Loading...
HomeMy WebLinkAboutDAQ-2024-0073991 DAQC-333-24 Site ID 10917 (B4) MEMORANDUM TO: STACK TEST FILE – COMPASS MINERALS INTERNATIONAL – Ogden Production Plant THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Paul Morris, Environmental Scientist DATE: April 12, 2024 SUBJECT: Source: AH-513 Contact: Holly Hurst: 801-732-3251 Location: 765 North 10500 West, Ogden, Weber County, Utah FRS ID#: UT0000004905700001 Test Contractor: Alliance Technical Group, LLC. Permit/AO#: Title V permit 5700001004, dated June 10, 2021, Date of Last Revision: December 15, 2023 Action Code: 3A Subject: Review of Stack Test Report dated April 11, 2024 On April 11, 2024, Utah Division of Air Quality (DAQ) received a test report (email copy) for retesting of the above listed unit following a test failure on October 11, 2023. Testing was performed February 15 and 16, 2024, to demonstrate compliance with the emission limits found in Title V permit condition II.B.5.b. The calculated test results are: Source Test Date Test Method Pollutant DAQ Result Result Limit AH-513 2/15-16/2024 5/202 PM 2.5 0.0014 gr/dscf 0.0015 gr/dscf 0.0114 gr/dscf 0.23 lb/hr 0.23 lb/hr 1.49 lb/hr PM 10 0.54 lb/hr 0.55 lb/hr 1.49 lb/hr Particle sizing was conducted using electron microscopy to determine PM10 and PM2.5 DEVIATIONS: No deviations were reported during this testing. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: Send a settlement agreement to resolve the stack test failure on October 11, 2023. ATTACHMENTS: DAQ stack test review excel spreadsheets, Compass Minerals stack test report. 6 , 3 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Compass Minerals - AH-513 Company Contact:Holly Hurst Contact Phone No.(801) 732-3251 Source Designation:AH-513 Test & Review Dates Test Date: 2/15-16/2024 Review Date: 4/11/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf 1.490 0.011 Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.0602 0.0004 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 51.00 14.19 0.9950 1.853 0.84 25.59 -0.32 0.28 Contractor Information Contracting Company: Alliance Technical Group Contact: Charles Horton Phone No.: 464-352-7568 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Compass Minerals - AH-513 Testing Results Lab Data - grams collected Test Date 2/15-16/2024 2/15-16/2024 2/15-16/2024 2/15-16/2024 Lab Data Probe Filter Back Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.0053 0.0625 0.0028 1.6% As ft^2 14.19 14.19 14.19 Run 2 0.0031 0.0256 0.0021 2.3% Pbar 25.59 25.59 25.59 Run 3 0.0036 0.0258 0.0022 2.6% Pq (static)-0.32 -0.32 -0.32 Run 4 Ps 25.57 25.57 25.57 Avg. Ts F 122.79 116.83 114.21 Front Half Emissions Summary CO2 - FCO2 3.00 3.00 3.00 Run 1 Run 2 Run 3 Run 4 Avg. O2 16.00 16.00 16.00 gr./dscf 0.0005 0.0003 0.0003 0.00038 N2+C 81.00 81.00 81.00 lbs/hr 0.0770 0.0484 0.0553 0.0602 Md 29.12 29.12 29.12 lbs/MMBtu Ms 27.50 27.95 27.86 Y 1.00 1.00 1.00 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 38.12 38.60 39.10 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 124.50 84.70 94.00 gr./dscf 0.0018 0.0013 0.0013 0.0014 AVG. Tm F 46.79 54.42 47.08 lbs/hr 0.2758 0.2026 0.2144 0.2309 Vm std 33.90 33.82 34.76 lbs/MMBtu Vw std 5.86 3.99 4.42 Bws 0.15 0.11 0.11 S Bws 0.15 0.12 0.11 Avg. Sqrt Dlp 0.49 0.49 0.50 Vs 32.32 31.50 32.03 F factor used scfm wet 21297.52 20972.34 21421.02 acfm 27510.48 26813.47 27262.49 Qsd dscfh 1091343.01 1125637.96 1140135.31 # Sample Points 24.00 24.00 24.00 Dn 0.280 0.280 0.280 An 4.28E-04 4.28E-04 4.28E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 60.00 60.00 60.00 Time @ point 2.50 2.50 2.50 PM 2.5 fraction 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Compass Minerals - AH-513 Flow & Moisture Test Date 2/15-16/2024 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 14.19 25.59 -0.32 25.57 123 3.00 16.00 81.00 29.12 27.50 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.1460 0.9950 0.84 38.120 124.50 46.79 33.900 5.860 0.1474 0.1460 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.494 32.32 21,298 27,510 1.09E+06 24 0.28 60 2.50 1.192500 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 800.976 0.44 2.00 123 50 Wt. (Final) Wt. (Initial) lc 2 803.020 0.45 2.10 123 48 574.60 483.00 91.6 3 805.130 0.46 2.10 123 47 649.70 637.20 12.5 4 807.250 0.48 2.20 123 48 578.50 573.90 4.6 5 809.430 0.44 2.00 124 47 738.20 733.40 4.8 6 811.530 0.42 2.00 123 46 995.1 984.1 11.0 7 813.570 0.32 1.60 124 47 8 815.510 0.24 1.10 123 47 Isokinetics 103.3 9 817.130 0.18 0.84 123 48 Test Date 2/15-16/2024 10 818.490 0.17 0.79 123 49 Start Time enter 11 819.850 0.17 0.79 123 48 End Time 12 821.210 0.17 0.79 123 48 Run 1 13 822.535 0.18 0.84 123 47 14 823.880 0.20 0.93 123 47 15 825.330 0.22 1.02 123 46 16 826.810 0.24 1.11 122 46 17 828.430 0.26 1.21 122 46 18 829.960 0.22 1.02 121 46 19 831.440 0.18 0.84 122 46 20 832.800 0.15 0.70 122 46 21 834.390 0.15 0.70 122 45 22 835.390 0.15 0.69 123 45 23 836.690 0.14 0.65 123 45 24 837.930 0.13 0.60 123 45 25 839.096 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Compass Minerals - AH-513 Flow & Moisture Test Date 2/15-16/2024 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 14.19 25.59 -0.32 25.57 117 3.00 16.00 81.00 29.12 27.95 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.1237 0.9950 0.84 38.600 84.70 54 33.818 3.987 0.1055 0.1237 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.488 31.50 20,972 26,813 1.13E+06 24 0.28 60 2.50 1.19 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 839.466 0.44 2.10 116.0 58.0 Wt. (Final) Wt. (Initial) lc 2 841.580 0.45 2.10 116.0 57.0 575.40 499.20 76.2 3 843.740 0.47 2.20 117.0 59.0 637.00 634.10 2.9 4 845.930 0.46 2.20 118.0 59.0 643.60 643.40 0.2 5 848.110 0.46 2.20 119.0 60.0 736.90 742.90 -6.0 6 850.270 0.42 2.00 119.0 60.0 985.6 974.2 11.4 7 852.360 0.25 1.20 118.0 61.0 8 853.990 0.21 0.99 118.0 61.0 Isokinetics 99.7 9 855.490 0.18 0.85 118.0 58.0 Test Date 2/15-16/2024 10 856.890 0.17 0.80 117.0 58.0 Start Time 11 858.270 0.18 0.85 117.0 57.0 End Time 12 859.690 0.16 0.76 117.0 56.0 Run 2 13 861.020 0.13 0.62 114.0 55.0 14 862.230 0.13 0.62 114.0 52.0 15 863.460 0.13 0.62 114.0 52.0 16 864.690 0.14 0.67 115.0 51.0 17 865.950 0.14 0.66 116.0 51.0 18 867.210 0.16 0.76 116.0 50.0 19 868.580 0.18 0.85 117.0 50.0 20 870.010 0.32 1.50 117.0 49.0 21 871.880 0.23 1.10 117.0 49.0 22 873.450 0.22 1.00 118.0 48.0 23 875.030 0.21 0.99 118.0 48.0 24 876.550 0.20 0.95 118.0 47.0 25 878.066 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Compass Minerals - AH-513 Flow & Moisture Test Date 2/15-16/2024 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 14.19 25.59 -0.32 25.57 114 3.00 16.00 81.00 29.12 27.86 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.1149 0.9950 0.84 39.101 94.00 47 34.760 4.425 0.1129 0.1149 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.497 32.03 21,421 27,262 1.14E+06 24 0.28 60 2.50 1.27 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 616.414 0.47 2.20 115.0 44.0 Wt. (Final) Wt. (Initial) lc 2 618.670 0.46 2.20 113.0 45.0 555.9 483.7 72.2 3 620.930 0.50 2.40 114.0 45.0 642.9 639.2 3.7 4 623.420 0.49 2.40 114.0 45.0 575.3 576.3 -1.0 5 625.490 0.48 2.30 113.0 46.0 740.5 736.8 3.7 6 627.720 0.42 2.00 114.0 46.0 991.1 975.7 15.4 7 629.795 0.26 1.30 115.0 46.0 8 631.530 0.21 1.00 115.0 47.0 Isokinetics 101.2 9 633.030 0.20 0.97 115.0 47.0 Test Date 2/15-16/2024 10 634.520 0.19 0.92 114.0 47.0 Start Time 11 635.925 0.18 0.88 115.0 48.0 End Time 12 637.330 0.17 0.83 114.0 48.0 Run 3 13 638.662 0.13 0.64 114.0 45.0 14 639.845 0.12 0.59 115.0 46.0 15 640.965 0.13 0.64 115.0 46.0 16 642.145 0.14 0.69 114.0 46.0 17 643.350 0.14 0.69 115.0 47.0 18 644.570 0.16 0.79 113.0 48.0 19 645.920 0.30 1.50 114.0 48.0 20 647.680 0.28 1.40 114.0 48.0 21 649.465 0.24 1.20 115.0 50.0 22 651.075 0.22 1.10 114.0 50.0 23 652.630 0.19 0.93 114.0 51.0 24 654.100 0.19 0.93 113.0 51.0 25 655.515 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Compass Minerals - AH-513 Company Contact:Holly Hurst Contact Phone No.