 A B
23 T Vinyl acetate 43 5.84 0.579 A 1 A B
24 T 1,1-Dichloroethane 63 5.75 0.570 A 2 A B
25 T 2-Butanol 45 ~.36 0.631 A 1 A B
26 T tert-Butyl ethyl ether (ETBE) 59 6.53 0.647 A 1 A B
27 T 2-Butanone 43 6.82 0.676 A 1 A B
28 T 2,2-Dichloropropane 77 7.07 0.701 A 2 A B
29 T cis-1,2-Dichloroethene 96 7.20 0.714 A 1 A B
30 T Chloroform 83 /7.57 0.751 A 2 A B
31 T tert-Amyl alcohol 59 8.49 0.842 A 1 A B
32 T Bromochloromethane 130 7.95 0.789 A 1 A B
33 T Tetrahydrofuran 42 8:08 0.801 A 2 A B
34 S Dibromofluoromethane 111 8.10 0.803 A 1 A B
35 T 1,1,1-Trichloroethane 97 8.49 0.842 A 2 A B
36 T Cyclohexane 84 8.47 0.840 A 1 A B
37 T 2,2,4-Trimethylpentane 57 8.46 0.839 A 1 A B
38 T 1,1-Dichloropropene 110 8.85 0.878 A 1 A B
39 T Carbon tetrachloride 119 9.02 0.894 A 1 A B
40 T tert-Amyl methyl ether (TAME) 73 9.20 0.912 A 2 A B
41 S 1,2-Dichloroethane-d4 65 9.22 0.914 A 1 A B
42 T 1,2-Dichloroethane 62 /" 9.41 0.933 A 1 A B
43 T Benzene 78 t/ 9.40 0.932 A 2 A B
44 T Trichloroethene 130 10 :67 1. 058 A 3 A B
45 T Methylcyclohexane 83 10.75 1. 066 A 2 A B
46 T 1,2-Dichloropropane 63 11.02 1. 093 A 1 A B
47 T 1,4-Dioxane 88 11.58 1.148 A 1 A B
48 T Bromodichloromethane 83 11.46 1.136 A 1 A B
49 T Dibromomethane 93 11.54 1.144 A 2 A B
50 T 2-Chloroethyl vinyl ether 63 12.15 1. 205 A 1 A B
51 T 4-Methyl-2-pentanone 43 12.20 1. 210 A 3 A B
52 T cis-1,3-Dichloropropene 75 12.51 1. 241 A 3 A B
S(A 51\1(~3 REPORT ID: 23E133 Page 81 of 345
53 I CHLOROBENZENE-D5 117 15.54 1. 000 A 2 A B
54 S Toluene-d8 98 12.91 0.831 A 1 A B
55 T Toluene 91 13.04 0.840 A 1 A B
56 T Ethyl methacrylate 69 13.49 0.868 A 1 A B
57 T trans-1,3-Dichloropropene 75 /13.43 0.865 A 1 A B
58 T l,l,2-Trichloroethane 97 13.69 0.881 A 2 A B
59 T 2-Hexanone 43 13.77 0.886 A 1 A B
60 T 1,3-Dichloropropane 76 14.13 0.910 A 1 A B
61 T Tetrachloroethene 164 14.19 0.913 A 3 A B
62 T Dibromochloromethane 129 14.54 0.936 A 1 A B
63 T 2-Ethyl-1-butanol 43 0.00 0.000 A 3 A B
64 T 1,2-Dibromoethane 107 14.87 0.957 A 1 A B
65 T 1-Chlorohexane 91 15.23 0.980 A 1 A B
66 T Chlorobenzene 112 15.60 1. 004 A 1 A B
67 T 1, 1, 1, 2-Tetrachloroethane 131 ' 15.69 1.010 A 1 A B
68 T Ethylbenzene 91 15.71 1.011 A 1 A B
69 T m-Xylene & p-Xylene 91 I 15.84 1.019 A 1 A B
70 T o-Xylene 91 j 16.56 1. 066 A 1 A B
71 T Styrene 104) 16.63 1.070 A 2 A B
72 T Isopropylbenzene 105 )17.17 1.105 A 3 A B
73 I l,2-DICHLOROBENZENE-D4 152 19.42 1.000 A 1 A B
74 T Bromoform 173 17.17 0.884 A 2 A B
75 T 1, 1, 2, 2-Tetrachloroethane 83 17.45 0.898 A 1 A B
76 S 4-Bromofluorobenzene 95 17.55 0.904 A 2 A B
77 T 1, 2, 3-Trichloropropane 110 17.67 0.910 A 1 A B
78 T trans-1,4-Dichloro-2-butene 53 17.77 0.915 A 1 A B
79 T n-Propylbenzene 91 17.77 0.915 A 2 A B
80 T Bromobenzene 156 17.81 0.917 A 1 A B
81 T l,3,5-Trimethylbenzene 105 .17.98 0.926 A 2 A B
82 T 2-Chlorotoluene 91 ~ 17.99 0.926 A 1 A B
83 T 4-Chlorotoluene 91/,18.06 0.930 A 1 A B
84 T tert-Butylbenzene 134 18.43 0.949 A 1 A B
85 T l,2,4-Trimethylbenzene 105 /18.47 0.951 A 1 A B
86 T sec-Butylbenzene 105 ,18.68 0.962 A 1 A B
87 T p-Isopropyltoluene 119 18.83 0.970 A 2 A B
88 T l,3-Dichlorobenzene 146 18.94 0.975 A 2 A B
89 T 1,2,3-Trimethylbenzene 105 19.02 0.979 A 2 A B
90 T 1,4-Dichlorobenzene 146 1 19 .05 0.981 A 2 A B
91 T n-Butylbenzene 91 ' 19.28 0.993 A 2 A B
92 T 1,2-Dichlorobenzene 146 19.44 1. 001 A 1 A B
93 T 1,2-Dibromo-3-chloropropane 157 ' 20.22 1.041 A 1 A B
94 T 1,2,4-Trichlorobenzene 180 21.05 1. 084 A 2 A B
95 T Hexachlorobutadiene 225 ' 21.18 1. 091 A 2 A B
96 T Naphthalene 129 21. 33 1.098 A 1 A B
97 T 1,2,3-Trichlorobenzene 180 21. 57 1.111 A 2 A B
Cal A == Average L == Linear LO == Linear w/origin Q == Quad QO == Quad w/origin
#Qual == number of qualifiers
A/H == Area or Height
ID R == R.T. B == R.T. & Q Q == Qvalue L == Largest A == All
--------------------------------------------------------------------------
V006E15.M Tue May 16 13:04:22 2023
~/!1(t3
REPORT ID: 23E133 Page 82 of 345
BFB
Data File D:\HPCHEM\1\DATA\23E15\REW247.D
Acq On 15 May 2023 1:21 pm
Sample BFB06E11
Vial: 1
Operator: LYamas
06 Inst
Multiplr: Misc T/CHK 1. 00
MS Integration Params: RTE.P
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title : METHOD 8260
ft\bundance TIC: REW247.D
600000
500000
400000
300000
200000
100000 \...
0
Time-> 16~00 16~50 doo 17~50 18~00 18~50 19.00
I
Abundance Average of 17.524 to 17.549 min.: REW247.D (-)
95
100000
80000 174
60000
75
40000
20000 50
37
I 5~ .?I~ ii .11 II }1 ~~ .dlll 0 lid 44 104 117 128 141 149
mlz--> 3'0 4'0 50 6'0 7'0 8'0 9'0 100 110 120 130 140 150 160 1'70 180
AutoFind: Scans 1111, 1112, 1113; Background Corrected with Scan 1101
I Target I
ReI. to I
Lower I Upper I
ReI. .~ Raw I Result I Mass Mass Limit% Limit% Abn% Abn Pass/Fail
----------------------------------------------------------------------
50 95 15 40 16.1 ,. 17574 PASS
75 95 30 60 42.6. 46548 PASS
95 95 100 100 100.0 109200 PASS
96 95 5 9 6.81" 7473 PASS
173 174 0.00 2 0.0 0 PASS
174 95 50 100 72.8/ 79544 PASS
175 174 5 9 7.8/ 6188 PASS
176 174 95 101 99.7/ 79317 PASS
177 176 5 9 5.9 4642 PASS
REW247.D V006E15.M
REPORT ID: 23E133 Page 83 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW248.D
Acq On 15 May 2023 1:47 pm
Sample V006E151
Vial: 2
Operator: LYamas
Inst 06
Misc 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
32) Bromochloromethane
35) 1 /1,l-Trichloroethane
10.09 114
15.54 117
19.42 152
8.10 111
9.22 65
12.92 98
17.55 95
50
62
94
64
67
101
151
43
61
59
74
142
49
76
53
73
96
45
43
63
1. 93
2.05
2.50
2.60
2.64
2.87
3.45
3.51
3.66
3.82 /'
4.18
4.10
4.41
4.37
4.64
4.68
4.91
5.61
5.84
5.75
6.55
6.86
7.09
7.20
7.58
7.95
8.50
c 59
43
77
/96
83
130
97
4047991
3493918
1340035
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
37993 0.29 ug/l 0.00
Recovery = 2.90%
25143 0.28 ug/l 0.00
Recovery = 2.80%
137203 0.30 ug/l 0.00
Recovery = 3.00%
47036 0.31 ug/l 0.00
Recovery = 3.10%
46653
56805
41603
30604
64666
58741
38048
69384
60113
30499
6329
70848
75417
126770
23974
54839
44211
120328
45884
73765
92956
36323
42723
44374
74424
23360
62496
0.26 ug/l
0.33 ug/l
0.29 ug/l
0.29 ug/l
0.27 ug/l
0.28 ug/l
0.34 ug/l
2.12 ug/l
0.27 ug/l
6.73 ug/l
0.58 ug/l
0.29 ug/l
0.48 ug/l
0.24 ug/l
1. 31 ug/l
0.25 ug/l
0.29 ug/l
0.30 ug/l
0.37 ug/l
0.30 ug/l
0.28 ug/l
1. 50 ug/l
0.32 ug/l
0.29 ug/l
0.30 ug/l
0.30 ug/l
0.31 ug/l
Qvalue
73
86
77
76
87
85
87
90
93
78
85
92
95
100
93
56
94
97
96
94
97
98
87
95
94
84
97
(#) = qualifier out of range (m) = manual integration
REW248.D V006E15.M Tue May 16 13:02:58 20233c.~ $/(1/z3 Page 1
REPORT ID: 23E133 Page 84 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW248.D
Acq On 15 May 2023 1:47 pm
Sample V006E151
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
36) Cyclohexane
38) 1,1-Diehloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Diehloroethane
43) Benzene
44) Triehloroethene
45) Methyleyclohexane
46) l,2-Diehloropropane
47) 1,4-Dioxane
48) Bromodiehloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Diehloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Diehloropropene
58) 1,l,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetraehloroethene
62) Dibromoehloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,l,2,2-Tetrachloroethane
78) trans-1,4-Diehloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
81) 1,3,5-Trimethylbenzene
82) 2-Chlorotoluene
83) 4-Chlorotoluene
84) tert-Butylbenzene
8.48
8.85
9.01
9.22
9.42
9.40
10.66
10.75
11.02
11.55
11.46
11.54
12.18
12.23
12.51
13.06
13.50
13.44
13.68
13.81
14.14
14.19
14.54
14.89
15.23
15.60
15.69
15.71
15.84
16.58
16.64
17.17
17.19
17.46
17.98
17.77
17.81
17.98
17.99
18.06
18.43
84
110
119
73
62
~78
130
83
63
88
83
93
63
43
75
91
69
75
97
43
76
164
129
107
91
"'112
131
/ 91
/ 91
/ 91
104
105
173
83
53
91
156
1 105
! 91
I 91
134
51372
18908
48271
79148
32408
167389
44625
50570
40949
1752
52122
18674
4676
78180
55272
173194
29549
43010
26008
51677
41641
35848
30880
24282
68849
111434
36902
212708
313345
154546
118095
203195
14638
23049
8829
250260
42648
162438
156058
128102
40580
0.24 ug/l
0.28 ug/l
0.30 ug/l
0.30 ug/l
0.29 ug/l
0.31 ug/l
0.30 ug/l
0.22 ug/l
0.32 ug/l
3.17 ug/l
0.31 ug/l
0.28 ug/l
0.43 ug/l
1. 34 ug/l
0.27 ug/l
0.30 ug/l
0.29 ug/l
0.29 ug/l
0.32 ug/l
1. 27 ug/l
0.28 ug/l
0.29 ug/l
0.30 ug/l
0.30 ug/l
0.29 ug/l
0.30 ug/l
0.29 ug/l
0.31 ug/l
0.62 ug/l
0.30 ug/l
0.30 ug/l
0.31 ug/l
0.30 ug/l
0.26 ug/l
0.38 ug/l
0.31 ug/l
0.31 ug/l
0.31 ug/l
0.30 ug/l
0.31 ug/l
0.33 ug/l
(#) = qualifier out of range (m) = manual integration ~ lA--
Qvalue
89
90
95
92
94
98
94
84
89
99
82
92
60
94
92
99
77
90
92
94
81
94
92
97
98
98
98
99
99
96
96
97
97
81
80
97
91
96
98
97
97
REW248.D V006E15.M Tue May 16 13:02:59 2023 ~. a
5/11(V
Page 2
REPORT ID: 23E133 Page 85 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW248.D
Aeq On 15 May 2023 1:47 pm
Sample V006E151
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
85 ) 1, 2, 4-Trimethylbenzene 18.47 105 166371 0.32 ug/l 96
86) see-Butylbenzene 18.68 105 233104 0.32 ug/l 99
87) p-Isopropyltoluene 18.84 119 184307 0.33 ug/l 99
88) l,3-Diehlorobenzene 18.94 146 86000 0.33 ug/l 98
89 ) l,2,3-Trimethylbenzene 19.02 (105 146005 0.31 ug/l 99
90) l,4-Diehlorobenzene 19.06 146 82833 0.32 ug/l 98
91) n-Butylbenzene 19.28 ~ 91 178346 0.33 ug/l 98
92) l,2-Diehlorobenzene 19.45 /146 71851 0.33 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.21 157 4652 0.33 ug/l 86
94) 1, 2, 4-Triehlorobenzene 21. 05 (180 52284 0.36 ug/l 97
95) Hexaehlorobutadiene 21.18 \ 225 34006 0.39 ug/l 93
96) Naphthalene 21. 33 128 92025 0.44 ug/l 99
97) l,2,3-Triehlorobenzene 21.59 ;180 42699 0.39 ug/l 96
~CA--
---------------------------------------------!I ~! (~ -~ ------------------
(#) = qualifier out of range (m) = manual integration
REW248.D V006E15.M Tue May 16 13:02:59 2023 Page 3
REPORT ID: 23E133 Page 86 of 345
i
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW248.D
Aeq On 15 May 2023 1:47 pm
Sample V006E151
Vial: 2
Operator: LYamas
06
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:02 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
nse via
4000000
1600000'
1000000
800000
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: D
~i~~~_-_> ______ ~~~~~~~~~=-~-=~~~==~~==~~~=-~~~~-===~-===~~~
REW248.D V006E15.M Tue May 16 13:03:02 2023 Page 4
REPORT ID: 23E133 Page 87 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW249.D
Acq On 15 May 2023 2:13 pm
Sample V006E152
Vial: 3
Operator: LYamas
06
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:04 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) 1/4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1/2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1/2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1/1/2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2/2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
8.10 111
9.22 65
12.92 98
17.55 95
1.69 85
1. 93 50
2.05 62
2.50 94
2.60 64
2.64 67
2.88 101
3.40 56
3.45 151
3.49 43
3.66 ",61
3.82 59
4.18 74
4.14 142
4.39 49
4.37 76
4.64 53
4.70 73
4.89 ·96
5.60 45
5.86 43
5.75 63
6.55 59
6.84 43
7.07 77
7.20 ! 96
7.57 83
3991932
3506540
1340560
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
58080 0.45 ug/l 0.00
Recovery = 4.50%
40049 0.45 ug/l 0.00
Recovery = 4.50%
206877 0.45 ug/l 0.00
Recovery = 4.50%
68150 0.45 ug/l 0.00
Recovery = 4.50%
71993
79008
77579
60590
43450
113245
101798
19750
56017
82686
101676
45579
4266
119639
105307
236333
41767
102541
72355
181807
40037
114614
158528
59971
65518
67618
116649
0.45 ug/l
0.45 ug/l
0.45 ug/l
0.43 ug/l
0.42 ug/l
0.48 ug/l
0.50 ug/l
1. 96 ug/l
0.51 ug/l
3.13 ug/l
0.46 ug/l
10.20 ug/l
0.40 ug/l
0.50 ug/l
0.67 ug/l
0.45 ug/l
2.31 ug/l
0.48 ug/l
0.48 ug/l
0.46 ug/l
0.33 ug/l
0.47 ug/l
0.49 ug/l
2.51 ug/l
0.49 ug/l
0.45 ug/l
0.48 ug/l
Qvalue
93
80
85
89
78
99
94
84
98
96
99
57
50
98
96
99
92
9$
95
99
71
97
95
96
87
99
95
(#) = qualifier out of range (m) = manual integration 6 ~
REW249.D V006E15.M Tue May 1613:05:10 2023 5/(1~S Page 1
REPORT ID: 23E133 Page 88 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW249.D
Acq On 15 May 2023 2:13 pm
Sample V006E152
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 3
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:04 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1 /1,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-l,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95 130
8.12 42
8.50 97
8.48 84
8.86 110
9.01 119
9.20 73
9.42 62
9.40 78
10.67 130
10.73 83
11. 03 ./ 63
11.59 88
11.46 83
11.54
12.15
12.23
12.51
13.06
13.50
13.43
13.68
13.78
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.72
15.84
16.58
16.64
17.17
17.17
17.46
17.65
17.69
.. 93
63
43
75
{-91
69
75
97
43
76
164
129
107
_ 91
112
131
./ 91
91
,/ 91
/104
105
.173
83
110
53
17 . 77 ./ 91
17.81 156
36968
11750
96364
89534
31778
80038
118294
53663
265102
66697
97775
61812
8070
89660
30343
8118
117192
94153
282723
45202
66643
40504
69294
69552
56658
50848
36465
108915
174498
61121
338859
493729
253909
194325
323919
22995
44101
11186
2614
400979
66286
0.48 ug/l
0.87 ug/l
0.48 ug/l
0.43 ug/l
0.48 ug/l
0.51 ug/l
0.46 ug/l
0.48 ug/l
0.49 ug/l
0.46 ug/l
0.44 ug/l
0.49 ug/l
14.82 ug/l
0.53 ug/l
0.47 ug/l
0.75 ug/l
2.04 ug/l
0.47 ug/l
0.49 ug/l
0.44 ug/l
0.45 ug/l
0.49 ug/l
1.69 ug/l
0.47 ug/l
0.45 ug/l
0.49 ug/l
0.45 ug/l
0.45 ug/l
0.47 ug/l
0.48 ug/l
0.49 ug/l
0.98 ug/l
0.49 ug/l
0.50 ug/l
0.49 ug/l
0.47 ug/l
0.50 ug/l
0.49 ug/l
0.11 ug/l
0.50 ug/l
0.48 ug/l
Qvalue
99
65
95
90
99
94
92
98
98
94
89
98
99
99
91
74
95
94
98
95
93
98
98
92
96
96
95
97
99
99
99
99
100
99
99
94
98
71
88
98
94
REPORT ID: 23E133 Page 89 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW249.D
Aeq On 15 May 2023 2:13 pm
Sample V006E152
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(c. l' Reviewed)
Vial: 3
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:04 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81) l,3,5-Trimethylbenzene 17.98 t" 105 250725 0.48 ug/l 98
82) 2-Chlorotoluene 17.99 _ 91 241328 0.47 ug/l 99
83) 4-Chlorotoluene 18.06 4 91 195576 0.48 ug/l 94
84) tert-Butylbenzene 18.43 134 59862 0.48 ug/l 99
85) 1, 2, 4-Trimethylbenzene 18.47 .... 105 259543 0.51 ug/l 97
86) see-Butylbenzene 18,.68 /105 363821 0.50 ug/l 98
87) p-Isopropyltoluene 18.83 119 279358 0.50 ug/l 99
88) l,3-Diehlorobenzene 18.94 _146 126305 0.48 ug/l 96
89) l,2,3-Trimethylbenzene 19.02 ' 105 231114 0.50 ug/l 97
90) l,4-Diehlorobenzene 19.05
,
146 128248 0.49 ug/l 97
'< 91 ) n-Butylbenzene 19.28 91 256912 0.48 ug/l 97
92) l,2-Diehlorobenzene 19.44 146 107158 0.49 ug/l 94 r 93) l,2-Dibromo-3-ehloropropan 20.22 157 6706 0.47 ug/l 90
94) 1,2,4-Triehlorobenzene 21. 05 .r 180 71234 0.50 ug/l 98
95) Hexaehlorobutadiene 21.18 225 45167 0.51 ug/l 99
96 ) Naphthalene 21. 33 128 103639 0.49 ug/l 98
97) 1, 2, 3-Triehlorobenzene 21.59 /180 52797 0.48 ug/l 93
(#) = qualifier out of range (m) = manual integration
REW249.D V006E15.M Tue May 16 13:05:11 2023 Page 3
REPORT ID: 23E133 Page 90 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW249.D
Aeq On 15 May 2023 2:13 pm
Sample V006E152
Mise 0.5ppb 8260/2.5ppb KET-AA/12.Sppb TBA
Vial: 3
Operator: LYamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:04 2023 Quant Results File: V006E1S.RE
i
Method
Title
Last Update
e via
3200000
3000000
2400000
2000000
D:\HPCHEM\1\METHODS\V006E1S.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
u:r z w ~ w m
0 a:
0
::l
...J u..
15
...t.
rfil'!le--> __ ~ ____ -""--,,,-=--_---,-,,=-_~= __ =~_-,-==-_--,-===-_--=-=_---,-=~_,-=-,-==--_-=.:.=-__ -,
REW249.D V006E15.M Tue May 16 13:05:14 2023 Page 4
REPORT ID: 23E133 Page 91 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Acq On 15 May 2023 2:39 pm
Sample V006E153
Misc 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
Quant Time: May 16 13:05 2023
Vial: 4
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Cone Units Dev(Min)
10.09
15.54
19.42
114 3815846
117 3307080
152 1289255
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111
9.22 65
12.92 98
17.55 95
1. 69
1.93
2.05
2.50
2.60
2.64
2.87
3.40
3.47
3.49
3.66
3.82
4.20
4.12
4.39
4.37
4.64
4.70
4.89
5.61
5.86
5.75
6.53
6.84
7.07
7.20
7.58
85
50
62
94
64
67
101
56
151
43
~ 61
59
74
142
49
76
53
73
/ 96
45
43
/63
59
43
77
96
83
120247 0.98 ug/l 0.00
Recovery = 9.80%
82904 0.97 ug/l 0.00
Recovery = 9.70%
449340 1.05 ug/l 0.00
Recovery = 10.50%
148893 1.02 ug/l 0.00
Recovery = 10.20%
150383
154743
169831
128679
100169
218071
196026
43352
104512
87099
202582
86580
11781
228491
165142
488158
73042
184704
140384
368437
109860
231943
290176
103199
133173
136259
228566
0.99 ug/l
0.92 ug/l
1. 03 ug/l
0.95 ug/l
1. 01 ug/l
0.97 ug/l
1. 00 ug/l
4.51 ug/l
0.99 ug/l
3.72 ug/l
0.96 ug/l
20.27 ug/l
1.14 ug/l
0.99 ug/l
1.11 ug/l
0.97 ug/l
4.22 ug/l
0.90 ug/l
0.97 ug/l
0.98 ug/l
0.94 ug/l
0.99 ug/l
0.93 ug/l
4.52 ug/l
1. 05 ug/l
0.95 ug/l
0.99 ug/l
Qvalue
77
89
93
98
92
100
96
81
95
87
99
77
70
100
98
99
98
91
98
98
90
99
99
98
92
96
98
(#) = qualifier out of range (m) = manual integration ~
REW250. D V006E15. M Tue May 16 13: 06: 00 2023 ~:;L/( 'v Page 1 51(1' ~ REPORT ID: 23E133 Page 92 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Acq On 15 May 2023 2:39 pm
Sample V006E153
Misc 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 4
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:05 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,1,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80} Bromobenzene
81) 1,3,5-Trimethylbenzene
82) 2-Chlorotoluene
7.95 130
8.49 97
8.48 84
8.85 110
9.02 119
9.20 73
9.41 62
9.40 78
10.67 130
10.73 83
11.02 63
11.46 83
11. 54 93
12.18 63
12.21 43
12.51 75
13.06 91
13.50 69
13.43 .(75
13.69 97
13.79 43
14.14 76
14.19 164
14.54 129
14.89 107
15.23 r 91
15.60 112
15.69 131
15.72 "...91
15.84 _ 91
16.58 /91
16.64 104
17.17 .-105
17.17 ..-173
17.45 83
17.67 110
17.77.... 53
17.77 -91
17.81 156
17.98 105
17.99 91
67470
186594
190247
62753
147951
222528
100158
514761
137045
207804
116884
163388
58609
8101
249272
176356
558925
84657
130233
76769
170644
135650
118695
92534
71083
233909
348259
118094
658042
987378
483001
365555
631717
43475
84314
22134
22010
800134
128714
505985
482053
0.92 ug/l
0.98 ug/l
0.95 ug/l
1. 00 ug/l
0.98 ug/l
0.91 ug/l
0.94 ug/l
1. 00 ug/l
0.99 ug/l
0.97 ug/l
0.97 ug/l
1. 02 ug/l
0.95 ug/l
0.78 ug/l
4.53 ug/l
0.93 ug/l
1.04 ug/l
0.88 ug/l
0.93 ug/l
0.99 ug/l
4.42 ug/l
0.98 ug/l
1. 00 ug/l
0.94 ug/l
0.94 ug/l
1. 03 ug/l
1. 00 ug/l
0.98 ug/l
1. 01 ug/l
2.07 ug/l
0.99 ug/l
0.99 ug/l
1. 02 ug/l
0.92 ug/l
0.99 ug/l
1. 02 ug/l
0.99 ug/l
1.04 ug/l
0.97 ug/l
1. 01 ug/l
0.97 ug/l
Qvalue
93
97
98
96
99
96
99
98
97
96
98
93
97
72
97
98
97
95
97
93
89
99
99
98
100
100
99
95
100
100
99
100
99
99
93
80
86
99
96
97
100
(#) = qualifier out of range (m) = manual integration ;;~ )
REW250. D V006E15. M Tue May 16 13,06,01 2023 fin f"" J Page 2
REPORT ID: 23E133 Page 93 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Aeq On 15 May 2023 2:39 pm
Sample V006E153
Mise 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed
Vial: 4
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:05 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
83) 4-Chlorotoluene 18.06 91 405372 1. 03 ug/l 97
84) tert-Butylbenzene 18.43 .134 117555 0.98 ug/l 86
85) l,2,4-Trimethylbenzene 18.47 105 498497 1. 01 ug/l 96
86) see-Butylbenzene 18.68 105 708889 1. 02 ug/l 99
87) p-Isopropyltoluene 18.83 119 535337 0.99 ug/l 97
88) l,3-Diehlorobenzene 18.94 146 252530 1. 00 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.02 105 445557 1. 00 ug/l 98
90) l,4-Diehlorobenzene 19.06 146 248895 0.98 ug/l 100
91) n-Butylbenzene 19.28 91 504196 0.98 ug/l 99
92) l,2-Diehlorobenzene 19.44 146 213399 1. 02 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.21 157 12515 0.92 ug/l 98
94) l,2,4-Triehlorobenzene 21.05 180 129155 0.94 ug/l 98
95) Hexaehlorobutadiene 21.18 225 90244 1. 06 ug/l 96
96) Naphthalene 21.33 128 190668 0.95 ug/l 97
97) l,2,3-Triehlorobenzene 21.57 180 105899 1. 00 ug/l 98
:? :3j(.f-n ( ~ 1
------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
REW250.D V006E15.M Tue May 16 13:06:01 2023 Page 3
REPORT ID: 23E133 Page 94 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW250.D
Aeq On 15 May 2023 2:39 pm
Sample V006E153
Mise 1ppb 8260/5ppb KET-AA/25ppb TBA
Vial: 4
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:05 2023 Quant Results File: V006E15.RE
i
Method
Title
Last Update
Response via
li\bundance
! 40000001
38000001
!
3600000j
i
34000001
I
I
3200000i
i
i
I
30000001
i
2800000:
I
26000001
I
24000001
i
i
22000001
I
20000001
1
18000001
I
i6000001
14000001
!
12000001
1000000]
800000
i [irne-:~_~
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW250.D
REW250.D V006E15.M Tue May 16 13:06:03 2023 Page 4
REPORT ID: 23E133 Page 95 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW251.D
Acq On 15 May 2023 3:05 pm
Sample V006E154
Vial: 5
Operator: LYamas
06
Misc 2ppb 8260/10ppb KET-AA/50ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22} Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
8.10 111
9.22 65
12.92 98
17.55 95
1. 70
1. 93
2.05
2.51
2.60
2.64
2.88
3.40
3.45
3.49
3.66
3.82
4.20
4.12
4.39
4.37
4.64
4.68
4.91
5.60
85
50
62
94
64
67
101
56
151
43
./ 61
59
74
142
49
76
53
73
96
( 45
43
63
59
43
77
5.84
5.75 /
6.55
6.84
7.07
7.20
7.58
/ 96
83
3845602
3365890
1298844
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
252349 2.03 ug/l 0.00
Recovery = 20.30%
180555 2.09 ug/l 0.00
Recovery = 20.90%
953811 2.18 ug/l 0.00
Recovery = 21.80%
309988 2.11 ug/l 0.00
Recovery = 21.10%
309277
346662
357869
269797
196082
490068
407376
109073
220328
189733
442969
220896
23332
496686
338399
1025563
180342
431042
311592
806286
222879
509818
707656
230218
282038
316271
489316
2.01 ug/l
2.03 ug/l
2.16 ug/l
1. 98 ug/l
1.96 ug/l
2.15 ug/l
2.07 ug/l
11. 25 ug/l
2.07 ug/l
11.17 ug/l
2.09 ug/l
51. 31 ug/l
2.25 ug/l
2.14 ug/l
2.25 ug/l
2.03 ug/l
10.34 ug/l
2.07 ug/l
2.14 ug/l
2.12 ug/l
1. 90 ug/l
2.15 ug/l
2.25 ug/l
10.01 ug/l
2.21 ug/l
2.20 ug/l
2.11 ug/l
Qvalue
88
93
98
91
91
100
99
97
99
95
98
89
99
98
97
99
93
97
96
99
94
98
98
98
98
95
98
(#) = qualifier out of range (m) = manual integration
REW251.D V006E15.M Tue May 16 13:06:54 2023
REPORT ID: 23E133 Page 96 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW251.D
Acq On 15 May 2023 3:05 pm
Sample V006E154
Misc 2ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 5
Operator: LYamas
Inst 06
Mul tiplr: 1. 00
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l /1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95 130
8.08 42
8.50 97
8.46 84
8.85 110
9.02 119
9.20 73
9.42 62
9.40 78
10.67 130
10.75/83
11.03 /63
11.58 88
11.46 <83
11. 54 93
12.16 63
12.21 43
12.51 -75
13.06 91
13.49 69
13.43 ./ 75
13.69 97
13.78 43
14.14 76
14.19 164
14.54 129
14.89 107
15.23 r 91
15.60 112
15. 69 ~131
15.71 r91
15.84 91
./
16.56 ~ 91
16.64 104
17 .17 ..l05
17.17..173
17.46 83
17.67 110
17.77" 53
17.77'" 91
17.81 156
157707
30822
390985
427109
131446
314816
520054
227805
1120908
290397
447568
249801
23328
340037
130658
22711
612168
410238
1199073
202519
295589
165943
415196
301971
257857
204679
161860
496386
775106
266450
1420621
2144800
1060204
819395
1374288
95130
180340
45447
45309
1718255
282700
(#) = qualifier out of range (m) = manual integration
REW251.D V006E15.M Tue May 16 13:06:54 2023
2.15 ug/l
2.38 ug/l
2.03 ug/l
2.12 ug/l
2.07 ug/l
2.08 ug/l
2.10 ug/l
2.11 ug/l
2.15 ug/l
2.08 ug/l
2.08 ug/l
2.06 ug/l
44.48 ug/l
2.10 ug/l
2.10 ug/l
2.18 ug/l
11. 03 ug/l
2.15 ug/l
2.18 ug/l
2.07 ug/l
2.08 ug/l
2.11 ug/l
10.57 ug/l
2.14 ug/l
2.14 ug/l
2.05 ug/l
2.10 ug/l
2.15 ug/l
2.19 ug/l
2.17 ug/l
2.14 ug/l
4.43 ug/l
2.14 ug/l
2.18 ug/l
2.17 ug/l
1.99 ug/l
2.10 ug/l
2.07 ug/l
2.03 ug/l
2.21 ug/l
2.10 ug/l
Qvalue
97
97
99
95
99
96
97
99
100
98
99
100
89
96
98
99
99
96
99
97
99
96
97
100
98
97
98
100
99
100
100
99
99
98
99
98
95
89
84
100
99
REPORT ID: 23E133 Page 97 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW251.D
Aeq On 15 May 2023 3:05 pm
Sample V006E154
Mise 2ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 5
Operator: LYamas
Inst 06
Multiplr: 1. 00
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81 ) l,3,5-Trimethylbenzene 17.98 /105 1081651 2.15 ug/l 100
82) 2-Chlorotoluene 17.99 ..-91 1084144 2.16 ug/l 99
83) 4-Chlorotoluene 18.06 ---91 835324 2.11 ug/l 98
84) tert-Butylbenzene 18.43 < 134 263746 2.19 ug/l 97
85) 1, 2, 4-Trimethylbenzene 18.47 105 1041492 2.10 ug/l 99
86) see-Butylbenzene 18.68 ; 105 1555759 2.23 ug/l 100
87) p-Isopropyltoluene 18.83 119 1185955 2.17 ug/l 99
88) l,3-Diehlorobenzene 18.94 L 146 547698 2.16 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.02 105 975483 2.16 ug/l 100
I
90) l,4-Diehlorobenzene 19.06/146 549441 2.16 ug/l 99
91 ) n-Butylbenzene 19.28 L 91 1102336 2.13 ug/l 100
92) l,2-Diehlorobenzene 19.44 ,146 472239 2.23 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.22 157 27927 2.04 ug/l 100
94) l,2,4-Triehlorobenzene 21. 05 I 180 294202 2.12 ug/l 98
95) Hexaehlorobutadiene 21.18 225 189957 2.22 ug/l 99
96) Naphthalene 21.33 128 427345 2.11 ug/l 99
I 97) l,2,3-Triehlorobenzene 21.57 '180 233695 2.19 ug/l 97
~L~ :/ !~1t1(~)
----------------------------------------------------------------,;Ji------
(#) = qualifier out of range (m) = manual integration
REW251.D V006E15.M Tue May 16 13:06:55 2023 Page 3
REPORT ID: 23E133 Page 98 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW251.D
Acq On 15 May 2023 3:05 pm
Sample V006E154
Mise 2ppb 8260/10ppb KET-AA/50ppb TBA
Vial: 5
Operator: LYamas
06
1.00
Inst
Multiplr:
MS Integration Params: RTE.P
Quant Time: May 16 13:06 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
f,bundance
40000001
3800000
3600000 1
3400000
3200000
I
3000000j
1
28000001
1
26000001
24000001
I
2200000
2000000 1
1800000
16000001
1400000j ,
12000001
i
, 10000001
800000
600000
400000
200000
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW251.D
u.i z
W
N
~ cr g
-' u..
~-
Cll
::;; 1-:
i 0~99~"-'~-,~~~'-~'-~~-',,-'~-r~'-~'-~~-'~~~'-~~-'~-'
fTime--> 20.00
REW251.D V006E15.M Tue May 16 13:06:57 2023
REPORT ID: 23E133 Page 99 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW252.D Vial: 6
Operator: LYamas Acq On 15 May 2023 3:31 pm
Sample V006E155 Inst 06
Misc 5ppb 8260/25ppb KET-AA/125ppb TBA Mul tiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc units Dev(Min)
10.09 114
15.54 117
19.42 152
3557639
3124358
1193635
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111 627878 5.46 ug/l 0.00
Recovery = 54.60%
9.22 65 430359 5.39 ug/l 0.00
Recovery = 53.90%
12.92 98 2234443 5.51 ug/l 0.00
Recovery = 55.10%
17.55 95 744773 5.51 ug/l 0.00
1. 70
1. 93
2.05
2.51
2.60
2.64
2.88
3.40
3.45
3.49
3.66
3.82
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.60
5.84
5.75
6.53
6.82
7.07
7.20
7.57 /
85
50
62
94
64
67
101
56
151
43
61
,-59
74
142
49
76
53
73
~96
45
43
./ 63
59
43
77
96
83
Recovery = 55.10%
796604
879650
873841
706180
511095
1158528
982617
237790
514631
382605
1062657
494012
46077
1138504
716059
2565521
440342
1029047
712459
1855853
547149
1168676
1527679
568785
642335
704825
1137254
5.60
5.58
5.70
5.59
5.52
5.50
5.39
26.52
5.22
27.53
5.42
124.05
4.79
5.30
5.14
5.48
27.28
5.35
5.29
5.28
5.04
5.33
5.26
26.73
5.43
5.30
5.30
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
96
97
100
98
99
98
97
99
98
96
99
98
91
100
100
100
96
98
100
100
99
99
98
100
99
99
99
(#) = qualifier out of range (m) = manual integration ?\n~W Page 1
REW252.D V006E15.M Tue May 16 13:07:37 2023
REPORT ID: 23E133 Page 100 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW252.D
Acq On 15 May 2023 3:31 pm
Sample V006E155
Misc 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) l,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,1,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95
8.08
8.49
8.48
8.84
9.02
9.20
9.41
9.40
10.66
10.75
11.02
11.57
11.46
11.54
12.15
12.20
12.51
13.06
13.49
13.43
13.68
13.77
14.14
14.19
14.54
14.88
15.23
15.60
15.69
130
42
97
84
110
119
73
62
78
130
83
,{~
83
93
63
43
~75
91
69
(-75
97
43
76
164
129
107
r 91
112
131
15.71/91
15.84 91 .r
16.56 91
16.63 /104
17.17 105
17.17 173
17.45 83
17.67 110
17. 77·~ 53
17.771/ 91
17.81 156
351232
56072
977399
1139498
308915
736609
1211378
525480
2604416
682258
1152076
565345
48188
753932
298845
48293
1464122
939617
2771973
470500
691724
376308
996069
685068
597664
483367
369034
1160888
1757717
594316
3250428
4893955
2431264
1844683
3101156
226869
427730
103231
101048
3934894
657815
5.16 ug/l
4.68 ug/l
5.48 ug/l
6.13 ug/l
5.26 ug/l
5.25 ug/l
5.29 ug/l
5.26 ug/l
5.40 ug/l
5.28 ug/l
5.77 ug/l
5.04 ug/l
99.31 ug/l
5.03 ug/l
5.19 ug/l
5.01 ug/l
28.53 ug/l
5.31 ug/l
5.43 ug/l
5.18 ug/l
5.23 ug/l
5.14 ug/l
27.32 ug/l
5.23 ug/l
5.34 ug/l
5.22 ug/l
5.15 ug/l
5.43 ug/l
5.36 ug/l
5.20 ug/l
5.28 ug/l
10.88 ug/l
5.30 ug/l
5.28 ug/l
5.28 ug/l
5.18 ug/l
5.43 ug/l
5.12 ug/l
4.93 ug/l
5.51 ug/l
5.33 ug/l
Qvalue
98
97
93
99
98
98
100
100
99
100
99
99
99
99
98
93
99
98
100
98
100
98
96
98
99
99
96
99
99
99
99
100
99
99
100
99
97
98
95
100
100
(#) = qualifier out of range (m) = manual integration ~
REW252.D V006E15.M Tue May 16 13,07,38 2023 ?31\/VV" Page 2 REPORT ID: 23E133 Page 101 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW252.D
Aeq On 15 May 2023 3:31 pm
Sample V006E155
Mise 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) l,3,5-Trimethylbenzene 17.98, 105 2487149 5.38 ug/l 99
82) 2-Chlorotoluene 17.99 91 2515191 5.46 ug/l 100
83) 4-Chlorotoluene 18.06 91 1914290 5.26 ug/l 99
84) tert-Butylbenzene 18.430/ f34 599863 5.41 ug/l 100
85) l,2 t 4-Trimethylbenzene 18.47 105 2394715 5.25 ug/l 100
86) see-Butylbenzene 18.68 . 105 3451091 5.37 ug/l 100
87) p-Isopropyltoluene 18.83 119 2645019 5.28 ug/l 100
88) 1t3-Diehlorobenzen~ 18.94 ,146 1246913 5.34 ug/l 99
89) 1 t 2 t 3-Trimethylbenzene 19.02 105 2200836 5.31 ug/l 99
90) l,4-Diehlorobenzene 19.06 ~146 1258042 5.38 ug/l 100
91) n-Butylbenzene 19.28' 91 2541174 5.35 ug/l 99
92) l,2-Diehlorobenzene 19.44 146 1049666 5.40 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.22 157 66500 5.29 ug/l 96
94) l,2,4-Triehlorobenzene 21.05/180 671805 5.26 ug/l 99
95) Hexaehlorobutadiene 21.18 225 439549 5.59 ug/l 99
96) Naphthalene 21.33 128 990988 5.32 ug/l 100
97) l,2,3-Triehlorobenzene 21.57/ 180 540371 5.51 ug/l 99
(#) = qualifier out of range (m) = manual integration
REW252.D V006E15.M Tue May 16 13:07:38 2023 Page 3
REPORT ID: 23E133 Page 102 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW252.D
Aeq On 15 May 2023 3:31 pm
Sample V006E155
Mise 5ppb 8260/25ppb KET-AA/125ppb TBA
Vial: 6
Operator: LYamas
Inst 06
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
V\bundance
[ ;;.J'IU'UVV'Vl
!
i
! 5200000
5000000
i 4600000
4400000
4200000
4000000
3800000
3600000
3200000
3000000
2600000
2400000
2200000
2000000
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW252.D
REW252.D V006E15.M Tue May 16 13:07:41 2023 Page 4
REPORT ID: 23E133 Page 103 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW253.D Vial: 7
Operator: LYamas Acq On 15 May 2023 3:57 pm
Sample V006E156 Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Cone Units Dev(Min)
10.08
15.54
19.42
114 4201521
117 3710147
152 1432830
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111 1305027 9.62 ug/l 0.00
Recovery = 96.20%
9.22 65 915332 9.70 ug/l 0.00
Recovery = 97.00%
12.91 98 4706069 9.77 ug/l 0.00
Recovery = 97.70%
17.55 95 1565323 9.65 ug/l 0.00
1. 69
1. 93
2.05
2.50 <"
2.60 -
2.64
2.88
3.40
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.60
5.84
5.75
6.53
6.82
7.07
7.20
7.57
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
/96
45
43
r 63
59
43
77
96 < 83
Recovery = 96.50%
1637617
1893638
1837298
1509839
1095198
2252461
2093398
454999
1010215
666083
2114930
1062191
94827
2277481
1429985
5329386
868979
2128776
1439653
3744955
1237880
2315425
3082964
1087224
1313299
1422036
2252579
9.75
10.17
10.14
10.13
10.02
9.06
9.72
42.96
8.67
41.86
9.13
225.85
8.35
8.97
8.69
9.64
45.59
9.38
9.04
9.03
9.65
8.94
8.98
43.27
9.40
9.05
8.89
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
(#) = qualifier out of range (m) = manual integration
REW253.D V006E15.M Tue May 16 13: 08: 16 2023 7t) [1[1\,3 Page 1
REPORT ID: 23E133 Page 104 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW253.D
Acq On 15 May 2023 3:57 pm
Sample V006E156
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 7
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1 ,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,1,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.95 130
8.08" 42
8.49 ./ 97
8.48 ~ 84
8.85 110
9.02 119
9.20 73
9.41 / 62
9.40,78
10.67 130
10.75 \ 83
11.02 «63
11.58 88
11. 46 <~ 83
11.54 93
12.15 63
12.20 43
12.51 " 75
13.04 91
13.49 69
13.43 75
13.69 97
13.77 43
14.13 76
14.19 164
14.54 129
14.87 107
15.23 <91
15.60 112
15.69 131
15.71 .91
15.84 . 91
16.56 ..-91
16.63 104
17.17 ,105
17.17 / 173
17.45 83
17.67 110
17.77 53
17.77~ 91
17.81 156
717797
119640
1783219
1973667
623075
1444891
2461779
1073573
5159975
1378480
2080780
1178744
94023
1543161
615764
106234
2784136
1916555
5505571
973573
1428058
753664
1852964
1419194
1209020
989254
767432
2341526
3556694
1205259
6503421
9801704
4856684
3730318
6172080
467221
854710
216138
215277
7793304
1317692
8.94 ug/l
8.46 ug/l
8.47 ug/l
8.99 ug/l
8.98 ug/l
8.73 ug/l
9.09 ug/l
9.11 ug/l
9.06 ug/l
9.04 ug/l
8.83 ug/l
8.90 ug/l
164.07 ug/l
8.72 ug/l
9.05 ug/l
9.33 ug/l
45.93 ug/l
9.18 ug/l
9.09 ug/l
9.02 ug/l
9.10 ug/l
8.67 ug/l
42.80 ug/l
9.13 ug/l
9.11 ug/l
9.00 ug/l
9.03 ug/l
9.22 ug/l
9.13 ug/l
8.89 ug/l
8.89 ug/l
18.35 ug/l
8.91 ug/l
9.00 ug/l
8.84 ug/l
8.88 ug/l
9.04 ug/l
8.92 ug/l
8.75 ug/l
9.09 ug/l
8.89 ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
(#) = qualifier out of range (m) = manual integration ~
REW253.D VD06E15.M TUe May 16 13:08:16 2023 :!J ~~1rfl.,b page 2
REPORT ID: 23E133 Page 105 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW253.D
Aeq On 15 May 2023 3:57 pm
Sample V006E156
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 7
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:07 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
81 ) l,3,5-Trimethylbenzene 17.98 105 4918141 8.86 ug/l
82) 2-Chlorotoluene 17.99 r 91 5027165 9.10 ug/l
83) 4-Chlorotoluene 18.06 -91 3879282 8.88 ug/l
84) tert-Butylbenzene 18.43 134 1183975 8.89 ug/l
85) l,2,4-Trimethylbenzene 18.47 ,105 4798479 8.76 ug/l
86) see-Butylbenzene 18.68 -105 6881508 8.93 ug/l
87) p-Isopropyltoluene 18.83 119 5369847 8.92 ug/l
88) l,3-Diehlorobenzene 18.94 146 2533563 9.04 ug/l
/ 89 ) l,2,3-Trimethylbenzene 19.02 105 4412429 8.87 ug/l
90) l,4-Diehlorobenzene 19.05 146 2552753 9.09 ug/l
-' 91) n-Butylbenzene 19.28 91 5062110 8.88 ug/l
92) l,2-Diehlorobenzene 19.44 146 2117371 9.07 ug/l
93) l,2-Dibromo-3-ehloropropan 20.22 /157 129657 8.59 ug/l
94) 1, 2, 4-Trichlorobenzene 21.05 180 1358872 8.87 ug/l
95) Hexaehlorobutadiene 21.18 /225 866034 9.18 ug/l
96) Naphthalene 21. 33 I 128 2030259 9.07 ug/l
97) 1, 2, 3-Trichlorobenzene 21.57 180 1069362 9.08 ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
REPORT ID: 23E133 Page 106 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW253.D
Aeq On 15 May 2023 3:57 pm
Sample V006E156
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 16 13:07 2023
TBA
Vial: 7
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Initial Calibration
~bundance TIC: REW253.D
]
: 1.05e+07
I
1e+07
9500000
9000000
8500000
80000001
75000001
'Iii:
7000000 1
6500000
6000000
5500000
5000000
4500000
4000000
3500000
3000000j
2500000
2000000
i
[ime-->
o iii '¥ I iii iii iii Iii iii i i
2.00 4.00 6.00 8.00
ilJ
iii iii iii i i i I i i
10.00 12.00 14.00
REW253.D V006E15.M Tue May 16 13:08:19 2023
i
::iii
f-:'
cD c Q)
>.
,
;::;
~
I ~
i
'7
::iii t-:
CD c:
Q)
::iii r:
I
I
'--'-.J
i I i i i
16.00
:;
f-:'
0; c
!
~
Q)
" ::;;;!'::iii ~.r: r: 0; c
~
I 0:
II ~ .= "-~ ~ " i
!is
1 l ''-....
i I i i i i I i i i i I
18.00 20.00
REPORT ID: 23E133 Page 107 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Acq On 15 May 2023 4:23 pm
Sample V006E157
Misc 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09
15.54
19.42
8.10
9.22
12.92
17.55
1. 69
1. 93
2.03
2.50
2.60
2.64
2.88
3.40
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.60
5.84
5.75
6.53
6.82
7.07
7.20
7.58
114 3805963
117 3335114
152 1311803
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
111
65
98
95
85
50
62
94
64
67
101
56
151
43
.~ 61
59
74
142
49
76
53
73
, 96
45
43
"" 63
59
43
77
/ 96
83
2512790 20.44
Recovery =
1738666 20.34
Recovery =
8724991 20.15
Recovery =
2958120 19.92
Recovery =
ug/l
204.40%
ug/l
203.40%
ug/l
201. 50%
ug/l
199.20%
0.00
0.00
0.00
0.00
2921912
3396093
3132768
2709922
1982072
4585668
3678797
19.20 ug/l
20.14 ug/l
19.10 ug/l
20.06 ug/l
20.02 ug/l
20.36 ug/l
18.85 ug/l
Qvalue
98
99
99
997420
2035596
1428238
4268621
2231395
189654
4590105
2880790
9982938
1890831
4347038
2882493
7614910
2341893
4696843
6337537
2414970
2500134
2882047
4553063
103.97 ug/l
19.28 ug/l
102.76 ug/l
20.34 ug/l
523.76 ug/l
18.45 ug/l
19.96 ug/l
19.33 ug/l
19.94 ug/l
109.51 ug/l
21.14 ug/l
19.99 ug/l
20.26 ug/l
20.15 ug/l
20.02 ug/l
20.38 ug/l
106.10 ug/l
19.76 ug/l
20.24 ug/l
19.83 ug/l
100
99
99
99
99
99
99
100
100
94
100
99
100
100
99
100
100
98
100
99
99
98
99
100
(#) = qualifier out of range (m) = manual integration ~
REW254 . D V006E15. M Tue May 16 13,09,41 2023 .-? j'}I1 (1';' Page 1
REPORT ID: 23E133 Page 108 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Acq On 15 May 2023 4:23 pm
Sample V006E157
Misc 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
32)
33)
35)
36)
38)
39)
40)
42)
43)
44)
45)
46)
47)
48)
49)
50)
51)
52)
55)
56)
57)
58)
59)
60)
61 )
62)
64)
65)
66)
67)
68)
69)
70)
71)
72)
74)
75)
77)
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
1, 1, 1-Trichloroethane
Cyclohexane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1,1,1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
1 ,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.95 130
8.08 42
8.49 97
8.48 84
8.84 110
9.02 119
9.19 73
9.41 .... 62
9.40 '78
10.66 130
10.75 ·83
11.02 r 63
11. 57 88
11.46 ~ 83
11.54 93
12. 15 ~ 63
12.20 43
12.51,75
13.06 91
13.49 69
13.43./75
13.69 97
13.76 43
14.14 76
14.19 164
14.54 129
14.88 107
15.23 r 91
15.60 112
15.69 131
15.71 .-91
15.84 . 91
16.56 '" 91
16.63 104
17.17' 105
17.17' 173
17.45 83
17.67 110
17.77 <' 53
17.77 J 91
17.81 156
1475341
250681
3524529
3763298
1267735
2927444
5052902
2182458
10376562
2763783
3944545
2397108
201018
3122921
1266634
203434
6052783
3910725
11116636
2052777
2975981
1557067
4205982
2883225
2403571
2033554
1604682
4668396
7105690
2464349
13161388
19160742
9770567
7629916
12396822
1022322
1816745
451376
463887
15431615
2727836
20.28 ug/l
19.58 ug/l
18.47 ug/l
18.92 ug/l
20.17 ug/l
19.52 ug/l
20.61 ug/l
20.43 ug/l
20.12 ug/l
20.00 ug/l
18.48 ug/l
19.98 ug/l
387.24 ug/l
19.47 ug/l
20.55 ug/l
19.73 ug/l
110.24 ug/l
20.67 ug/l
20.42 ug/l
21.17 ug/l
21.09 ug/l
19.94 ug/l
108.08 ug/l
20.64 ug/l
20.14 ug/l
20.58 ug/l
21. 00 ug/l
20.44 ug/l
20.29 ug/l
20.22 ug/l
20.02 ug/l
39.91 ug/l
19.94 ug/l
20.48 ug/l
19.76 ug/l
21.22 ug/l
20.99 ug/l
20.36 ug/l
20.60 ug/l
19.65 ug/l
20.11 ug/l
Qvalue
99
98
95
98
99
98
99
100
100
99
98
99
99
99
99
95
100
99
99
98
100
100
99
98
100
98
99
100
100
99
99
97
99
100
100
99
98
98
98
99
99
(#) = qualifier out of range (m) = manual integration~V\ .~
REW254.D V006E15.M Tue May 1613:09:422023 t5]\1{fl.; Page 2
REPORT ID: 23E133 Page 109 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Aeq On 15 May 2023 4:23 pm
Sample V006E157
Mise 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title METHOD 8260
Last Update Tue May 16 12:41:48 2023
Response via Initial Calibration
DataAeq Meth V006E15
Compound R.T. QIon Response Cone Unit Qvalue
-------------------------------------------------------------------------
81 ) 1,3,5-Trimethylbenzene 17.98,.......-105 9968910 19.63 ug/l 99
82) 2-Chlorotoluene 17.99 , 91 10215393 20.19 ug/l 99
83) 4-Chlorotoluene 18.06 <,91 7798700 19.50 ug/l 99
84) tert-Butylbenzene 18.43 134 2391915 19.62 ug/l 100
85) 1,2,4-Trimethylbenzene 18.47 105 9805084 19.55 ug/l 100
86) see-Butylbenzene 18.68 j .. 05 13766972 19.50 ug/l 99
87) p-Isopropyltoluene 18.83 119 10821876 19.64 ug/l 100
88) 1,3-Dichlorobenzene 18.94 J.46 5113416 19.94 ug/l 99
89) 1,2,3-Trimethylbenzene 19.02 105 8888768 19.52 ug/l 99
90) 1,4-Dichlorobenzene 19.06 <).46 5201666 20.23 ug/l 99
91 ) n-Butylbenzene 19.28 91 10313816 19.76 ug/l 99
92) 1,2-Dichlorobenzene 19.44 ./146 4335220 20.27 ug/l 100
93) 1,2-Dibromo-3-chloropropan 20.22 157 284745 20.60 ug/l 97
94) 1, 2, 4-Trichlorobenzene 21.05 /180 2832572 20.19 ug/l 99
95) Hexaehlorobutadiene 21.18 225 1738172 20.13 ug/l 99
96) Naphthalene 21.33 128 4372122 21.34 ug/l 100
97) 1,2,3-Trichlorobenzene 21.57 180 2246376 20.83 ug/l 99
./
(#) = qualifier out of range (m) = manual integration ~ ~ ~
REW254.D V006E15.M Tue May 16 13:09:42 2023 / ~1\1~ Page 3
REPORT ID: 23E133 Page 110 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW254.D
Aeq On 15 May 2023 4:23 pm
Sample V006E157
Mise 20ppb 8260/100ppb KET-AA/500ppb TBA
Vial: 8
Operator: LYamas
06 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
! I , 2.2e+071
j
2.1e+07j
2e+07
1.ge+07 1
1.8e+07
1.7e+07 j
1.6e+07
1.5e+07
1.4e+07
1.3e+07
1.2e+07
1.1e+07 I
1e+07
9000000
8000000
7000000
I 6000000
5000000
4000000
3000000
2000000
2.00
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW254.D
::;; ..: .,; c: .,
l
oil
::;:
1--
l
I
::;;
1-: .,
c:
.!E ~
~ m
::;; ..: .,-
c:
ill
:;j
I-
::;:
$~ ~ tU 1& Iil~ 1l c: _
z:.
I ::>
~ c:
;;.
..c:
~ 1D
E ~J .'" ~
~
::;; ..: .,;
'" ~ -~
0 , :E
0
9 N_
en ~-.,;
ru
'" 1l e
0 ::>
'8
E
:&
hl-~ .,;
~ ~,
::i: ..: .,; c
[ e c. e
0
:E ~
0
E
.§
~.
JW t ~'-.A. l , , , , I , , , , I i i , , I , , i i I , i , i I i
4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00
::;:
..: g
l::;;
.95 1--
II ~ld ., ~
1&;~
:Ti-]~
"'I-"" .,01
':(ijc,r
~...:
~
'--
i i i I
REW254.D V006E15.M Tue May 16 13:09:45 2023 ~ V f ''J Page 4 , \trl ,'lI REPORT ID: 23E133 Page 111 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Acq On 15 May 2023 4:49 pm
Sample V006E158
Misc 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Cone Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) 1,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) 1,1,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09
15.54
19.42
8.10
9.22
12.92
17.55
1. 69
1. 93
2.03
2.50
2.60
2.64
2.88
3.38
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.61
5.84
5.75
6.53
6.82
7.07
7.20
7.58
114 3921302
117 3465018
152 1341861
10.00 ug/l
10.00 ug/l
10.00 ug/l
111 3634116 28.70
Recovery =
65 2564386 29.12
Recovery =
98 12878257 28.62
Recovery =
95 4244847 27.95
Recovery =
ug/l
287.00%
ug/l
291. 20%
ug/l
286.20%
ug/l
279.50%
0.00
0.00
0.00
0.00
0.00
0.00
0.00
85
50
62
94
64
67
4891634
5557372
5007371
4404636
3210647
7215715
6228298
1502567
3276445
2113275
6858996
3457939
31.20 ug/l
31.99 ug/l
29.62 ug/l
31.65 ug/l
31. 48 ug/l
31.09 ug/l
30.97 ug/l
Qvalue
98
99
99
101
56
151
43
(,61
59
74
142
49
76
53
73
96
45
43
/ 63
59
43
77
j 96
83
305143
7257916
4500683
15184788
2867160
6818622
4600854
11963153
3690369
7437328
9825947
3614309
3949709
4550514
7175664
152.02 ug/l
30.13 ug/l
148.75 ug/l
31.73 ug/l
787.78 ug/l
28.80 ug/l
30.63 ug/l
29.31 ug/l
29.44 ug/l
161.17 ug/l
32.19 ug/l
30.97 ug/l
30.89 ug/l
30.81 ug/l
30.76 ug/l
30.67 ug/l
154.12 ug/l
30.29 ug/l
31. 02 ug/l
30.34 ug/l
100
99
99
99
99
99
100
100
98
98
100
99
99
99
100
100
99
98
99
97
100
98
99
99
(#) = qualifier out of range (m) = manual integration
REW255.D V006E15.M Tue May 16 13:10:29 2023
REPORT ID: 23E133 Page 112 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Acq On 15 May 2023 4:49 pm
Sample V006E158
Misc 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P .
Vial: 9
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32)
33)
35)
36)
38)
39)
40)
42)
43)
44)
45)
46)
47)
48)
49)
50)
51 )
52 )
55)
56)
57)
58)
59)
60)
61 )
62)
64)
65)
66)
67)
68)
69)
70)
71 )
72)
74)
75)
77)
78)
79)
80)
Bromochloromethane
Tetrahydrofuran
1,1,1-Trichloroethane
Cyclohexane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
1,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1,1,2,2-Tetrachloroethane
1,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.95
8.06
8.49
8.48
8.84
9.01
9.19
9.41
9.40
10.66
10.75
11.02
11.57
11.46
11.54
12.15
12.20
12.51
13.06
13.49
13.43
13.68
13.76
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.67
17.77,
17.77/
17.81
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
,--75
91
69
-r 75
97
43
76
164
129
107
91
1'12
131
91
r 91
./
(' 91
104
-l05
( 173
83
110
53
91
156
2310038
394090
6283300
6455052
2022903
4763085
7867379
3415413
16219166
4406334
6608062
3818779
318386
4919745
2003246
331940
9101129
6089701
17592168
3187653
4588683
2442488
6168161
4454405
3828935
3158179
2480976
7435969
11153144
3847809
19761702
25013531
15220079
11835660
18786463
1566079
2731255
698230
707821
19892507
4229917
30.81
29.87
31.97
31. 49
31. 23
30.83
31.14
31.04
30.52
30.95
30.05
30.89
595.29
29.78
31. 55
31.24
160.89
31.24
31.10
31. 64
31.29
30.10
152.56
30.69
30.88
30.76
31. 25
31. 34
30.65
30.38
28.93
50.15
29.90
30.57
28.82
31.78
30.85
30.78
30.73
24.77
30.49
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
99
96
95
98
100
97
99
99
99
99
98
99
97
99
99
100
100
100
100
99
99
99
99
98
100
98
99
99
100
100
96
82
99
100
98
99
99
96
100
90
99
(#) = qualifier out of range (m) = manual integration
REW255.D V006E15.M Tue May 16 13:10:30 2023 3., lA.... Page 2
j1n(fi~ REPORT ID: 23E133 Page 113 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Aeq On 15 May 2023 4:49 pm
Sample V006E158
Mise 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Vial: 9
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81) 1,3,5-Trimethylbenzene 17.98 /105 14922785 28.72 ug/l 98
82) 2-Chlorotoluene 17.99 91 15459982 29.88 ug/l 98
83) 4-Chlorotoluene 18.06 91 12209255 29.85 ug/l 98
84) tert-Butylbenzene 18.43 134 3736809 29.97 ug/l 99
85) 1,2,4-Trimethylbenzene 18.47 ,.-105 14519987 28.30 ug/l 96
86) see-Butylbenzene 18.68 -1..05 18106820 25.08 ug/l 91
87) p-Isopropyltoluene 18.83 119 15422290 27.36 ug/l 95
88) 1,3-Diehlorobenzene 18.94 ( 146 7982969 30.43 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.02 ~105 13383406 28.73 ug/l 98
90) 1,4-Diehlorobenzene 19.06 146 8051976 30.61 ug/l 99
91) n-Butylbenzene 19.28< 91 14814754 27.75 ug/l 94
92) 1,2-Diehlorobenzene 19.44 ....-146 6707148 30.67 ug/l 100
93) 1,2-Dibromo-3-ehloropropan 20.22 157 428089 30.27 ug/l 99
94) 1,2,4-Triehlorobenzene 21.05 180 4159006 28.98 ug/l 99
95) Hexaehlorobutadiene 21.18 225 2553506 28.90 ug/l 100
96) Naphthalene 21. 33 128 6492779 30.98 ug/l 98
97) 1,2,3-Triehlorobenzene 21.57' 180 3266204 29.61 ug/l 100
J 11\ :3; ------------------------------------------------------------~-l-t1 ~ ~ ------
(#) = qualifier out of range (m) = manual integration
REW255.D V006E15.M Tue May 16 13:10:30 2023 Page 3
REPORT ID: 23E133 Page 114 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW255.D
Aeq On 15 May 2023 4:49 pm
Sample V006E158
Mise 30ppb 8260/150ppb KET-AA/750ppb TBA
Vial:
Operator:
Inst
Multiplr:
9
LYamas
06
1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:09 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
: 1
, 32e+071
I
3e+071
1
2.8e+07
I
2.6e+071
I
2.4e+071
I
2.2e+071
i
2e+07j
I
1.8e+071
1.6e+071
I
1.4e+071
!
I
I
12e+071
10+071
I
80000001
6000000
40000001
I
!
20000001
I
I
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW255.D
a.
'"
OLT'-'-...,--'~~~:""'~I -,,":"';-~'r, -'I~~,c'-r'=, '.1-'4-, ';-,-';=i-''T''-.,''.::;~=?-'A'-Cr'-'i'-¥I ¥=?'=l.~, --;1=01., -';,c=i;, :!"~I ::;'~i ~~, ~I='-"r, =;,r'-;, ~'~I
Time--> 4.00 6.00 8.00 12.00 14.00 16.00 18.00 20.00
REW255.D V006E15.M Tue May 16 13:10:33 2023
REPORT ID: 23E133 Page 115 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW256.D Vial: 10
Operator: LYamas Acq On 15 May 2023 5:15 pm
Sample V006E159 Inst 06
Misc 50ppb 8260/250ppb KET-AA/1250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.09 114
15.54 117
19.42 152
4263582
3777879
1535124
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10
9.22
12.92
17.55
1. 69
1. 93
2.03
2.50
2.60
2.64
2.88
3.38
3.45
3.49
3.66
3.80
4.18
4.12
4.39
4.37
4.64
4.68
4.89
5.61
5.84
5.75
6.53
6.82
7.07
7.20
7.58
111 6545706 47.54 ug/l
475.40%
ug/l
482.10%
ug/l
453.10%
ug/l
450.60%
0.00
Recovery =
65 4616405 48.21
Recovery =
98 22230538 45.31
Recovery =
95 7830293 45.06
85
50
62
94
64
67
101
56
151
43
61
r 59
74
142
49
76
53
73
/ 96
45
43
/63
59
43
77
96
83
Recovery =
7733964
8922030
7627846
7062744
5155646
11900765
9887642
2562915
5251202
3510834
11224678
5951536
541252
11818617
7349390
24921334
4845338
11383845
7547333
19723543
6307546
12274712
16381044
6167866
6140601
7464245
11846328
45.36 ug/l
47.24 ug/l
41.50 ug/l
46.68 ug/l
46.49 ug/l
47.16 ug/l
45.22 ug/l
238.49 ug/l
44.41 ug/l
228.71 ug/l
47.75 ug/l
1247.02 ug/l
46.99 ug/l
45.87 ug/l
44.02 ug/l
44.45 ug/l
250.50 ug/l
49.42 ug/l
46.73 ug/l
46.85 ug/l
48.44 ug/l
46.70 ug/l
47.03 ug/l
241.89 ug/l
43.31 ug/l
46.80 ug/l
46.06 ug/l
0.00
0.00
0.00
Qvalue
98
99
99
99
99
99
98
100
100
98
100
98
100
99
99
99
100
99
100
99
98
99
98
99
98
100
99
(#) = qualifier out of range (m) = manual integration c!-, v---
REW256.D V006E15.M Tue May 16 13,11,29 2023 ~1\ .. "3 Page 1
REPORT ID: 23E133 Page 116 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW256.D
Acq On 15 May 2023 5:15 pm
Sample V006E159
Misc 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Vial: 10
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Conc Unit
32)
33)
35)
36)
38)
39 )
40 )
42 )
43)
44)
45 )
46 )
47)
48 )
49 )
50)
51 }
52)
55}
56}
57}
58)
59 }
60)
61)
62}
64}
65}
66)
67}
68)
69)
70)
71)
72)
74)
75)
77)
78)
80)
81 )
Bromochloromethane
Tetrahydrofuran
l,l,l-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
l,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2, 2-Tetrachloroethane
l,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
Bromobenzene
l,3,5-Trimethylbenzene
7.95
8.08
8.49
8.48
8.84
9.02
9.19
9.41
9.40
10.66
10.75
11.02
11. 57
11. 46
11.54
12.15
12.20
12.51
13.06
13.49
13.43
13.69
13.76
14.14
14.19
14.54
14.88
15.23
15.60
15.69
15.71
15.84
16.56
16.63
17.17
17.17
17.45
17.67
17.77
17.81
17.98
130
42
97
84
110
119
73
",62
r 78
130
, 83
" 63
88
83
93
<' 63
43
75
<'"91
.( 69
< 75
97
43
76
164
129
107
<" 91
112
131
91
<" ,/ 91
'" 91
1'04
105
<' .... 173
83
110
/ 53
156
• 105
3859644
684090
10183653
11210701
3313953
7708860
13165338
5690365
26628035
7228001
11475475
6211205
541704
8232455
3302777
569290
15478142
10218511
25317320
5443221
7777128
4105137
10599260
7416716
6302927
5285497
4128272
12325846
18269286
6537120
257?0219
30116380
22658539
19434222
24830260
2702109
4720460
1188632
1261746
7250408
20220424
47.35 ug/l
47.69 ug/l
47.65 ug/l
50.30 ug/l
47.06 ug/l
45.89 ug/l
47.93 ug/l
47.56 ug/l
46.09 ug/l
46.69 ug/l
47.99 ug/l
46.21 ug/l
931. 53 ug/l
45.82 ug/l
47.84 ug/l
49.28 ug/l
251.65 ug/l
48.22 ug/l
41.05 ug/l
49.55 ug/l
48.65 ug/l
46.40 ug/l
240.44 ug/l
46.87 ug/l
46.62 ug/l
47.22 ug/l
47.69 ug/l
47.64 ug/l
46.05 ug/l
47.35 ug/l
34.59 ug/l
55.38 ug/l
40.83 ug/l
46.04 ug/l
34.93 ug/l
47.94 ug/l
46.60 ug/l
45.81 ug/l
47.88 ug/l
45.68 ug/l
34.02 ug/l
Qvalue
99
96
93
98
100
99
98
98
99
98
98
99
100
99
99
98
100
99
89
98
98
99
98
97
100
97
99
99
99
100
80
62
90
97
87
99
98
98
99
99
82
REPORT ID: 23E133 Page 117 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW256.D
Aeq On 15 May 2023 5:15 pm
Sample V006E159
Mise 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Vial: 10
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
82) 2-Chlorotoluene 17.99 91 21740358 36.72 ug/l
83) 4-Chlorotoluene 18.06 ' 91 16944542 36.21 ug/l
84) tert-Butylbenzene 18.43 134 6164808 43.21 ug/l
85) l,2,4-Trimethylbenzene 18.47 105 19279917 32.84 ug/l <
86) see-Butylbenzene 18.68 -105 21586862 26.13 ug/l
87) p-Isopropyltoluene 18.83 119 19749938 30.63 ug/l
88) l,3-Diehlorobenzene 18.94 ""146 13161002 43.85 ug/l
89) l,2,3-Trimethylbenzene 19.02 /105 18258743 34.26 ug/l
90) 1,4-Diehlorobenzene 19.06 ,146 13423176 44.61 ug/l
91) n-Butylbenzene 19.28 91 18739437 30.68 ug/l
92) l,2-Diehlorobenzene 19.45 /146 11245927 44.94 ug/l
93) 1,2-Dibromo-3-ehloropropan 20.22 157 754989 46.67 ug/l
94) l,2,4-Triehlorobenzene 21. 05 180 7119063 43.36 ug/l
95) Hexaehlorobutadiene 21.18 225 4177934 41.34 ug/l
96) Naphthalene 21. 33 128 11176192 46.61 ug/l
97) 1, 2, 3-Triehlorobenzene 21. 57 ' 180 5601044 44.39 ug/l
Qvalue
87
84
99
76
71
79
98
83
97
76
100
98
99
100
99
99
____________________________________________________________ ~~~~1J~~
(#) = qualifier out of range (m) = manual integration
REW256.D V006E15.M Tue May 16 13:11:30 2023 Page 3
REPORT ID: 23E133 Page 118 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW256.D
Aeq On 15 May 2023 5:15 pm
Sample V006E159
Vial: 10
Operator: LYamas
Inst 06
Mise 50ppb 8260/250ppb KET-AA/1250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 13:11 2023 Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Initial Calibration
y\bundance TIC: REW256.D
i
I 5e+07'
i
4.6e+07'
I
4.4e+07: ,
I 4.2e+07
i
4e+07,
I
I 3.6e+07'
3.4e+07
2.8e+07
,
2.6e+071
i
2.46+07 1
2.2e+07 1
2e+07
1
1.8e+07 1
1.6e+07
1.4e+07
1.2e+07
1e+07
8000000
6000000
4000000
2000000
0
rfime-->
;,;;
f--
::;: r-:
REW256.D V006E15.M
::;: r-:
;,;;
f--
of
~ Q) , '" . e
.Q y
Page 4
REPORT ID: 23E133 Page 119 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E15\REW257.D Vial: 11
Operator: Acq On 15 May 2023 5:41 pm
Sample V006E1510
LYamas
06
Misc 100ppb 8260/500ppb KET-AA/2500ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) 1,1-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1,1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. Qlon Response Conc Units Dev(Min)
10.08
15.54
19.42
114 3587043
117 3209065
152 1275389
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8.10 111 13378109 115.48 ug/l 0.00
Recovery = 1154.80%
9.22 65 9453558 117.34 ug/l 0.00
Recovery = 1173.40%
12.91 98 31763488 76.22 ug/l 0.00
Recovery = 762.20%
17.55 95 15843554 109.74 ug/l 0.00
1. 69
1. 93
2.01
2.50
2.58
2.62
2.88
3.38
3.45
3.49
3.66
3.82
4.18
4.12
4.43
4.37
4.64
4.68
4.89
5.60
5.83
5.75
6.53
6.82
7.07
7.18
7.57
85
50
62
94
64
67
101
56
151
43
" 61
59
74
142
49
76
53
73
.,..96
45
43
/ 63
59
43
77
j 96
83
Recovery = 1097.40%
15852376
18349244
15070553
14232063
10419491
23260568
20235886
4729127
10662452
6686156
22634545
11761351
1083296
23646572
14750185
51162848
9397943
22345119
15130990
38821959
12421220
24388561
32287682
11785652
10887030
14996745
23685553
110.52 ug/l
115.47 ug/l
97.47 ug/l
111. 80 ug/l
111. 69 ug/l
109.57 ug/l
110.00 ug/l
523.06 ug/l
107.17 ug/l
521.12 ug/l
114.45 ug/l
2929.13 ug/l
111.79 ug/l
109.09 ug/l
105.01 ug/l
108.45 ug/l
577.50 ug/l
115.30 ug/l
111. 35 ug/l
109.60 ug/l
113.38 ug/l
110.28 ug/l
110.18 ug/l
549.39 ug/l
91. 28 ug/l
111. 76 ug/l
109.47 ug/l
Qvalue
98
99
100
100
100
98
99
98
99
99
100
98
88
99
100
97
100
100
100
98
98
99
97
99
97
100
99
(#) = qualifier out of range (m) = manual integration 3,lA-( 1:1 Page 1 ~ (1'V~ REW257.D V006E15.M Tue May 16 13:12:39 2023
REPORT ID: 23E133 Page 120 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW257.D
Acq On 15 May 2023 5:41 pm
Sample V006E1510
Misc 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32)
33)
35)
36 )
38)
39)
40 )
42)
43)
44)
45)
46)
47)
48)
49 )
50)
51 )
52)
55)
56)
57)
58)
59)
60)
61)
62)
64)
65)
66)
67)
70)
71)
72)
74)
75)
77)
78)
80)
81)
82)
83)
Bromochloromethane
Tetrahydrofuran
1, 1, I-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
l,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-l,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-l,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
l-Chlorohexane
Chlorobenzene
l,l,l,2-Tetrachloroethane
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1, 1, 2,2-Tetrachloroethane
1, 2, 3-Trichloropropane
trans-l,4-Dichloro-2-buten
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
7.95 130
8.08 42
8.49 97
8.48 84
8.84 110
9.02 119
9.20 73
9.41 62
9.40 78
10.67 130
10.75 83
11.02 63
11. 56 88
11.46 83
11. 54 93
12.15 63
12.20 43
12.51 ,",75
13.04 91
13.49 69
13.43 ./ 75
13.69 97
13.77 43
14.13 76
14.19 164
14.54 129
14.87 107
15.23 91
15.60 112
15.69 131
16.56 , 91
16.64 104
17.17 I 105
17.17 .,.1173
17.46 83
17.67 110
17.77 53
17.81 156
17.98 / 105
17.99 91
18.22 91
7634153
1324328
20413861
23518150
6653730
15628519
25893131
11365083
40300728
14506722
24020327
12382542
1157460
16470371
6591393
1145481
26984608
19845427
33180219
10783432
15448853
8164134
19657270
14803633
12870055
10589428
8198474
21928281
26918289
13164312
30228683
27988312
31869976
5413530
9181142
2341835
2443783
14628874
25384132
26915833
60232
111.32 ug/l
109.73 ug/l
113.53 ug/l
125.43 ug/l
112.31 ug/l
110.57 ug/l
112.04 ug/l
112.91 ug/l
82.91 ug/l
111.38 ug/l
119.41 ug/l
109.50 ug/l
2365.79 ug/l
108.97 ug/l
113.49 ug/l
117.85 ug/l
521. 47 ug/l
111.30 ug/l
63.33 ug/l
115.57 ug/l
113.76 ug/l
108.63 ug/l
524.96 ug/l
110.14 ug/l
112.06 ug/l
111.37 ug/l
111.50 ug/l
99.78 ug/l
79.87 ug/l
112.24 ug/l
64.12 ug/l
78.06 ug/l
52.78 ug/l
115.59 ug/l
109.10 ug/l
108.63 ug/l
111.62 ug/l
110.93 ug/l
51. 40 ug/l
54.72 ug/l
0.15 ug/l
Qvalue
100
93
99
97
100
98
98
99
85
99
98
99
98
99
99
96
94
98
71
99
99
99
94
97
99
97
99
91
77
100
60
68
56
99
99
98
98
99
60
48
87
(#) = qualifier out of range (m) = manual integration ~VL
REW257.D V006E15.M Tue May 16 13:12:40 2023 ./bj(1rP Page 2
REPORT ID: 23E133 Page 121 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E15\REW257.D
Aeq On 15 May 2023 5:41 pm
Sample V006E1510
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial: 11
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
84) tert-Butylbenzene 18.43 ~134 12616522 106.44 ug/l
85) 1,2,4-Trimethylbenzene 18.30 105 319789 0.66 ug/l
86) see-Butylbenzene 18.47 ~105 23894510 34.82 ug/l
88) 1,3-Diehlorobenzene 18.94 '146 19689309 78.97 ug/l
89) 1,2,3-Trimethylbenzene 19.02 , 105 23282917 52.59 ug/l
90) 1,4-Diehlorobenzene 19.07 , .. 146 19778680 79.12 ug/l
92) 1,2-Diehlorobenzene 19.46,146 18117521 87.15 ug/l
93) 1,2-Dibromo-3-ehloropropan 20.22 157 1508957 112.27 ug/l
94) 1,2,4-Triehlorobenzene 21.05 180 13807083 101.23 ug/l
95) Hexaehlorobutadiene 21.18" 225 8140789 96.95 ug/l
96 ) Naphthalene 21.33.....---128 20074354 100.77 ug/l
97) 1,2,3-Triehlorobenzene 21. 57 180 10713848 102.20 ug/l
Qvalue
93
61
38
77
58
76
82
98
99
99
96
99
(#) = qualifier out of range (m) = manual integration
REW257.D V006E15.M Tue May 1613,12,402023 --1)n('J2, Page 3
REPORT ID: 23E133 Page 122 of 345
Quanti~ation Report
Data File D:\HPCHEM\1\DATA\23E15\REW257.D
Aeq On 15 May 2023 5:41 pm
Sample V006E1510
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
Vial:
Operator:
Inst
Multiplr:
11
LYamas
06
1. 00
MS Integration Params: RTE.P
Quant Time: May 16 13:12 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
f.bundance
I
8.5e+07
8e+07
7.5e+07j
7e+07j
6.5e+071
6e+07
5.5e+071
5e+07
4.5e+071
j
4e+071
3~+~i
3e+071
I
I
2.5e+071
2e+07
1.5e+07
1e+07
5000000
rrime-->
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW257.D
8.00 10.00 12.00
l
J b
14.00
~
I--"
oi c::
~ .0 ~ e B .c::
~ a I--" .... I J;
I c::
~
CI)
oi c::
III c:
.2l e
REW257.D V006E15.M Tue May 16 13:12:43 2023
REPORT ID: 23E133 Page 123 of 345
SECOND SOURCE
VERIFICATION
REPORT ID: 23E133 Page 124 of 345
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratori es. Inc.
Lab Code : EMAX
Lab File ID: REW261
Instrument ID: 06
Project : ICAL
SDG No : ICAL
BFB Injection Date: 05/16/23
BFB Injection Time: 11:11
1 1 % RELATIVE 1
1 mle 1 ION ABUNDANCE CRITERIA ABUNDANCE 1
1 1 1
1 50 1 15 -40% of mass 95 16.428 1
1 75 1 30 . 60% of mass 95 1 42.584 1
1 95 1 Base Peak. 100% relative abundance __ 1 100.000 1
1 96 1 5 -9% of mass 95 1 6.057 1
1 173 1 Less than 2% of mass 174 1 0.000(0)1 1
1 174 1 Greater than 50% of mass 95 1 73.102 1
1 175 1 5 -9% of mass 174 1 5.425(7.42)1 1
1 176 1 95 -101% % of mass 174 1 70.934(97.03)1 1
1 177 1 5 -9% % of mass 176 1 4.437(6.26)2 1
I_I 1 I
I·Value is % mass 174 2-Value is % mass 176
This check applies to the following Calibration Standards:
1 EPA 1 LAB I LAB 1 DATE I TIME 1
I SAMPLE NO. 1 SAMPLE ID I FILE ID 1 ANALYZED 1 ANALYZED 1
1=====1====1===1 I 1
I1VSTD10 1 IV006E1502 IREW262 1 05/16/23 1 12:17 1
1 1 1 1 I I
REPORT ID: 23E133 Page 125 of 345
CONTINUE_CALIBRATION . CALIBRATION VERIFICATION
Instrument ID :06 IC Beginning DateTime :05/15/23 13:47
S~'ke Amount :10 PPB CC/CV File :REW262 IC File :REW253
1M WJI I'arameters
1 1,4·DIFLUOROBENZENE 2 D1chlorodifluoromethane 3 Chloromethane 4 Vinyl chloride
~ Bromomethane Chloroethane
~ Dichlorofluoromethane Trichl orofl uoromethane 5 9 Acrolein 10 1.1.2·Trichloro·1.2.2·trifluoroethane 511 Acetone 12 1.1·Dichloroethene 25 13 tert·Butyl alcohol 14 Acetonitrile 15 Methyl acetate 16 Iodomethane 17 Methylene chloride 18 CarbOn disulfide 5 19 Acrtlonitrile 20 ter .But2l methyl ether (MTBE) 21 trans·1. ·Dichloroethene 22 Isopropyl ether (DIPE) 23 Vinyl acetate 24 1.1·Dichloroethane 25 25 2· Butanol 26 tert·Butyl ethyl ether (ETBE)
5 27 2·Butanone 28 2.2'Dichloro~ropane 29 cis·1.2·Dich oroethene 30 Chloroform 5 31 tert.~l alcohol 32 Bromoch oromethane 33 Tetrahydrofuran
34 Dibromofluoromethane
35 1. 111. Trichloroethane 36 Cyc ohexane 37 2.2.4·Trimethylpentane
38 1.1·Dichloropropene 39 Carbon tetrachloride 40 tert'ml methr;l ether (TAME) 41 1.2·Dic loroet ane·d4 42 1.2·Dichloroethane 43 Benzene 44 Trichloroethene 45 MethnlCr;clohexane 46 1.2· ic loropropane 20 47 1.4·Dioxane 48 Bromodichloromethane 49 Di bromomethane
50 2·Chloroethyl vinyl ether
5 51 4'Meth~1'2.~entanone 52 CiS.1 as ·DiC loropropene
53 CHLOR ENZENE·D5 54 Toluene·d8
55 Toluene
56 Ethyl methacrr;late 57 trans·1.3·Dic loropropene
58 1. 1. 2-Trichloroethane
5 59 2-Hexanone 60 1.3-Dichloro~ropane 61 Tetrachloroe hene 62 Dibromochloromethane
~ 2-Ethyl-1-butanol 1.2-D1bromoethane
g~ 1-Chlorohexane Chlorobenzene
67 1. 1. 162-Tetrachloroethane
68 Ethyl enzene
2 69 m-Xylene & p-Xylene
70 o-Xylene
71 Styrene 72 I sopro~R 1 benzene 73 1.2-DI LOROBENZENE-D4 74 8romoform
75 1. 1.2. 2-Tetrachloroethane
76 4-Bromofluorobenzene
77 1.2.3-Trichloropropane
78 trans-114-Dichloro-2-butene
79 n-progy benzene 80 Bromo enzene
~~ 1.3n5-Trimethylbenzene 2-C lorotoluene
83 4-Chlorotoluene
84 tert-Butylbenzene
85 1. 2. 4-Tr1 methyl benzene
86 sec-Butyl benzene
87 ~-Isop.rO~Yltoluene 88 .3-Dich orobenzene
89 1. 2. 3-Trimethyl benzene
90 1.4-Dichlorobenzene
91 n-Butylbenzene
92 1. 2-01 chlorobenzene
§~ 1.2-Dibromo-3-chloropropane 1.2.4-Trichlorobenzene
95 Hexachlorobutadiene
96 Na~hthalene 97 1 .. 3·Trichlorobenzene
= * ~unt Nom1nal AmOunt M
{;{;_{;on I{;U;~ .\..\._~sp I~
10.000 0 4163900 1
9.577 ·4.2 1594659 0.383
10.075 0.7 1858552 0.446
9.883 ·1.2 1773793 0.426
9.987 ·0.1 1475861 0.354
10.009 0.1 1083934 0.260
10.285 2.9 2534516 0.609
9.404 ·6.0 2008246 8:~~ 48.753 ·2.5 511684
9.854 ·1.5 ~~m~~ 0.273
43.498 '13.0 37 8:g,~ 10.420 4.2 2
224.905 '10.0 1 0.010
9.224 ·7.8
1m
0.025
10.035 0.4 0.606
9.636 ·3.6 ~ 0.377
11.908 19.1 1.566
49.826 ·0.3 0.045
9.717 ·2.8 2 73 0.525
10.281 2.8 1621838 0.389
10.091 0.9 4149215 0.996
9.727 ·2.7 1237019 0.297
10.184 1.8 2614330 0.628
9.870 ·1.3 3357243 0.806
47.475 ·5.0 1182225 0.057
10.761 7.6 1489974 0.358
10.164 1.6 1583162 0.380
9.874 ·1.3 2479991 0.596
9.698 ·3.0 771973 0.185
8.736 ·12.6 122381 0.029
9.962 ·0.4 1339712 0.322
9.559 ·4.4 1995063 0.479
10.182 1.8 2216130 0.532
9.950 ·0.5 684285 0.164
10.272 2.7 1685341 0.405
9.709 ·2.9 2604562 0.626
9.764 ·2.4 913150 0.219
9.610 ·3.9 1122894 0.270
10.190 1.9 5749673 1.381
10.078 0.8 1523705 0.366
10.906 9.1 2546553 0.612
9.982 -0.2 1310301 0.315
174.464 ·12.8 99083 0.001
9.708 ·2.9 1703220 0.409
9.607 ·3.9 647747 0.156
9.011 ·9.9 101667 0.024
48.910 ·2.2 2937939 0.141
10.148 1.5 2100341 0.504
10.000 0 3625488 1
10.498 5.0 4942467 1.363
10.521 5.2 6227725 1.718
9.518 ·4.8 1003286 0.277
9.998 -0.0 1533970 0.423
9.311 -6.9 790536 0.218
47.476 -5.0 2008417 0.111
9.661 -3.4 1467098 0.405
10.361 3.6 1344362 0.371
9.617 -3.8 1033057 0.285
9.772 -2.3 811809 0.224
10.663 6.6 2647411 0.730
10.274 2.7 3911993 1.079
9.958 -0.4 1319527 0.364
10.251 2.5 7326123 2.021
21.084 5.4 11002997 1.517
10.103 1.0 5380834 1.484
10.117 1.2 4097984 1.130
10.224 2.~ 6974011 1.924
10.000 1368873 1
9.569 -4.3 480992 0.351
9.987 -0.1 902086 0.659
10.376 3.8 1607771 1.175
9.337 -6.6 216034 0.158
9.507 -4.9 22 95 0.163
10.850 8.5 26 6.494
10.233 2.3 1 1.058
10.508 5.1 ~ 4.069
10.684 6.8 5 4.120
10.410 4.1 4343425 3.173
10.516 5.2 1337846 0.977
10.364 3.6 5424992 3.963
10.660 6.6 7851381 5.736
10.637 6.4 6116783 U~ 10.497 5.0 2809205
10.194 1.9 4844060 3.539
10.345 3.5 2775669 2.028
10.958 9.6 ~~mi~ 4.359
10.155 1.5 1.655
8.960 -10.4 129253 0.094
10.336 3.4 1513149 1.105
11.128 11.3 1002912 0.733
9.920 -0.8 2120891 1.549
10.276 2.8 1156229 0.845
II\V~ I~ ~KUIl
1 10.086 10.085
0.400 1.690 1.693
8:tir 1.927 1.929 2.045 2.038
0.355 2.499 2.502 0.260 2.598 2.599 0.592 2.638 2.638 0.513 2.875 2.877 0.025 3.405 3.396 0.277 3.447 3.448
0.040 3.489 3.488 0.551 3.656 3.656 0.011 3.824 3.813
0.027 4.201 4.185 0.604 4.117 4.117 0.392 4.390 4.395
1.315 4.369 4.368 0.045 4.641 4.641 0.540 4.704 4.687 0.379 4.914 4.897 0.988 5.605 5.605
0.305 5.836 5.838
0.617 5.773 5.752
0.817 6.549 6.533 0.060 6.821 6.831 0.333 7.093 7.074
0.374 7.198 7.196
0.603 7.596 7.575
0.191 7.953 7.952
8j~ 8.078 8.075
8.099 8.099 0.501 8.489 8.493 0.523 8.476 8.474
0.165 8.853 8.847
0.394 9.021 9.017 0.644 9.203 9.200
0.225 9.216 9.216
0.281 9.424 9.414
1.355 9.398 9.398
0.363 10.670 10.663 0.561 10.748 10.745
0.315 11.021 11. 023
0.001 11.566 11. 569 0.421 11.462 11.462 0.162 11.540 11.539 0.027 12.150 12.154
U~ 12.202 12.209 12.513 12.513
1 15.538 15.537 1.299 12.916 12.915
1.633 13.059 13.057
0.291 13.487 13.489
0.423 13.435 13.434
0.234 13.695 13.689
0.117 13.772 13.770 0.419 14.136 14.135
0.358 14.188 14.187
0.296 14.538 14.538
0.229 14.876 14.879
U~ij 15.226 15.226 15.603 15.602 0.365 15.694 15.693 1.971 15.707 15.710
1.439 lt~~ 15.836
1.469 16.568
1.117 16.628 16.634
1.88f 17.173 17.173 19.419 19.419 0.367 17.173 17.174
0.660 17.446 17.451 1.132 17.550 17.549
0.169 17.667 17.665 0.172 17.771 17.770
5.985 17.771 17.770
j:8~ 17.809 17.809 17.978 17.978
3.856 17.991 17.991
ij:3~ 1B.056 18.056 18.433 18.432
3.824 18.472 18.471
5.381 18.679 18.679 4.201 18.835 18.835
1.955 18.939 18.938
3.471 19.017 19.016
1.960 19.056 19.055
3.978 19.276 19.276
1.630 19.445 19.446
0.105 20.224 20.221
1.069 21.055 21. 054
0.658 21.184 21.184
1.562 21.327 21.327
0.822 21.574 21.575
Column Spec :RTX502.2 ID :0.25MM IC Ending DateTime :05/15/23 17:41
HPChem Method :V006E15 Date_Time :05/16/23 12:17
I~_/'QU \;o=.xu ~o..::xr -co=.xz I {;o:::c-o r
0 7.72
9.53 9.17
8.19 8.16
7.59 6.20 8.86 7.94
18.81 0.0075 0.0356 0.9975
8.21
10.70
11.30 6.30
9.47
1U8 9.58 6.64 6.43 6.20 6.83
7.69 7.25 7.69
7.69 6.29
1U~ 7.49
8.58 11.51
6.60 6.68 7.31
8.16 6.90 5.93 6.58 11.23 6.21
11.84 6.64
7.09 11.55 11.05 7.27
0 7.13 8.62 9.34 7.62 6.47
9.00 6.36 7.39 6.12
7.06 6.27 6.31
6.91 5.72 8.96 5.46
5.99 6.20 0 8.04 7.66 7.49
6.04
6.85 9.51
6.90 6.52
6.44 5.83 8.15 6.65 9.56 7.45 7.54
6.31 6.69 7.80 8.54 8.34 9.93
9.35 5.97 7.45
--------------------------
REPORT ID: 23E133 Page 126 of 345
BFB
Data File D:\HPCHEM\1\DATA\23E16\REW261.D
Aeq On 16 May 2023 11:11 am
Sample BFB06E12
Mise T/CHK
MS Integration Params: RTE.P
Vial: 1
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title : METHOD 8260
Ab%~ TIC: REW261.D
600000
500000
400000
300000
200000
100000
0
tIJme--> 16~00 16~50 doo d50 18~00 18~50 19~00 I
fl\bundance Average of 17.523 to 17.549 min.: REW261.D (-)
95
120000
100000 174
80000 I
60000 75
40000
20000 50
3~. 44 ill 61 6~ II II 81 8~ 104109 117 128 135141 0 .111 .I
m/z--> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 1"70 180
AutoFind: Scans 1111, 1112, 1113; Background Corrected with Scan 1106
I Target I ReI. to I L~w7r
Mass Mass Llmlt%
50
75
95
96
173
174
175
176
177
95
95
95
95
174
95
174
174
176
15
30
100
5
0.00
50
5
95
5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
ReI.
Abn%
16.4
42.6
100.0
6.1
0.0
73.1
7.4
97.0
6.3
Raw
Abn
21160
54849
128803
7802
a
94157
6988
91365
5715
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REW261.D V006E15.M Tue May 16 13: 00: 46 2023 ~ ;\\1\'1 ~
J REPORT ID: 23E133 Page 127 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06
1.00
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M 1,1,2-Trichloro-1,2,2-trifl
11 TIM Acetone
12 C,T,M 1 /1-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1 /2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P/T,M 1 /1-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M 1,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2 /4-Trimethylpentane
38 T,M 1 /1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
(#) = Out of Range
REW262.D V006E15.M
Amount Calc.
10.000 10.000
10.000 9.577
10.000 10.075
10.000 9.883
10.000 9.987
10.000 10.009
10.000 10.285
10.000 9.404
50.000 48.753
10.000 9.854
50.000 43.498
10.000 10.420
250.000 224.905
-1. 000 0.000
10.000 9.224
10.000 10.035
10.000 9.636
10.000 11.908
50.000 49.826
10.000 9.717
10.000 10.281
10.000 10.091
10.000 9.727
10.000 10.184
250.000 0.000
10.000 9.870
50.000 47.475
10.000 10.761
10.000 10.164
10.000 9.874
50.000 0.000
10.000 9.698
10.000 8.736
10.000 9.962
10.000 9.559
10.000 10.182
10.000 0.000
10.000 9.950
10.000 10.272
10.000 9.709
10.000 9.764
%Dev Area% Dev(min)
0.0
4.2
-0.7
1.2
0.1
-0.1
-2.9
6.0
2.5
1.5
13.0
-4.2
10.0
0.0
7.8
-0.4
3.6
-19.1
0.3
2.8
-2.8
-0.9
2.7
-1. 8
100.0#
1.3
5.0
-7.6
-1. 6
1.3
100.0#
3.0
12.6
0.4
4.4
-1. 8
100.0#
0.5
-2.7
2.9
2.4
99
97
98
97
98
99
113
96
112
113
102
113
99
o
109
111
110
122
108
103
113
111
100
113
a
109
109
113
111
110
o
108
102
103
112
112
o
110
117
106
100
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.02
0.00
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.02
0.00
0.02
0.00
0.02
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
Page 1
REPORT ID: 23E133 Page 128 of 345
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Evaluate Continuing Cali. )ration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 1,2-Dichloroethane 10.000 9.610 3.9 105 0.01
T,M Benzene 10.000 10.190 -1. 9 111 0.00
T,M Trichloroethene 10.000 10.078 -0.8 111 0.00
T,M Methylcyclohexane 10.000 10.906 -9.1 122 0.00
C,T,M 1,2-Dichloropropane 10.000 9.982 0.2 111 0.00
T,M 1,4-Dioxane 200.000 174.464 12.8 105 -0.01
T,M Bromodichloromethane 10.000 9.708 2.9 110 0.00
T,M D ibromome thane 10.000 9.607 3.9 105 0.00
T,M 2-Chloroethyl vinyl ether 10.000 9.011 9.9 96 0.00
T,M 4-Methyl-2-pentanone 50.000 48.910 2.2 106 0.00
T,M cis-1,3-Dichloropropene 10.000 10.148 -1. 5 110 0.00
I CHLOROBENZENE-D5 10.000 10.000 0.0 98 0.00
S Toluene-d8 10.000 10.498 -5.0 105 0.00
C,T,M Toluene 10.000 10.521 -5.2 113 0.01
T,M Ethyl methacrylate 10.000 9.518 4.8 103 0.00
T,M trans-1,3-Dichloropropene 10.000 9.998 0.0 107 0.00
T,M 1,1,2-Trichloroethane 10.000 9.311 6.9 105 0.00
T,M 2-Hexanone 50.000 47.476 5.0 108 0.00
T,M 1,3-Dichloropropane 10.000 9.661 3.4 103 0.00
T,M Tetrachloroethene 10.000 10.361 -3.6 111 0.00
T,M Dibromochloromethane 10.000 9.617 3.8 104 0.00
T,M 2-Ethyl-1-butanol -1. 000 0.000 0.0 0 0.00
T,M 1,2-Dibromoethane 10.000 9.772 2.3 106 0.00
T,M 1-Chlorohexane 10.000 10.663 -6.6 113 0.00
P, T,M Chlorobenzene 10.000 10.274 -2.7 110 0.00
T,M 1, 1, 1,2-Tetrachloroethane 10.000 9.958 0.4 109 0.00
C,T,M Ethylbenzene 10.000 10.251 -2.5 113 0.00
T,M m-Xylene & p-Xylene 20.000 21.084 -5.4 112 0.00
T,M o-Xylene 10.000 10.103 -1. 0 111 0.00
T,M Styrene 10.000 10.117 -1.2 110 0.00
T,M Isopropylbenzene 10.000 10.224 -2.2 113 0.00
I 1,2-DICHLOROBENZENE-D4 10.000 10.000 0.0 96 0.00
P,T,M Bromoform 10.000 9.569 4.3 103 0.00
P,T,M 1,1,2,2-Tetrachloroethane 10.000 9.987 0.1 106 0.00
S 4-Bromofluorobenzene 10.000 10.376 -3.8 103 0.00
T,M 1, 2, 3-Trichloropropane 10.000 9.337 6.6 100 0.00
T,M trans-1,4-Dichloro-2-butene 10.000 9.507 4.9 104 0.00
T,M n-Propylbenzene 10.000 10.850 -8.5 114 0.00
T,M Bromobenzene 10.000 10.233 -2.3 110 0.00
(#) = Out of Range
REW262.D V006E15.M Tue May 16 13:01:04 2023
REPORT ID: 23E133 Page 129 of 345
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M l,3,5-Trimethylbenzene 10.000 10.508 -5.1 113 0.00
T,M 2-Chlorotoluene 10.000 10.684 -6.8 112 0.00
T,M 4-Chlorotoluene 10.000 10.410 -4.1 112 0.00
T,M tert-Butylbenzene 10.000 10.516 -5.2 113 0.00
T,M 1, 2, 4-Trimethylbenzene 10.000 10.364 -3.6 113 0.00
T,M sec-Butylbenzene 10.000 10.660 -6.6 114 0.00
T,M p-Isopropyltoluene 10.000 10.637 -6.4 114 0.00
T,M l,3-Dichlorobenzene 10.000 10.497 -5.0 111 0.00
T,M 1, 2, 3-Trimethylbenzene 10.000 10.194 -1. 9 110 0.00
T,M l,4-Dichlorobenzene 10.000 10.345 -3.5 109 0.00
T,M n-Butylbenzene 10.000 10.958 -9.6 118 0.00
T,M l,2-Dichlorobenzene 10.000 10.155 -1. 5 107 0.00
T,M l,2-Dibromo-3-chloropropane 10.000 8.960 10.4 100 0.00
T,M l,2,4-Trichlorobenzene 10.000 10.336 -3.4 111 0.00
T,M Hexachlorobutadiene 10.000 11.128 -11. 3 116 0.00
T,M Naphthalene 10.000 9.920 0.8 104 0.00
T,M 1, 2, 3-Trichlorobenzene 10.000 10.276 -2.8 108 0.00
.-
t;1A ~J (1( 1--'3 _____________________________________________________________ :it __________ _
(#) = Out of Range
REW262.D V006E15.M
SPCC's out = a CCC's out = 0
Tue May 16 13:01:05 2023 Page 3
REPORT ID: 23E133 Page 130 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M l,l,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M l,l-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1,2-Dichloroethane-d4
AvgRF CCRF
1.000 1.000
0.400 0.383
0.443/ 0.446
0.431 0.426
0.355 0.354
0.260 0.260
0.592 0.609
0.513 0.482
0.025 0.025
0.277 0.273
0.040 .... 0.033
0.551 0.575
0.011 0.010
0.000 0.000
0.027 0.025
0.604 0.606
0.392 0.377
1.315 1.566
0.045 0.045
0.540 0.525
0.379 0.389
0.988 0.996
0.305 0.297
0.617 /0.628
0.000 0.010
0.817 0.806
0.060 ~ 0.057
0.333 0.358
0.374 0.380
0.603 0.596
0.000 0.001
0.191 0.185
0.034 0.029
0.323 0.322
0.501 0.479
0.523 0.532
0.000 0.025
0.165 0.164
0.394 0.405
0.644 0.626
0.225 0.219
(#) = Out of Range
REW262.D V006E15.M Tue May 16 13:01:09 2023
%Dev Area% Dev(min)
0.0
4.3
-0.7
1.2
0.3
0.0
-2.9
6.0
0.0
1.4
17.5
-4.4
9.1
0.0
7.4
-0.3
3.8
-19.1
0.0
2.8
-2.6
-0.8
2.6
-1. 8
0.0
1.3
5.0
-7.5
-1. 6
1.2
0.0
3.1
14.7
0.3
4.4
-1. 7
0.0
0.6
-2.8
2.8
2.7
99
97
98
97
98
99
113
96
112
113
102
113
99
0#
109
111
110
122
108
103
113
111
100
113
0#
109
109
113
111
110
0#
108
102
103
112
112
0#
110
117
106
100
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02
0.00
0.02
0.00
0.00
0.00
0.00
0.02
0.02
0.00
0.00
0.02
0.00
0.02
0.00
,0. 02
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
REPORT ID: 23E133 Page 131 of 345
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1S02
Misc 10ppb 8260/S0ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06
1.00
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M l,2-Dichloroethane 0.281
T,M Benzene 1. 355
T,M Trichloroethene 0.363
T,M Methylcyclohexane 0.561
C,T,M l,2-Dichloropropane 0.315
T,M 1,4-Dioxane 0.001
T,M Bromodichloromethane 0.421
T,M Dibromomethane 0.162
T,M 2-Chloroethyl vinyl ether 0.027
T,M 4-Methyl-2-pentanone 0.144
T,M cis-1,3-Dichloropropene 0.497
I CHLOROBENZENE-D5 1.000
S Toluene-d8 1.299
C,T,M Toluene 1. 633
T,M Ethyl methacrylate 0.291
T,M trans-1,3-Dichloropropene 0.423
T,M 1,l,2-Trichloroethane 0.234
T,M 2-Hexanone 0.117
T,M 1,3-Dichloropropane 0.419
T,M Tetrachloroethene 0.358
T,M Dibromochloromethane 0.296
T,M 2-Ethyl-1-butanol 0.000
T,M 1,2-Dibromoethane 0.229
T,M 1-Chlorohexane 0.685
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
0.270 3.9 105 0.01
1. 381 -1. 9 111 0.00
0.366 -0.8 111 0.00
0.612 -9.1 122 0.00
0.315 0.0 111 0.00
0.001 0.0 105 -0.01
0.409 2.9 110 0.00
0.156 3.7 105 0.00
0.024 11.1 96 0.00
0.141 2.1 106 0.00
0.504 -1. 4 110 0.00
1. 000 0.0 98 0.00
1. 363 -4.9 105 0.00
1.718 -5.2 113 0.01
0.277 4.8 103 0.00
0.423 0.0 107 0.00
0.218 6.8 105 0.00
0.111 5.1 108 0.00
0.405 3.3 103 0.00
0.371 -3.6 111 0.00
0.285 3.7 104 0.00
0.000 0.0 0# 0.00
0.224 2.2 106 0.00
0.730 -6.6 113 0.00
P, T,M Chlorobenzene 1. 050/ 1.079 -2.8 110 0.00
T,M 1, 1, 1, 2-Tetrachloroethane 0.365 0.364 0.3 109 0.00
C,T,M Ethylbenzene 1.971 2.021 -2.5 113 0.00
T,M m-Xylene & p-Xylene 1.439 1. 517 -5.4 112 0.00
T,M o-Xylene 1.469 1.484 -1. a 111 0.00
T,M Styrene 1.117 1.130 -1. 2 110 0.00
T,M Isopropylbenzene 1. 882 1. 924 -2.2 113 0.00
I 1,2-DICHLOROBENZENE-D4 1.000 1. 000 0.0 96 0.00
P,T,M Bromoform 0.367 ....... 0.351 4.4 103 0.00
P,T,M 1,l,2,2-Tetrachloroethane 0.660 0.659 0.2 106 0.00
S 4-Bromofluorobenzene 1.132 --1..175 -3.8 103 0.00
T,M 1,2,3-Trichloropropane 0.169 0.158 6.5 100 0.00
T,M trans-1,4-Dichloro-2-butene 0.172 0.163 5.2 104 0.00
T,M n-Propylbenzene 5.985 6.494 -8.5 114 0.00
T,M Bromobenzene 1.034 1.058 -2.3 110 0.00
(#) = Out of Range
REW262.D V006E15.M Tue May 16 13:01:11 2023
REPORT ID: 23E133 Page 132 of 345
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D Vial: 2
Operator: LYamas Aeq On 16 May 2023 12:17 pm
Sample IV006E1502 Inst 06
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1, 3 , 5-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.856
T,M 4-Chlorotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M 1 /2,4-Trimethylbenzene 3.824
T,M see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
T,M 1,3-Diehlorobenzene 1. 955
T,M 1 /2,3-Trimethylbenzene 3.471
T,M 1,4-Diehlorobenzene 1. 960
T,M n-Butylbenzene 3.978
T,M 1,2-Diehlorobenzene 1.630
T,M 1,2-Dibromo-3-ehloropropane 0.105
T,M 1,2 /4-Triehlorobenzene 1.069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1.562
T,M 1,2,3-Triehlorobenzene 0.822
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
4.069 -5.1 113 0.00
4.120 -6.8 112 0.00
3.173 -4.1 112 0.00
0.977 -5.2 113 0.00
3.963 -3.6 113 0.00
5.736 -6.6 114 0.00
4.468 -6.4 114 0.00
2.052 -5.0 111 0.00
3.539 -2.0 110 0.00
2.028 -3.5 109 0.00
4.359 -9.6 118 0.00
1.655 -1. 5 107 0.00
0.094 10.5 100 0.00
1.105 -3.4 111 0.00
0.733 -11. 4 116 0.00
1.549 0.8 104 0.00
0.845 -2.8 108 0.00
,5lA :3/(7(13
--------------------------------------------------------------------------
(#) = Out of Range
REW262.D V006E15.M
SPCC's out = 0 CCC's out = 0
Tue May 16 13:01:12 2023 Page 3
REPORT ID: 23E133 Page 133 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Vial: 2
Operator: LYamas
Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 16 12:44 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.09 114
15.54 117
19.42 152
8.10
9.22
12.92
17.55
1.69
1. 93
2.05
2.50
2.60
2.64
2.87
3.40
3.45
3.49
3.66
3.82
4.20
4.12
4.39
4.37
4.64
4.70
4.91
5.61
5.84
5.77
6.55
6.82
7.09
7.20
7.60
111
65
98
95
85
50
62
94
64
67
101
56
151
43
/61
59
74
142
49
76
53
(73
96
45
43
63
( 59
43
77
96
"'83
4163900
3625488
1368873
10.00 ug/l
10.00 ug/l
10.00 ug/l
1339712 9.96
Recovery =
913150 9.76
Recovery =
4942467 10.50
Recovery =
1607771 10.38
Recovery =
ug/l
99.60%
ug/l
97.60%
ug/l
105.00%
ug/l
103.80%
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1594659
1858552
1773793
1475861
1083934
2534516
2008246
9.58 ug/l
10.08 ug/l
9.88 ug/l
9.99 ug/l
10.01 ug/l
10.28 ug/l
9.40 ug/l
Qvalue
98
98
98
511684
1137993
684437
2392205
1048289
103764
2524963
1571212
6520813
941239
2185973
1621838
4149215
1237019
2614330
3357243
1182225
1489974
1583162
2479991
48.75 ug/l
9.85 ug/l
43.50 ug/l
10.42 ug/l
224.90 ug/l
9.22 ug/l
10.03 ug/l
9.64 ug/l
11. 91 ug/l
49.83 ug/l
9.72 ug/l
10.28 ug/l
10.09 ug/l
9.73 ug/l
10.18 ug/l
9.87 ug/l
47.47 ug/l
10.76 ug/l
10.16 ug/l
9.87 ug/l
100
99
100
98
99
99
98
99
100
99
99
99
100
98
98
100
100
98
99
98
97
99
100
100
(#) = qualifier out of range (m) = manual integration 5
REW262.D V006E15.M Tue May 16 13:01:20 2023 lA-1\v'3 Page 1
61\ REPORT ID: 23E133 Page 134 of 345
Quantitation Report (Q r Reviewed)
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Acq On 16 May 2023 12:17 pm
Sample IV006E1502
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 12:44 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32)
33)
35)
36)
38)
39)
40)
42)
43)
44)
45)
46)
47)
48)
49)
50)
51)
52)
55)
56)
57)
58)
59 )
60)
61}
62)
64)
65 }
66)
67)
68}
69)
70)
71 )
72)
74)
75)
77 )
78}
79)
80 }
Bromochloromethane
Tetrahydrofuran
1, 1, 1-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
l,2-Dichloroethane
Benzene
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
1,4-Dioxane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
1,1,2,2-Tetrachloroethane
1,2,3-Trichloropropane
trans-1,4-Dichloro-2-buten
n-Propylbenzene
Bromobenzene
7.95
8.08
8.49
8.48
8.85
9.02
9.20
9.42
9.40
130
42
97
84
110
119
73
62
78
130
83
63
88
83
93
63
43
75
<r 91
69
" 75 . 97
43
76
164
129
107
10.67
10.75
11.02
11.57
11.46
11.54
12.15
12.20
12.51
13.06
13.49
13.43
13.69
13.77
14.14
14.19
14.54
14.88
15.23
15.60
15.69
~ 91
112
131
15.71 / 91
15.84., 91
16.56,91
16.63 104
" 17.17 105
J 17.17 173
17.45/'83
17.67 110
17.77 53
17.77 91
17.81 156
771973
122381
1995063
2216130
684285
1685341
2604562
1122894
5749673
1523705
2546553
1310301
99083
1703220
647747
101667
2937939
2100341
6227725
1003286
1533970
790536
2008417
1467098
1344362
1033057
811809
2647411
3911993
1319527
7326123
11002997
5380834
4097984
6974011
480992
902086
216034
223395
8889926
1448441
9.70 ug/l
8.74 ug/l
9.56 ug/l
10.18 ug/l
9.95 ug/l
10.27 ug/l
9.71 ug/l
9.61 ug/l
10.19 ug/l
10.08 ug/l
10.91 ug/l
9.98 ug/l
174.46 ug/l
9.71 ug/l
9.61 ug/l
9.01 ug/l
48.91 ug/l
10.15 ug/l
10.52 ug/l
9.52 ug/l
10.00 ug/l
9.31 ug/l
47.48 ug/l
9.66 ug/l
10.36 ug/l
9.62 ug/l
9.77 ug/l
10.66 ug/l
10.27 ug/l
9.96 ug/l
10.25 ug/l
21.08 ug/l
10.10 ug/l
10.12 ug/l
10.22 ug/l
9.57 ug/l
9.99 ug/l
9.34 ug/l
9.51 ug/l
10.85 ug/l
10.23 ug/l
Qvalue
100
97
100
90
99
97
99
99
100
99
98
99
94
99
98
99
99
99
100
100
98
99
99
98
99
100
100
100
100
100
99
99
100
99
99
99
98
100
97
100
99
---------------------------------------------------------;:--------------
(#) = qualifier out of range (m) = manual integration ~~1(~)
REW262.D V006E15.M Tue May 16 13:01:21 2023 !J \t Page 2
REPORT ID: 23E133 Page 135 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Aeq On 16 May 2023 12:17 pm
Sample IV006E1502
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 16 12:44 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
81 ) l,3,5-Trimethylbenzene 17.98 105 5569834 10.51 ug/l
82) 2-Chlorotoluene 17.99 91 5640189 10.68 ug/l
83) 4-Chlorotoluene 18.06 91 4343425 10.41 ug/l
84) tert-Butylbenzene 18.43 134 1337846 10.52 ug/l
85) l,2,4-Trimethylbenzene 18.47 105 5424992 10.36 ug/l
86) see-Butylbenzene 18.68 105 7851381 10.66 ug/l
87) p-Isopropyltoluene 18.83 119 6116783 10.64 ug/l
88) l,3-Diehlorobenzene 18.94 146 2809205 10.50 ug/l
89) 1, 2, 3-Trimethylbenzene 19.02 105 4844060 10.19 ug/l
90) l,4-Diehlorobenzene 19.06 146 2775669 10.35 ug/l
91 ) n-Butylbenzene 19.28 91 5967378 10.96 ug/l
92) l,2-Diehlorobenzene 19.45 146 2265912 10.16 ug/l
93) l,2-Dibromo-3-ehloropropan 20.22 157 129253 8.96 ug/l
94) l,2,4-Triehlorobenzene 21.05 180 1513149 10.34 ug/l
95) Hexaehlorobutadiene 21.18 225 1002912 11.13 ug/l
96) Naphthalene 21.33 128 2120891 9.92 ug/l
97) 1, 2, 3-Triehlorobenzene 21.57 180 1156229 10.28 ug/l
Qvalue
99
99
99
99
99
100
100
99
100
99
99
100
95
99
99
100
98
REPORT ID: 23E133 Page 136 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E16\REW262.D
Aeq On 16 May 2023 12:17 pm
Sample IV006E1502
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 16 12:44 2023
TBA
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Initial Calibration
f.bundance
I 1.2e+07
TIC: REW262.D
i i 1.15e+07
1.1e+071
1.05e+07j
I
1e+071
I
95000001
90000001
85000001
8000000
7500000
!