(801) 732-3251 Source Designation:AH-513 Test & Review Dates Test Date: 2/15-16/2024 Review Date: 4/12/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf 1.490 0.011 Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.3726 0.0023 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 51.00 14.19 0.9950 1.853 0.84 25.59 -0.32 0.28 Contractor Information Contracting Company: Alliance Technical Group Contact: Charles Horton Phone No.: 464-352-7568 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Compass Minerals - AH-513 Testing Results Lab Data - grams collected Test Date 2/15-16/2024 2/15-16/2024 2/15-16/2024 2/15-16/2024 Lab Data Probe Filter Back Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.0053 0.0625 0.0028 11.8% As ft^2 14.19 14.19 14.19 Run 2 0.0031 0.0256 0.0021 15.0% Pbar 25.59 25.59 25.59 Run 3 0.0036 0.0258 0.0022 11.0% Pq (static)-0.32 -0.32 -0.32 Run 4 Ps 25.57 25.57 25.57 Avg. Ts F 122.79 116.83 114.21 Front Half Emissions Summary CO2 - FCO2 3.00 3.00 3.00 Run 1 Run 2 Run 3 Run 4 Avg. O2 16.00 16.00 16.00 gr./dscf 0.0036 0.0020 0.0014 0.00235 N2+C 81.00 81.00 81.00 lbs/hr 0.5679 0.3160 0.2339 0.3726 Md 29.12 29.12 29.12 lbs/MMBtu Ms 27.50 27.95 27.86 Y 1.00 1.00 1.00 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 38.12 38.60 39.10 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 124.50 84.70 94.00 gr./dscf 0.0049 0.0029 0.0024 0.0034 AVG. Tm F 46.79 54.42 47.08 lbs/hr 0.7667 0.4701 0.3930 0.5433 Vm std 33.90 33.82 34.76 lbs/MMBtu Vw std 5.86 3.99 4.42 Bws 0.15 0.11 0.11 S Bws 0.15 0.12 0.11 Avg. Sqrt Dlp 0.49 0.49 0.50 Vs 32.32 31.50 32.03 F factor used scfm wet 21297.52 20972.34 21421.02 acfm 27510.48 26813.47 27262.49 Qsd dscfh 1091343.01 1125637.96 1140135.31 # Sample Points 24.00 24.00 24.00 Dn 0.280 0.280 0.280 An 4.28E-04 4.28E-04 4.28E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 60.00 60.00 60.00 Time @ point 2.50 2.50 2.50 PM 2.5 fraction 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Compass Minerals - AH-513 Flow & Moisture Test Date 2/15-16/2024 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 14.19 25.59 -0.32 25.57 123 3.00 16.00 81.00 29.12 27.50 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.1460 0.9950 0.84 38.120 124.50 46.79 33.900 5.860 0.1474 0.1460 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.494 32.32 21,298 27,510 1.09E+06 24 0.28 60 2.50 1.192500 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 800.976 0.44 2.00 123 50 Wt. (Final) Wt. (Initial) lc 2 803.020 0.45 2.10 123 48 574.60 483.00 91.6 3 805.130 0.46 2.10 123 47 649.70 637.20 12.5 4 807.250 0.48 2.20 123 48 578.50 573.90 4.6 5 809.430 0.44 2.00 124 47 738.20 733.40 4.8 6 811.530 0.42 2.00 123 46 995.1 984.1 11.0 7 813.570 0.32 1.60 124 47 8 815.510 0.24 1.10 123 47 Isokinetics 103.3 9 817.130 0.18 0.84 123 48 Test Date 2/15-16/2024 10 818.490 0.17 0.79 123 49 Start Time enter 11 819.850 0.17 0.79 123 48 End Time 12 821.210 0.17 0.79 123 48 Run 1 13 822.535 0.18 0.84 123 47 14 823.880 0.20 0.93 123 47 15 825.330 0.22 1.02 123 46 16 826.810 0.24 1.11 122 46 17 828.430 0.26 1.21 122 46 18 829.960 0.22 1.02 121 46 19 831.440 0.18 0.84 122 46 20 832.800 0.15 0.70 122 46 21 834.390 0.15 0.70 122 45 22 835.390 0.15 0.69 123 45 23 836.690 0.14 0.65 123 45 24 837.930 0.13 0.60 123 45 25 839.096 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Compass Minerals - AH-513 Flow & Moisture Test Date 2/15-16/2024 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 14.19 25.59 -0.32 25.57 117 3.00 16.00 81.00 29.12 27.95 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.1237 0.9950 0.84 38.600 84.70 54 33.818 3.987 0.1055 0.1237 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.488 31.50 20,972 26,813 1.13E+06 24 0.28 60 2.50 1.19 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 839.466 0.44 2.10 116.0 58.0 Wt. (Final) Wt. (Initial) lc 2 841.580 0.45 2.10 116.0 57.0 575.40 499.20 76.2 3 843.740 0.47 2.20 117.0 59.0 637.00 634.10 2.9 4 845.930 0.46 2.20 118.0 59.0 643.60 643.40 0.2 5 848.110 0.46 2.20 119.0 60.0 736.90 742.90 -6.0 6 850.270 0.42 2.00 119.0 60.0 985.6 974.2 11.4 7 852.360 0.25 1.20 118.0 61.0 8 853.990 0.21 0.99 118.0 61.0 Isokinetics 99.7 9 855.490 0.18 0.85 118.0 58.0 Test Date 2/15-16/2024 10 856.890 0.17 0.80 117.0 58.0 Start Time 11 858.270 0.18 0.85 117.0 57.0 End Time 12 859.690 0.16 0.76 117.0 56.0 Run 2 13 861.020 0.13 0.62 114.0 55.0 14 862.230 0.13 0.62 114.0 52.0 15 863.460 0.13 0.62 114.0 52.0 16 864.690 0.14 0.67 115.0 51.0 17 865.950 0.14 0.66 116.0 51.0 18 867.210 0.16 0.76 116.0 50.0 19 868.580 0.18 0.85 117.0 50.0 20 870.010 0.32 1.50 117.0 49.0 21 871.880 0.23 1.10 117.0 49.0 22 873.450 0.22 1.00 118.0 48.0 23 875.030 0.21 0.99 118.0 48.0 24 876.550 0.20 0.95 118.0 47.0 25 878.066 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Compass Minerals - AH-513 Flow & Moisture Test Date 2/15-16/2024 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 14.19 25.59 -0.32 25.57 114 3.00 16.00 81.00 29.12 27.86 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.1149 0.9950 0.84 39.101 94.00 47 34.760 4.425 0.1129 0.1149 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.497 32.03 21,421 27,262 1.14E+06 24 0.28 60 2.50 1.27 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 616.414 0.47 2.20 115.0 44.0 Wt. (Final) Wt. (Initial) lc 2 618.670 0.46 2.20 113.0 45.0 555.9 483.7 72.2 3 620.930 0.50 2.40 114.0 45.0 642.9 639.2 3.7 4 623.420 0.49 2.40 114.0 45.0 575.3 576.3 -1.0 5 625.490 0.48 2.30 113.0 46.0 740.5 736.8 3.7 6 627.720 0.42 2.00 114.0 46.0 991.1 975.7 15.4 7 629.795 0.26 1.30 115.0 46.0 8 631.530 0.21 1.00 115.0 47.0 Isokinetics 101.2 9 633.030 0.20 0.97 115.0 47.0 Test Date 2/15-16/2024 10 634.520 0.19 0.92 114.0 47.0 Start Time 11 635.925 0.18 0.88 115.0 48.0 End Time 12 637.330 0.17 0.83 114.0 48.0 Run 3 13 638.662 0.13 0.64 114.0 45.0 14 639.845 0.12 0.59 115.0 46.0 15 640.965 0.13 0.64 115.0 46.0 16 642.145 0.14 0.69 114.0 46.0 17 643.350 0.14 0.69 115.0 47.0 18 644.570 0.16 0.79 113.0 48.0 19 645.920 0.30 1.50 114.0 48.0 20 647.680 0.28 1.40 114.0 48.0 21 649.465 0.24 1.20 115.0 50.0 22 651.075 0.22 1.10 114.0 50.0 23 652.630 0.19 0.93 114.0 51.0 24 654.100 0.19 0.93 113.0 51.0 25 655.515 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Test Report Compass Minerals 765 North 10500 West Ogden, UT 84404 Sources Tested: One (1) Scrubber: AH-513 Test Dates: February 15 & 16, 2024 Project No. AST-2024-0698 Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Source Test Report Test Program Summary AST-2024-0698 Compass – Ogden, UT Page i Regulatory Information Permit Nos. Title V #5700001003 DAQE-AN1091070039-20 Source Information Source Name Source ID Target Parameters Salt Dryer (D-501) AH-513 PM, PM10, PM2.5 Contact Information Test Location Test Company Analytical Laboratories Compass Minerals Ogden, Inc. 765 North 10500 West Ogden, UT 84404 Holly Hurst hursth@compassminerals.com (801) 732-3251 Vikrant Chavan chavanv@compassminerals.com (801) 648-2005 Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Project Manager Charles Horton charles.horton@alliancetg.com (352) 663-7568 Field Team Leader Tobias Hubbard tobias.hubbard@alliancetg.com (605) 645-8562 QA/QC Manager Kathleen Shonk katie.shonk@alliancetg.com (812) 452-4785 Report Coordinator Indah Rahmadina indah.rahmadina@alliancetg.com Report Reviewer Sarah Perry sarah.perry@alliancetg.com Alliance Technical Group, LLC 5530 Marshall Street Arvada, CO 80002 Eric Grosjean eric.grosjean@alliancetg.com (303) 420-5949 Particle Technology Labs 555 Rogers Street Downers Grove, IL 60515 Oliver Urbanek ourbanek@particlelabs.com (630) 969-2703 Source Test Report Certification Statement AST-2024-0698 Compass – Ogden, UT Page ii Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the relevant sections in the test report. This report is only considered valid once an authorized representative of Alliance has signed in the space provided below; any other version is considered draft. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. Charles Horton, QSTI Alliance Technical Group, LLC Date 4/11/2024 Source Test Report Table of Contents AST-2024-0698 Compass – Ogden, UT Page iii TABLE OF CONTENTS 1.0 Introduction ................................................................................................................................................. 1-1 1.1 Process/Control System Descriptions .......................................................................................................... 