7000000j
65000001
6000000
5500000
5000000
45000001
40000001
35000001
3000000 1
2500000
2000000
1500000
1000000
500000
:;;
...::
Q) c: ..
,£;
~ ~-i!f R~ o g
!E ~ e~ e
.Q$, ..Q = .c: ~ ~
:;; :;;
1--1-:
o;i '" :;;-c: .. "0 l-,£; ." ~ i i ~ ai~ E: ~I-O CJJ5. 1-:0. 1; -gj(i}"i;
:;; :;;
~ ~
~ u:f m a-: t!!. ';lL
:;;
...::
I-
t-
o
III
! O~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
[ime~-=-> ______ ~~~ __ ~~ ____ ~~ __ ~~ ____ ~~ __ ~~ __ ~1~4~.0~0 __ ~1~6~.O~O __ ~~~ __ ~~ ____ ~
REW262.D V006E15.M Tue May 16 13:01:24 2023
REPORT ID: 23E133 Page 137 of 345
DAILY CALIBRATIONS
REPORT ID: 23E133 Page 138 of 345
1
2
3
4
5
6
7
8
9
10
11
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name: EMAX Laboratories, Inc.
Lab Code : EMAX
Lab File ID: REW407
Instrument ID: 06
Project : TEAD-S
SDG No : 23El33
BFB In~ect~on D~te: OS/23/23
BFB In]ect1on T1me: 08:15
m/e
50
75
95
96
ION ABUNDANCE CRITERIA
" RELATIVE
ABUNDANCE
173
174
175
176
177
17VaTue 1S % mass 174 2-Value 1S % mass 176
16.840
42.887
100.000
5.951
0.000(0)1
74.929
5.464(7.29)1
73.179(97.66)1
4.689(6.41)2
This check applies to the following samples, Lab QCs and Standards:
EPA LAB LAB DATE
SAMPLE NO. SAMPLE ID FILE ID ANALYZED
========================== ================ ============ ==========
VSTD10 CV006E1506 REW408 OS/23/23
LCS1W V006E19L REW409 OS/23/23
LCD1W V006E19C REW410 OS/23/23
MBLK1W V006E19B REW412 OS/23/23
S-55-90-052023 23E133-01 REW424 OS/23/23
S-78-91-052023 23E133-02 REW425 OS/23/23
S-91-91-05-2023D 23E133-03 REW426 OS/23/23
S-91-91-052023 23E133-04 REW427 OS/23/23
TB-20230515 -l3 23E133-07 REW430 OS/23/23
SWMU-13-EB-052023 23El33-06 REW431 OS/23/23
VSTD10 EV006E1506 REW432 OS/23/23
TIME
ANALYZED
==========
08: 41
09:07
09:33
10:25
15:36
16:02
16:28
16:54
18:12
18:38
19:04
REPORT ID: 23E133 Page 139 of 345
FORM B
VOLATILE INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name: EMAX Laboratories, Inc.
Lab Code: EMAX
Lab File ID: REW253
Instrument ID: 06
INTERNAL STANDARD (IS)
12 HOUR STD
UPPER LIMIT
LOWER LIMIT
4201521
8403042
2100761
Area #
10.08
10.25
9.913
RT #
======================== =============== ==============
1
2
3
4
5
6
7
8
9
10
11
VSTDI0 4453053
LCSIW 4621716
LCDIW 4593862
MBLKIW 4319466
S-55-90-052023 4126343
S-78-91-052023 3915841
S-91-91-05-2023D 3678794
S-91-91-052023 3812793
TB-20230515-13 4065134
SWMU-13-EB-052023 3947190
VSTDI0 3945661
Area Upper Limit = +100% of ICAL Midpoint IS Area
Area Lower Limit = -50% of ICAL Midpoint IS Area
10.10
10.10
10.10
10.10
10.10
10.10
10.10
10.10
10.10
10.10
10.10
3710147
7420294
1855074
Area #
===============
3822117
4019517
3956960
3587206
3555270
3378542
3245586
3328624
3532734
3390039
3456327
Retention Time (RT) Upper Limit +10 seconds of ICAL Midpoint IS RT
Retention Time (RT) Lower Limit = -10 seconds of ICAL Midpoint IS RT
15.54
15.71
15.37
RT #
==============
15.55
15.55
15.55
15.55
15.55
15.55
15.55
15.55
15.55
15.55
15.55
Project: TEAD-S
SDG No: 23E133
Date Analyzed: 05/15/23
Time Analyzed: 15:57
1432830
2865660
716415
Area #
19.42
19.59
19.25
RT #
=============== ==============
1439501 19.43
1554477 19.43
1535139 19.43
1352000 19.43
1323293 19.43
1335551 19.43
1272897 19.43
1300113 19.43
1291764 19.43
1265594 19.43
1357453 19.43
REPORT ID: 23E133 Page 140 of 345
BFB
Data File D:\HPCHEM\1\DATA\23E23\REW407.D Vial: 1
Acq On 23 May 2023 8:15 am Operator: LYamas
Sample BFB06E19 Inst 06
Misc T/CHK Multiplr: 1.00
MS Integration Params: RTE.P
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title : METHOD 8260
~bundance
1200000
1000000
800000
600000
400000
200000
TIC: REW407.D
16.00 16.50 17.00 17.50 18.00 18.50 19.00
Abundance
: 250000
200000
i 1500001
I
100000
50000
I
ltz--> 0
37
)1 44
I I
30 40
75
50
68
~11 11.1111.
I I
50 60 70
I
80
Average of 17.537 to 17.563 min.: REW407.D (-)
95
87 II II ,II 106 117 130 141148155
90 100 110 120 130 140 150 160
174
I
170 180
207
190 200 210
AutoFind: Scans 1112, 1113, 1114; Background Corrected with Scan 1106
I Target I Rel. to I Lower
Mass Mass Limit%
50 95 15
75 95 30
95 95 100
96 95 5
173 174 0.00
174 95 50
175 174 5
176 174 95
177 176 5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
Rel.
Abn%
16.8,/
42.9/
100.0
6.0
0.0
74.9.J
7.3 /
97.7
6.4 .j
REW407.D V006E15.M Tue May 23 10:52:34 2023
Raw
Abn
40976
104357
243328
14480
0
182323
13296
178064
11409
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 23E133 Page 141 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Acq On 23 May 2023 8:41 am
Sample CV006E1S06
Misc 10ppb 8260/S0ppb KET-AA/2S0ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E1S.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000
20%
Min. ReI. Area
Max. ReI. Area
SO%
200%
.",.---
Max. R.T. Dev 0.16min
Compound Amount Calc. %Dev Area% Dev(min)
1 I 1,4-DIFLUOROBENZENE
2 TIM Dichlorodifluoromethane
3 P/T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 TIM Acrolein
10 T,M 1,1,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T~M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P/T,M 1,1-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 TIM 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M 1, 1, 1-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M 1,1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1,2-Dichloroethane-d4
10.000 10.000
10.000 11.181
10.000 10.234
10.000 9.361/,
10.000 9.218
10.000 9.699
10.000 10.807
10.000 9.396
SO.OOO 47.137
10.000 9.762
50.000 46.760
10.000 10.602
250.000 230.346 /'
-1.000 0.000
10.000 9.315
10.000 10.239
10.000 10.661
10.000 9.999
50.000 S1.842
10.000 9.608
10.000 10.583
10.000 10.563
10.000 10.661
10.000 10.402
250.000 0.000
10.000 10.289
50.000 49.904
10.000 11.168
10.000 10.S06 ~
10.000 10.038
50.000 0.000
10.000 9.898
10.000 9.417
10.000 9.731
10.000 9.552
10.000 10.879
10.000 0.000
10.000 10.959
10.000 10.128
10.000 9.413
10.000 9.S79
(#) = Out of Range
REW408.D V006E1S.M Tue May 23 10:52:48 2023
0.0
-11. 8
-2.3
6.4
7.8
3.0
-8.1
6.0
5.7
2.4
6.5
-6.0
7.9
0.0
6.9
-2.4
-6.6
0.0
-3.7
3.9
-5.8
-5.6
-6.6
-4.0
100.0#
-2.9
0.2
-11. 7
-5.1
-0.4
100.0#
1.0
5.8
2.7
4.S
-8.8
100.0#
-9.6
-1.3
S.9
4.2
106
122
107
98
96
103
126
103
116
119
117
123
108
o
118
121
130
110
121
109
124
124
117
123
o
121
122
126
123
120
o
117
118
107
120
128
o
129
123
110
lOS
0.01
0.00
0.00
0.00
0.02
0.02
0.02
0.02
0.00
0.04
0.02
0.00
0.02
0.00
0.02
-0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.03
0.02
0.02
0.02
0.03
0.01
0.01
0.01
0.01
0.01
0.01
Page 1
REPORT ID: 23E133 Page 142 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Acq On 23 May 2023 8:41 am
Sample CV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M 1,2-Dichloroethane
43 T,M Benzene
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M 1,2-Dichloropropane
47 T,M 1,4-Dioxane
48 T,M Bromodichloromethane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M 1,1,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M 1,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 2-Ethyl-1-butanol
64 T,M 1,2-Dibromoethane
65 T,M 1-Chlorohexane
66 P, T,M Chlorobenzene
67 T,M 1,1,l,2-Tetrachloroethane
68 C,T,M Ethylbenzene
69 T,M m-Xylene & p-Xylene
70 T,M o-Xylene
71 T,M Styrene
72 T,M Isopropylbenzene
73 I l,2-DICHLOROBENZENE-D4
74 P,T,M Bromoform
75 P,T,M 1,1,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1,2,3-Trichloropropane
78 T,M trans-1,4-Dichloro-2-butene
79 T,M n-Propylbenzene
80 T,M Bromobenzene
Amount Calc.
10.000 10.362
10.000 10.453
10.000 10.599
10.000 10.974 ~
10.000 10.511
200.000 175.545
10.000 9.789
10.000 9.786
10.000 12.262
50.000 51.974
10.000 10.213
10.000 10.000
10.000 10.255 ~
10.000 10.759
10.000 9.792
10.000 9.981
10.000 9.375
50.000 49.334
10.000 10.073
10.000 10.488
10.000 9.628
-1.000 0.000
10.000 9.765
10.000 10.833
10.000 10.670
10.000 9.518 /.
10.000 10.359
20.000 20.967
10.000 9.937
10.000 10.201
10.000 10.180
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.402
9.846
10.193
9.626
8.674
10.778
10.324
(#) = Out of Range
REW408.D V006E15.M Tue May 23 10:52:48 2023
%Dev Area% Dev(min)
-3.6
-4.5
-6.0
-9.7
-5.1
12.2
2.1
2.1
-22.6#
-3.9
-2.1
121
122
124
132
125
113
119
115
139
120
118
0.0 103
-2.6 108
-7.6 122
2.1 112
0.2 113
6.3 111
1. 3 119
-0.7 114
-4.9 119
3.7 110
0.0 a
2.3 111
-8.3 121
0.03
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.03
0.01
0.01
0.01
0.01
0.03
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
-6.7 120 0.01
0.01 4.8 110
-3.6 120
-4.8 118
0.6 115
-2.0 117
-1. 8 119
0.0
6.0
1.5
-1. 9
3.7
13.3
-7.8
-3.2
100
106
109
106
108
100
119
117
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.00
0.00
0.00
0.01
Page 2
REPORT ID: 23E133 Page 143 of 345
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Acq On 23 May 2023 8:41 am
Sample CV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M l,3,5-Trimethylbenzene 10.000 10.512 -5.1 119 0.01
T,M 2-Chlorotoluene 10.000 10.356 -3.6 114 0.01
T,M 4-Chlorotoluene 10.000 11. 828 -18.3 134 0.01
T,M tert-Butylbenzene 10.000 10.217 -2.2 115 0.00
T,M l,2,4-Trimethylbenzene 10.000 10.465 -4.6 120 0.01
T,M sec-Butylbenzene 10.000 10.533 -5.3 119 0.01
T,M p-Isopropyltoluene 10.000 10.896 -9.0 123 0.01
T,M l,3-Dichlorobenzene 10.000 11. 035 -10.4 123 0.01
T,M l,2,3-Trimethylbenzene 10.000 10.842 -8.4 123 0.01
T,M l,4-Dichlorobenzene 10.000 10.947 -9.5 121 0.01
T,M n-Butylbenzene 10.000 11. 251 -12.5 127 0.01
T,M l,2-Dichlorobenzene 10.000 10.956 -9.6 121 0.01
T,M l,2-Dibromo-3-chloropropane 10.000 8.761 12.4 103 0.00
T,M l,2,4-Trichlorobenzene 10.000 10.483 -4.8 119 0.01
T,M Hexachlorobutadiene 10.000 11. 493 -14.9 126 0.01
T,M Naphthalene 10.000 10.145 -1.4 112 0.01
T,M l,2,3-Trichlorobenzene 10.000 10.421 -4.2 115 0.01
(#) = Out of Range
REW408.D V006E15.M
SPCC's out = 0 CCC's out = 0
Tue May 23 10:52:49 2023 Page 3
REPORT ID: 23E133 Page 144 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Acq On 23 May 2023 8:41 am
Sample CV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M l,l,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M 1,1-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1,2-Dichloroethane-d4
AvgRF CCRF
1. 000 1. 000
0.400 0.447
0.443 0.453
0.431.,-0.403
0.355 0.327
0.260 0.252
0.592 0.640
0.513 0.482
0.025 0.024
0.277 0.271
0.040 0.035
0.551 0.585
0.011 0.010
0.000 0.000
0.027 0.025
0.604 0.619
0.392 0.417
1.315 1.315
0.045 0.047
0.540 0.519
0.379 0.401
0.988 1.043
0.305 0.326
0.617 /0.641
0.000 0.010
0.817 0.840
0.060 0.060
0.333 0.371
0.374 0.393
0.603 0.606
0.000 0.001
0.191 0.189
0.034 0.032
0.323 0.314
0.501 0.479
0.523 0.569
0.000 0.026
0.165 0.181
0.394 0.399
0.644 0.606
0.225 0.215
(#) = Out of Range
REW408.D V006E15.M Tue May 23 10:52:54 2023
%Dev Area% Dev(min)
0.0
-11.7
-2.3
6.5
7.9
3.1
-8.1
6.0
4.0
2.2
12.5
-6.2
9.1
0.0
7.4
-2.5
-6.4
0.0
-4.4
3.9
-5.8
-5.6
-6.9
-3.9
0.0
-2.8
0.0
-11. 4
-5.1
-0.5
0.0
1.0
5.9
2.8
4.4
-8.8
0.0
-9.7
-1. 3
5.9
4.4
106
122
107
98
96
103
126
103
116
119
117
123
108
0#
118
121
130
110
121
109
124
124
117
123
0#
121
122
126
123
120
0#
117
118
107
120
128
0#
129
123
110
105
0.01
0.00
0.00
0.00
0.02
0.02
0.02
0.02
0.00
0.04
0.02
0.00
0.02
0.00
0.02
-0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.03
0.02
0.02
0.02
0.03
0.01
0.01
0.01
0.01
0.01
0.01
Page 1
REPORT ID: 23E133 Page 145 of 345
42
43
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62
63
64
65
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67
68
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75
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77
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80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Acq On 23 May 2023 8:41 am
Sample CV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1,2-Dichloroethane 0.281
T,M Benzene 1. 355
T,M Trichloroethene 0.363
T,M Methylcyclohexane 0.561
C/T,M l,2-Dichloropropane 0.315
T,M 1,4-Dioxane 0.001
T,M Bromodichloromethane 0.421
T,M Dibromomethane 0.162
T,M 2-Chloroethyl vinyl ether 0.027
T,M 4-Methyl-2-pentanone 0.144
T,M cis-1,3-Dichloropropene 0.497
I CHLOROBENZENE-D5 1.000
S Toluene-d8 1. 299
C,T,M Toluene 1. 633
T,M Ethyl methacrylate 0.291
T,M trans-1,3-Dichloropropene 0.423
T,M 1,1,2-Trichloroethane 0.234
T,M 2-Hexanone 0.117
T,M 1,3-Dichloropropane 0.419
T,M Tetrachloroethene 0.358
T,M Dibromochloromethane 0.296
T,M 2-Ethyl-1-butanol 0.000
T,M 1,2-Dibromoethane 0.229
T,M 1-Chlorohexane 0.685
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
0.291 -3.6 121 0.03
1.417 -4.6 122 0.01
0.385 -6.1 124 0.01
0.615 -9.6 132 0.01
0.331 -5.1 125 0.01
0.001 0.0 113 0.00
0.412 2.1 119 0.01
0.158 2.5 115 0.01
0.033 -22.2# 139 0.03
0.150 -4.2 120 0.01
0.508 -2.2 118 0.01
1.000 0.0 103 0.01
1.332 -2.5 108 0.01
1.756 -7.5 122 0.03
0.285 2.1 112 0.01
0.422 0.2 113 0.01
0.220 6.0 111 0.01
0.115 1.7 119 0.01
0.422 -0.7 114 0.01
0.375 -4.7 119 0.01
0.285 3.7 110 0.01
0.000 0.0 0# 0.00
0.224 2.2 111 0.01
0.742 -8.3 121 0.01
P, T,M Chlorobenzene 1.050/ 1.121 -6.8 120 0.01
T,M 1, 1, 1,2-Tetrachloroethane 0.365 0.348 4.7 110 0.01
C/T,M Ethylbenzene 1.971 2.042 -3.6 120 0.01
T,M m-Xylene & p-Xylene 1.439 1. 509 -4.9 118 0.01
T,M o-Xylene 1. 469 1.460 0.6 115 0.01
T,M Styrene 1.117 1.140 -2.1 117 0.01
T,M Isopropylbenzene 1.882 1.915 -1. 8 119 0.01
I 1 /2-DICHLOROBENZENE-D4 1.000 I 1. 000 0.0 100 0.01
P/T,M Bromoform 0.367) 0.345 6.0 106 0.01
P,T/M 1, 1, 2, 2-Tetrachloroethane 0.660 0.650 1.5 109 0.01
S 4-Bromofluorobenzene 1.132 1.154 -1. 9 106 0.01
T,M 1,2,3-Trichloropropane 0.169 0.163 3.6 108 0.00
T,M trans-1,4-Dichloro-2-butene 0.172 0.149 13.4 100 0.00
T,M n-Propylbenzene 5.985 6.451 -7.8 119 0.00
T,M Bromobenzene 1.034 1. 068 -3.3 117 0.01
(#) = Out of Range
REW408.D V006E15.M Tue May 23 10:52:57 2023 Page 2
REPORT ID: 23E133 Page 146 of 345
81
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Aeq On 23 May 2023 8:41 am
Sample CV006E1506
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1, 3, 5-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.856
T,M 4-Chlorotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M l,2,4-Trimethylbenzene 3.824
T,M see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
T,M 1,3-Diehlorobenzene 1.955
T,M l,2,3-Trimethylbenzene 3.471
T,M l,4-Diehlorobenzene 1. 960
T,M n-Butylbenzene 3.978
T,M l,2-Diehlorobenzene 1. 630
T,M l,2-Dibromo-3-ehloropropane 0.105
T,M l,2,4-Triehlorobenzene 1.069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1. 562
T,M l,2,3-Triehlorobenzene 0.822
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
4.070 -5.1 119 0.01
3.994 -3.6 114 0.01
3.605 -18.3 134 0.01
0.949 -2.2 115 0.00
4.002 -4.7 120 0.01
5.667 -5.3 119 0.01
4.577 -9.0 123 0.01
2.157 -10.3 123 0.01
3.764 -8.4 123 0.01
2.146 -9.5 121 0.01
4.476 -12.5 127 0.01
1. 786 -9.6 121 0.01
0.092 12.4 103 0.00
1.121 -4.9 119 0.01
0.757 -15.0 126 0.01
1. 585 -1. 5 112 0.01
0.857 -4.3 115 0.01
(#) = Out of Range
REW408.D V006E15.M
SPCC's out = 0 CCC's out = 0
Tue May 23 10:52:58 2023 Page 3
REPORT ID: 23E133 Page 147 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Acq On 23 May 2023 8:41 am
Sample CV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 9:05 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
10.10
15.55
19.43
8.12
9.23
12.93
17.56
1. 70
1. 93
2.05
2.53
2.63
2.66
2.90
3.40
3.49
3.51
3.65
3.82
4.20
4.10
4.41
4.39
4.66
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
114
117
152
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
4453053 -j
3822117/
1439501
10.00 ug/l
10.00 ug/l
10.00 ug/l
1399491 9.73
Recovery =
958069 9.58
Recovery =
5089811 10.25
Recovery =
1660851 10.19
Recovery =
ug/l
97.30%
ug/l
95.80%
ug/l
102.50%
ug/l
101. 90%
0.01
0.01
0.01
0.02
0.01
0.01
0.01
1991013
2018818
1796804
1456739
1123281
2848180
2145785
11.18 ug/l
10.23 ug/l
9.36 ug/l
9.22 ug/l
9.70 ug/l
Qvalue
97
529074
1205699
783662
2603009
1148211
112057
2755364
1858921
5856024
1047319
2311498
1785363
4645062
1449946
2855868
3742763
1329005
1653663
1750076
2696374
10.81 ug/l
9.40 ug/l
47.14 ug/l
9.76 ug/l
46.76 ug/l
10.60 ug/l
230.35 ug/l
9.31 ug/l
10.24 ug/l
10.66 ug/l
10.00 ug/l
51.84 ug/l
9.61 ug/l
10.58 ug/l
10.56 ug/l
10.66 ug/l
10.40 ug/l
10.29 ug/l
49.90 ug/l
11.17 ug/l
10.51 ug/l
10.04 ug/l
100
96
99
99
100
99
98
99
97
98
100
96
99
94
100
98
100
100
98
99
99
96
97
99
100
100
(#) = qualifier out of range (m) = manual integration
REW40S.D V006E15.M Tue May 23 10:53:07 2023 Page 1
REPORT ID: 23E133 Page 148 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Aeq On 23 May 2023 8:41 am
Sample CV006E1506
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 9:05 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAeq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.97
8.10
8.51
8.49
8.86
9.03
9.21
9.44
9.41
10.68
10.76
11. 03
11.58
11.47
11.55
12.17
12.21
12.53
13.07
13.50
13.45
13.71
13.78
14.15
14.20
14.55
14.89
15.24
15.61
15.71
15.72
15.85
16.58
16.64
17.19
17.19
17.46
17.67
17.77
17.77
17.82
130 842668
42 141092
97 2132124
84 2532262
110 806069
119 1777172
73 2700427
62 1294764
78 6308030
130 1713790
83 2740472
63 1475488
88 106620
83 1836727
93 705615
63 147951
43 3338803
75 2260606
91 6713523
69 1088233
75 1614295
97 839172
43 2200227
76 1612564
164 1434650
129 1090412
107 855237
91 2835448
112 4283168
131 1329546
91 7805085
91 11535346
91 5579415
104 4356069
105 7321174
173 496958
83 935213
110 234227
53 214351
91 9286211
156 1536717
(#) = qualifier out of range (m) = manual integration
9.90 ug/l
9.42 ug/l
9.55 ug/l
10.88 ug/l
10.96 ug/l
10.13 ug/l
9.41 ug/l
10.36 ug/l
10.45 ug/l
10.60 ug/l
10.97 ug/l
10.51 ug/l
175.54 ug/l
9.79 ug/l
9.79 ug/l
12.26 ug/l
51.97 ug/l
10.21 ug/l
10.76 ug/l
9.79 ug/l
9.98 ug/l
9.37 ug/l
49.33 ug/l
10.07 ug/l
10.49 ug/l
9.63 ug/l
9.77 ug/l
10.83 ug/l
10.67 ug/l
9.52 ug/l
10.36 ug/l
20.97 ug/l
9.94 ug/l
10.20 ug/l
10.18 ug/l
9.40 ug/l
9.85 ug/l
9.63 ug/l
8.67 ug/l
10.78 ug/l
10.32 ug/l
Qvalue
99
94
99
95
98
99
99
99
99
99
97
96
97
100
98
92
97
98
100
97
98
98
100
98
99
99
98
100
100
100
98
98
98
99
100
99
98
98
93
99
100
REW408.D V006E15.M Tue May 23 10:53:07 2023 Page 2
REPORT ID: 23E133 Page 149 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Aeq On 23 May 2023 8:41 am
Sample CV006E1506
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 23 9:05 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81) l,3,5-Trimethylbenzene 17.99 105 5859408 10.51 ug/l 100
82) 2-Chlorotoluene 18.00 91 5748940 10.36 ug/l 92
83) 4-Chlorotoluene 18.07 91 5189777 11.83 ug/l 96
84) tert-Butylbenzene 18.43 134 1366799 10.22 ug/l 96
85) l,2,4-Trimethylbenzene 18.48 105 5760782 10.47 ug/l 99
86) see-Butylbenzene 18.69 105 8157828 10.53 ug/l 100
87) p-Isopropyltoluene 18.85 119 6589001 10.90 ug/l 100
88) l,3-Diehlorobenzene 18.95 146 3105499 11.04 ug/l 99
89) l,2,3-Trimethylbenzene 19.03 105 5417755 10.84 ug/l 99
90 ) l,4-Diehlorobenzene 19.07 146 3088767 10.95 ug/l 100
91 ) n-Butylbenzene 19.29 91 6443057 11. 25 ug/l 99
92) l,2-Diehlorobenzene 19.46 146 2570580 10.96 ug/l 99
93) l,2-Dibromo-3-ehloropropan 20.22 157 132902 8.76 ug/l 95
94) l,2,4-Triehlorobenzene 21.07 180 1613781 10.48 ug/l 99
95) Hexaehlorobutadiene 21.20 225 1089211 11.49 ug/l 99
96) Naphthalene 21.34 128 2281018 10.15 ug/l 99
97 ) 1, 2, 3-Triehlorobenzene 21.59 180 1233083 10.42 ug/l 100
(#) = qualifier out of range (m) = manual integration
REW408.D V006E15.M Tue May 23 10:53:08 2023 Page 3
REPORT ID: 23E133 Page 150 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW408.D
Aeq On 23 May 2023 8:41 am
Sample CV006E1506
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Quant Time: May 23 9:05 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
l!\burldance
1 1,35e+071'
, 1,3e+07
i j , I ! 1.25e+07,
1 1.2e+071
I I
1 1,15e+071
, I
1,1e+071
I
105e+071
I
1e+071
i
95000001
i
9000000<1'
8500000
i
80000001
75000001 ,
7000000! !
!
i
i 6500000!
60000001
5500000j
!
5000000i
i 4500000~ I
40000001
35000001
3000000
2500000
2000000
1500000
1000000
[ime--> 2.00
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
(RTE Integrator)
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW408,O
4.00 6.00 10,00 12,00 14.00 16.00 18.00
, ~-j..:
I
:;<
'"' of c
1l.
fi e .Q .c
1
E e
.0
~"
1
20.00
REW408.D V006E15.M Tue May 23 10:53:10 2023
:;<
'"' '""-~ = Ii ~~ ~~ ..-(l)~
I.Q
:;<{i
~i~
c<'> ~C'{ IE~
I£.
~
Page 4
REPORT ID: 23E133 Page 151 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Acq On 23 May 2023 7:04 pm
Sample EV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50%VJMax. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M l,l,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M l,l-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-l,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M 1,1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1,2-Dichloroethane-d4
Amount Calc.
10.000 10.000
10.000 11.103
10.000 12.130
10.000 10.465
10.000 10.848
10.000 10.794
10.000 10.919
10.000 10.327
50.000 53.520
10.000 9.025
50.000 60.086
10.000 10.862
250.000 277.215
-1.000 0.000
10.000 10.419
10.000 9.813
10.000 11.599
10. 000 11. 349
50.000 62.458
10. 000 11. 028
10.000 11.131
10.000 11.798
10.000 11.685
10.000 11.401
250.000 0.000
10. 000 11. 625
50.000 61.830
10.000 10.358
10.000 11.302
10.000 11.213
50.000 0.000
10.000 11.101
10.000 10.576
10.000 10.414
10.000 9.653
10.000 8.911
10.000 0.000
10.000 10.556
10.000 10.280
10.000 10.566
10.000 10.132
(#) = Out of Range
REW432.D V006E15.M Wed May 24 09:07:34 2023
%Dev Area% Dev(min)
0.0 94
-11.0 107
-21. 3# 112
-4.6 97
-8.5 101
-7.9 101
-9.2 113
-3.3 100
-7.0 117
9.7 98
-20.2# 132
-8.6 112
-10.9 115
0.0 a
-4.2 117
1. 9 103
-16.0 125
-13.5 111
-24.9# 129
-10.3 110
-11. 3 116
-18.0 123
-16.9 114
-14.0 120
100.0# a
-16.3 122
-23.7# 134
-3.6 103
-13.0 117
-12.1 118
100.0# 0
-11. a 117
-5.8 117
-4.1 102
3.5 107
10.9 93
100.0# 0
-5.6 110
-2.8 111
-5.7 109
-1.3 98
0.01
0.02
0.02
0.00
0.02
0.02
0.02
0.02
0.00
0.04
0.02
0.00
0.02
0.00
0.02
-0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.03
0.02
0.02
0.02
0.03
0.03
0.03
0.01
0.01
0.01
0.01
Page 1
REPORT ID: 23E133 Page 152 of 345
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Acq On 23 May 2023 7:04 pm
Sample EV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M l,2-Dichloroethane 10.000 11.161 -11.6 115 0.03
TIM Benzene 10.000 11. 2 05 -12.1 116 0.01
TIM Trichloroethene 10.000 10.853 -8.5 113 0.01
T(M Methylcyclohexane 10.000 10.723 -7.2 114 0.01
C/T,M l,2-Dichloropropane 10.000 11.681 -16.8 123 0.03
TIM l,4-Dioxane 200.000 208.302 -4.2 119 0.01
TIM Bromodichloromethane 10.000 10.803 -8.0 116 0.01
TIM Dibromomethane 10.000 10.936 -9.4 113 0.01
TIM 2-Chloroethyl vinyl ether 10.000 7.831 21. 7# 79 0.01
T,M 4-Methyl-2-pentanone 50.000 63.377 -26.8# 130 0.01
TIM cis-1 /3-Dichloropropene 10.000 11. 210 -12.1 115 0.01
I CHLOROBENZENE-D5 10.000 10.000 0.0 93 0.01
S Toluene-d8 10.000 10.160 -1. 6 97 0.01
C/T,M Toluene 10.000 11.428 -14.3 117 0.03
TIM Ethyl methacrylate 10.000 11.105 -11.1 115 0.01
TIM trans-1,3-Dichloropropene 10.000 10.930 -9.3 112 0.01
T,M l,l(2-Trichloroethane 10.000 11.011 -10.1 118 0.01
TIM 2-Hexanone 50.000 59.935 -19.9 130 0.01
TIM 1(3-Dichloropropane 10.000 11. 489 -14.9 117 0.01
TIM Tetrachloroethene 10.000 10.955 -9.6 112 0.01
TIM Dibromochloromethane 10.000 10.974 -9.7 114 0.01
T(M 2-Ethyl-1-butanol -1.000 0.000 0.0 a 0.00
T,M l,2-Dibromoethane 10.000 11.277 -12.8 116 0.03
TIM 1-Chlorohexane 10.000 10.963 -9.6 111 0.01
PI TIM Chlorobenzene 10.000 11.543 -15.4 118 0.01
TIM l,l(l,2-Tetrachloroethane 10.000 11. 099 -11. a 116 0.01
C/T/M Ethylbenzene 10.000 11.127 -11.3 117 0.01
TIM m-Xylene & p-Xylene 20.000 22.820 -14.1 116 0.01
TIM o-Xylene 10.000 11. 317 -13.2 118 0.01
TIM Styrene 10.000 11.129 -11. 3 115 0.03
TIM Isopropylbenzene 10.000 11. 035 -10.4 116 0.01
I 1 /2-DICHLOROBENZENE-D4 10.000 10.000 0.0 95 0.01
P,T/M Bromoform 10.000 10.406 -4.1 111 0.01
P/T,M l,l(2(2-Tetrachloroethane 10.000 11.839 -18.4 124 0.01
S 4-Bromofluorobenzene 10.000 10.126 -1. 3 99 0.01
TIM 1(2,3-Trichloropropane 10.000 10.897 -9.0 116 0.00
TIM trans-1,4-Dichloro-2-butene 10.000 10.411 -4.1 113 0.01
TIM n-Propylbenzene 10.000 11.130 -11.3 116 0.00
TIM Bromobenzene 10.000 11.143 -11. 4 119 0.01
(#) = Out of Range
REW432.D V006E15.M Wed May 24 09:07:35 2023 Page 2
REPORT ID: 23E133 Page 153 of 345
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Acq On 23 May 2023 7:04 pm
Sample EV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 1, 3, 5-Trimethylbenzene 10.000 10.913 -9.1 117 0.01
T,M 2-Chlorotoluene 10.000 11. 435 -14.4 119 0.01
T,M 4-Chlorotoluene 10.000 10.868 -8.7 116 0.01
T,M tert-Butylbenzene 10.000 11.022 -10.2 117 0.01
T,M l,2,4-Trimethylbenzene 10.000 10.891 -8.9 118 0.01
T,M sec-Butylbenzene 10.000 11. 031 -10.3 117 0.01
T,M p-Isopropyltoluene 10.000 10.856 -8.6 115 0.01
T,M 1 ,3-Dichlorobenzene 10.000 11. 320 -13.2 119 0.01
T,M 1 ,2,3-Trimethylbenzene 10.000 10.961 -9.6 117 0.01
T,M l,4-Dichlorobenzene 10.000 11.114 -11.1 116 0.01
T,M n-Butylbenzene 10.000 10.868 -8.7 116 0.01
T,M l,2-Dichlorobenzene 10.000 11. 254 -12.5 118 0.01
T,M l,2-Dibromo-3-chloropropane 10.000 10.129 -1. 3 112 0.01
T,M l,2 ,4-Trichlorobenzene 10.000 10.563 -5.6 113 0.01
T,M Hexachlorobutadiene 10.000 10.708 -7.1 110 0.01
T,M Naphthalene 10.000 10.699 -7.0 112 0.01
T,M 1, 2, 3-Trichlorobenzene 10.000 10.628 -6.3 111 0.01
(#) = Out of Range
REW432.D V006E15.M
SPCC's out = a CCC's out = a
Wed May 24 09:07:35 2023 Page 3
REPORT ID: 23E133 Page 154 of 345
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Acq On 23 May 2023 7:04 pm
Sample EV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
I l,4-DIFLUOROBENZENE 1.000
T,M Dichlorodifluoromethane 0.400
P,T,M Chloromethane 0.443
C,T,M Vinyl chloride 0.431
T,M Bromomethane 0.355
T,M Chloroethane 0.260
T,M Dichlorofluoromethane 0.592
T,M Trichlorofluoromethane 0.513
T,M Acrolein 0.025
T,M 1,1,2-Trichloro-1,2,2-trifl 0.277
T,M Acetone 0.040
C,T,M 1,1-Dichloroethene 0.551
T,M tert-Butyl alcohol 0.011
T,M Acetonitrile 0.000
T,M Methyl acetate 0.027
T,M Iodomethane 0.604
T,M Methylene chloride 0.392
T,M Carbon disulfide 1.315
T,M Acrylonitrile 0.045
T,M tert-Butyl methyl ether (MT 0.540
T,M trans-1,2-Dichloroethene 0.379
T,M Isopropyl ether (DIPE) 0.988
T,M Vinyl acetate 0.305
P,T,M l,l-Dichloroethane 0.617
T,M 2-Butanol 0.000
T,M tert-Butyl ethyl ether (ETB 0.817
T,M 2-Butanone 0.060
T,M 2,2-Dichloropropane 0.333
T,M cis-1,2-Dichloroethene 0.374
C,T,M Chloroform 0.603
T,M tert-Amyl alcohol 0.000
T,M Bromochloromethane 0.191
T,M Tetrahydrofuran 0.034
S Dibromofluoromethane 0.323
T,M l,l,l-Trichloroethane 0.501
T,M Cyclohexane 0.523
T,M 2,2,4-Trimethylpentane 0.000
T,M l,l-Dichloropropene 0.165
T,M Carbon tetrachloride 0.394
T,M tert-Amyl methyl ether (TAM 0.644
S 1,2-Dichloroethane-d4 0.225
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
1.000 0.0 94 0.01
0.444 -11. 0 107 0.02
0.537 -21.2# 112 0.02
0.451 -4.6 97 0.00
0.385 -8.5 101 0.02
0.281 -8.1 101 0.02
0.646 -9.1 113 0.02
0.530 -3.3 100 0.02
0.027 -8.0 117 0.00
0.250 9.7 98 0.04
0.045 -12.5 132 0.02
0.599 -8.7 112 0.00
0.012 -9.1 115 0.02
0.000 0.0 0# 0.00
0.028 -3.7 117 0.02
0.593 1.8 103 -0.02
0.454 -15.8 125 0.02
1. 493 -13.5 111 0.02
0.057 -26.7# 129 0.02
0.596 -10.4 110 0.02
0.422 -11.3 116 0.02
1.165 -17.9 123 0.02
0.357 -17.0 114 0.02
0.703 -13.9 120 0.02
0.011 0.0 0# 0.02
0.950 -16.3 122 0.02
0.074 -23.3# 134 0.02
0.344 -3.3 103 0.02
0.423 -13.1 117 0.02
0.676 -12.1 118 0.02
0.001 0.0 0# 0.03
0.212 -11.0 117 0.02
0.036 -5.9 117 0.02
0.336 -4.0 102 0.02
0.484 3.4 107 0.03
0.466 10.9 93 0.03
0.022 0.0 0# 0.03
0.174 -5.5 110 0.01
0.405 -2.8 111 0.01
0.681 -5.7 109 0.01
0.228 -1. 3 98 0.01
(#) = Out of Range
REW432.D V006E15.M Wed May 24 09:07:40 2023 Page 1
REPORT ID: 23E133 Page 155 of 345
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
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60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Acq On 23 May 2023 7:04 pm
Sample EV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M l,2-Dichloroethane 0.281
T,M Benzene 1.355
T,M Trichloroethene 0.363
T,M Methylcyclohexane 0.561
C,T,M l,2-Dichloropropane 0.315
T,M l,4-Dioxane 0.001
T,M Bromodichloromethane 0.421
T,M Dibromomethane 0.162
T,M 2-Chloroethyl vinyl ether 0.027
T,M 4-Methyl-2-pentanone 0.144
T,M cis-1,3-Dichloropropene 0.497
I CHLOROBENZENE-D5 1.000
S Toluene-d8 1.299
C,T,M Toluene 1. 633
T,M Ethyl methacrylate 0.291
T,M trans-1,3-Dichloropropene 0.423
T,M l,l,2-Trichloroethane 0.234
T,M 2-Hexanone 0.117
T,M l,3-Dichloropropane 0.419
T,M Tetrachloroethene 0.358
T,M Dibromochloromethane 0.296
T,M 2-Ethyl-1-butanol 0.000
T,M l,2-Dibromoethane 0.229
T,M 1-Chlorohexane 0.685
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
0.313 -11. 4 115 0.03
1. 518 -12.0 116 0.01
0.394 -8.5 113 0.01
0.601 -7.1 114 0.01
0.368 -16.8 123 0.03
0.001 0.0 119 0.01
0.455 -8.1 116 0.01
0.177 -9.3 113 0.01
0.021 22.2# 79 0.01
0.183 -27.1# 130 0.01
0.557 -12.1 115 0.01
1. 000 0.0 93 0.01
1.319 -1. 5 97 0.01
1.866 -14.3 117 0.03
0.323 -11. 0 115 0.01
0.463 -9.5 112 0.01
0.258 -10.3 118 0.01
0.140 -19.7 130 0.01
0.481 -14.8 117 0.01
0.392 -9.5 112 0.01
0.325 -9.8 114 0.01
0.000 0.0 0# 0.00
0.258 -12.7 116 0.03
0.751 -9.6 111 0.01
P, T,M Chlorobenzene 1. 050 1.212 -15.4 118 0.01
T,M 1, 1, 1, 2-Tetrachloroethane 0.365 0.406 -11.2 116 0.01
C,T,M Ethylbenzene 1.971 2.193 -11. 3 117 0.01
T,M m-Xylene & p-Xylene 1.439 1.642 -14.1 116 0.01
T,M o-Xylene 1.469 1.663 -13.2 118 0.01
T,M Styrene 1.117 1. 243 -11. 3 115 0.03
T,M Isopropylbenzene 1.882 2.076 -10.3 116 0.01
I l,2-DICHLOROBENZENE-D4 1.000 1.000 0.0 95 0.01
P,T,M Bromoform 0.367 0.382 -4.1 111 0.01
P,T,M 1, 1, 2, 2-Tetrachloroethane 0.660 0.781 -18.3 124 0.01
S 4-Bromofluorobenzene 1.132 1.146 -1. 2 99 0.01
T,M 1, 2, 3-Trichloropropane 0.169 0.184 -8.9 116 0.00
T,M trans-1,4-Dichloro-2-butene 0.172 0.179 -4.1 113 0.01
T,M n-Propylbenzene 5.985 6.662 -11. 3 116 0.00
T,M Bromobenzene 1.034 1.152 -11. 4 119 0.01
(#) = Out of Range
REW432.D V006E15.M Wed May 24 09:07:42 2023 Page 2
REPORT ID: 23E133 Page 156 of 345
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Aeq On 23 May 2023 7:04 pm
Sample EV006E1506
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1, 3, 5-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.856
T,M 4-Chlorotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M 1,2,4-Trimethylbenzene 3.824
T,M see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
T,M l,3-Diehlorobenzene 1.955
T,M 1, 2, 3-Trimethylbenzene 3.471
T,M 1,4-Diehlorobenzene 1.960
T,M n-Butylbenzene 3.978
T,M 1,2-Diehlorobenzene 1. 630
T,M l,2-Dibromo-3-ehloropropane 0.105
T,M 1,2,4-Triehlorobenzene 1. 069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1.562
T,M 1, 2, 3-Triehlorobenzene 0.822
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
4.226 -9.1 117 0.01
4.410 -14.4 119 0.01
3.313 -8.7 116 0.01
1.024 -10.2 117 0.01
4.165 -8.9 118 0.01
5.935 -10.3 117 0.01
4.560 -8.5 115 0.01
2.213 -13.2 119 0.01
3.805 -9.6 117 0.01
2.178 -11.1 116 0.01
4.323 -8.7 116 0.01
1. 834 -12.5 118 0.01
0.107 -1. 9 112 0.01
1.130 -5.7 113 0.01
0.705 -7.1 110 0.01
1.671 -7.0 112 0.01
0.874 -6.3 111 0.01
(#) = Out of Range
REW432.D V006E15.M
SPCC's out = 0 CCC's out = 0
Wed May 24 09:07:43 2023 Page 3
REPORT ID: 23E133 Page 157 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW432.D Vial: 26
Operator: LYamas Acq On 23 May 2023 7:04 pm
Sample EV006E1506 Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 8:59 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1 r 2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) 1 r 1-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.10 114 394566
15.55 117 345632
19.43 152 1357453
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
8.12
9.23
12.93
17.56
1. 71
1. 95
2.05
2.52
2.62
2.66
2.90
3.40
3.49
3.51
3.66
3.82
4.20
4.10
4.41
4.39
4.66
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
1327043 10.41 0.02
Recovery =
ug/l
104.10%
ug/l
101.30%
ug/l
101. 60%
ug/l
101.30%
897933 10.13
Recovery
4559913 10.16
Recovery =
1555921 10.13
Recovery
1751756
2120307
1779789
1519011
1107693
2549754
2089653
532273
987654
881469
2362858
1224390
111062
2339711
1792146
5888991
1118020
2350882
1663822
4597092
1408200
2773578
3747132
1458993
1358970
1668231
2668741
11.10 ug/l
12.13 ug/l
10.46 ug/l
10.85 ug/l
10.79 ug/l
10.92 ug/l
10.33 ug/l
53.52 ug/l
9.02 ug/l
60.09 ug/l
10.86 ug/l
277.22 ug/l
10.42 ug/l
9.81 ug/l
11.60 ug/l
11.35 ug/l
62.46 ug/l
11.03 ug/l
11.13 ug/l
11.80 ug/l
11.69 ug/l
11.40 ug/l
11.63 ug/l
61.83 ug/l
10.36 ug/l
11.30 ug/l
11.21 ug/l
0.01
0.01
0.01
Qvalue
97
99
99
99
98
99
99
99
99
97
97
99
97
99
94
100
99
100
99
98
99
99
96
96
99
99
99
(#) = qualifier out of range (m) = manual integration
REW432.D V006E15.M Wed May 24 09:07:52 2023 Page 1
REPORT ID: 23E133 Page 158 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Acq On 23 May 2023 7:04 pm
Sample EV006E1506
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 8:59 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.97
8.10
8.52
8.50
8.87
9.03
9.22
9.44
9.41
10.68
10.76
11. 05
11.59
11.47
11.55
12.16
12.21
12.53
13.07
13.50
13.45
13.71
13.79
14.15
14.20
14.55
14.90
15.24
15.62
15.71
15.72
15.85
16.58
16.65
17.19
17.19
17.46
17.67
17.78
17.77
17.82
130 837354
42 140402
97 1909221
84 1837976
110 687900
119 1598193
73 2686065
62 1235748
78 5990997
130 1554974
83 2372652
63 1452995
88 112100
83 1796043
93 698655
63 83721
43 3607455
75 2198605
91 6448671
69 1116027
75 1598598
97 891280
43 2417211
76 1663262
164 1355116
129 1123856
107 893108
91 2594896
112 4189932
131 1402097
91 7581278
91 11353170
91 5746201
104 4297601
105 7176486
173 518716
83 1060480
110 250033
53 242606
91 9043358
156 1564038
(#) = qualifier out of range (m) = manual integration
11.10 ug/l
10.58 ug/l
9.65 ug/l
8.91 ug/l
10.56 ug/l
10.28 ug/l
10.57 ug/l
11.16 ug/l
11.20 ug/l
10.85 ug/l
10.72 ug/l
11. 68 ug/l
208.30 ug/l
10.80 ug/l
10.94 ug/l
7.83 ug/l
63.38 ug/l
11.21 ug/l
11. 43 ug/l
11.11 ug/l
10.93 ug/l
11.01 ug/l
59.94 ug/l
11.49 ug/l
10.95 ug/l
10.97 ug/l
11. 28 ug/l
10.96 ug/l
11.54 ug/l
11.10 ug/l
11.13 ug/l
22.82 ug/l
11.32 ug/l
11.13 ug/l
11.04 ug/l
10.41 ug/l
11.84 ug/l
10.90 ug/l
10.41 ug/l
11.13 ug/l
11. 14 ug/l
Qvalue
99
98
98
99
99
99
100
99
100
99
97
96
100
97
99
91
99
98
100
99
100
97
99
99
99
99
99
99
99
99
99
99
98
99
100
99
99
97
93
100
100
REW432.D V006E15.M Wed May 24 09:07:53 2023 Page 2
REPORT ID: 23E133 Page 159 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Aeq On 23 May 2023 7:04 pm
Sample EV006E1506
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 8:59 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. Qlon Response Cone Unit Qvalue
81 ) 1,3,5-Trimethylbenzene 17.99 105 5735997 10.91 ug/l 99
82) 2-Chlorotoluene 18.00 91 5986209 11.44 ug/l 98
83) 4-Chlorotoluene 18.07 91 4496959 10.87 ug/l 97
84) tert-Butylbenzene 18.45 134 1390427 11.02 ug/l 97
85) 1,2,4-Trimethylbenzene 18.48 105 5653421 10.89 ug/l 99
86 ) see-Butylbenzene 18.69 105 8057049 11.03 ug/l 100
87 ) p-Isopropyltoluene 18.85 119 6190349 10.86 ug/l 100
88) 1,3-Diehlorobenzene 18.95 146 3004207 11.32 ug/l 98
89) 1,2,3-Trimethylbenzene 19.03 105 5164817 10.96 ug/l 100
90) 1,4-Diehlorobenzene 19.07 146 2957074 11.11 ug/l 100
91) n-Butylbenzene 19.29 91 5868910 10.87 ug/l 100
92) 1,2-Diehlorobenzene 19.46 146 2490140 1l. 25 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.24 157 144891 10.13 ug/l 91
94) l,2,4-Triehlorobenzene 21.07 180 1533517 10.56 ug/l 99
95) Hexaehlorobutadiene 21.20 225 956954 10.71 ug/l 99
96) Naphthalene 21.34 128 2268396 10.70 ug/l 99
97) 1,2,3-Triehlorobenzene 21.59 180 1185838 10.63 ug/l 100
(#) = qualifier out of range (m) = manual integration
REW432.D V006E15.M Wed May 24 09:07:53 2023 Page 3
REPORT ID: 23E133 Page 160 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E23\REW432.D
Aeq On 23 May 2023 7:04 pm
Sample EV006E1506
Mise 10ppb 8260/50ppb KET AA/250ppb TEA
Vial:
Operator:
Inst
Multiplr:
26
LYamas
06
1. 00
MS Integration Params: RTE.P
Quant Time: May 24 8:59 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
... Response via
/\bundance
1.25e+07i ,
12e+oi
j
1.'15e+071
! : 1,1 e+07i
I
1.05e+01'
1 e+071
9500000:
9000eoo
85000001
80000001
1
7500000:
70000001
6500000:
60000001
55000001
5000000j
45000001
4000000:
3500000i
3000000'1:
2500000
20000001
1500000
10000001
5000001
I
'Time-->
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW432.D
REW432.D V006E15.M Wed May 24 09:07:56 2023 Page 4
REPORT ID: 23E133 Page 161 of 345
1
2
3
4
5
6
7
8
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratories, Inc.
Lab Code : EMAX
Project : TEAD-S
SDG No : 23E133
BFB Injection Date: OS/24/23
BFB Injection Time: 07:04
Lab File ID: REW433
Instrument ID: 06
ION ABUNDANCE CRITERIA
~ RELATIVE
ABUNDANCE m/e
50
75
95
96
~g = ~~~ ~~ ~~~~ ~~--------------------16.894
42.448
100.000
6.263
0.000(0)1
77.310
5.952(7.7)1
74.627(96.53)1
4.825(6.47)2
173
174
175
176
177
Base Peak, 100% relatlve abundance
~e~s9~h~; ~~s~f9~~a~s~s-'1~7-4---------------
~r=a~;.ro~h~~s~0~7~~ mass 95 __________ __
~5--9~0~%O~ ~~S~ai~6l·/4.----------------
~ue 18 % mass 174 2 value 18 % mass 176
This check applies to the following samples, Lab QCs and Standards:
EPA LAB LAB DATE
SAMPLE NO. SAMPLE ID FILE ID ANALYZED
========================== ================ ============ ==========
VSTD10 CV006E1507 REW434 OS/24/23
LCS2W V006E20L REW435 OS/24/23
LCD2W V006E20C REW436 OS/24/23
MBLK2W V006E20B REW438 OS/24/23
S13-CAM-DW1-052023 23E133-05 REW442 OS/24/23
S13-CAM-DW1-052023MS 23E133-05M REW447 OS/24/23
S13-CAM-DW1-052023MSD 23E133-05S REW448 OS/24/23
VSTD10 EV006E1507 REW458 OS/24/23
TIME
ANALYZED
==========
07 30
07 57
08 23
09 15
10 59
13 09
13 35
17 56
REPORT ID: 23E133 Page 162 of 345
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name: EMAX Laboratories, Inc.
Lab Code: EMAX
Lab File ID: REW253
Instrument ID: 06
INTERNAL STANDARD lIS) 1,4-DIFLUOROBENZENE
Area # RT #
1
2
3
4
5
6
7
8
12 HOUR STD
UPPER LIMIT
LOWER LIMIT
4201521
8403042
2100761
Area #
10.08
10.25
9.913
RT #
======================== =============== ==============
VSTD10 4442688
LCS2W 4400175
LCD2W 4521999
MBLK2W 5049583
S13-CAM-DW1-052023 4940168
S13-CAM-DW1-052023MS 5086518
S13-CAM-DW1-052023MSD 4998432
VSTD10 4894707
Area Upper Limit = +100% of ICAL Midpoint IS Area
Area Lower Limit = -50% of ICAL Midpoint IS Area
10.10
10.10
10.10
10.10
10.10
10.10
10.10
10.11
3710147
7420294
1855074
Area #
===============
3753055
3703345
3849030
4221155
4302652
4529672
4460938
4277559
Retention Time (RT) Upper Limit +10 seconds of ICAL Midpoint IS RT
Retention Time (RT) Lower Limit = -10 seconds of ICAL Midpoint IS RT
#
15.54
15.71
15.37
RT #
=======:::======
15.55
15.55
15.55
15.55
15.55
15.55
15.55
15.56
Project: TEAD-S
SDG No: 23E133
Date Analyzed: 05/15/23
Time Analyzed: 15:57
1,2~DICHLClROBENZENE-D4
Area # RT #
1432830
2865660
716415
Area #
===============
1477331
1447023
1509437
1588869
1671023
1828508
1828365
1683719
19.42
19.59
19.25
RT #
==============
19.43
19.43
19.43
19.43
19.43
19.43
19.43
19.43
REPORT ID: 23E133 Page 163 of 345
BFB
Data File D:\HPCHEM\1\DATA\23E24\REW433.D
Acq On 24 May 2023 7:04 am
Sample BFB06E20
Misc T/CHK
MS Integration Params: RTE.P
Vial: 1
Operator: LYamas
06
1.00
Inst
Multiplr:
Method D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
Title : METHOD 8260
rbundance
I
500000
TIC: REW433.D
!\
400000
300000
200000
100000
ime-> 16.00 16.50 17.00 17.50 18.00 18.50 19.00
ft\bundance
I 100000 I
!
soooo
600001
40000
I
50
Average of 17.550 to 17.576 min.: REW433.D (-)
95
75
174
II 20000 69
~~, 44 .dl 61t If .I J S1~IS iJ i 104 117 141 li ~/Z--> 0L,,30"""~40-rl-'Hi50.J.,--.,-..J.l-ri60Jfl-r.,...-t.t,70~4--t'180h-r-r4--,9IrlO !.f1+-"1 OnO'T-i-"11rrO-n-:1n2rTO"'-"13rrO--'-'--1"4c'-r0'-r-r-1"5"'0""'-1"S'"0"""-1"+"'0-tJ+L1"S"0"'-
AutoFind: Scans 1113, 1114, 1115; Background Corrected with Scan 1107
I Target I ReI. to I L~w7r
Mass Mass L1m1t%
50
75
95
96
173
174
175
176
177
95
95
95
95
174
95
174
174
176
15
30
100
5
0.00
50
5
95
5
I Upper I
Limit%
40
60
100
9
2
100
9
101
9
ReI.
Abn%
16.9 ....
42.4
100. cY
6.3
0.0""""
77.3
7.7
96.5
6.5
REW433.D V006E15.M Wed May 24 09:49:07 2023
Raw
Abn
18643
46843
110355
6911
o
85315
6568
82355
5325
I Result I
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 23E133 Page 164 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Acq On 24 May 2023 7:30 am
Sample CV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
(RTE Integrator)
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M l,l,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M l,l-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
Amount Calc.
10.000 10.000
10.000 10.697
10.000 10.112
10. 000 8.839../1
10.000 8.947
10.000 8.791
10.000 10.408
10.000 9.176
50.000 45.072
10.000 9.019
50.000 46.855
10.000 10.147
250.000 236.881 ~
-1.000 0.000
10.000 9.285
10.000 9.640
10.000 10.254
10.000 9.463
50.000 50.855
10.000 9.641
10.000 10.095
10.000 10.375
10.000 10.577
10.000 10.133
250.000 0.000
10.000 10.192
50.000 48.818
10.000 10.923
10.000 10.170 /
10.000 9.879
50.000 0.000
10.000 9.736
10.000 8.737
10.000 9.900
10.000 9.108
10.000 10.678
10.000 0.000
10.000 10.517
10.000 9.926
10.000 9.205
10.000 9.657
(#) = Out of Range
REW434.D V006E15.M Wed May 24 09:49:24 2023
%Dev Area% Dev(min)
0.0
-7.0
-1.1
11. 6
10.5
12.1
-4.1
8.2
9.9
9.8
6.3
-1. 5
5.2
0.0
7.1
3.6
-2.5
5.4
-1.7
3.6
-1. a
-3.8
-5.8
-1. 3
100.0#
-1. 9
2.4
-9.2
-1.7
l.2
100.0#
2.6
12.6
1.0
8.9
-6.8
100.0#
-5.2
0.7
7.9
3.4
106
116
105
92
93
93
121
100
111
110
117
118
111
o
118
114
125
104
118
109
118
122
116
120
o
120
119
123
119
118
o
115
109
109
114
126
o
124
120
107
105
0.01
0.02
0.02
0.00
0.02
0.02
0.02
0.00
0.00
0.04
0.02
0.00
0.02
0.00
0.02
-0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.04
0.02
0.02
0.02
0.03
0.01
0.01
0.01
0.01
0.01
0.01
Page 1
REPORT ID: 23E133 Page 165 of 345
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61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
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80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Acq On 24 May 2023 7:30 am
Sample CV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 1 /2-Dichloroethane 10.000 9.965 0.4 116 0.03
T,M Benzene 10.000 10.137 -1. 4 118 0.01
T,M Trichloroethene 10.000 10.395 -3.9 122 0.01
T,M Methylcyclohexane 10.000 11. 095 -11. 0 133 0.01
C/T,M l,2-Dichloropropane 10.000 10.327 /' -3.3 123 0.01
T,M 1/4-Dioxane 200.000 191.066 4.5 123 0.00
T,M Bromodichloromethane 10.000 9.775 2.2 119 0.01
T,M D ibromome thane 10.000 9.641 3.6 113 0.01
T,M 2-Chloroethyl vinyl ether 10.000 11. 748 -17.5 133 0.01
T,M 4-Methyl-2-pentanone 50.000 51. 417 -2.8 118 0.01
T,M cis-1 /3-Dichloropropene 10.000 10.064 -0.6 116 0.01
I CHLOROBENZENE-D5 10.000 10.000 0.0 101 0.01
S Toluene-d8 10.000 10.371 -3.7 107 0.01
C/T/M Toluene 10.000 10.531 -5.3 117 0.03
T,M Ethyl methacrylate 10.000 9.794.../ 2.1 110 0.01
T,M trans-1,3-Dichloropropene 10.000 10.126 -1. 3 113 0.01
T,M 1, 1, 2-Trichloroethane 10.000 9.746 2.5 114 0.01
T,M 2-Hexanone 50.000 49.461 1.1 117 0.01
T,M 1 /3-Dichloropropane 10.000 10.289 -2.9 114 0.01
T,M Tetrachloroethene 10.000 10.273 -2.7 114 0.01
T,M Dibromochloromethane 10.000 9.955 0.4 112 0.01
T,M 2-Ethyl-1-butanol -1. 000 0.000 0.0 0 0.00
T,M 1 /2-Dibromoethane 10.000 9.801 2.0 110 0.01
T,M 1-Chlorohexane 10.000 10.719 -7.2 118 0.01
P, T,M Chlorobenzene 10.000 1°of4 -5.6 117 0.01
T,M 1, 1, 1, 2-Tetrachloroethane 10.000 9.6 3.9 109 0.01
C,T/M Ethylbenzene 10.000 10.153 -1. 5 115 0.01
T,M m-Xylene & p-Xylene 20.000 20.861 -4.3 115 0.01
T,M o-Xylene 10.000 9.891 1.1 112 0.01
T,M Styrene 10.000 10.170 -1. 7 114 0.01
T,M Isopropylbenzene 10.000 10.172 -1. 7 116 0.01
I 1 /2-DICHLOROBENZENE-D4 10.000 10.000 0.0 103 0.01
P/T/M Bromoform 10.000 9.340 6.6 108 0.01
P/T,M 1 /1 /2 /2-Tetrachloroethane 10.000 9.825 1.8 112 0.01
S 4-Bromofluorobenzene 10.000 9.979 0.2 107 0.01
T,M l,2,3-Trichloropropane 10.00'0 9.329 6.7 108 0.00
T,M trans-l,4-Dichloro-2-butene 10.000 8.167 18.3 96 0.01
T,M n-Propylbenzene 10.000 10.035 -0.4 114 0.00
T,M Bromobenzene 10.000 10.003 -0.0 116 0.01
(#) = Out of Range
REW434.D V006E15.M Wed May 24 09:49:25 2023 Page 2
REPORT ID: 23E133 Page 166 of 345
81
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83
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85
86
87
88
89
90
91
92
93
94
95
96
97
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Acq On 24 May 2023 7:30 am
Sample CV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 1, 3, 5-Trimethylbenzene 10.000 9.851 1.5 115 0.01
T,M 2-Chlorotoluene 10.000 9.725 2.8 110 0.01
T,M 4-Chlorotoluene 10.000 11. 120 -11.2 129 0.01
T,M tert-Butylbenzene 10.000 9.819 1.8 114 0.00
T,M l,2,4-Trimethylbenzene 10.000 9.753 2.5 115 0.01
T,M sec-Butylbenzene 10.000 9.789 2.1 113 0.01
T,M p-Isopropyltoluene 10.000 10.140 -1. 4 117 0.01
T,M 1,3-Dichlorobenzene 10.000 10.716 -7.2 122 0.01
T,M 1,2,3-Trimethylbenzene 10.000 10.338 -3.4 120 0.01
T,M 1,4-Dichlorobenzene 10.000 10.520 -5.2 119 0.01
T,M n-Butylbenzene 10.000 10.130 -1.3 118 0.01
T,M 1,2-Dichlorobenzene 10.000 10.631 -6.3 121 0.01
T,M 1,2-Dibromo-3-chloropropane 10.000 8.614 13.9 103 0.00
T,M 1,2,4-Trichlorobenzene 10.000 9.455 5.4 110 0.01
T,M Hexachlorobutadiene 10.000 10.015 -0.2 112 0.01
T,M Naphthalene 10.000 9.317 6.8 106 0.01
T,M 1, 2, 3-Trichlorobenzene 10.000 9.381 6.2 107 0.01
(#) = Out of Range
REW434.D V006E15.M
sPCC's out = 0 CCC's out = 0
Wed May 24 09:49:25 2023 Page 3
REPORT ID: 23E133 Page 167 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Acq On 24 May 2023 7:30 am
Sample CV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 TIM Dichlorodifluoromethane
3 P/T/M Chloromethane
4 C/T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 TIM Acrolein
10 TIM l,1 /2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C/T,M 1 /1-Dichloroethene
13 TIM tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 TIM Iodomethane
17 T,M Methylene chloride
18 TIM Carbon disulfide
19 TIM Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 TIM trans-1,2-Dichloroethene
22 TIM Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P/T,M 1,1-Dichloroethane
25 T,M 2-Butanol
26 TIM tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2 /2-Dichloropropane
29 TIM cis-1,2-Dichloroethene
30 C/T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M 1,l,l-Trichloroethane
36 T,M Cyclohexane
37 TIM 2,2,4-Trimethylpentane
38 T,M 1 /1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1,2-Dichloroethane-d4
AvgRF CCRF
1.000 1.000
0.400 0.428
0.443 ~0.448
0.431 0.381
0.355 0.318
0.260 0.229
0.592 0.616
0.513 0.471
0.025 0.023
0.277 0.250
0.040 0.035
0.551 0.559
0.011 0.011
0.000 0.000
0.027 0.025
0.604 0.583
0.392 0.402
1.315 1.245
0.045 0.046
0.540 0.521
0.379 0.382
0.988 1.025
0.305 0.323
0.617 / 0.625
0.000 0.010
0.817 0.833
0.060 0.058
0.333 0.363
0.374 0.380
0.603 0.596
0.000 0.001
0.191 0.186
0.034 0.029
0.323 0.320
0.501 0.457
0.523 0.558
0.000 0.025
0.165 0.174
0.394 0.391
0.644 0.593
0.225 0.217
(#) = Out of Range
REW434.D V006E15.M Wed May 24 09:49:29 2023
%Dev Area% Dev(min)
0.0
-7.0
-1.1
11. 6
10.4
11. 9
-4.1
8.2
8.0
9.7
12.5
-1. 5
0.0
0.0
7.4
3.5
-2.6
5.3
-2.2
3.5
-0.8
-3.7
-5.9
-1. 3
0.0
-2.0
3.3
-9.0
-1. 6
1.2
0.0
2.6
14.7
0.9
8.8
-6.7
0.0
-5.5
0.8
7.9
3.6
106
116
105
92
93
93
121
100
111
110
117
118
111
0#
118
114
125
104
118
109
118
122
116
120
0#
120
119
123
119
118
0#
115
109
109
114
126
0#
124
120
107
105
0.01
0.02
0.02
0.00
0.02
0.02
0.02
0.00
0.00
0.04
0.02
0.00
0.02
0.00
0.02
-0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.04
0.02
0.02
0.02
0.03
0.01
0.01
0.01
0.01
0.01
0.01
Page 1
REPORT ID: 23E133 Page 168 of 345
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63
64
65
66
67
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80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Acq On 24 May 2023 7:30 am
Sample CV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1 /2-Dichloroethane 0.281
T,M Benzene 1. 355
T,M Trichloroethene 0.363
T,M Methylcyclohexane 0.561
C/T/M l,2-Dichloropropane 0.315
T,M l,4-Dioxane 0.001
T,M Bromodichloromethane 0.421
T,M D ibromome thane 0.162
T,M 2-Chloroethyl vinyl ether 0.027
T,M 4-Methyl-2-pentanone 0.144
T,M cis-1,3-Dichloropropene 0.497
I CHLOROBENZENE-D5 1. 000
S Toluene-d8 1. 299
C/T/M Toluene 1. 633
T,M Ethyl methacrylate 0.291
T,M trans-1 /3-Dichloropropene 0.423
T,M 1, 1, 2-Trichloroethane 0.234
T,M 2-Hexanone 0.117
T,M 1 /3-Dichloropropane 0.419
T,M Tetrachloroethene 0.358
T,M Dibromochloromethane 0.296
T,M 2-Ethyl-1-butanol 0.000
T,M l,2-Dibromoethane 0.2~9
T,M 1-Chlorohexane 0.685
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
0.280 0.4 116 0.03
1. 374 -1. 4 118 0.01
0.377 -3.9 122 0.01
0.622 -10.9 133 0.01
0.326 -3.5 123 0.01
0.001 0.0 123 0.00
0.412 2.1 119 0.01
0.156 3.7 113 0.01
0.032 -18.5 133 0.01
0.148 -2.8 118 0.01
0.500 -0.6 116 0.01
1. 000 0.0 101 0.01
1. 347 -3.7 107 0.01
1.719 -5.3 117 0.03
0.285 2.1 110 0.01
0.428 -1. 2 113 0.01
0.228 2.6 114 0.01
0.115 1.7 117 0.01
0.431 -2.9 114 0.01
/0.368 -2.8 114 0.01
0.295 0.3 112 0.01
0.000 0.0 0# 0.00
0.225 1.7 110 0.01
0.734 -7.2 118 0.01
P, T,M Chlorobenzene 1. 050 1.109 -5.6 117 0.01
T,M 1, 1, 1, 2-Tetrachloroethane 0.365 0.351 3.8 109 0.01
C/T,M Ethylbenzene 1.971 2.001 -1. 5 115 0.01
T,M m-Xylene & p-Xylene 1.439 1. 501 -4.3 115 0.01
T,M o-Xylene 1.469 1. 453 1.1 112 0.01
T,M Styrene 1.117 1.136 -1. 7 114 0.01
T,M Isopropylbenzene 1. 882 1. 914 -1. 7 116 0.01
T 1 /2-DICHLOROBENZENE-D4 1.000 1. 000 0.0 103 0.01
P/T/M Bromoform 0.367 0.343 6.5 108 0.01
P/T,M 1, 1, 2,2-Tetrachloroethane 0.660 0.648 1.8 112 0.01
S 4-Bromofluorobenzene 1.132 1.130 0.2 107 0.01
TIM l,2,3-Trichloropropane 0.169 0.158 6.5 108 0.00
T,M trans-1,4-Dichloro-2-butene 0.172 0.140 18.6 96 0.01
TIM n-Propylbenzene 5.985 6.006 -0.4 114 0.00
TIM Bromobenzene 1.034 1.034 0.0 116 0.01
(#) ~ Out of Range
REW434.D V006E15.M Wed May 24 09:49:32 2023 Page 2
REPORT ID: 23E133 Page 169 of 345
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Aeq On 24 May 2023 7:30 am
Sample CV006E1507
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M 1, 3, 5-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.856
T,M 4-Chlorotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M l,2,4-Trimethylbenzene 3.824
TIM see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
TIM l,3-Diehlorobenzene 1.955
TIM 1,2,3-Trimethylbenzene 3.471
T,M l,4-Diehlorobenzene 1. 960
T,M n-Butylbenzene 3.978
T,M 1,2-Diehlorobenzene 1.630
T,M 1,2-Dibromo-3-ehloropropane 0.105
T,M 1,2,4-Triehlorobenzene 1. 069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1. 562
T,M 1, 2, 3-Triehlorobenzene 0.822
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
3.814 1.5 115 0.01
3.751 2.7 110 0.01
3.389 -11.2 129 0.01
0.913 1.7 114 0.00
3.730 2.5 115 0.01
5.267 2.1 113 0.01
4.260 -1.4 117 0.01
2.095 -7.2 122 0.01
3.589 -3.4 120 0.01
2.062 -5.2 119 0.01
4.030 -1.3 118 0.01
1.733 -6.3 121 0.01
0.091 13.3 103 0.00
1.011 5.4 110 0.01
0.659 -0.2 112 0.01
1. 455 6.9 106 0.01
0.771 6.2 107 0.01
(#) = Out of Range
REW434.D V006E15.M
sPCC's out = 0 CCC's out = 0
Wed May 24 09:49:33 2023 Page 3
REPORT ID: 23E133 Page 170 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Acq On 24 May 2023 7:30 am
Sample CV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 7:52 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. Qlon Response Cone Units Dev(Min)
10.10
15.55
19.43
114
117
152
4442688::
3753055/
1477331
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.01
0.01
8.12 111 1420573 9.90 ug/l 0.02
Recovery = 99.00%
9.23 65 963650 9.66 ug/l 0.01
Recovery = 96.60%
12.93 98 5054574 10.37 ug/l 0.01
Recovery = 103.70%
17.56 95 1668831 9.98 ug/l 0.01
1. 71
1. 95
2.05
2.52
2.62
2.66
2.88
3.40
3.49
3.51
3.66
3.82
4.20
4.10
4.41
4.39
4.66
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.60
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
Recovery = 99.80%
1900361
1990176
1692648
1410630
1015794
2736559
2090585
504721
1111357
783343
2485492
1178036
111446
2588028
1783912
5529149
1024999
2314110
1699027
4551575
1435264
2775615
3698930
1297076
1613654
1690194
2647349
10.70 ug/l
10.11 ug/l
8.84 ug/l
8.95 ug/l
8.79 ug/l
10.41 ug/l
9.18 ug/l
45.07 ug/l
9.02 ug/l
46.86 ug/l
10.15 ug/l
236.88 ug/l
9.29 ug/l
9.64 ug/l
10.25 ug/l
9.46 ug/l
50.86 ug/l
9.64 ug/l
10.09 ug/l
10.37 ug/l
10.58 ug/l
10.13 ug/l
10.19 ug/l
48.82 ug/l
10.92 ug/l
10.17 ug/l
9.88 ug/l
Qvalue
98
100
97
98
99
99
99
96
99
97
97
99
96
99
94
99
99
100
100
98
99
100
98
97
99
100
99
(#) = qualifier out of range (m) = manual integration
REW434.D V006E15.M Wed May 24 09:49:39 2023 Page 1
REPORT ID: 23E133 Page 171 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Acq On 24 May 2023 7:30 am
Sample CV006E1507
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 7:52 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) l,2-Diehloroethane
43) Benzene
44) Trichloroethene
45) Methylcyelohexane
46) l,2-Dichloropropane
47) l,4-Dioxane
48) Bromodiehloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) eis-1,3-Diehloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Diehloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromoehloromethane
64) l,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) l,l,l,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Triehloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.97
8.10
8.51
8.49
8.87
9.03
9.22
9.44
9.41
10.68
10.76
11.03
11. 58
11.47
11.55
12.16
12.21
12.53
13.07
13.50
13.45
13.71
13.78
14.15
14.20
14.55
14.89
15.24
15.62
15.71
15.72
15.85
16.58
16.64
17.19
17.19
17.46
17.67
17.78
17.77
17.82
130 826916
42 130602
97 2028404
84 2479790
110 771717
119 1737658
73 2634853
62 1242362
78 6102694
130 1676887
83 2764298
63 1446314
88 115777
83 1829875
93 693555
63 141422
43 3295304
75 2222536
91 6452834
69 1068789
75 1608177
97 856626
43 2166042
76 1617390
164 1379875
129 1107031
107 842844
91 2754924
112 4163943
131 1317708
91 7511054
91 11269479
91 5453444
104 4264329
105 7183211
173 506671
83 957786
110 232951
53 207122
91 8873173
156 1528139
(#) = qualifier out of range (m) = manual integration
9.74 ug/l
8.74 ug/l
9.11 ug/l
10.68 ug/l
10.52 ug/l
9.93 ug/l
9.21 ug/l
9.97 ug/l
10.14 ug/l
10.39 ug/l
11.10 ug/l
10.33 ug/l
191.07 ug/l
9.78 ug/l
9.64 ug/l
11. 75 ug/l
51. 42 ug/l
10.06 ug/l
10.53 ug/l
9.79 ug/l
10.13 ug/l
9.75 ug/l
49.46 ug/l
10.29 ug/l
10.27 ug/l
9.95 ug/l
9.80 ug/l
10.72 ug/l
10.56 ug/l
9.61 ug/l
10.15 ug/l
20.86 ug/l
9.89 ug/l
10.17 ug/l
10.17 ug/l
9.34 ug/l
9.83 ug/l
9.33 ug/l
8.17 ug/l
10.03 ug/l
10.00 ug/l
Qvalue
99
97
99
95
99
97
100
98
99
99
97
97
98
99
98
99
98
98
100
96
98
97
98
99
99
99
99
99
100
98
98
98
97
98
99
99
99
98
96
99
100
REW434.D V006E15.M Wed May 24 09:49:40 2023 Page 2
REPORT ID: 23E133 Page 172 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Aeq On 24 May 2023 7:30 am
Sample CV006E1507
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 2
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 7:52 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81 ) 1, 3, 5-Trimethylbenzene 17.99 105 5635171 9.85 ug/l 100
82) 2-Chlorotoluene 18.00 91 5540739 9.73 ug/l 92
83) 4-Chlorotoluene 18.07 91 5007176 11.12 ug/l 97
84) tert-Butylbenzene 18.43 134 1348136 9.82 ug/l 97
85) l,2,4-Trimethylbenzene 18.48 105 5509874 9.75 ug/l 99
86) see-Butylbenzene 18.69 105 7781200 9.79 ug/l 100
87) p-Isopropyltoluene 18.85 119 6292832 10.14 ug/l 99
88) l,3-Diehlorobenzene 18.95 146 3095055 10.72 ug/l 98
89) 1, 2, 3-Trimethylbenzene 19.03 105 5301527 10.34 ug/l 99
90) l,4-Diehlorobenzene 19.07 146 3046131 10.52 ug/l 99
91) n-Butylbenzene 19.29 91 5953430 10.13 ug/l 99
92) l,2-Diehlorobenzene 19.46 146 2560021 10.63 ug/l 98
93) l,2-Dibromo-3-ehloropropan 20.22 157 134104 8.61 ug/l 96
94) l,2,4-Triehlorobenzene 21.07 180 1493786 9.45 ug/l 99
95) Hexaehlorobutadiene 21.20 225 974143 10.02 ug/l 99
96) Naphthalene 21. 34 128 2149941 9.32 ug/l 99
97) 1, 2, 3-Triehlorobenzene 21.59 180 1139139 9.38 ug/l 100
(#) = qualifier out of range (m) = manual integration
REW434.D V006E15.M Wed May 24 09:49:40 2023 Page 3
REPORT ID: 23E133 Page 173 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW434.D
Aeq On 24 May 2023 7:30 am
Sample CV006E1507
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Quant Time: May 24 7:52 2023
TBA
Vial: 2
Operator: LYamas
06 Inst
Multiplr: 1. 00
Quant Results File: V006E15.RE
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
I\bundance , I
1.25e+07
1.2e+07
1.15e+07
1.1e+07j
1.05e+07)
1e+07
9500000
9000000
8500000
8000000
75000001
I
7000000j
65000001 !
60000001
5500000
, 5000000
I
45000001
I
40000001
!
3500000j
I
3000000
2500000
2000000
1500000
1000000
500000
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW434.D
9
(3
:;;
1-"
I
I I I I ' I ' ...--.---.-,
lnQle'---_> ___ .----!2::.::.o''_'o~ __ 4-"'.0::..:0'--_-'6:o.::.0"_'0~_....:8"'_.=.:00~_....:..::.= __ ..:.=-=--__ ~= _ __'.1"'-'6._""OO"---_--'-18:::.=-:00=___=-20:::.=.:OO=__ __
REW434.D V006E15.M Wed May 24 09:49:43 2023 Page 4
REPORT ID: 23E133 Page 174 of 345
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Acq On 24 May 2023 5:56 pm
Sample EV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Mul tiplr: 1. 00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
I l,4-DIFLUOROBENZENE 10.000 10.000 0.0 116 0.03
TIM Dichlorodifluoromethane 10.000 8.989 10.1 107 0.02
P,T,M Chloromethane 10.000 10.055 -0.5 115 0.02
CIT,M Vinyl chloride 10.000 8.674 13.3 100 0.00
T,M Bromomethane 10.000 8.799 12.0 101 0.02
TIM Chloroethane 10.000 8.628 13.7 100 0.02
TIM Dichlorofluoromethane 10.000 9.393 6.1 121 0.02
T,M Trichlorofluoromethane 10.000 8.430 15.7 101 0.02
T,M Acrolein 50.000 46.378 7.2 126 0.00
T,M l,l,2-Trichloro-1,2,2-trifl 10.000 7.822 21.8# 105 0.04
T,M Acetone 50.000 48.136 3.7 132 0.02
C,T,M l,l-Dichloroethene 10.000 9.283 7.2 118 0.02
T,M tert-Butyl alcohol 250.000 238.676 4.5 123 0.02
T,M Acetonitrile -1.000 0.000 0.0 a 0.00
T,M Methyl acetate 10.000 8.169 18.3 114 0.02
T,M Iodomethane 10.000 8.113 18.9 105 -0.02
T,M Methylene chloride 10.000 9.575 4.3 128 0.02
T,M Carbon disulfide 10.000 10.196 -2.0 123 0.04
T,M Acrylonitrile 50.000 51.037 -2.1 130 0.02
T,M tert-Butyl methyl ether (MT 10.000 9.241 7.6 115 0.02
T,M trans-1,2-Dichloroethene 10.000 9.503 5.0 122 0.02
T,M Isopropyl ether (DIPE) 10.000 10.184 -1. 8 131 0.02
T,M Vinyl acetate 10.000 8.657 13.4 105 0.02
P,T,M l,l-Dichloroethane 10.000 9.710 2.9 127 0.02
T,M 2-Butanol 250.000 0.000 100.0# 0 0.02
T,M tert-Butyl ethyl ether (ETB 10.000 9.813 1.9 127 0.02
T,M 2-Butanone 50.000 48.839 2.3 131 0.02
T,M 2,2-Dichloropropane 10.000 8.729 12.7 108 0.02
T,M cis-1,2-Dichloroethene 10.000 9.692 3.1 125 0.02
C,T,M Chloroform 10.000 9.355 6.4 123 0.04
T,M tert-Amyl alcohol 50.000 0.000 100.0# 0 0.03
T,M Bromochloromethane 10.000 9.224 7.8 120 0.02
T,M Tetrahydrofuran 10.000 8.746 12.5 120 0.02
S Dibromofluoromethane 10.000 10.138 -1. 4 123 0.02
T,M 1 ,1,l-Trichloroethane 10.000 8.114 18.9 112 0.03
T,M Cyclohexane 10.000 7.210 27.9# 93 0.03
T,M 2,2,4-Trimethylpentane 10.000 0.000 100.0# 0 0.01
T,M 1,1-Dichloropropene 10.000 9.061 9.4 118 0.01
T,M Carbon tetrachloride 10.000 8.876 11. 2 118 0.01
T,M tert-Amyl methyl ether (TAM 10.000 8.903 11. a 114 0.03
S l,2-Dichloroethane-d4 10.000 9.901 1.0 119 0.03
(#) = Out of Range
REW458.D V006E15.M Wed May 24 18:19:23 2023 Page 1
REPORT ID: 23E133 Page 175 of 345
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Acq On 24 May 2023 5:56 pm
Sample EV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M l,2-Dichloroethane 10.000 9.235 7.7 118 0.03
T,M Benzene 10.000 9.603 4.0 123 0.03
T,M Trichloroethene 10.000 9.305 7.0 120 0.01
T,M Methylcyclohexane 10.000 8.801 12.0 116 0.01
C,T,M l,2-Dichloropropane 10.000 9.933 0.7 130 0.03
T,M l,4-Dioxane 200.000 177.467 11. 3 126 0.00
T,M Bromodichloromethane 10.000 9.138 8.6 122 0.01
T,M Dibromomethane 10.000 9.286 7.1 120 0.01
T,M 2-Chloroethyl vinyl ether 10.000 6.884 31.2# 86 0.03
T,M 4-Methyl-2-pentanone 50.000 50.433 -0.9 128 0.03
T,M cis-1,3-Dichloropropene 10.000 9.436 5.6 120 0.03
I CHLOROBENZENE-D5 10.000 10.000 0.0 115 0.03
S Toluene-d8 10.000 10.212 -2.1 121 0.01
C,T,M Toluene 10.000 9.758 2.4 124 0.03
T,M Ethyl methacrylate 10.000 9.490 5.1 121 0.01
T,M trans-1,3-Dichloropropene 10.000 9.234 7.7 117 0.03
T,M 1, 1, 2-Trichloroethane 10.000 9.276 7.2 123 0.01
T,M 2-Hexanone 50.000 48.439 3.1 130 0.01
T,M l,3-Dichloropropane 10.000 9.576 4.2 121 0.01
T,M Tetrachloroethene 10.000 9.298 7.0 118 0.03
T,M Dibromochloromethane 10.000 9.219 7.8 118 0.03
T,M 2-Ethyl-1-butanol -1.000 0.000 0.0 a 0.00
T,M l,2-Dibromoethane 10.000 9.256 7.4 118 0.03
T,M 1-Chlorohexane 10.000 9.464 5.4 118 0.01
P, T,M Chlorobenzene 10.000 9.584 4.2 121 0.01
T,M 1, 1, l,2-Tetrachloroethane 10.000 9.424 5.8 122 0.01
C,T,M Ethylbenzene 10.000 9.498 5.0 123 0.03
T,M m-Xylene & p-Xylene 20.000 19.315 3.4 121 0.03
T,M o-Xylene 10.000 9.453 5.5 122 0.03
T,M Styrene 10.000 9.409 5.9 121 0.03
T,M Isopropylbenzene 10.000 9.465 5.4 123 0.01
I l,2-DICHLOROBENZENE-D4 10.000 10.000 0.0 118 0.01
P,T,M Bromoform 10.000 8.587 14.1 114 0.01
P,T,M 1, 1, 2, 2-Tetrachloroethane 10.000 9.687 3.1 126 0.03
S 4-Bromofluorobenzene 10.000 9.867 1.3 120 0.01
T,M 1, 2, 3-Trichloropropane 10.000 8.871 11. 3 117 0.01
T,M trans-1,4-Dichloro-2-butene 10.000 8.733 12.7 117 0.01
T,M n-Propylbenzene 10.000 9.595 4.0 124 0.01
T,M Bromobenzene 10.000 9.400 6.0 124 0.01
(#) = Out of Range
REW458.D V006E15.M Wed May 24 18:19:24 2023 Page 2 ,
REPORT ID: 23E133 Page 176 of 345
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Acq On 24 May 2023 5:56 pm
Sample EV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Min. RRF
Max. RRF Dev
Tue May 16 12:41:48 2023
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 1,3,5-Trimethylbenzene 10.000 9.235 7.7 122 0.01
T,M 2-Chlorotoluene 10.000 9.456 5.4 122 0.01
T,M 4-Chlorotoluene 10.000 9.442 5.6 125 0.01
T,M tert-Butylbenzene 10.000 9.477 5.2 125 0.01
T,M 1,2,4-Trimethylbenzene 10.000 9.242 7.6 124 0.01
T,M sec-Butylbenzene 10.000 9.483 5.2 125 0.01
T,M p-Isopropyltoluene 10.000 9.228 7.7 122 0.01
T,M 1,3-Dichlorobenzene 10.000 9.423 5.8 122 0.01
T,M 1,2,3-Trimethylbenzene 10.000 9.223 7.8 122 0.01
T,M 1,4-Dichlorobenzene 10.000 9.352 6.5 121 0.01
T,M n-Butylbenzene 10.000 9.569 4.3 127 0.01
T,M 1,2-Dichlorobenzene 10.000 9.513 4.9 123 0.01
T,M 1,2-Dibromo-3-chloropropane 10.000 8.571 14.3 117 0.01
T,M 1,2,4-Trichlorobenzene 10.000 9.048 9.5 120 0.01
T,M Hexachlorobutadiene 10.000 9.458 5.4 121 0.01
T,M Naphthalene 10.000 9.097 9.0 118 0.01
T,M 1,2,3-Trichlorobenzene 10.000 9.109 8.9 118 0.03
(#) = Out of Range
REW458.D V006E15.M
SPCC's out = a CCC's out = a
Wed May 24 18:19:24 2023 Page 3
REPORT ID: 23E133 Page 177 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Acq On 24 May 2023 5:56 pm
Sample EV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Dichlorodifluoromethane
3 P,T,M Chloromethane
4 C,T,M Vinyl chloride
5 T,M Bromomethane
6 T,M Chloroethane
7 T,M Dichlorofluoromethane
8 T,M Trichlorofluoromethane
9 T,M Acrolein
10 T,M l,l,2-Trichloro-1,2,2-trifl
11 T,M Acetone
12 C,T,M l,l-Dichloroethene
13 T,M tert-Butyl alcohol
14 T,M Acetonitrile
15 T,M Methyl acetate
16 T,M Iodomethane
17 T,M Methylene chloride
18 T,M Carbon disulfide
19 T,M Acrylonitrile
20 T,M tert-Butyl methyl ether (MT
21 T,M trans-1,2-Dichloroethene
22 T,M Isopropyl ether (DIPE)
23 T,M Vinyl acetate
24 P,T,M l,l-Dichloroethane
25 T,M 2-Butanol
26 T,M tert-Butyl ethyl ether (ETB
27 T,M 2-Butanone
28 T,M 2,2-Dichloropropane
29 T,M cis-1,2-Dichloroethene
30 C,T,M Chloroform
31 T,M tert-Amyl alcohol
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
AvgRF
1.000
0.400
0.443
0.431
0.355
0.260
0.592
0.513
0.025
0.277
0.040
0.551
0.011
0.000
0.027
0.604
0.392
1. 315
0.045
0.540
0.379
0.988
0.305
0.617
0.000
0.817
0.060
0.333
0.374
0.603
0.000
0.191
0.034
0.323
0.501
0.523
0.000
0.165
0.394
0.644
0.225
50% Max. R.T. Dev 0.16min
200%
CCRF
1. 000
0.359
0.445
0.374
0.312
0.224
0.556
0.432
0.023
0.217
0.036
0.512
0.011
0.000
0.022
0.490
0.375
1. 341
0.046
0.499
0.360
1. 006
0.264
0.599
0.009
0.802
0.058
0.290
0.363
0.564
0.001
0.176
0.029
0.327
0.407
0.377
0.020
0.150
0.350
0.574
0.222
%Dev Area% Dev(min)
0.0
10.3
-0.5
13.2
12.1
13.8
6.1
15.8
8.0
21. 7#
10.0
7.1
0.0
0.0
18.5
18.9
4.3
-2.0
-2.2
7.6
5.0
-1. 8
13.4
2.9
0.0
1.8
3.3
12.9
2.9
6.5
0.0
7.9
14.7
-1. 2
18.8
27.9#
0.0
9.1
11. 2
10.9
1.3
116
107
115
100
101
100
121
101
126
105
132
118
123
0#
114
105
128
123
130
115
122
131
105
127
0#
127
131
108
125
123
0#
120
120
123
112
93
0#
118
118
114
119
0.03
0.02
0.02
0.00
0.02
0.02
0.02
0.02
0.00
0.04
0.02
0.02
0.02
0.00
0.02
-0.02
0.02
0.04
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.04
0.03
0.02
0.02
0.02
0.03
0.03
0.01
0.01
0.01
0.03
0.03
(#) = Out of Range
REW458.D V006E15.M Wed May 24 18:19:28 2023 Page 1
REPORT ID: 23E133 Page 178 of 345
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Acq On 24 May 2023 5:56 pm
Sample EV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M l,2-Dichloroethane
43 T,M Benzene
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M l,2-Dichloropropane
47 T,M l,4-Dioxane
48 T,M Bromodichloromethane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M 1, 1, 2-Trichloroethane
59 T,M 2-Hexanone
60 T,M l,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 2-Ethyl-1-butanol
64 T,M l,2-Dibromoethane
65 T,M 1-Chlorohexane
66 P, T,M Chlorobenzene
67 T,M l,l,l,2-Tetrachloroethane
68 C,T,M Ethylbenzene
69 T,M m-Xylene & p-Xylene
70 T,M o-Xylene
71 T,M Styrene
72 T,M Isopropylbenzene
73 I l,2-DICHLOROBENZENE-D4
74 P,T,M Bromoform
75 P,T,M l,l,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1{2,3-Trichloropropane
78 T,M trans-1,4-Dichloro-2-butene
79 T,M n-Propylbenzene
80 T,M Bromobenzene
AvgRF
0.281
1.355
0.363
0.561
0.315
0.001
0.421
0.162
0.027
0.144
0.497
1.000
1.299
1. 633
0.291
0.423
0.234
0.117
0.419
0.358
0.296
0.000
0.229
0.685
1.050
0.365
1.971
1.439
1.469
1.117
1. 882
1.000
0.367
0.660
1.132
0.169
0.172
5.985
1.034
CCRF
0.259
1. 301
0.338
0.494
0.313
0.001
0.385
0.150
0.019
0.146
0.469
1.000
1.326
1. 593
0.276
0.391
0.217
0.113
0.401
0.333
0.273
0.000
0.212
0.648
1. 007
0.344
1. 872
1. 390
1. 389
1. 051
1. 781
1.000
0.315
0.639
1.117
0.150
0.150
5.743
0.972
(#) = Out of Range
REW458.D V006E15.M Wed May 24 18:19:30 2023
%Dev Area% Dev(min)
7.8
4.0
6.9
11. 9
0.6
0.0
8.6
7.4
29.6#
-1.4
5.6
118
123
120
116
130
126
122
120
86
128
120
0.0 115
-2.1 121
2.4 124
5.2 121
7.6 117
7.3 123
3.4 130
4.3 121
7.0 118
7.8 118
0.0 0#
7.4 118
5.4 118
4.1 121
5.8 122
5.0 123
3.4 121
5.4 122
5.9 121
5.4 123
0.0
14.2
3.2
1.3
11. 2
12.8
4.0
6.0
118
114
126
120
117
117
124
124
0.03
0.03
0.01
0.01
0.03
0.00
0.01
0.01
0.03
0.03
0.03
0.03
0.01
0.03
0.01
0.03
0.01
0.01
0.01
0.03
0.03
0.00
0.03
0.01
0.01
0.01
0.03
0.03
0.03
0.03
0.01
0.01
0.01
0.03
0.01
0.01
0.01
0.01
0.01
Page 2
REPORT ID: 23E133 Page 179 of 345
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Aeq On 24 May 2023 5:56 pm
Sample EV006E1507
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
Tue May 16 12:41:48 2023
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M l,3,5-Trimethylbenzene 3.872
T,M 2-Chlorotoluene 3.856
T,M 4-Chlorotoluene 3.048
T,M tert-Butylbenzene 0.929
T,M l,2,4-Trimethylbenzene 3.824
T,M see-Butylbenzene 5.381
T,M p-Isopropyltoluene 4.201
T,M l,3-Diehlorobenzene 1.955
T,M 1, 2, 3-Trimethylbenzene 3.471
T,M l,4-Diehlorobenzene 1. 960
T,M n-Butylbenzene 3.978
T,M l,2-Diehlorobenzene 1.630
T,M l,2-Dibromo-3-ehloropropane 0.105
T,M l,2,4-Triehlorobenzene 1. 069
T,M Hexaehlorobutadiene 0.658
T,M Naphthalene 1. 562
T,M l,2,3-Triehlorobenzene 0.822
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
3.576 7.6 122 0.01
3.647 5.4 122 0.01
2.878 5.6 125 0.01
0.881 5.2 125 0.01
3.534 7.6 124 0.01
5.102 5.2 125 0.01
3.876 7.7 122 0.01
1.842 5.8 122 0.01
3.202 7.7 122 0.01
1. 833 6.5 121 0.01
3.807 4.3 127 0.01
1.551 4.8 123 0.01
0.090 14.3 117 0.01
0.968 9.4 120 0.01
0.623 5.3 121 0.01
1.421 9.0 118 0.01
0.749 8.9 118 0.03
(#) = Out of Range
REW458.D V006E15.M
SPCC's out = 0 CCC's out = 0
Wed May 24 18:19:31 2023 Page 3
REPORT ID: 23E133 Page 180 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW458.D Vial: 26
Operator: LYamas Acq On 24 May 2023 5:56 pm
Sample EV006E1507 Inst 06
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 24 18:19 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
73) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
2) Dichlorodifluoromethane
3) Chloromethane
4) Vinyl chloride
5) Bromomethane
6) Chloroethane
7) Dichlorofluoromethane
8) Trichlorofluoromethane
9) Acrolein
10) l,l,2-Trichloro-1,2,2-trif
11) Acetone
12) l,l-Dichloroethene
13) tert-Butyl alcohol
15) Methyl acetate
16) Iodomethane
17) Methylene chloride
18) Carbon disulfide
19) Acrylonitrile
20) tert-Butyl methyl ether (M
21) trans-1,2-Dichloroethene
22) Isopropyl ether (DIPE)
23) Vinyl acetate
24) l,l-Dichloroethane
26) tert-Butyl ethyl ether (ET
27) 2-Butanone
28) 2,2-Dichloropropane
29) cis-1,2-Dichloroethene
30) Chloroform
R.T. QIon Response Conc Units Dev(Min)
10.11 114
15.56 117
19.43 152
4894707~ 10.00 ug/l
4277559 / 10.00 ug/l
1683719 10.00 ug/l
0.03
0.03
0.01
8.12 111 1602709 10.14 ug/l 0.02
Recovery = 101.40%
9.24 65 1088476 9.90 ug/l 0.03
Recovery = 99.00%
12.93 98 5672240 10.21 ug/l 0.01
Recovery = 102.10%
17.56 95 1880482 9.87 ug/l 0.01
1. 71
1. 95
2.05
2.52
2.62
2.66
2.90
3.40
3.49
3.51
3.68
3.82
4.20
4.10
4.41
4.41
4.66
4.70
4.91
5.63
5.86
5.77
6.55
6.84
7.09
7.22
7.62
85
50
62
94
64
67
101
56
151
43
61
59
74
142
49
76
53
73
96
45
43
63
59
43
77
96
83
Recovery = 98.70%
1759444
2180226
1830134
1528535
1098405
2721122
2116096
572178
1061902
885351
2505191
1307730
108021
2399827
1835245
6563250
1133311
2443674
1762242
4922628
1294243
2930217
3923856
1429652
1420796
1774674
2762123
8.99 ug/l
10.05 ug/l
8.67 ug/l
8.80 ug/l
8.63 ug/l
9.39 ug/l
8.43 ug/l
46.38 ug/l
7.82 ug/l
48.14 ug/l
9.28 ug/l
238.68 ug/l
8.17 ug/l
8.11 ug/l
9.58 ug/l
10.20 ug/l
51. 04 ug/l
9.24 ug/l
9.50 ug/l
10.18 ug/l
8.66 ug/l
9.71 ug/l
9.81 ug/l
48.84 ug/l
8.73 ug/l
9.69 ug/l
9.36 ug/l
Qvalue
97
98
98
99
100
100
100
100
99
96
97
100
98
99
94
100
99
99
100
98
98
100
96
97
99
99
100
(#) = qualifier out of range (m) = manual integration
REW458.D V006E15.M Wed May 24 18:19:37 2023 Page 1
REPORT ID: 23E133 Page 181 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Acq On 24 May 2023 5:56 pm
Sample EV006E1507
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 18:19 2023 Quant Results File: V006E15.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Last Update
Response via
DataAcq Meth
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) 1,2-Dichloroethane
43) Benzene
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) 1,4-Dioxane
48) Bromodichloromethane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
64) 1,2-Dibromoethane
65) 1-Chlorohexane
66) Chlorobenzene
67) 1(1,1,2-Tetrachloroethane
68) Ethylbenzene
69) m-Xylene & p-Xylene
70) o-Xylene
71) Styrene
72) Isopropylbenzene
74) Bromoform
75) 1,1,2,2-Tetrachloroethane
77) 1(2,3-Trichloropropane
78) trans-1,4-Dichloro-2-buten
79) n-Propylbenzene
80) Bromobenzene
7.97
8.10
8.51
8.50
8'.86
9.03
9.23
9.44
9.42
10.68
10.76
11.05
11. 58
11.47
11.55
12.17
12.23
12.54
13.07
13.50
13.46
13.71
13.78
14.15
14.21
14.56
14.90
15.24
15.61
15.71
15.73
15.86
16.59
16.65
17.19
17.19
17.47
17.68
17.78
17.78
17.82
130 863176
42 144029
97 1990748
84 1844743
110 732515
119 1711977
73 2807486
62 1268483
78 6369640
130 1653759
83 2415870
63 1532758
88 118478
83 1884697
93 735966
63 91302
43 3561114
75 2295719
91 6814831
69 1180357
75 1671476
97 929231
43 2417715
76 1715726
164 1423399
129 1168430
107 907260
91 2772277
112 4305754
131 1473363
91 8009166
91 11892380
91 5940521
104 4496599
105 7618045
173 530916
83 1076212
110 252475
53 252429
91 9669607
156 1636507
(#) = qualifier out of range (m) = manual integration
9.22 ug/l
8.75 ug/l
8.11 ug/l
7.21 ug/l
9.06 ug/l
8.88 ug/l
8.90 ug/l
9.24 ug/l
9.60 ug/l
9.30 ug/l
8.80 ug/l
9.93 ug/l
177.47 ug/l
9.14 ug/l
9.29 ug/l
6.88 ug/l
50.43 ug/l
9.44 ug/l
9.76 ug/l
9.49 ug/l
9.23 ug/l
9.28 ug/l
48.44 ug/l
9.58 ug/l
9.30 ug/l
9.22 ug/l
9.26 ug/l
9.46 ug/l
9.58 ug/l
9.42 ug/l
9.50 ug/l
19.31 ug/l
9.45 ug/l
9.41 ug/l
9.47 ug/l
8.59 ug/l
9.69 ug/l
8.87 ug/l
8.73 ug/l
9.59 ug/l
9.40 ug/l
Qvalue
99
96
98
98
99
98
99
100
100
99
97
95
97
98
98
91
98
99
100
97
99
97
100
97
100
100
99
100
100
99
99
99
98
99
100
99
98
99
93
100
99
REW458.D V006E15.M Wed May 24 18:19:38 2023 Page 2
REPORT ID: 23E133 Page 182 of 345
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Aeq On 24 May 2023 5:56 pm
Sample EV006E1507
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 26
Operator: LYamas
Inst 06
TBA Multiplr: 1.00
Quant Time: May 24 18:19 2023 Quant Results File: V006E15.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V006E15.M (RTE Integrator)
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
V006E15
Compound R.T. QIon Response Cone Unit Qvalue
81) 1, 3, 5-Trimethylbenzene 17.99 105 6021006 9.24 ug/l 100
82) 2-Chlorotoluene 18.00 91 6139697 9.46 ug/l 99
83) 4-Chlorotoluene 18.07 91 4845756 9.44 ug/l 98
84) tert-Butylbenzene 18.44 134 1482852 9.48 ug/l 99
85) 1,2,4-Trimethylbenzene 18.48 105 5950653 9.24 ug/l 99
86) see-Butylbenzene 18.69 105 8591175 9.48 ug/l 100
87) p-Isopropyltoluene 18.85 119 6526873 9.23 ug/l 100
88) 1,3-Diehlorobenzene 18.95 146 3101853 9.42 ug/l 99
89) 1, 2, 3-Trimethylbenzene 19.03 105 5390573 9.22 ug/l 99
90) 1,4-Diehlorobenzene 19.07 146 3086377 9.35 ug/l 99
91) n-Butylbenzene 19.29 91 6409709 9.57 ug/l 99
92) 1,2-Diehlorobenzene 19.46 146 2610907 9.51 ug/l 98
93) 1,2-Dibromo-3-ehloropropan 20.24 157 152081 8.57 ug/l 93
94) 1,2,4-Triehlorobenzene 21.07 180 1629233 9.05 ug/l 99
95) Hexaehlorobutadiene 21.20 225 1048467 9.46 ug/l 99
96 ) Naphthalene 21.34 128 2392220 9.10 ug/l 100
97) 1,2,3-Triehlorobenzene 21. 60 180 1260602 9.11 ug/l 98
(#) = qualifier out of range (m) = manual integration
REW458.D V006E15.M Wed May 24 18:19:38 2023 Page 3\
REPORT ID: 23E133 Page 183 of 345
Quantitation Report
Data File D:\HPCHEM\1\DATA\23E24\REW458.D
Aeq On 24 May 2023 5:56 pm
Sample EV006E1507
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 26
Operator:
Inst
Multiplr:
LYamas
06
1. 00
Quant Time: May 24 18:19 2023 Quant Results File: V006E15.RE
Method
Title
Last Update
Response via
Abundance
11.35e+07j
I 1.3e+071
i 1.25e+07j
1.2e+071
; 1.15e+07 I
I
I
1.1e+07 i
i
. 1.05e+07 I ,
1e+07
•
9500000
9000000 I
I
8500000 I
SOOOOOO j
7500000 !
I 7000000
1
6500000 j
I
6000000 !