1-1 1.2 Project Team ............................................................................................................................................... 1-1 1.3 Site Specific Test Plan & Notification ........................................................................................................ 1-1 2.0 Summary of Results .................................................................................................................................... 2-1 3.0 Testing Methodology .................................................................................................................................. 3-1 3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate ........ 3-1 3.2 U.S. EPA Reference Test Method 3/3A – Oxygen/Carbon Dioxide ........................................................... 3-1 3.3 U.S. EPA Reference Test Method 4 – Moisture Content ............................................................................ 3-1 3.4 U.S. EPA Reference Test Methods 5 and 202 – Total Particulate Matter ................................................... 3-1 3.5 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3/3A .......................................... 3-2 LIST OF TABLES Table 1-1: Project Team ........................................................................................................................................... 1-1 Table 2-1: Summary of Results ................................................................................................................................ 2-1 Table 3-1: Source Testing Methodology .................................................................................................................. 3-1 APPENDICES Appendix A Sample Calculations Appendix B Field Data Appendix C Laboratory Data Appendix D Quality Assurance/Quality Control Data Appendix E Process Operating/Control System Data Introduction Source Test Report Introduction AST-2024-0698 Compass – Ogden, UT Page 1-1 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by Compass Minerals Ogden Inc. (Compass) to conduct compliance testing at the Ogden, Utah facility. The facility is subject to provisions of the Title V Operating Permit #5700001003. Testing was conducted to determine the emission rates of particulate matter (PM), particulate matter less than 2.5 microns (PM2.5), and particulate matter less than 10 microns (PM10) from the exhaust of one (1) scrubber designated as AH-513. Due to stack diameter and/or entrained water limitations of AH-513, Methods 5 and 202 were conducted in lieu of method 201A and 202. Particle sizing was conducted using scanning electron microscopy to determine PM10 and PM2.5. 1.1 Process/Control System Descriptions Compass operates a mineral recovery facility on the eastern shore of the south arm of the Great Salt Lake near Ogden, Utah in Weber County. This facility produces sodium chloride (NaCl), sulfate of potash (SOP) (K2SO4), and magnesium chloride (MgCl2). The process uses crystallized salts, including halite (sodium chloride) and a mixed salt containing potassium sulfate and magnesium sulfate from solar evaporation ponds. The raw halite is washed, wet-screened, dried, cooled, dry-screened, packages, and shipped. The mixed salt is washed, slurried, thickened, crystallized, and converted to schoenite which is then filtered, dried, screened, half granulated/compacted and shipped as sulfate of potash. 1.2 Project Team Personnel involved in this project are identified in the following table. Table 1-1: Project Team Compass Personnel Vikrant Chavan Alliance Personnel Tobias Hubbard Finn Townsley Alan Barrios Dillon Brown 1.3 Site Specific Test Plan & Notification Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by Compass. Summary of Results Source Test Report Summary of Results AST-2024-0698 Compass – Ogden, UT Page 2-1 2.0 Summary of Results Alliance conducted compliance testing at the Compass facility in Ogden, Utah on February 15 and 16, 2024. Testing consisted of determining the emission rates of PM, PM2.5, and PM10 from the exhaust of one (1) scrubber designated as AH-513. Table 2-1 provides a summary of the emission testing results with comparisons to the applicable UDAQ permit limits. Any difference between the summary results listed in the following table and the detailed results contained in appendices is due to rounding for presentation. Table 2-1: Summary of Results Run Number Run 1 Run 2 Run 3 Average Date 2/15/24 2/15/24 2/16/24 -- Filterable Particulate Matter less than 2.5 Microns Data Concentration, grain/dscf 0.00050 0.00030 0.00034 0.00038 Emission Rate, lb/hr 0.078 0.048 0.056 0.061 Filterable Particulate Matter less than 10 Microns Data Concentration, grain/dscf 0.0037 0.0020 0.0014 0.0024 Emission Rate, lb/hr 0.58 0.32 0.24 0.38 Condensable Particulate Matter Concentration, grain/dscf 0.0013 0.0010 0.0010 0.0011 Emission Rate, lb/hr 0.20 0.15 0.16 0.17 Total Particulate Matter less than 2.5 Microns Data 1 Concentration, grain/dscf 0.0018 0.0013 0.0013 0.0015 Emission Limit, grain/dscf -- -- -- 0.0114 Percent of Limit, % -- -- -- 13 Emission Rate, lb/hr 0.28 0.20 0.22 0.23 Emission Limit, lb/hr -- -- -- 1.49 Percent of Limit, % -- -- -- 16 Total Particulate Matter less than 10 Microns Data 2 Concentration, grain/dscf 0.0050 0.0029 0.0024 0.0035 Emission Rate, lb/hr 0.78 0.47 0.40 0.55 Emission Limit, lb/hr -- -- -- 1.49 Percent of Limit, % -- -- -- 37 1 Total PM2.5 is the summation of filterable PM2.5 and condensable PM. 2 Total PM10 is the summation of filterable PM10 and condensable PM. Testing Methodology Source Test Report Testing Methodology AST-2024-0698 Compass – Ogden, UT Page 3-1 3.0 Testing Methodology The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method descriptions are provided below while quality assurance/quality control data is provided in Appendix D. Table 3-1: Source Testing Methodology Parameter U.S. EPA Reference Test Methods Notes/Remarks Volumetric Flow Rate 1 & 2 Full Velocity Traverses Oxygen / Carbon Dioxide 3 / 3A Integrated Bag / Instrumental Analysis Moisture Content 4 Gravimetric Analysis Total Particulate Matter 5 / 202 Isokinetic Sampling 3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA Reference Test Method 1. To determine the minimum number of traverse points, the upstream and downstream distances were equated into equivalent diameters and compared to Figure 1-1 in U.S. EPA Reference Test Method 1. Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type thermocouple and pyrometer. Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2. 3.2 U.S. EPA Reference Test Method 3/3A – Oxygen/Carbon Dioxide The oxygen (O2) and carbon dioxide (CO2) testing was conducted in accordance with U.S. EPA Reference Test Method 3/3A. One (1) integrated Tedlar bag sample was collected during each test run. The bag samples were analyzed on site with a gas analyzer. The remaining stack gas constituent was assumed to be nitrogen for the stack gas molecular weight determination. The quality control measures are described in Section 3.5. 3.3 U.S. EPA Reference Test Method 4 – Moisture Content The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on the same balance to determine the amount of moisture condensed. 