1
5500000
1 5000000
I 4500000
i
I
4000000 i
3500000
1
3000000
2500000
2000000
1500000
1000000
500000
I 0 I
[fime-->
I
2.00
D:\HPCHEM\1\METHODS\V006E15.M
METHOD 8260
Tue May 16 12:41:48 2023
Initial Calibration
TIC: REW45S.D
I I I I
4.00 6.00 8.00 10.00 12.00
I
14.00
(RTE Integrator)
I~
IL
I I
16.00 18.00 20.00
REW458.D V006E15.M Wed May 24 18:19:41 2023 Page 4
REPORT ID: 23E133 Page 184 of 345
· ANALYTICAL LOGS
REPORT ID: 23E133 Page 185 of 345
Page 70
ANALYSIS LOG FOR VOLATILES
J ~
Start Date: 5. ({r:;l1..-~ o S-mL Purge 0 10-mL Purge r/ 2S-mL Purge Book#: A06·079 ,
&e Matrix Instrument No. 06 Sample Data Sample
Prep lab Sample ID DF W Notes INITIAL CALIBRATION REFERENCE
ID File Name A(.Zliyt S pH Ci, A ( \7. <2 <Spprn n('{) wrAA-T&A DATE r;("h~ !
01 ~E.VJ14.fJ BfBobtl\ jIJ IA NIIt l",fA I~:U ICAllD VClt:Jofl5 i
02 ~ V 06 b t: II)' IIlJl'> o!lS' I [0.1> -.lS .,.~ STANDARDS
4!f l.S NAME ID Amount Cone. 03 '4. I,.IIS"" o,1r IQS-U,S lui .("'ll/l)
04 Sf, -; 0.1 0.'S I r:; 2., DCC ~ 'YI~ I\:l-~O \-0 I " 2.fO
.L -Ill. -o'l. Ln
05 1)1 4 o.~ I ~ lb 5'0 DCC ilko s ~ 1--41-'\ ~ -0, s-ollW
06 S"2,. "5 .s-~r ~ ~ \l-S" Dec ItCTAA &VI-4JJ . ..II'L-tl1 Lor-b
07 ~ (.. ~ to ..n 'Z.S"o DCC4~ ~v\-4' _~C;-61 U1:>
08 54-'1 ). £1> J.o HID tr"6(' BFB 1')(, -ill 1 '51)
OJ 09 !"~ '( IS'" IS". "ISO
.~
~~~ ::~~
I ~ ~ lb IS/SURR. s.~ .. l> V i Icv/LCS ~~ ~'.;~ O~ \"'i!'M ~ -t 10 Ij(. If IS" ~ l-6b IZSD I n I
::J: 11 151 to .J: Illv \'" \IV IlM) "-oc. Ul»1IIb IcvILcS tu.b II 1.5" -el\ ;; 'i1> II J.tlI , .... 10
12 5"1< ~liUSE
I-
Icv/LCS ~ &-{ t-l't1.-6?l-01 ti 2S1l
< 13 ~ ~INSF ICV/LCS~. &vr41-6'-o~ 15" I\b g
14 \V" (gO WOObE:{~O( "'10.\ km£.. li:stl Data File Folder 'l~l'5 I ~ 15
v
LOT # Syringe Lot #
~ 16 V pH strip Mf V -0 (-04-tb
17 /' Chlorine strip -oI-or-6'\"-64-
18 / Methanol -Ot. -0 l-(.r-
19 /" NaHSO. .... -ol-OS--If'
20 / Reagent Water
21 ./ V Sand
22 /' t\: SS/e~ ~ 4Qjcl. Electronic Data Archival Location Date
23 ./ HPCHEM VOA/TOO6 r;-{l b/2_'!>
24 /' !¥,:~).(,o.t:.E'r-t\A Comments:
25 /'
26 /'
27 /
28 ./
29 /' Analyzed By: Lfr.y
30 L-Pt't '5 (! k1 (')..3 Date Disposed:S"ll~l~ Disposed By: L.Pr-I
REPORT ID: 23E133 Page 186 of 345
Page 71
ANALYSIS LOG FOR VOLATILES
sop ~MAX-8260 Rev.No.10 siEMAX-8260C Rev. No.! 0 EMAX-8260SIM Rev.No.! 0 EMAX-M8260SIM Rev.No. Q 0 EMAX-TCPSIM Rev.No. ~ 0 EMAX-6Z4 Rev.No. 2 0 EMAX-624.1 Rev.No. 0
Start Date: IJllbh .. ) o S-mL Purge 0 10-mL Purge ri 2S-mL Purge Book#' A06-079
I
Matrix Instrument No. 06 Sample Data Sample
Prep Lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
File Name Amount S ID pH CI,
1:)( 1"(1-3 <2 <Spprn DATE
01 (te\]J 2.10 ( ~ ff> ()('E; 11 ... I C-\ \ ICALID VQOfor:lt;'
02 ,.y Ill... \NO obE.l'D61. \1..~l'1
STANDARDS
NAME ID Amount Conc.
03 / 1~11 (moll)
04 Dce
05 / DCC
06 V Dec
07 :/ DCC
08 / BFB SlIl-4:I-'1';"'O I I !it)
o:J 09 / IS/SURR. S~
'00 -01 , ~ la. -0 .... » V ICV/LCS ~ ~t::t
'15"0 ..... 10 l n UO
:::t 11 / levlLes m,. 2.1) -c>1 ~ ~t'}S'f>
r-12 / ICV/LCStetf\4 So v I--t-'l. -\)~ -6 ~ f) 'lSO
~. 13 L ICV /LCS 3Adct. .sv t-4-I-bS" -,,~ ~ ~
~ 14 I Data File Folder 2,'~e{'"
~ 15 / LOT # Syringe Lot #
~ 16 / pH strip NSV-6I-04 -{(",
i 17 / Chlorine strip J,--o1-OS"1IS'-04
18 / Methanol
19 / NaHS04
20 / Reagent Water
21 / Sand
22 / Electronic Data Archival Location Date
23 / HPCHEM VOA/TOO6 1:;( I" IZl
24 / Comments:
25 V
26 /
27 /
28 L
29 / Analyzed By: lI!t
I ~ 1..Pt'l '511 J.('J.. 1;) Date Disposed: 511 !!b .. ~ Disposed By: LA. 'I 30
REPORT ID: 23E133 Page 187 of 345
Page 78
ANALYSIS LOG FOR VOLATILES
SOP ~MAX-8260 Rev.No. 10 ~MAX-826OC Rev. No.1 D EMAX-8260SIM Rev.No. 1 D EMAX-M8260SIM Rev.No. 0 D EMAX-TCPSIM Rev.No. 2 D EMAX-624 Rev.No. 6 D EMAX-624.1 Rev.No. 0 ---
Start Date: 15113 h~ D 5-mLPurge D 10-mL Purge fit' 2S-mL Purge Book#: A06-079
Matrix Instrument No. 06 Sample Data Sample
Prep
File Name
Lab Sample ID DF W Notes INITIAL CALIBRATION REFERENCE
Amount S ID pH CI,
;-/i r:/) .. " <2 <SDDm DATE
01 I2.Eh 14{)f\ ~rlM("'Flq ~:(S-ICAllD vt'tnb€lr
02 ~R W(J(\t,E.LS"""Ob STANDARDS
03 oq VG~("'ElqL NAME ID Amount Conc.
ful moIL
04 to ,l C DCC~ SV, . ..4fl--O ,-61 . ~ O'",tfl.. I
05 11 fl..JA.\~~ DCCB'K"b !t"I-d-.-qg -01, 5'"
06 It... VOObet'lPJ 'l~MJ DcclceTA~ ISv I-4-2.-o2.rl11 t\
07 .'l.. 13~l2...'?>-LW l. () .f ../ DC~. S V t-+I-R~'C) 1 ,
08 14-1.1EJ 05.--0 I ~ v' I BFB '1(, -01 ,
~ 09 \~ -o5lf ~"1v.J ./1/' IS/SURR. 'l'f-o' ~ '7 {ZJ/2ID
-t 10 l(::' -()~rJ " .I ICV/LC~ . VI-a-~I!.~ 1 n
::J: 11 \f) -O~N ..; v' ICV/lCSflC.b Sv l-4d -l.~-t) I ~
~
12 t~ "'" -lOtJ "v \iii ./ V ICV/LCS '1-4--'--,,,, -o~ S-
13 tq 12f"I0'1-l S-1M\.... 2? J V ~(,..v-ICV/LCS~. S V 1-4-I-bS"'-&' ~ j e::>
~ 14 1..0 2. ~€lO;--08 M ?-5"",L l ,0 V / Data File Folder 2..3€2.~
~
15 2.1 J -ass
""
~ ../ ./ LOT # Syringe LoU
16 1.."1,..-21.':;1? '2,-t o;t.. OSML '51> of ./ pH strip t-tC2.I03~C> H S" '0 .... o4rl.b
17 l:?, J/ -ttl: .l.t J.. ./ 1../ Chlorine strip 2.??'?'DI~ .l -ot-or'-of"-04-
18 24-1...~1~3-o1 'Lhtol\'. I.r. ./ ./ Methanol
19 'L1;"" I -02-I ,;" / NaHSO.
20 2-b \ -o~ \/ ./ Reagent Water 2.\.\1 '),-'l. '}. -() D 4
21 2...<1 J., -0+ \!/ 't..-V-./ Sand
22 '2$ V-\N~t Electronic Data Archival Location Date
23 .z.q {lINSt HPCHEM VOA/TOO6 5f2..4-(1-?J
24 "?;'O 2';El?> !>-o'1 2j;\1Ml len if ./ Comments:
25 l\ J; -ob ~ L ,/ J
26 ,I--"3'2 FVllrll..,tl~O~ 1'1:1>4-
27 "7
28
----
I---
29 / Analyzed By: LA.'1
30 "-LA'! r;( 2-~/'L?' Date Disposed: '\{14-h.~ Disposed By: L.t'N
REPORT ID: 23E133 Page 188 of 345
Page 79
ANALYSIS LOG FOR VOLATILES
SOP IS:I1:MAX-8260 Rev.No. 10 IlI4MAX-8260C Rev. No.1 0 EMAX-8260SIM Rev.No. 1 0 EMAX-M8260SIM Rev.No. 0 0 EMAX-TCPSIM Rev.No. 2 0 EMAX-624 Rev.No. 6 0 EMAX-624.1 Rev.No. 0
Start Date: lJiJ4:h'h o S-ml Purge 0 10-mlPurge ~ 2S-ml Purge Book#: A06-Q79
Matrix Instrument No. 06 Sample Data Sample
Prep
File Name lab Sample 10 OF W Notes INITIAL CALIBRATION REFERENCE
10 Amount S pH CI,
r:;( 1J'i13 <2 <5DDm DATE
.01 ~IIJ+~~ Bf~C\CcEto fj:04 ICAllD VO()~(S-
02 _34-0I0Qfo£t,OI'1 STANDARDS
03 3~ YO()fDF1ht NAME 10 Amount Conc.
lull melL
04 ~Ip J... c... DCC ~!:.
'i.\r\-A1._-0\ ~I
0-";;-8'1..
I
I
05 3'1 I2-\N~g DCC fl,(,o SVl-4l-tJt.-o 3 t;
06 3~ V'OO~EU)!b ~mL DCC k.e1.AA So\l 1-4'l--ov-Ci I t;
07 3<:f l.:;£l~~1;' hO 't/ I,J DCC~c\.. \V 1-~1-"t:;',(11 I
08 40 ""--oro V-I BFB I %-01 I ~-g;lw
g, 09 41 2 'elf;-()2. V ../ IS/SURR. I Clq-a~ ~ »
2~E.l3~-05 Iv" ICv/lCS ~~ II-""-01.-I ~ 10 At')... V n S\t -4~-lI':O 'i I
::t 11 4-2> 2. 3E. \42r-(' \ ./ J, ICV IlCS t'l.Wl SVr4-I-14rOl S'
12 44-J... -01-V 1/ ICV/lCS~ SV .... ~].....()?41" S'" r
4-t? 2 ";E.I44--0?> I ( OX ICV/lCS ~. SVl4( -bS"~()3 ~ 1J ~ 13 if ....-
0 14 4b J..--04-.; I Data File Folder ~e14 .. cs-m 15 4-1 2. '}tl '; '3 -os-M v ,/ LOT # Syringe lot #
~ 16 ~ J, -05"5 j ./ pH strip H.C.1-lll~ 30 ~-o'-G4-(b -:j
17 4I.t '2 -,£1 44-o4H v !/ Chlorine strip 2 1.1,',),,01 ~ L -ol-ot>Or--04-
18 1:)0 -o4-S ,v " ",. ,/ ./ Methanol
19 '" ~ -03:1:.. 2 .. Swlt .... to v ~ NaHSO.
20 5'2... '2.~'S-O-o I 2GML l.o v if Reagent Water R.UI~--ll-o 04-
21 ?3 \ -0'1.. v V Sand
22 t:;~ -~ ./ ,/ Electronic Data Archival location Date
23 I')tj -0+ V-I/' HPCHEM VOA/TOO6 5'1l4l~
24 c;t. -r£ Iv-\/' Comments:
25 ,,~ \.v -Oft, \.!.-" \V ../ .I
26 / 155"~ EVMb~(~t'\r") It):llo
27 / <-
28 ,..........-
29 r Analyzed By: ~
30 '!J\"I I? (Uf-I'1-~ Date Disposed: '5l'l4h~ Disposed By: W
REPORT ID: 23E133 Page 189 of 345
en

(!
)

0
-1

c ~
<C

c z
<C

l-en

REPORT ID: 23E133 Page 190 of 345
If
I
I
I
I
1.
I
I
I
I
II
II
I
I
~
Parent ID
~,'Jt-o(-1(
~
~
Parent ID
c;j\.A 0,f-:-o' -II
/
<::
Parent ID
0.A.-19..-aK--t(, v lD-l6
---.::.
STANDARDS LOG FORVOLATILES ·
Parent Standard Name Cone. Aliquot Fi11al :cone.
{\j~rto.., tA·~t-"' ~ . S"l> IS\) NbM $)"0,ut-. :;l,,S't>,.,,..
/ I
----------~
' /
/__
~
~
~
ol..# r-'1 l!r--?.>01)
Parent Standard Name Cone. Aliquot Final Cone.
Ov-bm JA'~t-''oU-6"1T){) IDI 7 !>?Jad l.SZ>~t.-
~ / -----------~
/
L /
~
~ ----\
~
0~{ rqf~
Parent Standard Name Cone. Aliquot Final Cone.
I "f/f" _C.p.,_ ( • MAl-_:#( 5?f"1TI J>/JY t]OO.J..-L %"VDnA. -A~'n 4 -Actt.tW-vL~'lt. r.:-r: I 'I
\:/-
( .... -------------~
""' )
~
~ ------v---
p dttt ( "7-~ 00
Page 1
Book No: SVl-42
Standard ID
Name
Final Volume
MeOH Solvent ID
Prep. Date
Exp.Date
Prepared By
Syringe ID:
Comments:
Standard ID SVl-42-01-02
Name OS.:~-q.~
Final Volume r~L
MeOH Solvent ID 'wt-Ac~1-~d P-
Prep. Date o4/rqf ?-J
Exp. Date rultq/~
Prepared By 1)6)
Comments:
Standard ID
Name
Final Volume
MeOH Solvent ID
Prep. Date
Exp. Date
Prepared By
Syringe ID: M&f....:> ?-Cl2--13
Comments:
REPORT ID: 23E133 Page 191 of 345
Page 6
STANDARDS lOG FOR VOlATilES
Book No: SVl-42
Parent ID Parent Standard Name Co-R:E1..-. Aliqu9~( Final k-Rl_Le. Standard ID
I~-"3.8 ~ ox -I~ lit '.t, ~ Ctt.P~-1-L 2-S"gO (o~ .,;v Name
f At4 ~ ,, v~ &M ~rz) 7--oUO rt.--ro t Final Volume ....
MeOH Solvent ID ----Prep. Date
-------Exp. Date
'\ Prepared By
i/
/
----------Comments: .... v
/
()6.{ ~I ~~"OJJ
Parent ID Parent Standard Name COt)~......-AliqypL. Fina~~R& Standard ID
~-~p -t0-1~ \!t"'uJ 0\d>~+e.. 1..s;:i:lo _f'
(601) ~ Name
r / ,,q_,r, \~ &-M ~ :2. {)()0 I~ J-Final Volume
MeOH Solvent ID ------Prep. Date
------Exp. Date
~ Prepared By
/ Syringe ID: tkXV...V 3o ~of~(s--
...------v ---------Comments:
---~
----------()sft ,f ')_~l70
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID
~ -'J, ~ -oJ{ -Jl ~1-Do ~ ')...~:~w~ (t cJ I.Al.-g-."() f»f\, Name
(_/ (o"!Y fl.~ ~ L--' /.L-£,' Final Volume
MeOH Solvent ID ----Prep. Date
~ Exp. Date
\ Prepared By
/
----~
Syringe ID: M<N-t>J -oYv '1--
---------Comments:
-----
----------( o ~II s[v~
REPORT ID: 23E133 Page 192 of 345
Page 78
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
Parent ID Parent Standard Name ..,,0 ,.., Cone. Aliquot Final Cone. Standard ID SV1-41-78-01
S.lfl ~ ~y w D cf .--DJ, Cu,C,.hWI VIII. 1\ilc J.£r.13-66q7 'UJtJbPOM 1.-~~L t;"l)llf)M Name Ylh!J tt•)
-08-t( IJY..II .t!JJ.. JJAA d~ ,· Final Volume IOml
-n(,lt.. u
2-rJevt. I MeOH Solvent ID . ~\NIA· {lll-li>-Oi'
-{11-0'1 l-c,~\t.rohe>t/.tiVI.f.. ~ ,~,.-Prep. Date ;tt/~'lj
--~-lll LL"t, -IJ.'\B 1-~0!M ?AJll.wt ~,. Exp. Date 4/f/V)
./ -DR-07 "\l'lA I t;MD!hoM .1.--IOObotliM Prepared By \It
' " Syringe ID: MS\1 ~o-; ..01· I\ -t>
--------------Comments: .,---
~
\rL '"!J/ rn>
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-41-78-02
c;~l-1,~ -{)~ -011 CI..L\tnWI VIJA n,ill '11··hf>l41 'tbOOtJP-rn 1.\1> ..wL \1>D0Yh Name ~lh.O {l 0 )
-bl-~C" DV..V a fi '> l'lhl c:.+zt I Final Volume ; 0tt"~l..
q btl ,,l. ·t-tJw.t. I I MeOH Solvent ID ~\N IA-·C>II-17 -'0 I
-61 -I}"1J 1-d\ I fl vI) k.t IUli'tl """" J.... Prep. Date 3/ttn
.• ~~~-1 f l 1.. ; -lt-18 ·~t;DO DD""' Z,D() .ML \:1' Exp. Date i{/f /)/)
,,... -67-Q} TBA t;1J ' 110/ln fJ !'h .J.. IDDODIM Prepared By \fl...
I
Syringe ID: MSV-(>7 i> 1-1!
~ --------Comments: .,---
< --\1.. '71 l'l"1
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID
l5v_l-~8 ··M ..of{ f~llh~ V M WI!~ 1 ~-{,()/.11 UJDb f)ll) I'VI 1-~,#~L f;1> Ill) .... Name
~ -)8 -t>K-K IN: V /ALIA~ 11r' ~l?J 1 Final Volume
-~S-6tl-ll ~~-~-\lJJt. ,
MeOH Solvent ID
-)t-0'3'-l4 I-th I ovn IAo.v:.MAL ,,. "--' Prep. Date
-~f-f)l-L< I 1.1· -TMI'J ~)llb DI'>W\ WO.Mt.. '-!..-Exp. Date
'l---;g -(}~_3rt 'I& A <;b Jl~DP.,., .1-lOCO &nl'k Prepared By
II Syringe ID:
>
------~ Comments:
~
<...._ .
~ \,.(_ ?l ~ /1/)
REPORT ID: 23E133 Page 193 of 345
Page 2
STANDARDS LOG FOR VOLATILES
Book No: SVl-42
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-42-02-01 w· "?R -o!-!t:. W1\-{'~· t--U 'i-.::# I ~w.-~~ ~.., Name ,_a::r--M c < ... ) u 10-16 -lruo<Lt\.. .f -A~ ~ln 'Lt..-.Y [/ ~ Final Volume !DI'\..L
'"' -MeOH Solvent 10 gt)I{A-vl\ ..rt-ox-------Prep. Date Olt./tt,.{ -v? -......
' Exp. Date 66(<-U ( "9-3-_
) Prepared By _ _ti).
/v Syringe ID:
/:
~
~ Comments:
~
/
<---"
D 'if IC ~~~cO
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-42-02-02
l(..\1\• 11-0l?-1-0 '1-bu hA r.o \ IDCDtml'\11 I.OmL 000.:11"'1 Name 1-bu hlno 1 { 1."l .. Final Volume t.OML ----MeOH Solvent 10 ~\N 11\p OlHV-Oi --r--Prep. Date 4/"Z..4/t"'
.::::> Exp. Date lo/z.~IV'1 ------Prepared By \IL
~ Syringe ID: MW-!?1~1>\-11 ~
t v
r-
Comments: -r-:---.-.
....._ "' h "' ..• ,. "1
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-42-02-03
'S"VI-}S -0~·i7 TA-A io~o1i;I)M 2~ I 1. f1> PDm Name TM-W.f(l"l J.... ·~0'1-ii Jc;.o oLrni'IL 7. OOOoo"" J... 1\!>ppl'\ Final Volume l.OmL
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---.. -r--Itt_ 1.{ /lll.f )
REPORT ID: 23E133 Page 194 of 345
Page 85
STANDARDS lOG FOR VOlATilES
Book No: SVl-41
Parent ID Parent Standard Name ConGmM Aliqu,qt .. Final,_,c;,w,c. Standard ID SV1-41-85-01
<-tv--'},f-o~-fl 2-/kfan cl t;7)~ ~~ r...J-b
v::l -((f"' {M f:to ~ h)Z..--'?-(fifO 1--'Kl1)
Name 4ao&l Cr 0
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" / tl;)-o"'1 u~"<if fr_e_ M·i-e--1.--1 .1-Prep. Date P'?/ ::>.q ( ').. '}_
LJ Exp. Date cq{"U(f·.,...~ ---Prepared By cJ1)
)
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9v.r <;,£-oR' ~r f '7---h.t-t-"ct~ noJlv (~ c., {S-o Name
<d ';:t -_L'r r ~/OW-x.tt f'U--?./0~ .L ~ Final Volume
(CJ-o;b . teA~. r ȣLc hlYa ~ ~ ( ooO I MeOH Solvent ID
~ to-6\.f Jvt -t ftt. j ?l ci4K+e-J../ L J_ Prep. Date
0 Exp. Date ----Prepared By ----...__ Syringe ID:
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MeOH Solvent ID -------Prep. Date
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REPORT ID: 23E133 Page 195 of 345
Page 76
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SV1-41-76-01
I <\1\-\11-lll·tn ... Vf>A -hi"i"'4 l:lkni 1111ilf ~VOniiiiM tOO. ,L li1JY1D"' Name ~f=V.
J 'I , I
Final Volume w~L --MeOH Solvent ID <.V·I\A· oll-1 r·oS ---r--Prep. Date 1.1'811"'1 ---r-.. Exp. Date 'fl '/11/'1
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MeOH Solvent ID SWIA -011-\9-Df
r----_ Prep. Date ";/f/l'} ----Exp. Date 'I IS IH -----Prepared By Vt. ----Syringe ID: MS'\IwO? -Dl· h
v
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-"\1'1-ll-0~ t:al\t'-ali\ill (}y:"~" .. n.,t.,.A ..... ;v /I.. I I I Final Volume IOn.L
-1,~-lll.-IS 1--l'.lPMt.
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-~! -04-t'l 1-t'.hlllvn \ti.v-fl/J\4 1{)00 001'11! d·,\w!L ~ Prep. Date -,n n J
-30 -Jl-1(, I 2., ~ ·.,... ·hriiM/-Ut ul J.~ ... ,., .... 1.XtJn ilOIIV\ UJO~l -.:...-~ Exp. Date .JH 1/1\ f'l..'~
v-W -o; -oz... -rr>A _1]1,00boow. J_ ~ $ Prepared By \It
l 000 f(Ji"'' Syringe ID: 11 s v -o1z -l> 1-11 -1--. ___::;> -----Comments:
~ ......._ . --1----\
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REPORT ID: 23E133 Page 196 of 345
r
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Parent Standard Name Cone. Aliquot Final Cone.
g~ rv? ~ w~ t-cvli*-
l...-~~ ~I ../.L-...-.l---'
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q, 2-6--o JX, ~))/)~ f·DM ~i)k
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Page 100
Book No: SV1-41
Standard ID SV1-41-100-01
Name
Final Volume
MeOH Solvent ID
Prep. Date
Exp. Date
Prepared By
Syringe ID: M@.; D ?:"'~ 7J
Comments:
Standard ID SV1-41-100-02
Name
Final Volume
MeOH Solvent ID
Prep. Date
Exp. Date
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Comments:
Standard ID SV1-41-100-03
Name ~>
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MeOH Solvent ID <wtA--dt HP-os:--
Prep. Date ou (rJ'f)....3-
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Syringe I D: M ~ .... .-o; "'C::"--f .f
Comments:
REPORT ID: 23E133 Page 197 of 345
Page 68
STANDARDS LOG FOR VOLATILES
Book No: SVl-41
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SV1-41-68-01
S\1 l-";~ · & ~ -11 .t.\.u,oroho .. -tll.H Mlx 1AJ00Dnw. iJDML t;7)~wt Name "'I<H~ (Wf,Z.)
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MeOH Solvent ID (WlA -hll· 11-og -----Prep. Date 'Z/1.'1 11.-1 ----Exp. Date 'l Jt..1 Jl, 1 -1--.. Prepared By VL
_) Syringe ID: 11W:+t=-i)t ------01....01~ ,-----
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&Vh~~-OHi0 C.urbofl 'DisuWfd e WOOvDM soc>~ Wipj?_rh Name cs"l-u..o_)
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) MeOH Solvent ID SWfA.-Oll-(%-0&
L Prep. Date Z-1741'2..3
/_ Exp. Date ~~~~h.<
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/
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SIW3~-Ot-60 to.vloon o < Sl-l l-Pt·rie ?OOOQPtn ;-{)0~ L5D>?V'ffl Name
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/
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REPORT ID: 23E133 Page 198 of 345
Page 73
STANDARDS lOG FOR VOLATILES
Book No: SV1-41
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID
~"-\-?~-ot\-oG. I r D-~.lmrf.r, 11. .Lurva . ..uR.d I 'Lrtl .) ~101-1 'tWA.LL ~J,o., Name
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o !?/ ,.. -:J-I l-~ .:>t7 ~~)4--MeOH Solvent ID
Prep. Date -----Exp. Date -----Prepared By cY(}
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..L -10-b\ \1 i'vlul
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MeOH Solvent ID SWIA·OII.If·O i
Prep. Date ~/1/L\ --~ Exp. Date ("/~ih)
-I> Prepared By Vl---______....-
~ Syringe 10: M.W :lf'> -01-1 I
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SV 1-1B -t>£. -0\-~ 'l."O n .U.lA '7AJIJfJOP'fVI l.~r""t.. ~ti>Pom Name G.M h•>
J... -11'1-{J) \1 i1111 I ·J n,;,+n,t-r J,... J.. f Final Volume IO lt\L
MeOH Solvent ID < \l.IIA .1} II ·lf·D8
~ Prep. Date ?,./'1/lJ ----... Exp. Date t; /'Z\/1:'1
) Prepared By VL
~ Syringe ID: H~V:1?~ -0 HI
~
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r--
'\1\..... "?/ lf/Z--3
REPORT ID: 23E133 Page 199 of 345
II
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-7,~-61.-1~
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-7~-Ill.-lf
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..
Parent Standard Name Cone. Aliquot Final Cone.
~1-0{) \'Mlltl WI i ')1 Z.OIJ/lpfl•"' 2)1)-.ML \DovWI
co.l,'fulfVIt''ll o~vqel'l.f). k tvli\1 l 1
1.-C..l~N~ "---"--
l-r: h ltwu \1 QJ( 0.11\l I fJDD VIII'>'\ OSmL
\.1..,1 -11"\1!1 z. <>no Pll\'V\ "l1JO.N'L 'IJ-
r~A 9 ~~ OO~pM .).. I o Oil p f'""
-->------------/
'-----VL 12-/ f,./'Yt-
Parent Standard Name Cone. Aliquot Final Cone.
"l'U.tMJ WUArilmix 7..-000 PDl'~'l 1-'\I>.ML c;llpp~
~ttlt'hv-lilt'~ ~WdtMI-<-»1i~ I ,I l
'1.-G\t'N't.
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\, ~ "\ -Th'B It GOp~...,. ~~ . .MIL -!..,.
'1\'JA l)l).OOD~nv"' ..L. 10 OODPI'l'\
>
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<61(o-o W\IA (,I WI i )I! ·t,toODvoVV\ 1. 'iO.ANL. 4'1J DOYI'\
C lllil-Nn ,·rA n../ 1"',n.o~t. WI-I \1 I' I
1-c,\e.vt J._ -L
\-/.h l01mh~.I{/JMI j {)ll01JOVI'\ () •~IYIL
1.~-1-H'\l; .• '2-QJOvo,,, Z.tn>A.-Vt. \t,...
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rJ,Lth>nitnlL J._. 7,..1::;V.»L <;l>DI>DM
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Page 25
Book No: SVl-41
Standard ID SV1-41-25-01
Name '6~~{) {2/')
Final Volume IOWIL
MeOH Solvent ID <;wtA-011~1\-0¥'
Prep. Date 17.../lbtn.
Exp. Date b/1 1.>/1-~
Prepared By Vt
Syringe ID: M~V-D'?-01-. I)
Comments:
Standard ID SV1-41-25-02
N<Jme '61-lP<> (2")
Final Volume tow.L
MeOH Solvent ID ~ WIA ··D\1-l \·Of
Prep. Date 1'2../ll:./Vt.-
Exp. Date l:. /.lb/VJ,
Prepared By VL
SyringeiD: MSV-D}~D/-11
Comments:
Standard ID SV1-41-25-03
Name ~UrAlh!){<bll)
Final Volume 16 lVI L
MeOH Solvent ID c.w \A--011-~r -ol
Prep. Date . ll../ f 0/"t-1.
Exp. Date ~I lb/'1 ... '1
Prepared By Vl.
Syringe ID: MSV~(l},-Oh-11
Comments:
REPORT ID: 23E133 Page 200 of 345
Page 3
STANDARDS LOG FOR VOLATILES
Book No: SVl-42
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-42-03-01
~Vl-~f-01-0'1-T/t_A 1 0 0 0-povn D•\M'-t\0'0111"> Name 'TAA (t6)
Final Volume 1..0~ L
MeOH Solvent 10 t.WlA-otHf-oi ----.. Prep. Date l.f /Zlif 1-l
'"" Exp. Date 10/1411..1
~ Prepared By VL -~ Syringe ID: MW, 0~ 1>1-ll ----~
/ Comments:
(
w.. ij/ll.t/H
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-42 -03-02
\'\11-?8-01-1) '22. LL-Tl-1 P IOODonvn IDO.~L SOOOW\ Name n.4-Tl"tl'(l.•)
Final Volume 'l. .C>tt~L
MeOH Solvent 10 _(,wlA-bl\-ti·Ot ------Prep. Date l1Jz.4n1
~ Exp. Date to/14 lVII
'). Prepared By VL .------v Syringe ID: ~~v.v~O") -ol-l-1
-------
f------~ Comments:
/
(
\.L ~ ~ 'N/2.:~
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-42 -03-03
_i'J 1-2'6-Dtl-11 \lihii\JJ.. <.Qilll ·1~1lOW\ l,OWIL 1Al>MM Name IL.d--llA {1! )
J.., -ll-0~ f.H.ro\ fiVI 4:_ AitllhtH"ttiw. "J.A)(ll) IWhM U.Sml.. ..L. Final Volume ID~L
MeOH Solvent 10 ~~IAvOII-If-Di ---1---Prep. Date Lj /2~/1"1 -"::) Exp. Date ~/l}
.....------Prepared By "vt0 VI.. ... ,l~~ '2')
----~ ---Syringe ID: Mw-0?,-oHr
/
L Comments:
(.__
\It Lj 114 n.:~
REPORT ID: 23E133 Page 201 of 345
Page 65
STANDARDS lOG FOR VOlATILES
Book No: SVl-41
-----------------------------~...:..:.:...;..:.........c~..:;.._ ______ """"';,.,.·····, ...
Parent ID Parent Standard Name Co~~ ...... Aliquot1 FinaiM?Ilc. Standard ID
~ -<J.,'K -0 6 --{)(, {4-+~ (\11"\ ~r (o'~ ~ Name
J./ lo--o1 ~ ..IM\Jh '&..! /'uP f (Ll ~ btm1Y (-n-v ,J.; Final Volume
{)
MeOH Solvent ID --Prep. Date --r----Exp. Date
'""" Prepared By
./ Syringe ID: M_9v-0;-'1) I -t:r-
_./ .-----
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---------f-" c: () '1/JG fr"h70
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard ID SVl-41-65-02
I t-.A-~ -.)b-1Y 7.. -l>1u f'ltvt4'l {rflA \)')1-'-('~ ~~ Name
.;----_
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-----Exp. Date
~ Prepared By
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--------------Comments: -----"--m~L M}..-,. CJVJ ,.
Parent ID Parent Standard Name COfl!Nw,., Aliql;lqt Finah<1)l&.,c. Standard ID
~ -'>,~ ~ o l ~ r ') G-u.lr, kt lLfl ,__ (~ .ho & Name
f a; "1 ~ Ni.feu.J n r1 ~.k. ( r I Final Volume
,\/ l)(r{O M.Q ~c\l ~ r R.l rJ ,0 k.e\'.Lt_ ,( L--\.~ l--MeOH Solvent ID
u u Prep. Date
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~ Prepared By
Syringe ID: M)fv'.,;.-v/ '"'tf .-----
------.-----Comments:
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1.... d't { rG ( '~-'J ~()()
REPORT ID: 23E133 Page 202 of 345
CPI
Date manufactured: 5/5/2022
Original issue date: 5/5/2022
Catalog No.: Lot No.: Storage:
Z-G34 481102 :S -10 oc
-020200-04
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
PIT Methanol
Expiration
Date:
4-May-2027
Carbon Disulfide Solution, 5,000 mg/L, 1 ml
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, m!!IL
carbon disulfide 75-15-0 99.9 200.24.1P 5044 ± 250
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS.' It may aslo be used for various US EPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for .
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-O:OI8ln(x+31) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E133 Page 203 of 345
Certificate of Analysis Page 2 of 2
Catalog No.: Z-034-020200-04 Lot No.: 481102 Expiration Date: 5/4/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-011. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc= ...fL,u;2 where U; are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 4-May-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Paul Johnson
Quality Control Supervisor
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 204 of 345
CPI
INTERNATIONAL
Date manufactured: 11/16/2022
Original issue date: 11/16/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
Z-034 492307 ::::: -10 oc PIT Methanol
Expiration
Date:
20-Nov-2025 Vinyl Acetate Solution, 2,500 mg/L, 1 mL
-020232-10
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mt!IL
vinyl acetate 108-05-4 99.9 232.7.1P 2496 ± 160
•Not a ctrtified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCJMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCJMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y"3·202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E133 Page 205 of 345
Certificate of Analysis Page 2 of 2
Catalog No.: Z-034-020232-10 Lot No.: 492307 Expiration Date: 11120/2025
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-011. This is consistent with the intended use ofthis CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc = ~Iui 2 where ui are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 20-Nov-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association ofLaboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist II
Certified By:
Dominique Lindner
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 206 of 345
Trusled ;\tlswt:r:;
Product Name: VOC Gas Standard
Product Number: DWM-544-1
Reference Material Certificate
Product Information Sheet
Storage Conditions: Store Frozen (-25° to -1 0°C).
chloroethane 2006 ± 10 ~g/ml
chloromethane 2009 ± 10 ~glml
dichlorodifluoromethane 2009 ± 10 ~g/ml
trichlorofluorometl:l~ne-2008 ± 10 ~g/mL
vinyl chloride 2010 ± 10 ~g/ml
Matrix: methanol (methyl alcohol)
Description:
ISO 17034
Lot Number: 0006685354
Lot Issue Date: 13-Jun-2022
Expiration Date: 31-Jul-2025
000075-00-3 RM00065
.000074"87-3 RM12571
000075-71-8 RM05289
0.00075-69-4 RM00017
000075-01-4 RM05458
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Traceability:.
The balances used for these measurements are calibrated with weights traceable to NI~3T in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delayfor the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Page: 1 of 2
CSD-QA-015.1 ISO 17025
REPORT ID: 23E133 Page 207 of 345
Agilent
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
~~~F!!_;~~~i~~!!i;i0:'!:~ii!~.~~~~; :~~::~:~'-;!
ACCAlZOITE:;;:D
·-··~-~-----···-
ru:F{:IIf:NCt.MI\"TI:fiiJ\l.
f.lllOUUCf.H
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV/SUD registered ISO
9001:2015 Quality Management System. Cert# 951215321
Page: 2 of 2
www.agllent.com/quality/
CSD-QA-015. 1
Sample lot approver:
/t:\(2
U(( ti '2 0 0 LA<f1? {)_u_c)_
Monica Bour·geois
Qi\115 R{:"!presentativr~
ISO 17025
REPORT ID: 23E133 Page 208 of 345
CPI~
lNTERNATIONAL
Date manufactured: 4/14/2022
Original issue date: 4/14/2022
Catalog No.: Lot No.: Storage:
Z-G34 479712 ::;-lO"C
-126047-01
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
6VI -6o-O/-oo
Certificate of Anal • SIS Date Received:
Page 1 of 5 Rev 0
Solvent:
Pff Methanol
Expiration
Date:
16-0ct-2023
Description:
Custom Volatiles Mix, 73-6047, Various
Concentrations, 1 mL
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mi!/L
2-nitropropane 79-46-9 97.7 219.7.1P 2003 ± 110
ally I chloride 107-05-1 98.9 227.1.2P 1995 ± 120
benzene 71-43-2 99.99 146.1.9P 2003 ± 110
bromobenzene 108-86-1 100 147.7.1P 2000 ± 140
bromochloromethane 74-97-5 99.7 148.1.3P 2008 ± 110
bromodich1oromethane 75-27-4 98.7 149.1.11P 1996 ± 110
bromoform 75-25-2 99.3 150.7.2P 1995 ± 110
n-buty !benzene 104-51-8 99.2 151.7.3.2P 1984 ± 110
sec-butylbenzene 135-98-8 99.5 152.1.2.1P 2007 ± 110
tert-buty1benzene 98-06-6 99.9 153.29.1P 2004 ± 110
carbon tetrachloride 56-23-5 100 154.9.1P 2005 ± 110
chlorobenzene 108-90-7 99.9 155.29.1P 2008 ± 110
2-chloroethanol 107-07-3 98.5 217.1.2.1P · 2006 ± 120
chloroform 67-66-3 99.8 156.7.1P 1998 ± 110
chloroprene 126-99-8 98.9 315.5.22P 1982 ± 140
2-ch1orotoluene 95-49-8 99.5 157.7.1P 2014 ± 110
4-chlorotoluene 106-43-4 99.9 158.9.3P 2015 ± 110
REPORT ID: 23E133 Page 209 of 345
Certificate of Analysis Page 2 of 5
Catalog No.: Z-034-126047-01
cis-! ,2-dichloroethy lene
dibromochloromethane
1,2-dibromo-3-chloropropane
I ,2--dibromoethane
dibromomethane
1 ,2-dichlorobenzene
I ,3--dichlorobenzene
1,4-dichlorobenzene
cis-! ,4--dichloro-2-butene
trans-! ,4-dichloro-2-butene
I, 1-dichloroethane
I ,2-dichloroethane
I, 1-dichloroethylene
trans-! ,2-dichloroethylene
dichlorofluoromethane (Freon 21)
I ,2-dichloropropane
I ,3-dichloropropane
2,2-dichloropropane
I, 1-dichloropropylene
cis-! ,3-dichloropropylene
trans-! ,3-dichloropropy Jene
I ,4-dioxane
ethyl ether
ethyl methacrylate
ethylbenzene
Manufactured By:
Brian Stokes
Production Chemist I
LotNo.: 479712
156-59-2 98.5
124-48-1 98.6
96-12-8 98.6
106-93-4 99.9
74-95-3 99.8
95-50-1 99.8
541-73-1 99.8
106-46-7 99.9
1476-11-5 96.2
110-57-6 98
75-34-3 98.1
107-06-2 99.9
75-35-4 99.98
156-60-5 99.7
75-43-4 98
78-87-5 99.7
142-28-9 100
594-20-7 99
563-58-6 99
10061-01-5 99.5
10061-02-6 99
123-91-1 99.93
60-29-7 99.8
97-63-2 99.5
100-41-4 100
Certified By:
Tyler Sherman
Quality Control Chemist I
Expiration Date: 10/16/2023
!66.1.7.1P 2000 ± 110
159.1.8.1P 2001±110
160.7.2.3P 1999 ± 110
161.9.1P 2002 ± 110
162.1.2P 2012 ± 120
43.7.1P 2006 ± 110
44.1.2P 2008 ± 110
45.29.1P 2030 ± 110
209.1.4.1P 1966 ± 110
20!.1.17P 1996 ± 110
!63.247.3.2P 1985 ± 120
!64.!58.1P 2001 ± !10
165.1.4P 2001 ± 110
167.9.!P 2000 ± 110
986.5.4P 1960 ± 140
168.8.l.IP 1994 ± !20
169.7.3P 2034 :1:140
170.158.1.1P 1999 ± 120
171.1 58.2.3P 1999 ± 120
172.7.6.1P 2003 :1: 110
173.7.11P 2002 :1: 110
223.1.4P 39940 ±2000
226.9.1P 1993 :1: 110
216.7.1P 2037 :1: 110
174.7.1P 2001 :1: 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 210 of 345
Certificate of Analysis Page 3 of 5
Catalog No.: Z-034-126047-01
hexachlorobutadiene
iodomethane
isobutyl alcohol
isopropylbenzene
4-isopropyholuene
methyl acrylonitrile
methyl methacrylate
methyl acrylate
methylene chloride
naphthalene
nitrobenzene
propionitrile
n-propylbenzene
styrene
I, I, I ,2-tetrachloroethane
I, 1,2,2-tetrachloroethane
tetrachloroethylene
tetrahydrofuran (THF)
toluene
1 ,2,3-trichlorobenzene
1,2,4-trichlorobenzene
1, 1,1-trichloroethane
1,1 ,2-trichloroethane
trichloroethylene
1 ,2,3-trichloropropane
Manufactured By:
Brian Stokes
Production Chemist I
LotNo.: 479712
87-68-3 98
74-88-4 99.9
78-83-1 100
98-82-8 98.9
99-87-6 99.9
126-98-7 98
80-62-6 99.8
96-33-3 99.9
75-09-2 99.99
91-20-3 99.8
98-95-3 100
107-12-0 99.8
103-65-1 99.7
100-42-5 99.5
630-20-6 99.8
79-34-5 99.6
127-18-4 100
109-99-9 99.99
108-88-3 100
87-61-6 99.8
120-82-1 99.6
71-55-6 99.6
79-00-5 99.6
79-01-6 98.1
96-18-4 99.5
Certified By:
Tyler Sherman
Quality Control Chemist I
Expiration Date: 10/16/2023
47.158.3.1P 2003 ± 120
203.29.2P 2000 ± 110
220.7.2P 39730 ± 2000
176.9.1P 1998 ± 120
177.9.3P 1998 ± 110
212.286.1.1P 19960 ± 1100
231.7.3P 2016 ± 120
349.1.1P 2015 ± 120
178.271.1P 2010 ± 110
26.9.1P 1996 ± 110
94.7.1P 1985 ± 110
218.7.3P 19900 ± 1000
179.7.2.2P 1999 ± 110
180.9.4P 2001 ± 110
181.7.2.9P 2005 ± 110
182.1.3P 2001 ± 120
183.1.2P 2001 ± 110
299.271.2P 2006 ± 110
184.48.1P 2003 ± 110
185.1.2P 1996 ± 110
54.29.1P 1992 ± 110
187.247.1.3P 1995 ± 110
195.7.1.6P 2001 ± 110
188.29.1P 1998 ± 120
189.1.3P 2009 ± 110
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 211 of 345
Certificate of Analysis Page 4 of 5
Catalog No.: Z-G34-126047-0l Lot No.: 479712 Expiration Date: 10/16/2023
I, I ,2-trichloro-1 ,2,2-trifluoroethane (Freon 113) 76-13-1 99 270.158.3P 1996 ± 120
1 ,2,4-trimethylbenzene 95-63-6 98.7 190.7.1P 1974 ± 110
1 ,3,5-trimethylbenzene 108-67-8 99.5 191.7.1P 1962 ± 110
m-xylene 108-38-3 99.7 193.7.1.2P 2001 ± 110
o-xylene 95-47-6 99 192.29.3P 2004 ± 120
p-xylene 106-42-3 99.9 194.7.1P 1998 ± 110
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+3l) + 0.1157) + 636.54y·3·202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. L S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
'JYler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 212 of 345
Certificate of Analysis Page 5 of 5
Catalog No.: Z-034-126047-01 Lot No.: 479712 Expiration Date: 10116/2023
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Instituie of Standards and Teclmology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc =the combined uncertainty Uc = ...f"Lu;2 where U; are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 16-0ct-2023
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 213 of 345
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: OGAD-001
Description: Oxygenate Gasoline Additive Standard
Lot: 222011266
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Component
MtBE
EtBE
Isopropyl ether
TAME
t-Butanol
Signal Word: Danger
CAS#
1634-04-4
637-92-3
108-20-3
994-05-8
75-65-0
Date Certified: Jan 19, 2022
Expiration: Jan 19, 2025
Sample Size: 1 mL
Components: 5
Storage Condition: Refrig (0-5 °C)
Certified Reference Material • ~""'~-
AR·1463
Purity%
Tel [phone]
Fax [phone]
www.AccuStandard.com
Certified Analyte
Concentration•
(iJg/mL)
1997
2002
2010
1983
9965
This Certified Reference Material was verified 1~·-a~an®..\iit~ ISO/IEC 17025
A product with a suffix (-1A. -2B, etc. oP01;.:..02, ete;)'~jjtii!'fot number has had Its expiration date extended and is identical to the same lot number without the ~uffix.
• All weights are traceable through Nt~T, Te~t Nq;~s84i2S9871·17
' Certified Analyte Concentration = Pii.tJ!Y: x Prep~~d Concentration.
The Uncertainty associated wiili'!Jiii'ce·~tiii~ifliidrii:~ntratlon reported on this certificate is :t2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard devlatiQn equal to ll!a 'pi>sl!ive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 Is chosen usiri~:.l!pproxii'ii_iitely a 95% confidence level.
Labels and Cl11'\l!IQI1tes follow.V.~, CoOYenUons In reporting numerical values: A comma (,)Is used to separate units of one-thousand or greater. A period (.)Is used as
a decimal p'ia'c-&htlilter-· .,_, .. · ·· · ·
The lnforrriati~il jln this ~rilfit:ate may not be reproduced wHhout the express permission of the manufacturer. Sea reverse side for additional information
Hazard lnform~ii: p]ijj!~~ fui~r to the SDS for Information regarding the hazards associated with using this material.
This product was:J!ti\~ared according to In-house procedures and Is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, JSOJIEC 17025 and certified to ISO 9001:2015 OR-QRGJIN0-001
Rev. 7/20
REPORT ID: 23E133 Page 214 of 345
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the. front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product Is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u8 = .f(u(V))2 + (u(m))2 + (u(JV))2 + (u{R0))2 This
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 Is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 215 of 345
~PI
INTERNATIONAl.
Date manufactured: 8/24/2022
Original issue date: 8/24/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
(707)545-790 1 Fax
Certificate of Anal sis Date Received:
Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-G34 492308 ::::-10 oc
Date:
23 -Aug-2027 2-Chloroethyl Vinyl Ether Solution, 2,000 mg/L, l mL
Pff Methanol
-020145-02
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound
CAS No. Purity(%) Neat Material Lot No. Concentration, mi!'IL
2-chloroethylvinyl ether
110-75-8 99.8 145.1.5P 2010 :1: 110
•Nota certified volue
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various US EPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+3l) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E133 Page 216 of 345
Certificate of Analysis
s v t--38~o~-n./
Page 2 of 2
Catalog No.: Z-034-020145-02 Lot No.: 492308 Expiration Date: 8/23/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=Iru.,: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, U 0 =the combined uncertainty Uc = --JL,llt 2 where lit are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Aug-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By: Certified By: Released By:
h-b C0U S~M~
Sanquetta Coakley Dominique Lindner Susan Mathews
Production Chemist I Quality Control Chemist I Quality Control Team Lead
REPORT ID: 23E133 Page 217 of 345
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-8010R-1-04-10X
Description: 1-Chlorohexane
Lot: 221031011
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Signal Word: Danger
Component
1-Chlorohexane
This Certified Reference Material was verified ~~:W~an~;~ ISO/IEC 17025
Date Certified: Mar 3, 2021
Expiration: Mar 3, 2031
Sample Size: 1 mL
Components: 1
Storage Condition: Ambient (>5 oc)
Certified Reference Material
Tel [phone]
Fax [phone]
www.AccuStandard.com
A product with a suffix (-1A, -28, etc. 0r ~~1;~. ~t~¥6,iH(~itot number has had Its expiration data extended and Is ldantlcel to the same lot number without the suffix.
• All weights are traceable through NISJ; Te-~t l'!q; ~s4i2s9B7H 7
. ' Certified Analyte Concentration " Pofitii¥ Prep~~d Concentration.
The Uncertainty associated wli!i ~'certlfliid' ®hcimtration reported on this certificate Is :1:2.4%. This value is the combined expanded uncertainty and represents an
estimated standard devlattOj(equal to.the paiiiilve square root of the total variation of tha uncertainty of components. A normal distribution Is assumed and a coverage
factor of Ko:2 Is chosen usti\iJ,approxfni!liety a 95% confidence level.
Labels and Ciirtlfltates follow,iJ.:a, Cliiwentions In reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period(.) Is used as
a decimal piii'ilii mai-l!eJ; ·.· .· ... ·.· .. . .
The lnformalioiJ,'on thiS..~)'tlfi!;l!la may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard lnform~ii6:n; Pt~ilse refer to the SOS for Information regarding the hazards associated with using this material.
This product was''pi:ilpared according to In-house procedures and Is guaranteed to ba homogeneous.
Certified By:
Larry Oecl<er, Organic QC Manager
Page 1 of 1 • Rev. 1
For use In routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001:2015 OA·OAG/INCHl01
Rev. 7/20
REPORT ID: 23E133 Page 218 of 345
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated dally using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the. front of this certificate. Class A glassware
is used in the manufacture and quality control of ail standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on !tm label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .{(u(V))l + (u(m))2 + (u(IV))2 + (u(RO))l I his
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 219 of 345
CPI
INTERNATI.ONAL
Date manufactured: 6/24/2022
Original issue date: 6/24/2022
Catalog No.: Lot No.: Storage:
Z-034 484154 :::-10 oc
-020869-08
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 2 Rev 0
Solvent:
Prr Methanol
Expiration
Date:
23-Jun-2027
Description:
1,2,3-Trimethylbenzene Solution, 2,500 mg!L, l mL
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography ( GC) or gas chromatograph/mass spectrometry ( GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, m!!IL
1 ,2,3-trimethylbenzene
526-73-8 92.7 869.8.4.1P 2536 ± 140
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various US EPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled% change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y'3202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -1 0 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E133 Page 220 of 345
Certificate of Analysis
~vt'"~og--L8
Page 2 of 2
Catalog No.: Z-034-020869-08 Lot No.: 484154 Expiration Date: 6/23/2027
(95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISO/IEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, Uc = the combined uncertainty uc = -YI.U; 2 where u; are the individual
uncertainty components for characterization, transportation, homogeneity, andshelflife.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 23-Jun-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Brian Stokes
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 221 of 345
CPI
INTERNATIONAL
Date manufactured: I 0115/2020
Original issue date: I 0/15/2020
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • Date Received:
SIS Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-034 426643 S -1 0 Degrees
c
Pff Methanol
Date: 14-0ct-2025 t-Butyl Alcohol Solution, 50,000 mg!L, l mL
-020511-06
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mi!IL
2-methyl-2-propanol 75-65-0 99.8 511.7.1P 49900 ± 2500
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 oc and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E133 Page 222 of 345
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-020232-10 Lot No.: 476834 Expiration Date: 3/6/2025
(95% confidence) values listed are detennined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is detennined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perfonn daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
are checked daily in accordance to in house procedure 02-LB-G-002. Balances are calibrated annually by an ISOIIEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
continued by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc = ..JL,U; 2 where ui are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short tenn and long tenn testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 6-Mar-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Melissa Workoff
Production Chemist I
Certified By:
Tyler Sherman
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 223 of 345
CERTIFIED REFERENCE MAT~~~-~~~---. ·-··-·--·~.so~· ~
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30006
Certificate of Analysis
-·"· ·. ,,.
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0183812
Description : VOA Calibration Mix #1
VOA Calibration Mix #1 5,0001-Jg/mL, P& T Methanoi/Water(90:1 0),
1mL/ampul
Container Size : 2 mL ------------------Pkg Amt: > 1 mL -----------------
Expiration Date : July 31, 2025 Storage: ooc or colder
---------------------Ship: Ambient
~Motorl>lfrodUcil'
Ca:tifi<atU321l.OI
CERTIFIED VALUES
,,~, .Gray, C.o.nc. . . ! ·"· E.xpan~e_d Uncertainty -·
·. (weight/volume) (95% C.L.; K=2)
Acetone 5,031.8 Jlg/mL +I-29.2555 Jlg/mL Gravimetric
CAS# 67-64-1 (Lot SHBN366!) +I-303.5928 )lg!mL Unstressed
Purity 99% +I-304.3136 JlglmL Stressed
2 2-Butanone (MEK) 5,041.0 )lglmL +I-29.3088 )lg!mL Gravimetric
CAS# 78-93-3 (Lot SHBN2844) +I-304.1459 )lg/mL Unstressed
Purity 99% +I-304.8680 )lg/mL Stressed
3 4-Methyl-2-pentanone (MIBK) 5,041.5 Jlg/mL +/-29.3117 )lg/mL Gravimetric
CAS# 108-10-1 (Lot SHBN3601) +I-304.1760 )lg/mL Unstressed
Purity 99% +I-304.8982 Jlg/mL Stressed
4 2-Hexanone 5,026.8 )lglmL +I-29.2264 JlglmL Gravimetric
CAS# 591-78-6 (Lot MKCM4072) +I-303.2911 )lg/mL Unstressed
Purity 99% +I-304.0112 )lg/mL Stressed
Solvent: P &T Methanol/Water (90: I 0)
CAS# 67-56-117732-18-5
Purity 99%
01-Aug-2020 rev. 1 of 3
REPORT ID: 23E133 Page 224 of 345
Cok.!~!l=
105m x O.S3m,; x 3.01lm
Rtx·S02.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240'C
fl rC/min. (hold 5 min.)
lnj. Temp:·
200"C
Det. Temp:
2SO'C
DeL Type;.