3.4 U.S. EPA Reference Test Methods 5 and 202 – Total Particulate Matter The total particulate matter (filterable and condensable PM) testing was conducted in accordance with U.S. EPA Reference Test Methods 5 and 202. The complete sampling system consisted of a stainless-steel nozzle, glass-lined probe, pre-weighed quartz filter, coil condenser, un-weighed Teflon filter, gas conditioning train, pump and calibrated dry gas meter. The gas conditioning train consisted of a coiled condenser and five (5) chilled impingers. The first, second and third impingers were initially empty, the fourth contained 100 mL of de-ionized water and the Source Test Report Testing Methodology AST-2024-0698 Compass – Ogden, UT Page 3-2 last impinger contained 200-300 grams of silica gel. The un-weighed 90 mm Teflon filter was placed between the second and third impingers. The probe liner heating system was maintained at a temperature of 248 ±25°F, and the impinger temperature was maintained at 68°F or less throughout testing. The temperature of the Teflon filter was maintained greater than 65°F but less than or equal to 85°F. Following the completion of each test run, the sampling train was leak checked at a vacuum pressure greater than or equal to the highest vacuum pressure observed during the run. Condensate was collected in the first dry impinger, therefore the front-half of the sample train (the nozzle, probe, and heated pre-weighed filter) was removed in order to purge the back-half of the sample train (coil condenser, first and second impingers and CPM filter). A glass bubbler was inserted into the first impinger. If needed, de-ionized ultra-filtered (DIUF) water was added to the first impinger to raise the water level above the bubbler, then the coil condenser was replaced. Zero nitrogen was connected to the condenser, and a 90-minute purge at 14 liters per minute was conducted. After the completion of the nitrogen purge the impinger contents were measured for moisture gain. The pre-weighed quartz filter was carefully removed and placed in container 1. The probe, nozzle and front half of the filter holder were rinsed three (3) and six (6) times with acetone to remove any adhering particulate matter and these rinses were recovered in container 2. All containers were sealed, labeled and liquid levels marked for transport to the identified laboratory for filterable particulate matter analysis. The contents of impingers 1 and 2 were recovered in container CPM Cont. #1. The back half of the filterable PM filter holder, the coil condenser, impingers 1 and 2 and all connecting glassware were rinsed with DIUF water and then rinsed with acetone, followed by hexane. The water rinses were added to container CPM Cont. #1 while the solvent rinses were recovered in container CPM Cont. #2. The Teflon filter was removed from the filter holder and placed in container CPM Cont. #3. The front half of the condensable PM filter holder was rinsed with DIUF water and then with acetone, followed by hexane. The water rinse was added to container CPM Cont. #1 while the solvent rinses were added to container CPM Cont. #2. All containers were sealed, labeled and liquid levels marked for transport to the identified laboratory for condensable particulate matter analysis. 3.5 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3/3A Cylinder calibration gases used met EPA Protocol 1 (+/- 2%) standards. Copies of all calibration gas certificates can be found in the Quality Assurance/Quality Control Appendix. Low-Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High-Level calibration gases were sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5% absolute difference. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance’s office, all written and electronic data was relinquished to the report coordinator and then a final review was performed by the Project Manager. Appendix A Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: Meter Pressure (Pm), in. Hg where, Pb 25.50 = barometric pressure, in. Hg ΔH 1.191 = pressure differential of orifice, in H2O Pm 25.59 = in. Hg Absolute Stack Gas Pressure (Ps), in. Hg where, Pb 25.50 = barometric pressure, in. Hg Pg -0.30 = static pressure, in. H2O Ps 25.48 = in. Hg Standard Meter Volume (Vmstd), dscf where, Y 0.995 = meter correction factor Vm 38.120 = meter volume, cf Pm 25.59 = absolute meter pressure, in. Hg Tm 514.5 = absolute meter temperature, oR Vmstd 33.267 = dscf Standard Wet Volume (Vwstd), scf where, Vlc 124.5 = weight of H2O collected, g Vwstd 5.871 = scf Moisture Fraction (BWSsat), dimensionless (theoretical at saturated conditions) where, Ts 122.8 = stack temperature, °F Ps 25.48 = absolute stack gas pressure, in. Hg BWSsat 0.145 = dimensionless Moisture Fraction (BWS), dimensionless (measured) where, Vwstd 5.871 = standard wet volume, scf Vmstd 33.267 = standard meter volume, dscf BWS 0.150 = dimensionless Moisture Fraction (BWS), dimensionless where, BWSsat 0.145 = moisture fraction (theoretical at saturated conditions) BWSmsd 0.150 = moisture fraction (measured) BWS 0.145 Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S 1 PM/CPM Pm = Pb + Δ H 13.6 Ps = Pb + Pg 13.6 = 17.636 × Y × Vm × Pm Vwstd = 0.04716 × Vlc BWSsat = 10., Ps BWS = Vwstd (Vwstd + Vmstd) BWS = BWSmsd unless BWSsat <BWSmsd Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S 1 PM/CPM Molecular Weight (DRY) (Md), lb/lb-mole where, CO2 3.6 = carbon dioxide concentration, % O2 15.1 = oxygen concentration, % Md 29.18 = lb/lb mol Molecular Weight (WET) (Ms), lb/lb-mole where, Md 29.18 = molecular weight (DRY), lb/lb mol BWS 0.145 = moisture fraction, dimensionless Ms 27.56 = lb/lb mol Average Velocity (Vs), ft/sec where, Cp 0.840 = pitot tube coefficient Δ P1/2 0.495 = velocity head of stack gas, (in. H2O)1/2 Ts 582.5 = absolute stack temperature, °R Ps 25.48 = absolute stack gas pressure, in. Hg Ms 27.56 = molecular weight of stack gas, lb/lb mol Vs 32.4 = ft/sec Average Stack Gas Flow at Stack Conditions (Qa), acfm where, Vs 32.4 = stack gas velocity, ft/sec As 14.19 = cross-sectional area of stack, ft2 Qa 27,559 = acfm Average Stack Gas Flow at Standard Conditions (Qs), dscfm where, Qa 27,559 = average stack gas flow at stack conditions, acfm BWS 0.145 = moisture fraction, dimensionless Ps 25.48 = absolute stack gas pressure, in. Hg Ts 582.5 = absolute stack temperature, °R Qs 18,172 = dscfm Md = (0.44 × % CO) + (0.32 × % O2) + (0.28 (100 − % CO − % O2)) Ms = Md (1 − BWS) + 18.015 (BWS) Qa = 60 × Vs × As Qs = 17.636 × Qa × (1 − BWS) × Ps Ts Vs = 85.49 × Cp × (Δ P /) avg × Ts Ps x Ms Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S 1 PM/CPM Dry Gas Meter Calibration Check (Yqa), dimensionless where, Y 0.995 = meter correction factor, dimensionless Θ 60 = run time, min. Vm 38.120 = total meter volume, dcf Tm 514.5 = absolute meter temperature, °R ΔH@ 1.853 = orifice meter calibration coefficient, in. H2O Pb 25.50 = barometric pressure, in. Hg ΔH avg 1.191 = average pressure differential of orifice, in H2O Md 29.18 = molecular weight (DRY), lb/lb mol (Δ H)1/2 1.065 = average squareroot pressure differential of orifice, (in. H2O)1/2 Yqa 1.2 = percent Volume of Nozzle (Vn), ft3 where, Ts 582.5 = absolute stack temperature, °R Ps 25.48 = absolute stack gas pressure, in. Hg Vlc 124.5 = volume of H2O collected, ml Vm 38.120 = meter volume, cf Pm 25.59 = absolute meter pressure, in. Hg Y 0.995 = meter correction factor, unitless Tm 514.5 = absolute meter temperature, oR Vn 50.721 = volume of nozzle, ft3 Isokinetic Sampling Rate (I), % where,* Vn 50.721 = nozzle volume, ft3 θ 60.0 = run time, minutes An 0.00043 = area of nozzle, ft2 Vs 32.4 = average velocity, ft/sec I 101.2 = % Filterable PM2.5 Concentration (Cs), grain/dscf where, Mn 67.8 = filterable PM2.5 mass, mg Vmstd 33.267 = standard meter volume, dscf Cs 0.00050 = grain/dscf C=M× 0.0154 Vmstd Yqa = Y − Θ Vm 0.0319 × Tm × 29 Δ@ × Pb + Δ Havg. 13.6 × ΔH avg. × 100 Vn = 0.002669 × +Vm × × Appendix A Example Calculations Location: Source: Project No.: Run No.: Parameter: Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S 1 PM/CPM Filterable PM Emission Rate (PMR), lb/hr where, Cs 0.00050 = filterable PM2.5 concentration, grain/dscf Qs 18,172 = average stack gas flow at standard conditions, dscfm PMR 0.078 = lb/hr Condensable PM Concentration (CCPM), grain/dscf where, MCPM 2.8 = condensable PM mass, mg Vmstd 33.267 = standard meter volume, dscf CCPM 0.0013 = grain/dscf Condensable PM Emission Rate (ERCPM), lb/hr where, CCPM 0.0013 = condensable PM concentration, grain/dscf Qs 18,172 = average stack gas flow at standard conditions, dscfm ERCPM 0.20 = lb/hr Total PM2.5 Concentration (CTPM), grain/dscf where, Cs 0.00050 = filterable PM2.5 concentration, grain/dscf CCPM 0.0013 = condensable PM2.5 concentration, grain/dscf CTPM 0.0018 = grain/dscf Total PM2.5 Emission Rate (ERTPM), lb/hr where, PMR 0.078 = filterable PM2.5 emission rate, lb/hr ERCPM 0.20 = condensable PM2.5 emission rate, lb/hr ERTPM 0.28 = lb/hr PMR = C× Qs × 60 7.0E +03 C=M× 0.0154 Vmstd ER  =  C× Qs × 60 ℎ 7.0E +03 =+ =+ Appendix B Emission Calculations Location Source Project No. Parameter Run Number Run 1 Run 2 Run 3 Average Date 2/15/24 2/15/24 2/16/24 -- Start Time 13:30 16:40 10:05 -- Stop