FlO
Brlttany Federinko-Openrtlons Tech I
Clara WinciJe -Operation5 T..ehnician I
01-Aug-2020 rev.
0 5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 07-Apr-2022
Date Passed: 11-Apr-2022
Balance: B251644995
Manufactured under Reatek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2of3
REPORT ID: 23E133 Page 225 of 345
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-603-M-5X
Description: Acrolein & Acrylonitrile
Lot: 223021463
Solvent: Methanol (90%)
Date Certified: Feb 21, 2023
Expiration: Jun 21, 2023
Sample Size: 1 ml
Components: 2
Tel [phone]
Fax [phone]
www.AccuStandard.com
Water (10%) Storage Condition: Freeze (<-10 °C)
Hazards: Refer to SDS for complete safety information
Component
Acrolein
Acrylonitrile
Signal Word: Danger
CAS#
107-02-8
107-13-1
Certified Reference Material
Purity'%
86.1
99.8
Pr!)pared
Concentration'
/ml
58 0S·
50.10
This Certified Reference Material was verified in accor\i!J'nce with ISbJIEC 17025 (AT-1339) and ISO 17034 (AR-1463)
• Weight compensated to 100% purity. \-~-~·. : : ... \· .. :_\·.
Certified Analyte
Concentration'
/ml
5001
5000
A product with a suffix (-1A, -28, etc. or ;01,.-02;'~\Q;) on:l.~t!·lot number has had Its expiration date extended and Is Identical to the same lot number without the suffix.
' Certified Analyte Concentration = Plifi!y ~'Prapar~lcbri'centratlon.
The Uncertainty associated with the.~jtlfled co.~centratlon reported on this certificate Is ±2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard deviation equal to.l~e posll!v~.· square root of tha total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen using 'iJpproxlriiately a)!5% confidence level.
'All weights are traceabl!lltliough Nl!lT, ·T~~t No. 664/291344·16 & 684/292805-19
' Purity/Identity determined by one or {nora of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and.c~&lfic!iltes follo~{:i:J.i;;.{:<lii~entions
In reporting numerical values: A comma(,) is used to separate units of one-thousand or greater. A period(.) Is used as
a decimal pi~~~ marker. ' . ·.
The lnformaiion on this certincate may not be reproduced without tha express permission of the manufacturer. See reverse side for additional information
Hazard lnformatl()n;.PI.~aserafer to the SDS for Information regarding the hazards associated with using this material.
This product was .. p(epared according to in-house procedures and Is guaranteed to be homogeneous .
. ~:··.'
Certified By:
Page 1 of 1
For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001:2015 OR·ORG/IN0·001
Rev. 7120
REPORT ID: 23E133 Page 226 of 345
1. Quality Standards:
ISO 17034:2016-General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u0 = .f(u(V))l + (u(m))Z + (u(IV))2 + (u{R0))2 I his
formula represents uncertainty components from the mass, volume, short-term stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 227 of 345
CPI~
Date manufactured: 10/4/2022
Original issue date: 10/4/2022
Catalog No.: Lot No.: Storage:
Z-034 489953 :s; -10 oc
-020354-09
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 2
Solvent:
P/T Methanol
Expiration
Date:
3-0ct-2027
Description:
2-Butanol Solution, 50000 mg/L, 1 ml
Rev 0
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, m!!/L
2-butanol 78-92-2 99.8 354.7.JP 50000 ± 2600
•Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
%Change= (-0.018ln(x+31) + 0.1157) + 636.54y"3
'
202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 23E133 Page 228 of 345
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-08S-10X
Description: Cyclohexane
Lot: 219101390
Solvent: Methanol
Hazards: Refer to SDS for complete safety information
Signal Word: Danger
Component
Cyclohexane
.->..._
This Certified Reference Material was verified,~:'
CAS#
110-82-7
Date Certified: Oct 25, 2019
Expiration: Oct 25, 2029
Sample Size: 1 ml
Components: 1
Storage Condition: Ambient (>5 °C)
Certified Reference Material
"'"l.'g.:t::--
AR-1463
Tel (203)786·529Q
Fax [phone]
www.AccuStandard.com
A product with e suffix (·1A, -2B, etc. 91!~~~. t number has had Its expiration date extended and Is identical to the same lot number without the suffix.
'All weights are traceable through N~:r~st Np;,664 'a'9s71-17
.
' Certified Analyte Concentration = PW~Y •. ~ Pref.#~d Conceniratlon.
The Uncertainty associated,,~,iftJh
r
r
c
J
'
f
f
i
~
~
~
:
~
i
\
t
e
n
t
r
a
t
i
o
n

report.ed on this certificate Is ±2.4%. This· value Is the combined expanded uncertainty and represents an
estimated standard deviatlil\i;equal to.;f,l)e posi!lve square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 is chosen U~JW:,!'Pproxl\il~el
y
a 95% confidence level.
Labels and.~l·l!f.if;.J'It
e
s

folloW:U$; . .9,#\'~~ntions In reporting numerical values: A comma(,) is used to separate units of one-thousand or greater. A period(.) is used as
a decimal Pf~iili'malkv~. . '.)•f.::i'"".
The fnforma{i~}hl~\iii\
{
~
i
i
l
r
.
t
l
l
j
!
J
.
e

may not be reproduced without the express permission of the manufacturer. See reverse side for additional informalion
Hazard lnform~!!im.l;'f)~~
~
·
'
i
'
l
\
i
~
r

to the SOS for Information regarding the hazards associated with using this material.
This product wa\i~~ared according to in-house procedures and Is guaranteed to be homogeneous.
Certl«ed By:
Larry Decker, Organic QC Manager
Page 1 of 1 -Rev. 1
For use In routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOnEC 17025 and certified to ISO 9001:2015
OR·OR<li1N<J.001
Rev. 7120
REPORT ID: 23E133 Page 229 of 345
1. Quality Standards:
ISO 17034:2016-General Requirements tor the Competence of
Reference Material Producers
ISO/IEC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
s-VI-?Jg---01-n
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side.-This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an 180/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used In the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: ua = .f(u(V)F Of (u(m)F + (u(IV))2 + (u(RO))l fhis
formula represents uncertainty components from the mass, volume, short-term ~ability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 230 of 345
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-09S-12.5X
Description: Methylcyclohexane
Lot: 222081 023
Solvent: Methanol
Date Certified: Aug 2, 2022
Expiration: Aug 2, 2032
Sample Size: 1 mL
Components: 1
Tel [phone]
Fax [phone]
www.AccuStandard.com
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 •c)
Signal Word: Danger
Component CAS#
Methyicyciohexane 108-87-2
This Certified Reference Material was verified in acco.rdance with ISO/IEC 17025
Certified Reference Material
Purity%
(GC/FID)
100.0
prepared
Conce!ltr.atlon•
··NstmLt
2538
Certified Analyte
Concentration'
(lJQ/ml)
2538
A product with a suffix (-1A, -28, etc. or -01, -02, etc.) on Its lot number has had Its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test NO. 684/289871-17
1 Certified Analyte Concentration= Purity xPrepared Concentration.
The Uncertainty associated with the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen usln·g approximately a 95% confidence level.
Labels and certificates follow U.S. Conventions in reporting numerical values: A comma(,) is used to separate units of one-thousand or greater. A period(.) is used as
a decimal place marker.
The information on this· certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information: Please refer to the SDS for information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001:2015 OR·ORG/IN0·001
Rev. 7/20
REPORT ID: 23E133 Page 231 of 345
1. Quality Standards:
ISO 17034:2016-General Requirements for the Competence of
Reference Material Producers
ISO/I EC 17025:2017 -General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u3 = .f(u(V))2 + (u(m))2 + (u(IV))2 + (u(R0))2 This
formula represents uncertainty components from the mass, volume, short-term Stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 232 of 345
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
Tel [phone]
Fax [phone]
www.AccuStandard.com
~V\-~q-(0··04
CERTIFICATE OF ANALYSIS
Catalog No: S-6524-0.25X
Description: Methyl acetate
Lot: 222031 007
Solvent: Methanol
Date Certified: Mar 2, 2022
Expiration: Mar 2, 2032
Sample Size: 1 mL
Components: 1
Hazards: Refer to SOS for complete safety information Storage Condition: Ambient (>5 oc)
Signal Word: Danger
Component CAS#
Methyl acetate 79-20-9
This Certified Reference Material was verified in accordance with ISO/IEC 17025
Certified Reference Material
Purity%
(GC/MS)
100.0
Pr~pared
Concentl'atlon•
. <llglmL)
Certified Analyte
Concentration'
(!Jg/ml)
2520
A product with a suffix (·1A, -28, etc. or ·01, -02, etc.)on lis lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'All weights are traceable through NIST, Test No. 684/289871-17
' Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty associated. With the certified concentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen using approximately a 95% confidence level.
Labels and certificates follow,u:s. Con~entions in reporting numerical values: A comma(.) is used to separate units of one-thousand or greater. A period·(.) is used as
a decimal place marker.
The information. on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information; Please refer to the SDS for information regarding the hazards associated with using this materiaL
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic QC Manager
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001 :2015 OR-ORG/INO·OOl
Rev. 7120
REPORT ID: 23E133 Page 233 of 345
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001:2015-Quality Management System-Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u8 = .f(u(V))2 + (u(m))2 + (u(IY))2 + (u(R0))2 This
formula represents uncertainty components from the mass, volume, short-term ~ability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 234 of 345
~ .... RESTEK CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: (814)353·1309
www.restek.com
Catalog No. : 30003
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description : VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,000~g/ml, P&T Methanol, 1mllampul
Container Size : 2 ml ------------------Pkg Amt: > 1 ml ------------------
Expiration Date : September 30, 2024 Storage: ooc or colder
@;
(A"CC'ieolTi"DJ
ISO i7034·A....,dKed
Refereoc.o ~~~10111 f'roctucar
Certfftclto t~222.0l
... :::,\ '·l···
0
ISOnEC 17025 Acc:rediled
Toi!l~g l>borarory
Certifiote 13222.02
CERTIFIED VALUES
1-Bromo-4-fluorobcnzcne (BFI:l)
CAS# 460-00-4 (Lot 2040 I KO)
Purity 99%
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
Grav. Cone.
(weight/volume)
5,030.0 ~g/mL
Expanded Uncertainty
(95% C.L.; K=2)
+!-29.5189
+I-'282.0557
+/-288.6541
j.tg/mL
J.lg/mL
j.tg/mL
Gravimetric
Unstressed
Stressed
REPORT ID: 23E133 Page 235 of 345
Column:
105m x 0.53mm x 3.0~rn
Rtx·502.2 (cat.l/10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ 8'C/min.(hold 5 min.)
lnj. Temp:
200'C
Oet. Temp:
lSO'C
Oet. Type:
FlO
Walker Workman-Operations technician I
10 15
Minules
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Dale Mixed: 27-Jun-2019
Dale Passed: 01-Jul-2019
Balance: 1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
REPORT ID: 23E133 Page 236 of 345
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/(JECD,
GC/MS, LC/MS, Rl, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
Purity of isomeric compounds is reported as the sum of the isomers.
Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified combined stressed
uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombined stressed = k Ufiravimetric + U~omogenetty + u;tora 9 e stabHity + u;,;1111 tn9 stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time
intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product If it was
stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at
www.restek.com/Contact-Us for use recommendations if your shipment was in-transit for more than 7 days at non-
standard temperature conditions.
Apply the certified combined unstressed uncertainty value if the product was received under standard shipping
conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard
conditions as specified below.
Label Conditions Standard Conditions Non-Standard Conditions
25°C Nominal (Room Temperature) < 60°C ~ 60°C up to 7 days
10°C or colder (Refrigerate) <40°C ~ 40°C up to 7 days
ooc or colder (Freezer) < 25°C ~ 25°C up to 7 days
Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed,
separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values
are available by contacting Restek Technical Service at www.restek.com/Contact-Us.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
• Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampules. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
REPORT ID: 23E133 Page 237 of 345
CPI
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
<;v \-~'3 --ol(-o s
Date Received: Date manufactured: 7/13/2022
Original issue date: 7/13/2022 Certificate of Analysis Page 1 of 2 Rev 0
Catalog No.: Lot No.: Storage:
Z-G34 484785
-122455-05
Certified Values:
Solvent:
PIT Methanol
Expiration
Date:
12-Jul-2027
Description:
Method 8260 Internal Standard Mix, 3-30, 2,500
mg/L, I ml
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity(%) Neat Material Lot No. Concentration, mi!/L
chlorobenzene-d5 3114-55-4 99.5 128.120.1P 2504 ± 130
I ,2-dichlorobenzene-d, 2199-69-1 99.7 247.29.3P 2514 ± 130
I ,4-difluorobenzene 540-36-3 99.3 129.158.1.2P 2523 ± 140
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled% change per day can be calculated using the following:
%Change= (-0.0 18ln(x+31) + 0.1157) + 636.54y"3
·
202
where x =boiling point of the most volatile analyte in the mix (degrees K)
y =boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 °C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
REPORT ID: 23E133 Page 238 of 345
Certificate of Analysis Page 2 of 2
Catalog No.: Z-G34-122455-05 Lot No.: 484785 Expiration Date: 7/12/2027
Method of Preparation:
All weights arc traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimctriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements:
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal ampule. Once
opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated using NIST
traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department of
Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology(NIST). Balances
arc checked daily in accordance to in house procedure 02-LB-G-002. Balances arc calibrated annually by an ISO/IEC
17025:2017 and ISO 17034:2016 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance with internal
procedure 02-QS-0 11. This is consistent with the intended use of this CRM. The homogeneity of this product has been
confirmed by procedures consistent with ISOIIEC 17025:2017 and ISO 17034:2016.
Hazardous Information:
Refer to MSDS
Calculation of Uncertainty:
The following equations are used to calculate the value of the expanded uncertainty: u=kuc: u=Expanded Uncertainty, k= the
coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty u 0 = '/'f.u;2 where u; are the individual
uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified value.
These tests include the effect of temperature and packaging on the product. This standard is guaranteed until the following
date: 12-Jul-2027
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO 17034:2016
Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American Association of Laboratory
Accreditation (A2LA).
Manufactured By:
Bradley Richter
Production Chemist I
Certified By:
Jared Ball
Quality Control Chemist I
Released By:
Susan Mathews
Quality Control Team Lead
REPORT ID: 23E133 Page 239 of 345
~ ....
RESTEK
11 0 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30240
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic plus
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0192204
Description : 8260A Surrogate Mix
8260A Surrogate Mix 2,5001Jg/mL, P&T Methanol, 1mUampul
Container Size : 2 mL ~~--------------
Pkg Amt: > 1 mL --~~-----------
Expiration Date: December 31, 2027 Storage: o•c or colder
Ship: Ambient
CERTIFIED VALUES
Expanded
· Elution Compound CAS# Lot# Punty Grav. Cone. Unce11ainty *
Order (weight/volume) (gS% C.L.; K=2)
Dibromofluoromethane 1868-53-7 022013 99% 2,517.6 J.Lg/mL +I-141.4279
2 1 ,2-Dichloroethane-d4 17060-07-0 PR-32845 99% 2,507.6 J.Lg/mL +I-140.8661
3 Toluene-d8 2037-26-5 I-27008 99% 2,511.4 J.Lg/mL +I-141.0796
4 1-Bromo-4-fiuorobenzene (BFB) 460-00-4 184975 99% 2,517.8 J.Lg/mL +I-141.4391
* Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
01-Nov-2022 rev. 1 of3
REPORT ID: 23E133 Page 240 of 345
Column:
105m x 0.53mm x 3.01'm
Rtx-502.2 (cat.#10910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240'C
@ B"C/min. (hold 5 min.)
lnj. Temp:
200'C
Det. Temp:
250"C
Det. Type:
FlO
Split Vent:
40ml/min
lnj.Vol
11'1
f. .. i'
r;}/*jJ/.. 1~"14Jr~·
Daniel Wasson • Operations Tech I
Christie Mills· Operations Tech II· ARM QC
01-Nov-2022 rev.
0
Quality Confirmation Test
l
5 10 15
Minutes
20 25 30
This chromatogram represents a general set of testing conditions chosen for product
____ _i:IC®Pla.D~ For .QRtimal results in your lab, conditioos.should.be.adJustedJor your
specific instrument, method, and application.
Date Mixed: 02-Dec-2022 Balance Serial#
Date Passed: 06-Dec-2022
1128342314
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2 of 3
REPORT ID: 23E133 Page 241 of 345
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
• Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
• Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/!JECD,
GC/MS, LC/MS, Rl, and/or melting point.
• Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
• Purity of isomeric compounds is reported as the sum of the isomers.
• Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
• The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombtned uncertatnty = k 2 2 2 ' 2
Ugravtmetric + Uhomog<m.,;ty + Ustorag11 stabtltty + Ushtpptng stabtltty
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
• The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
• Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
• Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2ml ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
• If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev. 3of3
REPORT ID: 23E133 Page 242 of 345
Certificate of Analysis
Product Name: Carbon Disulfide Standard
Product Number: EPA-1012-1
Lot Issue Date: 21-Sep-2020
Lot Number: 0006557585
Expiration Date: 30-Sep-2024
Description:
This analytical reference material (RMI was manufactured and verified in accordance with an ISO 9001 registered quality system and analyte
concentrations were verified by an ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each
analyte, determined gravimetrically, is listed below.
Analyte
carbon disulfide
Matrix: methanol (methyl alcoholl
Storage Conditions: Store Frozen (-25° to -10°C).
Traceability:
CAS#
000075-15-0
Analyte lot
RM08158
Concentration ± Uncertainty
5023 ± 251Jg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3, ISO 9001, ISO 17025,
and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are calibrated against a NIST traceable
thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This AM was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is no minimum sub-sample size required.
lnten ded Use:
This AM is intended for the preparation of working reference samples for use in routine laboratory analyses, calibration of instruments, validation of
analytical methods, assessments of measurement methods. and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at zo•c to 25•c immediately after opening the container and should be processed without delay for
the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above. provided the AM is handled and stored in accordance with the
instructions given in this certificate. This certification is nullified if the AM is damaged. contaminated. or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate. Agilent will notify the purchaser.
~
ACCAEOIT£0
REFCAEHC£ MAlfR~L
PfiOOUCE.R
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with TUV USA Inc registered ISO 9001 Quality
Management System. Cert # 56 100 18560026
Page: 1 of 1
www.agilent.com/quality/
CSO-OA-015.1
Sample lot approver:
~oo.wgzORA
Monica Bourgeois
QMS Representative
TEsnNotAIIOAATORV
ISO 17025 Cert
No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
REPORT ID: 23E133 Page 243 of 345
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: c; /1"1 11-1-___
by TUV USA to ISO 9001:2015
~·--.. _________ C_e_ri_if_ic_a_te_o_f_A_n_a_ly~..,..s_is_ .. ____ R_e_v _o _ Page
Catalog No.: Lot No.: Storage:
s -10 oc 3200-G34 480677
-120016-03
Compound
bromomethane
chloromethane
chloroethane
dichlorodifluoromethane
vinvl chloride
trich lorotluoromethane
Solvent: Exp. Date:
PIT Methanol 1 1/8/2026
CAS No Purity{%)
74-83-9 99.5
74-87-3 99.7
75-00-3 99.94
75-71-8 99
75-01-4 99
75-69-4 99
Description:
ISO 17034-Method 8260 Gases,
2.000 m2/L. 2 x 0.6 mL
Compound Lot No Concentration, m2:/L
139.158.1.11' 2025 ± 7.36 mg/L
140.158.3P 2013 ± 7.32 mg/L
141.2.31' 1979 ± 6.93 mg/L
142.158.5!' 2026 or 21.46 mg/L
143.158.5.21' 20 II ± 21.3 mg/L
l44.l.3P 1998 ± 13.43 mg/L
Second Source standards are prepared according to NELAC requirements.
Certified Bv:
Samuel Garrett All weights are traceable through N. I. S, T. Test No. 822/264157-00.
Concentration (correct for ouritv) and uncertaintv (95% confidence) values
REPORT ID: 23E133 Page 244 of 345
125 Market Street
New Haven, CT 06513
USA
~ AccuStandard®
Tel [phone]
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Sv\-~~-\o -0)
CERTIFICATE OF ANALYSIS
Catalog No: APP-9-211-20X
Description: Vinyl acetate
Lot: 222111294
Solvent: Methanol
Date Certified: Nov 21, 2022
Expiration: May 21, 2023
Sample Size: 1 ml
Components: 1
Hazards: Refer to SDS for complete safety information Storage Condition: Freeze (<-1 0 °C)
Signal Word: Danger
Component
CAS#
Vinyl acetate
108-05-4
: -·:~.
Certified Reference Material
Purity'%
100.0
P,r~pared
Coneertt@.tl9n•
_,.,> .. ''trot_,
:p:-.,~,,
.. ·"""·<·:.,
Certified Analyte
Concentration'
/mL
2006
This Certified Reference Material was verifietFlirl!ccor~~~-\vith
150/IEC 17025 (AT-1339) and ISO 17034 (AR-1463)
A product with a suffix (·1A, ·2B, etc. or -01.,. -O~}~ta.) pnJi$ii~t? number has had its expiration data extended and is Identical to the same lot number wtthout the suffix.
, Certified Analyte Concentration = P~fW:,tfi'E;pa~~ll~~ritration. . . .
The Uncertainty associated with the;:ti~):tified cq~~ntratioh reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal i('ji.fill. positiv~;squarEi root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K"2 Is chosen uslr)g~pp(oxim~t(iiy~'~$#o confidence level. ·
'All weights are traceabiEd!ii'o~gh N)~r.·r~'s\ No. 684/291344-18 & 684/292805-19
' Purity/Identity determined:ii~ one o{f'iiore of ihe following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels an~:t~:r\\iJ¢.~~)0s follovi'\]:~;,,p(>;i~entlons In reporting numerical values: A comma (,)is used to separate units of one-thousand or greater. A period(.) is used as
a decimal P!~%~ m~~~t;,. ' ·
The informatii;lfi:pn this. :Certificate may not be reproduced without the express permission Of the manufacturer. See reverse side for additional information
Hazard lnforma~QillPi~ase 'tater to the SDS for Information regarding the hazards associated with using this material.
This product wa~.~fepared according loin-house proc·adures and is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic ac Manager
Page 1 of 1
For use in routine labotatory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001:2015 OR·ORGIJN()-001
Rev. 7120
REPORT ID: 23E133 Page 245 of 345
1. Quality Standards:
ISO 17034:2016 -General Requirements for the Competence of
Reference Material Producers
ISO/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories
ISO 9001 :2015 -Quality Management System -Requirements
Eagle Registrations
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u8 = .f(u(V))2 + (u(m))2 + (u(IV))l + (u(RO))l I his
formula represents uncertainty components from the mass, volume, short-term !ftability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and limit of liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 246 of 345
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 575702
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0191824
Description : Custom Revised 8260 Megamix
Container Size :
Expiration Date :
Custom Revised 8260 Megamix 2,000-40,000f.]g/ml, P& T Methanol,
1mllampul
2 ml Pkg Amt: _>_1_m_L ______ _
November 30, 2025 Storage: ooc or colder
Ship; Ambient
~··.
(AC'CRi:ti ITioJ
ISO 17034 Ac.:redftcd
P:efP.f~Ma1t>ri61F'foducf!"
C'-rtifu::ate tlllJ.Ol
~',
{Af£Reori"]P'J
ISO/lEC 11 02S Aocr-.dited
TQStlngUbor>torY
(o?l'ttflcl19 U2ll02
CERTIFIED VALUES
Dichlorofluoromethane (CFC-21) 75-43-4 12841600 99% 2,000.0 11glmL +/-69.1292
2 Diethyl ether (ethyl ether) 60-29-7 SHBP5008 99% 2,011.0 11g/mL +/-69.5094
3 I, 1,2-Trichlorotrifluoroethane (CFC-113) 76-13-1 00016133 99% 2,008.0 11glmL +I-69.4057
4 I, 1-dichloroethene 75-35-4 SHBG8609V 99% 2,001.6 f.lg/mL +!-69.9029
5 Iodomethane (methyl iodide) 74-88-4 RD220125 99% 2,007.5 11glmL +I-69.3884
6 Allyl chloride ( 3-cbloropropene) 107-05-1 RP220405A 99% 2,011.0 !lglmL +I-69.5094
7 Methylene cbloride(dichloromcthane) 75~09-2 SHBP1417 99% 2,001.6 f.lglmL +I-69.9056
8 trans-! ,2-Dichloroethene 156-60-5 MKBH9850V 99% 2,001.7 f.lglmL +I-69.9064
9 1, 1-Dichloroethane 75-34-3 760200 99% 2,001.1 f.lglmL +I-69.8864
10 Chlciroprcnc (2-cbloro-1 ,3-butadiene) 126-99-8 220712JLM 99% 2;014.0 ftglmL +I-69.6131
11 Propionitrile 107-12-0 BCCF4J67 99% 20,009.5 11glmL +I-691.5748
12 2,2-Dichloropropane 594-20-7 RD220812 99% 2,004.3 flglmL +I-70.0110
13 cis-1,2-Dichloroethcne 156-59-2 MKCP7830 99% 2,014.0 11g/mL +1-70.3516
14 Methacrylonitrile 126-98-7 1012014 99% 20,031.5 jlglmL +I-692.3351
15 Methyl acrylate 96-33-3 SHBG66J6V 99% 2,007.0 f.LglmL +I-69.3711
16 Isobutanol (2-Methyl-1-propanol) 78-83-1 SHBP7066 99% 40,013.5 11glmL +I-1,382.9594
01-Nov-2022 rev.
~-RESTEK 1 of 5
REPORT ID: 23E133 Page 247 of 345
17 chloroform 67-66-J SHBN8469 99% 2,002.3 ttg/mL +/-69.9291
18 Bromochloromethane 74-97-5 00008541 99% 2,011.9 ttg/mL +/-70.2782
19 Tetrahydrofuran 109-99-9 SHBP0039 99% 2,005.0 ttg/mL +/-69.3020
20 1,1, !-trichloroethane 71-55-6 RD220613 98% 2,001.2 ttg/mL +/-69.8893
21 l, 1-Dichloropropene 563-58-6 220617JLM 99% 2,014.0 ttg/mL +/-70.3498
22 carbon tetrachloride 56-23-5 SHBL8097 99% 2,000.1 ttg/mL +/-69.8514
23 1 ,2-Dichloroethane 107-06-2 MKCN9758 99% 2,001.6 ttg/mL +/-69.9056
24 Benzene 71-43-2 MKCQ2104 99% 2,010.5 ttg/mL +/-70.2293
25 2-Chloroethanol 107-07-3 RD220606A 99% 2,002.5 ttg/mL +/-69.2156
26 Trichloroetheoe 79-01-6 SHBN3720 99% 2,001.6 jlg/mL +/-69.9047
27 1 ,2-Dichloropropane 78-87-5 BCBR0882V 99% 2,001.8 ttg/mL +/-69.9125
28 Methyl methacrylate 80-62-6 MKCQ2755 99% 2,007.5 f!g/mL +/-69.3884
29 bromodichloromethane 75-27-4 MKCF8470 99% 2,001.7 ttg/mL +/-69.9082
30 I ,4-Dioxane 123-91-1 SHBP8653 99% 40,041.0 f!g/mL +/-1,383.9099
31 2-Nitropropanc 79-46-9 BCCB9352 97% 2,003.5 ttg/mL +/-69.2514
32 Dibromomethane 74-95-3 I 0233302 99% 2,013.0 r•g/mL +/-70.3149
33 cis-1 ,3-Dichloropropene." -... 10061-01-5 RD22031! 99% 2,001.9 ttg/mL +/-69.9152
34 Toluene 108-88-3 ED097-US 99% 2,011.4 f!g/mL +/-70.2608
35 Ethyl methacrylate 97-63-2 MKCN6206 97% 2,004.0 f!g/mL +/-69.2681
36 trans-! ,3-Dichloropropene 10061-02-6 RD220816 99% 2,000.5 ttg/mL +/-69.8671
37 1, I ,2-Trichloroethane 79-00-5 FGBOJ 99% 2,001.9 jlg/mL +!-69.9134
38 1 ,3-Dichloropropane 142-28-9 BCCB98!7 99% 2,011.1 jlg/mL +/-70.2485
39 Tetrachlorocthene 127-18-4 SHBJ7422 99% 2,001.2 f!g/mL +/-69.8890
40 dibromochloromcthane 124-48-l MKCM8659 99% 2,002.2 ttg/mL +/-69.9256
41 I ,2-Dibromoethane (EDB) 106-93-4 BCCF5058 99% 2,006.0 jlg/mL +/-70:0704
42 Chlorobenzene 108-90-7 SHBN6640 99% 2,000.1 ttg/mL +1-69,8506
43 1 ,l, I ,2-Tetrachloroethane 630-20-6 GCOI 99% 2,009.8 ~•g/mL +/-70.2031
44 Ethylbenzene 100-4!-4 094632L2JG 99% 2,016.4 ~g/mL +/-70.4337
45 m-Xylene 108-38-3 SHBN6673 98% 2,012.6 ttg/mL +I-70.3019
46 p-Xylene 106-42-3 10234437 99% 2,009.1 ttg/mL +/-70.1787
47 o-Xylene 95-47-6 SHBN5105 98% 2,010.1 f!g/mL +/-70.2!63
48 Styrene 100-42-5 MKCQ3390 99% 2,012.6 jlg/mL +/-70.3027
49 Isopropylbenzene (cumene) 98-82-8 Z20D022 99% 2,009.3 p.g/mL +/-70.1874
50 bromofonn 75-25-2 MKCR0680 99% 2,000.8 ftg/mL +/-69.8750
51 cis-1,4-Dichloro-2-butene 1476-11-5 RD220907 97% 2,000.0 ttg/mL +/-69.1290
52 I, 1 ,2,2-Tetrachloroethane 79-34-5 OXACF +/-69.9466
01-Nov-2022 rev. ·---· RESTEK 2 of5
REPORT ID: 23E133 Page 248 of 345
53 I ,2,3-Trichloropropane 96-18-4 332900 99% 2,010.3 [!g/mL +I-70.2206
54 ~·ans-I ,4-dichloro-2-butene 110-57-6 RD220921 RSR 94% I ,999.9 ftg/mL +I-69.1240
55 n-Propylbenzenc I 03-65-1 MKCN1126 99% 2,009.1 [!glmL +I-70.1804
56 Bromo benzene 108-86-1 WXBC5147V 99% 2,012.5 )lg/mL +I-70.2992
57 1 ,3,5-Trimethylbenzene I 08-67-8 BCCF4166 99% 2,010.8 )lglmL +I-70.2381
58 2-Chlorotolucne 95-49-8 MKCF5243 99% 2,007.5 )lg/mL +I-70.1228
59 4-Chlorotoluene 106-43-4 MKCC8496 99% 2,012.4 [lg/mL +I-70.2957
60 tert-Butylbenzene 98-06-6 STBJJ937 99% 2,009.0 jJ.ghnL +I-70.1769
61 I ,2,4-Trimcthylbenzenc 95-63-6 WXBC9428V. 98% 2,004.8 ftg/mL +I-70.0297
62 sec-Butylbcnzcne 135-98-8 MKCP2266 99% 2,009.2 ftg/mL +/w 70.1839
63 p-lsopropy I toluene (p-Cymcne) 99-87-6 MKCR6143 99% 2,007.6 ftg/mL +I-70.1280
64 I ,3-Dichlorobcnzene 541-73-1 BCCD5315 99% 2,000. 7 )lglmL +/-69.8715
65 1 ,4-Dichlorobenzene I 06-46-7 MKBS4401V 99% 2,002.0 jtg/mL +I-69.9195
66 n-Butylbcnzene 104-51-8 09804AE 99% 2,006.9 [!g/mL +i-70.1036
67 I ,2-Dichlorobenzene 95-50-1 SHBN3835 99% 2,001.2 ftg/mL +/-69.8898
68 1 ,2-Dibromo-3-chloropropanc 96-12-8 HBMVB 97% 2,006.3 [!g/mL +I-70.0843
69 Nitrobenzene 98-95-3 10224044 99% 2,004.0 [!g/mL +I-69.2674
70 I ,2,4-Trichlorobcnzene 120-82-1 SHBM0526 99% 2,009.7 jJ.g/mL +/-70.1996
71 Hcxachlorobutadiene 87-68-3 X05J 99% 2,007.4 )lg/mL +!-70.1210
---~··--
72 Naphthalene 91-20-3 MKCH02J9 99'Yo 2,001.5 )lglmL +/-69.9132
73 I ,2,3-Trichlorobcnzene 87-61-6 MKBX7627V 99% 2,015.7 [lg/mL +/-70.4092
• Expanded Uncertainty displayed in same units as Grav. Cone.
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
-~-
01-Nov-2022 rev. RESTEK 3 of 5
REPORT ID: 23E133 Page 249 of 345
Column:
60m x 0.2Smm x 1.4~m
Rtx-502.2 (e<it.#10916)
Canier Gas:
helium·constant pressure 30 psi
Temp. Program:
40'C [hold 6 min.) to 240'C
@ 6'C/min. [hold 10 min.)
lnj. Temp:
zoo•c
Det. Temp:
250'(
Det. Type:
MSD
Split Vent:
20.0 ml/min.
lnj. Vol
1~1
Cathleen Soltis -Mix Technician
Jennijer Pollino. Operations T ~h lll· ARM QC
01-Nov-2022 rev.
Dale Min<l:
Quality Confirmation Test
i
"16,17 29.30 • .:31 ..:t5,4.6
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
18-Nov-2022 Balance Serial # B251644995
Dale Passed: 05-Dee-2022
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
4 of 5
REPORT ID: 23E133 Page 250 of 345
General Certified Reference Material Notes
Expiration Notes:
Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
Purity and/or chemical identity are detenmined by one or more of the following techniques: GC/FID, HPLC, GC/f.JECD,
GC/MS, LC/MS, Rl, and/or melting point.
Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
Purity of isomeric compounds is reported as the sum of the isomers.
Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
Ucombtned uncerta<nty = k U~rauimetrtc + U~omogene;ty + u;torag" sta/JiJity + u;htpptng stability
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
Stability of the unopened product. when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL am puis. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
-~.
01-Nov-2022 rev. RESTEK 5 of 5
REPORT ID: 23E133 Page 251 of 345
~ .... llESTEK CERTIFIED REFERENCE MATERIAL
11 0 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: (814}353-1309
www.restek.com
Catalog No. : 30465
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0164741
Description : California Oxygenates Mixture #1
California Oxygenates Mixture #1 2000-100001Jg/mL, P& T Methanol,
1mllampul
Container Size : 2 mL
~~--------------
PkgAmt: ___ >~1~m~L~-----------
Expiration Date : September 30, 2025 Storage: ooc or colder
Ship: Ambient
~;,
(ACCREDIT"'@)
ISO 11034 ActtedKed
R(l(erencq. AUtQJ1•1 F'loducQf
(Mffic.l!G-tJlllO\
.. ..
@ftE~tT]ru
ISOAEC 1702l; Acctedited
1iatlno l>boutory
Cortiliote • 3222.02
CERTIFIED VALUES
tert-Butano1 (TBA)
CAS# 75-65-0 (Lot SHBLS806)
Purity 99%
2 Methyl-tert-buty1 ether ( MTBE)
CAS # 1634-04-4 (Lot SHBL0822)
Purity 99%
3 Diisopropyl ether ( DIPE )
CAS# 108-20-3 (Lot SHBH1927V)
Purity 99%
4 Ethy1-tert-buty1 ether (ETBE)
CAS# 637-92-3 (Lot MKCM3774)
Purity 99%
5 tert-Amyl methyl ether (TAME)
CAS# 994-05-8 (Lot HMBG774SV)
Purity 99%
-.;-, •'i+ · .Grq_v.· COJ)C.-.~-· .c _,_ •
,.. ': , (weight/volume)
10,033.6 l!g/mL
2,000.0 llg/mL
2,006.0 f!g/mL
2,017.6 j!g/mL
2,009.2 J.tglmL
"' ,_. ~.f.l!!lande.d .UnceA"tainty_-. ~ ... l .. .L. . •·· ,.,~;~,;;.:.} ::.··
(95% C.L.; K=2)
+I-58.7489 1-lg/mL Gravimetric
+!-214.9330 llg/mL Unstressed
+I-221.1750 J.LglmL Stressed
+I-11.7371 1-lg/mL Gravimetric
+I-42.8500 llg/mL Unstressed
+1-44.0940 ).lg/mL Stressed
+I-11.7723 ).lg/mL Gravimetric
+I-42.9785 llg/mL Unstressed
+I-44.2263 1-lg/mL Stressed
+/-11.8404 ).lg/mL Gravimetric
+I-43.2270 1-1glmL Unstressed
+I-44.4820 llglmL Stressed
+I-II. 7911 J.LglmL Gravimetric
+I-43.0471 J,tg/mL Unstressed
+I-44.2968 fjg/mL Stressed
01-Aug-2020 rev.
1 of 3
REPORT ID: 23E133 Page 252 of 345
Solvent: P&T Methanol
CAS# 67-56-l
Purity 99%
Column:
105m x 0.53mm x 3.0~m
Rtx-502.2 (cat.Ul0910)
Carrier Gas:
hydrogen·constant pressure 11.0 psi.
Temp. Program:
40'C (hold 2 min.) to 240'C
@ 8'C/min. (hold 5 min.)
lnj. Temp:
zoo·c
Det. Temp:
250'C
Det. Type:
FlO
Walker Workman· Operations Te-chnician I
~~~it~L .....
.Ju•l\,.. Alben..on • Op4r•llon• Tech-ARM OC
'~·-·
01-Aug-2020 rev.
5 10 15 20
Minutes
This chromatogram represents a general set of testing conditions chosen for product
F~c:c::ept:=mr.B. For optimal results in your lab; conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 24-Sep-2020
Date Passed: 27-Sep-2020
Balance: !128360905
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
2 of3
REPORT ID: 23E133 Page 253 of 345
125 Market Street
New Haven. CT 06513
USA
~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-601C-10X
Description: 2-Chloroethylvinyl ether
Lot: 218061690-01
Date Certified: Jul 15, 2020
Expiration: Jul 15, 2023
Sample Size: 1 ml
Components: 1
Tel [phone]
Fax [phone]
www.AccuStandard.com
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Storage Condition: Freeze (<-10 •c)
Signal Word: Danger
Component
CAS#
2-Chloroethylviny\ ether
110-75-8
Certified Reference Material
Purity%
(GC/MS)
100.0
~J~pared
concentrMIQn'
<y9Yn1q
2006·
Certified Analyte
Concentration'
(j.!g/ml)
2006
A product with a suffix (·1A, -28, etc. qr~~p\":}'o2. number has had Its expiration date extended and Is Identical to the same lot number without the suffix.
'All weights are traceable through Nis'T: T~st No;,822-275872-11
'Certified Analyte Concentration=~;;';.;\ Pre.~~,l~d Concentration.
The Uncertainty assoclateq;W\tW@B' . '· :.'})\'bentratlon reported on this certificate Is ±2.4%. This value Is the combined expanded uncertainty and represents an
estimated standard deviat@:t'equal t~,t)le positive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2.1s chosen , .. , .. , roxiiJi!jtely a 95% confidence level.
Labels and,pe:f\.i foil .:,::C?P~Ventions in reporting numerical values: A comma (,) Is used to separate units of one-thousand or greater. A period(.) Is used as
a decimal ·... ,,:,;.•"'
The informait()):j)pn t~J:;:\¢\lttJflil.!!te may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard lnfomt'' ... ,, .. ~~·x:··. ·· iefer to the SDS for Information regarding the hazards associated with using this material.
ared according to In-house procedures and Is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic QC Manager
Page 1 of 1
For use In routine laboratory analysis.
AccuStandard is accredited to ISO 17034, 150/IEC 17025 and certified to ISO 9001:2015
OR-ORGnN0·001
Rev. 7/20
REPORT ID: 23E133 Page 254 of 345
1. Quality Standards:
ISO 17034:2016-General Requirements for the Competence of
Reference Material Producers ANAB Certificate Number AR-1463
180/IEC 17025:2017-General Requirements for the Competence of
Testing And Calibration Laboratories ANAB Certificate Number AT-1339
ISO 9001:2015-Quality Management System-Requirements
Eagle Registrations Certificate Number 3774
2. Intended Use: The product covered by this certificate is designed for calibration or for use in quality control procedures
for the specified chemical compounds listed on the reverse side. This product can be used for quantification and/or
identification. This product can also be used as a reference material to validate analytical procedures, subject to the
conditions under Section 7.
3. Manufacturing: All balances are calibrated daily using an in-house procedure with weights that are compared annually
to master weights and traceable to NIST. The balances are also calibrated annually by an ISO/IEC 17025 accredited
calibration laboratory. Please refer to the NIST test number listed on the front of this certificate. Class A glassware
is used in the manufacture and quality control of all standards. Good Laboratory Practices have been used throughout
the preparation of this Standard.
4. Homogeneity: This product is sufficiently homogeneous and any sample size would be within the uncertainty budget.
5. Stability: The manufacturer guarantees the stability of this solution through the expiration date stated on the label,
when handled and stored according to the conditions stated on the label
6. Uncertainty: The uncertainty values as stated on the face of this certificate have been determined using the
EURACHEM/CITAC Guide. We report a combined expanded uncertainty equal to the positive square root of the total
variance of the uncertainty of the components using the following formula: u11 = .f(u(V)Jl 1-(u(m))! + (u(lV))2 + (u(RO))ll his
formula represents uncertainty components from the mass, volume, short-term stability, long-term stability and
homogeneity factors associated with the production of this product. The expanded uncertainty, assumes a normal
distribution and a coverage factor of k=2 is chosen using approximately a 95% confidence level.
7. Legal Notice and Limit of Liability: This product is for routine laboratory analysis and research purposes only. The
company's liability will be limited to replacement of product or refund of purchase price. Notice of claims must be made
within thirty (30) days from date of delivery.
REPORT ID: 23E133 Page 255 of 345
Product Name: 1-Chlorohexane Standard
Product Number: EPA-1208-1
Storage Conditions: Store at Room Temperature (15° to 30°C).
Matrix: methanol (methyl alcohol)
Description:
Lot Number:
Lot Issue Date:
Expiration Date:
0006668972
1 0-Mar-2022
30-Apr-2025
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 1 of 2
CSO-OA·D15.1
REPORT ID: 23E133 Page 256 of 345
' . -. .. . ...... A "I
ISO 17034 ···:..:_··· 91 ent . .. . . . .
· Trusted Answers
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
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A.CCR£,.DITEO
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUV/SUD registered lSD 9001:2015
Quality Management System. Curt# 951215321
Page: 2 of2
www.agilentcom/quality/
CSD-QA-015.1
Sample lot approver:
~001AZfOW
Monica Bourgeois
QMS Representative
~
A C 0 R f:·D IT 6 D
ISO 17025 Cert
No. AT-1937
REPORT ID: 23E133 Page 257 of 345
Scientific
SIMPLE SOLUTIO~S FQR AOVAHCtO SCIENCE
Chromanex, 14271 Jeffey Rd #223, Irvine, CA 92620 [phone], Fax [phone]
Date manufactured: 10/15/2020
Original issue date: 10/15/2020 Certificate of Analysis DateReceived:
Catalog No.: Lot No.: Storage: Solvent: Expiration Description:
Date:
3200-44 453887 :::; -10 °C PIT Methanol 14-0ct-202 5 1,2,3-Trimethylbenzene Solution,
2500 mg/L, 1 mL
Certified Values:
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM
has been confirmed by ga.s chromatography (GC) or gas chromatograph/mass spectrometry
(GC/MS) using an internally developed method against an independent source. The uncertainty
value is calculated for a 95% confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ma/L
1,2,3-trimethylbenzene 526-73-8 95.2 869.3.19P 2515 ± 9.27
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control
standard for Chromatography Equipment such as GC, GC/MS, HPLC,and HPLC/MS. It may aslo be used for
various USEPA, NIOSH, and ASTM methods.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and
uncertainty (95% confidence) values listed are determined gravimetriclly.
Packaging and Storage:
The solution should be stored according to the following storage requirements: s -10 °C
Once the product is opened, it should be transferred to a vial with minimum head space if the product was in a seal
ampule. Once opened, the expiration is determined by user specifications.
Glassware Calibration:
Only Class A glassware is used in the manufacture and quality control of Standards. All Glassware is calibrated
REPORT ID: 23E133 Page 258 of 345
Certificate of Analysis
Catalog No.: 3200-44 Lot No.: 453887 Expiration Date: 10/14/2025
using NIST traceable weights.
Weights and Balance Calibration:
Weights used perform daily checks on balances calibrated annually by the State of South Carolina Department
of Agriculture Metrology Laboratory and are traceable to the National Institute of Standards and Technology
(NIST). Balances are checked daily in accordance to in house procedure 02-LB-004. Balances are calibrated
annually by an ISOIIEC 17025:2005 and ISO Guide 34:2009 accredited metrology service.
Homogeneity:
Random replicate samples of the final packaged CRM have been analyzed to prove homogeneity in accordance
with internal procedure 02-QS-1 0. This is consistent with the intended use of this CRM. The homogeneity of this
product has been confirmed by procedures consistent with ISO!IEC qulde 17025:2005 and ISO qulde 34:2009.
Hazardous information:
Refer to MSDS
Calculation of Uncertainty
The following equations are used to calculate the value of the expanded uncertainty: U=ku c: U=Expanded
Uncertainty, k= the coverage factor at the 95% confidence level, k=2, uc =the combined uncertainty uc= "2,u1
2
where u 1 are the individual uncertainty components for characterization, transportation, homogeneity, and shelf life.
Expiration Information:
The Stability of this product is based upon rigorous short term and long term testing of the solution for the certified
value. These tests include the effect of temperature and packaging on the product. This standard is guaranteed
until the following date: 14-0ct-2025
Accreditation:
This CRM was manufactured by an ISO 17025:2017 chemical testing lab (Certificate number 3031.01) and ISO
17034:2016 Reference Material Producer (RMP) Certificate number 3031.02 accredited by The American
Association of Laboratory Accreditation (A2LA).
Manufactured By: Certified By: Released By:
L. ~
Melissa Workoff Claire Desrochers Susan Mathews
\
REPORT ID: 23E133 Page 259 of 345
~' IRESTEK® CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30470
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
lot No.: A0162335
Description : tert-Butanol Standard
tert-Butanol Std 50,0001Jg/ml, P&T Methanol, 1 mL/ampul
Container Size : 2 ml
-------------------------------------
Pkg Amt: > 1 ml -----~~-------------
Expiration Date : July 31, 2023
----~----------------------
Storage: o•c or colder
a
ISO ·11034 Awedited
Re4'erw...e ~.~t~l~l Plodum
C~rlffiato "32ll0l
·.·.·.\ ..
" h::·
.:
(i'CC'ReE>ttj§'DJ
·ISOAEC 17025 Accredited
Totting L>boratcry
((!rtifiate f32~02
CERTIFIED VALUES
Compound . -
teti-Butanol (TBA)
CAS# 75-65-0 (Lot SHBL5806)
Purity 99%
Solvent: P&T Methanol
CAS# 67-56-1
Purity 99%
Grav.Conc.
(weight/volume)
50,008.0 J.lg/mL
Expanded Uncertainty
.. (95% C.L.; K:::2) .. -· ·· -

-
+/-292.8078
+1-1,071.2377
+/-1,102.3483
J.lg/niL
J.lglmL
j.lg/mL
Gravimetric
Unstressed
Stressed
14-May-2020 rev. 1 of 3
REPORT ID: 23E133 Page 260 of 345
Column:
105m x 0.53mm .x 3.0~m
Rtx-502.2 (c,t.Nl0910)
Carrier Gas:
hydrogen-constant pressure 11.0 psi.
Temp. Program:
40"C (hold 2 min.) to 240"C
@ s·cjmin. (hold 5 min.)
lnj. Temp:
2oo·c
Det. Temp:
25o·c
Det. Type:
FID
\~ J.i-3/ywo-<~'--'l(r:\ ~~
Kyll1.1 S\rublo-Opqratlon5 Technlelrm I
14-May-2020 rev.
10 15 20 25
Mlnllles
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Date Mixed: 07-Jul-2020
Date Passed: 09-Jul-2020
Balance: 1127510105
Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
/
(
2 of3
REPORT ID: 23E133 Page 261 of 345
14271 Jeffrey Road
#223
Irvine, CA 92620
Quality System
Audited & Registered
by TUV USA to ISO 9001:2015
Catalog No.: Lot No.:
sci ntlffc
It uri Q2-crf)
4~t ·-7 r{-u~ -r·--I ·1
Certificate of Analysis
Solvent: Exp. Date:
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: -------
Rev 0 Page
Description:
034-3200 480682
Storage:
::; -10 oc P/TMeOH:Water 9:1 4/28/2027 Ketones Solution, 2500 mg/L, 1 ml ISO 17034
-121020-I 7
Certified Bv:
Compound
acetone
2-butanone (MEK)
4-methvl-2-oentanone (MIBK)
2-hexanone
Melissa Workoff
CAS No
67-64-1
78-93-3
108-10-1
591-78-6
Purity(%) Compound Lot No Concentration, mi!!L
99.6 I 96.271.4P 2498 ± 53.47 mg!L
99.9 197.1.2P 2498 ± 53.51 mg/L
99.88 198.421.1.21' 2500 ± 54.02 mg/L
100 199.7.3P 2501 ± 53.58 mg!L
All weights are traceable through N. I. S. T. Test No. 822/264157-00.
Concentration (correct for ouritv) and uncertaintv (95% confidence) values
REPORT ID: 23E133 Page 262 of 345
Trusted A11swers
Reference Material Certificate
Product Information Sheet
Product Name: Acrolein and Acrylonitrile Standard
Product Number: AMN-623-1
Storage Conditions: Store Frozen (-25• to -lD"C).
acrylonitrile 2009 ± 10 IJg/mL
Matrix: methanol (methyl alcohol)
Description:
ISO 17034
Lot Number: 0006728532
Lot Issue Date: 14-Feb-2023
Expiration Date: 30-Jun-2023
000107-13-1 RM20527
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material (RM) standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above. Purity values are taken from approved vendor raw material certificates.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference (RM) standard was unitized according to an in-house procedure and is guaranteed to be homogeneous.
There is no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference (RM) standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard (RM) is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 1 of 2
CSD-QA-015.1 ISO 17025
REPORT ID: 23E133 Page 263 of 345
. . . .
••••
0 A ·1 ............... g1 ent . . .
Trusted Answers
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~~I/Qllllii8J!.!_I!
ACCREDITED
REFERENCE MATERIAL
PRODUCER
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with the TUVISUO registered ISO
9001:2015 Quality Management System. Cert# 951215321
Page: 2 of2
www.agilent.com/quality/
CSD-QA-015.1
Sample lot approver:
~ooM~QW
Monica Bourgeois
QMS Representative
ISO 17025
REPORT ID: 23E133 Page 264 of 345
~:~
(i\%jiEDIT:!EJ
Reference Materials Producer
Cart #2495.01
SPEXertificate®
Certificate of Reference Material
Catalog Number: S-1015 Lot No. CP200701 009
Cyclohexane Ship Date: August 6, 2021
Methanol (Purge & Trap Grade) Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quali~y
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed m
USEPA, ASTM and other methods relevant to the certified properties listed below. ·
Certified Compounds:
Compound
Cyclohexane
~
110-82-7
•-Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 1-19/mL
Purity
99.5%
Certifiedt
10181-Jg/ml
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepa~e the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6, 2021 Certifying Officer: .sn.e..INJ.O..........._ ~­
shanhon Macieira, Operations Manager
Page 1 of2
REPORT ID: 23E133 Page 265 of 345
Report of Cert~fication
Catalog Number: S-1 015
Description: Cyclohexane
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200701009
Ship Date: August 6, 2021
Expiration Date: August 5, 2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems-Requirements
-ISO/IEC 17025: General requirements for the competence of testing
and calibration laboratories
-ISO 17034: General requirements for the competence of reference
material producers
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials-Contents of certificates and
!abies
Storage Requirements:
-!SO Guide 35: Refernece Materials -General and Statistical
principals for certification
-Guide to the Expression of Uncertainty in Measurement, 2008
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions. (18°C to 27'C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5~L with a 25~L ga::; tight syrir.go. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
Ail analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked ancl
documented. For assistance, please contact sales support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used In all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-be
ttle. variation,-is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
-X= x ± U where X=certified value, U=expanded uncertainty, x=property value
- U = kuc where k=2 is the coverage factor at the 95% confidence level
-uc =combined standard uncertainty obtained by combining the individual compound standard uncertainty components u1. where Uc=.JrUi•
Legal Notice:
SPEX CertiPrep Certified Reference Materials a no not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.l'i>
Your Science Is Our Passion."'
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Page 2 of7
i
Rev: / j
r REPORT ID: 23E133 Page 266 of 345
R~r
~ SPEXertificate®
Reference Materials Producer
Cert #2495.01
Certificate of Reference Material
Catalog Number: S-3893 Lot No. CP200615008
Description: Methyl acetate
Matrix: Methanol (Purge & Trap Grade) Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
US EPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Methyl acetate
CAS#
79-20-9
* -Isomer ratios (when applicable} are an uncertified parameter.
Final Solution Verification:
Labeled
1000 ~g/ml
Purity
99.5%
Certified!
985 ~g/ml
Uncertainty
± 34 ~g/ml
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered with Atlantic
Scale, and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: June 20, 2022 Certifying Officer: 3~V>--~
Shannon Macieira, Operations Manager
Page 1 of 2
© 20211 Spex, an AB,sl.Y'Scienti~company.
REPORT ID: 23E133 Page 267 of 345
Report of Cert{(ication
Catalog Number: S-3893
Description: Methyl acetate
Matrix: Methanol (Purge & Trap Grade)
Lot No. CP200615008
Ship Date: June 20, 2022
Expiration Date: June 19, 2025
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
·ISO 9001: Quality management systems-Requirements
• ISO/IEC 17025: General requirements for the competence of testing
and calibration laboratories
-ISO 17034: General requirements for the competence of reference
material producers
• ISO Guide 30: Reference Materials • Selected terms and definitions
-ISO Guide 31: Reference Materials-Contents of certificates and
lables
Storage Requirements:
-ISO Guide 35: Refemece Materials -General and Statistical
principals for certification
• Guide to the Expression of Uncertainty in Measurement, 2008
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditlons (18•c to 27.C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE Is calculated from the SHIPPED DATE using our stability data and
Is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance Is acceptable. The minimum recommended
amount that should be removed from this vial is 5~L with a 25~L gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly cleaned prior to use. Dilutions should be performed only with Class
A volumetric glassware.
Material Source:
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Vendor
identifications are proprietary, however sources of all materials used in the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sal.es support at [e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all preparations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM D6362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity In accordance with our.intemal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-bo
ttle variation, Is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
-X= x ± U where X=certified value, U=expanded uncertainty, x=property value
-U = kuc where k=2 is the coverage factor at the 95% confidence level
-uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components u1, where uc="ru,•
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, or otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep. ~
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
REPORT ID: 23E133 Page 268 of 345
~! SPEXertificate®
(A"C'£ReotTii)J
Reference Materials Producer
Cart #2495.01
Certificate of Reference Material
Catalog Number: S-2470 Lot No. EN191227005
Methylcyclohexane
Methanol (Purge & Trap Grade) Ship Date: August 6, 2021
Expiration Date: August 5, 2024
This SPEXOrganics® Certified Reference Material, CRM, is intended primarily for use as a calibration standard or quality
control standard for organic chromatography .instrumentation such as GC, GC-MS, LC, and LC-MS. It can be employed in
USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound
Methylcyclohexane
CAS#
108-87-2
*-Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 iJglmL
Purity
99%
Certifiedt
1018 j..Jg/ml
Uncertainty
± 36 j..Jg/ml
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily with C1 weight set #23-190006 which is registered With Atlantic
Scale, and traceable tb NISTand NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: August 6, 2021 Certifying Officer: .Sbw.o,___ ~--­
Shannon Macieira, Operations Manager
Page 1 of 2
REPORT ID: 23E133 Page 269 of 345
··.:
Report of Cert~(ication
Catalog Number: S-2470 Lot No. EN191227005
Description: Methylcyclohexane
Matrix: Methanol (Purge & Trap Grade) Ship Date: August 6, 2021
Expiration Date: August 5, 2024
This Certified Reference Material (CRM) has been prepared and certified under an ISO 9001 (certified by DQS)
and ISO 17025 (accredited by A2LA), and ISO 17034 (accredited by A2LA) quality system consistent with the
following standards:
-ISO 9001: Quality management systems -Requirements
-ISO/IEC 17025: General requirements for the competence of testing
-ISO Guide 35: Refernece Materials-General and Statistical
principals for certification
and calibration laboratories -Guide to the Expression of Uncertainty in Measurement, 2008
-ISO 17034: General requirements for the competence of reference
material producers
-EURACHEM/CITAC Guide: Qualifying Uncertainty in Analytical
-ISO Guide 30: Reference Materials -Selected terms and definitions
-ISO Guide 31: Reference Materials -Contents of certificates and
lables
Storage Requirements:
Measurement -Third Edition
-NIST Technical Note 1297
To ensure the stability of the product once it arrives in your laboratory, please store this product in ambient conditions (18"C to 27"C). Note:
Shipping conditions may differ from storage conditions. The EXPIRATION DATE is calculated from the SHIPPED DATE using our stability data and
is applicable only if the product is stored under the laboratory specified conditions.
Instructions for Use:
Let material come to room temperature before use. Check for precipitate and if necessary sonicate for one minute. If compounds do not
dissolve after one minute then sonicate further until the product is dissolved. A clear appearance is acceptable. The minimum recommended
amount that should be removed from this vial is 5pl with a 25pl gas tight syringe. All solutions should be thoroughly mixed, by shaking, prior to
use. All surfaces that come in contact with the solution must be thoroughly ciC;aned prior to use. Dilutions should be performed only with Class (
A volumetric glassware.
Material Source: .
All analytes and matrix materials are obtained and verified by SPEX CertiPrep from pre-qualified vendors as per ISO guidelines. Veridor
identifications are proprietary, however sources of all materials used iri the preparation and testing of SPEX CertiPrep CRMs are tracked and
documented. For assistance, please contact sales support at crmsa![e-mail].
Method of Preparation:
Clean laboratory procedures and techniques have been used throughout the preparation. All materials, equipment, and analytical instrumentation
have been qualified prior to use. The highest purity solvents and Class A I calibrated volumetrics have been used in all prep·arations.
Homogeneity:
The homogeneity of this CRM has been confirmed by procedures consistent with ISO 17025, ISO 17034, and ASTM 06362-98 Appendix X2.
Random, replicate samples of the final, packaged material have been analyzed to prove homogeneity in accordance with our internal procedure
4300-HOMOGEN-1A. This is consistent with the intended use of this CRM. The Degree of Homogeneity, as expressed as maximum between-be
ttle variation, is 1.2%
Statistical Estimator and Confidence Limits:
The Certified value 'X' as listed on the reverse of this document is at the 95% level of confidence and can be expressed as:
• X= x ± U where X=certified value, U=expanded uncertainty, x=property value
-U = kuc where k=2 is the coverage factor at the 95% confidence level
-uc = combined standard uncertainty obtained by combining the individual compound standard uncertainty components u1. where uc=viw2
Legal Notice:
SPEX CertiPrep Certified Reference Materials are not for any cosmetic, drug, or household application and are to be used only by qualified
individuals who are trained in appropriate procedures. No claims against SPEX CertiPrep of any kind whatsoever, whether based on breech of
warranty, alleged negligence, pr otherwise, with respect to this Reference Material shall be greater than the purchase price. In no event shall
SPEX CertiPrep be liable for any loss of profits or any incidental, special, or consequential damages.
SPEX CertiPrep.l'j>
Your Science is Our Passion."
203 Norcross Ave. Metuchen, NJ 08840
www.spexcertiprep.com • E-mail: [e-mail]
Phone: [phone] • Fax [phone]
Page 2 of 2
Rev: 0
REPORT ID: 23E133 Page 270 of 345
LABORATORY REPORT FOR
BRICE
TEAD-S
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
SDG#: 23E133
REPORT ID: 23E133 Page 271 of 345
Client : BRICE
Project: TEAD-S
SDG 23E133
CASE NARRATIVE
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
A total of six(6) water samples were received on 05/18/23 to be analyzed for
Petroleum Hydrocarbons by Extraction in accordance with Method SW3520C/8015D and
project specific requirements.
Holding Time
Samples were analyzed within the prescribed holding time.
Calibration
Multi-calibration points were generated to establish initial calibration (ICAL).
ICAL was verified using a secondary source (ICV). Continuing calibration (CCV)
verifications were carried out on a frequency specified by the project. All
calibration requirements were within acceptance criteria. Refer to calibration
summary forms of I CAL , ICV and CCV for details.
Method Blank
Method blank was prepared and analyzed at the frequency required by the project.
For this SDG, one(l) method blank was analyzed. DSE026WB -result was compliant
to project requirement. Refer to sample result summary form for details.
Lab Control Sample
Lab control sample was prepared and analyzed at a frequency required by the
project. For this SDG, one(l) set of LCS/LCD was analyzed. DSE026WL/DSE026WC
were within LCS limits. Refer to LCS summary form for details.
Matrix QC Sample
Matrix spike sample was prepared and analyzed at a frequency required by the
project. For this SDG, one(l) set of MS/MSD was analyzed. TPH-Extractable (C10-
C24) was within MS QC limits in 23E133-05M/23E133-05S. Refer to Matrix QC
summary form for details.
Surrogate
Surrogates were added on QC and field samples. All surrogate recoveries were
within QC limits. Refer to sample result summary forms for details.
Sample Analysis
Samples were analyzed according to prescribed analytical procedures. Results
were evaluated in accordance to project requirements. For this SDG, all quality
control requirements were met.
REPORT ID: 23E133 Page 272 of 345
Client : BRICE
Project : TEAD-S
Client Laboratory Dilution %
Sample ID Sample ID Factor Moist
.-----------------
MBLK1W DSE026WB 1 NA
LCS1W DSE026WL 1 NA
LCD1W DSE026WC 1 NA
S-55-90-052023 E133-01 1 NA
S-78-91-052023 E133-02 1 NA
S-91-91-05-2023D E133-03 1 NA
S-91-91-052023 E133-04 1 NA
S13-CAM-DW1-052023 E133-05 1 NA
S13-CAM-DW1-052023MS E133-05M 1 NA
S13-CAM-DW1-052023MSD E133-05S 1 NA
SWMU-13-EB-052023 E133-06 1 NA
FN Filename
% Moist -Percent MOisture
LAB CHRONICLE
PETROLEUM HYDROCARBONS BY EXTRACTION
WATER
Analysis Extraction
DateTime DateTime
--------------------------
05/24/2304:55 05/22/2311: 15
05/24/2305:14 05/22/2311:15
05/24/2305:32 05/22/2311:15
05/24/2305:51 05/22/2311: 15
05/2412306:09 05/22/2311:15
05/24/2306:28 05/22/2311:15
05/24/2306:46 05/22/2311:15
05/24/2307:05 05/22/2311: 15
05/24/2307:23 05/22/2311: 15
05/24/2307:42 05/22/2311:15
05/24/2308:00 05/22/2311: 15
Sample
Data FN
LE23035A
LE23036A
LE23037A
LE23038A
LE23039A
LE23040A
LE23041A
LE23042A
LE23043A
LE23044A
LE23045A
SDG NO_
Instrument ID
23E133
D5
Calibration Prep.
Data FN Batch Notes
LE23033A
LE23033A
LE23033A
LE23033A
LE23033A
LE23033A
LE23033A
LE23033A
LE23033A
LE23033A
LE23033A
23DSE026W Method Blank
23DSE026W Lab Control Sample (LCS)
23DSE026W LCS Duplicate
23DSE026W Field Sample
23DSE026W Field Sample
23DSE026W Field Sample
23DSE026W Field Sample
23DSE026W Field Sample
23DSE026W Matrix Spike Sample (MS)
23DSE026W MS Duplicate (MSD)
23DSE026W Field Sample
REPORT ID: 23E133 Page 273 of 345
SAMPLE RESULTS
REPORT ID: 23E133 Page 274 of 345
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
Client
Project
Batch No.
: BRICE
: TEAD·S
23E133
Sample 10 S·55-90·052023
Lab Samp 10: 23E133-01
Lab File 10: LE23038A
Ext Btch 10: 23DSE026W
Calib. Ref.: LE23033A
PARAMETER
TPH-Extractable (C10·C24)
SURROGATE PARAMETERS
Bromobenzene
Hexacosane
Notes:
RESULTS
(ug/L)
--_ .... _-_ ......
ND
RESULT
............ _--_ ..
931
272
Date Collected: 05/16/23 09:15
Date Received: 05/18/23
Date Extracted: 05/22/23 11:15
Date Analyzed: 05/24/23 05:51
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument 10: D5
LOQ DL LOD
(ug/L) (ug/L) (ug/L)
---------_ .. .. ---_ ............ _ .. _-_ .. _----
550 110 220
SPK AMT %RECOVERY QC LIMIT
.. __ ........ -.... ----................ --.. --..............
1100 85 50-130
275 99 50·140
Detection limits are reported relative to sample result significant figures.
Sample Amount 910ml Final Volume: 10ml
Prepared by : RGalan Analyzed by : SDeeso
REPORT ID: 23E133 Page 275 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23038.dat
: D: \Projects\EZC331 \Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
SampleID
Acquired
Printed
User
: 23E133-01
: 05/24/2305:51:17
: 05/25/23 11:27:19
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DlESEL(TOT AL)
DlESEL(ClO-C24)
--FlO
R tention Time
0.4
'5 >
0.2
Ii)
~ ~ ~ I
~ ill
0.0
2
N
(Y)
0
'<1'1
3 4
1.598
5.278
dl •.
~! Ii)
I"-co
II '1 tO l
5 6
Area
1408553
649086
25600
1690
7
Minutes
Software Version: Version 3.3.1
8
Page 1 of 1
Average RF ESTD conc.
(ppm]
16632.78922 84.685
26182.66222 24.791
26203.75493 0.977
24916.61874 0.068
I 1l().521
9 10 11
0.4
15 >
0.2
0.0
REPORT ID: 23E133 Page 276 of 345
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
Client : BRICE Date Collected: 05/16/23 11:05
Project : TEAD-S Date Received: 05118/23
Batch No_ 23E133 Date Extracted: 05122/23 11: 15
Sample ID S-78-91-052023 Date Analyzed: 05/24/23 06:09
Lab Samp ID: 23E133-02 Dilution Factor: 1
Lab File ID: LE23039A Matrix: WATER
Ext Btch ID: 23DSE026W % Moisture: NA
Calib. Ref.: LE23033A Instrument ID: D5
RESULTS LOQ DL LOD
PARAMETER (ug/l) (ug/l) (ug/l) (ug/l)
...................... __ .......... _ ... ..................... ................ __ .. ...................... ......... _-----
TPH-Extractable (C10-C24) ND 540 110 220
SURROGATE PARAMETERS RESULT SPK_AMT %RECOVERY QC LIMIT
--_ .. __ .... _-----_ .. _-_ .. _-------_ ........... _--_ ............ ---.......... __ ........ ...... _-......... _--
Bromobenzene 869 1080 80 50-130
Hexacosane 250 270 93 50-140
Notes:
Detection limits are reported relative to sample result significant figures.
Sample Amount 930ml Final Volume : 10ml
Prepared by : RGalan Analyzed by : SDeeso
REPORT ID: 23E133 Page 277 of 345
Inst. Name:
File
Method
Sequence:
Sample ID
Acquired
Printed
User
FID Results
Name
: D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
: D:\Projects\EZC331\Data\LE23\LE23039.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
: 23E133-02
: 05/24123 06:09:45
: 05/25/23 11:27:25
:SDEESO
Retention Time Area
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(ClO-C24 )
1.598
5.288
1344692
608784
35847
5633
·.1
-c-FlO
R tention Time
0.4
0.2
010 ~~ ...:r-
0.0 ~l ill
2 3
o ('t) o N
o "'" ~I ~
4 5
1994956\
6
Minutes
7
Software Version: Version 3.3.1
8
Page 1 of 1
Average RF ESTD conc.
[ppm]
16632.78922 80.846
26182.66222 23.251
26203.75493 1.368
24916.61874 0.226
I····· .......... .
.•••• l05.~91 •.
9 10 11
0.4
0.2
0.0
REPORT ID: 23E133 Page 278 of 345
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
Client : BRICE Date Collected: 05/15/23 13:35
Project : TEAD·S Date Received: 05/18/23
Batch No. 23E133 Date Extracted: 05/22/23 11:15
Sample ID S·91·91·05·2023D Date Analyzed: 05/24/23 06:28
Lab Samp ID: 23E133·03 Dilution Factor: 1
Lab File ID: LE23040A Matrix: WATER
Ext Btch ID: 23DSE026W % Moisture: NA
Calib. Ref.: LE23033A Instrument ID: D5
RESULTS LOQ DL LOD
PARAMETER (ug/l) (ug/l) (ug/l) (ug/L)
---------........... _--_ .... _ ......... ----_ ........... --------_ .. ------_ .. _-_ .. .......... _-.. ---
TPH·Extractable (C10·C24) ND 520 100 210
SURROGATE PARAMETERS RESULT SPK_AMT %RECOVERY QC LIMIT
.... _-----------................ -.. -............ _ ........ ............... _ .. ------_ ............ -_ ...... _------
Bromobenzene 779 1040 75 50·130
Hexacosane 217 260 83 50·140
Notes:
Detection limits are reported relative to sample result significant figures.
Sample Amount 960ml Final Volume : 10ml
Prepared by : RGalan Analyzed by : SDeeso
REPORT ID: 23E133 Page 279 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23040.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331 \Sequence\LE23.seq
Sample ID
Acquired
Printed
User
: 23E133-03
: 05124/2306:28:18
: 05/25/23 11:27:32
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DlESEL(ClO-C24)
........ .... .... l» I. Totals ••
-c-FlO
R tention Time
0.4
0.2
2
1.598
5.302
Area
1244442
544487
214348
22928
Software Version: Version 3.3.1
Page 1 of 1
Average RF ESTD conc.
[ppm ]
16632.78922 74.819
26182.66222 20.796
26203.75493 8.180
24916.61874 0.920
I··· ............ . .' ............ . . ... .......... .
u 1Q4.715 ••.. ·····1
. ..
0.4
0.2
REPORT ID: 23E133 Page 280 of 345
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
Client
Project
Batch No.
: BRICE
TEAD·S
23E133
Sample ID S·91-91-052023
Lab Samp ID: 23E133·04
Lab File ID: LE23041A
Ext Btch ID: 23DSE026W
Calib. Ref.: LE23033A
PARAMETER
TPH-Extractable (C10·C24)
SURROGATE PARAMETERS
Bromobenzene
Hexacosane
Notes:
RESULTS
(ug/l)
-----------
ND
RESULT
-----------
770
205
Date Collected: 05/15/23 13:30
Date Received: 05/18/23
Date Extracted: 05/22/23 11:15
Date Analyzed: 05/24/23 06:46
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: D5
LOQ DL LOD
(ug/l) (ug/l) (ug/l)
-----------____ a -____ a -----------
510 100 200
SPK AMT %RECOVERY QC LIMIT
-----------. ----------------------
1020 76 50·130
255 81 50·140
Detection limits are reported relative to sample result significant figures.
Sample Amount 980ml Final Volume: 10ml
Prepared by : RGalan Analyzed by : SDeeso
REPORT ID: 23E133 Page 281 of 345
Inst. Name:
File
Method
Sequence:
Sample ID
Acquired
Printed
User
FID Results
Name
: D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
: D:\Projects\EZC331\Data\LE23\LE23041.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
: 23E133-04
: 05/24/2306:46:47
: 05/25/23 11:27:42
:SDEESO
Retention Time Area
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(ClO-C24 )
1.599
5.304
1255423
526905
206020
23122
I totals:.·
... ....... ... . ... ... ....... . ::: .... "".,.""
-r-FlO
R tention Time '<t
0
('t)
0.4 LI'i
L()
('t)
"-:
0.2 ~
~
('t) ~ "<I: «) 0 «) ('t)'<t «)
~ co r--('t)«)N 0
0 '<t ON'<t r--
I~ .~ MI M ~~~ 14 .1
0.0
2 3 4 5 6 7
Minutes
Software Version: Version 3.3.1
8
Page 1 of 1
Average RF ESTD conc.
(ppm ]
16632.78922 75.479
26182.66222 20.124
26203.75493 7.862
24916.61874 0.928
104..393 •
9 10 11
...
0.4
0.2
0.0
I
REPORT ID: 23E133 Page 282 of 345
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
Client : BRICE
Project : TEAD-S
Batch No_ 23E133
Sample ID S13-CAM-DW1-052023
Lab Samp ID: 23E133-05
Lab File ID: LE23042A
Ext Btch ID: 23DSE026W
Calib_ Ref_: LE23033A
PARAMETER
TPH-Extractable (C10-C24)
SURROGATE PARAMETERS
Bromobenzene
Hexacosane
Notes:
RESULTS
(ug/L)
....................
ND
RESULT
--_ ................
815
241
Date Co 11 ected : 05/15/23 11:35
Date Received: 05/18/23
Date Extracted: 05/22/23 11:15
Date Analyzed: 05/24/23 07:05
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: D5
LOQ DL LOD
(ug/L) (ug/L) (ug/L)
---------_ .. .... ---_ .......... ........... _----
540 110 220
SPK AMT %RECOVERY QC LIMIT
-........ ------.. _ .... -------............ _-----
1080 75 50-130
270 89 50-140
Detection limits are reported relative to sample result significant figures_
Sample Amount 930ml Final Volume: 10ml
Prepared by : RGalan Analyzed by : SDeeso
REPORT ID: 23E133 Page 283 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23042.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331 \Sequence\LE23.seq
Sample ID
Acquired
Printed
User
: 23E133-05
: 05/24/2307:05:28
: 05/25/23 11:27:49
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(ClO-C24)
I Totals
: .::;.:::::--::
0.4
"0 >
0.2
0.0
-r-FlO
R ~tention Time
(Om ~ 1.O;:g~
~ ~~"'":C':!
f~I~ln
2
1.0
1.0
0
""'I
3 4
1.598
5.332
N r--
C') C')
~ r--
4 1 Lril
5 6
Area
1260688
585815
22291
8724
.... .., ..................
18775 If
7
Minutes
Software Version: Version 3.3.1
8
Page 1 of 1
Average RF ESTD conc.
[ppm]
16632.78922 75.795
26182.66222 22.374
26203.75493 0.851
24916.61874 0.350
19~.37o
9 10 11
HI
..
0.4
15 >
0.2
0.0
REPORT ID: 23E133 Page 284 of 345
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
Client : BRICE Date Collected: 05/15/23 09:00
Project TEAD-S Date Received: 05/18/23
Batch No. 23E133 Date Extracted: 05/22/23 11: 15
Sample ID SWMU-13-EB-052023 Date Analyzed: 05/24/23 08:00
Lab Samp ID: 23E133-06 Dilution Factor: 1
Lab File ID: LE23045A Matrix: WATER
Ext Btch ID: 23DSE026W % Moisture: NA
Ca 1 i b. Ref.: LE23033A Instrument ID: 05
RESULTS LOQ DL LOD
PARAMETER (ug/l) (ug/l) (ug/l) (ug/l)
... -.......................................... ---_ .... -----.. .. .. .. .. .. .. .. .. .. .. ...................... .. --------.. -
TPH-Extractable (ClO-C24) NO 510 100 200
SURROGATE PARAMETERS RESULT SPK_AMT %RECOVERY QC LIMIT
.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. -.......... ...................... .. ......................
Bromobenzene 739 1020 72 50-130
Hexacosane 211 255 83 50-140
Notes:
Detection limits are reported relative to sample result significant figures.
Sample Amount 980ml Final Volume: 10ml
Prepared by : RGalan Analyzed by : SDeeso
REPORT ID: 23E133 Page 285 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GC/FID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23045.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
Sample ID
Acquired
Printed
User
: 23E133-06
: 05/24/23 08:00:57
: 05/25/23 11:28:14
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(C 1O-C24)
I totals
•••••••••••••••••
0.4
0.2
--FlO
R tent ion Time
2 3
1.597
5.329
Ol
N
(Y)
Lri
Area
1204413
541604
112505
79169
.. ......., ............................
19~%~1·
Software Version: Version 3.3.1
Page 1 of 1
Average RF ESTD conc.
l ppm]
16632.78922 72.412
26182.66222 20.686
26203.75493 4.293
24916.61874 3.177
100.568
0.4
0.2
REPORT ID: 23E133 Page 286 of 345
QC SUMMARIES
REPORT ID: 23E133 Page 287 of 345
METHOD SW3520C/8015D
PETROLEUM HYDROCARBONS BY EXTRACTION
Client : BRICE Date Collected: 05/22/23 11:15
Project : TEAD-S Date Received: 05/22123
Batch No. 23E133 Date Extracted: 05/22/23 11:15
Sample ID MBLK1W Date Analyzed: 05/24123 04:55
Lab Samp ID: DSE026WB Dilution Factor: 1
Lab File ID: LE23035A Matrix: WATER
Ext Btch ID: 23DSE026W % Moisture: NA
Calib. Ref.: LE23033A Instrument ID: D5
RESULTS LOQ DL LOD
PARAMETER (ug/L) (ug/L) (ug/L) (ug/L)
...... _-----------_ .... _------...... ----------_ .. _------....... ------------.. -----
TPH-Extractable (C10-C24) ND 500 100 200
SURROGATE PARAMETERS RESULT SPK AMT %RECOVERY QC LIMIT
.. ---_ .................... _--_ ........ _-........... _ ........ -.......... ---------.. ----.. -------.... -..........
Bromobenzene 792 1000 79 50-130
Hexacosane 233 250 93 50-140
Notes:
Detection limits are reported relative to sample result significant figures.
Sample Amount 1000ml Final Volume: 10ml
Prepared by : RGalan Analyzed by : SDeeso
REPORT ID: 23E133 Page 288 of 345
CLIENT
PROJECT
BATCH NO.
METHOD
MATRIX
: BRICE
: TEAD-S
: 23E133
: SW3520C/8015D
: WATER
DILUTION FACTOR: 1
SAMPLE ID : MBLK1W
LAB SAMPLE ID : DSE026WB
LAB FILE ID LE23035A
DATE PREPARED 05/22/23 11:15
DATE ANALYZED 05/24/23 04:55
PREP BATCH 23DSE026W
CALIBRATION REF: LE23033A
ACCESSION:
PARAMETERS
TPH-Extractable (C10-C24)
SURROGATE PARAMETERS
-----..... -.... -........... --_ .... _-
Bromobenzene
Hexacosane -
EMAX QUALITY CONTROL DATA
LAB CONTROL SAMPLE ANALYSIS
% MOISTURE:NA
1 1
LCS1W LCD1W
DSE026WL DSE026WC
LE23036A LE23037A
05122/23 11: 15 05/22/23 11:15
05/24/23 05:14 05124123 05:32
23DSE026W 23DSE026W
LE23033A LE23033A
MBResult SpikeAmt LCSResult LCSRec SpikeAmt
(ug/l) (ug/l) (ug/L) (%) (ug/L)
ND 5000 5070 101 5000
SpikeAmt LCSResult LCSRec SpikeAmt
(ug/l) (ug/l) (%) (ug/l)
-----------_ ...... ---.. ----.... -
1000 823 82 1000
250 263 105 250
MB: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
LCDResult LCDRec
(ug/l) (%)
5120 102
LCDResult LCDRec
(ug/l) (%)
----.... --.
858 86
273 109
RPD
(%)
QCLimit MaxRPD
(%) (%)
1 36-132 30
QCLimit
(%)
----------
50-130
50-140
REPORT ID: 23E133 Page 289 of 345
CLIENT
PROJECT
BATCH NO.
METHOD
MATRIX
: BRICE
: TEAD-S
: 23E133
: SW3520Cl8015D
: WATER
DILUTION FACTOR: 1
SAMPLE ID SI3-CAM-DWI-052023
LAB SAMPLE ID 23E133-05
LAB FILE ID LE23042A
DATE PREPARED 05/22123 11: 15
DATE ANALYZED 05/24/23 07:05
PREP BATCH 23DSE026W
CALIBRATION REF: LE23033A
ACCESSION:
PSResult SpikeAmt
PARAMETERS (ug/l) (ug/l)
TPH-Extractable (C10-C24) ND 5550
SpikeAmt
SURROGATE PARAMETERS (ug/l)
EMAX QUALITY CONTROL DATA
MS/MSD ANALYSIS
1
S13-CAM-DWI-052023MS
23E133-05M
LE23043A
05/22123 11: 15
05/24/23 07:23
23DSE026W
LE23033A
MSResult
(ug/l)
MSRec SpikeAmt
(%) (ug/l)
5430 98 5600
MSResult MSRec SpikeAmt
(ug/l) (%) (ug/l)
~ w w w ______________ • ______ ---------.--------.----.. -
Bromobenzene 1110 890 80 1120
Hexacosane 278 281 101 280
PS: Parent Sample MS: Matrix Spike MSD: Matrix Spike Duplicate
% MOISTURE: NA
1
SI3-CAM-DW1-052023MSD
23E133-05S
LE23044A
05/22/23 11: 15
05/24/23 07:42
23DSE026W
LE23033A
MSDResult MSDRec RPD
(%)
QCLimit MaxRPD
(ug/l) (%) (%) (%)
5690 102 5 36-132 30
MSDResult MSDRec QCLimit
(ug/l) (%) (%)
. --. -. -------------
890 79 50-130
298 106 50-140
REPORT ID: 23E133 Page 290 of 345
QC DATA
REPORT ID: 23E133 Page 291 of 345
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
Inst. Name: : D5 (Offline)
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23035.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
SampleID
Acquired
Printed
User
: DSE026WB
: 05/24/23 04:55:38
: 05/25/23 11:26:58
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(CI0-C24)
M.OIL(C24-C36)
I totalS ...............
. .............. . : :::::::::::::::
1.5
-FlO
R ~tention Time
1.0
0.5
('I)
IX) r-:
~ .Ii
I 0.0
2
('I)
0
""'I
I
3 4
1.598
5.287
r--
IX)
N
lI'i
0) ('I)
IX) IX)
0 co
1 11
II I
5
Area
1317946
6
Minutes
610714
5470
3062
2408
7
Software Version: Version 3.3.1
8
Page 1 of 1
Average RF ESTD conc.
(ppm]
16632.78922 79.238
26182.66222 23.325
26203.75493 0.209
24916.61874 0.123
20507.13317 0.117
1················· · ................ . .. ................ . · ......... " .. ,-, · ............. .
, ibj.QIZ
9 10 11
1.5
1.0
0.5
0.0
REPORT ID: 23E133 Page 292 of 345
Page 1 of!
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331 \Data\LE23\LE23036.dat
: D:\Projects\EZC331 \Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
SampleID
Acquired
Printed
User
: DSE026WL
: 05/24/2305:14:11
: 05/25/23 11:27:05
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DlESEL(TOT AL)
DlESEL(ClO-C24)
M.OIL(C24-C36)
I TotalS ... , ........... .
..... ..... ..... . ........... . .. . ::::::::::::::::::
................... , .................... ................. ... . ................. ... . ........ -....... , .. ................. -. . ................ . . ............... . , ..
~ : : : : : : : : : : : : : : : ~ : ~:;:
1.599
5.272
Area
1368914
687383
12798767
12632694
278745
Average RF ESTD conc.
[ppm)
16632.78922 82.302
26182.66222 26.253
26203.75493 488.433
24916.61874 506.999
20507.13317 13.593
1.5.----------------------------------.-1.5
..
0 >
-FlO
R tention Time
1.0 1.0
N .....
N
Lri
0.5 0.5
0.0 jL,~~~~[JJlillrutrutt~~~~W_---------------_4_ 0.0
2 3 4 5 6
Minutes
7
Software Version: Version 3.3.1
8 9 10 11
"" ~
REPORT ID: 23E133 Page 293 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23037.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
SampleID
Acquired
Printed
User
: DSE026WC
: OS/24/2305:32:44
: OS/25/23 11:27:12
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOTAL)
DIESEL(CI0-C24)
M.OIL(C24-C36)
1.599
5.295
Area
1426744
714253
12917390
12754418
291318
Page 1 of 1
Average RF ESTD conca
[ppm]
16632.78922 85.779
26182.66222 27.280
26203.75493 492.960
24916.61874 511.884
20507.13317 14.206
,................... . ....................... .. ........... ...... .. .. ................. . .. ......... ....... . .. ................... .
•• li~.tIQ~ •
1.5,--------,-------------------------------,-1.5
RAto~nti"n Time
1.0 1.0
0.5 0.5
0.0 -l"-1-11-1¥.~t+H+++-+L1..LW.LLLI!l-Il-Ht+HH.ff=f'=fHl...H_.L-----------------l-0.0
2 3 4 5 6
Minutes
7
Software Version: Version 3.3.1
8 9 10 11
REPORT ID: 23E133 Page 294 of 345
Page 10fl
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D: \Projects\EZC331 \Data\LE23\LE23043.dat
: D:\Projects\EZC331 \Method\DSD5B16M.met
: D:\Projects\EZC331 \Sequence\LE23.seq
Sample ID
Acquired
Printed
User
: 23E133-05M
: 05/24/2307:23:57
: 05/25/23 11:27:57
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(C 1O-C24)
ITotal~ •• ••• ••••••••. ......... ..1
1.598
5.344
Area
1332547
661441
12306090
12176109
Average RF ESTD conc.
r ppm]
16632.78922 80.116
26182.66222 25.263
26203.75493 469.631
24916.61874 488.674
I············· ..... .. .............. ... ............. .... . " ................... . .. ............ ..... .
•• 1()()3.683
1.5--,----------------------------------,-1.5
'6 >
1.0
0.5
-FlO
Retention Time
1.0
"<t
"<t
C')
ll'i 0.5
0.0 -tL~~'Im+_W~illllLUll1P_r+t#~=mL.J_Hl----------------_l_ 0.0
2 3 4 5 6
Minutes
7
Software Version: Version 3.3.1
8 9 10 11
'6 >
REPORT ID: 23E133 Page 295 of 345
Page 1 of 1
Inst. Name: : D5 (Offline)
METHOD 8015 by GC/FID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23044.dat
: D:\Projects\EZC331\Method\DSD5B16M.met
: D:\Projects\EZC331\Sequence\LE23.seq
Sample ID
Acquired
Printed
User
: 23E133-05S
: 05/24/23 07:42:30
: 05/25/23 11:28:04
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(C1O-C24 )
I totals· ...............
: i::::::::::::: ::
1.598
5.323
I.· ..
Area
1317910
694757
12792948
12620182
274257~;1
Average RF ESTD conc.
[ppm ]
16632.78922 79.236
26182.66222 26.535
26203.75493 488.210
24916.61874 506.497
··1 1100.478
1.5-,------------------------------------,1.5
'5 >
-FlO
R tention Time
1.0 1.0
C")
N
C")
Lri
0.5 0.5
0.0 --f"-rHt.*FfHtttH+-J-1--LLJUUJ.l.U4l+lHR.ft='l'=fIH-YI-+-}l------------------i-0.0
2 3 4 5 6
Minutes
7
Software Version: Version 3.3.1
8 9 10 11
'5 >
REPORT ID: 23E133 Page 296 of 345
INITIAL CALIBRATIONS
REPORT ID: 23E133 Page 297 of 345
Lab Name
Instrument ID
GC Colulilm
Column size ID
LFID & Datetime:
LFID & Datetime:
LFID & Datetime:
LFID & . Datetilile:
LFID & Datetime:
LFID & Datetime:
LFID & Datetime:
CONC UNIT:
iNITIAL CALIBRATION
METHOD MaOl5
EMAX Inc
05
HP5
30MXO.32HM 0.25UM
LB16040A 02/17123 04:34
LB16041A 02117/23 04:52
L616042A 02/17123 05:10
LB16043A 02117123 05:29
LB16044A 02/17/23 05:47
LB16045A 02/17/23 06:05
LB16046A 02/17/23 06:24
ppm
I CONC I CALIBRATION FACTORS (AREA)/UNIT I I
I COMPOUND X I 1.00XI 4.00XI 10.00XI 100.00XI 200.00XI 400.00XI 600.00XI MEAN I%RSDI
I I I I I I I I 1 1=1
IDIESEL(TOTAL> 5.001 254521 229001 251271 291881 272021 271551 264031 26203.81 7.51
IDIESELCC10·C24) 5.001 246201 220181 235171 276591 258751 256821 250461 24916.61 7.21
IDIESEL(C10·C2B) 5.001 246201 220181 235451 277651 259311 258101 251351 24974.81 7.41
IDIESEL(C10·C25) 5.001 246201 220181 235311 277351 259241 257741 251131 24959.31 7.31
I DIESELCC9-C24L 5. QOI Z46g0 I 2~.6751246441 2~~Q 12~~4!J . 26~_~L 25850 I 25719.0 I 7.71
IDIESEL(C9-C25) 5.001 246201 226751 246591 288951 269901 265761 2591YftS76L71t.81
IDIESEL(C10·C36) 5.001 246201 220181 235451 277651 259321 258141 251391 24976.11 7.41
IDIESELCC10·C40) 5.001 246201 220181 235451 277651 259321 258141 251391 24976.11 7.41
ITPH(C12-C30) 5.001 196571 180091 189731 226681 21101/210931 204151 20273.81 7.61
I································ ········I········I········I········I········I·······~I·······-1-······-1-·······-1-···1
I SURROGATE X I O.OOXI 1.00XI 2.00XI 4.00XI 5.00XI 6.00XI 11.00XI MEAN I%RSDI
I I I I I I I I I 1=1
IBROMOBENZENE 20.001 01 164981 157981 165701 17166/ 172631 165021 16632.81 3.21
IHEXACOSANE 5.001 01 271051 249921 274461 260821 257471 257241 26182.71 3.51
I I I I I I I I I I_I
DSD5B16.MET
REPORT ID: 23E133 Page 298 of 345
Lab Name
Instrument ID
GC Columm
Column size ID
LFID & Datetime:
LFID & Datetime:
LFID & Datetime:
LFID & Datetime:
LFID & Datetime:
LFID& Datetime:
LFIO & Datetime:
INITIAL CALIBRATION
METHOD M8015
EMAX Inc
05
HP5
30MXO.32MM 0.25UM
LB16040A 02/17/23 04:34
LB16041A 02/17/23 04:52
LB16042A 02/17/23 05:10
LB16043A 02/17/23 05:29
LB16044A 02/17/23 05:47
LB16045A 02/17/23 06:05
LB16046A 02/17/23 06:24
I I RT OF STANDARDS (MIN) I MEAN I RT WINDOW I RTW I NDOW I
I COMPOUND I 1.0X I 4.0XI 10.0XI100.0XI200.0XI400.0XI600.0XI RT I FROM I TO I WIDTH I
I I 1=1=1=1=1=1=1=1=1 I
IDIESELCTOTAL) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
IDIESEL(C10·C24) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
IDIESELCC10·C28) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
IDIESEL(C10'C25) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
IDIESEL(C9-C24) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
IDIESEL(C9-C25) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
IDIESEL(C10·C36) NAI NAINAI HAl HAl NAI foIAlNAINAI NAI NPtI
IDIESELCC10·C40) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
ITPH(C12-C30) NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI NAI
I································ ·····-1-····-1-····-1-····-1-····-1-····-1-····-1-····-1-····-1-····-1-······-1
I SURROGATE O.OXI 1.0XI 2.0XI 4.0XI 5.0XI 6.0XI 11.0XI RT I FROM I TO I WIDTH I
I I~I I I I 1-:--1=1=1=1=1 I
IBROMOBENZENE I 1.6371 1.6361 1.6361 1.6381 1.6381 1.6391 1.6401 1.6381 1.6281 1.6481 0.0101
IHEXACOSANE I 5.3451 5.3171 5.3451 5.3441 5.3511 5.3421 5.3661 5.3441 5.1501 5.5381 0.1941
I 1 __ 1 __ 1 __ 1 __ 1 __ 1 __ 1 __ 1 __ 1 __ 1 __ 1 I
DSD5B16.MET
REPORT ID: 23E133 Page 299 of 345
Page 1 of 1
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LB16\LB16040.dat
: D:\Projects\EZC331\Method\DSD5B16.met
: D:\Projects\EZC331\Sequence\LB16.seq
SampleID
Acquired
Printed
User
: DSD5B16001 DSL 5PPM
: 02117/23 04:34:11
: 02/17/23 10:34:02
:SDEESO
FID· Results
Name
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(ClO-C24)
DIESEL(CI0-C28)
DIESEL(ClO-C25)
DIESEL(C9-C24 )
DIESEL(C9-C25)
DIESEL(ClO-C36)
DIESEL(ClO-C40)
TPH(CI2-C30)
Retention Time Area
127260
123099
123099
123099
123099
123099
123099
123099
98285
Average RF ESTD conc.
[ ppm]
26203.75493
24916.61874
24974.8U14
24959.34205
25719.00905
25761. 73236
24976.07698
24976.07698
20273.82224
O.OOOBDL
O.OOOBDL
5.000 CAL
5.000 CAL
5.000 CAL
5.000 CAL
5.000 CAL
5.000 CAL
5.000 CAL
5.000 CAL
5.000 CAL
0.100 -,---_-_-F=ID,---------------------~-------TO.100
Retention Time
0.075 0.075
0.050 0.050
0.025 0.025
0.000 0.000
2 3 4 5 6 7 8 9 10 11
Minutes
Software Version: Version 3.3.1
g
REPORT ID: 23E133 Page 300 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LB16\LB16041.dat
: D:\Projects\EZC331\Method\DSD5B16.met
: . D:\Projects\EZC331 \Sequence\LB16.seq
Sample ID
Acquired
Printed
User
: DSD5B16002 DSL 20/20/5PPM
: 02/17123 04:52:32
: 02/17/23 10:34:28
:SDEESO
FIDResults
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(ClO-C24)
DIESEL(CIO-C28)
DIESEL(ClO-C25)
DIESEL(C9-C24)
DIESEL(C9-C25)
DIESEL(ClO-C36)
DIESEL(C 1O-C40)
TPH(CI2-C30)
FlO
R tention Time
0.2
~ >
0.1
1.636
5.317
r-.
C;;
to
Area
329954
135526
458009
440350
440350
440350
453490
453490
440350
440350
360177
Page 1 of 1
AverageRF ESTD conc.
[ppm ]
16632.78922 20.000 CAL
26182.66222 5.000 CAL
26203.75493 20.000 CAL
24916.61874 20.000 CAL
24914_. 812L4 20.ODneAL
24959.34205 20.000 CAL
25719.00905 20.000 CAL
25761.73236 20.000 CAL
24976.07698 20.000 CAL
24976.07698 20.000 CAL
20273.82224 20.000 CAL
0.2
"0 >
0.1
0.0 H-~IfffjM"'FF!'1"'~f#91ffi4Hf-.l4----L,~------------,--------{ 0.0
~~~ 2 6 7
Minutes
9 10 3 4 5 8 11
Software Version: Version 3.3.1
REPORT ID: 23E133 Page 301 of 345
METHOD 8015 by GC/FID
EMAX Laboratories, Inc.
Inst. Name: :D5 (Offline)
File
Method
Sequence:
: D:\Projects\EZC331\Data\LB16\LB16042.dat
: D:\Projects\EZC331\Meithod\DSD5B16.met
: D:\Projects\EZC331\Sequence\LB16.seq
SampleID
Acquired
Printed
User
: DSD5B16003 DSL 50/40/10PPM
: 02/17/2305:10:56
: 02/17/2310:35:13
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOTAL)
DIESEL(CI0-C24)
DIESEL(CI0-C28)
DIESEL(CI0-C25)
DIESEL(C9-C24)
DIESEL(C9-C25)
DIESEL(CI0-C36)
DIESEL(C1O-C40)
TPH(CI2-C30)
0.2
..,
0 >
0.1
2
r ...
Time
3 4
1.636
5345
10 ~
('t)
Iri
5
Area
631919
249915
1256326
1175829
11'Z727L
1176568
1232188
1232927
1177271
1177271
948632
6 7
Minutes
Software Version: Version 3.3.1
8
Page 1 of 1
Average RF ESTD conc.
(ppm')
16632.78922 40.000 CAL
26182.66222 10.000 CAL
26203.75493 50.000 CAL
24916.61874 50.000 CAL
24914.81214 50.QOQ CAL
24959.34205 50.000 CAL
25719.00905 50.000 CAL
25761.73236 50.000 CAL
24976.07698 50.000 CAL
24976.07698 50.000 CAL
20273.82224 50.000 CAL
9 10 11
0.2
g
0.1
REPORT ID: 23E133 Page 302 of 345
lost. Name: : D5 (Oftline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LB16\LB16043.dat
: D:\Projects\EZC331\MethodIDSD5B16.met
: D:\Projects\E~331\Sequence\LB16.seq
SampleID
Acquired
Printed
User
: DSD5B16004 DSL 500/80/20PPM
: 02/17/2305:29:14
: 02/17/23 10:35:27
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(C1 0-C24)
DJESEL(ClO-C28)
DIESEL(CI0-C25)
DIESEL(C9-C24)
DIESEL(C9-C25)
DIESEL(CI0-C36)
DlESEL(CIO-C40)
TPH(CI2-C30)
l.638
5.344·
Area
1325584
548920
14593933
13829692
13882587
13867327
14410088
14447723
13882587
13882587
11334233
Page 1 of 1
Average RF ESTD conc.
[ppm)
16632.78922 80.000 CAL
26182.66222 20.000 CAL
26203.75493 500.000 CAL
24916.61874 500.000 CAL
24974.81214 5QO.OOP.CAL.
24959.34205 500.000 CAL
25719.00905 500.000 CAL
2576l.73236 500.000 CAL
24976.07698 500.000 CAL
24976.07698 500.000 CAL
20273.82224 500.000 CAL
1.5-.--------------------------------.-1.5
1.0
0.5
-FlO
Retention Time
1.0
0.5
0.0 -»f:l!mem+.J.I.l-I-l-U..l.U..LRLLLI-J.I.I.I~:f:I::¥=+_+Hfl_+t_H_JL---------------___+o.o
~~' 2 5 6 7
Minutes
3 4 8 9 10 11
Software Version: Version 3.3.1
REPORT ID: 23E133 Page 303 of 345
lost. Name: : D5 (Omine)
METHOD 8015 by GCIFID
EMAX Laboratories, Ine.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LBI6\LBI6044.dat
: D:\Projects\EZC331Wetbod\DS])5B16.met
: D:\Projects\EZC331\Sequence\LB16.seq
SampleID
Acquired
Printed
User
: DSD5B16005 DSL 1000/100/25PPM
: 02/17/23 05:47:38
: 02/17/23 10:35:39
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOTAL)
DIESEL(CIO-C24)
DIESEL(CIO.,.C28)
DIESEL(CIO-C25)
DIESEL(C9-C24)
DIESEL(C9-C25)
DIESEL(C10-C36)
DIESEL(C10-C40)
TPH(C12-C30)
iH
...
1.638
5.351
Area
1716598
652056
27202149
25874558
25211321
25924360
26940662
26990464
25931684
25931684
21101382
Page 1 of 1
Average:RF ESTD cone.
(ppm)
16632.78922 100.000 CAL
26182.66222 25.000 CAL
26203.75493 1000.000 CAL
24916.61874 1000.000 CAL
24974JH2J4. lQ9Q,Q.9QCAL
24959.34205 1000.000 CAL
25719.00905 1000;000 CAL
25761.73236 1000.000 CAL
24976.07698 1000.000 CAL
24976.07698 1000.000 CAL
20273.82224 1000.000 CAL
1.5-,---,-----------------------------.1.5
FlO
R tention Time
1.0 1.0
N ..,.
M
'6 ~ '" > g
0.5 0.5
0.0 -It¥t'ftP~Wj..l.Ll..Ll.L..LLL.LLLLLLI...ll.J..l..IL..Jrn::~rtfttHl_\l....---------------_+ 0.0
~~~ 2 6 7
Minutes
4 5 3 8 9 11 10
Software Version: Version 3.3.1
REPORT ID: 23E133 Page 304 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LB16\LB16045.dat
: D:\Projects\EZC331\Method\DSD5B16.met
: D:\Projects\EZC331\Sequence\LB16.seq
Sample ID
Acquired
Printed
User
: DSD5B16006 DSL 2000/120/30PPM
: 02/17/23 06:05:57
: 02117/23 10:35:58
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(CI0-C24)
DIESEL(ClO-C28)
DIESEL(CI0-C25)
DIESEL(C9-C24)
DIESEL(C9-C25)
DIESEL(C 1O-C36)
D IESEL(C 1O-C40)
TPH(C12-C30)
2.0
FlO
R tention Time
1.5 N
to(Y)tO
r--.I':!r--.o ll)~NLq~r--.
ON NCC!(Y)
<X) NOO
.....: ("I) to 0
'i5 1.0 C'!~
(Y) '<0 > (Y)o>
<00
('t)mN
~
0.5
l.639
5.342
0> (Y) (Y)
..t
N -.r (Y) .n
Area
2071574
772417
54309003
51364869
51619128
51548928
52968152
53152211
51627177
51627177
42186218
Page 1 of 1
AverageRF ESTD conc.
[ ppm]
16632.78922 120.000 CAL
26182.66222 30.000 CAL
26203.75493 2000.000 CAL
24916.61874 2000.000 CAL
24974.81214 2000.QQOCAL .
24959.34205 2000.000 CAL
25719.00905 2000.000 CAL
2576l. 73236 2000.000 CAL
24976.07698 2000.000 CAL
24976.07698 2000.000 CAL
20273.82224 2000~000 CAL
2.0
1.5
1.0 'i5 >
0.5
0.0 -mtftt'11'-4-'-'..l..l....J...LLL.LL.L.J--LLl...l..l....J.-L..I.l..JLLI.L-4--f--+"'fFt'rI++++-'------------------_f_ 0.0
~\l-~ 2 3 9 10 11 5 6 7
Minutes
8 4
Software Version: Version 3.3.1
REPORT ID: 23E133 Page 305 of 345
Inst. Name: : DS (Offline)
METHOD 801S by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LBl6\LB16046.dat
: D:\Projects\EZC331 \Method\DSDSB16.met
: D:\Projects\EZC331\Sequence\LB16.seq
SampleID
Acquired
Printed
User
: DSDSB16007 DSL 3000/220/SSPPM
: 02117/2306:24:19
: 02/17/23 10:36:14
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(C1 0-C24)
. DIESEL(ClO~C28)
DIESEL(CI0-C25)
DIESEL(C9-C24 )
DIESEL(C9-C25)
DIESEL(CI0-C36)
DIESEL(CI0-C40)
TPH(CI2-C30)
..
r.·····
1.640
5.366
Area
3630476
1414809
79208394
75138224
7540.4700.
75339769
77550268
77751813
75418117
75418117
61245926
.......................... ~
6~j5~d~13;
Page 1 ofl
Average RF ESTD conc.
[ppm]
16632.78922 220.000 CAL
26182.66222 55;000 CAL
26203.75493 3000.000 CAL
24916.61874 3000.000 CAL
24274.81214 . 3~Q()Q,Q0.9CAL
24959.34205 3000.000 CAL
25719.00905 3000.000 CAL
25761.73236 3000.000 CAL
24976.07698 3000.000 CAL
24976.07698 3000.000 CAL
20273.82224 3000.000 CAL
3~--~------------------------------------------------------~3
FlO
R tention Time
2 2
O~~~2~~~3~~~4~~~5~TH~6~~~7~~~8~~~9~~~1~O~~~1~1~~~~
Minutes
Software Version: Version 3.3.1
REPORT ID: 23E133 Page 306 of 345
SECOND SOURCE
VERIFICATION
REPORT ID: 23E133 Page 307 of 345
Lab Name
Instrument ID
GC Columm
INITIAL ·CALIBRATION ·VERIFICATION
MEl'HODM80·15
EMAX Inc
D5
HP5
Column size ID 30MXO.32MM 0.25UM
Mid COhC Init LFID & Datetime: LB16043A 0211712023 05:29
Conc Cont LFIO & Datetime: LB16048A02/17/2023 07:01
CONC UNIT ppm
I I RT I RT WINDOW I TRUE I AVERAGE I RESULT I I %D I
I COMPOUND I MINUTES I FROM I TO I CONC I CF AREA I CONC I %D IQLI LIMITS I
I I I I 1=====1 I I I 1=1 I
IDIESEL(TOTAL) I NAI HAl NAI 500.01 26203.81138818821 529.771 61 I 201
IDIESEL(C10·C24) I NAI NAI NAI 500.01 24916.61133343871 535.161 71 I 201
IDIESEL(C10·C28) I NAI NAI NAI 500.01 24974.81134482041 538.471 81 I 201
IDIESEL(C10·C25) I NAI NAI NAI 500.01 24959.31133935351 536.611 71 I 201
IDIESEL(C9·C24) I NAI NAI NAI 500.01 25719.01136244261 529.741 61 I 201
IDIESEL(C9·C25) I NAI NAI NAI 500.01 25761.71136835741 531.161 61 I 201
IDIESEL(C10:C36) I NAI NAI NAI 500.01 24976.11134521551 538.601 81 I 201
IDIESEl(C10·C40) I NAI NAI NAI 500.01 24976.11134521551 538.601 81 I 201
ITPH(C12·C30) I NAI NAI NAI 500.01 20273.81115441471 569.411 141 I 201
1································1·······1·······1·······1·······1·········1········1········1······1··1······1
I SURROGATE I MINUTES I FROM I .. TO. ITBUECQNI CF.I ~.I CONC.I%IJ. IQLJ LIMITS 1
1 I I I I I I I 1=1=1=1
IBROMOBENZENE I 1.6381 1.6281 1.6481 80.01 16632.81 13969241 83.991 51 1 201
IHEXACOSANE I 5.3881 5.1941 5.5821 20.01 26182.71 5134021 19.611 ·21 I 201
I I I I 1 __ 1 I I 1 __ 1_1 __ 1
DSD5B16.MET
REPORT ID: 23E133 Page 308 of 345
Inst. Name: : D5 (Offline)
METHOD S015 by GC/FID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\ProJects\EZC331 \Data\LB16\LB1604S.dat
: D:\Projects\EZC331 \Method\DSD5B16.met
: D:\Projects\EZC331 \Sequence\LB16.seq
SampleID
Acquired
Printed
User
: IDSD5B16002 DSL 500/80/20PPM
: 0211712307:01:10
: 02117123 10:36:41
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(ClO-C24)
DIESEL(ClO-C28)
DIESEL(C10-C25)
DIESEL(C9-C24 )
DIESEL(C9-C25)
DIESEL(ClO-C36)
DIESEL(ClO-C40)
TPH(C12-C30)
1.638
5.388
Area
1396924
513402
13881882
13334387
13448204
13393535.
13624426
13683574
13452155
13452155
11544147
Page 1 of 1
AverageRF ESTD conc.