Time 15:05 17:55 11:19 -- Run Time, min (θ)60.0 60.0 60.0 60.0 Barometric Pressure, in. Hg (Pb)25.50 25.50 25.76 25.59 Meter Correction Factor (Y)0.995 0.995 0.995 0.995 Orifice Calibration Value (ΔH @)1.853 1.853 1.853 1.853 Meter Volume, ft3 (Vm)38.120 38.600 39.101 38.607 Meter Temperature, °F (Tm)54.8 54.0 53.1 54.0 Meter Temperature, °R (Tm)514.5 513.7 512.8 513.7 Meter Orifice Pressure, in. WC (ΔH)1.191 1.191 1.271 1.218 Volume H2O Collected, mL (Vlc)124.5 84.7 94.0 101.1 Nozzle Diameter, in (Dn)0.280 0.280 0.280 0.280 Area of Nozzle, ft2 (An)0.0004 0.0004 0.0004 0.0004 Filterable PM Mass, mg (Mn)67.8 28.7 29.4 42.0 SEM PM2.5 Fraction 1.6 2.3 2.6 2.2 Filterable PM2.5 Mass using SEM Analysis, mg (MFPM2.5)1.08 0.7 0.8 0.8 SEM PM10 Fraction 11.8 15.0 11.0 12.6 Filterable PM10 Mass using SEM Analysis, mg (MFPM10)8.0 4.3 3.2 5.2 Condensable PM Mass, mg (MCPM)2.8 2.1 2.2 2.4 Standard Meter Volume, ft3 (Vmstd)33.267 33.741 34.593 33.867 Standard Water Volume, ft3 (Vwstd)5.871 3.994 4.433 4.766 Moisture Fraction Measured (BWSmsd)0.150 0.106 0.114 0.123 Moisture Fraction @ Saturation (BWSsat)0.145 0.123 0.113 0.127 Moisture Fraction (BWS)0.145 0.106 0.113 0.121 Meter Pressure, in Hg (Pm)25.59 25.59 25.85 25.68 Volume at Nozzle, ft3 (Vn)50.721 48.410 49.332 49.49 Isokinetic Sampling Rate, (%)(I)101.2 99.8 100.4 100.5 DGM Calibration Check Value, (+/- 5%)(Yqa)1.2 2.7 1.4 1.8 Filterable PM2.5 Concentration, grain/dscf (Cs)0.00050 0.00030 0.00034 0.00038 Filterable PM2.5 Emission Rate, lb/hr (PMR2.5)0.078 0.048 0.056 0.061 Filterable PM10 Concentration, grain/dscf (Cs)0.0037 0.0020 0.0014 0.0024 Filterable PM10 Emission Rate, lb/hr (PMR10)0.58 0.32 0.24 0.38 Condensable PM Concentration, grain/dscf (CCPM)0.0013 0.0010 0.0010 0.0011 Condensable PM Emission Rate, lb/hr (ERCPM)0.20 0.15 0.16 0.17 Total PM10 Concentration, grain/dscf (Cs)0.0050 0.0029 0.0024 0.0035 Total PM10 Emission Rate, lb/hr (ERTPM10)0.78 0.47 0.40 0.55 Total PM2.5 Concentration, grain/dscf (CTPM)0.0018 0.0013 0.0013 0.0015 Total PM2.5 Emission Rate, lb/hr (ERTPM)0.28 0.20 0.22 0.23 Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S EMISSION CALCULATIONS ISOKINETIC DATA INPUT DATA PM/CPM Emission Calculations Location Source Project No. Parameter Run Number Run 1 Run 2 Run 3 Average Date 2/15/24 2/15/24 2/16/24 -- Start Time 13:30 16:40 10:05 -- Stop Time 15:05 17:55 11:19 -- Run Time, min 60.0 60.0 60.0 60.0 Point 1 0.44 0.44 0.47 0.45 Point 2 0.45 0.45 0.46 0.45 Point 3 0.46 0.47 0.50 0.48 Point 4 0.48 0.46 0.49 0.48 Point 5 0.44 0.46 0.48 0.46 Point 6 0.42 0.42 0.42 0.42 Point 7 0.34 0.25 0.26 0.28 Point 8 0.24 0.21 0.21 0.22 Point 9 0.18 0.18 0.20 0.19 Point 10 0.17 0.17 0.19 0.18 Point 11 0.17 0.18 0.18 0.18 Point 12 0.17 0.16 0.17 0.17 Point 13 0.18 0.13 0.13 0.15 Point 14 0.20 0.13 0.12 0.15 Point 15 0.22 0.13 0.13 0.16 Point 16 0.24 0.14 0.14 0.17 Point 17 0.26 0.14 0.14 0.18 Point 18 0.22 0.16 0.16 0.18 Point 19 0.18 0.18 0.30 0.22 Point 20 0.15 0.32 0.28 0.25 Point 21 0.15 0.23 0.24 0.21 Point 22 0.15 0.22 0.22 0.20 Point 23 0.14 0.21 0.19 0.18 Point 24 0.13 0.20 0.19 0.17 Square Root of ΔP, (in. WC)1/2 (ΔP)0.495 0.488 0.497 0.493 Pitot Tube Coefficient (Cp)0.840 0.840 0.840 0.840 Barometric Pressure, in. Hg (Pb)25.50 25.50 25.76 25.59 Static Pressure, in. WC (Pg)-0.30 -0.33 -0.32 -0.32 Stack Pressure, in. Hg (Ps)25.48 25.48 25.74 25.56 Stack Cross-sectional Area, ft2 (As)14.19 14.19 14.19 14.19 Temperature, °F (Ts)122.8 116.8 114.2 117.9 Temperature, °R (Ts)582.5 576.5 573.9 577.6 Moisture Fraction Measured (BWSmsd)0.150 0.106 0.114 0.123 Moisture Fraction @ Saturation (BWSsat)0.145 0.123 0.113 0.127 Moisture Fraction (BWS)0.145 0.106 0.113 0.121 O2 Concentration, %(O2)15.07 15.08 15.75 15.30 CO2 Concentration, %(CO2)3.62 3.6 3.2 3.47 Molecular Weight, lb/lb-mole (dry)(Md)29.18 29.18 29.14 29.17 Molecular Weight, lb/lb-mole (wet)(Ms)27.56 28.00 27.88 27.81 Velocity, ft/sec (Vs)32.4 31.5 31.9 31.9 At Stack Conditions, acfm (Qa)27,559 26,829 27,155 27,181 At Standard Conditions, dscfm (Qs)18,172 18,696 19,048 18,639 Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S VOLUMETRIC FLOW RATE CALCULATED DATA VELOCITY HEAD, in. WC PM/CPM Method 1 Data Location Source Project No. Date: Vertical Circular 57.00 in 6.00 in 51.00 in 14.19 ft2 2 4.3 ft 1.0 (must be ≥ 0.5) 10.0 ft 2.4 (must be ≥ 2) 24 24 1 Measurer (Initial and Date):JFT 2/14/24 Reviewer (Initial and Date):TCH 2/14/24 2 3 4 5 6 7 8 9 10 11 12 1 14.6 --6.7 --4.4 --3.2 --2.6 --2.1 1 2.1 1.07 7 1/16 2 85.4 --25.0 --14.6 --10.5 --8.2 --6.7 2 6.7 3.42 9 7/16 3 ----75.0 --29.6 --19.4 --14.6 --11.8 3 11.8 6.02 12 4 ----93.3 --70.4 --32.3 --22.6 --17.7 4 17.7 9.03 15 5 --------85.4 --67.7 --34.2 --25.0 5 25.0 12.75 18 3/4 6 --------95.6 --80.6 --65.8 --35.6 6 35.6 18.16 24 1/8 7 ------------89.5 --77.4 --64.4 7 64.4 32.84 38 7/8 8 ------------96.8 --85.4 --75.0 8 75.0 38.25 44 1/4 9 ----------------91.8 --82.3 9 82.3 41.97 48 10 ----------------97.4 --88.2 10 88.2 44.98 51 11 --------------------93.3 11 93.3 47.58 53 9/16 12 --------------------97.9 12 97.9 49.93 55 15/16 *Percent of stack diameter from inside wall to traverse point. A =4.3 ft. B =10 ft. Depth of Duct =51 in. Number of traverse points on a diameter Stack Diagram Cross Sectional Area LOCATION OF TRAVERSE POINTS Traverse Point % of Diameter Distance from inside wall Distance from outside of port No. of Test Ports: Number of Readings per Point: Distance A: Distance A Duct Diameters: Distance B: Distance B Duct Diameters: Minimum Number of Traverse Points: Actual Number of Traverse Points: CIRCULAR DUCT Duct Design: Nipple Length: Depth of Duct: Cross Sectional Area of Duct: Distance from Far Wall to Outside of Port: Duct Orientation: Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S 02/15/24 Stack Parameters Upstream Disturbance Downstream Disturbance B A Cyclonic Flow Check Location Compass Minerals - Ogden, UT Source Scrubber - AH-513 Project No.AST-2024-0064-S Date 02/15/24 Sample Point Angle (ΔP=0) 1 0 2 5 3 10 4 15 5 15 6 10 7 5 8 5 9 5 10 10 11 10 12 5 13 5 14 5 15 10 16 15 17 10 18 10 19 5 20 5 21 5 22 10 23 15 24 10 Average 8 Method 4 Data Location Source Project No. Parameter Analysis Run 1 Date:2/15/24 Impinger No.1 2 3 4 5 Total Contents Empty Empty Empty H2O Silica -- Initial Mass, g 483.0 637.2 573.9 733.4 984.1 3411.6 Final Mass, g 574.6 649.7 578.5 738.2 995.1 3536.1 Gain 91.6 12.5 4.6 4.8 11.0 124.5 Run 2 Date:2/15/24 Impinger No.1 2 3 4 5 Total Contents Empty Empty Empty H2O Silica -- Initial Mass, g 499.2 634.1 643.4 742.9 974.2 3493.8 Final Mass, g 575.4 637.0 643.6 736.9 985.6 3578.5 Gain 76.2 2.9 0.2 -6.0 11.4 84.7 Run 3 Date:2/16/24 Impinger No.1 2 3 4 5 Total Contents Empty Empty Empty H2O Silica -- Initial Mass, g 483.7 639.2 576.3 736.8 975.7 3411.7 Final Mass, g 555.9 642.9 575.3 740.5 991.1 3505.7 Gain 72.2 3.7 -1.0 3.7 15.4 94.0 Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S PM/CPM Gravimetric Isokinetic Field Data Location: Start Time:Source: Date: VALID End Time:Project No.:AST-2024-0064-S PM/CPM Moisture:14.5 % est.Est. Tm:60 °F Pb:25.50 in. Hg Barometric:25.70 in. Hg Est. Ts:140 °F Pg:-0.30 in. WC Static Press:-0.35 in. WC Est. ΔP:0.26 in. WC O2:15.1 % Stack Press:25.67 in. Hg Est. Dn:0.304 in.CO2:3.6 % CO2:3.0 %Target Rate:0.75 scfm Check Pt.Initial Final Corr. O2:16.0 %LEAK CHECKS Pre Mid 1 Mid 2 Mid 3 Post Mid 1 (cf)-- N2/CO:81.0 %0.840 S-type Leak Rate (cfm):0.002 ------0.000 Mid 2 (cf)-- Md:29.12 lb/lb-mole A3 SS Vacuum (in Hg):15 ------8 Mid 3 (cf)-- Ms:27.51 lb/lb-mole Pitot Tube:Pass ------Pass -- Stack Probe Filter Imp Exit Aux Amb.Amb.Amb.Amb.Amb. Begin End 40 Ideal Actual 40 40 40 40 A1 0.00 2.50 0.44 123 2.03 2.00 5 243 250 50 83 98.1 43.27 2 2.50 5.00 0.45 123 2.07 2.10 5 242 251 48 81 100.1 43.76 3 5.00 7.50 0.46 123 2.12 2.10 5 255 254 47 80 99.3 44.24 4 7.50 10.00 0.48 123 2.21 2.20 6 248 252 48 79 100.0 45.19 5 10.00 12.50 0.44 124 2.03 2.00 6 254 254 47 77 100.6 43.30 6 12.50 15.00 0.42 123 1.94 2.00 6 252 255 46 76 99.8 42.27 7 15.00 17.50 0.34 124 1.57 1.60 5 244 253 47 78 105.4 38.07 8 17.50 20.00 0.24 123 1.11 1.10 4 243 254 47 80 104.6 31.95 9 20.00 22.50 0.18 123 0.84 0.84 3 244 253 48 77 101.1 27.67 10 22.50 25.00 0.17 123 0.79 0.80 3 249 254 49 76 104.0 26.89 11 25.00 27.50 0.17 123 0.79 0.80 3 250 254 48 75 103.8 26.89 12 27.50 30.00 0.17 123 0.79 0.80 3 251 255 48 75 101.1 26.89 B1 30.00 32.50 0.18 123 0.84 0.84 3 250 250 47 77 100.0 27.67 2 32.50 35.00 0.20 123 0.93 0.89 3 254 255 47 78 102.3 29.17 3 35.00 37.50 0.22 123 1.02 1.00 3 252 255 46 78 99.7 30.59 4 37.50 40.00 0.24 122 1.11 1.10 3 253 255 46 79 98.7 31.93 5 40.00 42.50 0.26 122 1.21 1.20 3 250 251 46 80 100.4 33.23 6 42.50 45.00 0.22 121 1.02 1.00 3 251 252 46 81 99.6 30.54 7 45.00 47.50 0.18 122 0.84 0.84 3 250 254 46 81 101.2 27.65 8 47.50 50.00 0.15 122 0.70 0.70 3 248 254 46 81 104.5 25.24 9 50.00 52.50 0.15 122 0.70 0.70 3 244 252 45 82 106.9 25.24 10 52.50 55.00 0.15 123 0.69 0.70 3 251 254 45 81 106.2 25.26 11 55.00 57.50 0.14 123 0.65 0.66 3 250 253 45 81 104.9 24.41 12 57.50 60.00 0.13 123 0.60 0.61 3 252 252 45 82 102.3 23.52 Final DGM: Max Vac %ISO BWS 60.0 min 38.120 ft3 0.26 in. WC 54.8 °F 122.8 °F 6 1.191 in. WC 101.2 0.145 glass PR705-2 835.390 836.690 Mid-Point Leak Check Vol (cf):0.280 55 819.850 834.080 55 % ISO 837.930 54 832.800 P-420 Pitot Cp/Type: 809.430 54 55 ΔH @ (in.WC): Probe ID: Nozzle ID: Nozzle Dn (in.): 831.440 Liner Material: 811.530 Pitot Tube ΔP (in WC) 825.330 829.960 815.510 805.130 822.535 807.250 828.340 817.130 Pitot ID: 826.810 823.880 821.210 RE S U L T S 839.096 VmRun Time ΔP Tm 1.2 YqaΔHTs Scrubber - AH-513 STACK DATA (EST) M5-27 Run 1 13:30 15:05 Compass Minerals - Ogden, UT STACK DATA (EST)EQUIPMENT MOIST. DATA Vlc (ml) 124.5 K-FACTOR STACK DATA (FINAL)FILTER NO. Parameter:2/15/24 0.995 1.853 Meter Box ID: Y: Sa m p l e Pt . Gas Temperatures (°F) DGM Average Amb. Sample Time (minutes) Dry Gas Meter Reading (ft3) 56 56 57 57 818.490 53 53 54 803.020 800.976 813.570 55 55 55 56 40 55 55 Vs (fps) Pump Vac (in. Hg) Orifice Press. ΔH (in. WC) Gas Temperatures (°F) 54 54 54 54 4.535 54 56 Isokinetic Field Data Location: Start Time:Source: Date: VALID End Time:Project No.:AST-2024-0064-S PM/CPM Moisture:10.6 % est.Est. Tm:55 °F Pb:25.50 in. Hg Barometric:25.70 in. Hg Est. Ts:123 °F Pg:-0.33 in. WC Static Press:-0.35 in. WC Est. ΔP:0.26 in. WC O2:15.1 % Stack Press:25.67 in. Hg Est. Dn:0.298 in.CO2:3.6 % CO2:3.0 %Target Rate:0.75 scfm Check Pt.Initial Final Corr. O2:16.0 %LEAK CHECKS Pre Mid 1 Mid 2 Mid 3 Post Mid 1 (cf)-- N2/CO:81.0 %0.840 S-type Leak Rate (cfm):0.004 ------0.000 Mid 2 (cf)-- Md:29.12 lb/lb-mole A3 SS Vacuum (in Hg):15 ------10 Mid 3 (cf)-- Ms:27.94 lb/lb-mole Pitot Tube:Pass ------Pass -- Stack Probe Filter Imp Exit Aux Amb.Amb.Amb.Amb.Amb. Begin End --Ideal Actual -------- A1 0.00 2.50 0.44 116 2.20 2.10 5 247 252 58 80 97.4 42.67 2 2.50 5.00 0.45 116 2.25 2.10 5 244 263 57 82 98.4 43.15 3 5.00 7.50 0.47 117 2.35 2.20 5 248 268 59 80 97.7 44.14 4 7.50 10.00 0.46 118 2.29 2.20 5 241 267 59 82 98.4 43.71 5 10.00 12.50 0.46 119 2.29 2.20 5 244 266 60 83 97.6 43.74 6 12.50 15.00 0.42 119 2.09 2.00 5 247 271 60 81 98.6 41.80 7 15.00 17.50 0.25 118 1.25 1.20 4 251 266 61 82 99.3 32.22 8 17.50 20.00 0.21 118 1.05 0.99 3 252 259 61 83 99.5 29.53 9 20.00 22.50 0.18 118 0.90 0.85 3 253 258 58 84 100.3 27.34 10 22.50 25.00 0.17 117 0.86 0.80 3 252 259 58 82 101.6 26.55 11 25.00 27.50 0.18 117 0.91 0.85 3 252 262 57 84 101.6 27.32 12 27.50 30.00 0.16 117 0.81 0.76 3 250 262 56 82 100.9 25.75 B1 30.00 32.50 0.13 114 0.66 0.62 2 250 261 55 84 101.5 23.15 2 32.50 35.00 0.13 114 0.66 0.62 2 252 260 52 85 103.2 23.15 3 35.00 37.50 0.13 114 0.66 0.62 2 253 258 52 84 103.2 23.15 4 37.50 40.00 0.14 115 0.71 0.67 2 254 258 51 82 101.8 24.05 5 40.00 42.50 0.14 116 0.71 0.66 2 255 259 51 81 101.9 24.07 6 42.50 45.00 0.16 116 0.81 0.76 2 252 258 50 80 103.7 25.73 7 45.00 47.50 0.18 117 0.91 0.85 2 251 262 50 82 102.1 27.32 8 47.50 50.00 0.32 117 1.61 1.50 3 251 263 49 83 100.3 36.42 9 50.00 52.50 0.23 117 1.16 1.10 3 252 264 49 82 99.3 30.88 10 52.50 55.00 0.22 118 1.11 1.00 3 253 262 48 79 102.0 30.23 11 55.00 57.50 0.21 118 1.06 0.99 3 255 260 48 81 100.4 29.53 12 57.50 60.00 0.20 118 1.01 0.95 3 254 258 47 79 102.6 28.82 Final DGM: Max Vac %ISO BWS 60.0 min 38.600 ft3 0.25 in. WC 54.0 °F 116.8 °F 5 1.191 in. WC 99.8 0.106 MOIST. DATA Vlc (ml) 84.7 FILTER NO. Y: ΔH @ (in.WC): Probe ID: 0.995 1.853 Liner Material: Gas Temperatures (°F) 4.98 Pitot ID: Pitot Cp/Type: 0.280 P-420 Pitot Tube ΔP (in WC) PR705-2 glass Orifice Press. ΔH (in. WC) DGM Average Amb. -- RE S U L T S Run Time 2.7 Vm ΔH Yqa Pump Vac (in. Hg) Gas Temperatures (°F) 53 53 52 54 TsTm 54 55 16:40 K-FACTOR 16443-c STACK DATA (EST) Dry Gas Meter Reading (ft3) EQUIPMENT Scrubber - AH-513 Vs (fps) Compass Minerals - Ogden, UT 2/15/24 STACK DATA (EST) M5-27 Sample Time (minutes) Nozzle Dn (in.): % ISO Nozzle ID: 17:55 STACK DATA (FINAL) Mid-Point Leak Check Vol (cf): Run 2 Parameter: Meter Box ID: Sa m p l e Pt . ΔP 878.066 876.550 52 52 52 855.490 853.990 56 54 839.466 852.360 848.110 850.270 841.580 845.930 843.740 871.880 875.030 873.450 54 52 54 56 55 54 54 54 55 55 56 55 55 856.890 859.690 861.020 862.230 858.270 865.950 863.460 864.690 867.210 868.580 870.010 Isokinetic Field Data Location: Start Time:Source: Date: VALID End Time:Project No.:AST-2024-0064-S PM/CPM Moisture:11.3 % est.Est. Tm:54 °F Pb:25.76 in. Hg Barometric:25.70 in. Hg Est. Ts:117 °F Pg:-0.32 in. WC Static Press:-0.35 in. WC Est. ΔP:0.25 in. WC O2:15.8 % Stack Press:25.67 in. Hg Est. Dn:0.301 in.CO2:3.2 % CO2:3.0 %Target Rate:0.75 scfm Check Pt.Initial Final Corr. O2:16.0 %LEAK CHECKS Pre Mid 1 Mid 2 Mid 3 Post Mid 1 (cf)-- N2/CO:81.0 %0.840 S-type Leak Rate (cfm):0.001 ------0.000 Mid 2 (cf)-- Md:29.12 lb/lb-mole A3 SS Vacuum (in Hg):15 ------9 Mid 3 (cf)-- Ms:27.86 lb/lb-mole Pitot Tube:Pass ------Pass -- Stack Probe Filter Imp Exit Aux Amb.Amb.Amb.Amb.Amb. Begin End --Ideal Actual -------- A1 0.00 2.50 0.47 115 2.31 2.20 6 250 250 44 65 102.0 44.13 2 2.50 5.00 0.46 113 2.27 2.20 6 247 247 45 69 102.9 43.58 3 5.00 7.50 0.50 114 2.46 2.40 7 249 240 45 68 101.0 45.47 4 7.50 10.00 0.49 114 2.42 2.40 7 249 240 45 68 99.2 45.02 5 10.00 12.50 0.48 113 2.37 2.30 7 251 242 46 67 99.2 44.51 6 12.50 15.00 0.42 114 2.07 2.00 6 249 241 46 70 98.7 41.68 7 15.00 17.50 0.26 115 1.28 1.30 5 252 249 46 71 104.7 32.82 8 17.50 20.00 0.21 115 1.04 1.00 4 249 246 47 71 100.5 29.49 9 20.00 22.50 0.20 115 0.99 0.97 4 251 251 47 72 102.3 28.78 10 22.50 25.00 0.19 114 0.94 0.92 4 249 245 47 75 98.8 28.03 11 25.00 27.50 0.18 115 0.90 0.88 4 250 248 48 78 101.2 27.31 12 27.50 30.00 0.17 114 0.85 0.83 4 249 246 48 82 98.4 26.51 B1 30.00 32.50 0.13 114 0.65 0.64 3 254 245 45 68 99.9 23.19 2 32.50 35.00 0.12 115 0.60 0.59 3 247 248 46 69 98.4 22.30 3 35.00 37.50 0.13 115 0.65 0.64 3 246 244 46 70 99.6 23.21 4 37.50 40.00 0.14 114 0.70 0.69 3 249 244 46 71 97.9 24.06 5 40.00 42.50 0.14 115 0.70 0.69 3 251 242 47 71 99.0 24.08 6 42.50 45.00 0.16 113 0.80 0.79 4 252 245 48 72 102.5 25.70 7 45.00 47.50 0.30 114 1.50 1.50 5 255 243 48 75 97.7 35.22 8 47.50 50.00 0.28 114 1.40 1.40 5 251 240 48 77 102.6 34.03 9 50.00 52.50 0.24 115 1.20 1.20 5 250 244 50 79 100.0 31.53 10 52.50 55.00 0.22 114 1.10 1.10 5 250 243 50 81 100.5 30.16 11 55.00 57.50 0.19 114 0.95 0.93 4 248 244 51 78 102.2 28.03 12 57.50 60.00 0.19 113 0.96 0.93 4 245 244 51 75 98.3 28.01 Final DGM: Max Vac %ISO BWS 60.0 min 39.101 ft3 0.26 in. WC 53.1 °F 114.2 °F 7 1.271 in. WC 100.4 0.113 RE S U L T S Run Time 56 56 55 655.515 55 55 57 57 56 56 57 1.4 ΔHVm YqaΔPTmTs 616.414 631.530 629.795 625.490 627.720 623.240 633.030 620.930 651.075 11:19 K-FACTOR MOIST. DATA Vlc (ml) 94.0 Scrubber - AH-513 16420-c STACK DATA (EST) Parameter: 10:05Compass Minerals - Ogden, UT 2/16/24 Run 3 STACK DATA (EST) M5-27 Nozzle ID: Nozzle Dn (in.): Sa m p l e Pt . Sample Time (minutes) Dry Gas Meter Reading (ft3)-- 0.280 EQUIPMENT Meter Box ID: Y: ΔH @ (in.WC): Probe ID: Liner Material: Pitot ID: Pitot Cp/Type: 0.995 DGM Average Amb. Pitot Tube ΔP (in WC) Pump Vac (in. Hg) STACK DATA (FINAL) 4.954 FILTER NO. Mid-Point Leak Check Vol (cf): 55 % ISO 54 Vs (fps) Orifice Press. ΔH (in. WC) Gas Temperatures (°F) 49 Gas Temperatures (°F) PR705-2 1.853 glass P-420 51 48 51 49 50 50 50 654.100 652.630 53 647.680 649.465 618.670 50 54 51 643.350 644.570 640.965 645.920 634.520 639.845 642.145 638.662 637.330 635.925 Appendix C Project No. AST-2024-0698 Alliance Technical Group, LLC Analytical Services 5530 Marshall St. Arvada, CO 80002 (720) 457-9504 www.alliancetg.com Analytical Laboratory Report Compass Minerals - Ogden 765 N 10500 W Ogden, UT 84404 1 of 22 Quality Assurance Associate Date Certification Statement Alliance Source Testing, LLC (AST) has completed the analysis as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and AST is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Any deviations or problems are detailed in the relevant sections on the test report. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. Validation Signature The analytical data and all QC contained within this report was reviewed and validated by the following individual. James Davidson 2 of 22 Digitally signed by James Davidson DN: C=US, CN=James Davidson, E=james.davidson@stacktest.com Reason: I am the author of this document Location: your signing location here Date: 2024.03.06 16:15:13-06'00' Foxit PDF Editor Version: 11.2.7 James Davidson Project Narrative Analytical Method(s): Method 5 - Determination of Particulate Matter Emissions From Stationary Sources Method 202 - Dry Impinger Method for Determining Condensable Particulate Matter Emissions From Stationary Sources Filterable The filter(s) were either oven dried and/or desiccated per the method until a final weight was obtained. The liquid fractions were extracted if required, evaporated and cooled until a final weight was obtained. These fractions were summed together to provide the total Particulate Matter collected. Condensable The filter(s) were extracted per the method. The organic extract was added to the organic rinse, and the inorganic extract was added to the inorganic rinse. The inorganic fraction was extracted with solvent per the method. Extracts were combined with the organic rinse. The organic and inorganic fractions were evaporated and desiccated until a final weight was obtained. MDL The Minimum Detection Level (MDL) is 0.5 mg per fraction. If the measured result for a fraction is less than the MDL, the MDL was used in ensuing calculations. Blank Correction If blank correction is performed, only blank values returned higher than the MDL are used. If a blank returns a value less than the MDL, no correction is included. Method 202 Recovery Blank corrections are applied by fraction (inorganic subtracted from inorganic; organic subtracted from organic). Custody:The samples were received by Ryan Gillett on 2/22/24 in Arvada, CO. The samples were received in good condition with proper Chain-of-Custody documentation. No apparent container problems were noted upon receipt. Prior to analysis, the samples were kept secure with access limited to authorized personnel of AST. Number of Samples:23 (2 on Hold) Labeling: Acceptable Analyst:Jake Schmitt - Laboratory Analyst I Eric Grosjean - Technical Director Equipment:Mettler Toledo Balance ML-104, SN B217893065. This scale was used for analytical determinations of filters and rinse vessels. Denver Instruments Balance TB-6201, SN 17904189. This scale was used to measure the total mass of rinse collected for blank correction. Analysis was performed on the same balance as the associated tare. Quincy Lab Inc oven, 30CG, SN G3-012673. Lab Reagents:Acetone Lot Number: 224521 Hexane Lot Number: 224540 QC Notes:The samples met the minimum criteria established by the relevant method. A blank correction was applied per the method. 3 of 22 Client City, State Project No. Method Lab ID Field ID Filter ID 15588 - C 16443 - C 16420 - C Filter Tare Weight, g Date - Desiccator Time - Desiccator Date of Weighing 2/26/24 2/26/24 2/23/24 2/26/24 2/23/24 2/26/24 Time of Weighing 4:56 15:20 14:25 4:56 14:25 4:56 Filter Weight, g 0.5279 0.5276 0.5376 0.5374 0.5422 0.5420 Filter PM Mass, mg* Lab ID Field ID Beaker ID Beaker tare, g Beaker with Acetone, g Acetone Mass, g Date - Desiccator Time - Desiccator Date of Weighing 2/26/24 2/26/24 2/26/24 2/26/24 2/26/24 2/27/24 Time of Weighing 5:01 11:37 5:01 11:37 11:37 5:23 Weight, g 4.1528 4.1531 4.1263 4.1267 4.1569 4.1569 Rinse PM Mass, mg* Blank Corrected Total PM Mass, mg *All fractions were analyzed and returned values greater than the MDL of 0.5 mg. M5/202 - AH-513 Scrubber - Run 1 Cont. 1 M5/202 - AH-513 Scrubber - Run 2 Cont. 1 M5/202 - AH-513 Scrubber - Run 3 Cont. 1 Compass Minerals - Ogden Ogden, UT 84404 AST-2024-0698 EPA Method 5 Front Half Filter D40370 D40375 D40380 13:55 13:55 13:55 2/22/24 2/22/24 2/22/24 62.5 25.6 25.8 Front Half Rinse M5/202 - AH-513 Scrubber - Run 1 Cont. 2 M5/202 - AH-513 Scrubber - Run 2 Cont. 2 M5/202 - AH-513 Scrubber - Run 3 Cont. 2 32867 32871 32888 D40371 D40376 D40381 4.1477 4.1234 4.1533 97.9 91.6 108.9 12:51 93.8 87.5 104.7 2/23/24 2/23/24 2/23/24 67.8 28.7 29.4 0.4653 0.5119 0.5164 5.3 3.1 3.6 No 12:51 12:51 4 of 22 Client City, State Project No. Method Lab ID Field ID Beaker ID Beaker tare, g Beaker with Acetone, g Acetone Mass, g Date - Desiccator Time - Desiccator Date of Weighing 2/26/24 2/26/24 Time of Weighing 5:01 11:37 Weight, g 4.1526 4.1529 Blank Mass, mg* Compass Minerals - Ogden 148.25 M5 Acetone Blank 32850 0.0 12:51 144.10 2/23/24 4.1527 D40385 Acetone Blank EPA Method 5 AST-2024-0698 Ogden, UT 84404 5 of 22 Client City, State Project No. Method Lab ID Field ID Lab ID Field ID Beaker ID Beaker tare, g Beaker Solvent, g Solvent Mass, g Date - Desiccator Time - Desiccator Date of Weighing 2/26/24 2/26/24 2/26/24 2/26/24 2/26/24 2/26/24 Time of Weighing 5:08 11:57 5:08 11:57 5:08 11:57 Weight, g 3.9374 3.9377 3.9414 3.9416 3.9422 3.9424 Organic PM Mass, mg* Lab ID Field ID Beaker ID Beaker tare, g Beaker Water, g Water Mass, g Date - Desiccator Time - Desiccator Date of Weighing 2/27/24 2/28/24 2/26/24 2/26/24 2/26/24 2/27/24 Time of Weighing 13:33 5:01 5:16 11:49 11:49 5:30 Weight, g 49.7941 49.7945 81.6311 81.6315 86.3998 86.3999 Inorganic Mass, mg* Blank Corrected Total PM Mass, mg *All fractions were analyzed and returned values greater than the MDL of 0.5 mg. D40374 D40379 D40384 D40373 D40378 D40383 Inorganic Fraction 3.9359 3.9399 3.9405 M5/202 - AH-513 Scrubber - Run 1 Cont. 5 M5/202 - AH-513 Scrubber - Run 2 Cont. 5 M5/202 - AH-513 Scrubber - Run 3 Cont. 5 32903 32910 32930 437.1 255.6 252.7 M5/202 - AH-513 Scrubber - Run 1 Cont. 4 M5/202 - AH-513 Scrubber - Run 2 Cont. 4 M5/202 - AH-513 Scrubber - Run 3 Cont. 4 31766 31752 49.7912 81.6289 86.3974 337.2486.9 339.1 2.4 Yes 255.9 128.9 223.0 31586 252.0 125.0 219.1 1.7 1.7 1.8 2/23/24 Organic Fraction Compass Minerals - Ogden 2/26/24 2/23/24 2/23/24 7:25 15:10 15:10 3.1 2.4 M5/202 - AH-513 Scrubber - Run 1 Cont. 3 M5/202 - AH-513 Scrubber - Run 2 Cont. 3 M5/202 - AH-513 Scrubber - Run 3 Cont. 3 Ogden, UT 84404 AST-2024-0698 EPA Method 202 Teflon Filter D40372 D40377 D40382 2/23/24 2/23/24 15:37 15:37 15:37 2.8 2.1 2.2 6 of 22 Client City, State Project No. Method Lab ID Field ID Lab ID Field ID Beaker ID Beaker tare, g Beaker Solvent, g Solvent Mass, g Date - Desiccator Time - Desiccator Date of Weighing 2/26/24 2/26/24 2/26/24 2/26/24 Time of Weighing 5:08 11:57 5:08 11:57 Weight, g 3.9175 3.9173 3.8752 3.8753 Organic Mass, mg* Lab ID Field ID Beaker ID Beaker tare, g Beaker Water g Water Mass, g Date - Desiccator Time - Desiccator Date of Weighing 2/26/24 2/26/24 2/26/24 2/26/24 Time of Weighing 5:16 11:49 5:16 11:49 Weight, g 66.3589 66.3592 75.4776 75.4779 Inorganic Mass, mg* D40390 D40387 D40389 D40386 32899 32935 M202 - FT Proof Recovery Blank Cont. 5 M202 - FT Proof Blank Cont. 5 133.3 119.6 3.8729 2/23/24 2/23/24 129.4 115.7 3.9162 15:37 15:37 M202 - FT Proof Recovery Blank Cont. 4 M202 - FT Proof Blank Cont. 4 Field Train Blank Proof Blank 1.2 2.0 Inorganic Fraction Blanks Compass Minerals - Ogden Ogden, UT 84404 AST-2024-0698 EPA Method 202 Field Train Blank Teflon Filter Blanks Organic Fraction Blanks M202 - FT Proof Recovery Blank Cont. 3 N/A Field Train Blank Proof Blank N/A Proof Blank D40388 1.1 1.4 31747 66.3579 75.4764 31761 235.0 265.3 15:10 15:10 2/23/24 2/23/24 168.6 189.8 7 of 22 8 of 22 9 of 22 10 of 22 11 of 22 12 of 22 13 of 22 14 of 22 15 of 22 16 of 22 17 of 22 18 of 22 19 of 22 20 of 22 21 of 22 This is the last page of the report. 