[ppm]
16632.78922 83.986
26182.66222 19.608
26203.75493 529.767
24916.61874 535.160
24974.81214-538.471
24959.34205 536.614
25719.00905 529.741
25761.73236 531.159
24976.07698 538.602
24976.07698 538.602
20273.82224 569.411
1.5,-----------------------------------,-1.5
±< o >
1.0
0.5
-FlO
Retention Time
1.0
0.5
0.0 -h++-i"I'f¥.*l+l-I+Hi-+--WI-+l-LLLLLLLl4+l+lH+I+!=f==f"9'¥f"--r-f++L----------------!-0.0
2 3 4 5 6 7 8 9 10 11
Minutes
Software Version: Version 3.3.1
REPORT ID: 23E133 Page 309 of 345
DAILY CALIBRATIONS
REPORT ID: 23E133 Page 310 of 345
Lab Name
Instrument ID
GC Columm
Column size ID
Mid Cone Init LFID & Datetime:
Cone Cant LFID & Datetime:
CONC UNIT
CONTINUE CALIBRATION
METHOD M8015
EMAX Ine
D5
HP5
30MXO.32MM 0.25UM
LB16043A 02/17/2023
LE23033A OS/24/2023
ppm
05:29
04:18
I RT RT WINDOW I TRUE I AVERAGE I RESULT I I %D I
COMPOUND I MINUTES I FROM I TO I CONC I CF I AREA I CONC I %D IQLI LIMITS I
========1=1=1=1= I I 1=1=1=
IDIESEL(TOTAL) I NAI NAI NAI 500.0 26203.81122083091 465.901 ·71 I 20
IDIESEl(C10·C24) I NAI NAI NAI 500.0 24916.61118882681 477.121 ·51 I 20
IDIESEL(C10·C28) I NAI NAI NAI 500.0 24974.81119135331 477.021 ·51 I 20
IDIESEl(C10·C25) I NAI NAI NAI 500.0 24959.31119099441 477.171 ·51 I 20
IDIESEl(C9·C24) I NAI NAI NAI 500.0 25719.01119981701 466.511 ·71 I 20
IDIESEl(C9·C25) I NAI NAI NAI 500.0 25761.71120198461 466.581 ·71 I 20
IDIESEL(C10·C36) I NAI NAI NAI 500.0 24976.11119135331 477.001 ·51 I 20
IDIESEL(C10·C40) I NAI NAI NAI 500.0 24976.11119135331 477.001 ·51 I 20
ITPH(C12·C30) I NAI NAI NAI 500.0 20273.81 99761161 492.071 ·21 I 20
1································1·······1·······1·······1······· ·········1········1········1······1··1······ '
I SURROGATE I MINUTES I FROM I TO ITRUECON CF I AREA I CONC I %D IQLILIMITS
I 1==1=1=1=1 I I 1=1=1=1
IBROMOBENZENE I 1.5991 1.5891 1.6091 80.01 16632.81 13569891 81.581 21 I 201
IHEXACOSANE I 5.3041 5.1101 5.4981 20.01 26182.71 4790481 18.301 ·91 I 201
I 1 __ 1 __ 1 __ 1 __ 1 I I 1 __ 1_1_1
REPORT ID: 23E133 Page 311 of 345
Page 1 of 1
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331\Data\LE23\LE23033.dat
: D:\Projects\EZC331\Method\DSD5B16.met
: D:\Projects\EZC331\Sequence\LE23.seq
SampleID
Acquired
Printed
User
: CDSD5B160567 DSL 500/20/80 PPM
: 05/24/2304:18:32
: 05/25/23 11:26:43
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(CI0-C24)
DIESEL(CIO-C28)
DIESEL(CIO-C25)
DIESEL(C9-C24)
DIESEL(C9-C25)
DIESEL(CIO-C36)
DIESEL(CIO-C40)
TPH(CI2-C30)
l.599
5.304
I ..
Area
1356989
479048
12208309
11888268
11913533
11909944
11998170
12019846
11913533
11913533
9976116
Average RF ESTD conc.
(ppm]
16632.78922 8l.585
26182.66222 18.296
26203.75493 465.899
24916.61874 477.122
24974.81214 477.022
24959.34205 477.174
25719.00905 466.510
2576l.73236 466.578
24976.07698 476.998
24976.07698 476.998
20273.82224 492.069
. ··1·················· . .... . ................ . ...... .............. -... . ....................
•.•• > 4376.25() • •
1.5,--_-_-F=IO=-----------------------------.1.5
R tention Time
1.0 1.0
0.5 0.5
0.0 ht!'~fR-tIH+~.LLI..LLL.L4-l+1flP1H>-+-++-I4l,jJ----------------____i_ 0.0
2 3 4 5 6
Minutes
7
Software Version: Version 3.3.1
8 9 10 11
< HI . ....
REPORT ID: 23E133 Page 312 of 345
Lab Name
Instrument 10
GC Columm
Column size 10
Mid Cone Init LFID & Datetime:
Cone Cant LFID & Datetime:
CONC UNIT
CONTINUE CALIBRATION
METHOD M8015
EMAX Ine
D5
HP5
30MXO.32MM 0.25UM
LB16043A 02/17/2023
LE23048A OS/24/2023
ppm
05:29
08:56
I I RT RT WINDOW I TRUE I AVERAGE I RESULT I I .%'D I
I COMPOUND I MINUTES I FROM I TO I CONC I CF I AREA I CONC I .%'D IQLILIMITSI
I 1=1=1=1=1 I I 1=1=1=
IDIESEL(TOTAL) I NAI NAI NAI 500.01 26203.81117872211 449.831 ·101 I 20
IDIESEL(C10·C24) I NAI NAI NAI 500.01 24916.61114774511 460.631 ·81 I 20
IDIESEl(C10-C28) I NAI NAI NAI 500.01 24974.81115013871 460.521 -81 I 20
IDIESEL(C10-C25) I NAI NAI NAI 500.01 24959.31114978061 460.661 -81 I 20
IDIESEL(C9-C24) I NAI NAI NAI 500.01 25719.01115834531 450.391 -101 I 20
IDIESEL(C9-C25) I NAI NAI NAI 500.01 25761.71116038081 450.431 -101 I 20
IDIESEL(C10-C36) I NAI NAI NAI 500.01 24976.11115021081 460.521 -81 I 20
IDIESEL(C10-C40) I NAI NAI NAI 500.01 24976.11115021081 460.521 -81 I 20
ITPH(C12-C30) I NAI NAI NAI 500.01 20273.81 96282001 474.911 -51 I 20
1--------------------------------1-------1-------1-------1-------1---------1--------1--------1------1--1------
I SURROGATE I MINUTES I FROM I TO ITRUECONI CF I AREA I CONC I .%'D IQLILIMITS
I 1=1=1=1=1 I I 1=1=1=1
IBROMOBENZENE I 1.5971 1.5871 1.6071 80.01 16632.81 13172181 79.191 -11 I 201
IHEXACOSANE 15.32715.13315.5211 20.0126182.714639191 17.721 -111 I 201
I 1 __ 1 __ 1 __ 1 __ 1 I I 1 __ 1_1 __ 1
REPORT ID: 23E133 Page 313 of 345
Inst. Name: : D5 (Offline)
METHOD 8015 by GCIFID
EMAX Laboratories, Inc.
File
Method
Sequence:
: D:\Projects\EZC331 \Data\LE23\LE23048.dat
: D:\Projects\EZC331\Method\DSD5B16.met
: D:\Projects\EZC331\Sequence\LE23.seq
SampleID
Acquired
Printed
User
: CDSD5B160569 DSL 500/20/80 PPM
: 05124123 08:56:41
: 05/25/23 11:28:35
:SDEESO
FID Results
Name Retention Time
BROMOBENZENE
HEXACOSANE
DIESEL(TOT AL)
DIESEL(CIO-C24)
DIESEL(CIO-C28)
DIESEL(CI0-C25)
DIESEL(C9-C24)
DIESEL(C9-C25)
DIESEL(CIO-C36)
DIESEL(CIO-C40)
TPH(C12-C30)
ITOtalS • . . ............ .
' ............ . .................. i:>::::::::::::~ :
1.597
5.327
Area
1317218
463919
11787221
11477451
11501387
11497806
11583453
11603808
11502108
11502108
9628200
........................ , . ....................... . ........................ . ....... ............... .
103864619·,
Page 1 of 1
Average RF ESTD conc.
[ppm )
16632.78922 79.194
26182.66222 17.719
26203.75493 449.829
24916.61874 460.634
24974.81214 460.519
24959.34205 460.661
25719.00905 450.385
25761.73236 450.428
24976.07698 460.525
24976.07698 460.525
20273.82224 474.908
I ............ . . ................... . . .................... . ......................
•• 4225.3.28 •
1.5-.--------------------------------,-1.5
-FlO
Retention Time
1.0 1.0
0.5 0.5
0.0 l-M~~!m~nrmtlf:MU!:w..w1l11]l----------,__---_1o.o
2 3 4 5 6
Minutes
7
Software Version: Version 3.3.1
8 9 10 11
REPORT ID: 23E133 Page 314 of 345
ANALYTICAL LOGS
REPORT ID: 23E133 Page 315 of 345
J
I
1-
I~
I
I,·"
I
I
I'
I
I
I
1°'
I
I;'
I
ANALYSIS RUN tOG
for
EXTRACTABLE TPH
Note: For samples and relevant QCs/Standards
analyzed, refer to attached analytical sequence.
Comments:
toa-01
!
I
-2--'2. t:!, Gq'3 I '2:'':> M?/ 6
)
. Go(Y&od/-wko
~~dr;iJd!20a
. -. ..
'q .... 1rnL -MSF.:01,.Ol-05 '.
" .' o 15P:I1L "MSF-OI-01-09
p . ·;tPQpl cMSF-OI-Ol~07
P.?,O'IlL -MSF-OI-OI-0~
o 25 gL -MSF~Ol~03-18
¢:;J ..... TIlL -MSF~01-02-25
[]
Book#: AD5-061
Instrument No.: 05
Analytical Sequence: J~ f ~
Method File: ~'2l>stU" f)<;/yi61 b \ CCf>5E
.' ,
AKb5f3. t 5'1£ F-O~(J:.I b
J
Analytical Batch: C.AI"D'5~l5"Coq
SOP# Rev. #
(J'tMAX-8015D 8
~MAX-AKI021 AKI03 5
o EMAX-
..
STANDARDS ID Cone (ingJll
ICAl
[2(Diesel
.12!iV\otorOil [2rJP5 S>~-'t-Io-'f2-o'!,. If) -"1oct?
. !).tJY'<;..t ..
DSl DCC
.
ElECTRONfC DATA ARCHIVAL
Location Date
o EZCHROM_GC6890N
Analyzed By:
Date: REPORT ID: 23E133 Page 316 of 345
Friday, Feb 17, 2023 01 :31 PM REPORT ID: 23E133 Page 317 of 345
ANALYSIS RUN LOG
for
EXTRACTABLE TPH
Page 45
Note: For samples and relevant QCs/Standards Book#: ADS-061
analyzed, refer to attached analytical sequence. Instrument No.: os
Comments: Analytical Sequence:
Method File: CCl:) ~ r>flf IDS D5l? It ,
AIG05E.l1
Analytical Batch: CCC b fj P. '4 Ob (; 'I'
SOP # Rev. #
mMAX-801SD 8
~MAX-AK102/ AK103 5
o EMAX-
STANDARDS 10 Cone (mg/L)
ICAL
o Diesel
o Motor Oil 0 JPS
CH 2Cl z £.~5b Yilf r~£Nl.V·
DSLDCC SS1 ~-2-f? -If't -Of tcqk-r/zP
JPS/SW30 DCC ~S1.g -Z, -Q,,"'02 t;ct" /l{f7(;1
Alaska DCC >S5g.-~-Ol "'03 ~In
Arizona DCC
SYRINGES DRO ~$1r> ~ U -'50 -01 to
0 1 ml-MSF-OI-0I-05 C-t p~ S~~-U -If.~-ol 10
0 500 III -MSF-OI-01-06
0 250 Ill-MSF-OI-01-09
0 100 Ill-MSF-OI-01-07 ELECTRONIC DATA ARCHIVAL
0 50 Ill-MSF-OI-01-08 Location Date
0 25 Ill-MSF-01-03-18 o EZCHROM_GC6890N
0 10 Ill-MSF-OI-03-16 o External Hard Drive
0 1 Ill-MSF-01-02-25 Analyzed By:
0 Date: REPORT ID: 23E133 Page 318 of 345
................. ; ............................................................ +:
RW--:::.:::::::c:.: .• :: ....... , .......... ::, •....••..•..• :.;:::::::c .. :::.::.:: ... ·········································· ...................... ; .... :::::c.:::::.:.::::::::; ...• :=:::::::::~~:.:;::;::+-..................... ; ............................................................... [
~>;::.::.::.::.::.: ....... , .......... ::, ............. ::.,:::::,.:.:"."".: .................................................................. ; .... ::::::.:;:.;:.;.::::::::; ..... ::::::::.::::.:.:::::::::~ .................... ; .......................................................... .
4·':!~!!~~!~~~!!········;··········!::'·; .... ······· .. ~i:~:~·! .. "!.~~::' .............................................. ··············· .... ···}···,,·:::·:::··,,::···;;;;··::·c·····:::::::·:·:·:;·::· .... :l·· .... ··················}················· ............................................. i
.................... : ........................................ "'"" ..... ,, ......... . ::
~~:
...................................... ; .... :::::: .:-::. ~. ~':;.::::, ..... ;:::::,,·:::::::::,,::;:::1 ...... ·· .. ···· ................................................................. .
............................................ ~ ... ~~~.~~~!.~:~~~':'!j ...... ~~,~~.~I:~~!j ......... ··.··.··.·:::: ... :::r:.: ......... :::::.: ... ::::: .. ::::::.::::::: .... : ...... .
... ; ............................................................ .
.......................................... : .... ~~~~:~~.~.~~:~I·~~·!······~:~?~:~~~:~~~l····················· .. ~ ........................................................... .
4.}!!'!:'.'~!:'.'~~~·······!· .. ······~~!············5:~~!·~~~.~ ...................................................... ·· .. ·········i···~~·~~:~·~·~·~:!.'!":~!·····~::~~~~:~!'-~!·........... . ...... , ................................................................ ,:::
Tuesday, May 23, 2023 05:09 PM REPORT ID: 23E133 Page 319 of 345
..... :::,:.;..:::..""':7.7:..""'.::.;. ................................................................ + ... ~~~~~~:!:!!!"'.':l ..... ~~~~~~~~.~·;~':'.'~ ....................... ~
~~.~!!'!':!!~'~~ ....... L ......... ~.':'i············:~l·~~~.!.'!:~:.':'f: ................................................................... + ... ::.::.::.::;;.:.:::;;0.:; ..... =;;::=:.::.0.::.0.0:0} ........................ ; ..............•................................................ -1',
ffl:~.··;:;···,,··;;·······+·······::;·,·············::·;·~;;;;.:.:".;:'''" .. : ......................................... ·······················l····~~~·~·~!:~:!!!~:~l·····!~!::·~~·~·~~'~:~~!!1········· .... ··········;··························· .... ················ ... · .......... · .. ,·r
.... ·~v:·:·":·;·:·.:: .. :·" ........ ·· ...... · .... · ........ · ........ · ............ ·· .............. + .. :::..~.".::;;.:. !!!"'·~I .... ·~:~~~~~~~··~':'·'.1·· ............ · ...... · .. ·~ ........ · ...... · ...... · ............................. .
... :::i.::.:::::.::.:::::.:::.~::.::.::.::.: .. ;: ....................................................... i ... ::.7.:: .. :::.: ~:!!!':'.~+ ..... ~~~:~~~'~ .. ~':':'.~ ...................... ~ .................................................. ..
:7.:.~.: .•• ::.;·.: ....... :; ........ =, ............. ::-}:::::::~.;:.:.:.::: ................................................................. ·j .... ~~~·~~~~·~··~~~!l .... ·~~·,g~~'~:~~~:i ...................... ·; .... ·· .............. ·· ................ · .......................... ·t
·::.:·::·,::·-::·:·:: .... · .. , ........ ::::, .... · ...... ··::-f::::",,·,·:::·:·::' ...... · ...... ·· ................................................ · .... l .. · .. ~~~·~~{·:..·.'·'·'!!!1 .... ·:':-!::·~:~·~~;~;~!!!1 ............ · ...... · .. ~ .......... · ...... · ...... · .................................... .[
•. ~~~!!?~I~ ...... ~ ......... :.:~.~ ............ :l.f.:~~.~:::.l~' ................................................................... } ... ::.:2::::::;:::.;::::O+ .... :::::::;:;::::::·.:;:-:+ ...................... ; ............................................................. -/,
::::::·· ...... ·; .... · .... ::::::} .......... ··:::E:::~~:·."".:.7.:'·":"7::.: .......................................................... ..,. :~:,~~~~·~~:'!!!':'·~f .... ·~:~~~~~··~':'.'.~ ............ · ........ ·~
FINAL
3p 6(2-J~
Wednesday. May 24. 2023 04:55 PM REPORT ID: 23E133 Page 320 of 345
EXTRACTION LOG(S)
REPORT ID: 23E133 Page 321 of 345
EXTRACTION lOG
for
Page 92
TPH
SOP Rev. #
-c:tEMAX-3520 7
Book #: _______ ..cE::.;:Dc..;;S..c-1::.;:O..:.6 ______ _
Preparation Batch: 05£01(;' W --=-~~~-------------o EMAX-3540 4
o EMAX-3550 6
o EMAX-3580 4
Matrix: \I\la~e( "-
Micropipette ID: -=~:...;' r:....;A~f\~-....:O::...;'5~..:.(_· \~O~OQL' ~~iL!.\~) ______ _
Micropipette 10: _r_~_q_~-'G'_-...::O..:;3_--'-(_\..:..:O\):!._M!\lUj.l)-I------_
o EMAX-8015AZ 3
o EMAX-AK 102/103 5 Standards 10 Amount
Arlrlprllmll
o EMAX-AKSGC 0 Surrogate 5$.]1\-\\-06-09-(l·S
Note: For samples and relevant QCs/Standards Surrogate
extracted, refer to attached extraction sequence. LCS/MS \).~\. Ss 3 PI -1\ -(), -01 0-1
o MS/MSD can not be extracted due to insufficient amount of samples LCS/MS
Reagent Lot # /10
CH 2Cl 2 ''2.1.J1'ti.3.
Na 2S04 -SIN II? -ooq -1-3--0 c.l-
Lab Sample 10 Sonicator # Concentrator # HCI in ?-l 04. \)
9.$£011p w1J '6 Silica Sand
~ \\II. <f) Silica Gel
-'tJ( <6 Reagent Water 5W /1-\ -() \\. 24 -05
'(; VB ~ 0\ \ pH strip \\ C 1\ 0'7'30
-01 t Filter Paper I T 1"1-3 1-f:.3
-0-; \ Silica Gel Column
-()1.\ I TUNING (Note: A free flowing mixture of soil and solvent must be achieved.)
-0'; \ Sonicator # Power Output Reading Acceptance Criteria
~ OSl'll 7.. < 15 g sample: at least
.' \)'; C, -:z.. 10% power output.
-oto ~ > 15 g sample: at least
t \3\.\ -01 ~ 20% power output.
1 -O?J 1-Concentrator Water Bath Thermometer
Tpmnpr>t",p ~ptt;np.1Yl. Readine (OC\
E \\.\.£\. 01 J... 1 6S ~
-02N\ ~ 2 vS 35
-\)1~ 0 3 oS 3-S
-nil :h 4
'B. \:? 1 _ 0\ 0 5
J -D'l , ~~v,I}J~ '5 3~ $
-I I Comments:
f-
--
'-Test thermometer = SVOC-Tl -Prepared By:
r--Witnessed By:
t--Extract Received By: Extraction Location: r
Disposal Date: Disposed By: REPORT ID: 23E133 Page 322 of 345
FilelD: DSE026W
EXTRACTION LOG FOR EXTRACTABLE TPH
PrepBatchlD LabSamplelD Aliquot Unit Datelime Ve(ml) ExpAmt ExpVe(ml) PrepFctr Comments
23DSED26WOl DSE026WB 1000 ml S/22/23 12:02 10 1000 10 1
23DSE026W02 DSE026WL 1000 ml S/22/23 12:02 10 1000 10 lDSl
23DSE026W03 DSE026WC 1000 ml 5/22/23 12:02 10 1000 10 lDSL
23DSE026W04 E133-01 910 ml 5/22/23 12:02 10 1000 10 1.1
23DSE026W05 E133-02 930 ml 5/22/23 12 :02 10 1000 10 1.08
23DSE026W06 E133-03 960 ml 5/22/23 12:02 10 1000 10 1.04
23DSE026W07 E133-04 980 ml S/22/23 12:02 10 1000 10 1.02
23DSE026W08 E133-05 930 ml 5/22/23 12:02 10 1000 10 1.08 Turbid light yellow
23 DSE026W09 E133-05M 900 ml S/22/23 12:02 10 1000 10 1.11 DSL, Turbid light yellow
23DSE026Wl0 E133-0SS 890 ml 5/22/23 12:02 10 1000 10 1.12 DSL, Turbid light yellow
23DSE026Wll E133-06 980 ml 5/22/23 12:02 10 1000 10 1.02
23DSE026W12 E134-02 .910 ml 5/22/23 12:02 10 1000 10 1.1 Turbid light yellow
23 DSE026W13 E134-03 1000 ml 5/22/23 12:02 10 1000 10 1 Ughtyellow
23DSE026W14 E149-02 920 ml 5/22/23 12:02 10 1000 10 1.09
23DSE026W15 E149-02M 990 ml 5/22/23 12 :03 10 1000 10 1.01 DSL
23DSE026W16 E149-02S 990 ml 5/22/23 12:03 10 1000 10 1.01 DSl
23 DSE026W17 E149-04 880 ml 5/22/23 12 :03 10 1000 10 1.14
23DSE026W18 E152-01 900 ml 5/22/23 12:03 10 1000 10 1.11 Turbid yellow
23DSE026W19 E152-02 980 ml 5/22/23 12:03 10 1000 10 1.02 Turbid yellow
Ve=extract volume PrepFctr=(ExpAmt/Aliquot)(Ve/ExpVe)
171 Extraction Started @ 5/22/23 11:15 Prepared By: RGalan
171 Extraction Ended @ 5/23/23 5:15 Checked By: -J N
Comments: volume entered after extraction started, pH adjusted to <2 w/ conc He!. Date OS
SOP EMAX-3520 Rev. 7
REPORT ID: 23E133 Page 323 of 345
STANDARDS LOG(S)
REPORT ID: 23E133 Page 324 of 345
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STANDARDS lOG FOR EXTRACTABLE TPH
Book No: 553B-26
Parent ID Parent Standard Name Cone. Aliquot Final Cone. Standard 10 SS3B-26-40-01
<). . 9}5rr-Il'-0'2-.." oft> c4~ ~~L-ea; V>OcPlIA.1 re.O HIt.. ~ JlPrI Name {){}-(y
@ $S~fr ~ t( -a-z, -07 ·il1. 1m! ~~Cc.t-a,-r ~ 'PP"1 ")...p I1;t.-~DN Final Volume ff(/ M1.
I Yk,o(L , --Solvent ---~ Solvent ID & 2rZ-lf(!; " ----~ t {(~ ''2.;3 ; Prep. Date -----7/rlrh.') Exp. Date
.. I ~ . Prepared By ~
~ !O ("4~ Comments:
o-1lr CP l~ <0
~ (j)k-f*p.
Microsyring~ 10: ~F-01-01-S o MSF-01-01-6 o MSF-01-01-07 o MSF-01-01-OB 0 ~r;~_ 8'5[0731
D· MSF-Ol:..m;-09 o MSF-OI-03-16 o MSF-0l~03-1B 0
,
Parent ID Parent Standard.Name
; Cone. Aliquot Final Cone. Standard ID SS3B-26-40-02
.~~/o~_o7 -~"'l#O tfo fP\" all fiIP. ct/ <> DI~ 100' )"1.-!i{;t7 ,t'''f Name 'bOfN'fCl CPJ."-(
Cflt!--') ~ Final Volume to tU.. --Solvent t't <.-c.t:z. -t-L.. J.... . --; . ----Solvent ID fp'2!1A6 . &lZ6') " -------Prep. Date 111'¥1v>
~ f--' "r . .., (ft(I?~ Exp. Date ------.-
Prepared By ~) -----;~f.)dHS~ Comments:
.,;,;.-'. ~~ tlX"e -(;t~oW. ,
Mierosyringe 10: o MSF-01-01-S o MSF~01cO+-6 6sF-0l-D1-07 o MSF-01-OI-OB
o MSF-DI-OI-09 o MSF-01-03-16 o MSF-OI-03-1~ 0
Par-ent /D Parent Standard Name Cone. Aliquot Final Cone. Standard ID SS3B-26-40-03
@ J.
fj, ..... tl .... O'l -0'" -t>r t frp..( ~ 2,; GO,a>ppP1 1(0 "1L-6Co tf'C1 Name O~I-f)C,-C
'lr. ~~It-cf .. Qh -~ lJo/5 9t){vo~~ 1.fJt;o/fJCO . ~(O fIL. ~ho Final Volume 50' r1t,..
.r
ttbct'l.----Solvent
-----,-6?A~ Solvent 10 -----(; I"YI 11,.~ Prep. Date
~ -.
S( h 1'2--') Exp. Date ------Prepared By . SD ------S b -z./.., {'lfI.. Comments: I. --@ •. k~ fu,-dzl ~~.
Microsyringe II}: ~SF-O~-Ol-S ~SF-01-01--6 @ ~Pt o MSF-OI-OI-07 o MSF-01-01-OB ~}(g . ,:;...1'1-
·DMSF-Gl~Ol-09 o MSF-Ol-03-16 o MSF·OI-03-t~ Q
.-
REPORT ID: 23E133 Page 325 of 345
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STANDARDS LOG FOR EXTRACTABLE TPH
Parent ID Parent Standard'Name Cone. Aliquot Final Cone.
[;5St, A--l4 -rn ...<Jq M ..jf2" Of~' riO OCOrf'CI JrL. fPt1
~ ~S$A.";\ -010 .... 0 \ '07{o ~voq~ ~O: /lJPO.;J id) £9 ~ @
tJ , 0.\ ..er '3' tr ,
O-'f-,0 W 2P/~
\ I/,() (10 tcI>h (0
10 ~O tJOO ~Oh
'J,JJ 50 Ila;o roo~5
QO bO 'LCOO fl.OA,o
[1 J II hO Ito 'b£tt) ~4$
Microsyringe ID: crMSF-OI-0l-S G!l'MSF-01-01-6 ~SF-OI-OI-07 o MSF-OI-OI-08
O1'Vis F-OI-OI-09 q'MSF-OI-03-16 I2"MSF-Oh03-18 0
Parent ID Parent Standard Name Cone. Aliquot Final Conc.
~ >S~A--"-oS -' to ' ~::{I2--t)l~{ ~(j(;opfC1 10 J!l-bOO
~ ~~4--(( -0(, -or YiO(b S'cIW'4 Cj 1JV;1e-. ~11IJ9? Ilo /IN' ~o/vo
" " -----:--
------_____ f-""
-------; -------~o '2tlI4{'lJ) --
Microsyringe 10: o MSF-OI-0l-S o MSF-OI-Ol-6 o MSF-OI-OI-07 o MSF-OI-OI-08
o MSF-OI-OI-09 o MSF-OI-03-16 o MSF-OI-03-18 0
Parent ID Parent Standard Name Cone. Aliquot Final Cone.
~ ~S"f.l-H -04 -to Jr~ .~ '20/)0(;-~l-pf'f
@ §S$A-l' If -()b -04 ,?~(7 Mof·~o1J Goe;oo !(j) ~ I (f) (i)
0·5 O.'l to to
2.5' t 50 to
6 !L too {Oc)
2-5 lO fi;o £0(')
7~ ''bO ISO 0 (£00
J ,It II 1'5'0 fI:J $(100 1000
~I> 1..,,(/ql ~.
Microsyringe ID: ~SF-OI-01-S I:31J1sF-OI-01-6 ~SF-OI-OI-07 o MSF-OI-01-08
o MSF-OI-01-09 o MSF-OI-03-16 o MSF-OI-03-18 0
Page 42
Book No: 553B-26
Standard ID SS3B-26-42-01
Name PSt,.. 10*
Final Volume I ""U-
Solvent fta--C{<],
Solvent ID t 2-ZU ~
Prep, Date 2.. If'f (2,~
Exp, Date g-/ If Iz'1
Prepared By .81J,
Standard ID SS3B-26-42-02
Name t)~l.. '1.-6\1·
, Final Volume ( Mi.-
Solvent f'\-€YC(~
Solvent ID t ').~f4S
Prep. Date ?-I {lJ [ "1-1
Exp. Date . ~ {If 1'215
Prepared By SO
Comments:
Q Cf f . JtIp.~I~u~,
& CfJ G*p-glqf'PJ
Standard ID
Name
Final Volume
Solvent
Solvent ID
Prep. Date
Exp, Date
Prepared By <50
Comments:
REPORT ID: 23E133 Page 326 of 345
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STANDARDS LOG FOR EXTRACTABLE TPH
Parent 10 Parent Standard Name Cone. Aliquot Final Cone.
~511t-1l-ct> -0(, .JP6 ~(, ~OOOO 10 j}J ~oo "t?
S55A--tI -0 b -fr.)' . Y\.trlO' 1
,
(0 J;(., fOO, a9tr/ . 5'"''XJ !fa c<>c , ~
, ------~
----,.-
-----r-
~ .-----~ 1-;,J-~ --..
Microsyringe 10: ~5F-OI-Ol-S o MSF-OI-0l,-6 o MSF-0l-OI-07 o MSF-OI-OI-08
o MSF-OI-OI-09 o M5F-OI-03-16 o1\.4SF-Dl;P3;18 0 ,
ParentlD Parent Standard Name Cone. Aliquot Final Cone.
SS1A--If-CI:!> -ob J'P~ ·Pcwf 5'oOov {O' P'(., rirP PJof
SS$~-£1-Ou-()1, Ift;"'~CI \1otvv til f. !fa oOg to: p.C-' ~(;(;I Io,Co( . . , ;/ " '. ~" ---~
~ ~
----------..... --
-------Q) J(C((~ --,'.
Mierosyringe 10':~SF-OI-Ol-S o MSF-OI-01-6 o MSF-Oi-OH)7 o MSF-DI-DI-08
~sF~01"'"m-09 ff'MSF-OI-D3-16. D M5F-DI-03-18 0
Parent 10 Parent Standard Name Cone. Aliquot Final Cone.
9nA-""t~ -0'3>-()(, lp5 ,~ ;-0 Ooop~" to JI'~ {iCC-JP"1
~1:&-1~ -i 1-07 ., tv} 0 '. 'A1k.vo'tt-AieJ . , ".
too J f'/OO Pit 5 J.tt-. l1(Jd pptf , I -------V'
-----
-----r-'"
------------,~.J(<Pk, ---
MiCrosyringe 10: ,B"MSF-DI-Ol-S 0 MSF-OI-01-6 0 M5F-OI-OI-07 o MSF-OI-DI-08
o MSF-OI-DI-Q9~F-OI-03-16 D M5F-QI-03~18 0
Page 43
Book No: SS3B-26
Standard ID 553B-26-43-01
Name apS/fSL..Xl tc.vf
Final Volume ( I1t.-
Solvent l1v C b., .
Solvent 10 62--").-'f ~
Prep. Date l-frC(J {-;,I}
Exp, Date ~{ (t( (7--~
Prepared By ~D
com~nt~ ~ ,I
or ~ {lX-po 2;IVi
Standard ID S53B-26-43-02
Name -l{' § I~ W?> (j ''fCVz...
Final Volume t ~L:
Solvent r 6 2--1-if 3' '. , >i«j~
Solvent ID ~ he-Ct{,l. .-
Prep. Date 2.. f£rp{~
Exp. Date 'f)' ( Iq [2-') .
Prepared By Sf)
. Comments:
@~{J..
Standard'lO
:Name
,Final Volume
Solvent
Solvent ID
Prep. Date
Exp. Date
Prepared By
Comments:
(j) fk8fv[ IZkp. t-lU1
REPORT ID: 23E133 Page 327 of 345
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STANDARDS lOG FOR EXTRACTABLE TPH
Parent ID Parent Standard Name COnc.t~C1 Aliquot Final Cone.
0) '. ~"-lf -oz",.." O( IJW tCrr -(/If(j) 1.000 y'-ftPf
!i $S$A-"'u ..... o6 -05 DIW cGq-O~) 000 <» (1,) 51 (f) @ ~, .<» 5S $(} -u,-:--/..# (--OJ i> tp"1, ~~~Sj)ib --rooo 'P¢1 I :L r~ ''t--1"----7f -'
,
~ [0 6' 10 t; G
/0 2..0 10 W to (o
--.-2.0 40 ~o '2.0 1'];1) ZlJ
1t 60 fA U-'26 96
to bO '!,o ;iJ '}d >0
'/ :-_._-,,---p •• "-. i .' .-.... '40 ~" I'~cr ti° If!J 'ff)' , I
~SF-01-o1-5 -.
Mierosyringe ID: o MSF-01-o1-6 o MSF-01-o1-o7 P1<J!SF-01-o1-o8 ,
. " /-=-. o MSF-01-01-09 [J.-MS F-o 1-03-16 ur'MSF-01 ~O3-18 0
-
--Parent 10 Parent Standard Name Conc.fr;? Aliquot Final Cone,
@ .$S'J~lo -ob;"C1:U I ~fo,v~ck f)(2O' [4-VLA loco ?o f'l,; 20 {)pt1
@ ~S~I--lO-Ob~ 0(20 CCn.-~) 600 4c .JL 2C " @->5$~,-U -/ff-O'}. 6r"h.,b~ nJilv I OC/O 1n pI... 20 ~ , --------:--
~ ------------6t> 2-(I<f(1I') --,
Mierosyringe 10: o MSF-01-01-S o MSF-01-01-6 o MSF-oI-01-o7 o MSF-01~01-og
D MSF-01-oI-09 o MSF-01-03-16 o MSF-oI-03-18 0
Parent ID Parent Standard Name Cone·t9P~ Aliqu0tp.-Final ConC),joc.,
~ It ... /Or. (}If..;c,~ JPt pu1 IJ.5 /0
I
2&tYClO ,
[ ?P
. ,
2~5 flO
).~ 600
, . tio /[p()
/00 WoO
\. ... , ,) 1'50 "lQ(JQ
"J
",rl "'1-1't1""
Mierosyringe ID: ~SF-01-o1-S ~SF-01-01-6 Q-MSF-OI-o1-o7 Gt'MSF-OI-01.08
o MSF-OI-0I-09 o M5i=-Ol-03-16 o MSF-01-03-18 0
Page 45
Book No; 553B·26
, Standard iD SS3B-26-4S-01
Name c-& mAt,
Final Volume ( t'\L-
Solvent 1I\eCt'lL
Solvent ID 6 ~'-f"
Prep. Date z--{C<ffv>
Exp.Date r ( 'iii l')lj
Prepared By 56
Comments: '~Ikw fl.iSP; ~-1lill~
~. ~ ~~l!> •. 7lto/w
® (1.-)(~. . ~y~ ('Z-'1
Standard 10 5S3B-26-45-02
Name
. Final Volume
Solvent
Solvent ID
Prep. Date,
Exp. Date
Prepared By
Comments: I) q.f p:xp~. fo (l.~
t*"= Zfl M1J6S--
Standard ID SS3B'-2&-4S-03 -
Name opt r<>AL-
Final Volume t "'It--
Solvent Me.-C(7.,
Solvent ID " ~'),/f?~
Prep. Date "2--{fit (2Ij
Exp. Date ~ Illf 1<Zf5
Prepared By Sf)
Comments:
"hcc~
REPORT ID: 23E133 Page 328 of 345
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STANDARDS LOG FOR EXTRACTABLE TPH
Parent ID Parent Standard Name Conc.,~ Aliquot Final Conc.
~)'St--fo -CI}_d> Jri' ~ &"'0 or;o" 10 pA./ R:=O J>;J!L ,
~
~ ~
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o MSF-01-01-09 o MSF~01-03-16 o MSF~O! "Q3-18 0
Parent ID Parent Standard Name Conc.f'~ Aliquot Final Cone.
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Page 46
Book No: 553B-26
Standard ID 553B-26-46-01
Name ap&-~
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Prep. Date :2.1'Lf{<J.,'J i
Exp. Date t' Ib /7.,,)
Prepared By sD; .
Comments: .
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Na me
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CO mments:
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REPORT ID: 23E133 Page 329 of 345
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STANDARDS LOG FOR EXTRACTABLE TPH
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REPORT ID: 23E133 Page 330 of 345
Page 3
SfANDARDS tOG FOR EXTRACTABLE TPH
Book No: SS3A-ll
Rcvd. on Rcvd.
Exp. Date Comments Standard ID Name Source Lot # Location
By "
"
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REPORT ID: 23E133 Page 331 of 345
STANDARDS LOG FOR EXTRACTABLE TPH
StandardlD Name Source Lot # Location I Rcvd. on
Rcvd.
By
SS3A-11-04-01
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;"'" REPORT ID: 23E133 Page 332 of 345
Page 5
STANDARDS LOG FOR EXTRACTABLE TPH
Book No: SS3A-ll -_ ... _-----
Standard ID Name Source Lot # Location Rcvd. on
Rcvd.
By
Exp. Date Comments
(he. 'LSO .... /.)
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REPORT ID: 23E133 Page 333 of 345
Page 6
STANDARDS LOG FOR EXTRACTABLE TPH
Book No: SS3A-ll
Rcvd. Standard ID Name . Soyrce lot # Location Rcvd. on Exp. Date Comments ... ', ....... ' ii" ..... . . . By
G . --.~~-
553'-11-06-01 M.e,+-t.o1 !l'O1~ 51! ..,,~<-cpr 4-f<5 :zs 'i s: Ao1 H /'./111-81' fAu~ ~ ~ ~ 3f;~ It, 72t.
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REPORT ID: 23E133 Page 334 of 345
Page 3 Ei('
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Book No: SS3A-ll
Location Rcvd. on Rcvd.
Exp. Date Comments
I4-sf .l2k mq 8'''?, 1 Sti-~ 11011::>-('2..-( I &' p I fO/5/ k 5 ('),-,?Lf } r-f L.>(JO
~kk Aol '77bf1Lj-S,4l73> (&/2fllkJ IS}) 15 S2-5"'7 b (V'lL k
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(~i >r'1
REPORT ID: 23E133 Page 335 of 345
i
i
STANDArR,DS LbG:.F,QIR .• EXTRACTABLE TPH
j
Standard 10 Name Lot # Location I RcvQ;on
ss3A-ll,04-01 I 8'0'/'{'
''':'':'>';'''\'.' '\:.\.\\', ,; ....
ss3A-ll-04-02 1 Cv:J(;,yvl j~O rak ~ t !to l ~4-Lf-'11 f,4G>3 I~l (, ltf.
ss3A-ll-04-03 0;, ~ '. '5 ""~ O~{or"" 0 '( 1
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ss3A-ll-04-04 CJP-<ir G~j~ f~~ I Z'f I $(wJ 14{1{~ I( IJ
SS3A-ll-04"05 ~p-r s~J~j ~k{ ,q.0I~1.t¥1 ~~ 1~(''fIn.I~p
Ss3A-ll-04-06 ~o\5 Wo('k~"9 ~~(f"09CA+e 4iS 9t;4
SS3A-ll-04-07 1 ~ 2 t>iese\ (:'",e\ 41Sl q'i I SAo,
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.... ~ .. ' \
...... .\ .... _:',-..: .. ':.,\\\ ... : ",." ... \";"\ ',' '\','.: :\'.\ ...• " "'X·,;·,,\'.;· ,"," ,.'8'.\\',', \ .... -:,:' ','.\\'-:,\" .. \\'.' ......... \':.~'; .. .'.\\'. .'.,\\'. '.\\\ :.\ "'\\\\": .. ','.:. \ ........... -" ..
REPORT ID: 23E133 Page 336 of 345
~5''3 It--{ {-~'-O~~ •.. /.~,. .. ·····S·~·····K·· , :., . ' .. ' ..
,," :"':. :c ... ,' ': .".. ''' .. "
0",' '~. . .
110 Benner Circle
Bellefont~. PA 16823-8812
Tel~ ~0)356-1688
Fax: [phone]
www~reste~com
Catalog No. : 31259
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
FOR-LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Matenal is intended for Laboratory Use Only as a standard for
the.qualiUJtive an!!llorquantitativedetermination of the analyte(s) listed.
Lot No.: A0173887
Description : Diesel Fuel #2 Composite. Standard
Diesel Fuel #2 Composite Standard 50;OOOlJ9/mL. Methylene Chloride,
5mUamplii
Container Size: 5 mL ~~-------------------------Pkg Amt: > 5 mL
---------------------------------Expiration Date: July 31: 2028 Storage: 25°C nominal
------------~--------------------Ship: Ambient
. '::., }':., .. ' :; ~:-~, ." ~ ..... ,., .... "'. , .,
CERTIFIED
11""':"',"1 "." :;' 1
.. ' -":<-~: "" ." '.'~ .~
Ace:·· .'. E
~,~-~ ........--... ~~
CO' t i , "', " r' I' r="n~n.Jer l'ne ~a'~1y -J-IU lOn: ~ -Cornpound ,u,a" ~onc. ' bJ"r-'C<' L' ,",,' el~ li'_
a d I I /' I -"," •. I (9 ~O! ~. V? I r 91" j I \W81gntivc ume, j ..; Ie ~,_.; r\.=~
1 Diesel.Fuel·1I2CotttPoshe
CAS.# 68334,.3Q,;S.A
Purity -,-%
Solvent: Methylene chloride
CAS # 75-09--2
Purity 99%
(LotAOl60886)
, -
+1-. 290:6918> .. ,ig,mt
+/-1,488.6711 J.lglmL
+/-1,587.7189 J.lglmL
;GI;iviitie,iric .
UIl!l~ ..
Stressed
101
REPORT ID: 23E133 Page 337 of 345
l>atemanufactured: 7/1512022
"issue date: 111512022
Lot No.:
485259
Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
SS~A--(/-0' -0 1
11 A 6/'" 't J)
Certificate of Anal . sis Date Received: _ ............................... -..;..
Page 1 of 2 Rev 0
Solvent:
AcetonelMeC12 1: 1
Expiration,
Date:
4-Aug-2023
Description:
Method 8015 Working Surrogate, 2-1, ?OO &' 2,000
mg/L,.2 x 250 mI
Certified Values:
The certified value is based on gravimetnc'aridv()iumetric preparation of this CRM. This CRM has been
confrrmed by gas chromatography (GC}o~gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
. . ,
Compound '. ·CAS~_k._.!~rity (~) Neat Materia;lLot No. ConeentratiOi1~ ..... c:· '. '. :"'. :;""'cPi"7ff:
bronio~ne 147.7.21> 200'l·:I:"i_."r!{4;~~
-: .;···-::,: .. ·,;;.:,y:P\;/-·
hexacosane (C26) 422.7.np
"Not acOotilied v.ifue:":
Letthc standard warm to rooni tempenrture and sonicatebefOre-openmg;"
luten,ded Uses:
This Ce~fiedReferencemateria1(c::::RM) is intended for use as a calibtation standard or a qwitity control staridard for
Chrom1ltography Equipmentsuch asGC;GCIMS, HPLC, andHPLCIMS .. ]tmily aslobe'used for various USEPA, mOSH,
and ASTM methodS.This Certified Refetence materi~ (C~iS intended fot use as a ca1ihm,tion standard or a quality
con.trolstaiidard: for Clftomat0!WiPhy E<plipment sUch as GC, GCJMS, iEJllLC, andBPLC/MS. It tmiyalso be used for
variouS EN, ISO, EPA, andASTM methods. .
Recommended stora.g~COtltajn"et:fura.DlPlJledprod1lCts after opet:lijlgiS al2.~2tmn ~per vial with SCrew cap Teflon
lined silicon septWit~Tb:¢tD9d~led %diangeper day can be ctllcula:ted usjrigtheM16wing: . .
% Change = (,,0.0181n(x+3l) + O.1157) + 63<?54y·3202
where x=boilingpoint of the most volatileanaiyte in the miX (degrees K)
y= boitin$point of the SQlvellt(degreesK)
1Jlls mpqel asswnes the cQ!1~r is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the liUIXimum number of days the opened ampule should be stored.
·l\tetli'Od 9f prepn.p(i#oll::·
REPORT ID: 23E133 Page 338 of 345
CPI
Date manufactured: 10/512022
Original issue date: 10/512022
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
~ertificat~of Analysis,
to, 0".1",'1..,<-, Date Receiv.ed: fl.
Page 10f 2 Rev. 0
Catalog No.: Lot No.: Storage: Solvent: Expiration Description:
Date:
Z-G34 490018 -18°C +/-4°C Acetone 25-0ct-2023 Diesel Fuel Solution in Acetone, 50,000 mg/L, 4 x 2:
mL -OI0438-S6
-100
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by 'gas chromatography, (GC) or gas chromatograph/mass spectrometry (Ge/MS) using an
internally develop-e(tmeibmlaga.inslan in@P~I!gtm,t, sow~~·Th~_ @certai!t:ty y~:t!e is~~~:t!~_~~dfO~_~~?_%
confidence interval with a k value of 2.
CompoUnd
#2 diesel fuel
CAS N PU' n'ty (°/,0) • , o. ,. Ntm.t Material Lot No. ConcentratiOlJ, mt!ll
50030 ±2600 68416-~4-6 100 438.109;IP
~~tAt7~
Intended Uses:, .£'1)
This Certified, R.efetencemateriaI (CRM) is intended for use as a calibration standard or a quality contr~lstaildar4filr
ChrO~tograpby EqWpmentmCll asGC, OCIMS, HPLC, and HPLCIMS. It may asio be~for varW9S USEP:A,NlOSH,
andASTM methods;This,Certifi@~~ference material (CRM) isin~nded for use aSacalibration standard or aquatity ,
cobtrol stalidardfor ChiO$lt.q~y Equipment such as GC, GCIMS,HPLC,and HPLCIMS., It may alS() be'Used for
various EN, ISO, EPA; and ASTM inethods.
R~nunende4stoiage contab;i:er forampu1ed products after opening is a 12mmx32mm aJilber vial with screw.cap Teflon
Imedsilicon septum. Themodele<i ~change per day can be caIculatedusing the folloWing: ' '
%C~ge= (-O.018ln(x+31) + 0.1157) + 636,54y·3.202
Where x = bOiling point of the most volatile analytein the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assUmes the container is stored at -10 DC and is unopened during storage. The user should determine wQat the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stor.oo..
Metb-od of Preparation:
All weightsaretrlleeabletbrough N. 1. S. T. Test No. 8221264157-00. Concentration {cl;)rrectfor purity) anc:l uncertainty
REPORT ID: 23E133 Page 339 of 345
125 Market Street
New Haven. CT 06513
USA ~AccuStandard® Tel [phone]
Fax [phone]
www.AccuStandard.com
CERTIFICATE OF ANALYSIS
Catalog No: FU-012-40X
Description:' JP-5 Fuel
Lot: 217071354
Solvent: Methanol
Hazards: Refer to SDS for complete safetyinformation
Signal Word: Danger
Component
JP-5 Fuel
S S sA -II -Olf .... lO
reveL Of)
5lzil z 't.
C 1'\ {) I 'V'/\
CAS #
N/A
Date Certified: Jul 24. 2017
ExpiratiOn: Jul 24. 2027
Sample Size: 1 mL
Components: 1
Storage Condition: Ambient (>5 ·G)
Certified Reference Material
Purity %
This ·Certlfied Reference Material was
A product with a suffIX (-1A. -2B. has had lis expiration dsteextended and is identical to the same lot number without the suffix.
Page 1 of 1 -Rev, 2
ot""tioln.r<"",rte<jo"th,ls certjfi¢atf!! is ±2.4%. this value is the combined expanded uncertainty and represents an
"~'U"''',''N'V' t/)e total variation of the uncertaintyofcomponents. Anormal distribution is assumed and a coverage
in reportlngnumericalvalues: Acomma(.)Is used to separate unllsofone-thousand or greater. A period(.) Is used as
may not be reproduced without the express pennlssion of the manufacturer. 8ee reverse side for additional Information
to the 80S for information regarding the haZards associated with using this material.
according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
LarryOacker. OJ:ganlc OC Manager
For use in routine laboratory analjlsis,
AccuStandard is accredited to ISO 17034,ISOIIEC 17025 and' certifiedfo 1$0 9001 :2015 QR<lR<>I1NO-OO1; ,
ReV,712O REPORT ID: 23E133 Page 340 of 345
CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte. 'A 16~~:.~ __ _
Tel: [phone]
FIDc 1-814-353-1309
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for La/)Oratofy Use Only as a standard for
the qualitative and/or quantitative determination of the analyte{s) listed.
Catalog No. : 56192 Lot No.: A0193142
Description: Custom 5W30 Motor Oil Standard
Custom 5W30 Motor Oil Spmdard 5O,OOO~g/mL, Methylene Chloride,
1mUampul
Containu~ize : .=2:....:.m:....:.L=--___ ~----
expiration Date: January 31,2026
01-Nov..z022 rev.
Methylene chl9ilde
cAS'j· ·75~i
P.urity 99"/0
D.ate.Mh:ed: 03-Jim-2023
Pkg Arnt: > 1 mL
----~------~----
Storage: 1 aoc or colder
Ship: Ambi~nt
Balance: B442140311
... c:E<R TI.FI E D V.A LU E.~
Mamifac:lufedunder Restek'siSO 9001:2015
RegiStimldQiI"Ity.~
Certifi~~80397
REPORT ID: 23E133 Page 341 of 345
CERTIFIED REFERENCE MATERIAL
110 Benaer Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
. Certificate of Analysis
gravimetric
FOR LABORATORY USE ONLY~READ SDS PRIOR TO USE.
This Re{f3rence Material is intended for Laboratory Use Only as a standard for
the qualitative andlorquantitative detel7J1ination of theanalyte(s) listed.
Catalog No. : 56192 Lot No.: A0193186
. DeSCription : Custom 5W30 Motor Oil Standard . .
Custom 5W30 Motor Oil Standard 5O,OOOpg/mL, Methylene Chlonde,
1mUampui
Container Size: 2 mL ~~----------------Pkg Amt: > 1 mL -----------------
Expiration Date: January 31, 2026 Storage: 10°C or colder
Ship: Ambient,
SQIYAnt: .M~jbyl~ec;hl9rtc:le
CAS # 75...69-2'
Purity 99%
551.k-({-Oh -OS
~.~
Soom MOOdhOi' .. ~ Tiidi I DateMiIed: 04-Jan-2023 BaJaace: 8345965662
01-Nnv-2022 rev,
CERTIFIEr) .VALUI;S
Maniifactured un_ Restek'S iS09001:2015
Registered Qual!ly.Sj$tem
ceitificate#F~,H,~i
REPORT ID: 23E133 Page 342 of 345
~1-,4-rJ-C() -06
~tlSlrlC ~CERTIFIED REFERENCE rATERIAL
11QBenner Circle
Bellefonte; PA16823~812
Tel: (800)356~1688
Fax: [phone]
Catalog No. : 31252
DescriptiOn : JP-5 Standard .
:>
-;..
Certificate of Analysis
FOR LABORATORVUSE ONLY-READ SI)~ PRIOR TO USL
This Refe~rit:e Materia/is intencJedfor Laboratory. U~e Only as a standafd for
the' qualitative ariiflorquantita#iVe deteimin!,tion of th~ analyte(s) listed.
Lot No.: A0180S45
JP-5 Std 50,OOOj./glmL, Methylene Chloride. 1mLlampui
Container Size: 2 mL ~~-------------------------Expiration Date: February 28, 2029
PkgAmt; > 1 ml --------------~--------Storage: 25~C nominal •• ··
Ship: AmbiEmt
Elution , Compound i Grav, Cone, I Expal'ded Uncertainty
Order ! I . (weight 'fo:ume) i (95% C,L.' K=2)
.1 '" ',.nr;S?'
CAS #
Purit:Y
. -".~ .
8008-20-6,0
-.-%
Solvent: .. Methylene.chloride
CAS # 75~2
Purity 99"/0
. .
(LotU~193-2)
:+1-.' " 46'3~561i:,
+1-1;535A832
+1-1,632.1837
(C:4L k 1
I1gliriL
l1g1mL
l1g1mL
'~e'
Unstressed
StressCd
'not A •• n.-?n?ll rD.n 1 ,.
REPORT ID: 23E133 Page 343 of 345
I
\;
CERTIFIED REFERENCE MATERIAL
Gravimetric Certificate
FOR LABORATORY USE ONJ..Y-READ SDSPRIOR TO U~E.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte{s) listed.
Ca~log No. :j.:5~52::.;5=7~6,--____ _ Lot No.: A0177692
Description: f: Custom 10W30 Motor Oil Standard
">
.~. Custom 10W30 Motor Oil Standard 50,OOOJ,JglmL. Methylene Chloride.
· ... 1mUampul
Container SiZe: :02 mL
Expiration Date :'>;;;;;;0ct0~;;;"be-r""'3-1,-2-0-2-4----Pkg Amt: > 1 mL ...,..---------Storage: 10°C or colder
Ship: Ambient
CERTIFIED
'~mponent I Compound i Grav. Cone. , Exnanded Uncertainty
"'. "~-~
',;; . '''"::~ '" .. ";. ,-
:# ! I weight volume) ~:,)!o ,-,,~.: l\.=L ~ -I ' (! f (--0 r" v-)
(Lot M09402)
Solvent: :M~ybe chloride
'50,105;OIlg/niL . +1-. 463257510 . fig/1ttL .
+1-1,534.65619t Ilghm.
+1-. 1,631.304613 1lg/mL St¢Ssed
:.. ..
>:
CAS'#.' 75-09-2
••••••• _ •• _. ___ • ____ .. _____ ~ .. ~. ~. ~: •• ___ • ______________________________________________ ••• ___ • ____ ," ••• _ •••• _______ • __ •• • •• _ •••• ___ n •• _____ ' •• ___ • _________ •• ___ _
Purityj 99% ------;;:J:-~-=]---·-·-,;Jf$~-~1;;1--
RiiSIs~-~.Tedmk:lait1
;:
Date Mixed: 21-Oct-2021 Balance: 1128342314
~17
1 I
REPORT ID: 23E133 Page 344 of 345
125 Market Street
New Haven, CT 06513
USA'
'. : ~'.;,' ,
Component
SAE 10W30 Motor Oil
. ~'3A--lo-04-O 1
. AccuStandarde
Tel [phone]
Fax (203)78&-5287
www.AccuStendard.com
TE OF ANALYSIS '. . §
CAS #
N/A
Date Certified: Oct',18, 2017
E)(piratioil: Oct::'! 8,2027
Sample$ize: 1 mt
CQmp·orients·: 1 ~.:~
StorageCohdrtion:Arn~iehH>5 °e)
.::.:
>:
Certified Referen~eMaterial
---AR-1463
Purity %
Tech Mix
.,....~ ..
AT-1339 .
..., /u {'Z( 1~;'>Lf f'
71'Vt{u' {~'1({f'C1.
. -
. lot number has had its ~xpiralion dete extended and is identical toth~same.lot numberwithout'the suffix.
this certifICate is ±2.4%: This value is the combined expai!ded uncertainty and represents im
$~~=~~~' total variation of iIIe uncertainty of componenls, A normal di~tri6ution islissumeci and a coverage Ii .~~ . -
CQlwentiilins·,in-n9po.itin:l! numerical values: A comma (.) is used to separate units of one-thou~nd or greater. A perkid (.) is used as
berepi'oduced.~ithout the express permission of the manufacturer. See reverse side ~r additional informatiOn
?
Certified 8y:
Larry Decker. ~ic QC Mari&ger
';:.
Fofiuse in routine laboratory analysis.
"".
'A'C~,~SutndatdisaCC"'it(dto ISP 17034, ISOIll;C 1702$ and certified to IS9 9001:201~ 1lR,()RGII~I ..
Rev. Slts:-REPORT ID: 23E133 Page 345 of 345

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