22 of 22 Appendix D Method 3/3A Data Location Source Project No. Date/Time 2/15/24 10:30 Date/Time 2/15/24 10:30 Make/Model/SN Servomex 4900 100269 Servomex 4900 100269 Parameter Cylinder ID Cylinder Concentration, % Analyzer Concentration, %Cylinder ID Cylinder Concentration, % Analyzer Concentration, % Zero Gas 0.00 0.01 0.00 0.01 High Range Gas CC764364 23.98 24.01 CC764364 23.9 23.87 Mid Range Gas RR02538 11.00 11.00 RR02538 10.9 11.16 Concentration Span, % Required Accuracy, % Run No. Analysis Date/Time 2/15/2024 R1 2/15/2024 R2 2/16/2024 R3 Parameter O2 %CO2 %O2 %CO2 %O2 %CO2 % Analysis #1 15.02 3.66 15.05 3.60 15.76 3.30 Analysis #2 15.06 3.63 15.09 3.61 15.77 3.20 Analysis #3 15.14 3.58 15.11 3.59 15.72 3.10 Average 15.1 3.6 15.1 3.6 15.8 3.2 Date/Time 2/16/24 8:00 Date/Time 2/16/24 8:00 Make/Model/SN Servomex 4900 100269 Servomex 4900 100269 Parameter Cylinder ID Cylinder Concentration, % Analyzer Concentration, %Cylinder ID Cylinder Concentration, % Analyzer Concentration, % Zero Gas 0.00 0.00 0.00 0.05 High Range Gas CC764364 23.98 10.99 CC764364 23.90 11.02 Mid Range Gas RR02538 11.00 24.00 RR02538 10.90 23.98 Concentration Span, % Required Accuracy, % The remaining consistuent is assumed to be nitrogen. Run 1 Run 2 Run 3 Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S 0.48 0.48 24.0 O2 Data CO2 Data 23.9 24.0 23.9 0.48 0.48 Balance Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551-8150 Accreditation #62754 PGVP Vendor ID # G12023 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number:CC764364 Certification Date:09/21/2023 Product ID Number:127907 Expiration Date:09/19/2031 Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA COA #CC764364.20230830-0 Lot Number:CC764364.20230830 Customer PO. NO.:Tracking Number:108811898 Customer:Previous Certification Dates: This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531, using procedure G2. Do Not Use This Cylinder Below 100 psig (0.7 Megapascal). Certified Concentration(s) Component Concentration Uncertainty Analytical Principle Assayed On Carbon Dioxide 23.9 %±0.2 %FTIR 09/21/2023 Oxygen 23.98 %±0.04 %MPA 09/14/2023 Nitrogen Analytical Measurement Data Available Online. Reference Standard(s) Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference CC737012 CC737012.20230228 07/09/2031 GMIS N2 O2 20 %0.112 SRM 2659a EB0022021 EB0022021.20180323 07/15/2026 GMIS N2 CO2 14.9 %0.777 101001 Analytical Instrumentation SMART-CERT Component Principle Make MPC Date O2 MPA Thermo 09/13/2023 CO2 FTIR MKS 09/21/2023 Serial 1162980025 017146467 This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. Timothy Davis Analytical Chemist Assay Laboratory: Red Ball TGS Version 02-J, Revised on 2018-09-17 Model 410i MKS 2031DJG2EKVS13T Balance Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551-8150 Accreditation #62754 PGVP Vendor ID # G12023 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number:RR02538 Certification Date:09/21/2023 Product ID Number:125371 Expiration Date:09/19/2031 Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA COA #RR02538.20230831-0 Lot Number:RR02538.20230831 Customer PO. NO.:Tracking Number:103925725 Customer:Previous Certification Dates: This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531, using procedure G1. Do Not Use This Cylinder Below 100 psig (0.7 Megapascal). Certified Concentration(s) Component Concentration Uncertainty Analytical Principle Assayed On Carbon Dioxide 10.9 %±0.11 %FTIR 09/21/2023 Oxygen 11.00 %±0.03 %MPA 09/18/2023 Nitrogen Analytical Measurement Data Available Online. Reference Standard(s) Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference CC737012 CC737012.20230228 07/09/2031 GMIS N2 O2 20 %0.112 SRM 2659a EB0022021 EB0022021.20180323 07/15/2026 GMIS N2 CO2 14.9 %0.777 101001 Analytical Instrumentation SMART-CERT Component Principle Make MPC Date O2 MPA Thermo 09/18/2023 CO2 FTIR MKS 09/21/2023 Serial 1162980025 017146467 This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. Jasmine Godfrey Analytical Chemist Assay Laboratory: Red Ball TGS Version 02-J, Revised on 2018-09-17 Model 410i MKS 2031DJG2EKVS13T QA/QC Data Location Source Project No. Parameter #1 #2 #3 Dn (Average)Difference 2/15/24 A3 0.280 0.280 0.280 0.280 0.000 SS 2/15/24 P-420 no no no Date Probe or Thermocouple ID Reference Temp. (°F) Indicated Temp. (°F)Difference Criteria Probe Length 2/15/24 PR705-2 250.0 250.0 0.0%6 ' Date 02/15/24 Balance ID:5A2001026 Certified Weight ID:SLC-1KG-3 Certified Weight (g):1000.0 Measured Weight (g):999.8 Weight Difference (g):0.2 ---------- 2/15/24 Weather Station No No No 2/15/24 M5-27 ACETONE 230620 Fisher HEXANES 194731 Fisher DI 232650 Fisher Flow Rate (lpm):14 Flow Rate (lpm):14 Flow Rate (lpm):14 Clock Time Temperature Clock Time Temperature Clock Time Temperature 15:15 78.0 18:15 77.0 11:45 75.0 *1.5hr Purge Times* -78.0 --77.0 --75.0 -78.0 --77.0 --75.0 -78.0 --76.0 --75.0 16:45 78.0 19:45 76.0 13:15 75.0 Compass Minerals - Ogden, UT Scrubber - AH-513 AST-2024-0064-S Nozzle Diameter (in.) Date Nozzle ID Criteria PM/CPM Material Date Meter Box ID Positive Pressure Leak Check Pass ≤ 0.004 in. Date Pitot ID Evidence of damage? Weather Station Location OGDEN AIRPORT Evidence of mis-alignment? Calibration or Repair required? Field Balance Check Posttest Purge Run 1 Run 2 Run 3 ± 1.5 % (absolute) Reagent ByDateField LotField Prep performedLot# Date Barometric Pressure Evidence of damage?Reading Verified Calibration or Repair required? Document ID 620.004 Revision 23.0 Effective Date 1/25/23 Issuing Department Page 1 of 1 Console ID: Meter S/N:20035543 Critical Orifice S/N: (PbI) (PbF) (Pb) (Y)1330-31 1330-31 1330-25 1330-25 1330-19 1330-19 (K')0.8429 0.8429 0.6728 0.673 0.5186 0.519 (VP)13.0 13.0 15.0 15.0 17.0 17.0 Initial DGM Volume, ft3 (VmI)501.924 512.781 528.098 536.765 548.287 555.093 Final DGM Volume, ft3 (VmF)512.781 523.688 536.765 545.420 555.093 561.889 Total DGM Volume, ft3 (Vm)10.857 10.907 8.667 8.655 6.806 6.796 Ambient Temperature, °F (Ta)64 64 63 63 63 63 Initial DGM Temperature, °F (TmI)63 63 64 65 64 64 Final DGM Temperature, °F (TmF)63 64 65 64 64 65 Average DGM Temperature, °F ( Tm)63 64 65 65 64 65 Elapsed Time (Θ)10.00 10.00 10.00 10.00 10.00 10.00 Meter Orifice Pressure, in. WC (ΔH)3.20 3.20 2.10 2.10 1.30 1.30 Standard Meter volume, ft3 (Vmstd)9.2720 9.3058 7.3570 7.3468 5.7693 5.7553 Standard Critical Orifice Volume, ft3 (Vcr)9.2341 9.2341 7.3777 7.3777 5.6868 5.6868 Meter Correction Factor (Y)0.996 0.992 1.003 1.004 0.986 0.988 Tolerance --0.001 0.003 0.008 0.009 0.009 0.007 Orifice Calibration Value (ΔH @)1.803 1.801 1.842 1.842 1.917 1.915 Tolerance --0.051 0.052 0.011 0.011 0.063 0.062 Orifice Cal Check -- Meter Correction Factor (Y) Orifice Calibration Value (ΔH @) Accuracy Difference oF oR oF oR %oF 0 460 2 462 -0.4 2 68 528 69 529 -0.2 1 100 560 102 562 -0.4 2 223 683 225 685 -0.3 2 248 708 250 710 -0.3 2 273 733 274 734 -0.1 1 300 760 301 761 -0.1 1 400 860 401 861 -0.1 1 500 960 501 961 -0.1 1 600 1,060 600 1,060 0.0 0 700 1,160 700 1,160 0.0 0 800 1,260 800 1,260 0.0 0 900 1,360 900 1,360 0.0 0 1,000 1,460 999 1,459 0.1 1 1,100 1,560 1,100 1,560 0.0 0 1,200 1,660 1,199 1,659 0.1 1 Calibration Date: 0.94 1.68 1.66 DGM Calibration-Orifices Tech Services 25.07 25.07 25.07 K' Factor, ft3·R1/2 / in. WC·min CL23A Vacuum Pressure, in. Hg Initial Barometric Pressure, in. Hg Final Barometric Pressure, in. Hg Average Barometric Pressure, in. Hg Critifcal Orifice ID Calibration Detail M5-27 1330 Positive Pressure Leak Check Equipment Detail - Dry Gas Meter 0.995 1.853 Yes Personnel Reference Calibrator Make: Reference Calibrator Model: Reference Calibrator S/N: Calibration Detail Equipment Detail - Thermocouple Sensor Reference Temp.Display Temp. OMEGA T-197207 Stacey CunninghamReviewed By: RYAN LYONSCalibration By: 2/2/2024 Appendix E AH513 Compliance Testing Run 1 Run 2 Run 3 Average Start 02/15/2024 13:30 02/15/2024 16:40 02/16/2024 10:05 - Stop 02/15/2024 15:05 02/15/2024 17:55 02/16/2024 11:19 - Duration (min)60 60 60 - Fan Water (gpm).FT513 94.8 93.8 102.4 97.0 Spray Water (gpm).FT513B 35.0 32.6 37.1 34.9 Scrubber Water (gpm).FT513T 129.9 126.3 139.5 131.9 Fan Speed (rpm)AH513_RPM 1344.1 1344.1 1344.1 1344.1 Wet Salt (tph).W501 106.8 106.2 108.8 107.3 Throughput (tph).W503 121.4 120.5 120.4 120.7 Last Page of Report